p.1 

RCRA Box 1883 

Prepped by Ollie Stewart 

Document Number: 

91) ll-B-253 

Docket Number: 

A-90-19 

Printed 12/3/2008 10:42:16 AM Sheet 91 of 171 
P ^ 

RADIAN 

CORPORATIO N 

MEMORANDUM 

OATE: September 1, 1991 

TO: Project Fil e 6.3 

FROM: Thomas R. Olse n 

A-90-19 

ll-B-253 

\^0 

SUBJECT: Data Used to Develop the HON Proc 

The purpose of this memorandum is to present the sources and 

raw data used to develop model product processes for HON process 

vents. The models were used in developing national impacts and 

control cost impacts. Vent stream information contained in the 

industry profiles developed in the air oxidation, reactors, and' 

distillation NSPS BIDs1'

4 was reviewed and updated by adding new 

stream characteristics based on available information. The SOCMI 

NSPS BID data for air oxidation is presented in Attachment A. 

The SOCMI air oxidation data summarized from the Survey Reports 

.5-14 

on Atmospheric Emissions From the Petrochemical Industry IS 

presented in Attachment B. The SOCMI NSPS BID data for 

distillation and reactors is presented in Attachments C and D, 

respectively. The industry profiles were developed to represent 

total VOC emissions from SOCMI processes. The survey report and 

the Enviroscience reports, which were the original information 

sources for the profiles development, were reviewed to obtain the 

stream SOCMI/HAP composition and the production capacity of each 

plant represented by a profile stream. Radian added to or 

updated each profile using SOCMI/HAP information from existing 

sources, including information gathered under the authority of 

Section 114 of the Clean Air Act, trip reports, and source 

assessment documents. 

At this point, each profile was updated and the HAP to total 

VOC ratio and the production capacity for the majority of the 

vent streams were identified. Some vent streams did not contain 

information on HAP's. These entries were not eliminated from the 

PVDB (htni01)(ls) 

Progress Center/3200 E. Chapel Hill Rd./Nelson Hwy./P.O. Box 13000/Research Triangle Park, N.C. 27709/(919)541-9100 
P.3 

profile because total VOC emissions are assumed to be similar for 

all processes represented under each profile. For those streams 

without a HAP to total VOC ratio, an average ratio was developed 

for air oxidation, reactors, and distillation profiles. This 

average ratio was assigned to the streams without a specific 

ratio to estimate the HAP emissions from those streams. 

The level of effort necessary to quantify individual HAP 

emissions from streams with multiple HAP composition exceeded the 

benefit of identifying the multiple HAP emissions. The total VOC 

content of vent streams is included in the profiles. Radian used 

the appropriate HAP to VOC ratio factor to quantify total HAP 

emissions. 

cc: Les Evans, EPA/CPB 

Bart Ferrero, Radian 

Bennett King, Radian 

Project File 6.3 (M. Haley) 

PVDB (htmOD(ls) 
P.4 

r 

_\ 

# 

REFERENCES 

1. Reactor Processes in Synthetic Organic Chemical 

Manufacturing Industry - Background Information for Proposed 

Standard. U. S. Environmental Protection Agency. Research 

Triangle Park, NC. Publication No. EPA-450/3-90-016a. 

June 1990. p. 3-1. 

2. Air Oxidation Processes in Synthetic Organic Chemical 

Manufacturing Industry - Background Information for Proposed 

Standard. U. S. Environmental Protection Agency. Research 

Triangle Park, NC. Publication No. EPA-450/3-82-001a. 

October 1983. 

3. Distillation Operations in Synthetic Organic Chemical 

Manufacturing Industry - Background Information for Proposed 

Standard. U. S. Environmental Protection Agency. Research 

Triangle Park, NC. Publication No. EPA-450/83-005a. 

December 1983. pp. 3-8 to 3-11. 

4. IT Enviroscience. Emissions Control Options for the 

Synthetic Organic Chemicals Manufacturing Industry. 

Prepared for U. S. Environmental Protection Agency, OAQPS. 

July 1980, EPA Contract Number 68-02-2577. 

5. Engineering and Cost Study of Air Pollution Control for the 

Petrochemical Industry, Volume 2: Acrylonitrile 

Manufacture. U. S. Environmental Protection Agency. 

Research Triangle Park, NC. Publication 

No. EPA-450/3-73/006-b. February 1975. 

6. Engineering and Cost Study of Air Pollution Control for the 

Petrochemical Industry, Volume 3: Ethylene Dichloride 

Manufacture by Oxychlorination. U. S. Environmental 

Protection Agency. Research Triangle Park, NC. Publication 

No. EPA-450/3-73/006-C. November 1974. 

7. Engineering and Cost Study of Air Pollution Control for the 

Petrochemical Industry, Volume 4: Formaldehyde Manufacture 

with the Silver Catalyst Process. U. S. Environmental 

Protection Agency. Research Triangle Park, NC. Publication 

No. EPA-450/3-73-006-d. March 1975. 

8. Engineering and Cost Study of Air Pollution Control for the 

Petrochemical Industry, Volume 5: Formaldehyde Manufacture 

with the Mixed Oxide Catalyst Process. U. S. Environmental 

Protection Agency. Research Triangle Park, NC. Publication 

No. EPA-450 /3-73-006-e. March 1975. 

PVDB (htmOD(ls) 
P.5 

9. Engineering and Cost Study of Air Pollution Control for the 

Petrochemical Industry, Volume 6: Ethylene Oxide 

Manufacture by Direct Oxidation of Ethylene. U. S. 

Environmental Protection Agency. Research Triangle Park, 

NC. Publication No. EPA-450/3-73-006-f. June 1975. 

10. Engineering and Cost Study of Air Pollution Control for the 

Petrochemical Industry, Volume 7: Phthalic Anhydride 

Manufacture from Ortho-Xylene. U. S. Environmental 

Protection Agency. Research Triangle Park, NC. Publication 

No. EPA-450/3-73-006-g. July 1975. 

11. Engineering and Cost Study of Air Pollution Control for the 

Petrochemical Industry, Volume 8: Vinyl Chloride 

Manufacture by the Balanced Process. U. S. Environmental 

Protection Agency. Research Triangle Park, NC. Publication 

No. EPA-450/3-73-006-h. July 1975. 

12. Survey Reports on Atmospheric Emissions from the Petroleum 

Industry, Volume I. U. S. Environmental Protection Agency. 

Research Triangle Park, NC. Publication No. 

EPA-450/3-73-005-a. January 1974. 

13. Survey Reports on Atmospheric Emissions from the Petroleum 

Industry, Volume II. U. S. Environmental Protection Agency. 

Research Triangle Park, NC. Publication 

No. EPA-450/3-73-005-b. April 1974. 

14. Survey Reports on Atmospheric Emissions from the Petroleum 

Industry, Volume III. U. S. Environmental Protection 

Agency. Research Triangle Park, NC. Publication 

No. EPA-450/3-73-005-C. April 1974. 

15. Survey Reports on Atmospheric Emissions from the Petroleum 

Industry, Volume IV. U. S. Environmental Protection Agency. 

Research Triangle Park, NC. Publication 

No. EPA-450/3-73-005-d. April 1974. 

PVDB (htmOD(ls) 
P.6 

ATTACHMENT A 

•aSfa? 

..—r^rr-- •mhtaOKU) 
P.7 

A-81-22 

III-B- 1 

SEFA 

Office of Air Quality 

Protection Planning and Standards 

Research Triangle Park NC 27711 

EPA-450 3-82-00.! a 

October 1983 

Air Oxidation Processes Draf 

in Synthetic Organic EiS 

Chemical Manufacturing 

Industry — 

Background Information 

for Proposed Standards 
P.8 

•TABLE F-4. DISTRIBUTION OF NATIONAL STATISTICAL PROFILE DATA VECTORS 

3

'*nt 13 -naair 

1303 

"305 

:306 

•307 

: soi 

205 

2301' 

3302 

2303 

2305 

2 308 

5101 

5102 

5103 

5104 

'02 

1004 

1007 

2203 

2204 

2205 

2208 

2207 

2208 

902 

903 

904 

'001 

1005 

1301 

:302 

'303 

'SO* 

:305 

1806 

:so7 

1403 

1404 

1407 

1408 

'1409 

. 1410 

1411 

1418 

'.41S 

•421 

423 

'422 

•420 

'SOI 

5202 

5203 

5204 

5205 

52C6 

!2t: 

5208 

5209 

5201 

•our'y imus^onj <g/." 

— 326 

586 

115 

2.12 

55.3 

75.3 

117 

233 

617 

340 

219 

1370 

2150 

399 

1210 

13.7 

323 

223 

155 

26.4 

27.9 

36.0 

13.7 

14.6 

80.2 

103 

407 

78.7 

188 

529 

211 

205 

136 

14.1 

13S 

359 

15.1 

20.3 

33.7 

14.6 

0.0250 

15.8 

357 

0.0205 

39.6 

16.0 

19.5 

23.3 

31.4 

0.217 

30.2 

433 

348 

228 

:23 

464 

371 

78.9 

516 

•«t siting /tlul "Si/ie 3**941 "owrtu iatf*ir)i. 

:.:92 

-.35 

3.199 

3.301 

3.31 

3.234 

3.140 

3.144 

3.093 

3.090 

0.146 

1.04 

1.59 

0.728 

0.676 

0.M9 

0.269 

0.154 

0.217 

0.082 

0.089 

0.087 

0.08S 

0.109 

0.440 

0.433 

1.52 

0.386 

0.143 

0.391 

3.336 

0.387 

0.490 

0.205 

0.339 

0.793 

2.63 

2.49 

2.63 

2.54 

2.75 

2.53 

2.34 

2.39 

0.106 

0.138 

0.137 

0.299 

2.57 

1.71 

0.752 

'.99 

2.65 

2.30 

0.*22 

3.769 

0.769 

0.789 

4.25 

161 

529 

194 

3037 

1631 

52 

790 

1212 

3552 

2307 

1320 

1427 

1373 

1524 

2092 

365 

1524 

565 

516 

49* 

310 

231 

152 

97 

182 

182 

252 

1642 

979 

2264 

1341 

1277 

516 

1309 

912 

607 

24 

73 

61 

76 

33 

173 

547 

27 

176 

118 

118 

100 

61 

197 

182 

121 

216 

647 

143 

304 

242 

52 

289 

F-12 
P.9 

ATTACHMENT III 

EPA AIR OXIDATION REGULATORY PROGRAM 

STATISTICAL ANALYSIS - KEY VARIABLES 

Variable Number Definition of Variables 

1 Plant number 

JT" Plant size (IO6 lbs./yr.) 

3 Molecular weight product 

4 Molar oxygen ratio (MOR) 

IJ5J O- volume percent in reactor off gas 

6 CO volume percent in reactor offgas 

7 CO, volume percent in reactor offgas 

8 H20 volume percent in reactor offgas 

9 N2 volume percent in reactor offgas 

10 Product VOC percent in reactor offgas 

11 Feed VOC percent in reactor offgas 

12 Other VOC component in reactor offgas 

13 Non VOC combustible volume percent in 

_ reactor offgas (Hj* CH., and C,Hg) 

fl*T) Total volume percent VOC in~the reactor 

offgas (10+11+12) 

SD Heating value (Btu/SCF) reactor offgas. 

(Includes heating value of 6, 10, 11, 12, 

and 13) 

^ D D Flow of reactor offgas (1000 SCFM) 

17 Ti, auto-ignition temperature (°C) feed or 

product depending on which is lower 

18 EL, explosive limit feedstock, volume percent 

in air at atmospheric pressure and 2SUC 

temperature. 

19 Tr, reaction temperature (°C) 

20 Tr/TiEL 

21 A HR, (kcal/gm mole), global heat of reaction 

22 FiF , ratio of actual offgas to theoretical ?' 

air 

requirement. 
P.10 

ATTACHMENT III - CONTINUED 

~" EPA AIR OXIDATION REGULATORY PROGRAM 

STATISTICAL ANALYSIS - PRODUCTS/COMPANIES 

(Data Base from 1972 Houdry Petrochemical Survey) 

Acetaldehyde 

Eastman 

Acetic Acid 

Eastman 

Acrylonitrile 

American Cyanamid, Sohio, DuPont, Monsanto 

Ethylene Dichloride 

Conoco, Diamond Shamrock, Ethyl, Goodrich, PPG, Shell, 

Stauffer, Vulcan 

Ethylene Oxide 

PPG, Dow, Koch, UCC 

Formaldehyde 

Hercules, Tenneco, Georgia-Pacific, Borden, DuPont, Celanese, 

Reichhold, Gulf 

Hydrocyanic Acid 

Rohm and Haas 

Maleic Anhydride 

Monsanto, Denka, USS Chemical, Tenneco, Reichhold, 

Kopper 

Phthalic Anhydride 

UCC, Stepan, Monsanto, Koppers, USS Chemical 
• -n <7 v» w4»> wi ui wi wifwi (A wi w> WH* 

•;> e e e H ea o e\ s ei e e e 

4 W N — H » « M vJ>Cj0/ S WJ Kl 

*MJ>WH»MM M 

^ee^M»MW » 

d c ^ - —icr ue»j»eo«ne o 

8T 

... . •Jf- . . 

u u u ur— in t 

v i vj «j viAwi wi wi wi,— 

UlSuUlU ? M A S? » WUUuS J 

0*\WI UN|> A WI S I - ft. ^SUI U 9 \ 

KI a u A e 

wi vi o o> o 

3 -

• * A 4k * * I 

n •• 

o»«< . wi 

8 3 

WIWIWIWIWIWIWIW I / 5 

H0TO» M N e>MUM0iO>O>K> O 

ssiss: skkkssssic 

M » * Kl_ . 

. . . i • 

jk et wi u _ 

eoo . 5 

e w s 

MMU U 

ssks 

IM 

»-»wi a> JV 

8

j» • » Ki 

s e s 

VJ Oi 9 3B 

01 Ki — vi 

O"0» -J vj 

S S-Jk-vi 

o e s s 

£ s 2 s U ff — 

e s c 

?P.— p 

M M S '£ 

» 9> Jt «. 

8 8.S8S2.8S2;: *SS4£ ~ Z 

Meoewow» M 

jnweoeeioJke b 

wi e e * 

. . . i . 

U»« l u —1» - 5 

i i i i i • II I 

, Jk 

etee<oeea»i0i a 

C U U W> J AMMU I 

, s s s s 

*»-WI — W 0> 

jt-N».vjj e e> 

>.&-tr. cx 

• • • | • 

825* g 

M M >i i a M »<JI« « 

• • . • • 

©> Kl «J Wl 0\ 

s s s s- s s •«- s s 

*MMM»SIVIV> > 

poeesess o 

vlvjv|vjei^(.-lvlK I 

essssoss e 

e e e e s s e i . . 

& U M U 3 S VI 

e wi wi wi wi —-./i 

! i i i i*• 

8 Wl S_f> S » 

«HB-03>N I 

Wl Wl 4 . 'C 

Wl 0» 10 Jt 

e e wi 

v l vl IO Xt 

01 Wl * Jk 

ie e wi vi 

8 8 e S 

ai es at m 

I 

s M U M 

Wl Wl Wl 8 v j sss 

KIKIKIKIKIWIvlWIK I 

Wl 

Wl 

w 

X Sk 

•»• • 

Jk 

mm 

e 

s 

Jk 

Oi 

Kl 

U — O 

•> 10 V| 

VI W 0> 

SSS8S 

i i i • i 

dx 

e e e 

e s s 

Kl U Wl 

I I I I I 

8388 2 

SSSSS 

Jk v j «- Jk Kl 

M 0> v l e 0> 

* v99?u»tt o wieee e 

• ei8»ueci 8 oooo o 

e<oioio<a«i0<o e 

wi w w w wi 

wi Wl Wl Wl Wl 

MKIN N 

8 3L8.3_ 

jk»j t * 

Wl Wl Wl Wl 

Wl Wl Wl Wl 

NNNNNNNN N 

vivlvlvivlvjvjvjv l 

_.»j4jfl wi w« wiwt w» tn wi 

Wl wi tn tn tn S S tin tin 8 2 ?? 

e e» © c> 

j k j t j t j t 

v l vl vl vl 

M Kl Kl Kl 

Ill l 

ft* ta» IM » • 

S

e e w 

M Kl M 

e e e e 

E

W Kl Kl 

14 in i -

Wl vl w . 

» N U 

eeeeeeee e e *» •» •» o 

• •*••••• • •••• • 

NMMMkJklklM M r^ Wl Wl Wl vl 

SSSSSSSSS 82228 

I I I I I I I I I 

vlvjvlvlvlvlvlvlv l 

0>0>O»0>O»0>O»O>0 « 

eeeeeeee e 

weoeuNxo v 

• ••••••• • 

• < u « u s ei s M 

S2E:I25*,»

,

8 

u vi •• ?• 

vi Kl V vl 

%3 

IO 

«0 

e 

s 

e 

wi 

0> 

v l 

M 

Wl 

8 

0> 

Kl 

I I I I I I 

Jt U W W J t «-

»5ee * * Oi ui in in ai vi 

• • • • • • 

Jk VJ VJ VJ Jt 10 

tl 

t 

n 

a. 

$81 

w» 

Wl 

Wl 

e 

8 

Wl Wl Wl Wl 

KI o 

3 '-. 

Wl Kl Wl Jt 

e e e e 

III I 

o vj e vi 

ssss 

s Ifw 2 

«ff 

• • i 

w 

e Oi vl 0» Oi 

10 <0 Wl 0» 

Wl Wl v l Jt 

e KI e e 

e e i • i • 

Jt e 5 

— UPSf 

8 

8 

e 

w« 

i i i i •* • 

-ii 

ss 

I • • • K 

«3l 

Wt O " - " • 

w e 0>> vj wi 

8eS 8 - n 

IB5 Jk Jk Jt J t k 

NMM N 10 <o IO <o 

8

 JI 

i i U 

2? ^ 

» U -3 

i 

is 

.r 

.8888 8 8 8 v l v j v j vi>w i ij 0 wiwlwiwiflfq it 

wi wi wi tn 

ooo o 

s 

•o 

ssss 

»»UV l 

TTd 
ATTACIMENT A 

Col' 

6 

Ht(lmic Anhydride 

'180 1 10S 

1802 50 

1803 40 

1804 20 

1805 44 

1806 54 

1807 50 

98 

98 

98 

98 

98 

98 

98 

4.SO 13.29 

4.SO 13.50 

4.SO 14.38 

4.50 > 

4.SO 14.38 

4.SO 12.00 

4.SO 9.10 

0.25 

0.2S 

0.25 

0.25 

0.25 

0.25 

0.25 

0.25 

0.63 

0.S1 

0.10 

0.40 

WO. SO 19.50 

0.50 6.53 

O.SO 6.S3 

O.SO 5.90 

0.25 -

1.79 

1.80 

2.32 

2.27 

1.77 

2.00 

2.90 

0.30 

0.64 

0.13 

O.SO 

0.60 

0.S1 

1.90 

0.40 

0.30 

0.84 

0.84 

1.90 

0.14 

2.51 

2.60 

3.17 

1.79 

2.35 

4.00 

2.90 

4.00 

5.75 

3.20 

4.43 

4.50 

6.16 

5.30 

S.20 

0.08 

0.08 

3.23 

->v 

SOCMI AIR OXIDATION DATA FROM IKMORY QUBSTIONNAIRES 

VAPOR PHASE PROCESSES (Continued) 

10 11 12 

Page 2 of 3 

13 T4* 15 16 17 18 19 20 21 22 

- 1 -

7.23 75.03 

6.60 75.SO 

9.31 70.71 

- 95.80 

3.93 77.56 

4.00 77.00 

4.30 80.50 

3.50 71. 

3.96 68, 

5.60 70. 

1.89 72. 

- 72. 

6.69 70. 

- 71. 

74. 

2.20 75. 

- 77. 

- 92. 

5.10 92. 

5.69 70. 

60 

92 

00 

6i 

SO 

39 

80 

4S 

00 

70 

4n 

% 

0.003 

0.002 

0.002 

O.OOS 

0.20 

0.09 

0.03 

0.17 

0.105 

0.30 

0.03 

0.03 

b.io 

0.12 

0.07 

6.06 

0.12 

0.003 

0.07 

0.30 

0.60 

0.27 

0.40 

0.24 

0.017 

0.06 

0.13 

0.13 

0.20 

0.3D 

0.02 

0.05 

0.01 

I j H*f ldohyde ( 

'Vf i 1*0 44.1 1.41 0.19 0.41 0.10 83.30 

0.14 

0.39 

0.035 

0.035 

0.14 20.06 

14.60 49.15 £ 

5.80 300 

3.90 300 

3.90 3fO 

3.3030 I/ 3 Jfli O 

oo/ty 

SO 185 

AO 

36J50 

36 .EO 

36.50 

36. iO 

36. SO 

*6. ;o 

36. » 

36. Ml 

6. tO 

6. TO 

6.F0 

6. JO 

42S 

425 

425 

425 

425 

425 

42S 

635 

635 

635 

63S 

635 

635 

635 

635 

345 

345 

345 

345 

6SS 

1.636 

3.636 

0.636 

0.636 

0.636 

0.636 

0.636 

-869.38 2.43 

•869.38 2.96 

-869.38 3.56 

-869.38 2.88 

-869.38 3.31 

-869.38 2.99 

-869.38 2.96 

9.058 

0.058 

0.058 

0.058 

0.058 

0.058 

0.058 

0.058 

0.172 

0.172 

0.172 

0.172 

0.058 

-25. 

-25, 

-2S. 

-25 

-25 

-25 

-25 

-25 

-47 

-47 

-47 

-47 

-25 

17 0.569 6.4 N kur) 

17 1.64 lin t 

1.44 A W 

1.54. 

1.22 

1.40 

1.50 

1.58 +**i2U 

.92 JU4*l.n 

.92 1.C7 

.92 1.(7 

.92 1.58 

.17 1.60 

A1 

|.S*f 

2.0f' 

!>•• * 

3.6 462 0.694 -43.00 1.077 
ATTACHMENT A 

6 

SOCHI AIR OXIDATION DATA FROM HOUORY QUESTIONNAIRES 

LIQUID PHASE PROCESSES 

#*--; JJ>- <i« / s 

?2 

Page 3 of 3 

LXce f Idehyde 

I T 450 44.1 0.50 O.SO 

&J& /llH—thyl Terephthalate i 

< /100 10044 60 6000 194.2 3.0 -

1007 360 

• 

yfhenol 

^220 3 450 

2204 250 

2205 215 

2206 200 

2207 80 

2208 60 

194.2 3.0 

194.2 3.0 

\* 

94. 

94. 

94. 

94. 

.1 ^v 

1.0 

1.0 

1.0 

1.0 

94.1 1.0 

94.1 1.0 

(5% clobexano1 

1 93 

94 

ISO 100.2 1.0 

ISO 100.2 1.0 

ISO 100.2 1.0 

$ft .tjrophthallc Acid i 

1001 510 166.1 3.0 

1005 412 166.1 3.0 

2.21 

1.0 

0.82 

0.7C-. 

2.4C 

V 

i. 

0.70 

0.39 

96.50 

98.20 

94.09 

5.0 

7.10 

6.43 

6.09 

5.00 

4.50 

0.5 

0.15 

4.64 

0.22 

'•1 

1.0'. 

0.64 

1.27 

5.30 

5.34 

0.5 

0.67 

1.29 

1.30 

91. !»4 

92.58 

10 11 

,<> 

13 14 15 

yl" 

16 17 18 19 20 21 

95.00 

92.90 

93.39 

89.15 

9S.00 

9S.00 

98.80 0.0S 

99.04 0.003 

92.72 -

0.03 0.03 0.27 12.00 

0.08 

0.03 

0.10 

0.01 

0.03 

0.03 

0.03 

0.05 

0.1S 

0.2S 

0.06 

— 

-

-

~ 

— 

0.03 

-

0.09 

. 

-

~~' -

0.0125 

0.70 

0.03 

0.11 

-

-

-

-

-

-

-' 

-

-

-

0.94 

-

0.08 

0.03 

0.10 

' 0.04 

0.03 

0.11 

0.03 

0.05 

7.76 

4.42 

6.25. 

1.81 

1.89 

2.49 

1.89 

3.13 

cvt^- ^ 

°Qs/ i 0.266 

\0.76 

0.03 

0.11 

12.67 

/I2.47 

43.79 

10.55 

1.11 

60.00 

18.60 

17.00 

15.00 

10.18 

7.57 

5.00 

3.20 

6.00 

6.04 

8.30 

54.09 

32.15 

22 

0,693 

1.591 

1.008 

1.048 

..667 

1.32S 

1.066 

1.736 

1.460 

1.181 

1.749 

1.633 

1.762 

1.27S 
oB-A 

Unitod Stataa 

Environmental Protection 

Agancy 

TTT &- UCJ»I 

Offiea o* Air Quality •*•** EPA-4J3O/3-W-0C6 « 

Planning and Standards Oeeamhor i<uu • 

Reaaarch Triangta Park NC 27711

 WW!WT,0 «r

' * » 

Air 

Distillation 

Operations In 

Synthetic Organic 

Chemical 

ManufacturingBackground 

Information For 

Proposed 

Standards 

Draft 

EIS 

u ^ 

5 
EPA-450/3-83-005a 

Distillation Operations In 

Synthetic Organic Chemical 

ManufacturingBackground Information For 

Proposed Standards 

Emission Standards and Engineering Oivision 

[ U.S. ENVIRONMENTAL PROTECTION AGENCY 

i Office of Air, Noise, and Radiation 

i Office of Air Quality Planning and Standards 

Research Triangle Park. North Carolina 27711 

December 1983 
P.16 

[y.yV.v^V:— 

APPENDIX C 

NATIONAL EMISSIONS PROFILE 

The purpose of this appendix is to present the emissions data base 

gathered for the distillation NSPS. All emissions data collected are 

listed with appropriate reference to the source of the data. Those 

units used in the regulatory analysis are identified. 

S-v 

C-l 
33! 

1 

ssttfJi 

i i 
P.18 

IT 

o. 

0 

I 

Ci, 

.*» 

\ 

0 0 

oft 

Id ' •> 

i «• 

-•v~ 

0-3 

0 

Ru 

itfVr 

i l 

.i'ililiiiSgSSi-j 

I • f* * i i i • • • • • • • • 

..yg^ssss^sp*-* 

S?S(.***«***« 8. 

,S8S8!88888M8 S 

•mmmnm 

gSS(8!8888S('i >S8 

'!!i'E§|§iiiiESSi 

SSg(S!SSSS8t!s88 

IslEilillsHIIii 

fl 

Si? 

ggg(Sl88888(88 8 

u • • » t «i • • a • • • • • a 

-HIEl'iilliESSs 

"il l I J ! 

,S?gr8!88888C88 8 

!SS|S8!88888 C = = S 

iiiriliiiiiEiiiiiiiiiiili 

<

*SS NNNKN f i < 

88888888! 8 

araa*>aaa)a) a 

iiiiiiil i 

M

 'J o 

SSS AnS! fiSo 

• *••..•• • vooannflv o 

oeSSSeSSS 

ii i i 

88888888:8 

IIIgSS8R S 

£88888888 

fllllili i 

88888888:8 

• •••aa«j«i a mfcRRfcfc8 o o e o o o 

888888 88 8 

• •••aaa * a liiooooii 

SiiiSBSSiiEfiiiiS 

gE*--«"g-* 

8(8888 8 

• a a * • • • 

Hilill 

8(8888 8 

• a a • a a • 

iEissi i 8(8888 8 

* • • • 

!S2! 

o e i s:liii§i£siiiii§888 i 

I! ~ 1 : •! . I I • o n wet. "or-

. o e 

•fM 

* s ; 

-|.T U 

o. e> 

• pie"* : 

lEriiiHE'HSSSii 

*****e«a«»aataa « 

K«;iiii-.EBB-^in 

8(8888 8 

• • • • • a • 

5(SooS S 

888888 8 

• • a • • a a 

S(eSeo e 

8(8888 8 

* • • 9 • • _P 

iESiiio 

iEiiii ! 

8 8 

a a 

ii 

e e 

• • 

S8 

a a 

§1 

8 2 

a a 

ii 

. « 

•r •»• 

«• e 

e e 

8 8 

PI n 

S8 

8 8 

-. 8 

CD — 

• •aaofjoo a a 

8^(((88(8 n 

8888(88(8 8 

a a a • a • • a t • 

§§IH§§EI§ 

88(((88(8 8 

• •••aaoaaa -

§HEEi§L-§§ 

8S(*(88(8 S 

• •aoaaoaa * 

i§EEEmi§ 

88(^(88(8 8 

• aaoaattaa * 

83(((88(8 S 

• oa«ao«aaa > 

igEEri§EIs 

88(8(88(8 8 

aaaaaaoaa * 

IIHHIIEis 

iliBiiEi g 

• _ PI oS 8 **.-

• • • — CC 

» » tr «-

© © Ol**-

n 

8 ( 

ii 

8 ( 

• a 

§E 

S ( 

§E 

5 ( ( 

a » o 

* ( £ 

Soi>( » 

a • 

sE 

e e> 

• o> » . 

S ( 

IE 

«" •» a> 

C2S 

— • * » '•-* ' •«• •»•> as* a * aaa» oaw aa» •*•» am* «•>> as* ••> «•» 

J • ! ' ' I I : i 

S'fS' S » i . » i» »J i . •» . fci" te te 

3,553555833553:36 3 

Hsg;s:§!gggggdgggg;ggg 

'!USl'sJi'8 88 88'2{2 22 2!2>:8 

.--J ! "J . . . 1 

Esiiis 

sssstiiESSiiS 

|SJS25| -

ECCbkCi k 

B

l— ^ I * ^ I— li* 

DUUSB U 

c z ei a a j c 

ggSSggg 

2 - >2 * >2 22 

I! 

5E 

« « 

gg gg 

88 

lltllriKX K MIr S K *C TC JS X S >-^i--*.h>H»»-i - i--5 5 i- F >- •- •-

xxxxkuaa a •> • m. ac ic ac ae K 

l fc 8 bl'SMIS! !S JS ti fc»'« g g g §;§ K WJ-WIJW 

ae at 

bl bl 

8 8 

SS 

8 8 

8 8 

a a 

- 8 

MM 

S3 

u u 

illlliiiliil 

§St((88(i8sE 

aaaaaaaaaaa a 

uSuQuuuuC O 

gggggggggg 

ill l 

88( 8 

88( 8 

IIII 

88( 8 

iiii 

88( 8 

a a a a 

IIII 

88( 8 iiii 

88( 8 

a a a a 

88( 8 

• a • a 

lir l 

IH§ 

iiii 

ii§i 

(88 8 

rll i 

•> O O Q 

•» CD OD kS 

o* cs cs e 

•» <m — K 

•> o o o 

(8S 8 

(88 8 

a- o 5 8 

(88 8 

a * a a 

Eio o 

o> e e e 

o» n -• •»• iiii 

(8S 8 

a •» • a 

^§11 ll§ I 

§

e> o- o> p- o> e-

. ( ( ( ( ( ( 

*> •* *f P" P> •" _*• • • o> Q. o> o- D> o8

0. o- o- o- o> o-

(•• 6> o> o> o> o-

§

••»••»• ' 

p. o- o- •> o» o8 ( ( 5 ( » o-

...«• * . 

o c* o. o- e> o* o* 

e ( o. S> ( cr o> 

8((((( ( 

si s* t i i £ i 

8 ( o> ( ( ( o> 

ilrEII I 

ztttttt 

• a • a a • • 

SEEIEII 

8

» D> 0" •> o» o-

(» •• o> » o> o> 

e o> •* o" a> o- o 

:((((( ? 

§

P> D> Q f> O. O* 

> o o> o 

18( 8 

nn 

e» »r w o 

a> 8 8 o 

Eli l 

e. p» o> — e» a- oIIEIEII 

« p. a. o> e. e> e> 

•• »• a- »• •• p. o-

» p. p> & •>. p. » 

» a. •> o> •> o» » 

iiEiEIililEEEI I 

aaaaaaaaa*aa** a 

i i E i E s fe *

 s E E E E s I 

SS8SB33333SSSBS3 

ggIggggglggggggggg i g 

22222 s > 22»22 ! > 2

: > 2222 :>:>:> 222 !

'

:>: ' 2 2 

M K K K X X « 

cn co cn cn n i 

« z 

§y 

C-3 

t-^a.Ck(vi-i-H'*i*iSii£C g a zm'- — — — >•—Bc-.Q-1-i uxL.ki><a<M*:S:i S-B !i E

jij^|*$*>aPi -

D u y u 

::" rK*" 
CH 

' • 

" • 

9 

f 

--'- , 

9 

f 

, ? 1

 ,A 

10 

10 

tt 

11 

11 

11 

11 

11 

11 

11 

11 

11 

11 

11 

11 

11 

11 

. 2 ^ 

12 

o a: L

 l3 

* • 13 

14 

14 

14 

11 

14 

14 

14 

14 

14 

14 

IS 

13 

17 

17 

17 

17 

17 

17 

IB 

. IB 

IB 

IB 

IB 

IB 

IB 

ta 

ta 

i « 

* . V 

1 

n m NO CP'- TR FINL r-, OISI _(V 

srn LOCN cot CUD COUP CNTL HOOF, TYPE SCFH 

UCC TL* 1 

IB FIX 1 

JB FTX- 3 

UCC TL* 1 

UCC TLA 1 

UCC TLA - 1 

UCC TLA " 

Di FTX 

U U TLA I 

UCC TLA 3 

AC FOIA I 

.AC TOLA 1 

AC FOLA 1 

AC FOLA 3 

BP BTX 1 

BP BTX 3 

PP BTX 1 

. BP BTX a 

80 LOH 1 

80 ION ] 

MNS ATX 1 

MNS ATX 1 

NNS ATX 2 

MNS ATX 1 

BP OTX 4 

BP VTX 2 

NM9 PFL 1 

BP OTX 9 

DP VTX a 

CO DHB 1 

CO BHD 1 

UI CCA 2 

HI CCA 1 

MNS ATX 3 

NTS ATX 2 

MNS ATX 1 

UCC I W 2 

UCC I W 1 

UCC I W 1 

FMC BATX 1 

FMC BATX 3 

8 BPTX 1 

8 DPTX 2 

8 BPTX 1 

8 DPTX I 

8 BPIX I 

8 BPIX 1 

mi CLA i 

RU CLA 1 

RU CLA 1 

RU CLA | 

RU CLA 1 

RU CLA 1 

RU CLA 1 

mi af t i 

mi CLA 

no* ri * 

1 no* n n 

*• ftf .CMU 

V 

V 

v 

NV 

V 

V 

V 

1 V 

NV 

V 

NV 

V 

V 

NV 

NV 

NV 

NV 

V 

NV 

V 

NV 

NV 

NV 

V 

V 

V 

V 

V 

V 

NV 

V 

V 

NV 

V 

NV 

NV 

NV 

NV 

V 

NV 

NV 

V 

RV 

NV 

NU 

NV 

NV 

NV 

NV 

V 

V 

NV 

NV 

V 

NV 

I V 

3 NV 

7 y 

CON FIR CNT FRC 999.999 

CON ATN CNT FRC 7.400 

CON- ATN- CNT—FRC—30,000 

CON FLR CNT FRC 344.000 

SCB ATN CNT FRC 27.400 

CON ATN CNT-FRC—32.400 

CON AIM CNT FRC 13.200 

CON ATM CNT FRC 9TT.TV9 

CON R a CNT-FRC-000.000 

CON ATM CNT FRC 33.900 

CON FIR CNT FRC 10.200 

CON FLR CNT - FRC -33.70 0 

CON FLR CNT FRC 23.400 

CON NON CNT FRC 000.000 

CON NON CNT FRC- 000.000 

CON FLR CNT FRC 999.999 

CON FLR CNT FRC fff.99 ? 

CON FLR- Oft . FRC -Off.Off -

CON NON CNT FRC 000.000 

COM FLR CNT FRC fff.ff f 

CON. RCL - CNT--FRC—000.000 

COM INC CNT FRC fff.ff f 

Cm FIR CNT FRC fff.ff f 

Cm ATN CNT FRC fff.ff f 

Cm FLR CRT FRC fff.ff f 

Cm BLR CNT FRC fff.ff f 

SCB MX CNf FRC 000.000 

Cm ATN CNT FRC fff.ff f 

Cm ATN CNT FRC 73.000 

Cm ATM CNT FRC—1.300 -

CON ATN CNT FRC 83.900 

c m R a CNT FRC 000.000 

CON R a CNT FRC 000.000 

Cm FIR CNT FRC fff.ff f 

Cm FLR CNT FRC fff.ff f 

SCR R a CNT FRC 000.000 

SCB ATN CNT FRC 999.999 

c m Nm CNT FRC 000.000 

c m n m CNT FRC 000.000 

c m Nm CNT FRC 000.000 

c m R a CNT FRC 000.000 

c m R a CNT FRC 000.000 

Cm FIR CNT FRC fff.ff f 

c m R a CNT FRC 000.000 

c m R a CNT FRC 000.000 

c m R a CNT FRC 000.000 

Cm INC CNT FRC fff.ff f 

Cm ATM CNT FRC fff.ff f 

Cm ATM CNT FRC fff.ff f 

Cm ATM CNT FRC 0.020 

Cm ATM CNT FRC 0.007 

Cm ATM CNT FRC fff* W 

CW ATN CNT FRC fff.ff f 

COH AIM CNT FRC 999.999 

COM ATM CNT FRC 999.999 

COH MH CHt FRC 999.999 

COH M H CHt TRC 999.97 9 

COM .MW _Cai....r»X_999.99 9 

••.on n » c m ru t 77.••oo 

jmSL t_*m--

mm—mTJf_.**—-

PTU/ 

SCF 

9999 

OOOO 

-0000-

0130 

0400 

0093-

0008 

oooo 

MU_ 

037f 

0439 

0344 

oooo 

oooo 

fff f 

fff f 

vm: 

LB/HR 

f99f.ff f 

0000.000 

-0000.000-

028?.000 

0033.800 

0010.300 -

0000.000 

ffff.ff f 

0000.000-

0013.700 

0013.800 

0044.000-

0037.fOO 

0000.000 

0000.000 

ffff.ff f 

ffff.ff f 

oooo 

fff f 

- oooo 

ffff 

ffff 

JBStfff f 

fff f 

0008_ 

fff f 

0 

3443-

0104 

OOOO 

OOOO 

fff f 

fff f 

0400 

fff f 

OOOO 

OOOO 

OOOO 

OOOO 

OOOO 

fff f 

OOOO 

OOOO 

OOOO 

fff f 

fff f 

fff f 

3047 

3733 

fff f 

4999 

999? 

9999 

9999 

9999 

_9»99. 

I4V1 

*00f 4 

0000.000 

ffff.ff f 

-9099.999-

ffff.ff f 

ffff.ff f 

ffff.ff f 

ffff.ff f 

ffff.ff f 

.0000.009^ 

ffff.ff f 

0 . 0 

-0013.000 

0030.400 

0000.000 

0000.000 

ffff.ff f 

ffff.ff f 

0000.000 

ffff.ff f 

0000.000 

0000.000 

0000.000 

0000.000 

0000.000 

ffff.ff f 

0000.000 

0000.000 

0000.000 

0011.400 

ffff.ff f 

ffff.ff f 

0000.790 

0000.110 

ffff.ff f 

ffff.ff ? 

9?9f.f?? 

999?.??? 

9999.999 

9999.999 

9999.999 -

0100.30 0 

»*,V*1.IW'* 

OOOOiOOO 

XVOC XC XN XM 

999.?? ???.?? ???.?? ???.?? 

000.00 000.00 079.00 000.00 

-OO0IOO-O00I00-O7?IO0—000:00 -

003.00 009.30 034.40 013.10 

012.80 017.70 044.20 027.fO 

002.99 - 004.10 OBO>80- OOfifO 

000.20 000.40 Of4.00 001.40 

fff.f? m.?? vYf.w fw.ff. 

000.00—000.00 • 000.00— 000.00 003.80 OOf.OO M3. M 011.30 

017.10 033.80 010.30 013.10 

073.80 003.70 031.70 OTOilO 

017.30 018.40 032.30 018.40 

000.00 000.00 000.00 000.00 

000.00 - 000.00 -000.00 - 000.00• 

fff.f f fff.f f fff.f f fff.f f 

fff.f f fff.f f fff.f f fff.f f 

000.00 000.00 000.00 OOO.fO)( 

fff.f f fff.f f fff.f f fff.f f 

-999.99—-999.99—999.99—999*99-

fff.f f fff.f f fff.f f fff.f f 

fff.f f fff.f f fff.f f fff.f f 

fff.f f fff.f f -fff.f f -fff.ff -

fff.f f fff.f f fff.f f fff.f f 

fff.f f fff.f f fff.f f fff.f f 

; OOO.OO-OOO.OJ - 800.09—800.00 .-

fff.f f fff.f f fff.f f fff.f f 

0.00 0. 0 0. 0 Tf.0 0 

100.90- 080.00 -909.99-430.9 0 -

O02.fO 007.30 084.P0 007.30 

000.00 000.00 000.00 000.00 

000.00-000.00—000.00 -000.08 

fff.f f fff.f f fff.f f fff.f f 

fff.f f fff.f f fff.f f fff.f f 

000.00 - 000.00 000.00 000.00 

fff.f f fff.f f fff.f f fff.f f 

000.00 000.00 000.00 000.00 

-000.00••000.00 - 000.00 000.00 

000.00 000.00 000.00 000.00 

000.00 000.00 000.00 000.00 

000.00 000.00 000.00 OOC.00 

fff.0 0 fff.f f fff.f f fff.f f 

000.00 000.00 000.00 000.00 

000.00 000.00 000.00 000.00 

000.00 000.00 000.00 000.00 

fff.f f fff.f f fff.f f fff.f f 

fff.f f fff.f ? fff.f f fff.f f 

fff.f f fff.f f fff.f f fff.f f 

082.30 044.30 003.40 04f.3 0 

100.00 042.90 007.10 030.0*1 

fff.f f fff.f f fff.f f fff.f f 

fff.f f fff.f ? ?ff.f f fff.f f 

f??.?? ???.?? ???.?? 99?.?? 

fff.f f ff?.?? ???.?? 99?.99 

999.99 999.99 999.99 999.99 

999.9? 999.99 999.99 999.99 

..999.99-.999.9 9 ..999.9 9 -999.99 . 

030.4 0 029.4 0 014.2 0 037.3 0 

101.0 1 am . n i 000.1 * iei.*? i 

"•oa.ao Ww^oo.oa^oTbo 

xo 

?9?.?? 

021.00 

-031:00 -

OlB.BO' 

008.20 

003:20 

003.80 

,TYY.VT 

000.00 -^i 

oiiLsff 

010.80 

000.00 

000.0 * 

fff.f f 

fff.f f 

XCL 

???.?? 

000.00 

;000;00 

000.00 

000.00 

000:00 

000.00 

"99-9 9 

000:00 

KUHB 

99.??? 

2.000 

2:000 

2.433 

4.6?7 

2.703 

2.033 

TT.lrTT 

00.000 

.900.99 1.403 

000.00 -3.107 

000.00 

000.00 

099.09 

-990:00 

fff.f f 

fff.f f 

-Off nf?—Offiff 

000.00 

fff.f f 

-990.99-

fff.f f 

fff.ff 

•fff.f f 

fff.f f 

fff.f f 

*9*.9t: 

fff.f f 

0 . 0 

0*8.00 -

000.00 

000.00 

.000.00 

fff.f f 

fff.f f 

OOOiOO 

fff.f f 

000.00 

-000.00 

000.00 

000.09 

000.00 

fff.f f 

000.00 

000.00 

000.00 

fff.f f 

fff.f f 

fff.f f 

001.00 

000.00 

fff.f f 

m.?? 

???.? ? 

???.? ? 

999.9 9 

999.9 9 

-999.9 9 

000.0 0 

"01. n 

T

 000.0 0 

000.00 

fff.f f 

000.00 

fff.ff 

fff.f f 

-fff.f f 

fff.f f 

fff.ff 

w.ot . 

fff.f f 

0.90 . 

-999t99 

000.00 

000.00 

000.00 

fff.ff 

fff.ff 

OOOtOO 

fff.f f 

000.00 

OOOtOO 

090.00 

000.00 

OOOtOO 

fff.f f 

000.00 

OOOtOO 

000.00 

fff.f f 

fff.f f 

fff.f f 

000.00 

000.00 

fff.f f 

fff.f ? 

???.?? 

???.?? 

??9.9? 

999.9 ? 

999.9 9 

000.0 0 

001.0 1 

3:234 

2.774 

00.999 

00.900 

ff.ff f 

ff.ff f 

mm 

— HLI M.< 

X 70,21,27 u _ > _ , c 

• 

* „ 1 1 

13,14,73 . ' ! 

-iM^ c •?<-' •• x 

ZWiafMaiafZ __ . — , 

X 13,14,23 ffiH ^ 

. . . - • 1 

X 24,23,24 1 1 

1 

a.t-r\3 1 . 

1 

' 

24,109,41,42 

*»«>"»?. !*-<> 

. 

00.000" 24,U 0 ^ri?.- * _ ^ 1tt\.-.i -

ff.fff . jr-jij* xo o /i ^ M./-..,. c. 

-09.90V 24,84,83 

ff.ff f 

ff.ff f 

ff.fff ^ 

ff.ff f 

ff.ff f 

00.999 

ff.ff f 

2.099 

12.900 

2.288 

00.000 

00.000 

ff.ff f 

ff.ff f 

00.000 

ff.ff f 

00.000 

09.000 

00.090 

99.009 

99.000 

ff.ff f 

00.000 

00.000 

00.000 

ff.ff f 

ff.ff f 

ff.ff f 

10.230 

12.000 

ff.ff f 

ff.ff f 

??.??? 

??.??? 

??.??9 

99.99 9 

99.99 9 

7.01 4 

or . o«<» 

f m . \y ana) 

000:0 0 "njinn n 

m-f-n> 2.00 

! 

-: 

•!•• 

41,42,111 *!»-> ' ?cc 

04,«,tiS arfl (y ino /-MU^ O 

33,34,37 „ , , j 

I 27 1 

113,114,113 ' 1 

| 

84,83,114 1 1 

87,88,117 

j ' 

• 1 

It8,ilf,120 1 

10,11,121 ' 

1 

28,2f,3 0 

1 

f 

77 

* 10,1l.I ? 

1 r "• 

"'••••*«>•<» ii* m j ••>''•' " • "'"• ', i ' 

TJ 

D 
P.20 

m 

:«g( S 

o •» © 

5 

si* 

ii 

8 8 

8 8 

a • 

n 

•A 

R

. * R R 

i **; P. © . 

8 * tSS-B R 

*> 

S 

'SESU 

L I ' 

8(£8 S 

•r , . • a a ia 

"lEII 

S(8l88 

u • (a o4 • ia 

i ! 88 

• • •• • istif 

IIIIiEI 

a a - a • • a a 

8 8 888( 8 

88888( 8 

a a • • a a • • * 

88888( 8 

1§§§§M 

88888( 8 

a at a a • • a a 

88888( 8 

a at * • • •• * iiMIM 

88888( 8 

a a tn a a • • • 

88888( 8 

• • • • • 9 •* • ninn 

nhiit 

• 9 • • 9 •% 9 

nm 

ililli 

ssiiiii* 

•"«• «*• 8 8 8 2 ** 

8288888 8 > a a a . • 

iiiiiii l 

8888888 8 

aaaaaaa a 

SoooooS S 

8838888 8 

• • a a • a a ai a a 

SSIiiiiS 

8838888 8 

i§ii§ii § 

8888888 8 

© © ©|*T> © 5 © © 

8888888 8 

-a a ai a a • - a a 

ssiiiiis 

n% 

a • * 

FJgFJ 

8 8 © 

ir 

8 8 2 

a a a 

sii 

© b e S o o 

... . 

Fl © © 

8 8 8 

o o o 5 o o-

... • 

•o © •» 

sis 

8 8 8 

% > • a M O O 

8 8 8 

© © 8 8 8 

. . . ... 

FJ FJ o o o 

8888 8 

.» • a a * a 

°°2i i 

8R©8 8 

a a a a a 

8R-»§§ 

n 8 8 8 8 

. 1 . . , • . •.000 0 

> Bt 0 © 

o o 

© © 0 0 

o «• o 5 o 

• • . . , • . 

fcR088 

© © 

B 8 8 8 8 

... . . •. 

ooon 

i 

8288 8 

• 1 a a • • a 

a ai a a 9 .» a • • a a °7H% 

iiESsBs 

a a a a a a a 

o g •> n IN « n 

88(388. 2 

a • a a • - a a a 

iiESsis 

88(888 3 

a • a a a a a • 

§

8(SC= S © Z> 5 o © o 

88(883 8 

• 1 a • • I a a a 

iiEiss©-

88(883 2 

• • • • • • a a a 

UEHoS 

88(383 8 

a • • • • a a • 

UE.iiSs 

88(338 2 

a • • a a - a a a 

iSEsiss 

%nnn 

a . a • a t a a 0 nnm 

I ! 

§ © a> •» *•* e» •• iiio-Es 

Bit , • i t • ai a a ai a a a «a a at a • • J» • • 

^!»it)iiiii?iiMxt"x 

! 1 1 i 

•W* - te*a-f>»|j-»j»'j»^^^|«-^9a.^a*»»tJ»*-

sfsssssssssssssssssss 

4ifgg§ggggggggggSggg 

ggS»i8I« 8 88*» >8S2»8 >i » 

daiJ H a . R . » v ».a a 

^ i l T 

2"» ,e»eia.»©« . — ..... . « M N*j;*2! f T«*nni * 

• ', I I . C-5 

13 -J* Fl 

Cft2 

ii 

' o a 

IS! 

i i i 

SHftftiii 

III 

© © © 

2 

* 

.3 

IN PI 

o o 

*•" IV 

•3C- * 

I f j CM ,/ . 

R e-»Mi. -

•r w w w wxxrx 

%n% 

888 8 

8S8 8 

a a a a 

nn 

888 8 

• • a a tin 

888 8 

a a . a a 

iii i 

888 8 

iiii 

888 8 

• a ' • • 

iiii 

888 8 

• a •• a 

nn 

nm 

• a a • a a 

: 8 8 

5:88 

a a a 

m 

: 8 8 

a a a 

:i§ 

£ 88 

a a a m 

> a © 

» © © 

. . . 

: 8 8 

t a a 

:ii 

: 8 8 

a • a 

m 

in 

f ' O ' 

OQO.p-D-0-O.O.D.OQ O Oil 

. 8 8 ( ( x% S I\t •% 1§ 8 I:! 

8

oo»»»»»i.i>ooodioo o eo»»»»»t<»oooS|oo o 

S88(((((((88 8 8!8 8 8 

§

o©o>»e»j>>c»»e>oooQi©o o 

8S(((((»(8i8l;is s 

888(((((((8S8S I S S S 

ii§ll^'l^§il§ii§ 

8

ooc«.o.c»D.i>o.p.opoopo o o©c»o»o>o.o.».o>©ooooe o 

8 8 8((((((( 8 8 8 o o S S 

ooot>»t>o»e»4>i>oooooo o 

888(( ( ((((8888 8 S:8 

88S(((((((888Soo o 

888(((((((S8S8:8S S 

iiiEEE'iEEEiigiigi 

8

p p •- o- e- e- i © © a> » e> » 1 

• . . . • • 

8 8 

o> o> o> o> o- •> 

o> o> D> o. a. e> ' 

- - C« D> » B> 

§ 8 8 8 8 

oooo o 

888 ! 

8 8 8 1 K S B 

I FJ 5 0 

|||o-*:|R520| | 

MMMMM 

*• • • >t B 

5S8*>o§8Sejo?*« 

MMM 

u u u u u u SS 

g £ 8 £ & 3 S »?! 

IkEkkitkibi . 

^ » W k.^1 — mm >_. 

S

Z Z X X Z X Z U U U U U U CJ 

55gii*jdS'sSB5gSgri | 

<««zSK«c<t«<«<E £ 

g g g g g g S.S 

muzz* 

S

o u 

i i 

ggggg 

nm 

a a -a a 

iiii! 

tfci.i.1 . 

ssss: 

gggg! 

z.zz i 

*• w 0 

*ii 

iii 

iii 

' ^ 

• I » b. '. z z I u u 

iii 

1S8 ( 

© © © a. 

iliim^rlliilil 

§

C*i?*fc 0^*"** 0*

,

"*t22SS5'2S 8 a©©i>>e.»e.a.i>eoo . 0100 0 ooockSfo-fo-op o Si p p o ooo».o.»-o-i>-o-oo o 01O o o 

1

 I 

§

ae»-»»»»«»eo o OiO p o ©©•>OD>*.e.»a.©p o pi p p o 59»»»»»»<>c<e e ©l o p o ©©•>Q>a>e.e»a»e>ooooioo o 

1 I 

iiiiiiiiiiiimn 

MMMMM5M55MMM\xfM'liMM 

^**a J »^ij»4»^»»a l -^a_a.|J»- l a = £ * -

S5S55SSSSSSSS5.SSS 

«UUU~*22M'I(IM'2B'$ 

igg ggiiiiiigggggggg g 

>->->->«xx»<>««««»<>- : 

KIIIII.HI-K H J JJ|.> | 

JJJIZZII£ELL C 

-I -1 _i s 

m««<0'««<4><or«iv 

nnnnNMNNN N 

K K K > 

«ggfc 

iilii 

r^ r« rv K ^ 

n Fl XI M F 

: M K K K M « 

- !-• I— I* , » 4- 0 . S SS ggts ».lSsg 2»-

:ikt.it u jni* n<"'r*PFH l X

l

*j";* > 

I FJ Fl FJ Fl FJ-FJ WNPinriNn n FI.TC n r. n . 
CH FIN! NO COL TR riN L UTK P1SI ILUW 

f NTR I.OCN COL CND COUP CNR HOBC TTPC SCFH 

30 BB FTX 

-30 - Nl RCA -

30 NI ACA 

30 UC TLA 

so rtrs rri 

30 HNS rrx 

31 HON HNV 

... ai nm HNV 

31 MM HNV 

31 PPC NNNV 

• 31 PPG Nmrv 

32 DP CIMJ 

33 ALL BIL 

32 ALL BIL 

33 DP OHTN 

33 DP OHTN 

33 BP OHTN 

33 DP OHTN 

33 DP OHTN 

33 . DP CFNC 

33 DP CFNC 

33 DP CFNC 

33 DP CFNC 

33 DP CFNC 1 

33 DP CFNC 1 

_ 3 3 TE KTN 

_ 33 TC NTN 

, 33 TE RTN 

* 33 TE RTN 

33 TE RTN 

33 TC NTN 

34 Ml CLA 

33 Ml CLA 

33 Ml CLA 

34 8 BPTX 

34 8 BPTX 

37 UC 8C8V 1 

38 OL. BRY 1 

38 X BKY 

38 OL BRT 

3? UCC TLA 

3? UCC TLA 

40 TE RTN 

40 UC SCMV 1 

40 UC BCHV 1 

40 . UC SCW i 

41 AHH BRLA J 

41 AHH BRLA i 

41 HNS TCTX 1 

41 HNS TCTX 1 

41 HNS TCTX 

4i sm CCTX • 

41 SUN CCTX 

41 CLPP OBTX 

41 CULF SJLA 

41 CULF SJLA 

41 CULF SJLA 

4 \ CULF SJLA 

»_ OP 01 « 

Ir-•? *j* SS 

ii far uri 

BlU / VIII. 

SCF LB/HR XVOC 

1 V c m ATN CNT FRC 48.700 0072 0024.300 002.30 

4 V - c m -NON CNT -FRC -000.000-0000-0000.000—000.00 -

3 v c m Nm CNT FRC 000.000. 

3 V Cm ATTL_CNT_E?»£_2a«Z91 

B NV- SCB -ATN CUT-. FRC -fff.ff f 

2 V SCB ATH CNT FRC fff.?? f 

1 NV cm nm CNT FRC ooo.ooo 

1 V CON ATN CHT FRC -9.900 

t v en m cm FIN ooo.ooo 

1 ' V c m ATH CNT a M 1.800 

1 V Cm ATH CNT-FRC 2.400 

3 NV c m n m CNT FRC 000.000 

2 NV c m n m CNT FRC 000.000 

1 NV CON - ATH CNT FRC - 4.3*0-

1 NV Cm ATH CNT FRC 8.400 

t V Cm ATN CNT FRC 34.400 

I V IXN ATN CNT FRC B.fOO1 NV c m ATH CNT FRC 4.200 

1 NV c m ATH CNT FRC 173.800 

1 NV CON ATH CNI-FRC 13.009-

I V Cm ATN CNT FRC 171.000 

1 V Cm ATH CNT FRC 13.000 

0000_0009.009_000.09_ 

18 13.00JI 0_30_ 

. ffff_fA»f?.fft- .fff .Pff?P? ????.??? ???.?? 

OOOO 0000.000 000.00 

0177-0003.000-003.40-

000* 0000.000 000.00 

0431 0008.100 031.10 

-0042- 0001.300 -003.OOOOOO 0000.000 000.00 

OOOO 0000.000 000.00 

XC tN 

004.10 044.10 

XH 

011.70 

XO 

OIA.IO 

-000.00- 000.00—909.90-490.00 

009.00 -.900.99 . 

_.4Q_J-._-9 

-fff.ff—fff.ff -

fff.f f fff.f f 

000.00 000.00 

-003.49-973.39-

000.00 000.0* 

032.70 033.fO 

-003.70-072.70 

000.00 000.00 

000.00 000.00 

000.00 

3.J0~ 

-tff.ff -

fff.f f 

000.00 

-001.49 

000.00 

031.80 

-003.90 

000.09 

900.00 

900.00 

0.0 

-fff.f f 

ff?.?? 

000.00 

020.30 

000.00 

00?.30 

-017.80 

000.00 

000.00 

ffff... 0004.200—904.00—fff .ff -fff.f f -ff f .ff - fff .f f 

0234 0013.009 939.89 

9947 0017.099 994.10 

0047-0003.300--004.40 

0180 0003.000 023.30 

0740 0420.209 1OQ.00 

1*234- 0012.009-013.80-

9947 0037.000 004.40 

0047 0993.009 994.49 

I RV CON INC Dtl _FRC_2B1.000-0748-1434.000-100.00 -

NV c m ATN CNT FRC 7.000 OOOO 0010.000 fff.f f 

NV c m MX CNt FRC 099.000 9000 0099.999 000.00 . 

1 NV COH ATH CNI-FRC -12.400--1282. 0120.300-100.00-

1 NV c m ATN CNT FRC Tf.300 

1 NV c m n m CNT FRC 000.000 

I V Cm ATH CNT - FRC — 0.300-

l V Cm ATN CNT FRC fff.ff f 

1 NV c m Nm CNT FRC 000.000 

1 NV c m ATH CNT FRC fff.fff . 

1 NV c m ATN CNT FRC fff.f? ? 

1 V Cm ATH CNT FRC 2.000 

1 NV SCB ATH CNT FRC fff.ff f 

1 V SCB ATN CNT FRC fff.ff ? 

N V c m Nm CNT FRC 000.000 

N V c m Nm CNT FRC 000.000 

1 V c m ATN CNT FRC 4.300 

1 V CON ATN CNT FRC l?.SOO 

1 V C M ATH CNT FRC - 37.200 

t V Cm ATH CNT FRC 2I?.B00 

* NV Cm MM CNT FRC 000.000 

NV c m ATN CNT FRC 2.300 

NV Cm ATN CNT FRC 0.700 

NV Cm NON CNT FRC 000.000 

NV CAD ATH CNT FRC ???.??? 

V CAD ATH CNT FRC ???.??? 

NV c m ATH CNT FRC 0.043 

v c m MX CNT FRC 000.000 

I NV CON RCL CNT FRC 000.000 

* NV CON NON CNT FRC OOO.OOO 

l HV CON fXL CNT FLH 000.000 

1 NV CON NON CNT FRC 000.000 

I NV c m mw CNT FRC 000.000 

I HV CDH PXL CNT FRC 000.000 

t V COH ATH CHT FRC 19.700 

1 wV COH no . C M rRC 4.40 0 

4 WU COM WOW CM* CRC 000.00 0 

..-- r.-... Cr.. r»n rr r ton.to " 

«W*R 9 0ta-wriF t £ £ 

F Mtf ff*x* - . -

1433 0401.999 199.00 

*** — — ^ --_—— ——— __ _ -»j« 

OOOO OOQQ.OOQ 000.09 

-4?78- OMM.fOO- 100.00 

ffff ffff.ff f fff.f f 

OOOO 0000.000 000.00 

ffff -fff f .fff.- fff .ff -

ffff ffff.ff f fff.f f 

OOOO 0090.003 000.00 

JjT_aBaBJ_fe aajjB_aa_B_ jakkjajja. a^JJaJJa _BJ_B. 

f ??? - - ffff.fff• fff.f f ffff ffff.ff f fff.f f 

OOOO 0000.000 000.00 

OOOO 0000.000 000.00-

0000 0000.000 000.00 

OOOO 0000.000 0*0.00 

4? 3.400 1.80 

43 434.000 1.40 

OOOO 0090.0*0 000.00 

1012 0004.400 029.00 

0480 0000.400 014.70 

OOOO 0000.000 000.00 

???? ????.??? ???.?? 

???? ????.??? ???.?? 

0007 0000.000 000.40 

OOOO 0000.000 000.00 

OOOO 0000.000 000.00 

OOOO 0000.000 000.00 

OOOO 0000.000 000.00 

OOOO 0000.000 000.00 

OOOO 0000.000 000.00 

OOOO 0000.000 000.00 

OOOO 0000.000 000.00 

1706 0003.000 003.70 

OOOO 0000.000 000.00 

OO"") 0000.00 0 000.0 0 

ai-jv voc 

BCP LB/HR run r 

00f.39 043.10 

003.70 983.40 

003.f* -0*3.40-

008.00 032.00 

037.90 

011.00* 

OOf.SO 

002.70 

-014.49-O03.f9 

032.00 

014.70 000.00_944.49_ 

- 004.00—*44.**- 034.00 

992.80 093.99 

O02.f0 082.49 

011.39 

911.49 

- 014.70 - 909.99-9M.99-

fff.f f fff.f f fff.f f 

900.00 900.00 990.99 

021.ft -000.00-944.80-

023.10 .000.99 

999.99 999.99 

-044.40 OOO.** 

fff.f f fff.f f 

000.00 9*0.00 

-fff.f f - fff.ff -

fff.f f fff.f f 

000.00 07?.00 

fff.f f fff.f f 

fff.f f fff.f f 

000.00 999.99 

900.09 900.00 -

090.90 07?.00 

000.00 079.00 

4.00 71.20 

3.00 83.30 

000.00 000.09 

~033.M~004.SO~ 

020.20 014.39 

000.00 000.00 

fff.f f ff?.?? 

fff.f f fff.f f 

000.40 094.80 

000.00 000.00 

000.00 0*0.00 

000.00 000.00 

000.00 000.00 

000.00 070.00 

000.00 000.00 

000.00 000.00 

000.00 077.00 

024.00 000.00 

000.00 000.CO 

000.0 0 000.0 ? 

»r> » ~ 

044.30 

999.99 

-938.49-

fff.f f 

999.99 

-fff.f f 

fff.f f 

999.90 

• fff.ff -

fff.f f 

999.90 

•00.00 

0*0.90 

999.90 

12.00 

7.40 

000.00 

~042<f0 

034.40 

000.00 

fff.f f 

fff.f f 

000.40 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

073.20 

000.0 0 

000.0 0 

;

 — 

008.00 

_0J4,70_ 

004.00 

992.99 

902.fO 

-914.70 

fff.f f 

000.00 

•13.30 

012.49 

000.99 

-999.99 

fff.f f 

900.00 

fff.f f 

fff.f f 

931.09 

fff.f f 

fff.f f 

909.99 

900.00 

031.00 

031.00 

12.90 

4.10 

990.00 

00?.00 

008.?0 

000.00 

fff.f ? 

fff.?? 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

021.00 

000.00 

000.0 0 

oo cv oo 

XC1 

000.00 . 

000:00 

000.00 

0.00 

???.?? 

???.?? 

000.0* 

000.00 

000.09 

000.10 

090.00 

000.00 

000.00 

fff.f f 

099.99 

999.99 

990.99 

900.00 

niu n : >LK 

NUHB NCP 

2.383 

00.000 

00.000 

3.070 

ff.ff f 

ff.ff? 

00.000 

2.0?1 

00.000 

4.107 

2.200 

00.000 

00.000 

ff.ff f 

3.1fl 

2.043\ 

2.23? 

3.034 

099.99. I.0Q9' 

990.99 3.184 

999.99 

999.99 

009.99 

fff.f f 

000.99 

000.09 

990.09 

999.99 

999.99 

fff.f f 

999.00 

fff.f f 

fff.f f 

000.99 

fff.f f 

fff.f f 

000.90 

000.00 

000.09 

000.99 

999.00 

000.00 

000.00 

000.00 

000.00 

000.00 

???.?? 

???.?? 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

000.0 0 

COO.00 

2.244 

2.23? 

4.000 

2.024 

*9«990 

8.127 

8.810 

00.999 

11.999 

ff.ff f 

99.999 

ff.ff f 

ff.ff f 

2.990 

ff.ff f 

ff.ff f 

00.000 

00.000 

2.000 

2.000 

2.3fl 

2.211 

00.009 

4.137 

4.429 

00.000 

ff.ff? 

??.??? 

00.000 

00.000 

00.000 

00.000 

00.000 

00.000 

00.000 

00.000 

2.000 

11.304 

00.000 

00.ooo 

•TOM 

x" 

X 

X 

X 

I 

I" 

X 

X 

X 

X 

X 

h t i 

NO 

134,135 -JJJ- K ,ro ', , 

M

 I I 

84.87,88 1 

04,03,137 J/ J , } . , 0 U 

32 j 

I 1 33,34,33 

138,IS?,14* 

141,142,143 

40,41,42 n> •••'•• 

no 

*.".*» 

i 

1 i | 

1 

1 i 

i 

i 

. 

i 

i 

. • 

2B,2f,30 i | 

; i 

| 

4S,4f,l44 j 

1 i • 

44,43 1 1 i 

1 13,14,23 j 

8.43,143 V 8-L> 

> i 

tt-*?-iV -»s~ ! ; 

! 

144 ' ; 

• j ; 

84,83,147 j 

' ' 

j • 

132,133,148 

14?,170,171 

44,47,48 j 

| 

• 

5*,"J7.I7 ? 

JfU-b V -r"H7 

S T D Bt-W - 4 
' CM n.m HO cot. HS run. art aist now no / voc 

t HFR 10CN COI CNO COUP CHTI HODC TTPC SCFH ICF LB/HR XVK IC XH IM tO 

42 NP NIL 

42 NP NIL 

45 NP NIL 

42 PH 8TX~ 

• 42 PH 8TX 

« " PH SIX" 

42 RFC CCKT 

42 BFC CCKT 

42 BFC CCKT 

42 HBL BTX 

42 ARC* CVtx" 

42 MCO CVTX 

43 8 BPTX 

43 CO La A 

43 CO LCLA 

43 GO La * 

43 VU A A 

43 VU CLA 

43 BFC CCKT 

43 BFC CCKT 

43 IPC cckr 

43 BFC CCKT 

43 BFG CCKT 

43 BfC CCKT 

_ _ _ 43 BFC CCKT 

43 ~ICI BRLA-

_ 43 let NtLA 

'" i "WPP C Id* " 

•-" 43 PFC LCLA 

; 43 PPC LCLA 

j 44 S CLA 

j 44 S CLA 

| 44 S CLA 

44 CA La A 

44 CA La A 

• 44 BASF a A 

1 44 BASF a A 

1 ' " 43 CA LaA 

" 43 Oc sctx 

43 UC SCTX 

43 PPC BTX 

43 PPC_BTX_ 

43 BASF CLA 

44 BB FTX 

47 BR FNC 

47 CC B'TX 

47 NO HTNY 

| _ _ 4Z__TIJ.J"HJ_. 

• 47 HNS ATX 

j 48 UC SCW 

49 FHC BATX 

J 49 FHC BATX 

! 39 FHC BATX 

• -30 FTC BATX 

SO FHC BATX 

31 BP OTX 

31 . DP OTX 

31 OF VTX 

31 DP VTX 

51 OF VTX 

1 

3 

3 

3 

i 

3 

1 

i 

3 

7 

4 

4 

t 

i 

I 

i i 

i 

2 

i 

1 

1 

i 

t 

3 

i 

~ 6 

2 

2 

1 

1 

4 

2 

2 

3 

1 

4 

2 

1 

_ 2 _ 

2 

3 

2 

3 

1 

_ 2 _ 

t 

1 

2 

1 

2 

3 

3 

1 

7 

1 

7 

1 

NV OJN FIR CNT FRC 999.999 9999 9999.999 999.99 999.99 999.99 999.99 999.99 

NV Cm jm . CNT, FRC. ft*ft-000 OOOO 0000.OOtL_000.00..000.00 0__.Ofl__IO-.00_000.00 

lf___Sj-_J-4l_CNT_l^tC__000.900_9*M _900.** . 000.00 

NV c m n m CNT FRC 000.00* OOOO 0000.000 000.00 000.00 009.00 OOO.00 000.00 

NV Cm MX CNT FRC_OOQ,001_0*09—0900.999_999.99 _ 999.99 000.00_000.00 - 000.00 

VCO N RCL CHT FRC OOO.OOO OOOO 0OO9.O0O.OO9.9O_O0O.OO_0OO.O0_O09.OO. 000.00. 

NV COR RCL CNT FRC 900.000 OOOO 0000.000 000.00 000.00 000.00 000.00 009.00 

NV cm aR CNT FRC 009,000 00^..0000.009_999.99-J)99.99-900.09--*K-.90-900.eO 

NV Cm NON CHT FRC 909.999.9900-0000.000.909.00-009.90 999.00 .900.00 000.00 

NV Cm RXL CHT FRC OOO.OOO 0*00_ 0009.909- 9OO.OO.. 990.09 009.99_900.99 _990.09. 

NV CON MX CNT FR? 09-_>99 0J»W_ 9909.999-900.09_990.00_090.00_000.00 .000.00 

NV CON RON CNT FRC 909.909 9000 0000.000 000.00 000.00 000.00 000.00 000.00 

NV t_M INC CNT FRC fff.ff f fff f ffff.ff f fff.f f fff.f f fff.f f fff.f f fff.f f 

NV cm IHC CNT FRC B.J0O_^?L_O0O4^»_B_M4,-J-023.20 010.00_-3B.20_OOO.3O 

NV CON INC CNT FRC 383.390 0804 3030.900 93f.B9 924.89 919.00 039.80 000.10 

NV Cm INC CNT FRC lM.BOB 9094 D*9____________000_l__0f4._0 901.19 901.90 

NV Cm INC CNT FRC fff.ff f mi_WTf_m_MM?-.m.?l - fW_W_fff.fl--fff.f f 

NV CON NON CNT FRC 000.000 0009 0090.999 _ 000.00 000.00 000.00 000.0* 000.00 

V Cm INC CNT FRC 13.000 0183 0033.300 034.70 00f.30 043.70 027.10 011.40 

HV Cm INC CHT FRC 4.000 0727 0043,?J9_J99.99_g23.99 _99.9__023.09_ 900.00 

V COH INC CNT FRC 4.800 0033 0003.900 003.10 004.40 044.80 OOB.BO 017.40 

NV cm INC CNT FRC 12.300 0727 OCfB.800 100.00 040.00 000.00 020.00 000.00 

NV cm INC CNT FRC 4.940 0727 __H,Q9O_!9O_O0 969.90—B90.09-020.09_ 000.00 

HV COH IHC CRT FRC 2.400 1024 0038.000 190.00 023.00 000.00 030.09 999.00 

V Cm INC CNT FRC 0.900 1024 0014.000 100.00 023.0* 000.00 030.00 000.00 

NV c m R a CHT FRC 000.000 OOOO 0000.000 000.00 90g.9o._og0.g9_999.99_ 990.00 

V COH NOR CNT FRC 000.000 OOOO 0000.000 090.00 000.00 000.00 000.00 000.00 

NV COH INC CHT FRC ???.??? ???? ?Pff.??? fff.f f fff.f f Pff.f f f??.?P ???.?? 

NV c m INC CNT FRC fff.ff f fff f ffff-W f WM t ftt.f ? in.it JM.f t fff.f f 

HV Cm NON CNT FRC ???.??? ???? ????.??? ???.?? ???.?? ???.?? ???.?? ???.?? 

NV c m RCL CNT FLH 900.000 OOOO 0000.000 000.00 000.00 000.00 OOO.00 000.00 

NV cm Nm CNT FRC ooo.ooo 0099_99gg.90g_ooo.09 999.99__Kr0.0g_990.0o_000.00 

V CON ATH CHf FRC 73.100 OOOO 0000.000 000.00 000.00 079.99 090.00 0.1.00 

NV Cm ATH CHT FRC fff.ff f ffff ffff.ff f fff.f f fff.f f fff.f f fff.ff fff.f f 

V OM ATH CRT FRC _400.000 00*9 Jftt.-ff_nf.f f Iff.ff.fff.ffJtf.f f fff.f f 

V CON ATH CNT FRC fff.ff f ffff ffff.ff f fff.f f fff.f f fff.f f fff.f f fff.f f 

V Cm MX CNT FLH 000.090 OOOO 0000.000 000.00 000.00 009.00 990.00 000.99 

NV cm RCL CRT. FRC_.000.009_ 000? .OO09.0Og_O99.&g_ 999.99 _999.09_.999.99 .999.99. 

NV SCi ATN CNT FRC fff.ff f ffff ffff.ff f fff.f f fff.f f fff.f f fff.f f fff.f f 

HV cm Nm CHT FRC 000.000 OOOO 0000.000 000.00 099.00 000.00 000.00 009.99 

NV cm ATH CHT FRC _ 2.300 l|f| 9013.9*9 984.39 928.89 .999.09 033.30 .017.70 

-__-COH-N0N CNT_ FTC_OOO.OW _00O0_0OOO.<JO0__OOl^.OO__OO9^O9_OOO.0O 000.00 999.99 

NV CON RCL CNT FRC 900.000 OOOO 0000.000 000.00 000.00 009.00 900.00 000.00 

V Cm ATH CNT FRC fff.ff f ffff ffff.??? ff?.ff fff.f f fff.f f fff.ff fff.f f 

NV c m R a CNT FRC 000.000 oooo 0000.000 000.09 000.09 000.09 000.99 999.00 

1ft CiJ(LJ*0__CNt_BIL_»_0,WO_0000_0000.000 000.00 000.00 000.00 000.00 000.00 

V CON HON CNT FRC 000.000 OOOO 0000.000 900.00 000.00 000.00 000.00 000.00 

_»_SCB . ATH.CNT. FRC 12.300_000? 0000.800 001.30 000.60 041.20 0M.fO_923.3 0 

V COH AIM CNT FRC ???.??9 9999 9?9?.?99 999.99 999.9? ???.?? ???.?? f99.?? 

NV CON HON CNT FRC 000.000. OOOO. 0000.000 000.00 000.00 000.00 000.00 000.00 

HV CON PXL CNT FRC 000.000 OOOO 0000.000 000.00 000.00 000.00 000.00 000.00 

v c m RCL CNT FRC 000.000 OOOO 0000.000 000.00 000.00 000.00 000.00 000.00 

v c m R a CNT FLH 000.000 oooo 0000.000 000.00 000.00 000.00 000.00 000.00 

NV c m R a CNT FRC 000.000 oooo 0000.000 000.00 000.00 000.00 000.00 000.00 

v c m R a CHT FRC 000.000 OOOO 0000.000 009.00 000.00 000.00 000.00 000.00 

RV SCB ATH CRT FRC fff.ff f fff f f???.f?? fff.f ? fff.f f fff.f f fff.f f 999.99 

V ABS ATH CNT FRC fff.ff f ff?9 ff??.??? 999.9? fP?.f f fff.f f fff.f f f??.f f 

NV c m PXL CHT FRC 000.000 OOOO 0000.000 000.00 000.00 000.00 000.00 000.00 

V Cm ATH CNT FRC 81.100 OOOO 0000.000 090.00 000.00 100.00 000.00 000.00 

NV CW BLR CHT FRC 999.999 999? 99^7.999 999.99 999.99 999.99 999.99 997.99 

XCL • 

999.99 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

0*0.00 

-0*9,99 . 

000.00 

900.99 

ftf.17 

914.39 

913.39 

.900.39. 

fff.f f 

000.00 

OOf.30 

923.90 

004.49 

929.99 

929.90 

023.00 

_*SiOJ. 

000.00 

000.00 

fff.f f 

fff.f f 

fff.f f 

000.00 

000.99 

000.00 

fff.f f 

fff.f f 

fff.f f 

0*0.00 

000.90-

fff.f f 

.090.99 . 

999.90 

.999.99 . 

000.00 

fff.f f 

000.00. 

0*0.00 

000.00 

000.00 

999.99 

000.00 

000.00 

000.00 

000.00 

000.00 

000.00 

???.?? 

?99.?? 

000.00 

000.00 

999.99 

M OW sc* tar •« ' */* r 

NUMB NCP HO 

99.999 

-00.000 

00.000. 

00.000 

00.000 

00.000 

~90.000 

00.999 

90.000 

_99_9J"_-

00.000 

09.990 

»?.m 

3.123 

3.934 

2.923. 

ff.ff f 

00.009 

2.8-f 

3.900 

2.304 

3.000 

3.000 

8.000 

_!._o_! 

00.000 

00.000 

ff.ff f 

ff.ff f 

ff;*f f 

00.000 

09.000 

2.000 

ff.ff f 

ff.ff f 

ff.ff f 

00.099 

.09.000. 

ff.ff f 

.00.999. 

99.0001 

oo.oopj 

09.000 

ff.ff ? 

00.000 

00.000 

00.000 

2.000 

??.?99 

00.000 

00.000 

00.000 

00.000 

00.000 

00.000 

??.??? 

??.??? 

00.000 

2.000 

99.999 

U 6 • **"» iw > 

143,146,173 

1 * 

ITS 

174,177,178 

X 49,30,31 

. 

129,129,179 

X 32 

ue-** 

179,180,181 

34,33,182 7~_.- -

JI'J-V I - * • 

X 11,12,33 

183 

184,183,184 

IR7 

13,14,103 

34,33 Uft-H t HC? 1 ^ 0 

M.t>— ' 

184,183,18? JTg'V^ __o # 

1?0 

34,lfl,lf2,lf 3 »?-. ' *r> 

34,If4,lf3,l?6 . < ^* y 

34.iP7.iPB 

X 34 S.--<y,7 i »f5" 

34,84,83 

199 U «** - • 1 \_ 

200,201,202 

33,36,57 

J *» 

1 ; 

; 

1 

1 

; 

• 

1 

1 

1 

't ' 

1 j 

* > 

:. 
I MR LOCN 

St IP VTX 

32_ AC FOIA 

~ 32 BP BIX 

32 RH BPTX 

33 BB FIX 

34 t5 Fix 

33 USS M M 

34 USS M M 

37 Aii JIL 

37 AH JIL 

138 AH JIL 

38 K HTX 

38 BC HTX 

38 KO BPA 

_M___BBIR5 

COL CHD 

NV 

NV 

NV 

NV 

NV 

NV 

V 

V 

NV 

NV 

V 

NV 

V 

V 

v 

38 

38 

38 

3? 

!60 

40 

40 

40 

46 

40 

40 

P_ 

OOijJ 

62 

42 

43 

44 

43 

43 

43 

43 

43 

43 

43 

63 

43 

43 

43 

63 

43 

43 

43 

44 

44 

44 

47 

i 40 

' 48 

4? 

6? 

70 

10 

USS NPA 

U88 N1PA 

few* NIL 

CX M M 

AP PFL 

CC BITX 

CC BITX 

NP p a 

ALC K A 

ALE PLA 

HNS TCTX 

VU CLA 

LCP m w 

S BPTX 

9 BPTX 

UC IUV 

HF UHC 

BP. HTR 

BP HTH 

BP NTN 

BP NTN 

RH BPTX 

RH BPTX 

RH BPTX 

RH BPTX 

RH BPTX 

CYRO ALA 

CYRO ALA 

CYRO ALA 

CYRO ALA 

CYRO ALA 

CYRO ALA 

(IBS M M 

USS M M 

CMCV RCA 

BB FTX 

RU aA 

HOB PPA 

BASF a A 

BASF a A 

OS BPTX 

OS »tMNV 

V 

CQUT 

SCR 

cm 

CON 

cm 

CON 

COH 

cm 

cm 

cm 

cm 

cm 

COH 

cm 

SCB. 

cm. 

cm 

cm 

v 

NV 

NV 

NV 

NV 

NV 

NV 

NV 

NV 

NV 

NV 

NV 

NV 

NV 

V 

V 

NV 

NV 

NV 

V 

V 

V 

NV 

V 

NV 

NV 

NV 

NV 

NV 

V 

V 

iiv 

NV 

V 

NV 

NV 

V 

NV 

V 

NV 

MV 

SCB 

cm 

cm 

CON 

cm 

cm 

cm 

cm 

cm 

COM 

cm 

cm 

cm 

cm 

cm 

cm 

cm 

cm 

cm 

ABS 

cm 

cm 

cm 

cm 

cm 

cm 

cm 

cm 

cm 

cm 

cm 

cm 

cm 

cm 

cm 

SCB 

cm 

cm 

cm 

cm 

COH 

_:» 

CNIL HOPt 

ATH CNT 

n__o«L 

FLR CRT 

FLR CNT 

MX CRf 

ATH CHT 

ATH CNT 

ATH CNT 

ATN BTH 

ATH CHT 

ATH CHf 

ATH BTH 

ATH CHf 

RCL_CNL 

MM BTH 

ATH BIR 

ATH CHT 

MM CHT 

BLR CNT 

MM dif 

Ra CNT 

MM CNT 

BLR CHT 

MM CNT 

BLR CNT 

rta CNT 

MX CNT 

FLR OIL 

FLR CUT 

MM CNT 

MX CNT 

RCL CNT 

ATH CHT 

ATN CNT 

ATN m i 

ATH CHT 

FLR CHT 

FLR CNT 

FLR CNT 

ATN CNT 

ATH CHT 

RCL CNT 

ATN CHT 

ATH CNT 

MM CNT 

ATH CHT 

ATN CNT 

ATH CHT 

ATH CHT 

INC CHf 

N m CNT 

ATH CNT 

ATH CNT 

FLR CHT 

ATH CNT 

ATH CNT 

MH CNT 

•»*« CUT 

I Ilk 

IRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

_Rfff.fff ffff ????.??• tVf.f? fff.ff fff.ff fff.ff fff.ff 

fff.fff ffff ffff.fff fff.ff _m.-___M_i__m.-_-_m.tt 

fff.fff 

00.009 

00.000 

ff.fff 

ffff ffff.fff fff.ff fff.ff 

fff.fff ffff ?m.p?t fff.ff fff.ff 

000.000_JJ009_ 0*09,999 _999.00_ 009.90 

906.000 OOOO 0000.000 000.00 999.99 

fff.??? ???? 9???.??? fff.ff fff.ff 

fff.fff _fff? _ffff-tf___itt .n_ ttt.n 

437.999 001? 0123.000 002.00 001.fO 

fff.fff ffff ffff.fff fff.ff fff.ff fff.ff fff.ff fff.ff fff.ff 

0.2K_90*9_909j|.99J|_JMHJ.99_-KHJ.9g_.87«.'r9.992.49. 921.30.990.99 

ff fff.ff fff.ff fff.ff fff.ff fff.ff fff.ff TT.YTT 

ffff .tt __ tff.ft -ftf.tf .fff .tt.-ft.tt_ttt.ft -ttt.f t-_ft_m 

fff.ff fff.ff 

fff.ff tff.ft 

O99.oo_—goo.ggooo.oo 000.99 

fff.ff fff.ff 

-t-f__t_ tff.ft 

0?2.40 003.80 

???.?? 

fff.ff 

000.00 

000.00 

???.?? 

fff.ff. 

OOI.to 

fff.ff 

fff.ff 

fff.ff 

tff.ft 

000.00 

000.00 

tff.ft 

ff.fff 

ff.fff 

ft.tft 203 

000.09 3.122 X 30 

.2.000-

40,37,38 

FRC 4.3O0_.000O__9OO9,gg 99g.M_^Og.Og_g_f.g9__99.99_021.00_999.00—2.909 ___49.B9.8L 

FRC 

FRC 

--«_ 

FRC 

FRC 

_fRFRC 

FRC 

FRC 

FRC 

FRC 

F_C 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

TRC 

FRC 

FRC 

FRC 

FLH 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FLH 

FRC 

tut 

.OOO.OOO. 

009.999 

_____ 

_0099.O99__999.99 

9999.99 999.99 

.089,99__999.99_999.9Q_999.99_999.99__99.999 

009.99 990.09 999.99 999.99 999.99 99.900 X 40,82,03 

__-___t-__9_IO 024.70 OOfl-O-^—3____l 

•9.84.83 if * ___ 

ffff.ff fff.ff fff.ff fff.ff fff.ff 

009.090 0909 0009.999 999.99 909.00 990.99 990.99 

____J___M3__.P_B.3-___M.49 ___9aO-JMU.t--.03f-TO.. 

099.900 0009 9999.999 999.99 999.00 999.90 999.99 

909.900 0090 9999.999 999.90 999.99 999.99 999.99 

.OOB,O09_99__ __99_.9N-.B-9.__- 909.99_909.99_900.99-

9999 

2003 

9999. 

OOOO 

rm. 

0133 

340.000 1238 

000.900 OOOO 

_ttf_fft_!ftf.. 

009.990 

999.999 

_ *.***. 

4.fOO 

009.999 

..0*9.0** 

009.999 

.fff.fff. 

124.499 

fff.fff 

18.3*9 

2.499 

178.399 

132.900 

0.100 

000.000 

7.400 

1.700 

000.000 

72.fOO 

?4.200 

???.??? 

f??.?ff 

fff.fff 

fff.fff 

fff.fff 

1.300 

ft?.??? 

Pff.tff 

13.400 

1.300 

.fttt.tft 

0114.209 

2879 

2870 

1316 

9013 

1034 

928f.999 

9941.000 

1300.000 

91-f 

1483 

oooo 

0044 

02f3 

ffff 

ffff. 

ffff 

0332 

ffff 

ffff 

0904 

0143 

999.999 7999 

3448.000 097.30 

0000.009 999.90 

jttt.tfL._tt.n_ 

9000.900 090.90 

0999.999 999.99 

mg.W9Q3T.7 0 

0032.480 948.19 

9999.999 999.99 

.9999.999.9999.99. 

9000.009 990.99 

fff.f f 

Jtt.tt -

913.19 

fff.f f 

199.99. 

199.99 

097.80 

990.39 

100.00 

000.00 

021.fO 

100.00 

000.00 

002.39 

013.70 

ftf.t f 

tff.f t 

fff.f f 

fff.f f 

fff.f f 

009.40 

tff.f t 

fff.f f 

000.80 

014.60 

0000.490 

0*00.000 

0012.000 

0013.409 

0099.000 

0026.300 

0148.800 

fftt.ftf 

020.80 000.00 044.70 

009.99 000.00 900.00 

Ht.n_itf__t ttt.n. 

000.09 900.99 990.99 

000.00 099.99 999.9* 

929.39 .999.99_g44.79 

930.09 993.49 941.49 

999.99 999.99 999.99 

999.99.. 999.99—900.00 

990.99 999.99 099.99 

tW.t t fff.f f 

tw.n . Wf.f t 

99f.39 934.39 

fff.f f nt. n 

933.30 .990.00 

033.00 099.00 

023.99 000.09 

001.00 074.30 

021.20 000.00 

000.00 000.00 

016.00 014.30 

024.7* 000.00 

009.99 909.99 

903.10 047.00 

013.30 044.00 

fff.ff fff.ff 

ftt. w nt. n 

fft.ff tff.ft 

ffff.tft 

ftff.tft 

0001.BOO 

ffff.tft 

0902.100 

0003.400 

fft.ff 

019.30 

fff.ff 

fff.ff 

090.40 

000.40 

fft.ff 

037.90 

ftf.tf 

fff.ff 

009.00 

000.40 

nt. n 

fff. W 

013.30 

ttt. n 

033.30 

033.3* 

043.09 

991.49 

943.99 

99".90 

034.40 

041.fO 

089.00 

008.10 

030.00 

tn.t t 

ttt. n 

nt. n 

ttt.t t 

tn.t t 

021.70 

nt. n 

ttt. n 

066.10 

077.60 

nt.n 

000.00 

018.30 

009.99 

999.99 

999.00 

012.30 

000.00 

nt.n 

000.09 

999.9* 

912.09 . 

993.99 

999.99 

990.00 

900.90 

nt.n 

nt.n 

Olf.lO 

nt.n 

013.49 

913.40 

011.80 

021.00 

013.80 

0*0.09 

013.30 

013.40 

009.99 

Olf.BO 

010.30 

nt. n 

nt. n 

nt. n 

nt. n 

nt. n 

901.10 

nt.t t 

nt.t t 

032.8* 

020.60 

nt. n 

909.99 

990.99 

990.90 

999.99 

9*0.99 

999.90 

099.00 

nt.n 

900.99 

909.99 

. 999.00. 

909.99 

999.99 

999.00 

990.90 

0*0.90 

nt.n 

000.00 

000.90 

990.99 

999.99 

909.00 

000.99 

999.99 

909.9* 

099.00 

999.00 

990.99 

fft.ff 

nt. n 

nt. n 

nt. n 

tn.t t 

990.00 

tn.t t 

nt.t t 

000.70 

000.80 

tt-tt t 

00.09* 

3.714 

09.999 

00.900 

09.999 

7.tW 

99.900 

n.tn 

99.900 

09.900 

7.743 

f.044 

00.000 

99.0*0 

90.000 

n.tn 

n.nt 

2.207 

n.tn 

13.000 

13.000 

8.829 

2.033 

4.f09 

99.9*0 

3.322 

f.012 

00.000 

2.191 

3.331 

n.t n 

n.t n 

n.n t 

n.n t 

tt.n t 

2.f71 

tt.n t 

ft.f?? 

3.041 

2.?20 

4* 

2*3,294,297 

X 41,42,43 

IfS,If4,200 

41,42,43 

X 44,43,44 

2n,7f,84,83 

219,211,212 

213 

X 47,48,4f 

4,3,4 

X 41,42,79 

X 74,73,74 

X 71,72,73 

?99.99 999.99 99.999 

977.97 777.77 77.797 

IPO 

28,2?,30 

X 77 

X 78 

PP9.99 999 

x a ara, 

•*UH» N_» 

99.779 

"*** HOT 
P.24 

-I S 8 

RB 

©

 ; 

S 

5 ( 

s is 

ss 

•h" 

i 

•g'R-

• -i n ( ( -

SS 

5 

© 

K 2 5 

I R S 

_ ". -_ 

5 S 2 

"• "1(8 8 8 8 

(((((8(888888 8 8(888 8 

B tESU!liEiEEEEEEiEESiii E 

wjK,,aaaaaaaaaaaaaj,aaaaaaa a 

2*(888888(8((((((|8(,,"',,,,8 

_,(888888(S( 

88888(888((8((( 

888888888(88((( 

S3 

K 

O" © © © © 

(8888 

(8888 

R 2 

NN IS ^. 

8 ^is in S 

R S R •_ R* 

- fl • » 

CM n o is r> 

s_(f * 

© K • o © 

( ( ( 8 (' 

(((8( 

S3SS8 

o © © o © 

88888 

8888o o 8 mnimmnnnnv^nnn 

88: 

(888888(8 (!(((((;8 (8388888 8(888SS8888(888((8((((8888(((8(888SS 

IIIIIIiilEIi 

88888(8888(8 

EEE 

( ( ( 

tnn 

(888 8 

tun 

(((8 ( 

iiliE!iEiEEEEEEiE8ESlsMSEiSSS 

(_88888(8((((((8(88888888(888888888(888((8((((8888(((8(888_ 8 

(888888( 8 

Z ai a * a . • a ai a a 

"UlIiliEi 

5888888( 8 

CJ * V* • • • • a a • • a 

"EiiiiiiEi 

ilimiilBl 

88888(8888(8 

nt 

( ( ( 

&§§i_mH§§§ 

(8888 ! 

I 

• ! 

(888888( 8 

• ia a « a • «- a a 

EEEEEElESSEi 

d(((^('8(888 8 

* i a a ai a a> ai a a a 1 a a 

BinsiEi___ 

d(((((8(82g 8 

- • • a ai a a •• • a • • a 

mEE§£___§ 

(((((S(888 S 

•a a a • • • • . a a ai a a 

mEEfS-_8l 

81 

(! 

8 

• a a 

"iiiiii 

8 8(88 8 8 

i a ai a a ai a a 

: 5 sEiliI 

88(888 8 

• a • • a ai a a 

/"Slim 

888(888 8 

• a a ai a a ai a a 

fsEiii i 

illEIIii 

8 8 888(8888(8((((8 8 8 88((8(888 8 8 

a«aa*iaa«-aaa-aaa>aaaa a a aaa a a a a * • • • 

8g888(888((8((((8S88(((8(8888 § 

88888(888((8((((8838(((8(888§ 8 

iiliiEili^iBBi§!§iBi^i§ii§ 

iililiililiiiiliiiiii^-illliilliilllillllillllilillll^ 

f i ' I : i I ' I ; • i ! I ' 

• *( ! mmnmminn*in 

itmntnmnmn 

— 4a> a fa a • i a • a ia a a •• a » «• • 9 •• • 

-'"MiUiEiEEEEEEir 

8 ( ! 

3 8 ! 

i^i 

a ia .a 

7 8 

a a • • • a >• a 

^".Efiii 

___________ _ 

ii 

a . a a a ia a a a a a a a 

iilliliiiEt i 

_!_!£_!_! J. _!_!S.i._!_! 

©_-©©©».©OOV©©0.».©»©00 0 (©8((((8S-2-Ec_s___8 : E©5S*a>SD.5©ooKS(o(ooo S 

__l 

t»"l.t . (XI . UUUUUUUUWUC I 

^-___________5____ -

.|SSSSS-5SS5|SSS5S5SSS55S-SSSS--SSSS5SS 5 

_§;g__-__g_^;s__i-_ 

e|-_________§_ll__li 

( ( ( 

a . a a 

EEE 

_ _ _ 

**_ 

______»____= • __--$ _ 

8SS 

u S u 

» » » 

,__!__ _ 

BIBB BBB 

»•»•»« 8 S I 

ii__!i__l,_ l 

BBBBBBBBBBBB SSS 

u u S 

a a a a a 

EH" * 

_£___ 

k k k k k 

« S £ « a 

2SS8 5 

a u u in u 

! _ S-S___'5SSS'sSlSS:SSsisidf-d ^ 

5-siss 

I 

_.,5-- -

gj-_-**•_ : » 

tB-tgfciE 

_ 2 _ * » » » » _ » -» _ 

NMI««NNn«HM N 

K K M K K K K I 

iiiii 

§ i § § § 

tf i_ _? ^ t 

k ta. lb b U 

S

^*-(->^-^ta»^a^* — »>a>^^H4»^* — _-

gg___-___S5____5_ _ 

____ _ 

____ _ 

mn 9 9*9 9 

nm 

__£__: 

k k _• k k I 

C U — — -

S£S_!= 

BBsSSi 

____ _ __ 

01 01 9 'gi|"siiBS|g 

• © © _• *"' ->'•* — — —i •«•«• •NNNNNNNN*int>?TTttnnnii|l'inp n N N iv N. N. r«if* is •* ft NI N K N is }_ N r- ft t~r. -I* r« N r« r« N rk r« K K H K N K K N K 'MkMi > N N 

C-9 

_ = E5____S5lls2^_l- si

5

-_ii-§ s 

RRRSSSSSfcfcfcRSfcfcrSS 
• 

ii 

-81 81 Bl 81 81 Bl Bl Bl 81 81 82 82 82 82 82 82 84 84 83 S3 84 B4 87 

888 

888 

BBB 

NFR LOCH ca cm Four CHTL 

CC BCTX CC BCTX CE BCTX BR BR BP BP BP rr 

OSI 

USI 

HTX 

HTX 

HTX 

HTX 

HTX 

HTX 

BPTX 

BPTX 

CO LCLR CO LCLA 

CTH BRLA 

ETH BRLA 

PPC LCLA 

PPO LCLA BP BP 

- BP BP BP BP BP 

OCC 

UCC 

UCC 

VTX 

VTX 

VTX 

VTX 

VTX 

VTX 

OTX 

STX 

BTX 

STX 

888 -WM BRLA 

888 EMM MR,* 

888 EMM BRLA 

BBS EXON BRLA 

888 CXON BRLR 

888 TXEH 

888 TXCH 

BBB TKEH 

888 TXCH 

888 TXEH 

f ff 

999 

999 

999 

999 

999 

999 

999 

999 

999 

999 

999 

999 

999 

999 

999 

999 

999 

999 

in 

777 

9 1 9 

-A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A .A 

A 

A 

A 

A 

A 

A 

x\ 

'»l*# w\ .! 

LTX 

tTX 

LTX 

LTX 

LTX NS NS NB Y3 Y3 TS NS NS NS NS TS TS NS NS NS NS NS T3 MS HS MS 

W 

2 

t 

1 

2 

1 

1 

I 

1 

1 

3 

2 

2 

1 

3 

1 

3 

1 

• 

2 

7 

4 

1 

1 

7 

3 

4 

3 

2 

4 

4 

2 

3 

1 

7 

10 23 I t 

1 

1 

If 13 

3 

1 

1 

2 3, fl 

10 

1 

1 

1 

1 

1 

2 

t 

« 

2 

\ 

HV NV 

V NV NV NV NV NV NV NV NV NV NV NV NV NV NV NV NV 

V NV NV NV NV NV NV 

V 

V NV NV NV 

V NV 

V NV NV NV CO CO CO CO CO CO CO CO CO CO CO CO CO CO CO CO CO CO CO CO CO CO 

COM 

CON 

CON 

CON 

CON 

COH 

CON 

CON 

CON 

CON 

CON 

COH 

COH 

CON 

CON 

CON 

CON 

SCB 

SCB 

CON 

CON 

SCB 

CON 

CON 

COH 

CON 

CON 

CON 

CON 

CON 

CON 

CON 

COH 

COH 

COH 

COH 

COH 

CON 

CON 

CON 

CON 

CON 

CON 

CON 

CON 

CON 

CON 

CON 

CON 

CON 

CON 

CON 

CON 

COH 

CON 

COH 

sen 

COH 

cmi 

••*. - . — 

Ra 

HON 

RCL 

RCL 

RCT 

FLR 

FLR 

FIR 

FIR 

FLR MX 

RCL MM 

NON R a MX 

IRC 

ATN 

BLR 

INC 

INC 

ATN 

ATN 

ATN MX Ra 

ATN MM 

FLR MX 

FLR 

ATH Ra 

ATH Ra 

HOR MX 

ATN 

ATH MX Ra 

INC 

INC 

ATN 

ATN 

ATH 

ATN 

ATH 

ATH 

ATH 

ATH 

ATH 

ATH 

ATH 

ATH 

ATN 

ATH MH Mn 

f.*H 

NODE 

CHI 

CNT 

CNT 

CNT 

CRT-

CRT 

CNT 

CNT 

CNT 

CHT 

CHT 

CHT 

CHT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CRT 

CNT 

CNT 

CNT 

CHT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CHT 

CHT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CHT 

CHI cm 

•~»u 

TTPE 

FSC 

FRC 

FRC 

FRC 

FIN 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FLR 

-FRC 

FRC 

FLH 

FLH 

FRC 

FLH 

FRC 

FRC 

FRC 

FRC 

FLH 

FLH 

FRC 

FLH 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

FRC 

fivr 

rr.r. 

St.. *l 

000.000 

SCF 

OOOO 

___—L4_ —•—•—• —• —, —.—L _ 

900.000 ^JOOV 

000.000 

900.000 

"000:000 

10.300 

2.300 

9:000 

13.000 

fff.ff f 

OOO.OOO' 

OOO.OOO 

000.000 

099.900 

9*0.000 

999.900 

-nt:nt-

43.000 

0.199 

—SA.TOt-

14.700 

80.000 

3:3** 

tn.tt t 

000.000 

ooo.ooo -

tn.t n 

009.900 

-nt:fn-

000.000 

tn.t n 

tn:t n 

000.900 

tn.t n 

000:000 

000.000 

090.000 

tn.tf t 

tff.ft t 

000.000 

000.090 

tn.tt t 

ttf.t n 

tn.t n 

tn.tf t 

tft.ff t 

ttt.ff t 

999.999 

000.000 

ttt.t n 

tn.n 9 

tn.n ? 

???.??? 

999.999 

99?.??? 

?99.999 

000.000 

799.999 

979.979 

•?•?•? .77 7 

OOOO 

0009 

OOOO 74 

701 

1908 Mf 

99?? 

• OOOO" 

oooo 

OOOO 

OOOO" 

9999 

9999 

-tnt-

4 

834 

-128-

1444 

f 

- n m t 

0*00 

-000*-

ffff 

0090 

-ftft-

0000 

ffff 

ffff 

000* 

ffff 

ooo*

-

9999 

900* 

t t n 

t t n 

0*09 

oooo 

ffff 

t t n 

ffff 

t t n 

t t n 

??n 

??n 

oooo ? m 

ffff 

n?? 

? t n 

t t n 

??w 

???? 

oooo 

9999 

7979 

7717 - . 

LB/HR 

0900.000 

-0000.0*0"-

0000.000 

0000.009 

-0000:099" 

13.200 

3.200 

- 34:899 

4.409 

?tn.? n 

-00*9:9*©-

9900.000 

9000.000 

-0000:000 

9999.099 

9099.999 

-ttn:t n 

lf.000 

' 0.330 

—-8;4fB-

. 0.100 

If.4*0 

28.800 

tnt.t n 

0000.000 

-0000:000' 

ftn.t n 

9099.900 

-ffff.fff " 

9999.990 

ftn.t n 

ffff .nt • 

9900.900 

ftn.t n 

- oooo.ooo-

9090.000 

0000.009 

3.f99 

3.299 

0000.000 

0009.000 

ftn.tf f 

ttn.f n 

3.209 

0.?00 

2.300 

tw.t n 

ffff.fff 

0090.000 

ffff.fff 

ttn.n ? 

2.080 

0.420 

0.420 

9999.??? 

0.001 

0000.000 

999?.??? 

9799.979 

9799.97 ? 

IVOC 

0C0.00 

000:09 

900.90 

000.00 

000.00" 

8.30 

32.00 

-87:99-

t.to 

nt.t t 

•9*0.09-

9*9.99 

900.90 

900:00 

009.9* 

800.00 

tn.n-

13.90 

27.30 

—2:4 0 

40.80 

3.10 

72-90" 

tn. n 

000.0* 

000:00 

tn.n 

000.99 

-fffiff000.00 

nt. n 

-tn. n 

000.00 

tn. n 

900:99' 

000.99 

990.99 

nt: n 

tn. n 

990.00 

099:99 

nt. n 

tn. n 

tn. n 

nt. n 

ttt. n 

nt.t t 

ttf.t t 

990.00 

tn. n 

tn. n 

8.30 

nt. n 

tn.t t 

nt.t t 

tn.t t 

000.00 

???.?? 

999.99 

999.9 9 

xc 

OOC.CO 

009:0*-

990.00 

009.00 

000:00 

4.30 

23.90 

-31:70 " 

0.39 

tn. n 

900.00 

009.99 

099.90 

-*09:90 

090.00 

000.00 

-nt.n 

1.30 

21.20 

IN 

000.00 

-ooo:*o~ 

000.00 

000.00 

IH 

000.00 

-ooo:oo"" 

900.00 

990.00 

000:99 ~*90:00 " 

0.?9 

31.00 

-*3;9 0 

14.30 

nt.t t 

999:90 

999.99 

999.00 

'•90:99-

0*0.90 

899.99 

~tn: n 

to.oo 

41.39 

—8.-8*—02:40-

40.80 

33.90 

-33.3 0 

tn. n 

000.00 

090:00 

tn. n 

000.00 

It .30 

2.20 

33.30" 

tn. n 

0*0.00 

84.40 

23.30 — 4:80" 

73.20 

tn.t t 

-909:99 

999.99 

90f.*0 

-990:00' 

•09.99 

900.09 

-tn.n 2.f9 

9.9 

—o-t o 

49.39 

1.49 

-33.40 " 

fff.ff 

000.99 

"000.00 -990.99' 

tn.n 

999.99 

tn.n 

800.00 

-nt.n nt.tt ntiff~ 

000.00 

nt. n 

tn: n 

000.09 

tn. n 

000.00 

009.99 

990.09 

tn. n 

tn. n 

009.09 

000.09 

tn. n 

nt. n 

tn. n 

nt. n 

nt.f f 

nt.t t 

fft.t t 

000.90 

tn. n 

tn. n 

tn. n 

nt. n 

tn.t t 

nt.t t 

tn. n 

099.90 

f??.?? 

999.97 

•'99.9 9 

900.00 

nt. n 

090.00 

nt. n 

-ftt.ft • nt-n-

000.80 

tn. n 

090:00" 

000.00 

0*0.90 

tn. n 

fff.ff 

000.00 

099.99 

nt. n 

tn. n 

nt: n 

tn. n 

tn. n 

nt.t t 

tn.t t 

099.90 

nt.t t 

tn. n 

fff.ff 

ttt. n 

tn.t t 

tft.t t 

ttt. n 

090.00 

???.?? 

9??.9? 

7*9.7 ? 

090.00 

tn. n 

"000.00" 

099.00 

900.00 

fff.ff 

nt. n 

099.90 

900.99 

tn.t t t n 7t 

tn. n 

tn. n 

nt. n 

tff.f t 

ttt. n 

999.99 

nt. n 

nt.f t 

tn. n 

tn. n 

fff.ff 

nt. n 

tn. n 

000.00 

t??.?? 

999.99 

99c.9 7 

to 

000.00 

000.00 

000.00 

000.00 

090.00 

0.0 

0.9 

9.9 

0.0 

nt.f t 

099.00 

099.99 

099.00 

" 009:00 

000.90 

090.00 

nt. n 

3.40 

0.9 

- 9.0 

9.0 

42.70 

0.0 

tn. n 

000.00 

000.00 

tn.n 

000.00 

-fff.ff 

000.09 

tn. n 

nt. n 

900.99 

tn. n 

000.00 

999.99 

000.00 

nt. n 

fff.ff 

000.00 

900.09 

tn. n 

nt. n 

nt. n 

tn. n 

tn. n 

ttf.t t 

ttt. n 

009.00 

tn. n 

tn. n 

nt. n 

fff.ff 

nt. n 

ftt.f t 

nt.f f 

000.00 

???.?? 

999.99 

990.9 7 

2CL 

000.00 

000.00 

000.00 

000.00 

090.99 

0.00 

0.00 

0.99 

9.99 

fft.f f 

990.00 

009.00 

000.99 

099.00 

099.99 

090.00 

nt.n 

0.20 

0.09 

••99 

9.99 

0.00 

0.99 

nt. n 

000.00 

099.00 

tn. n 

099.99 

nt: n 

999.99 

tn. n 

nt. n 

909.99 

tn. n 

990.00 

999.00 

000.00 

nt. n 

ttt. n 

000.00 

000.90 

tn. n 

ttt. n 

tn. n 

tn. n 

nt. n 

tt?.t t 

???.?? 

990.99 

m.? ? 

fff.ff 

fff.ff 

???.n 

???.?? 

???.?? 

???.n 

900.00 

???.?9 

999.99 

999.9 9 

NUHB NCF NO 

00.000 224,227,228,229 

09.000 

00.000 

00.000 X 09,90,91 

00.000 

2.19. 

4.0B4 

3.479 

2.3?4 

??.??? 230,231,332 

99.909 

99.900 233 

00.099 

00.990 214,213,214,233 

99.909 

00.000 34,33,217,233 

ff.fff 

2.073 X 

4.431 

2.342 

4.*7t X 

3.021 X 

4.480 

n.t n 

00.000 

09.000 

n.t n 

00.099 

n.nt 

00.009 

n.t n 

n.t n 

90.000 

n.t n 

90.099 

99.999 

99.999 

n.tt t 

n.n t 

90.900 

90.990 

n.tt t 

n.n t 

tt.n t 

n.t n 

tf.ft f 

n.tt t 

n.tt t 

00.000 

n.t n 

tt.t n 

n.n t 

tf.ft ? 

??.??? 

??.??? 

ff.fff 

00.000 

??.?«"* 

97.99S T C TT*"* 

I • 

I 

M I- i>a-» caw Am*air no: 999.999 9999 9999.99? ?9T.?? 999.99 ???.9 999.9

9 99.999 i 

ro 01 
1 * 

f ff A N. 

f t? A NS 

f ff A NS 

nt A NS 

i tn—A- NS 

| tn A RS 

f ff A RS 

, 

' 

f tf A NS-

f tf A NB 

f ff A NS 

- fff A NS 

f ff A NS 

tn A NS 

- tn A NS 

f ff A TB 

f tf A TS 

— tn - A TS 

tn A TS 

tn A TS 

-fff A- NS 

nt A TS 

f tf A TS 

— nt - A TS 

tn A NS 

YTTTTTTT 

CHEHHO 1 

CHEHHO 2 

CHQMO 3 

O_MN0 4 

Cl CHEMHO 3 

• CHEHNO 4 

E — CHEHNO 7 -

' CHOBRJ 8 

CHEHNO f 

CHEMHO 10 

CHEHHO 11 

CHEHNO 12 

-—•CHEHNO 13 

- CHEHNO 14 

•• - • -CHEHNO IS 

• 'CHEHNO 17 

CHEHM* IB 

• CHEHM1 I f 

—• - CHEHNO 20 

CHEHNO 31 

CHEHNO 22 

CHEHNO 23 

CHEHNO 24 

CHEHNO 23 

CHEHNO 2ft 

CHEHNO 27 

CHEHNO 28 

OCHNO 29 

CHEHHO 30 

CHEHM) 31 

CHEHNO 33 

CHEHNO 33' 

CHEHNO 34 

' •'.*•- CHEHM) 33 

1 r_ CON ATH I CO CON ATH 1 CO CON ATH t CO CON ATH 

—1-CO-tON ATH-

1 CO CON ATH 

4 CO CON ATN 

— 1 CO CON ATH 1 CO CON ATH 1 CO CON ATH 1 CO COH ATH 1 CO CON ATH 1 CO CON ATH 1 CO CON ATH 8 CO CON R a 1 CO CON INC B CO CON INC 2 CO CON INC 1 CO CON INC 1 CO COH ATH 1 CO CON ATN 4 CO SCB ATH 1 CO COH ATH 3 CO CON ATN 

__pa^V__i __*_._M__a"< 

ACETALBEHTBC 

ACETIC ACIB 

ACETIC AWTTTMIDE 

ACETONE 

CNT 

CHT 

CNT 

CNT 

FRC 

FRC 

FRC 

FRC 

997.997 

999.999 

fff.f? ? 

tn.ttf 

-CNT—fRC flf.ll f 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

CNT 

ACETONE CTAN0HY0R1H 

ACETONITRILE 

— ACETOPHEHONE 

ACROLEIN 

ACRYLIC ACIB 

ACRYLIC ESTERS ' 

ACRYLONITRILE 

ABIPIC ACIB 

ABH-NITRILE 

ALKYL BENZENE 

ALLTL M.COK0L 

ALLYL CHLORIDE 

ANILINE 

BUTABIEHE 

1-BUTENE 

CAFROLACTUH 

CARBON BISULFIDE 

CARBOH TTrrtACHLtiRlBE 

CH-OROBEI_EN_ 

CHLORODIRUOROHETIMNE 

CHLCROFRENE 

CUCME 

COHEHE HTDROIIRUXIDE 

CiTLOHElUNE 

FRC 

FRC 

FRC-

FRC 

FRC 

FRC-

FRC 

FRC 

FRC 

FRC 

FRC 

FRO 

FRC 

FRC 

FRC" 

FRC 

FRC 

FBC-

FRC 

..•. . 

CTCLTCXAM-C/CTaOCXMIOL 

BICHLOROKtn-NE 

BICMXRODiaUOROHETHANE 

•IHETHTL T_-tT1ITHALATT: 

IIHITROTXUEKE 

BlFt-MYLAMON-

tn.t n n t .n t 

9977 

9999 

??ff 

fff ? 

ffff 

n t t 

-tn. nt ttn-

ftt.ff t 

ftf.ft f 

- tn «nt-

fn.t n 

nt«nf 

ntst n 

009.000 

tn.t n 

tnitn

-

tn.t n 

tn.t n 

-"9:24 9 

9.929 

4f.490 

77:320 

40.370 

t t n 

t t n 

ffff 

t t n 

t t n 

ttn-

9099 

t t n 

ttn-

t n t 

t t n 

1373-

9 

9 

8 

• 

. . .. 

9977.97V 

4.300 

9.700 

9.100 

999.99 

999.99 

9??.?? 

?n.?? 

999.77 

999.99 

ft?.?? 

m.?? 

997.77 777.79 

977.77 779.99 

999.99 999.9? 

???.?? ???.?? 

—. —.—L — ______ _fc__ _____ ___• _fc_._k _._. _____—___. • 

9n)9I999.9? fff.ff fff.ff999.9 9 

0.420 

0.3*0 

• mtiH9' 

ffft.t n 

1.000 

—0:90 0 

0.100 

13.900 

-ftn :tn-

9999.900 

tnt.t n 

tn. n 

nt. n 

nt. n 

nt. n 

-nt:n—nt:n -

nt. n 

tn.t t 

nt.t t 

tn. n 

fff.ff tn. n 

nt.n tn. n 

- fff iff —^?n^n -

nt.n tn. n 

tn.n tn. n 

-nt:ff tft;n fff.ff ?t?:n" 

tn. n 

tn. n 

-nt:n-

0*0.0 * 

tn. n 

___•___. _ A___L^______I • __•1 • 

T9TT.999 999.TT tnt-t n 

ftn.t n 

nt. n 

nt. n 

1:030-190:00 

0.0 

0.340 

1.340 

o.ot* 

0.00 

0.00 

0.2 * 

0.00 - •• " 

tn. n 

tn. n 

-nt;n-

000.** 

nt. n 

nt.n tn. n 

nt.n tn. n 

- fn :n - nt:n * 

099.99 099.99 

nt.n tn. n 

-tn:n tft:n nt:n-

tn. n 

tn. n 

-22:0 * • 0.0 

0.10 

tn.n nt. n 

tn.n tn. n 

—9:0 47:99-

n.99 9.9 

n.so 0.30 

• 

799.tt 

999.97 

f99.99 

m.?? 

FfF»TT 

tn. n 

tn. n 

.rf.llll'if.-m ^ 

999.99 

777.77 

999.99 

??*»?? 

-n?:? ? 

fff.ff 

?n.?? 

_ ^___A _ ___________k .___i 

fff:ftftt.f t tn.t t 

tn. n 

nt:n-

tn. n 

tn. n 

-fff.ff 

000.00 

tn. n 

fff.ff 

tn. n 

-nt; n 

nt. n 

nt. n 

tn. n 

009.00 

tn. n 

-fft.tt ttt.n • 

nt. n 

fff.ff 

-n:o o 

0.0 

*.o 

0:40 "—ra.iv v.av -a.ao 

0.0 n.o

o o.o 

... . 

21.0 * 

nt. n 

fff.ff — 0.9 * 

9.0 * 

9.99 

0:00 

•.0 0 

97.797 

77.799 

77.999 

??.999 

??.??? 

ff.ff f 

tt.ff t 

n.ttt 

n.t n 

n.t n 

n.t n 

n.t n 

n.n t 

n.t n 

99.009 

n.n t 

-n.t n 

n.t n 

n.t n 

t.ooo 

2.092 

2.000 

"i.n4 

2.009 

!.•.„ 

, _ £ 
'

• CHElftO 3) 

-WCHErNOr 3ft 

CHEHHO 27 

.- CHEHNO 38 

- OCHNO 3f 

CHEHNO 49 

- CHEHNO 41 

CHEHNO 42 

CHEHNO 43 

CHEHHO 44 

CHEHHO 43 

CHEHHO 44 

CHEHNO 47 

CHEHNO 48 

CHEHNO 49 

• CHEHNO 30 

CHEHNO 31 

CHEHNO 92 

i- • OCHNO S3 

DHUFHTLAHIONE 

(_ICIR.OTBITW* N 

tTHAHOL 

ETWNOUimNES-,- — -

ETHYL ACRYLATE 

ETHYLACETATE 

ETHYLBEN2-NE 

ETHYLENE 

ETHYLB1CHL0RIBE 

ETHYUtOC aYCOL 

ETHYLENE OXIBE 

ETHYL HEXAML 

FORHALBEHYK 

FORHIC ACIB 

avcioa 

aYCERIN 

HEXANETHYLEIC BIAHINE 

HYBROCEN CYAMHIBE 

ISOSUTAMX. 

CHEHNO 34 I90BUTRALBEHYBE 

CHEHNO 33 ISODECANOL 

OCHNO 94 ISOOCTOO. 

CHEHNO 37 ISOFHTHM.IC ACID 

V CHEHHO 38 HALEIC AMTTBRIBE 

CHEHHO Sf NESITTL OXIBE - --"-

• v CHEHNO 40 NETHMOL 

••• 7OCHN0 41 HETHYL CHLORIDE 

CHEHNO 42 HETHYL ETHYL NCTQK 

n CHEHNO 43 HETHYL BENZOATE 

,_> CHEHNO 44 HETHYL TOLUATE 

K> • OCHNO 43 HETHYL HETHACRYUTE 

CHEHNO 44 -HETHYL STYRENE 

CHEHNO 47 N- BUTANOL 

. CHEHNO 40 NITROBENZENE 

CHEHNO 49 -TOLUENE BIAHINE 

CHEHNO 70 PERCHLOROETHYLENE 

CHEHNO 71 PHENOL 

CHEHNO 72 PHTHALIC ANHTIRIBE 

OCHNO 73 PROPIOHIC ACIB 

CHEHHO 74 PROPYLENE 

CHEHNO 73 STYRENE 

CHEHNO 74 TEKPHTHALIC ACIB 

CHEHNO 77 TOLUENE DIISOCYANATE 

CHEHNO 78 TRICHLOROEHANE 

CH-HHO 79 TRICt-ORO-THTLENE 

CHEHNO 80 TRICHLCROFLUOtOHETHAHE 

Cf-EHHO Bt VINYL ACETATE 

CHEHHO 82 .VINYLOt-ORIBE 

- • CHEHHO 83 loOKCYUENZENE - ^V

1

 <W- c 

EOF i 

-1 

I

 : 

I 

j 

ro 
ATTACHMENT D 

htaO.(l-) 
A-83-29 

III-B-l 

•&EJ-A 

P.29 

I 

tad Statat Offtca ol Air Quality 

-rartrnanul Protaction Planning an* Standard* EPA-45<_ 3-90-01U 

mey Raaaareh Triangla Park NC 27711 .una 1090 

Reactor 

Processes in 

Synthetic Organic 

Chemical 

Manufacturing 

IndustryBackground 

Information for 

Proposed 

Standards 

Draft 

EIS 
-rs*--- r- P.30 

EPA-45Q/3-90-016a 

Reactor Processes in 

Synthetic Organic Chemical 

Manufacturing Industry — 

Background Information 

for Proposed Standards 

Emiaaiona Standards Oivision 

U.S. ENVIRONMENTAL PROTECTION AGENCY 

Offlca oi Air and Radiation 

Oftleo of Air Quality Planning and Standards 

Rosoarch Triangla Park, North Carolina 27711 

Juno 1990 
R^Jt, 

o I 

or J 

APPENDIX C. EMISSION DATA PROFILE 

Unit Process* 

I.D." 

ALK-1 

ALK-2 

VALIC-3 

ALK-4 

ALK-S 

ALK-6 

AlK-7 

ALK-8 

ALK-9 

AIK-10 

ALK-U 

ALK-12 

ALK-13 

AIK-14 

AMtl-1 

AMN-1 

AMH-2 

CAR-1 

CM- 2 

CARO 

CAR-4 

-'CIE-I 

• CHL-1 

CHL-2 

CM.-4 

CHL-5 

CHL-6 

CHL-7 

CHL-8 

CHL-9 

CHL-10 

CHL-11 

CHL-12 

CHL-13 

CHL-14 

.Hi-15 

VCheaical 

Linear Alkylbenzene 

Linear (Alkylbenzene 

EthylbJnzene 

Tetra Ethyl -

Tetra Methyl Lead 

Ethylbenzene 

Linear Alkylbenzene 

Linear Alkylbenzene 

Cuaene 

Cuaene 

Cuaene 

Cuaene 

Cuaene 

Dlaethyldlchlorosllane 

Nonylphenol 

Caprolactaa 

Ethanolaalnes 

Ethanolaalnes 

Acetic Acid 

Methanol 

Methanol 

Methanol 

Phenol/Acetone 

Ethylene Dichloride 

Chlorobenzene 

Chlorobenzene 

Ethylene Dichloride 

Ethylene Dichloride 

Ethylene Dichloride 

Methylene Chloride 

Ethylene Dichloride 

Ethylene Dichloride 

Methylene Chloride 

1,4-Dlchlorobutene 

He thyIchlorofora 

Allyl Chloride 

Mono Chlorotcetlc Acid 

Plant 

Production 

|10B lb/yr) 

250 

ONA 

1.795 

175 

147 

243 

140 

700 

230 

450 

400 

DNA 

DNA 

DNA 

280 

125 

40 

100 

1.484 

590 

1.070 

500 

550 

60 

73 

500 

700 

847 

DNA 

100 

too 

42 

DNA 

DNA 

250 

ONA 

Sequential Listing of All. 

Vent Gas Treataent Devices 

HCL/VOC Scrubbers 

• 

VOC Scrubber 

Condenser/1nc1nerator 

Condenser/VOC Scrubber 

Acid Gas Scrubber/Flare 

VOC/HCL Scrubbers 

-

-

-

-

-

-

-

-

_ 

-

VOC Scrubber/Flare 

Process Heater 

Process Heater 

Process Heater 

-

HCL Scrubber/Incinerator 

Condenser/Scrubber 

HCL Scrubber 

-

Incinerator 

Condenser/1nc1nera tor 

-

HCL Scrubber 

Condenser/ Inc 1 iterator 

-

Condenser/Scrubber 

-

-

Scrubber 

Process Vent Streaa Characteristics' 

flow (scfa) 

0NAd 

NO 

17 

ONA 

8.7 

Heat Value (Btu/scf) 

REACTOR 

DNA (low flow) 

ONA 

NO 

NO 

NO 

NO 

NO 

NO 

NO 

NO 

NO 

NO 

DNA 

(18.950)' 

ONA 

ONA 

NO 

0«) 

DNA 

55 

NO 

DNA 

DNA 

NO 

40 

(267) 

NO 

9.195 

NO 

NO 

ONA 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

ONA 

PROCESS 

181 

DNA 

4.0 

DNA 

DNA 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

DNA 

(295) 

DNA 

ONA 

PROCESS 

(163) 

ONA 

DNA (Assuaed 0) 

REACTOR 

REACTOR 

PROCESS 

DNA 

ONA 

PROCESS 

40 

(1.228) 

REACTOR 

REACTOR 

REACTOR 

/ 

PROCESS 

0 

PROCESS 

PROCESS 

DNA 

VOC (lb/hr) 

DNA • 

VENTS 

16 i 

DNA 

0.1 

14 

DNDNA A 

VENTS 

VENTS 

VENTS 

VENTS 

VENTS 

VENTS 

VENTS 

VENTS 

VENTS 

VENTS 

ONA 

(75) 

ONA 

ONA 

VENTS 

(74) 

2 

4 

VENTS 

ONA 

DNA 

VENTS 

3.6 

(113) 

VENTS 

7.2 

VENTS 

VENTS 

ONA 

Ref. 

1.2.3 

4.5 

6 

7.8.9.10 

U.12.13. 

.15.16.17 

3 

19 

20.21 

22.23 

24.25 

26.27 

28.29 

30 

31 

32.33 

34 

35 

36 

37.38 

39 

40 

3 

42 

43 

44 

45 

46 

47 

151 

137 

138 

48 

49 

50.51 

52 . 

53 

, — 
APPENDIX C. EMISSION DATA PROFILE (Continued) 

Unit Process 

I.O.1 

HVO-1 

HVD-2 

HYD-3 

HYD-5 

HVO-6 

HYD-7 

HYD-8 

HVO-9 

HYD-10 

HYD-11 

HVOC-3 

HVOC-4 

HVDC-5 

HYOC-6 

HYOC-7 

HYDC-8 

HVDC-9 

HVOC-10 

HYDC-U 

HYDC-12 

HVOF-1 

HY0F-2 

HYDI-1 

HYOO-1 

HVOO-2 

HYDO-3 

HVOR-1 

HYDR-2 

HYOR-3 

HYDR-4 

NIT-1 

NIT-2 

NIT-3 

NUT-1 

NUT-2 

HUT-3 

Cheaical 

Hexaaethylene dlaaine 

Hexaaethylene dlaaine 

Cyclohexane 

Aniline 

Butanediol 

Cyclohexanol 1 ' 

Toluene Dlaaine 

n-Butyl Alcohol 

Hexaaethylene Dlaaine 

O-Butylene 

Methyl Chloride 

Methyl Chloride 

Methyl Chloride 

Ethyl Chloride 

Ethyl Chloride 

Ethyl Chloride 

Ethyl Chloride 

Ethyl Chloride 

Ethyl Chloride 

Epichlorohydrin 

Oxo Alcohols 

Butyraldehyde 

Adiponitrile 

Propylene Oxide 

Sec Butyl Alcohol 

Glycerin 

Propylene Glycol 

Ethylene Glycol 

Ethylene Glycol 

Ethylene Glycol 

Nitrobenzene 

Dinitrotoluene 

Dinitrotoluene 

Linear Alkylbenzene 

Linear Alkylbenzene 

Plant 

Production 

(10D lb/yr) 

180 

190 

1.6 

150 

ONA 

ONA 

ONA 

DNA 

DNA 

DNA 

Sequential Listing of AIK 

Vent Gas Treataent Devices 

No Controls 

Boiler 

-

-

Flare 

-

Incinerator 

Condenser/Ref. Condenser 

Boiler 

-

ONA Scrubber/Condenser/Incinerator 

80 

DNA 

100 

16 

ONA 

DNA 

DNA 

DNA 

250 

500 

175 

180 

350 

270 

DNA 

ONA 

183 

ONA 

DNA 

123 

88 

ONA 

250 

DNA 

Dodecylbenzene sulfonic 

acid. Sodiua Salt ONA 

Refrigerated Condenser 

-

Flare 

-

-

-

-

Condenser/Inc1nerator 

Coabustion Device 

Condenser/Flare 

Boiler 

NH- Scrubber 

Condenser 

. Flare 

-

_ 

-

-

-

No Controls 

VOC Scrubber 

VOC Scrubber/Incinerator 

. 

-

" 

Process Vent Streaa Characteristics'* 

flow (scfa! 

70 

(113) 

NO 

NO 

DNA 

NO 

ONA 

5.429 

(1.304) 

NO 

DNA 

20 

NO 

(20) 

NO 

NO 

NO 

NO 

ONA 

ONA 

ONA 

(729) 

1.080 

99 

DNA 

DNA 

NO 

NO 

NO 

NO 

13 

822 

ONA 

NO 

NO 

NO 

Heat Value (Btu/scf) 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

323 

(900) 

PROCESS 

PROCESS 

DNA 

PROCESS 

DNA 

776 

(462) 

PROCESS 

ONA 

(Assuae 500) -

REACTOR PROCESS 

(1.286) 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

DNA 

DNA 

DNA 

(1.233) 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

70 

0 

DNA 

ONA 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

434 

0 

ONA 

PROCESS 

PROCESS 

PROCESS 

VOC (lb/hr) 

6.6 

0 

VENTS 

VENTS 

ONA 

VENTS 

DNA 

4.046 

(0) 

VENTS 

ONA 

2.1 

VENTS 

(168) 

VENTS 

VENTS 

VENTS 

VENTS 

DNA 

?.080 lb/106 lb 

DNA 

(2.394) 

27 

0.1 

DNA 

DNA 

VENTS 

VENTS 

VENTS 

VENTS 

19 

0.1 

ONA 

VENTS 

VENTS 

VENTS 

Ref. 

142 

143 

89.90 

91 

140 

74 

141 

92 

93 

94 

7.9.10 

95 

96.97 

98.99 

48 

100.101 

102,103 

104.105 

56.57.106 

146 

144 

107 

108 

106 

60.61.62 

149 

106.109 

110.111 

112 

113.114 

115.116 

1.127 

116 

2.119 

120 

145 

i'-
APPENDIX C. EMISSION DATA PROFILE (Continued) 

Unit Process 

I.O.1 Cheaical 

Plant 

Production 

HO9 lb/yr) 

Sequential Listing of AIK 

Vent Gas Treataent Devices 

Process Vent Streaa Characteristics'" 

flow (scfa) Heat Value (Btu/scf) VOC (lb/hr) Ref. 

Oil £-1 

OilG-2 

OLIG-3 

OLIG-4 

OLIG-5 

0X1-1 

0X1-2 

0X1-3 

0X1-4 

OXYA-1 

OXVC-1 

PHO-1 

PYR-1 

PYR-2 

PYR-3 

PVR-4 

PVR-S 

PYR-6 

PVR-7 

SUL-1 

SULP-1 

Octene DNA 

Dodecene ONA 

a-Butyfene ONA 

TrlproftlMM DNA 

Dodecene DNA 

Adipic Acid 640 

Adipic Acid 100 

Adipic Acid 700 

Ethylene Oxide 292 

Vinyl Acetate 398 

Ethylene Dichloride 912 

Toluene Diisocyanate ONA 

Ketene 300 

Ethylene ONA 

Ketene 600 

Propylene ONA 

Ethylene DNA 

Vinyl Chloride Honoaer 310 

Blvlnyl DNA 

Dodecylbenzene sulfonic 

acid 30 

Carbon Disulfide DNA 

NH3 Scrubber 

No Controls 

NH- Scrubber/Boiler 

No Controls 

No Controls 

Incinerator 

Acid Gas Scrubber 

NO 

NO 

NO 

NO 

NO 

2.800 

848 

(4.653) 

12.187 

7* 

(304) 

NO 

NO 

NO 

NO 

NO 

NO 

NO 

NO 

1.863 

NO 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

REACTOR 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

0 

0 

(0) 

4 

407 

(713) 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

PROCESS 

0 

PROCESS 

VENTS 

VENTS 

VENTS 

VENTS 

VENTS 

0 

0 

(0) 

130 

0.1 

(748) 

VENTS 

VENTS 

VENTS 

VENTS 

VENTS 

VENTS 

VENTS 

VENTS 

0.1 

VENTS 

121 

121 

122 

123 

124 

125 

147 

126.127 

128 

129.130 

131.132 

148 

54 

133.134 

55 

135 

135 

136 

92 

56 

137 

co 

co 
a. Process units m identified by the cheaical reaction associated with their aanufacture. Reaction codes are as follows: 

AIK 

ANNI 

ANN 

CAR 

CLE 

CUE 

CHL 

CONt 

OEHY 

OEM 

O.HC 

EST 

ETH 

ETHV 

FLU 

- Alkylation 

- Aanlnation 

- Aaaonylisis 

- Carbonylation 

- Clevage 

- Catalytic Reforming 

- Chlorination 

- Condensation 

- Dehydration 

- Dehydrogenation 

- Dehydrochlorination 

- Esterification 

- Etherlficatlon 

- Cthyaylatlon 

- Fluorloation 

HVO 

HVOC 

HYOF 

HYOI 

HYDO 

NIT 

NUT 

OLIG 

OX I 

OXVA 

OXVC 

PHO 

PVR 

SUL 

SULP 

Hydrogenation 

Hydrochlorination 

Hydrofonaylatlon 

Hydrodiaertzatlon 

Hydrolysis 

Nitration 

Neutralization 

Ollganerlzatlon 

Oxidation (Pure 0-) 

Oxyacetylation 

Oxychlorination (Pure 0.) 

Phosgenatton 

Pyrolysls 

Sulfonation 

Sulfurtzatlon (Vapor Phase) 

cn 

b. This listing Identifies all process vent streaa treataent devices. Including all coabustlon and noncaabustlon devices Identified In 

the data base. Devices are not listed when (1) there is no process vent streaa or (2) there is a vent but it Is recycled within the 

process or Is a feed to another process (e.g.. a hydrogen feed steaa). All devices are listed In the sequence In which they occur. 

c. For process units where coabustlon devices are used, the vent streaa characteristics presented ir e In parentheses and represent the 

vent streaa characteristics Just prior to the coabustlon device. For units without coabustlon devices, the vent streaa 

characteristics presented represent the vent at Its point at discharge to the ataosphere. These i n the characteristics upon which 

the TRE calculation fs based. 

d. DMA - Oata not available. 

e. For oil process units where coabustlon Is currently used. I.e., baseline, all vent streaa data and TRE's m tn parentheses.