p. 1



# RCRA Box 1883
Prepped by Ollie Stewart



# Document

Number: 

# 91 ) ll-B-25 3

Docket Number: 

# A-90-1 9

Printed 12/3/2008 10:42:16

AM Sheet 91 of 171P ^ 

# RADIA N
CORPORATIO N 

# MEMORANDU

M

OATE : Septembe r1 , 199 1 TO : Projec tFil e 6. 3 FROM : Thoma s R
. Olse n 

# A-90-1 9 ll-B-25 3

\^0

SUBJECT : Dat a Use

dt o Develo

pth e HO N Proc

The purpos e o f thi s memorandu m i s t o present th

e source s an

d
ra w dat a use

dt o develo

pmode l produc t processe s fo r HO N proces s vents . The model s wer e use dindevelopin

g nationa l impact s an d contro l cos t impacts . Ven t strea m informatio

ncontaine

di nth e industr y profile s develope

di nth e ai r oxidation , reactors , and ' distillatio

nNSP S BIDs 1 

# ' 4 

# wa s reviewe dan dupdate

db y addin g ne w strea m characteristic s base do navailabl e information . The SOCM I NSP S BI D dat a fo

r ai r oxidatio

ni s presente

dinAttachmen t A . The SOCM I ai r oxidatio ndat a summarize

dfro m th e Surve y Report s .5-1 4 

### I S 

# o nAtmospheri c Emission s Fro m th e Petrochemica l Industr y presentedi

nAttachmen t B . Th e SOCM I NSP S BI D dat a fo r distillatio

nan dreactor s i s presente di nAttachment s C an

dD , respectively . Th

e industr

y profile s wer e develope dt o represent tota l VOC emission s fro m SOCM I processes . Th e surve y repor t an

d th e Enviroscienc e reports , whichwer e th e origina l informatio n source s fo

r th e profile s development , wer e reviewe dt o obtai nth

e strea m SOCMI/HA

P compositio

nan dth e productio

ncapacity

o f eac h plant represente

db y a profil e stream . Radia nadde dt o or update deac hprofil e usin

g SOCMI/HA

P informatio

nfro m existin

g sources , includin

g informatio

ngathere

dunde r th

e authority

o f Sectio n11 4 o f th

e Clea nAi r Act , tri preports , an dsourc e assessmen t documents . A t thi s point , eac

hprofil e wa s update dan dth e HA P t o tota l VOC rati o an

dth e productio

ncapacity

fo r th e majority

o f th e vent stream

s wer e identified . Som e vent stream

s di dno t contai n informatio

no nHAP's . Thes e entrie s wer e no t eliminate dfro m th e

PVD B (htni01)(ls )

Progres s Center/320 0 E

. Chape l Hil l Rd./Nelso n Hwy./P.O

. Bo x13000/Researc h Triangl e Park , N.C

. 27709/(919)541-910 0

## P. 3



# profil e becaus e tota l VOC emission s are assume dt o be similar fo

r al l processe s represente dunde r eac

hprofile . For thos e stream s withou t a HA

P t o tota l VOC ratio , a naverage rati o wa s develope d fo r ai r oxidation , reactors , an ddistillatio

nprofiles . Thi s average rati o wa s assigne dt o th e stream

s withou t a specifi c rati o t o estimat e th e HA P emission s fro

m thos e streams . The leve l o f effor t necessar y t o quantify

individua l HA

P emission s fro

m stream s wit hmultipl e HA

P compositio

nexceede

dth e benefi t o f identifyin g th e multipl e HA

P emissions . The tota l VOC content o f ven t stream s i s include

dinth e profiles . Radianuse d th e appropriat e HA

P t o VOC rati o factor t o quantify tota l HA

P emissions .

cc : Le s Evans , EPA/CP B Bar t Ferrero , Radia n Bennet t King , Radia n Projec t Fil e 6. 3 (M . Haley )

PVD B (htmOD(ls )P. 4

r



### _\ #



# REFERENCE S

1 . Reacto r Processe s inSyntheti c Organi c Chemica l Manufacturin

g Industr

y - Backgroun

dInformatio

nfo r Propose

d Standard . U . S . Environmenta l Protectio nAgency . Research Triangl e Park , NC . Publicatio nNo . EPA-450/3-90-016a . June 1990 . p . 3-1 . 2 . Ai r Oxidatio

nProcesse s inSyntheti c Organi c Chemica l Manufacturin

g Industr

y - Backgroun

dInformatio

nfo r Propose

d Standard . U . S . Environmenta l Protectio nAgency . Research Triangl e Park , NC . Publicatio nNo . EPA-450/3-82-001a . Octobe r 1983 . 3 . Distillatio

nOperation s inSyntheti c Organi c Chemica l Manufacturin

g Industr

y - Backgroun

dInformatio

nfo r Propose

d Standard . U . S . Environmenta l Protectio nAgency . Research Triangl e Park , NC . Publicatio nNo . EPA-450/83-005a . Decembe r 1983 . pp . 3- 8 t o 3-11 . 4 . I T Enviroscience . Emission s Contro l Option s fo r th e Syntheti c Organi c Chemical s Manufacturin g Industry . Prepare dfo r U . S . Environmenta l Protectio nAgency , OAQPS . Jul y 1980 , EP

A Contrac t Number 68-02-2577 . 5 . Engineerin

g an dCos t Stud

y o f Ai r Pollutio

nContro l fo

r th e Petrochemica l Industry , Volum e 2 : Acrylonitril e Manufacture . U . S . Environmenta l Protectio nAgency . ResearchTriangl e Park , NC . Publicatio n No . EPA-450/3-73/006-b . Februar y 1975 . 6 . Engineerin

g an dCos t Stud

y o f Ai r Pollutio

nContro l fo

r th e Petrochemica l Industry , Volum e 3 : Ethylene Dichloride Manufactur e b

y Oxychlorination . U . S . Environmenta l Protectio

nAgency . ResearchTriangl e Park , NC . Publicatio n No . EPA-450/3-73/006-C . Novembe r 1974 . 7 . Engineerin

g an dCos t Stud

y o f Ai r Pollutio

nContro l fo

r th e Petrochemica l Industry , Volum e 4 : Formaldehyde Manufactur e wit hthe Silve r Catalys t Process . U . S . Environmenta l Protectio

nAgency . ResearchTriangl e Park , NC . Publicatio n No . EPA-450/3-73-006-d . March1975 . 8 . Engineerin

g an dCos t Stud

y o f Ai r Pollutio

nContro l fo

r th e Petrochemica l Industry , Volum e 5 : Formaldehyde Manufactur e wit hth e MixedOxide Catalys t Process . U . S . Environmenta l Protectio

nAgency . ResearchTriangl e Park , NC . Publicatio n No . EPA-45 0 /3-73-006-e . March1975 .

PVD B (htmOD(ls )

## P. 5



# 9 . Engineerin

g an dCos t Stud

y o f Ai r Pollutio

nContro l fo

r th e Petrochemica l Industry , Volum e 6 : Ethylene Oxide Manufactur e b

y Direc t Oxidatio

no f Ethylene . U . S . Environmenta l Protectio nAgency . ResearchTriangl e Park , NC . Publicatio

nNo . EPA-450/3-73-006-f . June 1975 . 10 . Engineerin

g an dCos t Stud

y o f Ai r Pollutio

nContro l fo

r th e Petrochemica l Industry , Volum e 7 : Phthali c Anhydride Manufactur e fro

m Ortho-Xylene . U . S . Environmenta l Protectio

nAgency . ResearchTriangl e Park , NC . Publicatio n No . EPA-450/3-73-006-g . Jul y 1975 . 11 . Engineerin

g an dCos t Stud

y o f Ai r Pollutio

nContro l fo

r th e Petrochemica l Industry , Volum e 8 : Viny l Chloride Manufactur e b

y th e Balance

dProcess . U . S . Environmenta l Protectio

nAgency . ResearchTriangl e Park , NC . Publicatio n No . EPA-450/3-73-006-h . Jul y 1975 . 12 . Surve

y Report s o

nAtmospheri c Emission s fro m th e Petroleu

m Industry , Volum

e I . U . S . Environmenta l Protectio nAgency . ResearchTriangl e Park , NC . Publicatio nNo . EPA-450/3-73-005-a . Januar y 1974 . 13 . Surve

y Report s o

nAtmospheri c Emission s fro m th e Petroleu

m Industry , Volum

e II . U . S . Environmenta l Protectio nAgency . ResearchTriangl e Park , NC . Publicatio n No . EPA-450/3-73-005-b . Apri l 1974 . 14 . Surve

y Report s o

nAtmospheri c Emission s fro m th e Petroleu

m Industry , Volum

e III . U . S . Environmenta l Protectio n Agency . ResearchTriangl e Park , NC . Publicatio n No . EPA-450/3-73-005-C . Apri l 1974 . 15 . Surve

y Report s o

nAtmospheri c Emission s fro m the Petroleu

m Industry , Volum

e IV . U . S . Environmenta l Protectio nAgency . ResearchTriangl e Park , NC . Publicatio n No . EPA-450/3-73-005-d . Apri l 1974 .

PVD B (htmOD(ls )

### P. 6



# ATTACHMEN

T A

•aSfa ?



### ..— r^rr- - 

### •mhtaOKU )P. 7 

# A-81-2 2

III-B- 1 

# SEF A Offic e o fAi rQualit y Protectio n Plannin g an d Standard s

Researc h Triangl e Par k

N C 2771 1 EPA-45 0 3-82-00. ! a

Octobe r198 3 

# Ai rOxidatio n Processe s Dra f i n Syntheti c Organi c Ei S Chemica l Manufacturin g Industr y— Backgroun d Informatio n fo rPropose d Standard s

### P. 8



### •TABL E F-4

. DISTRIBUTIO N OF NATIONA L STATISTICA L PROFIL E DAT A VECTOR

S

3 '*n t 1 3 -naair
130 3 "30 5 :30 6 •30 7 : so i 205 2301 ' 330 2 230 3 230 5 2 30 8 510 1 510 2 510 3 510 4 '0 2 1004 100 7 220 3 220 4 220 5 220 8 220 7 220 8 90 2 90 3 904 '00 1 1005 130 1 :30 2 '30 3 'SO * :30 5 180 6 :so7 140 3 140 4 140 7 140 8 '140 9

. 141 0 141 1 141 8 '.41 S •42 1 42 3 '42 2 •42 0 'SO I 520 2 520 3 520 4 520 5 52C 6 !2t : 520 8 520 9 520 1 •our' yimus^on j <g/. "

—326

586 11 5 2.1 2 55. 3 75. 3 11 7 233 61 7 340 21 9 137 0 215 0 39 9 121 0 13. 7 32 3 22 3 155 26. 4 27. 9 36. 0 13. 7 14. 6 80. 2 103 40 7 78. 7 188 52 9 21 1 20 5 13 6 14. 1 13 S 35 9 15. 1 20. 3 33. 7 14. 6 0.025 0 15. 8 35 7 0.020 5 39. 6 16. 0 19. 5 23. 3 31. 4 0.21 7 30. 2 43 3 34 8 22 8 :2 3 46 4 37 1 78. 9 51 6 

### •« tsitin g/tlu l "Si/i e 3**94 1 "owrt u iatf*ir)i

. :.:9 2 -.3 5 3.19 9 3.30 1 3.3 1 3.23 4 3.14 0 3.14 4 3.09 3 3.09 0 0.14 6 1.0 4 1.5 9 0.72 8 0.67 6 0.M 9 0.26 9 0.15 4 0.21 7 0.08 2 0.08 9 0.08 7 0.08 S 0.10 9 0.44 0 0.43 3 1.5 2 0.38 6 0.14 3 0.39 1 3.33 6 0.38 7 0.49 0 0.20 5 0.33 9 0.79 3 2.6 3 2.4 9 2.6 3 2.5 4 2.7 5 2.5 3 2.3 4 2.3 9 0.10 6 0.13 8 0.13 7 0.29 9 2.5 7 1.7 1 0.75 2 '.9 9 2.6 5 2.3 0 0.*2 2 3.76 9 0.76 9 0.78 9 4.2 5 16 1 52 9 194 3037 163 1 52 79 0 121 2 355 2 230 7 132 0 142 7 137 3 152 4 209 2 36 5 152 4 56 5 51 6 49 * 31 0 23 1 15 2 9 7 18 2 18 2 25 2 164 2 97 9 226 4 134 1 1277 51 6 130 9 91 2 60 7 2 4 7 3 6 1 76 3 3 17 3 54 7 2 7 176 11 8 11 8 10 0 6 1 19 7 182 12 1 21 6 64 7 14 3 304 24 2 5 2 28 9 

## F-1 2

### P. 9



# ATTACHMEN

T II I

EP AAI R OXIDATIO

NREGULATOR

Y PROGRA M STATISTICA

L ANALYSI S - KE

Y VARIABLE S
Variabl e Numbe r Definitio n o f Variable s 1 Plan t numbe r JT " Plan t siz e (IO 6 

# lbs./yr. ) 3 Molecula r weigh t produc t 4 Mola r oxyge n rati o (MOR ) IJ5 J O - volum e percen t i nreacto r of f ga s 6 C O volum e percen t i nreacto r offga s 7 CO , volum e percen t i nreacto r offga s 8 H 2 

# 0 volum e percen t i nreacto r offga s 9 N 2 

# volum e percen t i nreacto r offga s 1 0 Produc t VO C percen t i nreacto r offga s 1 1 Fee dVO C percen t i nreacto r offga s 1 2 Othe r VO C componen t i nreacto r offga s 1 3 No nVO C combustibl e volum e percen t in

_reacto r offga s (Hj * CH. , andC,Hg ) fl*T ) Tota l volum e percen t VO C in~th e reacto r offga s (10+11+12 ) 

# S D Heatin g valu e (Btu/SCF ) reacto r offgas . (Include s heatin g valu e o f 6 , 10 , 11 , 12 , and13 ) 

# ^ D D Flo w of reacto

r offgas (100 0 SCFM ) 1 7 Ti , auto-ignitio ntemperatur e (°C ) fee dor produc t dependin g o nwhic hi s lowe r 1 8 EL , explosiv e limi t feedstock , volum e percen t i nai r a t atmospheri c pressur e an d 2S U 

# C temperature . 1 9 Tr , reactio ntemperatur e (°C ) 2 0 Tr/TiE L 2 1 A HR , (kcal/g

m mole) , globa l hea t o f reaction 2 2 Fi , rati o o f actua l offga s t o theoretica l 

# F 

# ? ' ai r requirement .P.1 0



# ATTACHMEN T II I - CONTINUE D

~ " EPA AI ROXIDATIO NREGULATOR Y PROGRAM
STATISTICA L ANALYSI S - PRODUCTS/COMPANIE S
(Dat a Bas e from197 2 Houdr yPetrochemica l Survey )
Acetaldehyd e
Eastma n

Aceti c Aci d
Eastma n
Acrylonitril e America nCyanamid , Sohio , DuPont , Monsant o

Ethylen e Dichlorid e
Conoco , Diamon

dShamrock , Ethyl , Goodrich , PPG , Shell , Stauffer , Vulcan
Ethylen e Oxid e
PPG , Dow , Koch , UC C

Formaldehyd e Hercules , Tenneco , Georgia-Pacific , Borden , DuPont , Celanese , Reichhold , Gul f
Hydrocyani c Aci d
Roh m andHaa s

Malei c Anhydrid e
Monsanto , Denka , US S Chemical , Tenneco , Reichhold , Koppe r

Phthali c Anhydrid e UCC , Stepan , Monsanto , Koppers , US S Chemica l•- n < 7 v » w4» > wi u i w i wifwi (A wi w > WH * •;> e e e H ea o e\ s ei e e e 4 W N — H » « M vJ>Cj0/ S W J K l *MJ>WH»MM M ^ee^M»MW » d c ^ - —ic

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9 8 9 8 9 8 9 8 9 8 9 8 4.S

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0.S 1 0.1 0
0.4 0 WO . SO 19.5 0 0.5 0 6.5 3 O.SO 6.S 3 O.S O 5.9 0 0.2 5 - 1.7 9

1.8 0 2.3 2 2.2 7 1.7 7 2.0 0 2.9 0

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0.0 8 0.0 8
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v 

### SOCM

I AIROXIDATIO

N DAT A FRO M IKMOR YQUBSTIONNAIRE S VAPO RPHAS E PROCESSE S (Continued )

1 0 1 1 1 2 Pag e 2 o f 3



### 1 3 

# T4 * 15 16 1 7 1 8 19 2 0 2 1 2 2
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7.2 3 75.0 3 6.6 0 75.S O 9.3 1 70.7 1

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. 3.9 6 68 , 5.6 0 70

. 1.8 9 72

.

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. 6.6 9 70

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### ATTACHMEN T A



### 6 SOCH I AI ROXIDATIO N DAT A FRO M HOUOR YQUESTIONNAIRE S LIQUI DPHAS E PROCESSE S #*-- ; JJ>
- <i« / s 

### ? 2 Pag e 3 o f 3

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### 1. 0 1. 0 1. 0 1. 0 94. 1 1. 0 94. 1 1. 0 

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2.4 C 

# V

i. 

### 0.7 0 0.3 9 96.5 0

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## - 1 I : 

# I



# j

r

o

# ATTACHMEN T D

htaO.(l- )

# A-83-2 9

III-B- l


# •&EJ- A P.2 9 

# I

tad Stata t Offtc a o l Ai rQualit

y -rartrnanu l Protactio n Plannin g an * Standard * EPA-45<

_3-90-01 U me yRaaaare h Triangl a Par k N C 2771 1 .un a 109 0 

# Reacto r Processes i n Syntheti c Organi c Chemica l Manufacturin g Industry Backgroun d Informatio n fo r Propose d Standard s Draf t EI S-rs*--

- r- P.3 0



### EPA-45Q/3-90-016 a



# Reacto rProcesses i n Syntheti c Organi c Chemica l Manufacturin g Industr

y— Backgroun d Informatio n fo rProposed Standard s

Emiaaion a Standard s Oivisio n

U.S

. ENVIRONMENTA L PROTECTIO N AGENC Y

Offlca o i Ai ran d Radiatio n Oftleo o fAi rQualit

yPlannin g an d Standard s Rosoarc h Triangl a Park , Nort h Carolin a 2771 1

Jun o 199 0

# R^Jt,

o I 

### o r J

APPENDI XC . EMISSIO N

DAT A PROFIL E

Uni t Process * I.D. "

ALK- 1 ALK- 2 VALIC- 3 ALK- 4
ALK- S
ALK- 6 AlK- 7 ALK- 8 ALK- 9 AIK-1 0 ALK- U ALK-1 2 ALK-1 3 AIK-1 4 AMtl- 1
AMN- 1 AMH- 2
CAR- 1 CM- 2 CAR O CAR- 4
-'CIE- I

• CHL- 1 CHL- 2 CM.- 4 CHL- 5 CHL- 6 CHL- 7 CHL- 8 CHL- 9 CHL-1 0 CHL-1 1 CHL-1 2 CHL-1 3 CHL-1 4 .Hi-1 5



## VCheaica l

Linea r Alkylbenzen e Linea r (Alkylbenzene EthylbJnzen e Tetr a Ethy l - Tetr a Methy l Lead Ethylbenzen e Linea r Alkylbenzen e Linea r Alkylbenzen e Cuaen e Cuaen e Cuaen e Cuaen e Cuaen e Dlaethyldlchlorosllan e Nonylpheno l Caprolacta a Ethanolaalne s Ethanolaalne s Aceti c Aci d Methano l Methano l Methano l Phenol/Aceton e Ethylen e Dichlorid e Chlorobenzen e Chlorobenzen e Ethylen e Dichlorid e Ethylen e Dichlorid e Ethylen e Dichlorid e Methylen e Chlorid e Ethylen e Dichlorid e Ethylen e Dichlorid e Methylen e Chlorid e 1,4-Dlchlorobuten e H e thyIchlorofor a Ally l Chlorid e Mon o Chlorotcetl c Aci d Plan t Productio n |10 B

### lb/yr )



## 250 ON A 1.79 5 

## 17 5 14 7 24 3 14 0 700 230 450 40 0 DN A DN A DN A 280 12 5 4 0 10 0 1.48 4 

## 59 0 1.07 0 

## 50 0 550 6 0 7 3 500 700 847 DN A 10 0 

# to o 42 DN A DN A 25 0 ON A Sequentia l Listin g o f All . Ven t Ga s Treataen t Device s

HCL/VO C Scrubber s 

## • VO C Scrubbe r Condenser/1nc1nerato r Condenser/VO C Scrubbe r Aci dGa s Scrubber/Flar e VOC/HC L Scrubber s



## -

-

-

-

-

-

-

-

_

- VOC Scrubber/Flar e Proces s Heate r Proces s Heate r Proces s Heate r



## - HCL Scrubber/Incinerato r Condenser/Scrubbe r HC L Scrubbe r



## - Incinerato r Condenser/1nc1ner a to r



## - HC L Scrubbe r Condenser / In

c 1 iterato r



## - Condenser/Scrubbe r



## -

- Scrubbe r Proces s Ven t Strea a Characteristics ' flo w (scfa )

0NA d 

## N O 1 7 ON A 8. 7 Hea t Valu e (Btu/scf )

REACTO R

DN A (lo w flow ) 

## ON A N O N O N O N O N O N O N O N O
N O N O DN A (18.950) ' 

## ON A ON A N O 

# 0« ) DN A 5 5 N O DN A DN A N O 4 0 (267 ) 

## N O 9.19 5 

## N O N O ON A REACTOR REACTOR REACTOR REACTOR REACTOR REACTOR REACTOR REACTOR
REACTOR REACTOR

REACTOR 

## ON

A PROCES S 

## 18 1
DN A 4. 0 DN A DN A PROCES S PROCES S PROCES S PROCES S PROCES S PROCES S PROCES S PROCES S
PROCES S PROCES S 

## DN A (295 ) 

## DN A ON A
PROCES S (163 ) 

## ON A DN A (Assuae d0 ) REACTOR

REACTOR PROCES S



## DN A ON A PROCES S 

## 4 0 (1.228 ) REACTOR
REACTOR REACTOR



## / PROCES S



## 0PROCES S PROCES S 

## DN A VO C (lb/hr )

DN A • VENT S 

## 1 6 i 

## DN A 0. 1 1 4 DN A 

## DN A VENT S VENT S VENT S VENT S VENT S VENT S VENT S
VENT S
VENT S VENT S 

## ON A (75 ) 

## ON A ON A
VENT S (74 ) 

## 2 4 VENT S 

## ON A DN A VENT S 

## 3. 6 (113 ) VENT S 

## 7. 2 VENT S VENT S 

## ON A Ref .

1.2. 3 

## 4. 5 6 7.8.9.1 0 U.12.13 . .15.16.1 7 3 

## 1 9 20.2 1 22.2 3 24.2 5 26.2 7 28.2 9 

## 3 0 3 1 32.3 3 

## 34 35 36 37.3 8 

## 39 4 0 3 4 2 4 3 44 45 4 6 4 7 15 1 13 7 13 8 4 8 4 9 50.5 1 5 2 . 

## 53

, —

### APPENDI XC . EMISSION DATA PROFIL E (Continued )

Uni t Proces s I.O. 1



### HVO- 1 HVD- 2 HYD- 3 HYD- 5 HVO- 6 HYD- 7 HYD- 8 HVO- 9 HYD-1 0 HYD-1 1
HVOC- 3 HVOC- 4 HVDC- 5 HYOC- 6 HYOC- 7 HYDC- 8 HVDC- 9 HVOC-1 0 HYDC- U HYDC-1 2
HVOF- 1 HY0F- 2
HYDI- 1
HYOO- 1 HVOO- 2 HYDO- 3
HVOR- 1 HYDR- 2 HYOR- 3 HYDR- 4
NIT- 1 NIT- 2 NIT- 3
NUT- 1 NUT- 2 HUT- 3 Cheaica l

Hexaaethylen e dlaain e Hexaaethylen e dlaain e Cyclohexan e Anilin e Butanedio l Cyclohexano l 1 ' Toluen e Dlaain e n-Buty l Alcoho l Hexaaethylen e Dlaain e O-Butylen e Methy l Chlorid e Methy l Chlorid e Methy l Chlorid e Ethy l Chlorid e Ethy l Chlorid e Ethy l Chlorid e Ethy l Chlorid e Ethy l Chlorid e Ethy l Chlorid e Epichlorohydri n Ox o Alcohol s Butyraldehyd e Adiponitril e Propylen e Oxid e Se c Buty l Alcoho l Glyceri n Propylen e Glyco l Ethylen e Glyco l Ethylen e Glyco l Ethylen e Glyco l Nitrobenzen e Dinitrotoluen e Dinitrotoluen e Linea r Alkylbenzen e Linea r Alkylbenzen e Plan t Productio n (10 D

### lb/yr )



## 18 0 19 0 1. 6 15 0 ON A ON A ON A DN A DN A DN A Sequentia l Listin g o f AI K Ven t Ga s Treataen t Device s

N o Control s Boile r



## -

- Flar e



## - Incinerato r Condenser/Ref . Condense r Boile r



## - ON A Scrubber/Condenser/Incinerato r 

## 8 0 DN A 100 1 6 ON A DN A DN A DN A 250 50 0 17 5 18 0 350 27 0 DN A ON A 18 3 ON A DN A 12 3 88 ON A 250 DN A Dodecylbenzen e sulfoni c acid . Sodiu a Sal t 

## ON A Refrigerate dCondense r



## - Flar e



## -

-

-

- Condenser/Inc1nerato r Coabustio nDevic e Condenser/Flar e Boile r NH - Scrubbe r Condense r

. Flar e



## -

_

-

-

- N o Control s VO C Scrubbe r VO C Scrubber/Incinerato r



## .

-
" Proces s Ven t Strea a Characteristics' *

flo w (scfa !



## 7 0 (113 ) 

## N O N O DN A N O ON A 5.42 9 (1.304 ) 

## N O DN A 2 0 N O (20 ) 

## N O N O N O N O ON A ON A ON A (729 ) 1.08 0 

## 9 9 DN A DN A N O N O N O N O 1 3 822 ON A N O N O
N O Hea t Valu e (Btu/scf )

REACTOR REACTO R
REACTOR

REACTOR 

## 32

3 (900 ) PROCES S PROCES S 

## DN A PROCES S 

## DN A 776 (462 ) PROCES S 

## ON A (Assua e 500 ) - REACTOR PROCES S (1.286 ) REACTOR REACTOR REACTOR REACTOR PROCES S

PROCES S PROCES S PROCES S 

## DN A DN A DN A (1.233 )

REACTOR REACTOR REACTOR REACTO R

REACTOR REACTOR
REACTOR 

## 7 0

0 DN A ON A PROCES S PROCES S PROCES S PROCES S 

## 43 4 0 ON A PROCES S PROCES S
PROCES S VO C (lb/hr )



## 6. 6 0 VENT S VENT S 

## ON A VENT S 

## DN A 4.04 6 

## (0 ) VENT S 

## ON A 2. 1 VENT S (168 ) VENT S VENT S VENT S VENT S DN A ?.08 0 lb/10 6 

### lb 

## DN A (2.394 ) 

## 27 0. 1 DN A DN A VENT S VENT S VENT S VENT S 

## 1 9 0. 1 ON A VENT S VENT S
VENT S Ref .



## 14 2 14 3 89.9 0 

## 9 1 14 0 7 4 14 1 9 2 93 94 7.9.1 0 

## 9 5 96.9 7 98.9 9 

## 4 8 100.10 1 102,10 3 104.10 5 56.57.10 6 

## 14 6 14 4 10 7 10 8 10 6 60.61.6 2 

## 14 9 106.10 9 110.11 1 

## 11 2 113.11 4 115.11 6 1.12 7 

## 11 6 2.11 9 

## 12 0 14 5


# i'-

### APPENDI XC . EMISSION DATA PROFIL E (Continued )

Uni t Proces s I.O. 1 

### Cheaica l Plan t Production HO9 

### lb/yr ) Sequentia l Listing o f AI K

Ven t Ga s Treataen t Device s Proces s Ven t Strea a Characteristics' " flo w (scfa ) Hea t Valu e (Btu/scf ) VO C (lb/hr ) Ref

.
Oi l £- 1 OilG- 2 OLIG-3 OLIG-4 OLIG-5
0X1- 1 0X1- 2 0X1- 3 0X1- 4


### OXYA- 1
OXVC- 1
PHO- 1
PYR- 1 PYR- 2 PYR- 3 PVR- 4 PVR- S PYR- 6 PVR- 7


### SUL- 1

SULP- 1 Octen e DN A Dodecen e ON A a-Butyfen e ON A TrlproftlM M

DN

A Dodecen e DN A Adipi c Aci d64 0 Adipi c Aci d10 0 Adipi c Aci d70 0 Ethylen e Oxid e 29 2 Viny l Acetat e 39 8 Ethylen e Dichlorid e 91 2 Toluen e Diisocyanat e ON A
Keten e 30 0 Ethylen e ON A Keten e 60 0 Propylen e ON A Ethylen e DN A Viny l Chlorid e Honoae r 31 0 Blvlny l DN A Dodecylbenzen e sulfoni c aci d3 0 Carbo nDisulfid e DN A NH 3 

### Scrubbe r

No Control s NH - Scrubber/Boile r N o Control s
N o Control s Incinerato r

Aci dGa s Scrubbe r NO N O N O N O N O 2.80 0 84 8 (4.653 ) 12.18 7 

## 7 * (304 ) 

## N O
NO N O NO N O NO NO N O

1.86 3 

## N O REACTOR REACTOR REACTOR REACTOR REACTOR

REACTOR
REACTOR REACTOR REACTOR REACTOR REACTOR REACTOR REACTOR

REACTOR PROCES S

PROCES S PROCES S PROCES S PROCES S 0 0 (0 ) 4 

## 407 (713 )
PROCES S
PROCES S PROCES S PROCES S PROCES S PROCES S PROCES S PROCES S



## 0
PROCES S VENT S

VENT S VENT S VENT S VENT S 0 0 (0 ) 13 0 

## 0. 1 (748 )
VENT S
VENT S VENT S VENT S VENT S VENT S VENT S VENT S



## 0. 1
VENT S 12 1

12 1 12 2 12 3 12 4
12 5 14 7 126.12 7 12 8 129.13 0 131.13 2 14 8
5 4 133.13 4 5 5 13 5 13 5 13 6 9 2

5 6 13 7

c o

c o

### a . Proces s unit s m identifie db y

th e cheaica l reactio nassociate dwit hthei r aanufacture . Reactio ncode s ar e a s follows : 

# AI K ANN I 

# AN N CA R CL E CU E CH L CON t OEH Y 

# OE M O.H C 

# ES T ET H ETH V 

# FL U - Alkylatio n

- Aanlnatio n

- Aaaonylisi s

- Carbonylatio n

- Clevag e

- Catalyti c Reformin g

- Chlorinatio n

- Condensatio n

- Dehydratio n

- Dehydrogenatio n

- Dehydrochlorinatio n

- Esterificatio n

- Etherlficatlo n

- Cthyaylatlo n

- Fluorloatio n 

# HV O HVO C HYO F HYO I HYD O 

# NI T NU T OLI G O XI OXV A OXV C 

# PH O PV R SU L SUL P Hydrogenatio n Hydrochlorinatio n Hydrofonaylatlo n Hydrodiaertzatlo n Hydrolysi s Nitratio n Neutralizatio n Ollganerlzatlo n Oxidatio n(Pur e 0- ) Oxyacetylatio n Oxychlorinatio n(Pur e 0. ) Phosgenatto n Pyrolysl s Sulfonatio n Sulfurtzatlo n(Vapo r Phase )



# c n b . Thi s listin g Identifie s al l proces s ven t strea a treataen t devices . Includin g al l coabustlo nan dnoncaabustlo ndevice s Identifie dI n th e dat a base . Device s ar e no t liste dwhe n(1 ) ther e i s n o proces s ven t strea a o r (2 ) ther e i s a ven t bu t i t I s recycle dwithi nth e proces s o r I s a fee dt o anothe r proces s (e.g. . a hydroge nfee dsteaa) . Al l device s ar e liste dI nth e sequenc e I nwhic hthe y occur .
c . Fo r proces s unit s wher e coabustlo ndevice s ar e used , th e ven t strea a characteristic s presente dir e I nparenthese s an drepresen t th e ven t strea a characteristic s Jus t prio r t o th e coabustlo ndevice . Fo r unit s withou t coabustlo ndevices , th e ven t strea a characteristic s presente drepresen t th e ven t a t It s poin t a t discharg e t o th e ataosphere . Thes e i n th e characteristic s upo nwhic h th e TR E calculatio nf s based . d . DM A - Oat a no t available .
e . Fo r oi l proces s unit s wher e coabustlo nI s currentl y used . I.e. , baseline , al l ven t strea a dat a an dTRE' s m t nparentheses .