# EMISSIONS TEST REPORT BIG BEND POWER STATION FACILITY ID NUMBER 0570039 UNIT #4 MERCURY EMISSIONS SURVEY

Prepared for: Tampa Electric Company P.O. Box 111 Tampa, Florida 33601-0111

Prepared By: Tampa Electric Company Environmental, Health, & Safety Air Services Group

## TABLE OF CONTENTS 1.0 INTRODUCTION 1 2.0 SUMMARIZED DATA 2 3.0 SOURCE DESCRIPTIONS/TEST PROCEDURES 3 4.0 FIGURES TEST LOCATION 5

APPENDIX A DATA ANALYSIS Big Bend Unit 4 10/14/2009 Big Bend Unit 4 10/27/2009 Big Bend Unit 4 05/06/2009 Big Bend Unit 4 06/01/2009 Big Bend Unit 4 06/25/2009 Big Bend Unit 4 07/24/2009 Big Bend Unit 4 07/31/2009 Big Bend Unit 4 09/14/2009

# 1.0 INTRODUCTION During 2008 and 2009, Tampa Electric Company’s Environmental, Health, & Safety Air Services Group performed nu merous Mercury (Hg) sampling/analysis tests as a part of an overall Hg survey at Big Bend Station. This report summarizes the activities at Big Bend Unit #4.

1

### 2 

# 2.0 SUMMARIZED DATA EXECUTIVE SUMMARY Tampa Electric Company

Big Bend Power Station Mercury Testing Program Big Bend Power Station Unit 4 Test Date Test Duration, hrs Test Method  

### Concentration, ug/scm 10/14/2008 27.5 App K 0.59 10/27/2008 70.2 App K 0.29 05/06/2009 (a) 336 App K 0.73 05/06/2009 (b) 336 App K 0.77 06/01/2009 (a) 90.6 App K 0.63 06/01/2009 (b) 90.6 App K 0.60 06/25/2009 (a) 2 Spec 0.92 06/25/2009 (b) 2 30B 0.59 07/24/2009 (a) 168 30B 0.37 07/24/2009 (b) 168 30B 0.49

07/31/2009 283.7 30B 0.84 09/14/2009 4 Spec 1.11

App K refers to 40CFR75 Appendix K – Quality assurance and Operating Procedures for Sorbent Trap Monitoring Systems. Speciated refers to speciated traps, concentration reported is total of KCl and carbon analysis.

# 3.0 SOURCE DESCRIPTIONS/TEST PROCEDURES Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM coordinates East 361.9 North 3075.0. The Boiler No. 4 sampling location consists of a circular stack 24 feet in diameter with four sample ports located 90 degrees apart on the stack circumference. These ports are located downstream of the electrostatic precipitator, the SCR, and the FGD scrubber. The sampling ports were determined to be 3.0 diameters downstream of the transitionductwork and 8.5 diameters upstream of the stack exit. A diagram of the stack sampling location is included in Figure 1 along with other pertinent information on the test site. Boiler No. 4 is serviced by an electrostatic precipitator for the control of flyash emissions, a selective catalytic reduction (SCR) system for control of nitrogen oxides emissions, an ammonia injection system to control sulfur trioxide formation, and a flue gas desulfurization (FGD) system for control of sulfur dioxide emissions. Sampling was conducted using an Apex Instruments XC-6000 EPC Appendix K Sorbent Trap Monitoring Syst em. Sorbent traps were analyzed in-house using an Ohio-Lumex RA – 915+ 

### Zeeman Mercury Spectrometer with a RP-M324 attachment. Details of operations, cali brations, and Quality Assurance/Control activities are presented in the appendices by test date,

3

# 4.0 FIGURES

4FIGURE 1 EXHAUST STAC K 239 FT BIG BEND GENERATING STATION

5 71 FT

SAMPLING PLATFORM
E SP OUTLET UPPER

LOWER ESP OUTLET



## BIG BEND STACK #4

499 FT

260 FT

189 FT 

# N A

B C D

PORT LOCATION PLAN

REVISED 12-26- BOILE R N O 

### 4 TEST LOCATION

STACK DIAMETERS DOWNSTREAM FROM DISTURBANCE = 3.0 STACK DIAMETERS UPSTREAM FROM DISTURBANCE = 10.0 STACK DIAMETER = 24.0 FT. ID. STACK AREA = 65144.065 IN. ID. PORT LENGTH'S = 17 IN.



### 5

## APPENDIX A DATA ANALYSIS

## BIG BEND UNIT 4 10/14/2008

### Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration
ng Area Area/ng Pass/Fail



### 2000 249000 124.500 Pass 

### 1000 140000 140.000 Pass



### 500 65800 131.600 Pass 

### 100 12800 128.000 Pass



### 50 6420 128.400 Pass 

### 10 1200 120.000 Pass Mean (Area/ng): 128.7500 Standard Deviation: 6.7823 Relative Standard Deviation: 5 Pass Inverse of Mean, A: 0.00777



### Area Pass/Fail 

### Blank 4 Pass 

### 500 ngCheck 60400 Pass 

### Unknown QA Trap 99100 Value for unknown is: 1000 ng

Percent Recover y

is: 78 

### % QC has: Failed 

### Appendix K Mercury Analyzer Caibration

Calculated ng

Calculated ng 50 100 

### 29-Oct-08

515 1090 1940



### 782.9 472

0 9.4No Description M, mg C, ng/g Area Maximum Time BIG BEND HG - ST#4, INLET FGD, INLET SCR 1 condition 500NG 1 566 72400 7130 7:46:35 AM 2 BLANK 1 0.0 4 4 7:48:57 AM 3 Std__2000 1 1940 249000 20300 7:51:33 AM 4 Std__1000 1 1090 140000 20000 7:54:12 AM 5 Std__500 1 515 65800 8940 7:56:48 AM 6 Std__100 1 100 12800 1100 7:59:01 AM 7 Std__50 1 50 6420 1310 8:01:13 AM 8 Std__10 1 9.4 1200 179 8:04:02 AM 9 QCS 500 1 472 60400 8640 8:18:03 AM 10 BB 4 INLET FGD-(10/17/08)-23724 SEC 1 1 393 50300 7470 8:25:39 AM 11 SEC 2 1 43 5610 390 8:31:02 AM 12 BB 4 INLET SCR-(10/17/08)-23741 SEC 1 1 308 39400 4530 8:38:56 AM 13 SEC 2 1 15 2040 193 8:42:18 AM 14 BB 4 INLET FGD-(10/16/08)-23344 SEC 1 1 1220 157000 18400 8:48:25 AM 15 SEC 2 1 133 17100 1590 8:53:09 AM 16 SEC 3 1 18 2330 153 8:57:24 AM 17 BB ST#4-(10/14/08)-003312-SEC 1 1 281 36000 4310 9:05:44 AM 18 SEC 2A 1 97 12400 1170 9:10:39 AM 19 SEC 2B 1 17 2230 73 9:15:45 AM 20 SEC 3A - 1000ng SPIKE 1 775 99100 6660 9:19:59 AM 21 SEC 3B 1 7.9 1010 102 9:23:23 AM 22 ICV/CCV 500ng 1 540 69000 9610 9:26:38 AM 23 1Environmental, Health, & Safety A ir Services Group

3312 281 0 114 0 40.6% FAILED #DIV/0!

1000

783 78.3% PASSED 0.395 0 673.268 1 0.59 0.00 0.94 0.059 0.002 18.74 BB#4 - stack 10/(14-22)/2008 10/(14-22)/2008 10/(14-22)/2008 10/(14-22)/2008 BB#4 - stack BB#4 - stack BB#4 - stack lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.
lbs 

## /hr. Sam p le MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sam p le MercuryConcentration © L 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B TRAP ID TRAP ID ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) #DIV/0!

Normalized Total Hg Mass (M*)

## BIG BEND UNIT 3 10/27/2008

### Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration
ng Area Area/ng Pass/Fail



### 2000 295000 147.500 Pass 

### 1000 137000 137.000 Pass



### 500 66600 133.200 Pass 

### 100 14400 144.000 Pass



### 50 7460 149.200 Pass 

### 10 1510 151.000 Pass Mean (Area/ng): 143.650 Standard Deviation: 7.1161 Relative Standard Deviation: 5 Pass Inverse of Mean, A: 0.00696



### Area Pass/Fail 

### Blank -140 Pass 

### 500 ngCheck 77500 Pass 

### Unknown QA Trap 77300 Value for unknown is: 500 ng

Percent Recover y

is: 108 

### % QC has: Passed 

### 538 535

-1 10 

### Appendix K Mercury Analyzer Caibration

Calculated ng

Calculated ng 51 99 

### 18-Dec-08

460 946 2030No Description M, mg C, ng/g Area Maximum Time BB INLET SCR 4 - ST#4 12-18-08 1 CONDITION 500 1 535 77500 7580 8:52:07 AM 2 BLANK 1 3.3 477 28 8:54:56 AM 3 Std__2000 1 2050 295000 23800 8:57:20 AM 4 Std__1000 X 1 801 116000 11200 8:59:31 AM 5 Std__500 1 463 66600 7100 9:02:07 AM 6 Std__100 1 100 14400 1680 9:04:11 AM 7 Std__50 X 1 41 6010 826 9:06:12 AM 8 Std__10 1 10 1510 246 9:08:26 AM 9 Std__1000 1 953 137000 14200 9:21:14 AM 10 Std__50 X 1 36 5280 458 9:29:20 AM 11 Std__50 1 51 7460 759 9:34:36 AM 12 INLET SCR 4 - 21902 SECT 1 1 1530 221000 16100 9:45:34 AM 13 BLANK 1 -1.0 -140 10 11:53:18 AM 14 ICV - 500 1 491 70600 8800 11:56:08 AM 15 INLET SCR 4 - 21902 SECT 2 1 53 7700 535 11:59:48 AM 16 ST #4 - 23637 SECT 1 1 519 74600 9380 12:07:02 PM 17 ST #4 - 23637 SECT 2 1 10.0 1430 91 12:11:44 PM 18 QCS-500X 1 439 63200 9840 12:14:41 PM 19 QCS - 500X 1 446 64200 11000 12:19:34 PM 20 QCS-500 1 538 77300 17800 12:23:14 PM 21 1Environmental, Health, & Safety A ir Services Group

23637 519 0 10 0 1.9% PASSED #DIV/0!

0.529 0 1848.662 1 0.29 0.00 1.12 0.070 0.001

8.73 BB#4 - stack 10/27-11/03-2008 10/27-11/03-2008 10/27-11/03-2008 10/27-11/03-2008 BB#4 - stack BB#4 - stack BB#4 - stack lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.
lbs 

## /hr. Sam p le MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sam p le MercuryConcentration © L 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B TRAP ID TRAP ID ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) #DIV/0!

Normalized Total Hg Mass (M*)

## BIG BEND UNIT 4 05/06/2009

### Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration
ng Area Area/ng Pass/Fail



### 2000 236000 118.000 Pass 

### 1000 126000 126.000 Pass



### 500 65100 130.200 Pass 

### 100 12000 120.000 Pass



### 50 5560 111.200 Pass 

### 10 1240 124.000 Pass Mean (Area/ng): 121.567 Standard Deviation: 6.6746 Relative Standard Deviation: 5 Pass Inverse of Mean, A: 0.00823



### Area Pass/Fail 

### Blank 161 Pass 

### 1.3 10 

### Appendix K Mercury Analyzer Caibration

Calculated ng

Calculated ng 46 99 

### 12-Jun-09

542 1040 1960No Description M, mg C, ng/g Area Maximum Time 1 condition 2000 1 2080 250000 17800 8:12:48 AM 2 BLANK 1 1.3 161 6 8:15:11 AM 3 Std__2000 1 1960 236000 21200 8:17:37 AM 4 Std__1000 1 1040 126000 22600 8:20:06 AM 5 Std__500 X 1 592 71100 8420 8:22:22 AM 6 Std__100 1 99 12000 1300 8:24:30 AM 7 Std__50 1 46 5560 1010 8:26:40 AM 8 Std__10 1 10 1240 119 8:28:46 AM 9 Std__500 1 542 65100 10900 8:38:13 AM 10 Trap #45246(BB#4-14 day) section 1A 1 2350 283000 16500 8:57:13 AM 11 Section 1B 1 1270 153000 9160 9:01:33 AM 12 Section 2A 1 2.8 336 18 9:05:13 AM 13 Section 2B 1 22 2750 183 9:08:54 AM 14 Section 3A 1 13 1620 54 9:17:16 AM 15 Section 3B 1 1.8 214 18 9:21:14 AM 16 Trap #452420(BB#4-14 day) section 1A 1 2350 283000 16400 9:25:52 AM 17 Section 1B 1 1090 132000 6600 9:28:19 AM 18 Section 2A 1 35 4230 223 9:32:23 AM 19 Section 2B 1 9.1 1090 51 9:34:38 AM 20 Section 3A 1 2.5 296 22 9:39:34 AM 21 Section 3B 1 -0.6 -78 3 9:49:39 AM 22 Trap#23710(BB#3-2 day) section 1 1 334 40200 4660 9:55:43 AM 23 Section 2 1 5.3 637 73 9:59:16 AM 24 Trap#23640(BB#3-2 day) section 1 1 319 38300 3010 10:05:22 AM 25 Section 2 1 0.1 8 5 10:08:43 AM 26 CCV 500 X 1 595 71500 11200 10:11:05 AM 27 CCV 500 X 1 627 75300 9300 10:15:01 AM 28 CCV 1000 1 1090 132000 15200 10:18:52 AM 29 Trap#23415(BB#3-4 day) section 1 1 31 3740 252 10:22:52 AM 30 Section 2 1 2.3 274 10 10:25:53 AM 31 Section 3 - 150ng spike 1 223 26800 1680 10:29:26 AM 32 Trap #43326(BB#3-4 day) section 1 1 47 5760 353 10:36:24 AM 33 Section 2 1 10 1260 63 10:41:50 AM 34 Trap#23661(BB#3-3 day) section 1 1 276 33200 2500 10:47:28 AM 35 Section 2 1 1.1 131 7 10:52:11 AM 36 Section 3-150ng spike 1 117 14100 992 10:54:58 AM 37 Trap #22996(BB#3-3 day) section 1 1 202 24300 1410 10:58:30 AM 38 Section 2 1 12 1490 131 11:01:23 AM 39 Trap #45220(BB#4-Ecotherm-4 day) section 1A 1 1140 138000 7720 11:06:45 AM 40 Section 1B 1 31 3800 353 11:09:51 AM 41 Section 2 1 5.6 668 74 11:13:20 AM 42 Section 3 1 0.2 21 5 11:16:08 AM 43 Trap #45250(BB#4-Ecotherm-4 day) section 1A 1 135 16300 1260 11:21:30 AM 44 1Environmental, Health, & Safety A ir Services Group

45246 45242 3620 3440 39.6 46.6 1.1% PASSED 1.4%

3.6596 3.4866 5028.6 4528.43 0.73 0.77 15.52 0.970 0.003 25.29 BB #4 - 14 day 05/(06-20)/2009 05/(06-20)/2009 05/(06-20)/2009 05/(06-20)/2009 BB #4 - 14 day BB #4 - 14 day BB #4 - 14 day lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.
lbs 

## /hr. Sam p le MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sam p le MercuryConcentration © L 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B TRAP ID TRAP ID ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*)

## BIG BEND UNIT 4 06/01/2009

### Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration
ng Area Area/ng Pass/Fail



### 2000 236000 118.000 Pass 

### 1000 126000 126.000 Pass



### 500 65100 130.200 Pass 

### 100 12000 120.000 Pass



### 50 5560 111.200 Pass 

### 10 1240 124.000 Pass Mean (Area/ng): 121.567 Standard Deviation: 6.6746 Relative Standard Deviation: 5 Pass Inverse of Mean, A: 0.00823



### Area Pass/Fail 

### Blank 161 Pass 

### 1.3 10 

### Appendix K Mercury Analyzer Caibration

Calculated ng

Calculated ng 46 99 

### 12-Jun-09

542 1040 1960No Description M, mg C, ng/g Area Maximum Time 1 condition 2000 1 2080 250000 17800 8:12:48 AM 2 BLANK 1 1.3 161 6 8:15:11 AM 3 Std__2000 1 1960 236000 21200 8:17:37 AM 4 Std__1000 1 1040 126000 22600 8:20:06 AM 5 Std__500 X 1 592 71100 8420 8:22:22 AM 6 Std__100 1 99 12000 1300 8:24:30 AM 7 Std__50 1 46 5560 1010 8:26:40 AM 8 Std__10 1 10 1240 119 8:28:46 AM 9 Std__500 1 542 65100 10900 8:38:13 AM 10 Trap #45246(BB#4-14 day) section 1A 1 2350 283000 16500 8:57:13 AM 11 Section 1B 1 1270 153000 9160 9:01:33 AM 12 Section 2A 1 2.8 336 18 9:05:13 AM 13 Section 2B 1 22 2750 183 9:08:54 AM 14 Section 3A 1 13 1620 54 9:17:16 AM 15 Section 3B 1 1.8 214 18 9:21:14 AM 16 Trap #452420(BB#4-14 day) section 1A 1 2350 283000 16400 9:25:52 AM 17 Section 1B 1 1090 132000 6600 9:28:19 AM 18 Section 2A 1 35 4230 223 9:32:23 AM 19 Section 2B 1 9.1 1090 51 9:34:38 AM 20 Section 3A 1 2.5 296 22 9:39:34 AM 21 Section 3B 1 -0.6 -78 3 9:49:39 AM 22 Trap#23710(BB#3-2 day) section 1 1 334 40200 4660 9:55:43 AM 23 Section 2 1 5.3 637 73 9:59:16 AM 24 Trap#23640(BB#3-2 day) section 1 1 319 38300 3010 10:05:22 AM 25 Section 2 1 0.1 8 5 10:08:43 AM 26 CCV 500 X 1 595 71500 11200 10:11:05 AM 27 CCV 500 X 1 627 75300 9300 10:15:01 AM 28 CCV 1000 1 1090 132000 15200 10:18:52 AM 29 Trap#23415(BB#3-4 day) section 1 1 31 3740 252 10:22:52 AM 30 Section 2 1 2.3 274 10 10:25:53 AM 31 Section 3 - 150ng spike 1 223 26800 1680 10:29:26 AM 32 Trap #43326(BB#3-4 day) section 1 1 47 5760 353 10:36:24 AM 33 Section 2 1 10 1260 63 10:41:50 AM 34 Trap#23661(BB#3-3 day) section 1 1 276 33200 2500 10:47:28 AM 35 Section 2 1 1.1 131 7 10:52:11 AM 36 Section 3-150ng spike 1 117 14100 992 10:54:58 AM 37 Trap #22996(BB#3-3 day) section 1 1 202 24300 1410 10:58:30 AM 38 Section 2 1 12 1490 131 11:01:23 AM 39 Trap #45220(BB#4-Ecotherm-4 day) section 1A 1 1140 138000 7720 11:06:45 AM 40 Section 1B 1 31 3800 353 11:09:51 AM 41 Section 2 1 5.6 668 74 11:13:20 AM 42 Section 3 1 0.2 21 5 11:16:08 AM 43 Trap #45250(BB#4-Ecotherm-4 day) section 1A 1 135 16300 1260 11:21:30 AM 44 1Environmental, Health, & Safety A ir Services Group

45220 45250 1171 1152

5.8 28.2 0.5% PASSED 2.4%

1.1768 1.1802 1857.518 1976.016 0.63 0.60 3.67 0.229 0.003 22.18 BB#4-ecotherm-4 day 06/(01-05)/2009 06/(01-05)/2009 06/(01-05)/2009 06/(01-05)/2009 BB#4-ecotherm-4 day BB#4-ecotherm-4 day BB#4-ecotherm-4 day lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.
lbs 

## /hr. Sam p le MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sam p le MercuryConcentration © L 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B TRAP ID TRAP ID ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*)

## BIG BEND UNIT 4 06/25/2009

### Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration
ng Area Area/ng Pass/Fail



### 2000 456000 228.000 Pass 

### 1000 222000 222.000 Pass



### 500 121000 242.000 Pass 

### 100 23800 238.000 Pass



### 50 11000 220.000 Pass 

### 10 2310 231.000 Pass Mean (Area/ng): 230.2 Standard Deviation: 8.6814 Relative Standard Deviation: 4 Pass Inverse of Mean, A: 0.00434



### Area Pass/Fail 

### Blank Pass 

### 500 ngCheck Fail 

### Unknown QA Trap Value for unknown is: ng

Percent Recover y

is: #DIV/0! 

### % QC has: #DIV/0! 10 

### Appendix K Mercury Analyzer Caibration

Calculated ng

Calculated ng 48 104 

### 30-Jun-09

531 974 2000No Description M, mg C, ng/g Area Maximum Time BB#4 - Ecotherm - Speciated - 06/30/09 1 Blank 1 2.5 255 33 12:33:39 PM 2 Conditional 2000 1 1930 195000 18700 12:36:34 PM 3 Std__2000 1 1980 200000 12000 12:38:24 PM 4 Std__1000 1 1030 104000 12500 12:40:49 PM 5 Std__500 1 506 51100 6900 12:42:38 PM 6 Std__100 1 91 9210 1210 12:44:41 PM 7 Std__50 1 47 4780 552 12:46:44 PM 8 Std__10 1 12 1240 105 12:49:02 PM 9 Std__10 1 11 1180 105 12:55:52 PM 10 TRAP# 45250-(BB#4-Ecotherm-4 day) sec1a 1 235 23800 1960 1:04:53 PM 11 Section 1B 1 331 33400 2000 1:06:52 PM 12 Section 1C 1 208 21000 1160 1:08:57 PM 13 Section 1D 1 243 24600 1410 1:10:49 PM 14 Section 2A 1 3.5 353 29 1:17:14 PM 15 Section 2B 1 21 2170 105 1:19:28 PM 16 Section 3A 1 2.0 206 9 1:22:23 PM 17 Section 3B 1 1.7 176 6 1:25:54 PM 18 Trap #43336(BB#4 Speciated 30b)-Section 1 1 13 1370 122 1:31:26 PM 19 Section 2 1 0.2 25 8 1:34:47 PM 20Environmental, Health, & Safety A ir Services Group

34633-sp trap 4.8 0

0 0 0.0% PASSED #DIV/0!

0.0048 0

21.23 1

0.23 0.00 0.03 0.002 0.001

8.42 

### BB#4-speciated-2hr 06/25/2009 06/25/2009 06/25/2009 06/25/2009 BB#4-speciated-2hr BB#4-speciated-2hr BB#4-speciated-2hr lbs 

## /

yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.
lbs 

## /hr. Sam p le MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sam p le MercuryConcentration © L 

### Appendix K Emissions Calculation s

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B TRAP ID TRAP ID ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) #DIV/0!

Normalized Total Hg Mass (M*)Environmental, Health, & Safety A ir Services Group

34633-carbon 43336 - 30b 14 13 0.7 0.2 5.0% PASSED 1.5%

0.0147 0.0132

21.23 22.288

0.69 0.59 0.09 0.005 0.003 23.91 SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*) ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug TRAP ID TRAP ID ng 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B

Sam p le MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sam p le MercuryConcentration © L

lbs 

## /

yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.
lbs 

## /hr. 

### BB#4-speciated-2hr 06/25/2009 06/25/2009 06/25/2009 06/25/2009 BB#4-speciated-2hr BB#4-speciated-2hr BB#4-speciated-2hr

## BIG BEND UNIT 4 07/24/2009

### Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration
ng Area Area/ng Pass/Fail



### 2000 233000 116.500 Pass 

### 1000 112000 112.000 Pass



### 500 54700 109.400 Pass 

### 100 10500 105.000 Pass



### 50 5070 101.400 Pass 

### 10 1240 124.000 Pass Mean (Area/ng): 111.3833 Standard Deviation: 8.1251 Relative Standard Deviation: 7 Pass Inverse of Mean, A: 0.00898



### Area Pass/Fail 

### Blan k 298 Pass 

### 2000 ngCheck 205000 Pass 

### Appendix K Mercury Analyzer Caibration

Calculated ng

Calculated ng 45 94 

### 14-Aug -09

491 1000 2090



### 1840 2.7 11No Description M, mg C, ng/g Area Maximum Time BB#3&4-(08-14-09)

1 condition__2000ng 1 2010 224000 20700 9:36:10 AM 2 BLANK 1 2.7 298 11 9:39:36 AM 3 Std__2000 1 2090 233000 16300 9:41:42 AM 4 Std__1000 1 1000 112000 11900 9:43:41 AM 5 Std__500 1 491 54700 8090 9:45:42 AM 6 Std__100 1 94 10500 962 9:47:40 AM 7 Std__50 1 45 5070 575 9:49:44 AM 8 Std__10 1 11 1240 111 9:51:48 AM 9 Trap#45280(BB4-7 day) sec 1A 1 553 61600 6230 10:24:06 AM 10 Sec 1B 1 1090 122000 9910 10:28:16 AM 11 Sec 1C 1 58 6470 346 10:31:57 AM 12 Sec 2A 1 1.3 140 11 10:34:11 AM 13 Sec 2B 1 1.4 158 7 10:36:59 AM 14 Sec 3A 1 1.3 147 8 10:40:03 AM 15 Sec 3B 1 2.5 279 8 10:42:10 AM 16 Trap#45249(BB4-7 day) sec 1A 1 2160 241000 13800 10:54:33 AM 17 Sec 1B 1 115 12900 1250 10:56:50 AM 18 Sec 1C 1 19 2160 118 10:59:32 AM 19 Sec 2A 1 0.7 80 14 11:01:32 AM 20 Sec 2B 1 6.5 722 57 11:06:06 AM 21 Sec 3A 1 1.4 153 6 11:09:36 AM 22 Sec 3B 1 0.4 41 5 11:11:35 AM 23 CCV 1000ng 1 942 105000 8030 11:13:45 AM 24 Trap#45245(BB4-14 day) sec 1A 1 2520 281000 15900 12:16:36 PM 25 Sec 1B 1 623 69400 6260 12:19:21 PM 26 Sec 2A 1 6.3 704 51 12:23:30 PM 27 Sec 2B 1 14 1650 214 12:26:44 PM 28 Sec 3A 1 1.0 116 7 12:29:33 PM 29 Sec 3B 1 13 1520 67 12:31:46 PM 30 Trap#39335(BB4-14 day) sec1A 1 1880 210000 34500 12:39:48 PM 31 Sec 1B 1 1.9 212 24 12:42:52 PM 32 Sec 1C 1 765 85300 4620 12:46:24 PM 33 Sec 2A 1 13 1500 76 12:48:36 PM 34 Sec 2B 1 -2.2 -240 3 12:50:43 PM 35 Sec 2C 1 11 1250 65 12:53:07 PM 36 Sec 3A - spike 4500ng 1 3400 379000 32100 12:56:01 PM 37 Sec 3B 1 96 10800 855 12:59:27 PM 38 CCV-2000ng 1 1850 207000 30400 1:01:39 PM 39 Trap#45252(BB3-14 day) sec 1A 1 1240 139000 9490 1:46:18 PM 40 Sec 1B 1 50 5580 637 1:49:01 PM 41 Sec 2A 1 7.2 806 54 1:51:12 PM 42 Sec 2B 1 6.6 731 55 1:54:09 PM 43 Sec 3A 1 -0.1 -8 5 1:56:49 PM 44 Sec 3B 1 0.6 66 8 1:58:47 PM 45 Trap#45016(BB3-14 day) sec 1A 1 1280 143000 9040 2:06:56 PM 46 Sec 1B 1 94 10500 1710 2:09:39 PM47 Sec 1C 1 35 3960 198 2:12:13 PM 48 Sec 2A 1 -0.8 -92 7 2:14:29 PM 49 Sec 2B 1 3.6 396 22 2:16:25 PM 50 Sec 3A - spiked 4500ng 1 3170 354000 28300 2:19:26 PM 51 Sec 3B 1 337 37600 3750 2:21:24 PM 52 QCS - 2000ng 1 1690 189000 19000 2:23:42 PM 53 QCS - 2000ng 1 1680 188000 25500 2:27:24 PM 54 Std__2000ng 1 1730 193000 26300 2:31:18 PM 55 Std__2000ng 1 1840 205000 28000 2:35:21 PM 56 1Environmental, Health, & Safety A ir Services Group

45280 45249 1701 2294

6.5 9 0.4% PASSED 0.4%

1.7075 2.303 4590.708 4728.922 0.37 0.49 5.18 0.323 0.002 16.87 SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*) ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug TRAP ID TRAP ID ng 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B

Sam p le MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sam p le MercuryConcentration © L

lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.
lbs 

## /hr. BB#4 - 7 day 07/(24-31)/09 07/(24-31)/09 07/(24-31)/09 07/(24-31)/09 BB#4 - 7 day BB#4 - 7 day BB#4 - 7 day

## BIG BEND UNIT 4 07/31/2009

### Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration
ng Area Area/ng Pass/Fail



### 2000 233000 116.500 Pass 

### 1000 112000 112.000 Pass



### 500 54700 109.400 Pass 

### 100 10500 105.000 Pass



### 50 5070 101.400 Pass 

### 10 1240 124.000 Pass Mean (Area/ng): 111.3833 Standard Deviation: 8.1251 Relative Standard Deviation: 7 Pass Inverse of Mean, A: 0.00898



### Area Pass/Fail 

### Blan k 298 Pass 

### 2000 ngCheck 205000 Pass 

### Appendix K Mercury Analyzer Caibration

Calculated ng

Calculated ng 45 94 

### 14-Aug -09

491 1000 2090



### 1840 2.7 11No Description M, mg C, ng/g Area Maximum Time BB#3&4-(08-14-09)

1 condition__2000ng 1 2010 224000 20700 9:36:10 AM 2 BLANK 1 2.7 298 11 9:39:36 AM 3 Std__2000 1 2090 233000 16300 9:41:42 AM 4 Std__1000 1 1000 112000 11900 9:43:41 AM 5 Std__500 1 491 54700 8090 9:45:42 AM 6 Std__100 1 94 10500 962 9:47:40 AM 7 Std__50 1 45 5070 575 9:49:44 AM 8 Std__10 1 11 1240 111 9:51:48 AM 9 Trap#45280(BB4-7 day) sec 1A 1 553 61600 6230 10:24:06 AM 10 Sec 1B 1 1090 122000 9910 10:28:16 AM 11 Sec 1C 1 58 6470 346 10:31:57 AM 12 Sec 2A 1 1.3 140 11 10:34:11 AM 13 Sec 2B 1 1.4 158 7 10:36:59 AM 14 Sec 3A 1 1.3 147 8 10:40:03 AM 15 Sec 3B 1 2.5 279 8 10:42:10 AM 16 Trap#45249(BB4-7 day) sec 1A 1 2160 241000 13800 10:54:33 AM 17 Sec 1B 1 115 12900 1250 10:56:50 AM 18 Sec 1C 1 19 2160 118 10:59:32 AM 19 Sec 2A 1 0.7 80 14 11:01:32 AM 20 Sec 2B 1 6.5 722 57 11:06:06 AM 21 Sec 3A 1 1.4 153 6 11:09:36 AM 22 Sec 3B 1 0.4 41 5 11:11:35 AM 23 CCV 1000ng 1 942 105000 8030 11:13:45 AM 24 Trap#45245(BB4-14 day) sec 1A 1 2520 281000 15900 12:16:36 PM 25 Sec 1B 1 623 69400 6260 12:19:21 PM 26 Sec 2A 1 6.3 704 51 12:23:30 PM 27 Sec 2B 1 14 1650 214 12:26:44 PM 28 Sec 3A 1 1.0 116 7 12:29:33 PM 29 Sec 3B 1 13 1520 67 12:31:46 PM 30 Trap#39335(BB4-14 day) sec1A 1 1880 210000 34500 12:39:48 PM 31 Sec 1B 1 1.9 212 24 12:42:52 PM 32 Sec 1C 1 765 85300 4620 12:46:24 PM 33 Sec 2A 1 13 1500 76 12:48:36 PM 34 Sec 2B 1 -2.2 -240 3 12:50:43 PM 35 Sec 2C 1 11 1250 65 12:53:07 PM 36 Sec 3A - spike 4500ng 1 3400 379000 32100 12:56:01 PM 37 Sec 3B 1 96 10800 855 12:59:27 PM 38 CCV-2000ng 1 1850 207000 30400 1:01:39 PM 39 Trap#45252(BB3-14 day) sec 1A 1 1240 139000 9490 1:46:18 PM 40 Sec 1B 1 50 5580 637 1:49:01 PM 41 Sec 2A 1 7.2 806 54 1:51:12 PM 42 Sec 2B 1 6.6 731 55 1:54:09 PM 43 Sec 3A 1 -0.1 -8 5 1:56:49 PM 44 Sec 3B 1 0.6 66 8 1:58:47 PM 45 Trap#45016(BB3-14 day) sec 1A 1 1280 143000 9040 2:06:56 PM 46 Sec 1B 1 94 10500 1710 2:09:39 PM47 Sec 1C 1 35 3960 198 2:12:13 PM 48 Sec 2A 1 -0.8 -92 7 2:14:29 PM 49 Sec 2B 1 3.6 396 22 2:16:25 PM 50 Sec 3A - spiked 4500ng 1 3170 354000 28300 2:19:26 PM 51 Sec 3B 1 337 37600 3750 2:21:24 PM 52 QCS - 2000ng 1 1690 189000 19000 2:23:42 PM 53 QCS - 2000ng 1 1680 188000 25500 2:27:24 PM 54 Std__2000ng 1 1730 193000 26300 2:31:18 PM 55 Std__2000ng 1 1840 205000 28000 2:35:21 PM 56 1Environmental, Health, & Safety A ir Services Group

45245 39335 3143 2646.9 34.3 24 1.1% PASSED 0.9% 4500 3496 77.7% PASSED 3.1773 2.6709 3791.824 3993.627 0.84 0.67 15.59 0.974 0.003 30.08 SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*) ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug TRAP ID TRAP ID ng 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B

Sam p le MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sam p le MercuryConcentration © L

lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.
lbs 

## /hr. BB#4 - 14 day 07/31/09 - 08/12/09 07/31/09 - 08/12/09 07/31/09 - 08/12/09 07/31/09 - 08/12/09 BB#4 - 14 day BB#4 - 14 day BB#4 - 14 dayEnvironmental, Health, & Safety A ir Services Group

45245 39335 3143 2646.9 34.3 24 1.1% PASSED 0.9% 4500 3496 77.7% PASSED 3.1773 2.6709 3791.824 3993.627 0.84 0.67 15.59 0.974 0.003 30.08 SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*) ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug TRAP ID TRAP ID ng 

### Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng 

### SAMPLE A SAMPLE B

Sam p le MercuryConcentration ©

lbs. ug

## / scm ug

## / scm Sam p le MercuryConcentration © L

lbs 

## / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.
lbs 

## /hr. BB#4 - 14 day 07/31/09 - 08/12/09 07/31/09 - 08/12/09 07/31/09 - 08/12/09 07/31/09 - 08/12/09 BB#4 - 14 day BB#4 - 14 day BB#4 - 14 day

## BIG BEND UNIT 4 09/14/2009

### Ohio Lumex Zeeman Mercur y

Spectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration
ng Area Area/ng Cal. ng Pass/Fail



### 2000 438000 219.000 1820 Pass 

### 1000 236000 236.000 981 Pass



### 500 117000 234.000 486 Pass 

### 100 24600 246.000 102 Pass



### 50 13000 260.000 54 Pass 

### 10 2460 246.000 10 Pass Mean (Area/ng): 240.1667 Standard Deviation: 13.8912 Relative Standard Deviation: 6 Pass Inverse of Mean, A: 0.00416 

### r2 

### 0.99928 PASS



### Area Pass/Fail 

### Blank 276 Pass 

### 500 ngCheck Fail 

### Unknown QA TrapValue for unknown is: ng Percent Recover y

is: #DIV/0! 

### % QC has: #DIV/0!

### 1.1 Appendix K Mercury Analyzer Caibration

Calculated ng 15-Oct-09No Description M, mg C, ng/g Area Maximum Time BB-ST#1-2,3,4-(10-15-09)

1 condition 2000ng 1 2210 532000 37400 8:27:12 AM 2 BLANK 1 1.1 276 9 8:30:53 AM 3 Std__1000 1 1200 290000 18800 8:34:19 AM 4 Std__2000 1 1820 438000 39100 8:37:22 AM 5 Std__500 1 486 117000 8880 8:40:20 AM 6 Std__100 1 102 24600 1670 8:43:08 AM 7 Std__50 1 54 13000 917 8:46:29 AM 8 Std__10 1 10 2460 155 8:49:49 AM 9 Std__1000 1 981 236000 18200 8:59:19 AM 10 TrapB #54400-BB(stk#4)-7day-sec1 1 2000 483000 27600 9:21:18 AM 11 SEC 2 1 40 9840 422 9:26:01 AM 12 TrapA #54480-BB(stk#4)-7 day-sec1 1 1850 445000 32100 9:31:27 AM 13 SEC 2 1 37 9080 296 9:34:35 AM 14 TrapA #54482-BB(stk#3)-7 day-sec1 1 886 213000 14500 9:42:59 AM 15 SEC 2 1 15 3820 176 9:46:52 AM 16 TrapB #54479-BB(stk#3)-7 day-sec1 1 1080 261000 15200 9:54:12 AM 17 SEC 2 1 4.4 1050 37 9:57:33 AM 18 CCV-1000ng 1 985 237000 22100 10:00:50 AM 19 TrapB #001446-BB(stk#3)-spec 1 168 40600 2160 10:10:44 AM 20 TrapA #34705-BB(stk#3)-spec-sec1-kcl 1 7.3 1750 100 10:21:52 AM 21 SEC 2-kcl 1 0.2 59 11 10:25:28 AM 22 SEC 3-carbon 1 14 3400 206 10:29:07 AM 23 SEC 4-carbon 1 2.0 474 18 10:32:44 AM 24 TrapB #001430-BB(stk#4)-spec 1 0.8 190 10 10:47:31 AM 25 TrapA #34618-BB(stk#4)-spec-sec1-kcl 1 4.0 956 18 11:02:14 AM 26 SEC 1B-kcl 1 16 3960 79 11:05:29 AM 27 CCV-100ng 1 97 23500 1290 11:13:43 AM 28 SEC 2-kcl 1 0.4 99 9 11:26:43 AM 29 SEC 3-carbon 1 37 8930 619 11:31:20 AM 30 SEC 4-carbon 1 0.7 170 7 11:34:42 AM 31 CCV-100ng 1 94 22600 1140 12:38:16 PM 32 TrapB #54451-BB(cs01w)-spec-sec1-(09-14-09) 1 736 177000 10800 12:51:29 PM 33 SEC 2 1 13 3140 101 12:58:42 PM 34 TrapA #34640-BB(cs01w)-spec-sec2-kcl-(09-14-09) 1 0.6 154 8 1:07:54 PM 35 SEC 1-kcl 1 26 6310 261 1:14:42 PM 36 SEC 3-carbon 1 73 17600 1040 1:18:32 PM 37 SEC 4-carbon 1 2.1 498 27 1:23:30 PM 38 TrapA #45076-BB(cs01w)-sec1a-(09-16-09) 1 50 12200 322 1:34:22 PM 39 SEC 1b 1 32 7930 343 1:39:03 PM 40 SEC 2a 1 1.5 370 13 1:41:34 PM 41 SEC 2b 1 7.9 1910 84 1:44:56 PM 42 SEC 3a-spiked-4500ng 1 3180 765000 31900 1:48:09 PM 43 SEC 3b-spiked-4500ng 1 180 43500 1640 1:51:57 PM 44 CCV-2000ng 1 2030 488000 40000 1:55:30 PM 45 TrapB #45251-BB(cs01w)-sec1a-(09-16-09) 1 219 52700 1910 2:04:05 PM 46 SEC 1b 1 294 70800 2370 2:07:03 PM47 SEC 2a 1 0.0 5 9 2:10:13 PM 48 SEC 2b 1 7.7 1860 107 2:15:04 PM 49 SEC 3a 1 0.9 220 9 2:18:41 PM 50 SEC 3b 1 1.4 348 16 2:21:52 PM 51 TrapA #45219-BB(cs01w)-sec2a-(10-05-09) 1 13 3230 97 2:29:40 PM 52 SEC 2b 1 0.6 142 6 2:32:34 PM 53 SEC 1A 1 17 4100 214 2:36:07 PM 54 SEC 1B 1 295 71000 3400 2:38:55 PM 55 SEC 1C 1 1860 449000 19600 2:42:40 PM 56 TrapB #39349-BB(cs01w)-sec1a-(10-05-09) 1 1640 395000 19300 2:47:38 PM 57 SEC 1b 1 91 22100 1230 2:50:30 PM 58 SEC 2a 1 0.8 199 16 2:55:04 PM 59 SEC 2b 1 0.5 117 13 2:57:38 PM 60 SEC 3a-spiked-4500ng 1 2600 626000 37400 3:00:54 PM 61 SEC 3b-spiked-4500ng 1 682 164000 6340 3:04:02 PM 62 QCS-2000ng 1 1970 475000 26900 3:07:06 PM 63 1Environmental, Health, & Safety A ir Services Group

34618-carbon 1430-carbon 37 0.8 0.7 1.9% PASSED 0.0%

0.0377 0.0008

52.56 55.769

0.72 0.01 0.20 0.012 0.003 27.09

34618-kcl 20 0 0.4 0 2.0% PASSED #DIV/0!

0.0204 0

52.56 0.1

0.39 0.00 0.11 0.007 0.002 14.66 SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*) ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug TRAP ID TRAP ID ng Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng SAMPLE A SAMPLE B

Sam p le MercuryConcentration ©

lbs. ug

### / scm ug

### / scm Sam p le MercuryConcentration © L

lbs 

### / yr. Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data Calculated Mass Emission Data oz.
lbs



### /hr. BB#4 - speciated 09/14/2009 09/14/2009 09/14/2009 09/14/2009 BB#4 - speciated BB#4 - speciated BB#4 - speciated

TRAP ID Appendix K Emissions Calculations SAMPLE A SAMPLE B

SECTION 1 HG MASS (M1) ng SECTION 1 HG MASS (M1) ng TRAP ID

SECTION 2 Breakthrough (%B) SECTION 2 Breakthrough (%B) #DIV/0! SECTION 2 HG MASS (M2) ng SECTION 2 HG MASS (M2) ng

SECTION 3 Spike Value (Ms) ng SECTION 3 Spike Recovery (M3) ng SECTION 3 Spike Recovery (M3) ng SECTION 3 Spike Value (Ms) ng

SECTION 3 Recovery Percentage (%R) SECTION 3 Recovery Percentage (%R) Normalized Total Hg Mass (M*) ug Normalized Total Hg Mass (M*) ug Total Sample Volume (Vt) L Total Sample Volume (VT) L ug

### / scm

BB#4 - speciated 09/14/2009 Calculated Mass Emission Data Sam p le MercuryConcentration © ug

### / scm Sam p le MercuryConcentration © 09/14/2009 Calculated Mass Emission Data oz. lbs. BB#4 - speciated 09/14/2009 Calculated Mass Emission Data lbs 

### /hr. BB#4 - speciated

BB#4 - speciated 09/14/2009 Calculated Mass Emission Data lbs 

### / yr.