p. 1 

# RCRA Box 1883 Prepped by Ollie Stewart



### Document

Number: 

# 30 ) ll-B-19 1 Docket Number: 

# A-90-1 9

Printed 12/3/200810:42:11 AM

Sheet 30of 171P. 2

; 

## A-90-1 9 ll-B-19 1 

### MEMORANDU M TO : Proces s Vents Docke t A-90-1 9 FROM : WandaFloy

d DATE : Decembe

r 199 1 EPAAIRPOCK E SUBJECT : HON NESHAP : Industr y Characteristics/Trietfiahblanii'n e



## ll " 

## B B H O W

## I P 

# mm i l
Attache di s aproduct-proces s summar y (PPS ) fo r th e productio n o

f Triethanolamin e vi a ammonlysi s o

f ethylene oxide . Al

l emission s an

dproces s information i s reference dt o ethanolamine (141435A) . Thi s PPS wa s developeda s par

t o f th e Industria

l Profile project i n suppor t o f the Hazardou s Organic NESHA P (HON ) regulator

y effort . Information i

n thi s PPS i s useda s abasi s fo r emission s an

dcost impact estimate s fo

r th e HON program . 

# Tli e Carrespsodfn g fea% Assuraos

a N . Docuw t i s Oaolie

t !fe. i A-90-1 9

ll-B-25 2P. 3
Preparer : ^> C Oate : 7/3/^6 " Reviewer : ADMINISTRATIV E NOTE

S Pro<foct«Proce$ $ Cod e \&l^\V o fr Hour s spen t o n thi s PP

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d description ) Dat e Cleare d Initial s

Chemical s missin g CA S number s

Plan t wit h Cit vbu t n o Count y(plan t name , city , state )P. 4
Preparer : Date : ~7/~i Reviewer : Chemica l Name PRODUCT-PROCES S SUMMAR Y(PPS ) ^.VtsOutso

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W CHEMICAL SPECIFI C INFORMATIO N 1. 0 U.S . Productio nRe f # _jL_ , P g * \*o^*- . Re f Yea r ^ (indicat e th e sam

e referenc e Informationfo r an y answer s belo

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, ^ x«AC$V H a\\*~*fcA . 1. 8 CommentsP. 5

2. 0 Chemica l End-Us e Re f # , P g # t R e f Yea r
" ^ Percen t3. 0 U.S . Producer s Re f #

3. 2 Nane , Location , an dCapacit y . , P g # . , Re f Yea r



## wil l jpn ? p f K

gQLmillion s o f gallon s

Proces s Use d (us e P- P # ) Unit s

Tota l Capacit yP. 7

PRODUCT-PROCES S SPECIFI C INFORMATIO N 4. 0 Potentia l Product-Processe s (P-P ) Re f # , P g # Commerciall y%Nat' l Najn g Viabl e (Y/n ) Capacit y P- P 1 P- P 2 P- P 3 P- P 4 P- P 5 P- P 6 4. 1 Documentatio n o f P-P s Exclude d

P- P no t Commerciall yViabl e Reason s



### 4- 2 Proe«* $ 

## in thHm 2

_P. 8

C.3^Rii®iirT«»^;Xc1^irone3 l Re f # , P g # A1 r Oxidatio nReactio n Oxidatio nReactio n Alkylatio nReactio n Carbonylatio nReactio n Halogenatio nReactio n Condensatio nReactio n Dehydrogenatio nReactio n Dehydrohalogenatio nReactio n Esteriflcatio nReactio n Hydrogenatio nReactio n Hydrohalogenatio nReactio n Hydroformylatio nReactio n Hydrolysi s Reactio n Nitratio nReactio n Oxyacetylatlo nReactio n Oxyhalogenatio nReactio n Sulfonatio nReactio n Catalyti c Reformatio n Hydrodimerizatio nReactio n Generi c Reactio n 4. 4 Explai nho

w yo uselecte dth e reactio ntyp e i nlin e 4.3 .P. 9

4. 5 Writte nDescriptio n I nth e lef t margin , indicat e reference s an dpag e number s throughou t writte n description .P.1C L

5. 0 Proces s Flow

Diagram (attac ha t en

do f package ) 5. 1 Flow

Diagram Reference : Re f # , P g # 5. 2 Comment s onFlow

Diagram 

### $. 3 Proces s \<$npo§§ftg § Componen t Type s Distillatio nColumn s Absorber s Stripper s Reactor s Condenser s Vaporizer s Other s Re f # . . Pg #



# mmim:Hffjrm

Tata T Nufflbe

*P.1 1

6. 0 Chemica l Dat a 6. 1 Balance dChemica l Reaction s Re f I . , Pg #

6. 2 Chemica l Tre e Re f # . , P g #P.1 2

6. 4 Stoichiometr y

Re f # , p g # Show calculation s an

dassumption s an

dthe nsummariz e 1 ntabl e onnex t page .P.1 3



### 6. 4 Stoichiometr y

Conversio nFactor s 

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### c ) conversio nf*cto r fo > C0-Prodtfc*:« | 

## d ) coftvmfoi * n&u* farCoM^daueo i

* s A S J A V V A ff VWffffffff

f. fff

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### e ) C6»V*itfforF*cSo * TOr Co-Froduc t f |

* V S f, S S S S S S W S A S S S V . M V S SS S SS S S N SASSSSSSSSAwHW 

### f ) Conversio nFacto r Comment sP.1 4



### Stoichiometr y 6.4. 1 Produc t 6.4. 2 Ra w Materialfs ) # 1 # 2 # 3 # 4 # 5 6.4. 3 Co-Product s # 1 # 2 # 3 # 4 # 5 

### $,4t 4 BY-Product s # 1 ; # 2 # 3 # 4 . # 5 6.4. 5 Intermediate s # 1 # 2P.1 5

7. 0 Proces s Ven t Emissio nSource s r - 1 * Aysg^rproces s vtii l eafssiOBs g (Y/N ) 

### 7. 2 Af rOxidatio n v* M emissions ! (Y/N ) Re f #• P

g #

7. 3 Comment

s Re f #, P

g §

TA^ WOXWymrmUfmt (Y/N ) Re f #, P

g #

• • W » S % S S SAVSVWSSSSSVAVSV. S S SSNV . N SV , S SSSS* . ^^^^B^^^^i^ TM \ W g Mi^^BKa^BHH^^ M V " J 

### 7. 5 Comment

s Re f #, P

g #_P.1 6

7« S ITf^0Bf1<J » v6nt"eii1ssfons ^ (Y/N ) Re f # , P

g # 7. 7 NiimbeCpde r v'acmm j 7. 8 Number'no r W&kt" va?«u i 7. 9 Comment

s Re f # , P

g #P.1 7



### 8. 0 Transfe r Emissio nSource s Re f # , Pg # 8v l ®%f$^U/m~&mtWTrtesmre& (Y/N ) 8. 2 Whi t material s ar e transferred ? H I CA S Numbe r 8.2. 1 Produc t 8.2. 2 Co-Product s

8. 3 Comment s Re f # , P g #P.1 8

9. 0 Storag e EmissionSource s Re f # , Pg # 9. 1 Ar e mate r f»T * stored ? (Y/N ) 9. 2 Wha t material s ar e stored ? Storag e Servic e CA S | Typ e 9.2. 1 Produc t 9.2. 2 Co-Product s

9.2. 3 Ra w Material s

9.2. 4 Intermediate s
9. 4 Comment sStrea m # 3 Organic s

HAP s
Wate r Othe r P.1 9

10. 4 Comment s Re f # , Pg #P.2 0

10.0 . Wastewate r Emissio n Source s 

### 10: i r*;w$pfeta r present ? _ _ 10. 2 Describ e wastewate r Re f # . , Pg # (Y/N )

Stream Equipmen t Componen t Numbe r Producin g Wastewate r Comment s on flo w # 1 # 2 # 3 10. 3 Stream

Compositio nRe f # (provid e onl y

i f readil y

available ) Stream # 1 Stea m # 2 . , P g # Organic s Organic s
HAP s HAP s
Wate r Othe r Wate r Othe r