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# STATESVI

- LLE BRICH COM PANY



# ~ anu aciurers o ine ace 

# ~ rick
P. O. Box 471 (704) 872-4123 Statesville, N. C. 28687 

### March 12, 1998
Office of Air Quality & Standards Environmental Protection Agency Research Triangle Park, N. C. 27711 Dear Sirs: Statesville Brick Company has a high respect for the ecology andfor the health of people in the county, state and nation. Looking at wood as a fuel and sawdust as a waste, in 1981 we started utilizing sawdust as a fuel to burn brick. Thousands of tons of sawdust therefore did not go into a landfill or get burned as a waste; they went into brick production. It has been proven that HF reduction occurs when kiln eshaust passes through a sawdust drier. This means that Statesville Brick Company has had improved emissions since the adoption of the sawdust fuel. In considering the life of brick versus other construction materials it must be realized that brick have no equal. Frequently brick removed from a demolished building are used to build a new building. Also it is understood that functional brick buildings esist in Europe that are 1000 years old. Statesville Brick Company, with a masimum capacity of 45 million brick per year, is a relatively small brick facility. Necessary operating parameters do not include the technical personnel and sophisticated equipment required to produce the volume of chemicalanalyses and emissions data for this questionaire. Hiring a consulting and environmental firm to do the required testing would be an economic disaster for the company. We maintain that raw material and sawdust particulates, that are emitted and may contain HAPS or be called surrogates, are not HAPS because the contained HAPS are an integral or combined part of the parent material.In an effort to help EPA develop accurate numbers we are only submitting factual data based on tests which has been run at Statesville Brick Company. Respectfully,

, J ~ t

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` / ~ • `y'l►'W' 

### Brad Brown Technical Services /

### cr. ~ 

### '

- - NOT SOBJ E :' ' : ifi; . _ ; V + 7F o r rAFEd iJ4( dc .7 19d0.

1 

### INFORMATION REQUEST FOR BRICK AND STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS 

### Instructions Please return the completed information request to: Bruce C. Jordan, Director Attn: Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at (919) 541-5435. 

### This information request should be completed for each facility that manufactures brick and structural clay products, including facilities that are not major sources. Information is requested for all processes at your plant that emit hazardous air pollutants (HAP's), including those processes that are not associated with brick and structural clay products manufacturing. Sections II through VII re.quest information specific to brick and structural clay products manufacturing, and Section VIII requests information on emissions of HAP's from other processes located at the facility. Processes that may ernit HAP's include those processes that use or handle any materials that contain a HAP compound, all processes with elevated temperatures, and all other processes in which HAP compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this information request. Attachment 2 provides background information on the requirements of the Clean Air Act and explains how the information requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations and acronyms used in this information request. Several tables are provided throughout the information request for your convenience in answering the questions. An example response is given (shaded first column or row) in each table. If additional space is needed to respond, please make copies of applicable pages. If necessary, please make copies of this information request for additional facilities. iVo additional emission testing or monitoring is required to respond to this request.
tI. 

### General FacilitYInformation A. Name of company Name of facility 

### S a.. m e.

Page 1 of 28



# ~

### Facility address: L. QG Dv'O, 

### No. and street L
City 5—}-a.'}'e e, 

### State 

## N L. Zip 24S 4 , 71 

### Latitude and longitude coordinates of plant: 39' 42. 4q Ai g'/ D?.. 3 s W 

### Standard Industrial Classification (SIC) Code(s) of brick and structural clay products manufacturing operations .3 A5"I 

### Dun and Bradstreet No. 

### D D 32-1 71 yLB Total No. of employees for company 

## 7 Z for facility 

## $aw« (If facility is a foreign subsidiary or if company has foreign subsidiaries, include number of employees not based in the U.S.). Please complete the following shift information for the facility: Shift No. of employees Hours per shift Days per year



## X ~ l~ 36 

# F - x z 4-
B. Respondent name 1-& 

## ~ ✓ L Respondent title 1 r'k V% p. ✓ l: r& S 

### Respondent address (if different from above) and telephone number: CM a 

### ; ~ Itg~ No. and street 

# P D 13 " 4-71
City S s tate &S-- Zip — 7 .~~~'7 

### Telephone No.

- 

## 70 4 B 7 s"L Name and telephone number of technical contact person (if different from above) 

## Name Telephone No. (__j 1II. Information on Operating Permits and Applicable Federal Emission Standards 

### A. Please provide copies of relevant parts of all operating permits and permit applications for your facility. Relevant parts include the sections that providespecific information and data on: processes that emit HAP's; the use of HAPcontaining substances; eniission levels for HAP and surrogate pollutants (i.e., VOC Page 2 of 28

o ✓ , 

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### for organic HAP's and PM for metal and other particulate HAP's); emission control device design and operation; monitoring and operation and maintenance (O&M) procedures for control devices; and generation and releases of other media such as wastewater and solid waste that are associated with the operation of air pollution controls for brick and structural clay products manufacturing processes. If the operating permit or application contains the same information requested in aay part of this questionnaire, you may respond to the requested information by referencing the page or section of the permit/application to avoid duplication. If you reference your permit or application, you must supplement your response with all of the additional information requested in this questionnaire that is not included in the permit or permit application. If you prefer, you may submit the requested information from your permit/application on a 3-'/z inch diskette. B. If any source or emission unit at this facility is subject to a New Source Performance Standard or other Federal emission standard, please identify the source and applicable standard. Examples of applicable NSPS include 40 CFR 60, Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in Mineral lndustries.
1~ 

### S 0 u.y'e-,9- S



### W. Brick and Structural Clay Products Production and Raw Material Consumotion Information 

### A. Please provide the 1996 production rates and the current production capacity for each type of brick and structural clay product manufactured (e.g., structural brick, clay sewer pipes, structural clay tile, etc.). Note that production data should be provided in units of tons per year (tons/yr).
Product 1996 production (tons) Production capacity (tons/yr)

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### B. Please provide the type and amount of each raw material and body additive used in 1996 for manufacturing brick and structural clay products at your facility. Examples include clays, shale, and any additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade name. If the information requested is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. Raw materiaUbody additive Amount used in 1996 (tons/yr)



## D 1S ~ 

## S0 AS © 5

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### C. If available, please provide a copy of the MSDS's for the raw materials and additives listed above.
D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above.


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Page 4 of 28

1;11,

### E. Using Table 1, please provide information on the consumption and HAP composition of all glazes and colorants that contain HAP's or HAP precursors and that your facility applies to brick and structural clay products. Indicate whether the coatings are glazes or colorants. Also indicate the type of product that the coatings are applied to and the total weight of coatings used in 1996. If the glazes or colorants are formulated at your facility indicate so and provide the production capacity. List each ingredient of the glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient used in 1996. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table.
F. In the space below, please indicate any glazes or colorants used by your facility that do not contain HAP's and are substitutes for HAP-containing glazes or colorants used by your industry. Indicate which HAP-containing materials the 

## non-HAP glazes or colorants replace. Describe any limitations on the use of those substitute glazes or colorants.

G. If your facility colors brick and structural clay products by flashing, please indicate the types of substances used to flash the products and the amounts of those substances used in 1996. Substance 

# N. Amount used in 1996 Units (specifyj

H. If available, please provide a copy of the MSDS's for the glazes and colorants used by your facility. If your facility prepares its own glaze, please provide any available MSDS's for the glaze ingredients.

Page S of 28 

# I

### TABLE 1. CONSUMPTION AND HAP COMPOSTITON OF GLAZES .AND COLORANT ~



# I • - _ • • ; Type of product glazed or " colored S4v v&d - o&-" I 

# II 1996 consumption (tons/yr) 70 0 II Produced at facility? (yes/no) Production capacity (tons/yr) Total usage (weight) of each rY1q
~ 

### •u,., ~~ 

### Total 1996 ingredient (that is a HAP, Iqgredient usage, tons , contains a HAP, or is a HAP precursor) in 1996 

# R mAo s.L. c © 

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If additional space is required, please make copies of this page. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. 

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### D. 

### Using Table 7, please provide the following information on current monitoring procedures for each of the control devices listed in Tables 6A to 61): 

### parameters monitored (e.g., baghouse pressure drop), 

### monitoring frequency, monitoring devices used (e.g., differential pressure transducer, thermocouple), and 

### recordkeeping practices (e.g., manually recorded in log book, continuously recorded by electronic data acquisition system). Describe briefly other operation and maintenance (O&M) procedures for each control device. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table. VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing A. Please describe all pollution prevention practices (i.e., process modifications, such as re-use of discarded or rejected materials, or any practice that prevents or reduces the amount of air emissions, or the generation and release of solid waste or wastewater associated with the operation of air pollution controls). If the information requested here is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below.

Page 24 of 28 

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If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 28 of 28



# ~~

### NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION

DEPARTMENT OF ENVIRONIVIENT, HEALTH, AND NATURAL RESOURCES

, 

### DIVISION OF AIR QUALITY

'~ ✓ .J 

### lssue Date: April 9, 1997 Effective Date: Apri19, 1997 Expiration Date: March 31, 2002 Replaces Permit: 2493R5

To construct and operate air emission source(s) and/or air cleaning device(s), and for the discharge of the associated air contaminants into the atmosphere. In accordance with the provisions of Article 21B of Chapter 143, General Statutes of North Carolina as amended, and other applicable Laws, Rules and Regulations, Statesville Brick Conipany U.S. Highway 64/70 West Statesville, Iredell County, North Carolina is hereby authorized to construct and operate air emission sources and/or air cleaning devices and appurtenances consisting of:

a. One (1) sawdust/natural gas-fired kiln (ID No. 1; 10.1 tons per hour maximum capacity and 30 million Btu per hour heat input), b. One (1) simple cyclone (ID No. 2; nine feet in diameter) installed on a sawdust fuel dryer (ID No. 3; 3.75 tons per hour maximum drying capacity), and C. One (1) shale/clay grinding and screening operation (ID No. 4; 100 tons per hour process rate), 

### in accordance with the completed appGcation (APP025038) received March 6, 1997, including all plans, specifications, previous applications, and other supporting data, all of which are filed with the Department of Environment, Health, and Natural Resources and are incorporated as part of this Permit. This Permit is subject to the following specified conditions and limitations including any TESTING, REPORTING, OR MONITORING REQUIREMENTS:

A. SPECIFIC CONDITIONS AND LIMITATIONS 1. Any air emissiQn sources or control devices authorized to construct and operate above must be operated and maintained in accordance with the provisions contained herein. The Permittee shall comply with applicable Environmental Management Commission

i~

~~~

### Air Permit No. 2493R6

Page No. 2 Regiilations, including Title 15A North Carolina Administrative Code (NCAC), 

### Subchapter 2D .0515, .0516, .0521, and .0535. As required by 15A NCAC 2D .0515 "Particulates from Miscellaneous Industrial Processes," particulate emissions from the facility's air emissions sources (ID Nos . 1, 3, and 4) shall not exceed allowable emission rates. The allowable emission rates are, as defined in 2D .0515, a function of the process weight rate and shall be determined by the following equation(s), where P is the process rate in tons per hour (tons/hr) and E is allowable emission rate in pounds per hour (lbs/hr). P s 30 tons/hr: E= 4.1 (P)o' 6 '
b. P> 30 tons/hr: E= 55 (P) °- 1 `- 40 As required by 15A NCAC 2D .0521 "Control of Visible Emissions, visible emissions from the sawdust/natural gas-fired kiln and the shale/clay grinding operation (ID Nos. 1 and 4), established after July 1., 1971, shall not be more than 20 percent opacity when averaged over a six-minute period, except that six-minute periods averaging not more than 87 percent opacity may occur not more than once in any hour nor more than four (4) times in any 24-hour period. However, sources which must comply with 15A NCAC 2D .0524 "New Source Performance Standards" or .0525 "National Emission Standards for Hazardous Air Pollutants" must comply with applicable visible emissions requirements contained therein. 4. As required by 15A NCAC 2D .0521 "Control of Visible Emissions, visible emissions from the sawdust dryer (ID Nos. 3) existing as of July 1, 1971, shall not be more than 40 percent opacity when averaged over a six-minute period, except that six-minute periods averaging not more than 90 percent opacity may occur not more than once in any hour nor more than four (4). times in any 24-hour period. However, sources which must comply with 15A NCAC 2D .0524 "New Source Performance Standards" or .0525 "National Emission Standards for Hazardous Air Pollutants" must comply with applicable visible emissions requirements contained therein. As required by 15A NCAC 2D .0516 "Sulfur Dioxide Emissions from Combustion Sonrces," sulfiu dioxide emissions from the sawdust/natural gas-fired kiln (ID No. 1) shall not exceed 2.3 pounds per million Btu heat input. However, sources which must compl} , with 15A NCAC 2D .0524 "New Source Performance Standards" must comply with applicable sulftu dioxide emission requirements contained therein. The Permittee shall take all reasonable precautions with any operation, process, handling, transportation, or storage facilities to prevent fugitive emissions from becoming airborne. 7. NOTIFICATION REOUIREMENT 

### - As required by 15A NCAC 2D .0535, or for sources applicable to 15A NCAC 2D .0524 or .0525, when emissions exceed Environmental Management Regulations for more than four (4) hours, the Regional Supervisor, Division of Air Quality, shall be notified as promptly as possible, but in no case later than twenty-four (24) hours or on the next working day of becoming aware of the occurrence. Such notice shall specify the facility name and location, the nature and cause of the excess emission, the



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### Air Permit No. 2493R6

I'age No. 3 time when first observed,.the expected duration, and the estimated rate of emissions. This reporting requirement does not allow the operation of the facility in excess of Environmental Management Commission Regulations.
CYCLONE REOUIREMENTS 

### - Particulate matter emissions from the sawdust dryer (ID No. 3) shall be controlled by a cyclone (ID No. 2).

a. Inspection and Maintenance Requirements To comply with the provisions of this Permit and ensure that optimum control 

### efficiency is maintained, the Permittee shall establish an inspection and maintenance schedule/checklist based on manufacturer's recommendations. As a minimum, the inspection and maintenance program shall include an annual internal inspection to ensure the structural integrity. The results of this inspection and any maintenance performed on the cyclone, shall be recorded in a log book. b. Record Keeping Requirements A cyclone log book which shall be kept on site and made available to Division of Air Quality personnel upon request. Any variance from the cyclone

~ 

### manufacturer's recommendations shall be investigated with corrections made and date of actions recorded in the cyclone log book.
B. GENERAL CONDITIONS AND LIMITATIONS

1 0 1_ '•-0 N: : 5•\IM VLS 

## I . \ ji

~ : ; \• ~ ; ~ •\. : ~ ~ • 

### •: RENFWAL shallbe submitted to 

### Regional Supervisor North Carolina Division of Air Quality 919 North Main Street Mooresville, North Carolina 28115 2. PERMIT RENEWAL REQUIREMENT 

### - The Permittee, at least ninety (90) days prior to the expiration date of this Permit, shall request permit renewal by letter in accordance with 15A NCAC 2Q .0304 (d) and (f). Pursuant to 15A NCAC 2Q .0203 (i), no permit application fee is required for renewal of an existing air permit. The renewal request should be submitted to the Regional Supervisor, Division of Air Quality.
3. ANNUAL FEE PAYIVLNT 

### - Pursuant to 15A NCAC 2Q .0203 (a), the Permittee shall pay the Annual Permit Fee within thirty (30) days of being billed by the Division. Failure to pay the fee in a timely manner will cause the Division to initiate action to revoke the permit.
4. EQUO?MENT RELOCATIO 

### N - A new air permit shall be obtained by the Permittee prior to establishing, building, erecting, using, or operating the emission sources or air cleaning equipment at a site or location not specified in this permit.

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# ,_ ~ 

# i:~ 

### ir Permit No. 2493R6

No. 4 5. REPORTING REOLTIREMENT 

### - Any of the following that would result in previously 

### unpermitted, new, or increased emissions must be reported to the Regional Supervisor, Division of Air Quality:

a. Changes in the information submitted in the application regarding facility emissions; b. Changes that modify equipment or processes of existing permitted facilities; or C. Changes in the quantity or quality of materials processed. If appropriate, modifications to the permit may then be made by the Division of Air Quality to reflect any necessary changes in the permit conditions. In no case are any new or increased emissions allowed that will cause a violation of the emission limitations specified herein.

u. This permit is subject to revocation or modification by this Division upon a determination that infdrmation contained in the application or presented in the support thereof is incorrect, conditions under which this permit was granted have changed, or violations of conditions contained in this permit have occurred. The facility shall be properly operated and maintained at all times in a manner that will effect an overall reduction in air pollution. Unless otherwise specified by this permit, no emission source may be operated without the concurrent operation of its associated air cleaning device(s) and appurtenances.

~ 

### . This permit is nontransferable by the Permittee. Future owners and operators must obtain a new air permit from the Division of Air Quality.

~ 

### . This issuance of this permit in no way absolves the Permittee of liability for any potential civil penalties which may be assessed for violations of State law which have occurred prior to the effective date of this permit. J. This permit does not relieve the Perm.ittee of the responsibility of complying with all applicable requirements of any Federal, State, or Local water quality or land quality control authority. 10. Reports on the operation and maintenance of the facility shall be submitted by the Permittee to the Regional Supervisor, Division of Air Quality, at such intervals and in such of form and detail as may be required in such by the Division. Information required in such reports may include, but is not liniited to, process weight rates, firing rates, hours of operation, and preventive maintenance schedules. 11. A violation of any term or condition of this perniit shall subject the Permittee to enforcement pursuant to G. S. 143-215.114A, 143-215.114B, and 143-215.114C, including assessment of civil and/or criminal penalties.

0 1 ~

### Air Permit No. 2493R6

Page No. 5 12. Pursuant to North Caroli.na General Statute 143-215.3 (a) (2), no person shall refuse entry or access to any authorized representative of the Division of Air Quality who requests entry or access for purposes of inspection, and who presents appropriate credentials, nor shall any person obstruct, hamper, or interfere with any such representative while in the process of carrying out his official duties. Refusal of entry or access may constitute grounds for permit revocation and assessment of civil penalties. 13. The Permittee must comply with any applicable Federal, State, or Local requirements governing the handling, disposal, or incineration of hazardous, solid, or medical wastes, including the Resource Conservation and Recovery Act (RCRA) administered by the Division of Waste Management. 1

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### Crmit issued this the 9th day of April, 1997. NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION

Miciael S. Land , Acting Regional Supervisor Division of Air Quality By Authority of the Environmental Management Commission Air Permit No. 2493R6MATERIAL SAFETY DATA 

### SOD I UM CARBONATE 4FMC 497 -19 -8 

### U.S./CANADA VERSION EFFECTIVE: 02/13/97 PRINTED: 05/16/97 PRINTED FOR ............... WORTH CHEMICAL 2418 E PETTIGREW ST ATTN: SAFETY DIRECTOR DURHAM NC 27703


### ==ssassssaas=asssa=:sas=ss ~ 

### 1. CHEMICAL PRODUCT/COMPANY IDENTIFICATION =asa 

### PRODUCT NAME .............: SODIUM CARBONATE, ANHYDROUS SYNONYMS .................: SODA ASH, SODIUM CARBONATE ANHYDROUS INFORMATION PROVIDED BY..: FMC WYOMING CORPORATION 1735 MARKET STREET 

### PHILADELPHIA. PA 19103 (800) 253-7632 EMERGENCY PHONE NUMBERS CHEMTREC ..............: (800) 424-9300 MEDICAL ...............: (303) 595-9048 CALL COLLECT PLANT/OTHER ........... : (307) 875-2580 CALL COLLECT 

### COMPOSITION/INFORMATION ON INGREDIENTS ===== CAS * AND COMPONENTS ..... : 497-19-8 SODIUM CARBONATE 99.8%

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## 3. HAZARD IDENTIFICATION sasssssz=assezzaeaszas 

### EMERr,ENCY OVERVIEW ....... : WHITE GRANULAR SOLID. PRODUCT IS NON-COMBUSTIBLE. REACTS WITH ACIDS TO RELEASE CARBON DIOXIDE AND HEAT. IRRITATING TO THE EYES. CONTINUOUS CONTACT MAY IRRITATE SKIN. HEALTH EFFECTS ........... : DIRECT CONTACT WITH THE PRODUCT CAUSES IRRITATION OF THE EYES AND CONTINUOUS CONTACT MAY CAUSE SKIN IRRITATION (RED, DRY, CRACKED SKIN). EXCESSIVE LEVELS OF AIRBORNE DUST MAY IRRITATE THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT.
==3==x

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## 4. FIRST AID MEASURES =ss=saszzszsoss===s=s=saz 

### EYES .....................: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES, LIFTING THE UPPER AND LOWER LIDS OCCASIONALLY. SEE A MEDICAL DOCTOR IMMEDIATELY. SKIN .....................: WASH WITH PLENTY OF WATER FOR 15 MINUTES. IF IRRITATION OCCURS AND PERSISTS, OBTAIN MEDICAL ATTENTION. INHALATION ...............: REMOVE FROM EXPOSURE. IF DISCOMFORT OCCURS AND PERSISTS, OBTAIN MEDICAL ATTENTION. INGESTION ... . ........... .: RINSE MOUTH WITH WATER. DILUTE BY GIVING 1 OR 2 GLASSES OF WATER. DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SEE A MEDICAL DOCTOR IMMEDIATELY. NOTES TO PHYSICIAN.......: WHILE INTERNAL TOXICITY IS LOW, IRRITANT EFFECTS OF HIGH CONCENTRATIONS MAY PRODUCE (CONTINUED) PAGE 01NIATERIAL SAFETY DATA SOD I UM CARBONATE 

# AFMC

497 -19 -8 

### U.S./CANADA VERSION EFFECTIVE: 02/13/97 PRINTED: 05/16/97
FIRST AID MEASURES 

### CORNEAL OPACITIES AND VESICULAR SKIN REACTIONS IN HUMANS WITH ABRADED SKIN ONLY. TREATMENT IS SYMPTOMATIC AND SUPPORTIVE. =o=e=s=ss=asaso=3:s=asa=aslS 

### . FIRE FIGHTING MEASURES s=s=sasssx=====oasscs 

### EXTINGUISHING MEDIA ...... : SPECIAL FIREFIGHTINr, ..... : PROCEDURES DEGREE OF FIRE AND ....... : 

### EXPLOSION HAZARD HAZARDOUS DECOMPOSITION..: PRODUCTS WATER, WATER FOG, CARBON DIOXIDE (CO2), DRY CHEMICAL. WEAR FULL PROTECTIVE CLOTHING AND SELF CONTAINED BREATHINr, APPARATUS. NOT APPLICABLE. HEATED TO DECOMPOSITION, IT EMITS FUMES OF SODIUM OXIDE.

=====soa=ssszs=xssssssassm ~ 

## b. ACCIDENTAL RELEASE MEASURES
PROCEDURE FOR RELEASE .... : SWEEP UP AND RECYCLE INTO PROCESS IF OR SPILL CONTAMINATION DOES NOT PRESENT A PROBLEM. USE APPROPRIATE PROTECTIVE EQUIPMENT IF DUST IS GENERATED.OR CONTACT WITH EYES OR SKIN IS EXPECTED. FLUSH RESIDUES AND LIQUID TO HOLDING AREA FOR NEUTRALIZATION BEFORE DISCHARGE. HANDLING AND STORAGE HANDLING .................: USE AIR CONVEYING/MECHANICAL SYSTEMS FOR SULK TRANSFER TO STORAGE. FOR MANUAL HANDLINr, OF BULK TRANSFER USE MECHANICAL VENTILATION TO REMOVE AIRBORNE DUST FROM RAILCAR, SHIP OR TRUCK. USE APPROVED RESPIRATORY PROTECTION WHEN VENTILATION SYSTEMS ARE NOT AVAILABLE. SELECTION OF 

### RESPIRATORS IS BASED ON THE DUST CLOUD GENERATED. 

### VENTILATION ..............: PROVIDE GENERAL MECHANICAL AND/OR LOCAL EXHAUST VENTILATION TO PREVENT RELEASE OF AIRBORNE DUST INTO THE WORK ENVIRDNMENT. APPROVED RESPIRATORY PROTECTION SHOULD BE USED WHEN AIRBORNE DUST IS EXPECTED TO BE RELEASED. STORAGE ..................a STORE IN A COOL DRY AREA, AWAY FROM ACIDS.
=====aax=sssssss:sssssssss S. EXPOSURE CONTROLS/PERSONAL PROTECTION ==a=as 

### CONTROL MEASURES ......... : MINIMIZE EYE AND SKIN CONTACT BY USING APPROPRIATE PROTECTIVE EQUIPMENT. USE LOCAL OR GENERAL ROOM VENTILATION TO CONTROL AIRBORNE DUST THAT MAY BE GENERATED INTO THE WORK ENVIRONMENT. RECOMMENDED PERSONAL (CONTINUED) PAGE 02h1ATERIAL SAFETY DATA 

### SODIUM CARBONATE 

# fMC

497 —19 —8 

### I U.S./CANADA VERSION EFFECTIVE: 02/13/97 PRINTED; 05/16/97

=oz=aaazszszsa=sssa=xaazs 

### PROTECTIVE EQUIPMENT RESPIRATORY ........ :

EYES ......... .. .... : GLOVES.............: SPECIAL CLOTHING ... : AND EQUIPMENT 

### FOOTWEAR ........... :

MELTING/FREEZING POINT...: BOILINGPOINT ............: VAPOR PRESSURE...........: VAPOR DENSITY (AIR=1)....: ROOM TEMPERATURE.........: APPEARANCE AND STATE ODOR 

### .....................: SPECIFIC GRAVITY (H2O=1).: SOLUBILITY IN H20 % BY WT; % VOLATILES ..............: EVAPORATION RATE ......... : (BUTYL ACETATE=1) PH(AS IS) ...............: PH (1% SOLUTION) ......... : ODOR THRESHOLD ........... : DENSITY (G/ML) ........... : PARTITION COEFFICIENT .... : N—OCTANOL/WATER FLASHPOINT ..............s AUTOIGNITION TEMPERATURE.: FLAMMABLE LIMITS UPPER..: (AIR) LOWER..: EXPLOSIVE PROPERTIES ..... : OXIDIZING PROPERTIES......: SOLUBILITY ...............: — FAT SOLUBILITY (SOLVENT — OIL)

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### S. EXPOSURE CONTROLS/PERSONAL PROTECTION ======

USE APPROVED DUST RESPIRATORS FOR LOW LEVELS OF AIRBORNE DUST. HIGH CONCENTRATIONS MAY REQUIRE AIR SUPPLIED SYSTEMS. USE CUP TYPE CHEMICAL GOGGLES. USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT. ARM PROTECTORS AND APRONS. IF CLOTHING GECOMES CONTAMINATED REMOVE AND LAUNDER BEFORE REUSE. INDUSTRIAL SAFETY SHOES. 9. PHYSICAL AND CHEMICAL PROPERTIES 851 DEGREES C(1564 DEGREES F) DECDMPOSES NOT APPLICABLE NOT APPLICABLE WHITE. SOLID GRANULAR ODORLESS 2.509 33.2 MAXIMUM. NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE 11.4 NOT APPLICABLE DENSE GRADES,0.86-1.12; LIGHT GRADES,0.70



### - 0.90 

### NOT APPLICABLE NONCOMBUSTIBLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT AVAILABLE

10. STABILITY AND REACTIVITY sassaza=azszazszss 

### STABILITY ................: STABLE HAZARDOUS POLYMERIZATION.: WILL NOT OCCUR CONDITIONS TO AVOID ...... : CONTACT WITH ACIDS EXCEPT UNDER CONTROLLED CONDITIONS. MATERIALS TD AVOID ....... : ALUMINUM POWDER. ACIDS, FLUORINE, MOLTEN LITHIUM. MAJOR CONTAMINANTS THAT..: (CDNTINUED) PAGE 03MaTERIALSAFETYDATA 

### SODIUM CARBONATE 4FMC 497 -19 -8 U.S./CANADA VERSION 

### EFFECTIVE: 02/13/97 PRINTED: 05/16/97

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### 10. STABILITY AND REACTIVITY aaass::saa=aa

~ 

### a=ss C'ONTRIBUTE TO INSTABILITY NONE INCOMPATIBILITY .......... a REACTS WITH ACIDS WITH RELEASE OF LARGE VOLUMES OF CARBON DIOXIDE GAS AND HEAT. HAZARDOUS DECOMPOSITION..: NONE PRODUCTS SENSITIVITY TO MECH ...... : NONE IMPACT SENSITIVI•TY TO STATIC .... ; NONE DISCHARGE
=c_===saoaa=am=s=a=ssaaaas ~ 

### ll. TOXICOLOGICAL INFORMATION EYE CONTACT ..............: SEVERE IRRITANT (RABBIT) TOXICOLOGY 23:281-291 (1982) 

### SKIN CONTACT .............; NON-IRRITATING TO INTACT SKIN. MINOR IRRITATION MAY OCCUR ON ABRADED SKIN. NON-SENSITIZING (HUMANS, 0.25% SODIUM CARCONATE) TOXICOL. APPL. PHARMACOL. 31:481-490 (1975) 

### SKIN ABSORPTION .......... : NO DATA AVAILABLE. INHALATION ...............: LC50 = 2.3 MG/L (RAT,2 HR.) ENVIRON RES 31:138 (1983). INGESTION ................; LD50 = 4090 MG/KG (RAT) (RTECS 1985-6). 

### ACUTE EFFECTS FROM ....... : MAY CAUSE SEVERE IRfiITATION OF THE EYES, OVEREXPOSURE INCLUDING CORNEAL OPACITIES. DUSTS AND MISTS ARE IRRITATING TO THE SKIN, MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. CHRONIC EFFECTS FROM.....: MAY CAUSE INFLAMMATION OF THE MUCOUS MEMBRANES OVEREXPOSURE IN THE RESPIRATORY TRACT AND OF THE SKIN. (EFFECTS CONSIDERED INCLUDE: SENSITIVITIES, CARCINOGENICITY, TERATOGENICITY, MUTAGENICITY, SYNERGISTIC PRODUCTS, AND ANY MEDICAL CONDITIONS GENERALLY RECOGNIZED 

### AS BEING AGGRAVATED BY EXPOSURE.)



### ====o===aaaaa=sasasaaasass ~ 

### l2. ECOLOGICAL INFORMATION ENVIRONMENTAL FATE ....... : BIODEGRADABILITY DOES NOT APPLY TO INORGANIC 

### SUBSTANCES. NO OTHER DATA AVAILABLE. ENVIRONMENTAL EFFECTS .... ; 96 HR LC50 (DAPHNIA MAGNA) = 265-565 MG/L 96 HR LC50 (BLUEGILL SUNFISH) = 300-320 MG/L

(CONTINUED) PAGE 04h1ATERIAL SAFETY DATA SOD IUM CARBONATE 

# 4FMC

497 -19 -8 

### U.S./CANADA VERSION EFFECTIVE: 02/13/97 

## PRINTED: 05/16/97

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~ =sxssassrssasssssa 

## 13. DISPOSAL CONSIDERATIONS =====a=====__=====a WASTE DISPOSAL METHOD .... : SALVAGE AS MUCH MATERIAL AS POSSIBLE AND RETURN TO PROCESS IF CONTAMINATION DOES NOT PRESENT A PROBLEM. DISPOSE IN AN APPROVED LANDFILL IN ACCORDANCE WITH ACCEPTED GOVERNMENTAL REGULATIONS.

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### 14. TRANSPORT INFORMATION sasa:ssoo:=r===rro=a

~ 

### DOT PROPER SHIPPING NAME.: IATA 

### .....................: IMDG



### ..................... DOT CLASSIFICATION.......: DOTLABELS ...............: DOTMARKING ..............: DOT 

### PLACARD ..............: UN 

### NUMBER ................: HAZARDOUS SUBSTANCE/RQ ... : 49 

### STCC NUMBER ........... : PRECAUTIONS TO BE TAKEN..: IN TRANSPORTATION OTHERSHIPPING...........: INFORMATION SODIUM CARBONATE NOT APPLICABLE NOT APPLICABLE NON HAZARDOUS NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE SWEEP UPr RETURN TO CONTAINER FOR DISPOSAL. SODIUM CARBONATE IS GENERALY (r,RAS) WHEN USED WITH CURRENT MANUFACTURING PRACTICES. AND MARK AS WASTE REGARDED AS SAFE. GOOD

===a==a=sasass3sssasssa:ss ~ 

## 15. REGULATORY INFORMATION ar=sa=:s=s=s=r=a=rra OSHA 

### EXPOSURE LIMITS SUESTANCE(S) ........... : 

### OSHA PEL-TWA .......... : 

### STEL .............: 

### CEILING 

### .......... : SKIN DESIGNATION.: ACr,IH TLV-TWA .......... : 

### STEL

... ............ 

### CEILING .... ......: SKIN DESIGNATION.: TARGET ORGAN EFFECTS ..... : CARCINOGENIC POTENTIAL...: REGULATED BY OSHA ...... : 

### LISTED ON NTP REPORT...: IARC GROUP 1. 2A. 2B...: U.S. EPA REQUIREMENTS RELEASE REPORTING CERCLA (40 CFR 302) 

### LISTED SUBSTANCE(S)....: RQ ...............: 

### CATEGORY ......... : RCRA WASTE NO .... : 

### SODIUM CARBONATE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE EYE NO NO NO



### NOT LISTED NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE (CONTINUED) PAGE 05NIATERIALSAFETYDATA 

### SODIUM CARBONATE 

# 4FMC

497 —19 —8 U.S./CANADA VERSION EFFECTIVE: 02/13/97 PRINTED: 05/16/97

REGULATORY INFORMATION 

### UNLISTED SUBSTANCE(S)..: NOT APPLICABLE RQ............... NOT APPLICABLE CHARACTERISTIC ... : NOT APPLICABLE RCRA WASTE NO .... : NOT APPLICABLE 

### SARA TITLE III SEC 313 (40 CFR 372)...........: LISTED TOXIC CHEMICAL..: NOT LISTED INVENTORY REPORTING SARA TITLE III SEC 311/312 (40 CFR 370) SUBSTANCE(S) ........... : SODIUM CARBONATE HAZARD CATEGORY ........ : IMMEDIATE (ACUTE) HEALTH HAZARD (IRRITANT) PLANNING THRESHOLD ..... : 10.000 POUNDS EMERGENCY PLANNING SARA TITLE III SEC 302-303 (40 CFR 355) LISTED SUBSTANCE(S) .... : NOT APPLICABLE RQ .....................: NOT APPLICABLE PLANNI.NG THRESHOLD.....: NOT APPLICABLE U.S. TSCA STATUS ......... : LISTED CANADA INGREDIENT DISCLOSURE LIST SUCSTANCE(S) ........... : SODIUM CARBONATE CONTROLLED PRODUCT ....... a 

### YES HAZARD SYMBOLS ........... : TOXIC CLASS & DIVISION ....... a 

### CLASS D. DIVISION 2, SUBDIVISION E. PRODUCT IDENTIFICATION N0: NOT APPLICABLE DOMESTIC SUBSTANCE LIST..s LISTED CEPA PRIORITY LIST ....... : NOT LISTED CARCINOGENICITY ACGIH APPENDIX A ....... : NOT LISTED A1 — CONFIRMED HUMAN ... : NOT LISTED A1 — SUSPECTED HUMAN ... : NOT LISTED IARC GROUP 1 OR 2 ........ : NO LAEEL LANGUAGE (US/CANADA) HEALTH .................: DUST MAY CAUSE SEVERE IRRITATION OF EYES AND SLIGHT IRRITATION OF NOSE AND THROAT. REPEATED CONTACT MAY CAUSE REDNESS AND DRYr CRACKED SKIN. PHYSICAL ...............: NOT APPLICABLE HANDLING AND STORAGE ... s 

### DO NOT STORE CLOSE TO ACIDS. WEAR EYE PROTECTION AND APPROVED DUST RESPIRATOR WHEN EXCESSIVE DUST IS PRESENT. 

### FIRST AID ..............: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS. OBTAIN MEDICAL ATTENTION. FLUSH SKIN WITH WATER. STATE REGULATIONS........: CALIFORNIA PROPOSITION 65: SAFE WATER AND TOXIC ENFORCEMENT 

### ACT OF 1986. THE FOLLOWING CHEMICALS HAVE BEEN DETECTED. . (CONTINUED) PAGE 06h1ATERIAL SAFETY DATA 

### SODIUM CARBONATE IFMC
497 —19 —8 

### U.S./CANADA VERSION EFFECTIVE: 02/13/97 PRINTED: 05/16/97

=aa====assssosssasasssss:s ~ ls 

### . REGULATORY INFORMATION ARSENIC,PPM AS AS203 = 0.03 TOTAL CHROMIUM,PPM CR = 0.03 LEAD,PPM PB.......... = <1 CADMIUM,PPM CD....... = <0.1 ALL OTHER LISTED CHEMICALS ARE NOT DETECTED OR NOT SUSPECTED TO EE PRESENT.
_=====aa==zss=azasasasssos ~ 

### l6 

### . OTHER INFORMATION ss:zsassszsasess=osas==ox 

### PRODUCT USES .............: GLASS MANUFACTURE, DETERGENT MANUFACTURE, SODIUM CHEMICALS AND CARBONATE CHEMICALS MANUFACTURE, PULP AND PAPER, BRINE TREATMENTs WATER HARDNESS REMOVAL, PH ADJUSTMENT IN WATER OR WASTE WATER, FLUE GAS DESULFURIZATION, COAL TREATMENT, ION EXCHANGE RESIN REGENERATION. NFPA 704 HEALTH ..............: 2 FLAMMABILITY........: 0 REACTIVITY.......... 0 SPECIAL HAZARD...... 0 (DEGREE OF HAZARD 0 = NO HAZARD 4 = SEVERE HAZARD) HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) 

### HEALTH ...............• 2 FLAMMABILITY:........: 0 REACTIVITY: .......... : 0 PERSONAL PROTECTION INDEX (PPI) ........ :H (SAFETY GOGGLES, GLOVES, APRON AND VAPOR RESPIRATOR)

------------------------------------------------ THIS CHEMICAL IS CERTIFIED TO ANSI/NSF STANDARD 60. DRINKING WATER TREATMENT CHEMICALS— HEALTH EFFECTS. THE MAXIMUM DOSAGE LEVEL FOR THIS CHEMICAL IS 150 MG/L. _=====aa=sas3sssas=sasas:s ~ =sasasasxsssssasasosxsasasassssseszaa====m==ss 

### THE CONTENTS AND FORMAT OF THIS MSDS ARE IN ACCORDANCE WITH OSHA HAZARD COMMUNICATION AND CANADA'S WORKPLACE HAZARDOUS MATERIAL 

### INFORMATION SYSTEM (WHMIS).

PAGE 07

## Material Safety Data Sheet
Substance Identification identity: MANGANESE DIOXIDE Cas # : 1313-13-9 Trade Names: Brickox, GranuSpeck
Manufacturer: The Prince Manufacturing Co. Emergency: Chemtrec

One Prince Plaza 1-800-424-9300 Quincy, IL 62301 217-222-8854 

### Components and Contaminants Manganese Compound ( as Mn) 7439-96-5 5 mg/m° (C) 5 mg/m° (C) 51-55% Mn Iron Oxide 1309-37-1 --- -- 1-5% Fe 2 0 3 Silica, Crystalline Quartz (respirable) 14808-60-7 0.1 mg/m' 0.1 mg/m' (TWA) 1-5% Si0 2 Aluminum Oxide (non-fibrous) (respirable fraction) 1344-28-1 5 mg/m 3 5 mg/m' (TWA) 1-7% AI Z O, Barium Oxide 1304-28-5 -- --- 0.2-2% Ba0 

## Physical Data Boiling Point: NA Specific Grravlty (H = 0=1): 5.0 Vapor Pressure (mm/Hg): NA Melting Point: 535° C Vapor Density (Air-1): NA Evaporation Rate (Butyl Acetate=1): NA Solubility in Water: insoluble Appearance and Odor: black to brownish black, no odor 

## Fire and Explosion Hazard Data Flash Point: Not combustibie Flammable Limits: LEL NA UEL NA Extinguishing Media: Foam, CO Z , dry chemical or water. Special Fire Fighting Procedures: In the event of fire, wear full protective clothing and NIOSH-approved seif-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Unusual Fire and explosion hazards: Not combustibie, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. Increases the flammability of any combustible substance. 

### Reactivity Data Stability: Stable under ordinary conditions of use and storage. Conditions to avoid: Do not heat or grind in the presence of easiiy oxidizable substances or organic matter. Incompatibility (materials to avoid): Easily oxidizable substances, suifur, suifides, phosphides, hydrophosphides, chlorates, peroxides, aiuminum powder, rubidium acetyiide, potassiurn azide, chiorine trifluoride. Reacts with hydrochioric acid to form con•osive chlorine gas. Hazardous Decomposition or Byproducts: Upon heating it decomposes to form manganese sesquioxide and oxygen which facilitates combustion. Hazardous Polymerization: Will not occur. 

## Health Hazard Data Route of Entry: INHALATION: May irritate the respiratory tract. May increase the incidence of upper respiratory infections (pneumonia). Prolonged exposure to siiica dust may result in silicosis, a fibrotic lung disease. SKIN: May cause irritation. INGESTION: May cause abdominal pain and nausea. Manganese dioxide dust is poorly absorbed through the gut.

Manganese Dioxide, Page 1 

# ~ Reviewed July 1996 Unchanged since July 19y 

# ~

## Health Hazard Data Health Hazards (Acute and Chronic): Chronic exposure and inhalation of excessive manganese dust may cause disorders of the central nervous system. Carcinogenicity: NTP: No IARC Monographs: Yes (Silica) Signs and Symptoms of Exposure: Early symptoms of manganese toxicity include sluggishness, sleepiness, and weakness in legs. Symptoms of silicosis include impaired pulmonary function and wheezing. Aggravation of Pre-existing Conditions: Persons with impaired respiratory function may be more susceptible to the effect of this substance. Emergency and First Aid Procedures: IF INHALED, remove to fresh*air and seek medical attention for any breathing difficulty. IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. IN CASE OF EYE CONTACT, flush eyes immediately with water for at least 15 minutes. Seek medical attention if irritation persists. IF INGESTED, induce vomiting immediately by giving two glasses of water and sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

### Precautions for Safe Handling and Use Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory protection. Recover uncontaminated material for use. Vacuum or sweep remaining material, keeping dust to a minimum. Isolate wet material from dry and store away from combustible materials.

. Waste Disposal Method: Dispose of unreclaimable material in a RCRA-approved waste facility. Handling and Storing Precautions: Manganese dioxide is classifled as an oxidizer and should be stored in a dry place away from combusitlbes and sources of high heat. Protect containers from damage and keep closed when not in use. Other Precautions: Observe good personal hygiene. Wash after handling. 

### Control Measures Respiratory Protection: Use NIOSH approved pan`aculate respirator if dust generation occurs or is anticipated. OSHA standard 1910.134 or ANSI Z88.2-1980 specifications are recommended. Ventilation: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details. Protective Gloves: Yes Eye Protection: Safety goggles are recommended. Other Protective Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonged exposure to skin. Work and Hygienic Practices: ' Obsenre good personal hygiene. Wash after handling. 

### SARA Title III Section 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting req Emergency Planning and Community Right-to-Know Act of 1986 and of 40 CFR 372.45: Com onent 

### SAS % bv Weiaht Manganese Dioxide 

### 1313-13-9 51-55% Mn Barium Oxide 1304-28-5 0.1-1.8% Ba This information must be inciuded in all MSDS's that are copied and distributed for this material.

Manganese Dioxide, Page 2 „ ` Reviewed luly 1996 Unchanged since July 1996 

### ~

### 3LATZRIAL BAYETY DATA 88EET MSDS No: 037

CNZDSIN CORPORATION 

### 258 Elm Street New Canaan, CT 06840 

### Emergency Telephone Number (203) 966-8880 

### Telephone Number for Information (203) 966-8880 

### Date Prepared: October 23, 1995

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### SECTION 1: IDEZTTIlICATION
PRODUCT NAlME
: 

### Olivine, various grades SYNONYMS: Magnesium Iron Silicate

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### SECTION 2s COM80N8NT9 CAS# Component Percentace Exposure Limits 

### 1317-71-1 Olivine >99.3t PEL- 5 mg/m 3 TWA (respirable fraction) TLV- 10 mg/m 3 TWA (total dust) MSHA- 5 mg/m 3 TWA (respirable fraction) 7440-02-0 Nickel Compounds (as Nickel) 0.1-0.3t PEL- 1 mg/m 3 TWA TLV- 1 mg/ry TWA MSHA- 1 mg/m 3 TWA 7440-47-3 Chromium Compounds (as Chromium)_ 0.1-0.4t PEL- 0.5 mg/m 3 TWA TLV- 0.5 mg/m 3 TWA MSHA- 0.5 mg/m 3 TWA
PEL means OSHA Permissible Exposure Limit. TLV means American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value. MSHA means Mine Safety and Health Administration Exposure Limit. TWA means 8 hour time weighted average. Note: The Permissible Exposure Limits (PEL) reported above are the pre-1989 limits that were reinstated by OSHA June 30, 1993 following a decision by the lith Circuit Court of Appeals. These PELs are now being enforced by Federal OSHA. Be aware that cnore restrictive exposure limits may be enforced by some states, agencies or other authorities.
.........................................:.....................:.....s..............



### Page 1 of 6 Pages



## ~~MSDS No: 037

SECTION 3: SAZARDS IDSNTIPICATION


### EMERGENCY OVERVIEW This product is a chemically inert, non-combustible mineral. Excessive inhalation of dust may cause lung injury with symptoms of shortness of breath and reduced pulmonary function. See "Cancer Status" in this Section 3.
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~ aasaasassaaasssssasasssssassaasssasasassssasssssssasaaaassssaasssss s s s HEAI,TH HAZARDS : 

### Inhalation: 

### Inhalation of dust may cause irritation of the nose, throat and respiratory passages. Skin Contact: 

### No adverse effects expected. Eye Contact: 

### Contact may cause mechanical irritation and possible injury. Ingestion: 

### No adverse effects expected for normal, incidental ingestion.
Chronic Health Effects: 

### Prolonged overexposure to any nuisance dust may cause lung injury. Symptoms include cough, shortness of breath, aad reduced pulmonary fuaction. This product contains small amounts of nickel and chromium compounds. Hexavalent chromium has not been detected in this product (detection limit 0.11r). Overexposure to nickel and chromium compounds may cause respiratory and skin sensitization.
Cancer Status: 

### Nickel compounds are classified by ZARC as "carcinogenic to humans" (Group 1) and by NTP as "reasonably anticipated to be a carcinogen". Olivine is not listed as a carcinogen or suspected carcinogen by IARC, NTP or OSHA. Medical Conditions Aaaravated bY Exposure: Individuals with respiratory disease, including but not limited to, asthma and bronchitis, or subject to eye irritation should be excluded from exposure. Sians and Symptoms of Exposure: Overexposure to nuisance dusts may cause mucous membrane and respiratory irritation, cough, sore throat, nasal congestion, sneezing and shortness of breath.

sssaaasaaasaasaasssasasssssassaasssssaassasaasssssssssssasssssssssssaasssssaasassass SECTION 4: TIRST AID 

### Gross Inhalation: 

### Remove victim to fresh air. If breathing has stopped, perform artificial respiration. If breathinQ is difficult have qualified personnel administer oxygen. Get prompt medical attention. Skin Contact: 

### No first aid should be needed since this product does not affect the skin. Wash exposed skin with soap and water before breaks and at the end of the shift.

Page Z of 6 Pages 

# ,37

### MSDS No: 037

E,ye Contact: 

### Flush the eyes immediately with large amounts of running water, lifting the upper and lower lids occasionally. If irritation persists or for imbedded foreign body, get immediate medical attention. Inge stion:



### If large amounts are swallowed, get immediate medical attention.

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### BECTION S: FIRE AND S7CPLOSION DATA 

### Flash Point (Method Used): Fully oxidized, will not burn. Autoianition Tema: will not burn. Flammable Limits: LEL: Not applicable 4EL: Not applicable Extinauishing Media: This product will not burn but is compatible with all extinguishing media. Use any media that is appropriate for the surrounding fire. Special Fire Fighting Procedures: None required with respect to this product. Firefighters should always wear self-contained breathing apparatus for fires indoors or in confined areas. Unusual Fire and Explosion Hazards: 

### None. Hazardous Combustion Products: 

### None.

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### SECTION 6: ACCIDENTAL RSLlASE MZASQRE9 

### wear appropriate protective equipment. If uncontaminated, collect using dustless method (HEPA vacuum or wet method) and place in appropriate container for use. If contaminated: a) use appropriate method for the nature of contamination, b) consider possible toxic or fire hazards associated with the contaminating substance. Collect for disposal.

ssssaassssasssssssssaaaasssssassasssssssassssssssssa ~ sssasassssssssesssssassssssssss SECTION 7: IiANDLING AM STORAGs 

### Avoid breathing dust. Use normal precautions against bag breakage or spills of bulk material. Avoid creation of respirable dust. Use good housekeeping in storage and use areas to prevent accumulation of dust in work area. Use adequate ventilation and dust collection. Maintain and use proper, clean respiratory equipment (See Section 0. Launder clothing that has become dusty. wARN and TRAIN employees in accordance with state aad federal regulations. ATARN YOTJR EMPLOYEES (AND YOUR CUSTOMERS - IISERS IN CASE OF RESALE) BY POSTING AND OTH£R MEANS OF T8E HAZARDS AND OSAA PRECAtJTIONS TO BE USED. PROVIDE TRAINING FOR YOUR EMPLOYEES ABOUT OSAA PRECAUTIONS.
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### Page 3 of 6 pages

~-v~MSDS No: 037



### SECTION 8: EJCPOSQRS CONTROLS/PERSONAL PROTBCTION 

### Ventilation: 

### Use local exhaust as required to maintain exposures below applicable occupational exposure limits. See also ACGIH "Industrial Ventilation - A Manual for Recommended Practice", (current edition). Respiratory Protection: 

### Use appropriate respiratory protection for respirable particulates based on consideration of airborne workplace concentrations and duration of exposure. Refer to the most recent standards of ANSI (Z88.2) OSFiA (29 CFR 1910.134), MSHA (30 CFR Parts 56 and 57) and NIOSH Respirator Decision Logic. Gloves: 

### Protective gloves recommended. Eye Protection: 

### Safety glasses or goggles recommended. Other Protective Esuipment/Clothina: 

### As appropriate for the work environment. Dusty clothing should be laundered before reuse.

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### 9: PFIYSICAL AND CHEMICAL PROPERTIES 

### Appearance and Odor: 

### Light green to gray-green sand-size granules, odorless. Hc Not applicable Specific Gravitv (waterai): 2.3 - 3.6 

### Hoilina Point: 

### Not applicable Vapor Pressure: Not applicable Melting Point: 

### 2800 - 3200"F Vapor Densitv: Not applicable Solubility in water: 

### Insoluble Evaporation Rate: Not applicable Percent Volatile: 08 ssssssaasssassssasssssssssssssi esssssssssssssssssssssssssssssssssssssssssssssssssssas 

### SECTION 10: STABILITY AND REACTIVZTY 

### Stability: 

### Stable Conditions to Avoid: 

### None Incompatibility: 

### None known. xazardous Decomposition Products: 

### None known. Hazardous Polymerization: 

### Will not occur. Conditions to Avoid: 

### None

assasasssssssssssssssa ~ sssassssssssssssssssssssssssssssssssssssssssssssssasssassssss SsCTION 11: TOxICOLOGIChL ZNFORMATlolt 

### No acute toxicity data is available for product or components. Refer to Section 3 for health hazard information. as iaasaaiis

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~ SSS

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### Page 4 of 6 Pages

, 

## J,

### MSDS No: 037

SECTION 12: ECOLOGICAL INlOR?SATION 

### No ecotoxicity data is available. This product is not expected to present an environmental hazard.

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### SECTION 13: DISPOSAL waste Disposal Method: 

### If uncontaminated, dispose as an inert, non-metallic mineral. If contaminated, dispose in accordance with all applicable local, state/provincial and federal regulations.

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### SECTION 14: TRANSPORTATION DATA
U.S. DOT HAZARD CLASSIFICATION Proper Shipping Name: 

### Not Regulated Technical Name: 

### N/A UN Number: 

### N/A Hazard Class/Packina Group: 

### N/A Labels Rernaired: 

### None DOT Packaaina Recuirements: 

### N/A Exceptions: 

### N/A

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### SECTION 15: OTEER RECiQLATORY INFORMATION SARA 311/312: 

### Hazard Categories for SARA Section 311/312 Reporting: Chronic health
SARA 313 

### This Product Contains the Following Chemicals Subject to Annual 

### Release Reporting Requirements Under the SARA Section 313 (40 CFR 372): Nickel Compounds 0.1 - 0.3t Chromium Compounds 0.1 - 0.4% CERCLA Section 103 Reportable OuantitY: 

### None California Proposition 65: 

### This Product contains the following substances known to the State of California to cause cancer and/or reproductive harm: This product contains nickel compounds. Toxic Substances Control Act: 

### A11 of the components of this product are listed on the EPA TSCA Inventory or exempt from notification requirements. European InventorSr of Comercial Chemical Substances: 

### A11 of the components of this product are listed on the SINECS Inventory or exempt from notification requirements. Canadian Environmental protection_Act= 

### All the components of this product are listed on the Canadian Domestic Substances List or exempt from notification requirements.

Page 5 of 6 Pages

/4lMSDS No: 037



### Japan MITI: All of the components of this product are existing chemical eubstances as ' defined in the Chemical Substance Control Law. Australian Inventory of Chemical Substances: All of the components of this product are listed on the AICS inventory or exempt from notification requirements. Canadian wH+iIS Classification: Class D, Division 2, Subdivision A(Very Toxic Material causing other Toxic Effect)

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### 16: OTSHR INlORMATION

E~ 

### sropean Community Labeling Classification: 

### N/A Euro ean Community Risk and Safety Phrases: 

### None NFPA Hazard Ratings_ 

### Health: 1 Fire: 0 Reactivity: 0 HMIS Hazard Rating: 

### Health: 1 8ire: 0 Reactivity: 0
References• 

### Registry for Toxic Effects of Chemical Substances (RTECS), 1995 Hawley's Condensed Chemical Dictionary, twelfth edition NTP Seventh Annual Report on Carcinogens, 1994 Patty's Industrial Hygiene and Toxicology

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### CREATION DATE: October 23, 1995 REVISION DATE: October 23, 1995 The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. The information aet forth herein is based on technical data the Unimin Corporation believes reliable. It is intended for use by persons having technical skill and at their own discretion and risk. Since conditions of use are outside the control of Unimin Corporation, no warranties, expressed or implied, are made and no liability is assumed in connection with any use of this information. Any use of these data and information must be determined by the user to be in accordance with federal, state and local laws and regulations.

Page 6 of 6 Pages 

# y/

### - - [?S'-OMER - STATESVILLE BRICK COMPANY :age: 1 MATERIAL SAFETY DATA SHEET Prepared: 01/28/94
EMERGENCY PHONE Cerdec Corporation Drakenfeld Products ?.0. Box 519 Washington PA 15301 Information Phone: 412-223-5900 Prepared By : Lucy Sten

Product Safety Specialist CHEMTREC (800) 424-9300 This number is to be used onlyin the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals

SECTION I - IDENTITY INFORMATION

TRADE NAME : 5832A BUFF SPERSASTAIN CAS NUMBER : Mixture
PRODUCT CODE : 50F0832A0000 FAMILY/CHEMICAL NAME: Pigment and Silica Mixture.
PRODUCT TYPE: Clayware Stains.
:AZARD STATEMENT: This Material Safety Data Sheet (MSDS) has been prepared in compliance with the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous substance under that standard. The key Immediate Hazards are: - Skin, eye and respiratory irritant.

SECTION II - HAZARDOUS INGREDIENTS
This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of inetal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small

### ?age: 02 MATERIAL SAFETY DATA SHEET 5832A BUFF SPERSASTAIN (50F0832A0000)

SECTION II - HAZARDOUS INGREDIENTS (cont.)

:fAZARD STATEMENT: percentage of the starting materials may remain in this product 

### and are considered hazardous under OSHA. The pigment and/or frit ingredient(s) do not have exposure limit values. Exposure limit values for the components are listed beneath each ingredient as a guideline for safe use of these products. =ngrzdients CAS NUMBER ACGIH - TLV OSHA - PEL C.I. PIGMENT BROWN 24 68186-90-3* Carcinogenicity: 

### This product has not been reviewed for carcinogenicity by IARC, NTP or OSHA; however, antimony trioxide (Sb203) is considered to be carcinogenic by IARC (Group 2B).
ANTIMONY COMPOUND Sb TWA 0.5 mg/M3 0.5 mg/M3 CHROMIUM (III) COMPOUND Cr (+3) TWA 0.5 mg/M3 0.5 mg/M3 TITANIUM OXIDE Total Dust TWA 10.0 mg/M3 10.0 mg/M3 RESP 5.0 mg/M3

- 

### RYSTALLINE SILICA 14808-60-7 

### Carcinogenicity: 

### This product is considered to be carcinogenic by IARC (Group 2A).
CRYSTALLINE SILICA Dust RESP 0.1 mg/M3 0.1 mg/M3 .kMORPHOUS SILICA 112945-52-5 Carcinogenicity: 

### This product is not considered



# ~~

### Page: 03 MATERIAL SAFETY DATA SHEET 5832A BUFF SPERSASTAIN (50F0832A0000)

SECTION II - HAZARDOUS INGREDIENTS (cont.) Ingredients CAS NUMBER ACGIH - TLV OSHA - PEL

to be carcinogenic by IARC (Group 3) or OSHA.
AMORPHOUS SILICA Dust TWA 10.0 mg/M3 6.0 mg/M3

APPEARANCE rlEIGHT PER GALLON BOILING RANGE VOC VAPOR DENSITY EVAPORATION RATE SOLUBILITY IN WATER SECTION III - PHYSICAL DATA

: Brown Powder : N/AV : N/AP : 0 %(See Note in Section XII : Non Volatile : Non Volatile : Insoluble - Addendum)

SECTION IV - FIRE AND EXPLOSIVE HAZARD DATA

FLASH POINT FLAMMABILITY CLASS _OWER EXPLOSION LIMIT :JPPER EXPLOSION LIMIT

Z

- 

### XTINGUISHING MEDIA:
Water. : N/AP : NON-COMBUSTIBLE : N/AP : N/AP

FIRE FIGHTING PROCEDURES-SPECIAL: Fire-Fighters should wear self-contained breathing apparatus and full protective clothing when fighting chemical fires. Use water spray to cool nearby containers and structures exposed to fire.



# Y'1

### ag`: 04 MATERIAL SAFETY DATA SHEET 5832A BUFF SPERSASTAIN (50F0832A0000)

SECTION IV, - FIRE AND EXPLOSIVE HAZARD DATA (cont.)

'1NUSUAL FIRE AND EXPLOSION HAZARDS: This product will not burn. Use appropriate techniques to fight surrounding fire.

SECTION V - REACTIVITY DATA

:TABILITY Stable :AZARDOUS POLYMERIZATION : Will not occur

- 

### ONDITIONS TO AVOID:
None Known.

:NCOMPATIBILITY: None known.

:AZARDOUS DECOMPOSITION: will not occur.

SECTION VI - HEALTH HAZARD DATA
This product contains either pigment(s) that belong to the mixed 

### metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of inetal atoms and oxygen acoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small percentage of the starting materials may remain in this product and are considered hazardous under OSHA.

c~ 

### ~ /

### =age: 05 MATERIAL SAFETY DATA SHEET 5832A BUFF SPERSASTAIN (50F0832A0000)

SECTION VI - HEALTH HAZARD DATA (cont.)

PRIMARY ROUTES OF EXPOSURE: Inhalation, dermal and ingestion.

OVEREXPOSURE EFFECTS:

CONTAINS CRYSTALLINE SILICA: Crystalline silica can cause silicosis, a lung disease characterized by coughing, wheezing, impaired lung function and increased sputum production. This damage can be progressive and may cause death. May cause cancer following repeated and prolonged inhalation of the fine dust. Smoking aggravates these effects. Skin and eye contact may cause irritation due to mechanical abrasion.
This product contains mixed metal oxide pigment(s) which consist of antimony and trivalent chromium in combination with other materials.

CONTAINS ANTIMONY COMPOUNDS: May contain antimony trioxide which may cause coughing and rhinitis following breathing of dust. Lung tumors have been observed in female rats following inhalation exposure.
CONTAINS CHROMIUM (III) COMPOUNDS: Compounds of chromium, in its trivalent state, have no established toxicity. When swallowed, it is not expected to cause local or systemic effects since it is poorly absorbed. No specific effects have been observed from inhalation. Skin contact has been reported to cause skin irritation but not ulceration. Allergic skin reactions may occur in sensitive individuals, although it is believed that the hexavalent (VI) form of chromium is responsible for most of the reported cases.



# Z16

### ?age: 06 MATERIAL SAFETY DATA SHEET 5832A BUFF SPERSASTAIN (50F0832A0000)

SECTION VI - HEALTH HAZARD DATA (cont.)

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Respiratory conditions.
EMERGENCY AND FIRST AID PROCEDURES:

EYES For eye contact, immediately flush eyes for at least 15 minutes with running water. Hold eyelids apart to ensure rinsing of the entire eye surface and lids with water. Get immediate medical attention.
SKIN For skin contact, wipe away excess material with dry towel. Then wash affected areas with plenty of water, and soap if available, for several minutes. Get medical attention if irritation occurs.
=NHALATION: If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
INGESTION: If swallowed, give at least 3-4 glasses of water, but do not induce vomiting. Do not give anything by mouth to an unconscious or convulsing person. Get medical attention.
=HYSICIAN'S NOTE:


### None specified.

SECTION VII - TOXICOLOGY INFORMATION
Toxicology data of some components is available upon request. Please contact the Product Safety Specialist at (412) 223-5900.



# ~~

### Page: 07 MATERIAL SAFETY DATA SHEET 5832A BUFF SPERSASTAIN (50F0832A0000)

SECTION VII - TOXICOLOGY INFORMATION (cont.)

TOXICOLOGY INFORMATION

SECTION VIII - SPILL OR LEAK PROCEDURES

SPILL PROCEDURES: Wear appropriate protective equipment. Avoid the generation of dust. Vacuum or shovel,material and place in closable container(s) for disposal. [IASTE DISPOSAL METHODS: Dispose in accordance with Federal, State and Local regulations.

SECTION IX - SPECIAL PROTECTION INFORMATION

VENTILATION: Adequate ventilation should be provided to keep dust and vapor concentrations below acceptable Exposure Limits. Discharge from the ventilation system should comply with the applicable air pollution control regulations. Eliminate ignition sources.

PROTECTIVE GLOVES: Use gloves as a standard industrial handling procedure.

EYE PROTECTION: Wear safety glasses or goggles to protect against exposure.

RESPIRATORY PROTECTION: Appropriate respiratory protection is required when exposure to airborne contaminant is likely to exceed acceptable limits. Respirators should be selected and used in accordance with OSHA 

# Vf

### ='age: 08 MATERIAL SAFETY DATA SHEET 5832A BUFF SPERSASTAIN (50F0832A0000)

SECTION IX - SPECIAL PROTECTION INFORMATION (cont.)

RESPIRATORY PROTECTION: Subpart I(29 CFR 1910.134) and manufacturer's recommendations.

OTHER PROTECTIVE EQUIPMENT: None specified.

SECTION X - SPECIAL PRECAUTIONS

~ 

### ABELING INFORMATION: WARNING! Skin, eye and respiratory irritant. Contains crystalline silica which can cause lung damage, including cancer. Keep away from heat and flame. Avoid contact with eyes, skin and clothing. Do not breathe dust. Keep away from food products. Wash thoroughly after handling and before eating, drinking or using cosmetic or tobacco products or toilet facilities. Use with adequate ventilation. Keep container closed when not in use. FIRST AID: 

### If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case.of contact, immediately flush eyes or skin with plenty of water. Remove contaminated clothing. Get medical attention. IN CASE OF FIRE: Use water, dry chemical or carbon dioxide. IN CASE OF SPILL: Vacuum and dispose in accordance with federal, state and local regulations. For industrial use only.



# m

### Page: 09 MATERIAL SAFETY DATA SHEET 5832A BUFF SPERSASTAIN (50F0832A0000)

SECTION XI - REGULATORY INFORMATION

SARA 313 TITLE III - TOXIC CHEMICALS LIST: 96 0 1 

### Antimony Compound

: llo 

### Metal As Sb 96% Chromium (3) Compound . 5a Metal As Cr

PENNSYLVANIA RIGHT-TO-KNOW ACT: C.I. Pigment Brown 24 68186-90-3* S Quartz 14808-60-7 H Amorphous Silica 112945-52-5 H S= Pennsylvania Special Hazardous Substance H = Pennsylvania Hazardous Substance
T'OXIC SUBSTANCE CONTROL ACT (TSCA): A11 ingredients in this product are listed on the U.S. EPA TSCA Inventory of Chemical Substances.

SECTION XII - ADDENDUM

DEFINITIONS AND ABBREVIATIONS
Note: The V.O.C., listed in Section III, Physical Data, is an

estimated/calculated value based upon the EPA Method 24 for determining V.O.C.
ACGIH = American Conference of Governmental Industrial Hygienists C(Ceil) = The concentration that shall not be exceeded during any part of

the working exposure. CAS = Chemical Abstracts Service Registry Number EPA = Environmental Protection Agency IARC = International Agency for Research on Cancer LEL = Lower Explosion Limit N/AP = Not Applicable N/AV = Not Available

,V-71

### Page: 10 MATERIAL SAFETY DATA SHEET 5832A BUFF SPERSASTAIN (50F0832A0000)

SECTION XII - ADDENDUM (Cont.
NIOSH = National Institute for Occupational Safety and Health NTP = National Toxicology Program 

### OSHA = Occupational Safety and Health Administration PEEL = Permissible Exposure Limits SARA = Superfund Amendments and Reauthorization Act STEL = Short Term Exposure Limit. Usually a 15 minute time weighted

average exposure that should not be exceeded at any time during a work day. TLV = Threshold Limit Values TSCA = Toxic Substance Control Act WA = Time Weighted Average. Exposure concentration for a normal

8 hour work day and a 40 hour work week. O^ = Volatile Organic Content
DISCLAIMER The information and recommendations contained herein are.based upon data

~ 

### .;elieved to be correct. However, no guarantee or warranty of any kind expressed or implied is made with respect to the information contained herein.



# S/

### Stationary Source Sampling Report Statesville Brick Company Sawdust Dryer and Kiln Exhaust Stacks Statesville, North Carolina Trigon Project # 046-97-066 May 1997

'~ ~~--

### Stationary Source Sampling Report Statesville Brick Company Sawdust Dryer and Kiln Exhaust Stacks Statesville, North Carolina Trigon Project # 046-97-066 May 1997

,~

# STATIONARY SOURCE SAMPLING REPORT
FOR
STATESVILLE BRICK COMPANY STATESVILLE, NORTH CAROLINA

Sawdust Dryer and Kiln Exhaust Stacks

Performed by: Trigon Engineering Consultants, Inc. Environmental, Health & Safety Division 6200 Harris Technology Blvd. Charlotte, North Carolina 28269

704/598-1049 

### Trigon Project # 046-97-066 May 1997



## v`J



# ~

### REPORT CERTIFICATION

This report, all testing details, and the final results have been performed under the supervision and reviewed by the persons named below.

Date 

# Nrc` Ii d* Signature Tom E. Wynn Project Manager Environmental, Health & Safety Division Trigon Engineering Consultants, Inc.

Date 

# Lw'" , Ll I

~ 

# , H5 5

Signature 

# ___2
Pau11R. Jenkins, Jr. Quality Assurance Manager Environmental, Health & Safety Division Trigon Engineering Consultants, Inc.

Date J.A. "Tony" Blanton Stack Testing Department Manager Environmental, Health & Safety Division Trigon Engineering Consultants, Inc.

ii

~

~

### TABLE OF CONTENTS

1.0 INTRODUCTION ..................................................................................................................1 1.1 Purpose ..........................................................................................................................1 1.2 Outline of Test Program ...............................................................................................1 1.3 Test Participants ............................................................................................................2 2.0 PROCESS DESCRIPTION ...................................................................................................3 2.1 Discussion .....................................................................................................................3 Figure 1- Process Air Flow Schematic ........................................................................4 3.0 SAIVIPLING METHODS .......................................................................................................5 3 .1 Sampling Strategy .........................................................................................................5 3.2 Sampling and Analytical Procedures ...........................................................................5 3.2.1 Sampling Ports, Traverse Points and Cyclonic Flow Determination ...............................................................5 3.2.2 Stack Gas Velocity and Volumetric Flow Rate Detemiination ...................6 3.2.3 Dry Molecular Weight Determination .........................................................7 3.2.4 Moisture Determination ................................................................................8 3.2.5 Determination of Hydrogen Fluoride ...........................................................9 3.2.6 Sampling Ports and Points ..........................................................................10 Location of Sampling Ports and Poirits Figure 2- Sawdust Dryer Exhaust Stack ...................................................11 Figure 3- Kiln Exhaust Stack ....................................................................12 3.3 Quality Assurance and Quality Control .....................................................................13 4.0 RESULTS ...............................................................................................................................14 4 .1 Summary of Results ...................................................................................................14 4 .2 Discussion ...................................................................................................................14 4.3 Detailed Stack Sampling Results ...............................................................................14 Summary of Results Table 1- Sawdust Dryer Exhaust Stack .....................................................................15 Table 2- Kiln Exhaust Stack ......................................................................................16 5.0 APPENDICES .......................................................................................................................17 A. Summary of Results and Example Calculations B. Field Data Sheets C. Method 26 Laboratory Data D. Production Documentation E. Calibration Data



# iii ON

### 1.0 INTRODUCTION

This section describes the purpose, a brief outline including the sampling and analytical strategy, and the personnel involved in the test program.

1.1 Purpose The purpose of this sampling project was to determine concentrations, and emission rates of hydrogen fluoride from the Sawdust Dryer and Kiln Exhaust Stacks located at the Statesville Brick Company in Statesville, North Carolina. The results of the sampling and the documentation provided in this report will be used for emission inventory purposes.

1.2 Outline of Test Program Stationary source sampling was performed on May 15, 1997 by the Environmental, Health & Safety Division of Trigon Engineering Consultants, Inc. at the Statesville Brick Company facility in Statesville, North Carolina. Three 1-hour sampling runs were conducted simultaneously at the Sawdust Dryer and Kiln Exhaust Stacks. United States Environmental Protection Agency (US EPA) Methods 1 through 4 and Method 26 were used for the determination of hydrogen fluoride concentrations, and emission rates. All sampling and analytical procedures used were those established by the US EPA in standard reference test methods and appropriate state-of-the-art analytical procedures. The test runs were conducted during normal operating conditions.

1 

# 6-7

### 13 Test Participants

A list of the project participants, titles, affiliation and telephone numbers can be found below. Participant Title Affiliation Contact Tom E. Wynn Project Manager Trigon Engineering Telephone: (704) 598-1049 Consultants, Inc. Facsimile: (704) 598-1050 E. Logae Buder Environmental Trigon Engineering Sciendst Consultants,

. Inc .L f• A.k N John D. Archer Environmental Scientist Trigon Engineering ~ ~~ A '

~ 

## w Consultants, Inc. Jimmy L. Wallace Environmental Trigon Engineering Scientist Consultants, Inc. _=a... Brad Brown Technical Services Statesville Brick Telephone: (704) 872-4123 Company Facsimile: (704) 872-4125



# J--e

### 2.0 PROCESS DESCRIPTION

This section contains a brief description of the process, the type and amount of materials handled, and a typical process air flow schematic.

2.1 Discussion The Statesville Brick Company facility located in Statesville, North Carolina manufactures bricks in a tunnel kiln. The tunnel kiln was fired with 100% sawdust. Brick cars were being pushed at the rate of 19.35 cars per day. Each car was loaded with 6,336 bricks. The fired weight of each brick was 3.8 pounds per unit.

The air from the furnace zone of the kiln flows to the kiln exhaust fan and is then ducted out in two directions. The kiln exhaust duct is vented straight to the atmosphere. The second exhaust stream goes to the sawdust dryer, through a cyclone control device and then discharged to the atmosphere.. Figure 1 details the process air flow schematic from this process.
Production data during sampling was supplied by Statesville Brick Company personnel and is presented in Appendix D. All sampling was performed during material processing. Tests were suspended during intermittent periods when the process was not being run. There were no unusual process conditions noted during the sampling.

3 

# s~

## Tunnel Kiln Atmosphere 

# T

Stack k—Sampling Location


# T
Cyclone Atmosphere 

# T T

Sawdust Kiln Dryer Stack 

# T T <—Sampling Location

Tunnel Kiln

Figure 1 Process Air Flow Schematic 

# 0

### 3.0 SAMPLING METHODS

This section describes the sampling strategy, sampling and analytical methods, and quality assurance/quality control procedures implemented during this project.

3.1 Sampling Strategy The sampling and analytical procedures used during this test program were those established by the US EPA and the North Carolina Department of Environment, Health and Natural Resources (NC DEHNR). Sampling runs were conducted in triplicate to validate the sampling. Tests were conducted during normal operating conditions. There were no unusual conditions noted during the sampling.

3.2 Sampling and Analytical Procedures The US EPA methods used in this sampling program were Method 1 for the location of sampling ports and points, and determination of cyclonic flow, Method 2 for volumetric flow rate determination, Method 3 for the determination of dry molecular weight of the stack gas, and Method 4 for the determination of moisture in the stack gas. Method 26 was used to determine concentrations and emission rates of hydrogen fluoride. A sampling and analysis synopsis is discussed briefly in the following subsection. These test methods are available in the Code of Federal Regulations Volume 40, Part 60 or by request from Trigon.
3.2.1 Sampling Ports, Traverse Points and Cyclonic Flow Determination The Sawdust Dryer and Kiln Exhaust sampling locations were prepared according to the criteria in Method 1. The duct diameters upstream and downstream from the sampling ports were determined prior to sampling. The number of traverse points were chosen with respect to sampling port location. For velocity traverses Method 1 specifies a minimum of 12 traverse points for sampling ports located >8h2 downstream/upstream stack diameters from flow disturbances and 24 traverse points when located >2/>0.5. The amount of cyclonic flow was determined according to the criteria detailed in Method 1.

F~



## ~ l

### 3.2.2 Stack Gas Velocity and Volumetric Flow Rate Determination



### Method 2 is used for determining the average gas velocity in a stack from measurements of gas density and the average velocity head with a Type S(Stausscheibe or reverse type) pitot tube. This method is applicable for quantifying gas flows which meet the criteria of Method 1. Method 2 cannot be used for direct measurement of gas streams which exhibit cyclonic flow conditions as determined by Method 1, Section 2.4.
In principle measurements of velocity head and temperature are performed at the traverse points specified by Method 1. A properly scaled differential pressure gauge was selected for the range of Ap values encountered during the traverse. A 0- 10 and 0- 0.25 inches of water inclined manometers were used as the differential pressure gauge at the Sawdust Dryer and Kiln Exhaust Stacks respectively.
During this project, the sampling locations met all of the criteria detailed in Method 1. Gas stream density was determined by Method 3. Moisture determination was performed by Method 4. The principal components of the gas velocity measurement system were sequentially: * A calibrated stainless steel Type S pitot tube and Type K thermocouple; * Leak-free interface tubing between pitot tube and differential pressure gauge; * A 0 to 10 or 0- 0.25 inch inclined manometer and; * An 1VIST tra.ceable pyrometer. The apparatus was set-up according to manufacturer and reference method recommendations. Pretest and posttest leak checks were conducted using procedures outlined in Method 2, Section 3.1. Velocity head and temperature measurements were performed at the traverse points specified by Method 1. The atmospheric and static pressure of the stack was also determined for each set of velocity head readings. The volumetric flow rate calculations used were those specified in Method 2, Section 5. A more comprehensive explanation of the reference method is detailed in the Quality Assurance Handbook for Air Pollution Measurement Systems: Volume III (EPA/600/R-94/038c).

P., 

# & 9—

### 3.2.3 Dry Molecular Weight Determination

Method 3 is applicable for determining carbon dioxide and oxygen concentrations and dry molecular weight of a sample from a gas stream of a fossil-fuel combustion process. This method may also be applicable to other processes where it has been determined that compounds other than carbon dioxide, oxygen, carbon monoxide, and nitrogen are not present in concentrations suff cient to affect the results.
In principle a gas sample was withdrawn from each emission source by single-point, grab sampling. The collected sample was then analyzed for percent carbon dioxide and percent oxygen. The dry molecular weight determination was performed using an Fyrite analyzer.
During this project, the gaseous components were collected using a Method 3 sampling system following the Analytical Procedures outlined in the reference method. The principal components of the sampling system were sequentially: * A stainless steel probe; * A one-way squeeze bulb and saturator tube and; * Leak-free transport tubing to transfer the sample to the analyzer. The analysis was performed with a Fyrite type combustion gas analyzer at the time of sample collection. The dry molecular weight was calculated using Equation 3-1, Section 7 of Method 3. The analyzer was maintained and operated according to the instructions recommended by the manufacturer and in accordance with Method 3 criteria. The Fyrite analyzer was validated by analyzing a sample of ambient air which was verified to be 21.0% ± 0.3%.

7 

# 0

### 3.2.4 Moisture Determination

Method 4 involves the determination of stack gas moisture. Stack gas moisture must be measured when the flue gas flow rate or a pollutant gas concentration is determined. The moisture content is used to correct the emission concentration or mass emission rate to a dry basis. EPA Method 4, Section 3.3 of the EPA's Quality Assurance Handbook, Volume III, EPA-600/4-77-027b, was used to measure stack gas moisture content. Section 3.3 of the Quality Assurance Handbook, Volume III, provides detailed information on the application of Method 4.
The flue gas moisture content was determined using wet bulb/dry bulb thermometers and pardal pressure, vapor and saturated vapor pressure equations along with the reference method incorporated into the Method 26 sampling train. The wet bulb/dry bulb technique is described in Method 4 and is summarized below: * Moisten the wet bulb thermometer wick with deionized water; * Insert both thermometers into the flue gas stream and monitor the wet bulb temperature; *. When the wet bulb temperature has stabilized, record both the wet bulb and dry bulb thermometer temperatures; * Calculate the flue gas moisture content (PMV) using the equations below.

SVP = Vapor Pressure of Water at Saturation, inches of Mercury SVP =10x y (6.6911- (3144/(Wet Bulb + 390.86)))



### PMV = Percent Moisture by Volume PMV =(SVP -(0.000367(P, b ADry Bulb - Wet Bulbxl +((Wet Bulb - 32)/1571))))1(P b J x 100



### P., s = Absolute Pressure of Stack Gas P ab , = (Barometric Pressure + (Static Pressure/13.6))
A summary of the reference method will be described in the Method 26 sampling and analytical 

### procedures.

8 

# 49 

# ~

### 3.2.5 Determination of Hydrogen Fluoride

Testing for hydrogen fluoride was performed according to EPA Method 26. Gaseous and parkiculate pollutants were withdrawn from the emission source and collected in a multicomponent sampling train. In principle, particulate matter includes any material that was condensed at or above the filtration temperature of approximately 250 degrees Fahrenheit and was collected on a quartz glass fiber filter. The gaseous components were then bubbled through a measured volume of 0.1N sulfuric acid and 0.1N sodium hydroxide to determine moisture and hydrogen fluoride content of each emission source. The principal components of the sampling system were sequentially: * A borosilicate glass sample probe; * A heated (248°F f25°F) probe and filter assembly with quartz glass fiber filter; * An impinger train consisting of four sequential impingers. Impingers 1 and 2 containing 15 ml each of O.1N sulfuric acid. Impinger 3 contained 15 ml of O.1N sodium hydroxide followed by an impinger containing 20 grams of silica gel; and * A critical orifice metering system capable of maintaining a 2.0 liter per minute sampling rate and accurately deterniining the sample volume according to those specifications in the reference method. Sample clean up began immediately after each test run. Hydrogen fluoride was collected in the 0.1N sulfuric acid solution in impingers 1 and 2. The liquid in these impingers was measured to the nearest milliliter. The collected sample was placed in a glass storage container along with the deionized water rinse of impingers 1 and 2 and connecting glassware. The container was sealed and the liquid level was marked. The hydrogen fluoride samples were then shipped to Enthalpy Analytical, Inc., Raleigh, North Carolina with chain of custody documentation where they were analyzed by ion chromatography. The liquid in impinger 3 was measured to the nearest milliliter and discarded. The moisture collected by the silica gel in the fourth impinger was determined to the nearest 0.1 gram. All collected condensate measurements were recorded on the moisture determination and sample analysis data recovery form. The laboratory analyses and chain of custody documentation can be found in Appendix C.

9 / (f

~ •;7

### 3.2.6 Sampling Ports and Points

The dimensions of the Sawdust Dryer and Kiln Exhaust sampling sites and the location of the sampling ports and points are detailed in Figures 2 and 3. Method 1 sampling criteria was maintained in each instance. The stack cross sections were divided into the appropriate equal areas as detailed in Method 1. The ports were labeled using sequential alphabetical notation. Sampling for hydrogen fluoride was performed at a single representative point during each 60 minute sampling run. Velocity traverses were performed before and after the Method 26 sampling runs to determine the volumetric flow rate of each emission source.

10

'O-0

## Sawdust Dryer Ezhaust Stack

.~

,

. ~ 

# 384"

. r
~



# j

:


### 29.5" --/' h 

# F MI 

# ~ sEC 1 - 10w K—. 

# 1 

# 1 K 

## K

110.5"

Not to Scale



## Figure 2

Location of Sampling Ports and Points

11



## ~ 

# 7

### 37.5"



# ~ -38.0"- 

# ~

~



### 33"



# ~ I 240"



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. .

. .

. .

. . ! 

### i

. ~

. . . . . ~

. . . . . ~

~

. . . . . ~ 

## A B C D E
SEC?ION K—K



# ~ 

# r K 

# ~ 1 K 

## Kiln Ezhaust Stack

Not to Scale



## Figure 3

Location of Sampling Ports and Points

12 

# IN

### 3.3 Quality Assurance and Quality Control



### Trigon Engineering Consultants, Inc., has established quality assurance and quality control (QA/QC) guidelines for providing the highest quality sampling and analytical data from source tests. These QA/QC procedures were implemented to ensure the acceptability and reliability of the data generated.
In summary, a high degree of data quality was maintained throughout this project. All instrumentation leak checks and QA criteria were met. Quality control procedures for Method 26 have included the analysis of a reagent blank. The results of the reagent blank and quality control procedures can be found in Appendix C with the laboratory data.
Field data and final laboratory results were entered into Trigon's Air Quality Data System by an environmental scientist, independently audited by the Project Manager, and reviewed by the Quality Assurance Manager for verification of data. After. QC review by the QA Manager, the Department Manager verified the final report for completeness and reasonableness of data. The report was returned to the Project Manager for review and preparation of the final draft. The report requires the signature of the Project Manager, QA Manager, and the Department Manager before release to the client. Data and final reports are archived in a secured area for a minim 

### um period of three years.
Trigon's field and iaboratory test equipment has been maintained and calibrated in accordance with quality assurance procedures established by the US EPA in the Quality Assurance Handbook for Air Pollution Measurement Systems: Volume III. Equipment calibrations including pre-test and post-test calibration data are presented in Appendix E.

13 

# bC//

### 4.0 RESIJLTS

This section presents the mean hydrogen fluoride sampling results. Tabular results are also provided to present data from individual sampling runs collected during this project. Detailed sampling results and example calculations for the test program can be found in Appendix A. Field data sheets are presented in Appendix B.

4.1 Summary of Results The table below is a synopsis of the hydrogen fluoride sampling conducted at the Sawdust Dryer and Kiln Exhaust Stacks.
Hydrogen Fluoride Sampling Results Sawdust Dryer Kiln Exhaust Concentration, lbs/dscf 1.54E-06 5.65E-06 Emission Rate, pounds/hour 1.48 1.40 Emission Rate, pounds/ton 0.15 0.14

4.2 Discussion Results from this test program will be used by the Statesville Brick Company for emission inventory purposes.

43 Detailed Stack Sampling Results Tables 1 and 2 present the data from individual sampling runs at the Sawdust Dryer and Kiln Exhaust sampling sites. Included in these tables are gas velocity and volumetric flow rates, exhaust gas temperatures, and hydrogen fluoride concentrations, and emission rates.



# 14
JL ~

### TABLE 1 Summary of Results, Hydrogen Fluoride Sampling

Sawdust Dryer Exhaust Stack

Run Number 1 2 3 Avg. Date 05/15/97 05/15/97 05/15/97 

### Run Duration, Minutes 60 60 60 Sample Time, 24-hour clock 1100-1200 1240-1340 1400-1500 Average Stack Temperature, °F 184.8 183.5 179.9 182.7 Stack Gas Velocity, feet/second 80.5 80.9 81.5 81.0 Stack Gas Flow Rate, 16077 16006 16132 16072 dry standard cubic feet/minute*(DSCFIVl) Stack Gas Flow Rate, 22938 23050 23225 23071 actual cubic feet/minute(ACFl1) Hydrogen Fluoride: Catch, mg 2.08 2.73 2.95 2.59 Concentration, lbs/dscf 1.23E-06 1.61E-06 1.78E-06 1.54E-06 Emission Rate, lbs/hr 1.18 1.55 1.72 1.48 Emission Rate, lbs/ton 0.12 0.16 0.18 0.15

* 68°F, 29.92 Inches Hg


## 15



# ~ 6

### TABLE 2 Summary of Results, Hydrogen Fluoride Sampling

Kiln Exhaust Stack

Run Number 1 2 3 Avg. Date 05/15/97 05/15/97 05/15/97 Run Duration, Minutes 60 60 60 Sample Time, 24-hour clock 1100-1200 1240-1340 1400-1500 Average Stack Temperature, °F 509.7 530.3 526.0 522.0 Stack Gas Velocity, feet/second 14.8 14.5 14.8 14.7 Stack Gas Flow Rate, 4211 4061 4144 4138 dry standard cubic feet/minute*(DSCFIVI) Stack Gas Flow Rate, 8763 8606 8790 8720 actual cubic feet/minute(ACFNn Hydrogen Fluoride: Catch, mg 7.21 8.16 12.7 9.36 Concentration, lbs/dscf 4:28E-06 4.96E-06 7.72E-06 5.65E-06 Emission Rate, lbs/hr 1.08 1.21 1.92 1.40 Emission Rate, lbs/ton 0.11 0.12 0.20 0.14

* 68°F, 29.92 Inches Hg
16
ly-

### 5.0 APPENDICES

This section contains detailed supportive documentation that encompasses all aspects of the emission test program. Its contents serve as the foundation for the test report. The emission test report presents a summary of the information gathered during the sampling activities. The information contained in the appendices is necessary to facilitate the review of the emission test report and determine whether proper procedures were used to accomplish the test plan objectives.
Defensible data and the subsequent pollutant concentrations and emission rates is one of the primary objectives of any 

### emission test program. To this end, all results, example calculations, field data sheets, sample recovery, laboratory results, chain of custody documentation, and equipment calibrations have been provided to support these objectives.



## 17



# ~



# 3

### APPENDIX A

SUMMARY OF RESULTS AND EXAMPLE CALCULATIONS



## w., 

# /Y

### SUIVIMARY OF RESULTS EPA METHOD 26 Determination of Hydrogen Halide and Halogen Emissions Statesville Brick Statesville, North Carolina Sawdust Dryer Exhaust Stack 2 05/15/97 

## 60 28.71 -0.096 28.614 111.6 75.1 3.73 10.3 0.49 0.115 11.5 0.885 17.0 4.0 0.0 29.320 28.017 0.84 1.26 183.5 80.9 4.75 

## 16006 23050 Run 1 Date: 05/15/97 TT Net Time of Test, minutes 60 PB Barometric Pressure, in. Hg 28.75 SP Static Pressure, in Hg -0.081 PS Stack Pressure, Absolute, in. Hg 28.673 VM Volume Gas Sampled, Liters 112.2 TM Avg. Gas Meter Temp., Deg. F 77.3 VSTD Volume Dry Gas Sampled, Standard cu. ft. 3.74 VM Volume of Water Collected, ml 9.5 VMV Volume of Water Vapor, Standard cu. ft 0.45 Bws Moisture Content of Gas Stream 0.107 PMV Percent Moisture 10.7 MFD Mole. Fraction Dry Gas, lb/lb mole 0.893 P02 Percent Oxygen, Dry 16.5 PCO2 Percent Carbon Dioxide, Dry 4.5 PCO Percent Carbon Monoxide, Dry 0.0 MD Mole. Wt. Stack Gas, Dry Basis, lb/lb mole 29.380 MW Mole. Wt. Stack Gas, Wet Basis, lb/lb mole 28.164 CP Pitot Tube Coefficient 0.84 DPS Avg. Sqrt. Delta P, in. H20 1.25 TS Avg. Stack Temp., Deg. F 184.8 VS Avg. Stack Velocity, ft/sec 80.5 AS Area Stack, Ft2 4.75 QS Gas Volume Flow, Dry Std. Cond., CFM 16077 QA Gas Volume Flow, Actual, CFM 22938
A

- 

### 2 

### 3 Avg 05/15/97 - 

## 60 - 28.70 28.72 -0.110 -0.096 28.590 28.626 109.8 111.2 76.3 76.2 3.66 3.71 10.5 10.1 0.49 0.48 0.119 0.114 11.9 11.4 0.881 0.886 18.0 17.2 

## 3.0 3.8 0.0 0.0 29.200 29.300 27.867 28.016 0.84 0.84 1.27 1.26 179.9 182.7 81.5 81.0 4.75 4.75 

## 16132 16072 23225

- ' 

# ~ TFRIGON

### SUMMARY OF RESULTS EPA METHOD 26 Determination of Hydrogen Halide and Halogen Emissions Statesville Brick Statesville, North Carolina Sawdust Dryer Exhaust Stack Hydrogen Fluoride Concentrations and Emission Rates 

### FMF Hydrogen Fluoride Catch, mg 2.08 2.73 2.95 2.59 CAN Hydrogen Fluoride Concentration, lbs/dscf 1.23E-06 1.61E-06 1.78E-06 1.54E-06 CAW Hydrogen Fluoride Emission Rate, lbs/hr 1.18 1.55 1.72 1.48

"3 

# 7F

### SUIVIMARY OF RESULTS EPA METHOD 26 Determination of Hydrogen Halide and Halogen Emissions Statesville Brick Statesville, North Carolina Kiln Exhaust Stack 2 05/15/97 60 28.71 -0.0004 28.710 110.4 83.8 3.63 6.5 0.31 0.078 7.8 0.922 16.0 5.0 0.0 29.440 28.550 0.84 0.18 530.3 14.5 9.90 4061 8606 Run 1 Date: 05/15/97 TT Net Time of Test, minutes 60 PB Barometric Pressure, in. Hg 28.75 SP Static Pressure, in Hg -0.0006 PS Stack Pressure, Absolute, in. Hg 28.749 VM Volume Gas Sampled, Liters 112.2 TM Avg. Gas Meter Temp., Deg. F 81.4 VSTD Volume Dry Gas Sampled, Standard cu. ft. 3.71 VW Volume of Water Collected, ml 7.0 VMV Volume of Water Vapor, Standard cu. ft 0.33 Bws 1Vloisture Content of Gas Stream 0.082 PMV Percent Moisture 8.2 MFD Mole. Fraction Dry Gas, lb/lb mole 0.918 P02 Percent Oxygen, Dry 16.5 PCO2 Percent Carbon Dioxide, Dry 4.5 PCO Percent Carbon Monoxide, Dry 0.0 MD Mole. Wt. Stack Gas, Dry Basis, lb/lb mole 29.380 MW Mole. Wt. Stack Gas, Wet Basis, lb/lb mole 28.452 CP Pitot Tube Coefficient 0.84 DPS Avg. Sqrt. Delta P, in. H20 0.19 TS Avg. Stack Temp., Deg. F 509.7 VS Avg. Stack Velocity, ft/sec 14.8 AS Area Stack, Ft2 9.90 QS Gas Volume Flow, Dry Std. Cond., CFM 4211 QA Gas Volume Flow, Actual, CFM 8763 A-4 3 Avg 05/15/97 - 60 - 28.70 28.72 -0.0006 -0.0005 28.699 28.719 110.4 111.0 83.8 83.0 3.63 3.66 6.9 6.8 0.32 0.32 0.082 0.080 8.2 8.0 0.918 0.920 17.5 16.7 3.5 4.3 0.0 0.0 29.260 29.360 28.335 28.446 0.84 0.84 0.19 0.19 526.0 522.0 14.8 14.7 9.90 9.90 4144 4138 8790 

# Mo N

### SUMMARY OF RESULTS EPA METHOD 26 Determination of Hydrogen Halide and Halogen Emissions Statesville Brick Statesville, North Carolina Kiln Exhaust Stack Hydrogen Fluoride Concentrations and Emission Rates FMF Hydrogen Fluoride Catch, mg 7.21 8.16 12.7 9.36 CAN Hydrogen Fluoride Concentration, lbs/dscf 4.28E-06 4.96E-06 7.72E-06 5.65E-06 CAW Hydrogen Fluoride Emission Rate, lbs/hr 1.08 1.21 1.92 1.40



## i A-5 1 / 0

~ 

### _

### SUMMARY OF RESULTS EPA METHOD 26 Determination of Hydrogen Halide and Halogen Emissions Statesville Brick Statesville, North Carolina Kiln Exhaust Stack Example Calculations Run 1 Pressure of Stack, Absolute, in. Hg PS = PB - SP = 28.749 Volume of Water Vapor, Standard cu. ft VMV = 0.04709* VM = 0.33 Moisture Content of Gas Stream

VMV BWS= --------------------------- = 0.082

VSTD + VMV Percent Moisture

100 * VMV PMV= -- ----------- ------------- = 8.2

VSTD + VMV Mole Fraction of Dry Gas

100 - PMV MFD = ------------------- --- = 0.918

100 Mole. Wt. Stack Gas, Dry Basis, lb/lb mole MD = 0.44 * %CO2 + 0.32 * %02 + 0.28 * (100 - %CO2 - %02) = 29.38 Molecular Weight of Stack Gas, lb/lb mole MW = MD * MFD + [18 *(1-MFD)] = 28.452 Stack Gas Velocity at Stack Conditions, ft/sec VS = 85.49 * CP * DPS * SQRT (TS + 460)/(PS * MW) = 14.8 Dry Gas Measured Corrected To Standard Conditions, cu. ft. T(std) PB VSTD = Vm *0.0351 * Y * * _--- = 3.71 TM P(std) Stack Gas Volumetric Flow at Standard Cond. Dry, CFM 1058.82 * VS * PS * (1- Bws) QS = -- ----- -- ----- --- ---- ---- = 4211

TS + 460

A-6

### SUMMARY OF RESULTS EPA METHOD 26 Determination of Hydrogen Halide and Halogen Emissions Statesville Brick Statesville, North Carolina Kiln Exhaust Stack Stack Gas Volumetric Flow at Actual Cond. CFM QA = AS * VS * 60 = 8763 Hydrogen Fluoride Concentration, lbs/dscf (At Standard Conditions) 2.205e-06 * F1VIF CAN = ----- ------------- -- ---- ----



### VSTD Hydrogen Fluoride Emission Rate, lbs/hr (At Standard Conditions) CAW= 60*CAN* QS = 4.28E-06

1 

## 0 

# 1 Standard Conditions 68 Deg. F, 29.92 inches Hg

A-7 

# ~

### APPENDIX B

FIELD DATA SHEETS

B-1 U 

# ~` Point Yoa ~ 9ft u( :" St.aic ID sStadt . :

m: :. Df9tahoar.Pco

~ o-. .

L

~~ Iae:Virall :

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~ From: : On[s

~ de uI Porr

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~ O

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### zq S 3• 5 ~ ~ 

### 3• y$ 17.7 

### Za. S ,S- -2 a. o :Y .AA
s 2
~ 

### v z4.S 7• 0 ~•3~ 3sZ , ~ 

### Zq. S O 7 

## 3, 7V 0 zq.S

- 

### L

~ 

### 2. 13 q 'F2 ,3 2 r. S a y. O 2 y.. 2, Y i° 8R•.) 7-4.S -2G. O it 93• 3 ZK. S 7..r.2 0 ia 77,7 Za. S.2.y 9.t7 v
- , Ra



### B-2♦ ~ 6 ~ n !

~ .7 ~ a♦ ~ 3. 1

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. a 6

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a & 7 u+ L. 

# 1

! 2 97.9

Audited br. 

## & 6 Dua > >Y 7



# ~ QA

) 

## EPA iLlethod 1 Determination of Sampling Ports and Points

CGient feSr/: Ile A<', , 4. 4 City/State st'

~ sv-. / ~~ .~/C Sampling Location 0r*et - F

~ rL,y.,rst Date oS//!tf /9 7
Sampling Location Dimensions: From Far Wall to outside of Pott

Nipple Length Depth of Duct Width (Rectangular Duct) g fid
Equiralent Diameter Calcttlation (DE): : z Lensth s Width 2 (.411 DE= Length + R/idth ( Alt i- i(/lf )

Distance to Ports From Nearest FIow Disturbanca Upstreatn - A Downsueatn - B Dimensions in Inches • y Duct Diametets % 3• vy 

# ~ Stacic ,iirea, in Squar® Feet I f. . 75 Calculations By 'Tt-w DlSTURBaNCE 1—


### a
SAA/PLI,VC LOCaTlON r 

### i

I t r K 1 (

D/STtJRBa,vCE

Schemalic oj Samplirrg Location

## EPA 1Vlethod 2

Determination of Stack Gas Velocity, Volumetric Flow Rate and Cyclonic Flow
Client SfWfnv;l, ~-z Sampling I.ocation 

### 54.

~~ 

### -sr ~~r~ u Er/.. 4 . r' Run Date o5/lyIv

-r Barometric Pressure, in. Hg y0 Static Pressure, in. H Z O 

### -`, 1 1 D Static Pressure, in. Hg

- 

### o. 103 Stack Pressure, in. Hg 

### ZQ .`6 0 Stack Dimensions, in., diameter/side 1 

### Za•s City, State !le cOperators SLW ~ ,TD A T'itne /'S

- o 0 Pitot Tube I.D. No. 

### 207J. OZg Date Calibrated 

### o t ,) 31 R 7 Pitot Tube Coefficient 

### d ' Leak Check, in. H 2 0 <0.1 @ 

### 3.60 Side 2, in. 

### — Field Data

11 0 

# : ~ 

## A o
©~~~~~j~:i~~ • ®~~~~~®© •

~~~ ~~~~ 

# • • ~ ~~® •~~~ 

# •
. ~ , ©~ ~ • ~ ' ~tSi~~ ~ ~ ~



## ~®~~ ~~ 

# . , s

~~~~~~

# ■■ ~~~

Stack Temperature, Dry, ° F (A) Stack Temperature, Wet °F (B) 

### %

- A ~ Difference (A - B) 

### (aN Preliminary Percent Moisture / 0 . ~



## ~ 

# m

c y : 

# & nacG ~ 

### i 2a ~ 

### 1 B-3lFSY..S-r 16U.1 --

Date: 

### US / Zo / J '7 

### 'b `I ;) Zj 6- j i

~ 

### r? EPA Method 2 Determination of Stack Gas Velocity and Volumetric Flow Rate

Client Sampling Location P-x XGG-Sf Run Date CSAs 97 Pitot Tube I.D. No. '
~ bo. o'z 7 Date Calibrated 01103117 Stack Dimensions, in., diameter/side 1 a cf..5 ' 1 City, State Project Number 

### 0Rl61

- 17

- olz(o Operators 

### JLC-
~ Pitot Tube Coefficient, C P D. 8y Leak Check, in H : O <0.1 @ 3• o Side 2, in. .v.4-
Field Data

Run No./Sam le No. 

# 1 a 3 E 

# ° Time 24-Hour Clock) ov /2 '/o /A/6,-> Bar. Press..in. H¢ 9 ,8 • 79 $_'7 oL Static Press., H.O — — 4 /D Static Press., in. He - 0 , O y l - 0 . 0 9 ( - p , 0 5 - Q . ( 5 Stack Press., in. Hg (0 , Z1

- . 51 Zf, S Stack Tem ., Drv, v *-O

r - D 17. 5



### - & 1 X 1 117 Stack Tem ., Wet, Z.S (ZL.Q 17S Difference,'F (.+1O lt0 C? ( 3 Moisture. % 0 1 n • 5 1 1 . 4 i l . 11

Tiaversa Eoint' N'umt

~ er ,: Velodty

Head Op .:: Inches H U: Stack>'

Temperaturr >

~ £ °

G Vdocity : .:; IIeadAp: .: I'ndkes i

~ 0:> Stadc °

Temperature °I? Yeladty

`,:Head Ap Inches S.0 Stadc::

Tempeeatuee - 'S': .: velocity;::

Head Ap:: Inches IiGO: Stad[

. Temperature< '7$ 'Av 

### 36 I,Io 79 3 /.aa F:z ,3d 9(1 1,30 70 y / 60 88 /•Y ~ p.2 

## /,. ~ 

## 96 l.yo 7$ 

### .s /•6110 /~~5 EL /. 79 

## i -Go Sg /, G .3.3 

## R6

~ 

### . 9b 9-9 a. b o 3 ~ 

### F g ~ 

### .. ~ 

### 0

~ 

### B a,/S" R3 a.lo $( ~ `3.30

- 79
r i a, l l~ ~ 7 • ./:S + 0".3 a. vv F(0 0, / 0 7`7

92 . 96 83
~ 11 , ~ 50 96 / o8o

- 7 8

r. Jv S.;L l.ivo '7g

Averages I 

### os~ ~ 

### 7,s /o63 92,3 %.G3 ~G.~ l.~~ 

### 7x.3

I if.7


## r7 g TFZIGON I

## EPA Method 3- Molecular Weight Determination - Data Analysis

Client Name 

## lejv+l lt Q'n C

~ 

## — Project Number 

## 0 2 ( 1,'I 7' 0( f 1,19 Ciry/State ~S ✓
~~ 

## 11{- , nlC- Sample Date 

## & 47 Sampling Location
~ 

### GI

~ 

### T ~ 

## r4tv - EX.6, ,, +

, Operator 

## G-

~ 

## 3 Sample Type a Tedlar Bag o Multipoint BK Single Point Fuel Type wImcl Analyzer Type 

## Fvrite Serial # ~r~ C'• z ( z O-Oxygen Calibration Check Must Be 20.9 ± 0.1%
Run # and/or Sample ID Sampiing Time (24 - Hour C1ock) 

### ((Lo

Gas ' Re licate 1 Re iicate 2 Re iicate 3 Average: Percent Multiplier- Moiecular Weigbt Drp lb/lb mole> Actual ' Net - Actusi Net Actual Net' CO: 

### 032 - o N; . 100 

### ; y.O ` 100 '79. D:. 100 

### 79. U 7q, crn 0.28 Total 

## 2q, 3go

Run # and/or Sample ID 

## Z Sampling Time (24 - Hour Clock) 

## 13 0-0

Gas Re licate 1 Re Iicate 2` ' Re licate 3 Average> Percent Muitiplier Moiecular Rreiglit Dry lbllb mole Actual Net Actuai Net Actual Net 

### CO = 41,0 y. o L1 u 

### 4~ o 4. ° a il. O-D o:a4 1,700 °= I D l

~ 

### •D 7. 0 7. D ?. O 1?.0 1 ('T. cSD 032. 5. Nq D. N. 100 ?R.o ; 100 ?y.a

. 1W J 71.0 1 '79- 0 U 0Z8 Z

~ 

### 120 Total 24 . 3 20



### Run # and/or Sample ID 

### 3 Sampling T'ime (24 - Hour Clock) 

### 14 ZD

Gas- Re licate 1 Re licate 2 ReiDlicater3

I Average. Percent Multiplier Molecular Weigbt Drg IbJib moie: Actual I Net Actual Net Actual" Net C00. 3.0 3. 0 3. 0 3•a 3.a 3-r.) 3,Oa 0.44 ~ 3 Zo 

### °- iT.0 $,o !?,o lg,o lg,o 18.0 rd'.oZ) 0.32 5.?a J N, 100 ?q. 0 100 100> ': 14. 0 0" 0.28 Z2 ( Z. d Total

udited by: 

## .1DA — Date: 

### 5 - /I ~ 

### /11 MR 

# ~EPA Method 26 Determination of Hydrogen Chloride Emissions

ClientJ f w ~s

i / .~~~ Qr~c Run Number 1 City/State <{

~ .{:!

~ sv Ile Date osf/

~ s"/5 7 Sampling Location .~~~~ .sf c~~a~ CK~ .a.r Operators S/- 4,>

Amb. Temp., °F 

### 76 SET-UP DATA LEAK CHECKS Bar. Press., In. Hg. vZg , 7 9 Console Dry Gas Meter Coefficient Y= /. 0O Pre-Test D•fC ® /J_' In. Hg. Static Press., In. H 2 O ' (• (y Purge Time .S`,,.,;.. Purge Rate ' ~,~ << Post-Test y•/d @ /,-f'_ In. Hg.
a gb

~ .o28 Meter Box No. 1~ bb

~ bs

- 1> Stack Temp. 

### E

~ 

### ' 6' 19 O

~ Pitot Tube No. Pre-Test Pitot <0.1 @ 

### 3•' ) In. H Z O Sample Box No. Wet Bulb Temp 

### 1 Z t { O F Pitot Coeff. O.gSI Post-Test Pitot <0.1 @ 

### 3• 4

. ) In. H 2 O Pitot No. a op • nX6 % Moisture 

### 101 Orsat System ,fi4 Tedlar Bag No. _y4

~ Probe Temp. Setting 

### JAd Start Time 

### %/O6 End Time l2 OO Bag Leak Check _,t1_4 Sample ID No. 7C2/do — O/ Sample Container No. 

### 1 Level Marked 

### ✓ Observer i4oTlE

Sampie Rur► . : Time Iv1u{utes_ Clock

: : ..Time 24 Hour

. :.. Cloek. > Flow

.

Meter ' :.. Setang Liters/Minute Dry Gas

Meter Vol'ume: Titers : . Dry. Gas

Meter : Temperature S ° Ti ° G .,. ,. Pump

Vacuum Inclses H Stack

Temperature Y

~ ` C..

0 C[.,
5 10 

### ///U 2 15 

# :s °L a.S20 . 

### 2 y 25 30 113 0 

### 35 1 1 3L 40 // qU a ~ ~ /~ / °
45 50 55 60 87. 3 g 773 °F 189.3

- r Comments

?re +C.4 'C /- ,LS `+ o.s t h - .3t C' /b c"

~• ~ ~ ,'77 ' y, ,.77 

## 1 .y3 1.213

lya 

# • 5 `/ , . y 3 

## ( 

# 2 ) A ✓ e 1.97 I
-6 B 

### 'i-zet "~ c S Z ~ y 7 ~ 

### TF
~ 

### IGOf V'

, ~„~ ~. ~ 

### / /EPA Method 26 Determination of Hydrogen Chloride Emissions

Client Run Number a Ciry/State Date 63 '1 , 5A .7 Sampling Location Operators

Amb. Temp., °F 76 SET-UPDATA Bar. Press., In. Hg. a$ • 7 ~' Console Dry Gas Meter Coefficient Y= Static Press., In. H,.O 

### -/• /y Purge Time J

- i„ :., Purge Rate

~ Meter Boz No. SiDO -GS'O Stack Temp. 1

~ 3s ~ Pitot Tube No. 3~ w
. Sample Boz No.
~ d.. ~ Wet Bulb Temp lZs F Pitot CoePf. y , g`/ LEAK CFIECKS Pre-Test O. (j.A @ /-S In. Hg. Post-Test O.OS' ® /J' In. Hg. Pre-Test Pitot <0.1 @ 3 - y In. H : O Post-Test Pitot <0.1 ® 3-° In. H : O Pitot No. :)L aa . o a 8 % Moisture 

## 10 Orsat System Tedlar Bag No. ti4 ProbeTemp. Secting Q0 r~ Start Time / 2 YU End Time 1 3 yo Bag Leak Check /4-,4 Sample ID No. '7o44 - 0 2 Sample Container No. Z Level Marked ✓ Observer n1odNFamp S le Run Time .: Minutes :`: Cfock

Time 24 Hour Clack. Ffow.

Meter..

.. Setting : E iters/Ivlmute ,.

D Gas

. rY Meter .: Volume '`Lifers. D Gas

rY Meter , Temperature bf ~ Pum P. : ;.

Vacuum H¢ Inches Stack. ;

Temperature:

0 :d 

### yo 5 1.219T 10 I a S o 15 ;2bs' 20 l300 25 13ckS - 

### 2 .2y >`/o g ~ 30 13/0 85,
35 131.5 — .Z 7, ` I `I o e`'/
40 1 3.)v ~ a ~`!~~ ciS ' 45► 315

- 50 

### 1330 a`
55

~ 

## 3a3

~ 

## a 91,4 60

7,5' 1 '7 F /23.s ° ~

Cotnments

q ,5 S

~ 

# QA % •?

~ ' /•~5

e

### 26 ast tts+ 

## ~ u

/, 8S

B-7 

### A ,,,1,4 ef 8-f : Ti3AEPA Method 26 Determination of Hydrogen Chloride Emissions

Client e^"k Run Number 3 Ciry/State Date 04 - /iS/97 Sampling Location 6 ~ r.s"s+ Q~ rer - ~ ic%.,,.st' Operators JLC,J

Bar. Press., In. Hg. 29 .70 Static Press., In. H Z O

' / • 3-0 Meter Box No. Sample Box No. 1 Pitot No. 'loo. >Xg Probe Temp. Setting 1 o1c Sample ID No. 7066

~ 8 Console Dry Gas Meter Coeffici( Purge Time L~ •r+ •h Stack Temp. l?it lAV P Wet Bulb Temp % Moisture Start Time Sample Container No. 3 v Y - /- d0 Purge Rate Pitot Tube No. 'A&o•o%8 Pitot Coeff. 0

- 04 Orsat System --f--4 End Time /J'b y Level Marked ", LEAK CHECKS

~ ''3..3 Pre-Test a" /o

@ In. Hg. Post-Test O.io (a 13. 3 In. Hg. Pre-Test Pitot <0.1 ® - 3' ° In. H 2 0 Post-Test Pitot <0.1 Q 30 In. H Z O Tedlar Bag No. 141-4 Bag Leak Check /!iA Observer 1%fbWCAmb. Temp., °F --) 6 SET-UP DATA

Sample Run Ttme ':

~ Iinures Clock

Time 24 Hour : Clock -

Flow Meter

. Settittg Litecs/Minute. Dry Gas

.

Meter; . Volume .:. : Liters ` Dry Gas :>

Meter Te;nperature . 'F r Stack Temperattue



### o 5 

### l y b ~ ~ ~ ~/ /- 4 40 S~ 10 

### N/o a 15 1W/ ' 

### E3 20 

### I4;0
~ 

### , 2 s' /y. v ? eZ 

### 25 iy

~ 

### s'

~ 

### ''a 30 / 4

3E' a =Z q 35 /`/35 — 

### 2 215 40 /yyo 45 1y5c5' q 1s~ /~ /. 0 7 r 50 

## 1 y5a ~ 

## i 2.s

~ / L/ . o 

## -? g
55 ~ /. t7 72 60 lS6° — ~ ~/ .O 72? )l`/°G1 76 , 3 or / 7 F. 9

~

Cotnments



## /,

~ 

## y .~ 

## 3

~ 

### , s 3 ,~~

Q ~ ),Y i

.~; 

# Q A I, i3 7 

### 1.3 3 B-8 I I ~

4...8 1._f O 'r.r nr/—l—

### EPA Method 26A - Moisture Determinat 'on and Sample Reeovery - Data Analysis

Client Name 

### ST~~SVt ( I Q J3r , C 

### ~ ProjectNumber 0 7 16 - Q'J- O(c
~ F Ciry/State A1C Sample Date 

### z //J /qi' Sampling Location 

### S44Jd DryW Samples Recovered By 

### G-1-13 Clean-Up Box Number

. 1.10 Recovery Date 0 9I51R7 Chain of Custody: Date Received Received By Locked? 

### ~ 

### Equipment Documentation
Run Number l Z 3 Sam le ID Number bto - 01 70tz(j- OZ- 70C.1a - 03 Sam le Box Number I Z Probe Number ✓

~ — 

### Analysis of Moisture Recovery ReaRent Recovery Container # '701oi, -0I ?04(o -02 - ?666

- 03 Im in2er Absorbiniz Solution 0, 1 N NZSJ q 0. 1 /'J + L _5 0zi 0. N 14ti9 0 4 Descri tion of Rea¢ent c4Zcw G4eufReaLyent Level lVlarked? ✓ ✓ Final Volume, ml 2, ~ 3g.4 2*-3 - 39•3 2*t

— o 31.14 Initial Volume, ml 43 30

- htFl 30 -44

~ _ 30 Net Condensed Volume. ml 9. 1 0 4•3 q.lo

_. .... . Reaizent Recoverv Container # 70t0(0 - 0 0~ -DZ 1 7012io -0 Im in er Absorbina Solutiou 0. N NaO R 0.1 nj nJa.q tt 0. {/V voOH Descri tion of Reasent c,(ear zar CA lay , Reaeent Level Marked? ✓

- ~ ✓ Final Volume. ml (S, 2 l Initial Volume. ml I 5 1 S I S Net Condensed Volume. ml 0, 2

~ .2 0,1 Silica Gel Recovery Container # ZOlz(. - ol atil, - OZ G - 03 Percent Silica Gel S eut ys L) 50 Final Weisht,Q 20.7 7,0•8 Zo.$ Initial WeisEht. o ZD Zo ZD Net Absorbed Water. e 0.7 0. a 0. g Total Reavent Collected, v 10,3 0.5 

### Sample Recovery
Recoverv Container # 70(z6

- 0 70u10-OL 7owb-03 Rinsins Solution

- Js w,&w Ds V40.4z, pI ak , / Sam le Container Sealed'? / ✓ ✓ Li uid Level Marked? ✓ ` ~ ~ 

### Reagent Blanks Absorbinv ReaQent Blank N/ 1l ,5 , 4 1 Rinsina Reaitent Blank Dz Kzo Absorbino Blank Identification # 70 ~ '- o 7 Rinsing Blank Identification # ~ Absorbino Rea ent Blank / 9 , Rinsing Reaoent Blank NA Absorbino Blank Ideutiflcation # i,/A Rinsing Blank Identification # ,v,S

,,. ~ _............_ . , .,,., • _ ............. 

# ay 

# ~ 11 Reviewer lnitials ~ ~~ ✓ ~` 

### V. 

# QA B-953 'r

~ 

### r K

Sckematic of Sampliag Location

,Wdtbd bye

..

~ LJ

Datm oS /.2 Cl 97

Q 

### 4 ~ Q 

## EPA iLlethod 1 Determination of Sampling Ports and Points
Qient 

### 34a7 ~ S~~ 1~ 

### e IJrI Ck C'ity/State 

### 964? SY ,- 

## I l t, N C Sampling I.ocation 

## E

- " hav , .St 

## a~ 1 ck Date 

## Q5l IyT,? r I i Sampling I.ocation Dimensions: , i From Far Wa11 to Outside of Port S 5

Nipple L,ength ~ • ~ ~ Depth of Duct 

## .3 7. Width (Rectangular Duct) 

## z Equivaient Diameter Calculation (DE): 2 z Leo;th x Rlidth 2( y j. S)( 3W 

## DE =

_

tAn g Lh + Wiarh (37,5 + 3$
Distance to Ports From Nearest Flow Disturbance: Upstream - A Downstream - B Dimensions ia lnches --z 1 0

~ - r _ 33 J 

### ZY D 1! Duct Diameters '"' •

. ~ 

### 3 (e Stack Area, in Square Feet


### . q q-0 Calculations By 

### JDti ) 

### = 

## 37. 7s

. I • e I o

; ,< ~ • s 3 t

! •oa

e t 1 4711 34 1 ~ 1 

# diiii ~ ::.

. At oC.: _ Stadc D TataaQtbos " Tnardd:Wali 2rfQpre ;;>

Length scsaoe

~ oo: :.

Di :F :.,OuuideuEPort• 

### 10, 0 I 37-.5 3.75 o f1.7S I 

### Z 3 t7 . O 3q. S 

### t I, 25 ~ ~ A 

### 3 s0.0 3?.S 1r-7J Ka z,c,.?s 1 ?o. a 3'7.5 Z6 ZS 't 0 3H. ZS 

### S to•J 375 33. ?S g. ~ 

### 1•7S

I

. - 9 -
~ • I

,. a t ,i.o a , I L: 7 S7 ~ • 0 a T '7. , "T n, ann at11 ta.9 is.o 71.a _'9



# I

V - 

### B-10 TF~

## EPA Method 2

Determination of Stack Gas Yelocity, Yolumetric Flow Rate and Cyclonic Flow

Client `J/ 

### ~~ 'SV! 

### ~ ~ 13tric 

### ~ 2 Sampling Location K~ 

### 1— F

~ 

### rHc

~ 

### c1' Sf~~ lc Run Date _ 0~1N(l7 Barometric Pressure, in. Hg Zf.q D Static Pressure, ,in. H : O 0 k% Static Pressure, in. Hg – O. 00 ( l Stack Pressure, in. Hg 28,40 Stack Dimensions, in., diameter/side 1 3 7 i City, State I II t, , Jl/c , Operatots TbA

~ j'L LJ Tune jCn 15 Pitot Tu be I.D. No. 2

~ q . d y L1' Date Calibrated

_ 0 ( I

/ o`;jR 7 Pitot Tube Coefficient 0. g4 Leak Check, in. H2O <0.1 @ 4•0 Side 2, in. 

### 3 ? .0 Field Data

• Cvdo t

~



## ©~-~ 

# ---- ©

~-~ 

# _--- ®

~-~ 

# ---- ®®-

~ 

# ----

© , . ~ 

# . . . • ~~~~

Stack Temperature, Dry, °F (A) 

## Sr3 Stack Temperature, Wet °F (B) 

## 14 Lj DitYerence (A - B) 

## 30 c l Prel'uninary Percent Moisture f o

by: 7Llti Datec Us %2O/ (j7 B-il qlE'PA dtethod 2 Determination of Stack Gas Velocity and Volumetric Ffow Rate

~ ~ ~~ 

### 3f7 G Client ~'~ SVI Sampling Location 

### KAn. Fxhaw5l l ' fC. Run Date 

### 4l5l4'7 Pitot Tube I.D. No. 

### Z

~ 

### D• "q Date Calibrated 

### 0(1 0 3 /

~ 

### 17 Stack Dimensions. in., diameter,'side 1 

### 32. 5 City, State 

### 'sCt'SV: 1 [A

-- ~ 

### , Nc. Project Yumber 

### 0 to-q '7- oz.? la Operatots 

### JDA Pitot Tube Coefficient, C. 

### O.Ftl L.eak Check, in H.O <0.1 @ 

### L Side 2 

### , in. 

## .39

Field Data

Run No.iSamvle No. Z. .3 Cnd v 

### ~ -3 Time 24-Hour Clock) IZq () 14DD )507) Bar. Press.. in. He 2-f•78 Z8.7Z LY.`i a ZS.Za Static Press.. H.O -(

~ . .^. I0 - 0. ODS - D. 6DS - 0, 01 O Static Press.. in. H2 - 0. a
- Z)on

- w) L 0. 6000 - Q. 66b P T Stack Press.. in. H¢ Z$.7 Z$.7Zi u ?-$.70 Stack Tem .. Drv, °F q -5-

~ $ 57,2 5 2% S ZD Stack Temo.. Wet. °F 143 lyi 

# j Ms lqq 

### Difference. °F 35q 371 363 37 ( ,P 

### Moisture. % . t 1 7• t $• Z 1•

~ 

### (

~ 

### Field Data c_J 1 7 411 J
Travetx: Point .. Number :: VelodtT

Head Op:, Inches ILO Stadt

Temperatura
° F Velodtp .

:. Heud'zip - Inches 1i.0 Stad6:.

..

Temperature °E Velodty

Head ip Inches ILO Stadc::

Temperature
° F' Veiodt7!

Head Ap Inches Ii3O Stadt:

Tempernture: : ° F AI 8 1.OIS o.W t > 4J8S qff'd 0.035 o.oy5 518 530 0.03 C o.ayu SZZ j 523 o.' 0 o.o ~ S 52 , 5 1 5z3 Z Z O.OqC 0.035 

### ySS 0.035 1 0.04 0 5Z2 53 a 0. 0 30 0.035 5 1 4 

# 1 5 Zy O.oSb p,ot{v 5Z4 52 , 2 3 3 0.035 0.035 qlt o qlQ o.ot5 I o.o3o Szs 531 o,t,z5 0.030 57,to Szl 0. 0 5a0.035 5z.0 52 2 

### 0.030 6.045 4a d 

### 53 0 ~ 

### 532, o-oTD1 o. OLIS 52,9 SLZ 

### 0.030 o.045 22) 5 S o.030 o.uuo 

### HS 

## 8 q YQ 

### o.cZ o.0

~ 

### 1 530 53z. 

### O.ozo o.o 

### 4 5z? 5Z2 O.o2S 

### o.oy5 

### E -I Z- SZI 

### ( 0 ID I o,dtu 0,050 yY4 qql 0.00 0 

### o.cr,o 532- 533 oatss 

### SzA 1 533 O.otA o,oso SZI 5ZI 

### 2 1 L 10.06C 0.03SI Lifq 1410 0.050 O-OfOl 533 53 Z o.oSo 

### ,035 5L2 1 53Z, o.o5a b•o3U 5Z( Sz,o 3 3 0.035 0.03 0 419 qq3 a.a.5 o. o; b 5 33 530 o.o2 0. DZS 524o 531 0.021) 0. 02.5 SLb S Lo 4 o.oioo-aa 4 tq 4qS 0.015 0.035 531t 531 0.01 o.a3S 5 Sqb o,oibo.oq5 521I5Z! 5 S 

### o.o(o v.ot,S qqZ-14q5 0,o2 

### 0.00 535 53e 53( 5q1 

### 0.015 O.oyS

~ 

### o•oZS gEo 5L$ 0.03 0 s 3 0.0 1 40 .SLo Z o.0 S 

### 2 o. Dit 5 SZot o. o , 1S 5 NZ o. oH D SZf 3 0.0 S g lo 0•050 I M 0. 0 5 0 5 Z O.o.SD 520

~ O.stlo 411 o.uuo 

### 530 o.o4o 

### SuZ 0,050 52,0 5 0,02; 50V o.OZ5 53D o.o2 0 

### 540 0.035 5(9

, Y"es. 

### 0.038 1 

### 4?q.4 L2. 031t 

### 530• D 0• 03 ~ I 530•b 

### 0, 031 SZf. 4
p. S ments I 4 Q~► , ~ ~~ 3~ - G~ , c~a~ d bY ~„~ d o.,
~ cl.r
~ ' -

v ~ .~.r~ A ited br. a7L LJ Date: o ,

~ -/ a o/ 97 o

- r ~ O~ CL ~ JF: 0

- 5/ZL q '

- t ' ~

## EPA iVethod 3- Molecular Weight Determination - Data Analysis

Client Name 

## I'd

2 villp— Project Number 

### Otllv - 4? 

## - ULz 6 Ciry/State V, J A/ Sample Date oS JS 4'l Sampling Location Kir+_ 

## &6w5f SfaGk Operator EC ~ Sample Type o Tedlar Bag o Multipoint 2"'Single Point Fuel Type 

## w3ud Analyzer Type 

## Fvrite Serial # 

## -' o,9- , L 1 7 - ebzygen Calibration Check Must Be 20.9 t 0.1%

Run # and/or Sample ID 

## I Sampling Time (24 - Hour Clock) 

## 0 3 D

Gas: ' Re licate 1 Re licate 2" Re licate 3 Average: Percent Multiplier: : Molecular Weight Dey lbflb mole. Actual Net: Actual Net Actual: Net 

### co:; .5 S

~ 

### 1. 5 ,S U, S q. S Sd o:aa I. 4rD 1lrS f4,5 0 032 5.28 0 N:., 100 4 ~ 100 '79: U 100 ?S.0

~ g, 6t ~ 028 Z2 .12u T 

### o t a l 7-R.380

Run # and/or Sample ID 

## Z SampGng Time (24 - Hour Clock) 

## 1315

Gas- Re licate t Re licate 2 Re iicate 3 Average: Percent ' Miiltiplier : MolecularWeight. Dry Ib/1b mole Actual Net Actual Net ActuaP Net Co z :. 5.0 5, ~ ~ D S.o S a 5,0 S. 0 - 0 0:44 2.200 °s l co. 0 ( l.. 0 ( h. D (1a . o JU. 0 11-. 0 ( to .U
- Z; , 032. 5. Z a. 

### N: : ioo 7y. ~ 

### loo ?a. o` ioo: 74. o?9. o - J 0.28 Zz, f 20 Total 

### 2-Ci.4 d0

Run # and/or Sample ID 

## 3 Sampling Time (24 - Hour Clock) 

## /I y 0

Gas: Re licate 1 Re licate 2 Re licate 3 Average Percent Multiplier Molecular Weight: Dry* lb/ib mole Actuaf Net Actual Net ActuaF 

# I' Net C°= 3.5 3.5 

## 3.r 35 3.S 3.S 3.So 0 

### • 44 I.S4u °=:: i 1. S i 7. S 17. S f Z. s 17,5 r 7. .S 17. s o 032 N: : 100 ?4,n 1 oo ?9. 0 100_ 71. 6 ?9. 0:8 22, I ZU



# F

_ Total 2q.

Date: a° / 9 ~ 

# wi

~ B-13 ( 

# 9 ~

by:

~ 14 

### JOrsat System 

### /'tA Tedlar Bag No. /VA End Time 1'?' ~ . Bag Leak Check 

### /11)4 Level Marked 

### ',/ Observer 

### /V' W6 EPA Method 26 Determination of Hydrogen Chloride Emissions

Client _-Stin ~ 

## iI{

- "



## Rr

~ 

## (

- .J'L. Run Number Ciry/State 

## 6jz&SJJ I ( t- , lV C... Date Sampling Location 

## _k

/ :I r E" 6„r

~ 

### S "

~ 

### rccr v Operators 

### ,TfiJFi

Amb. Temp., °F 

## 15 SET-UPDATA

~ 'Z~ ~ ° Bar. Press., In. Hg. ~~- Console Dry Gas Meter Coefficient Y= Static Press., In. H 2 0 — 0 Purge Time •S m; rt. Purge Rate s tc. ktj Meter Boz No. q0

- 9 , 03 D Stack Temp. 

### 513 Pitot Tube No. 

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Meter Seiting .:: . Liters/Minute.: Dry Gas

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Sample. Run Tune " Minuces Ciock

Time 24 Hour Cloek Flow

Meter Setting Liters%Minnte Dry Gas

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Vacuum Fnches H Stack.

Temperature °F



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# QA► I•
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# 9~

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~ L Client Name 

### ` d XGRt ~ SV 

### I ~ 

### lle- ~ ✓



### U( City/State 

### sf S ✓ ; ~ 

### 1l- . N

~ - Sampling Location ~ 

### i l 1. achau

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. 

### 1?1& Chain of Custody: Date Received 

### Ination and Sample Recovery - Data Analysis

_ Project Number 

### 0
- Y (.

- q ~ ' Ote la

Sample Date 

### ()5115

. 10

_ Samples Recovered By 

### L
~ 

### f3

_ Recovery Date 

### OS 1 97

_ Received By Locked? 

### Equipment Documentation
Run Number 1 

### Z 3 Sam le ID Number '701z(D- 0 ?0(zU

- OS 701w1a-0' Sam le Box Number 1 Z ~ Probe Number 

### Analysis of Nloisture Recovery
Reaeent Recoverv Container # 

### 701.e

- 0 4 7bUu -oS 0t?d0 -0(0 Im inoer Absorbina Solution 0. nj NZSOu 0.1 N Hzsoq v.l n/ 14:..SOy Descri tion of Rea ent 4 4,w Oe.cw r.(uar ReaQent Level Marked'? ✓ 35.1 3 .'1 if•t , Final Volume. ml ' a ;Z
~ =1' Z-OT#

- tt1'*--Ztr Initial Volume, ml -4i--5- 'Is~ ~ ~~ Net Condensed Volume, ml

_ ... . . 5.7 30 '

. . . . ..... . 5, ~ S.lo

_ ... . . _ ... Rea:ent Recoverv Contaiiier # ?OLiLe

- Ot{ 1 7046

- 0$ '706O

- DU Im in er AbsorbinQ Solution 0.► N n/a014 o,J aDl{ 0.1W Nab 4 Descri tion of Rea ent G(tc

~ ✓ U+w ✓ ~~ Rea_ent Level Marked? ✓ ` ~ ~ Final Volume. ml I5 l 15 15.3 Initial Volume. ml f S.o 15. 0 

### 15. v Net Condensed Volume. ml 0.0 0.3 Silica Gel Recoverv Container # 7a , 6(a - OtF. ?Ctzlo - OS ?010l0-0tr Percent Silica Gel S ent 10 (o p Final Wei¢ht. o Z(. Z 21.1 Z 1. 0 Initial Weioht, o ZO Z O 2,0 Net Absorbed Water, o t. Z 1 - 0 Total ReaQent Collected, g 7.0 

### 4.5 (0.1 

### Sample Recovery
Reeoverv Container # tlta - 6N 7 auke - OS 1 042U -0 Rinsing Solution DS W:

~ ;Ec4_

-

DX i,./o:Ew t7S WukXV 1 Sam le Container Sealed? ✓ ' ~ ✓ Li uid Level Marked'? ✓ ✓ ✓ 

### Reagent Blanks
II Absorbins Reasent Blank I©./1/ 11,SDf_ - I Rinsins ReaQent Blank I DL 14z0 1 Absorbino Blank Identification # A - 07 Rinsing Blank Identification # — Absorbina Reazent Blank N/+ Rinsing , Rea ent Blank rJA Absorbin¢ Blank Identification # NA RinsinQ Blank Identification # NA


# r•
. . B-17 

# y~ ~

### APPENDIX C

LABORATORY DATA

~ 

## .i 98

# Trigon Engineering Consultants, Inc. Statesville Brick (046-97-066)



# Analytical Report (0597-26)



# EPA Method 26 Hydrogen Fluoride



# .~ .~~ Enthalpy Analytical, Inc.

3211 Bramer Drive Raleigh, NC 27604 919/850-4392


# C_ % ~

# Summary of Results

.~ ! ENTHALI'Y analytical , inc. C-3 

# mCompany: Tri on/Statesville Brick Clien[.#: 046-97-066 Analpsts BGH Entlialpy #i: 0597-26 Parameu:rir H dro en Fluoride PO:#i AM7559 #S les: 7 R ortDate: 05/14/97 

# I

- Compound Sample ID & Catch Weiglit (mg)

7066-01 7066-02 7066-03 7066-04 7066-05 7066-06
Hydrogen Fluoride 2.08 2.73 2.95 7.21 8.16 12.7

~ .



# ~ ~ ~+a~"~

~~ 

### ENTHALPY analytical, inc. D:UOBS97U05%0597-26\0597-26.WB2 17:02 06/04 f (/ /

# Results

~ ! 

### ENTHALf'Y analytical, inc. C-S 

### mo- I4 -

r

~ 

## 3

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N
~~

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### C-6


# ~~ ~

# Narrative Summary



# Y

ENTHALPY anaiyticai, inc. C_7 

# /! ~

# Enthalpy Analytical Narrative Summary

...

.. . 

### ..

. 

### .......... .................. 

### Trigon/Statesville Brick

.... . 

### ..

.. 

### .. 046-97-066 P.04- AM7559 

### 0';YV;#::.:

..... ........ ... ...... ... . 0597-26 W 

### BGH HF Custody Samples were received on 5/20/97 by, 

### Scott Grosshandler after being

relinquished by 

### Paul Jenkins of Trigon. Sainples were cold upon arrival and kept cold during storage. Prior to and during analysis they were kept under lock with access only to authorized personnel of Enthalpy Analytical, Inc. Analysis The samples were analyzed for hydrogen fluoride according to the procedures

outlined in the EPA 

### Method 26. 

### Quantitation was perfor

- ined a Hewlett Packard series 1100 

### High Performance Liquid Chromatograph. Detection occurred by 

### indirect UV 

### at 260 

### rum. Separation was accomplished by 

### a Hamilton PRP-XIOO 150 

### mm x 4.1 nun anion exchange column using 2 niM sodium benzoate pH6.4 

### as the eluent at 2.0 mL per minute. A 

### four point calbration curve was nm before and after the samples. Data from all calibration nin were used for the cali 'bration curve. The linearity coefficient of the curve was 0.9999


### Labeling OK Reproducibility OK Quality of Data OK Reporting Notes MDL Nfinimum Detection Linlit.

LOQ 

### Limit of Quantitation.

pp- Ok 

# )0401

~ 

### ENTHALPY analytical, inc. C-8

# Sample Custody



# Y )0 4 1 ENTHALf'Y analytical, inc. C-9 I~ •

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# Sample

Chromatograms



# Y

ENTHALPY anaiyticai, inc. C_li 

# /, ~ 

# S'

### Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\012-0801.D Sample Name: 7066-0 11 *

--------------------------------- 

### Injection Date : 03-Jun-97, 14:16:46 Seq. Line 8 Sample Name : 7066-01 *6 Vial : 12

~ 

### -. Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

~ VWD1 A, Wavelength=260 nm (0597-26A1012-0801.D)

mAU io - ~

80
I
- I i

~

; c a~ - rn 0 40 - -C a

- ' o cn

_ o 20 Area: 340.852 - , ~~

' \ co N

0

0 1 2 3 4 mi

---------------- 

### External Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 

### Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1

-- 1

--------------- --- 3.030 MM 340.85193 1.27263e-2 4.33780 Hydrogen fluoride Totals : 4.33780
*** End of Report ***

Groucho 6/3/97 10:13:15 PM BGH C-i2 Page 1 of =



## ~~ ~

### Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\012-0802.D Sample Name: 7066-01 *E

Injection Date : 03-Jun-97, 14:24:43 Seq. Line : 8 Sample Name : 7066-01 *6 Vial : 12 — Acq. Operator : BGH Inj : 2 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A1012-0802.D) mAU i
~ I io i I i

i I


### - ! I
80

~
60 , ~
i Q 7

~ C ~

~ O

~ 2

O O cn Area: 323.518

rn

00 rn

0 1 2 3 4 min



### External Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reAorted Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- ------------------ 3.006 MM 323.51764 1.27263e-2 4.11720 Hydrogen fluoride Totals 4.11720


### *** End of Report ***

roucho 6/3/97 10:13:47 PM BGH C-13 Page 1 of 1



## ~~~

### Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\013-0901.D Sample Name: 7066-0,2 x

Injection Date : 03-Jun-97, 14:32:50 Seq. Line : 9 Sample Name : 7066-02 *6 Vial : 13 i

- . Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

### Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A\013-0901.D) mAU -{ r i i
1
80 ;

~
~ ~ 60

40 =

_ ~ 0
~ ~

~ Area: 381.46

corlC9 ~

4


### External Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

# -------- I ----

- 

# -- I ---------- I ---------- I ---------- 1--1------------------ 2.990 MM . 381.46008 1.27263e-2 4.85459 Hydrogen fluoride Totals : 4.85459


### *** End of Report ***

Groucho 6/3/97 10:14:19 PM BGH C-14 Page 1 of 

# l/!

### nata Fi.le F:\HPCHEM\2\DATA\1997DATA\0597-26A\013-1001.D Sample Name: 7066-02 =6

Injection Date : 03-Jun-97, 14:41:01 Seq. Line : 10 Sample Name : 7066-02 *6 Vial : 13 Acq. Operator : BGH Inj : 1 Secruence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_LONG.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M .Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A\01 3-1 001.D) mAU io !

- i

- ~ 80

~ i I i I d 60 -- ~ . o

~ c

~ ' c

, m rn

_ o a 40 — S

~
~ C4 Area: 378.168 20 -

a~ o 0= •i

_

1 2 3 4


### External Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU * s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1--1--------------

--- - 2.967 MM 378.16846 1.27263e-2 4.81270 Hydrogen fluoride Totals 4.81270

---------------------------------------------------- -------- 

### *** End of Report ***

C-15 

### =roucho 6/3/97 10:14:58 PM BGH Page 1 ql min

### Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\014-1101.D Sample Name: 706

- 6-C3'*c'

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### Injection Date : 03-Jun-97, 15:24:04 Seq. Line Sample Name : 7066-03 *6 Vial

-- Acq. Operator : BGH Inj Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 : 11 : 14 : 1

column VW01 A, Wavelength=260 nm (0597-26A\014-1101.0) mAU f° Lo I

~ o ~

~ 

# • _ 80 i
~

~ I I

7 j CL)
60
I CD

, a 40 

# ^ y

v 0 ! nArea: 447.632

20 -

- Q ri 0

0 1 2 3 4 

# --------------------------------------------------------------------- External Standard Report

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1--1------------

----- - 3.044 MM . 447.63184 1.27263e-2 5.69672 Hydrogen fluoride Totals : 5.69672

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### *** End of Report ***

C '=roucho 6/ 3/ 9 7 10 : 15 : 31 PM BGH -16 page /~ ~

### Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\014-1102.D Sample Name: 7066-03 *~

------------------------ 

### Injection Date : 03-Jun-97, 15:32:00 Seq. Line 11 Sample Name : 7066-03 *6 vial : 14

~ 

### Acq. Operator : BGH Inj : 2 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A\0141102.0) mAU IU') i

- n i

- i

. I 80 - i I

- j
60 - i d
~ o
2 40 - c

- I N O

. ~ Area: 450.747 20 -



### o0 1 2 3 4 mir.

--------------- 

### External Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 3.024 MM 450.74686 1.27263e-2 5.73636 Hydrogen fluoride Totals : 5.73636

--------------------------------------------------



### *** End of Report ***

'=oucho 6/3/97 10:16:02 PM BGH C-17 Page l of _



### ~~

### Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\008-1201.D Sample Name: 7066-04.*2E

---- -------------------- 

### Injection Date : 03-Jun-97, 15:39:55 Seq. Line 12 Sample Name : 7066-04 *26 Vial : 8 -- Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A1008-1201.D) mAU 

## , , ' I° , n ' 

## j 

# o

I

I 80 - I j ~

1 i j ; 60 i I I i

~ _ d

i j c m 40— I ~ 0

~ I i 2

~ ~ 207 `

. \ Area: 296.041

o 0—

0 1 2 3 4



### External Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm R

- esults obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

### 2.996 MM 296.04080 1.27263e-2 3.76752 Hydrogen fluoride Totals : 3.76752

----------- 

### *** End of Report ***

Groucho 6/3/97 10:16:34 PM BGH C-18 Page 1 of ~ 

# /l~

### Data F
~ 

### 1e F:\HPCHEM\2\DATA\1997DATA\0597-26A\008-1301.D Sample Name: 7066-04 *26

Injection Date : 03-Jun-97, 15:48:02 Seq. Line : 13 Sample Name : 7066-04 *26 Vial : 8 ^ Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_LONG.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analvsis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26AW08 1301.D) mAU

~ n i

i

- I

_ I I 80 

## I I

~ 60 = CD

, 'o



### i , o 2 

## ~ d ~ 0 ~ ~

_ 0

~ i



### ~ Area: 300.673

° c~

3 4

--------------------------------------------------------------------- 

### External Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multinlier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Si.gnal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1
-- 1 ------------------ 2.990 MM . 300.67261 1.27263e-2 3.82646 Hydrogen fluoride Totals : 3.82646

----------------------------------------------------------------_----- --------------------------------------------------------------------- 

### *** End of Report ***

C-19 

### Groucho 6/3/97 10:17:06 PM BGH Page 1 / o; 1

### Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\009-1401.D Sample Name: 706.6-05•*2

------------------------- 

### Injection Date : 03-Jun-97, 16:31:10 Seq. Line 14 Sample Name : 7066-05 *26 Vial : 9

~ 

### Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A\009-1401.D) mAU I I° i o i

80 ' 

### ' ' ;


### I 

## a I

60

- i L I O 7

-

~ C v 40 , O

O 20 —, `\ j

~ Area: 298.803

0 ~ r~i

0 1 2 3 4



### External Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks

. not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU * s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 3.040 MM 298.80316 1.27263e-2 3.80267 Hydrogen fluoride Totals : 3.80267
*** End of Report ***

Groucho 6/3/97 10:17:36 PM BGH C-20 Page 1 o _ 

## //

### nata Fi.1e F:\HPCHEM\2\DATA\1997DATA\0597-26A\009-1402.D Sample Name: 7066-05 *26

-------------------------------- 

### Injection Date : 03-Jun-97, 16:39:16 Seq. Line 14 Sample Name : 7066-05 *26 Vial : 9 Acq. Operator : BGH Inj ; 2 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A\009-1402.0) mAU

U,

~ 80

1 ~
i 60 , I i

i Gl

~ O

, C d 40 — O S

- I ! ch M O 20 nArea: 302.895 \
I \ % N Q) 0

0 1

_ 2 3 4

----------- 

### External Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! 1997 10:05:30 PM'



### RetTime Type Area Amt/Area Amount [min] mAU *s [ug/mL]

------- I ------ I ---------- I ---------- I ---------- 

### 3.033 MM 302.89542 1.27263e-2 3.85475 

### Grp Name

-- 

### ~
------------------ 

### Hydrogen fluoride Totals 3.85475


### *** End of Report ***

roucho 6/ 3/ 9 7 10 : 18 : 0 7 PM BGH C-21 Page 1 p 

# ~ l

### Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\010-1501.D Sample Name: 7066-06•*2;

Injection Date : 03-Jun-97, 16:47:20 Seq. Line : 15 Sample Name : 7066-06 *26 Vial : 10 Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A\01 0-1 501.D) mAU m ~ i - io

80

I

. { w ? 60 — — 

# c

~

, >

, 2 40 —. ~ m - o r Area: 475.059
20-

0

2 3 4 mir


### External'Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks

. not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

# ------- I --- ---1 ---------- I ---------- I ---------- 1
-- 1 ------------------ 3.039 MM . 475.05911 1.27263e-2 6.04577 Hydrogen fluoride Totals : 6.04577



### *** End of Renort ***

Groucho 6/ 3/ 9 7 10 : 18 : 3 7 PM BGH C-22 Page 1 p 

# ~ 1

### nata File F:\HPCHEM\2\DATA\1997DATA\0597-26A\010-1601.D Sample Name: 7066-06 *2E

Injection Date : 03-Jun-97, 16:55:34 Seq. Line : 16 Sample Name : 7066-06 *26 vial : 10 Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_LONG.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A\01 0-1 601.D) mAU iu

~ i ; 

# I 0 a i 

### ~

80 = ' I i

- i o
60 -
~

_ ~ o

~ a

r w^ - N O nArea: 472.148

- ~ 20 -

0=

0 1 2 3



### External Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1--1------------ ------ 3.032 MM . 472.14780 1.27263e-2 6.00872 Hydrogen fluoride Totals : 6.00872

-----------------------------------------------------------------_---- --------------------------------------------------------------------- 

### *** End of Report ***

3roucho 6/3/97 10:19:08 PM BGH C

- ~ 

### Page 1Q

~ 

### ,1

### Data File F:\HPCHEM\2\DATA\199 ;DATA\0597-26A\011-1701.D Sample Name:.7066-0 7

Injection Date : 03-Jun-97, 17:38:48 Seq. Line : 17 Sample Name : 7066-07 Vial : 11 Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VW01 A, Wavelength=260 nm (0597-26A\011-1701.0) j mAU 

# ; ! ci

i

80 i

~ i i ' I 60 ~
~ ~ I

rn Q 

# e 4


### External Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 3.137 - - - Hydrogen fluoride Totals 1 Warnings or Errors : Warning : Calibrated compound(s) not found

Groucho 6/3/97 10:19:40 PM BGH C -24 Page 1 )



# ~ /

### Da

~ 

### ta File F:\HPCHEM\2\DATA\1997DATA\0597-26A\011-1702.D Sample Name: 7066-C

- ,

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### Injection Date : 03-Jun-97, 17:46:53 Secq. Line : 17 Sample Name : 7066-07 vial : 11

~ 

### . Acq. Operator : BGH Inj : 2 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M .Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0587-26A\011-1702.D) mA U I °' !

80 ~

60 i

y f

i 40 —

i

~ I
20 —

.. . Q N ' O f r 0 

# °-

~
0 1 2 3 4 mir,

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### External Standard Report

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution

. 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [rnin] mAU *s [ug/mL] 

# ------- I ------ I ---------- I ---------- ---------- 1
-- 1 ------------------ 3.137 - - - Hydrogen fluoride Totals : 0.00000 1 Warnings or Errors : Warning : Calibrated compound(s) not found
C-25 

### Groucho 6/3/97 10:20:16 PM BGH Page 1 Qf 

# ~ 2

# Curve(s)/QA Point(s)

Chromatograms



# .~ .~ ! ENTHALPY analytica , inc. C-26 

# 4~ 3

### Method.F:\HPCHEM\2\METHODS\0597-26A.M

- --------- 

### Calibration Table

Ca1ib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Calculate External Standard Based on Peak Area Rel. Reference Window : Abs. Reference Window : 

### Rel. Non-ref. Window Abs. Non-ref. Window Uncalibrated Peaks Partial Calibration Correct A11 Ret. Times: Curve Type Oria- n 

### Weight Recalibration Settings: Average Response Average Retention Time: 15.000 % 

### 0:000 min 15.000 a 

### 0.000 min not reported Yes, identified peaks are recalibrated No, only for identified peaks Linear Forced Equal
Average all calibrations Floating Average New 75 Calibration Report Options : Printout of recalibrations within a secruence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with.bracketing: Results of first cvcle (ending previous bracket) Signal 1: VWD1 A, Wavelength=260 nm RetTime Lvl Amount Area Amt/Area Ref Grp Name [min]



# ------- ~ 

# -- ~ 

# -- ~ 

# ----------

Sig [ug/mL] 

# I---------- --------------- 3.137 1 1 3.90000 

# I ---------- 296.43666 1.31563e-2 Hydrogen fluoride 2 7.26200 569.93527 1.27418e-2 3 10.19000 804.74997 1.26623e-2 4 15.04000 1181.98816 1.27243e-2



### Calibration ----------------



### Curves

-------------------- 

### Hydrogen fluoride at exp RT 3.137Area

### 12°° 4 

### I VWD1 A, Wavelength=260 nm 1000= i Correlation: 0.99998 

### $00_ ; Residual Std. Dev.: 6.25011 = 3 ! Formula: y = mx 500= Z m: 78.57715 

### 400= i 

### x: Amount [ug/mL] ' y : Area 200 = N 0 5 10 15 Amountf ug/mL] 

### 'roucho 6/4/97 3:21:25 PM BGH C-27 

### Page 1 of 1



## ~~ ~

### Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\001-0101.D Sample Name: Std I

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### Injection Date : 03-Jun-97, 11:46:05 Seq. Line : 1 Sample Name : Std 1 Vial : 1

~ 

### Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M 

### Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A\001-0101.0) mAU

~ o • 1 I

, i I
80 -- ~

7 ~ I

60 = ~ 0 I = , d rn , o 40

_ I j I ~ 

## O Area: 310.707 20 — ~

~ \



### , ~ ~; ~_ ~ i •`, 0

. ~
0 1 2 3 4 m:

--------------------------------------------------------------------- 

### External Standard Report

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks

. not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 3.021 MM - 310.70706 1.27263e-2 3.95417 Hydrogen fluoride Totals : 3.95417

--------------------------------------------------------------------- 

### *** End of Report ***

Groucho 6/3/97 10:11:03 PM BGH C-28 Page i

- of " 

## 1'5~J~

### Data F•ile F:\HPCHEM\2\DATA\1997DATA\0597-26A\001-1801.D Sample Name: Std :

Injection Date : 03-Jun-97, 17:54:58 Seq. Line : 18 

### Sample Name : Std 1 vial : 1

~ 

### Acq. Operator : BGH Inj : 1 Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/4/97 9:58:27 AM by BGH (modified after loading) Pnalysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A\001-1801.D) mAU 

# - I 0 i i

40 ' ~

i ~ c 

# 30

~ 

# o

_
20 - 

### ~ Area: 275.184 

# 10 - ;

~ 

# 1

0 -

0 1 2 v 4 5 6 mir

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### External Standard Report

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1
-- 1 ------------------ 2.812 MM 275.18378 1.27263e-2 3.50208 Hydrogen fluoride Totals : 3.50208

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### *** End of Report ***

Groucho 6/4/97 9:58:28 AM BGH C-29 Page 1 or 1 

# / ~~T)ata File 

### F:\HPCHEM\2\DATA\1997DATA\0597-26A\002-0201.D Sample Name: Sr-d 2

Injection Date 03-Jun-97, 

### 11:53:56 Seq. Line 2 Sample Name Std 2 Vial 2



### — Acq. Operator BGH Inj 

### I Sequence File - 

### F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method 

### AN_QUIK.M Analysis Method 

### F:\HPCHEM\2\METHODS\0597-26A.M .Last changed 

### 6/3/97 10:06:10 PM 

### by BGH Analysis of anions Ion 

### by Waters 430 IC 

### - PRP-x100 150x4.1 column

VWD 1 A, Wavelength=260 nm (0597-26A\002-0201 D) 1 mAU co r od) 80

cm

J
cn 40— Area: 581.581

20—



### o

1 2 3 min


### External Standard Report

Sorted By 

### Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 

### PM Multizlier 1.0000 

### Dilution 1.0000 

### Uncalibrated Peaks not reported Signal 1: 

### VWD1 A, 

### Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU 

### * s [Ug/mL] ------- I ------ I ---------- I ---------- I ---------- 1 - 1 ------------------ 3.061 MM 

### . 581.58105 1.27263e-2 7.40140 Hydrogen fluoride 

### Totals

: 

### 7.40140
End of Report

,3rouchc) 6/3/97 10:11:35 

### PM BGH 

### C-30 Page 1 

### of 1 

# 1 ( ~1~

### ')a'ta File F:\HPCHEM\2\DATA\1997DATA\0597-26A\002-2001.D Sample Name: Std 2

Injection Date : 03-Jun-97, 18:46:40 Seq. Line : 20 Sample Name : Std 2 Vial : 2 -- Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VW01 A, Wavelength=260 nm (0597-26A\002-2001.D) mAU i

~ ^ I



### _ ici ( i
80 --

60 i I ~ T I = I

- m O 40

~ ; ~Area: 558.289

~

- ~ n 20 —

o

0 1 2 3 4 min


### External Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 3.069 MM . 558.28949 1.27263e-2 7.10498 Hydrogen fluoride Totals : 7.10498

' ---------------------------------------------------------------------

--------------------------------------------------------------------- 

### *** End of Report ***

Groucho 6/3/97 10:22:04 PM BGH C-31 Page 1 

# ~~ k

### Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\003-0301.D Sample Name , : St--

~ 

### ; 3
Injection Date : 03-Jun-97, 12:01:50 Seq. Line : 3 Sample Name : Std 3 Vial : 3 Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A\003-0301.D) Lo mAU I

~ o
o`

~ I y 80

— O

~ I ~



# T

_ U7

~~~.

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 

### External Standard Report

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [rnin] mAU *s [ug/mL]



# ------- ~ 

# ------ ~ 

# ---------- I ---------- I ---------- 1--1------------------ 3.095 MM 823.49884 1.27263e-2 10.48013 Hydrogen fluoride Totals : 10.48013

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### *** End of Report ***

Groucho 6/3/97 10:12:08 PM BGH C-32 Page 1 of 1



## ~~~

### Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\003-2101.D Sample Name: S

- d :
Injection Date : 03-Jun-97, 18:54:57 Seq. Line : 21 

### Sample Name : Std 3 Vial : 3

~ 

### . Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Aca. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VW01 A, Wavelength=260 nm (0597-26A\003-2101.D) mAU _ i ~ , ~ i lo

i ! ~ 80

' o 

### ' T

T_ 60 -,

~ i 1 QI 0 n Area: 786.001

40 I1 ! 1 1 i `!

20 -

0

— ✓

0 1 2 3 4 m!n

----------------------------------------------- 

### External Standard Report
Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [rnin] mAU *s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 3.097 MM _ 786.00110 1.27263e-2 10.00292 Hydrogen fluoride Totals : 

### 10.00292
*** End of Report ***

Groucho 6/3/97 10:22:34 PM BGH C-33 Page 1 of = 

### /-3tD

### Data File F:\HPCHEM\2\DATA\1997DATA\0597-26A\004-0401.D Sample Name: Std 4

- ----- ------------------ 

### Injection Date : 03-Jun-97, 12:09:38 Seq. Line 4 Sample Name : Std 4 Vial : 4 Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Analysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A\004-0401.D) mAU j ~ i co ~ ~

~ I ~ w
80 ~ i Area: 1209.77

~ ~ ~ ,•- 60 I 1 j

~

40. i

! ~ I ,

20 —

0

0

--------------------- 

### External Standard Report
Sorted By Signal Ca1ib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 3.140 MM 1209.77063 1.27263e-2 15.39596 Hydrogen fluoride Totals : 15.39596
*** End of Report ***

Groucho 6/3/97 10:12:39 PM BGH C-34 Page 1 of 1 

# /31-

### nat•a File F:\HPCHEM\2\DATA\1997DATA\0597-26A\004-2201.D Sample Name: Std 4

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### Injection Date : 03-Jun-97, 19:03:11 Seq. Line : 22 Sample Name : Std 4 Vial : 4 Acq. Operator : BGH Inj : 1 Sequence File : F:\HPCHEM\2\SEQUENCE\0597-26A.S Acq. Method : AN_QUIK.M Analysis Method : F:\HPCHEM\2\METHODS\0597-26A.M Last changed : 6/3/97 10:06:10 PM by BGH Ana lysis of anions Ion by Waters 430 IC - PRP-x100 150x4.1 column

VWD1 A, Wavelength=260 nm (0597-26A\0042201.0) mAU ; I ~ ~ r- g

,

, I 

# 80

i 

# _ ~ i ^
60 - ~ i ~ Area: 1154.21

, i j % •

• - ; Q 40 , i
i I

20 - i ~

C~ 7

0 1 2 3 4 min

--------------------------------------------------------------------- --------------------------------------------------------------------- 

### External Standard Report

--------------------------------------------------------------------- 

### Sorted By Signal Calib. Data Modified Tuesday, June 03, 1997 10:05:30 PM Multiplier 1.0000 Dilution 1.0000 Uncalibrated Peaks not reported Signal 1: VWD1 A, Wavelength=260 nm Results obtained with enhanced integrator! RetTime Type Area Amt/Area Amount Grp Name [min] mAU * s [ug/mL] 

# ------- I ------ I ---------- I ---------- I ---------- 1--1------------------ 3.136 MM 1154.20569 1.27263e-2 14.68882 Hydrogen fluoride Totals 14.68882

--------------------------------------------------------------------- 

### *** End of Report ***

7roucho 6/3/97 10:23:06 PM BGH C-35 Page 1of 1 

## ~

### APPENDIX D

PRODUCTION DATA

n_1 

# /0

### Client: Statesville Brick Company

Date: May 15, 1997 Production Data Furnished By: Brad Brown Technical Services Statesville Brick Company
During sampling the following production parameters were recorded: Single brick weight: 3.8 pounds/brick Number of bricks per car: 6,336 bricks/car Number of cars per day: 19.35 cars/24 hours Production Rate: 9.706 tons per hour



# D-2 /3 

# ~

### APPENDIX E

CALIBRATION DATA

E-1



## ~~

### QUALITY ASSURANCE AND EQUIPMENT CALIBRATION PROCEDURES



### General. Each item of field or laboratory test equipment purchased or fabricated by Trigon Engineering Consultants is assigned a unique, permanent identification number. New items for which calibration is required are calibrated before initial field use. Equipment whose calibration status may change with use or with time is inspected in the field before testing begins, and again upon return from each field use. When an item of equipment is found to be out of calibration, it is adjusted and recalibrated or retired from service. All equipment is periodically recalibrated in full, regardless of the outcome of these regular inspections. Calibrations are conducted in accordance with United States Environmental Protection Agency (US EPA) specifications. Trigon follows the calibration procedures outlined in EPA Reference Methods found in the Code of Federal Regulations (Volume 40, Part 60) and those recommended in the Quality Assurance Handbook for Air Pollution Measurement Systems: Volume III (EPA/600/R-94/038c). When the Reference Methods do not detail procedures, Trigon uses methods such as those prescribed by the American Society for Testing and Materials (ASTM). Data obtained during calibrations are recorded on standardized forms, which are verified for completeness and accuracy by the Quality Assurance Manager. Data reduction and subsequent calculations are performed using Trigon's Air Quality Data System. Calibration calculations are performed by an environmental scientist, independently audited by the Project Manager, and reviewed by the Quality Assurance Manager for verification of data. Copies of calibration data are included in each test or project report. Inspection and Maintenance. An effective preventative maintenance program is necessary to ensure equipment performance quality prior to, during, and following every test. Each item of equipment returning from the field is inspected before it is returned to storage. During the course of these inspections, items are cleaned, repaired, reconditioned, and recalibrated when necessary. Each item of equipment transported to the field for a test project is inspected again prior to being packed. Trigon performs these quality assurance checks prior to departure for the project site to detect equipment problems which may occur during periods of storage. Trigon transports adequate back-up equipment to each project so as to avoid any unforeseen circumstances. Calibration. Source sampling equipment that require calibration include nozzles, pitot tubes, thermometers, flow meters, dry gas meters, and barometers. The following sections detail the calibration procedures followed by Trigon for each item.

E-2 

### / 2`

### Nozzles. Each probe nozzle is uniquely and permanently identified at the time of purchase

or fabrication, and it is calibrated before initial field use and prior to each test. The inside diameter of the nozzle is measured to the nearest 0.001 inch using a digital micrometer. Three measurements are made using different diameters each time. If the difference between the high and the low measurements do not exceed 0.004 inch, the average of the three measurements is used. If the difference exceeds this amount, or when the nozzle becomes nicked, dented, or corroded, the nozzle is reshaped, sharpened, and recalibrated. Regardless of usage, all nozzles are inspected and recalibrated on a yearly basis. Pitot Tubes. All Type S pitot tubes are constructed and calibrated in strict accordance with the procedures contained in EPA Reference Method 2. A Type S pitot tube will have a coefficient of 0.84 ±0.02. A standard pitot tube will have a coefficient of 0.99. Each pitot tube is visually inspected prior to any field use. If the inspection indicates damage, it is recalibrated. Regardless of usage, all pitot tubes are inspected and recalibrated on a yearly basis. Drv Gas Meter and Orifice. Each metering system receives a full calibration at the time of purchase and annually, thereafter. Post-test calibrations are performed after each source test. If the calibration factor, y(gamma), deviates by less than five percent from the initial value, the test data are acceptable. If y deviates by more than five percent, the meter is recalibrated and the meter coefficient (initial or recalibrated) that yields the lowest sample volume for the test runs is used. Standard practice at Trigon is to recalibrate the dry gas meter anytime y 

### is found to be outside the range of 0.98 < y< 

### 1.02. Barometer. Each field barometer is calibrated to agree within ± 0.1 inches Hg of a reference mercury barometer. The barometric pressure is corrected for pressure and temperature. Prior to and following each field test the field barometer is verified. Thermometers. Each new thermometer, pyrometer and thermocouple purchased or fabricated by Trigon is calibrated in strict accordance with US EPA Protocol. Calibration tolerance limits are as follow: Impinger Temperature Gauge ± 1°C or 2°F Dry Gas Meter Temperature Gauge ±3°C or 5.4°F Stack Thermocouples ±1.5% of absolute temperature All thermometers and thermocouples are inspected and calibrated prior to and following each field test. Regardless of usage, all thermometers and thermocouples are inspected and recalibrated on a yearly basis. Laboratory Equipment. Trigon Engineering Consultants has a written quality assurance document that 'covers calibration and maintenance of laboratory equipment. This includes calibration of each analytical balance against Class S weights. Calibration of thermometers, barometers, and wet test meters are traceable to NIST. A copy of our quality assurance document may be obtained by written request.

E-3 

# 13 ~ 

# 7

### PRETEST - POSTEST CALIBRATION DATA FORM Client 

### 'e-h_ Pretest Date &

- 7 Calibrator 

### Ou/ Reference Thermometer 

### 100.022 City/State 

### 54-k,-z.Xi r Postest Date e ~ 407 Calibrator 

### TzA-. , Reference Barometer 

### 600.003
Pretest' - > 

### Postest

,. Tem eratu '°F Ref. Teni '` °F Tem rature .°F Ref. Tem p` Ome a Red Team DBIWB#100.025 Omeiza Green Team DB/WB #100.031 Ome a Blue Team DB/WB #100.017 71171 7/ ?st~ Z~ Ome a Gold Team DBAVB#100.032 Ome a Grev Team DB #100.033 Ome a CEM DBAVB#100.026 Drv Gas Meter Inlet/Outlet #300.035 Drv Gas Meter Inlet/Outlet #300.045 Drv Gas Meter Inlet Outlet #300.067 Drv Gas Meter Inlet/Outlet #300.100 Drv Gas Meter Inlet/Outlet #300.200 Drv Gas Meter Inlet/Outlet #300.214 Drv Gas Meter Inlet Outlet #300.241 Drv Gas Meter Inle Outlet #300 .248 Drv Gas Meter Inlet/Outlet #300. Drv Gas Meter Inlet Outlet #300. Umbilical Ada tor # #300. Umbilical Ada tor # #300. Umbilical Ada tor # #300. Umbilical Ada tor # #300. Umbilical Ada tor # #300. Umbilical Ada tor # #300. Probe #200. Probe #200. Probe #200. Probe #200. Probe #200. Probe #200. Pitot #200. otY 7/ ?/ Zc Pitot #200. 7 7/ 70 7 v .qv0, 1.750 : ' t Z`L 7/ .12-1 °e, 70 CO, 0 3 0 72- 71 110 ?o

;. Field Baro' irt. A Ref Baro iu: He Fiildi Baro in Ref. Baro Barometer Red Team #600.001 Barometer Green Team #600.014 Barometer Blue Team #600.010 '29• /0 .Z9.0leS

~ o2S,9S g, 90G Barometer Gold Team #600.021 D Barometer CEM #600.020 D 

### Were all postest calibrations within the specified EPA Quality Assurance criteria? )e Yes ❑ No

E-4 130

### TYPE "S" PITOT TUBE CALIBRATION FORM 

### Date: 01/03/97 Calibrator: JJT Specifications: A.) Pitot tube assembly must be level. B.) If pitot tube is damaged explain under comments section. C.) Z= A Sin y(<0.125) and W= A Sin 0(<0.03125) D.) a < 10° and /3 <5° I.D. Length al ° cr2° 01 ° P2° y° 9° A, in. Z, in. W, in. PA, in. PB, in. Dt, in. Individual Pitot Tubes 200.057 1' 1.0 1.0 0.5 1.0 0.0 0.0 0.630 0.000 0.00000 0.315 0.315 0.247 200.019 2' 1.0 1.0 0.0 0.0 1.0 1.0 0.936 0.016 0.01634 0.468 0.468 0.377 200.058 30" 0.0 1.0 2.0 4.0 3.0 0.0 0.918 0.048 0.00000 0.459 0.459 0.377 200.049 3' 3.0 0.0 1.0 1.0 1.0 1.5 0.949 0.017 0.02484 0.474 0.475 0.375 200.028 3' 2.0 7.0 1.0 1.0 3.0 1.0 0.977 0.051 0.01705 0.488 0.489 0.375 200.025" 5' 1.0 2.0 2.0 2.0 1.0 1.5 0.931 0.016 0.02437 0.466 0.465 0.379 200.054 5' 2.0 1.0 0.5 0.5 1.0 1.5 0.784 0.014 0.02052 0.392 0.392 0.377 200.044 6' 2.0 1.0 1.0 1.0 3.0 1.0 0.984 0.051 0.01717 0.492 0.492 0.376 200.038 7' 3.0 0.0 0.0 0.0 0.0 1.5 0.951 0.000 0.02489 0.476 0.475 0.376 200.030 7' 6.0 7.0 1.0 1.0 2.0 1.0 0.978 0.034 0.01707 0.489 0.489 0.374 200.055 7' 1.0 1.0 0.0 1.0 0.0 1.0 0.841 0.000 0.01468 0.421 0.420 0.375 200.03110' 4.0 8.0 1.0 0.0 1.0 1.5 0.943 0.016 0.02468 0.471 0.472 0.372 300.164 And. 3.0 3.0 1.0 3.0 3.0 1.0 1.113 0.058 0.01942 0.556 0.557 0.374

Comments: Pitot Tubes Required Only Minor Maintenance - Further Calibration Not Required " Inconel 300.164 = Anderson Pitot Tube Extension C , - 

### E-5 

# /3J

~~ 

# n, ;

## TEMPERATURE SENSOR CALIBRATION FORM

NIST REFERENCE THERMOlV1ETER TRANSFER CALIBRATION Tolerance: +/- 1.5% of Absolute Temperature
Date: 01/03/97 Barometric Pressure, In. Hg: 29.455 Ambient Temperature, Deg. F: 76 Reference Thermometer No.: 100.023 Calibrated By: PRJ Reference Thermometer No.: 100.028
NIST Reference Transfer Temperature Thermocouple Reference Thermometer Instrument Difference ID No. Point Source Temperature Temperature CalculatIon Degrees F Degrees F Percent, % -30 to 120 Deg. F Thermometer Serial Number 97133 100.022 1 Water Bath 46 46 0.00

2 Water Bath 74 74 0.00 3 Water Bath 120 120 0.00 -5 to 400 Deg. C Thermometer Serial Number U38717 100.024 1 Water Bath 74 23 Deg. C 0.11

2 Water Bath 120 49 Deg. C -0.03 3 Oil Bath 274 134 Deg. C 0.11 •120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T-124997 Red Team 100.025 1 Water Bath 47 47 0.00

2 Water Bath 72 72 0.00 3 Water Bath 181 181 0.00 -120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T-151625 Green Team 100.031 1 Water Bath 46 46 0.00

2 Water Bath 74 75 -0.19 3 Water Bath 208 207 0.15 -120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T-98180 Blue Team 100.017 1 Water Bath 46 46 0.00

2 Water Bath 74 74 0.00 3 Water Bath 186 187 -0.15 -120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T-156311 Gold Team 100.032 1 Water Bath 46 46 0.00

2 Water Bath 74 74 0.00 3 Water Bath 186 186 0.00 -120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T-156877 Grey Team 100.033 1 Water Bath 47 47 0.00

2 Water Bath 76 76 0.00 3 Water Bath 193 193 0.00 -120 to 2000 Deg. F Omega HH25 KF Pyrometer Serial Number T-148889 CEM 100.026 1 Water Bath 46 46 0.00

2 Water Bath 74 74 0.00 3 Water Bath 186 186 0.00

Source = Type of calibration system used. Temperature Difference Calculation: (Ref. Temp. Deg. F+ 460) -(Test Temp. Deg. F+ 460) ---- — ---- — ------ ------------------------------------------------------- X 100 = <1.5%

Ref. Temp. Deg. F+ 460 ro
E-6 // 

### ~ /r

## TEMPERATURE SENSOR CALIBRATION FORM THERMOCOUPLES Tolerance: +/- 1-5% of Absolute Temperature
Date: 01/03/97 Barometric Pressure, In. Hg: Ambient Temperature, Deg. F: 76 Reference Thermometer No.: Calibrated By: PRJ Reference Thermometer No.: 29.455 100.024 100.028
Reference Thermocouple Tetnperature Thermocouple Reference Thermotneter Potentiometer Difference ID No. Polnt Source Temperature Temperature Calculation Degrees F Degrees F Percent, % Omega HH-25 KF Dry Bulb - Red Team 100.025 1 Water Bath 72 72 0.00

2 Water Bath 181 181 0.00 3 Oil Bath 290 289 0.13 Omega HH-25 KF Wet Bulb - Red Team 100.025 1 Water Bath 72 72 0.00

2 Water Bath 135 135 0.00 3 Water Bath 173 173 0.00 Omega HH-25 KF Dry Bulb - Green Team 100.031 1 Water Bath 76 75 0.19

2 Water Bath 175 175 0.00 3 Oil Bath 295 296 -0.13 Omega HH-25 KF Wet Bulb - Green Team 100.031 1 Water Bath 76 75 0.19

2 Water Bath 138 137 0.17 3 Water Bath 177 177 0.00 Omega HH-25 KF Dry Bulb - Blue Team 100.017 1 Water Bath 76 76 0.00

2 Water Bath 175 175 0.00 3 Oil Bath 295 296 -0.13 Omega HH-25 KF Wet Bulb - Blue Team 100.017 1 Water Bath 76 76 0.00

2 Water Bath 138 137 0.17 3 Water Bath 177 177 0.00 Omega HH-25 KF Dry Bulb - Gold Team 100.032 1 Water Bath 76 76 0.00

2 Water Bath 175 175 0.00 3 Oil Bath 295 295 0.00 Omega HH-25 KF Wet Bulb - Gold Team 100.032 1 Water Bath 76 76 0.00

2 Water Bath 138 138 0.00 3 Water Bath 177 177 0.00

Source = Type of calibration system used. Temperature Difference Calculation: (Ref. Temp. Deg. F+ 460) -(Test Temp. Deg. F+ 460) ----- ---------------------------------------------- — ---- ------------- X 100 = <1.5%

Ref. Temp. Deg. F+ 460


### E-7 / 

# ~ /

## TEMPERATURE SENSOR CALIBRATION FORM THERMOCOUPLES Tolerance: +/- 1-5% of Absolute Temperature
Date: 01/03/97 Barometric Pressure, In. Hg: Ambient Temperature, Deg. F: 76 Reference Thermometer No.: Calibrated By: PRJ Reference Thermometer No.: 29.455 100.024 100.028
Reference Thermocouple Temperature Thermocouple Reference Thermometer Potentiometer Difference ID No. Point Source Temperature Temperature Calculation Degrees F Degrees F Percent, % Omega HH-25 KF Dry Bulb - Grey Team 100.033 1 Water Bath 76 76 0.00

2 Water Bath 193 193 0.00 3 Oil Bath 290 291 -0.13 Omega HH-25 KF Wet Bulb - Grey Team 100.033 1 Water Bath 76 76 0.00

2 Water Bath 145 144 0.17 3 Water Bath 193 193 0.00 Omega HH-25 KF Dry Bulb - CEM 100.026 1 Water Bath 76 76 0.00

2 Water Bath 175 175 0.00 3 Oil Bath 295 296 -0.13 Omega HH-25 KF Wet Bulb - CEM 100.026 1 Water Bath 76 76 0.00

2 Water Bath 138 137 0.17 3 Water Bath 177 177 0.00

Source = Type of calibration system used. Temperature Difference Calculation: (Ref. Temp. Deg. F+ 460) -(Test Temp. Deg. F+ 460) ------- --------- — ---- ----------------------------------------------- X 100 = <1.5%

Ref. Temp. Deg. F+ 460

E-8

### TEMPERATURE SENSOR CALIBRATION FORM THERMOCOUPLES Tolerance: +/- 1.5% of Absolute Temperature
Date: 01/03/97 Barometric Pressure, In. Hg: 29.455 Ambient Temperature, Deg. F: 76 Reference Thermometer No.: 100.023 Calibrated By: PRJ Reference Thermometer No.: 100.024 Reference Thermocouple Temperature Thermocouple Reference Thermometer Potentiometer Difference ID No. Point Source Temperature Temperature Calculation Degrees F Degrees F Percent, % 2' Pitot Tube 200.019 1 Water Bath 73 73 0.00

2 Water Bath 190 190 0.00 3 Oil Bath 393 391 0.23 30" Pitot Tube 200.058 1 Water Bath 55 55 0.00

2 Water Bath 187 186 0.15 3 Oil Bath 376 375 0.12 3' Pitot Tube 200.049 1 Water Bath 73 73 0.00

2 Water Bath 190 190 0.00 3 Oil Bath 392 390 0.23 3' Pitot Tube 200.028 1 Water Bath 74 74 0.00

2 Water Bath 188 188 0.00 3 Oil Bath 391 392 -0.12 5' Pitot Tube - Inconel 200.025 1 Water Bath 73 73 0.00

2 Water Bath 188 188 0.00 3 Oil Bath 389 387 0.24 4 Muffle Furnace 520 522 -0.20 5 Muff7e Furnace 857 855 0.15 6 Muffle Furnace 1115 1116 -0.06 5' Pitot Tube 200.054 1 Water Bath 75 75 0.00

2 Water Bath 188 188 0.00 3 Oil Bath 388 387 0.12 6' Pitot Tube 200.043 1 Water Bath 73 73 0.00

2 Water Bath 186 185 0.15 3 Oil Bath 386 385 0.12 T Pitot Tube 200.038 1 Water Bath 73 73 0.00

2 Water Bath 186 186 0.00 3 Oil Bath 383 382 0.12 T Pitot Tube 200.030 1 Water Bath 73 73 0.00

2 Water Bath 184 184 0.00 3 Oil Bath 391 391 0.00 7' Pitot Tube 200.055 1 Water Bath 73 73 0.00

2 Water Bath 184 183 0.16 3 Oil Bath 386 385 0.12 10' Pitot Tube 200.031 1 Water Bath 73 73 0.00

2 Water Bath 183 183 0.00 3 Oil Bath 388 388 0.00 Source = Type of calibration system used. Temperature Difference Calculation: (Ref. Temp. Deg. F+ 460) -(Test Temp. Deg. F+ 460) ------------------------------- -- ----------------- ---------------------- X 100 = < 1.5%

Ref. Temp. Deg. F+ 460 I


### E-9 TF

~ 

### ICa'OIV'

## TEMPERATURE SENSOR CALIBRATION FORM THERMOCOUPLES Tolerance: +/- 1.5% of Absolute Temperature
Date: 01/03/97 Barometric Pressure, In. Hg: 29.455 Ambient Temperature, Deg. F: 76 Reference Thermometer No.: 100.023 Calibrated By: JJT Reference Thermometer No.: 100.028
Reference Thermocouple Temperature Thermocouple Reference Thermometer Potentiometer Difference ID No. Point Source Temperature Temperature Calculation Degrees F Degrees F Percent, % 400.030 BimetallIc DGM Body 1 Water Bath 33 33 0.00

2 Water Bath 73 73 0.00 3 Water Bath 120 120 0.00 400.032 DGM Body 1 Water Bath 33 34 -0.20

2 Water Bath 73 73 0.00 3 Water Bath 185 185 0.00 400.050 DGM Inlet 1 Water Bath 33 34 -0.20

2 Water Bath 73 73 0.00 3 Water Bath 186 186 0.00 400.050 DGM Outlet 1 Water Bath 33 34 -0.20

2 Water Bath 73 73 0.00 3 Water Bath 184 184 0.00

Source = Type of calibration system used. Temperature Difference Calculation: (Ref. Temp. Deg. F+ 460) -(Test Temp. Deg. F+ 460) -------------------------------- ----- ---- — ----- ---- ------------ -------- X 100 = <1.5%

Ref. Temp. Deg. F+ 460 I 

# .,a , ~ 

# r F ~

### EVER READY THERMOMETER CO., INC. 228 LACKAWANNA AVENUE WEST PATTERSON, NJ 07424 (201) 812-7474 PAGE 1 OF 2

R E P 0 R T 0 F CALIBRATION LIQUID-IN-GLASS-THERMOMETER CALIBRATED BY EVER READY THERMOMETER C0. FOR: TRIGON ENGINEERING MARKED: ERTCO CAT 1002-3FC S/N-2890 RANGE: +30 TO +124 DEGREES F IN 0.2 DEGREE GRADUATIONS.

THERMOMETER CORRECTION READING (ITS-90)** 32.00 F 0.00 F 40.00 -0.06 60.00 -0.06 100.00 0.00 120.00 -0.06 ** ALL TEMPERATURES IN THIS REPORT ARE BASED ON THE INTERNATIONAL TEMPERATURE SCALE OF 1990 (ITS-90) PUBLISHED IN THE METROLGIA 27, NO. 1, 3/10/90. THIS THERMOMETER WAS CALIBRATED AGAINST A STANDARD CALIBRATED AT THE NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY (NIST) FORMERLY THE NATIONAL BUREAU OF STANDARDS (NBS) IN ACCORDANCE WITH ASTM METHOD E 77, AND NBS MONOGRAPH 174. FOR A DISCUSSION OF ACCURACI-ES ATTAINABLE WITH SUCH THERMOMETERS SEE NBS MONOGRAPH 250-23. IF NO SIGN IS GIVEN ON THE CORRECTION, THE TRUE TEMPERATURE IS HIGHER THAN THE INDICATED TEMPERATURE; IF THE SIGN GIVEN IS NEGATIVE, THE TRUETEMPERATURE IS LOWER THAN THE INDICATED TEMPERATURE. TO USE THE CORRECTIONS PROPERLY, REFERENCE SHOULD BE MADE TO THE NOTES GIVEN BELOW. THE THERMOMETER WAS TESTED IN A LARGE, CLOSED-TOP, ELECTRICALLY HEATED, LIQUID BATH, BEING "IMMERSED" 76MM. THE TEMPERATURE OF THE ROOM WAS ABOUT 25 DEGREES C(77 DEGREES F). IF THE THERMOMETER IS USED UNDER CONDITIONS WHICH WOULD CAUSE THE AVERAGE TEMPERATURE OF THE EMERGENT LIQUID COLUMN TO DIFFER MARKEDLY FROM THAT PREVAILING IN THE TEST, APPRECIABLE DIFFERENCES IN THE INDICATIONS OF THE THERMOMETER WOULD RESULT.

CONTINUED

TEST NUMBER: 154161 DATE: 11/26/96 STANDARD SERIAL NO. 128239 NIST IDENTIFICATION NO. 88024 / E-11 

# /613

### EVER READY THERMOMETER CO., INC. PAGE 2 OF 2
R E P 0 R T 0 F CALIBRATION LIQUID-IN-GLASS-THERMOMETER

THE TABULATED CORRECTIONS APPLY PROVIDED THE ICE-POINT READING, TAKEN AFTER EXPOSURE FOR NOT LESS THAN 3 DAYS TO A TEMPERATURE OF ABOUT 20 DEGREES C(70 DEGREES F) IS 32.00 DEGREES F. IF THE ICE-POINT READING IS FOUND TO BE HIGHER (OR LOWER) THAN STATED, ALL OTHER READINGS WILL BE HIGHER (OR LOWER) TO THE SAME EXTENT. IF THE THERMOMETER IS USED AT A GIVEN TEMPERATURE SHORTLY AFTER BEING HEATED TO A HIGHER TEMPERATURE. AN ERROR OF 0.01 DEGREES OR LESS, FOR EACH 10 DEGREE DIFFERENCE BETWEEN THE TWO TEMPERATURES, MAY BE INTRODUCED. THE TABULATED CORRECTIONS APPLY IF THE THERMOMETER IS USED IN THE UPRIGHT POSITION; IF USED IN A HORIZONTAL POSITION, THE INDICATIONS MAY BE A FEW HUNDREDTHS OF A DEGREE HIGHER.

TEST NUMBER: 154161 DATE: 11/26/96 STANDARD SERIAL NO. 128239 NIST IDENTIFICATION NO. 88024

-------- 

# ~ Charles Tang-Niz QUALITY CONTROL 

# E-12 /

~ 

# -16

### EVER READY THERMOMETER CO., INC. PAGE 1 OF 2 228 LACKAWANNA AVENUE WEST PATTERSON, NJ 07424 (201) 812-7474

R E P 0 R T 0 F CALIBRATION LIQUID-IN-GLASS-THERMOMETER CALIBRATED BY EVER READY THERMOMETER CO.
MARKED: ERTCO CAT 612-3FC S/N-2775 RANGE: 0 TO +300 DEGREES F IN 2 DEGREE GRADUATIONS.

THERMOMETER CORRECTION READING (ITS-90)** 32.6 F -0.6 F 100.0 -1.6 200.0 -1.4 300.0 -1.0 ** ALL.TEMPERATURES IN THIS REPORT ARE BASED ON THE INTERNATIONAL TEMPERATURE SCALE OF 1990 (ITS-90) PUBLISHED IN THE METROLGIA 27, NO. 1, 3/10/90. THIS THERMOMETER WAS CALIBRATED AGAINST A STANDARD CALIBRATED AT THE NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY (NIST) FORMERLY THE NATIONAL BUREAU OF STANDARDS (NBS) IN ACCORDANCE WITH ASTM METHOD E 77, AND NBS MONOGRAPH 174. FOR A DISCUSSION OF ACCURACIES ATTAINABLE WITH SUCH THERMOMETERS SEE NBS MONOGRAPH 250-23. IF NO SIGN IS GIVEN ON THE CORRECTION, THE TRUE TEMPERATURE IS HIGHER THAN THE INDICATED TEMPERATURE; IF THE SIGN GIVEN IS NEGATIVE, THE TRUETEMPERATURE IS LOWER THAN THE INDICATED TEMPERATURE. TO USE THE CORRECTIONS PROPERLY, REFERENCE SHOULD BE MADE TO THE NOTES GIVEN BELOW. THE THERMOMETER WAS TESTED IN A LARGE, CLOSED-TOP, ELECTRICALLY HEATED, LIQUID BATH, BEING "IMMERSED" 76MM. THE TEMPERATURE OF THE ROOM WAS ABOUT 25 DEGREES C(77 DEGREES F). IF THE THERMOMETER IS USED UNDER CONDITIONS WHICH WOULD CAUSE THE AVERAGE TEMPERATURE OF THE EMERGENT LIQUID COLUMN TO DIFFER MARKEDLY FROM THAT PREVAILING IN THE TEST, APPRECIABLE DIFFERENCES IN THE INDICATIONS OF THE THERMOMETER WOULD RESULT.

CONTINUED

TEST NUMBER: 155404 DATE: 04/22/97 STANDARD SERIAL NO. 48511 NIST IDENTIFICATION N0. 92564

E-13 

# / V7

### EVER READY THERMOMETER CO., INC. PAGE 2 OF 2
R E P 0 R T O F CALIBRATION LIQUID-IN-GLASS-THERMOMETER

THE TABULATED CORRECTIONS APPLY PROVIDED THE ICE POINT READING IS 32.6 DEGREES F. IF THE ICE-POINT READING IS FOUND TO BE HIGHER (OR LOWER) THAN STATED, ALL OTHER READINGS WILL BE HIGHER (OR LOWER) TO THE SAME EXTENT.

TEST NUMBER: 155404 DATE: 04/22/97 STANDARD SERIAL NO. 48511 NIST IDENTIFICATION N0. 92564 

# . /
Charles Tang

- 

### Nian / 

### QUALITY CONTROL MA

~ 

### 1

E-14 / y0453 

# Bulletin D-01-82

S Suaa

~ sean 0•2- 7 a 6 0
. 17 .73 

### Meteorological Instruments 

# I s



## & Pressure Gauqes 

# m I m



# NATIONAL WEATHER SERVICE

- TYPE

MERCURIAL BAROMETERS Usable up to 900 metres (3,000 feet) T'ne National Weather Service type barometer is P91NC0's highest grade mercurial barcmeter. It is used by weather services and airports the wcrld over. T'ne glass tube has a uniform inside 

### diameter of 7 mm for constant capfllary depression throughout the length of the scale. Scales are sat at the factory by compariscn with a barometer certified by the Naticnal 8ureau of Standards, and read the local pressure without the necessity of correcting for 

### capillary depression. The vernier can be smoothly and precisely set by means of a rack and pinicn d; ive, controlled by a knurled adjusting knob. White plastic bac:<grounds on the mcunting panel facilitate observation of the Fortin rype cistern and mercury columrt. T'ne vemier has a sighting edge, front and rear, to avoid parallax. 

### A suspension bracket and an adjustable ring cfamp for the cistern hold the barometer firmly in the vertical position on the mounting panel. A dual scale Calsius/Fahrenheit thermometer with a— 25 to 50 °C/-10 to 120 °F range indicates the proper temperature to be used for temperature corrections. An instruction bcoklet with informaticn for understanding and proper use of the barometer is supclied with each instrument. Complete correction tables for temperature and gravity are included. T"nis barometer is accurate to = 0.3 mb, 0.2 mm, or 0.01 inch of 

### mercury when carefully set and read, and after temperature and gravity corrections ;ia , ,e been applied. For greatest accuracy a Certificate of Calibration may be obtained and the correction 

### contained therein also applied. Each National Weather Service barometer has a serial number. 

### The rugged construction of the National Weather Service type barometer is such that it can be shipped safely by United Parcel Service or express. The kidskin bag, in the Forcin type reservoir, dampens mercury column osciilations during shipment. The Iower part of the glass tube is narrowed down to minimize mercury weight, and is protected by foam cushions, thus offering added resistance to damage during shipment. The cistern may be .opened in the field for cleaning of the cistern glass and cistem mercury. Ttie 

### barometer contains approximately 680 grams (1.5 pounds) of inercury total. It is shipped completely assembled, filled with mercury and ready to use. Mounting panel dimensions are 19 x 76 x 1072 mm (314 x 3 x 42 inches). The shipping weight is 5 kg (11 pounds) and box dimensiens are 235 x 250 x 1197 mm (9 x 10 x 47 inches).



### Cataiog Number Scales 453 inch and millimetre 45381 inch and millibar 453M8 millibar and millimetre

E-15

# M.A.NUFACTURER'S CALIBRATION



# CERTIFICATE

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# NIA-NUFACTURER."S CALIBRATION 

# CERTIFICATE

The f-llcwincr record shows the accurac

- y o-f Your digital flowmer-er at tested fl.8w rates compared to 

## NTST *alib , :~ 

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## t andard TN 2505

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### E4-IA #1

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# -*: 21466 Pr .-. 7 `-'SUP_P TEOPE PP-4 7JPE (Cl) 

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