Sampling and Analysis of Water Streams 

Associated with the Development of Marcellus 

Shale Gas 

Final Report 

Prepared for 

Marcellus Shale Coalition 

(Formerly the Marcellus Shale Committee) 

Prepared By 

Thomas Hayes, Principal Investigator 

Gas Technology Institute 

1700 S. Mount Prospect Road 

Des Plaines, IL 60018 

December 31, 2009 
2 

List of Acronyms and Abbreviations 

Acronym Definition Acronym Definition 

ASWCMC Appalachian Shale Water 

Conservation and 

Management Coalition 

 MSC Marcellus Shale Coalition 

BBL/bbl Barrel (42 gallons) PADEP Pennsylvania Department of 

Environmental Protection 

BCF Billion Cubic Feet ug/L Micrograms per liter (ppb)

BTEX Benzene, Toluene, 

Ethylbenzene, Xylenes 

 QAPP Quality Assurance Project Plan 

Flowback 

Water 

The water stream that 

flows from a well in the 

weeks following hydraulic 

fracturing completion 

 TCF Trillion Cubic Feet 

Frac Hydraulic Fracture TDS Total Dissolved Solids 

Frac Job Well completion event 

involving hydraulic 

fracturing 

 TPH Total Petroleum Hydrocarbons 

FSAP Field Sampling and 

Analysis Plan 

 PCB Polychlorinated Biphenyl 

Compound 

mg/l Milligrams per liter (ppm) POTW Publicly Owned Treatment 

Works (a Sewage Treatment 

Facility) 

 WVDEP West Virginia Department of 

Environmental Protection 

 
3 

Table of Contents 

List of Acronyms and Abbreviations.............................................................................. 2

Executive Summary ...................................................................................................... 6

1.0 Introduction ........................................................................ 9

2.0 Methods and Procedures ................................................. 10

3.0 Results and Discussion.................................................... 19

3.1 Flowback Water Collection Characteristics ...................... 22

4.0 Implications for Fate and Transport.................................. 37

5.0 Conclusions...................................................................... 40

6.0 References Cited.............................................................. 42

Appendix ..................................................................................................................... 45

Appendix A – Field Sampling and Analysis Plan (FSAP) ........................................ 45

Appendix B – Quality Assurance Project Plan (QAPP)............................................ 45

Appendix C – Tabulated Data Obtained from Locations A - S................................. 45

Appendix D – Summary of Detected VOC, SVOC, Pesticides and PCBs ............... 45
4 

List of Figures 

Figure 1. Sampling Locations in Pennsylvania

Figure 2. Sampling Locations in West Virginia. 

Figure 3. Salt Concentration and Flowback Water Flow Versus Time from Location B
5 

List of Tables 

Table 1. Measurements and Determinations 

Table 2. Summary of Methods 

Table 3. Water Use and Flowback Water Collection Associated with Hydraulic 

Fracturing Completion of Shale Gas Wells 

Table 4. Concentration of Total Dissolved Solids in Flowback Water at 19 

Locations, mg/L 

Table 5. Summary of Chemical Characteristics of Influent Water(1) Used for 

Hydraulic Fracturing after Additives(2) Were Blended 

Table 6. Summary of Chemical Characteristics of Water Supplies(1) used for 

Hydraulic Fracturing before Additives were Blended 

Table 7. Summary of Chemical Characteristics of Flowback Water Sampled 5 

Days Following the Hydraulic Fracturing Event(1)

Table 8. Summary of Chemical Characteristics of Flowback Water Sampled at 14 

Days Following the Hydraulic Fracturing Event (1) 

Table 9. Total Metals Concentrations in the Influent Water and 5-day Flowback 

Water Obtained from 19 Locations 

Table 10. Comparisons of Metals Levels in Shale Gas Waters with Municipal 

Biosolids (Sewage Sludge) 
6 

Executive Summary 

At current estimates of recoverable natural gas of more than 489 tcf, the Marcellus 

Shale is considered to be among the largest natural gas reserves in the world. The 

development of this resource is technology driven, involving the use of hydraulic 

fracturing technology as one of the necessary initial steps to releasing natural gas from 

shale rock. Sustainable development of shale gas in the Marcellus Play requires the 

management of volumes of water in a manner that is protective of human health and 

the environment. Typically, 1 - 4 million gallons of an aqueous influent stream bearing 

very low concentrations of additives are introduced downhole during each well 

completion. These additives may include friction reducers, corrosion inhibitors, 

oxygen scavengers, scale inhibitors and biocides that can be blended into the water 

and sand mixture, but make up less than 0.5 percent of the total frac fluid that is 

injected into a drilled well at high pressures to achieve and maintain the fracture of the 

shale rock. Following fracturing, flowback water is collected from the well and placed 

into frac tanks and/or flowback impoundments. 

Effective management of flowback water requires some level of knowledge of the 

characteristics of the water. Flowback water contains salts, metals and organic 

compounds from the formation and the compounds that were introduced as additives 

to the influent stream. Discussions between the industry and regulatory agencies of 

Pennsylvania and West Virginia have pointed to the need for an information base on 

the composition and properties of flowback water and on the influent water streams 

that are used to perform frac jobs. The objective of this effort was to conduct the initial 

sampling and analysis of water streams associated with shale gas development in the 

Marcellus Shale. 

In recognition of the importance of this effort, 17 member companies of the Marcellus 

Shale Coalition (MSC) volunteered 19 locations where shale gas wells were scheduled 

to be hydraulically fractured. The Field Sampling and Analysis Plan and the Quality 

Assurance Project Plan were developed, reviewed, and finalized for the effort by the 
7 

companies of the Appalachian Shale Water Conservation and Management 

Committee (ASWCMC), Pennsylvania Department of Environmental Protection 

(PADEP) and West Virginia Department of Environmental Protection (WVDEP). At 

each of the host sites, samples of influent water streams at Day 0 and the flowback 

water streams at 1, 5, 14, and 90 days following the frac job event were collected by a 

single engineering subcontractor, URS. All samples were sent to Test America (a 

PADEP and WVDEP certified environmental testing laboratory) for analyses. The list 

of constituents recommended for the characterization study was developed from 

comments received from the PADEP, the WVDEP and members of the ASWCMC. 

Categories of determinations that were conducted included: 1) General Chemistry, 2) 

Organic Compounds, and 3) Metals. Once reviewed and qualified, data from these 

analyses were organized and tabulated in a source blind manner into an Excel 

spreadsheet that currently represents the information base. 

Results from this effort indicates that values for pH, alkalinity, total dissolved solids 

(TDS), total organic carbon (TOC), oils and greases and other parameters from 

general water characterization are within the normal ranges reported for conventional 

produced waters by the USGS. Flowback water concentrations of TDS ranged from 

680 to 345,000 mg/l; typical profiles show an increase in TDS in flowback water with 

time following a frac job event. As with conventional produced water, shale gas 

flowback water cations are dominated by sodium and calcium; the main anion is 

chloride. Metals normally seen in conventional produced waters, such as iron, 

calcium, magnesium, and boron, are at levels in flowback waters that are well within 

known ranges for normal produced waters. Heavy metals that are of concern in urban 

industrial wastewaters and POTW sludges --- such as chromium, copper, nickel, zinc, 

cadmium, lead, arsenic and mercury --- are at very low levels. Among volatile organic 

constituents (VOCs), approximately 96% of the constituent determinations were at 

non-detectable levels and less than 0.5% were detected above 1 ppm. VOCs that are 

measurable are those that are normally found in conventional produced waters. 

Regarding semi-volatile organic constituents (SVOCs), more than 98% of the 

determinations were at non-detectable levels and less than 0.03% of all the 

constituents were above 1 ppm; and several constituents were at low trace levels – 
8 

usually below 10 ppb. Pesticide concentrations measured in the samples were 

extremely low (all results were less than 1 ug/L) and extremely random with results 

occurring in some supply water, Day 0, Day 14 and Day 90 samples. It is possible that 

these low level concentrations are not representative of actual conditions and may be 

attributed to laboratory contamination or instrument noise. 

In conclusion, the results of this shale gas water characterization effort indicate that all 

pesticides, PCBs, and a large fraction of the VOC and SVOC should be considered to 

be unnecessary for the sampling and analysis of flowback waters in the future. 
9 

1.0 Introduction 

The Marcellus Shale formation is the largest known shale deposit in the world. It 

overlies much of the Appalachian Basin from West Virginia in the south, to Upstate 

New York in the north, and Ohio to the west. The recoverable reserves of natural gas 

in the Marcellus shale have been estimated at more than 489 trillion cubic feet 

(Engelder, 2008). 

Recent advances in horizontal drilling and multi-stage hydraulic fracturing technologies 

have made sustainable natural gas production viable from otherwise uneconomical, 

unconventional shale reservoirs such as the Barnett, Haynesville, Fayetteville, 

Woodford, et al. These tools and technologies have been successfully applied and 

currently enable the ongoing development of the Marcellus Shale. This development 

is currently underway in both West Virginia and Pennsylvania with the majority of the 

wells drilled and completed in southwest and northeast Pennsylvania. 

Many of the logistical challenges associated with the development of shale gas stem 

from the amounts of water associated with the completion and operation of shale gas 

wells that must be transported, stored and disposed of in a manner that is protective of 

human health and the environment. In the course of developing shale gas in the 

Appalachian Basin, thousands of wells will be drilled and completed. Hydraulic 

fracturing (“fracing”) is a necessary step for the completion of each of these wells in 

order to achieve economic well performance in terms of natural gas production. This 

step requires between 1 and 4 million gallons (23,800 and 95,200 bbl) of water for 

successful completion of each well; vertical wells require approximately 1 million 

gallons (23,800 bbl) and horizontal wells require 3-4 million gallons (71,400 to 95,200 

bbl) (Gaudlip, et al., 2008). 

During a typical “frac job,” water is pumped downhole while additives such as friction 

reducers and various grades of sand are introduced to ensure a successful fracture 

and completion of the shale. Following hydraulic fracturing, a fraction of the water 
10 

(approximately 25%) that was injected is collected over several days resulting in the 

collection of a “flowback” water stream that contains salts, oils and greases, and 

soluble organics (volatile and semi-volatile) that accumulated in the water downhole. 

Flowback water also contains low concentrations of additives that are introduced 

during the frac job which normally include friction reducing polymers, corrosion 

inhibitors, scale inhibitors, and biocides. These additives facilitate the hydraulic 

fracturing process and prevent problems with well operation. 

The first steps in identifying effective water management alternatives include an 

effective analysis of the characteristics of the water streams involved in shale gas 

development. The overall objective of this project is to develop an information base on 

the nature and composition of influent water and flowback waters associated with 

completions of shale gas wells in the Marcellus Shale. 

2.0 Methods and Procedures 

17 member companies of the MSC volunteered 19 locations for the sampling of 

influent and effluent water streams. At each location, a well completion was 

conducted using hydraulic fracturing procedures that involved the injection of an 

influent stream of water and the subsequent collection of flowback water. Standard 

procedures were used to conduct sampling and analysis needed for the development 

of water characterization data. All sampling was performed by the GTI subcontractor, 

URS, following the same standard procedures. All sample analyses were performed 

by a single laboratory, Test America of Pittsburgh, PA. Test America, an independent 

analytical laboratory, provided the appropriate sample containers, preservatives and 

completed the analytical analyses. Test America is certified in West Virginia and 

Pennsylvania. Data tabulation, analysis and information base development was 

provided by the Gas Technology Institute for this effort. 

Details of the methods and procedures used for the collection and analysis of samples 

obtained from each of the 19 locations are found in the Field Sampling and Analysis 

Plan (FSAP) which is located in Appendix A. The Field Sampling and Analysis Plan 
11 

(FSAP) was developed to ensure that the data and information gathered for the 

flowback characterization study was properly collected and documented. 

A major aim of the characterization study was to generate technically sound data. To 

meet this objective a Quality Assurance Project Plan (QAPP) was used to generate 

accurate, precise, representative and complete data; this document is provided in 

Appendix B. The QAPP provided the specific quality assurance/quality control 

(QA/QC) procedures executed during the flowback Characterization Study. 

Together the FSAP and QAPP comprise the Sampling and Analysis Plan (SAP). The 

SAP was designed to meet the following informational goals: 

• Identify the specific constituents of interest (COI) associated with flow back 

water; 

• Determine whether hydraulic fracturing additives are a source of COI in the 

management of water associated with shale gas development; and, 

• Provide sufficient information for the selection of proper water management and 

disposal techniques. 

Prior to initiating the characterization study, the SAP was reviewed by regulatory 

officials from the Pennsylvania Department of Environmental Protection (PADEP) and 

the West Virginia Department of Environmental Protection (WVDEP). 

The original SAP proposed that four (4) grab samples be taken from six (6) vertical or 

horizontal well locations throughout West Virginia and Pennsylvania. The following 

grab samples were proposed: 

• One baseline fracturing water sample that includes the fracturing additives, 

excluding the sand; 

• Flowback water samples collected on days 1, 5 and 14 following the fracturing 

process; and 
12 

• Water from an existing producing well at 90 days following hydraulic fracturing. 

The list of constituents recommended for the characterization study was developed 

from comments received from the PADEP, the WVDEP and members of the 

Appalachian Shale Water Conservation and Management Committee (ASWCMC). 

Because the recommended list of constituents was extremely extensive, it was 

decided that one sample from each site would be completed for the full list of 

recommended constituents. All other samples were collected and analyzed for a 

subset of these constituents, which was designed based on generator knowledge. 

Following the first few rounds of sampling, industry identified a data gap with respect 

to characterizing the supply water used for fracturing. Supply water is identified as the 

water used for fracturing prior to introducing the fracing additives. 

The updated protocol characterization study called for the collection of five (5) grab 

samples from the each of the volunteered locations and expanded the sampling effort 

to encompass 19 well locations volunteered by 17 member companies of the 

Marcellus Shale Coalition. Table1 presents the list of all of the constituents of interest 

(by category) that formed the basis for sample analysis. Analytical methods used to 

perform the various determinations are listed in Table 2. 

Under the updated sampling plan, the following grab samples were collected at each 

of the volunteered locations: 

• A supply water sample (before the blending of additives); 

• One influent water sample following blending with fracturing additives, excluding 

sand; 

• Flowback water samples collected on 1, 5 and 14 days after hydraulic 

fracturing; and 

• Water from the producing well at 90 days after completion. 

To address this data gap, it was decided to update the sampling/analysis protocol. 
13 

Following the collection of the samples and the performance of all of the 

determinations, the data was organized, qualified and tabulated by GTI using an Excel 

spreadsheet. 

Table 1. Measurements and Determinations 

General Chemistry 

pH 

Acidity 

Total Alkalinity 

Hardness as CaCO3 

Total Suspended Solids 

Turbidity 

Chloride 

Total Dissolved Solids 

Specific Conductance 

Total Kjeldahl Nitrogen 

Ammonia Nitrogen 

Nitrate-Nitrite 

Nitrite as N 

Biochemical Oxygen 

Demand 

Chemical Oxygen 

Demand 

Total Organic Carbon 

(TOC) 

Dissolved Organic 

Carbon 

Oil & Grease (HEM) 

Cyanide, Total 

Amenable Cyanide 

Bromide 

Fluoride 

Total Sulfide 

Sulfate 

Total Phosphorus 

Total Recoverable 

Phenolics 

Volatile Organic Compounds 

1, 4 - Dichlorobenzene 

1, 3 – Dichloropropane 

2, 2 – Dichloropropane 

1, 1 – Dichloropropene 

p – Isopropyltoluene 

Naphthalene 

n – Propylbenzene 

1, 2, 3 - Trichlorobenzene 

1, 2, 4 - Trichlorobenzene 

1, 2, 4 - Trimethylbenzene

1, 3, 5 - Trimethylbenzene

Benzyl chloride 

Isopropylbenzene 

2 – Butanone 

Methyl tert - butyl ether 

(MTBE) 

Xylenes (total) 

2 - Chloroethyl vinyl ether 

Cis - 1, 2 - Dichloroethene

Acetone 

Acrolein 

Acrylonitrile 

Benzene 

Bromodichloromethane 

Bromoform 

Bromomethane 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chloroethane 

Chloroform 

Chloromethane 

Dibromochloromethane 

1, 2 - Dibromo - 3 – 

chloropropane 

1, 2 - Dibromoethane (EDB) 

Dibromomethane 

Dichlorodifluoromethane 

1, 4 – Dioxane 

Ethylbenzene 

Ethylene Glycol 

2 – Hexanone 

Methylene chloride 

4 - Methyl - 2 - pentanone 

(MIBK) 

Styrene 

1, 1, 1, 2 – 

Tetrachloroethane 

1, 1, 2, 2 – 

Tetrachloroethane 

Tetrachloroethene 

Toluene 

1, 1, 1 – Trichloroethane 

1, 1, 2 – Trichloroethane 

Trichloroethene 

Trichlorofluoromethane 

1, 2, 3 – Trichloropropane 

Vinyl acetate 
14 

Bromobenzene 

n – Butylbenzene 

sec – Butylbenzene 

tert – Butylbenzene 

4 – Chlorotoluene 

1, 2 - Dichlorobenzene 

1, 3 – Dichlorobenzene 

1, 1 – Dichloroethane 

1, 2 – Dichloroethane 

1, 1 – Dichloroethene 

trans - 1, 2 - Dichloroethene 

1, 2 - Dichloropropane 

cis - 1, 3 - Dichloropropene 

trans-1, 3 - Dichloropropene 

Vinyl chloride 

Tert - butyl acetate 

Tetrahydrofuran 

1 - chloro - 4 – 

trifluoromethylbenz 

Semivolatile Organic Compounds 

Diphenylamine 

Benzidine 

bis (2 - Chloroisopropyl) 

ether 

1, 4 – Dioxane 

1, 2 – Diphenylhydrazine 

Acenaphthene 

Acenaphthylene 

Acetophenone 

2 – Acetylaminofluorene 

4 – Aminobiphenyl 

Aniline 

Benzo (a) anthracene 

Benzo (a) pyrene 

Benzo (b) fluoranthene 

Benzo (ghi) perylene 

Benzo (k) fluoranthene 

Benzyl alcohol 

bis (2 - Chloroethoxy) 

methane 

bis (2 - Chloroethyl) – 

ether 

bis (2 - Ethylhexyl) 

phthalate 

4 - Bromophenyl phenyl 

ether 

Butyl benzyl phthalate 

4 – Chloroaniline 

4 - Chloro - 3 – 

methylphenol 

2 – Chloronaphthalene 

2 – Chlorophenol 

4 - Chlorophenyl phenyl 

ether 

Chrysene 

Diallate 

Diethyl phthalate 

Dimethoate 

p - 

Dimethylaminoazobenzene 

7, 12 - Dimethylbenz (a) – 

anthracene 

2, 4 – Dimethylphenol 

Dimethyl phthalate 

Di - n - octyl phthalate 

1, 3 – Dinitrobenzene 

4, 6 - Dinitro - 2 – 

methylphenol 

2, 4 – Dinitrophenol 

2, 4 – Dinitrotoluene 

2, 6 – Dinitrotoluene 

Dinoseb 

Disulfoton 

Ethyl methanesulfonate 

Fluoranthene 

Fluorene 

Hexachlorobenzene 

Hexachlorobutadiene 

Hexachlorocyclopentadiene 

Hexachloroethane 

Hexachloropropene 

Indeno (1, 2, 3 - cd) pyrene 

Isodrin 

Isophorone 

Isosafrole 

3 - Methylcholanthrene 

Methyl methanesulfonate 

2 - Methylnaphthalene 

2 – Methylphenol 

3 - Methylphenol & 4 – 

Methylphenol 

Nitrobenzene 

2 – Nitrophenol 

4 – Nitrophenol 

N - Nitrosodi - n – 

butylamine 

N – Nitrosodiethylamine 

N – Nitrosodimethylamine 

N - Nitrosodi - n – 

propylamine 

N – Nitrosodiphenylamine 

N – 

Nitrosomethylethylamine 

N – Nitrosomorpholine 

N – Nitrosopiperidine 

N – Nitrosopyrrolidine 

5 - Nitro - o – Toluidine 

Parathion 

Pentachlorobenzene 

Pentachloroethane 

Pentachloronitrobenzene 

Pentachlorophenol 

Phenanthrene 

Phenol 

Phorate 

2 – Picoline 

Pronamide 

Pyrene 

Pyridine 

Safrole 

1, 2, 4, 5 – 

Tetrachlorobenzene 

2, 3, 4, 6 Tetrachlorophenol

Thionazin 

o – Toluidine 

1, 2, 4 – Trichlorobenzene 
15 

Dibenz (a, h) anthracene 

Dibenzofuran 

Di - n butyl phthalate 

1, 2 – Dichlorobenzene 

1, 3 – Dichlorobenzene 

1, 4 – Dichlorobenzene 

3, 3' – Dichlorobenzidine 

2, 4 – Dichlorophenol 

2, 6 – Dichlorophenol 

Naphthalene 

1, 4 - Naphthoquinone 

1 – Naphthylamine 

2 – Naphthylamine 

2 – Nitroaniline 

3 – Nitroaniline 

4 – Nitroaniline 

2, 4, 5 – Trichlorophenol 

2, 4, 6 – Trichlorophenol 

O, O, O – 

Triethylphosphorothioate 

Chlorobenzilate 

Aramite 

Metals 

Aluminum 

Antimony 

Arsenic 

Barium 

Beryllium 

Boron 

Calcium 

Cadmium 

Cobalt 

Chromium 

Trivalent Chromium 

Copper 

Iron 

Lead 

Lithium 

Magnesiium 

Manganese 

Molybdenum 

Nickel 

Potassium 

Sodium 

Selenium 

Tin 

Strontium 

Titanium 

Thallium 

Zinc 

Pesticides 

Chlordane (Technical) 

alpha – BHC 

beta – BHC 

delta – BHC 

gamma - BHC (Lindane) 

Heptachlor 

Aldrin 

Heptachlor epoxide 

Endosulfan I 

Dieldrin 

4, 4' – DDE 

Endrin 

Endrin ketone 

Endrin aldehyde 

Endosulfan II 

4, 4' – DDD 

Endosulfan sulfate 

4, 4' – DDT 

Methoxychlor 

Toxaphene 

Organophosphorus Pesticides 

Thionazin Ethyl parathion Tetraethyldithiopyrophosphate 

Polychlorinated Biphenyls (PCBs) 
16 

Aroclor 1016 

Aroclor 1221 

Aroclor 1232 

Aroclor 1242 

Aroclor 1248 

Aroclor 1254 

Aroclor 1260 
17 

Table 2. Summary of Methods 

Parameter Analytical Method Preparation Method 

pH SW846 9040 SW846 9040 

Acidity (Titrimetric) SM20 2310 B (4a) 

Alkalinity, Total SM18 2320 B SM18 2320 B 

Amenable Cyanide SM18 4500-CN E SM18 4500-CN E 

Biochemical Oxygen Demand SM18 5210 B SM18 5210 B 

Bromide MCAWW 300.1A MCAWW 300.1A 

Chemical Oxygen Demand MCAWW 410.4 MCAWW 410.4 

Chloride MCAWW 300.1A MCAWW 300.1A 

Cyanide, Total SW846 9012A SW846 9012A 

Dissolved Organic Carbon SW846 7196A SW846 7196A 

Fluoride MCAWW 300.1A MCAWW 300.1A 

Hexavalent Chromium EPA 901.1 MOD 

Hardness, Total SM20 2340C 

Mercury in Liquid Waste SW846 7470A SW846 7470A 

N-Hexane Extractable Material CFR136A 1664A H EPA 1664A 

Nitrate as N MCAWW 300.1A MCAWW 300.1A 

Nitrite-Nitrate MCAWW 353.2 MCAWW 353.2 

Nitrite as N MCAWW 300.1A MCAWW 300.1A 

Nitrogen, Ammonia MCAWW 350.1 MCAWW 350.1 

Organochlorine Pesticide SW846 8081A SW846 3510C 

Organophosphorus Compounds SW846 8141A SW846 3510 

Phenolics SW846 9066 SW846 9066 

Polychlorinated Biphenyls SW846 8082 SW846 3510C 

Semivolatile Organic Compounds SW846 8270C SW846 3520C 

Specific Conductance MCAWW 120.1 MCAWW 120.1 

Sulfate MCAWW 300.0A MCAWW 300.0A 

Sulfides, Total SW846 9030B/903 SW846 9030B/903 
18 

Table 2. Summary of Methods 

Parameter Analytical Method Preparation Method 

Total Phosphorus MCAWW 365.2 MCAWW 365.2 

Total Dissolved Solids SM18 2540 C 

Total Kjeldahl Nitrogen MCAWW 351.3 MCAWW 351.3 

Total Organic Carbon SM20 5310B 

Total Suspended Solids SM20 2540D 

Trace Inductively Coupled 

Plasma Metals 

SW846 6010B 

SW846 6010B 

SW846 3005A 

SW846 3010A 

Trivalent Chromium SW846 6010B Wet None 

Turbidity (Nephelometric) MCAWW 180.1 MCAWW 180.1 

Volatile Organics by GC/MS SW846 8260B SW846 5030B 

Ethylene Glycol SW846 8015 SW846 8015 

Methylene Blue Activated 

Substances (MBAS) 

SM5540C SM5540C 
19 

3.0 Results and Discussion 

Throughout the performance of the flowback water sampling program, natural gas 

development companies of the Marcellus Shale provided third party access to each of 

the sampled well sites. This access was necessary to obtain the critical flowback 

water samples at the standardized times of 0, 1, 5, and 14 days following the hydraulic 

fracturing event. About a third of the companies assisted with the collection of a 90 

day sampling of the flowback water, as well. 

In total, 17 shale gas companies enabled the sampling of 19 locations within the 

Marcellus Shale Region, including 3 locations in West Virginia and 16 locations in 

Pennsylvania, as shown in the maps of Figures 1 and 2. The approximate positions of 

all of the sampling locations (Locations A through S) are indicated on the maps. 

Locations in West Virginia included 2 well completion sites in Lewis County and 1 

completion site in Taylor County; both counties are in the northern half of the state, as 

seen in Figure 2. 

Host sites in Pennsylvania were well-distributed across the Commonwealth, involving 

sampling in the Southwestern, Central, Northern and Northeastern regions of the state 

representing the locations where most of the shale gas development is occurring. Half 

of the sites sampled (a total of 8) were located in the Southwestern area of the state 

as indicated on the map of Figure 1. Two sites were located in the Central portion and 

two sites were located on the Northeastern side of the state. The remaining four 

locations are positioned in the northern tier of Pennsylvania as shown in Figure 1. 
20 

Figure 1. Sampling Locations in Pennsylvania.
21 

Host sites in West Virginia, on the other hand, were located in three counties of the 

northern section of the state. 

Figure 2. Sampling Locations in West Virginia. 

 

Results from the analysis of all samples taken from Locations A through S have been 

tabulated. Measurements and determinations included the following: 1) General 

Chemistry; 2) Organic Compounds; and, 3) Metals. Tables of these results are 

presented in Appendix C. 
22 

3.1 Flowback Water Collection Characteristics 

As previously mentioned, the completion of each shale gas well examined in this 

project required the introduction of a substantial volume of influent water (bearing 

additives and sand) over a period of hours to achieve hydraulic fracturing. Following 

successful fracturing, a water stream emerges from the well under pressure; this 

stream is collected in frac tanks or in impoundments. The initial volume of water that 

is collected shortly after well completion is called flowback water. Beyond the 

completion period, water from the formation is co-produced with natural gas over time. 

Water volumes associated with 14 of the 19 wells sampled in this project are shown in 

Table 3. Of the 14 wells reporting water volume information, six wells were vertical 

wells and eight wells were of horizontal configuration. Of the vertical wells, an average 

of approximately 40,000 bbls of influent water were used to achieve fracturing, and 

about 16,000 bbls on average were collected within a 90 day period. Of the horizontal 

wells, an average of approximately 90,000 bbls of influent water were used to achieve 

fracturing, followed by a collection of about 18,000 bbls of effluent water (flowback). 

Cumulative volumes of water collected over time for these 14 completed wells are 

tabulated in Table 3. 

Salt concentrations in influent water and in flowback water generated over time from 

the 19 sampling locations are tabulated in Table 4. As shown in Table 4, influent 

water usually contains moderate to low concentrations of salts. Following the use of 

this water for hydraulic fracturing, a flowback water stream that is collected from the 

well exhibits increasing concentrations of salts with time. Evidently, the water 

introduced down-hole picks up soluble inorganic constituents from the formation 

(consisting mostly of sodium and calcium chloride); as this water resides down hole, it 

picks up increasing concentrations of total dissolved solids. 
23 

Table 3. Water Use and Flowback Water Collection Associated with Hydraulic 

Fracturing Completion of Shale Gas Wells 

Cumulative Volume of Flowback Water, bbls 

Location Well Type 

Total Vol. 

Frac Fluid 

Used, 

bbls 1 Day* 5 Days 14 Days 90 Days 

Percent 

Collected

A Vertical 40,046 3,950 10,456 15,023 37.5 

B Vertical 94,216 1,095 10,782 13,718 17,890 19.0 

C Horizontal 146,226 3,308 9,652 15,991 10.9 

D Horizontal 21,144 2,854 8,077 9,938 11,185 52.9 

E Horizontal 53,500 8,560 20,330 24,610 25,680 48.0

F Horizontal 77,995 3,272 10,830 12,331 17,413 22.3

G Horizontal 123,921 1,219 7,493 12,471 18,677 15.1

H Vertical 36,035 3,988 16,369 21,282 31,735 88.0 

K Horizontal 70,774 5,751 8,016 9,473 13.4 

M Horizontal 99,195 16,419 17,935 19,723 19.9 

N Vertical 11,435 2,432 2,759 3,043 3,535 30.9 

O Horizontal 96,706 5,131 19,202 19.8 

Q Vertical 23,593 1,315 3,577 5,090 21.6 

S Vertical 16,460 2,094 7,832 9,345 10,723 65.1 

 Weighted Average % Collected 24.3 

* Days from the hydraulic fracturing event. 

A typical profile of salt concentrations measured in flowback water with time is shown 

in Figure 3. In this figure, data from Location B is plotted. As seen in this diagram, 

early flowback water emerging soon after the frac job is relatively low in TDS content; 

following the initial day, the concentration of total dissolved solids increases with time 

from low salt concentrations to a plateau of elevated salt levels as measured at 14 and 

90 days. Also shown in this diagram is the marked concomitant decrease in flowback 

brine flow with time, exhibiting a high initial flow rate of over 2,400 bbls/day, then 

decreasing to a minimal flow rate of less than 55 bbls/day after the initial few weeks 

following completion, a 98% reduction of daily flow. It should be mentioned that the 

lowest flow rate bar shown on the chart in Figure 3 was calculated from cumulative 

water data between 14 and 90 days; actual flows in the 60 to 90 day period are 
24 

significantly less than 55 bbls/day. The diagram, however, demonstrates that although 

the TDS levels in the flowback water emerging between 14 and 90 days almost 

doubles to nearly reach 200,000 mg/l, the daily brine volumes produced by the well 

decrease to a deminimus level that can be easily managed as a normal produced 

water stream. 

Table 4. Concentration of Total Dissolved Solids in Flowback Water at 19 

Locations, mg/L 

Location Day 0* Day 1 Day 5 Day 14 Day 90 

A 990 15,400 54,800 105,000 216,000 

B 27,800 22,400 87,800 112,000 194,000 

C 719 24,700 61,900 110,000 267,000 

D 1,410 9,020 40,700 155,000 

E 5,910 28,900 55,100 124,000 

F 462 61,200 116,000 157,000 

G 1,920 74,600 125,000 169,000 

H 7,080 19,200 150,000 206,000 345,000 

I 265 122,000 238,000 261,000 

J 4,840 5,090 48,700 19,100 

K 804 18,600 39,400 3,010 

L 221 20,400 72,700 109,000 

M 371 228,000 

N 735 31,800 116,000 

O 2,670 17,400 125,000 186,000 

P 401 11,600 78,600 63,900 

Q 311 16,600 38,500 120,000 

R 481 15,100 46,900 20,900 

S 280 680 58,300 124,000 

 

* Day 0 sample was taken of the influent water plus additives without sand. 
25 

Figure 3. Salt Concentration and Flowback Water Flow Versus Time from 

Location B

3.1.1 General Chemistry 

A summary of the general chemical characteristics of the water influent streams and 

the flowback water effluents associated with the completion and operation of wells of 

the 19 sampling locations are presented in Tables 5-8. Characteristics of influent 

water, identified as Day 0 samples, after the blending of additives (not including sand) 

at each of the locations are shown in Table 5. The pH of these streams ranging from 

5.2 to 8.9 is generally representative of surface waters; however, the wide range of 

total dissolved solids (221 to 27,800 mg/l) reflects the implementation of water reuse 
26 

Table 5. Summary of Chemical Characteristics of Influent Water(1) Used for 

Hydraulic Fracturing after Additives(2) Were Blended 

Parameter Range Median Units 

pH 5.2 - 8.9 7.2 No Units

Acidity < 5 – 1,230 NC mg/L

Total Alkalinity 5 – 308 NC mg/L

Hardness as CaCO3 26 - 9,500 130 mg/L

Total Suspended Solids 4 - 5,290 NC mg/L

Turbidity 2.7 – 715 249 NTU

Chloride 18 - 10,700 90.2 mg/L

Total Dissolved Solids 221 - 27,800(3) 735 mg/L

Specific Conductance 177 – 34,600 726 Umhos/cm

Total Kjeldahl Nitrogen 2.3 – 400 33.5 mg/L

Ammonia Nitrogen 0.28 – 441 5.9 mg/L

Nitrate-Nitrite 0.1 – 3.1 NC 

Nitrite as N < 0.05 - 5 NC mg/L

Biochemical Oxygen Demand < 2.0 – 2,220 NC g/L 

Chemical Oxygen Demand 35.3 – 47,400 1,730 mg/L

Total Organic Carbon (TOC) 5.6 - 1,260 226 mg/L

Dissolved Organic Carbon 5 - 1,270 301 mg/L

Oil & Grease (HEM) 4.6 – 255 NC mg/L

Cyanide, Total 3.5 – 954 NC ug/L

Amenable Cyanide < 0.01- 0.87 NC mg/L

Bromide < 0.2 – 107 NC mg/L

Fluoride < 0.05 - 58.3 NC mg/L

Total Sulfide < 3 – 8.8 NC mg/L

Sulfate 2.9 – 2,920 NC mg/L

Total Phosphorus < 0.1 – 16 NC mg/L

Total Recoverable Phenolics < 0.01 - 0.77 NC mg/L

Sulfite < 5 – 61.6 NC mg/L

Methylene Blue Active Substances 

(MBAS) < 0.03 – 0.506 NC mg/L

(1) Influent water samples are identified as Day 0; samples at 19 locations, Locations A –S. 

(2) Additives included corrosion inhibitors, scale inhibitors, friction reducers, biocides, and oxygen 

scavengers. Blended water samples were taken before the addition of sand. 

(3) Upper end concentrations in the TDS range may be due to implementation of flowback water reuse 

and blending into the influent stream. 

NC - indicates the median concentration was not calculated due to undetected results.
27 

Table 6. Summary of Chemical Characteristics of Water Supplies(1) used for 

Hydraulic Fracturing before Additives were Blended 

Parameter Range Median Units 

 

pH 6.7 - 7.4 7.2 No Units 

Acidity < 5 – 5.5 NC mg/L 

Total Alkalinity 6.2 – 88.8 52.5 mg/L 

Hardness as CaCO3 18 - 1,080 132 mg/L 

Total Suspended Solids <2 – 24 NC mg/L 

Turbidity 1.3 – 33.7 3.7 NTU 

Chloride 4.1 – 3,000 35.2 mg/L 

Total Dissolved Solids 35 – 5,510(2) 334 mg/L 

Specific Conductance 55 – 10,100 423 umhos/cm 

Total Kjeldahl Nitrogen < 3 – 56.4 NC mg/L 

Ammonia Nitrogen 0.017 – 20.8 0.41 mg/L 

Nitrate-Nitrite < 0.1 – 3.0 NC mg/L 

Nitrite as N < 0.05 – 4.9 NC mg/L 

Biochemical Oxygen Demand < 2.0 – 110 NC mg/L 

Chemical Oxygen Demand < 10 – 924 NC mg/L 

Total Organic Carbon (TOC) 1.8 – 202 3.4 mg/L 

Dissolved Organic Carbon 1.4 – 222 3.2 mg/L 

Oil & Grease (HEM) Not Detected NC mg/L 

Cyanide, Total < 10 – 625 NC ug/L 

Amenable Cyanide < 0.01 - 0.27 NC mg/L 

Bromide < 0.2– 31.9 NC mg/L 

Fluoride < 0.05 - 1.2 NC mg/L 

Total Sulfide 1.6 - 5.6 NC mg/L 

Sulfate 3.8 – 139 26 mg/L 

Total Phosphorus < 0.1 – 0.14 NC mg/L 

Total Recoverable Phenolics 0.01 - 0.031 NC mg/L 

Sulfite 6 – 21.6 10.8 mg/L 

Methylene Blue Active 

Substances (MBAS) < 0.05 - 0.962 NC mg/L 

(1) Water Supplies at 8 Locations: F, H, I, J, L, M, N, S. 

(2) Upper end concentrations in the TDS range may be due to implementation of flowback water reuse 

and blending into the influent stream. 
28 

Table 7. Summary of Chemical Characteristics of Flowback Water Sampled 5 

Days Following the Hydraulic Fracturing Event(1)

Parameter Range Median Units

 

pH 5.8 - 7.2 6.6 No Units 

Acidity < 5 – 447 NC mg/L 

Total Alkalinity 48.8 – 327 138 mg/L 

Hardness as CaCO3 5,100 - 55,000 17,700 mg/L 

Total Suspended Solids 10.8 - 3,220 99 mg/L 

Turbidity 2.3 – 1540 80 NTU 

Chloride 26,400 - 148,000 41,850 mg/L 

Total Dissolved Solids 38,500 – 238,000 67,300 mg/L

Specific Conductance 79,500 – 470,000 167,500 umhos/cm 

Total Kjeldahl Nitrogen 38 – 204 86.1 mg/L 

Ammonia Nitrogen 29.4 –199 71.2 mg/L 

Nitrate-Nitrite < 0.1 – 1.2 NC mg/L 

Nitrite as N 1.2 – 29.3 NC mg/L 

Biochemical Oxygen 

Demand 37.1 - 1,950 144 mg/L 

Chemical Oxygen Demand 195 - 17,700 4,870 mg/L 

Total Organic Carbon (TOC) 3.7 – 388 62.8 mg/L 

Dissolved Organic Carbon 30.7 – 501 114 mg/L 

Oil & Grease (HEM) 4.6 – 655 6.3 mg/L 

Cyanide, Total < 10 - 72.1 NC ug/L 

Amenable Cyanide < 0.01 - 0.032 NC mg/L 

Bromide 185 - 1,190 445 mg/L 

Fluoride < 0.05 – 17.3 NC mg/L 

Total Sulfide < 3 – 5.6 NC mg/L 

Sulfate 2.4– 106 NC mg/L 

Total Phosphorus < 0.01 – 2.5 NC mg/L 

Total Recoverable Phenolics < 0.01 – 0.31 NC mg/L 

Sulfite 2.5 – 38 NC mg/L 

Methylene Blue Active 

Substances (MBAS) <0.012 –1.52 0.133 mg/L 

(1) Median values at 19 locations: Locations A – S. 

NC – indicates the median concentration was not calculated due to undetected results. 
29 

Table 8. Summary of Chemical Characteristics of Flowback Water Sampled at 

14 Days Following the Hydraulic Fracturing Event (1) 

Parameter Range Median Units

pH 4.9 – 6.8 6.2 No Units 

Acidity < 5 – 473 NC mg/L 

Total Alkalinity 26.1 – 121 85.2 mg/L 

Hardness as CaCO3 630 – 95,000 34,000 mg/L 

Total Suspended Solids 17 – 1,150 209 mg/L 

Turbidity 10.5 – 1,090 233 NTU 

Chloride 1,670 – 181,000 78,100 mg/L 

Total Dissolved Solids 3,010 – 261,000 120,000 mg/L 

Specific Conductance 6,800 710,000 256,000 Umhos/cm 

Total Kjeldahl Nitrogen 5.6 – 261 116 mg/L 

Ammonia Nitrogen 3.7 – 359 124.5 mg/L 

Nitrate-Nitrite < 0.1 – 0.92 NC mg/L 

Nitrite as N < 2.5 – 77.4 NC mg/L 

Nitrate as N < 0.5 - < 5 NC mg/L 

Biochemical Oxygen Demand 2.8 – 2070 39.8 mg/L 

Chemical Oxygen Demand 228 – 21,900 8530 mg/L 

Total Organic Carbon (TOC) 1.2 – 509 38.7 mg/L 

Dissolved Organic Carbon 5 – 695 43 mg/L 

Oil & Grease (HEM) < 4.6 – 103 NC mg/L 

Cyanide, Total < 10 NC ug/L 

Amenable Cyanide <0.01 NC mg/L 

Bromide 15.8- 1,600 704 mg/L 

Fluoride < 0.05 – < 50 NC mg/L 

Total Sulfide < 3.0 - 3.2 NC mg/L 

Sulfite (2) 7.2 – 73.6 13.8 Mg/l 

Sulfate <10 - 89.3 NC mg/L 

Total Phosphorus < 0.1 – 2.2 NC mg/L 

Total Recoverable Phenolics < 0.01 – 0.31 NC mg/L 

Sulfite 7.2 – 73.6 13.8 mg/L 

Methylene Blue Active 

Substances (MBAS) (2) <0.05 - 4.6 NC mg/L 

(1) Samples were collected from 17 locations. Day 14 samples were not collected at locations D and N. 

(2) Sulfite and MBAS were not sampled at locations B and C. 

NC – indicates the median concentration was not calculated due to undetected results. 

 
30 

 (i.e. the use of a portion of the flowback water from the completion of one well to 

blend with the freshwater influent stream for the next well completion) at a minority of 

the locations. Dissolved solids measurements for the influent waters used for 

hydraulic fracturing (with additives) had a median value of 735 mg/l, which is 

considered in the range of fresh surface water supplies. Interestingly, oil and grease 

measurements had a range of 4.6 to 255 mg/l while total organic carbon 

concentrations ranged from 5.6 to 1,260 mg/l. Elevated values in these 

measurements may be due to various degrees of blending of reused waters into frac 

job influent water supplies. 

A summary of the same characteristics is tabulated for water supplies from 8 locations 

(F, H, I, J, L, M, N, S) in Table 6; information in this table provides an indication of the 

quality of influent water before the blending of additives. The data in this table 

indicates that the water supply samples varied widely in quality. Total dissolved solids 

ranged from 35 to 5510 mg/l, with a median value of 334. Total organic carbon content 

ranged from 1.8 to 202 mg/l while biochemical oxygen demand ranged between 

undetected to 110 mg/l. These widely varying results reflect the fact that, in some 

cases, water used for hydraulic fracturing a prior well was re-used for a subsequent 

well, with the addition of previously unused water. Oils and greases were not detected 

in any of these samples, and many characteristic parameters are representative of 

typical surface water quality 

Characteristics of flowback water sampled at 5 and 14 days following the hydraulic 

fracturing event are presented in Tables 7 and 8, respectively. Consistent with the 

profile of Figure 3, the median value of total dissolved solids for 14-day samples 

(120,000 mg/l) was almost twice the median concentration value measured in the 5-

day samples (67,300 mg/l). However, the bulk of the water collected within the first 5 

days had the lowest concentrations of TDS, also consistent with Figure 3. The water 

is of relatively modest alkalinity, ranging between about 50 and 327 mg/l with a median 

value of 138 mg/l, reflecting low carbonate concentrations which allow for very high 

levels of soluble calcium which confers a very high hardness on the water as 

evidenced by median hardness values of 17,700 and 34,000 mg/l for the 5-day and 
31 

14-day sample sets, respectively. Cations are dominated by sodium and calcium in 

this water; anions are dominated by chloride. Levels of total organic carbon (TOC) in 

the flowback water samples at 5 and 14 days (with median values of 63 and 39 mg/l, 

respectively) are substantially lower (by about 75%) than the TOC of the blended 

influent water with additives; a possible reason for this is that the polyacrylamide 

friction reducers exert a TOC in the influent stream and are removed as water resides 

in the down-hole environment. The same observation is made, though less 

consistently, in comparing biochemical oxygen demand (BOD) values in flowback 

water with the BOD of the influent water streams; in general, the BOD levels of the 14-

day flowback waters are less than half the influent and Day 5 BOD concentrations. 

The widely varying BOD levels in the water supply and influent samples is, as stated 

previously, probably reflective of flowback water re-use. The moderate levels of BOD 

in the influent waters may have resulted from carbonaceous algae growth in the 

source water or resulted from the biodegradable nature of the additives (e.g. 

polyacrylamide friction reducing compounds). The loss of friction reducing compounds 

due to adherence to surfaces downhole may be responsible for the lower BOD 

concentrations in flowback waters. 

General characteristics of the samples tested in this project appear very consistent 

with the ranges of values reported in the literature for normal produced waters (USGS, 

2004). The large database collected by the USGS indicates that salinities for 

produced waters generated among all basins can vary widely from approximately 

5,000 to greater than 350,000 mg/l of total dissolved solids. Chloride is the dominant 

anion in nearly all formation waters associated with petroleum and with most 

conventional natural gas (Kharaka and Rice, 2004). Sodium is the most dominant 

cation in most producing fields and constitutes 70 to more than 90% of total cations 

(USGS, 2004). General characterization data from the waters tested at the 19 

locations of this project appear consistent with much of the available compositional 

information available from the USGS database. The USGS database containing 

produced water characterization data from more than 60,000 wells is accessible from 

the Internet at: http://energy.cr.usgs.gov/prov/prodwat/intro.htm . 
32 

3.1.2 Organic Compounds 

The organic compounds included in the characterization of water samples included the 

categories of VOC, SVOC, chlorinated pesticides, organophosphorus pesticides, and 

polychlorinated biphenyls. Most of the compounds in the first two categories and all 

compounds in the last three categories were included on the list of analyses in 

response to recommendations from PADEP and WVDEP. The following sections 

summarize the results among all five of the categories of analysis. 

Volatile Organic Compounds 

As presented in Table 1, samples collected from Locations A through S were analyzed 

for 70 volatile compounds of highly varied chemical characteristics, including the 

volatile hydrocarbon constituents that are normally found in produced water (such as 

benzene, toluene, ethylbenzene, and xylenes – or BTEX, and naphthalene) as well as 

constituents not known to be associated with conventional produced water such as 

chlorinated solvents and halogenated aromatics. A summary of the detected results 

for volatile compound determinations performed is shown in Appendix D. Many of the 

constituent determinations, on average, were at non-detectable levels. Appendix C 

provides a summary of all of the VOC results. 

Constituents that exceeded 100 ppb included components that are commonly present 

in conventional produced water, such as naphthalene, BTEX, several methylated 

benzene compounds and an alkylated toluene (p-isopropyltoluene). Few 

determinations of these compounds exceeded 2 ppm. In the locations where BTEX 

was measured at levels above 100 ppb, BTEX levels in the 5-day and 14-day flowback 

waters that were in contact with the natural gas producing formation were generally 

higher than BTEX concentrations in the influent water streams, indicating that these 

compounds are naturally occurring and not the result of additives. Levels of BTEX 

and methylated aromatics vary from location to location. Determination of factors that 

control levels of these compounds could potentially be determined through a 

correlation of the composition of volatiles and other flowback water characteristics with 

the key shale gas development parameters of geographic area, depth of wells, 

completion methods, etc. 
33 

Very few volatile organic compounds exceeded 2 ppm among the total of the 

locations. Several locations exhibited one or more of the volatile compounds that 

exceeded 1 ppm. Two ketones were measured in a very limited number of samples; 

acetone and 2-butanone (also known as methyl ethyl ketone or MEK), were found at 

measurable concentrations. These compounds are well known solvents in industry 

that are used for cleaning purposes. In a few samples, carbon disulfide was 

measured. In the manufacture of some types of polymers, carbon disulfide is useful in 

the promotion of nucleophilic attack in polymer synthesis; this compound may be a 

residual reactant from the manufacture of polymers used as friction reducers. 

However, carbon disulfide was only measured in a few samples examined at a limited 

number of locations. 

Semivolatile Organic Compounds 

A total of 112 semi-volatile organic compounds (as listed in Table 1) were included in 

the analysis of influent water and in flowback water samples. A summary of the 

detected results of semivolatile determinations in these samples is presented in 

Appendix D. More than 98% of the constituent determinations, on average, were at 

non-detectable levels and less than 0.03 percent of all the constituents were above 1 

ppm. Several constituents were measured in any of the samples at levels exceeding 

10 ppb. Acetophenone and aniline are commonly associated with fossil fuels, as are 

the methylated phenols. Only two compounds, bis (2-chloroethyl) ether and pyridine, 

were measured at levels greater than 1 ppm. The only compound that was measured 

at a level above 1 ppm more than once was pyridine. Pyridine is a nucleophile that is 

used widely in the manufacture of certain types of chemicals and pharmaceuticals and 

its presence may be due to its use as a precursor in the manufacture of one of the 

hydraulic fracturing additives. 

In general, nearly all of the SVOC determinations were either non-detect or at low 

trace levels. Detected SVOC constituents are summarized in Appendix D. Appendix 

C provides all the SVOC reported results. 
34 

Pesticides 

Determinations of the 20 chlorinated and three organophosphorus pesticides listed in 

Table 1 were conducted on the influent, 14-day and 90-day flowback water samples. 

Results from the measurements of pesticides in all samples are summarized in 

Appendix C. Pesticide concentrations measured in samples were extremely low (all 

samples were less than 1 ug/l.) and random with results occurring in some of the water 

supply, Day 0, Day 14 or Day 90 samples collected. It is possible that these low level 

concentrations are not representative of actual conditions and are attributed to 

laboratory contamination or instrument noise. Appendix C summarizes the pesticides 

results. Appendix D provides a summary of the detected pesticide results. 

Polychlorinated Biphenyls (PCBs) 

Determinations of the 7 polychlorinated biphenyl compounds (Aroclors) listed in Table 

1 were conducted on the influent, 14-day and 90-day flowback water streams. 

Aroclors were not detected in any sample, except for Aroclor 1248 that was detected 

at 8 ug/L in the Day 14 sample at Location R. The detected PCB result is summarized 

in Appendix D. Appendix C summarizes the all of the PCB results. 

3.1.4 Metals 

A summary of metal concentrations in the influent water stream (with additives) and 

the 5-Day Flowback water samples across all 19 locations is presented in Table 9; all 

concentrations in this table are reported in units of μg/l (ppb). As seen in this table, 

sodium is the major cation in all of the samples, followed by concentrations in some 

samples of calcium, magnesium and barium that will need to be monitored for 

purposes of scale control in some locations. Since strontium is present in flowback 

waters at concentrations between 345 to 4,830 mg/l in the 5-day flowback samples, it 

will be important for operators to implement procedures to prevent the formation of 

strontium-bearing scale. Iron levels in the range of 21 to 180 mg/l may also need to be 

watched and mitigated in order to prevent operational difficulties at a number of well 

completion locations. 

Heavy metals of toxicological concern that are often associated with urban industrial 

activity (including chromium, copper, nickel, zinc, lead, cadmium, mercury and arsenic) 
35 

are at very low levels in all of the shale gas water samples compared to levels 

reported for municipal wastewaters. Table 10 presents range values from the 5-Day 

Flowback samples which are compared to median heavy metals concentrations 

measured in sewage sludges (biosolids) generated by Penn State for the State of 

Pennsylvania (Stehouwer, 2000); note that concentrations in this table are reported in 

mg/l. The comparison shows that the levels of heavy metals of concern are 100 to 

10,000 times higher in municipal biosolids (sewage sludges that are routinely 

transported across communities to disposal sites) than the levels measured in shale 

gas waters. 
36 

Table 9. Total Metals Concentrations in the Influent Water and 5-day Flowback 

Water Obtained from 19 Locations 

-- Influent Water -- -- 5-Day Flowback --

Parameter Range Median Range Median Units

Aluminum ND – 1,030 B NC ND - 47,200 J NC ug/L 

Antimony ND - 21.6 BJ NC ND - 47.2 B NC ug/L 

Arsenic ND - 9.1 B NC ND – 124 NC ug/L 

Barium 63.1 BJ - 87,100 410 21,400 J - 13,900,000 686,000 ug/L 

Beryllium ND – 3 B NC ND NC ug/L 

Boron ND - 40,700 J NC 3,140 J - 97,900 12,200 ug/L

Cadmium ND - 10.5 NC ND - 9.6 B NC ug/L 

Calcium 6,690 BJ - 2,990,000 32,900 1,440,000 J - 23,500,000 J 4,950,000 ug/L 

Chromium ND - 704 NC ND - 152 NC ug/L 

Chromium +3 ND – 4.8 B NC ND – 67.4 NC ug/L 

Chromium +6 ND ND ND NC ug/L 

Cobalt ND - 11.9 B NC ND NC ug/L 

Copper ND – 120 B NC ND - 4,150 NC ug/L 

Iron 137 B - 14,300 1,180 21,400 - 180,000 39,000 ug/L 

Lead ND - 111 NC ND - 606 NC ug/L 

Lithium ND - 14,900 JE NC 10,600 - 153,000 43,700 ug/L 

Magnesium 1,250 B - 235,000 6,740 135,000 - 1,550,000 559,000 ug/L 

Manganese ND - 3,640 NC 881 - 7,040 2,630 ug/L 

Mercury ND - 0.66 BJ NC ND - 0.24 J NC ug/L 

Molybdenum ND - 91.8 B NC ND – 147 B 33.1 ug/L 

Nickel ND - 457 NC ND – 187 B NC ug/L 

Potassium 2250 B - 229,000 E 42,600 48,900 B - 2,430,000 301,000 ug/L 

Selenium ND - 35.3 B NC ND NC ug/L 

Sodium 25,700 B - 6,190,000 67,800 10,700,000 - 65,100,000 18,000,000 ug/L 

Strontium 58.5 BJE - 439,000 E 768 345,000 – 4,830,000 1,080,000 ug/L 

Thallium ND -19.8 B NC ND – 24.6 B NC ug/L 

Tin ND - 6.9 B NC ND - 25.7 B NC ug/L 

Titanium ND - 39.1 B NC ND – 313 B NC ug/L 

Zinc ND - 1,610 E NC 67.6 BJ – 2,930 J 172 ug/L 

* Influent Water is the supply water containing hydraulic fracturing additives, but without sand. Influent samples are 

identified as Day 0 samples. 

ND Not detected 

NC – Indicates the median concentration was not calculated due to undetected results. 

B Analyte was also detected in the method blank for that sample 

J Estimated concentration for analyte detected between the method detection level and the reporting limit 

G Analyzed at a diluted concentration due to matrix effects 

E The concentration exceeds the linear range of the instrument. The result is considered estimated.
37 

Table 10. Comparisons of Metals Levels in Shale Gas Waters with Municipal 

Biosolids (Sewage Sludge) 

Metal 5-day Flowback 

Range 

Sewage Sludge* Units 

Chromium ND – 0.152 35 mg/L 

Copper ND – 4.150 511 mg/L 

Nickel ND – 0.187 B 22.6 mg/L 

Zinc 0.068 – 2.93 J 705 mg/L 

Lead ND – 0.606 65 mg/L 

Cadmium ND – 0.096 B 2.3 mg/L 

Mercury ND – 0.00024 J 1.5 mg/L 

Arsenic ND – 0.124 3.6 mg/L 

* Penn State study reporting median heavy metal content values for Pennsylvania publicly owned treatment works 

(POTW) biosolids (Stehauwer, et al., 2000). 

ND – Not detected 

4.0 Implications for Fate and Transport 

As seen in Table 1, the list of measurements and determinations that were pursued in 

this study were very exhaustive but highly useful in establishing an information base to 

define a chemical fingerprint associated with flowback waters from this geologic 

formation. Much of the expense and time required for water characterization has 

arisen from the extensive effort to analyze the samples for large numbers of volatile 

and semivolatile organic compounds suggested by PADEP and WVDEP (including 

chlorinated pesticides, organophosphorus pesticides and polychlorinated biphenyls); 

the information base developed in this project strongly suggests that this level of water 

characterization in the future is not necessary and that monitoring should be focused 

on measuring constituents that are likely to be present. A number of observations 

that are relevant to fingerprinting and to the fate and transport of constituents can be 

made from consideration of the information base assembled from the first 19 locations. 
38 

First, there is clear indication that halogenated hydrocarbon compounds (among 

volatile, semivolatile, pesticides and PCB categories) and nearly all of the polynuclear 

aromatic hydrocarbons (of 3 rings and above) are not a part of typical components in 

flowback waters. Volatile and semivolatile organic constituents that are normally found 

at low levels in conventional produced waters, such as BTEX, methylated benzenes, 

naphthalene, naphthenic acids, volatile acids, simple alkanes, etc., are also found in 

flowback waters and in influent waters for frac jobs that utilize flowback water reuse. 

However, in terms of fate and transport in the environment, many volatile and 

semivolatile organics present in shale gas waters are at modest concentrations (most 

compounds are below 1 ppm). The challenge, therefore, is to choose an alternate 

parameter that can be used to quickly detect any small release of flowback water that 

may occur in the course of storage or handling. 

A more practical approach might be to use chloride analyses of samples to monitor 

fate and transport of flowback/produced waters. Chloride has been used as a 

conservative tracer in hydrogeochemical studies for decades and is well documented 

in the literature (Clement et al., 2000; Farrell et al., 1994; Lamontagne et al., 2005; 

Negrel and Lachassagne, 2000; Nelson et al., 2001; Paine, 2003; van Breukelen et al., 

1998). A general overview of the processes controlling the movement of solutes in the 

subsurface is provided below. 

Fate and transport of constituents in the soil/rock/water system is governed by four 

fundamental processes: advection, dispersion, retardation, and decay. Advection is 

simply the mass movement of a solute along with groundwater and is modeled by 

Darcy’s Law. Dispersion is a mathematical description of diffusion and mechanical 

mixing of a solute in a system. Diffusion is modeled using Fick’s first and second law. 

Dispersion is an empirical correction factor controlled by the physical properties of the 

soil/rock matrix (porosity, grain size, sorting, etc) and scale of the system. Retardation 

is the process by which non conservative solutes interact with the soil/rock and their 

movement downgradient is subsequently slowed. It is modeled by a linear equation 

that is a function of porosity, moisture content, bulk density, and the humic organic 

matter content. Examples of retardation reactions are adsorption-desorption, ion 
39 

exchange, precipitation-dissolution, and oxidation-reduction reactions. Decay is the 

process by which a solute is removed from the system due to chemical reactions, 

biological reactions, and/or radioactive decay and is modeled using the appropriate 

equation for the reaction occurring in the system. 

Conservative solutes are ones that can be modeled using only advection and 

dispersion. Common examples are chloride and bromide, but bromide levels in the 

samples collected as part of this study were several orders of magnitude lower than 

chloride levels. Non-conservative solutes can only be modeled using advection, 

dispersion, retardation, and/or decay. Examples of non-conservative solutes are 

volatile/semivolatile organics (e.g. benzene, toluene, PAHs, PCBs, etc.), sulfate, iron, 

and many others. Non-conservative species subsequently migrate slower throughout 

the subsurface than do conservative tracers and therefore are inappropriate to use as 

indicators of Marcellus Shale flowback water impact to a system. Nearly all classes of 

volatile and semivolatile organics discussed in this report have been shown to be 

sequestered to various types of soils, thereby significantly retarding their mobility in the 

environment (Linz and Nakles, 1997). 

Chloride, on the other hand, is more mobile and has considerable potential as an early 

sentinel indicator of flowback water impacts due to a number of advantages. In 

addition to being conservative (by virtue of its non-volatile, non-sequestering, nonreactive property), chloride is usually present in relatively high concentrations ranging 

from 10,000 to 200,000 mg/l, ten to a hundred times the concentration of most 

inorganics and more than a million times the levels of most volatile and semivolatile 

organic constituents. Chloride is also easily measured with field kits that can 

determine the presence of this anion with small samples, and verified in its presence 

with simple conductivity instruments. Due to its high concentration and its ubiquitous 

presence in flowback waters, chloride anion is an excellent monitoring tool for even the 

smallest leaks of flowback water into the environment. 
40 

5.0 Conclusions 

With the completion of this sampling and analysis effort, the following conclusions can 

be drawn from the results: 

1. General chemistry characterization of flowback water indicates that values for 

pH, alkalinity, total dissolved solids, total organic carbon, oils and greases and 

other parameters from general water characterization are well within the normal 

ranges reported for conventional produced waters. Flowback water appears 

similar in composition to conventional produced water, even in the presence of 

additives employed for performing hydraulic fracturing. 

2. Shale gas flowback water cations are dominated by sodium and calcium; 

anions are dominated by chloride. 

3. Metals in flowback water are well within the ranges for normal produced waters. 

Industrial heavy metals (e.g. chromium, copper, nickel, zinc, lead, cadmium, 

arsenic and mercury) are a small fraction (less than 1 percent) of the heavy 

metals content in municipal biosolids generated from POTW’s. 

4. Among volatile organic constituents, approximately 96% of these constituents 

were found at non-detectable levels and 0.5% were above 1 ppm for any of the 

5 sampling events among 19 locations. The data indicate that the constituents 

above 1 ppm are those that are a normal part of produced waters associated 

with natural gas operations (such as xylenes, toluene and naphthalene). 

5. Among SVOC, more than 98% of all determinations were at nondetectable 

levels and 0.03% of these constituents were above 1 ppm. 

6. Low levels (less than 1 ug/l) and the random distribution of chlorinated and 

organophosphorus pesticides suggest that these compounds are laboratory 

artifacts and are not contained in flowback water. 
41 

7. Only one PCB (Aroclor 1248) was detected in all the samples analyzed. This 

result should be considered an anomaly. 

8. Virtually, all halogenated organic compounds were at non-detect levels. This 

strongly suggests that additives that are blended with influent waters do not 

contain concentrations of organic chemicals of concern. 

9. The results of this shale gas water characterization effort indicate that 

pesticides, PCBs, and a large fraction of the volatile and semivolatile 

constituents should be considered to be unnecessary for the sampling and 

analysis of flowback waters in the future. 

10. Determination of factors that affect levels of organic and inorganic compounds 

could potentially be determined through a correlation of flowback water 

composition with the key shale gas development parameters of geographic 

area, depth of wells, completion methods, etc. 
42 

6.0 References Cited 

APHA. 1992. “Standard Methods for the Examination of Water and Wastewater”, 18th

Edition (SM18). 

APHA. 1999. “Standard Methods for the Examination of Water and Wastewater”, 20th

Edition (SM20). 

Clark, C.E. and J.A. Veil. 2009. Produced Water Volumes and Management 

Practices in the U.S. USDOE/Argonne Laboratories Report No. ANL/EVS/R-09/1. 

Clement, T.P., Johnson, C.D., Sun, Y., Klecka, G.M., and Bartlett, C., 2000, Natural 

attenuation of chlorinated ethene compounds; model development and field-scale 

application at the Dover site: Journal of Contaminant Hydrology, v. 42, p. 113-140. 

Engelder, T., and G.G. Lash. 2008. Marcellus Shale Play’s Vast Resource Potential 

Creating a Stir in Appalachia. The American Oil & Gas Reporter, May. 

Farrell, D.A., Woodbury, A.D., and Sudicky, E.A., 1994, The 1978 Borden tracer 

experiment; analysis of the spatial moments: Water Resources Research, v. 30, p. 

3213-3223. 

Gaudlip, A.W., L.O. Paugh, and T.D. Hayes. 2008. Marcellus Shale Water 

Management Challenges in Pennsylvania. SPE Paper No. SPE–119898-PP, Society 

of Petroleum Engineers. 

Kharaka, Y.K. and C.A. Rice. 2004. “Organic and Inorganic Species in Produced 

Water: Implications for Water Reuse”, Proceedings of the Natural Gas Technologies 

Conference, Phoenix, Feb 8-10. Available from the Gas Technology Institute, 

Lamontagne, S., Leaney, F.W., and Herczeg, A.L., 2005, Groundwater-surface water 

interactions in a large semi-arid floodplain; implications for salinity management: 

Hydrological Processes, v. 19, p. 3063-3080. 

Linz, D.G. and D.V. Nakles. 1997. Environmentally Acceptable Endpoints in Soil. 

American Academy of Environmental Engineers, United Book Press, Inc., Baltimore, 

MD. 

Negrel, P., and Lachassagne, P., 2000, Geochemistry of the Maroni River (French 

Guiana) during the low water stage; implications for water-rock interaction and 

groundwater characteristics: Journal of Hydrology, v. 237, p. 212-233. 

Nelson, M.D., Parker, B.L., Al, T.A., Cherry, J.A., and Loomer, D., 2001, Geochemical 

reactions resulting from in situ oxidation of PCE-DNAPL by KMnO (sub 4) in a sandy 

aquifer: Environmental Science & Technology, v. 35, p. 1266-1275. 

Paine, J., 2003, Determining salinization extent, identifying salinity sources, and 

estimating chloride mass using surface, borehole, and airborne electromagnetic 

induction methods: Water Resources Research, v. 39, p. 10. 
43 

Stehouwer, R.C., A.M. Wolf, and W.T. Doty. 2000. “Chemical Monitoring of Sewage 

Sludge in Pennsylvania: Variability and Application Uncertainty.” J. Environ. Qual. 29: 

1686 – 1695. 

USEPA. 1984. “Methods for Organic Chemical Analysis of Municipal and Industrial 

Wastewater”, 40CFR, Part 136, Appendix A, October 26. 

USEPA. 1983. “Methods for Chemical Analysis of Water and Wastes”, EPA-600/4-79-

020, March. 

USEPA. 1986. Test Methods for Evaluating Solid Waste, Physical/Chemical 

Methods”, Third Edition, November (SW846). 

USGS. 2009. USGS Produced Water Database. Available at: 

http://energy.cr.usgs.gov/prov/prodwat/intro.htm . 

van Breukelen, B.M., Appelo, C.A.J., and Olsthoorn, T.N., 1998, Hydrogeochemical 

transport modelling of 24 years of Rhine water infiltration in the dunes of the 

Amsterdam water supply: Journal of Hydrology, v. 209, p. 281-296. 
44 

Disclaimer 

This report was prepared by the Gas Technology Institute (GTI) as an account of work 

funded by the Marcellus Shale Coalition (MSC). Neither GTI nor any person acting on 

behalf of GTI: 

1. Makes any warranty or representation, express or implied with respect to the 

accuracy, completeness, or usefulness of the information contained in this 

report, or that the use of any information or method disclosed in this report may 

not infringe privately-owned rights, or 

2. Assumes any liability with respect to the use of, or for any and all damages, 

resulting from the use of, any information or method in this report. 
45 

Appendix 

		
		
				
	

		
						

		
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Appendix A 

Field Sampling and Analysis Plan (FSAP)
FIELD SAMPLING AND ANALYSIS PLAN 

DEVONIAN SHALE FLOW BACK WATER 

CHARACTERIZATION STUDY 

Prepared by 

Appalachian Shale Water Conservation and Management Committee 

December 2008 
TABLE OF CONTENTS 

1.0 INTRODUCTION ................................................................................................... 3 

1.1 PURPOSE ............................................................................................................ 3 

1.2 DATA OBJECTIVES .......................................................................................... 3 

1.3 BACKGROUND.................................................................................................. 3 

2.0 CHARACTERIZATION STUDY OF FLOW BACK WATER ............................. 5 

2.1 Sampling and Analyses ........................................................................................ 5 

3.0 SAMPLING PROTOCOLS ..................................................................................... 7 

3.1 PROJECT INITIATION ...................................................................................... 7 

3.2 DOCUMENTATION ........................................................................................... 7 

3.2.1 Field Logbook ............................................................................................... 7 

3.2.2 Chain-of-Custody Form ................................................................................ 8 

3.3 SAMPLE DESIGNATION AND IDENTIFICATION ....................................... 8 

3.4 SAMPLE MANAGEMENT AND SHIPMENT ................................................. 9 

4.0 SAMPLING EQUIPMENT AND PROCEDURES .............................................. 10 

5.0 INVESTIGATION DERIVED WASTE ............................................................... 11 

5.1 MANAGEMENT OF HAZARDOUS IDW ...................................................... 11 

6.0 REFERENCES ...................................................................................................... 12 

Tables 

1 Summary of Extensive List of Constituents of Interest, EPA Methods, Reporting 

Limits and Holding Times. 

2 Summary of List of Constituents Based on Generator Knowledge, EPA Methods, 

Reporting Limits and Holding Times 
1.0 INTRODUCTION 

This Field Sampling and Analysis Plan (SAP) details the procedures for sampling and 

field documentation to be utilized for the characterization study of the fracturing and flow 

back fluids associated with the Devonian shale. The FSAP has been prepared to ensure 

that all data and information gathered are properly sampled, documented, and technically 

sound. The FSAP and Quality Assurance Project Plan (QAPP) together comprise the 

Sampling and Analysis Plan (SAP). 

1.1 PURPOSE 

The FSAP includes a detailed description of field sampling procedures to be conducted. 

The procedures described are consistent with the RCRA Technical Enforcement 

Guidance Document (TEGD), U.S. EPA, 1989; RCRA Facility Investigation Guidance 

Document (U.S. EPA, May 1989); RCRA Ground Water Monitoring; Draft technical 

Guidance (U.S. EPA, 1992); Data Quality Objectives for Remedial Response Activities 

(U.S. EPA, 1987). 

The SAP consists of 5 sections. Section 1.0 includes a brief description of the data 

objectives and a brief discussion of the project. 2.0 provides information regarding 

documentation, quality assurance/quality control (QA/QC) requirements, and reporting. 

Section 3.0 addresses the sampling procedures. Section 4.0 describes the proper handling 

requirements of any investigative derived waste generated. Reference documents are 

provided in Section 5.0 

1.2 DATA OBJECTIVES 

The data objectives will address characterization of the fracturing and flow back fluids 

associated with the development of the Devonian shale. This characterization study will: 

Identify the specific constituents of interest (COI) associated with flow back 

water; 

Reduce/eliminate the allegations that the chemicals used for fracturing will 

contaminate groundwater; and 

Provide sufficient information for the selection of proper disposal techniques. 

 

Achieving these data objectives will require obtaining data of acceptable levels of 

certainty. Therefore, it is essential that the field and sampling procedures be completed 

under stringent and appropriate methods. 

 

1.3 BACKGROUND 

The process of developing Devonian Shale wells requires increasing the number of 

fractures and extending the existing fractures. Fracturing is necessary to obtain a greater 

volume of natural gas from the Devonian Shale at in a cost-efficient manner. Fracturing 

uses high volumes and high-pressure chemically treated water or a gel to induce fractures 
in the shale surrounding the well bore. Most applications require between 500 and 10,000 

psi. 

Fracturing is done by isolating off a portion of the well and injecting chemically treated 

water or gel and sand with cement, perforating, under very high pressure into the isolated 

portion of the well bore. Generally, 1.5 to 5 million gallons of water is pumped into the 

formation of a vertical or horizontal well, respectively. The high pressure fractures the 

shale and sand keeps the fractures open. A drop in pressure indicates that the formation 

has accepted water. 

To prevent the fractures from closing when the pressure is reduced several hundred tons 

of sand or other propant is pumped down the well and into the pressurized portion of the 

well. When the fracturing occurs the sand is forced into the fractures. If enough sand is 

trapped in the fractures it will prop the fractures open when the pressure is reduced. The 

propped fractures provide an increase in the permeability for gas flow. 

Approximately 25 to 30 percent of the water used in fracturing is recovered. This flow 

back water is currently a concern because there is a limited amount data. The ASMCWC 

is conducting this study in an effort to characterize the flow back water associated with 

the Devonian Shale. 

The flow back water will be collected in either an on-site off-stream temporary 

impoundment or a series of frac tanks. 
2.0 CHARACTERIZATION STUDY OF FLOW BACK WATER 

Fracturing is completed over several days depending on the geological formation. 

Because the flow back water is under pressure, initially the flowback water is recovered 

at a faster rate in the beginning of fracturing and significantly declines as facturing 

continues and the well is released to production. The initial concentrations at the start of 

fracturing (high yields of flow back water) should yield lower concentrations of 

constituents of interest (COI). It is assumed that the concentration of the fracturing 

chemicals remain constant throughout the flow back regardless of the rate of return. 

However, the increase concentration of in the COI is due to a longer residence time in the 

applicable formation and not associated to the additives of the fracing fluids. 

Therefore, to obtain representative samples of the flow back water samples will be 

collected on three separate days (i.e., days 1, 5 and 14). The data obtained from day 14 

should represent the chemical characteristics of the natural formation fluid. 

Additionally, a baseline sample of the fracturing fluid will be collected prior to injection. 

The baseline sample will contain the materials (e.g., water and chemicals) used in the 

fracturing process. A sample will also be collected from a well in Devonian shale that 

has been in production for a period of time (i.e., a well that has been in production for 

more than 3 months). The data obtained from this well should represent the chemical 

characteristics of the natural formation fluid. The analytical results associated with these 

samples will assist in the data interpretation. 

2.1 Sampling and Analyses 

In general, several frac tanks are connected in-line and filled simultaneously with the 

flow back water. This is completed to avoid back pressure when shutting one frac tank 

and opening another tank for additional capacity. This filling process will provide a 

composite sample of the flow back water over time. To minimize volatilization, a 

representative composite sample of the flow back water samples will be collected from 

the top of a frac tank or flow back impoundment. 

The flow back water is either pumped into the frac tanks for storage until the water is 

disposed of properly. If a project does have an impoundment that stores flow back water 

on site in an impoundment, a grab sample will be collected from the impoundment 

following day 1, 5 and 14 of fracturing. 

The base fracturing fluid will be collected prior to going down hole. The base fracturing 

fluid will be collected from either the sampling lines built into the blenders or as a grab 

sample from the blending containers. In either case a representative sample of the fluid 

will be collected. 

Numerous flow back water samples will be collected from several unique locations. 

Phase one of this characterization study will include the sampling of six flow back water 

samples from six unique locations. 
The list of constituents recommended for the characterization study was developed from 

comments received from the Pennsylvania Department of Environmental Protection 

(PADEP), the West Virginia Department of Environmental Protection (WVDEP) and 

members of the ASWCMC. Because the recommended list of constituents is extremely 

extensive, it was decided that one sample from each site will be completed for the full list 

of recommended constituents (Table 1). All other samples will be sampled for a subset 

of these constituents (Table 2), which are based on generator knowledge and Group 1 and 

Group 2. The analytical results of phase one of the characterization study will determine 

the list of constituents of subsequent sampling events. 
3.0 SAMPLING PROTOCOLS 

This section identifies the protocols to be implemented during field sampling. 

Specifically this section describes the preparation, documentation, and reporting 

procedures to be used that will assure quality assurance and quality control. 

3.1 PROJECT INITIATION 

Following acceptance of this plan by the ASWCMC and the state agencies, Gas 

Technology Institute (GTI) will authorize Test America an independent a credited 

analytical laboratory to provide the appropriate sample containers and preservatives; and 

URS, an independent environmental consulting company has been retained to collect the 

flow back water. Furthermore, Test America will complete the analytical analyses. Test 

America is certified by WVDEP and PADEP. 

The regulatory agencies are invited to collect split samples. The samples will be 

collected at the discretion of the agency. All agency sampling must be approved and 

coordinated with the appropriate gas company. 

3.2 DOCUMENTATION 

A field logbook and chain-of-custody form will be utilized during the field activities. 

3.2.1 Field Logbook 

During field activities, a site-specific logbook will be used for documentation of all notes. 

It is recommended that each page of the logbook be numbered and dated. The entries 

should be legible and contain accurate and inclusive documentation of the project 

activities. Once completed, the logbook becomes an accountable document and is 

maintained as part of the project file. The logbook should include, at a minimum, the 

following information: 

Identification of logbook ownership and telephone number on the inside front 

cover; 

Well location and identifying number; 

Names of field personnel at the site; 

Weather information (general); 

Sample locations and activities; 

Sample collection equipment; 

Date and time of monitoring of sampling; 

Water quality measurements (field pH, specific conductance, water temperature); 

Field instrument calibration information; 

Visual observations; 

Collection of field quality assurance samples (i.e., blanks or duplicates); 

Regulatory agency personnel observing sampling; 
Enter agency, collector’s name, samples splits, etc., if a regulatory agency splits 

samples; and 

Documentation of sample shipment dates, time, and carrier tracking (air bill) 

number, if necessary. 

Copies of the field book pages will become part of the sample data package. 

3.2.2 Chain-of-Custody Form 

The chain-of-custody form is used to record the custody of all samples collected. This 

chain-of-custody form documents transfer of the custody from the sampling personnel to 

another person, to the laboratory, or to another party, such as a courier delivery service. 

The chain-of-custody form also serves as a sample logging mechanism for the laboratory 

sample custodian. 

When the field personnel sends samples to the analytical laboratory, each cooler chest 

containing samples must be accompanied by a chain-of-custody form. These forms 

contain the following information pertaining to the samples: 

Project Name 

Name(s) and signature(s) of the individual(s) collection the samples; 

Sample location; 

Date and time of sample collection; 

Total number of sample containers per sample location; 

Type of sample preservation used (e.g., HNO3, HCl, etc.) 

Analytical parameters of interest for each sample and number of containers per 

analytical parameter; 

Remarks or observations; 

Signature(s) of all individual(s) relinquishing and receiving custody of the 

samples; 

Name of the carrier shipping the samples; and 

Air bill number under which sample containers(s) was sent, if applicable; 

The chain-of-custody forms are multi-colored carbon copy forms. The original copy 

(white) is submitted to the laboratory with the samples, the second copy (pink) is sent to 

GTI, and the third (yellow) is kept for the project files. 

3.3 SAMPLE DESIGNATION AND IDENTIFICATION 

Each sample collected for this characterization study will be assigned a unique sample 

tracking number. The identification of the well location and participating gas company 

will not be identified. All well locations will be blind. GTI will assign each well a 

project identifier. The project identifier will be a unique single alphanumeric letter that 

will identify the Devonian Shale well location and company. This unique alphanumeric 

letter will be provided to the third party environmental consultants to be used in the 

sample designation. 
3.4 SAMPLE MANAGEMENT AND SHIPMENT 

The possession of samples or other physical evidence shall be traceable from the time the 

samples are obtained until they have been submitted to the analytical laboratory. To 

simplify the documentation of possession that is maintained on the chain-of-custody 

form, the number of people who handle the sample during the investigation should be 

minimized. All samples will be documented in the field logbook, on the chain-ofcustody form and on the sample container labels. Field documentation procedures are 

provided above in Section 2.3 and the in the QAPP. 

Sample labels shall be completed for each sample using waterproof non-erasable ink. All 

samples are to be sealed immediately upon collection and are to be immediately place on 

ice in a cooler. 

Samples are to be properly packaged for shipment and delivery to the laboratory. To 

ensure that the samples are kept cold for preservation requirements, the samples are to be 

shipped in iced coolers for overnight delivery. Samples collected during the 

characterization study are to be classified as environmental samples. 

Shipping containers are to be secured with tape and use of security seal method to ensure 

that the cooler may not be opened without evidence of the seal being tampered. 

Ice used to keep the samples cooled must be secured in plastic bags (e.g., Zip-Lock® 

plastic bags) to ensure that melted ice does not cross contaminate the samples pr leak 

from the coolers. 

Samples will be either hand delivered to the laboratory or shipped via priority service to 

the laboratory or the air bill retained for the project file. 
4.0 SAMPLING EQUIPMENT AND PROCEDURES 

Grab samples will be conducted using a new PVC bailer from the top of the frac tank. 

The order, in which the grab samples are collected, as prioritized to the sensitivity to 

volatilization, is as follows: 

Volatile Organics 

Purgeable Organics 

Purgeable Organic Halogens 

Total Organic Halogens 

Total Organic Carbon 

Extractable Organics 

Total Metals 

Dissolved Metals 

Phenols 

Cyanide 

Sulfate and Chloride 

Turbidity 

Nitrate and Ammonia 

There is not an order of preference for the collection of the remaining conventional 

parameters. 

Temperature, pH, dissolve oxygen, and specific conductance measurements will be 

completed in the field 
5.0 INVESTIGATION DERIVED WASTE 

Materials which may be investigation derived waste (IDW) are: 

Personnel protective equipment (PPE), including disposable gloves, coveralls, 

booties, etc.; 

Disposable equipment, including plastic ground and equipment covers, aluminum 

foil, Composite liquid waste samplers (COLIWASAs), used sample containers, 

tape, etc.; 

5.1 MANAGEMENT OF HAZARDOUS IDW 

If wastes are suspected to be hazardous, appropriate analysis must be performed to make 

that determination. The analytical testing should meet the requirements of the potential 

disposal characterization requirements. If the IDW is determined to be hazardous wastes 

either through testing of characteristics or as a listed waste, they must be properly 

container and labeled. They may be stored on site for a maximum of 90 days before they 

must be manifested and shipped to a permitted treatment of disposal facility. 

Care should be taken to keep non-hazardous materials segregated from hazardous wastecontaminated materials. 
6.0 REFERENCES 

Kitrell, F.W. 1990. A Practical Guide to Water Quality Studies. 

U.S. EPA, 1986. Test Methods for Evaluating Solid Waste, Volume II; Field Manual, 

Physical/Chemical Methods. Office of Solid Waste and Emergency Response, SW-846, 

November 1986 

U.S. EPA 1987. Data Quality Objectives for Remedial response Activities. Oswer 

Directive 935507B, Office of Emergency and Remedial Response, Washington DC. 

EPA/5406/6=87/100 and 004. 

U.S. EPA, 1986. RCRA Ground-Water Technical Enforcement Guidance Document. 

Office of Waste Programs Enforcement, Washington DC, Oswer Directive 99501. 

U.S. EPA, 1992. RCRA Groundwater Monitoring: Draft Technical Guidance. Office of 

Solid Waste, Washington DC. EPA/530/R-93/001. 

U.S. EPA, 1998. Environmental Investigations Standard Operating Procedures and 

Quality Assurance Manual. U.S. EPA Region 4, Athens, GA, May 1996. 

 
Appendix B 

Quality Assurance Project Plan (QAPP) 
QUALITY ASSURANCE PROJECT PLAN 

DEVONIAN SHALE FLOWBACK WATER 

CHARACTERIZATION STUDY 

Prepared by 

Appalachian Shale Water Conservation and Management Committee 

November 2008 
TABLE CONTENTS

1.0 PURPOSE 3 

2.0 PROJECT DESCRIPTION 4 

2.1 SCOPE OF WORK 4 

3.0 QUALITY ASSURANCE OBJECTIVES FOR MEASUREMENT DATA 5 

3.1 DATA QUALITY LEVELS 5 

3.2 QUALITY CONTROL PARAMETERS 6 

4.0 SAMPLING PROCEDURES 8 

4.1 SAMPLE IDENTIFICATION 8 

4.2 SAMPLE CONTAINERS 9 

4.3 FIELD QA/QC SAMPLES 9 

4.3.1 Trip Blanks 9 

4.3.2 Equipment Blanks 10 

4.4 DOCUMENTATION 10 

5.0 SAMPLE CUSTODY 11 

6.0 ANALYTICAL PROCEDURES 12 

7.0 CALIBRATION PROCEDURES AND FREQUENCY 13 

7.1 PREPARATION OF STANDARDS 13 

7.2 CORRECTIVE ACTION 13 

8.0 DATA EVALUATION/VALIDATION 15 

8.1 FIELD DATA VALIDATION 15 

8.2 LABORATORY DATA VALIDATION 15 

8.3 INDEPENDENT DATA VALIDATION 16 

8.4 DATA REPORTING 16 

8.4.1 LEVEL I REPORTING 17 

8.4.2 LEVEL II REPORTING 17 

8.4.3 LEVEL III REPORTING 17 

9.0 QUALITY CONTROL PROCEDURES 19 

9.1 FIELD QC CHECKS 19 

9.1.1 EQUIPMENT BLANKS 19 

9.1.2 TRIP BLANKS 19 
9.2 INTERNAL LABORATORY QC CHECKS 20 

9.2.2 Preparation/Method Blanks 20 

9.2.3 Matrix Spike And Duplicate (Or Matrix Spike Duplicate) Analysis 21 

9.2.4 Surrogate Spike Standard Performance Evaluation 21 

9.2.5 Calibration Check Compounds And Reagent Blanks 21 

10.0 PERFORMANCE AND SYSTEM AUDITS 22 

10.1 PERFORMANCE AUDITS 22 

10.1.1 Laboratory Performance Audits 22 

10.2 SYSTEM AUDITS 22 

10.2.1 Laboratory System Audits 22 

11.0 ASSESSMENT PROCEDURES FOR DATA ACCEPTABILITY 23 

11.1 PRECISION 23 

11.2 ACCURACY 23 

11.3 COMPLETENESS 23 

11.4 QUALITY CONTROL CHARTS 24 

12.0 PREVENTIVE MAINTENANCE 25 

12.1 FIELD 25 

12.2 LABORATORY 25 

13.0 CORRECTIVE ACTION 26 

14.0 QA REPORTS TO MANAGEMENT 27 

FIGURE

1 Chain of Custody Record 

TABLES

1 Summary of Extensive List of Constituents of Interest, Reporting Limits, and Holding 

Times 

2 Summary of List of Constituents Based on Generator Knowledge, Reporting Limits, and 

Holding Times 
This document is the Quality Assurance Project Plan (QAPP), which provides specific quality 

assurance/quality control (QA/QC) procedures to be executed and supported for the 

Characterization Study of the flow back water associated with the well fracturing of the 

Devonian Shale. 

Data generated for environmental purposes must be technically sound and legally defensible, and 

supported by defined and verified limits of confidence. Therefore, the objective of this QAPP is 

to ensure the generation of accurate, precise, representative and complete data. The QAPP sets 

forth the data collection procedures and data evaluation processes, which will ensure that 

appropriate levels of data quality are obtained. 

Analyses must meet the QA/QC requirements associated with this QAPP and the following 

documents: 

SW-846, Third Edition (September 1986), as amended by updates 1 (July 1992), II (September 

1994), IIA (August 1993), and IIB (January 1995), or the most current SW-846 update; 

EPA's "Handbook for Analytical Quality Control in Water and Wastewater Laboratories" (EPA 

600/1-79-019); 

Standard Methods for the Examination of Water and Wastewater. 

Only U.S. EPA-approved methods will be used for chemical analyses. Any omission in this 

QAPP of relevant requirements, tasks and other items found in the referenced methods does not 

constitute a waiver of the omitted requirement, task, or item. It is the responsibility of all 

personnel involved in the various site investigation activities to perform and document the 

required procedures designated herein. 
The Appalachian Shale Water Conservation and Management Committee (ASWCMC) is 

conducting a study to characterize the fracturing and flow back water generated from 

development of Devonian Shale wells. 

Samples will be collected from both vertical and horizontal Devonian Shall gas wells. Numerous 

samples will be collected from several locations. Phase one of the characterization study will 

include 4 grab samples from 6 well sites. A sample will also be collected from a well that has 

been in production for at least three months. The following grab samples will be collected from 

each site: 

One baseline fracturing water sample that includes the fracturing chemicals, excluding 

the sand; 

Flowback water samples will be collected on days 1, 5 and 14 of the following the 

fracturing process; and 

Water from an existing producing well. 

The list of constituents recommended for the characterization study was developed from 

comments received from the Pennsylvania Department of Environmental Protection (PADEP), 

the West Virginia Department of Environmental Protection (WVDEP) and members of the 

ASWCMC. Because the recommended list of constituents is extremely extensive, it was decided 

that one sample from each site will be completed for the full list of recommended constituents 

(Table 2). All other samples will be sampled for a subset of these constituents (Table 3), which 

are based on generator knowledge. The analytical results of phase one of the characterization 

study will determine the list of constituents of subsequent sampling events. 

In addition, field measurements of pH, specific conductance, temperature, dissolved oxygen, and 

turbidity will be taken of flow back aqueous samples. 
Data Quality Objectives (DQOs) are qualitative and quantitative statements to ensure that data of 

known and appropriate quality are obtained during the characterization study (sampling and 

analysis). 

The data objectives will address characterization of the flow back fluids associated with well 

fracturing generated from Devonian shale. This characterization study will: 

Identify the specific constituents of interest (COI) associated with flow back water; 

Reduce/eliminate the allegations that the chemicals used for fracturing will contaminate 

groundwater; and 

Provide sufficient information for the selection of proper disposal techniques. 

 

Achieving these data objectives will require obtaining data of acceptable levels of 

certainty. Therefore, it is essential that the field and sampling procedures be completed 

under stringent and appropriate methods 

 

There are typically five analytical levels of data quality available to accomplish the objectives of 

investigations of this type. These levels are typically designated as follows: 

Level I: field screening or analysis using portable instruments, calibrated to noncompound specific standards; 

Level II: field analysis using portable instruments, calibrated to specific compounds; 

Level III: non-Contract Laboratory Program (non-CLP) laboratory methods; 

Level IV: CLP Routine Analytical Services (RAS) methods; and 

Level V: non-standard analytical methods. 

DQO Levels I and III will be used to characterize the Devonian Shale Fracturing Flowback 

sampling activities. The following sections describe the use of the analytical procedural levels 

that will be used during the project. 

Field Screening Methods - Level I

Field determinations of pH, specific conductance, temperature, dissolved oxygen, and turbidity 
will be made during characteristic sampling as part of a field screening procedure. These 

analytical methods are used to determine stability of the well and they are typically designated as 

Level I data quality. 

In addition, as part of the health and safety program, worker safety may be monitored via one or 

more of a variety of field screening tests such as a photoionization detector (PID) or flame 

ionization detector (FID) to test for volatile organic vapors, or a combustible gas indicator to test 

for explosivity potential. These tests, which are semi-quantitative, are classified as field 

screening evaluations, even though they typically are not used for site characterization purposes. 

Non-CLP Laboratory Methods - Level III

Level III analytical procedures provide precise, accurate and defensible data for the intended data 

uses, with a less formal documentation and reporting nomenclature at reduced analytical costs 

over Level IV data quality procedures. Data Quality Level III will be used during this 

characterization study. Table 1, summarizes analyses that will be conducted to characterize and 

quantify constituent concentrations. 

The exact quantitative criteria used to evaluate data quality from the laboratory's precision and 

accuracy perspective for the aqueous and solid sampling media will be presented in the selected 

laboratory Quality Assurance Manual(s) (Appendix QAPP-1 and following). The following is a 

description of terms that appear in the QAM. 

Reference: The reference of the U.S. EPA standard analytical methodology used for each 

procedure. 

Precision: A measure of the mutual agreement among individual measurements of the same 

property under prescribed similar conditions. Precision is evaluated based on the relative percent 

difference (RPD) between duplicate matrix spike results or duplicate sample results, as 

appropriate. The matrix spike duplicate RPD limits are parameter and method-specific, 

MS/MSD RPD QC limits will be presented in the laboratory QAMs. Laboratory duplicate 

sample RPD limits are typically 20 percent for aqueous media and 35 percent for solid media 

(exceptions may apply for solid media whose samples may be nonhomogeneous). Field 

duplicates are also evaluated by calculating the RPDs between field duplicate sample results. 

However, evaluations of field duplicate RPDs are used as advisory determinations since 

numerous factors in sampling and analysis may cause variances between field duplicate results. 

Accuracy: The degree of agreement of a measurement with an accepted reference or true 

value. Accuracy is evaluated based on the percent recovery of spiked samples. The matrix spike 

recoveries for organic analyses are method and parameter specific and are typically used as an 

advisory QA/QC measure due to the difficulty associated with recovering spiked organic 
parameters. Organic parameter percent recovery QC limits will be presented in the laboratory’s 

QAM. The matrix spike recoveries for inorganic and most conventional parameters are typically 

a range of ±25 percent. 

Completeness: A measure of the amount of valid data obtained from a measurement system 

compared to the amount expected to be obtained under normal conditions. The method of 

calculation for percent completeness is defined in Section 12.3. Completeness can be evaluated 

in two ways: 1) by comparing the number of samples actually collected to the expected number 

of samples to be collected; and 2) by comparing the number of valid analyses received from the 

laboratory to the number of actual samples collected. The results of any Level III analyses to be 

performed is typically used for characterization studies and as such will have a minimum 

completeness of 95 percent for both evaluations of completeness. 

Exact QA/QC criteria the laboratory will use to evaluate its data's precision and accuracy will be 

provided following selection of the analytical laboratory, if the criteria are not method-specific. 

Table 1 summarizes the individual parameters and associated reporting limits. 

There are also qualitative criteria that are adhered to ensure that data of known and appropriate 

quality are obtained during investigation activities. These criteria include representativeness and 

comparability. 

The sampling and analysis programs are designed to ensure that analytical data obtained during 

the characterization study represent current conditions found at the site and produce data of 

comparable quality. The sampling frequency was selected to ensure data are suitable for their 

intended use and adequately characterize the flow back water. Additionally, standard recognized 

analytical methodologies will be utilized to ensure comparability. These designs are instituted to 

ensure appropriate sample representativeness and data comparability. 
This section outlines the procedures to be used for the preparation of sampling equipment and 

containers and for sample preservation. It also provides some of the quality control and 

operating procedures to be followed for sampling. Detailed field sampling details including the 

number of samples to be collected, the rationale for sampling, and QC requirements are 

described in the Field Sampling and Analysis Plan. 

Each sample collected for this characterization study will be assigned a unique sample tracking 

number. The identification of the well location and participating gas company will not be 

identified. All well locations will be blind. GTI will assign each well a project identifier. The 

project identifier will be a unique single alphanumeric letter that will identify the Devonian Shale 

well location and company. This unique alphanumeric letter will be provided to the third party 

environmental consultants to be used in the sample designation. 

Flow back Sampling 

Fracturing is completed over several days depending on the geological formation. The flow back 

water is initially removed at a faster rate at the start of production and significantly declines as 

production continues. It is believed that the volume of water is relative to the concentration. It is 

assumed that the concentration of the fracturing chemicals remain constant throughout the flow 

back regardless of the rate of return. However, the increase of in the COI is due to a longer 

residence time in the applicable formation and not associated to the additives of the fracturing 

fluids. Therefore, to obtain representative samples of the flow back water samples will be 

collected on three separate days (i.e., days 1, 5 and 14). 

 

Additionally, a baseline sample of the fracturing fluid will be collected prior to injection. The 

baseline sample will contain the materials (e.g., water and chemicals) used in the fracturing 

process. A sample will also be collected from a well in Devonian shale that has been in 

production for a period of time (i.e., I production fro more than 3 months). The analytical results 

associated with these samples will assist in the data interpretation. 

Quality Assurance

The quality assurance field will only be used to indicate a sample collected for quality assurance 

purposes. 

Quality Assurance/Quality Control Samples will be identified as follows: 

EB - Equipment Blank 

TB - Trip Blank 
The following are sample identification samples. 

A05V Sample collected from company X on day 5 from a vertical well. 

CEH Sample collected from company Y from an existing horizontal well. 

TB Trip Blank. 

Each sample container will be marked with a label identifying the specific parameters of interest. 

The label will record the date of sample collection, alphanumeric identification, parameters to be 

analyzed, and preservatives, if applicable. Sample bottles should be prelabeled by the laboratory 

to avoid unnecessary delays. 

The specific information for each sample will be documented in the field logbook and on a 

chain-of-custody form. The sample identification will be correlated in the logbook and chain-ofcustody by sample designation, sampling date, time, and location. The analytical parameters for 

which the sample is to be analyzed and the respective number of sample bottles will be provided 

on the chain-of-custody sheet. 

All new pre-cleaned sample bottles with screw-type Teflon-lined lids will be used for holding 

and shipping samples. These sample bottles will be supplied by the analytical laboratory, and 

pre-preserved by the laboratory as necessary. 

Two types of field QA/QC samples will be collected (i.e., trip blanks and equipment blanks). 

The following provides a description of the essential field QA/QC samples. 

Trip blanks are collected only for volatile organic samples. The trip blank is prepared by the 

laboratory by filling a batch of pre-cleaned 40-ml vials with laboratory-grade water. The vials 

are transported to the site and returned to the laboratory in the same manner as the environmental 

sample containers. Any constituents found in the trip blank could be attributed to: a) interaction 

between the sample and the container, b) contaminated laboratory-grade water, or c) a storage or 

handling procedure which alters the sample. One trip blank should accompany VOC samples for 

each sampling event. The trip blank is placed in the cooler that contains samples for volatile 

organics. At no time after the preparation are trip blanks to be opened before they are returned to 

the laboratory. 
To verify that no constituents are introduced from sampling equipment, equipment blanks are 

collected by pouring distilled water through the representative sampling device and analyzing for 

all constituents of interest. One equipment blank will be collected during the characterization 

study. 

A number of documents will be used during the characterization study. These documents 

include: chain-of-custody forms and field data sheets. 

Chain-of-custody Forms

The field chain-of-custody form is used to record the custody of all samples collected. This 

chain-of-custody form documents the transfer of the custody from the sampling personnel to 

another person, to the laboratory, or another party, such as a courier delivery service. 

When the field team sends samples to an analytical laboratory, each shipping cooler containing 

samples, which are sent under one shipping document, must be accompanied by a chain-ofcustody form (Figure 1). These forms document information regarding the origination of 

samples and those parties having subsequent possession of samples. They also contain 

information pertaining to these samples, such as project name, name of the individuals collecting 

the samples, sample identification number, the date and time of collection, the number of sample 

containers for each parameter of interest for each sample, remarks or observations of samples, if 

appropriate, the signature of the person relinquishing control of the samples and the person 

receiving the samples, and the name of the overnight carrier shipping the samples to the 

laboratory. The original chain-of-custody sheet is sent with the samples. One copy will be 

submitted to Gas Technology Institute (GTI), and the other copy is stored in the field team files. 
The primary objective of sample custody is to create an accurate written verified record, which 

can be used to trace the possession and handling of the samples from the moment of collection 

through data analysis and reporting. 

The field sampler will be personally responsible for the care and custody of the samples collected 

until they are properly transferred. Samples will be accompanied by a Chain-of-Custody Record. 

 

Upon arrival at the laboratory, samples will be checked in using laboratory custody procedures 

outlined in the laboratory QAM. The laboratory is required to verify that all samples were 

received and in good condition. The laboratory should assign a laboratory-specific sample 

identification. This unique identification guarantees sample anonymity to the analyst of the 

sample's site. 

Once samples have been logged-in and transferred to the proper storage areas, the laboratory 

department manager is responsible for their proper storage and condition. Copies of the 

completed Chain-of-Custody Records and an analysis narrative presenting laboratory sample 

identifications and their correlating field assigned sample identifications should be included in 

the data package for delivery to the data user. 
All analyses will be performed using U.S. EPA analytical methods procedures from the 

following: 

 Third Edition (September 1986), as amended by updates 1 (July 1992), II (September 

1994), IIA (August 1993), and IIB (January 1995), or the most current SW-846 update; 

 EPA's "Handbook for Analytical Quality Control in Water and Wastewater Laboratories" 

(EPA 600/1-79-019); 

 Standard Methods for the Examination of Water and Wastewater. 

Table 1 and Table 2, summarize the list the constituents of interest (COIs) associated with the 

characterization study for the flow back water from the wells of the Devonian shale and the 

required reporting limits to be reported by the laboratory. Method selection was based on the 

following factors: reliability in identification and quantifications, and comparability of sample 

results and best achievability of the lower of federal Maximum Contaminant Levels (MCLs). 

All procedures for environmental sample handling, storage, and documentation while in the 

laboratory's custody and deliverable requirements upon delivery of the data to the user are stated 

in the laboratory QAMs. 
All field and laboratory equipment are calibrated before use to ensure proper operating 

conditions. Laboratory instrument calibration procedures are presented in the laboratory QAMs. 

Field calibration procedures and frequencies should be followed in accordance with the 

manufactures specifications. Field calibrations must be completed each day at a minimum. pH 

meters are required to be calibrated or verified every two hours at a minimum. 

All analytical methods must be validated at some point by the use of calibration standards. A 

calibration standard is made by the appropriate dilution of a pure substance, the purity of which 

is traceable to an NBS or U.S. EPA standard. Because of the high sensitivity of many analytical 

instruments, the calibration standard is an extremely dilute version of the pure compound. 

Because of the high dilution required to be within the linear range of the instrument, the 

preparation of the calibration standard is frequently made by serial dilution rather than in a single 

step. In order to provide standard solutions at sufficiently low concentrations, a minuscule 

amount of the pure substance will be required, the measurement of which is subject to extreme 

error. Thus, it is preferable to deal with potential dilution errors, rather than with the large error 

associated with the measurement of a very small amount of the pure substance. 

The initial standard is usually obtained either as a pure material or as a prepared certified solution 

of a given concentration of the pure compound or compounds. In preparing the stock solution of 

the calibration standard, great care must be exercised in measuring weights and volumes as 

accurately as possible, since all of the analyses following the calibration will be based on the 

accuracy of the calibration, and the accuracy of the analytical data is dependent on the calibration 

curve. It is the analyst's responsibility to assure that all standards used are within the standard 

solution holding time, and to prepare fresh standard solutions whenever necessary. In preparing 

working solutions, or using working solutions, the analyst must check for signs of deterioration 

of the standard, such as cloudiness, precipitation, or discoloration. The standard must also be 

periodically compared with previous runs of standards, and with independently prepared 

standards to assure that response factors fall within a historically accepted range. 

There are many laboratory functions that may require corrective action. The decision to 

undertake corrective action, and the ensuing action must be documented so that traceability can 

be maintained. The point of originating the corrective action varies, depending upon the mode of 

detection that such action is necessary. It is generally the role of either the Laboratory QA 

Officer or the Laboratory Department Manager to initiate such action. Those actions that affect 

the quality of the data will be recorded and the record maintained by the Laboratory QA Officer. 
The general procedures for appropriate laboratory corrective actions and identification of 

potential problems are presented in the analytical laboratory QAM. 
Data are typically validated by the laboratory and field personnel. First, during the field 

operations, field measures will be validated at the time of collection by the field sampler by 

verifying the use of standard operating procedures for the sampling effort and using field QC 

checks. Second, laboratory analytical results will be validated by the Laboratory Department 

Manager or the analyst who is the specific analytical task leader. 

Validation of field obtained data, as well as ongoing QA/QC checks of environmental samples 

being taken, is performed on field data. All field data are reviewed during the time of collection 

and second, all data are reviewed by secondary field personnel if multiple personnel are present. 

Corrections in the field logbooks will be removed by placing a single line through the entry, 

initialing and dating the correction. If information is added without a correction being necessary 

that entry will be initialed and dated to indicate that it was not entered at the original time of data 

entry. Entries should never be “whited out” or made in pencil. 

The individual Laboratory Department Managers should validate all laboratory data, prior to 

reporting. Some of the following QA/QC measures are reviewed or procedures are typically 

used: 

A standard curve is prepared prior to sample analysis; 

The standard regression coefficient is within the acceptable range; 

Standard reference materials are analyzed at the proper frequencies and acceptable results 

are obtained; 

The reagent blanks are analyzed at the proper frequency; 

Precision requirements of this plan are met; 

Accuracy requirements of this plan are met; 

Completeness requirements of this plan are met; 

Samples are analyzed within the proper sample holding times; 

All calculations are verified as correct; 

Proper units are reported; and 

The proper methodologies were used. 

Besides this review of analytical results and project specific precision, accuracy, and 

completeness requirements, the Laboratory Department Manager should perform unannounced 

audits of report forms and other data sheets as well as regular reviews of instrument logs, 

performance test results, and analysts’ performance. Any review of analytical results or internal 

QA/QC checks that indicate problems, immediate corrective actions should be taken and all data 

collected since the previous approved QC audits should be reviewed for validity. Specific 
laboratory procedures for validation of the analytical data generated are described in the 

laboratory QAMs. 

The laboratory will provide DQO Level 3 (i.e., CLP Like) data packages. However, the data 

packages will not be validated at this time. Data validation procedures following the applicable 

guidance from the current U. S. EPA's Contract Laboratory Program, National Functional 

Guidelines for Organic Data Review and the U. S. EPA's Contract Laboratory Program, 

National Functional Guidelines for Inorganic Data Review will be performed, if required. 

Analytical Laboratory

Once the data have been validated internally by the laboratory, all of the results are electronically 

or automatically entered into the laboratory's data management system where they are stored 

prior to reporting. When all analyses are completed for data storage, the Laboratory Director (or 

his/her designee) will issue a final data report including a descriptive case narrative. He or she 

will then issue the report to the data user. All applicable QC data should be included with the 

final report. 

The data reports generated for this project should contain all pertinent information for the data 

user to determine the applicability and usability of the data for its intended purposes. For this 

reason, a specified and uniform data reporting format should be implemented. For this project, 

DQO levels III data packages will be reported as a Level IV (CLP-like) deliverable to facilitate 

data validation, if needed. The following criteria and information should be supplied, at a 

minimum, for data reports generated for this project: 

1. A descriptive case narrative identifying any problems encountered during internal data 

validation (as described above); 

2. Completed and legible chain-of-custodies for all analyses contained within each 

submitted data package; 

3. A lab sample chronicle indicating which analyses were requested and performed for the 

samples contained in the data package; 

4. A summary of the laboratory sample identifications and the correlating field sample 

identifications; 

5. A summary of all applicable analytical results reported in the correct number of 

significant figures, reporting units; and 
6. Included in the individual sample reporting results should be the complete sample 

identifications, the sample dilutions (if necessary), and the individual sample analysis 

dates. 

Summary reporting only will be provided. Bulleted items above are required under this DQL. 

Summary reporting only will be provided. The data package reporting requirements are the same 

as Level I except legible and calculated QA/QC summaries for laboratory blanks, surrogate 

recoveries (if applicable), laboratory control sample recoveries, and matrix spike/matrix spike 

duplicate recoveries (or matrix spike recovery and laboratory duplicate results) must also be 

supplied under this DQL. 

The following summary forms and raw data deliverable requirements will apply for Data Quality 

Level III. 

The following forms are required for all analyses using Gas Chromatography/Mass Spectroscopy 

methods. 

Narrative and sample identification cross reference; 

Copies of Chain-of-Custody documentation; 

Laboratory chronicle; 

Method summaries and references; 

Organic analysis data sheet for samples and blanks (with TICs as required); 

System monitoring compound/surrogate recoveries summary; 

Matrix spike/Matrix spike duplicate summary or any lab duplicate; 

QC Check Sample summary; 

Method blank summary and results; 

Instrument performance check summary; 

Initial calibration summary for all constituents of interest; 

Continuing calibration check summary for all constituents of interest; 

Internal standard area and RT summary; 

Extraction/preparation logs; 

The handwritten calculation for at least one positive result in one sample at a rate of one 

calculation per twenty samples or per data package (whichever is greater) per fraction 

(e.g., VOC or SVOC); and 

Raw data including run logs, mass spectra, quantitation reports and chromatograms for 
samples, as well as any raw data used to complete the hand written calculation. 

The following forms are required for all total metal analyses. 

Narrative and sample identification cross reference; 

Copies of Chain-of-Custody documentation; 

Laboratory chronicle; 

Method summaries and references; 

Inorganic analysis data sheets; 

Initial and continuing calibration verification; 

Initial and continuing calibration blanks and preparation blank summary; 

ICP interference check sample summary; 

Spike sample recovery; 

Duplicate results summary; 

Laboratory Control Sample summary; 

Standard addition results summary, when applicable; 

ICP serial dilutions; 

Instrument detection limits; 

ICP inter-element correction factors summary; 

Preparation log; 

Analysis run log; 

The hand-written calculation for at least one positive result in one sample at a rate of one 

calculation per twenty samples or per data package (whichever is greater) per method 

(e.g., GFAA/ICP/CU); and 

Raw data. 

The following data and summary forms will be submitted by the laboratory for inorganic nonmetals analyses or other analyses not discussed above: 

Narrative and sample identification cross reference; 

Copies of Chain-of-Custody documentation; 

Laboratory chronicle; 

Method summaries and references; 

Analysis data sheets; 

Calibration summaries; and 

Calibration equation and curve plot; 

Blank results summary; 

Sample spike recovery, where applicable; 

Duplicate sample results, where applicable; and 

Laboratory control sample summary where applicable. 
Quality control (QC) procedures and checks are used to verify the accuracy of investigation data. 

Field QC checks are used to identify potential problems with sampling procedures such as the 

inconsistent use of sampling standard operating procedures or field introduced sample or water 

supply contamination and/or problems with sample homogeneity or representativeness. 

Laboratory QC checks are used to identify potential problems with analytical procedures such as 

the misapplication of required analytical methodologies or other laboratory related problems 

which could result in inaccurate or imprecise data reported. The laboratory QC checks and 

procedures presented in this section are required for most of the applicable methods, but the 

frequency of the QC checks should follow procedures outlined in the laboratory QAMs. 

To check the quality of data from field sampling efforts, field blanks and field duplicate samples 

will be collected for analysis. These samples will be treated as separate samples for 

identification, logging, and shipping. Analytical results on blanks and duplicates will be reported 

with the appropriate field sample data. The number of these samples, when required, and their 

use was described in Section 5.0. 

The equipment blank provides a check on possible sources of sample contamination. The 

equipment blanks should be collected in the worst-case scenario. The reason for performing 

equipment blanks in the most impacted area is to attempt to simulate a worst-case scenario 

regarding contributions from site condition or from improperly cleaned sampling equipment to 

sample contamination. One equipment blank will be for this project. Equipment blanks should 

be handled, transported, and analyzed in the same manner as the samples with which they are 

associated. 

The equipment blank water must be maintained at 4 (±2) C following collection and during 

shipment. Holding times for individual parameters are dictated by the specific analytical method 

being used. The holding-time clock begins at the time of sample collection of the equipment 

blank. 

Trip blanks are used to check for sample contamination introduced by the sample containers, by 

the sampling equipment, or by the sampling environment. Trip blanks travel to the site with the 

empty sample bottles and return from the site with the collected samples in an effort to simulate 

sample handling conditions. Trip blanks are collected in association with samples that are to be 

analyzed for volatile organic compounds. Potential sources of sample contamination are from 
the laboratory-grade reagent water, sample containers, field or laboratory ambient air, laboratory 

reagents, or cross contamination during shipping, handling, preparation or analysis. A trip blank 

should accompany VOC samples for each sampling event. 

The trip blank water must be maintained at 4 (±2) C through sample collection activities and 

during shipment. Holding times for individual parameters are dictated by the specific analytical 

method being used. The holding-time clock begins at the time of sample collection of the oldest 

sample in the sampling container. 

The QC check frequencies and requirements specified in the following sections is a general 

description only. The laboratory will follow the internal QC checks specified in its QAM for 

each analysis type employed. However, these QC checks must meet, at a minimum, the 

requirements specified in the respective U.S. EPA analytical methods. 

The following internal laboratory QC checks are performed for most analyses, whenever 

applicable, to ensure the measurement systems are under control: 

Initial and continuing calibrations; 

Preparation/method blanks; 

Matrix spike and matrix spike duplicate or matrix spike and laboratory duplicate analysis, 

as appropriate; 

Surrogate spike standard performance evaluation (for organic analyses only); and 

Calibration check compounds and reagent blanks (for organic analyses only). 

Additional internal laboratory QC checks are typically performed for most analyses, as required 

by the associated analytical method. Only the most common QC checks are generally described 

below. 

9.2.1 INITIAL AND CONTINUING CALIBRATION 

Each measurement system must be calibrated immediately prior to use and be shown to maintain 

the calibration throughout the course of the analysis. For the organic parameter methods, all 

target compounds will be checked during initial and continuing calibrations. Calibration 

procedures and frequencies is discussed for the various analysis types in the laboratory QAMs. 

An initial calibration will be performed prior to WSC sample analyses. Continuing calibrations 

will be typically analyzed at a minimum frequency of one every ten samples. For CLP GC/MS 

analysis, calibration checks are only required once every 12 hours of analysis. 

A preparation or method blank is run with each batch of samples received for analysis. 

Compound or analyte responses observed in the blank at levels above the reportable detection 
limit are reviewed for possible laboratory contamination. If high blank values are observed, 

laboratory glassware and reagents may need to be checked for contamination and the analysis of 

future samples halted until the system can be brought under control. A high blank value is 

typically defined as a value greater than the method detection limit. A preparation and/or method 

blank will be prepared at a frequency of one per 20 samples or one per day, whichever is greater. 

 

For all analyses where matrix spiking is possible, 1 in 20 samples is analyzed as matrix spikes 

and matrix spike duplicates or 1 in 20 samples is analyzed as matrix spikes and duplicates. Field 

personnel must provide additional volume for the laboratory to complete a MS/MSD. The 

percent recovery for spiked samples is calculated using the equations given in Section 12.0 and 

compared to the accuracy criteria specified in the QAM for the associated analytical method. 

The relative percent difference of replicate spikes or replicate analytical results are calculated 

using the equations given in Section 12.0 and compared to the precision criteria specified in the 

laboratory QAMs (Appendix QAPP-1 and following) for the associated analytical method. 

Surrogate standards are defined as nonpriority pollutant compounds used to monitor the percent 

recovery efficiencies of the analytical procedures on a sample-by-sample basis. Surrogate 

standard determinations are performed on all samples and blanks for organic analyses. All 

samples are fortified with surrogate spiking compounds before purging or extraction to monitor 

the preparation and analysis of samples. 

Surrogate compounds and recovery levels for the associated analyses are presented in the 

laboratory QAM (surrogate recovery limits are method- and media-specific and are either 

specified in the method or are calculated annually by the analytical laboratory as described in the 

analytical method). When the surrogate recovery level is outside of the control limits on the 

initial analysis, the laboratory must take the following actions for all organic analyses for 

samples:

Check calculations to assure there are no errors, check internal standard and surrogate 

spiking solutions for degradation or contamination and check instrument performance; 

and 

Recalculate or reinject/repurge the sample or re-extract and reanalyze the sample. 

These calibration check compounds and reagent blanks are analyzed periodically throughout the 

course of the analysis, depending on the required analysis. The exact frequencies and methods of 

use are presented in the laboratory QAM. 
Two types of audit procedures may be conducted during any environmental investigation: 

performance audits and system audits. These audits may be performed on the laboratory as well 

as field activities. A description of the laboratory's specific guidance for Performance and 

System Audits will be presented in laboratory QAMs. General procedures for laboratory 

performance and system audits are presented below. 

Laboratory performance audits are typically conducted by the Laboratory QA Officer on a regular 

basis. Each laboratory analyst is given a performance evaluation sample containing analytes for 

the parameters which he/she usually performs. These audit samples are used to identify 

problems in sample preparation or analysis techniques or methodologies which could lead to 

future analytical problems. 

Additionally, the laboratory performance audits include verification of each analyst's record 

keeping, proper use and understanding of procedures, and performance documentation. 

Corrective action will be taken for any deficiencies noted during the audit. 

Laboratory system audits are typically conducted by the Laboratory QA Officer. These audits are 

used to ensure that all aspects of the Laboratory's QAM are operative. This involves a thorough 

review of all laboratory methods performed and documentation to confirm that work is 

performed according to project specifications. 

In some cases, outside certification agencies conduct performance and system audits to verify 

contract compliance or the laboratories' ability to meet certification requirements on methods of 

analysis and documentation. Results of these outside certification audits may be reviewed at any 

time as a check on the laboratory’s internal auditing procedures. 
The following discussion describes the procedures that will be employed to evaluate the 

precision, accuracy, and completeness of the generated data. 

Precision is a measure of agreement among individual measurements of the same property under 

prescribed similar conditions. Precision is assessed by calculating the relative percent difference 

(RPD) of replicate spike samples or replicate sample analyses according to, the following 

equation: 

RPD = R1 - R2 x 100 where R1 = result 1 

 (R1 + R2)/2 R2 = result 2 

Accuracy is a measure of the closeness of an individual measurement to the true value. Accuracy 

is measured by calculating the percent recovery (%R) of known levels of spike compounds as 

follows: 

 concentration of spike sample - concentration of unspiked 

sample

%R = _____________________________________________________ x 100

 concentration of spike added

Completeness is a measure of the amount of valid data obtained from a measurement system, 

expressed as a percentage of the number of valid measurements that should have been collected. 

As is specified in Section 4.2, more than one completeness check can be evaluated. It is 

calculated as follows: 

 number of valid samples reported

Completeness (%) = _______________________________ x 100

 total number of samples analyzed
Quality control charts can be prepared after every 20 analytical determinations to graphically 

evaluate precision and accuracy criteria. The charts are prepared by calculating the mean value 

of the determinations and setting control limits at + 3 standard deviations from that mean. The 

following equations are used: 

The control limits should be within acceptance limits or ranges presented in the as yet unselected 

laboratory's QAM. If the values are found to be outside these limits or ranges, the measurement 

system is examined to determine if possible problems exist. 
Periodic preventive maintenance is required for equipment whose performance can affect results. 

Instrument manuals are kept on file for reference if equipment needs repair. Troubleshooting 

sections of manuals are often useful in assisting personnel in performing maintenance tasks. 

Field sampling personnel will be responsible for preventive maintenance of all field instruments. 

The field sampling personnel will protect the instruments by placing them in portable boxes 

and/or protective cases. 

All field equipment will be subject to a routine maintenance program, prior to and after each use. 

 The routine maintenance program for each piece of equipment will be in accordance with the 

manufacturer's operations and maintenance manual. All equipment will be cleaned and checked 

for integrity before and after each use. Necessary repairs will be performed immediately after 

any defects are observed, and before the item of equipment is used again. 

Equipment parts with a limited life (such as batteries, membranes and some electronic 

components) will be periodically checked and replaced or recharged as necessary according to 

the manufacturer's specifications. 

Preventive maintenance is important since it provides for a longer useful life of the equipment 

and helps to ensure a successful field sampling and testing program. Each piece of field 

equipment will have its own log sheet which contains the equipment identification and the type 

of maintenance performed. Since most equipment is used on an irregular basis, all equipment 

will be properly stored when not in use. 

All major laboratory instruments should normally be under service contract so that trained 

professionals are available on call to minimize instrument downtime. Other preventive 

maintenance schedules and/or procedures for laboratory equipment is presented in the laboratory 

QAMs (Appendix QAPP-1 and following). 
Corrective action procedures are divided into two subgroups: methods corrective action and 

systems corrective action. These corrective actions are implemented whenever system or 

performance audits note deficiencies or when QC procedures indicate a potential analytical 

problem. The laboratory guidance on Corrective Action procedures is presented in the laboratory 

QAMs. 
This QAPP provides a documentable mechanism for the assurance of quality work performed at 

for the characterization study. Audit reports will be provided by the Laboratory Director (or 

his/her designee) as a means of tracking program performance, as applicable, or if needed. 

Additionally, periodic assessments of measurement data accuracy, precision, and completeness 

and significant QA/QC problems will be performed and reported to laboratory and/or project 

management, if needed. 

Field QA reports will not be necessary considering the expected size and length of any individual 

sample collection activities. Any problems noted during sampling will be immediately 

communicated to GTI, so GTI can take whatever corrective actions necessary. 

Upon completion of the project-specific Work Plans, a final QA/QC report will be issued, 

assessing the overall degree of project conformance to specifications and the impact of any nonconformances that may affect management decisions. 

The final storage location of the files will be maintained at GTI’s office in Chicago. The files 

will be maintained for a period of at least three years. 
48 

Appendix C 

Tabulated Data Obtained from Locations A - S

Key to Abbreviations 

μg/l Micrograms per liter. ND Non-detect. Result is less than 

the method detection limit. 

B Method blank contamination. 

The associated method blank 

contains the target analyte at a 

reportable level. 

M Result was measured against 

nearest internal standard 

assuming a response factor of 1. 

E Estimated result. Result 

concentration exceeds the 

calibration range. 

MDL Method detection limit. 

J Estimated result. Result 

concentration exceeds the 

calibration range. 

RL Reporting limit. 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a) 5 U 5 U 5 U 5 U 925Amenable cyanide mg/L 0.01 SM18 4500-CN E 0.01 U 0.01 U 0.01 U 0.01 U 0.01 Ammonia Nitrogen mg/L 0.1 MCAWW 350.1 3.6 J 19.6 J 67.1 J 121 J 293Biochemical Oxygen Demand mg/L 2 SM18 5210 B 794 353 374 2.8 12.5Bromide mg/L 1 MCAWW 300.0A 0.2 U 82.9 274 604 1260Chemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4 3120 1670 9090 3280 28300Chloride mg/L 1 MCAWW 300.0A 74.6 J 9510 J 29800 J 67100 125000Dissolved Organic Carbon mg/L -- SM20 5310B 247 J 253 J 114 J 65 5960Fluoride mg/L 1 MCAWW 300.0A 0.05 U 0.5 G U 2.5 G U 5 G U 2.5 

Hardness, as CaCO3 mg/L 5 SM20 2340C 80 3600 12000 26000 59000Nitrate as N mg/L 0.05 MCAWW 300.0A 0.45 0.5 G U 2.5 G U 5 G U 2.5 Nitrate-Nitrite mg/L 0.1 MCAWW 353.2 1 J 0.36 J 0.33 J 0.18 J 0.1 Nitrite as N mg/L 0.05 MCAWW 300.0A 0.059 5 G U 29.3 17.6 2.5 Oil & Grease (HEM) mg/L 5 CFR136A 1664A HEM NA 4.8 U 4.8 U 5 U 62.6Specific Conductance umhos/cm -- MCAWW 120.1 498 J 31900 J 137000 J 248000 J 385000 Sulfate mg/L 1 MCAWW 300.0A 51.5 J 46.3 J 39.6 B J G 20.5 B J 50 

TOC mg/L 1 SM20 5310B 350 260 110 38.7 J 5680Total Alkalinity mg/L 5 SM18 2320 B 76.7 J 308 J 149 J 93.3 J 26.2 Total Dissolved Solids mg/L 10 SM18 2540 C 990 15400 54800 105000 216000Total Kjeldahl Nitrogen mg/L 3 MCAWW 351.3 39.2 56 76.2 124 202Total phosphorus mg/L 0.1 MCAWW 365.2 0.15 0.04 B 0.074 B 0.1 U 0.1 Total Suspended Solids mg/L 4 SM20 2540D 190 82 71 197 201Turbidity NTU -- MCAWW 180.1 321 13.1 2.3 20.1 175Cyanide, Total ug/L 10 SW846 9012A 10 U 10 U 10 U 10 U 10 Total Sulfide mg/L 3 SW846 9030B/9034 2.4 B 1.6 B 3.2 3 U 2.4 pH No Units -- SW846 9040 7.2 7.2 NA 6.5 5.7Total Recoverable Phenolics mg/L 0.01 SW846 9066 0.051 0.027 0.011 J 0.011 0.23Sulfite mg/L 1 SM4500-SO3 B NA NA NA NA NA

MBAS (mol.wt 320) mg/L 0.05 SM5540 C NA NA NA NA NA

Total and Dissolved MetalsAluminum ug/L 200 SW846 6010B 358 J 223 125 B J 174 B J 370 Aluminum-DISS ug/L 200 SW846 6010B 154 B J 47.7 B 166 B J 133 B J 348 Antimony ug/L 10 SW846 6010B 10 U 17.6 10 B 50 U 100 Antimony-DISS ug/L 10 SW846 6010B 10 U 18.3 9.5 B 10.2 B 100 Arsenic ug/L 10 SW846 6010B 10 U 13.3 17.4 B 24.8 B 46.2 Arsenic-DISS ug/L 10 SW846 6010B 10 U 12.8 21.5 B 19.4 B 106Barium ug/L 200 SW846 6010B 276 70200 J 157000 569000 639000Barium-DISS ug/L 200 SW846 6010B 104 B 30200 163000 583000 J 787000 Beryllium ug/L 4 SW846 6010B 4 U 4 U 20 U 20 U 40 Beryllium-DISS ug/L 4 SW846 6010B 4 U 4 U 20 U 0.9 B J 40 Boron ug/L 2000 SW846 6010B 43.8 B 8720 J 33700 56900 67300 Boron-DISS ug/L 2000 SW846 6010B 49.6 B 9000 J 34200 J 58000 J 85200 Cadmium ug/L 5 SW846 6010B 5 U 0.21 B 25 U 1.9 B 2.5 Cadmium-DISS ug/L 5 SW846 6010B 5 U 5 U 25 U 1.2 B 2.5 Calcium ug/L 5000 SW846 6010B 21100 828000 J 3400000 7820000 J 11400000 Calcium-DISS ug/L 5000 SW846 6010B 20200 827000 J 3460000 8070000 J 14400000 Chromium ug/L 5 SW846 6010B 5 U 21.1 25 U 31 17.7 Chromium-DISS ug/L 5 SW846 6010B 5 U 6.6 25 U 10.7 B 7.6 Cobalt ug/L 500 SW846 6010B 50 U 50 U 250 U 1250 U 2500 Cobalt-DISS ug/L 500 SW846 6010B 50 U 50 U 250 U 1250 U 2500 Copper ug/L 25 SW846 6010B 39.1 9.6 B 125 U 23 B 51.5 Copper-DISS ug/L 25 SW846 6010B 24.5 B 25 U 125 U 125 U 51.9 Iron ug/L 100 SW846 6010B 926 2680 10800 41200 J 103000Iron-DISS ug/L 100 SW846 6010B 362 1830 J 10300 40600 102000Lead ug/L 3 SW846 6010B 12.1 1.7 B 15 U 15 U 970Lead-DISS ug/L 3 SW846 6010B 7.6 3 U 15 U 15 U 647Lithium ug/L 500 SW846 6010B 40.4 B 9530 J E 24000 51800 67100Lithium-DISS ug/L 500 SW846 6010B 44.5 B 9480 J E 23300 E 51600 J 84900Magnesium ug/L 5000 SW846 6010B 3690 B 72800 J 314000 725000 1090000Magnesium-DISS ug/L 5000 SW846 6010B 3500 B 75300 319000 738000 1330000Manganese ug/L 150 SW846 6010B 91 697 960 1760 2130Manganese-DISS ug/L 150 SW846 6010B 73.3 704 991 1760 2590Molybdenum ug/L 400 SW846 6010B 1.2 B J 35.6 B J 30.6 B 18.8 B J 17 Molybdenum-DISS ug/L 400 SW846 6010B 4.8 B 34.8 B J 13.3 B 22.6 B 400 Nickel ug/L 40 SW846 6010B 9.5 B 68.3 33.2 B 33.3 B 2000 Nickel-DISS ug/L 40 SW846 6010B 2.6 B 61.5 29.5 B 21.2 B 2000 Potassium ug/L 5000 SW846 6010B 2300 B 183000 E 921000 1880000 1770000Potassium-DISS ug/L 5000 SW846 6010B 2590 B 188000 E 934000 E 1940000 2190000Selenium ug/L 5 SW846 6010B 3.2 B 5 U 25 U 25 U 50 Selenium-DISS ug/L 5 SW846 6010B 3 B 5 U 25 U 25 U 50 Silver ug/L 5 SW846 6010B 5 U 5 U 25 U 25 U 50 Silver-DISS ug/L 5 SW846 6010B 5 U 5 U 25 U 25 U 50 

2/20/2009

Day 14

Lewis County, WV

5/8/200

Day 5

2/11/2009

Day 1 Day 90

Location A

Day 0

2/7/2009 2/8/2009
PARAMETER UNITS PQL US EPA Method 2/20/2009

Day 14

Lewis County, WV

5/8/200

Day 5

2/11/2009

Day 1 Day 90

Location A

Day 0

2/7/2009 2/8/2009

Sodium ug/L 5000 SW846 6010B 88400 4490000 J E 15000000 31500000 39700000Sodium-DISS ug/L 5000 SW846 6010B 96100 4750000 15000000 32600000 49300000Strontium ug/L 50 SW846 6010B 726 E 137000 J E 872000 J 2080000 3480000Strontium-DISS ug/L 50 SW846 6010B 711 E 144000 J E 870000 J E 2080000 J 4370000 Thallium ug/L 10 SW846 6010B 19.8 B 4.9 B J 50 U 50 U 500 Thallium-DISS ug/L 10 SW846 6010B 23.6 B 6.2 B J 28.5 B J 17.4 B 500 Tin ug/L 1000 SW846 6010B 6.3 B 3.8 B 500 U 500 U 1000 Tin-DISS ug/L 1000 SW846 6010B 5.2 B 100 U 500 U 16.8 B 1000 Titanium ug/L 500 SW846 6010B 4 B 50 U 250 U 250 U 190 Titanium-DISS ug/L 500 SW846 6010B 50 U 50 U 250 U 250 U 196 Trivalent Chrom ug/L 50 SW846 6010B 5 U 6.6 25 U 25 U 50 Zinc ug/L 20 SW846 6010B 36.6 107 119 179 J 372 Zinc-DISS ug/L 20 SW846 6010B 35.5 89.9 115 J 160 J 382 Diss Hexavalent Cr-DISS mg/L 0.01 SW846 7196A 0.01 U 0.05 U 0.1 G U 0.1 G U 0.5 

Hexavalent Chromium mg/L 0.01 SW846 7196A 0.02 U 0.05 U 0.1 G U 0.1 G U 0.5 Mercury ug/L 0.2 SW846 7470A 0.036 B J 0.042 B J 0.027 B 0.029 B J 0.2 

Mercury-DISS ug/L 0.2 SW846 7470A 0.037 B J 0.08 B J 0.032 B J 0.028 B J 0.2 

Volatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,1,1-Trichloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,1,2-Trichloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,1-Dichloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,1-Dichloroethene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,1-Dichloropropene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,2,3-Trichlorobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,2,3-Trichloropropane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,2,4-Trichlorobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,2,4-Trimethylbenzene ug/L 5 SW846 8260B 16 4.7 J 1.1 J 1.9 J 0.82 1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,2-Dichlorobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,2-Dichloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,2-Dichloropropane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,3,5-Trimethylbenzene ug/L 5 SW846 8260B 6 3.1 J 5 U 10 U 5 1,3-Dichlorobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,3-Dichloropropane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,4-Dichlorobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 1,4-Dioxane ug/L 1000 SW846 8260B 1000 U 1000 U 1000 U 2000 U 1000 1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B NA NA NA NA NA 2,2-Dichloropropane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 2-Butanone ug/L 5 SW846 8260B 5 U 5 U 2 J 10 U 5 2-Chloroethyl vinyl ether ug/L 10 SW846 8260B 10 U 10 U 10 U 20 U 10 2-Hexanone ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 4-Chlorotoluene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Acetone ug/L 20 SW846 8260B 20 U 17 J 76 40 U 15 Acrolein ug/L 100 SW846 8260B 100 U 100 U 100 U 200 U 100 Acrylonitrile ug/L 100 SW846 8260B 100 U 100 U 100 U 200 U 100 Benzene ug/L 5 SW846 8260B 5 U 7.7 8 8.5 J 1.5 Benzyl chloride ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Bromobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Bromodichloromethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Bromoform ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Bromomethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Carbon disulfide ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Carbon tetrachloride ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Chlorobenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Chloroethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Chloroform ug/L 5 SW846 8260B 5 U 28 2.2 J 10 U 5 Chloromethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 cis-1,2-Dichloroethene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 cis-1,3-Dichloropropene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Dibromochloromethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Dibromomethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Dichlorodifluoromethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Ethylbenzene ug/L 5 SW846 8260B 2.3 J 0.98 J 5 U 10 U 5 Isopropylbenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Methyl tert-butyl ether (MTBE) ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Methylene chloride ug/L 5 SW846 8260B 5 U 1.6 J 1.4 J 10 U 5 Naphthalene ug/L 5 SW846 8260B 2.2 J 2.1 J 0.51 J 10 U 5 n-Butylbenzene ug/L 5 SW846 8260B 5 U 2 J 5 U 10 U 5 n-Propylbenzene ug/L 5 SW846 8260B 2 J 5 U 5 U 10 U 5 p-Isopropyltoluene ug/L 5 SW846 8260B 5 U 2.1 J 5 U 10 U 5 sec-Butylbenzene ug/L 5 SW846 8260B 3.2 J 5 U 5 U 10 U 5 Styrene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 
PARAMETER UNITS PQL US EPA Method 2/20/2009

Day 14

Lewis County, WV

5/8/200

Day 5

2/11/2009

Day 1 Day 90

Location A

Day 0

2/7/2009 2/8/2009

tert-butyl acetate ug/L -- SW846 8260B NA NA NA NA NA tert-Butylbenzene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Tetrachloroethene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 tetrahydrofuran ug/L -- SW846 8260B NA NA NA NA NA Toluene ug/L 5 SW846 8260B 3.1 J 5.1 2 J 3.4 J 1.6 trans-1,2-Dichloroethene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 trans-1,3-Dichloropropene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Trichloroethene ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Trichlorofluoromethane ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Vinyl acetate ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Vinyl chloride ug/L 5 SW846 8260B 5 U 5 U 5 U 10 U 5 Xylenes (total) ug/L 15 SW846 8260B 18 10 J 15 U 30 U 15 Semi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 1,2-Diphenylhydrazine ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 1,3-Dinitrobenzene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 1,4-Naphthoquinone ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 1-Naphthylamine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 2,3,7,8-TCDD ug/L -- SW846 8270C NA NA NA NA NA 2,4,5-Trichlorophenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 2,4,6-Trichlorophenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 2,4-Dimethylphenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 2,4-Dinitrophenol ug/L 40 SW846 8270C 48 U 480 U 940 U 480 U 480 2,4-Dinitrotoluene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 2,6-Dichlorophenol ug/L 2 SW846 8270C 2 19 U 38 U 19 U 19 2,6-Dinitrotoluene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 2-Acetylaminofluorene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 2-Chloronaphthalene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 2-Chlorophenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 2-Methylnaphthalene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 2-Methylphenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 2-Naphthylamine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 2-Nitroaniline ug/L 50 SW846 8270C 48 U 480 U 940 U 480 U 480 2-Nitrophenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 2-Picoline ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 3,3'-Dichlorobenzidine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 3-Methylcholanthrene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 3-Nitroaniline ug/L 50 SW846 8270C 48 U 480 U 940 U 480 U 480 4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C 48 U 480 U 940 U 480 U 480 4-Aminobiphenyl ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 4-Bromophenyl phenyl ether ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 4-Chloro-3-methylphenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 4-Chloroaniline ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 4-Nitroaniline ug/L 50 SW846 8270C 48 U 480 U 940 U 480 U 480 4-Nitrophenol ug/L 50 SW846 8270C 48 U 480 U 940 U 480 U 480 5-Nitro-o-toluidine ug/L 100 SW846 8270C 97 U 970 U 1900 U 960 U 950 7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Acenaphthene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Acenaphthylene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Acetophenone ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Aniline ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Aramite ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Benzidine ug/L 200 SW846 8270C 190 U 1900 U 3800 U 1900 U 1900 Benzo(a)anthracene ug/L 10 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Benzo(a)pyrene ug/L 5 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Benzo(b)fluoranthene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Benzo(ghi)perylene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Benzo(k)fluoranthene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Benzyl alcohol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 bis(2-Chloroethoxy)methane ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 bis(2-Chloroethyl) ether ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 bis(2-Chloroisopropyl) ether ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 bis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Butyl benzyl phthalate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Chlorobenzilate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Chrysene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Diallate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Dibenz(a,h)anthracene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Dibenzofuran ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Diethyl phthalate ug/L 10 SW846 8270C 9.7 U 97 U 35 J 96 U 95 Dimethoate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Dimethyl phthalate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Di-n-butyl phthalate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 
PARAMETER UNITS PQL US EPA Method 2/20/2009

Day 14

Lewis County, WV

5/8/200

Day 5

2/11/2009

Day 1 Day 90

Location A

Day 0

2/7/2009 2/8/2009

Di-n-octyl phthalate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Dinoseb ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Diphenylamine ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Disulfoton ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Ethyl methanesulfonate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Fluoranthene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Fluorene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Hexachlorobenzene ug/L 0.05 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Hexachlorobutadiene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Hexachlorocyclopentadiene ug/L 2 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Hexachloroethane ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Hexachloropropene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Indeno(1,2,3-cd)pyrene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Isodrin ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Isophorone ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Isosafrole ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Methyl methanesulfonate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Nitrobenzene ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 N-Nitrosodiethylamine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 N-Nitrosodimethylamine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 N-Nitrosodi-n-butylamine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 N-Nitrosodi-n-propylamine ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 N-Nitrosodiphenylamine ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 N-Nitrosomethylethylamine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 N-Nitrosomorpholine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 N-Nitrosopiperidine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 N-Nitrosopyrrolidine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 O,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 o-Toluidine ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Parathion ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 p-Dimethylaminoazobenzene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Pentachlorobenzene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Pentachloroethane ug/L 20 SW846 8270C 19 U 190 U 380 U 190 U 190 Pentachloronitrobenzene ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Pentachlorophenol ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Phenanthrene ug/L 2 SW846 8270C 2.7 19 U 38 U 19 U 19 Phenol ug/L 2 SW846 8270C 1.9 U 19 U 38 U 19 U 19 Phorate ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Pronamide ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Pyrene ug/L 2 SW846 8270C 0.54 J B 19 U 38 U 19 U 19 Pyridine ug/L 10 SW846 8270C 86 2600 1800 860 490Safrole ug/L 10 SW846 8270C 9.7 U 97 U 190 U 96 U 95 Thionazin ug/L 10 SW846 8270C 0.97 U 97 U 190 U 96 U 95 Tetraethyldithiopyrophosphate ug/L 10 SW846 8270C NA NA NA NA NAOrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 4,4'-DDE ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 4,4'-DDT ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Aldrin ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 alpha-BHC ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 beta-BHC ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Chlordane (technical) ug/L 0.05 SW846 8081A 0.48 U NA NA 0.48 U 0.48 delta-BHC ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Dieldrin ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Endosulfan I ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Endosulfan II ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Endosulfan sulfate ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Endrin ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Endrin aldehyde ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Endrin ketone ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 gamma-BHC (Lindane) ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Heptachlor ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Heptachlor epoxide ug/L 0.05 SW846 8081A 0.048 U NA NA 0.048 U 0.048 Methoxychlor ug/L 0.1 SW846 8081A 0.096 U NA NA 0.095 U 0.095 Toxaphene ug/L 2 SW846 8081A 1.9 U NA NA 1.9 U 1.9 

PCBsAroclor 1016 ug/L 0.4 SW846 8082 0.38 U NA NA 0.38 U 0.41 Aroclor 1221 ug/L 0.4 SW846 8082 0.38 U NA NA 0.38 U 0.41 Aroclor 1232 ug/L 0.4 SW846 8082 0.38 U NA NA 0.38 U 0.41 Aroclor 1242 ug/L 0.4 SW846 8082 0.38 U NA NA 0.38 U 0.41 Aroclor 1248 ug/L 0.4 SW846 8082 0.38 U NA NA 0.38 U 0.41 Aroclor 1254 ug/L 0.4 SW846 8082 0.38 U NA NA 0.38 U 0.41 

Aroclor 1260 ug/L 0.4 SW846 8082 0.38 U NA NA 0.38 U 0.41 
PARAMETER UNITS PQL US EPA Method 2/20/2009

Day 14

Lewis County, WV

5/8/200

Day 5

2/11/2009

Day 1 Day 90

Location A

Day 0

2/7/2009 2/8/2009

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141A 0.97 U NA NA 0.98 U 0.97 Alcohols

2-Propanol mg/L 10 SW846 8015 NA NA NA NA NAButyl alcohol mg/L 10 SW846 8015 NA NA NA NA NAEthanol mg/L 10 SW846 8015 NA NA NA NA NAMethanol mg/L 10 SW846 8015 NA NA NA NA NAn-Propanol mg/L 10 SW846 8015 NA NA NA NA NA

GlycolsEthylene Glycol mg/L 50 SW846 8015 NA NA NA NA NAPropylene glycol mg/L 50 SW846 8015 NA NA NA NA NAAcids

Acetic Acid mg/L 10 SW846 8015 NA NA NA NA NAButyric Acid mg/L 10 SW846 8015 NA NA NA NA NAPropionic Acid mg/L 10 SW846 8015 NA NA NA NA NAVolatile Acids mg/L 10 NA NA NA NA NA
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 107 106 

0.01 U 0.01 U 0.01 U 0.01 U 

9.3 J 32 J 82.4 J 107 J 

2 U 132 1950 149 

107 120 544 849 

1730 1340 6120 4340 

10700 J 10500 J 50000 78600 J 

153 J 204 J 50 J 36.9 J 

0.25 G U 0.65 1.2 G U 1.2 G U 

9500 4700 26400 43500 

0.25 G U 0.25 G U 1.2 G U 1.2 G U 0.15 0.27 J 0.15 J 0.089 B J 

5 G U 5 G U 12.5 G U 77.4 

19.4 5.7 4.8 U 30.8 

34600 J 48800 J 175000 J 284000 J 

198 J 222 J 106 60.1 J 168 207 50.6 34.2 121 J 226 J 97.6 J 53.2 J 

27800 22400 87800 112000 

23 51 71.7 112 

0.36 0.19 0.45 0.088 B 

790 81 35.6 17 338 130 20.9 25.6 

5.4 B 10 U 10 U 10 U 2.4 B 3 U 3 U 2.4 B 7.6 7.8 6.6 5.5 

0.082 0.064 0.01 U 0.015 

25.0 U 5.20 10.0 8.40 

0.500 U 0.0691 0.131 0.0857 

481 328 166 B 1000 U 200 U 39.9 B 1000 U 1000 U 

2.4 B 37.8 18 B 9.2 B 

3 B 37.4 12.2 B 12.6 B 

9.1 B 13.5 50 U 12.6 B 

10 U 11.3 50 U 10 B 

9810 3570 21400 J 74200 J 

11700 4680 J 37300 58200 J E 

4 U 4 U 20 U 2.2 B 4 U 4 U 20 U 20 U 

2140 J 9260 J 14300 J 16200 J 2400 J 9320 J 14800 J 16100 J 

10.5 5 U 25 U 1.4 B 

3.9 B 5 U 25 U 25 U 

2990000 1370000 J 7630000 J 12500000 J 3260000 J 1390000 J 8040000 J 12800000 J E 

4.8 B 11.1 7.5 B 8.4 B 1.5 B 8.6 7.2 B 25 U 

50 U 50 U 250 U 250 U 50 U 50 U 250 U 250 U 21 B 25 U 125 U 125 U 25 U 25 U 125 U 125 U 

11600 6030 20400 J 54200 

441 E 4440 18900 J 39800 111 3.8 15 U 15 U 

6.9 3 U 15 U 15 U 

14900 J E 13900 E 49100 J E 73700 J 16400 J E 14400 J E 49300 J 71400 J E 

235000 153000 817000 1330000 J 266000 154000 J 843000 1310000 

3640 1060 4220 7090 3930 1050 4360 7000 

8.9 B J 28.8 B J 9.6 B J 6.8 B J 5.4 B 29.1 B 27.6 B J 10.6 B J 

10.4 B 18.6 B J 11 B 7 B 

6.6 B 16.9 B 8.6 B 200 U 

229000 E 109000 E 300000 E 415000 257000 E 110000 E 316000 451000 E 

5 U 5 U 25 U 25 U 5 U 5 U 25 U 25 U 

0.82 B 0.73 B 2.8 B 5.5 B 

1.6 B J 5 U 25 U 25 U 

Washington, PA

Day 5 

Day 0 Day 1 Day 14

Location B

1/26/2009 1/29/2009 2/2/2009 2/10/2009
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Washington, PA

Day 5 

Day 0 Day 1 Day 14

Location B

1/26/2009 1/29/2009 2/2/2009 2/10/2009

6190000 6370000 22000000 J 32500000 J 6790000 6310000 22400000 31500000 J 

439000 E 167000 E 1080000 J E 1850000 J 478000 J E 166000 J E 1190000 J 1990000 J E 

6 B 5.4 B 50 U 50 U 

7.1 B 5.5 B J 50 U 50 U 6.9 B 5.1 B 500 U 500 U 9.4 B 7.4 B 500 U 500 U 

50 U 50 U 250 U 250 U 50 U 50 U 250 U 250 U 

4.8 B 11.1 5 U 8.4 

117 J 86.9 J 84.9 B J 66.8 B 

51.9 J 68.1 J 120 62.2 B 0.01 U 0.01 U 0.042 0.05 G U 0.05 G U 0.01 U 0.01 U 0.05 G U 0.55 J 0.05 B 0.023 B 0.049 B J 

0.054 B J 0.022 B 0.037 B 0.028 B J 

150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 140 J 82 110 J 74 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 100 J 33 120 65 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 

30000 U 5000 U 25000 U 10000 U 

NA NA NA NA 

150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 300 U 50 U 250 U 100 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 600 U 100 U 500 U 200 U 

3000 U 500 U 2500 U 1000 U 3000 U 500 U 2500 U 1000 U 

150 U 240 1200 420 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 

1500 25 U 120 U 50 U 

150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 

19 J 14 J 85 J 42 J 

150 U 3.2 J 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 

24 J 18 J 120 U 50 U 

150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 54 J 22 J 

84 J 25 U 68 J 50 U 

150 U 25 U 120 U 50 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Washington, PA

Day 5 

Day 0 Day 1 Day 14

Location B

1/26/2009 1/29/2009 2/2/2009 2/10/2009

NA NA NA NA 

150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 

NA NA NA NA 

81 J 340 2300 820 

150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 150 U 25 U 120 U 50 U 210 J B 180 B 1100 520 B 190 U 95 U 9.4 U 9.5 U 

38 U 19 U 1.9 U 1.9 U 

190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 

NA NA NA NA 

190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 7.7 J 9.4 U 9.5 U 940 U 480 U 47 U 48 U 190 U 95 U 9.4 U 9.5 U 

38 U 19 U 1.9 U 1.9 U 

190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 

38 U 19 U 1.9 U 1.9 U 

190 U 95 U 9.4 U 9.5 U 120 94 1.9 U 1.9 U 190 U 7.7 J 9.8 9.5 U 

41 J 95 U 9.4 U 9.5 U 

940 U 480 U 47 U 48 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 

3.5 J 8.7 J 14 11 

940 U 480 U 47 U 48 U 940 U 480 U 47 U 48 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 940 U 480 U 47 U 48 U 940 U 480 U 47 U 48 U 

1900 U 950 U 94 U 95 U 

190 U 95 U 9.4 U 9.5 U 

38 U 19 U 1.9 U 1.9 U 38 U 19 U 0.75 J 1.9 U 

190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 

3800 U 1900 U 190 U 190 U 

38 U 19 U 1.4 J B 1.9 U 38 U 19 U 1 J 1.9 U 38 U 19 U 1.1 J B 1.9 U 38 U 19 U 1.1 J 1.9 U 38 U 19 U 1 J B 1.9 U 

190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 

38 U 19 U 1.9 U 1.9 U 38 U 19 U 1.9 U 1.9 U 

190 U 95 U 1.8 J 1.8 J 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 

38 U 19 U 1.2 J B 1.9 U 

190 U 95 U 9.4 U 9.5 U 

38 U 19 U 3.2 1.9 U 

190 U 95 U 9.4 U 9.5 U 190 U 95 U 1.5 J 1.6 J B 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 1.8 J 9.5 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Washington, PA

Day 5 

Day 0 Day 1 Day 14

Location B

1/26/2009 1/29/2009 2/2/2009 2/10/2009

190 U 95 U 4.4 J 9.5 U 190 U 95 U 9.4 U 9.5 U 

38 U 19 U 1.9 U 1.9 U 

190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 

38 U 19 U 1.3 J B 1.9 U 11 J 8.4 J 1.9 U 1.9 U 38 U 19 U 0.99 J 1.9 U 38 U 19 U 1.9 U 1.9 U 

190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 

38 U 19 U 3.1 1.9 U 

190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 

38 U 19 U 1.9 U 1.9 U 

190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 

38 U 19 U 1.9 U 1.9 U 38 U 19 U 1.9 U 1.9 U 

190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 380 U 190 U 19 U 19 U 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 

22 J 16 J 1.8 J 1.9 U 38 U 11 J 1.9 U 1.9 U 

190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 9.5 U 

38 U 19 U 1.1 J B 1.9 U 

310 350 250 77 190 U 95 U 9.4 U 9.5 U 190 U 95 U 9.4 U 0.98 U 

NA NA NA NA 

0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 

0.48 U NA NA 0.5 U 

0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.048 U NA NA 0.05 U 0.095 U NA NA 0.099 U 

1.9 U NA NA 2U 

0.38 U NA NA 0.4 U 0.38 U NA NA 0.4 U 0.38 U NA NA 0.4 U 0.38 U NA NA 0.4 U 0.38 U NA NA 0.4 U 0.38 U NA NA 0.4 U 0.38 U NA NA 0.4 U 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Washington, PA

Day 5 

Day 0 Day 1 Day 14

Location B

1/26/2009 1/29/2009 2/2/2009 2/10/2009

0.96 U NA NA 0.98 U 

4 U 1 U 1 U 1 U 4 U 1 U 1 U 1 U 4 U 1 U 1 U 1 U 

88 8 3.2 4.7 

4 U 1 U 1 U 1 U 

20.1 20.6 20.8 11 

10 U 10 U 10 U 10 U 

NA NA NA 21.5 NA NA NA NA NA NA NA NA NA NA NA NA 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 5 U 5 U 

0.01 U 0.01 NR U 0.01 U 0.01 U 88.7 J 83.8 J 98.9 J 149 J 

4.9 132 63.7 39.8 0.2 U 151 331 637 

578 2980 5500 4560 

39.7 J 15100 J 39800 78100 J 

121 J 109 46.9 22.8 J 

0.036 B 0.5 G U 5 G U 1.2 G U 

36 4800 15000 33000 

0.86 0.98 5 G U 1.2 G U 

1.1 J 0.88 J 0.8 J 0.5 J 

0.05 U 3.1 B 7.1 20.3 

NA 13.9 5 U 4.7 U 

1190 J 64500 J 192000 J 239000 J 3

269 J 71.5 J 36.4 B J 22.3 B J 167 82.5 J 32.9 J 14.4 J 233 J 249 J 147 J 71.4 J 719 24700 61900 110000 2146 132 120 136 

16 8.5 1.3 0.55 

110 522 102 475 

9.1 164 14 72 

10 U 38.5 8.8 B J 10 U 

8 3U 3U 3U 

8.9 7.2 6.7 6.1 

0.0079 B J 0.0083 B 0.012 0.01 U 

NA NA NA NA NANA NA NA NA NA

217 J 705 B J 206 B J 235 B J 

68.7 B J 244 B J 176 B J 149 B J 

10 U 8.9 B 50 U 50 U 10 U 50 U 50 U 50 U 10 U 15.8 B 13.8 B 12 B 10 U 50 U 17.9 B 50 U 

63.1 B J 102000 J 787000 2160000 J 4257.2 B 15000 755000 J 2130000 J 430.21 B J 20 U 20 U 20 U 0.32 B J 20 U 20 U 20 U 

2430 J 13100 J 18800 19900 3460 J 14000 J 18500 J 19900 

5 U 25 U 25 U 2.2 B 5 U 25 U 25 U 25 U 

14300 1220000 4390000 J 9520000 18616400 J 1330000 J 4340000 J 9500000 J 194

1.2 B 49.1 20.8 B 21.8 B 1.1 B 9.4 B 14.6 B 25 U 

50 U 250 U 500 U 1250 U 50 U 250 U 500 U 1250 U 

7.7 B 28.4 B 125 U 125 U 

10.5 B 125 U 125 U 125 U 

439 J 29000 J 21200 J 33200 250 10500 18400 13800 

3.3 11.8 B 15 U 15 U 

205 15 U 15 U 15 U 

7.7 B J 16400 J E 43700 E 71800 E 9.2 B J 18000 J 41900 J 71200 J E 

2830 B 122000 432000 872000 173200 B 134000 426000 875000 18

58.7 1040 2440 4430 64.8 1020 2390 4420 

6.6 B 37.2 B 31.7 B J 18.8 B 6.1 B 17.8 B 45.1 B 20.7 B 1.3 B 10.9 B 200 U 200 U 

1 B 200 U 200 U 200 U 

42600 151000 349000 E 533000 E 545100 171000 343000 533000 E 5

5 U 25 U 25 U 25 U 5 U 25 U 25 U 25 U 5 U 25 U 25 U 25 U 5 U 25 U 25 U 25 U 

Lewis County, WV

Day 1 Day 5 

2/11/2009

Day 0 Day 14

2/17/2009 2/20/2009 2/27/2009 

Location C
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Lewis County, WV

Day 1 Day 5 

2/11/2009

Day 0 Day 14

2/17/2009 2/20/2009 2/27/2009 

Location C

70700 7690000 18200000 29100000 52886100 8430000 18000000 29200000 54

103 J 244000 J E 893000 E 1820000 J E 36168 J E 236000 J 891000 J 1800000 J E 37

10 U 50 U 19.4 B 15.9 B 

4.2 B 50 U 20.7 B 18 B 3.9 B 500 U 500 U 17.8 B 3.7 B 500 U 21.8 B 500 U 

50 U 250 U 250 U 250 U 50 U 250 U 250 U 250 U 

1.2 B 9.4 B 14.6 B 25 U 

11.7 B J 504 J 83.6 B J 116 78.6 J 92.4 B J 67.1 B J 100 0.01 U 0.1 G U 0.1 G U 0.5 U 0.01 U 0.1 G U 0.1 G U 0.07 B 

0.2 U 0.052 B J 0.04 B J 0.054 B J 

0.025 B J 0.056 B J 0.038 B J 0.2 U 

500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 

100000 U 20000 U 3000 U 1000 U 

NA NA NA NA ND U NA 

500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 

1000 U 200 U 30 U 10 U 

500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 

2000 U 400 U 60 U 8.1 J 

10000 U 2000 U 300 U 100 U 10000 U 2000 U 300 U 100 U 

500 U 100 U 8 J 3 J 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 

23000 1400 260 19 

500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Lewis County, WV

Day 1 Day 5 

2/11/2009

Day 0 Day 14

2/17/2009 2/20/2009 2/27/2009 

Location C

NA NA NA NA NA 

500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 

NA NA NA NA NA 

500 U 100 U 15 U 1.6 J 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 500 U 100 U 15 U 5 U 

1500 U 300 U 45 U 15 U 

9.6 U 9.7 U 9.8 U 9.4 U 1.9 U 1.9 U 2 U 1.9 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 

NA NA NA #N/A #N/A NA 

9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 

48 U 48 U 49 U 47 U 

9.6 U 9.7 U 9.8 U 9.4 U 1.9 U 1.9 U 2 U 1.9 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 1.9 U 1.9 U 2 U 1.9 U 9.6 U 9.7 U 9.8 U 9.4 U 1.3 J 2.1 0.34 J 1.9 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 

48 U 48 U 49 U 47 U 

9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 0.28 J 0.21 J 9.4 U 

48 U 48 U 49 U 47 U 48 U 48 U 49 U 47 U 

9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 

48 U 48 U 49 U 47 U 48 U 48 U 49 U 47 U 96 U 97 U 98 U 94 U 

9.6 U 9.7 U 9.8 U 9.4 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 9.6 U 2.9 J 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 

190 U 190 U 200 U 190 U 

1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 9.4 J 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 1.9 U 1.9 U 2 U 1.9 U 9.6 U 9.7 U 9.8 U 9.4 U 1.9 U 1.9 U 2 U 1.9 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 0.73 J 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 0.68 J 9.8 U 9.4 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Lewis County, WV

Day 1 Day 5 

2/11/2009

Day 0 Day 14

2/17/2009 2/20/2009 2/27/2009 

Location C

9.6 U 9.7 U 4.1 J 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 1.9 U 1.9 U 2 U 1.9 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 1.9 U 1.9 U 2 U 1.9 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 1.9 U 1.9 U 2 U 1.9 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 

19 U 19 U 20 U 19 U 

9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 

0.28 J 0.39 J 2 U 1.9 U 

1.9 U 1.9 U 2 U 1.9 U 9.6 U 9.7 U 9.8 U 9.4 U 9.6 U 9.7 U 9.8 U 9.4 U 1.9 U 1.9 U 2 U 1.9 U 

0.91 J 6.4 J 4.1 J 3 J 

9.6 U 9.7 U 9.8 U 9.4 U 

0.96 U 9.7 U 9.8 U 9.4 U 

NA NA NA NA NA

0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 

0.49 U NA NA 0.48 U 

0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.098 U NA NA 0.096 U 

2U NA NA 0.096 U 

0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Lewis County, WV

Day 1 Day 5 

2/11/2009

Day 0 Day 14

2/17/2009 2/20/2009 2/27/2009 

Location C

0.96 U NA NA 0.95 U 

NA NA NA NA NANA NA NA NA NANA NA NA NA NANA NA NA NA NANA NA NA NA NA

NA NA NA NA NANA NA NA NA NANA NA NA NA NANA NA NA NA NANA NA NA NA NANA NA NA NA NA
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1

Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 5 U 162

0.01 U 0.01 U 0.01 U 0.01 U

1.8 J 5.4 J 34.1 J 96

438 656 721 1080

1 35.5 242 766

3450 1290 6970 8590

234 4900 J 26800 J 78300857 J 435 J 161 305 J

0.15 0.75 0.5 G U 2.5 G 

230 1500 8400 40000

0.46 0.5 G U 0.5 G U 2.5 G 0.73 J 0.61 J 0.52 J 0.1 U0.32 4.7 6 2.5 G 

NA 4.8 U 350 21.3

1970 J 19200 J 122000 J 249000 J

374 J 348 J 25.9 J 50 G 741 342 161 J 302120 J 577 J 266 J 75.2 J

1410 9020 40700 155000

25.8 21.8 46.5 92.8

0.054 B 0.42 0.91 0.1 U

16 23.2 3220 153

385 31.4 786 174

10 U 10 U 10 U 10 U

8 1.6 B 2.4 B 3.2

7.1 7.7 6.6 6.2

0.065 J 0.01 U 0.028 0.0091 B

NA 10.8 9.60 9.60NA 3.38 0.210 4.54

298 J 887 J 47200 J 358 B

67.6 B J 681 J 670 B J 195 B

10 U 9.3 B 33.8 B 100 U10 U 9.8 B 13.6 B 100 U10 U 17.5 92.9 54 B10 U 16 17 B 50.7 B

111 B 7620 165000 1440000

75.4 B 4170 226000 J 1500000 J

4 U 4 U 20 U 40 U4 U 4 U 20 U 40 U

109 B E 5420 12200 13000 J103 B J 5750 J 13000 J 14000 J

5 U 5 U 7.4 B 2.5 B5 U 5 U 25 U 1.4 B

52700 297000 2260000 J 8500000 J56400 300000 2420000 J 8930000 J

4.3 B 32.6 130 50 U2.6 B 20 15 B 6.8 B1.1 B 50 U 250 U 1000 U0.7 B 50 U 250 U 1000 U

28.6 22.5 B 2280 250 U

25 U 25 U 125 U 250 U

1720 14700 140000 J 87800

810 10700 28400 78700

4.7 3 349 45.6 B2.6 B 3 U 15 U 60 U

17.5 B 4350 21400 4450028.4 B 4620 22700 J E 48000

16700 40800 291000 93300018000 42100 296000 1000000

146 1150 3290 4720149 1120 2540 5040

40 U 10.5 B 50.5 B J 400 U40 U 4.2 B 12 B 400 U

6.2 B 17.6 B 187 B 800 U2.1 B 4.1 B 13.3 B 800 U

3280 B 38000 144000 1910003540 B 38200 146000 202000

5 U 4.3 B 25 U 50 U5 U 5 U 25 U 50 U5 U 5 U 25 U 50 U5 U 5 U 25 U 50 U

Location D

2/12/2009 2/17/2009 5/13/09 2/13/2009

Day 5 Day 90

Greene County, PA

Day 0 Day 1
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Location D

2/12/2009 2/17/2009 5/13/09 2/13/2009

Day 5 Day 90

Greene County, PA

Day 0 Day 1

321000 2860000 12900000 26900000345000 2950000 14100000 28700000

789 J E 24100 J 345000 1220000911 J 24200 J 378000 J E 1300000 J

10 U 10 U 50 U 200 U10 U 10 U 50 U 200 U

6.7 B 7 B 25.7 B 1000 U5.5 B 6.3 B 500 U 1000 U3.2 B 15.1 B 195 B 130 B 

50 U 9.5 B 250 U 124 B 

4.3 B 32.6 15 B 50 U

43.6 248 2930 J 29.3 B 

36 J 108 J 283 J 130 B 

0.1 G U 0.1 G U 0.1 G U 0.5 G 0.1 G U 0.1 G U 0.1 G U 0.5 G 

0.025 B 0.05 B J 0.24 J 0.2 U0.056 B J 0.053 B J 0.064 B J 0.068 B 

2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 15 J 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U

400000 U 50000 U 20000 U 1000 U

NA NA NA NA 

2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U4000 U 500 U 200 U 10 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U8000 U 1000 U 140 J 20

40000 U 5000 U 2000 U 100 U40000 U 5000 U 2000 U 100 U

2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U

54000 7300 400 5 U

2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Location D

2/12/2009 2/17/2009 5/13/09 2/13/2009

Day 5 Day 90

Greene County, PA

Day 0 Day 1

NA NA NA NA 

2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U

NA NA NA NA 

2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U2000 U 250 U 100 U 5 U6000 U 750 U 300 U 15 U

11 U 9.8 U 9.7 U 9.4 U

2.2 U 2 U 1.9 U 1.9 U

11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U

NA NA NA NA 

11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U56 U 49 U 48 U 47 U11 U 9.8 U 9.7 U 9.4 U

2.2 U 2 U 1.9 U 1.9 U

11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U

2.2 U 2 U 1.9 U 1.9 U

11 U 9.8 U 9.7 U 9.4 U

7.5 3.7 1.9 U 1.9 U

11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U56 U 49 U 48 U 47 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 0.35 J 9.7 U 1.1 J56 U 49 U 48 U 47 U56 U 49 U 48 U 47 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U56 U 49 U 48 U 47 U56 U 49 U 48 U 47 U

110 U 98 U 97 U 94 U

11 U 9.8 U 9.7 U 9.5

2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U

0.97 J 5 J 9.7 U 2.1 J

11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U

220 U 200 U 190 U 190 U

2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U

11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U

2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U

11 U 3.9 J 30 9.4 U11 U 9.8 U 5.6 J 9.4 U11 U 9.8 U 9.7 U 9.4 U

2.2 U 2 U 1.9 U 1.9 U

11 U 9.8 U 9.7 U 9.4 U

2.2 U 2 U 1.9 U 1.9 U

11 U 9.8 U 9.7 U 9.4 U11 U 0.84 J 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 0.53 J 5.4 J
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Location D

2/12/2009 2/17/2009 5/13/09 2/13/2009

Day 5 Day 90

Greene County, PA

Day 0 Day 1

11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U

2.2 U 2 U 1.9 U 1.9 U

11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U

2.2 U 2 U 1.9 U 1.9 U2.2 U 0.31 J 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U

11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U

2.2 U 2 U 1.9 U 1.9 U

11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 3.2 J

2.2 U 2 U 1.9 U 1.9 U

11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U

2.2 U 2 U 1.9 U 1.9 U2.2 U 2 U 1.9 U 1.9 U

11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U22 U 20 U 19 U 19 U11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U

1.1 J 2 U 0.64 J 1.9 U2.2 U 2 U 1.9 U 2.4

11 U 9.8 U 9.7 U 9.4 U11 U 9.8 U 9.7 U 9.4 U

0.19 J 2 U 0.19 J 1.9 U

17 5.9 J 3.7 J 9.4 U11 U 9.8 U 9.7 U 9.4 U

0.96 U 9.8 U 9.7 U 0.97 U

NA NA NA NA

0.05 U NA NA 0.049 U0.11 NA NA 0.049 U0.05 U NA NA 0.049 U0.05 U NA NA 0.049 U0.05 U NA NA 0.049 U0.05 U NA NA 0.049 U

0.5 U NA NA 0.49 U

0.05 U NA NA 0.049 U0.05 U NA NA 0.049 U

0.0093 J PG NA NA 0.049 U

0.05 U NA NA 0.049 U

0.067 PG NA NA 0.049 U0.018 J PG NA NA 0.049 U

0.05 U NA NA 0.049 U0.05 U NA NA 0.049 U0.05 U NA NA 0.049 U

0.053 PG NA NA 0.049 U

0.05 U NA NA 0.049 U

0.1 U NA NA 0.098 U

2U NA NA 2 U

0.4 U NA NA 0.39 U0.4 U NA NA 0.39 U0.4 U NA NA 0.39 U0.4 U NA NA 0.39 U0.4 U NA NA 0.39 U0.4 U NA NA 0.39 U0.4 U NA NA 0.39 U
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Location D

2/12/2009 2/17/2009 5/13/09 2/13/2009

Day 5 Day 90

Greene County, PA

Day 0 Day 1

0.96 U NA NA 0.97 U

420 200 170 63 J

10 U 10 U 20 U 47 J10 U 10 U 20 U 28 J26 39 110 410 J10 U 10 U 20 U 10 Y50 U 50 U 52 100 U

260 160 160 100 U

NA NA NA 6.3 JNA NA NA 1.6 UNA NA NA 1.7 UNA NA NA NA
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 5 U 40.8 

0.027 0.01 NR U 0.01 U 0.01 U 

15.6 J 36.3 J 70.3 J NA 

788 158 106 32.4 

32.8 172 536 880 

996 1330 17700 4670 

3560 16900 48900 76800 

663 J 167 J 59.4 J 7.5 

3.9 1.2 0.045 B 2.5 U 

1060 4700 20000 39200 

0.31 B 1.3 1.5 B J 2.9 

1.1 J 0.38 J 0.38 J 0.91 J 

0.14 B 1.2 G U 2.5 G U 2.5 G U 

6.6 U 5 U 5.1 4.9 U 

4980 J 68400 J 183000 J 256000 J 

50.3 10.7 B J 40.2 B J 39.8 B J 

226 108 46.2 5.9 308 J 278 J 135 J 87.9 J 

5910 28900 55100 124000 

7.8 42.5 86.1 95.5 

0.14 0.11 0.097 B 2.5 G U 

1040 7 47 1100 

715 42.6 32.5 74.8 

69 35.5 10 U 10 U 

3U 3U 3U 3U 7 6.9 6.5 6 

0.14 J 0.057 J 0.0076 B 0.011 10.4 36.8 18.8 18.8 0.05 U 0.0621 0.258 0.05 U 

166 B 176 B 571 B 539 B J 

2000 U 2000 U 230 B 467 B J 

100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 35.4 B 50.8 B 100 U 27.4 B 54.4 B 81.6 B 

2210 26700 434000 1010000 J 2560 45700 489000 1000000 

40 U 40 U 40 U 40 U 40 U 40 U 40 U 40 U 

414 B J 8360 J 14400 J 16800 502 B J 10900 J 16000 J 17200 

50 U 50 U 50 U 4.4 B J 50 U 50 U 50 U 2.1 B 

227000 1030000 4950000 9600000 J 265000 1270000 5430000 10500000 J 

50 U 50 U 50 U 14 B J 50 U 50 U 50 U 50 U 

500 U 500 U 1000 U 1000 U 500 U 500 U 1000 U 2500 U 250 U 250 U 250 U 250 U 250 U 250 U 250 U 250 U 

1180 12400 28200 74800 1230 13600 29700 49800 J 

30 U 30 U 60 U 38.2 B J 30 U 30 U 34.4 B 150 U 

808 11800 34600 56100 

1000 15300 39400 58500 

49400 B 131000 559000 1000000 56100 160000 602000 1120000 J 

189 782 2630 5170 J 227 967 2880 5590 400 U 19.7 B 8.7 B 400 U 400 U 30 B 13.8 B 400 U 400 U 10.6 B 800 U 800 U 400 U 17.9 B 800 U 2000 U 

13200 B 63800 173000 299000 16600 B 80500 194000 281000 

50 U 50 U 50 U 30.1 B 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 8.9 B 

Greene County

4/1/2009 4/7/2009

Day 0 Day 14 Day 1 Day 5 

4/3/2009 

4/17/2009

Location E
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Greene County

4/1/2009 4/7/2009

Day 0 Day 14 Day 1 Day 5 

4/3/2009 

4/17/2009

Location E

1460000 7540000 21300000 32600000 1770000 9760000 23400000 31600000 

23200 139000 650000 1370000 J 28000 178000 721000 1380000 J 

100 U 100 U 200 U 200 U 100 U 100 U 200 U 500 U 

1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 

500 U 500 U 90 B 121 B 500 U 39.5 B 102 B 134 B 

50 U 50 U 50 U 50 U 

200 U 406 264 200 U 200 U 471 295 66.1 B 

0.05 G U 0.0086 B 0.5 G U 0.5 G U 

0.1 G U 0.01 U 0.5 G U 0.5 G U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.044 B J 0.2 U 0.2 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

0.72 J 5 U 1.1 J 5 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 5 U 0.64 J 5 U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

1000 U 1000 U 1000 U 1000 U 

NA NA NA NA 

5U 5U 5U 5U 5U 5U 5U 5U 

10 U 10 U 10 U 10 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

6.4 J 7.9 J 17 J 12 J 

100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 

5 U 7.8 5.8 17 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 2J 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 5 U 0.67 J 5 U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 0.73 J 5 U 5 U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Greene County

4/1/2009 4/7/2009

Day 0 Day 14 Day 1 Day 5 

4/3/2009 

4/17/2009

Location E

NA NA NA NA 

5U 5U 5U 5U 5U 5U 5U 5U 

NA NA NA NA 

5.6 3.8 J 7.7 13 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

15 U 15 U 5.1 J 3.2 J 10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 

10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

NA NA NA NA 

10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 50 U 100 U 47 U 48 U 10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 

10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 

10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 

10 U 0.32 J 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 50 U 100 U 47 U 48 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 0.87 J 0.38 J 50 U 100 U 47 U 48 U 50 U 100 U 47 U 48 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 50 U 100 U 47 U 48 U 50 U 100 U 47 U 48 U 

100 U 210 U 94 U 96 U 

10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 2 U 4.2 U 1.9 U 1.9 U 

10 U 9 J 10 6.4 J 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

200 U 420 U 190 U 190 U 

2 U 4.2 U 1.9 U 1.9 U 2 U 4.2 U 1.9 U 1.9 U 2 U 4.2 U 1.9 U 1.9 U 2 U 4.2 U 1.9 U 1.9 U 2 U 4.2 U 1.9 U 1.9 U 

10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 2 U 4.2 U 1.9 U 1.9 U 

4.1 J 21 U 1.6 J 9.6 U 

10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 

10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 

10 U 21 U 9.4 U 9.6 U 10 U 21 U 0.43 J 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

0.36 J 21 U 0.32 J 9.6 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Greene County

4/1/2009 4/7/2009

Day 0 Day 14 Day 1 Day 5 

4/3/2009 

4/17/2009

Location E

10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 

10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 2 U 4.2 U 0.27 J 1.9 U 2 U 4.2 U 1.9 U 1.9 U 2 U 4.2 U 1.9 U 1.9 U 

10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 

10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 

10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 2 U 4.2 U 1.9 U 1.9 U 

10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 20 U 42 U 19 U 19 U 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

1.3 J 4.2 U 1.9 U 1.9 U 

2 U 2.6 J 3.2 1.9 U 

10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

2 U 4.2 U 1.9 U 1.9 U 

35 430 310 200 10 U 21 U 9.4 U 9.6 U 10 U 21 U 9.4 U 9.6 U 

NA NA NA NA 

0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 

0.49 U NA NA 0.48 U 

0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.098 U NA NA 0.096 U 

2U NA NA 1.9 U 

0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Greene County

4/1/2009 4/7/2009

Day 0 Day 14 Day 1 Day 5 

4/3/2009 

4/17/2009

Location E

0.95 U NA NA 0.96 U 

10 UJ 5 UJ 5 UJ 10 UJ 10 UJ 20 J 10 J 10 UJ 10 UJ 5 UJ 5 UJ 10 UJ 10 UJ 5 UJ 5 UJ 10 UJ 10 UJ 5 UJ 5 UJ 10 UJ 

1000 UJ 100 UJ 100 UJ 50 UJ 1000 UJ 100 UJ 100 UJ 50 UJ 

100 UJ 10 UJ 50 UJ 500 UJ 100 UJ 10 UJ 50 UJ 500 UJ 100 UJ 10 UJ 50 UJ 500 UJ 230 290 260 380 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 B

MBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved Metals

Aluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 5 U 5 U 

0.01 U 0.01 U 0.01 U 0.01 U 20.8 J 12.9 J 60.3 J 115 J 

2.7 154 75.4 64.8 0.2 U 0.2 U 376 826 

13.2 J 851 J 2470 J 5170 18.5 30.7 31500 72000 10

3.6 J 288 J 40.2 J 47.3 J 

NA 0.1 1.2 G U 5 G U 

182 190 12300 34000 5

0.39 0.41 1.4 5 G U 0.51 0.47 0.45 J 0.34 J 0.05 U 0.05 U 1.2 G U 5 G U 

4.7 U 7.3 4.9 U 20.4 

575 J 476 J 124000 J 233000 J 28139 59.2 102 60.7 B 

3.8 J 205 43.5 62.8 

80.9 J 126 J 157 J 54 J 

215 462 61200 116000 15

56.4 33.5 77.7 55.9 

0.043 B 0.44 0.22 0.16 

16.8 90 B 6.8 204 15.7 145 14.8 45.6 

10 U 10 U 10 U 10 U 

5.6 8.8 2.4 B 3 U 6.7 7 6.4 6.4 

0.01 U 0.085 0.058 0.016 J 9.20 61.6 5 U 13.6 

0.0613 0.112 0.0641 0.05 U 0

2000 U 2000 U 510 B 950 B 2000 U 189 B 282 B 363 B 

19 B 100 U 100 U 100 U 

100 U 100 U 100 U 100 U 100 U 100 U 36.9 B 78.4 B 100 U 100 U 23 B 91.2 B 

74.7 B 91.4 B 19200 77100 891.6 B J 95.2 B J 16600 J 55200 7

40 U 40 U 40 U 40 U 40 U 40 U 40 U 40 U 

65.9 B J 122 B J 12600 J 12200 J 122.2 B 39.6 B 12400 16900 J 1

50 U 50 U 50 U 2.2 B 50 U 50 U 50 U 3 B 

49800 B 59500 3980000 8880000 140063400 J 61800 J 3850000 J 12000000 1430

50 U 50 U 11.4 B 39.3 B 50 U 50 U 50 U 12.1 B 

500 U 500 U 10.5 B 1000 U 500 U 500 U 9.5 B 1000 U 250 U 49.3 B 62.1 B 116 B 250 U 250 U 50.3 B 250 U 882 B 2440 12200 49600 7

1000 U 2310 10600 45700 4

30 U 30 U 25.2 B 61 30 U 30 U 19 B 63.8 

500 U 30.1 B 33900 55900 8500 U 29.4 B 33000 78800 9

6700 B 7910 B 394000 881000 1388690 B 8410 B 386000 1180000 137

116 B 140 B 2390 4680 136 B 128 B 2300 6120 400 U 400 U 11.5 B 30.8 B 400 U 400 U 11.2 B 20.2 B 400 U 25.1 B 15.3 B 26.4 B 400 U 400 U 9.3 B 800 U 

50000 U 50000 U 157000 246000 3650000 U 50000 U 160000 336000 39

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

Day 0 Day 1 Day 5 Day 

Washington, PA

Supply Water

3/24/2009 3/24/2009 3/27/2009 

4/1/2009 4/9/2

Location F
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470A

Mercury-DISS ug/L 0.2 SW846 7470A

Volatile Organic Compounds

1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 0 Day 1 Day 5 Day 

Washington, PA

Supply Water

3/24/2009 3/24/2009 3/27/2009 

4/1/2009 4/9/2

Location F

7980 B 25700 B 14700000 23700000 34009540 B 27400 B 14700000 31600000 3640

220 B 303 B 539000 1350000 210274 B 312 B 531000 1880000 233100 U 100 U 100 U 200 U 100 U 100 U 100 U 200 U 

1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 

500 U 500 U 39.9 B 126 B 500 U 500 U 55.3 B 170 B 

50 U 50 U 50 U 11.8 B 

200 U 59.5 B J 132 B J 106 B 200 U 38.8 B 42 B 84.6 B 

0.01 U 0.01 U 0.011 0.01 U 0.01 U 0.02 G U 0.014 0.05 G U 0.61 B J 0.66 B J 0.065 B J 0.2 U 0.66 B J 0.93 B J 0.064 B J 0.2 U 

5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 

0.61 J 5 U 11 52 

5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 5.2 J 33 J 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 

1000 U 1000 U 2000 U 10000 U 

NA NA NA NA 

5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 

10 U 10 U 20 U 100 U 

5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 

20 U 6 J 14 J 200 U 

100 U 100 U 200 U 1000 U 100 U 100 U 200 U 1000 U 

5 U 5 U 280 880 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 7.6 J 29 J 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 

1.1 J 5 U 10 U 50 U 

5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260B

Xylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics

1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 0 Day 1 Day 5 Day 

Washington, PA

Supply Water

3/24/2009 3/24/2009 3/27/2009 

4/1/2009 4/9/2

Location F

NA NA NA NA 

5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 

NA NA NA NA 

1.1 J 5 U 300 920 

5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 5 U 5 U 10 U 50 U 

15 U 15 U 120 340 

9.8 U 9.4 U 19 U 10 U 

2 U 1.9 U 3.8 U 2 U 

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 

NA NA NA NA 

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 9.8 J 7.1 J 

49 U 47 U 94 U 50 U 

9.8 U 9.4 U 19 U 10 U 

2 U 1.9 U 3.8 U 2 U 

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 

2 U 1.9 U 3.8 U 2 U 

9.8 U 9.4 U 19 U 10 U 

0.85 J 1.9 U 3.8 U 2 U 

9.8 U 9.4 U 9 J 7.9 J 9.8 U 9.4 U 19 U 10 U 

49 U 47 U 94 U 50 U 

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 14 J 11 

49 U 47 U 94 U 50 U 49 U 47 U 94 U 50 U 

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 

49 U 47 U 94 U 50 U 49 U 47 U 94 U 50 U 98 U 94 U 190 U 100 U 

9.8 U 9.4 U 19 U 10 U 

2 U 1.9 U 3.8 U 2 U 2 U 1.9 U 3.8 U 2 U 

0.46 J 9.4 U 19 U 11 

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 

200 U 190 U 380 U 200 U 

2 U 1.9 U 3.8 U 2 U 2 U 1.9 U 3.8 U 2 U 2 U 1.9 U 3.8 U 2 U 2 U 1.9 U 3.8 U 2 U 2 U 1.9 U 3.8 U 2 U 

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 

2 U 1.9 U 3.8 U 2 U 2 U 1.9 U 3.8 U 2 U 

2.2 J 9.4 U 19 U 33 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 

2 U 1.9 U 3.8 U 2 U 

9.8 U 9.4 U 19 U 10 U 

2 U 1.9 U 3.8 U 2 U 

9.8 U 9.4 U 19 U 10 U 2.3 J B 1.8 J B 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 0.29 J 19 U 14 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270C

Tetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides

4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081A

Toxaphene ug/L 2 SW846 8081A

PCBs

Aroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082

Aroclor 1260 ug/L 0.4 SW846 8082

Day 0 Day 1 Day 5 Day 

Washington, PA

Supply Water

3/24/2009 3/24/2009 3/27/2009 

4/1/2009 4/9/2

Location F

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 

2 U 1.9 U 3.8 U 2 U 

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 

2 U 1.9 U 3.8 U 2 U 2 U 1.9 U 3.8 U 2 U 2 U 1.9 U 3.8 U 2 U 2 U 1.9 U 3.8 U 2 U 

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 

2 U 1.9 U 3.8 U 2 U 

9.8 U 9.4 U 19 U 10 U 1.3 J 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 

2 U 1.9 U 3.8 U 2 U 

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 

2 U 1.9 U 3.8 U 2 U 2 U 1.9 U 3.8 U 2 U 

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 

20 U 19 U 38 U 20 U 

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 0.6 J 1.9 U 3.8 U 0.29 J 

2 U 1.9 U 16 15 

9.8 U 9.4 U 19 U 10 U 9.8 U 9.4 U 19 U 10 U 

2 U 1.9 U 3.8 U 2 U 

9.8 U 370 520 250 9.8 U 9.4 U 19 U 10 U 

0.95 U 0.95 U 19 U 10 U 

NA NA NA NA 

0.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 0

0.48 U 0.47 U NA NA 

0.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.048 U 0.047 U NA NA 00.095 U 0.094 U NA NA 0

1.9 U 1.9 U NA NA 

0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 
PARAMETER UNITS PQL US EPA Method

Organophosphorus Pesticides

Ethyl parathion ug/L 0.4 SW846 8141A

Alcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015

n-Propanol mg/L 10 SW846 8015Glycols

Ethylene Glycol mg/L 50 SW846 8015

Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015

Volatile Acids mg/L 10

Day 0 Day 1 Day 5 Day 

Washington, PA

Supply Water

3/24/2009 3/24/2009 3/27/2009 

4/1/2009 4/9/2

Location F

0.95 U 0.95 U NA NA 

1 U 1 U 1 U 5 UJ 1 U 1 U 1 U 5 UJ 1 U 1 U 1 U 5 UJ 1 U 1.2 3.4 5 UJ 1 U 1 U 1 U 5 UJ 

10 U 44 10 U 100 UJ 10 U 10 U 31 B 100 UJ 

NA NA 10 UJ 10 UJ NA NA 10 UJ 10 UJ NA NA 10 UJ 10 UJ NA 75 1000 230 5
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

1230 5 U 5 19.4 

0.01 U 0.01 U 0.01 U 0.01 U 

441 J 71.4 J NA 359 J 189 302 144 7.3 

0.2 U 261 553 697 

502 2100 4470 12800 

86 43300 77200 102000 

11.6 124 J 58.4 43 J 0.19 2.2 B 2.4 B 2.5 G U 

130 15000 44000 55000 

3.4 1.6 B 2 B 2.5 G U 2.4 J 1.9 J 0.63 J 0.16 J 2.5 G U 2.5 G U 2.5 G U 2.5 G U 4.7 U 4.6 U 10.8 4.6 U 

6720 J 147000 J 278000 J 360000 J 2920 19 B J 39.2 B J 49.4 B J 

11.4 J 123 60.8 42.2 

5 U 124 J 72.4 J 47.7 J 

1920 74600 125000 169000 

400 69.9 94.9 130 

0.26 0.19 2.5 G U 2.5 G U 

4 68 260 162 

4.7 126 92 32.9 

10 U 10 U 10 U 10 U 

3 U 3 U 3 U 1.6 B 6 7 6.3 6.4 

0.017 J 0.01 U 0.0084 B 0.011 J 

5 U 5.60 23.2 13.6 

0.0933 2.94 0.736 1.06 

2000 U 505 B 927 B J 835 B J 2000 U 358 B 508 B J 562 B J 

100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 28.2 B 54.2 B 77.3 B 100 U 37.4 B 70.5 B 82.3 B 339 B 1160000 3220000 J 5150000 J 348 B 1340000 3260000 5070000 

40 U 40 U 40 U 40 U 40 U 40 U 40 U 40 U 

59.3 B J 3030 J 3840 3880 68.7 B J 3470 J 3890 3820 

50 U 50 U 3 B J 3.8 B J 50 U 50 U 50 U 3.2 B 

32900 B 4070000 9270000 J 13100000 J 31800 B 4360000 9700000 J 14800000 J 

50 U 50 U 20.8 B J 12.7 B J 50 U 50 U 50 U 6.6 B 

7.9 B 2500 U 1000 U 5000 U 

14.2 B 2500 U 5000 U 5000 U 

120 B 250 U 73.3 B 250 U 

85.3 B 250 U 250 U 250 U 

14300 15700 33500 39200 13100 3690 16700 J 31500 J 

30 U 30 U 40.4 B J 78 B J 30 U 30 U 150 U 150 U 

34.1 B 80300 153000 201000 38.7 B 93000 155000 202000 

6190 B 271000 608000 781000 6240 B 293000 647000 J 875000 J 

67.2 B 1680 3440 J 4780 J 73.7 B 1930 3550 5170 

400 U 8.9 B 12.4 B 400 U 400 U 12.1 B 400 U 400 U 457 14.9 B 800 U 2000 U 452 20.1 B 2000 U 2000 U 

50000 U 127000 210000 312000 50000 U 144000 235000 274000 

50 U 50 U 50 U 39.4 B 50 U 50 U 50 U 49.5 B 50 U 50 U 9.3 B 8.4 B 50 U 50 U 50 U 8.1 B 

Day 0 Day 15 Day 1 Day 5

3/31/2009 4/8/2009 4/13/2009 

Lycoming County, PA

4/22/2009

Location G
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 0 Day 15 Day 1 Day 5

3/31/2009 4/8/2009 4/13/2009 

Lycoming County, PA

4/22/2009

Location G

45000 B 18100000 30800000 40300000 44700 B 20900000 31400000 41100000 

691 947000 2350000 J 3650000 J 686 1090000 2530000 J 3710000 J 100 U 100 U 200 U 500 U 100 U 100 U 500 U 500 U 

1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 

500 U 55.9 B 133 B 148 B 500 U 105 B 121 B 138 B 

50 U 50 U 50 U 50 U 

40.7 B 200 U 67.6 B J 52.2 B J 46.9 B 200 U 41.6 B 49.8 B 0.01 U 0.5 G U 1 G U 2.5 G U 0.01 U 0.5 G U 1 G U 2.5 G U 

0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 1.3 J 5 U 5 U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

1000 U 1000 U 1000 U 1000 U 

NA NA NA NA 

5U 5U 5U 5U 5U 5U 5U 5U 

10 U 10 U 10 U 10 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

20 U 13 J 16 J 26 

100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 

2.2 J 5 U 5 U 5 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 1.7 J 5 U 5 U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 0 Day 15 Day 1 Day 5

3/31/2009 4/8/2009 4/13/2009 

Lycoming County, PA

4/22/2009

Location G

NA NA NA NA 

5U 5U 5U 5U 5U 5U 5U 5U 

NA NA NA NA 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

15 U 15 U 15 U 15 U 

9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

NA NA NA NA 

9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

47 U 46 U 47 U 48 U 

9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 2.7 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

47 U 46 U 47 U 48 U 

9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

47 U 46 U 47 U 48 U 47 U 46 U 47 U 48 U 

9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

47 U 46 U 47 U 2.6 J 47 U 46 U 47 U 48 U 94 U 92 U 94 U 95 U 

9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 0.22 J 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 

0.21 J 0.98 J 0.81 J 0.38 J 

9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

190 U 180 U 190 U 190 U 

1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 1.1 J 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Day 0 Day 15 Day 1 Day 5

3/31/2009 4/8/2009 4/13/2009 

Lycoming County, PA

4/22/2009

Location G

9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 0.22 J 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

19 U 18 U 19 U 19 U 

9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 55 30 14 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

NA NA NA NA 

0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 

0.48 U NA NA 0.47 U 

0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.095 U NA NA 0.094 U 

1.9 U NA NA 1.9 U 

0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Day 0 Day 15 Day 1 Day 5

3/31/2009 4/8/2009 4/13/2009 

Lycoming County, PA

4/22/2009

Location G

0.94 U NA NA 0.94 U 

5 UJ NA 10 UJ 10 UJ 5 UJ NA 10 UJ 10 UJ 5 UJ NA 10 UJ 10 UJ 

8.3 J NA 58 J 39 J 

5 UJ NA 10 UJ 10 UJ 

100 UJ NA 100 UJ 100 UJ 100 UJ NA 100 UJ 100 UJ 

10 UJ NA 100 U 10 J 10 UJ NA 100 U 18 J 10 UJ NA 100 U 10 UJ 

250 NA 430 10 UJ 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1

Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 87.5 5 U 447 90

0.01 NR U 0.01 0.01 NR U 0.01 U 0.18.1 J 64.8 J 50.2 J NA 2

110 1740 737 138 20

31.9 41.7 176 1190 16

924 6410 2470 6710 176

3000 2810 14500 110000 1430

79.7 J 1270 J 612 J 140 73

1.2 58.3 32.9 17.3 

1080 1010 5200 55000 630

0.5 G U 0.5 G U 0.99 B 0.081 B 

0.036 B J 0.15 J 0.5 J 0.22 J 0.0

4.9 0.5 G U 2.5 G U 5 G U 4.8 U 64.1 4.8 U 16.2 75

10100 J 9980 J 49400 J 398000 J 4820

53.3 J 58.5 J 68 J 47.1 B J 6178.3 1260 443 J 119 J 8975.8 J 81.8 J 253 J 54.5 J 38

5510 7080 19200 150000 2060

16.7 73.9 52.9 204 20.14 0.16 0.083 B 2.5 G U 2

24 230 27.5 246 4

33.7 305 53.8 198 220.2 680 75.6 10 U 

3 U 3 U 3 U 3 U 1

7.3 5.2 7.5 5.9 5

0.031 0.072 0.055 0.31 0.

15.2 18.8 16.8 8.00 170.05 U 0.0506 0.05 U 0.737 1

264 B E 425 B 666 B 2460 J 26

2000 U 223 B 466 B 731 B J 7

100 U 100 U 100 U 20 B 2100 U 100 U 100 U 100 U 2100 U 100 U 100 U 124 1100 U 100 U 100 U 107 1

5480 6280 11700 1550000 J 180006120 6320 18900 1320000 18600

40 U 40 U 40 U 40 U 40 U 40 U 40 U 40 U 

2450 J 2580 J 12200 J 97900 11402680 J 2470 J 14600 J 91300 1150

50 U 50 U 50 U 8.6 B J 1250 U 50 U 50 U 5.7 B 

315000 329000 1180000 13600000 J 164000325000 301000 1340000 13900000 J 191000

50 U 50 U 13.5 B 92.4 J 9450 U 50 U 13.8 B 23.8 B 37

500 U 500 U 500 U 2500 U 25500 U 500 U 500 U 2500 U 25250 U 250 U 246 B 102 B 2250 U 250 U 199 B 250 U 

4310 3560 8140 180000 24204010 3920 7920 107000 J 1350

30 U 30 U 33 104 B J 530 U 30 U 34.3 150 U 1

2240 2340 8460 96800 11502450 2290 10300 95000 1230

30600 B 32300 B 102000 1080000 1290031200 B 29200 B 115000 1090000 J 14600

237 253 489 2650 J 34242 E 235 558 2260 34400 U 400 U 38.9 B 60.1 B 32400 U 400 U 51.5 B 400 U 8

11.1 B 400 U 71 B 2000 U 20

400 U 7.8 B 77.6 B 2000 U 20

53600 57400 187000 2430000 2820056900 54600 224000 2270000 29200

50 U 35.3 B 50 U 50 U 9550 U 50 U 50 U 50 U 150 U 50 U 50 U 8.1 B 150 U 50 U 50 U 12.2 B 1

4/7/2009 4/7/2009 4/8/2009 4/13/2009 4/22/200

Day 14 

Westmoreland County, PA

Supply Water Day 0 Day 1 Day 5

Location H
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

4/7/2009 4/7/2009 4/8/2009 4/13/2009 4/22/200

Day 14 

Westmoreland County, PA

Supply Water Day 0 Day 1 Day 5

Location H

1380000 1460000 5160000 48100000 6490001490000 1410000 6130000 46100000 626000

76200 78500 281000 4440000 J 5410081100 74300 330000 4290000 J 62800

100 U 100 U 100 U 500 U 1100 U 100 U 100 U 500 U 1

1000 U 1000 U 1000 U 1000 U 201000 U 1000 U 1000 U 1000 U 20

500 U 500 U 92 B 313 B 2

28 B 27.8 B 136 B 153 B 250 U 50 U 13.8 B 23.8 B 37

40.5 B E 176 B 82.7 B 1230 J 2244.1 B 169 B 89.1 B 753 170.01 U 0.05 G U 0.02 G U 0.25 G U 

0.019 0.05 G U 0.019 B 0.25 G U 0

0.2 U 0.2 U 0.051 B 0.2 U 0

0.071 B J 0.093 B J 0.046 B J 0.27 0

4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 

24000 5 U 4000 630 

4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 

11000 5 U 1900 280 

4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 

800000 U 1000 U 100000 U 20000 U 10

NA NA NA NA N

4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 8000 U 10 U 1000 U 200 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 

66000 23 5800 1600 80000 U 100 U 10000 U 2000 U 180000 U 100 U 10000 U 2000 U 1

4000 U 6.7 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 

10000 5 U 1400 260 

4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

4/7/2009 4/7/2009 4/8/2009 4/13/2009 4/22/200

Day 14 

Westmoreland County, PA

Supply Water Day 0 Day 1 Day 5

Location H

NA NA NA NA N

4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 

NA NA NA NA N

4000 U 3 J 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 4000 U 5 U 500 U 100 U 5200 J 15 U 860 J 130 J 

9.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 9

NA NA NA NA N

9.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 9

48 U 49 U 47 U 47 U 

9.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 9

0.72 J 2 U 1.9 U 1.9 U 1

9.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 9

48 U 49 U 47 U 47 U 

9.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 9

0.19 J 9.8 U 9.4 U 9.4 U 9

48 U 49 U 47 U 47 U 48 U 49 U 47 U 47 U 

9.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 9

48 U 49 U 47 U 47 U 48 U 49 U 47 U 47 U 97 U 98 U 94 U 94 U 

9.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 1.9 U 1.9 U 11.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 9

190 U 200 U 190 U 190 U 1

1.9 U 2 U 1.9 U 1.9 U 11.9 U 2 U 1.9 U 1.9 U 11.9 U 2 U 1.9 U 1.9 U 11.9 U 2 U 1.9 U 1.9 U 11.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 1.9 U 1.9 U 11.9 U 2 U 1.9 U 1.9 U 19.7 U 16 9.4 U 10 9.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 19.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 1.3 J 1.3 J 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

4/7/2009 4/7/2009 4/8/2009 4/13/2009 4/22/200

Day 14 

Westmoreland County, PA

Supply Water Day 0 Day 1 Day 5

Location H

9.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 1.9 U 1.9 U 1

0.13 J 2 U 1.9 U 1.9 U 1

1.9 U 2 U 1.9 U 1.9 U 11.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 1.9 U 1.9 U 11.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 9

19 U 20 U 19 U 19 U 

9.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 0.8 J 1.9 U 11.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 91.9 U 2 U 1.9 U 1.9 U 19.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 99.7 U 9.8 U 9.4 U 9.4 U 9

NA NA NA NA N

0.048 U 0.048 U NA NA 0.00.048 U 0.048 U NA NA 0.00.048 U 0.048 U NA NA 0.00.048 U 0.048 U NA NA 0.00.048 U 0.048 U NA NA 0.00.048 U 0.048 U NA NA 0.0

0.48 U 0.48 U NA NA 0.

0.048 U 0.048 U NA NA 0.00.048 U 0.048 U NA NA 0.00.048 U 0.22 PG NA NA 0.00.048 U 0.048 U NA NA 0.0.048 U 0.048 U NA NA 0.0.048 U 0.048 U NA NA 0.0.048 U 0.048 U NA NA 0.00.048 U 0.048 U NA NA 0.00.048 U 0.048 U NA NA 0.00.048 U 0.048 U NA NA 0.00.048 U 0.048 U NA NA 0.00.096 U 0.096 U NA NA 0.0

1.9 U 1.9 U NA NA 1

0.38 U 0.38 U NA NA 0.0.38 U 0.38 U NA NA 0.0.38 U 0.38 U NA NA 0.0.38 U 0.38 U NA NA 0.0.38 U 0.38 U NA NA 0.0.38 U 0.38 U NA NA 0.0.38 U 0.38 U NA NA 0.
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

4/7/2009 4/7/2009 4/8/2009 4/13/2009 4/22/200

Day 14 

Westmoreland County, PA

Supply Water Day 0 Day 1 Day 5

Location H

0.96 U 0.95 U NA NA 0.

31 J 450 J 280 J NA 

5 UJ 10 UJ 10 UJ NA 5 UJ 10 UJ 10 UJ NA 5 UJ 10 UJ 10 UJ NA 5 UJ 10 UJ 10 UJ NA 

100 UJ 1000 UJ 100 UJ NA 1100 UJ 1000 UJ 300 J NA 1

50 UJ 50 UJ 50 UJ NA 50 UJ 50 UJ 50 UJ NA 50 UJ 50 UJ 50 UJ NA 57 170 260 NA 16
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1

Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 5 U 123 

0.01 U 0.01 U 0.01 U 0.01 U 

0.064 B 5.9 127 199 J 

2 U 578 399 99.4 

0.22 1 238 901 18.7 2560 8790 195 49.9 90.2 58700 148000 

3.2 J 577 600 59.6 

0.05 U 0.05 U 2.5 G U 2.5 G U 

38 42 8600 42000 

0.05 U 0.02 B 2.5 G U 2.5 G U 

0.1 U 0.59 1.1 0.1 U 

0.05 U 0.034 B 2.5 G U 2.5 G U 

4.8 U 62.2 53.9 4.8 U 

247 J 362 J 200000 J 470000 J 

8.3 J 8.4 J 36.6 B J 50 G U 4.7 J 607 610 48 9.3 J 33.4 J 175 J 48.8 J 

400 265 122000 238000 

3 U 65.4 150 160 

0.14 0.062 B 0.084 B 0.45 

2 B 192 308 696 

3.1 75.2 461 203 

10 U 4.1 B 10 U 10 U 

1.6 B 3 U 3 U 3 U 7.3 7.6 6.6 5.8 

0.01 U 0.028 0.015 0.022 21.6 27.6 NA 6.80 

0.240 0.05 U NA 1.31 

2000 U 2000 U 1750 B J 418 B J 2000 U 227 B 286 B J 596 B J 

100 U 100 U 31.5 B 47.2 B 100 U 100 U 18.9 B 200 U 100 U 100 U 42.9 B 59.6 B 100 U 100 U 29.9 B 62.6 B 

1640 B 1170 B 516000 1400000 1580 B J 1500 B J 532000 J 1740000 

40 U 40 U 40 U 80 U 40 U 40 U 40 U 80 U 

34.3 B J 33.9 B J 5930 J 11900 44.2 B J 49.9 B J 6240 15400 

50 U 50 U 2.9 B 9.6 B 50 U 50 U 2.6 B 11.4 B 

11600 B J 9900 B J 2950000 9400000 J 12000 B J 13000 B J 3060000 11700000 

50 U 50 U 50.4 12.2 B 50 U 50 U 18.7 B 100 U 

500 U 500 U 1000 U 2500 U 500 U 500 U 1000 U 2500 U 250 U 250 U 68.3 B 500 U 250 U 250 U 35 B 500 U 192 B 198 B 58700 49700 

1000 U 175 B 21000 39100 J 

30 U 30 U 60 U 150 U 30 U 30 U 60 U 150 U 

42.2 B 29.7 B 34600 97600 32.7 B 51.7 B 36500 125000 

1840 B 1360 B 177000 604000 1830 B 1720 B 185000 765000 J 

13.9 B 150 U 2840 5520 

150 U 11.5 B 2870 6810 400 U 400 U 90 B 27.6 B 400 U 400 U 84.2 B 29.2 B 400 U 400 U 66.8 B 2000 U 400 U 400 U 66.8 B 2000 U 

50000 U 50000 U 378000 811000 

2240 B 3790 B 410000 1040000 

50 U 50 U 50 U 100 U 50 U 50 U 50 U 100 U 50 U 50 U 50 U 100 U 50 U 50 U 50 U 100 U 

Day 1 Day 5 

5/9/2009 5/9/2009 5/15/2009 5/19/2009 

Cameron County, PA

Supply Water Day 0

Location I
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 1 Day 5 

5/9/2009 5/9/2009 5/15/2009 5/19/2009 

Cameron County, PA

Supply Water Day 0

Location I

24400 B 54200 34700000 65100000 24900 B 70800 35000000 83400000 

1500 1070 492000 J 1800000 1460 J 1340 J 500000 J 2210000 J 

100 U 100 U 200 U 500 U 100 U 100 U 200 U 500 U 

1000 U 1000 U 1000 U 2000 U 1000 U 1000 U 1000 U 2000 U 

29.9 B J 27.1 B J 69.9 B 143 B 29.6 B J 24.4 B J 44.3 B 211 B 

50 U 50 U 50 U 100 U 

25.7 B J 45.7 B J 314 269 B J 61.5 B J 79.4 B J 187 B 195 B 0.25 G U 0.25 G U 0.5 U 0.25 G U 0.25 G U 0.25 G U 0.27 B 0.25 U 

0.053 B J 0.044 B J 0.2 U 0.2 U 

0.05 B J 0.47 B J 0.2 U 0.2 U 

5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 3.1 J 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 

1000 U 1000 U 5000 U 1000 U 

NA NA NA NA 

5 U 5 U 25 U 5 U 5 U 7.5 25 U 5 U 

10 U 10 U 50 U 10 U 

5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 

6.3 J B 20 U 390 130 

100 U 100 U 500 U 100 U 100 U 100 U 500 U 100 U 

5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 1.6 J 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 13 B 25 U 5 U 5 U 0.95 J 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 1 Day 5 

5/9/2009 5/9/2009 5/15/2009 5/19/2009 

Cameron County, PA

Supply Water Day 0

Location I

NA NA NA NA 

5 U 5 U 25 U 5 U 5 U 1.3 J 8.9 J 5 U 

NA NA NA NA 

5 U 6.7 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 0.81 J 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 

15 U 2.6 J 75 U 15 U 

9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1.9 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 

NA NA NA NA 

9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 

47 U 48 U 470 U 47 U 

9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1.9 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1.9 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 0.67 J 9.4 U 9.5 U 94 U 0.53 J 9.4 U 9.5 U 94 U 9.4 U 

47 U 48 U 470 U 1.3 J 

9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 1.2 J 

47 U 48 U 470 U 47 U 47 U 48 U 470 U 47 U 

9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 0.75 J 

47 U 48 U 470 U 47 U 47 U 48 U 470 U 47 U 94 U 95 U 940 U 94 U 

9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 0.9 J 1.9 U 1.9 U 19 U 0.84 J 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 

190 U 190 U 1900 U 190 U 

1.9 U 1.9 U 19 U 0.97 J 1.9 U 1.9 U 19 U 6.7 1.9 U 1.9 U 19 U 10 1.9 U 1.9 U 19 U 6.9 1.9 U 1.9 U 19 U 5.9 9.4 U 9.5 U 41 J 17 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1.9 U 1.9 U 1.9 U 19 U 1.9 U 9.4 U 9.5 U 94 U 6.9 J 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 0.85 J 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 11 9.4 U 9.5 U 94 U 0.87 J 9.4 U 9.5 U 94 U 1.3 J 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 0.87 J 9.4 U 9.5 U 94 U 5.3 J 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Day 1 Day 5 

5/9/2009 5/9/2009 5/15/2009 5/19/2009 

Cameron County, PA

Supply Water Day 0

Location I

9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1 J 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 5.5 19 U 6.1 1.9 U 1.9 U 19 U 0.82 J 1.9 U 1.9 U 19 U 1.9 U 1.9 U 1.9 U 19 U 1.9 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 9.5 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1.9 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1.9 U 1.9 U 1.9 U 19 U 1 J 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 

19 U 19 U 190 U 19 U 

9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 0.89 J 1.9 U 1.9 U 19 U 0.7 J 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 0.89 J 9.4 U 4.5 J 640 310 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 

NA NA NA NA 

0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 

0.48 U 0.47 U NA NA 

0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.095 U 0.094 U NA NA 

1.9 U 1.9 U NA NA 

0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Day 1 Day 5 

5/9/2009 5/9/2009 5/15/2009 5/19/2009 

Cameron County, PA

Supply Water Day 0

Location I

0.95 U 0.97 U NA NA 

10 UJ 20 UJ 10 UJ 10 UJ 10 UJ 20 UJ 10 UJ 10 UJ 10 UJ 20 UJ 10 UJ 10 UJ 10 UJ 130 J 52 J 59 J 10 UJ 20 UJ 10 UJ 10 UJ 

100 UJ 200 UJ 100 UJ 100 UJ 100 UJ 200 UJ 100 UJ 100 UJ 

1 U 50 UJ 10 UJ 10 UJ 1 U 50 UJ 10 UJ 10 UJ 1 U 50 UJ 10 UJ 10 UJ 

NA NA NA 57 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1

Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5U 5U 5U 5

0.01 U 0.01 U 0.01 NR U 0.01 

0.017 B J 5.6 J 13.2 36.9 

2 U 47.1 36.7 47.5 

0.14 B 36.6 39.1 233 

10 U 47400 397 4870 

42.3 2180 2460 26400 

3.2 J 168 J 207 J 30.7 

0.033 B 0.05 U 0.5 G U 1.2 

140 1300 1060 7800 

1.7 1.6 0.83 2.3 1.8 2 0.94 0.89 

0.05 U 0.05 U 0.39 B 1.2 

4.8 U 29.2 7.3 4.8 

380 J 9280 J 8740 J 90500 

43.7 27.7 17.4 J 17.6 

2.2 569 56.6 27.5 

71.4 J 191 J 107 J 187 

746 4840 5090 48700 

3 U 17.1 14.2 96.1 

0.044 B 0.072 B 0.14 0.088 

9.6 230 330 68.8 1.3 101 330 30.2 

10 U 4.6 B 15.2 10 

2.4 B 3 U 3 U 3 7.2 7.2 7.4 6.6 

0.01 J 0.027 0.03 0.01 10.0 20.4 13.2 6.00 

0.962 0.05 U 0.134 0.0761 

249 B J 400 B J 4030 J 111 

2000 U 2000 U 212 B 2000 

100 U 100 U 100 U 35.8 100 U 100 U 100 U 29.9 100 U 100 U 34.3 B 32.1 100 U 100 U 100 U 55.3 338 B 87100 121000 1210000 241 B J 84400 J 64400 J 1290000 

40 U 40 U 40 U 40 40 U 40 U 40 U 40 

29.8 B J 156 B J 1120 B J 3140 39.2 B 202 B 1180 B 3500 

50 U 50 U 2.5 B 50 50 U 50 U 50 U 50 

37500 B J 241000 J 305000 J 1790000 43200 B 293000 318000 1950000 

50 U 50 U 359 15.1 50 U 50 U 5.8 B 50 

500 U 500 U 500 U 500 500 U 500 U 500 U 500 250 U 250 U 41.3 B 250 250 U 250 U 250 U 250 273 B 3080 55200 39000 

1000 U 1510 14200 38200 

30 U 30 U 26.4 B 30 30 U 30 U 30 U 30 

33.8 B 2050 4060 37000 40.7 B 2590 3790 40000 

5160 B 21000 B 25900 B 154000 6160 B 25300 B 25900 B 167000 

145 B 395 1290 1100 129 B 430 1190 1200 400 U 400 U 372 B 400 400 U 400 U 185 B 14.9 400 U 400 U 203 B 400 400 U 400 U 24.1 B 400 

2850 B 11600 B 26700 B 48900 2260 B 13000 B 21600 B 53100 

50 U 50 U 50 U 50 50 U 50 U 50 U 50 50 U 50 U 50 U 50 50 U 50 U 50 U 50 

5/1/2009 5/4/2009 5/8/2009

Supply Water Day 5

5/1/2009

Day 0

Tioga County, PA

Day 1

Location J
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

5/1/2009 5/4/2009 5/8/2009

Supply Water Day 5

5/1/2009

Day 0

Tioga County, PA

Day 1

Location J

17800 B 884000 1090000 10700000 21300 B 1120000 1160000 11700000 

588 47900 56700 443000 685 J 58200 J 58600 J 477000 100 U 100 U 100 U 100 100 U 100 U 100 U 100 

1000 U 1000 U 1000 U 1000 1000 U 1000 U 1000 U 1000 

500 U 500 U 23.5 B 50.3 500 U 500 U 500 U 62.5 

50 U 50 U 209 50 

73.9 B J 76.8 B J 665 J 91 52.8 B 45.5 B 378 97.5 0.01 U 0.05 G U 0.086 0.5 0.01 U 0.05 G U 0.15 0.5 

0.2 U 0.056 B 0.2 U 0.043 0.2 U 0.051 B 0.2 U 0.2 

5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 2.6 J 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 

1000 U 1000 U 1000 U 1000 

NA NA NA NA 

5 U 5 U 5 U 5 5 U 5 U 5 U 5 

10 U 10 U 10 U 10 

5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 

20 U 10 J B 10 J B 22 

100 U 100 U 100 U 100 100 U 100 U 100 U 100 

5 U 5 U 5 U 0.99 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 7.8 5.8 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 3.7 J 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

5/1/2009 5/4/2009 5/8/2009

Supply Water Day 5

5/1/2009

Day 0

Tioga County, PA

Day 1

Location J

NA NA NA NA 

5 U 5 U 5 U 5 5 U 5 U 5 U 5 

NA NA NA NA 

5 U 1.3 J 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 

15 U 2.6 J 15 U 15 

9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

NA NA NA NA 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 25 9.4 

49 U 1000 U 48 U 47 

9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 

2 U 40 U 0.82 J 1.9 

9.8 U 200 U 7.3 J 9.4 9.8 U 200 U 9.6 U 9.4 

49 U 1000 U 48 U 47 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 4.5 J 9.4 

49 U 1000 U 48 U 47 49 U 1000 U 48 U 47 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

49 U 1000 U 48 U 47 49 U 1000 U 48 U 47 98 U 2000 U 96 U 94 

9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 

9.8 U 200 U 13 1.1 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

200 U 4000 U 190 U 190 

2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 4300 18 17 2 U 40 U 1.9 U 1.9 

9.8 U 200 U 1.2 J 1.6 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 1.6 J 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 0.3 J 5.3 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

5/1/2009 5/4/2009 5/8/2009

Supply Water Day 5

5/1/2009

Day 0

Tioga County, PA

Day 1

Location J

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

20 U 400 U 19 U 19 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 0.76 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 3.2 J 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

NA NA NA NA 

0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.038 J PG NA NA 

0.048 U 0.049 U NA NA 

0.48 U 0.49 U NA NA 

0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.096 U 0.098 U NA NA 

1.9 U 2 U NA NA 

0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

5/1/2009 5/4/2009 5/8/2009

Supply Water Day 5

5/1/2009

Day 0

Tioga County, PA

Day 1

Location J

0.95 U 1 U NA NA 

10 UJ NA 10 UJ 13 10 UJ NA 10 UJ 10 10 UJ NA 10 UJ 10 10 UJ NA 10 UJ 10 10 UJ NA 10 UJ 10 

100 UJ NA 100 UJ 100 100 UJ NA 100 UJ 100 

0.15 U NA 0.15 U 10 0.16 U NA 0.16 U 10 0.17 U NA 0.17 U 10 

NA NA NA NA 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

66.7 5 U 5 U 0.01 NR U 0.01 NR U 0.01 U 0

14 16.8 J 29.4 J 

430 650 214 3

18.9 117 185 1

1260 855 1720 2

82 10200 34000 J 16

301 J 197 158 

0.05 U 0.38 1.2 G U 0

104 2100 5100 6

1.6 2.4 1.2 G U 0

0.37 0.32 0.2 0

0.056 1.1 4.8 

4.9 U 4.8 U 4.9 U 

507 J 35700 J 79500 J 68

21.5 J 21.6 J 6.6 B J 0

949 J 124 103 116 J 311 J 245 J 9804 18600 39400 30

47.2 25.2 38 

0.097 B 0.14 0.12 0

26 172 61 5

249 63.8 140 5320 16.7 7.4 B J 

1.6 B 1.6 B 1.6 B 6.3 7.4 6.9 

0.011 0.01 U 0.052 0.00

10.4 8.8 5 U 0.05 U 0.575 0.012 0.07

311 B 420 B J 2000 U 39

2000 U 166 B 205 B 20

16.7 B 34.9 B 33.7 B 1

100 U 36.5 B 21.7 B 1100 U 32.3 B 28.8 B 7100 U 100 U 32.6 B 1

1220 B 251000 893000 10501360 B J 224000 1010000 1020

40 U 40 U 40 U 40 U 40 U 40 U 

71.4 B J 2850 3550 476.4 B J 2590 4170 3

50 U 50 U 50 U 50 U 50 U 50 U 

26600 B J 577000 J 1440000 J 173022900 B J 493000 1590000 2040

50 U 48.1 B 14.6 B 550 U 50 U 6.6 B 

500 U 500 U 500 U 1500 U 500 U 500 U 5250 U 250 U 250 U 4250 U 250 U 250 U 2745 B 18000 33600 1660567 B 11700 34400 268

30 U 70.9 30 U 1

21.2 B 35.7 30 U 

42 B 23600 41800 34

56.3 B 20200 47800 40

4320 B 52000 135000 1853760 B 44800 B 150000 219

33.2 B 519 881 2127.5 B 440 1020 12

400 U 54.4 B 33.1 B 1400 U 42.7 B 34 B 4400 U 176 B 400 U 7400 U 33.4 B 400 U 6

2750 B 35800 B 54600 822790 B 31900 B 64000 81

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

Bradford County, PA

05/07/2009 5/20/2009

Day 0 Day 5 Day 1

5/22/2009

Day 14

6/2/200

Location K
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Bradford County, PA

05/07/2009 5/20/2009

Day 0 Day 5 Day 1

5/22/2009

Day 14

6/2/200

Location K

67800 6630000 11700000 922080700 5830000 J 13200000 J 11000

1310 117000 357000 390

899 J E 99700 J 390000 J 461100 U 100 U 100 U 1100 U 100 U 100 U 1

1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 10

22.3 B J 38.5 B 23.9 B 121.2 B J 39.4 B 39.2 B 5

50 U 50 U 50 U 

99.7 B J 198 B J 147 B J 576.1 B J 109 B J 172 B J 7

0.5 G U 0.1 G U 0.17 B 00.5 G U 0.1 G U 0.17 B 0.0

0.052 B J 0.2 U 0.2 U 

0.46 B J 0.2 U 0.2 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

42 14 7.7 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

20 7.7 5.3 

5U 5U 5U 5U 5U 5U 5U 5U 5U 

1000 U 1000 U 1000 U 10

NA NA NA 

5U 5U 5U 5U 5U 5U 

10 U 10 U 10 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 

6.7 J B 5.9 J 6.9 J 

100 U 100 U 100 U 1100 U 100 U 100 U 1

5 U 5 U 5 U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

1.7 J 5 U 5 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 

3.9 J 5 U 5 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 5 U 5 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Bradford County, PA

05/07/2009 5/20/2009

Day 0 Day 5 Day 1

5/22/2009

Day 14

6/2/200

Location K

NA NA NA 

5U 5U 5U 5U 5U 5U 

NA NA NA 

5 U 5 U 5 U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

35 4.8 J 3 J 

9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

NA NA NA 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

50 U 48 U 47 U 

9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

50 U 48 U 47 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 0

50 U 48 U 47 U 50 U 48 U 47 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

50 U 48 U 47 U 50 U 48 U 47 U 99 U 95 U 94 U 1

9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

200 U 190 U 190 U 2

1.1 J 1.9 U 1.9 U 6.9 1.9 U 1.9 U 

11 1.9 U 1.9 U 

7.4 1.9 U 1.9 U 6.7 1.9 U 1.9 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 

15 B 1.8 J 9.4 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 1.7 J 1.9 U 1.9 U 9.9 U 9.5 U 9.4 U 

12 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 09.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 5 J 9.4 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Bradford County, PA

05/07/2009 5/20/2009

Day 0 Day 5 Day 1

5/22/2009

Day 14

6/2/200

Location K

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

10 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

20 U 19 U 19 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 19.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

NA NA NA 

0.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.0

0.49 U NA NA 0

0.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.049 U NA NA 0.00.098 U NA NA 0.0

2U NA NA 

0.39 U NA NA 00.39 U NA NA 00.39 U NA NA 00.39 U NA NA 00.39 U NA NA 00.39 U NA NA 00.39 U NA NA 0
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Bradford County, PA

05/07/2009 5/20/2009

Day 0 Day 5 Day 1

5/22/2009

Day 14

6/2/200

Location K

0.95 U NA NA 0

10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 

100 UJ 100 UJ 100 UJ 1220 J 130 J 100 UJ 1

50 UJ 42 J 39 J 50 UJ 20 UJ 10 UJ 50 UJ 20 UJ 10 UJ 

2300 170 400 1
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1

Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5.5 5 U 5 U 5 U 

0.27 0.87 0.14 0.032 

3.9 2.9 31.6 71.2 

2 U 2 U 27.6 37.1 

30.6 9.2 162 413 

594 511 1010 4250 101 115 9580 35100 J 222 J 361 J 313 117 

0.05 U 0.05 U 0.5 G U 1.2 G 

124 114 2200 12600 

0.59 0.91 1.7 1.2 G 0.61 1 0.74 0.54 

0.3 0.34 0.5 G U 1.2 G 4.6 U 20 U 5.2 U 8.4 U 

519 J 599 J 33800 J 118000 J 

48.3 J 40 J 58.9 J 51.4 J 

202 J 155 J 115 80.5 

33.6 J 62 J 186 J 109 J 

390 221 20400 72700 

17.9 24 46.4 67.6 

0.088 B 0.063 B 0.1 U 1 G 

14 B 4 U 71 23.2 

9.1 2.7 16.2 20.9 

625 954 177 46.1 

3 U 3 U 3 U 2.4 B 

6.8 7.8 7.8 6.7 

0.011 0.01 0.022 0.026 

10.8 NA 9.60 12.4 

0.317 NA 0.301 0.234 

2000 U 2000 U 290 B J 350 B 2000 U 2000 U 223 B J 310 B 

100 U 100 U 17.9 B 100 U 100 U 21.1 B 19.8 B 100 U 100 U 100 U 100 U 40.7 B 100 U 100 U 100 U 100 U 243 B 108 B 7110 34700 222 B J 91.2 B J 6520 J 60700 J 

40 U 40 U 40 U 40 U 40 U 40 U 40 U 40 U 

47.9 B J 43.3 B J 7290 J 14100 J 54.1 B J 54.5 B J 6690 14400 

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

32000 B J 31500 B J 833000 3890000 33900 B J 33800 B J 757000 3970000 

50 U 50 U 10.4 B 10.5 B 50 U 50 U 50 U 50 U 

500 U 500 U 4.5 B 500 U 500 U 500 U 500 U 500 U 250 U 250 U 57.2 B 250 U 250 U 250 U 47.2 B 250 U 

1810 137 B 5570 21500 

968 B 1000 U 4950 20200 

30 U 30 U 26.1 B 51.1 30 U 30 U 30 U 30 U 

500 U 500 U 17400 49700 500 U 500 U 15900 52100 

6530 B 6740 B 89000 424000 7090 B 7170 B 81300 440000 

29.3 B 7.5 B 682 2110 27.8 B 150 U 608 2160 

400 U 400 U 151 B 47.2 B 400 U 400 U 135 B 48.6 B 400 U 400 U 41.7 B 400 U 400 U 400 U 32.7 B 400 U 

2360 B 2250 B 126000 308000 3250 B 4220 B 118000 322000 

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

Supply Water Day 1 Day 5

Butler County, PA

5/12/2009 5/14/2009 5/18/2009 

Day 0 

Location L
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Supply Water Day 1 Day 5

Butler County, PA

5/12/2009 5/14/2009 5/18/2009 

Day 0 

Location L

46900 B 64800 6290000 17900000 49400 B 72000 5630000 18600000 

634 206 B 169000 J 738000 J 580 J 158 B J 151000 J 763000 J 100 U 100 U 100 U 100 U 100 U 100 U 100 U 26.9 B 

1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 

500 U 19.4 B J 500 U 53.7 B 

26.9 B J 500 U 500 U 42.8 B 

50 U 50 U 50 U 50 U 

35.8 B J 34.8 B J 95.6 B 172 B 75.9 B J 138 B J 79.5 B 147 B 0.25 G U 0.25 G U 0.01 U 0.25 U 0.25 G U 0.25 U 0.01 U 0.25 U 

0.054 B J 0.05 B J 0.2 U 0.2 U 

0.53 B J 0.57 B J 0.2 U 0.2 U 

5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 

27 5 U 0.81 J 38 

5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 

14 5 U 0.78 J 32 

5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 

1000 U 1000 U 1000 U 2000 U 

NA NA NA NA 

5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 

10 U 10 U 10 U 20 U 

5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 

9.8 J 20 U 6 J 17 J 

100 U 100 U 100 U 200 U 100 U 100 U 100 U 200 U 

5 U 5 U 39 99 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 

50 9.3 5 U 10 U 

5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 

1.3 J 5 U 5 U 10 U 

5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 

0.65 J 5 U 1.3 J 17 

5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 

4.6 J 3.8 J 5 U 10 U 

5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Supply Water Day 1 Day 5

Butler County, PA

5/12/2009 5/14/2009 5/18/2009 

Day 0 

Location L

NA NA NA NA 

5 U 5 U 5 U 10 U 

2.2 J 5 U 5 U 10 U 

NA NA NA NA 

5 U 5 U 46 260 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 5 U 5 U 5 U 10 U 2 J 15 U 15 220 

12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 

12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 0.81 J 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 

NA NA NA NA 

12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 1.5 J 9.4 U 58 U 48 U 48 U 47 U 12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 

12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 

12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 

12 U 9.7 U 2.7 J 4 J 12 U 9.7 U 9.6 U 9.4 U 58 U 48 U 48 U 47 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 3 J 5.2 J 58 U 48 U 48 U 47 U 58 U 48 U 48 U 47 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 58 U 48 U 48 U 47 U 58 U 48 U 48 U 47 U 

120 U 97 U 96 U 94 U 

12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 2.3 U 1.9 U 1.9 U 1.9 U 

12 U 1.2 J 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 

230 U 190 U 190 U 190 U 

2.3 U 1.9 U 1.9 U 1.9 U 2.3 U 1.9 U 1.9 U 1.9 U 2.3 U 1.9 U 1.9 U 1.9 U 2.3 U 1.9 U 1.9 U 1.9 U 2.3 U 1.9 U 1.9 U 1.9 U 

12 U 16 9.6 U 7.1 J 12 U 9.7 U 9.6 U 9.4 U 

6.7 1.9 U 1.9 U 1.9 U 2.3 U 1.9 U 1.9 U 1.9 U 

12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 

12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 

12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 3 J 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 

6.3 J 5.5 J 9.6 U 9.4 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Supply Water Day 1 Day 5

Butler County, PA

5/12/2009 5/14/2009 5/18/2009 

Day 0 

Location L

12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 

12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 2.3 U 1.9 U 1.9 U 1.9 U 2.3 U 1.9 U 1.9 U 1.9 U 2.3 U 1.9 U 1.9 U 1.9 U 

12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 

12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 

12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 2.3 U 1.9 U 1.9 U 1.9 U 

12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 23 U 19 U 19 U 19 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 2.3 U 1.9 U 5.5 10 

12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 

2.3 U 1.9 U 1.9 U 1.9 U 

12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 12 U 9.7 U 9.6 U 9.4 U 

NA NA NA NA 

0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 

0.47 U 0.48 U NA NA 

0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.094 U 0.096 U NA NA 

1.9 U 1.9 U NA NA 

0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Supply Water Day 1 Day 5

Butler County, PA

5/12/2009 5/14/2009 5/18/2009 

Day 0 

Location L

0.99 U 0.98 U NA NA 

10 UJ NA 10 UJ 10 UJ 10 UJ NA 10 UJ 10 UJ 10 UJ NA 10 UJ 10 UJ 10 UJ NA 10 UJ 10 UJ 10 UJ NA 10 UJ 10 UJ 

100 UJ NA 100 UJ 100 UJ 100 UJ NA 100 UJ 100 UJ 

1.5 UJ NA 7.5 UJ 7.5 UJ 1.6 UJ NA 8 UJ 8 UJ 1.7 UJ NA 8.5 UJ 8.5 UJ 

NA NA NA NA 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 11.4 NA NA 2

0.01 U 0.0097 B 0.01 U 0.01 U 00.25 J 1.5 J 173 192 2

2 U 137 36.3 103 12 G U 10 G U NA NA 11

10 U 490 10700 7600 91

4.1 B 29.9 B NA NA 15101.4 84.3 77 33.1 

0.05 U 0.009 B 2.5 G U 2.5 G U 

18 26 NA NA 950

0.24 B 2.5 U 2.5 G U 2.5 G U 0.24 0.24 0.01 B 0.049 B J 00.21 B 2.5 G U NA 25.9 5

4.6 U 33.2 NA NA 

54.8 J 177 J NA NA 7100

3.8 B 2.9 B 50 G U 50 G U 1.8 86.6 2.2 3.7 6.2 J 9.6 J NA NA 2

51 371 NA NA 2280

2.2 B 31.3 158 178 10.1 U 0.096 B 1.4 0.1 U 

4 U 110 NA NA 4

4.3 254 NA NA 6

10 U 12.5 10 U 10 U 

1.6 B 3 U 3 U 3 U 7.1 6.2 5.9 7.2 

0.01 U 0.0069 B 0.007 B 0.29 0.0

6 12 24.4 11.6 1

0.05 U 0.05 0.241 0.291 0.1

122 B J 180 B J 165 B 131 B 1160 B 239 B 289 B J 188 B J 2

14.6 B 100 U 13.9 B 17.3 B 1

100 U 100 U 16.9 B 20.9 B 1100 U 100 U 100 U 100 U 1100 U 100 U 100 U 100 U 1271 B 579 B 1450000 1730000 19700274 B 621 B 1430000 1760000 19900

40 U 40 U 40 U 40 U 40 U 40 U 40 U 40 U 

2000 U 2000 U 12000 10500 1002000 U 2000 U 11800 11000 97

50 U 50 U 50 U 50 U 50 U 50 U 50 U 1.5 B 

4880 B J 6690 B J 19700000 J 23500000 J 2640003690 B 6080 B 19700000 J 23800000 J 262000

50 U 50 U 15.7 B 50 U 50 U 50 U 50 U 50 U 

500 U 500 U 5000 U 5000 U 50500 U 500 U 5000 U 5000 U 50250 U 44.5 B 255 78.9 B 2250 U 250 U 81.1 B 57.7 B 2605 B 497 B 67200 53100 610543 B 460 B 37600 44800 533

30 U 30 U 30 U 30 U 30 U 30 U 30 U 30 U 

500 U 500 U 129000 137000 1550500 U 28.1 B 126000 J 154000 J 1580

1080 B 1250 B 1320000 1550000 180001440 B 1460 B 1310000 1600000 17400

134 B 127 B 5960 7040 85127 B 130 B 5850 7170 84400 U 400 U 48.2 B 400 U 4400 U 400 U 34.7 B J 400 U 4400 U 19.5 B 400 U 400 U 4400 U 400 U 400 U 400 U 4

50000 U 50000 U 923000 849000 972050000 U 50000 U 1000000 1010000 10100

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

McKean County, PA

Day 5

5/19/2009 6/19

6/6/2009 6/10/2009

Supply Water

5/19/2009

Day 0 Day 1 Da

Location M
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

McKean County, PA

Day 5

5/19/2009 6/19

6/6/2009 6/10/2009

Supply Water

5/19/2009

Day 0 Day 1 Da

Location M

4200 B 32600 B 20600000 17200000 2320003600 B J 34200 B J 31500000 31300000 304000

352 B 768 4330000 4830000 55700340 B J 816 J 4280000 J 4920000 J 53500100 U 100 U 27.2 B 100 U 1100 U 100 U 100 U 100 U 1

1000 U 1000 U 1000 U 1000 U 101000 U 1000 U 1000 U 1000 U 10

500 U 500 U 500 U 500 U 5500 U 29.8 B 500 U 500 U 5

50 U 50 U 50 U 50 U 

56.7 B J 50.2 B J 391 J 270 J 241.1 B J 40.6 B J 314 J 240 J 10.01 U 0.01 G U 0.5 G U 0.5 G U 0.01 U 0.05 G U 0.5 G U 0.5 G U 

0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 5 U 1.6 J 4 J 05U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 5 U 1.2 J 3.3 J 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

1000 U 1000 U 1000 U 1000 U 10

NA NA NA NA 

5U 5U 5U 5U 5 U 3.6 J 5 U 5 U 

10 U 10 U 10 U 10 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

20 U 20 U 21 18 J 

100 U 100 U 100 U 100 U 1100 U 100 U 100 U 100 U 1

5 U 5 U 3.5 J 3.2 J 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 5 U 5 U 0.63 J 5 U 5 U 5 U 0.53 J 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

McKean County, PA

Day 5

5/19/2009 6/19

6/6/2009 6/10/2009

Supply Water

5/19/2009

Day 0 Day 1 Da

Location M

NA NA NA NA 

5U 5U 5U 5U 5U 5U 5U 5U 

NA NA NA NA 

5 U 5 U 3.8 J 4.8 J 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

15 U 15 U 3.2 J 6 J 

9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 

NA NA NA NA 

9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 

48 U 50 U 48 U 47 U 

9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 0.28 J 0.26 J 9.6 U 10 U 9.5 U 9.4 U 

48 U 50 U 48 U 47 U 

9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 0.69 J 

48 U 50 U 48 U 47 U 48 U 50 U 48 U 47 U 

9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 

48 U 50 U 48 U 47 U 48 U 50 U 48 U 47 U 96 U 100 U 95 U 94 U 

9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 0.8 J 9.6 U 10 U 2.2 J 2.1 J 9.6 U 10 U 9.5 U 9.4 U 

190 U 200 U 190 U 190 U 1

1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 

6 J 10 U 2.8 J 9.4 U 

9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 2.4 J B 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 1.3 J 9.4 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

McKean County, PA

Day 5

5/19/2009 6/19

6/6/2009 6/10/2009

Supply Water

5/19/2009

Day 0 Day 1 Da

Location M

9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 2.2 J 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 

19 U 20 U 19 U 19 U 

9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 2.6 J 2 J 140 100 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 

NA NA NA NA 

0.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.0

0.48 U 0.49 U NA NA 0

0.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.05 NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.0

0.8 PG 0.84 PG NA NA 0.0

0.048 U 0.049 U NA NA 0.00.095 U 0.098 U NA NA 0.0

1.9 U 2 U NA NA 

0.38 U 0.39 U NA NA 00.38 U 0.39 U NA NA 00.38 U 0.39 U NA NA 00.38 U 0.39 U NA NA 00.38 U 0.39 U NA NA 00.38 U 0.39 U NA NA 00.38 U 0.39 U NA NA 0
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

McKean County, PA

Day 5

5/19/2009 6/19

6/6/2009 6/10/2009

Supply Water

5/19/2009

Day 0 Day 1 Da

Location M

0.95 U 0.97 U NA NA 

10 UJ 20 UJ 10 UJ 10 UJ 10 UJ 20 UJ 10 UJ 10 UJ 10 UJ 20 UJ 10 UJ 10 UJ 10 UJ 20 UJ 23 J 21 J 10 UJ 20 UJ 10 UJ 10 UJ 

100 UJ 200 UJ 100 UJ 100 UJ 1100 UJ 200 UJ 100 UJ 100 UJ 1

1 U 100 UJ 10 UJ 500 UJ 1 U 100 UJ 10 UJ 500 UJ 1 U 100 UJ 10 UJ 500 UJ 

57 2300 1100 1200 520
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5U 5U 5U 

0.08 0.01 U 0.01 U 0

0.3 J 83.3 J 83.6 J 1

2 U 166 73.2 7

0.2 U 0.9 165 6

11.6 J 734 J 1760 J 32

8.3 132 17500 6722.5 218 20.2 

0.05 U 0.05 U 0.5 G U 

26 50 5100 300

0.17 0.12 0.5 G U 0.14 0.23 0.45 00.05 U 0.22 4.7 1

4.6 U 4.6 U 4.8 U 

91.6 J 1350 J 73600 J 2730

6.9 J 165 J 110 J 

3 J 208 J 28.1 J 3

16.2 J 154 J 254 J 1

35 735 31800 1160

3 U 142 101 1

0.1 U 15.4 4.1 0

2 B 14.4 112 1

2.9 8.8 50.4 3

85.9 5.4 B 10 U 

3U 3U 3U 

7.4 8.2 7.4 

0.01 U 0.01 U 0.014 0.0

NA 6.80 6.80 1NA 0.0809 0.0969 0.06

2000 U 2000 U 2000 U 32000 U 2000 U 2000 U 2

14.2 B J 21.6 B J 34.9 B J 117.2 B J 100 U 41.5 B J 1

100 U 100 U 46 B 1100 U 100 U 48.8 B 1309 B J 1420 B J 271000 J 35300290 B 3400 272000 31700

40 U 40 U 40 U 40 U 40 U 40 U 

36.4 B J 40700 J 6680 J 8328.2 B J 44700 J 6540 J 77

50 U 50 U 50 U 50 U 50 U 50 U 

7450 B 15600 B 1400000 852006730 B 16100 B 1340000 79300

50 U 50 U 36.8 B 450 U 50 U 29.4 B 2

500 U 500 U 500 U 50500 U 500 U 500 U 50250 U 71.3 B 57.1 B 6250 U 87.2 B 36.6 B 2

1000 U 834 B 13900 4691000 U 688 B 10900 64

30 U 30 U 55.2 230 U 30 U 48.8 

500 U 180 B J 26000 J 1060500 U 196 B 24600 972

1100 B 1740 B 112000 67801070 B 1790 B 108000 6290

26.9 B 18.3 B 725 25

150 U 17 B 683 23400 U 400 U 36.6 B 1400 U 400 U 34.3 B 4400 U 400 U 42.9 B 1400 U 400 U 35 B 4

2660 B 48300 B 115000 3390

50000 U 50700 110000 3040

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

Day 1

07/14/09 7/15/2009 7/19/200

Supply Water Day 0 Day 5

Potter County, PA

07/14/09

Location N
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 1

07/14/09 7/15/2009 7/19/200

Supply Water Day 0 Day 5

Potter County, PA

07/14/09

Location N

8930 B J 74400 J 8210000 J 3110008100 B 80000 7800000 290000

204 B J 3020 J 388000 J 29800187 B J 3150 J 368000 J 26900100 U 100 U 100 U 1100 U 100 U 28.3 B 1

1000 U 1000 U 1000 U 101000 U 1000 U 1000 U 10

500 U 500 U 37.8 B 5500 U 500 U 23.4 B 5

50 U 50 U 29.3 B 4

54.6 B J 75.5 B J 617 J 227.2 B J 80.7 B J 538 J 20.01 U 0.01 U 0.5 U 0.01 U 0.0062 B 0.37 B 

0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 

5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 4.2 J 25 U 05 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 3.4 J 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 

1000 U 5000 U 5000 U 10

NA NA NA 

5 U 25 U 25 U 5 U 25 U 25 U 

10 U 50 U 50 U 

5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 0

20 U 170 90 J 2

100 U 500 U 500 U 1100 U 500 U 500 U 1

5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 5.5 J 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 1

07/14/09 7/15/2009 7/19/200

Supply Water Day 0 Day 5

Potter County, PA

07/14/09

Location N

NA NA NA 

5 U 25 U 25 U 5 U 25 U 25 U 

NA NA NA 

5 U 25 U 25 U 05 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 5 U 25 U 25 U 

15 U 25 J 75 U 

9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 

NA NA NA 

9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 0.39 J 9.4 U 

48 U 48 U 47 U 

9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 2.5 09.5 U 9.5 U 0.2 J 9.5 U 9.5 U 9.4 U 

48 U 48 U 47 U 

9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 0.33 J 

48 U 48 U 47 U 48 U 48 U 47 U 

9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 

48 U 48 U 47 U 48 U 48 U 47 U 95 U 95 U 94 U 

9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 0.29 J 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 0.82 J 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 

190 U 190 U 190 U 1

1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.7 9.1 J 6.5 J 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 1.2 J 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 0.29 J 0.54 J 0
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Day 1

07/14/09 7/15/2009 7/19/200

Supply Water Day 0 Day 5

Potter County, PA

07/14/09

Location N

9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 0.45 J 0.01.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 

19 U 19 U 19 U 

9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 0.89 J 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 1.9 U 1.9 U 0.18 J 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 9.5 U 9.5 U 9.4 U 

NA NA NA 

0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.048 U 0.048 U NA 

0.48 U 0.48 U NA 

0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.048 U 0.048 U NA 0.095 U 0.095 U NA 

1.9 U 1.9 U NA 

0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Day 1

07/14/09 7/15/2009 7/19/200

Supply Water Day 0 Day 5

Potter County, PA

07/14/09

Location N

0.95 U 0.95 U NA 

NA 10 UJ 10 UJ NA 10 UJ 10 UJ NA 10 UJ 10 UJ NA 10 UJ 10 UJ NA 10 UJ 10 UJ 

NA 500 UJ 100 UJ 1NA 500 UJ 100 UJ 1

NA 15 22 J NA 1 U 2 UJ NA 1 U 2 UJ NA 20 200 3
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 48.7 

0.01 U 0.01 NR U 0.01 U 

10 52 135 

924 606 1520 

20 G U 69.8 885 J 

2420 1480 7390 1060 7860 86800 

558 J 271 240 

5 G U 2.5 G U 2.5 G U 

570 25000 36000 

5 G U 2.5 G U 2.5 G U 

0.1 0.18 0.1 U 

5 G U 6.7 19.9 J 

255 4.6 U 40.7 

4000 J 30700 J 261000 J 

100 G U 50 G U 50 G U 575 J 308 237 

66.1 J 114 J 94.2 J 

2670 17400 125000 

89.9 88.8 147 

0.5 21.8 2.3 

5290 4 U 302 

505 152 54.6 

10 U 21.5 5.2 B 

3 U 3 U 3.2 

7.2 6.5 6.5 

0.77 J 0.036 J 0.15 J 47.2 26.8 16.8 0.05 U 0.198 0.0897 

1030 B 1120 B 536 B 

162 B J 274 B 172 B J 100 U 15.8 B 100 U 100 U 15 B 100 U 100 U 48 B 100 U 100 U 28 B 100 U 

72200 387000 13900000 62300 447000 12700000 

40 U 40 U 40 U 40 U 40 U 40 U 

1190 B 808 B 3570 1310 B 944 B 3200 

50 U 50 U 50 U 50 U 50 U 50 U 

123000 J 676000 J 9250000 J 120000 J 800000 J 8200000 J 

17.3 B 37.5 B 33.4 B 

50 U 12.9 B 27.7 B 

500 U 500 U 25000 U 500 U 500 U 25000 U 

79.4 B 250 U 250 U 34.1 B 250 U 250 U 

7400 20900 J 43500 

954 B 18000 38400 

19.4 B 30 U 30 U 

30 U 30 U 30 U 

1800 14200 132000 1930 17300 125000 

14700 B 65700 691000 14800 B 76400 610000 

288 760 J 5550 196 823 4960 

50.6 B J 25.9 B 400 U 58.4 B 24.1 B 400 U 

400 U 48.3 B 400 U 400 U 39.5 B 400 U 

7840 B 33500 B 353000 6850 B 39900 B 284000 

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

Day 0

7/1/2009 7/1/2009

Day 1

Susquehanna County

Day 5 

7/6/2009 0

Location O
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 0

7/1/2009 7/1/2009

Day 1

Susquehanna County

Day 5 

7/6/2009 0

Location O

589000 3920000 34100000 658000 4670000 30900000 

27000 J E 196000 J 2960000 J 28200 J E 233000 J 2660000 J 

100 U 100 U 100 U 

29.5 B 100 U 38 B 

1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 

500 U 33.8 B 500 U 500 U 48.6 B 500 U 

50 U 50 U 33.4 B 

1610 E 244 211 

924 287 J 183 B 

0.1 U 0.1 U 2 G U 

0.05 U 0.1 U 2 G U 

0.2 U 0.2 U 0.2 U 

0.17 B 0.2 U 0.2 U 

50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 67 59 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 

7.7 J 6.7 J 5 U 

50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 

10000 U 5000 U 1000 U 

NA NA NA 

50 U 25 U 5 U 50 U 17 J 5 U 

100 U 50 U 10 U 

50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 

130 J 69 J 20 U 

1000 U 500 U 100 U 1000 U 500 U 100 U 

50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 

820 720 0.5 J 

50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 0

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Day 1

Susquehanna County

Day 5 

7/6/2009 0

Location O

NA NA NA 

50 U 25 U 5 U 50 U 25 U 5 U 

NA NA NA 

19 J 25 U 0.94 J 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 46 J 26 J 15 U 

190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

NA NA NA 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 940 U 470 U 49 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 260 52 2 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 940 U 470 U 49 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 940 U 470 U 49 U 940 U 470 U 49 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 940 U 470 U 49 U 940 U 470 U 49 U 

1900 U 940 U 98 U 

190 U 94 U 9.8 U 

38 U 19 U 2 U 38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

3800 U 1900 U 200 U 

38 U 19 U 2 U 38 U 19 U 2 U 38 U 19 U 2 U 38 U 19 U 2 U 38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 38 U 19 U 2 U 

190 U 94 U 2.5 J 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Day 0

7/1/2009 7/1/2009

Day 1

Susquehanna County

Day 5 

7/6/2009 0

Location O

190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 38 U 19 U 2 U 38 U 19 U 2 U 38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 380 U 190 U 20 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 38 U 3.5 J 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 1.1 J 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

NA NA NA 

0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 

0.11 PG NA NA 

0.051 U NA NA 0.051 U NA NA 

0.51 U NA NA 

0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.065 PG NA NA 0.051 U NA NA 

0.1 U NA NA 

2U NA NA 

0.41 U NA NA 0.41 U NA NA 0.41 U NA NA 0.41 U NA NA 0.41 U NA NA 0.41 U NA NA 0.41 U NA NA 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Day 0

7/1/2009 7/1/2009

Day 1

Susquehanna County

Day 5 

7/6/2009 0

Location O

1 U NA NA 

20 UJ 10 UJ 10 UJ 20 UJ 10 UJ 10 UJ 

120 J 230 J 110 J 

20 UJ 10 UJ 10 UJ 20 UJ 10 UJ 10 UJ 

200 UJ 200 UJ 100 UJ 200 UJ 200 UJ 100 UJ 

50 UJ 1 U 1 U 50 UJ 1 U 1 U 50 UJ 1 U 1 U 

200 200 300 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1

Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 28.8 

0.01 U 0.01 U 0.01 U 0.00.28 J 17.4 J 107 J 7

4.2 391 1260 750.2 U 60 477 48

35.3 J 1180 J 4820 317

152 J 6450 43900 4560

5 302 240 23

0.27 1.3 1.2 G U 1

194 2200 24000 2100

0.52 0.75 1.2 G U 10.47 0.56 0.46 0.80.11 2.9 11.8 9

5 U 4.9 U 57.7 

726 J 24600 J 160000 J 17500

73.7 J 65.6 J 53.1 J 48

5.6 J 292 J 287 22

38.6 J 255 J 93.2 J 12

401 11600 78600 6390

2.3 B 61.6 92.9 420.1 U 0.17 0.11 0.1

10 18 10.8 79

3.4 15.7 486 70

10 U 9.8 B 10 U 1

3U 3U 3U 

7.3 7.6 6.3 6

0.01 U 0.027 0.037 0.0

10 8.40 2.5 U 7.2

0.05 U 0.178 0.0777 0.12

2000 U 2000 U 378 B J 522000 U 227 B 435 B J 30

100 U 25.3 B J 100 U 14100 U 19.3 B J 15.2 B 10100 U 100 U 100 U 10100 U 100 U 100 U 10173 B J 2590 J 28900 4390187 B 2690 41000 7200

40 U 40 U 40 U 440 U 40 U 40 U 4

80.8 B J 6510 J 21000 206090.2 B J 7200 J 22900 2110

50 U 50 U 50 U 550 U 50 U 50 U 1

63200 616000 6160000 J 57000069900 655000 6450000 J 578000

50 U 33.2 B 44.2 B 9850 U 26.4 B 45 B 75

500 U 500 U 500 U 50500 U 5.3 B 500 U 50250 U 250 U 250 U 25

32.1 B 250 U 250 U 25

1000 U 5240 28800 67301000 U 5120 30300 2160

30 U 30 U 30 U 330 U 30 U 30 U 3

500 U 7900 J 40200 5650500 U 8300 43000 J 5740

9410 B 65500 658000 61300

10400 B 70100 715000 63200

23.7 B 369 1300 22415.4 B 397 1390 224

400 U 72.4 B 44.4 B J 87400 U 75.4 B 47 B 93

21.1 B 28.6 B 400 U 2516.6 B 30.8 B 400 U 40

4590 B 99500 656000 E 614004010 B 105000 723000 E 62800

50 U 50 U 50 U 550 U 50 U 50 U 550 U 50 U 50 U 550 U 50 U 50 U 5

Day 1 Day 5 Day 14

7/15/2009 7/20/2009

7/14/2009 

Day 0

Butler County, PA 

7/29/2009

Location P
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 1 Day 5 Day 14

7/15/2009 7/20/2009

7/14/2009 

Day 0

Butler County, PA 

7/29/2009

Location P

56700 J 3040000 J 18000000 211000062000 3230000 18700000 2100000

417 B J 93100 J 1240000 J E 121000464 B J 98300 J 1320000 J E 124000100 U 100 U 100 U 33100 U 100 U 23.6 B 4

1000 U 1000 U 1000 U 1001000 U 1000 U 1000 U 21

500 U 500 U 500 U 50500 U 500 U 500 U 50

50 U 26.4 B 44.2 B 98

72.3 B J 184 B J 150 B J 9045.3 B J 154 B J 245 J 100.01 U 0.01 U 0.25 G U 00.01 U 0.0068 B 0.25 G U 0

0.2 U 0.2 U 0.2 U 00.2 U 0.2 U 0.2 U 0

5 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 50

0.79 J 1.4 J 840 71

5 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 940 775 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 50

1000 U 2000 U 100000 U 10000

NA NA NA N

5 U 10 U 500 U 505 U 10 U 500 U 50

10 U 20 U 1000 U 100

5 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 50

12 J 320 5200 200

100 U 200 U 10000 U 1000100 U 200 U 10000 U 1000

5 U 140 2000 1105 U 10 U 500 U 505 U 10 U 500 U 50

2.2 J 10 U 500 U 50

5 U 10 U 500 U 505 U 10 U 500 U 235 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 50

2.4 J 10 U 500 U 50

5 U 5.9 J 500 U 505 U 10 U 500 U 505 U 10 U 500 U 50

2.1 J 10 U 500 U 50

5 U 10 U 500 U 505 U 10 U 500 U 505 U 2.5 J 650 475 U 10 U 160 J 125 U 10 U 500 U 505 U 10 U 500 U 50

0.55 J 10 U 500 U 50

5 U 10 U 500 U 505 U 10 U 500 U 95 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 50
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 1 Day 5 Day 14

7/15/2009 7/20/2009

7/14/2009 

Day 0

Butler County, PA 

7/29/2009

Location P

NA NA NA N

5 U 10 U 500 U 505 U 10 U 500 U 50

NA NA NA N

0.93 J 92 6200 520

5 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 505 U 10 U 500 U 50

5.1 J 32 6500 5409.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 19.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 9

NA NA NA N

9.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 9

47 U 48 U 98 U 4

9.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 19.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 19.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 19.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 9

47 U 48 U 98 U 4

9.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 2.5 J 20 U 9

47 U 48 U 98 U 447 U 48 U 98 U 4

9.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 9

47 U 48 U 98 U 447 U 48 U 98 U 494 U 97 U 200 U 9

9.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 11.9 U 1.9 U 3.9 U 19.4 U 0.95 J 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 9

190 U 190 U 390 U 19

1.9 U 1.9 U 3.9 U 11.9 U 1.9 U 3.9 U 11.9 U 1.9 U 3.9 U 11.9 U 1.9 U 3.9 U 11.9 U 1.9 U 3.9 U 19.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 11.9 U 1.9 U 3.9 U 14.2 J 5.9 J 16 J 49.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 19.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 19.4 U 9.7 U 20 U 9

0.49 J 0.51 J 20 U 9

9.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 90.6 J 0.46 J 0.84 J 9
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Day 1 Day 5 Day 14

7/15/2009 7/20/2009

7/14/2009 

Day 0

Butler County, PA 

7/29/2009

Location P

9.4 U 9.7 U 15 J 99.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 19.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 11.9 U 1.9 U 3.9 U 11.9 U 1.9 U 3.9 U 11.9 U 1.9 U 3.9 U 19.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 19.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 19.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 11.9 U 1.9 U 3.9 U 19.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 9

19 U 19 U 39 U 1

9.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 91.9 U 1.9 U 3.9 U 11.9 U 1.9 U 3.9 U 19.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 91.9 U 0.28 J 3.9 U 19.4 U 360 470 229.4 U 9.7 U 20 U 99.4 U 9.7 U 20 U 9

NA NA NA N

0.047 U NA NA 0.00.047 U NA NA 0.00.047 U NA NA 0.00.047 U NA NA 0.00.047 U NA NA 0.00.047 U NA NA 0.0

0.47 U NA NA 0

0.047 U NA NA 0.00.047 U NA NA 0.00.047 U NA NA 0.00.047 U NA NA 0.00.047 U NA NA 0.00.047 U NA NA 0.00.047 U NA NA 0.00.047 U NA NA 0.00.047 U NA NA 0.00.047 U NA NA 0.00.047 U NA NA 0.00.094 U NA NA 0

1.9 U NA NA 

0.38 U NA NA 00.38 U NA NA 00.38 U NA NA 00.38 U NA NA 00.38 U NA NA 00.38 U NA NA 00.38 U NA NA 0
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Day 1 Day 5 Day 14

7/15/2009 7/20/2009

7/14/2009 

Day 0

Butler County, PA 

7/29/2009

Location P

0.97 U NA NA 0.9

10 UJ 10 UJ 10 UJ 110 UJ 10 UJ 10 UJ 110 UJ 10 UJ 10 UJ 110 UJ 190 J 160 J 1410 UJ 10 UJ 10 UJ 1

100 UJ 100 UJ 100 UJ 10100 UJ 100 UJ 100 UJ 10

1 U 1 U 20 UJ 11 U 1 U 20 UJ 11 U 1 U 20 UJ 1

20 80 250 15
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 5 U 63.2 

0.01 NR U 0.01 NR U 0.01 NR U 0.01 U 

1.8 16.1 65.4 102 J 

121 184 144 98.1 

4.5 87.9 310 720 

1770 1080 1850 14000 J 

78.1 J 8960 J 33500 71500 1

467 341 J 160 25.8 

0.25 G U 2.5 G U 2.5 G U 2.5 G U 

88 2200 9100 32000 

0.25 G U 2.5 G U 2.5 G U 2.5 G U 0.33 0.51 0.055 B J 0.025 B 0.25 G U 6.5 13.2 19.9 

5 U 4.8 U 4.6 U 4.8 U 

426 J 39800 J 130000 J 249000 J 4

45.3 J 31.8 B J 50 G U 50 G U 

410 J 142 J 46.5 J 24 J 

49 J 338 J 140 J 113 J 

311 16600 38500 120000 2

11.9 24.3 61.7 83.1 

0.034 B 0.16 0.097 B 0.055 B J 

120 9.2 95 62 

20.7 11.7 68.2 10.5 92.4 21.2 72.1 10 U 

4.8 3.2 2.4 B 3 U 6.9 7.5 6.6 6.2 

0.033 J 0.0087 B J 0.018 J 0.01 U 

12.0 12.4 6.4 14.8 

0.501 0.05 U 0.133 0.836 

2000 U 395 B 246 B 640 B 2000 U 190 B 173 B J 737 B 

100 U 24.7 B 100 U 37.2 B J 100 U 25.2 B 100 U 38.5 B J 100 U 100 U 100 U 46.4 B 100 U 100 U 100 U 65 B 227 B 37600 415000 1700000 J 34294 B 43800 401000 1730000 25

40 U 40 U 40 U 40 U 40 U 40 U 40 U 40 U 

2000 U 5110 9070 10400 J 

33.5 B 5840 8500 10800 J 

50 U 50 U 50 U 1.4 B 50 U 50 U 50 U 1.9 B 

27800 B J 641000 J 3120000 J 8790000 18026800 B J 728000 J 2890000 J 8730000 134

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

500 U 500 U 500 U 1000 U 500 U 500 U 500 U 1000 U 

39.7 B 250 U 28.9 B 250 U 35.6 B 250 U 250 U 250 U 

429 B J 5830 J 37500 72700 3

1000 U 5000 30400 72900 2

30 U 14.5 B 30 U 60 U 30 U 14.5 B 30 U 60 U 

500 U 12300 29300 68700 J 1500 U 14300 27000 69100 

6400 B 59800 331000 938000 166090 B 67100 307000 963000 12

8.2 B J 752 J 2300 4790 

150 U 826 2130 4890 400 U 21.1 B 20.6 B J 14.8 B 400 U 24.1 B 400 U 400 U 400 U 400 U 400 U 800 U 400 U 400 U 400 U 800 U 

50000 U 45400 B 187000 265000 8

4110 B 53500 163000 267000 6

50 U 50 U 50 U 50 U 50 U 50 U 50 U 44.2 B 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

Day 5 D

7/1/2009 10/

7/15/2009

Day 14

7/6/2009

Day 0 Day 1

6/30/2009

Westmoreland County, PA

Location Q
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 5 D

7/1/2009 10/

7/15/2009

Day 14

7/6/2009

Day 0 Day 1

6/30/2009

Westmoreland County, PA

Location Q

63200 5400000 1.7E+07 30800000 J 49767900 5960000 1.6E+07 31300000 368

292 B J 86200 J 422000 J 1310000 J 28254 B J 98800 J 396000 J 1300000 J 21100 U 100 U 100 U 200 U 100 U 100 U 100 U 200 U 

1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 22.4 B 1000 U 

500 U 44.5 B 500 U 139 B 500 U 35.4 B 500 U 113 B 

50 U 50 U 50 U 50 U 

37.7 B 78.6 B 156 B 144 B J 2

69 B J 100 B J 159 B 137 B J 1

0.5 G U 0.5 G U 0.1 G U 0.25 G U 0.5 G U 0.5 G U 0.1 G U 0.25 U 0.2 U 0.2 U 0.2 U 0.2 U 

0.095 B 0.2 U 0.2 U 0.2 U 

5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 

1000 U 1000 U 1000 U 10000 U 

NA NA NA NA 

5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 

10 U 10 U 10 U 100 U 

5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 

28 16 J 42 520 

100 U 100 U 100 U 1000 U 100 U 100 U 100 U 1000 U 

5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 4 J 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 5 D

7/1/2009 10/

7/15/2009

Day 14

7/6/2009

Day 0 Day 1

6/30/2009

Westmoreland County, PA

Location Q

NA NA NA NA 

5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 

NA NA NA NA 

5 U 5 U 1.2 J 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 

15 U 15 U 4.4 J 150 U 

9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

NA NA NA NA 

9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

48 U 48 U 47 U 47 U 

9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

48 U 48 U 47 U 47 U 

9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 0.2 J 9.4 U 

48 U 48 U 47 U 47 U 48 U 48 U 47 U 47 U 

9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

48 U 48 U 47 U 47 U 48 U 48 U 47 U 47 U 95 U 95 U 94 U 94 U 

9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 1.2 J 0.34 J 0.33 J 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

190 U 190 U 190 U 190 U 

1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 4.4 J 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 

10 9.5 U 9.4 U 3.7 J 

9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.1 J 9.5 U 9.4 U 9.4 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Day 5 D

7/1/2009 10/

7/15/2009

Day 14

7/6/2009

Day 0 Day 1

6/30/2009

Westmoreland County, PA

Location Q

9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

19 U 19 U 19 U 19 U 

9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

NA NA NA NA 

0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 

0.17 PG NA NA 0.047 U 

0.048 U NA NA 0.047 U 

0.26 NA NA 0.047 U 0.48 U NA NA 0.47 U 

0.072 PG NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 

0.12 NA NA 0.047 U 0.26 PG NA NA 0.047 U 

0.095 U NA NA 0.094 U 

1.9 U NA NA 1.9 U 

0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Day 5 D

7/1/2009 10/

7/15/2009

Day 14

7/6/2009

Day 0 Day 1

6/30/2009

Westmoreland County, PA

Location Q

0.95 U NA NA 0.95 U 

110 J 38 J 28 J 20 J 

20 UJJ 5 UJ 10 UJ 10 UJ 20 UJJ 5 UJ 10 UJ 10 UJ 20 UJ 5 UJ 10 UJ 10 UJ 20 UJ 5 UJ 10 UJ 10 UJ 

200 UJ 100 UJ 100 UJ 100 UJ 200 UJ 100 UJ 100 UJ 100 UJ 

20 UJ 1 U 33 33 J 20 UJ 5 UJ 1 U 10 UJ 20 UJ 1 U 1 U 10 UJ 

300 100 120 600 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1

Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 5 U 408 

0.01 NR U 0.01 NR U 0.01 NR U 0.01 U 0.58 13.4 41.1 J 15 

271 692 1250 6.2 

10 G U 72.7 272 113 

1990 1660 3200 1760 

18 B 7060 32100 J 12300 

452 540 501 343 

2.5 G U 0.5 G U 2.5 G U 0.5 G U 

34 1500 8300 4000 

2.5 G U 0.5 G U 2.5 G U 0.5 G U 

0.13 0.035 B 0.053 B J 0.038 B 

2.5 G U 3.8 11.8 3.8 

134 5 U 655 96.1 192 J 29800 J 98400 J 41500 J 

11 B 25.3 J 34.5 B J 10 G U 

173 604 388 J 323 

60.4 J 577 J 327 J 85.2 J 

481 15100 46900 20900 

27.2 44.7 65.6 30.5 0.63 1.4 0.96 0.87 

732 36.8 1180 286 650 10 1540 233 

46.4 22.9 18.5 7.3 B 

3 U 3 U 5.6 3.2 

7.2 7.1 6.7 4.9 

0.035 0.027 0.046 0.059 J 

14.0 10.8 11.6 13.2 0.03 U 0.0505 1.52 1.66 

430 B 608 B 1870 B 1900 B 

2000 U 655 B 2000 U 426 B J 

100 U 24.8 B 39.7 B 100 U 100 U 26.8 B 100 U 100 U 100 U 55.1 B 43 B 100 U 100 U 62.4 B 40.2 B 100 U 

67.5 B 36500 686000 296000 78.6 B 33700 603000 251000 

3 B 40 U 40 U 40 U 

40 U 40 U 40 U 40 U 

2000 U 7850 17300 5330 2000 U 9150 17100 5130 

50 U 50 U 2.2 B 50 U 50 U 50 U 50 U 50 U 

7200 B J 430000 J 2560000 J 1190000 J 5450 B J 494000 J 2610000 J 1130000 J 

704 31 B 152 65.5 

50 U 32 B 67.4 40 B 

11.9 B 500 U 500 U 500 U 

500 U 500 U 500 U 500 U 

40.5 B 250 U 4150 518 

250 U 250 U 274 387 

7500 J 16700 J 172000 J 214000 

468 B 18200 93100 183000 

30 U 54.7 606 25.2 B 

1.3 B 39.9 30 U 30 U 

500 U 9500 37700 12500 500 U 11300 36100 12100 

1490 B 37500 B 283000 133000 1090 B 43200 B 287000 126000 

104 B J 1280 J 4030 J 5100 150 U 1420 3440 4780 

91.8 B 23.6 B 147 B 23.1 B J 

400 U 25.2 B 104 B 400 U 440 22 B 67 B 98.3 B 400 U 22.6 B 19.9 B 93.3 B 

50000 U 25100 B 109000 46500 B 50000 U 31200 B 111000 39400 B 

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

Day 0 Day 1 Day 5

6/22/2009 6/23/2009 7/13/2009 7/7/2009 

Tyler County, WV

Day 14 

Location R
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 0 Day 1 Day 5

6/22/2009 6/23/2009 7/13/2009 7/7/2009 

Tyler County, WV

Day 14 

Location R

33300 B 4280000 16900000 5970000 41900 B 4970000 16800000 5680000 

58.5 B J E 43100 J 387000 J 175000 J 73.9 B J E 50400 J 364000 J 163000 J 

100 U 100 U 100 U 100 U 100 U 25.1 B 30.5 B 100 U 

1000 U 1000 U 1000 U 23.5 B 1000 U 1000 U 1000 U 1000 U 

39.1 B 26.3 B 107 B 500 U 22.9 B 34.5 B 35 B 500 U 

50 U 32 B 67.4 65.5 

67.9 B 56.1 B 740 1290 

52 B J 61.2 B J 122 B J 1160 

0.25 G U 0.05 G U 0.5 G U 0.1 G U 0.25 U 0.05 G U 0.5 G U 0.25 G U 

0.065 B J 0.2 U 0.2 U 0.2 U 

0.2 U 0.2 U 0.2 U 0.2 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 8.1 4 J 3.7 J 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 1J 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

1000 U 1000 U 1000 U 1000 U #N/A NA ND U NA NA 

5U 5U 5U 5U 5 U 8.1 5 U 5 U 

10 U 10 U 10 U 10 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

25 100 30 42 

100 U 100 U 100 U 100 U 100 U 9.1 J 100 U 100 U 

5 U 4.2 J 5 U 5 U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 150 5 U 5 U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 1 J 1.4 J 5 U 5 U 

0.95 J 5 U 5 U 5 U 

5U 5U 5U 5U 5 U 5 U 2.2 J 5 U 5 U 14 2.1 J 0.66 J 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 0 Day 1 Day 5

6/22/2009 6/23/2009 7/13/2009 7/7/2009 

Tyler County, WV

Day 14 

Location R

NA NA NA NA 

5U 5U 5U 5U 

1.4 J 5 U 5 U 5 U 

NA NA NA NA 

1.2 J 3.2 J 2.5 J 1.3 J 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

8.4 J 13 J 6 J 6.6 J 

10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 19 U 

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 

NA NA ND U NA NA 

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 50 U 55 U 94 U 470 U 10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 19 U 

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 19 U 

10 U 11 U 19 U 94 U 

2 U 3.1 3.8 U 120 

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 50 U 55 U 94 U 470 U 10 U 11 U 19 U 94 U 

5.3 J 25 19 U 94 U 

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 50 U 55 U 94 U 470 U 50 U 55 U 94 U 470 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 50 U 55 U 94 U 470 U 50 U 55 U 94 U 470 U 

100 U 110 U 190 U 940 U 

10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 19 U 2 U 2.2 U 3.8 U 19 U 

10 U 4.9 J 22 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 

200 U 220 U 380 U 1900 U 

2 U 2.2 U 3.8 U 19 U 2 U 2.2 U 3.8 U 19 U 2 U 2.2 U 3.8 U 19 U 2 U 2.2 U 3.8 U 19 U 2 U 2.2 U 3.8 U 19 U 

10 U 11 U 19 U 750 10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 19 U 2 U 2.2 U 3.8 U 19 U 

21 11 U 8.7 J 49 J 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 19 U 

10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 19 U 

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 

1 J 11 U 19 U 94 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Day 0 Day 1 Day 5

6/22/2009 6/23/2009 7/13/2009 7/7/2009 

Tyler County, WV

Day 14 

Location R

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 19 U 

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 19 U 2 U 2.2 U 3.8 U 19 U 2 U 2.2 U 3.8 U 19 U 2 U 2.2 U 3.8 U 19 U 

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 19 U 

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 19 U 

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 19 U 2 U 2.2 U 3.8 U 19 U 

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 20 U 22 U 38 U 190 U 10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 22 2 U 2.2 U 3.8 U 19 U 

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 

2 U 2.2 U 3.8 U 13 J 

4.1 J 31 10 J 94 U 

10 U 11 U 19 U 94 U 10 U 11 U 19 U 94 U 

NA NA NA NA 

0.05 U NA NA 0.048 U 0.05 U NA NA 0.72 0.05 U NA NA 0.048 U 0.05 U NA NA 0.048 U 0.05 U NA NA 0.048 U 0.05 U NA NA 0.87 PG 

0.5 U NA NA 0.48 U 

0.05 U NA NA 0.4 PG 0.05 U NA NA 0.31 PG 0.05 U NA NA 0.048 U 0.05 U NA NA 0.28 PG 0.05 U NA NA 0.048 U 0.05 U NA NA 0.32 PG 0.05 U NA NA 0.048 U 0.05 U NA NA 0.048 U 0.05 U NA NA 0.96 0.05 U NA NA 0.49 PG 0.05 U NA NA 0.22 PG 

0.1 U NA NA 0.096 U 

2U NA NA 1.9 U 

0.4 U NA NA 0.38 U 0.4 U NA NA 0.38 U 0.4 U NA NA 0.38 U 0.4 U NA NA 0.38 U 0.4 U NA NA 8 0.4 U NA NA 0.38 U 0.4 U NA NA 0.38 U 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Day 0 Day 1 Day 5

6/22/2009 6/23/2009 7/13/2009 7/7/2009 

Tyler County, WV

Day 14 

Location R

0.96 U NA NA 0.95 U 

57 J 41 J 57 J 11 J 20 UJ 10 UJ 20 UJ 10 UJ 20 UJ 10 UJ 20 UJ 10 UJ 20 UJ 220 J 380 J 44 J 20 UJ 10 UJ 20 UJ 10 UJ 

200 U 100 U 200 UJ 100 UJ 200 U 100 U 200 UJ 100 UJ 

10 UJ 39 50 UJ 450 J 10 UJ 1 U 50 UJ 1 U 10 UJ 1 U 50 UJ 1 U 

300 100 250 600 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1

Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 5 U 

0.01 U 0.01 U 0.01 U 0.52 J 3 J 2.8 J 

2 U 2220 1440 

0.2 U 0.2 U 0.2 U 

18.4 J 4810 J 3420 J 28.1 58.5 64.2 3

2.3 J 906 J 657 J 

0.05 U 0.05 U 0.077 

156 156 156 

1.8 2.6 2.7 

3 3.1 2.8 

0.05 U 0.06 0.045 B 

4.6 U 158 13.7 

466 J 480 J 479 J 1

8.4 32.6 17.7 2.7 931 672 

88.8 J 109 J 123 J 

277 280 680 5

3 U 42.3 47.5 

0.1 U 0.082 B 0.037 B 

4 U 200 142 

1.7 308 300 

10 U 3.5 B 6.6 B 

3.2 3 U 3 U 

7 7.2 7.9 

0.0065 B 0.044 0.048 

11.2 20 15.2 

0.0969 0.05 U 0.0613 

177 B 623 B 507 B 

2000 U 203 B 165 B 

15.4 B 16.8 B 100 U 

100 U 100 U 13.5 B 100 U 100 U 100 U 100 U 100 U 100 U 840 B 410 B 332 B 65734 B 346 B 240 B 7

40 U 40 U 40 U 40 U 40 U 40 U 

18.9 B 17.8 B 18.1 B 15.8 B 13.8 B 14.2 B 

1.7 B 2.1 B 2.2 B 

2 B 50 U 1.3 B 

40100 B J 35200 B J 35200 B J 40837500 B J 36000 B J 37800 B J 45

50 U 50 U 7.5 B 50 U 50 U 50 U 

500 U 4.4 B 5.7 B 500 U 5.4 B 6.2 B 250 U 109 B 43.9 B 250 U 123 B 37.2 B 394 B 1790 6490 

1000 U 726 B 1670 3

30 U 30 U 30 U 30 U 30 U 30 U 

500 U 42 B 500 U 3

42.1 B 31.1 B 500 U 3

18300 B 15700 B 16000 B 317000 B 16200 B 17300 B 4

8.7 B 37.9 B 146 B 

150 U 30.5 B 119 B 400 U 400 U 14.2 B 400 U 400 U 400 U 400 U 400 U 16.7 B 400 U 400 U 400 U 

2930 B 2420 B 2690 B 303090 B 2590 B 3000 B 35

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

Day 0 Day 

Day 1 

8/25/2009 8/25/2009 8/25/2009 8/29/2

Supply Water

Centre County, PA

Location S
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 0 Day 

Day 1 

8/25/2009 8/25/2009 8/25/2009 8/29/2

Supply Water

Centre County, PA

Location S

37700 B 60800 63800 164035300 B 71800 69200 1800

723 E 597 580 156653 J E 624 J 594 J 17100 U 100 U 100 U 100 U 100 U 100 U 

1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 

500 U 500 U 500 U 500 U 500 U 500 U 

50 U 50 U 50 U 

172 B J 164 B J 138 B J 156 B J 140 B J 73.8 B J 

0.01 U 0.0078 B 0.05 G U 0.01 U 0.05 G U 0.05 G U 

0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 

5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 11 33 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 2.8 J 13 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 

1000 U 1000 U 1000 U 

NA NA NA 

5 U 5 U 5 U 5 U 5 U 5 U 

10 U 10 U 10 U 

5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 

20 U 5.4 J 14 J 

100 U 100 U 100 U 100 U 100 U 100 U 

5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 0.81 J 1.8 J 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 1.8 J 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 0 Day 

Day 1 

8/25/2009 8/25/2009 8/25/2009 8/29/2

Supply Water

Centre County, PA

Location S

NA NA NA 

5 U 5 U 5 U 5 U 5 U 5 U 

NA NA NA 

5 U 1.6 J 3.8 J 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 

15 U 5.4 J 16 

9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

NA NA NA 

9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

47 U 47 U 47 U 

9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

47 U 47 U 47 U 

9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

47 U 47 U 47 U 47 U 47 U 47 U 

9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

47 U 47 U 47 U 47 U 47 U 47 U 94 U 94 U 94 U 

9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

190 U 190 U 190 U 

1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 J B 14 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 0.6 J 2 J 9.4 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Day 0 Day 

Day 1 

8/25/2009 8/25/2009 8/25/2009 8/29/2

Supply Water

Centre County, PA

Location S

9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

1.9 U 1.9 U 1.9 U 1.9 U 2 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

19 U 19 U 19 U 

9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 3.4 3.5 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 0.76 J 0.89 J 9.4 U 70 18 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

NA NA NA 

0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 

0.47 U 0.47 U NA 

0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.041 J NA 0.051 0.063 NA 0.047 U 0.047 U NA 0.094 U 0.094 U NA 

1.9 U 1.9 U NA 

0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Day 0 Day 

Day 1 

8/25/2009 8/25/2009 8/25/2009 8/29/2

Supply Water

Centre County, PA

Location S

0.94 U 0.95 U NA 

10 U 310 150 J 10 U 20 U 20 UJ 10 U 20 U 20 UJ 10 U 20 U 20 UJ 10 U 20 U 20 UJ 

100 U 200 U 200 UJ 100 U 240 200 UJ 

1 U 50 U 1.4 1 U 50 U 1 U 1 U 50 U 1 U 

15 150 75 
49 

Appendix D 

Summary of Detected VOCs, SVOC, 

Pesticides and PCBs
Location B

Day 0 Day 1 Day 5

PARAMETER UNITS PQL US EPA Method 2/7/2009 2/8/2009 2/11/20091,2,3-Trichlorobenzene ug/L 5 SW846 8260B 1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B 16 140 J 82 110 J 74 1,3,5-Trimethylbenzene ug/L 5 SW846 8260B 6 100 J 33 120 65 2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260B 76 Acrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260B 7.7 8 8.5 J 240 1200 420 Bromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260B 1500Chloroform ug/L 5 SW846 8260B 28Chloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260B 19 J 14 J 85 J 42 Isopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260B 24 J 18 Jn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260B 54 J 22 sec-Butylbenzene ug/L 5 SW846 8260B 84 J 68 JTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260B 5.1 81 J 340 820 Xylenes (total) ug/L 15 SW846 8260B 18 210 J B 1100 NOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laboratory detection limit.J - The reported result is an estimated result. The result is less than the laboratory reporting limit.E - The resported result is an estimated result.

Volatile Organic Compounds

2/20/2009 1/26/2009 1/29/2009 2/2/2009 2/10/200

Day 14 Day 0 Day 1 Day 5 Day 14 

Location A
PARAMETER UNITS PQL US EPA Method

1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is lJ - The reported result is an estimated result. The result is less than thE - The resported result is an estimated result.

Volatile Organic Compounds

Location D 

Day 0 Day 1 Day 5 Day 14 Day 0 Day 1 Day 90 Day 0 Da

2/11/2009 2/17/2009 2/20/2009 2/27/2009 2/12/2009 2/13/2009 5/13/09 4/1/2009 4/3/2

140 J 20

23000 1400 260 19 54000 7300 400

5.6 

2/17/2009

Location C

Day 5
PARAMETER UNITS PQL US EPA Method

1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is lJ - The reported result is an estimated result. The result is less than thE - The resported result is an estimated result.

Volatile Organic Compounds

Loc G Location H

Day 14 Day 0 

4/22/2009 4/7/2009 

170 J

66 J

11 52 33 980 24000 4000 

5.2 J 33 J 21 J 820 11000 1900 

14 J 98 J 26 66000 23 5800 

280 880 400 290 6.7

7.6 J 29 J 23 J 270

130 J 10000 1400 

300 920 540 1600120 340 280 3300 5200 J 860 J 

3/27/2009 4/1/2009 4/9/2009 6/29/2009 4/7/2009 4/8/2009 4/13

Day 1 Day 5 Day 14 Day 90 Supply Water Day 1 D

Location F
PARAMETER UNITS PQL US EPA Method

1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is lJ - The reported result is an estimated result. The result is less than thE - The resported result is an estimated result.

Volatile Organic Compounds

Location I Location J Locat

Day 5 Day 14 Day 0 Day 1 Day 14 Day 0 Da

5/19/2009 5/28/2009 5/1/2009 5/4/2009 5/18/2009 05/07/2009 5/20/

42 20 

7.5

390 130 25 22 B 330

7.8 5.8

13 B

8.9 J

6.7

35

5/9/2009 5/15/2009 5/8/2009

Day 0 Day 1 Day 5
PARAMETER UNITS PQL US EPA Method

1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is lJ - The reported result is an estimated result. The result is less than thE - The resported result is an estimated result.

Volatile Organic Compounds

Location L

Supply Water Day 0 Day 1 Day 5 Day 14 Day 1 Day 14

5/12/2009 5/13/2009 5/14/2009 5/18/2009 5/27/2009 6/6/2009 6/19/2009

27 38 770 14 32 670 

21 170 90 J 

39 99 260 6.2

50 9.3

17 220

86

5.5 J

46 260 1500 15 220 2700 25 J 

07/14/09 7/15/2009 7/1

Day 0 Day 1 D

Location M Location N 
PARAMETER UNITS PQL US EPA Method

1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is lJ - The reported result is an estimated result. The result is less than thE - The resported result is an estimated result.

Volatile Organic Compounds

Location P Location Q

Day 90 Day 0 Day 5 Day 14

10/29/2009 6/30/2009 7/6/2009 7/15/2009

840 710 84940 770 79

320 5200 190 28 16 J 42 520140 2000 1100 200

230 J

5.9 J

650 470 J 46160 J 120 J

90 J

92 6200 5200 58032 6500 5400 530

7/15/2009 7/1/2009 7/20/2009 7/29/2009

Day 1 Day 5 Day 1 Day 14
PARAMETER UNITS PQL US EPA Method

1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260BToluene ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is lJ - The reported result is an estimated result. The result is less than thE - The resported result is an estimated result.

Volatile Organic Compounds

Location R Location S

Day 0 Day 1 Day 5 Day 14 Day 0 Day 1 Day 14

6/22/2009 6/23/2009 7/13/2009 7/7/2009 8/25/2009 8/25/2009 9/8/2009

6.5

8.1 11 33

13

8.1

25 100 30 42 1300 31

150

14

28 J

16

8/29/2009

Day 5
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C 22-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270C 35 JDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270C 2.7Phenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270C 86 2600 1800 860 490NOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laboratory detection limit.

J - The reported result is an estimated result. The result is less than the laboratory reporting limit.E - The resported result is an estimated result.

2/7/2009 2/11/2009 2/20/2009

Location A

2/8/2009

Day 0 Day 1 Day 5 Day 14 Day 90

Semi-Volatile Organic Compounds

5/8/2009
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.

Semi-Volatile Organic Compounds

Location B

120 94

11

41 J

14 11 14

9.8

3.2

11 J 8.4 J

0.99 J

3.1

22 J 16 J

11 J

310 350 250 77 260

2/2/2009 2/10/2009

Day 14

1/26/2009 1/29/2009 4/29/2009

Day 0 Day 1 Day 5 Day 90
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.

Semi-Volatile Organic Compounds

Location D

7.5 3.7

0.35 J 1.1 J

9.5

30

2.4

17

2/12/2009 2/17/2009 5/13/09 2/13/2009

Day 0 Day 1 Day 90 Day 5
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.

Semi-Volatile Organic Compounds

Location E

10

2.6 J 3.2

35 430 310 200 57

4/1/2009 4/17/2009 4/3/2009 4/7/2009 4/17/2009

Day 0 Day 14 Day1 Day 5 Day 90
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.

Semi-Volatile Organic Compounds

Location F

11 12 J1133 87014

3 J

16 15 16

370 520 250 220 140

3/24/2009 3/27/2009 6/29/2009

Day 0 Day 1 Day 14 Day 90

4/1/2009 4/9/2009

Day 5
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.

Semi-Volatile Organic Compounds

Location G

2.7

16 10 

55 30 14

4/8/2009 4/22/2009 4/13/2009 4/7/2009 4/13/2009 

Day 0 

Locaction 

Day1 Day 5 Day 14 Day 5
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.

Semi-Volatile Organic Compounds

Location I

6.7

10

6.95.9

41 J 17

11

5.5 6.1

9.5

640 310 42

Day 5

5/9/2009 5/15/2009 5/19/2009 10/20/2009

Day 0 Day 1 Day 90
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.

Semi-Volatile Organic Compounds

2

13

6.9

11

7.46.7

4300 18 17

9.6

12

130

10

2.7

Day 14 Day 0

5/1/2009 5/4/2009 05/07/2009 5/8/2009 5/18/2009

Location J Loca

Day0 Day 1 Day 5
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.

Semi-Volatile Organic Compounds

Location L

5/13/2009

16

5.5 10

5/14/2009 5/18/2009

Day 0 Day 1 Day 5
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.

Semi-Volatile Organic Compounds

2.5

140 100 94

Day 5

6/10/2009

Location M

6/6/2009

Day 1

7/15/2009

Location N

Day 1 Day 14

6/19/2009
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.

Semi-Volatile Organic Compounds

260 52

3.5 J

7/1/2009

Day 1

7/1/2009

Location O

Day 0
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.

Semi-Volatile Organic Compounds

Location P Loc

12151616

16 J 15 J

21

9.4 U

360 470 220 340

7/15/2009

Day 1

10/29/2009 

Day 5 Day 14 

7/20/2009 7/29/2009

Day 90
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.

Semi-Volatile Organic Compounds

Location R

3.1 120

25

22

750

21 49 J 

22 13 J 

31 10 J

6/22/2009 1

6/23/2009 7/13/2009 7/7/2009

Day 0 Day 1 Day 5 Day 14 
PARAMETER UNITS PQL US EPA Method

2,4-Dimethylphenol ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcetophenone ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270CDi-n-octyl phthalate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CNOTESNA - Not ApplicableNR - Analytical data has not been reported by the laboratory to date.ND - The constituent was not detected. The reported concentration is less than the laJ - The reported result is an estimated result. The result is less than the laboratory reE - The resported result is an estimated result.

Semi-Volatile Organic Compounds

Location S

14

2.3

2

2.4

3.4 3.5

70 18 530 280

8/25/2009 8/25/2009 8/29/2009 9/8/2009

Day 0 Day 1 Day 5 Day 14
Pesticides

PARAMETER UNITS PQL US EPA Method4,4'-DDE ug/L 0.05 SW846 8081A 0.11Aldrin ug/L 0.05 SW846 8081A 0.12 PG beta-BHC ug/L 0.05 SW846 8081A 0.062 PGdelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081A 0.22 PGEndosulfan II ug/L 0.05 SW846 8081A 0.42Endrin ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081A 0.24 0.093Heptachlor epoxide ug/L 0.05 SW846 8081AAroclor 1248 ug/L 0.4 SW846 8082

PG - indicates that the result is estimated and the sample was diluted due to matrix interference

Location C Location H Location D Location E Location F

5/15/2009 6/29/2009 4/22/2009 

Day 90

2/12/2009

Day 90

4/17/2009 4/7/2009

Day 0 Day 90 Day 14 

Day 0
Pesticides

PARAMETER UNITS PQL US EPA Method4,4'-DDE ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AAroclor 1248 ug/L 0.4 SW846 8082

PG - indicates that the result is estimated and the sample was diluted d

0.083 

0.37 0.069 PG

0.27 0.38

0.1 0.8 PG 0.84 

Location I Location M Location J 

Location K Location L

6/2/2009 

5/27/2009 5/19/2009 5/19/20

Day 14 Day 14

5/28/2009 5/18/2009

Day 14 Day 14 Supply Water Day 0 
Pesticides

PARAMETER UNITS PQL US EPA Method4,4'-DDE ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AAroclor 1248 ug/L 0.4 SW846 8082

PG - indicates that the result is estimated and the sample was diluted d

0.72

0.17 PG0.26 0.87 PG 0.41 PG

0.072 PG 0.4 PG

0.31 PG

1.8 PG 

0.28 PG0.32 PG0.96 0.34

0.12 0.49 PG 0.41 PG 0.051 0.0630.26 PG 0.22 PG 0.31

8

Location Q Location R Location S

6/30/2009 7/7/2009 10/28/2009 8/25/2009 8/25/2009

Day 0 Day 14 Day 90 Supply Water Day 0 
ATTACHMENT B 

MSC Database for the 8 Northern Pennsylvania Wells 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

1230 5 U 5 19.4 

0.01 U 0.01 U 0.01 U 0.01 U 

441 J 71.4 J NA 359 J 189 302 144 7.3 

0.2 U 261 553 697 

502 2100 4470 12800 

86 43300 77200 102000 

11.6 124 J 58.4 43 J 0.19 2.2 B 2.4 B 2.5 G U 

130 15000 44000 55000 

3.4 1.6 B 2 B 2.5 G U 2.4 J 1.9 J 0.63 J 0.16 J 2.5 G U 2.5 G U 2.5 G U 2.5 G U 4.7 U 4.6 U 10.8 4.6 U 

6720 J 147000 J 278000 J 360000 J 2920 19 B J 39.2 B J 49.4 B J 

11.4 J 123 60.8 42.2 

5 U 124 J 72.4 J 47.7 J 

1920 74600 125000 169000 

400 69.9 94.9 130 

0.26 0.19 2.5 G U 2.5 G U 

4 68 260 162 

4.7 126 92 32.9 

10 U 10 U 10 U 10 U 

3 U 3 U 3 U 1.6 B 6 7 6.3 6.4 

0.017 J 0.01 U 0.0084 B 0.011 J 

5 U 5.60 23.2 13.6 

0.0933 2.94 0.736 1.06 

2000 U 505 B 927 B J 835 B J 2000 U 358 B 508 B J 562 B J 

100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 28.2 B 54.2 B 77.3 B 100 U 37.4 B 70.5 B 82.3 B 339 B 1160000 3220000 J 5150000 J 348 B 1340000 3260000 5070000 

40 U 40 U 40 U 40 U 40 U 40 U 40 U 40 U 

59.3 B J 3030 J 3840 3880 68.7 B J 3470 J 3890 3820 

50 U 50 U 3 B J 3.8 B J 50 U 50 U 50 U 3.2 B 

32900 B 4070000 9270000 J 13100000 J 31800 B 4360000 9700000 J 14800000 J 

50 U 50 U 20.8 B J 12.7 B J 50 U 50 U 50 U 6.6 B 

7.9 B 2500 U 1000 U 5000 U 

14.2 B 2500 U 5000 U 5000 U 

120 B 250 U 73.3 B 250 U 

85.3 B 250 U 250 U 250 U 

14300 15700 33500 39200 13100 3690 16700 J 31500 J 

30 U 30 U 40.4 B J 78 B J 30 U 30 U 150 U 150 U 

34.1 B 80300 153000 201000 38.7 B 93000 155000 202000 

6190 B 271000 608000 781000 6240 B 293000 647000 J 875000 J 

67.2 B 1680 3440 J 4780 J 73.7 B 1930 3550 5170 

400 U 8.9 B 12.4 B 400 U 400 U 12.1 B 400 U 400 U 457 14.9 B 800 U 2000 U 452 20.1 B 2000 U 2000 U 

50000 U 127000 210000 312000 50000 U 144000 235000 274000 

50 U 50 U 50 U 39.4 B 50 U 50 U 50 U 49.5 B 50 U 50 U 9.3 B 8.4 B 50 U 50 U 50 U 8.1 B 

Day 0 Day 15 Day 1 Day 5

3/31/2009 4/8/2009 4/13/2009 

Lycoming County, PA

4/22/2009

Location G
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 0 Day 15 Day 1 Day 5

3/31/2009 4/8/2009 4/13/2009 

Lycoming County, PA

4/22/2009

Location G

45000 B 18100000 30800000 40300000 44700 B 20900000 31400000 41100000 

691 947000 2350000 J 3650000 J 686 1090000 2530000 J 3710000 J 100 U 100 U 200 U 500 U 100 U 100 U 500 U 500 U 

1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 

500 U 55.9 B 133 B 148 B 500 U 105 B 121 B 138 B 

50 U 50 U 50 U 50 U 

40.7 B 200 U 67.6 B J 52.2 B J 46.9 B 200 U 41.6 B 49.8 B 0.01 U 0.5 G U 1 G U 2.5 G U 0.01 U 0.5 G U 1 G U 2.5 G U 

0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 1.3 J 5 U 5 U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

1000 U 1000 U 1000 U 1000 U 

NA NA NA NA 

5U 5U 5U 5U 5U 5U 5U 5U 

10 U 10 U 10 U 10 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

20 U 13 J 16 J 26 

100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 

2.2 J 5 U 5 U 5 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 1.7 J 5 U 5 U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 0 Day 15 Day 1 Day 5

3/31/2009 4/8/2009 4/13/2009 

Lycoming County, PA

4/22/2009

Location G

NA NA NA NA 

5U 5U 5U 5U 5U 5U 5U 5U 

NA NA NA NA 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

15 U 15 U 15 U 15 U 

9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

NA NA NA NA 

9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

47 U 46 U 47 U 48 U 

9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 2.7 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

47 U 46 U 47 U 48 U 

9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

47 U 46 U 47 U 48 U 47 U 46 U 47 U 48 U 

9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

47 U 46 U 47 U 2.6 J 47 U 46 U 47 U 48 U 94 U 92 U 94 U 95 U 

9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 0.22 J 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 

0.21 J 0.98 J 0.81 J 0.38 J 

9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

190 U 180 U 190 U 190 U 

1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 1.1 J 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Day 0 Day 15 Day 1 Day 5

3/31/2009 4/8/2009 4/13/2009 

Lycoming County, PA

4/22/2009

Location G

9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 0.22 J 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

19 U 18 U 19 U 19 U 

9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 1.9 U 1.8 U 1.9 U 1.9 U 9.4 U 55 30 14 9.4 U 9.2 U 9.4 U 9.5 U 9.4 U 9.2 U 9.4 U 9.5 U 

NA NA NA NA 

0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 

0.48 U NA NA 0.47 U 

0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.095 U NA NA 0.094 U 

1.9 U NA NA 1.9 U 

0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Day 0 Day 15 Day 1 Day 5

3/31/2009 4/8/2009 4/13/2009 

Lycoming County, PA

4/22/2009

Location G

0.94 U NA NA 0.94 U 

5 UJ NA 10 UJ 10 UJ 5 UJ NA 10 UJ 10 UJ 5 UJ NA 10 UJ 10 UJ 

8.3 J NA 58 J 39 J 

5 UJ NA 10 UJ 10 UJ 

100 UJ NA 100 UJ 100 UJ 100 UJ NA 100 UJ 100 UJ 

10 UJ NA 100 U 10 J 10 UJ NA 100 U 18 J 10 UJ NA 100 U 10 UJ 

250 NA 430 10 UJ 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1

Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 5 U 123 

0.01 U 0.01 U 0.01 U 0.01 U 

0.064 B 5.9 127 199 J 

2 U 578 399 99.4 

0.22 1 238 901 18.7 2560 8790 195 49.9 90.2 58700 148000 

3.2 J 577 600 59.6 

0.05 U 0.05 U 2.5 G U 2.5 G U 

38 42 8600 42000 

0.05 U 0.02 B 2.5 G U 2.5 G U 

0.1 U 0.59 1.1 0.1 U 

0.05 U 0.034 B 2.5 G U 2.5 G U 

4.8 U 62.2 53.9 4.8 U 

247 J 362 J 200000 J 470000 J 

8.3 J 8.4 J 36.6 B J 50 G U 4.7 J 607 610 48 9.3 J 33.4 J 175 J 48.8 J 

400 265 122000 238000 

3 U 65.4 150 160 

0.14 0.062 B 0.084 B 0.45 

2 B 192 308 696 

3.1 75.2 461 203 

10 U 4.1 B 10 U 10 U 

1.6 B 3 U 3 U 3 U 7.3 7.6 6.6 5.8 

0.01 U 0.028 0.015 0.022 21.6 27.6 NA 6.80 

0.240 0.05 U NA 1.31 

2000 U 2000 U 1750 B J 418 B J 2000 U 227 B 286 B J 596 B J 

100 U 100 U 31.5 B 47.2 B 100 U 100 U 18.9 B 200 U 100 U 100 U 42.9 B 59.6 B 100 U 100 U 29.9 B 62.6 B 

1640 B 1170 B 516000 1400000 1580 B J 1500 B J 532000 J 1740000 

40 U 40 U 40 U 80 U 40 U 40 U 40 U 80 U 

34.3 B J 33.9 B J 5930 J 11900 44.2 B J 49.9 B J 6240 15400 

50 U 50 U 2.9 B 9.6 B 50 U 50 U 2.6 B 11.4 B 

11600 B J 9900 B J 2950000 9400000 J 12000 B J 13000 B J 3060000 11700000 

50 U 50 U 50.4 12.2 B 50 U 50 U 18.7 B 100 U 

500 U 500 U 1000 U 2500 U 500 U 500 U 1000 U 2500 U 250 U 250 U 68.3 B 500 U 250 U 250 U 35 B 500 U 192 B 198 B 58700 49700 

1000 U 175 B 21000 39100 J 

30 U 30 U 60 U 150 U 30 U 30 U 60 U 150 U 

42.2 B 29.7 B 34600 97600 32.7 B 51.7 B 36500 125000 

1840 B 1360 B 177000 604000 1830 B 1720 B 185000 765000 J 

13.9 B 150 U 2840 5520 

150 U 11.5 B 2870 6810 400 U 400 U 90 B 27.6 B 400 U 400 U 84.2 B 29.2 B 400 U 400 U 66.8 B 2000 U 400 U 400 U 66.8 B 2000 U 

50000 U 50000 U 378000 811000 

2240 B 3790 B 410000 1040000 

50 U 50 U 50 U 100 U 50 U 50 U 50 U 100 U 50 U 50 U 50 U 100 U 50 U 50 U 50 U 100 U 

Day 1 Day 5 

5/9/2009 5/9/2009 5/15/2009 5/19/2009 

Cameron County, PA

Supply Water Day 0

Location I
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 1 Day 5 

5/9/2009 5/9/2009 5/15/2009 5/19/2009 

Cameron County, PA

Supply Water Day 0

Location I

24400 B 54200 34700000 65100000 24900 B 70800 35000000 83400000 

1500 1070 492000 J 1800000 1460 J 1340 J 500000 J 2210000 J 

100 U 100 U 200 U 500 U 100 U 100 U 200 U 500 U 

1000 U 1000 U 1000 U 2000 U 1000 U 1000 U 1000 U 2000 U 

29.9 B J 27.1 B J 69.9 B 143 B 29.6 B J 24.4 B J 44.3 B 211 B 

50 U 50 U 50 U 100 U 

25.7 B J 45.7 B J 314 269 B J 61.5 B J 79.4 B J 187 B 195 B 0.25 G U 0.25 G U 0.5 U 0.25 G U 0.25 G U 0.25 G U 0.27 B 0.25 U 

0.053 B J 0.044 B J 0.2 U 0.2 U 

0.05 B J 0.47 B J 0.2 U 0.2 U 

5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 3.1 J 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 

1000 U 1000 U 5000 U 1000 U 

NA NA NA NA 

5 U 5 U 25 U 5 U 5 U 7.5 25 U 5 U 

10 U 10 U 50 U 10 U 

5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 

6.3 J B 20 U 390 130 

100 U 100 U 500 U 100 U 100 U 100 U 500 U 100 U 

5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 1.6 J 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 13 B 25 U 5 U 5 U 0.95 J 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 1 Day 5 

5/9/2009 5/9/2009 5/15/2009 5/19/2009 

Cameron County, PA

Supply Water Day 0

Location I

NA NA NA NA 

5 U 5 U 25 U 5 U 5 U 1.3 J 8.9 J 5 U 

NA NA NA NA 

5 U 6.7 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 0.81 J 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 5 U 5 U 25 U 5 U 

15 U 2.6 J 75 U 15 U 

9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1.9 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 

NA NA NA NA 

9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 

47 U 48 U 470 U 47 U 

9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1.9 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1.9 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 0.67 J 9.4 U 9.5 U 94 U 0.53 J 9.4 U 9.5 U 94 U 9.4 U 

47 U 48 U 470 U 1.3 J 

9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 1.2 J 

47 U 48 U 470 U 47 U 47 U 48 U 470 U 47 U 

9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 0.75 J 

47 U 48 U 470 U 47 U 47 U 48 U 470 U 47 U 94 U 95 U 940 U 94 U 

9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 0.9 J 1.9 U 1.9 U 19 U 0.84 J 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 

190 U 190 U 1900 U 190 U 

1.9 U 1.9 U 19 U 0.97 J 1.9 U 1.9 U 19 U 6.7 1.9 U 1.9 U 19 U 10 1.9 U 1.9 U 19 U 6.9 1.9 U 1.9 U 19 U 5.9 9.4 U 9.5 U 41 J 17 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1.9 U 1.9 U 1.9 U 19 U 1.9 U 9.4 U 9.5 U 94 U 6.9 J 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 0.85 J 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 11 9.4 U 9.5 U 94 U 0.87 J 9.4 U 9.5 U 94 U 1.3 J 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 0.87 J 9.4 U 9.5 U 94 U 5.3 J 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Day 1 Day 5 

5/9/2009 5/9/2009 5/15/2009 5/19/2009 

Cameron County, PA

Supply Water Day 0

Location I

9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1 J 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 5.5 19 U 6.1 1.9 U 1.9 U 19 U 0.82 J 1.9 U 1.9 U 19 U 1.9 U 1.9 U 1.9 U 19 U 1.9 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 9.5 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1.9 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 1.9 U 1.9 U 1.9 U 19 U 1 J 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 

19 U 19 U 190 U 19 U 

9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 0.89 J 1.9 U 1.9 U 19 U 0.7 J 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 1.9 U 1.9 U 19 U 0.89 J 9.4 U 4.5 J 640 310 9.4 U 9.5 U 94 U 9.4 U 9.4 U 9.5 U 94 U 9.4 U 

NA NA NA NA 

0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 

0.48 U 0.47 U NA NA 

0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.048 U 0.047 U NA NA 0.095 U 0.094 U NA NA 

1.9 U 1.9 U NA NA 

0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Day 1 Day 5 

5/9/2009 5/9/2009 5/15/2009 5/19/2009 

Cameron County, PA

Supply Water Day 0

Location I

0.95 U 0.97 U NA NA 

10 UJ 20 UJ 10 UJ 10 UJ 10 UJ 20 UJ 10 UJ 10 UJ 10 UJ 20 UJ 10 UJ 10 UJ 10 UJ 130 J 52 J 59 J 10 UJ 20 UJ 10 UJ 10 UJ 

100 UJ 200 UJ 100 UJ 100 UJ 100 UJ 200 UJ 100 UJ 100 UJ 

1 U 50 UJ 10 UJ 10 UJ 1 U 50 UJ 10 UJ 10 UJ 1 U 50 UJ 10 UJ 10 UJ 

NA NA NA 57 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1

Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5U 5U 5U 5

0.01 U 0.01 U 0.01 NR U 0.01 

0.017 B J 5.6 J 13.2 36.9 

2 U 47.1 36.7 47.5 

0.14 B 36.6 39.1 233 

10 U 47400 397 4870 

42.3 2180 2460 26400 

3.2 J 168 J 207 J 30.7 

0.033 B 0.05 U 0.5 G U 1.2 

140 1300 1060 7800 

1.7 1.6 0.83 2.3 1.8 2 0.94 0.89 

0.05 U 0.05 U 0.39 B 1.2 

4.8 U 29.2 7.3 4.8 

380 J 9280 J 8740 J 90500 

43.7 27.7 17.4 J 17.6 

2.2 569 56.6 27.5 

71.4 J 191 J 107 J 187 

746 4840 5090 48700 

3 U 17.1 14.2 96.1 

0.044 B 0.072 B 0.14 0.088 

9.6 230 330 68.8 1.3 101 330 30.2 

10 U 4.6 B 15.2 10 

2.4 B 3 U 3 U 3 7.2 7.2 7.4 6.6 

0.01 J 0.027 0.03 0.01 10.0 20.4 13.2 6.00 

0.962 0.05 U 0.134 0.0761 

249 B J 400 B J 4030 J 111 

2000 U 2000 U 212 B 2000 

100 U 100 U 100 U 35.8 100 U 100 U 100 U 29.9 100 U 100 U 34.3 B 32.1 100 U 100 U 100 U 55.3 338 B 87100 121000 1210000 241 B J 84400 J 64400 J 1290000 

40 U 40 U 40 U 40 40 U 40 U 40 U 40 

29.8 B J 156 B J 1120 B J 3140 39.2 B 202 B 1180 B 3500 

50 U 50 U 2.5 B 50 50 U 50 U 50 U 50 

37500 B J 241000 J 305000 J 1790000 43200 B 293000 318000 1950000 

50 U 50 U 359 15.1 50 U 50 U 5.8 B 50 

500 U 500 U 500 U 500 500 U 500 U 500 U 500 250 U 250 U 41.3 B 250 250 U 250 U 250 U 250 273 B 3080 55200 39000 

1000 U 1510 14200 38200 

30 U 30 U 26.4 B 30 30 U 30 U 30 U 30 

33.8 B 2050 4060 37000 40.7 B 2590 3790 40000 

5160 B 21000 B 25900 B 154000 6160 B 25300 B 25900 B 167000 

145 B 395 1290 1100 129 B 430 1190 1200 400 U 400 U 372 B 400 400 U 400 U 185 B 14.9 400 U 400 U 203 B 400 400 U 400 U 24.1 B 400 

2850 B 11600 B 26700 B 48900 2260 B 13000 B 21600 B 53100 

50 U 50 U 50 U 50 50 U 50 U 50 U 50 50 U 50 U 50 U 50 50 U 50 U 50 U 50 

5/1/2009 5/4/2009 5/8/2009

Supply Water Day 5

5/1/2009

Day 0

Tioga County, PA

Day 1

Location J
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

5/1/2009 5/4/2009 5/8/2009

Supply Water Day 5

5/1/2009

Day 0

Tioga County, PA

Day 1

Location J

17800 B 884000 1090000 10700000 21300 B 1120000 1160000 11700000 

588 47900 56700 443000 685 J 58200 J 58600 J 477000 100 U 100 U 100 U 100 100 U 100 U 100 U 100 

1000 U 1000 U 1000 U 1000 1000 U 1000 U 1000 U 1000 

500 U 500 U 23.5 B 50.3 500 U 500 U 500 U 62.5 

50 U 50 U 209 50 

73.9 B J 76.8 B J 665 J 91 52.8 B 45.5 B 378 97.5 0.01 U 0.05 G U 0.086 0.5 0.01 U 0.05 G U 0.15 0.5 

0.2 U 0.056 B 0.2 U 0.043 0.2 U 0.051 B 0.2 U 0.2 

5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 2.6 J 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 

1000 U 1000 U 1000 U 1000 

NA NA NA NA 

5 U 5 U 5 U 5 5 U 5 U 5 U 5 

10 U 10 U 10 U 10 

5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 

20 U 10 J B 10 J B 22 

100 U 100 U 100 U 100 100 U 100 U 100 U 100 

5 U 5 U 5 U 0.99 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 7.8 5.8 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 3.7 J 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

5/1/2009 5/4/2009 5/8/2009

Supply Water Day 5

5/1/2009

Day 0

Tioga County, PA

Day 1

Location J

NA NA NA NA 

5 U 5 U 5 U 5 5 U 5 U 5 U 5 

NA NA NA NA 

5 U 1.3 J 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 5 U 5 U 5 U 5 

15 U 2.6 J 15 U 15 

9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

NA NA NA NA 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 25 9.4 

49 U 1000 U 48 U 47 

9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 

2 U 40 U 0.82 J 1.9 

9.8 U 200 U 7.3 J 9.4 9.8 U 200 U 9.6 U 9.4 

49 U 1000 U 48 U 47 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 4.5 J 9.4 

49 U 1000 U 48 U 47 49 U 1000 U 48 U 47 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

49 U 1000 U 48 U 47 49 U 1000 U 48 U 47 98 U 2000 U 96 U 94 

9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 

9.8 U 200 U 13 1.1 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

200 U 4000 U 190 U 190 

2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 4300 18 17 2 U 40 U 1.9 U 1.9 

9.8 U 200 U 1.2 J 1.6 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 1.6 J 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 0.3 J 5.3 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

5/1/2009 5/4/2009 5/8/2009

Supply Water Day 5

5/1/2009

Day 0

Tioga County, PA

Day 1

Location J

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 1.9 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

20 U 400 U 19 U 19 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 2 U 40 U 1.9 U 0.76 

9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

2 U 40 U 1.9 U 1.9 

9.8 U 200 U 3.2 J 9.4 9.8 U 200 U 9.6 U 9.4 9.8 U 200 U 9.6 U 9.4 

NA NA NA NA 

0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.038 J PG NA NA 

0.048 U 0.049 U NA NA 

0.48 U 0.49 U NA NA 

0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.048 U 0.049 U NA NA 0.096 U 0.098 U NA NA 

1.9 U 2 U NA NA 

0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 0.38 U 0.39 U NA NA 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

5/1/2009 5/4/2009 5/8/2009

Supply Water Day 5

5/1/2009

Day 0

Tioga County, PA

Day 1

Location J

0.95 U 1 U NA NA 

10 UJ NA 10 UJ 13 10 UJ NA 10 UJ 10 10 UJ NA 10 UJ 10 10 UJ NA 10 UJ 10 10 UJ NA 10 UJ 10 

100 UJ NA 100 UJ 100 100 UJ NA 100 UJ 100 

0.15 U NA 0.15 U 10 0.16 U NA 0.16 U 10 0.17 U NA 0.17 U 10 

NA NA NA NA 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

66.7 5 U 5 U 0.01 NR U 0.01 NR U 0.01 U 0

14 16.8 J 29.4 J 

430 650 214 3

18.9 117 185 1

1260 855 1720 2

82 10200 34000 J 16

301 J 197 158 

0.05 U 0.38 1.2 G U 0

104 2100 5100 6

1.6 2.4 1.2 G U 0

0.37 0.32 0.2 0

0.056 1.1 4.8 

4.9 U 4.8 U 4.9 U 

507 J 35700 J 79500 J 68

21.5 J 21.6 J 6.6 B J 0

949 J 124 103 116 J 311 J 245 J 9804 18600 39400 30

47.2 25.2 38 

0.097 B 0.14 0.12 0

26 172 61 5

249 63.8 140 5320 16.7 7.4 B J 

1.6 B 1.6 B 1.6 B 6.3 7.4 6.9 

0.011 0.01 U 0.052 0.00

10.4 8.8 5 U 0.05 U 0.575 0.012 0.07

311 B 420 B J 2000 U 39

2000 U 166 B 205 B 20

16.7 B 34.9 B 33.7 B 1

100 U 36.5 B 21.7 B 1100 U 32.3 B 28.8 B 7100 U 100 U 32.6 B 1

1220 B 251000 893000 10501360 B J 224000 1010000 1020

40 U 40 U 40 U 40 U 40 U 40 U 

71.4 B J 2850 3550 476.4 B J 2590 4170 3

50 U 50 U 50 U 50 U 50 U 50 U 

26600 B J 577000 J 1440000 J 173022900 B J 493000 1590000 2040

50 U 48.1 B 14.6 B 550 U 50 U 6.6 B 

500 U 500 U 500 U 1500 U 500 U 500 U 5250 U 250 U 250 U 4250 U 250 U 250 U 2745 B 18000 33600 1660567 B 11700 34400 268

30 U 70.9 30 U 1

21.2 B 35.7 30 U 

42 B 23600 41800 34

56.3 B 20200 47800 40

4320 B 52000 135000 1853760 B 44800 B 150000 219

33.2 B 519 881 2127.5 B 440 1020 12

400 U 54.4 B 33.1 B 1400 U 42.7 B 34 B 4400 U 176 B 400 U 7400 U 33.4 B 400 U 6

2750 B 35800 B 54600 822790 B 31900 B 64000 81

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

Bradford County, PA

05/07/2009 5/20/2009

Day 0 Day 5 Day 1

5/22/2009

Day 14

6/2/200

Location K
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Bradford County, PA

05/07/2009 5/20/2009

Day 0 Day 5 Day 1

5/22/2009

Day 14

6/2/200

Location K

67800 6630000 11700000 922080700 5830000 J 13200000 J 11000

1310 117000 357000 390

899 J E 99700 J 390000 J 461100 U 100 U 100 U 1100 U 100 U 100 U 1

1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 10

22.3 B J 38.5 B 23.9 B 121.2 B J 39.4 B 39.2 B 5

50 U 50 U 50 U 

99.7 B J 198 B J 147 B J 576.1 B J 109 B J 172 B J 7

0.5 G U 0.1 G U 0.17 B 00.5 G U 0.1 G U 0.17 B 0.0

0.052 B J 0.2 U 0.2 U 

0.46 B J 0.2 U 0.2 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

42 14 7.7 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

20 7.7 5.3 

5U 5U 5U 5U 5U 5U 5U 5U 5U 

1000 U 1000 U 1000 U 10

NA NA NA 

5U 5U 5U 5U 5U 5U 

10 U 10 U 10 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 

6.7 J B 5.9 J 6.9 J 

100 U 100 U 100 U 1100 U 100 U 100 U 1

5 U 5 U 5 U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

1.7 J 5 U 5 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 

3.9 J 5 U 5 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 5 U 5 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Bradford County, PA

05/07/2009 5/20/2009

Day 0 Day 5 Day 1

5/22/2009

Day 14

6/2/200

Location K

NA NA NA 

5U 5U 5U 5U 5U 5U 

NA NA NA 

5 U 5 U 5 U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

35 4.8 J 3 J 

9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

NA NA NA 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

50 U 48 U 47 U 

9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

50 U 48 U 47 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 0

50 U 48 U 47 U 50 U 48 U 47 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

50 U 48 U 47 U 50 U 48 U 47 U 99 U 95 U 94 U 1

9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

200 U 190 U 190 U 2

1.1 J 1.9 U 1.9 U 6.9 1.9 U 1.9 U 

11 1.9 U 1.9 U 

7.4 1.9 U 1.9 U 6.7 1.9 U 1.9 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 

15 B 1.8 J 9.4 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 1.7 J 1.9 U 1.9 U 9.9 U 9.5 U 9.4 U 

12 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 09.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 5 J 9.4 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Bradford County, PA

05/07/2009 5/20/2009

Day 0 Day 5 Day 1

5/22/2009

Day 14

6/2/200

Location K

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

10 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

20 U 19 U 19 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

2 U 1.9 U 1.9 U 

9.9 U 9.5 U 9.4 U 19.9 U 9.5 U 9.4 U 9.9 U 9.5 U 9.4 U 

NA NA NA 

0.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.0

0.49 U NA NA 0

0.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.00.049 U NA NA 0.049 U NA NA 0.00.098 U NA NA 0.0

2U NA NA 

0.39 U NA NA 00.39 U NA NA 00.39 U NA NA 00.39 U NA NA 00.39 U NA NA 00.39 U NA NA 00.39 U NA NA 0
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Bradford County, PA

05/07/2009 5/20/2009

Day 0 Day 5 Day 1

5/22/2009

Day 14

6/2/200

Location K

0.95 U NA NA 0

10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 10 UJ 

100 UJ 100 UJ 100 UJ 1220 J 130 J 100 UJ 1

50 UJ 42 J 39 J 50 UJ 20 UJ 10 UJ 50 UJ 20 UJ 10 UJ 

2300 170 400 1
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 11.4 NA NA 2

0.01 U 0.0097 B 0.01 U 0.01 U 00.25 J 1.5 J 173 192 2

2 U 137 36.3 103 12 G U 10 G U NA NA 11

10 U 490 10700 7600 91

4.1 B 29.9 B NA NA 15101.4 84.3 77 33.1 

0.05 U 0.009 B 2.5 G U 2.5 G U 

18 26 NA NA 950

0.24 B 2.5 U 2.5 G U 2.5 G U 0.24 0.24 0.01 B 0.049 B J 00.21 B 2.5 G U NA 25.9 5

4.6 U 33.2 NA NA 

54.8 J 177 J NA NA 7100

3.8 B 2.9 B 50 G U 50 G U 1.8 86.6 2.2 3.7 6.2 J 9.6 J NA NA 2

51 371 NA NA 2280

2.2 B 31.3 158 178 10.1 U 0.096 B 1.4 0.1 U 

4 U 110 NA NA 4

4.3 254 NA NA 6

10 U 12.5 10 U 10 U 

1.6 B 3 U 3 U 3 U 7.1 6.2 5.9 7.2 

0.01 U 0.0069 B 0.007 B 0.29 0.0

6 12 24.4 11.6 1

0.05 U 0.05 0.241 0.291 0.1

122 B J 180 B J 165 B 131 B 1160 B 239 B 289 B J 188 B J 2

14.6 B 100 U 13.9 B 17.3 B 1

100 U 100 U 16.9 B 20.9 B 1100 U 100 U 100 U 100 U 1100 U 100 U 100 U 100 U 1271 B 579 B 1450000 1730000 19700274 B 621 B 1430000 1760000 19900

40 U 40 U 40 U 40 U 40 U 40 U 40 U 40 U 

2000 U 2000 U 12000 10500 1002000 U 2000 U 11800 11000 97

50 U 50 U 50 U 50 U 50 U 50 U 50 U 1.5 B 

4880 B J 6690 B J 19700000 J 23500000 J 2640003690 B 6080 B 19700000 J 23800000 J 262000

50 U 50 U 15.7 B 50 U 50 U 50 U 50 U 50 U 

500 U 500 U 5000 U 5000 U 50500 U 500 U 5000 U 5000 U 50250 U 44.5 B 255 78.9 B 2250 U 250 U 81.1 B 57.7 B 2605 B 497 B 67200 53100 610543 B 460 B 37600 44800 533

30 U 30 U 30 U 30 U 30 U 30 U 30 U 30 U 

500 U 500 U 129000 137000 1550500 U 28.1 B 126000 J 154000 J 1580

1080 B 1250 B 1320000 1550000 180001440 B 1460 B 1310000 1600000 17400

134 B 127 B 5960 7040 85127 B 130 B 5850 7170 84400 U 400 U 48.2 B 400 U 4400 U 400 U 34.7 B J 400 U 4400 U 19.5 B 400 U 400 U 4400 U 400 U 400 U 400 U 4

50000 U 50000 U 923000 849000 972050000 U 50000 U 1000000 1010000 10100

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

McKean County, PA

Day 5

5/19/2009 6/19

6/6/2009 6/10/2009

Supply Water

5/19/2009

Day 0 Day 1 Da

Location M
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

McKean County, PA

Day 5

5/19/2009 6/19

6/6/2009 6/10/2009

Supply Water

5/19/2009

Day 0 Day 1 Da

Location M

4200 B 32600 B 20600000 17200000 2320003600 B J 34200 B J 31500000 31300000 304000

352 B 768 4330000 4830000 55700340 B J 816 J 4280000 J 4920000 J 53500100 U 100 U 27.2 B 100 U 1100 U 100 U 100 U 100 U 1

1000 U 1000 U 1000 U 1000 U 101000 U 1000 U 1000 U 1000 U 10

500 U 500 U 500 U 500 U 5500 U 29.8 B 500 U 500 U 5

50 U 50 U 50 U 50 U 

56.7 B J 50.2 B J 391 J 270 J 241.1 B J 40.6 B J 314 J 240 J 10.01 U 0.01 G U 0.5 G U 0.5 G U 0.01 U 0.05 G U 0.5 G U 0.5 G U 

0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 5 U 1.6 J 4 J 05U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 5 U 1.2 J 3.3 J 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

1000 U 1000 U 1000 U 1000 U 10

NA NA NA NA 

5U 5U 5U 5U 5 U 3.6 J 5 U 5 U 

10 U 10 U 10 U 10 U 

5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

20 U 20 U 21 18 J 

100 U 100 U 100 U 100 U 1100 U 100 U 100 U 100 U 1

5 U 5 U 3.5 J 3.2 J 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5 U 5 U 5 U 0.63 J 5 U 5 U 5 U 0.53 J 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

McKean County, PA

Day 5

5/19/2009 6/19

6/6/2009 6/10/2009

Supply Water

5/19/2009

Day 0 Day 1 Da

Location M

NA NA NA NA 

5U 5U 5U 5U 5U 5U 5U 5U 

NA NA NA NA 

5 U 5 U 3.8 J 4.8 J 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 

15 U 15 U 3.2 J 6 J 

9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 

NA NA NA NA 

9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 

48 U 50 U 48 U 47 U 

9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 0.28 J 0.26 J 9.6 U 10 U 9.5 U 9.4 U 

48 U 50 U 48 U 47 U 

9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 0.69 J 

48 U 50 U 48 U 47 U 48 U 50 U 48 U 47 U 

9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 

48 U 50 U 48 U 47 U 48 U 50 U 48 U 47 U 96 U 100 U 95 U 94 U 

9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 0.8 J 9.6 U 10 U 2.2 J 2.1 J 9.6 U 10 U 9.5 U 9.4 U 

190 U 200 U 190 U 190 U 1

1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 

6 J 10 U 2.8 J 9.4 U 

9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 2.4 J B 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 1.3 J 9.4 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

McKean County, PA

Day 5

5/19/2009 6/19

6/6/2009 6/10/2009

Supply Water

5/19/2009

Day 0 Day 1 Da

Location M

9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 2.2 J 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 

19 U 20 U 19 U 19 U 

9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 1.9 U 2 U 1.9 U 1.9 U 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 1.9 U 2 U 1.9 U 1.9 U 2.6 J 2 J 140 100 9.6 U 10 U 9.5 U 9.4 U 9.6 U 10 U 9.5 U 9.4 U 

NA NA NA NA 

0.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.0

0.48 U 0.49 U NA NA 0

0.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.05 NA NA 0.00.048 U 0.049 U NA NA 0.00.048 U 0.049 U NA NA 0.0

0.8 PG 0.84 PG NA NA 0.0

0.048 U 0.049 U NA NA 0.00.095 U 0.098 U NA NA 0.0

1.9 U 2 U NA NA 

0.38 U 0.39 U NA NA 00.38 U 0.39 U NA NA 00.38 U 0.39 U NA NA 00.38 U 0.39 U NA NA 00.38 U 0.39 U NA NA 00.38 U 0.39 U NA NA 00.38 U 0.39 U NA NA 0
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

McKean County, PA

Day 5

5/19/2009 6/19

6/6/2009 6/10/2009

Supply Water

5/19/2009

Day 0 Day 1 Da

Location M

0.95 U 0.97 U NA NA 

10 UJ 20 UJ 10 UJ 10 UJ 10 UJ 20 UJ 10 UJ 10 UJ 10 UJ 20 UJ 10 UJ 10 UJ 10 UJ 20 UJ 23 J 21 J 10 UJ 20 UJ 10 UJ 10 UJ 

100 UJ 200 UJ 100 UJ 100 UJ 1100 UJ 200 UJ 100 UJ 100 UJ 1

1 U 100 UJ 10 UJ 500 UJ 1 U 100 UJ 10 UJ 500 UJ 1 U 100 UJ 10 UJ 500 UJ 

57 2300 1100 1200 520
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 48.7 

0.01 U 0.01 NR U 0.01 U 

10 52 135 

924 606 1520 

20 G U 69.8 885 J 

2420 1480 7390 1060 7860 86800 

558 J 271 240 

5 G U 2.5 G U 2.5 G U 

570 25000 36000 

5 G U 2.5 G U 2.5 G U 

0.1 0.18 0.1 U 

5 G U 6.7 19.9 J 

255 4.6 U 40.7 

4000 J 30700 J 261000 J 

100 G U 50 G U 50 G U 575 J 308 237 

66.1 J 114 J 94.2 J 

2670 17400 125000 

89.9 88.8 147 

0.5 21.8 2.3 

5290 4 U 302 

505 152 54.6 

10 U 21.5 5.2 B 

3 U 3 U 3.2 

7.2 6.5 6.5 

0.77 J 0.036 J 0.15 J 47.2 26.8 16.8 0.05 U 0.198 0.0897 

1030 B 1120 B 536 B 

162 B J 274 B 172 B J 100 U 15.8 B 100 U 100 U 15 B 100 U 100 U 48 B 100 U 100 U 28 B 100 U 

72200 387000 13900000 62300 447000 12700000 

40 U 40 U 40 U 40 U 40 U 40 U 

1190 B 808 B 3570 1310 B 944 B 3200 

50 U 50 U 50 U 50 U 50 U 50 U 

123000 J 676000 J 9250000 J 120000 J 800000 J 8200000 J 

17.3 B 37.5 B 33.4 B 

50 U 12.9 B 27.7 B 

500 U 500 U 25000 U 500 U 500 U 25000 U 

79.4 B 250 U 250 U 34.1 B 250 U 250 U 

7400 20900 J 43500 

954 B 18000 38400 

19.4 B 30 U 30 U 

30 U 30 U 30 U 

1800 14200 132000 1930 17300 125000 

14700 B 65700 691000 14800 B 76400 610000 

288 760 J 5550 196 823 4960 

50.6 B J 25.9 B 400 U 58.4 B 24.1 B 400 U 

400 U 48.3 B 400 U 400 U 39.5 B 400 U 

7840 B 33500 B 353000 6850 B 39900 B 284000 

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

Day 0

7/1/2009 7/1/2009

Day 1

Susquehanna County

Day 5 

7/6/2009 0

Location O
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 0

7/1/2009 7/1/2009

Day 1

Susquehanna County

Day 5 

7/6/2009 0

Location O

589000 3920000 34100000 658000 4670000 30900000 

27000 J E 196000 J 2960000 J 28200 J E 233000 J 2660000 J 

100 U 100 U 100 U 

29.5 B 100 U 38 B 

1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 

500 U 33.8 B 500 U 500 U 48.6 B 500 U 

50 U 50 U 33.4 B 

1610 E 244 211 

924 287 J 183 B 

0.1 U 0.1 U 2 G U 

0.05 U 0.1 U 2 G U 

0.2 U 0.2 U 0.2 U 

0.17 B 0.2 U 0.2 U 

50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 67 59 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 

7.7 J 6.7 J 5 U 

50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 

10000 U 5000 U 1000 U 

NA NA NA 

50 U 25 U 5 U 50 U 17 J 5 U 

100 U 50 U 10 U 

50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 

130 J 69 J 20 U 

1000 U 500 U 100 U 1000 U 500 U 100 U 

50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 

820 720 0.5 J 

50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 0

7/1/2009 7/1/2009

Day 1

Susquehanna County

Day 5 

7/6/2009 0

Location O

NA NA NA 

50 U 25 U 5 U 50 U 25 U 5 U 

NA NA NA 

19 J 25 U 0.94 J 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 50 U 25 U 5 U 46 J 26 J 15 U 

190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

NA NA NA 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 940 U 470 U 49 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 260 52 2 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 940 U 470 U 49 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 940 U 470 U 49 U 940 U 470 U 49 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 940 U 470 U 49 U 940 U 470 U 49 U 

1900 U 940 U 98 U 

190 U 94 U 9.8 U 

38 U 19 U 2 U 38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

3800 U 1900 U 200 U 

38 U 19 U 2 U 38 U 19 U 2 U 38 U 19 U 2 U 38 U 19 U 2 U 38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 38 U 19 U 2 U 

190 U 94 U 2.5 J 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Day 0

7/1/2009 7/1/2009

Day 1

Susquehanna County

Day 5 

7/6/2009 0

Location O

190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 38 U 19 U 2 U 38 U 19 U 2 U 38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 38 U 19 U 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 380 U 190 U 20 U 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 38 U 3.5 J 2 U 

190 U 94 U 9.8 U 190 U 94 U 9.8 U 

38 U 19 U 2 U 

190 U 94 U 1.1 J 190 U 94 U 9.8 U 190 U 94 U 9.8 U 

NA NA NA 

0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 

0.11 PG NA NA 

0.051 U NA NA 0.051 U NA NA 

0.51 U NA NA 

0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.051 U NA NA 0.065 PG NA NA 0.051 U NA NA 

0.1 U NA NA 

2U NA NA 

0.41 U NA NA 0.41 U NA NA 0.41 U NA NA 0.41 U NA NA 0.41 U NA NA 0.41 U NA NA 0.41 U NA NA 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Day 0

7/1/2009 7/1/2009

Day 1

Susquehanna County

Day 5 

7/6/2009 0

Location O

1 U NA NA 

20 UJ 10 UJ 10 UJ 20 UJ 10 UJ 10 UJ 

120 J 230 J 110 J 

20 UJ 10 UJ 10 UJ 20 UJ 10 UJ 10 UJ 

200 UJ 200 UJ 100 UJ 200 UJ 200 UJ 100 UJ 

50 UJ 1 U 1 U 50 UJ 1 U 1 U 50 UJ 1 U 1 U 

200 200 300 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 5 U 63.2 

0.01 NR U 0.01 NR U 0.01 NR U 0.01 U 

1.8 16.1 65.4 102 J 

121 184 144 98.1 

4.5 87.9 310 720 

1770 1080 1850 14000 J 

78.1 J 8960 J 33500 71500 1

467 341 J 160 25.8 

0.25 G U 2.5 G U 2.5 G U 2.5 G U 

88 2200 9100 32000 

0.25 G U 2.5 G U 2.5 G U 2.5 G U 0.33 0.51 0.055 B J 0.025 B 0.25 G U 6.5 13.2 19.9 

5 U 4.8 U 4.6 U 4.8 U 

426 J 39800 J 130000 J 249000 J 4

45.3 J 31.8 B J 50 G U 50 G U 

410 J 142 J 46.5 J 24 J 

49 J 338 J 140 J 113 J 

311 16600 38500 120000 2

11.9 24.3 61.7 83.1 

0.034 B 0.16 0.097 B 0.055 B J 

120 9.2 95 62 

20.7 11.7 68.2 10.5 92.4 21.2 72.1 10 U 

4.8 3.2 2.4 B 3 U 6.9 7.5 6.6 6.2 

0.033 J 0.0087 B J 0.018 J 0.01 U 

12.0 12.4 6.4 14.8 

0.501 0.05 U 0.133 0.836 

2000 U 395 B 246 B 640 B 2000 U 190 B 173 B J 737 B 

100 U 24.7 B 100 U 37.2 B J 100 U 25.2 B 100 U 38.5 B J 100 U 100 U 100 U 46.4 B 100 U 100 U 100 U 65 B 227 B 37600 415000 1700000 J 34294 B 43800 401000 1730000 25

40 U 40 U 40 U 40 U 40 U 40 U 40 U 40 U 

2000 U 5110 9070 10400 J 

33.5 B 5840 8500 10800 J 

50 U 50 U 50 U 1.4 B 50 U 50 U 50 U 1.9 B 

27800 B J 641000 J 3120000 J 8790000 18026800 B J 728000 J 2890000 J 8730000 134

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

500 U 500 U 500 U 1000 U 500 U 500 U 500 U 1000 U 

39.7 B 250 U 28.9 B 250 U 35.6 B 250 U 250 U 250 U 

429 B J 5830 J 37500 72700 3

1000 U 5000 30400 72900 2

30 U 14.5 B 30 U 60 U 30 U 14.5 B 30 U 60 U 

500 U 12300 29300 68700 J 1500 U 14300 27000 69100 

6400 B 59800 331000 938000 166090 B 67100 307000 963000 12

8.2 B J 752 J 2300 4790 

150 U 826 2130 4890 400 U 21.1 B 20.6 B J 14.8 B 400 U 24.1 B 400 U 400 U 400 U 400 U 400 U 800 U 400 U 400 U 400 U 800 U 

50000 U 45400 B 187000 265000 8

4110 B 53500 163000 267000 6

50 U 50 U 50 U 50 U 50 U 50 U 50 U 44.2 B 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

Day 5 D

7/1/2009 10/

7/15/2009

Day 14

7/6/2009

Day 0 Day 1

6/30/2009

Westmoreland County, PA

Location Q
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 5 D

7/1/2009 10/

7/15/2009

Day 14

7/6/2009

Day 0 Day 1

6/30/2009

Westmoreland County, PA

Location Q

63200 5400000 1.7E+07 30800000 J 49767900 5960000 1.6E+07 31300000 368

292 B J 86200 J 422000 J 1310000 J 28254 B J 98800 J 396000 J 1300000 J 21100 U 100 U 100 U 200 U 100 U 100 U 100 U 200 U 

1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 22.4 B 1000 U 

500 U 44.5 B 500 U 139 B 500 U 35.4 B 500 U 113 B 

50 U 50 U 50 U 50 U 

37.7 B 78.6 B 156 B 144 B J 2

69 B J 100 B J 159 B 137 B J 1

0.5 G U 0.5 G U 0.1 G U 0.25 G U 0.5 G U 0.5 G U 0.1 G U 0.25 U 0.2 U 0.2 U 0.2 U 0.2 U 

0.095 B 0.2 U 0.2 U 0.2 U 

5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 

1000 U 1000 U 1000 U 10000 U 

NA NA NA NA 

5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 

10 U 10 U 10 U 100 U 

5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 

28 16 J 42 520 

100 U 100 U 100 U 1000 U 100 U 100 U 100 U 1000 U 

5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 4 J 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 5 D

7/1/2009 10/

7/15/2009

Day 14

7/6/2009

Day 0 Day 1

6/30/2009

Westmoreland County, PA

Location Q

NA NA NA NA 

5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 

NA NA NA NA 

5 U 5 U 1.2 J 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 5 U 5 U 5 U 50 U 

15 U 15 U 4.4 J 150 U 

9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

NA NA NA NA 

9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

48 U 48 U 47 U 47 U 

9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

48 U 48 U 47 U 47 U 

9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 0.2 J 9.4 U 

48 U 48 U 47 U 47 U 48 U 48 U 47 U 47 U 

9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

48 U 48 U 47 U 47 U 48 U 48 U 47 U 47 U 95 U 95 U 94 U 94 U 

9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 1.2 J 0.34 J 0.33 J 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

190 U 190 U 190 U 190 U 

1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 4.4 J 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 

10 9.5 U 9.4 U 3.7 J 

9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.1 J 9.5 U 9.4 U 9.4 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Day 5 D

7/1/2009 10/

7/15/2009

Day 14

7/6/2009

Day 0 Day 1

6/30/2009

Westmoreland County, PA

Location Q

9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

19 U 19 U 19 U 19 U 

9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 9.5 U 9.5 U 9.4 U 9.4 U 

NA NA NA NA 

0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 

0.17 PG NA NA 0.047 U 

0.048 U NA NA 0.047 U 

0.26 NA NA 0.047 U 0.48 U NA NA 0.47 U 

0.072 PG NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 0.048 U NA NA 0.047 U 

0.12 NA NA 0.047 U 0.26 PG NA NA 0.047 U 

0.095 U NA NA 0.094 U 

1.9 U NA NA 1.9 U 

0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 0.38 U NA NA 0.38 U 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Day 5 D

7/1/2009 10/

7/15/2009

Day 14

7/6/2009

Day 0 Day 1

6/30/2009

Westmoreland County, PA

Location Q

0.95 U NA NA 0.95 U 

110 J 38 J 28 J 20 J 

20 UJJ 5 UJ 10 UJ 10 UJ 20 UJJ 5 UJ 10 UJ 10 UJ 20 UJ 5 UJ 10 UJ 10 UJ 20 UJ 5 UJ 10 UJ 10 UJ 

200 UJ 100 UJ 100 UJ 100 UJ 200 UJ 100 UJ 100 UJ 100 UJ 

20 UJ 1 U 33 33 J 20 UJ 5 UJ 1 U 10 UJ 20 UJ 1 U 1 U 10 UJ 

300 100 120 600 
PARAMETER UNITS PQL US EPA Method

Conventional AnalysesAcidity mg/L 5 SM20 2310B (4a)Amenable cyanide mg/L 0.01 SM18 4500-CN EAmmonia Nitrogen mg/L 0.1 MCAWW 350.1Biochemical Oxygen Demand mg/L 2 SM18 5210 BBromide mg/L 1 MCAWW 300.0AChemical Oxygen Demand (COD) mg/L 10 MCAWW 410.4Chloride mg/L 1 MCAWW 300.0ADissolved Organic Carbon mg/L -- SM20 5310BFluoride mg/L 1 MCAWW 300.0AHardness, as CaCO3 mg/L 5 SM20 2340CNitrate as N mg/L 0.05 MCAWW 300.0ANitrate-Nitrite mg/L 0.1 MCAWW 353.2Nitrite as N mg/L 0.05 MCAWW 300.0AOil & Grease (HEM) mg/L 5 CFR136A 1664A HEMSpecific Conductance umhos/cm -- MCAWW 120.1

Sulfate mg/L 1 MCAWW 300.0ATOC mg/L 1 SM20 5310BTotal Alkalinity mg/L 5 SM18 2320 BTotal Dissolved Solids mg/L 10 SM18 2540 CTotal Kjeldahl Nitrogen mg/L 3 MCAWW 351.3Total phosphorus mg/L 0.1 MCAWW 365.2Total Suspended Solids mg/L 4 SM20 2540DTurbidity NTU -- MCAWW 180.1Cyanide, Total ug/L 10 SW846 9012ATotal Sulfide mg/L 3 SW846 9030B/9034pH No Units -- SW846 9040Total Recoverable Phenolics mg/L 0.01 SW846 9066Sulfite mg/L 1 SM4500-SO3 BMBAS (mol.wt 320) mg/L 0.05 SM5540 C Total and Dissolved MetalsAluminum ug/L 200 SW846 6010BAluminum-DISS ug/L 200 SW846 6010BAntimony ug/L 10 SW846 6010BAntimony-DISS ug/L 10 SW846 6010BArsenic ug/L 10 SW846 6010BArsenic-DISS ug/L 10 SW846 6010BBarium ug/L 200 SW846 6010BBarium-DISS ug/L 200 SW846 6010BBeryllium ug/L 4 SW846 6010BBeryllium-DISS ug/L 4 SW846 6010BBoron ug/L 2000 SW846 6010BBoron-DISS ug/L 2000 SW846 6010BCadmium ug/L 5 SW846 6010BCadmium-DISS ug/L 5 SW846 6010BCalcium ug/L 5000 SW846 6010BCalcium-DISS ug/L 5000 SW846 6010BChromium ug/L 5 SW846 6010BChromium-DISS ug/L 5 SW846 6010BCobalt ug/L 500 SW846 6010BCobalt-DISS ug/L 500 SW846 6010BCopper ug/L 25 SW846 6010BCopper-DISS ug/L 25 SW846 6010BIron ug/L 100 SW846 6010BIron-DISS ug/L 100 SW846 6010BLead ug/L 3 SW846 6010BLead-DISS ug/L 3 SW846 6010BLithium ug/L 500 SW846 6010BLithium-DISS ug/L 500 SW846 6010BMagnesium ug/L 5000 SW846 6010BMagnesium-DISS ug/L 5000 SW846 6010BManganese ug/L 150 SW846 6010BManganese-DISS ug/L 150 SW846 6010BMolybdenum ug/L 400 SW846 6010BMolybdenum-DISS ug/L 400 SW846 6010BNickel ug/L 40 SW846 6010BNickel-DISS ug/L 40 SW846 6010BPotassium ug/L 5000 SW846 6010BPotassium-DISS ug/L 5000 SW846 6010BSelenium ug/L 5 SW846 6010BSelenium-DISS ug/L 5 SW846 6010BSilver ug/L 5 SW846 6010BSilver-DISS ug/L 5 SW846 6010B

5 U 5 U 5 U 

0.01 U 0.01 U 0.01 U 0.52 J 3 J 2.8 J 

2 U 2220 1440 

0.2 U 0.2 U 0.2 U 

18.4 J 4810 J 3420 J 28.1 58.5 64.2 3

2.3 J 906 J 657 J 

0.05 U 0.05 U 0.077 

156 156 156 

1.8 2.6 2.7 

3 3.1 2.8 

0.05 U 0.06 0.045 B 

4.6 U 158 13.7 

466 J 480 J 479 J 1

8.4 32.6 17.7 2.7 931 672 

88.8 J 109 J 123 J 

277 280 680 5

3 U 42.3 47.5 

0.1 U 0.082 B 0.037 B 

4 U 200 142 

1.7 308 300 

10 U 3.5 B 6.6 B 

3.2 3 U 3 U 

7 7.2 7.9 

0.0065 B 0.044 0.048 

11.2 20 15.2 

0.0969 0.05 U 0.0613 

177 B 623 B 507 B 

2000 U 203 B 165 B 

15.4 B 16.8 B 100 U 

100 U 100 U 13.5 B 100 U 100 U 100 U 100 U 100 U 100 U 840 B 410 B 332 B 65734 B 346 B 240 B 7

40 U 40 U 40 U 40 U 40 U 40 U 

18.9 B 17.8 B 18.1 B 15.8 B 13.8 B 14.2 B 

1.7 B 2.1 B 2.2 B 

2 B 50 U 1.3 B 

40100 B J 35200 B J 35200 B J 40837500 B J 36000 B J 37800 B J 45

50 U 50 U 7.5 B 50 U 50 U 50 U 

500 U 4.4 B 5.7 B 500 U 5.4 B 6.2 B 250 U 109 B 43.9 B 250 U 123 B 37.2 B 394 B 1790 6490 

1000 U 726 B 1670 3

30 U 30 U 30 U 30 U 30 U 30 U 

500 U 42 B 500 U 3

42.1 B 31.1 B 500 U 3

18300 B 15700 B 16000 B 317000 B 16200 B 17300 B 4

8.7 B 37.9 B 146 B 

150 U 30.5 B 119 B 400 U 400 U 14.2 B 400 U 400 U 400 U 400 U 400 U 16.7 B 400 U 400 U 400 U 

2930 B 2420 B 2690 B 303090 B 2590 B 3000 B 35

50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 50 U 

Day 0 Day 

Day 1 

8/25/2009 8/25/2009 8/25/2009 8/29/2

Supply Water

Centre County, PA

Location S
PARAMETER UNITS PQL US EPA Method

Sodium ug/L 5000 SW846 6010BSodium-DISS ug/L 5000 SW846 6010BStrontium ug/L 50 SW846 6010BStrontium-DISS ug/L 50 SW846 6010BThallium ug/L 10 SW846 6010BThallium-DISS ug/L 10 SW846 6010BTin ug/L 1000 SW846 6010BTin-DISS ug/L 1000 SW846 6010BTitanium ug/L 500 SW846 6010BTitanium-DISS ug/L 500 SW846 6010BTrivalent Chrom ug/L 50 SW846 6010BZinc ug/L 20 SW846 6010BZinc-DISS ug/L 20 SW846 6010BDiss Hexavalent Cr-DISS mg/L 0.01 SW846 7196AHexavalent Chromium mg/L 0.01 SW846 7196AMercury ug/L 0.2 SW846 7470AMercury-DISS ug/L 0.2 SW846 7470AVolatile Organic Compounds1,1,1,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,1-Trichloroethane ug/L 5 SW846 8260B1,1,2,2-Tetrachloroethane ug/L 5 SW846 8260B1,1,2-Trichloroethane ug/L 5 SW846 8260B1,1-Dichloroethane ug/L 5 SW846 8260B1,1-Dichloroethene ug/L 5 SW846 8260B1,1-Dichloropropene ug/L 5 SW846 8260B1,2,3-Trichlorobenzene ug/L 5 SW846 8260B1,2,3-Trichloropropane ug/L 5 SW846 8260B1,2,4-Trichlorobenzene ug/L 5 SW846 8260B1,2,4-Trimethylbenzene ug/L 5 SW846 8260B1,2-Dibromo-3-chloropropane ug/L 5 SW846 8260B1,2-Dibromoethane (EDB) ug/L 5 SW846 8260B1,2-Dichlorobenzene ug/L 5 SW846 8260B1,2-Dichloroethane ug/L 5 SW846 8260B1,2-Dichloropropane ug/L 5 SW846 8260B1,3,5-Trimethylbenzene ug/L 5 SW846 8260B1,3-Dichlorobenzene ug/L 5 SW846 8260B1,3-Dichloropropane ug/L 5 SW846 8260B1,4-Dichlorobenzene ug/L 5 SW846 8260B1,4-Dioxane ug/L 1000 SW846 8260B1-chloro-4-trifluoromethylbenzene ug/L -- SW846 8260B2,2-Dichloropropane ug/L 5 SW846 8260B2-Butanone ug/L 5 SW846 8260B2-Chloroethyl vinyl ether ug/L 10 SW846 8260B2-Hexanone ug/L 5 SW846 8260B4-Chlorotoluene ug/L 5 SW846 8260B4-Methyl-2-pentanone (MIBK) ug/L 5 SW846 8260BAcetone ug/L 20 SW846 8260BAcrolein ug/L 100 SW846 8260BAcrylonitrile ug/L 100 SW846 8260BBenzene ug/L 5 SW846 8260BBenzyl chloride ug/L 5 SW846 8260BBromobenzene ug/L 5 SW846 8260BBromodichloromethane ug/L 5 SW846 8260BBromoform ug/L 5 SW846 8260BBromomethane ug/L 5 SW846 8260BCarbon disulfide ug/L 5 SW846 8260BCarbon tetrachloride ug/L 5 SW846 8260BChlorobenzene ug/L 5 SW846 8260BChloroethane ug/L 5 SW846 8260BChloroform ug/L 5 SW846 8260BChloromethane ug/L 5 SW846 8260Bcis-1,2-Dichloroethene ug/L 5 SW846 8260Bcis-1,3-Dichloropropene ug/L 5 SW846 8260BDibromochloromethane ug/L 5 SW846 8260BDibromomethane ug/L 5 SW846 8260BDichlorodifluoromethane ug/L 5 SW846 8260BEthylbenzene ug/L 5 SW846 8260BIsopropylbenzene ug/L 5 SW846 8260BMethyl tert-butyl ether (MTBE) ug/L 5 SW846 8260BMethylene chloride ug/L 5 SW846 8260BNaphthalene ug/L 5 SW846 8260Bn-Butylbenzene ug/L 5 SW846 8260Bn-Propylbenzene ug/L 5 SW846 8260Bp-Isopropyltoluene ug/L 5 SW846 8260Bsec-Butylbenzene ug/L 5 SW846 8260BStyrene ug/L 5 SW846 8260B

Day 0 Day 

Day 1 

8/25/2009 8/25/2009 8/25/2009 8/29/2

Supply Water

Centre County, PA

Location S

37700 B 60800 63800 164035300 B 71800 69200 1800

723 E 597 580 156653 J E 624 J 594 J 17100 U 100 U 100 U 100 U 100 U 100 U 

1000 U 1000 U 1000 U 1000 U 1000 U 1000 U 

500 U 500 U 500 U 500 U 500 U 500 U 

50 U 50 U 50 U 

172 B J 164 B J 138 B J 156 B J 140 B J 73.8 B J 

0.01 U 0.0078 B 0.05 G U 0.01 U 0.05 G U 0.05 G U 

0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 

5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 11 33 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 2.8 J 13 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 

1000 U 1000 U 1000 U 

NA NA NA 

5 U 5 U 5 U 5 U 5 U 5 U 

10 U 10 U 10 U 

5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 

20 U 5.4 J 14 J 

100 U 100 U 100 U 100 U 100 U 100 U 

5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 0.81 J 1.8 J 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 1.8 J 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 
PARAMETER UNITS PQL US EPA Method

tert-butyl acetate ug/L -- SW846 8260Btert-Butylbenzene ug/L 5 SW846 8260BTetrachloroethene ug/L 5 SW846 8260Btetrahydrofuran ug/L -- SW846 8260BToluene ug/L 5 SW846 8260Btrans-1,2-Dichloroethene ug/L 5 SW846 8260Btrans-1,3-Dichloropropene ug/L 5 SW846 8260BTrichloroethene ug/L 5 SW846 8260BTrichlorofluoromethane ug/L 5 SW846 8260BVinyl acetate ug/L 5 SW846 8260BVinyl chloride ug/L 5 SW846 8260BXylenes (total) ug/L 15 SW846 8260BSemi-Volatile Organics1,2,4,5-Tetrachlorobenzene ug/L 10 SW846 8270C1,2-Diphenylhydrazine ug/L 2 SW846 8270C1,3-Dinitrobenzene ug/L 10 SW846 8270C1,4-Naphthoquinone ug/L 10 SW846 8270C1-Naphthylamine ug/L 10 SW846 8270C2,3,4,6-Tetrachlorophenol ug/L 10 SW846 8270C2,3,7,8-TCDD ug/L -- SW846 8270C2,4,5-Trichlorophenol ug/L 10 SW846 8270C2,4,6-Trichlorophenol ug/L 10 SW846 8270C2,4-Dimethylphenol ug/L 10 SW846 8270C2,4-Dinitrophenol ug/L 40 SW846 8270C2,4-Dinitrotoluene ug/L 10 SW846 8270C2,6-Dichlorophenol ug/L 2 SW846 8270C2,6-Dinitrotoluene ug/L 10 SW846 8270C2-Acetylaminofluorene ug/L 10 SW846 8270C2-Chloronaphthalene ug/L 2 SW846 8270C2-Chlorophenol ug/L 10 SW846 8270C2-Methylnaphthalene ug/L 2 SW846 8270C2-Methylphenol ug/L 10 SW846 8270C2-Naphthylamine ug/L 10 SW846 8270C2-Nitroaniline ug/L 50 SW846 8270C2-Nitrophenol ug/L 10 SW846 8270C2-Picoline ug/L 10 SW846 8270C3,3'-Dichlorobenzidine ug/L 10 SW846 8270C3-Methylcholanthrene ug/L 10 SW846 8270C3-Methylphenol & 4-Methylphenol ug/L 10 SW846 8270C3-Nitroaniline ug/L 50 SW846 8270C4,6-Dinitro-2-methylphenol ug/L 50 SW846 8270C4-Aminobiphenyl ug/L 10 SW846 8270C4-Bromophenyl phenyl ether ug/L 10 SW846 8270C4-Chloro-3-methylphenol ug/L 10 SW846 8270C4-Chloroaniline ug/L 10 SW846 8270C4-Chlorophenyl phenyl ether ug/L 10 SW846 8270C4-Nitroaniline ug/L 50 SW846 8270C4-Nitrophenol ug/L 50 SW846 8270C5-Nitro-o-toluidine ug/L 100 SW846 8270C7,12-Dimethylbenz(a)anthracene ug/L 10 SW846 8270CAcenaphthene ug/L 2 SW846 8270CAcenaphthylene ug/L 2 SW846 8270CAcetophenone ug/L 10 SW846 8270CAniline ug/L 10 SW846 8270CAramite ug/L 10 SW846 8270CBenzidine ug/L 200 SW846 8270CBenzo(a)anthracene ug/L 10 SW846 8270CBenzo(a)pyrene ug/L 5 SW846 8270CBenzo(b)fluoranthene ug/L 2 SW846 8270CBenzo(ghi)perylene ug/L 2 SW846 8270CBenzo(k)fluoranthene ug/L 2 SW846 8270CBenzyl alcohol ug/L 10 SW846 8270Cbis(2-Chloroethoxy)methane ug/L 10 SW846 8270Cbis(2-Chloroethyl) ether ug/L 2 SW846 8270Cbis(2-Chloroisopropyl) ether ug/L 2 SW846 8270Cbis(2-Ethylhexyl) phthalate ug/L 10 SW846 8270CButyl benzyl phthalate ug/L 10 SW846 8270CChlorobenzilate ug/L 10 SW846 8270CChrysene ug/L 2 SW846 8270CDiallate ug/L 10 SW846 8270CDibenz(a,h)anthracene ug/L 2 SW846 8270CDibenzofuran ug/L 10 SW846 8270CDiethyl phthalate ug/L 10 SW846 8270CDimethoate ug/L 10 SW846 8270CDimethyl phthalate ug/L 10 SW846 8270CDi-n-butyl phthalate ug/L 10 SW846 8270C

Day 0 Day 

Day 1 

8/25/2009 8/25/2009 8/25/2009 8/29/2

Supply Water

Centre County, PA

Location S

NA NA NA 

5 U 5 U 5 U 5 U 5 U 5 U 

NA NA NA 

5 U 1.6 J 3.8 J 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 

15 U 5.4 J 16 

9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

NA NA NA 

9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

47 U 47 U 47 U 

9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

47 U 47 U 47 U 

9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

47 U 47 U 47 U 47 U 47 U 47 U 

9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

47 U 47 U 47 U 47 U 47 U 47 U 94 U 94 U 94 U 

9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

190 U 190 U 190 U 

1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 J B 14 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 0.6 J 2 J 9.4 U 
PARAMETER UNITS PQL US EPA Method

Di-n-octyl phthalate ug/L 10 SW846 8270CDinoseb ug/L 10 SW846 8270CDiphenylamine ug/L 2 SW846 8270CDisulfoton ug/L 10 SW846 8270CEthyl methanesulfonate ug/L 10 SW846 8270CFluoranthene ug/L 2 SW846 8270CFluorene ug/L 2 SW846 8270CHexachlorobenzene ug/L 0.05 SW846 8270CHexachlorobutadiene ug/L 2 SW846 8270CHexachlorocyclopentadiene ug/L 2 SW846 8270CHexachloroethane ug/L 10 SW846 8270CHexachloropropene ug/L 10 SW846 8270CIndeno(1,2,3-cd)pyrene ug/L 2 SW846 8270CIsodrin ug/L 10 SW846 8270CIsophorone ug/L 10 SW846 8270CIsosafrole ug/L 10 SW846 8270CMethyl methanesulfonate ug/L 10 SW846 8270CNitrobenzene ug/L 2 SW846 8270CN-Nitrosodiethylamine ug/L 10 SW846 8270CN-Nitrosodimethylamine ug/L 10 SW846 8270CN-Nitrosodi-n-butylamine ug/L 10 SW846 8270CN-Nitrosodi-n-propylamine ug/L 2 SW846 8270CN-Nitrosodiphenylamine ug/L 2 SW846 8270CN-Nitrosomethylethylamine ug/L 10 SW846 8270CN-Nitrosomorpholine ug/L 10 SW846 8270CN-Nitrosopiperidine ug/L 10 SW846 8270CN-Nitrosopyrrolidine ug/L 10 SW846 8270CO,O,O-Triethyl phosphorothioate ug/L 10 SW846 8270Co-Toluidine ug/L 10 SW846 8270CParathion ug/L 10 SW846 8270Cp-Dimethylaminoazobenzene ug/L 10 SW846 8270CPentachlorobenzene ug/L 10 SW846 8270CPentachloroethane ug/L 20 SW846 8270CPentachloronitrobenzene ug/L 10 SW846 8270CPentachlorophenol ug/L 10 SW846 8270CPhenanthrene ug/L 2 SW846 8270CPhenol ug/L 2 SW846 8270CPhorate ug/L 10 SW846 8270CPronamide ug/L 10 SW846 8270CPyrene ug/L 2 SW846 8270CPyridine ug/L 10 SW846 8270CSafrole ug/L 10 SW846 8270CThionazin ug/L 10 SW846 8270CTetraethyldithiopyrophosphate ug/L 10 SW846 8270COrganochlorine Pesticides4,4'-DDD ug/L 0.05 SW846 8081A4,4'-DDE ug/L 0.05 SW846 8081A4,4'-DDT ug/L 0.05 SW846 8081AAldrin ug/L 0.05 SW846 8081Aalpha-BHC ug/L 0.05 SW846 8081Abeta-BHC ug/L 0.05 SW846 8081AChlordane (technical) ug/L 0.05 SW846 8081Adelta-BHC ug/L 0.05 SW846 8081ADieldrin ug/L 0.05 SW846 8081AEndosulfan I ug/L 0.05 SW846 8081AEndosulfan II ug/L 0.05 SW846 8081AEndosulfan sulfate ug/L 0.05 SW846 8081AEndrin ug/L 0.05 SW846 8081AEndrin aldehyde ug/L 0.05 SW846 8081AEndrin ketone ug/L 0.05 SW846 8081Agamma-BHC (Lindane) ug/L 0.05 SW846 8081AHeptachlor ug/L 0.05 SW846 8081AHeptachlor epoxide ug/L 0.05 SW846 8081AMethoxychlor ug/L 0.1 SW846 8081AToxaphene ug/L 2 SW846 8081APCBsAroclor 1016 ug/L 0.4 SW846 8082Aroclor 1221 ug/L 0.4 SW846 8082Aroclor 1232 ug/L 0.4 SW846 8082Aroclor 1242 ug/L 0.4 SW846 8082Aroclor 1248 ug/L 0.4 SW846 8082Aroclor 1254 ug/L 0.4 SW846 8082Aroclor 1260 ug/L 0.4 SW846 8082

Day 0 Day 

Day 1 

8/25/2009 8/25/2009 8/25/2009 8/29/2

Supply Water

Centre County, PA

Location S

9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

1.9 U 1.9 U 1.9 U 1.9 U 2 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

19 U 19 U 19 U 

9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 3.4 3.5 1.9 U 1.9 U 1.9 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 1.9 U 0.76 J 0.89 J 9.4 U 70 18 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 9.4 U 

NA NA NA 

0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 

0.47 U 0.47 U NA 

0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.047 U NA 0.047 U 0.041 J NA 0.051 0.063 NA 0.047 U 0.047 U NA 0.094 U 0.094 U NA 

1.9 U 1.9 U NA 

0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 0.38 U 0.38 U NA 
PARAMETER UNITS PQL US EPA Method

Organophosphorus PesticidesEthyl parathion ug/L 0.4 SW846 8141AAlcohols

2-Propanol mg/L 10 SW846 8015Butyl alcohol mg/L 10 SW846 8015Ethanol mg/L 10 SW846 8015Methanol mg/L 10 SW846 8015n-Propanol mg/L 10 SW846 8015GlycolsEthylene Glycol mg/L 50 SW846 8015Propylene glycol mg/L 50 SW846 8015

Acids

Acetic Acid mg/L 10 SW846 8015Butyric Acid mg/L 10 SW846 8015Propionic Acid mg/L 10 SW846 8015Volatile Acids mg/L 10

Day 0 Day 

Day 1 

8/25/2009 8/25/2009 8/25/2009 8/29/2

Supply Water

Centre County, PA

Location S

0.94 U 0.95 U NA 

10 U 310 150 J 10 U 20 U 20 UJ 10 U 20 U 20 UJ 10 U 20 U 20 UJ 10 U 20 U 20 UJ 

100 U 200 U 200 UJ 100 U 240 200 UJ 

1 U 50 U 1.4 1 U 50 U 1 U 1 U 50 U 1 U 

15 150 75