, II-D-052 A=99=30 

STATESVI-LLE BRICH COM PANY 

~anu aciurers o ine ace ~ rick 

P. O. Box 471 (704) 872-4123 

Statesville, N. C. 28687 

March 12, 1998 

Office of Air Quality & Standards 

Environmental Protection Agency 

Research Triangle Park, N. C. 27711 

Dear Sirs: 

Statesville Brick Company has a high respect for the ecology and 

for the health of people in the county, state and nation. Looking at wood as a fuel and sawdust as a waste, in 1981 we started 

utilizing sawdust as a fuel to burn brick. Thousands of tons of 

sawdust therefore did not go into a landfill or get burned as a 

waste; they went into brick production. It has been proven that 

HF reduction occurs when kiln eshaust passes through a sawdust 

drier. This means that Statesville Brick Company has had 

improved emissions since the adoption of the sawdust fuel. 

In considering the life of brick versus other construction materials 

it must be realized that brick have no equal. Frequently brick 

removed from a demolished building are used to build a new building. 

Also it is understood that functional brick buildings esist in 

Europe that are 1000 years old. 

Statesville Brick Company, with a masimum capacity of 45 million 

brick per year, is a relatively small brick facility. Necessary 

operating parameters do not include the technical personnel and 

sophisticated equipment required to produce the volume of chemical 

analyses and emissions data for this questionaire. Hiring a consulting and environmental firm to do the required testing would be 

an economic disaster for the company. 

We maintain that raw material and sawdust particulates, that are 

emitted and may contain HAPS or be called surrogates, are not HAPS 

because the contained HAPS are an integral or combined part of the 

parent material. 

In an effort to help EPA develop accurate numbers we are only submitting factual data based on tests which has been run at Statesville Brick Company. 

Respectfully, 

, 

J ~ 

t 

~ \-I, ~ C` / ~• `y'l►'W' 

Brad Brown 

Technical Services / 
cr.~' - - 

NOT SOBJ E :' ' : ifi; . _ ; V + 7F 

o

r rAFEd iJ4( dc .7 19d0. 

1 

INFORMATION REQUEST FOR BRICK AND 

STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS 

Instructions 

Please return the completed information request to: 

Bruce C. Jordan, Director 

Attn: Bill Neuffer 

Emission Standards Division (MD-13) 

U. S. Environmental Protection Agency 

Office of Air Quality Planning and Standards 

Research Triangle Park, North Carolina 27711 

If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at 

(919) 541-5435. 

This information request should be completed for each facility that manufactures brick and 

structural clay products, including facilities that are not major sources. Information is 

requested for all processes at your plant that emit hazardous air pollutants (HAP's), 

including those processes that are not associated with brick and structural clay 

products manufacturing. Sections II through VII re.quest information specific to brick 

and structural clay products manufacturing, and Section VIII requests information on 

emissions of HAP's from other processes located at the facility. Processes that may ernit 

HAP's include those processes that use or handle any materials that contain a HAP 

compound, all processes with elevated temperatures, and all other processes in which HAP 

compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is 

included as Attachment 1 to this information request. Attachment 2 provides background 

information on the requirements of the Clean Air Act and explains how the information 

requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations 

and acronyms used in this information request. 

Several tables are provided throughout the information request for your convenience in 

answering the questions. An example response is given (shaded first column or row) in 

each table. If additional space is needed to respond, please make copies of applicable 

pages. If necessary, please make copies of this information request for additional facilities. 

iVo additional emission testing or monitoring is required to respond to this request. 

tI. General FacilitYInformation 

A. Name of company 

Name of facility S a.. m e. 

Page 1 of 28 

~ 
Facility address: L. QG Dv'O, 

No. and street L 

City 5—}-a.'}'e e, StateN L.Zip 24S 4, 71 

Latitude and longitude coordinates of plant: 39' 42. 4q Ai g'/ D?.. 3 s W 

Standard Industrial Classification (SIC) Code(s) of brick and structural clay products 

manufacturing operations .3 A5"I 

Dun and Bradstreet No. D D 32-1 71 yLB 

Total No. of employees for company 7Z for facility $aw« 

(If facility is a foreign subsidiary or if company has foreign subsidiaries, include 

number of employees not based in the U.S.). 

Please complete the following shift information for the facility: 

Shift No. of employees Hours per shift Days per year 

X ~ l~ 36 

F-x z 4- 

B. Respondent name 1-&~ ✓L 

Respondent title 1 r'k V% p.✓ l: r& S 

Respondent address (if different from above) and telephone number: CM a; ~ Itg~ 

No. and street P D 13 " 4-71 

City S s tate &S-- Zip —7.~~~'7 

Telephone No. -70 4 B 7 s"L 

Name and telephone number of technical contact person (if different from above) 

Name Telephone No. (__j 

1II. Information on Operating Permits and Applicable Federal Emission Standards 

A. Please provide copies of relevant parts of all operating permits and permit 

applications for your facility. Relevant parts include the sections that provide 

specific information and data on: processes that emit HAP's; the use of HAPcontaining substances; eniission levels for HAP and surrogate pollutants (i.e., VOC 

Page 2 of 28 

o ✓ , A. S vJ► i ✓~ S f`} `(-p N- l~ i lhi 

~ ~ -3 
for organic HAP's and PM for metal and other particulate HAP's); emission control 

device design and operation; monitoring and operation and maintenance (O&M) 

procedures for control devices; and generation and releases of other media such as 

wastewater and solid waste that are associated with the operation of air pollution 

controls for brick and structural clay products manufacturing processes. 

If the operating permit or application contains the same information requested 

in aay part of this questionnaire, you may respond to the requested information 

by referencing the page or section of the permit/application to avoid 

duplication. If you reference your permit or application, you must supplement your 

response with all of the additional information requested in this questionnaire that is 

not included in the permit or permit application. If you prefer, you may submit the 

requested information from your permit/application on a 3-'/z inch diskette. 

B. If any source or emission unit at this facility is subject to a New Source Performance 

Standard or other Federal emission standard, please identify the source and 

applicable standard. Examples of applicable NSPS include 40 CFR 60, 

Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing 

Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and 

Dryers in Mineral lndustries. 

1~ S 0 u.y'e-,9- S 

W. Brick and Structural Clay Products Production and Raw Material Consumotion 

Information 

A. Please provide the 1996 production rates and the current production capacity for 

each type of brick and structural clay product manufactured (e.g., structural brick, 

clay sewer pipes, structural clay tile, etc.). Note that production data should be 

provided in units of tons per year (tons/yr). 

Product 1996 production (tons) Production capacity (tons/yr) 

~ r: 

r 7 q3 ~. o ~ I `~ 

© , re A, ~rr\ S Page 3 of 28 

4 
B. Please provide the type and amount of each raw material and body additive used in 

1996 for manufacturing brick and structural clay products at your facility. Examples 

include clays, shale, and any additives that are mixed into the raw material prior to 

forming. Indicate additives by chemical compound, rather than by trade name. If the 

information requested is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than providing the information 

below. 

Raw materiaUbody additive Amount used in 1996 (tons/yr) 

D 1S ~ 

S0 AS © 5 

n ~ ~ 

C. If available, please provide a copy of the MSDS's for the raw materials and additives 

listed above. 

D. If available, please provide chemical analyses, including fluorine, metals, and organic 

content, of the raw materials listed above. 

re cc ' uc,S mc4,r,,: c~C af 1 7 7v ✓`Zo ~s f~r~ 

(~ Ml s DS e%~~~s airG C t; vt01. , 

Page 4 of 28 

1;11, 
E. Using Table 1, please provide information on the consumption and HAP 

composition of all glazes and colorants that contain HAP's or HAP precursors and 

that your facility applies to brick and structural clay products. Indicate whether the 

coatings are glazes or colorants. Also indicate the type of product that the coatings 

are applied to and the total weight of coatings used in 1996. If the glazes or 

colorants are formulated at your facility indicate so and provide the production 

capacity. List each ingredient of the glaze or colorant. Beside each ingredient, 

indicate the total amount of the ingredient used in 1996. If the information requested 

in the table is contained in your facility's operating permit or permit application, you 

may reference the applicable sections of the permit (or application) rather than filling 

out the table. 

F. In the space below, please indicate any glazes or colorants used by your facility that 

do not contain HAP's and are substitutes for HAP-containing glazes or colorants 

used by your industry. Indicate which HAP-containing materials the non-HAP 

glazes or colorants replace. Describe any limitations on the use of those substitute 

glazes or colorants. 

G. If your facility colors brick and structural clay products by flashing, please indicate 

the types of substances used to flash the products and the amounts of those 

substances used in 1996. 

Substance N. 

Amount used in 1996 Units (specifyj 

H. If available, please provide a copy of the MSDS's for the glazes and colorants used 

by your facility. If your facility prepares its own glaze, please provide any available 

MSDS's for the glaze ingredients. 

Page S of 28 

I 
TABLE 1. CONSUMPTION AND HAP COMPOSTITON OF GLAZES .AND COLORANT ~ 

I

•- _ • • ; 

Type of product glazed or " 

colored S4v v&d-o&-" I 

II 1996 consumption (tons/yr) 

70 0 

II 

Produced at facility? (yes/no) 

Production capacity (tons/yr) 

Total usage (weight) of each rY1q~•u,., ~~ Total 1996 

ingredient (that is a HAP, Iqgredient usage, tons , 

contains a HAP, or is a HAP 

precursor) in 1996 

R mAo s.L. c © 

I 

If additional space is required, please make copies of this page. If the information requested in 

the table is contained in your facility's operating permit or permit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

V' N D+ Q6 

v •J Page 6 of 28 

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D. Using Table 7, please provide the following information on current monitoring 

procedures for each of the control devices listed in Tables 6A to 61): parameters 

monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices 

used (e.g., differential pressure transducer, thermocouple), and recordkeeping 

practices (e.g., manually recorded in log book, continuously recorded by electronic data 

acquisition system). Describe briefly other operation and maintenance (O&M) 

procedures for each control device. If the information requested in the table is 

contained in your facility's operating permit, you may reference the applicable sections 

of the permit rather than filling out the table. 

VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing 

A. Please describe all pollution prevention practices (i.e., process modifications, such as 

re-use of discarded or rejected materials, or any practice that prevents or reduces the 

amount of air emissions, or the generation and release of solid waste or wastewater 

associated with the operation of air pollution controls). If the information requested 

here is contained in your facility's operating permit, you may reference the applicable 

sections of the permit rather than providing the information below. 

Page 24 of 28 

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:~ ~ 
. . •. . 1 ~ •' • '• • ~ • • 

. annual • . • • d- , . .d • t ons ^er / 

 ~~~iti~' 

~ V '1 . . ~ _ • /~,,[_, S_ .. ~,y., ,' _ . • ; r-~Y •Y' - . .. `- ~S:b)~:.~1~~1.-~~~ '1. _ ~ s...~"'a' - 1~ ~'~ 

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If the information requested in the table is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the table. 

Page 28 of 28 

~~ 
NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION 

DEPARTMENT OF ENVIRONIVIENT, HEALTH, AND NATURAL RESOURCES 

, 

DIVISION OF AIR QUALITY 

'~✓.J 

lssue Date: April 9, 1997 Effective Date: Apri19, 1997 

Expiration Date: March 31, 2002 Replaces Permit: 2493R5 

To construct and operate air emission source(s) and/or air cleaning device(s), and for the 

discharge of the associated air contaminants into the atmosphere. In accordance with the 

provisions of Article 21B of Chapter 143, General Statutes of North Carolina as amended, and 

other applicable Laws, Rules and Regulations, 

Statesville Brick Conipany 

U.S. Highway 64/70 West 

Statesville, Iredell County, North Carolina 

is hereby authorized to construct and operate air emission sources and/or air cleaning devices and 

appurtenances consisting of: 

a. One (1) sawdust/natural gas-fired kiln (ID No. 1; 10.1 tons per hour maximum 

capacity and 30 million Btu per hour heat input), 

b. One (1) simple cyclone (ID No. 2; nine feet in diameter) installed on a sawdust 

fuel dryer (ID No. 3; 3.75 tons per hour maximum drying capacity), and 

C. One (1) shale/clay grinding and screening operation (ID No. 4; 100 tons per hour 

process rate), 

in accordance with the completed appGcation (APP025038) received March 6, 1997, including all 

plans, specifications, previous applications, and other supporting data, all of which are filed with 

the Department of Environment, Health, and Natural Resources and are incorporated as part of 

this Permit. 

This Permit is subject to the following specified conditions and limitations including any 

TESTING, REPORTING, OR MONITORING REQUIREMENTS: 

A. SPECIFIC CONDITIONS AND LIMITATIONS 

1. Any air emissiQn sources or control devices authorized to construct and operate above must 

be operated and maintained in accordance with the provisions contained herein. The 

Permittee shall comply with applicable Environmental Management Commission 

i~ 

~~~ 
Air Permit No. 2493R6 

Page No. 2 

Regiilations, including Title 15A North Carolina Administrative Code (NCAC), 

Subchapter 2D .0515, .0516, .0521, and .0535. 

As required by 15A NCAC 2D .0515 "Particulates from Miscellaneous Industrial 

Processes," particulate emissions from the facility's air emissions sources (ID Nos . 1, 3, 

and 4) shall not exceed allowable emission rates. The allowable emission rates are, as 

defined in 2D .0515, a function of the process weight rate and shall be determined by the 

following equation(s), where P is the process rate in tons per hour (tons/hr) and E is 

allowable emission rate in pounds per hour (lbs/hr). 

P s 30 tons/hr: E= 4.1 (P)o' 6' 

b. P> 30 tons/hr: E= 55 (P) °- 1 `- 40 

As required by 15A NCAC 2D .0521 "Control of Visible Emissions, visible emissions 

from the sawdust/natural gas-fired kiln and the shale/clay grinding operation (ID Nos. 1 

and 4), established after July 1., 1971, shall not be more than 20 percent opacity when 

averaged over a six-minute period, except that six-minute periods averaging not more than 

87 percent opacity may occur not more than once in any hour nor more than four (4) times 

in any 24-hour period. However, sources which must comply with 15A NCAC 2D .0524 

"New Source Performance Standards" or .0525 "National Emission Standards for 

Hazardous Air Pollutants" must comply with applicable visible emissions requirements 

contained therein. 

4. As required by 15A NCAC 2D .0521 "Control of Visible Emissions, visible emissions from 

the sawdust dryer (ID Nos. 3) existing as of July 1, 1971, shall not be more than 40 percent 

opacity when averaged over a six-minute period, except that six-minute periods averaging 

not more than 90 percent opacity may occur not more than once in any hour nor more than 

four (4). times in any 24-hour period. However, sources which must comply with 15A 

NCAC 2D .0524 "New Source Performance Standards" or .0525 "National Emission 

Standards for Hazardous Air Pollutants" must comply with applicable visible emissions 

requirements contained therein. 

As required by 15A NCAC 2D .0516 "Sulfur Dioxide Emissions from Combustion 

Sonrces," sulfiu dioxide emissions from the sawdust/natural gas-fired kiln (ID No. 1) shall 

not exceed 2.3 pounds per million Btu heat input. However, sources which must compl} , 

with 15A NCAC 2D .0524 "New Source Performance Standards" must comply with 

applicable sulftu dioxide emission requirements contained therein. 

The Permittee shall take all reasonable precautions with any operation, process, handling, 

transportation, or storage facilities to prevent fugitive emissions from becoming airborne. 

7. NOTIFICATION REOUIREMENT - As required by 15A NCAC 2D .0535, or for sources 

applicable to 15A NCAC 2D .0524 or .0525, when emissions exceed Environmental 

Management Regulations for more than four (4) hours, the Regional Supervisor, Division 

of Air Quality, shall be notified as promptly as possible, but in no case later than twenty-four 

(24) hours or on the next working day of becoming aware of the occurrence. Such notice 

shall specify the facility name and location, the nature and cause of the excess emission, the 

~~ 
Air Permit No. 2493R6 

I'age No. 3 

time when first observed,.the expected duration, and the estimated rate of emissions. This 

reporting requirement does not allow the operation of the facility in excess of Environmental 

Management Commission Regulations. 

CYCLONE REOUIREMENTS- Particulate matter emissions from the sawdust dryer (ID 

No. 3) shall be controlled by a cyclone (ID No. 2). 

a. Inspection and Maintenance Requirements 

To comply with the provisions of this Permit and ensure that optimum control 

efficiency is maintained, the Permittee shall establish an inspection and maintenance 

schedule/checklist based on manufacturer's recommendations. As a minimum, the 

inspection and maintenance program shall include an annual internal inspection to 

ensure the structural integrity. The results of this inspection and any maintenance 

performed on the cyclone, shall be recorded in a log book. 

b. Record Keeping Requirements 

A cyclone log book which shall be kept on site and made available to Division of Air 

Quality personnel upon request. Any variance from the cyclone ~ manufacturer's 

recommendations shall be investigated with corrections made and date of actions 

recorded in the cyclone log book. 

B. GENERAL CONDITIONS AND LIMITATIONS 

101_ '•-0 N: : 5•\IM VLSI . \ ji ~ : ; \• ~ ; ~ •\. : ~ ~ • 

•: RENFWAL shallbe submitted to 

Regional Supervisor 

North Carolina Division of Air Quality 

919 North Main Street 

Mooresville, North Carolina 28115 

2. PERMIT RENEWAL REQUIREMENT - The Permittee, at least ninety (90) days prior 

to the expiration date of this Permit, shall request permit renewal by letter in accordance 

with 15A NCAC 2Q .0304 (d) and (f). Pursuant to 15A NCAC 2Q .0203 (i), no permit 

application fee is required for renewal of an existing air permit. The renewal request 

should be submitted to the Regional Supervisor, Division of Air Quality. 

3. ANNUAL FEE PAYIVLNT - Pursuant to 15A NCAC 2Q .0203 (a), the Permittee shall 

pay the Annual Permit Fee within thirty (30) days of being billed by the Division. Failure 

to pay the fee in a timely manner will cause the Division to initiate action to revoke the 

permit. 

4. EQUO?MENT RELOCATION - A new air permit shall be obtained by the Permittee prior 

to establishing, building, erecting, using, or operating the emission sources or air cleaning 

equipment at a site or location not specified in this permit. 

,~,_~i 
:~ ir Permit No. 2493R6 

No. 4 

5. REPORTING REOLTIREMENT- Any of the following that would result in previously 

unpermitted, new, or increased emissions must be reported to the Regional Supervisor, 

Division of Air Quality: 

a. Changes in the information submitted in the application regarding facility 

emissions; 

b. Changes that modify equipment or processes of existing permitted facilities; or 

C. Changes in the quantity or quality of materials processed. 

If appropriate, modifications to the permit may then be made by the Division of Air 

Quality to reflect any necessary changes in the permit conditions. In no case are any new 

or increased emissions allowed that will cause a violation of the emission limitations 

specified herein. 

u. This permit is subject to revocation or modification by this Division upon a determination 

that infdrmation contained in the application or presented in the support thereof is 

incorrect, conditions under which this permit was granted have changed, or violations of 

conditions contained in this permit have occurred. The facility shall be properly operated 

and maintained at all times in a manner that will effect an overall reduction in air pollution. 

Unless otherwise specified by this permit, no emission source may be operated without the 

concurrent operation of its associated air cleaning device(s) and appurtenances. 

~ . This permit is nontransferable by the Permittee. Future owners and operators must obtain 

a new air permit from the Division of Air Quality. 

~ . This issuance of this permit in no way absolves the Permittee of liability for any potential 

civil penalties which may be assessed for violations of State law which have occurred prior 

to the effective date of this permit. 

J. This permit does not relieve the Perm.ittee of the responsibility of complying with all 

applicable requirements of any Federal, State, or Local water quality or land quality 

control authority. 

10. Reports on the operation and maintenance of the facility shall be submitted by the 

Permittee to the Regional Supervisor, Division of Air Quality, at such intervals and in such 

of form and detail as may be required in such by the Division. Information required in 

such reports may include, but is not liniited to, process weight rates, firing rates, hours of 

operation, and preventive maintenance schedules. 

11. A violation of any term or condition of this perniit shall subject the Permittee to 

enforcement pursuant to G. S. 143-215.114A, 143-215.114B, and 143-215.114C, 

including assessment of civil and/or criminal penalties. 

01 ~ 
 Air Permit No. 2493R6 

Page No. 5 

12. Pursuant to North Caroli.na General Statute 143-215.3 (a) (2), no person shall refuse entry 

or access to any authorized representative of the Division of Air Quality who requests 

entry or access for purposes of inspection, and who presents appropriate credentials, nor 

shall any person obstruct, hamper, or interfere with any such representative while in the 

process of carrying out his official duties. Refusal of entry or access may constitute 

grounds for permit revocation and assessment of civil penalties. 

13. The Permittee must comply with any applicable Federal, State, or Local requirements 

governing the handling, disposal, or incineration of hazardous, solid, or medical wastes, 

including the Resource Conservation and Recovery Act (RCRA) administered by the 

Division of Waste Management. 

1~ Crmit issued this the 9th day of April, 1997. 

NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION 

Miciael S. Land , Acting Regional Supervisor 

Division of Air Quality 

By Authority of the Environmental Management Commission 

Air Permit No. 2493R6 
MATERIAL SAFETY DATA SOD I UM CARBONATE 4FMC 

497 -19 -8 

U.S./CANADA VERSION EFFECTIVE: 02/13/97 PRINTED: 05/16/97 

PRINTED FOR ............... WORTH CHEMICAL 

2418 E PETTIGREW ST 

ATTN: SAFETY DIRECTOR 

DURHAM NC 27703 

==ssassssaas=asssa=:sas=ss ~ 1. CHEMICAL PRODUCT/COMPANY IDENTIFICATION =asa 

PRODUCT NAME .............: SODIUM CARBONATE, ANHYDROUS 

SYNONYMS .................: SODA ASH, SODIUM CARBONATE ANHYDROUS 

INFORMATION PROVIDED BY..: FMC WYOMING CORPORATION 

1735 MARKET STREET 

PHILADELPHIA. PA19103 

(800) 253-7632 

EMERGENCY PHONE NUMBERS 

CHEMTREC ..............: (800) 424-9300 

MEDICAL ...............: (303) 595-9048 CALL COLLECT 

PLANT/OTHER ........... : (307) 875-2580 CALL COLLECT 

COMPOSITION/INFORMATION ON INGREDIENTS ===== 

CAS * AND COMPONENTS ..... : 497-19-8 SODIUM CARBONATE 99.8% 

oasasa=a=sszassasssssszsss 3. HAZARD IDENTIFICATION sasssssz=assezzaeaszas 

EMERr,ENCY OVERVIEW ....... : WHITE GRANULAR SOLID. PRODUCT IS 

NON-COMBUSTIBLE. REACTS WITH ACIDS TO RELEASE 

CARBON DIOXIDE AND HEAT. IRRITATING TO THE 

EYES. CONTINUOUS CONTACT MAY IRRITATE SKIN. 

HEALTH EFFECTS ........... : DIRECT CONTACT WITH THE PRODUCT CAUSES 

IRRITATION OF THE EYES AND CONTINUOUS CONTACT 

MAY CAUSE SKIN IRRITATION (RED, DRY, CRACKED 

SKIN). 

EXCESSIVE LEVELS OF AIRBORNE DUST MAY IRRITATE 

THE MUCOUS MEMBRANES AND UPPER RESPIRATORY 

TRACT. 

==3==x ~ sazazsss=ssaxssszss 4. FIRST AID MEASURES =ss=saszzszsoss===s=s=saz 

EYES .....................: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 

15 MINUTES, LIFTING THE UPPER AND LOWER LIDS 

OCCASIONALLY. SEE A MEDICAL DOCTOR IMMEDIATELY. 

SKIN .....................: WASH WITH PLENTY OF WATER FOR 15 MINUTES. IF 

IRRITATION OCCURS AND PERSISTS, OBTAIN 

MEDICAL ATTENTION. 

INHALATION ...............: REMOVE FROM EXPOSURE. IF DISCOMFORT OCCURS 

AND PERSISTS, OBTAIN MEDICAL ATTENTION. 

INGESTION ... . ........... .: RINSE MOUTH WITH WATER. DILUTE BY GIVING 1 OR 2 

GLASSES OF WATER. DO NOT INDUCE VOMITING. NEVER 

GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. 

SEE A MEDICAL DOCTOR IMMEDIATELY. 

NOTES TO PHYSICIAN.......: WHILE INTERNAL TOXICITY IS LOW, IRRITANT 

EFFECTS OF HIGH CONCENTRATIONS MAY PRODUCE 

(CONTINUED) PAGE 01 
NIATERIAL SAFETY DATA SOD I UM CARBONATE AFMC 

497 -19 -8 

U.S./CANADA VERSION EFFECTIVE: 02/13/97 PRINTED: 05/16/97 

FIRST AID MEASURES 

CORNEAL OPACITIES AND VESICULAR SKIN 

REACTIONS IN HUMANS WITH ABRADED SKIN ONLY. 

TREATMENT IS SYMPTOMATIC AND SUPPORTIVE. 

=o=e=s=ss=asaso=3:s=asa=aslS . FIRE FIGHTING MEASURES s=s=sasssx=====oasscs 

EXTINGUISHING MEDIA ...... : 

SPECIAL FIREFIGHTINr, ..... : 

PROCEDURES 

DEGREE OF FIRE AND ....... : 

EXPLOSION HAZARD 

HAZARDOUS DECOMPOSITION..: 

PRODUCTS 

WATER, WATER FOG, CARBON DIOXIDE (CO2), 

DRY CHEMICAL. 

WEAR FULL PROTECTIVE CLOTHING AND SELF 

CONTAINED BREATHINr, APPARATUS. 

NOT APPLICABLE. 

HEATED TO DECOMPOSITION, IT EMITS FUMES OF 

SODIUM OXIDE. 

=====soa=ssszs=xssssssassm ~ b. ACCIDENTAL RELEASE MEASURES 

PROCEDURE FOR RELEASE .... : SWEEP UP AND RECYCLE INTO PROCESS IF 

OR SPILL CONTAMINATION DOES NOT PRESENT A PROBLEM. USE 

APPROPRIATE PROTECTIVE EQUIPMENT IF DUST IS 

GENERATED.OR CONTACT WITH EYES OR SKIN IS 

EXPECTED. FLUSH RESIDUES AND LIQUID TO HOLDING 

AREA FOR NEUTRALIZATION BEFORE DISCHARGE. 

HANDLING AND STORAGE 

HANDLING .................: USE AIR CONVEYING/MECHANICAL SYSTEMS FOR SULK 

TRANSFER TO STORAGE. FOR MANUAL HANDLINr, OF BULK 

TRANSFER USE MECHANICAL VENTILATION TO REMOVE 

AIRBORNE DUST FROM RAILCAR, SHIP OR TRUCK. USE 

APPROVED RESPIRATORY PROTECTION WHEN VENTILATION 

SYSTEMS ARE NOT AVAILABLE. SELECTION OF 

RESPIRATORS IS BASED ON THE DUST CLOUD 

GENERATED. 

VENTILATION ..............: PROVIDE GENERAL MECHANICAL AND/OR LOCAL EXHAUST 

VENTILATION TO PREVENT RELEASE OF AIRBORNE DUST 

INTO THE WORK ENVIRDNMENT. APPROVED RESPIRATORY 

PROTECTION SHOULD BE USED WHEN AIRBORNE DUST 

IS EXPECTED TO BE RELEASED. 

STORAGE ..................a STORE IN A COOL DRY AREA, AWAY FROM ACIDS. 

=====aax=sssssss:sssssssss S. EXPOSURE CONTROLS/PERSONAL PROTECTION ==a=as 

CONTROL MEASURES ......... : MINIMIZE EYE AND SKIN CONTACT BY USING 

APPROPRIATE PROTECTIVE EQUIPMENT. USE LOCAL OR 

GENERAL ROOM VENTILATION TO CONTROL AIRBORNE 

DUST THAT MAY BE GENERATED INTO THE WORK 

ENVIRONMENT. 

RECOMMENDED PERSONAL 

(CONTINUED) PAGE 02 
h1ATERIAL SAFETY DATA SODIUM CARBONATE fMC 

497 —19 —8 

I U.S./CANADA VERSION EFFECTIVE: 02/13/97 PRINTED; 05/16/97 

=oz=aaazszszsa=sssa=xaazs 

PROTECTIVE EQUIPMENT 

RESPIRATORY ........ : 

EYES ......... .. .... : 

GLOVES.............: 

SPECIAL CLOTHING ... : 

AND EQUIPMENT 

FOOTWEAR ........... : 

MELTING/FREEZING POINT...: 

BOILINGPOINT ............: 

VAPOR PRESSURE...........: 

VAPOR DENSITY (AIR=1)....: 

ROOM TEMPERATURE.........: 

APPEARANCE AND STATE 

ODOR .....................: 

SPECIFIC GRAVITY (H2O=1).: 

SOLUBILITY IN H20 % BY WT; 

% VOLATILES ..............: 

EVAPORATION RATE ......... : 

(BUTYL ACETATE=1) 

PH(AS IS) ...............: 

PH (1% SOLUTION) ......... : 

ODOR THRESHOLD ........... : 

DENSITY (G/ML) ........... : 

PARTITION COEFFICIENT .... : 

N—OCTANOL/WATER 

FLASHPOINT ..............s 

AUTOIGNITION TEMPERATURE.: 

FLAMMABLE LIMITS UPPER..: 

(AIR) LOWER..: 

EXPLOSIVE PROPERTIES ..... : 

OXIDIZING PROPERTIES......: 

SOLUBILITY ...............: 

— FAT SOLUBILITY 

(SOLVENT — OIL) 

coz=== ~sazasa=assssssas 

S. EXPOSURE CONTROLS/PERSONAL PROTECTION ====== 

USE APPROVED DUST RESPIRATORS FOR LOW LEVELS OF 

AIRBORNE DUST. HIGH CONCENTRATIONS MAY REQUIRE 

AIR SUPPLIED SYSTEMS. 

USE CUP TYPE CHEMICAL GOGGLES. 

USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT. 

ARM PROTECTORS AND APRONS. IF CLOTHING GECOMES 

CONTAMINATED REMOVE AND LAUNDER BEFORE REUSE. 

INDUSTRIAL SAFETY SHOES. 

9. PHYSICAL AND CHEMICAL PROPERTIES 

851 DEGREES C(1564 DEGREES F) 

DECDMPOSES 

NOT APPLICABLE 

NOT APPLICABLE 

WHITE. SOLID GRANULAR 

ODORLESS 

2.509 

33.2 MAXIMUM. 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

11.4 

NOT APPLICABLE 

DENSE GRADES,0.86-1.12; LIGHT GRADES,0.70 - 0.90 

NOT APPLICABLE 

NONCOMBUSTIBLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT AVAILABLE 

10. STABILITY AND REACTIVITY sassaza=azszazszss 

STABILITY ................: STABLE 

HAZARDOUS POLYMERIZATION.: WILL NOT OCCUR 

CONDITIONS TO AVOID ...... : CONTACT WITH ACIDS EXCEPT UNDER CONTROLLED 

CONDITIONS. 

MATERIALS TD AVOID ....... : ALUMINUM POWDER. ACIDS, FLUORINE, MOLTEN 

LITHIUM. 

MAJOR CONTAMINANTS THAT..: 

(CDNTINUED) PAGE 03 
MaTERIALSAFETYDATA SODIUM CARBONATE 4FMC 

497 -19 -8 

U.S./CANADA VERSION EFFECTIVE: 02/13/97 PRINTED: 05/16/97 

coa==ssss ~ assssssssasssas 10. STABILITY AND REACTIVITY aaass::saa=aa ~ a=ss 

C'ONTRIBUTE TO INSTABILITY NONE 

INCOMPATIBILITY .......... a REACTS WITH ACIDS WITH RELEASE OF LARGE VOLUMES 

OF CARBON DIOXIDE GAS AND HEAT. 

HAZARDOUS DECOMPOSITION..: NONE 

PRODUCTS 

SENSITIVITY TO MECH ...... : NONE 

IMPACT 

SENSITIVI•TY TO STATIC .... ; NONE 

DISCHARGE 

=c_===saoaa=am=s=a=ssaaaas ~ ll. TOXICOLOGICAL INFORMATION 

EYE CONTACT ..............: SEVERE IRRITANT (RABBIT) 

TOXICOLOGY 23:281-291 (1982) 

SKIN CONTACT .............; NON-IRRITATING TO INTACT SKIN. MINOR IRRITATION 

MAY OCCUR ON ABRADED SKIN. 

NON-SENSITIZING (HUMANS, 0.25% SODIUM CARCONATE) 

TOXICOL. APPL. PHARMACOL. 31:481-490 (1975) 

SKIN ABSORPTION .......... : NO DATA AVAILABLE. 

INHALATION ...............: LC50 = 2.3 MG/L (RAT,2 HR.) ENVIRON 

RES 31:138 (1983). 

INGESTION ................; LD50 = 4090 MG/KG (RAT) (RTECS 1985-6). 

ACUTE EFFECTS FROM ....... : MAY CAUSE SEVERE IRfiITATION OF THE EYES, 

OVEREXPOSURE INCLUDING CORNEAL OPACITIES. DUSTS AND MISTS 

ARE IRRITATING TO THE SKIN, MUCOUS MEMBRANES 

AND UPPER RESPIRATORY TRACT. 

CHRONIC EFFECTS FROM.....: MAY CAUSE INFLAMMATION OF THE MUCOUS MEMBRANES 

OVEREXPOSURE IN THE RESPIRATORY TRACT AND OF THE SKIN. 

(EFFECTS CONSIDERED 

INCLUDE: 

SENSITIVITIES, 

CARCINOGENICITY, 

TERATOGENICITY, 

MUTAGENICITY, 

SYNERGISTIC 

PRODUCTS, AND ANY 

MEDICAL CONDITIONS 

GENERALLY RECOGNIZED 

AS BEING AGGRAVATED 

BY EXPOSURE.) 

====o===aaaaa=sasasaaasass ~ l2. ECOLOGICAL INFORMATION 

ENVIRONMENTAL FATE ....... : BIODEGRADABILITY DOES NOT APPLY TO INORGANIC 

SUBSTANCES. NO OTHER DATA AVAILABLE. 

ENVIRONMENTAL EFFECTS .... ; 96 HR LC50 (DAPHNIA MAGNA) = 265-565 MG/L 

96 HR LC50 (BLUEGILL SUNFISH) = 300-320 MG/L 

(CONTINUED) PAGE 04 
h1ATERIAL SAFETY DATA SOD IUM CARBONATE 4FMC 

497 -19 -8 

U.S./CANADA VERSION EFFECTIVE: 02/13/97 PRINTED: 05/16/97 

=o== ~ =sxssassrssasssssa 13. DISPOSAL CONSIDERATIONS =====a=====__=====a 

WASTE DISPOSAL METHOD .... : SALVAGE AS MUCH MATERIAL AS POSSIBLE AND RETURN 

TO PROCESS IF CONTAMINATION DOES NOT PRESENT A 

PROBLEM. DISPOSE IN AN APPROVED LANDFILL IN 

ACCORDANCE WITH ACCEPTED GOVERNMENTAL 

REGULATIONS. 

c=nosaosssrsarssasssssss 14. TRANSPORT INFORMATION sasa:ssoo:=r===rro=a ~ 

DOT PROPER SHIPPING NAME.: 

IATA .....................: 

IMDG ..................... 

DOT CLASSIFICATION.......: 

DOTLABELS ...............: 

DOTMARKING ..............: 

DOT PLACARD ..............: 

UN NUMBER ................: 

HAZARDOUS SUBSTANCE/RQ ... : 

49STCC NUMBER ........... : 

PRECAUTIONS TO BE TAKEN..: 

IN TRANSPORTATION 

OTHERSHIPPING...........: 

INFORMATION 

SODIUM CARBONATE 

NOT APPLICABLE 

NOT APPLICABLE 

NON HAZARDOUS 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

SWEEP UPr RETURN TO CONTAINER 

FOR DISPOSAL. 

SODIUM CARBONATE IS GENERALY 

(r,RAS) WHEN USED WITH CURRENT 

MANUFACTURING PRACTICES. 

AND MARK AS WASTE 

REGARDED AS SAFE. 

GOOD 

===a==a=sasass3sssasssa:ss~ 15. REGULATORY INFORMATION ar=sa=:s=s=s=r=a=rra 

OSHA 

EXPOSURE LIMITS 

SUESTANCE(S) ........... : 

OSHA PEL-TWA .......... : 

STEL .............: 

CEILING .......... : 

SKIN DESIGNATION.: 

ACr,IH TLV-TWA .......... : 

STEL ... ............ 

CEILING .... ......: 

SKIN DESIGNATION.: 

TARGET ORGAN EFFECTS ..... : 

CARCINOGENIC POTENTIAL...: 

REGULATED BY OSHA ...... : 

LISTED ON NTP REPORT...: 

IARC GROUP 1. 2A. 2B...: 

U.S. EPA REQUIREMENTS 

RELEASE REPORTING 

CERCLA (40 CFR 302) 

LISTED SUBSTANCE(S)....: 

RQ ...............: 

CATEGORY ......... : 

RCRA WASTE NO .... : 

SODIUM CARBONATE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

EYE 

NO 

NO 

NO 

NOT LISTED 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

(CONTINUED) PAGE 05 
NIATERIALSAFETYDATA SODIUM CARBONATE 4FMC 

497 —19 —8 

U.S./CANADA VERSION EFFECTIVE: 02/13/97 PRINTED: 05/16/97 

REGULATORY INFORMATION 

UNLISTED SUBSTANCE(S)..: NOT APPLICABLE 

RQ............... NOT APPLICABLE 

CHARACTERISTIC ... : NOT APPLICABLE 

RCRA WASTE NO .... : NOT APPLICABLE 

SARA TITLE III SEC 313 

(40 CFR 372)...........: 

LISTED TOXIC CHEMICAL..: NOT LISTED 

INVENTORY REPORTING 

SARA TITLE III SEC 311/312 

(40 CFR 370) 

SUBSTANCE(S) ........... : SODIUM CARBONATE 

HAZARD CATEGORY ........ : IMMEDIATE (ACUTE) HEALTH HAZARD (IRRITANT) 

PLANNING THRESHOLD ..... : 10.000 POUNDS 

EMERGENCY PLANNING 

SARA TITLE III SEC 302-303 

(40 CFR 355) 

LISTED SUBSTANCE(S) .... : NOT APPLICABLE 

RQ .....................: NOT APPLICABLE 

PLANNI.NGTHRESHOLD.....: NOT APPLICABLE 

U.S. TSCA STATUS ......... : LISTED 

CANADA 

INGREDIENT DISCLOSURE LIST 

SUCSTANCE(S) ........... : SODIUM CARBONATE 

CONTROLLED PRODUCT ....... a YES 

HAZARD SYMBOLS ........... : TOXIC 

CLASS & DIVISION ....... a CLASS D. DIVISION 2, SUBDIVISION E. 

PRODUCT IDENTIFICATION N0: NOT APPLICABLE 

DOMESTIC SUBSTANCE LIST..s LISTED 

CEPA PRIORITY LIST ....... : NOT LISTED 

CARCINOGENICITY 

ACGIH APPENDIX A ....... : NOT LISTED 

A1 — CONFIRMED HUMAN ... : NOT LISTED 

A1 — SUSPECTED HUMAN ... : NOT LISTED 

IARC GROUP 1 OR 2 ........ : NO 

LAEEL LANGUAGE (US/CANADA) 

HEALTH .................: DUST MAY CAUSE SEVERE IRRITATION OF EYES AND 

SLIGHT IRRITATION OF NOSE AND THROAT. REPEATED 

CONTACT MAY CAUSE REDNESS AND DRYr CRACKED SKIN. 

PHYSICAL ...............: NOT APPLICABLE 

HANDLING AND STORAGE ... s DO NOT STORE CLOSE TO ACIDS. WEAR EYE 

PROTECTION AND APPROVED DUST RESPIRATOR WHEN 

EXCESSIVE DUST IS PRESENT. 

FIRST AID ..............: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH 

WATER FOR AT LEAST 15 MINUTES. IF IRRITATION 

PERSISTS. OBTAIN MEDICAL ATTENTION. FLUSH SKIN 

WITH WATER. 

STATE REGULATIONS........: CALIFORNIA PROPOSITION 65: SAFE WATER AND TOXIC 

ENFORCEMENT ACT OF 1986. THE FOLLOWING CHEMICALS 

HAVE BEEN DETECTED. 

. (CONTINUED) PAGE 06 
h1ATERIAL SAFETY DATA SODIUM CARBONATE IFMC 

497 —19 —8 

U.S./CANADA VERSION EFFECTIVE: 02/13/97 PRINTED: 05/16/97 

=aa====assssosssasasssss:s ~ ls . REGULATORY INFORMATION 

ARSENIC,PPM AS AS203 = 0.03 

TOTAL CHROMIUM,PPM CR = 0.03 

LEAD,PPM PB.......... = <1 

CADMIUM,PPM CD....... = <0.1 

ALL OTHER LISTED CHEMICALS ARE NOT DETECTED OR 

NOT SUSPECTED TO EE PRESENT. 

_=====aa==zss=azasasasssos ~ l6 . OTHER INFORMATION ss:zsassszsasess=osas==ox 

PRODUCT USES .............: GLASS MANUFACTURE, DETERGENT MANUFACTURE, SODIUM 

CHEMICALS AND CARBONATE CHEMICALS MANUFACTURE, 

PULP AND PAPER, BRINE TREATMENTs WATER HARDNESS 

REMOVAL, PH ADJUSTMENT IN WATER OR WASTE WATER, 

FLUE GAS DESULFURIZATION, COAL TREATMENT, ION 

EXCHANGE RESIN REGENERATION. 

NFPA 704 

HEALTH ..............: 2 

FLAMMABILITY........: 0 

REACTIVITY.......... 0 

SPECIAL HAZARD...... 0 

(DEGREE OF HAZARD 

0 = NO HAZARD 

4 = SEVERE HAZARD) 

HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) 

HEALTH ...............• 2 

FLAMMABILITY:........: 0 

REACTIVITY: .......... : 0 

PERSONAL PROTECTION 

INDEX (PPI) ........ :H 

(SAFETY GOGGLES, GLOVES, APRON AND VAPOR 

RESPIRATOR) 

------------------------------------------------ 

THIS CHEMICAL IS CERTIFIED TO ANSI/NSF 

STANDARD 60. DRINKING WATER TREATMENT CHEMICALS— 

HEALTH EFFECTS. THE MAXIMUM DOSAGE LEVEL FOR 

THIS CHEMICAL IS 150 MG/L. 

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THE CONTENTS AND FORMAT OF THIS MSDS ARE IN 

ACCORDANCE WITH OSHA HAZARD COMMUNICATION AND 

CANADA'S WORKPLACE HAZARDOUS MATERIAL 

INFORMATION SYSTEM (WHMIS). 

PAGE 07 
Material Safety Data Sheet 

Substance Identification 

identity: MANGANESE DIOXIDE Cas #: 1313-13-9 

Trade Names: Brickox, GranuSpeck 

Manufacturer: The Prince Manufacturing Co. Emergency: Chemtrec 

One Prince Plaza 1-800-424-9300 

Quincy, IL 62301 

217-222-8854 

Components and Contaminants 

Manganese Compound ( as Mn) 7439-96-5 5 mg/m° (C) 5 mg/m° (C) 51-55% Mn 

Iron Oxide 1309-37-1 --- -- 1-5% Fe203 

Silica, Crystalline Quartz (respirable) 14808-60-7 0.1 mg/m' 0.1 mg/m' (TWA) 1-5% Si02 

Aluminum Oxide (non-fibrous) 

(respirable fraction) 1344-28-1 5 mg/m3 5 mg/m' (TWA) 1-7% AIZO, 

Barium Oxide 1304-28-5 -- --- 0.2-2% Ba0 

Physical Data 

Boiling Point: NA Specific Grravlty (H=0=1): 5.0 

Vapor Pressure (mm/Hg): NA Melting Point: 535° C 

Vapor Density (Air-1): NA Evaporation Rate (Butyl Acetate=1): NA 

Solubility in Water: insoluble 

Appearance and Odor: black to brownish black, no odor 

Fire and Explosion Hazard Data 

Flash Point: Not combustibie 

Flammable Limits: LEL NA UEL NA 

Extinguishing Media: Foam, COZ, dry chemical or water. 

Special Fire Fighting Procedures: In the event of fire, wear full protective clothing and NIOSH-approved 

seif-contained breathing apparatus with full face piece operated in the 

pressure demand or other positive pressure mode. 

Unusual Fire and explosion hazards: Not combustibie, but substance is a strong oxidizer and its heat of 

reaction with reducing agents or combustibles may cause ignition. 

Increases the flammability of any combustible substance. 

Reactivity Data 

Stability: Stable under ordinary conditions of use and storage. 

Conditions to avoid: Do not heat or grind in the presence of easiiy oxidizable substances or 

organic matter. 

Incompatibility (materials to avoid): Easily oxidizable substances, suifur, suifides, phosphides, 

hydrophosphides, chlorates, peroxides, aiuminum powder, rubidium 

acetyiide, potassiurn azide, chiorine trifluoride. Reacts with 

hydrochioric acid to form con•osive chlorine gas. 

Hazardous Decomposition or Byproducts: Upon heating it decomposes to form manganese sesquioxide and 

oxygen which facilitates combustion. 

Hazardous Polymerization: Will not occur. 

Health Hazard Data 

Route of Entry: INHALATION: May irritate the respiratory tract. May increase the 

incidence of upper respiratory infections (pneumonia). Prolonged 

exposure to siiica dust may result in silicosis, a fibrotic lung disease. 

SKIN: May cause irritation. 

INGESTION: May cause abdominal pain and nausea. Manganese 

dioxide dust is poorly absorbed through the gut. 

Manganese Dioxide, Page 1 ~ 

Reviewed July 1996 Unchanged since July 19y~ 
Health Hazard Data 

Health Hazards (Acute and Chronic): Chronic exposure and inhalation of excessive manganese dust may cause 

disorders of the central nervous system. 

Carcinogenicity: NTP: No IARC Monographs: Yes (Silica) 

Signs and Symptoms of Exposure: Early symptoms of manganese toxicity include sluggishness, sleepiness, 

and weakness in legs. Symptoms of silicosis include impaired pulmonary 

function and wheezing. 

Aggravation of Pre-existing Conditions: Persons with impaired respiratory function may be more susceptible to the 

effect of this substance. 

Emergency and First Aid Procedures: IF INHALED, remove to fresh*air and seek medical attention for any 

breathing difficulty. 

IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical 

attention if red & irritated. 

IN CASE OF EYE CONTACT, flush eyes immediately with water for at least 

15 minutes. Seek medical attention if irritation persists. 

IF INGESTED, induce vomiting immediately by giving two glasses of water 

and sticking finger down throat. Never give anything by mouth to an 

unconscious person. Call a physician immediately. 

Precautions for Safe Handling and Use 

Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory 

protection. Recover uncontaminated material for use. Vacuum or sweep 

remaining material, keeping dust to a minimum. Isolate wet material from 

dry and store away from combustible materials. . 

Waste Disposal Method: Dispose of unreclaimable material in a RCRA-approved waste facility. 

Handling and Storing Precautions: Manganese dioxide is classifled as an oxidizer and should be stored in a 

dry place away from combusitlbes and sources of high heat. Protect 

containers from damage and keep closed when not in use. 

Other Precautions: Observe good personal hygiene. Wash after handling. 

Control Measures 

Respiratory Protection: Use NIOSH approved pan`aculate respirator if dust generation occurs or is 

anticipated. OSHA standard 1910.134 or ANSI Z88.2-1980 specifications 

are recommended. 

Ventilation: A system of local and/or general exhaust is recommended to keep 

employee exposures below the Airborne Exposure Limits. Local exhaust is 

generally preferred because it can control the emissions of the contaminant 

at its source, preventing dispersion of it into the general work area. Please 

refer to the ACGIH document, "Industrial Ventilation, A Manual of 

Recommended Practices", most recent edition, for details. 

Protective Gloves: Yes 

Eye Protection: Safety goggles are recommended. 

Other Protective Clothing or Equipment: Use other protective equipment when necessary in order to avoid 

prolonged exposure to skin. 

Work and Hygienic Practices: ' Obsenre good personal hygiene. Wash after handling. 

SARA Title III Section 313 Supplier Notification 

This product contains the following toxic chemicals subject to the reporting req Emergency 

Planning and Community Right-to-Know Act of 1986 and of 40 CFR 372.45: 

Com onent SAS % bv Weiaht 

Manganese Dioxide 1313-13-9 51-55% Mn 

Barium Oxide 1304-28-5 0.1-1.8% Ba 

This information must be inciuded in all MSDS's that are copied and distributed for this material. 

Manganese Dioxide, Page 2 „ ` 

Reviewed luly 1996 Unchanged since July 1996 ~ 
3LATZRIAL BAYETY DATA 88EET MSDS No: 037 

CNZDSIN CORPORATION 

258 Elm Street 

New Canaan, CT 06840 

Emergency Telephone Number 

(203) 966-8880 

Telephone Number for Information 

(203) 966-8880 

Date Prepared: October 23, 1995 

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SECTION 1: IDEZTTIlICATION 

PRODUCT NAlME :Olivine, various grades 

SYNONYMS: Magnesium Iron Silicate 

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SECTION 2s COM80N8NT9 

CAS# Component Percentace Exposure Limits 

1317-71-1 Olivine >99.3t PEL- 5 mg/m 3TWA 

(respirable fraction) 

TLV- 10 mg/m 3TWA 

(total dust) 

MSHA- 5 mg/m 3TWA 

(respirable fraction) 

7440-02-0 Nickel Compounds (as Nickel) 0.1-0.3t PEL- 1 mg/m 3TWA 

TLV- 1 mg/ry TWA 

MSHA- 1 mg/m 3TWA 

7440-47-3 Chromium Compounds (as Chromium)_ 0.1-0.4t PEL- 0.5 mg/m 3TWA 

TLV- 0.5 mg/m 3TWA 

MSHA- 0.5 mg/m 3TWA 

PEL means OSHA Permissible Exposure Limit. 

TLV means American Conference of Governmental Industrial Hygienists (ACGIH) Threshold 

Limit Value. 

MSHA means Mine Safety and Health Administration Exposure Limit. 

TWA means 8 hour time weighted average. 

Note: The Permissible Exposure Limits (PEL) reported above are the pre-1989 limits 

that were reinstated by OSHA June 30, 1993 following a decision by the lith Circuit 

Court of Appeals. These PELs are now being enforced by Federal OSHA. Be aware that 

cnore restrictive exposure limits may be enforced by some states, agencies or other 

authorities. 

.........................................:.....................:.....s.............. 

Page 1 of 6 Pages 

~~ 
MSDS No: 037 

SECTION 3: SAZARDS IDSNTIPICATION 

EMERGENCY OVERVIEW 

This product is a chemically inert, non-combustible mineral. Excessive inhalation of 

dust may cause lung injury with symptoms of shortness of breath and reduced pulmonary 

function. See "Cancer Status" in this Section 3. 

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HEAI,TH HAZARDS : 

Inhalation:Inhalation of dust may cause irritation of the nose, throat and 

respiratory passages. 

Skin Contact: No adverse effects expected. 

Eye Contact:Contact may cause mechanical irritation and possible injury. 

Ingestion:No adverse effects expected for normal, incidental ingestion. 

Chronic Health Effects: Prolonged overexposure to any nuisance dust may cause lung 

injury. Symptoms include cough, shortness of breath, aad reduced pulmonary fuaction. 

This product contains small amounts of nickel and chromium compounds. Hexavalent 

chromium has not been detected in this product (detection limit 0.11r). Overexposure 

to nickel and chromium compounds may cause respiratory and skin sensitization. 

Cancer Status:Nickel compounds are classified by ZARC as "carcinogenic to humans" 

(Group 1) and by NTP as "reasonably anticipated to be a carcinogen". Olivine is not 

listed as a carcinogen or suspected carcinogen by IARC, NTP or OSHA. 

Medical Conditions Aaaravated bY Exposure: Individuals with respiratory disease, 

including but not limited to, asthma and bronchitis, or subject to eye irritation 

should be excluded from exposure. 

Sians and Symptoms of Exposure: Overexposure to nuisance dusts may cause mucous 

membrane and respiratory irritation, cough, sore throat, nasal congestion, sneezing 

and shortness of breath. 

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SECTION 4: TIRST AID 

Gross Inhalation:Remove victim to fresh air. If breathing has stopped, perform 

artificial respiration. If breathinQ is difficult have qualified personnel administer 

oxygen. Get prompt medical attention. 

Skin Contact: No first aid should be needed since this product does not affect the 

skin. Wash exposed skin with soap and water before breaks and at the end of the 

shift. 

Page Z of 6 Pages 

,37 
MSDS No: 037 

E,ye Contact: Flush the eyes immediately with large amounts of running water, lifting 

the upper and lower lids occasionally. If irritation persists or for imbedded foreign 

body, get immediate medical attention. 

stion: Inge If large amounts are swallowed, get immediate medical attention. 

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BECTION S: FIRE AND S7CPLOSION DATA 

Flash Point (Method Used): Fully oxidized, will not burn. 

Autoianition Tema: will not burn. 

Flammable Limits: LEL: Not applicable 4EL: Not applicable 

Extinauishing Media: This product will not burn but is compatible with all 

extinguishing media. Use any media that is appropriate for the surrounding fire. 

Special Fire Fighting Procedures: None required with respect to this product. 

Firefighters should always wear self-contained breathing apparatus for fires indoors 

or in confined areas. 

Unusual Fire and Explosion Hazards: None. 

Hazardous Combustion Products: None. 

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SECTION 6: ACCIDENTAL RSLlASE MZASQRE9 

wear appropriate protective equipment. If uncontaminated, collect using dustless 

method (HEPA vacuum or wet method) and place in appropriate container for use. If 

contaminated: a) use appropriate method for the nature of contamination, b) consider 

possible toxic or fire hazards associated with the contaminating substance. Collect 

for disposal. 

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SECTION 7: IiANDLING AM STORAGs 

Avoid breathing dust. Use normal precautions against bag breakage or spills of bulk 

material. Avoid creation of respirable dust. Use good housekeeping in storage and use 

areas to prevent accumulation of dust in work area. 

Use adequate ventilation and dust collection. Maintain and use proper, clean 

respiratory equipment (See Section 0. Launder clothing that has become dusty. wARN 

and TRAIN employees in accordance with state aad federal regulations. 

ATARN YOTJR EMPLOYEES (AND YOUR CUSTOMERS - IISERS IN CASE OF RESALE) BY POSTING AND 

OTH£R MEANS OF T8E HAZARDS AND OSAA PRECAtJTIONS TO BE USED. PROVIDE TRAINING FOR YOUR 

EMPLOYEES ABOUT OSAA PRECAUTIONS. 

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Page 3 of 6 pages 

~-v~ 
MSDS No: 037 

SECTION 8: EJCPOSQRS CONTROLS/PERSONAL PROTBCTION 

Ventilation: Use local exhaust as required to maintain exposures below applicable 

occupational exposure limits. See also ACGIH "Industrial Ventilation - A Manual for 

Recommended Practice", (current edition). 

Respiratory Protection: Use appropriate respiratory protection for respirable 

particulates based on consideration of airborne workplace concentrations and duration 

of exposure. Refer to the most recent standards of ANSI (Z88.2) OSFiA (29 CFR 

1910.134), MSHA (30 CFR Parts 56 and 57) and NIOSH Respirator Decision Logic. 

Gloves:Protective gloves recommended. 

Eye Protection: Safety glasses or goggles recommended. 

Other Protective Esuipment/Clothina: As appropriate for the work environment. Dusty 

clothing should be laundered before reuse. 

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9: PFIYSICAL AND CHEMICAL PROPERTIES 

Appearance and Odor: Light green to gray-green sand-size granules, odorless. 

Hc Not applicable Specific Gravitv (waterai): 2.3 - 3.6 

Hoilina Point:Not applicable Vapor Pressure: Not applicable 

Melting Point: 2800 - 3200"F Vapor Densitv: Not applicable 

Solubility in water:Insoluble Evaporation Rate: Not applicable 

Percent Volatile: 08 

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SECTION 10: STABILITY AND REACTIVZTY 

Stability:Stable 

Conditions to Avoid:None 

Incompatibility:None known. 

xazardous Decomposition Products: None known. 

Hazardous Polymerization: Will not occur. 

Conditions to Avoid: None 

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SsCTION 11: TOxICOLOGIChL ZNFORMATlolt 

No acute toxicity data is available for product or components. Refer to Section 3 for 

health hazard information. 

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Page 4 of 6 Pages 

, 

J, 
MSDS No: 037 

SECTION 12: ECOLOGICAL INlOR?SATION 

No ecotoxicity data is available. This product is not expected to present an 

environmental hazard. 

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SECTION 13: DISPOSAL 

waste Disposal Method: If uncontaminated, dispose as an inert, non-metallic mineral. 

If contaminated, dispose in accordance with all applicable local, state/provincial 

and federal regulations. 

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SECTION 14: TRANSPORTATION DATA 

U.S. DOT HAZARD CLASSIFICATION 

Proper Shipping Name:Not Regulated 

Technical Name: N/A 

UN Number:N/A 

Hazard Class/Packina Group:N/A 

Labels Rernaired:None 

DOT Packaaina Recuirements:N/A 

Exceptions:N/A 

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SECTION 15: OTEER RECiQLATORY INFORMATION 

SARA 311/312:Hazard Categories for SARA Section 311/312 Reporting: 

Chronic health 

SARA 313This Product Contains the Following Chemicals Subject to Annual Release 

Reporting Requirements Under the SARA Section 313 (40 CFR 372): 

Nickel Compounds 0.1 - 0.3t 

Chromium Compounds 0.1 - 0.4% 

CERCLA Section 103 Reportable OuantitY: None 

California Proposition 65:This Product contains the following substances known to 

the State of California to cause cancer and/or reproductive harm: This product 

contains nickel compounds. 

Toxic Substances Control Act: A11 of the components of this product are listed on the 

EPA TSCA Inventory or exempt from notification requirements. 

European InventorSr of Comercial Chemical Substances: A11 of the components of this 

product are listed on the SINECS Inventory or exempt from notification requirements. 

Canadian Environmental protection_Act= All the components of this product are listed 

on the Canadian Domestic Substances List or exempt from notification requirements. 

Page 5 of 6 Pages 

/4l 
MSDS No: 037 

Japan MITI: All of the components of this product are existing chemical eubstances as 

' defined in the Chemical Substance Control Law. 

Australian Inventory of Chemical Substances: All of the components of this product 

are listed on the AICS inventory or exempt from notification requirements. 

Canadian wH+iIS Classification: Class D, Division 2, Subdivision A(Very Toxic 

Material causing other Toxic Effect) 

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16: OTSHR INlORMATION 

E~sropean Community Labeling Classification: N/A 

Euro ean Community Risk and Safety Phrases: None 

NFPA Hazard Ratings_ Health: 1 Fire: 0 Reactivity: 0 

HMIS Hazard Rating: Health: 1 8ire: 0 Reactivity: 0 

References• 

Registry for Toxic Effects of Chemical Substances (RTECS), 1995 

Hawley's Condensed Chemical Dictionary, twelfth edition 

NTP Seventh Annual Report on Carcinogens, 1994 

Patty's Industrial Hygiene and Toxicology 

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CREATION DATE: October 23, 1995 REVISION DATE: October 23, 1995 

The data in this Material Safety Data Sheet relates only to the specific material 

designated herein and does not relate to use in combination with any other 

material or in any process. The information aet forth herein is based on technical 

data the Unimin Corporation believes reliable. It is intended for use by persons 

having technical skill and at their own discretion and risk. Since conditions of 

use are outside the control of Unimin Corporation, no warranties, expressed or 

implied, are made and no liability is assumed in connection with any use of this 

information. Any use of these data and information must be determined by the user 

to be in accordance with federal, state and local laws and regulations. 

Page 6 of 6 Pages 

y/ 
-- [?S'-OMER - STATESVILLE BRICK COMPANY 

:age: 1 MATERIAL SAFETY DATA SHEET 

Prepared: 01/28/94 

EMERGENCY PHONE 

Cerdec Corporation 

Drakenfeld Products 

?.0. Box 519 

Washington PA 15301 

Information Phone: 412-223-5900 

Prepared By : Lucy Sten 

Product Safety Specialist 

CHEMTREC (800) 424-9300 

This number is to be used only 

in the event of chemical emergencies involving a spill, leak, 

fire, exposure or accident 

involving chemicals 

SECTION I - IDENTITY INFORMATION 

TRADE NAME : 5832A BUFF SPERSASTAIN 

CAS NUMBER : Mixture 

PRODUCT CODE : 50F0832A0000 

FAMILY/CHEMICAL NAME: 

Pigment and Silica Mixture. 

PRODUCT TYPE: 

Clayware Stains. 

:AZARD STATEMENT: 

This Material Safety Data Sheet (MSDS) has been prepared in 

compliance with the Federal OSHA Hazard Communication Standard 

29 CFR 1910.1200. 

This product is considered to be a hazardous substance under 

that standard. 

The key Immediate Hazards are: 

- Skin, eye and respiratory irritant. 

SECTION II - HAZARDOUS INGREDIENTS 

This product contains either pigment(s) that belong to the mixed 

metal oxide pigment class and/or frit which is an amorphous 

glassy material. These ingredients have been chemically reacted 

at high temperatures. They consist of inetal atoms and oxygen 

atoms arranged in unique structures; the toxicological 

properties have not been thoroughly investigated. A small 
?age: 02 MATERIAL SAFETY DATA SHEET 

5832A BUFF SPERSASTAIN (50F0832A0000) 

SECTION II - HAZARDOUS INGREDIENTS (cont.) 

:fAZARD STATEMENT: 

percentage of the starting materials may remain in this product 

and are considered hazardous under OSHA. 

The pigment and/or frit ingredient(s) do not have exposure limit 

values. Exposure limit values for the components are listed 

beneath each ingredient as a guideline for safe use of these 

products. 

=ngrzdients CAS NUMBER ACGIH - TLV OSHA - PEL 

C.I. PIGMENT BROWN 24 68186-90-3* 

Carcinogenicity: 

This product has not been reviewed 

for carcinogenicity by IARC, NTP 

or OSHA; however, antimony trioxide 

(Sb203) is considered to be carcinogenic by IARC (Group 2B). 

ANTIMONY COMPOUND 

Sb TWA 0.5 mg/M3 0.5 mg/M3 

CHROMIUM (III) COMPOUND 

Cr (+3) TWA 0.5 mg/M3 0.5 mg/M3 

TITANIUM OXIDE 

Total Dust TWA 10.0 mg/M3 10.0 mg/M3 

RESP 5.0 mg/M3 

-RYSTALLINE SILICA 14808-60-7 

Carcinogenicity: 

This product is considered to be 

carcinogenic by IARC (Group 2A). 

CRYSTALLINE SILICA 

Dust RESP 0.1 mg/M3 0.1 mg/M3 

.kMORPHOUS SILICA 112945-52-5 

Carcinogenicity: 

This product is not considered 

~~ 
Page: 03 MATERIAL SAFETY DATA SHEET 

5832A BUFF SPERSASTAIN (50F0832A0000) 

SECTION II - HAZARDOUS INGREDIENTS (cont.) 

Ingredients CAS NUMBER ACGIH - TLV OSHA - PEL 

to be carcinogenic by IARC 

(Group 3) or OSHA. 

AMORPHOUS SILICA 

Dust TWA 10.0 mg/M3 6.0 mg/M3 

APPEARANCE 

rlEIGHT PER GALLON 

BOILING RANGE 

VOC 

VAPOR DENSITY 

EVAPORATION RATE 

SOLUBILITY IN WATER 

SECTION III - PHYSICAL DATA 

: Brown Powder 

: N/AV 

: N/AP 

: 0 %(See Note in Section XII 

: Non Volatile 

: Non Volatile 

: Insoluble 

- Addendum) 

SECTION IV - FIRE AND EXPLOSIVE HAZARD DATA 

FLASH POINT 

FLAMMABILITY CLASS 

_OWER EXPLOSION LIMIT 

:JPPER EXPLOSION LIMIT 

Z- XTINGUISHING MEDIA: 

Water. 

: N/AP 

: NON-COMBUSTIBLE 

: N/AP 

: N/AP 

FIRE FIGHTING PROCEDURES-SPECIAL: 

Fire-Fighters should wear self-contained breathing apparatus and 

full protective clothing when fighting chemical fires. 

Use water spray to cool nearby containers and structures exposed 

to fire. 

Y'1 
ag`: 04 MATERIAL SAFETY DATA SHEET 

5832A BUFF SPERSASTAIN (50F0832A0000) 

SECTION IV, - FIRE AND EXPLOSIVE HAZARD DATA (cont.) 

'1NUSUAL FIRE AND EXPLOSION HAZARDS: 

This product will not burn. Use appropriate techniques to fight 

surrounding fire. 

SECTION V - REACTIVITY DATA 

:TABILITY Stable 

:AZARDOUS POLYMERIZATION : Will not occur 

- ONDITIONS TO AVOID: 

None Known. 

:NCOMPATIBILITY: 

None known. 

:AZARDOUS DECOMPOSITION: 

will not occur. 

SECTION VI - HEALTH HAZARD DATA 

This product contains either pigment(s) that belong to the mixed 

metal oxide pigment class and/or frit which is an amorphous 

glassy material. These ingredients have been chemically reacted 

at high temperatures. They consist of inetal atoms and oxygen 

acoms arranged in unique structures; the toxicological 

properties have not been thoroughly investigated. A small 

percentage of the starting materials may remain in this product 

and are considered hazardous under OSHA. 

~ / c~ 
=age: 05 MATERIAL SAFETY DATA SHEET 

5832A BUFF SPERSASTAIN (50F0832A0000) 

SECTION VI - HEALTH HAZARD DATA (cont.) 

PRIMARY ROUTES OF EXPOSURE: 

Inhalation, dermal and ingestion. 

OVEREXPOSURE EFFECTS: 

CONTAINS CRYSTALLINE SILICA: 

Crystalline silica can cause silicosis, a lung disease 

characterized by coughing, wheezing, impaired lung function 

and increased sputum production. This damage can be 

progressive and may cause death. May cause cancer following 

repeated and prolonged inhalation of the fine dust. Smoking 

aggravates these effects. Skin and eye contact may cause 

irritation due to mechanical abrasion. 

This product contains mixed metal oxide pigment(s) which 

consist of antimony and trivalent chromium in combination 

with other materials. 

CONTAINS ANTIMONY COMPOUNDS: 

May contain antimony trioxide which may cause coughing and 

rhinitis following breathing of dust. Lung tumors have been 

observed in female rats following inhalation exposure. 

CONTAINS CHROMIUM (III) COMPOUNDS: 

Compounds of chromium, in its trivalent state, have no 

established toxicity. When swallowed, it is not expected to 

cause local or systemic effects since it is poorly absorbed. 

No specific effects have been observed from inhalation. 

Skin contact has been reported to cause skin irritation 

but not ulceration. Allergic skin reactions may occur in 

sensitive individuals, although it is believed that the 

hexavalent (VI) form of chromium is responsible for most 

of the reported cases. 

Z16 
?age: 06 MATERIAL SAFETY DATA SHEET 

5832A BUFF SPERSASTAIN (50F0832A0000) 

SECTION VI - HEALTH HAZARD DATA (cont.) 

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: 

Respiratory conditions. 

EMERGENCY AND FIRST AID PROCEDURES: 

EYES 

For eye contact, immediately flush eyes for at least 15 minutes 

with running water. Hold eyelids apart to ensure rinsing of the 

entire eye surface and lids with water. Get immediate medical 

attention. 

SKIN 

For skin contact, wipe away excess material with dry towel. 

Then wash affected areas with plenty of water, and soap if 

available, for several minutes. Get medical attention if 

irritation occurs. 

=NHALATION: 

If inhaled, remove from area to fresh air. Get medical 

attention if respiratory irritation develops or if breathing 

becomes difficult. 

INGESTION: 

If swallowed, give at least 3-4 glasses of water, but do not 

induce vomiting. Do not give anything by mouth to an 

unconscious or convulsing person. Get medical attention. 

=HYSICIAN'S NOTE: 

None specified. 

SECTION VII - TOXICOLOGY INFORMATION 

Toxicology data of some components is available upon request. 

Please contact the Product Safety Specialist at (412) 223-5900. 

~~ 
Page: 07 MATERIAL SAFETY DATA SHEET 

5832A BUFF SPERSASTAIN (50F0832A0000) 

SECTION VII - TOXICOLOGY INFORMATION (cont.) 

TOXICOLOGY INFORMATION 

SECTION VIII - SPILL OR LEAK PROCEDURES 

SPILL PROCEDURES: 

Wear appropriate protective equipment. Avoid the generation of 

dust. Vacuum or shovel,material and place in closable 

container(s) for disposal. 

[IASTE DISPOSAL METHODS: 

Dispose in accordance with Federal, State and Local regulations. 

SECTION IX - SPECIAL PROTECTION INFORMATION 

VENTILATION: 

Adequate ventilation should be provided to keep dust and vapor 

concentrations below acceptable Exposure Limits. Discharge from 

the ventilation system should comply with the applicable air 

pollution control regulations. Eliminate ignition sources. 

PROTECTIVE GLOVES: 

Use gloves as a standard industrial handling procedure. 

EYE PROTECTION: 

Wear safety glasses or goggles to protect against exposure. 

RESPIRATORY PROTECTION: 

Appropriate respiratory protection is required when exposure to 

airborne contaminant is likely to exceed acceptable limits. 

Respirators should be selected and used in accordance with OSHA 

Vf 
='age: 08 MATERIAL SAFETY DATA SHEET 

5832A BUFF SPERSASTAIN (50F0832A0000) 

SECTION IX - SPECIAL PROTECTION INFORMATION (cont.) 

RESPIRATORY PROTECTION: 

Subpart I(29 CFR 1910.134) and manufacturer's recommendations. 

OTHER PROTECTIVE EQUIPMENT: 

None specified. 

SECTION X - SPECIAL PRECAUTIONS 

~ ABELING INFORMATION: 

WARNING! 

Skin, eye and respiratory irritant. 

Contains crystalline silica which can cause lung damage, 

including cancer. 

Keep away from heat and flame. 

Avoid contact with eyes, skin and clothing. 

Do not breathe dust. 

Keep away from food products. 

Wash thoroughly after handling and before eating, drinking or 

using cosmetic or tobacco products or toilet facilities. 

Use with adequate ventilation. 

Keep container closed when not in use. 

FIRST AID: 

If inhaled, remove to fresh air. If not breathing, give 

artificial respiration. If breathing is difficult, give 

oxygen. In case.of contact, immediately flush eyes or skin 

with plenty of water. Remove contaminated clothing. Get 

medical attention. 

IN CASE OF FIRE: 

Use water, dry chemical or carbon dioxide. 

IN CASE OF SPILL: 

Vacuum and dispose in accordance with federal, state and 

local regulations. 

For industrial use only. 

m 
Page: 09 MATERIAL SAFETY DATA SHEET 

5832A BUFF SPERSASTAIN (50F0832A0000) 

SECTION XI - REGULATORY INFORMATION 

SARA 313 TITLE III - TOXIC CHEMICALS LIST: 

96 01 Antimony Compound : llo Metal As Sb 

96% Chromium (3) Compound . 5a Metal As Cr 

PENNSYLVANIA RIGHT-TO-KNOW ACT: 

C.I. Pigment Brown 24 68186-90-3* S 

Quartz 14808-60-7 H 

Amorphous Silica 112945-52-5 H 

S= Pennsylvania Special Hazardous Substance 

H = Pennsylvania Hazardous Substance 

T'OXIC SUBSTANCE CONTROL ACT (TSCA): 

A11 ingredients in this product are listed on the U.S. EPA TSCA 

Inventory of Chemical Substances. 

SECTION XII - ADDENDUM 

DEFINITIONS AND ABBREVIATIONS 

Note: The V.O.C., listed in Section III, Physical Data, is an 

estimated/calculated value based upon the EPA Method 24 for 

determining V.O.C. 

ACGIH = American Conference of Governmental Industrial Hygienists 

C(Ceil) = The concentration that shall not be exceeded during any part of 

the working exposure. 

CAS = Chemical Abstracts Service Registry Number 

EPA = Environmental Protection Agency 

IARC = International Agency for Research on Cancer 

LEL = Lower Explosion Limit 

N/AP = Not Applicable 

N/AV = Not Available 

,V-71 
Page: 10 MATERIAL SAFETY DATA SHEET 

5832A BUFF SPERSASTAIN (50F0832A0000) 

SECTION XII - ADDENDUM (Cont. 

NIOSH = National Institute for Occupational Safety and Health 

NTP = National Toxicology Program 

OSHA = Occupational Safety and Health Administration 

PEEL = Permissible Exposure Limits 

SARA = Superfund Amendments and Reauthorization Act 

STEL = Short Term Exposure Limit. Usually a 15 minute time weighted 

average exposure that should not be exceeded at any time during 

a work day. 

TLV = Threshold Limit Values 

TSCA = Toxic Substance Control Act 

WA = Time Weighted Average. Exposure concentration for a normal 

8 hour work day and a 40 hour work week. 

O^ = Volatile Organic Content 

DISCLAIMER 

The information and recommendations contained herein are.based upon data 

.;elieved to be correct. However, no guarantee or warranty of any kind ~

expressed or implied is made with respect to the information contained herein. 

S/ 
Stationary Source Sampling Report 

Statesville Brick Company 

Sawdust Dryer and Kiln Exhaust Stacks 

Statesville, North Carolina 

Trigon Project # 046-97-066 

May 1997 

~~-- '~ 
Stationary Source Sampling Report 

Statesville Brick Company 

Sawdust Dryer and Kiln Exhaust Stacks 

Statesville, North Carolina 

Trigon Project # 046-97-066 

May 1997 

,~ 
STATIONARY SOURCE SAMPLING REPORT 

FOR 

STATESVILLE BRICK COMPANY 

STATESVILLE, NORTH CAROLINA 

Sawdust Dryer and Kiln Exhaust Stacks 

Performed by: 

Trigon Engineering Consultants, Inc. 

Environmental, Health & Safety Division 

6200 Harris Technology Blvd. 

Charlotte, North Carolina 28269 

704/598-1049 

Trigon Project # 046-97-066 

May 1997 

v`J~ 
REPORT CERTIFICATION 

This report, all testing details, and the final results have been performed under the supervision and 

reviewed by the persons named below. 

Date Nrc` Ii d* Signature 

Tom E. Wynn 

Project Manager 

Environmental, Health & Safety Division 

Trigon Engineering Consultants, Inc. 

DateLw'",Ll I ~, H5 5 Signature___2 

Pau11R. Jenkins, Jr. 

Quality Assurance Manager 

Environmental, Health & Safety Division 

Trigon Engineering Consultants, Inc. 

Date 

J.A. "Tony" Blanton 

Stack Testing Department Manager 

Environmental, Health & Safety Division 

Trigon Engineering Consultants, Inc. 

ii 

~ 

~ 
TABLE OF CONTENTS 

1.0 INTRODUCTION ..................................................................................................................1 

1.1 Purpose ..........................................................................................................................1 

1.2 Outline of Test Program ...............................................................................................1 

1.3 Test Participants ............................................................................................................2 

2.0 PROCESS DESCRIPTION ...................................................................................................3 

2.1 Discussion .....................................................................................................................3 

Figure 1- Process Air Flow Schematic ........................................................................4 

3.0 SAIVIPLING METHODS .......................................................................................................5 

3 .1 Sampling Strategy .........................................................................................................5 

3.2 Sampling and Analytical Procedures ...........................................................................5 

3.2.1 Sampling Ports, Traverse Points 

and Cyclonic Flow Determination ...............................................................5 

3.2.2 Stack Gas Velocity and Volumetric Flow Rate Detemiination ...................6 

3.2.3 Dry Molecular Weight Determination .........................................................7 

3.2.4 Moisture Determination ................................................................................8 

3.2.5 Determination of Hydrogen Fluoride ...........................................................9 

3.2.6 Sampling Ports and Points ..........................................................................10 

Location of Sampling Ports and Poirits 

Figure 2- Sawdust Dryer Exhaust Stack ...................................................11 

Figure 3- Kiln Exhaust Stack ....................................................................12 

3.3 Quality Assurance and Quality Control .....................................................................13 

4.0 RESULTS ...............................................................................................................................14 

4.1 Summary of Results ...................................................................................................14 

4.2 Discussion ...................................................................................................................14 

4.3 Detailed Stack Sampling Results ...............................................................................14 

Summary of Results 

Table 1- Sawdust Dryer Exhaust Stack .....................................................................15 

Table 2- Kiln Exhaust Stack ......................................................................................16 

5.0 APPENDICES .......................................................................................................................17 

A. Summary of Results and Example Calculations 

B. Field Data Sheets 

C. Method 26 Laboratory Data 

D. Production Documentation 

E. Calibration Data 

iii 

ON 
1.0 INTRODUCTION 

This section describes the purpose, a brief outline including the sampling and analytical strategy, 

and the personnel involved in the test program. 

1.1 Purpose 

The purpose of this sampling project was to determine concentrations, and emission rates of 

hydrogen fluoride from the Sawdust Dryer and Kiln Exhaust Stacks located at the Statesville Brick 

Company in Statesville, North Carolina. The results of the sampling and the documentation 

provided in this report will be used for emission inventory purposes. 

1.2 Outline of Test Program 

Stationary source sampling was performed on May 15, 1997 by the Environmental, Health & 

Safety Division of Trigon Engineering Consultants, Inc. at the Statesville Brick Company facility 

in Statesville, North Carolina. Three 1-hour sampling runs were conducted simultaneously at the 

Sawdust Dryer and Kiln Exhaust Stacks. United States Environmental Protection Agency (US 

EPA) Methods 1 through 4 and Method 26 were used for the determination of hydrogen fluoride 

concentrations, and emission rates. All sampling and analytical procedures used were those 

established by the US EPA in standard reference test methods and appropriate state-of-the-art 

analytical procedures. The test runs were conducted during normal operating conditions. 

1 

6-7 
13 Test Participants 

A list of the project participants, titles, affiliation and telephone numbers can be found below. 

Participant Title Affiliation Contact 

Tom E. Wynn Project Manager Trigon Engineering Telephone: (704) 598-1049 

Consultants, Inc. Facsimile: (704) 598-1050 

E. Logae Buder Environmental Trigon Engineering 

Sciendst Consultants, Inc . 

.L f• A.k N 

John D. Archer Environmental 

Scientist 

Trigon Engineering ~ ~~ 

A

' 

~ w Consultants, Inc. 

Jimmy L. Wallace Environmental Trigon Engineering 

Scientist Consultants, Inc. _=a... 

Brad Brown Technical Services Statesville Brick Telephone: (704) 872-4123 

Company Facsimile: (704) 872-4125 

J--e 
2.0 PROCESS DESCRIPTION 

This section contains a brief description of the process, the type and amount of materials handled, 

and a typical process air flow schematic. 

2.1 Discussion 

The Statesville Brick Company facility located in Statesville, North Carolina manufactures bricks 

in a tunnel kiln. The tunnel kiln was fired with 100% sawdust. Brick cars were being pushed at the 

rate of 19.35 cars per day. Each car was loaded with 6,336 bricks. The fired weight of each brick 

was 3.8 pounds per unit. 

The air from the furnace zone of the kiln flows to the kiln exhaust fan and is then ducted out in two 

directions. The kiln exhaust duct is vented straight to the atmosphere. The second exhaust stream 

goes to the sawdust dryer, through a cyclone control device and then discharged to the atmosphere.. 

Figure 1 details the process air flow schematic from this process. 

Production data during sampling was supplied by Statesville Brick Company personnel and is 

presented in Appendix D. All sampling was performed during material processing. Tests were 

suspended during intermittent periods when the process was not being run. There were no unusual 

process conditions noted during the sampling. 

3 

s~ 
Tunnel Kiln 

Atmosphere 

T 

Stack k—Sampling Location 

T 

Cyclone 

Atmosphere 

T T 

Sawdust Kiln 

Dryer Stack 

T T 

<—Sampling Location 

Tunnel Kiln 

Figure 1 

Process Air Flow Schematic 

0 
3.0 SAMPLING METHODS 

This section describes the sampling strategy, sampling and analytical methods, and quality 

assurance/quality control procedures implemented during this project. 

3.1 Sampling Strategy 

The sampling and analytical procedures used during this test program were those established by the 

US EPA and the North Carolina Department of Environment, Health and Natural Resources (NC 

DEHNR). Sampling runs were conducted in triplicate to validate the sampling. Tests were 

conducted during normal operating conditions. There were no unusual conditions noted during the 

sampling. 

3.2 Sampling and Analytical Procedures 

The US EPA methods used in this sampling program were Method 1 for the location of sampling 

ports and points, and determination of cyclonic flow, Method 2 for volumetric flow rate 

determination, Method 3 for the determination of dry molecular weight of the stack gas, and 

Method 4 for the determination of moisture in the stack gas. Method 26 was used to determine 

concentrations and emission rates of hydrogen fluoride. A sampling and analysis synopsis is 

discussed briefly in the following subsection. These test methods are available in the Code of 

Federal Regulations Volume 40, Part 60 or by request from Trigon. 

3.2.1 Sampling Ports, Traverse Points and Cyclonic Flow Determination 

The Sawdust Dryer and Kiln Exhaust sampling locations were prepared according to the criteria in 

Method 1. The duct diameters upstream and downstream from the sampling ports were determined 

prior to sampling. The number of traverse points were chosen with respect to sampling port 

location. For velocity traverses Method 1 specifies a minimum of 12 traverse points for sampling 

ports located >8h2 downstream/upstream stack diameters from flow disturbances and 24 traverse 

points when located >2/>0.5. The amount of cyclonic flow was determined according to the criteria 

detailed in Method 1. 

F~ 

~l 
3.2.2 Stack Gas Velocity and Volumetric Flow Rate Determination 

Method 2 is used for determining the average gas velocity in a stack from measurements of gas 

density and the average velocity head with a Type S(Stausscheibe or reverse type) pitot tube. This 

method is applicable for quantifying gas flows which meet the criteria of Method 1. Method 2 

cannot be used for direct measurement of gas streams which exhibit cyclonic flow conditions as 

determined by Method 1, Section 2.4. 

In principle measurements of velocity head and temperature are performed at the traverse points 

specified by Method 1. A properly scaled differential pressure gauge was selected for the range of 

Ap values encountered during the traverse. A 0- 10 and 0- 0.25 inches of water inclined 

manometers were used as the differential pressure gauge at the Sawdust Dryer and Kiln Exhaust 

Stacks respectively. 

During this project, the sampling locations met all of the criteria detailed in Method 1. Gas stream 

density was determined by Method 3. Moisture determination was performed by Method 4. The 

principal components of the gas velocity measurement system were sequentially: 

* A calibrated stainless steel Type S pitot tube and Type K thermocouple; 

* Leak-free interface tubing between pitot tube and differential pressure gauge; 

* A 0 to 10 or 0- 0.25 inch inclined manometer and; 

* An 1VIST tra.ceable pyrometer. 

The apparatus was set-up according to manufacturer and reference method recommendations. 

Pretest and posttest leak checks were conducted using procedures outlined in Method 2, Section 

3.1. Velocity head and temperature measurements were performed at the traverse points specified 

by Method 1. The atmospheric and static pressure of the stack was also determined for each set of 

velocity head readings. The volumetric flow rate calculations used were those specified in Method 

2, Section 5. A more comprehensive explanation of the reference method is detailed in the Quality 

Assurance Handbook for Air Pollution Measurement Systems: Volume III (EPA/600/R-94/038c). 

P., 

& 9— 
3.2.3 Dry Molecular Weight Determination 

Method 3 is applicable for determining carbon dioxide and oxygen concentrations and dry 

molecular weight of a sample from a gas stream of a fossil-fuel combustion process. This method 

may also be applicable to other processes where it has been determined that compounds other than 

carbon dioxide, oxygen, carbon monoxide, and nitrogen are not present in concentrations suff cient 

to affect the results. 

In principle a gas sample was withdrawn from each emission source by single-point, grab sampling. 

The collected sample was then analyzed for percent carbon dioxide and percent oxygen. The dry 

molecular weight determination was performed using an Fyrite analyzer. 

During this project, the gaseous components were collected using a Method 3 sampling system 

following the Analytical Procedures outlined in the reference method. The principal components of 

the sampling system were sequentially: 

* A stainless steel probe; 

* A one-way squeeze bulb and saturator tube and; 

* Leak-free transport tubing to transfer the sample to the analyzer. 

The analysis was performed with a Fyrite type combustion gas analyzer at the time of sample 

collection. The dry molecular weight was calculated using Equation 3-1, Section 7 of Method 3. 

The analyzer was maintained and operated according to the instructions recommended by the 

manufacturer and in accordance with Method 3 criteria. The Fyrite analyzer was validated by 

analyzing a sample of ambient air which was verified to be 21.0% ± 0.3%. 

7 

0 
3.2.4 Moisture Determination 

Method 4 involves the determination of stack gas moisture. Stack gas moisture must be measured 

when the flue gas flow rate or a pollutant gas concentration is determined. The moisture content is 

used to correct the emission concentration or mass emission rate to a dry basis. EPA Method 4, 

Section 3.3 of the EPA's Quality Assurance Handbook, Volume III, EPA-600/4-77-027b, was used 

to measure stack gas moisture content. Section 3.3 of the Quality Assurance Handbook, Volume 

III, provides detailed information on the application of Method 4. 

The flue gas moisture content was determined using wet bulb/dry bulb thermometers and pardal 

pressure, vapor and saturated vapor pressure equations along with the reference method 

incorporated into the Method 26 sampling train. The wet bulb/dry bulb technique is described in 

Method 4 and is summarized below: 

* Moisten the wet bulb thermometer wick with deionized water; 

* Insert both thermometers into the flue gas stream and monitor the wet bulb temperature; 

*. When the wet bulb temperature has stabilized, record both the wet bulb and dry bulb 

thermometer temperatures; 

* Calculate the flue gas moisture content (PMV) using the equations below. 

SVP = Vapor Pressure of Water at Saturation, inches of Mercury 

SVP =10xy(6.6911- (3144/(Wet Bulb + 390.86))) 

PMV = Percent Moisture by Volume 

PMV =(SVP -(0.000367(P,bADry Bulb - Wet Bulbxl +((Wet Bulb - 32)/1571))))1(P bJ x 100 

P.,s= Absolute Pressure of Stack Gas 

Pab, = (Barometric Pressure + (Static Pressure/13.6)) 

A summary of the reference method will be described in the Method 26 sampling and analytical 

procedures. 

8 

49 ~ 
3.2.5 Determination of Hydrogen Fluoride 

Testing for hydrogen fluoride was performed according to EPA Method 26. Gaseous and 

parkiculate pollutants were withdrawn from the emission source and collected in a multicomponent 

sampling train. In principle, particulate matter includes any material that was condensed at or 

above the filtration temperature of approximately 250 degrees Fahrenheit and was collected on a 

quartz glass fiber filter. The gaseous components were then bubbled through a measured volume of 

0.1N sulfuric acid and 0.1N sodium hydroxide to determine moisture and hydrogen fluoride content 

of each emission source. The principal components of the sampling system were sequentially: 

* A borosilicate glass sample probe; 

* A heated (248°F f25°F) probe and filter assembly with quartz glass fiber filter; 

* An impinger train consisting of four sequential impingers. Impingers 1 and 2 containing 15 

ml each of O.1N sulfuric acid. Impinger 3 contained 15 ml of O.1N sodium hydroxide 

followed by an impinger containing 20 grams of silica gel; and 

* A critical orifice metering system capable of maintaining a 2.0 liter per minute sampling 

rate and accurately deterniining the sample volume according to those specifications in the 

reference method. 

Sample clean up began immediately after each test run. Hydrogen fluoride was collected in the 0.1N 

sulfuric acid solution in impingers 1 and 2. The liquid in these impingers was measured to the nearest 

milliliter. The collected sample was placed in a glass storage container along with the deionized water 

rinse of impingers 1 and 2 and connecting glassware. The container was sealed and the liquid level 

was marked. The hydrogen fluoride samples were then shipped to Enthalpy Analytical, Inc., Raleigh, 

North Carolina with chain of custody documentation where they were analyzed by ion 

chromatography. The liquid in impinger 3 was measured to the nearest milliliter and discarded. The 

moisture collected by the silica gel in the fourth impinger was determined to the nearest 0.1 gram. All 

collected condensate measurements were recorded on the moisture determination and sample analysis 

data recovery form. The laboratory analyses and chain of custody documentation can be found in 

Appendix C. 

9 

/ 

(f~

•;7 
3.2.6 Sampling Ports and Points 

The dimensions of the Sawdust Dryer and Kiln Exhaust sampling sites and the location of the 

sampling ports and points are detailed in Figures 2 and 3. Method 1 sampling criteria was 

maintained in each instance. The stack cross sections were divided into the appropriate equal areas 

as detailed in Method 1. The ports were labeled using sequential alphabetical notation. Sampling 

for hydrogen fluoride was performed at a single representative point during each 60 minute 

sampling run. Velocity traverses were performed before and after the Method 26 sampling runs to 

determine the volumetric flow rate of each emission source. 

10 

'O-0 
Sawdust Dryer Ezhaust Stack 

.~ 

, 

. ~ 384" . r ~ j: 

29.5" --/' h 

FMI 

~ sEC 1-10w K—. 

1 1 

K K 

110.5" 

Not to Scale 

Figure 2 

Location of Sampling Ports and Points 

11 

~7 
37.5" 

~-38.0"-~ 

~ 

33" 

~ 

I 

240" 

~ 

~ 

. 

. 

. 

. 

. 

. 

. 

. 

. 

! 

i . 

~ 

. . . . . ~ 

. . . . . ~ ~ 

. . . . . ~ A B C D E 

SEC?ION K—K 

~ 

r 

K 

~ 

1 

K 

Kiln Ezhaust Stack 

Not to Scale 

Figure 3 

Location of Sampling Ports and Points 

12 

IN 
3.3 Quality Assurance and Quality Control 

Trigon Engineering Consultants, Inc., has established quality assurance and quality control 

(QA/QC) guidelines for providing the highest quality sampling and analytical data from source 

tests. These QA/QC procedures were implemented to ensure the acceptability and reliability of the 

data generated. 

In summary, a high degree of data quality was maintained throughout this project. All 

instrumentation leak checks and QA criteria were met. Quality control procedures for Method 26 

have included the analysis of a reagent blank. The results of the reagent blank and quality control 

procedures can be found in Appendix C with the laboratory data. 

Field data and final laboratory results were entered into Trigon's Air Quality Data System by an 

environmental scientist, independently audited by the Project Manager, and reviewed by the 

Quality Assurance Manager for verification of data. After. QC review by the QA Manager, the 

Department Manager verified the final report for completeness and reasonableness of data. The 

report was returned to the Project Manager for review and preparation of the final draft. The report 

requires the signature of the Project Manager, QA Manager, and the Department Manager before 

release to the client. Data and final reports are archived in a secured area for a minimum period of 

three years. 

Trigon's field and iaboratory test equipment has been maintained and calibrated in accordance with 

quality assurance procedures established by the US EPA in the Quality Assurance Handbook for 

Air Pollution Measurement Systems: Volume III. Equipment calibrations including pre-test and 

post-test calibration data are presented in Appendix E. 

13 

bC// 
4.0 RESIJLTS 

This section presents the mean hydrogen fluoride sampling results. Tabular results are also 

provided to present data from individual sampling runs collected during this project. Detailed 

sampling results and example calculations for the test program can be found in Appendix A. Field 

data sheets are presented in Appendix B. 

4.1 Summary of Results 

The table below is a synopsis of the hydrogen fluoride sampling conducted at the Sawdust Dryer 

and Kiln Exhaust Stacks. 

Hydrogen Fluoride Sampling Results 

Sawdust Dryer Kiln Exhaust 

Concentration, lbs/dscf 1.54E-06 5.65E-06 

Emission Rate, pounds/hour 1.48 1.40 

Emission Rate, pounds/ton 0.15 0.14 

4.2 Discussion 

Results from this test program will be used by the Statesville Brick Company for emission 

inventory purposes. 

43 Detailed Stack Sampling Results 

Tables 1 and 2 present the data from individual sampling runs at the Sawdust Dryer and Kiln 

Exhaust sampling sites. Included in these tables are gas velocity and volumetric flow rates, exhaust 

gas temperatures, and hydrogen fluoride concentrations, and emission rates. 

14 

JL~ 
TABLE 1 

Summary of Results, Hydrogen Fluoride Sampling 

Sawdust Dryer Exhaust Stack 

Run Number 1 2 3 Avg. 

Date 05/15/97 05/15/97 05/15/97 

Run Duration, Minutes 60 60 60 

Sample Time, 24-hour clock 1100-1200 1240-1340 1400-1500 

Average Stack Temperature, °F 184.8 183.5 179.9 182.7 

Stack Gas Velocity, feet/second 80.5 80.9 81.5 81.0 

Stack Gas Flow Rate, 16077 16006 16132 16072 

dry standard cubic feet/minute*(DSCFIVl) 

Stack Gas Flow Rate, 22938 23050 23225 23071 

actual cubic feet/minute(ACFl1) 

Hydrogen Fluoride: 

Catch, mg 2.08 2.73 2.95 2.59 

Concentration, lbs/dscf 1.23E-06 1.61E-06 1.78E-06 1.54E-06 

Emission Rate, lbs/hr 1.18 1.55 1.72 1.48 

Emission Rate, lbs/ton 0.12 0.16 0.18 0.15 

* 68°F, 29.92 Inches Hg 

15 

~6 
TABLE 2 

Summary of Results, Hydrogen Fluoride Sampling 

Kiln Exhaust Stack 

Run Number 1 2 3 Avg. 

Date 05/15/97 05/15/97 05/15/97 

Run Duration, Minutes 60 60 60 

Sample Time, 24-hour clock 1100-1200 1240-1340 1400-1500 

Average Stack Temperature, °F 509.7 530.3 526.0 522.0 

Stack Gas Velocity, feet/second 14.8 14.5 14.8 14.7 

Stack Gas Flow Rate, 4211 4061 4144 4138 

dry standard cubic feet/minute*(DSCFIVI) 

Stack Gas Flow Rate, 8763 8606 8790 8720 

actual cubic feet/minute(ACFNn 

Hydrogen Fluoride: 

Catch, mg 7.21 8.16 12.7 9.36 

Concentration, lbs/dscf 4:28E-06 4.96E-06 7.72E-06 5.65E-06 

Emission Rate, lbs/hr 1.08 1.21 1.92 1.40 

Emission Rate, lbs/ton 0.11 0.12 0.20 0.14 

* 68°F, 29.92 Inches Hg 

16 

ly- 
5.0 APPENDICES 

This section contains detailed supportive documentation that encompasses all aspects of the 

emission test program. Its contents serve as the foundation for the test report. The emission test 

report presents a summary of the information gathered during the sampling activities. The 

information contained in the appendices is necessary to facilitate the review of the emission test 

report and determine whether proper procedures were used to accomplish the test plan objectives. 

Defensible data and the subsequent pollutant concentrations and emission rates is one of the 

primary objectives of any emission test program. To this end, all results, example calculations, 

field data sheets, sample recovery, laboratory results, chain of custody documentation, and 

equipment calibrations have been provided to support these objectives. 

17 

~3 
APPENDIX A 

SUMMARY OF RESULTS AND EXAMPLE CALCULATIONS 

w., /Y 
SUIVIMARY OF RESULTS 

EPA METHOD 26 

Determination of Hydrogen Halide and Halogen Emissions 

Statesville Brick 

Statesville, North Carolina 

Sawdust Dryer Exhaust Stack 

2 

05/15/97 

60 

28.71 

-0.096 

28.614 

111.6 

75.1 

3.73 

10.3 

0.49 

0.115 

11.5 

0.885 

17.0 

4.0 

0.0 

29.320 

28.017 

0.84 

1.26 

183.5 

80.9 

4.75 

16006 

23050 

Run 1 

Date: 05/15/97 

TT Net Time of Test, minutes 60 

PB Barometric Pressure, in. Hg 28.75 

SP Static Pressure, in Hg -0.081 

PS Stack Pressure, Absolute, in. Hg 28.673 

VM Volume Gas Sampled, Liters 112.2 

TM Avg. Gas Meter Temp., Deg. F 77.3 

VSTD Volume Dry Gas Sampled, Standard cu. ft. 3.74 

VM Volume of Water Collected, ml 9.5 

VMV Volume of Water Vapor, Standard cu. ft 0.45 

Bws Moisture Content of Gas Stream 0.107 

PMV Percent Moisture 10.7 

MFD Mole. Fraction Dry Gas, lb/lb mole 0.893 

P02 Percent Oxygen, Dry 16.5 

PCO2 Percent Carbon Dioxide, Dry 4.5 

PCO Percent Carbon Monoxide, Dry 0.0 

MD Mole. Wt. Stack Gas, Dry Basis, lb/lb mole 29.380 

MW Mole. Wt. Stack Gas, Wet Basis, lb/lb mole 28.164 

CP Pitot Tube Coefficient 0.84 

DPS Avg. Sqrt. Delta P, in. H20 1.25 

TS Avg. Stack Temp., Deg. F 184.8 

VS Avg. Stack Velocity, ft/sec 80.5 

AS Area Stack, Ft2 4.75 

QS Gas Volume Flow, Dry Std. Cond., CFM 16077 

QA Gas Volume Flow, Actual, CFM 22938 

A-2 

3 Avg 

05/15/97 - 

60 - 

28.70 28.72 

-0.110 -0.096 

28.590 28.626 

109.8 111.2 

76.3 76.2 

3.66 3.71 

10.5 10.1 

0.49 0.48 

0.119 0.114 

11.9 11.4 

0.881 0.886 

18.0 17.2 

3.0 3.8 

0.0 0.0 

29.200 29.300 

27.867 28.016 

0.84 0.84 

1.27 1.26 

179.9 182.7 

81.5 81.0 

4.75 4.75 

16132 16072 

23225 

- ' 

~ TFRIGON 
SUMMARY OF RESULTS 

EPA METHOD 26 

Determination of Hydrogen Halide and Halogen Emissions 

Statesville Brick 

Statesville, North Carolina 

Sawdust Dryer Exhaust Stack 

Hydrogen Fluoride Concentrations and Emission Rates 

FMF Hydrogen Fluoride Catch, mg 2.08 2.73 2.95 2.59 

CAN Hydrogen Fluoride Concentration, lbs/dscf 1.23E-06 1.61E-06 1.78E-06 1.54E-06 

CAW Hydrogen Fluoride Emission Rate, lbs/hr 1.18 1.55 1.72 1.48 

"3 7F 
SUIVIMARY OF RESULTS 

EPA METHOD 26 

Determination of Hydrogen Halide and Halogen Emissions 

Statesville Brick 

Statesville, North Carolina 

Kiln Exhaust Stack 

2 

05/15/97 

60 

28.71 

-0.0004 

28.710 

110.4 

83.8 

3.63 

6.5 

0.31 

0.078 

7.8 

0.922 

16.0 

5.0 

0.0 

29.440 

28.550 

0.84 

0.18 

530.3 

14.5 

9.90 

4061 

8606 

Run 1 

Date: 05/15/97 

TT Net Time of Test, minutes 60 

PB Barometric Pressure, in. Hg 28.75 

SP Static Pressure, in Hg -0.0006 

PS Stack Pressure, Absolute, in. Hg 28.749 

VM Volume Gas Sampled, Liters 112.2 

TM Avg. Gas Meter Temp., Deg. F 81.4 

VSTD Volume Dry Gas Sampled, Standard cu. ft. 3.71 

VW Volume of Water Collected, ml 7.0 

VMV Volume of Water Vapor, Standard cu. ft 0.33 

Bws 1Vloisture Content of Gas Stream 0.082 

PMV Percent Moisture 8.2 

MFD Mole. Fraction Dry Gas, lb/lb mole 0.918 

P02 Percent Oxygen, Dry 16.5 

PCO2 Percent Carbon Dioxide, Dry 4.5 

PCO Percent Carbon Monoxide, Dry 0.0 

MD Mole. Wt. Stack Gas, Dry Basis, lb/lb mole 29.380 

MW Mole. Wt. Stack Gas, Wet Basis, lb/lb mole 28.452 

CP Pitot Tube Coefficient 0.84 

DPS Avg. Sqrt. Delta P, in. H20 0.19 

TS Avg. Stack Temp., Deg. F 509.7 

VS Avg. Stack Velocity, ft/sec 14.8 

AS Area Stack, Ft2 9.90 

QS Gas Volume Flow, Dry Std. Cond., CFM 4211 

QA Gas Volume Flow, Actual, CFM 8763 

A-4 

3 Avg 

05/15/97 - 

60 - 

28.70 28.72 

-0.0006 -0.0005 

28.699 28.719 

110.4 111.0 

83.8 83.0 

3.63 3.66 

6.9 6.8 

0.32 0.32 

0.082 0.080 

8.2 8.0 

0.918 0.920 

17.5 16.7 

3.5 4.3 

0.0 0.0 

29.260 29.360 

28.335 28.446 

0.84 0.84 

0.19 0.19 

526.0 522.0 

14.8 14.7 

9.90 9.90 

4144 4138 

8790 

MoN 
SUMMARY OF RESULTS 

EPA METHOD 26 

Determination of Hydrogen Halide and Halogen Emissions 

Statesville Brick 

Statesville, North Carolina 

Kiln Exhaust Stack 

Hydrogen Fluoride Concentrations and Emission Rates 

FMF Hydrogen Fluoride Catch, mg 7.21 8.16 12.7 9.36 

CAN Hydrogen Fluoride Concentration, lbs/dscf 4.28E-06 4.96E-06 7.72E-06 5.65E-06 

CAW Hydrogen Fluoride Emission Rate, lbs/hr 1.08 1.21 1.92 1.40 

i 

A-5 1 / 0 ~_ 
SUMMARY OF RESULTS 

EPA METHOD 26 

Determination of Hydrogen Halide and Halogen Emissions 

Statesville Brick 

Statesville, North Carolina 

Kiln Exhaust Stack 

Example Calculations Run 1 

Pressure of Stack, Absolute, in. Hg 

PS = PB - SP = 28.749 

Volume of Water Vapor, Standard cu. ft 

VMV = 0.04709* VM = 0.33 

Moisture Content of Gas Stream 

VMV 

BWS= --------------------------- = 0.082 

VSTD + VMV 

Percent Moisture 

100 * VMV 

PMV= -- ----------- ------------- = 8.2 

VSTD + VMV 

Mole Fraction of Dry Gas 

100 - PMV 

MFD = ------------------- --- = 0.918 

100 

Mole. Wt. Stack Gas, Dry Basis, lb/lb mole 

MD = 0.44 * %CO2 + 0.32 * %02 + 0.28 * (100 - %CO2 - %02) = 29.38 

Molecular Weight of Stack Gas, lb/lb mole 

MW = MD * MFD + [18 *(1-MFD)] = 28.452 

Stack Gas Velocity at Stack Conditions, ft/sec 

VS = 85.49 * CP * DPS * SQRT (TS + 460)/(PS * MW) = 14.8 

Dry Gas Measured Corrected To Standard Conditions, cu. ft. 

T(std) PB 

VSTD = Vm *0.0351 * Y * * _--- = 3.71 

TM P(std) 

Stack Gas Volumetric Flow at Standard Cond. Dry, CFM 

1058.82 * VS * PS * (1- Bws) 

QS = -- ----- -- ----- --- ---- ---- = 4211 

TS + 460 

A-6 
SUMMARY OF RESULTS 

EPA METHOD 26 

Determination of Hydrogen Halide and Halogen Emissions 

Statesville Brick 

Statesville, North Carolina 

Kiln Exhaust Stack 

Stack Gas Volumetric Flow at Actual Cond. CFM 

QA = AS * VS * 60 = 8763 

Hydrogen Fluoride Concentration, lbs/dscf 

(At Standard Conditions) 

2.205e-06 * F1VIF 

CAN = ----- ------------- -- ---- ---- 

VSTD 

Hydrogen Fluoride Emission Rate, lbs/hr 

(At Standard Conditions) 

CAW= 60*CAN* QS = 

4.28E-06 

101 

Standard Conditions 68 Deg. F, 29.92 inches Hg 

A-7 ~ 
APPENDIX B 

FIELD DATA SHEETS 

B-1 U ~ 
` Point 

Yoa 

~ 9ft u( :" 

St.aic ID 

sStadt . : 

m: 

:. Df9tahoar.Pco ~o-. . 

L~~Iae:Virall 

: ~iippte 

ieaqtk 

Distaaw ~ From: 

: On[s ~ de uI Porr 

~ ~ •1 I ay.s v.~~ O I o.6d a ~O 

3 i~.~ zq S 3• 5~ ~ 3• y$ 

17.7 Za. S ,S- -2 a. o :Y .AA 

s 2~ v z4.S 7• 0 ~•3~ 

~ 3sZ, Zq. S O 

7 

3, 7V 0 zq.S -L ~2. 13 

q 'F2 ,3 2 r. S a y. O 2 y..2,Y 

i° 8R•.) 7-4.S -2G. O 

it 93• 3 ZK. S 7..r.2 0 

ia 77,7 Za. S.2.y 9.t7 v -,Ra 

B-2 

♦ ~ 6 ~ n ! 

~ .7 ~ a♦ ~ 3. 1 

•~ I • t 5 'e-5 1.2 s.' ! 

.6 . ay i . a 6 .. a i 

M.1 =6 17.7 

a & 7 u+ L. 

1!2 97.9 

Audited br.&6 Dua > >Y 7 

~QA) 

EPA iLlethod 1 

Determination of Sampling Ports and Points 

CGient feSr/: Ile A<',,4.4 City/State st'~sv-. /~~ .~/C 

Sampling Location 0r*et- F~rL,y.,rst Date oS//!tf /9 7 

Sampling Location Dimensions: 

From Far Wall to outside of Pott 

Nipple Length 

Depth of Duct 

Width (Rectangular Duct)gfid 

Equiralent Diameter Calcttlation (DE): 

: z Lensth s Width 2 (.411 

DE= 

Length + R/idth ( Alt i- i(/lf ) 

Distance to Ports From Nearest FIow Disturbanca 

Upstreatn - A Downsueatn - B 

Dimensions in Inches • y 

Duct Diametets % 3• vy ~ 

Stacic ,iirea, in Squar® Feet If. . 75 

Calculations By 'Tt-w 

DlSTURBaNCE 1— 

a 

SAA/PLI,VC 

LOCaTlON r i 

t I r 

K 1 ( 

D/STtJRBa,vCE 

Schemalic oj Samplirrg Location 
EPA 1Vlethod 2 

Determination of Stack Gas Velocity, Volumetric Flow Rate and Cyclonic Flow 

Client SfWfnv;l,~-z 

Sampling I.ocation54.~~-sr ~~r~u Er/.. 4. r' 

Run Date -r 

o5/lyIv 

Barometric Pressure, in. Hg y0 

Static Pressure, in. HZO -`, 11 D 

Static Pressure, in. Hg - o. 103 

Stack Pressure, in. Hg ZQ .`60 

Stack Dimensions, in., diameter/side 1 Za•s 

City, State !le cOperators SLW ~ ,TD A 

T'itne /'S-o 0 

Pitot Tube I.D. No. 207J. OZg 

Date Calibrated o t ,) 31 R 7 

Pitot Tube Coefficient d ' 

Leak Check, in. H20 <0.1 @ 3.60 

Side 2, in. — 

Field Data 

11 0 

: 

~ 

A o 

®~~~~~®© 

©~~~~~j~:i~~ • 

• 

~~~ ~~~~ • • ~ 

~~® •~~~ • . ~ , 

©~ ~ • ~ ' ~tSi~~ ~ ~ ~ 

~®~~ ~~ . , s 

~~~~~~■■~~~ 

Stack Temperature, Dry, °F (A) Stack Temperature, Wet °F (B) % -A ~ 

Difference (A - B) (aN Preliminary Percent Moisture / 0 . ~ 

~ 

m cy:&nacG ~ i 2a ~ 1 B-3 
lFSY..S-r 16U.1 -- 

Date:US / Zo / J '7 

'b `I ;) Zj 6- j i~ r? 

EPA Method 2 

Determination of Stack Gas Velocity and Volumetric Flow Rate 

Client 

Sampling Location P-x XGG-SfRun Date CSAs 97 

Pitot Tube I.D. No. '~bo. o'z 7 

Date Calibrated 01103117 

Stack Dimensions, in., diameter/side 1 a cf..5 '1 

City, State 

Project Number 0Rl61 - 17- olz(o 

Operators JLC-~ 

Pitot Tube Coefficient, CPD. 8y 

Leak Check, in H:O <0.1 @ 3• o 

Side 2, in. .v.4- 

Field Data 

Run No./Sam le No. 1 a 3 E ° 

Time 24-Hour Clock) ov /2 '/o /A/6,-> 

Bar. Press..in. H¢ 9,8• 79 $_'7 oL 

Static Press., H.O — — 4 /D 

Static Press., in. He - 0 , O y l - 0 . 0 9 ( - p , 0 5 - Q . ( 5 

Stack Press., in. Hg (0, Z1-. 51 Zf, S 

Stack Tem ., Drv, v*-Or- D 17.5 -&1X1 117 

Stack Tem ., Wet, Z.S (ZL.Q 17S 

Difference,'F (.+1O lt0 C? ( 3 

Moisture. % 0 1 n • 5 1 1 . 4i l . 11 

Tiaversa 

Eoint' 

N'umt ~ er 

,: Velodty 

Head Op .:: 

Inches H U: 

Stack>' 

Temperaturr 

> ~£ °G 

Vdocity : 

.:; IIeadAp: .: 

I'ndkes i~0:> 

Stadc ° 

Temperature 

°I? 

Yeladty 

`,:Head Ap 

Inches S.0 

Stadc:: 

Tempeeatuee - 

'S': .: 

velocity;:: 

Head Ap:: 

Inches IiGO: 

Stad[ 

. Temperature< 

'7$ 

'Av 36 I,Io 79 

3 /.aa F:z ,3d 9(1 1,30 70 

y / 60 88 /•Y~ p.2 /,.~ 96 l.yo 7$ 

.s /•6110 /~~5 EL /. 79 

i -Go Sg /, G .3.3 R6 

~ . 9b 9-9 a. b o 3 ~ F 

g ~..~0 ~B a,/S" R3 a.lo $(~ `3.30 -79 

ri a, l l~ ~ 7 • ./:S+ 0".3 a. vv F(0 0, / 0 7`7 

92 . 96 83 ~11 , ~50 96 / o8o -7 8 

r. Jv S.;L l.ivo '7g 

Averages I os~ ~ 7,s /o63 92,3 %.G3 ~G.~ l.~~ 7x.3 

I if.7 

r7 g TFZIGON I 
EPA Method 3- Molecular Weight Determination - Data Analysis 

Client Name lejv+l lt Q'n C ~— Project Number02( 1,'I 7' 0(f 1,19 

Ciry/State ~S✓~~ 11{- , nlC- Sample Date & 47 

Sampling Location ~GI~T ~r4tv-EX.6,,,+, Operator G- ~3 

Sample Type a Tedlar Bag o Multipoint BK Single Point Fuel Type wImcl 

Analyzer Type Fvrite Serial # ~r~C'• z (z O-Oxygen Calibration Check Must Be 20.9 ± 0.1% 

Run # and/or Sample ID Sampiing Time (24 - Hour C1ock) ((Lo 

Gas ' Re licate 1 Re iicate 2 Re iicate 3 Average: 

Percent 

Multiplier- Moiecular Weigbt 

Actual Drp lb/lb mole> ' Net- Actusi Net Actual Net' 

CO: 

032 - o 

N; . 100 ; y.O ` 100 '79. D:. 100 79. U 7q, crn 0.28 

Total 2q, 3go 

Run # and/or Sample ID Z Sampling Time (24 - Hour Clock) 13 0-0 

Gas Re licate 1 Re Iicate 2` ' Re licate 3 Average> 

Percent 

Muitiplier Moiecular Rreiglit 

Actual Net Actuai Net Actual Net Dry lbllb mole 

CO= 41,0 y. o L1 u 4~ o 4. ° a il. O-D o:a4 1,700 

°= I D l ~ •D 7. 0 7. D ?. O 1?.0 1 ('T. cSD 032. 5. Nq D. 

N. 100 ?R.o ; 100 ?y.a . 1W J 71.0 1 '79- 0U 0Z8 Z~ 120 

Total 24 . 3 20 

Run # and/or Sample ID 3 Sampling T'ime (24 - Hour Clock) 14 ZD 

Gas- Re licate 1 Re licate 2 ReiDlicater3 

I Average. 

Percent 

Multiplier Molecular Weigbt 

Actual Drg IbJib moie: I Net Actual Net Actual" Net 

C00. 3.0 3. 0 3. 0 3•a 3.a 3-r.) 3,Oa 0.44 ~ 3 Zo 

°- iT.0 $,o !?,o lg,o lg,o 18.0 rd'.oZ) 0.32 5.?a J 

N, 100 ?q. 0 100 100> ': 14. 0 0" 0.28 Z2 ( Z. d 

Total 

udited by:.1DA— Date:5-/I ~ /11 

MR ~ 
EPA Method 26 Determination of Hydrogen Chloride Emissions 

ClientJ f w~s i/ .~~~ Qr~c Run Number 1 

City/State <{~.{:!~sv Ile Date osf/~s"/5 7 

Sampling Location .~~~~ .sf c~~a~ CK~.a.r Operators S/- 4,> 

Amb. Temp., °F 76 SET-UP DATA LEAK CHECKS 

Bar. Press., In. Hg. vZg ,79 Console Dry Gas Meter Coefficient Y= /. 0O Pre-Test D•fC ® /J_' In. Hg. 

Static Press., In. H2O ' (• (y Purge Time .S`,,.,;.. Purge Rate '~,~ << Post-Test y•/d @ /,-f'_ In. Hg. 

a gb~.o28 

Meter Box No. 1~bb~ bs-1> Stack Temp. E~6' ' 19 O ~ Pitot Tube No. Pre-Test Pitot <0.1 @3•')In. HZO 

Sample Box No. Wet Bulb Temp1 Zt{ O F Pitot Coeff. O.gSI Post-Test Pitot <0.1 @3• 4.)In. H2O 

Pitot No. a op • nX6 % Moisture 101 Orsat System ,fi4 Tedlar Bag No. _y4 

~ 

Probe Temp. Setting JAd Start Time%/O6 End Time l2 OO Bag Leak Check _,t1_4 

Sample ID No. 7C2/do — O/ Sample Container No. 1 Level Marked ✓ Observer i4oTlE 

Sampie 

Rur► . : 

Time 

Iv1u{utes_ 

Clock 

: : ..Time 

24 Hour :.. . 

Cloek. > 

Flow . Meter ' :.. 

Setang 

Liters/Minute 

Dry Gas 

Meter 

Vol'ume: 

Titers : . 

Dry. Gas 

Meter : 

Temperature 

S °Ti °G .,. 

,. 

Pump 

Vacuum 

Inclses 

H 

Stack 

Temperature 

Y~` C.. 

0 

C[., 

5 

10 ///U 2 

15 :s °L a.S20 

.2 y 

25 

30 113 0 

35 1 13L 

40 // qU a ~ ~ /~/ ° 

45 

50 

55 

60 

87. 3g 

773 °F 189.3 -rComments 

?re +C.4 'C /- ,LS `+ o.s t h-.3t C' /b c" 

~• ~ ~ 

,'77 

' y, ,.77 

1 .y3 

1.213 

lya • 5 `/ 

 , . y 3 

(2) 

A✓e 

1.97 

I 

-6 

B 'i-zet "~ c S Z~ y 7 ~ 

TF~IGOf V' 

,~„~ ~. ~ / / 
EPA Method 26 Determination of Hydrogen Chloride Emissions 

Client Run Number a 

Ciry/State Date 63'1,5A .7 

Sampling Location Operators 

Amb. Temp., °F 76 SET-UPDATA 

Bar. Press., In. Hg.a$ • 7 ~' Console Dry Gas Meter Coefficient Y= 

Static Press., In. H,.O -/• /y Purge Time J-i„ :., Purge Rate 

~ 

Meter Boz No. SiDO -GS'O Stack Temp. 1 ~3s ~ Pitot Tube No. 

3~ w . 

Sample Boz No. ~d.. ~ Wet Bulb TemplZs F Pitot CoePf.y,g`/ 

LEAK CFIECKS 

Pre-Test O. (j.A @ /-S In. Hg. 

Post-Test O.OS' ® /J' In. Hg. 

Pre-Test Pitot <0.1 @ 3 - y In. H:O 

Post-Test Pitot <0.1 ® 3-° In. H:O 

Pitot No. :)L aa . o a 8 % Moisture 10 Orsat System Tedlar Bag No. ti4 

ProbeTemp. SectingQ0 r~ 

Start Time / 2 YU End Time 13 yo Bag Leak Check /4-,4 

Sample ID No.'7o44 - 0 2 Sample Container No. Z Level Marked ✓ Observer n1odNFS amp le 

Run 

Time .: 

Minutes :`: 

Cfock 

Time 

24 Hour 

Clack. 

Ffow. 

Meter.. .. 

Setting : E iters/Ivlmute 

,. 

D Gas 

. rY 

Meter .: 

Volume 

'`Lifers. 

D Gas rY 

Meter , 

Temperature 

bf ~ 

Pum P. : ;. Vacuum 

H¢ 

Inches 

Stack. ; 

Temperature: 

0 :d yo 

5 1.219T 

10 I a So 

15 ;2bs' 

20 l300 

25 13ckS- 2 .2y >`/o g~ 

30 13/0 85, 

35 131.5— .Z 7, ` I `I o e`'/ 

40 1 3.)v ~ a ~`!~~ ciS' 

45 ► 315- 

50 1330 a` 

55 ~ 3a3 ~ a 91,4 

60 

7,5' 1 '7 F /23.s ° ~ 

Cotnments 

q,5 S 

~QA 

% •?~' 

/•~5 

e26 

ast tts+ ~u 

/, 8S 

B-7 A,,,1,4 ef 8-f : Ti3A 
EPA Method 26 Determination of Hydrogen Chloride Emissions 

Client e^"k Run Number 3 

Ciry/State Date 04-/iS/97 

Sampling Location6~ r.s"s+ Q~rer- ~ic%.,,.st' Operators JLC,J 

Bar. Press., In. Hg.29 .70 

Static Press., In. HZO' / •3-0 

Meter Box No. 

Sample Box No.1 

Pitot No.'loo. >Xg 

Probe Temp. Setting 1 o1c 

Sample ID No. 7066 ~8 

Console Dry Gas Meter Coeffici( 

Purge Time L~ •r+ •h 

Stack Temp. l?it lAV P 

Wet Bulb Temp 

% Moisture 

Start Time 

Sample Container No.3 

v Y - /- d0 

Purge Rate 

Pitot Tube No.'A&o•o%8 

Pitot Coeff. 0 - 04 

Orsat System--f--4 

End Time/J'b y 

Level Marked ", 

LEAK CHECKS ~ 

''3..3 

Pre-Test a" /o @ In. Hg. 

Post-Test O.io (a 13. 3 In. Hg. 

Pre-Test Pitot <0.1 ®-3' ° In. H20 

Post-Test Pitot <0.1 Q30 In. HZO 

Tedlar Bag No.141-4 

Bag Leak Check /!iA 

Observer 1%fbWCAmb. Temp., °F --) 6 SET-UP DATA 

Sample 

Run 

Ttme ': 

~Iinures 

Clock 

Time 

24 Hour : Clock 

- 

Flow 

Meter . Settittg 

Litecs/Minute. 

Dry Gas . Meter; . 

Volume .:. 

: Liters ` 

Dry Gas :> 

Meter 

Te;nperature . 

'F 

r 

Stack 

Temperattue 

o 

5 l y b~ ~ ~ ~/ /-440 S~ 

10 N/o a 

15 1W/ ' E3 

20 I4;0 ~, 2 s' /y. v ? eZ 

25 iy~

s' ~''a 

30 / 43E' a =Z q 

35 /`/35— 2 215 

40 /yyo 

45 1y5c5' q 1s~ /~/. 0 7 r 

50 1 y5a ~ i 2.s~ / L/ . o -? g 

55 

~/. t7 72 

60 lS6° — ~ ~/ .O 72? 

)l`/°G1 

76 , 3 or / 7 F. 9 ~ 

Cotnments 

/, ~ y .~ 3 

~ , s3 ,~~ 

Q ~ 

),Y i 

.~; 

QA I, i3 7 

1.3 3 B-8 

I 

I ~ 

4...8 1._f O 'r.r nr/—l— 
EPA Method 26A - Moisture Determinat 'on and Sample Reeovery - Data Analysis 

Client Name ST~~SVt ( I Q J3r , C ~ ProjectNumber 0716 -Q'J- O(c~F 

Ciry/State A1C Sample Date z //J /qi' 

Sampling Location S44Jd DryW Samples Recovered By G-1-13 

Clean-Up Box Number . 1.10 Recovery Date 09I51R7 

Chain of Custody: Date Received Received By Locked? ~ 

Equipment Documentation 

Run Number l Z 3 

Sam le ID Number bto - 01 70tz(j- OZ- 70C.1a - 03 

Sam le Box Number I Z 

Probe Number ✓ ~ — 

Analysis of Moisture Recovery 

ReaRent Recovery Container # '701oi, -0I ?04(o -02- ?666 - 03 

Im in2er Absorbiniz Solution 0, 1 N NZSJ q 0. 1 /'J +L_5 0zi 0. N 14ti9 0 4 

Descri tion of Rea¢ent c4Zcw G4eufReaLyent Level lVlarked? ✓ ✓ 

Final Volume, ml 2,~ 3g.4 2*-3-39•3 2*t—o 31.14 

Initial Volume, ml 43 30 -htFl 30 -44~_ 30 

Net Condensed Volume. ml 9. 1 0 4•3 q.lo 

_. .... . 

Reaizent Recoverv Container # 70t0(0 - 0 0~ -DZ 17012io -0 

Im in er Absorbina Solutiou 0. N NaO R 0.1 nj nJa.q tt 0. {/V voOH 

Descri tion of Reasent c,(ear zar CA lay , 

Reaeent Level Marked? ✓ -~ ✓ 

Final Volume. ml (S, 2 l 

Initial Volume. ml I 5 1 S I S 

Net Condensed Volume. ml 0, 2 ~ .2 0,1 

Silica Gel Recovery Container # ZOlz(. - ol atil, -OZ G - 03 

Percent Silica Gel S eut ys L) 50 

Final Weisht,Q 20.7 7,0•8 Zo.$ 

Initial WeisEht. o ZD Zo ZD 

Net Absorbed Water. e 0.7 0. a 0. g 

Total Reavent Collected, v 10,3 0.5 

Sample Recovery 

Recoverv Container # 70(z6 -0 70u10-OL 7owb-03 

Rinsins Solution -Js w,&w Ds V40.4z, pI ak,/ 

Sam le Container Sealed'? / ✓ ✓ 

Li uid Level Marked? ✓ `~ ~ 

Reagent Blanks 

Absorbinv ReaQent Blank N/ 1l ,5,41 Rinsina Reaitent Blank Dz Kzo 

Absorbino Blank Identification # 70 ~ '- o 7 Rinsing Blank Identification # ~ 

Absorbino Rea ent Blank / 9, Rinsing Reaoent Blank NA 

Absorbino Blank Ideutiflcation # i,/A Rinsing Blank Identification # ,v,S 

,,. ~ _............_ . , .,,., • _ ............. 

ay ~ 

11 Reviewer lnitials ~ ~~✓ ~` 

V. 

QA B-9 
53 'r 

~ r 

K 

Sckematic of Sampliag Location 

,Wdtbd bye~.. LJ Datm oS /.2 Cl 97 

Q4 ~ 

Q 

EPA iLlethod 1 

Determination of Sampling Ports and Points 

Qient 34a7~ S~~ 1~ e IJrI Ck C'ity/State 964? SY ,- I l t, N C 

Sampling I.ocation E-" hav,.St a~1 ck Date Q5l IyT,? rI i 

Sampling I.ocation Dimensions: , i 

From Far Wa11 to Outside of Port S 5 

Nipple L,ength ~ • ~ ~ 

Depth of Duct .3 7. 

Width (Rectangular Duct) z 

Equivaient Diameter Calculation (DE): 

2 z Leo;th x Rlidth 2( y j. S)( 3W 

DE = _ 

tAngLh + Wiarh (37,5 + 3$ 

Distance to Ports From Nearest Flow Disturbance: 

Upstream - A Downstream - B 

Dimensions ia lnches --z 10 ~- r_ 33 J ZY D 1! 

Duct Diameters '"' • ~ 3 (e .

Stack Area, in Square Feet . q q-0 

Calculations By JDti 

) 

= 37. 7s 

. I • e I o 

; ,< ~ • s 3 t 

! •oa 

e t 1 4711 34 1 ~ 1 diiii~ 

::. 

. At oC.: _ Stadc D TataaQtbos " 

Tnardd:Wali 

2rfQpre ;;> 

Length 

Di scsaoe:F ~ oo: :. 

:.,OuuideuEPort• 

I 10, 0 37-.5 3.75 o f1.7S I 

Z 3 t7 . O 3q. S t I, 25 ~ ~ A 

3 s0.0 3?.S 1r-7J Ka z,c,.?s 

1 ?o. a 3'7.5 Z6 ZS 't 0 3H. ZS 

S to•J 375 33. ?S g. ~ 1•7S 

I . 

-

9 - 

~ • I 

,. a 

t ,i.o a , I L: 

7 S7~ • 0 a T '7. , "T 

n, ann at11 ta.9 is.o 71.a _'9 

I 

V - 

B-10 TF~ 
EPA Method 2 

Determination of Stack Gas Yelocity, Yolumetric Flow Rate and Cyclonic Flow 

Client `J/~~'SV! ~~ 13tric~2 

Sampling Location K~ 1— F~rHc ~c1' Sf~~ lc 

Run Date _ 0~1N(l7 

Barometric Pressure, in. Hg Zf.q D 

Static Pressure, ,in. H:O 0 k% 

Static Pressure, in. Hg – O. 00 ( l 

Stack Pressure, in. Hg 28,40 

Stack Dimensions, in., diameter/side 1 3 7 i 

City, State I II t, , Jl/c, 

Operatots TbA ~ j'L LJ 

Tune jCn 15 

Pitot Tu be I.D. No. 2~q . d y L1' 

Date Calibrated_ 0 (

I

/ o`;jR 7 

Pitot Tube Coefficient 0. g4 

Leak Check, in. H2O <0.1 @ 4•0 

Side 2, in. 3? .0 

Field Data 

• 

Cvdo t 

~ 

©~-~ © ---- ®~-~

~-~_--- ---- ®®-~---- 

© , . ~. . . • ~~~~ 

Stack Temperature, Dry, °F (A) Sr3 Stack Temperature, Wet °F (B) 14 Lj 

DitYerence (A - B) 30 cl Prel'uninary Percent Moisture f o 

by: 7Llti DatecUs %2O/ (j7 B-il ql 
E'PA dtethod 2 

Determination of Stack Gas Velocity and Volumetric Ffow Rate 

~ 

Client ~'~SVI ~ ~~ 3f7 G 

Sampling Location KAn. Fxhaw5ll' fC. 

Run Date 4l5l4'7 

Pitot Tube I.D. No. Z ~D• "q 

Date Calibrated 0(1 0 /3 ~17 

Stack Dimensions. in., diameter,'side 1 32. 5 

City, State 'sCt'SV: 1 [A--~ , Nc. 

Project Yumber 0 to-q '7- oz.? la 

Operatots JDA 

Pitot Tube Coefficient, C. O.Ftl 

L.eak Check, in H.O <0.1 @ L 

Side 2, in. .39 

Field Data 

Run No.iSamvle No. Z. .3 Cnd v~ -3 

Time 24-Hour Clock) IZq () 14DD )507) 

Bar. Press.. in. He 2-f•78 Z8.7Z LY.`i a ZS.Za 

Static Press.. H.O -(~ . .^. I0 - 0. ODS - D. 6DS - 0, 01 O 

Static Press.. in. H2 - 0. a-Z)on - w) L 0. 6000 - Q. 66b PT 

Stack Press.. in. H¢ Z$.7 Z$.7Zi u ?-$.70 

Stack Tem .. Drv, °F q -5-~$ 57,2 5 2% S ZD 

Stack Temo.. Wet. °F 143 lyij Ms lqq 

Difference. °F 35q 371 363 37 (,P 

Moisture. % . t 1 7• t $• Z 1• ~( 

~ 

Field Data c_J 1 7 

411 J 

Travetx: 

Point .. 

Number 

:: VelodtT 

Head Op:, 

Inches ILO 

Stadt 

Temperatura 

°F 

Velodtp . 

:. Heud'zip - 

Inches 1i.0 

Stad6:. .. 

Temperature 

°E 

Velodty 

Head ip 

Inches ILO 

Stadc:: 

Temperature 

°F' 

Veiodt7! 

Head Ap 

Inches Ii3O 

Stadt: 

Tempernture: 

: °F 

AI 8 1.OIS o.W t > 4J8S qff'd 0.035 o.oy5 518 530 0.03 C o.ayu SZZ j 523 o.' 0 o.o~ S 52,5 15z3 

Z Z O.OqC 0.035 ySS 0.035 1 0.04 0 5Z2 53 a 0.030 0.035 5 14 1 5 Zy O.oSb p,ot{v 5Z4 52, 2 

3 3 0.035 0.035 qlto qlQ o.ot5 I o.o3o Szs 531 o,t,z5 0.030 57,to Szl 0. 05a0.035 5z.0 522 

~ 0.030 6.045 4a d 53 0 532, o-oTD1 o. OLIS 52,9 SLZ 0.030 o.045 22) 

5 S o.030 o.uuo HS8 q YQ o.cZ o.0 ~1 530 53z. O.ozo o.o4 5z? 5Z2 O.o2S o.oy5 E-I Z- SZI ( 

0 ID I o,dtu 0,050 yY4 qql 0.000 o.cr,o 532- 533 oatss SzA 1 533 O.otA o,oso SZI 5ZI 

2 1 L 10.06C 0.03SI Lifq 1410 0.050 O-OfOl 533 53 Z o.oSo ,035 5L2 1 53Z, o.o5a b•o3U 5Z( Sz,o 

3 3 0.035 0.030 419 qq3 a.a.5 o. o; b 5 33 530 o.o2 0. DZS 524o 531 0.021) 0. 02.5 SLb S Lo 

4 o.oioo-aa 4 tq 4qS 0.015 0.035 531t 531 0.01 o.a3S 5 Sqb o,oibo.oq5 521I5Z! 

5 S o.o(o v.ot,S qqZ-14q5 0,o2 0.00 535 53e 53( 5q1 0.015 O.oyS 

~ o•oZS gEo 5L$ 0.03 0 s 3 0.0140 .SLo 

Z o.0 S 2 o. Dit 5 SZot o. o,1S 5 NZ o. oH D SZf 

3 0.0 S glo 0•050 IM 0. 0 5 0 5 Z O.o.SD 520 

~ O.stlo 411 o.uuo 530 o.o4o SuZ 0,050 52,0 

5 0,02; 50V o.OZ5 53D o.o20 540 0.035 5(9 

, Y"es. 0.038 14?q.4 L2. 031t 530• D 0• 03 ~ I 530•b 0, 031 SZf. 4 

p. S ments I 

4Q~► ,~ ~~ 3~- G~, c~a~d bY ~„~d o.,~cl.r~' - 

v ~ .~.r~ 

A ited br. a7L LJ Date: o ,~-/ a o/ 97 o -r~ 

O~CL ~ JF: 0-5/ZL q '-t '~ 
EPA iVethod 3- Molecular Weight Determination - Data Analysis 

Client Name I'd2villp— Project Number Otllv - 4? - ULz 6 

Ciry/State V, J A/ Sample Date oS JS 4'l 

Sampling Location Kir+_ &6w5f SfaGk Operator EC ~ 

Sample Type o Tedlar Bag o Multipoint 2"'Single Point Fuel Type w3ud 

Analyzer Type Fvrite Serial # -' o,9- , L 1 7- ebzygen Calibration Check Must Be 20.9 t 0.1% 

Run # and/or Sample ID I Sampling Time (24 - Hour Clock) 0 3 D 

Gas: ' Re licate 1 Re licate 2" Re licate 3 Average: 

Percent 

Multiplier: : Molecular Weight 

Actual Net: Actual Net Actual: Net Dey lbflb mole. 

co:; .5 S ~1. 5 ,S U, S q. S Sd o:aa I. 4rD 

1lrS f4,5 0 032 5.28 0 

N:., 100 4 ~ 100 '79: U 100 ?S.0 ~g, 6t~ 028 Z2 .12u 

To

ta

l 7-R.380 

Run # and/or Sample ID Z SampGng Time (24 - Hour Clock) 1315 

Gas- Re licate t Re licate 2 Re iicate 3 Average: 

Percent 

' Miiltiplier : MolecularWeight. 

Actual Net Actual Net ActuaP Net Dry Ib/1b mole 

Coz:. 5.0 5, ~ ~ D S.o S a 5,0 S. 0-0 0:44 2.200 

°s l co. 0 ( l.. 0 ( h. D (1a . o JU. 0 11-. 0 ( to .U-Z;, 032. 5. Z a. 

N:: ioo 7y. ~ loo ?a. o` ioo: 74. o?9. o-J 0.28 Zz, f 20 

Total 2-Ci.4 d0 

Run # and/or Sample ID 3 Sampling Time (24 - Hour Clock)/I y 0 

Gas: Re licate 1 Re licate 2 Re licate 3 Average 

Percent 

Multiplier Molecular Weight: 

Dry* lb/ib mole Actuaf Net Actual Net ActuaF I' Net 

C°= 3.5 3.5 3.r 35 3.S 3.S 3.So 0•44 I.S4u 

°=:: i 1. S i 7. S 17. S f Z. s 17,5 r 7. .S 17. s o 032 

N:: 100 ?4,n 1

oo ?9. 0 100_ 71. 6 ?9. 0:8 22, I ZU 

F_ 

 Total 2q. 

(9~ 

Date:a° / 9 ~ 

B-13 

~ wi by: ~14

J 
Orsat System /'tA Tedlar Bag No. /VA 

End Time 1'?'~ . Bag Leak Check /11)4 

Level Marked',/ Observer /V' W6 

EPA Method 26 Determination of Hydrogen Chloride Emissions 

Client _-Stin ~ iI{-"Rr ~(-.J'L. Run Number 

Ciry/State 6jz&SJJ I ( t- , lV C... Date 

Sampling Location_k/:I r E" 6„r~S "

~rccr v Operators ,TfiJFi 

Amb. Temp., °F 15 SET-UPDATA 

~ 'Z~ ~ ° 

Bar. Press., In. Hg. ~~- Console Dry Gas Meter Coefficient Y= 

Static Press., In. H2 0 — 0Purge Time •S m; rt. Purge Rate s tc. ktj 

Meter Boz No. q0-9 , 03 D Stack Temp. 513 Pitot Tube No. ,'?_ 140~ 

Sample Boz No. 3 Wet Bulb Temp 1 T D Pitot CoePl'._0 1,~_ ~

Pitot No. NA % Moisture g~ 

Probe Temp. Setting 25 0 Start Time 

Sample ID No. 3U ~ 'M Sample Container No. 1 

LEAS CHECSS 

Pre-Test7.02® 2) In. Hg 

Post-Test 6~~ T% (gZb In. Hg 

Pre-Test Pitot <0.1 @ ' /. +- In. H:0 

4- y3 

Post-Test Pitot <0.1 @— (,_In. H:0 

Sample .: Run 

Ttme .: 

Minutes:..: : 

Clock 

Time 

24 Hour 

...Clock:: 

Flow 

Meter 

Seiting .:: . 

Liters/Minute.: 

Dry Gas 

Meter 

.: Volume 

Liters 

Dry Gas .. 

Meter 

Temperaaire 

°F 

. PumP 

Vacuum 

Inches 

Hg 

Stack :..: 

Temperature 

'F 

o 11 0v Z S f yv 5,73 

5 1105 Zb SZ 

10 II10 

15 11 r5 Z Z 544 

20 IIZa G 8Z 70 57— 

25 r125 v 31 z 53 Z 

30 ( 3 a 2 

e ~IS 

35 n 35 

40 i1 0 Z ~ I Z() 5q 3 

45 Z 1 ZO 531< 

50 ti 5a Z $ u~ 533 

55 itsS Z 535 

60 I lC3D L 4 ~ Z(J J 3q 

ar.L~ 53Z.8 

Cottunents + IJd.— ; V'eSSw.L. 

~ ~sa~, avK. v4-Co4'61 9*1 

~μ t c~. ~..hw 

l ~ —~—,..~..~ ~ 

~i D1'~ 

~ ;.CL ~ +,83 

$3 ~~~' ~`~'~+ . c,~.~- S~~

'" - 

t Y o 1- 

~3

WTRGON.:

~ + 

u,~2,d•Re~- ~~s

B-14 ~!~ 

Av . I. 7 7 I 4 
EPA Method 26 Determination of Hydrogen Chloride Emissions 

r 4

~ 

Client ~s1/t ~ IZ ~( ~ Ck Run Number 

City/State t~t~C3y , ArC- Date 051' 

Sampling Location '56CK Operators jDp 

Amb. Temp., °F ~ 5 

Bar. Press., In. Hg. G~ 72 

SET-UP DATA LEAB CFIECSS 

Console Dry Gas Meter Coefftcient Y= (• O?D Pre-Test0• J 10@ U In. Hg. 

,70a L s tC 

Static Press., In. H:0 -0•065 Purge Time 5 -;et- Purge Rate ~ b Post-Test 1~ ppS , @ 20 In. Hg. 

Meter Boz No. q ov 030 Stack Temp. 0 Pitot Tube No. ~b~ • Oy ~ Pre-Test Pitot <0.1 ® 4 C In. HZO 

Sample Box No. 4 Wet Bulb Temp Pitot CoefP. o•g 

•Y q• y Post-Test Pitot <0.1 ® -L1Ae In. H:O 

Pitot No. /N A 3Yo Moisture r(• ~ Orsat System N,C Tedlar Bag No. ~ 

Probe Temp. Setting GS L) Start Time q b End Time 13 q D Bag Leak Check 

Sample ID No. 70U(a Sample Container No. 1- Level 'Ylarked f Observer /1N D,4h7 

Sample. 

Run 

Tune " 

Minuces 

Ciock 

Time 

24 Hour 

Cloek 

Flow 

Meter 

Setting 

Liters%Minnte 

Dry Gas 

Meter ' 

Volume 

Liters ' 

Dry Gas ; 

Meter 

Temperature` 

°F 

Pump 

Vacuum 

Fnches 

H 

Stack. 

Temperature 

°F 

o 

5 

10 

15 ~ Zs s Z a ZA s3 Z 

20 535 

25 13 5CD 

30 i3 ro 2 rZ Lo 5~/Z 

35 i.s t s 2 g 2. ZD s3 

40 132D zz 5:30 

45 13 ~s z a~ Z~ sLL) 

50 3 3-0 Z 15 5 Z3 

55 1335 2 65 Z-0 SZ ~ 

60 IN z~ Z g z-v 520 

83.8 53 2 .7 

Cotnments ~S~ tiok 04 a-,j I 

Fr o 

aY; 

r. ~Y 

(, QU 

a_ 1414 

~_. 

t,1'f 

1.71 

1:13 

t•?q 

I • 7f-i5 q.

~5 
EPA Method 26 Determination of Hydrogen Chloride Emissions 

Client ~ 7Ad~2S>,/Ilk Run Number 3 

Ciry/State ~fa~tZS~t I ~~ ,/!/C Date 

~. T 

Sampling Location XI ~ h. r~lc ~nwu31 Operators J~q 

Amb. Temp., °F ~ Z SET-UP DATA LEAS CHECK4 

Bar. Press., In. Hg. Console Dry Gas Meter Coefficient Y= l' Dy Pje-Test C• bb q 0 ~0 In. Hg. 

Static Press., In. H :0 — 0 ~ ~~ 

c 

Purge Time J Yr:+.. 

sC~t 

Purge Rate n.:N b~tbPost-Test U. ODZ ~ Z 0 In. Hg. 

Meter Box No. ~~~ 03~ Stack Temp. v'3 D Pitot Tube No.=- 64y Pre-Test Pitot <0.1 @ +~ Y_ In. H20 

Sample Box No. J Wet Bulb Temp ~ Pitot CoePF. C~ •d Post-Test Pitot <0.1 ® ''1• d2- In. H20 

Pitot No. NA % Moisture g Z Orsat System !yA Tedlar Bag No. N a 

Probe Temp. Setting 2,5() Start Time I No-O End Time 10 0 Bag Leak Check NA 

Sample ID No. / u~G ~L' Sample Container No. 7 Level Marked ', Observer /dOJ'/(- 

Sample :; 

Run 

Time ' 

Minures> . 

Clock 

Time 

' 24 Hour 

` :: Clock 

Flow 

ffifetee 

Setting: .. 

;; Liters/Miaute : 

Dry Gas: 

Meter _.;; 

Volume 

Liters:: 

Dry Gas 

Meter, ;: 

Temperature 

°F : : 

Pump ' 

Vacuum .; 

 Incttes: 

H 

Stack 

Teniperature 

' F 

0 1'Yo17 Z 

5 lqot Z d L ~ SNS 

10 F3 zD 5Z ~ 

ls 1415 Z Zo 30 

20 1 ZD Z 13 Zr7 529 

25 Iq25 Z Z ZD 5 31 

30 1qR Z 5 uq 

35 

40 IqLm Z Z Z~ SZ3 

45 i 4.S 

50 Z FG 2.0 SD D 

55 1 SS z T5 Z o JSI Z 

60 .,Lf4D 71 6 ~I z 4 szg 

S3, g S2g, 

Cotnments -

f gw A'1D k- °r a"'f I 

p

Q~ 3'CcJ asyao ~97 

QA► 

I• ~3 ~-~<< 

(-t3 

I•~~ 1,43 B-16 9~ 
EPA Method 26A - Moisture Deterrr, 

~ L 

Client Name ` 

 d 

XGRt~SV I

~ 

lle- ~✓ U( 

City/State sf S✓; ~ 1l- . N ~- 

Sampling Location ~i l 1. achau-e S7~c~ 

Clean-Up Box Number . 1?1& 

Chain of Custody: Date Received 

Ination and Sample Recovery - Data Analysis 

_ Project Number 0-Y (. - q ~ ' Ote la 

Sample Date ()5115.10 

_ Samples Recovered By L~f3 

_ Recovery Date OS 1 97 

_ Received By Locked? 

Equipment Documentation 

Run Number 1 Z 3 

Sam le ID Number '701z(D- 0 ?0(zU - OS 701w1a-0' 

Sam le Box Number 1 Z ~ 

Probe Number 

Analysis of Nloisture Recovery 

Reaeent Recoverv Container # 701.e - 0 4 7bUu -oS 0t?d0 -0(0 

Im inoer Absorbina Solution 0. nj NZSOu 0.1 N Hzsoq v.l n/ 14:..SOy 

Descri tion of Rea ent 44,w Oe.cw r.(uar 

ReaQent Level Marked'? ✓ 35.1 3 .'1 if•t, 

Final Volume. ml 'a 

;Z~

=1' Z-OT# -tt1'*--Ztr 

Initial Volume, ml -4i--5- 'Is~ ~ ~~ 

Net Condensed Volume, ml 

_ ... . . 5.7 30 ' . . . . ..... . 5, ~ S.lo 

_ ... . . _ ... 

Rea:ent Recoverv Contaiiier # ?OLiLe -Ot{ 17046 -0$ '706O -DU 

Im in er AbsorbinQ Solution 0.► N n/a014 o,J aDl{ 0.1W Nab 4 

Descri tion of Rea ent G(tc~✓ U+w✓ ~~ 

Rea_ent Level Marked? ✓ `~ ~ 

Final Volume. ml I5 l 15 15.3 

Initial Volume. ml f S.o 15. 0 15. v 

Net Condensed Volume. ml 0.0 0.3 

Silica Gel Recoverv Container # 7a,6(a - OtF. ?Ctzlo - OS ?010l0-0tr 

Percent Silica Gel S ent 10 (o p 

Final Wei¢ht. o Z(. Z 21.1 Z 1. 0 

Initial Weioht, o ZO Z O 2,0 

Net Absorbed Water, o t. Z 1 - 0 

Total ReaQent Collected, g 7.0 4.5 (0.1 

Sample Recovery 

Reeoverv Container # tlta - 6N 7 auke - OS 1 042U -0 

Rinsing Solution DS W:~;Ec4_ -DX i,./o:Ew t7S WukXV1 

Sam le Container Sealed? ✓ '~ ✓ 

Li uid Level Marked'? ✓ ✓ ✓ 

Reagent Blanks 

II Absorbins Reasent Blank I©./1/ 11,SDf_ - I Rinsins ReaQent Blank I DL 14z0 1 

Absorbino Blank Identification # A - 07 Rinsing Blank Identification # — 

Absorbina Reazent Blank N/+ Rinsing,Rea ent Blank rJA 

Absorbin¢ Blank Identification # NA RinsinQ Blank Identification # NA 

r•. . 

B-17 y~ ~ 
APPENDIX C 

LABORATORY DATA 

~.i 98 
Trigon Engineering Consultants, Inc. 

Statesville Brick 

(046-97-066) 

Analytical Report 

(0597-26) 

EPA Method 26 

Hydrogen Fluoride 

.~ .~~ 

Enthalpy Analytical, Inc. 

3211 Bramer Drive 

Raleigh, NC 27604 

919/850-4392 

C_ % ~ 
Summary of Results 

.~ ! ENTHALI'Yanalytical, inc. C-3 m 
Company: Tri on/Statesville Brick Clien[.#: 046-97-066 

Analpsts BGH Entlialpy #i: 0597-26 

Parameu:rir H dro en Fluoride PO:#i AM7559 

#S les: 7 R ortDate: 05/14/97 

I-Compound Sample ID & Catch Weiglit (mg) 

7066-01 7066-02 7066-03 7066-04 7066-05 7066-06 

Hydrogen Fluoride 2.08 2.73 2.95 7.21 8.16 12.7 

~ . 

~

~ ~+a~"~ 

~~ ENTHALPYanalytical, inc. 

D:UOBS97U05%0597-26\0597-26.WB2 17:02 06/04 

f (/ / 
Results 

~ ! ENTHALf'Yanalytical, inc. 

C-S mo- I 
4- 

r 

3 ~

~ u 

3 r 

.~ u 0 

a 

N 

~~ 

a 

~ U ~ 

~ 

ti 

~ 

~ 

~ J Q 

_ H Z W 

Q 

~ 

2 

~ 

s 

~ ~ ~ 

0 

~ '. u° 

~. 

Q 

3 e O p 

j ' E 

rj. ~, 

Y : 

~ O 

< ' U 

~ . 

~ o 

6 S 

i 

Y 

a. 

E 6 c. a 

a a 

e a a 

a 

ai 

A c 

z 

~ 

Y 

a 

e 

~ 

C-6 

~~ ~ 
Narrative Summary 

Y ENTHALPY anaiyticai, inc. 

C_7 /! ~ 
Enthalpy Analytical Narrative Summary 

... .. .......... . ... .................. Trigon/Statesville Brick 

.... . .... .. 

046-97-066 

P.04- AM7559 

0';YV;#::.: ..... ........ ... ...... ... . 

0597-26 

W BGH 

HF 

Custody Samples were received on 5/20/97 by, Scott Grosshandler after being 

relinquished by Paul Jenkins of Trigon. Sainples were cold upon arrival and 

kept cold during storage. Prior to and during analysis they were kept under lock 

with access only to authorized personnel of Enthalpy Analytical, Inc. 

Analysis The samples were analyzed for hydrogen fluoride according to the procedures 

outlined in the EPA Method 26. Quantitation was perfor -ined a Hewlett Packard 

series 1100 High Performance Liquid Chromatograph. Detection occurred by 

indirect UV at 260 rum. Separation was accomplished by a Hamilton PRP-XIOO 

150 mm x 4.1 nun anion exchange column using 2 niM sodium benzoate pH6.4 

as the eluent at 2.0 mL per minute. 

A four point calbration curve was nm before and after the samples. Data from 

all calibration nin were used for the cali 'bration curve. The linearity coefficient 

of the curve was 0.9999 

Labeling OK 

Reproducibility OK 

Quality of Data OK 

Reporting Notes MDL Nfinimum Detection Linlit. 

LOQ Limit of Quantitation. 

pp- Ok 

)0401~ ENTHALPY analytical, inc. 

C-8 
Sample Custody 

Y)04 1 ENTHALf'Yanalytical, inc. 

C-9 

I~ • 
O ~; 

~ . . ~~ — •i ~ ~ ~ ~ ~ ~ 

L ~, ~.: ~~ ~ __ — •.—• — ~ y r.~i 

. ` i

;' ~~ m: ~. -t: ^ 

_ 

• ~: 

X: 

~ ~ ',U A A 

\ •'~~ 

~i 

'~'~ `.•i:: . ~ . Y.: .. • ._. ,' i .' Q~ .v 

! 

~ 

~ ` 

ei 

. 

'~ 

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~ 

~ 

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.~ 

~ . 

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~ 

i 

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~'/~ <'~".'~ .~f.L:::: 

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7 

~• ` ~ ~ 

✓t ~ ,' *•sj>' :: 

~..' z 

~.'. •, v Y . ~ J ~ b '`~ ~ Q ~ ~ ~ -. 

z cn 

~:' ~7 

~ ~ ~• ' C' p ~• ~ v ~ ~ ° `.qt ~ c~~ -

F4 

.:'':' ~~". 

; '.:: r.+. :: <':'''::.':: \r "7 

~•., ~ 

~ -•l 1 I ~ ;9 

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a 

~ ~~'r.~1 ~ ~ 

~~ '''::' 

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!r. . `N• ~ ~ •~ •_ ~ 

~~. ~ ' ~• ^ './] ~~ 

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..~~ ' . V'. . ~ ~Y ~ ~ ~~ ,J• ~~ ~ ~ ~ 

Fr.l Miil a ~ 

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~'~ , l- ,,~ •u ' 

c ~ ~ — ~..; ;.~ N ,•~

. :i;, a - - 

C-lU /b / 
Sample 

Chromatograms 

Y ENTHALPYanaiyticai, inc. 

C_li /,~ S' 
Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\012-0801.D Sample Name: 7066-0 11 * 

--------------------------------- 

Injection Date : 03-Jun-97, 14:16:46 Seq. Line 8 

Sample Name : 7066-01 *6 Vial : 12 

~-. Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

~ 

VWD1 A, Wavelength=260 nm (0597-26A1012-0801.D) 

mAU 

io 

- ~ 

80 

I 

- I 

i 

~ 

; c 

a~ 

- rn 0 

40 - -C a 

- ' o 

cn 

_ o 

20 - Area: 340.852 , ~~ 

' \ co 

N 

0 

0 1 2 3 4 mi 

---------------- 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1 -- 1 --------------- --- 3.030 MM 340.85193 1.27263e-2 4.33780 Hydrogen fluoride 

Totals : 4.33780 

*** End of Report *** 

Groucho 6/3/97 10:13:15 PM BGH C-i2 Page 1 of = 

~~ ~ 
Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\012-0802.D Sample Name: 7066-01 *E 

Injection Date : 03-Jun-97, 14:24:43 Seq. Line : 8 

Sample Name : 7066-01 *6 Vial : 12 

— Acq. Operator : BGH Inj : 2 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A1012-0802.D) 

mAU i ~ I 

io i I i i I - ! I 

80 

~ 

60 , ~ 

i Q 7 

~ C ~ 

~ 

O 

~ 

2 

O 

O 

cn Area: 323.518 

rn 00 

rn 

0 1 2 3 4 min 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reAorted 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] ------- I ------ I ---------- I ---------- I ---------- ------------------ 

3.006 MM 323.51764 1.27263e-2 4.11720 Hydrogen fluoride 

Totals 4.11720 

*** End of Report *** 

roucho 6/3/97 10:13:47 PM BGH C-13 Page 1 of 1 

~~~ 
Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\013-0901.D Sample Name: 7066-0,2 x 

Injection Date : 03-Jun-97, 14:32:50 Seq. Line : 9 

Sample Name : 7066-02 *6 Vial : 13 

i- . Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A\013-0901.D) 

mAU 

-{ r 

i 

i 

1 

80 ; 

~ ~ ~ 

60 

40 = ~ _ 

0 

~ 

~ 

~ Area: 381.46 

co rlC9 ~ 

4 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] 

-------- I ----- -- I ---------- I ---------- I ---------- 1--1------------------ 

2.990 MM . 381.46008 1.27263e-2 4.85459 Hydrogen fluoride 

Totals : 4.85459 

*** End of Report *** 

Groucho 6/3/97 10:14:19 PM BGH C-14 Page 1 of 

l/! 
nata Fi.le F:\HPCHEM\2\DATA\1997DATA\0597-26A\013-1001.D Sample Name: 7066-02 =6 

Injection Date : 03-Jun-97, 14:41:01 Seq. Line : 10 

Sample Name : 7066-02 *6 Vial : 13 

Acq. Operator : BGH Inj : 1 

Secruence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_LONG.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

.Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A\01 3-1 001.D) 

mAU 

io ! 

- i 

- ~ 80 

~ i I 

i 

I 

d 

60 -- ~ 

.o 

~ 

c 

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, m 

rn 

_ o 

a 

40 — S 

~ 

~ 

C4 Area: 378.168 

20 - 

a~o 

0= •i _ 

1 2 3 4 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU * s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1--1-------------- --- - 

2.967 MM 378.16846 1.27263e-2 4.81270 Hydrogen fluoride 

Totals 4.81270 

---------------------------------------------------- -------- 

*** End of Report *** 

C-15 

=roucho 6/3/97 10:14:58 PM BGH Page 1 ql 

min 
Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\014-1101.D Sample Name: 706- 6-C3'*c' 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

Injection Date : 03-Jun-97, 15:24:04 Seq. Line 

Sample Name : 7066-03 *6 Vial 

-- Acq. Operator : BGH Inj 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 

: 11 

: 14 

: 1 

column 

VW01 A, Wavelength=260 nm (0597-26A\014-1101.0) 

mAU Lo f° I 

~ o ~ ~ • _ 80 i ~ ~ I I 

7 j CL) 

60 

I CD 

, a 

40 ^ y v 

0 

! nArea: 447.632 

20 - 

- Q 

0 ri 

0 1 2 3 4 

--------------------------------------------------------------------- 

External Standard Report 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1--1------------ ----- - 

3.044 MM . 447.63184 1.27263e-2 5.69672 Hydrogen fluoride 

Totals : 5.69672 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

*** End of Report *** 

C '=roucho 6/ 3/ 9 7 10 : 15 : 31 PM BGH -16page 

/~ ~ 
Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\014-1102.D Sample Name: 7066-03 *~ 

------------------------ 

Injection Date : 03-Jun-97, 15:32:00 Seq. Line 11 

Sample Name : 7066-03 *6 vial : 14 

~ Acq. Operator : BGH Inj : 2 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A\0141102.0) 

mAU IU') i 

- ni 

- i 

. I 

80 - i I 

- j 

60 - 

i d 

~ o 

2 

40 - 

c 

- I N 

O 

.~Area: 450.747 

20 - 

o0 1 2 3 4 mir. 

--------------- 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 

3.024 MM 450.74686 1.27263e-2 5.73636 Hydrogen fluoride 

Totals : 5.73636 

-------------------------------------------------- 

*** End of Report *** 

'=oucho 6/3/97 10:16:02 PM BGH C-17 Page l of _ 

~~ 
Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\008-1201.D Sample Name: 7066-04.*2E 

---- -------------------- 

Injection Date : 03-Jun-97, 15:39:55 Seq. Line 12 

Sample Name : 7066-04 *26 Vial : 8 

-- Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A1008-1201.D) 

, mAU , I°,o n' ' j 

I 

I 80 - 

I 

j 

 ~ 

1 

i 

j 

; 

60 

i I 

I i 

_ ~ d 

i j c 

m 

40— 

I ~ 0 

I ~ i 2 

~ ~ 

207 

` .\Area: 296.041 

o 

0— 

0 1 2 3 4 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

R-esults obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] 

2.996 MM 296.04080 1.27263e-2 3.76752 Hydrogen fluoride 

Totals : 3.76752 

----------- 

*** End of Report *** 

Groucho 6/3/97 10:16:34 PM BGH C-18 Page 1 of~ 

/l~ 
Data F ~ 1e F:\HPCHEM\2\DATA\1997DATA\0597-26A\008-1301.D Sample Name: 7066-04 *26 

Injection Date : 03-Jun-97, 15:48:02 Seq. Line : 13 

Sample Name : 7066-04 *26 Vial : 8 

^ Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_LONG.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analvsis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26AW08 1301.D) 

mAU ~ n i 

i 

- I _ I I 

80 

I I 

~ 60 = 

CD 

, 'o i , o 

2 

~ d ~ 0 

~ ~ _ 

0 

~i 

~Area: 300.673 

° 

c~ 

3 4 

--------------------------------------------------------------------- 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multinlier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Si.gnal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1 -- 1 ------------------ 

2.990 MM . 300.67261 1.27263e-2 3.82646 Hydrogen fluoride 

Totals : 3.82646 

----------------------------------------------------------------_----- --------------------------------------------------------------------- 

*** End of Report *** 

C-19 

Groucho 6/3/97 10:17:06 PM BGH Page 1/o; 1 
Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\009-1401.D Sample Name: 706.6-05•*2 

------------------------- 

Injection Date : 03-Jun-97, 16:31:10 Seq. Line 14 

Sample Name : 7066-05 *26 Vial : 9 

~ Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A\009-1401.D) 

mAU I° I 

i o i 

80 ' 

' ' 

; 

I 

a I 

60 

- i L 

I O 7 

- 

~ C 

v 

40 , O 

O 

20 —, `\ j~Area: 298.803 

0 ~ r~i 

0 1 2 3 4 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks . not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU * s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 

3.040 MM 298.80316 1.27263e-2 3.80267 Hydrogen fluoride 

Totals : 3.80267 

*** End of Report *** 

Groucho 6/3/97 10:17:36 PM BGH C-20 Page 1 o _ 

// 
nata Fi.1e F:\HPCHEM\2\DATA\1997DATA\0597-26A\009-1402.D Sample Name: 7066-05 *26 

-------------------------------- 

Injection Date : 03-Jun-97, 16:39:16 Seq. Line 14 

Sample Name : 7066-05 *26 Vial : 9 

Acq. Operator : BGH Inj ; 2 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A\009-1402.0) 

mAU 

U, 

~ 

80 

1 ~ 

i 60 , 

I i 

i Gl 

~ O 

, C 

d 

40 — O 

S 

- 

I ! 

ch M 

O 

20 nArea: 302.895 \ 

I \ % N 

Q) 

0 

0 1 _ 2 3 4 

----------- 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

1997 10:05:30 PM' 

RetTime Type Area Amt/Area Amount 

[min] mAU *s [ug/mL] 

------- 

 I 

 ------ 

 I 

 ---------- 

 I 

 ---------- 

 I 

 ---------- 

3.033 MM 302.89542 1.27263e-2 3.85475 

Grp Name 

-- ~ ------------------ 

Hydrogen fluoride 

Totals 3.85475 

*** End of Report *** 

roucho 6/ 3/ 9 7 10 : 18 : 0 7 PM BGH C-21 Page 1 p~l 
Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\010-1501.D Sample Name: 7066-06•*2; 

Injection Date : 03-Jun-97, 16:47:20 Seq. Line : 15 

Sample Name : 7066-06 *26 Vial : 10 

Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A\01 0-1 501.D) 

mAU m ~ i - 

io 

80 

I 

. 

{ w 

? 

60 — — c ~ 

, > 

, 2 

40 —. ~ 

m 

- o 

r Area: 475.059 

20- 

0 

2 3 4 mir 

External'Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks . not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] 

------- I --- ---1 ---------- I ---------- I ---------- 1 -- 1 ------------------ 3.039 MM . 475.05911 1.27263e-2 6.04577 Hydrogen fluoride 

Totals : 6.04577 

*** End of Renort *** 

Groucho 6/ 3/ 9 7 10 : 18 : 3 7 PM BGH C-22 Page 1 p~ 1 
nata File F:\HPCHEM\2\DATA\1997DATA\0597-26A\010-1601.DSample Name: 7066-06 *2E 

Injection Date : 03-Jun-97, 16:55:34 Seq. Line : 16 

Sample Name : 7066-06 *26 vial : 10 

Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_LONG.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A\01 0-1 601.D) 

mAU ; iuI ~i 

 0 

a i ~ 

80 = 

' I 

i 

- 

i 

o 

60 - 

~ 

_ 

~ o 

~ 

a 

w^ - r 

N 

O 

nArea: 472.148 

- ~ 

20 - 

0= 

0 1 2 3 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1--1------------ ------ 

3.032 MM . 472.14780 1.27263e-2 6.00872 Hydrogen fluoride 

Totals : 6.00872 

-----------------------------------------------------------------_---- --------------------------------------------------------------------- 

*** End of Report *** 

3roucho 6/3/97 10:19:08 PM BGH C-~ Page 1Q ~ ,1 
Data File F:\HPCHEM\2\DATA\199 ;DATA\0597-26A\011-1701.D Sample Name:.7066-0 7 

Injection Date : 03-Jun-97, 17:38:48 Seq. Line : 17 

Sample Name : 7066-07 Vial : 11 

Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VW01 A, Wavelength=260 nm (0597-26A\011-1701.0) 

j mAU 

; !

ci i 

80 

i 

~ 

i 

i 

' I 

60 ~ 

~ ~ I 

rn 

Q 

e 4 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 

3.137 - - - Hydrogen fluoride 

Totals 

1 Warnings or Errors : 

Warning : Calibrated compound(s) not found 

Groucho 6/3/97 10:19:40 PM BGH C-24 Page 1 )

~/ 
Da ~ta File F:\HPCHEM\2\DATA\1997DATA\0597-26A\011-1702.D Sample Name: 7066-C -, 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

Injection Date : 03-Jun-97, 17:46:53 Secq. Line : 17 

Sample Name : 7066-07 vial : 11 

~ . Acq. Operator : BGH Inj : 2 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

.Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0587-26A\011-1702.D) 

mA U I °' ! 

80 ~ 

60 i 

y 

f 

i 

40 — 

i 

~ I 

20 — 

.. . Q 

N ' O fr0 

°- ~ 

0 1 2 3 4 mir, 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

External Standard Report 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution . 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[rnin] mAU *s [ug/mL] 

------- I ------ I ---------- I---------- ---------- 1 -- 1 ------------------ 

3.137 - - - Hydrogen fluoride 

Totals : 0.00000 

1 Warnings or Errors : 

Warning : Calibrated compound(s) not found 

C-25 

Groucho 6/3/97 10:20:16 PM BGH Page 1 Qf~2 
Curve(s)/QA Point(s) 

Chromatograms 

.~ .~ ! ENTHALPYanalytica , inc. 

C-26 

4~3 
Method.F:\HPCHEM\2\METHODS\0597-26A.M 

- --------- 

Calibration Table 

Ca1ib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Calculate External Standard 

Based on Peak Area 

Rel. Reference Window : 

Abs. Reference Window : 

Rel. Non-ref. Window 

Abs. Non-ref. Window 

Uncalibrated Peaks 

Partial Calibration 

Correct A11 Ret. Times: 

Curve Type 

Oria- n 

Weight 

Recalibration Settings: 

Average Response 

Average Retention Time: 

15.000 % 

0:000 min 

15.000 a 

0.000 min 

not reported 

Yes, identified peaks are recalibrated 

No, only for identified peaks 

Linear 

Forced 

Equal 

Average all calibrations 

Floating Average New 75 

Calibration Report Options : 

Printout of recalibrations within a secruence: 

Calibration Table after Recalibration 

Normal Report after Recalibration 

If the sequence is done with.bracketing: 

Results of first cvcle (ending previous bracket) 

Signal 1: VWD1 A, Wavelength=260 nm 

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

[min] 

------- ~ -- ~ -- ~ ---------- 

Sig [ug/mL] 

I---------- --------------- 

3.137 1 1 3.90000 

I ---------- 

296.43666 1.31563e-2 Hydrogen fluoride 

2 7.26200 569.93527 1.27418e-2 

3 10.19000 804.74997 1.26623e-2 

4 15.04000 1181.98816 1.27243e-2 

Calibration 

---------------- 

Curves 

-------------------- 

Hydrogen fluoride at exp RT 3.137 Area12°° 4 I VWD1 A, Wavelength=260 nm 

1000= i Correlation: 0.99998 

$00_ ; Residual Std. Dev.: 6.25011 

= 3 ! Formula: y = mx 

500= Z m: 78.57715 

400= i x: Amount [ug/mL] 

' y : Area 200 = 

N 

0 5 10 15 

Amountf ug/mL] 

'roucho 6/4/97 3:21:25 PM BGH C-27 Page 1 of 1 

~~ ~ 
Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\001-0101.D Sample Name: Std I 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

Injection Date : 03-Jun-97, 11:46:05 Seq. Line : 1 

Sample Name : Std 1 Vial : 1 

~ Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A\001-0101.0) 

mAU 

~ o 

• 1 I , 

i I 

80 -- 

~ 

7 ~ I 

60 = ~ 

0 

I = 

, d 

rn 

, o 

40 _ 

I 

j I ~ O 

Area: 310.707 

20 — ~ 

~ \ 

, ~ ~; ~_ ~i•`, 0 . ~ 

0 1 2 3 4 m: 

--------------------------------------------------------------------- 

External Standard Report 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks . not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 

3.021 MM - 310.70706 1.27263e-2 3.95417 Hydrogen fluoride 

Totals : 3.95417 

--------------------------------------------------------------------- 

*** End of Report *** 

Groucho 6/3/97 10:11:03 PM BGH C-28 Page i - of " 

1'5~J~ 
Data F•ile F:\HPCHEM\2\DATA\1997DATA\0597-26A\001-1801.D Sample Name: Std : 

Injection Date : 03-Jun-97, 17:54:58 Seq. Line : 18 

Sample Name : Std 1 vial : 1 

~ Acq. Operator : BGH Inj : 1 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/4/97 9:58:27 AM by BGH 

(modified after loading) 

Pnalysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A\001-1801.D) 

mAU 

- I

0 i 

i 

40 '~ 

i ~ c 30 

~ o 

 _ 

20 - 

~ Area: 275.184 

10 - ; ~1 

0 - 

0 

1 2 v 4 

5 6 mir 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

External Standard Report 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1 -- 1 ------------------ 

2.812 MM 275.18378 1.27263e-2 3.50208 Hydrogen fluoride 

Totals : 3.50208 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

*** End of Report *** 

Groucho 6/4/97 9:58:28 AM BGH C-29 Page 1 or 1 

/ ~~ 
T)ata File F:\HPCHEM\2\DATA\1997DATA\0597-26A\002-0201.D Sample Name: Sr-d 2 

Injection Date 03-Jun-97, 11:53:56 Seq. Line 2 

Sample Name Std 2 Vial 2 

— Acq. Operator BGH Inj I 

Sequence File - F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method AN_QUIK.M 

Analysis Method F:\HPCHEM\2\METHODS\0597-26A.M 

.Last changed 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD 1 A, Wavelength=260 nm (0597-26A\002-0201 D) 

1 mAU co 

rod) 80 

cm 

J 

cn 

40— 

Area: 581.581 

20— 

o 

1 2 3 min 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multizlier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU * s [Ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1 - 1 ------------------ 

3.061 MM . 581.58105 1.27263e-2 7.40140 Hydrogen fluoride 

Totals : 7.40140 

End of Report 

,3rouchc) 6/3/97 10:11:35 PM BGH C-30 Page 1 of 1 

1(~1~ 
')a'ta File F:\HPCHEM\2\DATA\1997DATA\0597-26A\002-2001.D Sample Name: Std 2 

Injection Date : 03-Jun-97, 18:46:40 Seq. Line : 20 

Sample Name : Std 2 Vial : 2 

-- Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VW01 A, Wavelength=260 nm (0597-26A\002-2001.D) 

mAU i 

~ ^ I 

_ ici ( 

 i 

80 -- 

60 

i I ~ 

T I = 

I 

- m 

O 40 ~ ; 

~Area: 558.289 

~ 

- ~ n 

20 — 

o 

0 1 2 3 4 min 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 

3.069 MM . 558.28949 1.27263e-2 7.10498 Hydrogen fluoride 

Totals : 7.10498 

' --------------------------------------------------------------------- 

--------------------------------------------------------------------- 

*** End of Report *** 

Groucho 6/3/97 10:22:04 PM BGH C-31 Page 1~~

k 
Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\003-0301.D Sample Name , : St--~; 3 

Injection Date : 03-Jun-97, 12:01:50 Seq. Line : 3 

Sample Name : Std 3 Vial : 3 

Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A\003-0301.D) 

Lo mAU I ~o 

o` 

~ 

I y 

80 — O 

~ I ~ _ 

T 

U7 

~~~. 

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 

External Standard Report 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[rnin] mAU *s [ug/mL] 

------- ~ ------ ~ ---------- I ---------- I ---------- 1--1------------------ 

3.095 MM 823.49884 1.27263e-2 10.48013 Hydrogen fluoride 

Totals : 10.48013 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

*** End of Report *** 

Groucho 6/3/97 10:12:08 PM BGH C-32 Page 1 of 1 

~~~ 
Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\003-2101.D Sample Name: S -d : 

Injection Date : 03-Jun-97, 18:54:57 Seq. Line : 21 

Sample Name : Std 3 Vial : 3 

~ . Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Aca. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VW01 A, Wavelength=260 nm (0597-26A\003-2101.D) 

mAU _ i ~ , i lo ~ 

i ! ~ 

80 

' o 

' T_ T 

60 -, 

~ 

i 1 

 0 

QI 

n Area: 786.001 

40 I1 ! 1 1 i `! 

20 - 

0 — ✓ 

0 1 2 3 4 m!n 

----------------------------------------------- 

External Standard Report 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[rnin] mAU *s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 

3.097 MM _ 786.00110 1.27263e-2 10.00292 Hydrogen fluoride 

Totals : 10.00292 

*** End of Report *** 

Groucho 6/3/97 10:22:34 PM BGH C-33 Page 1 of = 

/-3tD 
Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\004-0401.D Sample Name: Std 4 

- ----- ------------------ 

Injection Date : 03-Jun-97, 12:09:38 Seq. Line 4 

Sample Name : Std 4 Vial : 4 

Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A\004-0401.D) 

mAU j ~ i co 

~ ~ 

~ I ~ 

w 

80 ~ 

i Area: 1209.77 

~ ~ ~ ,•- 

60 I 1 

j ~ 

40. 

i 

!~ 

I , 

20 — 

0 

0 

--------------------- 

External Standard Report 

Sorted By Signal 

Ca1ib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU *s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 

3.140 MM 1209.77063 1.27263e-2 15.39596 Hydrogen fluoride 

Totals : 15.39596 

*** End of Report *** 

Groucho 6/3/97 10:12:39 PM BGH C-34 Page 1 of 1 

/31- 
nat•a File F:\HPCHEM\2\DATA\1997DATA\0597-26A\004-2201.D Sample Name: Std 4 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

Injection Date : 03-Jun-97, 19:03:11 Seq. Line : 22 

Sample Name : Std 4 Vial : 4 

Acq. Operator : BGH Inj : 1 

Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S 

Acq. Method : AN_QUIK.M 

Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

Last changed : 6/3/97 10:06:10 PM by BGH 

Ana lysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column 

VWD1 A, Wavelength=260 nm (0597-26A\0042201.0) 

mAU ; I~ ~ 

r- g 

, 

, I 80 

i 

 ~ 

_ 

i ^ 

60 -~ i ~ Area: 1154.21 

, i j % • 

• - ; Q 

40 , i 

i I 

20 - i ~ 

C~7 

0 1 2 3 4 min 

--------------------------------------------------------------------- 

--------------------------------------------------------------------- 

External Standard Report 

--------------------------------------------------------------------- 

Sorted By Signal 

Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM 

Multiplier 1.0000 

Dilution 1.0000 

Uncalibrated Peaks not reported 

Signal 1: VWD1 A, Wavelength=260 nm 

Results obtained with enhanced integrator! 

RetTime Type Area Amt/Area Amount Grp Name 

[min] mAU * s [ug/mL] 

------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 

3.136 MM 1154.20569 1.27263e-2 14.68882 Hydrogen fluoride 

Totals 14.68882 

--------------------------------------------------------------------- 

*** End of Report *** 

7roucho 6/3/97 10:23:06 PM BGH C-35 Page 1of 1~ 
APPENDIX D 

PRODUCTION DATA 

n_1 /0 
Client: Statesville Brick Company 

Date: May 15, 1997 

Production Data Furnished By: Brad Brown 

Technical Services 

Statesville Brick Company 

During sampling the following production parameters were recorded: 

Single brick weight: 3.8 pounds/brick 

Number of bricks per car: 6,336 bricks/car 

Number of cars per day: 19.35 cars/24 hours 

Production Rate: 9.706 tons per hour 

D-2 /3~ 
APPENDIX E 

CALIBRATION DATA 

E-1 

~~ 
QUALITY ASSURANCE AND EQUIPMENT CALIBRATION PROCEDURES 

General. Each item of field or laboratory test equipment purchased or fabricated by Trigon 

Engineering Consultants is assigned a unique, permanent identification number. New items 

for which calibration is required are calibrated before initial field use. Equipment whose 

calibration status may change with use or with time is inspected in the field before testing 

begins, and again upon return from each field use. When an item of equipment is found 

to be out of calibration, it is adjusted and recalibrated or retired from service. All 

equipment is periodically recalibrated in full, regardless of the outcome of these regular 

inspections. 

Calibrations are conducted in accordance with United States Environmental Protection 

Agency (US EPA) specifications. Trigon follows the calibration procedures outlined in EPA 

Reference Methods found in the Code of Federal Regulations (Volume 40, Part 60) and 

those recommended in the Quality Assurance Handbook for Air Pollution Measurement 

Systems: Volume III (EPA/600/R-94/038c). When the Reference Methods do not detail 

procedures, Trigon uses methods such as those prescribed by the American Society for 

Testing and Materials (ASTM). 

Data obtained during calibrations are recorded on standardized forms, which are verified 

for completeness and accuracy by the Quality Assurance Manager. Data reduction and 

subsequent calculations are performed using Trigon's Air Quality Data System. Calibration 

calculations are performed by an environmental scientist, independently audited by the 

Project Manager, and reviewed by the Quality Assurance Manager for verification of data. 

Copies of calibration data are included in each test or project report. 

Inspection and Maintenance. An effective preventative maintenance program is necessary 

to ensure equipment performance quality prior to, during, and following every test. Each 

item of equipment returning from the field is inspected before it is returned to storage. 

During the course of these inspections, items are cleaned, repaired, reconditioned, and 

recalibrated when necessary. 

Each item of equipment transported to the field for a test project is inspected again prior 

to being packed. Trigon performs these quality assurance checks prior to departure for the 

project site to detect equipment problems which may occur during periods of storage. 

Trigon transports adequate back-up equipment to each project so as to avoid any 

unforeseen circumstances. 

Calibration. Source sampling equipment that require calibration include nozzles, pitot 

tubes, thermometers, flow meters, dry gas meters, and barometers. The following sections 

detail the calibration procedures followed by Trigon for each item. 

E-2 / 2` 
Nozzles. Each probe nozzle is uniquely and permanently identified at the time of purchase 

or fabrication, and it is calibrated before initial field use and prior to each test. The inside 

diameter of the nozzle is measured to the nearest 0.001 inch using a digital micrometer. 

Three measurements are made using different diameters each time. If the difference 

between the high and the low measurements do not exceed 0.004 inch, the average of the 

three measurements is used. If the difference exceeds this amount, or when the nozzle 

becomes nicked, dented, or corroded, the nozzle is reshaped, sharpened, and recalibrated. 

Regardless of usage, all nozzles are inspected and recalibrated on a yearly basis. 

Pitot Tubes. All Type S pitot tubes are constructed and calibrated in strict accordance with 

the procedures contained in EPA Reference Method 2. A Type S pitot tube will have a 

coefficient of 0.84 ±0.02. A standard pitot tube will have a coefficient of 0.99. Each pitot 

tube is visually inspected prior to any field use. If the inspection indicates damage, it is 

recalibrated. Regardless of usage, all pitot tubes are inspected and recalibrated on a yearly 

basis. 

Drv Gas Meter and Orifice. Each metering system receives a full calibration at the time 

of purchase and annually, thereafter. Post-test calibrations are performed after each source 

test. If the calibration factor, y(gamma), deviates by less than five percent from the initial 

value, the test data are acceptable. If y deviates by more than five percent, the meter is 

recalibrated and the meter coefficient (initial or recalibrated) that yields the lowest sample 

volume for the test runs is used. Standard practice at Trigon is to recalibrate the dry gas 

meter anytime y is found to be outside the range of 0.98 < y< 1.02. 

Barometer. Each field barometer is calibrated to agree within ± 0.1 inches Hg of a 

reference mercury barometer. The barometric pressure is corrected for pressure and 

temperature. Prior to and following each field test the field barometer is verified. 

Thermometers. Each new thermometer, pyrometer and thermocouple purchased or 

fabricated by Trigon is calibrated in strict accordance with US EPA Protocol. Calibration 

tolerance limits are as follow: 

Impinger Temperature Gauge ± 1°C or 2°F 

Dry Gas Meter Temperature Gauge ±3°C or 5.4°F 

Stack Thermocouples ±1.5% of absolute temperature 

All thermometers and thermocouples are inspected and calibrated prior to and following 

each field test. Regardless of usage, all thermometers and thermocouples are inspected and 

recalibrated on a yearly basis. 

Laboratory Equipment. Trigon Engineering Consultants has a written quality assurance 

document that 'covers calibration and maintenance of laboratory equipment. This includes 

calibration of each analytical balance against Class S weights. Calibration of thermometers, 

barometers, and wet test meters are traceable to NIST. A copy of our quality assurance 

document may be obtained by written request. 

E-3 13 ~7 
PRETEST - POSTEST CALIBRATION DATA FORM 

Client 'e-h_ 

Pretest Date & -7 CalibratorOu/ 

Reference Thermometer 100.022 

City/State 54-k,-z.Xir 

Postest Date e ~407 Calibrator TzA-., 

Reference Barometer 600.003 

Pretest' - 

> Postest 

,. 

Tem eratu '°F Ref. Teni '` °F Tem rature .°F Ref. Tem p` 

Ome a Red Team DBIWB#100.025 

Omeiza Green Team DB/WB #100.031 

Ome a Blue Team DB/WB #100.017 71171 7/ ?st~ Z~ 

Ome a Gold Team DBAVB#100.032 

Ome a Grev Team DB #100.033 

Ome a CEM DBAVB#100.026 

Drv Gas Meter Inlet/Outlet #300.035 

Drv Gas Meter Inlet/Outlet #300.045 

Drv Gas Meter Inlet Outlet #300.067 

Drv Gas Meter Inlet/Outlet #300.100 

Drv Gas Meter Inlet/Outlet #300.200 

Drv Gas Meter Inlet/Outlet #300.214 

Drv Gas Meter Inlet Outlet #300.241 

Drv Gas Meter Inle Outlet #300 .248 

Drv Gas Meter Inlet/Outlet #300. 

Drv Gas Meter Inlet Outlet #300. 

Umbilical Ada tor # #300. 

Umbilical Ada tor # #300. 

Umbilical Ada tor # #300. 

Umbilical Ada tor # #300. 

Umbilical Ada tor # #300. 

Umbilical Ada tor # #300. 

Probe #200. 

Probe #200. 

Probe #200. 

Probe #200. 

Probe #200. 

Probe #200. 

Pitot #200. otY 7/ ?/ Zc 

Pitot #200. 7 7/ 70 7v 

.qv0, 1.750 :'t Z`L 7/ .12-1 °e, 70 

CO, 0 3 0 72- 71 110 ?o 

;. 

Field Baro' irt. A Ref Baro iu: He Fiildi Baro in Ref. Baro 

Barometer Red Team #600.001 

Barometer Green Team #600.014 

Barometer Blue Team #600.010 '29• /0 .Z9.0leS~ o2S,9S g, 90G 

Barometer Gold Team #600.021 D 

Barometer CEM #600.020 D 

Were all postest calibrations within the specified EPA Quality Assurance criteria? )e Yes ❑ No 

E-4 130 
TYPE "S" PITOT TUBE CALIBRATION FORM 

Date: 01/03/97 Calibrator: JJT 

Specifications: 

A.) Pitot tube assembly must be level. 

B.) If pitot tube is damaged explain under comments section. 

C.) Z= A Sin y(<0.125) and W= A Sin 0(<0.03125) 

D.) a < 10° and /3 <5° 

I.D. Length al° cr2° 01°P2° y° 9° A, in. Z, in. W, in. PA, in. PB, in. Dt, in. 

Individual Pitot Tubes 

200.057 1' 1.0 1.0 0.5 1.0 0.0 0.0 0.630 0.000 0.00000 0.315 0.315 0.247 

200.019 2' 1.0 1.0 0.0 0.0 1.0 1.0 0.936 0.016 0.01634 0.468 0.468 0.377 

200.058 30" 0.0 1.0 2.0 4.0 3.0 0.0 0.918 0.048 0.00000 0.459 0.459 0.377 

200.049 3' 3.0 0.0 1.0 1.0 1.0 1.5 0.949 0.017 0.02484 0.474 0.475 0.375 

200.028 3' 2.0 7.0 1.0 1.0 3.0 1.0 0.977 0.051 0.01705 0.488 0.489 0.375 

200.025" 5' 1.0 2.0 2.0 2.0 1.0 1.5 0.931 0.016 0.02437 0.466 0.465 0.379 

200.054 5' 2.0 1.0 0.5 0.5 1.0 1.5 0.784 0.014 0.02052 0.392 0.392 0.377 

200.044 6' 2.0 1.0 1.0 1.0 3.0 1.0 0.984 0.051 0.01717 0.492 0.492 0.376 

200.038 7' 3.0 0.0 0.0 0.0 0.0 1.5 0.951 0.000 0.02489 0.476 0.475 0.376 

200.030 7' 6.0 7.0 1.0 1.0 2.0 1.0 0.978 0.034 0.01707 0.489 0.489 0.374 

200.055 7' 1.0 1.0 0.0 1.0 0.0 1.0 0.841 0.000 0.01468 0.421 0.420 0.375 

200.03110' 4.0 8.0 1.0 0.0 1.0 1.5 0.943 0.016 0.02468 0.471 0.472 0.372 

300.164 And. 3.0 3.0 1.0 3.0 3.0 1.0 1.113 0.058 0.01942 0.556 0.557 0.374 

Comments: Pitot Tubes Required Only Minor Maintenance - Further Calibration Not Required 

" Inconel 300.164 = Anderson Pitot Tube Extension C, - 

E-5 /3J ~~n, ; 
TEMPERATURE SENSOR CALIBRATION FORM 

NIST REFERENCE THERMOlV1ETER TRANSFER CALIBRATION 

Tolerance: +/- 1.5% of Absolute Temperature 

Date: 01/03/97 Barometric Pressure, In. Hg: 29.455 

Ambient Temperature, Deg. F: 76 Reference Thermometer No.: 100.023 

Calibrated By: PRJ Reference Thermometer No.: 100.028 

NIST Reference Transfer Temperature 

Thermocouple Reference Thermometer Instrument Difference 

ID No. Point Source Temperature Temperature CalculatIon 

Degrees F Degrees F Percent, % 

-30 to 120 Deg. F Thermometer Serial Number 97133 

100.022 1 Water Bath 46 46 0.00 

2 Water Bath 74 74 0.00 

3 Water Bath 120 120 0.00 

-5 to 400 Deg. C Thermometer Serial Number U38717 

100.024 1 Water Bath 74 23 Deg. C 0.11 

2 Water Bath 120 49 Deg. C -0.03 

3 Oil Bath 274 134 Deg. C 0.11 

•120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T-124997 Red Team 

100.025 1 Water Bath 47 47 0.00 

2 Water Bath 72 72 0.00 

3 Water Bath 181 181 0.00 

-120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T-151625 Green Team 

100.031 1 Water Bath 46 46 0.00 

2 Water Bath 74 75 -0.19 

3 Water Bath 208 207 0.15 

-120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T-98180 Blue Team 

100.017 1 Water Bath 46 46 0.00 

2 Water Bath 74 74 0.00 

3 Water Bath 186 187 -0.15 

-120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T-156311 Gold Team 

100.032 1 Water Bath 46 46 0.00 

2 Water Bath 74 74 0.00 

3 Water Bath 186 186 0.00 

-120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T-156877 Grey Team 

100.033 1 Water Bath 47 47 0.00 

2 Water Bath 76 76 0.00 

3 Water Bath 193 193 0.00 

-120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T-148889 CEM 

100.026 1 Water Bath 46 46 0.00 

2 Water Bath 74 74 0.00 

3 Water Bath 186 186 0.00 

Source = Type of calibration system used. 

Temperature Difference Calculation: 

(Ref. Temp. Deg. F+ 460) -(Test Temp. Deg. F+ 460) 

---- — ---- — ------ ------------------------------------------------------- X 100 = <1.5% 

Ref. Temp. Deg. F+ 460 ro 

E-6 

//~/r 
TEMPERATURE SENSOR CALIBRATION FORM 

THERMOCOUPLES 

Tolerance: +/- 1-5% of Absolute Temperature 

Date: 01/03/97 Barometric Pressure, In. Hg: 

Ambient Temperature, Deg. F: 76 Reference Thermometer No.: 

Calibrated By: PRJ Reference Thermometer No.: 

29.455 

100.024 

100.028 

Reference Thermocouple Tetnperature 

Thermocouple Reference Thermotneter Potentiometer Difference 

ID No. Polnt Source Temperature Temperature Calculation 

Degrees F Degrees F Percent, % 

Omega HH-25 KF Dry Bulb - Red Team 

100.025 1 Water Bath 72 72 0.00 

2 Water Bath 181 181 0.00 

3 Oil Bath 290 289 0.13 

Omega HH-25 KF Wet Bulb - Red Team 

100.025 1 Water Bath 72 72 0.00 

2 Water Bath 135 135 0.00 

3 Water Bath 173 173 0.00 

Omega HH-25 KF Dry Bulb - Green Team 

100.031 1 Water Bath 76 75 0.19 

2 Water Bath 175 175 0.00 

3 Oil Bath 295 296 -0.13 

Omega HH-25 KF Wet Bulb - Green Team 

100.031 1 Water Bath 76 75 0.19 

2 Water Bath 138 137 0.17 

3 Water Bath 177 177 0.00 

Omega HH-25 KF Dry Bulb - Blue Team 

100.017 1 Water Bath 76 76 0.00 

2 Water Bath 175 175 0.00 

3 Oil Bath 295 296 -0.13 

Omega HH-25 KF Wet Bulb - Blue Team 

100.017 1 Water Bath 76 76 0.00 

2 Water Bath 138 137 0.17 

3 Water Bath 177 177 0.00 

Omega HH-25 KF Dry Bulb - Gold Team 

100.032 1 Water Bath 76 76 0.00 

2 Water Bath 175 175 0.00 

3 Oil Bath 295 295 0.00 

Omega HH-25 KF Wet Bulb - Gold Team 

100.032 1 Water Bath 76 76 0.00 

2 Water Bath 138 138 0.00 

3 Water Bath 177 177 0.00 

Source = Type of calibration system used. 

Temperature Difference Calculation: 

(Ref. Temp. Deg. F+ 460) -(Test Temp. Deg. F+ 460) 

----- ---------------------------------------------- — ---- ------------- X 100 = <1.5% 

Ref. Temp. Deg. F+ 460 

E-7 /~/ 
TEMPERATURE SENSOR CALIBRATION FORM 

THERMOCOUPLES 

Tolerance: +/- 1-5% of Absolute Temperature 

Date: 01/03/97 Barometric Pressure, In. Hg: 

Ambient Temperature, Deg. F: 76 Reference Thermometer No.: 

Calibrated By: PRJ Reference Thermometer No.: 

29.455 

100.024 

100.028 

Reference Thermocouple Temperature 

Thermocouple Reference Thermometer Potentiometer Difference 

ID No. Point Source Temperature Temperature Calculation 

Degrees F Degrees F Percent, % 

Omega HH-25 KF Dry Bulb - Grey Team 

100.033 1 Water Bath 76 76 0.00 

2 Water Bath 193 193 0.00 

3 Oil Bath 290 291 -0.13 

Omega HH-25 KF Wet Bulb - Grey Team 

100.033 1 Water Bath 76 76 0.00 

2 Water Bath 145 144 0.17 

3 Water Bath 193 193 0.00 

Omega HH-25 KF Dry Bulb - CEM 

100.026 1 Water Bath 76 76 0.00 

2 Water Bath 175 175 0.00 

3 Oil Bath 295 296 -0.13 

Omega HH-25 KF Wet Bulb - CEM 

100.026 1 Water Bath 76 76 0.00 

2 Water Bath 138 137 0.17 

3 Water Bath 177 177 0.00 

Source = Type of calibration system used. 

Temperature Difference Calculation: 

(Ref. Temp. Deg. F+ 460) -(Test Temp. Deg. F+ 460) 

------- --------- — ---- ----------------------------------------------- X 100 = <1.5% 

Ref. Temp. Deg. F+ 460 

E-8 
TEMPERATURE SENSOR CALIBRATION FORM 

THERMOCOUPLES 

Tolerance: +/- 1.5% of Absolute Temperature 

Date: 01/03/97 Barometric Pressure, In. Hg: 29.455 

Ambient Temperature, Deg. F: 76 Reference Thermometer No.: 100.023 

Calibrated By: PRJ Reference Thermometer No.: 100.024 

Reference Thermocouple Temperature 

Thermocouple Reference Thermometer Potentiometer Difference 

ID No. Point Source Temperature Temperature Calculation 

Degrees F Degrees F Percent, % 

2' Pitot Tube 

200.019 1 Water Bath 73 73 0.00 

2 Water Bath 190 190 0.00 

3 Oil Bath 393 391 0.23 

30" Pitot Tube 

200.058 1 Water Bath 55 55 0.00 

2 Water Bath 187 186 0.15 

3 Oil Bath 376 375 0.12 

3' Pitot Tube 

200.049 1 Water Bath 73 73 0.00 

2 Water Bath 190 190 0.00 

3 Oil Bath 392 390 0.23 

3' Pitot Tube 

200.028 1 Water Bath 74 74 0.00 

2 Water Bath 188 188 0.00 

3 Oil Bath 391 392 -0.12 

5' Pitot Tube - Inconel 

200.025 1 Water Bath 73 73 0.00 

2 Water Bath 188 188 0.00 

3 Oil Bath 389 387 0.24 

4 Muffle Furnace 520 522 -0.20 

5 Muff7e Furnace 857 855 0.15 

6 Muffle Furnace 1115 1116 -0.06 

5' Pitot Tube 

200.054 1 Water Bath 75 75 0.00 

2 Water Bath 188 188 0.00 

3 Oil Bath 388 387 0.12 

6' Pitot Tube 

200.043 1 Water Bath 73 73 0.00 

2 Water Bath 186 185 0.15 

3 Oil Bath 386 385 0.12 

T Pitot Tube 

200.038 1 Water Bath 73 73 0.00 

2 Water Bath 186 186 0.00 

3 Oil Bath 383 382 0.12 

T Pitot Tube 

200.030 1 Water Bath 73 73 0.00 

2 Water Bath 184 184 0.00 

3 Oil Bath 391 391 0.00 

7' Pitot Tube 

200.055 1 Water Bath 73 73 0.00 

2 Water Bath 184 183 0.16 

3 Oil Bath 386 385 0.12 

10' Pitot Tube 

200.031 1 Water Bath 73 73 0.00 

2 Water Bath 183 183 0.00 

3 Oil Bath 388 388 0.00 

Source = Type of calibration system used. 

Temperature Difference Calculation: 

(Ref. Temp. Deg. F+ 460) -(Test Temp. Deg. F+ 460) 

------------------------------- -- ----------------- ---------------------- X 100 = < 1.5% 

Ref. Temp. Deg. F+ 460 I 

E-9 

TF~ICa'OIV' 
TEMPERATURE SENSOR CALIBRATION FORM 

THERMOCOUPLES 

Tolerance: +/- 1.5% of Absolute Temperature 

Date: 01/03/97 Barometric Pressure, In. Hg: 29.455 

Ambient Temperature, Deg. F: 76 Reference Thermometer No.: 100.023 

Calibrated By: JJT Reference Thermometer No.: 100.028 

Reference Thermocouple Temperature 

Thermocouple Reference Thermometer Potentiometer Difference 

ID No. Point Source Temperature Temperature Calculation 

Degrees F Degrees F Percent, % 

400.030 BimetallIc 

DGM Body 1 Water Bath 33 33 0.00 

2 Water Bath 73 73 0.00 

3 Water Bath 120 120 0.00 

400.032 

DGM Body 1 Water Bath 33 34 -0.20 

2 Water Bath 73 73 0.00 

3 Water Bath 185 185 0.00 

400.050 

DGM Inlet 1 Water Bath 33 34 -0.20 

2 Water Bath 73 73 0.00 

3 Water Bath 186 186 0.00 

400.050 

DGM Outlet 1 Water Bath 33 34 -0.20 

2 Water Bath 73 73 0.00 

3 Water Bath 184 184 0.00 

Source = Type of calibration system used. 

Temperature Difference Calculation: 

(Ref. Temp. Deg. F+ 460) -(Test Temp. Deg. F+ 460) 

-------------------------------- ----- ---- — ----- ---- ------------ -------- X 100 = <1.5% 

Ref. Temp. Deg. F+ 460 I 

.,a ,~r F ~ 
EVER READY THERMOMETER CO., INC. 

228 LACKAWANNA AVENUE 

WEST PATTERSON, NJ 07424 

(201) 812-7474 

PAGE 1 OF 2 

R E P 0 R T 0 F CALIBRATION 

LIQUID-IN-GLASS-THERMOMETER 

CALIBRATED BY EVER READY THERMOMETER C0. FOR: 

TRIGON ENGINEERING 

MARKED: ERTCO CAT 1002-3FC S/N-2890 

RANGE: +30 TO +124 DEGREES F IN 0.2 DEGREE GRADUATIONS. 

THERMOMETER CORRECTION 

READING (ITS-90)** 

32.00 F 0.00 F 

40.00 -0.06 

60.00 -0.06 

100.00 0.00 

120.00 -0.06 

** ALL TEMPERATURES IN THIS REPORT ARE BASED ON THE INTERNATIONAL 

TEMPERATURE SCALE OF 1990 (ITS-90) PUBLISHED IN THE METROLGIA 27, 

NO. 1, 3/10/90. 

THIS THERMOMETER WAS CALIBRATED AGAINST A STANDARD CALIBRATED AT THE 

NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY (NIST) FORMERLY THE 

NATIONAL BUREAU OF STANDARDS (NBS) IN ACCORDANCE WITH ASTM METHOD 

E 77, AND NBS MONOGRAPH 174. 

FOR A DISCUSSION OF ACCURACI-ES ATTAINABLE WITH SUCH THERMOMETERS SEE 

NBS MONOGRAPH 250-23. 

IF NO SIGN IS GIVEN ON THE CORRECTION, THE TRUE TEMPERATURE IS HIGHER 

THAN THE INDICATED TEMPERATURE; IF THE SIGN GIVEN IS NEGATIVE, THE TRUE 

TEMPERATURE IS LOWER THAN THE INDICATED TEMPERATURE. TO USE THE CORRECTIONS PROPERLY, REFERENCE SHOULD BE MADE TO THE NOTES GIVEN BELOW. 

THE THERMOMETER WAS TESTED IN A LARGE, CLOSED-TOP, ELECTRICALLY HEATED, 

LIQUID BATH, BEING "IMMERSED" 76MM. THE TEMPERATURE OF THE ROOM WAS 

ABOUT 25 DEGREES C(77 DEGREES F). IF THE THERMOMETER IS USED UNDER 

CONDITIONS WHICH WOULD CAUSE THE AVERAGE TEMPERATURE OF THE EMERGENT 

LIQUID COLUMN TO DIFFER MARKEDLY FROM THAT PREVAILING IN THE TEST, 

APPRECIABLE DIFFERENCES IN THE INDICATIONS OF THE THERMOMETER WOULD 

RESULT. 

CONTINUED 

TEST NUMBER: 154161 

DATE: 11/26/96 

STANDARD SERIAL NO. 128239 

NIST IDENTIFICATION NO. 88024 

/ 

E-11 /613 
EVER READY THERMOMETER CO., INC. PAGE 2 OF 2 

R E P 0 R T 0 F CALIBRATION 

LIQUID-IN-GLASS-THERMOMETER 

THE TABULATED CORRECTIONS APPLY PROVIDED THE ICE-POINT READING, TAKEN 

AFTER EXPOSURE FOR NOT LESS THAN 3 DAYS TO A TEMPERATURE OF ABOUT 20 

DEGREES C(70 DEGREES F) IS 32.00 DEGREES F. IF THE ICE-POINT READING 

IS FOUND TO BE HIGHER (OR LOWER) THAN STATED, ALL OTHER READINGS WILL 

BE HIGHER (OR LOWER) TO THE SAME EXTENT. IF THE THERMOMETER IS USED 

AT A GIVEN TEMPERATURE SHORTLY AFTER BEING HEATED TO A HIGHER TEMPERATURE. 

ANERROR OF 0.01 DEGREES OR LESS, FOR EACH 10 DEGREE DIFFERENCE BETWEEN 

THE TWO TEMPERATURES, MAY BE INTRODUCED. THE TABULATED CORRECTIONS APPLY 

IF THE THERMOMETER IS USED IN THE UPRIGHT POSITION; IF USED IN A HORIZONTAL 

POSITION, THE INDICATIONS MAY BE A FEW HUNDREDTHS OF A DEGREE HIGHER. 

TEST NUMBER: 154161 

DATE: 11/26/96 

STANDARD SERIAL NO. 128239 

NIST IDENTIFICATION NO. 88024 -------- ~ 

Charles Tang-Niz 

QUALITY CONTROL 

E-12 / ~-16 
EVER READY THERMOMETER CO., INC. PAGE 1 OF 2 

228 LACKAWANNA AVENUE 

WEST PATTERSON, NJ 07424 

(201) 812-7474 

R E P 0 R T 0 F CALIBRATION 

LIQUID-IN-GLASS-THERMOMETER 

CALIBRATED BY EVER READY THERMOMETER CO. 

MARKED: ERTCO CAT 612-3FC S/N-2775 

RANGE: 0 TO +300 DEGREES F IN 2 DEGREE GRADUATIONS. 

THERMOMETER CORRECTION 

READING (ITS-90)** 

32.6 F -0.6 F 

100.0 -1.6 

200.0 -1.4 

300.0 -1.0 

** ALL.TEMPERATURES IN THIS REPORT ARE BASED ON THE INTERNATIONAL 

TEMPERATURE SCALE OF 1990 (ITS-90) PUBLISHED IN THE METROLGIA 27, 

NO. 1, 3/10/90. 

THIS THERMOMETER WAS CALIBRATED AGAINST A STANDARD CALIBRATED AT THE 

NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY (NIST) FORMERLY THE 

NATIONAL BUREAU OF STANDARDS (NBS) IN ACCORDANCE WITH ASTM METHOD 

E 77, AND NBS MONOGRAPH 174. 

FOR A DISCUSSION OF ACCURACIES ATTAINABLE WITH SUCH THERMOMETERS SEE 

NBS MONOGRAPH 250-23. 

IF NO SIGN IS GIVEN ON THE CORRECTION, THE TRUE TEMPERATURE IS HIGHER 

THAN THE INDICATED TEMPERATURE; IF THE SIGN GIVEN IS NEGATIVE, THE TRUE 

TEMPERATURE IS LOWER THAN THE INDICATED TEMPERATURE. TO USE THE CORRECTIONS PROPERLY, REFERENCE SHOULD BE MADE TO THE NOTES GIVEN BELOW. 

THE THERMOMETER WAS TESTED IN A LARGE, CLOSED-TOP, ELECTRICALLY HEATED, 

LIQUID BATH, BEING "IMMERSED" 76MM. THE TEMPERATURE OF THE ROOM WAS 

ABOUT 25 DEGREES C(77 DEGREES F). IF THE THERMOMETER IS USED UNDER 

CONDITIONS WHICH WOULD CAUSE THE AVERAGE TEMPERATURE OF THE EMERGENT 

LIQUID COLUMN TO DIFFER MARKEDLY FROM THAT PREVAILING IN THE TEST, 

APPRECIABLE DIFFERENCES IN THE INDICATIONS OF THE THERMOMETER WOULD 

RESULT. 

CONTINUED 

TEST NUMBER: 155404 

DATE: 04/22/97 

STANDARD SERIAL NO. 48511 

NIST IDENTIFICATION N0. 92564 

E-13 / V7 
EVER READY THERMOMETER CO., INC. PAGE 2 OF 2 

R E P 0 R T O F CALIBRATION 

LIQUID-IN-GLASS-THERMOMETER 

THE TABULATED CORRECTIONS APPLY PROVIDED THE ICE POINT READING IS 

32.6 DEGREES F. IF THE ICE-POINT READING IS FOUND TO BE HIGHER (OR LOWER) 

THAN STATED, ALL OTHER READINGS WILL BE HIGHER (OR LOWER) TO THE SAME 

EXTENT. 

TEST NUMBER: 155404 

DATE: 04/22/97 

STANDARD SERIAL NO. 48511 

NIST IDENTIFICATION N0. 92564 

. / 

Charles Tang - Nian / 

QUALITY CONTROL MA~1 

E-14 / y0 
453 

Bulletin D-01-82 

S 

Suaa~ sean 0•2- 7a 6 0. 17 .73 

Meteorological Instruments I s 

& Pressure Gauqes 

m I m 

NATIONAL WEATHER SERVICE -TYPE 

MERCURIAL BAROMETERS 

Usable up to 900 metres (3,000 feet) 

T'ne National Weather Service type barometer is P91NC0's highest 

grade mercurial barcmeter. It is used by weather services and 

airports the wcrld over. T'ne glass tube has a uniform inside 

diameter of 7 mm for constant capfllary depression throughout the 

length of the scale. Scales are sat at the factory by compariscn 

with a barometer certified by the Naticnal 8ureau of Standards, and 

read the local pressure without the necessity of correcting for 

capillary depression. The vernier can be smoothly and precisely set 

by means of a rack and pinicn d; ive, controlled by a knurled 

adjusting knob. White plastic bac:<grounds on the mcunting panel 

facilitate observation of the Fortin rype cistern and mercury columrt. 

T'ne vemier has a sighting edge, front and rear, to avoid parallax. 

A suspension bracket and an adjustable ring cfamp for the cistern 

hold the barometer firmly in the vertical position on the mounting 

panel. A dual scale Calsius/Fahrenheit thermometer with a— 25 to 

50 °C/-10 to 120 °F range indicates the proper temperature to be 

used for temperature corrections. An instruction bcoklet with 

informaticn for understanding and proper use of the barometer is 

supclied with each instrument. Complete correction tables for 

temperature and gravity are included. 

T"nis barometer is accurate to = 0.3 mb, 0.2 mm, or 0.01 inch of 

mercury when carefully set and read, and after temperature and 

gravity corrections ;ia,,e been applied. For greatest accuracy a 

Certificate of Calibration may be obtained and the correction 

contained therein also applied. Each National Weather Service 

barometer has a serial number. 

The rugged construction of the National Weather Service type 

barometer is such that it can be shipped safely by United Parcel 

Service or express. The kidskin bag, in the Forcin type reservoir, 

dampens mercury column osciilations during shipment. The Iower 

part of the glass tube is narrowed down to minimize mercury 

weight, and is protected by foam cushions, thus offering added 

resistance to damage during shipment. The cistern may be .opened 

in the field for cleaning of the cistern glass and cistem mercury. Ttie 

barometer contains approximately 680 grams (1.5 pounds) of inercury 

total. It is shipped completely assembled, filled with mercury and 

ready to use. Mounting panel dimensions are 19 x 76 x 1072 mm 

(314 x 3 x 42 inches). The shipping weight is 5 kg (11 pounds) and box 

dimensiens are 235 x 250 x 1197 mm (9 x 10 x 47 inches). 

Cataiog Number Scales 

453 inch and millimetre 

45381 inch and millibar 

453M8 millibar and millimetre 

E-15 
M.A.NUFACTURER'S CALIBRATION 

CERTIFICATE 

-L!F rr;" M ;~~a ?,,rT :!7 jar,j 7~ 

-Xi l '.;X; 7% 7 

':7 _W 

~Zt - - '77 

VT 

I i=v;. L . 

24 

M 

NIA-NUFACTURER."S CALIBRATION 

CERTIFICATE 

The f-llcwincr record shows the accurac-y o-f Your digital flowmer-er 

at tested fl.8w rates compared to NTST *alib C il ,:~ated standard TN 2505~ 611 

= H_MYl\E ~E4-IA #11 481. certif ied 09/08/92. 

CALIBRATION DATE: 05/23/96 

D=IERMAL UNIT -*: 21466 

Pr.-.7`-'SUP_P 

TEOPEPP-4 7JPE (Cl) 

P=P. HUMIDITY (%.) : 

CALI=ION FLOW (ml/min) EURDMI 

50.77, 

502 . '17 1 

CALITBRA =-, BY : LvL A7P-M651 I 

y ED.= s 

Humonics /sr.c. 11 -~15~ "T" Cord-ol-ra. CA 57 9 17 

I'm A- 
E-17 

11-5-1