From: Keith Barnett/RTP/USEPA/US                                                              

To: Cortney_Higgins@omb.eop.gov                                                            

Date: 07/31/2010 10:54 PM                                                                    

Subject:  

Fw: EPA Organic HAP Data for Alternate THC Limit                                             

Dear Courtney:

This isn't the official docket entry but I think you had asked for this.

Keith W. Barnett

USEPA/OAQPS/SPPD/MMG

Mail Code D243‐02

Research Triangle Park, NC  27711

919‐541‐5605

barnett.keith@epa.gov

Forwarded by Keith Barnett/RTP/USEPA/US on 07/31/2010 10:53 PM

From:       Keith Barnett/RTP/USEPA/US                                                       

To:        "Willis James" <jwillis@titanamerica.com>                                        

Date:    01/25/2010 02:24 PM                                                              

Subject: RE: EPA Organic HAP Data for Alternate THC Limit                                 

(See attached file: II‐B‐016.pdf)This is form the old docket

This is from the 2007 ICR data.

(See attached file: OrganicHAP 092908.xls) Keith W. Barnett USEPA/OAQPS/SPPD/MMG

Mail Code D243‐02 Research Triangle Park, NC  27711

919‐541‐5605

barnett.keith@epa.gov

From:       "Willis James" <jwillis@titanamerica.com>                                        

To:     Keith Barnett/RTP/USEPA/US@EPA                                                   

Date:    01/25/2010 01:09 PM                                                              

Subject: RE: EPA Organic HAP Data for Alternate THC Limit                                 

Keith:

Are you able to point me in the right direction for this data?

Thanks

Jay
From: Willis James

Sent: Thursday, January 21, 2010 4:33 PM

amail.epa.gov

e THC Limit

ying to find the organic HAPs data that the EPA used in setting the

ternate THC limit. We have not been able to find on the Docket.

lis

mes S. Willis, III, P.E., P.G.

rporate Engineering Environmental Manager Titan America, LLC

34

To: Barnett.Keith@ep

Subject: EPA Organic HAP Data for Alternat

Keith

I am tr

al

Is this something you have that you can share.

Thanks

Jay

Jay Wil

Ja

Co

6071 Catawba Road

Troutville, Virginia 24175

Office: (540) 966‐65

Fax: (540) 966‐6812

Mobile: (540) 892‐9983

jwillis@titanamerica.com

nfidentiality Notice:

les attached to it, may contain confidential information

at is intended only for use of the Addressee(s) names above.

n in reliance

age

Co

This message including fi

th

If you are not an intended recipient any dissemination or copying of the

information contained in this message or the taking of any actio

upon the information, is strictly prohibited.  If you have received this mess

in error, please notify the sender immediately by return Email or by phone and

delete the original transmission and any attachments without reading or saving in

any manner.

Thank you.









9/29/2008 

O

Company Location Kiln Kiln Type Raw Mill

Averag(as propppm @

e THC 

ane), 

 7% O2

Formalhyde, ppmvd%O2

de

@7

Bepp%O

nzene, 

mvd@7

2

Toluenppmvd%O2

e, @7

Etbepp%O

hyl 

nzene, mvd@7

2

m,pXyleneppmvd%O2

, 

@7

Stpp%

Ash Grove Cement Montana City, MT 1 wet no 0.41 ND 0.06 ND ND ND ND 

Ash Grove Cement Midlothian, TX 3 wet no 13.83

Ash Grove Cement Leamington, UT 1 preheater/calciner yes 14.14

Ash Grove Cement Seattle, WA 1 preheater/calciner yes 14.23 2.78 0.13 0.05 

Ash Grove Cement Inkom, ID 2 wet no 20.50

Ash Grove Cement Inkom, ID 1 wet no ND 0.16 0.15 ND ND N

Ash Grove Cement Durkee, OR 1 preheater/calciner yes 30.84 15.54 0.21 0.09 0.25 

Ash Grove Cement (new) Durkee, OR 1 preheater/calciner yes 3.72 0.29 0.23 0.1 0.28 

Holcim Trident Kiln #1 wet no 5.56Holcim Mason City Kiln #3 long dry no 6.78

Holcim Mason City Kiln #2 long dry no 11.07

Holcim Artesia, MS wet no 18.35

Holcim Theodore, AL Kiln #1 preheater/calciner no 23.74Holcim Holly Hill, SC preheater/calciner yes 28.48Holcim Portland, CO Kiln #4 preheater/calciner yes 44.97Holcim Midlothian, TX Kiln #1 preheater/calciner yes 51.59

Holcim Devil's Slide, UT Kiln #1 preheater/calciner yes 51.91Holcim Midlothian, TX Kiln #2 preheater/calciner yes 62.82

Holcim Clarksville, M 121.01

Holcim Dundee Kiln #1 and wet no 748.15

Lafarge Whitehall, PA Kiln 2 preheater no 8.33

Lafarge Whitehall, PA Kiln 3 preheater no 10.81

Lafarge Ravena, NY 1 wet no 25.26

Lafarge Ravena, NY 2 wet no 25.26

Lehigh Evansville, PA Kiln2 preheater/calciner no 1.69

Lehigh York, PA White Cem wet no 1.74Lehigh Evansville, PA Kiln1 preheater/calciner no 2.18

Lehigh Union Bridge E02-001 preheater/calciner yes 6.83

Lehigh Redding, CA 1 preheater yes 13.62

Lehigh Waco, TX 39 wet no 18.97

Lehigh Mitchell, IN 1 preheater no 49.09

Lehigh Mitchell, IN 2 preheater no 49.09

Lehigh Mason City 8 preheater/calciner yes 50.53

Lone Star Industries Oglesby, IL 3 long dry no 2.25Lone Star Industries Maryneal 3 preheater no 30.16

Lone Star Industries Pryor 3 long dry no 125.24

Lone Star Industries Pryor 2 long dry no 149.75

Lone Star Industries Pryor 1 long dry no 173.83

TXI Midlothian Kiln E2-22 preheater/calciner 3.96

Lehigh Glen Falls, NY 1 PH/PC yes 3.29 

Lafarge Tulsa 2 long dry no 0.04 

Lafarge Tulsa 1 long dry no 0.02 

California PC Colton 1 long dry no 3.53 0.71 0.3 ND ND ND 

California PC Colton 1 long dry no 1.47 0.3 0.05 ND ND ND California PC Colton 2 long dry no 1.22 0.46 0.06 ND ND ND 

Lafarge Davenport, IA 1 preheater/calciner 0.15 Lafarge Sugar Creek, MO 3 preheater/calciner yes 5.57 0.59 0.4 0.35 0.98 

Lehigh Leeds, AL 5 preheater 6.8 

Test data in other unitsLafarge Ravena 1&2 wet no 55.2 

OrganicHAP 092908.xls 
9/29/08

Organic HAP Test Data 9/26/2008

Plant/Kiln

Lehigh, Glen Falls, NY

Test date 2002

Kiln ID Kiln 1

Kiln type PC

RM On

Moisture, fraction 0.17

%O2 11

Formaldehyde ppmw 2.9

Formaldehyde ppmvd@7%O2 3.38

Acetaldehyde, acrylonitrile, hexane, phenol ND

RM Off

Moisture, fraction 0.19

%O2 6.73

Formaldehyde ppmw 3

Formaldehyde ppmvd@7%O2 2.39

Acetaldehyde, acrylonitrile, hexane, phenol ND

Total

Formaldehyde, Wtd avg, ppmvd@7%O2 3.29

Formaldehyde, Wtd avg, tpy 0.95

Total organic HAP 3.29

Lehigh, Glen Falls, NY

Test date 2006

Kiln ID Kiln 1

Kiln type PC

RM On

%O2 11

Moisture, fraction 0.139

NMHC ppm@7% O2 pp @ 2.5

NMHC ppmvd@7% O2 2.15

NMHC lbs/hr 0.98

RM Off

%O2 5.90

Moisture, fraction 0.2006

NMHC ppm@7% O2 3.5

NMHC ppmvd@7% O2 2.80

NMHC lbs/hr 1.53

Total

NMHC Wtd Avg RM on/off, ppmvd@7%O2 2.22

NMHC Wtd Avg RM on/off, tpy 4.10

Page 2 OrganicHAP 092908.xls
9/29/08

Lafarge, Tulsa

Test date 2002

Kiln ID Kiln 2

Kiln type Dry

Moisture, fraction 0.1371

Formaldehyde, ppm@7%O2 0.051

Formaldehyde, ppmvd@7%O2 0.04

Formaldehyde, tpy 0.048

Kiln ID Kiln 1

Kiln type Dry

Moisture, fraction 0.1292

Formaldehyde, ppm@7%O2 0.027

Formaldehyde, ppmvd@7%O2 0.02

Formaldehyde, tpy 0.028

California PC, Colton

Test date 2002

Kiln ID Kiln 1

Kiln type Dry

Moisture, fraction 0.04

%O2 13.43

Formaldehyde, ppmw 1.97

Formaldehyde, ppmvd@7%O2 3.53

Formaldehyde, tpy 4.56

Benzene, ppmvd 0.38

Benzene, ppmvd@7%O2 0.71

Benzene, tpy 2.19

Toluene, ppmvd 0.16

Toluene, ppmvd@7%O2 0.30

Toluene, tpy 1.11

Acetaldehyde, phenol, hexane, ethyl benzene, m,p,o-xylene, styrene y , p , , y , ,p, y , y ND

Total organic HAP, ppmvd@7%O2 4.53

California PC, Colton

Test date 2005

Kiln ID Kiln1

Kiln type Dry

Moisture, fraction 0.06

%O2 12

Formaldehyde, ppmvw 1

Formaldehyde, ppmvd@7%O2 1.47

Formaldehyde, tpy 2.4

Benzene, ppmvd 0.19

Benzene, ppmvd@7%O2 0.30

Benzene, tpy 1.11

Toluene, ppmvd 0.03

Toluene, ppmvd@7%O2 0.05

Toluene, tpy 0.21

Acetaldehyde, phenol, hexane, ethyl benzene, m,p,o-xylene, styrene ND

Total organic HAP, ppmvd@7%O2 1.81

Page 3 OrganicHAP 092908.xls
9/29/08

California PC, Colton

Test date 2005

Kiln ID Kiln 2

Kiln type Dry

Moisture, fraction 0.04

%O2 14

Formaldehyde, ppmvw 0.63

Formaldehyde, ppmvd@7%O2 1.22

Formaldehyde, tpy 1.54

Benzene, ppmvd 0.23

Benzene, ppmvd@7%O2 0.46

Benzene, tpy 1.42

Toluene, ppmvd 0.03

Toluene, ppmvd@7%O2 0.06

Toluene, tpy 0.19

Acetaldehyde, phenol, hexane, ethyl benzene, m,p,o-xylene, styrene ND

Total organic HAP, ppmvd@7%O2 1.74

Ash Grove, Seattle

Test date 2001

Kiln ID Kiln 1

Kiln type PC

RM On

Moisture, fraction 0.132

%O2 9.52

Benzene, ppmvd 0.1

Benzene, ppmvd@7%O2 0.12

Benzene, tpy 0.55

Toluene, ppmvd 0.04

Toluene, ppmvd@7%O2 0.05

Toluene, tpy 0.26

Formaldehyde, ppmvw y , pp 2.3

Formaldehyde, ppmvd@7%O2 2.44

Formaldehyde, tpy 5.63

Ethyl benzene,mp-xlyene, styrene ND

RM Off

Moisture, fraction 0.073

%O2 8.73

Benzene, ppmvd 0.21

Benzene, ppmvd@7%O2 0.24

Toluene, ppmvd 0.08

Toluene, ppmvd@7%O2 0.09

Formaldehyde, ppmvw 5.5

Formaldehyde, ppmvd@7%O2 5.82

Total

Benzene, Wtd avg, ppmvd@7%O2 0.13

Toluene, Wtd avg, ppmvd@7%O2 0.05

Formaldehyde, Wtd avg, ppmvd@7%O2 2.78

Total organic HAP, ppmvd@7%O2 2.96

Page 4 OrganicHAP 092908.xls
9/29/08

Ash Grove, Montana City, MT

Test date 2000

Kiln ID Kiln 1

Kiln type Wet

%O2 (not reported. Used avg of 3 other wet kilns) 5.86

Benzene, ppmvd 0.06

Benzene, ppmvd@7%O2 0.06

Toluene, phenol, formaldehyde, naphthalene, hexane, ethyl 

benzene, m,p,o-xylene, styrene ND

Ash Grove, Durkee, OR

Date July 2001

Kiln Kiln

Kiln type PC

RM On

Moisture, fraction 0.1768

%O2 6.03

Benzene, ppmvd 0.22

Benzene, ppmvd@7%O2 0.21

Toluene,ppmvd 0.1

Toluene,ppmvd@7%O2 0.09

m,p-Xylene, ppmvd 0.27

m,p-Xylene, ppmvd@7%O2 0.25

Styrene, ppmvd 0.26

Styrene, ppmvd@7%O2 0.24

Formaldehyde, ppmvw 20.2

Formaldehyde, ppmvw@7%O2 15.54

Phenol, naphthalene ND

Total organic HAP, ppmvd@7%O2 16.34

Ash Grove, Durkee, OR

Date April 2002

Kiln Kiln 1

Kiln type PC

RM On

Moisture, fraction 0.116266667

%O2 7.7

Benzene, ppmvd 0.22

Benzene, ppmvd@7%O2 0.23

Toluene, ppmvd 0.1

Toluene, ppmvd@7%O2 0.11

m,p-Xylenes, ppmvd 0.27

m,p-Xylenes, ppmvd@7%O2 0.28

Styrene, ppmvd 0.26

Styrene, ppmvd@7%O2 0.27

Formaldehyde, ppmvw 0.3

Formaldehyde, ppmvd@7%O2 0.28

Naphthalene, ppmvd 0.002

Naphthalene, ppmvd@7%O2 0.002

THC(M25A), ppmvd as propane 3.6

THC, ppmvd@7%O2 3.8

Volumetric flow rate

dscfm 147929

wscfm 167391

Page 5 OrganicHAP 092908.xls
9/29/08

RM Off

Moisture, fraction 0.1368

%O2 5.93

Benzene, ppmvd 0.22

Benzene, ppmvd@7%O2 0.20

Toluene, ppmvd 0.1

Toluene, ppmvd@7%O2 0.09

m,p-Xylenes, ppmvd 0.27

m,p-Xylenes, ppmvd@7%O2 0.25

Styrene, ppmvd 0.26

Styrene, ppmvd@7%O2 0.24

Formaldehyde, ppmvw 0.5

Formaldehyde, ppmvd@7%O2 0.40

Naphthalene, ppmvd 0.008

Naphthalene, ppmvd@7%O2 0.01

THC(M25A), ppmvd as propane 3.3

THC, ppmvd@7%O2 3.1

Volumetric flow rate

dscfm 125600

wscfm 145505

Total

Benzene, Wtd avg, ppmvd@7%O2 0.23

Toluene, Wtd avg, ppmvd@7%O2 0.10

m,p-Xylenes, Wtd avg, ppmvd@7%O2 0.28

Styrene, Wtd avg, ppmvd@7%O2 0.27

Formaldehyde, Wtd avg, ppmvd@7%O2 0.29

Naphthalene, Wtd avg, ppmvd@7%O2 0.002

Total organic HAP, ppmvd@7%O2 1.18

THC, ppmvd@7%O2 3.72 31.7 HAP% of THC

Ash Grove, Louisville, NE

Date 2005

Kiln Kiln 2

Kiln type PC tpy

Benzene,g/sec, baseline 0.023 0.7

Benzene, g/sec, TDF 0.021 0.7

Page 6 OrganicHAP 092908.xls
9/29/08

Lafarge, Whitehall,PA

Date March 2006

Kiln Kiln 3

Kiln type PH

%O2 5.3

Total THC as methane, ppmvd 64.9

Total THC as propane, ppmvd@7%O2* 19.28

Benzene, ug/dscm@7%O2 143

Benzene, lb/hr 0.0287

Naphthalene, ug/dscm@7%O2 180

Naphthalene, lb/hr 0.0363

Methyl chloride, lb/hr 0.0355

Methyl bromide, lb/hr 0.0255

Acetone, lb/hr 0.00189

Methyl iodine, lb/hr 0.0112

Phenol, lb/hr 0.0517

2-Methylphenol, lb/hr 0.003

3&4-Methylphenol, lb/hr 0.007

Acetophenone, lb/hr 0.004

2-Methylnaphthalene, lb/hr 0.003

Acenaphthylene, lb/hr 0.002

Dibenzofuran, lb/hr 0.003

Diethyl phthalate, lb/hr 0.0004

Bis(2-ethylhexyl)phthalate, lb/hr 0.003

Benzoic acid, lb/hr 0.015

Total org HAP, lb/hr 0.23

*Converted THC methane to THC propane by dividing by 3.

Lafarge, Whitehall,PA

Date Sept 2006

Kiln Kiln 2

Kiln type PH

%O2 3.8

Total NMHC as Methane Total NMHC as Methane [VOC], ppmvd 22.9

Total NMHC as Methane [VOC], ppmvd@7%O2 18.7

Total NMHC as Methane [VOC], lb/hr 3.2

Kiln Kiln 3

Kiln type PH

%O2 5.3

Total NMHC as Methane [VOC], ppmvd 11.4

Total NMHC as Methane [VOC], ppmvd@7%O2 10.2

Total NMHC as Methane [VOC], lb/hr 1.2

Lafarge, Seattle

Date June 2000

Kiln Kiln

Kiln type Wet

Moisture, fraction 0.30

%O2 6.7

Benzene, ug/m3 2417

Benzene, lb/hr 0.726

Page 7 OrganicHAP 092908.xls
9/29/08

Lafarge, Ravena, NY

Date February 2004

Kiln Kiln 1&2, common stack

Kiln type Wet

%O2 6.94

Moisture, fraction 0.286

Naphthalene, mg/M3@7%O2 0.0371

Naphthalene,lb/hr 0.0634

2-Methylnaphthalene, mg/M3@7%O2 0.209

2-Methylnaphthalene, lb/hr 0.291

Phenanthrene, mg/M3@7%O2 0.11

Phenanthrene, lb/hr 0.153

Total org HAP, mg/M3@7%O2 0.3561

Total org.HAP, lb/hr 0.5074

Total NMHC, ppmvd 21.82

Total NMHC, lb/hr 55.2

THC, ppmvd as propane 25.4

THC, ppmvd@7%O2 as propane 25.3

THC, lb/hr as propane 55.2 0.9 HAP% of THC

Lafarge, Davenport IA

Date "March 2000

Kiln Kiln 1

Kiln type PC

Moisture, fraction 0.11

%O2 9.8

Benzene, ppmv 0.15

Benzene, ppm@7%O2 0.17

Benzene, ppmvd@7%O2 0.15

Volumetric flow rate, dscfm 271587

Lafarge, Sugar Creek, MO g , g ,

Date August 2002

Kiln Kiln 3

Kiln type PC

RM On (95% of time) tpy

Moisture, fraction 0.14

%O2 (not reported, used avg. of 6 PC kilns) 9.2

Benzene, ppmvd 0.5 3.12

Benzene, ppmvd@7%O2 0.59

Toluene, ppmvd 0.34 2.46

Toluene, ppmvd@7%O2 0.40

Ethyl benzene, ppmvd 0.3 2.49

Ethyl benzene, ppmvd@7%O2 0.36

m,p-Xylenes, ppmvd 0.71 5.98

m,p-Xylenes, ppmvd@7%O2 0.84

Styrene, ppmvd 0.46 3.8

Styrene, ppmvd@7%O2 0.55

o-Xylene, ppmvd 0.35 2.95

o-Xylene, ppmvd@7%O2 0.41

Formaldehyde, ppmvw 5.4 14.92

Formaldehyde, ppmvd@7%O2 5.51

Volumetric flow rate, dscfm 122537

Volumetric flow rate, wscfm 141940

Page 8 OrganicHAP 092908.xls
9/29/08

RM Off (5% of time) tpy

Moisture, fraction 0.15

%O2 (not reported, used avg of 4 PC kilns) 6.8

Benzene, ppmvd 0.62 0.19

Benzene, ppmvd@7%O2 0.61

Toluene, ppmvd 0.34 0.12

Toluene, ppmvd@7%O2 0.34

Ethyl benzene, ppmvd 0.27 0.11

Ethyl benzene, ppmvd@7%O2 0.27

m,p-Xylenes, ppmvd 3.71 1.54

m,p-Xylenes, ppmvd@7%O2 3.66

Styrene, ppmvd 0.4 0.16

Styrene, ppmvd@7%O2 0.39

o-Xylene, ppmvd 0.3 0.12

o-Xylene, ppmvd@7%O2 0.30

Formaldehyde, ppmvw 8.2 1.13

Formaldehyde, ppmvd@7%O2 6.88

Volumetric flow rate, dscfm 114961

Volumetric flow rate, wscfm 134567

Total tpy

Benzene, ppmvd 0.51 3.31

Benzene, ppmvd@7%O2 0.59

Toluene, ppmvd 0.34 2.58

Toluene, ppmvd@7%O2 0.40

Ethyl benzene, ppmvd 0.30 2.6

Ethyl benzene, ppmvd@7%O2 0.35

m,p-Xylenes, ppmvd 0.86 7.52

m,p-Xylenes, ppmvd@7%O2 0.98

Styrene, ppmvd 0.46 3.96

Styrene, ppmvd@7%O2 0.54

o-Xylene, ppmvd 0.35 3.07

o-Xylene, ppmvd@7%O2 0.41

Formaldehyde, ppmvw y , pp 5.54 16.05

Formaldehyde, ppmvd@7%O2 5.57

Total all organic HAP, ppmd@7%O2 8.85 39.09

Lehigh, Leeds, AL

Date April 2002

Kiln 5

Kiln type PH

Moisture, fraction 0.1313

%O2 14.65

Formaldehyde, ppmvw 3.52 My calculation

Formaldehyde, ppmvd (reported)?? 4.05 3.06

Formaldehyde, ppmvd@7%O2 9.0 6.8

Formaldehyde, lb/hr 3.66

Volumetric flow rate, dscfm 194295

Volumetric flow rate, ascfm 298076

Page 9 OrganicHAP 092908.xls
9/29/08

Ash Grove, Inkom, ID

Date Sept/Oct 2000

Kiln Kiln 1

Kiln type Wet

Moisture, fraction 0.3308

%O2 3.95 tpy

Benzene, ppmvd 0.2 0.26

Benzene, ppmvd@7%O2 0.16

Toluene, ppmvd 0.18 0.27

Toluene, ppmvd@7%O2 0.15

Formaldehyde phenol, naphthalene, hexane, ethyl benzene, m,p,oxylene, styrene ND

Total organic HAP, ppmvd@7%O2 0.31

Volumetric flow rate, dscfm 24604

Volumetric flow rate, wscfm 36777

HAP MW

Formaldehyde 30

Benzene 78

Toluene 92

m,p-Xylene 106

Styrene 104

o-Xylene 106

Hexane 86

Phenol 94

Page 10 OrganicHAP 092908.xls