## From: Keith Barnett/RTP/USEPA/US

To: Cortney_Higgins@omb.eop.gov

Date: 07/31/2010 10:54 PM Subject:

Fw: EPA Organic HAP Data for Alternate THC Limit

Dear Courtney:

This isn't the official docket entry but I think you had asked for this.

Keith W. Barnett USEPA/OAQPS/SPPD/MMG
Mail Code D243

‐ 02
Research Triangle Park, NC 27711

919

‐ 541

‐ 5605 barnett.keith@epa.gov

Forwarded by Keith Barnett/RTP/USEPA/US on 07/31/2010 10:53 PM

From: Keith Barnett/RTP/USEPA/US

To: "Willis James" <jwillis@titanamerica.com>

Date: 01/25/2010 02:24 PM Subject: RE: EPA Organic HAP Data for Alternate THC Limit

(See attached file: II

‐ B

‐ 016.pdf)This is form the old docket

This is from the 2007 ICR data.

(See attached file: OrganicHAP 092908.xls) Keith W. Barnett USEPA/OAQPS/SPPD/MMG
Mail Code D243

‐ 02 Research Triangle Park, NC 27711

919

‐ 541

‐ 5605 barnett.keith@epa.gov

From: "Willis James" <jwillis@titanamerica.com>

To: Keith Barnett/RTP/USEPA/US@EPA

Date: 01/25/2010 01:09 PM Subject: RE: EPA Organic HAP Data for Alternate THC Limit

Keith:

Are you able to point me in the right direction for this data?

Thanks

Jay

## Fr om: Willis James

Sent: Thursday, January 21, 2010 4:33 PM amail.epa.gov

e THC Limit

ying to find the organic HAPs data that the EPA used in setting the

ternate THC limit. We have not been able to find on the Docket.

lis

mes S. Willis, III, P.E., P.G. rporate Engineering Environmental Manager Titan America, LLC

34 To: Barnett.Keith@ep Subject: EPA Organic HAP Data for Alternat

Keith

I am tr
al

Is this something you have that you can share.

Thanks

Jay

Jay Wil

Ja

Co

6071 Catawba Road Troutville, Virginia 24175
Office: (540) 966

‐ 65

Fax: (540) 966

‐ 6812
Mobile: (540) 892

‐ 9983 jwillis@titanamerica.com

nfidentiality Notice:

les attached to it, may contain confidential information

at is intended only for use of the Addressee(s) names above.

n in reliance

age Co

This message including fi
th
If you are not an intended recipient any dissemination or copying of the
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upon the information, is strictly prohibited. If you have received this mess in error, please notify the sender immediately by return Email or by phone and
delete the original transmission and any attachments without reading or saving in

any manner. Thank you.9/29/2008Summary of Organic HAP Test DataOCompanyLocationKilnKiln TypeRawMillAverag(as propppm @e THCane),7% O2Formalhyde,ppmvd%O2de@7Bepp%Onzene,mvd@72Toluenppmvd%O2e,@7Etbepp%Ohylnzene,mvd@72m,pXyleneppmvd%O2,@7Styrene,ppmvd@7%O2o-Xylene,ppmvd@7%O2Acetaldehyde,ppmvd@7%O2Phenol,ppmvd@7%O2Hexane,ppmvd@7%O2Naphthalene,ppmvd@7%O2TotalorganicHAP,ppmvd@7%O2Org. HAPas % ofTHCAsh Grove CementMontana City, MT 1wetno0.41ND0.06NDNDNDND NDND ND0.06 14.68Ash Grove CementMidlothian, TX 3wetno13.83Ash Grove CementLeamington,UT 1preheater/calciner yes14.14Ash Grove CementSeattle, WA1preheater/calcineryes14.232.78 0.13 0.052.96 20.80Ash Grove CementInkom, ID2wetno20.50Ash Grove CementInkom, ID1 wetnoND0.160.15 NDND ND NDND ND ND0.31Ash Grove CementDurkee, OR1preheater/calcineryes30.8415.54 0.210.090.25 0.24NDND16.33 52.94Ash Grove Cement(new) Durkee, OR1 preheater/calcineryes3.720.29 0.23 0.10.28 0.270.0021.172 31.51HolcimTridentKiln#1 wetno5.56HolcimMason CityKiln#3 long dryno6.78HolcimMason CityKiln#2 long dryno11.07HolcimArtesia, MSwetno18.35HolcimTheodore, ALKiln#1preheater/calciner no23.74HolcimHolly Hill, SCpreheater/calciner yes28.48HolcimPortland, COKiln#4preheater/calciner yes44.97HolcimMidlothian, TX Kiln#1preheater/calciner yes51.59HolcimDevil's Slide,UT Kiln#1preheater/calciner yes51.91HolcimMidlothian, TX Kiln#2preheater/calciner yes62.82HolcimClarksville, M121.01HolcimDundeeKiln#1 andwetno748.15LafargeWhitehall, PAKiln2 preheaterno8.33LafargeWhitehall, PAKiln3 preheaterno10.81LafargeRavena, NY1wetno25.26LafargeRavena, NY2wetno25.26LehighEvansville, PA Kiln2preheater/calciner no1.69LehighYork,PAWhiteCemwetno1.74LehighEvansville, PA Kiln1preheater/calciner no2.18LehighUnionBridgeE02-001preheater/calciner yes6.83LehighRedding, CA1preheateryes13.62LehighWaco, TX39wetno18.97LehighMitchell, IN1preheaterno49.09LehighMitchell, IN2preheaterno49.09LehighMason City8preheater/calciner yes50.53Lone Star Industries Oglesby, IL3long dryno2.25Lone Star Industries Maryneal3 preheaterno30.16Lone Star Industries Pryor3long dryno125.24Lone Star Industries Pryor2long dryno149.75Lone Star Industries Pryor1long dryno173.83TXIMidlothianKilnE2-22 preheater/calciner3.96LehighGlenFalls, NY1 PH/PCyes3.293.29LafargeTulsa2 long dryno0.040.04LafargeTulsa1 long dryno0.020.02California PCColton1 long dryno3.530.710.3 NDND ND ND ND ND ND4.54California PCColton1 long dryno1.470.30.05 NDND ND ND ND ND ND1.82California PCColton2 long dryno1.220.460.06 NDND ND ND ND ND ND1.74LafargeDavenport, IA1 preheater/calciner0.150.15LafargeSugarCreek, MO3 preheater/calcineryes5.57 0.59 0.4 0.350.98 0.54 0.418.84LehighLeeds, AL5 preheater6.86.8Test data in other unitsLafargeRavena1&2wetno55.20.51 0.92Average HAP % of THC 24.17Mean (ppmvd@7%O2) 3.433714Median (ppmvd@7%O@ 1.78OrganicHAP 092908.xlsPage 1

### 9/29/08

Organic HAP Test Data 9/26/2008

Plant/Kiln Lehigh, Glen Falls, NY

Test date 2002

Kiln ID Kiln 1 Kiln type PC

RM On Moisture, fraction 0.17

%O2 11 Formaldehyde ppmw 2.9 Formaldehyde ppmvd@7%O2 3.38 Acetaldehyde, acrylonitrile, hexane, phenol ND

RM Off
Moisture, fraction 0.19

%O2 6.73 Formaldehyde ppmw 3 Formaldehyde ppmvd@7%O2 2.39 Acetaldehyde, acrylonitrile, hexane, phenol ND

Total Formaldehyde, Wtd avg, ppmvd@7%O2 3.29 Formaldehyde, Wtd avg, tpy 0.95 Total organic HAP 3.29

Lehigh, Glen Falls, NY

Test date 2006

Kiln ID Kiln 1 Kiln type PC

RM On

%O2 11 Moisture, fraction 0.139 NMHC ppm@7% O2 pp @ 2.5 NMHC ppmvd@7% O2 2.15

NMHC lbs/hr 0.98

RM Off

%O2 5.90 Moisture, fraction 0.2006 NMHC ppm@7% O2 3.5 NMHC ppmvd@7% O2 2.80

NMHC lbs/hr 1.53

Total NMHC Wtd Avg RM on/off, ppmvd@7%O2 2.22 NMHC Wtd Avg RM on/off, tpy 4.10



### Page 2 OrganicHAP 092908.xls

### 9/29/08

Lafarge, Tulsa

Test date 2002

Kiln ID Kiln 2 Kiln type Dry Moisture, fraction 0.1371 Formaldehyde, ppm@7%O2 0.051 Formaldehyde, ppmvd@7%O2 0.04 Formaldehyde, tpy 0.048

Kiln ID Kiln 1 Kiln type Dry Moisture, fraction 0.1292 Formaldehyde, ppm@7%O2 0.027 Formaldehyde, ppmvd@7%O2 0.02 Formaldehyde, tpy 0.028

California PC, Colton

Test date 2002

Kiln ID Kiln 1 Kiln type Dry Moisture, fraction 0.04

%O2 13.43 Formaldehyde, ppmw 1.97 Formaldehyde, ppmvd@7%O2 3.53 Formaldehyde, tpy 4.56 Benzene, ppmvd 0.38 Benzene, ppmvd@7%O2 0.71 Benzene, tpy 2.19 Toluene, ppmvd 0.16 Toluene, ppmvd@7%O2 0.30 Toluene, tpy 1.11

Acetaldehyde, phenol, hexane, ethyl benzene, m,p,o-xylene, styrene y , p
, , y
, , p
, y
, y ND Total organic HAP, ppmvd@7%O2 4.53

California PC, Colton

Test date 2005

Kiln ID Kiln1 Kiln type Dry Moisture, fraction 0.06

%O2 12 Formaldehyde, ppmvw 1 Formaldehyde, ppmvd@7%O2 1.47 Formaldehyde, tpy 2.4 Benzene, ppmvd 0.19 Benzene, ppmvd@7%O2 0.30 Benzene, tpy 1.11 Toluene, ppmvd 0.03 Toluene, ppmvd@7%O2 0.05 Toluene, tpy 0.21

Acetaldehyde, phenol, hexane, ethyl benzene, m,p,o-xylene, styrene ND Total organic HAP, ppmvd@7%O2 1.81



### Page 3 OrganicHAP 092908.xls

### 9/29/08

California PC, Colton

Test date 2005

Kiln ID Kiln 2 Kiln type Dry Moisture, fraction 0.04

%O2 14 Formaldehyde, ppmvw 0.63 Formaldehyde, ppmvd@7%O2 1.22 Formaldehyde, tpy 1.54 Benzene, ppmvd 0.23 Benzene, ppmvd@7%O2 0.46 Benzene, tpy 1.42 Toluene, ppmvd 0.03 Toluene, ppmvd@7%O2 0.06 Toluene, tpy 0.19

Acetaldehyde, phenol, hexane, ethyl benzene, m,p,o-xylene, styrene ND Total organic HAP, ppmvd@7%O2 1.74

Ash Grove, Seattle

Test date 2001

Kiln ID Kiln 1 Kiln type PC

RM On Moisture, fraction 0.132

%O2 9.52 Benzene, ppmvd 0.1 Benzene, ppmvd@7%O2 0.12 Benzene, tpy 0.55 Toluene, ppmvd 0.04 Toluene, ppmvd@7%O2 0.05 Toluene, tpy 0.26 Formaldehyde, ppmvw y , p p 2.3 Formaldehyde, ppmvd@7%O2 2.44 Formaldehyde, tpy 5.63 Ethyl benzene,mp-xlyene, styrene ND

RM Off
Moisture, fraction 0.073

%O2 8.73 Benzene, ppmvd 0.21 Benzene, ppmvd@7%O2 0.24 Toluene, ppmvd 0.08 Toluene, ppmvd@7%O2 0.09 Formaldehyde, ppmvw 5.5 Formaldehyde, ppmvd@7%O2 5.82

Total Benzene, Wtd avg, ppmvd@7%O2 0.13 Toluene, Wtd avg, ppmvd@7%O2 0.05 Formaldehyde, Wtd avg, ppmvd@7%O2 2.78 Total organic HAP, ppmvd@7%O2 2.96



### Page 4 OrganicHAP 092908.xls

### 9/29/08

Ash Grove, Montana City, MT

Test date 2000

Kiln ID Kiln 1 Kiln type Wet %O2 (not reported. Used avg of 3 other wet kilns) 5.86 Benzene, ppmvd 0.06 Benzene, ppmvd@7%O2 0.06 Toluene, phenol, formaldehyde, naphthalene, hexane, ethyl benzene, m,p,o-xylene, styrene ND

Ash Grove, Durkee, OR

Date July 2001

Kiln Kiln Kiln type PC

RM On Moisture, fraction 0.1768

%O2 6.03 Benzene, ppmvd 0.22 Benzene, ppmvd@7%O2 0.21 Toluene,ppmvd 0.1 Toluene,ppmvd@7%O2 0.09 m,p-Xylene, ppmvd 0.27 m,p-Xylene, ppmvd@7%O2 0.25 Styrene, ppmvd 0.26 Styrene, ppmvd@7%O2 0.24 Formaldehyde, ppmvw 20.2 Formaldehyde, ppmvw@7%O2 15.54 Phenol, naphthalene ND Total organic HAP, ppmvd@7%O2 16.34

Ash Grove, Durkee, OR

Date April 2002

Kiln Kiln 1 Kiln type PC

RM On Moisture, fraction 0.116266667

%O2 7.7 Benzene, ppmvd 0.22 Benzene, ppmvd@7%O2 0.23 Toluene, ppmvd 0.1 Toluene, ppmvd@7%O2 0.11 m,p-Xylenes, ppmvd 0.27 m,p-Xylenes, ppmvd@7%O2 0.28 Styrene, ppmvd 0.26 Styrene, ppmvd@7%O2 0.27 Formaldehyde, ppmvw 0.3 Formaldehyde, ppmvd@7%O2 0.28 Naphthalene, ppmvd 0.002 Naphthalene, ppmvd@7%O2 0.002 THC(M25A), ppmvd as propane 3.6 THC, ppmvd@7%O2 3.8

Volumetric flow rate

dscfm 147929

wscfm 167391



### Page 5 OrganicHAP 092908.xls

### 9/29/08

RM Off
Moisture, fraction 0.1368

%O2 5.93 Benzene, ppmvd 0.22 Benzene, ppmvd@7%O2 0.20 Toluene, ppmvd 0.1 Toluene, ppmvd@7%O2 0.09 m,p-Xylenes, ppmvd 0.27 m,p-Xylenes, ppmvd@7%O2 0.25 Styrene, ppmvd 0.26 Styrene, ppmvd@7%O2 0.24 Formaldehyde, ppmvw 0.5 Formaldehyde, ppmvd@7%O2 0.40 Naphthalene, ppmvd 0.008 Naphthalene, ppmvd@7%O2 0.01 THC(M25A), ppmvd as propane 3.3 THC, ppmvd@7%O2 3.1

Volumetric flow rate

dscfm 125600

wscfm 145505

Total Benzene, Wtd avg, ppmvd@7%O2 0.23 Toluene, Wtd avg, ppmvd@7%O2 0.10 m,p-Xylenes, Wtd avg, ppmvd@7%O2 0.28 Styrene, Wtd avg, ppmvd@7%O2 0.27 Formaldehyde, Wtd avg, ppmvd@7%O2 0.29 Naphthalene, Wtd avg, ppmvd@7%O2 0.002 Total organic HAP, ppmvd@7%O2 1.18 THC, ppmvd@7%O2 3.72 31.7 HAP% of THC

Ash Grove, Louisville, NE

Date 2005

Kiln Kiln 2 Kiln type PC tpy Benzene,g/sec, baseline 0.023 0.7 Benzene, g/sec, TDF 0.021 0.7



### Page 6 OrganicHAP 092908.xls

### 9/29/08

Lafarge, Whitehall,PA

Date March 2006

Kiln Kiln 3 Kiln type PH

%O2 5.3 Total THC as methane, ppmvd 64.9 Total THC as propane, ppmvd@7%O2* 19.28 Benzene, ug/dscm@7%O2 143 Benzene, lb/hr 0.0287 Naphthalene, ug/dscm@7%O2 180 Naphthalene, lb/hr 0.0363 Methyl chloride, lb/hr 0.0355 Methyl bromide, lb/hr 0.0255
Acetone, lb/hr 0.00189 Methyl iodine, lb/hr 0.0112 Phenol, lb/hr 0.0517 2-Methylphenol, lb/hr 0.003 3&4-Methylphenol, lb/hr 0.007 Acetophenone, lb/hr 0.004 2-Methylnaphthalene, lb/hr 0.003 Acenaphthylene, lb/hr 0.002 Dibenzofuran, lb/hr 0.003 Diethyl phthalate, lb/hr 0.0004 Bis(2-ethylhexyl)phthalate, lb/hr 0.003 Benzoic acid, lb/hr 0.015 Total org HAP, lb/hr 0.23 *Converted THC methane to THC propane by dividing by 3.

Lafarge, Whitehall,PA

Date Sept 2006

Kiln Kiln 2 Kiln type PH

%O2 3.8

Total NMHC as Methane [ C ] pp vd To ta l NM HC as M e t hane VO , m 22.9 Total NMHC as Methane [VOC], ppmvd@7%O2 18.7 Total NMHC as Methane [VOC], lb/hr 3.2

Kiln Kiln 3 Kiln type PH

%O2 5.3 Total NMHC as Methane [VOC], ppmvd 11.4 Total NMHC as Methane [VOC], ppmvd@7%O2 10.2 Total NMHC as Methane [VOC], lb/hr 1.2

Lafarge, Seattle

Date June 2000

Kiln Kiln Kiln type Wet Moisture, fraction 0.30

%O2 6.7 Benzene, ug/m3 2417 Benzene, lb/hr 0.726



### Page 7 OrganicHAP 092908.xls

### 9/29/08

Lafarge, Ravena, NY

Date February 2004

Kiln Kiln 1&2, common stack Kiln type Wet

%O2 6.94 Moisture, fraction 0.286 Naphthalene, mg/M3@7%O2 0.0371 Naphthalene,lb/hr 0.0634 2-Methylnaphthalene, mg/M3@7%O2 0.209 2-Methylnaphthalene, lb/hr 0.291 Phenanthrene, mg/M3@7%O2 0.11 Phenanthrene, lb/hr 0.153 Total org HAP, mg/M3@7%O2 0.3561 Total org.HAP, lb/hr 0.5074 Total NMHC, ppmvd 21.82 Total NMHC, lb/hr 55.2 THC, ppmvd as propane 25.4 THC, ppmvd@7%O2 as propane 25.3 THC, lb/hr as propane 55.2 0.9 HAP% of THC

Lafarge, Davenport IA

Date "March 2000

Kiln Kiln 1 Kiln type PC
Moisture, fraction 0.11

%O2 9.8 Benzene, ppmv 0.15 Benzene, ppm@7%O2 0.17 Benzene, ppmvd@7%O2 0.15

Volumetric flow rate, dscfm 271587

Lafarge, Sugar Creek, MO g , g , Date August 2002

Kiln Kiln 3 Kiln type PC RM On (95% of time) tpy Moisture, fraction 0.14 %O2 (not reported, used avg. of 6 PC kilns) 9.2 Benzene, ppmvd 0.5 3.12 Benzene, ppmvd@7%O2 0.59 Toluene, ppmvd 0.34 2.46 Toluene, ppmvd@7%O2 0.40 Ethyl benzene, ppmvd 0.3 2.49 Ethyl benzene, ppmvd@7%O2 0.36 m,p-Xylenes, ppmvd 0.71 5.98 m,p-Xylenes, ppmvd@7%O2 0.84 Styrene, ppmvd 0.46 3.8 Styrene, ppmvd@7%O2 0.55 o-Xylene, ppmvd 0.35 2.95 o-Xylene, ppmvd@7%O2 0.41 Formaldehyde, ppmvw 5.4 14.92 Formaldehyde, ppmvd@7%O2 5.51

Volumetric flow rate, dscfm 122537 Volumetric flow rate, wscfm 141940



### Page 8 OrganicHAP 092908.xls

### 9/29/08

RM Off (5% of time) tpy Moisture, fraction 0.15 %O2 (not reported, used avg of 4 PC kilns) 6.8 Benzene, ppmvd 0.62 0.19 Benzene, ppmvd@7%O2 0.61 Toluene, ppmvd 0.34 0.12 Toluene, ppmvd@7%O2 0.34 Ethyl benzene, ppmvd 0.27 0.11 Ethyl benzene, ppmvd@7%O2 0.27 m,p-Xylenes, ppmvd 3.71 1.54 m,p-Xylenes, ppmvd@7%O2 3.66 Styrene, ppmvd 0.4 0.16 Styrene, ppmvd@7%O2 0.39 o-Xylene, ppmvd 0.3 0.12 o-Xylene, ppmvd@7%O2 0.30 Formaldehyde, ppmvw 8.2 1.13 Formaldehyde, ppmvd@7%O2 6.88

Volumetric flow rate, dscfm 114961 Volumetric flow rate, wscfm 134567

Total tpy Benzene, ppmvd 0.51 3.31 Benzene, ppmvd@7%O2 0.59 Toluene, ppmvd 0.34 2.58 Toluene, ppmvd@7%O2 0.40 Ethyl benzene, ppmvd 0.30 2.6 Ethyl benzene, ppmvd@7%O2 0.35 m,p-Xylenes, ppmvd 0.86 7.52 m,p-Xylenes, ppmvd@7%O2 0.98 Styrene, ppmvd 0.46 3.96 Styrene, ppmvd@7%O2 0.54 o-Xylene, ppmvd 0.35 3.07 o-Xylene, ppmvd@7%O2 0.41 Formaldehyde, ppmvw y , p p 5.54 16.05 Formaldehyde, ppmvd@7%O2 5.57

Total all organic HAP, ppmd@7%O2 8.85 39.09

Lehigh, Leeds, AL

Date April 2002

Kiln 5 Kiln type PH Moisture, fraction 0.1313

%O2 14.65 Formaldehyde, ppmvw 3.52 My calculation Formaldehyde, ppmvd (reported)?? 4.05 3.06 Formaldehyde, ppmvd@7%O2 9.0 6.8 Formaldehyde, lb/hr 3.66

Volumetric flow rate, dscfm 194295 Volumetric flow rate, ascfm 298076



### Page 9 OrganicHAP 092908.xls

### 9/29/08

Ash Grove, Inkom, ID

Date Sept/Oct 2000

Kiln Kiln 1 Kiln type Wet Moisture, fraction 0.3308

%O2 3.95 tpy Benzene, ppmvd 0.2 0.26 Benzene, ppmvd@7%O2 0.16 Toluene, ppmvd 0.18 0.27 Toluene, ppmvd@7%O2 0.15Formaldehyde phenol, naphthalene, hexane, ethyl benzene, m,p,oxylene, styrene ND Total organic HAP, ppmvd@7%O2 0.31

Volumetric flow rate, dscfm 24604 Volumetric flow rate, wscfm 36777

HAP MW

Formaldehyde 30

Benzene 78

Toluene 92 m,p-Xylene 106 Styrene 104 o-Xylene 106

Hexane 86

Phenol 94



### Page 10 OrganicHAP 092908.xls