AECOM 

Appendix D 

Laboratory Data 

r 

VES018093 
Metho d 5/26 A 

VES01809 
AECOM Report Environment 

Case Narrative 

Re.: Gravimetric Analysis of Filter and Front Half Probe Rinse Samples - Veolia ES Tech, 

Sauget, IL 

Project #: 60133216 

LAB ID #: 09-064, 09-067, 09-069 

ANALYTICAL PROCEDURE: 

Eleven (11) Teflon® type filters and 12 front half acetone rinse samples were 

analyzed via EPA Method 5 Gravimetric Analysis as governed by AECOM's SOP 

2629-300. 

Consecutive gravimetric weights of filters and beaker residues were taken with an 

annually calibrated Mettler balance, and weighed within specified limits as outlined 

in EPA Method 5 and AECOM's SOP 2629-300. 

1. For two of three shipments received, 09-067 and 09-069, one field blank of 

both filter and acetone were analyzed as specified by EPA Method 5 

Gravimetric Analysis and AECOM's SOP 2629-300. The first set of samples, 

09-064, contained one acetone blank, but no filter blank was received. 

2. Laboratory blanks of both filter and acetone were analyzed for each of the 

three sets of samples per the same Method and SOP as listed above. 

1. For the first set of samples received, Lab ID: 09-064, two of the acetone 

sample bottles, M5-Acetone-RB and M5-U3-AR-R3, did not have the level of 

acetone marked on the bottle. Additionally, following evaporation of the first 

of these two samples, i.e. the field blank, a moist, oily-appearing residue was 

observed in the sample beaker. The gravimetric result for that sample 

indicated a net gain of 1.9 mg. 

2. For the third set of samples, Lab ID: 09-069, one of the acetone rinse sample 

bottles, M5-U4-FHR-R2, was found to contain a piece of aluminum foil, which 

was removed during the acetone rinse procedure and prior to weighing. 

QUALITY CONTROL: 

DISCUSSION: 

Date Samples Received by the Laboratory: 12/04, 12/11 & 12/21/09 

Date Analysis Started: 12/07/09 

R:\AirDBase\M5DBWIethod 5 DatabaseWETHOD 5 CLIENT FILESWeolia\09-064_067_069_CaseNarrative.doc 

Page 2 of 14 
j AECOM 

i 

Method 5 Exposed Filter Data Sheet 

Balance Used: Mettler 3 

Project Manager: 

Project Name: 

Project Number: 

Analysis Method: 

Project Manager: Jeff Gorman Day Dale Time R.H.(%)";, R.T.CF) Analyst j 

Project Name: 

Project Number: 

Analysis Method: 

Veolia Start Tuesday 12/15/2009 9:00 41 58 WV 

Project Manager: 

Project Name: 

Project Number: 

Analysis Method: 

60133216 Wt, 1 Wednesday 12/16/2009 9.00 38 68 MW 

Project Manager: 

Project Name: 

Project Number: 

Analysis Method: Oven Dried Wt. Z Friday 12/18/2009 16:30 33 68 AC 

Project Manager: 

Project Name: 

Project Number: 

Analysis Method: 

Wt. 3 

Wt. 4 

vQAsSheet:-

Paaoff 

, X, Initial Weight ' . 

Filler #_, 

Sample 

RunDate Sample ID 

' Hltef- . 

Typa/Size 

1st Wt. 

Grams 

2nd Wt. 

• Grams 

A 1&2 Wt. 

Grams -

' 3rdWt, 

Grams 

A2&3 Wti: 

Grams 

41hWt. 

Grams 

A 38.4 Wt. 

Grams 

Final Wt. 

Grams 

A FW-IW 

Total Grams 

vQAsSheet:-

Paaoff •ate Grams, - Filler #_, 

Sample 

RunDate Sample ID 

' Hltef- . 

Typa/Size 

1st Wt. 

Grams 

2nd Wt. 

• Grams 

A 1&2 Wt. 

Grams -

' 3rdWt, 

Grams 

A2&3 Wti: 

Grams 

41hWt. 

Grams 

A 38.4 Wt. 

Grams 

Final Wt. 

Grams 

A FW-IW 

Total Grams 

88 11/25/09 0.3926 T1828 — Lab Blank 82.6 0.3927 0.3927 0.0000 ok by Wt. 0.3927 0.0003 

87 11/25/09 0.4060 T1812 12/10/09 M5-Filter Blank 82.6 0.4059 0.4058 0.0001 okbyWt. 0.4059 0.0003 

88 11/25/09 0.4137 T1820 12/08/09 M5-U2-F-R1 82.6 0.4142 0.4143 0.0001 ok by Wt. 0.4143 0.0006 

87 11/25/09 0.3971 T1811 12/09/09 M5-U2-F-R2 82.6 0.3982 0.3981 0.0001 ok by Wt. 0.3982 0,0011 

87 11/25/09 0.3979 T1810 12/10/09 M5-U2-F-R3 82.6 0.3984 0.39B4 0.0000 ok byWt. 0.3984 0.0003 

o 

Filter Type; G=Glass ^^T^wjiff i Q=Quartz 

1. Delta Weight tolerance +i- O.OOOSg of total weight less tare weight between two consecutive weightings or average weight. 

2. Filters must be weighed with Uie proper conditions (RH = 25-50 % and RT = 59-78 deg f) 

3. Fillers must be properly conditioned (2& hour desiccation; Further Conditioning > 6 hours). 

4. Conditioning for oven method; Oven dried at 105 deg c fo 2-3 hours; Further conditioning > 6 hours, 

5. Total grams below or equal to .0005 (LDL) is presented as .0003. 

Veolia J)9-067__60133216 email.xls 

VES018096 
AECOM 

Method 5 Front Half Acetone Probe Rinse Data Sheet 

Jeff Gorman 

Balance Used: 

Project Manager: 

Project Name: 

Project Number: 

Analysis Method: 

Veolia 

60133216 

'Heat Aopllcatlgn 

Cay Date Time ;R.H.(%) . R.T.<°F) . Analyst 

Start Thursday 12/17/2009 10:30 34 67 RB 

Wt. 1 Friday 12/18/2009 16:23 33 68 AC 

Wt. 2 Monday 12/21/2009 8:45 33 68 WV 

Wt. 3 Tuesday 12/22/2009 10:32 32 68 PT 

Wt. 4 

GA Sheet 

PageT Beaker #. 

•Sample 

Run Date' Sample 10 

Field 

mL' 

Lab 

mL 

1st Wt. 

Grams; 

2nd Wt, 

: Grams 

•41&2Wt. 

Grams 

3rd Wt. 

Grams 

A2BWL. 

Grams 

4th Wt. 

Grams. 

A3&4Wt. 

Grams 

Final Wt. 

Grams 

485 12/11/09 110.4412 457 Lab blank 110.4414 110.4421 0.0007 110.4416 ok by Wt. 

485 12/11/09 90.5580 M5-Acetone-R8-U2 ok by Wt. 90.5579 

485 12/11/09 97.5228 M5-U2-AR-R1 97.5242 97.5249 0.0007 97.5244 ok by Wt. 

12/11/09 94.9358 361 12/09/09 M5-U2-AR-R2 94.9382 94.9386 0.0004 ok by Wt. 94.9384 

485 12/11/09 106.1784 409 12/10/09 M5-U2-AR-R3 70 50 106.1798 106.1801 0.0003 ok by Wt. 106.1800 

Acetone Manufacturer/Lot No.: Rsher/092950__ 

Acetone Rinse = 25 mis twice - (50 mis total) 

1. Delta Weigh! tolerance +l~ 0.0005g of total weight less tare weight between two consecutive weightings Dr average weight. 

2. Beakers must be weighed with the proper conditions (RH = 25 - 50 % and RT = 50-78 deg f) 

3. Beakers must be properly conditioned (24 hour desiccation: Further Conditioning > 6 hours). 

4. Natural Evaporation Method = Evaporate to dryness at room temperature under a hood / watch glass cover 

5. Heat Application = Under a hcod and watch glass over sample, apply heat below the boiling point cf sample until evaporated to 25 mis: then follow step 4 {above) for remaining portion 

6. Total grams below or equaf to .0005 (LDL) Is presented as .0003. 

VES018097 
SAMPL E LOG-I N & RECEIP T CHECKLIS T 

Client/Proj#_ 

Project Mqr: O^'fi ^ £?<£>r i^nA^ Lab Pool #: 09-1^7 

Inspected & Logged in by:_ Date & Tme-Mifa 

lis KMaiys iSMig 

H 

Du'ei/^/^ f 

Due: lil^tU 

HT: 

Due: 

Circle the appropnate response: 

1) $Jtippe$ J Hand delivered 

2) COC p^seEri / not present on receipt 

3) Samples broken / leaking /<Jrjtac£) on receipt 

4) Samples ^^^gjit / chilled on receipt 

5) Samples preserved correctly / incorrectly ^^e^recommended 

6) ReceivedCw|[^/ outside holding time 

7) COC tapes present / gfitjjjj^sent on samples / NA 

9) DiscrepanciesiN^JpS-iscrepancies noted between COCs and samples 

Additional Comments: -

61 

Pag e 13 o f 1 4 

8/26/2O08 
Sampl e Traceabilst y Lis t 

Site of Program: Veolia E S Tec h Sample Date: rZ-lo-o<j - ii- A - 0<i Projec t Location: Ssuge i It P.O. #: 

Type of Program: CP T Date Shipped: | V~lo-ot Laboratory : AECO M Eiwh oilmen-. 

Projec t #: 60133216 

Program Office: Syracus e N Y 

Shipper / Steven Milo 

Recovery: si> **• f \««u ^ ("Jeff Gorma n 

Laboratory : AECO M Eiwh oilmen-. 

Program Contact: Jeff Gorma n FedEx Air Bill #: 

Item Sampl e ID Cod e Sample Matrix Sampl e Description Analitical Parameters Special Instructions 

1 M5-U2-F-R1 Filter WIS, Filter, Run 1 Particular- M^lor O T- ac 7 - ^T. 

2 MS-U2-AR-R 1 Acetone iM5, F M Acetone Rinsa, Run ! Paniculate tviaiiot' ry?~ O'-">-. -

3 

4 M5-U2-F-R2 Filter WIS, Filter, Ru n 2 Particulate twsilni O

c

?~Q6"?~ -T 

5 M5-U2-AR-R 2 Acetone M S, F H .Acetone Rinse, Ru n Z Pintliculatt; iviaUei O

c

'"Oz ',-~ 

6 

7 W15-U2-F-R3 Filter WIS, Filter, Run 3 Particulate Mailoi 

8 iW!5-U2-AR-R3 Acstone M 5 , F H Acetone Rinss , Run .: Pariiculsit.- ivisfi^v 

9 

10 

11 

12 

13 

14 

15 

16 

17 

18 • 

19 o

1

" ' -o<r~"-- / 

20 (yi5-Acetone-RB-U2 Acetone M5-Acetone Blank particulate Waiter 

Field Notes/ Comment s 

Pag e of 

Relinquished By (print): Date: 

Signature: Time: 

^Ad a \1oO 

Relinquished By (print): Date: 

Signature: Time: 

Relinquished By (print): Date: 

Signature: Time: 

Received by Lab (print): Date: 

Signature: Time: 

Received By (print): Date: 

Signature: Time: 

Received By (print): Date: 

Signature: Time: 

Received By (print): Date: 

Signature: Time: 

Analytical Laboratory Destination: 

AECO M Environment 

325 Aye r Roa d 

Harvard, M A 01451 

Attn: Mr. Pau l Taverna (978) 772-2345 Ext 32 

VES018099 
TestAmerica Laboratories, Inc. 

ANALYTICAL REPORT 

PROJECT NO. 60133216 

Veoli a - ES Tech. 

L ot #: H9L140402 

Jef f Gorman 

AECOM, Inc 

5105 Caiqpuswood Drive 

Suite 104 

East Syracuse, NY 13057 

TESTAMERICA LABORATORIES, XHC. 

Kevin S. Woodcock 

Project Manager 

December 17, 2009 

S815 Middlebrook Pike Knoxville,TN3792t tel 865.291.3000 fax865.584.4315 www.testamericainc.com 

VES01810 
ANALYTICAL METHODS SUMMARY 

H9L140402 

ANALYTICAL 

PARAMETER —

 METH0 P 

Chlorine Emissions KNOX 00S0/2SA Mod 

Hydrogen Chloride Emissions KNOX 0050/26A Mod 

References: 

KNOX TestAmerica Laboratories Inc., Knoxville Laboratory Standard 

Operating Procedure 
3 

SAMPLE SUMMARY 

H9L140402 

WO # SAMPLE# CLIENT SAMPLE ID 

SAMPLED SAMP 

DATE TIME 

LQ2RG 

LQ2RK 

LQ2RM 

LQ2RN 

LQ2RV 

LQ2RW 

LQ2R1 

LQ2R2 

LQ2R3 

001 

002 

003 

004 

005 

006 

007 

008 

009 

CPT-HCL-FB-U2 

CPT-CL2-FB-U2 

CPT-U2-HCL-IMP1- 4-RIA 

CPT-U2-CL2-IMP5-6-Rl 

CPT-U2-CL2-IMP1-4-R2A 

CPT-TJ2-CL2-IMP5-6-R2 

CPT-U2-HCL-IMP1-4-R3A 

CPT-U2-CL2-IMP5-6-R3 

CPT-H20-U2-FB 

12/08/09 

12/08/09 

12/09/09 

12/09/09 

12/10/09 

12/10/09 

12/06/09 

12/08/09 

12/08/09 

HOTE(S): 

- The analytical results of lite samples listed above ate presented on the following pages. 

• All calculations are performed before rounding to avoid round-off errors in calculated results. 

- Results noted as "ND" were not detected at or above the stated limit. 

- This report must not be reproduced, ctccpt in full, without the written approval of die laboratory. 

- Kcsults lor lite following parameters are never reported on a dry weight basis: color, corrosiviiy. density, (lashpoini. iEniiabtlliy, layers, odor, 

palm filler test. pH. porosity pressure, rcaciivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight. 

VES01810: 
PROJECT NARRATIVE 

H9L140402 

The results reported herein are applicable to the samples submitted for analysis only. 

This report shall not be reproduced except in foil, without the written approval of the 

laboratory. 

The original chain of custody documentation is included with this report. 

Sample Receipt 

Custody seals were not present. 

Quality Control and Data Interpretation 

Unless otherwise noted, all holding times and QC criteria were met and the test results 

shown in this report meet all applicable NELAC requirements. 

Samples were analyzed for chloride by ion chromatography using SOP number ICNOXWC-005 (based on EPA methods 9056, 9057 and 26A). All sample results were reported 

as total ug hydrogen chloride (HCI) and total ug chlorine (Cb). Results were calculated 

using tlie foUowing equations: 

Cl 2, ug = (Chloride, ug / mL)* (Sample Volume, mL)* Bench Dilution 

NaOH impinger samples were treated with sodium thiosulfate (Na^SzOj) prior to the final 

analysis in order to convert residual hypochlorite (OCT) to chloride ion. 

Note: A sample volume of 100 mL was used to convert the results to total ug for the 

method blanks, laboratory control samples, and client reagent blanks in order to 

standardize the analyte sample total. 

TestAmericii Knoxville maintains the following certifications, approvals and accreditations: Arkansas DEQ Lab #88-

0688, California DHS ELAP Cert. #2423, Colorado DPHE, Connecticut DPH Lab //PH-0223, Florida DOH Lab 

#E87177, Georgia DNR Lab #906, Hawaii DOH, Illinois EPA Lab #200012, Indiana DOH Lab #C-TN-02, Iowa DNR 

Lab #375, Kansas DHE Ceru #E-)0349, Kentucky DEP Lab #90101, Louisiana DEQ Cert. #03079, Louisiana DOHH, 

Maryland DOE Cert. #277, Michigan DEQ Lab #9933, Nevada DEP, New Jersey DEP Lab #TN001, New York DOH 

Lab #10781, North Carolina DPH Lab #21705, North Carolina DEHMR Cert. #64, Ohio EPA VAP Lab «CL0059, 

Oklahoma DEQ Lab #9415, Pennsylvania DEP Lab #68-00576, South Carolina DHEC Cen #84001001, Tennessee 

DOH Lab #02014, Texas CEQ, Utah DOH LabS QUAN3, Virginia DGS Lab #00165. Washingion DOE Lab #C1314, 

West Virginia DEP Cert. #345, West Virginia DHHR Cert S9955C, Wisconsin DNR Lab #998044300, Naval Facilities 

Engineering Service Center and USDA Soil Permit #S-46424. This list of approvals is subject to change and does not 

imply that laboratory certification is available for all parameters reported in this environmental sample data report. 

HCi, ug = (Chloride, ug/ mL)* (Sample Volume, mL) 

Molecular Weight HCp 

Molecular Weight Cl 

* Bench Dilution 
PROJECT NARRATIVE 

H9L140402 

For demonstration of analytical method perfonnance on these samples, TestAmerica 

Knoxville analyzed matrix spikes (MS) and matrix spike duplicates (MSD). Acceptable 

recoveries of these spikes demonstrate that quantitation from this particular stack gas 

matrix is accurate and acceptable. Impinger samples containing O.IN H2SO4 and 0.1N 

NaOH display matrix interference effects causing poor metliod performance and possibly 

giving unreliable data unless the interference is removed. Therefore, the samples were 

diluted in the lab to remove the interference for a more accurate chloride response. The 

samples may be analyzed at increasing dilutions along with matrix spikes until matrix 

spikes recover from the sample within laboratory control limits. The ion chromatograph 

calibration range used to quantitate the sample results permits a standard ten-fold sample 

dilution while supporting the reporting limit with the low calibration standard. 

The dilution factor reported on tlie sample result form does not represent the bench 

dilution factor. It is actually the combination of factors required by the method to convert 

the anion reporting limit and method detection limit from ug/mL to total ug. It may 

appear to be elevated because it includes the total sample volume in mL. 
6 

QC DATA ASSOCIATION SUMMARY 

H9L140402 

Sample Preparation and Analysis Control Numbers 

SAMPLES MATRIX 

ANALYTICAL 

METHOD 

LEACH 

BATCH # 

PREP 

BATCH # MS RUN# 

001 AIR KNOX 0050/2SA Mod 9349122 9349107 

002 AIR KNOX 00SO/26A Mod 9350153 9350127 

003 AIR KNOX 0050/26A Mod 9349122 9349107 

004 AIR KNOX O0SO/26A Mod 93S0153 9350127 

005 . AIR KNOX 0050/26A Mod 9349122 9349107 

OOS AIR KNOX 0050/26A Mod 9350153 9350127 

007 AIR KNOX 005O/26A Mod 9349122 9349107 

008 AIR KNOX 00SO/2SA Mod 9349122 9349107 

009 AIR KNOX 0050/26A Mod 9350153 9350127 

VES01810 
7 

Sample Data Summary 

VES01810 
8 

AECOM, lac 

Clien t Sainple ID: CPT-TT2-HCL-IMP1-4-R1A 

General Chemistry 

Lot-Sairtple #. ..: H9L14Q402-001 Work Order #...: LQ2RG Matrix AIR 

Date Sampled. ; 12/06/09 Date Received..: 12/11/09 

PREPARATION- PRKP 

PARAMETER RESULT RL ONITS METHOD ANALYSIS DATE BATCH # 

Hydrogen chloride 16700 2000 ug KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 19951.53 MDL . . t 840 

VES01810 
9 

AECOM, Inc 

Clien t Sample ID: CPT-U2-CL2-IMP5-6-R1 

General Chemistry 

Lot-Sample #...: H9L140402-002 Work Order LQ2RK Matrix : AIR 

Date Sampled...: 12/08/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Chlorine 278 B 480 ug KNOX 0050/26A Mod 12/15/09 9350153 

Dilution Factor: 4800 MDL : 200 

NOTK(S) : ... 

RL Reporting Limit 

B Estimated result. Result is less than HL. 

VES018108 
10 

AECOM, Inc 

Clien t Sample ID: CPT-TJt2-CL2-_l_?l-4-R2A 

General Chemistry 

Lot-Sample it...: H9L140402-003 Work Order #. : LQ2RM Matrix : AIR 

Date Sampled : 12/09/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Hydrogen chlorid e 22000 2030 ug KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 20250.06 MDL ,: 850 

VES01810! 
11 

Lot-Sample #. 

Date Sampled. 

PARAMETER 

AECOM, Inc 

Clien t Sample XDi CPT-U2-CL2-IMP5-6-R2 

General Chemistry 

: H9L140402-004 Work Order #...: LQ2RN 

, : 12/09/09 Date Received..: 12/11/09 

Matrix. .: AIR 

Chlorine 

RESULT RL 

ND 

UNITS 

480 ug 

Dilution Factor: 4800 

METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

KNOX 0050/26A Mod 12/15/09 

HDL : 200 

93501S3 

VES018110 
12 

AECOM, Inc 

Clien t Sample ID: CPT-TJ2-HCL-IMP1-4-R3A 

Lot-Sample #...: H9L140402-005 

Date Sampled...: 12/10/09 

PARAMETER RESOLT 

General Chemistry 

Work Order #...: LQ2RV 

Date Received..: 12/11/09 

RL UNITS METHOD 

Matrix : AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Hydrogen chlorid e 32400 3990 ug KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 39903.05 MDL : noo 

VES018111 
13 

Lot-Sample #. 

Date Sampled. 

PARAMETER 

AECOM, Inc 

Clien t Sample ID: CPT-TJ2-CL2-TMP5-6-R3 

General Chemistry 

.: H9L140402-006 Work Order #...: LQ2RW 

.: 12/10/09 Date Received..: 12/11/09 

Matrox. AIR 

Chlorine 

RESULT RL DHITS 

ND 490 ug 

Dilution Factor: 4900 

METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

KNOX 0050/26A Mod 12/15/09 

MDL : 210 

9350153 

VES018112 
14 

AECOM, Inc 

Clien t Sample ID: CPT-H20-U2-FB 

General Chemistry 

Lot-Sample #...: H9L140402-007 Work Order : LQ2R1 Matrix : AIR 

Date Sampled. : 12/08/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Hydrogen chloride ND 103 ug KNOX 0050/26A Mod 12/14/09 9349122 

VES018113 
15 

AECOM, Inc 

Clien t Sample ID : CPT-HCL-FB-UGeneral Chemistry 

Lot-Sample : H9L140402-008 Work Order #...; LQ2E2 Matrix : AIR 

Date Sampled...: 12/08/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Hydrogen chlorid e ND 411 ug KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 4113.72 MDL = 170 

VES018114 
16 

Lot-Sample #, 

Date Sampled. 

PARAMETER 

AKCOM, Inc 

Clien t Sample ID.- CPT-CL2-FB-U2 

General Chemistry 

.: H9L140402-009 Work Order #-..: LQ2R3 

.: 12/08/09 Date Received..: 12/11/09 

RESULT RL UNITS METHOD 

Matrix : AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Chlorine ND 100 ug 

Dilution Factor: 1000 

KNOX 0050/26A Mod 12/15/09 

MD- : 42 

9350153 

VES01811! 
17 

METHOD BLANK REPORT 

General Chemistry 

Clien t Lot H9L14 0402 

PARAMETER RESULT 

Chlorine 

Hydrogen chloride 

REPORTING 

LIMIT UNITS METHOD 

Matrix , : AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Work Order #: LQ6MH1AA MB Lot-Sample #: H9L160000-153 

ND 10.0 ug KNOX 0050/26A Mod 12/15/09 9350153 

Dilution Factor: 100 

Work Order #: LQ4NF1AA MB Lot-Sample #: H9L150000-122 

ND 10.3 ug KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 102.8 

NOTECS) : 

Calculations are performed before rounding co avoid round-off errors in calculated results. 

VES018116 
18 

LABORATORY CONTROL SAMPLE EVALUATION REPORT 

General Chemistry 

Lot-Sample H9L140402 Matrix. . : AIR 

PARAMETER 

Chlorine 

PERCENT 

RECOVERY 

98 

99 

RECOVERY 

LIMITS RPD 

RPD 

LIMITS METHOD 

PREPARATIONANALYSIS DATE 

PREP 

BATCH # 

W0#:LQ6MH1AC-LCS/LQ6MH1AD-LCSD LCS Lot-Sampled: H9L160000-153 

(90 - 110) KNOX 0050/26A Mod 12/15/09 9350153 

(90 - 110) 0.81 (0-20) KNOX 0050/26A Mod 12/15/09 9350153 

Dilution Factor; 100 

Hydrogen chloride 

101 

98 

W0#:LQ4NF1AC-L_S/LQ4NF1AD-LCSD LCS Lot-Samplefr: H9L150000-122 

(90 - 110) KNOX 0050/26A Mod 12/14/09 9349122 

(90 - 110) 2.4 (0-20) KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 102.8 

NOTE(S) : 

Calculations arc performed before rounding 10 ovoid round-off errors in calculated rcsulis. 

VES01811 
19 

LABORATORY CONTROL SAMPLE DATA REPORT 

General Chemistry 

Lot-Sample H9L140402 Matrix. AIR 

PARAMETER 

Chlorine 

PERCNT PREPARATION- PREP 

RECVRY RPD METHOD ANALYSIS DATE BATCH # 

W0#:LQ6MH1AC-LCS/LQ5MH1AD-LCSD LCS Lot-Sample#: H9L160000-153 

73.B ug 98 KNOX 0050/26A Mod 12/15/09 9350153 

74.4 ug 99 0-81 KNOX 0050/26A Mod 12/15/09 9350153 

Dilution Factor: 100 

SPIKE MEASURED 

AMOUNT AMOUNT UNITS 

75.0 

75.0 

Hydrogen chloride 

77.1 

77.1 

W0# : LQ4NF1AC - LCS / LQ4NF1AD -LCSD LCS Lot-Satnple#: H9L150000-122 

77.S ug 101 KNOX 0050/2SA Mod 12/14/09 9349122 

75.8 ug 98 2.4 KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 102.8 

NOTECS) ; 

Calculations arc performed before rounding to avoid round-off errors in calculated results. 

VES018118 
20 

MATRIX SPIKE SAMPLE EVALUATION REPORT 

General Chemistry 

Clien t Lot #... 

Date Sampled.... 

: H9L140402 

: 12/09/09 Date Received. 12/11/09 

PARAMETER 

Chlorine 

PERCENT RECOVERY 

RECOVERY LIMITS RPD 

RPD 

LIMITS METHOD 

Matrix. : AIR 

PREPARATIONANALYSIS DATE PREP 

BATCH # 

101 

103 

WO#: LQ2RN1AD-MS/LQ2 RN1AE- MSD MS Lot-Sample #: H9L14O402-0O4 

(75 - 125) KNOX 0050/26A Mod 12/15/09 9350153 

(75 - 125) 1.7 (0-20) KNOX 0050/26A Mod 12/15/09 9350153 

Dilution Factor: 4800 

Hydrogen chlorid e 

98 (75 

94 (75 

WO#: LQ2RM1AD-MS/LQ2RM1AE-MSD MS Lot-Sample #: H9L140402-003 

125) KNOX 0050/26A Mod 12/14/09 9349122 

125) 0.56 (0-20) KNOX 0050/2SA Mod 12/14/09 9349122 

Dilution Factor: 20260 

NO— (S) : 

CalculM-ions arc performed before rounding lo avoid round-off errors io calcufcued results. 

VES018119 
21 

MATRIX SPIKE SAMPLE DATA, REPORT 

General Chemistry 

Clien t Lo t #...: H9L140402 

Date Sampled...: 12/09/09 

SAMPLE SPIKE 

PARAMETER AMOUNT AMT 

Matrix. .: AIR 

Date Received..: 12/11/09 

Chlorine 

ND 

ND 

960 

960 

Hydrogen chloride 

22000 4050 

22O00 4050 

MEASRD 

AMOUNT UNITS 

PERCNT 

RBCVRY RPD METHOD 

PREPARATION - PREP 

ANALYSIS DATE BATCH # 

WO#: LQ2RN1AD-MS/LQ2RN1AE-MSD MS Lot-Sample #: H9L140402-004 

971 ug 101 KNOX 0050/26A 12/15/09 9350153 

988 ug 103 1.7 KNOX 0050/26A 12/15/09 9350153 

Dilution Factor: 4800 

WO#: LQ2RM17AD-MS/LQ2RM1AE-MSD MS Lot-Sample #: H9L140402-003 

25900 ug 98 KNOX 0050/26A 12/14/09 9349122 

25800 ug 94 0.56 KNOX 0050/26A 12/14/09 9349122 

Dilution Factor: 20260 

NOTB(S) ; _________ _ 

CalcataiitiB are performed before rounding io avoid round-off errors in calculaied rcsulis. 

VES01812C 
22 

Clien t Lot #...: H9L140402 

Date Sampled...: 12/08/09 

SAMPLE DUPLICATE EVALUATION JREPORT 

General C_emistry 

Work Order #...-. LQ2RG-SMP 

LQ2RG-DUP 

Date Received..: 12/11/09 

PARAM RESULT 

Hydrogen chlorid e 

16700 16900 

Matrix. AIR 

DUPLICATE 

RESULT UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L140402-001 

U g 0.95 (0-20) KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 19951.53 

VES01812' 
23 

Clien t Lot 

Date Sampled. 

PARMM RESULT 

Chlorine 

278 B 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

.: H9L140402 Work Order #...: LQ2RK-SMP 

LQ2RK-DUP 

,: 12/08/09 Date Received..: 12/11/09 

Matrix. AIR 

DUPLICATE 

RESULT UNITS 

RPD 

RPD LIMIT METHOD 

289 B 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD LOt-Sample #: H9L140402-002 

ug 4.1 (0-20) KNOX D050/26A Mod 12/15/09 9350153 

Dilution Factor: 4800 

NOTE (S) 

Calculations are performed before rounding io avoid round-off errors in calculated results. 

B Estimated result. Result is less than RL. 

VES018122 
24 

Clien t Lot #...: H9L140402 

Date Sampled...: 12 /09/09 

DUPLICATE 

PARAM RESULT RESULT 

Hydrogen chlorid e 

22000 21600 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LQ2RM-SMP 

LQ2RM-DUP 

Date Received..: 12/11/09 

Matrix. AIR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L140402-003 

U g 1.7 (0-20) KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 20260.06 

VES018123 
25 

H9L140402 

12/09/09 

DUPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LQ2RN-SMP 

LQ2RN-D-P 

Date Received..: 12/11/09 

ND 

Matrix. A IR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

~~ SD Lot-Sample #: H9L140402-004 

ug o (0-20) KNOX 0050/26A Mod 12/15/09 9350153 

Dilution Factor; 4800 

VES018124 
26 

Clien t Lot #...: H9L140402 

Date Sampled...: 12/10/09 

SAMPLE DOPLICATE EVALUATION EEPORT 

General Chemistry 

Work Order #...: LQ2RV-SMP 

LQ2RV-DUP 

Date Received..; 12/11/09 

PARAM RESULT 

DUPLICATE 

RESULT 

Hydrogen chloride 

32400 31600 

Matrix. AIR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE. BATCH # 

SD Lot-Sample #: H9L140402-005 

ug 2.4 (0-20) KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor; 39903.05 

VES018125 
27 

H9L140402 

12/10/09 

DUPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order ft...: LQ2RW-SMP 

LQ2RW-DUP 

Date Received..: 12/11/09 

ND 

Matrix. AIR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L140402-006 

ug 0 (0-20) KNOX 0050/26A Mod 12/15/09 9350153 

Dilution Factor: 4900 

VES01812J 
28 

Clien t Lot #. . .: H9L140402 

Date Sampled...: 12/08/09 

DUPLICATE 

PARflM RESULT RESULT 

Hydrogen chloride 

ND ND 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order LQ2R1-SMP 

LQ2R1-DUP 

Date Received..: 12/11/09 

Matrix. AIR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L140402-007 

u g 0 (0-20) KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 1028.43 

VES018127 
29 

Clien t Lot #..-: H9L140402 

Date Sampled...: 12/08/09 

DUPLICATE 

PARAN RESULT RESULT 

Hydrogen chloride 

ND ND 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LQ2R2-SMP 

LQ2R2-DUP 

Date Received..: 12/11/09 

UNITS 

RPD 

RPD LIMIT METHOD 

Matrix. AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH ft 

SD Lot-Sample" #: .H9L140402-0O8 

ug 0 (0-20) KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor; 4113.72 

VES018128 
30 

H9L140402 

12/08/09 

DUPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General ChemistryWork Order #...: LQ2R3-SMP 

LQ2R3-DUP 

Date Received..: 12/11/09 

ND 

Matrix. .: AIR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

— ' SD Lot-Sample #: H9L140402-009 

u g o (0-20) KNOX 0050/26A Mod 12/15/09 9350153 

Dilution Factor: 1000 

VES01812J 
31 

Sample Receipt Documentation 

VES018130 
Sample Traceability List j AECO M 

Site of Program: Veolia ES Tech Sample DatB: i„-?\-o<? - tS-'lo-o^ Project Location: Sauget, IL Lab P0#': 

Tvoe of Pronram: CPT Date Shipped: iZr | o -o l Laboratory: Test America, Inc. 

Project*: 60133216 Shipper/ Steven Milo Knoxville. TN 

Recovery: \ _ rW_>-, peff Gorman 

Laboratory: Test America, Inc. 

Knoxville. TN 

Proqram Office: Syracuse NY 

Shipper/ Steven Milo 

Recovery: \ _ rW_>-, peff Gorman 

Laboratory: Test America, Inc. 

Knoxville. TN 

Program Contact: Jeff Gorman FedEx Air Bill #: 

Item Sample ID Code Sample Matrix Sample Description Analytical Parameters Special Instructions 

1 CPT-U2-HCL-IMP1-4-R 1 A 0.1N H2S04 Unit 2, Impingers 1-4, Run 1 A H C L

 j o 

M f i irrr^-rv AV Oil (\\ ^ 

_ 

3 CPT-U2-CI2-JWIP5-6-R 1 0.1 N NaOH Unit 2, Impingers 5-6, Run 1 

'—fcBJ- TxiJlrAVi^y ?n<~Kno 

4 1X7. °\AJC^> 

5 CPT-U2-HCL-IMP1-4-R 2 A 0.1N H2S04 Unit 2, ImpingBrs 1-4, Run 2 A flXL. 

5 

7 CPT-U2-CI2-IW1P5-6-R 2 0.1N NaOH Unit 2, Impingers 5-8, Run 2 c i 2 a#l „ A 

a 

9 

4n 

CPT-U2-HCL-1MP1-4-R 3 A 0.1N H2S04 Unit 2, Impingers 1-4. Run 3 A HCL Sto^Lj *j 

t in °i f^tt r 

IU 

11 

U r 1 -Ux»l 1—t-"Jftftl N-"!"! * o U 

CPT-U2-CI2-IIWP5-6-R 3 0.1N NaOH Unit 2, Impingers 5-6, Run 3 .

 M.VL

 s&HU' f; 

CI2 8U^I/> < 

12 Nb JA.aTt»n\ jj 

13 

14 

15 

16 

17 f?PT - \A 7 0 -OvF © V\xO Fie. U PiU k )AC\ rvviA C>l^-

18 CPT-HCL-FB-U2 0.1N H2S04 0.1N H2S04 Field Blank HCL 

19 CPT-CI2-FB-U2 0.1N NaOH 0.1N NaOH Field Blank CI2 

20 

Field Notes/ Comments 

Page of 

Relinquished By (print): Date: 

Steven Milo &~lO-Ol 

Signature; /> Time: 

-W/ l !7oo 

Relinquished By (print): Date; 

Signature: Time: 

Relinquished By (print): Date: 

Signature: Time: 

Received by Lab (print): Date: 

Signature: Time: 

Received By (print): Date: 

—Signature^. Time: 

Received By (print): Date: 

Signature: Time: j 

Received By (print); Date: 

Signature: Time: 

Received By (print): Date: Analytical Laboratory Destination: 

—Signature^. Time: 

Received By (print): Date: 

Signature: Time: j 

Received By (print); Date: 

Signature: Time: 

TestAmerica Inc. 

5815 Middlebrook Pike 

Knoxville, TN 37921 

Attn: Mr. Kevin Woodcock 865-291-3000 

OJ 

to 

VES018131 
TESTAMERICA KNOXVILLE SAMPLE RECEIPT/CONDITION UPON RECEIPT ANOMALY CHECKLIST 

Lot Number: r^uMTHOT), 

Review Items NA If No, what was the problem? Comments/Actions Taken 

1. Do sample container labels match COC? 

(IDs, Dates, Times) / 

—L 

a la Do not match COC 

D lb Incomplete information 

• lc Marking smeared 

• Id Label torn 

Q le No label 

U If COC not received 

a lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) / 

—L 

a la Do not match COC 

D lb Incomplete information 

• lc Marking smeared 

• Id Label torn 

Q le No label 

U If COC not received 

a lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) / 

—L 

a la Do not match COC 

D lb Incomplete information 

• lc Marking smeared 

• Id Label torn 

Q le No label 

U If COC not received 

a lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) / 

—L 

a la Do not match COC 

D lb Incomplete information 

• lc Marking smeared 

• Id Label torn 

Q le No label 

U If COC not received 

a lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) / 

—L 

a la Do not match COC 

D lb Incomplete information 

• lc Marking smeared 

• Id Label torn 

Q le No label 

U If COC not received 

a lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) / 

—L 

a la Do not match COC 

D lb Incomplete information 

• lc Marking smeared 

• Id Label torn 

Q le No label 

U If COC not received 

a lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) / 

—L 

a la Do not match COC 

D lb Incomplete information 

• lc Marking smeared 

• Id Label torn 

Q le No label 

U If COC not received 

a lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) / 

—L 

a la Do not match COC 

D lb Incomplete information 

• lc Marking smeared 

• Id Label torn 

Q le No label 

U If COC not received 

a lg Other: 

I. Is the cooler temperature within limits? (> freezing 

temp. ofwaterto6 pC;NC, 1668, 1613B: 0-4"C; 

VOST: 10°C;MA:2-6°C) 

J 

1 

I. Is the cooler temperature within limits? (> freezing • 2a Temp Blank = 

temp. ofwaterto6 pC;NC, 1668, 1613B: 0-4"C; 

VOST: 10°C;MA:2-6°C) 

J 

1 

• 2b Cooler Temp = 

I. Is the cooler temperature within limits? (> freezing 

temp. ofwaterto6 pC;NC, 1668, 1613B: 0-4"C; 

VOST: 10°C;MA:2-6°C) 

J 

1 

3. Were samples received with correct chemical 

preservative (excluding Encore)? 

0 3a Sample preservative = 

i 

3. Were samples received with correct chemical 

preservative (excluding Encore)? 

0 3a Sample preservative = 

i 

4. Were custody seals present/intact on cooler and/or 

containers? \ 4a Not present 

• 4b Not intact 

• 4c Other: 

4. Were custody seals present/intact on cooler and/or 

containers? \ 4a Not present 

• 4b Not intact 

• 4c Other: 

4. Were custody seals present/intact on cooler and/or 

containers? \ 4a Not present 

• 4b Not intact 

• 4c Other: 

5. Were all of the samples listed on the COC received? 0 Sa Samples received-noton COC 

• 5b Samples not received-on COC 

5. Were all of the samples listed on the COC received? 0 Sa Samples received-noton COC 

• 5b Samples not received-on COC 

6. Were all of the sample containers received intact? 

I 

• 6a Leaking 

• 6b Broken 

6. Were all of the sample containers received intact? 

I 

• 6a Leaking 

• 6b Broken 

7. Were VOA samples received without headspace? -1 • 7a Headspace (VOA only) 

S. Were samples received in appropriate containers? J —f- D 8a Improper container 

9. Did you check for residual chlorine, if necessary? 

i . J • 9a Could not be determined due 

to matrix interference 

9. Did you check for residual chlorine, if necessary? 

i . J • 9a Could not be determined due 

to matrix interference 

10. Were samples received witliin holding time? J i • 10a Holding time expired 

11. For rad samples, was sample activity info, provided? 1, • Incomplete information 

12. For I613B water samples is pH<9? J If no, was pH adjusted to pH 7 - 9 

with sulfuric acid? 

12. For I613B water samples is pH<9? J If no, was pH adjusted to pH 7 - 9 

with sulfuric acid? 

13. Are tlie shipping containers intact? i 

-f— 

• 13a Leaking 

D 13b Other: 

13. Are tlie shipping containers intact? i 

-f— 

• 13a Leaking 

D 13b Other: 

13. Are tlie shipping containers intact? i 

-f— 

• 13a Leaking 

D 13b Other: 

14. Was COC relinquished? (Signed/Dated/Timed) • 14a Not relinquished 

15. Are tests/parameters listed for each sample? D 15a Incomplete information 

16. Is the matrix ofthe samples noted? • 15n Incomplete information 

17, Is the date/time of sample collection noted? h 

• 15a Incomplete information 

18, Is the client and project name/tf identified? 1 1 0 15a Incomplete information 

19. Was tlie sampler identified on the COC? / 

Ouote#: ^"Yi ^ PM Instructions: 

""~"N/\ -.r ,, . -

Sample Receiving Associate Date:Jj4l]]0^_ QA026R21.doc, 090409 

w 

co 

VES018132 
34 

Wet Chemistry 

VES018133 
35 

Sample Summary 

VES018134 
36 

AECOM, Inc 

Clien t Sample ID: CPT-D2-HCD-IMP1-4-RXA 

General Chemistry 

Lot-Sample #...: H9L140402-001 Work Order #...: LQ2RG Matrix : AIR 

Date Sampled...: 12/08/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL OKITS METHOD ANALYSIS DATE BATCH # 

Hydrogen chlorid e 16700 2000 ug KHOX 005Q/26A Mod 12/14/09 9349122 

Dilution Factor: 19951.53 MDL : 840 

VES018135 
37 

AECOM. Inc 

Clien t Sample ID: CPT-D2-CL2-IMP5-6-S1 

General Chemistry 

Lot-Sample #...: H9L140402-002 Work Order #...: LQ2RK Matrix : AIR 

Date Sampled...: 12/08/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATS BATCH # 

Chlorine 278 B 480 ug KNOX 0050/2SA Mod 12/15/09 9350153 

Dilution Factor: 4800 MDL : 200 

NOTE (S) : 

Rl Rq>orting Limit 

B Esiirmicd result. Result is less than RL. 

VES018136 
38 

AECOM, Inc 

Clien t Sample ID: CET-D2-CL2-IMP1-4-R2A 

General Chemistry 

Lot-Sannple H9L140402-003 Work Order #...: LQ2RM Matrix : AIR 

Date Sampled...: 12/09/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Hydrogen cnlorid e 22000 2030 ug KHOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 20260.06 MDL : SSO 

VES018137 
39 

AECOM, Inc -

Clien t Sample ID: CPT-D2-CL2-IMP5-6-E2 

General Chemistry 

Lot-Sample #...: H9L140402-004 Work Order : LQ2RN Matrix : AIR 

Date Sampled...: 12/09/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Chlorine ND 480 ug KNOX O05O/26A Mod 12/15/09 9350153 

Dilution Factor! 4800 MDL : 200 

VES018138 
40 

AECOM, Inc 

Clien t Sample ID: CPT-02-HCL-IME>l-4-R3A 

General Chemistry 

Lot-Sample it... : H9L140402-005 Work Order #...: LQ2RV Matrix : AIR 

Date Sampled...: 12/10/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Hydrogen chloride 32400 3990 ug KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 399Q3.05 MDL : 1700 

VES018139 
41 

AECOM, Inc 

Clien t Sample IDt CPT-U2-CL2-IMP5-6-E3 

General Chemistry 

Lot-Sample #...: H9L140402-006 Work Order #...: LQ2RW Matrix : AIR 

Date Sampled...: 12/10/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH J 

Chlorine ND 490 ug KNOX O05O/26A Mod 12/15/09 9350153 

Dilution Factor: 4900 MDL : 210 

VES018140 
42 

AECOM, Inc 

Clien t Sample ID: CPT-H20-02-5B 

General Chemistry 

Lot-Sample #...: H9L140402-007 Work Order LQ2R1 

Date Sampled...: 12/08/09 Date Received..: 12/11/09 

PARAMETER RESULT RL UNITS METHOD 

Hydrogen chloride 

Matrix. .: AIR 

PREPARATION- PREP 

ANALYSIS DATS BATCH # 

ND 103 ug KNOX 0050/2SA Mod 12/14/09 

Dilution Factor-. 1028.43 MDL i 43 

9349122 

VES018141 
43 

AECOM, Inc 

Clien t Sample ID: CPT-HCL-PB-02 

General Chemistry 

Lot-Sample #. H9L140402-008 Work Order #...: LQ2R2 Matrix = AIR 

Date Sampled...: 12/08/09 Date Received..s 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH ft 

Hydrogen chloride ND 411 ug KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 4113.72 MDL. : 170 

VES018142 
44 

AECOM, Inc 

Clien t Sample ID: CPT-CL2-FB-02 

General Chemistry 

H9L140402-009 Work Order #...: LQ2R3 

12/08/09 Date Received..: 12/11/09 

RESULT RL UNITS METHOD 

Matrix. AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

ND 100 ug 

Dilution Factor: 1000 

KNOX 005O/2SA Mod 12/15/09 

MDL : 42 

9350153 

VES018143 
45 

QC Summary 

VES018144 
46 

Clien t Lot H9L1404D2 

PARAMETER RESULT 

Chlorine 

Hydrogen chloride 

ND 

ND 

METHOD BLANK REPORT 

General Chemistry 

Matrix. A I R 

REPORTING 

LIMIT UNITS METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Work Order #: LQ6MH1AA MB Lot-Sample #: H9LI6000Q-153 

10.0 ug KNOX 0050/26A Mod 12/15/09 9350153 

Dilution Factor: 100 

Work Order #: LQ4NF1AA MB Lot-Sample #: H9L150000-122 

10.3 ug KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 102.8 

NOTE (S): 

Calculiiions are performed before rounding lo avoid round-off errors in calculaied results. 

VES018145 
47 

LABORATORY COHTROL SAMPLE EVALuATTOH REPORT 

PARAMETER 

Chlorine 

General Chemistry 

Lot-Sample #.. H9L140402 

PERCENT 

RECOVERY 

98 

99 

RECOVERY 

LIMITS RPD 

RPD 

LIMITS METHOD 

Matrix : AIR 

PREPARATIONANALYSIS DATE 

PREP 

BATCH # 

W0#:LQ6MH1AC-LCS/LQSMH1AD-LCSD LCS Lot-Satnple#: H9L160OD0-153 

(90 - 110) KNOX 0O50/26A Mod 12/15/09 9350153 

(90 - 110) 0.81 (0-20) KNOX D050/26A Mod 12/15/09 9350153 

Dilution Factor: 100 

Hydrogen chloride 

101 

98 

W0#:LQ4NF1AC-LCS/LQ4NF1AD-LCSD LCS Lot-Sample#: H9L150000-122 

(90 - 110) KNOX 0050/26A Mod 12/14/09 9349122 

(90 - 110) 2.4 (0-20) KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 102.8 

NOTE (S) ; 

Calculations are performed before rounding to avoid round-off errors in calculated results. 

VES018146 
48 

LABORATORY COHTROI. SAMPLE DATA REPORT 

General Cnemistxy 

Lot-Sample #...: H9L140402 Matrix. AIR 

PARAMETER 

Chlorine 

SPIKE MEASORED 

AMOUNT AMOUNT UNITS 

PERCNT 

RECVRY RPD METHOD 

PREPARATIONANALYSIS DATE 

75.0 

75.0 

PREP 

BATCH # 

W0#:LQSMH1AC-LCS/LQ6MH1AD-LCSD LCS Lot-Sample#: H9L160000-153 

73.8 ug- 98 KNOX 0050/26A Mod 12/15/09 9350153 

74:4 ug 99 0.81 KNOX 0050/2SA Mod 12/15/09 9350153 

Dilution Factor: 100 

Hydrogen chlorid e 

77.1 

77.1 

W0#:LQ4NF1AC-LCS/LQ4NF1AD-LCSD LCS Lot-Sample*: H9L150OO0-122 

77.6 ug 101 KNOX 0050/26A Mod 12/14/09 9349122 

75.8 ug 98 2.4 KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 102.8 

HOTE(S) 

Calculations arc performed before rounding to avoid round-off errors in calculated results. 

VES018147 
49 

MATRIX SPIKE SAMPLE EVALUATION REPORT 

General Chemistry 

Clien t Lot H9L140402 

Date Sampled...: 12/09/09 Date Received..: 12/11/09 

PARAMETER 

Chlorine 

PERCENT RECOVERY 

RECOVERY LIMITS RPD 

RPD 

LIMITS METHOD 

Matrxx. AIR 

PREPARATIONANALYSIS DATE 

PREP 

BATCH # 

101 

103 

WO#: LQ2RN1AD-MS/LQ2RN1AE-MSD MS Lot-Sample #: H9L140402-004 

(75 - 125) KNOX 0050/2SA Mod 12/15/09 9350153 

(75 - 125) 1.7 (0-20) KNOX 0050/26A Mod 12/15/09 9350153 

Dilution Factor; 4800 

Hydrogen chloride 

98 (75 

94 (75 

W0#: LQ2RM1AD-MS/LQ2RM1AE-MSD MS Lot-Sample #: H9L14O402-OO3 

125) KNOX 0050/26A Mod 12/14/09 9349122 

125) 0.56 (0-20) KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 20260 

NOTE{S): 

Calculations arc performed before rounding to avoid round-off errors in calculated results. 

VES018148 
50 

MATRIX SPIKE SAMPLE DATA REPORT 

General Chemistry 

Clien t Lot H9L140402 

Date Sampled...: 12/09/09 

SAMPLE SPIKE MEASRD 

Matrxx. AIR 

Date Received..: 12/11/09 

PARAMETER AMOUNT AMT 

Chlorine 

ND 

ND 

960 

960 

AMOUNT UNITS 

PERCNT 

RECVRY RPD METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

WO#: LQ2RN1AD-MS/LQ2RN1AE-MSD MS Lot-Sample #: H9L14O402-004 

971 ug 101 KNOX 0050/26A 12/15/09 9350153 

986 ug 103 1.7 KNOX 0050/26A 12/15/09 9350153 

Dilution Factors 4800 

Hydrogen chloride 

22000 4050 

22000 4050 

WO#: LQ2RM1AD-MS/LQ2RM1AE-MSD MS Lot-Sample #: H9L14O402-003 

25900 ug 98 KNOX 0050/26A 12/14/09 9349122 

25800 ug 94 0.56 KNOX 0050/26A 12/14/09 9349122 

Dilution Facton 20260 

NOTE(S); 

Calculations arc pcrfacmed before rounding to avoid round-off errors in calculated results. 

VES018149 
51 

Clien t Lot #...: H9L140402 

Date Sampled...: 12/08/09 

DUPLICATE 

PARAM RESULT RESULT 

Hydrogen chloride 

1S700 16900 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #. „.: LQ2RG-SMP 

LQ2RG-DUP 

Date Received..: 12/11/09 

Matrix:. AIR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot^Sample #: H9L140402-001 

•ug 0.96 (0-20) KNOX 0050/2SA Mod 12/14/09 9349122 

Dilution Factor! 19351.53 

VES018150 
52 

Clien t Lot #. 

Date Sampled. 

PARAM RESULT 

Chlorine 

278 B 

H9L140402 

12/08/09 

DUPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LQ2RK-SMP 

LQ2RK-DUP 

Date Received..: 12/11/09 

Matrix. AIR 

UNITS RPD 

RPD 

LIMIT METHOD 

289 B 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L140402-002 

ug 4.1 (O-20) KNOX 0050/2SA Mod 12/15/09 9350153 

Dilution Factor: 4800 

NOTB(S) : 

Calculations ate performed before roundiog to avoid round-off errors in calculated results. 

B Estimated result. Result is less than RL. 

VES018151 
53 

Clien t Lot #...: H9L140402 

Date Sampled...: 12/09/09 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #.-.: LQ2RM-SMP 

LQ2RM-DUP 

Date Received..: 12/11/09 

DUPLICATE 

PARAM RESULT RESULT 

Hydrogen chloride 

22000 21600 

UNITS 

RPD 

RPD LIMIT METHOD 

Matrix. : AIR 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L140402-0O3 

ug 1.7 (0-20) KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor; 20260.06 

VES018152 
54 

H9L140402 

12/09/09 

DUPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LQ2RN-SMP 

LQ2RN-DUP 

Date Received..: 12/11/09 

ND 

UNITS RPD 

RPD 

LIMIT METHOD 

Matrix. AIR 

PREPARATION- PREP I 

ANALYSIS DATE BATCH # f 

SD Lot-Sample #: H9L140402-004 

ug 0 (0-20) KNOX 0050/26A Mod 12/15/09 9350153 

Dilution Factor: 4800 

VES018153 
55 

Clien t Lo t #...: H9L140402 

Date Sampled...: 12/10/09 

DUPLICATE 

PARAM RESULT RESULT 

Hydrogen chloride 

32400 31600 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LQ2RV-SMP 

LQ2RV-DUP 

Date Received..: 12/11/09 

Matrix. AIR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L140402-005 

ug 2.4 (0-20) KNOX 0050/26A Mod 12/14/09 9349122 

Dilution Factor: 39903.05 

VES018154 
59 

H9L140402 

12/08/09 

DUPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General C_emistry • 

Work Order #...i LQ2R3-SMP 

LQ2R3-DUP 

Date Received..: 12/11/09 

ND 

Matrix. AIR 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L140402-009 

ug 0 (0-20) KNOX 0050/26A Mod 12/15/09 9350153 

Dilution. Factor: 1000 

VES018155 
Method 0023A 

VES018156 
•Vista 

Analytical Laboratory 

December 27,2009 

Vista Project LD.: 32275 

Mr. Jeffrey Gorman 

AECO M Environment 

5015 Campuswood Drive 

Suite 104 

East Syracuse, NY 13057-4232 

Dear Mr. Gorman, 

Enclosed are the results for the four MM5 samples received at Vista Analytical Laboratory on 

December 12, 2009 under your Project Name "60133216". These samples were extracted and 

analyzed using Method 0023A for tetra-through-octa chlorinated dioxins and furans. The front and 

back halves were extracted and analyzed separately for samples Rl , R2 and R3. A standard 

turnaround time was provided for this work. 

The following report consists of a Sample Inventory (Section I), Analytical Results (Section II) 

and the Appendix, which contains the chain-of-custody, a list of data qualifiers and abbreviations, 

Vista's current certifications, and copies of the raw data (if requested). 

Vista Analytical Laboratory is committed to serving you effectively. If you require additional 

information, please contact me at 916-673-1520 or by email at mmaier@vista-analytical.com. 

Thank you for choosing Vista as part of your analytical support team. 

Sincerely, 

Martha M . Maier 

Laboratory Director 

Vista Anaiyiicai Laboratory certifies thai Ihe report herein meets all Ihe requirements set forth by NELAC for those applicable 

y, test methods. Results relate only lo ihe samples as received by the laboratory. This report should not be reproduced except in full 

i-i. without the written approval cf Vista Analytical Laboratory. 

Vista Analytical Laboratory | H04WindfieldWay | El Dorado Hills, CA 95762 I ph: 916-673-1520 | fx: 916-673-0106 I wwww.vista-analytical.com 

Project 32275 Page 1 of 18 

VES018157 
Wista 

Section I: Sample Inventory Report 

Date Received: 12/12/2009 

Project No.: 32275 

Project Name: 60133216 

Lab. Sample ID Client Sample ID Component ID 

001 CPT-U2-M23A-XAD-R1 BHR 

XAD 

002 CPT-U2-M23A-PF-R1 FHR 

FILTER 

003 CPT-U2-M23A-XAD-R2 BHR 

XAD 

004 CPT-U2-M23A-PF-R2 FHR 

FILTER 

005 CPT-U2-M23A-XAD-R3 BHR 

XAD 

006 CPT-U2-M23A-PF-R3 FHR 

FILTER 

007 CPT-U2-M23A-U2-FB ACE/MeC12/TOL 

FILTER 

XAD 

SmpinvgnmmS.rpI 

Project 32275 Page 2 of 18 

VES018158 
Wista 

SECTION n 

Project 32275 

Page 3 of 18 

VES018159 
Avist a 

Method Blank Method 0023A 

Matrix: MM5 QC Batch No.: 2646 L a b Sample: 0-MB001 

Sample Size: Sample Date Extracted 21-Dec-09 Date Analyzed DB-5: 23-Dec-09 Date Analyzed DB-225: NA 

Analyte Cone. (pg/Sample) D L

 a EMP C b Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD N D 2.69 IS 13C-2,3,7,8-TCDD 94.7 40-135 

1,2,3,7,8-PeCDD ND 4.00 13C-1,2,3,7,8-PeCDD 98.9 40- 135 

1,2,3,4,7,8-HxCDD N D 6.58 13C-l,2,3,6,7,8-HxCDD 79.8 40-135 

1,2,3,6,7,8-HxCDD ND 5.17 13C- 1,2,3,4,6,7,8-HpCDD 105 40- 135 

1,2,3,7,8,9-HxCDD ND 5.43 13C-OCDD 111 40-135 

1,2,3,4,6,7.8-HpCDD ND 3.09 13C-2,3,7,8-TCDF 96.6 40- 135 

OCDD N D : 5.10 13C-l,2,3,7,8-PeCDF 108 40-135 

2,3,7,8-TCDF ND 2.36 13C-l,2,3,6,7,8-HxCDF 75.7 40- 135 

1,2,3,7,8-PeCDF ND 2.75 13C-l,2,3,4,6,7,8-HpCDF 95.1 40- 135 

2,3,4,7,8-PeCDF N D 2.91 13C-OCDF 99.4 40- 135 

1.2,3,4,7,8-HxCDF ND 2.05 PS 37Cl-2,3,7,8-TCDD 107 70-130 

1,2,3,6,7,8-HxCDF ND 1.63 13C-2,3,4,7,8-PeCDF 102 70- 130 

2,3,4,6,7,8-HxCDF ND 2.06 13C-l,2,3,4,7,8-HxCDD 124 70- 130 

1,2,3,7,8,9-HxCDF ND 2.31 13C-l,2,3,4,7,8-HxCDF 126 70- 130 

1,2,3,4,6,7,8-HpCDF ND 2.74 13C-l,2,3,4,7,8,9-HpCDF 110 70-130 

1,2,3,4,7.8,9-HpCDF - ND 3.52 AS 13C-l,2.3,7,8,9-HxCDF 107 40- 135 

OCD F ND 6.33 

Totals Toxic Equivalent Quotient (TEQ) Data 

e 

Total TCDD ND 2.69 T E Q (Min-Max): 0 - 9.15 

Total PeCDD ND 4.00 

Total HxCDD ND 5.67 a. Sample specific estimated detection limit. 

Total HpCDD ND 3.09 b. Estimated maximum possible concentration. 

Total TCDF ND 2.36 c. Method detection limit. 

Total PeCDF ND 2.83 d. Lower control limit - upper control limit. 

Total HxCDF ND 1.98 e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF ND 3.08 

Analyst: MAS Approved By: William J. Luksemburg 27-Dec-2009 07:08 

32275 Page 4 of 18 

VES018160 
OPR Results Method 0023A 

Matrix: MM5 QC Balch No.: 2646 Lab Sample: 0-OPR001 

Sample Size: Sample Date Extracted: 21-Dec-09 Date Analyzed DB-5: 23-Dec-09 Date Analyzed DB-225: N A 

Analyte Spike Cone. Cone. (ng/mL) O PR Limits Labeled Standard %R LCL-UC L Qualifier 

2,3,7,8-TCDD 2.50 2.38 : 1.75-3.25 IS 13C-2,3,7,8-TCDD 103 40 - 135 

1,2,3,7,8-PeCDD 12.5 11.5 8.75 - 16.25 13C-l,2,3,7,8-PeCDD 119 40- 135 

1,2,3,4,7,8-HxCDD 12.5 14.9 8.75 - 16.25 13C-l,2,3,6,7,8-HxCDD 88:7 40 - 135 

1,2,3,6,7,8-HxCDD 12.5 11.2 8.75 - 16.25 13C-l,2,3,4,6,7,8-HpCDD 119 40 - 135 

1,2,3,7,8,9-HxCDD 12.5 12.8 8.75 - 16.25 13C-OCDD 126 40 - 135 

1,2,3,4,6,7,8-HpCDD 12.5 11.5 8.75- 16.25 13C-2,3,7,8-TCDF 103 40 - 135 

OCDD 25.0 22.3 17.5-32.5 13C-l,2,3,7,8-PeCDF 122 40-135 

2,3,7,8-TCDF 2.50 2.39 1.75-3.25 13C-l,2,3,6,7,8-HxCDF 90.1 40-135 

1,2,3,7,8-PeCDF 12.5 11.9 8.75 - 16.25 13C-l,2,3,4,6,7,8-HpCDF 107 40-135 

2,3,4,7,8-PeCDF 12.5 11.4 8.75 - 16.25 13C-OCDF 112 40- 135 

1,2,3,4,7,8-HxCDF 12.5 14.7 8.75 - 16.25 AS 13C-l,2,3,7,8,9-HxCDF 104 40 - 135 

1,2,3,6,7,8-HxCDF 12.5 12.0 8.75 - 16.25 

2,3,4,6,7,8-HxCDF 12.5 13.1 8.75 - 16.25 

1,2,3,7,8,9-HxCDF 12.5 13.0 8.75 - 16.25 

1,2,3.4,6,7,8-HpCDF 12.5 11.5 8.75 - 16.25 

1,2,3,4,7,8,9-HpCDF 12.5 12.4 8.75 - 16.25 

OCDF 25.0 22.9 17.5-32.5 

Analyst: MA S Approved By: William J. Luksemburg 27-Dec-2009 07:08 

Project 32275 Page 5 of 18 

VES018161 
V vista 

Sample ID: CPT-U2-M23A-XAD-R1 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: AECO M Environment 

Project: 60133216 

Date Collected: 8-Dec-09 

Time Collected: NA 

Matrix: 

Sample Size: 

M M5 

Sample 

Lab Sample: 32275-001 

QC Batch No.: 2646 

Date Analyzed DB-5" 23-Dec-09 

Date Received: 12-Dec-09 

Date Extracted 21-Dec-09 

Dates Analyzed DB-22S: 24-Dec-09 

Analyte Cone. (pg/Sample) D L

 a EMPC b Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD 4.14 J IS 13C-2,3,7,8-TCDD 99.1 40-135 

1,2,3,7,8-PeCDD 21.1 J 13C-l,2,3,7,8-PeCDD 105 40 - 135 

1,2,3,4,7,8-HxCDD 27:0 J 13C-l,2,3,6,7,8-HxCDD 89.4 40-135 

1,2,3,6,7,8-HxCDD 49.0 J 13C-1,2,3,4,6,7,8-HpCDD 116 40-135 

1,2,3,7,8,9-HxCDD 31.0 J 13C-OCDD 126 40-135 

1,2,3,4,6,7,8-HpCDD 203 13C-2,3,7,8-TCDF 105 40-135 

OCDD 167 13C-l,2,3,7,8-PeCDF 117 40-135 

2,3,7,8-TCDF 22.5 13C-l,27 3,6,7,8-HxCDF 82.6 40- 135 

•1,2,3,7,8-PeCDF 32.5 J 13C-1,2,3,4,6,7,8-HpCDF 105 40-135 

2,3,4,7,8-PeCDF 104 13C-OCDF 114 40-135 

1,2,3,4,7,8-HxCDF 55.1 ES 37Cl-2,3,7,8-TCDD 89.0 70-130 

1,2,3,6,7,8-HxCDF 47.0 LP 13C-2,3,4,7,8-PeCDF 89.7 70- 130 

2,3,4,6,7,8-HxCDF 96.0 13C-1,2,3,4,7,8-HxCDD 101 70-130 

1,2,3,7,8,9-HxCDF 24.8 J 13C-l,2,3,4,7,8-HxCDF 106 70-130 

1,2,3,4,6,7,8-HpCDF 114 13C- 1,2,3,4,7,8,9-HpCDF 93.2 70 - 130 

1,2,3,4,7,8,9-HpCDF 22.5 J AS !3C-l,2,3,7,8,9-HxCDF 108 40-135 

OCDF 42.5 J 

Totals Toxic Equivalent Quotieiit (TEQ) Data

 e 

Total TCDD 2530 2540 T E Q (Min-Max): 107-107 

Total PeCDD 1930 

Total HxCDD 4540 a. Sample specific estimated detection limit. 

Total HpCDD 457 b. Estimated maximum possible concentration. 

Total TCDF 1470 1510 P c. Method detection limit. 

Total PeCDF 1120 P d. Lower control limit - upper control limit. 

Total HxCDF 669 P e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF 202 

Analyst: MAS Approved By: William J. Luksemburg 27-Dec-2009 07:08 

ect 32275 Page 6 of 18 

VES018162 
Sample 11): CPT-U2-M23A-PF-R1 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: AECO M Environment 

Project: 60133216 

Date Collected: 8-Dec-09 

Time Collected: NA 

Matrix: 

Sample Size: 

M M5 

Sample 

Lab Sample: 32275-002 

QC Batch No.: 2646 

Date Analyzed DB-5: 23-DCC-09 

Date Received: 12-Dec-09 

Date Extracted: 21-Dec-09 

Date Analyzed DB-225 Ny\ 

Analyte Cone. (pg/Sample) D L

 a E!YIPCb Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD ND 2.87 IS 13C-2,3,7,8-TCDD 102 40- 135 

1,2,3,7,8-PeCDD N D 4.13 13C-l,2,3,7,8-PeCDD 106 40- 135 

1,2,3,4,7,8-HxCDD N D 5.22 13C-l,2,3,6,7,8-HxCDD 85.7 40- 135 

1,2,3,6,7,8-HxCDD ND 4.11 13C-1,2,3,4,6,7,8-HpCDD 115 40- 135 

1,2,3,7,8,9-HxCDD ND 4.31 13C-OCDD 121 40-135 

1,2,3,4,6,7,8-HpCDD ND 8.03 13C-2,3,7,8-TCDF 106 40- 135 

OCDD N D 8.89 13C-l,2,3,7,8-PeCDF 116 40 - 135 

2,3,7,8-TCDF ND 2.58 13C-1,2,3,6,7,8-HxCDF 80.6 40- 135 

1 2.3,7,8-PeCDF N D 3.92 13C-l,2,3,4,6,7,8-HpCDF 103 40-135 

2,3,4,7,8-PeCDF ND 4.15 13C-OCDF 109 40 - 135 

1,2,3,4,7,8-HxCDF ND 3.93 ES 37Cl-2,3,7,8-TCDD N A 70-130 

1,2,3,6,7,8-HxCDF ND 4.60 13C-2,3,4,7,8-PeCDF N A 70-130 

2,3,4,6,7,8-HxCDF N D 1,68 13C-l,2,3,4,7,8-HxCDD N A 70- 130 

1,2,3,7,8,9-HxCDF ND 1.89 13C-l,2,3,4,7,8-HxCDF N A 70-130 

1,2,3,4,6,7,8-HpCDF ND 3.11 13C-1,2,3,4,7,8,9-HpCDF NA 70-130 

1.2,3,4,7,8.9-HpCDF ND 4.10 M 13C-l,2,3,7,8,9-HxCDF 110 40-135 

OCDF N D 6.33 

Totals Toxic Equivalent Quotient (TEQ) Data

 e 

Total TCDD ND 2.87 T E Q (Min-Max): 0-10.2 

Total PeCDD ND 4.13 

Total HxCDD ND 8.34 a. Sample specific estimated detection limit. 

Total HpCDD ND 8.03 b. Estimated maximum possible concentration. 

Total TCDF ND 2.97 c. Method detection limit. 

Total PcCDF ND 4.03 d. Lower control limit - upper control limit. 

Total HxCDF ND 5.72 e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF) 

Total HpCDF ND 3.11 

Analyst: MA S Approved By: William J Luksemburg 27-Dec-2009 11:34 

Project 32275 Page 7 of 18 

VES018163 
Sample ID: CPT-U2-M23 A-XAD-R2 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: AECO M Environment 

Project. 60133216 

Date Collected: 9-DeC-09 

Time Collected: NA 

Matrix: 

Sample Size: 

M M5 

Sample 

Lab Sample: 32275-003 

QC Batch No.: 2646 

Date Analyzed DB-5: 23-Dec-09 

Date Received: ] 2-Dec-09 

Date Extracted: 21 -Dec-09 

Dales Analyzed DB-225: 24-Dec-09 

Analyte Cone. (pg/Sample) D L

 a EMPC b Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD ND 3.34 IS 13C-2,3,7,8-TCDD 95.0 40 - 135 

1,2,3,7,8-PeCDD 18.6 J 13C-1,2,3,7,8-PeCDD 105 40 - 135 

1,2,3,4,7,8-HxCDD 21.9 J 13C-1,2,3,6,7,8-HxCDD 90.1 40-135 

1,2,3,6,7,8-HxCDD 43.2 J 13C-1,2,3,4,6,7,8-HpCDD 117 40- 135 

1,2,3,7,8,9-HxCDD 24.7 J 13C-OCDD 125 40-135 

1,2,3,4,6,7,8-HpCDD 194 13C-2,3,7,8-TCDF 107 40 - 135 

OCDD 182 13C-l,2,3,7,8-PeCDF 114 40- 135 

2,3,7,8-TCDF 15.0 13C-l,2,3,6,7,8-HxCDF 84.8 40-135 

1,2,3,7,8-PeCDF 21.8 J 13C-1,2,3,4,6,7,8-HpCDF 106 40 - 135 

2,3,4,7,8-PeCDF 56.3 13C-OCDF 113 40-135 

1,2,3,4,7,8-HxCDF 46.1 i 37Cl-2,3,7,8-TCDD 102 70-130 

1,2,3,6,7,8-HxCDF 32.8 L P 13C-2,3,4,7,8-PeCDF 101 70-130 

2,3,4,6,7,8-HxCDF 55.0 13C- 1,2,3,4,7,8-HxCDD 120 70-130 

1,2,3,7,8,9-HxCDF 15.3 J 13C-l,2,3,4,7,8-HxCDF 123 70-130 

1,2,3,4,6,7,8-HpCDF 133 13C-1,2,3,4,7,8,9-HpCDF 116 70-130 

1,2,3,4,7,8,9-HpCDF 19.2 J AS 13C-l,2,3,7,8,9-HxCDF 106 40-135 

OCDF 73.0 J 

Totals Toxic Equivalent Quotient (TEQ) Data

 e 

Total TCD D 1960 1980 T E Q (Min-Max): 67.7 - 71.0 

Total PeCDD 1420 

Total HxCDD 3440 a. Sample specific estimated detection limit 

Total HpCDD 411 b. Estimated maximum possible concentration. 

Total TCDF 740 745 P c. Method detection limit. 

Total PeCDF 590 596 P d. Lower control limit - upper control limit. 

Total HxCDF 422 P e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF 214 

Analyst: MAS Approved By William J. Luksemburg 27-Dec-2009 07:08 

ect 32275 Pag e 8 o f 18 

VES018164 
Sample ID: CPT-U2-M23A-PF-R2 Method 0023A 

Client Data Sample Data Laboratory Data 

Name: .AECOM Environment 

Project: 601332] 6 

Date Collected: 9-Dec-09 

Time Collected: NA 

Matrix: 

Sample Size: 

M M5 

Sample 

Lab Sample: 32275-004 

QC Batch No.: 2646 

Date Analyzed DB-5. 23-Dec-09 

Date Received: 12-Dec-09 

Date Extracted: 21-Dec-09 

Date Analyzed DB-225: 

Analyte Cone. (pg/Sainple) D L

 a EMPC b Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD ND 2.27 IS 13C-2,3,7,8-TCDD 107 40-135 

1,2,3,7,8-PeCDD ND 3.34 13C-l,2,3,7,8-PeCDD 113 40- 135 

1,2,3,4,7,8-HxCDD ND 7.68 13C-l,2,3,6,7,8-HxCDD 88.4 40-135 

1,2,3,6,7,8-HxCDD ND 6.04 13C-l,2,3,4,6,7,8-HpCDD 124 40- 135 

1,2,3,7,8,9-HxCDD ND 6.34 13C-OCDD 132 40- 135 

1,2,3,4,6,7,8-HpCDD 5.41 J 13C-2,3,7,8-TCDF 108 40- 135 

OCDD 17.6 J 13C-l,2,3,7,8-PeCDF 123 40- 135 

2,3,7,8-TCDF ND 3.84 13C-1,2,3,6,7,8-HxCDF 82.7 40-135 

1,2,3,7,8-PeCDF ND 4.33 13C-1,2,3,4,6,7,8-HpCDF 107 40- 135 

2,3,4,7,8-PeCDF ND 4.58 13C-OCDF 118 40- 135 

1,2,3,4,7,8-HxCDF ND 3.11 PJ 37Cl-2,3,7,8-TCDD N A 70-130 

1,2,3,6,7,8-HxCDF ND 2.48 13C-2,3,4,7,8-PeCDF NA 70-130 

2,3,4,6,7,8-HxCDF ND 3:13 13C-1,2,3,4,7,8-HxCDD NA 70 - 130 

1.2,3,7,8,9-HxCDF ND 1.85 13C-l,2,3,4,7,8-HxCDF NA 70- 130 

1,2,3,4,6,7,8-HpCDF 9.35 .1 13C-1,2,3,4,7,8,9-HpCDF NA 70 - 130 

1,2,3,4,7,8,9-HpCDF ND 3.56 AS 13C-l,2,3,7,8,9-HxCDF 110 40- 135 

OCDF 5.75 1 

Totals Toxic Equivalent Quotient (TEQ) Data

 e 

Total TCDD ND 3.86 T E Q (Min-Max); 0.171 - 10.1 

Total PeCDD ND 6.35 

Total HxCDD 11.2 a. Sample specific estimated detection limit. 

Total HpCDD 5.41 b. Estimated maximum possible concentration. 

Total TCDF 3.09 5.70 c. Method detection limit. 

Total PeCDF ND 4.45 d. Lower control Hmit - upper control limit. 

Total HxCDF ND 6.45 e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF 9.35 

Analyst: MA S Approved By: William J. Luksemburg 27-Dec-2009 1 1:34 

Project 32275 Page 9 of 18 

VES018165 
V vist a 

Sample ro. CPT-U2-M23A-XAD-R3 Metho d 0023A 

Client Data Sample Data Laboratory Data 

Name: AECO M Environment 

Project: 60133216 

Dale Collected: 10-Dec-09 

Time Collected: N A 

Matrix: 

Sample Size: 

MM5 

Sample 

Lab Sample: 32275-005 

QC Batch No.: 2646 

Date Analyzed DB-5: 23-Dec-09 

Date Received: 12-Dec-09 

Date Extracted: 21-Dec-09 

Dates Analyzed DB-225: 24-Dec-09 

Analyte Cone. (pg/SampIe) D L

 a EMPC b Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD ND 4.80 IS 13C-2,3,7,8-TCDD 99.3 40- 135 

1,2,3,7,8-PeCDD 17.1 J 13C-l,2,3,7,8-PeCDD 103 40 - 135 

1,2,3,4,7,8-HxCDD , : NT) 17.7 13C-l,2,3,6,7,8-HxCDD 86.6 40- 135 

1,2,3,6,7,8-HxCDD 32.2 J 13C-1,2,3,4,6,7,8-HpCDD 113 40-135 

1,2,3,7,8,9-HxCDD 23.7 J 13C-OCDD 118 40-135 

1,2,3,4,6,7,8-HpCDD 149 13C-2,3,7,8-TCDF 105 40- 135 

OCDD 117 13C-l,2,3,7,8-PeCDF 109 40 - 135 

2,3,7,8-TCDF 14.1 13C- 1,2,3,6,7,8-HxCDF 82.6 40- 135 

1,2,3,7,8-PeCDF 16.6 J 13C-1,2,3,4,6,7,8-HpCDF 101 40-135 

2,3,4,7,8-PeCDF 50.1 13C-OCDF U l 40-135 

1,2,3,4,7,8-HxCDF 25.9 J £ S 37Cl-2,3,7,8-TCDD 97.4 70-130 

1,2,3,6,7,8-HxCDF 23.7 L P 13C-2,3,4,7,8-PeCDF 103 70- 130 

2,3,4,6,7,8-HxCDF 44.0 J 13C-1,2,3,4,7,8-HxCDD 122 70 - 130 

1.2,3,7,8,9-HxCDF 11.2 J 13C-l,2,3,4,7,8-HxCDF 120 70- 130 

1,2,3,4,6,7,8-HpCDF 63.5 13C-l,2,3,4,7,8,9-HpCDF 115 70-130 

1,2,3,4,7,8,9-HpCDF 11.6 J AS 13C-l,2,3,7,8,9-HxCDF 108 40-135 

OCDF 21.0 J 

Totals Toxic Equivalent Quotient (TEQ) Data

 c 

Total TCD D 1880 T E Q (Min-Max): 54.2 - 60.8 

Total PeCDD 1510 

Total HxCDD 2730 2750 a. Sample specific estimated detection limit. 

Total HpCDD 319 b. Estimated maximum possible concentration. 

Total TCDF 688 P c. Method detection limit. 

Total PeCDF 501 516 P d. Lower control limit - upper control limit. 

Total HxCDF 313 P e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF 111 

Analyst: MA S Approved By: William J. Luksemburg 27-Dec-2009 07:08 

Project 32275 Page 10 of 18 

VES018166 
i i ' 

V vista 

Sample BD: CPT-U2-M23A-PF-R3 Method 0023A 

Client Data Sample Data La bora tory Data 

Name: AECO M Environment 

Project: 60133216 

Date Collected: 10-Dec-09 

Time Collected: NA 

Matrix: 

Sample Size: 

M M5 

Sample 

Lab Sample: 32275-006 

QC Batch No.: 2646 

Date Analyzed DB-5: 23-Dec-09 

Date Received: 12-Dec-09 

Date Extracted: 21-Dec-09 

Date Analyzed DB-225 NA 

Analyte Cone. (pg/Sample) D L

 a EMPC b Qualifiers Labeled Standard % R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD ND 2.37 II 13C-2,3,7,8-TCDD 107 40-135 

1,2,3,7,8-PeCDD ND 3.70 13C-1,2,3,7,8-PeCDD 120 40- 135 

1,2,3,4,7,8-HxCDD N D 4.98 13C-1,2,3,6,7,8-HxCDD 88.1 40- 135 

1,2,3,6,7,8-HxCDD ND 3.92 13C-l,2,3,4,6,7,8-HpCDD 122 40- 135 

1,2,3,7,8,9-HxCDD ND 4.11 13C-OCDD 131 40 - 135 

1,2,3,4,6,7,8-HpCDD ND 8.70 13C-2,3,7,8-TCDF 105 40-135 

OCDD 14.2 J 13C-l,2,3,7,8-PeCDF 141 40-135 H 

2,3,7,8-TCDF N D 3.02 13C-l,2,3,6,7,8-HxCDF 83.1 40- 135 

1,2,3,7,8-PeCDF KD 3.52 :

 13C-1,2,3,4,6,7,8-HpCDF 107 40-135 

2,3,4,7,8-PeCDF ND 3.73 13C-OCDF 120 40-135 

1,2,3,4,7,8-HxCDF ND 2.61 PS 37Cl-2,3,7,8-TCDD N A 70-130 

1,2,3,6,7,8-HxCDF N D 1.57 13C-2,3,4,7,8-PeCDF N A 70- 130 

2,3,4,6,7,8-HxCDF N D 1.98 13C-l,2,3,4,7,8-HxCDD N A 70 - 130 

1.2,3,7,8,9-HxCDF N D 2.22 13C-l,2,3,4,7,8-HxCDF N A 70- 130 

1,2,3,4,6,7,8-HpCDF 6.49 J 13C-l,2,3,4,7,8,9-HpCDF N A 70 - 130 

1,2,3,4,7,8,9-HpCDF ND 2.28 AS 13C-l,2,3,7,8,9-HxCDF 109 40-135 

OCDF N D 7.44 

Totals Toxic Equivalent Quotient (TEQ) Data

 e 

Total TCDD N D 3.90 T E Q (Min-Max): 0.0791 - 8.89 

Total PeCDD ND 6.85 

Total HxCDD 7.84 a. Sample specific estimated detection limit 

Total HpCDD ND 8.70 b. Estimated maximum possible concentration. 

Total TCD F ND 3.65 c. Method detection limit. 

Total PeCDF N D 3.62 d. Lower control limit - upper control limit. 

Total HxCDF 3.04 e, TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF 6.49 

Analyst: MAS Approved By: William J. Luksemburg 27-Dec-2009 U :34 

Project 32275 Page II of IS 

VES018167 
w V vista 

Sample ID: CPT-TJ2-M23A-U2-FB Method 0023A 

Client Data Sample Data Laboratory Data 

Name: AECO M Environment 

Project: 60133216 

Date Collected: 10-Dec-09 

Time Collected: NA 

Matrix: 

Sample Size: 

M M5 

Sample 

Lab Sample: 32275-007 

QC Batch No.: 2646 

Date Analyzed DB-5. 23-Dec-09 

Date Received: 12-Dec-09 

Date Extracted: 21 -Dec-09 

Date Analyzed DB-225: N A 

Analyte Cone. (pg/Sainple) D L

 2 EMPC b Qualifiers Labeled Standard %R LCL-UCL d

 Qualifiers 

2,3,7,8-TCDD ND 2.60 IS l3C-2,3,7,8-TCDD 106 40-135 

1,2,3,7,8-PeCDD ND 4.10 13C- 1,2,3,7,8-PeCDD 111 40 - 135 

1,2,3,4,7,8-HxCDD ND 5.62 13C-l,2,3,6,7,8-HxCDD 87.6 40 - 135 

1,2,3,6,7,8-HxCDD ND 4.42 13C-1,2,3,4,6,7,8-HpCDD 119 40 - 135 

1,2,3,7,8,9-HxCDD N D 4.64 13C-OCDD 125 40- 135 

1,2,3,4,6,7,8-HpCDD ND 2.80 13C-2,3,7,8-TCDF 103 40- 135 

OCDD N D 6.10 13C-l,2,3,7,8-PeCDF 120 40-135 

2,3,7,8-TCDF ND 1.96 13C-1,2,3,6,7,8-HxCDF 86.1 40-135 

1,2,3,7,8-PeCDF ND 2.97 13C-l,2,3,4,6,7,8-HpCDF 108 40-135 

2,3,4,7,8-PeCDF ND 3.15 13C-OCDF 115 40- 135 

1,2,3,4,7,8-HxCDF ND 2.54 ES 37Cl-2,3,7,8-TCDD 99.5 70- 130 

1,2,3,6,7,8-HxCDF ND 2.02 13C-2,3:4,7,8-PeCDF 104 70- 130 

2,3,4,6,7,8-HxCDF ND 2.55 13C-l,2,3,4,7,8-HxCDD 129 70- 130 

1,2,3,7,8,9-HxCDF ND 2.87 13C-l,2,3,4,7,8-HxCDF 125 70-130 

1,2,3,4,6,7,8-HpCDF ND 1.74 13C-1,2,3,4,7,8,9-HpCDF 113 70-130 

1,2,3,4,7,8,9-HpCDF ND 2.23 A§ 13C-l,2,3,7,8,9-HxCDF 110 40-135 

OCDF ND 6.70 

Totals Toxic Equivalent Quotient (TEQ) Data

 e 

Total TCDD ND 2.60 T E Q (Min-Max): 0-9.12 

Total PeCDD ND 4.10 

Total HxCDD ND 4.84 a. Sample specific estimated detection limit. 

Total HpCDD ND 2.80 b Estimated maximum possible concentration. 

Total TCDF ND 1.96 c. Method detection limit. 

Total PeCDF ND 3.06 d. Lower control limit - upper control limit. 

Total HxCDF ND 2.46 e. TEQ based on (1989) International Toxic Equivalent Factors (ITEF). 

Total HpCDF ND 1.96 

Analyst: MAS Approved By: William J. Luksemburg 27-Dec-2009 07:08 

ect 32275 Page 12 of 18 

VES018168 
Vist a 

APPENDIX 

Project 32275 

Page 13 of 18 

VES018169 
^VlStQ 

DATA QUALIFIERS & ABBREVIATIONS 

B This compound was also detected in the method blank. 

D Dilution 

E The amount detected is above the High Calibration Limit. 

P The amount reported is the maximum possible concentration due to possible 

chlorinated diphenylether interference. 

H Recovery was outside laboratory acceptance limits. 

I Chemical Interference 

J The amount detected is below the Low Calibration Limit. 

* See Cover Letter 

Cone. Concentration 

D L Sample-specific estimated detection limit 

IVEDL The minimum concentration of a substance that can be measured and 

reported with 99% confidence that the analyte concentration is greater 

than zero in the matrix tested. 

EMP C Estimated Maximum Possible Concentration 

NA Not applicable 

R L Reporting Limit - concentrations that correspond to low calibration point 

ND Not Detected 

T E Q Toxic Equivalency 

Unless otherwise noted, solid sample results are reported in dry weight. Tissue samples are reported 

in wet weight. 

Project 32275 Page 14 of 18 

VES018170 
CERTIFICATIONS 

Accrediting Authority Certificate Number 

State of Alaska, DEC CA413-2008 

State of Arizona AZ0639 

State of Arkansas, DEQ 08-043-0 

State of Arkansas, DOH Reciprocity through CA 

State of California - NELAP Primary AA 02102CA 

State of Colorado N/A 

State of Connecticut PH-0182 

State of Florida, DEP E87777 

State of Indiana Department of Health C-CA-02 

Commonwealth of Kentucky 90063 

State of Louisiana, Health and Hospitals LA08000 

State of Louisiana, DEQ 01977 

State of Maine 2008024 

State of Michigan 9932 

State of Mississippi Reciprocity through CA 

Naval Facilities Engineering Service Center NFESC413 

State of Nevada CA004132007A 

State of New Jersey CA003 

State of New Mexico Reciprocity through CA 

State of New York, DOH 11411 

State of North Carolina 06700 

State of North Dakota, DOH R-078 

State of Oklahoma D9919 

State of Oregon CA200001-006 

State of Pennsylvania 68-00490 

State of South Carolina 87002001 

State of Tennessee TN02996 

State of Texas T104704189-08-TX 

U.S. Army Corps of Engineers N/A 

State of Utah CA16400 

Commonwealth of Virginia 00013 

State of Washington C1285 

State of Wisconsin 998036160 

State of Wyoming 8TMS-Q 

Project 32275 Page 15 of 18 

VES018171 
Sample Traceability List 

\ AECO M 

Site of Program; Veolia ES Tech Sample Date: |-2./«/e>1 - \i\\a\o*\ Project Location: Sauqet, IL Lab PO #': 

Type of Program: CPT •ate Shipped: ' tl/io/ol ' Laboratory: Vista Analytical 

Project*: 60133216 Shipper 1 Steven Milo El Dorado Hills, CA 

Recovery: .N-, »>• rAoenii / Jeff Gorman 

Laboratory: Vista Analytical 

El Dorado Hills, CA 

Prooram Office: Syracuse NY 

Shipper 1 Steven Milo 

Recovery: .N-, »>• rAoenii / Jeff Gorman 

Laboratory: Vista Analytical 

El Dorado Hills, CA 

Program Contact: Jeff Gorman 1 ,1 FedEx Air Bill #: 

Item Sample ID Code Sample Matrix Sample Description Analytical Parameters Special Instructions 

1 CPT-U2-M23A-XAD-R1 XAD2 RESIN M23 XAD Resin Trap, Run 1 PCDDs/PCDFs EPA 0023A 

2 CPT-U2-M23A-PF-R1 FILTER M23 PM Filter, Run 1 PCDDs/PCDFs EPA 0023A 

3 

4 CPT-U2-M23A-XAD-R2 XAD2 RESIN M23 XAD Resin Trap, Run 2 PCDDs/PCDFs EPA 0023A 

5 CPT-U2-M23A-PF-R2 FILTER M23 PM Filter, Run 2 PCDDs/PCDFs EPA 0023A 

6 

7 CPT-U2-M23A-XAD-R3 XAD2 RESIN M23 XAD Resin Trap, Run 3 PCDDs/PCDFs 

8 CPT-U2-M23A-PF-R3 FILTER M23 PM Filter, Run 3 PCDDs/PCDFs 

9 

10 CPT-M23A-PF-U2-FB FILTER Particulate Filter Field Blank PCDDs/PCDFs EPA 0023A 

11 CPT-M23A-XAD-U2-FB XAD2 RESIN Xad Resin Trap Field Blank PCDDs/PCDFs EPA 0023A 

12 CPT-M23A-U2 Field Blank Acetone/MeClaToluefle M23 Blank PCDDs/PCDFs EPA 0023A 

13 

14 CPT-U2-M23A-FHR-R1 Aceione/MaClj/Toiuene M23A Front Half Rinse, Run 1 PCDDs/PCDFs EPA 0023A 

15 C PT-U2-M23A-FH R-R2 Acelone/MeCI^Toluene M23A Front Half Rinse, Run 2 PCDDs/PCDFs EPA 0023A 

16 CPT-U2-M23A-FHR-R3 AcetoneyMeCI2Toluene M23A Front Half Rinse, Run 3 PCDDs/PCDFs EPA 0023A 

17 

18 CPT-U2-M23A-BHR-R1 Acelone/MeCl2/Toluene M23A Back Half Rinse, Run 1 PCDDs/PCDFs EPA 0023A 

19 CPT-U2-M23A-BHR-R2 Acetone/MeCl2/To!uene M23A Back Half Rinse, Run 2 PCDDs/PCDFs EPA 0023A 

20 CPT-U2-M23A-BHR-R3 Acetone/MeCIBToluene M23A Back Half Rinse, Run 3 PCDDs/PCDFs EPA 0023A 

Field Notes/ Comments 

Page 1 of 1 

Relinquished By (print): Date: 

Steven Milo ffifZp, 

2 f c ,; r 

Relinquished By (print): Date: 

Signature: Time: 

Relinquished By (print): Date: 

Signature: Time: t 

Received by Lab (print):, Date: j . 1 

Received By (print): Date: 

Signature: Time: 

Received By (print): Date: 

Signature: Time: 

Received By (print): Date: 

Signature: Time: 

Received Analytical Laboratory Destination: By (print): Date: 

Signature: Time: 

Received By (print): Date: 

Signature: Time: 

Received By (print): Date: 

Signature: Time: 

Vista Analytical Laboratories, Inc. 

1104 Wlndfield Way 

El Dorado Hills, CA 95762 

Attn: Ms. Martha Maier 916-673-1520 

Project 32275 Page 16 of IS 

VES018172 
Vista Project #: 

SAMPLE LOG-IN CHECKLIST 

TAT 

Wvist a 

w Analytical Laboratory 

Date/Time 

Samples Arrival: i r . „ ^ 

Initials: Location: [^Jj^''^-' 

Shelf/Rack: 1^/^ 

Logged In: 

Date/Time initials: Location: J 

Shelf/Rack: U.// ^ 

Delivered By: fTFedEx)! UPS I^JGgl DHL " a n d

 , Other Delivered 

Preservation: Ice f Blue Ice ^ Dry Ice None 

Temp°C ti . Time: Q6f [ Thermometer ID: IR-1 

mmmmmmmmmmmmmmmmmmm YES NO NA 

Adequate Sample Volume Received? 1/ 

Holding Time Acceptable? 

Shipping Container(s) Intact? 

Shipping Custody Seals Intact? 1 ^ 

Shipping Documentation Present? 

Airbill Trk# $(flb WfrQttl 

Sample Container Intact? 

Sample Custody Seals Intact? 

Chain of Custody / Sample Documentation Present? 

COC Anomaly/Sample Acceptance Form completed? 

If Chlorinated or Drinking Water Samples, Acceptable Preservation? 

Na2S2 03 Preservation Documented? 

Shipping Container (^Vista^ Client {^eTalrf^^ Return^ Dispose 

U 2 - F/3 

h\ur fob 

4 

Project 32275 

Sample Login 3/2007 rmh 

Page 17 of 18 

VES018173 
SAMPLE LOG-IN CHECKLIST 

Vista Project #:. TAT 

Vist a 

V Analytical Laboraiory 

Samples Arrival: 

Daterrime Initials: Location: (j(J\Z-£— 

Shelf/Rack: ^ ^A 

Logged In: 

Date/Time initials: Location: j 

Shelf/Rack: W ffif 

Delivered By: ^ UPS Cal DHL * and

. Other Delivered 

Preservation: Ice Blue Ice Dry Ice None 

Temp °C /^mWvyV Time: Q<\Z\ Thermometer ID: IR-1 

Adequate Sample Volume Received? 

Holding Time Acceptable? 

Shipping Container(s) Intact? 

Shipping Custody Seals Intact? 

Shipping Documentation Present? 

Airbill Trk# <=>?Jt ^11 0 

Sample Container Intact? 

Sample Custody Seals Intact? 

Chain of Custody / Sample Documentation Present? 

COC Anomaly/Sample Acceptance Form completed? 

If Chlorinated or Drinking Water Samples, Acceptable Preservation? 

Na2S2 03 Preservation Documented? 

Shipping Container Vista 

Comments: 

CPT-MZ3A-UZ FB 

i 

Retain 

3tfR /Fff£. 

Sample 

Container 

R3 

Project 32275 

Sample Login 3/7007 rmh 

Page 18 of 18 

VES018174 
Waste Feed 

VES018175 
festAmencQ 

THE LEADER IN ENVIRONMENTAL TESTING 

TestAmerica Laboratories, Inc, 

ANALYTICAL REPORT 

PROJECT NO. 60133216 

Veoli a - ES Tech 

Lot #: H9L140403 

Jef f Gorman 

AECOM, Inc 

5105 Carrrpuswopd Drive 

Suite 104 

East Syracuse, NT 13057 

TESTAMERICA LABORATORIES, INC. 

Kevin S. Woodcock 

Project Manager 

December 31, 2009 

5815 Middlebrook Pike Knoxville, TN 37921 tel 865.291.3000 fax 865.584.4315 www.testamericainc.co m 

VES018176 
ANALYTICAL METHODS SUMMARY 

H9L1404O3 

PARAMETER 

ANALYTICAL 

METHOD 

Ash Content 

Heat of Combustion 

Heat of Combustion D5B65 

Tota l Chlorine 

References: 

ASTM Annual Book Of ASTM Standards. 

ASTM D482-00a 

•ASTM D240-02 

ASTM D5865-00 

KNOX WC-0016 

KNOX TestAmerica Laboratories Inc., Knoxville Laboratory Standard 

Operating Procedure 
3 

SAMPLE SUMMARY 

H9H.40403 

WO # SAMPLES CLIENT SAMPLE ID 

SAMPLED SAMP 

DATE TIME 

LQ2TC 001 HBTU-U2-M23A-R1 12/08/09 

LQ2TD 002 HBTU-U2-M23A-R2 12/09/09 

LQ2TE 003 HBTU-02-M23A-R3 12/10/09 

LQ2TF 004 LBTU-U2-M23A-R1 12/08/09 

LQ2TG 005 LBTU-TJ2-M23A-R2 12/09/09 

LQ2TH 006 LBTU-U2-M23A-R3 12/10/09 

LQ2TJ 007 SF-U2-M23A-R1 12/08/09 

LQ2TK 008 SF-U2-M23A-R2. 12/09/09 

LQ2TL 009 SF-U2-M23A-R3 12/10/09 

LQ2TM 010 CS-U2-M23A-R1 12/08/09 

LQ2TP O i l CS-U2-M23A-R2 12/09/09 

LQ2TQ 012 CS-U2-M23A-R3 12/10/09 

LQ2TR 013 HBTU-U2-M26A-R1 12/08/09 

LQ2TT 014 HBTU-U2-M26A-R2 12/09/09 

LQ2TV 015 'HBTO-U2-M26A-R3 12/10/09 

LQ2TW 016 LBTU-U2-M26A-R1 12/08/09 

LQ2T0 017 LBTU-U2-M26A-R2 12/09/09 

LQ2TL 018 LBTU-U2-M26A-R3 12/10/09 

LQ2T3 019 SF-U2-M26A-R1 12/08/09 

LQ2T4 020 SF-U2-M26A-R2 . 12/09/09 

LQ2T5 021 SF-U2-M26A-R3 12/10/09 

LQ2T5 022 CS-U2-M26A-R1 12/08/09 

LQ2T7 023 CS-U2-M26A-R2 12/09/09 

LQ2T3 024 CS-U2-M26A-R3 12/10/09 

HQTE(S) ; 

- Till! anaiyiicai results of die samples listed above are presented on tlie following pages. 

- All calculations are performed before rounding to avoid round-off errors in calculated results. 

- Results noted as "ND" were not detected ot or above die slated limit. 

- Tlits report must not be reproduced, except in full, without die written approval of die laboralory. 

- Results for (lie following parameters are never reported on a dry weight basis: color, corrosiviiy. density, flashpoint, ignitability, layers, odor, 

paint filter test. pH, porosity pressure, reactivity, redox poiemial. specific gravity, spot lests. solids, solubility, temperature, viscosity, and weight. 

VES018178 
7 

QC DATA ASSOCIATION SUMMARY 

H9L140403 

Sample Preparation and Analysis Control Numbers 

ANALYTICAL 

SAMPLE* MATRIX METHOD 

001 WASTE ASTM D482-O0a 

WASTE KNOX WG-0016 

HASTE ASTM D240-02 

002 WASTE ASTM D482-O0a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

003 WASTE ASTM D482-O0a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

004 WASTE ASTM D482-0pa 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

005 WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

006 WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 ' 

007 WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

008 WASTE ASTM D482~00a 

WASTE KNOX WC-0016 

WASTE ASTM D24 0-02 

009 WASTE ASTM D4B2-O0a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

010 SOLID ASTM D482-00a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

011 SOLID ASTM D482-00a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

LEACH 

BATCH 

PREP 

BATCH '4 

9363434 

9351082 

9356348 

9363434 

9351082 

93S6348 

9363434-

9351082 

9356348 

9363434 

9351082 

9356348 

9363434 

9351082 

935634 8 

9363434 

9351082 

9356348 

9363434 

9352031 

9357188 

9363434 

9352031 

9357188 

9363434 

9352031 

9357188 

9363433 

9356065 

9350032 

9363433 

9356065 

9350032 

MS RONS 

9363224 

9363224 

9351116 

9356190 

9363223 

9356036 

9350021 

(Continued on next page) 

VES018179 
8 

QC DATA ASSOCIATION SUMMARY 

H9L140403 

Sample Preparation and Analysis Control Numbers 

SAMPLES 

012 

ANALYTICAL 

METHOD 

013 

014 

015 

01G 

o n 

018 

019 

020 

021 

022 

SOLID ASTM D482-00a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

WASTE , ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ' ASTM D240-02 

WASTE . ASTM D482-O0a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE ASTM D4B2-00a 

WASTE KNOX WC-O016 

WASTE ASTM D240-02 

WASTE ' ASTM D482-00a 

WASTE KNOX WC-O0I6 

WASTE ASTM D240-02 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE ASTM D4B2-O0a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D24O-02 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D24O-02 

WASTE ASTM D482-00a 

WASTE KNOX WC-0016 

WASTE ASTM D240-02 

SOLID ASTM D482-00a 

SOLID KNOX.WC-0016 

SOLID ASTM D5865-00 

LEACH ' 

BATCH # 

PREP 

BATCH $ 

9363433 

9356065 

9350032 

9363434 

9352031 

9357188 

9363434 

9352031 

9357188 

9363434 

9352031 

9357188 

9363434 

•9352031 

9357188 

9363434 

9352031 

9357188 

9363434 

9352031 

9357188 

9363434 

9352031 

9357188 

9363434 

9352031 

935718B 

9363434 

9352031 

9357188 

9363433 

9356065 

9350032 

MS RONS 

9352011 

9357125 

.9352011 

9357125 

(Continued on next page) 

VES018180 
9 

QC DATA ASSOCIATION SUMMARY 

H9L140403 

Sample Preparation and Analysis Control Numbers 

ANALYTICAL 

SAMPLE* MATRIX . METHOD 

023 SOLID ASTM D482-00a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

024 SOLID ASTM D482-00a 

SOLID KNOX WC-0016 

SOLID ASTM D5865-00 

LEACH 

BATCH 

PREP 

BATCH » 

9363433 

9356065 

9350032 

9363433 

9356065 

9350032 

MS RUN if 

VES018181 
10 
11 

Lot-Sample #. 

Bate Sampled. 

PARAMETER 

AECOM, Inc 

Clien t Sample ZD: HBTU-02-M23A-R1 

General Chemistry 

H9L140403-001 Work Order #...: LQ2TC 

12/08/09 Date Received..: 12/11/09 

Matrix : WASTE 

RESDLT RL ONITS 

Ash Content 

Gross Calorifi c 

Value 

Tota l Chlorine 

1370 200 mg/kg 

Dilution Factor: 1 

9190 1800 BT0/lb 

Dilution Factor: 1 • 

16200 1690 mg/kg 

Dilution Factor: 8.46 

METHOD 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL : 130 

KHOX WC-0016 

MDL. i : 510 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363434 

12/22/09 9356348 

12/17-12/18/09 9351082 

VES018183 
12 

AECOM, Inc 

Clien t Sample IDs HBTU-U2 -M23A-R2 

General Chemistry 

Lot-Sample #... 1 H9L140403-002 Work Order #.. 

Date Sampled— : 12/09/09 Date Received. 

PARAMETER RESULT RL DNITS 

Ash Content 

Gross Calorifi c 

Value 

Tota l Chlorine 

1910 200 mg/kg 

Dilution Factor: 1 

9430 1800 BTO"/lb 

Dilution Factor: 1 

14200 1540 mg/kg 

Dilution Factor: 8.18 

LQ2TD 

12/11/09 

Matrix. WASTE 

_ METHOD -

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL ' : 130 

KNOX WC-0016 

MDL

 J : 490 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363434 

12/22/09 9356348 

12/17-12/18/09 9351082 

VES018184 
13 

AECOM, Inc 

Clien t Sample ID: HBTO-02-M23A-R3 

General Chemistry 

Lot-Sample #..,: H9L140403-003 Work Order #...: LQ2TE 

Date Sampled. : 12/10/09 Date Received..: 12/11/09 

Matrix. WASTE 

PARAMETER RESULT RL UNITS 

Ash Content. 

Gross Calorifi c 

Value 

Total Chlorine 

2490 200 mg/kg 

Dilution Factor: l 

9870 1800 BTU/lb 

Dilution Factor: 1 

13900 1700 mg/kg 

Dilution Factor: 8.El 

_• METHOD 

ASTM D482-00a 

MDI. : SI 

ASTM D240-02 

MDL.. .: 130 

KNOX WC-0016 

MDL : 510 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363434 

12/22/09 9356348 

12/17-12/18/09 9351082 

VES018185 
14 

AECOM, Inc 

Clien t Sample ID: LBTET-U2-M23A-R1 

General Chemistry 

Lot-Sample #...: H9L140403-004 Work Order #... t LQ2TF Matrix : WASTE 

Date Sampled.12/08/0 9 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESPLT RL DNITS METHOD • ANALYSIS DATE BATCH # 

Ash Content 2340 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 MDL : 51 

Gross Calorifi c ND 1800 BTD/lb ASTM D240-02 12/22/09 9356348 

Value 

Dilution Factor: 1 MDL : 130 

Tota l Chlorine 1120 306 mg/kg KNOX WC-0016 12/17-12/18/09 9351082 

Dilution Factor: 1.53 MDL : 32 

VES018186 
15 

AECOM, Inc 

Clien t Sample ID: LBTU-TJ2-M23A-R2 

General Chemistry 

Lot-Sample #...: H9L140403-005 Work Order ft...: LQ2TG Matrix. : WASTE 

Date Sampled : 12/09/09 Date Received..: 12/11/09 

PARAMETER RESULT RL OMITS 

200 mg/kg 

Dilution Factors 1 

1800 BTU/lb 

Dilution Factor: 1 

290 mg/kg 

Dilution Factor: 1.45 

METHOD 

ASTM D482-00a 

MDL. . : 51 

ASTM D240-02 

MDL : 130 

KNOX WC-0016 

MDL : 87 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363434 

12/22/09 9356348 

12/17-12/18/09 9351082 

Ash Content 1900 

Gross Calorifi c ND 

Value 

Tota l Chlorine 988 

VES018187 
16 

AECOM, Inc 

Clien t Sample ID: LBTTJ-D2 -M23A-R3 

General Chemistry 

tot-Sample #...: H9L140403-006 Work Order ft-..: LQ2TH Matrix..... :. WASTE 

Date Sampled...: 12/10/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER ' RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

A sh Content 2290 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 MDL SI 

Gross Calorifi c 134 B 1800 BTU/lb ASTM D240-02 12/22/09 9356348 

Value 

Dilution Factor: 1 MDL -. : 130 

Total Chlorine 1140 288 mg/kg KNOX WC-0016 12/17-12/18/09 9351082 

Dilution Factor: 1.44 MDL s. 86 

HOTE (S) : \ .' • • * . . 

RL Reporting Limit 

B Estimated result. Result is less than Rl. 

VES018188 
17 

AECOM, Inc 

Clien t Sample.ID: SF-D2-M23A-R1 

General Chemistry 

Lot-Sample #...: H9L140403-007 Work Order #-..: LQ2TJ Matrix . ..: WASTE 

Date Sampled...: 12/08/09 Date Received..:. 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL OMITS . METHOD ANALYSIS DATE BATCH # 

Ash Content 7420 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 MDL.- : 51 

Gross Calorifi c ND 1800 BTU/lb ASTM D240-02 12/23/09 9357188 

Value. 

Dilution Factor: 1 MDL : 130 

Tota l Chlorine 4730 840 mg/kg KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 4.2 MDL : 250 

VES018189 
18 

AECOM, Inc 

Clien t Sample ID: SF-U2-M23A-R2 

General Caemistry 

Lot-Sample ii...: H9L140403-OOB Work Order : LQ2TK Matrix : WASTE 

Date Sampled...: 12/09/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 7720 200 mg/kg ASTM D482^00a 12/29-12/31/09 9363434 

Dilution Factor: 1 MDL : 51 

Gross Calorifi c ND 1800 BTU/lb ASTM D240-02 12/23/09 9357188 

Value 

Dilution Factor: 1 MDL. : 130 

Total Chlorine 4830 824 mg/kg KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 4.12 MDL 250 

VES018190 
19 

AECOM, Inc 

Clien t Sample ID: SF-TJ2-M23A-R3 

General ChemistryLot-Sample #...: H9L140403-009 .Work Order #...: LQ2TL 

Date Sampled.. 

PARAMETER 

12/10/09 

RESULT 

Date Received..: 12/11/09 

RL UNITS METHOD 

Matrix : WASTE 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Ash Content 

Gross Calorifi c 

VaLue 

Tota l Chlorine 

7540 200 mg/kg 

Dilution Factor: i 

ND 1800 BTU/lb 

Dilution Factor; 1 

4810 838 mg/kg 

Dilution Factor: 4.19 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

KNOX WC-0016 

MDL : 2S0 

12/29-12/31/09 9363434 

12/23/09 93571B8 

12/21-12/28/09 9352031 

VES018191 
20 

AECOM, Inc 

Clien t Sample ID: CS-U2-M23A-R1 

General Chemistry 

Lot-Sample #...: H9L140403-010. Work Order #...: LQ2TM Matrix..,......: SOLID 

Date Sampled...: 12/08/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL . UNITS METHOD . ANALYSIS DATE BATCH # 

A sh Content 716000 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363433 

Dilution Factor: 1 MDL, : 51 

Gross Calorifi c ND . 1800 BTU/lb . ASTM D5865-00 12/16/09 9350032 

value 

Dilution Factor: 1 MDL 130 

Tota l Chlorine 129 B 202 mg/kg KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 1.01 MDL : 61 

NOTB<S): ' [ . ; 

R l Reporting Umil 

B Estiniatnl result. Result is less than RL. 

VES018192 
21 

AECOM, Inc 

Clien t Sample ID: CS-02-M23A-R2 

General Chemistry 

Lot-Sample #...: H9L140403-011 Work Order #...: LQ2TP Matrix : SOLID 

Date Sampled...: 12/09/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

A sh Content 713000 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363433 

Dilution Factor: 1 MDL : 51 

Gross Calorifi c ND 1800 BTU/lb ASTM D586S-00 12/16/09 9350032 

Value 

Dilution Factor: 1 MDL : 130 

Tota l Chlorine 134 B 200 mg/kg KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 1 MDL : 60 

HOTE(S) : ; ; ' \ 

RL Reportins Limil 

B Estimated result. Result is less than RL. 

VES018193 
22 

AECOM, Inc 

Clien t Sample ID: CS-02-M23A-R3 

General Chemistry 

Lot-Sample : H9L140403r012 Work Order #...: LQ2TQ Matrix ..: SOLID 

Date Sampled : 12/10/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESOLT RL DNITS METHOD ANALYSIS DATE BATCH # 

Ash. Content 708000 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363433 

Dilution Factor: 1 ' MDL = 51 

Gross Calorifi c ND 1800 BTO/lb ASTM D5S65-00 12/16/09 9350032 

Value 

Dilution Factor: 1 MDL ...': 130 

Tota l Chlorine 141 B 200 mg/kg KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 1 MDL : 60 

mote ts): ' ; ; ; 

RL Reporting Limit 

B Estimated result. Result is less than M-. 

VES018194 
23 

AECOM, Inc 

Clien t Sample JD: HBTU-T/2-M26A-R1 

General Chemistry 

Lot-Sample ii...: H9L14Q403-013 Work Order : LQ2TR Matrix : WASTE 

Date Sampled...: 12/08/09 Date Received. 12/11/09 

PARAMETER RESULT RL UNITS 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

1360 200 mg/kg 

Dilution Factor: 1 

10200 1800 BTU/lb 

Dilution Factor: 1 

15300 1680 mg/kg 

Dilution Factor: 8.39 

_ METHOD _ _ 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL : 130 

KNOX WC-0016 

MDL : 500 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363434 

12/23/09 9357188 

12/21-12/28/09 9352031 

VES018195 
24 

AECOM, Inc 

Clien t Sample Hi: HBTU-U2-M26A-R2 

General Chemistry 

Lot-Sample if... : H9L140403-.014 Work Order #...: LQ2TT Matrix. : WASTE 

Date Sampled...; 12/09/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS • METHOD ANALYSIS DATE BATCH # 

Ash Content I860 200 rag/kg ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 MDL ..: 51 

Gross Calorifi c 9810 1800 BT0/lb ASTM D240-02 12/23/09 9357188 

Value 

Dilution Factor: 1 MDL 130 

Tota l Chlorine 13500 1690 mg/kg KNOX WC-0016 12/21-12/28/09 9352031 

. Dilution Factor: 8.47 MDL , i 510 

VES018196 
25 

AECOM, Inc ' _ 

Clien t Sample ID: HBTU-02-M26A-R3 _ 

General Chemistry 

Lot-Sample #...:• H9L140403-01S Work Order ft...: LQ2TV Matrix : WASTE 

Date Sampled...: 12/10/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 2950 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 MDL. >....! 51 

Gross Calorifi c 9810 1800 BTU/lb ASTM D240-02 12/23/09 9357188 

Value 

Dilution Factor: 1 MDL ;..: 130 

Tota l Chlorine 14500 1680 mg/kg KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: a.4 MDL : 500 

VES018197 
26 

AECOM, Inc 

Clien t Sample ID: LBTU-U2-M26A-R1 

General ChemistryLot-Sample #. ..: H9L140403-016 Work Order #...: LQ2TW 

Date Sampled--.: 12/08/09 Date Received..: 12/11/09 

PARAMETER RESULT RL UNITS METHOD 

Matrix : WASTE 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

2260 200 mg/kg 

Dilution Factor: 1 

ND 1800 BTU/lb 

Dilution Factor: 1 

1180 278 mg/kg 

Dilution Factor: 1.-39 

ASTM D482-00a 

MDL. : 51-

' ASTM D240-02 

MDL , : 130 

KNOX WC-0016 

12/29-12/31/09 9363434 

12/23/09 935718B 

12/21-12/29/09 9352031 

MDL. S3 

VES018198 
27 

AECOM, Inc 

Clien t Sample ID: LBTU-U2-M26A-R2 

General Chemistry 

lot-Sample*...: H9L140403-017 Work Order LQ2T0 Matrix .: WASTE 

Date Sampled...: 12/09/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ' ANALYSIS DATE BATCH # 

Ash Content 1990 200 mg/kg ASTM D482-O0a 12/29-12/31/09 9363434 

Dilution Factor: 1 MDL : 51 

Gross Calorifi c ND 1800 BTU/lb ASTM D240-02 . 12/23/09 9357188 

Value 

Dilution Factor: 1 MDI... : 130 

Tota l Chlorine 1060 280 mg/kg KNOX WC-0016 12/21-12/29/09 9352031 

Dilution Factor: 1.4 MDL : 84 

VES018199 
28 

AECOM, Inc 

Clien t Sample ID: JLBTO-U2-M26A-R3 

, . General Chemistry 

Lot-Sample it. ..: H9L140403-018 Work Order #...: LQ2T1 Matrix ..: WASTE 

Date Sampled...: 12/10/09 Date Received..= 12/11/09 

PREPARATION- PREP 

PARAMETER , RESULT RL UNITS METHOD • ANALYSIS DATE BATCH # 

Ash Content 2350 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 MDL : 51 

Gross Calorifi c ND 1800 BTU/lb ASTM D240-02 .12/23/09 9357188 

Value 

Dilution Factor: 1 MDL 13 0 

Total Chlorine 1230 282 mg/kg KNOX WC-0016 12/21-12/29/09 9352031 

Dilution Factor: 1.41 MDL : 85 

VES018200 
29 

AECOM, Inc 

Clien t Sample ID: SF-U2-M26A-R1 

General Chemistry 

Lot-Sample ft...: H9L140403-019 Work Order : LQ2T3 Matrix.... : WASTE 

Date Sampled : 12/08/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 7760 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor; 1 MDL : 51 

Gross Calorifi c ND 1800 BTU/lb ASTM D240-02 12/23/09 9357188 

Value 

Dilution Factor: 1 MDL........:...; 130 

Tota l Chlorine 4970 840 mg/kg KHOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 4.2 MDL. : 250 

VES018201 
30 

Lot-Sample ft.., 

Date Sampled... 

PARAMETER 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

AECOM, Inc 

Clien t Sample XTJ: SF-U2-M26A-R2 

General Chemistry 

H9L140403-020 

12/09/09 

RESULT 

Work Order #... 

Date Received.. 

RL UNITS 

8060 200 mg/kg 

Dilution Factor: 1 

ND 1800 BTU/lb 

Dilution Factor: 1 

4510 836 mg/kg 

Dilution Factor: 4.18 

LQ2T4 

12/11/09 

METHOD 

Matrix. WASTE 

ASTM D482-00a 

MDL,, : 51 

ASTM D240-02 

MDL. : 130 

KNOX WC-0016 

MDL. 250 

PREPARATION- PREP 

ANALYSIS DATE BATCH ft 

12/29-12/31/09 9363434 

12/23/09 9357188 

12/21-12/28/09 9352031 

VES018202 
31 

AECOM, Inc 

Clien t Sample ID: SF-U2-M26A-R3 

General Chemistry 

Lot-Sample : H9L140403-021 Work Order : LQ2T5 Matrix : WASTE 

Date Sampled. : 12/10/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER . RESULT Rl; UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 7930 200 mg/kg ASTM D4B2-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 MDL .- SI 

Grpss Calorifi c ND . 1800 BTU/lb ASTM D240-02 12/23/09 9357188 

Value 

Dilution Factor: 1 MDL : 13 0 

Tota l Chlorine 4790 844 mg/kg KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 4.22 . HDL ..: 250 

VES018203 
32 

Lot-Sample #...: H9L140403-022 

Date Sampled : 12/08/09 

AECOM, Inc 

Clien t Sample ID: CS-U2-M26A-R1 

General ChemistryWork Order #...: LQ2T6 

Date Received..: 12/11/09 

Matrix.» i SOLID 

RESULT RL UNITS METHOD 

PREPARATION- PREP 

PARAMETER ANALYSIS DATE BATCH # 

Ash Content , 809000 200 mg/kg 

Dilution Factor: 1 

Gross Calorifi c ND 1800 BTU/lb 

Value 

Dilution Factor: 1 

Total Chlorine ND 200 mg/kg 

Dilution Factor: 1 

ASTM D482-00a 12/29-12/31/09 9363433 

MDL : 51 

ASTM D5865-00 12/16/09 9350032 

MDL ..: 130 

KNOX WC-0016 12/22-12/29/09 9356065 

MDL : 60 

VES018204 
33 

AECOM, Inc 

Clien t Sample ID: CS-D2-M26A-R2 

General Chemistry 

Lot-Sample H9L140403-023 Work Order : LQ2T7 

Date Sampled...: 12/09/09 Date Received..: 12/11/09 

Matrix : SOLID 

PARAMETER RESULT RL UNITS 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

787000 200 mg/kg 

Dilution Factor: 1 

ND 1800 BTU/lb 

Dilution Factor: 1 

ND 200 mg/kg 

Dilution Factor: 1 

_ METHOD 

ASTM D482-00a 

.MDL : 51 

ASTM D5865-00. 

MDL : 130 

KNOX WC-0-016 

MDL : 60 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363433 

12/16/09 9350032 

12/22-12/29/09 9356065 

VES018205 
34 

AECOM,. Inc 

Clien t Sample ID: CS-U2-M26A-R3 

General Chemistry 

Lot-Sample #. . .: H9L140403-024 Work Order #...: LQ2T8 

Date Sampled : 12/10/09 Date Received..: 12/11/09 

PARAMETER . RESULT RL UNITS METHOD 

Matrix : SOLID 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

769000 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363433 

Dilution Factor: 1 MDL : SI 

ND 

ND 

1800 BTU/lb ASTM DS865-00 12/16/09 

Dilution Factor: 1 MDL ,...: 130 

9350032 

200 mg/kg KNOX WC-0016 12/22-12/29/09 9356055 

Dilution Factor: 1 MDL : 60 

VES018206 
35 

Client lo t H9L140403 

PARAMETER 

Ash Content 

RESULT 

METHOD BLANK REPORT 

General Chemistry 

REPORTING 

LIMIT UNITS METHOD 

Matrix : WASTE 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Work Order #: LRPQFIAA MB Lot-Sample #: H9L290000-434 

ND 200 mg/kg ASTM D482-O0a 12/29-12/31/09 93S3434 

Dilution Factor: 1 

Total Chlorine Work Order #: LQ76D1AA MB Lot-Sample #: H9L170000-082 

ND 200 tng/kg KNOX WC-0016 12/17-12/18/09 9351082 

Dilution Factor: 1 . 

Total Chlorin e Work Order #; LRAEQ1AA MB Lot-Sample #: H9L180000-031 

ND 200 mg/kg KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 1 

NOTJtS) 

Calculators arc pcrrormcd bcfori: rounding to avoid rauntl-off errors in calculated results. 

VES018207 
36 

Clien t Lot H9L140403 

PARAMETER RESULT 

Ash Content 

ND 

METHOD BLANK REPORT 

General Chemistry 

Matrxx. SOLID 

REPORTING 

LIMIT UNITS METHOD 

PREPARATION- PREP 

• ANALYSIS DATE BATCH # 

Work Order #: LRPQE1AA MB Lot-Sample #: H9L290000-433 

200 mg/kg ASTM D482-00a 12/29-12/31/09 9363433 

Dilution Factor: 1 

Total Chlorine Work Order #:' LRGLV1AA MB Lot-Sample #.- H9L220000-065 

ND 200 mg/kg KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 1 

NOTE(S) : . 

Calculations arc performed before rounding lo avoid roundoff errors in calculated results. 

VES018208 
37 

LABORATORY CONTROL SAMPLE EVALUATION REPORT 

General Chemistry 

Lot-Sample #. H9L140403 Matrix : SOLID 

PERCENT RECOVERY RPD 

PARAMETER RECOVERY LIMITS RPD LIMITS METHOD 

Ash Content 

100 

i o o 

PREPARATION- PREP 

; ANALYSIS DATE BATCH # 

W0#:LRPQE1AC-LCS/LRPQE1AD-LCSD LCS Lot-Sample*: H9L290000-433 

(90 - 110) ASTM D482-O0a 12/29-12/31/09 9363433 

(90 - 110) 0.32 (0-10) ASTM D4B2-O0a 12/29-12/31/09 9363433 

Dilution Factor; 1 

Gross Calorifi c 

Value 

100 

100 

W0#:LQS8P1AA-LCS/LQ58P1AC-LCSD LCS Lot-Sample*: H9L160000-032 

(98 - 102) ASTM D5865-00 

(98 - 102) 0.10 (0-2.0) ASTM D5865-00 

Dilution Factor: 1 

12/16/09 

12/16/09 

9350032 

9350032 

NOTB(S) : 

Calculations arc pcrrormcd before rounding to avoid round-off errors in calculated results. 

VES018209 
38 

LABORATORY COHTROL SAMPLE DATA REPORT 

General Chemistry 

Lot-Sample #...: H9L140403 Matrix : SOLID 

PARAMETER 

Ash Content 

SPIKE MEASURED 

AMOUNT AMOUNT UNITS 

PERCNT 

RECVRY RPD. METHOD 

4000 

4000 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

W0#:LRPQE1AC-LCS/LRPQE1AD-LCSD LCS Lot-Sample#: H9L290000-433 

4000 mg/kg 100 ASTM D482-0Oa 12/29-12/31/09 9363433 

3990 mg/kg 100 0.32 ASTM D4B2-00a 12/29-12/31/09 93S3433 

Dilution Factor.- 1 

Gross Calorifi c 

Value 

11400 

11400 

WO#-.LQ58PlAA-LCS/LQ58PlAC-LCSD LCS Lot-Sample*: H9L160000-032 

11300 BTU/lb 100 

11300 BTU/lb 100 

Dilution Factor: 1 

ASTM D58S5-00 

0.10 ASTM D5865-00 

12/16/09 

12/16/09 

93S0032 

9350032 

NOTE(S) : 

Calculations arc performed before rounding to avoid round-off errors in calculated results. 

VES018210 
.39 

LABORATORY CONTROL SAMPLE EVALUATION REPORT 

General Chemistry 

Lot-Sample H9L140403 

PERCENT RECOVERY RPD 

PARAMETER RECOVERY LIMITS RPD_ LIMITS METHOD 

Ash Content 

Matrix: r WASTE 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

W0#:LRPQP1AC-LCS/LRPQP1AD-LCSD LCS Lot-Sample#: H9L290000-434 

100 (90 - 110) ASTM D482-00a 12/29-12/31/09 9363434 

99 (90 - 110) 0.93 (0-10) ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 

Gross Calorifi c 

Value 

100 

99 

W0#:LRG6J1AA-LCS/LRG6J1AC-LCSD LCS Lot-rSample*: H9L220000-348 

(98 - 102) ASTM D240-02 

(98 - 102) 0.42 (0-2.0) ASTM D240-02 

Dilution Factor: 1 

12/22/09 9356348 

12/22/09 9356348 

Gross Calorifi c 

Value 

100 

100 

W0#:LRJKE1AA-LCS/LRJKE1AC-LCSD LCS Lot-Sample*: H9L2300O0-188 

(98 - 102) ASTM D240-02 

(98 - 102) 0.04 (0-2.0) ASTM D240-02 

Dilution Factor: 1 

12/23/09 9357188 

12/23/09 9357188 

NOTE(S): 

Calculations arc pcrrormcd before rounding to avoid round-orf errors in calculated results. 

VES018211 
40 

LABORATORY CONTROL SAMPLE DATA REPORT 

General Chemistry 

Lot-Sample #.. H9L140403 Matrix. WASTE 

PARAMETER 

Ash Content 

SPIKE 

AMOUNT 

4000 

4000 

MEASURED 

AMOUNT UNITS 

PERCNT 

RECVRY RPD METHOD 

PREPARATIONANALYSIS DATE 

PREP 

BATCH # 

W0#:LRPQF1AC-LCS/LRPQF1AD-LCSD LCS Lot-Sample#: H9L290O00-434 

3980 mg/kg 100 ASTM D482-O0a 12/29-12/31/09 9363434 

3940 mg/kg 99 0.93 ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 

Gross Calorifi c 

Value 

20600 

20600 

W0#:LRG6J1AA-LCS/LRG6J1AC-LCSD LCS Lot-Sample*: H9L220O00-348 

20500 BTU/lb 100 

20500 BTU/lb 99 

Dilution Factor: 1 

ASTM D240-02 

0.42 ASTM D240-02 

12/22/09 

12/22/09 

93S634B 

9356348 

Gross Calorific ' 

Value 

20600 

20600 

W0#:LRJKE1AA-LCS/LRJKE1AC-LCSD LCS Lot-Sample*: H9L230O00-188 

20500 BTU/lb 100 

20500 BTU/lb 100 

Dilution Factor: 1 

ASTM D240-02 

0.04 ASTM D240-02 

12/23/09 

12/23/09 

9357188 

9357188 

NOTB(S ) : 

Calculations arc performed before rounding to avoid round-off errors in calculated results. 

VES018212 
41 

LABORATORY COHTROL SAMPLE EVALXJATIOH REPORT 

General Chemistry 

Clien t Lot : H9L140403 Matrix : WASTE 

PERCENT RECOVERY PREPARATION- PREP 

PARAMETER RECOVERY LIMITS - METHOD ' ANALYSIS DATE BATCH # 

Total Chlorine Work Order #: LQ76D1AC LCS Lot-Sample#: H9L170000-082 

100 (80 - 120) KNOX WC-0016 12/17-12/18/09 9351082 

Dilution Factor: S 

Total Chlorine Work Order #: LRAEQ1AC LCS Lot-Sample*: H9L180000-031 

96 - (80 - 120) KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 5 

NOTE(S) : . . ' • 

CalculMions arc pcrrormcd before rounding lo avoid round-off errors in calculated results. 

VES018213 
42 

LABORATORY COHTROL SAMPLE DATA REPORT 

General Chemistry 

Clien t Lot : H9L140403 Matrix..... : WASTE 

SPIKE MEASURED .PERCNT PREPARATION- PREP 

PARAMETER AMOUNT AMOUNT UNITS RECVRY METHOD ANALYSIS DATE BATCH # 

Total Chlorine Work Order #: LQ76D1AC LCS Lot-Sample*: H9L170000-082 

10000 9950 mg/kg 100 KNOX WC-0016 12/17-12/18/09 9351082 

Dilution Factor: S 

Total Chlorine Work Order #: LRAEQ1AC LCS Lot-Sample*: H9L180000-031 

10OO0 9570 mg/kg 96 KNOX WC-0016 . 12/21-12/28/09 9352031 

Dilution Factor: S 

NOTE(S) : ; 

Calculations arc pcrrormcd before rounding io avoid round-ofr errors in calculous! results. 

VES018214 
43 

LABORATORY CONTROL SAMPLE EVALUATION REPORT 

General Chemistry 

Clien t Lot #.-.: H9L1404Q3 Matrix ; SOLID 

PERCENT RECOVERY PREPARATION- PREP 

PARAMETER ' RECOVERY LIMITS METHOD ' ANALYSIS DATE BATCH # 

Tota l Chlorine Work Order #: LRGLV1AC LCS Lot-Sample*: H9L22000G-OS5 

95 [80 - 120) KNOX WC-001S 12/22-12/29/09 9356065 

Dilution Factor; 5 

_ HOTE(S) : ' \ 

Calculations arc pcrrormcd before rounding id avoid round-off errors in calculaied results. 

VES018215 
44 

LABORATORY CONTROL SAMPLE DATA REPORT 

General Chemistry 

Clien t Lo t H9L140403 Matrix : SOLID 

SPIKE MEASURED • PERCNT PREPARATION- PREP 

PARAMETER AMOUNT AMOUNT UNITS RECVRY METHOD ANALYSIS DATE BATCH # 

Tota l Chlorine Work Order #: LRGLV1AC LCS Lot-Sample#: H9L220000-065 

10000 9480 mg/kg 95 KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 5 

NOTE(S) ; • ; 

Calculations are performed before rounding io avoid round-off errors in calculated rcsulis. 

VES018216 
45 

MATRIX SPIKE SAMPLE EVALUATION REPORT 

Clien t Lot #...: H9L140403 

Date Sampled : 12/08/09 

General Chemistry 

Date Received..: 12/11/09 

Matrix : WASTE 

PARAMETER 

PERCENT RECOVERY 

RECOVERY LIMITS RPD 

RPD 

LIMITS METHOD 

PREPARATIONANALYSIS DATE PREP 

BATCH # 

Tota l Chlorine 

100-

99 

WOft: LQ2TG1AG-MS/LQ2TG1AH-MSD MS Lot-Sample #: H9L14O403-005 

(80 - 120) KNOX WC-0016 12/17-12/18/09 9351082 

(80 - 120) 1.5 (0-10) KNOX WC-0016 12/17-12/18/09 9351082 

Dilution Factor: 6.SB 

Tota l Chlorine 

87 

97 

W0#: LQ2TR1AE-MS/LQ2TR1AF-MSD MS Lot-Sample #: H9L140403-013 

(80 - 120) KNOX WC-0016 12/21-12/28/09 9352031 

(80 - 120) 1.0 (0-10) KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 9.57 

NOTE(S ) : 

Calculations arc performed before rounding to avoid round-off errors in calculated results. 

VES018217 
46 

MATRIX SPIKE SAMPLE DATA REPORT 

General Chemistry 

Clien t Lot #... 

Date Sampled— 

: H9L140403' 

: 12/08/09 Date Received..: 12/11/09 

Matrxx . WASTE 

SAMPLE SPIKE MEASRD 

PARAMETER AMOUNT AMT 

Tota l Chlorine 

988 14000 

988 14400 

AMOUNT UNITS 

PERCNT 

RECVRY RPD• METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

W0#J LQ2TG1AG-MS/LQ2TG1AH-MSD MS Lot-Sample #: H9L140403-005 

14900 mg/kg 100 KNOX WC-0016 12/17-12/18/09 9351082 

15200 mg/kg 99 1.5 KNOX WC-0016 12/17-12/18/09 9351082 

Dilution Factor: 6.38 

Tota l Chlorine 

15300 19100 

15300 17300 

WO#: LQ2TR1AB-MS/LQ2TR1AF-MSD MS Lot-Sample #: H9L140403-013 

31800 mg/kg 87 KNOX WC-0016 12/21-12/28/09 9352031 

32200 mg/kg 97 1.0 KNOX WC-0016 12/21-12/2B/09 9352031 

Dilution Factor: 9.57 

NOTS(S) 

Calculations arc pcrrormcd before rounding to avoid round-off errors in calculated results. 

VES018218 
47 

MATRIX SPIKE SAMPLE EVALUATION REPORT 

Cliea t Lot #... 

Date Sampled.... 

: H9L140403 

: 12/09/09 

General Chemistry 

Date Received. 12/11/09 

Matrix : SOLID 

PARAMETER 

Total Chlorine 

88 

91 

PERCENT RECOVERY 

RECOVERY LIMITS RPD 

RPD 

LIMITS METHOD 

PREPARATIONANALYSIS DATE 

PREP 

BATCH # 

WO#: LQ2TP1AG-MS/LQ2TP1AH-MSD MS Lot-Sample #: H9L140403-011 

(80 - 120) KNOX WC-0016 12/22-12/29/09 9356065 

(80 - 120) 2.2 (0-10) KNOX WC-0016 12/22-12/29/09 9356065 

Dilufci-oil Factor; 5.01 

NOTE(S) 

Calculations arc performed before rounding to avoid round-off errors in calculated results. 

VES018219 
48 

MATRIX.SPIKE SAMPLE DATA REPORT 

General CSaemis tryClien t Lot #...: H9L140403 

Date Sampled—: 12/09/09 

Matrix : SOLID 

Date Received..: 12/11/09 

PARAMETER 

SAMPLE SPIKE 

AMOUNT AMT 

Total Chlorine 

134 

134 

10000 

9940 

MEASRD 

AMOUNT UNITS 

•PERCNT 

RECVRY RPD METHOD 

PREPARATIONANALYSIS DATE PREP 

BATCH # 

WO#: LQ2TP1AG-MS/LQ2TP1AH-MSD MS Lot-Sample #: H9L14O403-011 

8960 mg/kg 88 KNOX WC-0016 12/22-12/29/09 9356065 

9160 mg/kg 91 2.2 KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 5.OX 

HOTE(S) : 

Calcutiiions ore pcrrormcd before rounding ro avoid round-off errors hi calculated results. 

VES018220 
49 

Clien t Lot #. 

Date Sampled. 

PARAM RESULT 

Ash Content 

1370 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

.: H9L140403 Work Order #-..: LQ2TC-SMP 

LQ2TC-DUP . 

.: 12/08/09 Date Received..: 12/11/09 

DUPLICATE 

RESULT UNITS 

RPD 

RPD LIMIT METHOD 

Matrix : WASTE 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

1340 mg/kg 1.8 

Dilution Factor: 1 

SD Lot-Sample #: H9L140403-001 

(0-10) ASTM D482-00a 12/29-12/31/09 9363434 

VES018221 
50 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Clien t Lot H9L140403 Work Order LQ2TG-SMP Matrix : WASTE 

LQ2TG-DUP 

Date Sampled...: 12/09/09 Date Received..: 12/11/09 

DUPLICATE RPD PREPARATION- PREP 

PARAM RESULT RESULT UNITS RPD LIMIT METHOD ANALYSIS DATE BATCH # 

Gross Calorifi c SD Lot-Sample #: H9L140403-005 

Value 

ND ND BTU/lb 0 (0-10) ASTM D240-02 12/22/09 9356348 

Dilution Factor: l 

Ash Content SD Lot-Sample #: H9L140403-0O5 

1900 1880 mg/kg 1.1 (0-10) ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 

Total Chlorine SD Lot-Sample #: H9L140403-005 

988 999 • mg/kg 1.2 (0-10) KNOX WC-0016 12/17-12/18/09 9351082 

Dilution Factor: 1.-45 

VES018222 
51 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Clien t Lot #. ..: H9L140403 Work Order #.-.: LQ2TP-SMP Matrix : SOLID 

LQ2TP-DUP 

Date Sampled...: 12/09/09 Date Received..: 12/11/09 

DUPLICATE . RPD PREPARATION- PREP 

PARAM RESULT RESULT UNITS RPD LIMIT METHOD, ANALYSIS DATE BATCH # 

Gross Calorifi c SD Lot-Sample #: H9L140403-011 

Value 

ND ND BTU/lb 0 (0-10) ASTM D586S-00 12/16/09 9350032 

Dilution Factor: 1 

Ash Content ' SD Lot-Sample #: H9L140403-011 

713000 703000 mg/kg 1.3 (0-10) ASTM D482-00a 12/29-12/31/09 9363433 

Dilution Factor: 1 

Tota l Chlorine SD Lot-Sample #: H9L140403-011 

134 B 132 B mg/kg 1.6 (0-10) KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 1 

NOTE(S) : 

Calculaliouis arc performed before rounding lo avoid round-off errors in calculaied results. 

B Estimated result. Result is less than Rl. 

VES018223 
52 

Clien t Lot #., 

Date Sampled.. 

PARAM RESULT 

Gross Calorifi c 

Value 

10200 

Total Chlorine 

15300 

H9L140403 

12/08/09 

DUPLICATE 

RESULT 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LQ2TR-SMP 

LQ2TR-DUP 

Date Received..: 12/11/09 

9900 

15200 

UNITS 

RPD 

RPD LIMIT METHOD 

Matrix : WASTE 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

BTU/lb 2.9 

Dilution Factor: l 

SD Lot-Sample #: H9L140403-013 

(0-10) ASTM D240-02 12/23/0.9 9357188 

SD Lot-Sample #: H9L140403-013 

mg/kg 0.19 (0-10) KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 8.39 

VES018224 
53 

Clien t Lot #...: H9L140403 

Date Sampled...: 12/08/09 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #...: LQ2T3-SMP 

LQ2T3-DOT 

Date Received..: 12/11/09 

PARAM RESULT 

Tota l Chlorine 

4970 

DUPLICATE 

RESULT 

4790 

Matrox. WASTE 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L140403-019 

mg/kg 3.6 (0-10) KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factors 4.2 

VES018225 
54 

Cliecnt Lot #...: H9L140403 

Data Sampled...: 12/10/09 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work. Order #.. .: LQ2T5-SMP 

LQ2T5-DUP 

Date Received..: 12/11/09 

PARAM RESULT 

DUPLICATE 

RESULT 

Gross Calorifi c 

Value 

ND ND 

UNITS 

RPD 

RPD LIMIT METHOD 

Matrix : WASTE 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

BTU/lb 0 

Dilution Factor: 1 

SD Lot-Sample #: H9L140403-021 

(0-10) ASTM D240-02 12/23/09 9357188 

VES018226 
55 

Sample Receipt Documentation 

VES018227 
Sample Traceability List 

AECO M 

Site of Program: Veolia ES Tech Sample Date: itfsc- \2,f/o/o^> Project Location: Sauget, IL P.O.* 

Type of Proqram; CPT Date Shipped: Laboratory: Test America, Inc. 

Project* 60133216 . Knoxville, TN 

Program Office: Syracuse NY 

Shipper/ Steven Milo 

Recovery: Jeff Gorman 

Laboratory: Test America, Inc. 

Knoxville, TN 

Program Contact: Jeff Gorman FedEx Air Bill ft 

Item Sample ID Code Sample Matrix Sample Description Analitloal Parameters Special Instructions 

1 HBTU-U2-M23A-R1 Liquid High Btu, Unit 2, Run 1 Physical Parameters 5 Cl -fofaA r.U l( 

2 HBTU-U2-M23A-R2 Liquid High Btu, Unit 2, Run Z Physical Parameters & Cl Tok J ^ 

3 HBTU-U2-W123A-R3 Liquid High Btu, Unit 2, Run 3 Physical Parameters & Cl ' f^, 7 

4 

S LBTU-U2-M23A-R1 Liquid Low Btu, Unit 2, Run 1 Physical Parameters & Cl T o I 

6 LBTU-U2-M23A-R2 Liquid Low Btu, Unit 2, Run 2 Physical Parameters 5 Cl ' •fo.faj c X 

7 LBTU-U2-M23A-R3 Liquid Low Btu, Unit 2, Run 3 Physical Parameters & Ct -^uf f. f/<7ie.ije.£> 

8 

9 SF-U2-M23A-R1 Liquid Speciality Feeder, Unit 2, Run 1 Physical Parameters & Cl -fSfc,/ f10 SF-U2-WI23A-R2 Liquid Specilaity Feeder, Unit 2, Run 2 Physical Parameters & C) ' / , 

11 SF-U2-M23A-R3 Liquid Speciality Feeder, Unit 2. Run 3 Physical Parameters & Cl ' ffifa f 

12 1 

13 CS-U2-M23A-R1 Solid Containerized Solids, Unit 2, Run 1 Physical Parameters SCI -yS fe. / 

14 CS-U2-M23A-R2 Solid Containerized Solids, Unit 2, Run 2 Physical Parameters S Cl -rCfe I t 

15 CS-U2-M23A-R3 Solid Containerized Solids, Unit 2, Run 3 Physical Parameters & Cl

 1 -7^ , ,f C.hloit.i« 

16 

17 

18 

19 

20 

Field Notes/ Comments 1. Physical Parameters = Total chlorides, heat content & ash content. 

2. Cl 

Page 1 of _2 

Relinquished By (print): Dale: 

SH««r* H.lo |2«t » 

Signature: . Time: 

-fYujL I7CO 

Relinquished By (print): Date: 

Signature: Time: 

Relinquished By (print): Date: 

Signature: Time: 

[Received by Lab (print): Date: 

Signature: Time: 

Received By (print): Date: 

^loftature^_ . Time: 

%TMth DVC D 

Received By (print): Date: 

Signature: Time: 

Received By (print): Date: 

Signature: Time: 

[Analytical Laboratory Destination: 

TestAmerica Inc. 

5B15 Middlebrook Pike 

Knoxville, TN 37921 

I Attn: Mr. Kevin Woodcock 885-291-3000 

VES018228 
Sample Traceability List 

AECO M 

Site of Program: Veolia ES Tech Sample Date: - ll-lO^Sl Project Location; Sauqet, IL P.O. #: 

Type of Program: CPT Date Shipped: /JZ- /<3 7 Laboratory: Test America, Inc. 

Project #: 6013321B Knoxville, TN 

Program Office: Syracuse NY 

Shipper / Steven Milo 

Recovery: Jeff Gorman 

Laboratory: Test America, Inc. 

Knoxville, TN 

Program Contact: Jeff Gorman FedEx Air Bill #: 

Item Sample ID Code Sample Matrix Sample Description Analitlcal Parameters Special instructions 

21 HBTU-U2-M26A-R1 Liquid High Btu, Unit 2, Run 1 Physical Parameters & Ci -fS-fal 

22 HBTU-U2.M26A-R2 Liquid High Btu, Unit 2, Run 2 Physical Parameters & Cl ' -rS4rJ f 

23 HBTU-U2-M26A-R3 Liquid High Btu, Unit 2, Run 3 Physical Parameters & Cl ' | ~ 

24 1 

25 LBTU-U2-M26A-R1 Liquid Low Btu, Unit 2, Run 1 Physical Parameters & Cl ~Jofe,l / ' if lcln tie. 

» 26 LBTU-U2-M26A-R2 Liquid Low Btu, Unil 2, Run 2 Physical Parameters & Cl -r^-fc./ 

27 LBTU-U2-M26A-R3 Liquid Low Btu, Unit 2, Run 3 Physical Parameters & Cl ' fok^ 1 

28 

29 SF-U2-M26A-R1 Liquid Speciality Feeder, Unit 2, Run 1 Physical Parameters & Cl (~X~o h i 1 

30 SF-U2-M26A-R2 Liquid Specilaily Feeder, Unit 2, Run 2 Physical Parameters & Cl -T^-faJ 

31 SF-U2-M26A-R3 Liquid Speciality Feeder, Unit 2, Run 3 Physical Parameters & Cl ^-f, feJ| \r\ \r\f.\n*> 

32 

33 CS-U2-M26A-R1 Solid Containerized Solids, Unit 2, Run 1 Physical Parameters S Cl |-t^,t a j r 

34 CS-U2-WI26A-R2 Solid Containerized Solids, Unit 2, Run 2 Physical Parameters & Cl ' ^rtJkiA 

35 CS-U2-W126A-R3 Solid Containerized Solids, Unit 2, Run 3 Physical Parameters & Cl -^-j^ J 

36 {0 PflXt^ (35'JO fcXYi ^PNT Pin 

37 : Wpdf 9\M 

38 ^$1* <o1f^ Pin 

39 51A% q<*6L 

40 

Field Notes/ Comments 1. Physical Parametersm = Total chlorides, heat content & ash content. 

2. Cl 

Page _2__ of 2 

Relinquished By (print): Date; 

5ioaan ti.'lo U/JO/OT 

Signature: J Time: 

Stettin ~4WtJb i loo 

Relinquished By (print): Date: 

Signature: Time: 

Relinquished By (print): Date: 

Signature: Time: 

Received by Lab (print): Date: 

Signature: Time: 

Received By (print): Dale: 

sSignature: Time: 

JP^mh lO'.DO 

Received By (print): Date: 

Signature: Time: 

Received By (print): Date: 

Signature: Time: 

Analytical Laboratory Destination: 

Test America Inc. 

5815 Middlebrook Pike 

Knoxville, TN 37921 

Attn: Mr. Kevin Woodcock 865-291-3000 

Ol 

VES018229 
TESTAMERICA KNOXVILLE SAMPLE RECEIPT/CONDITION UPON RECEIPT ANOMALY CHECKLIST 

Lot Number: MU^Hl k 

Review Items Mo 

| 

If No, what was the problem? Comments/Actions Taken 

1. Do sample container labels match COC? 

(IDs, Dates, Times) { 

/ 

B la Do not match COC 

• lb Incomplete information 

O l c Marking smeared 

0 Id Label torn 

• le No label 

• lf COC not received 

• lg Other: 

1. Do sample container labels match COC? l f\ P&t , UM X 51ftmiR B IJBTU, -

(IDs, Dates, Times) { 

/ 

B la Do not match COC 

• lb Incomplete information 

O l c Marking smeared 

0 Id Label torn 

• le No label 

• lf COC not received 

• lg Other: 

iAZ." WTJ / J A . - kl. 

1. Do sample container labels match COC? 

(IDs, Dates, Times) { 

/ 

B la Do not match COC 

• lb Incomplete information 

O l c Marking smeared 

0 Id Label torn 

• le No label 

• lf COC not received 

• lg Other: 

?jaKSVM\\SV7. 1 (A W L STS 

1. Do sample container labels match COC? 

(IDs, Dates, Times) { 

/ 

B la Do not match COC 

• lb Incomplete information 

O l c Marking smeared 

0 Id Label torn 

• le No label 

• lf COC not received 

• lg Other: 

LJROk-UZL.- frATXeA- fiZ> .LAD <3|\J 

1. Do sample container labels match COC? 

(IDs, Dates, Times) { 

/ 

B la Do not match COC 

• lb Incomplete information 

O l c Marking smeared 

0 Id Label torn 

• le No label 

• lf COC not received 

• lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) { 

/ 

B la Do not match COC 

• lb Incomplete information 

O l c Marking smeared 

0 Id Label torn 

• le No label 

• lf COC not received 

• lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) { 

/ 

B la Do not match COC 

• lb Incomplete information 

O l c Marking smeared 

0 Id Label torn 

• le No label 

• lf COC not received 

• lg Other: 

1. Do sample container labels match COC? 

(IDs, Dates, Times) { 

/ 

B la Do not match COC 

• lb Incomplete information 

O l c Marking smeared 

0 Id Label torn 

• le No label 

• lf COC not received 

• lg Other: 

2. Is the cooler temperature within limits? (> freezing 

temp, of water to 6"C; NC, 1668,16T3B: 0-4°C; 

VOST: 10"C;MA:2-6,'C) 

J 2. Is the cooler temperature within limits? (> freezing • 2a Tenro Blank = 

temp, of water to 6"C; NC, 1668,16T3B: 0-4°C; 

VOST: 10"C;MA:2-6,'C) 

J • 2b Cooler Temp = 

2. Is the cooler temperature within limits? (> freezing 

temp, of water to 6"C; NC, 1668,16T3B: 0-4°C; 

VOST: 10"C;MA:2-6,'C) 

J 

3. Were samples received with correct chemical 

preservative (excluding Encore)? V • 3a Sample preservative = 

_x , 

3. Were samples received with correct chemical 

preservative (excluding Encore)? V • 3a Sample preservative = 

_x , 

4. Were custody seals present/intact on cooler and/or 

containers? 7 SI 4a Not present 0 4b Not intact 

D 4c Other: 

4. Were custody seals present/intact on cooler and/or 

containers? 7 SI 4a Not present 0 4b Not intact 

D 4c Other: 

4. Were custody seals present/intact on cooler and/or 

containers? 7 SI 4a Not present 0 4b Not intact 

D 4c Other: 

5. Were all of the samples listed on the COC received? 0 5a Samples received-not on COC 

Q 5b Samples not received-on COC 

5. Were all of the samples listed on the COC received? 0 5a Samples received-not on COC 

Q 5b Samples not received-on COC 

6. Were ail of the sample containers received intact? 

•j 

/ 

• 6a Leaking 

0 6b Broken 

6. Were ail of the sample containers received intact? 

•j 

/ 

• 6a Leaking 

0 6b Broken 

7. Were VOA samples received without headspace? y_ V D 7a Headspace (VOA only) 

8. Were samples received in appropriate containers? V D 8a Improper container 

9, Did ybu check for residual chlorine, if necessary? 

/ 

J 

• 9a Could not be determined due 

to matrix interference 

9, Did ybu check for residual chlorine, if necessary? 

/ 

J 

• 9a Could not be determined due 

to matrix interference 

10. Were samples received within holding time? I 

M 

• 10a Holding time expired 

11. For rad samples, was sample activity info, provided? • Incomplete information 

12. For 1613B water samples is pH<9? 

y 

If no, was pH adjusted to pH 7 - 9 

with sulfuric acid? 

12. For 1613B water samples is pH<9? 

y 

If no, was pH adjusted to pH 7 - 9 

with sulfuric acid? 

13. Are the shipping containers intact? 

f 

D 13a Leaking 

• 13b Other: 

13. Are the shipping containers intact? 

f 

D 13a Leaking 

• 13b Other: 

14. Was COC relinquished? (Signed/Dated/Timed) I • 14a Not relinquished 

IS. Are tests/parameters listed for each sample? D 15a Incomplete information 

16. Is the matrix ofthe samples noted? D 15a Incomplete information 

17. Is the date/time of sample collection noted? 7 0 15a Incomplete information 

18. Is the client and project name/# identified? J / • 15a Incomplete information 

19. Was the sampler identified on the COC? / 

Ouote#: ftM-7?,c'i . PM Instructions: 

Sample Receiving Assoc!) QA026R21.doc, 090409 

CO 

VES018230 
59 
60 

Sample Summary 

VES018232 
61 

Lot-Sample #. 

Date Sampled. 

PARAMETER 

Ash. Content 

Gross Calorifi c 

Value 

Total Chlorine 

AECOM, Inc 

Clien t Sample TD: HBTU-U2-M23A-R1 

General Chemistry 

H9L140403-001 Work Order : LQ2TC 

12/08/03 Date Received..: 12/11/09 

Matrix : WASTE 

RESULT RL UNITS 

1370 200 rag/kg 

Dilution Factor: 1 

9190 1800 BTU/lb 

Dilution Factor: 1 

16200 1690 mg/kg 

Dilution Factor: 8.46 

_ METHOD 

ASTM D482-00a 

MDL 5 1 

ASTM D240-02 

HDL 13 0 

KNOX HC-0016 

HDL : 510 

PREPARATION- PREP 

ANALYSIS DATS BATCH ft 

12/29-12/31/09 9363434 

12/22/09 9356348 

12/17-12/18/09 9351082 

VES018233 
62 

AECOM, Inc 

Clien t Sample ID: HBTO-TJ2-M23A-R2 

General Chemistry 

Lot-Sample -. H9L140403-002 Work Order #...: LQ2TD Matrix.. : WASTE 

Date Sampled...: 12/09/09 Date Received. 12/11/09 

PARAMETER RESULT RL UNITS 

Ash Content 

Gross Calorifi c 

VaLue 

Total Chlorine 

1910 200 mg/kg 

Dilution Factor: 1 

9430 1800 BTD/Ib 

Dilution Factor: 1 

14200 1640 mg/kg 

Dilution Factor: 8.18 

_ METHOD 

ASTM D482-00a 

MDIJ. : 51 

ASTM D240-02 

MDL 130 

KNOX WC-0016 

MDL 490 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363434 

12/22/09 9356348 

12/17-12/18/09 9351082 

VES018234 
63 

AECOM, Inc 

Clien t Sample ID: HBTO-02-M23A-R3 

General Chemistry 

Lot-Sample : H9L140403-003 Work Order : LQ2TE Matrix : WASTE 

Date Sampled...: 12/10/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT SL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 2490 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 MDI. : 51 

Gross Calorifi c 9870 1800 BTTJ/lb ASTM D240-02 12/22/09 9356348 

Value 

Dilution Factor: 1 MDL : 130 

Tota l Chlorine 13900 1700 mg/kg KNOX WC-0016 12/17-12/18/09 9351082 

Dilution Factor: 8.51 MDL : 510 

VES018235 
64 

AECOM, Inc 

Clien t Sample ID: LBTU-U2-M23A-R1 

General Chemistry 

Lot-Sample #...: H9L140403-004 Work Order «...: LQ2TF 

Date Sampled...: 12/08/09 Date Received..: 12/11/09 

Matrix : WASTE 

PARAMETER 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

RESULT RL UNITS 

2340 200 mg/kg 

Dilution Factors 1 

ND 1800 BTU/lb 

Dilution Factor; 1 

1120 306 mg/kg 

Dilution Factors 1.S3 

_ METHOD 

ASTM D4B2-00a 

MDL : Bl 

ASTM D24O-02 

HDL , 130 

KNOX WC-0016 

HDL : 92 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363434 

12/22/09 935634B 

12/17-12/18/09 9351082 

VES018236 
65 

Lot-Sampl e #. 

Date SampledPARAMETER 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

AECOM, Inc 

Clien t Sample ID: LBTO-U2-M23A-R2 

General Chemistry 

H9L140403-005 Work Order #...: LQ2TG 

12/09/09 Date Received..: 12/11/09 

Matrix : WASTE 

RESULT RL UNITS 

1900 200 mg/kg 

Dilution Factor: 1 

ND 1800 BTU/lb 

Dilution Factor: 1 

988 290 mg/kg 

Dilution Factor: 1.45 

_ METHOD 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL : 130 

KNOX WC-0016 

MDL ....: 87 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363434 

12/22/09 9356348 

12/17-12/18/09 9351082 

VES018237 
66 

AECOM, Inc 

Clien t Sample ID: LBTU-U2-M23A-R3 

General Chemistry 

Lot-Sample #...: H9L140403-006 Work Order #...: LQ2TH Matrix.. : WASTE 

Date Sampled...: 12/10/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESDLT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 2290 200 mg/kg ASTM D482-O0a 12/29-12/31/09 9363434 

Dilution Factors 1 MDL : 51 

Gross Calorifi c 134 B 1800 BTU/lb ASTM D240-02 12/22/09 9356348 

• Value 

Dilution Factor: 1 MDL : 130 

Tota l Chlorine 1140 288 mg/kg KNOX WC-0016 12/17-12/18/09 9351082 

Dilution Factor: 1.44 MDL 86 

MOTB(S) : t . 

RL Rsporiins Limit 

B Estimated result. Result is less Ulan RL. 

VES018238 
67 

AECOM, Inc 

Clien t Sample ID: SF-TJ2-M23A-R1 

General Chemistry 

Lot-Sample H9L140403-007 Work Order : LQ2TJ Matrix : WASTE 

Date Sampled...: 12/08/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 7420 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 MDL : 51 

Gross Calorifi c ND 1800 BTU/lb ASTM D240-02 12/23/09 9357188 

Value 

Dilution Factor: 1 MDL. : 130 

Total Chlorine 4730 840 mg/kg KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 4.2 MDL.... : 250 

VES018239 
68 

AECOM, Inc 

Clien t Sample XD: SF-TJ2-M23A-H2 

General Chemistry 

Lot-Sample #...: H9L140403-008 Work Order LQ2TK Matrix : WASTE 

Date Sampled : 12/09/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 7720 200 mg/kg ASTM D482-00a 12/29-12/31/09 93S3434 

Dilution Factor: 1 MDL .: SI 

Gross Calorifi c ND 1800 BTU/lb ASTM D240-02 12/23/09 9357188 

Value 

Dilution Factor: 1 MDL s 130 

Tota l Chlorine 4830 824 mg/kg KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 4.12 MDL..... : 2S0 

VES018240 
69 

AECOM, Inc 

Clien t Sample ID: SF-U2-M23A-E3 

General Chemistry 

Lot-Sample #...: H9L140403-009 Work Order LQ2TL 

Date Sampled. : 12/10/09 Date Received..: 12/11/09 

PARAMETER RESULT RL UNITS METHOD 

Matrix. : WASTE 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Ash Content 

Gross Calorifi c 

Value 

Tota l Chlorine 

7540 200 mg/kg 

Dilution Factor: 1 

ND 1800 BTU/lb 

Dilution Factor: 1 

4810 838 mg/kg 

Dilution Factor: 4.19 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL : 130 

-KNOX WC-0016 

MDL : 250 

12/29-12/31/09 9363434 

12/23/09 9357188 

12/21-12/28/09 9352031 

VES018241 
70 

AECOM, Inc 

Clien t Sample ID: CS-U2-M23A-R1 

General Chemistry 

Lot-Sample #...: H9L140403-010 Work Order #... = LQ2TM Matrix : SOLID 

Date Sampled...: 12/OB/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 716000 200 mg/kg ASTM D4B2-O0a 12/29-12/31/09 9363433 

Dilution Factor: 1 MDL : SI 

Gross Calorifi c ND 1800 BTU/lb ASTM D5865-00 12/15/09 9350032 

Value 

Dilution Factor: 1 HDL : 130 

Tota l Chlorine 129 B 202 mg/kg KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 1.01 MDL : 61 

MOTS <S) : r _ , 

RL Rtporting Limit 

B Estimated result. Result is less than RL. 

VES018242 
71 

AECOM, Inc 

Clien t Sample ID: CS-TJ2-M23A-R2 

General Chemistry 

Lot-Sample #...: H9L140403-011 Work Order #...: LQ2TP 

Date Sampled...: 12/09/09 Date Received..: 12/11/09 

Matrix. SOLID 

PARAMETER RESULT RL UNITS 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

713000 200 mg/kg 

Dilution Factors 1 

ND 1800 BTU/lb 

Dilution Factor: 1 

134 B 200 mg/kg 

Dilution Factor: 1 

_ METHOD 

ASTM D482-00a 

MDL. : 51 

ASTM D58S5-00 

MDL : 130 

KNOX WC-0016 

MDL . s SO 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363433 

12/16/03 9350032 

12/22-12/29/09 9356065 

NOTE(S) : 

RL Reporting Limii 

B Estimated result. Result is less than RL. 

VES018243 
72 

AECOM, Inc 

Clien t Sample ID: CS-U2-M23A.-R3 

General Chemistry 

Lot-Sample ft-..: H9L140403-012 Work Ordex #.-.: LQ2TQ Matrix : SOLID 

Date Sampled : 12/10/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 708000 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363433 

Dilution Factor: 1 HDL .: 51 

Gross Calorifi c ND .1800 BTU/lb ASTM D5865-00 12/16/09 9350032 

VaLue 

Dilution Factor: 1 HDL : 130 

Tota l Chlorine 141 B 200 mg/kg KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 1 MDL : SO 

NOTE(S) : : 

RL Repotting Limit 

B Estimated result. Result is less than RL. 

VES018244 
73 

AECOM, Inc 

Clien t Sample ID: HBTO-02-M26A-R1 

• General Chemistry 

Lot-Sample #...: H9L140403-013 Work Order #-..: LQ2TR Matrix : WASTE 

Date Sampled : 12/08/09 Date Received..: 12/11/0? 

PREPARATION- PREP 

PARAMETER RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 1360 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor.- 1 MDL : 51 

Gross Calorifi c . 10200 1800 BTtr/lb ASTM D240-02 12/23/09 9357188 

Value 

Dilution Factor.- 1 MDL 130 

Tota l Chlorine 15300 1680 mg/kg KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 8.39 MDL : 500 

VES018245 
74 

AECOM, Inc 

Clien t Sample XX): HBTO-02-M26A-R2 

General Chemistry 

Lot-Sample #...: H9L140403-014 Work Order #...: LQ2TT Matrix : WASTE 

Date Sampled...: 12/09/09 Date Received..: 12/11/09 

PREPARATION- PREP 

PARAMETER RESOLT RL TJNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 1BS0 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factors 1 MDI. : 51 

Gross Calorifi c 9810 1800 BT0/lb ASTM D240-02 12/23/09 9357188 

Value 

Dilution Factor: 1 MDL : 130 

Tota l Chlorine 13500 1690 mg/kg KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 8.47 MDL : 510 

VES018246 
75 

AECOM, Inc 

Clien t Sample ID: HBTU-TJ2-M26A-R3 

General Chemistry 

Lot-Sample #...: H9L140403-015 Work Order #...: LQ2TV 

Date Sampled— : 12/10/09 Date Received..: 12/11/09 

PARAMETER RESULT RL UNITS METHOD 

Matrix : WASTE 

PREPARATION- PREP 

- ANALYSIS DATE BATCH # 

Ash Content 

Gross Calorifi c 

Value 

Tota l Chlorine 

2950 200 rag/kg 

Dilution Factors 1 

9810 1800 BTU/lb 

Dilution Factor: 1 

14500 1680 mg/kg 

Dilution Factor: 8.4 

ASTM D482-00a 

MDL s 51 

ASTM D240-02 

MDL : 130 

KNOX WC-0016 

MDL : 500 

12/29-12/31/09 9363434 

12/23/09 935718B 

12/21-12/28/09 9352031 

VES018247 
76 

AECOM, Inc 

Clien t Sample ID: LBTU-U2-M2SA-R1 

General Chemistry 

Lot-Sample #...: H9L140403-016 Work Order #...: LQ2TW 

Date Sampled. : 12/08/09 Date Received..: 12/11/09 

Matrix : WASTE 

PARAMETER RESDLT RL UNITS 

Ash Content 

Gross Calorifi c 

value 

Total Chlorine 

2260 200 mg/kg 

Dilution Factor: 1 

ND 18 00 BTU/lb 

Dilution Factor: 1 

1180 278 mg/kg 

Dilution Factor: 1.3 9 

_ METHOD 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL 130 

KNOX WC-0016 

MDL : 83 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363434 

12/23/09 9357188 

12/21-12/29/09 9352031 

VES018248 
77 

Lot-Sample #... 

Date Sampled... 

AECOM, la c 

Clien t Sample TD: LBTU-U2-M26A-R2 

General Chemistry 

H9L140403-017 Work Order : LQ2T0 

12/09/09 Date Received..: 12/11/09 

Matrix. WASTE 

PARAMETER RESULT RL UNITS 

Ash Content 1990 

Gross Calorifi c ND 

Value 

Total Chlorine 10S0 

200 mg/kg 

Dilution Factor: 1 

1800 BTU/lb 

Dilution Factor: 1 

280 mg/kg 

Dilution Factor; 1.4 

_ METHOD 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL : 130 

KNOX WC-0016 

MDL : 84 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363434 

12/23/09 9357188 

12/21-12/29/09 9352031 

VES018249 
78 

Lot-Sample #. 

Date Sampled. 

PARAMETER 

AECOM, Inc 

Clien t Sample ZD: LBTU-U2-M26A-R3 

General Chemistry 

H9L140403-018 Work Order #...: LQ2T1 

12/10/09 Date Received..r 12/11/09 

Matrix : WASTE 

RESULT RL UNITS 

Ash Content 

Gross Calorifi c 

Value 

Tota l Chlorine 

2360 200 mg/kg 

Dilution Factor: 1 

ND 1800 BTU/lb 

Dilution Factor: 1 

1230 282 mg/kg 

Dilution Factor: 1.41 

_ METHOD 

ASTM D482-O0a 

MDD .: 51 

ASTM D240-02 

MDL : 130 

KNOX WC-0016 

MDL : 85 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363434 

12/23/09 9357188 

12/21-12/29/09 9352031 

VES018250 
79 

AECOM, Inc 

Clien t Sample ID: SF-U2-M26A-R1 

General Chemistry 

Lot-Sample #...: H9L140403-019 Work Order 

Date Sampled...: 12/0 8/09 Date Received.. 

PARAMETER RESULT RL UNITS 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

7760 200 mg/kg 

Dilution Factors 1 

ND 1800 BTU/lb 

Dilution Factors 1 

4970 840 mg/kg 

Dilution Factor s 4.2 

LQ2T3 

12/11/09 

Matrix. WASTE 

_ METHOD 

ASTM D482-00a 

MDL : 51 

ASTM D240-02 

MDL 130 

KNOX WC-0016 

MDL s 250 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363434 

12/23/09 93S7188 

12/21-12/28/09 9352031 

VES018251 
80 

AECOM, Inc 

Clien t Sample ID: SF-U2-M26A-R2 

General Chemistry 

Lot-Sample .- H9L140403-020 Work Order #...: LQ2T4 

Date Sampled...: 12/09/09 Date Received.. -. 12/11/09 

Matrxx. WASTE 

PARAMETER RESULT RL TJNITS 

Ash Content 

Gross Calorifi c 

Value 

Total Chlorine 

8060 200 mg/kg 

Dilution Factor: 1 

ND 1800 BTD/lb 

Dilution Factor: 1 

4510 836 mg/kg 

Dilution Factor: 4.18 

_ METHOD 

ASTM D482~00a 

MDL : 51 

ASTM D24 0-02 

MDL : 130 

KNOX WC-0016 

MDL ; 250 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363434 

12/23/09 93571B8 

12/21-12/28/09 9352031 

VES018252 
81 

AECOM, Inc 

Clien t Sample ID: SF-D2-M26A-E3 

General Chemistry 

Lot-Sample #._.: H9L140403-021 Work Order #...: LQ2T5 Matrix : WASTE 

Date Sampled : 12/10/09 Date Received..s 12/11/09 

PREPARATION- PREP 

PARAMETER RESDLT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 7930 200 mg/kg ASTM D4B2-00a 12/29-12/31/09 93S3434 

Dilution Factor: 1 MDL 51 

Gross Calorifi c ND 1800 BTU/lb ASTM D24O-02 12/23/09 9357188 

Value 

Dilution Factor: 1 MDL : 130 

Tota l Chlorine 4790 844 mg/kg KNOX WC-001S 12/21-12/28/09 9352031 

Dilution Factor: 4.22 MDL...W : 250 

VES018253 
82 

AECOM, Inc 

Clien t sample XB: CS-xr2-M26A.-Rl 

General Chemistry 

Lot-Sample #...: H9L14O403-022 Work Order #.-.: LQ2T6 Matrix : SOLID 

Date Sampled...: 12/08/09 Date Received..: 12/11/09 

PREPARATION- •PREP 

PARAMETER , RESULT RL UNITS METHOD ANALYSIS DATE BATCH # 

Ash Content 809000 200 mg/kg ASTM D482-00a 12/29-12/31/09 9363433 

Dilution Factor; 1 MDL .: 51 

Gross Calorifi c ND 1B0O BTU/lb ASTM D58S5-00 12/16/09 9350032 

Value 

Dilution Factor: 1 MDL : 130 

Total Chlorine ND 200 mg/kg KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 1 MDL : 60 

VES018254 
83 

Lot-Sample #. 

Date Sampled. 

PARAMETER 

AECOM, Inc 

Clien t Sample 3D: CS-TX2-M26A-R2 

General Chemistry 

H9L140403-023 Work Order #...: LQ2T7 

12/09/09 Date Received..: 12/11/09 

Matrix. SOLID 

RESULT RL UNITS 

Ash Content 

Gross Calorifi c 

Value 

Total chlorin e 

787000 200 mg/kg 

Dilution Factor; 1 

ND 1800 BTU/lb 

Dilution Factor: 1 

ND 200 mg/kg 

Dilution Factor: 1 

_ METHOD 

ASTM D482-00a 

MDL. 51 

ASTM D586S-00 

MDL : 130 

KNOX WC-0016 

MDL : 60 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363433 

12/16/09 9350032 

12/22-12/29/09 9356065 

VES018255 
84 

Lot-Sample #... 

Date Sampled— 

Ash Content 

AECOM, Inc 

Clien t Sample ID: CS-D2-M26A-R3 

General Chemistry 

H9L1404 03-024 Work Order #...: LQ2T8 

12/10/09 Date Received..: 12/11/09 

Matrix. SOLID 

PARAMETER RESULT RL UNITS 

7S9000 200 mg/kg 

Dilution. Factor; 1 

Gross Calorifi c ND 

Value 

Total Chlorine ND 

1800 BTU/lb 

Dilution Factor: 1 

200 mg/kg 

Dilution Factor: 1 

METHOD 

ASTM D482-00a 

MDL : SI 

ASTM D58S5-00 

MDL : 130 

KNOX WC-001S 

MDL : SO 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

12/29-12/31/09 9363433 

12/16/09 9350032 

12/22-12/29/09 9356065 

VES018256 
85 

QC Summary 

VES018257 
86 

Clien t Lot #... H9L140403 

METHOD BLANK EEPORT 

General Chemistry 

Matrix ; WASTE 

PARAMETER 

Ash Content 

RESULT 

ND 

REPORTING 

LIMIT UNITS METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Work Order #: LRPQF1AA MB Lot-Sample #: H9L290000-434 

200 mg/kg ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor; 1 

Total Chlorine Work Order #: LQ76D1AA MB Lot-Sample #: H9L170000-082 

ND 200 mg/kg KNOX WC-0016 12/17-12/18/09 93S1082 

Dilution Factor: 1 

Total Chlorine Work Order #: LRAEQ1AA MB Lot-Sample #: H9L180000-031 

ND 200 mg/kg KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 1 

KOTEfS): 

Calculations arc performed before rounding 10 avoid round-off errors in calculated results. 

VES018258 
87 

Clien t lo t H9L14 0403 

PARAMETER RESULT 

Ash Content 

Total Chlorine 

ND 

ND 

METHOD BLANK REPORT 

General Chemistry 

Matrix. SOLID 

REPORTING 

LIMIT UNITS METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

Work Order #: LRPQE1AA MB Lot-Sample #: H9L290000-433 

200 mg/kcj ASTM D482-00a 12/29-12/31/09 9363433 

Dilution Factor: 1 

Work Order #: LRGLV1AA MB Lot-Sample #: H9L220000-O65 

200 mg/kg KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 1 

NOTE (S) : 

Calculations arc performed before rounding io avoid round-off errors iu calculated results. 

VES018259 
88 

LABORATORY CONTROL SAMPLE EVALUATION REPORT 

General Chemistry 

Lot-Sample H9L140403 Matrix. 

PARAMETER 

Ash Content 

PERCENT 

RECOVERY 

100 

100 

RECOVERY 

LIMITS RPD 

RPD 

LIMITS METHOD 

PREPARATIONANALYSIS DATE 

: SOLID 

PREP 

BATCH # 

W0#:LRPQE1AC-LCS/LRPQE1AD-LCSD LCS Lot-Sample#: H9L290O00-433 

(90 - 110) ASTM D482-00a 12/29-12/31/09 9363433 

(90 - 110) 0.32 (0-10) ASTM D482-0Oa 12/29-12/31/09 9363433 

Dilution Factor: 1 

Gross Calorifi c 

Value 

100 

100 

W0#:LQ58P1AA-LCS/LQ58P1AC-LCSD LCS Lot-Sample#: H9L1S0O00-032 

(98 - 102) ASTM D5B65-00 

(98 - 102) 0.10 (0-2.0) ASTM D5865-00 

Dilution Factor: 1 

12/16/09 

12/16/09 

9350032 

9350032 

NOTE(S): 

Calcutiiions are performed before rounding lo avoid round-off errors in calculated results. 

VES018260 
89 

LABORATORY CONTROL SAMPLE DATA REPORT 

General Chemistry 

Lot-Sample : H9L140403 Matrix : SOLID 

PARAMETER 

Ash Content 

SPIKE MEASURED 

AMOUNT AMOUNT UNITS 

PERCNT 

RECVRY RPD METHOD 

PREPARATIONANALYSIS DATE 

4000 

4000 

Gross Calorifi c 

Value 

11400 

11400 

PREP 

BATCH # 

W0#:LRPQE1AC-LCS/LRPQE1AD-LCSD LCS Lot-Sample#: H9L290QO0-433 

4000 mg/kg 100 ASTM D4B2-00a 12/29-12/31/09 9363433 

3990 mg/kg 100 0.32 ASTM D4B2-00a 12/29-12/31/09 9363433 

Dilution Factor: x 

W0#:LQ58P1AA-LCS/LQ58P1AC-LCSD LCS Lot-Sample#: H9L1600O0-032 

113 00 BTU/lb 100 

11300 BTU/lb 100 

Dilution Factor: 1 

ASTM D5865-00 

0.10 ASTM DS86S-00 

12/16/09 

12/16/09 . 

9350032 

9350032 

NOTE(S) ; 

Calculations are performed before rounding to avoid round-off errors in calculated results. 

VES018261 
90 

LABORATORY CONTROI. SAMPLE EVALUATION REPORT 

General Chemistry 

Lot-Sample #...: H9L140403 Matrix : WASTE 

PERCENT RECOVERY RPD 

PARAMETER RECOVERY LIMITS RPD LIMITS METHOD 

Ash. Content 

PREPARATION- PREP 

ANALYSIS DATE BATCH ft 

100 

99 

W0#;LRPQF1AC-LCS/LRPQF1AD-LCSD LCS Lot-Sample#: H9L290000-434 

(90 - 110) ASTM D482-00a 12/29-12/31/09 9363434 

(90 - 110) 0.93 (0-10) ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 

Gross Calorifi c 

Value 

100 

99 

W0#:LRG6J1AA-LCS/LRG6J1AC-LCSD LCS Lot-Sample#: H9L220000-348 

(98 - 102) ASTM D240-02 

(98 - 102) 0.42 (0-2.0) ASTM D240-02 

Dilution Factor: 1 

12/22/09 

12/22/09 

9356348 

9356348 

Gross calorifi c 

Value 

100 

10 0 

W0#:LRJKE1AA-LCS/LRJKE1AC-LCSD LCS Lot-Sample#: H9L230000-188 

(98 - 102) ASTM D240-02 

(98 - 102) 0.04 (0-2.0) ASTM D240-02 

Dilution Factor: 1 

12/23/09 

12/23/09 

9357188 

9357188 

SOTB(S) ; 

Calculltiorts arc performed before rounding to avoid round-off errors in calculated results. 

VES018262 
91 

LABORATORY COHTROL SAMPLE DATA REPORT 

General Chemistry 

Lot-Sample #.. H9L140403 Matrix : WASTE 

PARAMETER 

Ash Content 

SPIKE 

AMOUNT 

4000 

4000 

MEASURED 

AMOUNT UNITS 

PERCNT 

RECVRY RPD METHOD 

PREPARATIONANALYSIS DATE PREP 

BATCH # 

W0#:LRPQF1AC-LCS/LRPQF1AD-LCSD LCS Lot-Sample*: H9L290000-434 

3980 mg/kg 100 ASTM D482-00a 12/29-12/31/09 93S3434 

3940 mg/kg 99 0.93 ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 

Gross Calorifi c W0#:LRG6J1AA-LCS/LRGSJ1AC-LCSD LCS Lot-Sample#: H9L220000-348 

Value 

20600 20500 BTU/lb 100 ASTM D24O-02 12/22/09 9356348 

20600 20500 BTU/lb 99 0.42 ASTM D240-02 12/22/09 9356348 

Dilution Factor: 1 

Gross Calorifi c 

Value 

20600 

20600 

W0#:LRJKE1AA-LCS/LRJKE1AC-LCSD LCS Lot-Sample#: H9L230000-188 

20500 BTU/lb 100 

20500 BTU/lb 100 

Dilution Factor: l 

ASTM D240-02 

0.04 ASTM D240-02 

12/23/09 

12/23/09 

9357188 

9357188 

NOTE(S) ; 

Calculations arc performed before rounding lo avoid round-off errors in calculated results. 

VES018263 
92 

LABORATORY CONTROL SAMPLE EVALUATION REPORT 

General Chends tryClien t Lot #...: H9L140403 Matrix : WASTE 

PERCENT RECOVERY PREPARATION- PREP 

PARAMETER RECOVERY LIMITS METHOD ANALYSIS DATE BATCH # 

Total Chlorine Work Order #: LQ76D1AC LCS Lot-Sample#: H9L170000-082 

100 (80 - 120) KNOX WC-0016 12/17-12/18/09 9351082 

Dilution factor: S 

Total Chlorine Work Order #: LRAEQ1AC LCS Lot-Sample#: H9L180000-031 

96 (80 - 120) KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 5 

NOTE(S) : , 

Calculations arc performed before rounding io avoid round-off errors in calculated results. 

VES018264 
93 

LABORATORY COHTROL SAMPLE DATA REPORT 

General ChemistryClien t Lot #...: H9L140403 Matrix : WASTE 

SPIKE MEASURED PERCNT PREPARATION- PREP 

PARAMETER AMOUNT AMOUNT UNITS RECVRY METHOD ANALYSIS DATE BATCH ff 

Tota l Chlorine Work Order ff: LQ76D1AC LCS Lot-Sampleff: H9L170000-082 

10000 9950 mg/kg 100 KNOX WC-0016 12/17-12/18/09 9351082 

Dilution Factor: 5 

Total Chlorine Work Order ff: LRAEQ1AC LCS Lot-Sample#: H9L180000-031 

10000 9570 mg/kg 96 KNOX WC-001S 12/21-12/28/09 9352031 

Dilution Factor: 5 

NOTE (S) ; 

Calculations are perrarmed before roundins 'a avoid round-off errors in calculaied results. 

VES018265 
94 

LABORATORY CONTROL SAMPLE EVALUATION REPORT 

General Chemistry 

Clien t Lot if.-. : H9L140403 Matrix. = SOLID 

PERCENT RECOVERY PREPARATION- PREP 

PARAMETER RECOVERY LIMITS METHOD ANALYSIS DATE BATCH ft 

Tota l Chlorine Work Order ft: LRGLV1AC LCS Lot-Sample#: H9L220000-OS5 

95 (80 - 120) KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 5 

NOTE(S) : ; , 

Calculations are performed before roundins to avoid round-off errors in calculated results. 

VES018266 
95 

IABORBXOEY CONTROL SAMPLE DATA REPORT 

General Chendstry 

Clien t Lot #...: H9L140403 Matrix : SOLID 

SPIKE MEASURED PERCNT PREPARATION- PREP 

PARAMETER AMOUNT AMOUNT UNITS RECVRY METHOD ANALYSIS DATE BATCH # 

Tota l Chlorine Work Order #: LRGLV1AC LCS Lot-Sample#: H9L220000-OS5 

10000 9480 mg/kg 9S KNOX WC-0016 12/22-12/29/09 9356d65 

Dilution Factor: S 

NOTB(S) : 

Calculations arc performed before rounding to avoid round-off errors in calculated results, 

VES018267 
96 

MATRIX SPIKE SAMPLE EVALUATION REPORT 

General Chemistry 

Client Lo t #...: H9L140403 Matrix : WASTE 

Date Sampled...: 12/08/09 Date Received..: 12/11/09 

PERCENT RECOVERY RPD PREPARATION- PREP 

PARAMETER RECOVERY LIMITS RPD LIMITS METHOD ANALYSIS DATE BATCH # 

Total Chlorine W0#: LQ2TG1AG-MS/LQ2TG1AH-MSD MS Lot-Sample #: H9L14O403-0O5 

100 (80 - 120) KNOX WC-0016 12/17-12/18/09 93S1082 

99 (80 - 120) 1.5 (0-10) KNOX WC-0016 12/17-12/18/09 9351082 

Dilution Factor: 6.98 

Total Chlorine WO#: LQ2TR1AE-MS/LQ2TR1AF-MSD MS Lot-Sample #: H9L140403-013 

87 (80 - 120) KNOX WC-0016 12/21-12/28/09 9352031 

97 (80 - 120) 1.0 (0-10) KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 9.57 

NOTE(S) : 

Calculous are performed before rounding io avoid round-off errors in calculated results. 

VES018268 
97 

MATRIX SPIKE SAMPLE DATA REPORT 

General ChemistryClien t Lot #.. 

Date Sampled.. 

.: H9L140403 

,: 12/08/09 Date Received..; 12/11/09 

Matrix. WASTE 

SAMPLE SPIKE MEASRD 

PARAMETER AMOUNT AMT 

Total Chlorine 

988 14000 

988 14400 

PERCNT 

RECVRY RPD METHOD 

PREPARATION- PREP 

AMOUNT UNITS ANALYSIS DATE BATCH # 

WO#: LQ2TG1AG-MS/LQ2TG1AH-MSD MS Lot-Sample #: H9L140403-005 

14900 mg/kg 100 KNOX WC-0016 12/17-12/18/09 9351082 

15200 mg/kg 99 1.5 KNOX WC-0016 12/17-12/18/09 9351082 

Dilution Factor: 6.98 

Total Chlorine 

15300 19100 

15300 17300 

W0#: LQ2TR1AE-MS/LQ2TR1AF-MSD MS Lot-Sample #: H9L140403-013 

31800 mg/kg 87 KNOX WC-0016 12/21-12/28/09 9352031 

32200 mg/kg 97 1-0 KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 9.S7 

NOTE(S): 

emulations are performed before rounding to avoid round-off errors in calculated results. 

VES018269 
98 

MATRIX SPIKE SAMPLE EVALUATION REPORT 

General Cnetnistry 

Clien t Lot # : H9L140403 Matrix : SOLID 

Date Sampled...: 12/09/09 Date Received..: 12/11/09 

PERCENT RECOVERY RPD PREPARATION- PREP 

PARAMETER RECOVERY LIMITS RPD LIMITS METHOD ANALYSIS DATE BATCH # 

Tota l Chlorine WO#: LQ2TP1AG-MS/LQ2TP1AH-MSD MS Lot-Sample #: H9L14O403-011 

88 (BO - 120) KNOX WC-0016 12/22-12/29/09 9356065 

91 (80 - 120) 2.2 (0-10) KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 5.01 

NOTE(S): 

Calculnions arc performed before rounding lo avoid round-off errors in calculaied results. 

VES018270 
99 

MATRIX SPIKE SAMPLE DATA REPORT 

General Chemistry 

Clien t Lot #... 

Date Sampled.... 

H9L140403 

12/09/09 Date Received. 12/11/09 

Matrix : SOLID 

PARAMETER 

SAMPLE SPIKE 

AMOUNT AMT 

Tota l Chlorine 

134 ' 

134 

MEASRD 

AMOUNT UNITS 

PERCNT 

RECVRY RPD METHOD 

PREPARATIONANALYSIS DATE 

10000 

9940 

PREP 

BATCH # 

WO#: LQ2TP1AG-MS/LQ2TP1AH-MSD MS Lot-Sample #: H9L140403-011 

8960 mg/kg 88 KNOX WC-0016 12/22-12/29/09 935606S 

9160 mg/kg 91 2.2 KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Pacton 5.01 

HOTS (5) : 

Calculations are performed before rounding lo avoid round-off errors in calculated rcsulis. 

VES018271 
100 

SAMPLE DUPLICATE EVALUATION EEPORT 

General Chemistry 

H9L140403 Work Order : LQ2TC-SMP Matrix : WASTE 

LQ2TC-DUP 

12/08/09 Date Received..: 12/11/09 

DUPLICATE RPD PREPARATION- PREP 

RESULT UNITS RPD LIMIT METHOD ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L140403-001 

1340 mg/kg 1.8 (0-10) ASTM D482-00a 12/29-12/31/09 9363434 

Dilution Factor: 1 

VES018272 
101 

Clien t Lot #. ..: 

Date Sampled — : 

PARAM RESULT 

Gross Calorifi c 

Value 

MD 

Ash Content 

1900 

Tota l Chlorine 

988 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

H9L140403 Work Order #. 

12/09/09 

LQ2TG-SMP 

LQ2TG-DUP 

Date Received..: 12/11/09 

Matrix. WASTE 

DUPLICATE 

RESULT 

ND 

1880 

999 

RPD 

UNITS RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # . . 

BTU/lb 0 (0-10) ASTM D240-02 

Dilution Factor: 1 

SD Lot-Sample #: H9L140403-005 

12/22/09 9356348 

SD Lot-Sample #: H9L140403-0OS 

• mg/kg 1.1 (0-10) ASTM D482-00a 

Dilution Factor: 1 

12/29-12/31/09 9363434 

SD Lot-Sample #; H9L140403-0O5 

mg/kg 1.2 (0-10) KNOX WC-0016 

Dilution Factor: 1.45 

12/17-12/18/09 9351082 . 

VES018273 
102 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Clien t Lot #...: H9L140403 Work Order #-..: LQ2TP-SMP Matrix. : SOLID 

LQ2TP-DUP 

Date Sampled : 12/09/09 Date Received..: 12/11/09 

DUPLICATE RPD PREPARATION- PREP 

PARAM RESULT RESULT UNITS RPD LIMIT METHOD ANALYSIS DATE BATCH # 

Gross Calorifi c SD Lot-Sample #: H9L14G403-011 

Value 

ND ND BTU/lb 0 (0-10) ASTM D5865-00 12/16/09 9350032 

Dilution Factor: 1 

Ash Content SD Lot-Sample #; H9L140403-011 

713000 703000 mg/kg' 1.3 (0-10) ASTM D482-00a 12/29-12/31/09 9363433 

Dilution Factor: 1 

Total Chlorine SD Lot-Sample #: H9L140403-011 

134 B 132 B mg/kg 1.6 (0-10) KNOX WC-0016 12/22-12/29/09 9356065 

Dilution Factor: 1 

NOTE (S) : 

Calculations arc pcrrormcd before rounding to avoid round-off errors in calculated results. 

B Estimated result. Result is less ton RL. 

VES018274 
103 

Clien t Lot it... : H9L140403 

Date Sampled...: 12/08/09 

SAMPLE DUPLICATE EVALUATION EEPORT 

General Chemistry 

Work Order #...: LQ2TR-SMP 

LQ2TR-DUP 

Date Received..: 12/11/09 

PARAM RESULT 

DUPLICATE 

RESULT 

Gross Calorifi c 

Value 

10200 

Total Chlorine 

15300 

9900 

15200 

Matrxx. WASTE 

UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #: H9L140403-013 

BTU/lb 2.9 (0-10) ASTM D240-02 12/23/09 

Dilution Factor: 1 

9357188 

SD Lot-Sample #: H9L140403-013 

mg/kg 0.19 (0-10) KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor: 8.39 

VES018275 
104 

Clien t Lot #...: H9L140403 

Date Sampled...: 12/08/09 

PARAM RESULT 

Tota l Chlorine 

4970 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #..-: LQ2T3-SMP 

LQ2T3-DUP 

Date Received..: 12/11/09 

4790 

Matrxx. WASTE 

DUPLICATE 

RESULT UNITS 

RPD 

RPD LIMIT METHOD 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

SD Lot-Sample #:- H9L140403-019 

mg/kg 3.5 (0-10) KNOX WC-0016 12/21-12/28/09 9352031 

Dilution Factor s 4.2 

VES018276 
105 

Clien t Lot #...: H9L140403 

Date Sampled...: 12/10/09 

SAMPLE DUPLICATE EVALUATION REPORT 

General Chemistry 

Work Order #... 

Date Received.. 

PARAM RESULT 

DUPLICATE 

RESULT 

Gross Calorifi c 

Value 

ND ND 

LQ2T5-SMP 

LQ2T5-DUP 

12/11/09 

UNITS 

RPD 

RPD LIMIT METHOD 

Matrix : WASTE 

PREPARATION- PREP 

ANALYSIS DATE BATCH # 

BTU/lb 0 

Dilution Factor: 1 

SD Lot-Sample #: H9L140403-021 

(0-10) ASTM D240-02 12/23/09 9357188 

VES018277 
r 

VES018278 
VES018279-018750.pdf 
Prepared for: 

rMti.fATv

e

enune

iCal S °IUti °n S

 Q V €OU A 

'

 muull e

 "venue — - ENVIRONMENT/ 

Sauget, IL 62201 sewings 

Comprehensive Performance Test Report 

Prepared for the Fixed Hearth Incinerator 

Number 3 in Accordance with 40 CFR § 

63 Subpart EEE 

AECOM 

February 2010 

Document No.: 60133216 

AZCOM 

VES018279 
Prepared for: 

Veolia ES Technical Solutions 

7 Mobile Avenue 

Sauget; IL 62201 

QV€OU A 

ErWIRONMENm. 

Comprehensive Performance Test Report 

Prepared for the Fixed Hearth Incinerator 

Number 3 in Accordance with 40 CFR § 

63 Subpart EEE 

"Prepared By Steven Milo 

Reviewed By Jeffrey Gorman 

AECOM 

February 2010 

Document No.: 60133216 

AECOM 

VES018280 
AsCOM 

Contents 

1.0 Introduction •• 1-1 

1.1 Program Summary 1-1 

1.2 Purpose and Objective of the Performance Test 1-1 

1.3 Program Description 1-1 

1.3.1 Test Operating Conditions 1-1 

1.3.2 Baghouse Cleaning Cycle 1-2 

1.3.3 Chlorine Feed 1-2 

1.4 Conditions in USEPA CPT Approval Letter Dated November 25, 2009 1-2 

1.4.1 Incinerator 2 DRE Data in Lieu Request 1-2 

1.4.2 Incinerators 2, 3, and 4 Metals Data in Lieu Request 1-2 

1.4.3 Request to Use Method 23 for Dioxins/Furans on Incinerators 2 and 3 1-3 

1.4.4 "As Fired" Waste Analyses and Waste Descriptions 1-3 

1.4.5 Tables 1-1 and 5-1 ofthe CPT Plans for Incinerators 2, 3, and 4 1-3 

2.0 Incinerator Process Description 2-6 

2.1 Process Overview 2-6 

2.2 Waste Feed Systems [40 CFR § 63.1207(f)(1)(ii)(c) and (f)(1)(iii)(D) and (E)] 2-6 

2.2,1 Unit 3 Liquid Waste Feed System and Blending Operations 2-6 

2.2.1.1 Organic and Aqueous Liquid Waste Feeds 2-6 

2.2.1.2 Packaged Waste Feed 2-7 

2.2.1.3 Specialty Liquid Waste Feeds 2-7 

2.3 Manufacturer, Make and Model of the Incinerator [40 CFR § 63.1207(f)(1)(iii)(A)] 2-7 

2.3.1 Combustion Chamber and Burners [40 CFR §63.1207(f)(1)(iii)(B) and (C) 2-7 

2.3.2 Secondary Combustion Chamber 2-8 

2.3.3 Location of Combustion Zone Temperature Device [40 CFR §63.1207(f)(1)(xix)] 2-8 

2.3.4 Hazardous Waste Residence Time [40 CFR §63.1207(f)(1)(ix)] 2-8 

2.3.5 Combustion System Leak... 2-9 

2.3.6 Emergency Safety Vent 2-9 

2.4 Procedures for Rapidly Stopping Hazardous Waste Feed During Equipment Malfunction [40 CFR 

§63.1207(f)(1)(viii)] 2-9 

2.5 Air Pollution Control Equipment [40 CFR §63.1207(f)(1)(iii)(G)] 2-9 

2.5.1 Air Pollution Control Systems Descriptions 2-9 

2.5.1.1 Lime System 2-10 

2.5.1.2 Spray Dry Absorber 2-10 

2.5.1.3 Fabric Filter 2-11 

2.5.1.4 Induced Draft Fan and Stack 2-11 

2.6 Stack Emissions Monitoring [40 CFR §63.1207(f)(1)(iii)(H)] 2-11 

i February 2O10 

VES018281 
A-COM 

2.6.1 CEMS System Description 2-12 

2.7 Process Monitoring and Control 2-12 

2.8 Automatic Waste Feed Cut-off System [40 CFR §63.1207(f)(1)(iii)(F)] : 2-13 

2.8.1 • AWFCO System Testing 2-14 

2.9 Air Pollution Control Equipment Maintenance Practices [40 CFR §63.1207(f)(1)(iii)(G)] 2-14 

2.9.1 Program Overview 2-14 

2.9.2 Test Program Preparation Activities., 2-15 

3.0 Summary of Results 3-1 

3.1 Process Operating Conditions 3-1 

3.2 Stack Emission Results for Total Chlorides (HCI/CI2) : 3-1 

3.3 Stack Emission Results for Particulate Matter.... 3-1 

3.4 Stack Emission Results for Dioxins and Furans 3-1 

3.5 Stack Emission Results for Total Hydrocarbons 3-1 

4.0 Sampling and Analytical Program 4-1 

4.1 Waste Feed Stream Sampling Procedures 4-1 

4.2 Stack Sampling Procedures 4-1 

4.2.1 Stack Sampling Location 4-1 

4.2.2 Velocity, Moisture and Fixed Gas Determinations 4-2 

4.2.3 Particulate Matter (PM), HCI and Cl 2 4-2 

4.2.4 PCDDs/PCDFs 4-2 

4.2.5 Continuous Emission Monitoring 4-2 

4.3 Analytical Procedures.... 4-3 

4.3.1 Analysis of Waste feed Streams 4-3 

4.3.1.1 Chemical and Physical Properties of Waste feed Streams 4-3 

4.3.2 Analysis of Stack Gas Samples : 4-3 

4.3.2.1 Total Chlorides (HCI/CI2) in Stack Gas Samples 4-3 

4.3.2.2 Particulate Matter (Gravimetric Analysis) 4-3 

4.3.2.3 Stack Gas-Analysis for PCDDs/PCDFs 4-3 

5.0 Quality Assurance 5-1 

5.1 Sample Collection QA/QC: 5-1 

5.1.1 Waste Feed Streams 5-1 

5.1.2 Stack Sampling QA/QC 5-1 

5.1.3 Pre-Sampling Activities 5-1 

5.1.4 Equipment Calibration.. 5-1 

5.1.5 Glassware Preparation 5-2 

5.1.5.1 Sample Media Preparation 5-2 

5.2 Chain-of-Custody 5-3 

5.3 Analytical QA/QC 5-3 

ii February 2010 

VES018282 
AZCOM 

5.3.1 Analysis of Waste Feed Streams 5-3 

5.3.1.1 Chemical and Physical Properties of Waste Feed Streams 5-3 

5.3.2 Analysis of Stack Gas Samples : 5-3 

5.3.2.1 Total Chlorides (HCI/CI2) in Stack Gas Samples.... 5-3 

5.3.2.2 Particulate Matter (Gravimetric Analysis) 5-3 

5.3.2.3 PCDDs/PCDFs in Stack Gas Samples 5-4 

List of Appendices 

Appendix A Facility Operating Data 

Appendix B Reference Method Field Data and Calculations 

Appendix C Reference Method Calibrations, Verifications, and Certifications 

Appendix D Laboratory Data 

List of Tables 

Table 1 -1 Summary of Applicable MACT Emission Standards 1-4 

Table 1-2 MACT OPLs Established During the Performance Test 1 -5 

Table 2-1 Continuous Emission Monitors 2-12 

Table 2-2 Technical Information Summary on Incinerator No. 3 2-16 

Table 2-3 Current AWFCO Parameters and Limits for Incinerator No. 3 2-17 

Table 3-1 Waste Feed Rates and Operating Conditions 3-2 

Table 3-2 RM 5/26A Sampling Parameters and Emission Results - Total Chloride/PM 3-3 

Table 3-3 RM 0023A Sampling Parameters and Emission Results - Dioxin and Furan 3-4 

Table 3-4 RM 25A Sampling Parameters and Emission Results 3-5 

Table 4-1 Traverse Point Locations 4-4 

Table 5-1 QA/QC Requirements for Chemical/Physical Properties of Waste Feed 5-5 

Table 5-2 QA/QC Requirements for Chlorides in Stack Gas 5-6 

Table 5-3 QA/QC Requirements for PCDD/PCDF Analyses of Stack Gas Samples 5-7 

List of Figures 

Figure 2-1 Hydrated Lime Specifications 2-18 

Figure 4-1 Unit 3 Exhaust Stack Schematic 4-5 

iii February 2010 

VES018283 
1.0 Introduction 

1.1 Program Summary 

AECOM Environment (AECOM) was retained by Veolia ES Technical Solutions (Veolia), to conduct a 

comprehensive performance test (CPT) for its Incinerator No. 3 as required under 40 CFR § 63.1207 of the 

Hazardous Waste Combustor (HWC) MACT regulations. The CPT was conducted during the week of 

November 30, 2009 for the Sauget, IL facility. 

The results from this testing indicate that emissions for dioxins and furans (PCDDs/PCDFs), total 

hydrocarbons, hydrogen chloride and chlorine, and particulate matter (PM) met the applicable emission 

standards under 40 CFR 63 Subpart EEE (otherwise known as the HWC MACT regulations). A summary of 

the test results can be found in Section 3 of this report. 

1.2 Purpose and Objective of the Performance Test 

The purpose of the CPT was to validate the performance level of the incinerator against the requirements in 40 

CFR Part 63, Subpart EEE. To this end, the specific objectives of this CPT were to: 

• Demonstrate that the emissions from the incinerator meet the HWC MACT emission limits while 

treating hazardous waste forthe parameters being tested. 

• Collect monitoring data in order to re-establish operating parameter limits (OPLs) or set new OPLs on 

key operating variables that will ensure that the incinerator operates within the HWC MACT emission 

limits while treating hazardous waste. 

The test program included feeding a variety of liquid and solid waste materials to the incinerator, sampling and 

analyzing the feed streams, monitoring certain process parameters and conducting emissions testing. The 

emissions standards that were evaluated under the HWC MACT regulations are summarized in Table 1 -1. 

1.3 Program Description 

1.3.1 Test Operating Conditions 

The test condition for this CPT was designed to demonstrate compliance with the applicable MACT dioxins 

and furans (PCDDs/PCDFs); total hydrocarbons, hydrogen chloride and chlorine, and particulate matter (PM) 

emissions standards. During the dioxin/furan emission testing, Unit 3 was operated at minimum combustion 

zone temperatures while maximizing pumpable and total waste feeds. Normal (or higher) levels of chlorine 

were fed. The flue gas flow rate and baghouse inlet temperature were maximized. 

During the HCI/CI2 emission testing, Unit 3 was operated at maximum flue gas flow rate and maximum 

chlorine feed rate. Sorbent feed rate and carrier fluid flow rate were minimized. 

1-1 February 2010 
AZCONl 

During the PM emission testing, Unit 3 was operated at maximum flue gas flow rate and maximum ash feed 

rate. To ensure that the particulate matter control device underwent its normal (or more frequent) cleaning 

cycle, a cleaning cycle was manually initiated during each run if a timed cleaning cycle was not anticipated. 

The waste feed rates that were used for the performance test program are summarized in Table 1-2. A copy 

of the actual process monitoring data is included in Appendix A. 

1.3.2 Baghouse Cleaning Cycle 

During all three test runs in the PM and HCI/CI2 testing programs on Unit 3, cleaning cycles forthe baghouses 

were manually initiated during the testing. The cleaning cycles were manually initiated to ensure the 

baghouses went through a cleaning cycle during the stack sampling since the typical operation ofthe cleaning 

cycle is initiated by a timer every four hours. The baghouse cleaning cycles occurred at approximately 11:31 

during Run 1, at 10:20 during Run 2, and at 10:58 during Run 3 ofthe PM and HCI/CI2 testing programs. 

Relatively higher pressure drops can be noted in the operating data for approximately seven minutes during 

which the baghouses were undergoing the cleaning cycle. This satisfies the requirements in 40 CFR 

§63.1207(g)(1)(C). 

1.3.3 Chlorine Feed 

Pursuant to 40 CFR §63.1207(g)(1)(A), normal or higher levels of chlorine were fed to Unit 3 during the 

dioxin/furan performance tests. The historical average feedrate for chlorine is 60 Ib/hr. The test feedrates for 

chlorine during all dioxin/furan test runs were >131 Ib/hr. 

1.4 Conditions in USEPA CPT Approval Letter Dated November 25, 2009 

1.4.1 Incinerator 2 DRE Data in Lieu Request 

USEPA stated in the CPT approval letter that Veolia may re-submit the request to use previous DRE test data 

as documentation of compliance with the HWC MACT emission standard for DRE. On December 3, 2009, 

Veolia submitted results of an Incinerator 2 DRE test (report dated March 8, 1993) to the USEPA. EPA 

reviewed the Incinerator 2 data and concluded that it meets the criteria set forth in 40 C.F.R. § 

63.1207(c)(2)(i)(A-D). USEPA sent Veolia a letter dated December 11, 2009 approving Veolia's request to 

use prior RCRA Trial Burn DRE data for Incinerator 2 to demonstrated compliance with the DRE standard in 

40 C.F.R. § 63.1219(c) and to establish the DRE OPL's required by 40 C.F.R. § 63.12190). 

1.4.2 Incinerators 2, 3, and 4 Metals Data in Lieu Request 

The USEPA approves Veolia's request to use metals performance test data from August and September 2008 

to demonstrate compliance with the mercury, SVM, and LVM emission standards and to establish the 

applicable mercury, SVM, and LVM OPL's if metals feed rates are based solely on the spike concentrations. 

The results of the performance tests on each hazardous waste incinerator demonstrate compliance with the 

mercury, SVM, and LVM emission standards under the conditions that existed during testing. Due to the 

questionable moisture content ofthe solid waste samples, agreement on the metals concentration ofthe solid 

waste is the subject of current discussions Veolia and USEPA are having regarding the inclusion of metals 

feeds that were native to the wastes to determine the metals feed rates for the 2008 performance tests. 

1-2 February 2010 

VES018285 
1.4.3 Request to Use Method 23 for Dioxins/Furans on Incinerators 2 and 3. 

USEPA disapproved Veolia's request to use Method 23 instead of Method 0023A to conduct the dioxin/furan 

performance tests on Incinerators 2 and 3. Veolia used Method 0023A for the dioxin/furan performance tests 

on all three incinerators. 

1.4.4 "As Fired" Waste Analyses and Waste Descriptions 

Veolia agreed to include in the final test burn report the "as fired" heating value and concentrations of ash, 

mercury, SVM, LVM, total chlorine and organic HAP's in each wastestream burned during the CPT. Included 

in Appendix A are the waste feed profile sheets, which contain the chemical compositions of the wastes, and 

the analyses ofthe wastes, which contain the "as fired" heating value and concentrations of ash, mercury, 

SVM, LVM, and total chlorine. 

1.4.5 Tables 1-1 and 5-1 of the CPT Plans for Incinerators 2, 3, and 4 

For the hydrogen chloride and chlorine emissions parameter in Tables 1-1 and 5-1, the correct limit should be 

32 ppmv Cl" on a dry basis, corrected to 7% oxygen. The correct citation is 40 C.F.R. § 63.1219(a)(6). These 

have been corrected in this report. 

For the PCDDs/PCDFs (TEQ basis) emissions parameter in Tables 1-1 and 5-1, the limit of 0.20 ng/dscm for 

operation above 400 deg F and the limit of 0.40 ng/dscm for operation below 400 deg F can apply to Veolia's 

hazardous waste incinerators since the inlet temperature to the particulate matter control device can be 

controlled above or below 400 deg F. Incinerators 2 and 3 demonstrated compliance at an emission level 

<0.20 ng/dscm so both units continue to have the ability to operate their respective pollution control equipment 

with an inlet temperature above 400 deg F. Incinerator 4 has historically demonstrated compliance at an 

emission level of <0.20 ng/dscm however was only capable of demonstrating compliance at an emission level 

of <0.40 ng/dscm. The inlet temperature must be controlled below 400 deg F. Veolia is currently considering 

whether to continue operating below 400 deg F or repeat the test. 

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Table 1-1 Summary of Applicable MACT Emission Standards 

I Emissions Parameter Limit Citation 

PCDDs/PCDFs (TEQ basis) £0.20 ng/dscm 

£ 0.40 ng/dscm 

40 CFR 63.1219(a)(1)(i)(A) 

40 CFR§63.1219(a)(1)(i)(B) 

Carbon Monoxide < 100 ppmv 40 CFR§63.1219(a)(5)(i) 

Total Hydrocarbons s10 ppmv 40 CFR § 63.1219(a)(5)(ii) 

Hydrogen Chloride & Chlorine £ 32 ppmv dry as Cl" 40 CFR § 63.1219(a)(6) 

Particulate Matter (PM) £ 0.013 gr/dscf 40 CFR § 63.1219(a)(7) 

Note: All emission concentrations are corrected to 7% oxygen. 

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Table 1-2 MACT OPLs Established During the Performance Test 

Process Parameter Units 

Avg. 

Period 

How Limit 

Established 

Maximum Pumpable Waste 

Feed Rate 

Ib/hr 1-hr Avg. of max. HRAs for 

each run 

Maximum Total Hazardous 

Waste Feed Rate 

Ib/hr 1-hr Avg. of max. HRAs for 

each run 

Minimum PCC Temperature °F 1-hr Avg. of the test run 

averages 

Minimum SCC Temperature °F 1-hr Average ofthe test 

run averages 

Maximum Flue Gas Flowrate acfm 1-hr Average of maximum 

HRAs for each run 

Maximum Ash Feed Rate Ib/hr 12-hr Average of the test 

run averages 

Maximum Chlorine/Chloride 

Feed Rate 

Ib/hr 12-hr Average, of the test 

run averages 

Minimum Sorbent Feedrate lb/lb Cl 2 1-hr Avg. of the test run 

averages 

Minimum Carrier Fluid 

Flowrate 

gal/lb Cl 2 1-hr Avg. of the test run 

averages 

Maximum Fabric Filter Inlet 

Temperature 

op 1-hr Average of the test 

run averages 

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2.0 Incinerator Process Description 

A-COM 

2.1 Process Overview 

Veolia operates two Fixed Hearth Dual Chambered Incinerators (Units 2 and 3) and one rotary kiln incinerator 

(Unit 4) at the Sauget, IL facility. The two fixed hearth units are rated at 16 million Btu/hr each. Incineration 

Unit No. 3 is a mirror image of Unit No. 2. Both of these units have their own waste handling systems as 

described in the sections that follow. The only difference being Unit No. 2 is equipped with four (4) baghouse 

modules, while Unit No. 3 is equipped with three (3) baghouse modules. However, each incinerator is 

operated identically with only three baghouse modules in service during operation. Unit 4 is rated at 50 million 

Btu/hr and is equipped with its own tank farm system, drum storage, bulk solids storage and feed systems. 

2.2 Waste Feed Systems [40 CFR § 63.1207(f)(1)(ii)(c) and (f)(1)(iii)(D) and (E)] 

2.2.1 Unit 3 Liquid Waste Feed System and Blending Operations 

The fixed hearth incinerator is designed to receive containers, aqueous liquid wastes, organic liquid wastes, 

specialty liquid feeds and direct inject liquids fed through the aqueous or organic liquid feed systems. These 

units can receive any combination of wastes - liquid, semi-solid or solid - with a heat value of up to 16 million 

Btu/hr. 

Unit 3 is supported by storage/blend tanks located in Tank Farm #1. Rates of feed are controlled at each 

incinerator. Segregated liquid wastes are stored until utilized in the waste blending facilities. At that time, 

liquids are delivered to the blending tanks where the daily liquid feed to the incinerator is formulated, tested, 

and released to the incinerator. Biending of stored liquid wastes to achieve optimum heating value and 

viscosity for incineration takes place in Tanks 2,4,6 & 8. Six additional tanks (10, 20, 30, 40, 50 & 60) are 

used to segregate different waste stream types for blending of liquid feed to the incinerator. Several criteria 

are important in designing a blend from available Wastes that have been segregated principally by physical 

and chemical properties. These include compatibility, proper range of heating value, and permit restrictions 

regarding elemental composition (based on emission limitations). The material is transferred through 

aboveground pipelines from the tank farm to the incinerator. Pipelines used to transfer liquid organic waste 

and aqueous waste are equipped with strainers. 

In compliance with the Benzene NESHAP, all tanks are vented to individual carbon adsorption canisters for 

removal of organics before vapor is discharged to the atmosphere. Each carbon adsorber canister is 

essentially equivalent to a 55 gallon container or greater, if necessary. All tanks are equipped with 

conservation vents, in addition to the carbon canister adsorber. All tanks are grounded, and flame arrestors 

are installed between the carbon adsorbers and the tanks. 

2.2.1.1 Organic and Aqueous Liquid Waste Feeds 

The liquid waste injectors used in the combustion chambers are air-atomizing injectors. These are used for 

injection of high Btu, low Btu liquids and specialty feed liquids. Dual fluid injection nozzles will be used for 

atomization of the waste. Each of the injectors is rated at 0-300 gph. The liquid waste feed nozzles are 

served by parallel redundant pumps and recirculation systems with back pressure control. 

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2.2.1.2 Packaged Waste Feed 

Containers of wastes are sampled and analyzed after receipt in accordance with the facility's Waste Analysis 

Plan. These wastes can then be delivered directly to Unit 3 or repacked into small combustible containers at 

the facility. Fiberboard or plastic containers (fully or partially full of waste), up to 40-gallon size, may be 

charged directly to the primary chamber. These will be received at the dock adjoining each fixed hearth 

incinerator, and charged to the incinerator within 24 hours or returned to permitted storage. 

Solids, usually packaged in plastic or fiberboard containers, are introduced into the incinerator through a PLC 

controlled airlock-ram system located at the lower front of the primary chamber of the incinerator. The airlock 

is composed of a refractory-lined door, a door into the airlock enclosure, and two pneumatic rams. The action 

of the feeder is as follows: 

• With the incinerator door closed, the airlock door is opened. 

• The first pneumatic ram (load ram) pushes weighed charges of waste into the airlock chamber. 

• The airlock door is closed. 

• A switch is activated either automatically or manually, which opens the door to the incinerator and 

actuates the ram (charge ram) that pushes the waste into the incinerator. The ram then retracts and 

the incinerator door closes. 

2.2.1.3 Specialty Liquid Waste Feeds 

Specialty Feed Systems associated with incinerator No. 3 are as follows 

• Hooded Specialty Container Feeder 

• Glove Box Emission Control Systems 

• Direct Inject Liquid Feed System 

2.3 Manufacturer, Make and Model of the Incinerator [40 CFR § 63.1207(f)(1)(iii)(A)] 

2.3.1 Combustion Chamber and Burners [40 CFR §63.1207(f)(1)(iii)(B) and (C) 

Incinerator No. 3 features a two-stage combustion process. Ignition of waste material takes place in the 

primary (lower) combustion chamber (PCC). A secondary (upper) combustion chamber (SCC) serves as an 

"after-burner" for process gases. Ignition of the waste takes place at temperatures in excess of 1700 

degrees F. The secondary combustion chamber maintains a minimum temperature of approximately 1800 

degrees F. 

The fixed hearth incinerator is fabricated of carbon steel. The primary chamber has an external diameter of 9 

feet and is 17.5 feet long. The interior walls of the chamber are lined with approximately 10 inches of brick 

refractory and insulation backing, making the internal operating diameter approximately 7'2". The crosssectional area of the chamber is thus 40.3 square feet. Table 2-2 provides a summary of the incinerator 

design specifications. 

Liquid and solid waste feeds enter the lower chamber on the front-face of the chamber. The primary burner 

and the specialty feed injector are located near the front-face of the chamber and are mounted tangentially. 

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The primary burner is a North American burner rated at 12.0 million Btu/hr. and is used in the lower chamber 

to maintain permitted temperatures. It will burn only natural gas or No. 2 fuel oil. The burner system is 

supplied with combustion air at a static pressure of 30" water column (WC). The pilot for the primary burner will 

burn natural gas. 

The fuel system for the lower chamber (and secondary combustion chamber) is controlled by a Factory Mutual 

approved burner management system complete with interlocks and safety valves. 

2.3.2 Secondary Combustion Chamber 

The secondary combustion chamber (SCC) is a horizontal, cylindrical chamber that has an external 

diameter of 9 feet and is 17.5 feet long. The interior walls of the chamber are lined with approximately 10 

inches of brick refractory and insulation backing, making the internal operating diameter approximately 

7'2". The cross-sectional area of the chamber is thus 40.3 square feet. 

Following ignition of the waste material under controlled or starved-air conditions in the lower chamber, offgases travel through a refractory-lined flue gas passage into the upper chamber, which acts as an afterburner. 

Turbulence is achieved by the tangential introduction of air and additional fuel in the upper chamber. 

The SCC is equipped with one burner mounted tangentially on the side ofthe chamber. The burner is a North 

American burner rated at 6.0 million Btu/hr and is fueled with natural gas or fuel oil. 

As with the primary chamber burner, the SCC burner is supplied with atomizing air and is equipped with a 

burner management system. This system controls the ignition and initiates an automatic shutoff when there is 

a loss of flame, combustion air supply, fuel pressure, atomizing air pressure, or pilot burner. 

Leaving the upper chamber, the hot gas stream travels through 28 feet of refractory-lined stack sections before 

reaching the start of the gas scrubbing system. The combined volume of the upper and lower chambers, the 

flue gas passage and the hot crossover section is approximately 1,567 cubic feet. The total retention time of 

combustion gases within the system is approximately 5 seconds. 

2.3.3 Location of Combustion Zone Temperature Device [40 CFR §63.1207(f)(1)(xix)] 

The thermocouple that monitors temperature in the primary combustion chamber is located on top ofthe 

chamber about five feet from the transition. The thermocouple that monitors temperature in the SCC is located 

on top of the chamber above the transition. 

2.3.4 Hazardous Waste Residence Time [40 CFR §63.1207(f)(1)(ix)] 

The Hazardous waste gas residence time for the Fixed Hearth Incinerator is calculated as follows: 

• Primary Combustion Chamber Volume - 635 ft3 

• Secondary Combustion Chamber Volume - 635 ft3 

• Total Volume - 1270 ft3 

• Maximum Flue Gas Flowrate -17,382 acfm (290 ft3/sec) 

• Total Combustion Zone Residence Time = (1270 ft3)/(290 ft3/sec) = 4.4 sec 

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Since these incinerators are fixed hearth units residence time is based on the elapsed time since the last 

solids charge was put into the combustion zone or based on the travel length of the ash ram that functions to 

clear the primary combustion chamber of solid waste residue. An elapsed time of one hour or a travel length , 

of 110 inches for the ash ram have been established as the criteria for determining when solid waste is no 

longer in the combustion zones. 

2.3.5 Combustion System Leak 

Combustion system leaks are prevented through maintaining a totally sealed combustion chamber, coupled 

with the use of an induced draft fan that maintains a vacuum of normally - 4 to - 6 inches of water column in 

both combustion chambers while wastes are being fed to the unit. 

2.3.6 Emergency Safety Vent 

The incinerator is equipped with an emergency safety vent (ESV) located at the top of the secondary 

combustion chamber. This ESV is a refractory-lined emergency thermal relief vent (TRV) which is held in the 

closed position by a pneumatic cylinder. The control valve in the line supplying air to the cylinder and the 

cylinder vent valve that opens the TRV are located in the control room for each unit. Valve locks (with keys 

attached) are utilized to deter indiscriminate operation of these valves. Opening ofthe TRV allows hot 

combustion gas to vent from the combustion system during emergency shutdown events. The purpose of the 

TRV is to protect the downstream APCS from excessive temperature situations. A limit switch on the 1RV 

shuts off all waste feeds to the system as it senses that the cap is opening. 

2.4 Procedures for Rapidly Stopping Hazardous Waste Feed During Equipment 

Malfunction [40 CFR §63.1207(f)(1)(viii)] 

Equipment malfunctions are identified by the control system, observation of process control variables, or by 

regular field inspections. 

In the event of minor equipment malfunctions (e.g. waste feed or scrubber leaks), the control room operator 

will be notified. The control room operator will then close the waste feed valves and disable the waste feed 

pumps. 

In the event of major equipment malfunctions (e.g. fire), the emergency stop button located in the control room 

wiil be pushed. If this button is pushed, all equipment will switch to its fail-safe position. 

2.5 Air Pollution Control Equipment [40 CFR §63.1207(f)(1 )(iii)<G)] 

2.5.1 Air Pollution Control Systems Descriptions 

The air pollution control system consists of a spray dryer absorber and fabric filter baghouse. The air pollution 

control system neutralizes acidic compounds and removes particulate from the exhaust gas. Two 

subsystems, the spray dryer absorber and the fabric filter, carry out the chemical neutralization and particulate 

removal functions, respectively. A third subsystem, the lime system, is used to prepare and provide lime slurry 

to the spray dryer absorber for use in the chemical neutralization process. The induced draft fan and stack 

provide the mechanical energy required to transport the flue gas through the interconnecting ductwork, to its 

eventual discharge point to atmosphere. 

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2.5.1.1 Lime System 

The lime system prepares lime slurry for use in the chemical neutralization process in sufficient supply and 

concentration to maintain continuous flue gas treatment in the spray dryer absorber. The system has been 

designed for batch mixing to provide this service. Veolia utilizes hydrated lime as its neutralizing agentin the 

air pollution control systems. The key neutralization parameter of the hydrated lime is the "CaO Equivalent". 

Figure 2-1 is the specification sheet for the hydrated lime that Veolia uses. Veolia has used this specific 

product for over 20 years and plans to continue with its use. Although, if Veolia does change suppliers or type 

of lime in the future, it would have a "CaO Equivalent" specification equal to or greater than the 72.6% shown 

on Figure 2-1. 

Hydrated lime is stored in a storage bin above the lime preparation area. The storage bin is sized to hold 

enough hydrated lime to maintain several days of system operation at the maximum combustion rate ofthe 

incinerator. Lime is discharged through the conical storage bin bottom. The flow of the material from the bin is 

aided by a vibrating "live bottom," or bin activator. A variable speed screw feeder is used to meter the 

hydrated lime in the proportions required for batch mixing lime slurry. The lime is mixed with water in atank 

beneath the iime storage bin. The screw feeder speed and the rate that water is added to the lime slurry tank 

are variable so that the desired lime solids concentration can be achieved in the tank. The variable feed 

adjustments allow water and lime to be added to the lime slurry tank at a rate that will allow a batch mode of 

mixing. An agitator is provided in the slurry tank to mix the water and lime and to maintain the suspension of 

lime solids. The mixed lime slurry is pumped at a continuous rate of flow through a recirculation loop to the 

atomizer at a rate of up to 10 gpm. 

2.5.1.2 Spray Dry Absorber 

Unit 3 is equipped with a Spray Dryer Absorber (SDA) located immediately downstream ofthe secondary 

combustion chamber. The SDA unit is fabricated of 3/8 inch carbon steel. The function of the SDA is to: 

• Further cool the combustion gases from 1600-2000°F to 300-500°F, 

• Neutralize and remove HCI and other acids from the combustion gases, 

• Remove a portion of the particulate (fly ash) from these gases. 

Slurry flow to the spray dryer absorber (SDA) is metered by a flow control valve to obtain the proper feed 

concentration to the spray dryer absorber atomizer. Automatic (or manual) adjustment to the flow is made as 

a function of the output from a hydrochloric acid (HCI) analyzer in the gas duct downstream of the fabric filter. 

The amount of slurry metered is proportional to the amount of HCI monitored. 

The slurry passes through a stationary swirl-type liquid distributor into the atomizer wheel where induced 

centrifugal force from the rapidly spinning wheel discharges the slurry through the wheel nozzles at high 

velocity. The design of the atomizer wheel, its rate of spin, and the discharge velocity of the slurry, create a 

cloud of finely divided droplets around the periphery of the atomizer wheel. A feedback signal from the 

atomizer power transmitter provides verification that water flow to the atomizer increases or decreases in 

proportion to the spray dryer absorber outlet temperature. 

Flue gas enters from the bottom of the spray dryer absorber through a vertical, centrally located disperser. 

The disperser directs the flue gas through the zone filled by the atomized slurry cloud where the flue gas and 

slurry mix and most ofthe absorption occurs. The gases then flow downward through the absorber chamber 

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AECOM 

and exit through a bottom side duct. As the gases contact and pass through the cloud of atomized lime slurry, 

the water in the slurry evaporates, cooling the gases. Simultaneously, the lime in the slurry reacts with the 

hydrogen chloride in the gases to produce calcium salts. Some of the resulting dry material, consistingof 

calcium salts, fly ash and excess lime, falls to the conical bottom ofthe unit. The dry material from each unit is 

discharged to a conveyor system that transports it to a dump trailer or equivalent type system. 

2.5.1.3 Fabric Filter 

Gas exhausted from the spray dryer absorber is distributed by manifold ducts to three fabric filter modules. 

Within each filter module, the gas is passed through Teflon-coated fiberglass cloth bags. The gas passes from 

the outside to the inside ofthe filter bags. Particulate, entrained in the gas stream, is mechanically deposited 

on the outside ofthe filter bags as the gas passes through the cloth. 

Each module has a clean air plenum and housing section to contain approximately 96 bags. Each bag is 

approximately 6" in diameter by 20' long. The baghouses are fabricated from 3/16" mild steel plate, of welded 

construction, gas tight and stiffened to withstand the maximum operating negative pressure. Each 

compartment has a tube sheet that supports the bags and provides for top bag/cage removal. Access ta the 

clean air plenum is via a side access door in the clean air plenum. 

The fabric filter cleaning mechanism utilizes jets of air to clean the filter bags. Periodically, the cleaning 

sequence will be initiated. The sequence is either started at the end of a timed cycle, or when the differential 

pressure across the filter reaches a predetermined setpoint of approximately 7.0" w.c, or when the operator 

initiates a cycle. The controller then sequences to each row of filter bags in each module, releasing a burst of 

air opposite to the direction of gas flow. The quickly released burst of air dislodges dust cake on the exterior of 

each bag as it travels from the top to the bottom ofthe bags. Released from the bag, the dust cake falls by 

gravity into the hopper at the bottom of the module. From there it is discharged to a conveyor system that 

transports it to a dump trailer, or equivalent type system. 

Treated by the spray dryer absorber and filtered by the fabric filter, the cleaned flue gas exits the Fabric filter 

modules to an outlet manifold for exhaust. 

2.5.1.4 Induced Draft Fan and Stack 

The induced draft fan and stack are located downstream of the fabric filter. Combustion gases are drawn 

through the system by a 75 hp induced draft (ID) fan, rated at 15,000 acfm at 400° F saturated, and 22" water 

column pressure. The induced draft fan provides the mechanism for transporting the incinerator flue gas 

through the spray dryer absorber, Fabric filter, and all interconnecting ducts. The ID fan includes an inlet 

volume control damper to be used to control the velocity of the gas within the ducting and treatment devices. 

Treated gasses exhausted from the induced draft fan to the atmosphere through a 90-ft. high stack. The 

stack diameter is 39 inches I.D. The stack is equipped with instrument sampling ports and a sampling platform 

for emissions testing. Figure 4-1 provides details on the design and sample port locations and configurations 

for the stack. 

2.6 Stack Emissions Monitoring [40 CFR §63.1207(f)(1 )(iii)(H)] 

The continuous emissions monitoring system (CEMS) consists of sample probes, sample delivery and 

conditioning apparatus, and gas analyzers. Samples are extracted from the sampling ports on the stack. A 

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AECOM 

CEM performance test and quality assurance program has been implemented in accordance with the 

Appendix to Subpart EEE of Part 63—Quality Assurance Procedures for Continuous Emissions 

, Monitors Used for Hazardous Waste Combustors. 

Responses from each CEMS were fed to the Control System (CS) where the CO hourly rolling average was 

calculated and interlocked to the waste feed cutoff valves as part ofthe Automatic Waste Feed Cutoff System 

(AWFCO) discussed in Section 2.8, below. The following provides a brief description ofthe CEMS 

instruments including the operating range and measurement principal. 

2.6.1 CEMS System Description 

The Continuous Emissions Monitoring Systems (CEMS) currently utilized at Incinerator 3 analyzes for opacity, 

carbon monoxide, hydrogen chloride, total hydrocarbons and oxygen. These monitors, except opacity, are 

extractive devices mounted in sampling ports on the stack. The table below summarizes the analyzer 

specifications. 

The opacity monitor continuously measures the stack gas opacity and reports the measurements to an 

indicator and a recorder. An opacity that exceeds a preset limit triggers an alarm and interlock. 

Carbon monoxide and hydrogen chloride are monitored with extractive non-disperse infrared analyzers, Total 

hydrocarbon is monitored with an extractive flame ion detector analyzer. Oxygen is monitored with a 

zirconium oxide cell. 

Stack gas flow rate is continuously monitored using an anubar that sends a 4-20 mA signal to the PLC that 

converts the signal to acfm. 

Table 2-1 Continuous Emission Monitors 

Parameter Current Mfg. Range Principle 

Oxygen COSA 0-25% Electrochemical 

Carbon Monoxide Ecochem MC3 0-200 ppmv 

0-3000 ppmv 

Infrared 

Total hydrocarbons Thermoelectron 0-100 ppmv FID/I nfrared 

Hydrogen chloride Ecochem MC3 0-1,000 ppmv infrared 

Opacity Teledyne 0-100% White light 

Stack gas flow PSE/Rosemount 0-20,000 acfm Pressure drop 

2.7 Process Monitoring and Control 

The facility is equipped with a state-of-the-art monitoring and control system, which facilitates compliance with 

permit conditions, and otherwise, collects process control information, facilitates efficient operation and detects 

and prevents damage to the facility. The system consists of three major components: 

• A human-machine interface (HMI) system, 

• Programmable logic controller's (PLC's), and 

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AECOM 

• A high speed ethernet cable connects all control system components 

The desired control functions are implemented through the HMI system. All digital control and emergency 

interlocks are accomplished by the PLC. 

The control system is capable of monitoring the "operational envelope" ofthe incinerator and is capable of 

performing a number of activities including: 

• Control room indication of processor sensors located within the incinerator system (such as pressure 

indication of a field installed pressure transmitter); 

• Process controller for single instrument loops or an individual sub-system, such as a temperature 

control loop involving a sensor reading from one temperature transmitter affecting the function of one 

temperature control valve; and 

• Alarm for an exceedance of a designated setpoint, such as a high pressure or low temperature. 

The process control computer will continuously control and monitor the operation of the incinerator. When 

out-of-range conditions exist, it will notify the operator of those conditions. The process control computer is 

programmed to shut-down equipment (i.e., bring the system into a safe mode) when designated parameters 

are exceeded, which is a protective mechanism against potential equipment damage, operation outside of 

permit limits, or conditions that might lead to a release to the environment. 

Continuous monitoring ofthe incinerator and scrubber system is an important aspect of the system design. A 

digital readout of all monitoring instrumentation is displayed on the main control screen. An audible and visual 

alarm alerts the incinerator operator to significant deviations from normal operating conditions. This system 

allows an immediate response to adverse conditions by the operator. Automatic waste feed cut-off and 

incineration shutdown mechanisms are also interlocked with the monitoring system at or prior to reaching 

permit limit levels. Monitoring methods and calibration frequencies are listed in Table 2-3. 

The Incinerator has an independent process control computer that interfaces to the Quantum Progammable 

controllers. The process computer is capable of controlling the incinerator in case of a failure in a HMI server. 

This computer runs a RSVIEW HMI control software that provides operator interface to all instrumentation and 

controls. 

2.8 Automatic Waste Feed Cut-off System [40 CFR §63.1207(f)(1)(iii)(F)] 

The incinerator has an Automatic Waste Feed Cut-Off (AWFCO) System that will shut waste feeds off in the 

event certain operating parameters deviate from allowable set points. The PLC continuously monitors 

operating parameters, making adjustments to the process as needed for proper control. Alarm logic is 

incorporated into the PLC system to automatically initiate an AWFCO. Table 2-3 summarizes the current 

AWFCO set points. AWFCO limits have been established based on several factors that are summarized 

below. 

• Regulatory/permit limits - established to comply with existing permits. An example of this type of limit 

is the low temperature limit, below which waste can not be fed until the proper limit is re-established. 

In addition, the HWC MACT regulations require that the AWFCO system be interlocked with the span 

of each process instrument that is part ofthe Continuous Monitoring System (CMS). A listing of these 

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CMS instruments and their interlocked span setpoints is maintained as part of Veolia's Operating 

Record. 

• Process safety limits - established to assure process equipment is protected and unsafe operating 

conditions do hot occur. An example of this is inadequate excess air in the combustion chamber that 

can lead to fuel rich conditions. 

• Utility or Power failure - established to facilitate a controlled shutdown of the process during loss of 

process air, steam, water or electricity. An example of this is the loss of instrument air that is 

necessary for certain types process instruments to function properly. Wastes will not be re-introduced 

into the incinerators until proper operation of key instruments is re-established. 

In addition to the AWFCO system, operators can manually shutdown waste feeds or the entire process should 

this be needed. 

2.8.1 AWFCO System Testing 

Veolia tests the AWFCO systems bi-weekly, as weekly testing would unduly interfere with operations by 

ceasing and restarting waste feeds, potentially increasing emissions, incurring excessive downtime, burning 

additional natural gas during the downtime, and increasing operating costs. Testing ofthe AWFCO system is 

a time-consuming and manpower intensive process. The current testing program has been in place under the 

RCRA permit for over 20 years and has proven to be adequate in detecting problems. This rationale is 

included in the facility's AWFCO Plan. In some cases this testing occurs more frequently depending on how 

often actual AWFCOs occur at the unit. Per the required frequency, incinerator personnel check the 

functionality of AWFCO logic that is part of the incinerator's PLC system to make sure that should process 

conditions deviate from allowable limits, the computer logic will initiate waste feed shutdowns as required. 

This is accomplished by manually simulating process conditions that are outside allowable limits and observing 

and documenting when the control or block valve software logic on the waste feed line begins to initiate valve 

closure. Should actual AWFCOs occur during a given testing period, these are documented by operating 

personnel to satisfy regulatory requirements for system testing. Results ot this testing are documented on a 

separate AWFCO Testing Log and maintained as part of the unit's Operating Record. 

2.9 Air Pollution Control Equipment Maintenance Practices [40 CFR 

§63.1207{f)(1)(iii)(G)J 

2.9.1 Program Overview 

Once equipment is installed and operational, Veolia utilizes an extensive preventative maintenance (PM) 

program to keep equipment operational and prevent breakdowns and failures. Based upon the type of 

equipment and historical operations and maintenance experience, schedules for various inspection and PM 

activities are followed. This includes aspects such as documenting detailed maintenance histories on 

equipment, routine inspection and lubrication programs for high wear equipment and non-destructive testing of 

piping and vessels using techniques like ultrasound to assess integrity. The frequency of these activities 

varies depending upon the equipment, PM activity and the incinerator's shutdown schedule. 

For example, frequent (i.e., weekly) instrument and certain mechanical equipment checks are made for critical 

process items. Lubrication, vibration analysis and other mechanical integrity checks are done at longer 

frequencies like monthly or quarterly. Finally, such items as inspecting refractory brick for wear, are typically 

performed when the entire incinerator is shut down for maintenance. 

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2.9.2 Test Program Preparation Activities 

Prior to testing, instrumentation associated with key parameters of the test were checked, calibrated, cr 

replaced, as appropriate, to ensure proper operation of the instrumehtation during testing (i.e., waste feed 

flowmeters and scales, CEMS, pressure transmitters, thermocouples, stack flowmeters, etc.). 

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Table 2-2 Technical Information Summary on Incinerator No. 3 

Manufacturer Trade Waste Incineration 

Model No. TWI-2000, Series 2 

Type Fixed Hearth, Dual Chamber 

Date of Manufacture 1987 

Dimensions Primary Chamber Secondary Chamber 

External Length 17.5' 17.5' 

External Diameter 9' 9' 

Internal Diameter 7'2" 7'2" 

Cross-sectional area 40.3 square feet 40.3 square feet 

Burners Primary Chamber Burner Secondary Chamber Burner 

Manufacturer North American North American 

Size 12.0 Million Btu/hr 6.0 Million Btu/hr 

Fuel Natural Gas Natural Gas 

Primer Mover Induced Draft Fan 15,000 acfm @ 400°F saturated, 22 in. water column 

2-16 February 2010 

VES018299