## Prepared for

P ROJECT 

## N O 

## .: 12 84

September 1 6 , 20 1 0 

# NY DEC SGEIS

I NFORMATION



# R EQUESTS

AND NDUSTRY



# R E S PONSES

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# i Table of Contents

Introduction

................................ ................................ ................................ ................................ ................. 1

IOGA’s Preamble to All Responses

................................ ................................ ................................ ........... 2

Activity Estimates

................................ ................................ ................................ ................................ ....... 5

a. Regional Ozone Precursors

................................ ................................ ................................ ......... 1 0

b. Land Disturbance

................................ ................................ ................................ ........................ 1 3

c. Landfills

................................ ................................ ................................ ................................ ...... 1 5

Air Impacts

................................ ................................ ................................ ................................ ................ 1 8

1. Simultaneous Operations

................................ ................................ ................................ ............ 1 8

2. Centralized Impoundments

................................ ................................ ................................ ......... 1 8

3. Produced Water Quality

................................ ................................ ................................ ............. 19

4. Potential for Air Emissions from Produced Water

................................ ................................ ..... 37

5. Duration of C ontinuous Operations at an Individual Well Pad

................................ .................. 38

6. Particulate Matter Modeling

................................ ................................ ................................ ....... 40

7. Mitigation Measures

................................ ................................ ................................ ................... 40

8. Mitigation Measures for Impoundments

................................ ................................ .................... 4 4

9. Annualized Emissions

................................ ................................ ................................ ................ 4 5

10. H 2 

## S Data

................................ ................................ ................................ ................................ ..... 4 9

11. 1

- hour National Ambient Air Quality Standard for NO 2



## ................................ ............................ 4 9

Alternatives

................................ ................................ ................................ ................................ ................ 5 3

1. Comparison of Specific HVHF Additives to Class GA Groundwater Standards

....................... 5 3

2. UV Light as a Substitute for Biocide

................................ ................................ .......................... 5 6

Casing and Cement

................................ ................................ ................................ ................................ ... 59

1. Casing Requirements

................................ ................................ ................................ .................. 59

2. Casing Thread Compound

................................ ................................ ................................ .......... 6 0

3. Cement Requirements

................................ ................................ ................................ ................ 6 0

4. Centralizer Requirements

................................ ................................ ................................ ........... 6 1

5. Radial Cement Bond Log

................................ ................................ ................................ ........... 6 1

6. Centralizer Spacing

................................ ................................ ................................ ..................... 6 2

Centralized Facilities

................................ ................................ ................................ ................................ 6 3

1.

- 5. Centralized Impoundments

................................ ................................ ................................ ......... 6 3

6. Centralized Compression

................................ ................................ ................................ ............ 6 4

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# ii Drill Cuttings Characterization

................................ ................................ ................................ ............... 6 6

1. Marcellus Cuttings Data

................................ ................................ ................................ ............. 6 6

2. Segregation and Disposal of Cuttings

................................ ................................ ......................... 68

Produced Water Characterization

................................ ................................ ................................ .......... 7 0

1. Maximum TDS

................................ ................................ ................................ ........................... 7 0

Produced Water Reuse/Recycling

................................ ................................ ................................ ........... 7 3

1. Recycling Methodologies

................................ ................................ ................................ ........... 7 3

2. Use of On

- Site Reserve Pits for Recycling

................................ ................................ ................. 7 6

Greenhouse Gas

................................ ................................ ................................ ................................ ........ 78

1. Greenhouse Gas Mitigation Measures

................................ ................................ ........................ 78

Hydraulic Fracturing Additives

– Composition and Man a gement

................................ ...................... 8 0

1. Anticipated Use of Additives in NY

................................ ................................ ........................... 8 0

2. Unattended Chemicals

................................ ................................ ................................ ................ 8 2

Naturally Occurring Radioactive Materials

................................ ................................ ........................... 8 3

1. Naturally Occurring Radioactive Materials Data

................................ ................................ ....... 8 3

Well Development Patterns

................................ ................................ ................................ ...................... 87

1. Potential Well Configurations

................................ ................................ ................................ .... 87

Traffic

................................ ................................ ................................ ................................ ........................ 9 0

1. Estimated Daily Truck Traffic

................................ ................................ ................................ .... 9 0

ATTACHMENTS

Attachment A Marcellus Shale Coalition Study: ―Sampling and Analysis of Water Streams Associated

with the Development of Marcellus Shale Gas, Final Report‖

Attachment B Marcellus Shale Coalition Database for the 8 Northern Pennsylvania Wells

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# iii Acronyms and Abbreviations

μg microgram

AKRF Allee King Rosen and Fleming, Inc.

API American Petroleum Institute

ASTDR Agency for Toxic Substances and Disease Registry

ASTM American Society for Testing and Materials

bbl barrel

bhp

- hr brake horsepower

- hour

BMP best management practice

BOD Biochemical oxygen demand

BOP blow

- out preventer

bpm barrels per minute

C&D Construction and Demolition Debris

CAA Clean Air Act

CBL cement bond logs

CFR Code of Federal Regulations

cm 2 

## square centimeter

CO 2 

## e carbon dioxide equivalents

COD Chemical oxygen demand

DEC New York State Department of Environmental Conservation

DFW Dallas

- Fort Worth

DOC diesel oxidation catalyst

DOT U.S. Department of Transportation

DPF diesel particulate filte rs

dpm disintegrations per minute

dSGEIS draft Supplemental Generic Environmental Impact Statement

EI emission inventory

EIA U.S. Energy Information Administration

EIS Environmental Impact Statement

EPA U.S. Environmental Protection Agency

ft foot/fe et

g gram

GHG Greenhouse Gas

H 2 

## S Hydrogen sulfide

HESI Halliburton Energy Services, Inc.

hp horsepower

hr hour

HVHF high volume hydraulic fracturing

IOGA Independent Oil and Gas Association of New York

L liter

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# iv lb pound

m meter

m 2 

## square meter

MBAS Methylene blue activated substances

MDC Minimum detectable concentration

mg milligram

mi 2 

## square mile

MSC Marcellus Shale Coalition

MSW Municipal Solid Waste (MSW)

mW megaWatt

MWD measurement

- while

- drilling

NAAQS National Ambient Air Quality Standards

NCRP National Council on Radiation Protection and Measurements

NEPA National Environmental Policy Act

NGO non

- governmental organization

nm nanometer

NO Nitric oxide

NO 2 

## Nitrogen dioxide

NO

x 

## Oxides of nitrogen

NORM naturally occurring radi oactive material

NRDC Natural Resources Defense Council

NYSERDA New York State Energy Research and Development Authority

PA DEP Pennsylvania Department of Environmental Protection

PAH Polynuclear aromatic hydrocarbon

PCB polychlorinated biphenyls

pCi/g picocuries per gram

pCi/L picocuries per liter

PM particulate matter

ppb parts per billion

PSC Public Service Commission

PSD Prevention of Significant Deterioration

psi pounds per square inch

RCRA Resource Conservation and Recovery Act

SEQR State Environmental Quality Review Act

SGEIS Supplemental Generic Environmental Impact Statement

SIP State Implementation Plan

STP standard temperature and pressure

SUA surface use agreements

TCLP Toxicity Characteristic Leachate Procedure

TDS Total dissol ved solids

THPS tetrakis (hydroxymethyl) phosphonium sulfate

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# v TOC Total organic carbon

tpd tons per day

TPH total petroleum hydrocarbons

tpy tons per year

ULSD ultra low sulfur diesel

UV ultraviolet

VOC volatile organic compounds

WV DEP West Virgini a Department of Environmental Protection

yr year

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 1 Introduction

By letter dated April 12, 2010, t he New York State Department of Environmental Conservation

(DEC) , Division of Mineral Resources

, requested additional technical information from the

Independent Oil and Gas Association of New York (IOGA) regard ing high volume hydraulic

fracturing (HVHF) as it is addressed by the draft Supplemental Generic Environmental Impact

Statement (dSGEIS). Additional technical questions were received from DEC in

communications dated April 20, 2010, and May 27, 2010. ALL Consulting facilitat ed this

collaborative effort between IOGA member companies to address DEC’s information requests

. ALL Consulting compiled responses from the participants in the preparation of this report. This

report summarizes DEC’s questions and re sponses by presenting each question as phrased by

DEC followed by the applicable composite response representing IOGA’s industry perspective

. The table of contents of this report refers to each question in the order presented by DEC

.

A complete copy of the Marcellus Shale Coalition study ―Sampling and Analysis of Water

Streams Associated with the Development of Marcellus Shale Gas‖ dated December 31, 2009,

and which is discussed herein, is provided in Attachment A.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 2 IOGA’s Preamble to All Responses

The DEC is currently conducting a very conservative environmental impact review of the

permitting process for drilling individual natural gas wells requiring environmental review under

the State Environmental Quality Review Act (SEQR). This environmental impact review will

supplement the review previously conducted under the 1992 GEIS. 1 

## Once the Supplemental

Generic Environmental Impact Statement (SGEIS) is finalized, the SGEIS will implement

existing statutory and regulatory requirements t o avoid and minimize pollution and mitigate

environmental impacts to the maximum extent practicable. When final, the SGEIS, in

combination with the DEC’s 1992 GEIS, will serve as the environmental impact review under

SEQR for horizontal drilling with high

- volume hydraulic fracture completions and set forth

mitigation measures to meet the statutory and regulatory objectives

.

As part of its ongoing environmental impact review, DEC’s Division of Mineral Resources has

requested technical and projected operat ional information from the natural gas industry. This

document serves as the Independent Oil & Gas Association of New York’s ( IOGA ) response to

these technical questions and data requests . However, many of the information requests 2

, 3

, 4



## cannot be answered with certainty because of the numerous contributing factors , either

individually or in combination with each other, that make it difficult to reliably project

anticipated rates of drilling activity. Furthermore, circumstances that cannot be predicted tod ay

may not necessarily become any more predictable tomorrow

, or even a decade or two f u rther

down the road . There are simply too many factors that can affect future development, not the

least of which are the viability and geographic extent of the untested shale plays in the State of

New York as well as commodity pricing and further technological advances in development

methods . By definition, the SGEIS will apply collectively to the Marcellus Shale, the Utica

Shale, and to any other low permeability natural gas reservoirs that may be identified within the

State’s borders

. 5 

## The unpredictability of these factors for the Marcellus Shale applies equally to

the Utica Shale and other low permeability natural g as reservoirs. Furthermore, as yet

unidentified low permeability reservoirs introduce still another layer of predictive uncertainty to

the issue. Thus, there is a very complex nature to the uncertainty and unpredictability.

Many of DEC’s questions hinge on the rate of development of the Marcellus Shale in New York

and the potential consequent impacts to air, water and land. The following is by no means an

exhaustive list, but it does outline some of the more salient factors that may influence the rate

an d extent of development in New York . Although the following list of variables is identified

for the Marcellus Shale in New York, these variables are equally applicable to other shale and

low permeability plays in New York State.

 The geology and gas produc tion potential of the Marcellus Shale in New York has yet to be

determined:

o The Marcellus production fairway in New York has yet to be defined.

o If production rates are less than anticipated, development will also be limited.

o Optimal economic depth and thic kness of the Marcellus are yet to be determined;

these factors will affect :

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 3  The amount of acreage, and hence drillable locations (such as that proximal to

the Marcellus outcrop belt)

, that will not be practical for development.

 The point at which depth o r play thickness no longer provide s viable drilling

opportunities.

 The location and development of pipelines will affect the areas and locations developed and

the pace of that development.

 The Marcellus will not be developed in a vacuum absent competition from other equally, or

perhaps even more, lucrative natural gas and oil plays throughout the United States. The

pace of development will be affected by :

o The availability of drilling equipment. The Marcellus must compete with other active

plays like the B arnett, Fayetteville, and Haynesville S hales for the available

horizontal

- drilling rig fleet. At the same time that the Marcellus is gaining

momentum, other new shale gas plays like the Collingwood in Michigan and the

Eagle Ford in Texas are also beginnin g to emerge. Not only will there be stiff

competition for drilling rigs, but also for mobile steel storage tanks (―frac tanks‖),

diesel engines, and other equipment. It is unrealistic to anticipate a limitless supply

of equipment for development in New Y ork

.

o The availability of skilled workers and service contractors. It is equally unrealistic to

anticipate that a limitless supply of skilled workers would be devoted exclusively to

the Marcellus in New York.

o The availability of leasable land with good production potential. Not all land will

have good production potential. Not all land will be leasable.

o Similarly, these plays will compete for investment dollars, which are also finite.

Producers will make decisions on where to place their investments based on a number

of factors, including resource potential, infrastructure needs, and the state and local

regulatory climate.

 I f the price of natural gas continues to hover at low levels, or declines further, it will no doubt

slow the rate of development . On the other hand, if commodity prices increase markedly

, there will be greater incentive for the producing companies to accelerate development.

 The pace of development will be affected by the regulatory and political climate:

o The political climate in N ew York includes strong anti

- drilling voices. If non

governmental organizations (NGOs) choose to litigate the final SGEIS, in doing so

they may seek to force DEC to limit drilling or request an injunction on drilling in

New York.

o It is anticipated that th e SGEIS will establish some of the most stringent regulatory

standards in the country, which may deter some operators from drilling in New York.

o The New York Legislature has taken an extreme interest in shale development.

Currently, a number of bills are pending which seek to impose either a moratorium on

drilling or greater regulatory control over drilling and hydraulic fracturing operations

and one such proposal has passed the New York State Senate

.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 4 o These factors will make it difficult for some operators to obtain the investors

necessary for development of shale reservoirs in New York

. Investment capital is

necessary because an individual hori zontal shale gas well can cost as much as 5

million dollars to drill and complete.

The SGEIS is focused on the Marcellus Shale and other low

- permeability reservoirs. For the

myriad reasons outlined above, the total collective development rate for these pl ays taken

together is simply unpredictable. Therefore, in asking to predict the extent of a given

environmental impact, DEC has asked a question that cannot be answered with absolute

certainty. Nonetheless, IOGA recognizes that DEC needs to generate fund amental development

parameters to use in finalizing the SGEIS, regardless of the concerns stated above. Therefore,

IOGA has prepared the following responses to the DEC’s requests for information based on the

best available information existing at the time this response was prepared and IOGA’s good

- faith

estimates of anticipated peak development rates. All of the following responses are subject to

the caveats discussed in this Preamble and are

, therefore

, incorporated by reference into each

individual resp onse set forth below.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 5 Activity Estimates

1. Please provide an updated estimate of the number of Marcellus wells in New York

likely to be drilled and completed annually by high

- volume hydraulic fracturing

(HVHF). This information is necessary to evaluate comments regarding the

following topics:

IOGA Response:

It is IOGA’s position that this question cannot be answered with certainty because of the

numerous contributing factors which cannot be reliably foreseen. The se are outlined in

greater detail in the Preamble, but are briefly reiterated here :

 The geology and gas production potential of the Marcellus Shale in New York has

yet to be determined.

 The location and development of pipelines will affect the areas and pace of

development. A related factor will be the review and approval process for

pipelines by the Public Service Commission.

 Marcellus Shale development in New York will occur simultaneous ly with

development in Pennsylvania, which has been moving forward in earnest since

2008. Development in New York will, therefore, compete against Pennsylvania’s

already existing development which is subject to differing regulatory, legislative

and taxing climates.

 The Marcellus Shale will not be developed in a vacuum and will be subject to

competition from othe r equally, or perhaps even more, lucrative natural gas and

oil plays throughout the United States. The pace of development will be affected

by:

o The availability of drilling equipment.

o The availability of skilled workers and service contractors.

o The availability of leasable land with good production potential.

o The availability of investment dollars , particularly in light of competition

with other active and emerging natural gas plays.

o The regulatory and political climate of New York State.

Despi te the foregoing , IOGA has prepared the following good

- faith estimate of peak

drilling ( i.e.

, worst case for impacts ) for the Marcellus Shale and other low permeability

reservoir plays in New York. The following response is subject to all of the caveats

m entioned in the Preamble to this document.

It is important to emphasize that the following estimate is for the peak year of

development; i.e

., that year in which the greatest number of wells are drilled in a single

year over the entire life of the play. I t cannot be overemphasized that this is not an

estimate of how development will ramp up or the average development rate expected for

the play. In fact, once the SGEIS is complete and the DEC is issuing permits, it will

require a number of years for the dr illing rate to ramp up to the peak year rate. Likewise,

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 6 after the peak year occurs, the drilling rate is expected to ramp down over several years

until full

- field development is reached. Drilling in New York will begin slowly as initial

permits to drill are approved by DEC and operators mobilize drilling equipment to the

area. The rate of drilling is expected to gradually increase over time as the geologic

characteristics of the Marcellus Shale in New York become better understood, thus

defining its geog raphic coverage and allowing for a well economics

- based definition of

the play. Once the play is more thoroughly defined, and assuming that no external

factors limit permitting ( e.g.

, a moratorium on drilling or fracturing , price of natural gas),

then drilling rates would be expected to ramp up to the peak year.

Additionally important is the fact that drilling rates and any associated environmental

disturbances are of a rolling nature. That is, not all wells will be acti vely drilled at any

one point in time. Instead, once the play development begins to gain traction

, some wells

will be drilled as others are being fractured and completed while still others will be

producing to pipelines. As the drilling rate ramps up to the peak year the number of wells

drill ed on an annualized basis (12

- month rolling average) will increase until that peak

rate i s achieved; thereafter, the drilling rate will decline until full

- field development is

reached and all wells are producing onlin e with no continuing drilling or hydraulic

fracturing activity. Likewise, the associated environmental disturbances from the drilling

and completion phases of development will not co

- occur at all prospective well locations

at the same time, but will occur over a broad geographic area throughout the peak year

. Many of the responses provided herein are keyed

- in to that peak year of development

– the year of maximum drilling rate. Therefore in evaluating the extent of environmental

disturbance, it is very i mportant to understand that maximum disturbance will not occur

every year that development takes place; disturbance will march in lock

- step with the

development rate rising to the peak and then falling until full

- field development has all

wells online and producing.

In order to estimate the peak drilling development rate for the Marcellus Shale play in

New York, the following methodology was used:

 The acreage for the Marcellus in New York was determined based on:

o There are approximately 18,724 square miles ( mi 2 

## ) of Marcellus subcrop

in upstate New York (based on the U.S. Energy Information

Administration’s [ EIA ] play boundary map 6 

## ).

o The area of the New York City surface water supply drainage basin of

1,612 mi 2 

## underlain by Marcellus Shale was removed from the total as this

acreage will not be included in the final SGEIS.

o The area of the Syracuse, NY surface water supply drainage basin of 34

mi 2 

## underlain by Marcellus Shale was removed from the total as this

acr eage will not be included in the final SGEIS.

o This leaves a total of 17,078 mi 2 

## or 10,929,920 acres (640 acres per square

mile) of geographic area potentially available for development

.

 The following assumptions for Marcellus development were applied:

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 7 o Appr oximately 90% of wells will be horizontal wells with an average of

160 acres developed per well (developing approximately 97.25% of the

total acreage).

o Approximately 10% wells will be vertical wells with an average of 40

acres developed per well (developin g approximately 2.75% of the total

acreage).

 For comparison, note that the Fayetteville Shale play in Arkansas

has an overall total of approximately 88% horizontal and 12%

vertical wells. 7



##  For the Fayetteville, this equates approximately to 96.7% of the

acreage being developed by horizontal wells and 3.3% of the

acreage being developed by vertical wells.

o On a conservatively high basis, it is assumed that of the total Marcellus

acreage addressed by the SGEIS, approximately two thirds (67%) will be

developa ble. The remainder would be in areas where the shale is either:

 Too thin to allow practical development,

 Too shallow to allow practical development, or

 Located in lands that cannot be leased or pooled for development.

 As noted above, the New York City and Syracuse water supply

watersheds were removed prior to prorating the 67% factor to

define developable acreage.

o This estimate assumes that t he Marcellus play will require approximately

30 years to reach full

- field development; depending on their areal extent,

other low permeability plays in New York may involve a similar

timeframe

. Note that the number of years to accomplish full

- field

development cannot be determined with precision at this early stage of the

process. The methodology used herein to e stimate annual average and

peak drilling rates cannot be used to predict full

- field development. Full

field development is a function of development restrictions by the

regulatory agencies, timing of permit issuance, lease agreements and

expiration dates, surface use agreements, pipeline right of way acquisition,

availability of drilling and completion equipment, drilling and production

characteristics of the wells, future technology improvements, and the

future demand for and price of natural gas. As min eral leases expire and

new leases are acquired and drilling schedules are adjusted the term for

full

- field development will also change

.

 Based on the foregoing parameters , the average annual drilling rate is predicted to

be approximately 1,484 horizontal wells per year and 168 vertical wells per year.

 Because this annualized drilling rate is likely to be less during ramp

- up and ramp

down periods and exceeded during the years of peak drilling activity

, the

calculated average drilling rate is multiplied by a factor of up to 1.5 to

approximate the peak (i.e., worst

- case) drilling rate

.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 8  Therefore, peak drilling activity ( drilling during the year(s) of maximum drilling

rate) is estimated at :

o Horizontal wells: 2,216.

o Vertical wells: 246.

 An alternative drilling rate estimate can be developed based on rig availability.

o Rig count considerations:

 According to EIA (referencing Baker Hughes, Inc.), as of August

13, 2010, there were 885 rigs drilling horizontal wells (oil and gas

combined) in the U.S., the highest recorded level for onshore

horizontal rig activity. 8



##  Horizontal rigs are used in a variety of unconventional plays such

as the Bakken Shale (oil) and other shale gas plays (Barnett,

Fayetteville, and Haynesville, etc.). Five unconventional oil and

gas pla ys (Bakken, Barnett, Fayetteville, Haynesville, and

Marcellus) currently dominate the domestic, onshore directional

drilling activity. The drilling rate estimate provided herein

assumes that each of those plays will receive an equal 20% share

of the avail able rig fleet. This approach is overly conservative as

will be demonstrated below; however, it is used as a base

assumption for this estimate.

 Twenty percent of the available rig fleet would dedicate

approximately 171 rigs for Marcellus well drilling in New York

and Pennsylvania combined.

o Drilling time considerations:

 Total time to drill a Marcellus well is estimated at approximately

21 to 25 days

. As is common with all emerging oil and gas plays,

this worst

- case drilling time is anticipated to decrease in the future

as local play

- specific drilling experience is gained. Frequently, the

vertical segment of a horizontal well is drilled with a smaller air

rotary drilling rig through any potable groundwater

- bearing strata

to set the surface casing ; beyond t hat depth the remaining vertical

hole may be drilled down to the kick

- point by either continuing

with the air rig or using the larger mud rotary rig that will also drill

the horizontal portion of the borehole . Drilling with air uses no

drilling mud and so helps to minimize the potential for impacts to

shallow groundwater. After the air rig is removed, the larger rig

used to drill any remaining vertical portion of the borehole and the

horizontal leg is mobilized to the site.

 The horizontal portion of a typical Marcellus well requires

approximately 14 days to drill.

o Breakdown of horizontal to vertical wells will be 90:10 as used in the first

estimate presented above.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 9 o Based on the se assumptions, the resulting drilling rate is e stimated to be

approximately 1,570 horizontal wells per year and 174 vertical wells per

year.

o This drilling rate will be less during ramp

- up and ramp

- down periods.

o The assumption of 20% of available horizontal rigs being dedicated to the

Marcellus in New York and Pennsylvania is considered overly

conservative (i.e. high) for the following reasons:

 The allocation of the available horizontal

- capable drill rig fleet will

be based on the economics of each play, not an arbitrary allocation

of one

- fifth of the available fleet among the five prominent plays.

Those plays with higher return on invested drilling dollars are

expected to see the most drilling.

 Competition for the available rig fleet knows no political

boundaries. Unconventional oil and gas plays acr oss North

America will in fact compete for available rigs. Therefore, plays

such as the Horn River Basin shales in British Columbia will also

likely affect the availability of directional rigs throughout the U.S.

 Additional unconventional plays are eme rging such as the Eagle

Ford in south Texas, the Collingwood in Michigan, and the Utica

Shale in the St. Lawrence lowlands as well as others. This

competition for available rigs will further dilute the number of rigs

available for the Marcellus play.

- This estimate assumes it is likely that at least twice as much

drilling will take place annually in Pennsylvania as in New

York because of the approximately doubled aerial extent of

the Marcellus play in Pennsylvania and the fact that

development in Pennsylvan ia has a three year head start on

New York. Note that the Marcellus is also being explored

in Maryland, Ohio, Virginia, and West Virginia; thus,

activity in these states would further dilute the number of

rigs available for New York.

- Although new drill ri gs will be manufactured and older rigs

may be retro

- fitted for horizontal drilling capability, at the

same time other rigs will also be taken out of service as

they age.

o Therefore, it is unreasonable to anticipate that any greater commitment of

the avail able rig fleet would be dedicated to these two states in a single

unconventional gas play. It is more likely that the rig count will be much

smaller with the majority of the rigs dedicated to the larger area of

Pennsylvania. For these reasons, the estima ted drilling rate presented here

is believed to be a highly optimistic overestimate.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 10  Therefore, using the above two drilling rate estimates, IOGA submits the

following estimate of drilling during the year(s) of peak drilling activity:

o Horizontal wells: 1, 570 to 2,2 1 6.

o Vertical wells: 1 74 to 2 46

.

o Note that for the myriad reasons noted above and in the Preamble, as well

as the evolving nature of drilling and completion technologies and the

likelihood that some areas will not be drilled (because of geologic constraints,

surface use/obstructions, or the inability to lease the minerals), it is

impractical and potentially very misleading to attempt to estimate the number

of wells at full

- field development. Therefore, such a number is not provided.

a. Potential eff

ects of regional emissions of ozone precursors on ozone

nonattainment area state implementation plans (see question 9 under “Air

Impacts” for more detail ).

IOGA Response:

Estimated Ozone Impacts: To estimate the potential impacts from the development of

M arcellus Shale upon New York’s regional ozone status, a comparison of annual oxides

of nitrogen ( NO

x 

## ) and volatile organic compounds ( VOC ) emissions from development

activities to an existing baseline of these emissions is used. 9 

## Thus, for the year of

estimated peak development (2,2 1 6 horizontal and 2 46 vertical wells), the following

estimation methodology is provided for average annual NO

x 

## emissions per horizonta l

well and then calculated for all wells during peak annual operatio ns:

 Drilling Emissions = 12.6 lb/hr 10 

## x 24 hr/day x 25 days = 7,560 lb (single well) x

2,2 1 6 wells/yr x tons/2,000 lb = 8, 376 tons per year (tpy).

 Completion Emissions (frac) = 60 lb/hr 11



## x 6 hrs /frac x 8 fracs/well = 28 80

lb/well x 2,2 1 6 wells/yr x tons/2,000 lb = 3, 191 tpy.

 Completion Emissions (flare) = 34 lb/hr 12 

## x 72 hrs /well = 2,448 lb/well x 2,2 1 6

wells/yr x tons/2,000 lb = 2,7 12 tpy. Therefore, the total completion emissions

are 5,9 03 tpy.

 Production Emissions = 0.86 lb/hr 13 

## x 8,760 hr/yr = 7,533 lb/yr x 2,2 1 6 wells/yr x

tons/2,000 lb = 8,3 47 tpy.

 Therefore, the total annual NO

x 

## emissions estimate for all horizontal wells drilled

during a peak year = 22, 626 tpy.

In a similar manner, the NO

x 

## emissions for vertical wells:

 Dr illing Emissions = 12.6 lb/hr x 24 hr/day x 11 days = 3,326 lb (single well) x

2 46 wells/yr x tons/2,000 lb = 4 0 9 tpy.

 Completion Emissions (frac) = 60 lb/hr x 6 hrs /frac x 1 frac/well = 36 0 lb/well x

2 46 wells /yr x tons/2,000 lb = 44 tpy.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 11  Completion Emissions (flare) = 34 lb/hr x 72 hrs /well = 2,448 lb/well x 2 46 wells

/yr x tons/2,000 lb = 30 1 tpy. Therefore, the total completion emissions are 3 45

tpy.

 Production Emissions = 0.86 lb/hr x 8,760 hr/yr = 7,53 4 lb/yr x 2 46 wells/yr x

tons/2,000 lb = 9 27 tpy.

 Therefore, the total annual NO

x 

## emissions estimate for all vertical wells drilled

during a peak year = 1,6 8 1 tpy.

Likewise, the average annual VOC emissions for horizontal wells:

 Drilling Emissions = 0.53 lb/hr 14 

## x 24 hr/day x 25 days = 318 lb (single well) x

2,2 1 6 wells/yr x tons/2,000 lb = 35 2 tpy.

 Completion Emissions (frac) = 2.5 lb/hr 15



## x 6 hrs /frac x 8 fracs/well = 120 lb/well

x 2,2 1 6 wells /yr x tons/2,000 lb = 13 3 tpy.

 Completion Emissions (flare & vent ) = 4.9 lb/hr 16 

## x 72 hrs /well + 97 lb/hr x 3

hr s/well = 644 lb/well x 2,2 1 6 wells /yr x tons/2,000 lb = 71 3 tpy. Therefore, the

total completion emissions are 8 4 6 tpy.

 Production Emissions = 0.554 lb/hr 17 

## x 8,760 hr/yr = 4,853 lb/yr x 2,2 1 6 wells /yr

x tons/2,000 lb = 5, 377 tpy.

 Therefore, the total annual VOC emissions estimate for all horizontal wells drilled

during a peak year = 6, 57 5 tpy.

In a similar manner, the VOC emissions for vertical wells:

 Drilling Emissions = 0.53 lb/hr x 24 hr/day x 11 da ys = 140 lb (single well) x 2 46

wells/yr x tons/2,000 lb = 1 7 tpy.

 Completion Emissions (frac) = 2.5 lb/hr x 6 hrs /frac x 1 frac/well = 15 lb/well x

2 46 wells /yr x tons/2,000 lb = 2 tpy.

 Completion Emissions (flare & vent ) = 4.9 lb/hr x 72 hrs /well + 97 lb/hr x 3

hrs/well = 644 lb/well x 2 46 wells/yr x tons/2,000 lb = 79 tpy. Therefore, the

total completion emissions are 8 1 tpy.

 Production Emissions = 0.554 lb/hr x 8,760 hr/yr = 4,853 lb/yr x 2 46 wells/yr x

tons/2,000 lb = 597 tpy.

 Therefore, the t otal annual VOC emissions estimate for all vertical wells drilled

during a peak year = 69 5 tpy.

The combined results are provided in E xhibit 1

.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 12 Exhibit 1

Ozone Precursor Emission Estimates (tpy) for the Year of Peak Development

Drilling Completion Production Totals

Horizontal

- NO

x 

### 8, 376 5,9 0 3 8,3 47 22, 626

Vertical

- NO

x 

### 4 0 9 3 45 9 27 1,6 8 1

Total NO

x 

### 8, 785 6,2 48 9, 274 24, 30 7

Horizontal

- VOC 35 2 8 4 6 5, 377 6, 57 5

Vertical

- VOC 1 7 8 1 597 695

Total VOC 3 69 9 2 7 5,9 74 7, 27 0



## According to the 2002 baseline emission inventory (EI) year used in New York’s 2007

State Implementation Plan (SIP) demonstration for the 8

- hr ozone standard, a total of

659,186 tpy of NO

x 

## emissions were estimated statewide. 18 

## Therefore, the impact from

the development of the M arcellus at worst

- case peak development rate would add 3. 7 %

to existing NO

x 

## emissions.

From the same baseline data, a total of 1,352,076 tpy of VOC emissions were estimated

statewide. Therefore, the total impact of 7, 27 0 tpy from the development of the

Ma rcellus would add 0.5 4 % (one half of one percent) to existing VOC emissions

.

Assumptions/considerations used in these calculations include:

 Average emission rates for dry gas are used for every well for every phase of

development.

 Maximum number of wells (both horizontal and vertical) in any year.

 No credit is taken for any mitigation measures, permit emissions controls, or state

and federal regulatory requirements that are expected to reduce these estimates.

 Drilling emissions are conservatively estimated at 25 days for the horizontal wells

(11 days for vertical well drilling).

 Heater emissions are included year

- round in the production estimates; however,

they would be seasonal and would take place during the non

- ozone season.

 Off

- pad compressor emissions are included in the production estimates; however,

it is anticipated that most well pads will not include a compressor.

 No credit is taken for the rolling nature of development (i.e., that all wells will not

be drilled or completed at the same time, on the same pad) and the resulting

impact on air emissions.

 No credit is taken for improved nonroad engine performance and resultant

reduced NOx emissions from the higher tier engines that will be phased in over

time

.

 No credit is taken for reduced emission completions (green completions) which

would significantly reduce flaring and hence related NO

x 

## and VOC emissions.

Because the Public Service Commission ( P S C ) currently requires an Article VII

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 13 application for pipelin e construction be submitted after well completion , and

because green completions require a pipeline to be available to receive gas during

the flowback process, it is not currently possible to complete wells using the

reduced emissions approach in New York

. I OGA understands that the 2009 State

Energy Plan 19 

## includes a recommendation to coordinate drilling and pipeline

requirements so that green completions may be possible . Therefore, early in the

play’s development

, green completions are not expected to be the standard;

however, as the play evolves

, it is expected that green completions can become

more commonplace. At the very least, once the initial wells on a pad are

completed and connected to the gathering line it is anticipated that subsequent

wells cou ld be completed using a reduced emissions approach.

Importantly, the magnitude of a ir emissions is largely dependent on the development rate

and the locations where development will occur. The tons per year of air emissions can

be estimated relative to t he development rate. However, DEC must recognize that the

development rate estimate was prepared based on worst

- case peak drilling and, therefore,

does not represent average annual conditions, or conditions that are likely to occur during

the development ramp

- up or ramp

- down.

Furthermore, air emissions are subject to specific permitting and monitoring

requirements. Any exceedance of the permitted limits would represent potential

violations subject to DEC enforcement. Because it is the intention of oper ator members

of IOGA to conduct their business in full compliance with applicable laws and

regulations, and industry’s compliance history in New York demonstrates this, the

frequency of occurrence of such violations, which cannot be realistically predicted , is

exp ected to be minimal.

Additional detail is provided in the response to i tem ― Air Impacts 9 ‖

.

b. Potential stream degradation impacts from stormwater runoff from land

disturbance and impervious surfaces (including gravel roads and wellpads).

IOGA Response:

Properly designed, permitted, and constructed well sites do not result in surface run

- off

that can migrate to and impact streams and other surface waters. Proper mitigation

measures, such as hay bales or silt fence s

, prevent the offsite transport of sediment laden

storm water, and thereby preclud e stream degradation.

Similar to the above discussion relative to air emissions, land disturbance and the

potential for stream degradation are largely dependent on the devel opment rate and the

locations where development will occur. The number of acres disturbed can be estimated

in a manner similar to the development rate. However, DEC must recognize that the

development rate estimate was prepared based on worst

- case peak d rilling and, therefore,

does not represent average annual conditions, or conditions that are likely to occur during

the development ramp

- up or ramp

- down.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 14 Furthermore, the potential for stream degradation is even less predictable than is the

drilling rate and land disturbance. Stream degradation can occur from two potential

sources: 1) erosion of soil from well pads and roads with transport to streams and

subsequent deposition of sediment in streams, or 2) damage caused at stream crossings.

Both erosion and sedimentation control and stream crossings are addressed in the well

permitting process and through field inspections. Therefore, such occurrences would be

potential violations subject to DEC enforcement. Because it is the intention of operator

memb ers of IOGA to conduct their business in full compliance with applicable laws and

regulations, and industry’s compliance history in New York demonstrates this, the

frequency of occurrence of such violations, which cannot be realistically predicted, is

expe cted to be minimal. To assume a percentage rate of such violation is unrealistic.

Despite this, IOGA provides the following response , which is subject to all of the caveats

mentioned in the Preamble to this document.

Based on information that IOGA previo usly presented to DEC 20 

## and communications

with numerous operators, anywhere from one to four wells will initially be drilled on a

multi

- well pad in a given year ; it is not anticipated that an entire multi

- well pad, which

may include upwards of 10 horizonta l wells ( see Exhibit 18), will be drilled in any 12

month period . Assuming that on average two horizontal wells are drilled on each well

pad within the first year of the pad’s initial development, the rate of new multi

- well pad

construction is estimated t o be approximately 1,1 08 during the year(s) of peak drilling

activity . In addition, as many as 2 46 vertical (single) well pads could be constructed

during the year(s) of peak drilling activity.

Land disturbance in the form of constructed gravel roads, uti lity corridors, and well pads

can be estimated as follows:

 Horizontal wells:

o During the development phase, a multi

- well pad for horizontal well

development disturbs approximately 7.4 acres including the incremental

portion of associated roads and utility c orridors. The multi

- well pad alone

would disturb approximately 3.5 to 4.0 acres. 21

, 22



## o Based on 1,1 08 horizontal well pads constructed in the year of peak

development, 8, 197 acres of total land disturbance for horizontal drilling

would be anticipated during that entire year.

 Vertical wells:

o A single

- well pad for a vertical well disturbs approximately 4.8 acres

including the incremental portion of associated roads and utility corridors.

The single well pad alone would disturb approximately 2.0 aces. 23



## Therefore, the initial land disturbance for vertical wells is estimated at 4.8

acres per well.

o Based on 2 46 vertical well pads constructed in the year of peak

development, a tota l of 1, 182 acres of total land disturbance for vertical

drilling would be anticipated during that entire year.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 15  Therefore, the total combined temporary horizontal and vertical well land

disturbance is estimated at 9,379 acres during the year of worst

- case p eak

development. Note that this estimate does not take into account the rolling nature

of development, which means that only the active well pads will exhibit the

maximum surface disturbance area. Interim reclamation will reduce the long

term surface dis turbance acreage that would exist during production. A nd, a fter

production has ceased, final reclamation will return the well site to pre

- drilling

conditions.

 Following full development of each pad and interim reclamation once the wells

are producing to t he gas pipelines, a lesser amount of acreage would remain

disturbed throughout the well’s productive lifetime until the well(s) is abandoned

and full site reclamation is completed. During the period of active production,

disturbance is estimated at:

o 1.5 a cres for a multi

- well horizontal well pad plus incremental portion of

associated roads. 24



## o Approximately 0.5 acre (based on partial reclamation of a 150 ft x 200 ft

pad) for a single

- well vertical well pad plus incremental portion of

associated roads. 25



## c. Exi sting solid waste landfill capacity relative to disposal of cuttings and salt cake

or sludge from treatment facilities.

IOGA Response:

The rate of generation of solid waste is largely dependent on the development rate.

However, DEC must recognize that the development rate estimate was focused on peak

drilling and, therefore, does not represent average annual conditions or conditions that are

likely to occur during the development ramp

- up or ramp

- down.

The industry is constantly working to decrease the production of wastes requiring

disposal and also to increase its reuse/recycling of residual materials. Because full

- field

development will occur over decades, it is realistic to anticipate that further strides will

be m ade in waste minimization. Furthermore, the population of upstate New York will

always require landfills for management of its wastes. Therefore, it is realistic to

anticipate that as existing landfills reach capacity, either those landfills will expand their

permitted capacity or new landfills will be developed to meet society’s needs, if for

nothing other than general household refuse. To estimate existing landfill capacity

relative to disposal of drilling wastes would be highly speculative and yield a n answer

with, at best, a very short lifetime of accuracy. Therefore, this request from DEC is

unknowable with any degree of long

- term certainty. Despite this, and subject to all of the

caveats mentioned in the Preamble to this document, IOGA has compile d a list of

landfills in the upstate area and their current capacity statistics. Only a limited number of

those landfills are currently used buy the natural gas industry for waste disposal.

The DEC was contacted to determine the name, location and remai ning capacity of

Municipal Solid Waste (MSW) Landfills and Construction and Demolition Debris (C&D)

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 16 landfills currently operating within and/or proximal to the Marcellus and Utica Shale play

areas. In addition, each individual landfill facility provided b y the DEC was contacted to

determine its current status ( e.g., active or closed), as well as its remaining capacity.

MSW landfills are capable of receiving drilling waste, such as drilling muds, and general

construction refuse generated from oil and gas a ctivities

, whereas, C&D landfills are only

capable of receiving general construction refuse generated from oil and gas activities.

Exhibit 2 below provides a list of MSW landfills, their location and remaining capacity;

Exhibit 3 provides the same informa tion for C&D landfills. For reporting purposes,

remaining capacity for a given landfill refers to a facility that has undergone

environmental review and permitting and may require construction of additional cells to

reach the indentified capacity level.

Information collected from operators to confirm the landfills that are currently being

utilized for oil

- and gas

- related activities was also collected and cross

- referenced with the

information provided in E xhibit s 2 and 3

.

Solid waste generated from drilling and production activities that could be sent to a

landfill include drilling cuttings, solids from recycling and filtering produced water, and

filter media from the recycling. Wastes are disposed of by various methods based on the

quality of the w aste, regulatory requirements, distance to the site, and cost. Disposal

methods and sites used will vary from year to year based on these factors. Landfills

typically use the material as daily cover or stockpile the material for future use.

Exhibit 2

Municipal Solid Waste in New York that can Accept Drilling Waste

Municipal Solid Waste (MSW)

Landfills City/County Remaining Capacity for MSW

Landfills (tons)(2009) a



### Modern Lewiston/ Niagara 22,140,000 b



### Allied Waste Niagara Niagara Falls/ Niagara 8,000,000

Chaffee Sardinia/Erie 6,080,000

Chautauqua Ellery/ Chautauqua 2,560,000

Alleghany County Angelica/ All e ghany 190,162

Hyland Angelica/ Alleghany 6,546,963

Mill Seat Bergen/Genesee 5,600,000

High Acres Western Expansion Fairport/Monroe 44,400,000

SMI Waterloo/Seneca 29,177,215

Ontario County Sanitary Stanley/Ontario 7,188,841

Bath Sanitary Bath/Steuben 2,133,100

Chemung County Sanitary Chemung/ Chemung 1,056,005

Broome County Binghamton/ Broome 13,140,600

Cortland County Westside Extension McGraw/ Cortland 808,131

Auburn #2 Auburn/Cayuga 876,106

Bristol Hill Fulton/Oswego 3,190,636

DANC Rodman/ Jefferson 3,026,746

Ava Ava/Oneida 21,116,282

Madison County Westside Extension Canastota/ Madison 8,263,747

Chenango County Norwich/ Chenango 1,643,984

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 17 Exhibit 2

Municipal Solid Waste in New York that can Accept Drilling Waste

Sullivan Monticello/ Sullivan Closed

Delaware County Walton/Delaware 554,188

Albany Rapp Road Albany/Albany 2,240,000

Colonie Sanitary Cohoes/Saratoga 4,864,389

Fulton County Johnstown/ Fulton 8,760,708

Steuben Sanitary Steuben County 2,422,279 b

a 

### Capacity does not include any permit restrictions that may be in place for cover material.

b 

### Based on 2008 data as reported to the DEC by the facility.



## Exhibit 3

Construction and Demolition Debris Landfills in New York

Construction and Demolition

Debris (C & D) Landfills City/County Remaining Capacity for C & D

Landfills (tons)(2009) a



### Bethlehem Rupert Road Selkirk /Albany Closed

Burton Clark Delhi/Delaware 640,000

Chemung County Area 3 Chemung/Chemung 246,432

Delaware County Walton/Delaware 15,926

Santoro Schenectady/ Schenectady Closed

Lake George Debris Lake George/ Warren Closed

Thurman Debris Thurman /Warren Closed

Honeywell/Camillus Bed #15 Syracuse/ Onondaga 326,448

Hakes Disposal, Inc. Painted Post/ Steuben 3,242,212

L.C. Whitford Co. C&D Scio /Allegany 37,520

Southern Tier Kleen Fill Wellsville /Allegany 0

Niagara Co. Refuse Disposal District Lockport /Niagara 34,384

a 

### Capacity does not include any permit restrictions that may be in place for cover material.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 18 Air Impacts

1. Comments state that the assumption in the air quality modeling of short term

simultaneous operations (over any 24 hour period) of one well drilling and one well

undergoing completion at a single pad would not occur. This assumption in the

draft SGEIS was made based on previous industry responses. It should be

understood that the draft SGEIS has considered all possible worst case operations

and any limitations on operations will become permit conditions, with case specific

analysis required for any deviations. Thus, unless industry unanimously confirms

that this simultaneous operation scenario will not occur under any circumstance in

Marcellus shale drilling in NY, this assumption will be retained.

IOGA Response:

The followi ng response is subject to all of the caveats mentioned in the Preamble to this

document.

It is the unanimous opinion of IOGA members that drilling and HVHF activities will

never co

- occur on the same well pad at the same time under any circumstances. For b oth

logistical and safety considerations , operators will not conduct both activities at the same

time on a multiple well pad. Therefore, the assumption of such co

- occurrence as a worst

case scenario by DEC is an impractical and excessive representation of potential air

emissions from a single well pad . If DEC chooses to stipulate in the final SGEIS that

drilling and HVHF cannot co

- occur on a single well pad

, w ithout project

- specific

environmental review and approval under SEQR , this is not expected to adv ersely impact

development and IOGA would not object

.

2. Comments state that the size of centralized impoundments could be larger than 5

acres and should not be thus limited, but instead a range specified. The 5 acres is

approximately the size of the 500ft by 500ft impoundment previously identified by

industry as the likely worst case size and has been incorporated in the air quality

modeling of additive emissions. It should be understood that the draft SGEIS has

attempted to consider the impact of possible wor st case conditions and operations

and any deviations will need case specific analysis. Thus, industry should provide an

upper bound to the size of centralized as well as potential onsite impoundments for

flowback water and the associated flowback water qua ntities these are meant to

hold. In addition, the maximum number of pads which could be serviced by a

centralized impoundment should be identified, including those outside the 4

- mile

radius area assumed for one such impoundment.

IOGA Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

It is the opinion of IOGA members that the flowback of HVHF

- produced water to

impoundments or open pits will not occur on a routine basis as part of the develop ment of

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 19 the Marcellus Shale in New York; produced water returned during the flowback process

will be stored in tanks . Therefore, the use of produced water impoundments should be

removed from the SGEIS as a standard practice in New York. With this is mind , the

request for size and service area for centralized produced water impoundments are also

no longer relevant considerations.

Industry recognizes that any future use of an impoundment (well pad dedicated or

centralized) to manage produced water would l ikely require project

- specific

environmental review and approval, potentially up to and including preparation of an

independent, project

- specific EIS. Suc h a scenario is not expected to adversely impact

development of the Marcellus Shale and IOGA would no t object

.

To clarify the usage of the term ―flowback‖ in its responses, IOGA offers the following:

flowback is a process in the completion of a gas well. Water, including spent HVHF

chemicals

, is produced to the surface during the flowback process. Wate r also continues

to be produced to the surface after the gas well is connected to a gas gathering line and

goes on production. However, a well may not produce water throughout its entire life.

All of this water is referred to as produced water and is col lectively defined as such

herein. IOGA will refer to flowback as the process and produced water as the fluid.

3. Comments state that a maximum of 20% of the water used for hydraulic fracturing

will return during the flowback process and that many of the addi tive constituents

(e.g., methanol) will not fully return in inflow water concentrations. It should be

understood that the draft SGEIS has to consider possible worst case conditions,

unless actual data is provided to the contrary. Thus, industry should prov ide all

information from previous studies undertaken by industry, contractors or

consultants which identifies the percent of flowback water as a fraction of inflow

water. The information should be provided for various timesteps after hydraulic

fracturing o perations, especially over the long term (i.e., months). In addition, any

actual data which compares the concentration of a chemical additive constituent or

a surrogate in the flowback to the concentration in inflow water should be provided.

IOGA Response:

The composition of produced waters will change as the chemicals used in HVHF change

throughout the evolution of the Marcellus play development. HVHF service companies

are working to minimize the volumes and toxicological properties of chemical additives

necessary to provide the necessary fluid characteristics. Therefore, an assessment of

current produced water characteristics is likely to be overly conservative in relation to the

possible produced water of future years.

Currently, the most comprehensive database available for analytical results from

produced water samples is that compiled by the Marcellus Shale Coalition (MSC). 26



## Unfortunately, this database has several shortcomings such as the inclusion of analytical

methods inappropriate for the charact erization of produced water (e.g.

, polychlorinated

biphenyls [ PCBs ] , organo

- chlorine pesticides, etc.

– compounds that are no longer in

manufacture or have highly limited legal uses). The detection of some of these

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 20 compounds may raise misdirected concerns simply because they were detected without

due consideration of the fact that these chemicals are not used by the HVHF industry.

The database also has a great many detections that are invalidated because of the

occurrence of the same target analyte in laboratory method blank samples. This indicates

contamination of the samples at the laboratory and is not representative of the

investigatory samples.

Despite the foregoing caveats, including those set forth in the Preamble, Attachment B

summarizes HVHF fluids data from eight Marcellus Shale wells drilled in northern PA.

Data was collected at various times in the HVHF process including:

 Source water prior to blending of HVHF chemicals. Note that only wells added

to the study once it was already in progress were sampled for source water. The

initial sampling plan was based on 6 well locations. The revised plan which

included source water sampling in cluded 19 wells

, not all of which were deemed

to be located in regions of the play to have comparable character to the New York

play area.

 HVHF inflow fluids (these are samples identified as ―Day 0‖) after blending but

prior to the addition of proppant. T hese samples are intended to be representative

of the HVHF fluid that is being pumped downhole and representative of the

chemical input and concentration of chemicals that makeup the hydraulic

fracturing fluids.

 Produced water at various time durations aft er initiation of the flowback process

(―Day 1‖, ―Day 5‖, ―Day 14‖, and ―Day 90‖). Note that not all wells were

sampled at ―day 90

. ‖

This data was originally compiled by the MSC; a complete copy of their study of 19

Marcellus Shale gas wells located in Pe nnsylvania and West Virginia is provided as

Attachment A . The MSC report outlines the methodologies and justification for the

analytical methods used. Note that the Pennsylvania Department of Environmental

Protection ( PA DEP ) and the West Virginia Depart ment of Environmental Protection

( WV DEP ) were instrumental in the development of sampling and analytical protocols

for the MSC study ; however, it is IOGA’s opinion that some of the analyses performed

were inappropriate

.

The eight Marcellus Shale wells that were identified as being located in the northern

counties of P ennsylvania and thus having comparable character to New York play area

are presented:

 Lycoming County

– well ―G‖ (horizontal well)

 Cameron County

– well ―I‖ (well orientation unspecified)

 Tioga County

– well ―J‖ (well orientation unspecified)

 Bradford County

– well ―K‖ (horizontal well)

 McKean County

– well ―M‖ (horizontal well)

 Potter County

– well ―O‖ (horizontal well)

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 21  Susquehanna County

– well ―Q‖ (vertical well)

 Centre County

– well ―S‖ (vertical well)

.

Locations for these wells are indicated on Figure 1 of the MSC study (see Attachment A ).

It is anticipated that the data from these Marcellus Shale wells in the north central

counties of Pennsylvania will p rovide data most similar to what may be encountered in

the Marcellus Shale of New York State and, therefore, be of greatest interest to DEC.

The remaining discussion , therefore, applies to the data collected from those eight wells

only and does not includ e discussion of the analyses or results from the other 11 wells in

the study.

The following data summarizes general information about the eight Marcellus Shale gas

wells drilled in northern Pennsylvania (see Exhibit 4 ; also see Table 3 of the MSC study;

At tachment A ):

 Produced water recovery volumes for the HVHF fluid from the horizontal wells

ranged from 13.4% to 19.9% through the first 14 days of the flowback process

.

 One horizontal well was sampled at 90 days after initiation of the flowback

process had recovered 15.1% of the HVHF fluid volume at that time.

 Vertical wells may indicate higher produced recovery during the flowback

process ; however, only two data points are available. The produced water volume

for the vertical wells was 21.6% at 14 days for one well and 65.1% at 90 days for

the other well. It is not possible to conclusively state that recovery from vertical

wells is greater than that of horizontal wells; however, the data from wells in this

study indicate this may be the case.

 In general , average daily produced water rates decline over time.

Exhibit 4

Produced Water Data

Well Well Type Total Vol.

Frac Fluid

Used (in

BBLs) % Recovered

(at maximum

days

recorded) Average Daily Produced Water in BBLs

Day 1 Days 2

- 5 Days 6

- 14 Days 15

- 90

G Horizontal 123,921 15.1% 1,219.00 1,568.50 553.11 81.66

I Data on produced water volume is not available from the MSC database for this well

J Data on produced water volume is not available from the MSC database for this well

K Horizontal 70,774 13.4% 5,751.0 566.3 161.9

M Horizontal 99,195 19.9% 16,419.0 379.0 198.7

O Horizontal 96,706 19.9% 5,131.0 3,517.8

Q Vertical 23,593 21.6% 1,315.0 565.5 168.1

S Vertical 16,460 65.1% 2,094.0 1,434.5 168.1 18.1



## The analytical data tables for the eight Marcellus Shale gas wells drilled in northern

Pennsylvania (A ttachment B ) are discussed below:

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 22 Organic Compounds

- General

 Many of the detected constituents occurred at concentrations such that the data

required on e of the following qualifier flags:

o ―J‖

– an estimated concentration from a diluted sample where the results

are outside of the calibration range for the instrumentation/analytical

method. 27



## o ―PG‖

– an estimated concentration based on a diluted sample where

results from dual column analysis differ by more than 40%. 28



##  The constituent concentration data for many of the wells indicates that isolated

detections of many of the compounds occurred, such that compounds were only

detected in one or two produced water samples (note that ―Day 0‖ is inflow and

not a samp l e from the flowback process ) making identification of meaningful

trends in concentrations of specific constituents during flowback impossible for

most wells.

 The compounds acetone and pyridine showed the greatest tendency to trend but

were not present in every well. Those wells which showed a trend toward

decreasing concentrations for a specific chemical over time are presented below:

o Acetone

– well ―I‖; note that acetone was not detected in the inflow

fr acture fluid (sample ―Day 0‖) for this well.

o Pyridine

– well ―G‖

o Pyridine

– well ―I‖; note that pyridine was not detected in the inflow

fracture fluid (sample ―Day 0‖) for this well.

o Pyridine

– well ―M‖

o Pyridine was present in samples from well ―S‖, inclu ding the inflow (―Day

0‖) sample, but there is no discernable trend in the flowback

concentrations over time.

 The following compounds are not present in every well, but in one well showed a

trend toward increasing in concentrations with time:

o Acetone

– wel l ―Q‖; note that acetone was also detected in the inflow

fracture fluid (sample ―Day 0‖) for this well.

 The following discussion of detected organic compounds is organized by those

compounds potentially present in HVHF additives first followed by compounds

not likely to have been derived from an HVHF additive.

Organic Compounds

– Potentially Directly Related to HVHF Additives

 According to the Agency for Toxic Substances and Disease Registry (ATSDR),

pyridine is a liquid used in the manufacture of pharmaceu ticals, vitamins, food

flavorings, paints, dyes, rubber products, adhesives, insecticides, and herbicides.

It is present in crude coal tar. Pyridine can also exist as a natural breakdown

product of a variety of natural materials and is readily broken dow n by

microbes. 29 

## Pyridine was present in the inflow fluid (―Day 0‖) samples from well

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 23 ―S‖ but not in the inflow sample from well ―I‖ (source water was not sampled for

either of these wells); inflow samples were not obtained from wells ―G‖ and ―M‖.

Therefo re, it is unclear from the MSC database if pyridine was present in the

fracture fluid chemistry or from natural occurrence. The presence of pyridine in

flowback water samples may either be the result of natural occurrence or as a

component of biocides.

 Other compounds detected in flowback water samples from these eight wells

included:

o Benzene (71

- 43

- 2) was only detected in one sample from one well at a

concentration of 6.2 μg/L in a ―Day 14‖ sample. It occurs naturally in

crude oil and has many uses in carpets, compact discs, fuels,

pharmaceuticals, and tires. 30 

## Benzene is present in acid corrosion

inhibitors as a solvent for the active ingredients; benzene is part of the

carrier fluids 31 

## . Therefore, the detection of benzene in produced water

may be rel ated to HVHF chemical use.

o Naphthalene (91

- 20

- 3) was only detected in samples from one well at a

maximum concentration of 820 μg/L in a ―Day 0‖ sample. It occurs

naturally in petroleum and coal tar and is used in the manufacture of dyes,

insecticides, o rganic solvents, and synthetic resins

. I t is also used as

insecticide and repellent (moth balls), in explosives, fuel additives,

fungicides, lubricants, in oilfield chemicals, vermicides, and wood

preservative. 32 

## Naphthalene is present in corrosion inhibi tors, friction

reducers, and some solvents that may be used in HVHF. Therefore, the

detection of naphthalene in produced water may be related to HVHF

chemical use.

o Phenol (108

- 95

- 2) was detected in only one sample from one well at a

concentration of 3.5 μg/L (J

- flagged; estimated) in a ―Day 1‖ sample. It is

used in manufacturing deodorizers, disinfectants, drugs, dyes, explosives,

pesticides, and thermosetting resins. 33 

## Phenol was not identified as being

present in any of the HVHF chemicals previously s ubmitted to the DEC as

a stand

- alone compound. However, there are numerous phenols present in

the fracturing fluid chemicals submitted to the DEC. Therefore, the

detection of phenol in produced water may be related to HVHF chemical

use.

o Toluene (108

- 88

- 3) was detected in two of the eight wells and was only

detected in the inflow (―Day 0‖) samples. Maximum concentration

detected 19 μg/L (J

- flagged; estimated) from an inflow sample. It occurs

naturally in crude oil and has many uses in artificial sweete ners,

automotive parts, cosmetics, fabric coatings, flexible foams, paint, and

printing inks. 34 

## Toluene is present in acid corrosion inhibitors as a solvent

for the active ingredients and as part of the carrier fluid

. 35 

## Therefore, the

detection of toluene in produced water may be related to HVHF chemical

use.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 24 o 1,2,4

- Trimethylbenzene (95

- 63

- 6) was detected in three of the eight wells

and in each of the three wells it was detected in both the inflow (―Day 0‖)

and early produced water samples. Maximum concen tration detected 67

μg/L from an inflow sample. It occurs in petroleum and coal tar and it is

used as a chemical manufacturing intermediate and solvent for resins and

gums. 36 

## 1,2,4

- Trimethylbenzene was identified as being present in the

HVHF chemicals pre viously submitted to the DEC. Therefore, the

detection of 1,2,4

- Trimethylbenzene in produced water may be related to

HVHF chemical use.

o Xylenes (total) was detected in three of the eight wells and in two of those

three wells it was also detected in the inflow (―Day 0‖) samples.

Maximum concentration detected 46 μg/L (J

- flagged; estimated) from an

inflow sample. It occurs naturally in petroleum and has many uses in

adhesives, bactericides, clothing, fuels, lubricants, paints, plastics, and

rubber. 37

, 38 

## Xylene is present in acid corrosion inhibitors as a solvent for

the active ingredients and as part of the carrier fluid. 39 

## Therefore, the

detection of xylene in produced water may be related to HVHF chemical

use.

o Alcohols (butanol, ethanol, methanol, n

- p ropanol, and 2

- propanol)

– among the alcohols, only ethanol, methanol, and 2

- prapanol were

detected, and that in only a limited number of samples. Wells ―I‖

(methanol), ―O‖(ethanol), ―Q‖ (2

- propanol), and ―S‖ (2

- propanol) each

exhibit concentrations of on e of the alcohols in the inflow (―Day 0‖)

samples as well as in the produced water samples from Day 1 and Day

14/15. These consistently demonstrate a trend of decreasing concentration

from maximum concentrations in the inflow (―Day 0‖) to minimum

concentr ations in the Day 14/15 samples. All of the detected

concentrations are J

- flagged (estimated) and the majority of sample results

were not detected. Ethanol , methanol, and 2

- propanol may each be

present in a variety of fracturing additives as these alcoho ls are often used

as a solvent to carry polymers present in inhibitors, gelling agents and

crosslinkers. 40 

## Therefore, the detection of ethanol, methanol, or 2

- propanol in produced water may be related to HVHF chemical use.

o Glycols (ethylene glycol and pr opylene glycol)

– among the glycols, only

propylene glycol was detected, and that in only a limited number of

samples. Well ―K‖ (propylene glycol) and Well ―S‖ (propylene glycol)

each exhibit s concentrations of propylene glycol in the inflow (―Day 0‖)

sam ples as well as in either the Day 1 or Day 14/15 sample. Neither well

exhibited detections from three or more samples; therefore, it is not

possible to establish a reliable trend in concentration with only two data

points for each well. However, the over all trend appears to be one of

decreasing concentration from maximum concentrations in the inflow

(―Day 0‖) to lesser concentrations in the produced water samples (either

Day 1 or Day 14/15). Most (three out of four) of the detected

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 25 concentrations are J

- f

lagged (estimated) and the majority of sample results

were not detected. P ropylene glycol is present in friction reducers and is

used as surfactant within the friction reducer compound. 41 

## Therefore, the

detection of ethanol, methanol, or 2

- propanol in pro duced water may be

related to HVHF chemical use.

Organic Compounds

– Potentially Ind irectly Related to HVHF Additives

 The following compounds are not included on the lists of HVHF additives;

however, they are components of kerosene, which is included on the HVHF

additives list. 42 

## Therefore, these compounds may be present in HVHF additives

by virtue of being a component of kerosene or a similar range hydrocarbon.

 Polynuclear aromatic hydrocarbons (PAHs)

– PAHs occur naturally in crude oil

and as component s of many petroleum products such as asphalt, gasoline, diesel

oil, fresh and used motor oil, roofing tar, and wood preservative (creosote). They

can also be products of incomplete combustion of many substances including oils

and plants (e.g.

, forest fire s, tobacco in cigarettes, etc.) and can be emitted by

volcanoes. 43

, 44



## o Benzo(a)pyrene (50

- 32

- 8) was detected in two of the eight wells and in

one of those two wells it was also detected in the inflow (―Day 0‖) sample.

Maximum concentration detected 6.9 μg/L from an inflow sample.

Benzo(a)pyrene was not identified as being a specific constituent of any of

the HVHF chemicals previously submitted to the DEC ; it is present as a

component of kerosene

. Therefore, the detected presence of

benzo(a)pyrene in produce d water may be related to HVHF activities.

o Benzo(b)fluoranthene (205

- 99

- 2) was detected in two of the eight wells

and in one of those two wells it was also detected in the inflow (―Day 0‖)

sample. Maximum concentration detected 11 μg/L from an inflow

sample. Benzo(b) fluoranthene was not identified as being a specific

constituent of any of the HVHF chemicals submitted to the DEC ; it is

present as a component of kerosene . Therefore, the detected presence of

benzo(b)fluoranthene in produced water may be related to HVHF

activities

.

o Benzo(g,h,i)perylene (191

- 24

- 2) was detected in two of the eight wells

and in one of those two wells it was also detected in the inflow (―Day 0‖)

sample. Maximum concentration detected 7.4 μg/L from an inflow

sample. Ben zo(g,h,i)perylene was not identified as being a specific

constituent of any of the HVHF chemicals previously submitted to the

DEC ; it is present as a component of kerosene

. Therefore, the detected

presence of benzo(g,h,i)perylene in produced water may be related to

HVHF activities.

o Benzo(k)fluoranthene (207

- 08

- 9) was detected in two of the eight wells

and in one of those two wells it was also detected in the inflow (―Day 0‖)

sample. Maximum concentration detected 6.7 μg/L from an inflow

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 26 sample. Benzo(k) fluoranthene was not previously identified as being a

specific constituent of any of the HVHF chemicals submitted to the DEC ;

it is present as a component of kerosene

. Therefore, the detected presence

of benzo(k)fluoranthene in produced water may be relat ed to HVHF

activities.

o Dibenz(a,h)anthracene (53

- 70

- 3) was detected in three of the eight wells

and in one of those three wells it was also detected in the inflow (―Day 0‖)

sample. Maximum concentration detected 12 μg/L from an inflow

sample. Dibenz(a,h) anthracene was not identified as being a specific

constituent of any of the HVHF chemicals previously submitted to the

DEC ; it is present as a component of kerosene

. Therefore, the detected

presence of dibenz(a,h)anthracene in produced water may be relate d to

HVHF activities.

o Fluoranthene (206

- 44

- 0) was detected in two samples from one well, one

sample of which was an inflow (―Day 0‖) sample. Maximum

concentration detected 6.1 μg/L from a ―Day 5‖ sample. Fluoranthene

was not identified as being a specifi c constituent of any of the HVHF

chemicals previously submitted to the DEC ; it is present as a component

of kerosene

. Therefore, the detected presence of fluoranthene in produced

water may be related to HVHF activities.

o Indeno(1,2,3

- cd)pyrene (193

- 39

- 5) was detected in three of the eight wells

and in one of those three wells it was also detected in the inflow (―Day 0‖)

sample. Maximum concentration detected 10 μg/L from an inflow

sample. Indeno(1,2,3

- cd)pyrene was not identified as being a specific

constituent of any of the HVHF chemicals previously submitted to the

DEC ; it is present as a component of kerosene

. Therefore, the detected

presence of indeno(1,2,3

- cd)pyrene in produced water may be related to

HVHF activities.

 2

- Methylnaphthalen e (91

- 57

- 6) was detected in three of the eight wells and in one

of those three wells it was also detected in the inflow (―Day 0‖) sample.

Maximum concentration detected 260 μg/L from the inflow sample. It occurs

naturally in coal tar and is used as a che mical manufacturing intermediate for

insecticides and plant growth regulators ; it is also used in brightening agents, dye

carriers, and surfactants. 2

- Methylnaphthalene was not identified as being a

specific constituent of any of the HVHF chemicals previo usly submitted to the

DEC, but is similar to naphthalene which i s on the HVHF chemicals list in the

dSGEIS . 2

- Methylnaphthalene is also a natural constituent of petroleum, is

present in natural oils, and can be found as a byproduct of shale oil production

. 45



## Therefore, the detected presence of 2

- methylnaphthalene in produced water may

be related to HVHF activities.

 1,3,5

- Trimethylbenzene (108

- 67

- 8) was detected in three of the eight wells and in

two of those three wells it was also detected in the inflow (―Day 0‖) samples.

Maximum concentration detected 20 μg/L from an inflow sample. It occurs in

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 27 petroleum and coal tar and it is used as a chemical manufacturing intermediate

and solvent for resins and gums. 46 

## 1,3,5

- Trimethylbenzene was not identified as

being a specific constituent of any of the HVHF chemicals previously submitted

to the DEC, but is similar to 1,2,4

- Trimethylbenzene (95

- 63

- 6) which was on the

HVHF chemicals list in the dSGEIS

. 1,3,5

- Trimethylbenzene is also a natural

constituent of petroleum. Therefore, the detected presence of 1,3,5

- trimethylbenzene in produced water may be related to HVHF activities.

Organic Compounds

– Unrelated to HVHF Additives

 Acetone is a very common laboratory contaminant and is presen t in a variety of

sa mples. This, combined with its inconsistent concentration trends within

individual wells, calls into question whether this compound is actually present in

the investigatory samples or if these detections are simply the result of laboratory

contamination. Acetone, along with 2

- Butanone (MEK), methylene chloride, and

phthalates, are common laboratory contaminants; acetone is often used in the

cleaning of glass wear used in lab analysis. 47 

## T herefore, the detected presence of

acetone in produced water is beli eved to be unrelated to HVHF activities and is

potentially an artifact of the analytical activities as the lab.

 Other compounds detected in produced water samples from these eight wells

included:

o Acetophenone (98

- 86

- 2) was only detected in one sample from one well at

a concentration of 13 μg/L in a ―Day 1‖ sample. It is used as a chemical

manufacturing intermediate and solvent for agrocehmicals,

pharmaceuticals and other organic chemicals; it is used as a sol vent for

cellulose, plastics, and resins; as a plasticizer; in beverages, cosmetics,

flavorings, foods, perfumes, soaps and detergents, and tobacco. 48



## Acetophenone was not identified as being a specific constituent of any of

the HVHF chemicals previously s ubmitted to the DEC. Therefore, the

detected presence of acetophenone in produced water is believed to be

unrelated to HVHF activities.

o B is(2

- Chloroethyl) ether (111

- 44

- 4) was only detected in samples from

one well at a maximum concentration of 4,300 μg/L in a ―Day 0‖ sample.

It is used as a cleaner and solvent, as a component of paint and varnish, as

a pesticide, rust inhibitor, and a chemical intermediate in manufacturing. 49



## B is(2

- Chloroethyl) ether was not identified as being a specific constituent

of any of the HVHF chemicals previously submitted to the DEC.

Therefore, the detected presence of bis(2

- Chloroethyl) ether in produced

water is believed to be unrelated to HVHF activities.

o Bromoform (75

- 25

- 2) was only detected in samples from one well at a

maximum concentration of 7.8 μg/L in a ―Day 0‖ sample. It is used as a

chemical manufacturing intermediate in agro

- c h emicals and organic

synthesis and solvent for greases, oils, and waxes; it is used in cough

suppressant, fire resistant gauges, and sedat ive. 50 

## Bromoform was not

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 28 identified as being a specific constituent of any of the HVHF chemicals

previously submitted to the DEC. It can be formed in the environment as

a result of disinfection byproducts associated with the use of chlorine to

kill bacter ia. 51 

## Bromoform is also a common laboratory reagent. 52



## Therefore, the detected presence of bromoform in produced water is

believed to be unrelated to HVHF activities.

o 2

- Butanone (78

- 93

- 3; also known as methyl ethyl ketone ) was detected in

two of the eight wells and in one of two wells it was also detected in the

inflow (―Day 0‖) sample. Maximum concentration detected 17 μg/L (J

flagged; estimated) from a ―Day 1‖ produced water sample. It occurs

naturally in some fruits, vegetables, and trees and is also manufactured for

use in cleaning agents, glues, and paints and other coatings. 53 

## 2

- butanone

was not identified as being a specific constituent of any of the HVHF

chemicals previously submitted to the DEC. While 2

- Butanone is a

manufactured chemical it can also be present in the environment from

natural sources, and is commonly present in air as a result of car and truck

emissions

. I t is dissolved easily in water and is quickly broken down to

simpler chemicals in a manner of weeks. 54 

## 2

- Butanone is also used as

solvent in the production of paraffin and denatured alcohols. 55 

## Therefore,

the detected presence of 2

- butanone in produced water is believed to be

unrelated to HVHF activities.

o P

- Isopropyltoluene (99

- 87

- 6) was only detected in one sample from one

well at a concentration of 28 μg/L (J

- flagged; estimated) in a ―Day 5‖

sample. It occurs naturally in oil of cumin and oil of thyme and it is used

in perfumes, synthetic fibers, synthetic pesticides, and synthetic resins. 56



## P

- Isopropyltoluene was not identified as being a specific constituent of

any of the HVHF chemicals previously submitted to the DEC. It is also a

natural microbicide used to treat E. coli

. 57 

## Therefore, the detected

presence of p

- isopropyltoluene in produc ed water is believed to be

unrelated to HVHF activities.

o Methylene chloride (75

- 09

- 2) was detected in only one sample from one

well (―I‖)

. I t is a common laboratory contaminant, and it is ―B‖ flagged

, indicating that the laboratory detected methylene chloride in the lab blank

sample associated with that investigatory sample. Therefore, methylene

chloride is conclusively indicated to be a result of laboratory

contamination; it is conclusively unrelated to HVHF activities.

o N

- Nitrosodiphenylamine (62

- 75

- 9) was only detected in only one sample

from one well at a concentration of 2.7 μg/L in a ―Day 14‖ sample. It is

used in the manufacture of chemicals and rubber products (tires), but was

replaced in the early 1980s with more efficient chemicals (c urrently there

is only one remaining man u f a cturer in the U.S.); it may also exist naturally

from the activity of microbes. 58 

## N

- Nitrosodiphenylamine was not

identified as being a specific constituent of any of the HVHF chemicals

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 29 previously submitted to the DEC. Therefore, the detected presence of n

nitrosodiphenylamine in produced water is believed to be unrelated to

HVHF activities.

o PCBs were not detected in samples from the eight wells from northern

Pennsylvania counties. The manufacture of PCBs was ba nned in the U.S.

in 1979 ; 59 

## therefore, PCBs would not be a constituent of any drilling or

fracturing additive.

o Pesticides

– primarily banned organochlorine pesticides:

 Aldrin (309

- 00

- 2) was detected in three of the eight wells

including two ―Day 0‖ samp l es. Maximum concentration detected

0.17 μg/L (PG

- flagged; est i mated) in a ―Day 0‖ sample. It does

not occur naturally. Until 1970, it was used as an insecticide for

food and non

- food crops and also for termite control (until 1987);

EPA banned all use of it in 1987. 60 

## Aldrin was not identified as

being a specific constituent of any of the HVHF chemicals

previously submitted to the DEC. Therefore, the detected presence

of aldrin in produced water is believed to be unrelated to HVHF

activities.

 B eta

- BHC (319

- 85

- 7) was detected in two of the eight wells

including one ―Day 0‖ sample. Maximum concentration detected

0.37 μg/L in a ―Day 14‖ sample. It does not occur naturally.

Among the BHC isomers, the gamma isomer (Lindane) provided

the vast major ity of insecticidal properties. In the U.S. Lindane

has not been manufactured since 1976, but is available in imported

products. Beta

- BHC was used in the same manner as Lindane. 61



## B eta

- BHC was not identified as being a specific constituent of any

of the HVHF chemicals previously submitted to the DEC.

Therefore, the detected presence of beta

- BHC in produced water is

believed to be unrelated to HVHF activities.

 D elta

- BHC (319

- 86

- 8) was detected in only one of the eight wells

at a concentration of 0.072 μ g/L (PG

- flagged; estimated) in a ―Day

0‖ sample. It does not occur naturally. Among the BHC isomers,

the gamma isomer (Lindane) provided the vast majority of

insecticidal properties. In the U.S. Lindane has not been

manufactured since 1976, but is avail able in imported products.

Delta

- BHC was used in the same manner as Lindane. 62 

## D elta

BHC was not identified as being a specific constituent of any of

the HVHF chemicals previously submitted to the DEC. Therefore,

the detected presence of delta

- BHC in pro duced water is believed

to be unrelated to HVHF activities.

 G amma

- BHC (58

- 89

- 9; Lindane) was detected in only one sample

from one well at a concentration of 0.27 μg/L in a ―Day 14‖

sample. It is a broad spectrum insecticide for the protection of

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 30 seeds a nd soil as well as wood and timber. It has also been used in

veterinary and pharmaceutical products. 63 

## In the U.S. Lindane has

not been manufactured since 1976, but is available in imported

products. 64 

## G amma

- BHC was not identified as being a specific

cons tituent of any of the HVHF chemicals previously submitted to

the DEC. Therefore, the detected presence of gamma

- BHC in

produced water is believed to be unrelated to HVHF activities.

 Endosulfan I (115

- 29

- 7) was detected in only one sample from one

well a t a concentration of 0.5 μg/L in a ―Day 14‖ sample. It does

not occur naturally and is used as an insecticide for food and non

food crops and is also used as a wood preservative. 65 

## Endosulfan 1

was not identified as being a specific constituent of any of the

HVHF chemicals previously submitted to the DEC. Therefore, the

detected presence of endosulfan I in produced water is believed to

be unrelated to HVHF activities.

 Heptachlor (76

- 44

- 8) was detected in six of the eight wells

including two sour ce water samples. Maximum concentration

detected 0.84 μg/L (PG

- flagged; estimated) in a ―Day 0‖ sample; it

is also present in the supply water sample from the same well at a

concentration of 0.8 μg/L (also PG

- flagged). It does not occur

naturally. Until 1988, it was used as an insecticide for buildings

(including residences) and food crops; current use is restricted to

fire ant control at underground electrical transformers. 66



## Heptachlor was not identified as being a specific constituent of any

of the HV HF chemicals previously submitted to the DEC.

Therefore, the detected presence of heptachlor in produced water

is believed to be unrelated to HVHF activities.

 Heptachlor epoxide (1024

- 57

- 3) was detected in only one sample

from one well at a concentratio n of 0.26 μg/L (PG

- flagged;

estimated) in a ―Day 0‖ sample. It is a breakdown product of

heptachlor. 67 

## Heptachlor epoxide was not identified as being a

specific constituent of any of the HVHF chemicals previously

submitted to the DEC. Therefore, the dete cted presence of

heptachlor epoxide in produced water is believed to be unrelated

to HVHF activities.

o Phthalates

– plasticizers: Phthalates are the most commonly used

p l asticizers and are used to make soft, flexible PVC for automotive,

building and construction materials, cable, flooring, medical devices, and

toys. 68



##  B is(2

- Ethylhexyl) phthalate (117

- 81

- 7) was detected in three of the

eight wells and in two of those three wells, it w as also detected in

the inflow (―Day 0‖) samples. Maximum concentration detected

14 μg/L from an inflow sample. Bis(2

- Ethylhexyl) phthalate was

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 31 not identified as being present in any of the HVHF chemicals

previously submitted to the DEC. Therefore, the detected presence

of bis(2

- ethylhexyl) phthalate in produced water is believed to be

unrelated to HVHF activities.

 Di

- n

- butyl phthalate was only detected in one sample from one

well at a concentration of 130 μg/L in a ―Day 14‖ sample. Di

- n

butyl phthala te was not identified as being present in any of the

HVHF chemicals previously submitted to the DEC. Therefore, the

detected presence of di

- n

- butyl phthalate in produced water is

believed to be unrelated to HVHF activities.

o Tetrachloroethene (127

- 18

- 4) was only detected in one sample from one

well at a concentration of 8.9 μg/L (J

- flagged; estimated) in a ―Day 1‖

sample. It does not occur naturally and it has many uses including as a

chemical intermediate in the manufacture of fluorocarbons, paint

remov ers, and printing inks, in copying machines, dry cleaning solvent, a

solvent for caffeine (coffee) fats, greases, gums, rubbers, and waxes, in

textile processing, and as a vapor

- degreaser, as a vermifuge, and in

veterinary medicines. 69 

## Tetrachloroethene wa s not identified as being

present in any of the HVHF chemicals previously submitted to the DEC.

Therefore, the detected presence of tetrachloroethene in produced water is

believed to be unrelated to HVHF activities.

o 1,2,3

- Trichlorobenzene (87

- 61

- 6) was only detected in one sample from

one well at a concentration of 6.5 μg/L in a ―Day 14‖ sample. It has many

uses including as a fungicide or lubricant. 70 

## 1,2,3

- Trichlorobenzene was

not identified as being present in any of the HVHF chemicals previously

sub mitted to the DEC. Therefore, the detected presence of 1,2,3

-

trichlorobenzene in produced water is believed to be unrelated to HVHF

activities.

Indicator Parameters

 Many of the detected constituents occurred at concentrations such that the data

require d one of the following a qualifier flags:

o ―J‖

– an estimated concentration from a diluted sample where the results

are outside of the calibration range for the instrumentation/analytical

method. 71



## o ―GU‖

– the ―G‖ qualifier indicates the sample required dilu tion in order to

analyze and the ―U‖ qualifier indicates that the target analyte was not

detected. 72



## o ―B‖

– the target analyte was detected in the laboratory method blank

associated with the laboratory analysis of the investigatory sample.

Consequently, the presence of the analyte may reflect sample

contamination introduced in the laboratory rather than i ts actual presence

in the investigatory sample. The analytical result has no definitive bearing

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 32 on either the actual presence of or the concentration, if in fact present, in

any ―B‖

- flagged sample and so these data cannot be relied upon for

objective eval uation. The environmental industry standard in

investigatory studies is to consider laboratory

- contaminated samples non

representative of actual conditions.

 The following tables summarize indicator parameters and metals from the MSC

database.

 The primar y observations from this data are:

o Total dissolved solids (TDS) concentrations in the fracturing fluids are

only moderately higher than those in the make

- up source water. TDS

increases significantly during the flowback process (see response to i tem

―Flowback Water Characterization #1‖ for a more detailed discussion).

The source of this increase is believed to be from connate water present in

the target formation and, possibly, from dissolution of some salts that may

be present in solid form in t he Marcellus (however, note that the Marcellus

does not have an evaporite depositional facies and so contribution from

dissolution is expected to be minimal, if any). Some salts, particularly

potassium chloride, may be present in HVHF additives; however, the

additive concentrations would typically be in the range of up to a few tens

of thousands of mg/L, not high tens of thousands or hundreds of thousands

of mg/L as observed in some later produced water samples. Therefore, the

majority of increased TDS co ncentrations are believed to be largely

representative of salts naturally present in the Marcellus Shale and are not

a direct result of the HVHF additives

.

o Biochemical oxygen demand (BOD) has a negligible presence in the

make

- up source water and demonstr ates its highest concentrations in the

inflow samples, with generally decreasing concentrations over time during

the flowback process . This is likely to be a result of the addition of guar

and other organic

- based gelling agents in the HVHF fluids.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 33 Exhibit 5

Comparison of Water Supply and Inflow Fracturing Fluids

- Select Indicator Parameters and Inorganics

Water Supply Inflow Fracturing Fluid

Parameter Measuring Units Range Median Range Median

Low High Low High

pH pH, acid, iron control 7.0 7.3 7.15 6.0 7.6 7.05

Total Alkalinity Scale potential mg/L 6.2 88.8 40.35 2.5 191 57.55

Hardness as CaCO3 Scale potential mg/L 18 156 89 26 1,300 117

Chloride Brine mg/L 28.1 49.9 42.3 58.5 2,180 86

Total Dissolved Solids (TDS) TDS mg/L 51 746 338.5 265 4,840 587.5

Total Kjeldahl Nitrogen Numerous HVHF additives mg/L 1.5 1.5 1.5 11.9 400 44.75

Biochemical Oxygen Demand

(BOD) Polyacrylamide friction reducer mg/L 1 1 1 121 2,220 309.5

Chemical Oxygen Demand (COD) mg/L 5 18.7 11.7 490 47,400 2,095

Total Organic Carbon (TOC) Polyacrylamide friction reducer mg/L 2.3 2.4 2.45 11.4 949 572

Oil & Grease Hydrocarbons, friction reducer mg/L 2.3 2.4 2.35 2.35 158 31.2

Cyanide, total μg/L 5 5 5 5 320 12.5

Bromide Brine mg/L 0.07 1 0.16 0.1 36.6 4.75

Sulfate Breaker mg/L 8.3 43.7 8.4 8.4 2,920 32.6

Sulfite mg/L 6 21.6 10.6 2.5 47.2 16

Methylene Blue Activated

Substances (MBAS) Surfactants mg/L 0.025 0.962 0.16845 0.025 0.501 0.025

Barium, total Scale potential μg/L * * * 37,600 1,160,000 79,650

Calcium, total Scale potential μg/L * * * 123,000 241,000 182,000

Chromium, total μg/L 25 25 25 25 25 25

Copper, total μg/L 125 125 125 125 125 125

Iron, total μg/L * * * 1,790 14,300 5,240

Lead, total μg/L 15 15 15 15 1790 15

Magnesium, total Scale potential μg/L * * * * * *

Mercury, total μg/L 0.1 0.1 0.1 0.1 0.1 0.1

Nickel, total μg/L 200 200 200 200 200 200

Sodium, total Brine μg/L * * * 60,800 18,100,000 67,800

Strontium, total Scale potential μg/L 588 1,500 723 597 47,900 1,070

Zinc, total μg/L * * * 1,610 1,610 1,610

Notes: For the purposes of tabulation and statistical calculations, a non

- detection is set to half the value of the detection limit.

For the purposes of statistical calculations, no value is included when the detection is "B"

- flagged for presence in a lab blank.

* = all sample results were "B"

- flagged for presence in a lab blank

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 34 Exhibit 6

Comparison Of Produced Water Quality Over Time

- Select Indicator Parameters and Inorganics

Day 1 Day 14/15

Parameter Measuring Units Range Median Range Median

Low High Low High

pH pH, acid, iron control 5.9 7.9 7.2 5.6 6.8 6.5

Total Alkalinity Scale potential mg/L 107 338 124 26.1 119 82.75

Hardness as CaCO3 Scale potential mg/L 156 25,000 2,200 630 95,000 42,400

Chloride Brine mg/L 64.2 58,700 8,410 1,670 181,000 79,000

Total Dissolved Solids (TDS) TDS mg/L 680 122,000 17,400 3,010 261,000 146,500

Total Kjeldahl Nitrogen Numerous HVHF additives mg/L 14.2 150 58.7 5.6 199 123

Biochemical Oxygen Demand (BOD) Polyacrylamide friction reducer mg/L 36.3 1,440 350.5 7.3 990 25.4

Chemical Oxygen Demand (COD) mg/L 397 10,700 1,790 228 21,900 11,050

Total Organic Carbon (TOC) Polyacrylamide friction reducer mg/L 2.2 672 133 1.2 509 23.8

Oil & Grease Hydrocarbons, friction reducer mg/L 2.3 53.9 2.4 2.3 36.2 4.9

Cyanide, total μg/L 5 21.5 15.2 5 5 5

Bromide Brine mg/L 0.1 261 87.9 65 1,190 708.5

Sulfate Breaker mg/L 17.4 25 21.6 5 25 25

Sulfite mg/L 5.6 26.8 13.2 9.2 73.6 13.8

Methylene Blue Activated

Substances (MBAS) Surfactants mg/L 0.025 2.94 0.198 0.0733 1.06 0.1945

Barium, total Scale potential μg/L 37,600 1,450,000 387,000 105,000 12,500,000 1,835,000

Calcium, total Scale potential μg/L 305,000 19,700,000 676,000 173,000 26,400,000 11,050,000

Chromium, total μg/L 25 359 37.7 25 567 242.5

Copper, total μg/L 125 255 125 125 493 125

Iron, total μg/L 5,830 67,200 19,450 39,200 223,000 74,900

Lead, total μg/L 15 70.9 15 15 453 52.5

Magnesium, total Scale potential μg/L 52,000 1,320,000 121,350 77,600 1,800,000 938,000

Mercury, total μg/L 0.1 0.1 0.1 0.1 0.1 0.1

Nickel, total μg/L 200 200 200 200 1,000 400

Sodium, total Brine μg/L 63,800 34,700,000 6,015,000 922,000 85,600,000 31,750,000

Stronti um, total Scale potential μg/L 580 4,330,000 156,500 39,000 5,570,000 3,320,000

Zinc, total μg/L 100 665 314 223 1,330 554

Notes: For the purposes of tabulation and statistical calculations, a non

- detection is set to half the value of the detection limit.

For the purposes of statistical calculations, no value is included when the detection is "B"

- flag ged for presence in a lab blank.

* = all sample results were "B"

- flagged for presence in a lab blank

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 35 o Chemical oxygen demand (COD) also has negligible presence in the

make

- up source water and demonstrates its highest concentrations in the

produced water samples with generally increasing concentrations over

time during the flowback process . This is likely to be a result of the

increased TDS in produced waters over time.

o Total organic carbon (TOC) has a negligible presence in the make

- up

source water and demonstrates its highest concentrations in the inflow

samples with generally decreasi ng concentrations over time during the

flowback process . The MSC study suggests that this is a result of poly

acrylamide friction reducers in the inflow. 73



## o Oil and grease has a negligible presence in the make

- up source water and

demonstrates its highest concentrations in the inflow samples with

generally decreasing concentrations over time during the flowback

process . The oil and grease detections may reflect the presence of mineral

oil or petroleum hydrocarbons in friction reducer additives in the inflo w

and produced samples. 74



## o Cyanide was detected with only scattered reliability. Many of the detected

cyanide results were ―B‖

- flagged as laboratory contaminants and so were

not conclusively present in those samples. Of the valid detected

concentrations, those with the greatest values tend to occur in ―Day 0‖ in

flow or ―Day 1‖ produced samples (for example see Wells K and Q data).

There are no known HVHF additives which contain cyanide and cyanide

may occur naturally; therefore, the origin of its presen ce in the limited

number of valid sample results is unknown. Note that nitrile compounds

contain a CN functional group, some of which are present in HVHF

additives; however, the laboratory analysis detects the cyanide ion.

Therefore, the CN functional gr oup in nitrile compounds will not be

picked up by the cyanide analysis. 75



## o Bromide, chloride, and sodium are primary constituents of brine. They

have only a negligible contribution to the make

- up source water (if fresh

water rather than recycled water i s used) and considerably greater

concentrations in the inflow HVHF fluids. This may be a result of reuse

of HVHF

- produced water in subsequent fracture stimulations which the

MSC study indicates was done for some wells; however, the specific wells

in which produced water was reused are not specifically identified by that

study. 76 

## It may also be a result of chloride salt

- based HVHF fluids such as

potassium chloride. The greatest concentrations of these three constituents

are in the later stage produced wate r and so are believed to also be

representative of salts naturally present in the Marcellus Shale (as connate

water or dissolved from solids in the target formation).

o Sulfate and sulfite are present in the make

- up source waters but exhibit

their greatest concentrations in the inflow samples and somewhat

decreasing concentrations over time during the flowback process . The

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 36 presence of sulfate and sulfite may be a reflection of breakers and other

HVHF additives.

o Methylene blue activated substances (MBAS) ar e present in make

- up

source waters at their second highest concentration and do not exhibit

conclusive trends over time during the flowback process . The MSC study

suggests that MBAS may be a reflection of surfactants used in the HVHF

fluids. 77 

## Therefore, their presence in the source water may be a result of

residuals present in recycled produced water used for make

- up water in

subsequent fracture stimulations, which the MSC study indicates was done

for some wells; however, the specific wells in which produ ced water was

reused are not specifically identified by that study. 78



## Metals

 As with the indicator parameters, many of the detected metallic elements occurred

at concentrations such that the data required one of the following qualifier flags:

o ―J‖

– an estimated concentration from a diluted sample where the results

are outside of the calibration range for the instrumentation/analytical

method. 79



## o ―GU‖

– the ―G‖ qualifier indicates the sample required dilution in order

to analyze and the ―U‖ qualifier ind icates that the target analyte was not

detected. 80



## o ―B‖

– the target analyte was detected in the laboratory method blank

associated with the laboratory analysis of the investigatory sample.

Consequently, the presence of the analyte may reflect sample

conta mination introduced in the laboratory rather than its actual presence

in the investigatory sample. The analytical result has no definitive bearing

on either the actual presence of or the concentration, if in fact present, in

any ―B‖

- flagged sample and so these data cannot be relied upon for

objective evaluation. The environmental industry standard in

investigatory studies is to consider laboratory contaminated samples non

representative of actual conditions.

 The following metals were only detected wit h ―B‖

- flagged samples in the MSC

study. As such, these data cannot be relied upon to indicate either the presence of

or concentration of a metal.

o Antimony, total

o Arsenic, total

o Cadmium, total

o Mercury, total

o Selenium, total

 Hexavalent chromium was prese nt in four of 39 samples from the eight wells

from northern Pennsylvania and three of those were ―B‖

- flagged as having been

present in the associated laboratory blank. The detection limits for hexavalent

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 37 chromium were uniformly low

, suggesting that signif icant sample dilution was

not a contributing factor to non

- detections. Therefore, it is realistic to be

suspicious of the one apparently valid observation. Industry is not aware of the

use of hexavalent chromium in any of its HVHF additives.

 The follow ing metals were present in inflow samples as well as in numerous

produced samples and display a general trend of increasing concentrations over

time during the flowback process . Note that several were present at low

concentrations in the source water and several were not conclusively present in

source water due to their detection in associated laboratory blanks; therefore,

those results are not valid samples for comparison.

o Barium, total

o Calcium, total

o Iron, total

o Magnesium, total (note: all source water a nd inflow sample data was ―B‖

- flagged as laboratory contamination; however, the Day 1 and Day 14 data

suggest an increasing trend may be present)

o Sodium, total

o Strontium, total

 The following metals may be present (the majority of the data is non

- detect or

―B‖

- flagged as a lab contaminant); however, it is difficult to conclusively

demonstrate a trend in concentrations.

o Chromium, total

o Copper, total

o Lead, total

o Nickel, total

o Zinc, total

 The origin of the metals whose concentrations increase with time during the

flowback process are likely sourced from the target formation or its connate

water. Metals may also be present as components of HVHF additives that contain

metallic elements in their chemical make

- up; however, none of the additives are

metal

- based.

4. C omments state that the assumption in the air quality modeling that the

concentration of the additives in inflow water are representative of concentrations

in flowback impoundments is too conservative and/or more representative data

from flowback water shou ld be collected and used in the assessments. The draft

SGEIS assumption was necessary because very little information was provided from

industry on flowback water concentrations of the specific additive constituents and

thus the analysis was based on the c onservative assumption. For air quality

modeling to use more representative flowback water concentrations in the emission

calculations, industry must provide all available data noted below:

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 38 a. The concentration of the following chemicals in flowback water: each of the

13 chemicals identified in Table 6

- 13 of the draft SGEIS, plus propylene

glycol monobutyl ether, dimethyl diallyl ammonium chloride, any other

microbiocide to be used in addition t o glutaraldehyde, dazomet, tetrakis,

cupric chloride

- dihydrate, and any other known acute or long

- term high

toxicity chemical from Table 5

- 6 of the draft SGEIS proposed for use in

additives.

b. For each chemical listed in item (a), a determination whether eac h was a

constituent of the inflow hydraulic fracturing water mix and the

corresponding concentration of the chemical in the inflow hydraulic

fracturing water mix.

c. The number of samples taken for each of the chemicals listed in item (a),

whether these were from a single well or different well locations, and a

determination that the samples are representative of Marcellus Shale

operations.

d. If the analyses requested in item (a) are not available, industry should

indicate whether it plans to obtain this data an d, if yes, the proposed

schedule and methodology.

IOGA Response:

The fo llowing response is subject to all of the caveats mentioned in the Preamble to this

document.

As stated under item ―Air Impacts #2‖ above, flowback of HVHF produced water to

impoundment s or open pits will not occur; produced water returned during the flowback

process will be stored in tanks. Therefore, the concerns about air emissions of HVHF

constituents from impoundments are no longer relevant considerations for the SGEIS.

Basic info rmation regarding HVHF fluid and produced water chemistry is provided in

response to item ―Air Impacts #3.‖

5. Comments recommend that the drilling and hydraulic fracturing engines should be

treated as intermittent nonstationary sources similar to other con struction activities.

Industry must provide a detailed description of how long it expects these drilling

and hydraulic fracturing engines to be at a single pad over a year period in order to

drill and complete 10 wells noted in the comment. This should inc lude a

quantification of the “intermittent” nature noted. In recognition that the draft

SGEIS is to consider possible worst case conditions and operations, these time

frames should include periods when the engines are still on site even if not in

operation

.

IOGA Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 39 The U.S. Environmental Protection Agency ( EPA ) has defined ― stationary engines ‖ as all

internal

- combustion engines that are used either i n a fixed application, or in a portable (or

transportable) application in which the engine will remain at a single location for a full

year or more (≥365 consecutive days). 81 

## The DEC defines a ― stationary source ‖ as ― Any

building, structure, facility or installation, excluding nonroad engines that emits or may

emit any air pollutant.‖ 82 

## Moreover, the DEC defines a ― nonroad engine ‖ as an internal

combustion engine that, by itself or in or on a piece of equipment, is portable or

transportable, meaning desig ned to be and capable of being carried or moved from one

location to another. Indicators of transportability include, but are not limited to, wheels,

skids, carrying handles, doll ies , trailer s , or platform s .‖ 83 

## Therefore, i ndustry considers

the drilling a nd hydraulic fracturing engines as non

- stationary sources since these engines

meet the definition of nonroad engines and will be located at a single well pad for less

than one year. 84



## Early in the play development, a typical Marcellus Shale horizontal wel l is estimated to

require 25 days to drill from spud to total depth. As is common with all emerging oil and

gas plays, t his worst

- case drilling time is anticipated to decrease in the future as local

play

- specific drilling experience is gained. In some ca ses, operators are projecting an

average drilling time of only 10 days depending on the length of a lateral wellbore.

As noted in the response to i tem ―Activity Estimates 1 b ‖ (see page 13), industry

anticipates typically drilling the first one to four we lls on a multi

- well pad (on average

two wells in the first year of development on a given pad) and then moving the drilling

rig off site to another well pad to prove up that subsequent location, and so on. Although

an entire multi

- well pad may include upwards of 10 horizontal wells (see Exhibit 18), all

10 horizontal wells will not be drilled during any 12

- month period

. After the drilling rig

moves off

- site, the HVHF equipment will be brought in to stimulate and complete these

two wells. Based on this scenario, the drilling and HVHF engines are expected to be on

site for each well pad , using a worst

- case assumption, as follows:

 Mobilizing the drilling rig to the well pad will require 3 days.

 Drilling the two initial wells will require 20 days per well (40 days total).

 De

- mobilizing the drilling rig from the well pad will require 3 days.

 Mobilizing the HVHF equipment to the well pad will require 2 days.

 Performing the HVHF stimulation will require 5 days per well (10 days total).

 De

- mobilizing the HVHF equipment will require 2 days.

Therefore, the total operational time for each well pad per year is estimated at 50 days

with 10 days mobilizing

- demobilizing. To conservatively account for any down time

(equipment repairs, awaiting readiness of the next dr illing location, well logging, etc.), a

factor of 25 % can be added bringing the total to 62.5 days of operations and 12.5 days of

mobilizing

- demobilizing for a total of 75 days. This worst

- case scenario represents the

total time that drilling and fracturi ng engines are on

- site and operable as well as on

- site

and inactive in any given 12

- month time period. Drilling and fracturing equipment are

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 40 never operational on the same pad at the same time. It is not anticipated that drilling will

reoccupy a given wel l pad within that 12

- month period.

IOGA cannot foresee any circumstances where an operator would engage in continuous

drilling and completion activities at a single well pad for more than 12 consecutive

months. As noted above, one to four wells (on averag e two wells) will be drilled on the

same multi

- well pad during a year (on average 75 days for two wells ) in that year (12

consecutive months). It is in the best interest of operators to manage their engines in this

manner as it is consistent with the definition of non

- road engine: a portable engine that is

in use for less than 12 consecutive months and that does not meet the definition of a

seasonal source (6 NYCRR § 200.1(aw) . Otherwise, more restrictive permitting

requir ements would prevail.

6. A supplemental modeling analysis was undertaken by Chesapeake Energy for PM10

and PM2.5 to provide more “refined and realistic” impacts by modifying a number

of the modeling assumptions used in the draft SGEIS. Chesapeake notes that t he

modeling input and output files can be made available upon request. DEC requests

that all modeling input and output files be provided, including the study on the

effects of using ULSD fuel on particulate emissions (page 24, Appendix 1 of

Chesapeake’s co mments).

IOGA Response

IOGA submitted the requested information under via separate email communication to

DEC dated June 21, 2010. No further discussion is provided herein.

7. The draft SGEIS requested that industry identify mitigation measures which shoul d

meet the criterion of minimizing impacts to the maximum extent practicable. To

that end, Chesapeake, IOGA and NRDC/AKRF have identified a set of mitigation

measures for the elimination of modeled exceedences of the particulate matter

standards. These inc lude: a) use of cleaner engines, i.e. EPA Tier 4 or higher than

EPA Tier 2 with diesel particulate filters (DPF), b) use of clean fuels such as gas and

biofuels, and c) manufacturers’ guarantee of low emissions for tier 2 and 3 engines.

DEC requests that industry provide details on the current use of each of these

measures (including DPF) at other well drilling sites and their availability and

practical use for drilling and hydraulic fracturing in Marcellus Shale in NY. Also,

any additional available mitig ation measures for pollutants which are projected to

exceed pollutant thresholds, in lieu of using the stack height extension noted in

the SGEIS , should be described.

IOGA Response:

The following response is subject to all of the caveats mentioned in the Pr eamble to this

document.

IOGA understands that

, in preparing the draft SGEIS (dSGEIS), the DEC simplified their

air modeling by using wors t

- case emission rates and very conservative assumptions.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 41 Therefore, when that modeling showed a potential exceedance of a particulate matter

standard, industry felt it important to conduct additional air modeling with more realistic,

but still conservative

, assumptions. This allowed IOGA members to determine more

realistic impacts from planned development activities and evaluate the effectiveness of

potential mitigation measures. The supplemental modeling was based on a number of

refined assumptions to the DEC’s modeling analysis and focused on the drilling and

hydraulic fracturing sources because they were the most sig nificant contributors to the

maximum impacts. These refinements and their justification are discussed below:

 HVHF stimulation of one well while drilling a second at the same well pad will

not occur. Therefore, both drilling and HVHF engine emissions shou ld not be

modeled as if they were to occur simultaneously. By modeling source groups

such as drilling, hydraulic fracturing, and production separately, the supplemental

modeling was able to examine the impacts from individual activities. Thus,

simultaneo us impacts from drilling and hydraulic fracturing sources a re avoided.

 The emissions data used in the DEC’s analysis were for total particulate matter

(PM). The hydraulic fracturing and drilling emissions were adjusted by

speciating PM into PM 10 

## and PM 2.5 

## . Pursuant with EPA ’s Compilation of Air

Pollutant Emission Factors, AP

- 42 Chapter 3.4 Table 3.4

- 2, PM 10 

## for diesel

engines is approximately 82 % of total PM and PM 2.5 

## is 69 % of total PM.

 Hydraulic fracturing emissions were modeled by DEC as 5 sources rath er than as

15 individual engine sources. The supplemental modeling included all 15 engines

as individual sources, which also led to an inherently larger downwash structure.

 Since there is typically a defined well pad area with restricted access, the

suppl emental modeling did not include on

- pad receptors.

 Due to the widespread availability of ultra low sulfur diesel (ULSD) fuel in New

York

, the supplemental modeling assumed a 10 % emission reduction for its use in

the drilling and HVHF engines. This also re presents a potential mitigation

measure under the clean fuel category.

The results of the supplemental modeling reduced the off

- pad short

- term PM impacts

considerably. In addition, DEC’s emission estimates assumed that HVHF engines will

operate continuous ly for 24 hours. In fact, this is not consistent with actual HVHF

operations. The expected maximum the engines may actually operate at peak horsepower

is for 2 hours at a time up to 5 times per day ( i.e.

, five fracturing sub

- stages, each of two

hours duration). Since the 5 HVHF stages in any given 24

- hour period will not occur at

the same hours of the day, IOGA recognizes that it is difficult to accurately represent the

10 hours per day of actual HVHF eng ine operation in the model. However, modeling a

worst case hourly particulate emission rate for the entire 24

- hour period is not

representative of the actual operation of these sources and is considered by IOGA to be

overly conservative.

The conservative nature of the DEC’s modeling for particulate matter becomes even

greater when considering compliance with the associated NAAQS. Since the NAAQS

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 42 considers individual 24

- hour concentrations over a 3

- year period, compliance

demonstrations base upon the HVHF engines operating as continuous sources is again

overly conservative . These sources are only emitting at a maximum of 10 hours a day

during actual operation and they are only physically present on the well pad for up to 75

days per year ( drilling and frac turing combined, see response to item ―Air Impacts 5)

above)

.

It is significant to note that the only area in the state that is designated as nonattainment

for the 24

- hour PM 2.5 

## standard is a ten

- county portion of New York’s Consolidated

Metropolitan Sta tistical Area. 85 

## Since all shale development activities will occur in the

central part of the state, outside of this ten

- county portion of New York's Consolidated

Metropolitan Statistical Area, the air quality impact from that activity is not likely to

cause a significant impact upon New York’s particulate matter attainment status.

Nonroad diesel engines such as those used in drilling and HVHF activities are often

exempt from air permitting to include dispersion modeling requirements since they

qualify as portable or non

- stationary sources. However, this does not mean that these

sources are unregulated. On November 15, 1990, the Clean Air Act Amendments of

1990 (CAAA) were enacted in order to broaden and strengthen the CAA. While the

CAA had long spec ifically authorized EPA regulation of on

- highway vehicle and engine

emissions, the 1990 amendments extended EPA's authority to regulate nonroad vehicles

and engines. 86 

## Specifically, S ection 213 directed EPA to:

 Conduct a study of emissions from nonroad engines and vehicles;

 Determine whether emissions of CO, NO X 

## , and VOCs from nonroad engines and

vehicles are significant contributors to ozone or CO in more than one area which

has failed to attain the NAAQS for o zone or CO; and

 Regulate those categories or classes of new nonroad engines and vehicles that

contribute to such air pollution if nonroad emissions are determined to be

significant.

EPA may also regulate other emissions ( e.g. , PM, hydrocarbons [HC], smok e, etc.) from

new nonroad engines or vehicles if the y determine that they contribute to air pollution

which may reasonably be anticipated to endanger public health or welfare. Based upon

the EPA’s nonroad emissions study, new regulations were developed co ntaining

standards to address these emissions. 87 

## In June 1994, EPA adopted the first set of

emissions standards (Tier 1) for all new nonroad diesel engines greater than 37 kilowatts

( 50 horsepower [ hp ])

. The Tier 1 standards were phased in for different e ngine sizes

between 1996 and 2000, reducing NO

x 

## emissions from these engines by 30 percent.

In 1998, EPA adopted more stringent emission standards (Tier 2 and 3) for NO

x 

## , HC, and

PM from new nonroad diesel engines. 88 

## This program included the first set of standards

for nonroad diesel engines less than 37 kW (phasing in between 1999 and 2000). It also

phased in more stringent ( Tier 2 ) emission standards from 2001 to 2006 for all engine

sizes and add ed yet more stringent ( Tier 3 ) standards for engines between 37 and 560 kW

(50 and 750 hp) from 2006 to 2008.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 43 On May 10, 2004, EPA finalized their Clean Air Nonroad Diesel Rule to reduce

emissions from non

- road diesel engines by integrating engine and fuel controls as a

system to gain the greatest emission reductions. 89 

## The new engine (Tier 4) standards will

reduce PM and NO

x 

## emissions by 90 percent. Standards for new engines will be phased

in starting with the smallest engines in 2008 until all but the very largest diesel engines

meet both NO

x 

## and PM standards in 2014.

Nonroad diesel engines such as those used in drilling and HVHF activities are often

exempt from air permitting to include dispersion modeling requirements since they

qualify as portable or non

- stationary sources. Howeve r , the EPA has regulated these

sources through other regulatory provisions. Since 1990, the EPA has passed

increasingly more stringent rules (Tier standards) that target emission reductions from

nonroad engines especially for NO

x 

## and particulate emissions . As a result of the EPA’s

action, air emissions from these engines are now heavily regulated and face new CAAA

deadlines that will force additional emissions reductions. As new engines are phased into

the drilling and completion process, the emissions a ssociated with drilling will decrease

over time, which is consistent with a regulatory approach taken by the EPA implementing

the CAA relative to the sources.

Since industry’s modeled 24

- hour PM 2.5 

## impacts still exceeded the standard when the

DEC’s backgro und number of 30 μg/m 3 

## was used, IOGA is providing further comment

on some potential mitigation measures mentioned in the dSGEIS . These include some

new as well as previously identified measures.

 Clean fuel options

- use of ULSD fuel.

 Use of Tier 4 diesel engines.

 Use of Tier 2 or Tier 3 diesel engines equipped with either a diesel particulate

filter (DPF) or a diesel oxidation catalyst (DOC).

 Use of Tier 2 or Tier 3 diesel engines for which the manufacturer or operator can

demonstrate by stack testing tha t PM 2.5 

## emissions at 90 % load are less than 0.10

g/bhp

- hr for that model of engine.

 Diesel engine fleet turnover.

 Raise the stack height on the drill rig engines.

 Siting of all HVHF engines such that no engine stack is within 150 feet from the

edge of the drilling pad.

The following paragraphs discuss these options. It is expected that ULSD will be widely

available for use by sources such as the drilling and HVHF engines as a clean fuel option.

Other clean fuel options for diesel equipment may include bi

- fuels and natural gas

- firing

engines

. Industry is experimenting with the use of bi

- fuel diesel engines for drilling rigs.

This technology can provide significant reduc tions in PM emissions. In addition,

Caterpillar is developing a gas

- fired engine package. I nformation was not available from

the manufacturers on the time frame for availability of these options.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 44 Tier 4 engines are not available at the time this response was prepared . Manufacturers

are expected to begin phasing in production and packaging of Tier 4 engines in 2011.

However, it is expected to take several years before Tier 4 diesel engines are readily

available. Early indications from engine manufacture rs are that these engines will cost

50 % more than present Tier 3 engine technology.

Use of Tier 2 or Tier 3 diesel engines for which the manufacturer or operator can

demonstrate through stack testing (or manufacturer’s certification) that PM 2.5 

## emissions

at 90 % load are less than 0.10 g/bhp

- hr for that model of engine. Again, information was

not available from the manufacturers on the time frame for availability of this option. A

survey of nine drilling rig s (three engines per rig, total of 27 engines ) currently operating

in the Marcellus revealed that 3.5% of the engines were uncertified (Tier 0), 25% were

Tier 1, 49% were Tier 2, and 22% were Tier 3. 90



## As engines from the diesel fleet undergo turnover, newer engines will be equipped and

oper ated with controls such as those listed above and will be subject to more stringent

regulations intended to reduce PM emissions. The Dallas

- Fort Worth (DFW) SIP

allocates 4.86 tons per day ( tpd ) of VOC and 20.78 tpd of NO

x 

## reductions due to fleet

turnover

. 91 

## Although unquantified, the control measures relied upon in the DFW area SIP

also provide reductions in PM as a side benefit.

The last two mitigation measures (raising stack height and siting HVHF engines at least

150 feet from the edge of the drillin g pad) listed above are available options that

operators may rely upon as needed.

In addition, in the unlikely event that operators become subject to modeling as part of the

air permitting process , those operators will consider the above refinements as well as :

 U sing 5 years of meteorological data for modeling parameters instead of a single

year

.

 U s ing a more representative background concentration based upon the

predominantly rural setting of the Marcellus Shale o perating area.

The use of one or more of the above modeling refinements and mitigation measures

should meet the criterion of minimizing PM impacts to the maximum extent practicable

and will provide absolute assurance that , assuming their applicability, th e National

Ambient Air Quality Standards ( NAAQS ) for PM 2.5 

## would not be exceeded from drilling

and completion activities.

8. Industry comments do not describe any mitigation measures to eliminate the

potential projected exceedences of certain thresholds for t oxic pollutants due to

emissions at the flowback impoundments, short of calling the limitation of public

access by fencing unwarranted. Most of the comments relate to questioning the

modeling assumptions and approach through certain calculations and claims

. Industry should identify specific mitigation measures it can impose in practice to

eliminate the impoundment emissions resulting in threshold exceedences, including

the elimination or reduction of specific additive constituents when flowback water

will b e stored in an uncovered impoundment.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 45 IOGA Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

As noted previously in the response to ―Air Impacts #2

, ‖ it is the opinion of IOGA

members that the flo wback of HVHF

- produced water to impoundments or open pits will

not occur on a routine basis; produced water returned during the flowback process will be

stored in tanks. Therefore, the use of impoundments for the management of produced

water should be rem oved from the SGEIS as a standard practice. Industry recognizes that

any future use of an impoundment ( well pad dedicated or centralized) to manage

produced water would likely require project

- specific environmental review and approval,

potentially up to a nd including preparation of an independent, project

- specific

Environmental Impact Statement ( EIS ) . Such a scenario is not expected to adversely

impact development of the Marcellus Shale and IOGA would not object

.

Therefore, in answer to this information request, mitigation measures aimed at reducing

or eliminating toxic pollutant emissions from produced water impoundments are not

necessary given industry’s election not to use open pits or impoundments for managing

produced wa ter. Their applicability and use would be limited to site

- specific review and

approval beyond the scope of the SGEIS.

9. In order to assess the potential effects of the regional emissions of Ozone precursors

( NOx and VOC) on the Ozone nonattainment area SIPs , industry is requested to

present an estimate of the total number of wells it expects will be drilled and

completed annually in the Marcellus Shale in NY and the corresponding annual

emissions of NOx and VOCs. These estimates should include both stationar y and

mobile sources. Also, IOGA should provide the referenced "mitigation measures"

used for the Barnett Shale in the Dallas Fort

- Worth nonattainment area.

IOGA Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

Estimated Ozone Impacts: To estimate the potential impacts from the development of

Marcellus Shale upon New York’s regional ozone status, a comparison of annual NO

x 

## and VOC emissions from development activities to an existing baseline of t hese

emissions is used. 92 

## Thus, for the year of estimated peak development (2,2 1 6 horizontal

and 246 vertical wells), the following estimation methodology is provided for average

annual NO

x 

## emissions per horizontal well and then calculated for all wells during peak

annual operations:

 Drilling Emissions = 12.6 lb/hr 93 

## x 24 hr/day x 25 days = 7,560 lb (single well) x

2,2 1 6 wells/yr x tons/2,000 lb = 8, 376 tpy.

 Completion Emissions (frac) = 60 lb/hr 94 

## x 6 hrs/frac x 8 fracs/well = 2880

lb/well x 2,216 wells/yr x tons/2,000 lb = 3, 191 tpy.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 46  Completion Emissions (flare) = 34 lb/hr 95 

## x 72 hrs/well = 2,448 lb/well x 2,216

wells/yr x tons/2,000 lb = 2,7 12 tpy. Therefore, the total completion emissions

are 5,9 03 tpy.

 Product ion Emissions = 0.86 lb/hr 96 

## x 8,760 hr/yr = 7,533 lb/yr x 2,216 wells/yr x

tons/2,000 lb = 8,3 47 tpy.

 Therefore, the total annual NO

x 

## emissions estimate for all horizontal wells drilled

during a peak year = 22, 626 tpy.

In a similar manner, the NO

x 

## emissions for vertical wells:

 Drilling Emissions = 12.6 lb/hr x 24 hr/day x 11 days = 3,326 lb (single well) x

246 wells/yr x tons/2,000 lb = 409 tpy.

 Completion Emissions (frac) = 60 lb/hr x 6 hrs/frac x 1 frac/well = 360 lb/well x

246 wells /yr x tons/ 2,000 lb = 44 tpy.

 Completion Emissions (flare) = 34 lb/hr x 72 hrs/well = 2,448 lb/well x 246 wells

/yr x tons/2,000 lb = 301 tpy. Therefore, the total completion emissions are 345

tpy.

 Production Emissions = 0.86 lb/hr x 8,760 hr/yr = 7,534 lb/yr x 246 wells/yr x

tons/2,000 lb = 927 tpy.

 Therefore, the total annual NO

x 

## emissions estimate for all vertical wells drilled

during a peak year = 1,68 1 tpy.

Likewise, the average annual VOC emissions for horizonta l wells:

 Drilling Emissions = 0.53 lb/hr 97 

## x 24 hr/day x 25 days = 318 lb (single well) x

2,216 wells/yr x tons/2,000 lb = 35 2 tpy.

 Completion Emissions (frac) = 2.5 lb/hr 98 

## x 6 hrs/frac x 8 fracs/well = 120 lb/well

x 2,216 wells /yr x tons/2,000 lb = 13 3 tpy.

 Completion Emissions (flare & vent) = 4.9 lb/hr 99 

## x 72 hrs/well + 97 lb/hr x 3

hrs/well = 644 lb/well x 2,216 wells /yr x tons/2,000 lb = 71 3 tpy. Therefore, the

total completion emissions are 8 4 6 tpy.

 Production Emissions = 0.554 lb/hr 100 

## x 8,760 hr/yr = 4,853 lb/yr x 2,216 wells

/yr x tons/2,000 lb = 5, 377 tpy.

 Therefore, the total annual VOC emissions estimate for all horizontal wells drilled

during a peak year = 6, 57 5 tpy.

In a similar manner, the VOC emissions for vertical wells:

 Drilling Emissions = 0.53 lb/hr x 24 hr/day x 11 days = 140 lb (single well) x 246

wells/yr x tons/2,000 lb = 17 tpy.

 Completion Emissions (frac) = 2.5 lb/hr x 6 hrs/frac x 1 frac/well = 15 lb/well x

246 wells /yr x tons/2,000 lb = 2 tpy.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 47  Completion Emis sions (flare & vent) = 4.9 lb/hr x 72 hrs/well + 97 lb/hr x 3

hrs/well = 644 lb/well x 246 wells/yr x tons/2,000 lb = 79 tpy. Therefore, the

total completion emissions are 81 tpy.

 Production Emissions = 0.554 lb/hr x 8,760 hr/yr = 4,853 lb/yr x 246 wells/ yr x

tons/2,000 lb = 597 tpy.

 Therefore, the total annual VOC emissions estimate for all vertical wells drilled

during a peak year = 69 5 tpy.

The combined results are provided in Exhibit 7

.

Exhibit 7

Ozone Precursor Emission Estimates (tpy) for the Year of Peak Development

Drilling Completion Production Totals

Horizontal

- NO

x 

### 8, 376 5,9 0 3 8,3 47 22, 626

Vertical

- NO

x 

### 409 345 927 1,68 1

Total NO

x 

### 8, 785 6,2 48 9, 274 24, 30 7

Horizontal

- VOC 35 2 8 4 6 5, 377 6, 57 5

Vertical

- VOC 17 81 597 695

Total VOC 3 69 9 2 7 5,9 74 7, 27 0



## According to the 2002 baseline EI year used in New York’s 2007 SIP demonstration for

the 8

- h ou r ozone standard, a total of 659,186 tpy of NO

x 

## emissions were estimated

statewide. 101 

## Therefore, the impact from the development of the Marcellus at worst

- case

peak would add 3.7 % to existing NO

x 

## emissions.

From the same baseline data, a total of 1,352,076 tpy of VOC emissions were estimated

statewide. Therefore, the total impact of 7, 27 0 tpy from the development of the

Marcellus would add 0.54 % (one half of one percent) to existing VOC emissions

.

Assumptions/considerations used in these calculations include:

 Average emission rates for dry gas are used for every well for every phase of

de velopment.

 Maximum number of wells (both horizontal and vertical) in any year.

 No credit is taken for any mitigation measures, permit emissions controls, or state

and federal regulatory requirements that are expected to reduce these estimates.

 Drilling emi ssions are conservatively estimated at 25 days for the horizontal wells

(11 days for vertical well drilling).

 Heater emissions are included year

- round in the production estimates; however,

they would be seasonal and would take place during the non

- ozone se ason.

 Off

- pad compressor emissions are included in the production estimates; however,

some well pads may not require a compressor.

 No credit is taken for the rolling nature of development (i.e., that all wells will not

be drilled or completed at the same t ime, on the same pad) and the resulting

impact on air emissions.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 48  No credit is taken for reduced emission completions (green completions) which

would significantly reduce flaring and hence related NO

x 

## and VOC emissions.

Because the PSC currently requires an Article VII application for pipeline

construction be submitted after well completion, and because green completions

require a pipeline to be available to receive gas during the flowback process, it is

not currently possible to complete wells using the r educed emissions approach in

New York. IOGA understands that the 2009 State Energy Plan includes a

recommendation to coordinate drilling and pipeline requirements so that green

completions may be possible. 102 

## Therefore, early in the play’s development,

green completions are not expected to be the standard; however, as the play

evolves it is expected that green completions can become more commonplace. At

the very least, once the initial wells on a pad are compl eted and connected to the

gathering line it is anticipated that subsequent wells could be completed using a

reduced emissions approach.

Comparison to Barnett Shale:

One excellent means of considering the future ozone impact of developing th e Marcellus

Shale gas field in New York is to consider the Barnett Shale gas field in North Texas. In

Exhibit 8 below

, the number of wells drilled in the DFW nine

- county ozone non

attainment area is shown along with annual ozone readings in the same area for the

period from 2000 to 2008. 103 

## As shown, the number of wells grew from less than 100 to

Exhibit 8

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 49 over 8,000 during this period while the area’s ozone levels have dropped from 102 parts

per billion ( ppb ) to 91 ppb.

There are several similarities in these two areas that lend value to this comparison:

 Both areas of the country are currently treated as ozone moderate non

- attainment

areas for SIP pu r

poses

.

 Development activities for the Barnett Shale relied upon many of the same HVHF

practices that are planned for the Marcellus Shale area.

 The Barnett’s rate of development (roughly 1,000 new wells per year) compares

favorably with the rate planned for the Marcellus in New York.

Overall, comparing these two shale gas plays offers a reasonable level of confidence that

the State of New York can reap the economic benefits of developing shale gas in the state

while successfully regulating their regional ozone issue

.

10. Please provide any available hydrogen sulfide testing data for the Marc ellus in the

northern tier of Pennsylvania. Please indicate the test duration, the instrumentation

that was used, the monitoring frequency and the detection level of the instrum ent.

IOGA Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

Mudloggers have detected minor Hydrogen sulfide ( H 2 

## S ) with their sniffer equipment on

Marcellus wells in Pennsylvania; however, they wer e unable to substantiate this

observation. In New York, there is some potential for H 2 

## S associated with the Trenton

Black River section. Marcellus drilling rigs will be equipped with H 2 

## S detection

equipment.

11. EPA's promulgated new 1

- hour National Ambien t Air Quality Standard for NO2

became effective on April 12, 2010, and applied to all subsequent permitting

activities without final permits. It also applies to all SEQRA type assessments

compatible in scope to EPA's National Environmental Policy Act (NEPA ) projects.

Preliminary assessment of 1

- hour NO2 impacts from the sources modeled in the

draft SGEIS, based on Tables 8 and 15 of ALL Consulting’s 8/26/09 air emissions

data report, indicates the potential for significant exceedences of the standard due to

the emissions from the drilling and hydraulic fracturing engines.

In order to address these projections, industry is asked to provide descriptions of

the NOx control and mitigation measures it has used previously, including a

discussion of the use of Non

- or Selective Catalytic Reduction (NSCR or SCR)

systems, similar to their use for the compressors described in Tables 18 and 24 of

the 8/26/09 ALL report in order to meet regulatory emissions standards. The

operational percentage and geographical areas in which SCR has been used for

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 50 control, especially in Ozone nonattainm ent areas, and any practical limitations

should also be discussed.

IOGA Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

IOGA members understand that compliance demonstrations for a new or revise d NAAQS

is required for air permitting of Prevention of Significant Deteri or ation (PSD) major

sources, assuming EPA has developed appropriate air models and modeling protocols.

However, in the case of the new short

- term n itrogen dioxide ( NO 2 

## ) standard, EP A has not

yet addressed those issues. For non

- PSD sources, Section 110(a)(1) of the Clean Air Act

(CAA) states

, ―Each State shall, after reasonable notice and public hearings [ emphasis

added], adopt and submit to the Administrator, within 3 years (or such shorter period as

the Administrator may prescribe) after the promulgation of a national primary ambient air

quality standard (or any revisions thereof) under Section 109 for any air pollutant, a plan

which provides for implementation, maintenance, and enf orcement of such primary

standard in each air quality control region (or portion thereof) within each State.‖ 104



## IOGA members understand that when EPA sets a NAAQS, the Administrator cannot

consider cost/benefit, but must only look at protection of health a nd welfare. However,

this must be considered in the SIP development process, which has yet to be prepared by

the DEC and subsequently reviewed by EPA as it relates to the new NAAQS. Bypassing

this very important SIP process will result in mandatory and a rbitrary NO

x 

## controls on

non

- PSD major sources without any public review or input on the cost/benefit of such

controls.

The new 1

- hour standard for NO 2 

## presents several challenges when faced with

demonstrating compliance through the use of dispersion model ing. In announcing the

new standard, EPA failed to provide

 an associated significance level

,

 an appropriate NO

x 

## to NO 2 

## conversion ratio

, a 

## and

 a prescribed and viable methodology for determining design values.

Without a significan ce level, the radius of impact due to proposed construction or

modification activities cannot be correctly determined. The use of an accurate nitrogen

conversion ratio is critical to determining modeled impacts. The present methodologies

to determine a design value based upon the 3

- year average of the 98 th 

## percentile of the

annual distribution of daily maximum 1

- hour concentrations can result in enormous data

files that require vast storage capacity and may exceed the capacity of many servers. 105



## Perhaps the most important fail ing by EPA was the lack of guidance on an appropriate

NO

x 

## - to

- NO 2 

## conversion ratio for the new standard. As explained in the Colorado

Department of Public Health and Environment’s SCREEN3 Stationary Source Modeling

a 

### The EPA did issue a guidance memo in June of 2010 that recommended a 3

- tiered screening approach for

NO 2 

### conversion assessments.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 51 Guidance , typically most NO

x 

## emitted from combustion sources is emitted as Nitr i c

oxide ( NO )

. 106 

## A California Air Resources Board study examined emissions from

several reciprocating engines and various fired heaters and boilers. 107 

## That report

concluded

, ―NO

x 

## emissions from sources without NO

x 

## control were almost entirely

NO. ‖ 108 

## Sources with NO

x 

## control devices had lower NO

x 

## emissions concentrations, with

an NO 2 

## proportion of up to 15 %

. 109 

## It is only after photochemical reactions with ozone in

the atmosphere occur that a greater percentage of th e NO is converted to NO 2

, 

## depending

on ambient ozone concentrations and time for reaction. 110 

## For the annual NO 2 

## NAAQS,

EPA assumes that 75 % of the NO is converted to NO 2 

## . For the shorter 1

- h ou r averaging

period, there is very little time for NO to be conv erted to NO 2 

## ; therefore, a conservative

assumption of 10 % to 15 % NO 2 

## would be appropriate. In June 2010, the EPA issued a

guidance memo that recommended the use of the same three

- tiered screening approach

previously used for nitrogen conversion assessment s of the annual NO 2 

## standard. 111



## Although any guidance that assists both regulatory agencies and the regulated community

in dealing with this new standard is a step in the right direction, EPA’s new memo failed

to provide the detailed information required t o address the atmospheric chemistry

involved in the short

- term interactions.

Reliance on previous NO 2 

## mitigation measures that were specifically designed for longer

averaging periods may or may not be suitable for applicability to the new 1

- hour

standard. Without further study of the atmospheric chemistry involved in the conversion

process and the subsequent establishment of published guidance based upon the findings

of that study, a reliable compliance methodology cannot be determined.

The result of these deficiencies is that both industry and regulatory agencies are left

facing a standard without a consistent, reliable means to demonstrate compliance (or non

compliance) with the standard. The EPA’s Guideline on Air Quality Models ’ (40 CFR

Part 51, Append ix W) stated purpose is to provide guidelines that promote consistency in

the use of modeling within the air quality management process. 112 

## EPA’s modeling

guideline must be updated and accompanied by public review and comment to allow a

reasonably accurate compliance demonstration for the 1

- hour standard using dispersion

models such as AERMOD. In response to these NO 2 

## concerns as well as related

concerns for other air pollutants, the Air & Waste Management Association’s AB

- 3

Meteorology Committee submitted a letter to EPA that provided a detailed review of the

issues raised by the guidance memos posted by the EPA as well as a set of

recommendations on the implementation of modeling procedures needed to address the

new NAAQS for NO 2



## . 113



## The new standard is caus ing implementation problems across the country. IOGA

members are working to address these NO 2 

## issues, but initial modeling results indicate

that compliance demonstrations will be difficult. This applies to all manner of NO 2 

## emissions including many encountered in everyday life, not just in the development of

natural gas resources. One example of these difficulties is the proposed installation of a

new diesel emergency generator at a hospital or prison which may not be a llowable since

its modeled NO 2 

## emissions would likely exceed the new standard. Another example is a

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 52 diesel

- fired bulldozer ; after one hour on a construction site

, it would likely not meet the

standard.

Finally, it would be futile for industry to recommend or investigate mitigation m easures

designed to attain the standard without any assurance of a correct compliance

demonstration methodology. Iowa, Arkansas, and New Mexico are examples of states

that are not requiring such compliance demonstrations at th e time of this response

. 114



## Th e SGEIS should state that all proposed construction and modification projects

including those involving a potential increase of nitrogen compounds from stationary

sources will be subject to DEC’s SIP restrictions as well as the permitting regulations

inten ded to assure compliance with the new standard. EPA’s guidance for compliance

demonstrations is inadequate to address this new standard; likewise, it is not possible for

a regulatory agency to demonstrate non

- compliance. To suggest mitigation measures

ap propriate to ensure compliance at this point would be impossible because the necessity

or benefit of such mitigation cannot yet be defined. In order to resolve this conundrum,

IOGA strongly recommends a NO

- to

- NO 2 

## conversion factor of not greater than 10 % to

15 % NO 2 

## and that the DEC consider how it will implement this new standard for minor

and temporary nonroad mobile sources in a realistic manner that is still protective of

human health

.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 53 Alternatives

1. Describe the specific function in hydraulic fracturing additives of the following

chemicals that could be present in concentrations that would exceed Class GA

groundwater standards, and discuss the availability of less potentially hazardous

alternatives or the status of any efforts to develop alternatives: acrylamide;

benzene; toluene; xylene; ethylbenzene; petroleum distillates; kerosene; ethylene

oxide; dibromoacetonitrile; 2;2

- Dibromo

- 3 nitrilopropionamide; ethlyene glycol.

IOGA Response

The following re sponse is subject to all of the caveats mentioned in the Preamble to this

document.

It is difficult, if not impossible, to anticipate whether or not a particular chemical would

be present in a concentration exceeding a specific groundwater standard prior t o that

chemical ever coming in contact with groundwater. Although chemicals will be handled

on well sites, for those chemicals to reach groundwater would first require a release event

to occur. Operators and service companies have safety precautions in p lace to prevent

chemical releases and DEC has regulations for well construction which are designed to

prevent releases to shallow groundwater as well as other water

- bearing strata. More

specifically, a release is unlikely to occur for the following reason s:

 All chemicals present on

- site at ―stock strength‖ (undiluted before blending for

HVHF) are maintained in containers. These containers meet U

. S

. Department of

Transportation (DOT) standards for the transportation of hazardous materials and

are designed to preclude the possibility of accidental release.

 The chemicals are mixed immediately prior to being pumped into the subsurface

as part of the HVHF stimulation job. Mixing is done in a controlled mixing

hopper, where wet chemicals are piped into the hopp er by rubber hoses, and dry

chemicals are mixed through a funnel which feeds the dry chemical into the

fluids. Additional steps are taken to avoid spills

, including the use of bermed

plastic containers around any wet chemicals to capture any spills or acc idental

discharges to the well pad.

 When pumped down hole, the HVHF fluids are contained within multiple layers

of protective casing and cement, including the conductor, surface, and deep

casings which provide redundant protections. This engineered syst em prevents

drilling fluids and HVHF fluids from coming into contact with both shallow and

deep formations. The casing system for each well is also designed to prevent

fluids from migrating up the wellbore to shallow groundwater.

 In the subsurface, ther e are typically thousands of feet of impermeable strata

between the target formation and shallow, potable groundwater. 115

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 54 Moreover, even assuming that a release could occur, any constituent concentration in

groundwater resulting from a release cannot reasona bly be foreseen because it is

impossible to know in advance critical contributing factors including:

 How the release would occur.

 Whether or not the chemical would be released in a liquid or solid form and what

its mobility would be in soil and, hence, its ability to impact groundwater.

 The volume of the chemical that would be released.

 Whether the chemical would be released at a ―stock strength‖ or blended (diluted

HVHF fluid) concentration. Each chemical is substantially diluted in the final

HVHF chemica l blend (see response to Item Hydraulic Fracturing Additives 1 for

examples of weight percent volumes of additives).

 The amount of the released chemical that would be absorbed by soil before

reaching groundwater.

 The extent of dilution that would occur o nce such a release comes into contact

with shallow groundwater.

It is for these reasons that IOGA believes it is impossible to predict with any degree of

certainty whether or not a constituent concentration exceeding a groundwater standard

would be prese nt on

- site. Just because a chemical is present on

- site, that does not mean

that it will be released; just because a chemical is present at a given concentration that

does not mean that it would be present in a groundwater aquifer at that same

concentratio n. Therefore, a meaningful comparison of stock chemical concentrations

inside of DOT

- approved containers to potable groundwater standards cannot be made and

it would be inappropriate to do so.

Furthermore, not all well sites are constructed above strata b earing Class GA

groundwater. Class GA groundwater is defined as fresh groundwater that is ―a source of

potable water supply.‖ 116 

## Potable water is defined as ―those fresh waters usable for

drinking water, culinary or food processing purposes.‖ 117 

## This does n ot describe all

groundwaters of the state but only the highest quality groundwater . Shallow groundwater

is often not suitable for drinking water even though it may not be saline water . For

instance, it is not uncommon for shallow groundwater to be highly turbid, rendering it

unsuitable as a drinking water supply. It is likely then that n ot all well pads will be

underlain by Class GA groundwater.

Furthermore, water quality typically decreases with depth; deeper waters tend to be older

and have been subj ect to the expanse of geologic time to interact with minerals naturally

present in the formation or other waters that may have migrated through the formation.

As such, it is highly unlikely that connate formation waters in shale gas target formations

woul d be classifiable as Class GA groundwater because their inherent salinity exceeds

the definition of fresh water (Class GSB saline groundwater is defined as having chloride

>1,000 mg/L or TDS >2,000 mg/L). Formation water quality typically observed in

prod uced waters from the Marcellus Shale have TDS concentrations greater than 50,000

mg/L (see response to Item Flowback Water Characterization 1); therefore, by New

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 55 York’s definition, these connate formation waters are unsuitable for use as drinking

water. C onsequently, implying that Class GA groundwater standards for constituents of

concern would be applicable to the connate water of the target formation is also

inappropriate.

In sum, if a spill were to occur on a well site, if there were no containment meas ures, and

if no emergency response measures were taken to control such a spill, it is conceivable

that some chemicals could ultimately percolate through the overlying soils and reach

groundwater; however, the concentration of a chemical after such a releas e would still not

be known without investigation. To presume in advance that a regulatory exceedance

would result is unfounded. A regulatory exceedance would require failure of the

containers used to transport the material and/or the secondary containmen t required to

contain surface spills and/or a failure of the engineered cementing and casing system, all

of which are designed to prevent an unwanted release of these materials.

To address the remainder of the question, DEC has presented a list of specifi c compounds

they would like to understand the function of and if any alternative, less hazardous

compounds could be used in their place. A discussion of each compound follows:

 Acrylamide (79

- 06

- 1):

o First, it is important to understand that the shale gas industry does not use

acrylamide monomers (i.e.

, acrylamide). 118 

## Groundwater standards for

acrylamide are not applicable to the polyacrylamides. The dSGEIS

identified multiple acrylamide polymers (i.e

. , polyacrylamide) as being

used in HVHF fluids primarily as friction reducers. 119



## o Alternative: The shale gas industry is currently evaluating polyacrylamide

friction reducers that utilize either food

- grade mineral oil or salt brine as

the carrier solutio n.

 Benzene (71

- 43

- 2); toluene (108

- 88

- 3); xylene (1330

- 20

- 7); ethylbenzene (100

-

41

- 4); petroleum distillates (64742

- 65

- 0) ; kerosene (8008

- 20

- 6):

o These have all been identified as being components of friction reducers,

acid corrosion inhibitors, gelling ag ents, and paraffin dispersants. 120



## o Benzene, toluene, ethylbenzene, and xylene are not present as independent

additives, but as constituents of kerosene. 121



## o Alternative: Mineral oil is used as a less hazardous alternative to

kerosene. The shale gas industr y is currently evaluating the use of food

grade mineral oil. 122



##  Dibromoacetonitrile (3252

- 43

- 5) and 2,2

- Dibromo

- 3 nitrilopropionamide (10222

-

01

- 2):

o These are present in biocides used in HVHF fluids to kill bacteria present

downhole. Such bacteria create production problems by clogging pore

spaces in the reservoir as well as fouling pipes and associated production

equipment. In addition to fouling, some bacteria generate acidic

conditions that can result in increased corrosion of met al piping and

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 56 equipment if bacterial growth is not controlled. As such operators use

chemicals such as dibromoacetonitrile (3252

- 43

- 5); 2,2

- Dibromo

- 3

nitrilopropionamide (10222

- 01

- 2) to control the growth of bacteria and

prevent the damage those bacteria can cause. 123



## o Alternative: Glutaraldehyde (111

- 30

- 8) and tetrakis (hydroxymethyl)

phosphonium sulfate (THPS; 55566

- 30

- 8) are used as alternatives to

dibromoacetonitrile and 2,2

- Dibromo

- 3 nitrilopropionamide.

Glutaraldehyde is a sterilant commonly used in t he healthcare industry for

multiple purposes, such as for steriliz ing instruments; it has been in use

since the 1960s as a safer alternative to formaldehyde. THPS is a biocide

particularly suited to sulfate

- reducing bacteria which can cause corrosion

of i ron; it is also used as an epoxy curing agent and as a flame retardant,

particularly for cotton fabrics. 124



##  Ethlyene glycol (107

- 21

- 1) and Ethylene oxide (75

- 21

- 8):

o Ehylene glycol is used in corrosion inhibitors, scale inhibitors, clay and

iron control age nts, and gelling agents and breakers. It is a desiccant and

is commonly used to remove water from natural gas. 125

, 126 

## Ethylene Oxide

is a precursor to Ethylene Glycol and is also a steril a nt which may be

present in some bactericides. 127



## o Alternative: The shale gas industry is currently evaluating polyaspartic

acid (25608

- 40

- 6) as an alternative scale inhibitor. Polyaspartic acid is a

manufactured amino polycarboxylic acid that can function as a scale

inhibitor, corrosion inhibitor, dispersant, chelati on agent, and water

absorber. According to the manufacturer, polyaspartic acid is non

- toxic,

biodegradable, and non

- polluting. 128



## 2. Provide additional information regarding the use of ultraviolet light as an

alternative for controlling bacteria growth. Specif ically, has this technology been

used in shale wells, particularly in the Marcellus? How effective is the technology at

this time? What is the process for using this technology and what equipment is

necessary?

IOGA Response

The following response is subjec t to all of the caveats mentioned in the Preamble to this

document.

Practicality of Using the Technology

In the shale gas industry, ultraviolet ( UV ) light has recently been introduced as a

treatment option to help reduce the volume of biocide required to k ill or inhibit bacterial

growth in HVHF fluids. Although the use of biocides is still necessary when UV

treatment is used on make

- up waters for microbe treatment, the volume of biocides

needed are greatly reduced. 129 

## This in turn reduces residual biocides in produced water

and thus the degree of treatment such wastewater might require. The use of UV light has

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 57 been shown to reduce bacteria comparable to the efficiency of biocides in a cost effective

manner 130 

## and the equipment used is usually small (footprint ) and can be integrated with

most production operations. 131



## Effectiveness and Process

The effectiveness of UV light on water treatment is dependent on the rate of fluid flow,

intensity of the UV light source, and the transmittance level of the fluid ( e.g

., the ability

to allow light to completely pass through). To achieve a level of effectiveness and

success, the water needs to be irradiated at an intensity of 110 mW/m 2 

## with 254 nm light

for one second 132 

## and a transmittance rate of at least 50% at 80 barrels per minute

(bpm). 133



## Halliburton recently applied UV light technology in the Haynesville Shale to treat HVHF

fluids for horizontal wells. Water treatment rates reached up to 120 bpm with

disinfection quality equal to or better than the use of biocides. 134 

## Volumes in the range of

3.4 to 3.7 million gallons of water were treated at an average rate of 80 bpm and initial

concentrations of bacteria (1

- 10 million per cubic centimeter) were reduced by 99%.

From this application, Halliburton indicated their UV sy stem is capable of reducing the

volume of biocides from 5,000 gallons to 500 gallons for a 5

- million gallon HVHF

stimulation. 135 

## The 500 gallons of biocide are still required to account for potential

bacterial recontamination from additives and proppant or from the downhole

environment.

Ecosphere Technologies (Ecosphere) has also applied UV water treatment as part of an

advanced oxidation water treatment process in the Fayetteville Shale. According to

Ecosphere, associated costs to treat water with their advanced oxidation process ranges

from $0.60 to $0.75 per barrel ( bbl ) ; the technology is capable of processing up to 10

bpm. 136



## Limitation s

The use of UV treatment typically takes place prior to adding chemicals to the make

- up

water since the presence of these additives in the water can alter the effectiveness of the

UV treatment process. UV light treatment has no residual kill capacity and as such, the

effectiveness of the treatment is limited to waters which can be passed through the

treatment system. Because there is no residual treatment effect from UV light treatment,

the application of low concentrations of biocides is still required for long

- term protection

from bacteria. Microbes or other organisms already present in the target formation are

not affected by the UV water treatment process, nor are those that may be present in the

additives or propants. The performance of UV light wa ter treatment on microbes in raw

water is affected by the concentration of microbes, suspended solids, soluble molecules,

and mineral concentrations. 137 

## Furthermore, certain molecules are capable of absorbing

UV, such as humic acids and iron, thus decreasin g the overall energy available to kill

microbes. Therefore, pre

- filtering to remove these components may be necessary prior to

treating the water using UV. The effectiveness of UV light treatment is not affected by

pH, temperature, alkalinity, or total i norganic carbon. 138 

## Because constituents in the

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 58 make

- up water may absorb the UV

, decreasing its effectiveness at killing bacteria, the

practice of reuse/recycling of produced water in subsequent fracture jobs may be

incompatible with the process unless the TDS, etc.

, are at low enough concentrations that

adsorption does not preclude sufficient transmittance for effective treatment.

Availability of the technology

UV light water treatment technology is currently being applied or tested on HVHF fluids

in the Haynesville Shale by Halliburton and within the Fayetteville Shale by Ecosphere.

Both of these systems are mounted on mobile units and therefore can be moved fr om one

location to another with relative ease.

The availability of UV technology equipment that is designed to treat HVHF fluids to

operators in the Marcellus Shale is uncertain , but, based on available information this

technology is likely not yet being applied in this play . Furthermore, the practical use of

UV light to treat make

- up water that is in whole or in part comprised of recycled

produced water ( i.e.

, water with typically higher TDS levels) has not been fully

evaluated. High TDS levels that ar e commonly found in produced water in the Marcellus

may reduce the effectiveness of UV treatment or require the use of larger UV units (or

more UV units) in order to achieve satisfactory treatment. Alternatively, treatment to

reduce TDS prior to UV treatm ent may be required. Therefore, the continued use of

traditional volumes of biocides to treat bacteria will likely be necessary for many wells in

the Marcellus Shale; at least until UV treatment options or other treatment alternatives

become more readily available.

Alternative Bacteria Reducing Water Technologies

Other alternative treatment technology options to reduce or kill bacteria in HVHF fluids

may include some advanced oxidation treatments such as ozonation or ultrasound. As

with UV, the advantage s of ozonation or ultrasound are that these technologies are

capable of removing bacteria without producing waste by

- products which require further

handling, and that treatment equipment is usually small (footprint)

. 139 

## Disadvantages

include expensive costs and complex chemistry (high COD in any reused/recycled

produced water can ―consume‖ much of the ozone intended for bacterial treatment

requiring the generation of excess ozone). If sufficient ozone is generated to overcome

COD and bacterial load at surfa ce, any excess ozone will provide some short

- term

residual treatment effect to address bacteria in the formation ; however, it has no long

term effect as it has a half

- life measured in minutes. 140 

## In addition, the availability of

these technologies in the Ma rcellus play may be limited.

Lastly, Schlumberger reportedly is developing a new biocide that would only persist a

few hours before becoming non

- toxic. 141 

## Although this new technology has not been

field evaluated, a potential reduction in toxicity of chemi cals returned to the surface in

produced water could help to ease environmental and regulatory concerns. However,

important treatment and operational considerations are unknown at the time this response

was prepared , including cost, effectiveness, residua l disinfection capabilities, availability,

etc.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 59 Casing and Cement

1. Please specify any API and/or ASTM standards, recommended practices and/or

testing requirements (e.g. API SPEC 5B, API RP 5A5, API RP 5C1) for surface,

intermediate and production casing implemented by industry for shale development

by high

- volume hydraulic fracturing in general, and for the Marcellus shale in the

northern tier of Pennsylvania in particular.

IOGA Response:

The following response is subject to all of the caveats mentioned i n the Preamble to this

document.

The industry adheres to American Petroleum Institute ( API ) Specification 5CT,

Specifications for Casing and Tubing (April 2002) and API Specification 5B,

Specification for Threading, Gauging, and Thread Inspection of Casing , Tubing, and Line

Pipe Threads (August 1996, with March 2004 Addendum) for surface, intermediate, and

production casing used for shale gas development. API

- recommended practices are also

followed for the use, transportation, storage, handling, and recond itioning of casing and

tubing (RP 5C1) and for inspection of casing and tubing (RP 5A5). Further, for high

volume hydraulically fractured wells, industry follows API Guidance Document HF1,

Hydraulic Fracturing Operations

— Well Construction and Integrity Gu idelines (October

2009), which incorporates the above specifications by reference.

In Pennsylvania, the industry follows the requirements set forth in 25 Pa. Code §78.84,

Casing Standards. These regulations are currently undergoing revision and industry w ill

comply with the proposed regulations if and when they become final. These proposed

regulations include the following requirements for casing:

 Casing must withstand the effects of tension, and prevent leaks, burst and collapse

during its installation , cementing, and subsequent drilling and producing

operations.

 Surface casing must be a string of new pipe with a pressure rating that is at least

20 % greater than the anticipated maximum pressure to which the surface casing

will be exposed.

 Used casing m ay be approved for use as surface, intermediate or production

casing but must be pressure tested after cementing and before continuation of

drilling. A passing pressure test is holding the anticipated maximum pressure to

which it will be exposed for 30 mi nutes with not more than a 10 % decrease in

pressure.

 Plain end casing must pass a pressure test (30 minutes with not more than a 10 %

decrease in pressure) and must be welded according to requirements set forth in

the regulation.

 

## Casing attached to a blow

- o ut preventer (BOP) must pass a pressure test holding

120 % of the highest expected working pressure for 30 minutes with not more than

a 10 % decrease in pressure.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 60 2. Please specify any API and/or ASTM standards, recommended practices and/or

testing requirement s (e.g. API RP 5A3) for casing thread compound used for

surface, intermediate and production casing jobs that are implemented by industry

for shale development by high

- volume hydraulic fracturing in general, and for the

Marcellus shale in the northern tier of Pennsylvania in particular.

IOGA Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

The industry follows API Recommended Practice 5A3, Recommended Practice on

Thread Compounds for Casing, Tubing, Lin e Pipe, and Drill Stem Elements (November

2009), which provides requirements, recommendations and methods for the testing of

thread compounds to evaluate the critical performance properties and physical and

chemical characteristics of thread com pounds under laboratory conditions.

3. Please specify any API and/or ASTM standards, recommended practices and/or

testing requirements (e.g. ASTM International C 150) for cement for surface,

intermedia te and production cement jobs that are implemented by industry for

shale development by high

- volume hydraulic fracturing in general, and for the

Marcellus shale in the northern tier of Pennsylvania in particular.

IOGA Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

The industry adheres to API Specification 10A, Specification for Cements and Materials

for Well Cementing (April 2002, with January 2005 Addendum). This specification

gives the physical and chemical requirements for various classes of we ll cements, as well

as procedures for physical testing. Further, for high volume hydraulically fractured

wells, industry follows API Guidance Document HF1, Hydraulic Fracturing

Operations

—

Well Construction and Integrity Guidelines (October 2009), which

in corporates the above specification by reference.

In Pennsylvania, the industry follows the requirements set forth in 25 Pa. Code §78.85,

Cement Standards. These regulations are currently undergoing revision and industry will

comply with the proposed regul ations if and when they become final. These proposed

regulations include the following requirements and performance standards for cement:

 The cement must meet or exceed American Society for Testing and Materials

( ASTM ) International C 150, Type I, II or I II Standard or ―API Specification 10

. ‖

 The cement must isolate the well from fresh water, contain the pressure from

drilling, completion, and production, protect the casing, resist degradation, and

prevent gas flow behind the casing.

 The operator must all ow the cement to set to a minimum compressive strength of

350 pounds per square inch ( psi ) at the casing seat.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 61  The casing may not be disturbed for a minimum of eight hours after cementing

operations are complete.

In addition, the cement job log must be ava ilable on the well site for inspection and must

be maintained by the operator for a minimum of five years.

4. Please specify any API and/or ASTM standards, recommended practices and/or

testing requirements (e.g. API SPEC 10D) for bow

- spring centralizers used for

surface, intermediate and production casing/cement jobs that are implemented by

industry for shale development by high

- volume hydraulic fracturing in general, and

for the Marcellus shale in the northern tier of Pennsylvania in particular.

IOGA Response :

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

The industry follows API s pecification 10D for Bow

- Spring Casing Centralizers (March

2002), which provides m inimum performance requirements and test proce dures for bow

spring casing centralizers.

5. Based on experience elsewhere, particularly in the Marcellus Shale in the northern

tier of Pennsylvania, please indicate whether industry proposes to use radial cement

bond logs, instead of conventional cement bond logs, on wells in New York that will

be subject to high

- volume hydraulic fracturing. Explain why or why not.

IOGA Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

Industry intends to use both co nventional cement bond logs (CBLs) and radial bond logs

as required by the particular situation.

 Standard CBLs employ a tool which is calibrated relative to a fluid of lesser

compressive strength, usually mud or water behind pipe. It can identify good or

poor bonding to the pipe and can identify the top of cement.

 The radial logging tools employ mul tiple receivers (usually eight) that enable the

viewing of the pipe bonding in a segmented or radial view and therefore

theoretically better enable the identification of possible cement channeling.

While the radial log provides more detail, it is not cle ar whether it is better at determining

the top of cement or cement quality, which are the characteristics needed to determine the

correct placement of the cement and whether a good bond between cement and casing has

been achieved.

Therefore, the radial too l is not appropriate in all cases; however, it may be useful in

specific situations. For example, if pressure testing of the cement indicates a potential

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 62 problem (i.e., poor cement

- to

- casing bond or cement

- to

- formation bond), the radial tool

may be used t o determine whether channeling is present and where it occurs.

6. The Department currently requires the running of centralizers on production casing

“at the base and at the top of the production interval if casing is run and extends

through that interval, with one additional centralizer every 300 feet of the cemented

interval.” Based on experience elsewhere, particularly in the Marcellus Shale in the

northern tier of Pennsylvania, please indicate whether industry proposes to run

centralizers more frequently in the lateral portion of HVHF wells, and why or why

not. Is there a standard interval used to centralize casing set in a lateral section of a

HVHF well? If “yes,” please provide the reference or study used to support the

identified standard interval.

IOG A Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

Centralizers are not used in the lateral portions of many HVHF shale gas wells. In a

horizontal hole, c entralizers serve principally to help ac hieve a uniform cement job. This

is important when preventing the flow of fluids and gases behind the casing and in

protecting fresh water aquifers. However, the horizontal portion of a shale gas well is

entirely within the production zone and does not intersect any other strata. Any gas flow

behind the pipe would be stopped by the cement and seals in the vertical portion of the

well. Therefore, the purpose of cement in the lateral portion of the well is to provide

structural support to the production casing in that interval rather than for zonal isolation

. This has proven to be sufficient in many cases. Producers are testing the use of

centralizers in the lateral portion of the well bore for their effect on drilling efficiency, so

far with mixed succ ess. Any increase in efficiency must be weighed against the cost of

using centralizers. Therefore, at the time this response was prepared , there is no

expectation of uniform practice in the use of centralizers in the horizontal leg of shale gas

wells.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 63 Centralized Facilities

1. IOGANY commented that centralized flowback impoundments would service an

area larger than the area described in the dSGEIS (four

- mile radius). State a size

range for the area that would be served by a centralized flowback impoundmen t

and describe the practical limitations, if any, on the distance between a well pad and

centralized impoundment.

2. IOGANY states that centralized flowback impoundments may be larger than 5

acres. Please state a proposed size range for centralized impoundmen ts.

3. IOGANY states “Therefore, CFIs are subject to multiple approvals. A streamlined

approval process should be established that allows coordination between the various

agencies and does not require duplicate permit applications and is commensurate

with the temporary nature of the facility (i.e. less than 6

- months).” Please elaborate

on the noted 6

- month time frame. Is IOGANY suggesting that a centralized

flowback impoundment would only have a life of 6 months? Please provide the

anticipated maximum duration of use for a centralized flowback water

impoundment.

4. Describe the proposed delivery of water to and from a centralized flowback water

impoundment. Based on experience to date, is delivery proposed to be by temporary

piplines, by truck, or a combination of both? For temporary pipelines, state the

anticipated maximum duration of use of any individual pipeline.

5. Describe the proposed day

- to

- day operation of a centralized impoundment,

including:

a. t he presence and activities of on

- site staff and

b. how leakage is monitored and managed.

IOGA Response to Centralized Facilities 1 through 5 :

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

As noted previously in the response to ―Air Impacts #2

, ‖ the flowback of HVHF

produced water to impoundments or open pits will not occur on a routine basis; produced

water returned during the flowback process will be stored in tanks . Therefore, the use of

produced water impoundments should be removed from the S GEIS as a standard

practice. Industry recognizes that any future use of an impoundment ( well pad dedicated

or centralized) to manage produced water would likely require project

- specific

environmental review and approval, potentially up to and including pr eparation of an

independent, project

- specific EIS. Such a scenario is not expected to adversely impact

development of the Marcellus Shale and IOGA would not object

.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 64 Therefore, responses to the information request ―Centralized Facilities 1

– 5‖

— size of

s ervice area, size of impoundment, duration of service, pipeline or truck deliveries, daily

operational activities, and leak monitoring

— are not necessary. Their applicability and

use would be limited to site

- specific review and approval beyond the scope of the SGEIS.

6. State a size range for an area that would be served by a centralized compressor

station and describe the practical limitations, if any, on the distance between a well

pad and a centralized compressor station.

IOGA Response:

C entralized compress or station s utilized for field gas gathering compression are not

standardized. A compressor engine’s size and location will be dependent on a number of

factors

, includ ing gas production volumes, type of compressor (reciprocating or

centrifugal), wellhead pressures, suction/discharge pressures, pressure drop during

transmission, age of the well or field ( i.e. , production decline) , diameter of the gathering

lines, proximity of the nearest available gas transmission line, and production facilities ’

gas use, e tc. Each of these factors

, and many more

, can vary considerably ove r the life of

a well or field. The sum total impact of these variables cannot be realistically predicted,

particularly in light of the fact that there has been no Marcellus Shale developm ent using

horizontal drilling and HVHF in New York. This makes such prediction completely

impractical. The following response is subject to all of the caveats mentioned in the

Preamble to this document.

In general, a gathering system and associated compr essor station must be engineered to

handle the gas from multiple well s and to accommodate future growth based upon

anticipated field development. Thus, natural gas gathering systems must balance

continual changes from the addition of new wells and the dep letion of old wells. Add to

this the fact that a compressor’s suitability and efficiency are largely driven by its intake

flow volume and discharge pressure. 142 

## These operating parameters have a reciprocal

relationship, meaning that for a given horsepower rating, as pressure requirements

increase, the volume of gas compressed decreases. These factors demonstrate the range

of complexity of designing a reasonable and economical gas gathering system and ha ve

led many producers to rely on skid

- mounted rental units that can be changed out as

needed to optimize gathering activities.

For the myriad reasons outlined above, the location and size of a centralized compressor

station is simply unpredictable with an y degree of certainty. S pecific estimation of the

number, location, spacing, and size of compressors is impossible at this stage of

developmental planning for the Marcellus Shale in New York

. Regardless, construction

and operation of any gas gathering st ation will be subject to DEC air permitting including

PSD/NSR review.

Caterpillar 3606 and Cat 3612 engines in the 1,200

- to 1,800

- horsepower (hp) range are

commonly used. If suitable electrical power is available, electric driven compressors of

approxi mately 3,300 hp may be used. To date, operators have not experienced

limitations on the compressor engine size other than those that would result in triggering

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 65 a more rigorous air permi t t ing threshold. The diameter of the gas gathering line or

pipeline a long with the frictional loss will dictate the system design. Also, well density

will have a bearing on this as the well density must be sufficient to support the economics

of the compression system.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 66 Drill Cuttings Characterization

1. Provide any availabl e Marcellus cuttings data and analysis, particularly for wells in

the northern tier of Pennsylvania, along with the following:

a. Identify the drilling mud composition and disposal method for each cuttings

sample analyzed.

IOGA Response:

The following respons e is subject to all of the caveats mentioned in the Preamble to this

document.

Exhibit 9 provides a summary of analytical results (low and high ranges) for drill cuttings

sampled in the northern tier counties of Pennsylvania

, including Bradford, Susquehanna,

T i oga, and Wyoming. Only those compounds/metals detected in at least one cuttings

sample analysis are tabulated (exception: the BTEX compounds were included); no other

compounds/metals analyzed for were detected by the l aboratory analyses. Note: 2

-

butanone (methyl ethyl ketone) is a potential lab contaminant and is not believed to be

present as a specific constituent of drilling mud.

Based on the available analytical data for drill cuttings from Marcellus Shale wells

(northern tier of Pennsylvania), total petroleum hydrocarbons (TPH) may be present in

drill cuttings from wells in which invert drilling muds are used. Minor concentrations of

aluminum, iron, and manganese may also be present; most likely from the clay mi nerals

that make up the mud or cuttings themselves. T oxicity C haracteristic Leachate Procedure

(TCLP) e xtraction analytical is specifically applicable to hazardous waste determination

for toxicity characteristic and is routinely required by landfills for waste characterization

screening prior to acceptance for disposal. The data indicates none of the detected TCLP

sample concentrations exceed their respective Resource Conservation and Recovery Act

(RCRA) levels; therefore, the drill cuttings are not defin able as a hazardous waste.

Furthermore, 6 NYCRR 371.1(e)(2)(v) excludes from the definition of hazardous waste

― drilling fluids, produced waters, and other wastes associated with the exploration,

development, or production of crude oil, natural gas or geot hermal energy‖.

Disposal methods for drill cuttings will vary based on certain factors such as the quality

of waste, regulatory requirements, distance to the landfill, and transportation and disposal

costs. Currently, operators primarily dispose of drill cuttings by landfill disposal.

However, some operators may also choose to manage drill cuttings via land farming.

Drill cuttings sent to landfills are typically used as daily cover material by the landfill. In

some cases (such as air drilling), drill cu ttings may also be stockpiled for future use as

road or well pad construction material if it is appropriate for such use. Also, cuttings

from air drilling may be disposed of on

- site.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 67 Exhibit 9

Analytical Data Summary for Drill Cuttings Sampled

in the northern tier of Pennsylvania

Constituent Low Result

(mg/L) High Result

(mg/L) RCRA Hazardous Waste

Characteristic Limits

(mg/L) Method

TOTALS data

2

- Butanone <0.020 <2.19 NA EPA 8260B

Benzene <0.020 <0.437 NA EPA 8260B

Ethylbenzene <0.437 < 0.437 NA EPA 8260B

Toluene < 0.437 < 0.437 NA EPA 8260B

Xylenes, total < 0.437 < 0.437 NA EPA 8260B

Naphthalene < 3.61 3.25 NA EPA 8270C

Pyridine <3.61 <3.61 NA EPA 8270C

TPH 5,330 202,000 NA EPA 8015D

Aluminum ND 4.55 NA EPA 6000/7000 Series

Iron ND 8.4 NA EPA 6000/7000 Series

Manganese ND 8.93 NA EPA 6000/7000 Series

TCLP data

2

- Butanone <0.200 2.19 200 TCLP

- EPA 8260B

Benzene < 0.020 <0.020 0.5 TCLP

- EPA 8260B

Pyrdine <0.020 0.87 5 TCLP

- EPA 8270C/D

Arsenic <0.009 0.4 5 TCLP

- EPA 6010B/C

Barium 0.28 9.07 100 TCLP

- EPA 6010B/C

Cadmium <0.0022 0.16 1 TCLP

- EPA 6010B/C

Chromium < 0.0060 <0.500 5 TCLP

- EPA 6010B/C

Copper <0.011 0.362 NA TCLP

- EPA 6010C

Lead <0.067 2.59 5 TCLP

- EPA 6010B/C

Mercury < 0.0008 < 0.0020 0.2 TCLP

- EPA 7470/A

Nickel < 0.10 0.79 NA TCLP

- EPA 6010C

Selenium < 0.022 < 0.500 1 TCLP

- EPA 6010B/C

Silver 0.0087 <0.100 5 TCLP

- EPA 6010B/C

Zinc 0.12 172 NA TCLP

- EPA 6010C

Note: NA = not applicable



## DEC verbally requested information regarding the potential for acid run

- off from drill

cuttings containing pyrite that are buried on

- site . For such a situation, t hree factors

require consideration: 1) the amount and quality of acid ic water resulting from contact

with the pyrite , which are influenced by the amount of water and ox ygen in the

environment; 2) the amount of alkaline water percolating through buried drill cuttings,

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 68 which can reduce the potential for oxidation and the acidity of the water generated; and

3) the hydrologic cycle regime of the subsurface area where the waste is buried.

When necessary, the implementation of preventative engineering controls or measures

can be used to minimize the potential for acid run

- off. Some of these measures include

 Qua ntify ing the amount pyrite prior to encapsulation and/or burying,

 Eliminat ing water and air contact with pyritic material,

 Covering waste material with an impermeable liner, and/or encapsulating the drill

cuttings using a polyurethane sealant, and

 Cover ing material with suitable alkaline overburden material.

If the material is to be disposed of off

- site, it must be hauled by a DEC permitted waste

transporter. Drill cuttings can also be buried and disposed of on

- site with approval by the

DEC, unless the cut tings are oil

- based. Drill cuttings from oil

- based drilling muds

require disposal in a permitted landfill. 143 

## In Pennsylvania , drill cuttings are considered a

RCRA exempt waste; however, drill cuttings waste is classified by State code (PA 25

287.1) as a r esidual waste. The PA DEP requires permitted landfills accepting residual

waste ( e.g., drill cuttings) to conduct analytical characterization of the residual waste

prior to accepting the waste material.

2. Describe whether or how cuttings derived from oil

- or polymer

- based mud drilling

will be separated from cuttings derived from air or fresh water mud drilling if used

at the same well, and whether different disposal methods would be proposed for

cuttings from the same well if more than one drilling fluid is used.

IOGA Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

In general, the segregation of wastes generated during exploration and production

activities is a common practice that is utilized by the o il and g as industry, as prudent

waste management decisions for non

- hazardous wastes are based on the inherent nature

of the waste. This is important to operators as it can often lead to reduce d waste

management costs and minimize the potential for ac cidents.

Current best management practices (BMPs) for waste management used by the industry

begin with identifying the inherent nature of the waste that allows for the protection of

human health and the environment. O perational decisions to segregate dr ill cuttings

generated with differing mud systems (i.e., air drilling , water

- based mud , oil

- based mud,

or polymer

- based mud drilling ) are based on the inherent nature of the waste and the

appropriate options for disposal or beneficial reuse in accordance with applicable state

regulations (relative to RCRA Subtitle D landfills).

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 69 Segregation is achieved by

 Air drilling cuttings are routinely placed in half

- tanks and are managed separately

from the remainder of the mud system.

 Drill cuttings from different portions of the borehole drilled with different mud

systems are placed in separate tanks; the tanks are cleaned between uses

associated with differing mud systems.

 Furthermore, air drilling (―pre

- set‖/surface drilling) is done separately fro m

horizontal drilling (―big rig‖) and occurs at different times (a smaller air rig will

drill the pre

- set and a larger mud rotary rig will drill the horizontal) . As a result

, there is no intermingling of the cuttings.

Disposal of cuttings is through permi tted Subtitle D landfills. Laboratory analysis for

drill cuttings is provided to the landfills specific to the drilling mud type and the waste

acceptance criteria of the specific landfill.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 70 Flowback Water Characterization

1. An operator commented that the dSGEIS is incorrect in stating on page 7

- 59 that

“concentrations of TDS in the return and process water increase over the life of the

well.” The comment stated that “once the flowback process is complete, after a few

months o f production, the TDS levels tend to stabilize for the lifespan of the well and

do not continue to increase.” Please state the TDS concentration at which

stabilization occurs, and provide supporting production

- phase data and analysis

from Marcellus wells i n the northern tier of Pennsylvania.

IOGA Response:

There is as yet no Marcellus well produced water data from New York and only limited

data from northern Pennsylvania. The TDS can be expected to vary based on the geology

of a given area within the Marc ellus subcrop area and also because HVHF additive

chemistry will not be the same in every well. Furthermore, because TDS is not a single

compound , it does not have a single solubility. TDS is comprised of numerous dissolved

constituents and the presence of one salt can either enhance or retard the solubility of

another salt. Therefore, it is not possible to conclusively predict the maximum TDS that

will be encountered in New York. The following response is subject to all of the caveats

mentioned in the Preamble to this document.

TDS data from the eight northern Pennsylvania wells in the MSC study are summarized

in Exhibits 10 and 11

.

Exhibit 1 0

TDS Concentrations (in mg/L)

Well Source 0 1 5 14 90

G 1920 74600 125000 169000 298000

I 400 265 122000 238000 261000 271000

J 746 4840 5090 48700 19100

K 804 18600 39400 3010

M 51 371 228000

O 2670 17400 125000 186000

Q 311 16600 38500 120000 207000

S 277 280 680 58300 124000

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 71 These data indicate that TDS concentrations generally increase over time during the

flowback process and may approach or exceed 300,000 mg/L. However, Wells J and K

clearly demonstrate that not all wells exhibit such an increasing trend in TDS

concentrations.

TDS concentrations wit hin a single well become asymptotic as the connate water

conditions predominate in produced water and actual contribution from the pumped

fracture fluid diminishes. Ultimately, TDS concentrations must become asymptotic as

saturation is reached. However, defining a saturation concentration for TDS is not as

straightforward as it would be with an individual salt solution. As noted above, this is

because TDS for a given shale gas

- produced water is comprised of numerous dissolved

constituents. Furthermore, the presence of one salt can either enhance or retard the

solubility of another salt. The saturation limit for sodium chloride at 0 °C is 35.7 g/L, or

357,000 mg/L (39.12 g/L or 391,200 mg/L at 100 ° C). 144 

## It is unlikely that TDS would

significantly exceed this level at standard temperature and pressure (STP). 145 

## According

to the Produced Water Society, the salinity of produced water can reach 400,000 mg/L;

however, that is not specific to the Marcellus Shale. 146



## Based on the currently available information fr om northern Pennsylvania, TDS in the

Marcellus of New York is expected to be highly variable. The maximum (i.e.

, for worst

case wells, not average wells) TDS observed is expected to be in the range of 300,000

mg/L to 360,000 mg/L. However, in many cases the maximum TDS from a given well

will likely be considerably less. In fact, stabilized TDS is frequently within the range of

150,000 mg/L to 200,000 mg/L. To date, there is insufficient data with which to

definitively quantify a maximum value for this p roduced water parameter. Exhibit 1 1

0 50000 100000 150000 200000 250000 300000 350000

Source 0 1 5 14 90 TDS Concentration (mg/L)



### Days Since Flowback Commenced G

I

J

K

M

O

Q

S

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 72 Note that although TDS concentrations may increase over time until the asymptotic

maximum is approached, average daily volume of brine water produced typically

decreases significantly over time (see E xhibit 12 ).

Exhibit 12

Produced Water Data

Well Well

Type Total Vol.

Frac Fluid

Used (in

BBLs) %

Recovered

(at

maximum

days

recorded) Average Daily Produced Water in BBLs

Day 1 Days 2

- 5 Days 6

- 14 Days 15

- 90

G Horizontal 123,921 15.1% 1,219.00 1,568.50 553.11 81.66

I Data on produced water volume is not available from the MSC database for this well

J Data on produced water volume is not available from the MSC database for this well

K Horizontal 70,774 13.4% 5,751.0 566.3 161.9

M Horizontal 99,195 19.9% 16,419.0 379.0 198.7

O Horizontal 96,706 19.9% 5,131.0 3,517.8

Q Vertical 23,593 21.6% 1,315.0 565.5 168.1

S Vertical 16,460 65.1% 2,094.0 1,434.5 168.1 18.1

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 73 Flowback Water Reuse/Recycling

1. Press reports and presentations by representatives of the Susquehanna River Basin

Commission assert flowback water recycling rates as high as 100% associated with

Marcellus Shale development in Pennsylvania. Describe the methodologies used to

achieve this, including:

a. Fluid storage and handling at every stage in t he process,

b. Any on

- site treatment process, including equipment and methodology,

c. Volume, description, composition and disposal of any residual waste fluid and/or

solids, including concentrations, handling and disposal of naturally occurring

radioactive mate rials, and

d. The types of additives necessary for the reuse of flowback. Provide a pie chart

depicting a typical fracturing fluid composition (by weight) where recycled

flowback is utilized and provide an explanation for any differences in this pie

chart fro m that requested below, under “Hydraulic Fracturing Additives

– Composition and Management.”

IOGA Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

The reuse and recycling of produced water from t he flowback process for future

fracturing operations is an evolving practice in the Marcellus Shale. While some

companies are targeting goals of recycling 100% of the water produced from a well

, 147



## the technologies and methods that are being utilized for re cycling and reuse vary by

company and from one well to another. Produced w ater quality varies such that 100%

recycling is not always possible ; some produced water contains enough scale

- causing

constituents (e.g.

, barium, strontium, calcium, and iron) that service companies may

consider the water to be unsuitable for recycl ing

. 148 

## Furthermore, recycling technologies

are still evolving in the Marcellus play and are expected to continue to evolve over time,

just as these technologies have been optimized for ot her shale gas plays in the United

States. Originally operators focus ed on treating produced water using polymers and

flocculants to precipitate out and remove metals, but more recently operators have begun

using filtration technologies to achieve the same goal. 149



## Locations of recycling facilities vary by operator and are also based on local conditions.

Some operators are using on

- site treatment at the well pad where the water is produced or

at another permitted pad; others are permitting centralized wate r processing facilities for

recycling water and storage using steel tanks. 150 

## Local conditions that may dictate

whether on

- site or off

- site facilities are used include topography, existing land use

, and

surface use agreements (SUA). SUAs may also dictate w here temporary pipelines

(―fastlines‖) can be installed to transport produced water to a centralized facility. In

locations where pipelines cannot be used, water trucks would be used to haul recycled

water between the well site and the treatment facility.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 74 As discussed under the i tem ― Air Impacts 2 ,‖ IOGA has responded that the operators will

not use centralized storage impoundments for water produced during flowback, but

instead produced water, including that used for reuse/recycling, will be stored in s teel

tanks. 151



## Operators will place 500 bbl steel tanks on the well pad to contain the produced water. In

some instances operators may set up tanks to capture and segregate water produced

during the flowback process based on the estimated water quality ; when such tanks are

used, water that is typically suitable for re

- use with little or no processing can be stored

separately from water that requires some degree of treatment. The produced water is

monitored as it flows back into these tanks so that operat ors can identify and isolate water

that is suitable for re

- use. If necessary, any water not suitable for direct reuse or

treatment followed by reuse is separated for appropriate disposal. 152



## Recycling contractors currently active in the Marcellus Play inc lude M i SWACO and

Tetra Tech. 153 

## Other companies, including Fountain Quail, have recently committed

resources to the Marcellus Shale p lay but their processes are still in the testing and

development phase for this area.

Fracturing additives must still be us ed for fracture treatments that employ recycled

produced water as part, or all, of the make

- up water. Current recycled water fractures use

between 10% and 20 % recycled fluids; the remainder of the fracture fluid is comprised of

fresh water. Because of th e large volume of fresh water necessary for HVHF stimulation,

there is still a need to add chemicals to treat the fracture water that is going downhole

because:

 The residual HVHF chemicals in the water produced during flowback are

typically not at the orig inal blended concentrations as these chemicals have

reacted with the target formation during their first HVHF use and/or they were

exhausted during their first use.

 The addition of 80% to 90% fresh water significantly dilutes any residual

chemicals in th e recycled fluid. 154



## Limitations to the reuse of fracturing fluids are currently based on the volume of

produced water returns during the flowback period and the timing of upcoming fracture

treatments. As noted above, t he mixing of fresh water with prod uced water from the

Marcellus Shale allows operators to achieve an overall make

- up water quality in the

effective range of the intended chemical additives. This has several advantages, most

notably:

 Reuse avoids the need for extensive treatment or disposal of the produced water.

 Reuse of produced water helps to lessen the demand on fresh water sources.

Currently operators are maximizing the volume of produced water that is being recycled

in the Marcellus Shale either by direct reuse or through trea tment of the water at on

- site

or commercial water treatment plants and subsequent reuse as HVHF make

- up water.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 75 The addition of fracturing chemicals for an HVHF that uses recycled water is performed

in a similar manner to one which uses only freshwater for the make

- up water. The

primary difference is that two sources of water, fresh water and recycled produced water,

are typically fed into the mixing manifold. Pumps are used to control the feed rate of

each water type in order to control the mixing rat io and, hence, the overall quality of the

resulting make

- up water. The fracturing chemical additives are then combined in the

mixing manifold with the blended make

- up water just prior to the fluid being pumped

downhole, similar to any HVHF stimulation.

Fracture fluid chemical composition varies by service company, by operator, and by

geological conditions. Because there are bacteria and scale

- forming minerals present in

the connate formation water within the shale and because the produced water is a mix ture

of that connate water and the pumped fracturing fluid, the produced water often requires

higher additive concentrations than fresh water fracture fluid mixes. Specifically,

additional concentrations of the following are commonly necessary:

 Scale inhi bitors

– because produced water contains scale

- forming metals from the

formation, higher concentrations of scale inhibitors are often necessary.

 Friction reducers

– because the produced water tends to have higher total

dissolved solids and suspended solids concentrations, which result in greater

friction when pumping the fracturing fluids than would fresh water, higher

concentrations of friction reducers are often necessary.

For example, s cale inhibitors for a fresh water fracture fluid may be added at a

concentration of 8 ppm while a recycled fracture fluid with 20% recycled water may

require up to 30 ppm. 155 

## Similarly, f resh water fracture fluids may have 500 ppm friction

reducer while 20% recycled water may require 1,000 ppm friction reducer.

The pie chart in Exhibit 1 3 provides an example of the composition of a typical recycled

fracture fluid where the water is comprised of 15% recycled produced water and 85%

Exhibi t 1 3

Example Frac Fluid with Recycled Water

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 76 fresh water. In this example only thr ee chemical additives are being used : the acid flush

for the initial stage of the fracture treatment and two chemical additives for the fracture

fluid ( biocide and friction reducer )

.

As long as wells are being hydraulically fractured in the Marcellus play, produced water

will continue to be available for reuse in future HVHF stimulations. In the later

development al life of the Marcellus Shale play, there may come a time when the number

of new wells (i.e., new fracture treatments) dec reas es to a point where not all of the

produced water available can be utilized in new fracture stimulations and the volume of

produced water will exceed the volume of water needed for fracture treatments. If and

when this were to occur, the d isposal of p roduced water would be required.

Additionally, those processes that treat the produced water may also generate residual

w aste products . While the waste products will vary by technology , they may include

concentrated brines, spent filter media, residual solids , and sludges. Disposal of excess

produced water and treatment wastes is conducted in accordance with applicable

regulations. Liquid wastes not suitable for reuse or further treatment and recycling are

managed through subsurface disposal in Class I I disposal wells permitted in accordance

with the Safe Drinking Water Act, Underground Injection Control program regulations,

and permitting process. 156 

## Any residual solid materials are disposed of by landfilling or

landfarming in accordance with applicable solid waste disposal regulations.

2. IOGANY commented that the SGEIS should consider use of on

- site (i.e., at the well

pad) reserve pits as large as 2 million gallons to promote water recycling. More

information is needed for the Department to consider an d respond to this comment.

The following information must be provided:

a. Proposed dimensions for a 2

- million gallon pit (length, width, depth), including

internal dimensions if the pit will be segmented,

b. Full description of proposed liner, monitoring and leak detection systems,

c. Detailed description of installation practices that will prevent liner damage

during installation,

d. Detailed description of proposed operation for recycling. Describe all mechanical

activities that could occur above the liner system, and how they will be

conducted to prevent liner damage,

e. Detailed description of treatment systems associated with reserve pit use for

recycling, including description of any waste that is generated and how the waste

is managed,

f. Detailed description of pro posed pit closure and site reclamation,

g. Explain whether it is proposed that the pit’s use in a recycling plan would be

limited to the well pad where it is located, or if it is proposed that such a pit

would service other well pads. State the anticipated ma ximum duration of use

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 77 for each case, including overall duration and the percentage of time that the pit

would contain fluid,

h. Explain whether this pit would be separate from, or the same as, the drilling

reserve pit used to contain drilling fluids and cutti ngs. If cuttings will be

contained in the same pit that is used for flowback water recycling, then explain

how cuttings will be managed, including whether cuttings would remain in the

pit for the entire duration of its use or whether they would be intermit tently

removed. If cuttings would be intermittently removed while the pit is still in

active operation for fluid recycling, describe how this would be done without

damaging the pit liner system, and

i. Provide a detailed explanation of the comment that “[P]it s are markedly more

flexible and make it easier to condition, treat and ultimately recycle flowback

water.” Identify the constraints or problems associated with tanks that are

solved by using pits instead.

IOGA Response:

The following response is subject t o all of the caveats mentioned in the Preamble to this

document.

As stated under item ―Air Impacts #2‖ above, the flowback of HVHF produced water to

impoundments or open pits will not occur; produced water returned during the flowback

process will be store d in tanks. Therefore, the use of large reserve pits for the recycling

of produced water is not an issue. With this is mind, the request for dimensions (a), liner

and leak detection systems (b), installation practices (c), operational activities (d),

tre atment systems (e), pit closure and reclamation (f), service area and duration of

operations (g), management of cuttings from the pit (h), and potential benefits of such pit

use for recycling are no longer relevant considerations for the SGEIS.

Industry re cognizes that any future use of a large pit or impoundment (well pad dedicated

or centralized) to manage produced water would likely require project

- specific

environmental review and approval, potentially up to and including preparation of an

independent, project

- specific EIS. Such a scenario is not expected to adversely impact

development of the Marcellus Shale and IOGA would not object.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 78 Greenhouse Gas

1. Of the greenhouse gas mitigation measures identified in the dSGEIS on pages 7

- 91

through 7

- 95, what measures does industry propose to implement with respect to

high

- volume hydraulic fracturing in New York? For each measure explain why its

implementation is or is not proposed. Please identify and describe in detail any

additional mitigation measures that are proposed.

IOGA Response

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

In 2009, the EPA issued the Greenhouse Gas (GHG) Reporting Rule requiring the

reporting of GHG emissions from large sources and suppliers in the U

. S. 157 

## The rule was

intended to collect accurate and timely emissions data to inform future policy

decisions. 158



## In 2010, the EPA made one such policy decision by finalizing the Greenhouse Gas

Tailoring Rule. 159 

## This rule established new perm itting thresholds for GHGs that were

―tailored‖ to address the Title V and PSD programs regulated under the New Source

Review program for stationary sources in the Clean Air Act. Since the facilities that are

envisioned for the development of the Marcellu s Shale in New York are not typically

regulated under either of those two permitting programs, their permitting thresholds and

requirements related to GHGs are not yet known.

In 2009, the DEC’s Office of Air, Energy and Climate issued its Guide for Assess ing

Energy Use and Greenhouse Gas Emissions in an Environmental Impact Statement

(Guide)

. 160 

## The policy reported that the Guide is to be used by DEC staff in reviewing an

EIS when the DEC is the lead agency under SEQR and energy use or GHG emissions

have be en identified as significant in a positive declaration, or as a result of scoping, and,

therefore, are required to be discussed in an EIS. The DEC has met one goal of the Guide

by characterizing and presenting estimates of total annual emissions of relati ve GHGs, as

both short tons and as carbon dioxide equivalents (CO 2 

## e). In addition, the major

contributors of GHGs are to be identified and a menu of potential BMPs offered.

IOGA members have reviewed the list of potential GHG mitigation BMPs and measures

presented in the Guide and believe those listed in the menu below are the ones most

likely to be utilized in the natural gas development of the Marcellus Shale in New York.

 energy efficient heaters and generators

,

 use of biodiesel or other biofuel

,

 incorporate solar energy

,

 conserve and restore the site , and

 incorporate idling procedures

.

Additionally, there are substantial incentives for operators to use the most fuel

- efficient

engines and to reduce fugitive methane leaks as much as practicable in order to produce

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 79 more natural gas to sales. One additional mitigation measure that has proven effective in

reducing methane losses has been through active and voluntary parti cipation in the EPA’s

Natural Gas STAR Program. The success of this program was seen in 2008 through

domestic emission reductions that led to more than $802 million in additional revenue

from natural gas sales and the avoidance of 46.3 million tons of CO 2 

## e. 161 

## Thus, IOGA

recognizes that proof of participation in this program is an important addition to the menu

of BMPs and mitigation measures listed above. Finally, the DEC has presented a lengthy

list of possible GHG mitigation measures in the dSGEIS that industry will consider for

inclusion in their individual Greenhouse Gas Mitigation Plans.

In sum

, federal or state regulations affecting the permitting of GHGs for operations

typical of shale gas development have not yet been developed. Because GHGs are not

regulated and have no target standards, it would not be prudent to propose mitigation

measures at the time this response was prepared . Without standards, it is not possible to

predict if mitigation measures will be appropriate, sufficient, or excessiv e. Once EPA

completes their initial emissions inventory of GHGs and establishes standards for GHGs,

it is likely those standards will be incorporated into future permitting requirements.

IOGA industry members are prepared to address those issues once the y become known.

However, implementing mitigation measures now, with their associated expenditures,

could result in the need to replace those measures with alternative approaches once target

standards are established.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 80 Hydraulic Fracturing Additives

– Composition and Management

1. Halliburton Energy Services, Inc. (HESI) states that DEC should correct statements

in the draft SGEIS regarding the number of products that are typically used at a

well site and states that the fracturing fluids anticipated to be used in New York's

Marcellus Shale would rarely, if ever, include an additive from each of the 12 classes

of additives. HESI states that the fracturing fluid system to be used in any frac job

in the Marcellus would typically include no more than four or f ive different

additives and in some cases would include as few as three. Specify which 3 to 5

additives would be present and provide a pie chart depicting a typical frac fluid

composition (by weight) for Marcellus wells in the northern tier of Pennsylvania

, similar to that depicted in Figure 5

- 3. If fracturing fluid used in New York is

expected to be significantly different from what is currently used in Pennsylvania,

provide a separate pie chart for New York as well as an explanation of why the

composition difference is expected.

IOGA Response

While IOGA recognizes Halliburton’s comment as based on that company’s expectations

of the service they anticipate providing in N ew Y ork State , it may not be possible to

reduce the number of additives to 3 to 5 total chemical categories for all fracture

treatments. In discussions IOGA NY has had with fracturing service providers and

operators, there are many variables in the development process many of which are factors

resulting from local variability in site conditi ons which affect the number of chemicals

used in a fracture fluid. As such

, the number of chemical additives being used for

fracture treatments in nearby Pennsylvania development varies from the 3 to 5 chemical

categories (as noted by Halliburton) to trea tments which utilize 8 to 12 chemical additive

categories. 162 

## Furthermore, discussions with service providers, operators and fracturing

chemical manufacturers have noted that industry is refining and changing fracture fluid

compositions as the Marcellus pla y develops. As a result, the number of additives used

in a facture fluid is likely to vary over time as operators and service companies gain play

specific experience and a further understanding of what additives are most effective for

that play. This may result in a reduction of chemical additives from the 8 to 12 identified

or may result in an increase from the 3 to 5 that Halliburton proposed. With no

development of the Marcellus Shale using horizontal wells and HVHF in New York State

to date, it is no t possible to foresee the range of potential HVHF fluid compositions over

the coming decades with any certainty. Nonetheless, and in light of the caveats just

mentioned and those outlined in the Preamble, IOGA recognizes that DEC desires

potential startin g points for their evaluation, and so has prepared the following response.

In addition, IOGA notes that its members have no incentive to use a greater number of

chemical additives than is necessary and plan only to use the number required to

effectively s timulate any particular well.

Pie charts depicting several potential chemical make

- ups for slickwater HVHF fluids are

presented below. Exhibit 14 163 

## is a pie chart showing the breakdown by weight percent

of a fracture fluid comprised of freshwater that uses chemical additives from eight

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 81 additive categories. The fluid is 99.4% water and proppant (sand) with 0.56% chemical

additives, of which 0.4% is hydrochloric acid. The hydrochloric acid is typically pumped

during the initial substage of the first fractur e stage in the stimulation job and, therefore,

will be diluted by the subsequent large volume of water pumped during the remaining

stages of the complete fracture treatment.

Exhibit 1 5 164 

## presents a second pie chart depicting an alternative chemical make

- up for a

slickwater HVHF fluid. This chart shows breakdown by weight percent of a fracture

fluid comprised of freshwater and chemical additives from six additive categories. The

HVHF fluid in Exhibit 1 5 is 99.2% water and proppant (sand) with 0.78% chemical Exhibit 1 4

Fracture Fluid from the Marcellus Shale

- Pennsylvania (weight percent)

Exhibit 15

Fracture Fluid from the Marcellus Shale

- Pennsylvania (weight percent)

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 82 additives, of which 0.67% is hydrochloric acid. As noted for fracturing f luid example

from Exhibit 1 4 , the acid is typically pumped during the initial substage of the first

fracture stage in the stimulation job and is diluted by the subsequent pumping of large

volumes of water present in the remainder of the fracture treatment stages.

It is important to note that the list of HVHF chemicals previously provided prior to the

dSGEIS was the best reasonable approximation of the expected chemicals to be used in

New York. However, chemical additives are also evolving as chemical sup pliers are

working to develop ―greener‖ alternative chemicals. Also, operators are testing non

chemical alternatives (primarily treatment methods) to limit or reduce the number and

volume of chemicals used in fracture treatments. 165 

## Furthermore, service co mpanies and

chemical suppliers have stated the information supplied as part of the data request for the

dSGEIS on chemicals and as presented in Chapter 5 of the Draft SGEIS is as detailed and

complete as possible at the time this response was prepared

. 166 

## Currently, there are no

additional chemicals to be added to the chemical lists provided in Chapter 5 of the

dSGEIS.

2. Comments include a recommendation to revise Proposed Supplementary Permit

Condition 33c in Appendix10. Further detail is necessary regar ding the security

measures taken to restrict access to the chemical additives while they remain on an

unattended site.

IOGA Response

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

IOGA recognizes the pot ential concern with having chemicals present on unsecured sites.

Discussions with operators and service companies using chemicals onsite during

hydraulic fracturing stimulations have uniformly indicated that it is against company

policy to leave any chemi cals unattended on a well pad. 167 

## Based on these comments

from operators and service companies, it can be reasonably expected that unused

chemical additives will not be left unattended. 168

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 83 Naturally Occurring Radioactive Materials

1. Many comments were receiv ed on the topic of naturally occurring radioactive

materials in the Marcellus Shale. Provide any available NORM data and analysis

from Marcellus operations in the northern tier of Pennsylvania, including drill

cuttings, flowback water, production brine, tr eatment plant sludge and scale

buildup on piping and other equipment. Document and describe the sampling and

analysis methodology used.

IOGA Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

The f ollowing information regarding produced water and drill cuttings is provided in

response to comments to DEC. Liquid and solid samples were collected from twelve

(12) different wells located in three counties in Pennsylvania, specifically Bradford,

Seneca and Tioga C ount ies . Each of the wells intercepted the Marcellus Shale Play.

There are no data available from the operators regarding the other processes identified by

DEC, such as NORM in treatment plant sludge or scale buildup on equipment.

Produced Water

All of the produced water samples were collected after the wells were fractured. The data

provided in Exhibit 1 6 represent the analytical results for radiological parameters,

including uranium, thorium and associated decay progeny. Samples from the same wells

were collected over multiple days after treatment. The results show that the

concentration of radiological constituents were low in samples collected less than 30 days

after fracturing. The data for gross alpha concentrations ranged from less than 10

picocuries per liter (pCi/ L ) to 1,000 pCi/ L for samples collected from Day 0 to as long as

Day 14 after fracturing, with an apparent increase in concentration over time, reaching an

equilibrium state after approximately 30 days. Consequently, the results shown in

Exhibit 1 6 represent samples collected more than 30 days after fracturing.

Exhibit 1 6

Total Radionuclides in Produced Water

Parameter Methods Units Median Error (± SD) MDC Number of

Samples

Gross Alpha SW 9310 MOD pCi/L 4830 2500 1900 4

Gross Beta SW 9310 MOD pCi/L 1295 1900 753 4

Radium 226 EPA 901.1 Mod. pCi/L 766 510 90 3

Radium 228 EPA 901.1 Mod. pCi/L 273 230 170 3

Uranium 238 EPA 901.1 Mod. pCi/L 21 570 770 5

pCi/L

– picocuries per liter

MDC

– Minimum detectable concentration

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 84 Each produced water sample was analyzed for gross alpha and beta concentrations using

the EPA SW846 Method 9310. 169

, 170 

## This method was developed for liquids that exhibit

elevated concentrations of TDS. b 

## For gross alpha and gross beta radiation, an aliquot of

the liquid sample was dried directly onto the planchet; the volume of liquid was varied

such that the dried residue did not exceed 100 milligrams. The sample was then counted

using a calibrated, ga s flow proportional detector. The results are reported as total alpha

or total beta activity per unit mass. The method for specific isotopic analysis was

completed using gamma spectroscopy using EPA 901.1, DOE HASL 300 Method Ga

- 01

- R or its equivalent. 171 

## The laboratory reported the specific gamma lines that were used to

quantify the isotope. For Radium

- 226, the gamma lines from Bismuth

- 214 (609 keV)

was used, assuming secular equilibrium.

The results for produced water samples are summarized in Exhibit 1 6 . These results

indicate that the gross alpha radiation averaged 4,830 ± 2,500 picocuries per liter (pCi/ L )

with a sample detection limit of 1,900 pCi/ L . For gross beta radiation, the results

averaged 1,295 ± 1,900 picocuries per liter (pCi/l) with a sample detection limit of 750

pCi/ L . The sample detection limits were elevated because of interference from TDS. For

Radium

- 226, the concentrations averaged 766 ± 510 pCi/ L with a sample detection limit

of 90 pCi/ L . Concentrations of U ranium

- 238 were no t detected in the produced water

samples.

Other analytical results for NORM in produced water were summarized by the DEC in

2009. 172 

## These results indicated the gross alpha radiation ranged from 22 to 18,950

pCi/ L . For gross beta radiation, the results ran ged from 62 to 7,445 pCi/ L . For R adium

226, the concentrations ranged from 2.6 to 33 pCi/ L . No information was provided

regarding the analytical methods that were used nor the applicable sample detection

limits. The results summarized in Exhibit 1 6 are similar to those reported by the DEC,

with gross alpha and gross beta concentrations within the range of the DEC data.

However, the results for Radium

- 226 shown in Exhibit 1 6 are higher than the Radium

226 concentrations reported by the DEC.

Drill Cutting s

Drill cuttings were collected from wells located in Pennsylvania, specifically in Bradford,

Seneca and Tioga C ount ies . The data shown in Exhibit 1 7 represent the analytical results

for uranium, thorium and associated decay progeny for the cuttings. Iso topic analysis

was performed using gamma spectroscopy (DOE HASL 300 Method Ga

- 01

- R or its

equivalent). 173 

## The laboratories reported the specific gamma lines (energies) that were

used to quantify each isotope. For Radium

- 226, the gamma lines from its progen y

Bismuth

- 214 (609 keV) was used, after the sample was prepared and held until secular

equilibrium between parents and progeny was re

- established.

b 

### Originally, the analytical laboratories used procedures designed for analysis of drinking water samples

(specified in USEPA regulations 40 CFR 141.25 and Appendix A to Subpart C of Part 141) which are not

appropriate for samples with elevated TDS. These results were reported as ―non detects‖, but with detection limits

as high as 5, 000 pCi/l, attributed to interferences from TDS and barium.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 85 Exhibit 17

Total Radionuclides in Drill Cuttings

Parameter Methods Units Median Error (± SD) MDC Number of

Samples

Lead 210 EPA 901.1 Mod. pCi/g 1.4 2.7 4.2 7

Radium 226 EPA 901.1 Mod. pCi/g 2.7 0.6 0.6 11

Radium 228 EPA 901.1 Mod. pCi/g 1.1 0.4 0.5 8

Uranium 238 EPA 901.1 Mod. pCi/g 2.0 2.0 3.5 8

pCi/g

– picocuries per gram

MDC

– Minimum detectable concentration



## Exhibit 1 7 shows Radium

- 226 was present in concentrations averaging 2.7 ± 0.6

pCi/gram (pCi/g) with a sample detection limit of 0.6 pCi/g. The concentrations of

Radium

- 228 averaged 1.1 ± 0.4 pCi/g with a sample detection limit of 0.5 pCi/g

. Uranium

- 238 and Lead

- 210 were not detected in the cuttings samples above a nominal

detection limit.

Other analytical results for Marcellus rock cuttings were summarized by the DEC in

2009. 174 

## These results indicated that Radium

- 226 was present in concent rations

averaging 1.4 ± 0.6 pCi/g. The concentration of Radium

- 228 averaged 1.0 ± 0.2 pCi/g.

The concentration of Uranium

- 238 averaged 0.8 ± 0.4 pCi/g. The concentration of Lead

210 averaged 1.4 ± 1.0 pCi/g. No information was provided regarding the an alytical

methods used or the individual sample detection limits. However, the DEC results are

comparable to those summarized in Exhibit 1 7

.

The Exhibit 1 7 results and data from DEC were compared to published data for other

ores that are encountered the mineral industry. The National Council on Radiation

Protection and Measurements (NCRP) Report Number 118 summarized radionuclide

concentrations in a variety of ore types commonly used in the manufacturing industry. 175



## Naturally occurring radioactive mater ials, including Radium

- 226, was reported in most of

them. For example, the concentration of Radium

- 226 in bauxite ore used to produce

aluminum ranged from 2.7 to 10.8 pCi/g. The concentration of Radium

- 226 in ore and

slag from the production of tin range d from 27.0 to 54.1 pCi/g. Zirconium sands used in

the production of deodorants, corrosion resistant surfaces, flashbulbs, and lamp filaments

was reported to contain Radium

- 226 in concentrations ranging from 108 to 190 pCi/g.

The concentrations of NORM i n the drill cuttings from the Marcellus Shale Play are thus

consistent with and similar to other materials commonly used in manufacturing

throughout the U.S. and the world.

Radiation Dose Assessment

Two separate radiation surveys were performed within the last 24 months to identify the

potential for exposure of workers to radioactive materials during the operation of drilling

equipment. Direct exposure rates (gamma radiation) were measured in all areas

accessible to workers at the sites. No levels in exce ss of the measured background level

of 10 to 13 microrads per hour were reported. Elevated exposure rates were noted,

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 86 however, on contact with some process water tanks (i.e., 20 to 160 microrads per hour).

A conservative estimate of total radiation dose potential for a hypothetical worker is

estimated to be less than 10 millirem in a year, based on a work duration in the vicinity of

NORM

- bearing equipment of 1,000 hours per year. This estimate is less than the DEC

limit established for members of the pub lic (less than 100 millirem per year) and not

readily distinguishable from normal background radiation exposures incurred by humans

by virtue of being alive. 176 

## In 2009, the NCRP summarized the majority of radiation

sources that contribute to the exposure o f the U.S. population. 177 

## The report identified

two major contributors to the exposure of the U.S. population from ionizing radiation:

exposure to ubiquitous background radiation and medical exposure of patients. The total

background exposure was reported to be approximately 610 millirem per year.

During the surveys at the well drilling sites, removable activity was assessed on the

equipment surfaces that were routinely occupied and accessible. Samples were collected

and analyzed for gross alpha radiation . All results were less than 20 disintegrations per

minute (dpm) per 100 square centimeters (100 cm 2 

## ). This low level of removable

radioactivity confirms that there is no significant ingestion or inhalation exposure

pathway for drilling workers.

Conclusions

The concentration of naturally occurring radioactive material found in produced water

and drill cuttings from the Marcellus Shale Play are consistent with NORM found in

materials commonly used in other manufacturing operations where ore and sla g are

handled. Workers at the drill sites have a radiation dose potential that is significantly

below the limits established DEC for members of the public. As stated in the d SGEIS,

―levels of radioactivity that are essentially background values, do not i ndicate an

exposure concern for workers or the general public associated with the Marcellus

cuttings‖. 178 

## Workers do not directly handle the water produced from the well; instead it

is pumped to storage containers and used for future wells. The water is no t potable as it

contains a high concentration of dissolved solids from the minerals present in the

formation. Consequently, the drilling tasks do not represent an occupational hazard of

significance and they present radiological risks that are significant ly lower than general

workplace risks encountered in other industries in New York.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 87 Well Development Patterns

1. IOGANY states that other well patterns may be considered for HVHF wells. Please

provide a discussion that describes potential wellbore configurations, and a

schematic of each configuration.

IOGA Response:

The following response is subject to all of the caveats mentioned in the Preamble to this

document.

Horizontal wells will be drilled from multi

- well pads to develop larger acreage spacin g

units with less surface disturbance than would a greater number of vertical wellbores

each drilled from individual well pads. This is discussed in greater detail in IOGA’s

response to item ―Activity Estimates 1b.‖

Spacing units for horizontal drilling in the Marcellus have not yet been set, but may be in

the 160

- acre to 80

- acre per well range. This will allow drilling from four to eight

horizontal wells from each multi

- well pad developing 640 acres. It is also possible that a

multi

- well pad may be us ed to develop 1,280 acres or more. In doing so the total acreage

developed could be apportioned to a greater number of wells with individual spacing

units similar to those contemplated above. Alternatively, in some cases it may be

possible to develop the larger acreage with the same number of wells but with longer

horizontal legs such that each well produces a greater acreage. For example, it may be

possible to develop 1,280 acres with eight wells each developing 160 acres.

The number of wells on a wel l pad, the length of the horizontal lateral, and the acreage

that can potentially be developed by a single well are based on many factors that

contribute to optimal drilling patterns including:

 The following geologic controls will influence the most effici ent drilling patterns

to develop the natural gas resource :

o Target formation thickness.

o Target formation depth.

o Areal extent of appropriate lithologic facies.

o Natural jointing within the target formation. The orientation of the natural

jointing will dictat e the optimal azimuth orientation of the wellbores.

Horizontal wells are oriented such that HVHF induced fractures will

intersect the maximum number of natural fractures in order to maximize

the fracture network and, therefore, natural gas production.

o Str uctural boundaries/complexity.

o Thermal maturity.

 Depth:

o All other factors being equal, the deeper the target formation, the longer

the lateral can be. Typically, the length of the lateral will not greatly

exceed the depth of the well using currently available drilling technology

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 88 for onshore consolidated strata (i.e.

, not off

- shore extended

- reach drilling

technology for use in unconsolidated formations). Rather, a 5,000 ft deep

well could have a horizontal lateral of approximately 5,000 ft in length,

but would be unlikely to have a lateral length much greater t han that.

o Well economics dictate the depth and lateral lengths that are practical for

development of a specific location. Shallower depths to the target

formation may not allow sufficient horizontal leg length

, and ; therefore

, may be more economically producible using vertical wells.

 Engineering controls and other mechanical

- physical factors : 179



## o Wellbore length.

o Well pad spacing.

o Interwell spacing.

o Radius of the build angle from the vertical to horizontal portions of the

borehole

.

o Cased hole versus open hole at the kick

- point.

o Whether or not measurement

- while

- drilling (MWD) instrumentation is

used.

o Geophysical logging tool requirements.

o Actual production experience in the play as it is gained.

 Land potentially available for leasin g.

 Distribution of a given company’s leasehold and the ability for two or more

companies to enter into joint ventures, or unitizations, when one does not hold all

of the acreage necessary to develop an area.

 Topography and other factors that may limit the size or placement of well pads.

Operators currently envision the use of several potential ―ideal‖ development patterns

including those shown in E xhibit 1 8 . However, as noted previously, the ―ideal‖

conditions may not prevail in all areas and may also chan ge between areas. As yet there

is insufficient production data from the Marcellus and there are no absolutes dictating the

spacing unit size, length of horizontal lateral, and the number of horizontal wells from a

single multi

- well pad. Horizontal legs a re anticipated to be from 3,000 to 5,000 feet long.

The following generic schematics depict six

- , eight

- , and ten

- well multi

- well pad

development scenarios each developing 640 acres and each having lateral leg lengths of

4,500 feet. Exhibit 1 8 must be co nsidered a generalized schematic; specific well pad

configurations must be expected to vary from these examples.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 89 It is important to note that other more complex multi

- lateral drilling patterns such as

pinnate wells may become advantageous in the future. The natural gas industry is

continually evaluating optimal drilling patterns for its wells. It would be impractical, and

not in the interest of optimal resource development, t o impose a single drilling pattern

and employ it at every well pad. What is appropriate for one well pad is not necessarily

appropriate for another. The well pattern schematics provided herein are not the only

possible approaches. Wellbore configuration s should be flexible, allowing for adaptation

to specific location

- or economic

- driven situations as well as to allow for the future

development of new approaches or technologies.

Generic Well Development Patterns for 6, 8, and 10 Well

Pads Exhibit 1 8

Generic Well Development Patterns for 6, 8, and 10 Well Pads

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 90 Traffic Characterization

1. Information is requested regarding the distribution of truck traffic over time, e.g.,

on a day

- by

- day basis. This information will be used to evaluate comments on the

draft SGEIS regarding socioeconomic issues and the portrayal of traffic impacts. It

may also feed into review of comments regarding air emissions. Please use the

templates provided (for both light

- duty and heavy

- duty trips) in the DEC’s June 8,

2010 e

- mail correspondence. Please account for all trips, whether by the operat or,

drilling contractor, subcontractors, or material/supply/equipment/water delivery.

IOGA Response:

It is not possible to accurately assess a ―typical‖ number of traffic trips necessary to

complete a well because of the many variables which can be involve d in drilling and

completing a well including:

 Multi

- well pads v. single well pads.

 Vertical wells v. horizontal wells.

 Drill rig availability

– the vertical section is commonly drilled with a small rig

(often, but not always, an air rotary rig) down to the surface casing point and in

some cases down to the kick point and then a larger rig is brought in to drill the

horizontal leg . In some cases, the well is drilled entirely with the lager rig

.

 Trucking v. the use of pipelines (fastlines) for water transport

– early year drilling

will involve mostly trucks, later year drilling ( e.g.

, peak year) may involve the use

of fastlines.

 The variable sizes of water trucks.

 The availability of supplies needed for drilling and completion.

 Weather.

 Etc.

The foll owing response is subject to all of the caveats mentioned in the Preamble to this

document.

The following describes assumptions that were used in developing the two calculation

scenarios provided herein for 1) a new well location completed early on in the

development life of the field, and 2) a well location completed during the peak

development year.

Assumptions:

 New well pad with single horizontal well being developed (industry expects to

initially drill two wells on each well pad which would reduce the number of truck

trips).

 Well pad will be multi

- well pad but will be developed over time.

 Well is being drilled by two rigs (vertical rig and directional rig).

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 91  Well will be completed using HVHF consisting of 10 stages and approximately 5

million gallons of water total (assumes that all water is trucked in).

The following is a breakdown of the approximate number of truck trips per activity, a

more detailed daily breakdown is provided in the attached Excel workshee t. These truck

trip estimates are representative of the initial mobilization to a multi

- horizontal well pad;

they would also be representative of the remobilization to a well pad after the first few

wells have been drilled and the rig is returned to drill out the balance of the remaining

wells. Because the ―early well pad scenario‖ represents all water transportation by truck

(later in the peak scenario it is assumed that fastlines may be used for some water

transport)

, it is representative of the worst

- c ase scenario for truck traffic.

Exhibit 19

Traffic Estimate, Horizontal Wells

Well Pad Activity Early Well Pad Scenario

(worst

- case) Peak Well Pad Scenario

Heavy Truck Light Truck Heavy Truck Light Truck

Drill Pad Construction 45 90 45 90

Rig Mobilization 95 140 95 140

Drilling Fluids 45 45

Non

- Rig Drilling

Equipment 45 45

Drilling (rig crew etc.) 50 140 50 140

Completion Chemicals 20 326 20 290

Completion Equipment 5 5

HF Equipment (Trucks

&Tanks) 175 175

HF Water Hauling 500 60

HF Sand 23 23

Produced Water Disposal 100 17

Final Pad Prep 45 50 45 50

Misc 85 85

TOTAL TRUCK TRIPS

PER WELL 1,148 831 625 795

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 92 Exhibit 2 0

Traffic Estimate, Vertical Wells

Well Pad Activity Early Well Pad Scenario

(worst

- case) Peak Well Pad Scenario

Heavy Truck Light Truck Heavy Truck Light Truck

Drill Pad Construction 32 90 25 90

Rig Mobilization 50 140 50 140

Drilling Fluids 15 15

Non

- Rig Drilling Equipment 10 10

Drilling (rig crew etc.) 30 70 30 70

Completion Chemicals 10 72 10 72

Completion Equipment 5 5

HF Equipment (Trucks

&Tanks) 75 75

HF Water Hauling 90 25

HF Sand 5 5

Produced Water Disposal 42 26

Final Pad Prep 34 50 34 50

Misc 0 85 0 85

TOTAL TRUCK TRIPS

PER WELL 398 507 310 507



## The cumulative traffic impact, on an annualized basis, can be estimated based on the

following ( peak development scenario using fastlines for a portion of water transport at

average annual pad development rate of 1,108 horizontal well pads and 246 vertical

pads ) :

 Horizontal wells:

o 2,216 wells on 1,108 well pads.

o An average of 625 heavy truck trips for the initial well on a pad.

o An average of 260 heavy truck trips per well for the second well on a pad.

o An average of 795 light truck trips for the initial well on a pad.

o An average of 596 light truck trips per well for the second well on a pad.

o A subtotal of 1,384,703 heavy truck trips to drill and develop 2,216

horizontal wells during the peak year of development.

o A subto tal of 1,541,174 light truck trips to drill and develop 2,216

horizontal wells during the peak year of development.

 Vertical wells:

o 2 46 wells on 246 well pads

.

o An average of 3 10 heavy truck trips

.

o An average of 507 light truck trips.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 93 o A subtotal of 76,313 heavy truck trips to drill and develop 2 46 vertical

wells during the peak year of development.

o A subtotal of 124, 808 light truck trips to drill and develop 2 46 vertical

wells during the peak year of development.

1 

### NY DEC, Division of Mineral Resources, Final Generic Environmental Impact Statement on the Oil, Gas and

Solution Mining Regulatory Program , Volumes I, II and III (July 1992).

2 

### NY DEC, Noti ce of SGEIS Information Needs (letter from the New York State Department of Environmental

Conservation Division of Mineral Resources to the Independent Oil & Gas Association of New York), April 12,

2010.

3 

### NY DEC, Supplementary Notice of SGEIS Information Needs (letter from the New York State Department of

Environmental Conservation Division of Mineral Resources to the Independent Oil & Gas Association of New

York), April 20, 2010.

4 

### NY DEC, Additional SGEIS Information Need

– Traffic (e

- mail from the New Y ork State Department of

Environmental Conservation Division of Mineral Resources to the Independent Oil & Gas Association of New

York), May 27, 2010.

5 

### NY DEC, Division of Mineral Resources, DRAFT Supplemental Generic Environmental Impact Statement On

The Oil, Gas and Solution Mining Regulatory Program: Well Permit Issuance for Horizontal Drilling and High

Volume Hydraulic Fracturing to Develop the Marcellus Shale and Other Low

- Permeability Gas Reservoirs

(September 2009), available at http://www.dec.ny.gov/energy/58440.html

.

6 

### U.S. Energy Information Administration (EIA), ―Marcellus Shale Gas Play, Appalachian Basin,‖ map (March

17, 2010) http://www.eia.doe.gov/oil_gas/rpd/shaleusa5.pdf (accessed May 2010).

7 

### Arkansas Oil and Gas Commission (AOGC), Arkansas Online Data System Overview (n.d.), http://www.aogc

.state.ar.us/JDesignerPro/JDPArkansas/AR_Welcome.html (accessed May 2010).

8 

### U.S. Energy Information Administration (EIA), ―Natural Gas Weekly Update, Overview (For the Week

Ending Wednesday, August 18, 2010)‖, (August 19, 2010), http://tonto.eia.doe.gov/oog/info/ngw/ngupdate.asp

(accessed August 24, 2010).

9 

### ALL Consulting, NY DEC SGEIS Information Requests and Industry Responses , prepared for the Independent

Oil & Gas Association of New York (IOGA NY), October 14, 2009.

10 

### ALL Consulting, Table 8 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

11 

### ALL Consulting, Table 15 in NY DEC SGEIS Information Requests and Industr y Responses , prepared for

IOGA NY, October 14, 2009.

12 

### ALL Consulting, Table 15 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

13 

### ALL Consulting, Table 18 in NY DEC SGEIS Information Requests and Industr y Responses , prepared for

IOGA NY, October 14, 2009.

14 

### ALL Consulting, Table 7 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

15 

### ALL Consulting, Table 14 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

16 

### ALL Consulting, Table 14 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

17 

### ALL Consulting, Table 14 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

18 

### NY DEC, ―Emission Inventories,‖ Section 4.0 in New York State Implementation Plans: Ozone (8

- Hour

NAAQS): Attainment Demonstration for NY Metro Area , Final Proposed Revision (February 2008), 4

- 1 throu gh 4

- 16, http://www.dec.ny.gov/chemical/37026.html (accessed May 2010).

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 94 19 

### New York State Energy Planning Board (SEPB), 2009 State Energy Plan , Volumes I

- III (December 2009),

http://www.nysenergyplan.com/stateenergyplan.html (accessed August 4, 2010).

20 

### ALL Consulting, NY DEC SGEIS Information Requests and Industry Responses , prepared for IOGA NY,

October 14, 2009.

21 

### Ground Water Protections Council (GWPC) and ALL Consulting, Modern Shale Gas Development in the

United States: A Primer , prepared for the U.S. Department of Energy, Office of Fossil Energy, and National Energy

Technology Laboratory (April 2009), available online at: http://fossil.energy.gov/programs/oilgas/publications/

naturalgas_general/Shale_Gas_Primer_2009.pdf

.

22 

### ALL Consulting, NY DEC SGEI S Information Requests and Industry Responses , prepared for he Independent

Oil & Gas Association of New York (IOGA NY), October 14, 2009.

23 

### GWPC and ALL Consulting, Modern Shale Gas Development in the United States: A Primer , prepared for

the U.S. Departme nt of Energy, Office of Fossil Energy, and National Energy Technology Laboratory (April 2009),

available online at: http://fossil.energy.gov/pr ograms/oilgas/publications/naturalgas_general/Shale_Gas

_Primer_2009.pdf

.

24 

### ALL Consulting, NY DEC SGEIS Information Requests and Industry Responses , prepared for IOGA NY,

October 14, 2009.

25 

### ALL Consulting, NY DEC SGEIS Information Requests and Industry R esponses , prepared for IOGA NY,

October 14, 2009.

26 

### The Gas Technology Institute (GTI), Sampling and Analysis of Water Streams Associated with the

Development of Marcellus Shale Gas , Final report, prepared for: Marcellus Shale Coalition (Formerly the Marce llus

Shale Committee), December 31, 2009.

27 

### Personal communication with Test America, Inc., May 27, 2010.

28 

### Personal communication with Test America, Inc., May 27, 2010.

29 

### Agency for Toxic Substances and Disease Registry (ATSDR), ―ToxFAQs for Pyridine‖ (Se ptember 1995),

http://www.atsdr.cdc.gov/tfacts52.html (accessed May 2010).

30 

### Chemicalland21.com, ―Benzene‖ (n.d.), http://chemicalland21. com/petrochemical/BENZENE.htm (accessed

June 7

- 18, 2010).

31 

### Personal communication with Universal Well Services, May 20, 2010.

32 

### Chemicalland21.com, ―Naphthalene‖ (n.d.), http://chemicalland21.com/petrochemical/naphthalene.htm

(accessed June 7

- 18, 2010).

33 

### Chemicalland21.com, ―Phenol‖ (n.d.), http://chemicalland21.com/petrochemical/PHENOL.htm (accessed

June 7

- 18, 2010).

34 

### Chemicalland21.com, ―Toluene‖ (n.d.), http://chemicalland21.com/petrochemical/TOLUENE.htm (accessed

June 7

- 18, 2010).

35 

### Personal communication with Universal W ell Services, May 20, 2010.

36 

### Chemicalland21.com, ―Psuedocumene (1,2,4

- trimethyl benzene)‖ (n.d.),

http://chemicalland21.com/industrialchem/organic/PSEUDOCUMENE.htm (accessed J une 2010).

37 

### Chemicalland21.com, ―p

- Xylene‖ (n.d.), http://chemicalland21.com/petrochemical/p

- XYLENE.htm

(accessed June 7

- 18, 2010).

38 

### Chemicalland21.com, ―o

- Xylene‖ (n.d.), http://chemicalland21.com/petrochemical/o

- XYLENE.htm

(accessed June 7

- 18, 2010).

39 

### Personal communication with Universal Well Services, May 20, 2010.

40 

### D. V. Satyanarayana Gupta, Greg Niechwiadowicz, and Anita C. Jerat, ―Carbon Dioxide Compatible Non

Aqueous Crosslinked Fracturing Fluids and Methods for Their Use,‖ Patent 7049436 (issued May 23, 2006),

http://www.patentstorm.us/patent s/7049436/description.html (accessed July 22,2010).

41 

### James B. Crews and William Russell Wood, ―Friction Loss Reduction in Viscoelastic Surfactant Fracturing

Fluids Using Low Molecular Weight Water

- Soluble Polymers,‖ patent application (filed April 6, 2009 ),

http://www.faqs.org/patents/app/20090192056 (accessed July 22, 2010).

42 

### National Park Service (NPS), ―Environmental Contaminants Encyclopedia: Kerosene Entry‖ (July 1, 1997),

http://www.nature.nps.gov/hazardssafety/toxic/kerosene.pdf (accessed June 2010).

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 95 43 

### NPS, ―Environmental Contaminants Encyclopedia: Benzo [a] Pyrene Entry‖ (July 1, 1997),

http://www.nature.nps.gov/hazardssafety/toxic/benzoapy.pdf (accessed June 7

- 18, 2010).

44 

### U.S. Environmental Protection Agency (EPA), ―Benzo(g,h,i)perylene,‖ CAS Number: 191

- 24

- 2 (n.d.)

, http://www.epa.gov/epawaste/hazard/wastemin/minimize/factshts/benzoper.pdf (accessed June 2010).

45 

### ATSDR, ―Public Health Statement for Naphthalene, 1

- Methylnaphthale ne, and 2

- Methylnaphthalene‖ (2005),

http://www.atsdr.cdc.gov/toxprofiles/phs67.html (accessed June 7

- 18, 2010).

46 

### Chemicalland21.com, ―Mesitylene (1,3,5

- trimethyl benzene)‖ (n.d.), http://chemicalland21.com/

industrialchem/organic/MESITYLENE.htm (accessed June 7

- 18, 2010).

47 

### California Department of Toxic Substances Control, ECL User’s Manual , Appendix C (2006).

48 

### Che micalland21.com, ―Acetophenone‖ (n.d.), http://chemicalland21.com/industrialchem/organic/

acetophenone.htm (accessed June 7

- 18, 2010).

49 

### ASTDR, ―ToxFAQs for Bis(2

- chloroethyl) Ether‖ (July 1999), http://www.atsdr.cdc.gov/tfacts127.html

(accessed June 2010).

50 

### Chemicalland21.com, ―Bromoform‖ (n.d.), ht tp://chemicalland21.com/industrialchem/solalc/

BROMOFORM.htm (accessed June 7

- 18, 2010).

51 

### J. Alan Beech, Raymond Diaz, Cesar Ordaz, and Besteiro Palomeque, ―Nitrates, Chlorates and

Trihalomethanes in Swimming Pool Water,‖ American Journal of Public Health , 70, no. 1 (1980), 79

- 82.

52 

### ATSDR, ―Toxicological Profile for Bromoform and Chlorodibromomethane‖ (August 2005),

http://www.atsdr.cdc.gov/toxprofiles/tp130.html (Accessed June 7

- 18, 2010).

53 

### ASTDR, ―ToxFAQs for 2

- Butanone‖ (September 1995), http://www.atsdr.cdc.gov/tfacts29.html (accessed

June 7

- 18, 2010).

54 

### ASTDR, ―ToxFAQs for 2

- Butanone‖ (September 1995), http://www.atsdr.cdc.gov/tfacts29.html (accessed

June 7

- 18, 2010).

55 

### ATSDR, ―Public Health Statement for 2

- Butanone‖ (July 1992), http://www.a tsdr.cdc.gov/toxprofiles/

phs29.html (accessed June 7

- 18, 2010).

56 

### TradeOffer, ―P

- isopropyltoluene‖ (© 2005), http://www.tradeoffer.com/view_details.php?browse=sell&id

=173068 ( accessed June 7

- 18, 2010).

57 

### Gabriella Kiskó and Sibel Roller, ―Carvacrol and p

- Cymene Inactivate Escherichia Coli )157:H7 in Apple

Juice,‖ BMC Microbiology 5, no. 36 (2005), http://www.biomedcentra l.com/1471

- 2180/5/36 (accessed June 7

- 18,

2010).

58 

### ASTDR, ―ToxFAQs for n

- Nitrosodiphenylamine‖ (April 1993), http://www.atsdr.cdc.gov/tfacts16.html

(accessed June 2010).

59 

### EPA, ―Polychlorinated Biphenyls (PCBs): Basic Information‖ (March 24, 2009), http://www.epa.gov/

epawaste/hazard/tsd/pcbs/pubs/about.htm (accessed August 4, 2010).

60 

### ASTDR, ―ToxFAQs for Aldrin/Dieldrin‖ (September 2002), http://www.atsdr.cdc.gov/toxfaqs/

tf.asp?id=316&tid=56 (accessed June 7

- 18, 2010).

61 

### ASTDR, ―Public Health Statement: Hexachlorocyclohexane‖ (n.d.) http://www.atsdr.cdc.gov/

toxprofiles/tp43

- c1.pdf (accessed June 7

- 18, 2010).

62 

### ASTDR, ―Public Health Statement: Hexachlorocyclohexane‖ (n.d.) http://www.atsdr.cdc.gov/

toxprofiles/tp43

- c1.pdf (accessed June 7

- 18, 2010).

63 

### Chemicalland21.com, ―Lindane‖ (n.d.), http://che micalland21.com/lifescience/uh/LINDANE.htm (accessed

June 7

- 18, 2010).

64 

### ASTDR, ―Public Health Statement: Hexachlorocyclohexane‖ (n.d.) http://www.atsdr.cdc.gov/

toxprofiles/tp43

- c1.pdf (acce ssed June 7

- 18, 2010).

65 

### ASTDR, ―Toxic Substances Portal: Endosulfan‖ (April 1, 2010), http://www.atsdr.cdc.gov/substances/

toxsubstance.asp?toxid=113 (accessed June 7

- 18, 2010)

.

66 

### ASTDR, ―ToxFAQs for Heptachlor and Heptachlor Epoxide‖ (August 2007), http://www.atsdr.cdc.gov/

tfacts12.html (accessed June 7

- 18, 2010).

67 

### ASTDR, ―ToxFAQs for Heptachlor and Heptachlor Epoxide‖ (Aug ust 2007), http://www.atsdr.cdc.gov/

tfacts12.html (accessed June 7

- 18, 2010).

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 96 68 

### Chemicalland21.com, ―Bis(2

- Ethylhexyl) Phthalate‖ (n.d.), http://chemicalland21.com/industrialchem/

plasticizer/DOP.htm (accessed June 7

- 18, 2010).

69 

### Chemicalland21.com, ―Tetrachloroethene‖ (n.d.), http://chemicalland2 1.com/industrialchem/solalc/

PERCHLOROETHYLENE.htm (accessed June 7

- 18, 2010).

70 

### Chemicalland21.com, ―1,2,3

- tricholorbenzene‖ (n.d.), http://chemicalland21.com/speci altychem/finechem/

1,2,3

- TRICHLOROBENZENE.htm (accessed June 7

- 18, 2010).

71 

### Personal communication with Test America, Inc., May 27, 2010.

72 

### Personal communication with Test America, Inc., June 9, 2010.

73 

### GTI, Sampling and Analysis of Water Streams Associa ted with the Development of Marcellus Shale Gas

, Final report, prepared for: Marcellus Shale Coalition (Formerly the Marcellus Shale Committee), December 31,

2009.

74 

### Personal communication with Test America, Inc., June 15, 2010.

75 

### Personal communication wi th Test America, Inc., June 15, 2010.

76 

### GTI, Sampling and Analysis of Water Streams Associated with the Development of Marcellus Shale Gas

, Final report, prepared for: Marcellus Shale Coalition (Formerly the Marcellus Shale Committee), December 31,

2009.

77 

### GTI, Sampling and Analysis of Water Streams Associated with the Development of Marcellus Shale Gas

, Final report, prepared for: Marcellus Shale Coalition (Formerly the Marcellus Shale Committee), December 31,

2009.

78 

### GTI, Sampling and Analysis of Water St reams Associated with the Development of Marcellus Shale Gas

, Final report, prepared for: Marcellus Shale Coalition (Formerly the Marcellus Shale Committee), December 31,

2009.

79 

### Personal communication with Test America, Inc., May 27, 2010.

80 

### Personal comm unication with Test America, Inc., June 9, 2010.

81 

### EPA, ―Technical Highlights: Emission Regulations for Stationary and Mobile Engines,‖ EPA420

- F

- 02

- 034,

(September 2002), 2, available at http://w ww.epa.gov/nonroad/2002/420f02034.pdf

.

82 

### NY DEC, ―Part 200.1: Definitions (cd),‖ of New York Regulations, Chapter III

– Air Resources, Part 200:

General Provisions (June 8, 2010), http://www.dec. ny.gov/regs/13427.html#13438

.

83 

### NY DEC, ―Part 200.1: Definitions (aw)(1)(iii),‖ of New York Regulations, Chapter III

– Air Resources, Part

200: General Provisions (June 8, 2010), http://www.dec.n y.gov/regs/13427.html#13438

.

84 

### EPA, ―Technical Highlights: Emission Regulations for Stationary and Mobile Engines,‖ EPA420

- F

- 02

- 034,

(September 2002), 2, available at http://www.epa.gov/nonroad/2 002/420f02034.pdf

.

85 

### EPA, ―Green Book: Particulate Matter PM

- 2.5 2006 Standard Nonattainment Area/State/County Report‖

(June 15, 2010), http://epa.gov/airquality/greenbk/rnca.html (accessed August 6 , 2010).

86 

### EPA, ―Part A

– Motor Vehicle Emission and Fuel Standards,‖ of Clean Air Act: Title II

– Emission

Standards for Moving Sources (1990), http://epa.gov/oar/caa/title2.html (accessed September 9, 2010).

87 

### EPA, Federal Register Environmental Documents , ―Control of Air Pollution; Determination of Significance

for Nonroad Sources and Emissions Standards for New Nonroad Compression Engines At or Above 37 Kilowatts,‖

(June 17, 1994), http://www.epa.gov/fedrgstr/EPA

- AIR/1996/November/Day

- 12/pr

- 23833DIR/Other/a5645

- 4.html

(accessed September 9, 2010).

88 

### EPA, Federal Register Environmental Documents , ―Control of Emissions of Air Pollution from Nonroad

Diesel E ngines,‖ (dated October 23, 1998), http://www.epa.gov/fedrgstr/EPA

- AIR/1998/October/Day

23/a24836.htm (accessed September 9, 2010).

89 

### 40 CFR Parts 9, 69, 80, 86, 89, 94, 1039, 1048, 1051, 1065, and 1068, ―Control of Emissions of Air Pollution

From Nonroad Diesel Engines and Fuel,‖ Federal Register, Part II, Environmental Protection Agency (June 29,

2004).

90 

### Personal communication with Chesapeake Energy Corporation, August 23, 2 010.

91 

### Texas Commission on Environmental Quality (TCEQ), ―4.6.3. Allocation of the June 2009 through 2010

Fleet Turnover Reductions,‖ State of Texas Air Quality Implementation Plan for the Control of Ozone Air Pollution:

Dallas/Fort Worth 1997 Eight

- Hour Ozone Nonattainment Area , TCEQ Project No. 2009

- 021

- SIP

- NR (September

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 97 23, 2009), available at http://www.tceq.state.t x.us/assets/public/implementation/air/sip/dfw/dfw_sip021809/

PdfNo4_PROPOSED_DFW_RRC_SIP_Narrative.pdf

.

92 

### ALL Consulting, NY DEC SGEIS Information Requests and Industry Responses , prepared for IOGA NY,

October 14, 2009.

93 

### ALL Consulting, Table 8 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

94 

### ALL Consulting, Table 15 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

95 

### ALL Consulting, Table 15 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

96 

### ALL Consulting, Table 18 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

97 

### ALL Consulting, Table 7 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

98 

### ALL Consulting, Table 14 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

99 

### ALL Consulting, Table 14 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

100 

### ALL Consulting, Table 18 in NY DEC SGEIS Information Requests and Industry Responses , prepared for

IOGA NY, October 14, 2009.

101 

### NY DEC, ―Emission Inventories,‖ Se ction 4.0 in New York State Implementation Plans: Ozone (8

- Hour

NAAQS): Attainment Demonstration for NY Metro Area , Final Proposed Revision (February 2008), 4

- 1 through 4

- 16, http://www.dec.ny.gov/c hemical/37026.html (accessed May 2010).

102 

### SEPB, 2009 State Energy Plan , Volumes I

- III (December 2009), http://www.nysenergyplan.com/

stateenergyplan.html (accessed August 4, 2010).

103 

### North Tex as Council of Governments (NTCOG), ―Number of Barnett Shale Wells versus 8 Hour Historical

Ozone Levels Both in the 9 County DFW Non

- Attainment Area‖ (November 2008), as published in Michael E.

Powell, Jr., ―Recent Developments in the Barnett Shale,‖ Powel l Barnett Shale Newsletter (presentation), slide 42,

http://www.barnettshalenews.com/documents/2009TAEPExpo/Recent%20Developments%20 in%20the%20Barnett

%20Shale.pdf (accessed August 6, 2010).

104 

### EPA, ―Clean Air Act: Title I

– Air Pollution Prevention and Control‖ (updated December 19, 2008),

http://www.epa.gov/oar/caa/title1.html (acce ssed May 2010).

105 

### New Mexico Environment Department (NMED), ―1

- hour NO2 Modeling for NMED Minor Sources‖

(March 2010), available at http://www.nmenv.state.nm.us/aq b/modeling/documents/

NM_1hourNO2methodology.pdf

.

106 

### Colorado Department of Public Health and Environment (CODPHE), SCREEN3 Stationary Source Modeling

Guidance (December 2005), 7, available at http://www.colorado.gov/airquality/permits/screen.pdf

.

107 

### California Air Resources Board (CARB), NOx and VOC Species Profiles for Gas Fired Stationary

Combustion Sources , ARB Contract No. A5

- 158

- 32 (January 1995), available at http://www.arb.ca.gov/research/

apr/past/a132

- 104_1.pdf

.

108 

### California Air Resources Board (CARB), NOx and VOC Species Profiles for Gas Fired Stationary

Combustion Sources , ARB Contract No. A5

- 158

- 32 (January 1995), E

- 9, available at http://www.arb.ca.gov/

research/apr/past/a132

- 104_1.pdf

.

109 

### California Air Resources Board (CARB), NOx and VOC Species Profiles for Gas Fired St ationary

Combustion Sources , ARB Contract No. A5

- 158

- 32 (January 1995), 5

- 17 and Table 5

- 10, available at

http://www.arb.ca.gov/research/apr/past/a132

- 104_1.pdf

.

110 

### Tyler Fox, Leader Air Quality Modeling Group, EPA

, Memorandum, to Regional Air Division Directors,

― Applicability of Appendix W Modeling Guidance for the 1

- hour NO 2 

### National Ambient Air Quality Standard ‖

(June 28, 2010), available at http://www.epa.gov/ttn/scram/ClarificationMemo_AppendixW_Hourly

- NO2

- NAAQS_FINAL_06

- 28

- 2010.pdf

.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 98 111 

### Tyler Fox to Regional Air Division Directors (EPA), memorandum, (Subject : Applicability of Appendix W

Modeling Guidance for the 1

- hour NO 2 

### National Ambient Air Quality Standard), June 28, 2010, available at

http://www.epa.gov/ttn/scram/ClarificationMemo_AppendixW_Hourly

- NO2

- NAAQS_FINAL_06

- 28

- 2010.pdf

.

112 

### ―Appendix W to Part 51

– Guideline on Air Quality Models,‖ 40 CFR Part 51, Federal Register , 70, no. 216

(November 9, 2005) Part III, Environmental Protection Agency, available at http://www.epa.gov/ttn/scram/

guidance/guide/appw_05.pdf

.

113 

### Air and Waste Management Association (AWMA), Letter from AWMA’s AB

- 3 Committee to EPA/RTP

,

― Comments of the Air & Waste Management Association’s AB

- 3 Meteorological and Modeling Committee

Regarding New Dispersion Modeling Issues: PM2.5 and 1

- hour NAAQS for NO2 and SO ‖ ( March 12, 2010 )

. .

114 

### Iowa Department of Natural Resources (DNR), ―Here’s How the New 1

- Hour Nitrogen Dioxide NAAQS

Applies to PSD Permit Applications,‖ (n.d.), http://www.iowadnr.gov/air/news/articles/10apr13.html (accessed June

2010 ).

115 

### GWPC and ALL Consulting, Modern Shale Gas Development in the United States: A Primer , prepared for

the U.S. Department of Energy, Office of Fossil Energy and the National Energy Technology Laboratory (April

2009).

116 

### NY DEC,―Part 701: Classifications: Surface Waters and Groundwater‖ (1991), http://www.dec.ny.gov/regs/

4592.html (accessed June 25, 2010).

117 

### NY DEC, ―Part 700: Definitions, Samples and Tests‖ (1991), http://www.dec.ny.gov/regs/4593 .html

(accessed June 25, 2010).

118 

### Privileged and confidential Information provided by Chesapeake Energy Corp. in support of the IOGA

response to DEC’s information requests, 2010..

119 

### Information provided by multiple service companies which participated in th e data request for the Draft

SGEIS who were polled by IOGA NY in drafting this response.

120 

### Information provided by multiple service companies which participated in the data request for the Draft

SGEIS who were polled by IOGA NY in drafting this response.

121 

### Information provided by multiple service companies which participated in the data request for the Draft

SGEIS who were polled by IOGA NY in drafting this response.

122 

### Privileged and confidential Information provided by Chesapeake Energy Corp. in support of the IOGA

response to DEC’s information requests, 2010.

123 

### Information provided by multiple service companies which participated in the data request for the Draft

SGEIS who were polled by IOGA NY in drafting this response

.

124 

### Chemicalland21.com, ―Tetrakis(hy droxymethyl)phosphonium sulfate‖ (n.d.), http://chemicalland21.com/

specialtychem/finechem/BIS%5BTETRAKIS(HYDROXYMETHYL)PHOSPHONIUM%5D% 20SULFATE.htm

(accessed July 22, 2010).

125 

### Information provided by multiple service companies which participated in the data request for the Draft

SGEIS who were polled by IOGA NY in drafting this response.

126 

### Dow Chemical, ―DOW Ethylene Glycol: Gas Dehydration & Treating‖ (© 1995

- 2010),

http://www.dow.com/ethyleneglycol/app/gas.htm (accessed June 2010).

127 

### U.S. Department of Labor, Occupational Safety & Health Administration (OSHA), ―Safety and Health

Topics: Ethylene Oxide‖ (2010), http://www.osha.gov/SLTC/ethyleneoxide/ (accessed June 2010).

128 

### Lebond Chemical, ―Polyaspartic Acid‖ (© 2009), http://www.lebondchem.com/polyaspartic

- acid.html

(accessed July 2010).

129 

### Lindsey Gloe and Greg Neal, ― UV Light Reduces the Amount of Biocide Required to Disinfect Water for

Fracturing Fluids,‖ presen ted at the Society of Petroleum Engineers (SPE) Eastern Regional Meeting, Charleston,

WV, September 23

- 25, 2009.

130 

### Kembe Kleinwolterink, Brandon Watson, Dave Allison, and Matt Sharrock, ―UV Light Technology Controls

Bacteria while Reducing Environmental Ri sks,‖ World Oil (December 2009).

131 

### Venture Engineering & Construction

, ― Marcellus Shale

– Water Treatment Options Worth Considering,‖

Technical Brief, http://www.ventu reengr.com/downloads/Marcellus%20Shale_Water_Treatment.pdf (accessed

August 11, 20 1 0).

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 99 132 

### J. B. Clark, J. C. Luppens, and P. T. Tucker, ―Using Ultraviolet Radiation for Controlling Sulfate

- Reducing

Bacteria in Injection Water,‖ SPE 13245, presented at the SPE Annual Technical Conference and Exhibition,

Houston, TX, September 16

- 19, 1984.

133 

### Kembe Kleinwolterink, Brandon Watson, Dave Allison, and Matt Sharrock, ―UV Light Technology Controls

Bacteria while Reducing Environmental Risks,‖ World Oil (December 200 9).

134 

### Kembe Kleinwolterink, Brandon Watson, Dave Allison, and Matt Sharrock, ―UV Light Technology Controls

Bacteria while Reducing Environmental Risks,‖ World Oil (December 2009).

135 

### Kembe Kleinwolterink, Brandon Watson, Dave Allison, and Matt Sharrock , ―UV Light Technology Controls

Bacteria while Reducing Environmental Risks,‖ World Oil (December 2009).

136 

### Personal communication with Dennis McGuire (Ecosphere Energy Solutions, Inc.), July 10, 2009.

137 

### Nace International

, ―Selection, Application, and Eva luation of Biocides in the Oil and Gas Industry‖ ( NACE

International Publication , 2005)

.

138 

### Haliburton, Kawartha, Pine Ridge District Health Unit, ―Environmental Health Fast Facts: Using Ultraviolet

Light to Treat Water ‖ (2005), https://www.hkpr.on.ca/uploadedFiles/uvlight.pdf (accessed August 11, 2020)..

139 

### Venture Engineering & Construction, ―Marcellus Shale

– Water Treatment Options Worth Considering.‖

140 

### Lenntech, ―Ozone decomposition‖ (n.d.), http://www.lenntech.com/library/ozone/decomposition/

ozone

- decomposition.htm (accessed June 18, 2010).

141 

### David Wethe, ― Halliburton Hunts New Ba cteria Killer to Protect Shale

- Gas Boom,‖ Bloomberg (March 29,

2010), http://www.bloomberg.com/apps/news?pid=20601109&sid=aINvzI7k5xYY (accessed June 18, 2010).

142 

### Staff Reporter , ―Options Drive Gas Compression,‖ Hart Energy Publishing, LP (August 1, 2005),

http://www.epmag.com/archives/features/2104.htm (accessed August 6, 2010).

143 

### NY DEC, Final Generic Environmental I mpact Statement on the Oil, Gas and Solution Mining Regulatory

Program (July 1992, Reprinted 2003), available at http://www.dec.ny.gov/energy/45912.html

.

144 

### David R. Lide, ed., CRC Handbook of Chemistry and Physics , 74 th 

### ed. (Boca Raton, FL: CRC Press, 1994).

145 

### Personal communication with Richard Burrows, Ph.D. (Test America, Inc.), May 14, 2010.

146 

### Produced Water Society (PWS), ―Produced Water Facts,‖ (n.d.), http://70.86.131.22/~produced/

page.php?page_name=produced_water_facts (accessed June 2010).

147 

### Comments from IOGA NY participating companies.

148 

### Comments from IOGA NY participating companies.

149 

### Comments from IOGA NY pa rticipating companies.

150 

### Comments from IOGA NY participating companies.

151 

### Comments from IOGA NY participating companies.

152 

### Comments from IOGA NY participating companies.

153 

### Comments from IOGA NY participating companies.

154 

### Comments from IOGA NY particip ating companies.

155 

### Comments from IOGA NY participating companies.

156 

### EPA, ―Underground Injection Control Program: Underground Injection Control Quick Finder‖ (February 22,

2010), http://www.epa.gov/safewater/uic/index.html (accessed July 26, 2010).

157 

### EPA, Greenhouse Gas Mandatory Reporting, EPA

- HQ

- OAR

- 2008

- 0508

- 2278 (dated October 2008),

available at http://www.regulations.gov/search/Regs/home.html#docketDetail?R=EPA

- HQ

- OAR

- 2008

- 0508

.

158 

### EPA, ―Climate Change

– Regulatory Initiatives: Greenhouse Gas Reporting Program‖ (updated July 20,

2010), http://www.epa.gov/climatechange/emissions/ghgrulemaking.html (accessed June 2010).

159 

### EPA, ―Final GHG Tailoring Rule,‖ New Source Review: Regulations and Standards (May 2010),

http://www.epa.gov/NSR/actions.html#2010 (accessed August 2010).

160 

### NY DEC, Technical Guidance: Guide for Assessing Energy Use and Greenhouse Gas Emissions in

Environmental Impact Statements (September 2008), available at http://www.nyupstateplanning.org/

GHG

- EISGuide08.pdf

.

161 

### EPA, ―Natural Gas STAR Program: Accomplishments‖ (updated December 2009), http://www.epa.gov/

gasstar/accomplishments/index.html (accessed August 2010).

162 

### Information provided by IOGA NY operators and service companies.

## NY DEC SGEIS Information Requests

and Industry Responses September 16 , 2010



# 100 163 

### Chemical Data Provided by Well Service Company.

164 

### Chemical Data Provided by IO GA NY Operator.

165 

### Information provided by IOGA NY operators and service companies.

166 

### Comment response from Service Companies contacted as part of developing this comment response.

167 

### Information provided by IOGA NY operators and service companies.

168 

### Based o n personal communication with Industry reps from Halliburton (May 2010), Universal Well Services

(May 2010), Chesapeake Energy (June 2010), Triana Energy (June 2010), Talisman Energy (June 2010), Kemira

(May 2010), and Baker Hughes (May 2010).

169 

### EPA

, Tes t Methods for Evaluating Solid Waste, Physical/Chemical Methods , SW

- 846, 3rd Edition, 2008.

170 

### EPA

, Gross Alpha and Gross Beta , SW

- 846, Method 9310, February, 2007.

171 

### U.S. Department of Energy, The Procedures Manual of the Environmental Measurements Laboratory,

HASL

- 300 , Volume I, Section 4.5.4, 28th Edition, February 1997.

172 

### NY DEC, Division of Mineral Resources, Table 5

- 10, DRAFT Supplemental Generic Environmental Impact

Statement On The Oil, Gas and Solution Mining Regulatory Program: Well Permit Issuance for Horizontal Drilling

and High

- Volume Hydraulic Fracturing to Develop the Marcellus Shale and Other Low

- Permeability Gas

Reservoirs (September 2009), available at http://www.dec.ny.gov/energy/58440.html

.

173 

### U.S. Department of Energy, HASL

- 300, The Procedures Manual of the Environmental Measurements

Laboratory, HASL

- 300 , Volume I, Section 4.5.4, 28th Edition, February, 1997.

174 

### NY DEC, Division of Mineral Resources, Table 5

- 2, DRAFT Supplemental Generic Environmental Impact

Statement On The Oil, Gas and Solution Mining Regulatory Program: Well Permit Issuance for Horizontal Drilling

and High

- Volume Hydraulic Fracturing to Develop the Marcellus Shale and Other Low

- Permeability Gas

Reservoirs (September 2009), available at http://www.dec.ny.gov/energy/58440.html

.

175 

### National Council on Radiation Protection and Measurements, Radiation Protection in the Mineral Extraction

Industry , NCRP Report 118, November 30, 1993.

176 

### State of New York, NYCRR, Title 10, Section 16.7, Radiation dose limits for individual members of the

public , 1994.

177 

### National Council on Radiation Protection and Measurements, Ioniz ing Radiation Exposure of the Population

of the United States , NCRP Report 160,2009.

178 

### NY DEC, Division of Mineral Resources, Section 5.2.4.2, DRAFT Supplemental Generic Environmental

Impact Statement On The Oil, Gas and Solution Mining Regulatory Program: Well Permit Issuance for Horizontal

Drilling and High

- Volume Hydraulic Fracturing to Develop the Marcellus Shale and Other Low

- Permeability Gas

Reservoirs (September 2009), available at http://www.dec.ny.gov/energy/58440.html

.

179 

### U.S. EIA, ―Drilling Sideways

– A Review of Horizontal Wells Technology and Its Domestic Application‖

(April 1993), http://www.eia.doe.gov/pub/oil_gas/natural_gas/analysis_publications/drilling_sideways_well

_technology/pdf/tr0565.pdf (accessed July 30, 2010).

## ATTACHMENT A

Marcellus Shale Coalition Study:

“ Sampling and Analysis of Water Streams Associated with the Development of Marcellus

Shale Gas, Final Report ”

# Sampling and Analysis of Water Streams

Associated with the Development of Marcellus

Shale Gas

Final Report

Prepared for

Marcellus Shale Coalition

(Formerly the Marcellus Shale Committee)

Prepared By

Thomas Hayes, Principal Investigator

Gas Technology Institute

1700 S. Mount Prospect Road

Des Plaines, IL 60018

December 31, 20092 

# List of Acronyms and Abbreviations

Acronym Definition Acronym Definition



## ASWCMC Appalachian Shale Water

Conservation and

Management Coalition MSC Marcellus Shale Coalition

BBL/bbl Barrel (42 gallons) PADEP Pennsylvania Department of

Environmental Protection

BCF Billion Cubic Feet ug/L Micrograms per liter (ppb)

BTEX Benzene, Toluene,

Ethylbenzene, Xylenes QAPP Quality Assurance Project Plan

Flowback

Water The water stream that

flows from a well in the

weeks following hydraulic

fracturing completion TCF Trillion Cubic Feet

Frac Hydraulic Fracture TDS Total Dissolved Solids

Frac Job Well completion event

involving hydraulic

fracturing TPH Total Petroleum Hydrocarbons

FSAP Field Sampling and

Analysis Plan PCB Polychlorinated Biphenyl

Compound

mg/l Milligrams per liter (ppm) POTW Publicly Owned Treatment

Works (a Sewage Treatment

Facility)

WVDEP West Virginia Department of

Environmental Protection3 

# Table of Contents

List of Acronyms and Abbreviations.............................................................................. 2

Executive Summary ...................................................................................................... 6

1.0 Introduction ........................................................................ 9

2.0 Methods and Procedures ................................................. 10

3.0 Results and Discussion.................................................... 19

3.1 Flowback Water Collection Characteristics ...................... 22

4.0 Implications for Fate and Transport.................................. 37

5.0 Conclusions...................................................................... 40

6.0 References Cited.............................................................. 42

Appendix ..................................................................................................................... 45

Appendix A – Field Sampling and Analysis Plan (FSAP) ........................................ 45

Appendix B – Quality Assurance Project Plan (Q APP). ........................................... 45

Appendix C – Tabulated Data Obtained from Locations A - S................................. 45

Appendix D – Summary of Detected VOC, SVOC, Pesticides and PCBs ............... 454 

# List of Figures

Figure 1. Sampling Locations in Pennsylvania

Figure 2. Sampling Locations in West Virginia.

Figure 3. Salt Concentration and Flowback Water Flow Versus Time from Location B5 

# List of Tables

Table 1. Measurements and Determinations

Table 2. Summary of Methods

Table 3. Water Use and Flowback Water Collection Associated with Hydraulic

Fracturing Completion of Shale Gas Wells

Table 4. Concentration of Total Dissolved Solids in Flowback Water at 19

Locations, mg/L

Table 5. Summary of Chemical Characteristics of Influent Water(1) Used for

Hydraulic Fracturing after Additives(2) Were Blended

Table 6. Summary of Chemical Characteristics of Water Supplies (1) 

## used for

Hydraulic Fracturing before Additives were Blended

Table 7. Summary of Chemical Characteristics of Flowback Water Sampled 5

Days Following the Hydraulic Fracturing Event (1)



## Table 8. Summary of Chemical Characteristics of Flowback Water Sampled at 14

Days Following the Hydraulic Fracturing Event (1)



## Table 9. Total Metals Concentrations in the Influent Water and 5-day Flowback

Water Obtained from 19 Locations

Table 10. Comparisons of Metals Levels in Shale Gas Waters with Municipal

Biosolids (Sewage Sludge)6 

# Executive Summary

At current estimates of recoverable natural gas of more than 489 tcf, the Marcellus

Shale is considered to be among the largest natural gas reserves in the world. The

development of this resource is technology driven, involving the use of hydraulic

fracturing technology as one of the necessary initial steps to releasing natural gas from

shale rock. Sustainable development of shale gas in the Marcellus Play requires the

management of volumes of water in a manner that is protective of human health and

the environment. Typically, 1 - 4 million gallons of an aqueous influent stream bearing

very low concentrations of additives are introduced downhole during each well

completion. These additives may include friction reducers, corrosion inhibitors,

oxygen scavengers, scale inhibitors and biocides that can be blended into the water

and sand mixture, but make up less than 0.5 percent of the total frac fluid that is

injected into a drilled well at high pressures to achieve and maintain the fracture of the

shale rock. Following fracturing, flowback water is collected from the well and placed

into frac tanks and/or flowback impoundments.

Effective management of flowback water requires some level of knowledge of the

characteristics of the water. Flowback water contains salts, metals and organic

compounds from the formation and the compounds that were introduced as additives

to the influent stream. Discussions between the industry and regulatory agencies of

Pennsylvania and West Virginia have pointed to the need for an information base on

the composition and properties of flowback water and on the influent water streams

that are used to perform frac jobs. The objecti ve of this effort was to conduct the initial

sampling and analysis of water streams associated with shale gas development in the

Marcellus Shale.

In recognition of the importance of this effort, 17 member companies of the Marcellus

Shale Coalition (MSC) volunteered 19 locations where shale gas wells were scheduled

to be hydraulically fractured. The Field Sampling and Analysis Plan and the Quality

Assurance Project Plan were developed, reviewed, and finalized for the effort by the7 

## companies of the Appalachian Shale Water Conservation and Management

Committee (ASWCMC), Pennsylvania Department of Environmental Protection

(PADEP) and West Virginia Department of Environmental Protection (WVDEP). At

each of the host sites, samples of influent water streams at Day 0 and the flowback

water streams at 1, 5, 14, and 90 days following the frac job event were collected by a

single engineering subcontractor, URS. All samples were sent to Test America (a

PADEP and WVDEP certified environmental testing laboratory) for analyses. The list

of constituents recommended for the char acterization study was developed from

comments received from the PADEP, the WVDEP and members of the ASWCMC.

Categories of determinations that were conducted included: 1) General Chemistry, 2)

Organic Compounds, and 3) Metals. Once reviewed and qualified, data from these

analyses were organized and tabulated in a source blind manner into an Excel

spreadsheet that currently represents the information base.

Results from this effort indicates that values for pH, alkalinity, total dissolved solids

(TDS), total organic carbon (TOC), oils and greases and other parameters from

general water characterization are within the normal ranges reported for conventional

produced waters by the USGS. Flowback wa ter concentrations of TDS ranged from

680 to 345,000 mg/l; typical profiles show an increase in TDS in flowback water with

time following a frac job event. As with conventional produced water, shale gas

flowback water cations are dominated by sodium and calcium; the main anion is

chloride. Metals normally seen in conventional produced waters, such as iron,

calcium, magnesium, and boron, are at levels in flowback waters that are well within

known ranges for normal produced waters. H eavy metals that are of concern in urban

industrial wastewaters and POTW sludges --- such as chromium, copper, nickel, zinc,

cadmium, lead, arsenic and mercury --- are at very low levels. Among volatile organic

constituents (VOCs), approximately 96% of the constituent determinations were at

non-detectable levels and less than 0.5% were detected above 1 ppm. VOCs that are

measurable are those that are normally found in conventional produced waters.

Regarding semi-volatile organic constituents (SVOCs), more than 98% of the

determinations were at non-detectable levels and less than 0.03% of all the

constituents were above 1 ppm; and several constituents were at low trace levels –8 

## usually below 10 ppb. Pesticide concentrations measured in the samples were

extremely low (all results were less than 1 ug/L) and extremely random with results

occurring in some supply water, Day 0, Day 14 and Day 90 samples. It is possible that

these low level concentrations are not representative of actual conditions and may be

attributed to laboratory contamination or instrument noise.

In conclusion, the results of this shale gas water characterization effort indicate that all

pesticides, PCBs, and a large fraction of the VOC and SVOC should be considered to

be unnecessary for the sampling and analysis of flowback waters in the future.9 

# 1.0 Introduction

The Marcellus Shale formation is the largest known shale deposit in the world. It

overlies much of the Appalachian Basin from West Virginia in the south, to Upstate

New York in the north, and Ohio to the west. The recoverable reserves of natural gas

in the Marcellus shale have been estimat ed at more than 489 trillion cubic feet

(Engelder, 2008).

Recent advances in horizontal drilling and multi-stage hydraulic fracturing technologies

have made sustainable natural gas production viable from otherwise uneconomical,

unconventional shale reservoirs such as t he Barnett, Haynesville, Fayetteville,

Woodford, et al. These tools and technologies have been successfully applied and

currently enable the ongoing development of the Marcellus Shale. This development

is currently underway in both West Virginia and Pennsylvania with the majority of the

wells drilled and completed in southwest and northeast Pennsylvania.

Many of the logistical challenges associat ed with the development of shale gas stem

from the amounts of water associated with the completion and operation of shale gas

wells that must be transported, stored and dispos ed of in a manner that is protective of

human health and the environment. In the course of developing shale gas in the

Appalachian Basin, thousands of wells will be drilled and completed. Hydraulic

fracturing (“fracing”) is a necessary step for the completion of each of these wells in

order to achieve economic well performance in terms of natural gas production. This

step requires between 1 and 4 million gallons (23,800 and 95,200 bbl) of water for

successful completion of each well; vertical wells require approximately 1 million

gallons (23,800 bbl) and horizontal wells require 3-4 million gallons (71,400 to 95,200

bbl) (Gaudlip, et al., 2008).

During a typical “frac job,” water is pumped downhole while additives such as friction

reducers and various grades of sand are in troduced to ensure a successful fracture

and completion of the shale. Following hydraulic fracturing, a fraction of the water10 

## (approximately 25%) that was injected is collected over several days resulting in the

collection of a “flowback” water stream that contains salts, oils and greases, and

soluble organics (volatile and semi-volatile) that accumulated in the water downhole.

Flowback water also contains low concentrations of additives that are introduced

during the frac job which normally include friction reducing polymers, corrosion

inhibitors, scale inhibitors, and biocides. These additives facilitate the hydraulic

fracturing process and prevent problems with well operation.

The first steps in identifying effective water management alternatives include an

effective analysis of the characteristics of the water streams involved in shale gas

development. The overall objective of this project is to develop an information base on

the nature and composition of influent water and flowback waters associated with

completions of shale gas wells in the Marcellus Shale.



# 2.0 Methods and Procedures

17 member companies of the MSC volunteered 19 locations for the sampling of

influent and effluent water streams. At each location, a well completion was

conducted using hydraulic fracturing procedur es that involved the injection of an

influent stream of water and the subsequent collection of flowback water. Standard

procedures were used to conduct sampli ng and analysis needed for the development

of water characterization data. All sampli ng was performed by the GTI subcontractor,

URS, following the same standard procedures. All sample analyses were performed

by a single laboratory, Test America of Pittsburgh, PA. Test America, an independent

analytical laboratory, provided the appropriate sample containers, preservatives and

completed the analytical analyses. Test America is certified in West Virginia and

Pennsylvania. Data tabulation, analysis and information base development was

provided by the Gas Technology Institute for this effort.

Details of the methods and procedures used for the collection and analysis of samples

obtained from each of the 19 locations are found in the Field Sampling and Analysis

Plan (FSAP) which is located in A ppendix A. The Field Sampling and Analysis Plan11 

## (FSAP) was developed to ensure that the data and information gathered for the

flowback characterization study was properly collected and documented.

A major aim of the characterization study was to generate technically sound data. To

meet this objective a Quality Assurance Project Plan (QAPP) was used to generate

accurate, precise, representative and complete data; this document is provided in

Appendix B. The Q APP provi ded the specific quality assurance/quality control

(QA/QC) procedures executed during the flowback Characterization Study.

Together the F SAP and Q APP comprise the Sampling and Analysis Plan (SAP). The

SAP was desi gned to meet the following informational goals:

• Identify the specific constituents of interest (COI) associated with flow back

water;

• Determine whether hydraulic fracturing additives are a source of COI in the

management of water associated with shale gas development; and,

• Provide sufficient information for the selection of proper water management and

disposal techniques.

Prior to initiating the characterization study, the SAP was reviewed by regulatory

officials from the Pennsylvania Department of Environmental Protection (PADEP) and

the West Virginia Department of Environmental Protection (WVDEP).

The original SAP pr oposed that four (4) grab samples be taken from six (6) vertical or

horizontal well locations throughout West Virginia and Pennsylvania. The following

grab samples were proposed:

• One baseline fracturing water sample that includes the fracturing additives,

excluding the sand;

• Flowback water samples collected on days 1, 5 and 14 following the fracturing

process; and12 

## • Water from an existing producing well at 90 days following hydraulic fracturing.

The list of constituents recommended fo r the characterization study was developed

from comments received from the PADEP, the WVDEP and members of the

Appalachian Shale Water Conservation and Management Committee (ASWCMC).

Because the recommended list of constituents was extremely extensive, it was

decided that one sample from each site would be completed for the full list of

recommended constituents. All other samples were collected and analyzed for a

subset of these constituents, which wa s designed based on generator knowledge.

Following the first few rounds of sampling, industry identified a data gap with respect

to characterizing the supply water used for fracturing. Supply water is identified as the

water used for fracturing prior to introducing the fracing additives.

The updated protocol characterization study ca lled for the collection of five (5) grab

samples from the each of the volunteered locations and expanded the sampling effort

to encompass 19 well locations volunteered by 17 member companies of the

Marcellus Shale Coalition. Table1 presents the list of all of the constituents of interest

(by category) that formed the basis for sample analysis. Analytical methods used to

perform the various determinations are listed in Table 2.

Under the updated sampling plan, the following grab samples were collected at each

of the volunteered locations:

• A supply water sample (before the blending of additives);

• One influent water sample following blending with fracturing additives, excluding

sand;

• Flowback water samples collected on 1, 5 and 14 days after hydraulic

fracturing; and

• Water from the producing well at 90 days after completion.

To address this data gap, it was decided to update the sampling/analysis protocol.13 

## Following the collection of the samp les and the performance of all of the

determinations, the data was organized, qualified and tabulated by GTI using an Excel

spreadsheet.

Table 1. Measurements and Determinations

General Chemistry

pH

Acidity

Total Alkalinity

Hardness as CaCO3

Total Suspended Solids

Turbidity

Chloride

Total Dissolved Solids

Specific Conductance Total Kjeldahl Nitrogen

Ammonia Nitrogen

Nitrate-Nitrite

Nitrite as N

Biochemical Oxygen

Demand

Chemical Oxygen

Demand

Total Organic Carbon

(TOC)

Dissolved Organic

Carbon Oil & Grease (HEM)

Cyanide, Total

Amenable Cyanide

Bromide

Fluoride

Total Sulfide

Sulfate

Total Phosphorus

Total Recoverable

Phenolics



## Volatile Organic Compounds

1, 4 - Dichlorobenzene

1, 3 – Dichloropropane

2, 2 – Dichloropropane

1, 1 – Dichloropropene

p – Isopropyltoluene

Naphthalene

n – Propylbenzene

1, 2, 3 - Trichlorobenzene

1, 2, 4 - Trichlorobenzene

1, 2, 4 - Trimethylbenzene

1, 3, 5 - Trimethylbenzene

Benzyl chloride

Isopropylbenzene

2 – Butanone

Methyl tert - butyl ether

(MTBE)

Xylenes (total)

2 - Chloroethyl vinyl ether

Cis - 1, 2 - Dichloroethene Acetone

Acrolein

Acrylonitrile

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide

Carbon tetrachloride

Chlorobenzene

Chloroethane

Chloroform

Chloromethane

Dibromochloromethane

1, 2 - Dibromo - 3 –

chloropropane

1, 2 - Dibromoethane (EDB)

Dibromomethane

Dichlorodifluoromethane 1, 4 – Dioxane

Ethylbenzene

Ethylene Glycol

2 – Hexanone

Methylene chloride

4 - Methyl - 2 - pentanone

(MIBK)

Styrene

1, 1, 1, 2 –

Tetrachloroethane

1, 1, 2, 2 –

Tetrachloroethane

Tetrachloroethene

Toluene

1, 1, 1 – Trichloroethane

1, 1, 2 – Trichloroethane

Trichloroethene

Trichlorofluoromethane

1, 2, 3 – Trichloropropane

Vinyl acetate14 

## Bromobenzene

n – Butylbenzene

sec – Butylbenzene

tert – Butylbenzene

4 – Chlorotoluene

1, 2 - Dichlorobenzene

1, 3 – Dichlorobenzene 1, 1 – Dichloroethane

1, 2 – Dichloroethane

1, 1 – Dichloroethene

trans - 1, 2 - Dichloroethene

1, 2 - Dichloropropane

cis - 1, 3 - Dichloropropene

trans-1, 3 - Dichloropropene Vinyl chloride

Tert - butyl acetate

Tetrahydrofuran

1 - chloro - 4 –

trifluoromethylbenz



## Semivolatile Organic Compounds

Diphenylamine

Benzidine

bis (2 - Chloroisopropyl)

ether

1, 4 – Dioxane

1, 2 – Diphenylhydrazine

Acenaphthene

Acenaphthylene

Acetophenone

2 – Acetylaminofluorene

4 – Aminobiphenyl

Aniline

Benzo (a) anthracene

Benzo (a) pyrene

Benzo (b) fluoranthene

Benzo (ghi) perylene

Benzo (k) fluoranthene

Benzyl alcohol

bis (2 - Chloroethoxy)

methane

bis (2 - Chloroethyl) –

ether

bis (2 - Ethylhexyl)

phthalate

4 - Bromophenyl phenyl

ether

Butyl benzyl phthalate

4 – Chloroaniline

4 - Chloro - 3 –

methylphenol

2 – Chloronaphthalene

2 – Chlorophenol

4 - Chlorophenyl phenyl

ether

Chrysene

Diallate Diethyl phthalate

Dimethoate

p -

Dimethylaminoazobenzene

7, 12 - Dimethylbenz (a) –

anthracene

2, 4 – Dimethylphenol

Dimethyl phthalate

Di - n - octyl phthalate

1, 3 – Dinitrobenzene

4, 6 - Dinitro - 2 –

methylphenol

2, 4 – Dinitrophenol

2, 4 – Dinitrotoluene

2, 6 – Dinitrotoluene

Dinoseb

Disulfoton

Ethyl methanesulfonate

Fluoranthene

Fluorene

Hexachlorobenzene

Hexachlorobutadiene

Hexachlorocyclopentadiene

Hexachloroethane

Hexachloropropene

Indeno (1, 2, 3 - cd) pyrene

Isodrin

Isophorone

Isosafrole

3 - Methylcholanthrene

Methyl methanesulfonate

2 - Methylnaphthalene

2 – Methylphenol

3 - Methylphenol & 4 –

Methylphenol Nitrobenzene

2 – Nitrophenol

4 – Nitrophenol

N - Nitrosodi - n –

butylamine

N – Nitrosodiethylamine

N – Nitrosodimethylamine

N - Nitrosodi - n –

propylamine

N – Nitrosodiphenylamine

N –

Nitrosomethylethylamine

N – Nitrosomorpholine

N – Nitrosopiperidine

N – Nitrosopyrrolidine

5 - Nitro - o – Toluidine

Parathion

Pentachlorobenzene

Pentachloroethane

Pentachloronitrobenzene

Pentachlorophenol

Phenanthrene

Phenol

Phorate

2 – Picoline

Pronamide

Pyrene

Pyridine

Safrole

1, 2, 4, 5 –

Tetrachlorobenzene

2, 3, 4, 6 Tetrachlorophenol

Thionazin

o – Toluidine

1, 2, 4 – Trichlorobenzene15 

## Dibenz (a, h) anthracene

Dibenzofuran

Di - n butyl phthalate

1, 2 – Dichlorobenzene

1, 3 – Dichlorobenzene

1, 4 – Dichlorobenzene

3, 3' – Dichlorobenzidine

2, 4 – Dichlorophenol

2, 6 – Dichlorophenol Naphthalene

1, 4 - Naphthoquinone

1 – Naphthylamine

2 – Naphthylamine

2 – Nitroaniline

3 – Nitroaniline

4 – Nitroaniline 2, 4, 5 – Trichlorophenol

2, 4, 6 – Trichlorophenol

O, O, O –

Triethylphosphorothioate

Chlorobenzilate

Aramite



## Metals

Aluminum

Antimony

Arsenic

Barium

Beryllium

Boron

Calcium

Cadmium

Cobalt Chromium

Trivalent Chromium

Copper

Iron

Lead

Lithium

Magnesiium

Manganese

Molybdenum Nickel

Potassium

Sodium

Selenium

Tin

Strontium

Titanium

Thallium

Zinc



## Pesticides

Chlordane (Technical)

alpha – BHC

beta – BHC

delta – BHC

gamma - BHC (Lindane)

Heptachlor

Aldrin

Heptachlor epoxide Endosulfan I

Dieldrin

4, 4' – DDE

Endrin

Endrin ketone

Endrin aldehyde

Endosulfan II 4, 4' – DDD

Endosulfan sulfate

4, 4' – DDT

Methoxychlor

Toxaphene



## Organophosphorus Pesticides

Thionazin Ethyl parathion Tetraethyldithiopyrophosphate



## Polychlorinated Biphenyls (PCBs)16 

## Aroclor 1016

Aroclor 1221

Aroclor 1232 Aroclor 1242

Aroclor 1248 Aroclor 1254

Aroclor 126017 

## Table 2. Summary of Methods

Parameter Analytical Method Preparation Method

pH SW846 9040 SW846 9040

Acidity (Titrimetric) SM20 2310 B (4a)

Alkalinity, Total SM18 2320 B SM18 2320 B

Amenable Cyanide SM18 4500-CN E SM18 4500-CN E

Biochemical Oxygen Demand SM18 5210 B SM18 5210 B

Bromide MCAWW 300.1A MCAWW 300.1A

Chemical Oxygen Demand MCAWW 410.4 MCAWW 410.4

Chloride MCAWW 300.1A MCAWW 300.1A

Cyanide, Total SW846 9012A SW846 9012A

Dissolved Organic Carbon SW846 7196A SW846 7196A

Fluoride MCAWW 300.1A MCAWW 300.1A

Hexavalent Chromium EPA 901.1 MOD

Hardness, Total SM20 2340C

Mercury in Liquid Waste SW846 7470A SW846 7470A

N-Hexane Extractable Material CFR136A 1664A H EPA 1 664A

Nitrate as N MCAWW 300.1A MCAWW 300.1A

Nitrite-Nitrate MCAWW 353.2 MCAWW 353.2

Nitrite as N MCAWW 300.1A MCAWW 300.1A

Nitrogen, Ammonia MCAWW 350.1 MCAWW 350.1

Organochlorine Pesticide SW846 8081A SW846 3510C

Organophosphorus Compounds SW846 8141A SW846 3510

Phenolics SW846 9066 SW846 9066

Polychlorinated Biphenyls SW846 8082 SW846 3510C

Semivolatile Organic Compounds SW846 8270C SW846 3520C

Specific Conductance MCAWW 120.1 MCAWW 120.1

Sulfate MCAWW 300.0A MCAWW 300.0A

Sulfides, Total SW846 9030B/903 SW846 9030B/90318 

## Table 2. Summary of Methods

Parameter Analytical Method Preparation Method

Total Phosphorus MCAWW 365.2 MCAWW 365.2

Total Dissolved Solids SM18 2540 C

Total Kjeldahl Nitrogen MCAWW 351.3 MCAWW 351.3

Total Organic Carbon SM20 5310B

Total Suspended Solids SM20 2540D

Trace Inductively Coupled

Plasma Metals SW846 6010B

SW846 6010B SW846 3005A

SW846 3010A

Trivalent Chromium SW846 6010B Wet None

Turbidity (Nephelometric) MCAWW 180.1 MCAWW 180.1

Volatile Organics by GC/MS SW846 8260B SW846 5030B

Ethylene Glycol SW846 8015 SW846 8015

Methylene Blue Activated

Substances (MBAS) SM5540C SM5540C19 

# 3.0 Results and Discussion

Throughout the performance of the flowback water sampling program, natural gas

development companies of the Marcellus Shale provided third party access to each of

the sampled well sites. This access was necessary to obtain the critical flowback

water samples at the standardized times of 0, 1, 5, and 14 days following the hydraulic

fracturing event. About a third of the companies assisted with the collection of a 90

day sampling of the flowback water, as well.

In total, 17 shale gas companies enabled the sampling of 19 locations within the

Marcellus Shale Region, including 3 locations in West Virginia and 16 locations in

Pennsylvania, as shown in the maps of Figures 1 and 2. The approximate positions of

all of the sampling locations (Locations A through S) are indicated on the maps.

Locations in West Virginia included 2 well completion sites in Lewis County and 1

completion site in Taylor County; both counties are in the northern half of the state, as

seen in Figure 2.

Host sites in Pennsylvania were well-distributed across the Commonwealth, involving

sampling in the Southwestern, Central, Northern and Northeastern regions of the state

representing the locations where most of the shale gas development is occurring. Half

of the sites sampled (a total of 8) were located in the Southwestern area of the state

as indicated on the map of Figure 1. Two sites were located in the Central portion and

two sites were located on the Northeastern side of the state. The remaining four

locations are positioned in the northern tier of Pennsylvania as shown in Figure 1.20 

## Figure 1. Sampling Locations in Pennsylvania.21 

## Host sites in West Virginia, on the other hand, were located in three counties of the

northern section of the state.

Figure 2. Sampling Locations in West Virginia.

Results from the analysis of all samples taken from Locations A through S have been

tabulated. Measurements and determinations included the following: 1) General

Chemistry; 2) Organic Compounds; and, 3) Metals. Tables of these results are

presented in Appendix C.22 

# 3.1 Flowback Water Collection Characteristics

As previously mentioned, the completion of each shale gas well examined in this

project required the introduction of a subs tantial volume of influent water (bearing

additives and sand) over a period of hours to achieve hydraulic fracturing. Following

successful fracturing, a water stream emer ges from the well under pressure; this

stream is collected in frac tanks or in impoundments. The initial volume of water that

is collected shortly after well completion is called flowback water. Beyond the

completion period, water from the formation is co-produced with natural gas over time.

Water volumes associated with 14 of the 19 wells sampled in this project are shown in

Table 3. Of the 14 wells reporting water volume information, six wells were vertical

wells and eight wells were of horizontal configuration. Of the vertical wells, an average

of approximately 40,000 bbls of influent water were used to achieve fracturing, and

about 16,000 bbls on average were collected within a 90 day period. Of the horizontal

wells, an average of approximately 90,000 bbls of influent water were used to achieve

fracturing, followed by a collection of about 18,000 bbls of effluent water (flowback).

Cumulative volumes of water collected over time for these 14 completed wells are

tabulated in Table 3.

Salt concentrations in influent water and in flowback water generated over time from

the 19 sampling locations are tabulated in Table 4. As shown in Table 4, influent

water usually contains moderate to low concent rations of salts. Following the use of

this water for hydraulic fracturing, a flowback water stream that is collected from the

well exhibits increasing concentrations of salts with time. Evidently, the water

introduced down-hole picks up soluble inorganic constituents from the formation

(consisting mostly of sodium and calcium chloride); as this water resides down hole, it

picks up increasing concentrations of total dissolved solids.23 

## Table 3. Water Use and Flowback Water Collection Associated with Hydraulic

Fracturing Completion of Shale Gas Wells

Cumulative Volume of Flowback Water, bbls

Location Well Type Total Vol.

Frac Fluid

Used,

bbls 1 Day* 5 Days 14 Days 90 Days Percent

Collected

A Vertical 40,046 3,950 10,456 15,023 37.5

B Vertical 94,216 1,095 10,782 13,718 17,890 19.0

C Horizontal 146,226 3,308 9,652 15,991 10.9

D Horizontal 21,144 2,854 8,077 9,938 11,185 52.9

E Horizontal 53,500 8,560 20,330 24,610 25,680 48.0

F Horizontal 77,995 3,272 10,830 12,331 17,413 22.3

G Horizontal 123,921 1,219 7,493 12,471 18,677 15.1

H Vertical 36,035 3,988 16,369 21,282 31,735 88.0

K Horizontal 70,774 5,751 8,016 9,473 13.4

M Horizontal 99,195 16,419 17,935 19,723 19.9

N Vertical 11,435 2,432 2,759 3,043 3,535 30.9

O Horizontal 96,706 5,131 19,202 19.8

Q Vertical 23,593 1,315 3,577 5,090 21.6

S Vertical 16,460 2,094 7,832 9,345 10,723 65.1

Weighted Average % Collected 24.3

* Days from the hydraulic fracturing event.



## A typical profile of salt concentrations measured in flowback water with time is shown

in Figure 3. In this figure, data from Location B is plotted. As seen in this diagram,

early flowback water emerging soon after the frac job is relatively low in TDS content;

following the initial day, the concentration of total dissolved solids increases with time

from low salt concentrations to a plateau of elevated salt levels as measured at 14 and

90 days. Also shown in this diagram is the marked concomitant decrease in flowback

brine flow with time, exhibiting a high initial flow rate of over 2,400 bbls/day, then

decreasing to a minimal flow rate of less than 55 bbls/day after the initial few weeks

following completion, a 98% reduction of daily flow. It should be mentioned that the

lowest flow rate bar shown on the chart in Figure 3 was calculated from cumulative

water data between 14 and 90 days; actual flows in the 60 to 90 day period are24 

## significantly less than 55 bbls/day. The diagram, however, demonstrates that although

the TDS levels in the flowback water emerging between 14 and 90 days almost

doubles to nearly reach 200,000 mg/l, the daily brine volumes produced by the well

decrease to a deminimus level that can be easily managed as a normal produced

water stream.

Table 4. Concentration of Total Dissolved Solids in Flowback Water at 19

Locations, mg/L

Location Day 0* Day 1 Day 5 Day 14 Day 90

A 990 15,400 54,800 105,000 216,000

B 27,800 22,400 87,800 112,000 194,000

C 719 24,700 61,900 110,000 267,000

D 1,410 9,020 40,700 155,000

E 5,910 28,900 55,100 124,000

F 462 61,200 116,000 157,000

G 1,920 74,600 125,000 169,000

H 7,080 19,200 150,000 206,000 345,000

I 265 122,000 238,000 261,000

J 4,840 5,090 48,700 19,100

K 804 18,600 39,400 3,010

L 221 20,400 72,700 109,000

M 371 228,000

N 735 31,800 116,000

O 2,670 17,400 125,000 186,000

P 401 11,600 78,600 63,900

Q 311 16,600 38,500 120,000

R 481 15,100 46,900 20,900

S 280 680 58,300 124,000

* Day 0 sample was taken of the influent water plus additives without sand.25 

## Figure 3. Salt Concentration and Flowback Water Flow Versus Time from

Location B

3.1.1 General Chemistry

A summary of the general chemical characteristics of the water influent streams and

the flowback water effluents associated with the completion and operation of wells of

the 19 sampling locations are presented in Tables 5-8. Characteristics of influent

water, identified as Day 0 samples, after the blending of additives (not including sand)

at each of the locations are shown in Table 5. The pH of these streams ranging from

5.2 to 8.9 is generally representative of surface waters; however, the wide range of

total dissolved solids (221 to 27,800 mg/l) reflects the implementation of water reuse26 

## Table 5. Summary of Chemical Characteristics of Influent Water(1) Used for

Hydraulic Fracturing after Additives(2) Were Blended

Parameter Range Median Units

pH 5.2 - 8.9 7.2 No Units

Acidity < 5 – 1,230 NC mg/L

Total Alkalinity 5 – 308 NC mg/L

Hardness as CaCO3 26 - 9,500 130 mg/L

Total Suspended Solids 4 - 5,290 NC mg/L

Turbidity 2.7 – 715 249 NTU

Chloride 18 - 10,700 90.2 mg/L

Total Dissolved Solids 221 - 27,800 (3) 

## 735 mg/L

Specific Conductance 177 – 34,600 726 Umhos/cm

Total Kjeldahl Nitrogen 2.3 – 400 33.5 mg/L

Ammonia Nitrogen 0.28 – 441 5.9 mg/L

Nitrate-Nitrite 0.1 – 3.1 NC

Nitrite as N < 0.05 - 5 NC mg/L

Biochemical Oxygen Demand < 2.0 – 2,220 NC g/L

Chemical Oxygen Demand 35.3 – 47,400 1,730 mg/L

Total Organic Carbon (TOC) 5.6 - 1,260 226 mg/L

Dissolved Organic Carbon 5 - 1,270 301 mg/L

Oil & Grease (HEM) 4.6 – 255 NC mg/L

Cyanide, Total 3.5 – 954 NC ug/L

Amenable Cyanide < 0.01- 0.87 NC mg/L

Bromide < 0.2 – 107 NC mg/L

Fluoride < 0.05 - 58.3 NC mg/L

Total Sulfide < 3 – 8.8 NC mg/L

Sulfate 2.9 – 2,920 NC mg/L

Total Phosphorus < 0.1 – 16 NC mg/L

Total Recoverable Phenolics < 0.01 - 0.77 NC mg/L

Sulfite < 5 – 61.6 NC mg/L

Methylene Blue Active Substances

(MBAS) < 0.03 – 0.506 NC mg/L

(1) Influent water samples are identified as Day 0; samples at 19 locations, Locations A –S.

(2) Additives included corrosion inhibitors, scale inhibitors, friction reducers, biocides, and oxygen

scavengers. Blended water samples were taken before the addition of sand.

(3) Upper end concentrations in the TDS range may be due to implementation of flowback water reuse

and blending into the influent stream.

NC - indicates the median concentration was not calculated due to undetected results.27 

## Table 6. Summary of Chemical Characteristics of Water Supplies (1) 

## used for

Hydraulic Fracturing before Additives were Blended

Parameter Range Median Units

pH 6.7 - 7.4 7.2 No Units

Acidity < 5 – 5.5 NC mg/L

Total Alkalinity 6.2 – 88.8 52.5 mg/L

Hardness as CaCO3 18 - 1,080 132 mg/L

Total Suspended Solids <2 – 24 NC mg/L

Turbidity 1.3 – 33.7 3.7 NTU

Chloride 4.1 – 3,000 35.2 mg/L

Total Dissolved Solids 35 – 5,510 (2) 

## 334 mg/L

Specific Conductance 55 – 10,100 423 umhos/cm

Total Kjeldahl Nitrogen < 3 – 56.4 NC mg/L

Ammonia Nitrogen 0.017 – 20.8 0.41 mg/L

Nitrate-Nitrite < 0.1 – 3.0 NC mg/L

Nitrite as N < 0.05 – 4.9 NC mg/L

Biochemical Oxygen Demand < 2.0 – 110 NC mg/L

Chemical Oxygen Demand < 10 – 924 NC mg/L

Total Organic Carbon (TOC) 1.8 – 202 3.4 mg/L

Dissolved Organic Carbon 1.4 – 222 3.2 mg/L

Oil & Grease (HEM) Not Detected NC mg/L

Cyanide, Total < 10 – 625 NC ug/L

Amenable Cyanide < 0.01 - 0.27 NC mg/L

Bromide < 0.2– 31.9 NC mg/L

Fluoride < 0.05 - 1.2 NC mg/L

Total Sulfide 1.6 - 5.6 NC mg/L

Sulfate 3.8 – 139 26 mg/L

Total Phosphorus < 0.1 – 0.14 NC mg/L

Total Recoverable Phenolics 0.01 - 0.031 NC mg/L

Sulfite 6 – 21.6 10.8 mg/L

Methylene Blue Active

Substances (MBAS) < 0.05 - 0.962 NC mg/L

(1) Water Supplies at 8 Locations: F, H, I, J, L, M, N, S.

(2) Upper end concentrations in the TDS range may be due to implementation of flowback water reuse

and blending into the influent stream.28 

## Table 7. Summary of Chemical Characteristics of Flowback Water Sampled 5

Days Following the Hydraulic Fracturing Event (1)



## Parameter Range Median Units

pH 5.8 - 7.2 6.6 No Units

Acidity < 5 – 447 NC mg/L

Total Alkalinity 48.8 – 327 138 mg/L

Hardness as CaCO3 5,100 - 55,000 17,700 mg/L

Total Suspended Solids 10.8 - 3,220 99 mg/L

Turbidity 2.3 – 1540 80 NTU

Chloride 26,400 - 148,000 41,850 mg/L

Total Dissolved Solids 38,500 – 238,000 67,300 mg/L

Specific Conductance 79,500 – 470,000 167,500 umhos/cm

Total Kjeldahl Nitrogen 38 – 204 86.1 mg/L

Ammonia Nitrogen 29.4 –199 71.2 mg/L

Nitrate-Nitrite < 0.1 – 1.2 NC mg/L

Nitrite as N 1.2 – 29.3 NC mg/L

Biochemical Oxygen

Demand 37.1 - 1,950 144 mg/L

Chemical Oxygen Demand 195 - 17,700 4,870 mg/L

Total Organic Carbon (TOC) 3.7 – 388 62.8 mg/L

Dissolved Organic Carbon 30.7 – 501 114 mg/L

Oil & Grease (HEM) 4.6 – 655 6.3 mg/L

Cyanide, Total < 10 - 72.1 NC ug/L

Amenable Cyanide < 0.01 - 0.032 NC mg/L

Bromide 185 - 1,190 445 mg/L

Fluoride < 0.05 – 17.3 NC mg/L

Total Sulfide < 3 – 5.6 NC mg/L

Sulfate 2.4– 106 NC mg/L

Total Phosphorus < 0.01 – 2.5 NC mg/L

Total Recoverable Phenolics < 0.01 – 0.31 NC mg/L

Sulfite 2.5 – 38 NC mg/L

Methylene Blue Active

Substances (MBAS) <0.012 –1.52 0.133 mg/L

(1) Median values at 19 locations: Locations A – S.

NC – indicates the median concentration was not calculated due to undetected results.29 

## Table 8. Summary of Chemical Characteristics of Flowback Water Sampled at

14 Days Following the Hydraulic Fracturing Event (1)



## Parameter Range Median Units

pH 4.9 – 6.8 6.2 No Units

Acidity < 5 – 473 NC mg/L

Total Alkalinity 26.1 – 121 85.2 mg/L

Hardness as CaCO3 630 – 95,000 34,000 mg/L

Total Suspended Solids 17 – 1,150 209 mg/L

Turbidity 10.5 – 1,090 233 NTU

Chloride 1,670 – 181,000 78,100 mg/L

Total Dissolved Solids 3,010 – 261,000 120,000 mg/L

Specific Conductance 6,800 710,000 256,000 Umhos/cm

Total Kjeldahl Nitrogen 5.6 – 261 116 mg/L

Ammonia Nitrogen 3.7 – 359 124.5 mg/L

Nitrate-Nitrite < 0.1 – 0.92 NC mg/L

Nitrite as N < 2.5 – 77.4 NC mg/L

Nitrate as N < 0.5 - < 5 NC mg/L

Biochemical Oxygen Demand 2.8 – 2070 39.8 mg/L

Chemical Oxygen Demand 228 – 21,900 8530 mg/L

Total Organic Carbon (TOC) 1.2 – 509 38.7 mg/L

Dissolved Organic Carbon 5 – 695 43 mg/L

Oil & Grease (HEM) < 4.6 – 103 NC mg/L

Cyanide, Total < 10 NC ug/L

Amenable Cyanide <0.01 NC mg/L

Bromide 15.8- 1,600 704 mg/L

Fluoride < 0.05 – < 50 NC mg/L

Total Sulfide < 3.0 - 3.2 NC mg/L

Sulfite (2) 

## 7.2 – 73.6 13.8 Mg/l

Sulfate <10 - 89.3 NC mg/L

Total Phosphorus < 0.1 – 2.2 NC mg/L

Total Recoverable Phenolics < 0.01 – 0.31 NC mg/L

Sulfite 7.2 – 73.6 13.8 mg/L

Methylene Blue Active

Substances (MBAS) (2) 

## <0.05 - 4.6 NC mg/L

(1) Samples were collected from 17 locations. Day 14 samples were not collected at locations D and N.

(2) Sulfite and MBAS we re not sampled at locations B and C.

NC – indicates the median concentration was not calculated due to undetected results.30 

## (i.e. the use of a portion of the flowback water from the completion of one well to

blend with the freshwater influent stream for the next well completion) at a minority of

the locations. Dissolved solids measur ements for the influent waters used for

hydraulic fracturing (with additives) had a median value of 735 mg/l, which is

considered in the range of fresh surface wa ter supplies. Interestingly, oil and grease

measurements had a range of 4.6 to 255 mg/l while total organic carbon

concentrations ranged from 5.6 to 1,260 mg/l. Elevated values in these

measurements may be due to various degrees of blending of reused waters into frac

job influent water supplies.

A summary of the same characteristics is tabulated for water supplies from 8 locations

(F, H, I, J, L, M, N, S) in Table 6; information in this table provides an indication of the

quality of influent water before the blending of additives. The data in this table

indicates that the water supply samples varied widely in quality. Total dissolved solids

ranged from 35 to 5510 mg/l, with a median value of 334. Total organic carbon content

ranged from 1.8 to 202 mg/l while biochemical oxygen demand ranged between

undetected to 110 mg/l. These widely varying results reflect the fact that, in some

cases, water used for hydraulic fracturing a prior well was re-used for a subsequent

well, with the addition of previously unused water. Oils and greases were not detected

in any of these samples, and many charac teristic parameters are representative of

typical surface water quality

Characteristics of flowback water sampled at 5 and 14 days following the hydraulic

fracturing event are presented in Tables 7 and 8, respectively. Consistent with the

profile of Figure 3, the median value of total dissolved solids for 14-day samples

(120,000 mg/l) was almost twice the median concentration value measured in the 5-

day samples (67,300 mg/l). However, the bulk of the water collected within the first 5

days had the lowest concentrations of TDS, also consistent with Figure 3. The water

is of relatively modest alkalinity, ranging between about 50 and 327 mg/l with a median

value of 138 mg/l, reflecting low carbonate concentrations which allow for very high

levels of soluble calcium which confers a very high hardness on the water as

evidenced by median hardness values of 17,700 and 34,000 mg/l for the 5-day and31 

## 14-day sample sets, respectively. Cations are dominated by sodium and calcium in

this water; anions are dominated by chloride. Levels of total organic carbon (TOC) in

the flowback water samples at 5 and 14 days (with median values of 63 and 39 mg/l,

respectively) are substantially lower (by about 75%) than the TOC of the blended

influent water with additives; a possible reason for this is that the polyacrylamide

friction reducers exert a TOC in the influent stream and are removed as water resides

in the down-hole environment. The same observation is made, though less

consistently, in comparing biochemical oxygen demand (BOD) values in flowback

water with the BOD of the influent water streams; in general, the BOD levels of the 14-

day flowback waters are less than half the influent and Day 5 BOD concentrations.

The widely varying BOD levels in the water supply and influent samples is, as stated

previously, probably reflective of flowback water re-use. The moderate levels of BOD

in the influent waters may have resulted from carbonaceous algae growth in the

source water or resulted from the biodegradable nature of the additives (e.g.

polyacrylamide friction reducing compounds). The loss of friction reducing compounds

due to adherence to surfaces downhole may be responsible for the lower BOD

concentrations in flowback waters.

General characteristics of the samples tested in this project appear very consistent

with the ranges of values reported in the li terature for normal produced waters (USGS,

2004). The large database collected by the USGS indicates that salinities for

produced waters generated among all basins can vary widely from approximately

5,000 to greater than 350,000 mg/l of total dissolved solids. Chloride is the dominant

anion in nearly all formation waters associated with petroleum and with most

conventional natural gas (Kharaka and Rice , 2004). Sodium is the most dominant

cation in most producing fields and constitutes 70 to more than 90% of total cations

(USGS, 2004). General characterization data from the waters tested at the 19

locations of this project appear consistent with much of the available compositional

information available from the USGS database. The USGS database containing

produced water characterization data from more than 60,000 wells is accessible from

the Internet at: http://energy.cr.usgs.gov/prov/prodwat/intro.htm

.32 

## 3.1.2 Organic Compounds

The organic compounds included in the characterization of water samples included the

categories of VOC, SVOC, chlorinated pesticides, organophosphorus pesticides, and

polychlorinated biphenyls. Most of the compounds in the first two categories and all

compounds in the last three categories were included on the list of analyses in

response to recommendations from PADEP and WVDEP. The following sections

summarize the results among all five of the categories of analysis.

Volatile Organic Compounds

As presented in Table 1, samples collected from Locations A through S were analyzed

for 70 volatile compounds of highly varied chemical characteristics, including the

volatile hydrocarbon constituents that ar e normally found in produced water (such as

benzene, toluene, ethylbenzene, and xylenes – or BTEX, and naphthalene) as well as

constituents not known to be associated wi th conventional produced water such as

chlorinated solvents and halogenated aromatics. A summary of the detected results

for volatile compound determinations performed is shown in Appendix D. Many of the

constituent determinations, on average, were at non-detectable levels. Appendix C

provides a summary of all of the VOC results.

Constituents that exceeded 100 ppb included components that are commonly present

in conventional produced water, such as naphthalene, BTEX, several methylated

benzene compounds and an alkylated toluene (p-isopropyltoluene). Few

determinations of these compounds exceeded 2 ppm. In the locations where BTEX

was measured at levels above 100 ppb, BTEX levels in the 5-day and 14-day flowback

waters that were in contact with the natural gas producing formation were generally

higher than BTEX concentrations in the influe nt water streams, indicating that these

compounds are naturally occurring and not the result of additives. Levels of BTEX

and methylated aromatics vary from location to location. Determination of factors that

control levels of these compounds could potentially be determined through a

correlation of the composition of volatiles and other flowback water characteristics with

the key shale gas development parameters of geographic area, depth of wells,

completion methods, etc.33 

## Very few volatile organic compounds exceeded 2 ppm among the total of the

locations. Several locations exhibited one or more of the volatile compounds that

exceeded 1 ppm. Two ketones were measured in a very limited number of samples;

acetone and 2-butanone (also known as methyl ethyl ketone or MEK), were found at

measurable concentrations. These compoun ds are well known solvents in industry

that are used for cleaning purposes. In a few samples, carbon disulfide was

measured. In the manufacture of some types of polymers, carbon disulfide is useful in

the promotion of nucleophilic attack in polymer synthesis; this compound may be a

residual reactant from the manufacture of polymers used as friction reducers.

However, carbon disulfide was only measured in a few samples examined at a limited

number of locations.

Semivolatile Organic Compounds

A total of 112 semi-volatile organic compounds (as listed in Table 1) were included in

the analysis of influent water and in flowback water samples. A summary of the

detected results of semivolatile determinations in these samples is presented in

Appendix D. More than 98% of the constituent determinations, on average, were at

non-detectable levels and less than 0.03 percent of all the constituents were above 1

ppm. Several constituents were measured in any of the samples at levels exceeding

10 ppb. Acetophenone and aniline are commonly associated with fossil fuels, as are

the methylated phenols. Only two compounds, bis (2-chloroethyl) ether and pyridine,

were measured at levels greater than 1 ppm. The only compound that was measured

at a level above 1 ppm more than once was pyridine. Pyridine is a nucleophile that is

used widely in the manufacture of certain types of chemicals and pharmaceuticals and

its presence may be due to its use as a prec ursor in the manufacture of one of the

hydraulic fracturing additives.

In general, nearly all of the SVOC determinations were either non-detect or at low

trace levels. Detected SVOC constituents are summarized in Appendix D. Appendix

C provides all the SVOC reported results.34 

## Pesticides

Determinations of the 20 chlorinated and th ree organophosphorus pesticides listed in

Table 1 were conducted on the influent, 14-day and 90-day flowback water samples.

Results from the measurements of pesticides in all samples are summarized in

Appendix C. Pesticide concentrations measured in samples were extremely low (all

samples were less than 1 ug/l.) and random with results occurring in some of the water

supply, Day 0, Day 14 or Day 90 samples collected. It is possible that these low level

concentrations are not representative of ac tual conditions and are attributed to

laboratory contamination or instrument noise. Appendix C summarizes the pesticides

results. Appendix D provides a summary of the detected pesticide results.

Polychlorinated Biphenyls (PCBs)

Determinations of the 7 polychlorinated biphenyl compounds (Aroclors) listed in Table

1 were conducted on the influent, 14-day and 90-day flowback water streams.

Aroclors were not detected in any sample, except for Aroclor 1248 that was detected

at 8 ug/L in the Day 14 sample at Location R. The detected PCB result is summarized

in Appendix D. Appendix C summarizes the all of the PCB results.

3.1.4 Metals

A summary of metal concentrations in the influent water stream (with additives) and

the 5-Day Flowback water samples across all 19 locations is presented in Table 9; all

concentrations in this table are reported in units of μg/l (ppb). As seen in this table,

sodium is the major cation in all of the samples, followed by concentrations in some

samples of calcium, magnesium and barium that will need to be monitored for

purposes of scale control in some locations. Since strontium is present in flowback

waters at concentrations between 345 to 4,830 mg/l in the 5-day flowback samples, it

will be important for operators to implement procedures to prevent the formation of

strontium-bearing scale. Iron levels in the range of 21 to 180 mg/l may also need to be

watched and mitigated in order to prevent operational difficulties at a number of well

completion locations.

Heavy metals of toxicological concern that are often associated with urban industrial

activity (including chromium, copper, nickel, zinc, lead, cadmium, mercury and arsenic)35 

## are at very low levels in all of the shale gas water samples compared to levels

reported for municipal wastewaters. Table 10 presents range values from the 5-Day

Flowback samples which are compared to median heavy metals concentrations

measured in sewage sludges (biosolids) generated by Penn State for the State of

Pennsylvania (Stehouwer, 2000); note that concentrations in this table are reported in

mg/l. The comparison shows that the levels of heavy metals of concern are 100 to

10,000 times higher in municipal biosolids (sewage sludges that are routinely

transported across communities to disposal sites) than the levels measured in shale

gas waters.36 

## Table 9. Total Metals Concentrations in the Influent Water and 5-day Flowback

Water Obtained from 19 Locations

-- Influent Water -- -- 5-Day Flowback --

Parameter Range Median Range Median Units

Aluminum ND – 1,030 B NC ND - 47,200 J NC ug/L

Antimony ND - 21.6 BJ NC ND - 47.2 B NC ug/L

Arsenic ND - 9.1 B NC ND – 124 NC ug/L

Barium 63.1 BJ - 87,100 410 21,400 J - 13,900,000 686,000 ug/L

Beryllium ND – 3 B NC ND NC ug/L

Boron ND - 40,700 J NC 3,140 J - 97,900 12,200 ug/L

Cadmium ND - 10.5 NC ND - 9.6 B NC ug/L

Calcium 6,690 BJ - 2,990,000 32,900 1,440,000 J - 23,500,000 J 4,950,000 ug/L

Chromium ND - 704 NC ND - 152 NC ug/L

Chromium +3 ND – 4.8 B NC ND – 67.4 NC ug/L

Chromium +6 ND ND ND NC ug/L

Cobalt ND - 11.9 B NC ND NC ug/L

Copper ND – 120 B NC ND - 4,150 NC ug/L

Iron 137 B - 14,300 1,180 21,400 - 180,000 39,000 ug/L

Lead ND - 111 NC ND - 606 NC ug/L

Lithium ND - 14,900 JE NC 10,600 - 153,000 43,700 ug/L

Magnesium 1,250 B - 235,000 6,740 135,000 - 1,550,000 559,000 ug/L

Manganese ND - 3,640 NC 881 - 7,040 2,630 ug/L

Mercury ND - 0.66 BJ NC ND - 0.24 J NC ug/L

Molybdenum ND - 91.8 B NC ND – 147 B 33.1 ug/L

Nickel ND - 457 NC ND – 187 B NC ug/L

Potassium 2250 B - 229,000 E 42,600 48,900 B - 2,430,000 301,000 ug/L

Selenium ND - 35.3 B NC ND NC ug/L

Sodium 25,700 B - 6,190,000 67,800 10,700,000 - 65,100,000 18,000,000 ug/L

Strontium 58.5 BJE - 439,000 E 768 345,000 – 4,830,000 1,080,000 ug/L

Thallium ND -19.8 B NC ND – 24.6 B NC ug/L

Tin ND - 6.9 B NC ND - 25.7 B NC ug/L

Titanium ND - 39.1 B NC ND – 313 B NC ug/L

Zinc ND - 1,610 E NC 67.6 BJ – 2,930 J 172 ug/L



### * Influent Water is the supply water containing hydraulic fracturing additives, but without sand. Influent samples are

identified as Day 0 samples.

ND Not detected

NC – Indicates the median concentration was not calculated due to undetected results.

B Analyte was also detected in the method blank for that sample

J Estimated concentration for analyte detected between the method detection level and the reporting limit

G Analyzed at a diluted concentration due to matrix effects

E The concentration exceeds the linear range of the instrument. The result is considered estimated.37 

## Table 10. Comparisons of Metals Levels in Shale Gas Waters with Municipal

Biosolids (Sewage Sludge)

Metal 5-day Flowback

Range Sewage Sludge* Units

Chromium ND – 0.152 35 mg/L

Copper ND – 4.150 511 mg/L

Nickel ND – 0.187 B 22.6 mg/L

Zinc 0.068 – 2.93 J 705 mg/L

Lead ND – 0.606 65 mg/L

Cadmium ND – 0.096 B 2.3 mg/L

Mercury ND – 0.00024 J 1.5 mg/L

Arsenic ND – 0.124 3.6 mg/L

* Penn State study reporting median heavy metal content values for Pennsylvania publicly owned treatment works

(POTW) biosolids (Stehauwer, et al., 2000).

ND – Not detected



# 4.0 Implications for Fate and Transport

As seen in Table 1, the list of measurements and determinations that were pursued in

this study were very exhaustive but highly useful in establishing an information base to

define a chemical fingerprint associated with flowback waters from this geologic

formation. Much of the expense and time required for water characterization has

arisen from the extensive effort to analyze the samples for large numbers of volatile

and semivolatile organic compounds suggested by PADEP and WVDEP (including

chlorinated pesticides, organophosphorus pesticides and polychlorinated biphenyls);

the information base developed in this project strongly suggests that this level of water

characterization in the future is not necessary and that monitoring should be focused

on measuring constituents that are likely to be present. A number of observations

that are relevant to fingerprinting and to t he fate and transport of constituents can be

made from consideration of the information ba se assembled from the first 19 locations.38 

## First, there is clear indication that halogenated hydrocarbon compounds (among

volatile, semivolatile, pesticides and PCB categories) and nearly all of the polynuclear

aromatic hydrocarbons (of 3 rings and above) are not a part of typical components in

flowback waters. Volatile and semivolatile organic constituents that are normally found

at low levels in conventional produced wa ters, such as BTEX, methylated benzenes,

naphthalene, naphthenic acids, volatile acids, simple alkanes, etc., are also found in

flowback waters and in influent waters for frac jobs that utilize flowback water reuse.

However, in terms of fate and transport in the environment, many volatile and

semivolatile organics present in shale gas waters are at modest concentrations (most

compounds are below 1 ppm). The challenge, therefore, is to choose an alternate

parameter that can be used to quickly detec t any small release of flowback water that

may occur in the course of storage or handling.

A more practical approach might be to use chloride analyses of samples to monitor

fate and transport of flowback/produced waters. Chloride has been used as a

conservative tracer in hydrogeochemical studies for decades and is well documented

in the literature (Clement et al., 2000; Farrell et al., 1994; Lamontagne et al., 2005;

Negrel and Lachassagne, 2000; Nelson et al., 2001; Paine, 2003; van Breukelen et al.,

1998). A general overview of the processes controlling the movement of solutes in the

subsurface is provided below.

Fate and transport of constituents in the soil/rock/water system is governed by four

fundamental processes: advection, dispersion, retardation, and decay. Advection is

simply the mass movement of a solute along with groundwater and is modeled by

Darcy’s Law. Dispersion is a mathematical description of diffusion and mechanical

mixing of a solute in a system. Diffusion is modeled using Fick’s first and second law.

Dispersion is an empirical correction factor co ntrolled by the physical properties of the

soil/rock matrix (porosity, gr ain size, sorting, etc) and scale of the system. Retardation

is the process by which non conservative so lutes interact with the soil/rock and their

movement downgradient is subsequently slowed. It is modeled by a linear equation

that is a function of porosity, moisture content, bulk density, and the humic organic

matter content. Examples of retardation reactions are adsorption-desorption, ion39 

## exchange, precipitation-dissolution, and oxidation-reduction reactions. Decay is the

process by which a solute is removed from the system due to chemical reactions,

biological reactions, and/or radioactive decay and is modeled using the appropriate

equation for the reaction occurring in the system.

Conservative solutes are ones that can be modeled using only advection and

dispersion. Common examples are chloride and bromide, but bromide levels in the

samples collected as part of this study were several orders of magnitude lower than

chloride levels. Non-conservative solutes can only be modeled using advection,

dispersion, retardation, and/or decay. Examples of non-conservative solutes are

volatile/semivolatile organics (e.g. benzene, toluene, PAHs, PCBs, etc.), sulfate, iron,

and many others. Non-conservative spec ies subsequently migrate slower throughout

the subsurface than do conservative tracers and therefore are inappropriate to use as

indicators of Marcellus Shale flowback water impact to a system. Nearly all classes of

volatile and semivolatile organics discussed in this report have been shown to be

sequestered to various types of soils, thereby significantly retarding their mobility in the

environment (Linz and Nakles, 1997).

Chloride, on the other hand, is more mobile and has considerable potential as an early

sentinel indicator of flowback water impacts due to a number of advantages. In

addition to being conservative (by virtue of its non-volatile, non-sequestering, nonreactive property), chloride is usually present in relatively high concentrations ranging

from 10,000 to 200,000 mg/l, ten to a hundred times the concentration of most

inorganics and more than a million times the levels of most volatile and semivolatile

organic constituents. Chloride is also easily measured with field kits that can

determine the presence of this anion with small samples, and verified in its presence

with simple conductivity instruments. Due to its high concentration and its ubiquitous

presence in flowback waters, chloride anion is an excellent monitoring tool for even the

smallest leaks of flowback water into the environment.40 

# 5.0 Conclusions

With the completion of this sampling and analysis effort, the following conclusions can

be drawn from the results:

1. General chemistry characterization of flowback water indicates that values for

pH, alkalinity, total dissolved solids, total organic carbon, oils and greases and

other parameters from general water characterization are well within the normal

ranges reported for conventional produced waters. Flowback water appears

similar in composition to conventional produced water, even in the presence of

additives employed for performing hydraulic fracturing.

2. Shale gas flowback water cations are dominated by sodium and calcium;

anions are dominated by chloride.

3. Metals in flowback water are well within the ranges for normal produced waters.

Industrial heavy metals (e.g. chromium, copper, nickel, zinc, lead, cadmium,

arsenic and mercury) are a small fraction (less than 1 percent) of the heavy

metals content in municipal biosolids generated from POTW’s.

4. Among volatile organic constituents, approximately 96% of these constituents

were found at non-detectable levels and 0.5% were above 1 ppm for any of the

5 sampling events among 19 locations. The data indicate that the constituents

above 1 ppm are those that are a normal part of produced waters associated

with natural gas operations (such as xylenes, toluene and naphthalene).

5. Among SVOC, more than 98% of all determinations were at nondetectable

levels and 0.03% of these constituents were above 1 ppm.

6. Low levels (less than 1 ug/l) and the random distribution of chlorinated and

organophosphorus pesticides suggest th at these compounds are laboratory

artifacts and are not contained in flowback water.41 

## 7. Only one PCB (Aroclor 1248) was detected in all the samples analyzed. This

result should be considered an anomaly.

8. Virtually, all halogenated organic compounds were at non-detect levels. This

strongly suggests that additives that are blended with influent waters do not

contain concentrations of organic chemicals of concern.

9. The results of this shale gas water characterization effort indicate that

pesticides, PCBs, and a large fraction of the volatile and semivolatile

constituents should be considered to be unnecessary for the sampling and

analysis of flowback waters in the future.

10. Determination of factors that affect levels of organic and inorganic compounds

could potentially be determined through a correlation of flowback water

composition with the key shale gas development parameters of geographic

area, depth of wells, completion methods, etc.42 

# 6.0 References Cited

APHA. 1992. “Standard Methods for the Examination of Water and Wastewater”, 18 th



## Edition (SM18).

APHA. 1999. “Standard Methods for the Examination of Water and Wastewater”, 20 th



## Edition (SM20).

Clark, C.E. and J.A. Veil. 2009. Produced Water Volumes and Management

Practices in the U.S. USDOE/Argonne Laboratories Report No. ANL/ EVS/R-09/1.

Clement, T.P., Johnson, C.D., Sun, Y., Klecka, G.M., and Bartlett, C., 2000, Natural

attenuation of chlorinated ethene compounds; model development and field-scale

application at the Dover site: Journal of Contaminant Hydrology, v. 42, p. 113-140.

Engelder, T., and G.G. Lash. 2008. Marcellus Shale Play’s Vast Resource Potential

Creating a Stir in Appalachia. The American Oil & Gas Reporter, May.

Farrell, D.A., Woodbury, A.D., and Sudicky, E.A., 1994, The 1978 Borden tracer

experiment; analysis of the spatial moments: Water Resources Research, v. 30, p.

3213-3223.

Gaudlip, A.W., L.O. Paugh, and T.D. Hayes. 2008. Marcellus Shale Water

Management Challenges in Pennsylvania. SPE Paper No. SPE–119898-PP, Society

of Petroleum Engineers.

Kharaka, Y.K. and C.A. Rice. 2004. “Organic and Inorganic Species in Produced

Water: Implications for Water Reuse”, Proceedings of the Natural Gas Technologies

Conference, Phoenix, Feb 8-10. Available from the Gas Technology Institute,

Lamontagne, S., Leaney, F.W., and Herczeg, A.L., 2005, Groundwater-surface water

interactions in a large semi-arid floodplain; implications for salinity management:

Hydrological Processes, v. 19, p. 3063-3080.

Linz, D.G. and D.V. Nakles. 1997. Environmentally Acceptable Endpoints in Soil.

American Academy of Environmental Engineers, United Book Press, Inc., Baltimore,

MD.

Negrel, P., and Lachassagne, P., 2000, Geochemistry of the Maroni River (French

Guiana) during the low water stage; implications for water-rock interaction and

groundwater characteristics: Journal of Hydrology, v. 237, p. 212-233.

Nelson, M.D., Parker, B.L., Al, T.A., Cherry, J.A., and Loomer, D., 2001, Geochemical

reactions resulting from in situ oxidation of PCE-DNAPL by KMnO (sub 4) in a sandy

aquifer: Environmental Science & Technology, v. 35, p. 1266-1275.

Paine, J., 2003, Determining salinization extent, identifying salinity sources, and

estimating chloride mass using surface, borehole, and airborne electromagnetic

induction methods: Water Resources Research, v. 39, p. 10.43 

## Stehouwer, R.C., A.M. Wolf, and W.T. Doty. 2000. “Chemical Monitoring of Sewage

Sludge in Pennsylvania: Variability and Application Uncertainty.” J. Environ. Qual. 29:

1686 – 1695.

USEPA. 1984. “Methods for Organic Chemical Analysis of Municipal and Industrial

Wastewater”, 40CFR, Part 136, Appendix A, October 26.

USEPA. 1983. “Methods for Chemical Analysis of Water and Wastes”, EPA- 600/4-79-

020, March.

USEPA. 1986. Test Methods for Evaluating Solid Waste, Physical/Chemical

Methods”, Third Edition, November (SW846).

USGS. 2009. USGS Produced Water Database. Available at:

http://energy.cr.usgs.gov/prov/prodwat/intro.htm

.

van Breukelen, B.M., Appelo, C.A.J., and Olsthoorn, T.N., 1998, Hydrogeochemical

transport modelling of 24 years of Rhine water infiltration in the dunes of the

Amsterdam water supply: Journal of Hydrology, v. 209, p. 281-296.44 

# Disclaimer

This report was prepared by the Gas Technology Institute (GTI) as an account of work

funded by the Marcellus Shale Coalition (MSC). Neither GTI nor any person acting on

behalf of GTI:

1. Makes any warranty or representation, express or implied with respect to the

accuracy, completeness, or usefulness of the information contained in this

report, or that the use of any information or method disclosed in this report may

not infringe privately-owned rights, or

2. Assumes any liability with respect to the use of, or for any and all damages,

resulting from the use of, any information or method in this report.45 

# Appendix

		
		
				


		
					

		
	 	!	" 	#	$		%

	!	
	
	#	!	&"'	
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# Appendix A

Field Sampling and Analysis Plan (FSAP)

# FIELD SAMPLING AND ANALYSIS PLAN

DEVONIAN SHALE FLOW BACK WATER

CHARACTERIZATION STUDY

Prepared by

Appalachian Shale Water Conserva tion and Management Committee

December 2008

## TABLE OF CONTENTS

1.0 INTRODUCTION ................................................................................................... 3

1.1 PURPOSE ............................................................................................................ 3

1.2 DATA OBJECTIVES .......................................................................................... 3

1.3 BACKGROUND.................................................................................................. 3

2.0 CHARACTERIZATION STUDY OF FLOW BACK WATER ............................. 5

2.1 Sampling and Analyses ........................................................................................ 5

3.0 SAMPLING PROTOCOLS ..................................................................................... 7

3.1 PROJECT INITIATION ...................................................................................... 7

3.2 DOCUMENTATION ........................................................................................... 7

3.2.1 Field Logbook ............................................................................................... 7

3.2.2 Chain-of-Custody Form ................................................................................ 8

3.3 SAMPLE DESIGNATION AND IDENTIFICATION ....................................... 8

3.4 SAMPLE MANAGEMENT AND SHIPMENT ................................................. 9

4.0 SAMPLING EQUIPMENT AND PROCEDURES .............................................. 10

5.0 INVESTIGATION DERIVED WASTE ............................................................... 11

5.1 MANAGEMENT OF HAZARDOUS IDW ...................................................... 11

6.0 REFERENCES ...................................................................................................... 12

Tables

1 Summary of Extensive List of Constitue nts of Interest, EPA Methods, Reporting

Limits and Holding Times.

2 Summary of List of Constituents Based on Generator Knowledge, EPA Methods,

Reporting Limits and Holding Times

## 1.0 INTRODUCTION

This Field Sampling and Analysis Plan (SAP) de tails the procedures for sampling and

field documentation to be utilized for the characte rization study of the fracturing and flow

back fluids associated with the Devonian shale. The FSAP has been prepared to ensure

that all data and information gathered are properly sampled, documented, and technically

sound. The FSAP and Quality Assurance Project Plan (QAPP) together comprise the

Sampling and Analysis Plan (SAP).

1.1 PURPOSE

The FSAP includes a detailed description of field sampling procedures to be conducted.

The procedures described are consistent with the RCRA Technical Enforcement

Guidance Document (TEGD), U.S. EPA, 1989; RCRA Facility Investigation Guidance

Document (U.S. EPA, May 1989); RCRA Ground Water Monitoring; Draft technical

Guidance (U.S. EPA, 1992); Data Quality Object ives for Remedial Response Activities

(U.S. EPA, 1987).

The SAP consists of 5 sections. Secti on 1.0 includes a brief description of the data

objectives and a brief discussion of the project. 2.0 provides information regarding

documentation, quality assurance/quality c ontrol (QA/QC) requirements, and reporting.

Section 3.0 addresses the sampling procedures. Section 4.0 describes the proper handling

requirements of any investigative derived waste generated. Reference documents are

provided in Section 5.0

1.2 DATA OBJECTIVES

The data objectives will address characteriz ation of the fracturing and flow back fluids

associated with the development of the Devonian shale. This characterization study will:

Identify the specific constituents of int erest (COI) associated with flow back

water;

Reduce/eliminate the allegations that th e chemicals used for fracturing will

contaminate groundwater; and

Provide sufficient information for the selection of proper disposal techniques.

Achieving these data objectives will require obtaining data of acceptable levels of

certainty. Therefore, it is essential that the field and sampling procedures be completed

under stringent and appropriate methods.

1.3 BACKGROUND

The process of developing Devonian Shale we lls requires increasing the number of

fractures and extending the existing fractures. Fracturing is necessary to obtain a greater

volume of natural gas from the Devonian Shale at in a cost-efficient manner. Fracturing

uses high volumes and high-pressure chemically treated water or a gel to induce fractures

## in the shale surrounding the well bore. Most applications require between 500 and 10,000

psi.

Fracturing is done by isolating off a portion of the well and injecting chemically treated

water or gel and sand with cement, perforating, under very high pressure into the isolated

portion of the well bore. Generally, 1.5 to 5 million gallons of water is pumped into the

formation of a vertical or horizontal well, respectively. The high pressure fractures the

shale and sand keeps the fractures open. A drop in pressure indicates that the formation

has accepted water.

To prevent the fractures from closing when the pressure is reduced several hundred tons

of sand or other propant is pumped down the well and into the pressurized portion of the

well. When the fracturing occurs the sand is forced into the fractures. If enough sand is

trapped in the fractures it will prop the frac tures open when the pressure is reduced. The

propped fractures provide an increase in the permeability for gas flow.

Approximately 25 to 30 percent of the wa ter used in fracturing is recovered. This flow

back water is currently a concern beca use there is a limited amount data. The ASMCWC

is conducting this study in an effort to char acterize the flow back water associated with

the Devonian Shale.

The flow back water will be collected in either an on-site off-stream temporary

impoundment or a series of frac tanks.

## 2.0 CHARACTERIZATION STUDY OF FLOW BACK WATER

Fracturing is completed over several days depending on the geological formation.

Because the flow back water is under pressure, initially the flowback water is recovered

at a faster rate in the beginning of fracturing and significantly declines as facturing

continues and the well is released to production. The initial concentrations at the start of

fracturing (high yields of flow back wa ter) should yield lower concentrations of

constituents of interest (COI). It is assumed that the concentration of the fracturing

chemicals remain constant throughout the f low back regardless of the rate of return.

However, the increase concentration of in th e COI is due to a longer residence time in the

applicable formation and not associated to the additives of the fracing fluids.

Therefore, to obtain representative samples of the flow back water samples will be

collected on three separate days (i.e., days 1, 5 and 14). The data obtained from day 14

should represent the chemical character istics of the natural formation fluid.

Additionally, a baseline sample of the fracturin g fluid will be collected prior to injection.

The baseline sample will contain the materials (e.g., water and chemicals) used in the

fracturing process. A sample will also be collected from a well in Devonian shale that

has been in production for a period of time (i.e., a well that has been in production for

more than 3 months). The data obtained from this well should represent the chemical

characteristics of the natural formation fluid. The analytical results associated with these

samples will assist in the data interpretation.

2.1 Sampling and Analyses

In general, several frac tanks are connec ted in-line and filled simultaneously with the

flow back water. This is completed to avoid back pressure when shutting one frac tank

and opening another tank for additional cap acity. This filling process will provide a

composite sample of the flow back water ov er time. To minimize volatilization, a

representative composite sample of the flow back water samples will be collected from

the top of a frac tank or flow back impoundment.

The flow back water is either pumped into the frac tanks for storage until the water is

disposed of properly. If a project does have an impoundment that stores flow back water

on site in an impoundment, a grab sample will be collected from the impoundment

following day 1, 5 and 14 of fracturing.

The base fracturing fluid will be collected pr ior to going down hole. The base fracturing

fluid will be collected from either the sampling li nes built into the blenders or as a grab

sample from the blending containers. In either case a representative sample of the fluid

will be collected.

Numerous flow back water samples will be collected from several unique locations.

Phase one of this characterization study will include the sampling of six flow back water

samples from six unique locations.

## The list of constituents recomm ended for the characterization study was developed from

comments received from the Pennsylvania Department of Environmental Protection

(PADEP), the West Virginia Department of Environmental Protection (WVDEP) and

members of the ASWCMC. Because the reco mmended list of constituents is extremely

extensive, it was decided that one sample from each site will be completed for the full list

of recommended constitue nts (Table 1). All other samples will be sampled for a subset

of these constituents (Table 2), w hich are based on generato r knowledge and Group 1 and

Group 2. The analytical results of phase one of the characterization study will determine

the list of constituents of subsequent sampling events.

## 3.0 SAMPLING PROTOCOLS

This section identifies the protocols to be implemented during field sampling.

Specifically this section describes the pr eparation, documentation, and reporting

procedures to be used that will assure qua lity assurance and quality control.

3.1 PROJECT INITIATION

Following acceptance of this plan by the ASWCMC and the state agencies, Gas

Technology Institute (GTI) will authorize Te st America an independent a credited

analytical laboratory to provide the appropria te sample containers and preservatives; and

URS, an independent environmental consulting company has been retained to collect the

flow back water. Furthermore, Test America will complete the analytical analyses. Test

America is certified by WVDEP and PADEP.

The regulatory agencies are invited to collect split samples. The samples will be

collected at the discretion of the agency. All agency sampling must be approved and

coordinated with the appropriate gas company.

3.2 DOCUMENTATION

A field logbook and chain-of-custody form will be utilized during the field activities.

3.2.1 Field Logbook

During field activities, a site-specific logbook will be used for documentation of all notes.

It is recommended that each page of the logbook be numbered a nd dated. The entries

should be legible and contain accurate and inclusive documentation of the project

activities. Once completed, the logbook becomes an accountable document and is

maintained as part of the project file. The logbook should include, at a minimum, the

following information:

Identification of logbook ownership and telephone number on the inside front

cover;

Well location and identifying number;

Names of field personnel at the site;

Weather information (general);

Sample locations and activities;

Sample collection equipment;

Date and time of monitoring of sampling;

Water quality measurements (field pH, spe cific conductance, water temperature);

Field instrument calibration information;

Visual observations;

Collection of field quality assu rance samples (i.e., blanks or duplicates);

Regulatory agency personnel observing sampling;

## Enter agency, collector’s name, samples splits, etc ., if a regulatory agency splits

samples; and

Documentation of sample shipment dates, time, a nd carrier tracking (air bill)

number, if necessary.

Copies of the field book pages will bec ome part of the sample data package.

3.2.2 Chain-of-Custody Form

The chain-of-custody form is used to reco rd the custody of all samples collected. This

chain-of-custody form documents transfer of the custody from the sampling personnel to

another person, to the laboratory, or to another party, such as a courier delivery service.

The chain-of-custody form also serves as a sample logging mechanism for the laboratory

sample custodian.

When the field personnel sends samples to the analyt ical laboratory, each cooler chest

containing samples must be accompanied by a chai n-of-custody form. These forms

contain the following information pertaining to the samples:

Project Name

Name(s) and signature(s) of the individual(s) collection the samples;

Sample location;

Date and time of sample collection;

Total number of sample containers per sample location;

Type of sample preservation used (e.g., HNO 3 

## , HCl, etc.)

Analytical parameters of interest for each sample and number of containers per

analytical parameter;

Remarks or observations;

Signature(s) of all individual(s) relinquishing and receiving custody of the

samples;

Name of the carrier shipping the samples; and

Air bill number under which sample c ontainers(s) was sent, if applicable;

The chain-of-custody forms are multi-colored carbon copy forms. The original copy

(white) is submitted to the laboratory with the samples, the second copy (pink) is sent to

GTI, and the third (yellow) is kept for the project files.

3.3 SAMPLE DESIGNATION AND IDENTIFICATION

Each sample collected for this characterizati on study will be assigned a unique sample

tracking number. The identification of the we ll location and participating gas company

will not be identified. All well locations will be blind. GTI will assign each well a

project identifier. The project identifie r will be a unique single alphanumeric letter that

will identify the Devonian Shale well locati on and company. This unique alphanumeric

letter will be provided to the third party e nvironmental consultants to be used in the

sample designation.

## 3.4 SAMPLE MANAGEMENT AND SHIPMENT

The possession of samples or other physical evide nce shall be traceable from the time the

samples are obtained until they have been submitted to the analytical laboratory. To

simplify the documentation of possession that is maintained on the chain-of-custody

form, the number of people who handle the sample during the investigation should be

minimized. All samples will be documente d in the field logbook, on the chain-ofcustody form and on the sample container la bels. Field documentation procedures are

provided above in Section 2.3 and the in the QAPP.

Sample labels shall be completed for each sample using waterproof non-erasable ink. All

samples are to be sealed immediately upon c ollection and are to be immediately place on

ice in a cooler.

Samples are to be properly packaged for shipment and delivery to the laboratory. To

ensure that the samples are kept cold for pres ervation requirements, the samples are to be

shipped in iced coolers for overnight delivery. Samples collected during the

characterization study are to be classified as environmental samples.

Shipping containers are to be secured with tape and use of security seal method to ensure

that the cooler may not be opened without evidence of the seal being tampered.

Ice used to keep the samples cooled must be secured in plastic bags (e.g., Zip-Lock®

plastic bags) to ensure that melted ice does not cross contaminate the samples pr leak

from the coolers.

Samples will be either hand delivered to the laboratory or shipped via priority service to

the laboratory or the air bill retained for the project file.

## 4.0 SAMPLING EQUIPMENT AND PROCEDURES

Grab samples will be conducted using a new PVC bailer from the top of the frac tank.

The order, in which the grab samples are collected, as prioritized to the sensitivity to

volatilization, is as follows:

Volatile Organics

Purgeable Organics

Purgeable Organic Halogens

Total Organic Halogens

Total Organic Carbon

Extractable Organics

Total Metals

Dissolved Metals

Phenols

Cyanide

Sulfate and Chloride

Turbidity

Nitrate and Ammonia

There is not an order of preference for the collection of the remaining conventional

parameters.

Temperature, pH, dissolve ox ygen, and specific conductance measurements will be

completed in the field

## 5.0 INVESTIGATION DERIVED WASTE

Materials which may be investigation derived waste (IDW) are:

Personnel protective equipment (PPE), including disposable gloves, coveralls,

booties, etc.;

Disposable equipment, including plastic g round and equipment covers, aluminum

foil, Composite liquid waste samplers (COLIWASAs), used sample containers,

tape, etc.;

5.1 MANAGEMENT OF HAZARDOUS IDW

If wastes are suspected to be hazardous, appropr iate analysis must be performed to make

that determination. The analytical testing should meet the requirements of the potential

disposal characterization requirements. If the IDW is determined to be hazardous wastes

either through testing of characteristics or as a listed waste, they must be properly

container and labeled. They may be stored on si te for a maximum of 90 days before they

must be manifested and shipped to a permitted treatment of disposal facility.

Care should be taken to keep non-hazardous materials segregated from hazardous wastecontaminated materials.

## 6.0 REFERENCES

Kitrell, F.W. 1990. A Practical Guide to Water Quality Studies.

U.S. EPA, 1986. Test Methods for Evaluating S olid Waste, Volume II; Field Manual,

Physical/Chemical Methods. Office of Solid Waste and Emergency Response, SW-846,

November 1986

U.S. EPA 1987. Data Quality Objectives for Remedial response Ac tivities. Oswer

Directive 935507B, Office of Emergency and Remedial Response, Washington DC.

EPA/5406/6=87/100 and 004.

U.S. EPA, 1986. RCRA Ground-Water T echnical Enforcement Guidance Document.

Office of Waste Programs Enforcement, Washington DC, Oswer Directive 99501.

U.S. EPA, 1992. RCRA Groundwater Monitoring: Dr aft Technical Guidance. Office of

Solid Waste, Washington DC. EPA/530/R-93/001.

U.S. EPA, 1998. Environmental Investigations S tandard Operating Procedures and

Quality Assurance Manual. U.S. EPA Region 4, Athens, GA, May 1996.

# Appendix B

Quality Assurance Project Plan (QAPP)

# QUALITY ASSURANCE PROJECT PLAN

DEVONIAN SHALE FLOWBACK WATER

CHARACTERIZATION STUDY

Prepared by

Appalachian Shale Water Conserva tion and Management Committee

November 2008

## TABLE CONTENTS

1.0 PURPOSE 3

2.0 PROJECT DESCRIPTION 4

2.1 SCOPE OF WORK 4

3.0 QUALITY ASSURANCE OBJECTIVES FOR MEASUREMENT DATA 5

3.1 DATA QUALITY LEVELS 5

3.2 QUALITY CONTROL PARAMETERS 6

4.0 SAMPLING PROCEDURES 8

4.1 SAMPLE IDENTIFICATION 8

4.2 SAMPLE CONTAINERS 9

4.3 FIELD QA/QC SAMPLES 9

4.3.1 Trip Blanks 9

4.3.2 Equipment Blanks 10

4.4 DOCUMENTATION 10

5.0 SAMPLE CUSTODY 11

6.0 ANALYTICAL PROCEDURES 12

7.0 CALIBRATION PROC EDURES AND FREQUENCY 13

7.1 PREPARATION OF STANDARDS 13

7.2 CORRECTIVE ACTION 13

8.0 DATA EVALUATION/VALIDATION 15

8.1 FIELD DATA VALIDATION 15

8.2 LABORATORY DATA VALIDATION 15

8.3 INDEPENDENT DATA VALIDATION 16

8.4 DATA REPORTING 16

8.4.1 LEVEL I REPORTING 17

8.4.2 LEVEL II REPORTING 17

8.4.3 LEVEL III REPORTING 17

9.0 QUALITY CONTROL PROCEDURES 19

9.1 FIELD QC CHECKS 19

9.1.1 EQUIPMENT BLANKS 19

9.1.2 TRIP BLANKS 19

## 9.2 INTERNAL LABORATORY QC CHECKS 20

9.2.2 Preparation/Method Blanks 20

9.2.3 Matrix Spike And Duplicate (Or Ma trix Spike Duplicate) Analysis 21

9.2.4 Surrogate Spike Standard Performance Evaluation 21

9.2.5 Calibration Check Compounds And Reagent Blanks 21

10.0 PERFORMANCE AND SYSTEM AUDITS 22

10.1 PERFORMANCE AUDITS 22

10.1.1 Laboratory Performance Audits 22

10.2 SYSTEM AUDITS 22

10.2.1 Laboratory System Audits 22

11.0 ASSESSMENT PROCEDURES FOR DATA ACCEPTABILITY 23

11.1 PRECISION 23

11.2 ACCURACY 23

11.3 COMPLETENESS 23

11.4 QUALITY CONTROL CHARTS 24

12.0 PREVENTIVE MAINTENANCE 25

12.1 FIELD 25

12.2 LABORATORY 25

13.0 CORRECTIVE ACTION 26

14.0 QA REPORTS TO MANAGEMENT 27

FIGURE

1 Chain of Custody Record

TABLES

1 Summary of Extensive List of Constituents of Interest, Reporting Limits, and Holding

Times

2 Summary of List of Constituents Based on Ge nerator Knowledge, Reporting Limits, and

Holding Times

## This document is the Quality Assurance Project Plan (QAPP), which provides specific quality

assurance/quality control (QA/QC) procedures to be executed and supported for the

Characterization Study of the flow back water associated with the well fracturing of the

Devonian Shale.

Data generated for environmental purposes must be tec hnically sound and legally defensible, and

supported by defined and ve rified limits of confidence. Therefore, the objective of this QAPP is

to ensure the generation of accurate, precise, rep resentative and complete data. The QAPP sets

forth the data collection procedures a nd data evaluation processes, which will ensure that

appropriate levels of data quality are obtained.

Analyses must meet the QA/QC requirements a ssociated with this QAPP and the following

documents:

SW-846, Third Edition (September 1986), as amended by updates 1 (July 1992), II (September

1994), IIA (August 1993), and IIB (January 1995), or the most current SW-846 update;

EPA's "Handbook for Analytical Quality Control in Water and Wastewa ter Laboratories" (EPA

600/1-79-019);

Standard Methods for the Examination of Water and Wastewater.

Only U.S. EPA-approved methods will be used for chemical analyses. Any omission in this

QAPP of relevant requirements, tasks and other items found in the referenced methods does not

constitute a waiver of the omitted requirement, task, or item. It is the responsibility of all

personnel involved in the various site investigation activities to perform and document the

required procedures designated herein.

## The Appalachian Shale Water C onservation and Management Committee (ASWCMC) is

conducting a study to characterize the frac turing and flow back water generated from

development of Devonian Shale wells.

Samples will be collected from both vertical and horizontal Devonian Shall gas wells. Numerous

samples will be collected from se veral locations. Phase one of the characterization study will

include 4 grab samples from 6 well sites. A sample will also be collected from a well that has

been in production for at least three months. The following grab samples will be collected from

each site:

One baseline fracturing wa ter sample that includes the fracturing chemicals, excluding

the sand;

Flowback water samples will be collected on days 1, 5 and 14 of the following the

fracturing process; and

Water from an existing producing well.

The list of constituents recomm ended for the characterizat ion study was developed from

comments received from the Pennsylvania De partment of Environmental Protection (PADEP),

the West Virginia Department of Environmental Protection (WVDEP) and members of the

ASWCMC. Because the recommended list of c onstituents is extremely extensive, it was decided

that one sample from each site will be completed fo r the full list of rec ommended constituents

(Table 2). All other samples will be sampled for a subset of these const ituents (Table 3), which

are based on generator knowledge. The analytical results of phase one of the characterization

study will determine the list of const ituents of subsequent sampling events.

In addition, field measurements of pH, specific c onductance, temperature, dissolved oxygen, and

turbidity will be taken of flow back aqueous samples.

## Data Quality Objectives (DQOs) are quali tative and quantitative statements to ensure that data of

known and appropriate quality are obtained during the characterization study (sampling and

analysis).

The data objectives will address characterizat ion of the flow back fluids associated with well

fracturing generated from Devonian shale. This characterization study will:

Identify the specific constituents of intere st (COI) associated with flow back water;

Reduce/eliminate the allegations that the chem icals used for fracturing will contaminate

groundwater; and

Provide sufficient information for the se lection of proper disposal techniques.

Achieving these data objectives will re quire obtaining data of acceptable levels of

certainty. Therefore, it is essential that the field and sampling procedures be completed

under stringent and appropriate methods

There are typically five analyt ical levels of data quality av ailable to accomplish the objectives of

investigations of this type. These levels are typically designated as follows:

Level I: field screening or analysis using portable instruments, calibrated to noncompound specific standards;

Level II: field analysis using portable instruments, calibrated to specific compounds;

Level III: non-Contract Laboratory Program (non-CLP) laboratory methods;

Level IV: CLP Routine Analyti cal Services (RAS) methods; and

Level V: non-standard analytical methods.

DQO Levels I and III will be used to characterize the Devonian Shale Fracturing Flowback

sampling activities. The following sections describe the use of the analyt ical procedural levels

that will be used during the project.

Field Screening Methods - Level I

Field determinations of pH, specific conductance, temperature, dissolved oxygen, and turbidity

## will be made during characteristic sampling as part of a field screening procedure. These

analytical methods are used to determine stability of the well and they are typically designated as

Level I data quality.

In addition, as part of the health and safety program, worker safety may be monitored via one or

more of a variety of field screening tests such as a photoionization detector (PID) or flame

ionization detector (FID) to test for volatile orga nic vapors, or a combustible gas indicator to test

for explosivity potential. These tests, which are semi-quantitative, are classified as field

screening evaluations, even though they typically ar e not used for site characterization purposes.

Non-CLP Laboratory Methods - Level III

Level III analytical procedures provide precise, accurate and defensible data for the intended data

uses, with a less formal documentation and reporting nomenclature at reduced analytical costs

over Level IV data quality procedures. Data Quality Level III will be used during this

characterization study. Table 1, summarizes analyses that will be conducted to characterize and

quantify constituent concentrations.

The exact quantitative criteria used to evaluate da ta quality from the laboratory's precision and

accuracy perspective for the aqueous and sol id sampling media will be presented in the selected

laboratory Quality Assurance Manual(s) (Appendix QA PP-1 and following). The following is a

description of terms that appear in the QAM.

Reference : The reference of the U.S. EPA standard analytical methodology used for each

procedure.

Precision : A measure of the mutual agree ment among individual measurements of the same

property under prescribed simi lar conditions. Precision is eva luated based on the relative percent

difference (RPD) between duplicate matrix spike results or duplicate sample results, as

appropriate. The matrix spike duplicate RP D limits are parameter and method-specific,

MS/MSD RPD QC limits will be prese nted in the laboratory QAMs. Laboratory duplicate

sample RPD limits are typically 20 percent for aqueous media and 35 pe rcent for solid media

(exceptions may apply for solid media w hose samples may be nonhomogeneous). Field

duplicates are also evaluated by ca lculating the RPDs between fie ld duplicate sample results.

However, evaluations of field duplicate RPDs ar e used as advisory determinations since

numerous factors in sampling and analysis may ca use variances between field duplicate results.

Accuracy : The degree of agree ment of a measurement with an a ccepted reference or true

value. Accuracy is evaluated base d on the percent rec overy of spiked samples. The matrix spike

recoveries for organic analyses are method and parameter specific and are typically used as an

advisory QA/QC measure due to the difficulty associated with recovering spiked organic

## parameters. Organic parameter pe rcent recovery QC limits will be presented in the laboratory’s

QAM. The matrix spike rec overies for inorganic and most conve ntional parameters are typically

a range of ±25 percent.

Completeness : A measure of the amount of va lid data obtained from a measurement system

compared to the amount expected to be obtained under normal conditions. The method of

calculation for percent completeness is defined in Section 12.3. Completeness can be evaluated

in two ways: 1) by comparing the number of samples actually collected to the expected number

of samples to be collected; and 2) by comparing the number of va lid analyses received from the

laboratory to the number of actual samples collected. Th e results of any Level III analyses to be

performed is typically used for characterization studies and as such will have a minimum

completeness of 95 percent for both evaluations of completeness.

Exact QA/QC criteria the laboratory will use to evaluate its data's precision and accuracy will be

provided following selection of the analytical la boratory, if the criteria are not method-specific.

Table 1 summarizes the individual paramete rs and associated reporting limits.

There are also qualitative criteria that are a dhered to ensure that data of known and appropriate

quality are obtained during investigation activit ies. These criteria include representativeness and

comparability.

The sampling and analysis programs are desig ned to ensure that analytical data obtained during

the characterization study represent curre nt conditions found at the site and produce data of

comparable quality. The sampling frequency was selected to e nsure data are suitable for their

intended use and adequately char acterize the flow back water. Additionally, standard recognized

analytical methodologies will be utilized to ensure comparability. These designs are instituted to

ensure appropriate sample repres entativeness and data comparability.

## This section outlines the procedures to be used fo r the preparation of sampling equipment and

containers and for sample preservation. It also provides some of the quality control and

operating procedures to be followed for sampli ng. Detailed field sampling details including the

number of samples to be collected, the ra tionale for sampling, and QC requirements are

described in the Field Sampling and Analysis Plan.

Each sample collected for this characterization st udy will be assigned a unique sample tracking

number. The identification of the well location and participating gas company will not be

identified. All well locations will be blind. GTI will a ssign each well a project identifier. The

project identifier will be a unique single a lphanumeric letter that will identify the Devonian Shale

well location and company. This unique a lphanumeric letter will be provided to the third party

environmental consultants to be used in the sample designation.

Flow back Sampling

Fracturing is completed over several days depe nding on the geological formation. The flow back

water is initially removed at a faster rate at the start of production and significantly declines as

production continues. It is believed that the volume of water is relative to the concentration. It is

assumed that the concentration of the fracturing chemicals remain constant throughout the flow

back regardless of the rate of return. Howeve r, the increase of in the COI is due to a longer

residence time in the applicable formation and not associated to the additives of the fracturing

fluids. Therefore, to obtain representative samples of the flow back water samples will be

collected on three separate days (i.e., days 1, 5 and 14).

Additionally, a baseline sample of the fracturing f luid will be collected prior to injection. The

baseline sample will contain the materials (e.g., water and chem icals) used in the fracturing

process. A sample will also be collected f rom a well in Devonian shale that has been in

production for a period of time ( i.e., I production fro more than 3 months). The analytical results

associated with these samples will assist in the data interpretation.

Quality Assurance

The quality assurance field will only be used to indicate a sample collected for quality assurance

purposes.

Quality Assurance/Quality Control Sa mples will be identified as follows:

EB - Equipment Blank

TB - Trip Blank

## The following are sample identification samples.

A05V Sample collected from company X on day 5 from a vertical well.

CEH Sample collected from company Y from an existing horizontal well.

TB Trip Blank.

Each sample container will be marked with a label id entifying the specific pa rameters of interest.

The label will record the date of sample coll ection, alphanumeric identificat ion, parameters to be

analyzed, and preservatives, if applicable. Sample bottles should be prelabeled by the laboratory

to avoid unnecessary delays.

The specific information for each sample will be documented in the field logbook and on a

chain-of-custody form. The sample identification will be correlated in the logbook and chain-ofcustody by sample designation, sampling date, time, and location. The analytical parameters for

which the sample is to be analyzed and the respective number of sample bottles will be provided

on the chain-of-custody sheet.

All new pre-cleaned sample bottles with screw-typ e Teflon-lined lids will be used for holding

and shipping samples. These sample bottles will be supplied by the analytical laboratory, and

pre-preserved by the labora tory as necessary.

Two types of field QA/QC samples will be collected (i.e., trip bl anks and equipment blanks).

The following provides a description of the essential field QA/QC samples.

Trip blanks are collected only for volatile organic samples. The trip blank is prepared by the

laboratory by filling a batch of pre-cleaned 40-ml vials with labor atory-grade water. The vials

are transported to the site and returned to the laboratory in the same manner as the environmental

sample containers. Any constituents found in the trip bl ank could be attributed to: a) interaction

between the sample and the container, b) contaminate d laboratory-grade water, or c) a storage or

handling procedure whic h alters the sample. One trip blank should accompany VOC samples for

each sampling event. The trip blank is placed in the cooler that contains samples for volatile

organics. At no time after the preparation are trip blanks to be opened be fore they are returned to

the laboratory.

## To verify that no constituents are introduc ed from sampling equipment, equipment blanks are

collected by pouring distilled water through the re presentative sampling device and analyzing for

all constituents of interest. One equipment bla nk will be collected during the characterization

study.

A number of documents will be used during the ch aracterization study. These documents

include: chain-of-custody for ms and field data sheets.

Chain-of-custody Forms

The field chain-of-custody form is used to r ecord the custody of all samples collected. This

chain-of-custody form documents the transfer of the custody from the sampling personnel to

another person, to the laboratory, or another party, such as a courier delivery service.

When the field team sends samples to an analyt ical laboratory, each shipping cooler containing

samples, which are sent under one shipping doc ument, must be accompanied by a chain-ofcustody form (Figure 1). These fo rms document information regarding the origination of

samples and those parties having subsequent possession of samples. They also contain

information pertaining to these samples, such as proj ect name, name of the individuals collecting

the samples, sample identification number, the date and time of collection, the number of sample

containers for each parameter of interest for each sample, remar ks or observations of samples, if

appropriate, the signa ture of the person relinquishing control of the samples and the person

receiving the samples, and the name of the overnight carrier shipping the samples to the

laboratory. The original chain-of-custody sheet is sent with the samples. One copy will be

submitted to Gas Technology Institute (GTI), and the other copy is stored in the field team files.

## The primary objective of sample custody is to create an accura te written verified record, which

can be used to trace the possession and handli ng of the samples from the moment of collection

through data analysis and reporting.

The field sampler will be personally responsible for the care and custody of the samples collected

until they are properly transferr ed. Samples will be accompanied by a Chain-of-Custody Record.

Upon arrival at the laboratory, samples will be ch ecked in using laboratory custody procedures

outlined in the laboratory QAM. The laboratory is required to verify that all samples were

received and in good condition. The laboratory should assign a laboratory-specific sample

identification. This unique identification guarantees sample anonymity to the analyst of the

sample's site.

Once samples have been logged-in and transferred to the proper storage areas, the laboratory

department manager is responsible for their prop er storage and condition. Copies of the

completed Chain-of-Custody Records and an anal ysis narrative presenting laboratory sample

identifications and their correlating field assi gned sample identifications should be included in

the data package for delivery to the data user.

## All analyses will be performed using U.S. EPA analytical methods procedures from the

following:

Third Edition (September 1986), as amende d by updates 1 (July 1992), II (September

1994), IIA (August 1993), and IIB (January 1995), or the most current SW-846 update;

EPA's "Handbook for Analytical Quality C ontrol in Water and Wa stewater Laboratories"

(EPA 600/1-79-019);

Standard Methods for the Examinat ion of Water and Wastewater.

Table 1 and Table 2, summarize the list the c onstituents of interest (COIs) associated with the

characterization study for the flow back wa ter from the wells of the Devonian shale and the

required reporting limits to be reported by the laboratory. Method selection was based on the

following factors: reliability in id entification and quantificati ons, and comparability of sample

results and best achievability of the lower of federal Maximum Contaminant Levels (MCLs).

All procedures for environmental sample handling, storage, and documentation while in the

laboratory's custody and delive rable requirements upon delivery of the data to the user are stated

in the laboratory QAMs.

## All field and laboratory equipment are calibrated before use to ensure proper operating

conditions. Laboratory instrument calibration pro cedures are presented in the laboratory QAMs.

Field calibration procedures and frequenc ies should be followed in accordance with the

manufactures specifications. Field cal ibrations must be completed each day at a minimum. pH

meters are required to be cali brated or verified every two hours at a minimum.

All analytical methods must be validated at some point by the use of calibration standards. A

calibration standard is made by the appropria te dilution of a pure substance, the purity of which

is traceable to an NBS or U.S. EPA standard. Beca use of the high sensitivity of many analytical

instruments, the calibration standard is an extremely dilute version of the pure compound.

Because of the high dilution required to be wit hin the linear range of the instrument, the

preparation of the calibration standard is fr equently made by serial dilution rather than in a single

step. In order to provide standard solutions at sufficiently low concentrations, a minuscule

amount of the pure substance will be required, the measurement of which is subject to extreme

error. Thus, it is preferable to deal with potential dilution errors, rather than with the large error

associated with the measurement of a very small amount of the pure substance.

The initial standard is usually obtained either as a pure material or as a prepared certified solution

of a given concentration of the pure c ompound or compounds. In preparing the stock solution of

the calibration standard, great care must be exercised in measuring weights and volumes as

accurately as possible, since all of the analys es following the calibration will be based on the

accuracy of the calibration, and the accuracy of the analytical data is dependent on the calibration

curve. It is the analyst's responsibility to assure that all standards used are within the standard

solution holding time, and to prepare fresh standa rd solutions whenever necessar y. In preparing

working solutions, or using working solutions, the an alyst must check for signs of deterioration

of the standard, such as cloudiness, precipitation, or discoloration. The standard must also be

periodically compared with pre vious runs of standards, and with independently prepared

standards to assure that response f actors fall within a historically accepted range.

There are many laboratory functions that may require corrective action. The decision to

undertake corrective action, a nd the ensuing action must be documente d so that traceability can

be maintained. The point of originating the correc tive action varies, depending upon the mode of

detection that such action is necessary. It is generally the role of ei ther the Laboratory QA

Officer or the Laboratory Department Manager to initi ate such action. Those actions that affect

the quality of the data will be recorded and the record maintained by the La boratory QA Officer.

## The general procedures for a ppropriate laboratory corrective actions and identification of

potential problems are presented in the analytical laboratory QAM.

## Data are typically validated by the labora tory and field personnel. First, during the field

operations, field measures will be validated at the time of coll ection by the field sampler by

verifying the use of standard operating proce dures for the sampling effort and using field QC

checks. Second, laboratory analytical result s will be validated by the Laboratory Department

Manager or the analyst who is the specific analytical task leader.

Validation of field obtained da ta, as well as ongoing QA /QC checks of environmental samples

being taken, is performed on field da ta. All field data are reviewed during the time of collection

and second, all data are reviewed by secondary field personnel if multiple personnel are present.

Corrections in the field logbooks will be removed by placing a single line through the entry,

initialing and dating the correction. If infor mation is added without a correction being necessary

that entry will be initialed and da ted to indicate that it was not enter ed at the original time of data

entry. En tries should never be “whited out” or made in pencil.

The individual Laboratory Department Managers should validate all labora tory data, prior to

reporting. Some of the following QA/QC measures are reviewed or procedures are typically

used:

A standard curve is prepared prior to sample analysis;

The standard regression coefficient is within the acceptable range;

Standard reference materia ls are analyzed at the proper frequencies a nd acceptable results

are obtained;

The reagent blanks are analyzed at the proper frequency;

Precision requirements of this plan are met;

Accuracy requirements of this plan are met;

Completeness requirements of this plan are met;

Samples are analyzed within the proper sample holding times;

All calculations are verified as correct;

Proper units are reported; and

The proper methodologies were used.

Besides this review of analytical results and project specific precision, accuracy, and

completeness requirements, the Laboratory De partment Manager should perform unannounced

audits of report forms and other da ta sheets as well as reg ular reviews of instrument logs,

performance test results, and analysts’ performance. Any review of analytical results or internal

QA/QC checks that indicate problems, immediate corrective acti ons should be taken and all data

collected since the previous a pproved QC audits should be reviewed for validity. Specific

## laboratory procedures for valida tion of the analytical data generated are described in the

laboratory QAMs.

The laboratory will provide DQO Le vel 3 (i.e., CLP Like) data pa ckages. However, the data

packages will not be validated at this time. Data validation procedures following the applicable

guidance from the current U. S. EPA's Contract Laboratory Program, National Functional

Guidelines for Organic Data Review and the U. S. EPA's Contract Laboratory Program,

National Functional Guidelines for Inorganic Data Review will be performed, if required.

Analytical Laboratory

Once the data have been validated internally by the laboratory, all of the results are electronically

or automatically entered into the laboratory 's data management system where they are stored

prior to reporting. When all analyses are completed for data storage, the Laboratory Director (or

his/her designee) will issue a final data report including a descriptive case narrative. He or she

will then issue the report to the data user. Al l applicable QC data should be included with the

final report.

The data reports generated for this project shou ld contain all pertinent information for the data

user to determine the applicability and usability of the data for its intended purposes. For this

reason, a specified and uniform data reporting for mat should be implemented. For this project,

DQO levels III data packages will be reported as a Level IV (CLP -like) deliverable to facilitate

data validation, if needed. The following criteria and information should be supplied, at a

minimum, for data reports generated for this project:

1. A descriptive case narrative identifying any problems encountered during internal data

validation (as described above);

2. Completed and legible chain-of-custodies for all analyses contained within each

submitted data package;

3. A lab sample chronicle indicating which analys es were requested and performed for the

samples contained in the data package;

4. A summary of the laboratory sample identifications and the correlating field sample

identifications;

5. A summary of all applicable analytical results reported in the correct number of

significant figures, reporting units; and

## 6. Included in the individual sample reporting re sults should be the complete sample

identifications, the sample dilutions (if necessary), and the individual sample analysis

dates.

Summary reporting only will be provided. Bull eted items above are required under this DQL.

Summary reporting only will be provided. The data package reporting requirements are the same

as Level I except legible and calcula ted QA/QC summaries for labor atory blanks, surrogate

recoveries (if applicable) , laboratory control sample r ecoveries, and matrix spike/matrix spike

duplicate recoveries (or matrix spike recovery and labor atory duplicate results) must also be

supplied under this DQL.

The following summary forms and raw data deli verable requirements will apply for Data Quality

Level III.

The following forms are required for all analys es using Gas Chromatography/Mass Spectroscopy

methods.

Narrative and sample identification cross reference;

Copies of Chain-of-Custody documentation;

Laboratory chronicle;

Method summaries and references;

Organic analysis data sheet for samples and blanks (with TICs as required);

System monitoring compound/surrog ate recoveries summary;

Matrix spike/Matrix spike duplicate summary or any lab duplicate;

QC Check Sample summary;

Method blank summary and results;

Instrument performance check summary;

Initial calibration summary for all constituents of interest;

Continuing calibration check summary for all constituents of interest;

Internal standard area and RT summary;

Extraction/preparation logs;

The handwritten calculation for at least one positive result in one sample at a rate of one

calculation per twenty samples or per data pack age (whichever is greater) per fraction

(e.g., VOC or SVOC); and

Raw data including run logs, mass spectra , quantitation reports and chromatograms for

## samples, as well as any raw data use d to complete the hand written calculation.

The following forms are required for all total metal analyses.

Narrative and sample identification cross reference;

Copies of Chain-of-Custody documentation;

Laboratory chronicle;

Method summaries and references;

Inorganic analysis data sheets;

Initial and continuing calibration verification;

Initial and continuing calibration blanks and preparation blank summary;

ICP interference check sample summary;

Spike sample recovery;

Duplicate results summary;

Laboratory Control Sample summary;

Standard addition results summary, when applicable;

ICP serial dilutions;

Instrument detection limits;

ICP inter-element correction factors summary;

Preparation log;

Analysis run log;

The hand-written calculati on for at least one positive result in one sample at a rate of one

calculation per twenty samples or per data pa ckage (whichever is greater) per method

(e.g., GFAA/ICP/CU); and

Raw data.

The following data and summary forms will be submitted by the laboratory for inorganic nonmetals analyses or other analyses not discussed above:

Narrative and sample identification cross reference;

Copies of Chain-of-Custody documentation;

Laboratory chronicle;

Method summaries and references;

Analysis data sheets;

Calibration summaries; and

Calibration equation and curve plot;

Blank results summary;

Sample spike recovery , where applicable;

Duplicate sample results, where applicable; and

Laboratory control sample summary where applicable.

## Quality control (QC) procedures and checks are used to verify the accuracy of investigation data.

Field QC checks are used to identify potential problems with sampling procedures such as the

inconsistent use of sampling standard operating proc edures or field introduced sample or water

supply contamination and/or problems with sample homogeneity or representativeness.

Laboratory QC checks are used to identify potential problems with analytical procedures such as

the misapplication of required analytical methodologies or other labo ratory related problems

which could result in inaccurate or imprecise data reported. The laboratory QC checks and

procedures presented in this section are require d for most of the applicable methods, but the

frequency of the QC checks should follow proced ures outlined in the laboratory QAMs.

To check the quality of data from field sampling efforts, field blanks and field duplicate samples

will be collected for analysis. These samples will be treated as separate samples for

identification, logging, and shipping. Analytical results on blanks and dupli cates will be reported

with the appropriate field sample data. The number of these samples, when required, and their

use was described in Section 5.0.

The equipment blank provides a check on possible sources of sample contamination. The

equipment blanks should be collec ted in the worst-case scenario. The reason for performing

equipment blanks in the most impacted area is to attempt to simulate a worst-case scenario

regarding contributions from site condition or from im properly cleaned sampli ng equipment to

sample contamination. One equipment blank will be for this proj ect. Equipment blanks should

be handled, transported, and analyzed in the same manner as the samples with which they are

associated.

The equipment blank water must be maintained at 4 (±2) C following collection and during

shipment. Holding times for individual parameters ar e dictated by the specific analytical method

being used. The holding-time clock begins at the time of sample collection of the equipment

blank.

Trip blanks are used to check for sample c ontamination introduced by the sample containers, by

the sampling equipment, or by the sampling e nvironment. Trip blanks travel to the site with the

empty sample bottles and return from the site with the c ollected samples in an effort to simulate

sample handling conditions. Trip blanks are c ollected in association with samples that are to be

analyzed for volatile organic compounds. Potential sources of sample contamination are from

## the laboratory-grade reagent wa ter, sample containers, field or labora tory ambient air, laboratory

reagents, or cross contamination during shipping, handling, preparation or analysis. A trip blank

should accompany VOC samples for each sampling event.

The trip blank water must be maintained at 4 (±2) C through sample collection activities and

during shipment. Holding times for individual parameters are dictated by the specific analytical

method being used. The holding-time clock begins at the time of sample collection of the oldest

sample in the sampling container.

The QC check frequencies a nd requirements specified in the following sections is a general

description only. The laboratory will follow the internal QC checks specified in its QAM for

each analysis type employed. However, these QC checks must meet, at a minimum, the

requirements specified in the respective U.S. EPA analytical methods.

The following internal laboratory QC checks ar e performed for most analyses, whenever

applicable, to ensure the mea surement systems are under control:

Initial and continuing calibrations;

Preparation/method blanks;

Matrix spike and matrix spike duplicate or matrix spike a nd laboratory duplicate analysis,

as appropriate;

Surrogate spike standard performance evaluation (for organic analyses only); and

Calibration check compounds and reagent blanks (for organic analyses only).

Additional internal laboratory QC checks are typica lly performed for most analyses, as required

by the associated analytical method. Only the most common QC checks are generally described

below.

9.2.1 INITIAL AND CONTINUING CALIBRATION

Each measurement system must be calibrated imme diately prior to use and be shown to maintain

the calibration throughout the course of the anal ysis. For the organic parameter methods, all

target compounds will be checked during initial and continuing calibrations. Calibration

procedures and frequencies is discussed for the various analysis types in the laboratory QAMs.

An initial calibration will be performed prior to WSC sample analyses. Continuing calibrations

will be typically analyzed at a minimum freque ncy of one every ten samples. For CLP GC/MS

analysis, calibration checks are only required once every 12 hours of analysis.

A preparation or method blank is run with each batch of samples received for analysis.

Compound or analyte responses observed in the blank at levels above the reportable detection

## limit are reviewed for possible laboratory contamination. If high blank values are observed,

laboratory glassware and reagents may need to be checked for contamination and the analysis of

future samples halted until the system can be brought under control. A high blank value is

typically defined as a value greater than the method detection limit. A preparation and/or method

blank will be prepared at a frequency of one per 20 samples or one per day, whichever is greater.

For all analyses where matrix spiking is possible, 1 in 20 samples is analyzed as matrix spikes

and matrix spike duplicates or 1 in 20 samples is analyzed as matrix spikes and duplicates. Field

personnel must provide additional volume for the la boratory to complete a MS/MSD. The

percent recovery for spi ked samples is calculated using the equations given in Section 12.0 and

compared to the accuracy criter ia specified in the QAM for the associated analytical method.

The relative percent difference of replicate spikes or replicate analytical results are calculated

using the equations given in Section 12.0 and compar ed to the precision criteria specified in the

laboratory QAMs (Appendix QAPP-1 and following) for the associated analytical method.

Surrogate standards are define d as nonpriority pollutant compounds used to monitor the percent

recovery efficiencies of the analytical proc edures on a sample-by-sample basis. Surrogate

standard determinations are performed on all samples and blanks for organic analyses. All

samples are fortified with surrogate spiking compounds before purging or extraction to monitor

the preparation and analysis of samples.

Surrogate compounds and recovery levels for the associated analyses are presented in the

laboratory QAM (surrogate rec overy limits are method- and media-specific and are either

specified in the method or are calculated annually by the analytical laboratory as described in the

analytical method). When the surrogate recove ry level is outside of the control limits on the

initial analysis, the laboratory must take the foll owing actions for all organic analyses for

samples:

Check calculations to assure there are no erro rs, check internal st andard and surrogate

spiking solutions for degradation or contamination and check instrument performance;

and

Recalculate or reinject/repurge the sample or re-extract and reanalyze the sample.

These calibration check compounds and reagent blanks are analyzed periodically throughout the

course of the analysis, depending on the required analysis. The exact frequencies and methods of

use are presented in the laboratory QAM.

## Two types of audit procedures may be conducted during any environmental investigation:

performance audits and system audit s. These audits may be perf ormed on the laboratory as well

as field activities. A description of the labor atory's specific guidance for Performance and

System Audits will be presented in laboratory QA Ms. General proce dures for laboratory

performance and system audits are presented below.

Laboratory performance audits are typically conduc ted by the Laboratory QA Officer on a regular

basis. Each laboratory analyst is given a performance evaluation sample containing analytes for

the parameters which he/she usually performs. These audit samples are used to identify

problems in sample preparation or analysis techniques or methodologies which could lead to

future analytical problems.

Additionally, the laboratory performance audits include verification of each analyst's record

keeping, proper use and understanding of pr ocedures, and performance documentation.

Corrective action will be taken for any deficiencies noted during the audit.

Laboratory system audits are typically conducted by the Laboratory QA Officer. These audits are

used to ensure that all aspects of the Laboratory's QAM are operative. This involves a thorough

review of all laboratory methods performed a nd documentation to confirm that work is

performed according to project specifications.

In some cases, outside certification agencies conduct performance and system audits to verify

contract compliance or the labora tories' ability to meet certification requirements on methods of

analysis and documentation. Result s of these outside certification a udits may be reviewed at any

time as a check on the laboratory’s internal auditing procedures.

## The following discussion describe s the procedures that will be employed to evaluate the

precision, accuracy, and compl eteness of the ge nerated data.

Precision is a measure of agreement among individual measurements of the same property under

prescribed similar conditions. Pr ecision is assessed by calculating the relative percent difference

(RPD) of replicate spike samples or replicate sa mple analyses according to, the following

equation:

RPD = R1 - R2 x 100 where R1 = result 1

(R1 + R2)/2 R2 = result 2

Accuracy is a measure of the closeness of an individual measurement to the true value. Accuracy

is measured by calculating the percent recovery (%R) of known levels of spike compounds as

follows:

concentration of spike sample - concentration of unspiked

sample

%R = ____________________________________________________

_ x 100

concentration of spike added

Completeness is a measure of the amount of valid data obtained from a measurement system,

expressed as a percentage of the number of vali d measurements that should have been collected.

As is specified in Section 4.2, more than one comple teness check can be evaluated. It is

calculated as follows:

number of valid samples reported

Completeness (%) =

_______________________________ x 100

total number of samples analyzed

## Quality control charts can be prepared after ev ery 20 analytical determinations to graphically

evaluate precision and accuracy criteria. The charts are prepare d by calculating the mean value

of the determinations and se tting control limits at + 3 standard deviations from that mean. The

following equations are used:

The control limits should be withi n acceptance limits or ranges presented in the as yet unselected

laboratory's QAM. If the values are found to be outside these limits or ranges, the measurement

system is examined to determine if possible problems exist.

## Periodic preventive maintenance is re quired for equipment whose perf ormance can affect results.

Instrument manuals are kept on file for referen ce if equipment needs repair. Troubleshooting

sections of manuals are often useful in assisti ng personnel in performing maintenance tasks.

Field sampling personnel will be responsible for preventive maintenance of all field instruments.

The field sampling personnel will protect the instruments by placing them in portable boxes

and/or protective cases.

All field equipment will be subject to a routine maintenance program, prior to and after each use.

The routine maintenance progra m for each piece of equipment will be in accordance with the

manufacturer's operations and maintenance manual. All equipment will be cleaned and checked

for integrity before and after each use. Nece ssary repairs will be perf ormed immediately after

any defects are observed, and before the item of equipment is used again.

Equipment parts with a limited life (such as batteries, membranes and some electronic

components) will be periodically checked and replac ed or recharged as necessary according to

the manufacturer's specifications.

Preventive maintenance is important since it prov ides for a longer useful life of the equipment

and helps to ensure a successful field sampling and testing program. Each piece of field

equipment will have its own log sheet which contains the equipment identific ation and the type

of maintenance performed. Since most equipment is used on an irregular basis, all equipment

will be properly stored when not in use.

All major laboratory instruments should normally be under service contract so that trained

professionals are available on call to m inimize instrument downtime. Other preventive

maintenance schedules and/or procedure s for laboratory equipment is presented in the laboratory

QAMs (Appendix QAPP-1 and following).

## Corrective action procedures are divided int o two subgroups: methods corrective action and

systems corrective action. These correc tive actions are implemented whenever system or

performance audits note deficiencies or when QC procedures indicate a potential analytical

problem. The laboratory guidance on Corrective Action procedures is presented in the laboratory

QAMs.

## This QAPP provides a documentable mechanism for the a ssurance of quality work performed at

for the characterization study. Audit reports will be provided by the Laboratory Director (or

his/her designee) as a means of tracking progra m performance, as appli cable, or if needed.

Additionally, periodic assessments of measurement data accuracy, precision, and completeness

and significant QA/QC problems will be performed and reporte d to laboratory and/or project

management, if needed.

Field QA reports will not be nece ssary considering the expected size and length of any individual

sample collection activities. Any problems noted during sampling will be immediately

communicated to GTI, so GTI can take whatever corrective actions necessary.

Upon completion of the project-specific Work Plans, a final QA/QC report will be issued,

assessing the overall degree of project conformance to specifications and the impact of any nonconformances that may affect management decisions.

The final storage location of the files will be maintained at GTI’s office in Chicago. The files

will be maintained for a period of at least three years.48 

# Appendix C

Tabulated Data Obtained from Locations A - S

Key to Abbreviations

μg/l Micrograms per liter. 

## ND Non-detect. Result is less than

the method detection limit.



## B Method blank contamination.

The associated method blank

contains the target analyte at a

reportable level. 

## M Result was measured against

nearest internal standard

assuming a response factor of 1.



## E Estimated result. Result

concentration exceeds the

calibration range. 

## MDL Method detection limit.



## J Estimated result. Result

concentration exceeds the

calibration range. 

## RL Reporting limit.PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a) 5 U 5 U 5 U 5 U 925Amenable cyanide mg/L 0.01 SM18 4500-CN E 0.01 U 0.01 U 0.01 U 0.01 U 0.01 UAmmonia Nitrogen mg/L 0.1 MCAWW 350.1 3.6 J 19.6 J 67.1 J 121 J 293Biochemical Oxygen Demand mg/L 2 SM18 5210 B 794 353 374 2.8 12.5Bromide mg/L 1 MCAWW 300.0A 0.2 U 82.9 274 604 1260Chemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4 3120 1670 9090 3280 28300Chloride mg/L 1 MCAWW 300.0A 74.6 J 9510 J 29800 J 67100 125000Dissolved Organic Carbon mg/L -- SM20 5310B 247 J 253 J 114 J 65 5960Fluoride mg/L 1 MCAWW 300.0A 0.05 U 0.5 G U 2.5 G U 5G U 2.5 G UHardness, as CaCO3 mg/L 5 SM202340C 80 3600 12000 26000 59000Nitrate as N mg/L 0.05 MCAWW 300.0A 0.45 0.5 G U 2.5 G U 5 G U 2.5 G UNitrate-Nitrite mg/L 0.1 MCAWW 353.2 1 J 0.36 J 0.33 J 0.18 J 0.1 UNitrite as N mg/L 0.05 MCAWW 300.0A 0.059 5 G U 29.3 17.6 2.5 G UOil & Grease (HEM) mg/L 5 CFR136A 1664A HEM NA 4.8 U 4.8 U 5 U 62.6Specific Conductance umhos/cm -- MCAWW120.1 498 J 31900 J 137000 J 248000 J 385000 JSulfate mg/L 1 MCAWW 300.0A 51.5 J 46.3 J 39.6 B JG20.5 B J 50 G UTOC mg/L 1 SM20 5310B 350 260 110 38.7 J 5680Total Alkalinity mg/L 5 SM18 2320 B 76.7 J 308 J 149 J 93.3 J 26.2 JTotal Dissolved Solids mg/L 10 SM18 2540 C 990 15400 54800 105000 216000Total Kjeldahl Nitrogen mg/L 3 MCAWW 351.3 39.2 56 76.2 124 202Total phosphorus mg/L 0.1 MCAWW 365.2 0.15 0.04 B 0.074 B 0.1 U 0.1 UTotal Suspended Solids mg/L 4 SM20 2540D 190 82 71 197 201Turbidity NTU -- MCAWW 180.1 321 13.1 2.3 20.1 175Cyanide, Total ug/L 10 SW846 9012A 10 U 10 U 10 U 10 U 10 UTotal Sulfide mg/L 3 SW846 9030B/9034 2.4 B 1.6 B 3.2 3 U 2.4 BpH No Units -- SW846 9040 7.2 7.2 NA 6.5 5.7Total Recoverable Phenolics mg/L 0.01 SW846 9066 0.051 0.027 0.011 J 0.011 0.23Sulfite mg/L 1 SM4500-SO3 B NA NA NA NA NAMBAS (mol.wt 320) mg/L 0.05 SM5540 C NANANANANATotal and Dissolved MetalsAluminum ug/L 200 SW846 6010B 358 J 223 125 B J 174 B J 370 BAluminum-DISS ug/L 200 SW846 6010B 154 B J 47.7 B 166 B J 133 B J 348 BAntimony ug/L 10 SW846 6010B 10 U 17.6 10 B 50 U 100 UAntimony-DISS ug/L 10 SW846 6010B 10 U 18.3 9.5 B 10.2 B 100 UArsenic ug/L 10 SW846 6010B 10 U 13.3 17.4 B 24.8 B 46.2 BArsenic-DISS ug/L 10 SW846 6010B 10 U 12.8 21.5 B 19.4 B 106Barium ug/L 200 SW846 6010B 276 70200 J 157000 569000 639000Barium-DISS ug/L 200 SW846 6010B 104 B 30200 163000 583000 J 787000 JBeryllium ug/L 4 SW846 6010B 4 U 4 U 20 U 20 U 40 UBeryllium-DISS ug/L 4 SW846 6010B 4 U 4 U 20 U 0.9 B J 40 UBoron ug/L 2000 SW846 6010B 43.8 B 8720 J 33700 56900 67300 JBoron-DISS ug/L 2000 SW846 6010B 49.6 B 9000 J 34200 J 58000 J 85200 JCadmium ug/L 5 SW846 6010B 5 U 0.21 B 25 U 1.9 B 2.5 BCadmium-DISS ug/L 5 SW846 6010B 5 U 5 U 25 U 1.2 B 2.5 BCalcium ug/L 5000 SW846 6010B 21100 828000 J 3400000 7820000 J 11400000 JCalcium-DISS ug/L 5000 SW846 6010B 20200 827000 J 3460000 8070000 J 14400000 JChromium ug/L 5 SW846 6010B 5 U 21.1 25 U 31 17.7 BChromium-DISS ug/L 5 SW846 6010B 5 U 6.6 25 U 10.7 B 7.6 BCobalt ug/L 500 SW846 6010B 50 U 50 U 250 U 1250 U 2500 UCobalt-DISS ug/L 500 SW846 6010B 50 U 50 U 250 U 1250 U 2500 UCopper ug/L 25 SW846 6010B 39.1 9.6 B 125 U 23 B 51.5 BCopper-DISS ug/L 25 SW846 6010B 24.5 B 25 U 125 U 125 U 51.9 BIron ug/L 100 SW846 6010B 926 2680 10800 41200 J 103000Iron-DISS ug/L 100 SW846 6010B 362 1830 J 10300 40600 102000Lead ug/L 3 SW846 6010B 12.1 1.7 B 15 U 15 U 970Lead-DISS ug/L 3 SW846 6010B 7.6 3 U 15 U 15 U 647Lithium ug/L 500 SW846 6010B 40.4 B 9530 J E 24000 51800 67100Lithium-DISS ug/L 500 SW846 6010B 44.5 B 9480 J E 23300 E 51600 J 84900Magnesium ug/L 5000 SW846 6010B 3690 B 72800 J 314000 725000 1090000Magnesium-DISS ug/L 5000 SW846 6010B 3500 B 75300 319000 738000 1330000Manganese ug/L 150 SW846 6010B 91 697 960 1760 2130Manganese-DISS ug/L 150 SW846 6010B 73.3 704 991 1760 2590Molybdenum ug/L 400 SW846 6010B 1.2 B J 35.6 B J 30.6 B 18.8 B J 17 BMolybdenum-DISS ug/L 400 SW846 6010B 4.8 B 34.8 B J 13.3 B 22.6 B 400 UNickel ug/L 40 SW846 6010B 9.5 B 68.3 33.2 B 33.3 B 2000 UNickel-DISS ug/L 40 SW846 6010B 2.6 B 61.5 29.5 B 21.2 B 2000 UPotassium ug/L 5000 SW846 6010B 2300 B 183000 E 921000 1880000 1770000Potassium-DISS ug/L 5000 SW846 6010B 2590 B 188000 E 934000 E 1940000 2190000Selenium ug/L 5 SW846 6010B 3.2 B 5 U 25 U 25 U 50 USelenium-DISS ug/L 5 SW846 6010B 3 B 5 U 25 U 25 U 50 USilver ug/L 5 SW846 6010B 5 U 5 U 25 U 25 U 50 USilver-DISS ug/L 5 SW846 6010B 5 U 5 U 25 U 25 U 50 U2/20/2009Day 14Lewis County, WV5/8/2009Day 52/11/2009Day 90Day 1LocationADay 02/7/2009 2/8/2009PARAMETERUNITS PQL US EPA Method2/20/2009Day 14Lewis County, WV5/8/2009Day 52/11/2009Day 90Day 1LocationADay 02/7/2009 2/8/2009Sodium ug/L 5000 SW846 6010B 88400 4490000 J E 15000000 31500000 39700000Sodium-DISS ug/L 5000 SW846 6010B 96100 4750000 15000000 32600000 49300000Strontium ug/L 50 SW846 6010B 726 E 137000 J E 872000 J 2080000 3480000Strontium-DISS ug/L 50 SW846 6010B 711 E 144000 J E 870000 J E 2080000 J 4370000 JThallium ug/L 10 SW846 6010B 19.8 B 4.9 B J 50 U 50 U 500 UThallium-DISS ug/L 10 SW846 6010B 23.6 B 6.2 B J 28.5 B J 17.4 B 500 UTin ug/L 1000 SW846 6010B 6.3 B 3.8 B 500 U 500 U 1000 UTin-DISS ug/L 1000 SW846 6010B 5.2 B 100 U 500 U 16.8 B 1000 UTitanium ug/L 500 SW846 6010B 4 B 50 U 250 U 250 U 190 B JTitanium-DISS ug/L 500 SW846 6010B 50 U 50 U 250 U 250 U 196 B JTrivalent Chrom ug/L 50 SW846 6010B 5 U 6.6 25 U 25 U 50 UZinc ug/L 20 SW846 6010B 36.6 107 119 179 J 372 JZinc-DISS ug/L 20 SW846 6010B 35.5 89.9 115 J 160 J 382 JDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196A 0.01 U 0.05 U 0.1 G U 0.1G U 0.5 G UHexavalent Chromium mg/L 0.01 SW846 7196A 0.02 U 0.05 U 0.1 G U 0.1 G U 0.5 G UMercury ug/L 0.2 SW846 7470A 0.036 B J 0.042 B J 0.027 B 0.029 B J 0.2 UMercury-DISS ug/L 0.2 SW846 7470A0.037 B J 0.08 B J 0.032 B J 0.028 B J 0.2 UVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,1,1-Trichloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,1,2-Trichloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,1-Dichloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,1-Dichloroethene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,1-Dichloropropene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,2,3-Trichlorobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,2,3-Trichloropropane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,2,4-Trichlorobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,2,4-Trimethylbenzene ug/L 5 SW846 8260B 16 4.7 J 1.1 J 1.9 J 0.82 J1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,2-Dichlorobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,2-Dichloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,2-Dichloropropane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,3,5-Trimethylbenzene ug/L 5 SW846 8260B 6 3.1 J 5 U 10 U 5 U1,3-Dichlorobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,3-Dichloropropane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,4-Dichlorobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U1,4-Dioxane ug/L 1000 SW846 8260B 1000 U 1000 U 1000 U 2000 U 1000 U1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B NA NA NA NA NA2,2-Dichloropropane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U2-Butanone ug/L 5 SW846 8260B 5 U 5 U 2 J 10 U 5 U2-Chloroethyl vinyl ether ug/L 10 SW846 8260B 10 U 10 U 10 U 20 U 10 U2-Hexanone ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U4-Chlorotoluene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 U4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UAcetone ug/L 20 SW846 8260B 20 U 17 J 76 40 U 15 J BAcrolein ug/L 100 SW846 8260B 100 U 100 U 100 U 200 U 100 UAcrylonitrile ug/L 100 SW846 8260B 100 U 100 U 100 U 200 U 100 UBenzene ug/L 5 SW846 8260B 5 U 7.7 8 8.5 J 1.5 JBenzyl chloride ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UBromobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UBromodichloromethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UBromoform ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UBromomethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UCarbon disulfide ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UCarbon tetrachloride ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UChlorobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UChloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UChloroform ug/L 5 SW846 8260B 5 U 28 2.2 J 10 U 5 UChloromethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Ucis-1,2-Dichloroethene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Ucis-1,3-Dichloropropene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UDibromochloromethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UDibromomethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UDichlorodifluoromethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UEthylbenzene ug/L 5 SW846 8260B 2.3 J 0.98 J 5 U 10 U 5 UIsopropylbenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UMethylene chloride ug/L 5 SW846 8260B 5 U 1.6 J 1.4 J 10 U 5 UNaphthalene ug/L 5 SW846 8260B 2.2 J 2.1 J 0.51 J 10 U 5 Un-Butylbenzene ug/L 5 SW846 8260B 5 U 2 J 5 U 10 U 5 Un-Propylbenzene ug/L 5 SW846 8260B 2 J 5 U 5 U 10 U 5 Up-Isopropyltoluene ug/L 5 SW846 8260B 5 U 2.1 J 5 U 10 U 5 Usec-Butylbenzene ug/L 5 SW846 8260B 3.2 J 5 U 5 U 10 U 5 UStyrene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UPARAMETERUNITS PQL US EPA Method2/20/2009Day 14Lewis County, WV5/8/2009Day 52/11/2009Day 90Day 1LocationADay 02/7/2009 2/8/2009tert-butyl acetate ug/L -- SW846 8260B NA NA NA NA NAtert-Butylbenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UTetrachloroethene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Utetrahydrofuran ug/L -- SW846 8260B NA NA NA NA NAToluene ug/L 5 SW846 8260B 3.1 J 5.1 2 J 3.4 J 1.6 Jtrans-1,2-Dichloroethene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Utrans-1,3-Dichloropropene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UTrichloroethene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UTrichlorofluoromethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UVinyl acetate ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UVinyl chloride ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 UXylenes (total) ug/L 15 SW846 8260B 18 10 J 15 U 30 U 15 USemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U1,2-Diphenylhydrazine ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 U1,3-Dinitrobenzene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U1,4-Naphthoquinone ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U1-Naphthylamine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U2,3,7,8-TCDD ug/L -- SW846 8270C NA NA NA NA NA2,4,5-Trichlorophenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U2,4,6-Trichlorophenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U2,4-Dimethylphenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U2,4-Dinitrophenol ug/L 40 SW846 8270C 48 U 480 U 940 U 480 U 480 U2,4-Dinitrotoluene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U2,6-Dichlorophenol ug/L 2 SW846 8270C 2 19 U 38 U 19 U 19 U2,6-Dinitrotoluene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U2-Acetylaminofluorene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U2-Chloronaphthalene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 U2-Chlorophenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U2-Methylnaphthalene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 U2-Methylphenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U2-Naphthylamine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U2-Nitroaniline ug/L 50 SW846 8270C 48 U 480 U 940 U 480 U 480 U2-Nitrophenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U2-Picoline ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U3,3'-Dichlorobenzidine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U3-Methylcholanthrene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U3-Nitroaniline ug/L 50 SW846 8270C 48 U 480 U 940 U 480 U 480 U4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C 48 U 480 U 940 U 480 U 480 U4-Aminobiphenyl ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U4-Bromophenyl phenyl ether ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U4-Chloro-3-methylphenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U4-Chloroaniline ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 U4-Nitroaniline ug/L 50 SW846 8270C 48 U 480 U 940 U 480 U 480 U4-Nitrophenol ug/L 50 SW846 8270C 48 U 480 U 940 U 480 U 480 U5-Nitro-o-toluidine ug/L 100 SW846 8270C 97 U 970 U 1900 U 960 U 950 U7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UAcenaphthene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UAcenaphthylene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UAcetophenone ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UAniline ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UAramite ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UBenzidine ug/L 200 SW846 8270C 190 U 1900 U 3800 U 1900 U 1900 UBenzo(a)anthracene ug/L 10 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UBenzo(a)pyrene ug/L 5 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UBenzo(b)fluoranthene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UBenzo(ghi)perylene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UBenzo(k)fluoranthene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UBenzyl alcohol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Ubis(2-Chloroethoxy)methane ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Ubis(2-Chloroethyl) ether ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Ubis(2-Chloroisopropyl) ether ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Ubis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UButyl benzyl phthalate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UChlorobenzilate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UChrysene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UDiallate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UDibenz(a,h)anthracene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UDibenzofuran ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UDiethyl phthalate ug/L 10 SW846 8270C 9.7 U 97 U 35 J 96 U 95 UDimethoate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UDimethyl phthalate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UDi-n-butyl phthalate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UPARAMETERUNITS PQL US EPA Method2/20/2009Day 14Lewis County, WV5/8/2009Day 52/11/2009Day 90Day 1LocationADay 02/7/2009 2/8/2009Di-n-octyl phthalate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UDinoseb ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UDiphenylamine ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UDisulfoton ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UEthyl methanesulfonate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UFluoranthene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UFluorene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UHexachlorobenzene ug/L 0.05 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UHexachlorobutadiene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UHexachlorocyclopentadiene ug/L 2 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UHexachloroethane ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UHexachloropropene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UIsodrin ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UIsophorone ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UIsosafrole ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UMethyl methanesulfonate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UNitrobenzene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UN-Nitrosodiethylamine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UN-Nitrosodimethylamine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UN-Nitrosodi-n-butylamine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UN-Nitrosodi-n-propylamine ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UN-Nitrosodiphenylamine ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UN-Nitrosomethylethylamine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UN-Nitrosomorpholine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UN-Nitrosopiperidine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UN-Nitrosopyrrolidine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Uo-Toluidine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UParathion ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Up-Dimethylaminoazobenzene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UPentachlorobenzene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UPentachloroethane ug/L 20 SW846 8270C 19 U 190 U 380 U 190 U 190 UPentachloronitrobenzene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UPentachlorophenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UPhenanthrene ug/L 2 SW846 8270C 2.7 19 U 38 U 19 U 19 UPhenol ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 UPhorate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UPronamide ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UPyrene ug/L 2 SW846 8270C 0.54 J B 19 U 38 U 19 U 19 UPyridine ug/L 10 SW846 8270C 86 2600 1800 860 490Safrole ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 UThionazin ug/L 10 SW846 8270C 0.97 U 97 U 190 U 96 U 95 UTetraethyldithiopyrophosphate ug/L 10 SW846 8270C NANANANANAOrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 U4,4'-DDE ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 U4,4'-DDT ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 UAldrin ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Ualpha-BHC ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Ubeta-BHC ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 UChlordane (technical) ug/L 0.05 SW846 8081A 0.48 U NA NA 0.48 U 0.48 Udelta-BHC ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 UDieldrin ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 UEndosulfan I ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 UEndosulfan II ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 UEndosulfan sulfate ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 UEndrin ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 UEndrin aldehyde ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 UEndrin ketone ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Ugamma-BHC (Lindane) ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 UHeptachlor ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 UHeptachlor epoxide ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 UMethoxychlor ug/L 0.1 SW846 8081A 0.096 U NA NA 0.095 U 0.095 UToxaphene ug/L 2 SW846 8081A1.9 U NANA1.9 U 1.9 UPCBsAroclor 1016 ug/L 0.4 SW846 8082 0.38 U NA NA 0.38 U 0.41 UAroclor 1221 ug/L 0.4 SW846 8082 0.38 U NA NA 0.38 U 0.41 UAroclor 1232 ug/L 0.4 SW846 8082 0.38 U NA NA 0.38 U 0.41 UAroclor 1242 ug/L 0.4 SW846 8082 0.38 U NA NA 0.38 U 0.41 UAroclor 1248 ug/L 0.4 SW846 8082 0.38 U NA NA 0.38 U 0.41 UAroclor 1254 ug/L 0.4 SW846 8082 0.38 U NA NA 0.38 U 0.41 UAroclor 1260 ug/L 0.4 SW846 8082 0.38 U NANA0.38 U 0.41 UPARAMETERUNITS PQL US EPA Method2/20/2009Day 14Lewis County, WV5/8/2009Day 52/11/2009Day 90Day 1LocationADay 02/7/2009 2/8/2009Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141A 0.97 U NA NA 0.98 U 0.97 UAlcohols2-Propanol mg/L 10 SW846 8015 NA NA NA NA NAButyl alcohol mg/L 10 SW846 8015 NA NA NA NA NAEthanol mg/L 10 SW846 8015 NA NA NA NA NAMethanol mg/L 10 SW846 8015 NA NA NA NA NAn-Propanol mg/L 10 SW846 8015 NANANANANAGlycolsEthylene Glycol mg/L 50 SW846 8015 NA NA NA NA NAPropylene glycol mg/L 50 SW846 8015 NANANANANAAcidsAcetic Acid mg/L 10 SW846 8015 NA NA NA NA NAButyric Acid mg/L 10 SW846 8015 NA NA NA NA NAPropionic Acid mg/L 10 SW846 8015 NA NA NA NA NAVolatile Acids mg/L 10 NANANANANAPARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 107 106 1850.01 U 0.01 U 0.01 U 0.01 U 0.01 U9.3 J 32 J 82.4 J 107 J 2592 U 132 1950 149 33.6107 120 544 849 1380 J1730 1340 6120 4340 3660010700 J 10500 J 50000 78600 J 122000153 J 204 J 50 J 36.9 J 15.4 J0.25 G U 0.65 1.2 G U 1.2 G U 2.5 G U9500 4700 26400 43500 850000.25 G U 0.25 G U 1.2 G U 1.2 G U 2.5 G U0.15 0.27 J 0.15 J 0.089 B J NA5 G U 5 G U 12.5 G U 77.4 2.5 G U19.4 5.7 4.8 U 30.8 14.734600 J 48800 J 175000 J 284000 J 440000 J198 J 222 J 106 60.1 J 83.8 J168 207 50.6 34.2 12.6121 J 226 J 97.6 J 53.2 J 43.1 J27800 22400 87800 112000 19400023 51 71.7 112 1360.36 0.19 0.45 0.088 B 0.1 U790 81 35.6 17 150338 130 20.9 25.6 1165.4 B 10 U 10 U 10 U 10 U2.4 B 3 U 3 U 2.4 B 3.27.6 7.8 6.6 5.5 6.10.082 0.064 0.01 U 0.015 0.039 J25.0 U 5.20 10.0 8.40 30.80.500 U 0.0691 0.131 0.0857 0.138481 328 166 B 1000 U 811 B J200 U 39.9 B 1000 U 1000 U 536 B2.4 B 37.8 18 B 9.2 B 100 U3 B 37.4 12.2 B 12.6 B 100 U9.1 B 13.5 50 U 12.6 B 11410 U 11.3 50 U 10 B 1519810 3570 21400 J 74200 J 13300011700 4680 J 37300 58200 J E 179000 J4 U 4 U 20 U 2.2 B 40 U4 U 4 U 20 U 20 U 40 U2140 J 9260 J 14300 J 16200 J 13500 J2400 J 9320 J 14800 J 16100 J 1860010.5 5 U 25 U 1.4 B 7.7 B3.9 B 5 U 25 U 25 U 8.6 B2990000 1370000 J 7630000 J 12500000 J 18300000 J3260000 J 1390000 J 8040000 J 12800000 J E 230000004.8 B 11.1 7.5 B 8.4 B 20.9 B1.5 B 8.6 7.2 B 25 U 17.5 B50 U 50 U 250 U 250 U 2500 U50 U 50 U 250 U 250 U 2500 U21 B 25 U 125 U 125 U 27.2 B25 U 25 U 125 U 125 U 250 U11600 6030 20400 J 54200 69700441 E 4440 18900 J 39800 74300111 3.8 15 U 15 U 68 B6.9 3 U 15 U 15 U 150 U14900 J E 13900 E 49100 J E 73700 J 8860016400 J E 14400 J E 49300 J 71400 J E 115000235000 153000 817000 1330000 J 1710000266000 154000 J 843000 1310000 21600003640 1060 4220 7090 88303930 1050 4360 7000 113008.9 B J 28.8 B J 9.6 B J 6.8 B J 400 U5.4 B 29.1 B 27.6 B J 10.6 B J 400 U10.4 B 18.6 B J 11 B 7 B 2000 U6.6 B 16.9 B 8.6 B 200 U 2000 U229000 E 109000 E 300000 E 415000 335000257000 E 110000 E 316000 451000 E 4220005 U 5 U 25 U 25 U 44 B5 U 5 U 25 U 25 U 64.70.82 B 0.73 B 2.8 B 5.5 B 50 U1.6 B J 5 U 25 U 25 U 10.4 BWashington, PADay 5 Day 904/29/2009Day 14Day 0 Day 1Location B1/26/2009 1/29/2009 2/2/2009 2/10/2009PARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BWashington, PADay 5 Day 904/29/2009Day 14Day 0 Day 1Location B1/26/2009 1/29/2009 2/2/2009 2/10/20096190000 6370000 22000000 J 32500000 J 342000006790000 6310000 22400000 31500000 J 44600000439000 E 167000 E 1080000 J E 1850000 J 2520000478000 J E 166000 J E 1190000 J 1990000 J E 3350000 J6 B 5.4 B 50 U 50 U 500 U7.1 B 5.5 B J 50 U 50 U 500 U6.9 B 5.1 B 500 U 500 U 1000 U9.4 B 7.4 B 500 U 500 U 1000 U50 U 50 U 250 U 250 U 156 B50 U 50 U 250 U 250 U 195 B4.8 B 11.1 5 U 8.4 17.5 B117 J 86.9 J 84.9 B J 66.8 B 73.8 B J51.9 J 68.1 J 120 62.2 B 67.1 B0.01 U 0.01 U 0.042 0.05 G U 0.5 G U0.05 G U 0.01 U 0.01 U 0.05 G U 0.25 G U0.55 J 0.05 B 0.023 B 0.049 B J 0.2 U0.054 B J 0.022 B 0.037 B 0.028 B J 0.2 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 16 J150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U140 J 82 110 J 74 23 J150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U100 J 33 120 65 19 J150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U30000 U 5000 U 25000 U 10000 U 10000 UNA NA NA NA NA150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U300 U 50 U 250 U 100 U 100 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U600 U 100 U 500 U 200 U 75 J B3000 U 500 U 2500 U 1000 U 1000 U3000 U 500 U 2500 U 1000 U 1000 U150 U 240 1200 420 360150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U1500 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U19 J 14 J 85 J 42 J 21 J150 U 3.2 J 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U24 J 18 J 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 54 J 22 J 50 U84 J 25 U 68 J 50 U 50 U150 U 25 U 120 U 50 U 50 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CWashington, PADay 5 Day 904/29/2009Day 14Day 0 Day 1Location B1/26/2009 1/29/2009 2/2/2009 2/10/2009NA NA NA NA NA150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 UNA NA NA NA NA81 J 340 2300 820 660150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U150 U 25 U 120 U 50 U 50 U210 J B 180 B 1100 520 B 300190 U 95 U 9.4 U 9.5 U 9.5 U38 U 19 U 1.9 U 1.9 U 1.9 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 UNA NA NA NA NA190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 7.7 J 9.4 U 9.5 U 8.3 J940 U 480 U 47 U 48 U 48 U190 U 95 U 9.4 U 9.5 U 9.5 U38 U 19 U 1.9 U 1.9 U 1.9 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U38 U 19 U 1.9 U 1.9 U 1.9 U190 U 95 U 9.4 U 9.5 U 9.5 U120 94 1.9 U 1.9 U 1.9 U190 U 7.7 J 9.8 9.5 U 1141 J 95 U 9.4 U 9.5 U 9.5 U940 U 480 U 47 U 48 U 48 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U3.5 J 8.7 J 14 11 14940 U 480 U 47 U 48 U 48 U940 U 480 U 47 U 48 U 48 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U940 U 480 U 47 U 48 U 48 U940 U 480 U 47 U 48 U 48 U1900 U 950 U 94 U 95 U 95 U190 U 95 U 9.4 U 9.5 U 9.5 U38 U 19 U 1.9 U 1.9 U 1.9 U38 U 19 U 0.75 J 1.9 U 1.9 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U3800 U 1900 U 190 U 190 U 190 U38 U 19 U 1.4 J B 1.9 U 1.9 U38 U 19 U 1 J 1.9 U 1.9 U38 U 19 U 1.1 J B 1.9 U 1.9 U38 U 19 U 1.1 J 1.9 U 1.9 U38 U 19 U 1 J B 1.9 U 1.9 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U38 U 19 U 1.9 U 1.9 U 1.9 U38 U 19 U 1.9 U 1.9 U 1.9 U190 U 95 U 1.8 J 1.8 J 9.8190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U38 U 19 U 1.2 J B 1.9 U 1.9 U190 U 95 U 9.4 U 9.5 U 9.5 U38 U 19 U 3.2 1.9 U 1.9 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 1.5 J 1.6 J B 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 1.8 J 9.5 U 9.5 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Washington, PADay 5 Day 904/29/2009Day 14Day 0 Day 1Location B1/26/2009 1/29/2009 2/2/2009 2/10/2009190 U 95 U 4.4 J 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U38 U 19 U 1.9 U 1.9 U 1.9 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U38 U 19 U 1.3 J B 1.9 U 1.9 U11 J 8.4 J 1.9 U 1.9 U 1.9 U38 U 19 U 0.99 J 1.9 U 1.9 U38 U 19 U 1.9 U 1.9 U 1.9 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U38 U 19 U 3.1 1.9 U 1.9 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U38 U 19 U 1.9 U 1.9 U 1.9 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U38 U 19 U 1.9 U 1.9 U 1.9 U38 U 19 U 1.9 U 1.9 U 1.9 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U380 U 190 U 19 U 19 U 19 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U22 J 16 J 1.8 J 1.9 U 0.3 J38 U 11 J 1.9 U 1.9 U 1.9 U190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 9.5 U 9.5 U38 U 19 U 1.1 J B 1.9 U 1.9 U310 350 250 77 260190 U 95 U 9.4 U 9.5 U 9.5 U190 U 95 U 9.4 U 0.98 U 0.98 UNANANANANA0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.48 U NA NA 0.5 U 0.49 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.048 U NA NA 0.05 U 0.049 U0.095 U NA NA 0.099 U 0.098 U1.9 U NANA2U 2U0.38 U NA NA 0.4 U 0.39 U0.38 U NA NA 0.4 U 0.39 U0.38 U NA NA 0.4 U 0.39 U0.38 U NA NA 0.4 U 0.39 U0.38 U NA NA 0.4 U 0.39 U0.38 U NA NA 0.4 U 0.39 U0.38 U NANA0.4 U 0.39 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Washington, PADay 5 Day 904/29/2009Day 14Day 0 Day 1Location B1/26/2009 1/29/2009 2/2/2009 2/10/20090.96 U NA NA 0.98 U 0.98 U4 U 1 U 1 U 1 U 10 UJ4 U 1 U 1 U 1 U 10 UJ4 U 1 U 1 U 1 U 10 UJ88 8 3.2 4.7 10 UJ4 U 1 U 1 U 1 U 10 UJ20.1 20.6 20.8 11 100 UJ10 U 10 U 10 U 10 U 100 UJNA NA NA 21.5 10 UJNA NA NA NA 10 UJNA NA NA NA 10 UJNANANANA6300PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 5 U 5 U 2200.01 U 0.01 NR U 0.01 U 0.01 U 0.01 NR U88.7 J 83.8 J 98.9 J 149 J 1824.9 132 63.7 39.8 2420.2 U 151 331 637 1080578 2980 5500 4560 1620039.7 J 15100 J 39800 78100 J 107000121 J 109 46.9 22.8 J 117 J0.036 B 0.5 G U 5 G U 1.2 G U 2.5 G U36 4800 15000 33000 770000.86 0.98 5 G U 1.2 G U 2.5 G U1.1 J 0.88 J 0.8 J 0.5 J 0.029 B0.05 U 3.1 B 7.1 20.3 2.5 G UNA 13.9 5 U 4.7 U 5 U1190 J 64500 J 192000 J 239000 J 384000 J269 J 71.5 J 36.4 B J 22.3 B J 50 G U167 82.5 J 32.9 J 14.4 J 117233 J 249 J 147 J 71.4 J 41.4 J719 24700 61900 110000 267000146 132 120 136 13416 8.5 1.3 0.55 0.1 U110 522 102 475 4469.1 164 14 72 27710 U 38.5 8.8 B J 10 U 42.68 3U 3U 3U 3U8.9 7.2 6.7 6.1 5.90.0079 B J 0.0083 B 0.012 0.01 U 0.01 UNA NA NA NA NANANANANANA217 J 705 B J 206 B J 235 B J 1040 B J68.7 B J 244 B J 176 B J 149 B J 910 B J10 U 8.9 B 50 U 50 U 200 U10 U 50 U 50 U 50 U 200 U10 U 15.8 B 13.8 B 12 B 91.2 B10 U 50 U 17.9 B 50 U 117 B63.1 B J 102000 J 787000 2160000 J 422000057.2 B 15000 755000 J 2130000 J 4370000 J0.21 B J 20 U 20 U 20 U 80 U0.32 B J 20 U 20 U 20 U 80 U2430 J 13100 J 18800 19900 25300 J3460 J 14000 J 18500 J 19900 256005 U 25 U 25 U 2.2 B 2.6 B5 U 25 U 25 U 25 U 100 U14300 1220000 4390000 J 9520000 1860000016400 J 1330000 J 4340000 J 9500000 J 194000001.2 B 49.1 20.8 B 21.8 B 100 U1.1 B 9.4 B 14.6 B 25 U 100 U50 U 250 U 500 U 1250 U 2500 U50 U 250 U 500 U 1250 U 2500 U7.7 B 28.4 B 125 U 125 U 500 U10.5 B 125 U 125 U 125 U 500 U439 J 29000 J 21200 J 33200 93000250 10500 18400 13800 591003.3 11.8 B 15 U 15 U 150 U205 15 U 15 U 15 U 150 U7.7 B J 16400 J E 43700 E 71800 E 1220009.2 B J 18000 J 41900 J 71200 J E 1250002830 B 122000 432000 872000 17900003200 B 134000 426000 875000 183000058.7 1040 2440 4430 977064.8 1020 2390 4420 99006.6 B 37.2 B 31.7 B J 18.8 B 800 U6.1 B 17.8 B 45.1 B 20.7 B 800 U1.3 B 10.9 B 200 U 200 U 2000 U1 B 200 U 200 U 200 U 2000 U42600 151000 349000 E 533000 E 54800045100 171000 343000 533000 E 5640005 U 25 U 25 U 25 U 100 U5 U 25 U 25 U 25 U 100 U5 U 25 U 25 U 25 U 100 U5 U 25 U 25 U 25 U 100 ULewis County, WVDay 90Day 5Day 12/11/2009Day 0 Day 145/15/092/17/2009 2/20/2009 2/27/2009Location CPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BLewis County, WVDay 90Day 5Day 12/11/2009Day 0 Day 145/15/092/17/2009 2/20/2009 2/27/2009Location C70700 7690000 18200000 29100000 5280000086100 8430000 18000000 29200000 54100000103 J 244000 J E 893000 E 1820000 J E 3620000 J168 J E 236000 J 891000 J 1800000 J E 3710000 J10 U 50 U 19.4 B 15.9 B 500 U4.2 B 50 U 20.7 B 18 B 162 B3.9 B 500 U 500 U 17.8 B 2000 U3.7 B 500 U 21.8 B 500 U 2000 U50 U 250 U 250 U 250 U 242 B50 U 250 U 250 U 250 U 264 B1.2 B 9.4 B 14.6 B 25 U 100 U11.7 B J 504 J 83.6 B J 116 178 B78.6 J 92.4 B J 67.1 B J 100 196 B0.01 U 0.1 G U 0.1 G U 0.5 U 1 G U0.01 U 0.1 G U 0.1 G U 0.07 B 0.1 G U0.2 U 0.052 B J 0.04 B J 0.054 B J 0.2 U0.025 B J 0.056 B J 0.038 B J 0.2 U 0.2 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U100000 U 20000 U 3000 U 1000 U 1000 UNA NA NA NA ND U NA ND U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U1000 U 200 U 30 U 10 U 10 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U2000 U 400 U 60 U 8.1 J 11 J10000 U 2000 U 300 U 100 U 100 U10000 U 2000 U 300 U 100 U 100 U500 U 100 U 8 J 3 J 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U23000 1400 260 19 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CLewis County, WVDay 90Day 5Day 12/11/2009Day 0 Day 145/15/092/17/2009 2/20/2009 2/27/2009Location CNA NA NA NA NA500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 UNA NA NA NA NA500 U 100 U 15 U 1.6 J 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U500 U 100 U 15 U 5 U 5 U1500 U 300 U 45 U 15 U 15 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.9 U 1.9 U 2 U 1.9 U 1.9 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 UNA NA NA #N/A #N/A NA ND U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U48 U 48 U 49 U 47 U 48 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.9 U 1.9 U 2 U 1.9 U 1.9 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.9 U 1.9 U 2 U 1.9 U 1.9 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.3 J 2.1 0.34 J 1.9 U 1.9 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U48 U 48 U 49 U 47 U 48 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 0.28 J 0.21 J 9.4 U 9.5 U48 U 48 U 49 U 47 U 48 U48 U 48 U 49 U 47 U 48 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U48 U 48 U 49 U 47 U 48 U48 U 48 U 49 U 47 U 48 U96 U 97 U 98 U 94 U 95 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.9 U 1.9 U 2 U 1.9 U 1.9 U1.9 U 1.9 U 2 U 1.9 U 1.9 U9.6 U 2.9 J 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U190 U 190 U 200 U 190 U 190 U1.9 U 1.9 U 2 U 1.9 U 1.9 U1.9 U 1.9 U 2 U 1.9 U 1.9 U1.9 U 1.9 U 2 U 1.9 U 1.9 U1.9 U 1.9 U 2 U 1.9 U 1.9 U1.9 U 1.9 U 2 U 1.9 U 1.9 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.9 U 1.9 U 2 U 1.9 U 1.9 U1.9 U 1.9 U 2 U 1.9 U 1.9 U9.4 J 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.9 U 1.9 U 2 U 1.9 U 1.9 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.9 U 1.9 U 2 U 1.9 U 1.9 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 0.73 J 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 0.68 J 9.8 U 9.4 U 9.5 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Lewis County, WVDay 90Day 5Day 12/11/2009Day 0 Day 145/15/092/17/2009 2/20/2009 2/27/2009Location C9.6 U 9.7 U 4.1 J 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.9 U 1.9 U 2 U 1.9 U 1.9 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.9 U 1.9 U 2 U 1.9 U 1.9 U1.9 U 1.9 U 2 U 1.9 U 1.9 U1.9 U 1.9 U 2 U 1.9 U 1.9 U1.9 U 1.9 U 2 U 1.9 U 1.9 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.9 U 1.9 U 2 U 1.9 U 1.9 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.9 U 1.9 U 2 U 1.9 U 1.9 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.9 U 1.9 U 2 U 1.9 U 1.9 U1.9 U 1.9 U 2 U 1.9 U 1.9 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U19 U 19 U 20 U 19 U 19 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U0.28 J 0.39 J 2 U 1.9 U 1.9 U1.9 U 1.9 U 2 U 1.9 U 1.6 J9.6 U 9.7 U 9.8 U 9.4 U 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U1.9 U 1.9 U 2 U 1.9 U 1.9 U0.91 J 6.4 J 4.1 J 3 J 9.5 U9.6 U 9.7 U 9.8 U 9.4 U 9.5 U0.96 U 9.7 U 9.8 U 9.4 U 9.5 UNANANANANA0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.097 U0.49 U NA NA 0.48 U 0.97 U0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.097 U0.049 U NA NA 0.048 U 0.240.049 U NA NA 0.048 U 0.097 U0.098 U NA NA 0.096 U 0.19 U2U NANA0.096 U 3.9 U0.39 U NA NA 0.38 U 0.39 U0.39 U NA NA 0.38 U 0.39 U0.39 U NA NA 0.38 U 0.39 U0.39 U NA NA 0.38 U 0.39 U0.39 U NA NA 0.38 U 0.39 U0.39 U NA NA 0.38 U 0.39 U0.39 U NANA0.38 U 0.39 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Lewis County, WVDay 90Day 5Day 12/11/2009Day 0 Day 145/15/092/17/2009 2/20/2009 2/27/2009Location C0.96 U NA NA 0.95 U 0.97 UNA NA NA NA NANA NA NA NA NANA NA NA NA NANA NA NA NA NANANANANANANA NA NA NA NANANANANANANA NA NA NA NANA NA NA NA NANA NA NA NA NANANANANANAPARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 5 U 1620.01 U 0.01 U 0.01 U 0.01 U1.8 J 5.4 J 34.1 J 96438 656 721 10801 35.5 242 7663450 1290 6970 8590234 4900 J 26800 J 78300857 J 435 J 161 305 J0.15 0.75 0.5 G U 2.5 G U230 1500 8400 400000.46 0.5 G U 0.5 G U 2.5 G U0.73 J 0.61 J 0.52 J 0.1 U0.32 4.7 6 2.5 G UNA 4.8 U 350 21.31970 J 19200 J 122000 J 249000 J374 J 348 J 25.9 J 50 G U741 342 161 J 302120 J 577 J 266 J 75.2 J1410 9020 40700 15500025.8 21.8 46.5 92.80.054 B 0.42 0.91 0.1 U16 23.2 3220 153385 31.4 786 17410 U 10 U 10 U 10 U8 1.6 B 2.4 B 3.27.1 7.7 6.6 6.20.065 J 0.01 U 0.028 0.0091 BNA 10.8 9.60 9.60NA3.38 0.210 4.54298 J 887 J 47200 J 358 B67.6 B J 681 J 670 B J 195 B10 U 9.3 B 33.8 B 100 U10 U 9.8 B 13.6 B 100 U10 U 17.5 92.9 54 B10 U 16 17 B 50.7 B111 B 7620 165000 144000075.4 B 4170 226000 J 1500000 J4 U 4 U 20 U 40 U4 U 4 U 20 U 40 U109 B E 5420 12200 13000 J103 B J 5750 J 13000 J 14000 J5 U 5 U 7.4 B 2.5 B5 U 5 U 25 U 1.4 B52700 297000 2260000 J 8500000 J56400 300000 2420000 J 8930000 J4.3 B 32.6 130 50 U2.6 B 20 15 B 6.8 B1.1 B 50 U 250 U 1000 U0.7 B 50 U 250 U 1000 U28.6 22.5 B 2280 250 U25 U 25 U 125 U 250 U1720 14700 140000 J 87800810 10700 28400 787004.7 3 349 45.6 B2.6 B 3 U 15 U 60 U17.5 B 4350 21400 4450028.4 B 4620 22700 J E 4800016700 40800 291000 93300018000 42100 296000 1000000146 1150 3290 4720149 1120 2540 504040 U 10.5 B 50.5 B J 400 U40 U 4.2 B 12 B 400 U6.2 B 17.6 B 187 B 800 U2.1 B 4.1 B 13.3 B 800 U3280 B 38000 144000 1910003540 B 38200 146000 2020005 U 4.3 B 25 U 50 U5 U 5 U 25 U 50 U5 U 5 U 25 U 50 U5 U 5 U 25 U 50 ULocation D2/13/20092/12/2009 2/17/2009 5/13/09Day 90Day 5Greene County, PADay 0 Day 1PARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BLocation D2/13/20092/12/2009 2/17/2009 5/13/09Day 90Day 5Greene County, PADay 0 Day 1321000 2860000 12900000 26900000345000 2950000 14100000 28700000789 J E 24100 J 345000 1220000911 J 24200 J 378000 J E 1300000 J10 U 10 U 50 U 200 U10 U 10 U 50 U 200 U6.7 B 7 B 25.7 B 1000 U5.5 B 6.3 B 500 U 1000 U3.2 B 15.1 B 195 B 130 B J50 U 9.5 B 250 U 124 B J4.3 B 32.6 15 B 50 U43.6 248 2930 J 29.3 B J36 J 108 J 283 J 130 B J0.1 G U 0.1 G U 0.1 G U 0.5 G U0.1 G U 0.1 G U 0.1 G U 0.5 G U0.025 B 0.05 B J 0.24 J 0.2 U0.056 B J 0.053 B J 0.064 B J 0.068 B J2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 15 J 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U400000 U 50000 U 20000 U 1000 UNA NA NA NA2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U4000 U 500 U 200 U 10 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U8000 U 1000 U 140 J 2040000 U 5000 U 2000 U 100 U40000 U 5000 U 2000 U 100 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U54000 7300 400 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CLocation D2/13/20092/12/2009 2/17/2009 5/13/09Day 90Day 5Greene County, PADay 0 Day 1NA NA NA NA2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 UNA NA NA NA2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U6000 U 750 U 300 U 15 U11 U 9.8 U 9.7 U 9.4 U2.2 U 2 U 1.9 U 1.9 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 UNA NA NA NA11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U56 U 49 U 48 U 47 U11 U 9.8 U 9.7 U 9.4 U2.2 U 2 U 1.9 U 1.9 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U2.2 U 2 U 1.9 U 1.9 U11 U 9.8 U 9.7 U 9.4 U7.5 3.7 1.9 U 1.9 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U56 U 49 U 48 U 47 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 0.35 J 9.7 U 1.1 J56 U 49 U 48 U 47 U56 U 49 U 48 U 47 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U56 U 49 U 48 U 47 U56 U 49 U 48 U 47 U110 U 98 U 97 U 94 U11 U 9.8 U 9.7 U 9.52.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U0.97 J 5 J 9.7 U 2.1 J11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U220 U 200 U 190 U 190 U2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U11 U 3.9 J 30 9.4 U11 U 9.8 U 5.6 J 9.4 U11 U 9.8 U 9.7 U 9.4 U2.2 U 2 U 1.9 U 1.9 U11 U 9.8 U 9.7 U 9.4 U2.2 U 2 U 1.9 U 1.9 U11 U 9.8 U 9.7 U 9.4 U11 U 0.84 J 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 0.53 J 5.4 JPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Location D2/13/20092/12/2009 2/17/2009 5/13/09Day 90Day 5Greene County, PADay 0 Day 111 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U2.2 U 2 U 1.9 U 1.9 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U2.2 U 2 U 1.9 U 1.9 U2.2 U 0.31 J 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U2.2 U 2 U 1.9 U 1.9 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 3.2 J2.2 U 2 U 1.9 U 1.9 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U22 U 20 U 19 U 19 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U1.1 J 2 U 0.64 J 1.9 U2.2 U 2 U 1.9 U 2.411 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U0.19 J 2 U 0.19 J 1.9 U17 5.9 J 3.7 J 9.4 U11 U 9.8 U 9.7 U 9.4 U0.96 U 9.8 U 9.7 U 0.97 UNANANANA0.05 U NA NA 0.049 U0.11 NA NA 0.049 U0.05 U NA NA 0.049 U0.05 U NA NA 0.049 U0.05 U NA NA 0.049 U0.05 U NA NA 0.049 U0.5 U NA NA 0.49 U0.05 U NA NA 0.049 U0.05 U NA NA 0.049 U0.0093 J PG NA NA 0.049 U0.05 U NA NA 0.049 U0.067 PG NA NA 0.049 U0.018 J PG NA NA 0.049 U0.05 U NA NA 0.049 U0.05 U NA NA 0.049 U0.05 U NA NA 0.049 U0.053 PG NA NA 0.049 U0.05 U NA NA 0.049 U0.1 U NA NA 0.098 U2U NANA2 U0.4 U NA NA 0.39 U0.4 U NA NA 0.39 U0.4 U NA NA 0.39 U0.4 U NA NA 0.39 U0.4 U NA NA 0.39 U0.4 U NA NA 0.39 U0.4 U NANA0.39 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Location D2/13/20092/12/2009 2/17/2009 5/13/09Day 90Day 5Greene County, PADay 0 Day 10.96 U NA NA 0.97 U420 200 170 63 J10 U 10 U 20 U 47 J10 U 10 U 20 U 28 J26 39 110 410 J10 U 10 U 20 U 10 YJ50 U 50 U 52 100 UJ260 160 160 100 UJNA NA NA 6.3 JNA NA NA 1.6 UJNA NA NA 1.7 UJNANANANAPARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 5 U 40.8 3450.027 0.01 NRU0.01 U 0.01 U 0.01 U15.6 J 36.3 J 70.3 J NA 214 J788 158 106 32.4 2632.8 172 536 880 1430996 1330 17700 4670 85703560 16900 48900 76800 121000 J663 J 167 J 59.4 J 7.5 57.63.9 1.2 0.045 B 2.5 U 5 G U1060 4700 20000 39200 1060000.31 B 1.3 1.5 B J 2.9 15.91.1 J 0.38 J 0.38 J 0.91 J 0.085 B0.14 B 1.2 G U 2.5 G U 2.5 G U 5 G U6.6 U 5 U 5.1 4.9 U 6.14980 J 68400 J 183000 J 256000 J 46800050.3 10.7 B J 40.2 B J 39.8 B J 42.4 B J226 108 46.2 5.9 207308 J 278 J 135 J 87.9 J 40.3 J5910 28900 55100 124000 1990007.8 42.5 86.1 95.5 1460.14 0.11 0.097 B 2.5 G U 0.2 G U1040 7 47 1100 237715 42.6 32.5 74.8 15969 35.5 10 U 10 U 1.9 B J3U 3U 3U 3U 3U7 6.9 6.5 6 5.90.14 J 0.057 J 0.0076 B 0.011 0.0089 B10.4 36.8 18.8 18.8 18.80.05 U 0.0621 0.258 0.05 U 0.05 U166 B 176 B 571 B 539 B J 1020 B J2000 U 2000 U 230 B 467 B J 285 B J100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U100 U 100 U 35.4 B 50.8 B 100 U100 U 27.4 B 54.4 B 81.6 B 100 U2210 26700 434000 1010000 J 21100002560 45700 489000 1000000 264000040 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U414 B J 8360 J 14400 J 16800 18600502 B J 10900 J 16000 J 17200 23700 J50 U 50 U 50 U 4.4 B J 50 U50 U 50 U 50 U 2.1 B 50 U227000 1030000 4950000 9600000 J 19400000265000 1270000 5430000 10500000 J 2370000050 U 50 U 50 U 14 B J 50 U50 U 50 U 50 U 50 U 50 U500 U 500 U 1000 U 1000 U 5000 U500 U 500 U 1000 U 2500 U 5000 U250 U 250 U 250 U 250 U 250 U250 U 250 U 250 U 250 U 250 U1180 12400 28200 74800 1440001230 13600 29700 49800 J 15500030 U 30 U 60 U 38.2 B J 30 U30 U 30 U 34.4 B 150 U 30 U808 11800 34600 56100 1120001000 15300 39400 58500 5610 J49400 B 131000 559000 1000000 181000056100 160000 602000 1120000 J 2260000189 782 2630 5170 J 10400227 967 2880 5590 12800400 U 19.7 B 8.7 B 400 U 400 U400 U 30 B 13.8 B 400 U 400 U400 U 10.6 B 800 U 800 U 400 U400 U 17.9 B 800 U 2000 U 400 U13200 B 63800 173000 299000 59200016600 B 80500 194000 281000 78200050 U 50 U 50 U 30.1 B 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 8.9 B 50 UGreene County4/1/2009 4/7/2009Day 90Day 0 Day 14Day 1 Day 54/17/20094/3/2009 4/17/2009Location EPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BGreene County4/1/2009 4/7/2009Day 90Day 0 Day 14Day 1 Day 54/17/20094/3/2009 4/17/2009Location E1460000 7540000 21300000 32600000 477000001770000 9760000 23400000 31600000 60100000 J23200 139000 650000 1370000 J 2870000 J28000 178000 721000 1380000 J 3640000 J100 U 100 U 200 U 200 U 100 U100 U 100 U 200 U 500 U 27.1 B1000 U 1000 U 1000 U 1000 U 1000 U1000 U 1000 U 1000 U 1000 U 1000 U500 U 500 U 90 B 121 B 500 U500 U 39.5 B 102 B 134 B 500 U50 U 50 U 50 U 50 U 50 U200 U 406 264 200 U 147 B J200 U 471 295 66.1 B 173 B J0.05 G U 0.0086 B 0.5 G U 0.5 G U 0.19 B0.1 G U 0.01 U 0.5 G U 0.5 G U 0.550.2 U 0.2 U 0.2 U 0.2 U 0.2 U0.2 U 0.044 B J 0.2 U 0.2 U 0.2 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U0.72 J 5 U 1.1 J 5 U 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 5 U 0.64 J 5 U 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U1000 U 1000 U 1000 U 1000 U 1000 UNA NA NA NA NA5U 5U 5U 5U 5U5U 5U 5U 5U 5U10 U 10 U 10 U 10 U 10 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U6.4 J 7.9 J 17 J 12 J 20 U100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U5 U 7.8 5.8 17 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 2J 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 5 U 0.67 J 5 U 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 0.73 J 5 U 5 U 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CGreene County4/1/2009 4/7/2009Day 90Day 0 Day 14Day 1 Day 54/17/20094/3/2009 4/17/2009Location ENA NA NA NA NA5U 5U 5U 5U 5U5U 5U 5U 5U 5UNA NA NA NA NA5.6 3.8 J 7.7 13 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U15 U 15 U 5.1 J 3.2 J 15 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 UNA NA NA NA NA10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U50 U 100 U 47 U 48 U 48 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U10 U 0.32 J 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U50 U 100 U 47 U 48 U 48 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 0.87 J 0.38 J 9.5 U50 U 100 U 47 U 48 U 48 U50 U 100 U 47 U 48 U 48 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U50 U 100 U 47 U 48 U 48 U50 U 100 U 47 U 48 U 48 U100 U 210 U 94 U 96 U 95 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U2 U 4.2 U 1.9 U 1.9 U 1.9 U10 U 9 J 10 6.4 J 1.3 J10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U200 U 420 U 190 U 190 U 190 U2 U 4.2 U 1.9 U 1.9 U 1.9 U2 U 4.2 U 1.9 U 1.9 U 1.9 U2 U 4.2 U 1.9 U 1.9 U 1.9 U2 U 4.2 U 1.9 U 1.9 U 1.9 U2 U 4.2 U 1.9 U 1.9 U 1.9 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U2 U 4.2 U 1.9 U 1.9 U 1.9 U4.1 J 21 U 1.6 J 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 0.43 J 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U0.36 J 21 U 0.32 J 9.6 U 9.5 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Greene County4/1/2009 4/7/2009Day 90Day 0 Day 14Day 1 Day 54/17/20094/3/2009 4/17/2009Location E10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U2 U 4.2 U 0.27 J 1.9 U 1.9 U2 U 4.2 U 1.9 U 1.9 U 1.9 U2 U 4.2 U 1.9 U 1.9 U 1.9 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U2 U 4.2 U 1.9 U 1.9 U 1.9 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U20 U 42 U 19 U 19 U 19 U10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U1.3 J 4.2 U 1.9 U 1.9 U 1.9 U2 U 2.6 J 3.2 1.9 U 1 J10 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 U2 U 4.2 U 1.9 U 1.9 U 1.9 U35 430 310 200 5710 U 21 U 9.4 U 9.6 U 9.5 U10 U 21 U 9.4 U 9.6 U 9.5 UNANANANANA0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.062 PG0.49 U NA NA 0.48 U 0.5 U0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.05 U0.049 U NA NA 0.048 U 0.043 J0.049 U NA NA 0.048 U 0.05 U0.098 U NA NA 0.096 U 0.1 U2U NANA1.9 U 2 U0.39 U NA NA 0.38 U 0.4 U0.39 U NA NA 0.38 U 0.4 U0.39 U NA NA 0.38 U 0.4 U0.39 U NA NA 0.38 U 0.4 U0.39 U NA NA 0.38 U 0.4 U0.39 U NA NA 0.38 U 0.4 U0.39 U NANA0.38 U 0.4 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Greene County4/1/2009 4/7/2009Day 90Day 0 Day 14Day 1 Day 54/17/20094/3/2009 4/17/2009Location E0.95 U NA NA 0.96 U 0.99 U10 UJ 5 UJ 5 UJ 10 UJ 10 UJ10 UJ 20 J 10 J 10 UJ 10 UJ10 UJ 5 UJ 5 UJ 10 UJ 10 UJ10 UJ 5 UJ 5 UJ 10 UJ 10 UJ10 UJ 5 UJ 5 UJ 10 UJ 10 UJ1000 UJ 100 UJ 100 UJ 50 UJ 50 UJ1000 UJ 100 UJ 100 UJ 50 UJ 50 UJ100 UJ 10 UJ 50 UJ 500 UJ 500 UJ100 UJ 10 UJ 50 UJ 500 UJ 500 UJ100 UJ 10 UJ 50 UJ 500 UJ 500 UJ230 290 260 380 380PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 5 U 5 U 122 3880.01 U 0.01 U 0.01 U 0.01 U 0.01 U 0.01 U20.8 J 12.9 J 60.3 J 115 J 135 J 168 J2.7 154 75.4 64.8 120 124000.2 U 0.2 U 376 826 1040 160013.2 J 851 J 2470 J 5170 8370 1840018.5 30.7 31500 72000 100000 138000 J3.6 J 288 J 40.2 J 47.3 J 10.8 J 1480NA 0.1 1.2 G U 5 G U 2 B 2.5 G U182 190 12300 34000 53000 770000.39 0.41 1.4 5 G U 2.5 G U 2.5 G U0.51 0.47 0.45 J 0.34 J 0.25 J 0.1 U0.05 U 0.05 U 1.2 G U 5 G U 2.5 G U 2.5 G U4.7 U 7.3 4.9 U 20.4 9.9 802575 J 476 J 124000 J 233000 J 288000 J 480000 J139 59.2 102 60.7 B 89.3 J 32.8 B J3.8 J 205 43.5 62.8 44 J 153080.9 J 126 J 157 J 54 J 60.2 J 11.5 J215 462 61200 116000 157000 20000056.4 33.5 77.7 55.9 127 87.70.043 B 0.44 0.22 0.16 0.09 B 0.1 U16.8 90 B 6.8 204 209 8315.7 145 14.8 45.6 254 13410 U 10 U 10 U 10 U 10 U 10 U5.6 8.8 2.4 B 3 U 3 U 4.86.7 7 6.4 6.4 6.2 5.90.01 U 0.085 0.058 0.016 J 0.01 U 0.239.20 61.6 5 U 13.6 18.8 8.800.0613 0.112 0.0641 0.05 U 0.465 0.6992000 U 2000 U 510 B 950 B 1450 B 25702000 U 189 B 282 B 363 B 395 B 2000 U19 B 100 U 100 U 100 U 100 U 38.3 B100 U 100 U 100 U 100 U 100 U 100 U100 U 100 U 36.9 B 78.4 B 82.8 B 109100 U 100 U 23 B 91.2 B 63.2 B 99 B74.7 B 91.4 B 19200 77100 83100 8720091.6 B J 95.2 B J 16600 J 55200 75700 10400040 U 40 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U 40 U65.9 B J 122 B J 12600 J 12200 J 14700 J 1270022.2 B 39.6 B 12400 16900 J 15400 J 1590050 U 50 U 50 U 2.2 B 4.7 B 3.2 B50 U 50 U 50 U 3 B 3.8 B 2.8 B49800 B 59500 3980000 8880000 14000000 19800000 J63400 J 61800 J 3850000 J 12000000 14300000 24600000 J50 U 50 U 11.4 B 39.3 B 32.8 B 15.8 B50 U 50 U 50 U 12.1 B 11.6 B 16 B500 U 500 U 10.5 B 1000 U 2500 U 5000 U500 U 500 U 9.5 B 1000 U 2500 U 46 B250 U 49.3 B 62.1 B 116 B 73.3 B 250 U250 U 250 U 50.3 B 250 U 250 U 32.4 B882 B 2440 12200 49600 75200 68700 J1000 U 2310 10600 45700 47300 7420030 U 30 U 25.2 B 61 106 B 300 U30 U 30 U 19 B 63.8 150 U 300 U500 U 30.1 B 33900 55900 86000 105000500 U 29.4 B 33000 78800 94500 1270006700 B 7910 B 394000 881000 1380000 18300008690 B 8410 B 386000 1180000 1370000 2320000116 B 140 B 2390 4680 7320 8990 J136 B 128 B 2300 6120 7740 11000400 U 400 U 11.5 B 30.8 B 400 U 400 U400 U 400 U 11.2 B 20.2 B 400 U 400 U400 U 25.1 B 15.3 B 26.4 B 2000 U 4000 U400 U 400 U 9.3 B 800 U 2000 U 4000 U50000 U 50000 U 157000 246000 368000 36600050000 U 50000 U 160000 336000 394000 46100050 U 50 U 50 U 50 U 50 U 49.9 B50 U 50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 5.6 B 50 UDay 5Day 1Day 0Day 90Day 14Washington, PASupply Water4/9/20093/24/2009 3/24/2009 3/27/2009 6/29/20094/1/2009Location FPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 5Day 1Day 0Day 90Day 14Washington, PASupply Water4/9/20093/24/2009 3/24/2009 3/27/2009 6/29/20094/1/2009Location F7980 B 25700 B 14700000 23700000 34000000 390000009540 B 27400 B 14700000 31600000 36400000 47800000220 B 303 B 539000 1350000 2100000 3410000 J274 B 312 B 531000 1880000 2330000 4140000 J100 U 100 U 100 U 200 U 500 U 1000 U100 U 100 U 100 U 200 U 500 U 1000 U1000 U 1000 U 1000 U 1000 U 1000 U 1000 U1000 U 1000 U 1000 U 1000 U 1000 U 1000 U500 U 500 U 39.9 B 126 B 192 B 260 B500 U 500 U 55.3 B 170 B 187 B 264 B50 U 50 U 50 U 11.8 B 11.6 B 15.8 B200 U 59.5 B J 132 B J 106 B 123 B 218200 U 38.8 B 42 B 84.6 B 92.8 B 250 J0.01 U 0.01 U 0.011 0.01 U 0.25 G U 0.25 G U0.01 U 0.02 G U 0.014 0.05 G U 0.25 G U 0.25 G U0.61 B J 0.66 B J 0.065 B J 0.2 U 0.2 U 0.2 U0.66 B J 0.93 B J 0.064 B J 0.2 U 0.2 U 0.2 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 170 J5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 66 J0.61 J 5 U 11 52 33 9805 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 5.2 J 33 J 21 J 8205 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U1000 U 1000 U 2000 U 10000 U 5000 U 50000 UNA NA NA NA NA NA NDU5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U10 U 10 U 20 U 100 U 50 U 500 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U20 U 6 J 14 J 200 U 98 J 1000 U100 U 100 U 200 U 1000 U 500 U 5000 U100 U 100 U 200 U 1000 U 500 U 5000 U5 U 5 U 280 880 400 2905 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 7.6 J 29 J 23 J 2705 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U1.1 J 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 130 J5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 5Day 1Day 0Day 90Day 14Washington, PASupply Water4/9/20093/24/2009 3/24/2009 3/27/2009 6/29/20094/1/2009Location FNA NA NA NA NA NA5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 UNA NA NA NA NA NA NDU1.1 J 5 U 300 920 540 16005 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U5 U 5 U 10 U 50 U 25 U 250 U15 U 15 U 120 340 280 33009.8 U 9.4 U 19 U 10 U 47 U 94 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 UNA NA NA NA NA NA NDU9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 9.8 J 7.1 J 8.3 J 94 U49 U 47 U 94 U 50 U 240 U 470 U9.8 U 9.4 U 19 U 10 U 47 U 94 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U9.8 U 9.4 U 19 U 10 U 47 U 94 U0.85 J 1.9 U 3.8 U 2 U 9.4 U 19 U9.8 U 9.4 U 9 J 7.9 J 7.5 J 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U49 U 47 U 94 U 50 U 240 U 470 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 14 J 11 12 J 94 U49 U 47 U 94 U 50 U 240 U 470 U49 U 47 U 94 U 50 U 240 U 470 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U49 U 47 U 94 U 50 U 240 U 470 U49 U 47 U 94 U 50 U 240 U 470 U98 U 94 U 190 U 100 U 470 U 940 U9.8 U 9.4 U 19 U 10 U 47 U 94 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U0.46 J 9.4 U 19 U 11 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U200 U 190 U 380 U 200 U 940 U 1900 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U2.2 J 9.4 U 19 U 33 870 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U9.8 U 9.4 U 19 U 10 U 47 U 94 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U9.8 U 9.4 U 19 U 10 U 47 U 9 J2.3 J B 1.8 J B 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 0.29 J 19 U 14 47 U 94 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 5Day 1Day 0Day 90Day 14Washington, PASupply Water4/9/20093/24/2009 3/24/2009 3/27/2009 6/29/20094/1/2009Location F9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U9.8 U 9.4 U 19 U 10 U 47 U 94 U1.3 J 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U20 U 19 U 38 U 20 U 94 U 190 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U0.6 J 1.9 U 3.8 U 0.29 J 9.4 U 3 J2 U 1.9 U 16 15 16 19 U9.8 U 9.4 U 19 U 10 U 47 U 94 U9.8 U 9.4 U 19 U 10 U 47 U 94 U2 U 1.9 U 3.8 U 2 U 9.4 U 19 U9.8 U 370 520 250 220 1409.8 U 9.4 U 19 U 10 U 47 U 94 U0.95 U 0.95 U 19 U 10 U 0.95 U 4.8 UNANANANANANA0.048 U 0.047 U NA NA 0.048 U 0.049 U0.048 U 0.047 U NA NA 0.048 U 0.049 U0.048 U 0.047 U NA NA 0.048 U 0.049 U0.048 U 0.047 U NA NA 0.048 U 0.12 PG0.048 U 0.047 U NA NA 0.048 U 0.049 U0.048 U 0.047 U NA NA 0.048 U 0.049 U0.48 U 0.47 U NA NA 0.48 U 0.49 U0.048 U 0.047 U NA NA 0.048 U 0.049 U0.048 U 0.047 U NA NA 0.048 U 0.049 U0.048 U 0.047 U NA NA 0.048 U 0.049 U0.048 U 0.047 U NA NA 0.048 U 0.049 U0.048 U 0.047 U NA NA 0.048 U 0.049 U0.048 U 0.047 U NA NA 0.048 U 0.049 U0.048 U 0.047 U NA NA 0.048 U 0.049 U0.048 U 0.047 U NA NA 0.048 U 0.049 U0.048 U 0.047 U NA NA 0.048 U 0.049 U0.048 U 0.047 U NA NA 0.048 U 0.0930.048 U 0.047 U NA NA 0.048 U 0.049 U0.095 U 0.094 U NA NA 0.097 U 0.098 U1.9 U 1.9 U NANA1.9 U 2 U0.38 U 0.38 U NA NA 0.39 U 0.39 U0.38 U 0.38 U NA NA 0.39 U 0.39 U0.38 U 0.38 U NA NA 0.39 U 0.39 U0.38 U 0.38 U NA NA 0.39 U 0.39 U0.38 U 0.38 U NA NA 0.39 U 0.39 U0.38 U 0.38 U NA NA 0.39 U 0.39 U0.38 U 0.38 U NANA0.39 U 0.39 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 5Day 1Day 0Day 90Day 14Washington, PASupply Water4/9/20093/24/2009 3/24/2009 3/27/2009 6/29/20094/1/2009Location F0.95 U 0.95 U NA NA 0.95 U 4.8 U1 U 1 U 1 U 5 UJ 10 UJ 200 UJ1 U 1 U 1 U 5 UJ 10 UJ 200 UJ1 U 1 U 1 U 5 UJ 10 UJ 200 UJ1 U 1.2 3.4 5 UJ 10 UJ 4500 J1 U 1 U 1 U 5 UJ 10 UJ 200 UJ10 U 44 10 U 100 UJ 100 UJ 290 J10 U 10 U 31 B 100 UJ 100 UJ 250 UJNA NA 10 UJ 10 UJ 100 UJ 50 UJNA NA 10 UJ 10 UJ 100 UJ 50 UJNA NA 10 UJ 10 UJ 100 UJ 50 UJNA75 1000 230 51000 100000PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B1230 5 U 5 19.4 1490.01 U 0.01 U 0.01 U 0.01 U 0.01 U441 J 71.4 J NA 359 J 220 J189 302 144 7.3 2 U0.2 U 261 553 697 171502 2100 4470 12800 12700 J86 43300 77200 102000 166000 J11.6 124 J 58.4 43 J 16.40.19 2.2 B 2.4 B 2.5 G U 5 G U130 15000 44000 55000 960003.4 1.6 B 2 B 2.5 G U 5 G U2.4 J 1.9 J 0.63 J 0.16 J 0.051 B2.5 G U 2.5 G U 2.5 G U 2.5 G U 1464.7 U 4.6 U 10.8 4.6 U 4.8 U6720 J 147000 J 278000 J 360000 J 7420002920 19 B J 39.2 B J 49.4 B J 100 G U11.4 J 123 60.8 42.2 63.35 U 124 J 72.4 J 47.7 J 25 J1920 74600 125000 169000 298000400 69.9 94.9 130 157 J0.26 0.19 2.5 G U 2.5 G U 1 G U4 68 260 162 71.54.7 126 92 32.9 94.510 U 10 U 10 U 10 U 10 U3 U 3 U 3 U 1.6 B 3 U6 7 6.3 6.4 5.80.017 J 0.01 U 0.0084 B 0.011 J 0.01 U5 U 5.60 23.2 13.6 NA0.0933 2.94 0.736 1.06 NA2000 U 505 B 927 B J 835 B J 173 B J2000 U 358 B 508 B J 562 B J 167 B J100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U100 U 28.2 B 54.2 B 77.3 B 100 U100 U 37.4 B 70.5 B 82.3 B 100 U339 B 1160000 3220000 J 5150000 J 8450000348 B 1340000 3260000 5070000 753000040 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U59.3 B J 3030 J 3840 3880 299068.7 B J 3470 J 3890 3820 2680 J50 U 50 U 3 B J 3.8 B J 50 U50 U 50 U 50 U 3.2 B 50 U32900 B 4070000 9270000 J 13100000 J 2290000031800 B 4360000 9700000 J 14800000 J 2050000050 U 50 U 20.8 B J 12.7 B J 50 U50 U 50 U 50 U 6.6 B 50 U7.9 B 2500 U 1000 U 5000 U 5000 U14.2 B 2500 U 5000 U 5000 U 5000 U120 B 250 U 73.3 B 250 U 250 U85.3 B 250 U 250 U 250 U 250 U14300 15700 33500 39200 5870013100 3690 16700 J 31500 J 4170030 U 30 U 40.4 B J 78 B J 30 U30 U 30 U 150 U 150 U 30 U34.1 B 80300 153000 201000 26200038.7 B 93000 155000 202000 230000 J6190 B 271000 608000 781000 12800006240 B 293000 647000 J 875000 J 117000067.2 B 1680 3440 J 4780 J 974073.7 B 1930 3550 5170 8760400 U 8.9 B 12.4 B 400 U 400 U400 U 12.1 B 400 U 400 U 54.4 B457 14.9 B 800 U 2000 U 400 U452 20.1 B 2000 U 2000 U 400 U50000 U 127000 210000 312000 54700050000 U 144000 235000 274000 47700050 U 50 U 50 U 39.4 B 50 U50 U 50 U 50 U 49.5 B 50 U50 U 50 U 9.3 B 8.4 B 50 U50 U 50 U 50 U 8.1 B 50 UDay 1Day 0 Day 15Day 510/21/20094/13/20093/31/2009 4/8/2009Lycoming County, PADay 904/22/2009Location GPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 1Day 0 Day 15Day 510/21/20094/13/20093/31/2009 4/8/2009Lycoming County, PADay 904/22/2009Location G45000 B 18100000 30800000 40300000 5860000044700 B 20900000 31400000 41100000 50700000 J691 947000 2350000 J 3650000 J 6390000 J686 1090000 2530000 J 3710000 J 5710000 J100 U 100 U 200 U 500 U 26.4 B100 U 100 U 500 U 500 U 53.8 B1000 U 1000 U 1000 U 1000 U 1000 U1000 U 1000 U 1000 U 1000 U 29.8 B500 U 55.9 B 133 B 148 B 500 U500 U 105 B 121 B 138 B 500 U50 U 50 U 50 U 50 U 50 U40.7 B 200 U 67.6 B J 52.2 B J 48 B J46.9 B 200 U 41.6 B 49.8 B 42.3 B J0.01 U 0.5 G U 1 G U 2.5 G U 2 G U0.01 U 0.5 G U 1 G U 2.5 G U 2 G U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 1.3 J 5 U 5 U 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U1000 U 1000 U 1000 U 1000 U 1000 UNA NA NA NA NA5U 5U 5U 5U 5U5U 5U 5U 5U 5U10 U 10 U 10 U 10 U 10 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U20 U 13 J 16 J 26 12 J100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U2.2 J 5 U 5 U 5 U 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 1.7 J 5 U 5 U 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 1Day 0 Day 15Day 510/21/20094/13/20093/31/2009 4/8/2009Lycoming County, PADay 904/22/2009Location GNA NA NA NA NA5U 5U 5U 5U 5U5U 5U 5U 5U 5UNA NA NA NA NA5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U15 U 15 U 15 U 15 U 15 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 UNA NA NA NA NA9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U47 U 46 U 47 U 48 U 50 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 2.7 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U47 U 46 U 47 U 48 U 50 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U47 U 46 U 47 U 48 U 50 U47 U 46 U 47 U 48 U 50 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U47 U 46 U 47 U 2.6 J 50 U47 U 46 U 47 U 48 U 50 U94 U 92 U 94 U 95 U 100 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 0.22 J 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U0.21 J 0.98 J 0.81 J 0.38 J 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U190 U 180 U 190 U 190 U 200 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 1.1 J 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 1Day 0 Day 15Day 510/21/20094/13/20093/31/2009 4/8/2009Lycoming County, PADay 904/22/2009Location G9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 0.22 J 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U19 U 18 U 19 U 19 U 20 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 55 30 14 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 UNANANANANA0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.48 U NA NA 0.47 U 0.72 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.095 U NA NA 0.094 U 0.14 U1.9 U NANA1.9 U 2.9 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NANA0.38 U 0.4 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 1Day 0 Day 15Day 510/21/20094/13/20093/31/2009 4/8/2009Lycoming County, PADay 904/22/2009Location G0.94 U NA NA 0.94 U 1 U5 UJ NA 10 UJ 10 UJ NA5 UJ NA 10 UJ 10 UJ NA5 UJ NA 10 UJ 10 UJ NA8.3 J NA 58 J 39 J NA5 UJ NA10 UJ 10 UJ NA100 UJ NA 100 UJ 100 UJ NA100 UJ NA100 UJ 100 UJ NA10 UJ NA 100 U 10 J NA10 UJ NA 100 U 18 J NA10 UJ NA 100 U 10 UJ NA250 NA430 10 UJ NAPARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 87.5 5 U 447 90.5 7200.01 NR U 0.01 0.01 NR U 0.01 U 0.01 U 0.01 U18.1 J 64.8 J 50.2 J NA 291 J 416110 1740 737 138 2070 4.131.9 41.7 176 1190 1600 1990924 6410 2470 6710 17600 26303000 2810 14500 110000 143000 18500079.7 J 1270 J 612 J 140 73.2 3.3 J1.2 58.3 32.9 17.3 5 G U 5 G U1080 1010 5200 55000 63000 780000.5 G U 0.5 G U 0.99 B 0.081 B 5 G U 5 G U0.036 B J 0.15 J 0.5 J 0.22 J 0.091 B J 0.1 U4.9 0.5 G U 2.5 G U 5 G U 5 G U 42.84.8 U 64.1 4.8 U 16.2 75.4 4.6 U10100 J 9980 J 49400 J 398000 J 482000 J 600000 J53.3 J 58.5 J 68 J 47.1 B J 61.6 B J 100 G U78.3 1260 443 J 119 J 89.2 J 475.8 J 81.8 J 253 J 54.5 J 38.1 J 7.5 J5510 7080 19200 150000 206000 34500016.7 73.9 52.9 204 261 3120.14 0.16 0.083 B 2.5 G U 2.5 G U 0.1 U24 230 27.5 246 439 43633.7 305 53.8 198 238 10620.2 680 75.6 10 U 10 U 10 U3 U 3 U 3 U 3 U 1.6 B 47.3 5.2 7.5 5.9 5.9 5.20.031 0.072 0.055 0.31 0.31 J 0.02 J15.2 18.8 16.8 8.00 17.2 11.20.05 U 0.0506 0.05 U 0.737 1.4 0.469264 B E 425 B 666 B 2460 J 2630 B J 173 B2000 U 223 B 466 B 731 B J 785 B J 2000 U100 U 100 U 100 U 20 B 200 U 100 U100 U 100 U 100 U 100 U 200 U 100 U100 U 100 U 100 U 124 135 B 100 U100 U 100 U 100 U 107 140 B 100 U5480 6280 11700 1550000 J 1800000 J 21600006120 6320 18900 1320000 1860000 237000040 U 40 U 40 U 40 U 80 U 40 U40 U 40 U 40 U 40 U 80 U 2.7 B2450 J 2580 J 12200 J 97900 114000 1450002680 J 2470 J 14600 J 91300 115000 15500050 U 50 U 50 U 8.6 B J 12.4 B J 50 U50 U 50 U 50 U 5.7 B 9 B 50 U315000 329000 1180000 13600000 J 16400000 J 24000000 J325000 301000 1340000 13900000 J 19100000 J 24800000 J50 U 50 U 13.5 B 92.4 J 94.2 B J 13.5 B50 U 50 U 13.8 B 23.8 B 37.8 B 7.3 B500 U 500 U 500 U 2500 U 2500 U 5000 U500 U 500 U 500 U 2500 U 2500 U 5000 U250 U 250 U 246 B 102 B 241 B 250 U250 U 250 U 199 B 250 U 68 B 250 U4310 3560 8140 180000 242000 1580004010 3920 7920 107000 J 135000 J 15100030 U 30 U 33 104 B J 596 J 30 U30 U 30 U 34.3 150 U 148 B 30 U2240 2340 8460 96800 115000 1370002450 2290 10300 95000 123000 14800030600 B 32300 B 102000 1080000 1290000 174000031200 B 29200 B 115000 1090000 J 1460000 J 1830000237 253 489 2650 J 3470 J 3040242 E 235 558 2260 3400 3230400 U 400 U 38.9 B 60.1 B 32.4 B 400 U400 U 400 U 51.5 B 400 U 800 U 400 U11.1 B 400 U 71 B 2000 U 2000 U 400 U400 U 7.8 B 77.6 B 2000 U 2000 U 18 B53600 57400 187000 2430000 2820000 395000056900 54600 224000 2270000 2920000 408000050 U 35.3 B 50 U 50 U 95.6 B 50 U50 U 50 U 50 U 50 U 100 U 50 U50 U 50 U 50 U 8.1 B 100 U 50 U50 U 50 U 50 U 12.2 B 100 U 50 U4/7/20097/22/20094/7/2009 4/8/2009 4/13/2009 4/22/2009Day 14 Day 90Westmoreland County, PADay 5Day 1Supply Water Day 0Location HPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B4/7/20097/22/20094/7/2009 4/8/2009 4/13/2009 4/22/2009Day 14 Day 90Westmoreland County, PADay 5Day 1Supply Water Day 0Location H1380000 1460000 5160000 48100000 64900000 758000001490000 1410000 6130000 46100000 62600000 8250000076200 78500 281000 4440000 J 5410000 J 8020000 J81100 74300 330000 4290000 J 6280000 J 8460000 J100 U 100 U 100 U 500 U 151 B 168100 U 100 U 100 U 500 U 172 B 1961000 U 1000 U 1000 U 1000 U 2000 U 1000 U1000 U 1000 U 1000 U 1000 U 2000 U 24.2 B500 U 500 U 92 B 313 B 247 B 500 U28 B 27.8 B 136 B 153 B 207 B 500 U50 U 50 U 13.8 B 23.8 B 37.8 B 13.5 B40.5 B E 176 B 82.7 B 1230 J 2290 J 81144.1 B 169 B 89.1 B 753 1790 8400.01 U 0.05 G U 0.02 G U 0.25 G U 1 G U 0.25 G U0.019 0.05 G U 0.019 B 0.25 G U 0.5 G U 0.5 G U0.2 U 0.2 U 0.051 B 0.2 U 0.2 U 0.2 U0.071 B J 0.093 B J 0.046 B J 0.27 0.2 U 0.2 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U24000 5 U 4000 630 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U11000 5 U 1900 280 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U800000 U 1000 U 100000 U 20000 U 1000 U 1000 UNA NA NA NA NA NA4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U8000 U 10 U 1000 U 200 U 10 U 10 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U66000 23 5800 1600 20 13 J80000 U 100 U 10000 U 2000 U 100 U 100 U80000 U 100 U 10000 U 2000 U 100 U 100 U4000 U 6.7 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U10000 5 U 1400 260 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C4/7/20097/22/20094/7/2009 4/8/2009 4/13/2009 4/22/2009Day 14 Day 90Westmoreland County, PADay 5Day 1Supply Water Day 0Location HNA NA NA NA NA NA4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 UNA NA NA NA NA NA4000 U 3 J 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U4000 U 5 U 500 U 100 U 5 U 5 U5200 J 15 U 860 J 130 J 15 U 15 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 UNA NA NA NA NA NA9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U48 U 49 U 47 U 47 U 48 U 47 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U0.72 J 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U48 U 49 U 47 U 47 U 48 U 47 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U0.19 J 9.8 U 9.4 U 9.4 U 9.5 U 0.28 J48 U 49 U 47 U 47 U 48 U 47 U48 U 49 U 47 U 47 U 48 U 47 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U48 U 49 U 47 U 47 U 48 U 47 U48 U 49 U 47 U 47 U 48 U 47 U97 U 98 U 94 U 94 U 95 U 94 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U190 U 200 U 190 U 190 U 190 U 190 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 16 9.4 U 10 20 5 J9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 1.7 J 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 1.3 J 1.3 J 11 0.39 JPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 80824/7/20097/22/20094/7/2009 4/8/2009 4/13/2009 4/22/2009Day 14 Day 90Westmoreland County, PADay 5Day 1Supply Water Day 0Location H9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 7.2 J9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U0.13 J 2 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U19 U 20 U 19 U 19 U 19 U 19 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 0.8 J 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U1.9 U 2 U 1.9 U 1.9 U 1.9 U 1.9 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 U9.7 U 9.8 U 9.4 U 9.4 U 9.5 U 9.4 UNANANANANA#N/A0.048 U 0.048 U NA NA 0.048 U 0.048 U0.048 U 0.048 U NA NA 0.048 U 0.048 U0.048 U 0.048 U NA NA 0.048 U 0.048 U0.048 U 0.048 U NA NA 0.048 U 0.350.048 U 0.048 U NA NA 0.048 U 0.048 U0.048 U 0.048 U NA NA 0.048 U 0.048 U0.48 U 0.48 U NA NA 0.48 U 0.48 U0.048 U 0.048 U NA NA 0.048 U 0.048 U0.048 U 0.048 U NA NA 0.048 U 0.048 U0.048 U 0.22 PG NA NA 0.048 U 0.048 U0.048 U 0.048 U NA NA 0.42 0.048 U0.048 U 0.048 U NA NA 0.27 PG 0.048 U0.048 U 0.048 U NA NA 0.07 PG 0.048 U0.048 U 0.048 U NA NA 0.064 PG 0.048 U0.048 U 0.048 U NA NA 0.057 PG 0.048 U0.048 U 0.048 U NA NA 0.048 U 0.048 U0.048 U 0.048 U NA NA 0.017 J PG 0.048 U0.048 U 0.048 U NA NA 0.048 U 0.048 U0.096 U 0.096 U NA NA 0.095 U 0.095 U1.9 U 1.9 U NANA1.9 U 1.9 U0.38 U 0.38 U NA NA 0.38 U 0.38 U0.38 U 0.38 U NA NA 0.38 U 0.38 U0.38 U 0.38 U NA NA 0.38 U 0.38 U0.38 U 0.38 U NA NA 0.38 U 0.38 U0.38 U 0.38 U NA NA 0.38 U 0.38 U0.38 U 0.38 U NA NA 0.38 U 0.38 U0.38 U 0.38 U NANA0.38 U 0.38 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 104/7/20097/22/20094/7/2009 4/8/2009 4/13/2009 4/22/2009Day 14 Day 90Westmoreland County, PADay 5Day 1Supply Water Day 0Location H0.96 U 0.95 U NA NA 0.95 U 0.95 U31 J 450 J 280 J NA 66 J 10 J5 UJ 10 UJ 10 UJ NA 10 UJ 10 UJ5 UJ 10 UJ 10 UJ NA 10 UJ 10 UJ5 UJ 10 UJ 10 UJ NA 10 UJ 10 UJ5 UJ 10 UJ 10 UJ NA10 UJ 10 UJ100 UJ 1000 UJ 100 UJ NA 100 UJ 100 UJ100 UJ 1000 UJ 300 J NA100 UJ 100 UJ50 UJ 50 UJ 50 UJ NA 50 UJ 100 UJ50 UJ 50 UJ 50 UJ NA 50 UJ 100 UJ50 UJ 50 UJ 50 UJ NA 50 UJ 100 UJ57 170 260 NA1600 700PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 5 U 123 216 3360.01 U 0.01 U 0.01 U 0.01 U 0.01 U 0.01 U0.064 B 5.9 127 199 J 229 278 J2 U 578 399 99.4 10.4 3.40.22 1 238 901 1010 151018.7 2560 8790 195 12100 20200 J49.9 90.2 58700 148000 181000 1960003.2 J 577 600 59.6 26.5 13.20.05 U 0.05 U 2.5 G U 2.5 G U 5 G U 5 G U38 42 8600 42000 50800 1040000.05 U 0.02 B 2.5 G U 2.5 G U 5 G U 7.40.1 U 0.59 1.1 0.1 U 0.1 U 0.580.05 U 0.034 B 2.5 G U 2.5 G U 52 5 G U4.8 U 62.2 53.9 4.8 U 4.8 U 4.7247 J 362 J 200000 J 470000 J 570000 J 7630008.3 J 8.4 J 36.6 B J 50 G U 100 G U 44.2 B J4.7 J 607 610 48 12.8 149.3 J 33.4 J 175 J 48.8 J 37.3 J 25.3 J400 265 122000 238000 261000 2710003 U 65.4 150 160 131 2180.14 0.062 B 0.084 B 0.45 0.1 U 0.08 B2 B 192 308 696 65.2 823.1 75.2 461 203 180 67.210 U 4.1 B 10 U 10 U 10 U 3.6 B1.6 B 3 U 3 U 3 U 3 U 3 U7.3 7.6 6.6 5.8 5.6 5.10.01 U 0.028 0.015 0.022 0.017 0.01 U21.6 27.6 NA 6.80 31.2 NA0.240 0.05 U NA1.31 0.191 NA2000 U 2000 U 1750 B J 418 B J 846 B 904 B J2000 U 227 B 286 B J 596 B J 983 B 130 B J100 U 100 U 31.5 B 47.2 B 27.2 B 100 U100 U 100 U 18.9 B 200 U 200 U 100 U100 U 100 U 42.9 B 59.6 B 89.2 B 100 U100 U 100 U 29.9 B 62.6 B 75.6 B 100 U1640 B 1170 B 516000 1400000 2460000 46700001580 B J 1500 B J 532000 J 1740000 2500000 581000040 U 40 U 40 U 80 U 80 U 3.4 B40 U 40 U 40 U 80 U 80 U 6.8 B34.3 B J 33.9 B J 5930 J 11900 16400 1870044.2 B J 49.9 B J 6240 15400 16800 24300 J50 U 50 U 2.9 B 9.6 B 11.8 B J 3.5 B J50 U 50 U 2.6 B 11.4 B 12.2 B 3 B11600 B J 9900 B J 2950000 9400000 J 17300000 J 3300000012000 B J 13000 B J 3060000 11700000 17600000 J 4100000050 U 50 U 50.4 12.2 B 28.8 B 9.7 B50 U 50 U 18.7 B 100 U 24.4 B 8 B500 U 500 U 1000 U 2500 U 2500 U 5000 U500 U 500 U 1000 U 2500 U 2500 U 5000 U250 U 250 U 68.3 B 500 U 79 B 48.1 B250 U 250 U 35 B 500 U 500 U 28.6 B192 B 198 B 58700 49700 76600 1310001000 U 175 B 21000 39100 J 53900 15200030 U 30 U 60 U 150 U 150 U 13.2 B30 U 30 U 60 U 150 U 150 U 30 U42.2 B 29.7 B 34600 97600 170000 32300032.7 B 51.7 B 36500 125000 172000 323000 J1840 B 1360 B 177000 604000 1100000 20200001830 B 1720 B 185000 765000 J 1110000 255000013.9 B 150 U 2840 5520 9560 16900150 U 11.5 B 2870 6810 9630 21200400 U 400 U 90 B 27.6 B 34.4 B 400 U400 U 400 U 84.2 B 29.2 B 31.8 B 400 U400 U 400 U 66.8 B 2000 U 2000 U 400 U400 U 400 U 66.8 B 2000 U 2000 U 400 U50000 U 50000 U 378000 811000 1300000 28600002240 B 3790 B 410000 1040000 1320000 385000050 U 50 U 50 U 100 U 100 U 50 U50 U 50 U 50 U 100 U 100 U 50 U50 U 50 U 50 U 100 U 100 U 50 U50 U 50 U 50 U 100 U 100 U 50 UDay 14Day 5Day 15/19/20095/9/2009 5/9/20095/28/2009 10/20/20095/15/2009Day 90Cameron County, PADay 0Supply WaterLocation IPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 14Day 5Day 15/19/20095/9/2009 5/9/20095/28/2009 10/20/20095/15/2009Day 90Cameron County, PADay 0Supply WaterLocation I24400 B 54200 34700000 65100000 85600000 9550000024900 B 70800 35000000 83400000 88000000 117000000 J1500 1070 492000 J 1800000 3120000 6290000 J1460 J 1340 J 500000 J 2210000 J 3210000 J 7820000 J100 U 100 U 200 U 500 U 500 U 26.8 B100 U 100 U 200 U 500 U 500 U 100 U1000 U 1000 U 1000 U 2000 U 2000 U 1000 U1000 U 1000 U 1000 U 2000 U 2000 U 1000 U29.9 B J 27.1 B J 69.9 B 143 B 197 B 500 U29.6 B J 24.4 B J 44.3 B 211 B 230 B 500 U50 U 50 U 50 U 100 U 24.4 B 50 U25.7 B J 45.7 B J 314 269 B J 591 J 810 J61.5 B J 79.4 B J 187 B 195 B 566 992 J0.25 G U 0.25 G U 0.5 U 0.25 G U 0.5 G U 0.5 G U0.25 G U 0.25 G U 0.27 B 0.25 U 0.25 G U 0.5 G U0.053 B J 0.044 B J 0.2 U 0.2 U 0.2 U 0.2 U0.05 B J 0.47 B J 0.2 U 0.2 U 0.2 U 0.2 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 3.1 J 5 U 2.4 J 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 2.3 J 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U1000 U 1000 U 5000 U 1000 U 1000 U 1000 UNA NA NA NA NA NA5 U 5 U 25 U 5 U 5 U 5 U5 U 7.5 25 U 5 U 5 U 5 U10 U 10 U 50 U 10 U 10 U 10 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U6.3 J B 20 U 390 130 25 20 U100 U 100 U 500 U 100 U 100 U 100 U100 U 100 U 500 U 100 U 100 U 100 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 1.6 J 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 13 B 25 U 5 U 5 U 5 U5 U 0.95 J 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 14Day 5Day 15/19/20095/9/2009 5/9/20095/28/2009 10/20/20095/15/2009Day 90Cameron County, PADay 0Supply WaterLocation INA NA NA NA NA NA5 U 5 U 25 U 5 U 5 U 5 U5 U 1.3 J 8.9 J 5 U 5 U 5 UNA NA NA NA NA NA5 U 6.7 25 U 5 U 3 J 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 0.81 J 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U15 U 2.6 J 75 U 15 U 6.9 J 15 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 UNA NA NA NA NA NA9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U47 U 48 U 470 U 47 U 48 U 100 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 0.67 J 1.9 U 4 U9.4 U 9.5 U 94 U 0.53 J 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U47 U 48 U 470 U 1.3 J 48 U 100 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 1.2 J 8.1 J 20 U47 U 48 U 470 U 47 U 48 U 100 U47 U 48 U 470 U 47 U 48 U 100 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 0.75 J 9.7 U 20 U47 U 48 U 470 U 47 U 48 U 100 U47 U 48 U 470 U 47 U 48 U 100 U94 U 95 U 940 U 94 U 97 U 200 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 0.9 J 1.9 U 4 U1.9 U 1.9 U 19 U 0.84 J 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U190 U 190 U 1900 U 190 U 190 U 400 U1.9 U 1.9 U 19 U 0.97 J 1.9 U 4 U1.9 U 1.9 U 19 U 6.7 1.9 U 4 U1.9 U 1.9 U 19 U 10 1.9 U 4 U1.9 U 1.9 U 19 U 6.9 1.9 U 4 U1.9 U 1.9 U 19 U 5.9 1.9 U 4 U9.4 U 9.5 U 41 J 17 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U9.4 U 9.5 U 94 U 6.9 J 4 J 1.4 J9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 0.85 J 1.9 U 0.29 J B9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 11 1.9 U 4 U9.4 U 9.5 U 94 U 0.87 J 9.7 U 20 U9.4 U 9.5 U 94 U 1.3 J 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 0.87 J 9.7 U 20 U9.4 U 9.5 U 94 U 5.3 J 9.7 U 20 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 14Day 5Day 15/19/20095/9/2009 5/9/20095/28/2009 10/20/20095/15/2009Day 90Cameron County, PADay 0Supply WaterLocation I9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1 J 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 5.5 19 U 6.1 1.9 U 4 U1.9 U 1.9 U 19 U 0.82 J 1.9 U 4 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 9.5 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U1.9 U 1.9 U 19 U 1 J 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U19 U 19 U 190 U 19 U 19 U 40 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 0.89 J 1.9 U 4 U1.9 U 1.9 U 19 U 0.7 J 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 0.89 J 1.9 U 4 U9.4 U 4.5 J 640 310 9.7 U 429.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 UNANANANANANA0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.37 0.05 U0.48 U 0.47 U NA NA 0.48 U 0.5 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.095 U 0.094 U NA NA 0.095 U 0.1 U1.9 U 1.9 U NANA1.9 U 2 U0.38 U 0.38 U NA NA 0.38 U 0.4 U0.38 U 0.38 U NA NA 0.38 U 0.4 U0.38 U 0.38 U NA NA 0.38 U 0.4 U0.38 U 0.38 U NA NA 0.38 U 0.4 U0.38 U 0.38 U NA NA 0.38 U 0.4 U0.38 U 0.38 U NA NA 0.38 U 0.4 U0.38 U 0.38 U NANA0.38 U 0.4 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 14Day 5Day 15/19/20095/9/2009 5/9/20095/28/2009 10/20/20095/15/2009Day 90Cameron County, PADay 0Supply WaterLocation I0.95 U 0.97 U NA NA 0.95 U 1 U10 UJ 20 UJ 10 UJ 10 UJ 10 UJ UJ10 UJ 20 UJ 10 UJ 10 UJ 10 UJ UJ10 UJ 20 UJ 10 UJ 10 UJ 10 UJ UJ10 UJ 130 J 52 J 59 J 48 J J10 UJ 20 UJ 10 UJ 10 UJ 10 UJ UJ100 UJ 200 UJ 100 UJ 100 UJ 100 UJ UJ100 UJ 200 UJ 100 UJ 100 UJ 100 UJ UJ1 U 50 UJ 10 UJ 10 UJ 100 UJ UJ1 U 50 UJ 10 UJ 10 UJ 100 UJ UJ1 U 50 UJ 10 UJ 10 UJ 100 UJ UJNANANA57 460PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5U 5U 5U 5U 5U0.01 U 0.01 U 0.01 NR U 0.01 U 0.01 U0.017 B J 5.6 J 13.2 36.9 17.8 J2 U 47.1 36.7 47.5 20.30.14 B 36.6 39.1 233 6510 U 47400 397 4870 853042.3 2180 2460 26400 8060 J3.2 J 168 J 207 J 30.7 J 82.80.033 B 0.05 U 0.5 G U 1.2 G U 0.5 G U140 1300 1060 7800 31001.7 1.6 0.83 2.3 0.5 G U1.8 2 0.94 0.89 0.920.05 U 0.05 U 0.39 B 1.2 G U 1.84.8 U 29.2 7.3 4.8 U 4.8 U380 J 9280 J 8740 J 90500 J 32000 J43.7 27.7 17.4 J 17.6 B J 10 G U2.2 569 56.6 27.5 23.671.4 J 191 J 107 J 187 J 119 J746 4840 5090 48700 191003 U 17.1 14.2 96.1 17.90.044 B 0.072 B 0.14 0.088 B 0.39.6 230 330 68.8 11501.3 101 330 30.2 52410 U 4.6 B 15.2 10 U 10 U2.4 B 3 U 3 U 3 U 3 U7.2 7.2 7.4 6.6 6.80.01 J 0.027 0.03 0.01 U 0.009 B10.0 20.4 13.2 6.00 9.60.962 0.05 U 0.134 0.0761 0.137249 B J 400 B J 4030 J 111 B 4680 J2000 U 2000 U 212 B 2000 U 266 B J100 U 100 U 100 U 35.8 B 25.7 B100 U 100 U 100 U 29.9 B 100 U100 U 100 U 34.3 B 32.1 B 60.4 B100 U 100 U 100 U 55.3 B 100 U338 B 87100 121000 1210000 589000241 B J 84400 J 64400 J 1290000 J 496000 J40 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U29.8 B J 156 B J 1120 B J 3140 J 885 B J39.2 B 202 B 1180 B 3500 J 901 B50 U 50 U 2.5 B 50 U 1.5 B50 U 50 U 50 U 50 U 50 U37500 B J 241000 J 305000 J 1790000 J 84700043200 B 293000 318000 1950000 J 92800050 U 50 U 359 15.1 B 46050 U 50 U 5.8 B 50 U 5.7 B500 U 500 U 500 U 500 U 500 U500 U 500 U 500 U 500 U 500 U250 U 250 U 41.3 B 250 U 253250 U 250 U 250 U 250 U 250 U273 B 3080 55200 39000 2230001000 U 1510 14200 38200 4580030 U 30 U 26.4 B 30 U 45330 U 30 U 30 U 30 U 34.733.8 B 2050 4060 37000 1220040.7 B 2590 3790 40000 133005160 B 21000 B 25900 B 154000 776006160 B 25300 B 25900 B 167000 83800145 B 395 1290 1100 2810129 B 430 1190 1200 1710400 U 400 U 372 B 400 U 188 B400 U 400 U 185 B 14.9 B 25.6 B400 U 400 U 203 B 400 U 216 B400 U 400 U 24.1 B 400 U 33.3 B2850 B 11600 B 26700 B 48900 B 989002260 B 13000 B 21600 B 53100 10600050 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U5/1/2009 5/4/2009 5/8/2009Day 5Supply Water5/1/2009Day 145/18/2009Day 0Tioga County, PADay 1Location JPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B5/1/2009 5/4/2009 5/8/2009Day 5Supply Water5/1/2009Day 145/18/2009Day 0Tioga County, PADay 1Location J17800 B 884000 1090000 10700000 394000021300 B 1120000 1160000 11700000 4120000588 47900 56700 443000 197000 J685 J 58200 J 58600 J 477000 J 210000 J100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U1000 U 1000 U 1000 U 1000 U 1000 U1000 U 1000 U 1000 U 1000 U 1000 U500 U 500 U 23.5 B 50.3 B J 63.6 B500 U 500 U 500 U 62.5 B J 500 U50 U 50 U 209 50 U 50 U73.9 B J 76.8 B J 665 J 91 B J 133052.8 B 45.5 B 378 97.5 B J 178 B0.01 U 0.05 G U 0.086 0.5 G U 0.520.01 U 0.05 G U 0.15 0.5 G U 0.5 U0.2 U 0.056 B 0.2 U 0.043 B J 0.2 U0.2 U 0.051 B 0.2 U 0.2 U 0.2 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 2.6 J 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U1000 U 1000 U 1000 U 1000 U 2000 UNA NA NA NA NA5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U10 U 10 U 10 U 10 U 20 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U20 U 10 J B 10 J B 22 B 330100 U 100 U 100 U 100 U 200 U100 U 100 U 100 U 100 U 200 U5 U 5 U 5 U 0.99 J 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 7.8 5.8 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 3.7 J 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C5/1/2009 5/4/2009 5/8/2009Day 5Supply Water5/1/2009Day 145/18/2009Day 0Tioga County, PADay 1Location JNA NA NA NA NA5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 UNA NA NA NA NA5 U 1.3 J 5 U 5 U 2.5 J5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U15 U 2.6 J 15 U 15 U 30 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 UNA NA NA NA NA9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 25 9.4 U 9.5 U49 U 1000 U 48 U 47 U 48 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 0.82 J 1.9 U 29.8 U 200 U 7.3 J 9.4 U 0.19 J9.8 U 200 U 9.6 U 9.4 U 9.5 U49 U 1000 U 48 U 47 U 48 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 4.5 J 9.4 U 0.61 J49 U 1000 U 48 U 47 U 48 U49 U 1000 U 48 U 47 U 48 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U49 U 1000 U 48 U 47 U 48 U49 U 1000 U 48 U 47 U 48 U98 U 2000 U 96 U 94 U 95 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 0.67 J2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 13 1.1 J 1 J9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U200 U 4000 U 190 U 190 U 190 U2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 4300 18 17 1.9 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 1.2 J 1.6 J B 9.69.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 1.6 J 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 0.3 J 5.3 J 130PARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 80825/1/2009 5/4/2009 5/8/2009Day 5Supply Water5/1/2009Day 145/18/2009Day 0Tioga County, PADay 1Location J9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 2.79.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 0.78 J2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 2.79.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U20 U 400 U 19 U 19 U 19 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1 J2 U 40 U 1.9 U 0.76 J 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 3.2 J 9.4 U 3.5 J9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 UNANANANANA0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.0830.048 U 0.038 J PGNA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.48 U 0.49 U NA NA 0.48 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.044 J PG0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.270.048 U 0.049 U NA NA 0.36 PG0.048 U 0.049 U NA NA 0.052 PG0.096 U 0.098 U NA NA 0.095 U1.9 U 2 U NANA1.9 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NANA0.38 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 105/1/2009 5/4/2009 5/8/2009Day 5Supply Water5/1/2009Day 145/18/2009Day 0Tioga County, PADay 1Location J0.95 U 1 U NA NA 0.95 U10 UJ NA 10 UJ 13 J 10 UJ10 UJ NA 10 UJ 10 UJ 10 UJ10 UJ NA 10 UJ 10 UJ 10 UJ10 UJ NA 10 UJ 10 UJ 10 UJ10 UJ NA10 UJ 10 UJ 10 UJ100 UJ NA 100 UJ 100 UJ 100 UJ100 UJ NA100 UJ 100 UJ 100 UJ0.15 U NA 0.15 U 10 UJ 1.5 UJ0.16 U NA 0.16 U 10 UJ 1.6 UJ0.17 U NA 0.17 U 10 UJ 1.7 JUNANANANA110PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B66.7 5 U 5 U 5 U0.01 NR U 0.01 NR U 0.01 U 0.01 U14 16.8 J 29.4 J 3.7430 650 214 30.518.9 117 185 15.81260 855 1720 22882 10200 34000 J 1670 J301 J 197 158 5.20.05 U 0.38 1.2 G U 0.05 U104 2100 5100 6301.6 2.4 1.2 G U 0.650.37 0.32 0.2 0.680.056 1.1 4.8 1.74.9 U 4.8 U 4.9 U 9.4507 J 35700 J 79500 J 6800 J21.5 J 21.6 J 6.6 B J 0.78 B J949 J 124 103 7.2116 J 311 J 245 J 91.3 J804 18600 39400 301047.2 25.2 38 5.60.097 B 0.14 0.12 0.1726 172 61 561249 63.8 140 548320 16.7 7.4 B J 10 U1.6 B 1.6 B 1.6 B 3 U6.3 7.4 6.9 6.60.011 0.01 U 0.052 0.0097 B10.4 8.8 5 U 140.05 U 0.575 0.012 0.0733311 B 420 B J 2000 U 39902000 U 166 B 205 B 2000 U16.7 B 34.9 B 33.7 B 14.1 B100 U 36.5 B 21.7 B 100 U100 U 32.3 B 28.8 B 79.8 B100 U 100 U 32.6 B 100 U1220 B 251000 893000 1050001360 B J 224000 1010000 10200040 U 40 U 40 U 40 U40 U 40 U 40 U 40 U71.4 B J 2850 3550 464 B76.4 B J 2590 4170 313 B50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U26600 B J 577000 J 1440000 J 173000 J22900 B J 493000 1590000 204000 J50 U 48.1 B 14.6 B 56750 U 50 U 6.6 B 50 U500 U 500 U 500 U 10.9 B500 U 500 U 500 U 500 U250 U 250 U 250 U 493250 U 250 U 250 U 250 U745 B 18000 33600 166000567 B 11700 34400 2680030 U 70.9 30 U 13821.2 B 35.7 30 U 30 U42 B 23600 41800 341056.3 B 20200 47800 40004320 B 52000 135000 18500 B3760 B 44800 B 150000 21900 B33.2 B 519 881 217027.5 B 440 1020 1230400 U 54.4 B 33.1 B 149 B400 U 42.7 B 34 B 400 U400 U 176 B 400 U 769400 U 33.4 B 400 U 62.1 B2750 B 35800 B 54600 8230 B2790 B 31900 B 64000 8140 B50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U50 U 50 U 50 U 50 UBradford County, PA05/07/2009 5/20/2009Day 1Day 0 Day 55/22/2009Day 146/2/2009Location KPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BBradford County, PA05/07/2009 5/20/2009Day 1Day 0 Day 55/22/2009Day 146/2/2009Location K67800 6630000 11700000 92200080700 5830000 J 13200000 J 11000001310 117000 357000 39000899 J E 99700 J 390000 J 46100 J100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U1000 U 1000 U 1000 U 23 B1000 U 1000 U 1000 U 1000 U22.3 B J 38.5 B 23.9 B 119 B21.2 B J 39.4 B 39.2 B 500 U50 U 50 U 50 U 50 U99.7 B J 198 B J 147 B J 517 J76.1 B J 109 B J 172 B J 75.7 B0.5 G U 0.1 G U 0.17 B 0.05 G U0.5 G U 0.1 G U 0.17 B 0.047 B0.052 B J 0.2 U 0.2 U 0.2 U0.46 B J 0.2 U 0.2 U 0.2 U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U42 14 7.7 3.9 J5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U20 7.7 5.3 2.8 J5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U1000 U 1000 U 1000 U 1000 UNA NA NA NA5U 5U 5U 5U5U 5U 5U 5U10 U 10 U 10 U 10 U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U6.7 J B 5.9 J 6.9 J 20 U100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U5 U 5 U 5 U 1.5 J5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U1.7 J 5 U 5 U 5 U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U3.9 J 5 U 5 U 5 U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5 U 5 U 5 U 2.3 JPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CBradford County, PA05/07/2009 5/20/2009Day 1Day 0 Day 55/22/2009Day 146/2/2009Location KNA NA NA NA5U 5U 5U 5U5U 5U 5U 5UNA NA NA NA5 U 5 U 5 U 1.6 J5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U35 4.8 J 3 J 3.7 J9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 UNA NA NA NA9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U50 U 48 U 47 U 50 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U50 U 48 U 47 U 50 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 0.41 J50 U 48 U 47 U 50 U50 U 48 U 47 U 50 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U50 U 48 U 47 U 50 U50 U 48 U 47 U 50 U99 U 95 U 94 U 100 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U200 U 190 U 190 U 200 U1.1 J 1.9 U 1.9 U 2 U6.9 1.9 U 1.9 U 2 U11 1.9 U 1.9 U 2 U7.4 1.9 U 1.9 U 2 U6.7 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 9.1 J9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U15 B 1.8 J 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U1.7 J 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U12 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 0.73 J9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 5 J 9.4 U 10 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Bradford County, PA05/07/2009 5/20/2009Day 1Day 0 Day 55/22/2009Day 146/2/2009Location K9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U10 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U20 U 19 U 19 U 20 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 1509.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 UNANANANA0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.49 U NA NA 0.48 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.036 J PG0.049 U NA NA 0.10.049 U NA NA 0.048 U0.098 U NA NA 0.097 U2U NANA1.9 U0.39 U NA NA 0.39 U0.39 U NA NA 0.39 U0.39 U NA NA 0.39 U0.39 U NA NA 0.39 U0.39 U NA NA 0.39 U0.39 U NA NA 0.39 U0.39 U NANA0.39 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Bradford County, PA05/07/2009 5/20/2009Day 1Day 0 Day 55/22/2009Day 146/2/2009Location K0.95 U NA NA 0.95 U10 UJ 10 UJ 10 UJ 10 UJ10 UJ 10 UJ 10 UJ 10 UJ10 UJ 10 UJ 10 UJ 10 UJ10 UJ 10 UJ 10 UJ 10 UJ10 UJ 10 UJ 10 UJ 10 UJ100 UJ 100 UJ 100 UJ 100 UJ220 J 130 J 100 UJ 100 UJ50 UJ 42 J 39 J 10 UJ50 UJ 20 UJ 10 UJ 10 UJ50 UJ 20 UJ 10 UJ 10 UJ2300 170 400 110PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5.5 5 U 5 U 5 U 2520.27 0.87 0.14 0.032 0.01 U3.9 2.9 31.6 71.2 114 J2 U 2 U 27.6 37.1 42630.6 9.2 162 413 704594 511 1010 4250 12000101 115 9580 35100 J 49000222 J 361 J 313 117 57.20.05 U 0.05 U 0.5 G U 1.2 G U 2.5 G U124 114 2200 12600 270000.59 0.91 1.7 1.2 G U 2.5 G U0.61 1 0.74 0.54 0.330.3 0.34 0.5 G U 1.2 G U 13.44.6 U 20 U 5.2 U 8.4 U 103519 J 599 J 33800 J 118000 J 181000 J48.3 J 40 J 58.9 J 51.4 J 28.8 B202 J 155 J 115 80.5 83.233.6 J 62 J 186 J 109 J 99.8 J390 221 20400 72700 10900017.9 24 46.4 67.6 1100.088 B 0.063 B 0.1 U 1 G U 0.039 B14 B 4 U 71 23.2 8659.1 2.7 16.2 20.9 1090625 954 177 46.1 2.7 B3 U 3 U 3 U 2.4 B 3.26.8 7.8 7.8 6.7 6.10.011 0.01 0.022 0.026 0.0410.8 NA 9.60 12.4 7.200.317 NA0.301 0.234 0.1262000 U 2000 U 290 B J 350 B J 728 B2000 U 2000 U 223 B J 310 B J 418 B100 U 100 U 17.9 B 100 U 100 U100 U 21.1 B 19.8 B 100 U 100 U100 U 100 U 100 U 40.7 B 110100 U 100 U 100 U 100 U 43.5 B243 B 108 B 7110 34700 82300222 B J 91.2 B J 6520 J 60700 J 7560040 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U47.9 B J 43.3 B J 7290 J 14100 J 1780054.1 B J 54.5 B J 6690 14400 1830050 U 50 U 50 U 50 U 4.4 B J50 U 50 U 50 U 50 U 1.8 B32000 B J 31500 B J 833000 3890000 7300000 J33900 B J 33800 B J 757000 3970000 7570000 J50 U 50 U 10.4 B 10.5 B 16750 U 50 U 50 U 50 U 50 U500 U 500 U 4.5 B 500 U 27.8 B500 U 500 U 500 U 500 U 15.6 B250 U 250 U 57.2 B 250 U 212 B250 U 250 U 47.2 B 250 U 250 U1810 137 B 5570 21500 574000968 B 1000 U 4950 20200 13500030 U 30 U 26.1 B 51.1 17130 U 30 U 30 U 30 U 60 U500 U 500 U 17400 49700 78500500 U 500 U 15900 52100 787006530 B 6740 B 89000 424000 7920007090 B 7170 B 81300 440000 81300029.3 B 7.5 B 682 2110 1860027.8 B 150 U 608 2160 16700400 U 400 U 151 B 47.2 B 69.4 B400 U 400 U 135 B 48.6 B 400 U400 U 400 U 41.7 B 400 U 82.6 B400 U 400 U 32.7 B 400 U 35.8 B2360 B 2250 B 126000 308000 4960003250 B 4220 B 118000 322000 50800050 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 UDay 5Day 1Supply WaterButler County, PA5/27/20095/12/2009 5/14/2009 5/18/2009Day 0 Day 14Location LPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 5Day 1Supply WaterButler County, PA5/27/20095/12/2009 5/14/2009 5/18/2009Day 0 Day 14Location L46900 B 64800 6290000 17900000 2660000049400 B 72000 5630000 18600000 26400000634 206 B 169000 J 738000 J 1620000580 J 158 B J 151000 J 763000 J 1650000 J100 U 100 U 100 U 100 U 200 U100 U 100 U 100 U 26.9 B 200 U1000 U 1000 U 1000 U 1000 U 1000 U1000 U 1000 U 1000 U 1000 U 1000 U500 U 19.4 B J 500 U 53.7 B 175 B26.9 B J 500 U 500 U 42.8 B 105 B50 U 50 U 50 U 50 U 50 U35.8 B J 34.8 B J 95.6 B 172 B 330 J75.9 B J 138 B J 79.5 B 147 B 74.5 B0.25 G U 0.25 G U 0.01 U 0.25 U 0.1 U0.25 G U 0.25 U 0.01 U 0.25 U 0.1 U0.054 B J 0.05 B J 0.2 U 0.2 U 0.2 U0.53 B J 0.57 B J 0.2 U 0.2 U 0.2 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U27 5 U 0.81 J 38 7705 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U14 5 U 0.78 J 32 6705 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U1000 U 1000 U 1000 U 2000 U 10000 UNA NA NA NA NA5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U10 U 10 U 10 U 20 U 100 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U9.8 J 20 U 6 J 17 J 200 U100 U 100 U 100 U 200 U 1000 U100 U 100 U 100 U 200 U 1000 U5 U 5 U 39 99 2605 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U50 9.3 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U1.3 J 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U0.65 J 5 U 1.3 J 17 2205 U 5 U 5 U 10 U 865 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U4.6 J 3.8 J 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 5Day 1Supply WaterButler County, PA5/27/20095/12/2009 5/14/2009 5/18/2009Day 0 Day 14Location LNA NA NA NA NA5 U 5 U 5 U 10 U 50 U2.2 J 5 U 5 U 10 U 50 UNA NA NA NA NA5 U 5 U 46 260 15005 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U5 U 5 U 5 U 10 U 50 U2 J 15 U 15 220 270012 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 0.81 J 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 UNA NA NA NA NA12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 1.5 J 9.4 U 9.4 U58 U 48 U 48 U 47 U 47 U12 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 9.7 U 2.7 J 4 J 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U58 U 48 U 48 U 47 U 47 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 3 J 5.2 J 9.4 U58 U 48 U 48 U 47 U 47 U58 U 48 U 48 U 47 U 47 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U58 U 48 U 48 U 47 U 47 U58 U 48 U 48 U 47 U 47 U120 U 97 U 96 U 94 U 94 U12 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 1.2 J 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U230 U 190 U 190 U 190 U 190 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 16 9.6 U 7.1 J 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U6.7 1.9 U 1.9 U 1.9 U 1.9 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 9.7 U 9.6 U 9.4 U 6.4 J12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 3 J 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U6.3 J 5.5 J 9.6 U 9.4 U 9.4 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 5Day 1Supply WaterButler County, PA5/27/20095/12/2009 5/14/2009 5/18/2009Day 0 Day 14Location L12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U23 U 19 U 19 U 19 U 19 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 0.62 J2.3 U 1.9 U 5.5 10 1.9 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U2.3 U 1.9 U 1.9 U 1.9 U 1.9 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 U12 U 9.7 U 9.6 U 9.4 U 9.4 UNANANANANA0.047 U 0.048 U NA NA 0.048 U0.047 U 0.048 U NA NA 0.048 U0.047 U 0.048 U NA NA 0.048 U0.047 U 0.048 U NA NA 0.048 U0.047 U 0.048 U NA NA 0.037 J PG0.047 U 0.048 U NA NA 0.069 PG0.47 U 0.48 U NA NA 0.48 U0.047 U 0.048 U NA NA 0.048 U0.047 U 0.048 U NA NA 0.048 U0.047 U 0.048 U NA NA 0.048 U0.047 U 0.048 U NA NA 0.048 U0.047 U 0.048 U NA NA 0.048 U0.047 U 0.048 U NA NA 0.046 J PG0.047 U 0.048 U NA NA 0.048 U0.047 U 0.048 U NA NA 0.048 U0.047 U 0.048 U NA NA 0.380.047 U 0.048 U NA NA 0.048 U0.047 U 0.048 U NA NA 0.048 U0.094 U 0.096 U NA NA 0.095 U1.9 U 1.9 U NANA1.9 U0.38 U 0.38 U NA NA 0.38 U0.38 U 0.38 U NA NA 0.38 U0.38 U 0.38 U NA NA 0.38 U0.38 U 0.38 U NA NA 0.38 U0.38 U 0.38 U NA NA 0.38 U0.38 U 0.38 U NA NA 0.38 U0.38 U 0.38 U NANA0.38 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 5Day 1Supply WaterButler County, PA5/27/20095/12/2009 5/14/2009 5/18/2009Day 0 Day 14Location L0.99 U 0.98 U NA NA 0.95 U10 UJ NA 10 UJ 10 UJ 10 UJ10 UJ NA 10 UJ 10 UJ 13 J10 UJ NA 10 UJ 10 UJ 10 UJ10 UJ NA 10 UJ 10 UJ 10 UJ10 UJ NA10 UJ 10 UJ 10 UJ100 UJ NA 100 UJ 100 UJ 100 UJ100 UJ NA100 UJ 100 UJ 100 UJ1.5 UJ NA 7.5 UJ 7.5 UJ 7.5 UJ1.6 UJ NA 8 UJ 8 UJ 8 UJ1.7 UJ NA 8.5 UJ 8.5 UJ 8.5 UJNANANANA290PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 11.4 NA NA 2000.01 U 0.0097 B 0.01 U 0.01 U 0.01 U0.25 J 1.5 J 173 192 268 J2 U 137 36.3 103 10.22 G U 10 G U NA NA 119010 U 490 10700 7600 91804.1 B 29.9 B NA NA 1510001.4 84.3 77 33.1 50.05 U 0.009 B 2.5 G U 2.5 G U 2.5 G U18 26 NA NA 950000.24 B 2.5 U 2.5 G U 2.5 G U 2.5 G U0.24 0.24 0.01 B 0.049 B J 0.110.21 B 2.5 G U NA 25.9 55.84.6 U 33.2 NA NA 7.454.8 J 177 J NA NA 710000 J3.8 B 2.9 B 50 G U 50 G U 50 G U1.8 86.6 2.2 3.7 1.26.2 J 9.6 J NA NA 26.1 J51 371 NA NA 2280002.2 B 31.3 158 178 1990.1 U 0.096 B 1.4 0.1 U 2.24 U 110 NA NA 40.84.3 254 NA NA 67.810 U 12.5 10 U 10 U 10 U1.6 B 3 U 3 U 3 U 3 U7.1 6.2 5.9 7.2 5.80.01 U 0.0069 B 0.007 B 0.29 0.006 B6 12 24.4 11.6 10.40.05 U 0.05 0.241 0.291 0.198122 B J 180 B J 165 B 131 B 158 B160 B 239 B 289 B J 188 B J 210 B J14.6 B 100 U 13.9 B 17.3 B 100 U100 U 100 U 16.9 B 20.9 B 15.7 B100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U271 B 579 B 1450000 1730000 1970000274 B 621 B 1430000 1760000 199000040 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U2000 U 2000 U 12000 10500 100002000 U 2000 U 11800 11000 974050 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 1.5 B 1.5 B4880 B J 6690 B J 19700000 J 23500000 J 26400000 J3690 B 6080 B 19700000 J 23800000 J 26200000 J50 U 50 U 15.7 B 50 U 50 U50 U 50 U 50 U 50 U 50 U500 U 500 U 5000 U 5000 U 5000 U500 U 500 U 5000 U 5000 U 5000 U250 U 44.5 B 255 78.9 B 250 U250 U 250 U 81.1 B 57.7 B 250 U605 B 497 B 67200 53100 61000543 B 460 B 37600 44800 5330030 U 30 U 30 U 30 U 30 U30 U 30 U 30 U 30 U 30 U500 U 500 U 129000 137000 155000500 U 28.1 B 126000 J 154000 J 158000 J1080 B 1250 B 1320000 1550000 18000001440 B 1460 B 1310000 1600000 1740000134 B 127 B 5960 7040 8560127 B 130 B 5850 7170 8420400 U 400 U 48.2 B 400 U 400 U400 U 400 U 34.7 B J 400 U 400 U400 U 19.5 B 400 U 400 U 400 U400 U 400 U 400 U 400 U 400 U50000 U 50000 U 923000 849000 972000 E50000 U 50000 U 1000000 1010000 1010000 E50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 UMcKean County, PADay 56/10/20095/19/2009 6/19/20096/6/2009Supply Water5/19/2009Day 14Day 1Day 0Location MPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BMcKean County, PADay 56/10/20095/19/2009 6/19/20096/6/2009Supply Water5/19/2009Day 14Day 1Day 0Location M4200 B 32600 B 20600000 17200000 232000003600 B J 34200 B J 31500000 31300000 30400000352 B 768 4330000 4830000 5570000 E340 B J 816 J 4280000 J 4920000 J 5350000 J E100 U 100 U 27.2 B 100 U 100 U100 U 100 U 100 U 100 U 100 U1000 U 1000 U 1000 U 1000 U 1000 U1000 U 1000 U 1000 U 1000 U 1000 U500 U 500 U 500 U 500 U 500 U500 U 29.8 B 500 U 500 U 500 U50 U 50 U 50 U 50 U 50 U56.7 B J 50.2 B J 391 J 270 J 223 J41.1 B J 40.6 B J 314 J 240 J 143 B J0.01 U 0.01 G U 0.5 G U 0.5 G U 1 G U0.01 U 0.05 G U 0.5 G U 0.5 G U 1 G U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 5 U 1.6 J 4 J 0.98 J5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 5 U 1.2 J 3.3 J 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U1000 U 1000 U 1000 U 1000 U 1000 UNA NA NA NA NA5U 5U 5U 5U 5U5 U 3.6 J 5 U 5 U 5 U10 U 10 U 10 U 10 U 10 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U20 U 20 U 21 18 J 18 J100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U5 U 5 U 3.5 J 3.2 J 6.25U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 5 U 5 U 0.63 J 5 U5 U 5 U 5 U 0.53 J 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CMcKean County, PADay 56/10/20095/19/2009 6/19/20096/6/2009Supply Water5/19/2009Day 14Day 1Day 0Location MNA NA NA NA NA5U 5U 5U 5U 5U5U 5U 5U 5U 5UNA NA NA NA NA5 U 5 U 3.8 J 4.8 J 3.4 J5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U15 U 15 U 3.2 J 6 J 6.2 J9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 UNA NA NA NA NA9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U48 U 50 U 48 U 47 U 48 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 0.28 J 0.26 J 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U48 U 50 U 48 U 47 U 48 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 0.69 J 9.6 U48 U 50 U 48 U 47 U 48 U48 U 50 U 48 U 47 U 48 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U48 U 50 U 48 U 47 U 48 U48 U 50 U 48 U 47 U 48 U96 U 100 U 95 U 94 U 96 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 0.8 J 9.6 U9.6 U 10 U 2.2 J 2.1 J 2 J9.6 U 10 U 9.5 U 9.4 U 9.6 U190 U 200 U 190 U 190 U 190 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U6 J 10 U 2.8 J 9.4 U 2.5 J9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 2.4 J B 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 1.3 J 9.4 U 9.6 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082McKean County, PADay 56/10/20095/19/2009 6/19/20096/6/2009Supply Water5/19/2009Day 14Day 1Day 0Location M9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U2.2 J 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U19 U 20 U 19 U 19 U 19 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U2.6 J 2 J 140 100 949.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 UNANANANANA0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.48 U 0.49 U NA NA 0.48 U0.048 U 0.049 U NA NA 0.026 J0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.05 NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.8 PG 0.84 PG NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.095 U 0.098 U NA NA 0.096 U1.9 U 2 U NANA1.9 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NANA0.38 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10McKean County, PADay 56/10/20095/19/2009 6/19/20096/6/2009Supply Water5/19/2009Day 14Day 1Day 0Location M0.95 U 0.97 U NA NA 1 U10 UJ 20 UJ 10 UJ 10 UJ 10 UJ10 UJ 20 UJ 10 UJ 10 UJ 10 UJ10 UJ 20 UJ 10 UJ 10 UJ 10 UJ10 UJ 20 UJ 23 J 21 J 16 J10 UJ 20 UJ 10 UJ 10 UJ 10 UJ100 UJ 200 UJ 100 UJ 100 UJ 100 U100 UJ 200 UJ 100 UJ 100 UJ 100 U1 U 100 UJ 10 UJ 500 UJ 10 UJ1 U 100 UJ 10 UJ 500 UJ 10 UJ1 U 100 UJ 10 UJ 500 UJ 10 UJ57 2300 1100 1200 52000PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5U 5U 5U 5U0.08 0.01 U 0.01 U 0.01 U0.3 J 83.3 J 83.6 J 1822 U 166 73.2 70.90.2 U 0.9 165 60811.6 J 734 J 1760 J 32008.3 132 17500 672002.5 218 20.2 320.05 U 0.05 U 0.5 G U 1.2 G U26 50 5100 300000.17 0.12 0.5 G U 1.2 G U0.14 0.23 0.45 0.140.05 U 0.22 4.7 13.24.6 U 4.6 U 4.8 U 5.191.6 J 1350 J 73600 J 273000 J6.9 J 165 J 110 J 7.3 B J3 J 208 J 28.1 J 37.816.2 J 154 J 254 J 145 J35 735 31800 1160003 U 142 101 1370.1 U 15.4 4.1 0.712 B 14.4 112 1712.9 8.8 50.4 32885.9 5.4 B 10 U 10 U3U 3U 3U 3U7.4 8.2 7.4 6.60.01 U 0.01 U 0.014 0.017NA 6.80 6.80 12.8NA0.0809 0.0969 0.06572000 U 2000 U 2000 U 360 B J2000 U 2000 U 2000 U 208 B J14.2 B J 21.6 B J 34.9 B J 19.4 B17.2 B J 100 U 41.5 B J 18.5 B100 U 100 U 46 B 100 U100 U 100 U 48.8 B 100 U309 B J 1420 B J 271000 J 3530000290 B 3400 272000 317000040 U 40 U 40 U 40 U40 U 40 U 40 U 40 U36.4 B J 40700 J 6680 J 836028.2 B J 44700 J 6540 J 771050 U 50 U 50 U 50 U50 U 50 U 50 U 50 U7450 B 15600 B 1400000 8520000 J6730 B 16100 B 1340000 7930000 J50 U 50 U 36.8 B 44.7 B50 U 50 U 29.4 B 27.2 B500 U 500 U 500 U 5000 U500 U 500 U 500 U 5000 U250 U 71.3 B 57.1 B 64.8 B250 U 87.2 B 36.6 B 250 U1000 U 834 B 13900 469001000 U 688 B 10900 649030 U 30 U 55.2 20.6 B30 U 30 U 48.8 30 U500 U 180 B J 26000 J 106000500 U 196 B 24600 97200 J1100 B 1740 B 112000 6780001070 B 1790 B 108000 62900026.9 B 18.3 B 725 2590150 U 17 B 683 2360400 U 400 U 36.6 B 16.6 B J400 U 400 U 34.3 B 400 U400 U 400 U 42.9 B 19.1 B400 U 400 U 35 B 400 U2660 B 48300 B 115000 33900050000 U 50700 110000 30400050 U 50 U 50 U 50 U50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U50 U 50 U 50 U 50 UDay 107/14/09 7/15/2009 7/19/2009Day 5Day 0Supply WaterPotter County, PA07/14/09Location NPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 107/14/09 7/15/2009 7/19/2009Day 5Day 0Supply WaterPotter County, PA07/14/09Location N8930 B J 74400 J 8210000 J 311000008100 B 80000 7800000 29000000204 B J 3020 J 388000 J 2980000 J187 B J 3150 J 368000 J 2690000 J100 U 100 U 100 U 100 U100 U 100 U 28.3 B 100 U1000 U 1000 U 1000 U 1000 U1000 U 1000 U 1000 U 1000 U500 U 500 U 37.8 B 500 U500 U 500 U 23.4 B 500 U50 U 50 U 29.3 B 44.7 B54.6 B J 75.5 B J 617 J 241 J27.2 B J 80.7 B J 538 J 262 J0.01 U 0.01 U 0.5 U 0.5 G U0.01 U 0.0062 B 0.37 B 0.5 G U0.2 U 0.2 U 0.2 U 0.2 U0.2 U 0.2 U 0.2 U 0.2 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 4.2 J 25 U 0.54 J5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 3.4 J 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U1000 U 5000 U 5000 U 1000 UNA NA NA NA5 U 25 U 25 U 5 U5 U 25 U 25 U 3.4 J10 U 50 U 50 U 10 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 0.65 J20 U 170 90 J 210100 U 500 U 500 U 100 U100 U 500 U 500 U 100 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 5.5 J 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 107/14/09 7/15/2009 7/19/2009Day 5Day 0Supply WaterPotter County, PA07/14/09Location NNA NA NA NA5 U 25 U 25 U 5 U5 U 25 U 25 U 5 UNA NA NA NA5 U 25 U 25 U 0.91 J5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U5 U 25 U 25 U 5 U15 U 25 J 75 U 4.7 J9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 UNA NA NA NA9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 0.39 J 9.4 U 9.4 U48 U 48 U 47 U 47 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 2.5 0.41 J9.5 U 9.5 U 0.2 J 9.4 U9.5 U 9.5 U 9.4 U 9.4 U48 U 48 U 47 U 47 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 0.33 J 9.4 U48 U 48 U 47 U 47 U48 U 48 U 47 U 47 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U48 U 48 U 47 U 47 U48 U 48 U 47 U 47 U95 U 95 U 94 U 94 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 0.29 J 1.9 U1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 0.82 J 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U190 U 190 U 190 U 190 U1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U9.7 9.1 J 6.5 J 5.8 J9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 1.2 J 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 0.29 J 0.54 J 0.61 JPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 107/14/09 7/15/2009 7/19/2009Day 5Day 0Supply WaterPotter County, PA07/14/09Location N9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 0.45 J 0.097 J1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U19 U 19 U 19 U 19 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 0.89 J 1.9 U1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U1.9 U 1.9 U 0.18 J 1.9 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 UNANANANA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.48 U 0.48 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.048 U 0.048 U NA NA0.095 U 0.095 U NA NA1.9 U 1.9 U NANA0.38 U 0.38 U NA NA0.38 U 0.38 U NA NA0.38 U 0.38 U NA NA0.38 U 0.38 U NA NA0.38 U 0.38 U NA NA0.38 U 0.38 U NA NA0.38 U 0.38 U NANAPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 107/14/09 7/15/2009 7/19/2009Day 5Day 0Supply WaterPotter County, PA07/14/09Location N0.95 U 0.95 U NA NANA 10 UJ 10 UJ 10 UJNA 10 UJ 10 UJ 10 UJNA 10 UJ 10 UJ 10 UJNA 10 UJ 10 UJ 10 UJNA10 UJ 10 UJ 10 UJNA 500 UJ 100 UJ 100 UJNA500 UJ 100 UJ 100 UJNA 15 22 J 23NA 1 U 2 UJ 1 UNA 1 U 2 UJ 1 UNA20 200 350PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 48.7 4730.01 U 0.01 NR U 0.01 U 0.01 U10 52 135 237 J924 606 1520 72520 G U 69.8 885 J 8722420 1480 7390 10000 J1060 7860 86800 98300 J558 J 271 240 6955 G U 2.5 G U 2.5 G U 2.5 G U570 25000 36000 540005 G U 2.5 G U 2.5 G U 2.5 G U0.1 0.18 0.1 U 0.1 U5 G U 6.7 19.9 J 25.9255 4.6 U 40.7 17.54000 J 30700 J 261000 J 428000 J100 G U 50 G U 50 G U 50 G U575 J 308 237 509 J66.1 J 114 J 94.2 J 95.1 J2670 17400 125000 18600089.9 88.8 147 1800.5 21.8 2.3 0.038 B5290 4 U 302 324505 152 54.6 24410 U 21.5 5.2 B 1.9 B3 U 3 U 3.2 3 U7.2 6.5 6.5 6.60.77 J 0.036 J 0.15 J 0.1347.2 26.8 16.8 73.60.05 U 0.198 0.0897 4.601030 B 1120 B 536 B 845 B162 B J 274 B 172 B J 912 B100 U 15.8 B 100 U 48.8 B J100 U 15 B 100 U 45 B J100 U 48 B 100 U 76.6 B100 U 28 B 100 U 86.5 B72200 387000 13900000 12500000 J62300 447000 12700000 1360000040 U 40 U 40 U 40 U40 U 40 U 40 U 40 U1190 B 808 B 3570 2520 J1310 B 944 B 3200 2760 J50 U 50 U 50 U 3.1 B50 U 50 U 50 U 3.3 B123000 J 676000 J 9250000 J 10300000120000 J 800000 J 8200000 J 1120000017.3 B 37.5 B 33.4 B 31.2 B50 U 12.9 B 27.7 B 19.4 B500 U 500 U 25000 U 5000 U500 U 500 U 25000 U 5000 U79.4 B 250 U 250 U 54.8 B34.1 B 250 U 250 U 250 U7400 20900 J 43500 77500954 B 18000 38400 5870019.4 B 30 U 30 U 60 U30 U 30 U 30 U 60 U1800 14200 132000 147000 J1930 17300 125000 16200014700 B 65700 691000 79400014800 B 76400 610000 858000288 760 J 5550 7100196 823 4960 763050.6 B J 25.9 B 400 U 400 U58.4 B 24.1 B 400 U 400 U400 U 48.3 B 400 U 800 U400 U 39.5 B 400 U 800 U7840 B 33500 B 353000 2330006850 B 39900 B 284000 25300050 U 50 U 50 U 34 B50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U50 U 50 U 50 U 50 UDay 07/1/2009 7/1/2009Day 1Susquehanna CountyDay 5 Day 147/6/2009 07/15/2009Location OPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 07/1/2009 7/1/2009Day 1Susquehanna CountyDay 5 Day 147/6/2009 07/15/2009Location O589000 3920000 34100000 36800000 J658000 4670000 30900000 3910000027000 J E 196000 J 2960000 J 3520000 J28200 J E 233000 J 2660000 J 3580000 J100 U 100 U 100 U 200 U29.5 B 100 U 38 B 200 U1000 U 1000 U 1000 U 1000 U1000 U 1000 U 1000 U 1000 U500 U 33.8 B 500 U 126 B500 U 48.6 B 500 U 152 B50 U 50 U 33.4 B 50 U1610 E 244 211 229 J924 287 J 183 B 127 B J0.1 U 0.1 U 2 G U 13.20.05 U 0.1 U 2 G U 2 U0.2 U 0.2 U 0.2 U 0.2 U0.17 B 0.2 U 0.2 U 0.2 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U67 59 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U7.7 J 6.7 J 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U10000 U 5000 U 1000 U 1000 UNA NA NA NA50 U 25 U 5 U 5 U50 U 17 J 5 U 5 U100 U 50 U 10 U 10 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U130 J 69 J 20 U 20 U1000 U 500 U 100 U 100 U1000 U 500 U 100 U 100 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U820 720 0.5 J 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 07/1/2009 7/1/2009Day 1Susquehanna CountyDay 5 Day 147/6/2009 07/15/2009Location ONA NA NA NA50 U 25 U 5 U 5 U50 U 25 U 5 U 5 UNA NA NA NA19 J 25 U 0.94 J 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U46 J 26 J 15 U 15 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 UNA NA NA NA190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U940 U 470 U 49 U 4700 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U260 52 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U940 U 470 U 49 U 4700 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U940 U 470 U 49 U 4700 U940 U 470 U 49 U 4700 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U940 U 470 U 49 U 4700 U940 U 470 U 49 U 4700 U1900 U 940 U 98 U 9400 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U3800 U 1900 U 200 U 19000 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U190 U 94 U 2.5 J 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 07/1/2009 7/1/2009Day 1Susquehanna CountyDay 5 Day 147/6/2009 07/15/2009Location O190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U380 U 190 U 20 U 1900 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U38 U 3.5 J 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 1.1 J 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 UNANANANA0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.11 PG NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.51 U NA NA 0.48 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.065 PG NA NA 0.048 U0.051 U NA NA 0.048 U0.1 U NA NA 0.095 U2U NANA1.9 U0.41 U NA NA 0.38 U0.41 U NA NA 0.38 U0.41 U NA NA 0.38 U0.41 U NA NA 0.38 U0.41 U NA NA 0.38 U0.41 U NA NA 0.38 U0.41 U NANA0.38 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 07/1/2009 7/1/2009Day 1Susquehanna CountyDay 5 Day 147/6/2009 07/15/2009Location O1 U NA NA 4.8 U20 UJ 10 UJ 10 UJ 10 UJ20 UJ 10 UJ 10 UJ 10 UJ120 J 230 J 110 J 39 J20 UJ 10 UJ 10 UJ 10 UJ20 UJ 10 UJ 10 UJ 10 UJ200 UJ 200 UJ 100 UJ 100 UJ200 UJ 200 UJ 100 UJ 100 UJ50 UJ 1 U 1 U 20 UJ50 UJ 1 U 1 U 20 UJ50 UJ 1 U 1 U 20 UJ200 200 300 800PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 28.8 5 U 2530.01 U 0.01 U 0.01 U 0.01 U 0.01 U0.28 J 17.4 J 107 J 78 J 134 J4.2 391 1260 752 5250.2 U 60 477 487 67835.3 J 1180 J 4820 3170 4440152 J 6450 43900 45600 66300 J5 302 240 237 1210.27 1.3 1.2 G U 1.2 G U 5 U194 2200 24000 21000 530000.52 0.75 1.2 G U 1.2 G U 5 G U0.47 0.56 0.46 0.83 0.031 B0.11 2.9 11.8 9.4 5 G U5 U 4.9 U 57.7 5 U 4.6 U726 J 24600 J 160000 J 175000 J 23100073.7 J 65.6 J 53.1 J 48.7 64 B J5.6 J 292 J 287 226 29738.6 J 255 J 93.2 J 121 J 80.5 J401 11600 78600 63900 1170002.3 B 61.6 92.9 42.2 1210.1 U 0.17 0.11 0.14 0.2 G U10 18 10.8 79.2 1123.4 15.7 486 708 41610 U 9.8 B 10 U 10 U 10 U3U 3U 3U 3U 3U7.3 7.6 6.3 6.6 6.20.01 U 0.027 0.037 0.02 0.0410 8.40 2.5 U 7.20 NA0.05 U 0.178 0.0777 0.125 NA2000 U 2000 U 378 B J 529 B J 225 B J2000 U 227 B 435 B J 301 B J 208 B J100 U 25.3 B J 100 U 14.9 B 100 U100 U 19.3 B J 15.2 B 100 U 100 U100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U173 B J 2590 J 28900 43900 56000187 B 2690 41000 72000 6320040 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U80.8 B J 6510 J 21000 20600 2440090.2 B J 7200 J 22900 21100 27800 J50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 1.6 B 50 U63200 616000 6160000 J 5700000 J 837000069900 655000 6450000 J 5780000 J 939000050 U 33.2 B 44.2 B 98.3 52.250 U 26.4 B 45 B 75.5 48.1 B500 U 500 U 500 U 500 U 500 U500 U 5.3 B 500 U 500 U 500 U250 U 250 U 250 U 250 U 104 B32.1 B 250 U 250 U 250 U 81.9 B1000 U 5240 28800 67300 1400001000 U 5120 30300 21600 11100030 U 30 U 30 U 30 U 10530 U 30 U 30 U 30 U 30 U500 U 7900 J 40200 56500 62900500 U 8300 43000 J 57400 J 71000 J9410 B 65500 658000 613000 90800010400 B 70100 715000 632000 103000023.7 B 369 1300 2240 315015.4 B 397 1390 2240 3540400 U 72.4 B 44.4 B J 87.8 B J 400 U400 U 75.4 B 47 B 93.2 B 400 U21.1 B 28.6 B 400 U 25.2 B 30.9 B16.6 B 30.8 B 400 U 400 U 27.4 B4590 B 99500 656000 E 614000 821000 E4010 B 105000 723000 E 628000 952000 E50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 UDay 1 Day 5 Day 147/15/2009 7/20/2009Day 907/14/200910/29/2009Day 0Butler County, PA7/29/2009Location PPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 1 Day 5 Day 147/15/2009 7/20/2009Day 907/14/200910/29/2009Day 0Butler County, PA7/29/2009Location P56700 J 3040000 J 18000000 21100000 2510000062000 3230000 18700000 21000000 28200000 J417 B J 93100 J 1240000 J E 1210000 J 1790000 J E464 B J 98300 J 1320000 J E 1240000 J 2020000 J E100 U 100 U 100 U 33.9 B 100 U100 U 100 U 23.6 B 41 B 100 U1000 U 1000 U 1000 U 1000 U 1000 U1000 U 1000 U 1000 U 21.4 B 1000 U500 U 500 U 500 U 500 U 500 U500 U 500 U 500 U 500 U 500 U50 U 26.4 B 44.2 B 98.3 48.1 B72.3 B J 184 B J 150 B J 90.3 B J 424 J45.3 B J 154 B J 245 J 105 B J 236 J0.01 U 0.01 U 0.25 G U 0.1 G U 0.25 G U0.01 U 0.0068 B 0.25 G U 0.1 G U 0.25 G U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U0.79 J 1.4 J 840 710 845 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 940 770 795 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U1000 U 2000 U 100000 U 100000 U 5000 UNA NA NA NA NA5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U10 U 20 U 1000 U 1000 U 50 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U12 J 320 5200 2000 U 190100 U 200 U 10000 U 10000 U 500 U100 U 200 U 10000 U 10000 U 500 U5 U 140 2000 1100 2005 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U2.2 J 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 230 J 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U2.4 J 10 U 500 U 500 U 25 U5 U 5.9 J 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U2.1 J 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 2.5 J 650 470 J 465 U 10 U 160 J 120 J 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U0.55 J 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 90 J 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 1 Day 5 Day 147/15/2009 7/20/2009Day 907/14/200910/29/2009Day 0Butler County, PA7/29/2009Location PNA NA NA NA NA5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 UNA NA NA NA NA0.93 J 92 6200 5200 5805 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5 U 10 U 500 U 500 U 25 U5.1 J 32 6500 5400 5309.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 UNA NA NA NA NA9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 1247 U 48 U 98 U 47 U 47 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U9.4 U 9.7 U 20 U 9.4 U 159.4 U 9.7 U 20 U 9.4 U 9.4 U47 U 48 U 98 U 47 U 47 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 2.5 J 20 U 9.4 U 1647 U 48 U 98 U 47 U 47 U47 U 48 U 98 U 47 U 47 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U47 U 48 U 98 U 47 U 47 U47 U 48 U 98 U 47 U 47 U94 U 97 U 200 U 94 U 94 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U9.4 U 0.95 J 20 U 9.4 U 169.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U190 U 190 U 390 U 190 U 190 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U4.2 J 5.9 J 16 J 4.6 J 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U9.4 U 9.7 U 20 U 9.4 U 9.4 U0.49 J 0.51 J 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U0.6 J 0.46 J 0.84 J 9.4 U 9.4 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 1 Day 5 Day 147/15/2009 7/20/2009Day 907/14/200910/29/2009Day 0Butler County, PA7/29/2009Location P9.4 U 9.7 U 15 J 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U19 U 19 U 39 U 19 U 19 U9.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 1.9 U 3.9 U 1.9 U 1.9 U1.9 U 1.9 U 3.9 U 1.9 U 219.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 U1.9 U 0.28 J 3.9 U 1.9 U 1.9 U9.4 U 360 470 220 3409.4 U 9.7 U 20 U 9.4 U 9.4 U9.4 U 9.7 U 20 U 9.4 U 9.4 UNANANANANA0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.47 U NA NA 0.5 U 0.47 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.047 U NA NA 0.05 U 0.047 U0.094 U NA NA 0.1 U 0.094 U1.9 U NANA2 U 1.9 U0.38 U NA NA 0.4 U 0.38 U0.38 U NA NA 0.4 U 0.38 U0.38 U NA NA 0.4 U 0.38 U0.38 U NA NA 0.4 U 0.38 U0.38 U NA NA 0.4 U 0.38 U0.38 U NA NA 0.4 U 0.38 U0.38 U NANA0.4 U 0.38 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 1 Day 5 Day 147/15/2009 7/20/2009Day 907/14/200910/29/2009Day 0Butler County, PA7/29/2009Location P0.97 U NA NA 0.95 U 0.95 U10 UJ 10 UJ 10 UJ 10 UJ NA10 UJ 10 UJ 10 UJ 10 UJ NA10 UJ 10 UJ 10 UJ 10 UJ NA10 UJ 190 J 160 J 140 J NA10 UJ 10 UJ 10 UJ 10 UJ NA100 UJ 100 UJ 100 UJ 100 UJ NA100 UJ 100 UJ 100 UJ 100 UJ NA1 U 1 U 20 UJ 10 UJ NA1 U 1 U 20 UJ 10 UJ NA1 U 1 U 20 UJ 10 UJ NA20 80 250 150 NAPARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 5 U 63.2 6980.01 NR U 0.01 NR U 0.01 NR U 0.01 U 0.01 U1.8 16.1 65.4 102 J 215 J121 184 144 98.1 1214.5 87.9 310 720 10901770 1080 1850 14000 J 708078.1 J 8960 J 33500 71500 131000467 341 J 160 25.8 18.40.25 G U 2.5 G U 2.5 G U 2.5 G U 2.5 G U88 2200 9100 32000 900000.25 G U 2.5 G U 2.5 G U 2.5 G U 2.5 G U0.33 0.51 0.055 B J 0.025 B 0.069 B0.25 G U 6.5 13.2 19.9 84.55 U 4.8 U 4.6 U 4.8 U 6.4426 J 39800 J 130000 J 249000 J 46400045.3 J 31.8 B J 50 G U 50 G U 50 G U410 J 142 J 46.5 J 24 J 34.149 J 338 J 140 J 113 J 52.9 J311 16600 38500 120000 20700011.9 24.3 61.7 83.1 1280.034 B 0.16 0.097 B 0.055 B J 1 G U120 9.2 95 62 53420.7 11.7 68.2 10.5 26492.4 21.2 72.1 10 U 10 U4.8 3.2 2.4 B 3 U 3 U6.9 7.5 6.6 6.2 5.90.033 J 0.0087 B J 0.018 J 0.01 U 0.01 U12.0 12.4 6.4 14.8 14.80.501 0.05 U 0.133 0.836 0.8362000 U 395 B 246 B 640 B 271 B J2000 U 190 B 173 B J 737 B 181 B J100 U 24.7 B 100 U 37.2 B J 100 U100 U 25.2 B 100 U 38.5 B J 100 U100 U 100 U 100 U 46.4 B 100 U100 U 100 U 100 U 65 B 100 U227 B 37600 415000 1700000 J 3440000294 B 43800 401000 1730000 256000040 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U2000 U 5110 9070 10400 J 1360033.5 B 5840 8500 10800 J 10200 J50 U 50 U 50 U 1.4 B 2.6 B J50 U 50 U 50 U 1.9 B 50 U27800 B J 641000 J 3120000 J 8790000 1800000026800 B J 728000 J 2890000 J 8730000 1340000050 U 50 U 50 U 50 U 14.8 B50 U 50 U 50 U 50 U 50 U500 U 500 U 500 U 1000 U 5000 U500 U 500 U 500 U 1000 U 5000 U39.7 B 250 U 28.9 B 250 U 56.6 B35.6 B 250 U 250 U 250 U 250 U429 B J 5830 J 37500 72700 3210001000 U 5000 30400 72900 22000030 U 14.5 B 30 U 60 U 5030 U 14.5 B 30 U 60 U 15.7 B500 U 12300 29300 68700 J 100000500 U 14300 27000 69100 74500 J6400 B 59800 331000 938000 16900006090 B 67100 307000 963000 12900008.2 B J 752 J 2300 4790 10200150 U 826 2130 4890 7700400 U 21.1 B 20.6 B J 14.8 B 17.5 B400 U 24.1 B 400 U 400 U 400 U400 U 400 U 400 U 800 U 49.9 B400 U 400 U 400 U 800 U 36.5 B50000 U 45400 B 187000 265000 8580004110 B 53500 163000 267000 61100050 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 44.2 B 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 UDay 90Day 57/1/2009 10/27/20097/15/2009Day 147/6/2009Day 0 Day 16/30/2009Westmoreland County, PALocation QPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 90Day 57/1/2009 10/27/20097/15/2009Day 147/6/2009Day 0 Day 16/30/2009Westmoreland County, PALocation Q63200 5400000 1.7E+07 30800000 J 4970000067900 5960000 1.6E+07 31300000 36800000 J292 B J 86200 J 422000 J 1310000 J 2860000 J254 B J 98800 J 396000 J 1300000 J 2100000 J100 U 100 U 100 U 200 U 100 U100 U 100 U 100 U 200 U 100 U1000 U 1000 U 1000 U 1000 U 1000 U1000 U 1000 U 22.4 B 1000 U 1000 U500 U 44.5 B 500 U 139 B 500 U500 U 35.4 B 500 U 113 B 500 U50 U 50 U 50 U 50 U 50 U37.7 B 78.6 B 156 B 144 B J 247000 J69 B J 100 B J 159 B 137 B J 182000 J0.5 G U 0.5 G U 0.1 G U 0.25 G U 1 G U0.5 G U 0.5 G U 0.1 G U 0.25 U 1 G U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U0.095 B 0.2 U 0.2 U 0.2 U 0.2 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 4.9 J5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U1000 U 1000 U 1000 U 10000 U 1000 UNA NA NA NA NA5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U10 U 10 U 10 U 100 U 10 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U28 16 J 42 520 20 U100 U 100 U 100 U 1000 U 100 U100 U 100 U 100 U 1000 U 100 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 4 J 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 90Day 57/1/2009 10/27/20097/15/2009Day 147/6/2009Day 0 Day 16/30/2009Westmoreland County, PALocation QNA NA NA NA NA5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 UNA NA NA NA NA5 U 5 U 1.2 J 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U15 U 15 U 4.4 J 150 U 15 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 UNA NA NA NA NA9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U48 U 48 U 47 U 47 U 47 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U48 U 48 U 47 U 47 U 47 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 0.2 J 9.4 U 9.4 U48 U 48 U 47 U 47 U 47 U48 U 48 U 47 U 47 U 47 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U48 U 48 U 47 U 47 U 47 U48 U 48 U 47 U 47 U 47 U95 U 95 U 94 U 94 U 94 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 1.2 J 0.34 J 0.33 J 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U190 U 190 U 190 U 190 U 190 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 4.4 J 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U10 9.5 U 9.4 U 3.7 J 2 J9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.1 J 9.5 U 9.4 U 9.4 U 9.4 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 90Day 57/1/2009 10/27/20097/15/2009Day 147/6/2009Day 0 Day 16/30/2009Westmoreland County, PALocation Q9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U19 U 19 U 19 U 19 U 19 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 UNANANANANA0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.17 PG NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.26 NA NA 0.047 U 0.048 U0.48 U NA NA 0.47 U 0.48 U0.072 PG NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.12 NA NA 0.047 U 0.048 U0.26 PG NA NA 0.047 U 0.048 U0.095 U NA NA 0.094 U 0.096 U1.9 U NANA1.9 U 1.9 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NANA0.38 U 0.4 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 90Day 57/1/2009 10/27/20097/15/2009Day 147/6/2009Day 0 Day 16/30/2009Westmoreland County, PALocation Q0.95 U NA NA 0.95 U 0.98 U110 J 38 J 28 J 20 J 20 J20 UJJ 5 UJ 10 UJ 10 UJ 10 UJ20 UJJ 5 UJ 10 UJ 10 UJ 10 UJ20 UJ 5 UJ 10 UJ 10 UJ 10 UJ20 UJ 5 UJ 10 UJ 10 UJ 10 UJ200 UJ 100 UJ 100 UJ 100 UJ 100 UJ200 UJ 100 UJ 100 UJ 100 UJ 100 UJ20 UJ 1 U 33 33 J 33 J20 UJ 5 UJ 1 U 10 UJ 10 UJ20 UJ 1 U 1 U 10 UJ 10 UJ300 100 120 600 600PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 5 U 408 1330.01 NR U 0.01 NR U 0.01 NR U 0.01 U 0.01 U0.58 13.4 41.1 J 15 273 J271 692 1250 6.2 141010 G U 72.7 272 113 8091990 1660 3200 1760 3060018 B 7060 32100 J 12300 82200 J452 540 501 343 15602.5 G U 0.5 G U 2.5 G U 0.5 G U 5 G U34 1500 8300 4000 610002.5 G U 0.5 G U 2.5 G U 0.5 G U 5 G U0.13 0.035 B 0.053 B J 0.038 B 0.112.5 G U 3.8 11.8 3.8 5 G U134 5 U 655 96.1 469192 J 29800 J 98400 J 41500 J 28500011 B 25.3 J 34.5 B J 10 G U 34.7 B J173 604 388 J 323 132060.4 J 577 J 327 J 85.2 J 64.8 J481 15100 46900 20900 14400027.2 44.7 65.6 30.5 2770.63 1.4 0.96 0.87 0.11 B G732 36.8 1180 286 918650 10 1540 233 148046.4 22.9 18.5 7.3 B 4.4 B J3 U 3 U 5.6 3.2 3 U7.2 7.1 6.7 4.9 5.90.035 0.027 0.046 0.059 J 0.02714.0 10.8 11.6 13.2 NA0.03 U 0.0505 1.52 1.66 NA430 B 608 B 1870 B 1900 B 564 B J2000 U 655 B 2000 U 426 B J 272 B J100 U 24.8 B 39.7 B 100 U 100 U100 U 26.8 B 100 U 100 U 100 U100 U 55.1 B 43 B 100 U 100 U100 U 62.4 B 40.2 B 100 U 100 U67.5 B 36500 686000 296000 377000078.6 B 33700 603000 251000 39400003 B 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U2000 U 7850 17300 5330 169002000 U 9150 17100 5130 17900 J50 U 50 U 2.2 B 50 U 50 U50 U 50 U 50 U 50 U 5.5 B7200 B J 430000 J 2560000 J 1190000 J 110000005450 B J 494000 J 2610000 J 1130000 J 11500000704 31 B 152 65.5 25.6 B50 U 32 B 67.4 40 B 50 U11.9 B 500 U 500 U 500 U 5000 U500 U 500 U 500 U 500 U 5000 U40.5 B 250 U 4150 518 218 B250 U 250 U 274 387 107 B7500 J 16700 J 172000 J 214000 140000468 B 18200 93100 183000 5160030 U 54.7 606 25.2 B 59.81.3 B 39.9 30 U 30 U 30 U500 U 9500 37700 12500 85400500 U 11300 36100 12100 88700 J1490 B 37500 B 283000 133000 11500001090 B 43200 B 287000 126000 1230000104 B J 1280 J 4030 J 5100 7910150 U 1420 3440 4780 830091.8 B 23.6 B 147 B 23.1 B J 400 U400 U 25.2 B 104 B 400 U 400 U440 22 B 67 B 98.3 B 400 U400 U 22.6 B 19.9 B 93.3 B 400 U50000 U 25100 B 109000 46500 B 32100050000 U 31200 B 111000 39400 B 34700050 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 UDay 0 Day 1 Day 56/22/200910/28/20097/7/20096/23/2009 7/13/2009Tyler County, WVDay 14 Day 90Location RPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 0 Day 1 Day 56/22/200910/28/20097/7/20096/23/2009 7/13/2009Tyler County, WVDay 14 Day 90Location R33300 B 4280000 16900000 5970000 3860000041900 B 4970000 16800000 5680000 39900000 J58.5 B J E 43100 J 387000 J 175000 J 1960000 J73.9 B J E 50400 J 364000 J 163000 J 2070000 J100 U 100 U 100 U 100 U 100 U100 U 25.1 B 30.5 B 100 U 100 U1000 U 1000 U 1000 U 23.5 B 1000 U1000 U 1000 U 1000 U 1000 U 26.7 B39.1 B 26.3 B 107 B 500 U 500 U22.9 B 34.5 B 35 B 500 U 500 U50 U 32 B 67.4 65.5 50 U67.9 B 56.1 B 740 1290 510 J52 B J 61.2 B J 122 B J 1160 471 J0.25 G U 0.05 G U 0.5 G U 0.1 G U 1 G U0.25 U 0.05 G U 0.5 G U 0.25 G U 0.38 B0.065 B J 0.2 U 0.2 U 0.2 U 0.2 U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 8.1 4 J 3.7 J 1.1 J5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 1J 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U1000 U 1000 U 1000 U 1000 U 1000 U#N/A NA ND U NA NA NA5U 5U 5U 5U 5U5 U 8.1 5 U 5 U 5 U10 U 10 U 10 U 10 U 10 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U25 100 30 42 20 U100 U 100 U 100 U 100 U 100 U100 U 9.1 J 100 U 100 U 100 U5 U 4.2 J 5 U 5 U 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 150 5 U 5 U 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U1 J 1.4 J 5 U 5 U 5 U0.95 J 5 U 5 U 5 U 5 U5U 5U 5U 5U 5U5 U 5 U 2.2 J 5 U 5 U5 U 14 2.1 J 0.66 J 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 0 Day 1 Day 56/22/200910/28/20097/7/20096/23/2009 7/13/2009Tyler County, WVDay 14 Day 90Location RNA NA NA NA NA5U 5U 5U 5U 5U1.4 J 5 U 5 U 5 U 5 UNA NA NA NA NA1.2 J 3.2 J 2.5 J 1.3 J 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U8.4 J 13 J 6 J 6.6 J 15 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 19 U 38 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 UNA NA ND U NA NA NA10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U50 U 55 U 94 U 470 U 950 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 19 U 38 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 19 U 38 U10 U 11 U 19 U 94 U 190 U2 U 3.1 3.8 U 120 38 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U50 U 55 U 94 U 470 U 950 U10 U 11 U 19 U 94 U 190 U5.3 J 25 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U50 U 55 U 94 U 470 U 950 U50 U 55 U 94 U 470 U 950 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U50 U 55 U 94 U 470 U 950 U50 U 55 U 94 U 470 U 950 U100 U 110 U 190 U 940 U 1900 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 19 U 38 U2 U 2.2 U 3.8 U 19 U 38 U10 U 4.9 J 22 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U200 U 220 U 380 U 1900 U 3800 U2 U 2.2 U 3.8 U 19 U 38 U2 U 2.2 U 3.8 U 19 U 38 U2 U 2.2 U 3.8 U 19 U 38 U2 U 2.2 U 3.8 U 19 U 38 U2 U 2.2 U 3.8 U 19 U 38 U10 U 11 U 19 U 750 190 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 19 U 38 U2 U 2.2 U 3.8 U 19 U 38 U21 11 U 8.7 J 49 J 58 J B10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 19 U 38 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 19 U 38 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U1 J 11 U 19 U 94 U 190 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 0 Day 1 Day 56/22/200910/28/20097/7/20096/23/2009 7/13/2009Tyler County, WVDay 14 Day 90Location R10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 19 U 38 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 19 U 4.1 J B2 U 2.2 U 3.8 U 19 U 38 U2 U 2.2 U 3.8 U 19 U 38 U2 U 2.2 U 3.8 U 19 U 38 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 19 U 38 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 19 U 38 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 19 U 38 U2 U 2.2 U 3.8 U 19 U 38 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U20 U 22 U 38 U 190 U 380 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 22 29 J B2 U 2.2 U 3.8 U 19 U 38 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 U2 U 2.2 U 3.8 U 13 J 24 J B4.1 J 31 10 J 94 U 190 U10 U 11 U 19 U 94 U 190 U10 U 11 U 19 U 94 U 190 UNANANANANA0.05 U NA NA 0.048 U 0.25 U0.05 U NA NA 0.72 0.25 U0.05 U NA NA 0.048 U 0.25 U0.05 U NA NA 0.048 U 0.25 U0.05 U NA NA 0.048 U 0.25 U0.05 U NA NA 0.87 PG 0.41 PG0.5 U NA NA 0.48 U 2.5 U0.05 U NA NA 0.4 PG 0.25 U0.05 U NA NA 0.31 PG 0.25 U0.05 U NA NA 0.048 U 1.8 PG0.05 U NA NA 0.28 PG 0.25 U0.05 U NA NA 0.048 U 0.25 U0.05 U NA NA 0.32 PG 0.25 U0.05 U NA NA 0.048 U 0.25 U0.05 U NA NA 0.048 U 0.25 U0.05 U NA NA 0.96 0.340.05 U NA NA 0.49 PG 0.41 PG0.05 U NA NA 0.22 PG 0.310.1 U NA NA 0.096 U 0.5 U2U NANA1.9 U 10 U0.4 U NA NA 0.38 U 0.4 U0.4 U NA NA 0.38 U 0.4 U0.4 U NA NA 0.38 U 0.4 U0.4 U NA NA 0.38 U 0.4 U0.4 U NA NA 8 0.4 U0.4 U NA NA 0.38 U 0.4 U0.4 U NANA0.38 U 0.4 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 0 Day 1 Day 56/22/200910/28/20097/7/20096/23/2009 7/13/2009Tyler County, WVDay 14 Day 90Location R0.96 U NA NA 0.95 U 0.99 U57 J 41 J 57 J 11 J NA20 UJ 10 UJ 20 UJ 10 UJ NA20 UJ 10 UJ 20 UJ 10 UJ NA20 UJ 220 J 380 J 44 J NA20 UJ 10 UJ 20 UJ 10 UJ NA200 U 100 U 200 UJ 100 UJ NA200 U 100 U 200 UJ 100 UJ NA10 UJ 39 50 UJ 450 J NA10 UJ 1 U 50 UJ 1 U NA10 UJ 1 U 50 UJ 1 U NA300 100 250 600 NAPARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 5 U 22.9 90.20.01 U 0.01 U 0.01 U 0.01 U 0.01 U0.52 J 3 J 2.8 J 44.8 J 128 J2 U 2220 1440 218 9900.2 U 0.2 U 0.2 U 306 60218.4 J 4810 J 3420 J 1810 2190028.1 58.5 64.2 36800 J 79000 J2.3 J 906 J 657 J 217 2140.05 U 0.05 U 0.077 1.2 G U 2.5 G U156 156 156 15400 340001.8 2.6 2.7 1.2 G U 0.43 B3 3.1 2.8 1.2 J 0.410.05 U 0.06 0.045 B 10.3 2.5 G U4.6 U 158 13.7 7.5 36.2466 J 480 J 479 J 116000 J 266000 J8.4 32.6 17.7 2.4 B J 33.5 B J2.7 931 672 104 15088.8 J 109 J 123 J 175 J 74.2 J277 280 680 58300 1240003 U 42.3 47.5 75.9 1160.1 U 0.082 B 0.037 B 0.053 B 0.035 B4 U 200 142 62 511.7 308 300 293 46010 U 3.5 B 6.6 B 10 U 7.4 B3.2 3 U 3 U 3 U 1.6 B7 7.2 7.9 6.4 6.60.0065 B 0.044 0.048 0.021 0.111.2 20 15.2 38.0 9.200.0969 0.05 U 0.0613 0.189 0.0945177 B 623 B 507 B 152 B 2000 U2000 U 203 B 165 B 2000 U 2000 U15.4 B 16.8 B 100 U 31.3 B 49.1 B100 U 100 U 13.5 B 24.1 B 100 U100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U840 B 410 B 332 B 652000 1500000734 B 346 B 240 B 712000 151000040 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U18.9 B 17.8 B 18.1 B 7920 1360015.8 B 13.8 B 14.2 B 8950 140001.7 B 2.1 B 2.2 B 3.8 B 3.9 B2 B 50 U 1.3 B 50 U 3 B40100 B J 35200 B J 35200 B J 4080000 J 11800000 J37500 B J 36000 B J 37800 B J 4510000 J 12000000 J50 U 50 U 7.5 B 50 U 10.2 B50 U 50 U 50 U 50 U 50 U500 U 4.4 B 5.7 B 500 U 2500 U500 U 5.4 B 6.2 B 500 U 2500 U250 U 109 B 43.9 B 71.4 B 35.3 B250 U 123 B 37.2 B 55 B 38.8 B394 B 1790 6490 77900 732001000 U 726 B 1670 34700 3400030 U 30 U 30 U 21.2 B 21.7 B30 U 30 U 30 U 30 U 30 U500 U 42 B 500 U 34800 9490042.1 B 31.1 B 500 U 37800 931018300 B 15700 B 16000 B 373000 98700017000 B 16200 B 17300 B 412000 10000008.7 B 37.9 B 146 B 1850 2670150 U 30.5 B 119 B 2030 2680400 U 400 U 14.2 B 39.1 B 400 U400 U 400 U 400 U 26.8 B 400 U400 U 400 U 16.7 B 19 B 400 U400 U 400 U 400 U 400 U 400 U2930 B 2420 B 2690 B 301000 10200003090 B 2590 B 3000 B 354000 105000050 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 UDay 14Day 0 Day 5Day 18/29/2009 9/8/20098/25/20098/25/2009 8/25/2009Supply WaterCentre County, PALocation SPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 14Day 0 Day 5Day 18/29/2009 9/8/20098/25/20098/25/2009 8/25/2009Supply WaterCentre County, PALocation S37700 B 60800 63800 16400000 3270000035300 B 71800 69200 18000000 33000000723 E 597 580 1560000 5020000653 J E 624 J 594 J 1710000 J 4930000 J100 U 100 U 100 U 24.6 B 100 U100 U 100 U 100 U 100 U 100 U1000 U 1000 U 1000 U 1000 U 20.7 B1000 U 1000 U 1000 U 1000 U 1000 U500 U 500 U 500 U 500 U 500 U500 U 500 U 500 U 500 U 500 U50 U 50 U 50 U 50 U 50 U172 B J 164 B J 138 B J 343 J 604 J156 B J 140 B J 73.8 B J 238 J 673 J0.01 U 0.0078 B 0.05 G U 0.5 G U 0.5 G U0.01 U 0.05 G U 0.05 G U 0.42 B G 0.25 G U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U0.2 U 0.2 U 0.2 U 0.049 B J 0.2 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 6.55 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 1.5 J5 U 11 33 50 U 3.9 J5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 2.8 J 13 50 U 1.1 J5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U1000 U 1000 U 1000 U 10000 U 1000 UNA NA NA NA NA5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U10 U 10 U 10 U 100 U 10 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U20 U 5.4 J 14 J 1300 31100 U 100 U 100 U 1000 U 100 U100 U 100 U 100 U 1000 U 100 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 0.81 J 1.8 J 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 1.8 J 50 U 2.8 J5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 28 J 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 14Day 0 Day 5Day 18/29/2009 9/8/20098/25/20098/25/2009 8/25/2009Supply WaterCentre County, PALocation SNA NA NA NA NA5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 UNA NA NA NA NA5 U 1.6 J 3.8 J 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U15 U 5.4 J 16 150 U 15 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 UNA NA NA NA NA9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U47 U 47 U 47 U 470 U 48 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U47 U 47 U 47 U 470 U 48 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 1.9 J 9.5 U47 U 47 U 47 U 470 U 48 U47 U 47 U 47 U 470 U 48 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U47 U 47 U 47 U 470 U 48 U47 U 47 U 47 U 470 U 48 U94 U 94 U 94 U 940 U 95 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U190 U 190 U 190 U 1900 U 190 U1.9 U 1.9 U 1.9 U 19 U 1.2 J1.9 U 1.9 U 1.9 U 19 U 1.1 J1.9 U 1.9 U 1.9 U 19 U 1 J1.9 U 1.9 U 1.9 U 19 U 1.2 J1.9 U 1.9 U 1.9 U 19 U 0.91 J9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U1.9 U 1.9 U 1.9 U 19 U 1.9 U1.9 J B 14 9.4 U 94 U 7.5 J B9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.1 J9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 2.39.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 7.7 J B 2.6 J B9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U0.6 J 2 J 9.4 U 94 U 1.5 JPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 14Day 0 Day 5Day 18/29/2009 9/8/20098/25/20098/25/2009 8/25/2009Supply WaterCentre County, PALocation S9.4 U 9.4 U 9.4 U 94 U 9.3 J9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.7 J9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.3 J1.9 U 2 1.9 U 19 U 1.4 J1.9 U 1.9 U 1.9 U 19 U 1 J1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 2.49.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U1.9 U 1.9 U 1.9 U 19 U 1.7 J9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U19 U 19 U 19 U 190 U 19 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 3.4 3.5 19 U 1.3 J1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 0.76 J 0.89 J 19 U 1.1 J9.4 U 70 18 530 2809.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 UNANANANANA0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.47 U 0.47 U NA NA 0.49 U0.047 U 0.047 U NA NA 0.048 J PG0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.50.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.041 J NA NA 0.049 U0.051 0.063 NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.094 U 0.094 U NA NA 0.098 U1.9 U 1.9 U NANA2 U0.38 U 0.38 U NA NA 0.39 U0.38 U 0.38 U NA NA 0.39 U0.38 U 0.38 U NA NA 0.39 U0.38 U 0.38 U NA NA 0.39 U0.38 U 0.38 U NA NA 0.39 U0.38 U 0.38 U NA NA 0.39 U0.38 U 0.38 U NANA0.39 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 14Day 0 Day 5Day 18/29/2009 9/8/20098/25/20098/25/2009 8/25/2009Supply WaterCentre County, PALocation S0.94 U 0.95 U NA NA 0.98 U10 U 310 150 J 140 J 83 J10 U 20 U 20 UJ 10 UJ 10 UJ10 U 20 U 20 UJ 10 UJ 10 UJ10 U 20 U 20 UJ 10 UJ 10 UJ10 U 20 U 20 UJ 10 UJ 10 UJ100 U 200 U 200 UJ 100 UJ 100 UJ100 U 240 200 UJ 150 J 110 J1 U 50 U 1.4 5.8 J 6.6 J1 U 50 U 1 U 1 U 2 UJ1 U 50 U 1 U 2 UJ 2 UJ15 150 75 600 60049 

# Appendix D

Summary of Detected VOCs, SVOC,

Pesticides and PCBsLocation BDay 0 Day 1 Day 5PARAMETERUNITS PQL US EPA Method2/7/2009 2/8/2009 2/11/20091,2,3-Trichlorobenzene ug/L 5 SW846 8260B16 J1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B 16 140 J 82 110 J 74 23 J1,3,5-Trimethylbenzene ug/L 5 SW846 8260B 6 100 J 33 120 65 19 J2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260B 7675 J BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260B 7.7 8 8.5 J 240 1200 420 360Bromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260B1500Chloroform ug/L 5 SW846 8260B 28Chloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260B19 J 14 J 85 J 42 J 21 JIsopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260B24 J 18 Jn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260B54 J 22 Jsec-Butylbenzene ug/L 5 SW846 8260B84 J 68 JTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260B 5.1 81 J 340 820 660Xylenes (total) ug/L 15 SW846 8260B 18 210 J B 1100 300NOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laboratory detection limit.J - The reported result is an estimated result. The result is less than the laboratory reporting limit.E - The resported result is an estimated result.Volatile Organic Compounds2/20/2009 1/26/2009 1/29/2009 2/2/2009 2/10/2009 4/29/2009Day 0 Day 1 Day 5 Day 14 Day 90Day 14Location APARAMETERUNITS PQL US EPA Method1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration islJ - The reported result is an estimated result. The result is less than thE - The resported result is an estimated result.Volatile Organic CompoundsLocation D Location EDay 0 Day 1 Day 5 Day 14 Day 0 Day 1 Day 90 Day 0 Day1 Day 5 Day 142/11/2009 2/17/2009 2/20/2009 2/27/2009 2/12/2009 2/13/2009 5/13/09 4/1/2009 4/3/2009 4/7/2009 4/17/2009140 J 207.8 5.8 1723000 1400 260 19 54000 7300 4005.6 7.7 132/17/2009Location CDay 5PARAMETERUNITS PQL US EPA Method1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration islJ - The reported result is an estimated result. The result is less than thE - The resported result is an estimated result.Volatile Organic CompoundsLoc G Location HDay 14 Day 0 Day 144/22/2009 4/7/2009 4/22/2009170 J66 J11 52 33 980 24000 4000 6305.2 J 33 J 21 J 820 11000 1900 28014 J 98 J 26 66000 23 5800 1600 20280 880 400 290 6.77.6 J 29 J 23 J 270130 J 10000 1400 260300 920 540 1600120 340 280 3300 5200 J 860 J 130 J3/27/2009 4/1/2009 4/9/2009 6/29/2009 4/7/2009 4/8/2009 4/13/2009Day 14 Day 90Day 1 Day 5Day 1 Day 5Supply WaterLocation FPARAMETERUNITS PQL US EPA Method1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration islJ - The reported result is an estimated result. The result is less than thE - The resported result is an estimated result.Volatile Organic CompoundsLocation I Location J Location KDay 5 Day 14 Day 0 Day 1 Day 14 Day 0 Day 1 Day 55/19/2009 5/28/2009 5/1/2009 5/4/2009 5/18/2009 05/07/2009 5/20/2009 5/22/200942 14 7.720 7.7 5.37.5390 130 25 22 B 3307.8 5.813 B8.9 J6.7355/15/2009 5/8/20095/9/2009Day 1 Day 5Day 0PARAMETERUNITS PQL US EPA Method1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration islJ - The reported result is an estimated result. The result is less than thE - The resported result is an estimated result.Volatile Organic CompoundsLocation LSupply Water Day 0 Day 1 Day 5 Day 14 Day 1 Day 145/12/2009 5/13/2009 5/14/2009 5/18/2009 5/27/2009 6/6/2009 6/19/200927 38 77067 5914 32 6707.7 J 6.7 J17 J21 170 90 J 210 130 J 69 J39 99 260 6.250 9.317 220865.5 J820 72046 260 150019 J15 220 2700 25 J 46 J 26 J07/14/09 7/15/2009 7/19/2009 7/1/2009 7/1/2009Day 0 Day 1 Day 5 Day 0 Day 1Location N Location OLocation MPARAMETERUNITS PQL US EPA Method1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration islJ - The reported result is an estimated result. The result is less than thE - The resported result is an estimated result.Volatile Organic CompoundsLocation P Location QDay 90 Day 0 Day 5 Day 1410/29/2009 6/30/2009 7/6/2009 7/15/2009840 710 84940 770 79320 5200 190 28 16 J 42 520140 2000 1100 200230 J5.9 J650 470 J 46160 J 120 J90 J92 6200 5200 58032 6500 5400 5307/20/2009 7/29/20097/15/2009 7/1/2009Day 1 Day 5 Day 1Day 14PARAMETERUNITS PQL US EPA Method1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration islJ - The reported result is an estimated result. The result is less than thE - The resported result is an estimated result.Volatile Organic CompoundsLocation R Location SDay 0 Day 1 Day 5 Day 14 Day 0 Day 1 Day 146/22/2009 6/23/2009 7/13/2009 7/7/2009 8/25/2009 8/25/2009 9/8/20096.58.1 11 33138.125 100 30 42 1300 311501428 J168/29/2009Day 5PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C 22-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270C 35 JDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270C 2.7Phenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270C 86 2600 1800 860 490NOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laboratory detection limit.J - The reported result is an estimated result. The result is less than the laboratory reporting limit.E - The resported result is an estimated result.2/7/2009 2/11/2009 2/20/2009Location A2/8/2009Day 1 Day 5 Day 14 Day 90Day 0Semi-Volatile Organic Compounds5/8/2009PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.Semi-Volatile Organic CompoundsLocation B120 941141 J14 11 149.83.211 J 8.4 J0.99 J3.122 J 16 J11 J310 350 250 77 2602/2/2009 2/10/2009Day 144/29/20091/26/2009 1/29/2009Day 0 Day 1 Day 5 Day 90PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.Semi-Volatile Organic CompoundsLocation D7.5 3.70.35 J 1.1 J9.5302.4172/13/20092/12/2009 2/17/2009 5/13/09Day 0 Day 1 Day 90Day 5PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.Semi-Volatile Organic CompoundsLocation E102.6 J 3.235 430 310 200 574/1/2009 4/17/20094/3/2009 4/7/2009 4/17/2009Day 90Day1 Day 5Day 0 Day 14PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.Semi-Volatile Organic CompoundsLocation F11 12 J1133 870143 J16 15 16370 520 250 220 1406/29/20093/24/2009 3/27/2009Day 14 Day 90Day 0 Day 14/1/2009 4/9/2009Day 5PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.Semi-Volatile Organic CompoundsLocation G2.716 10 201155 30 144/8/2009 4/22/20094/13/2009 4/7/2009 4/13/2009 4/22/2009Day 14Day 0Locaction HDay1 Day 5 Day 14 Day 5PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.Semi-Volatile Organic CompoundsLocation I6.7106.95.941 J 17115.5 6.19.5640 310 42Day 510/20/20095/9/2009 5/15/2009 5/19/2009Day 90Day 0 Day 1PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.Semi-Volatile Organic Compounds2136.9117.46.74300 18 179.612130102.7150Day 0Day 145/18/20095/1/2009 5/4/2009 05/07/20095/8/2009Day 146/2/2009Location KLocation JDay 1 Day 5Day0PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.Semi-Volatile Organic CompoundsLocation L5/13/2009165.5 105/14/2009 5/18/2009Day 5Day 0 Day 1PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.Semi-Volatile Organic Compounds2.5140 100 94Day 56/10/2009Location M6/6/2009Day 17/15/2009Location NDay 1 Day 146/19/2009PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.Semi-Volatile Organic Compounds260 523.5 J7/1/2009Day 17/1/2009Location ODay 0PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.Semi-Volatile Organic CompoundsLocation P Location Q1215161616 J 1015 J219.4 U360 470 220 3407/15/2009Day 110/29/2009 6/30/2009Day 5 Day 14 Day 07/20/2009 7/29/2009Day 90PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.Semi-Volatile Organic CompoundsLocation R3.1 120252275021 49 J 58 J B4.1 J B22 29 J B13 J 24 J B31 10 J7/7/20096/23/2009 7/13/20096/22/2009 10/28/2009Day 14 Day 90Day 1 Day 5Day 0PARAMETERUNITS PQL US EPA Method2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.Semi-Volatile Organic CompoundsLocation S142.322.43.4 3.570 18 530 2808/25/2009 8/29/2009 9/8/20098/25/2009Day 14Day 0 Day 1 Day 5PesticidesPARAMETERUNITS PQL US EPA Method4,4'-DDE ug/L 0.05 SW846 8081A 0.11Aldrin ug/L 0.05 SW846 8081A 0.12 PG 0.35beta-BHC ug/L 0.05 SW846 8081A 0.062 PGdelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081A 0.22 PGEndosulfan II ug/L 0.05 SW846 8081A0.42Endrin ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081A 0.24 0.093Heptachlor epoxide ug/L 0.05 SW846 8081AAroclor 1248 ug/L 0.4 SW846 8082PG - indicates that the result is estimated and the sample was diluted due to matrix interferenceLocation DLocation C Location HLocation FLocation E5/15/2009 6/29/2009 4/22/2009 7/22/2009Day 902/12/2009Day 904/7/20094/17/2009Day 0 Day 90 Day 14 Day 90Day 0PesticidesPARAMETERUNITS PQL US EPA Method4,4'-DDE ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AAroclor 1248 ug/L 0.4 SW846 8082PG - indicates that the result is estimated and the sample was dilutedd0.0830.11 PG0.37 0.069 PG0.27 0.380.1 0.8 PG 0.84 PG 0.065 PGLocation I Location MLocation LLocation KLocation J Location O5/19/2009 5/19/20096/2/2009 7/1/20095/27/2009Day 14 Day 145/28/2009 5/18/2009Supply Water Day 0 Day 0Day 14 Day 14PesticidesPARAMETERUNITS PQL US EPA Method4,4'-DDE ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AAroclor 1248 ug/L 0.4 SW846 8082PG - indicates that the result is estimated and the sample was dilutedd0.720.17 PG0.26 0.87 PG 0.41 PG0.072 PG 0.4 PG0.31 PG1.8 PG 0.50.28 PG0.32 PG0.96 0.340.12 0.49 PG 0.41 PG 0.051 0.0630.26 PG 0.22 PG 0.3189/8/2009Location SLocation RLocation Q8/25/2009 8/25/20096/30/2009 7/7/2009 10/28/2009Day 14Supply Water Day 0Day 0 Day 14 Day 90

## ATTACHMENT B

MSC Database for the 8 Northern Pennsylvania WellsPARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B1230 5 U 5 19.4 1490.01 U 0.01 U 0.01 U 0.01 U 0.01 U441 J 71.4 J NA 359 J 220 J189 302 144 7.3 2 U0.2 U 261 553 697 171502 2100 4470 12800 12700 J86 43300 77200 102000 166000 J11.6 124 J 58.4 43 J 16.40.19 2.2 B 2.4 B 2.5 G U 5 G U130 15000 44000 55000 960003.4 1.6 B 2 B 2.5 G U 5 G U2.4 J 1.9 J 0.63 J 0.16 J 0.051 B2.5 G U 2.5 G U 2.5 G U 2.5 G U 1464.7 U 4.6 U 10.8 4.6 U 4.8 U6720 J 147000 J 278000 J 360000 J 7420002920 19 B J 39.2 B J 49.4 B J 100 G U11.4 J 123 60.8 42.2 63.35 U 124 J 72.4 J 47.7 J 25 J1920 74600 125000 169000 298000400 69.9 94.9 130 157 J0.26 0.19 2.5 G U 2.5 G U 1 G U4 68 260 162 71.54.7 126 92 32.9 94.510 U 10 U 10 U 10 U 10 U3 U 3 U 3 U 1.6 B 3 U6 7 6.3 6.4 5.80.017 J 0.01 U 0.0084 B 0.011 J 0.01 U5 U 5.60 23.2 13.6 NA0.0933 2.94 0.736 1.06 NA2000 U 505 B 927 B J 835 B J 173 B J2000 U 358 B 508 B J 562 B J 167 B J100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U100 U 28.2 B 54.2 B 77.3 B 100 U100 U 37.4 B 70.5 B 82.3 B 100 U339 B 1160000 3220000 J 5150000 J 8450000348 B 1340000 3260000 5070000 753000040 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U59.3 B J 3030 J 3840 3880 299068.7 B J 3470 J 3890 3820 2680 J50 U 50 U 3 B J 3.8 B J 50 U50 U 50 U 50 U 3.2 B 50 U32900 B 4070000 9270000 J 13100000 J 2290000031800 B 4360000 9700000 J 14800000 J 2050000050 U 50 U 20.8 B J 12.7 B J 50 U50 U 50 U 50 U 6.6 B 50 U7.9 B 2500 U 1000 U 5000 U 5000 U14.2 B 2500 U 5000 U 5000 U 5000 U120 B 250 U 73.3 B 250 U 250 U85.3 B 250 U 250 U 250 U 250 U14300 15700 33500 39200 5870013100 3690 16700 J 31500 J 4170030 U 30 U 40.4 B J 78 B J 30 U30 U 30 U 150 U 150 U 30 U34.1 B 80300 153000 201000 26200038.7 B 93000 155000 202000 230000 J6190 B 271000 608000 781000 12800006240 B 293000 647000 J 875000 J 117000067.2 B 1680 3440 J 4780 J 974073.7 B 1930 3550 5170 8760400 U 8.9 B 12.4 B 400 U 400 U400 U 12.1 B 400 U 400 U 54.4 B457 14.9 B 800 U 2000 U 400 U452 20.1 B 2000 U 2000 U 400 U50000 U 127000 210000 312000 54700050000 U 144000 235000 274000 47700050 U 50 U 50 U 39.4 B 50 U50 U 50 U 50 U 49.5 B 50 U50 U 50 U 9.3 B 8.4 B 50 U50 U 50 U 50 U 8.1 B 50 UDay 1Day 0 Day 15Day 510/21/20094/13/20093/31/2009 4/8/2009Lycoming County, PADay 904/22/2009Location GPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 1Day 0 Day 15Day 510/21/20094/13/20093/31/2009 4/8/2009Lycoming County, PADay 904/22/2009Location G45000 B 18100000 30800000 40300000 5860000044700 B 20900000 31400000 41100000 50700000 J691 947000 2350000 J 3650000 J 6390000 J686 1090000 2530000 J 3710000 J 5710000 J100 U 100 U 200 U 500 U 26.4 B100 U 100 U 500 U 500 U 53.8 B1000 U 1000 U 1000 U 1000 U 1000 U1000 U 1000 U 1000 U 1000 U 29.8 B500 U 55.9 B 133 B 148 B 500 U500 U 105 B 121 B 138 B 500 U50 U 50 U 50 U 50 U 50 U40.7 B 200 U 67.6 B J 52.2 B J 48 B J46.9 B 200 U 41.6 B 49.8 B 42.3 B J0.01 U 0.5 G U 1 G U 2.5 G U 2 G U0.01 U 0.5 G U 1 G U 2.5 G U 2 G U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 1.3 J 5 U 5 U 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U1000 U 1000 U 1000 U 1000 U 1000 UNA NA NA NA NA5U 5U 5U 5U 5U5U 5U 5U 5U 5U10 U 10 U 10 U 10 U 10 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U20 U 13 J 16 J 26 12 J100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U2.2 J 5 U 5 U 5 U 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 1.7 J 5 U 5 U 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 1Day 0 Day 15Day 510/21/20094/13/20093/31/2009 4/8/2009Lycoming County, PADay 904/22/2009Location GNA NA NA NA NA5U 5U 5U 5U 5U5U 5U 5U 5U 5UNA NA NA NA NA5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U15 U 15 U 15 U 15 U 15 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 UNA NA NA NA NA9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U47 U 46 U 47 U 48 U 50 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 2.7 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U47 U 46 U 47 U 48 U 50 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U47 U 46 U 47 U 48 U 50 U47 U 46 U 47 U 48 U 50 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U47 U 46 U 47 U 2.6 J 50 U47 U 46 U 47 U 48 U 50 U94 U 92 U 94 U 95 U 100 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 0.22 J 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U0.21 J 0.98 J 0.81 J 0.38 J 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U190 U 180 U 190 U 190 U 200 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 1.1 J 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 1Day 0 Day 15Day 510/21/20094/13/20093/31/2009 4/8/2009Lycoming County, PADay 904/22/2009Location G9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 0.22 J 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U19 U 18 U 19 U 19 U 20 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U1.9 U 1.8 U 1.9 U 1.9 U 2 U9.4 U 55 30 14 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 U9.4 U 9.2 U 9.4 U 9.5 U 10 UNANANANANA0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.48 U NA NA 0.47 U 0.72 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.048 U NA NA 0.047 U 0.072 U0.095 U NA NA 0.094 U 0.14 U1.9 U NANA1.9 U 2.9 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NANA0.38 U 0.4 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 1Day 0 Day 15Day 510/21/20094/13/20093/31/2009 4/8/2009Lycoming County, PADay 904/22/2009Location G0.94 U NA NA 0.94 U 1 U5 UJ NA 10 UJ 10 UJ NA5 UJ NA 10 UJ 10 UJ NA5 UJ NA 10 UJ 10 UJ NA8.3 J NA 58 J 39 J NA5 UJ NA10 UJ 10 UJ NA100 UJ NA 100 UJ 100 UJ NA100 UJ NA100 UJ 100 UJ NA10 UJ NA 100 U 10 J NA10 UJ NA 100 U 18 J NA10 UJ NA 100 U 10 UJ NA250 NA430 10 UJ NAPARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 5 U 123 216 3360.01 U 0.01 U 0.01 U 0.01 U 0.01 U 0.01 U0.064 B 5.9 127 199 J 229 278 J2 U 578 399 99.4 10.4 3.40.22 1 238 901 1010 151018.7 2560 8790 195 12100 20200 J49.9 90.2 58700 148000 181000 1960003.2 J 577 600 59.6 26.5 13.20.05 U 0.05 U 2.5 G U 2.5 G U 5 G U 5 G U38 42 8600 42000 50800 1040000.05 U 0.02 B 2.5 G U 2.5 G U 5 G U 7.40.1 U 0.59 1.1 0.1 U 0.1 U 0.580.05 U 0.034 B 2.5 G U 2.5 G U 52 5 G U4.8 U 62.2 53.9 4.8 U 4.8 U 4.7247 J 362 J 200000 J 470000 J 570000 J 7630008.3 J 8.4 J 36.6 B J 50 G U 100 G U 44.2 B J4.7 J 607 610 48 12.8 149.3 J 33.4 J 175 J 48.8 J 37.3 J 25.3 J400 265 122000 238000 261000 2710003 U 65.4 150 160 131 2180.14 0.062 B 0.084 B 0.45 0.1 U 0.08 B2 B 192 308 696 65.2 823.1 75.2 461 203 180 67.210 U 4.1 B 10 U 10 U 10 U 3.6 B1.6 B 3 U 3 U 3 U 3 U 3 U7.3 7.6 6.6 5.8 5.6 5.10.01 U 0.028 0.015 0.022 0.017 0.01 U21.6 27.6 NA 6.80 31.2 NA0.240 0.05 U NA1.31 0.191 NA2000 U 2000 U 1750 B J 418 B J 846 B 904 B J2000 U 227 B 286 B J 596 B J 983 B 130 B J100 U 100 U 31.5 B 47.2 B 27.2 B 100 U100 U 100 U 18.9 B 200 U 200 U 100 U100 U 100 U 42.9 B 59.6 B 89.2 B 100 U100 U 100 U 29.9 B 62.6 B 75.6 B 100 U1640 B 1170 B 516000 1400000 2460000 46700001580 B J 1500 B J 532000 J 1740000 2500000 581000040 U 40 U 40 U 80 U 80 U 3.4 B40 U 40 U 40 U 80 U 80 U 6.8 B34.3 B J 33.9 B J 5930 J 11900 16400 1870044.2 B J 49.9 B J 6240 15400 16800 24300 J50 U 50 U 2.9 B 9.6 B 11.8 B J 3.5 B J50 U 50 U 2.6 B 11.4 B 12.2 B 3 B11600 B J 9900 B J 2950000 9400000 J 17300000 J 3300000012000 B J 13000 B J 3060000 11700000 17600000 J 4100000050 U 50 U 50.4 12.2 B 28.8 B 9.7 B50 U 50 U 18.7 B 100 U 24.4 B 8 B500 U 500 U 1000 U 2500 U 2500 U 5000 U500 U 500 U 1000 U 2500 U 2500 U 5000 U250 U 250 U 68.3 B 500 U 79 B 48.1 B250 U 250 U 35 B 500 U 500 U 28.6 B192 B 198 B 58700 49700 76600 1310001000 U 175 B 21000 39100 J 53900 15200030 U 30 U 60 U 150 U 150 U 13.2 B30 U 30 U 60 U 150 U 150 U 30 U42.2 B 29.7 B 34600 97600 170000 32300032.7 B 51.7 B 36500 125000 172000 323000 J1840 B 1360 B 177000 604000 1100000 20200001830 B 1720 B 185000 765000 J 1110000 255000013.9 B 150 U 2840 5520 9560 16900150 U 11.5 B 2870 6810 9630 21200400 U 400 U 90 B 27.6 B 34.4 B 400 U400 U 400 U 84.2 B 29.2 B 31.8 B 400 U400 U 400 U 66.8 B 2000 U 2000 U 400 U400 U 400 U 66.8 B 2000 U 2000 U 400 U50000 U 50000 U 378000 811000 1300000 28600002240 B 3790 B 410000 1040000 1320000 385000050 U 50 U 50 U 100 U 100 U 50 U50 U 50 U 50 U 100 U 100 U 50 U50 U 50 U 50 U 100 U 100 U 50 U50 U 50 U 50 U 100 U 100 U 50 UDay 14Day 5Day 15/19/20095/9/2009 5/9/20095/28/2009 10/20/20095/15/2009Day 90Cameron County, PADay 0Supply WaterLocation IPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 14Day 5Day 15/19/20095/9/2009 5/9/20095/28/2009 10/20/20095/15/2009Day 90Cameron County, PADay 0Supply WaterLocation I24400 B 54200 34700000 65100000 85600000 9550000024900 B 70800 35000000 83400000 88000000 117000000 J1500 1070 492000 J 1800000 3120000 6290000 J1460 J 1340 J 500000 J 2210000 J 3210000 J 7820000 J100 U 100 U 200 U 500 U 500 U 26.8 B100 U 100 U 200 U 500 U 500 U 100 U1000 U 1000 U 1000 U 2000 U 2000 U 1000 U1000 U 1000 U 1000 U 2000 U 2000 U 1000 U29.9 B J 27.1 B J 69.9 B 143 B 197 B 500 U29.6 B J 24.4 B J 44.3 B 211 B 230 B 500 U50 U 50 U 50 U 100 U 24.4 B 50 U25.7 B J 45.7 B J 314 269 B J 591 J 810 J61.5 B J 79.4 B J 187 B 195 B 566 992 J0.25 G U 0.25 G U 0.5 U 0.25 G U 0.5 G U 0.5 G U0.25 G U 0.25 G U 0.27 B 0.25 U 0.25 G U 0.5 G U0.053 B J 0.044 B J 0.2 U 0.2 U 0.2 U 0.2 U0.05 B J 0.47 B J 0.2 U 0.2 U 0.2 U 0.2 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 3.1 J 5 U 2.4 J 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 2.3 J 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U1000 U 1000 U 5000 U 1000 U 1000 U 1000 UNA NA NA NA NA NA5 U 5 U 25 U 5 U 5 U 5 U5 U 7.5 25 U 5 U 5 U 5 U10 U 10 U 50 U 10 U 10 U 10 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U6.3 J B 20 U 390 130 25 20 U100 U 100 U 500 U 100 U 100 U 100 U100 U 100 U 500 U 100 U 100 U 100 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 1.6 J 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 13 B 25 U 5 U 5 U 5 U5 U 0.95 J 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 14Day 5Day 15/19/20095/9/2009 5/9/20095/28/2009 10/20/20095/15/2009Day 90Cameron County, PADay 0Supply WaterLocation INA NA NA NA NA NA5 U 5 U 25 U 5 U 5 U 5 U5 U 1.3 J 8.9 J 5 U 5 U 5 UNA NA NA NA NA NA5 U 6.7 25 U 5 U 3 J 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 0.81 J 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U5 U 5 U 25 U 5 U 5 U 5 U15 U 2.6 J 75 U 15 U 6.9 J 15 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 UNA NA NA NA NA NA9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U47 U 48 U 470 U 47 U 48 U 100 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 0.67 J 1.9 U 4 U9.4 U 9.5 U 94 U 0.53 J 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U47 U 48 U 470 U 1.3 J 48 U 100 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 1.2 J 8.1 J 20 U47 U 48 U 470 U 47 U 48 U 100 U47 U 48 U 470 U 47 U 48 U 100 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 0.75 J 9.7 U 20 U47 U 48 U 470 U 47 U 48 U 100 U47 U 48 U 470 U 47 U 48 U 100 U94 U 95 U 940 U 94 U 97 U 200 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 0.9 J 1.9 U 4 U1.9 U 1.9 U 19 U 0.84 J 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U190 U 190 U 1900 U 190 U 190 U 400 U1.9 U 1.9 U 19 U 0.97 J 1.9 U 4 U1.9 U 1.9 U 19 U 6.7 1.9 U 4 U1.9 U 1.9 U 19 U 10 1.9 U 4 U1.9 U 1.9 U 19 U 6.9 1.9 U 4 U1.9 U 1.9 U 19 U 5.9 1.9 U 4 U9.4 U 9.5 U 41 J 17 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U9.4 U 9.5 U 94 U 6.9 J 4 J 1.4 J9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 0.85 J 1.9 U 0.29 J B9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 11 1.9 U 4 U9.4 U 9.5 U 94 U 0.87 J 9.7 U 20 U9.4 U 9.5 U 94 U 1.3 J 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 0.87 J 9.7 U 20 U9.4 U 9.5 U 94 U 5.3 J 9.7 U 20 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 14Day 5Day 15/19/20095/9/2009 5/9/20095/28/2009 10/20/20095/15/2009Day 90Cameron County, PADay 0Supply WaterLocation I9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1 J 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 5.5 19 U 6.1 1.9 U 4 U1.9 U 1.9 U 19 U 0.82 J 1.9 U 4 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 9.5 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 1.9 U 1.9 U 4 U1.9 U 1.9 U 19 U 1 J 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U19 U 19 U 190 U 19 U 19 U 40 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 0.89 J 1.9 U 4 U1.9 U 1.9 U 19 U 0.7 J 1.9 U 4 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U1.9 U 1.9 U 19 U 0.89 J 1.9 U 4 U9.4 U 4.5 J 640 310 9.7 U 429.4 U 9.5 U 94 U 9.4 U 9.7 U 20 U9.4 U 9.5 U 94 U 9.4 U 9.7 U 20 UNANANANANANA0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.37 0.05 U0.48 U 0.47 U NA NA 0.48 U 0.5 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.048 U 0.047 U NA NA 0.048 U 0.05 U0.095 U 0.094 U NA NA 0.095 U 0.1 U1.9 U 1.9 U NANA1.9 U 2 U0.38 U 0.38 U NA NA 0.38 U 0.4 U0.38 U 0.38 U NA NA 0.38 U 0.4 U0.38 U 0.38 U NA NA 0.38 U 0.4 U0.38 U 0.38 U NA NA 0.38 U 0.4 U0.38 U 0.38 U NA NA 0.38 U 0.4 U0.38 U 0.38 U NA NA 0.38 U 0.4 U0.38 U 0.38 U NANA0.38 U 0.4 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 14Day 5Day 15/19/20095/9/2009 5/9/20095/28/2009 10/20/20095/15/2009Day 90Cameron County, PADay 0Supply WaterLocation I0.95 U 0.97 U NA NA 0.95 U 1 U10 UJ 20 UJ 10 UJ 10 UJ 10 UJ UJ10 UJ 20 UJ 10 UJ 10 UJ 10 UJ UJ10 UJ 20 UJ 10 UJ 10 UJ 10 UJ UJ10 UJ 130 J 52 J 59 J 48 J J10 UJ 20 UJ 10 UJ 10 UJ 10 UJ UJ100 UJ 200 UJ 100 UJ 100 UJ 100 UJ UJ100 UJ 200 UJ 100 UJ 100 UJ 100 UJ UJ1 U 50 UJ 10 UJ 10 UJ 100 UJ UJ1 U 50 UJ 10 UJ 10 UJ 100 UJ UJ1 U 50 UJ 10 UJ 10 UJ 100 UJ UJNANANA57 460PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5U 5U 5U 5U 5U0.01 U 0.01 U 0.01 NR U 0.01 U 0.01 U0.017 B J 5.6 J 13.2 36.9 17.8 J2 U 47.1 36.7 47.5 20.30.14 B 36.6 39.1 233 6510 U 47400 397 4870 853042.3 2180 2460 26400 8060 J3.2 J 168 J 207 J 30.7 J 82.80.033 B 0.05 U 0.5 G U 1.2 G U 0.5 G U140 1300 1060 7800 31001.7 1.6 0.83 2.3 0.5 G U1.8 2 0.94 0.89 0.920.05 U 0.05 U 0.39 B 1.2 G U 1.84.8 U 29.2 7.3 4.8 U 4.8 U380 J 9280 J 8740 J 90500 J 32000 J43.7 27.7 17.4 J 17.6 B J 10 G U2.2 569 56.6 27.5 23.671.4 J 191 J 107 J 187 J 119 J746 4840 5090 48700 191003 U 17.1 14.2 96.1 17.90.044 B 0.072 B 0.14 0.088 B 0.39.6 230 330 68.8 11501.3 101 330 30.2 52410 U 4.6 B 15.2 10 U 10 U2.4 B 3 U 3 U 3 U 3 U7.2 7.2 7.4 6.6 6.80.01 J 0.027 0.03 0.01 U 0.009 B10.0 20.4 13.2 6.00 9.60.962 0.05 U 0.134 0.0761 0.137249 B J 400 B J 4030 J 111 B 4680 J2000 U 2000 U 212 B 2000 U 266 B J100 U 100 U 100 U 35.8 B 25.7 B100 U 100 U 100 U 29.9 B 100 U100 U 100 U 34.3 B 32.1 B 60.4 B100 U 100 U 100 U 55.3 B 100 U338 B 87100 121000 1210000 589000241 B J 84400 J 64400 J 1290000 J 496000 J40 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U29.8 B J 156 B J 1120 B J 3140 J 885 B J39.2 B 202 B 1180 B 3500 J 901 B50 U 50 U 2.5 B 50 U 1.5 B50 U 50 U 50 U 50 U 50 U37500 B J 241000 J 305000 J 1790000 J 84700043200 B 293000 318000 1950000 J 92800050 U 50 U 359 15.1 B 46050 U 50 U 5.8 B 50 U 5.7 B500 U 500 U 500 U 500 U 500 U500 U 500 U 500 U 500 U 500 U250 U 250 U 41.3 B 250 U 253250 U 250 U 250 U 250 U 250 U273 B 3080 55200 39000 2230001000 U 1510 14200 38200 4580030 U 30 U 26.4 B 30 U 45330 U 30 U 30 U 30 U 34.733.8 B 2050 4060 37000 1220040.7 B 2590 3790 40000 133005160 B 21000 B 25900 B 154000 776006160 B 25300 B 25900 B 167000 83800145 B 395 1290 1100 2810129 B 430 1190 1200 1710400 U 400 U 372 B 400 U 188 B400 U 400 U 185 B 14.9 B 25.6 B400 U 400 U 203 B 400 U 216 B400 U 400 U 24.1 B 400 U 33.3 B2850 B 11600 B 26700 B 48900 B 989002260 B 13000 B 21600 B 53100 10600050 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U5/1/2009 5/4/2009 5/8/2009Day 5Supply Water5/1/2009Day 145/18/2009Day 0Tioga County, PADay 1Location JPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B5/1/2009 5/4/2009 5/8/2009Day 5Supply Water5/1/2009Day 145/18/2009Day 0Tioga County, PADay 1Location J17800 B 884000 1090000 10700000 394000021300 B 1120000 1160000 11700000 4120000588 47900 56700 443000 197000 J685 J 58200 J 58600 J 477000 J 210000 J100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U1000 U 1000 U 1000 U 1000 U 1000 U1000 U 1000 U 1000 U 1000 U 1000 U500 U 500 U 23.5 B 50.3 B J 63.6 B500 U 500 U 500 U 62.5 B J 500 U50 U 50 U 209 50 U 50 U73.9 B J 76.8 B J 665 J 91 B J 133052.8 B 45.5 B 378 97.5 B J 178 B0.01 U 0.05 G U 0.086 0.5 G U 0.520.01 U 0.05 G U 0.15 0.5 G U 0.5 U0.2 U 0.056 B 0.2 U 0.043 B J 0.2 U0.2 U 0.051 B 0.2 U 0.2 U 0.2 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 2.6 J 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U1000 U 1000 U 1000 U 1000 U 2000 UNA NA NA NA NA5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U10 U 10 U 10 U 10 U 20 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U20 U 10 J B 10 J B 22 B 330100 U 100 U 100 U 100 U 200 U100 U 100 U 100 U 100 U 200 U5 U 5 U 5 U 0.99 J 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 7.8 5.8 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 3.7 J 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C5/1/2009 5/4/2009 5/8/2009Day 5Supply Water5/1/2009Day 145/18/2009Day 0Tioga County, PADay 1Location JNA NA NA NA NA5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 UNA NA NA NA NA5 U 1.3 J 5 U 5 U 2.5 J5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U5 U 5 U 5 U 5 U 10 U15 U 2.6 J 15 U 15 U 30 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 UNA NA NA NA NA9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 25 9.4 U 9.5 U49 U 1000 U 48 U 47 U 48 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 0.82 J 1.9 U 29.8 U 200 U 7.3 J 9.4 U 0.19 J9.8 U 200 U 9.6 U 9.4 U 9.5 U49 U 1000 U 48 U 47 U 48 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 4.5 J 9.4 U 0.61 J49 U 1000 U 48 U 47 U 48 U49 U 1000 U 48 U 47 U 48 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U49 U 1000 U 48 U 47 U 48 U49 U 1000 U 48 U 47 U 48 U98 U 2000 U 96 U 94 U 95 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 0.67 J2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 13 1.1 J 1 J9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U200 U 4000 U 190 U 190 U 190 U2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 4300 18 17 1.9 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 1.2 J 1.6 J B 9.69.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 1.6 J 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 0.3 J 5.3 J 130PARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 80825/1/2009 5/4/2009 5/8/2009Day 5Supply Water5/1/2009Day 145/18/2009Day 0Tioga County, PADay 1Location J9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 2.79.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 0.78 J2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U2 U 40 U 1.9 U 1.9 U 2.79.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U20 U 400 U 19 U 19 U 19 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1 J2 U 40 U 1.9 U 0.76 J 1.9 U9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 U2 U 40 U 1.9 U 1.9 U 1.9 U9.8 U 200 U 3.2 J 9.4 U 3.5 J9.8 U 200 U 9.6 U 9.4 U 9.5 U9.8 U 200 U 9.6 U 9.4 U 9.5 UNANANANANA0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.0830.048 U 0.038 J PGNA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.48 U 0.49 U NA NA 0.48 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.044 J PG0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.270.048 U 0.049 U NA NA 0.36 PG0.048 U 0.049 U NA NA 0.052 PG0.096 U 0.098 U NA NA 0.095 U1.9 U 2 U NANA1.9 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NANA0.38 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 105/1/2009 5/4/2009 5/8/2009Day 5Supply Water5/1/2009Day 145/18/2009Day 0Tioga County, PADay 1Location J0.95 U 1 U NA NA 0.95 U10 UJ NA 10 UJ 13 J 10 UJ10 UJ NA 10 UJ 10 UJ 10 UJ10 UJ NA 10 UJ 10 UJ 10 UJ10 UJ NA 10 UJ 10 UJ 10 UJ10 UJ NA10 UJ 10 UJ 10 UJ100 UJ NA 100 UJ 100 UJ 100 UJ100 UJ NA100 UJ 100 UJ 100 UJ0.15 U NA 0.15 U 10 UJ 1.5 UJ0.16 U NA 0.16 U 10 UJ 1.6 UJ0.17 U NA 0.17 U 10 UJ 1.7 JUNANANANA110PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B66.7 5 U 5 U 5 U0.01 NR U 0.01 NR U 0.01 U 0.01 U14 16.8 J 29.4 J 3.7430 650 214 30.518.9 117 185 15.81260 855 1720 22882 10200 34000 J 1670 J301 J 197 158 5.20.05 U 0.38 1.2 G U 0.05 U104 2100 5100 6301.6 2.4 1.2 G U 0.650.37 0.32 0.2 0.680.056 1.1 4.8 1.74.9 U 4.8 U 4.9 U 9.4507 J 35700 J 79500 J 6800 J21.5 J 21.6 J 6.6 B J 0.78 B J949 J 124 103 7.2116 J 311 J 245 J 91.3 J804 18600 39400 301047.2 25.2 38 5.60.097 B 0.14 0.12 0.1726 172 61 561249 63.8 140 548320 16.7 7.4 B J 10 U1.6 B 1.6 B 1.6 B 3 U6.3 7.4 6.9 6.60.011 0.01 U 0.052 0.0097 B10.4 8.8 5 U 140.05 U 0.575 0.012 0.0733311 B 420 B J 2000 U 39902000 U 166 B 205 B 2000 U16.7 B 34.9 B 33.7 B 14.1 B100 U 36.5 B 21.7 B 100 U100 U 32.3 B 28.8 B 79.8 B100 U 100 U 32.6 B 100 U1220 B 251000 893000 1050001360 B J 224000 1010000 10200040 U 40 U 40 U 40 U40 U 40 U 40 U 40 U71.4 B J 2850 3550 464 B76.4 B J 2590 4170 313 B50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U26600 B J 577000 J 1440000 J 173000 J22900 B J 493000 1590000 204000 J50 U 48.1 B 14.6 B 56750 U 50 U 6.6 B 50 U500 U 500 U 500 U 10.9 B500 U 500 U 500 U 500 U250 U 250 U 250 U 493250 U 250 U 250 U 250 U745 B 18000 33600 166000567 B 11700 34400 2680030 U 70.9 30 U 13821.2 B 35.7 30 U 30 U42 B 23600 41800 341056.3 B 20200 47800 40004320 B 52000 135000 18500 B3760 B 44800 B 150000 21900 B33.2 B 519 881 217027.5 B 440 1020 1230400 U 54.4 B 33.1 B 149 B400 U 42.7 B 34 B 400 U400 U 176 B 400 U 769400 U 33.4 B 400 U 62.1 B2750 B 35800 B 54600 8230 B2790 B 31900 B 64000 8140 B50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U50 U 50 U 50 U 50 UBradford County, PA05/07/2009 5/20/2009Day 1Day 0 Day 55/22/2009Day 146/2/2009Location KPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BBradford County, PA05/07/2009 5/20/2009Day 1Day 0 Day 55/22/2009Day 146/2/2009Location K67800 6630000 11700000 92200080700 5830000 J 13200000 J 11000001310 117000 357000 39000899 J E 99700 J 390000 J 46100 J100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U1000 U 1000 U 1000 U 23 B1000 U 1000 U 1000 U 1000 U22.3 B J 38.5 B 23.9 B 119 B21.2 B J 39.4 B 39.2 B 500 U50 U 50 U 50 U 50 U99.7 B J 198 B J 147 B J 517 J76.1 B J 109 B J 172 B J 75.7 B0.5 G U 0.1 G U 0.17 B 0.05 G U0.5 G U 0.1 G U 0.17 B 0.047 B0.052 B J 0.2 U 0.2 U 0.2 U0.46 B J 0.2 U 0.2 U 0.2 U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U42 14 7.7 3.9 J5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U20 7.7 5.3 2.8 J5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U1000 U 1000 U 1000 U 1000 UNA NA NA NA5U 5U 5U 5U5U 5U 5U 5U10 U 10 U 10 U 10 U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U6.7 J B 5.9 J 6.9 J 20 U100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U5 U 5 U 5 U 1.5 J5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U1.7 J 5 U 5 U 5 U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U3.9 J 5 U 5 U 5 U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5 U 5 U 5 U 2.3 JPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CBradford County, PA05/07/2009 5/20/2009Day 1Day 0 Day 55/22/2009Day 146/2/2009Location KNA NA NA NA5U 5U 5U 5U5U 5U 5U 5UNA NA NA NA5 U 5 U 5 U 1.6 J5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U5U 5U 5U 5U35 4.8 J 3 J 3.7 J9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 UNA NA NA NA9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U50 U 48 U 47 U 50 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U50 U 48 U 47 U 50 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 0.41 J50 U 48 U 47 U 50 U50 U 48 U 47 U 50 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U50 U 48 U 47 U 50 U50 U 48 U 47 U 50 U99 U 95 U 94 U 100 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U200 U 190 U 190 U 200 U1.1 J 1.9 U 1.9 U 2 U6.9 1.9 U 1.9 U 2 U11 1.9 U 1.9 U 2 U7.4 1.9 U 1.9 U 2 U6.7 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 9.1 J9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U15 B 1.8 J 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U1.7 J 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U12 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 0.73 J9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 5 J 9.4 U 10 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Bradford County, PA05/07/2009 5/20/2009Day 1Day 0 Day 55/22/2009Day 146/2/2009Location K9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U10 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U20 U 19 U 19 U 20 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 U2 U 1.9 U 1.9 U 2 U9.9 U 9.5 U 9.4 U 1509.9 U 9.5 U 9.4 U 10 U9.9 U 9.5 U 9.4 U 10 UNANANANA0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.49 U NA NA 0.48 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.048 U0.049 U NA NA 0.036 J PG0.049 U NA NA 0.10.049 U NA NA 0.048 U0.098 U NA NA 0.097 U2U NANA1.9 U0.39 U NA NA 0.39 U0.39 U NA NA 0.39 U0.39 U NA NA 0.39 U0.39 U NA NA 0.39 U0.39 U NA NA 0.39 U0.39 U NA NA 0.39 U0.39 U NANA0.39 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Bradford County, PA05/07/2009 5/20/2009Day 1Day 0 Day 55/22/2009Day 146/2/2009Location K0.95 U NA NA 0.95 U10 UJ 10 UJ 10 UJ 10 UJ10 UJ 10 UJ 10 UJ 10 UJ10 UJ 10 UJ 10 UJ 10 UJ10 UJ 10 UJ 10 UJ 10 UJ10 UJ 10 UJ 10 UJ 10 UJ100 UJ 100 UJ 100 UJ 100 UJ220 J 130 J 100 UJ 100 UJ50 UJ 42 J 39 J 10 UJ50 UJ 20 UJ 10 UJ 10 UJ50 UJ 20 UJ 10 UJ 10 UJ2300 170 400 110PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 11.4 NA NA 2000.01 U 0.0097 B 0.01 U 0.01 U 0.01 U0.25 J 1.5 J 173 192 268 J2 U 137 36.3 103 10.22 G U 10 G U NA NA 119010 U 490 10700 7600 91804.1 B 29.9 B NA NA 1510001.4 84.3 77 33.1 50.05 U 0.009 B 2.5 G U 2.5 G U 2.5 G U18 26 NA NA 950000.24 B 2.5 U 2.5 G U 2.5 G U 2.5 G U0.24 0.24 0.01 B 0.049 B J 0.110.21 B 2.5 G U NA 25.9 55.84.6 U 33.2 NA NA 7.454.8 J 177 J NA NA 710000 J3.8 B 2.9 B 50 G U 50 G U 50 G U1.8 86.6 2.2 3.7 1.26.2 J 9.6 J NA NA 26.1 J51 371 NA NA 2280002.2 B 31.3 158 178 1990.1 U 0.096 B 1.4 0.1 U 2.24 U 110 NA NA 40.84.3 254 NA NA 67.810 U 12.5 10 U 10 U 10 U1.6 B 3 U 3 U 3 U 3 U7.1 6.2 5.9 7.2 5.80.01 U 0.0069 B 0.007 B 0.29 0.006 B6 12 24.4 11.6 10.40.05 U 0.05 0.241 0.291 0.198122 B J 180 B J 165 B 131 B 158 B160 B 239 B 289 B J 188 B J 210 B J14.6 B 100 U 13.9 B 17.3 B 100 U100 U 100 U 16.9 B 20.9 B 15.7 B100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U271 B 579 B 1450000 1730000 1970000274 B 621 B 1430000 1760000 199000040 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U2000 U 2000 U 12000 10500 100002000 U 2000 U 11800 11000 974050 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 1.5 B 1.5 B4880 B J 6690 B J 19700000 J 23500000 J 26400000 J3690 B 6080 B 19700000 J 23800000 J 26200000 J50 U 50 U 15.7 B 50 U 50 U50 U 50 U 50 U 50 U 50 U500 U 500 U 5000 U 5000 U 5000 U500 U 500 U 5000 U 5000 U 5000 U250 U 44.5 B 255 78.9 B 250 U250 U 250 U 81.1 B 57.7 B 250 U605 B 497 B 67200 53100 61000543 B 460 B 37600 44800 5330030 U 30 U 30 U 30 U 30 U30 U 30 U 30 U 30 U 30 U500 U 500 U 129000 137000 155000500 U 28.1 B 126000 J 154000 J 158000 J1080 B 1250 B 1320000 1550000 18000001440 B 1460 B 1310000 1600000 1740000134 B 127 B 5960 7040 8560127 B 130 B 5850 7170 8420400 U 400 U 48.2 B 400 U 400 U400 U 400 U 34.7 B J 400 U 400 U400 U 19.5 B 400 U 400 U 400 U400 U 400 U 400 U 400 U 400 U50000 U 50000 U 923000 849000 972000 E50000 U 50000 U 1000000 1010000 1010000 E50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 UMcKean County, PADay 56/10/20095/19/2009 6/19/20096/6/2009Supply Water5/19/2009Day 14Day 1Day 0Location MPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BMcKean County, PADay 56/10/20095/19/2009 6/19/20096/6/2009Supply Water5/19/2009Day 14Day 1Day 0Location M4200 B 32600 B 20600000 17200000 232000003600 B J 34200 B J 31500000 31300000 30400000352 B 768 4330000 4830000 5570000 E340 B J 816 J 4280000 J 4920000 J 5350000 J E100 U 100 U 27.2 B 100 U 100 U100 U 100 U 100 U 100 U 100 U1000 U 1000 U 1000 U 1000 U 1000 U1000 U 1000 U 1000 U 1000 U 1000 U500 U 500 U 500 U 500 U 500 U500 U 29.8 B 500 U 500 U 500 U50 U 50 U 50 U 50 U 50 U56.7 B J 50.2 B J 391 J 270 J 223 J41.1 B J 40.6 B J 314 J 240 J 143 B J0.01 U 0.01 G U 0.5 G U 0.5 G U 1 G U0.01 U 0.05 G U 0.5 G U 0.5 G U 1 G U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 5 U 1.6 J 4 J 0.98 J5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 5 U 1.2 J 3.3 J 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U1000 U 1000 U 1000 U 1000 U 1000 UNA NA NA NA NA5U 5U 5U 5U 5U5 U 3.6 J 5 U 5 U 5 U10 U 10 U 10 U 10 U 10 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U20 U 20 U 21 18 J 18 J100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U5 U 5 U 3.5 J 3.2 J 6.25U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5 U 5 U 5 U 0.63 J 5 U5 U 5 U 5 U 0.53 J 5 U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CMcKean County, PADay 56/10/20095/19/2009 6/19/20096/6/2009Supply Water5/19/2009Day 14Day 1Day 0Location MNA NA NA NA NA5U 5U 5U 5U 5U5U 5U 5U 5U 5UNA NA NA NA NA5 U 5 U 3.8 J 4.8 J 3.4 J5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U5U 5U 5U 5U 5U15 U 15 U 3.2 J 6 J 6.2 J9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 UNA NA NA NA NA9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U48 U 50 U 48 U 47 U 48 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 0.28 J 0.26 J 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U48 U 50 U 48 U 47 U 48 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 0.69 J 9.6 U48 U 50 U 48 U 47 U 48 U48 U 50 U 48 U 47 U 48 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U48 U 50 U 48 U 47 U 48 U48 U 50 U 48 U 47 U 48 U96 U 100 U 95 U 94 U 96 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 0.8 J 9.6 U9.6 U 10 U 2.2 J 2.1 J 2 J9.6 U 10 U 9.5 U 9.4 U 9.6 U190 U 200 U 190 U 190 U 190 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U6 J 10 U 2.8 J 9.4 U 2.5 J9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 2.4 J B 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 1.3 J 9.4 U 9.6 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082McKean County, PADay 56/10/20095/19/2009 6/19/20096/6/2009Supply Water5/19/2009Day 14Day 1Day 0Location M9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U2.2 J 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U19 U 20 U 19 U 19 U 19 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U1.9 U 2 U 1.9 U 1.9 U 1.9 U9.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 U1.9 U 2 U 1.9 U 1.9 U 1.9 U2.6 J 2 J 140 100 949.6 U 10 U 9.5 U 9.4 U 9.6 U9.6 U 10 U 9.5 U 9.4 U 9.6 UNANANANANA0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.48 U 0.49 U NA NA 0.48 U0.048 U 0.049 U NA NA 0.026 J0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.05 NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.8 PG 0.84 PG NA NA 0.048 U0.048 U 0.049 U NA NA 0.048 U0.095 U 0.098 U NA NA 0.096 U1.9 U 2 U NANA1.9 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NA NA 0.38 U0.38 U 0.39 U NANA0.38 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10McKean County, PADay 56/10/20095/19/2009 6/19/20096/6/2009Supply Water5/19/2009Day 14Day 1Day 0Location M0.95 U 0.97 U NA NA 1 U10 UJ 20 UJ 10 UJ 10 UJ 10 UJ10 UJ 20 UJ 10 UJ 10 UJ 10 UJ10 UJ 20 UJ 10 UJ 10 UJ 10 UJ10 UJ 20 UJ 23 J 21 J 16 J10 UJ 20 UJ 10 UJ 10 UJ 10 UJ100 UJ 200 UJ 100 UJ 100 UJ 100 U100 UJ 200 UJ 100 UJ 100 UJ 100 U1 U 100 UJ 10 UJ 500 UJ 10 UJ1 U 100 UJ 10 UJ 500 UJ 10 UJ1 U 100 UJ 10 UJ 500 UJ 10 UJ57 2300 1100 1200 52000PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 48.7 4730.01 U 0.01 NR U 0.01 U 0.01 U10 52 135 237 J924 606 1520 72520 G U 69.8 885 J 8722420 1480 7390 10000 J1060 7860 86800 98300 J558 J 271 240 6955 G U 2.5 G U 2.5 G U 2.5 G U570 25000 36000 540005 G U 2.5 G U 2.5 G U 2.5 G U0.1 0.18 0.1 U 0.1 U5 G U 6.7 19.9 J 25.9255 4.6 U 40.7 17.54000 J 30700 J 261000 J 428000 J100 G U 50 G U 50 G U 50 G U575 J 308 237 509 J66.1 J 114 J 94.2 J 95.1 J2670 17400 125000 18600089.9 88.8 147 1800.5 21.8 2.3 0.038 B5290 4 U 302 324505 152 54.6 24410 U 21.5 5.2 B 1.9 B3 U 3 U 3.2 3 U7.2 6.5 6.5 6.60.77 J 0.036 J 0.15 J 0.1347.2 26.8 16.8 73.60.05 U 0.198 0.0897 4.601030 B 1120 B 536 B 845 B162 B J 274 B 172 B J 912 B100 U 15.8 B 100 U 48.8 B J100 U 15 B 100 U 45 B J100 U 48 B 100 U 76.6 B100 U 28 B 100 U 86.5 B72200 387000 13900000 12500000 J62300 447000 12700000 1360000040 U 40 U 40 U 40 U40 U 40 U 40 U 40 U1190 B 808 B 3570 2520 J1310 B 944 B 3200 2760 J50 U 50 U 50 U 3.1 B50 U 50 U 50 U 3.3 B123000 J 676000 J 9250000 J 10300000120000 J 800000 J 8200000 J 1120000017.3 B 37.5 B 33.4 B 31.2 B50 U 12.9 B 27.7 B 19.4 B500 U 500 U 25000 U 5000 U500 U 500 U 25000 U 5000 U79.4 B 250 U 250 U 54.8 B34.1 B 250 U 250 U 250 U7400 20900 J 43500 77500954 B 18000 38400 5870019.4 B 30 U 30 U 60 U30 U 30 U 30 U 60 U1800 14200 132000 147000 J1930 17300 125000 16200014700 B 65700 691000 79400014800 B 76400 610000 858000288 760 J 5550 7100196 823 4960 763050.6 B J 25.9 B 400 U 400 U58.4 B 24.1 B 400 U 400 U400 U 48.3 B 400 U 800 U400 U 39.5 B 400 U 800 U7840 B 33500 B 353000 2330006850 B 39900 B 284000 25300050 U 50 U 50 U 34 B50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U50 U 50 U 50 U 50 UDay 07/1/2009 7/1/2009Day 1Susquehanna CountyDay 5 Day 147/6/2009 07/15/2009Location OPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 07/1/2009 7/1/2009Day 1Susquehanna CountyDay 5 Day 147/6/2009 07/15/2009Location O589000 3920000 34100000 36800000 J658000 4670000 30900000 3910000027000 J E 196000 J 2960000 J 3520000 J28200 J E 233000 J 2660000 J 3580000 J100 U 100 U 100 U 200 U29.5 B 100 U 38 B 200 U1000 U 1000 U 1000 U 1000 U1000 U 1000 U 1000 U 1000 U500 U 33.8 B 500 U 126 B500 U 48.6 B 500 U 152 B50 U 50 U 33.4 B 50 U1610 E 244 211 229 J924 287 J 183 B 127 B J0.1 U 0.1 U 2 G U 13.20.05 U 0.1 U 2 G U 2 U0.2 U 0.2 U 0.2 U 0.2 U0.17 B 0.2 U 0.2 U 0.2 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U67 59 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U7.7 J 6.7 J 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U10000 U 5000 U 1000 U 1000 UNA NA NA NA50 U 25 U 5 U 5 U50 U 17 J 5 U 5 U100 U 50 U 10 U 10 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U130 J 69 J 20 U 20 U1000 U 500 U 100 U 100 U1000 U 500 U 100 U 100 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U820 720 0.5 J 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 07/1/2009 7/1/2009Day 1Susquehanna CountyDay 5 Day 147/6/2009 07/15/2009Location ONA NA NA NA50 U 25 U 5 U 5 U50 U 25 U 5 U 5 UNA NA NA NA19 J 25 U 0.94 J 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U50 U 25 U 5 U 5 U46 J 26 J 15 U 15 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 UNA NA NA NA190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U940 U 470 U 49 U 4700 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U260 52 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U940 U 470 U 49 U 4700 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U940 U 470 U 49 U 4700 U940 U 470 U 49 U 4700 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U940 U 470 U 49 U 4700 U940 U 470 U 49 U 4700 U1900 U 940 U 98 U 9400 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U3800 U 1900 U 200 U 19000 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U190 U 94 U 2.5 J 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 07/1/2009 7/1/2009Day 1Susquehanna CountyDay 5 Day 147/6/2009 07/15/2009Location O190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U38 U 19 U 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U380 U 190 U 20 U 1900 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U38 U 3.5 J 2 U 190 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 U38 U 19 U 2 U 190 U190 U 94 U 1.1 J 940 U190 U 94 U 9.8 U 940 U190 U 94 U 9.8 U 940 UNANANANA0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.11 PG NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.51 U NA NA 0.48 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.051 U NA NA 0.048 U0.065 PG NA NA 0.048 U0.051 U NA NA 0.048 U0.1 U NA NA 0.095 U2U NANA1.9 U0.41 U NA NA 0.38 U0.41 U NA NA 0.38 U0.41 U NA NA 0.38 U0.41 U NA NA 0.38 U0.41 U NA NA 0.38 U0.41 U NA NA 0.38 U0.41 U NANA0.38 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 07/1/2009 7/1/2009Day 1Susquehanna CountyDay 5 Day 147/6/2009 07/15/2009Location O1 U NA NA 4.8 U20 UJ 10 UJ 10 UJ 10 UJ20 UJ 10 UJ 10 UJ 10 UJ120 J 230 J 110 J 39 J20 UJ 10 UJ 10 UJ 10 UJ20 UJ 10 UJ 10 UJ 10 UJ200 UJ 200 UJ 100 UJ 100 UJ200 UJ 200 UJ 100 UJ 100 UJ50 UJ 1 U 1 U 20 UJ50 UJ 1 U 1 U 20 UJ50 UJ 1 U 1 U 20 UJ200 200 300 800PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 5 U 63.2 6980.01 NR U 0.01 NR U 0.01 NR U 0.01 U 0.01 U1.8 16.1 65.4 102 J 215 J121 184 144 98.1 1214.5 87.9 310 720 10901770 1080 1850 14000 J 708078.1 J 8960 J 33500 71500 131000467 341 J 160 25.8 18.40.25 G U 2.5 G U 2.5 G U 2.5 G U 2.5 G U88 2200 9100 32000 900000.25 G U 2.5 G U 2.5 G U 2.5 G U 2.5 G U0.33 0.51 0.055 B J 0.025 B 0.069 B0.25 G U 6.5 13.2 19.9 84.55 U 4.8 U 4.6 U 4.8 U 6.4426 J 39800 J 130000 J 249000 J 46400045.3 J 31.8 B J 50 G U 50 G U 50 G U410 J 142 J 46.5 J 24 J 34.149 J 338 J 140 J 113 J 52.9 J311 16600 38500 120000 20700011.9 24.3 61.7 83.1 1280.034 B 0.16 0.097 B 0.055 B J 1 G U120 9.2 95 62 53420.7 11.7 68.2 10.5 26492.4 21.2 72.1 10 U 10 U4.8 3.2 2.4 B 3 U 3 U6.9 7.5 6.6 6.2 5.90.033 J 0.0087 B J 0.018 J 0.01 U 0.01 U12.0 12.4 6.4 14.8 14.80.501 0.05 U 0.133 0.836 0.8362000 U 395 B 246 B 640 B 271 B J2000 U 190 B 173 B J 737 B 181 B J100 U 24.7 B 100 U 37.2 B J 100 U100 U 25.2 B 100 U 38.5 B J 100 U100 U 100 U 100 U 46.4 B 100 U100 U 100 U 100 U 65 B 100 U227 B 37600 415000 1700000 J 3440000294 B 43800 401000 1730000 256000040 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U2000 U 5110 9070 10400 J 1360033.5 B 5840 8500 10800 J 10200 J50 U 50 U 50 U 1.4 B 2.6 B J50 U 50 U 50 U 1.9 B 50 U27800 B J 641000 J 3120000 J 8790000 1800000026800 B J 728000 J 2890000 J 8730000 1340000050 U 50 U 50 U 50 U 14.8 B50 U 50 U 50 U 50 U 50 U500 U 500 U 500 U 1000 U 5000 U500 U 500 U 500 U 1000 U 5000 U39.7 B 250 U 28.9 B 250 U 56.6 B35.6 B 250 U 250 U 250 U 250 U429 B J 5830 J 37500 72700 3210001000 U 5000 30400 72900 22000030 U 14.5 B 30 U 60 U 5030 U 14.5 B 30 U 60 U 15.7 B500 U 12300 29300 68700 J 100000500 U 14300 27000 69100 74500 J6400 B 59800 331000 938000 16900006090 B 67100 307000 963000 12900008.2 B J 752 J 2300 4790 10200150 U 826 2130 4890 7700400 U 21.1 B 20.6 B J 14.8 B 17.5 B400 U 24.1 B 400 U 400 U 400 U400 U 400 U 400 U 800 U 49.9 B400 U 400 U 400 U 800 U 36.5 B50000 U 45400 B 187000 265000 8580004110 B 53500 163000 267000 61100050 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 44.2 B 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 UDay 90Day 57/1/2009 10/27/20097/15/2009Day 147/6/2009Day 0 Day 16/30/2009Westmoreland County, PALocation QPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 90Day 57/1/2009 10/27/20097/15/2009Day 147/6/2009Day 0 Day 16/30/2009Westmoreland County, PALocation Q63200 5400000 1.7E+07 30800000 J 4970000067900 5960000 1.6E+07 31300000 36800000 J292 B J 86200 J 422000 J 1310000 J 2860000 J254 B J 98800 J 396000 J 1300000 J 2100000 J100 U 100 U 100 U 200 U 100 U100 U 100 U 100 U 200 U 100 U1000 U 1000 U 1000 U 1000 U 1000 U1000 U 1000 U 22.4 B 1000 U 1000 U500 U 44.5 B 500 U 139 B 500 U500 U 35.4 B 500 U 113 B 500 U50 U 50 U 50 U 50 U 50 U37.7 B 78.6 B 156 B 144 B J 247000 J69 B J 100 B J 159 B 137 B J 182000 J0.5 G U 0.5 G U 0.1 G U 0.25 G U 1 G U0.5 G U 0.5 G U 0.1 G U 0.25 U 1 G U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U0.095 B 0.2 U 0.2 U 0.2 U 0.2 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 4.9 J5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U1000 U 1000 U 1000 U 10000 U 1000 UNA NA NA NA NA5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U10 U 10 U 10 U 100 U 10 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U28 16 J 42 520 20 U100 U 100 U 100 U 1000 U 100 U100 U 100 U 100 U 1000 U 100 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 4 J 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 90Day 57/1/2009 10/27/20097/15/2009Day 147/6/2009Day 0 Day 16/30/2009Westmoreland County, PALocation QNA NA NA NA NA5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 UNA NA NA NA NA5 U 5 U 1.2 J 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U15 U 15 U 4.4 J 150 U 15 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 UNA NA NA NA NA9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U48 U 48 U 47 U 47 U 47 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U48 U 48 U 47 U 47 U 47 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 0.2 J 9.4 U 9.4 U48 U 48 U 47 U 47 U 47 U48 U 48 U 47 U 47 U 47 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U48 U 48 U 47 U 47 U 47 U48 U 48 U 47 U 47 U 47 U95 U 95 U 94 U 94 U 94 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 1.2 J 0.34 J 0.33 J 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U190 U 190 U 190 U 190 U 190 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 4.4 J 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U10 9.5 U 9.4 U 3.7 J 2 J9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.1 J 9.5 U 9.4 U 9.4 U 9.4 UPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 90Day 57/1/2009 10/27/20097/15/2009Day 147/6/2009Day 0 Day 16/30/2009Westmoreland County, PALocation Q9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U19 U 19 U 19 U 19 U 19 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U1.9 U 1.9 U 1.9 U 1.9 U 1.9 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 U9.5 U 9.5 U 9.4 U 9.4 U 9.4 UNANANANANA0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.17 PG NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.26 NA NA 0.047 U 0.048 U0.48 U NA NA 0.47 U 0.48 U0.072 PG NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.048 U NA NA 0.047 U 0.048 U0.12 NA NA 0.047 U 0.048 U0.26 PG NA NA 0.047 U 0.048 U0.095 U NA NA 0.094 U 0.096 U1.9 U NANA1.9 U 1.9 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NA NA 0.38 U 0.4 U0.38 U NANA0.38 U 0.4 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 90Day 57/1/2009 10/27/20097/15/2009Day 147/6/2009Day 0 Day 16/30/2009Westmoreland County, PALocation Q0.95 U NA NA 0.95 U 0.98 U110 J 38 J 28 J 20 J 20 J20 UJJ 5 UJ 10 UJ 10 UJ 10 UJ20 UJJ 5 UJ 10 UJ 10 UJ 10 UJ20 UJ 5 UJ 10 UJ 10 UJ 10 UJ20 UJ 5 UJ 10 UJ 10 UJ 10 UJ200 UJ 100 UJ 100 UJ 100 UJ 100 UJ200 UJ 100 UJ 100 UJ 100 UJ 100 UJ20 UJ 1 U 33 33 J 33 J20 UJ 5 UJ 1 U 10 UJ 10 UJ20 UJ 1 U 1 U 10 UJ 10 UJ300 100 120 600 600PARAMETERUNITS PQL US EPA MethodConventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM202340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 CTotal and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B5 U 5 U 5 U 22.9 90.20.01 U 0.01 U 0.01 U 0.01 U 0.01 U0.52 J 3 J 2.8 J 44.8 J 128 J2 U 2220 1440 218 9900.2 U 0.2 U 0.2 U 306 60218.4 J 4810 J 3420 J 1810 2190028.1 58.5 64.2 36800 J 79000 J2.3 J 906 J 657 J 217 2140.05 U 0.05 U 0.077 1.2 G U 2.5 G U156 156 156 15400 340001.8 2.6 2.7 1.2 G U 0.43 B3 3.1 2.8 1.2 J 0.410.05 U 0.06 0.045 B 10.3 2.5 G U4.6 U 158 13.7 7.5 36.2466 J 480 J 479 J 116000 J 266000 J8.4 32.6 17.7 2.4 B J 33.5 B J2.7 931 672 104 15088.8 J 109 J 123 J 175 J 74.2 J277 280 680 58300 1240003 U 42.3 47.5 75.9 1160.1 U 0.082 B 0.037 B 0.053 B 0.035 B4 U 200 142 62 511.7 308 300 293 46010 U 3.5 B 6.6 B 10 U 7.4 B3.2 3 U 3 U 3 U 1.6 B7 7.2 7.9 6.4 6.60.0065 B 0.044 0.048 0.021 0.111.2 20 15.2 38.0 9.200.0969 0.05 U 0.0613 0.189 0.0945177 B 623 B 507 B 152 B 2000 U2000 U 203 B 165 B 2000 U 2000 U15.4 B 16.8 B 100 U 31.3 B 49.1 B100 U 100 U 13.5 B 24.1 B 100 U100 U 100 U 100 U 100 U 100 U100 U 100 U 100 U 100 U 100 U840 B 410 B 332 B 652000 1500000734 B 346 B 240 B 712000 151000040 U 40 U 40 U 40 U 40 U40 U 40 U 40 U 40 U 40 U18.9 B 17.8 B 18.1 B 7920 1360015.8 B 13.8 B 14.2 B 8950 140001.7 B 2.1 B 2.2 B 3.8 B 3.9 B2 B 50 U 1.3 B 50 U 3 B40100 B J 35200 B J 35200 B J 4080000 J 11800000 J37500 B J 36000 B J 37800 B J 4510000 J 12000000 J50 U 50 U 7.5 B 50 U 10.2 B50 U 50 U 50 U 50 U 50 U500 U 4.4 B 5.7 B 500 U 2500 U500 U 5.4 B 6.2 B 500 U 2500 U250 U 109 B 43.9 B 71.4 B 35.3 B250 U 123 B 37.2 B 55 B 38.8 B394 B 1790 6490 77900 732001000 U 726 B 1670 34700 3400030 U 30 U 30 U 21.2 B 21.7 B30 U 30 U 30 U 30 U 30 U500 U 42 B 500 U 34800 9490042.1 B 31.1 B 500 U 37800 931018300 B 15700 B 16000 B 373000 98700017000 B 16200 B 17300 B 412000 10000008.7 B 37.9 B 146 B 1850 2670150 U 30.5 B 119 B 2030 2680400 U 400 U 14.2 B 39.1 B 400 U400 U 400 U 400 U 26.8 B 400 U400 U 400 U 16.7 B 19 B 400 U400 U 400 U 400 U 400 U 400 U2930 B 2420 B 2690 B 301000 10200003090 B 2590 B 3000 B 354000 105000050 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 U50 U 50 U 50 U 50 U 50 UDay 14Day 0 Day 5Day 18/29/2009 9/8/20098/25/20098/25/2009 8/25/2009Supply WaterCentre County, PALocation SPARAMETERUNITS PQL US EPA MethodSodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260BDay 14Day 0 Day 5Day 18/29/2009 9/8/20098/25/20098/25/2009 8/25/2009Supply WaterCentre County, PALocation S37700 B 60800 63800 16400000 3270000035300 B 71800 69200 18000000 33000000723 E 597 580 1560000 5020000653 J E 624 J 594 J 1710000 J 4930000 J100 U 100 U 100 U 24.6 B 100 U100 U 100 U 100 U 100 U 100 U1000 U 1000 U 1000 U 1000 U 20.7 B1000 U 1000 U 1000 U 1000 U 1000 U500 U 500 U 500 U 500 U 500 U500 U 500 U 500 U 500 U 500 U50 U 50 U 50 U 50 U 50 U172 B J 164 B J 138 B J 343 J 604 J156 B J 140 B J 73.8 B J 238 J 673 J0.01 U 0.0078 B 0.05 G U 0.5 G U 0.5 G U0.01 U 0.05 G U 0.05 G U 0.42 B G 0.25 G U0.2 U 0.2 U 0.2 U 0.2 U 0.2 U0.2 U 0.2 U 0.2 U 0.049 B J 0.2 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 6.55 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 1.5 J5 U 11 33 50 U 3.9 J5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 2.8 J 13 50 U 1.1 J5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U1000 U 1000 U 1000 U 10000 U 1000 UNA NA NA NA NA5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U10 U 10 U 10 U 100 U 10 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U20 U 5.4 J 14 J 1300 31100 U 100 U 100 U 1000 U 100 U100 U 100 U 100 U 1000 U 100 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 0.81 J 1.8 J 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 1.8 J 50 U 2.8 J5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 28 J 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 UPARAMETERUNITS PQL US EPA Methodtert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDay 14Day 0 Day 5Day 18/29/2009 9/8/20098/25/20098/25/2009 8/25/2009Supply WaterCentre County, PALocation SNA NA NA NA NA5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 UNA NA NA NA NA5 U 1.6 J 3.8 J 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U5 U 5 U 5 U 50 U 5 U15 U 5.4 J 16 150 U 15 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 UNA NA NA NA NA9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U47 U 47 U 47 U 470 U 48 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U47 U 47 U 47 U 470 U 48 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 1.9 J 9.5 U47 U 47 U 47 U 470 U 48 U47 U 47 U 47 U 470 U 48 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U47 U 47 U 47 U 470 U 48 U47 U 47 U 47 U 470 U 48 U94 U 94 U 94 U 940 U 95 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U190 U 190 U 190 U 1900 U 190 U1.9 U 1.9 U 1.9 U 19 U 1.2 J1.9 U 1.9 U 1.9 U 19 U 1.1 J1.9 U 1.9 U 1.9 U 19 U 1 J1.9 U 1.9 U 1.9 U 19 U 1.2 J1.9 U 1.9 U 1.9 U 19 U 0.91 J9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U1.9 U 1.9 U 1.9 U 19 U 1.9 U1.9 J B 14 9.4 U 94 U 7.5 J B9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.1 J9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 2.39.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 7.7 J B 2.6 J B9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U0.6 J 2 J 9.4 U 94 U 1.5 JPARAMETERUNITS PQL US EPA MethodDi-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082Day 14Day 0 Day 5Day 18/29/2009 9/8/20098/25/20098/25/2009 8/25/2009Supply WaterCentre County, PALocation S9.4 U 9.4 U 9.4 U 94 U 9.3 J9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.7 J9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.3 J1.9 U 2 1.9 U 19 U 1.4 J1.9 U 1.9 U 1.9 U 19 U 1 J1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 2.49.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 1.9 U 1.9 U 19 U 1.9 U1.9 U 1.9 U 1.9 U 19 U 1.7 J9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U19 U 19 U 19 U 190 U 19 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 3.4 3.5 19 U 1.3 J1.9 U 1.9 U 1.9 U 19 U 1.9 U9.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 U1.9 U 0.76 J 0.89 J 19 U 1.1 J9.4 U 70 18 530 2809.4 U 9.4 U 9.4 U 94 U 9.5 U9.4 U 9.4 U 9.4 U 94 U 9.5 UNANANANANA0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.47 U 0.47 U NA NA 0.49 U0.047 U 0.047 U NA NA 0.048 J PG0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.50.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.047 U 0.041 J NA NA 0.049 U0.051 0.063 NA NA 0.049 U0.047 U 0.047 U NA NA 0.049 U0.094 U 0.094 U NA NA 0.098 U1.9 U 1.9 U NANA2 U0.38 U 0.38 U NA NA 0.39 U0.38 U 0.38 U NA NA 0.39 U0.38 U 0.38 U NA NA 0.39 U0.38 U 0.38 U NA NA 0.39 U0.38 U 0.38 U NA NA 0.39 U0.38 U 0.38 U NA NA 0.39 U0.38 U 0.38 U NANA0.39 UPARAMETERUNITS PQL US EPA MethodOrganophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015AcidsAcetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10Day 14Day 0 Day 5Day 18/29/2009 9/8/20098/25/20098/25/2009 8/25/2009Supply WaterCentre County, PALocation S0.94 U 0.95 U NA NA 0.98 U10 U 310 150 J 140 J 83 J10 U 20 U 20 UJ 10 UJ 10 UJ10 U 20 U 20 UJ 10 UJ 10 UJ10 U 20 U 20 UJ 10 UJ 10 UJ10 U 20 U 20 UJ 10 UJ 10 UJ100 U 200 U 200 UJ 100 UJ 100 UJ100 U 240 200 UJ 150 J 110 J1 U 50 U 1.4 5.8 J 6.6 J1 U 50 U 1 U 1 U 2 UJ1 U 50 U 1 U 2 UJ 2 UJ15 150 75 600 600