# Evaporative Emissions from In

- Use Vehicles: Test Fleet Expansion (CRC E

- 77

- 2b)

Final Report

# Evaporative Emissions from In

- Use Vehicles: Test Fleet Expansion (CRC E

- 77

- 2b)

Final Report

Assessment and Standards Division Office of Transportation and Air Quality U.S. Environmental Protection Agency

Prepared for EPA by Harold Haskew & Associates, Inc.

EPA Contract No. EP-C-07-028

Work Assignment No. 2-05

for

Southwest Research Institute

NOTICE

This technical report does not necessarily represent final EPA decisions or positions. It is intended to present technical analysis of issues using data that are currently available. The purpose in the release of such reports is to facilitate the exchange of technical information and to inform the public of technical developments.

EPA-420-R-10-025 October 2010

# EVAPORATIVE EMISSIONS FROM IN

- USE VEHICLES : TEST FLEET EXPANSION

FINAL REPORT

EPA Report EPA

- 420

- R

- 10

- 025 SwRI ® 

## Project No. 03.14936.05 CRC Report CRC E

- 77

- 2b

Prepared for:

Environmental Protection Agency 26 West Martin Luther King Drive Cincinnati, OH 45268

EPA Contract EP

- C

- 07

- 028 Work Assignment 2

- 05

Prepared by:

Harold M. Haskew, P.E. Thomas F. Liberty Harold Haskew & Associates, Inc. 425 W. Huron, S uite 230 Milford, MI 48381

Reviewed and Submitted by: Martin J. Heimrich Southwest Research Institute

June 2010



# SOUTHWEST RESEARCH INSTITUTE ****

SAN ANTONIO , TX ● HOUSTON, TX ● WASHINGTON, DC

# EVAPORATIVE EMISSIONS FROM IN

- USE VEHICLES : TEST FLEET EXPANSION

FINAL REPORT

EPA Report EPA

- 420

- R

- 10

- 025 SwRI ® 

## Project No. 03.14936.05 CRC Report CRC E

- 77

- 2b

Prepared for:

Environmental Protection Agency 26 West Martin Luther King Drive Cincinnati, OH 45268

EPA Contract EP

- C

- 07

- 028 Work Assignment 2

- 05

Prepared by:

Harold M. Haskew, P.E. Thomas F. Liberty Harold Haskew & Associates, Inc. 425 W. Huron, S uite 230 Milford, MI 48381



## June 2010

Reviewed & Submitted by: Approv ed by:

_________________________________ ________________________________ Martin J. Heimrich, Manager Jeff J. White, Director

DEPARTMENT OF EMISSIONS RESEARCH AND DEVELOPMENT ENGINE, EMISSIONS AND VEHICLE RESEARCH DIVISION

This report shall not be reproduced, except in full, without the written approval of Southwest Research Institute ®

. Results and discussion given in this report relate only to the test items described in this report.

### SwRI Final Report 03.14936.05 

## ii CRC E

- 77

- 2b 

## FOREWORD

This project was conducted for the US Environmental Protection Agency (EPA) under contract with Southwest Research Institute ® 

## (SwRI ® 

## ). This report is submitted in fulfillment of Work Assignments 1

- 05 and 2

- 05 of EPA Contract EP

- C

- 07

- 028 by Southwest Research Institute, 6220 Culebra Road, San Antonio, Texas 78238. Work Assignment 1

- 05 was initiated on June 28, 2008, and this project c ontinued with Work Assignment 2

- 05 and was contractually completed on June 27, 2010. The program was identified within SwRI as project 03. 14175.05 for Work Assignment 1

- 05 and as project 03. 14936.05 for Work Assignment 2

- 05.

This report is identified by EPA as EPA

- 420

- R

- 10

- 025.

This project was also identified by the Coordinating Research Council (CRC) as project E

- 77

- 2b. The work reported herein is a part of a continuing series of CRC E

- 7 7 evaporative emission/ permeation test programs.

Harold Haskew a nd Associates (HH&A) was subcontracted by SwRI to lead the laboratory work under SwRI Subcontract Nos. A99099X and A99184X. The evaporative emissions and permeation emissions test work was performed at Automotive Testing Laboratory (ATL) in Mesa, Arizona.

The EPA Work Assignment Manager was Ms. Constance Hart of the Assessment and Standards Division, Office of Transportation and Air Quality, Ann Arbor, Michigan. The project contract was managed by the Department of Emissions Research and Development in t he Engine, Vehicle and Emissions Research Division of SwRI, under the supervision of Mr. Jeff White, Director. Mr. Patrick Merritt managed EPA Contract EP

- C

- 07

- 028, and Mr. Martin Heimrich managed Work Assignments 1

- 05 and 2

- 05. Mr. Harold Haskew of HH&A was the principal technical investigator for the project, and Mr. Gregory Barton of ATL managed the emissions test laboratory.

### SwRI Final Report 03.14936.05 

## iii CRC E

- 77

- 2b 

## ABSTRACT

This report describes an ongoing investigation into the evaporative emission performance of aging light

- duty vehicl es. The objective of this study was to add additional data to the Coordinating Research Council’s (CRC) E

- 77

- 2 evaporative emission/ permeation test program. This was done to enhance the statistical power of the test program and hence the usability of the data. T he sponsor selected eight vehicles for evaluation on four gasoline fuel blends spanning three levels of vapor pressure (7, 9 and 10 psi) and two levels of ethanol (zero and 10 volume percent designated as E0 and E10, respectively). The selected ve hicles were prepared for test, preconditioned for a minimum of four weeks on the test fuel when the ethanol level was changed, and then subjected to the test sequence. The evaporative emission test sequence consisted of the following four parts:

• Static Permeation Rate Measurement s at 86 and 105 °F (Includes leak checks)

• Dynamic (Running Loss) Permeation and Canister Loss Measurement at 86°F

• Hot Soak (“True” or Net Value) following the Dynamic Test at 86°F

• Three Day Diurnal (65°F to 105°F) Perme ation and Canister Loss Measurement

The E

- 77

- 2b test program was a continuation of the earlier E

- 77 test program. The permeation trends previously shown were again present. The small sample size and limited number of tests preclude making statements abo ut statistical validity, but in general:

• Increasing ethanol content (0% to 10%) increased permeation in the “enhanced” vehicles tested.

• “Near zero” and “zero evap” vehicles were less sensitive (or insensitive) to ethanol level. This may be due to the permeation control materials used to achieve the lower emission levels, or perhaps the limited sample size.

• Increased fuel volatility increased permeation levels for “enhanced” vehicles.

### SwRI Final Report 03.14936.05 

## iv CRC E

- 77

- 2b 

## ACKNOWLEDGEMENTS

The authors would like to recognize the many contributions made by the E

- 77

- 2b Project Panel and CRC. The E

- 77

- 2b CRC Project Panel and CRC staff are identified below:

E

- 77

- 2b CRC Project Panel

Name Company David Brzezinski US Environmental Protection Agency Wendy Clark National Renewable Energy Laboratory Dominic DiCicco Ford Motor Company King Eng Shell Global Solutions (US) Jim Frusti Chrysler LLC Pam Graham Inergy Automotive Benjamin Hancock California Air Resources Board Constance Hart US Environmental Protection Agency Phil Heirigs Chevron Global Downstream Jeff Jetter Honda R&D Americas Inc. Keith Knoll National Renewable Energy Laboratory John Koupal US Environmental Protection Agency David Lax American Petroleum Institute Jeffrey Long California Air Resources Board Hector Maldonado California Air Resources Board Mani Natarajan Marathon Oil Company David Patterson Mitsubishi Motors R&D of America Charles Schleyer ExxonMobil Research & Engineering Jenny Sigelko Chrysler LLC Nakia Simon Chrysler Group LLC James Uihlein Chevron Global Downstream Michael Viola General Motors R&D Center Ken Wright ConocoPhillips

CRC Staff

Name Company Brent Bailey CRC Chris Tennant CRC Jane B e ck C R C

These individuals met on a regular basis throughout the pro gram to discuss the progress and make recommendations. The Steering Committee and CRC contributed significantly to this project.

### SwRI Final Report 03.14936.05 

## v CRC E

- 77

- 2b 

## TABLE OF CONTENTS

Page

FOREWORD

................................ ................................ ................................ ................................ .. ii

ABSTRACT

................................ ................................ ................................ ................................ ... i i i

ACKNOWLEDGEMENTS

................................ ................................ ................................ ........... iv

LIST OF FIGURES

................................ ................................ ................................ ...................... v i i

LIST OF TABLES

................................ ................................ ................................ ....................... v i i i

ACRONYMS

................................ ................................ ................................ ................................ . ix

EXECUTIVE SUMMARY

................................ ................................ ................................ ............. x

1.0 INTRODUCTION

................................ ................................ ................................ ............... 1 1.1 Background

................................ ................................ ................................ .......................... 1 1.2 Period of Performance

................................ ................................ ................................ ......... 2

2.0 TEST PROGRAM OVERVIEW

................................ ................................ ......................... 3 2.1 Vehicle Selection

................................ ................................ ................................ ................. 3 2.2 Vehicle Fleet

................................ ................................ ................................ ........................ 3 2.3 Test Fuels

................................ ................................ ................................ ............................. 5 2.4 Adaption Period for Test Fuel Changes

................................ ................................ ............... 5

3.0 DISCUSSION OF TEST RESULTS

................................ ................................ ................... 6 3.1 Results

................................ ................................ ................................ ................................ .. 6 3.1.1 Static Permeation Rate ( Constant Temperature ( 86°F ) )

................................ ..................... 9 3.1.2 Static Permeation Rate ( Constant Temperature ( 1 05°F ) )

................................ ................... 9 3.1.3 Dynamic (Running Loss) Permeation

................................ ................................ ................ 10 3.1.4 Hot Soak ("True Hot Soak") Permeation Rate

................................ ................................ .. 1 1 3.1.5 Diurnal Permeation Performance

................................ ................................ ..................... 1 2 3.1.6 Temperature Impact on Steady

- State Permeation

................................ ............................. 1 5 3.1.7 Special Cases: Fuel System Leak u nder Pressure

................................ ............................. 1 5 3.1.8 Carbon Canister Breakthrough

................................ ................................ ......................... 1 9 3.2 Speciation

................................ ................................ ................................ ........................... 20 3.3 Reactivity

................................ ................................ ................................ ........................... 2 1 3.4 Summary of Findings and Results

................................ ................................ ..................... 2 8 3.5 Lo oking Ahead

................................ ................................ ................................ ................... 2 8

### SwRI Final Report 03.14936.05 

## vi CRC E

- 77

- 2b 

## TABLE OF CONTENTS (CONT'D)

APPENDICES No. of Pages

A

- E

- 77 TEST CONCEPT AND THEORY

................................ ................................ ............. 5 B

- TEST PROCEDURES

................................ ................................ ................................ ......... 9 C

- FUEL INSPECTIONS

................................ ................................ ................................ ......... 2 D

- SUMMARY OF E

- 77

- 2b PROGRAM TEST RESULTS AND INDIVIDUAL VEHICLE EVAPORATIVE TEST RESULTS

................................ ................................ . 2 9 E

- COMPLETE SPECIATION RESULTS

– ALL E

- 77

- 2b VEHICLES

........................... 262

### SwRI Final Report 03.14936.05 

## vii CRC E

- 77

- 2b 

## LIST OF FIGURES

Figure Page

1 Period of Performance

................................ ................................ ................................ ...... 2

2 86°F Static Performance

................................ ................................ ................................ ... 9

3 105°F Static Performance

................................ ................................ ............................... 10

4 Running Loss Performance

................................ ................................ ............................. 1 1

5 True Hot Soak Performance

................................ ................................ ............................ 1 2

6 Day One Diurnal Performance

................................ ................................ ........................ 1 3

7 Day Two Diurnal Performance

................................ ................................ ....................... 1 3

8 Day Three Diurnal Performance

................................ ................................ ..................... 1 4

9 Total (3 Day) Diurnal Performance

................................ ................................ ................ 1 4

10 Temperature Effect on Static Permeation

................................ ................................ ....... 1 5

11 Vehicle 220b Static Performance

................................ ................................ .................... 1 6

12 Vehicle 221b Static Performance

................................ ................................ .................... 1 6

13 Canister Breakthrough

................................ ................................ ................................ .... 1 9

### SwRI Final Report 03.14936.05 

## viii CRC E

- 77

- 2b 

## LIST OF TABLES

Table Page

1 E

- 77

- 2b Fleet Composition

................................ ................................ ............................... 3

2 E

- 77 Composite Fleet

– All Programs

................................ ................................ .............. 4

3 Test Fuel Target Values

................................ ................................ ................................ .... 5

4 Enhanced Evap (Tier 1) Certified Data

................................ ................................ ............ 7

5 Near Zero (Tier 2) Evap Certified Data

................................ ................................ ............ 8

6 Zero Evap Certified Data

................................ ................................ ................................ .. 8

7 Vehicle 220b Data Summary

................................ ................................ .......................... 1 7

8 Vehicle 221b Data Summary

................................ ................................ .......................... 1 8

9 Speciation Results

– Vehicle 210c

– 72

- Hour Diurnal Test

................................ ........... 20

10 Ma ss Sorted Speciation Results

– Vehicle 210c

– 72

- Hour Diurnal Test

...................... 2 1

11 Reactivity Results

................................ ................................ ................................ ........... 2 3

12 Vehicle Reactivity Summaries

– Vehicle 206b

................................ .............................. 2 4

13 Vehicle Reactivity Summaries

– Vehicle 208b

................................ .............................. 2 4

14 Vehicle Reactivity Summaries

– Vehicle 209 b

................................ .............................. 2 5

15 Vehicle Reactivity Summaries

– Vehicle 210b

................................ .............................. 2 5

16 Vehicle Reactivity Summaries

– Vehicle 213b

................................ .............................. 2 6

17 Vehicle Reactivity Summaries

– Vehicle 220b

................................ .............................. 2 6

18 Vehicle Reactivity Summaries

– Vehicle 221b

................................ .............................. 2 7

19 Vehicle Reactivity Summaries

– Vehicle 222b

................................ .............................. 2 7

### SwRI Final Report 03.14936.05 

## ix CRC E

- 77

- 2b 

## ACRONYMS

API

................. American Petroleum Institute ARB

............... California Air Resources Board ASTM

............ A STM International

– a standards organization ATL

................ Automotive Testing Laborator y, Inc. AQIRP

............ Air Quality Improvement Research Program (Auto/Oil) CAS

................ Chemical Abstract Service CFR

................ Code of Federal Regulations CRC

................ Coordinating Research Council, Inc. CVS

................ Constant Volume Sampler DHB

............... Diurnal Heat Build DVPE

............. Dry Vapor Pressure Equivalent EPA

................ (US) Environmental Protection Agency FID

................. Flame Ionization Detector FTTP

.............. Fuel Tank Temperature Profile GC

.................. Gas Chromatograph HC

.................. Hydrocarbon HH&A

............ Harold Haskew & Associates LA

- 92

............. Unified Driving Cycle MIR

................ Maximum Incremental Reactivity MOVES

.......... Motor Vehicle Emissions Simulator

– EPA model to simulate emissions from mobile so urces MTBE

............ Methyl Tertiary Butyl Ether NBR

............... Nitrile Rubber or Acrylonitrile Butadiene Rubber OBD2

............. On

- Board Diagnostics Level 2 ORVR

............ Onboard Refueling Vapor Recovery PFI

.................. Port Fuel Injection psi

................... Pounds p er Square Inch PZEV

.............. Partial Zero Emission Vehicle (Calif ornia) RL SHED

....... Running Loss Sealed Housing for Evaporative Determination RVP

................ Reid Vapor Pressure SAE

................ Society of Automotive Engineers SHED

............. Sealed Housing for Evaporative Determination SwRI

.............. South w est Research Institute TEFVO

........... Transient Emission Following Vehi cle Operation (True Hot Soak) THC

................ Total Hydrocarbon VOC

............... Volatile Organic Compound VT SHED

....... Variable Temperature Sealed Housing for Evaporative Determination

### SwRI Final Report 03.14936.05 

## x CRC E

- 77

- 2b 

## EXECUTIVE SUMMARY

This report describes an ongoing investigation into the evaporative emission performance of aging light

- duty vehicles. Evaporative emissions are, in this context, the fuel

- related emissions that escape from the vehicle at rest and during vehicle operation (omitting those that come from the tailpipe). The CRC E

- 77

- 2b Evaporative E mission Test Program, the subject of this report, evolved from the “CRC E

- 77 Pilot Study” and the recently published CRC E

- 77

- 2 report, “Enhanced Evaporative Emissions Vehicles.” This series of studies used test procedures and insight borrowed from other CRC test programs, including E

- 65, “Fuel Permeation from Automotive Systems.”

The objective of this study was to add additional data to the Coordinating Research Council ’s (CRC) E

- 77

- 2 permeation test program. This was done to enhance the statistical po wer of the test program and hence the usability of the data. T he sponsor selected eight vehicles for evaluation on four gasoline fuel blends spanning three levels of vapor pressure (7, 9 and 10 psi) and two levels of ethanol (zero and 10 volume percent de signated as E0 and E10, respectively). The selected vehicles were prepared for test, preconditioned for a minimum of four weeks on the test fuel when the ethanol level was changed, and then subjected to the test sequence. The evaporative emission test sequ ence consisted of the following four parts:

• Static Permeation Rate Measurement at 86°F and 105°F (Includes leak checks)

• Dynamic (Running Loss) Permeation and Canister Loss Measurement at 86°F

• Hot Soak (“True” or Net Value) following the Dynamic Test at 86°F

• Three Day Diurnal (65°F to 105°F) Permeation and Canister Loss Measurement

Eight vehicles, each selected to represent a high volume nationwide model, were tested under this work assignment:

• Five of the vehicles were owned by CRC and were approved for use in this test program. They include: 2002 Nissan Altima, 2002 Chevy Trailblazer, 2004 Chrysler Stratus, 2004 Chevy Impala, and 2004 Dodge Ram Pickup.

• Three vehicles were leased for the du ration of the testing. The vehicle types were two enhanced evaporative emission certified models (2000 Chevrolet Malibu, and 2000 Mitsubishi Galant) and one PZEV (2004 Ford Focus).

Each vehicle started the evaluation with a four week preconditioning on 10 psi E10 fuel, and then ran the 10 psi E10 evaporative emission test sequence (static, running loss, hot soak, and diurnal). The four week period is thought to be appropriate for the permeation rate to re

stabilize following the fuel change. After valid ation and committee approval of these data, the fuel was changed to a lower vapor pressure (7 psi) E10 fuel, allowed to re

- stabilize for up to one week, and then re

- evaluated on the emission test sequence. The shorter stabilization period is thought approp riate to allow the system to respond to a fuel with equivalent ethanol content but lower vapor pressure.

The fuel comparisons selected for this project were two levels of ethanol content with vapor pressure varied as listed on the following page

.

### SwRI Final Report 03.14936.05 

## xi CRC E

- 77

- 2b 

## TEST FU EL TARGET VALUES

Fuel Reid Vapor Pressure

E0 7 psi, 9 psi E10 7 psi, 10 psi

It seemed logical to combine as much of the previous E

- 77 data with the newly gathered data into the discussion of results as possible. The "enhanced emission" vehicles gave, on average, increasing permeation rates with increasing volatility and with increasing ethanol level. The small sample of “near zero” emission vehicles did not indicate the same trend, except for the diurnal test r esults. The authors suggest that this might be due to the permeation emission control materials used in the newer vehicles, or it may be an artifact of the smaller sample size.

The project plan included the “speciation” of the evaporative emission result s for each of the vehicles and test fuels. A sample of the ambient hydrocarbon ( HC ) concentration in the VT

SHED was collected in a Tedlar TM 

## bag during each test, and later analyzed for HC species using the laboratory’s Varian TM 

## chromatograph, and the “Auto

- Oil Test Procedure.” The results of this “speciation” allowed the calculation of the average reactivity of the permeate for each of the vehicles and fuels.

The E

- 77

- 2b test program was a continuation of the earlier E

- 77 tes t program which added eight vehicles to be tested on four fuels to increase the size of the knowledge base. The permeation trends previously shown were again present. The small sample size and limited number of tests preclude making statements about stati stical validity, but in general:

• Increasing ethanol content (0% to 10%) increased permeation in the " enhanced " vehicles tested.

• " Near zero " and " zero evap " vehicles were less sensitive (or insensitive) to ethanol level. This may be due to the materials used to achieve the lower emission levels, or perhaps the limited sample size.

• Increased fuel volatility increased permeation levels for " enhanced " vehic les.

• The lower emitting " near zero " and " zero evap " vehicles did not exhibit a clear trend with increasing volatility level. Again, this may be due to the permeation control materials used for the vehicles tested, or the small sample size.

• " Near zero " and " zero evap " vehicles had lower emissions than the " enhanced " vehicles.

• The two vehicles identified with " leaks " were not included in the analysis for the permeation trends, but were interesting in that they may suggest deterioration with time for the vehicles at eight or more years of age.

### SwRI Final Report 03.14936.05 

## 1 of 28 CRC E

- 77

- 2b 

## 1.0 INTRODUCTION

1.1 Background

This report describes an ongoing investigation into the evaporative emission performance of aging light

- duty vehicles. Evaporative emissions are, in this context, the fuel

- related emissions that escape from the vehicle at rest and during vehicle operation (omitting those that come from t he tailpipe). The CRC E

- 77

- 2b Evaporative Emission Test Program, the subject of this report, evolved from the “CRC E

- 77 Pilot Study” and the recently published CRC E

- 77

- 2 report, “Enhanced Evaporative Emissions Vehicles.” This series of studies used test procedures and insight borrowed from other CRC test programs, including E

- 65, “Fuel Permeation from Automotive Systems.” Three reports preceded this study:

• A New Approach to Modeling On

- Road Vehicle Evaporative Emissions (A report to EPA by HH&A

- Measure “Mechanisms” June 2
, 2005)

• Vehicle Evaporative Emission Mechanisms: A Pilot Stud y

- CRC E

- 77 (Ten Vehicle Concept Demonstration

- Published June 24, 2008)

• Enhanced Evaporative Emission Vehicles

- CRC E

- 77

- 2 (Eight vehicle continuatio n of the pilot study

– Published April 9, 2010 )

The test work for all these programs was conducted at the Automotive Testing Laboratory, Inc. (ATL) facilities in Mesa, AZ 1

1 

### ATL, 263 S. Mulberry Street, Mesa, AZ (480) 649 7906, 

## , where unique experience and facilities exist to conduct evaporative emission program s of this nature.

The objective of this study was to add additional data to the Coordinating Research Council (CRC) E

- 77

- 2 permeation test program. This was done to enhance the statistical power of the test program and hence the usability of the data. T he sponsor selected eight vehicles for evaluation on four gasoline fuel blends spanning three levels of vapor pressure (7, 9 and 10 psi) and two levels of ethanol (zero and 10 volume percent designated as E0 and E10, respectively). The selected vehicles w ere prepared for test, preconditioned for a minimum of four weeks on the test fuel when the ethanol level was changed, and then subjected to the test sequence. The evaporative emission test sequence consisted of the following four parts:

• Static Permeat ion Rate Measurement at 86°F and 105°F (Includes leak checks)

• Dynamic (Running Loss) Permeation and Canister Loss Measurement at 86°F

• Hot Soak (“True” or Net Value) following the Dynamic Test at 86°F

• Three Day Diurnal (65°F to 105°F) Permeation a nd Canister Loss Measurement

While the main objective of this project was to measure the evaporative emission performance of the selected vehicles, a second objective was to develop and refine the test p rocedures and analysis methods. We have included co mprehensive documentation of these test procedures in Appendix A ( E

- 77 Test Concept and Theory ) and Appendix B ( Test Procedures ).

www.ATL

- AZ.com , Greg Barton, President

### SwRI Final Report 03.14936.05 

## 2 of 28 CRC E

- 77

- 2b 

## Each vehicle started the evaluation with a four week preconditioning on 10 psi E10 fuel, and then ran the 10 psi E10 evapora tive emission test sequence (static, running loss, hot soak, and diurnal). The four week period is thought to be appropriate for the permeation rate to re

stabilize following the fuel change. After validation and committee approval of these data, the fuel was changed to a lower vapor pressure (7 psi) E10 fuel, allowed to re

- stabilize for up to one week, and then re

- evaluated on the emission test sequence. The shorter stabilization period is thought appropriate to allow the system to respond to a fuel with equivalent ethanol content but lower vapor pressure.

Once the ethanol fuel test results were approved, the vehicle was refueled with 9 psi E0 fuel, and again subjected to a four week minimum re

- stabilization. The evaporative performance test sequence was then repeated, and repeated again with a 7 psi E0 fuel after a one week stabilization period.

1. 2 Period of Performance

The vehicle emission testing started during the week of November 17, 2008. Procedural errors were identified , and the data was discarded. T he vehicle testing was restarted in January 2009 with procedural corrections, and continued through October of 2009 . No erroneous data

were included in the project data set. The period of performance by vehicle number is given in Figure 1. Fifty

- four (54) weekly progress reports were made.

FIGURE 1. PERIOD OF PERFORMANCE 206b 208b 209b 210b 213b 220b 221b 222bVehicle Test ID 

## E

**- 77** 

**- 2b Testing Period of Vehicles** 

### SwRI Final Report 03.14936.05 

## 3 of 28 CRC E

- 77

- 2b 

## 2.0 TEST PROGRAM OVERVIEW

2.1 Vehicle Selection

Eight vehicles, each selected to represent a high volume nationwide model, were tested under this work assignment:

**•** Five of the vehicles were owned by CRC and were approved for use in this test program. They include: 2002 Nissan Altima, 2002 Chevy Trailblazer, 2004 Chrysler Stratus, 2004 Chevy Impala, and 2004 Dodge Ram Pickup.

**•** Three vehicles were leased for the duration of the testing. The vehicle types were two enhanced evaporative emission certified models (2000 Chevrolet Malibu, and 2000 Mitsubishi Galant) and one PZEV 2



## All candidate vehicles for this pr ogram received a thorough inspection before beginning the test preparation sequence. This included inspection of the engine, transmission, axles, exhaust system and tires, and verification that no OBD2 faults were present.

Each candidate vehicle was checked at the start of the test program to make sure that there were no system leaks, to verify system purge was present, and to generally establish that the vehicles were safe to operate. Each vehicle had to be registered and insured for road operation t o accomplish the many road preconditioning drives.

2.2 Vehicle Fleet

Table 1 below lists and describes the eight vehicles studied in this program. The odometers (Odo.) in the following tables are the indicated odometer readings at the time of the vehicle ’s initial inspection into the testing program.

TABLE 1. E

- 77

- 2b FLEET COMPOSITION (2004 Ford Focus).

2 

### Partial Zero Emission Vehicle

– a California certification class with very low exhaust emission and a “zero evaporative emission system.” Fuel Tank Veh Evap Standards Tank Plastic No. Yr Make Model Odo. Evap Family (all are ORVR) Size Metal

220b 2000 Chevrolet Malibu 69,367 YGMXR0124919 Tier 1 14.2 Plastic 221b 2000 Mitsubishi Galant ES 97,875 YDSXR0165A1F Tier 1 16.3 Plastic 206b 2002 Nissan Altima 110,399 2NSXR0120RCB Tier 1 20.0 Plastic 208b 2002 Chevrolet Trailblazer 60,233 2GMXR0175922 Tier 1 18.6 Plastic 209b 2004 Chrysler Stratus 63,778 4CRXR0130GBA Tier 1 16.0 Plastic 210b 2004 Chevrolet Impala 63,157 4GMXR0124919 Near Zero 17.0 Plastic 213b 2004 Dodge Ram 1500 99,372 4CRXR0218GDH Near Zero 35.0 Plastic 222b 2004 Ford Focus ZX3 71,633 4FMXR0120GCX Zero Evap 14.0 Metal

### SwRI Final Report 03.14936.05 

## 4 of 28 CRC E

- 77

- 2b 

## As stated previously , the E

- 77

- 2b program added eight vehicles to the E

- 77 program database. Table 2 below lists the “composite E

- 77 vehicle fleet,” sorted by vehicle model year, with the 2b vehicles highlighted in light blue

. Not all data from the composite fleet are usable for later analysis, as the use of the INNOVA analyzer for identification of methanol and refrigerant (R

- 134a) leaks did not become available until the latter part of the Pilot Program. Pre INNOVA data tests that were not used in the analysis are indicated with the yellow shading.

TABLE 2. E

- 77 COMPOSITE FLEET

– ALL PROGRAMS

___________________________ Light blue

– E

- 77

- 2b program vehicles Yellow

– Pre

- INNOVA tests not used in the analysis Tank Fuel Tank Veh Evap Standards Size Plastic No. Yr Make Model Odo. Evap Family gal. Metal 003 1992 Honda Accord 71,129 92FG Tier 0 17.0 Metal 010 1992 Toyota Camry 162,838 EV-E Tier 0 18.5 Metal 009 1995 Plymouth Neon 106,220 SCR1050AYM02 Tier 0 11.2 Metal 001 1996 Chevrolet S-10 68,420 TGM1082AYMEA Tier 1 19.0 Metal 006 1996 Chevrolet Cavalier 112,768 TGM1089AYMEA Tier 1 15.3 Metal 007 1996 Chevrolet Cavalier 113,125 TGM1089AYMEA Tier 1 15.3 Metal 008 1996 Ford Explorer 114,822 TFM1120AYMED Tier 1 21.0 Metal 202b 1996 Ford Taurus 86,538 TFM1115AYMEB Tier 1 16.0 Metal 216b 1996 Ford Taurus 88,820 TFM1115AYMEB Tier 1 16.0 Metal 004 1999 Dodge Grand Caravan SE 98,765 XCRXE0101G2A Tier 0 20.0 Plastic 204b 1999 Honda Accord 100,418 XHNX R 0130AAA Tier 1 17.1 Metal 002 2000 Toyota Tacoma 80,557 YTYXE0095AE0 Tier 1 15.1 Metal 220b 2000 Chevrolet Malibu 69,367 YGMXR0124919 Tier 1 14.2 Plastic 221b 2000 Mitsubishi Galant ES 97,875 YDSXR0165A1F Tier 1 16.3 Plastic 205b 2001 Toyota Corolla 92,047 1TYX R 0115AK1 Tier 1 13.2 Metal 207b 2001 Dodge Caravan 92,740 1CRX R 0165XAA Tier 1 20.0 Plastic 206b 2002 Nissan Altima 2NSX R 0120RCB Tier 1 20.0 Plastic 208b 2002 Chevrolet Trailblazer 60,233 2GMX R 0175922 Tier 1 18.6 Plastic 209b 2004 Chrysler Stratus 63,778 4CRX R 0130GBA Tier 1 16.0 Plastic 210b 2004 Chevrolet Impala 63,157 4GMX R 0124919 Tier 2 17.0 Plastic 211b 2004 Toyota Camry LE 43,588 4TYX R 0130A11 Tier 2 18.5 Plastic 213b 2004 Dodge Ram 1500 99,372 4CRX R 0218GDH Tier 2 35.0 Plastic 214b 2004 Ford Escape 40,188 4FMX R 0110BBE Tier 2 16.0 Plastic 215b 2004 Toyota High Lander 88,693 4TYX R 0165PZ1 Tier 2 19.1 Plastic 222b 2004 Ford Focus ZX3 71,633 4FMXR0120GCX Zero Evap 14.0 Metal 212b 2006 Ford Taurus 28,354 6FMX R 0185GAK Tier 2 18.0 Metal 005 2007 Ford Taurus 6,916 7FMXR0185GAR Tier 2 18.0 Metal 

### E-77 Composite Fleet - All Programs

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## 2.3 Test Fuels

The fuel comparisons selected for this project were two levels of ethanol content with vapor pressure varied as listed in Table 3.

TABLE 3. TEST FUEL TARGET VALUES

7 psi 9 psi 10 psi E0 X X E10 X X

CRC had fuels remaining from Project E

- 74 in quantities sufficient to conduct this program, e.g., 7 psi E0 and E10. Inspection records of the base fuels are located in Appendix C
, using their E

- 74b identifications, fuels 6 and 7
, respectively. The nominal 7 psi fuels, both E0 and E10, were locally blended with commercial butane to make the higher volatility 9 psi E0, and the 10 psi E10. The blends were done in drum batches, approximately 50 gallons at a time, by adding small amoun ts of butane, circulating for a brief period, then sampling and determining the new volatility with a “Grabner” 3

3 

## instrument, using test procedures described in ASTM D5191. The higher (10 psi instead of 9 psi) vapor pressure of the E10 fuel was specified because many localities permit “splash blending” of ethanol to gasoline and allow a 1 psi exemption for their vapor pressure limits.

2.4 Adaption Period for Test Fuel Changes

Many areas of the United States were required to use an oxygenated fuel to imp rove vehicle emissions, especially during the summer season. While Methyl Tertiary Butyl Ether (MTBE) was the most common oxygenate, ethanol was also used. Project E

- 65 demonstrated that the permeation of vehicle fuel systems increased with the use of fu els containing ethanol, compared to fuels with MTBE, or no oxygenate. Project E

- 65 also demonstrated that if ethanol had been previously used, and the fuel replaced with a non

- ethanol blend, it could take two to four weeks for the ethanol increase to diss ipate (the “ethanol carry

- over effect”).

The protocols adopted for this test program were to require a minimum of four weeks of vehicle exposure to a new fuel when first introducing ethanol to the vehicle, and the same period of time when moving to an ethanol

- free (E0) fuel.

www.grabner

- instruments.com
, MINIVAP VPS / VPSH Vapor Pressure Tester

. The portable MINIVAP VPS and VPSH vapor pressure testers are the worldwide accepted standard instruments for the determination of the vapor pressure of gasoline according to ASTM D5191, ASTM D6377, ASTM D6378 and EN 13016 1+2.

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## 3.0 DISCUSSION OF TEST RESULTS

3.1 Results

The results from the E

- 77

- 2b vehicle tests are summarized in Appendix D

. It seemed logical to combine as much of the previous E

- 77 data with the newly gathered data into the discussion of results as possible. Not all of the data w ere comparable, and t he following summary is offered to explain the various choices.

**•** While not part of t he contracted E

- 77 Pilot Study , the laboratory found that the vehicle tests needed to be corrected for the presence of the non

- fuel contributors methanol and the refrigerant R134a. The INNOVA analyzer that the laboratory purchased and used to make these corrections was not available for testing until vehicle 006 . Of the remaining vehicles t ested, only 006 and 008 were Tier 1 models ( v ehicle 007 was an implanted leak test, and vehicles 009 and 010 were pre

- enhanced, Tier 0 models)

. The Pilot Study only ran a one day diurnal, rather than the three day test that became the norm.

**•** The 105oF static tests were first introduced in the E

- 77

- 2b test sequence to enhance the evidence that permeation is directly affected by temperature. The earlier test programs did not have that information.

Emission results are presented below for each of the four evaporative emission elements (static, running loss, hot soak and diurnal), with data averaged for selected and representative vehicles tested in the E

- 77, E

- 77

- 2 and E

- 77

- 2b programs that were tested on the four fuels used in this (2b) study. A list of the data used in the following plots is tabulated in Tables 4, 5, and 6.

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## TABLE 4. ENHANCED EVAP (T ier 1) CERTIFIED DATA

86 Static 105 Static RL Tru-HS Veh. Fuel mg/hr mg/hr mg/hr mg/hr Day 1 Day 2 Day 3 Total

06 7E0

--- --- --- --- 375.6

--- --- --- 9E0

--- --- --- --- 468.5

--- --- --- E-77 08 7E0

--- --- --- --- 133.1

--- --- --- 9E0

--- --- --- --- 150.4

--- --- --- 204 10E10 84.3

--- 316.4 0.4 1547.9 1779.9 1771.1 5099.0 7E10 66.4

--- 287.9 29.7 1260.2 1165.2 1165.2 3590.6 9E0 33.8

--- 249.2 44.3 628.3 581.0 577.0 1786.4 7E0 12.9

--- 222.6 18.7 367.2 287.7 293.6 948.5 205 10E10 41.6

--- 191.6 29.5 1794.1 1730.9 1741.7 5266.6 7E10 59.6

--- 232.8 71.9 1783.4 1715.0 1523.9 5022.3 9E0 19.5

--- 103.1 1.0 499.5 481.0 507.2 1487.8 7E0 9.9

--- 67.1 0.0 383.0 365.4 367.0 1115.4 207 10E10 78.7

--- 858.1 237.7 1406.4 1264.4 1223.7 3894.5 7E10 64.4

--- 812.2 122.2 1086.5 812.0 823.6 2722.0 9E0 32.5

--- 833.9 5.8 406.4 337.3 308.0 1051.7 E-77-2 7E0 40.1

--- 842.5 0.0 397.5 302.6 268.9 969.1 214 10E10 24.4

--- 133.1 57.4 492.0 839.4 11373.8 12705.2 7E10 23.9

--- 105.7 32.9 524.2 397.4 394.4 1315.9 9E0 10.7

--- 96.7 52.1 455.9 358.5 1101.7 1916.1 7E0 25.2

--- 36.3 3.3 494.3 319.0 281.5 1094.8 215 10E10 10.4

--- 71.9 1.6 319.2 260.2 237.0 816.4 7E10 12.2

--- 97.9 0.0 224.7 231.7 267.5 724.0 9E0 8.5

--- 81.1 25.1 202.1 165.9 176.3 544.3 7E0 8.7

--- 79.7 22.5 248.3 294.1 288.8 831.1
206b 10E10 124.9 314.1 546.5 165.1 2776.6 31004.6 43028.2 76809.3 7E10 149.3 307.9 436.7 174.9 2582.6 2258.5 2144.0 6985.0 9E0 61.1 178.8 365.6 102.5 1500.0 1285.6 1250.8 4036.4 7E0 52.0 118.1 245.1 68.8 1171.9 931.2 890.3 2993.3 208b 10E10 37.5 61.2 329.5 36.0 795.0 561.4 495.8 1852.2 7E10 27.2 51.8 254.7 77.3 780.6 510.4 449.4 1740.5 9E0 37.2 55.0 228.0 37.9 778.0 567.2 519.4 1864.6 E-77-2b 7E0 24.8 64.5 124.9 75.0 422.1 419.4 476.0 1317.5 209b 10E10 28.8 73.3 323.6 113.7 535.5 423.5 475.5 1434.5 7E10 28.6 54.1 205.7 24.5 383.1 349.1 323.5 1055.7 9E0 23.4 29.5 144.4 5.0 327.8 250.5 224.3 802.6 7E0 16.8 28.8 166.2 16.8 354.1 249.7 218.1 821.9

86 Static 105 Static RL Tru-HS Fuel mg/hr mg/hr mg/hr mg/hr Day 1 Day 2 Day 3 Total 7psi E0 23.8 70.5 223.1 25.6 434.7 396.1 385.5 1261.4 9psi E0 28.3 87.8 262.7 34.2 541.7 503.4 583.1 1686.2 7psi E10 54.0 137.9 304.2 66.7 1078.2 929.9 886.4 2894.5 10psi E10 53.8 149.5 346.3 80.2 1208.3 4733.0 7543.4 13484.7 Diurnal Emissions- mg

Diurnal Emissions- mg 

### Average Values for the Tier 1 Vehicle Tests

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## TABLE 5. NEAR ZERO (T ier 2) EVAP CERTIFIED DATA

TABLE 6. ZERO EVAP CERTIFIED DATA

An observation is present in the following analysis. The "enhanced emission" vehicles gave, on average, increasing permeation rates with increasing volatility and with increasing ethanol level. The small sample of “near zero” emission vehicles did not in dicate the same trend, except for the diurnal test results. The authors suggest that this might be due to the permeation control materials used in the newer vehicles, or it may be an artifact of the smaller sample size. 86 Static 105 Static RL Tru-HS Veh. Fuel mg/hr mg/hr mg/hr mg/hr Day 1 Day 2 Day 3 Total

211 10E10 19.9 138.3 0.0 337.0 226.8 217.9 781.6 7E10 9.4 56.3 13.8 243.8 183.8 184.3 611.9 9E0 10.1 83.7 15.3 130.3 115.8 100.6 346.7 7E0 9.1 104.6 0.7 207.1 100.2 87.4 394.7 E-77-2 212 10E10 10.6 148.9 0.0 124.3 87.9 102.8 315.1 7E10 21.8 201.2 0.0 184.8 100.2 75.8 360.8 9E0 3.2 115.8 0.4 100.5 70.8 57.4 228.7 7E0 0.9 184.5 1.8 101.6 71.2 57.0 229.7
210b 10E10 19.9 70.1 147.5 60.6 486.5 458.3 441.3 1386.1 7E10 29.9 51.9 218.3 61.8 445.1 388.3 359.1 1192.5 9E0 21.2 33.5 171.1 19.8 407.8 377.4 358.3 1143.4 7E0 18.7 35.5 216.0 49.0 270.6 266.6 221.1 758.3 E-77-2b 213b 10E10 39.2 106.8 130.9 0.9 650.6 615.4 700.7 1966.7 7E10 29.6 82.2 243.1 60.5 602.8 577.7 588.9 1769.4 9E0 14.7 34.5 203.1 14.5 346.3 328.4 292.8 967.5 7E0 21.1 35.3 135.1 12.2 357.8 283.3 276.5 917.5

86 Static 105 Static RL Tru-HS Fuel mg/hr mg/hr mg/hr mg/hr Day 1 Day 2 Day 3 Total 7psi E0 12.5 35.4 160.1 15.9 234.2 180.3 160.5 575.1 9psi E0 12.3 34.0 143.4 12.5 246.2 223.1 202.3 671.6 7psi E10 22.7 67.0 179.7 34.0 369.1 312.5 302.0 983.6 10psi E10 22.4 88.4 141.4 15.4 399.6 347.1 365.7 1112.4 Diurnal Emissions- mg



### Average Values for Tier 2 Vehicle Tests Diurnal Emissions- mg

86 Static 105 Static RL Tru-HS Veh. Fuel mg/hr mg/hr mg/hr mg/hr Day 1 Day 2 Day 3 Total

222b 7E0 3.38 6.36 128.79 5.44 58.6 39.0 38.8 136.4 9E0 3.10 5.75 45.55 0.00 77.4 41.9 57.9 177.2 E-77-2b 7E10 12.10 16.29 61.68 0.00 99.6 104.0 84.0 287.6 10E10 3.75 7.36 73.08 0.0 104.1 79.7 73.4 257.2 Diurnal Emissions- mg

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## 3.1.1 Static Permeation Ra te (Co nstant Temperature (86°F))

Average permeation rate s are compared b y fuel specification for three vehicle groups : “enhanced,” “near zero
, ” and “zero evap” evaporative emissions.

Figure 2 shows the 86 oF static permeation rate performance for the average of eight “enhanced” and four “near zero” vehicles tested on the four fuels in this test program. This composite result confirms the trend shown in the earlier programs of increasing permeation rate with increasing ethanol content and increasing vapor pres sure of the fuel. The “zero evap” vehicle is shown only for reference. Due to a sample size of only one, no statistical significance can be implied.

FIGURE 2. 86°F STATIC PERFORMANCE

3.1.2 Static Permeation Rate (Constant Temperature (105°F))

Average permeation rate s are compared b y fuel specification for two vehicle groups: “enhanced” and the “near zero” evaporative emissions at an elevated test temperature (105oF). 0 10 20 30 40 50 60

7psi E0 9psi E0 7psi E10 10psi E10Static Permeation Rate-mg/hr

Test Fuel 

## 86 o F Static Performance All E77 Programs

Enhanced

- 8 Vehicles
Near Zero

- 4 Vehicles Zero Evap

- 1 Vehicle

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## Figure 3 shows the 105oF static permeation rate performance for the average of three “enhanced” and two “near zero” vehicles tested on the four fuels in this test program. Again, this composite result confirms the trends shown in the earlier programs of increasing permeation rate with increasing ethanol content and increasing va por pressure of the fuel for the enhanced vehicles, albeit at a higher test temperature. The “zero evap” vehicle is shown for reference.

FIGURE 3. 105°F STATIC PERFORMANCE

3.1.3 Dynamic (Running Loss) Permeation

In a similar presentation, Figure 4 shows the average “Running Loss” permeation rate for the vehicle types and the fuels tested. “Running Loss” permeation as described here is the permeation measured during a “cold start” 48

- minute drive in a Running Loss Sealed Housing for Evaporative Deter mination (RL

- SHED) at 86°F.

Figure 4 presents the running loss permeation rates for eight “enhanced” and four “near zero” vehicles tested. The “enhanced” vehicles displayed a similar increase in permeation with ethanol content and vapor pressure as was s een in the static tests, but the “near zero” vehicles appear to be insensitive within the small sample size available (4). 0 20 40 60 80 100 120 140 160

7psi E0 9psi E0 7psi E10 10psi E10Static Permeation Rate-mg/hr

Test Fuel 

## 105 o F Static Performance All E77 Programs

Enhanced

- 3 Vehicles
Near Zero

- 2 Vehicles Zero Evap

- 1 Vehicle

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## FIGURE 4. RUNNING LOSS PERFORMANCE

3.1.4 Hot Soak (“True Hot Soak”) Permeation

T he Hot Soak emissions as defined in this report are the net increase in permeation rates following vehicle operation. The mass increase was measured in the SHED for one hour immediately following vehicle operation, and the previously measured static (or n ormal) permeation at the same temperature was subtracted. Although this is not the traditional CFR definition, the justification for the new definition is shown in Appendix B (the "True" Hot Soak, page B

- 7) of this report.

The “True Hot Soak” performance for the average of the vehicles is summarized in Figure 5. There was a large increase (~2.5:1) in the hot soak value with the E10 fuel compared to the E0 for the “enhanced” vehicles, but no clear trend is present for the “near zero” vehicles due in part to the small sample size and relatively low levels attained. There may be an indication that hot soak permeation may decrease on the Near Zero vehicles with increasing vapor pressure. 0 50 100 150 200 250 300 350 400

7psi E0 9psi E0 7psi E10 10psi E10Running Loss Permeation Rate-mg/hr

Test Fuel 

## Running Loss Performance All E77 Programs

Enhanced

- 8 Vehicles
Near Zero

- 4 Vehicles Zero Evap

- 1 Vehicle

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## FIGURE 5. TRUE HOT SOAK PERFORMANCE

3.1.5 Diurnal Permeation Performance

Figure 6 present s the diurnal permeation results for the first day of the three

- day diurnal test (65° to 105°F). A similar performance trend can be made for days 2 and 3, and for the total emission for all three days

Figure 6 shows that t he average day 1 diurnal permeation for the “e nhanced ” v ehicles increased as ethanol content increased. The “near zero” vehicles showed a slight increasing higher trend with increasing volatility. The one “zero evap” vehicle run shows considerably lower diurnal performance.

Figures 7
, 8, and 9 display the diurn al performance obtained for days two, three, and the total of the 3

- day diurnal tests run (E77

- 2 and E77

- 2b). The trends observed for day 1 hold true for the entire test. The averages for the 10 psi E10 fuel are highly dominated by one vehicle. 0 10 20 30 40 50 60 70 80 90

7psi E0 9psi E0 7psi E10 10psi E10True Hot Soak Permeation Rate-mg/hr

Test Fuel 

## True Hot Soak Performance All E77 Programs

Enhanced

- 8 Vehicles
Near Zero

- 4 Vehicles Zero Evap

- 1 Vehicle

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## FIGURE 6. DAY ONE DIURNAL PERFORMANCE

FIGURE 7. DAY TWO DIURNAL PERFORMANCE 0 200 400 600 800 1000 1200 1400

7psi E0 9psi E0 7psi E10 10psi E10Diurnal Permeation Rate-mg/day

Test Fuel 

### Day 1 Diurnal Performance All E77 Programs

Enhanced

- 8/10 Vehicles
Near Zero

- 4 Vehicles Zero Evap

- 1 Vehicle 8 Vehicles

8 Vehicles

10 Vehicles

10 Vehicles

0 200 400 600 800 1000 1200 1400 1600 1800 2000

7psi E0 9psi E0 7psi E10 10psi E10Diurnal Permeation Rate-mg/day

Test Fuel 

### Day 2 Diurnal Performance All E77 Programs

Enhanced

- 8 Vehicles
Near Zero

- 4 Vehicles Zero Evap

- 1 Vehicle 4733

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## FIGURE 8. DAY THREE DIURNAL PERFORMANCE

FIGURE 9. TOTAL (3 DAY) DIURNAL PERFORMANCE 0 200 400 600 800 1000 1200 1400 1600 1800 2000

7psi E0 9psi E0 7psi E10 10psi E10Diurnal Permeation Rate-mg/day

Test Fuel 

### Day 3 Diurnal Performance All E77 Programs

Enhanced

- 8 Vehicles
Near Zero

- 4 Vehicles Zero Evap

- 1 Vehicle 7543

0 500 1000 1500 2000 2500 3000

7psi E0 9psi E0 7psi E10 10psi E10Diurnal Permeation Rate-mg

Test Fuel 

### Total (3 Days) Diurnal Performance All E77 Programs

Enhanced

- 8 Vehicles
Near Zero

- 4 Vehicles Zero Evap

- 1 Vehicle 13485

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## 3.1.6 Temperature Impact on Steady

- State Permeation

F or many years , and from many test programs, it has been s uggested and confirmed that a 10oC increase (18°F) in ambient temperature approximately doubles the steady

- state (static) permeation rate. The results of this latest program reconfirm that temperature impact. Figure 10

cross

- plots the 86oF s tatic permeation against the 105o F static permeation for six vehicles run on four different fuels, with the 2:1 line shown f or reference. Vehicles 206b, 208b, and 209b are certified to Tier 1 standards. Vehicles 210b and 213 b are Tier 2, while vehicle 222 b is a Zero Evap model.

FIGURE 10. TEMPERATURE EFFECT ON STATIC PERMEATION

3.1.7 Special Cases: Fuel System Leak Under Pressure

Vehicles 220b (2000 Chevrolet Malibu) and 221b (2000 Mitsubishi Galant) both exhibited significant leaks when the fuel system was pressurized during the static test. This procedure (Appendix B

– Test Procedure s ) is utilized to check for fu el system leaks. The effect of this leak can be seen in Figures 11 and 12. 0 50 100 150 200 250 300 350

0 20 40 60 80 100 120 140 160 105 deg F Static Permeation - mg/hr

86 deg F Static Permeation

- mg/hr 

## Temperature Effect on Static Permeation S w RI E

- 77

- 2b Program Vehicles

10E10 Fuel

7E10 Fuel

9E0 Fuel

7E0 Fuel

206b

- Large Square 208b

- Small Diamond 209b

- Small Circle 210b

- Small Triangle 213b

- Small Square 222b

- Large Triangle

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## FIGURE 11. VEHICLE 220b STATIC PERFORMANCE

FIGURE 12. VEHICLE 221b STATIC PERFORMANCE

0 5000 10000 15000 20000 25000

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 86 F Permeation Vehicle 220b

- 2000 Chevrolet Malibu

10 psi E10

- 7537
7 psi E10

- 7564
9 psi E0

- 7644
7 psi E0

- 7677

0 200 400 600 800 1000 1200 1400 1600

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 86 F Permeation Vehicle 221b

- 2000 Mitsubishi Galant

10 psi E10

- 7557
7 psi E10

- 7571
9 psi E0

- 7650
7 psi E0

- 7691

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## While this leak shows up very dramatically on the static leak check test, there is no reason to think the effect is not present in all testing (static, dynamic and diurnal). For this reason, these two vehicles were removed from all analyses in Section 3.1. The reactivity results are presented for reference in section 3.3, but should be used with care, as there are permeation and leaks present in the analysis. Tables 7 and 8 display the actual test results.

TABLE 7. VEHICLE 220 b DATA SUMMARY

2000 Chevrolet Malibu SHED Corrected Results Canister Fuel Permeation mg/day Loss Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g 220b 10.0/E10 Static (86) Perm 05/05/09 7537 68.1 0.00 Press. Incr. 20127.5 Prs+Fuel Incr. 23281.0

Static (105) Perm 05/06/09 7541 214.3 0.00 Press. Incr. 33978.6 Prs+Fuel Incr. 40776.4

Dynamic RL 05/07/09 25774 134.0 0.00 TEFVO 5.1 0.00

72 DHB 65-105 05/12/09 7546

Day 1 1306.1 0.30 Day 2 1889.7 10.40 Day 3 2055.8 24.30

7.0/E10 Static (86) Perm 06/03/09 7564 50.4 0.00 Press. Incr. 9122.4 Prs+Fuel Incr. 15723.6

Static (105) Perm 06/04/09 7565 182.0 0.00 Press. Incr. 23090.2 Prs+Fuel Incr. 28945.5

Dynamic RL 06/05/09 25781 697.9 0.00 TEFVO 76.8 0.00

72 DHB 65-105 06/09/09 7569

Day 1 1177.6 0.00 Day 2 1612.1 0.00 Day 3 1483.1 0.00

9.0/E0 Static (86) Perm 08/18/09 7644 102.3 0.00 Press. Incr. 23180.8 Prs+Fuel Incr. 28272.5

Static (105) Perm 08/19/09 7647 1858.1 0.00 Press. Incr. 35297.9 Prs+Fuel Incr. 51362.4

Dynamic RL 08/20/09 25789 2417.0 0.00 "True" HS 352.5 0.00

72 DHB 65-105 08/25/09 7657

Day 1 6733.3 0.00 Day 2 5884.8 0.00 Day 3 7049.9 0.00

7.0/E0 Static (86) Perm 09/09/09 7677 62.7 0.00 Press. Incr. 13514.7 Prs+Fuel Incr. 16556.8

Static (105) Perm 09/10/09 7680 279.2 0.00 Press. Incr. 22735.8 Prs+Fuel Incr. 30081.7

Dynamic RL 09/11/09 25794 3447.3 0.00 "True" HS 707.1 0.00

72 DHB 65-105 09/15/09 7686

Day 1 6218.7 0.00 Day 2 6214.7 0.00 Day 3 7041.9 0.00

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## TABLE 8. VEHICLE 221b DATA SUMMARY

The leak in vehicle 220 was later determined to be a deteriorating crack in the fuel vapor
vent elbow on the fuel sending unit on the top of the tank The vehicle was dropped from further testing in the later E

- 77

- 2c progra m

. 2000 Mitsubishi Galant SHED Corrected Results Canister Fuel Permeation mg/day Loss Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g 221b 10.0/E10 Static (86) Perm 05/27/09 7557 38.9 0.00 Press. Incr. 1568.7 Prs+Fuel Incr. 1693.9

Static (105) Perm 05/28/09 7559 80.2 0.00 Press. Incr. 1932.6 Prs+Fuel Incr. 2147.1

Dynamic RL 05/29/09 25778 116.2 0.00 TEFVO 26.9 0.00

72 DHB 65-105 06/02/09 7562

Day 1 827.9 2.00 Day 2 724.1 5.40 Day 3 702.4 21.80

7.0/E10 Static (86) Perm 06/10/09 7571 22.7 0.00 Press. Incr. 930.7 Prs+Fuel Incr. 971.0

Static (105) Perm 06/11/09 7572 61.4 0.00 Press. Incr. 1282.3 Prs+Fuel Incr. 1408.5

Dynamic RL 06/12/09 25783 102.0 0.00 TEFVO 40.5 0.00

72 DHB 65-105 06/16/09 7579

Day 1 894.7 0.00 Day 2 676.7 0.00 Day 3 618.0 0.00

9.0/E0 Static (86) Perm 08/20/09 7650 55.6 0.00 Press. Incr. 1348.8 Prs+Fuel Incr. 1406.0

Static (105) Perm 08/21/09 7652 94.8 0.00 Press. Incr. 1646.7 Prs+Fuel Incr. 1788.2

Dynamic RL 08/24/09 25790 135.2 0.00 "True" HS 29.0 0.00

72 DHB 65-105 09/01/09 7667

Day 1 706.4 0.30 Day 2 543.7 2.60 Day 3 538.3 9.30

7.0/E0 Static (86) Perm 09/17/09 7691 35.9 0.00 Press. Incr. 988.8 Prs+Fuel Incr. 961.8

Static (105) Perm 09/18/09 7692 66.8 0.00 Press. Incr. 1215.9 Prs+Fuel Incr. 1343.8

Dynamic RL 09/22/09 25797 189.8 0.00 "True" HS 42.5 0.00

72 DHB 65-105 10/07/09 7716

Day 1 603.0 0.00 Day 2 503.1 0.00 Day 3 487.0 0.00

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## 3.1.8 Carbon Canister Breakthrough

Canister breakthrough is measured by the weight change recorded for the trap canister outside the SHED. It quantifies the amount of vapors that overwhelm the evaporative system storage canister. Figure 13 displays the breakthrough resulting from testing of 9 psi E0 fuel.

FIGURE 13. CANISTER BREAKTHROUGH

Of the six vehicles for which useable data were obtained for subsequent analysis in this program, no breakthrough occurred when tested on summer grade 7 psi fuel, only two showed some breakthrough on 9 psi transitional grade fuels (shown in Figure 13), but all six exhibited significant breakthrough when tested with 10 psi winter grade fuel.

The lack of canister breakthrough for the 7 psi fuels (summer gra de) indicates that the storage capacity of these six systems is appropriately sized. 60 65 70 75 80 85 90 95 100 105 110

0 5 10 15 20 25 30 35 40 45 50

0 10 20 30 40 50 60 70SHED Temperature-deg FCanister Breakthrough-mg

Test Time

- hrs. 

### Canister Breakthrough 9 psi E0 Fuel

- 65 F to 105 F Diurnal

206b

- 2002 Nissan Altima

210b

- 2004 Chevrolet Impala

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## 3.2 Speciation

The project plan included the “speciation” of the evaporative emission results for each of the vehicles and test fuels. A sample of the ambient hydrocarbon ( HC ) concentration in the VT

SHED was collected in a Tedlar TM 

## bag during each test, and later analyzed for HC species using the laboratory’s Varian TM 

## chromatograph, and the “Auto

- Oil Test Procedure.” The results of this “speciation” allowed the calculation of the average reactivity of the permeate for each of the vehicles and fuels. Appendix B contains a full description of ATL’s Speciation Method.

An example of the speciation results is shown in Table 9 below. This table shows just the firs t 25 of 172 hydrocarbons that are identified using the “Auto

- Oil” test method, as reported by the lab.

TABLE 9. SPECIATION RESULTS

– VEHICLE 210 b

– 72

- HOUR DIURNAL TEST

Table 9 shows the “Detailed Hydrocarbon Speciation Results,” listed in the order that they appear, or “elute.” Second column is the species name, and the third is the CAS number 4

4 

### The CAS number is the C hemical A bstract S ervice r egistry number assigned to each specific molecule. CAS registry numbers are copyrighted by the American Chemical Society. Redistribution rights for CAS registry numbers are reserved by the American Chemical Society. “CAS registry” is a registered trademar k of the American Chemical S ociety. The CAS REGISTRY mostly covers substances identified from the scientific literature from 1957 to the present with some classes (fluorine

- and silicon

- containing compounds) going back to the early 1900s. Each substance i n REG ISTRY is identified by a unique numeric identifier called a CAS Registry Number

. 

## . The “net” values shown are the values after the initial, or time

- zero SHED mass values have been subtracted. Detailed Hydrocarbon Speciation Results Net mass Net conc. Species Name CAS # (mg) (ppmC) (mg) (ppmC) 1 Methane 00074-82-8 0.000 0.000 0% 0% 2 Ethylene 00074-85-1 0.000 0.000 0% 0% 3 Acetylene (Ethyne) 00074-86-2 0.000 0.000 0% 0% 4 Ethane 00074-84-0 0.000 0.000 0% 0% 5 Propene 00115-07-1 0.000 0.000 0% 0% 6 Propane 00074-98-6 2.567 0.080 0% 0% 7 Allene (Propadiene) 00463-49-0 0.000 0.000 0% 0% 8 Propyne 00074-99-7 0.000 0.000 0% 0% 9 2-Methylpropane 00075-28-5 6.877 0.218 0% 1% 10 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 4.323 0.142 0% 0% 11 1,3-Butadiene 00106-99-0 0.748 0.025 0% 0% 12 n-Butane 00106-97-8 150.105 4.763 11% 12% 13 2,2-Dimethylpropane 00463-82-1 0.000 0.000 0% 0% 14 t-2-Butene 00624-64-6 9.424 0.310 1% 1% 15 1-Butyne 00107-00-6 0.000 0.000 0% 0% 16 c-2-Butene 00590-18-1 6.054 0.199 0% 0% 17 3-Methyl-1-butene 00563-45-1 0.000 0.000 0% 0% 18 2-Methylbutane (Isopentane) 00078-78-4 119.321 3.812 9% 9% 19 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 8.829 0.301 1% 1% 20 2-Methyl-1-butene 00563-46-2 13.520 0.444 1% 1% 21 n-Pentane 00109-66-0 28.890 0.923 2% 2% 22 2-Methyl-1,3-butadiene 00078-79-5 0.535 0.018 0% 0% 23 t-2-Pentene 00646-04-8 27.079 0.890 2% 2% 24 3,3-Dimethyl-1-butene 00558-37-2 0.000 0.000 0% 0% 25 c-2-Pentene 00627-20-3 14.071 0.462 1% 1% 72DHB % total

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## A more useful presentation is shown in Table 10, where the results have been sorted by net mass, bringing the largest mass species to the top. In this case, the largest mass present was ethanol, at 221.0 mg, or 16% of the identified mass. The complete data set for the speciations can be found in Appendix E

.

TABLE 10. MASS SORTED SPECIATION RESULTS

– VEHICLE 210 b

– 72

- HOUR DIURNAL TEST

3.3 Reactivity



## Previous E

- 7 7 test programs had not included speciation in the test evaluation, and this program E

- 77

- 2b, was the first that allowed average reactivity to be calculated. E PA along with CRC has collected the data in this study to be used in the Motor Vehicle Emissions Simulator ( MOVES ) model. EPA handles its estimates of ozone formation in both their rulemakings and in State Implementation Plans by air quality modeling. The modeling requires inventories such as from MOVES and NONROAD models for HC, CO, NO X 

## and PM. For HC, the exhaust and evaporative HC (VOC) emissions are speciated using speciation profiles that break HC down into individual chemical constituents. These profiles are typically obtained from an EPA tool called SPECIATE ( http://www.epa.gov/ttn/chief/software/speciate/index.html ) . SPECIATE generally has over 100 different compounds (paraffins, olefins, alkynes, alcohols, and aldehydes) for both exhaust and evapo ra tive emissions. The component hydrocarbons are then used in air Detailed Hydrocarbon Speciation Results Net mass Net conc. Species Name CAS # (mg) (ppmC) (mg) (ppmC) Ethanol 00064-17-5 220.954 4.417 16% 11% 12 n-Butane 00106-97-8 150.105 4.763 11% 12% 18 2-Methylbutane (Isopentane) 00078-78-4 119.321 3.812 9% 9% 81 Toluene 00108-88-3 111.734 3.912 8% 10% 40 n-Hexane 00110-54-3 85.020 2.730 6% 7% 36 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 50.765 1.630 4% 4% 38 3-Methylpentane 00096-14-0 37.109 1.191 3% 3% 63 2,2,4-TriMePentane (IsoOctane) 00540-84-1 34.009 1.098 2% 3% 26 2-Methyl-2-butene 00513-35-9 32.366 1.064 2% 3% 21 n-Pentane 00109-66-0 28.890 0.923 2% 2% 53 Benzene 00071-43-2 27.841 0.985 2% 2% 23 t-2-Pentene 00646-04-8 27.079 0.890 2% 2% 49 Methylcyclopentane 00096-37-7 24.806 0.815 2% 2% 56 Cyclohexane 00110-82-7 22.521 0.740 2% 2% 34 2,3-Dimethylbutane 00079-29-8 20.899 0.671 2% 2% 25 c-2-Pentene 00627-20-3 14.071 0.462 1% 1% 57 2-Methylhexane 00591-76-4 14.030 0.452 1% 1% 74 Methylcyclohexane 00108-87-2 13.577 0.446 1% 1% 20 2-Methyl-1-butene 00563-46-2 13.520 0.444 1% 1% 66 n-Heptane 00142-82-5 12.843 0.413 1% 1% 79 2,3,4-Trimethylpentane 00565-75-3 12.580 0.406 1% 1% 59 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 12.194 0.393 1% 1% 50 2,4-Dimethylpentane 00108-08-7 10.867 0.350 1% 1% 14 t-2-Butene 00624-64-6 9.424 0.310 1% 1% 42 t-2-Hexene 04050-45-7 8.954 0.294 1% 1% 72DHB % total

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## quality models to predict ozone formation. A recent example of this modeling is discussed in the Regulatory Impact Analysis for the Renewable Fuels Standards which uses the CMAQ (Community Mul ti

- scale Air Quality) model ( http://www.epa.gov/AMD/CMAQ/ ) . An example of an EPA rulemaking package is the Regulatory Impact Analysis for the recent RFS2 rulemaking:

“Draft Regulatory Impact Analysis: Changes to Renewable Fuel Standard Program
, ” EPA

420

- D

- 09

- 001
, May 2009
, http://www.epa.gov/otaq/renewablefuels/420d09001.pdf

. A more simplified approach to assessing ozone formation potential is use of reactivity factors. Hydrocarbons are one of the precursors to the formation of atmospheric ozone. Each of the individual species of hydrocarbons in gasoline may have differing reaction rates in the ozone

forming process. In 1994
, Dr. William Carter of the University of California published a set of “ozone forming potential” factors known as the Maximum Incremental Reactivity (MIR) scale. The applicability of these factors is a subject of debate, but ARB has used the Carter Factors in their atmospheric predictions. These factors have been up dated over the years, and the CY 200 8 values used in this analy sis were taken from the ARB web site at:

http://www.arb.ca.gov/fuels/gasoline/premodel/pmdevelop.htm

The MIR is the ratio of the mass of ozone that would be formed under ideal conditions by a similar mass of the Volatile Organic Compound ( VOC ) . For example, one mg of ethanol is predicted to form 1.45 mg of ozone. One can estimate the average reactivity of an ambient mixture by summing the predicted ozone result for all the identified species, and then dividing by the sum of the measured VOC mass.

A sample chart, using the data from the three

- day diurnal on Vehicle 210 b is shown in Table 11, illustrat ing how the average reactivity of the various fuels was calculated . Again, the various species are sorted by decreasing order of their mass in the measured SHED sample. The left column is the species name, with its CAS number at the next right. The Cart er factor (MIR) is next, and then the mass of the species, as VOC in mg.

The sum of the predicted ozone for this test (Table 11) was 3812.8 mg, from 1298.2 mg of VOC. Dividing the total ozone mass by the total VOC mass gives the average reactivity of th is test of 2.937. T he summary of reactivities for all eight vehicles is shown in Tables 12 through 19

.

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## TABLE 1 1

. REACTIVITY RESULTS

Vehicle 210b

- Fuel 10 psi E10

- 3 Day Diurnal

- Test 7462 Non Zero Mass Species Sorted By VOC

Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064

- 17

- 5 1.45 220.95 320.157

n

- Butane 00106

- 97

- 8 1.08 150.10 161.650
2

- Methylbutane (Isopentane) 00078

- 78

- 4 1.35 119.32 161.666
Toluene 00108

- 88

- 3 3.93 111.73 438.558

n

- Hexane 00110

- 54

- 3 1.13 85.02 96.470
2

- MePentane & 4

- Me

- c

- 2

- Pentene 00691

- 38

- 3+00107

- 83

- 5 1.40 50.76 70.959
3

- Methylpentane 00096

- 14

- 0 1.69 37.11 62.747 2,2,4

- TriMePentane (IsoOctane) 00540

- 84

- 1 1.20 34.01 40.781
2

- Methyl

- 2

- butene 00513

- 35

- 9 14.20 32.37 459.437

n

- Pentane 00109

- 66

- 0 1.21 28.89 35.099
Benzene 00071

- 43

- 2 0.69 27.84 19.331

t

- 2

- Pentene 00646

- 04

- 8 10.47 27.08 283.609 1,2,3

- Trimethylbenzene 00526

- 73

- 8 11.94 0.36 4.244
Unknown #22

. 2.94 0.34 0.989
1

- Heptene 00592

- 76

- 7 4.29 0.33 1.428

t

- 1,3 & c

- 1,4

- DiMeCyHexane 02207

- 03

- 6+00624

- 29

- 3 2.94 0.32 0.933
1

- Nonene 00124

- 11

- 8 2.49 0.32 0.786 Isopropylbenzene (Cumene) 00098

- 82

- 8 2.94 0.28 0.835 2,4,4

- Trimethyl

- 2

- Pentene 00107

- 40

- 4 6.30 0.28 1.744
Indan 00496

- 11

- 7 3.23 0.27 0.886 1,1

- Dimethylcyclohexane 00590

- 66

- 9 1.12 0.17 0.186
Total 1298.2 3812.8 2.937 No MIR available, use weighted average of 2.9369

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## TABLE 12. VEHICLE REACTIVITY SUMMARIES Vehicle 206b

Test Fuel Test No. Bag THC mg GC as % of THC GC VOC

mg Ozone mg Reactivity Species Present 86° F E10

- 10 psi 7456 247.0 100.8 249.1 885.1 3.553 71 Static E10

- 7 psi 7484 279.7 79.6 222.7 796.1 3.575 60 E0

- 9 psi 7539 123.3 99.5 122.8 511.2 4.164 55 E0

- 7 psi 7561 97.3 80.1 78.0 284.8 3.651 56

105° F E10

- 10 psi 7459 630.7 93.1 587.4 2085.4 3.550 86 Static E10

- 7 psi 7487 606.2 125.3 759.4 2686.3 3.538 84 E0

- 9 psi 7545 366.7 72.9 267.3 814.4 3.047 30 E0

- 7 psi 7563 234.6 85.9 201.5 854.3 4.241 30

Dynamic E10

- 10 psi 25753 727.2 87.3 634.7 2191.6 3.453 66 E10

- 7 psi 25760 673.6 90.0 606.0 2158.5 3.562 59 E0

- 9 psi 25775 456.1 76.8 350.1 1316.4 3.760 54 E0

- 7 psi 25780 316.9 78.8 249.7 987.9 3.956 52

DHB E10

- 10 psi 7476 76809.3 82.4 63303.9 148993.1 2.354 123 Total E10

- 7 psi 7495 6985.0 88.6 6189.7 21304.5 3.442 108 E0

- 9 psi 7551 4036.4 91.1 3677.3 11381.0 3.095 107 E0

- 7 psi 7567 2993.3 93.4 2797.0 8687.2 3.106 105



## TABLE 13 . VEHICLE REACTIVITY SUMMARIES Vehicle 208b

Test Fuel Test No. Bag THC mg GC as % of THC GC VOC

mg Ozone mg Reactivity Species Present 86° F E10

- 10 psi 7413 75.6 127.7 96.6 413.8 4.284 42 Static E10

- 7 psi 7478 50.5 102.6 51.9 136.0 2.623 40 E0

- 9 psi 7530 74.2 121.3 90.0 287.6 3.195 52 E0

- 7 psi 7568 49.6 102.0 50.6 159.2 3.146 55

105° F E10

- 10 psi 7415 115.2 110.4 127.1 415.6 3.268 59 Static E10

- 7 psi 7480 105.4 104.1 109.7 391.9 3.572 76 E0

- 9 psi 7532 112.7 102.4 115.4 370.1 3.207 60 E0

- 7 psi 7570 123.9 94.4 117.0 403.3 3.448 63

Dynamic E10

- 10 psi 25744 337.0 95.8 322.8 1369.5 4.242 56 E10

- 7 psi 25759 308.3 132.8 409.4 1718.9 4.198 72 E0

- 9 psi 25771 257.5 159.1 409.6 1853.2 4.524 52 E0

- 7 psi 25782 199.7 51.9 103.6 353.6 3.413 40

DHB E10

- 10 psi 7463 1852.2 103.6 1919.2 5628.6 2.933 107 Total E10

- 7 psi 7489 1740.5 89.3 1554.4 5099.2 3.281 107 E0

- 9 psi 7556 1864.6 93.2 1737.6 4606.5 2.651 98 E0

- 7 psi 7575 1317.5 88.6 1167.2 3392.4 2.906 86

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## TABLE 1 4 . VEHICLE REACTIVITY SUMMARIES

Vehicle 209b

Test Fuel Test No. Bag THC mg GC as % of THC GC VOC

mg Ozone mg Reactivity Species Present 86° F E10

- 10 psi 7423 52.1 165.6 86.2 276.2 3.205 63 Static E10

- 7 psi 7466 54.4 130.9 71.2 262.9 3.692 78 E0

- 9 psi 7501 44.8 83.4 37.3 76.3 2.043 19 E0

- 7 psi 7524 38.8 120.5 46.8 161.0 3.441 51

105° F E10

- 10 psi 7424 160.9 117.8 189.4 593.2 3.131 65 Static E10

- 7 psi 7467 102.4 98.8 101.2 340.7 3.368 57 E0

- 9 psi 7504 55.8 86.1 48.1 186.9 3.886 52 E0

- 7 psi 7527 62.4 101.5 63.3 245.8 3.885 50

Dynamic E10

- 10 psi 25742 401.4 111.9 449.1 1629.8 3.629 74 E10

- 7 psi 25755 217.1 85.1 184.7 701.1 3.796 58 E0

- 9 psi 25761 140.9 102.9 145.0 658.3 4.541 45 E0

- 7 psi 25768 166.6 87.9 146.4 543.1 3.708 31

DHB E10

- 10 psi 7461 1434.5 93.8 1345.1 3821.9 2.841 110 Total E10

- 7 psi 7472 1055.7 93.7 989.6 2879.4 2.909 89 E0

- 9 psi 7508 802.6 59.6 478.6 1316.0 2.749 65 E0

- 7 psi 7533 821.9 94.5 776.5 2515.6 3.239 81



## TABLE 1 5

. VEHICLE REACTIVITY SUMMARIES

Test Fuel Test No. Bag THC mg GC as % of THC GC VOC mg Ozone mg Reactivity Species Present 86 ° F E10 - 10 psi 7449 51.6 89.7 46.3 143.2 3.096 49 Static E10 - 7 psi 7468 63.0 96.2 60.6 186.3 3.072 56 E0 - 9 psi 7523 46.2 121.3 56.1 208.1 3.712 53 E0 - 7 psi 7547 37.5 90.0 33.7 108.4 3.214 40

105 ° F E10 - 10 psi 7451 147.3 102.1 150.3 473.4 3.150 62 Static E10 - 7 psi 7471 117.5 92.6 108.8 346.6 3.186 69 E0 - 9 psi 7525 69.8 132.1 92.3 296.6 3.215 62 E0 - 7 psi 7549 74.0 104.9 77.6 270.6 3.486 48

Dynamic E10 - 10 psi 25749 198.4 85.9 170.5 569.7 3.342 52 E10 - 7 psi 25756 189.1 100.1 189.2 710.5 3.754 48 E0 - 9 psi 25767 178.0 74.9 133.2 328.8 2.468 41 E0 - 7 psi 25776 234.9 84.5 198.4 848.9 4.278 32

DHB E10 - 10 psi 7462 1386.1 93.7 1298.2 3812.8 2.937 95 Total E10 - 7 psi 7482 1192.5 87.0 1037.4 3101.2 2.989 86 E0 - 9 psi 7531 1143.4 88.3 1010.2 2351.6 2.328 32 E0 - 7 psi 7550 758.3 87.7 665.0 1927.4 2.898 86 

### Vehicle 210b

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## TABLE 1 6 . VEHICLE REACTIVITY SUMMARIES

TABLE 1 7 . VEHICLE REACTIVITY SUMMARIES Caution: These measurements include known leaks as well as permeation Test Fuel Test No. Bag THC mg GC as % of THC GC VOC mg Ozone mg Reactivity Species Present 86 ° F E10 - 10 psi 7442 74.9 84.5 63.3 229.3 3.620 59 Static E10 - 7 psi 7464 60.4 77.3 46.7 118.1 2.531 12 E0 - 9 psi 7506 34.8 88.3 30.7 102.3 3.329 41 E0 - 7 psi 7526 40.9 86.2 35.3 104.0 2.947 38

105 ° F E10 - 10 psi 7446 228.3 105.1 239.8 761.0 3.174 78 Static E10 - 7 psi 7465 159.2 87.2 138.9 440.2 3.169 64 E0 - 9 psi 7507 71.1 82.7 58.8 173.0 2.943 32 E0 - 7 psi 7528 66.8 106.3 71.0 251.7 3.546 50

Dynamic E10 - 10 psi 25750 144.8 124.2 179.8 839.7 4.669 48 E10 - 7 psi 25754 284.5 88.3 251.3 879.7 3.500 60 E0 - 9 psi 25764 191.7 52.9 101.4 314.8 3.105 38 E0 - 7 psi 25769 141.4 69.4 98.1 381.1 3.885 59

DHB E10 - 10 psi 7429 1966.7 101.3 1992.2 5290.8 2.656 92 Total E10 - 7 psi 7473 1769.4 67.1 1187.5 4082.1 3.438 80 E0 - 9 psi 7516 967.5 88.7 858.6 2298.5 2.677 73 E0 - 7 psi 7538 917.6 94.2 864.0 2571.4 2.976 80 

### Vehicle 213b

Test Fuel Test No. Bag THC mg GC as % of THC GC VOC mg Ozone mg Reactivity Species Present 86 ° F E10 - 10 psi 7537 21249.9 91.1 19364.6 45551.4 2.352 87 Static E10 - 7 psi 7564 11657.5 81.0 9442.0 28464.0 3.015 96 E0 - 9 psi 7644 24378.7 96.6 23556.0 50039.7 2.124 93 E0 - 7 psi 7677 14347.6 99.7 14299.8 35390.0 2.475 114

105 ° F E10 - 10 psi 7541 36851.0 78.1 28779.5 70524.0 2.450 105 Static E10 - 7 psi 7565 24424.1 91.8 22427.0 66555.4 2.968 127 E0 - 9 psi 7647 44422.3 90.3 40098.4 88163.2 2.199 108 E0 - 7 psi 7680 25952.5 105.4 27348.3 68042.1 2.488 120

Dynamic E10 - 10 psi 25774 180.3 74.0 133.5 501.4 3.756 45 E10 - 7 psi 25781 685.5 64.2 440.2 1445.3 3.283 69 E0 - 9 psi 25789 2388.4 99.7 2380.7 6653.4 2.795 55 E0 - 7 psi 25794 3527.7 104.6 3689.9 12792.2 3.467 114

DHB E10 - 10 psi 7546 5251.6 91.5 4805.1 12517.4 2.605 107 Total E10 - 7 psi 7569 4272.9 91.7 3916.7 11477.1 2.930 125 E0 - 9 psi 7657 19668.0 103.4 20327.8 49439.0 2.432 128 E0 - 7 psi 7686 19475.3 103.9 20242.7 51559.2 2.547 134 

### Vehicle 220b

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## TABLE 1 8 . VEHICLE REACTIVITY SUMMARIES Caution: These measurements include known leaks as well as permeation

TABLE 1 9 . VEHICLE REACTIVITY SUMMARIES Test Fuel Test No. Bag THC mg GC as % of THC GC VOC mg Ozone mg Reactivity Species Present 86 ° F E10 - 10 psi 7557 1592.1 85.9 1367.1 3249.9 2.377 57 Static E10 - 7 psi 7571 951.42 75.9 722.3 2179.9 3.018 65 E0 - 9 psi 7650 1390.71 89.8 1248.3 2750.8 2.204 66 E0 - 7 psi 7691 979.48 114.5 1121.8 2764.8 2.465 72

105 ° F E10 - 10 psi 7559 2131.5 92.0 1960.1 4768.7 2.433 79 Static E10 - 7 psi 7572 1354.2 93.7 1268.7 3796.8 2.993 76 E0 - 9 psi 7652 1823.3 100.0 1824.1 3993.6 2.189 66 E0 - 7 psi 7692 1351.9 115.3 1558.2 4073.8 2.614 103

Dynamic E10 - 10 psi 25778 158.8 97.8 155.3 519.8 3.347 54 E10 - 7 psi 25783 144.6 118.7 171.6 578.9 3.373 59 E0 - 9 psi 25790 192.8 161.7 311.8 851.8 2.732 55 E0 - 7 psi 25797 230.2 88.6 204.1 877.0 4.298 49

DHB E10 - 10 psi 7562 2254.5 86.6 1952.6 5269.2 2.699 90 Total E10 - 7 psi 7579 2189.4 85.0 1860.2 5643.5 3.034 104 E0 - 9 psi 7667 1788.4 90.9 1625.8 4353.4 2.678 83 E0 - 7 psi 7716 1593.2 103.2 1644.2 4729.0 2.876 92 

### Vehicle 221b

Test Fuel Test No. Bag THC mg GC as % of THC GC VOC mg Ozone mg Reactivity Species Present 86 ° F E10 - 10 psi 7552 12.2 212.7 26.0 76.7 2.953 21 Static E10 - 7 psi 7576 28.2 95.7 27.0 73.7 2.729 29 E0 - 9 psi 7655 6.4 79.8 5.1 28.5 5.617 10 E0 - 7 psi 7712 7.0 215.7 15.1 59.6 3.957 24

105 ° F E10 - 10 psi 7554 20.6 163.4 33.7 119.6 3.545 32 Static E10 - 7 psi 7578 28.9 111.3 32.1 134.5 4.189 41 E0 - 9 psi 7659 11.7 180.8 21.2 100.3 4.734 46 E0 - 7 psi 7715 14.0 228.9 32.1 165.4 5.146 43

Dynamic E10 - 10 psi 25779 73.3 30.1 22.1 54.9 2.488 22 E10 - 7 psi 25785 51.6 66.8 34.5 81.1 2.351 21 E0 - 9 psi 25791 33.5 145.1 48.6 231.3 4.759 19 E0 - 7 psi 25808 97.2 72.7 70.6 220.5 3.122 39

DHB E10 - 10 psi 7558 257.2 70.4 181.0 525.8 2.905 68 Total E10 - 7 psi 7580 287.6 93.6 269.1 853.3 3.171 66 E0 - 9 psi 7696 177.2 95.4 169.1 728.2 4.307 64 E0 - 7 psi 7742 136.4 67.5 92.1 286.4 3.111 47 

### Vehicle 222b

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## 3.4 Summary of Findings and Results

The E

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- 2b test program was a continuation of the earlier E

- 77 test program which added eight vehicles to be tested on four fuels to increase the size of the knowledge base. The permeation trends previously shown were again present. The small sample size and limited number of tests preclude making statements about statistical validity, but in general:

**•** Increasing ethan ol content (0% to 10%) increased permeation in the “enhanced” vehicles tested.

**•** “Near zero” and “zero evap” vehicles were less sensitive (or insensitive) to ethanol level. This may be due to the materials used to achieve the lower emission levels, or perhaps the limited sample size.

**•** Increased fuel volatility increased permeation levels for “enhanced” vehicles.

**•** The lower emitting “near zero” and zero evap” vehicles did not exhibit a clear trend with increasing volatility level. Again, this may be due to the materials used for the vehicles tested, or the small sample size.

**•** “Near zero” and “zero evap” vehicles had lower emissions than the “enhanced” vehicles.

**•** The two vehicles identified with “leaks” were not included in the analysis for the permeation trends, but were interesting in that they may suggest deterioration with time for the vehicles at eight or more years of age.

3.5 Looking Ahead

Additional test work is suggested to increase the knowledge base (particularly concerning the newer designs) . Since losing two vehicles to leak conditions, the knowledge base contains a total of eight “enhanced” vehicles, four “near zero” vehicles and only one “zero evap” vehicle

– hardly enough to make any statistical evaluation of trends. Consideration shoul d be given to additional testing.

## APPENDIX A

E

- 77 TEST CONCEPT AND THEORY

## A

- 1 The Test Concept: Measuring Leaks, Permeation and Diurnal Vapor Losses

CRC’s E

- 77 emission test programs have developed (and strive to continually improve) new methodologies for understanding and quantifying vehicle evaporative emission rates

. The concept partitions and assigns the vehicle’s contribution to the evaporative emission inventory into three mechanisms :
1. Permeation 2. Tank vapor venting 3. Leaks ( with two subsets

- Liquid and Vapor)

Permeation is the migration of HC through the various elastomers in a vehicle fuel system 5



## Figure A

- 1. Control System Schematic . Previous testing has shown that p ermeation rate is strongly affected by the material’s temperature, doubling for each 10oC (18oF) increase in the range of normal summer temperatures (See, among others, CRC Project E

- 65

- 3 report.) It is also strongly af fected by gasoline composition, especially with ethanol

- containing fuels.

Tank vapor venting emissions are controlled by fitting a carbon canister to the atmospheric tank vent. Figure A1 is a schematic of a typical early control system. During a daily heating period, the temperature of the vehicle’s fuel tank increases, forcing HC vapors from the tank. Exc ess emissions, exceeding the carbon canister’s capacity, are vented to the atmosphere.

5 

### “Fuel Permeation from Automotive Systems: Final Report CRC Project E

- 65,” Haskew, Liberty and McClement,

September 2004, available on the CRC and California Air Resou rces Board websites.

## A

- 2 Leaks can be liquid or vapor. Mass emissions are measured in a VT SHED or Variable Temperature Sealed Housing for Evapor ative Determination. The SHED test method combines all three emission mechanisms (leaks, diurnal venting, and permeation) into a single test result.

The SHED technique involves placing the veh icle in a sealed enclosure (Figure A2), and calculating the mass in the enclosure from the volume, density and concentration in the enclosure at the start and end of a time period. The difference between the mass at the start and end of test is the emissio n rate, e.g., grams per unit time.

Permeation and tank venting losses are strongly driven by fuel composition, ambient temperature, and ambient temperature change. L iquid l eaks are not strongly affected by normal sum mer temperatures, and they are thou ght to have two components:

1. S tatic leaks occurring while the engine is turned off and the vehicle is stationary. 2. I ncrease in leak rate caused by the system pressure increase during engine operation.

A Test Method for Separating Permeation from Tank Venting and Leaks

– In a previous CRC Project (E

- 65), the canister loss was separated from the permeation measurement by venting the losses from the carbon canister outside the SHED. For Project E

- 77, the canister vent loss es were collected and measured in a separate “trap canister” on a scale outside the SHED, as shown in Figure A3. This vent line was capped off, i.e., sealed during the Static Test, but connected as shown in the figure for the Dynamic and the Diurnal Tests. The ambient temperature in the SHED was constant during the static test, and there was no vapor created at constant temperature. This vent was closed to pressurize the system for the leak evaluations. The resulting SHED increase in HC mass was permeation 6

6 

### This is a simplification. There are other HC sources present that are not fuel permeation. These include tire, paint,

adhesives and vinyl emissions, and the possibility of fuel leaks from the fuel injectors. The authors believe th ese to be a minor component of the emissions measured in this study. 

## . The last mechanism that needed to be evaluated was leaks. Leaks can be both vapor and liquid. A liquid leak can have significant mass, currently undetected by the vehicle’s on

- board diagnostic system. Considerable thought and effort have gone into t he creation of a simple and effective liquid leak detection methodology, without success. The techniques used in this project Figure A

- 2. S ealed H ousing for E vaporative D etermination

Figure A

- 3. Trap Canister

## A

- 3 required the use of a SHED for measurements. The techniques were not simple, but they proved effective.

Based on experience, a vehicle’s permeation rate is expected to lie between 4 to 90 mg/hour range. The presence of a static liquid leak is expected to overwhelm this value; such a leak would (or could) be apparent by inspection. Leaks from the vehicles were quantified in a thr ee

step test process. The first step was to measure the static permeation rate of the vehicle at 86oF. The vehicle was allowed to stabilize at 86oF in the SHED and the permeation rate was calculated from the mass increase in the SHED. The second part of the test, looking for pressure driven leaks in the vapor system, was performed by pressurizing the vehicle’s tank to 5” H 2 

## O through a special fuel cap and tubing from outside the SHED (Figure A4). The special fuel cap, the hose and the pressurization appa ratus was installed before the start of the sequence. The HC concentration in the SHED was monitored, and the increase in the mass of HC in the SHED was compared to the static permeation rate. If there was no (or insignificant) rate of increase, it was de duced that no vapor leak is present.

The third and final part of the test was to energize the vehicle’s fuel pump and pressurize the system up to and including the injectors (Figure A

- 5). If there were a pressure leak in the liquid system, an increase in the SHED mass over time would be seen, i.e., the leak would be additive to the permeation rate. Figure A

- 4. Static Test

– Tank

## A

- 4 Figure A

- 5. Static Test

– Fuel Pump Energized

Other Tests ( Dynamic, Hot Soak, and Diurnal )

- A similar configuration is used to isolate the tank venting losses from the permeation measure ments determined by other test procedures. The vehicle’s canister vent is connected with a low permeation hose (Teflon TM 

## ) to a bulk

- head fitting in the SHED wall and then to a separate “trap canister” on a top

- loading scale. Any HC emissions that escape f rom the vehicle’s canister are captured in the trap canister, and measured at a 0.01 g (10 milligram) precision. The trap canister (a 1 Liter Ford model) is periodically purged and maintained at a “dry” condition so that it captures all of the vehicle’s e scaping emissions. This assumption is probably violated during the high volatility tests where there are 30 grams of daily emissions, but this is not a concern at this time.

Test Elements for E

- 77

- 2

- The following flow chart (Figure A

- 6) displays the various elements utilized during the testing of the various vehicles and fuels during this program. Details of each of the four basic tests follow the flow chart.

## A

- 5 Drain and 40% Fill with 10 psi E10 Test Fuel

Road Preconditioning Four LA

- 4’s or E quivalent

Drain and 40% Fill with 10psi E10 Test Fuel

Overnight Park at 86°F

Move to SHED Connect Test Instrumentation Stabilize at 86°F

Perform Constant Temperature Permeation Series (86°F) 1 hour Permeation Rate Test 1⁄2 hour Tank Pressurized Test 1⁄2 hour Pump Energized Test

Transfer to RL SHED Connect Test Instrumentation Stabilize at 86°F Perform Dynamic Permeation Test Two LA92 Driving Cycles & One Hour Hot Soak

Drain and 40% Fill With 10 psi E10 Test Fuel

Road Preconditioning Four LA

- 4’s or Equivalent

Move to VT

- SHED Connect Test Instrumentation Stabilize at 65°F for 6 hrs. Minimum

Perform 3

- Day Diurnal Evaluation 72 hr 65° to 105°F VT Test

Drain and 40% Fill with 7 psi E10 Test Fuel

Condition Fuel System By Driving for One Day

Repeat Steps 1

– 12 On 7 psi E10 Test Fuel

Drain and Fill with 9 psi E0 Test Fuel Condition Fuel System by 4 weeks Driving

Repeat Steps 1

– 12 On 9 and 7 psi E0 Precondition Fuel System With 4 Weeks Driving on 10 psi E10 Test Fuel

1

2

3

4

5

6

7 8

9

10

11

12



## Figure A

- 6. Testing Flow Chart

## APPENDIX B

TEST PROCEDURES

## B

- 1 Test Procedures

– There are four basic tests in the E

- 77

- 2 test protocol.

1. Static Permeation Rate (Includes checks for vapor and liquid leaks) 2. Running Emissions (Dynamic Test) 3. Hot Soak 4. Diurnal

Each is described in detail below.

1. Static Permeation Testing

The constant temperature (static) permeation rate is measured in a traditional SHED (constant temperature) in the following manner.

A. The fuel tank is drained and filled to 40% tank capacity with the test fuel. B. The day before testing, the vehicle is driven over four road trips of 7.5 miles each to precondition the canister

. 7 

## C. Upon return from the road pre

- conditioning, the fuel tank is drained and filled to 40% tank capacity with the test fuel

. (These drives are similar to the LA

- 4.)

8 

## D. Vehicle is parked for 18

- 22 hours in a controlled temperature environment at test temperature (86oF)

. E. The vehicle is then moved (with out starting) into the test (86oF) SHED

. F. T he canister vent is connected to the SHED bulkhead fitting which routes the vapor to the trap canister outside the SHED

. G. T he tank system pressurization hose is connected. H. T he fuel pump electrical connection is connected. I. The SHED is sealed , the inside temperature is allowed to stabilize and the test is started. Continuous total hydrocarbon (THC) measurements are made using a FID

. E thanol, methanol and R134a concentrations are measured using an INNOVA analy zer . All measurements are made at least every minute for one hour to determine the stabilized permeation rate. J. At the end of the static test (60 minutes), the vehicle’s vapor system is pressurized to 5 inches of water for thirty minutes . M easurements are made to quantify vapor leaks as determined by a c hange in the SHED uncorrected mass

. K. T he fuel pump is then energized for 30 minutes while maintaining the 5 inches of water on the vapor system . L iquid leaks are quantified as determined by a change in the SHED concentrations.

The purpose of steps J and K above is to validate that the permeation rate measurement was made without the presence of any leak

– either liquid or vapor.

7 

### This conditioning can be done in the laboratory on a chassis dynamometer if proper attention is paid to underbody

cooling and unrepresentative fuel tank temperatures are avoided. 8 

### Vehicles with ORVR systems will add the refueling vapors to the canister. This is OK.

## B

- 2 2. Running Loss Test (Dynamic Test)

A. The v ehicle is placed in the RL

- SHED and prepared for test. (The fuel level and condition for the dynamic test is the fuel remaining after completion of the static test

– 40% fresh fill of the appropriate test fuel

. ) B. Outside air s ource for the engine is connected. C. Vehicle e xhaust is c onnect ed. D. F uel tank thermocouple is connected. E. C anister vent is connected to the SHED bulkhead fitting which routes the vapor to the trap canister outside the SHED

. F. V ehicle is allowed to stabilize in the RL

- SHED at test temperature (86°F) for a minimum

o f 12 hours

– preferably overnight. G. T wo cycles of the Unified Cycle (LA

- 92) driving schedule (48 min.) are driven while measuring the mass emissions in the SHED. Vehicle is allowed to i dle (in drive) for 30 seconds between the two cycles. A mbient air temperature is maintained (to the extent possible) at 86°F. F uel tank surface temperature is monitored during vehicle operation. It should increase during the drive from 10 to 18°F to simulate expected on

- road temperature increase. M easured mas s emissions are corrected using the INNOVA data for the ethanol, methanol and refrigerant emissions.

3. Hot Soak 9



## A. E ngine is turned off , transmission selecto r is placed in park, and driver exit s the enclosure, using the double door air lock, taking care to minimize any air exchange between the laboratory and the SHED. This starts the one hour “hot soak” period. This procedure is executed immediately following the Running Loss Test procedure described above.

B. M easure ment of mass emission s in the SHED are co ntinued for another 60 minutes (until time = 108 minutes), correcting for the ethanol, methanol and refrigerant mass using the INNOVA instrument data. This ends the hot soak. H ot soak emissions are calculated as the net difference for the one hour hot soa k (CorrMass 108 

## – CorrMass 48 

## minus the 86°F static hourly rate, all mass rates in mg/hour).

4. Diurnal Test A. The fuel tank is drained and filled to 40% tank capacity with the test fuel. B. The day before testing, the vehicle is to be driven over four road trips of 7.5 miles each to precondition the vehicle and the canister

. C. Upon return from the road pre

- conditioning, the fuel tank is drained and filled to 40% tank capacity with the test fuel

. D. The v ehicle is parked for 18

- 22 hours in a controlled t emperature environment at the initial diurnal test temperature (65oF)

. E. The SHED is sealed, allowed to stabilize at the 65°F temperature and the 3

- day California Diurnal Test is started. F. “Continuous” (every 30 seconds) total hydrocarbon measurements are made using a Flame Ionization Detector ( FID ). E thanol, methanol and R134a (refrigerant)

9 

### As defined here, the “hot soak” is the temporary increase in emission rate caused by the vehicle’s immediately

preceding operation. It is the increase in the SHED ma ss (corrected for EtOH, MeOH and R

- 134a) over the one hour period minus the previously established “static” permeation rate.

## B

- 3 concentrations are measured using an INNOVA analyzer, at least every 10 minutes for the duration of the test (72 hours).

Static Permeation Test

– Leak Validation

If a leak is detected during either the vapor system pressure portion (Step J) or the pump energized portion (Step K) of the Static Permeation Test procedure, it calls into question whether
t he permeation rate measurement accurately reflects fuel system permeation or if instead a combination of permeation and the implied leak was measured. If a leak is confirmed, the permeation rate measurement is called into question, and an investigation, p ossible remedy, and retest is indicated.

The permeation rate measurement must be corrected for the FID’s ethanol misrepresentation, and the presence of non

- fuel HC (methanol and refrigerant). The leak check, however, is made using the change in mass incre ase in the SHED using the uncorrected FID mass calculation as the determinate. The corrections for ethanol, methanol and refrigerant were found to be introducing “noise” into the trace that was being misinterpreted as leak(s).

Figure A

- 7 above represents the calculations made during the inspection of data from a successful test. EXCEL’s © 

## “SLOPE” function is used to calculate the linear regression values based on the FID calculation for mass for: Time 0 to 60 minutes, Time 64 to 90 minutes, and Time 94 to 120 minutes. A four

- minute gap was included between each sequence to establish the new mass emission rate during the “pressure on,” (T 60 

## to T 90 

## ), and the “pump energized” periods.

The slope of 0.47 for the “Tank Pressur ized” period in the example above is compared to the slope of 0.62 calculated for the permeation rate (or hot soak) period. Since the “Tank Pressurized” slope is not more than 10% higher than the hot soak permeation rate, it is assumed y = 0.62 x
- 1.9 y = 0.47 x + 6.7 y = 0.55x

- 0.1

0 10 20 30 40 50 60 70 80 90 100

0 20 40 60 80 100 120SHED Mass-mg

Test Time

- minutes Leak Test Vehicle 204

- 1999 Honda Accord

- 9 psi E0

Test 7028 Pump Activated Tank Pressurized



## Figure A

- 7. Leak Test

## B

- 4 that there is no le ak present. A similar comparison is made for the slope determined during the “pump on” period. The choice of a 10% allowance is arbitrary and is used here to allow for normal and unavoidable test variation.

For tests in which the above procedure determines that no leak is present, a value of zero is reported in the test summary for the leak results. If a positive value is reported, it calls that test into question, and an investigation, possible repair, and retest is indicated.

Static Permeation Rate Determination

The static permeation rate is determined based on a linear regression through the individual data points (30 second data) corrected fuel results from the first 60 minutes of testing, as illustrated in Figure A

- 8.

In this example, the static permeation rate is 33.8 mg/hr.

Dynamic (Running Loss) and Hot Soak Test

The preceding section addressed the concepts of separating the permeation emissions from the tank venting emissions, and establishing the presence or absence of leaks. The second part of this study includes a dynamic test to measure the permeation and tank venting emissions during vehicle operation (“running losses”) and the temporary condition following vehicle operation k nown as the “hot soak.”

This is considered a “dynamic” test because the vehicle is driven and the fuel and vapor system temperatures rise during the test. The ambient temperature in the Running Loss SHED during y = 0.5636x + 0.505

0 5 10 15 20 25 30 35 40 45

0 10 20 30 40 50 60Permeation-mgs.

Test Time

- mins. Static Permeation Determination Vehicle 204

- 1999 Honda Accord

- 9 psi E0 Fuel

Raw SHED

Corrected Fuel

Permeation Rate Based on Corrected Results
Permeation Rate = .5636 x Time = 33.8 mgs/hr



## Figure A

- 8. Stati c Permeation Determination

## B

- 5 test was held constant at 86°F, while the v ehicle’s fuel system temperature rose during the test. Two 1435 second (23.9

- minute) LA

- 92 driving cycles were performed consecutively during the running loss measurements with a 30

- second idle in between. During this test, tank fuel temperature was expec ted to rise by an average approximately 18°F above the initial ambient temperature. The running loss air handling system included a proportional speed under

- car blower operated as a slave to dynamometer speed. This apparatus was used during running loss testing with minor tuning for specific vehicles. It is capable of reasonable fuel tank temperature control without additional input. Each vehicle was fitted with a surface

- mount thermocouple at the front of the fuel tank, located at approximately the 1/8 th 

## fill level to measure the fuel liquid temperature. No attempt was made to follow a predefined fuel tank temperature profile (FTTP) in this program. Fuel temperatures were recorded, and results are available in the real

- time records.

Vehicle running loss emissions are measured in a special version of a SHED known as a Running Loss SHED (RL

- SHED), shown in Figure A

- 9. Special features of the RL

- SHED include a sealed chassis dynamometer for simulating vehicle driving loads, a sealed outside air supply for engine intake, a sealed exhaust conduit for engine exhaust, and an under

- chassis fan for simulating underbody air flow as described above. A vehicle is operated inside the RL

- SHED over a chosen driving cycle. The increase in HC emissions inside the enclosure are measured and calculated as mass emissions per 40 CFR §86.163

- 96. Vehicle testing in an RL

- SHED is complicated by several factors, including:

1. The engine must be supplied with external induction ai r. 2. The exhaust must be conducted externally without any leaks. 3. The load supplied to the vehicle through the chassis dynamometer must not create or allow external leaks. 4. The internal SHED temperature must be maintained while sizable heat is reje cted to the ambient by the running engine and exhaust. Figure A

- 9 . Running Loss SHED

## B

- 6 5. The cooling air supplied to the radiator must be modulated to represent the vehicle’s road speed. 6. The underbody (and especially the fuel system) temperature should represent the rate of rise ex perienced by a real road

- drive.

Canister vent losses were isolated from permeation emissions using the technique described previously. The vehicle’s carbon canister fresh air vent was connected to the outside of the RL

SHED using a leak

- tight Teflon ® 

## hos e connected to a small carbon “trap” canister located on a top

- loading precision scale. The scale precision was 0.01 grams (10 milligrams). There were no tank venting emissions measured on any of the running loss test measurements. All of the vehicles a ppeared to be actively “purging” the vehicle’s control canister and drawing fresh air during the test. If there were any emissions from the vehicle’s canister, as might have occurred if there were no vehicle purge or if very high volatility fuels with exc essive vapor generation were used, it would have been measured.

The Running Loss Driving Cycle consisted of two cycles of the “Unified Driving Cycle,” otherwise known as the LA

- 92. A velocity versus time plot for one cycle is shown in Figure A

10.

The LA

- 92 cycle takes 24 minutes to complete, and covers 9.8 miles, with many speed changes. Two back

- to

- back cycles were driven, the first as a “cold start,” and the second following a 30 second vehicle idle. The “cold start” condition was created by soaking the vehicle for a minimum of 18 hours at 86°F, moving it to the stabilized 86°F RL

- SHED, making the test connections, and then waiting a minimum of one hour before the initial start and run.

The SHED emis sions were measured during the 48 minutes of engine operation, and then continuously for one hour after the engine was turned off. This one hour, engine

- off duration was the “hot soak” period. The total test time is 1 hour and 48 minutes. Fig ure A

- 10. Running Loss Driving Cycle Unified Cycle (LA-92)

0 10 20 30 40 50 60 70 80

0 5 10 15 20 25 Test Time - minutesSpeed - mph Cycle Time (min) 23.9 Maximum Speed (mph) 67.2 Average Speed (mph) 24.6 Average Non-Zero Speed (mph) 29.4 Time @ Zero Speed (%) 16.2 Distance (miles) 9.82

## B

- 7 Figure A

- 11 sho ws results from the 9 psi E0 fuel test on Vehicle 204. The horizontal axis is test time in minutes, and the vertical axis is the HC mass measured in the RL

- SHED during the test period.

The engine was shut off at the end of the second LA92 drive cycle ( ~48 minutes), and the analysis system continued to measure the HC emissions in the SHED for the next 60 minutes. This represented the “hot soak” portion of the test.

The “True” Hot Soak

The traditional hot soak is determined from the increase in SHED emissions as measured for one hour following a prescribed drive to heat up the vehicle (2 LA

- 92 cycles during the Running Loss Test) . Hot soak emissions, however, have two components: that caused by the elevate d temperature resulting from the drive, and that resulting from one hour of static permeation.

To separate these two components and determine the “true” hot soak emissions, the following procedure was used. “Traditional” hot soak emissions were first cal culated by subtracting the “start of hot soak” cumulative SHED HC value (i.e., 199 mg @ t = 48 minutes) from the final cumulative SHED HC value (i.e., 277.4 mg @ t = 108 min.). This resulted in a cumulative SHED HC value of 78 mg for the 1 hour hot soak. The previously determined static permeation value (i.e., 33.8 mg for a 1 hour hot soak test

- see Figure A

- 8) was then subtracted to arrive at the “true” hot soak value of 44.2 mg.

In Figure A

- 11, the static permeation rate is superimposed as a solid bl ue line on the plot from the starting point of the hot soak until its end (one hour). While the “traditional” hot soak would 0 50 100 150 200 250 300

0 20 40 60 80 100 120Corrected Total Fuel Cumulative Permeation-mg

Test Time

- minutes Running Loss and Hot Soak Vehicle 204

- 1999 Honda Accord

- 9 psi E0 Fuel

Test 25668 Running Loss Hot Soak

Running Loss Std. =0.05 g/mi This Test = 0.010 g/mi


### 

RL = 249 mg/hr 277.4

233.2 Tru HS = 44.2

199.0



## Figure A

- 11. Running Loss Test

## B

- 8 be calculated as 78 mg (277 mg

– 199 mg), the “true” hot soak is determined as 44.2 mg (277.4 mg

- 233.2 mg). True hot soak value s reported here were determined in this manner.

Diurnal Test

Diurnal permeation wa s determined by subjecting the vehicle to a three

- day period in a temperature

- controlled SHED while continuously recording the total HC every 30 seconds. The SHED environmental temperature wa s varied from 65° F to 105°F per the California Diurnal Test protocol. Canister vent losses were isolated from permeation emissions using the technique described previously. The vehicle’s carbon canister fresh air vent was conne cted to the outside of the RL

- SHED using a leak

- tight Teflon ® 

## hose connected to a small carbon “trap” canister located on a top

- loading precision scale. The scale precision was 0.01 grams (10 milligrams).


## ATL’s Speciation Method

ATL has developed a h ydrocarbon speciation method that is functionally equivalent to the dual

- gas chromatograph (GC) AQIRP method. The AQIRP, or “Auto/Oil Program,” test method was first documented in two SAE papers,

1. SAE 920320, Advanced Emission Speciation Methodologies for the Auto/Oil Air Quality Improvement Research Program

- I. Hydrocarbons and Ethers; and

2. SAE 920321, Advanced Emissions Speciation Methodologies for the Auto/Oil Air Quality Improvement Research Program

– II. Aldehydes, Ketones, and Alcohols
A later upda te to the HC and Oxygenates procedures was published as:

SAE 930142, Improved Emissions Speciation Methodology for Phase II of the Auto/Oil Air Quality Improvement Research Program

-- Hydrocarbons and Oxygenates

(See also, for reference, ARB’s SOP NO. MLD 115, “Procedure for the Determination of Ethers and Alcohols in Gasoline by Gas Chromatography”, January 2003, and SOP NO. MLD 118, “Procedures for the Detailed Hydrocarbon Analysis of Gasolines by Single Column High Efficiency (Capillary) Column Gas Chromatography”, August 1997).

Instrumentation demands are simplified, and overall analysis time is shortened; yet high resolution and sensitivity are still achieved. In this single

- GC/dual column method, all compon ents are separated using on column type and temperature program. Analysis time for a cycle is 65 minutes. Each exhaust or evaporative gas sample is simultaneously injected (using a single sampling from the bag) into two identical columns present in the G C. A Varian Model 3400 GC is used for HC analysis. The GC is equipped with a dual temperature

- controlled Valco 6

- port valve injector; dual flame ionization detectors (FID), and dual 60 meter x 0.32

- mm ID fused silica capillary columns with 1.0μ polydimet hylsiloxane stationary phase (J&W DB

- 1). One of the injectors uses an 85 μL sampling loop for low sensitivity analysis of C 1 

## - C 12 

## while the other injector either uses a 1000 μL loop for high sen sitivity analysis of C 4 

## - C 12 

## (for simultaneous low/high sensit ivity analysis of a single bag sample). Column A contains an 85μl sample loop (splitless injection) that provides an injection volume that is small enough to allow resolution of the C1 through C4 hydrocarbons while large enough to retain the highest sensi tivity possible.

## B

- 9 Column B receives a 1000μl splitless injection, providing higher sensitivity for components eluting after isobutane. Quantitative comparison of two overlap components (butane and isopentane) provides a quality control measure. Data from Column A is used to detect and quantitate the 12 earliest eluting hydrocarbons with detection limits of 15

- 25 ppb v 

## C corresponding to 0.2

- 0.3 mg/mi hydrocarbon for FTP stages 1 and 3, and 0.3

- 0.5 mg/mi for FTP stage 2. Data from Column B gives detection l imits 0.017

- 0.04 mg/mi HC for components eluting after isopentane (18 th 

## in elution order). The components eluting between the 9 th 

## and 18 th 

## in elution order have detection limits ranging between the levels listed above for each column.

The advantage of th is approach is that, even for relatively clean vehicles, essentially all of the first 12 species are typically present at levels exceeding the Column A detection limit. Those speciated components that are below the first column detection limit tend to be in the molecular weight range best suited for the 1000μl injection analysis, which provides the limits 0.017

- 0.04 mg/mi HC for components eluting after isopentane (18 th 

## in elution order), where additional sensitivity is needed. In previous work that appli ed this analysis approach, detection limits were determined to be between 0.02

- 0.06 mg/mi for the toxics 1,3

- butadiene and benzene. ATL’s hydrocarbon method uses Varian 3600 GCs with dual injectors, columns, and flame ionization detectors, allowing two sim ilar analyses to be run simultaneously, as mentioned above. A Varian Star PC

- based (using Microsoft Windows TM 

## ) data system is used for data acquisition. Custom

- made software is used for peak identification and converting data into a Microsoft Excel TM 

## sprea dsheet format. A comparison of the total hydrocarbon determined using the GC versus the CVS (“speciation recovery”) is used as a quality control measure, and ATL routinely achieves hydrocarbon speciation recoveries ranging from 93% to 105% for lower emitt ing vehicles. A 23 hydrocarbon component standard mixture is analyzed at the start of each day on each GC to provide quantifying coefficients and a quality control check on daily reproducibility of instrument performance.

## APPENDIX C

FUEL INSPECTION S

## C

- 1 

## TABLE C

- 2. CRC E

- 77

- 2b FUEL INSPECTIONS

E0 E10 Inspection Units Fuel 6 Fuel 7

API Gravity °API 60.2 58.5

Relative Density 60/60°F 0.7381 0.7447

DVPE psi 6.95 7.30

Oxygenates--D4815 MTBE vol % 0.00 0.00 ETBE vol % 0.00 0.00 EtOH vol % 0.00 9.54 O2 wt % 0.00 3.53 Hydrocarbon Composition Aromatics vol % 22.1 24.4 Olefins vol % 8.0 8.8 Saturates vol % 70.0 57.3

D86 Distillation IBP °F 99.9 104.0 5% Evaporated °F 131.9 128.0 10% Evaporated °F 142.4 133.0 20% Evaporated °F 156.5 141.0 30% Evaporated °F 170.6 145.0 40% Evaporated °F 184.3 153.0 50% Evaporated °F 197.9 195.0 60% Evaporated °F 212.4 219.0 70% Evaporated °F 231.1 241.0 80% Evaporated °F 259.4 271.0 90% Evaporated °F 313.6 317.0 95% Evaporated °F 331.7 330.0 EP °F 361.0 360.0 Recovery vol % 97.8 97.8

Residue vol % 1.3 1.0 Loss vol % 1.0 1.2

Driveability Index 1120.7 1101.5 

# CRC E-77-2b Fuel Inspections
Data from CRC E-74

## C

- 2 

## TABLE C

- 2 (CONT'D). CRC E

- 77

- 2b FUEL INSP ECTIONS

Fuel Units Fuel 6 Fuel 7 Sulfur Content ppm 29 27 Estimated C/H Ratio 6.2090 6.3323 Est. Net Heat of Combustion btu/lb 18573 18514 Benzene vol % 0.90 1.00 Research Octane Number 93.2 94.0 Motor Octane Number 83.8 83.8 (R+M)/2 88.5 88.9

Fuel Units Fuel 6 Fuel 7 Aromatics vol % 23.86 24.81 Olefins vol % 7.52 8.92 Saturates vol % 67.43 56.21 Unclassified vol % 1.15 0.86 Ethanol vol % 0.00 9.20 Benzene vol % 0.89 1.06 C/H Ratio 6.200 6.092 Oxygen wt. % 0.008 1 3.40 Net Heat of Combustion btu/lb 18,703 18,016

1 Contains 0.04 vol % MTBE

Fuel Units Fuel 6 Fuel 7 Oxygen wt. % 0.008 3.396 C+H wt. % 99.99 96.60 H wt. % 13.89 13.62 C wt. % 86.10 82.98

Fuel Units 6 7 Haltermann D3338 Btu/lb 18,573 18,514 Average D3338 Btu/lb 18,578 18,514 Oxygen Corrected D3338 Btu/lb 18,578 17,860 DHA Btu/lb 18,703 18,016 

### Carbon, Hydrogen, and Oxygen

Net Heat of Combusion -- Btu/lb Suppliers Additional Inspections

Detailed Hydrocarbon Analysis

## APPENDIX D

SUMMARY OF E

- 77

- 2B PROGRAM TEST RESULTS AND INDIVIDUAL VEHICLE EVAPORATIVE TEST RESULTS

## D

- 1 TABLE D

- 1. CRC E

- 77

- 2b PROGRAM TEST RESULTS

Vehicle Day 1 Day 2 Day 3

No. Fuel 86o F Leaks 105o F Leaks RL TEFVO Perm (Brkthru) Perm (Brkthru) Perm (Brkthru)

E10 - 10 psi 124.9 0.0 314.1 0.0 546.5 165.1 2777 (20.0) 31005 (14.7) 43028 (8.6) E10 - 7 psi 149.3 0.0 307.9 0.0 436.7 174.9 2582.6 (0.0) 2258.5 (0.0) 2144.0 (1.87) E0 - 9 psi 61.1 0.0 178.8 0.0 365.6 102.5 1500.0 (0.0) 1285.6 (14.6) 1250.8 (30.7) E0 - 7 psi 52.0 0.0 118.1 0.0 245.1 68.8 1171.9 (0.0) 931.2 (0.0) 890.3 (1.3)

E10 - 10 psi 37.5 0.0 61.2 0.0 329.5 36.0 794.0 (0.0) 561.4 (5.1) 495.8 (21.7) E10 - 7 psi 27.2 0.0 51.8 0.0 254.7 77.3 780.6 (0.0) 510.4 (0.0) 449.4 (0.0) E0 - 9 psi 37.2 0.0 55.0 9.1 228.0 37.9 777.0 (0.0) 567.2 (0.0) 519.4 (0.0) E0 - 7 psi 24.8 0.0 64.5 0.0 124.9 75.0 422.1 (11.3) 419.4 (9.7) 476.0 (9.2)

E10 - 10 psi 28.8 0.0 73.3 0.0 323.6 113.7 535.5 (0.0) 423.5 (0.0) 475.5 (13.0) E10 - 7 psi 28.6 0.0 54.1 0.0 205.7 24.5 383.1 (0.0) 349.1 (0.0) 323.5 (0.0) E0 - 9 psi 23.4 5.8 29.5 0.0 144.4 5.0 327.8 (0.0) 250.5 (0.0) 224.3 (0.0) E0 - 7 psi 16.8 1.9/7.9 28.8 0.0 166.2 16.8 354.1 (0.0) 249.7 (0.0) 218.1 (0.0)

E10 - 10 psi 19.9 0.0 70.1 34.1 147.5 60.6 486.5 (8.0) 458.3 (28.3) 441.3 (34.8) E10 - 7 psi 29.9 0.0 51.9 23.2 218.3 61.8 445.1 (0.0) 388.3 (0.0) 359.1 (0.0) E0 - 9 psi 21.2 4.0 33.5 4.8 171.1 19.8 407.8 (0.0) 377.4 (0.0) 358.3 (30.9) E0 - 7 psi 18.7 0.0 35.5 0.0 216.0 49.0 270.6 (0.0) 266.6 (0.0) 221.1 (0.1)

E10 - 10 psi 39.2 0.0 106.8 0.0 130.9 0.9 650.6 (0.0) 615.4 (0.0) 700.7 (1.6) E10 - 7 psi 29.6 0.0 82.2 0.0 243.1 60.5 602.8 (0.0) 577.7 (0.0) 588.9 (0.0) E0 - 9 psi 14.7 0.0 34.5 0.0 203.1 14.5 346.3 (0.0) 328.4 (0.0) 292.8 (0.0) E0 - 7 psi 21.1 0.0 35.3 0.0 135.1 12.2 357.8 (0.0) 283.3 (0.0) 276.5 (0.0)

E10 - 10 psi 3.7 0.0 7.4 8.3 73.1 0.0 104.1 (1.7) 79.7 (16.0) 73.4 (30.2) E10 - 7 psi 12.1 0.0 16.3 0.0 67.1 0.0 99.6 (0.0) 104.0 (0.0) 84.0 (0.0) E0 - 9 psi 3.1 0.0 5.8 0.0 45.5 0.0 77.4 (0.0) 41.9 (0.0) 57.9 (0.0) E0 - 7 psi 3.4 0.0 6.4 0.0 128.8 5.4 58.6 (0.0) 39.0 (0.0) 38.8 (0.0)

Tier 1 Vapor Leak Near Zero Liquid Leak Zero Evap 206b 2002 Nisan Altima

208b 2002 Chevrolet Trailblazer

209b 2004 Chrysler Stratus

210b 2004 Chevrolet

Impala

213b 2004 Dodge Ram 1500

222b 2004 Ford Focus Diurnal (65o to 105o) - mg/day Static Permeation - mg/hr Dynamic Perm. - mg/hr

## D

- 2 Individual Vehicle Evaporative Performance on the Various Fuels

Vehicle 206b

– 2002 Nissan Altima

SHED Corrected Results Canister Fuel Permeation mg/day Loss Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g 206b 10.0/E10 Static (86) Perm 01/28/09 7456 124.9 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 01/29/09 7459 314.1 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Dynamic RL 01/30/09 25753 546.5 0.00 TEFVO 165.1 10.59
72 DHB 65-105 03/03/09 7476

Day 1 2776.6 20.00 Day 2 31004.6 14.70 Day 3 43028.2 8.60

7.0/E10 Static (86) Perm 03/11/09 7484 149.3 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 03/12/09 7487 307.9 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Dynamic RL 03/13/09 25760 436.7 0.00 TEFVO 174.9 0.31
72 DHB 65-105 03/24/09 7495

Day 1 2582.6 0.00 Day 2 2258.5 0.00 Day 3 2144.0 1.87

9.0/E0 Static (86) Perm 05/06/09 7539 61.1 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 05/07/09 7545 178.8 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Dynamic RL 05/08/09 25775 365.6 0.00 TEFVO 102.5 0.00
72 DHB 65-105 05/19/09 7551

Day 1 1500.0 0.00 Day 2 1285.6 14.60 Day 3 1250.8 30.70

## D

- 3 7.0/E0 Static (86) Perm 06/02/09 7561 52.0 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0

Static (105) Perm 06/03/09 7563 118.1 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0

Dynamic RL 06/04/09 25780 245.1 0.00 "True" HS 68.8 0.13

72 DHB 65-105 06/09/09 7567

Day 1 1171.9 0.00 Day 2 931.2 0.00 Day 3 890.3 1.30

## D

- 4 Vehicle 206b

– 2002 Nissan Altima

0 50 100 150 200 250 300

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 86 F Permeation Vehicle 206b

- 2002 Nissan Altima

10 psi E10

- 7456
7 psi E10

- 7484
9 psi E0

- 7539
7 psi E0

- 7561

0 100 200 300 400 500 600 700

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 105 F Permeation Vehicle 206b

- 2002 Nissan Altima

10 psi E10

- 7459
7 psi E10

- 7487
9 psi E0

- 7545
7 psi E0

- 7563

## D

- 5 Vehicle 206b

– 2002 Nissan Altima (cont.)

0 100 200 300 400 500 600 700 800

0 20 40 60 80 1005 min Running Avg.Cumulative Permeation-mg

Test Time

- minutes Running Loss and Hot Soak Vehicle 206b

- 2002 Nissan Altima

10 psi E10

- 25753
7 psi E10

- 25760
9 psi E0

- 7545
7 psi E0 Running Loss Hot Soak

0 10000 20000 30000 40000 50000 60000 70000 80000 90000

0 10 20 30 40 50 60 70Cumulative Permeation-mg.

Test Time

- hrs. Three Day Diurnal Vehicle 206b

- 2002 Nissan Altima

10 psi E10

- 7476
7 psi E10

- 7495
9 psi E0

- 7551
7 psi E0

- 7567

## D

- 6 Vehicle 20 8 b

– 2002 Chevrolet Trailblazer

SHED Corrected Results Canister Fuel Permeation mg/day Loss Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g 208b 10.0/E10 Static (86) Perm 12/18/08 7413 37.5 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 12/19/08 7415 61.2 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Dynamic RL 01/16/09 25744 329.5 0.00 TEFVO 36.0 0.00
72 DHB 65-105 02/10/09 7463

Day 1 795.0 0.00 Day 2 561.4 5.10 Day 3 495.8 21.70

7.0/E10 Static (86) Perm 03/04/09 7478 27.2 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 03/05/09 7480 51.8 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Dynamic RL 03/06/09 25759 254.7 0.00 TEFVO 77.3 0.00
72 DHB 65-105 03/17/09 7489

Day 1 780.6 0.00 Day 2 510.4 0.00 Day 3 449.4 0.00

9.0/E0 Static (86) Perm 04/28/09 7530 37.2 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 04/29/09 7532 55.0 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 9.1 Dynamic RL 05/01/09 25771 228.0 0.00 TEFVO 37.9 0.00
72 DHB 65-105 05/27/09 7556

Day 1 778.0 0.00 Day 2 567.2 0.00 Day 3 519.4 0.00

## D

- 7 7.0/E0 Static (86) Perm 06/09/09 7568 24.8 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0

Static (105) Perm 06/10/09 7570 64.5 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0

Dynamic RL 06/11/09 25782 124.9 0.00 TEFVO 75.0 0.00

72 DHB 65-105 06/16/09 7575

Day 1 422.1 11.30 Day 2 419.4 9.70 Day 3 476.0 9.20

## D

- 8 Vehicle 208b

– 2002 Chevrolet Trailblazer

0 10 20 30 40 50 60 70 80

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 86 F Permeation Vehicle 208b

- 2002 Chevrolet Trailblazer

10 psi E10

- 7413 7 psi E10

- 7578 9 psi E0

- 7530 7 psi E0

- 7568

0 20 40 60 80 100 120 140

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 105 F Permeation Vehicle 208b

- 2002 Chevrolet Trailblazer

10 psi E10

- 7415 7 psi E10

- 7480 9 psi E0

- 7532 7 psi E0

- 7570

## D

- 9 Vehicle 20 8 b

– 2002 Chevrolet Trailblazer (cont.)

0 50 100 150 200 250 300 350

0 20 40 60 80 1005 min Running Avg.Cumulative Permeation-mg

Test Time

- minutes Running Loss and Hot Soak Vehicle 208b

- 2002 Chevrolet Trailblazer

10 psi E10

- 25744

7 psi E10

- 25759

9 psi E0

- 25771

7 psi E0

- 25782 Running Loss Hot Soak

0 500 1000 1500 2000 2500

0 10 20 30 40 50 60 70Cumulative Permeation-mg.

Test Time

- hrs. Three Day Diurnal Vehicle 208b

- 2002 Chevrolet Trailblazer

10 psi E10

- 7463

7 psi E10

- 7489

9 psi E0

- 7556

7 psi E0

- 7575

## D

- 10 Vehicle 209b

– 2004 Chrysler Stratus

SHED Corrected Results Canister Fuel Permeation mg/day Loss Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g 209b 10.0/E10 Static (86) Perm 12/30/08 7423 28.8 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 12/31/08 7424 73.3 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Dynamic RL 01/08/09 25742 323.6 0.00 TEFVO 113.7 0.00
72 DHB 65-105 02/03/09 7461

Day 1 535.5 0.00 Day 2 423.5 0.00 Day 3 475.5 13.01

7.0/E10 Static (86) Perm 02/12/09 7466 28.6 0 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 02/13/09 7467 54.1 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Dynamic RL 02/17/09 25755 205.7 0.14 TEFVO 24.5 0.00
72 DHB 65-105 02/24/09 7472

Day 1 383.1 0.00 Day 2 349.1 0.00 Day 3 323.5 0.00

9.0/E0 Static (86) Perm 04/01/09 7501 23.4 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 5.8 Static (105) Perm 04/02/09 7504 29.5 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Dynamic RL 04/03/09 25761 144.4 0.00 TEFVO 5.0 0.00
72 DHB 65-105 04/07/09 7508

Day 1 327.8 0.00 Day 2 250.5 0.00 Day 3 224.3 0.00

## D

- 11 7.0/E0 Static (86) Perm 04/22/09 7524 16.8 0.00 Press. Incr. 1.9 Prs+Fuel Incr. 7.9

Static (105) Perm 04/23/09 7527 28.8 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0

Dynamic RL 04/24/09 25768 166.2 0.00 TEFVO 16.8 0.00

72 DHB 65-105 04/29/09 7533

Day 1 354.1 0.00 Day 2 249.7 0.00 Day 3 218.1 0.00

## D

- 12 Vehicle 209b

– 2004 Chrysler Stratus

0 10 20 30 40 50 60

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 86 F Permeation Vehicle 209b

- 2004 Chrysler Stratus

10 psi E10

- 7423
7 psi E10

- 7466
9 psi E0

- 7501
7 psi E0

- 7524

0 20 40 60 80 100 120 140 160 180

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 105 F Permeation Vehicle 209b

- 2004 Chrysler Stratus

10 psi E10

- 7424

7 psi E10

- 7467

9 psi E0

- 7504

7 psi E0

- 7527

## D

- 13 Vehicle 20 9 b

– 200 4 Chrysler Stratus (cont.)

0 50 100 150 200 250 300 350 400 450

0 20 40 60 80 1005 min Running Avg.Cumulative Permeation-mg

Test Time

- minutes Running Loss and Hot Soak Vehicle 209b

- 2004 Chrysler Stratus

10 psi E10

- 25742
7 psi E10

- 25755
9 psi E0

- 25761
7 psi E0

- 25768

Running Loss Hot Soak

0 200 400 600 800 1000 1200 1400 1600

0 10 20 30 40 50 60 70Cumulative Permeation-mg.

Test Time

- hrs. Three Day Diurnal Vehicle 209b

- 2004 Chrysler Stratus

10 psi E10

- 7461
7 psi E10

- 7472
9 psi E0

- 7508
7 psi E0

- 7533

7 psi E0 Test : Shared Innova

- Permeation shown is raw SHED

.

## D

- 14 Vehicle 210b

– 2004 Chevrolet Impala

SHED Corrected Results Canister Fuel Permeation mg/day Loss Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g 210b 10.0/E10 Static (86) Perm 01/20/09 7449 19.9 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 01/21/09 7451 70.1 2.87 Press. Incr. 0.0 Prs+Fuel Incr. 34.1 Dynamic RL 01/23/09 25749 147.5 0.00 TEFVO 60.6 0.00
72 DHB 65-105 02/04/09 7462

Day 1 486.5 8.00 Day 2 458.3 28.30 Day 3 441.3 34.80

7.0/E10 Static (86) Perm 02/18/09 7468 29.9 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 02/19/09 7471 51.9 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 23.2 Dynamic RL 02/23/09 25756 218.3 0.14 TEFVO 61.8 0.03
72 DHB 65-105 03/10/09 7482

Day 1 445.1 0.00 Day 2 388.3 0.00 Day 3 359.1 0.00

9.0/E0 Static (86) Perm 04/21/09 7523 21.2 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 4.0 Static (105) Perm 04/22/09 7525 33.5 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 4.8 Dynamic RL 04/23/09 25767 171.1 0.00 TEFVO 19.8 0.00
72 DHB 65-105 04/28/09 7531

Day 1 407.8 0.00 Day 2 377.4 0.00 Day 3 358.3 30.91

## D

- 15 7.0/E0 Static (86) Perm 05/13/09 7547 18.7 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0

Static (105) Perm 05/14/09 7549 35.5 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0

Dynamic RL 04/15/09 25776 216.0 0.00 TEFVO 49.0 0.00

72 DHB 65-105 05/19/09 7550

Day 1 270.6 0.00 Day 2 266.6 0.00 Day 3 221.1 0.11

## D

- 1 6 Vehicle 210b

– 2004 Chevrolet Impala

0 10 20 30 40 50 60 70

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 86 F Permeation Vehicle 210b

- 2004 Chevrolet Impala

10 psi E10

- 7449
7 psi E10

- 7468
9 psi E0

- 7523
7 psi E0

- 7547

0 20 40 60 80 100 120 140 160

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 105 F Permeation Vehicle 210b

- 2004 Chevrolet Impala

10 psi E10

- 7451
7 psi E10

- 7471
9 psi E0

- 7525
7 psi E0

- 7549

## D

- 17 Vehicle 2 10 b

– 200 4 Chevrolet Impala (cont.)

0 50 100 150 200 250 300

0 20 40 60 80 1005 min Running Avg.Cumulative Permeation-mg

Test Time

- minutes Running Loss and Hot Soak Vehicle 210b

- 2004 Chevrolet Impala

10 psi E10

- 25749
7 psi E10

- 25756
9 psi E0

- - 25767
7 psi E0

- 25776

Running Loss Hot Soak

0 200 400 600 800 1000 1200 1400 1600

0 10 20 30 40 50 60 70Cumulative Permeation-mg.

Test Time

- hrs. Three Day Diurnal Vehicle 210b

- 2004 Chevrolet Impala

10 psi E10

- 7462
7 psi E10

- 7482
9 psi E0

- 7531
7 psi E0

- 7550

## D

- 18 Vehicle 213b

– 2004 Dodge Ram 1500

SHED Corrected Results Canister Fuel Permeation mg/day Loss Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g 213b 10.0/E10 Static (86) Perm 01/14/09 7442 39.2 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 01/15/09 7446 106.8 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Dynamic RL 01/26/09 25750 130.9 0.00 TEFVO 0.9 0.00
72 DHB 65-105 01/06/09 7429

Day 1 650.6 0.00 Day 2 615.4 0.00 Day 3 700.7 1.60

7.0/E10 Static (86) Perm 02/11/09 7464 29.6 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 02/12/09 7465 82.2 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Dynamic RL 02/13/09 25754 243.1 0.00 TEFVO 60.5 0.00
72 DHB 65-105 02/25/09 7473

Day 1 602.8 0.00 Day 2 577.7 0.00 Day 3 588.9 0.00

9.0/E0 Static (86) Perm 04/07/09 7506 14.7 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 04/08/09 7507 34.5 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Dynamic RL 04/09/09 25764 203.1 0.61 TEFVO 14.5 0.00
72 DHB 65-105 04/14/09 7516

Day 1 346.3 0.00 Day 2 328.4 0.00 Day 3 292.8 0.00

## D

- 19 7.0/E0 Static (86) Perm 04/23/09 7526 21.1 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0

Static (105) Perm 04/24/09 7528 35.3 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0

Dynamic RL 04/27/09 25769 135.1 0.00 TEVFO 12.2 0.00

72 DHB 65-105 05/05/09 7538

Day 1 357.8 0.00 Day 2 283.3 0.00 Day 3 276.5 0.00

## D

- 20 Vehicle 213b

– 2004 Dodge Ram 1500

0 10 20 30 40 50 60 70 80

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 86 F Permeation Vehicle 213b

- 2004 Dodge Ram 1500

10 psi E10

- 7442
7 psi E10

- 7464
9 psi E0

- 7506
7 psi E0

- 7526

0 50 100 150 200 250

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 105 F Permeation Vehicle 213b

- 2004 Dodge Ram 1500

10 psi E10

- 7446

7 psi E10

- 7465

9 psi E0

- 7507

7 psi E0

- 7528

## D

- 21 Vehicle 2 1 3 b

– 200 4 Dodge Ram 1500 (cont.)

0 50 100 150 200 250 300

0 20 40 60 80 1005 min Running Avg.Cumulative Permeation-mg

Test Time

- minutes Running Loss and Hot Soak Vehicle 213b

- 2004 Dodge Ram 1500

10 psi E10

- 25750
7 psi E10

- 25754
9 psi E0

- 25764
7 psi E0

- 25769

Running Loss Hot Soak

0 500 1000 1500 2000 2500

0 10 20 30 40 50 60 70Cumulative Permeation-mg.

Test Time

- hrs. Three Day Diurnal Vehicle 213b

- 2004 Dodge Ram 1500

10 psi E10

- 7429
7 psi E10

- 7473
9 psi E0

- 7516
7 psi E0

- 7538

## D

- 22 Vehicle 221b

- 2000 Mitsubishi Galant

2000 Mitsubishi Galant SHED Corrected Results Canister Fuel Permeation mg/day Loss Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g 221b 10.0/E10 Static (86) Perm 05/27/09 7557 38.9 0.00 Press. Incr. 1568.7 Prs+Fuel Incr. 1693.9 Static (105) Perm 05/28/09 7559 80.2 0.00 Press. Incr. 1932.6 Prs+Fuel Incr. 2147.1

"True" HS 26.9 0.00

72 DHB 65-105 06/02/09 7562

Day 1 827.9 2.00 Day 2 724.1 5.40 Day 3 702.4 21.80

7.0/E10 Static (86) Perm 06/10/09 7571 22.7 0.00 Press. Incr. 930.7 Prs+Fuel Incr. 971.0

Static (105) Perm 06/11/09 7572 61.4 0.00 Press. Incr. 1282.3 Prs+Fuel Incr. 1408.5 Dynamic RL 06/12/09 25783 102.0 0.00 "True" HS 40.5 0.00

Day 1 894.7 0.00 Day 2 676.7 0.00 Day 3 618.0 0.00

9.0/E0 Static (86) Perm 08/20/09 7650 55.6 0.00 Prs+Fuel Incr. 1406.0

Static (105) Perm 08/21/09 7652 94.8 0.00 Press. Incr. 1646.7 Prs+Fuel Incr. 1788.2

Dynamic RL 08/24/09 25790 135.2 0.00 "True" HS 29.0 0.00

72 DHB 65-105 09/01/09 7667

Day 1 706.4 0.30 Day 2 543.7 2.60 Day 3 538.3 9.30

## D

- 23 7.0/E0 Static (86) Perm 09/17/09 7691 35.9 0.00 Press. Incr. 988.8 Prs+Fuel Incr. 961.8

Static (105) Perm 09/18/09 7692 66.8 0.00 Press. Incr. 1215.9 Prs+Fuel Incr. 1343.8

Dynamic RL 09/22/09 25797 189.8 0.00 "True" HS 42.5 0.00

72 DHB 65-105 10/07/09 7716

Day 1 603.0 0.00 Day 2 503.1 0.00 Day 3 487.0 0.00

## D

- 24 0 200 400 600 800 1000 1200 1400 1600

0 20 40 60 80 100 1205 min Running Avg.Corrected SHED Mass-mg

Test Time

- minutes 

### Static 86 F Permeation Vehicle 221b

- 2000 Mitsubishi Galant

10 psi E10

- 7557
7 psi E10

- 7571
9 psi E0

- 7650
7 psi E0

- 7691

0 500 1000 1500 2000

0 20 40 60 80 100 1205 min Running Avg.Corrected SHED Mass-mg

Test Time

- minutes 

### Static 105 F Permeation Vehicle 221b

- 2000 Mitsubishi Galant

10 psi E10

- 7559
7 psi E10

- 7572
9 psi E0

- 7652
7 psi E0

- 7692

## D

- 25 0 50 100 150 200 250

0 20 40 60 80 1005 min Running Avg.Cumulative Permeation-mg

Test Time

- minutes 

### Running Loss and Hot Soak Vehicle 221b

- 2000 Mitsubishi Galant

10 psi E10

- 25778

7 psi E10

- 25783

9 psi E0

- 25790

7 psi E0

- 25797

Running Loss Hot Soak

0 500 1000 1500 2000 2500

0 10 20 30 40 50 60 70Cumulative Permeation-mg.

Test Time

- hrs. 

### Three Day Diurnal Vehicle 221b

- 2000 Mitsubishi Galant

10 psi E10

- 7562
7 psi E10

- 7579
9 psi E0

- 7667
7 psi E0

- 7716

## D

- 26 Vehicle 222b

– 2004 Ford Focus

SHED Corrected Results Canister Fuel Permeation mg/day Loss Veh psi/EtOH Test Type Date Test# mg/hr (Corrected) g 222b 10.0/E10 Static (86) Perm 05/20/09 7552 3.7 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 05/21/09 7554 7.4 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 8.3 Dynamic RL 06/03/09 25779 73.1 0.00 TEFVO 0.0 0.00
72 DHB 65-105 05/27/09 7558

Day 1 104.1 1.70 Day 2 79.7 16.00 Day 3 73.4 30.20

7.0/E10 Static (86) Perm 06/17/09 7576 12.1 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Static (105) Perm 06/18/09 7578 16.3 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0 Dynamic RL 07/01/09 25785 61.7 0.00 TEFVO 0.0 0.00
72 DHB 65-105 06/23/09 7580

Day 1 99.6 0.00 Day 2 104.0 0.00 Day 3 84.0 0.00

9.0/E0 Static (86) Perm 08/25/09 7655 3.1 0.00 Press. Incr. 0.5 Prs+Fuel Incr. 4.0 Static (105) Perm 08/26/09 7659 5.8 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.5 Dynamic RL 08/27/09 25791 45.5 0.00 "True" HS 0.0 0.00
72 DHB 65-105 09/22/09 7696

Day 1 77.4 0.00 Day 2 41.9 0.00 Day 3 57.9 0.00

## D

- 27 7.0/E0 Static (86) Perm 10/06/09 7712 3.4 0.60 Press. Incr. 0.0 Prs+Fuel Incr. 0.0

Static (105) Perm 10/07/09 7715 6.4 0.00 Press. Incr. 0.0 Prs+Fuel Incr. 0.0

Dynamic RL 10/23/09 25808 128.8 0.00 "True" HS 5.4 0.00

72 DHB 65-105 10/27/09 7742

Day 1 58.6 0.00 Day 2 39.0 0.00 Day 3 38.8 0.00

## D

- 28 Vehicle 222b

– 2004 Ford Focus

0 5 10 15 20 25 30

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 86 F Permeation Vehicle 222b

- 2004 Ford Focus

10 psi E10

- 7552
7 psi E10

- 7576
9 psi E0

- 7655
7 psi E0

- 7712

0 5 10 15 20 25 30

0 20 40 60 80 100 1205 min Running Avg.Cumulative SHED Mass-mg

Test Time

- minutes Static 105 F Permeation Vehicle 222b

- 2004 Ford Focus

10 psi E10

- 7554

7 psi E10

- 7578

9 psi E0

- 7659

7 psi E0

- 7715

## D

- 29 Vehicle 2 22 b

– 200 4 Ford Focus (cont.)

0 10 20 30 40 50 60 70 80 90 100

0 20 40 60 80 1005 min Running Avg.Cumulative Permeation-mg

Test Time

- minutes Running Loss and Hot Soak Vehicle 222b

- 2004 Ford Focus

10 psi E10

- 25779 7 psi E10

- 25785 9 psi E0

- 25791 7 psi E0

- 25808

Running Loss Hot Soak

0 50 100 150 200 250 300 350

0 10 20 30 40 50 60 70Cumulative Permeation-mg.

Test Time

- hrs. Three Day Diurnal Vehicle 222b

- 2004 Ford Focus

10 psi E10

- 7558
7 psi E10

- 7580
9 psi E0

- 7696
7 psi E0

- 7742

## APPENDIX E

COMPLETE SPECIATION TEST RESULTS

– ALL E

- 77

- 2b VEHICLES

## E

- 1 Test Fuel Test No. Bag THC mg GC as % of THC GC VOC

mg Ozone mg Reactivity Species Present 86 ° F E10 - 10 psi 7456 247.0 100.8 249.1 885.1 3.553 71 Static E10 - 7 psi 7484 279.7 79.6 222.7 796.1 3.575 60 E0 - 9 psi 7539 123.3 99.5 122.8 511.2 4.164 55 E0 - 7 psi 7561 97.3 80.1 78.0 284.8 3.651 56

105 ° F E10 - 10 psi 7459 630.7 93.1 587.4 2085.4 3.550 86 Static E10 - 7 psi 7487 606.2 125.3 759.4 2686.3 3.538 84 E0 - 9 psi 7545 366.7 72.9 267.3 814.4 3.047 30 E0 - 7 psi 7563 234.6 85.9 201.5 854.3 4.241 30

Dynamic E10 - 10 psi 25753 727.2 87.3 634.7 2191.6 3.453 66 E10 - 7 psi 25760 673.6 90.0 606.0 2158.5 3.562 59 E0 - 9 psi 25775 456.1 76.8 350.1 1316.4 3.760 54 E0 - 7 psi 25780 316.9 78.8 249.7 987.9 3.956 52

DHB E10 - 10 psi 7476 76809.3 82.4 63303.9 148993.1 2.354 123 Total E10 - 7 psi 7495 6985.0 88.6 6189.7 21304.5 3.442 108 E0 - 9 psi 7551 4036.4 91.1 3677.3 11381.0 3.095 107 E0 - 7 psi 7567 2993.3 93.4 2797.0 8687.2 3.106 105 

## Vehicle 206b

## E

- 2 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 48.01 188.431 n-Butane 00106-97-8 1.08 28.79 31.008 Ethanol 00064-17-5 1.45 27.48 39.815 2-Methylbutane (Isopentane) 00078-78-4 1.35 16.98 23.013 n-Hexane 00110-54-3 1.13 11.59 13.154 Benzene 00071-43-2 0.69 8.67 6.020 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.40 49.622 2-Methyl-2-butene 00513-35-9 14.20 5.73 81.281 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.55 29.779 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 5.53 7.729 t-2-Pentene 00646-04-8 10.47 5.38 56.317 n-Pentane 00109-66-0 1.21 5.20 6.318 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.59 33.912 3-Methylpentane 00096-14-0 1.69 3.73 6.304 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.47 4.157 Methylcyclopentane 00096-37-7 2.05 2.99 6.132 c-2-Pentene 00627-20-3 10.28 2.89 29.663 Cyclohexane 00110-82-7 1.14 2.55 2.901 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.45 10.769 2,3-Dimethylbutane 00079-29-8 0.90 2.40 2.158 2-Methyl-1-butene 00563-46-2 6.38 2.26 14.412 n-Heptane 00142-82-5 0.97 2.05 1.976 Methylcyclohexane 00108-87-2 1.56 2.03 3.158 ortho-Xylene 00095-47-6 7.58 1.74 13.178 2-Methylpropane 00075-28-5 1.18 1.65 1.944 2,3-Dimethylpentane 00565-59-3 1.25 1.49 1.865 2,3,4-Trimethylpentane 00565-75-3 0.95 1.49 1.414 t-2-Hexene 04050-45-7 8.55 1.46 12.466 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.42 16.728 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.42 16.626 1-Methylcyclopentene 00693-89-0 12.45 1.40 17.471 2,4-Dimethylpentane 00108-08-7 1.46 1.35 1.964 c-2-Butene 00590-18-1 14.26 1.31 18.701 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.30 7.178 2-Methylhexane 00591-76-4 1.09 1.26 1.365 2-Methylheptane 00592-27-8 0.97 1.19 1.148 t-2-Butene 00624-64-6 15.20 1.13 17.156 n-Octane 00111-65-9 0.80 1.11 0.887 Ethylbenzene 00100-41-4 2.96 1.11 3.279 Cyclopentene 00142-29-0 6.69 1.08 7.194 3-Methyl-t-2-pentene 00616-12-6 11.66 1.03 11.983 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.99 3.172 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.95 6.256 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.89 7.065 Vehicle 206b - Fuel 10 psi E10 - 86 ° F Static - Test 7456 Non Zero Mass Species Sorted By VOC

## E

- 3 **continued**

Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 10 psi E10 - 86 ° F Static - Test 7456 Non Zero Mass Species Sorted By VOC

Indan 00496-11-7 3.23 0.87 2.825 3-Methyl-c-2-pentene 00922-62-3 12.52 0.84 10.507 2,4-Dimethylhexane 00589-43-5 1.61 0.84 1.341 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.80 4.248 2-Methyl-2-pentene 00625-27-4 11.03 0.77 8.489 Unknown #22

. 3.55 0.75 2.668 2,2,5-Trimethylhexane 03522-94-9 1.05 0.75 0.786 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.71 8.495 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.70 1.117 3-Methylheptane 00589-81-1 1.12 0.67 0.759 t-1,2-Dimethylcyclopentane 00822-50-4 3.55 0.67 2.393 1,4-Diethylbenzene 00105-05-5 4.39 0.67 2.943 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.65 5.111 c-1,3-Dimethylcyclohexane 00638-04-0 3.55 0.65 2.316 2,2-DiMeHexane 00590-73-8 0.94 0.63 0.595 n-Nonane 00111-84-2 0.68 0.60 0.409 c-1,3-Dimethylcyclopentane 02532-58-3 3.55 0.55 1.950 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.49 2.816 2,3,5-Trimethylhexane 01069-53-0 1.12 0.44 0.497 n-Decane 00124-18-5 0.59 0.43 0.256 2,2-Dimethylpentane 00590-35-2 1.04 0.41 0.424 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.40 2.857 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.37 0.405 2,2-Dimethylbutane 00075-83-2 1.11 0.34 0.378 Isopropylbenzene (Cumene) 00098-82-8 3.55 0.25 0.883 Unknown #1 3.55 0.20 0.728 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.18 1.861

Total 249.1 885.1 3.553

No MIR available, use weighted average of 3.5531

## E

- 4 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 109.41 429.434 Ethanol 00064-17-5 1.45 79.67 115.437 n-Butane 00106-97-8 1.08 60.47 65.121 2-Methylbutane (Isopentane) 00078-78-4 1.35 38.51 52.170 n-Hexane 00110-54-3 1.13 25.70 29.162 Benzene 00071-43-2 0.69 18.23 12.655 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 16.75 129.906 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 14.86 79.761 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 13.07 18.270 2-Methyl-2-butene 00513-35-9 14.20 12.49 177.237 t-2-Pentene 00646-04-8 10.47 11.85 124.115 n-Pentane 00109-66-0 1.21 11.80 14.341 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 10.54 77.838 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 8.58 10.285 3-Methylpentane 00096-14-0 1.69 8.57 14.486 Methylcyclopentane 00096-37-7 2.05 7.71 15.795 Cyclohexane 00110-82-7 1.14 6.66 7.578 2,3-Dimethylbutane 00079-29-8 0.90 5.96 5.355 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.80 25.486 c-2-Pentene 00627-20-3 10.28 5.69 58.531 2-Methyl-1-butene 00563-46-2 6.38 5.09 32.497 n-Propylbenzene 00103-65-1 1.96 4.72 9.255 ortho-Xylene 00095-47-6 7.58 4.50 34.080 1,3,5-Trimethylbenzene 00108-67-8 11.75 4.25 49.981 2,3,4-Trimethylpentane 00565-75-3 0.95 4.19 3.978 t-2-Butene 00624-64-6 15.20 4.15 63.096 n-Heptane 00142-82-5 0.97 4.01 3.876 2,3-Dimethylpentane 00565-59-3 1.25 3.98 4.972 Methylcyclohexane 00108-87-2 1.56 3.95 6.147 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.62 42.314 2-Methylhexane 00591-76-4 1.09 3.59 3.897 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.40 18.850 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 3.37 10.766 2,4-Dimethylpentane 00108-08-7 1.46 3.25 4.738 t-2-Hexene 04050-45-7 8.55 3.22 27.547 1-Methylcyclopentene 00693-89-0 12.45 2.97 37.042 2-Methylpropane 00075-28-5 1.18 2.90 3.408 Ethylbenzene 00100-41-4 2.96 2.70 8.013 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 2.46 13.032 c-2-Butene 00590-18-1 14.26 2.43 34.700 Cyclopentene 00142-29-0 6.69 2.41 16.094 n-Octane 00111-65-9 0.80 2.22 1.771 3-Methyl-t-2-pentene 00616-12-6 11.66 2.22 25.834 2,4-Dimethylhexane 00589-43-5 1.61 2.02 3.242 Vehicle 206b - Fuel 10 psi E10 - 105 ° F Static - Test 7459 Non Zero Mass Species Sorted By VOC

## E

- 5 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 10 psi E10 - 105 ° F Static - Test 7459 Non Zero Mass Species Sorted By VOC

3-Methyl-c-2-pentene 00922-62-3 12.52 1.96 24.488 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.90 22.685 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.71 11.279 2-Methyl-2-pentene 00625-27-4 11.03 1.64 18.090 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.47 2.354 1,4-Diethylbenzene 00105-05-5 4.39 1.35 5.927 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.30 10.350 n-Decane 00124-18-5 0.59 1.30 0.768 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.20 1.315 2,2-DiMeHexane 00590-73-8 0.94 1.19 1.118 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 1.14 8.556 2,3,5-Trimethylhexane 01069-53-0 1.12 1.07 1.200 3-Methylheptane 00589-81-1 1.12 1.06 1.195 Indan 00496-11-7 3.23 1.02 3.303 Unknown #22

. 3.55 0.91 3.248 2-Methylheptane 00592-27-8 0.97 0.86 0.834 t-1,2-Dimethylcyclopentane 00822-50-4 3.55 0.85 3.026 n-Nonane 00111-84-2 0.68 0.81 0.553 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.74 5.261 Ethylcyclohexane 01678-91-7 1.35 0.72 0.975 2,2,5-Trimethylhexane 03522-94-9 1.05 0.69 0.729 4-Methyloctane 02216-34-4 0.85 0.67 0.571 Isopropylbenzene (Cumene) 00098-82-8 3.55 0.66 2.350 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.61 2.367 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.57 4.492 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.53 3.086 3,3-Dimethylpentane 00562-49-2 1.12 0.52 0.587 Unknown #5 3.55 0.47 1.684 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 0.45 0.532 t-1,4-Dimethylcyclohexane 02207-04-7 3.55 0.43 1.513 c-1,3-Dimethylcyclopentane 02532-58-3 3.55 0.42 1.492 2,2-Dimethylbutane 00075-83-2 1.11 0.38 0.419 c-2-Heptene 06443-92-1 7.08 0.37 2.621 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.35 2.629 1,3-Diethylbenzene 00141-93-5 7.08 0.33 2.338 c-1,3-Dimethylcyclohexane 00638-04-0 3.55 0.33 1.154 1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 0.30 2.294 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.30 3.100 Styrene 00100-42-5 1.66 0.24 0.406 2,2-Dimethylpentane 00590-35-2 1.04 0.22 0.226 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.55 0.21 0.738 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.18 1.487

Total 587.4 2085.4 3.550

No MIR available, use weighted average of 3.5503 

### continued

## E

- 6 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 117.87 462.653 Ethanol 00064-17-5 1.45 77.41 112.160 n-Butane 00106-97-8 1.08 49.17 52.950 2-Methylbutane (Isopentane) 00078-78-4 1.35 26.52 35.927 n-Hexane 00110-54-3 1.13 24.76 28.090 Benzene 00071-43-2 0.69 22.18 15.398 n-Propylbenzene 00103-65-1 1.96 20.00 39.201 Unknown #22

. 3.45 17.66 60.998 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 17.56 94.271 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 17.10 132.635 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 12.68 93.657 2-Methyl-2-butene 00513-35-9 14.20 12.20 173.135 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 12.09 14.503 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 12.00 16.775 n-Pentane 00109-66-0 1.21 9.49 11.533 t-2-Pentene 00646-04-8 10.47 8.90 93.256 3-Methylpentane 00096-14-0 1.69 8.83 14.937 Methylcyclopentane 00096-37-7 2.05 8.46 17.345 Cyclohexane 00110-82-7 1.14 7.60 8.643 1,3,5-Trimethylbenzene 00108-67-8 11.75 7.59 89.211 2-Methylpropane 00075-28-5 1.18 6.46 7.604 2,3-Dimethylbutane 00079-29-8 0.90 6.33 5.693 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 6.11 26.866 2,3,4-Trimethylpentane 00565-75-3 0.95 5.96 5.657 2,3-Dimethylpentane 00565-59-3 1.25 5.65 7.054 ortho-Xylene 00095-47-6 7.58 5.23 39.602 c-2-Pentene 00627-20-3 10.28 5.20 53.457 Methylcyclohexane 00108-87-2 1.56 5.15 8.003 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 5.07 16.180 n-Heptane 00142-82-5 0.97 5.00 4.828 2-Methylhexane 00591-76-4 1.09 4.75 5.153 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 4.59 25.446 n-Octane 00111-65-9 0.80 4.51 3.591 2-Methyl-1-butene 00563-46-2 6.38 4.51 28.743 Cyclopentene 00142-29-0 6.69 3.91 26.172 2,4-Dimethylpentane 00108-08-7 1.46 3.80 5.550 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 3.29 12.566 2,4-Dimethylhexane 00589-43-5 1.61 3.27 5.247 2,2-DiMeHexane 00590-73-8 0.94 3.23 3.036 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.10 24.626 Ethylbenzene 00100-41-4 2.96 2.96 8.781 3-Methyl-t-2-pentene 00616-12-6 11.66 2.84 33.133 3-Methyl-c-2-pentene 00922-62-3 12.52 2.78 34.781 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 2.78 32.521 Vehicle 206b - Fuel 10 psi E10 - Dynamic - Test 25753 Non Zero Mass Species Sorted By VOC

## E

- 7 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 10 psi E10 - Dynamic - Test 25753 Non Zero Mass Species Sorted By VOC

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.73 2.979 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.61 17.244 2,2,5-Trimethylhexane 03522-94-9 1.05 2.52 2.659 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 2.46 13.049 t-2-Hexene 04050-45-7 8.55 2.40 20.514 t-2-Butene 00624-64-6 15.20 2.38 36.190 2-Methyl-2-pentene 00625-27-4 11.03 2.36 26.010 1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.30 16.259 c-2-Butene 00590-18-1 14.26 1.82 25.931 n-Nonane 00111-84-2 0.68 1.80 1.230 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.76 2.825 c-1,3-Dimethylcyclopentane 02532-58-3 3.45 1.75 6.033 2-Methylheptane 00592-27-8 0.97 1.65 1.596 t-1,2-Dimethylcyclopentane 00822-50-4 3.45 1.58 5.472 3-Methylheptane 00589-81-1 1.12 1.58 1.781 2,2-Dimethylbutane 00075-83-2 1.11 1.51 1.676 Indan 00496-11-7 3.23 1.36 4.390 c-1,3-Dimethylcyclohexane 00638-04-0 3.45 0.82 2.836 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.80 6.011 Isopropylbenzene (Cumene) 00098-82-8 3.45 0.78 2.702 Ethylcyclohexane 01678-91-7 1.35 0.61 0.814 t-1,4-Dimethylcyclohexane 02207-04-7 3.45 0.52 1.791

Total 634.7 2191.6 3.453

No MIR available, use weighted average of 3.4531 

### continued

## E

- 8 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 22238.67 23949.113 2-Methylbutane (Isopentane) 00078-78-4 1.35 14866.21 20142.039 2-Methylpropane 00075-28-5 1.18 3913.84 4605.038 Ethanol 00064-17-5 1.45 2333.12 3380.625 n-Pentane 00109-66-0 1.21 1930.18 2345.041 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1422.57 1988.449 Toluene 00108-88-3 3.93 1379.64 5415.108 n-Hexane 00110-54-3 1.13 1341.84 1522.557 2-Methyl-2-butene 00513-35-9 14.20 1323.52 18787.299 t-2-Pentene 00646-04-8 10.47 1248.37 13074.803 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1137.90 1364.475 2-Methyl-1-butene 00563-46-2 6.38 922.81 5886.165 3-Methylpentane 00096-14-0 1.69 844.25 1427.512 c-2-Butene 00590-18-1 14.26 834.12 11894.362 2,3-Dimethylbutane 00079-29-8 0.90 705.81 634.310 c-2-Pentene 00627-20-3 10.28 644.03 6621.505 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 585.08 6848.147 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 570.01 4526.514 2,3-Dimethylpentane 00565-59-3 1.25 429.33 535.941 Methylcyclopentane 00096-37-7 2.05 339.04 694.969 2,4-Dimethylpentane 00108-08-7 1.46 336.49 491.047 Benzene 00071-43-2 0.69 335.00 232.607 2,3,4-Trimethylpentane 00565-75-3 0.95 287.60 272.885 Propane 00074-98-6 0.46 266.68 121.904 Cyclohexane 00110-82-7 1.14 237.51 270.139 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 219.54 700.548 2-Methylhexane 00591-76-4 1.09 216.38 234.811 n-Heptane 00142-82-5 0.97 193.59 186.959 2,4-Dimethylhexane 00589-43-5 1.61 136.50 219.158 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 131.06 694.428 Methylcyclohexane 00108-87-2 1.56 127.17 197.793 Cyclopentene 00142-29-0 6.69 125.09 836.329 t-2-Hexene 04050-45-7 8.55 123.48 1055.588 2,2-Dimethylbutane 00075-83-2 1.11 111.28 123.658 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 98.95 158.848 3-Methyl-t-2-pentene 00616-12-6 11.66 93.97 1095.679 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 93.85 727.823 2-Methyl-2-pentene 00625-27-4 11.03 78.27 863.564 3-Methyl-c-2-pentene 00922-62-3 12.52 75.32 942.829 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 70.98 410.108 2,2,5-Trimethylhexane 03522-94-9 1.05 70.44 74.173 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 66.30 438.014 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 63.49 69.333 1-Methylcyclopentene 00693-89-0 12.45 56.66 705.719 Vehicle 206b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7476 Non Zero Mass Species Sorted By VOC

## E

- 9 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7476 Non Zero Mass Species Sorted By VOC

2,2,3-Trimethylbutane 00464-06-2 1.05 19.23 20.263 Ethylbenzene 00100-41-4 2.96 18.93 56.077 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 17.25 75.806 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 13.57 52.421 c-1,3-Dimethylcyclohexane 00638-04-0 2.35 13.53 31.844 Ethane 00074-84-0 0.26 13.03 3.424 2-Methyl-1,3-butadiene 00078-79-5 10.48 12.67 132.793 3,5-Dimethylheptane 00926-82-9 1.42 12.58 17.904 Unknown #5 2.35 12.10 28.475 1,3,5-Trimethylbenzene 00108-67-8 11.75 12.05 141.695 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 11.81 92.502 3,3-Dimethylhexane 00563-16-6 1.15 9.90 11.401 2,2-DiMeHexane 00590-73-8 0.94 9.62 9.051 n-Propylbenzene 00103-65-1 1.96 9.45 18.519 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 9.16 50.746 2,3,5-Trimethylhexane 01069-53-0 1.12 8.71 9.758 4-Methyloctane 02216-34-4 0.85 8.01 6.791 t-1,4-Dimethylcyclohexane 02207-04-7 2.35 5.76 13.550 Unknown #8 2.35 5.75 13.537 c-2-Heptene 06443-92-1 7.08 5.66 40.019 3-Methyloctane 02216-33-3 0.88 5.08 4.493 1,3-Butadiene 00106-99-0 12.45 5.07 63.201 n-Nonane 00111-84-2 0.68 4.89 3.337 t-3-Heptene 14686-14-7 6.17 4.65 28.721 Unknown #13 2.35 4.28 10.072 1-Nonene 00124-11-8 2.49 4.09 10.201 2,4-Dimethylheptane 02213-23-2 1.26 3.95 4.993 1,2,3-Trimethylbenzene 00526-73-8 11.94 3.93 46.913 Ethylene 00074-85-1 8.88 3.78 33.601 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 3.70 3.163 Isopropylbenzene (Cumene) 00098-82-8 2.35 3.64 8.578 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 3.59 22.613 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 3.57 23.383 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.35 3.56 8.390 t-4-Octene 14850-23-8 4.69 3.28 15.386 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 3.23 27.020 1-Heptene 00592-76-7 4.29 2.76 11.818 1-Butyne 00107-00-6 6.05 2.49 15.065 Indan 00496-11-7 3.23 2.25 7.265 Unknown #16 2.35 2.23 5.250 Unknown #3 2.35 2.21 5.197 

### continued

## E

- 10 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7476 Non Zero Mass Species Sorted By VOC

1,1-Dimethylcyclohexane 00590-66-9 1.12 2.10 2.337 Unknown #9 2.35 2.05 4.819 t-2-Nonene 06434-78-2 2.35 1.71 4.031 c-2-Octene 07642-04-8 2.35 1.67 3.936 Unknown #6

. 2.35 1.53 3.608 3-Ethyl-c-2-Pentene 00816-79-5 9.76 1.46 14.297 1,4-Diethylbenzene 00105-05-5 4.39 1.34 5.879 2,2-Dimethyloctane 15869-87-1 0.76 1.34 1.011 Unknown #10 2.35 1.16 2.725 n-Decane 00124-18-5 0.59 1.16 0.683 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 1.15 1.356 Unknown #7 2.35 1.11 2.612 c- & t-4-Nonene 02198-23-4 4.42 0.88 3.897 t-2-Octene & t-1,2-DiMeCyHexane 13389-42-9+06876-23-9 7.43 0.77 5.695 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.69 4.872 c-1,2-Dimethylcyclohexane 02207-01-4 2.35 0.65 1.527 Unknown #11 2.35 0.59 1.388 sec-Butylbenzene 00135-98-8 2.29 0.59 1.345 1,3-Diethylbenzene 00141-93-5 7.08 0.59 4.158 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.59 4.424 4-Methyl-t-2-pentene 00674-76-0 8.04 0.58 4.700 Isobutylbenzene 00538-93-2 2.35 0.48 1.131 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.45 1.729 Styrene 00100-42-5 1.66 0.44 0.739 1,2,3,5-Tetramethylbenzene 00527-53-7 9.26 0.32 2.954 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.29 2.212 Unknown #14 2.35 0.24 0.570 Unknown #4 2.35 0.20 0.469

Total 63303.9 148993.1 2.354

No MIR available, use weighted average of 2.3536 

### continued

## E

- 11 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 47.17 185.157 Ethanol 00064-17-5 1.45 29.29 42.448 n-Butane 00106-97-8 1.08 18.20 19.599 2-Methylbutane (Isopentane) 00078-78-4 1.35 13.25 17.958 n-Hexane 00110-54-3 1.13 10.81 12.261 Benzene 00071-43-2 0.69 8.83 6.131 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.10 38.104 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 7.01 54.340 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.15 38.067 2-Methyl-2-butene 00513-35-9 14.20 5.01 71.131 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 4.98 6.966 t-2-Pentene 00646-04-8 10.47 4.96 51.966 n-Pentane 00109-66-0 1.21 3.94 4.790 3-Methylpentane 00096-14-0 1.69 3.27 5.526 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.02 3.620 Methylcyclopentane 00096-37-7 2.05 3.01 6.163 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.76 12.130 Cyclohexane 00110-82-7 1.14 2.69 3.056 c-2-Pentene 00627-20-3 10.28 2.19 22.522 2,3-Dimethylbutane 00079-29-8 0.90 2.17 1.953 n-Heptane 00142-82-5 0.97 1.99 1.923 2-Methyl-1-butene 00563-46-2 6.38 1.89 12.052 ortho-Xylene 00095-47-6 7.58 1.87 14.160 Methylcyclohexane 00108-87-2 1.56 1.65 2.565 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.65 9.132 t-2-Hexene 04050-45-7 8.55 1.53 13.101 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.44 16.896 n-Propylbenzene 00103-65-1 1.96 1.37 2.692 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.36 15.948 2,3,4-Trimethylpentane 00565-75-3 0.95 1.33 1.266 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.32 4.211 2,3-Dimethylpentane 00565-59-3 1.25 1.24 1.546 2,4-Dimethylpentane 00108-08-7 1.46 1.24 1.807 Indan 00496-11-7 3.23 1.17 3.788 2-Methylhexane 00591-76-4 1.09 1.12 1.214 3-Methyl-t-2-pentene 00616-12-6 11.66 1.09 12.719 Ethylbenzene 00100-41-4 2.96 1.02 3.022 c-2-Butene 00590-18-1 14.26 0.96 13.734 Cyclopentene 00142-29-0 6.69 0.95 6.331 n-Octane 00111-65-9 0.80 0.87 0.695 3-Methyl-c-2-pentene 00922-62-3 12.52 0.83 10.391 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.77 6.136 3-Methylheptane 00589-81-1 1.12 0.76 0.850 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.73 8.760 Vehicle 206b - Fuel 7 psi E10 - 86 ° F Static - Test 7484 Non Zero Mass Species Sorted By VOC

## E

- 12 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 7 psi E10 - 86 ° F Static - Test 7484 Non Zero Mass Species Sorted By VOC

2,4-Dimethylhexane 00589-43-5 1.61 0.73 1.165 2-Methyl-2-pentene 00625-27-4 11.03 0.68 7.456 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.64 4.254 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.62 3.270 n-Nonane 00111-84-2 0.68 0.61 0.420 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.59 4.196 2-Methylheptane 00592-27-8 0.97 0.50 0.484 2,2,5-Trimethylhexane 03522-94-9 1.05 0.50 0.526 t-1,2-Dimethylcyclopentane 00822-50-4 3.58 0.44 1.562 2,2-DiMeHexane 00590-73-8 0.94 0.43 0.409 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.39 0.621 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.38 0.413 c-1,3-Dimethylcyclopentane 02532-58-3 3.58 0.35 1.256 n-Decane 00124-18-5 0.59 0.32 0.189 2,2-Dimethylbutane 00075-83-2 1.11 0.32 0.355 Unknown #1 3.58 0.19 0.685

Total 222.7 796.1 3.575

No MIR available, use weightedaverage of 3.5752 

### continued

## E

- 13 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 147.65 579.528 Ethanol 00064-17-5 1.45 114.05 165.262 n-Butane 00106-97-8 1.08 45.54 49.041 2-Methylbutane (Isopentane) 00078-78-4 1.35 43.06 58.343 n-Hexane 00110-54-3 1.13 34.97 39.680 Benzene 00071-43-2 0.69 26.02 18.067 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 21.06 163.325 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 19.46 104.460 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 18.52 25.884 n-Propylbenzene 00103-65-1 1.96 16.82 32.957 2-Methyl-2-butene 00513-35-9 14.20 15.88 225.363 n-Pentane 00109-66-0 1.21 15.41 18.723 t-2-Pentene 00646-04-8 10.47 15.13 158.417 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 14.80 109.346 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 12.66 15.180 3-Methylpentane 00096-14-0 1.69 12.32 20.830 Methylcyclopentane 00096-37-7 2.05 10.73 21.986 Cyclohexane 00110-82-7 1.14 9.05 10.289 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 7.91 34.771 c-2-Pentene 00627-20-3 10.28 7.71 79.250 2,3-Dimethylbutane 00079-29-8 0.90 7.11 6.388 2-Methyl-1-butene 00563-46-2 6.38 7.09 45.221 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 6.40 74.888 1,3,5-Trimethylbenzene 00108-67-8 11.75 5.85 68.792 ortho-Xylene 00095-47-6 7.58 5.83 44.143 2,3,4-Trimethylpentane 00565-75-3 0.95 5.79 5.496 n-Heptane 00142-82-5 0.97 5.79 5.594 Methylcyclohexane 00108-87-2 1.56 5.69 8.843 2-Methylhexane 00591-76-4 1.09 5.12 5.559 2,3-Dimethylpentane 00565-59-3 1.25 5.03 6.283 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.92 15.710 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 4.60 25.482 t-2-Hexene 04050-45-7 8.55 4.48 38.337 2,4-Dimethylpentane 00108-08-7 1.46 4.46 6.504 Ethylbenzene 00100-41-4 2.96 3.71 10.987 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.64 19.270 c-2-Butene 00590-18-1 14.26 3.52 50.172 2-Methylpropane 00075-28-5 1.18 3.30 3.880 1,2,3-Trimethylbenzene 00526-73-8 11.94 3.27 39.092 Cyclopentene 00142-29-0 6.69 3.18 21.255 3-Methyl-c-2-pentene 00922-62-3 12.52 3.08 38.581 3-Methyl-t-2-pentene 00616-12-6 11.66 3.08 35.876 n-Octane 00111-65-9 0.80 2.80 2.232 2,4-Dimethylhexane 00589-43-5 1.61 2.74 4.399 Vehicle 206b - Fuel 7 psi E10 - 105 ° F Static - Test 7487 Non Zero Mass Species Sorted By VOC

## E

- 14 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 7 psi E10 - 105 ° F Static - Test 7487 Non Zero Mass Species Sorted By VOC

1-Methylcyclopentene 00693-89-0 12.45 2.67 33.297 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.53 16.697 2-Methyl-2-pentene 00625-27-4 11.03 2.52 27.769 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.15 3.447 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.85 14.700 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.70 1.853 2,2-Dimethylbutane 00075-83-2 1.11 1.46 1.624 2-Methylheptane 00592-27-8 0.97 1.45 1.402 Cyclopentane 00287-92-3 2.24 1.42 3.170 2,2,5-Trimethylhexane 03522-94-9 1.05 1.37 1.444 Indan 00496-11-7 3.23 1.32 4.285 t-1,2-Dimethylcyclopentane 00822-50-4 3.54 1.27 4.477 n-Nonane 00111-84-2 0.68 1.23 0.841 1,4-Diethylbenzene 00105-05-5 4.39 1.22 5.372 2,2-DiMeHexane 00590-73-8 0.94 1.14 1.073 3-Methylheptane 00589-81-1 1.12 1.04 1.165 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.98 5.651 Isopropylbenzene (Cumene) 00098-82-8 3.54 0.92 3.268 c-1,3-Dimethylcyclopentane 02532-58-3 3.54 0.90 3.198 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.89 6.282 2,3,5-Trimethylhexane 01069-53-0 1.12 0.88 0.990 3,3-Dimethylpentane 00562-49-2 1.12 0.80 0.892 c-1,3-Dimethylcyclohexane 00638-04-0 3.54 0.79 2.799 n-Decane 00124-18-5 0.59 0.70 0.413 2,2-Dimethylpentane 00590-35-2 1.04 0.67 0.700 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.67 5.234 4-Methyloctane 02216-34-4 0.85 0.64 0.546 3-Methyloctane 02216-33-3 0.88 0.53 0.472 1-Nonene 00124-11-8 2.49 0.52 1.297 Unknown #1 3.54 0.51 1.795 Ethylcyclohexane 01678-91-7 1.35 0.50 0.667 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.49 1.887 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.45 3.360 2,2,3-Trimethylbutane 00464-06-2 1.05 0.37 0.392 Unknown #5 3.54 0.35 1.250 1,3-Diethylbenzene 00141-93-5 7.08 0.34 2.397 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.31 3.284 t-1,4-Dimethylcyclohexane 02207-04-7 3.54 0.26 0.914 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.23 1.703 1,2-Diethylbenzene 00135-01-3 5.43 0.12 0.648

Total 759.4 2686.3 3.538

No MIR available, use weighted average of 3.5376 

### continued

## E

- 15 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 127.65 501.023 Ethanol 00064-17-5 1.45 83.31 120.716 n-Butane 00106-97-8 1.08 43.76 47.129 2-Methylbutane (Isopentane) 00078-78-4 1.35 33.21 44.997 n-Hexane 00110-54-3 1.13 27.16 30.820 Benzene 00071-43-2 0.69 24.00 16.665 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 20.12 156.011 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 18.50 99.305 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 16.26 120.071 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 13.02 18.193 2-Methyl-2-butene 00513-35-9 14.20 11.93 169.328 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 10.31 12.362 n-Pentane 00109-66-0 1.21 10.02 12.172 t-2-Pentene 00646-04-8 10.47 9.93 104.038 Methylcyclopentane 00096-37-7 2.05 9.15 18.758 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 7.28 31.989 Cyclohexane 00110-82-7 1.14 6.92 7.872 ortho-Xylene 00095-47-6 7.58 6.76 51.232 3-Methylpentane 00096-14-0 1.69 6.72 11.365 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 6.47 24.707 2,3-Dimethylbutane 00079-29-8 0.90 6.40 5.753 Ethylene 00074-85-1 8.88 5.85 51.939 2-Methylpropane 00075-28-5 1.18 5.82 6.846 c-2-Pentene 00627-20-3 10.28 5.19 53.381 1,3,5-Trimethylbenzene 00108-67-8 11.75 4.90 57.606 n-Heptane 00142-82-5 0.97 4.76 4.601 2-Methyl-1-butene 00563-46-2 6.38 4.55 29.012 2,3,4-Trimethylpentane 00565-75-3 0.95 4.42 4.196 Methylcyclohexane 00108-87-2 1.56 4.42 6.879 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.84 21.282 2,3-Dimethylpentane 00565-59-3 1.25 3.74 4.675 n-Octane 00111-65-9 0.80 3.68 2.932 Indan 00496-11-7 3.23 3.45 11.169 Ethylbenzene 00100-41-4 2.96 3.43 10.176 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.37 39.471 t-2-Hexene 04050-45-7 8.55 3.27 27.979 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 3.21 10.252 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.05 24.212 2,4-Dimethylpentane 00108-08-7 1.46 3.04 4.440 2-Methylhexane 00591-76-4 1.09 2.57 2.794 3-Methyl-c-2-pentene 00922-62-3 12.52 2.56 32.096 3-Methyl-t-2-pentene 00616-12-6 11.66 2.46 28.681 c-2-Butene 00590-18-1 14.26 2.38 33.934 2,4-Dimethylhexane 00589-43-5 1.61 2.18 3.497 Vehicle 206b - Fuel 7 psi E10 - Dynamic - Test 25760 Non Zero Mass Species Sorted By VOC

## E

- 16 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 7 psi E10 - Dynamic - Test 25760 Non Zero Mass Species Sorted By VOC

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.18 3.497 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.11 13.910 2-Methyl-2-pentene 00625-27-4 11.03 2.06 22.768 1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.01 14.257 c-1,3-Dimethylcyclopentane 02532-58-3 3.56 1.88 6.682 2,2-DiMeHexane 00590-73-8 0.94 1.80 1.699 n-Nonane 00111-84-2 0.68 1.74 1.188 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 1.42 7.511 t-1,2-Dimethylcyclopentane 00822-50-4 3.56 1.41 5.009 3-Methylheptane 00589-81-1 1.12 1.18 1.323 2,2,5-Trimethylhexane 03522-94-9 1.05 1.11 1.168 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.00 1.094 2-Methylheptane 00592-27-8 0.97 0.44 0.421 Methane 00074-82-8 0.01 0.43 0.006 Cyclopentene 00142-29-0 6.69 0.21 1.393

Total 606.0 2158.5 3.562

No MIR available, use weighted average of 3.5618 

### continued

## E

- 17 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 938.92 3685.272 Ethanol 00064-17-5 1.45 876.24 1269.651 2-Methylbutane (Isopentane) 00078-78-4 1.35 561.05 760.158 n-Hexane 00110-54-3 1.13 430.31 488.263 n-Butane 00106-97-8 1.08 402.75 433.722 Benzene 00071-43-2 0.69 238.37 165.516 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 208.48 291.415 2-Methyl-2-butene 00513-35-9 14.20 201.15 2855.258 t-2-Pentene 00646-04-8 10.47 191.91 2010.007 n-Pentane 00109-66-0 1.21 168.04 204.158 3-Methylpentane 00096-14-0 1.69 140.20 237.064 Methylcyclopentane 00096-37-7 2.05 118.13 242.150 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 103.84 124.515 Cyclohexane 00110-82-7 1.14 98.63 112.179 c-2-Pentene 00627-20-3 10.28 93.76 964.026 2-Methyl-1-butene 00563-46-2 6.38 80.98 516.533 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 77.52 601.227 2,3-Dimethylbutane 00079-29-8 0.90 72.95 65.561 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 55.79 653.040 n-Heptane 00142-82-5 0.97 55.25 53.357 t-2-Hexene 04050-45-7 8.55 52.42 448.132 Methylcyclohexane 00108-87-2 1.56 51.82 80.605 2-Methylhexane 00591-76-4 1.09 47.45 51.496 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 44.04 140.517 2,3,4-Trimethylpentane 00565-75-3 0.95 43.48 41.253 2,4-Dimethylpentane 00108-08-7 1.46 43.09 62.880 c-2-Butene 00590-18-1 14.26 43.00 613.201 2,3-Dimethylpentane 00565-59-3 1.25 41.65 51.995 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 39.05 206.928 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 38.62 207.348 Cyclopentene 00142-29-0 6.69 38.47 257.197 3-Methyl-t-2-pentene 00616-12-6 11.66 36.34 423.683 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 36.31 268.204 1-Methylcyclopentene 00693-89-0 12.45 35.58 443.119 3-Methyl-c-2-pentene 00922-62-3 12.52 32.31 404.403 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 28.33 187.184 2-Methyl-2-pentene 00625-27-4 11.03 28.26 311.775 2-Methylpropane 00075-28-5 1.18 23.43 27.573 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 21.96 174.381 2,4-Dimethylhexane 00589-43-5 1.61 21.71 34.862 n-Octane 00111-65-9 0.80 20.58 16.388 ortho-Xylene 00095-47-6 7.58 19.14 145.003 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 18.58 81.632 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 15.64 25.102 Vehicle 206b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7495 Non Zero Mass Species Sorted By VOC

## E

- 18 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7495 Non Zero Mass Species Sorted By VOC

Cyclopentane 00287-92-3 2.24 14.32 32.040 Ethylbenzene 00100-41-4 2.96 13.32 39.465 1,3,5-Trimethylbenzene 00108-67-8 11.75 12.80 150.415 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 12.40 13.541 t-1,2-Dimethylcyclopentane 00822-50-4 3.44 11.43 39.328 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 11.11 61.570 n-Propylbenzene 00103-65-1 1.96 10.37 20.327 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 9.93 57.400 2,2,5-Trimethylhexane 03522-94-9 1.05 9.88 10.407 2-Methylheptane 00592-27-8 0.97 9.65 9.336 2,2-DiMeHexane 00590-73-8 0.94 9.40 8.851 c-1,3-Dimethylcyclopentane 02532-58-3 3.44 9.15 31.502 2,2-Dimethylbutane 00075-83-2 1.11 8.93 9.920 3-Methylheptane 00589-81-1 1.12 8.65 9.726 2,2-Dimethylpentane 00590-35-2 1.04 5.95 6.207 2,3,5-Trimethylhexane 01069-53-0 1.12 5.83 6.525 c-1,3-Dimethylcyclohexane 00638-04-0 3.44 5.46 18.800 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 5.14 40.310 1,2,3-Trimethylbenzene 00526-73-8 11.94 4.82 57.560 Ethylcyclohexane 01678-91-7 1.35 4.60 6.188 2,2,3-Trimethylbutane 00464-06-2 1.05 4.56 4.808 n-Nonane 00111-84-2 0.68 4.00 2.731 Propane 00074-98-6 0.46 3.83 1.751 3,3-Dimethylpentane 00562-49-2 1.12 3.82 4.276 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 3.12 12.065 n-Decane 00124-18-5 0.59 2.99 1.769 t-1,4-Dimethylcyclohexane 02207-04-7 3.44 2.60 8.939 Indan 00496-11-7 3.23 2.53 8.194 4-Methyloctane 02216-34-4 0.85 2.52 2.138 2-Methyl-1,3-butadiene 00078-79-5 10.48 2.51 26.290 Isopropylbenzene (Cumene) 00098-82-8 3.44 2.43 8.367 Unknown #5 3.44 2.39 8.239 c-2-Heptene 06443-92-1 7.08 2.25 15.947 t-3-Heptene 14686-14-7 6.17 2.09 12.898 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.44 1.80 6.193 1,4-Diethylbenzene 00105-05-5 4.39 1.77 7.774 Unknown #16 3.44 1.75 6.008 1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.71 12.126 Cyclopentadiene 00542-92-7 6.89 1.71 11.786 3,3-Dimethylhexane 00563-16-6 1.15 1.54 1.769 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.48 12.428 Unknown #8 3.44 1.40 4.829 

### continued

## E

- 19 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7495 Non Zero Mass Species Sorted By VOC

2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.34 8.743 3-Methyloctane 02216-33-3 0.88 1.22 1.078 1,1-Dimethylcyclohexane 00590-66-9 1.12 1.15 1.278 2,4-Dimethylheptane 02213-23-2 1.26 1.10 1.390 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 1.06 0.902 1-Heptene 00592-76-7 4.29 0.94 4.023 1-Nonene 00124-11-8 2.49 0.89 2.222 sec-Butylbenzene 00135-98-8 2.29 0.81 1.846 Unknown #3 3.44 0.80 2.746 1,3-Diethylbenzene 00141-93-5 7.08 0.70 4.951 Unknown #9 3.44 0.70 2.396 Unknown #13 3.44 0.69 2.386 Isobutylbenzene 00538-93-2 3.44 0.63 2.182 t-2-Nonene 06434-78-2 3.44 0.63 2.178 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.58 4.371 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 0.53 0.628 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.52 2.000 3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.50 4.927 c- & t-4-Nonene 02198-23-4 4.42 0.48 2.117 t-4-Octene 14850-23-8 4.69 0.35 1.632 c-1,2-Dimethylcyclohexane 02207-01-4 3.44 0.29 1.014 Unknown #6 3.44 0.25 0.848

Total 6189.7 21304.5 3.442

No MIR available, use weighted average of 3.4419 

### continued

## E

- 20 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 28.42 111.564 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.52 55.563 2-Methylbutane (Isopentane) 00078-78-4 1.35 7.13 9.666 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.19 48.014 Benzene 00071-43-2 0.69 5.88 4.082 n-Hexane 00110-54-3 1.13 5.87 6.664 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.07 27.215 Cyclohexane 00110-82-7 1.14 4.60 5.235 Ethanol 00064-17-5 1.45 4.09 5.920 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.96 4.138 2-Methyl-2-butene 00513-35-9 14.20 2.81 39.831 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.47 10.839 t-2-Pentene 00646-04-8 10.47 2.06 21.590 3-Methylpentane 00096-14-0 1.69 1.98 3.343 n-Pentane 00109-66-0 1.21 1.96 2.379 Methylcyclopentane 00096-37-7 2.05 1.90 3.886 n-Butane 00106-97-8 1.08 1.81 1.948 ortho-Xylene 00095-47-6 7.58 1.78 13.522 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.76 2.108 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.73 20.357 2,3-Dimethylbutane 00079-29-8 0.90 1.49 1.337 Ethylbenzene 00100-41-4 2.96 1.26 3.726 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.23 6.812 c-2-Pentene 00627-20-3 10.28 1.12 11.502 n-Propylbenzene 00103-65-1 1.96 1.09 2.135 2,3,4-Trimethylpentane 00565-75-3 0.95 1.01 0.954 Methylcyclohexane 00108-87-2 1.56 0.98 1.525 n-Heptane 00142-82-5 0.97 0.96 0.928 2-Methyl-1-butene 00563-46-2 6.38 0.88 5.615 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.87 5.756 2,4-Dimethylhexane 00589-43-5 1.61 0.86 1.384 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.80 4.257 t-2-Hexene 04050-45-7 8.55 0.80 6.807 2,2,5-Trimethylhexane 03522-94-9 1.05 0.73 0.771 2,3-Dimethylpentane 00565-59-3 1.25 0.72 0.896 2,4-Dimethylpentane 00108-08-7 1.46 0.71 1.042 2-Methylhexane 00591-76-4 1.09 0.70 0.763 3-Methyl-c-2-pentene 00922-62-3 12.52 0.70 8.716 2-Methyl-2-pentene 00625-27-4 11.03 0.64 7.012 3-Methyl-t-2-pentene 00616-12-6 11.66 0.63 7.327 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.61 7.312 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.60 1.907 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.59 6.955 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.55 0.879 Cyclopentene 00142-29-0 6.69 0.52 3.502 Vehicle 206b - Fuel 9 psi E0 - 86 ° F Static - Test 7539 Non Zero Mass Species Sorted By VOC

## E

- 21 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 9 psi E0 - 86 ° F Static - Test 7539 Non Zero Mass Species Sorted By VOC

n-Octane 00111-65-9 0.80 0.52 0.416 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.49 0.533 2,2-DiMeHexane 00590-73-8 0.94 0.43 0.404 Indan 00496-11-7 3.23 0.40 1.304 t-1,2-Dimethylcyclopentane 00822-50-4 4.16 0.37 1.551 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.36 2.879 c-2-Butene 00590-18-1 14.26 0.33 4.698 c-1,3-Dimethylcyclopentane 02532-58-3 4.16 0.29 1.219 2-Methylheptane 00592-27-8 0.97 0.29 0.282 2,3,5-Trimethylhexane 01069-53-0 1.12 0.24 0.266

Total 122.8 511.2 4.164

No MIR available, use weighted average of 4.1644 

### continued

## E

- 22 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 56.24 220.748 2-Methylbutane (Isopentane) 00078-78-4 1.35 31.47 42.640 n-Butane 00106-97-8 1.08 27.75 29.885 Ethanol 00064-17-5 1.45 18.75 27.170 n-Hexane 00110-54-3 1.13 14.82 16.814 Cyclohexane 00110-82-7 1.14 14.24 16.195 Benzene 00071-43-2 0.69 11.97 8.310 3-Methylpentane 00096-14-0 1.69 9.31 15.741 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.95 69.388 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 8.75 12.227 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.68 41.259 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 6.63 7.955 2-Methyl-2-butene 00513-35-9 14.20 6.51 92.459 n-Pentane 00109-66-0 1.21 5.80 7.045 t-2-Pentene 00646-04-8 10.47 5.17 54.128 Methylcyclopentane 00096-37-7 2.05 4.89 10.023 c-2-Pentene 00627-20-3 10.28 2.88 29.587 2,3,4-Trimethylpentane 00565-75-3 0.95 2.79 2.644 2-Methyl-1-butene 00563-46-2 6.38 2.61 16.619 ortho-Xylene 00095-47-6 7.58 2.50 18.977 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 2.17 6.934 2,4-Dimethylpentane 00108-08-7 1.46 2.16 3.155 2,3-Dimethylpentane 00565-59-3 1.25 2.08 2.600 2-Methylhexane 00591-76-4 1.09 1.85 2.008 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.83 8.034 t-2-Hexene 04050-45-7 8.55 1.76 15.011 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.52 17.837 2,3-Dimethylbutane 00079-29-8 0.90 1.52 1.367 3-Methyl-t-2-pentene 00616-12-6 11.66 1.41 16.427 n-Heptane 00142-82-5 0.97 1.26 1.219

Total 267.3 814.4 3.047 Vehicle 206b - Fuel 9 psi E0 - 105 ° F Static - Test 7545 Non Zero Mass Species Sorted By VOC

## E

- 23 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 64.08 251.497 2-Methylbutane (Isopentane) 00078-78-4 1.35 26.84 36.363 n-Butane 00106-97-8 1.08 24.36 26.232 Ethanol 00064-17-5 1.45 20.34 29.475 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 14.47 112.251 Benzene 00071-43-2 0.69 14.46 10.043 n-Hexane 00110-54-3 1.13 12.90 14.640 Cyclohexane 00110-82-7 1.14 12.33 14.027 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 11.79 63.296 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 9.26 12.942 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 9.15 67.583 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 7.41 8.883 3-Methylpentane 00096-14-0 1.69 7.05 11.922 2,3-Dimethylbutane 00079-29-8 0.90 6.92 6.221 2-Methyl-2-butene 00513-35-9 14.20 5.98 84.864 1,3,5-Trimethylbenzene 00108-67-8 11.75 5.80 68.169 Methylcyclopentane 00096-37-7 2.05 5.38 11.030 n-Pentane 00109-66-0 1.21 5.37 6.527 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 4.99 21.931 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 4.33 50.669 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.75 19.859 c-2-Butene 00590-18-1 14.26 3.62 51.692 ortho-Xylene 00095-47-6 7.58 3.60 27.299 1,2,3-Trimethylbenzene 00526-73-8 11.94 3.45 41.143 t-2-Pentene 00646-04-8 10.47 3.28 34.359 n-Propylbenzene 00103-65-1 1.96 3.27 6.414 2,2-DiMeHexane 00590-73-8 0.94 3.27 3.080 n-Heptane 00142-82-5 0.97 3.24 3.129 2,3,4-Trimethylpentane 00565-75-3 0.95 3.20 3.034 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 2.89 22.970 Indan 00496-11-7 3.23 2.83 9.149 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 2.74 8.729 Methylcyclohexane 00108-87-2 1.56 2.68 4.173 2-Methyl-1-butene 00563-46-2 6.38 2.68 17.071 Ethylbenzene 00100-41-4 2.96 2.61 7.747 2,3-Dimethylpentane 00565-59-3 1.25 2.59 3.228 2,2,5-Trimethylhexane 03522-94-9 1.05 2.54 2.674 2,4-Dimethylpentane 00108-08-7 1.46 2.27 3.306 2-Methylhexane 00591-76-4 1.09 2.24 2.435 Unknown #22 3.76 2.06 7.762 2-Methyl-2-pentene 00625-27-4 11.03 2.05 22.639 Cyclopentene 00142-29-0 6.69 1.87 12.476 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.72 11.343 c-2-Pentene 00627-20-3 10.28 1.51 15.533 Vehicle 206b - Fuel 9 psi E0 - Dynamic - Test 25775 Non Zero Mass Species Sorted By VOC

## E

- 24 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 9 psi E0 - Dynamic - Test 25775 Non Zero Mass Species Sorted By VOC

3-Methyl-c-2-pentene 00922-62-3 12.52 1.49 18.609 t-2-Hexene 04050-45-7 8.55 1.42 12.172 3-Methyl-t-2-pentene 00616-12-6 11.66 1.24 14.404 2,2-Dimethylbutane 00075-83-2 1.11 1.22 1.350 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.16 6.454 n-Octane 00111-65-9 0.80 1.13 0.901 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.99 10.330 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.94 1.021 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.83 1.339 Methane 00074-82-8 0.01 0.50 0.007

Total 350.1 1316.4 3.760

No MIR available, use weighted average of 3.7602 

### continued

## E

- 25 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 482.40 1893.416 2-Methylbutane (Isopentane) 00078-78-4 1.35 480.37 650.844 n-Butane 00106-97-8 1.08 442.07 476.067 Cyclohexane 00110-82-7 1.14 212.89 242.139 n-Hexane 00110-54-3 1.13 209.35 237.545 Ethanol 00064-17-5 1.45 189.89 275.142 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 139.65 195.200 Benzene 00071-43-2 0.69 117.42 81.533 2-Methyl-2-butene 00513-35-9 14.20 98.71 1401.233 3-Methylpentane 00096-14-0 1.69 94.97 160.588 n-Pentane 00109-66-0 1.21 85.36 103.713 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 82.11 98.461 Methylcyclopentane 00096-37-7 2.05 76.82 157.466 t-2-Pentene 00646-04-8 10.47 75.24 788.046 2,3-Dimethylbutane 00079-29-8 0.90 66.61 59.861 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 53.35 413.777 c-2-Pentene 00627-20-3 10.28 40.05 411.810 2-Methyl-1-butene 00563-46-2 6.38 39.72 253.383 2,3,4-Trimethylpentane 00565-75-3 0.95 34.59 32.824 2,4-Dimethylpentane 00108-08-7 1.46 31.16 45.466 2-Methylhexane 00591-76-4 1.09 29.55 32.072 2,3-Dimethylpentane 00565-59-3 1.25 28.32 35.350 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 28.01 89.386 t-2-Hexene 04050-45-7 8.55 26.19 223.900 Methylcyclohexane 00108-87-2 1.56 24.94 38.791 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 24.14 282.494 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 24.07 177.752 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 23.79 127.748 n-Heptane 00142-82-5 0.97 22.63 21.858 3-Methyl-t-2-pentene 00616-12-6 11.66 22.01 256.629 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 21.78 115.424 1-Methylcyclopentene 00693-89-0 12.45 20.29 252.744 Cyclopentene 00142-29-0 6.69 19.34 129.339 3-Methyl-c-2-pentene 00922-62-3 12.52 19.22 240.649 2-Methyl-2-pentene 00625-27-4 11.03 17.22 189.990 2,4-Dimethylhexane 00589-43-5 1.61 16.53 26.536 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 15.36 101.470 c-2-Butene 00590-18-1 14.26 14.11 201.260 ortho-Xylene 00095-47-6 7.58 13.88 105.180 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 11.63 18.678 2,2-DiMeHexane 00590-73-8 0.94 11.02 10.376 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 10.52 46.229 Ethylbenzene 00100-41-4 2.96 10.44 30.930 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 9.22 73.213 Vehicle 206b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7551 Non Zero Mass Species Sorted By VOC

## E

- 26 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7551 Non Zero Mass Species Sorted By VOC

2,2-Dimethylbutane 00075-83-2 1.11 9.08 10.085 2,2,5-Trimethylhexane 03522-94-9 1.05 8.92 9.390 n-Octane 00111-65-9 0.80 8.35 6.647 1,3,5-Trimethylbenzene 00108-67-8 11.75 8.33 97.916 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 8.23 8.991 t-1,2-Dimethylcyclopentane 00822-50-4 3.09 7.69 23.786 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 7.20 39.925 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 6.84 39.518 c-1,3-Dimethylcyclopentane 02532-58-3 3.09 6.24 19.303 n-Propylbenzene 00103-65-1 1.96 5.57 10.911 3-Methylheptane 00589-81-1 1.12 5.23 5.876 2-Methylheptane 00592-27-8 0.97 5.03 4.870 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 3.89 30.472 2,2-Dimethylpentane 00590-35-2 1.04 3.87 4.038 3,3-Dimethylpentane 00562-49-2 1.12 3.73 4.175 2,2,3-Trimethylbutane 00464-06-2 1.05 3.60 3.798 c-1,3-Dimethylcyclohexane 00638-04-0 3.09 3.17 9.825 2-Methylpropane 00075-28-5 1.18 3.12 3.672 1,2,3-Trimethylbenzene 00526-73-8 11.94 3.03 36.182 Unknown #5 3.09 2.11 6.544 c-2-Heptene 06443-92-1 7.08 2.11 14.958 Ethylcyclohexane 01678-91-7 1.35 2.02 2.715 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.97 7.620 Unknown #16 3.09 1.72 5.322 1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.65 11.656 Isopropylbenzene (Cumene) 00098-82-8 3.09 1.60 4.963 2,3,5-Trimethylhexane 01069-53-0 1.12 1.56 1.748 1,3-Butadiene 00106-99-0 12.45 1.54 19.233 Indan 00496-11-7 3.23 1.46 4.717 t-3-Heptene 14686-14-7 6.17 1.43 8.832 1,4-Diethylbenzene 00105-05-5 4.39 1.41 6.209 2-Methyl-1,3-butadiene 00078-79-5 10.48 1.35 14.151 Ethylene 00074-85-1 8.88 1.32 11.722 Unknown #8 3.09 1.30 4.009 t-1,4-Dimethylcyclohexane 02207-04-7 3.09 1.29 3.993 4-Methyloctane 02216-34-4 0.85 1.27 1.080 n-Nonane 00111-84-2 0.68 1.27 0.864 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.09 1.25 3.877 3,5-Dimethylheptane 00926-82-9 1.42 1.22 1.734 1,1-Dimethylcyclohexane 00590-66-9 1.12 1.15 1.277 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.13 7.421 3,3-Dimethylhexane 00563-16-6 1.15 1.10 1.263 

### continued

## E

- 27 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7551 Non Zero Mass Species Sorted By VOC

Unknown #13 3.09 1.10 3.390 2,4-Dimethylheptane 02213-23-2 1.26 1.09 1.382 3-Methyloctane 02216-33-3 0.88 1.07 0.950 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.03 8.638 1-Nonene 00124-11-8 2.49 0.95 2.364 4-Methyl-t-2-pentene 00674-76-0 8.04 0.91 7.338 1-Heptene 00592-76-7 4.29 0.82 3.498 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.81 0.690 Unknown #3 3.09 0.75 2.322 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.72 5.457 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.66 5.010 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 0.61 0.726 1,3-Diethylbenzene 00141-93-5 7.08 0.61 4.323 n-Decane 00124-18-5 0.59 0.61 0.360 Unknown #6

. 3.09 0.60 1.872 t-4-Octene 14850-23-8 4.69 0.55 2.561 3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.50 4.857 sec-Butylbenzene 00135-98-8 2.29 0.48 1.111 3-Methylnonane 005911-04-6 0.66 0.44 0.287 t-2-Nonene 06434-78-2 3.09 0.33 1.012 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.28 1.056

Total 3677.3 11381.0 3.095

No MIR available, use weighted average of 3.0950 

### continued

## E

- 28 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 15.58 61.151 n-Butane 00106-97-8 1.08 6.84 7.366 2-Methylbutane (Isopentane) 00078-78-4 1.35 5.87 7.949 n-Hexane 00110-54-3 1.13 3.78 4.289 Cyclohexane 00110-82-7 1.14 3.76 4.273 Ethanol 00064-17-5 1.45 3.54 5.131 Benzene 00071-43-2 0.69 2.82 1.959 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.58 19.984 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.19 3.056 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.10 15.524 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.02 10.860 2-Methyl-2-butene 00513-35-9 14.20 1.67 23.717 t-2-Pentene 00646-04-8 10.47 1.65 17.267 n-Pentane 00109-66-0 1.21 1.54 1.867 3-Methylpentane 00096-14-0 1.69 1.38 2.341 Methylcyclopentane 00096-37-7 2.05 1.36 2.795 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.35 1.624 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.32 5.782 ortho-Xylene 00095-47-6 7.58 1.25 9.434 2,3-Dimethylbutane 00079-29-8 0.90 1.01 0.904 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.97 11.459 2,3,4-Trimethylpentane 00565-75-3 0.95 0.90 0.852 2-Methyl-1-butene 00563-46-2 6.38 0.74 4.693 c-2-Pentene 00627-20-3 10.28 0.70 7.167 2,3,5-Trimethylhexane 01069-53-0 1.12 0.61 0.679 2-Methylheptane 00592-27-8 0.97 0.59 0.566 t-2-Hexene 04050-45-7 8.55 0.57 4.910 3-Methyl-t-2-pentene 00616-12-6 11.66 0.52 6.070 2,4-Dimethylpentane 00108-08-7 1.46 0.51 0.744 2,4-Dimethylhexane 00589-43-5 1.61 0.49 0.789 Cyclopentene 00142-29-0 6.69 0.49 3.270 Ethylbenzene 00100-41-4 2.96 0.49 1.439 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.48 1.538 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.47 3.085 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.43 3.442 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.43 4.996 n-Propylbenzene 00103-65-1 1.96 0.40 0.791 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.40 4.801 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.39 2.161 Methylcyclohexane 00108-87-2 1.56 0.38 0.596 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.38 0.414 n-Heptane 00142-82-5 0.97 0.38 0.362 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.36 1.934 2-Methyl-2-pentene 00625-27-4 11.03 0.35 3.908 2,3-Dimethylpentane 00565-59-3 1.25 0.31 0.390 Vehicle 206b - Fuel 7 psi E0 - 86 ° F Static - Test 7561 Non Zero Mass Species Sorted By VOC

## E

- 29 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 7 psi E0 - 86 ° F Static - Test 7561 Non Zero Mass Species Sorted By VOC

2,2-DiMeHexane 00590-73-8 0.94 0.30 0.287 3-Methylheptane 00589-81-1 1.12 0.29 0.326 3-Methyl-c-2-pentene 00922-62-3 12.52 0.26 3.292 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.25 0.395 n-Octane 00111-65-9 0.80 0.13 0.107 Indan 00496-11-7 3.23 0.12 0.388 2,2,5-Trimethylhexane 03522-94-9 1.05 0.09 0.100 c-2-Butene 00590-18-1 14.26 0.08 1.104 c-1,3-Dimethylcyclopentane 02532-58-3 3.65 0.06 0.235 t-1,2-Dimethylcyclopentane 00822-50-4 3.65 0.06 0.230 2-Methylhexane 00591-76-4 1.09 0.02 0.024

Total 78.0 284.8 3.651

No MIR available, use weighted average of 3.6506 

### continued

## E

- 30 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 38.00 149.142 2-Methylbutane (Isopentane) 00078-78-4 1.35 19.36 26.230 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 18.15 134.070 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 14.53 112.710 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 14.41 77.345 Cyclohexane 00110-82-7 1.14 10.72 12.197 n-Butane 00106-97-8 1.08 10.60 11.418 n-Hexane 00110-54-3 1.13 9.62 10.917 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 5.96 8.332 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.36 23.532 1,3,5-Trimethylbenzene 00108-67-8 11.75 4.71 55.405 t-2-Hexene 04050-45-7 8.55 4.53 38.693 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.38 5.253 3-Methylpentane 00096-14-0 1.69 4.29 7.258 ortho-Xylene 00095-47-6 7.58 4.10 31.052 Benzene 00071-43-2 0.69 4.08 2.834 2-Methyl-2-butene 00513-35-9 14.20 3.95 56.048 n-Pentane 00109-66-0 1.21 3.62 4.399 Methylcyclopentane 00096-37-7 2.05 3.55 7.277 t-2-Pentene 00646-04-8 10.47 2.90 30.371 2,3,4-Trimethylpentane 00565-75-3 0.95 2.10 1.990 2-Methyl-1-butene 00563-46-2 6.38 1.62 10.340 c-2-Pentene 00627-20-3 10.28 1.59 16.337 2-Methylhexane 00591-76-4 1.09 1.57 1.708 2,3-Dimethylpentane 00565-59-3 1.25 1.54 1.925 2,4-Dimethylpentane 00108-08-7 1.46 1.50 2.196 n-Heptane 00142-82-5 0.97 1.37 1.326 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.36 4.345 2,3-Dimethylbutane 00079-29-8 0.90 1.23 1.108 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.73 8.575

Total 201.5 854.3 4.241 Vehicle 206b - Fuel 7 psi E0 - 105 ° F Static - Test 7563 Non Zero Mass Species Sorted By VOC

## E

- 31 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 52.27 205.169 2-Methylbutane (Isopentane) 00078-78-4 1.35 21.18 28.691 n-Butane 00106-97-8 1.08 17.56 18.909 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 11.14 86.374 Benzene 00071-43-2 0.69 10.11 7.019 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 9.16 49.186 n-Hexane 00110-54-3 1.13 8.99 10.198 Cyclohexane 00110-82-7 1.14 8.66 9.847 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.69 56.815 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 6.08 8.496 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 5.09 6.101 3-Methylpentane 00096-14-0 1.69 4.86 8.217 2,3-Dimethylbutane 00079-29-8 0.90 4.66 4.187 2-Methyl-2-butene 00513-35-9 14.20 4.53 64.340 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 4.27 18.778 n-Pentane 00109-66-0 1.21 4.27 5.185 1,3,5-Trimethylbenzene 00108-67-8 11.75 4.25 49.992 Methylcyclopentane 00096-37-7 2.05 4.24 8.698 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.37 39.442 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 2.70 14.330 ortho-Xylene 00095-47-6 7.58 2.62 19.839 2,3,4-Trimethylpentane 00565-75-3 0.95 2.58 2.444 1,2,3-Trimethylbenzene 00526-73-8 11.94 2.54 30.367 c-2-Butene 00590-18-1 14.26 2.49 35.498 2,2-DiMeHexane 00590-73-8 0.94 2.49 2.341 n-Heptane 00142-82-5 0.97 2.40 2.314 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 2.30 18.263 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 2.30 7.336 t-2-Pentene 00646-04-8 10.47 2.28 23.914 n-Propylbenzene 00103-65-1 1.96 2.19 4.300 Ethylbenzene 00100-41-4 2.96 2.13 6.323 Indan 00496-11-7 3.23 2.08 6.717 Methylcyclohexane 00108-87-2 1.56 2.04 3.168 2,2,5-Trimethylhexane 03522-94-9 1.05 1.99 2.097 2,3-Dimethylpentane 00565-59-3 1.25 1.96 2.444 2-Methyl-1-butene 00563-46-2 6.38 1.91 12.175 2-Methylhexane 00591-76-4 1.09 1.74 1.885 2,4-Dimethylpentane 00108-08-7 1.46 1.68 2.456 2-Methyl-2-pentene 00625-27-4 11.03 1.53 16.928 Unknown #22

. 3.96 1.44 5.705 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.40 9.255 Cyclopentene 00142-29-0 6.69 1.27 8.475 c-2-Pentene 00627-20-3 10.28 1.26 12.931 t-2-Hexene 04050-45-7 8.55 1.20 10.235 Vehicle 206b - Fuel 7 psi E0 - Dynamic - Test 25780 Non Zero Mass Species Sorted By VOC

## E

- 32 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 7 psi E0 - Dynamic - Test 25780 Non Zero Mass Species Sorted By VOC

3-Methyl-c-2-pentene 00922-62-3 12.52 1.13 14.097 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.00 5.542 3-Methyl-t-2-pentene 00616-12-6 11.66 0.91 10.619 2,2-Dimethylbutane 00075-83-2 1.11 0.90 0.997 n-Octane 00111-65-9 0.80 0.88 0.701 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.73 0.797 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.65 6.780 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.61 0.986

Total 249.7 987.9 3.956

No MIR available, use weighted average of 3.9564 

### continued

## E

- 33 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 418.45 566.959 Toluene 00108-88-3 3.93 354.98 1393.317 n-Butane 00106-97-8 1.08 206.12 221.975 Cyclohexane 00110-82-7 1.14 199.31 226.692 n-Hexane 00110-54-3 1.13 164.51 186.670 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 118.19 165.211 Ethanol 00064-17-5 1.45 107.80 156.198 Benzene 00071-43-2 0.69 84.73 58.835 3-Methylpentane 00096-14-0 1.69 80.52 136.149 2-Methyl-2-butene 00513-35-9 14.20 75.59 1072.971 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 72.16 86.528 n-Pentane 00109-66-0 1.21 67.66 82.200 Methylcyclopentane 00096-37-7 2.05 63.94 131.069 2,3-Dimethylbutane 00079-29-8 0.90 57.89 52.025 t-2-Pentene 00646-04-8 10.47 55.50 581.294 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 42.28 327.932 2,3,4-Trimethylpentane 00565-75-3 0.95 31.57 29.955 2-Methyl-1-butene 00563-46-2 6.38 30.98 197.581 c-2-Pentene 00627-20-3 10.28 30.32 311.693 2,4-Dimethylpentane 00108-08-7 1.46 26.70 38.957 2-Methylhexane 00591-76-4 1.09 25.34 27.500 2,3-Dimethylpentane 00565-59-3 1.25 23.93 29.876 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 23.58 75.240 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 20.51 110.102 Methylcyclohexane 00108-87-2 1.56 20.37 31.681 t-2-Hexene 04050-45-7 8.55 19.96 170.626 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 18.36 214.937 3-Methyl-t-2-pentene 00616-12-6 11.66 17.54 204.459 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 17.54 92.912 n-Heptane 00142-82-5 0.97 17.48 16.882 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 16.23 119.835 1-Methylcyclopentene 00693-89-0 12.45 15.37 191.440 3-Methyl-c-2-pentene 00922-62-3 12.52 15.18 190.024 Cyclopentene 00142-29-0 6.69 14.82 99.067 2,4-Dimethylhexane 00589-43-5 1.61 14.18 22.763 2-Methyl-2-pentene 00625-27-4 11.03 14.12 155.789 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 12.02 79.430 ortho-Xylene 00095-47-6 7.58 11.39 86.265 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 10.87 17.454 c-2-Butene 00590-18-1 14.26 10.65 151.850 2,2-DiMeHexane 00590-73-8 0.94 9.27 8.730 2,2,5-Trimethylhexane 03522-94-9 1.05 8.74 9.207 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 8.43 37.046 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 8.27 9.027 Vehicle 206b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7567 Non Zero Mass Species Sorted By VOC

## E

- 34 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7567 Non Zero Mass Species Sorted By VOC

Ethylbenzene 00100-41-4 2.96 8.16 24.176 2,2-Dimethylbutane 00075-83-2 1.11 7.90 8.782 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.86 54.489 1,3,5-Trimethylbenzene 00108-67-8 11.75 6.74 79.229 n-Octane 00111-65-9 0.80 6.54 5.207 t-1,2-Dimethylcyclopentane 00822-50-4 3.11 6.35 19.727 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 6.09 33.755 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 5.52 31.865 c-1,3-Dimethylcyclopentane 02532-58-3 3.11 5.27 16.373 2-Methylheptane 00592-27-8 0.97 4.81 4.654 3-Methylheptane 00589-81-1 1.12 4.54 5.110 n-Propylbenzene 00103-65-1 1.96 4.54 8.898 2,2-Dimethylpentane 00590-35-2 1.04 3.35 3.496 2,2,3-Trimethylbutane 00464-06-2 1.05 3.25 3.425 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 3.18 24.924 3,3-Dimethylpentane 00562-49-2 1.12 3.16 3.534 2-Methylpropane 00075-28-5 1.18 3.06 3.600 c-1,3-Dimethylcyclohexane 00638-04-0 3.11 2.75 8.529 1,2,3-Trimethylbenzene 00526-73-8 11.94 2.49 29.713 Unknown #5 3.11 1.98 6.152 2,3,5-Trimethylhexane 01069-53-0 1.12 1.89 2.120 Indan 00496-11-7 3.23 1.83 5.910 3,3-Dimethylhexane 00563-16-6 1.15 1.68 1.936 c-2-Heptene 06443-92-1 7.08 1.67 11.836 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.65 6.357 1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.51 10.682 3,5-Dimethylheptane 00926-82-9 1.42 1.42 2.020 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.11 1.41 4.373 n-Decane 00124-18-5 0.59 1.33 0.787 Isopropylbenzene (Cumene) 00098-82-8 3.11 1.32 4.094 t-1,4-Dimethylcyclohexane 02207-04-7 3.11 1.20 3.724 t-3-Heptene 14686-14-7 6.17 1.19 7.312 1,1-Dimethylcyclohexane 00590-66-9 1.12 1.13 1.265 Unknown #13 3.11 1.12 3.470 n-Nonane 00111-84-2 0.68 1.09 0.743 2-Methyl-1,3-butadiene 00078-79-5 10.48 1.07 11.233 4-Methyloctane 02216-34-4 0.85 1.06 0.897 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.02 6.648 4-Methyl-t-2-pentene 00674-76-0 8.04 0.84 6.747 Unknown #16 3.11 0.81 2.525 1-Nonene 00124-11-8 2.49 0.80 1.983 1-Heptene 00592-76-7 4.29 0.77 3.322 

### continued

## E

- 35 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 206b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7567 Non Zero Mass Species Sorted By VOC

2,4-Dimethylheptane 02213-23-2 1.26 0.76 0.956 Unknown #3 3.11 0.74 2.297 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.73 6.103 3-Methylnonane 005911-04-6 0.66 0.72 0.470 3-Methyloctane 02216-33-3 0.88 0.67 0.593 Unknown #8 3.11 0.58 1.812 t-4-Octene 14850-23-8 4.69 0.50 2.360 Unknown #6

. 3.11 0.46 1.413 1,3-Diethylbenzene 00141-93-5 7.08 0.45 3.221 sec-Butylbenzene 00135-98-8 2.29 0.45 1.028 1,4-Diethylbenzene 00105-05-5 4.39 0.45 1.964 3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.43 4.156 Isobutylbenzene 00538-93-2 3.11 0.42 1.320 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.40 1.538 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.38 2.877 t-2-Nonene 06434-78-2 3.11 0.38 1.168 c-2-Octene 07642-04-8 3.11 0.32 0.981 Unknown #9 3.11 0.26 0.798 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.23 0.194

Total 2797.0 8687.2 3.106

No MIR available, use weighted average of 3.1059 

### continued

## E

- 36 Test Fuel Test No. Bag THC mg GC as % of THC GC VOC

mg Ozone mg Reactivity Species Present 86 ° F E10 - 10 psi 7413 75.6 127.7 96.6 413.8 4.284 42 Static E10 - 7 psi 7478 50.5 102.6 51.9 136.0 2.623 40 E0 - 9 psi 7530 74.2 121.3 90.0 287.6 3.195 52 E0 - 7 psi 7568 49.6 102.0 50.6 159.2 3.146 55

105 ° F E10 - 10 psi 7415 115.2 110.4 127.1 415.6 3.268 59 Static E10 - 7 psi 7480 105.4 104.1 109.7 391.9 3.572 76 E0 - 9 psi 7532 112.7 102.4 115.4 370.1 3.207 60 E0 - 7 psi 7570 123.9 94.4 117.0 403.3 3.448 63

Dynamic E10 - 10 psi 25744 337.0 95.8 322.8 1369.5 4.242 56 E10 - 7 psi 25759 308.3 132.8 409.4 1718.9 4.198 72 E0 - 9 psi 25771 257.5 159.1 409.6 1853.2 4.524 52 E0 - 7 psi 25782 199.7 51.9 103.6 353.6 3.413 40

DHB E10 - 10 psi 7463 1852.2 103.6 1919.2 5628.6 2.933 107 Total E10 - 7 psi 7489 1740.5 89.3 1554.4 5099.2 3.281 107 E0 - 9 psi 7556 1864.6 93.2 1737.6 4606.5 2.651 98 E0 - 7 psi 7575 1317.5 88.6 1167.2 3392.4 2.906 86 

## Vehicle 208b

## E

- 37 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 11.06 43.423 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 9.50 51.027 Ethanol 00064-17-5 1.45 8.80 12.744 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.88 58.214 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.52 50.528 2,3,4-Trimethylpentane 00565-75-3 0.95 6.12 5.809 2-Methylbutane (Isopentane) 00078-78-4 1.35 5.78 7.827 n-Butane 00106-97-8 1.08 4.61 4.969 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.24 14.225 1,3,5-Trimethylbenzene 00108-67-8 11.75 3.10 36.422 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.81 15.597 n-Hexane 00110-54-3 1.13 2.69 3.057 ortho-Xylene 00095-47-6 7.58 2.58 19.561 Methylcyclopentane 00096-37-7 2.05 1.93 3.948 Benzene 00071-43-2 0.69 1.76 1.221 n-Propylbenzene 00103-65-1 1.96 1.58 3.099 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.45 1.744 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.44 17.177 Ethylbenzene 00100-41-4 2.96 1.24 3.660 n-Pentane 00109-66-0 1.21 1.19 1.449 Cyclohexane 00110-82-7 1.14 1.18 1.343 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.11 1.548 2-Methyl-2-butene 00513-35-9 14.20 1.04 14.692 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.94 1.514 3-Methylpentane 00096-14-0 1.69 0.88 1.490 3-Methyl-t-2-pentene 00616-12-6 11.66 0.74 8.623 t-2-Pentene 00646-04-8 10.47 0.59 6.160 Methylcyclohexane 00108-87-2 1.56 0.54 0.834 n-Heptane 00142-82-5 0.97 0.49 0.475 2-Methyl-1-butene 00563-46-2 6.38 0.44 2.778 2-Methylpropane 00075-28-5 1.18 0.42 0.489 n-Octane 00111-65-9 0.80 0.41 0.327 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.38 4.469 3-Methyl-c-2-pentene 00922-62-3 12.52 0.37 4.629 2-Methylhexane 00591-76-4 1.09 0.35 0.379 t-2-Hexene 04050-45-7 8.55 0.31 2.689 c-2-Pentene 00627-20-3 10.28 0.29 2.966 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.26 0.845 2,3-Dimethylpentane 00565-59-3 1.25 0.25 0.309 2,2,5-Trimethylhexane 03522-94-9 1.05 0.17 0.176 c-2-Butene 00590-18-1 14.26 0.09 1.292 2,4-Dimethylpentane 00108-08-7 1.46 0.08 0.123

Total 96.6 413.8 4.284 Vehicle 208b - Fuel 10 psi E10 - 86 ° F Static - Test 7413 Non Zero Mass Species Sorted By VOC

## E

- 38 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 23.14 33.536 Toluene 00108-88-3 3.93 19.45 76.343 2-Methylbutane (Isopentane) 00078-78-4 1.35 10.42 14.119 n-Butane 00106-97-8 1.08 7.49 8.064 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.05 27.126 n-Hexane 00110-54-3 1.13 4.57 5.181 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.70 28.705 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.14 4.383 Benzene 00071-43-2 0.69 2.84 1.974 n-Pentane 00109-66-0 1.21 2.46 2.983 2-Methyl-2-butene 00513-35-9 14.20 2.36 33.500 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.17 2.601 t-2-Pentene 00646-04-8 10.47 1.99 20.809 3-Methylpentane 00096-14-0 1.69 1.90 3.216 Methylcyclopentane 00096-37-7 2.05 1.69 3.469 2,3-Dimethylbutane 00079-29-8 0.90 1.63 1.468 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.59 18.644 Methylcyclohexane 00108-87-2 1.56 1.55 2.413 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.50 8.314 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.50 6.592 n-Heptane 00142-82-5 0.97 1.49 1.436 Cyclohexane 00110-82-7 1.14 1.39 1.584 2-Methylhexane 00591-76-4 1.09 1.27 1.376 ortho-Xylene 00095-47-6 7.58 1.22 9.263 2-Methylpropane 00075-28-5 1.18 1.21 1.422 2-Methyl-1-butene 00563-46-2 6.38 1.14 7.282 c-2-Pentene 00627-20-3 10.28 1.03 10.608 2,2-DiMeHexane 00590-73-8 0.94 0.98 0.922 2,3,4-Trimethylpentane 00565-75-3 0.95 0.97 0.920 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.95 3.018 2,3-Dimethylpentane 00565-59-3 1.25 0.84 1.051 3-Methylheptane 00589-81-1 1.12 0.79 0.889 n-Octane 00111-65-9 0.80 0.77 0.616 n-Decane 00124-18-5 0.59 0.77 0.455 Cyclopentene 00142-29-0 6.69 0.77 5.133 n-Propylbenzene 00103-65-1 1.96 0.76 1.488 2,4-Dimethylpentane 00108-08-7 1.46 0.72 1.053 Ethylbenzene 00100-41-4 2.96 0.65 1.934 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.65 7.749 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.64 7.434 t-2-Hexene 04050-45-7 8.55 0.63 5.402 2,3,5-Trimethylhexane 01069-53-0 1.12 0.60 0.677 2,4-Dimethylhexane 00589-43-5 1.61 0.58 0.937 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.56 2.979 Vehicle 208b - Fuel 10 psi E10 - 105 ° F Static - Test 7424 Non Zero Mass Species Sorted By VOC

## E

- 39 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 10 psi E10 - 105 ° F Static - Test 7424 Non Zero Mass Species Sorted By VOC

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.54 3.538 c-2-Butene 00590-18-1 14.26 0.53 7.599 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.52 4.101 3-Methyl-c-2-pentene 00922-62-3 12.52 0.50 6.302 t-1,2-Dimethylcyclopentane 00822-50-4 3.27 0.48 1.564 n-Nonane 00111-84-2 0.68 0.44 0.301 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.41 0.653 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.39 2.790 3-Methyl-t-2-pentene 00616-12-6 11.66 0.36 4.246 2-Methyl-2-pentene 00625-27-4 11.03 0.33 3.663 2,2,5-Trimethylhexane 03522-94-9 1.05 0.32 0.336 2-Methylheptane 00592-27-8 0.97 0.27 0.260 c-1,3-Dimethylcyclopentane 02532-58-3 3.27 0.26 0.858 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.19 0.208 2,2-Dimethylbutane 00075-83-2 1.11 0.07 0.081

Total 127.1 415.6 3.268

No MIR available, use weighted average of 3.2684 

### continued

## E

- 40 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 43.48 170.672 n-Propylbenzene 00103-65-1 1.96 31.22 61.185 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 28.49 152.962 Ethanol 00064-17-5 1.45 20.14 29.185 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 19.58 144.613 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 11.37 88.165 n-Butane 00106-97-8 1.08 10.88 11.720 1,3,5-Trimethylbenzene 00108-67-8 11.75 10.32 121.351 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 9.53 41.872 2-Methylbutane (Isopentane) 00078-78-4 1.35 8.30 11.251 n-Hexane 00110-54-3 1.13 8.20 9.301 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 7.69 42.632 Benzene 00071-43-2 0.69 7.47 5.186 2-Methylpropane 00075-28-5 1.18 7.08 8.325 n-Decane 00124-18-5 0.59 6.26 3.702 1,2,3-Trimethylbenzene 00526-73-8 11.94 5.96 71.104 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.97 39.448 ortho-Xylene 00095-47-6 7.58 4.95 37.537 Unknown #22 4.24 4.48 19.024 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.38 5.256 1,3-Butadiene 00106-99-0 12.45 3.93 48.972 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.62 5.061 2,3-Dimethylbutane 00079-29-8 0.90 3.47 3.114 Indan 00496-11-7 3.23 3.32 10.737 n-Octane 00111-65-9 0.80 3.11 2.478 3-Methylpentane 00096-14-0 1.69 2.93 4.958 Methylcyclohexane 00108-87-2 1.56 2.75 4.275 n-Nonane 00111-84-2 0.68 2.74 1.872 1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.64 18.726 t-2-Pentene 00646-04-8 10.47 2.62 27.487 2,3,5-Trimethylhexane 01069-53-0 1.12 2.52 2.818 2,4-Dimethylhexane 00589-43-5 1.61 2.47 3.970 Methylcyclopentane 00096-37-7 2.05 2.19 4.493 Cyclohexane 00110-82-7 1.14 2.11 2.394 Ethylbenzene 00100-41-4 2.96 2.10 6.233 t-2-Hexene 04050-45-7 8.55 1.82 15.585 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.74 20.334 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.64 1.786 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.63 2.611 n-Pentane 00109-66-0 1.21 1.60 1.946 2,3,4-Trimethylpentane 00565-75-3 0.95 1.54 1.465 2-Methylheptane 00592-27-8 0.97 1.39 1.340 2,3-Dimethylpentane 00565-59-3 1.25 1.35 1.687 2-Methyl-2-pentene 00625-27-4 11.03 1.30 14.366 Vehicle 208b - Fuel 10 psi E10 - Dynamic - Test 25744 Non Zero Mass Species Sorted By VOC

## E

- 41 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 10 psi E10 - Dynamic - Test 25744 Non Zero Mass Species Sorted By VOC

Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.22 3.888 3-Methyl-t-2-pentene 00616-12-6 11.66 1.19 13.917 c-2-Butene 00590-18-1 14.26 1.18 16.826 3-Methyl-c-2-pentene 00922-62-3 12.52 1.15 14.398 c-2-Pentene 00627-20-3 10.28 1.13 11.662 2-Methyl-1-butene 00563-46-2 6.38 1.11 7.093 n-Heptane 00142-82-5 0.97 1.02 0.987 2-Methylhexane 00591-76-4 1.09 0.95 1.034 2,2,5-Trimethylhexane 03522-94-9 1.05 0.95 1.002 Cyclopentene 00142-29-0 6.69 0.78 5.200 2-Methyl-2-butene 00513-35-9 14.20 0.71 10.103 2,4-Dimethylpentane 00108-08-7 1.46 0.11 0.162

Total 322.8 1369.5 4.242

No MIR available, use weighted average of 4.2422 

### continued

## E

- 42 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 304.65 441.435 n-Butane 00106-97-8 1.08 222.82 239.960 Toluene 00108-88-3 3.93 203.31 798.007 2-Methylbutane (Isopentane) 00078-78-4 1.35 151.53 205.313 n-Hexane 00110-54-3 1.13 127.32 144.463 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 67.88 94.875 3-Methylpentane 00096-14-0 1.69 49.21 83.206 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 48.37 58.050 2-Methyl-2-butene 00513-35-9 14.20 45.52 646.141 Benzene 00071-43-2 0.69 44.28 30.747 n-Pentane 00109-66-0 1.21 40.33 48.994 t-2-Pentene 00646-04-8 10.47 38.38 401.979 Methylcyclopentane 00096-37-7 2.05 34.84 71.406 Cyclohexane 00110-82-7 1.14 32.56 37.029 2,3-Dimethylbutane 00079-29-8 0.90 26.99 24.254 n-Propylbenzene 00103-65-1 1.96 21.68 42.492 Methylcyclohexane 00108-87-2 1.56 21.43 33.332 2,3,4-Trimethylpentane 00565-75-3 0.95 21.05 19.972 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 20.11 155.988 n-Heptane 00142-82-5 0.97 20.08 19.391 c-2-Pentene 00627-20-3 10.28 19.50 200.531 2-Methylhexane 00591-76-4 1.09 19.22 20.858 2-Methyl-1-butene 00563-46-2 6.38 18.36 117.083 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 17.73 56.577 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 16.26 87.281 2,4-Dimethylpentane 00108-08-7 1.46 14.54 21.214 t-2-Hexene 04050-45-7 8.55 12.79 109.358 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 11.98 140.179 n-Octane 00111-65-9 0.80 10.30 8.203 2,3-Dimethylpentane 00565-59-3 1.25 10.15 12.665 2,4-Dimethylhexane 00589-43-5 1.61 9.90 15.898 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 9.78 51.836 3-Methyl-t-2-pentene 00616-12-6 11.66 9.52 111.028 1-Methylcyclopentene 00693-89-0 12.45 8.82 109.908 3-Methyl-c-2-pentene 00922-62-3 12.52 8.70 108.885 2-Methyl-2-pentene 00625-27-4 11.03 7.77 85.668 c-2-Butene 00590-18-1 14.26 7.76 110.587 Cyclopentene 00142-29-0 6.69 7.56 50.547 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 7.19 11.539 2,2,5-Trimethylhexane 03522-94-9 1.05 7.05 7.428 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 6.97 46.030 1,3,5-Trimethylbenzene 00108-67-8 11.75 6.90 81.131 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 6.69 29.395 ortho-Xylene 00095-47-6 7.58 6.06 45.874 Vehicle 208b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7463 Non Zero Mass Species Sorted By VOC

## E

- 43 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7463 Non Zero Mass Species Sorted By VOC

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 6.04 33.447 2,2-DiMeHexane 00590-73-8 0.94 5.82 5.476 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 5.58 6.095 2-Methylheptane 00592-27-8 0.97 5.35 5.177 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 5.30 42.092 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.84 35.784 3-Methylheptane 00589-81-1 1.12 4.34 4.885 t-1,2-Dimethylcyclopentane 00822-50-4 2.93 4.26 12.501 Ethylbenzene 00100-41-4 2.96 4.03 11.926 c-1,3-Dimethylcyclohexane 00638-04-0 2.93 3.64 10.664 c-1,3-Dimethylcyclopentane 02532-58-3 2.93 3.42 10.033 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 3.34 19.320 n-Nonane 00111-84-2 0.68 3.07 2.099 2,2-Dimethylpentane 00590-35-2 1.04 3.03 3.159 2,2-Dimethylbutane 00075-83-2 1.11 2.92 3.248 Unknown #16 2.93 2.90 8.514 3,3-Dimethylpentane 00562-49-2 1.12 2.57 2.870 1,2,3-Trimethylbenzene 00526-73-8 11.94 2.40 28.710 n-Decane 00124-18-5 0.59 2.35 1.391 Ethylcyclohexane 01678-91-7 1.35 2.00 2.687 2,2,3-Trimethylbutane 00464-06-2 1.05 1.88 1.980 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.85 14.502 4-Methyloctane 02216-34-4 0.85 1.74 1.474 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.62 6.275 1,4-Diethylbenzene 00105-05-5 4.39 1.56 6.852 t-1,4-Dimethylcyclohexane 02207-04-7 2.93 1.52 4.444 Indan 00496-11-7 3.23 1.39 4.500 3,3-Dimethylhexane 00563-16-6 1.15 1.27 1.464 2,3,5-Trimethylhexane 01069-53-0 1.12 1.26 1.414 1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.25 8.853 Unknown #8 2.93 1.25 3.659 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.93 1.24 3.644 Unknown #5 2.93 1.22 3.565 c-2-Heptene 06443-92-1 7.08 1.20 8.479 3-Methyloctane 02216-33-3 0.88 1.11 0.979 Unknown #13 2.93 1.07 3.130 3,5-Dimethylheptane 00926-82-9 1.42 1.05 1.494 1,1-Dimethylcyclohexane 00590-66-9 1.12 0.92 1.027 Isopropylbenzene (Cumene) 00098-82-8 2.93 0.89 2.597 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 0.88 1.044 1,3-Butadiene 00106-99-0 12.45 0.84 10.453 2,4-Dimethylheptane 02213-23-2 1.26 0.79 1.004 

### continued

## E

- 44 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7463 Non Zero Mass Species Sorted By VOC

t-3-Heptene 14686-14-7 6.17 0.79 4.845 sec-Butylbenzene 00135-98-8 2.29 0.73 1.683 1-Nonene 00124-11-8 2.49 0.70 1.755 2,2-Dimethyloctane 15869-87-1 0.76 0.70 0.532 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.57 6.012 1,3-Diethylbenzene 00141-93-5 7.08 0.57 4.028 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.55 3.571 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.52 3.891 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.51 4.271 Isobutylbenzene 00538-93-2 2.93 0.50 1.477 1-Heptene 00592-76-7 4.29 0.49 2.099 Unknown #9 2.93 0.47 1.382 t-2-Nonene 06434-78-2 2.93 0.47 1.372 4-Methyl-t-2-pentene 00674-76-0 8.04 0.41 3.270 c- & t-4-Nonene 02198-23-4 4.42 0.39 1.703 Unknown #15 2.93 0.38 1.113 Unknown #3 2.93 0.35 1.025 Unknown #14 2.93 0.35 1.017 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.34 1.295 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.31 0.267 3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.24 2.389

Total 1919.2 5628.6 2.933

No MIR available, use weighted average of 2.9328 

### continued

## E

- 45 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 13.42 19.440 Toluene 00108-88-3 3.93 12.66 49.684 2-Methylbutane (Isopentane) 00078-78-4 1.35 5.73 7.768 n-Butane 00106-97-8 1.08 4.23 4.558 n-Pentane 00109-66-0 1.21 1.94 2.362 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.44 10.670 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.27 1.777 2,4-Dimethylpentane 00108-08-7 1.46 1.10 1.611 2,3-Dimethylbutane 00079-29-8 0.90 1.00 0.899 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.90 1.080 Unknown #16 2.62 0.57 1.507 2,3,4-Trimethylpentane 00565-75-3 0.95 0.57 0.540 n-Decane 00124-18-5 0.59 0.54 0.317 n-Hexane 00110-54-3 1.13 0.52 0.591 c-2-Butene 00590-18-1 14.26 0.52 7.382 3-Methylpentane 00096-14-0 1.69 0.45 0.768 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.39 4.539 t-2-Pentene 00646-04-8 10.47 0.38 3.958 2-Methylhexane 00591-76-4 1.09 0.36 0.387 Indan 00496-11-7 3.23 0.32 1.041 2,4-Dimethylhexane 00589-43-5 1.61 0.32 0.515 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.31 1.203 2,3-Dimethylpentane 00565-59-3 1.25 0.28 0.350 Methylcyclopentane 00096-37-7 2.05 0.28 0.574 2,2,5-Trimethylhexane 03522-94-9 1.05 0.27 0.282 t-1,2-Dimethylcyclopentane 00822-50-4 2.62 0.27 0.696 2-Methyl-2-butene 00513-35-9 14.20 0.24 3.374 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.22 2.571 2-Methyl-1-butene 00563-46-2 6.38 0.21 1.355 3-Methylheptane 00589-81-1 1.12 0.20 0.220 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.19 0.209 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.18 0.777 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.17 1.190 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.10 0.640 Cyclopentene 00142-29-0 6.69 0.09 0.619 2,2-Dimethylbutane 00075-83-2 1.11 0.08 0.092 2,3,5-Trimethylhexane 01069-53-0 1.12 0.06 0.072 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.05 0.083 c-2-Pentene 00627-20-3 10.28 0.03 0.315 ortho-Xylene 00095-47-6 7.58 0.00 0.018

Total 51.9 136.0 2.623

No MIR available, use weighted average of 2.6226 Vehicle 208b - Fuel 7 psi E10 - 86 ° F Static - Test 7466 Non Zero Mass Species Sorted By VOC

## E

- 46 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 18.17 26.321 Toluene 00108-88-3 3.93 15.73 61.725 n-Hexane 00110-54-3 1.13 6.45 7.317 2-Methylbutane (Isopentane) 00078-78-4 1.35 5.34 7.233 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.62 5.056 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 3.34 24.682 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.99 16.036 n-Butane 00106-97-8 1.08 2.46 2.653 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.25 2.693 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.15 16.664 2-Methyl-2-butene 00513-35-9 14.20 2.05 29.124 3-Methylpentane 00096-14-0 1.69 1.99 3.370 Methylcyclopentane 00096-37-7 2.05 1.92 3.928 t-2-Pentene 00646-04-8 10.47 1.85 19.379 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.82 21.352 n-Pentane 00109-66-0 1.21 1.77 2.153 Benzene 00071-43-2 0.69 1.70 1.178 2-Methylpropane 00075-28-5 1.18 1.58 1.861 Cyclohexane 00110-82-7 1.14 1.48 1.687 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.41 6.191 Unknown #16 3.57 1.38 4.935 2-Methylhexane 00591-76-4 1.09 1.34 1.449 2,3-Dimethylbutane 00079-29-8 0.90 1.33 1.199 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.14 6.292 Methylcyclohexane 00108-87-2 1.56 1.07 1.661 1-Methylcyclopentene 00693-89-0 12.45 0.99 12.341 2,4-Dimethylpentane 00108-08-7 1.46 0.94 1.373 t-1,2-Dimethylcyclopentane 00822-50-4 3.57 0.92 3.274 2-Methyl-1-butene 00563-46-2 6.38 0.88 5.614 ortho-Xylene 00095-47-6 7.58 0.84 6.374 2,3,5-Trimethylhexane 01069-53-0 1.12 0.80 0.891 c-1,3-Dimethylcyclohexane 00638-04-0 3.57 0.79 2.834 2,3,4-Trimethylpentane 00565-75-3 0.95 0.73 0.690 c-2-Pentene 00627-20-3 10.28 0.72 7.413 n-Heptane 00142-82-5 0.97 0.69 0.665 t-2-Hexene 04050-45-7 8.55 0.68 5.813 3-Methylheptane 00589-81-1 1.12 0.64 0.720 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.62 7.437 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.58 1.862 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.58 6.822 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.58 0.629 2-Methylheptane 00592-27-8 0.97 0.55 0.536 4-Methyloctane 02216-34-4 0.85 0.53 0.450 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.52 3.403 Vehicle 208b - Fuel 7 psi E10 - 105 ° F Static - Test 7480 Non Zero Mass Species Sorted By VOC

## E

- 47 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 7 psi E10 - 105 ° F Static - Test 7480 Non Zero Mass Species Sorted By VOC

c-2-Butene 00590-18-1 14.26 0.51 7.328 2,3-Dimethylpentane 00565-59-3 1.25 0.50 0.630 2,2-Dimethylpentane 00590-35-2 1.04 0.48 0.499 Unknown #18 3.57 0.47 1.664 3-Methyl-t-2-pentene 00616-12-6 11.66 0.46 5.406 2-Methyl-2-pentene 00625-27-4 11.03 0.42 4.603 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.41 2.389 n-Octane 00111-65-9 0.80 0.40 0.322 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.39 0.634 Isopropylbenzene (Cumene) 00098-82-8 3.57 0.38 1.368 1,4-Diethylbenzene 00105-05-5 4.39 0.38 1.657 n-Propylbenzene 00103-65-1 1.96 0.37 0.730 n-Decane 00124-18-5 0.59 0.37 0.220 Indan 00496-11-7 3.23 0.35 1.130 Cyclopentene 00142-29-0 6.69 0.33 2.238 2,2-DiMeHexane 00590-73-8 0.94 0.33 0.314 c-1,3-Dimethylcyclopentane 02532-58-3 3.57 0.32 1.141 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.31 1.186 2,2,5-Trimethylhexane 03522-94-9 1.05 0.30 0.311 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.29 2.183 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.28 1.474 t-1,4-Dimethylcyclohexane 02207-04-7 3.57 0.25 0.907 Unknown #1 3.57 0.24 0.852 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.23 0.875 3,3-Dimethyl-1-butene 00558-37-2 5.68 0.20 1.115 Ethylbenzene 00100-41-4 2.96 0.20 0.579 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.18 1.836 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.17 1.302 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.13 1.041 2,4-Dimethylhexane 00589-43-5 1.61 0.10 0.156 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.08 0.539 2,2-Dimethylbutane 00075-83-2 1.11 0.02 0.024

Total 109.7 391.9 3.572

No MIR available, use weighted average of 3.5716 

### continued

## E

- 48 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 44.29 47.694 Toluene 00108-88-3 3.93 40.01 157.028 Ethanol 00064-17-5 1.45 31.03 44.959 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 29.45 217.541 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 18.29 98.224 2-Methylbutane (Isopentane) 00078-78-4 1.35 15.90 21.542 n-Hexane 00110-54-3 1.13 13.82 15.678 Benzene 00071-43-2 0.69 10.84 7.524 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 9.61 42.209 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.62 66.887 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 8.37 98.005 1,3,5-Trimethylbenzene 00108-67-8 11.75 8.19 96.312 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 7.91 11.057 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 7.39 40.969 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 7.01 8.406 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.29 49.968 2-Methyl-2-butene 00513-35-9 14.20 5.96 84.605 3-Methylpentane 00096-14-0 1.69 5.74 9.698 n-Pentane 00109-66-0 1.21 5.51 6.698 2,3,3-Trimethylpentane 00560-21-4 0.95 5.46 5.168 2,3-Dimethylbutane 00079-29-8 0.90 5.31 4.771 n-Decane 00124-18-5 0.59 5.12 3.023 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 4.79 37.502 Cyclohexane 00110-82-7 1.14 4.17 4.739 Ethylbenzene 00100-41-4 2.96 4.06 12.017 Methylcyclopentane 00096-37-7 2.05 3.85 7.900 t-2-Pentene 00646-04-8 10.47 3.84 40.194 Cyclopentene 00142-29-0 6.69 3.69 24.647 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 3.67 23.104 Unknown #23 4.20 3.63 15.257 c-2-Pentene 00627-20-3 10.28 3.60 37.032 4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 3.53 15.550 n-Propylbenzene 00103-65-1 1.96 3.49 6.849 2-Methyl-1-butene 00563-46-2 6.38 3.49 22.291 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 3.44 10.991 1,3-Butadiene 00106-99-0 12.45 3.15 39.249 c-2-Butene 00590-18-1 14.26 3.08 43.992 ortho-Xylene 00095-47-6 7.58 3.03 22.950 2,4-Dimethylhexane 00589-43-5 1.61 2.76 4.427 3-Methyl-c-2-pentene 00922-62-3 12.52 2.67 33.377 Unknown #16 4.20 2.52 10.589 n-Octane 00111-65-9 0.80 2.39 1.907 Ethane 00074-84-0 0.26 2.39 0.628 t-2-Hexene 04050-45-7 8.55 2.15 18.343 Vehicle 208b - Fuel 7 psi E10 - Dynamic - Test 25759 Non Zero Mass Species Sorted By VOC

## E

- 49 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 7 psi E10 - Dynamic - Test 25759 Non Zero Mass Species Sorted By VOC

2-Methylhexane 00591-76-4 1.09 2.08 2.261 1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.08 14.750 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.03 3.261 1-Octene 00111-66-0 3.14 1.97 6.182 3-Methylheptane 00589-81-1 1.12 1.74 1.959 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 1.65 8.720 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.59 6.140 3-Methyl-t-2-pentene 00616-12-6 11.66 1.56 18.216 2,3,5-Trimethylhexane 01069-53-0 1.12 1.52 1.704 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.46 1.593 Indan 00496-11-7 3.23 1.41 4.569 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.37 9.083 2,3-Dimethylpentane 00565-59-3 1.25 1.32 1.646 2-Methyl-2-pentene 00625-27-4 11.03 1.31 14.479 2,2-DiMeHexane 00590-73-8 0.94 1.26 1.190 1-Methyl-2-Propylbenzene 01074-17-5 5.43 1.17 6.364 c-2-Heptene 06443-92-1 7.08 1.16 8.215 n-Nonane 00111-84-2 0.68 1.16 0.791 2-Methyl-1,3-butadiene 00078-79-5 10.48 1.15 12.008 4-Methyloctane 02216-34-4 0.85 1.03 0.871 2,2-Dimethylbutane 00075-83-2 1.11 0.97 1.073 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 0.94 1.108 1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 0.84 6.332 t-1,2-Dimethylcyclopentane 00822-50-4 4.20 0.84 3.506 Unknown #18 4.20 0.79 3.313 1,3-Diethylbenzene 00141-93-5 7.08 0.57 4.023 Cyclopentadiene 00542-92-7 6.89 0.53 3.622 2,2-Dimethylpentane 00590-35-2 1.04 0.40 0.421

Total 409.4 1718.9 4.198

No MIR available, use weighted average of 4.1985 

### continued

## E

- 50 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 272.11 394.281 Toluene 00108-88-3 3.93 180.22 707.380 2-Methylbutane (Isopentane) 00078-78-4 1.35 131.81 178.590 n-Hexane 00110-54-3 1.13 115.21 130.730 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 59.52 83.203 Benzene 00071-43-2 0.69 47.52 32.995 3-Methylpentane 00096-14-0 1.69 43.72 73.931 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 43.69 52.394 2-Methyl-2-butene 00513-35-9 14.20 40.42 573.824 n-Pentane 00109-66-0 1.21 36.90 44.826 t-2-Pentene 00646-04-8 10.47 35.21 368.761 n-Butane 00106-97-8 1.08 34.54 37.199 Methylcyclopentane 00096-37-7 2.05 31.08 63.707 Cyclohexane 00110-82-7 1.14 29.67 33.748 2,3-Dimethylbutane 00079-29-8 0.90 23.40 21.034 2,3,3-Trimethylpentane 00560-21-4 0.95 20.16 19.061 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 19.18 120.861 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 18.65 144.643 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 18.28 143.250 c-2-Pentene 00627-20-3 10.28 17.84 183.408 2-Methylhexane 00591-76-4 1.09 17.45 18.938 2-Methyl-1-butene 00563-46-2 6.38 16.93 108.012 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 15.35 48.985 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 14.64 108.113 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 13.76 73.861 2,4-Dimethylpentane 00108-08-7 1.46 12.81 18.699 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 11.54 135.123 t-2-Hexene 04050-45-7 8.55 11.24 96.084 n-Octane 00111-65-9 0.80 9.92 7.899 2,4-Dimethylhexane 00589-43-5 1.61 9.52 15.290 2,3-Dimethylpentane 00565-59-3 1.25 9.08 11.339 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 8.60 45.544 3-Methyl-c-2-pentene 00922-62-3 12.52 8.60 107.599 3-Methyl-t-2-pentene 00616-12-6 11.66 8.35 97.416 c-2-Butene 00590-18-1 14.26 7.37 105.100 1-Octene 00111-66-0 3.14 7.22 22.695 2-Methyl-2-pentene 00625-27-4 11.03 7.10 78.373 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 7.01 11.248 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 6.56 43.336 Cyclopentene 00142-29-0 6.69 6.46 43.182 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 5.78 45.866 ortho-Xylene 00095-47-6 7.58 5.45 41.303 1,3,5-Trimethylbenzene 00108-67-8 11.75 5.41 63.568 2,3,5-Trimethylhexane 01069-53-0 1.12 5.38 6.030 Vehicle 208b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7489 Non Zero Mass Species Sorted By VOC

## E

- 51 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7489 Non Zero Mass Species Sorted By VOC

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.34 23.450 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 5.19 5.670 2,2-DiMeHexane 00590-73-8 0.94 4.77 4.492 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 4.67 25.903 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 4.58 17.712 2-Methylpropane 00075-28-5 1.18 4.38 5.158 3-Methylheptane 00589-81-1 1.12 4.17 4.688 t-1,2-Dimethylcyclopentane 00822-50-4 3.28 3.69 12.089 t-1,4-Dimethylcyclohexane 02207-04-7 3.28 3.40 11.162 n-Propylbenzene 00103-65-1 1.96 3.17 6.214 Ethylbenzene 00100-41-4 2.96 3.12 9.246 1,2,3-Trimethylbenzene 00526-73-8 11.94 3.12 37.225 2,2-Dimethylpentane 00590-35-2 1.04 2.84 2.965 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.79 16.094 c-1,3-Dimethylcyclopentane 02532-58-3 3.28 2.58 8.449 2,2-Dimethylbutane 00075-83-2 1.11 2.52 2.800 n-Nonane 00111-84-2 0.68 2.45 1.671 Unknown #16 3.28 2.25 7.379 4-Methyloctane 02216-34-4 0.85 2.03 1.718 3,5-Dimethylheptane 00926-82-9 1.42 2.00 2.852 3,3-Dimethylpentane 00562-49-2 1.12 1.97 2.206 n-Decane 00124-18-5 0.59 1.90 1.125 Ethylene 00074-85-1 8.88 1.59 14.130 Ethane 00074-84-0 0.26 1.50 0.395 Unknown #13 3.28 1.46 4.783 2,2,3-Trimethylbutane 00464-06-2 1.05 1.39 1.470 1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.26 8.930 Unknown #5 3.28 1.24 4.074 Indan 00496-11-7 3.23 1.12 3.633 3-Methyloctane 02216-33-3 0.88 1.00 0.883 Unknown #8 3.28 0.97 3.192 1,1-Dimethylcyclohexane 00590-66-9 1.12 0.97 1.079 1,3-Butadiene 00106-99-0 12.45 0.95 11.892 1-Nonene 00124-11-8 2.49 0.93 2.313 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.28 0.92 3.015 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.90 0.767 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 0.86 1.021 3,3-Dimethylhexane 00563-16-6 1.15 0.85 0.984 t-4-Octene 14850-23-8 4.69 0.76 3.555 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.75 7.901 2,4-Dimethylheptane 02213-23-2 1.26 0.74 0.939 c-2-Heptene 06443-92-1 7.08 0.74 5.252 

### continued

## E

- 52 1,3-Diethylbenzene 00141-93-5 7.08 0.72 5.097 Unknown #9 3.28 0.65 2.116 t-3-Heptene 14686-14-7 6.17 0.62 3.853 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.61 3.986 t-2-Nonene 06434-78-2 3.28 0.61 1.993 Isopropylbenzene (Cumene) 00098-82-8 3.28 0.59 1.950 1-Methyl-2-Propylbenzene 01074-17-5 5.43 0.59 3.198 sec-Butylbenzene 00135-98-8 2.29 0.56 1.281 1,4-Diethylbenzene 00105-05-5 4.39 0.50 2.190 Unknown #14 3.28 0.49 1.613 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.45 1.734 4-Methyl-t-2-pentene 00674-76-0 8.04 0.43 3.493 Unknown #3 3.28 0.43 1.408 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.38 3.215 1-Heptene 00592-76-7 4.29 0.37 1.580 2,3,4-Trimethylpentane 00565-75-3 0.95 0.37 0.348 c- & t-4-Nonene 02198-23-4 4.42 0.33 1.465 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.32 2.411 Isobutylbenzene 00538-93-2 3.28 0.29 0.956 1-Methylcyclopentene 00693-89-0 12.45 0.26 3.247 3-Methylnonane 005911-04-6 0.66 0.23 0.149

Total 1554.4 5099.2 3.281

No MIR available, use weighted average of 3.2806 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7489 Non Zero Mass Species Sorted By VOC 

### continued

## E

- 53 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 11.13 11.987 Toluene 00108-88-3 3.93 10.03 39.373 2-Methylbutane (Isopentane) 00078-78-4 1.35 7.82 10.589 Cyclohexane 00110-82-7 1.14 7.12 8.097 Ethanol 00064-17-5 1.45 4.65 6.745 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.56 33.649 n-Hexane 00110-54-3 1.13 3.83 4.349 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.46 4.149 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.82 3.936 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.29 17.789 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.76 9.464 Benzene 00071-43-2 0.69 1.75 1.215 2,3-Dimethylbutane 00079-29-8 0.90 1.74 1.567 3-Methylpentane 00096-14-0 1.69 1.72 2.901 Methylcyclopentane 00096-37-7 2.05 1.66 3.403 2,3,4-Trimethylpentane 00565-75-3 0.95 1.46 1.387 n-Pentane 00109-66-0 1.21 1.44 1.751 2-Methyl-2-butene 00513-35-9 14.20 1.18 16.745 2,4-Dimethylhexane 00589-43-5 1.61 1.16 1.864 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.09 6.016 t-2-Pentene 00646-04-8 10.47 1.06 11.079 2,4-Dimethylpentane 00108-08-7 1.46 0.89 1.305 2,2,5-Trimethylhexane 03522-94-9 1.05 0.89 0.933 2-Methylhexane 00591-76-4 1.09 0.81 0.875 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.77 3.377 t-2-Hexene 04050-45-7 8.55 0.76 6.477 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.74 8.746 3-Methyl-c-2-pentene 00922-62-3 12.52 0.66 8.273 n-Propylbenzene 00103-65-1 1.96 0.65 1.271 2,3-Dimethylpentane 00565-59-3 1.25 0.64 0.794 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.61 3.217 3-Methyl-t-2-pentene 00616-12-6 11.66 0.61 7.079 Unknown #22 3.19 0.56 1.792 2-Methyl-1-butene 00563-46-2 6.38 0.56 3.568 Ethylbenzene 00100-41-4 2.96 0.55 1.628 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.52 6.262 ortho-Xylene 00095-47-6 7.58 0.52 3.946 n-Heptane 00142-82-5 0.97 0.50 0.482 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.49 5.688 2-Methyl-2-pentene 00625-27-4 11.03 0.45 4.920 Indan 00496-11-7 3.23 0.44 1.436 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.44 1.400 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.43 2.840 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.43 0.469 Vehicle 208b - Fuel 9 psi E0 - 86 ° F Static - Test 7530 Non Zero Mass Species Sorted By VOC

## E

- 54 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 9 psi E0 - 86 ° F Static - Test 7530 Non Zero Mass Species Sorted By VOC

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.39 0.618 3-Methylheptane 00589-81-1 1.12 0.38 0.427 2-Methylheptane 00592-27-8 0.97 0.34 0.329 c-2-Pentene 00627-20-3 10.28 0.31 3.189 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.30 2.403 Cyclopentene 00142-29-0 6.69 0.29 1.942 c-2-Butene 00590-18-1 14.26 0.26 3.711 2,2-Dimethylbutane 00075-83-2 1.11 0.12 0.132

Total 90.0 287.6 3.195

No MIR available, use weighted average of 3.1946 

### continued

## E

- 55 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 15.66 61.452 n-Butane 00106-97-8 1.08 11.72 12.625 Cyclohexane 00110-82-7 1.14 9.05 10.291 2-Methylbutane (Isopentane) 00078-78-4 1.35 8.80 11.921 Ethanol 00064-17-5 1.45 8.28 11.996 n-Hexane 00110-54-3 1.13 4.60 5.215 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.91 4.690 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.64 28.201 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.52 4.921 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.12 16.775 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.86 21.113 Benzene 00071-43-2 0.69 2.49 1.726 3-Methylpentane 00096-14-0 1.69 2.40 4.061 2,3-Dimethylbutane 00079-29-8 0.90 2.00 1.800 2,3,4-Trimethylpentane 00565-75-3 0.95 1.83 1.733 Methylcyclopentane 00096-37-7 2.05 1.80 3.680 2-Methyl-2-butene 00513-35-9 14.20 1.69 24.058 n-Pentane 00109-66-0 1.21 1.64 1.991 t-2-Pentene 00646-04-8 10.47 1.47 15.391 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.31 5.735 ortho-Xylene 00095-47-6 7.58 1.28 9.660 2,4-Dimethylpentane 00108-08-7 1.46 1.19 1.744 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.06 12.427 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.98 5.183 2,4-Dimethylhexane 00589-43-5 1.61 0.92 1.480 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.80 9.383 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.79 4.386 2-Methylhexane 00591-76-4 1.09 0.78 0.847 2,3-Dimethylpentane 00565-59-3 1.25 0.70 0.868 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.68 1.089 Ethylbenzene 00100-41-4 2.96 0.67 1.986 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.67 2.135 2-Methyl-1-butene 00563-46-2 6.38 0.66 4.208 t-1,2-Dimethylcyclopentane 00822-50-4 3.21 0.66 2.105 c-2-Pentene 00627-20-3 10.28 0.65 6.727 2-Methylheptane 00592-27-8 0.97 0.64 0.622 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.63 7.474 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.62 4.125 2,2-Dimethylbutane 00075-83-2 1.11 0.61 0.683 2,2,5-Trimethylhexane 03522-94-9 1.05 0.59 0.625 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.55 0.602 t-2-Hexene 04050-45-7 8.55 0.54 4.582 n-Propylbenzene 00103-65-1 1.96 0.54 1.049 Cyclopentene 00142-29-0 6.69 0.49 3.274 Vehicle 208b - Fuel 9 psi E0 - 105 ° F Static - Test 7532 Non Zero Mass Species Sorted By VOC

## E

- 56 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 9 psi E0 - 105 ° F Static - Test 7532 Non Zero Mass Species Sorted By VOC

2-Methyl-2-pentene 00625-27-4 11.03 0.48 5.339 Methylcyclohexane 00108-87-2 1.56 0.48 0.744 2,2-DiMeHexane 00590-73-8 0.94 0.48 0.449 Unknown #16 3.21 0.46 1.472 3-Methyl-c-2-pentene 00922-62-3 12.52 0.45 5.667 1-Methylcyclopentene 00693-89-0 12.45 0.45 5.568 3-Methylheptane 00589-81-1 1.12 0.43 0.480 c-2-Butene 00590-18-1 14.26 0.42 6.040 n-Octane 00111-65-9 0.80 0.42 0.331 n-Heptane 00142-82-5 0.97 0.39 0.376 c-1,3-Dimethylcyclopentane 02532-58-3 3.21 0.33 1.051 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.33 2.591 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.32 2.270 n-Nonane 00111-84-2 0.68 0.24 0.165 2,4-Dimethylheptane 02213-23-2 1.26 0.21 0.266 3-Methyl-t-2-pentene 00616-12-6 11.66 0.05 0.607

Total 115.4 370.1 3.207

No MIR available, use weighted average of 3.2066 

### continued

## E

- 57 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 49.24 193.287 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 28.61 211.333 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 24.19 129.907 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 23.46 181.972 n-Hexane 00110-54-3 1.13 22.68 25.733 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 19.89 23.856 Cyclohexane 00110-82-7 1.14 19.72 22.424 3-Me-1-Hexene 03404-61-3 4.27 13.55 57.915 1,3,5-Trimethylbenzene 00108-67-8 11.75 12.44 146.274 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 10.63 46.701 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 9.20 12.855 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 9.20 53.133 Benzene 00071-43-2 0.69 9.16 6.362 2,3,4-Trimethylpentane 00565-75-3 0.95 8.61 8.171 3-Methylpentane 00096-14-0 1.69 8.01 13.547 ortho-Xylene 00095-47-6 7.58 6.97 52.783 n-Pentane 00109-66-0 1.21 6.76 8.212 Methylcyclopentane 00096-37-7 2.05 6.65 13.629 2-Methylhexane 00591-76-4 1.09 6.57 7.132 n-Heptane 00142-82-5 0.97 6.43 6.208 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 5.90 32.693 1-Methylcyclopentene 00693-89-0 12.45 5.55 69.091 2,3-Dimethylbutane 00079-29-8 0.90 5.47 4.916 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 5.09 16.242 4-Methyl-t-2-pentene 00674-76-0 8.04 4.94 39.753 Ethylbenzene 00100-41-4 2.96 4.88 14.467 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.78 37.998 Unknown #22 4.52 4.76 21.530 2,2,5-Trimethylhexane 03522-94-9 1.05 4.54 4.777 2-Methyl-2-butene 00513-35-9 14.20 4.45 63.114 n-Butane 00106-97-8 1.08 4.42 4.764 2-Methylbutane (Isopentane) 00078-78-4 1.35 3.73 5.048 Indan 00496-11-7 3.23 3.59 11.626 n-Propylbenzene 00103-65-1 1.96 3.56 6.975 2,4-Dimethylpentane 00108-08-7 1.46 3.33 4.858 1,2,3-Trimethylbenzene 00526-73-8 11.94 3.32 39.635 2-Methyl-1,3-butadiene 00078-79-5 10.48 3.10 32.468 3-Methyl-t-2-pentene 00616-12-6 11.66 3.05 35.574 2,3-Dimethylpentane 00565-59-3 1.25 2.92 3.646 t-2-Pentene 00646-04-8 10.47 2.91 30.439 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 2.84 33.293 2,4-Dimethylhexane 00589-43-5 1.61 2.68 4.305 2,2-Dimethylpentane 00590-35-2 1.04 2.58 2.688 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.45 2.673 Vehicle 208b - Fuel 9 psi E0 - Dynamic - Test 25771 Non Zero Mass Species Sorted By VOC

## E

- 58 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 9 psi E0 - Dynamic - Test 25771 Non Zero Mass Species Sorted By VOC

t-2-Hexene 04050-45-7 8.55 2.10 17.988 2,3,5-Trimethylhexane 01069-53-0 1.12 2.01 2.248 2-Methyl-1-butene 00563-46-2 6.38 1.91 12.174 c-2-Pentene 00627-20-3 10.28 1.80 18.508 1,3-Butadiene 00106-99-0 12.45 1.49 18.584 c-2-Butene 00590-18-1 14.26 1.47 21.026 Cyclopentene 00142-29-0 6.69 1.14 7.607 3-Methyl-c-2-pentene 00922-62-3 12.52 0.88 11.062

Total 409.6 1853.2 4.524

No MIR available, use weighted average of 4.5241 

### continued

## E

- 59 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 226.83 307.323 n-Butane 00106-97-8 1.08 223.98 241.202 Cyclohexane 00110-82-7 1.14 192.86 219.354 Toluene 00108-88-3 3.93 167.30 656.673 n-Hexane 00110-54-3 1.13 94.18 106.869 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 82.44 98.861 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 72.60 101.472 3-Methylpentane 00096-14-0 1.69 49.77 84.157 2,3-Dimethylbutane 00079-29-8 0.90 35.98 32.338 2,3,4-Trimethylpentane 00565-75-3 0.95 34.51 32.747 n-Pentane 00109-66-0 1.21 34.15 41.485 2-Methyl-2-butene 00513-35-9 14.20 33.96 481.993 Methylcyclopentane 00096-37-7 2.05 33.50 68.663 Benzene 00071-43-2 0.69 32.27 22.407 Ethanol 00064-17-5 1.45 30.56 44.275 t-2-Pentene 00646-04-8 10.47 26.47 277.198 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 20.03 155.313 2,4-Dimethylpentane 00108-08-7 1.46 19.99 29.167 2-Methylhexane 00591-76-4 1.09 17.93 19.453 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 16.52 52.723 2,3-Dimethylpentane 00565-59-3 1.25 15.96 19.917 2,4-Dimethylhexane 00589-43-5 1.61 15.36 24.658 2,2,5-Trimethylhexane 03522-94-9 1.05 13.89 14.624 c-2-Pentene 00627-20-3 10.28 13.64 140.198 2-Methyl-1-butene 00563-46-2 6.38 12.87 82.116 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 11.31 18.150 t-2-Hexene 04050-45-7 8.55 10.72 91.658 3-Methyl-t-2-pentene 00616-12-6 11.66 9.78 114.064 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 8.94 104.661 n-Heptane 00142-82-5 0.97 8.88 8.578 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 8.85 46.887 3-Methyl-c-2-pentene 00922-62-3 12.52 8.64 108.144 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 8.04 8.777 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.97 42.775 2,3,5-Trimethylhexane 01069-53-0 1.12 7.52 8.424 1-Methylcyclopentene 00693-89-0 12.45 6.91 86.056 2-Methyl-2-pentene 00625-27-4 11.03 6.89 75.985 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 5.99 39.576 2,2-Dimethylbutane 00075-83-2 1.11 5.76 6.402 ortho-Xylene 00095-47-6 7.58 5.74 43.500 Cyclopentene 00142-29-0 6.69 5.74 38.349 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.33 39.403 Methylcyclohexane 00108-87-2 1.56 5.14 7.996 c-2-Butene 00590-18-1 14.26 4.32 61.588 Vehicle 208b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7556 Non Zero Mass Species Sorted By VOC

## E

- 60 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7556 Non Zero Mass Species Sorted By VOC

t-1,2-Dimethylcyclopentane 00822-50-4 2.65 4.26 11.303 Ethylbenzene 00100-41-4 2.96 4.04 11.966 2,2-DiMeHexane 00590-73-8 0.94 4.03 3.795 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.66 16.090 1,3,5-Trimethylbenzene 00108-67-8 11.75 3.51 41.294 c-1,3-Dimethylcyclopentane 02532-58-3 2.65 3.46 9.164 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.43 27.267 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.78 16.057 2,2-Dimethylpentane 00590-35-2 1.04 2.71 2.826 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.64 14.650 2-Methylheptane 00592-27-8 0.97 2.64 2.556 3-Methylheptane 00589-81-1 1.12 2.47 2.775 n-Propylbenzene 00103-65-1 1.96 2.32 4.556 n-Octane 00111-65-9 0.80 2.26 1.796 Ethylene 00074-85-1 8.88 2.22 19.715 Unknown #16 2.65 2.05 5.438 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 2.05 16.040 2,2,3-Trimethylbutane 00464-06-2 1.05 1.80 1.896 Unknown #5 2.65 1.75 4.627 3,5-Dimethylheptane 00926-82-9 1.42 1.58 2.252 3,3-Dimethylpentane 00562-49-2 1.12 1.50 1.677 Unknown #13 2.65 1.44 3.829 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 1.39 5.303 Indan 00496-11-7 3.23 1.14 3.694 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.01 3.894 1-Nonene 00124-11-8 2.49 1.00 2.500 c-2-Heptene 06443-92-1 7.08 0.95 6.717 1,3-Diethylbenzene 00141-93-5 7.08 0.90 6.400 1,3-Butadiene 00106-99-0 12.45 0.90 11.231 3,3-Dimethylhexane 00563-16-6 1.15 0.81 0.938 4-Methyloctane 02216-34-4 0.85 0.73 0.615 t-3-Heptene 14686-14-7 6.17 0.70 4.305 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.69 4.499 c-1,3-Dimethylcyclohexane 00638-04-0 2.65 0.66 1.760 2,4-Dimethylheptane 02213-23-2 1.26 0.66 0.839 Isopropylbenzene (Cumene) 00098-82-8 2.65 0.61 1.623 Unknown #8 2.65 0.59 1.575 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.54 5.671 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.65 0.54 1.433 t-2-Nonene 06434-78-2 2.65 0.50 1.329 Unknown #3 2.65 0.43 1.140 1-Methyl-2-Propylbenzene 01074-17-5 5.43 0.43 2.325 

### continued

## E

- 61 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7556 Non Zero Mass Species Sorted By VOC 

### continued

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.43 3.567 n-Nonane 00111-84-2 0.68 0.41 0.283 1-Heptene 00592-76-7 4.29 0.39 1.672 3-Methyloctane 02216-33-3 0.88 0.36 0.318 1,1-Dimethylcyclohexane 00590-66-9 1.12 0.32 0.352 2,2-Dimethyloctane 15869-87-1 0.76 0.30 0.230 1c-2t-3-TriMeCyPentane 15890-40-1 2.65 0.29 0.780 sec-Butylbenzene 00135-98-8 2.29 0.29 0.658 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.28 1.746 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.27 0.232 Isobutylbenzene 00538-93-2 2.65 0.25 0.651 t-1,4-Dimethylcyclohexane 02207-04-7 2.65 0.18 0.483

Total 1737.6 4606.5 2.651

No MIR available, use weighted average of 2.6511

## E

- 62 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 8.61 11.665 Toluene 00108-88-3 3.93 5.61 22.020 n-Butane 00106-97-8 1.08 5.20 5.598 Cyclohexane 00110-82-7 1.14 3.19 3.630 n-Hexane 00110-54-3 1.13 2.08 2.355 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.65 2.310 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.55 1.860 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.45 11.249 n-Pentane 00109-66-0 1.21 1.44 1.755 t-2-Pentene 00646-04-8 10.47 1.20 12.565 3-Methylpentane 00096-14-0 1.69 1.19 2.005 Benzene 00071-43-2 0.69 1.08 0.751 Indan 00496-11-7 3.23 0.87 2.828 c-2-Pentene 00627-20-3 10.28 0.84 8.640 2,3,4-Trimethylpentane 00565-75-3 0.95 0.81 0.767 2,3-Dimethylbutane 00079-29-8 0.90 0.77 0.691 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.68 3.661 3-Methyl-c-2-pentene 00922-62-3 12.52 0.66 8.258 Unknown #16 3.15 0.66 2.072 2-Methyl-2-butene 00513-35-9 14.20 0.65 9.182 Methylcyclopentane 00096-37-7 2.05 0.64 1.308 1-Butyne 00107-00-6 6.05 0.60 3.611 c-2-Butene 00590-18-1 14.26 0.51 7.330 2,3,5-Trimethylhexane 01069-53-0 1.12 0.50 0.561 2,4-Dimethylhexane 00589-43-5 1.61 0.47 0.754 Isopropylbenzene (Cumene) 00098-82-8 3.15 0.45 1.402 2,3-Dimethylpentane 00565-59-3 1.25 0.41 0.506 2-Methylhexane 00591-76-4 1.09 0.40 0.434 2,4-Dimethylpentane 00108-08-7 1.46 0.39 0.575 t-2-Hexene 04050-45-7 8.55 0.39 3.347 n-Octane 00111-65-9 0.80 0.38 0.302 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.34 1.819 c-1,3-Dimethylcyclopentane 02532-58-3 3.15 0.33 1.029 2-Methyl-1-butene 00563-46-2 6.38 0.33 2.081 Ethanol 00064-17-5 1.45 0.31 0.446 Ethylbenzene 00100-41-4 2.96 0.26 0.781 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.26 1.451 ortho-Xylene 00095-47-6 7.58 0.25 1.859 2,2,5-Trimethylhexane 03522-94-9 1.05 0.24 0.258 3-Methyl-t-2-pentene 00616-12-6 11.66 0.24 2.752 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.23 0.377 2,2-Dimethylbutane 00075-83-2 1.11 0.23 0.258 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.23 1.017 2-Methyl-2-pentene 00625-27-4 11.03 0.23 2.485 Vehicle 208b - Fuel 7 psi E0 - 86 ° F Static - Test 7568 Non Zero Mass Species Sorted By VOC

## E

- 63 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 7 psi E0 - 86 ° F Static - Test 7568 Non Zero Mass Species Sorted By VOC

n-Propylbenzene 00103-65-1 1.96 0.22 0.426 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.21 2.496 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.21 1.382 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.21 0.664 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.19 0.207 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.18 1.300 2-Methylheptane 00592-27-8 0.97 0.18 0.172 3-Methylheptane 00589-81-1 1.12 0.17 0.188 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.10 0.815 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.06 0.727 t-1,2-Dimethylcyclopentane 00822-50-4 3.15 0.06 0.182

Total 50.6 159.2 3.146

No MIR available, use weighted average of 3.1461 

### continued

## E

- 64 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 15.30 60.052 2-Methylbutane (Isopentane) 00078-78-4 1.35 13.66 18.514 Cyclohexane 00110-82-7 1.14 11.04 12.558 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.47 55.201 n-Butane 00106-97-8 1.08 6.68 7.192 n-Hexane 00110-54-3 1.13 4.95 5.616 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.44 5.321 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.72 5.196 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.56 27.572 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.77 14.863 3-Methylpentane 00096-14-0 1.69 2.62 4.427 Ethanol 00064-17-5 1.45 2.23 3.235 Benzene 00071-43-2 0.69 2.21 1.532 2,3,4-Trimethylpentane 00565-75-3 0.95 2.05 1.943 2,3-Dimethylbutane 00079-29-8 0.90 1.97 1.766 n-Pentane 00109-66-0 1.21 1.76 2.139 2-Methyl-2-butene 00513-35-9 14.20 1.68 23.915 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.58 18.554 Methylcyclopentane 00096-37-7 2.05 1.43 2.935 t-2-Pentene 00646-04-8 10.47 1.40 14.676 2-Methylhexane 00591-76-4 1.09 1.12 1.213 2,4-Dimethylpentane 00108-08-7 1.46 1.10 1.608 ortho-Xylene 00095-47-6 7.58 0.98 7.450 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.96 4.218 2,4-Dimethylhexane 00589-43-5 1.61 0.93 1.501 2,3-Dimethylpentane 00565-59-3 1.25 0.90 1.124 Methylcyclohexane 00108-87-2 1.56 0.88 1.366 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.88 10.477 2,2-DiMeHexane 00590-73-8 0.94 0.79 0.744 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.78 2.501 2,2,5-Trimethylhexane 03522-94-9 1.05 0.76 0.804 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.75 1.211 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.70 3.884 t-2-Hexene 04050-45-7 8.55 0.69 5.899 1-Butyne 00107-00-6 6.05 0.66 3.993 n-Heptane 00142-82-5 0.97 0.65 0.630 2-Methylheptane 00592-27-8 0.97 0.64 0.615 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.63 4.444 c-2-Pentene 00627-20-3 10.28 0.59 6.104 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.58 3.079 1-Methylcyclopentene 00693-89-0 12.45 0.57 7.067 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.57 0.618 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.57 3.736 Ethylbenzene 00100-41-4 2.96 0.55 1.617 Vehicle 208b - Fuel 7 psi E0 - 105 ° F Static - Test 7570 Non Zero Mass Species Sorted By VOC

## E

- 65 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 7 psi E0 - 105 ° F Static - Test 7570 Non Zero Mass Species Sorted By VOC

2-Methyl-1-butene 00563-46-2 6.38 0.53 3.377 Indan 00496-11-7 3.23 0.51 1.649 3-Methyl-c-2-pentene 00922-62-3 12.52 0.48 5.975 3-Methyl-t-2-pentene 00616-12-6 11.66 0.48 5.566 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.44 5.191 n-Undecane 01120-21-4 0.52 0.43 0.223 c-2-Butene 00590-18-1 14.26 0.39 5.566 2-Methyl-2-pentene 00625-27-4 11.03 0.37 4.064 n-Octane 00111-65-9 0.80 0.37 0.292 3-Methylheptane 00589-81-1 1.12 0.33 0.376 2,2-Dimethylbutane 00075-83-2 1.11 0.30 0.335 Unknown #22

. 3.45 0.26 0.899 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.24 1.815 2,2-Dimethylpentane 00590-35-2 1.04 0.23 0.238 t-1,2-Dimethylcyclopentane 00822-50-4 3.45 0.20 0.700 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.20 1.591 Cyclopentene 00142-29-0 6.69 0.18 1.181 2,3,5-Trimethylhexane 01069-53-0 1.12 0.17 0.193 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.12 0.919

Total 117.0 403.3 3.448

No MIR available, use weighted average of 3.4476 

### continued

## E

- 66 Species CAS No. MIR Composite VOC

mg Ozone mg n-Propylbenzene 00103-65-1 1.96 28.20 55.259 Toluene 00108-88-3 3.93 13.03 51.131 Cyclohexane 00110-82-7 1.14 10.16 11.555 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.81 41.960 1,3,5-Trimethylbenzene 00108-67-8 11.75 4.84 56.854 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.82 37.344 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.71 5.652 n-Butane 00106-97-8 1.08 3.05 3.281 Ethane 00074-84-0 0.26 2.47 0.650 ortho-Xylene 00095-47-6 7.58 2.26 17.147 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.03 8.899 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.79 9.903 Benzene 00071-43-2 0.69 1.69 1.176 2-Methylbutane (Isopentane) 00078-78-4 1.35 1.45 1.960 2,3-Dimethylbutane 00079-29-8 0.90 1.27 1.139 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.25 1.742 2,3,4-Trimethylpentane 00565-75-3 0.95 1.20 1.138 Methylcyclopentane 00096-37-7 2.05 1.09 2.237 2,4-Dimethylpentane 00108-08-7 1.46 1.07 1.563 3-Methylpentane 00096-14-0 1.69 1.01 1.707 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.00 11.947 2,2,5-Trimethylhexane 03522-94-9 1.05 0.96 1.008 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.76 7.932 2,4-Dimethylhexane 00589-43-5 1.61 0.73 1.174 2,2-Dimethylbutane 00075-83-2 1.11 0.66 0.738 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.63 1.006 Ethylbenzene 00100-41-4 2.96 0.62 1.835 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.47 3.720 2,3-Dimethylpentane 00565-59-3 1.25 0.41 0.508 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.40 2.113 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.33 0.357 Cyclopentene 00142-29-0 6.69 0.29 1.967 3-Methyl-t-2-pentene 00616-12-6 11.66 0.23 2.692 n-Heptane 00142-82-5 0.97 0.21 0.202 2-Methyl-2-butene 00513-35-9 14.20 0.17 2.457 Methylcyclohexane 00108-87-2 1.56 0.16 0.255 2-Methylhexane 00591-76-4 1.09 0.13 0.139 n-Undecane 01120-21-4 0.52 0.11 0.058 c-2-Pentene 00627-20-3 10.28 0.11 1.112 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.02 0.068

Total 103.6 353.6 3.413 Vehicle 208b - Fuel 7 psi E0 - Dynamic - Test 25782 Non Zero Mass Species Sorted By VOC 

### continued

## E

- 67 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 166.23 225.216 Cyclohexane 00110-82-7 1.14 133.72 152.087 Toluene 00108-88-3 3.93 125.86 494.015 n-Butane 00106-97-8 1.08 74.60 80.336 n-Hexane 00110-54-3 1.13 71.28 80.879 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 53.08 74.200 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 50.19 60.179 3-Methylpentane 00096-14-0 1.69 35.73 60.417 Benzene 00071-43-2 0.69 27.27 18.934 2-Methyl-2-butene 00513-35-9 14.20 27.25 386.746 n-Pentane 00109-66-0 1.21 26.97 32.769 2,3-Dimethylbutane 00079-29-8 0.90 25.95 23.320 Ethanol 00064-17-5 1.45 25.83 37.429 Methylcyclopentane 00096-37-7 2.05 24.26 49.718 t-2-Pentene 00646-04-8 10.47 22.05 230.932 2,3,4-Trimethylpentane 00565-75-3 0.95 19.36 18.369 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 14.93 115.821 2,4-Dimethylpentane 00108-08-7 1.46 13.76 20.080 2-Methylhexane 00591-76-4 1.09 12.45 13.509 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 11.33 36.151 c-2-Pentene 00627-20-3 10.28 10.95 112.570 2,3-Dimethylpentane 00565-59-3 1.25 10.41 13.000 2-Methyl-1-butene 00563-46-2 6.38 10.03 63.975 2,4-Dimethylhexane 00589-43-5 1.61 9.09 14.597 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 8.94 66.052 t-2-Hexene 04050-45-7 8.55 8.50 72.690 3-Methyl-t-2-pentene 00616-12-6 11.66 7.46 86.970 3-Methyl-c-2-pentene 00922-62-3 12.52 7.23 90.547 2,2,5-Trimethylhexane 03522-94-9 1.05 7.23 7.615 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 6.82 36.159 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 6.81 10.940 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 6.72 78.603 n-Heptane 00142-82-5 0.97 6.41 6.190 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.71 30.658 1-Methylcyclopentene 00693-89-0 12.45 5.48 68.258 2-Methyl-2-pentene 00625-27-4 11.03 5.30 58.508 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 4.99 5.451 2,2-DiMeHexane 00590-73-8 0.94 4.84 4.552 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.82 31.813 Cyclopentene 00142-29-0 6.69 4.58 30.623 ortho-Xylene 00095-47-6 7.58 4.14 31.338 2,2-Dimethylbutane 00075-83-2 1.11 3.56 3.954 c-2-Butene 00590-18-1 14.26 3.49 49.718 Methylcyclohexane 00108-87-2 1.56 3.31 5.155 Vehicle 208b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7575 Non Zero Mass Species Sorted By VOC

## E

- 68 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 208b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7575 Non Zero Mass Species Sorted By VOC

Ethylbenzene 00100-41-4 2.96 3.14 9.307 t-1,2-Dimethylcyclopentane 00822-50-4 2.91 2.98 8.649 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.65 11.642 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 2.49 19.786 c-1,3-Dimethylcyclopentane 02532-58-3 2.91 2.32 6.754 1,3,5-Trimethylbenzene 00108-67-8 11.75 2.19 25.686 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.09 12.090 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.00 11.087 3-Methylheptane 00589-81-1 1.12 1.94 2.181 n-Propylbenzene 00103-65-1 1.96 1.92 3.763 2,2-Dimethylpentane 00590-35-2 1.04 1.87 1.955 2-Methylheptane 00592-27-8 0.97 1.81 1.755 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.54 12.100 n-Octane 00111-65-9 0.80 1.36 1.085 2,2,3-Trimethylbutane 00464-06-2 1.05 1.31 1.377 2,3,5-Trimethylhexane 01069-53-0 1.12 1.20 1.346 3,3-Dimethylpentane 00562-49-2 1.12 1.12 1.258 Unknown #16 2.91 1.11 3.235 c-2-Heptene 06443-92-1 7.08 0.96 6.789 Unknown #5 2.91 0.93 2.692 1,3-Butadiene 00106-99-0 12.45 0.84 10.459 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.75 5.298 n-Decane 00124-18-5 0.59 0.74 0.438 1-Nonene 00124-11-8 2.49 0.67 1.671 c-1,3-Dimethylcyclohexane 00638-04-0 2.91 0.66 1.929 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.65 4.264 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.65 7.748 3,3-Dimethylhexane 00563-16-6 1.15 0.63 0.722 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.62 2.400 Indan 00496-11-7 3.23 0.60 1.932 t-3-Heptene 14686-14-7 6.17 0.56 3.482 4-Methyloctane 02216-34-4 0.85 0.51 0.432 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.47 3.954 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.43 2.684 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.42 4.405 t-2-Nonene 06434-78-2 2.91 0.39 1.140 n-Nonane 00111-84-2 0.68 0.38 0.260 1-Heptene 00592-76-7 4.29 0.36 1.540 Unknown #8 2.91 0.33 0.949 2,4-Dimethylheptane 02213-23-2 1.26 0.28 0.351 Isopropylbenzene (Cumene) 00098-82-8 2.91 0.22 0.649 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.18 0.151

Total 1167.2 3392.4 2.906

No MIR available, use weighted average of 2.9065 

### continued

## E

- 69 Test Fuel Test No. Bag THC mg GC as % of THC GC VOC

mg Ozone mg Reactivity Species Present 86 ° F E10 - 10 psi 7423 52.1 165.6 86.2 276.2 3.205 63 Static E10 - 7 psi 7466 54.4 130.9 71.2 262.9 3.692 78 E0 - 9 psi 7501 44.8 83.4 37.3 76.3 2.043 19 E0 - 7 psi 7524 38.8 120.5 46.8 161.0 3.441 51

105 ° F E10 - 10 psi 7424 160.9 117.8 189.4 593.2 3.131 65 Static E10 - 7 psi 7467 102.4 98.8 101.2 340.7 3.368 57 E0 - 9 psi 7504 55.8 86.1 48.1 186.9 3.886 52 E0 - 7 psi 7527 62.4 101.5 63.3 245.8 3.885 50

Dynamic E10 - 10 psi 25742 401.4 111.9 449.1 1629.8 3.629 74 E10 - 7 psi 25755 217.1 85.1 184.7 701.1 3.796 58 E0 - 9 psi 25761 140.9 102.9 145.0 658.3 4.541 45 E0 - 7 psi 25768 166.6 87.9 146.4 543.1 3.708 31

DHB E10 - 10 psi 7461 1434.5 93.8 1345.1 3821.9 2.841 110 Total E10 - 7 psi 7472 1055.7 93.7 989.6 2879.4 2.909 89 E0 - 9 psi 7508 802.6 59.6 478.6 1316.0 2.749 65 E0 - 7 psi 7533 821.9 94.5 776.5 2515.6 3.239 81 

## Vehicle 209b

## E

- 70 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 14.30 20.721 Toluene 00108-88-3 3.93 10.09 39.602 2-Methylbutane (Isopentane) 00078-78-4 1.35 8.82 11.956 n-Butane 00106-97-8 1.08 8.71 9.383 n-Propylbenzene 00103-65-1 1.96 3.96 7.758 n-Hexane 00110-54-3 1.13 3.17 3.600 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.00 16.083 Benzene 00071-43-2 0.69 2.16 1.498 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.76 2.462 2-Methyl-2-butene 00513-35-9 14.20 1.46 20.779 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.46 11.302 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.39 10.247 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.30 1.559 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.24 6.850 n-Pentane 00109-66-0 1.21 1.23 1.497 3-Methylpentane 00096-14-0 1.69 1.23 2.081 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.19 5.209 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.09 12.824 t-2-Pentene 00646-04-8 10.47 0.87 9.116 Unknown #16 3.20 0.86 2.759 Methylcyclohexane 00108-87-2 1.56 0.84 1.305 2-Methylpropane 00075-28-5 1.18 0.83 0.976 Methylcyclopentane 00096-37-7 2.05 0.82 1.673 2,3-Dimethylbutane 00079-29-8 0.90 0.75 0.670 Unknown #22

. 3.20 0.73 2.353 Cyclohexane 00110-82-7 1.14 0.63 0.721 ortho-Xylene 00095-47-6 7.58 0.61 4.652 3-Methyl-c-2-pentene 00922-62-3 12.52 0.58 7.318 c-2-Pentene 00627-20-3 10.28 0.58 5.985 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.57 3.789 3-Methyl-t-2-pentene 00616-12-6 11.66 0.57 6.623 t-2-Hexene 04050-45-7 8.55 0.56 4.809 n-Octane 00111-65-9 0.80 0.55 0.441 2-Methyl-1-butene 00563-46-2 6.38 0.53 3.389 n-Decane 00124-18-5 0.59 0.52 0.306 2,3,4-Trimethylpentane 00565-75-3 0.95 0.51 0.482 2-Methyl-2-pentene 00625-27-4 11.03 0.50 5.476 2,2-DiMeHexane 00590-73-8 0.94 0.48 0.456 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.44 5.270 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.43 5.040 c-2-Butene 00590-18-1 1.12 0.37 0.420 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.36 1.929 c-1,3-Dimethylcyclohexane 00638-04-0 3.20 0.36 1.145 t-2-Butene 00624-64-6 15.20 0.31 4.729 Vehicle 209b - Fuel 10 psi E10 - 86 ° F Static - Test 7423 Non Zero Mass Species Sorted By VOC

## E

- 71 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 10 psi E10 - 86 ° F Static - Test 7423 Non Zero Mass Species Sorted By VOC

Indan 00496-11-7 3.23 0.31 1.003 Ethylbenzene 00100-41-4 2.96 0.30 0.882 2,4-Dimethylpentane 00108-08-7 1.46 0.29 0.419 2,2-Dimethylpentane 00590-35-2 1.04 0.29 0.299 n-Heptane 00142-82-5 0.97 0.27 0.256 Cyclopentene 00142-29-0 6.69 0.25 1.689 t-1,2-Dimethylcyclopentane 00822-50-4 3.20 0.23 0.729 2-Methylheptane 00592-27-8 0.97 0.21 0.207 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.17 1.346 2,4-Dimethylhexane 00589-43-5 1.61 0.16 0.257 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.15 0.248 2,2,5-Trimethylhexane 03522-94-9 1.05 0.14 0.152 n-Nonane 00111-84-2 0.68 0.14 0.097 c-1,3-Dimethylcyclopentane 02532-58-3 3.20 0.13 0.407 2-Methylhexane 00591-76-4 1.09 0.12 0.128 2,2-Dimethylbutane 00075-83-2 1.11 0.10 0.116 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.08 0.584 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.05 0.050 2,3-Dimethylpentane 00565-59-3 1.25 0.05 0.056

Total 86.2 276.2 3.205

No MIR available, use weighted average of 3.2047 

### continued

## E

- 72 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 36.10 38.874 Ethanol 00064-17-5 1.45 27.85 40.352 Toluene 00108-88-3 3.93 21.91 85.991 2-Methylbutane (Isopentane) 00078-78-4 1.35 13.86 18.776 n-Hexane 00110-54-3 1.13 6.99 7.932 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.75 25.498 n-Propylbenzene 00103-65-1 1.96 4.23 8.287 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.93 5.492 Benzene 00071-43-2 0.69 3.89 2.702 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 3.37 24.854 2-Methyl-2-butene 00513-35-9 14.20 3.33 47.232 t-2-Pentene 00646-04-8 10.47 3.27 34.277 n-Pentane 00109-66-0 1.21 3.24 3.939 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.83 21.981 3-Methylpentane 00096-14-0 1.69 2.77 4.687 2-Methylpropane 00075-28-5 1.18 2.54 2.989 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.25 2.694 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.74 7.634 Methylcyclopentane 00096-37-7 2.05 1.70 3.486 n-Heptane 00142-82-5 0.97 1.66 1.605 c-2-Pentene 00627-20-3 10.28 1.64 16.908 Cyclohexane 00110-82-7 1.14 1.64 1.868 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.50 8.311 t-2-Butene 00624-64-6 15.20 1.50 22.773 2,3-Dimethylbutane 00079-29-8 0.90 1.44 1.290 2-Methyl-1-butene 00563-46-2 6.38 1.42 9.061 Propane 00074-98-6 0.46 1.33 0.608 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.31 15.407 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.18 3.751 2,3,4-Trimethylpentane 00565-75-3 0.95 1.17 1.106 c-2-Butene 00590-18-1 14.26 1.14 16.299 ortho-Xylene 00095-47-6 7.58 1.06 8.040 n-Decane 00124-18-5 0.59 1.04 0.614 1-Methylcyclopentene 00693-89-0 12.45 1.04 12.902 Methylcyclohexane 00108-87-2 1.56 1.02 1.588 2-Methylhexane 00591-76-4 1.09 1.02 1.104 Indan 00496-11-7 3.23 1.00 3.220 n-Octane 00111-65-9 0.80 0.98 0.782 Unknown #16 3.13 0.91 2.847 n-Nonane 00111-84-2 0.68 0.87 0.592 t-2-Hexene 04050-45-7 8.55 0.83 7.064 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.82 4.322 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.80 9.374 c-1,3-Dimethylcyclohexane 00638-04-0 3.13 0.80 2.506 Vehicle 209b - Fuel 10 psi E10 - 105 ° F Static - Test 7424 Non Zero Mass Species Sorted By VOC

## E

- 73 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 10 psi E10 - 105 ° F Static - Test 7424 Non Zero Mass Species Sorted By VOC

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.78 6.191 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.77 5.468 2,2-DiMeHexane 00590-73-8 0.94 0.67 0.632 2,4-Dimethylpentane 00108-08-7 1.46 0.65 0.945 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.64 4.227 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.60 7.132 3-Methyl-t-2-pentene 00616-12-6 11.66 0.59 6.900 2,4-Dimethylhexane 00589-43-5 1.61 0.58 0.932 2,3-Dimethylpentane 00565-59-3 1.25 0.54 0.679 3-Methylheptane 00589-81-1 1.12 0.54 0.609 Cyclopentene 00142-29-0 6.69 0.48 3.194 3-Methyl-c-2-pentene 00922-62-3 12.52 0.47 5.940 2,2,5-Trimethylhexane 03522-94-9 1.05 0.47 0.492 2-Methyl-2-pentene 00625-27-4 11.03 0.44 4.882 Ethylbenzene 00100-41-4 2.96 0.38 1.136 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.34 0.547 2,2-Dimethylbutane 00075-83-2 1.11 0.24 0.267 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.22 0.244 c-1,3-Dimethylcyclopentane 02532-58-3 3.13 0.20 0.618 t-1,2-Dimethylcyclopentane 00822-50-4 3.13 0.15 0.475 2-Methylheptane 00592-27-8 0.97 0.04 0.043

Total 189.4 593.2 3.131

No MIR available, use weighted average of 3.1310 

### continued

## E

- 74 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 44.55 174.871 n-Butane 00106-97-8 1.08 43.19 46.507 Ethanol 00064-17-5 1.45 37.14 53.809 Methane 00074-82-8 0.01 35.35 0.490 2-Methylbutane (Isopentane) 00078-78-4 1.35 31.49 42.661 n-Hexane 00110-54-3 1.13 15.57 17.672 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 11.73 62.985 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 9.83 72.625 t-2-Butene 00624-64-6 15.20 9.53 144.815 Benzene 00071-43-2 0.69 9.51 6.604 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 8.85 12.365 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.29 64.294 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 7.58 9.088 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 6.90 80.773 1,3,5-Trimethylbenzene 00108-67-8 11.75 6.65 78.216 3-Methylpentane 00096-14-0 1.69 6.35 10.743 Cyclohexane 00110-82-7 1.14 6.29 7.158 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.14 48.787 n-Pentane 00109-66-0 1.21 6.13 7.452 2,3-Dimethylbutane 00079-29-8 0.90 5.63 5.056 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.42 23.823 2,3,5-Trimethylhexane 01069-53-0 1.12 5.38 6.026 n-Decane 00124-18-5 0.59 5.30 3.133 Methylcyclopentane 00096-37-7 2.05 5.11 10.470 Methylcyclohexane 00108-87-2 1.56 4.95 7.701 t-2-Pentene 00646-04-8 10.47 4.90 51.356 2-Methyl-2-butene 00513-35-9 14.20 4.68 66.468 2-Methylhexane 00591-76-4 1.09 4.20 4.560 1,3-Butadiene 00106-99-0 12.45 4.02 50.073 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.00 12.776 Cyclopentene 00142-29-0 6.69 3.80 25.392 n-Heptane 00142-82-5 0.97 3.67 3.546 2-Methyl-1-butene 00563-46-2 6.38 3.40 21.696 2,3,4-Trimethylpentane 00565-75-3 0.95 3.34 3.167 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.28 17.358 n-Octane 00111-65-9 0.80 3.20 2.550 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.15 17.481 1,2,3-Trimethylbenzene 00526-73-8 11.94 3.06 36.483 3-Methyl-c-2-pentene 00922-62-3 12.52 2.84 35.612 c-2-Pentene 00627-20-3 10.28 2.72 27.932 t-2-Hexene 04050-45-7 8.55 2.65 22.663 Unknown #16 3.63 2.56 9.299 2,4-Dimethylhexane 00589-43-5 1.61 2.54 4.080 3-Methyl-t-2-pentene 00616-12-6 11.66 2.35 27.391 Vehicle 209b - Fuel 10 psi E10 - Dynamic - Test 25742 Non Zero Mass Species Sorted By VOC

## E

- 75 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 10 psi E10 - Dynamic - Test 25742 Non Zero Mass Species Sorted By VOC

ortho-Xylene 00095-47-6 7.58 2.21 16.710 2-Methyl-2-pentene 00625-27-4 11.03 2.20 24.253 2,3-Dimethylpentane 00565-59-3 1.25 2.16 2.691 c-2-Butene 00590-18-1 14.26 2.01 28.689 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.01 2.192 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.98 13.100 c-1,3-Dimethylcyclopentane 02532-58-3 3.63 1.85 6.726 n-Nonane 00111-84-2 0.68 1.80 1.229 1-Methylcyclopentene 00693-89-0 12.45 1.75 21.755 2,4-Dimethylpentane 00108-08-7 1.46 1.69 2.472 2-Methylpropane 00075-28-5 1.18 1.62 1.908 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 1.62 12.212 2-Methylheptane 00592-27-8 0.97 1.53 1.483 1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.51 10.702 Styrene 00100-42-5 1.66 1.50 2.493 3-Methylheptane 00589-81-1 1.12 1.49 1.674 3,3-Dimethylpentane 00562-49-2 1.12 1.47 1.649 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.42 2.282 t-1,2-Dimethylcyclopentane 00822-50-4 3.63 1.40 5.068 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.37 7.912 2,2-DiMeHexane 00590-73-8 0.94 1.18 1.115 2,2,5-Trimethylhexane 03522-94-9 1.05 1.15 1.209 Ethylbenzene 00100-41-4 2.96 1.14 3.382 2-Methyl-1,3-butadiene 00078-79-5 10.48 1.05 11.022 Unknown #22 3.63 0.86 3.108 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.56 2.178 Indan 00496-11-7 3.23 0.44 1.411 2,2-Dimethylpentane 00590-35-2 1.04 0.42 0.436 n-Propylbenzene 00103-65-1 1.96 0.26 0.510 2,2-Dimethylbutane 00075-83-2 1.11 0.20 0.226

Total 449.1 1629.8 3.629

No MIR available, use weighted average of 3.6290 

### continued

## E

- 76 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 218.98 317.298 n-Butane 00106-97-8 1.08 198.76 214.048 Toluene 00108-88-3 3.93 124.89 490.191 2-Methylbutane (Isopentane) 00078-78-4 1.35 122.86 166.463 n-Hexane 00110-54-3 1.13 69.89 79.304 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 39.64 55.408 2-Methyl-2-butene 00513-35-9 14.20 29.68 421.352 Benzene 00071-43-2 0.69 29.49 20.479 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 28.71 34.431 3-Methylpentane 00096-14-0 1.69 28.66 48.453 n-Pentane 00109-66-0 1.21 27.93 33.927 t-2-Pentene 00646-04-8 10.47 26.84 281.076 Methylcyclopentane 00096-37-7 2.05 20.34 41.693 Cyclohexane 00110-82-7 1.14 18.50 21.039 Methanol 00067-56-1 0.66 18.21 11.971 2,3-Dimethylbutane 00079-29-8 0.90 16.56 14.882 2-Methylpropane 00075-28-5 1.18 14.35 16.889 c-2-Pentene 00627-20-3 10.28 13.97 143.652 Methylcyclohexane 00108-87-2 1.56 13.00 20.214 2-Methyl-1-butene 00563-46-2 6.38 12.92 82.403 2,3,4-Trimethylpentane 00565-75-3 0.95 12.54 11.901 n-Heptane 00142-82-5 0.97 11.91 11.506 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 11.62 90.139 2-Methylhexane 00591-76-4 1.09 11.28 12.236 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 10.24 32.662 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 9.39 50.443 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 9.15 107.105 t-2-Hexene 04050-45-7 8.55 8.29 70.836 2,4-Dimethylpentane 00108-08-7 1.46 8.26 12.061 c-2-Butene 00590-18-1 14.26 7.59 108.280 n-Octane 00111-65-9 0.80 6.59 5.245 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 6.49 34.394 2,4-Dimethylhexane 00589-43-5 1.61 6.16 9.885 3-Methyl-t-2-pentene 00616-12-6 11.66 6.03 70.364 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.03 47.921 2,3-Dimethylpentane 00565-59-3 1.25 5.76 7.188 1-Methylcyclopentene 00693-89-0 12.45 5.51 68.669 Cyclopentene 00142-29-0 6.69 5.38 35.956 3-Methyl-c-2-pentene 00922-62-3 12.52 5.33 66.740 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.98 36.797 2-Methyl-2-pentene 00625-27-4 11.03 4.93 54.363 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.75 7.629 2,2,5-Trimethylhexane 03522-94-9 1.05 4.72 4.974 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.70 31.029 Vehicle 209b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7461 Non Zero Mass Species Sorted By VOC

## E

- 77 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7461 Non Zero Mass Species Sorted By VOC

1,3,5-Trimethylbenzene 00108-67-8 11.75 3.99 46.921 n-Decane 00124-18-5 0.59 3.97 2.348 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.89 17.096 ortho-Xylene 00095-47-6 7.58 3.68 27.884 2,2-Dimethylbutane 00075-83-2 1.11 3.67 4.073 2,2-DiMeHexane 00590-73-8 0.94 3.59 3.377 2,3,5-Trimethylhexane 01069-53-0 1.12 3.49 3.905 2-Methylheptane 00592-27-8 0.97 3.41 3.300 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.41 18.899 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.15 3.444 3-Methylheptane 00589-81-1 1.12 3.05 3.435 t-1,2-Dimethylcyclopentane 00822-50-4 2.84 2.79 7.916 c-1,3-Dimethylcyclohexane 00638-04-0 2.84 2.43 6.905 n-Nonane 00111-84-2 0.68 2.32 1.583 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.29 13.231 c-1,3-Dimethylcyclopentane 02532-58-3 2.84 2.20 6.263 Ethylbenzene 00100-41-4 2.96 2.01 5.961 n-Propylbenzene 00103-65-1 1.96 1.96 3.833 2,2-Dimethylpentane 00590-35-2 1.04 1.82 1.900 Unknown #16 2.84 1.63 4.620 3,3-Dimethylpentane 00562-49-2 1.12 1.62 1.816 Indan 00496-11-7 3.23 1.50 4.849 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.35 16.144 3,5-Dimethylheptane 00926-82-9 1.42 1.33 1.893 4-Methyloctane 02216-34-4 0.85 1.28 1.088 Isopropylbenzene (Cumene) 00098-82-8 2.84 1.28 3.625 2,2,3-Trimethylbutane 00464-06-2 1.05 1.26 1.327 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.21 9.487 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.11 4.280 t-1,4-Dimethylcyclohexane 02207-04-7 2.84 1.05 2.970 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 1.03 7.734 Unknown #14 2.84 0.97 2.769 Unknown #13 2.84 0.95 2.690 3-Methyloctane 02216-33-3 0.88 0.94 0.831 Unknown #5 2.84 0.91 2.588 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 0.91 1.077 c-2-Heptene 06443-92-1 7.08 0.90 6.354 3,3-Dimethylhexane 00563-16-6 1.15 0.88 1.016 1-Nonene 00124-11-8 2.49 0.85 2.112 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.74 6.232 1,1-Dimethylcyclohexane 00590-66-9 1.12 0.73 0.811 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.69 0.591 

### continued

## E

- 78 Unknown #8 2.84 0.68 1.945 2,2-Dimethyloctane 15869-87-1 0.76 0.67 0.510 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.84 0.67 1.914 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.66 4.687 t-3-Heptene 14686-14-7 6.17 0.64 3.925 4-Methyl-t-2-pentene 00674-76-0 8.04 0.60 4.852 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.60 6.270 Unknown #9 2.84 0.57 1.623 t-4-Octene 14850-23-8 4.69 0.51 2.401 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.45 2.955 Isobutylbenzene 00538-93-2 2.84 0.45 1.271 c- & t-4-Nonene 02198-23-4 4.42 0.43 1.910 2,4-Dimethylheptane 02213-23-2 1.26 0.42 0.533 n-Undecane 01120-21-4 0.52 0.41 0.213 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.41 1.555 1-Methyl-2-Propylbenzene 01074-17-5 5.43 0.40 2.161 1-Heptene 00592-76-7 4.29 0.39 1.672 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.34 2.562 t-2-Nonene 06434-78-2 2.84 0.34 0.960 1,3-Diethylbenzene 00141-93-5 7.08 0.30 2.111 sec-Butylbenzene 00135-98-8 2.29 0.28 0.642 1,4-Diethylbenzene 00105-05-5 4.39 0.28 1.210 Unknown #3 2.84 0.25 0.716 c-2-Octene 07642-04-8 2.84 0.24 0.674

Total 1345.1 3821.9 2.841

No MIR available, use weighted average of 2.8415 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7461 Non Zero Mass Species Sorted By VOC 

### continued

## E

- 79 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 8.03 11.636 Toluene 00108-88-3 3.93 7.65 30.015 n-Propylbenzene 00103-65-1 1.96 5.24 10.263 2-Methylbutane (Isopentane) 00078-78-4 1.35 3.82 5.174 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.37 18.069 n-Hexane 00110-54-3 1.13 3.23 3.663 n-Butane 00106-97-8 1.08 2.21 2.375 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.06 15.189 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.47 17.298 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.44 2.015 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.40 10.885 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.29 1.549 2,3,5-Trimethylhexane 01069-53-0 1.12 1.17 1.309 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.09 4.770 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.07 5.949 3-Methylpentane 00096-14-0 1.69 1.05 1.782 Cyclohexane 00110-82-7 1.14 0.95 1.080 Benzene 00071-43-2 0.69 0.95 0.659 Methylcyclopentane 00096-37-7 2.05 0.89 1.827 1,4-Diethylbenzene 00105-05-5 4.39 0.87 3.834 Unknown #16 3.69 0.87 3.204 c-2-Butene 00590-18-1 14.26 0.83 11.816 2-Methyl-2-butene 00513-35-9 14.20 0.81 11.538 2,3,4-Trimethylpentane 00565-75-3 0.95 0.77 0.730 3-Methylheptane 00589-81-1 1.12 0.72 0.809 n-Pentane 00109-66-0 1.21 0.69 0.844 Methylcyclohexane 00108-87-2 1.56 0.68 1.055 Unknown #5 3.69 0.67 2.468 2,3-Dimethylbutane 00079-29-8 0.90 0.64 0.574 Isobutylbenzene 00538-93-2 3.69 0.61 2.261 1-Methylcyclopentene 00693-89-0 12.45 0.58 7.268 n-Octane 00111-65-9 0.80 0.58 0.462 t-2-Pentene 00646-04-8 10.47 0.53 5.579 ortho-Xylene 00095-47-6 7.58 0.53 3.979 2-Methyl-1-butene 00563-46-2 6.38 0.52 3.328 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.50 3.736 n-Heptane 00142-82-5 0.97 0.47 0.458 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.46 2.665 c-1,3-Dimethylcyclohexane 00638-04-0 3.69 0.43 1.598 n-Decane 00124-18-5 0.59 0.42 0.247 3-Methyl-c-2-pentene 00922-62-3 12.52 0.40 5.010 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.39 4.680 t-2-Butene 00624-64-6 15.20 0.39 5.921 2-Methylheptane 00592-27-8 0.97 0.38 0.367 Vehicle 209b - Fuel 7 psi E10 - 86 ° F Static - Test 7466 Non Zero Mass Species Sorted By VOC

## E

- 80 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 7 psi E10 - 86 ° F Static - Test 7466 Non Zero Mass Species Sorted By VOC

3,3-Dimethylpentane 00562-49-2 1.12 0.37 0.414 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.35 0.378 2-Methylhexane 00591-76-4 1.09 0.34 0.372 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.34 2.404 Ethylcyclohexane 01678-91-7 1.35 0.32 0.428 t-2-Hexene 04050-45-7 8.55 0.31 2.691 3-Methyl-t-2-pentene 00616-12-6 11.66 0.30 3.484 2,4-Dimethylhexane 00589-43-5 1.61 0.30 0.477 1,3-Diethylbenzene 00141-93-5 7.08 0.30 2.104 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.29 0.938 Indan 00496-11-7 3.23 0.29 0.940 Isopropylbenzene (Cumene) 00098-82-8 3.69 0.29 1.069 2,4-Dimethylpentane 00108-08-7 1.46 0.29 0.421 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.29 1.904 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.28 3.285 n-Nonane 00111-84-2 0.68 0.26 0.179 2,2-DiMeHexane 00590-73-8 0.94 0.26 0.245 Ethylbenzene 00100-41-4 2.96 0.26 0.758 2,2-Dimethylbutane 00075-83-2 1.11 0.24 0.262 2,2,3-Trimethylbutane 00464-06-2 1.05 0.23 0.247 t-1,4-Dimethylcyclohexane 02207-04-7 3.69 0.23 0.850 3-Methyloctane 02216-33-3 0.88 0.22 0.197 c-2-Pentene 00627-20-3 10.28 0.22 2.259 2-Methyl-2-pentene 00625-27-4 11.03 0.22 2.414 2,3-Dimethylpentane 00565-59-3 1.25 0.20 0.252 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.17 0.273 Unknown #22

. 3.69 0.17 0.615 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.15 0.792 t-1,2-Dimethylcyclopentane 00822-50-4 3.69 0.14 0.520 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.13 0.488 2,2-Dimethylpentane 00590-35-2 1.04 0.12 0.125 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.10 0.808 c-1,3-Dimethylcyclopentane 02532-58-3 3.69 0.10 0.374 2,2,5-Trimethylhexane 03522-94-9 1.05 0.02 0.018

Total 71.2 262.9 3.692

No MIR available, use weighted average of 3.6921 

### continued

## E

- 81 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 20.03 29.021 Toluene 00108-88-3 3.93 14.57 57.186 n-Propylbenzene 00103-65-1 1.96 5.69 11.143 n-Hexane 00110-54-3 1.13 5.12 5.811 2-Methylbutane (Isopentane) 00078-78-4 1.35 4.65 6.294 n-Butane 00106-97-8 1.08 3.45 3.712 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.38 18.131 Benzene 00071-43-2 0.69 2.96 2.053 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.62 19.375 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.50 3.491 2-Methyl-2-butene 00513-35-9 14.20 2.46 34.890 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.19 2.620 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.18 16.910 t-2-Pentene 00646-04-8 10.47 1.98 20.783 Methylcyclopentane 00096-37-7 2.05 1.86 3.814 3-Methylpentane 00096-14-0 1.69 1.83 3.095 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 1.48 5.654 Cyclohexane 00110-82-7 1.14 1.46 1.658 n-Pentane 00109-66-0 1.21 1.46 1.768 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.27 7.026 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.16 5.109 2,3,5-Trimethylhexane 01069-53-0 1.12 1.16 1.298 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.03 12.087 Methylcyclohexane 00108-87-2 1.56 1.01 1.564 2,3-Dimethylbutane 00079-29-8 0.90 0.95 0.851 c-2-Pentene 00627-20-3 10.28 0.93 9.572 ortho-Xylene 00095-47-6 7.58 0.83 6.264 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.82 5.781 2-Methyl-1-butene 00563-46-2 6.38 0.75 4.785 2,3,4-Trimethylpentane 00565-75-3 0.95 0.71 0.672 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.69 2.189 2-Methylhexane 00591-76-4 1.09 0.64 0.699 2,4-Dimethylpentane 00108-08-7 1.46 0.53 0.770 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.52 2.739 2,2-DiMeHexane 00590-73-8 0.94 0.50 0.470 t-2-Hexene 04050-45-7 8.55 0.49 4.198 n-Heptane 00142-82-5 0.97 0.46 0.448 n-Octane 00111-65-9 0.80 0.46 0.366 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.44 5.164 Indan 00496-11-7 3.23 0.41 1.338 3-Methyl-t-2-pentene 00616-12-6 11.66 0.41 4.761 c-2-Butene 00590-18-1 14.26 0.33 4.700 Cyclopentene 00142-29-0 6.69 0.33 2.177 2,3-Dimethylpentane 00565-59-3 1.25 0.32 0.395 Vehicle 209b - Fuel 7 psi E10 - 105 ° F Static - Test 7467 Non Zero Mass Species Sorted By VOC

## E

- 82 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 7 psi E10 - 105 ° F Static - Test 7467 Non Zero Mass Species Sorted By VOC

2,4-Dimethylhexane 00589-43-5 1.61 0.30 0.479 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.24 0.266 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.23 0.363 2-Methyl-2-pentene 00625-27-4 11.03 0.22 2.452 n-Nonane 00111-84-2 0.68 0.22 0.151 t-1,2-Dimethylcyclopentane 00822-50-4 3.37 0.21 0.715 2-Methylheptane 00592-27-8 0.97 0.21 0.199 c-1,3-Dimethylcyclopentane 02532-58-3 3.37 0.19 0.644 Ethylbenzene 00100-41-4 2.96 0.15 0.459 t-2-Butene 00624-64-6 15.20 0.12 1.777 2,2-Dimethylbutane 00075-83-2 1.11 0.06 0.067 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.04 0.273 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.01 0.044

Total 101.2 340.7 3.368

No MIR available, use weighted average of 3.3679 

### continued

## E

- 83 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 35.12 50.894 n-Propylbenzene 00103-65-1 1.96 30.30 59.383 Toluene 00108-88-3 3.93 23.82 93.488 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 9.43 50.651 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.30 39.116 Benzene 00071-43-2 0.69 4.86 3.375 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.07 31.564 1,3-Butadiene 00106-99-0 12.45 3.50 43.606 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 3.46 13.217 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.41 27.114 n-Hexane 00110-54-3 1.13 3.36 3.814 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.31 3.963 2-Methyl-2-butene 00513-35-9 14.20 2.45 34.840 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 2.39 27.945 2,3,5-Trimethylhexane 01069-53-0 1.12 2.38 2.664 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.29 3.202 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.20 12.185 t-2-Pentene 00646-04-8 10.47 2.13 22.323 1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.07 14.643 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.03 8.934 Methylcyclohexane 00108-87-2 1.56 1.86 2.895 3-Methyl-c-2-pentene 00922-62-3 12.52 1.76 21.996 n-Nonane 00111-84-2 0.68 1.59 1.085 n-Decane 00124-18-5 0.59 1.56 0.923 ortho-Xylene 00095-47-6 7.58 1.54 11.700 Indan 00496-11-7 3.23 1.49 4.814 2-Methyl-1,3-butadiene 00078-79-5 10.48 1.48 15.567 3-Methylpentane 00096-14-0 1.69 1.31 2.208 2,3,4-Trimethylpentane 00565-75-3 0.95 1.29 1.224 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.26 8.292 2-Methyl-1-butene 00563-46-2 6.38 1.25 7.965 2-Methyl-2-pentene 00625-27-4 11.03 1.21 13.386 2,4-Dimethylpentane 00108-08-7 1.46 1.20 1.745 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.18 6.842 2,2-Dimethylpentane 00590-35-2 1.04 1.15 1.203 3-Methylheptane 00589-81-1 1.12 1.14 1.278 t-1,2-Dimethylcyclopentane 00822-50-4 3.80 1.06 4.037 3-Methyl-t-2-pentene 00616-12-6 11.66 1.03 11.951 2-Methylhexane 00591-76-4 1.09 1.02 1.112 2,2-DiMeHexane 00590-73-8 0.94 0.98 0.921 Methylcyclopentane 00096-37-7 2.05 0.94 1.930 Unknown #22 3.80 0.88 3.354 2,3-Dimethylbutane 00079-29-8 0.90 0.84 0.750 Vehicle 209b - Fuel 7 psi E10 - Dynamic - Test 25755 Non Zero Mass Species Sorted By VOC

## E

- 84 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 7 psi E10 - Dynamic - Test 25755 Non Zero Mass Species Sorted By VOC

2,4-Dimethylhexane 00589-43-5 1.61 0.77 1.237 t-2-Hexene 04050-45-7 8.55 0.73 6.259 Cyclopentene 00142-29-0 6.69 0.67 4.475 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.66 2.112 c-2-Pentene 00627-20-3 10.28 0.65 6.641 n-Pentane 00109-66-0 1.21 0.64 0.780 Cyclohexane 00110-82-7 1.14 0.61 0.690 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.55 0.597 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.54 0.869 2,2-Dimethylbutane 00075-83-2 1.11 0.48 0.539 c-1,3-Dimethylcyclopentane 02532-58-3 3.80 0.46 1.747 2,3-Dimethylpentane 00565-59-3 1.25 0.34 0.426 n-Heptane 00142-82-5 0.97 0.29 0.282 n-Octane 00111-65-9 0.80 0.26 0.209 2,2,5-Trimethylhexane 03522-94-9 1.05 0.11 0.115

Total 184.7 701.1 3.796

No MIR available, use weighted average of 3.7962 

### continued

## E

- 85 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 221.56 321.030 Toluene 00108-88-3 3.93 99.93 392.229 2-Methylbutane (Isopentane) 00078-78-4 1.35 90.34 122.396 n-Hexane 00110-54-3 1.13 68.20 77.380 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 36.80 51.441 n-Butane 00106-97-8 1.08 29.36 31.623 3-Methylpentane 00096-14-0 1.69 26.53 44.862 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 25.38 30.437 Benzene 00071-43-2 0.69 25.06 17.398 2-Methyl-2-butene 00513-35-9 14.20 24.20 343.459 n-Pentane 00109-66-0 1.21 22.72 27.605 t-2-Pentene 00646-04-8 10.47 21.34 223.528 Methylcyclopentane 00096-37-7 2.05 19.37 39.708 Cyclohexane 00110-82-7 1.14 18.08 20.563 2,3-Dimethylbutane 00079-29-8 0.90 14.93 13.421 Methanol 00067-56-1 0.66 14.65 9.632 Methylcyclohexane 00108-87-2 1.56 11.07 17.215 c-2-Pentene 00627-20-3 10.28 10.84 111.430 2-Methyl-1-butene 00563-46-2 6.38 10.46 66.727 2-Methylhexane 00591-76-4 1.09 10.09 10.946 n-Heptane 00142-82-5 0.97 9.85 9.514 2,3,4-Trimethylpentane 00565-75-3 0.95 9.77 9.270 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 9.31 29.715 2,4-Dimethylpentane 00108-08-7 1.46 7.99 11.665 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 7.48 58.032 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 7.27 85.077 t-2-Hexene 04050-45-7 8.55 7.16 61.179 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.50 29.524 2,3-Dimethylpentane 00565-59-3 1.25 5.29 6.599 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 5.24 27.745 2,4-Dimethylhexane 00589-43-5 1.61 5.21 8.367 3-Methyl-t-2-pentene 00616-12-6 11.66 5.12 59.714 2,2-DiMeHexane 00590-73-8 0.94 5.11 4.812 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.95 39.318 n-Octane 00111-65-9 0.80 4.63 3.688 1-Methylcyclopentene 00693-89-0 12.45 4.63 57.639 2-Methyl-2-pentene 00625-27-4 11.03 4.36 48.134 Cyclopentene 00142-29-0 6.69 4.36 29.130 c-2-Butene 00590-18-1 14.26 4.23 60.377 3-Methyl-c-2-pentene 00922-62-3 12.52 4.09 51.143 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.08 6.552 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 3.86 25.506 2-Methylpropane 00075-28-5 1.18 3.80 4.467 2,2,5-Trimethylhexane 03522-94-9 1.05 3.51 3.694 Vehicle 209b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7472 Non Zero Mass Species Sorted By VOC

## E

- 86 Propane 00074-98-6 0.46 2.77 1.268 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.50 10.963 2-Methylheptane 00592-27-8 0.97 2.42 2.343 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.37 2.585 ortho-Xylene 00095-47-6 7.58 2.36 17.866 c-1,3-Dimethylcyclohexane 00638-04-0 2.91 2.35 6.845 t-1,2-Dimethylcyclopentane 00822-50-4 2.91 2.07 6.012 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.06 11.914 1,3,5-Trimethylbenzene 00108-67-8 11.75 2.00 23.561 2,2-Dimethylpentane 00590-35-2 1.04 1.99 2.072 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.98 10.977 c-1,3-Dimethylcyclopentane 02532-58-3 2.91 1.87 5.449 Ethylcyclohexane 01678-91-7 1.35 1.82 2.450 3-Methylheptane 00589-81-1 1.12 1.62 1.826 n-Nonane 00111-84-2 0.68 1.47 1.001 3,3-Dimethylpentane 00562-49-2 1.12 1.45 1.625 n-Propylbenzene 00103-65-1 1.96 1.36 2.667 2,2,3-Trimethylbutane 00464-06-2 1.05 1.27 1.339 Unknown #16 2.91 1.22 3.559 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.20 9.418 2,3,5-Trimethylhexane 01069-53-0 1.12 1.12 1.253 Isopropylbenzene (Cumene) 00098-82-8 2.91 1.11 3.242 2,2-Dimethylbutane 00075-83-2 1.11 0.89 0.986 t-1,4-Dimethylcyclohexane 02207-04-7 2.91 0.79 2.297 4-Methyloctane 02216-34-4 0.85 0.72 0.613 4-Methyl-t-2-pentene 00674-76-0 8.04 0.72 5.804 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.72 2.767 Unknown #5 2.91 0.71 2.079 Indan 00496-11-7 3.23 0.70 2.257 n-Decane 00124-18-5 0.59 0.66 0.391 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.65 4.630 c-2-Heptene 06443-92-1 7.08 0.54 3.800 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.50 6.000 Unknown #8 2.91 0.48 1.407 2,4-Dimethylheptane 02213-23-2 1.26 0.47 0.600 1-Nonene 00124-11-8 2.49 0.41 1.018 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.41 4.277 3-Methyloctane 02216-33-3 0.88 0.39 0.347 t-3-Heptene 14686-14-7 6.17 0.37 2.272 1,4-Diethylbenzene 00105-05-5 4.39 0.35 1.515 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.91 0.34 0.985 3,3-Dimethylhexane 00563-16-6 1.15 0.32 0.372 1,1-Dimethylcyclohexane 00590-66-9 1.12 0.19 0.216 Unknown #22 2.91 0.11 0.307 Ethylbenzene 00100-41-4 2.96 0.10 0.294

Total 989.6 2879.4 2.909

No MIR available, use weighted average of 2.9095 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7472 Non Zero Mass Species Sorted By VOC 

### continued

## E

- 87 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 11.10 15.044 Toluene 00108-88-3 3.93 7.07 27.752 n-Butane 00106-97-8 1.08 5.84 6.286 n-Hexane 00110-54-3 1.13 3.60 4.079 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.11 2.944 3-Methylpentane 00096-14-0 1.69 1.45 2.453 n-Pentane 00109-66-0 1.21 1.41 1.708 Methylcyclopentane 00096-37-7 2.05 0.93 1.897 Benzene 00071-43-2 0.69 0.93 0.643 n-Heptane 00142-82-5 0.97 0.78 0.755 2-Methyl-1-butene 00563-46-2 6.38 0.47 3.021 2-Methylhexane 00591-76-4 1.09 0.35 0.381 2,3-Dimethylpentane 00565-59-3 1.25 0.32 0.404 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.32 3.748 2,4-Dimethylpentane 00108-08-7 1.46 0.25 0.370 t-2-Pentene 00646-04-8 10.47 0.16 1.711 2-Methyl-2-butene 00513-35-9 14.20 0.14 2.009 c-2-Pentene 00627-20-3 10.28 0.07 0.728 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.05 0.383

Total 37.3 76.3 2.043 Vehicle 209b - Fuel 9 psi E0 - 86 ° F Static - Test 7501 Non Zero Mass Species Sorted By VOC

## E

- 88 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 7.46 29.293 Ethanol 00064-17-5 1.45 3.73 5.410 n-Butane 00106-97-8 1.08 3.03 3.268 2-Methylbutane (Isopentane) 00078-78-4 1.35 2.65 3.585 Cyclohexane 00110-82-7 1.14 2.64 3.007 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.25 16.583 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.78 13.818 n-Hexane 00110-54-3 1.13 1.71 1.944 Benzene 00071-43-2 0.69 1.51 1.046 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.50 8.037 2,4-Dimethylhexane 00589-43-5 1.61 1.11 1.780 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.04 1.244 2-Methylhexane 00591-76-4 1.09 1.01 1.097 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.99 1.388 2-Methyl-2-butene 00513-35-9 14.20 0.89 12.599 3-Methyl-c-2-pentene 00922-62-3 12.52 0.88 11.052 t-2-Butene 00624-64-6 15.20 0.86 13.078 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.84 3.671 3-Methylpentane 00096-14-0 1.69 0.78 1.324 2,2,5-Trimethylhexane 03522-94-9 1.05 0.66 0.699 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.64 7.502 Methylcyclopentane 00096-37-7 2.05 0.50 1.021 2,3-Dimethylpentane 00565-59-3 1.25 0.48 0.602 2,2-DiMeHexane 00590-73-8 0.94 0.48 0.452 3,3-Dimethylpentane 00562-49-2 1.12 0.48 0.533 n-Heptane 00142-82-5 0.97 0.46 0.445 n-Pentane 00109-66-0 1.21 0.45 0.541 2,3,4-Trimethylpentane 00565-75-3 0.95 0.44 0.417 n-Undecane 01120-21-4 0.52 0.42 0.218 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.42 2.747 c-2-Butene 00590-18-1 14.26 0.40 5.721 Methylcyclohexane 00108-87-2 1.56 0.40 0.617 t-2-Pentene 00646-04-8 10.47 0.40 4.150 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.38 2.122 Ethylbenzene 00100-41-4 2.96 0.37 1.109 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.35 1.120 ortho-Xylene 00095-47-6 7.58 0.33 2.480 2,4-Dimethylpentane 00108-08-7 1.46 0.32 0.466 2,3-Dimethylbutane 00079-29-8 0.90 0.32 0.283 Cyclopentene 00142-29-0 6.69 0.31 2.093 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.31 0.500 2-Methyl-2-pentene 00625-27-4 11.03 0.30 3.341 3-Methyl-t-2-pentene 00616-12-6 11.66 0.30 3.471 n-Propylbenzene 00103-65-1 1.96 0.24 0.465 Vehicle 209b - Fuel 9 psi E0 - 105 ° F Static - Test 7504 Non Zero Mass Species Sorted By VOC

## E

- 89 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 9 psi E0 - 105 ° F Static - Test 7504 Non Zero Mass Species Sorted By VOC

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.23 2.771 t-2-Hexene 04050-45-7 8.55 0.22 1.843 2-Methyl-1-butene 00563-46-2 6.38 0.19 1.213 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.17 1.239 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.16 0.870 c-2-Pentene 00627-20-3 10.28 0.12 1.195 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.11 1.312 2,3,5-Trimethylhexane 01069-53-0 1.12 0.07 0.084

Total 48.1 186.9 3.886 

### continued

## E

- 90 Species CAS No. MIR Composite VOC

mg Ozone mg 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 21.51 158.891 Toluene 00108-88-3 3.93 13.47 52.857 Ethanol 00064-17-5 1.45 9.01 13.058 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 8.09 43.456 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.35 49.266 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 5.79 6.939 Cyclohexane 00110-82-7 1.14 5.44 6.189 n-Pentane 00109-66-0 1.21 4.53 5.504 n-Hexane 00110-54-3 1.13 4.30 4.884 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 4.19 18.426 n-Butane 00106-97-8 1.08 4.19 4.516 Unknown #22 4.54 4.16 18.872 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 4.13 5.769 1,3,5-Trimethylbenzene 00108-67-8 11.75 3.52 41.408 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.15 24.983 3-Methylpentane 00096-14-0 1.69 3.03 5.116 Benzene 00071-43-2 0.69 2.79 1.939 2,3,4-Trimethylpentane 00565-75-3 0.95 2.57 2.441 2-Methyl-2-butene 00513-35-9 14.20 2.10 29.813 Methylcyclopentane 00096-37-7 2.05 1.95 4.006 1,3-Butadiene 00106-99-0 12.45 1.95 24.239 2,3-Dimethylbutane 00079-29-8 0.90 1.84 1.650 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.83 10.148 ortho-Xylene 00095-47-6 7.58 1.80 13.626 n-Heptane 00142-82-5 0.97 1.78 1.716 2,4-Dimethylpentane 00108-08-7 1.46 1.64 2.395 Ethylbenzene 00100-41-4 2.96 1.62 4.793 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.60 5.116 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.41 16.855 2-Methylbutane (Isopentane) 00078-78-4 1.35 1.37 1.863 2,3-Dimethylpentane 00565-59-3 1.25 1.30 1.623 t-2-Pentene 00646-04-8 10.47 1.27 13.332 2-Methylhexane 00591-76-4 1.09 1.16 1.260 n-Propylbenzene 00103-65-1 1.96 1.14 2.240 c-2-Pentene 00627-20-3 10.28 1.08 11.124 2,2,5-Trimethylhexane 03522-94-9 1.05 1.06 1.114 2,4-Dimethylhexane 00589-43-5 1.61 1.03 1.660 2-Methyl-1-butene 00563-46-2 6.38 0.90 5.765 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.90 1.442 Methylcyclohexane 00108-87-2 1.56 0.80 1.241 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.79 5.573 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.74 7.778 t-2-Butene 00624-64-6 15.20 0.67 10.245 c-2-Butene 00590-18-1 14.26 0.57 8.162 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.43 5.028

Total 145.0 658.3 4.541

No MIR available, use weighted average of 4.5409 Vehicle 209b - Fuel 9 psi E0 - Dynamic - Test 25761 Non Zero Mass Species Sorted By VOC

## E

- 91 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 77.44 104.928 n-Butane 00106-97-8 1.08 62.23 67.019 Toluene 00108-88-3 3.93 43.02 168.863 Cyclohexane 00110-82-7 1.14 35.66 40.563 Ethanol 00064-17-5 1.45 33.17 48.065 n-Hexane 00110-54-3 1.13 24.59 27.898 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 18.99 26.550 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 14.89 17.849 3-Methylpentane 00096-14-0 1.69 12.42 21.008 n-Pentane 00109-66-0 1.21 10.84 13.168 2-Methyl-2-butene 00513-35-9 14.20 10.26 145.619 2,3-Dimethylbutane 00079-29-8 0.90 9.84 8.842 Benzene 00071-43-2 0.69 9.41 6.534 Methylcyclopentane 00096-37-7 2.05 8.50 17.425 t-2-Pentene 00646-04-8 10.47 8.46 88.597 2,3,4-Trimethylpentane 00565-75-3 0.95 6.48 6.148 c-2-Pentene 00627-20-3 10.28 4.71 48.428 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.61 35.780 2-Methyl-1-butene 00563-46-2 6.38 4.30 27.407 2,4-Dimethylpentane 00108-08-7 1.46 4.23 6.172 2-Methylhexane 00591-76-4 1.09 4.00 4.341 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 3.26 10.402 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.18 37.221 2,4-Dimethylhexane 00589-43-5 1.61 3.14 5.036 t-2-Hexene 04050-45-7 8.55 3.12 26.678 2,3-Dimethylpentane 00565-59-3 1.25 2.99 3.737 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.73 4.377 3-Methyl-t-2-pentene 00616-12-6 11.66 2.55 29.754 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 2.48 13.134 2,2,5-Trimethylhexane 03522-94-9 1.05 2.37 2.499 2,2-DiMeHexane 00590-73-8 0.94 2.31 2.170 Methylcyclohexane 00108-87-2 1.56 2.26 3.508 n-Heptane 00142-82-5 0.97 2.24 2.168 3-Methyl-c-2-pentene 00922-62-3 12.52 2.05 25.607 2-Methylpropane 00075-28-5 1.18 2.04 2.399 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.02 10.862 2-Methyl-2-pentene 00625-27-4 11.03 1.96 21.648 Cyclopentene 00142-29-0 6.69 1.82 12.175 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.81 1.978 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.77 13.069 ortho-Xylene 00095-47-6 7.58 1.74 13.179 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.73 11.412 1-Methylcyclopentene 00693-89-0 12.45 1.62 20.182 c-2-Butene 00590-18-1 14.26 1.59 22.730 Vehicle 209b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7508 Non Zero Mass Species Sorted By VOC

## E

- 92 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7508 Non Zero Mass Species Sorted By VOC

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.48 11.771 t-2-Butene 00624-64-6 15.20 1.35 20.554 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.34 7.452 Ethylbenzene 00100-41-4 2.96 1.19 3.520 2,2-Dimethylbutane 00075-83-2 1.11 1.18 1.307 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.10 12.896 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.00 4.406 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.96 5.555 Unknown #16 2.75 0.95 2.623 t-1,2-Dimethylcyclopentane 00822-50-4 2.75 0.89 2.455 n-Octane 00111-65-9 0.80 0.87 0.695 c-1,3-Dimethylcyclopentane 02532-58-3 2.75 0.83 2.281 2,2-Dimethylpentane 00590-35-2 1.04 0.79 0.822 3-Methylheptane 00589-81-1 1.12 0.73 0.822 n-Propylbenzene 00103-65-1 1.96 0.69 1.356 2-Methylheptane 00592-27-8 0.97 0.59 0.575 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.49 5.845 2,3,5-Trimethylhexane 01069-53-0 1.12 0.38 0.421 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.37 2.878 2,2,3-Trimethylbutane 00464-06-2 1.05 0.32 0.337 3,3-Dimethylpentane 00562-49-2 1.12 0.29 0.328

Total 478.6 1316.0 2.749

No MIR available, use weighted average of 2.7495 

### continued

## E

- 93 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 5.83 22.894 2-Methylbutane (Isopentane) 00078-78-4 1.35 5.54 7.499 n-Butane 00106-97-8 1.08 4.28 4.604 Cyclohexane 00110-82-7 1.14 2.83 3.223 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.23 16.498 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.62 1.937 n-Hexane 00110-54-3 1.13 1.54 1.742 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.49 7.996 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.33 1.862 Ethanol 00064-17-5 1.45 1.24 1.803 Benzene 00071-43-2 0.69 1.14 0.792 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.10 6.088 2-Methyl-2-butene 00513-35-9 14.20 1.06 15.026 3-Methylpentane 00096-14-0 1.69 0.90 1.526 2,3-Dimethylbutane 00079-29-8 0.90 0.90 0.806 2,3,4-Trimethylpentane 00565-75-3 0.95 0.82 0.779 2,4-Dimethylhexane 00589-43-5 1.61 0.79 1.263 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.73 0.793 n-Propylbenzene 00103-65-1 1.96 0.71 1.397 n-Pentane 00109-66-0 1.21 0.63 0.762 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.62 7.318 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.58 2.548 Methylcyclopentane 00096-37-7 2.05 0.56 1.146 Methylcyclohexane 00108-87-2 1.56 0.54 0.843 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.50 3.864 2,2-DiMeHexane 00590-73-8 0.94 0.47 0.438 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.46 2.450 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.46 5.380 2,4-Dimethylpentane 00108-08-7 1.46 0.44 0.641 3-Methyl-t-2-pentene 00616-12-6 11.66 0.42 4.890 c-2-Pentene 00627-20-3 10.28 0.40 4.160 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.40 1.278 c-2-Butene 00590-18-1 14.26 0.39 5.610 t-2-Hexene 04050-45-7 8.55 0.37 3.126 ortho-Xylene 00095-47-6 7.58 0.36 2.706 Ethylbenzene 00100-41-4 2.96 0.34 1.018 2,2-Dimethylbutane 00075-83-2 1.11 0.32 0.359 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.32 2.259 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.27 0.438 2-Methyl-1-butene 00563-46-2 6.38 0.27 1.732 2-Methyl-2-pentene 00625-27-4 11.03 0.25 2.788 2-Methylhexane 00591-76-4 1.09 0.24 0.262 t-2-Butene 00624-64-6 15.20 0.23 3.452 3-Methylheptane 00589-81-1 1.12 0.21 0.232 Vehicle 209b - Fuel 7 psi E0 - 86 ° F Static - Test 7524 Non Zero Mass Species Sorted By VOC

## E

- 94 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 7 psi E0 - 86 ° F Static - Test 7524 Non Zero Mass Species Sorted By VOC

Cyclopentene 00142-29-0 6.69 0.20 1.332 2,2,5-Trimethylhexane 03522-94-9 1.05 0.17 0.182 c- & t-4-Nonene 02198-23-4 4.42 0.08 0.371 n-Octane 00111-65-9 0.80 0.08 0.067 t-2-Pentene 00646-04-8 10.47 0.07 0.755 2,3-Dimethylpentane 00565-59-3 1.25 0.03 0.034 n-Heptane 00142-82-5 0.97 0.03 0.026

Total 46.8 161.0 3.441 

### continued

## E

- 95 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 9.38 36.819 2-Methylbutane (Isopentane) 00078-78-4 1.35 7.23 9.800 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.46 32.909 Cyclohexane 00110-82-7 1.14 3.72 4.228 n-Butane 00106-97-8 1.08 2.88 3.103 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.72 14.588 Ethanol 00064-17-5 1.45 2.57 3.727 n-Hexane 00110-54-3 1.13 2.29 2.599 Benzene 00071-43-2 0.69 2.05 1.425 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.01 15.600 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.64 2.288 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.53 1.839 3-Methylpentane 00096-14-0 1.69 1.24 2.103 2-Methyl-2-butene 00513-35-9 14.20 1.20 17.094 n-Pentane 00109-66-0 1.21 1.17 1.418 t-2-Pentene 00646-04-8 10.47 1.05 11.043 2,3,4-Trimethylpentane 00565-75-3 0.95 1.05 0.998 Indan 00496-11-7 3.23 1.03 3.338 2,3-Dimethylbutane 00079-29-8 0.90 0.87 0.779 ortho-Xylene 00095-47-6 7.58 0.82 6.213 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.79 9.284 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.73 4.050 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.68 2.978 Methylcyclopentane 00096-37-7 2.05 0.68 1.384 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.62 7.388 n-Propylbenzene 00103-65-1 1.96 0.61 1.188 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.57 3.026 c-2-Pentene 00627-20-3 10.28 0.55 5.668 3-Methyl-t-2-pentene 00616-12-6 11.66 0.55 6.417 2,2-DiMeHexane 00590-73-8 0.94 0.51 0.477 2,4-Dimethylhexane 00589-43-5 1.61 0.50 0.805 Methylcyclohexane 00108-87-2 1.56 0.45 0.703 2-Methyl-1-butene 00563-46-2 6.38 0.43 2.765 2,4-Dimethylpentane 00108-08-7 1.46 0.42 0.611 t-2-Hexene 04050-45-7 8.55 0.42 3.551 2-Methyl-2-pentene 00625-27-4 11.03 0.41 4.468 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.39 2.573 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.37 0.589 3-Methyl-c-2-pentene 00922-62-3 12.52 0.34 4.290 t-2-Butene 00624-64-6 15.20 0.33 4.960 Cyclopentene 00142-29-0 6.69 0.31 2.086 2,2,5-Trimethylhexane 03522-94-9 1.05 0.31 0.323 c-2-Butene 00590-18-1 1.12 0.28 0.313 n-Heptane 00142-82-5 0.97 0.23 0.220 Vehicle 209b - Fuel 7 psi E0 - 105 ° F Static - Test 7527 Non Zero Mass Species Sorted By VOC

## E

- 96 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 7 psi E0 - 105 ° F Static - Test 7527 Non Zero Mass Species Sorted By VOC

Ethylbenzene 00100-41-4 2.96 0.21 0.620 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.19 2.235 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.17 0.541 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.15 0.165 2,3-Dimethylpentane 00565-59-3 1.25 0.12 0.146 2-Methylhexane 00591-76-4 1.09 0.05 0.058

Total 63.3 245.8 3.885 

### continued

## E

- 97 Species CAS No. MIR Composite VOC

mg Ozone mg 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 23.40 172.811 Ethanol 00064-17-5 1.45 19.89 28.822 2-Methylbutane (Isopentane) 00078-78-4 1.35 15.24 20.645 n-Butane 00106-97-8 1.08 14.62 15.746 Toluene 00108-88-3 3.93 12.48 48.992 Cyclohexane 00110-82-7 1.14 7.61 8.651 1,3,5-Trimethylbenzene 00108-67-8 11.75 5.25 61.680 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.16 4.987 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.86 20.746 n-Hexane 00110-54-3 1.13 3.68 4.173 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.32 25.747 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.25 4.539 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.19 25.356 Ethylbenzene 00100-41-4 2.96 2.50 7.407 Benzene 00071-43-2 0.69 2.41 1.671 n-Propylbenzene 00103-65-1 1.96 2.12 4.155 Methylcyclopentane 00096-37-7 2.05 2.00 4.092 3-Methylpentane 00096-14-0 1.69 1.81 3.055 ortho-Xylene 00095-47-6 7.58 1.67 12.657 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.67 19.932 t-2-Pentene 00646-04-8 10.47 1.62 17.013 2,4-Dimethylpentane 00108-08-7 1.46 1.61 2.347 2,3,4-Trimethylpentane 00565-75-3 0.95 1.53 1.450 2-Methylhexane 00591-76-4 1.09 1.44 1.559 2,3-Dimethylpentane 00565-59-3 1.25 1.35 1.687 2,3-Dimethylbutane 00079-29-8 0.90 1.29 1.160 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.01 3.217 2-Methyl-2-butene 00513-35-9 14.20 0.84 11.990 2-Methyl-1-butene 00563-46-2 6.38 0.69 4.421 n-Pentane 00109-66-0 1.21 0.56 0.677 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.38 1.677

Total 146.4 543.1 3.708 Vehicle 209b - Fuel 7 psi E0 - Dynamic - Test 25768 Non Zero Mass Species Sorted By VOC

## E

- 98 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 128.86 174.588 n-Butane 00106-97-8 1.08 76.34 82.212 Toluene 00108-88-3 3.93 75.66 296.949 Cyclohexane 00110-82-7 1.14 64.10 72.906 t-3-Hexene & c-3-Hexene 13269-52-8+07642-09-3 7.43 38.95 289.368 Ethanol 00064-17-5 1.45 31.56 45.726 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 30.89 43.183 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 29.15 34.954 3-Methylpentane 00096-14-0 1.69 21.20 35.842 Benzene 00071-43-2 0.69 18.26 12.680 n-Pentane 00109-66-0 1.21 17.87 21.715 2-Methyl-2-butene 00513-35-9 14.20 16.88 239.595 Unknown #2 3.24 16.23 52.569 t-2-Pentene 00646-04-8 10.47 13.99 146.569 Methylcyclopentane 00096-37-7 2.05 13.65 27.980 2,3,4-Trimethylpentane 00565-75-3 0.95 12.88 12.220 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 9.85 76.418 2,4-Dimethylpentane 00108-08-7 1.46 7.65 11.165 c-2-Pentene 00627-20-3 10.28 7.14 73.417 2-Methyl-1-butene 00563-46-2 6.38 7.06 45.029 2-Methylhexane 00591-76-4 1.09 6.85 7.429 2,2,5-Trimethylhexane 03522-94-9 1.05 6.30 6.638 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 6.23 19.874 2,4-Dimethylhexane 00589-43-5 1.61 6.06 9.728 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.95 43.923 2,3-Dimethylpentane 00565-59-3 1.25 5.43 6.776 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 4.94 57.832 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.88 7.835 t-2-Hexene 04050-45-7 8.55 4.62 39.527 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.62 24.814 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 4.00 31.363 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.97 21.015 3-Methyl-t-2-pentene 00616-12-6 11.66 3.91 45.631 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.43 3.741 2,2-DiMeHexane 00590-73-8 0.94 3.40 3.204 3-Methyl-c-2-pentene 00922-62-3 12.52 3.10 38.849 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 2.93 18.449 Cyclopentene 00142-29-0 6.69 2.87 19.158 c-2-Butene 00590-18-1 14.26 2.81 40.040 1,3,5-Trimethylbenzene 00108-67-8 11.75 2.80 32.917 2-Methyl-2-pentene 00625-27-4 11.03 2.76 30.409 ortho-Xylene 00095-47-6 7.58 2.73 20.661 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 2.72 21.617 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.55 16.820 Vehicle 209b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7533 Non Zero Mass Species Sorted By VOC

## E

- 99 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 209b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7533 Non Zero Mass Species Sorted By VOC

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.38 10.442 2,2-Dimethylbutane 00075-83-2 1.11 2.28 2.535 t-2-Butene 00624-64-6 15.20 2.27 34.435 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.01 11.151 t-1,2-Dimethylcyclopentane 00822-50-4 3.24 1.74 5.650 c-1,3-Dimethylcyclopentane 02532-58-3 3.24 1.73 5.606 Ethylbenzene 00100-41-4 2.96 1.69 5.011 n-Propylbenzene 00103-65-1 1.96 1.61 3.161 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.58 6.100 3-Methylheptane 00589-81-1 1.12 1.57 1.763 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.52 8.803 Unknown #16 3.24 1.49 4.835 2,3,5-Trimethylhexane 01069-53-0 1.12 1.45 1.625 n-Octane 00111-65-9 0.80 1.09 0.866 2,2-Dimethylpentane 00590-35-2 1.04 1.07 1.114 t-1,4-Dimethylcyclohexane 02207-04-7 3.24 0.97 3.130 2,2,3-Trimethylbutane 00464-06-2 1.05 0.94 0.996 2-Methylpropane 00075-28-5 1.18 0.92 1.083 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.89 10.621 3,3-Dimethylpentane 00562-49-2 1.12 0.87 0.973 Unknown #5 3.24 0.81 2.609 Indan 00496-11-7 3.23 0.80 2.602 Unknown #22

. 3.24 0.77 2.503 1-Nonene 00124-11-8 2.49 0.62 1.553 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.61 4.293 t-3-Heptene 14686-14-7 6.17 0.58 3.555 2,4-Dimethylheptane 02213-23-2 1.26 0.55 0.697 4-Methyl-t-2-pentene 00674-76-0 8.04 0.55 4.398 4-Methyloctane 02216-34-4 0.85 0.53 0.452 n-Undecane 01120-21-4 0.52 0.50 0.259 n-Nonane 00111-84-2 0.68 0.47 0.318 c-2-Heptene 06443-92-1 7.08 0.38 2.694 Isopropylbenzene (Cumene) 00098-82-8 3.24 0.35 1.129 3,5-Dimethylheptane 00926-82-9 1.42 0.33 0.466 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.28 2.982 3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.17 1.707 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.16 0.137

Total 776.5 2515.6 3.239

No MIR available, use weighted average of 3.2395 

### continued

## E

- 100 Test Fuel Test No. Bag THC mg GC as % of THC GC VOC

mg Ozone mg Reactivity Species Present 86 ° F E10 - 10 psi 7449 51.6 89.7 46.3 143.2 3.096 49 Static E10 - 7 psi 7468 63.0 96.2 60.6 186.3 3.072 56 E0 - 9 psi 7523 46.2 121.3 56.1 208.1 3.712 53 E0 - 7 psi 7547 37.5 90.0 33.7 108.4 3.214 40

105 ° F E10 - 10 psi 7451 147.3 102.1 150.3 473.4 3.150 62 Static E10 - 7 psi 7471 117.5 92.6 108.8 346.6 3.186 69 E0 - 9 psi 7525 69.8 132.1 92.3 296.6 3.215 62 E0 - 7 psi 7549 74.0 104.9 77.6 270.6 3.486 48

Dynamic E10 - 10 psi 25749 198.4 85.9 170.5 569.7 3.342 52 E10 - 7 psi 25756 189.1 100.1 189.2 710.5 3.754 48 E0 - 9 psi 25767 178.0 74.9 133.2 328.8 2.468 41 E0 - 7 psi 25776 234.9 84.5 198.4 848.9 4.278 32

DHB E10 - 10 psi 7462 1386.1 93.7 1298.2 3812.8 2.937 95 Total E10 - 7 psi 7482 1192.5 87.0 1037.4 3101.2 2.989 86 E0 - 9 psi 7531 1143.4 88.3 1010.2 2351.6 2.328 32 E0 - 7 psi 7550 758.3 87.7 665.0 1927.4 2.898 86 

## Vehicle 210b

## E

- 101 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 6.57 9.515 n-Butane 00106-97-8 1.08 6.22 6.701 Toluene 00108-88-3 3.93 5.87 23.037 2-Methylbutane (Isopentane) 00078-78-4 1.35 5.65 7.657 n-Hexane 00110-54-3 1.13 2.63 2.979 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.51 2.107 n-Pentane 00109-66-0 1.21 1.17 1.426 t-2-Butene 00624-64-6 15.20 1.14 17.324 3-Methylpentane 00096-14-0 1.69 1.12 1.900 2-Methyl-2-butene 00513-35-9 14.20 1.11 15.724 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.01 1.206 Benzene 00071-43-2 0.69 0.94 0.651 t-2-Pentene 00646-04-8 10.47 0.84 8.831 2-Methylpropane 00075-28-5 1.18 0.75 0.879 2,3,5-Trimethylhexane 01069-53-0 1.12 0.63 0.701 2-Methyl-1-butene 00563-46-2 6.38 0.62 3.937 2,3-Dimethylbutane 00079-29-8 0.90 0.60 0.537 Methylcyclopentane 00096-37-7 2.05 0.55 1.120 c-2-Pentene 00627-20-3 10.28 0.46 4.759 Methylcyclohexane 00108-87-2 1.56 0.45 0.700 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.40 2.128 2-Methyl-2-pentene 00625-27-4 11.03 0.39 4.312 Cyclohexane 00110-82-7 1.14 0.37 0.426 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.37 1.186 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.35 2.715 2,2-Dimethylpentane 00590-35-2 1.04 0.34 0.353 3-Methyl-t-2-pentene 00616-12-6 11.66 0.33 3.871 2,4-Dimethylpentane 00108-08-7 1.46 0.33 0.479 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.31 2.434 3-Methylheptane 00589-81-1 1.12 0.29 0.327 2,3,4-Trimethylpentane 00565-75-3 0.95 0.27 0.260 t-2-Hexene 04050-45-7 8.55 0.26 2.197 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.24 1.592 n-Decane 00124-18-5 0.59 0.24 0.141 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.23 2.675 n-Octane 00111-65-9 0.80 0.20 0.160 2,2-DiMeHexane 00590-73-8 0.94 0.19 0.181 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.19 1.040 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.18 0.291 2-Methylhexane 00591-76-4 1.09 0.14 0.154 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.13 1.590 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.13 0.141 c-1,3-Dimethylcyclopentane 02532-58-3 3.10 0.12 0.365 Vehicle 210b - Fuel 10 psi E10 - 86 ° F Static - Test 7449 Non Zero Mass Species Sorted By VOC

## E

- 102 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 210b - Fuel 10 psi E10 - 86 ° F Static - Test 7449 Non Zero Mass Species Sorted By VOC

Cyclopentene 00142-29-0 6.69 0.11 0.716 2,2-Dimethylbutane 00075-83-2 1.11 0.10 0.107 c-2-Butene 00590-18-1 14.26 0.09 1.335 2,3-Dimethylpentane 00565-59-3 1.25 0.09 0.116 n-Heptane 00142-82-5 0.97 0.03 0.026 3-Methyl-c-2-pentene 00922-62-3 12.52 0.02 0.201

Total 46.3 143.2 3.096

No MIR available, use weighted average of 3.0957 

### continued

## E

- 103 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 26.13 37.866 n-Butane 00106-97-8 1.08 22.93 24.694 Toluene 00108-88-3 3.93 17.77 69.730 2-Methylbutane (Isopentane) 00078-78-4 1.35 10.04 13.603 n-Hexane 00110-54-3 1.13 6.79 7.701 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.67 34.461 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 4.35 6.083 Benzene 00071-43-2 0.69 3.49 2.427 2-Methyl-2-butene 00513-35-9 14.20 3.06 43.498 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.04 3.644 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.89 15.532 t-2-Pentene 00646-04-8 10.47 2.72 28.535 3-Methylpentane 00096-14-0 1.69 2.66 4.501 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.57 19.932 Methylcyclopentane 00096-37-7 2.05 2.02 4.136 Cyclohexane 00110-82-7 1.14 1.91 2.177 n-Pentane 00109-66-0 1.21 1.85 2.250 c-2-Pentene 00627-20-3 10.28 1.60 16.490 2,3-Dimethylbutane 00079-29-8 0.90 1.55 1.396 Methylcyclohexane 00108-87-2 1.56 1.47 2.291 n-Heptane 00142-82-5 0.97 1.36 1.318 2-Methylpropane 00075-28-5 1.18 1.30 1.525 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.22 14.397 2-Methyl-1-butene 00563-46-2 6.38 1.22 7.791 ortho-Xylene 00095-47-6 7.58 1.05 7.959 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.00 4.408 3-Methyl-c-2-pentene 00922-62-3 12.52 0.98 12.273 2-Methylhexane 00591-76-4 1.09 0.95 1.035 2,2-DiMeHexane 00590-73-8 0.94 0.92 0.870 2,3,4-Trimethylpentane 00565-75-3 0.95 0.91 0.865 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.86 2.756 2,4-Dimethylpentane 00108-08-7 1.46 0.80 1.168 Indan 00496-11-7 3.23 0.80 2.579 t-2-Hexene 04050-45-7 8.55 0.78 6.705 c-2-Butene 00590-18-1 14.26 0.70 9.989 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.69 8.092 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.66 4.330 Ethylbenzene 00100-41-4 2.96 0.64 1.908 2,2-Dimethylpentane 00590-35-2 1.04 0.63 0.659 3-Methyl-t-2-pentene 00616-12-6 11.66 0.63 7.340 t-1,2-Dimethylcyclopentane 00822-50-4 3.15 0.63 1.971 2-Methyl-2-pentene 00625-27-4 11.03 0.62 6.889 2,3,5-Trimethylhexane 01069-53-0 1.12 0.61 0.687 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.60 4.777 Vehicle 210b - Fuel 10 psi E10 - 105 ° F Static - Test 7451 Non Zero Mass Species Sorted By VOC

## E

- 10 4 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 210b - Fuel 10 psi E10 - 105 ° F Static - Test 7451 Non Zero Mass Species Sorted By VOC

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.58 3.232 n-Octane 00111-65-9 0.80 0.56 0.442 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.49 2.597 n-Decane 00124-18-5 0.59 0.48 0.286 2,2,5-Trimethylhexane 03522-94-9 1.05 0.44 0.459 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.43 5.152 2,4-Dimethylhexane 00589-43-5 1.61 0.39 0.627 2,3-Dimethylpentane 00565-59-3 1.25 0.39 0.487 n-Propylbenzene 00103-65-1 1.96 0.38 0.752 3-Methylheptane 00589-81-1 1.12 0.37 0.412 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.35 0.561 n-Nonane 00111-84-2 0.68 0.34 0.230 c-1,3-Dimethylcyclopentane 02532-58-3 3.15 0.28 0.878 t-2-Butene 00624-64-6 15.20 0.21 3.145 2,2-Dimethylbutane 00075-83-2 1.11 0.14 0.157 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.14 0.153 2-Methylheptane 00592-27-8 0.97 0.13 0.125 Cyclopentene 00142-29-0 6.69 0.07 0.483

Total 150.3 473.4 3.150

No MIR available, use weighted average of 3.1499 

### continued

## E

- 105 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 25.42 99.788 Ethanol 00064-17-5 1.45 25.37 36.763 Methane 00074-82-8 0.01 16.82 0.233 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.94 58.673 n-Butane 00106-97-8 1.08 7.24 7.798 n-Hexane 00110-54-3 1.13 6.62 7.507 Methanol 00067-56-1 0.66 5.82 3.824 Benzene 00071-43-2 0.69 4.96 3.443 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 4.67 54.675 2-Methylbutane (Isopentane) 00078-78-4 1.35 4.63 6.271 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.00 31.059 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.52 18.915 Methylcyclopentane 00096-37-7 2.05 3.01 6.175 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.90 3.474 2-Methyl-2-butene 00513-35-9 14.20 2.88 40.952 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.74 3.831 2-Methylpropane 00075-28-5 1.18 2.34 2.748 n-Pentane 00109-66-0 1.21 2.10 2.556 Cyclohexane 00110-82-7 1.14 2.09 2.379 1,3,5-Trimethylbenzene 00108-67-8 11.75 2.03 23.901 3-Methylpentane 00096-14-0 1.69 1.67 2.824 3-Methyl-t-2-pentene 00616-12-6 11.66 1.61 18.781 Methylcyclohexane 00108-87-2 1.56 1.60 2.481 3-Methyl-c-2-pentene 00922-62-3 12.52 1.59 19.901 2,3-Dimethylbutane 00079-29-8 0.90 1.58 1.424 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.58 5.042 2,2-DiMeHexane 00590-73-8 0.94 1.56 1.470 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.54 6.753 t-2-Pentene 00646-04-8 10.47 1.53 16.010 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.49 11.796 ortho-Xylene 00095-47-6 7.58 1.36 10.282 2,3,4-Trimethylpentane 00565-75-3 0.95 1.29 1.224 n-Decane 00124-18-5 0.59 1.28 0.759 2-Methyl-1-butene 00563-46-2 6.38 1.23 7.828 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.16 6.420 2-Methylhexane 00591-76-4 1.09 1.15 1.251 2-Methylheptane 00592-27-8 0.97 1.14 1.100 n-Propylbenzene 00103-65-1 1.96 1.11 2.183 2,4-Dimethylhexane 00589-43-5 1.61 1.10 1.771 2,2,5-Trimethylhexane 03522-94-9 1.05 1.03 1.080 2-Methyl-2-pentene 00625-27-4 11.03 0.90 9.924 n-Octane 00111-65-9 0.80 0.81 0.644 c-2-Pentene 00627-20-3 10.28 0.80 8.190 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.61 7.339 Vehicle 210b - Fuel 10 psi E10 - Dynamic - Test 25749 Non Zero Mass Species Sorted By VOC

## E

- 106 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 210b - Fuel 10 psi E10 - Dynamic - Test 25749 Non Zero Mass Species Sorted By VOC

2,3-Dimethylpentane 00565-59-3 1.25 0.60 0.746 Cyclopentene 00142-29-0 6.69 0.38 2.517 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.35 0.568 Indan 00496-11-7 3.23 0.35 1.128 2,4-Dimethylpentane 00108-08-7 1.46 0.34 0.499 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.25 1.330 n-Heptane 00142-82-5 0.97 0.23 0.222 t-2-Hexene 04050-45-7 8.55 0.15 1.252

Total 170.5 569.7 3.342 

### continued

## E

- 107 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 220.95 320.157 n-Butane 00106-97-8 1.08 150.10 161.650 2-Methylbutane (Isopentane) 00078-78-4 1.35 119.32 161.666 Toluene 00108-88-3 3.93 111.73 438.558 n-Hexane 00110-54-3 1.13 85.02 96.470 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 50.76 70.959 3-Methylpentane 00096-14-0 1.69 37.11 62.747 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 34.01 40.781 2-Methyl-2-butene 00513-35-9 14.20 32.37 459.437 n-Pentane 00109-66-0 1.21 28.89 35.099 Benzene 00071-43-2 0.69 27.84 19.331 t-2-Pentene 00646-04-8 10.47 27.08 283.609 Methylcyclopentane 00096-37-7 2.05 24.81 50.848 Cyclohexane 00110-82-7 1.14 22.52 25.614 2,3-Dimethylbutane 00079-29-8 0.90 20.90 18.782 c-2-Pentene 00627-20-3 10.28 14.07 144.667 2-Methylhexane 00591-76-4 1.09 14.03 15.225 Methylcyclohexane 00108-87-2 1.56 13.58 21.118 2-Methyl-1-butene 00563-46-2 6.38 13.52 86.241 n-Heptane 00142-82-5 0.97 12.84 12.404 2,3,4-Trimethylpentane 00565-75-3 0.95 12.58 11.936 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 12.19 38.911 2,4-Dimethylpentane 00108-08-7 1.46 10.87 15.859 t-2-Butene 00624-64-6 15.20 9.42 143.219 t-2-Hexene 04050-45-7 8.55 8.95 76.543 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 8.83 103.340 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.39 65.050 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 7.37 39.025 2,3-Dimethylpentane 00565-59-3 1.25 7.06 8.810 2-Methylpropane 00075-28-5 1.18 6.88 8.091 3-Methyl-t-2-pentene 00616-12-6 11.66 6.78 79.092 2,2-DiMeHexane 00590-73-8 0.94 6.44 6.064 c-2-Butene 00590-18-1 14.26 6.05 86.334 1-Methylcyclopentene 00693-89-0 12.45 5.82 72.486 3-Methyl-c-2-pentene 00922-62-3 12.52 5.81 72.707 2,4-Dimethylhexane 00589-43-5 1.61 5.74 9.222 2-Methyl-2-pentene 00625-27-4 11.03 5.70 62.866 n-Propylbenzene 00103-65-1 1.96 5.60 10.970 Cyclopentene 00142-29-0 6.69 5.49 36.724 n-Octane 00111-65-9 0.80 5.29 4.214 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 5.07 33.491 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.74 25.450 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.35 6.976 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.32 34.326 Vehicle 210b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7462 Non Zero Mass Species Sorted By VOC

## E

- 108 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 210b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7462 Non Zero Mass Species Sorted By VOC

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.19 30.982 2,2,5-Trimethylhexane 03522-94-9 1.05 3.41 3.587 2-Methylheptane 00592-27-8 0.97 3.08 2.978 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.91 3.177 2,2-Dimethylbutane 00075-83-2 1.11 2.88 3.197 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.87 16.584 t-1,2-Dimethylcyclopentane 00822-50-4 2.94 2.84 8.354 ortho-Xylene 00095-47-6 7.58 2.72 20.614 Propane 00074-98-6 0.46 2.57 1.173 3-Methylheptane 00589-81-1 1.12 2.39 2.686 c-1,3-Dimethylcyclopentane 02532-58-3 2.94 2.36 6.944 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.19 9.607 c-1,3-Dimethylcyclohexane 00638-04-0 2.94 2.01 5.913 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.90 22.357 2,2-Dimethylpentane 00590-35-2 1.04 1.87 1.948 3,3-Dimethylpentane 00562-49-2 1.12 1.64 1.838 Ethylbenzene 00100-41-4 2.96 1.56 4.622 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.51 8.373 2,2,3-Trimethylbutane 00464-06-2 1.05 1.48 1.557 2,3,5-Trimethylhexane 01069-53-0 1.12 1.48 1.654 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.33 10.441 3,5-Dimethylheptane 00926-82-9 1.42 1.27 1.813 n-Nonane 00111-84-2 0.68 1.24 0.846 n-Decane 00124-18-5 0.59 1.10 0.649 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.94 3.641 t-1,4-Dimethylcyclohexane 02207-04-7 2.94 0.93 2.719 4-Methyloctane 02216-34-4 0.85 0.84 0.710 n-Undecane 01120-21-4 0.52 0.78 0.407 Unknown #16 2.94 0.77 2.266 1,3-Butadiene 00106-99-0 12.45 0.75 9.317 3,3-Dimethylhexane 00563-16-6 1.15 0.75 0.859 Unknown #8 2.94 0.71 2.071 Unknown #5 2.94 0.70 2.055 c-2-Heptene 06443-92-1 7.08 0.64 4.497 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.54 3.522 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.53 5.604 t-3-Heptene 14686-14-7 6.17 0.51 3.162 2,4-Dimethylheptane 02213-23-2 1.26 0.51 0.643 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.49 3.501 3-Methyloctane 02216-33-3 0.88 0.40 0.358 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.40 3.349 4-Methyl-t-2-pentene 00674-76-0 8.04 0.39 3.119 

### continued

## E

- 109 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 210b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7462 Non Zero Mass Species Sorted By VOC

1,2,3-Trimethylbenzene 00526-73-8 11.94 0.36 4.244 Unknown #22

. 2.94 0.34 0.989 1-Heptene 00592-76-7 4.29 0.33 1.428 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.94 0.32 0.933 1-Nonene 00124-11-8 2.49 0.32 0.786 Isopropylbenzene (Cumene) 00098-82-8 2.94 0.28 0.835 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.28 1.744 Indan 00496-11-7 3.23 0.27 0.886 1,1-Dimethylcyclohexane 00590-66-9 1.12 0.17 0.186

Total 1298.2 3812.8 2.937

No MIR available, use weighted average of 2.9369 

### continued

## E

- 110 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 9.09 13.176 Toluene 00108-88-3 3.93 7.16 28.122 n-Propylbenzene 00103-65-1 1.96 6.76 13.254 n-Hexane 00110-54-3 1.13 3.69 4.183 2-Methylbutane (Isopentane) 00078-78-4 1.35 3.45 4.674 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.06 2.876 Benzene 00071-43-2 0.69 1.76 1.225 2-Methyl-2-butene 00513-35-9 14.20 1.70 24.198 3-Methylpentane 00096-14-0 1.69 1.66 2.811 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.63 1.952 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.40 7.514 t-2-Pentene 00646-04-8 10.47 0.99 10.400 Cyclohexane 00110-82-7 1.14 0.99 1.128 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.93 6.846 n-Butane 00106-97-8 1.08 0.91 0.984 c-2-Pentene 00627-20-3 10.28 0.90 9.302 2,3-Dimethylbutane 00079-29-8 0.90 0.90 0.809 n-Pentane 00109-66-0 1.21 0.86 1.048 Methylcyclopentane 00096-37-7 2.05 0.75 1.538 2-Methylheptane 00592-27-8 0.97 0.71 0.688 2,2,5-Trimethylhexane 03522-94-9 1.05 0.68 0.712 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.67 5.176 2,3,4-Trimethylpentane 00565-75-3 0.95 0.64 0.611 ortho-Xylene 00095-47-6 7.58 0.63 4.770 n-Heptane 00142-82-5 0.97 0.62 0.599 Methylcyclohexane 00108-87-2 1.56 0.61 0.946 2,2-DiMeHexane 00590-73-8 0.94 0.60 0.562 2-Methylhexane 00591-76-4 1.09 0.54 0.588 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.40 1.292 c-1,3-Dimethylcyclohexane 00638-04-0 3.07 0.40 1.234 2,4-Dimethylhexane 00589-43-5 1.61 0.39 0.634 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.38 1.677 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.38 4.415 3-Methylheptane 00589-81-1 1.12 0.38 0.422 2-Methyl-1-butene 00563-46-2 6.38 0.36 2.322 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.36 2.545 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.36 0.574 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.35 1.947 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.35 1.846 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.30 3.487 2,3,5-Trimethylhexane 01069-53-0 1.12 0.29 0.326 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.27 2.165 2,2-Dimethylpentane 00590-35-2 1.04 0.25 0.263 3-Methyl-t-2-pentene 00616-12-6 11.66 0.25 2.875 Vehicle 210b - Fuel 7 psi E10 - 86 ° F Static - Test 7468 Non Zero Mass Species Sorted By VOC

## E

- 111 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 210b - Fuel 7 psi E10 - 86 ° F Static - Test 7468 Non Zero Mass Species Sorted By VOC

2,4-Dimethylpentane 00108-08-7 1.46 0.25 0.359 n-Octane 00111-65-9 0.80 0.24 0.187 2,3-Dimethylpentane 00565-59-3 1.25 0.22 0.280 t-2-Hexene 04050-45-7 8.55 0.22 1.879 Cyclopentene 00142-29-0 6.69 0.18 1.182 2-Methyl-2-pentene 00625-27-4 11.03 0.17 1.892 Ethylbenzene 00100-41-4 2.96 0.17 0.492 Indan 00496-11-7 3.23 0.15 0.501 t-1,2-Dimethylcyclopentane 00822-50-4 3.07 0.13 0.402 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.07 0.073 c-1,3-Dimethylcyclopentane 02532-58-3 3.07 0.05 0.165 c-2-Butene 00590-18-1 14.26 0.01 0.157

Total 60.6 186.3 3.072

No MIR available, use weighted average of 3.0717 

### continued

## E

- 112 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 19.89 28.827 Toluene 00108-88-3 3.93 14.19 55.715 n-Hexane 00110-54-3 1.13 6.43 7.298 2-Methylbutane (Isopentane) 00078-78-4 1.35 5.86 7.933 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.47 4.855 3-Methylpentane 00096-14-0 1.69 2.92 4.939 Benzene 00071-43-2 0.69 2.82 1.956 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.80 3.358 Methanol 00067-56-1 0.66 2.75 1.806 Cyclohexane 00110-82-7 1.14 2.70 3.075 n-Butane 00106-97-8 1.08 2.33 2.512 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.24 12.029 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.17 16.849 2-Methyl-2-butene 00513-35-9 14.20 2.07 29.337 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.01 14.814 Methylcyclopentane 00096-37-7 2.05 1.97 4.031 t-2-Pentene 00646-04-8 10.47 1.83 19.185 n-Pentane 00109-66-0 1.21 1.81 2.202 2-Methylhexane 00591-76-4 1.09 1.63 1.770 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.48 4.732 2,3-Dimethylbutane 00079-29-8 0.90 1.47 1.322 n-Heptane 00142-82-5 0.97 1.28 1.240 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.24 14.615 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.07 4.690 c-2-Pentene 00627-20-3 10.28 1.04 10.707 2-Methyl-1-butene 00563-46-2 6.38 1.03 6.540 2,4-Dimethylpentane 00108-08-7 1.46 1.01 1.469 3,3-Dimethylpentane 00562-49-2 1.12 0.96 1.073 2,3,4-Trimethylpentane 00565-75-3 0.95 0.91 0.859 Methylcyclohexane 00108-87-2 1.56 0.82 1.270 2,3-Dimethylpentane 00565-59-3 1.25 0.73 0.912 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.68 3.770 Cyclopentene 00142-29-0 6.69 0.68 4.544 ortho-Xylene 00095-47-6 7.58 0.65 4.925 3-Methyl-c-2-pentene 00922-62-3 12.52 0.64 8.054 Unknown #16 8.55 0.64 5.476 Indan 00496-11-7 3.23 0.64 2.071 n-Octane 00111-65-9 0.80 0.63 0.505 2,4-Dimethylhexane 00589-43-5 1.61 0.62 0.995 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.60 7.052 Ethylbenzene 00100-41-4 2.96 0.48 1.412 t-2-Hexene 04050-45-7 8.55 0.47 3.992 2,2-Dimethylpentane 00590-35-2 1.04 0.47 0.486 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.45 3.215 Vehicle 210b - Fuel 7 psi E10 - 105 ° F Static - Test 7471 Non Zero Mass Species Sorted By VOC

## E

- 113 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 210b - Fuel 7 psi E10 - 105 ° F Static - Test 7471 Non Zero Mass Species Sorted By VOC

n-Nonane 00111-84-2 0.68 0.43 0.296 2,2-DiMeHexane 00590-73-8 0.94 0.41 0.389 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.41 3.232 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.40 2.674 3-Methylheptane 00589-81-1 1.12 0.39 0.433 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.38 0.613 c-2-Butene 00590-18-1 14.26 0.38 5.403 3-Methyl-t-2-pentene 00616-12-6 11.66 0.37 4.356 n-Decane 00124-18-5 0.59 0.31 0.181 1,4-Diethylbenzene 00105-05-5 4.39 0.30 1.336 2-Methyl-2-pentene 00625-27-4 11.03 0.30 3.320 2,2,3-Trimethylbutane 00464-06-2 1.05 0.26 0.274 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.23 2.801 2,2,5-Trimethylhexane 03522-94-9 1.05 0.21 0.222 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.21 0.225 2,3,5-Trimethylhexane 01069-53-0 1.12 0.20 0.224 2,2-Dimethylbutane 00075-83-2 1.11 0.19 0.207 Unknown #5 3.19 0.18 0.577 Ethylcyclohexane 01678-91-7 1.35 0.15 0.208 t-1,4-Dimethylcyclohexane 02207-04-7 3.19 0.14 0.441 c-1,3-Dimethylcyclopentane 02532-58-3 3.19 0.11 0.364 3-Methyloctane 02216-33-3 0.88 0.11 0.098 c-1,3-Dimethylcyclohexane 00638-04-0 3.19 0.08 0.255 2-Methylheptane 00592-27-8 0.97 0.04 0.037 t-1,2-Dimethylcyclopentane 00822-50-4 3.19 0.01 0.016

Total 108.8 346.6 3.186

No MIR available, use weighted average of 3.1858 

### continued

## E

- 114 Species CAS No. MIR Composite VOC

mg Ozone mg n-Propylbenzene 00103-65-1 1.96 49.37 96.738 Ethanol 00064-17-5 1.45 25.13 36.416 Toluene 00108-88-3 3.93 23.14 90.836 Methane 00074-82-8 0.01 12.96 0.180 Unknown #9 3.75 8.61 32.314 t-2-Butene 00624-64-6 15.20 6.42 97.600 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.35 28.739 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.81 35.510 Unknown #22

. 3.75 4.46 16.759 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.17 32.377 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.83 44.790 1,3,5-Trimethylbenzene 00108-67-8 11.75 3.34 39.255 Benzene 00071-43-2 0.69 3.13 2.176 Methylcyclohexane 00108-87-2 1.56 2.62 4.079 2,4-Dimethylpentane 00108-08-7 1.46 2.59 3.777 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.37 10.407 Unknown #16 3.75 2.36 8.872 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.25 12.469 2-Methyl-2-butene 00513-35-9 14.20 2.22 31.533 2,3,4-Trimethylpentane 00565-75-3 0.95 1.66 1.579 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.49 8.598 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.33 15.834 t-1,2-Dimethylcyclopentane 00822-50-4 3.75 1.25 4.692 Methylcyclopentane 00096-37-7 2.05 1.17 2.405 ortho-Xylene 00095-47-6 7.58 1.15 8.702 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.14 1.366 n-Nonane 00111-84-2 0.68 1.10 0.750 n-Heptane 00142-82-5 0.97 1.05 1.010 c-1,3-Dimethylcyclohexane 00638-04-0 3.75 1.03 3.878 2,4-Dimethylhexane 00589-43-5 1.61 0.79 1.272 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.79 1.272 n-Octane 00111-65-9 0.80 0.77 0.610 c-2-Pentene 00627-20-3 10.28 0.75 7.761 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.57 0.622 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 3.82 0.57 2.162 n-Hexane 00110-54-3 1.13 0.54 0.608 1,4-Diethylbenzene 00105-05-5 4.39 0.51 2.247 3-Methyl-t-2-pentene 00616-12-6 11.66 0.42 4.887 3-Methyl-c-2-pentene 00922-62-3 12.52 0.40 4.984 c-2-Butene 00590-18-1 14.26 0.34 4.917 2,3-Dimethylpentane 00565-59-3 1.25 0.34 0.427 2-Methylhexane 00591-76-4 1.09 0.30 0.325 2-Methyl-2-pentene 00625-27-4 11.03 0.21 2.312 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.20 1.587 Vehicle 210b - Fuel 7 psi E10 - Dynamic - Test 25756 Non Zero Mass Species Sorted By VOC

## E

- 115 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 210b - Fuel 7 psi E10 - Dynamic - Test 25756 Non Zero Mass Species Sorted By VOC 

### continued

2,2,5-Trimethylhexane 03522-94-9 1.05 0.09 0.092 Cyclopentene 00142-29-0 6.69 0.08 0.560 n-Undecane 01120-21-4 0.52 0.03 0.014 t-2-Hexene 04050-45-7 8.55 0.02 0.179

Total 189.2 710.5 3.754

No MIR available, use weighted average of 3.7545

## E

- 116 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 189.14 274.057 Toluene 00108-88-3 3.93 105.48 414.004 2-Methylbutane (Isopentane) 00078-78-4 1.35 84.31 114.234 n-Hexane 00110-54-3 1.13 78.27 88.812 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 42.94 60.023 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 32.59 39.085 3-Methylpentane 00096-14-0 1.69 31.61 53.452 2-Methyl-2-butene 00513-35-9 14.20 25.77 365.852 Benzene 00071-43-2 0.69 25.76 17.885 n-Propylbenzene 00103-65-1 1.96 23.14 45.338 n-Pentane 00109-66-0 1.21 23.05 28.006 Methylcyclopentane 00096-37-7 2.05 21.91 44.904 t-2-Pentene 00646-04-8 10.47 21.33 223.407 Cyclohexane 00110-82-7 1.14 20.87 23.733 n-Butane 00106-97-8 1.08 19.35 20.836 2,3-Dimethylbutane 00079-29-8 0.90 17.41 15.642 Methylcyclohexane 00108-87-2 1.56 12.74 19.820 Methanol 00067-56-1 0.66 12.58 8.268 2-Methylhexane 00591-76-4 1.09 12.28 13.331 2,3,4-Trimethylpentane 00565-75-3 0.95 12.08 11.463 c-2-Pentene 00627-20-3 10.28 11.28 116.014 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 11.28 35.981 n-Heptane 00142-82-5 0.97 11.03 10.652 2-Methyl-1-butene 00563-46-2 6.38 10.29 65.662 2,4-Dimethylpentane 00108-08-7 1.46 9.90 14.447 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 9.44 73.237 t-2-Hexene 04050-45-7 8.55 7.58 64.823 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 7.47 87.416 2,3-Dimethylpentane 00565-59-3 1.25 6.60 8.243 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 6.45 34.196 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 6.40 34.345 3-Methyl-t-2-pentene 00616-12-6 11.66 5.93 69.157 2,2-DiMeHexane 00590-73-8 0.94 5.87 5.526 3-Methyl-c-2-pentene 00922-62-3 12.52 5.62 70.387 2,4-Dimethylhexane 00589-43-5 1.61 5.56 8.934 n-Octane 00111-65-9 0.80 5.51 4.384 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.36 39.610 c-2-Butene 00590-18-1 14.26 5.21 74.262 1-Methylcyclopentene 00693-89-0 12.45 4.83 60.185 2-Methyl-2-pentene 00625-27-4 11.03 4.76 52.523 Cyclopentene 00142-29-0 6.69 4.64 31.020 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.62 36.682 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.50 29.726 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.45 7.138 Vehicle 210b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7482 Non Zero Mass Species Sorted By VOC

## E

- 117 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 210b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7482 Non Zero Mass Species Sorted By VOC

2,2,5-Trimethylhexane 03522-94-9 1.05 4.32 4.546 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.71 4.056 2-Methylpropane 00075-28-5 1.18 3.06 3.604 2-Methylheptane 00592-27-8 0.97 2.89 2.800 t-1,2-Dimethylcyclopentane 00822-50-4 2.99 2.84 8.492 ortho-Xylene 00095-47-6 7.58 2.58 19.575 1,3,5-Trimethylbenzene 00108-67-8 11.75 2.55 29.924 2,2-Dimethylpentane 00590-35-2 1.04 2.40 2.504 c-1,3-Dimethylcyclopentane 02532-58-3 2.99 2.21 6.593 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.15 11.914 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.15 12.399 Ethylcyclohexane 01678-91-7 1.35 2.09 2.815 3-Methylheptane 00589-81-1 1.12 2.06 2.315 2,2-Dimethylbutane 00075-83-2 1.11 1.78 1.982 3,3-Dimethylpentane 00562-49-2 1.12 1.74 1.945 Ethylbenzene 00100-41-4 2.96 1.70 5.025 c-1,3-Dimethylcyclohexane 00638-04-0 2.99 1.65 4.941 Unknown #16 2.99 1.62 4.840 2,3,5-Trimethylhexane 01069-53-0 1.12 1.34 1.496 2,2,3-Trimethylbutane 00464-06-2 1.05 1.24 1.304 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 1.21 4.623 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.05 8.207 4-Methyloctane 02216-34-4 0.85 1.05 0.888 n-Nonane 00111-84-2 0.68 1.03 0.706 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.90 3.481 t-1,4-Dimethylcyclohexane 02207-04-7 2.99 0.80 2.390 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.76 0.650 3,3-Dimethylhexane 00563-16-6 1.15 0.75 0.862 Unknown #5 2.99 0.70 2.085 1,3-Diethylbenzene 00141-93-5 7.08 0.63 4.457 Unknown #8 2.99 0.63 1.877 t-3-Heptene 14686-14-7 6.17 0.62 3.814 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.99 0.53 1.572 c-2-Heptene 06443-92-1 7.08 0.52 3.652 n-Decane 00124-18-5 0.59 0.52 0.305 1-Nonene 00124-11-8 2.49 0.42 1.058 3-Methyloctane 02216-33-3 0.88 0.41 0.367 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.41 4.327 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.38 2.474 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.32 2.696 2,4-Dimethylheptane 02213-23-2 1.26 0.28 0.352 1-Octene 00111-66-0 3.14 0.19 0.590

Total 1037.4 3101.2 2.989

No MIR available, use weighted average of 2.9895 

### continued

## E

- 118 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 5.96 8.079 Toluene 00108-88-3 3.93 5.77 22.658 Cyclohexane 00110-82-7 1.14 4.27 4.855 n-Butane 00106-97-8 1.08 3.06 3.297 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.95 14.395 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.95 2.336 Ethanol 00064-17-5 1.45 1.83 2.655 n-Hexane 00110-54-3 1.13 1.60 1.819 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.50 2.095 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.41 10.971 2,3-Dimethylbutane 00079-29-8 10.48 1.23 12.879 Methylcyclopentane 00096-37-7 2.05 1.22 2.493 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.21 6.495 Benzene 00071-43-2 0.69 1.21 0.838 Methylcyclohexane 00108-87-2 1.56 1.13 1.752 t-2-Butene 00624-64-6 15.20 1.12 17.027 2-Methyl-2-butene 00513-35-9 14.20 1.04 14.806 c-2-Butene 00590-18-1 1.12 0.98 1.098 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.92 4.027 n-Pentane 00109-66-0 1.21 0.91 1.102 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.90 4.977 2,4-Dimethylhexane 00589-43-5 1.61 0.89 1.437 3-Methylpentane 00096-14-0 1.69 0.88 1.481 Propane 00074-98-6 0.46 0.82 0.377 2,2,5-Trimethylhexane 03522-94-9 1.05 0.82 0.864 2,3,4-Trimethylpentane 00565-75-3 0.95 0.81 0.764 n-Propylbenzene 00103-65-1 1.96 0.76 1.492 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.75 3.993 2-Methylpropane 00075-28-5 1.18 0.69 0.813 Unknown #16 3.71 0.64 2.358 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.58 6.929 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.56 0.895 3-Methyl-c-2-pentene 00922-62-3 12.52 0.54 6.738 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.52 6.074 2,4-Dimethylpentane 00108-08-7 1.46 0.52 0.754 c-2-Pentene 00627-20-3 10.28 0.50 5.134 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.49 0.537 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.47 5.530 t-2-Pentene 00646-04-8 10.47 0.41 4.242 2,2-Dimethylbutane 00075-83-2 1.11 0.36 0.404 t-2-Hexene 04050-45-7 8.55 0.36 3.037 3-Methyl-t-2-pentene 00616-12-6 11.66 0.32 3.765 2-Methyl-2-pentene 00625-27-4 11.03 0.30 3.266 2-Methyl-1-butene 00563-46-2 6.38 0.29 1.876 Vehicle 210b - Fuel 9 psi E0 - 86 ° F Static - Test 7523 Non Zero Mass Species Sorted By VOC

## E

- 119 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 210b - Fuel 9 psi E0 - 86 ° F Static - Test 7523 Non Zero Mass Species Sorted By VOC

2,3,5-Trimethylhexane 01069-53-0 1.12 0.29 0.325 Unknown #22 3.71 0.26 0.966 Cyclopentene 00142-29-0 6.69 0.23 1.513 n-Heptane 00142-82-5 0.97 0.21 0.208 2,3-Dimethylpentane 00565-59-3 1.25 0.19 0.240 2-Methylhexane 00591-76-4 1.09 0.14 0.155 Ethylbenzene 00100-41-4 2.96 0.13 0.392 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.09 0.280 ortho-Xylene 00095-47-6 7.58 0.08 0.622

Total 56.1 208.1 3.712

No MIR available, use weighted average of 3.7122 

### continued

## E

- 120 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 11.62 45.627 2-Methylbutane (Isopentane) 00078-78-4 1.35 8.51 11.534 n-Butane 00106-97-8 1.08 7.76 8.352 Cyclohexane 00110-82-7 1.14 6.68 7.592 Ethanol 00064-17-5 1.45 5.88 8.523 n-Hexane 00110-54-3 1.13 3.70 4.199 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.00 4.200 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.92 3.502 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.12 11.380 Benzene 00071-43-2 0.69 1.98 1.372 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.97 15.278 3-Methylpentane 00096-14-0 1.69 1.92 3.241 2,3-Dimethylbutane 00079-29-8 0.90 1.69 1.517 Methylcyclopentane 00096-37-7 2.05 1.51 3.105 2-Methyl-2-butene 00513-35-9 14.20 1.46 20.719 n-Pentane 00109-66-0 1.21 1.35 1.644 2,3,4-Trimethylpentane 00565-75-3 0.95 1.28 1.217 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.24 14.603 Unknown #16 3.21 1.08 3.478 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.02 5.645 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.02 4.475 2,4-Dimethylhexane 00589-43-5 1.61 0.99 1.592 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.98 3.142 Ethylbenzene 00100-41-4 2.96 0.92 2.735 t-2-Pentene 00646-04-8 10.47 0.91 9.575 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.88 6.479 Indan 00496-11-7 3.23 0.80 2.585 2-Methylhexane 00591-76-4 1.09 0.78 0.850 2,2,5-Trimethylhexane 03522-94-9 1.05 0.76 0.804 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.69 1.102 2,4-Dimethylpentane 00108-08-7 1.46 0.67 0.973 2,2-DiMeHexane 00590-73-8 0.94 0.66 0.622 t-2-Hexene 04050-45-7 8.55 0.62 5.321 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.62 0.677 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.61 3.243 n-Propylbenzene 00103-65-1 1.96 0.61 1.197 3-Methyl-t-2-pentene 00616-12-6 11.66 0.57 6.652 Cyclopentene 00142-29-0 6.69 0.57 3.785 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.56 6.578 c-1,3-Dimethylcyclopentane 02532-58-3 3.21 0.56 1.801 Methylcyclohexane 00108-87-2 1.56 0.55 0.860 2,3,5-Trimethylhexane 01069-53-0 1.12 0.53 0.596 3-Methyl-c-2-pentene 00922-62-3 12.52 0.52 6.493 2-Methyl-1-butene 00563-46-2 6.38 0.51 3.274 Vehicle 210b - Fuel 9 psi E0 - 105 ° F Static - Test 7525 Non Zero Mass Species Sorted By VOC

## E

- 121 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 210b - Fuel 9 psi E0 - 105 ° F Static - Test 7525 Non Zero Mass Species Sorted By VOC

ortho-Xylene 00095-47-6 7.58 0.51 3.852 2,3-Dimethylpentane 00565-59-3 1.25 0.50 0.621 c-2-Pentene 00627-20-3 10.28 0.50 5.112 n-Heptane 00142-82-5 0.97 0.50 0.480 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.49 5.904 c-2-Butene 00590-18-1 14.26 0.43 6.174 2,2-Dimethylbutane 00075-83-2 1.11 0.43 0.474 2-Methyl-2-pentene 00625-27-4 11.03 0.39 4.349 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.37 2.467 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.36 2.889 n-Octane 00111-65-9 0.80 0.36 0.287 n-Undecane 01120-21-4 0.52 0.34 0.176 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.33 2.347 1-Methylcyclopentene 00693-89-0 12.45 0.32 4.037 t-2-Butene 00624-64-6 15.20 0.28 4.224 n-Nonane 00111-84-2 0.68 0.23 0.157 1,4-Diethylbenzene 00105-05-5 4.39 0.16 0.685 2,4-Dimethylheptane 02213-23-2 1.26 0.14 0.177

Total 92.3 296.6 3.215

No MIR available, use weighted average of 3.2145 

### continued

## E

- 122 Species CAS No. MIR Composite VOC

mg Ozone mg n-Propylbenzene 00103-65-1 1.96 23.02 45.118 Toluene 00108-88-3 3.93 18.28 71.734 Methane 00074-82-8 0.01 11.43 0.158 n-Butane 00106-97-8 1.08 10.27 11.057 Ethanol 00064-17-5 1.45 9.56 13.853 Cyclohexane 00110-82-7 1.14 8.21 9.341 2-Methylbutane (Isopentane) 00078-78-4 1.35 5.39 7.302 n-Hexane 00110-54-3 1.13 4.73 5.367 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.65 5.579 Unknown #22

. 2.47 3.41 8.417 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.58 3.606 3-Methylpentane 00096-14-0 1.69 2.39 4.035 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.29 12.290 2,3,5-Trimethylhexane 01069-53-0 1.12 2.26 2.537 2,2,5-Trimethylhexane 03522-94-9 1.05 2.26 2.385 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.99 3.189 Benzene 00071-43-2 0.69 1.83 1.273 2,3-Dimethylbutane 00079-29-8 10.48 1.78 18.707 Methylcyclopentane 00096-37-7 2.05 1.64 3.358 2,3,4-Trimethylpentane 00565-75-3 0.95 1.55 1.470 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.52 12.053 t-2-Pentene 00646-04-8 10.47 1.04 10.885 Methylcyclohexane 00108-87-2 1.56 1.03 1.598 2,2-Dimethylbutane 00075-83-2 1.11 0.93 1.034 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.93 4.086 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.91 10.817 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.88 10.264 2,4-Dimethylhexane 00589-43-5 1.61 0.79 1.276 3-Methyl-t-2-pentene 00616-12-6 11.66 0.76 8.817 3-Methyl-c-2-pentene 00922-62-3 12.52 0.67 8.414 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.67 5.197 c-2-Butene 00590-18-1 14.26 0.65 9.260 2,4-Dimethylpentane 00108-08-7 1.46 0.56 0.813 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.45 5.325 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.45 2.510 2-Methyl-1-butene 00563-46-2 6.38 0.39 2.486 n-Pentane 00109-66-0 1.21 0.33 0.406 ortho-Xylene 00095-47-6 7.58 0.25 1.907 n-Heptane 00142-82-5 0.97 0.21 0.203 Ethylbenzene 00100-41-4 2.96 0.19 0.551 2,3-Dimethylpentane 00565-59-3 1.25 0.09 0.107

Total 133.2 328.8 2.468

No MIR available, use weighted average of 2.4679 Vehicle 210b - Fuel 9 psi E0 - Dynamic - Test 25767 Non Zero Mass Species Sorted By VOC

## E

- 123 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 54.04 78.296 Benzene 00071-43-2 0.69 22.22 15.428 2-Methylbutane (Isopentane) 00078-78-4 1.35 144.00 195.102 2,3-Dimethylbutane 00079-29-8 0.90 21.42 19.250 3-Methylpentane 00096-14-0 1.69 29.96 50.665 Methylcyclopentane 00096-37-7 2.05 20.36 41.734 n-Butane 00106-97-8 1.08 155.08 167.008 2,4-Dimethylpentane 00108-08-7 1.46 11.61 16.947 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 11.63 90.175 Toluene 00108-88-3 3.93 102.96 404.127 n-Pentane 00109-66-0 1.21 22.14 26.902 n-Hexane 00110-54-3 1.13 57.31 65.027 Cyclohexane 00110-82-7 1.14 108.36 123.241 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 8.62 27.493 n-Heptane 00142-82-5 0.97 5.50 5.308 2-Methyl-2-butene 00513-35-9 14.20 22.23 315.503 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 46.07 55.239 2-Methyl-1-butene 00563-46-2 6.38 8.33 53.151 2,3-Dimethylpentane 00565-59-3 1.25 8.66 10.809 2,3,4-Trimethylpentane 00565-75-3 0.95 18.40 17.463 2,4-Dimethylhexane 00589-43-5 1.61 8.99 14.433 2,2-DiMeHexane 00590-73-8 0.94 5.68 5.350 2-Methylhexane 00591-76-4 1.09 10.00 10.857 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 6.51 10.452 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 5.74 30.392 3-Methyl-t-2-pentene 00616-12-6 11.66 6.25 72.822 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.21 16.338 c-2-Pentene 00627-20-3 10.28 9.61 98.755 t-2-Pentene 00646-04-8 10.47 17.57 184.018 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 43.96 61.453 2,2,5-Trimethylhexane 03522-94-9 1.05 7.84 8.251 t-2-Hexene 04050-45-7 8.55 6.97 59.590

Total 1010.2 2351.6 2.328 Vehicle 210b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7531 Non Zero Mass Species Sorted By VOC

## E

- 124 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 2.37 3.428 Benzene 00071-43-2 0.69 1.75 1.218 2-Methylbutane (Isopentane) 00078-78-4 1.35 1.94 2.631 2,3-Dimethylbutane 00079-29-8 0.90 0.35 0.315 ortho-Xylene 00095-47-6 7.58 0.68 5.127 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.10 5.908 3-Methylpentane 00096-14-0 1.69 0.39 0.658 Methylcyclopentane 00096-37-7 2.05 0.54 1.098 Ethylbenzene 00100-41-4 2.96 0.16 0.468 n-Butane 00106-97-8 1.08 2.49 2.684 2,4-Dimethylpentane 00108-08-7 1.46 0.44 0.638 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.94 7.257 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.33 3.859 Toluene 00108-88-3 3.93 6.01 23.579 n-Pentane 00109-66-0 1.21 0.20 0.248 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.26 3.053 n-Hexane 00110-54-3 1.13 1.08 1.225 Cyclohexane 00110-82-7 1.14 3.28 3.734 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.31 0.994 Cyclopentene 00142-29-0 6.69 0.17 1.112 n-Heptane 00142-82-5 0.97 0.23 0.222 2-Methyl-2-butene 00513-35-9 14.20 0.47 6.740 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.15 1.742 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.33 1.600 2-Methyl-1-butene 00563-46-2 6.38 0.08 0.528 2,3-Dimethylpentane 00565-59-3 1.25 0.46 0.573 2,3,4-Trimethylpentane 00565-75-3 0.95 0.52 0.496 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.59 0.644 2,4-Dimethylhexane 00589-43-5 1.61 0.21 0.334 2-Methylhexane 00591-76-4 1.09 0.45 0.486 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.39 0.633 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.71 3.908 3-Methyl-t-2-pentene 00616-12-6 11.66 0.64 7.494 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.05 0.404 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.54 2.378 t-2-Butene 00624-64-6 15.20 0.18 2.684 c-2-Pentene 00627-20-3 10.28 0.36 3.746 t-2-Pentene 00646-04-8 10.47 0.28 2.891 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.81 1.126 2,2,5-Trimethylhexane 03522-94-9 1.05 0.49 0.514

Total 33.7 108.4 3.214 Vehicle 210b - Fuel 7 psi E0 - 86 ° F Static - Test 7547 Non Zero Mass Species Sorted By VOC

## E

- 125 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 2.74 3.967 Benzene 00071-43-2 0.69 2.24 1.555 2-Methylbutane (Isopentane) 00078-78-4 1.35 8.05 10.900 2,3-Dimethylbutane 00079-29-8 0.90 1.59 1.431 ortho-Xylene 00095-47-6 7.58 0.51 3.895 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.81 9.736 3-Methylpentane 00096-14-0 1.69 1.74 2.944 Methylcyclopentane 00096-37-7 2.05 0.97 1.988 Ethylbenzene 00100-41-4 2.96 0.70 2.070 n-Propylbenzene 00103-65-1 1.96 0.36 0.704 n-Butane 00106-97-8 1.08 5.28 5.681 2,4-Dimethylpentane 00108-08-7 1.46 0.68 0.989 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.47 19.128 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.46 17.163 Methylcyclohexane 00108-87-2 1.56 0.57 0.884 Toluene 00108-88-3 3.93 10.95 42.984 n-Pentane 00109-66-0 1.21 1.36 1.650 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.34 3.983 n-Hexane 00110-54-3 1.13 2.93 3.325 Cyclohexane 00110-82-7 1.14 6.44 7.327 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.50 1.605 Cyclopentene 00142-29-0 6.69 0.72 4.827 n-Heptane 00142-82-5 0.97 0.48 0.465 2-Methyl-2-butene 00513-35-9 14.20 1.47 20.870 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.67 7.943 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.64 3.163 2-Methyl-1-butene 00563-46-2 6.38 0.51 3.240 2,3-Dimethylpentane 00565-59-3 1.25 0.51 0.634 2,3,4-Trimethylpentane 00565-75-3 0.95 1.15 1.094 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.73 0.794 2,4-Dimethylhexane 00589-43-5 1.61 0.52 0.829 c-2-Butene 00590-18-1 14.26 0.30 4.268 2,2-DiMeHexane 00590-73-8 0.94 0.83 0.783 2-Methylhexane 00591-76-4 1.09 0.55 0.592 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.45 0.721 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.54 2.886 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.81 4.503 3-Methyl-t-2-pentene 00616-12-6 11.66 0.58 6.713 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 3.43 25.352 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.95 4.191 t-2-Butene 00624-64-6 15.20 0.21 3.168 2-Methyl-2-pentene 00625-27-4 11.03 0.40 4.406 c-2-Pentene 00627-20-3 10.28 0.62 6.376 t-2-Pentene 00646-04-8 10.47 0.87 9.127 Vehicle 210b - Fuel 7 psi E0 - 105 ° F Static - Test 7549 Non Zero Mass Species Sorted By VOC

## E

- 126 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 210b - Fuel 7 psi E0 - 105 ° F Static - Test 7549 Non Zero Mass Species Sorted By VOC

2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.87 4.015 3-Methyl-c-2-pentene 00922-62-3 12.52 0.20 2.467 2,2,5-Trimethylhexane 03522-94-9 1.05 0.63 0.662 t-2-Hexene 04050-45-7 8.55 0.30 2.572

Total 77.6 270.6 3.486 

### continued

## E

- 127 Species CAS No. MIR Composite VOC

mg Ozone mg 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 40.56 299.543 Ethanol 00064-17-5 1.45 21.41 31.027 Toluene 00108-88-3 3.93 19.77 77.583 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 14.52 77.953 n-Butane 00106-97-8 1.08 13.81 14.870 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 13.35 103.515 Cyclohexane 00110-82-7 1.14 13.23 15.048 Benzene 00071-43-2 0.69 12.44 8.636 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 7.50 32.943 Unknown #22

. 4.28 5.84 24.969 Methylcyclohexane 00108-87-2 1.56 4.61 7.177 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.57 19.785 2,2,5-Trimethylhexane 03522-94-9 1.05 2.96 3.113 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.52 3.017 Indan 00496-11-7 3.23 2.48 8.026 2-Methylpropane 00075-28-5 1.18 2.45 2.878 1,3,5-Trimethylbenzene 00108-67-8 11.75 2.36 27.698 t-1,2-Dimethylcyclopentane 00822-50-4 4.28 2.21 9.475 2-Methyl-2-butene 00513-35-9 14.20 1.82 25.771 Methane 00074-82-8 0.01 1.74 0.024 2,3,4-Trimethylpentane 00565-75-3 0.95 1.39 1.323 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.36 16.196 2,3,5-Trimethylhexane 01069-53-0 1.12 1.33 1.485 2,4-Dimethylhexane 00589-43-5 1.61 1.09 1.743 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.67 4.433 t-2-Butene 00624-64-6 15.20 0.63 9.523 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.57 0.618 2-Methyl-2-pentene 00625-27-4 11.03 0.57 6.246 ortho-Xylene 00095-47-6 7.58 0.53 3.979 3-Methyl-t-2-pentene 00616-12-6 11.66 0.40 4.645 3-Methyl-c-2-pentene 00922-62-3 12.52 0.40 4.987 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.40 0.637

Total 198.4 848.9 4.278

No MIR available, use weighted average of 4.2779 Vehicle 210b - Fuel 7 psi E0 - Dynamic - Test 25776 Non Zero Mass Species Sorted By VOC

## E

- 128 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 85.49 115.836 Toluene 00108-88-3 3.93 74.41 292.053 Cyclohexane 00110-82-7 1.14 67.10 76.315 n-Butane 00106-97-8 1.08 44.50 47.923 n-Hexane 00110-54-3 1.13 37.15 42.148 Ethanol 00064-17-5 1.45 29.71 43.055 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 27.65 38.648 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 25.39 30.442 3-Methylpentane 00096-14-0 1.69 19.28 32.594 Benzene 00071-43-2 0.69 16.17 11.230 2-Methyl-2-butene 00513-35-9 14.20 15.53 220.428 n-Pentane 00109-66-0 1.21 14.40 17.492 2,3-Dimethylbutane 00079-29-8 0.90 13.64 12.260 t-2-Pentene 00646-04-8 10.47 12.54 131.368 Methylcyclopentane 00096-37-7 2.05 12.54 25.696 2,3,4-Trimethylpentane 00565-75-3 0.95 10.55 10.007 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.43 65.411 2,4-Dimethylpentane 00108-08-7 1.46 6.88 10.036 c-2-Pentene 00627-20-3 10.28 6.84 70.290 2-Methylhexane 00591-76-4 1.09 6.27 6.806 2-Methyl-1-butene 00563-46-2 6.38 6.00 38.260 2,2-DiMeHexane 00590-73-8 0.94 5.41 5.089 2,3-Dimethylpentane 00565-59-3 1.25 5.23 6.525 2,4-Dimethylhexane 00589-43-5 1.61 5.20 8.345 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.82 15.364 t-2-Hexene 04050-45-7 8.55 4.64 39.655 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.51 7.237 2,2,5-Trimethylhexane 03522-94-9 1.05 4.41 4.639 Methane 00074-82-8 0.01 4.22 0.058 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.17 22.386 Methanol 00067-56-1 0.66 4.02 2.641 3-Methyl-t-2-pentene 00616-12-6 11.66 3.99 46.498 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.97 46.519 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.92 20.769 3-Methyl-c-2-pentene 00922-62-3 12.52 3.44 43.023 n-Heptane 00142-82-5 0.97 3.12 3.015 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.12 3.405 Cyclopentene 00142-29-0 6.69 2.84 18.970 2-Methyl-2-pentene 00625-27-4 11.03 2.76 30.451 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.62 17.299 1-Methylcyclopentene 00693-89-0 12.45 2.52 31.397 ortho-Xylene 00095-47-6 7.58 2.33 17.666 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 2.33 18.509 c-2-Butene 00590-18-1 14.26 2.31 33.002 Vehicle 210b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7550 Non Zero Mass Species Sorted By VOC

## E

- 129 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 210b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7550 Non Zero Mass Species Sorted By VOC

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.28 10.024 Ethylbenzene 00100-41-4 2.96 2.17 6.436 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.96 10.860 Methylcyclohexane 00108-87-2 1.56 1.96 3.041 t-1,2-Dimethylcyclopentane 00822-50-4 2.90 1.75 5.072 2,2-Dimethylbutane 00075-83-2 1.11 1.74 1.938 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.60 18.834 2,3,5-Trimethylhexane 01069-53-0 1.12 1.45 1.627 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.42 8.188 c-1,3-Dimethylcyclopentane 02532-58-3 2.90 1.37 3.969 n-Propylbenzene 00103-65-1 1.96 1.27 2.482 3-Methylheptane 00589-81-1 1.12 1.25 1.410 Unknown #16 2.90 1.22 3.535 2,2-Dimethylpentane 00590-35-2 1.04 1.18 1.235 2,2,3-Trimethylbutane 00464-06-2 1.05 1.16 1.225 2-Methylheptane 00592-27-8 0.97 1.13 1.097 1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.01 7.124 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.96 7.520 3,3-Dimethylpentane 00562-49-2 1.12 0.92 1.025 n-Octane 00111-65-9 0.80 0.87 0.694 Unknown #1 2.90 0.86 2.492 Ethylene 00074-85-1 8.88 0.84 7.462 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.68 8.106 Indan 00496-11-7 3.23 0.64 2.084 c-1,3-Dimethylcyclohexane 00638-04-0 2.90 0.64 1.847 Unknown #5 2.90 0.55 1.583 4-Methyl-t-2-pentene 00674-76-0 8.04 0.50 4.050 3,3-Dimethylhexane 00563-16-6 1.15 0.50 0.577 t-3-Heptene 14686-14-7 6.17 0.49 3.040 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.47 1.811 Isopropylbenzene (Cumene) 00098-82-8 2.90 0.47 1.354 c-2-Heptene 06443-92-1 7.08 0.45 3.160 1-Nonene 00124-11-8 2.49 0.41 1.019 1,3-Diethylbenzene 00141-93-5 7.08 0.34 2.375 Unknown #8 2.90 0.33 0.962 t-2-Nonene 06434-78-2 2.90 0.32 0.916 3,5-Dimethylheptane 00926-82-9 1.42 0.31 0.441 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.29 3.029 4-Methyloctane 02216-34-4 0.85 0.26 0.221 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.24 1.978 n-Nonane 00111-84-2 0.68 0.22 0.151 Unknown #10 2.90 0.21 0.605

Total 665.0 1927.4 2.898

No MIR available, use weighted average of 2.8982

## E

- 130 Test Fuel Test No. Bag THC mg GC as % of THC GC VOC

mg Ozone mg Reactivity Species Present 86 ° F E10 - 10 psi 7442 74.9 84.5 63.3 229.3 3.620 59 Static E10 - 7 psi 7464 60.4 77.3 46.7 118.1 2.531 12 E0 - 9 psi 7506 34.8 88.3 30.7 102.3 3.329 41 E0 - 7 psi 7526 40.9 86.2 35.3 104.0 2.947 38

105 ° F E10 - 10 psi 7446 228.3 105.1 239.8 761.0 3.174 78 Static E10 - 7 psi 7465 159.2 87.2 138.9 440.2 3.169 64 E0 - 9 psi 7507 71.1 82.7 58.8 173.0 2.943 32 E0 - 7 psi 7528 66.8 106.3 71.0 251.7 3.546 50

Dynamic E10 - 10 psi 25750 144.8 124.2 179.8 839.7 4.669 48 E10 - 7 psi 25754 284.5 88.3 251.3 879.7 3.500 60 E0 - 9 psi 25764 191.7 52.9 101.4 314.8 3.105 38 E0 - 7 psi 25769 141.4 69.4 98.1 381.1 3.885 59

DHB E10 - 10 psi 7429 1966.7 101.3 1992.2 5290.8 2.656 92 Total E10 - 7 psi 7473 1769.4 67.1 1187.5 4082.1 3.438 80 E0 - 9 psi 7516 967.5 88.7 858.6 2298.5 2.677 73 E0 - 7 psi 7538 917.6 94.2 864.0 2571.4 2.976 80 

## Vehicle 213b

## E

- 131 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 16.97 24.593 Toluene 00108-88-3 3.93 10.78 42.296 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.07 37.471 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.07 11.117 n-Butane 00106-97-8 1.08 2.01 2.169 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.96 15.195 Benzene 00071-43-2 0.69 1.62 1.123 Propane 00074-98-6 0.46 1.53 0.699 1,4-Diethylbenzene 00105-05-5 4.39 1.34 5.889 n-Hexane 00110-54-3 1.13 1.12 1.275 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.10 4.841 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.03 12.098 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.94 1.127 2,3,4-Trimethylpentane 00565-75-3 0.95 0.89 0.845 n-Heptane 00142-82-5 0.97 0.80 0.774 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.67 3.724 Methylcyclohexane 00108-87-2 1.56 0.67 1.043 t-2-Pentene 00646-04-8 10.47 0.65 6.813 2-Methyl-2-butene 00513-35-9 14.20 0.63 8.921 n-Decane 00124-18-5 0.59 0.58 0.343 n-Octane 00111-65-9 0.80 0.55 0.441 ortho-Xylene 00095-47-6 7.58 0.50 3.813 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.48 3.185 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.45 1.448 2-Methylpropane 00075-28-5 1.18 0.45 0.528 n-Nonane 00111-84-2 0.68 0.45 0.305 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.41 3.059 2-Methylhexane 00591-76-4 1.09 0.40 0.433 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.39 4.626 2,2,5-Trimethylhexane 03522-94-9 1.05 0.39 0.406 Ethylbenzene 00100-41-4 2.96 0.39 1.141 2,2-DiMeHexane 00590-73-8 0.94 0.37 0.351 n-Propylbenzene 00103-65-1 1.96 0.37 0.717 t-2-Hexene 04050-45-7 8.55 0.35 2.976 Cyclohexane 00110-82-7 1.14 0.34 0.390 c-2-Pentene 00627-20-3 10.28 0.33 3.401 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.33 0.361 Methylcyclopentane 00096-37-7 2.05 0.33 0.670 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.32 0.513 c-1,3-Dimethylcyclohexane 00638-04-0 3.62 0.32 1.155 3-Methyl-t-2-pentene 00616-12-6 11.66 0.29 3.373 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.29 2.026 3-Methylheptane 00589-81-1 1.12 0.29 0.321 2,4-Dimethylhexane 00589-43-5 1.61 0.28 0.445 Vehicle 213b - Fuel 10 psi E10 - 86 ° F Static - Test 7442 Non Zero Mass Species Sorted By VOC

## E

- 132 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 213b - Fuel 10 psi E10 - 86 ° F Static - Test 7442 Non Zero Mass Species Sorted By VOC

2-Methyl-2-pentene 00625-27-4 11.03 0.24 2.600 2,3-Dimethylpentane 00565-59-3 1.25 0.22 0.280 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.20 2.364 t-1,2-Dimethylcyclopentane 00822-50-4 3.62 0.17 0.626 2,3-Dimethylbutane 00079-29-8 0.90 0.16 0.143 2,4-Dimethylpentane 00108-08-7 1.46 0.14 0.199 2-Methylheptane 00592-27-8 0.97 0.13 0.130 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.13 1.037 3-Methyl-c-2-pentene 00922-62-3 12.52 0.12 1.542 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.12 0.161 c-2-Butene 00590-18-1 14.26 0.09 1.335 3-Methylpentane 00096-14-0 1.69 0.07 0.121 Cyclopentene 00142-29-0 6.69 0.04 0.251 c-1,3-Dimethylcyclopentane 02532-58-3 3.62 0.01 0.039 2-Methyl-1-butene 00563-46-2 6.38 0.01 0.035

Total 63.3 229.3 3.620

No MIR available, use weighted average of 3.6201 

### continued

## E

- 133 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 66.40 96.207 Toluene 00108-88-3 3.93 29.59 116.147 n-Butane 00106-97-8 1.08 19.17 20.643 2-Methylbutane (Isopentane) 00078-78-4 1.35 12.34 16.714 n-Hexane 00110-54-3 1.13 8.64 9.804 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 6.69 49.398 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 6.07 32.577 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 5.13 7.176 Benzene 00071-43-2 0.69 4.59 3.185 3-Methylpentane 00096-14-0 1.69 4.55 7.695 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.49 34.840 2-Methyl-2-butene 00513-35-9 14.20 3.78 53.673 n-Pentane 00109-66-0 1.21 3.39 4.119 t-2-Pentene 00646-04-8 10.47 3.37 35.301 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.15 3.774 Methylcyclopentane 00096-37-7 2.05 2.47 5.066 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.28 10.010 1,3,5-Trimethylbenzene 00108-67-8 11.75 2.22 26.092 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 2.06 24.077 2,3-Dimethylbutane 00079-29-8 0.90 2.03 1.821 Cyclohexane 00110-82-7 1.14 2.02 2.298 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.93 10.678 Methylcyclohexane 00108-87-2 1.56 1.80 2.805 c-2-Pentene 00627-20-3 10.28 1.74 17.930 2-Methylpropane 00075-28-5 1.18 1.74 2.042 2,3,4-Trimethylpentane 00565-75-3 0.95 1.61 1.531 n-Heptane 00142-82-5 0.97 1.58 1.523 n-Decane 00124-18-5 0.59 1.50 0.888 t-2-Butene 00624-64-6 15.20 1.50 22.758 2-Methyl-1-butene 00563-46-2 6.38 1.48 9.423 2,2-DiMeHexane 00590-73-8 0.94 1.42 1.335 2-Methylhexane 00591-76-4 1.09 1.42 1.538 ortho-Xylene 00095-47-6 7.58 1.40 10.583 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 1.28 6.781 n-Octane 00111-65-9 0.80 1.22 0.970 n-Propylbenzene 00103-65-1 1.96 1.17 2.295 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.11 3.544 n-Nonane 00111-84-2 0.68 1.01 0.693 t-2-Hexene 04050-45-7 8.55 0.98 8.417 c-1,3-Dimethylcyclohexane 00638-04-0 3.17 0.98 3.107 1-Methylcyclopentene 00693-89-0 12.45 0.95 11.784 2,4-Dimethylpentane 00108-08-7 1.46 0.91 1.328 2,4-Dimethylhexane 00589-43-5 1.61 0.89 1.432 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.88 1.407 Vehicle 213b - Fuel 10 psi E10 - 105 ° F Static - Test 7446 Non Zero Mass Species Sorted By VOC

## E

- 134 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 213b - Fuel 10 psi E10 - 105 ° F Static - Test 7446 Non Zero Mass Species Sorted By VOC

2,3-Dimethylpentane 00565-59-3 1.25 0.87 1.083 3-Methylheptane 00589-81-1 1.12 0.87 0.974 3-Methyl-c-2-pentene 00922-62-3 12.52 0.78 9.794 3-Methyl-t-2-pentene 00616-12-6 11.66 0.72 8.398 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.69 0.757 2,2,5-Trimethylhexane 03522-94-9 1.05 0.67 0.706 Ethylbenzene 00100-41-4 2.96 0.67 1.978 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.64 7.621 Unknown #16 3.17 0.61 1.933 2-Methyl-2-pentene 00625-27-4 11.03 0.57 6.288 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.55 4.361 Cyclopentene 00142-29-0 6.69 0.55 3.672 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.53 3.051 3,5-Dimethylheptane 00926-82-9 1.42 0.49 0.700 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.47 3.081 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.47 3.294 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.46 3.484 2-Methylheptane 00592-27-8 0.97 0.43 0.419 3,3-Dimethylpentane 00562-49-2 1.12 0.40 0.450 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.40 1.527 2,3,5-Trimethylhexane 01069-53-0 1.12 0.39 0.436 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.37 2.938 t-1,4-Dimethylcyclohexane 02207-04-7 3.17 0.37 1.165 c-2-Butene 00590-18-1 14.26 0.30 4.256 Indan 00496-11-7 3.23 0.25 0.801 t-1,2-Dimethylcyclopentane 00822-50-4 3.17 0.24 0.772 Propane 00074-98-6 0.46 0.21 0.097 2,2-Dimethylpentane 00590-35-2 1.04 0.19 0.199 n-Undecane 01120-21-4 0.52 0.17 0.087 3-Methyloctane 02216-33-3 0.88 0.15 0.133 2,2-Dimethylbutane 00075-83-2 1.11 0.13 0.140 c-1,3-Dimethylcyclopentane 02532-58-3 3.17 0.11 0.362 1,4-Diethylbenzene 00105-05-5 4.39 0.11 0.500 Unknown #22

. 3.17 0.05 0.151

Total 239.8 761.0 3.174

No MIR available, use weighted average of 3.1738 

### continued

## E

- 135 Species CAS No. MIR Composite VOC

mg Ozone mg 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 48.10 355.240 Ethanol 00064-17-5 1.45 20.65 29.922 Toluene 00108-88-3 3.93 17.09 67.082 n-Butane 00106-97-8 1.08 12.30 13.248 Benzene 00071-43-2 0.69 7.28 5.056 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 6.21 33.338 2-Methylbutane (Isopentane) 00078-78-4 1.35 5.64 7.641 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 5.32 7.443 n-Hexane 00110-54-3 1.13 4.88 5.535 1,3,5-Trimethylbenzene 00108-67-8 11.75 4.05 47.553 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.92 30.394 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 2.87 22.769 1,2,3-Trimethylbenzene 00526-73-8 11.94 2.40 28.641 2-Methyl-2-butene 00513-35-9 14.20 2.27 32.226 2,3-Dimethylbutane 00079-29-8 0.90 2.13 1.914 Cyclopentene 00142-29-0 6.69 2.10 14.050 ortho-Xylene 00095-47-6 7.58 2.10 15.872 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.00 8.784 n-Pentane 00109-66-0 1.21 1.96 2.382 2,2-DiMeHexane 00590-73-8 0.94 1.95 1.832 t-2-Pentene 00646-04-8 10.47 1.71 17.945 Cyclohexane 00110-82-7 1.14 1.69 1.917 Methylcyclopentane 00096-37-7 2.05 1.64 3.370 3-Methylpentane 00096-14-0 1.69 1.53 2.593 Methylcyclohexane 00108-87-2 1.56 1.38 2.152 n-Heptane 00142-82-5 0.97 1.29 1.243 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.24 1.485 2,4-Dimethylhexane 00589-43-5 1.61 1.18 1.895 c-2-Butene 00590-18-1 14.26 1.18 16.785 3-Methyl-t-2-pentene 00616-12-6 11.66 1.12 13.102 2-Methyl-2-pentene 00625-27-4 11.03 1.08 11.938 n-Octane 00111-65-9 0.80 1.07 0.849 2,3-Dimethylpentane 00565-59-3 1.25 1.06 1.326 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.93 2.982 2-Methylhexane 00591-76-4 1.09 0.85 0.922 t-2-Hexene 04050-45-7 8.55 0.77 6.582 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.70 8.219 2,3,4-Trimethylpentane 00565-75-3 0.95 0.63 0.598 Ethylbenzene 00100-41-4 2.96 0.60 1.785 2-Methylpropane 00075-28-5 1.18 0.58 0.683 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.50 0.798 2-Methyl-1-butene 00563-46-2 6.38 0.47 3.005 c-2-Pentene 00627-20-3 10.28 0.41 4.184 2,2-Dimethylbutane 00075-83-2 1.11 0.26 0.292 Vehicle 213b - Fuel 10 psi E10 - Dynamic - Test 25750 Non Zero Mass Species Sorted By VOC

## E

- 136 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 213b - Fuel 10 psi E10 - Dynamic - Test 25750 Non Zero Mass Species Sorted By VOC

2,4-Dimethylpentane 00108-08-7 1.46 0.25 0.372 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.21 1.173 Indan 00496-11-7 3.23 0.14 0.449 2,2,5-Trimethylhexane 03522-94-9 1.05 0.13 0.137

Total 179.8 839.7 4.669 

### continued

## E

- 137 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 545.98 791.116 n-Butane 00106-97-8 1.08 196.96 212.113 2-Methylbutane (Isopentane) 00078-78-4 1.35 188.38 255.236 Toluene 00108-88-3 3.93 152.43 598.276 n-Hexane 00110-54-3 1.13 112.72 127.905 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 66.10 92.391 3-Methylpentane 00096-14-0 1.69 47.30 79.974 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 44.91 53.858 2-Methyl-2-butene 00513-35-9 14.20 42.05 596.841 n-Pentane 00109-66-0 1.21 41.19 50.042 Benzene 00071-43-2 0.69 36.90 25.618 t-2-Pentene 00646-04-8 10.47 35.47 371.500 Methylcyclopentane 00096-37-7 2.05 31.20 63.956 Cyclohexane 00110-82-7 1.14 30.10 34.240 2,3-Dimethylbutane 00079-29-8 0.90 28.27 25.405 c-2-Pentene 00627-20-3 10.28 18.47 189.858 Methylcyclohexane 00108-87-2 1.56 18.04 28.062 n-Propylbenzene 00103-65-1 1.96 17.85 34.974 n-Heptane 00142-82-5 0.97 17.59 16.983 2-Methylhexane 00591-76-4 1.09 17.47 18.958 2-Methyl-1-butene 00563-46-2 6.38 16.67 106.309 2,3,4-Trimethylpentane 00565-75-3 0.95 16.34 15.504 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 15.37 49.056 2,4-Dimethylpentane 00108-08-7 1.46 14.06 20.524 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 13.60 105.486 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 11.73 137.329 t-2-Hexene 04050-45-7 8.55 10.99 93.957 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 10.21 54.106 2,3-Dimethylpentane 00565-59-3 1.25 9.55 11.924 3-Methyl-t-2-pentene 00616-12-6 11.66 9.02 105.173 2,4-Dimethylhexane 00589-43-5 1.61 8.19 13.147 2,2-DiMeHexane 00590-73-8 0.94 8.05 7.572 3-Methyl-c-2-pentene 00922-62-3 12.52 7.86 98.410 2-Methyl-2-pentene 00625-27-4 11.03 7.65 84.351 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.60 40.822 c-2-Butene 00590-18-1 14.26 7.39 105.363 1-Methylcyclopentene 00693-89-0 12.45 7.27 90.514 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.25 53.551 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 6.85 45.279 Cyclopentene 00142-29-0 6.69 6.54 43.759 n-Octane 00111-65-9 0.80 6.43 5.122 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 5.75 45.673 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 5.63 9.044 2,2,5-Trimethylhexane 03522-94-9 1.05 5.33 5.615 Vehicle 213b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7429 Non Zero Mass Species Sorted By VOC

## E

- 138 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 213b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7429 Non Zero Mass Species Sorted By VOC

2,2-Dimethylbutane 00075-83-2 1.11 5.25 5.837 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 4.25 4.640 ortho-Xylene 00095-47-6 7.58 3.89 29.499 2-Methylheptane 00592-27-8 0.97 3.84 3.714 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.83 16.839 t-1,2-Dimethylcyclopentane 00822-50-4 2.66 3.59 9.539 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 3.58 20.708 3-Methylheptane 00589-81-1 1.12 3.34 3.754 1,3,5-Trimethylbenzene 00108-67-8 11.75 3.19 37.483 c-1,3-Dimethylcyclopentane 02532-58-3 2.66 3.09 8.205 Ethylbenzene 00100-41-4 2.96 2.93 8.676 2,2-Dimethylpentane 00590-35-2 1.04 2.89 3.011 c-1,3-Dimethylcyclohexane 00638-04-0 2.66 2.51 6.676 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.29 12.712 3,3-Dimethylpentane 00562-49-2 1.12 1.89 2.111 2,2,3-Trimethylbutane 00464-06-2 1.05 1.70 1.788 2,3,5-Trimethylhexane 01069-53-0 1.12 1.70 1.900 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.66 13.038 3,5-Dimethylheptane 00926-82-9 1.42 1.46 2.083 n-Nonane 00111-84-2 0.68 1.42 0.972 n-Decane 00124-18-5 0.59 1.37 0.810 t-1,4-Dimethylcyclohexane 02207-04-7 2.66 1.16 3.070 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.08 4.182 Unknown #16 2.66 0.96 2.559 4-Methyloctane 02216-34-4 0.85 0.96 0.816 1,3-Butadiene 00106-99-0 12.45 0.93 11.634 n-Undecane 01120-21-4 0.52 0.90 0.468 Unknown #8 2.66 0.88 2.338 Unknown #5 2.66 0.87 2.321 3,3-Dimethylhexane 00563-16-6 1.15 0.86 0.987 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.84 9.981 c-2-Heptene 06443-92-1 7.08 0.73 5.167 Indan 00496-11-7 3.23 0.70 2.274 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.67 6.998 t-3-Heptene 14686-14-7 6.17 0.64 3.949 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.62 4.046 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.62 4.372 2,4-Dimethylheptane 02213-23-2 1.26 0.58 0.739 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.50 4.182 3-Methyloctane 02216-33-3 0.88 0.46 0.411 4-Methyl-t-2-pentene 00674-76-0 8.04 0.45 3.583 1-Heptene 00592-76-7 4.29 0.42 1.784 

### continued

## E

- 139 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 213b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7429 Non Zero Mass Species Sorted By VOC

t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.66 0.40 1.053 Unknown #22

. 2.66 0.39 1.028 1-Nonene 00124-11-8 2.49 0.36 0.903 Isopropylbenzene (Cumene) 00098-82-8 2.66 0.33 0.868 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.32 2.004 1,1-Dimethylcyclohexane 00590-66-9 1.12 0.19 0.214

Total 1992.2 5290.8 2.656

No MIR available, use weighted average of 2.6557 

### continued

## E

- 140 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 10.30 14.920 Toluene 00108-88-3 3.93 8.66 33.974 2-Methylbutane (Isopentane) 00078-78-4 1.35 6.25 8.467 n-Hexane 00110-54-3 1.13 5.36 6.082 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.01 4.211 n-Butane 00106-97-8 1.08 2.98 3.204 n-Pentane 00109-66-0 1.21 2.45 2.977 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.29 2.743 3-Methylpentane 00096-14-0 1.69 1.95 3.291 2-Methyl-2-butene 00513-35-9 14.20 1.79 25.347 t-2-Pentene 00646-04-8 10.47 1.20 12.564 Benzene 00071-43-2 0.69 0.44 0.309

Total 46.7 118.1 2.531 Vehicle 213b - Fuel 7 psi E10 - 86 ° F Static - Test 7464 Non Zero Mass Species Sorted By VOC

## E

- 141 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 44.26 64.134 Toluene 00108-88-3 3.93 18.17 71.299 n-Hexane 00110-54-3 1.13 6.19 7.025 2-Methylbutane (Isopentane) 00078-78-4 1.35 4.46 6.047 n-Propylbenzene 00103-65-1 1.96 4.44 8.705 Benzene 00071-43-2 0.69 3.67 2.548 Ethylene 00074-85-1 8.88 3.37 29.926 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.07 4.294 2-Methyl-2-butene 00513-35-9 14.20 2.71 38.429 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.62 3.148 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.56 19.822 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.46 13.214 n-Butane 00106-97-8 1.08 2.26 2.439 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.26 16.716 3-Methylpentane 00096-14-0 1.69 2.18 3.679 t-2-Pentene 00646-04-8 10.47 2.03 21.252 n-Pentane 00109-66-0 1.21 1.70 2.066 Cyclohexane 00110-82-7 1.14 1.57 1.786 n-Heptane 00142-82-5 0.97 1.53 1.473 Methylcyclohexane 00108-87-2 1.56 1.41 2.200 2,3-Dimethylbutane 00079-29-8 0.90 1.36 1.226 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.12 4.934 2,3,4-Trimethylpentane 00565-75-3 0.95 1.11 1.057 Cyclopentene 00142-29-0 6.69 0.97 6.504 2,4-Dimethylhexane 00589-43-5 1.61 0.95 1.530 Methylcyclopentane 00096-37-7 2.05 0.92 1.889 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.90 10.600 c-2-Pentene 00627-20-3 10.28 0.90 9.260 2-Methyl-1-butene 00563-46-2 6.38 0.88 5.610 2,2-DiMeHexane 00590-73-8 0.94 0.83 0.786 2-Methylhexane 00591-76-4 1.09 0.83 0.901 Indan 00496-11-7 3.23 0.81 2.610 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.77 4.256 ortho-Xylene 00095-47-6 7.58 0.74 5.628 3-Methylheptane 00589-81-1 1.12 0.73 0.823 t-2-Hexene 04050-45-7 8.55 0.70 5.985 2,3,5-Trimethylhexane 01069-53-0 1.12 0.69 0.776 n-Nonane 00111-84-2 0.68 0.68 0.463 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.65 7.710 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.62 1.003 c-2-Butene 00590-18-1 14.26 0.58 8.304 2,4-Dimethylpentane 00108-08-7 1.46 0.55 0.805 n-Octane 00111-65-9 0.80 0.53 0.424 t-1,2-Dimethylcyclopentane 00822-50-4 3.17 0.52 1.643 Vehicle 213b - Fuel 7 psi E10 - 105 ° F Static - Test 7465 Non Zero Mass Species Sorted By VOC

## E

- 142 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 213b - Fuel 7 psi E10 - 105 ° F Static - Test 7465 Non Zero Mass Species Sorted By VOC

2,3-Dimethylpentane 00565-59-3 1.25 0.51 0.643 3-Methyl-t-2-pentene 00616-12-6 11.66 0.49 5.702 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.47 5.501 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.44 3.509 2-Methylheptane 00592-27-8 0.97 0.43 0.416 c-1,3-Dimethylcyclopentane 02532-58-3 3.17 0.42 1.338 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.41 2.182 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.37 2.651 c-1,3-Dimethylcyclohexane 00638-04-0 3.17 0.36 1.156 2,2-Dimethylpentane 00590-35-2 1.04 0.36 0.378 3-Methyl-c-2-pentene 00922-62-3 12.52 0.30 3.802 2,2,5-Trimethylhexane 03522-94-9 1.05 0.30 0.317 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.30 1.143 2-Methyl-2-pentene 00625-27-4 11.03 0.29 3.180 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.27 0.294 Ethylbenzene 00100-41-4 2.96 0.26 0.777 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.22 1.462 n-Decane 00124-18-5 2.49 0.19 0.479 2,2-Dimethylbutane 00075-83-2 1.11 0.14 0.151 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.07 0.218

Total 138.9 440.2 3.169

No MIR available, use weighted average of 3.1690 

### continued

## E

- 143 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 47.19 68.379 n-Propylbenzene 00103-65-1 1.96 22.51 44.110 Toluene 00108-88-3 3.93 18.46 72.447 2-Methylbutane (Isopentane) 00078-78-4 1.35 15.85 21.474 n-Butane 00106-97-8 1.08 14.36 15.469 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 8.24 44.223 n-Hexane 00110-54-3 1.13 7.72 8.755 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 6.57 76.868 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.85 43.177 n-Pentane 00109-66-0 1.21 5.52 6.706 Methylcyclopentane 00096-37-7 2.05 5.03 10.302 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.28 5.127 1,3,5-Trimethylbenzene 00108-67-8 11.75 3.91 45.905 Benzene 00071-43-2 0.69 3.90 2.708 3-Methylpentane 00096-14-0 1.69 3.60 6.089 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.51 27.847 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.45 4.824 t-2-Butene 00624-64-6 15.20 3.40 51.712 2-Methyl-2-butene 00513-35-9 14.20 3.36 47.725 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.17 13.935 Methylcyclohexane 00108-87-2 1.56 3.01 4.681 t-2-Pentene 00646-04-8 10.47 2.95 30.924 2,3-Dimethylbutane 00079-29-8 0.90 2.83 2.543 2,3,4-Trimethylpentane 00565-75-3 0.95 2.76 2.617 Cyclohexane 00110-82-7 1.14 2.51 2.858 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.41 18.705 2-Methylheptane 00592-27-8 0.97 2.36 2.286 c-2-Pentene 00627-20-3 10.28 2.31 23.709 Ethylbenzene 00100-41-4 2.96 2.13 6.319 2,2-DiMeHexane 00590-73-8 0.94 2.10 1.981 n-Octane 00111-65-9 0.80 2.08 1.656 n-Nonane 00111-84-2 0.68 1.99 1.361 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.97 6.275 n-Heptane 00142-82-5 0.97 1.94 1.877 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.92 10.624 2-Methyl-1-butene 00563-46-2 6.38 1.88 11.960 2,4-Dimethylpentane 00108-08-7 1.46 1.47 2.152 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.47 9.684 n-Decane 00124-18-5 0.59 1.44 0.849 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.42 1.554 3-Methyl-c-2-pentene 00922-62-3 12.52 1.40 17.563 3-Methylheptane 00589-81-1 1.12 1.31 1.477 ortho-Xylene 00095-47-6 7.58 1.29 9.761 1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.28 9.098 Vehicle 213b - Fuel 7 psi E10 - Dynamic - Test 25754 Non Zero Mass Species Sorted By VOC

## E

- 144 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 213b - Fuel 7 psi E10 - Dynamic - Test 25754 Non Zero Mass Species Sorted By VOC

1,2,3-Trimethylbenzene 00526-73-8 11.94 1.28 15.258 2-Methyl-1,3-butadiene 00078-79-5 10.48 1.21 12.730 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.21 1.940 2,3,5-Trimethylhexane 01069-53-0 1.12 1.16 1.297 2,2,5-Trimethylhexane 03522-94-9 1.05 1.14 1.196 2-Methylhexane 00591-76-4 1.09 1.13 1.229 2,4-Dimethylhexane 00589-43-5 1.61 1.13 1.807 c-2-Butene 00590-18-1 14.26 1.10 15.662 3-Methyl-t-2-pentene 00616-12-6 11.66 0.69 8.057 Cyclopentene 00142-29-0 6.69 0.67 4.479 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.65 3.440 2-Methyl-2-pentene 00625-27-4 11.03 0.63 6.931 t-2-Hexene 04050-45-7 8.55 0.46 3.938 2,3-Dimethylpentane 00565-59-3 1.25 0.38 0.480 Indan 00496-11-7 3.23 0.26 0.828 2,2-Dimethylbutane 00075-83-2 1.11 0.15 0.172

Total 251.3 879.7 3.500 

### continued

## E

- 145 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 395.89 573.641 Toluene 00108-88-3 3.93 94.26 369.982 2-Methylbutane (Isopentane) 00078-78-4 1.35 88.04 119.281 n-Hexane 00110-54-3 1.13 70.01 79.440 1,3-Butadiene 00106-99-0 12.45 45.50 566.676 Unknown #2 3.44 41.56 142.858 2-Methyl-1-butene 00563-46-2 6.38 37.14 236.925 1-Methylcyclopentene 00693-89-0 12.45 31.23 388.904 3-Methylpentane 00096-14-0 1.69 28.27 47.799 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 26.08 31.278 2-Methyl-2-butene 00513-35-9 14.20 23.92 339.483 2-Methyl-1,3-butadiene 00078-79-5 10.48 21.51 225.440 Methylcyclopentane 00096-37-7 2.05 19.90 40.784 Cyclohexane 00110-82-7 1.14 18.54 21.082 Cyclopentane 00287-92-3 2.24 18.49 41.375 2,2-Dimethylpropane 00463-82-1 0.65 12.80 8.272 Methylcyclohexane 00108-87-2 1.56 11.70 18.206 3,3-Dimethyl-1-butene 00558-37-2 5.68 11.27 64.059 2-Methylhexane 00591-76-4 1.09 10.68 11.584 2,3,4-Trimethylpentane 00565-75-3 0.95 10.31 9.780 n-Heptane 00142-82-5 0.97 9.67 9.337 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 9.46 30.194 2,4-Dimethylpentane 00108-08-7 1.46 8.44 12.310 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 7.58 88.759 t-2-Hexene 04050-45-7 8.55 6.94 59.321 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.90 53.491 2,3-Dimethylpentane 00565-59-3 1.25 5.74 7.167 2,2-DiMeHexane 00590-73-8 0.94 5.53 5.204 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 5.29 28.010 2-Methylpropane 00075-28-5 1.18 5.24 6.168 2,4-Dimethylhexane 00589-43-5 1.61 5.17 8.301 1-Butyne 00107-00-6 6.05 5.05 30.569 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 4.89 21.466 3-Methyl-c-2-pentene 00922-62-3 12.52 4.86 60.816 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.69 37.221 n-Octane 00111-65-9 0.80 4.64 3.692 Cyclopentene 00142-29-0 6.69 4.16 27.845 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.15 27.435 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 3.98 6.384 2-Methyl-2-pentene 00625-27-4 11.03 3.96 43.704 2,2,5-Trimethylhexane 03522-94-9 1.05 3.43 3.610 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.37 18.074 Propane 00074-98-6 0.46 3.19 1.459 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.74 2.989 Vehicle 213b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7473 Non Zero Mass Species Sorted By VOC

## E

- 146 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 213b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7473 Non Zero Mass Species Sorted By VOC

2,3,5-Trimethylhexane 01069-53-0 1.12 2.52 2.817 t-1,2-Dimethylcyclopentane 00822-50-4 3.44 2.33 8.004 2-Methylheptane 00592-27-8 0.97 2.21 2.137 3-Methylheptane 00589-81-1 1.12 2.01 2.263 2,2-Dimethylpentane 00590-35-2 1.04 1.88 1.962 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.81 21.240 c-1,3-Dimethylcyclopentane 02532-58-3 3.44 1.79 6.154 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.73 10.022 ortho-Xylene 00095-47-6 7.58 1.69 12.769 c-1,3-Dimethylcyclohexane 00638-04-0 3.44 1.68 5.775 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.47 8.143 Cyclopentadiene 00542-92-7 6.89 1.44 9.933 3,3-Dimethylpentane 00562-49-2 1.12 1.42 1.583 3,5-Dimethylheptane 00926-82-9 1.42 1.38 1.964 2,2,3-Trimethylbutane 00464-06-2 1.05 1.26 1.333 Ethylbenzene 00100-41-4 2.96 1.18 3.492 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.18 9.231 n-Decane 00124-18-5 0.59 1.13 0.666 Unknown #17 3.44 0.97 3.328 t-2-Nonene 06434-78-2 3.44 0.92 3.150 4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 0.85 3.737 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.84 3.260 4-Methyloctane 02216-34-4 0.85 0.78 0.662 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.77 5.697 t-1,4-Dimethylcyclohexane 02207-04-7 3.44 0.68 2.348 3,3-Dimethylhexane 00563-16-6 1.15 0.64 0.733 Unknown #5 3.44 0.63 2.172 c-2-Heptene 06443-92-1 7.08 0.60 4.229 1,4-Diethylbenzene 00105-05-5 4.39 0.59 2.596 Isobutylbenzene 00538-93-2 3.44 0.57 1.966 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.44 0.54 1.846 Unknown #8 3.44 0.50 1.733 2,4-Dimethylheptane 02213-23-2 1.26 0.47 0.601 1-Nonene 00124-11-8 2.49 0.40 1.001 t-3-Heptene 14686-14-7 6.17 0.28 1.727 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.22 1.415

Total 1187.5 4082.1 3.438

No MIR available, use weighted average of 3.4375 

### continued

## E

- 147 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 4.25 16.673 2-Methylbutane (Isopentane) 00078-78-4 1.35 3.29 4.456 n-Butane 00106-97-8 1.08 3.08 3.312 Cyclohexane 00110-82-7 1.14 2.13 2.418 Ethanol 00064-17-5 1.45 1.68 2.437 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.18 5.167 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.09 1.528 n-Hexane 00110-54-3 1.13 0.97 1.097 2,3-Dimethylbutane 00079-29-8 0.90 0.88 0.794 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.86 1.035 2-Methyl-2-butene 00513-35-9 14.20 0.79 11.210 2,4-Dimethylhexane 00589-43-5 1.61 0.68 1.095 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.59 3.258 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.56 3.025 3-Methylpentane 00096-14-0 1.69 0.52 0.878 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.51 5.963 Benzene 00071-43-2 0.69 0.50 0.345 c-2-Pentene 00627-20-3 10.28 0.49 5.089 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.48 3.687 2,2,5-Trimethylhexane 03522-94-9 1.05 0.44 0.465 n-Propylbenzene 00103-65-1 1.96 0.44 0.858 2,3,4-Trimethylpentane 00565-75-3 0.95 0.44 0.415 n-Pentane 00109-66-0 1.21 0.42 0.507 Methylcyclopentane 00096-37-7 2.05 0.42 0.852 2,3,5-Trimethylhexane 01069-53-0 1.12 0.39 0.432 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.38 2.805 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.33 0.355 c-2-Butene 00590-18-1 14.26 0.31 4.361 t-2-Hexene 04050-45-7 8.55 0.30 2.583 t-2-Pentene 00646-04-8 10.47 0.29 3.087 Methylcyclohexane 00108-87-2 1.56 0.26 0.402 2-Methyl-1-butene 00563-46-2 6.38 0.24 1.525 3-Methyl-t-2-pentene 00616-12-6 11.66 0.24 2.768 ortho-Xylene 00095-47-6 7.58 0.24 1.781 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.23 0.721 Cyclopentene 00142-29-0 6.69 0.22 1.481 2,3-Dimethylpentane 00565-59-3 1.25 0.19 0.241 t-2-Butene 00624-64-6 15.20 0.18 2.704 2-Methylhexane 00591-76-4 1.09 0.14 0.149 Ethylbenzene 00100-41-4 2.96 0.10 0.283 2,4-Dimethylpentane 00108-08-7 1.46 0.04 0.064

Total 30.7 102.3 3.329 Vehicle 213b - Fuel 9 psi E0 - 86 ° F Static - Test 7506 Non Zero Mass Species Sorted By VOC

## E

- 148 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 9.69 38.049 n-Propylbenzene 00103-65-1 1.96 7.64 14.968 n-Butane 00106-97-8 1.08 5.48 5.902 2-Methylbutane (Isopentane) 00078-78-4 1.35 5.03 6.817 Cyclohexane 00110-82-7 1.14 4.65 5.285 3-Methylnonane 05911-04-6 0.66 3.79 2.486 n-Hexane 00110-54-3 1.13 2.83 3.214 2,2-DiMeHexane 00590-73-8 0.94 1.76 1.654 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.55 2.169 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.51 1.813 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.39 10.230 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.31 10.155 2-Methyl-2-butene 00513-35-9 14.20 1.29 18.309 Benzene 00071-43-2 0.69 1.26 0.873 3-Methylpentane 00096-14-0 1.69 1.25 2.112 t-2-Pentene 00646-04-8 10.47 1.10 11.491 n-Pentane 00109-66-0 1.21 1.09 1.324 2,3,4-Trimethylpentane 00565-75-3 0.95 0.99 0.937 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.94 11.016 Methylcyclopentane 00096-37-7 2.05 0.69 1.405 c-2-Pentene 00627-20-3 10.28 0.63 6.438 n-Heptane 00142-82-5 0.97 0.44 0.426 2-Methylhexane 00591-76-4 1.09 0.43 0.472 ortho-Xylene 00095-47-6 7.58 0.37 2.828 t-2-Hexene 04050-45-7 8.55 0.36 3.107 2-Methyl-1-butene 00563-46-2 6.38 0.34 2.185 3-Methyl-t-2-pentene 00616-12-6 11.66 0.26 3.088 2,4-Dimethylpentane 00108-08-7 1.46 0.23 0.340 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.18 2.114 2,3-Dimethylpentane 00565-59-3 1.25 0.14 0.172 c-2-Butene 00590-18-1 14.26 0.10 1.450 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.04 0.135

Total 58.8 173.0 2.943 Vehicle 213b - Fuel 9 psi E0 - 105 ° F Static - Test 7507 Non Zero Mass Species Sorted By VOC

## E

- 149 Species CAS No. MIR Composite VOC

mg Ozone mg Cyclohexane 00110-82-7 1.14 10.76 12.234 Toluene 00108-88-3 3.93 9.38 36.829 n-Hexane 00110-54-3 1.13 5.02 5.696 2-Methylbutane (Isopentane) 00078-78-4 1.35 4.78 6.470 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 4.64 5.565 2,2,5-Trimethylhexane 03522-94-9 1.05 3.99 4.205 Methane 00074-82-8 0.01 3.99 0.055 2,3,5-Trimethylhexane 01069-53-0 1.12 3.95 4.424 Benzene 00071-43-2 0.69 3.77 2.620 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 3.75 27.705 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.58 27.777 t-2-Pentene 00646-04-8 10.47 3.17 33.177 n-Butane 00106-97-8 1.08 3.15 3.387 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.95 4.126 Ethylbenzene 00100-41-4 2.96 2.90 8.585 2,3,4-Trimethylpentane 00565-75-3 0.95 2.71 2.572 Ethanol 00064-17-5 1.45 2.38 3.441 2,2-DiMeHexane 00590-73-8 0.94 2.24 2.110 2,4-Dimethylpentane 00108-08-7 1.46 2.15 3.135 Methylcyclopentane 00096-37-7 2.05 2.15 4.401 t-2-Hexene 04050-45-7 8.55 2.00 17.095 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.88 14.920 n-Pentane 00109-66-0 1.21 1.79 2.169 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.58 8.739 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.55 8.339 2-Methyl-2-butene 00513-35-9 14.20 1.54 21.867 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.48 4.730 3-Methyl-t-2-pentene 00616-12-6 11.66 1.45 16.934 Methylcyclohexane 00108-87-2 1.56 1.36 2.113 2,3-Dimethylpentane 00565-59-3 1.25 1.18 1.475 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.15 5.039 n-Heptane 00142-82-5 0.97 0.97 0.934 ortho-Xylene 00095-47-6 7.58 0.46 3.474 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.42 4.898 2-Methyl-1-butene 00563-46-2 6.38 0.39 2.491 2-Methylhexane 00591-76-4 1.09 0.39 0.420 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.36 0.572 2,3-Dimethylbutane 00079-29-8 0.90 0.04 0.039

Total 101.4 314.8 3.105 Vehicle 213b - Fuel 9 psi E0 - Dynamic - Test 25764 Non Zero Mass Species Sorted By VOC

## E

- 150 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 137.80 148.404 2-Methylbutane (Isopentane) 00078-78-4 1.35 122.64 166.167 Toluene 00108-88-3 3.93 78.85 309.495 Cyclohexane 00110-82-7 1.14 72.52 82.482 Ethanol 00064-17-5 1.45 44.76 64.855 n-Hexane 00110-54-3 1.13 43.02 48.814 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 33.34 46.607 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 26.47 31.744 3-Methylpentane 00096-14-0 1.69 22.16 37.466 Benzene 00071-43-2 0.69 19.39 13.466 n-Pentane 00109-66-0 1.21 18.25 22.172 2-Methyl-2-butene 00513-35-9 14.20 17.16 243.526 2,3-Dimethylbutane 00079-29-8 0.90 16.32 14.665 Methylcyclopentane 00096-37-7 2.05 15.20 31.158 t-2-Pentene 00646-04-8 10.47 14.13 148.012 2,3,4-Trimethylpentane 00565-75-3 0.95 10.22 9.699 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.44 65.490 2,4-Dimethylpentane 00108-08-7 1.46 8.30 12.111 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.88 58.216 2-Methylhexane 00591-76-4 1.09 7.73 8.392 2,2-DiMeHexane 00590-73-8 0.94 7.32 6.894 2-Methyl-1-butene 00563-46-2 6.38 7.03 44.865 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 7.01 22.361 c-2-Pentene 00627-20-3 10.28 6.77 69.601 2,3-Dimethylpentane 00565-59-3 1.25 6.08 7.595 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 4.80 56.150 2,4-Dimethylhexane 00589-43-5 1.61 4.79 7.698 t-2-Hexene 04050-45-7 8.55 4.70 40.186 3-Methyl-t-2-pentene 00616-12-6 11.66 4.53 52.798 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.41 34.991 3-Methyl-c-2-pentene 00922-62-3 12.52 4.19 52.429 n-Heptane 00142-82-5 0.97 4.12 3.978 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.12 6.610 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.91 20.696 2,2,5-Trimethylhexane 03522-94-9 1.05 3.48 3.664 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.31 17.751 2-Methyl-2-pentene 00625-27-4 11.03 3.30 36.401 Cyclopentene 00142-29-0 6.69 3.26 21.774 1-Methylcyclopentene 00693-89-0 12.45 3.11 38.790 Methylcyclohexane 00108-87-2 1.56 3.10 4.829 c-2-Butene 00590-18-1 14.26 3.02 43.106 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 3.01 19.864 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.51 2.740 ortho-Xylene 00095-47-6 7.58 2.24 16.957 Vehicle 213b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7516 Non Zero Mass Species Sorted By VOC

## E

- 151 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 213b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7516 Non Zero Mass Species Sorted By VOC

Ethylbenzene 00100-41-4 2.96 1.81 5.362 t-1,2-Dimethylcyclopentane 00822-50-4 2.68 1.75 4.696 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.70 7.485 2,3,5-Trimethylhexane 01069-53-0 1.12 1.69 1.888 c-1,3-Dimethylcyclopentane 02532-58-3 2.68 1.62 4.325 2,2-Dimethylbutane 00075-83-2 1.11 1.53 1.698 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.49 8.626 Propane 00074-98-6 0.46 1.42 0.648 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.34 7.434 3-Methylheptane 00589-81-1 1.12 1.33 1.490 2-Methylheptane 00592-27-8 0.97 1.21 1.166 2,2-Dimethylpentane 00590-35-2 1.04 1.18 1.236 c-1,3-Dimethylcyclohexane 00638-04-0 2.68 1.18 3.171 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.17 13.745 n-Octane 00111-65-9 0.80 1.12 0.895 2-Methylpropane 00075-28-5 1.18 1.10 1.292 2,2,3-Trimethylbutane 00464-06-2 1.05 1.03 1.086 3,3-Dimethylpentane 00562-49-2 1.12 0.86 0.961 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.86 6.732 c-2-Heptene 06443-92-1 7.08 0.73 5.139 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.62 7.440 Unknown #5 2.68 0.52 1.400 t-3-Heptene 14686-14-7 6.17 0.52 3.219 4-Methyl-t-2-pentene 00674-76-0 8.04 0.49 3.951 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.43 1.658 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.34 3.568 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.30 2.155 2,4-Dimethylheptane 02213-23-2 1.26 0.28 0.356 Methane 00074-82-8 0.01 0.25 0.003

Total 858.6 2298.5 2.677

No MIR available, use weighted average of 2.6770 

### continued

## E

- 152 Species CAS No. MIR Composite VOC

mg Ozone mg n-Propylbenzene 00103-65-1 1.96 4.66 9.129 n-Butane 00106-97-8 1.08 4.48 4.821 Ethanol 00064-17-5 1.45 3.43 4.964 Toluene 00108-88-3 3.93 3.30 12.936 2-Methylbutane (Isopentane) 00078-78-4 1.35 2.46 3.328 Cyclohexane 00110-82-7 1.14 1.90 2.160 n-Hexane 00110-54-3 1.13 1.25 1.414 Benzene 00071-43-2 0.69 1.08 0.751 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.94 1.320 Methylcyclopentane 00096-37-7 2.05 0.90 1.847 2,3-Dimethylbutane 00079-29-8 0.90 0.87 0.780 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.86 6.636 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.76 0.834 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.70 4.642 2-Methyl-2-butene 00513-35-9 14.20 0.55 7.769 t-2-Hexene 04050-45-7 8.55 0.54 4.631 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.48 2.113 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.46 5.429 Indan 00496-11-7 3.23 0.45 1.453 2,4-Dimethylpentane 00108-08-7 1.46 0.45 0.655 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.44 2.354 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.38 0.455 3-Methyl-c-2-pentene 00922-62-3 12.52 0.37 4.633 2,3,5-Trimethylhexane 01069-53-0 1.12 0.36 0.405 2-Methyl-1-butene 00563-46-2 6.38 0.36 2.292 2,3,4-Trimethylpentane 00565-75-3 0.95 0.36 0.338 c-2-Pentene 00627-20-3 10.28 0.31 3.183 c-2-Butene 00590-18-1 14.26 0.27 3.862 n-Pentane 00109-66-0 1.21 0.27 0.325 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.27 0.429 Ethylbenzene 00100-41-4 2.96 0.22 0.656 2-Methylhexane 00591-76-4 1.09 0.22 0.238 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.21 2.505 Cyclopentene 00142-29-0 6.69 0.19 1.293 t-2-Pentene 00646-04-8 10.47 0.19 1.969 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.17 0.542 ortho-Xylene 00095-47-6 7.58 0.10 0.752 2,3-Dimethylpentane 00565-59-3 1.25 0.09 0.109

Total 35.3 104.0 2.947 Vehicle 213b - Fuel 7 psi E0 - 86 ° F Static - Test 7526 Non Zero Mass Species Sorted By VOC

## E

- 153 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 9.49 37.259 2-Methylbutane (Isopentane) 00078-78-4 1.35 6.08 8.236 Cyclohexane 00110-82-7 1.14 5.90 6.710 n-Butane 00106-97-8 1.08 5.83 6.273 Ethanol 00064-17-5 1.45 4.29 6.213 n-Hexane 00110-54-3 1.13 3.00 3.407 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.47 3.453 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.11 2.533 Benzene 00071-43-2 0.69 2.09 1.454 2-Methyl-2-butene 00513-35-9 14.20 1.84 26.133 Methylcyclopentane 00096-37-7 2.05 1.71 3.507 3-Methyl-c-2-pentene 00922-62-3 12.52 1.63 20.410 2,3-Dimethylbutane 00079-29-8 0.90 1.61 1.446 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.55 12.007 3-Methylpentane 00096-14-0 1.69 1.54 2.599 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.22 6.570 t-2-Pentene 00646-04-8 10.47 1.15 12.044 n-Pentane 00109-66-0 1.21 1.13 1.375 2,3,4-Trimethylpentane 00565-75-3 0.95 1.11 1.057 ortho-Xylene 00095-47-6 7.58 0.98 7.435 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.89 10.685 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.86 10.162 2,4-Dimethylpentane 00108-08-7 1.46 0.84 1.230 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.79 3.451 c-2-Pentene 00627-20-3 10.28 0.78 8.015 Ethylbenzene 00100-41-4 2.96 0.76 2.250 t-2-Hexene 04050-45-7 8.55 0.65 5.594 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.65 3.576 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.64 0.700 3-Methyl-t-2-pentene 00616-12-6 11.66 0.62 7.254 2-Methyl-1-butene 00563-46-2 6.38 0.51 3.280 2-Methylhexane 00591-76-4 1.09 0.51 0.553 2,2-DiMeHexane 00590-73-8 0.94 0.46 0.437 2,3-Dimethylpentane 00565-59-3 1.25 0.43 0.540 2-Methyl-2-pentene 00625-27-4 11.03 0.42 4.675 Cyclopentene 00142-29-0 6.69 0.41 2.729 Methylcyclohexane 00108-87-2 1.56 0.40 0.620 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.39 2.587 n-Heptane 00142-82-5 0.97 0.36 0.352 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.36 4.181 2,3,5-Trimethylhexane 01069-53-0 1.12 0.33 0.367 c-2-Butene 00590-18-1 14.26 0.30 4.335 2-Methylheptane 00592-27-8 0.97 0.27 0.264 2,4-Dimethylhexane 00589-43-5 1.61 0.27 0.437 Vehicle 213b - Fuel 7 psi E0 - 105 ° F Static - Test 7528 Non Zero Mass Species Sorted By VOC

## E

- 154 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 213b - Fuel 7 psi E0 - 105 ° F Static - Test 7528 Non Zero Mass Species Sorted By VOC

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.27 1.421 2,2,5-Trimethylhexane 03522-94-9 1.05 0.26 0.269 n-Propylbenzene 00103-65-1 1.96 0.25 0.489 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.23 0.734 2,2-Dimethylbutane 00075-83-2 1.11 0.16 0.176 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.15 0.240

Total 71.0 251.7 3.546 

### continued

## E

- 155 Species CAS No. MIR Composite VOC

mg Ozone mg n-Propylbenzene 00103-65-1 1.96 11.71 22.952 Toluene 00108-88-3 3.93 9.41 36.935 n-Butane 00106-97-8 1.08 7.85 8.449 2-Methylbutane (Isopentane) 00078-78-4 1.35 7.14 9.672 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.94 21.177 n-Hexane 00110-54-3 1.13 3.84 4.352 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.80 20.688 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 2.76 32.264 n-Pentane 00109-66-0 1.21 2.64 3.209 Methylcyclopentane 00096-37-7 2.05 2.27 4.653 Benzene 00071-43-2 0.69 2.10 1.460 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.96 2.346 t-2-Butene 00624-64-6 15.20 1.84 27.977 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.78 20.918 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.69 2.357 3-Methylpentane 00096-14-0 1.69 1.58 2.665 2,3-Dimethylbutane 00079-29-8 0.90 1.53 1.376 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.52 12.081 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.48 6.521 2-Methyl-2-butene 00513-35-9 14.20 1.46 20.689 Methylcyclohexane 00108-87-2 1.56 1.29 2.005 t-2-Pentene 00646-04-8 10.47 1.19 12.424 2,3,4-Trimethylpentane 00565-75-3 0.95 1.11 1.049 Cyclohexane 00110-82-7 1.14 1.08 1.228 Ethylbenzene 00100-41-4 2.96 1.08 3.194 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.02 7.946 n-Octane 00111-65-9 0.80 1.02 0.813 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.00 3.205 n-Heptane 00142-82-5 0.97 1.00 0.965 2-Methylheptane 00592-27-8 0.97 0.96 0.926 c-2-Pentene 00627-20-3 10.28 0.94 9.631 2-Methyl-1-butene 00563-46-2 6.38 0.89 5.655 2,2-DiMeHexane 00590-73-8 0.94 0.86 0.811 n-Nonane 00111-84-2 0.68 0.82 0.558 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.79 4.358 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.78 5.147 3-Methyl-c-2-pentene 00922-62-3 12.52 0.75 9.435 n-Decane 00124-18-5 0.59 0.74 0.440 3-Methylheptane 00589-81-1 1.12 0.69 0.773 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.65 4.618 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.64 1.023 2,4-Dimethylpentane 00108-08-7 1.46 0.64 0.928 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.63 7.550 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.62 0.675 Vehicle 213b - Fuel 7 psi E0 - Dynamic - Test 25769 Non Zero Mass Species Sorted By VOC

## E

- 156 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 213b - Fuel 7 psi E0 - Dynamic - Test 25769 Non Zero Mass Species Sorted By VOC

2,4-Dimethylhexane 00589-43-5 1.61 0.61 0.984 2,3,5-Trimethylhexane 01069-53-0 1.12 0.61 0.679 ortho-Xylene 00095-47-6 7.58 0.54 4.120 c-2-Butene 00590-18-1 14.26 0.52 7.407 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.51 5.337 2-Methylhexane 00591-76-4 1.09 0.50 0.541 2,2,5-Trimethylhexane 03522-94-9 1.05 0.49 0.515 3-Methyl-t-2-pentene 00616-12-6 11.66 0.35 4.110 2-Methyl-2-pentene 00625-27-4 11.03 0.29 3.219 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.29 1.528 Cyclopentene 00142-29-0 6.69 0.29 1.924 t-2-Hexene 04050-45-7 8.55 0.23 1.967 2,3-Dimethylpentane 00565-59-3 1.25 0.21 0.262 Indan 00496-11-7 3.23 0.11 0.345 2,2-Dimethylbutane 00075-83-2 1.11 0.08 0.092

Total 98.1 381.1 3.885 

### continued

## E

- 157 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 127.04 172.118 Toluene 00108-88-3 3.93 123.83 486.039 Cyclohexane 00110-82-7 1.14 79.53 90.453 n-Butane 00106-97-8 1.08 74.55 80.280 n-Hexane 00110-54-3 1.13 43.71 49.595 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 34.55 48.288 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 28.63 34.327 3-Methylpentane 00096-14-0 1.69 23.32 39.423 Ethanol 00064-17-5 1.45 22.08 31.989 Benzene 00071-43-2 0.69 20.03 13.907 n-Pentane 00109-66-0 1.21 18.79 22.825 2-Methyl-2-butene 00513-35-9 14.20 17.74 251.830 2,3-Dimethylbutane 00079-29-8 0.90 17.30 15.547 Methylcyclopentane 00096-37-7 2.05 15.61 31.988 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 14.87 115.305 t-2-Pentene 00646-04-8 10.47 14.54 152.271 2,3,4-Trimethylpentane 00565-75-3 0.95 11.41 10.825 Ethylbenzene 00100-41-4 2.96 7.97 23.619 2,4-Dimethylpentane 00108-08-7 1.46 7.96 11.622 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 7.62 56.265 2-Methylhexane 00591-76-4 1.09 7.54 8.184 c-2-Pentene 00627-20-3 10.28 7.23 74.294 2-Methyl-1-butene 00563-46-2 6.38 6.98 44.505 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 6.60 21.056 2,3-Dimethylpentane 00565-59-3 1.25 6.36 7.943 2,2-DiMeHexane 00590-73-8 0.94 6.30 5.930 2,4-Dimethylhexane 00589-43-5 1.61 5.52 8.857 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.43 29.166 t-2-Hexene 04050-45-7 8.55 5.41 46.249 3-Methyl-c-2-pentene 00922-62-3 12.52 5.37 67.261 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 4.86 56.897 3-Methyl-t-2-pentene 00616-12-6 11.66 4.61 53.718 2,2,5-Trimethylhexane 03522-94-9 1.05 4.57 4.811 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.46 7.153 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 4.42 23.438 ortho-Xylene 00095-47-6 7.58 4.13 31.305 n-Heptane 00142-82-5 0.97 3.89 3.759 1-Methylcyclopentene 00693-89-0 12.45 3.46 43.139 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.37 26.789 c-2-Butene 00590-18-1 14.26 3.33 47.422 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.25 3.554 2-Methyl-2-pentene 00625-27-4 11.03 3.23 35.603 Cyclopentene 00142-29-0 6.69 3.13 20.938 1,3,5-Trimethylbenzene 00108-67-8 11.75 3.08 36.198 Vehicle 213b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7538 Non Zero Mass Species Sorted By VOC

## E

- 158 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 213b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7538 Non Zero Mass Species Sorted By VOC

c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.88 18.998 2,2-Dimethylbutane 00075-83-2 1.11 2.55 2.836 Methylcyclohexane 00108-87-2 1.56 2.53 3.936 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.28 10.024 t-1,2-Dimethylcyclopentane 00822-50-4 2.98 2.08 6.186 c-1,3-Dimethylcyclopentane 02532-58-3 2.98 1.73 5.138 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.56 8.648 n-Propylbenzene 00103-65-1 1.96 1.41 2.767 2-Methylheptane 00592-27-8 0.97 1.38 1.339 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.19 14.151 2,2-Dimethylpentane 00590-35-2 1.04 1.14 1.184 3-Methylheptane 00589-81-1 1.12 1.05 1.183 Styrene 00100-42-5 1.66 1.05 1.742 n-Octane 00111-65-9 0.80 0.92 0.729 3,3-Dimethylpentane 00562-49-2 1.12 0.90 1.007 Unknown #16 2.98 0.89 2.662 c-2-Heptene 06443-92-1 7.08 0.88 6.247 2-Methylpropane 00075-28-5 1.18 0.86 1.008 Methane 00074-82-8 0.01 0.75 0.010 1c-2t-3-TriMeCyPentane 15890-40-1 2.98 0.72 2.141 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.71 5.590 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.71 4.094 2,3,5-Trimethylhexane 01069-53-0 1.12 0.70 0.780 Unknown #5 2.98 0.69 2.056 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.64 2.485 2,2,3-Trimethylbutane 00464-06-2 1.05 0.58 0.615 c-1,3-Dimethylcyclohexane 00638-04-0 2.98 0.49 1.466 2,4-Dimethylheptane 02213-23-2 1.26 0.48 0.612 4-Methyl-t-2-pentene 00674-76-0 8.04 0.44 3.544 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.43 3.053 t-3-Heptene 14686-14-7 6.17 0.38 2.375 1-Nonene 00124-11-8 2.49 0.38 0.938 Unknown #1 2.98 0.36 1.062 Unknown #3 2.98 0.27 0.812 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.26 2.754 Isopropylbenzene (Cumene) 00098-82-8 2.98 0.19 0.572

Total 864.0 2571.4 2.976

No MIR available, use weighted average of 2.9760 

### continued

## E

- 159 Test Fuel Test No. Bag THC mg GC as % of THC GC VOC

mg Ozone mg Reactivity Species Present 86 ° F E10 - 10 psi 7537 21249.9 91.1 19364.6 45551.4 2.352 87 Static E10 - 7 psi 7564 11657.5 81.0 9442.0 28464.0 3.015 96 E0 - 9 psi 7644 24378.7 96.6 23556.0 50039.7 2.124 93 E0 - 7 psi 7677 14347.6 99.7 14299.8 35390.0 2.475 114

105 ° F E10 - 10 psi 7541 36851.0 78.1 28779.5 70524.0 2.450 105 Static E10 - 7 psi 7565 24424.1 91.8 22427.0 66555.4 2.968 127 E0 - 9 psi 7647 44422.3 90.3 40098.4 88163.2 2.199 108 E0 - 7 psi 7680 25952.5 105.4 27348.3 68042.1 2.488 120

Dynamic E10 - 10 psi 25774 180.3 74.0 133.5 501.4 3.756 45 E10 - 7 psi 25781 685.5 64.2 440.2 1445.3 3.283 69 E0 - 9 psi 25789 2388.4 99.7 2380.7 6653.4 2.795 55 E0 - 7 psi 25794 3527.7 104.6 3689.9 12792.2 3.467 114

DHB E10 - 10 psi 7546 5251.6 91.5 4805.1 12517.4 2.605 107 Total E10 - 7 psi 7569 4272.9 91.7 3916.7 11477.1 2.930 125 E0 - 9 psi 7657 19668.0 103.4 20327.8 49439.0 2.432 128 E0 - 7 psi 7686 19475.3 103.9 20242.7 51559.2 2.547 134 

## Vehicle 220b

## E

- 160 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 7504.66 8081.860 2-Methylbutane (Isopentane) 00078-78-4 1.35 3577.47 4847.069 n-Hexane 00110-54-3 1.13 1212.40 1375.686 Ethanol 00064-17-5 1.45 782.86 1134.340 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 696.54 973.617 n-Pentane 00109-66-0 1.21 552.04 670.690 3-Methylpentane 00096-14-0 1.69 486.85 823.208 2-Methyl-2-butene 00513-35-9 14.20 461.55 6551.700 t-2-Pentene 00646-04-8 10.47 380.13 3981.302 Toluene 00108-88-3 3.93 347.37 1363.432 2,3-Dimethylbutane 00079-29-8 0.90 326.18 293.136 2-Methyl-1-butene 00563-46-2 6.38 269.35 1718.089 Methylcyclopentane 00096-37-7 2.05 230.99 473.483 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 229.49 275.190 c-2-Pentene 00627-20-3 10.28 206.83 2126.466 Cyclohexane 00110-82-7 1.14 203.89 231.897 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 160.56 1879.309 c-2-Butene 00590-18-1 14.26 147.02 2096.413 Benzene 00071-43-2 0.69 127.10 88.252 2,4-Dimethylpentane 00108-08-7 1.46 99.66 145.434 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 94.87 753.371 2-Methylhexane 00591-76-4 1.09 81.35 88.280 2-Methylpropane 00075-28-5 1.18 80.49 94.701 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 68.36 362.204 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 68.07 217.192 Methylcyclohexane 00108-87-2 1.56 66.82 103.924 t-2-Hexene 04050-45-7 8.55 64.95 555.280 Cyclopentene 00142-29-0 6.69 59.41 397.197 2,3,4-Trimethylpentane 00565-75-3 0.95 56.98 54.068 3-Methyl-t-2-pentene 00616-12-6 11.66 53.80 627.284 2-Methyl-2-pentene 00625-27-4 11.03 51.40 567.109 2,3-Dimethylpentane 00565-59-3 1.25 49.74 62.087 n-Heptane 00142-82-5 0.97 49.68 47.976 3-Methyl-c-2-pentene 00922-62-3 12.52 45.23 566.173 2,2-Dimethylbutane 00075-83-2 1.11 40.40 44.893 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 39.21 259.025 1-Methylcyclopentene 00693-89-0 12.45 34.02 423.682 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 32.91 190.139 2,4-Dimethylhexane 00589-43-5 1.61 28.80 46.238 2,2-Dimethylpentane 00590-35-2 1.04 25.61 26.714 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 20.29 157.349 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 19.83 31.830 c-1,3-Dimethylcyclopentane 02532-58-3 2.35 16.89 39.737 t-1,2-Dimethylcyclopentane 00822-50-4 2.35 16.30 38.334 Vehicle 220b - Fuel 10 psi E10 - 86 ° F Static - Test 7537 Non Zero Mass Species Sorted By VOC

## E

- 161 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 10 psi E10 - 86 ° F Static - Test 7537 Non Zero Mass Species Sorted By VOC

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 14.61 107.883 2,2,5-Trimethylhexane 03522-94-9 1.05 13.82 14.551 2,2,3-Trimethylbutane 00464-06-2 1.05 12.76 13.445 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 12.18 13.306 n-Octane 00111-65-9 0.80 12.18 9.697 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 10.86 58.288 3,3-Dimethylpentane 00562-49-2 1.12 10.21 11.425 Propane 00074-98-6 0.46 10.13 4.631 2-Methylheptane 00592-27-8 0.97 9.25 8.945 3-Methylheptane 00589-81-1 1.12 8.21 9.232 ortho-Xylene 00095-47-6 7.58 6.03 45.711 c-1,3-Dimethylcyclohexane 00638-04-0 2.35 5.99 14.085 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.53 24.279 2-Methyl-1,3-butadiene 00078-79-5 10.48 4.75 49.801 1,3,5-Trimethylbenzene 00108-67-8 11.75 4.72 55.535 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 4.57 35.840 Ethylbenzene 00100-41-4 2.96 3.93 11.646 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.66 20.279 Unknown #5 2.35 3.52 8.281 n-Propylbenzene 00103-65-1 1.96 2.73 5.354 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 2.70 10.414 3,5-Dimethylheptane 00926-82-9 1.42 2.58 3.679 t-1,4-Dimethylcyclohexane 02207-04-7 2.35 2.48 5.843 Cyclopentadiene 00542-92-7 6.89 2.28 15.738 3,3-Dimethylhexane 00563-16-6 1.15 2.28 2.623 2,3,5-Trimethylhexane 01069-53-0 1.12 2.28 2.551 c-2-Heptene 06443-92-1 7.08 2.07 14.615 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.35 1.90 4.463 t-3-Heptene 14686-14-7 6.17 1.84 11.381 4-Methyloctane 02216-34-4 0.85 1.84 1.558 Unknown #3 2.35 1.53 3.602 1,1-Dimethylcyclohexane 00590-66-9 1.12 1.50 1.669 1-Heptene 00592-76-7 4.29 1.41 6.061 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.29 15.436 n-Nonane 00111-84-2 0.68 1.27 0.870 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.16 7.601 Indan 00496-11-7 3.23 1.06 3.434 Unknown #8 2.35 1.11 2.605 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.98 8.232 1,3-Butadiene 00106-99-0 12.45 0.95 11.792 

### continued

## E

- 162 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 10 psi E10 - 86 ° F Static - Test 7537 Non Zero Mass Species Sorted By VOC

Isopropylbenzene (Cumene) 00098-82-8 2.35 0.76 1.786 1-Nonene 00124-11-8 2.49 0.73 1.828 3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.61 6.001

Total 19364.6 45551.4 2.352

No MIR available, use weighted average of 2.3523 

### continued

## E

- 163 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 10042.39 10814.781 2-Methylbutane (Isopentane) 00078-78-4 1.35 5140.76 6965.156 Ethanol 00064-17-5 1.45 2480.02 3593.485 n-Hexane 00110-54-3 1.13 1267.24 1437.910 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1087.54 1520.153 n-Pentane 00109-66-0 1.21 817.11 992.732 3-Methylpentane 00096-14-0 1.69 765.94 1295.108 2-Methyl-2-butene 00513-35-9 14.20 693.03 9837.500 Toluene 00108-88-3 3.93 600.67 2357.643 t-2-Pentene 00646-04-8 10.47 566.37 5931.860 Unknown #2 2.45 522.26 1279.801 2-Methyl-1-butene 00563-46-2 6.38 394.85 2518.552 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 392.14 470.220 Methylcyclopentane 00096-37-7 2.05 371.24 760.965 Cyclohexane 00110-82-7 1.14 325.07 369.721 c-2-Pentene 00627-20-3 10.28 307.85 3165.135 Benzene 00071-43-2 0.69 261.49 181.568 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 233.60 2734.151 c-2-Butene 00590-18-1 14.26 201.08 2867.390 2,4-Dimethylpentane 00108-08-7 1.46 162.60 237.280 2-Methylhexane 00591-76-4 1.09 136.61 148.251 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 11.57 124.96 1446.257 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 117.89 742.952 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 116.95 373.180 2-Methylpropane 00075-28-5 1.18 108.99 128.237 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 106.17 562.535 t-2-Hexene 04050-45-7 8.55 104.25 891.181 2,3,3-Trimethylpentane 00560-21-4 0.95 101.38 95.875 Cyclopentene 00142-29-0 6.69 89.79 600.341 3-Methyl-t-2-pentene 00616-12-6 11.66 86.47 1008.195 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 86.47 677.498 2,3-Dimethylpentane 00565-59-3 1.25 83.74 104.538 2-Methyl-2-pentene 00625-27-4 11.03 81.66 900.965 3-Methyl-c-2-pentene 00922-62-3 12.52 72.79 911.149 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 62.18 410.779 2,2-Dimethylbutane 00075-83-2 1.11 60.00 66.675 2,4-Dimethylhexane 00589-43-5 1.61 50.58 81.214 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 50.28 290.496 2,2-Dimethylpentane 00590-35-2 1.04 41.61 43.399 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 37.40 290.019 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 36.11 57.969 t-1,2-Dimethylcyclopentane 00822-50-4 2.45 26.43 64.767 1-Octene 00111-66-0 3.14 25.94 81.498 n-Octane 00111-65-9 0.80 23.96 19.078 Vehicle 220b - Fuel 10 psi E10 - 105 ° F Static - Test 7541 Non Zero Mass Species Sorted By VOC

## E

- 164 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 10 psi E10 - 105 ° F Static - Test 7541 Non Zero Mass Species Sorted By VOC

c-1,3-Dimethylcyclopentane 02532-58-3 2.45 21.80 53.413 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 21.45 23.422 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 20.78 111.546 2,2,3-Trimethylbutane 00464-06-2 1.05 20.40 21.497 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 19.80 146.249 3,3-Dimethylpentane 00562-49-2 1.12 17.86 19.980 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 15.75 60.864 3-Methylheptane 00589-81-1 1.12 13.90 15.632 Propane 00074-98-6 0.46 12.19 5.574 ortho-Xylene 00095-47-6 7.58 10.98 83.193 t-1,4-Dimethylcyclohexane 02207-04-7 2.45 10.73 26.306 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 9.65 42.401 1,3,5-Trimethylbenzene 00108-67-8 11.75 8.40 98.793 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 7.15 39.641 2-Methyl-1,3-butadiene 00078-79-5 10.48 6.95 72.810 Ethylbenzene 00100-41-4 2.96 6.94 20.556 3,5-Dimethylheptane 00926-82-9 1.42 6.52 9.276 1-Methylcyclopentene 00693-89-0 12.45 5.20 64.751 n-Propylbenzene 00103-65-1 1.96 5.04 9.868 Unknown #5 2.45 4.36 10.676 3,3-Dimethylhexane 00563-16-6 1.15 4.30 4.953 c-2-Heptene 06443-92-1 7.08 3.54 25.084 2,3,5-Trimethylhexane 01069-53-0 1.12 3.23 3.617 1,2,3-Trimethylbenzene 00526-73-8 11.94 3.00 35.865 t-3-Heptene 14686-14-7 6.17 2.91 17.948 1,1-Dimethylcyclohexane 00590-66-9 1.12 2.75 3.071 4-Methyloctane 02216-34-4 0.85 2.75 2.332 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.45 2.74 6.710 n-Nonane 00111-84-2 0.68 2.67 1.825 Cyclopentadiene 00542-92-7 6.89 2.65 18.246 Unknown #8 2.45 2.58 6.333 2,4-Dimethylheptane 02213-23-2 1.26 2.13 2.699 Unknown #16 2.45 1.95 4.785 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.93 12.615 3-Methyloctane 02216-33-3 0.88 1.93 1.704 Unknown #3 2.45 1.89 4.638 Unknown #13 2.45 1.82 4.448 1-Heptene 00592-76-7 4.29 1.71 7.327 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 1.66 1.415 t-4-Octene 14850-23-8 4.69 1.62 7.615 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.62 13.589 Isopropylbenzene (Cumene) 00098-82-8 2.45 1.43 3.504 

### continued

## E

- 165 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 10 psi E10 - 105 ° F Static - Test 7541 Non Zero Mass Species Sorted By VOC

1,3-Butadiene 00106-99-0 12.45 1.42 17.743 1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.36 9.664 1-Nonene 00124-11-8 2.49 1.33 3.326 Unknown #9 2.45 1.17 2.861 Indan 00496-11-7 3.23 1.07 3.455 1,4-Diethylbenzene 00105-05-5 4.39 0.99 4.351 3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.88 8.637 n-Decane 00124-18-5 0.59 0.82 0.483 2-Methylheptane 00592-27-8 0.97 0.71 0.684 1-Butyne 00107-00-6 6.05 0.70 4.251 2,2-Dimethyloctane 15869-87-1 0.76 0.59 0.444 c-2-Octene 07642-04-8 2.45 0.55 1.352 c- & t-4-Nonene 02198-23-4 4.42 0.52 2.293 Unknown #7 2.45 0.51 1.261 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.49 3.688 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 0.48 0.571 t-2-Nonene 06434-78-2 2.45 0.48 1.165 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.47 1.798 sec-Butylbenzene 00135-98-8 2.29 0.44 1.019

Total 28779.5 70524.0 2.450

No MIR available, use weighted average of 2.4505 

### continued

## E

- 166 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 20.69 81.203 n-Hexane 00110-54-3 1.13 15.30 17.365 Ethanol 00064-17-5 1.45 8.67 12.564 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.36 39.529 2,3,3-Trimethylpentane 00560-21-4 0.95 6.54 6.186 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 6.16 7.382 Unknown #2 3.76 5.52 20.733 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 4.69 20.624 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.34 33.634 1,3,5-Trimethylbenzene 00108-67-8 11.75 4.26 50.132 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 3.92 30.725 Unknown #23 3.76 3.61 13.563 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 3.39 21.348 1-Octene 00111-66-0 3.14 2.87 9.017 Benzene 00071-43-2 0.69 2.23 1.546 Cyclohexane 00110-82-7 1.14 2.16 2.459 3-Methylheptane 00589-81-1 1.12 2.01 2.256 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.88 2.048 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.81 21.618 2,4-Dimethylhexane 00589-43-5 1.61 1.76 2.818 ortho-Xylene 00095-47-6 7.58 1.69 12.817 2-Methyl-2-butene 00513-35-9 14.20 1.60 22.727 n-Propylbenzene 00103-65-1 1.96 1.54 3.011 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.50 8.318 3-Methylpentane 00096-14-0 1.69 1.42 2.398 n-Butane 00106-97-8 1.08 1.39 1.496 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.30 2.080 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.29 1.802 2-Methylhexane 00591-76-4 1.09 1.18 1.279 Ethylbenzene 00100-41-4 2.96 1.14 3.363 t-2-Pentene 00646-04-8 10.47 1.13 11.783 Methylcyclopentane 00096-37-7 2.05 1.07 2.194 Methane 00074-82-8 0.01 0.99 0.014 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.94 3.008 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.94 3.622 2,4-Dimethylpentane 00108-08-7 1.46 0.86 1.251 3-Methyl-c-2-pentene 00922-62-3 12.52 0.84 10.510 n-Octane 00111-65-9 0.80 0.81 0.642 2,3-Dimethylpentane 00565-59-3 1.25 0.79 0.990 Cyclopentene 00142-29-0 6.69 0.57 3.794 Indan 00496-11-7 3.23 0.45 1.440 t-2-Hexene 04050-45-7 8.55 0.42 3.589 2-Methyl-1-butene 00563-46-2 6.38 0.32 2.070 n-Pentane 00109-66-0 1.21 0.16 0.189 3-Methyl-t-2-pentene 00616-12-6 11.66 0.02 0.245

Total 133.5 501.4 3.756

No MIR available, use weighted average of 3.7557 Vehicle 220b - Fuel 10 psi E10 - Dynamic - Test 25774 Non Zero Mass Species Sorted By VOC

## E

- 167 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 892.60 961.253 2-Methylbutane (Isopentane) 00078-78-4 1.35 526.18 712.909 Ethanol 00064-17-5 1.45 428.56 620.967 Toluene 00108-88-3 3.93 351.76 1380.656 n-Hexane 00110-54-3 1.13 308.99 350.599 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 202.21 282.648 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 192.65 231.016 3-Methylpentane 00096-14-0 1.69 151.41 256.016 n-Pentane 00109-66-0 1.21 102.33 124.325 2-Methyl-2-butene 00513-35-9 14.20 95.80 1359.818 Cyclohexane 00110-82-7 1.14 95.58 108.714 Methylcyclopentane 00096-37-7 2.05 93.41 191.477 2,3-Dimethylbutane 00079-29-8 0.90 90.28 81.133 t-2-Pentene 00646-04-8 10.47 78.05 817.462 2,3,4-Trimethylpentane 00565-75-3 0.95 71.14 67.498 Benzene 00071-43-2 0.69 64.99 45.126 Methylcyclohexane 00108-87-2 1.56 59.68 92.818 2-Methylhexane 00591-76-4 1.09 57.54 62.439 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 50.18 160.132 2,4-Dimethylpentane 00108-08-7 1.46 49.79 72.657 n-Heptane 00142-82-5 0.97 47.93 46.289 2-Methyl-1-butene 00563-46-2 6.38 47.42 302.473 c-2-Pentene 00627-20-3 10.28 42.18 433.701 2,3-Dimethylpentane 00565-59-3 1.25 33.91 42.337 2,4-Dimethylhexane 00589-43-5 1.61 33.29 53.444 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 33.24 257.829 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 28.63 335.068 t-2-Hexene 04050-45-7 8.55 27.16 232.162 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 24.94 40.040 2,2,5-Trimethylhexane 03522-94-9 1.05 24.23 25.514 n-Octane 00111-65-9 0.80 23.84 18.988 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 23.50 124.511 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 21.98 117.995 3-Methyl-t-2-pentene 00616-12-6 11.66 21.21 247.336 c-2-Butene 00590-18-1 14.26 20.30 289.422 3-Methyl-c-2-pentene 00922-62-3 12.52 19.91 249.228 2-Methyl-2-pentene 00625-27-4 11.03 19.48 214.867 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 18.91 139.677 1-Methylcyclopentene 00693-89-0 12.45 18.81 234.242 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 16.71 18.253 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 16.03 105.888 Cyclopentene 00142-29-0 6.69 14.61 97.703 2-Methylheptane 00592-27-8 0.97 14.02 13.559 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 13.03 103.456 Vehicle 220b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7546 Non Zero Mass Species Sorted By VOC

## E

- 168 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7546 Non Zero Mass Species Sorted By VOC

2,2-Dimethylpentane 00590-35-2 1.04 12.12 12.640 3-Methylheptane 00589-81-1 1.12 11.69 13.140 t-1,2-Dimethylcyclopentane 00822-50-4 2.61 11.53 30.038 ortho-Xylene 00095-47-6 7.58 10.03 75.993 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 9.47 41.600 c-1,3-Dimethylcyclopentane 02532-58-3 2.61 9.28 24.168 2,2-Dimethylbutane 00075-83-2 1.11 9.21 10.238 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 8.99 51.949 1,3,5-Trimethylbenzene 00108-67-8 11.75 8.94 105.076 Ethylbenzene 00100-41-4 2.96 8.72 25.839 c-1,3-Dimethylcyclohexane 00638-04-0 2.61 8.41 21.910 2-Methylpropane 00075-28-5 1.18 8.36 9.839 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 7.31 40.486 3,3-Dimethylpentane 00562-49-2 1.12 6.91 7.726 2,2,3-Trimethylbutane 00464-06-2 1.05 6.08 6.412 n-Propylbenzene 00103-65-1 1.96 5.37 10.519 2,2-DiMeHexane 00590-73-8 0.94 5.22 4.918 n-Nonane 00111-84-2 0.68 4.61 3.147 3,5-Dimethylheptane 00926-82-9 1.42 4.34 6.185 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 4.30 33.725 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 4.07 15.727 2,3,5-Trimethylhexane 01069-53-0 1.12 3.80 4.259 t-1,4-Dimethylcyclohexane 02207-04-7 2.61 3.61 9.404 4-Methyloctane 02216-34-4 0.85 3.60 3.054 Unknown #5 2.61 3.44 8.973 Unknown #8 2.61 3.44 8.973 Unknown #16 2.61 3.30 8.596 n-Decane 00124-18-5 0.59 3.09 1.828 3,3-Dimethylhexane 00563-16-6 1.15 2.78 3.197 1,2,3-Trimethylbenzene 00526-73-8 11.94 2.70 32.264 Unknown #13 2.61 2.42 6.302 1,1-Dimethylcyclohexane 00590-66-9 1.12 2.27 2.531 3-Methyloctane 02216-33-3 0.88 2.17 1.920 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.61 2.17 5.648 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 1.94 1.660 Indan 00496-11-7 3.23 1.94 6.274 c-2-Heptene 06443-92-1 7.08 1.87 13.219 2,4-Dimethylheptane 02213-23-2 1.26 1.78 2.257 1-Nonene 00124-11-8 2.49 1.78 4.445 Isopropylbenzene (Cumene) 00098-82-8 2.61 1.72 4.477 1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.71 12.093 t-3-Heptene 14686-14-7 6.17 1.63 10.042 

### continued

## E

- 169 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7546 Non Zero Mass Species Sorted By VOC

1,4-Diethylbenzene 00105-05-5 4.39 1.53 6.712 t-4-Octene 14850-23-8 4.69 1.48 6.962 Unknown #9 2.61 1.47 3.839 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.32 8.608 2-Methyl-1,3-butadiene 00078-79-5 10.48 1.17 12.249 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.09 9.131 Unknown #3 2.61 1.09 2.835 Propane 00074-98-6 0.46 1.05 0.479 1-Heptene 00592-76-7 4.29 0.98 4.191 c- & t-4-Nonene 02198-23-4 4.42 0.89 3.942 1,3-Butadiene 00106-99-0 12.45 0.88 10.993 t-2-Nonene 06434-78-2 2.61 0.84 2.181 2,2-Dimethyloctane 15869-87-1 0.76 0.77 0.584 sec-Butylbenzene 00135-98-8 2.29 0.60 1.382 3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.60 5.844 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 0.53 0.633 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.53 2.038 c-2-Octene 07642-04-8 2.61 0.52 1.349 Unknown #7 2.61 0.47 1.224 4-Methyl-t-2-pentene 00674-76-0 8.04 0.43 3.492 1,3-Diethylbenzene 00141-93-5 7.08 0.34 2.410

Total 4805.1 12517.4 2.605

No MIR available, use weighted average of 2.6050 

### continued

## E

- 170 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 2650.87 3591.628 Ethanol 00064-17-5 1.45 800.67 1160.156 n-Butane 00106-97-8 1.08 756.65 814.851 n-Hexane 00110-54-3 1.13 580.87 659.099 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 514.76 719.528 n-Pentane 00109-66-0 1.21 408.11 495.831 3-Methylpentane 00096-14-0 1.69 360.08 608.854 2-Methyl-2-butene 00513-35-9 14.20 338.74 4808.373 t-2-Pentene 00646-04-8 10.47 280.15 2934.157 2,3-Dimethylbutane 00079-29-8 0.90 254.63 228.837 Toluene 00108-88-3 3.93 242.74 952.747 2-Methyl-1-butene 00563-46-2 6.38 198.81 1268.108 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 171.61 205.776 Methylcyclopentane 00096-37-7 2.05 170.27 349.010 c-2-Pentene 00627-20-3 10.28 152.17 1564.527 Cyclohexane 00110-82-7 1.14 145.36 165.322 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 119.30 1396.394 c-2-Butene 00590-18-1 14.26 108.49 1547.021 Benzene 00071-43-2 0.69 92.64 64.323 2,4-Dimethylpentane 00108-08-7 1.46 73.97 107.943 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 71.61 568.645 2-Methylpropane 00075-28-5 1.18 62.65 73.719 2-Methylhexane 00591-76-4 1.09 60.01 65.118 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 51.06 162.915 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 50.68 268.531 Methylcyclohexane 00108-87-2 1.56 50.21 78.100 t-2-Hexene 04050-45-7 8.55 48.28 412.718 Cyclopentene 00142-29-0 6.69 43.71 292.221 2,3,4-Trimethylpentane 00565-75-3 0.95 42.32 40.158 3-Methyl-t-2-pentene 00616-12-6 11.66 39.85 464.665 2-Methyl-2-pentene 00625-27-4 11.03 37.64 415.293 n-Heptane 00142-82-5 0.97 37.08 35.811 2,3-Dimethylpentane 00565-59-3 1.25 36.74 45.867 3-Methyl-c-2-pentene 00922-62-3 12.52 33.57 420.182 2,2-Dimethylbutane 00075-83-2 1.11 29.63 32.923 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 28.99 191.537 1-Methylcyclopentene 00693-89-0 12.45 25.94 323.019 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 24.21 139.870 2,4-Dimethylhexane 00589-43-5 1.61 21.28 34.162 2,2-Dimethylpentane 00590-35-2 1.04 19.27 20.104 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 15.13 24.292 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 14.95 115.931 t-1,2-Dimethylcyclopentane 00822-50-4 3.01 11.74 35.401 2,2,5-Trimethylhexane 03522-94-9 1.05 10.44 10.999 Vehicle 220b - Fuel 7 psi E10 - 86 ° F Static - Test 7564 Non Zero Mass Species Sorted By VOC

## E

- 171 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E10 - 86 ° F Static - Test 7564 Non Zero Mass Species Sorted By VOC

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 10.20 75.368 n-Octane 00111-65-9 0.80 9.96 7.934 c-1,3-Dimethylcyclopentane 02532-58-3 3.01 9.87 29.743 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 9.46 50.792 2,2,3-Trimethylbutane 00464-06-2 1.05 9.37 9.880 Propane 00074-98-6 0.46 9.06 4.142 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 8.66 9.460 3,3-Dimethylpentane 00562-49-2 1.12 7.99 8.934 2-Methylheptane 00592-27-8 0.97 7.06 6.828 3-Methylheptane 00589-81-1 1.12 5.65 6.356 ortho-Xylene 00095-47-6 7.58 4.53 34.296 c-1,3-Dimethylcyclohexane 00638-04-0 3.01 4.43 13.349 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.81 16.734 1,3,5-Trimethylbenzene 00108-67-8 11.75 3.77 44.336 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 3.71 29.091 2-Methyl-1,3-butadiene 00078-79-5 10.48 3.58 37.532 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 3.29 18.230 Ethylbenzene 00100-41-4 2.96 2.87 8.490 3,5-Dimethylheptane 00926-82-9 1.42 2.55 3.634 n-Propylbenzene 00103-65-1 1.96 2.06 4.034 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 2.04 7.897 t-1,4-Dimethylcyclohexane 02207-04-7 3.01 1.85 5.591 3,3-Dimethylhexane 00563-16-6 1.15 1.85 2.132 Unknown #5 3.01 1.84 5.541 Cyclopentadiene 00542-92-7 6.89 1.64 11.270 2,3,5-Trimethylhexane 01069-53-0 1.12 1.56 1.748 c-2-Heptene 06443-92-1 7.08 1.51 10.680 n-Nonane 00111-84-2 0.68 1.47 1.006 t-3-Heptene 14686-14-7 6.17 1.36 8.372 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.34 16.030 Unknown #16 3.01 1.25 3.768 1,1-Dimethylcyclohexane 00590-66-9 1.12 1.17 1.303 4-Methyloctane 02216-34-4 0.85 1.13 0.958 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.01 1.11 3.358 Unknown #8 3.01 1.11 3.341 Unknown #3 3.01 0.87 2.626 1,3-Butadiene 00106-99-0 12.45 0.86 10.721 1-Heptene 00592-76-7 4.29 0.82 3.495 Isopropylbenzene (Cumene) 00098-82-8 3.01 0.80 2.405 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.79 5.197 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.72 5.127 t-4-Octene 14850-23-8 4.69 0.67 3.165 

### continued

## E

- 172 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E10 - 86 ° F Static - Test 7564 Non Zero Mass Species Sorted By VOC

1-Nonene 00124-11-8 2.49 0.67 1.671 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.66 5.506 n-Decane 00124-18-5 0.59 0.64 0.380 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.63 0.538 2,4-Dimethylheptane 02213-23-2 1.26 0.42 0.536 3-Methyloctane 02216-33-3 0.88 0.41 0.366 Unknown #9 3.01 0.40 1.208 3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.31 3.028 1-Butyne 00107-00-6 6.05 0.18 1.099 n-Undecane 01120-21-4 0.52 0.16 0.086

Total 9442.0 28464.0 3.015

No MIR available, use weighted average of 3.0146 

### continued

## E

- 173 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 5769.20 7816.612 Ethanol 00064-17-5 1.45 2589.89 3752.691 n-Butane 00106-97-8 1.08 1559.36 1679.295 n-Hexane 00110-54-3 1.13 1414.77 1605.303 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1218.97 1703.867 n-Pentane 00109-66-0 1.21 915.30 1112.033 3-Methylpentane 00096-14-0 1.69 858.34 1451.348 2-Methyl-2-butene 00513-35-9 14.20 773.35 10977.672 Toluene 00108-88-3 3.93 656.57 2577.062 t-2-Pentene 00646-04-8 10.47 633.05 6630.198 2,3-Dimethylbutane 00079-29-8 0.90 593.24 533.142 2-Methyl-1-butene 00563-46-2 6.38 441.57 2816.547 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 440.53 528.245 Methylcyclopentane 00096-37-7 2.05 412.33 845.189 Cyclohexane 00110-82-7 1.14 347.77 395.544 c-2-Pentene 00627-20-3 10.28 344.63 3543.302 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 263.56 3084.817 Benzene 00071-43-2 0.69 227.73 158.124 c-2-Butene 00590-18-1 14.26 226.76 3233.612 2,4-Dimethylpentane 00108-08-7 1.46 182.35 266.113 2-Methylhexane 00591-76-4 1.09 151.57 164.481 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 144.84 1150.181 Methylcyclohexane 00108-87-2 1.56 132.17 205.572 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 131.60 419.935 2-Methylpropane 00075-28-5 1.18 127.58 150.115 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 121.35 642.951 t-2-Hexene 04050-45-7 8.55 117.30 1002.733 2,3,4-Trimethylpentane 00565-75-3 0.95 115.01 109.127 Cyclopentene 00142-29-0 6.69 104.56 699.056 n-Heptane 00142-82-5 0.97 97.85 94.496 3-Methyl-t-2-pentene 00616-12-6 11.66 96.96 1130.464 2,3-Dimethylpentane 00565-59-3 1.25 93.43 116.628 2-Methyl-2-pentene 00625-27-4 11.03 91.72 1011.846 3-Methyl-c-2-pentene 00922-62-3 12.52 82.76 1036.021 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 71.09 469.667 2,2-Dimethylbutane 00075-83-2 1.11 69.23 76.931 1-Methylcyclopentene 00693-89-0 12.45 66.31 825.804 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 58.14 335.930 2,4-Dimethylhexane 00589-43-5 1.61 57.48 92.290 2,2-Dimethylpentane 00590-35-2 1.04 47.87 49.926 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 41.57 66.729 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 40.64 315.148 t-1,2-Dimethylcyclopentane 00822-50-4 2.97 29.75 88.286 2,2,5-Trimethylhexane 03522-94-9 1.05 29.38 30.935 Vehicle 220b - Fuel 7 psi E10 - 105 ° F Static - Test 7565 Non Zero Mass Species Sorted By VOC

## E

- 174 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E10 - 105 ° F Static - Test 7565 Non Zero Mass Species Sorted By VOC

n-Octane 00111-65-9 0.80 28.01 22.300 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 26.14 140.342 2,2,3-Trimethylbutane 00464-06-2 1.05 25.38 26.755 c-1,3-Dimethylcyclopentane 02532-58-3 2.97 25.04 74.296 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 24.60 26.870 3,3-Dimethylpentane 00562-49-2 1.12 21.75 24.335 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 21.73 160.471 2-Methylheptane 00592-27-8 0.97 17.82 17.240 Propane 00074-98-6 0.46 16.88 7.715 3-Methylheptane 00589-81-1 1.12 15.97 17.957 c-1,3-Dimethylcyclohexane 00638-04-0 2.97 12.00 35.609 ortho-Xylene 00095-47-6 7.58 11.88 89.997 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 10.82 47.540 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 10.16 79.609 1,3,5-Trimethylbenzene 00108-67-8 11.75 10.00 117.556 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 8.49 47.032 2-Methyl-1,3-butadiene 00078-79-5 10.48 8.27 86.655 Ethylcyclohexane 01678-91-7 1.35 8.09 10.877 Ethylbenzene 00100-41-4 2.96 7.29 21.601 n-Propylbenzene 00103-65-1 1.96 6.42 12.574 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 5.54 21.384 t-1,4-Dimethylcyclohexane 02207-04-7 2.97 5.50 16.327 Unknown #5 2.97 5.42 16.092 3,3-Dimethylhexane 00563-16-6 1.15 5.35 6.156 Cyclopentadiene 00542-92-7 6.89 5.09 35.060 c-2-Heptene 06443-92-1 7.08 4.75 33.578 n-Nonane 00111-84-2 0.68 4.07 2.777 t-3-Heptene 14686-14-7 6.17 3.84 23.672 1,2,3-Trimethylbenzene 00526-73-8 11.94 3.79 45.212 1,1-Dimethylcyclohexane 00590-66-9 1.12 3.66 4.080 2,3,5-Trimethylhexane 01069-53-0 1.12 3.61 4.049 Unknown #3 2.97 3.19 9.455 Unknown #8 2.97 3.01 8.926 4-Methyloctane 02216-34-4 0.85 2.94 2.494 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.97 2.91 8.627 Unknown #13 2.97 2.75 8.159 1-Heptene 00592-76-7 4.29 2.66 11.402 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 2.65 17.338 Isopropylbenzene (Cumene) 00098-82-8 2.97 2.59 7.693 4-Methyl-t-2-pentene 00674-76-0 8.04 2.56 20.606 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 2.25 18.832 3-Methyloctane 02216-33-3 0.88 2.23 1.971 

### continued

## E

- 175 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E10 - 105 ° F Static - Test 7565 Non Zero Mass Species Sorted By VOC

n-Decane 00124-18-5 0.59 2.22 1.312 Unknown #16 2.97 2.08 6.186 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 2.06 1.763 1-Nonene 00124-11-8 2.49 1.81 4.502 1,3-Butadiene 00106-99-0 12.45 1.71 21.247 1,4-Diethylbenzene 00105-05-5 4.39 1.65 7.255 2,4-Dimethylheptane 02213-23-2 1.26 1.65 2.088 t-4-Octene 14850-23-8 4.69 1.55 7.276 Unknown #9 2.97 1.54 4.573 Indan 00496-11-7 3.23 1.54 4.965 3-Ethyl-c-2-Pentene 00816-79-5 9.76 1.48 14.414 Unknown #23 2.97 1.45 4.316 1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.40 9.937 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 1.24 9.372 1-Methyl-2-Propylbenzene 01074-17-5 5.43 1.21 6.580 Unknown #14 2.97 1.15 3.408 2,2-Dimethyloctane 15869-87-1 0.76 0.97 0.733 1,3-Diethylbenzene 00141-93-5 7.08 0.97 6.834 c- & t-4-Nonene 02198-23-4 4.42 0.95 4.195 t-2-Nonene 06434-78-2 2.97 0.89 2.656 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.87 6.526 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 0.82 0.971 sec-Butylbenzene 00135-98-8 2.29 0.72 1.655 3-Methylnonane 2.97 0.72 2.141 Unknown #7 2.97 0.67 1.996 Unknown #4 2.97 0.65 1.943 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.65 2.498 Isobutylbenzene 00538-93-2 2.97 0.65 1.933 Unknown #6

. 2.97 0.64 1.886 1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 0.62 6.348 Unknown #15 2.97 0.57 1.680 Unknown #10 2.97 0.48 1.430 1-Butyne 00107-00-6 6.05 0.42 2.558 1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 0.39 2.944 t-2-Octene & t-1,2-DiMeCyHexane 13389-42-9+06876-23-9 5.92 0.37 2.164 c-1,2-Dimethylcyclohexane 02207-01-4 2.97 0.34 1.006 n-Undecane 01120-21-4 0.52 0.34 0.176 c-2-Octene 07642-04-8 2.97 0.32 0.959 Unknown #12 2.97 0.32 0.944 4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 0.25 1.123 1,2,4,5-Tetramethylbenzene 00095-93-2 9.26 0.19 1.748

Total 22427.0 66555.4 2.968

No MIR available, use weighted average of 2.9676 

### continued

## E

- 176 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 98.83 133.901 Ethanol 00064-17-5 1.45 28.30 41.006 n-Hexane 00110-54-3 1.13 26.58 30.156 Toluene 00108-88-3 3.93 24.49 96.112 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 22.09 30.872 n-Pentane 00109-66-0 1.21 16.18 19.656 3-Methylpentane 00096-14-0 1.69 15.88 26.846 2-Methyl-2-butene 00513-35-9 14.20 12.64 179.359 n-Butane 00106-97-8 1.08 11.94 12.859 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 11.47 13.757 2,3-Dimethylbutane 00079-29-8 0.90 11.39 10.233 t-2-Pentene 00646-04-8 10.47 10.47 109.676 Methylcyclopentane 00096-37-7 2.05 8.17 16.737 2-Methyl-1-butene 00563-46-2 6.38 7.92 50.510 Cyclohexane 00110-82-7 1.14 6.74 7.663 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 6.19 33.261 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 5.12 16.339 c-2-Pentene 00627-20-3 10.28 5.06 52.052 c-2-Butene 00590-18-1 14.26 4.93 70.326 Benzene 00071-43-2 0.69 4.79 3.324 1,3,5-Trimethylbenzene 00108-67-8 11.75 4.41 51.813 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 4.36 51.038 2,4-Dimethylpentane 00108-08-7 1.46 3.96 5.784 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.86 20.464 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.79 30.111 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.67 28.441 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.57 15.704 2,3,4-Trimethylpentane 00565-75-3 0.95 3.55 3.372 2-Methylpropane 00075-28-5 1.18 3.43 4.033 2-Methylhexane 00591-76-4 1.09 3.32 3.604 Methylcyclohexane 00108-87-2 1.56 3.12 4.854 n-Heptane 00142-82-5 0.97 2.95 2.854 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.60 17.196 t-2-Hexene 04050-45-7 8.55 2.54 21.712 1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.51 17.810 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.43 17.949 2,2-Dimethylpentane 00590-35-2 1.04 2.29 2.391 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.26 12.543 n-Octane 00111-65-9 0.80 2.11 1.684 n-Nonane 00111-84-2 0.68 2.06 1.404 2,3-Dimethylpentane 00565-59-3 1.25 2.01 2.514 Methane 00074-82-8 0.01 1.99 0.028 2-Methyl-2-pentene 00625-27-4 11.03 1.91 21.073 3-Methyl-t-2-pentene 00616-12-6 11.66 1.89 22.026 Vehicle 220b - Fuel 7 psi E10 - Dynamic - Test 25781 Non Zero Mass Species Sorted By VOC

## E

- 177 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E10 - Dynamic - Test 25781 Non Zero Mass Species Sorted By VOC

n-Undecane 01120-21-4 0.52 1.87 0.975 2,2,5-Trimethylhexane 03522-94-9 1.05 1.81 1.902 Cyclopentene 00142-29-0 6.69 1.77 11.804 ortho-Xylene 00095-47-6 7.58 1.76 13.337 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.67 19.911 3-Methyl-c-2-pentene 00922-62-3 12.52 1.66 20.757 2,2-Dimethylbutane 00075-83-2 1.11 1.62 1.796 n-Propylbenzene 00103-65-1 1.96 1.60 3.133 3,3-Dimethylpentane 00562-49-2 1.12 1.46 1.630 3-Methylheptane 00589-81-1 1.12 1.40 1.569 t-1,2-Dimethylcyclopentane 00822-50-4 3.28 1.38 4.516 Indan 00496-11-7 3.23 1.34 4.321 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.32 2.113 1-Methylcyclopentene 00693-89-0 12.45 1.25 15.571 c-1,3-Dimethylcyclohexane 00638-04-0 3.28 1.20 3.939 c-1,3-Dimethylcyclopentane 02532-58-3 3.28 1.20 3.928 Ethylbenzene 00100-41-4 2.96 1.07 3.180 n-Decane 00124-18-5 0.59 1.02 0.600 2-Methylheptane 00592-27-8 0.97 0.81 0.780 2,2,3-Trimethylbutane 00464-06-2 1.05 0.73 0.768 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.68 2.611 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.67 3.875 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.63 6.610 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.52 0.571 2,4-Dimethylhexane 00589-43-5 1.61 0.02 0.034

Total 440.2 1445.3 3.283

No MIR available, use weighted average of 3.2833 

### continued

## E

- 178 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 489.17 662.773 Ethanol 00064-17-5 1.45 400.13 579.776 Toluene 00108-88-3 3.93 359.77 1412.113 n-Hexane 00110-54-3 1.13 300.42 340.878 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 192.23 268.701 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 182.57 218.917 3-Methylpentane 00096-14-0 1.69 145.21 245.525 n-Butane 00106-97-8 1.08 119.26 128.430 n-Pentane 00109-66-0 1.21 95.19 115.644 Cyclohexane 00110-82-7 1.14 93.57 106.425 2-Methyl-2-butene 00513-35-9 14.20 90.18 1280.067 Methylcyclopentane 00096-37-7 2.05 89.98 184.432 2,3-Dimethylbutane 00079-29-8 0.90 84.97 76.362 t-2-Pentene 00646-04-8 10.47 73.23 766.951 2,3,4-Trimethylpentane 00565-75-3 0.95 68.70 65.189 Benzene 00071-43-2 0.69 64.99 45.127 Methylcyclohexane 00108-87-2 1.56 58.40 90.837 2-Methylhexane 00591-76-4 1.09 54.62 59.269 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 48.02 153.243 n-Heptane 00142-82-5 0.97 47.88 46.239 2,4-Dimethylpentane 00108-08-7 1.46 47.48 69.294 2-Methyl-1-butene 00563-46-2 6.38 43.73 278.949 c-2-Pentene 00627-20-3 10.28 39.42 405.244 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 34.71 269.153 2,4-Dimethylhexane 00589-43-5 1.61 32.69 52.491 2,3-Dimethylpentane 00565-59-3 1.25 31.57 39.406 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 28.61 211.289 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 27.35 320.167 t-2-Hexene 04050-45-7 8.55 26.15 223.518 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 25.58 137.339 n-Octane 00111-65-9 0.80 25.39 20.218 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 23.79 38.192 2,2,5-Trimethylhexane 03522-94-9 1.05 23.77 25.033 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 22.90 121.314 3-Methyl-t-2-pentene 00616-12-6 11.66 20.75 241.964 3-Methyl-c-2-pentene 00922-62-3 12.52 19.27 241.268 2-Methyl-2-pentene 00625-27-4 11.03 18.56 204.719 c-2-Butene 00590-18-1 14.26 18.06 257.579 1-Methylcyclopentene 00693-89-0 12.45 18.02 224.391 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 16.64 18.172 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 15.53 102.611 Cyclopentene 00142-29-0 6.69 13.49 90.225 2-Methylheptane 00592-27-8 0.97 13.31 12.877 3-Methylheptane 00589-81-1 1.12 11.96 13.451 Vehicle 220b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7569 Non Zero Mass Species Sorted By VOC

## E

- 179 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7569 Non Zero Mass Species Sorted By VOC

2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 11.86 94.172 2,2-Dimethylpentane 00590-35-2 1.04 11.44 11.931 t-1,2-Dimethylcyclopentane 00822-50-4 2.93 11.38 33.352 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 11.25 49.438 1,3,5-Trimethylbenzene 00108-67-8 11.75 10.70 125.754 ortho-Xylene 00095-47-6 7.58 10.23 77.467 2,2-Dimethylbutane 00075-83-2 1.11 9.79 10.883 c-1,3-Dimethylcyclopentane 02532-58-3 2.93 9.07 26.589 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 8.70 48.240 c-1,3-Dimethylcyclohexane 00638-04-0 2.93 8.65 25.348 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 8.21 47.420 Ethylbenzene 00100-41-4 2.96 7.78 23.059 2-Methylpropane 00075-28-5 1.18 7.40 8.705 n-Propylbenzene 00103-65-1 1.96 6.78 13.292 3,3-Dimethylpentane 00562-49-2 1.12 6.66 7.446 2,2,3-Trimethylbutane 00464-06-2 1.05 5.72 6.028 n-Nonane 00111-84-2 0.68 5.18 3.537 2,2-DiMeHexane 00590-73-8 0.94 4.79 4.504 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 4.32 33.865 4-Methyloctane 02216-34-4 0.85 4.15 3.519 Unknown #16 2.93 4.07 11.939 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 4.07 15.734 2,3,5-Trimethylhexane 01069-53-0 1.12 3.93 4.401 t-1,4-Dimethylcyclohexane 02207-04-7 2.93 3.78 11.067 3,5-Dimethylheptane 00926-82-9 1.42 3.74 5.329 Unknown #8 2.93 3.60 10.550 Unknown #5 2.93 3.53 10.346 1,2,3-Trimethylbenzene 00526-73-8 11.94 3.50 41.768 n-Decane 00124-18-5 0.59 3.19 1.884 3-Methyloctane 02216-33-3 0.88 3.01 2.662 3,3-Dimethylhexane 00563-16-6 1.15 2.96 3.407 Unknown #13 2.93 2.84 8.314 1,1-Dimethylcyclohexane 00590-66-9 1.12 2.48 2.768 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 2.40 2.050 Indan 00496-11-7 3.23 2.34 7.572 1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.28 16.138 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.93 2.25 6.584 c-2-Heptene 06443-92-1 7.08 2.11 14.911 1-Nonene 00124-11-8 2.49 1.89 4.711 Isopropylbenzene (Cumene) 00098-82-8 2.93 1.84 5.394 1,4-Diethylbenzene 00105-05-5 4.39 1.78 7.792 t-3-Heptene 14686-14-7 6.17 1.73 10.692 

### continued

## E

- 180 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7569 Non Zero Mass Species Sorted By VOC

2,4-Dimethylheptane 02213-23-2 1.26 1.61 2.041 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 1.49 1.759 Unknown #9 2.93 1.32 3.856 1-Methyl-2-Propylbenzene 01074-17-5 5.43 1.30 7.076 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.22 7.986 1,3-Butadiene 00106-99-0 12.45 1.16 14.450 1-Heptene 00592-76-7 4.29 1.15 4.924 t-4-Octene 14850-23-8 4.69 1.12 5.244 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.12 9.362 3-Methylnonane 2.93 1.08 3.176 Ethylene 00074-85-1 8.88 1.02 9.052 2-Methyl-1,3-butadiene 00078-79-5 10.48 1.00 10.454 Propane 00074-98-6 0.46 0.99 0.452 Unknown #14 2.93 0.92 2.697 c- & t-4-Nonene 02198-23-4 4.42 0.91 4.022 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.90 6.791 t-2-Nonene 06434-78-2 2.93 0.88 2.585 Unknown #3 2.93 0.88 2.581 Unknown #22

. 2.93 0.86 2.524 1,3-Diethylbenzene 00141-93-5 7.08 0.84 5.930 c-2-Octene 07642-04-8 2.93 0.82 2.398 sec-Butylbenzene 00135-98-8 2.29 0.78 1.795 2,2-Dimethyloctane 15869-87-1 0.76 0.74 0.560 n-Undecane 01120-21-4 0.52 0.72 0.378 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.63 2.409 4-Methyl-t-2-pentene 00674-76-0 8.04 0.62 5.015 1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 0.62 6.279 3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.61 5.955 Unknown #7 2.93 0.58 1.693 Isobutylbenzene 00538-93-2 2.93 0.56 1.630 Unknown #6

. 2.93 0.54 1.583 Unknown #12 2.93 0.50 1.468 Unknown #10 2.93 0.45 1.317 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.41 3.123 t-2-Octene & t-1,2-DiMeCyHexane 13389-42-9+06876-23-9 5.92 0.41 2.440 Unknown #17 2.93 0.41 1.190 1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 0.33 2.478 Unknown #15 2.93 0.30 0.878 4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 0.28 1.240

Total 3916.7 11477.1 2.930

No MIR available, use weighted average of 2.9303 

### continued

## E

- 181 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 9476.55 10205.420 2-Methylbutane (Isopentane) 00078-78-4 1.35 6062.19 8213.588 Cyclohexane 00110-82-7 1.14 1145.93 1303.337 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 749.37 1047.458 n-Hexane 00110-54-3 1.13 595.96 676.225 n-Pentane 00109-66-0 1.21 516.50 627.514 3-Methylpentane 00096-14-0 1.69 480.94 813.205 2,3-Dimethylbutane 00079-29-8 0.90 442.20 397.402 2-Methyl-2-butene 00513-35-9 14.20 413.43 5868.679 Toluene 00108-88-3 3.93 401.99 1577.804 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 341.71 409.745 t-2-Pentene 00646-04-8 10.47 320.70 3358.834 Methylcyclopentane 00096-37-7 2.05 227.84 467.014 2-Methyl-1-butene 00563-46-2 6.38 219.35 1399.150 c-2-Pentene 00627-20-3 10.28 174.52 1794.265 t-2-Butene 00624-64-6 15.20 132.26 2010.005 Benzene 00071-43-2 0.69 130.94 90.916 2,4-Dimethylpentane 00108-08-7 1.46 128.45 187.447 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 127.39 1491.092 c-2-Butene 00590-18-1 14.26 102.93 1467.759 2,3,4-Trimethylpentane 00565-75-3 0.95 87.93 83.431 2,2-Dimethylbutane 00075-83-2 1.11 87.02 96.698 2,3-Dimethylpentane 00565-59-3 1.25 75.65 94.439 2-Methylhexane 00591-76-4 1.09 74.15 80.472 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 67.24 356.267 t-2-Hexene 04050-45-7 8.55 64.62 552.425 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 64.49 205.770 3-Methyl-t-2-pentene 00616-12-6 11.66 62.94 733.843 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 61.13 485.454 Cyclopentene 00142-29-0 6.69 53.21 355.777 2-Methyl-2-pentene 00625-27-4 11.03 50.00 551.639 3-Methyl-c-2-pentene 00922-62-3 12.52 44.98 563.086 1-Methylcyclopentene 00693-89-0 12.45 38.94 484.991 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 37.82 249.884 3-Methyl-1-butene 00563-45-1 6.85 36.81 252.358 2-Methylpropane 00075-28-5 1.18 33.81 39.779 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 31.90 184.292 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 31.78 246.451 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 29.81 47.859 2,4-Dimethylhexane 00589-43-5 1.61 29.62 47.552 2,2,5-Trimethylhexane 03522-94-9 1.05 25.30 26.642 n-Heptane 00142-82-5 0.97 23.59 22.784 2,2-Dimethylpentane 00590-35-2 1.04 18.53 19.325 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 18.52 20.224 Vehicle 220b - Fuel 9 psi E0 - 86 ° F Static - Test 7644 Non Zero Mass Species Sorted By VOC

## E

- 182 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 9 psi E0 - 86 ° F Static - Test 7644 Non Zero Mass Species Sorted By VOC

Methylcyclohexane 00108-87-2 1.56 16.79 26.122 t-1,2-Dimethylcyclopentane 00822-50-4 2.12 16.73 35.534 c-1,3-Dimethylcyclopentane 02532-58-3 2.12 13.43 28.535 2,2,3-Trimethylbutane 00464-06-2 1.05 11.95 12.596 4-Methyl-t-2-pentene 00674-76-0 8.04 11.71 94.130 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 11.47 61.582 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 10.49 77.485 ortho-Xylene 00095-47-6 7.58 9.39 71.125 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 7.78 34.179 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 7.32 57.358 3,3-Dimethylpentane 00562-49-2 1.12 7.03 7.865 3-Methylheptane 00589-81-1 1.12 6.24 7.017 Ethylbenzene 00100-41-4 2.96 6.15 18.224 Unknown #1 2.12 4.83 10.259 2-Methylheptane 00592-27-8 0.97 4.80 4.647 2-Methyl-1,3-butadiene 00078-79-5 10.48 4.62 48.464 1,3,5-Trimethylbenzene 00108-67-8 11.75 4.43 52.038 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 4.18 23.191 Propane 00074-98-6 0.46 4.17 1.908 n-Propylbenzene 00103-65-1 1.96 3.93 7.710 Unknown #5 2.12 3.68 7.826 n-Octane 00111-65-9 0.80 3.17 2.527 c-2-Heptene 06443-92-1 2.12 2.95 6.277 Unknown #6

. 2.12 2.46 5.236 1,2,3-Trimethylbenzene 00526-73-8 11.94 2.28 27.177 c-1,3-Dimethylcyclohexane 00638-04-0 2.12 2.19 4.662 t-3-Heptene 14686-14-7 6.17 2.10 12.978 Unknown #3 2.12 2.07 4.405 Unknown #16 2.12 1.87 3.977 Unknown #22

. 2.12 1.83 3.890 1-Heptene 00592-76-7 4.29 1.82 7.802 3,3-Dimethylhexane 00563-16-6 1.15 1.66 1.908 2,3,5-Trimethylhexane 01069-53-0 1.12 1.65 1.853 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.64 10.762 Ethylcyclohexane 01678-91-7 1.35 1.64 2.203 n-Nonane 00111-84-2 0.68 1.46 0.995 1,1-Dimethylcyclohexane 00590-66-9 1.12 1.45 1.612 Methane 00074-82-8 0.01 1.33 0.018 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.33 11.117 Styrene 00100-42-5 1.66 1.24 2.052 Unknown #8 2.12 1.10 2.331 Isopropylbenzene (Cumene) 00098-82-8 2.12 1.02 2.170 

### continued

## E

- 183 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 9 psi E0 - 86 ° F Static - Test 7644 Non Zero Mass Species Sorted By VOC

3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.97 9.450 1-Nonene 00124-11-8 2.49 0.89 2.210 4-Methyloctane 02216-34-4 0.85 0.84 0.710 2,4-Dimethylheptane 02213-23-2 1.26 0.82 1.041 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.75 4.734 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.12 0.70 1.480 1,3-Butadiene 00106-99-0 12.45 0.64 7.994

Total 23556.0 50039.7 2.124

No MIR available, use weighted average of 2.1243 

### continued

## E

- 184 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 13505.49 14544.237 2-Methylbutane (Isopentane) 00078-78-4 1.35 9713.77 13161.067 Cyclohexane 00110-82-7 1.14 2674.68 3042.085 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1448.55 2024.768 n-Hexane 00110-54-3 1.13 1252.04 1420.662 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1063.79 1275.612 3-Methylpentane 00096-14-0 1.69 954.60 1614.109 n-Pentane 00109-66-0 1.21 868.43 1055.084 2,3-Dimethylbutane 00079-29-8 0.90 836.00 751.307 2-Methyl-2-butene 00513-35-9 14.20 701.33 9955.338 Toluene 00108-88-3 3.93 683.32 2682.063 t-2-Pentene 00646-04-8 10.47 537.38 5628.248 Methylcyclopentane 00096-37-7 2.05 488.57 1001.463 2,3,4-Trimethylpentane 00565-75-3 0.95 364.02 345.394 2-Methyl-1-butene 00563-46-2 6.38 361.34 2304.852 2,4-Dimethylpentane 00108-08-7 1.46 300.42 438.410 c-2-Pentene 00627-20-3 10.28 294.44 3027.258 Benzene 00071-43-2 0.69 273.07 189.604 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 213.03 2493.441 2-Methylhexane 00591-76-4 1.09 208.43 226.182 2,3-Dimethylpentane 00565-59-3 1.25 203.30 253.786 t-2-Butene 00624-64-6 15.20 190.39 2893.522 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 183.66 586.061 c-2-Butene 00590-18-1 14.26 156.04 2225.116 2,2-Dimethylbutane 00075-83-2 1.11 149.97 166.643 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 138.21 732.285 t-2-Hexene 04050-45-7 8.55 134.27 1147.862 3-Methyl-t-2-pentene 00616-12-6 11.66 131.42 1532.305 2,4-Dimethylhexane 00589-43-5 1.61 117.92 189.323 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 115.00 184.612 2-Methyl-2-pentene 00625-27-4 11.03 102.46 1130.401 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 96.46 748.104 3-Methyl-c-2-pentene 00922-62-3 12.52 95.63 1197.103 Cyclopentene 00142-29-0 6.69 94.31 630.569 1-Methylcyclopentene 00693-89-0 12.45 93.50 1164.488 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 88.56 703.287 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 77.91 418.321 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 74.39 491.440 n-Heptane 00142-82-5 0.97 72.26 69.783 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 64.71 373.877 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 63.26 467.230 2,2,5-Trimethylhexane 03522-94-9 1.05 62.81 66.145 3-Methyl-1-butene 00563-45-1 6.85 59.58 408.389 Methylcyclohexane 00108-87-2 1.56 54.72 85.117 Vehicle 220b - Fuel 9 psi E0 - 105 ° F Static - Test 7647 Non Zero Mass Species Sorted By VOC

## E

- 185 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 9 psi E0 - 105 ° F Static - Test 7647 Non Zero Mass Species Sorted By VOC

t-1,2-Dimethylcyclopentane 00822-50-4 2.20 46.75 102.786 2,2-Dimethylpentane 00590-35-2 1.04 40.75 42.504 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 39.42 173.207 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 36.88 40.280 c-1,3-Dimethylcyclopentane 02532-58-3 2.20 36.59 80.450 ortho-Xylene 00095-47-6 7.58 32.08 243.040 1,3,5-Trimethylbenzene 00108-67-8 11.75 29.47 346.410 4-Methyl-t-2-pentene 00674-76-0 8.04 25.95 208.593 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 25.34 140.416 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 24.99 195.770 2,2,3-Trimethylbutane 00464-06-2 1.05 24.02 25.321 1,2,3-Trimethylbenzene 00526-73-8 11.94 22.49 268.523 3,3-Dimethylpentane 00562-49-2 1.12 19.27 21.557 1-Methyl-3-Propylbenzene 01074-43-7 7.08 19.07 135.059 n-Propylbenzene 00103-65-1 1.96 16.55 32.438 Ethylbenzene 00100-41-4 2.96 15.85 46.961 Indan 00496-11-7 3.23 13.39 43.324 1,4-Diethylbenzene 00105-05-5 4.39 12.70 55.719 Unknown #16 2.20 12.53 27.550 2-Methylpropane 00075-28-5 1.18 10.60 12.475 1-Methyl-2-Propylbenzene 01074-17-5 5.43 9.83 53.430 c-2-Heptene 06443-92-1 7.08 9.35 66.163 Unknown #13 2.20 9.24 20.320 2-Methylheptane 00592-27-8 0.97 8.97 8.676 3-Methylheptane 00589-81-1 1.12 8.84 9.935 3,5-Dimethylheptane 00926-82-9 1.42 8.76 12.468 3,3-Dimethylhexane 00563-16-6 1.15 8.68 9.991 Isopropylbenzene (Cumene) 00098-82-8 2.20 8.01 17.611 2-Methyl-1,3-butadiene 00078-79-5 10.48 8.00 83.901 Unknown #1 2.20 7.25 15.930 1-Nonene 00124-11-8 2.49 6.52 16.256 t-3-Heptene 14686-14-7 6.17 6.48 39.994 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 6.32 41.394 2,3,5-Trimethylhexane 01069-53-0 1.12 6.29 7.051 Unknown #5 2.20 6.27 13.793 1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 6.24 63.426 n-Octane 00111-65-9 0.80 5.90 4.700 Unknown #3 2.20 5.86 12.893 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.20 5.86 12.876 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 5.41 40.743 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 5.27 39.690 1-Heptene 00592-76-7 4.29 5.22 22.403 

### continued

## E

- 186 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 9 psi E0 - 105 ° F Static - Test 7647 Non Zero Mass Species Sorted By VOC

1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 5.15 19.898 n-Butylbenzene 00104-51-8 2.29 5.10 11.690 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 4.56 38.172 c-1,3-Dimethylcyclohexane 00638-04-0 2.20 4.19 9.209 1,3-Diethylbenzene 00141-93-5 7.08 3.88 27.462 4-Methyloctane 02216-34-4 0.85 3.84 3.258 sec-Butylbenzene 00135-98-8 2.29 3.69 8.447 t-2-Nonene 06434-78-2 2.20 3.69 8.103 1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 3.47 26.167 Unknown #8 2.20 3.41 7.501 2,4-Dimethylheptane 02213-23-2 1.26 3.33 4.212 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 3.22 20.301 Isobutylbenzene 00538-93-2 2.20 3.16 6.942 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 3.15 12.028 3-Methyloctane 02216-33-3 0.88 3.08 2.722 t-4-Octene 14850-23-8 4.69 3.03 14.222 3-Ethyl-c-2-Pentene 00816-79-5 9.76 2.95 28.756 n-Nonane 00111-84-2 0.68 2.56 1.750 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 1.78 1.523 1,1-Dimethylcyclohexane 00590-66-9 1.12 1.78 1.987 t-1,4-Dimethylcyclohexane 02207-04-7 2.20 1.36 3.000 Unknown #6 2.20 1.33 2.917

Total 40098.4 88163.2 2.199

No MIR available, use weighted average of 2.1987 

### continued

## E

- 187 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 269.58 365.257 Cyclohexane 00110-82-7 1.14 260.03 295.753 Toluene 00108-88-3 3.93 257.58 1011.006 n-Butane 00106-97-8 1.08 243.42 262.141 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 149.78 179.600 n-Hexane 00110-54-3 1.13 95.00 107.789 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 88.81 124.131 2,3,4-Trimethylpentane 00565-75-3 0.95 66.17 62.789 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 64.02 343.730 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 63.74 494.302 3-Methylpentane 00096-14-0 1.69 63.57 107.495 2,3-Dimethylbutane 00079-29-8 0.90 47.93 43.072 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 45.43 199.609 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 44.81 330.946 Methylcyclopentane 00096-37-7 2.05 37.42 76.698 n-Pentane 00109-66-0 1.21 36.38 44.193 2,2,5-Trimethylhexane 03522-94-9 1.05 31.69 33.371 2,4-Dimethylpentane 00108-08-7 1.46 30.13 43.974 2-Methyl-2-butene 00513-35-9 14.20 27.27 387.108 Benzene 00071-43-2 0.69 27.23 18.910 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 25.76 82.203 2-Methylhexane 00591-76-4 1.09 25.42 27.584 2,3-Dimethylpentane 00565-59-3 1.25 23.79 29.697 1,3,5-Trimethylbenzene 00108-67-8 11.75 22.93 269.521 t-2-Pentene 00646-04-8 10.47 21.86 228.949 2,4-Dimethylhexane 00589-43-5 1.61 20.69 33.226 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 20.23 32.484 n-Heptane 00142-82-5 0.97 17.15 16.560 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 15.59 86.382 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 15.37 81.438 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 14.53 15.864 2-Methyl-1-butene 00563-46-2 6.38 14.15 90.287 c-2-Pentene 00627-20-3 10.28 13.59 139.745 n-Propylbenzene 00103-65-1 1.96 13.50 26.459 ortho-Xylene 00095-47-6 7.58 13.49 102.226 2,3,5-Trimethylhexane 01069-53-0 1.12 11.40 12.776 Unknown #16 2.79 10.86 30.361 3-Methyl-t-2-pentene 00616-12-6 11.66 10.58 123.391 t-2-Hexene 04050-45-7 8.55 10.58 90.470 t-1,2-Dimethylcyclopentane 00822-50-4 2.79 8.58 23.992 Ethylbenzene 00100-41-4 2.96 8.30 24.591 1,2,3-Trimethylbenzene 00526-73-8 11.94 8.25 98.453 3-Methylheptane 00589-81-1 1.12 8.11 9.123 2,2-Dimethylbutane 00075-83-2 1.11 8.02 8.911 Vehicle 220b - Fuel 9 psi E0 - Dynamic - Test 25789 Non Zero Mass Species Sorted By VOC

## E

- 188 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 9 psi E0 - Dynamic - Test 25789 Non Zero Mass Species Sorted By VOC

1-Methylcyclopentene 00693-89-0 12.45 7.71 96.014 2-Methyl-2-pentene 00625-27-4 11.03 6.97 76.909 c-1,3-Dimethylcyclopentane 02532-58-3 2.79 6.85 19.131 Methylcyclohexane 00108-87-2 1.56 6.78 10.541 3-Methyl-c-2-pentene 00922-62-3 12.52 6.59 82.532 Cyclopentene 00142-29-0 6.69 6.52 43.578 2,2-Dimethylpentane 00590-35-2 1.04 6.13 6.393 n-Octane 00111-65-9 0.80 5.67 4.516 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 5.34 62.538 2-Methylheptane 00592-27-8 0.97 4.84 4.683 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.54 29.964

Total 2380.7 6653.4 2.795

No MIR available, use weighted average of 2.7947 

### continued

## E

- 189 Species CAS No. MIR Composite VOC

mg Ozone mg Cyclohexane 00110-82-7 1.14 2643.58 3006.714 2-Methylbutane (Isopentane) 00078-78-4 1.35 2560.63 3469.363 Toluene 00108-88-3 3.93 1916.57 7522.592 n-Butane 00106-97-8 1.08 1875.86 2020.143 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1562.98 1874.200 n-Hexane 00110-54-3 1.13 980.68 1112.754 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 910.28 1272.376 3-Methylpentane 00096-14-0 1.69 648.42 1096.390 2,3,4-Trimethylpentane 00565-75-3 0.95 639.78 607.049 2,3-Dimethylbutane 00079-29-8 0.90 481.07 432.339 Methylcyclopentane 00096-37-7 2.05 403.11 826.281 2,4-Dimethylpentane 00108-08-7 1.46 307.60 448.886 n-Pentane 00109-66-0 1.21 285.38 346.713 2,2,5-Trimethylhexane 03522-94-9 1.05 264.19 278.202 2-Methyl-2-butene 00513-35-9 14.20 259.61 3685.166 2,4-Dimethylhexane 00589-43-5 1.61 259.46 416.578 2,3-Dimethylpentane 00565-59-3 1.25 250.68 312.927 2-Methylhexane 00591-76-4 1.09 249.85 271.132 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 230.04 1784.097 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 227.46 725.803 Benzene 00071-43-2 0.69 216.35 150.224 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 190.62 306.007 t-2-Pentene 00646-04-8 10.47 186.84 1956.837 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 139.34 152.175 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 134.72 723.366 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 116.89 863.338 2-Methyl-1-butene 00563-46-2 6.38 108.96 695.021 c-2-Pentene 00627-20-3 10.28 102.93 1058.279 n-Heptane 00142-82-5 0.97 102.71 99.194 t-2-Hexene 04050-45-7 8.55 102.09 872.758 3-Methyl-t-2-pentene 00616-12-6 11.66 100.99 1177.529 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 91.64 485.539 3-Methyl-c-2-pentene 00922-62-3 12.52 79.20 991.387 1-Methylcyclopentene 00693-89-0 12.45 78.94 983.143 2-Methyl-2-pentene 00625-27-4 11.03 76.89 848.310 ortho-Xylene 00095-47-6 7.58 71.30 540.145 2,2-Dimethylbutane 00075-83-2 1.11 70.51 78.350 Methylcyclohexane 00108-87-2 1.56 68.87 107.119 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 61.04 714.439 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 59.85 395.408 t-1,2-Dimethylcyclopentane 00822-50-4 2.43 57.32 139.397 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 55.08 242.007 1,3,5-Trimethylbenzene 00108-67-8 11.75 53.20 625.384 Ethylbenzene 00100-41-4 2.96 46.59 138.042 Vehicle 220b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7657 Non Zero Mass Species Sorted By VOC

## E

- 190 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7657 Non Zero Mass Species Sorted By VOC

3-Methylheptane 00589-81-1 1.12 45.74 51.435 c-1,3-Dimethylcyclopentane 02532-58-3 2.43 43.12 104.879 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 42.72 236.717 2,2-Dimethylpentane 00590-35-2 1.04 41.75 43.552 Cyclopentene 00142-29-0 6.69 40.07 267.923 2-Methylheptane 00592-27-8 0.97 37.77 36.528 2,3,5-Trimethylhexane 01069-53-0 1.12 36.96 41.403 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 32.03 185.086 n-Propylbenzene 00103-65-1 1.96 31.02 60.784 Unknown #16 2.43 30.74 74.756 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 27.90 218.631 Unknown #5 2.43 27.82 67.658 2,2,3-Trimethylbutane 00464-06-2 1.05 27.03 28.489 c-2-Butene 00590-18-1 14.26 25.69 366.299 Unknown #13 2.43 25.22 61.328 n-Octane 00111-65-9 0.80 24.50 19.510 3,5-Dimethylheptane 00926-82-9 1.42 21.65 30.814 1-Methyl-3-Propylbenzene 01074-43-7 7.08 21.10 149.450 3,3-Dimethylpentane 00562-49-2 1.12 19.22 21.501 4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 19.13 84.333 1-Nonene 00124-11-8 2.49 18.27 45.552 Isopropylbenzene (Cumene) 00098-82-8 2.43 16.68 40.569 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 15.26 58.935 c-1,3-Dimethylcyclohexane 00638-04-0 2.43 13.16 32.011 1-Methyl-2-Propylbenzene 01074-17-5 5.43 12.74 69.217 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 12.63 100.326 4-Methyl-t-2-pentene 00674-76-0 8.04 11.84 95.172 c-2-Heptene 06443-92-1 7.08 11.62 82.195 4-Methyloctane 02216-34-4 0.85 10.95 9.285 3,3-Dimethylhexane 00563-16-6 1.15 10.20 11.750 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 10.07 63.469 1,4-Diethylbenzene 00105-05-5 4.39 10.01 43.930 Unknown #8 2.43 9.65 23.458 t-2-Nonene 06434-78-2 2.43 9.55 23.237 Indan 00496-11-7 3.23 9.50 30.729 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 9.20 7.857 3-Methyloctane 02216-33-3 0.88 8.89 7.868 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.43 8.64 21.015 t-3-Heptene 14686-14-7 6.17 7.93 48.926 1,1-Dimethylcyclohexane 00590-66-9 1.12 7.74 8.626 2,4-Dimethylheptane 02213-23-2 1.26 7.68 9.718 3-Methylnonane 2.43 7.56 18.381 

### continued

## E

- 191 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7657 Non Zero Mass Species Sorted By VOC

t-4-Octene 14850-23-8 4.69 7.39 34.647 n-Decane 00124-18-5 0.59 7.29 4.307 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 6.96 45.553 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 6.05 45.571 1-Heptene 00592-76-7 4.29 5.78 24.769 1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 5.77 58.588 n-Nonane 00111-84-2 0.68 5.71 3.898 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 5.47 6.476 Unknown #3 2.43 5.30 12.892 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 5.12 42.865 Unknown #6

. 2.43 4.96 12.074 t-1,4-Dimethylcyclohexane 02207-04-7 2.43 4.39 10.680 Unknown #9 2.43 4.36 10.594 sec-Butylbenzene 00135-98-8 2.29 4.19 9.596 1,3-Diethylbenzene 00141-93-5 7.08 3.76 26.645 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 3.65 27.512 Unknown #12 2.43 3.45 8.398 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 3.30 12.617 3-Ethyl-c-2-Pentene 00816-79-5 9.76 3.22 31.463 Unknown #10 2.43 2.87 6.971 Unknown #1 2.43 2.77 6.747 1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 2.66 20.040 Isobutylbenzene 00538-93-2 2.43 2.58 6.284 Unknown #14 2.43 2.47 6.000 c-1,2-Dimethylcyclohexane 02207-01-4 2.43 2.40 5.836 2-Methyl-1,3-butadiene 00078-79-5 10.48 2.40 25.140 c-2-Octene 07642-04-8 2.43 2.30 5.606 Unknown #4 2.43 2.18 5.291 1,2,3,5-Tetramethylbenzene 00527-53-7 9.26 2.03 18.779 n-Undecane 01120-21-4 0.52 1.98 1.033 Unknown #15 2.43 1.77 4.294 Unknown #7 2.43 1.60 3.895 2,2-Dimethyloctane 15869-87-1 0.76 1.48 1.119 Unknown #11 2.43 1.41 3.435 c- & t-4-Nonene 02198-23-4 4.42 1.38 6.097 Naphthalene 00091-20-3 3.28 1.26 4.141 1,2-Diethylbenzene 00135-01-3 5.43 1.20 6.530 t-2-Octene & t-1,2-DiMeCyHexane 13389-42-9+06876-23-9 5.92 0.82 4.831 Unknown #18 2.43 0.79 1.918 1-Undecene 00821-95-4 1.77 0.72 1.281 Unknown #17 2.43 0.71 1.726 Unknown #20 2.43 0.49 1.187 1,3-Butadiene 00106-99-0 12.45 0.42 5.224

Total 20327.8 49439.0 2.432

No MIR available, use weighted average of 2.4321 

### continued

## E

- 192 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 4755.33 6442.941 n-Butane 00106-97-8 1.08 2804.48 3020.183 Cyclohexane 00110-82-7 1.14 947.18 1077.287 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 621.17 868.257 n-Hexane 00110-54-3 1.13 484.59 549.854 n-Pentane 00109-66-0 1.21 410.06 498.199 3-Methylpentane 00096-14-0 1.69 387.85 655.811 Toluene 00108-88-3 3.93 372.27 1461.151 2,3-Dimethylbutane 00079-29-8 0.90 355.33 319.334 2-Methyl-2-butene 00513-35-9 14.20 324.01 4599.304 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 301.05 360.994 t-2-Pentene 00646-04-8 10.47 250.71 2625.789 Methylcyclopentane 00096-37-7 2.05 184.42 378.029 2-Methyl-1-butene 00563-46-2 6.38 171.45 1093.593 c-2-Pentene 00627-20-3 10.28 136.37 1402.106 Benzene 00071-43-2 0.69 106.54 73.980 2,4-Dimethylpentane 00108-08-7 1.46 106.52 155.451 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 100.97 1181.827 t-2-Butene 00624-64-6 15.20 100.03 1520.254 2-Methylpropane 00075-28-5 1.18 85.84 101.004 2,3,4-Trimethylpentane 00565-75-3 0.95 85.48 81.106 c-2-Butene 00590-18-1 14.26 80.09 1142.038 2,2-Dimethylbutane 00075-83-2 1.11 67.79 75.333 2,3-Dimethylpentane 00565-59-3 1.25 64.83 80.930 2-Methylhexane 00591-76-4 1.09 63.09 68.467 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 55.59 177.379 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 55.45 293.784 t-2-Hexene 04050-45-7 8.55 51.07 436.554 3-Methyl-t-2-pentene 00616-12-6 11.66 50.32 586.652 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 48.47 384.874 Cyclopentene 00142-29-0 6.69 41.68 278.641 2-Methyl-2-pentene 00625-27-4 11.03 39.73 438.373 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 38.65 299.777 2,4-Dimethylhexane 00589-43-5 1.61 38.17 61.289 3-Methyl-c-2-pentene 00922-62-3 12.52 35.89 449.291 1-Methylcyclopentene 00693-89-0 12.45 31.28 389.566 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 29.72 196.364 3-Methyl-1-butene 00563-45-1 6.85 29.26 200.602 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 27.02 43.375 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 25.91 149.689 2,2,5-Trimethylhexane 03522-94-9 1.05 25.85 27.217 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 23.67 127.097 n-Heptane 00142-82-5 0.97 20.24 19.545 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 19.56 144.444 Vehicle 220b - Fuel 7 psi E0 - 86 ° F Static - Test 7677 Non Zero Mass Species Sorted By VOC

## E

- 193 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E0 - 86 ° F Static - Test 7677 Non Zero Mass Species Sorted By VOC

2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 18.02 19.684 2,2-Dimethylpentane 00590-35-2 1.04 15.21 15.867 t-1,2-Dimethylcyclopentane 00822-50-4 2.47 14.33 35.462 Methylcyclohexane 00108-87-2 1.56 13.88 21.584 Propane 00074-98-6 0.46 12.18 5.566 ortho-Xylene 00095-47-6 7.58 11.75 89.001 c-1,3-Dimethylcyclopentane 02532-58-3 2.47 11.09 27.448 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 10.96 48.171 2,2,3-Trimethylbutane 00464-06-2 1.05 9.83 10.358 1,3,5-Trimethylbenzene 00108-67-8 11.75 8.91 104.686 Ethylbenzene 00100-41-4 2.96 7.71 22.846 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 6.71 37.180 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 6.23 48.793 3,3-Dimethylpentane 00562-49-2 1.12 5.94 6.647 n-Propylbenzene 00103-65-1 1.96 5.02 9.845 3-Methylheptane 00589-81-1 1.12 4.75 5.346 2-Methylheptane 00592-27-8 0.97 4.75 4.593 Unknown #1 2.47 3.83 9.486 2,3,5-Trimethylhexane 01069-53-0 1.12 3.78 4.230 Unknown #5 2.47 3.68 9.114 1,2,3-Trimethylbenzene 00526-73-8 11.94 3.44 41.119 2-Methyl-1,3-butadiene 00078-79-5 10.48 3.43 35.917 1-Methyl-3-Propylbenzene 01074-43-7 7.08 3.22 22.771 c-2-Heptene 06443-92-1 7.08 3.08 21.773 1,4-Diethylbenzene 00105-05-5 4.39 2.93 12.842 Unknown #16 2.47 2.84 7.037 1-Methyl-2-Propylbenzene 01074-17-5 5.43 2.74 14.882 n-Octane 00111-65-9 0.80 2.45 1.953 Unknown #13 2.47 2.19 5.412 c-1,3-Dimethylcyclohexane 00638-04-0 2.47 1.97 4.879 3,5-Dimethylheptane 00926-82-9 1.42 1.89 2.696 t-3-Heptene 14686-14-7 6.17 1.77 10.938 Indan 00496-11-7 3.23 1.76 5.679 Isopropylbenzene (Cumene) 00098-82-8 2.47 1.62 4.011 3,3-Dimethylhexane 00563-16-6 1.15 1.60 1.839 1-Nonene 00124-11-8 2.49 1.50 3.745 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.50 9.792 Unknown #3 2.47 1.34 3.307 n-Decane 00124-18-5 0.59 1.33 0.785 1-Heptene 00592-76-7 4.29 1.30 5.592 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 1.26 9.470 1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 1.26 12.762 

### continued

## E

- 194 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E0 - 86 ° F Static - Test 7677 Non Zero Mass Species Sorted By VOC

1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 1.23 9.243 4-Methyloctane 02216-34-4 0.85 1.13 0.955 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 1.08 6.796 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 1.05 8.796 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 1.02 0.872 2,4-Dimethylheptane 02213-23-2 1.26 0.92 1.164 1,1-Dimethylcyclohexane 00590-66-9 1.12 0.92 1.023 3-Methyloctane 02216-33-3 0.88 0.89 0.789 t-2-Nonene 06434-78-2 2.47 0.86 2.129 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.47 0.83 2.066 1,2-Diethylbenzene 00135-01-3 5.43 0.77 4.211 3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.76 7.439 sec-Butylbenzene 00135-98-8 2.29 0.75 1.712 t-4-Octene 14850-23-8 4.69 0.75 3.499 1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 0.71 5.387 Isobutylbenzene 00538-93-2 2.47 0.71 1.750 t-1,4-Dimethylcyclohexane 02207-04-7 2.47 0.68 1.685 Unknown #8 2.47 0.67 1.656 3-Methylnonane 2.47 0.61 1.522 Unknown #6

. 2.47 0.60 1.495 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 0.59 0.698 n-Nonane 00111-84-2 0.68 0.58 0.394 1,3-Butadiene 00106-99-0 12.45 0.48 5.925 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.44 1.689 1,3-Diethylbenzene 00141-93-5 7.08 0.40 2.835 Unknown #4 2.47 0.20 0.503 1-Butyne 00107-00-6 6.05 0.15 0.893 n-Undecane 01120-21-4 0.52 0.01 0.004

Total 14299.8 35390.0 2.475

No MIR available, use weighted average of 2.4749 

### continued

## E

- 195 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 8764.59 11875.037 n-Butane 00106-97-8 1.08 4859.64 5233.408 Cyclohexane 00110-82-7 1.14 2002.13 2277.155 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1243.11 1737.602 n-Hexane 00110-54-3 1.13 1001.50 1136.376 Toluene 00108-88-3 3.93 856.61 3362.204 3-Methylpentane 00096-14-0 1.69 784.45 1326.408 n-Pentane 00109-66-0 1.21 777.45 944.548 2,3-Dimethylbutane 00079-29-8 0.90 701.05 630.032 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 669.74 803.101 2-Methyl-2-butene 00513-35-9 14.20 622.22 8832.412 t-2-Pentene 00646-04-8 10.47 478.46 5011.111 Methylcyclopentane 00096-37-7 2.05 380.82 780.590 2-Methyl-1-butene 00563-46-2 6.38 321.47 2050.481 c-2-Pentene 00627-20-3 10.28 259.21 2665.056 2,4-Dimethylpentane 00108-08-7 1.46 223.75 326.528 Benzene 00071-43-2 0.69 222.99 154.832 2,3,4-Trimethylpentane 00565-75-3 0.95 197.80 187.675 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 182.54 2136.613 t-2-Butene 00624-64-6 15.20 173.16 2631.622 2-Methylpropane 00075-28-5 1.18 145.88 171.641 c-2-Butene 00590-18-1 14.26 140.52 2003.758 2,3-Dimethylpentane 00565-59-3 1.25 139.41 174.023 2-Methylhexane 00591-76-4 1.09 136.67 148.308 2,2-Dimethylbutane 00075-83-2 1.11 130.26 144.744 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 121.08 386.346 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 111.34 589.945 t-2-Hexene 04050-45-7 8.55 104.95 897.210 3-Methyl-t-2-pentene 00616-12-6 11.66 103.39 1205.434 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 88.68 687.753 2,4-Dimethylhexane 00589-43-5 1.61 87.44 140.389 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 82.16 652.441 2-Methyl-2-pentene 00625-27-4 11.03 81.05 894.128 Cyclopentene 00142-29-0 6.69 80.05 535.205 3-Methyl-c-2-pentene 00922-62-3 12.52 74.65 934.484 1-Methylcyclopentene 00693-89-0 12.45 64.97 809.151 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 62.40 100.167 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 60.71 401.110 2,2,5-Trimethylhexane 03522-94-9 1.05 60.21 63.401 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 53.31 286.254 3-Methyl-1-butene 00563-45-1 6.85 52.13 357.334 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 49.14 283.915 n-Heptane 00142-82-5 0.97 46.07 44.496 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 41.17 44.963 Vehicle 220b - Fuel 7 psi E0 - 105 ° F Static - Test 7680 Non Zero Mass Species Sorted By VOC

## E

- 196 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E0 - 105 ° F Static - Test 7680 Non Zero Mass Species Sorted By VOC

1-Methyl-3-Ethylbenzene 00620-14-4 7.39 34.81 257.119 2,2-Dimethylpentane 00590-35-2 1.04 31.12 32.463 2,2-DiMeHexane 00590-73-8 0.94 30.50 28.708 t-1,2-Dimethylcyclopentane 00822-50-4 2.49 30.41 75.650 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 25.50 112.051 ortho-Xylene 00095-47-6 7.58 25.49 193.083 c-1,3-Dimethylcyclopentane 02532-58-3 2.49 24.11 59.989 2,2,3-Trimethylbutane 00464-06-2 1.05 19.96 21.034 1,3,5-Trimethylbenzene 00108-67-8 11.75 18.93 222.525 Ethylbenzene 00100-41-4 2.96 18.75 55.552 Propane 00074-98-6 0.46 17.08 7.807 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 15.81 87.588 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 13.54 106.125 3,3-Dimethylpentane 00562-49-2 1.12 12.18 13.631 3-Methylheptane 00589-81-1 1.12 11.62 13.065 n-Propylbenzene 00103-65-1 1.96 11.09 21.728 2-Methylheptane 00592-27-8 0.97 10.73 10.378 2,3,5-Trimethylhexane 01069-53-0 1.12 8.22 9.211 1,2,3-Trimethylbenzene 00526-73-8 11.94 8.12 96.945 Unknown #5 2.49 7.44 18.522 1-Methyl-3-Propylbenzene 01074-43-7 7.08 6.90 48.873 Unknown #16 2.49 6.77 16.834 Unknown #1 2.49 6.51 16.201 c-2-Heptene 06443-92-1 7.08 6.38 45.146 2-Methyl-1,3-butadiene 00078-79-5 10.48 5.97 62.552 n-Octane 00111-65-9 0.80 5.77 4.594 Indan 00496-11-7 3.23 4.77 15.423 3,5-Dimethylheptane 00926-82-9 1.42 4.70 6.691 Unknown #13 2.49 4.20 10.457 Isopropylbenzene (Cumene) 00098-82-8 2.49 4.09 10.165 1,4-Diethylbenzene 00105-05-5 4.39 4.01 17.618 t-3-Heptene 14686-14-7 6.17 3.92 24.203 3,3-Dimethylhexane 00563-16-6 1.15 3.34 3.850 1-Methyl-2-Propylbenzene 01074-17-5 5.43 3.21 17.438 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 3.20 20.966 1-Nonene 00124-11-8 2.49 2.97 7.402 c-1,3-Dimethylcyclohexane 00638-04-0 2.49 2.91 7.235 1-Heptene 00592-76-7 4.29 2.89 12.404 Unknown #3 2.49 2.77 6.884 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 2.54 2.165 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.49 2.47 6.155 Unknown #6

. 2.49 2.46 6.112 

### continued

## E

- 197 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E0 - 105 ° F Static - Test 7680 Non Zero Mass Species Sorted By VOC

3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 2.28 19.076 4-Methyloctane 02216-34-4 0.85 2.02 1.718 3-Methyloctane 02216-33-3 0.88 1.95 1.728 1,1-Dimethylcyclohexane 00590-66-9 1.12 1.91 2.134 1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 1.88 19.101 2,4-Dimethylheptane 02213-23-2 1.26 1.79 2.268 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 1.70 12.806 Unknown #8 2.49 1.67 4.151 n-Decane 00124-18-5 0.59 1.62 0.959 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 1.60 6.123 sec-Butylbenzene 00135-98-8 2.29 1.54 3.525 3-Methylnonane 2.49 1.53 3.819 3-Ethyl-c-2-Pentene 00816-79-5 9.76 1.52 14.836 t-2-Nonene 06434-78-2 2.49 1.48 3.680 1,2,3,5-Tetramethylbenzene 00527-53-7 9.26 1.35 12.506 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 1.31 8.240 t-1,4-Dimethylcyclohexane 02207-04-7 2.49 1.25 3.099 Isobutylbenzene 00538-93-2 2.49 1.12 2.787 n-Nonane 00111-84-2 0.68 1.09 0.745 1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 1.02 7.716 1,3-Butadiene 00106-99-0 12.45 0.98 12.253 1,3-Diethylbenzene 00141-93-5 7.08 0.84 5.927 c-1,2-Dimethylcyclohexane 02207-01-4 2.49 0.82 2.033 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 0.80 0.947 Unknown #9 2.49 0.80 1.990 1,2,4,5-Tetramethylbenzene 00095-93-2 9.26 0.67 6.186 c-2-Octene 07642-04-8 2.49 0.66 1.635 4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 0.62 2.753 Unknown #12 2.49 0.49 1.207 Unknown #4 2.49 0.42 1.044 n-Butylbenzene 00104-51-8 2.29 0.36 0.815 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.28 2.080 n-Undecane 01120-21-4 0.52 0.25 0.132 2,2-Dimethyloctane 15869-87-1 0.76 0.20 0.148

Total 27348.3 68042.1 2.488

No MIR available, use weighted average of 2.4880 

### continued

## E

- 198 Species CAS No. MIR Composite VOC

mg Ozone mg Cyclohexane 00110-82-7 1.14 385.12 438.025 2-Methylbutane (Isopentane) 00078-78-4 1.35 371.97 503.974 Toluene 00108-88-3 3.93 351.94 1381.382 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 199.68 1072.127 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 196.81 235.994 n-Butane 00106-97-8 1.08 143.43 154.461 n-Hexane 00110-54-3 1.13 122.85 139.394 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 114.17 159.587 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 106.45 825.559 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 94.05 694.666 2,3,4-Trimethylpentane 00565-75-3 0.95 88.91 84.360 3-Methylpentane 00096-14-0 1.69 80.49 136.094 1,3,5-Trimethylbenzene 00108-67-8 11.75 68.09 800.358 2,3-Dimethylbutane 00079-29-8 0.90 65.49 58.855 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 58.20 255.720 Methylcyclopentane 00096-37-7 2.05 51.19 104.920 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 44.35 245.761 2,4-Dimethylhexane 00589-43-5 1.61 42.97 68.998 n-Pentane 00109-66-0 1.21 41.09 49.916 2,2,5-Trimethylhexane 03522-94-9 1.05 40.84 43.009 ortho-Xylene 00095-47-6 7.58 38.61 292.515 2,4-Dimethylpentane 00108-08-7 1.46 37.61 54.882 1,2,3-Trimethylbenzene 00526-73-8 11.94 37.49 447.540 2-Methyl-2-butene 00513-35-9 14.20 36.06 511.918 Benzene 00071-43-2 0.69 34.66 24.065 2-Methylhexane 00591-76-4 1.09 33.50 36.352 2,3-Dimethylpentane 00565-59-3 1.25 32.54 40.619 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 32.38 103.320 1-Methyl-3-Propylbenzene 01074-43-7 7.08 32.04 226.874 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 31.29 50.239 n-Propylbenzene 00103-65-1 1.96 29.23 57.280 Ethylbenzene 00100-41-4 2.96 28.70 85.018 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 25.25 27.573 t-2-Pentene 00646-04-8 10.47 23.93 250.683 Unknown #16 3.47 22.78 78.988 Indan 00496-11-7 3.23 22.56 72.974 1-Methyl-2-Propylbenzene 01074-17-5 5.43 22.10 120.098 n-Heptane 00142-82-5 0.97 18.55 17.912 c-2-Pentene 00627-20-3 10.28 18.19 187.043 2-Methyl-1-butene 00563-46-2 6.38 16.70 106.517 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 16.17 121.897 1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 16.08 163.373 t-2-Hexene 04050-45-7 8.55 15.50 132.535 3-Methyl-t-2-pentene 00616-12-6 11.66 15.37 179.197 Vehicle 220b - Fuel 7 psi E0 - Dynamic - Test 25794 Non Zero Mass Species Sorted By VOC

## E

- 199 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E0 - Dynamic - Test 25794 Non Zero Mass Species Sorted By VOC

2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 14.81 78.469 1,4-Diethylbenzene 00105-05-5 4.39 13.00 57.054 3-Methyl-c-2-pentene 00922-62-3 12.52 12.48 156.261 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 12.47 145.965 n-Decane 00124-18-5 0.59 12.41 7.332 2-Methyl-2-pentene 00625-27-4 11.03 12.19 134.512 2,2-DiMeHexane 00590-73-8 0.94 11.86 11.162 t-2-Butene 00624-64-6 15.20 11.05 167.884 1-Methylcyclopentene 00693-89-0 12.45 10.90 135.760 2,2-Dimethylbutane 00075-83-2 1.11 10.89 12.096 4-Methyl-t-2-pentene 00674-76-0 8.04 9.93 79.853 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 9.87 65.180 t-1,2-Dimethylcyclopentane 00822-50-4 3.47 9.69 33.596 c-2-Butene 00590-18-1 14.26 9.46 134.928 3-Methylheptane 00589-81-1 1.12 8.28 9.305 2,3,5-Trimethylhexane 01069-53-0 1.12 8.00 8.961 n-Octane 00111-65-9 0.80 7.83 6.234 c-1,3-Dimethylcyclopentane 02532-58-3 3.47 7.27 25.206 Cyclopentene 00142-29-0 6.69 7.19 48.040 Isopropylbenzene (Cumene) 00098-82-8 3.47 6.98 24.183 1,3-Diethylbenzene 00141-93-5 7.08 6.82 48.287 3-Methylnonane 3.47 6.78 23.518 2-Methylheptane 00592-27-8 0.97 6.75 6.526 Styrene 00100-42-5 1.66 6.21 10.321 2,2-Dimethylpentane 00590-35-2 1.04 6.03 6.288 n-Nonane 00111-84-2 0.68 5.92 4.042 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 5.74 33.179 2-Methylpropane 00075-28-5 1.18 5.64 6.634 Unknown #18 3.47 5.58 19.333 n-Butylbenzene 00104-51-8 2.29 5.31 12.170 sec-Butylbenzene 00135-98-8 2.29 5.20 11.924 1-Undecene 00821-95-4 1.77 5.03 8.924 Unknown #5 3.47 4.97 17.215 Ethylcyclohexane 01678-91-7 1.35 4.90 6.587 2,2,3-Trimethylbutane 00464-06-2 1.05 4.75 5.006 1-Nonene 00124-11-8 2.49 4.66 11.605 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 4.65 17.766 c-2-Heptene 06443-92-1 7.08 4.63 32.729 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 4.21 32.961 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.15 32.941 Unknown #24 3.47 4.11 14.244 4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 3.96 17.442 

### continued

## E

- 200 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E0 - Dynamic - Test 25794 Non Zero Mass Species Sorted By VOC

n-Undecane 01120-21-4 0.52 3.70 1.930 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 3.58 26.990 4-Methyloctane 02216-34-4 0.85 3.58 3.034 3-Methyl-1-butene 00563-45-1 6.85 3.49 23.934 1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 3.43 25.884 Unknown #6

. 3.47 3.30 11.450 Naphthalene 00091-20-3 3.28 3.24 10.638 c-1,3-Dimethylcyclohexane 00638-04-0 3.47 3.12 10.809 3,3-Dimethylpentane 00562-49-2 1.12 3.01 3.372 Isobutylbenzene 00538-93-2 3.47 2.99 10.375 1,1-Dimethylcyclohexane 00590-66-9 1.12 2.47 2.756 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.47 2.47 8.568 3,3-Dimethylhexane 00563-16-6 1.15 2.40 2.762 3-Methyloctane 02216-33-3 0.88 2.35 2.081 1,2-Diethylbenzene 00135-01-3 5.43 2.08 11.324 1-Heptene 00592-76-7 4.29 1.78 7.649 2,4-Dimethylheptane 02213-23-2 1.26 1.78 2.255 Unknown #8 3.47 1.73 6.005 Unknown #20 3.47 1.56 5.393 t-3-Heptene 14686-14-7 6.17 1.52 9.377 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 1.39 1.646 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 1.30 1.107 2-Methyl-1,3-butadiene 00078-79-5 10.48 1.25 13.100 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 1.23 8.072 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 1.01 6.385 t-1,4-Dimethylcyclohexane 02207-04-7 3.47 0.92 3.203 Unknown #1 3.47 0.69 2.389 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.66 5.535

Total 3689.9 12792.2 3.467

No MIR available, use weighted average of 3.4668 

### continued

## E

- 201 Species CAS No. MIR Composite VOC

mg Ozone mg Cyclohexane 00110-82-7 1.14 2781.83 3163.949 2-Methylbutane (Isopentane) 00078-78-4 1.35 2708.35 3669.503 Toluene 00108-88-3 3.93 2047.86 8037.885 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1622.66 1945.756 n-Hexane 00110-54-3 1.13 1029.43 1168.072 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 964.70 1348.439 n-Butane 00106-97-8 1.08 687.61 740.501 3-Methylpentane 00096-14-0 1.69 678.06 1146.507 2,3,4-Trimethylpentane 00565-75-3 0.95 675.28 640.725 2,3-Dimethylbutane 00079-29-8 0.90 502.21 451.336 Methylcyclopentane 00096-37-7 2.05 424.33 869.782 2,4-Dimethylpentane 00108-08-7 1.46 319.31 465.972 n-Pentane 00109-66-0 1.21 308.39 374.676 2,2,5-Trimethylhexane 03522-94-9 1.05 281.46 296.395 2-Methyl-2-butene 00513-35-9 14.20 277.04 3932.600 2,4-Dimethylhexane 00589-43-5 1.61 273.19 438.626 2-Methylhexane 00591-76-4 1.09 262.79 285.175 2,3-Dimethylpentane 00565-59-3 1.25 261.52 326.467 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 251.66 1951.697 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 239.29 763.565 Benzene 00071-43-2 0.69 230.34 159.937 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 200.68 322.163 t-2-Pentene 00646-04-8 10.47 197.73 2070.893 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 147.98 161.607 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 137.12 736.236 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 129.98 960.035 2-Methyl-1-butene 00563-46-2 6.38 115.39 736.039 n-Heptane 00142-82-5 0.97 114.06 110.154 c-2-Pentene 00627-20-3 10.28 108.89 1119.567 t-2-Hexene 04050-45-7 8.55 106.56 910.942 3-Methyl-t-2-pentene 00616-12-6 11.66 105.14 1225.831 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 99.40 526.683 2,2-DiMeHexane 00590-73-8 0.94 87.94 82.771 3-Methyl-c-2-pentene 00922-62-3 12.52 83.41 1044.084 1-Methylcyclopentene 00693-89-0 12.45 83.19 1036.094 2-Methyl-2-pentene 00625-27-4 11.03 80.28 885.656 ortho-Xylene 00095-47-6 7.58 77.18 584.743 2,2-Dimethylbutane 00075-83-2 1.11 73.59 81.769 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 64.94 760.100 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 62.64 413.807 t-1,2-Dimethylcyclopentane 00822-50-4 2.55 60.49 154.069 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 56.51 248.325 1,3,5-Trimethylbenzene 00108-67-8 11.75 55.08 647.405 Ethylbenzene 00100-41-4 2.96 51.55 152.738 Vehicle 220b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7686 Non Zero Mass Species Sorted By VOC

## E

- 202 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7686 Non Zero Mass Species Sorted By VOC

3-Methylheptane 00589-81-1 1.12 48.91 54.991 c-1,3-Dimethylcyclopentane 02532-58-3 2.55 45.86 116.797 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 44.77 248.123 2,2-Dimethylpentane 00590-35-2 1.04 43.43 45.301 Cyclopentene 00142-29-0 6.69 42.07 281.299 2-Methylheptane 00592-27-8 0.97 40.88 39.541 2,3,5-Trimethylhexane 01069-53-0 1.12 40.14 44.962 Unknown #16 2.55 34.81 88.655 n-Propylbenzene 00103-65-1 1.96 33.47 65.583 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 33.27 192.238 t-2-Butene 00624-64-6 15.20 31.11 472.786 Unknown #5 2.55 29.42 74.943 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 29.27 229.309 2,2,3-Trimethylbutane 00464-06-2 1.05 28.28 29.804 Unknown #13 2.55 28.17 71.750 n-Octane 00111-65-9 0.80 28.05 22.333 c-2-Butene 00590-18-1 14.26 27.58 393.341 1-Methyl-3-Propylbenzene 01074-43-7 7.08 24.60 174.232 3,5-Dimethylheptane 00926-82-9 1.42 24.30 34.589 3,3-Dimethylpentane 00562-49-2 1.12 20.27 22.673 1-Nonene 00124-11-8 2.49 20.25 50.466 2-Methylpropane 00075-28-5 1.18 19.01 22.371 1,2,3-Trimethylbenzene 00526-73-8 11.94 18.87 225.237 Isopropylbenzene (Cumene) 00098-82-8 2.55 18.22 46.403 c-1,3-Dimethylcyclohexane 00638-04-0 2.55 14.49 36.919 3-Methyl-1-butene 00563-45-1 6.85 13.74 94.204 Unknown #6

. 2.55 13.55 34.503 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 13.24 105.107 4-Methyloctane 02216-34-4 0.85 12.88 10.923 c-2-Heptene 06443-92-1 7.08 12.32 87.155 1-Methyl-2-Propylbenzene 01074-17-5 5.43 11.92 64.785 Indan 00496-11-7 3.23 11.45 37.045 3-Methyloctane 02216-33-3 0.88 10.81 9.566 t-2-Nonene 06434-78-2 2.55 10.74 27.343 3,3-Dimethylhexane 00563-16-6 1.15 10.69 12.307 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 10.53 8.989 1,4-Diethylbenzene 00105-05-5 4.39 10.45 45.863 Unknown #8 2.55 9.67 24.617 n-Decane 00124-18-5 0.59 9.58 5.660 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.55 9.31 23.719 2,4-Dimethylheptane 02213-23-2 1.26 8.65 10.938 1,1-Dimethylcyclohexane 00590-66-9 1.12 8.60 9.584 

### continued

## E

- 203 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7686 Non Zero Mass Species Sorted By VOC

3-Methylnonane 2.55 8.49 21.618 t-3-Heptene 14686-14-7 6.17 8.37 51.625 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 7.29 47.685 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 7.21 54.349 1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 6.82 69.284 2,4-DiMeOctane+AlBenz+PrCyHexane 04032-94-4+00300-57-2+ 1.18 6.28 7.432 1-Heptene 00592-76-7 4.29 6.01 25.778 n-Nonane 00111-84-2 0.68 5.67 3.868 Unknown #3 2.55 5.49 13.984 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 5.34 44.723 1,3-Diethylbenzene 00141-93-5 7.08 5.04 35.723 t-1,4-Dimethylcyclohexane 02207-04-7 2.55 4.94 12.581 Unknown #9 2.55 4.74 12.080 sec-Butylbenzene 00135-98-8 2.29 4.69 10.750 Methane 00074-82-8 0.01 4.14 0.057 Unknown #12 2.55 3.66 9.315 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 3.64 13.897 3-Ethyl-c-2-Pentene 00816-79-5 9.76 3.39 33.053 n-Butylbenzene 00104-51-8 2.29 3.21 7.359 Propane 00074-98-6 0.46 3.18 1.454 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 3.14 23.657 Unknown #10 2.55 2.96 7.543 Isobutylbenzene 00538-93-2 2.55 2.95 7.503 1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 2.87 21.607 Unknown #14 2.55 2.75 7.009 Ethylene 00074-85-1 8.88 2.65 23.562 c-1,2-Dimethylcyclohexane 02207-01-4 2.55 2.49 6.350 c-2-Octene 07642-04-8 2.55 2.45 6.232 2-Methyl-1,3-butadiene 00078-79-5 10.48 2.44 25.541 4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 2.29 10.116 c- & t-4-Nonene 02198-23-4 4.42 2.21 9.787 n-Undecane 01120-21-4 0.52 1.88 0.983 Unknown #7 2.55 1.82 4.626 t-2-Octene & t-1,2-DiMeCyHexane 13389-42-9+06876-23-9 5.92 1.80 10.689 Unknown #15 2.55 1.73 4.417 1,2-Diethylbenzene 00135-01-3 5.43 1.65 8.947 1,2,3,5-Tetramethylbenzene 00527-53-7 9.26 1.63 15.111 2,2-Dimethyloctane 15869-87-1 0.76 1.48 1.118 Unknown #11 2.55 1.42 3.609 

### continued

## E

- 204 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 220b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7686 Non Zero Mass Species Sorted By VOC

Unknown #18 2.55 1.39 3.538 4-Methyl-t-2-pentene 00674-76-0 8.04 1.38 11.125 Naphthalene 00091-20-3 3.28 1.27 4.165 Unknown #4 2.55 1.10 2.810 1,2,4,5-Tetramethylbenzene 00095-93-2 9.26 0.85 7.896 Unknown #20 2.55 0.60 1.535 Unknown #19 2.55 0.51 1.292 Unknown #17 2.55 0.43 1.093 1,3-Butadiene 00106-99-0 12.45 0.36 4.511

Total 20242.7 51559.2 2.547

No MIR available, use weighted average of 2.5471 

### continued

## E

- 205 Test Fuel Test No. Bag THC mg GC as % of THC GC VOC

mg Ozone mg Reactivity Species Present 86 ° F E10 - 10 psi 7557 1592.1 85.9 1367.1 3249.9 2.377 57 Static E10 - 7 psi 7571 951.42 75.9 722.3 2179.9 3.018 65 E0 - 9 psi 7650 1390.71 89.8 1248.3 2750.8 2.204 66 E0 - 7 psi 7691 979.48 114.5 1121.8 2764.8 2.465 72

105 ° F E10 - 10 psi 7559 2131.5 92.0 1960.1 4768.7 2.433 79 Static E10 - 7 psi 7572 1354.2 93.7 1268.7 3796.8 2.993 76 E0 - 9 psi 7652 1823.3 100.0 1824.1 3993.6 2.189 66 E0 - 7 psi 7692 1351.9 115.3 1558.2 4073.8 2.614 103

Dynamic E10 - 10 psi 25778 158.8 97.8 155.3 519.8 3.347 54 E10 - 7 psi 25783 144.6 118.7 171.6 578.9 3.373 59 E0 - 9 psi 25790 192.8 161.7 311.8 851.8 2.732 55 E0 - 7 psi 25797 230.2 88.6 204.1 877.0 4.298 49

DHB E10 - 10 psi 7562 2254.5 86.6 1952.6 5269.2 2.699 90 Total E10 - 7 psi 7579 2189.4 85.0 1860.2 5643.5 3.034 104 E0 - 9 psi 7667 1788.4 90.9 1625.8 4353.4 2.678 83 E0 - 7 psi 7716 1593.2 103.2 1644.2 4729.0 2.876 92 

## Vehicle 221b

## E

- 206 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 507.38 546.399 2-Methylbutane (Isopentane) 00078-78-4 1.35 244.45 331.201 Ethanol 00064-17-5 1.45 112.02 162.308 n-Hexane 00110-54-3 1.13 53.33 60.513 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 47.74 66.732 n-Pentane 00109-66-0 1.21 38.87 47.229 3-Methylpentane 00096-14-0 1.69 33.41 56.489 2-Methyl-2-butene 00513-35-9 14.20 32.15 456.361 Toluene 00108-88-3 3.93 28.26 110.903 t-2-Pentene 00646-04-8 10.47 26.46 277.129 2,3-Dimethylbutane 00079-29-8 0.90 24.22 21.766 2-Methyl-1-butene 00563-46-2 6.38 19.05 121.508 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 16.89 20.256 Methylcyclopentane 00096-37-7 2.05 16.25 33.304 Cyclohexane 00110-82-7 1.14 16.17 18.394 c-2-Pentene 00627-20-3 10.28 14.57 149.764 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 13.65 159.727 c-2-Butene 00590-18-1 14.26 10.97 156.379 Benzene 00071-43-2 0.69 10.09 7.005 2,4-Dimethylpentane 00108-08-7 1.46 7.20 10.501 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.88 54.642 2-Methylpropane 00075-28-5 1.18 5.57 6.558 2-Methylhexane 00591-76-4 1.09 5.21 5.656 Methylcyclohexane 00108-87-2 1.56 5.16 8.021 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 5.10 26.998 t-2-Hexene 04050-45-7 8.55 4.90 41.861 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.87 15.546 Cyclopentene 00142-29-0 6.69 4.31 28.829 2,3,4-Trimethylpentane 00565-75-3 0.95 4.12 3.911 3-Methyl-t-2-pentene 00616-12-6 11.66 4.08 47.578 2,3-Dimethylpentane 00565-59-3 1.25 3.80 4.741 2-Methyl-2-pentene 00625-27-4 11.03 3.76 41.465 3-Methyl-c-2-pentene 00922-62-3 12.52 3.50 43.821 n-Heptane 00142-82-5 0.97 3.42 3.303 2,2-Dimethylbutane 00075-83-2 1.11 3.29 3.657 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 3.00 19.794 2,4-Dimethylhexane 00589-43-5 1.61 2.63 4.222 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.43 14.038 1-Methylcyclopentene 00693-89-0 12.45 2.40 29.841 2,2-Dimethylpentane 00590-35-2 1.04 1.98 2.069 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.85 2.978 2,2,5-Trimethylhexane 03522-94-9 1.05 1.32 1.389 t-1,2-Dimethylcyclopentane 00822-50-4 2.38 1.26 2.996 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.25 1.370 Vehicle 221b - Fuel 10 psi E10 - 86 ° F Static - Test 7557 Non Zero Mass Species Sorted By VOC

## E

- 207 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 10 psi E10 - 86 ° F Static - Test 7557 Non Zero Mass Species Sorted By VOC

n-Octane 00111-65-9 0.80 1.09 0.866 c-1,3-Dimethylcyclopentane 02532-58-3 2.38 1.00 2.387 2-Methylheptane 00592-27-8 0.97 0.86 0.836 2,2,3-Trimethylbutane 00464-06-2 1.05 0.85 0.901 3,3-Dimethylpentane 00562-49-2 1.12 0.83 0.932 c-1,3-Dimethylcyclohexane 00638-04-0 2.38 0.71 1.680 3-Methylheptane 00589-81-1 1.12 0.64 0.715 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.55 5.749 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.46 3.580 Unknown #5 2.38 0.26 0.625 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.25 0.970 t-1,4-Dimethylcyclohexane 02207-04-7 2.38 0.20 0.482 t-3-Heptene 14686-14-7 6.17 0.17 1.037

Total 1367.1 3249.9 2.377

No MIR available, use weighted average of 2.3773 

### continued

## E

- 208 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 654.61 704.963 2-Methylbutane (Isopentane) 00078-78-4 1.35 330.02 447.133 Ethanol 00064-17-5 1.45 199.28 288.754 n-Hexane 00110-54-3 1.13 80.10 90.882 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 69.35 96.933 n-Pentane 00109-66-0 1.21 53.77 65.332 Toluene 00108-88-3 3.93 49.46 194.113 3-Methylpentane 00096-14-0 1.69 48.75 82.430 2-Methyl-2-butene 00513-35-9 14.20 45.60 647.285 t-2-Pentene 00646-04-8 10.47 37.84 396.335 2,3-Dimethylbutane 00079-29-8 0.90 35.30 31.727 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 27.98 33.546 2-Methyl-1-butene 00563-46-2 6.38 25.93 165.410 Methylcyclopentane 00096-37-7 2.05 25.14 51.537 Cyclohexane 00110-82-7 1.14 24.77 28.177 c-2-Pentene 00627-20-3 10.28 20.58 211.612 Benzene 00071-43-2 0.69 15.99 11.101 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 15.19 177.840 c-2-Butene 00590-18-1 14.26 14.09 200.980 2,4-Dimethylpentane 00108-08-7 1.46 11.42 16.661 2-Methylhexane 00591-76-4 1.09 9.62 10.435 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 8.82 70.036 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.51 65.987 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 8.38 26.727 Methylcyclohexane 00108-87-2 1.56 7.88 12.255 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 7.69 40.730 2,3,4-Trimethylpentane 00565-75-3 0.95 7.54 7.157 t-2-Hexene 04050-45-7 8.55 7.41 63.364 2-Methylpropane 00075-28-5 1.18 6.78 7.979 2,3-Dimethylpentane 00565-59-3 1.25 6.54 8.161 n-Heptane 00142-82-5 0.97 6.22 6.005 Cyclopentene 00142-29-0 6.69 6.20 41.456 3-Methyl-t-2-pentene 00616-12-6 11.66 6.04 70.384 2-Methyl-2-pentene 00625-27-4 11.03 5.67 62.532 3-Methyl-c-2-pentene 00922-62-3 12.52 5.31 66.467 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.48 24.042 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.47 29.525 2,2-Dimethylbutane 00075-83-2 1.11 4.28 4.759 1-Methylcyclopentene 00693-89-0 12.45 3.91 48.731 2,4-Dimethylhexane 00589-43-5 1.61 3.55 5.700 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 3.33 19.258 2,2-Dimethylpentane 00590-35-2 1.04 2.78 2.896 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.66 4.272 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.56 11.235 Vehicle 221b - Fuel 10 psi E10 - 105 ° F Static - Test 7559 Non Zero Mass Species Sorted By VOC

## E

- 209 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 10 psi E10 - 105 ° F Static - Test 7559 Non Zero Mass Species Sorted By VOC

ortho-Xylene 00095-47-6 7.58 2.41 18.246 2,2,5-Trimethylhexane 03522-94-9 1.05 2.10 2.215 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.99 23.409 t-1,2-Dimethylcyclopentane 00822-50-4 2.43 1.99 4.842 n-Octane 00111-65-9 0.80 1.90 1.511 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.89 2.067 Ethylbenzene 00100-41-4 2.96 1.66 4.914 c-1,3-Dimethylcyclopentane 02532-58-3 2.43 1.64 3.978 2,2,3-Trimethylbutane 00464-06-2 1.05 1.41 1.491 Propane 00074-98-6 0.46 1.41 0.643 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.33 9.834 3,3-Dimethylpentane 00562-49-2 1.12 1.29 1.440 2-Methylheptane 00592-27-8 0.97 1.25 1.205 3-Methylheptane 00589-81-1 1.12 1.20 1.352 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.15 6.399 c-1,3-Dimethylcyclohexane 00638-04-0 2.43 0.92 2.242 n-Propylbenzene 00103-65-1 1.96 0.92 1.801 2,2-DiMeHexane 00590-73-8 0.94 0.80 0.754 n-Decane 00124-18-5 0.59 0.75 0.441 n-Nonane 00111-84-2 0.68 0.62 0.426 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.58 6.893 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.55 4.296 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.49 5.122 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.48 1.854 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.43 0.42 1.031 Unknown #5 2.43 0.41 1.005 t-3-Heptene 14686-14-7 6.17 0.36 2.224 Unknown #16 2.43 0.36 0.873 3,3-Dimethylhexane 00563-16-6 1.15 0.36 0.411 3,5-Dimethylheptane 00926-82-9 1.42 0.33 0.475 4-Methyloctane 02216-34-4 0.85 0.31 0.265 1-Nonene 00124-11-8 2.49 0.27 0.672 t-1,4-Dimethylcyclohexane 02207-04-7 2.43 0.25 0.619 2,3,5-Trimethylhexane 01069-53-0 1.12 0.25 0.283 Unknown #3 2.43 0.25 0.606

Total 1960.1 4768.7 2.433

No MIR available, use weighted average of 2.4329 

### continued

## E

- 210 Species CAS No. MIR Composite VOC

mg Ozone mg n-Propylbenzene 00103-65-1 1.96 35.68 69.925 Toluene 00108-88-3 3.93 18.49 72.586 Ethanol 00064-17-5 1.45 15.22 22.056 Methane 00074-82-8 0.01 9.22 0.128 Unknown #22

. 3.35 6.27 20.981 Benzene 00071-43-2 0.69 5.45 3.787 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.89 37.958 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.88 26.179 Propane 00074-98-6 0.46 3.47 1.588 1-Butyne 00107-00-6 6.05 3.03 18.355 ortho-Xylene 00095-47-6 7.58 2.57 19.460 2,3,5-Trimethylhexane 01069-53-0 1.12 2.49 2.787 Cyclohexane 00110-82-7 1.14 2.44 2.778 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.25 9.872 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 2.11 11.157 Indan 00496-11-7 3.23 2.07 6.692 2,2-DiMeHexane 00590-73-8 0.94 2.03 1.914 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.91 22.476 n-Hexane 00110-54-3 1.13 1.90 2.152 3-Methyl-c-2-pentene 00922-62-3 12.52 1.83 22.931 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.77 21.115 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.66 1.994 n-Decane 00124-18-5 0.59 1.63 0.963 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.60 10.573 1,3-Butadiene 00106-99-0 12.45 1.45 18.033 2,4-Dimethylhexane 00589-43-5 1.61 1.38 2.221 2-Methyl-2-pentene 00625-27-4 11.03 1.37 15.100 2,2-Dimethylpentane 00590-35-2 1.04 1.18 1.233 1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.11 7.827 3-Methyl-t-2-pentene 00616-12-6 11.66 1.01 11.784 2-Methylheptane 00592-27-8 0.97 0.94 0.910 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.91 5.033 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.91 9.504 n-Undecane 01120-21-4 0.52 0.89 0.467 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.85 0.932 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.77 5.775 c-1,3-Dimethylcyclopentane 02532-58-3 3.35 0.74 2.467 2,3,4-Trimethylpentane 00565-75-3 0.95 0.72 0.685 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.72 5.686 t-2-Hexene 04050-45-7 8.55 0.72 6.120 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.69 1.111 Methylcyclohexane 00108-87-2 1.56 0.66 1.025 3-Methylnonane 05911-04-6 0.66 0.56 0.367 2,2,5-Trimethylhexane 03522-94-9 1.05 0.52 0.552 Vehicle 221b - Fuel 10 psi E10 - Dynamic - Test 25778 Non Zero Mass Species Sorted By VOC

## E

- 211 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 10 psi E10 - Dynamic - Test 25778 Non Zero Mass Species Sorted By VOC

Ethylbenzene 00100-41-4 2.96 0.52 1.534 2-Methyl-1-butene 00563-46-2 6.38 0.50 3.184 c-2-Butene 00590-18-1 14.26 0.28 4.022 2-Methylhexane 00591-76-4 1.09 0.28 0.303 2,3-Dimethylpentane 00565-59-3 1.25 0.26 0.322 t-2-Pentene 00646-04-8 10.47 0.24 2.500 n-Octane 00111-65-9 0.80 0.15 0.122 n-Pentane 00109-66-0 1.21 0.04 0.054 Cyclopentene 00142-29-0 6.69 0.04 0.282 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.02 0.245

Total 155.3 519.8 3.347

No MIR available, use weighted average of 3.3471 

### continued

## E

- 212 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 405.47 436.652 Ethanol 00064-17-5 1.45 401.87 582.293 2-Methylbutane (Isopentane) 00078-78-4 1.35 204.81 277.497 Toluene 00108-88-3 3.93 144.31 566.423 n-Hexane 00110-54-3 1.13 94.53 107.256 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 58.08 81.188 n-Pentane 00109-66-0 1.21 46.82 56.882 2-Methyl-2-butene 00513-35-9 14.20 46.22 656.138 Benzene 00071-43-2 0.69 42.13 29.250 t-2-Pentene 00646-04-8 10.47 41.61 435.802 3-Methylpentane 00096-14-0 1.69 39.23 66.329 Cyclohexane 00110-82-7 1.14 36.84 41.905 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 27.82 33.355 2,3-Dimethylbutane 00079-29-8 0.90 26.04 23.406 Methylcyclopentane 00096-37-7 2.05 25.48 52.221 2-Methyl-1-butene 00563-46-2 6.38 24.07 153.548 c-2-Pentene 00627-20-3 10.28 21.57 221.725 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 16.40 127.185 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 14.90 174.354 c-2-Butene 00590-18-1 14.26 11.51 164.182 2-Methylhexane 00591-76-4 1.09 11.04 11.986 2,4-Dimethylpentane 00108-08-7 1.46 10.89 15.891 t-2-Hexene 04050-45-7 8.55 10.44 89.227 2,3,4-Trimethylpentane 00565-75-3 0.95 9.90 9.391 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 9.76 31.155 n-Heptane 00142-82-5 0.97 9.54 9.218 2,3-Dimethylpentane 00565-59-3 1.25 8.41 10.501 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 8.32 44.086 Methylcyclohexane 00108-87-2 1.56 7.80 12.139 3-Methyl-t-2-pentene 00616-12-6 11.66 7.57 88.256 Cyclopentene 00142-29-0 6.69 7.56 50.570 2,2-DiMeHexane 00590-73-8 0.94 6.78 6.384 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.75 53.635 3-Methyl-c-2-pentene 00922-62-3 12.52 6.24 78.115 2-Methyl-2-pentene 00625-27-4 11.03 5.88 64.848 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 5.78 38.174 1-Methylcyclopentene 00693-89-0 12.45 5.72 71.292 2,4-Dimethylhexane 00589-43-5 1.61 5.31 8.522 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 5.12 27.500 ortho-Xylene 00095-47-6 7.58 4.45 33.722 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.12 30.430 2,2-Dimethylbutane 00075-83-2 1.11 3.60 3.997 2-Methylpropane 00075-28-5 1.18 3.37 3.965 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 3.29 5.280 Vehicle 221b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7562 Non Zero Mass Species Sorted By VOC

## E

- 213 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7562 Non Zero Mass Species Sorted By VOC

n-Octane 00111-65-9 0.80 3.19 2.542 2,2,5-Trimethylhexane 03522-94-9 1.05 3.19 3.360 Ethylbenzene 00100-41-4 2.96 3.15 9.335 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.88 3.146 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.85 16.486 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.57 11.292 t-1,2-Dimethylcyclopentane 00822-50-4 2.70 2.44 6.572 2-Methylheptane 00592-27-8 0.97 2.23 2.153 2,2-Dimethylpentane 00590-35-2 1.04 1.99 2.080 c-1,3-Dimethylcyclopentane 02532-58-3 2.70 1.90 5.131 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.84 21.657 3-Methylheptane 00589-81-1 1.12 1.78 2.000 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.57 8.723 n-Propylbenzene 00103-65-1 1.96 1.55 3.035 3,3-Dimethylpentane 00562-49-2 1.12 1.45 1.620 2,3,5-Trimethylhexane 01069-53-0 1.12 1.42 1.586 2,2,3-Trimethylbutane 00464-06-2 1.05 1.35 1.424 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.19 9.299 3,5-Dimethylheptane 00926-82-9 1.42 1.00 1.426 Unknown #1 2.70 0.95 2.557 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.89 9.374 1,3-Butadiene 00106-99-0 12.45 0.89 11.106 Unknown #16 2.70 0.89 2.400 n-Decane 00124-18-5 0.59 0.89 0.525 n-Nonane 00111-84-2 0.68 0.88 0.601 c-1,3-Dimethylcyclohexane 00638-04-0 2.70 0.87 2.358 t-3-Heptene 14686-14-7 6.17 0.81 5.009 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.77 9.183 Propane 00074-98-6 0.46 0.74 0.340 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.70 0.72 1.939 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.65 2.529 Isopropylbenzene (Cumene) 00098-82-8 2.70 0.63 1.711 Indan 00496-11-7 3.23 0.59 1.916 3,3-Dimethylhexane 00563-16-6 1.15 0.51 0.584 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.49 3.481 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.48 4.002 Unknown #5 2.70 0.47 1.259 c-2-Heptene 06443-92-1 7.08 0.42 2.981 4-Methyloctane 02216-34-4 0.85 0.39 0.334 t-1,4-Dimethylcyclohexane 02207-04-7 2.70 0.36 0.969 1-Nonene 00124-11-8 2.49 0.31 0.762 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.30 1.950 

### continued

## E

- 214 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7562 Non Zero Mass Species Sorted By VOC

2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.25 1.554 2,4-Dimethylheptane 02213-23-2 1.26 0.25 0.310 Unknown #8 2.70 0.18 0.492 Unknown #14 2.70 0.08 0.221

Total 1952.6 5269.2 2.699

No MIR available, use weighted average of 2.6986 

### continued

## E

- 215 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 183.65 248.820 Ethanol 00064-17-5 1.45 85.05 123.234 n-Butane 00106-97-8 1.08 55.98 60.286 n-Hexane 00110-54-3 1.13 42.42 48.137 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 36.76 51.389 n-Pentane 00109-66-0 1.21 29.25 35.538 3-Methylpentane 00096-14-0 1.69 26.06 44.059 2-Methyl-2-butene 00513-35-9 14.20 24.79 351.885 Toluene 00108-88-3 3.93 21.45 84.201 t-2-Pentene 00646-04-8 10.47 20.72 216.997 2,3-Dimethylbutane 00079-29-8 0.90 18.25 16.404 2-Methyl-1-butene 00563-46-2 6.38 14.75 94.109 Methylcyclopentane 00096-37-7 2.05 12.48 25.573 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 12.26 14.700 c-2-Pentene 00627-20-3 10.28 11.25 115.647 Cyclohexane 00110-82-7 1.14 10.96 12.467 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 10.28 120.270 c-2-Butene 00590-18-1 14.26 8.44 120.327 Benzene 00071-43-2 0.69 7.98 5.543 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 5.61 44.524 2,4-Dimethylpentane 00108-08-7 1.46 5.40 7.883 n-Propylbenzene 00103-65-1 1.96 4.99 9.781 2-Methylhexane 00591-76-4 1.09 4.63 5.023 Methylcyclohexane 00108-87-2 1.56 4.49 6.989 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.19 13.370 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 4.00 21.181 2-Methylpropane 00075-28-5 1.18 3.70 4.351 t-2-Hexene 04050-45-7 8.55 3.61 30.821 Cyclopentene 00142-29-0 6.69 3.29 22.015 2,3,4-Trimethylpentane 00565-75-3 0.95 3.09 2.934 2-Methyl-2-pentene 00625-27-4 11.03 3.06 33.788 3-Methyl-t-2-pentene 00616-12-6 11.66 3.00 34.957 n-Heptane 00142-82-5 0.97 2.89 2.787 2,3-Dimethylpentane 00565-59-3 1.25 2.85 3.560 3-Methyl-c-2-pentene 00922-62-3 12.52 2.80 35.108 2,2-Dimethylbutane 00075-83-2 1.11 2.64 2.935 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.45 16.187 1-Methylcyclopentene 00693-89-0 12.45 1.96 24.373 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.88 10.848 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.84 14.307 2,2-Dimethylpentane 00590-35-2 1.04 1.56 1.630 2,4-Dimethylhexane 00589-43-5 1.61 1.51 2.422 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.28 2.052 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.11 1.213 Vehicle 221b - Fuel 7 psi E10 - 86 ° F Static - Test 7571 Non Zero Mass Species Sorted By VOC

## E

- 216 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 7 psi E10 - 86 ° F Static - Test 7571 Non Zero Mass Species Sorted By VOC

t-1,2-Dimethylcyclopentane 00822-50-4 3.02 1.02 3.093 c-1,3-Dimethylcyclopentane 02532-58-3 3.02 0.99 2.984 n-Octane 00111-65-9 0.80 0.85 0.676 Unknown #22

. 3.02 0.82 2.476 3,3-Dimethylpentane 00562-49-2 1.12 0.81 0.902 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.71 3.799 2,2,3-Trimethylbutane 00464-06-2 1.05 0.70 0.734 2,2,5-Trimethylhexane 03522-94-9 1.05 0.67 0.704 2-Methylheptane 00592-27-8 0.97 0.52 0.502 ortho-Xylene 00095-47-6 7.58 0.51 3.902 3-Methylheptane 00589-81-1 1.12 0.51 0.577 Propane 00074-98-6 0.46 0.51 0.232 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.43 1.903 2,3,5-Trimethylhexane 01069-53-0 1.12 0.42 0.468 c-1,3-Dimethylcyclohexane 00638-04-0 3.02 0.41 1.241 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.41 2.264 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.40 4.174 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.36 1.364 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.28 2.182 Ethylbenzene 00100-41-4 2.96 0.22 0.642 t-1,4-Dimethylcyclohexane 02207-04-7 3.02 0.16 0.480

Total 722.3 2179.9 3.018

No MIR available, use weighted average of 3.0180 

### continued

## E

- 217 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 300.70 407.411 Ethanol 00064-17-5 1.45 175.93 254.913 n-Butane 00106-97-8 1.08 86.54 93.192 n-Hexane 00110-54-3 1.13 76.52 86.830 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 64.44 90.071 n-Pentane 00109-66-0 1.21 49.08 59.633 Toluene 00108-88-3 3.93 48.57 190.638 3-Methylpentane 00096-14-0 1.69 45.21 76.439 2-Methyl-2-butene 00513-35-9 14.20 42.39 601.709 t-2-Pentene 00646-04-8 10.47 35.06 367.186 2,3-Dimethylbutane 00079-29-8 0.90 31.83 28.603 2-Methyl-1-butene 00563-46-2 6.38 24.29 154.955 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 23.37 28.018 Methylcyclopentane 00096-37-7 2.05 22.39 45.898 Cyclohexane 00110-82-7 1.14 20.15 22.915 c-2-Pentene 00627-20-3 10.28 19.28 198.187 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 16.25 190.254 Benzene 00071-43-2 0.69 14.77 10.255 c-2-Butene 00590-18-1 14.26 13.00 185.313 2,4-Dimethylpentane 00108-08-7 1.46 9.82 14.329 2-Methylhexane 00591-76-4 1.09 8.43 9.146 Methylcyclohexane 00108-87-2 1.56 8.15 12.672 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 7.85 62.371 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 7.20 22.976 t-2-Hexene 04050-45-7 8.55 6.54 55.875 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 6.52 34.548 2,3,4-Trimethylpentane 00565-75-3 0.95 5.94 5.635 2-Methylpropane 00075-28-5 1.18 5.68 6.687 Cyclopentene 00142-29-0 6.69 5.68 37.998 n-Heptane 00142-82-5 0.97 5.59 5.397 2,3-Dimethylpentane 00565-59-3 1.25 5.31 6.624 3-Methyl-t-2-pentene 00616-12-6 11.66 5.24 61.099 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 5.09 39.451 2-Methyl-2-pentene 00625-27-4 11.03 4.87 53.696 3-Methyl-c-2-pentene 00922-62-3 12.52 4.63 57.940 2,2-Dimethylbutane 00075-83-2 1.11 4.44 4.934 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.07 26.881 1-Methylcyclopentene 00693-89-0 12.45 3.74 46.520 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 3.22 18.583 2,4-Dimethylhexane 00589-43-5 1.61 3.18 5.103 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.91 15.637 Methane 00074-82-8 0.01 2.70 0.037 2,2-Dimethylpentane 00590-35-2 1.04 2.58 2.693 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.39 3.835 Vehicle 221b - Fuel 7 psi E10 - 105 ° F Static - Test 7572 Non Zero Mass Species Sorted By VOC

## E

- 218 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 7 psi E10 - 105 ° F Static - Test 7572 Non Zero Mass Species Sorted By VOC

2,2,5-Trimethylhexane 03522-94-9 1.05 1.87 1.969 t-1,2-Dimethylcyclopentane 00822-50-4 2.99 1.66 4.961 n-Octane 00111-65-9 0.80 1.55 1.230 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.54 11.385 ortho-Xylene 00095-47-6 7.58 1.41 10.693 2-Methylheptane 00592-27-8 0.97 1.41 1.359 c-1,3-Dimethylcyclopentane 02532-58-3 2.99 1.37 4.095 2,2,3-Trimethylbutane 00464-06-2 1.05 1.31 1.383 3,3-Dimethylpentane 00562-49-2 1.12 1.28 1.432 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.21 5.325 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.21 1.323 3-Methylheptane 00589-81-1 1.12 1.04 1.174 2,3,5-Trimethylhexane 01069-53-0 1.12 0.98 1.101 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.91 10.720 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.86 6.753 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.77 8.107 n-Propylbenzene 00103-65-1 1.96 0.73 1.427 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.72 4.010 Ethylbenzene 00100-41-4 2.96 0.72 2.129 c-1,3-Dimethylcyclohexane 00638-04-0 2.99 0.71 2.137 Propane 00074-98-6 0.46 0.67 0.307 3,5-Dimethylheptane 00926-82-9 1.42 0.47 0.665 n-Nonane 00111-84-2 0.68 0.44 0.302 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.44 1.706 Unknown #5 2.99 0.39 1.171 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.27 3.231 t-1,4-Dimethylcyclohexane 02207-04-7 2.99 0.26 0.776 t-3-Heptene 14686-14-7 6.17 0.24 1.501 n-Decane 00124-18-5 0.59 0.23 0.133 3,3-Dimethylhexane 00563-16-6 1.15 0.22 0.250 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.14 0.896 n-Undecane 01120-21-4 0.52 0.13 0.068

Total 1268.7 3796.8 2.993

No MIR available, use weighted average of 2.9927 

### continued

## E

- 219 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 40.59 58.808 Toluene 00108-88-3 3.93 17.21 67.543 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 10.33 76.277 n-Hexane 00110-54-3 1.13 6.67 7.565 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 5.32 6.382 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.63 24.844 Benzene 00071-43-2 0.69 4.58 3.177 1,3,5-Trimethylbenzene 00108-67-8 11.75 4.22 49.624 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.77 29.213 2-Methylbutane (Isopentane) 00078-78-4 1.35 3.54 4.799 Methylcyclohexane 00108-87-2 1.56 3.12 4.859 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 3.01 13.205 3-Methylpentane 00096-14-0 1.69 2.99 5.055 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 2.99 4.179 2-Methylhexane 00591-76-4 1.09 2.92 3.165 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 2.90 9.239 c-1,3-Dimethylcyclopentane 02532-58-3 3.37 2.88 9.709 t-1,2-Dimethylcyclopentane 00822-50-4 3.37 2.71 9.150 Unknown #16 3.37 2.66 8.955 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.60 14.407 Unknown #22

. 3.37 2.48 8.357 n-Pentane 00109-66-0 1.21 2.32 2.815 1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.28 16.130 2,3,4-Trimethylpentane 00565-75-3 0.95 1.99 1.885 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.96 15.603 n-Nonane 00111-84-2 0.68 1.90 1.300 t-2-Pentene 00646-04-8 10.47 1.58 16.559 n-Octane 00111-65-9 0.80 1.53 1.217 2-Methyl-1-butene 00563-46-2 6.38 1.52 9.671 2,2-Dimethylpentane 00590-35-2 1.04 1.46 1.521 3-Methylheptane 00589-81-1 1.12 1.42 1.595 n-Decane 00124-18-5 0.59 1.40 0.826 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 1.37 7.237 2-Methyl-2-butene 00513-35-9 14.20 1.36 19.369 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.27 1.382 n-Heptane 00142-82-5 0.97 1.26 1.216 1,4-Diethylbenzene 00105-05-5 4.39 1.21 5.321 2,3,5-Trimethylhexane 01069-53-0 1.12 1.20 1.342 n-Butane 00106-97-8 1.08 1.14 1.232 2,2,5-Trimethylhexane 03522-94-9 1.05 1.13 1.193 2,3-Dimethylpentane 00565-59-3 1.25 1.03 1.285 n-Undecane 01120-21-4 0.52 1.00 0.524 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.00 11.734 2,4-Dimethylpentane 00108-08-7 1.46 0.92 1.346 Vehicle 221b - Fuel 7 psi E10 - Dynamic - Test 25783 Non Zero Mass Species Sorted By VOC

## E

- 220 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 7 psi E10 - Dynamic - Test 25783 Non Zero Mass Species Sorted By VOC

2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.84 1.343 n-Propylbenzene 00103-65-1 1.96 0.81 1.589 c-2-Butene 00590-18-1 14.26 0.69 9.881 c-2-Pentene 00627-20-3 10.28 0.63 6.458 Ethylbenzene 00100-41-4 2.96 0.60 1.775 2,3-Dimethylbutane 00079-29-8 0.90 0.52 0.464 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.50 5.980 3-Methyl-t-2-pentene 00616-12-6 11.66 0.42 4.900 t-2-Hexene 04050-45-7 8.55 0.27 2.335 Methane 00074-82-8 0.01 0.25 0.003 Indan 00496-11-7 3.23 0.23 0.759 2,4-Dimethylhexane 00589-43-5 1.61 0.17 0.269 2,2-Dimethylbutane 00075-83-2 1.11 0.16 0.172 2-Methyl-2-pentene 00625-27-4 11.03 0.15 1.623 ortho-Xylene 00095-47-6 7.58 0.07 0.520

Total 171.6 578.9 3.373

No MIR available, use weighted average of 3.3727 

### continued

## E

- 221 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 462.69 670.422 Toluene 00108-88-3 3.93 201.13 789.442 2-Methylbutane (Isopentane) 00078-78-4 1.35 182.81 247.689 n-Hexane 00110-54-3 1.13 108.39 122.983 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 61.21 85.555 n-Butane 00106-97-8 1.08 58.34 62.826 Benzene 00071-43-2 0.69 49.41 34.308 2-Methyl-2-butene 00513-35-9 14.20 47.01 667.349 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 44.60 53.484 3-Methylpentane 00096-14-0 1.69 44.17 74.687 n-Pentane 00109-66-0 1.21 43.09 52.348 t-2-Pentene 00646-04-8 10.47 41.06 430.020 Cyclohexane 00110-82-7 1.14 33.85 38.501 Methylcyclopentane 00096-37-7 2.05 29.78 61.051 2,3-Dimethylbutane 00079-29-8 0.90 26.14 23.492 2-Methyl-1-butene 00563-46-2 6.38 23.36 149.005 c-2-Pentene 00627-20-3 10.28 21.21 218.100 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 20.26 157.099 2,3,4-Trimethylpentane 00565-75-3 0.95 19.46 18.463 Methylcyclohexane 00108-87-2 1.56 16.07 25.002 2-Methylhexane 00591-76-4 1.09 15.30 16.606 n-Heptane 00142-82-5 0.97 14.61 14.110 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 14.09 164.892 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 13.58 43.342 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 13.45 72.212 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 13.39 98.893 2,4-Dimethylpentane 00108-08-7 1.46 13.08 19.095 t-2-Hexene 04050-45-7 8.55 11.58 99.003 c-2-Butene 00590-18-1 14.26 10.58 150.824 2,3-Dimethylpentane 00565-59-3 1.25 9.39 11.720 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 9.20 48.766 2,4-Dimethylhexane 00589-43-5 1.61 8.64 13.864 3-Methyl-t-2-pentene 00616-12-6 11.66 8.30 96.729 n-Octane 00111-65-9 0.80 7.84 6.241 3-Methyl-c-2-pentene 00922-62-3 12.52 7.80 97.607 Cyclopentene 00142-29-0 6.69 7.68 51.325 2,2,5-Trimethylhexane 03522-94-9 1.05 7.03 7.406 2-Methyl-2-pentene 00625-27-4 11.03 6.84 75.490 1-Methylcyclopentene 00693-89-0 12.45 6.76 84.235 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 6.53 10.483 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 6.49 51.542 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 6.37 42.086 ortho-Xylene 00095-47-6 7.58 6.09 46.157 2,2-DiMeHexane 00590-73-8 0.94 5.99 5.635 Vehicle 221b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7579 Non Zero Mass Species Sorted By VOC

## E

- 222 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7579 Non Zero Mass Species Sorted By VOC

1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.88 25.857 1,3,5-Trimethylbenzene 00108-67-8 11.75 5.07 59.652 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 4.96 5.417 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 4.38 24.261 Ethylbenzene 00100-41-4 2.96 4.29 12.719 2-Methylheptane 00592-27-8 0.97 4.29 4.149 2,2-Dimethylbutane 00075-83-2 1.11 3.52 3.913 t-1,2-Dimethylcyclopentane 00822-50-4 3.03 3.46 10.510 3-Methylheptane 00589-81-1 1.12 3.44 3.874 n-Propylbenzene 00103-65-1 1.96 3.19 6.256 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 3.19 18.438 2,2-Dimethylpentane 00590-35-2 1.04 2.87 2.994 c-1,3-Dimethylcyclopentane 02532-58-3 3.03 2.77 8.389 2-Methylpropane 00075-28-5 1.18 2.63 3.097 Unknown #16 3.03 2.46 7.477 n-Nonane 00111-84-2 0.68 2.32 1.582 c-1,3-Dimethylcyclohexane 00638-04-0 3.03 2.11 6.401 3,3-Dimethylpentane 00562-49-2 1.12 2.05 2.289 2,2,3-Trimethylbutane 00464-06-2 1.05 1.71 1.806 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.52 11.903 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.52 18.133 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 1.41 5.433 3,5-Dimethylheptane 00926-82-9 1.42 1.38 1.959 4-Methyloctane 02216-34-4 0.85 1.36 1.156 2,3,5-Trimethylhexane 01069-53-0 1.12 1.30 1.456 Unknown #5 3.03 1.17 3.542 n-Decane 00124-18-5 0.59 1.15 0.682 t-1,4-Dimethylcyclohexane 02207-04-7 3.03 1.15 3.493 1-Methyl-3-Propylbenzene 01074-43-7 7.08 1.01 7.124 Unknown #8 3.03 1.00 3.022 3,3-Dimethylhexane 00563-16-6 1.15 0.93 1.071 Unknown #13 3.03 0.92 2.795 Indan 00496-11-7 3.23 0.90 2.899 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 3.03 0.89 2.697 3-Methyloctane 02216-33-3 0.88 0.84 0.740 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.82 8.593 1-Nonene 00124-11-8 2.49 0.77 1.930 Isopropylbenzene (Cumene) 00098-82-8 3.03 0.74 2.236 1,1-Dimethylcyclohexane 00590-66-9 1.12 0.72 0.800 2,4-Dimethylheptane 02213-23-2 1.26 0.70 0.881 c-2-Heptene 06443-92-1 7.08 0.69 4.903 1-Methyl-2-Propylbenzene 01074-17-5 5.43 0.66 3.577 

### continued

## E

- 223 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7579 Non Zero Mass Species Sorted By VOC

3-Methylnonane 3.03 0.64 1.944 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.63 4.764 1,4-Diethylbenzene 00105-05-5 4.39 0.61 2.658 t-3-Heptene 14686-14-7 6.17 0.59 3.610 t-2-Nonene 06434-78-2 3.03 0.51 1.538 Unknown #9 3.03 0.49 1.478 4-Methyl-t-2-pentene 00674-76-0 8.04 0.46 3.712 sec-Butylbenzene 00135-98-8 2.29 0.45 1.029 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.41 3.396 Unknown #3 3.03 0.37 1.130 c- & t-4-Nonene 02198-23-4 4.42 0.36 1.591 1-Heptene 00592-76-7 4.29 0.34 1.452 1,3-Diethylbenzene 00141-93-5 7.08 0.31 2.205 Propane 00074-98-6 0.46 0.31 0.141 Isobutylbenzene 00538-93-2 3.03 0.29 0.890 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.27 0.227 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.23 1.478 n-Undecane 01120-21-4 0.52 0.19 0.098

Total 1860.2 5643.5 3.034

No MIR available, use weighted average of 3.0338 

### continued

## E

- 224 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 460.36 495.765 2-Methylbutane (Isopentane) 00078-78-4 1.35 319.27 432.580 Cyclohexane 00110-82-7 1.14 60.88 69.245 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 39.91 55.782 n-Hexane 00110-54-3 1.13 33.30 37.790 Toluene 00108-88-3 3.93 30.43 119.456 n-Pentane 00109-66-0 1.21 27.36 33.236 3-Methylpentane 00096-14-0 1.69 25.94 43.858 2,3-Dimethylbutane 00079-29-8 0.90 23.51 21.131 2-Methyl-2-butene 00513-35-9 14.20 22.33 316.947 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 18.56 22.251 t-2-Pentene 00646-04-8 10.47 17.69 185.320 Methylcyclopentane 00096-37-7 2.05 12.61 25.840 2-Methyl-1-butene 00563-46-2 6.38 12.29 78.397 c-2-Pentene 00627-20-3 10.28 10.04 103.198 Benzene 00071-43-2 0.69 8.78 6.097 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 7.86 92.045 2,4-Dimethylpentane 00108-08-7 1.46 6.98 10.185 c-2-Butene 00590-18-1 14.26 6.30 89.898 2,3,4-Trimethylpentane 00565-75-3 0.95 5.19 4.929 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.90 38.034 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.87 26.155 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 4.83 21.244 2,2-Dimethylbutane 00075-83-2 1.11 4.65 5.170 2-Methylhexane 00591-76-4 1.09 4.48 4.867 2,3-Dimethylpentane 00565-59-3 1.25 4.20 5.242 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.16 13.278 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 3.86 20.462 t-2-Hexene 04050-45-7 8.55 3.77 32.188 Ethanol 00064-17-5 1.45 3.71 5.373 3-Methyl-t-2-pentene 00616-12-6 11.66 3.67 42.836 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.56 28.237 Cyclopentene 00142-29-0 6.69 3.29 22.007 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 3.00 22.154 3-Methyl-c-2-pentene 00922-62-3 12.52 2.99 37.449 2-Methyl-2-pentene 00625-27-4 11.03 2.90 31.999 2-Methylpropane 00075-28-5 1.18 2.63 3.096 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.58 17.033 1-Methylcyclopentene 00693-89-0 12.45 2.29 28.479 2,4-Dimethylhexane 00589-43-5 1.61 2.17 3.477 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.07 3.322 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 1.97 11.388 2,2,5-Trimethylhexane 03522-94-9 1.05 1.93 2.034 n-Heptane 00142-82-5 0.97 1.82 1.761 Vehicle 221b - Fuel 9 psi E0 - 86 ° F Static - Test 7650 Non Zero Mass Species Sorted By VOC

## E

- 225 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 9 psi E0 - 86 ° F Static - Test 7650 Non Zero Mass Species Sorted By VOC

1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.74 9.663 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.61 1.755 n-Propylbenzene 00103-65-1 1.96 1.35 2.645 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.32 15.795 ortho-Xylene 00095-47-6 7.58 1.27 9.618 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.19 14.047 2,2-Dimethylpentane 00590-35-2 1.04 1.19 1.241 t-1,2-Dimethylcyclopentane 00822-50-4 2.20 1.17 2.582 c-1,3-Dimethylcyclopentane 02532-58-3 2.20 0.93 2.059 Ethylbenzene 00100-41-4 2.96 0.80 2.363 Methylcyclohexane 00108-87-2 1.56 0.78 1.217 2,2,3-Trimethylbutane 00464-06-2 1.05 0.69 0.728 4-Methyl-t-2-pentene 00674-76-0 8.04 0.66 5.311 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.61 3.874 n-Octane 00111-65-9 0.80 0.61 0.484 3,3-Dimethylpentane 00562-49-2 1.12 0.57 0.638 2-Methylheptane 00592-27-8 0.97 0.54 0.523 3-Methylheptane 00589-81-1 1.12 0.49 0.546 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.35 3.665 Unknown #1 2.20 0.29 0.634 n-Decane 00124-18-5 0.59 0.16 0.096 2,3,5-Trimethylhexane 01069-53-0 1.12 0.08 0.087

Total 1248.3 2750.8 2.204

No MIR available, use weighted average of 2.2036 

### continued

## E

- 226 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 636.36 685.309 2-Methylbutane (Isopentane) 00078-78-4 1.35 469.23 635.754 Cyclohexane 00110-82-7 1.14 100.16 113.921 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 62.96 88.010 n-Hexane 00110-54-3 1.13 53.73 60.962 Toluene 00108-88-3 3.93 51.80 203.304 n-Pentane 00109-66-0 1.21 41.21 50.068 3-Methylpentane 00096-14-0 1.69 41.07 69.450 2,3-Dimethylbutane 00079-29-8 0.90 36.44 32.750 2-Methyl-2-butene 00513-35-9 14.20 33.67 477.972 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 31.65 37.952 t-2-Pentene 00646-04-8 10.47 26.30 275.421 Methylcyclopentane 00096-37-7 2.05 20.33 41.665 2-Methyl-1-butene 00563-46-2 6.38 18.05 115.161 c-2-Pentene 00627-20-3 10.28 14.23 146.307 Benzene 00071-43-2 0.69 13.97 9.701 2,4-Dimethylpentane 00108-08-7 1.46 11.64 16.988 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 10.46 122.473 2,3,4-Trimethylpentane 00565-75-3 0.95 8.67 8.225 c-2-Butene 00590-18-1 14.26 7.62 108.727 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 7.07 54.853 2-Methylhexane 00591-76-4 1.09 6.98 7.574 2,2-Dimethylbutane 00075-83-2 1.11 6.79 7.541 2,3-Dimethylpentane 00565-59-3 1.25 6.71 8.375 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 6.41 33.972 t-2-Hexene 04050-45-7 8.55 5.98 51.126 3-Methyl-t-2-pentene 00616-12-6 11.66 5.34 62.218 Ethanol 00064-17-5 1.45 5.20 7.530 2-Methyl-2-pentene 00625-27-4 11.03 4.72 52.108 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.65 36.962 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 4.65 14.842 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 4.64 24.922 Cyclopentene 00142-29-0 6.69 4.64 31.029 3-Methyl-c-2-pentene 00922-62-3 12.52 4.35 54.439 2-Methylpropane 00075-28-5 1.18 4.18 4.921 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 3.77 24.888 1-Methylcyclopentene 00693-89-0 12.45 3.66 45.560 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 3.42 25.265 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 3.04 4.874 2,4-Dimethylhexane 00589-43-5 1.61 2.97 4.775 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.92 16.865 2,2,5-Trimethylhexane 03522-94-9 1.05 2.46 2.586 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 2.39 2.605 n-Heptane 00142-82-5 0.97 2.27 2.189 Vehicle 221b - Fuel 9 psi E0 - 105 ° F Static - Test 7652 Non Zero Mass Species Sorted By VOC

## E

- 227 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 9 psi E0 - 105 ° F Static - Test 7652 Non Zero Mass Species Sorted By VOC

Methylcyclohexane 00108-87-2 1.56 2.27 3.525 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.24 9.822 ortho-Xylene 00095-47-6 7.58 2.18 16.550 2,2-Dimethylpentane 00590-35-2 1.04 1.89 1.969 t-1,2-Dimethylcyclopentane 00822-50-4 2.19 1.88 4.117 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.67 19.620 c-1,3-Dimethylcyclopentane 02532-58-3 2.19 1.55 3.401 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.20 6.668 2,2,3-Trimethylbutane 00464-06-2 1.05 1.18 1.241 Ethylbenzene 00100-41-4 2.96 1.17 3.466 4-Methyl-t-2-pentene 00674-76-0 8.04 1.15 9.273 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.86 5.413 2-Methylheptane 00592-27-8 0.97 0.84 0.809 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.81 9.717 3-Methylheptane 00589-81-1 1.12 0.80 0.904 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.71 5.575 3,3-Dimethylpentane 00562-49-2 1.12 0.69 0.777 n-Propylbenzene 00103-65-1 1.96 0.67 1.309 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.56 5.836 Unknown #1 2.19 0.49 1.079 n-Octane 00111-65-9 0.80 0.40 0.322 2,3,5-Trimethylhexane 01069-53-0 1.12 0.09 0.097

Total 1824.1 3993.6 2.189

No MIR available, use weighted average of 2.1894 

### continued

## E

- 228 Species CAS No. MIR Composite VOC

mg Ozone mg Cyclohexane 00110-82-7 1.14 34.45 39.177 n-Butane 00106-97-8 1.08 32.29 34.777 2-Methylbutane (Isopentane) 00078-78-4 1.35 30.81 41.741 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 28.39 39.678 Toluene 00108-88-3 3.93 26.61 104.454 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 15.77 18.914 2,3-Dimethylbutane 00079-29-8 0.90 15.66 14.071 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 11.73 62.966 n-Pentane 00109-66-0 1.21 10.89 13.226 n-Hexane 00110-54-3 1.13 9.50 10.777 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 8.50 37.361 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.33 49.088 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 6.09 44.983 3-Methylpentane 00096-14-0 1.69 5.66 9.578 Benzene 00071-43-2 0.69 5.02 3.483 2,3,4-Trimethylpentane 00565-75-3 0.95 4.83 4.583 2,3-Dimethylpentane 00565-59-3 1.25 4.27 5.335 Methylcyclopentane 00096-37-7 2.05 3.70 7.591 2-Methyl-2-butene 00513-35-9 14.20 3.01 42.795 2-Methyl-1-butene 00563-46-2 6.38 2.95 18.815 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 2.89 33.783 2-Methylhexane 00591-76-4 1.09 2.88 3.123 1,3,5-Trimethylbenzene 00108-67-8 11.75 2.65 31.164 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.58 14.295 2,4-Dimethylhexane 00589-43-5 1.61 2.56 4.103 2,4-Dimethylpentane 00108-08-7 1.46 2.30 3.354 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.15 14.180 t-2-Pentene 00646-04-8 10.47 1.82 19.081 Ethylbenzene 00100-41-4 2.96 1.78 5.272 3-Methylheptane 00589-81-1 1.12 1.75 1.966 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.70 5.414 2-Methylheptane 00592-27-8 0.97 1.66 1.607 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.53 18.249 n-Propylbenzene 00103-65-1 1.96 1.52 2.978 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.47 2.354 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 1.28 8.041 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 1.22 1.337 ortho-Xylene 00095-47-6 7.58 1.15 8.681 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.10 8.700 n-Heptane 00142-82-5 0.97 0.99 0.954 3-Methyl-c-2-pentene 00922-62-3 12.52 0.93 11.589 2,2,5-Trimethylhexane 03522-94-9 1.05 0.89 0.942 2-Methyl-2-pentene 00625-27-4 11.03 0.84 9.286 3-Methyl-t-2-pentene 00616-12-6 11.66 0.72 8.341 Vehicle 221b - Fuel 9 psi E0 - Dynamic - Test 25790 Non Zero Mass Species Sorted By VOC

## E

- 229 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 9 psi E0 - Dynamic - Test 25790 Non Zero Mass Species Sorted By VOC

2,2-Dimethylpentane 00590-35-2 1.04 0.71 0.739 2,2-Dimethylbutane 00075-83-2 1.11 0.69 0.765 t-2-Hexene 04050-45-7 8.55 0.67 5.756 2,2-DiMeHexane 00590-73-8 0.94 0.65 0.611 1,3-Butadiene 00106-99-0 12.45 0.59 7.321 1-Methylcyclopentene 00693-89-0 12.45 0.43 5.374 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.42 4.417 Cyclopentene 00142-29-0 6.69 0.34 2.254 2,3,5-Trimethylhexane 01069-53-0 1.12 0.20 0.220 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.19 1.003 c-2-Pentene 00627-20-3 10.28 0.11 1.115

Total 311.8 851.8 2.732 

### continued

## E

- 230 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 391.77 421.903 2-Methylbutane (Isopentane) 00078-78-4 1.35 291.96 395.579 Toluene 00108-88-3 3.93 149.99 588.714 Cyclohexane 00110-82-7 1.14 111.22 126.496 n-Hexane 00110-54-3 1.13 66.44 75.387 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 53.20 74.363 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 41.21 49.420 3-Methylpentane 00096-14-0 1.69 36.07 60.983 Benzene 00071-43-2 0.69 34.30 23.814 n-Pentane 00109-66-0 1.21 33.28 40.434 2-Methyl-2-butene 00513-35-9 14.20 32.16 456.446 t-2-Pentene 00646-04-8 10.47 28.33 296.746 2,3-Dimethylbutane 00079-29-8 0.90 26.75 24.037 Methylcyclopentane 00096-37-7 2.05 22.50 46.117 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 22.02 170.745 2,3,4-Trimethylpentane 00565-75-3 0.95 15.69 14.886 2-Methyl-1-butene 00563-46-2 6.38 14.69 93.703 c-2-Pentene 00627-20-3 10.28 13.83 142.219 2,4-Dimethylpentane 00108-08-7 1.46 11.90 17.361 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 9.74 52.287 2-Methylhexane 00591-76-4 1.09 9.69 10.513 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 9.48 110.908 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 9.14 67.516 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 8.54 27.262 2,3,5-Trimethylhexane 01069-53-0 1.12 8.51 9.529 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 8.43 44.676 2,3-Dimethylpentane 00565-59-3 1.25 8.42 10.515 c-2-Butene 00590-18-1 14.26 8.36 119.250 t-2-Hexene 04050-45-7 8.55 8.22 70.309 3-Methyl-t-2-pentene 00616-12-6 11.66 7.14 83.278 2,4-Dimethylhexane 00589-43-5 1.61 7.13 11.455 Ethylbenzene 00100-41-4 2.96 6.65 19.712 1-Methylcyclopentene 00693-89-0 12.45 5.80 72.203 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 5.74 36.175 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 5.53 8.883 3-Methyl-c-2-pentene 00922-62-3 12.52 5.49 68.775 2,2,5-Trimethylhexane 03522-94-9 1.05 5.33 5.609 Cyclopentene 00142-29-0 6.69 5.23 34.958 2-Methylpropane 00075-28-5 1.18 5.09 5.985 2-Methyl-2-pentene 00625-27-4 11.03 5.05 55.729 n-Heptane 00142-82-5 0.97 5.01 4.837 ortho-Xylene 00095-47-6 7.58 4.99 37.775 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 4.88 32.261 4-Methyl-t-2-pentene 00674-76-0 8.04 4.19 33.668 Vehicle 221b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7667 Non Zero Mass Species Sorted By VOC

## E

- 231 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7667 Non Zero Mass Species Sorted By VOC

2,2-Dimethylbutane 00075-83-2 1.11 4.18 4.642 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.96 4.324 Methylcyclohexane 00108-87-2 1.56 3.59 5.580 1,3,5-Trimethylbenzene 00108-67-8 11.75 3.43 40.267 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.23 25.667 Ethanol 00064-17-5 1.45 2.91 4.215 Propane 00074-98-6 0.46 2.77 1.265 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.42 13.969 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.30 12.728 t-1,2-Dimethylcyclopentane 00822-50-4 2.68 2.12 5.690 n-Propylbenzene 00103-65-1 1.96 2.07 4.056 c-2-Heptene 06443-92-1 7.08 1.79 12.655 2,2-Dimethylpentane 00590-35-2 1.04 1.74 1.814 c-1,3-Dimethylcyclopentane 02532-58-3 2.68 1.72 4.609 2-Methylheptane 00592-27-8 0.97 1.70 1.647 3-Methylheptane 00589-81-1 1.12 1.53 1.716 Indan 00496-11-7 3.23 1.44 4.665 n-Octane 00111-65-9 0.80 1.38 1.098 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.21 9.514 Unknown #16 2.68 0.98 2.627 n-Decane 00124-18-5 0.59 0.93 0.551 2,2,3-Trimethylbutane 00464-06-2 1.05 0.88 0.929 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.85 10.147 Unknown #5 2.68 0.84 2.247 3,3-Dimethylpentane 00562-49-2 1.12 0.81 0.903 Isopropylbenzene (Cumene) 00098-82-8 2.68 0.81 2.159 Unknown #1 2.68 0.71 1.896 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.66 2.549 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.62 6.448 3,5-Dimethylheptane 00926-82-9 1.42 0.53 0.762 c-1,3-Dimethylcyclohexane 00638-04-0 2.68 0.49 1.302 1-Nonene 00124-11-8 2.49 0.47 1.166 2-MeOctane & 2,3-DiMeHeptane 03074-71-3+03221-61-2 0.85 0.30 0.257 t-3-Heptene 14686-14-7 6.17 0.29 1.805 Unknown #9 2.68 0.28 0.744 1,4-Diethylbenzene 00105-05-5 4.39 0.26 1.162 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.22 1.849 3,3-Dimethylhexane 00563-16-6 1.15 0.20 0.226 n-Nonane 00111-84-2 0.68 0.14 0.098

Total 1625.8 4353.4 2.678

No MIR available, use weighted average of 2.6776 

### continued

## E

- 232 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 353.11 478.423 n-Butane 00106-97-8 1.08 239.03 257.412 Cyclohexane 00110-82-7 1.14 69.24 78.747 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 50.17 70.124 n-Hexane 00110-54-3 1.13 36.39 41.296 n-Pentane 00109-66-0 1.21 31.28 38.004 Toluene 00108-88-3 3.93 29.62 116.252 2,3-Dimethylbutane 00079-29-8 0.90 29.50 26.514 3-Methylpentane 00096-14-0 1.69 28.09 47.498 2-Methyl-2-butene 00513-35-9 14.20 25.04 355.396 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 21.13 25.335 t-2-Pentene 00646-04-8 10.47 19.17 200.764 Methylcyclopentane 00096-37-7 2.05 13.81 28.309 2-Methyl-1-butene 00563-46-2 6.38 13.42 85.617 c-2-Pentene 00627-20-3 10.28 10.68 109.799 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 9.33 68.913 Benzene 00071-43-2 0.69 8.77 6.091 2,4-Dimethylpentane 00108-08-7 1.46 7.87 11.484 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 7.55 88.328 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 6.77 52.471 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 6.25 33.583 c-2-Butene 00590-18-1 14.26 5.84 83.339 2,2-Dimethylbutane 00075-83-2 1.11 5.77 6.410 2,3,4-Trimethylpentane 00565-75-3 0.95 5.63 5.341 2-Methylpropane 00075-28-5 1.18 5.19 6.112 2-Methylhexane 00591-76-4 1.09 4.79 5.194 2,3-Dimethylpentane 00565-59-3 1.25 4.64 5.797 2,4-Dimethylheptane 02213-23-2 1.26 4.19 5.297 t-2-Hexene 04050-45-7 8.55 4.12 35.227 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 4.09 21.663 3-Methyl-t-2-pentene 00616-12-6 11.66 4.07 47.420 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 3.64 28.886 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 3.39 10.817 2-Methyl-2-pentene 00625-27-4 11.03 3.26 35.990 Cyclopentene 00142-29-0 6.69 3.17 21.193 3-Methyl-c-2-pentene 00922-62-3 12.52 3.06 38.350 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 2.81 18.539 2,4-Dimethylhexane 00589-43-5 1.61 2.61 4.194 1,3,5-Trimethylbenzene 00108-67-8 11.75 2.37 27.849 1-Methylcyclopentene 00693-89-0 12.45 2.37 29.494 2,2,5-Trimethylhexane 03522-94-9 1.05 2.29 2.413 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.20 9.687 3-Methyl-1-butene 00563-45-1 6.85 2.16 14.823 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.15 12.430 Vehicle 221b - Fuel 7 psi E0 - 86 ° F Static - Test 7691 Non Zero Mass Species Sorted By VOC

## E

- 233 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 7 psi E0 - 86 ° F Static - Test 7691 Non Zero Mass Species Sorted By VOC

3,3-Dimethylhexane 00563-16-6 1.15 2.07 2.386 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.75 2.813 ortho-Xylene 00095-47-6 7.58 1.60 12.131 n-Heptane 00142-82-5 0.97 1.57 1.516 Ethylbenzene 00100-41-4 2.96 1.45 4.299 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.30 7.189 t-1,2-Dimethylcyclopentane 00822-50-4 2.46 1.15 2.832 2,2-Dimethylpentane 00590-35-2 1.04 1.08 1.131 2-Methylheptane 00592-27-8 0.97 1.08 1.040 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.07 12.797 Propane 00074-98-6 0.46 1.01 0.462 c-1,3-Dimethylcyclopentane 02532-58-3 2.46 0.95 2.341 n-Propylbenzene 00103-65-1 1.96 0.88 1.727 2,2,3-Trimethylbutane 00464-06-2 1.05 0.79 0.837 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.70 0.767 Methylcyclohexane 00108-87-2 1.56 0.58 0.898 3,3-Dimethylpentane 00562-49-2 1.12 0.50 0.564 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.45 3.536 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.40 4.224 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.35 2.183 3-Methylheptane 00589-81-1 1.12 0.33 0.370 2,3,5-Trimethylhexane 01069-53-0 1.12 0.32 0.361 n-Octane 00111-65-9 0.80 0.24 0.191 4-Methyl-t-2-pentene 00674-76-0 8.04 0.17 1.380

Total 1121.8 2764.8 2.465

No MIR available, use weighted average of 2.4645 

### continued

## E

- 234 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 424.48 575.119 n-Butane 00106-97-8 1.08 264.00 284.303 Cyclohexane 00110-82-7 1.14 120.32 136.846 Toluene 00108-88-3 3.93 69.41 272.440 Unknown #2 2.61 63.63 166.355 n-Hexane 00110-54-3 1.13 57.55 65.305 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 47.69 57.184 3-Methylpentane 00096-14-0 1.69 43.68 73.864 n-Pentane 00109-66-0 1.21 39.63 48.144 2,3-Dimethylbutane 00079-29-8 0.90 39.00 35.047 2-Methyl-2-butene 00513-35-9 14.20 31.47 446.654 t-2-Pentene 00646-04-8 10.47 24.83 260.030 Methylcyclopentane 00096-37-7 2.05 22.35 45.814 2-Methyl-1-butene 00563-46-2 6.38 16.53 105.461 2,3,4-Trimethylpentane 00565-75-3 0.95 16.31 15.471 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 14.33 76.946 Benzene 00071-43-2 0.69 14.31 9.935 2,4-Dimethylpentane 00108-08-7 1.46 13.68 19.967 c-2-Pentene 00627-20-3 10.28 13.19 135.562 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 10.76 83.472 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 10.04 117.496 2,3-Dimethylpentane 00565-59-3 1.25 9.39 11.716 2-Methylhexane 00591-76-4 1.09 9.39 10.185 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 8.53 63.011 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 8.44 26.917 2,2-Dimethylbutane 00075-83-2 1.11 7.24 8.050 2,4-Dimethylhexane 00589-43-5 1.61 6.89 11.066 c-2-Butene 00590-18-1 14.26 6.52 93.031 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 6.46 34.232 2,2,5-Trimethylhexane 03522-94-9 1.05 6.42 6.757 t-2-Hexene 04050-45-7 8.55 6.30 53.899 3-Methyl-t-2-pentene 00616-12-6 11.66 6.10 71.088 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.90 25.924 3-Methyl-c-2-pentene 00922-62-3 12.52 4.96 62.136 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 4.91 7.883 2-Methylpropane 00075-28-5 1.18 4.79 5.636 1,3,5-Trimethylbenzene 00108-67-8 11.75 4.70 55.274 Cyclopentene 00142-29-0 6.69 4.46 29.822 2-Methyl-2-pentene 00625-27-4 11.03 4.38 48.341 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.37 34.694 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 4.17 23.083 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 3.98 26.304 1-Methylcyclopentene 00693-89-0 12.45 3.98 49.558 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 3.85 4.204 Vehicle 221b - Fuel 7 psi E0 - 105 ° F Static - Test 7692 Non Zero Mass Species Sorted By VOC

## E

- 235 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 7 psi E0 - 105 ° F Static - Test 7692 Non Zero Mass Species Sorted By VOC

n-Heptane 00142-82-5 0.97 3.71 3.583 ortho-Xylene 00095-47-6 7.58 3.15 23.847 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.90 16.778 1,2,3-Trimethylbenzene 00526-73-8 11.94 2.75 32.824 3-Methyl-1-butene 00563-45-1 6.85 2.69 18.437 1-Methyl-3-Propylbenzene 01074-43-7 7.08 2.64 18.691 Methylcyclohexane 00108-87-2 1.56 2.58 4.017 Indan 00496-11-7 3.23 2.50 8.071 1,4-Diethylbenzene 00105-05-5 4.39 2.36 10.359 n-Propylbenzene 00103-65-1 1.96 2.31 4.534 t-1,2-Dimethylcyclopentane 00822-50-4 2.61 2.19 5.728 Unknown #16 2.61 2.03 5.297 2,2-Dimethylpentane 00590-35-2 1.04 1.98 2.070 c-1,3-Dimethylcyclopentane 02532-58-3 2.61 1.80 4.702 Ethylbenzene 00100-41-4 2.96 1.62 4.800 3-Methylheptane 00589-81-1 1.12 1.52 1.712 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.37 10.715 2,2,3-Trimethylbutane 00464-06-2 1.05 1.34 1.409 4-Methyl-t-2-pentene 00674-76-0 8.04 1.21 9.694 2-Methylheptane 00592-27-8 0.97 1.18 1.138 2,3,5-Trimethylhexane 01069-53-0 1.12 1.06 1.189 3,5-Dimethylheptane 00926-82-9 1.42 0.97 1.381 1,3-Diethylbenzene 00141-93-5 7.08 0.94 6.636 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.94 5.895 1-Methyl-2-Propylbenzene 01074-17-5 5.43 0.90 4.890 n-Octane 00111-65-9 0.80 0.86 0.688 1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 0.86 8.744 3,3-Dimethylpentane 00562-49-2 1.12 0.86 0.962 Unknown #5 2.61 0.85 2.219 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.80 5.997 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.79 5.948 Isopropylbenzene (Cumene) 00098-82-8 2.61 0.74 1.922 3-Methyloctane 02216-33-3 0.88 0.73 0.650 1,3-Dimethyl-4-Ethylbenzene 00874-41-9 7.54 0.67 5.063 c-2-Heptene 06443-92-1 7.08 0.63 4.425 1-Nonene 00124-11-8 2.49 0.58 1.440 2,4-Dimethylheptane 02213-23-2 1.26 0.55 0.702 1,2,3,5-Tetramethylbenzene 00527-53-7 9.26 0.55 5.073 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.55 2.107 1-Methyl-4-Isobutylbenzene 05161-04-6 3.82 0.52 2.002 c-1,3-Dimethylcyclohexane 00638-04-0 2.61 0.50 1.304 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.47 3.094 

### continued

## E

- 236 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 7 psi E0 - 105 ° F Static - Test 7692 Non Zero Mass Species Sorted By VOC

2-Methyl-1,3-butadiene 00078-79-5 10.48 0.44 4.638 sec-Butylbenzene 00135-98-8 2.29 0.44 1.005 3-Methylnonane 2.61 0.42 1.101 Isobutylbenzene 00538-93-2 2.61 0.41 1.070 Unknown #3 2.61 0.36 0.951 1,2,4,5-Tetramethylbenzene 00095-93-2 9.26 0.29 2.718 t-3-Heptene 14686-14-7 6.17 0.28 1.725 3,3-Dimethylhexane 00563-16-6 1.15 0.27 0.316 t-2-Nonene 06434-78-2 2.61 0.27 0.706 3-Ethyl-c-2-Pentene 00816-79-5 9.76 0.27 2.630 n-Nonane 00111-84-2 0.68 0.24 0.165 Unknown #8 2.61 0.23 0.610 n-Undecane 01120-21-4 0.52 0.22 0.115 Unknown #13 2.61 0.18 0.466 n-Decane 00124-18-5 0.59 0.18 0.104 1,1-Dimethylcyclohexane 00590-66-9 1.12 0.15 0.172 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.61 0.13 0.333

Total 1558.2 4073.8 2.614

No MIR available, use weighted average of 2.6144 

### continued

## E

- 237 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 25.19 98.866 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 21.01 155.169 2-Methylbutane (Isopentane) 00078-78-4 1.35 20.87 28.280 n-Butane 00106-97-8 1.08 13.42 14.448 Cyclohexane 00110-82-7 1.14 12.89 14.657 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 11.57 62.112 Unknown #2 4.30 10.80 46.422 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 8.41 65.248 1,3,5-Trimethylbenzene 00108-67-8 11.75 7.39 86.814 n-Hexane 00110-54-3 1.13 6.01 6.823 Cyclopentane 00287-92-3 2.24 5.80 12.966 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 5.29 6.344 Benzene 00071-43-2 0.69 3.83 2.662 n-Pentane 00109-66-0 1.21 3.24 3.933 ortho-Xylene 00095-47-6 7.58 2.91 22.066 Ethylbenzene 00100-41-4 2.96 2.80 8.281 3-Methylpentane 00096-14-0 1.69 2.65 4.482 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 2.51 13.908 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.51 11.027 4-Methyl-t-2-pentene 00674-76-0 8.04 2.42 19.467 n-Propylbenzene 00103-65-1 1.96 2.40 4.694 2-Methyl-2-butene 00513-35-9 14.20 2.30 32.658 n-Heptane 00142-82-5 0.97 2.27 2.193 Methylcyclopentane 00096-37-7 2.05 2.25 4.618 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.83 14.570 Methylcyclohexane 00108-87-2 1.56 1.73 2.691 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 1.66 10.990 2,3,4-Trimethylpentane 00565-75-3 0.95 1.57 1.494 2,4-Dimethylpentane 00108-08-7 1.46 1.42 2.070 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.36 16.265 2-Methyl-2-pentene 00625-27-4 11.03 1.33 14.635 3-Methyl-t-2-pentene 00616-12-6 11.66 1.28 14.976 c-2-Butene 00590-18-1 14.26 1.24 17.637 2-Methylhexane 00591-76-4 1.09 1.18 1.283 1-Methylcyclopentene 00693-89-0 12.45 1.07 13.316 2-Methyl-1-butene 00563-46-2 6.38 1.06 6.784 t-2-Hexene 04050-45-7 8.55 1.05 9.000 2,3-Dimethylpentane 00565-59-3 1.25 0.99 1.234 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.99 1.582 2,3,5-Trimethylhexane 01069-53-0 1.12 0.79 0.880 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.74 7.736 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.60 1.920 c-2-Pentene 00627-20-3 10.28 0.39 4.017 t-2-Pentene 00646-04-8 10.47 0.37 3.864 Vehicle 221b - Fuel 7 psi E0 - Dynamic - Test 25797 Non Zero Mass Species Sorted By VOC

## E

- 238 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 7 psi E0 - Dynamic - Test 25797 Non Zero Mass Species Sorted By VOC

2,2,5-Trimethylhexane 03522-94-9 1.05 0.35 0.368 2,2-Dimethylbutane 00075-83-2 1.11 0.09 0.099 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.09 0.096 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.08 0.980 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.06 0.335

Total 204.1 877.0 4.298

No MIR available, use weighted average of 4.2975 

### continued

## E

- 239 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 331.35 448.947 n-Butane 00106-97-8 1.08 196.09 211.173 Toluene 00108-88-3 3.93 163.70 642.521 Cyclohexane 00110-82-7 1.14 150.06 170.677 n-Hexane 00110-54-3 1.13 81.40 92.365 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 67.99 95.037 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 46.75 56.065 3-Methylpentane 00096-14-0 1.69 44.37 75.032 n-Pentane 00109-66-0 1.21 40.94 49.745 2-Methyl-2-butene 00513-35-9 14.20 39.67 563.085 Benzene 00071-43-2 0.69 38.43 26.682 t-2-Pentene 00646-04-8 10.47 35.41 370.822 2,3-Dimethylbutane 00079-29-8 0.90 33.20 29.835 Methylcyclopentane 00096-37-7 2.05 28.54 58.502 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 19.67 152.524 2-Methyl-1-butene 00563-46-2 6.38 18.63 118.852 2,3,4-Trimethylpentane 00565-75-3 0.95 18.39 17.444 c-2-Pentene 00627-20-3 10.28 16.98 174.558 2,4-Dimethylpentane 00108-08-7 1.46 14.71 21.471 2-Methylhexane 00591-76-4 1.09 12.51 13.577 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 11.33 132.658 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 11.07 35.326 t-2-Hexene 04050-45-7 8.55 10.95 93.620 2,3-Dimethylpentane 00565-59-3 1.25 10.18 12.710 2,3,5-Trimethylhexane 01069-53-0 1.12 9.69 10.858 3-Methyl-t-2-pentene 00616-12-6 11.66 9.57 111.535 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 9.08 48.126 c-2-Butene 00590-18-1 14.26 8.88 126.689 Methylcyclohexane 00108-87-2 1.56 8.47 13.172 2,4-Dimethylhexane 00589-43-5 1.61 8.25 13.252 1-Methylcyclopentene 00693-89-0 12.45 8.00 99.614 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 7.16 38.440 3-Methyl-c-2-pentene 00922-62-3 12.52 7.15 89.462 2,2,5-Trimethylhexane 03522-94-9 1.05 6.83 7.194 Cyclopentene 00142-29-0 6.69 6.79 45.423 2-Methyl-2-pentene 00625-27-4 11.03 6.69 73.811 n-Heptane 00142-82-5 0.97 6.30 6.086 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 6.28 10.088 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 5.94 39.243 2,2-Dimethylbutane 00075-83-2 1.11 5.57 6.195 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 5.34 23.450 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 5.32 39.329 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 4.55 4.964 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 4.53 35.955 Vehicle 221b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7716 Non Zero Mass Species Sorted By VOC

## E

- 240 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7716 Non Zero Mass Species Sorted By VOC

ortho-Xylene 00095-47-6 7.58 4.42 33.470 Ethanol 00064-17-5 1.45 4.18 6.063 Ethylbenzene 00100-41-4 2.96 3.64 10.793 t-1,2-Dimethylcyclopentane 00822-50-4 2.88 3.01 8.650 2-Methylpropane 00075-28-5 1.18 2.94 3.457 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 2.89 16.719 c-1,3-Dimethylcyclopentane 02532-58-3 2.88 2.38 6.852 3-Methylheptane 00589-81-1 1.12 2.31 2.599 n-Propylbenzene 00103-65-1 1.96 2.00 3.927 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.99 11.025 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.99 23.385 2,2-Dimethylpentane 00590-35-2 1.04 1.94 2.028 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 1.86 14.558 Propane 00074-98-6 0.46 1.73 0.792 n-Octane 00111-65-9 0.80 1.50 1.198 2-Methylheptane 00592-27-8 0.97 1.49 1.445 1,2,3-Trimethylbenzene 00526-73-8 11.94 1.31 15.644 2,2,3-Trimethylbutane 00464-06-2 1.05 1.17 1.236 Unknown #5 2.88 1.17 3.358 Unknown #16 2.88 1.03 2.969 3,3-Dimethylpentane 00562-49-2 1.12 1.03 1.151 c-1,3-Dimethylcyclohexane 00638-04-0 2.88 0.99 2.849 Isopropylbenzene (Cumene) 00098-82-8 2.88 0.99 2.837 1-MeCyHexene & 4-MeHeptane 00591-49-1+00589-53-7 3.86 0.86 3.327 n-Decane 00124-18-5 0.59 0.82 0.487 c-2-Heptene 06443-92-1 7.08 0.82 5.775 Unknown #1 2.88 0.80 2.302 3-Me-t-3-Hexene & t-2-Heptene 03899-36-3+14686-13-6 8.38 0.78 6.535 Indan 00496-11-7 3.23 0.77 2.482 3,5-Dimethylheptane 00926-82-9 1.42 0.75 1.061 1,4-Diethylbenzene 00105-05-5 4.39 0.70 3.062 4-Methyloctane 02216-34-4 0.85 0.70 0.592 3-Methyloctane 02216-33-3 0.88 0.68 0.603 Styrene 00100-42-5 1.66 0.67 1.111 Unknown #8 2.88 0.63 1.802 1-Nonene 00124-11-8 2.49 0.56 1.386 t-3-Heptene 14686-14-7 6.17 0.54 3.357 3,3-Dimethylhexane 00563-16-6 1.15 0.49 0.565 1,3-Dimethyl-2-Ethylbenzene 02870-04-4 10.16 0.48 4.882 2,4,4-TMe-1- & 2,3-DMe-2-Pentene 00107-39-1+10574-37-5 6.54 0.40 2.620 n-Nonane 00111-84-2 0.68 0.38 0.260 2,4-Dimethylheptane 02213-23-2 1.26 0.35 0.447 

### continued

**continued**

## E

- 241 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 221b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7716 Non Zero Mass Species Sorted By VOC

n-Undecane 01120-21-4 0.52 0.34 0.178 1-Heptene 00592-76-7 4.29 0.28 1.188 Unknown #3 2.88 0.22 0.619 1,1-Dimethylcyclohexane 00590-66-9 1.12 0.17 0.185 t-1,3 & c-1,4-DiMeCyHexane 02207-03-6+00624-29-3 2.88 0.16 0.462 t-4-Octene 14850-23-8 4.69 0.12 0.553

Total 1644.2 4729.0 2.876

No MIR available, use weighted average of 2.8762

## E

- 242 Test Fuel Test No. Bag THC mg GC as % of THC GC VOC

mg Ozone mg Reactivity Species Present 86 ° F E10 - 10 psi 7552 12.2 212.7 26.0 76.7 2.953 21 Static E10 - 7 psi 7576 28.2 95.7 27.0 73.7 2.729 29 E0 - 9 psi 7655 6.4 79.8 5.1 28.5 5.617 10 E0 - 7 psi 7712 7.0 215.7 15.1 59.6 3.957 24

105 ° F E10 - 10 psi 7554 20.6 163.4 33.7 119.6 3.545 32 Static E10 - 7 psi 7578 28.9 111.3 32.1 134.5 4.189 41 E0 - 9 psi 7659 11.7 180.8 21.2 100.3 4.734 46 E0 - 7 psi 7715 14.0 228.9 32.1 165.4 5.146 43

Dynamic E10 - 10 psi 25779 73.3 30.1 22.1 54.9 2.488 22 E10 - 7 psi 25785 51.6 66.8 34.5 81.1 2.351 21 E0 - 9 psi 25791 33.5 145.1 48.6 231.3 4.759 19 E0 - 7 psi 25808 97.2 72.7 70.6 220.5 3.122 39

DHB E10 - 10 psi 7558 257.2 70.4 181.0 525.8 2.905 68 Total E10 - 7 psi 7580 287.6 93.6 269.1 853.3 3.171 66 E0 - 9 psi 7696 177.2 95.4 169.1 728.2 4.307 64 E0 - 7 psi 7742 136.4 67.5 92.1 286.4 3.111 47 

## Vehicle 222b

## E

- 243 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 3.93 11.33 44.477 n-Hexane 00110-54-3 1.13 1.49 1.687 n-Pentane 00109-66-0 1.21 1.32 1.607 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.30 1.557 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 1.25 1.750 Benzene 00071-43-2 0.69 1.19 0.823 Cyclohexane 00110-82-7 1.14 1.07 1.216 2,3,3-Trimethylpentane 00560-21-4 0.95 0.71 0.673 3-Methylpentane 00096-14-0 1.69 0.70 1.187 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.69 2.217 2-Methylhexane 00591-76-4 1.09 0.66 0.713 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.60 4.685 Methylcyclopentane 00096-37-7 2.05 0.59 1.210 2-Methylbutane (Isopentane) 00078-78-4 1.35 0.57 0.770 2,3-Dimethylpentane 00565-59-3 1.25 0.48 0.596 2,4-Dimethylpentane 00108-08-7 1.46 0.42 0.610 2,3-Dimethylbutane 00079-29-8 0.90 0.41 0.372 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.38 2.425 2-Methyl-1-butene 00563-46-2 6.38 0.30 1.885 t-2-Pentene 00646-04-8 10.47 0.27 2.866 2-Methyl-2-butene 00513-35-9 14.20 0.24 3.340

Total 26.0 76.7 2.953 Vehicle 222b - Fuel 10 psi E10 - 86 ° F Static - Test 7552 Non Zero Mass Species Sorted By VOC

## E

- 244 Species CAS No. MIR Composite VOC

mg Ozone mg Ethanol 00064-17-5 1.45 4.92 7.125 n-Butane 00106-97-8 1.08 3.90 4.200 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 2.99 13.133 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.83 15.207 Toluene 00108-88-3 3.93 2.21 8.674 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.91 14.814 n-Hexane 00110-54-3 1.13 1.28 1.449 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.12 1.339 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.10 12.894 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.93 1.300 n-Pentane 00109-66-0 1.21 0.90 1.096 ortho-Xylene 00095-47-6 7.58 0.83 6.310 Benzene 00071-43-2 0.69 0.72 0.500 3-Methylpentane 00096-14-0 1.69 0.69 1.173 Cyclohexane 00110-82-7 1.14 0.65 0.736 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.60 3.313 4-Isopropyltoluene (p-Cymene) 00099-87-6 4.41 0.58 2.573 2,2-DiMeHexane 00590-73-8 0.94 0.55 0.519 Ethylbenzene 00100-41-4 2.96 0.54 1.595 2,3,3-Trimethylpentane 00560-21-4 0.95 0.52 0.487 n-Propylbenzene 00103-65-1 1.96 0.49 0.960 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.44 1.405 Methylcyclopentane 00096-37-7 2.05 0.43 0.884 2-Methyl-2-Hexene & c-3-Heptene 02738-19-4+07642-10-6 7.84 0.42 3.265 t-2-Pentene 00646-04-8 10.47 0.39 4.041 2-Methyl-2-butene 00513-35-9 14.20 0.35 4.951 2,3-Dimethylbutane 00079-29-8 0.90 0.34 0.302 2,4-Dimethylpentane 00108-08-7 1.46 0.31 0.459 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.31 1.930 c-2-Pentene 00627-20-3 10.28 0.26 2.662 2-Methylhexane 00591-76-4 1.09 0.20 0.222 2-Methylbutane (Isopentane) 00078-78-4 1.35 0.03 0.044

Total 33.7 119.6 3.545 Vehicle 222b - Fuel 10 psi E10 - 105 ° F Static - Test 7554 Non Zero Mass Species Sorted By VOC

## E

- 245 Species CAS No. MIR Composite VOC

mg Ozone mg 2,4-Dimethylhexane 00589-43-5 1.61 2.97 4.776 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.81 3.364 2,3,5-Trimethylhexane 01069-53-0 1.12 2.16 2.419 c-2-Pentene 00627-20-3 10.28 2.00 20.515 2,2,5-Trimethylhexane 03522-94-9 1.05 1.70 1.792 2,3-Dimethylbutane 00079-29-8 0.90 1.55 1.394 2-Methylbutane (Isopentane) 00078-78-4 1.35 1.52 2.055 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 1.13 1.816 2,3,4-Trimethylpentane 00565-75-3 0.95 0.92 0.871 n-Pentane 00109-66-0 1.21 0.65 0.786 2-Methylhexane 00591-76-4 1.09 0.62 0.676 Ethanol 00064-17-5 1.45 0.56 0.816 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.56 1.782 Benzene 00071-43-2 0.69 0.55 0.384 ortho-Xylene 00095-47-6 7.58 0.44 3.299 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.37 0.512 t-2-Pentene 00646-04-8 10.47 0.35 3.635 2,3-Dimethylpentane 00565-59-3 1.25 0.34 0.429 2-Methyl-1-butene 00563-46-2 6.38 0.33 2.075 Toluene 00108-88-3 3.93 0.24 0.929 3-Methylpentane 00096-14-0 1.69 0.22 0.364 Methylcyclopentane 00096-37-7 2.05 0.08 0.173

Total 22.1 54.9 2.488 Vehicle 222b - Fuel 10 psi E10 - Dynamic - Test 25779 Non Zero Mass Species Sorted By VOC

## E

- 246 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 40.78 55.250 Ethanol 00064-17-5 1.45 23.27 33.720 n-Butane 00106-97-8 1.08 21.95 23.642 Toluene 00108-88-3 3.93 11.56 45.359 n-Pentane 00109-66-0 1.21 5.85 7.110 n-Hexane 00110-54-3 1.13 5.15 5.844 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 3.39 39.620 Cyclohexane 00110-82-7 1.14 3.32 3.772 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.28 3.929 Benzene 00071-43-2 0.69 3.25 2.257 2,2-DiMeHexane 00590-73-8 0.94 3.21 3.019 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 3.13 4.377 t-2-Pentene 00646-04-8 10.47 2.77 29.061 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.70 19.972 2-Methyl-2-butene 00513-35-9 14.20 2.54 36.085 3-Methylpentane 00096-14-0 1.69 2.36 3.987 2-Methyl-1-butene 00563-46-2 6.38 2.32 14.800 1-Butyne 00107-00-6 6.05 2.25 13.628 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.20 17.064 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.78 9.562 Methylcyclopentane 00096-37-7 2.05 1.74 3.560 2,3-Dimethylbutane 00079-29-8 0.90 1.63 1.467 c-2-Pentene 00627-20-3 10.28 1.56 16.016 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.29 15.193 2,3,4-Trimethylpentane 00565-75-3 0.95 1.29 1.226 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.24 3.948 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.17 6.503 Methylcyclohexane 00108-87-2 1.56 1.17 1.812 2,4-Dimethylpentane 00108-08-7 1.46 1.15 1.680 2,3-Dimethylpentane 00565-59-3 1.25 1.11 1.384 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.01 8.015 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.95 4.161 2-Methylhexane 00591-76-4 1.09 0.93 1.011 c-2-Butene 00590-18-1 14.26 0.90 12.800 n-Heptane 00142-82-5 0.97 0.90 0.865 n-Decane 00124-18-5 0.59 0.87 0.514 ortho-Xylene 00095-47-6 7.58 0.82 6.192 2,3,5-Trimethylhexane 01069-53-0 1.12 0.77 0.865 2,2,5-Trimethylhexane 03522-94-9 1.05 0.77 0.808 2,4-Dimethylhexane 00589-43-5 1.61 0.75 1.208 3-Methyl-c-2-pentene 00922-62-3 12.52 0.75 9.327 t-2-Hexene 04050-45-7 8.55 0.70 6.011 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.64 0.702 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.63 3.364 Vehicle 222b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7558 Non Zero Mass Species Sorted By VOC

## E

- 247 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 222b - Fuel 10 psi E10 - 3 Day Diurnal - Test 7558 Non Zero Mass Species Sorted By VOC

1,3-Butadiene 00106-99-0 12.45 0.58 7.233 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.57 0.922 Indan 00496-11-7 3.23 0.56 1.819 3-Methyl-t-2-pentene 00616-12-6 11.66 0.55 6.363 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.53 3.501 n-Octane 00111-65-9 0.80 0.51 0.404 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.50 5.973 n-Propylbenzene 00103-65-1 1.96 0.50 0.977 2-Methylheptane 00592-27-8 0.97 0.47 0.459 Ethylbenzene 00100-41-4 2.96 0.45 1.330 1,4-Dimethyl-2-Ethylbenzene 01758-88-9 7.54 0.41 3.126 2,2-Dimethylbutane 00075-83-2 1.11 0.38 0.424 2-Methyl-2-pentene 00625-27-4 11.03 0.37 4.110 c-1,3-Dimethylcyclopentane 02532-58-3 2.90 0.37 1.082 2,2-Dimethylpentane 00590-35-2 1.04 0.36 0.374 3,3-Dimethylpentane 00562-49-2 1.12 0.33 0.366 Cyclopentene 00142-29-0 6.69 0.32 2.143 t-1,2-Dimethylcyclopentane 00822-50-4 2.90 0.26 0.760 3-Methylheptane 00589-81-1 1.12 0.24 0.270 2,2,3-Trimethylbutane 00464-06-2 1.05 0.21 0.226 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.21 1.484 4-Methyl-t-2-pentene 00674-76-0 8.04 0.17 1.392 1-Dodecene 00112-41-4 1.56 0.17 0.265 n-Undecane 01120-21-4 0.52 0.17 0.087

Total 181.0 525.8 2.905

No MIR available, use weighted average of 2.9048 

### continued

## E

- 248 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 9.028 12.231 n-Butane 00106-97-8 1.08 4.627 4.983 Ethanol 00064-17-5 1.45 2.319 3.360 Unknown #2 2.73 1.701 4.641 3-Methylnonane 05911-04-6 0.66 1.336 0.876 n-Pentane 00109-66-0 1.21 1.297 1.576 Toluene 00108-88-3 3.93 0.916 3.596 2-Methyl-2-butene 00513-35-9 14.20 0.758 10.755 2-Methyl-1-butene 00563-46-2 6.38 0.691 4.410 t-2-Pentene 00646-04-8 10.47 0.636 6.661 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.464 5.431 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.448 3.477 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.408 4.797 ortho-Xylene 00095-47-6 7.58 0.281 2.125 2,3-Dimethylpentane 00565-59-3 1.25 0.274 0.342 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.268 1.485 2,4-Dimethylpentane 00108-08-7 1.46 0.230 0.336 2-Methylhexane 00591-76-4 1.09 0.225 0.244 2,2-Dimethylbutane 00075-83-2 1.11 0.204 0.226 Methylcyclopentane 00096-37-7 2.05 0.193 0.396 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.159 0.507 Benzene 00071-43-2 0.69 0.116 0.080 n-Hexane 00110-54-3 1.13 0.104 0.118 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.094 0.112 c-2-Pentene 00627-20-3 10.28 0.072 0.739 n-Undecane 01120-21-4 0.52 0.071 0.037 Cyclohexane 00110-82-7 1.14 0.054 0.061 Ethylbenzene 00100-41-4 2.96 0.026 0.078 3-Methylpentane 00096-14-0 1.69 0.005 0.009

Total 27.0 73.7 2.729

No MIR available, use weighted average of 2.7288 Vehicle 222b - Fuel 7 psi E10 - 86 ° F Static - Test 7576 Non Zero Mass Species Sorted By VOC

## E

- 249 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 7.67 10.390 Ethanol 00064-17-5 1.45 4.52 6.543 n-Butane 00106-97-8 1.08 2.20 2.375 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 1.75 12.892 n-Pentane 00109-66-0 1.21 1.63 1.981 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.48 17.289 Toluene 00108-88-3 3.93 1.24 4.862 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.03 12.159 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.01 4.442 t-2-Pentene 00646-04-8 10.47 0.94 9.838 2-Methyl-2-butene 00513-35-9 14.20 0.92 13.031 2-Methyl-1-butene 00563-46-2 6.38 0.82 5.243 1-Butyne 00107-00-6 6.05 0.69 4.202 Unknown #22

. 4.19 0.61 2.557 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.59 7.017 c-2-Butene 00590-18-1 14.26 0.53 7.609 n-Hexane 00110-54-3 1.13 0.45 0.505 c-2-Pentene 00627-20-3 10.28 0.39 4.061 2,3,5-Trimethylhexane 01069-53-0 1.12 0.39 0.433 2,2-DiMeHexane 00590-73-8 0.94 0.38 0.354 n-Undecane 01120-21-4 0.52 0.36 0.190 n-Propylbenzene 00103-65-1 1.96 0.33 0.652 Methylcyclohexane 00108-87-2 1.56 0.23 0.354 ortho-Xylene 00095-47-6 7.58 0.20 1.538 1,2-Dimethyl-4-Ethylbenzene 00934-80-5 7.54 0.19 1.469 2,2-Dimethylbutane 00075-83-2 1.11 0.19 0.206 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.16 0.265 2,3-Dimethylbutane 00079-29-8 0.90 0.15 0.138 Methylcyclopentane 00096-37-7 2.05 0.14 0.297 n-Heptane 00142-82-5 0.97 0.14 0.140 Benzene 00071-43-2 0.69 0.14 0.098 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.14 0.193 Ethylbenzene 00100-41-4 2.96 0.13 0.392 Cyclohexane 00110-82-7 1.14 0.10 0.118 3-Methylpentane 00096-14-0 1.69 0.07 0.116 2,3-Dimethylpentane 00565-59-3 1.25 0.07 0.086 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.04 0.305 2,3,4-Trimethylpentane 00565-75-3 0.95 0.04 0.036 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.03 0.158 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.01 0.006 2,4-Dimethylpentane 00108-08-7 1.46 0.01 0.008

Total 32.1 134.5 4.189

No MIR available, use weighted average of 4.1888 Vehicle 222b - Fuel 7 psi E10 - 105 ° F Static - Test 7578 Non Zero Mass Species Sorted By VOC

## E

- 250 Species CAS No. MIR Composite VOC

mg Ozone mg n-Propylbenzene 00103-65-1 1.96 10.83 21.219 Ethanol 00064-17-5 1.45 5.29 7.670 Unknown #22

. 2.35 2.68 6.291 Toluene 00108-88-3 3.93 2.66 10.434 2,3,5-Trimethylhexane 01069-53-0 1.12 2.26 2.532 n-Decane 00124-18-5 0.59 1.42 0.839 n-Octane 00111-65-9 0.80 1.15 0.919 2-Methylheptane 00592-27-8 0.97 1.09 1.053 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 1.05 5.803 Indan 00496-11-7 3.23 0.96 3.105 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.93 4.984 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.85 0.928 n-Heptane 00142-82-5 0.97 0.77 0.748 Benzene 00071-43-2 0.69 0.69 0.478 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.64 7.554 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.60 4.395 Ethylbenzene 00100-41-4 2.96 0.31 0.916 ortho-Xylene 00095-47-6 7.58 0.14 1.038 2,2,5-Trimethylhexane 03522-94-9 1.05 0.13 0.137 2,3-Dimethylbutane 00079-29-8 0.90 0.02 0.019 2-Methylhexane 00591-76-4 1.09 0.02 0.023

Total 34.5 81.1 2.351

No MIR available, use weighted average of 2.3514 Vehicle 222b - Fuel 7 psi E10 - Dynamic - Test 25785 Non Zero Mass Species Sorted By VOC

## E

- 251 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 92.55 125.393 Ethanol 00064-17-5 1.45 37.91 54.925 n-Pentane 00109-66-0 1.21 21.15 25.692 2-Methyl-2-butene 00513-35-9 14.20 10.63 150.891 t-2-Pentene 00646-04-8 10.47 10.13 106.146 Toluene 00108-88-3 3.93 9.02 35.392 n-Butane 00106-97-8 1.08 8.38 9.026 2-Methyl-1-butene 00563-46-2 6.38 7.59 48.406 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 5.40 63.239 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 5.40 7.545 n-Hexane 00110-54-3 1.13 5.15 5.840 c-2-Pentene 00627-20-3 10.28 5.02 51.574 Benzene 00071-43-2 0.69 3.58 2.484 2,2-DiMeHexane 00590-73-8 0.94 3.53 3.322 2,3-Dimethylbutane 00079-29-8 0.90 3.29 2.954 Methylcyclopentane 00096-37-7 2.05 2.78 5.694 3-Methylpentane 00096-14-0 1.69 2.68 4.528 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.45 18.079 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 2.29 2.748 Cyclohexane 00110-82-7 1.14 1.73 1.972 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.39 10.766 3-Methyl-c-2-pentene 00922-62-3 12.52 1.28 16.079 2,3,5-Trimethylhexane 01069-53-0 1.12 1.26 1.413 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.14 9.033 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 1.10 3.503 2-Methylhexane 00591-76-4 1.09 1.08 1.174 2,3,4-Trimethylpentane 00565-75-3 0.95 1.01 0.957 2,4-Dimethylpentane 00108-08-7 1.46 0.99 1.447 Methylcyclohexane 00108-87-2 1.56 0.94 1.470 c-2-Butene 00590-18-1 14.26 0.93 13.274 2,2-Dimethylbutane 00075-83-2 1.11 0.90 0.998 2-Methylheptane 00592-27-8 0.97 0.86 0.834 Cyclopentene 00142-29-0 6.69 0.86 5.733 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.81 4.328 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.80 4.634 n-Heptane 00142-82-5 0.97 0.75 0.725 2,2,3-Trimethylbutane 00464-06-2 1.05 0.75 0.786 t-2-Hexene 04050-45-7 8.55 0.74 6.294 n-Decane 00124-18-5 0.59 0.72 0.425 2,3-Dimethylpentane 00565-59-3 1.25 0.69 0.858 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.65 4.312 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.60 3.182 c-1,3-Dimethylcyclopentane 02532-58-3 3.17 0.60 1.904 3-Methyl-t-2-pentene 00616-12-6 11.66 0.57 6.636 Vehicle 222b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7580 Non Zero Mass Species Sorted By VOC

## E

- 252 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 222b - Fuel 7 psi E10 - 3 Day Diurnal - Test 7580 Non Zero Mass Species Sorted By VOC

2-Methyl-2-pentene 00625-27-4 11.03 0.56 6.222 Ethylbenzene 00100-41-4 2.96 0.52 1.552 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.50 0.551 n-Octane 00111-65-9 0.80 0.50 0.397 2,4-Dimethylhexane 00589-43-5 1.61 0.48 0.776 2,2,5-Trimethylhexane 03522-94-9 1.05 0.40 0.416 3,3-Dimethylpentane 00562-49-2 1.12 0.38 0.429 t-1,2-Dimethylcyclopentane 00822-50-4 3.17 0.38 1.198 1c-2t-3-TriMeCyPentane 15890-40-1 3.17 0.35 1.101 4-Methyl-t-2-pentene 00674-76-0 8.04 0.34 2.771 n-Propylbenzene 00103-65-1 1.96 0.34 0.658 3-Methylheptane 00589-81-1 1.12 0.33 0.366 ortho-Xylene 00095-47-6 7.58 0.27 2.025 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.25 0.401 Indan 00496-11-7 3.23 0.24 0.792 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 0.24 1.042 c-1,3-Dimethylcyclohexane 00638-04-0 3.17 0.20 0.642 2-Methyl-1,3-butadiene 00078-79-5 10.48 0.20 2.083 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.17 0.953 n-Nonane 00111-84-2 0.68 0.14 0.094 1-Methyl-3-Propylbenzene 01074-43-7 7.08 0.13 0.886 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.11 1.344

Total 269.1 853.3 3.171

No MIR available, use weighted average of 3.1711 

### continued

## E

- 253 Species CAS No. MIR Composite VOC

mg Ozone mg Toluene 00108-88-3 1.46 0.92 1.336 2-Methyl-2-butene 00513-35-9 14.20 0.69 9.865 t-2-Pentene 00646-04-8 10.47 0.67 6.987 2,2-Dimethylbutane 00075-83-2 1.11 0.62 0.689 c-2-Pentene 00627-20-3 10.28 0.61 6.288 n-Pentane 00109-66-0 1.21 0.60 0.729 n-Heptane 00142-82-5 0.97 0.56 0.541 Cyclopentene 00142-29-0 6.69 0.29 1.914 2-Methylbutane (Isopentane) 00078-78-4 1.35 0.10 0.132 n-Hexane 00110-54-3 1.13 0.02 0.025

Total 5.1 28.5 5.617 Vehicle 222b - Fuel 9 psi E0 - 86 ° F Static - Test 7655 Non Zero Mass Species Sorted By VOC

## E

- 254 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 1.54 2.081 Toluene 00108-88-3 3.93 1.41 5.543 c-2-Butene 00590-18-1 14.26 1.13 16.161 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.11 4.861 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.06 12.518 2,3-Dimethylbutane 00079-29-8 0.90 0.95 0.853 2,3,4-Trimethylpentane 00565-75-3 0.95 0.87 0.822 Ethylbenzene 00100-41-4 2.96 0.84 2.475 n-Pentane 00109-66-0 1.21 0.80 0.967 ortho-Xylene 00095-47-6 7.58 0.60 4.559 2-Methyl-2-butene 00513-35-9 14.20 0.60 8.542 2,4,4-Trimethyl-2-Pentene 00107-40-4 6.30 0.54 3.406 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.53 1.698 n-Heptane 00142-82-5 0.97 0.53 0.513 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.53 6.286 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.52 2.885 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 0.51 2.732 2,3-Dimethylpentane 00565-59-3 1.25 0.46 0.578 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 0.43 3.190 2,4-Dimethylpentane 00108-08-7 1.46 0.42 0.613 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.40 0.481 Methylcyclohexane 00108-87-2 1.56 0.40 0.619 t-2-Pentene 00646-04-8 10.47 0.38 3.995 2,3,5-Trimethylhexane 01069-53-0 1.12 0.38 0.424 2,4-Dimethylhexane 00589-43-5 1.61 0.34 0.542 2-Methylhexane 00591-76-4 1.09 0.32 0.352 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.31 0.440 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.30 0.325 t-2-Hexene 04050-45-7 8.55 0.30 2.540 n-Propylbenzene 00103-65-1 1.96 0.29 0.566 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.26 2.027 n-Butane 00106-97-8 1.08 0.26 0.276 2-Methyl-1-butene 00563-46-2 6.38 0.25 1.611 3-Methylpentane 00096-14-0 1.69 0.24 0.406 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.24 0.383 2,2-Dimethylbutane 00075-83-2 1.11 0.23 0.251 Cyclopentene 00142-29-0 6.69 0.21 1.396 Cyclohexane 00110-82-7 1.14 0.20 0.231 c-2-Pentene 00627-20-3 10.28 0.18 1.878 Benzene 00071-43-2 0.69 0.14 0.095 2,2,5-Trimethylhexane 03522-94-9 1.05 0.12 0.131 n-Hexane 00110-54-3 1.13 0.06 0.073

Total 21.2 100.3 4.734 Vehicle 222b - Fuel 9 psi E0 - 105 ° F Static - Test 7659 Non Zero Mass Species Sorted By VOC

## E

- 255 Species CAS No. MIR Composite VOC

mg Ozone mg 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 14.78 109.195 3-Methylnonane 05911-04-6 0.66 7.99 5.238 1,3,5-Trimethylbenzene 00108-67-8 11.75 4.20 49.413 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.15 3.778 Toluene 00108-88-3 3.93 2.95 11.569 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 2.35 3.766 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.79 14.205 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 1.76 13.636 2,3,5-Trimethylhexane 01069-53-0 1.12 1.70 1.906 n-Propylbenzene 00103-65-1 1.96 1.62 3.182 t-1,4-Dimethylcyclohexane 02207-04-7 4.76 1.35 6.439 2,3,4-Trimethylpentane 00565-75-3 0.95 1.22 1.161 n-Undecane 01120-21-4 0.52 0.89 0.467 n-Octane 00111-65-9 0.80 0.74 0.592 2,2-DiMeHexane 00590-73-8 0.94 0.63 0.592 t-3-Heptene 14686-14-7 6.17 0.51 3.175 Ethylbenzene 00100-41-4 2.96 0.39 1.165 2-Methylhexane 00591-76-4 1.09 0.37 0.396 ortho-Xylene 00095-47-6 7.58 0.18 1.389

Total 48.6 231.3 4.759

No MIR available, use weighted average of 4.7594 Vehicle 222b - Fuel 9 psi E0 - Dynamic - Test 25791 Non Zero Mass Species Sorted By VOC

## E

- 256 Species CAS No. MIR Composite VOC

mg Ozone mg 2-Methylbutane (Isopentane) 00078-78-4 1.35 29.66 40.180 1,3-Butadiene 00106-99-0 12.45 17.21 214.335 Toluene 00108-88-3 3.93 12.92 50.712 Ethanol 00064-17-5 1.45 12.91 18.706 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 7.64 10.680 Cyclohexane 00110-82-7 1.14 6.43 7.310 n-Hexane 00110-54-3 1.13 5.51 6.253 n-Pentane 00109-66-0 1.21 5.34 6.491 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.71 34.801 3-Methylpentane 00096-14-0 1.69 4.18 7.076 Methylcyclohexane 00108-87-2 1.56 4.04 6.278 2,3-Dimethylbutane 00079-29-8 0.90 3.62 3.250 2-Methyl-1-butene 00563-46-2 6.38 3.40 21.671 t-2-Pentene 00646-04-8 10.47 3.33 34.860 2-Methyl-2-butene 00513-35-9 14.20 3.29 46.756 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 3.28 3.928 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 3.02 23.403 1-Butyne 00107-00-6 6.05 2.86 17.332 Benzene 00071-43-2 0.69 2.53 1.757 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 2.27 12.196 Methylcyclopentane 00096-37-7 2.05 1.97 4.035 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.90 8.327 c-2-Pentene 00627-20-3 10.28 1.70 17.465 3,3-Dimethylpentane 00562-49-2 1.12 1.59 1.780 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 1.55 18.134 2,3,4-Trimethylpentane 00565-75-3 0.95 1.51 1.437 c-2-Butene 00590-18-1 14.26 1.28 18.226 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.21 9.587 2,2-Dimethylbutane 00075-83-2 1.11 1.09 1.212 Ethylbenzene 00100-41-4 2.96 1.00 2.974 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.98 5.200 2,3,5-Trimethylhexane 01069-53-0 1.12 0.98 1.094 2,4-Dimethylpentane 00108-08-7 1.46 0.77 1.119 2,2,5-Trimethylhexane 03522-94-9 1.05 0.74 0.780 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.69 3.848 t-2-Hexene 04050-45-7 8.55 0.66 5.657 2-Methylhexane 00591-76-4 1.09 0.65 0.708 ortho-Xylene 00095-47-6 7.58 0.65 4.921 2,3-Dimethylpentane 00565-59-3 1.25 0.65 0.807 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.58 0.938 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.56 0.611 3-Methyl-t-2-pentene 00616-12-6 11.66 0.53 6.212 3-Methyl-c-2-pentene 00922-62-3 12.52 0.50 6.248 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.50 2.861 Vehicle 222b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7696 Non Zero Mass Species Sorted By VOC

## E

- 257 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 222b - Fuel 9 psi E0 - 3 Day Diurnal - Test 7696 Non Zero Mass Species Sorted By VOC

1-Methylcyclopentene 00693-89-0 12.45 0.46 5.729 c-1,3-Dimethylcyclohexane 00638-04-0 4.31 0.46 1.970 4-Methyl-t-2-pentene 00674-76-0 8.04 0.45 3.652 2-Methyl-2-pentene 00625-27-4 11.03 0.44 4.888 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.42 4.959 c-2-Hexene & 3-MeCyclopentene 07688-21-3+01120-62-3 6.61 0.42 2.779 n-Heptane 00142-82-5 0.97 0.41 0.392 2,4-Dimethylhexane 00589-43-5 1.61 0.39 0.632 2,2-Dimethylpentane 00590-35-2 1.04 0.37 0.382 n-Octane 00111-65-9 0.80 0.32 0.253 n-Undecane 01120-21-4 0.52 0.31 0.163 n-Propylbenzene 00103-65-1 1.96 0.31 0.608 Cyclopentene 00142-29-0 6.69 0.30 2.020 t-1,2-Dimethylcyclopentane 00822-50-4 4.31 0.28 1.189 3-Methylheptane 00589-81-1 1.12 0.27 0.305 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.24 2.867 c-2-Heptene 06443-92-1 7.08 0.23 1.602 2-Methylheptane 00592-27-8 0.97 0.21 0.205 c-1,3-Dimethylcyclopentane 02532-58-3 4.31 0.20 0.845 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.18 0.585

Total 169.1 728.2 4.307

No MIR available, use weighted average of 4.3074 

### continued

## E

- 258 Species CAS No. MIR Composite VOC

mg Ozone mg n-Butane 00106-97-8 1.08 4.26 4.585 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 2.34 17.308 2-Methylbutane (Isopentane) 00078-78-4 1.35 1.49 2.014 Toluene 00108-88-3 3.93 1.04 4.064 c-2-Butene 00590-18-1 14.26 0.83 11.892 Cyclohexane 00110-82-7 1.14 0.70 0.794 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 0.59 4.567 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.50 2.637 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.43 0.518 2,4-Dimethylhexane 00589-43-5 1.61 0.41 0.663 3-Methylpentane 00096-14-0 1.69 0.39 0.653 n-Pentane 00109-66-0 1.21 0.27 0.323 2,4-Dimethylpentane 00108-08-7 1.46 0.25 0.358 1,3,5-Trimethylbenzene 00108-67-8 11.75 0.24 2.801 Methylcyclopentane 00096-37-7 2.05 0.21 0.434 2-Methyl-2-butene 00513-35-9 14.20 0.21 2.918 t-2-Hexene 04050-45-7 8.55 0.20 1.712 n-Hexane 00110-54-3 1.13 0.18 0.199 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.12 0.660 2,3,4-Trimethylpentane 00565-75-3 0.95 0.11 0.103 2,3-Dimethylbutane 00079-29-8 0.90 0.11 0.095 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.11 0.147 Benzene 00071-43-2 0.69 0.08 0.053 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.03 0.093

Total 15.1 59.6 3.957 Vehicle 222b - Fuel 7 psi E0 - 86 ° F Static - Test 7712 Non Zero Mass Species Sorted By VOC

## E

- 259 Species CAS No. MIR Composite VOC

mg Ozone mg Benzene 00071-43-2 0.69 0.20 0.142 2-Methylpropane 00075-28-5 1.18 0.97 1.141 2,2-Dimethylbutane 00075-83-2 1.11 0.13 0.140 2-Methylbutane (Isopentane) 00078-78-4 1.35 2.90 3.932 2,3-Dimethylbutane 00079-29-8 0.90 0.26 0.234 ortho-Xylene 00095-47-6 7.58 0.57 4.329 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 3.71 19.912 3-Methylpentane 00096-14-0 1.69 0.20 0.333 Ethylbenzene 00100-41-4 2.96 0.51 1.513 n-Propylbenzene 00103-65-1 1.96 0.35 0.695 n-Butane 00106-97-8 1.08 0.96 1.039 2,4-Dimethylpentane 00108-08-7 1.46 0.19 0.271 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.35 18.237 1,3,5-Trimethylbenzene 00108-67-8 11.75 1.40 16.495 Methylcyclohexane 00108-87-2 1.56 0.35 0.537 Toluene 00108-88-3 3.93 1.10 4.315 n-Pentane 00109-66-0 1.21 0.70 0.850 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.22 2.538 n-Hexane 00110-54-3 1.13 0.76 0.863 Cyclohexane 00110-82-7 1.14 0.53 0.603 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.27 0.863 n-Octane 00111-65-9 0.80 0.02 0.013 Cyclopentene 00142-29-0 6.69 0.13 0.869 n-Heptane 00142-82-5 0.97 0.22 0.210 Indan 00496-11-7 3.23 0.67 2.176 2-Methyl-2-butene 00513-35-9 14.20 0.09 1.216 1,2,3-Trimethylbenzene 00526-73-8 11.94 0.63 7.531 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 0.32 0.390 2-Methyl-1-butene 00563-46-2 6.38 0.17 1.093 2,3-Dimethylpentane 00565-59-3 1.25 0.17 0.218 2,3,4-Trimethylpentane 00565-75-3 0.95 0.18 0.169 2,4-Dimethylhexane 00589-43-5 1.61 0.03 0.050 3-Methylheptane 00589-81-1 1.12 0.23 0.261 c-2-Butene 00590-18-1 14.26 0.56 7.938 2-Methylhexane 00591-76-4 1.09 0.04 0.040 2-Methylheptane 00592-27-8 0.97 0.38 0.371 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.04 0.193 1-Ethyl-2-Methylbenzene 00611-14-3 5.54 0.72 3.986 3-Methyl-t-2-pentene 00616-12-6 11.66 0.36 4.179 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 6.49 47.900 1-Methyl-4-Ethylbenzene 00622-96-8 4.39 1.54 6.787 t-2-Pentene 00646-04-8 10.47 0.01 0.112 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 0.51 0.713

Total 32.1 165.4 5.146 Vehicle 222b - Fuel 7 psi E0 - 105 ° F Static - Test 7715 Non Zero Mass Species Sorted By VOC

## E

- 260 Species CAS No. MIR Composite VOC

mg Ozone mg 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 9.93 13.882 Toluene 00108-88-3 3.93 8.56 33.605 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 5.80 6.951 1-Methyl-3-Ethylbenzene 00620-14-4 7.39 4.33 32.008 Cyclohexane 00110-82-7 1.14 3.63 4.126 2-Methylbutane (Isopentane) 00078-78-4 1.35 3.11 4.212 1-Butyne 00107-00-6 6.05 3.06 18.514 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 2.60 20.131 2,3,5-Trimethylhexane 01069-53-0 1.12 2.41 2.694 n-Hexane 00110-54-3 1.13 2.31 2.621 2,3,4-Trimethylpentane 00565-75-3 0.95 1.47 1.393 2,4-Dimethylpentane 00108-08-7 1.46 1.40 2.042 3-Methylpentane 00096-14-0 1.69 1.36 2.300 t-2-Pentene 00646-04-8 10.47 1.35 14.118 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 1.34 10.680 n-Undecane 01120-21-4 0.52 1.29 0.673 t-2-Hexene 04050-45-7 8.55 1.29 11.000 Methylcyclopentane 00096-37-7 2.05 1.29 2.637 n-Octane 00111-65-9 0.80 1.12 0.890 n-Butane 00106-97-8 1.08 1.01 1.091 2-Methylhexane 00591-76-4 1.09 0.95 1.028 2,2-Dimethylpentane 00590-35-2 1.04 0.93 0.966 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.85 0.933 2,4-Dimethylhexane 00589-43-5 1.61 0.82 1.315 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.80 1.281 n-Heptane 00142-82-5 0.97 0.76 0.732 2,3-Dimethylbutane 00079-29-8 0.90 0.76 0.679 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.75 2.405 2,2,5-Trimethylhexane 03522-94-9 1.05 0.74 0.783 2-Methyl-1-butene 00563-46-2 6.38 0.70 4.438 Benzene 00071-43-2 0.69 0.69 0.481 2-Methyl-2-butene 00513-35-9 14.20 0.63 8.950 Methylcyclohexane 00108-87-2 1.56 0.60 0.931 c-2-Pentene 00627-20-3 10.28 0.59 6.036 2,3-Dimethylpentane 00565-59-3 1.25 0.58 0.726 Ethylbenzene 00100-41-4 2.96 0.52 1.536 Unknown #22

. 3.12 0.12 0.382 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.10 1.227 n-Pentane 00109-66-0 1.21 0.09 0.109

Total 70.6 220.5 3.122

No MIR available, use weighted average of 3.1224 Vehicle 222b - Fuel 7 psi E0 - Dynamic - Test 25808 Non Zero Mass Species Sorted By VOC

## E

- 261 Species CAS No. MIR Composite VOC

mg Ozone mg Benzene 00071-43-2 0.69 1.57 1.088 2,2-Dimethylbutane 00075-83-2 1.11 0.44 0.493 2-Methylbutane (Isopentane) 00078-78-4 1.35 12.03 16.295 2,3-Dimethylbutane 00079-29-8 0.90 3.59 3.228 ortho-Xylene 00095-47-6 7.58 2.09 15.860 1,2,4-TriMeBenz & t-Butylbenzene 00095-63-6+00098-06-6 5.37 1.46 7.829 3-Methylpentane 00096-14-0 1.69 5.15 8.704 Methylcyclopentane 00096-37-7 2.05 1.42 2.904 n-Butane 00106-97-8 1.08 7.14 7.694 2,4-Dimethylpentane 00108-08-7 1.46 0.64 0.930 meta- & para-Xylenes 00108-38-3+00106-42-3 7.76 4.62 35.806 Methylcyclohexane 00108-87-2 1.56 2.36 3.667 Toluene 00108-88-3 3.93 5.87 23.052 n-Pentane 00109-66-0 1.21 2.14 2.598 1-Pentene & 2-Butyne 00109-67-1+00503-17-3 11.70 0.24 2.782 n-Hexane 00110-54-3 1.13 6.58 7.464 Cyclohexane 00110-82-7 1.14 5.00 5.691 Cyclohexene & 3-Methylhexane 00110-83-8+00589-34-4 3.19 0.49 1.552 n-Octane 00111-65-9 0.80 0.45 0.362 n-Nonane 00111-84-2 0.68 0.76 0.518 2-Methylpropene & 1-Butene 00115-11-7+00106-98-9 7.94 0.94 7.476 n-Decane 00124-18-5 0.59 0.70 0.414 Cyclopentene 00142-29-0 6.69 0.35 2.337 n-Heptane 00142-82-5 0.97 0.04 0.037 2-Methyl-2-butene 00513-35-9 14.20 1.57 22.225 2,2,4-TriMePentane (IsoOctane) 00540-84-1 1.20 1.94 2.329 2-Methyl-1-butene 00563-46-2 6.38 0.63 4.037 2,3-Dimethylpentane 00565-59-3 1.25 0.22 0.279 2,3,4-Trimethylpentane 00565-75-3 0.95 0.64 0.611 2,3-DiMeHexane & 2,3-MeEtPentane 00584-94-1+ 1.09 0.37 0.400 2,4-Dimethylhexane 00589-43-5 1.61 0.30 0.487 c-2-Butene 00590-18-1 14.26 1.14 16.253 2-Methylhexane 00591-76-4 1.09 0.34 0.364 2,5-DiMeHexane & EtCyPentane 00592-13-2+01640-89-7 1.61 0.02 0.031 2-Methyl-1-pentene & 1-Hexene 00592-41-6+00763-29-1 5.30 0.56 2.968 3-Methyl-t-2-pentene 00616-12-6 11.66 0.59 6.832 t-2-Butene 00624-64-6 15.20 1.18 17.923 2-Methyl-2-pentene 00625-27-4 11.03 0.40 4.405 c-2-Pentene 00627-20-3 10.28 0.48 4.932 t-2-Pentene 00646-04-8 10.47 1.09 11.444 3 & 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 5.78 0.69 4.003 2-MePentane & 4-Me-c-2-Pentene 00691-38-3+00107-83-5 1.40 8.95 12.511 3-Methyl-c-2-pentene 00922-62-3 12.52 0.48 6.045 2,3,5-Trimethylhexane 01069-53-0 1.12 0.73 0.818 Vehicle 222b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7742 Non Zero Mass Species Sorted By VOC

## E

- 262 Species CAS No. MIR Composite VOC

mg Ozone mg Vehicle 222b - Fuel 7 psi E0 - 3 Day Diurnal - Test 7742 Non Zero Mass Species Sorted By VOC

n-Undecane 01120-21-4 0.52 2.40 1.255 2,2,5-Trimethylhexane 03522-94-9 1.05 0.45 0.470 t-2-Hexene 04050-45-7 8.55 0.82 6.991

Total 92.1 286.4 3.111 

### continued