Center for

Radiation

Research

J -QC

100

.1156

# 86-3441

1986

October 1986

U.S. DEPARTMENT OF COMMERCE

National Bureau of Standards

NBSIR 86-3441

NBS

RESEARCH

INFORMATION CENTER

UUO 1 JO

Center for

Radiation

Research

Chris E. Kuyatt, Director

U.S. DEPARTMENT OF COMMERCE

National Bureau of Standards

National Measurement Laboratory Center for Analytical Chemistry

Gaithersburg, MD 20899

October 1986

U.S. DEPARTMENT OF COMMERCE, Malcolm Baldrige, Secretary

National Bureau of Standards, Ernest Ambler, Director

ABSTRACT

This report summarizes research projects, measurement method development,

calibration and testing, and data evaluation activities that were carried

out during Fiscal Year 1986 in the NBS Center for Radiation Research.

These activities fall in the areas of atomic and plasma radiation,

radiation physics, radiometric physics, radiation sources and

instrumentation, ionizing radiation, and nuclear physics.

Key Words: Atomic radiation, ionizing radiation; measurement support;

nuclear radiation; plasma radiation; radiation

instrumentation, radiation measurements; radiation physics,

radiation sources; radiometric physics.

i
INTRODUCTION

This report is a summary of the technical activities of the NBS

Center for Radiation Research (CRR) for the period October 1, 1985 to

September 30, 1986. The Center is one of four Centers in the National

Measurement Laooratory.

The Center for Radiation Research develops and maintains the

scientific competences and experimental facilities necessary to provide

the Nation with a central basis for uniform physical measurements,

measurement methodology, and measurement services in the areas of near infra-red radiation, optical (visible) radiation, ultraviolet radiation,

and ionizing radiation (x rays, gamma rays, electrons, neutrons,

radi oacti vity , etc.); provides government, industry, and the academic

community with essential calibrations for field radiation measurements

needed in such applied areas as nuclear power, lighting, solar

measurements, aerospace, defense, color and appearance, health care,

radiation processing, advanced laser development, and radiation protection

for public safety; carries out research in order to develop improved

radiation standards, new radiation measurement technology, and improved

understanding of atomic, molecular, and ionizing radiation processes, and

to elucidate the interaction of radiation and particles (electrons,

neutrons, and ions) with inanimate and biological materials; collects,

compiles, critically evaluates, and supplements the existing atomic,

molecular, and ionizing radiation data bases in order to meet the major

demands of the Nation for such data; and participates in col 1 aborst’ ve efforts with other NBS centers in the interdisciplinary applications of

radi ati on.

The summary of activities is organized into six parts, one for each

of the five Divisions in the Center: Atomic and Plasma Radiation,

Radiation Physics, Radiometric Physics, Radiation Sources and

Instrumentation, and Ionizing Radiation, and one for the Nuclear Physics

Group. A major subgroup of the Ionizing Radiation Division is the Office

of Radiation Measurement. Each organizational unit tells its own story in

its own way. In general there is an introduction followed by a series of

short reports on current activities, publications during the year, talks

given, committee participation, and professional interactions.

A detailed table of contents has been provided to permit the reader

to find those activities of greatest interest. To obtain more information

about particular work, the reader should address the individual scientists

or their division, c/o Center for Radiation Research, Radiation Physics

Building, C229, National Bureau of Standards, Gaithersburg, MD 20899.
Table of Contents

ABSTRACT i

INTRODUCTION ii

CRR ORGANIZATION CHART vii

ATOMIC AND PLASMA RADIATION - Division 531 1

Atomic Spectroscopy Group 3

Atomic Radiation Data Group 6

Plasma Radiation Group 9

Invited Talks 14

Publications 15

Publications in Preparation 20

Technical & Professional Committee Participation & Leadership .... 23

Major Consulting and Advisory Services 25

Journal Editorships 27

Trips Sponsored by Others 28

Calibration Services Performed 29

Sponsored Seminars and Colloquia 30

RADIATION PHYSICS - Division 533 33

Far Ultraviolet Physics Group 36

Electron Physics Group 42

Photon Physics Group 48

Sponsored Workshops, Conferences, and Symposia 57

Invited Talks 58

Publications 63

Publications in Preparation 67
Technical & Professional Committee Participation & Leadership .... 7U

Major Consulting and Advisory Services 73

Journal Editorships 75

Trips Sponsored by Others « . „ ... . „ . . „ . . . ... 76

Calibration Services Performed 79

Sponsored Seminars and Colloquia 90

RADIOMETRIC PHYSICS - Division 534 83

Spectroradi ometry and Optical Pyromet ry Group 87

Spectrophotometry Group 89

Photodetector Physics and Metrology Group 94

Radiometric Measurement Services Group 97

Invited Talks 101

Publications 102

Publications in Preparation 104

Technical & Professional Committee Participation & Leadership ... 106

Journal Editorships 109

Standards Committee Meetings 110

Standards Writing Ill

Major Consulting and Advisory Services 112

Standard Reference Materials 113

Measurement Assurance Services lib

Calibration Services Performed lib

Trips Sponsored by Others 11 ;

Sponsored Seminars and Colloquia 113

i v
RADIATION SOURCE AND INSTRUMENTATION - Division 535 119

CW Accelerator Research (Microtron) 119

Linac Operations 146

Instrumentation Services ... . .... 148

Radiation Instrumentation Standards 151

Invited Talks 154

Publications 155

Publications in Preparation 156

Technical & Professional Committee Participation & Leadership .... 157

Major Consulting and Advisory Services 160

Sponsored Seminars and Colloquia 161

IONIZING RADIATION DIVISION - Division 536 163

Office of Radiation Measurement 164

Radiation Theory Group 173

Radiation Chemistry & Chemical Dosimetry Group 177

Neutron Mesurements & Research Group 183

Neutron Dosimetry Group 196

Radioactivity Group 206

X-Ray Physics Group 214

Dosimetry Group 218

Sponsored Workshops, Conferences, and Symposia 224

Invited Talks 225

Publications 231

Publications in Preparation 238

Technical & Professional Committee Participation & Leadership 244

Major Consulting and Advisory Services 254

v
Journal Editorships 263

Trips Sponsored by Others 264

Standard Reference Materials 268

Calibration Services Performed 269

Sponsored Seminars and Colloquia 273

NUCLEAR PHYSICS GROUP - 530.1 275

Sponsored Workshops, Conferences, and Symposia 287

Invited Talks 288

Publications 291

Publications in Preparation 293

Technical & Professional Committee Participation & Leadership 294

Trips Sponsored by Others 296

Sponsored Seminars and Colloquia 298

LIST OF ACRONYMS 299

vi
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TECHNICAL ACTIVITIES

Division 531, Atomic and Plasma Radiation

The Atomic and Plasma Radiation Division carries out a broad range

of experimental and theoretical research on atomic structure and atomic

radiation in plasmas. The division determines a large variety of atomic

radiation and collision data, encompassing wavelengths of spectral lines;

atomic energy levels; ionization potentials; atomic transition probabilities; plasma line broadening parameters; ionization and excitation cross sections and rate coefficients, and dielectronic rate coefficients. Two

data centers located in the division critically evaluate and compile

atomic energy levels and transition probabilities. The division is also

engaged in research on the interaction of atomic radiation with plasma

environments, and it explores such effects for the development of new measurement techniques. Furthermore, well-defined atomic radiation

sources are developed as VUV radiometric standards or wavelength standards.

These activities support several areas of science and technology.

A good deal of our work ties into magnetic fusion research, where atomic

data are needed for studies of the effects of heavy ion impurities and

where atomic radiation processes are utilized as non-interfering plasma

probes. Other areas of direct applications are parts of the Strategic

Defense Initiative (SDI), vacuum ultraviolet and x-ray laser development,

and space astronomy and solar physics. In all these areas, atomic

radiation data are one of the basic ingredients, and plasma measurement

techniques utilizing the emitted radiation are applied. Our vacuum ultraviolet radiometry work is now providing small calibrated radiation

source packages to allow radiometric calibrations on board spacecraft,

which are used, for example, on the space shuttle for accurate monitoring

of the solar ultraviolet radiation, and are part of the space telescope

i nstrumentati on

.

The division consists of three technical groups: Atomic Spectroscopy, Atomic Radiation Data, and the Plasma Radiation Groups. The

division currently has 17 professional physicists, among them 15 Ph.D.s,

plus 1 IPA. During 1986 the division has had 11 guest scientists from

China (3), Israel (2), France (2), India (1), Soviet Union (1), and

Yugosl avia ( 1)

.

Some of our significant accomplishments during the past year are:

a Measurements and identifications of spectral lines from very

highly ionized atoms to obtain reference wavelengths for x-ray

laser research and test calculated Lamb shifts.

1
Division 531, Technical Activities (cont'd.)

o Critical evaluation of experimental and theoretical results

available for helium lsn£ level systems to obtain accurate

ionization energies and confirm two-el ectron quantumel ectrodynami c energy contri outi ons

.

o Calculations of electron impact excitation cross sections for

very highly ionized atoms based on a fully relativistic

formulation of the problem.

o Development and numerical study of upper and lower bound

procedures for theoretical atomic oscillator strengths.

o Measurement of population inversion in C 3+ in a theta pinch

pi asma.

o Characterization of 1 aser-produced plasmas as irradiance source

for the XUV region.

These and other activities are discussed in the following sections, where

the principal work of the three technical groups during the past year is

described.

2
Division 531, Technical Activities (cont'd.)

I . Atomic Spectroscopy Group

( a ) Highly Ion i z ed Atoms

The wavelengths and energy levels for spectra of highly ionized

atoms are necessary for diagnostics of high-temperature plasmas (tokamak

plasmas, etc.) and for x-ray laser research. These spectra are also of

basic interest for testing atomic calculations including large relativistic and quantum-field (QED) contributions. We have excited very highly

charged ions in 1 aser-produced plasmas using the 24-beam OMEGA laser at

the University of Rochester. The charge states identified in our most

recent spectra range from Au 49+ to U65+

, the latter spectrum extending

the Co i soel ect ronic sequence to the heaviest of the naturally occurring

elements. Lines of Fe-like, Cu-like, and Zn-like ions were also identified (0.9 to 11 nm). Comparisons of measured wavelengths in the Cu-like

spectra with relativistic calculations confirm QED contributions for the

4s-4p transitions, but significant differences remain between calculated

and observed values (J. Reader and collaborators from the Naval Research

Lab.)

.

Other high-ionization spectra obtained with the OMEGA facility

which we have analyzed include F-like ions (Zr 31+ to Sn 41 +

), 0-like ions

(y3l+ _ Nb 33+

), and the Br ions Br 24+ and Br28 + - Br 30+ .

We have given high priority to completing our measurements of

spectra for the Na-like ions of elements through Sn because these wavelengths are being used as standards in the work on Ne-like ionic x-ray

lasers at Livermore. Using i soel ectroni c smoothing of the data we are obtaining wavelengths for the Na sequence in the region 5-30 nm accurate

to about ±0.0007 nm. We plan to use similar procedures in deriving wavelengths from our data for the Co and Fe i soel ectroni c sequences (elements

Kr to U, wavelengths 1 to 10 nm) . (J. Reader, et al .

)

We are exciting and analyzing spectra of ions of the elements Cu

to Mo stripped to the n=3 shell. Both allowed (electric dipole) and forbidden (magnetic dipole) lines are being studied. These spectra are important for tokamak diagnostics as well as x-ray laser studies, and the

wavelengths in some cases will also be useful for VUV standards. We have

measured and analyzed the n=3-3 transitions in Cu 11+ through Cu 20+ and

Zn 11+ through Zn 18+

, and are working on similar ion stages for Ga, Ge, and

As. We plan to extend this work from Se to Mo (Z=34-41) using the Texas

tokamak (TEXT) as the radiation source. (V. Kaufman and J. Sugar).

The Ne i soel ectroni c sequence has special interest in that soft

x-ray laser lines have been demonstrated in Ne-like selenium. We extendea

our research on this sequence to obtain the energy level structures for

3
Division 531, Technical Activities (cont'd.)

Ca 10+ through Fe 16+

, and we probably will eventually add Co 17+ and Ni 18+

using the NBS laser (Kaufman, Sugar, and a Swedish collaborator,

u. Litz$n)

.

(b) Wavelength Standards (5 to 330 nm)

We completed our measurements of the spectrum of a platinum

hollow-cathode discharge for the VUV and UV region 110-330 nm. We are now combining these results with measurements at longer wavelengths to optimize the energy levels and derive Ri tz-pri nci pi e wavelengths. The values

for almost 3000 lines having uncertainties of ±0.0001 to ±0.0003 nm will

be used for on-board calibration of the High-Resolution Spectrograph for

the Space Telescope and also for hi gh-accuracy laboratory spectroscopy.

Our just-published measurements of 900 Y 5+ lines include

accurate Ritz-type wavelengths for 225 lines in the XUV region 18-40 nm. Together with our previous Y 3+ determinations and our Y 4+ work still in

progress, these wavelengths comprise a system of yttrium standards for the

range 18-70 nm.

At a lower accuracy level, our ongoing measurements of lines in

the spectra of Fe ions, Fe 15+ to Fe 19+

, are being used for standards in

the 5-13 nm region (uncertainties ~±0.0005 nm). Use of our wavelengths

now being obtained for the Na i soel ectroni c sequence as standards was noted above (J. Reader and N. Acquista).

( c) Ionization of Lithium Vapor by CW Quasi resonant Laser Radiation

In the course of assembling apparatus for observation of Rydberg

states of atomic Li, we noted that laser radiation tuned to the 2p-3d

transition of Li was strongly absorbed in the vapor despite the fact that

the 2p state is not thermally populated. Further observation showed that

the absorption was accompanied by strong fluorescence and ion production.

Similar effects have been observed in Na and Cs in other laboratories, but

for these species the effect was produced only for broadband laser pumping. In Li the absorption was very strong for single frequency radiation.

By making a systematic study of the dependence of the vapor transparency , ion production, and fluorescence spectrum on vapor density, laser power,

and laser tuning, we were able to determine the hybrid molecular/atomic

processes by which the absorption proceeds. In a sequence of steps

including a molecular absorption, atomic/molecular excitation transfer, a saturated atomic absorption, and an atomic energy-pool i ng collision the

vapor reaches an equilibrium condition in which there is a high density of

hot 2p and 3d atoms. From this state ions can be produced by direct

photoionization or associative ionization. (C. J. Sansonetti and

D. Veza)

4
Division 531, Technical Activities (cont'd.)

(d) Energy Levels, Ionization Energy, and Lamb Shifts in Helium

High-accuracy wavelength measurements in helium are of fundamental interest for testing relativistic and QED (quantum electrodynamic)

contributions to energy levels of this basic two-electron system. We have

combined experimental energy-level determinations with theoretical calculations to derive a new value for the ionization energy of 4 He I accurate

to ±12 MHz with respect to the ls2s 3 S level. The entire lsnji level

system is determined with relative accuracies of 10-20 MHz except for a few low levels. Values for the Lamb shifts of lsns and lsnp levels

yielded by the data give the first confirmation of predicted two-electron

QED contributions and reveal large errors in available Lamb-shift calculations for lsns terms (n=3-5). Improvement of these results to accuracies

of 1 to 3 MHz will allow much more rigorous tests of two-electron QED

energies, and also test rel ati vi sti c-recoil shifts, nuclear-size effects,

and higher-order QED contributions that have never been confirmed (some

have not yet been calculated). These accuracies can be achieved with

laser spectroscopy and an atomic-beam source. We expect to carry out the

needed wavelength measurements as the first use of a new atomic-beam

source now being designed. (W. C. Martin, C. Cromer, C. J. Sansonetti)

(e) Atomic Energy Levels Data Center

Our new energy-level compilations for the 235 spectra of the

i ron-group elements potassium through through nickel ( Z= 19-28 ) were

published in a one-volume supplement to the J. Phys. Chem. Ref. Data.

( J. Sugar and C. Corl iss)

We completed and published the most extensive compilation of

data for (forbidden) magnetic-dipole transitions ever carried out. The

data include 1660 predicted wavelengths and transition probabilities

(10 nm to 26 mm) for atoms and ions of the elements beryllium through

molybdenum. These tables will be used extensively for diagnostics and

analysis of radiation from laboratory (tokamak, etc.) and astrophysi cal

plasmas. (V. Kaufman and J. Sugar)

We have completed critical evaluation and compilation of the

energy-level data for more than half of the 42 spectra of molybdenum, an element of special interest for tokamak-di scharge diagnostics.

(J. Sugar). A separate compilation giving wavelengths and energy-levels

classifications for the spectra of Mo 5+ through Mo 41+ is almost ready for

submission for publication. We also collaborated with the Japanese group

on a similar compilation for spectra of the nickel ions Ni 8+ through Ni 27+

(manuscript in preparati on) . (J. Sugar and Japanese collaborators)

5
Division 531, Technical Activities (cont'd.)

We are critically reviewing and compiling data on energy levels

for the spectra of sulfur and chlorine. The results of new calculations,

theoretical interpretations, and measurements stimulated by our reviews

are being included in these compilations. (W. C. Martin, R. Zaiuoas,

A. Robey)

We monitor the literature on atomic energy levels, wavelengths,

wavefunctions , etc., and the resulting reference files and published

bibliographies are used by a wide clientele. We plan a fourth supplement

to our 3i bl i og r aphy on Atomic Energy Levels and Spectra, covering the

period from January 1984 through December 1987. (A. Robey, R. Zalubas)

1 1 . Atomic Radiation Data Group

The work of this group is entirely theoretical and consists of two

major areas: (1) theoretical studies of atomic structure and processes,

and (2) critical evaluation and compilation of atomic transition probability and spectral line shape data. The first activity involves the

development of advanced theoretical methods and their implementation to

calculate atomic data. The main areas of activity have been dielectronic

recombination, relativistic quantum mechanics, electron correlation, and

radiative and collisional transition rates. The critical evaluation and

compilation of transition probability and spectral line shape data takes

place in the Data Center on Atomic Transition Probabilities, which also

maintains an up-to-date bibliography of the literature in these fields.

(a) Theoretical Studies

The comprehensive dielectronic recombination computer codes have

been used to calculate total recombination rates for highly stripped ions

in a hot plasma. Work has been completed on selected ions in the lithium,

fluorine and oxygen i soel ect roni c sequences, and papers describing this

research have been submitted for publication. In addition to the data for

the ions actually computed, these studies also include empirically derived

formulas for interpolating recombination rate data for other ions of these

sequences. The influence of the metastable excited states of the ground

configuration on the dielectronic process has also been studied for the

ions Fe XX, Fe XIX, and Fe XVIII. In addition, we are now wrapping up our studies of dielectronic satellites in lithium-like ions.

Currently, these codes are being revised and expanded to include

the effects of intermediate coupling and configuration interaction in the

target ion, dielectronic states and final states. We have also developed

exact analytic expressions for matrix elements when the core wave function

6
Division 531, Technical Activities (cont'd.)

is represented analytically, and the continuum and Rydberg orbitals are

well represented by a hydrogenic approximation. This development, which

allows the rapid computation of radiative and autoionization rates, has

also been incorporated into the programs. (L. J. Roszman)

Our relativistic distorted wave programs for computing electron

impact excitation cross sections are now operational and have begun to

produce results for excitations in ions with alkali -like configurations.

These codes are fully relativistic in that they represent all electrons by

four-component Dirac spinors, both the scattering electron as well as those in the target ion, for which the wave function is normally a correlated, relativistic wave function. For the high incident energies encountered in the highly ionized ion regime, it has been necessary to go to a very large number of partial waves in the distorted wave expansion, and

then to extrapolate the remainder by connecting with the plane-wave Born

approximation, and a great deal of our efforts were devoted to implementing this procedure. It is expected that, for very highly charged ions,

relativistic effects should be important, not only for the target ion, but

also for the scattering electron; results obtained for Xe 51+ show significant departures from the nonrel ati vi Stic calculation, particularly in the

2s > 2p 1/2 , 2p 3/2 excitations. (Y.-K. Kim)

We have also intensively examined the problem of theoreti cal 1 y

bounding quantum mechanical matrix elements, in particular as a means of

establishing upper and lower bounds for theoretical oscillator strengths.

A number of theorems have been proved and a variety of bounding procedures

developed, and we have begun to apply them in test calculations on a mul ti -el ect ron atom. For this purpose we have selected the lithium atom

resonance transition using the Hartree-Fock approximation, which is known

to produce fairly accurate results for this transition. The point is to

test the bounding procedures, to explore their limitations and strengths,

and to determine which is likely to be the most useful. We have also done

accurate correlation calculations to provide a standard and information on what will contribute most to improving the f-value and its bounds. Our

work to date has yielded a total error width of 10%, with the lower bound

much closer than the upper bound. (A. W. Weiss and D. Roginsky)

The studies of 3d- s hel 1 collapse have led us to a series of

calculations on the 3p 5 3d states of the argon i soel ect roni c sequence,

probably the simplest example where strong state-dependent shell collapse

effects occur. While our treatment of correlation is somewhat limited, it

is far more extensive than is usually done for such a system. We find

that it is essential to include not only 3p-3d and 3s-3d correlation, but

also, unfortunately, 3p-3p and 3s-3p correlations which are strongly state

dependent due to the possibility of excitations into the term-dependent

7
Division 531, Technical Activities (cont'd.)

and collapsing 3d shell. As of this writing, there are ambiguities in our results which are not yet fully understood. (A. W. Weiss)

During the past year, we hosted a number of atomic theorists,

some for an extended period of time, and some as regular weekly visitors.

P. M. Mohr (NSF) spends one day a week with us working with

Y.-K. Kim on computational aspects of QED problems. They have recently

completed a set of calculations of the Lamb shift for n=3 levels of

hydrogen-like ions, and they now believe they are beginning to see the

pattern of QED corrections for highly charged hydrogen-like ions as a function of principal quantum number.

M. A. A1 i (Howard Univ.) also spends one day a week here,

working with Dr. Kim on relativistic atomic structure calculations for

heavy and highly charged ions.

J. P. Desclaux (Grenoble) spent the month of May with us again

this year, working with Dr. Kim on relativistic continuum electron codes.

These programs were the ones used for the relativistic scattering calculations described above. Dr. Desclaux' s visit was partially supported by a NATO research grant.

U. I. Safronova (USSR) also visited us for one month in November

1986. She consulted extensively, and intensively with Drs. Kim and Weiss

on the relativistic correlation problem, as well as with a number of the

members of the spectroscopy group.

D. V. I. Roginsky (Israel) has spent the entire year with us studying the problem of bounding theoretical oscillator strengths. He has

worked closely with A. W. Weiss on this problem, a collaboration which has

proved mutually stimulating.

L. Woltz (Florida) has also been with us over the past year,

collaborating with L. Roszman and W. L. Wiese on problems in the theory of

spectral line broadening.

(b) Data Center on Atomic Transition Probabililty

Critical evaluations and tabulations of atomic transition

probability data for the iron group elements, scandium through nickel, has

continued. The research activity in this field is very strong, propelled

by the interests of two user communities, namely the astrophysicists and

the fusion community. This has meant that new and revised data are

8
Division 531, Technical Activities (cont'd.)

continually becoming available, and we attempt to include this material to

the greatest extent possible, revising and adding to existing data tables.

This influx of new data has slowed the pace of our work somewhat, although

we feel that we are making steady progress. During the past year, we have

completed the evaluation of both allowed and forbidden lines for all ions

i soel ectronic with sulfur, phosphorus, silicon, aluminum, and magnesium.

Tabulations of the forbidden lines of neutral and low ionization stages of

all the elements. Sc through Ni , have been completed, as have the

forbidden lines of ions in the oxygen, fluorine and neon sequences.

We continually monitor the literature, maintaining an up-to-date

bibliography on site. Also, we continue to supply, in regular intervals,

bibliographical reference material for inclusion in the "International

Bulletin on Atomic and Molecular Data for Fusion," published by the International Atomic Energy Agency. Our input is their principal, and often

only, source of spectroscopic references. We are currently learning how

to utilize an IBM PC for data evaluation applications as well as for

bibliographic purposes.

III. Plasma Radiation Group

Our plasma measurements program provides valuable data and measurement techniques for fusion diagnostics, plasma densities, VUV radiometry,

and VUV lasing schemes. The activity in collisional rate coefficients is

of critical importance in plasma modeling, especially fusion-type plasmas

and VUV laser schemes. The research on line shapes and scattering has

impact on gain measurements in lasing media as well as fundamental

measurements of plasma densities. Our portable radiometric standards have

been used for many spacecraft calibrations and are still in demand for

that purpose.

(a) Collisional Rate Coefficients with the 50 kJ Theta Pinch

Ti 9+ relative excitation rate measurements were accomplished

from experiments on the NBS 50k J theta pinch. These results were compared

with distorted wave calculations, and agreement between experiment and

theory was found within combined uncertainties. A procedure to account

for opacity in certain Ti 9+ transitions was also applied. These rates

will be used in plasma modeling where titanium is an impurity from e.g.

walls or limiters. (R. Datla, J. Roberts)

Experimental conditions were investigated to observe a recom- bination phase of the theta pinch plasma. An electron density of 3 x 10 16

and an electron temperature from 20-30 eV was generated in a C

2 H2 plasma.

The recombination into C3+ showed a population inversion in the n=4 levels

9
Division 531, Technical Activities (cont'd.)

compared with the n=3 levels. The population ratio of the 4f/3d was measured to be 4.5 which would be sufficient to give a substantial laser

gain in the 1165 A C 3+ transition for our 28 cm long plasma. Further

investigation indicated the ion temperature to be approximately 1 keV from

Doppler line widths. Thus the effective gain in the 1165 A transition is

substantially reduced because of its Doppler width of 1-2 A. Further

investigations with different theta pinch configurations maintaining this

inversion ratio are hoped to bring the ion temperature down so the gain

per unit length is sufficient to make this an attractive lasing medium.

If successful this will provide valuable data on VUV lasing methods using sources such as a theta pinch. (R. Datla, J. Roberts)

(b) Tokamak Spectroscopy

More than 35 spectral lines from magnetic dipole (M 1) transitions were reported from observation of the Texas Experimental Tokamak

(TEXT). About a third of these were in the air portion of the spectrum

above 2000 A, making them easily observable and usable for experiments

on ion temperature measurement and ion transport studies in tokamaks.

(J. Roberts, R. Datla, T. Pittman, J. Sugar, V. Kaufman)

First time ever measurements of absolute excitation rate co- efficients in highly ionized elements have been reported using the TEXT

tokamak. Based on the absolute radi omet ri cal ly calibrated measurements of

emission spectral lines, both M 1 and the electric dipole lines of interest, Cl -like and Al-like Fe, Ni , Cu, and Zn excitation rates were measured. Many of the previously measured M 1 lines permitted the absolute

number density of the ion ground state to be measured. SURF II and

branching ratio calibrated spectrometers in the XUV and VUV spectral

region down to 150 A were used to measure the absolute spectral line intensities. Combining these two critical measurements yielded the absolute

excitation rate coefficient measurement. (R. Datla, J. Roberts)

( c) Autoionization in Electric Fields

We have observed the effects of d.c. electric fields on highly

excited levels of Ba and Gd. The "Rydberg manifold," or fanning out of

levels as the field increases, is quite different than previously observed. In a detailed theoretical treatment we showed that this difference arises from the anisotropic character of the ionic core of the douoly

excited atom. This gives rise to many additional fine structure components where presence gives rise to quite complex spectra, particularly in

the presence of electric fields.

10
Division 531, Technical Activities (cont'd.)

In a recently submitted manuscript we present an algorithm for

computing the complex manifold structure in "jK coupling," and obtain

excellent agreement with our experimental spectra. (D. Kelleher)

(d) Calculation of Spectral Line Shapes for Ions in Plasmas

We have recently completed a calculation of the colli si onal

broadening of the Balmer alpha (n=3->2) lines of C 5+ in a plasma. The

alpha line is the lasing transition (183 A) of interest in x-ray laser

schemes being investigated at Princeton and also at Livermore. Above a certain electron density, the col 1 i sional broadening will become large

enough to quench the lasing. It is critical in laser design to have a reliable estimate of this density (the beta transition, n=4+2, can be used

to estimate the experimental density). Our theoretical method utilizes a numerical simulation to derive the time dependent fields of the perturbing

ions, and an analytic approach to determine the subsequent line shape. We are in the process of generalizing the method to include fine structure so that it can be applied to transitions in the entire region from degenerate

to isolated levels. This work is supported by the Air Force Office of

Scientific Research. In collaboration with J. Cooper of JILA, we are also

developing an entirely analytic theory, which approximates the strong

collisions by a nearest neighbor model. (D. Kelleher, D. Oza)

(e) Vacuum Ultraviolet Radiometry with Plasmas

Previous to this year we calibrated the irradiance of the Space

Telescope Optical Simulator (STOS), which was then used to calibrate the

Faint Object Spectrograph (FOS), one of the instruments on the Space

Telescope. Upon completion of calibration, the FOS and the other

instruments were incorporated into the Space Telescope, which is to be

deployed in orbit by the Space Shuttle. In the past year we performed

fourteen calibrations of three Pt-Cr-Ne and five Pt-Ne hollow cathode

lamps which were then used in preflight throughput tests of the Space

Telescope with its installed instruments. In addition to the FOS, the

instruments are the high resolution spectrograph, the wide-field planetary

camera, the faint object camera, and the high speed photometer. The

recently completed throughput tests were highly successful and even more

useful than projected. As a result, we are now beginning preparations for

a post-throughput test calibration of the hollow cathode lamp. (J. Klose,

M. Bridges)

tion of

carri ed

program

Another major project of the past year

our calibration services. An exhaustive

out to put on record a detailed descripti

in the vacuum ultraviolet. (J. Klose, M.

has been the documentatreatment has been

on of our calibration

Bridges)

11
Division 531, Technical Activities (cont'd.)

Work is also continuing with laser-produced plasmas as sources

of irradiance in the far UV region. This effort is directed toward development of a standard irradiance source in the spectral region which would

be available to anyone with access to a pulsed laser of modest energy.

Both Nd:YAG and ruby lasers have been used. Observations completed so far

include quantitative high resolution spectra from different target materials in order to identify those giving a most suitable spectral output,

i.e. a sufficiently intense continuum relatively free of lines over some

spectral range. Present efforts involve measuring the spectral irradiance

dependence on laser energy, quality of laser focus on the target, and beam

quality of the laser. This characterization of the source determines the

irradiance for a given setup, i.e. laser, target material and geometry,

and focussing optics. To measure the irradiance on an absolute basis, a spectrometer was calibrated at SURF. Measurements with this instrument

are being made to calibrate the irradiance from the 1 aser-produced plasma

sources. (M. Bridges)

( f ) Stark Broadened Widths and Shifts of Non-hydrogeni c Ion Lines

Vie have completed the experiments observing the Stark broadening

of spectral lines in the noble gases. Spectral lines from both the first

and second ionization stages of Ne, Ar, Kr, and Xe were observed in this

study. We found that irregularities in the trend along the homologous

sequence of these gases can occur when there exist perturbing level (s) near the upper or lower energy level of the emitting ion. Nearby perturbing levels can cause additional broadening of some lines and must be con- sidered when interpolating new data along a sequence.

Vie also measured the broadening of spectral lines from states of

high orbital angular momentum in singly ionized nitrogen. The measurements were compared with two theories having different approaches in

treating the form of coupling in the atomic structure of these lines. Our

results could not definitively determine which approach was more suitable

and concluded that additional theoretical work was necessary.

A He-Ne laser quadrature i nterf erometer was used to determine

the electron densities in the above studies. The temperature was determined using a Boltzmann plot of relative intensities of 0 II impurity

1 i nes.

At this time we are conducting new experiments observing the

width and shift of lithium-like beryllium ion lines. We have demonstrated

the feasibility of introducing beryllium into a helium plasma using a laser ablation technique. Studies determining the plasma equilibrium and

distribution of beryllium in the discharge have begun. We have made preliminary measurements of Be + spectral line profiles and have encountered

12
Division 531, Technical Activities (cont'd.)

some unexpected results. Hydrogen-like line profiles were not always

observed. For instance, the 3p 2 P° - 4d 2 D Be+ transition showed a line

p

r‘O f ile that was strongly asymmetric and included a feature in the line

wing resembling a forbidden component line. Detailed study of these lines

will continue using a more advanced multichannel detector. This work in

ionized beryllium is a natural step progressing from our earlier work on the width and shift of ionized helium lines. (T. Pittman)

(g) Rayleigh Scattering and Near Resonance Fluorescence

Experimental results have been accomplished using the near resonance Rayleigh scattering (NRRS) technique. The NRRS technique

involved the generation of a plasma column in a Ba vapor heat pipe with

the resonant ionization processes using a flashlamp pumped laser called

the pump laser. Simultaneously and colli nearly a Nd:YAG principal dye

laser (probe laser) tuned near the Ba + resonance lines at 553.6 nm is used

for the scattering measurements. The probe laser beam is substantially

smaller in diameter than the pump laser. Thus the right angle scattered

radiation must traverse the plasma before detection and may suffer from

radiation trapping. The first experiment investigated this opacity

problem and provided a simple solution to ensure opacity effects do not

contribute to the interpretation of the observed signal. The second

experiment measured the temporal and spatial evolution of the absolute

density of Ba + in the plasma column. The results of this experiment show

a substantial difference between these local temporally resolved measurements and the line integrated measurements of previously investigations.

The third experiment measured the depolarization of the NRRS signal as a function of detuning of the probe laser over the Ba + resonance transition.

Comparison of the measurements with theory showed very good agreement.

(A. Nee, G. Chen)

13
INVITED TALKS

Division 531, Atomic and Plasma Radiation

Kelieher, D. H., “Electric Field Effects on Structure in the Continuum,"

Conference on Photon and Continuum States of Atoms and Molecules, Cortina,

Italy, June 16-20, 1986.

Kim, Yong-Ki , "Relativistic Effects in Atoms and Molecules," Chemistry

Department Colloquium, Howard University, Washington, DC, February 14,

1986.

Kim, Yong-Ki, "Energy and Angular Distributions of Secondary Electrons,"

Physi kal i sches Institut der Universitat Tubingen, West Germany, June 13,

1986.

Kim, Yong-Ki, "Relativistic Effects in Electron-Atom Collisions," Symposium on Relativistic Many-Body Problems, Trieste, Italy, July 3, 1986.

Kim, Yong-Ki, "Relativistic Effects in Electron-Ion Excitations," Joint

Workshop of U.S. -Japan Fusion Collaboration Program, Institute of Plasma

Physics, Nagoya University, Nagoya, Japan, September 2, 1986.

Martin, W. C., "Research on Atomic Spectroscopy at NBS," Symposium on Atomic Spectroscopy , Lund University, Sweden, November 4, 1986.

Sansonetti , C. J., Classical Methods for Precision Wavelength Metrology,"

NBS Staff Research Seminar, December 4, 1985.

Sugar, Jack, "Critical Compilation of Atomic Energy Levels and Transition

Probabilities," Colloquium on Atomic Spectra and Oscillator Strengths for

Astrophysics and Fusion Research, Toledo, Ohio, August 11, 1986.

Wiese, W. L., "Improvements in Atomic Transition Probability Data,"

Working Group on Atomic Transition Probabilities, General Assembly of the

International Astronomical Union, New Delhi, India, November 1985.

Wiese, W. L., "The Determination of Atomic Transition Probabi 1 i ti es--A

Continuing Challenge," Harvard College Observatory, May 12, 1986.

Wiese, W. L., "Ion Broadening of Heavy Element Lines in Plasmas," 8th

International Conference on Spectral Line Shapes, Williamsburg, Virginia,

June 9, 1986.

Wiese, W. L., "Atomic Transition Probabi 1 iti es--Some Continuing

Challenges," Colloquium on Atomic Spectra and Oscillator Strengths for

Astrophysics and Fusion Research, Toledo, Ohio, August 11, 1986.

14
PUBLICATIONS

Division 531, Atomic and Plasma Radiation

Adelman, Saul J. and Fuhr, Jeffrey R., Optical region elemental abundance

analyses of B and A stars. IV. Re-evaluation with new critically com- piled Fe II oscillator strengths and improved estimates of the damping

constants, Astron. Astrophys. 152, 434-438 (1985).

Behring, W. E., Brown, C. M., Feldman, U., Seely, J. F., Reader, J.,

Richardson, M. C., Transitions of the type 2s-2p in Oxygenlike Y, Zr, and

Nb, J. Opt. Soc. Am. B _3» 1113-1115 ( 1986).

Bridges, J. M., Cromer, C. L., and Mcllrath, T. J., Investigation of a

1 aser-produced plasma VUV light source, Ap pi . Opt. _25, 2208 (1986).

Bridges, J. M. , Cromer, C. L., and Mcllrath, T. J., Laser produced plasma

XUV radiation source, X-Ray Calibration: Techniques, Sources & Detectors,

Proc. SPIE 689, 19 (1986).

Cooke, W. E. and Cromer, C. L., Multichannel quantum-defect theory and an equivalent N-level system, Phys. Rev. A _32 , 2725-2738 (1985).

Cooke, W. E. and Cromer, C. L., Closed-form expression for two-photon core excitation of Rydberg states, Phys. Rev. A _33 , 3529-3530 (1986).

Cromer, C. L., Bridges, J. M., Roberts, J. R., and Lucatorto, T. B., Highresolution VUV spectrometer with multichannel detector for absorption

studies of transient species, Appl . Opt. _24, 2996-3001 ( 1986).

Cromer, C. L. and Clark, C. W., Resonant Structure in Multiphoton Ionization of Calcium, J. Phys. B ^8, L497 (1985).

Datla, R. U., Roberts, J. R., Rowan, W. L., and Mann, J. B., Excitation

rate measurements of Cu XIII and Cu XVII ions, submitted to Phys. Rev.

[in press],

Feldman, U., Seely, J. F., Brown, C. M., Ekberg, J. 0., Richardson, M.

C., Behring, W. E., and Reader, J., Spectrum and Energy Levels of Br XXV,

Br XXIX, Br XXX, and Br XXXI [in press].

Gohil, P., Kaufman, V., and Mcllrath, T. J., High-resolution spectra of

laser plasma light sources in the grazing incidence region, Appl. Opt. 25,

2039-2040 (1986).

15
Division 531, Publications (cont'd.)

Jones, D. E. and Wiese, W. L., Stark Widths and Asymmetries of Some Neutral Carbon Lines, in Spectral Line Shapes , Vol . 3, 63 (Walter de Gruyter

arid Co., Berlin, 1985).

Jones, Douglas W., Wiese, W. L., and Woltz, L. A., Ion broadening of Ar I lines in a plasma, Phys. Rev. A _34 , 450-456 (1986).

Jupen, C., Litzen, 1)., Kaufman, V., and Sugar, J., Ne-like Ca XI ti Mn XVI

transition arrays 2p 5 3£ - 2p 5 4£ and energy levels, accepted by Phys. Rev.

A [in press].

Kaufman, V. and Sugar, J., Forbidden Lines in the ns 2 np

k Ground Configurations and nsnp Excited Configurations of Be through Mo Atoms and Ions, J. Phys. Chem. Ref. Data JL5, 321-426 ( 1986).

Kelleher, D. E., Ligare, M. K., and Brewer, L. R., Resonant four-photon

ionization of atomic hydrogen, Phys. Rev. A _31_, 2747 ( 1985).

Kelleher, D. E., Delpech, J. F., and Weiner, J., Broadening of a valence

autoionization resonance in electric fields, Phys. Rev. A 32, 2230-2233

(1985).

Kelly, Hugh P. and Kim, Yong-Ki , Editors, Atomic Theory Workshop on

Rel ativi Stic and QED Effects in Heavy Atoms , AIP Conference ProceecTi ngs

,

No. 136 (American Institute of Physics, New York, 1985).

Kim, Y.-K., Relativistic Effects in Electron-Ion Collisions, being pub1 i shed i n Institute of PI asma Physics Report No . IPPJ-AM-47

,

1986.

KonjeviC N. and Pittman, T. L. , Stark broadening of singly ionized neon lines, J. Quant. Spectrosc. Radiat. Transfer _35_, 473-477 ( 1986).

KonjeviC, N. and Pittman, T., Stark broadening of spectral lines of

homologous, doubly ionized inert gases, [in press],

Martin, W. C., Working Group 4: Structure of Atomic Spectra, in Reports

on Astronomy, Vol. XIX A, 156 (Reidel Publ . Co., Dordrecht, Holland]

1985). •

Mcllrath, T. J., Sugar, J., Kaufman, V., Cooper, D., and Hill, W. T., Ill,

Laser-driven ionization of Cs and absorption spectrum of resultant Cs

+ vapor, J. Opt. Soc. Am. B _3> 398-402 ( 1986).

Mori, K., Wiese, W. L., Shirai, T., Nakai , Y., Ozawa, K., and Kato, T. , Spectral Data and Grotrian Diagrams for Highly Ionized Titanium, Ti J- Ti XXII, At. Data Nucl . Data Tables 34_> ?9 (1986).

16
Division 531, Publications (cont'd.)

Persson, W. and Reader, J., Spectrum and energy levels of Y VI, J. Opt.

Soc. Am. B 2 , 959-988 (1986)

.

Pittman, T. L. and Fleurier, C., Plasma shifts of the He II H and P lines, Phys. Rev. A, 33, 1291-1296 (1986).

Pittman, T. L. and KonjeviC, N. , Experimental Study of Stark Broadened

N II Lines from States of High Orbital Angular Momentum, [in press],

Pittman, T. L. and Konjevit, N. , Stark broadening along homologous

sequences of singly ionized noble gases, J. Quant. Spectrosc. Radiat.

Transfer 35, 247-253 (1986)

.

Reader, J. and Sansonetti , C. J., Accurate energies for the low-lying

levels of singly ionized 198 Hg, Phys. Rev. A 33, Rapid Communications,

1440-1443 (1986).

Reader, J., Spectrum and energy levels of the sodiumlike ion Sr 27+

, J.

Opt. Soc. Am. B _3, 870-873 (1986).

Reader, J., Acquista, N., and Goldsmith, S., 4s 2 4p-4s4p 2 and 4s 2 4p-4s 2 5s

transitions of galliumlike ions from Rb VII to In XIX, J. Opt. Soc. Am.

B 3, 874-878 (1986).

Reader, J., Brown, C. M., Ekberg, J. 0., Seely, J. F. , Feldman, U., and

Behring, W. E., 2s 2 2p 5 - 2s2p 6 transitions in fluorinelike ions from Zr 31+

to Sn 41+

, being published in J. Opt. Soc. Am. [in press],

Roszman, L. J., Dielectronic recombination rates for some ions of the

lithium i soel ectroni c sequence, Phys. Rev. A [in press].

Roszman, L. J., Dielectronic recombination rate coefficients for ions of

the fluorine i soel ectroni c sequence, Phys. Rev. A [in press].

Rudd, M. E., Kim, Y.-K., Madison, D. H., and Gallagher, J. W., Electron

production in proton collisions: Total cross sections, Rev. Mod. Phys.

57, 965-994 (1985).

Saloman, E. 8., Cooper, J. W., and Kelleher, D. E., Electric-field-induced

interference in autoionizing resonances, Phys. Rev. Lett. _55, 193-196

(1985).

Sansonetti, Craig J. and Andrew, Kenneth L., Spectrum and energy levels of

singly ionized cesium: I. Revision and extension of the Cs II energy

levels, J. Opt. Soc. Am. B 3, 386-397 (1986).

17
Division 531, Publications (cont'd.)

Sansonetti , C. J. and Weber, K.-H., High-precision measurements of

Doppler-free two-photon transitions in Rb: New values for proposed

dye-laser reference wavelengths, J. Opt. Soc. Am. B 2, 1385-1391 (1985).

Sonntag, B. F., Cromer, C. L. , Bridges, J. M. , Mcllrath, T. J., and

Lucatorto, T. B., Laser-XUV Excited State Spectroscopy, Proc. of Third

Topical Meeting on Short Wavelength Coherent Radiation (1986).

Sugar, J. and Kaufman, V., The Mg-like spectrum of Cu XVIII, accepted by

J. Opt. Soc. Am. [in press].

Sugar, J. and Corliss, C., Atomic Energy Levels of the Iron-Period

Elements: Potassium through Nickel, J. Phys. Chem. Ref. Data 14, Supple

No. 2 (1985).

Sugar, Jack, Brewer, W. D., Kalkowski, G., Kaindl, G., and Paparazzo, E. Photoabsorption by the 3d shell in Ce, Pr, Ho, and Er: Observations and

calculations, Phys. Rev. A 32 , 2242 (1985).

Sugar, J. and Kaufman, V., Copper Spectra in a Laser-Generated Plasma:

Measurements and Classifications of Cu XII to Cu XXI, J. Opt. Soc. Am. B

3 , 704-710 (1986).

Sugar, J. and Kaufman, V., Wavelengths and Energy Levels of Zn XII to

Zn XIX, accepted by Phys. Scripta [in press].

Weiss, A. W., Local exchange approximations, Phys. Rev. A _34, Brief

Reports, 624-625 (1986).

Wiese, W. L., Experimental Methods for Determining Atomic Transition

Probabilities, in The Physics of Ionized Gases , Proc. XII SPIG 1984,

pp. 621 (World Scient. Publ . Co., Singapore, 1985).

Wiese, W. L., Editor, Spectroscopic Data Tables for Iron, in Reports on Astronomy, Vol . XIXA, 122 (Reidel Publishing Co., Oordrecht, Hoi 1 and ,

1985)

.

Wiese, W. L., Improvements in Transition Probability Data, in High! ights

of Astronomy , Vol. 7 (Reidel Publishing Co., Dordrecht, Hoi 1 and , 1986)

.

Wiese, W. L., Transition Probabilities (Atomic Physics), in Encycl oped i

a

of Physical Science and Technology, p. (Academic Press, New Vork,

1986)

.

18
Division 531, Publications (cont'd)

Wiese, W. L. and Jones, Douglas W., Ion Broadening of Heavy Element Lines

in Plasmas, as Proceedings for 8th International Conference on Spectral

Line Shapes, in Spectral Line Shapes , Vol . 4 [in press].

Woltz, L. A., Quasi-Static Ion Broadening of Isolated Spectral Lines [in

press]

.

19
PUBLICATIONS IN PREPARATION

Division 531, Atomic and Plasma Radiation

Brewer, L. R., Buchinger, F., Ligare, M., and Kelleher, D. E., ResonanceEnhanced Multi photon Ionization of Atomic Hydrogen (in preparation).

Chen, Guoxong and Nee, T.-J., Depolarization of the Near-ResonanceRayleigh Scattering by Barium Ions (in preparation).

Chen, Guoxong and Nee, T.-J., A Local Measurement of Ba+ Density Temporal

Evolution (in preparat ion)

.

Clark, Charles W., and Kelleher, D. E., Quadrupole Moments and Tensor

Polarizabilities from Fine Structure Splittings of Non-Penetrating

Orbitals (in preparati on)

.

Datla, R. U., Roberts, J. R., Mann, J. B., Electron impact excitation of

Ti X (in preparation)

.

Datla, R. U., Roberts, J. R., and Rowan, W. L., Measurements of Magnetic

Dipole Transition Wavelengths in Co XV and Co XX, submitted to Astrophys

J.

Datla, R. U., Roberts, J. R., and Rowan, W. L., The 3 P

3 P

? Magnetic

Dipole Transition in the Ground Configuration of Co XX, submitted to J. Opt. Soc. Am.

Jones, Douglas W., Pichler, G., and Wiese, W. L., Asymmetries in spectral

lines due to plasma ion broadening - Some unusual cases and a possible

test for plasma homogeneity, submitted to Phys. Rev.

Kelleher, D. E. and Saloman, E. B., The Stark effects of Rydberg levels

with an isotropic ion core (in preparati on)

.

Kim, Y.-K., Martin, W. C., and Weiss, A. W., Relativistic and Correlation

Effects in the 2s3p Configuration of Beryllium-like Ions (in preparation) .

Kim, Y.-K., and Desclaux, J. P., Relativistic Effects in Electron-Atom

Collisions, a review article for the Proceedings of the Symposium on Relativistic Many-Body Problems held in Trieste, Italy, June 30-July 4,

1986. The proceedings will be published as a special issue of the Physica

Seri pta

.

Klose, Jules Z. and Bridges, J. Mervin, Radiometric Calibrations of

Portable Sources in the Vacuum Ultraviolet (in preparat i on) .

20
Division 531, Publications in Preparation (cont'd.)

Martin, W. C., Improved 4 He I lsn£ ionization energy levels, and Lamb

shifts for lsns and lsnp terms (submitted to Phys. Rev. A).

Mishin, V. I., Lomoardi , G., Cooper, J. W., and Kelleher, D. E., Effects

of very low fields on narrow autoionizing states in Gadolinium, submitted

to Phys. Rev. A.

Nee, T. A., Calculation of Helium Plasma Satellites in Turbulent Plasmas

( i n preparati on)

.

Nee, T.-J. and Chen, Guoxong, Opacity Effects on Near-Resonance-Rayl eigh

Scattering in a Barium Plasma (in preparati on)

.

Oza, D. H., Greene, R. L., and Kelleher, D. E., The Stark broadening of Ha and Hg of C+5

, submitted to Phys. Rev. A.

Oza, D. H., Autoionization States {3l2l') of Helium-like Nitrogen Ion (in

preparation)

.

Roberts, J. R., Pittman, T. L., Sugar, J., Kaufman, V., and Rowan, W. !_.,

Magnetic Dipole Wavelength Measurements in the n=3 Configurations of

Highly Ionized Cu, Zn, Ga, As, Kr, and Y (submitted to Phys. Rev. A).

Roginsky, D. V. I., e-tight upper bounds to expectation values (in

preparation)

Roszman, L. J., The dielectronic recombination rate coefficients for ions

of the oxygen i soel ectroni c sequence, submitted to Phys. Rev. A.

Roszman, L. J., The dielectronic recombination rates for ions of the

nitrogen i soel ectroni c sequence, (in preparati on)

.

Roszman, L. J., The influence of ground configuration in metastable states

upon the dielectronic recombination of impurity ions in moderate density

plasmas (in preparation).

Seely, J. F., Ekberg, J. 0., Brown, C. M., Feldman, U., Behring, W. E.,

Reader, J., and Richardson, M. C., Laser-Produced Spectra and QED Effects

for Fe-like, Co-like, Cu-like, and Zn-like Ions of Au, Pb, Bi , Tb, ana U (submitted to Phys. Rev. Lett.).

Shirai, T., Ishii, K., Sugar, J., Mori, K, Nakai , Y., and Ozawa, K.

,

Spectral Data for Highly Ionized Molybdenum, Mo VI- Mo XL II, to be

submitted to J. Phys. and Chem. Ref. Data.

21
Division 531, Publications in Preparation (cont'd.)

Veza, D. and Sansonetti , C. J., Ionization of lithium vapor by cw

quasi resonant laser radiation (in preparati on)

.

Weber, J.-H. and Sansonetti, C. J., Accurate energies of nS, nP, nD, nF

and nG levels of neutral cesium (submitted to Phys. Rev. A).

22
TECHNICAL AND PROFESSIONAL COMMITTEE PARTICIPATION AND LEADERSHIP

Division 531, Atomic and Plasma Radiation Division

Daniel E. Kelleher

Member, International Organizing Committee of the Conference on Spectral Line Shapes.

Yong-Ki Kim

Member of Program Committee, APS Topical Conference on High

Temperature Plasmas.

Georgia Martin

Chairperson, NAS/NRC Committee on Line Spectra of the Elements - Atomic Spectroscopy.

William C. Martin

Chairman, Working Group on Structure of Atomic Spectra, International Astronomical Union.

Member, IAEA Network of Atomic Data Centers for Fusion.

James R. Roberts

Member of TEXT Users Organization.

Jack Sugar

Member, OSA Fellows and Honorary Members Committee.

Member, NAS/NRC Committee on Line Spectra of the Elements - Atomic Spectroscopy.

Wolfgang L. Wiese

Member of Organizing Committee, International Astronomical Union,

Commision on Fundamental Spectroscopic Data.

Chairman, Working Group on Atomic Transition Probabilities, International Astronomical Union, Commission 14.

Member, IAEA network of Atomic Data Centers for Fusion.

23
Division 531, Technical and Professional Committee Participation and

Leadership (cont'd.)

Wolfgang L. Wiese

Member, OSA Meggers Award Committee.

Co-Chairman, US-Japan Workshop on "Tokamak Diagnostics by Visible,

VUV and X-ray Radiation," Nagoya, Japan.

24
MAJOR CONSULTING AND ADVISORY SERVICES

Division 531, Atomic and Plasma Radiation

1. The Data Centers on Atomic Energy Levels and Transition Probabilities

routinely fill requests for atomic data or literature information

submitted by scientists in a wide range of research areas. The

requests average about 30 per month. On occasion, special reports

are prepared for particular user groups. Thus, W. C. Martin and

W. L. Wiese write updates on atomic data of interest for the astrophysical community for the IAU Transactions, and give review reports

at the General Assemblies of the International Astronomical Union.

3. Y.-K. Kim serves as a consultant to the A Division of the Lawrence

Livermore Laboratory on x-ray laser development.

4. J. Z. Klose performed numerous tests and calibrations of five Pt-Ne

and three Pt-Cr-Ne hollow cathode lamps this year as part of contract

work with Martin Marietta Aerospace. His work involved close consultation with Martin Marietta personnel concerning the results of each

test and plans for successive tests and calibrations.

5. W. C. Martin and J. Reader have consulted and advised NASA scientists

and other astronomers on standard wavelengths for calibration of the

High-Resolution Spectrograph for the Space Telescope.

6. J. Reader consulted with members of the x-ray laser program at

Lawrence Livermore National Laboratory about the spectra of highly

ionized atoms in 1 aser-produced plasmas and the wavelength calibration of such spectra.

7. J. R. Roberts serves as a member of the TEXT Users Organization

(TUO). TEXT stands for Texas Experimental Tokamak and is a national

plasma users facility. The TUO steering committee considers the

special needs of off-site user groups and has provided advice and

perspective on the users program to the TEXT managers and the Office

of Fusion Energy at DOE.

8. L. J. Roszman provided consulting activities on various electron-ion

collision processes and high density plasma modeling for x-ray laser

research and development in the Lawrence Livermore National Laboratory A and Physics Divisions.

25
Division 531, Major Consulting and Advisory Services (cont'd.)

9. L. J. Roszman advises and consults with the Impurity Transport

Modeling Group of the Princeton Plasma Physics Laboratory on electron-ion collision processes and other atomic data as well

as the modeling of low density plasmas.

10. J. Sugar and W. L. Wiese consulted and advised the Japan Atomic

Energy Research Institute (JAERI) on the compilation of spectral

1 i nes

.

26
JOURNAL EDITORSHIPS

Division 531, Atomic and Plasma Radiation

j. Reader, Editor, Line Spectra of the Elements, Handbook of Chemistry and

Physics , CRC Press.

W. L. Wiese, Associate Editor, Journal of Quantitative Spectroscopy and

Radiation Transfer.

27
TRIPS SPONSORED BY OTHERS

Division 531, Atomic and Plasma Radiation

Victor Kaufman worked at the Zeeman Laboratory of the University of

Amsterdam making spectroscopic observations and measurements of Ca III and

CA IV. All expenses including airfare and per diem were paid by the

Zeeman Laboratory (June, July 1986).

Yong-Ki Kim traveled to Lawrence Livermore National Laboratory to consult

with the members of A Division on X-ray lasers. Expenses were paid by

LLNL (April 1986).

Yong-Ki Kim traveled to Grenoble, France to collaborate with J. P.

Desclaux of the French AEC on the development of Relativistic Continuum

Wavefunction Codes. The trip was paid fully from a NATO research grant

(June 1986).

Yong-Ki Kim traveled to Trieste, Italy to participate in the Symposium on Relativistic Many-Body Problems. Trip was fully paid by the International

Center for Theoretical Physics in Trieste (July 1986).

W. C. Martin traveled to Lund, Sweden, to participate in a symposium on atomic spectroscopy at the University of Lund in honor of Professor

Bengt Ed1$n's eightieth birthday. All expenses were paid by the

University of Lund (November 1986).

J. Reader traveled to the Lawrence Livermore National Laboratory to

consult with members of the x-ray laser program about the spectra of

highly ionized atoms in 1 aser-produced plasmas and the wavelength

calibration of such spectra. Trip was paid for by LLNL (August 1986).

L. J. Roszman traveled twice to the Lawrence Livermore National Laboratory

to consult with an R-Program group led by Dr. S. Dalhed. Both trips were

paid for by LLNL (February, July 1986).

J. Sugar attended the Colloquium on Atomic Spectra and Oscillator

Strengths for Astrophysics and Fusion Research at the University of Toledo

in Toledo, Ohio. The conference paid for a portion of the trip (August

1986).

W. L. Wiese traveled to Toledo, Ohio and gave an invited talk at the

Colloquium on Atomic Spectra and Oscillator Strengths for Astrophysics and

Fusion Research at the University of Toledo. They paid his airfare and

partial per diem (August 1986).

28
CALIBRATION SERVICES PERFORMED

Division 531, Atomic and Plasma Radi ation

Type of Service Customer SP 250

No. of

Tests

Hollow Cathode

Lamp

Martin Marietta Contract 5

UV Spectral

Radiometer

Perkin Elmer 40040S 1

Deuterium Lamp Univ. of Colorado 40030S 1

Deuterium Lamp NRL 40030S 1

29
SPONSORED SEMINARS AND COLLOQUIA

Division 531, Atomic and Plasma Radiation

Munir Nayfeh, University of Illinois, "Atomic Engineering of Giant Dipole

Atoms," October 10, 1985.

K.-T. Lu, Graduate School, USTC, Academy of Sciences, Beijing, "On the

Formation and Structures of Excimers: Triatomic Hydrogen and

Fermi --Comp! exes ," October 15, 1985.

Dan Roginsky, Racah Institute of Physics, Hebrew University of Jerusalem,

"Novel Error Bounds for Atomic Oscillator Strengths," October 28, 1985.

Kurt Behringer, Joint European Torus (JET), Culham, England,

"Spectroscopic Diagnostics on the JET Tokamak," November 1, 1985.

U. I. Safronova, Institute of Spectroscopy, USSR Academy of Science,

"Di el ectronic Satellites of Highly Charged Ions," November 4, 1985.

Dipak Oza, Louisiana State University, "Electron Scattering by Hydrogenic

Targets: Close-Coupling Methods," December 12, 1985.

Masahide Ohno, Institute of Physics, University of Bonn, West Germany,

"g-Hartree ab initio Calculation of Atomic Ionization Energies,"

February 26, 1986

Stephen Younger, Lawrence Livermore National Laboratory, "The Importance

of Atomic Physics for X-ray Lasers and Thermonuclear Fusion," March 4,

1986.

Sveneric Johansson, Department of Physics, University of Lund, Sweden,

"Laboratory and Stellar Spectra of Iron-Group Elements," March 6, 1986.

Robert Cowan, Los Alamos National Laboratory, Los Alamos, New Mexico,

"Calculations of Atomic Energy Levels and Spectra with Applications to

Photoelectron Spectra and Dielectronic Recombination Rates," May 13,

1986.

Lars Engstrdm, Argonne National Laboratory, Argonne, Illinois,

"Differential Lifetime Measurements as a Probe of Atomic Structure,"

May 27, 1986.

Jean-Paul Desclaux, Centre d'Etudes Nucleaires de Grenoble, France,

"High-Precision Energy Level Calculations of Two-Electron Ions," May 23,

1986.

30
Division 531, Sponsored Seminars and Colloquia (cont'd.)

Kei shi Ishii, Kyoto University, Kyoto, Japan, "The Cobalt Isoel ectroni

c

Sequence," July 18, 1986.

Peter Hagel stein, Lawrence Livermore National Laboratory, "Relativistic

Atomic Physics Calculations for Model Making,", August 6, 1986.

Indrek Martinson, University of Lund, Sweden, "Recent Advances in Lifetime

Measurements for Multiply Ionized Atoms," August 22, 1986.

31

TECHNICAL ACTIVITIES

Division 533, Radiation Physics

The Radiation Physics Division focuses on measurement programs

relating to the use of electron, laser, ultraviolet, ana soft x-ray

radiation in the energy range from about 5 eV (250 nm) to 500 eV (2.5 nm)

.

In support of this mission, radiation standards and advanced

measurement techniques are developed. Through our standards program, the

Division provides the central national basis for the measurement of far

ultraviolet and soft x-ray radiation. The NBS synchrotron radiation

facility and a detector calibration facility based upon wel 1 -characteri zed

photoionization chambers serve as national radiation standards.

Measurement services are available for the calibration of the quantum

efficiency of UV photodiodes and the spectral responsivity of vacuum ultraviolet spectrometer systems.

Through our electron measurements program, new types of electron

sources and detectors are developed to investigate the properties of

matter on an atomic scale. For example, specially designed spin-polarized

electron sources and detectors are used to determine fundamental atomic

scattering properties and to measure surface magnetism. An electron

tunneling device is being developed to provide "images" of surfaces on an atomic scale and to study relationships between macroscopic material

properties and surface microstructure.

With the goals of improving standards and understanding the

fundamental physical phenomena upon which they are based, the Division

also conducts theoretical and experimental research on the electronic

structure of atomic and molecular systems, the interaction of the systems

with photon and electrons, and radiation deposition and energy transfer

processes. Theories are developed for the scattering and transport of

electrons in materials of fundamental and technological interest. New

techniques and instrumentation are developed to study radiative reactions

with matter, including photoexcitation and photoionization processes and

non-linear effects in intense laser fields. Studies are underway to

investigate to what extent the properties and behavior of atomic systems

can be manipulated by measuring and controlling atomic and molecular

states in their local environment.

The Division has two major research facilities, a dedicated

synchrotron ultraviolet radiation facility ( SURF- II) and a polarized

electron research facility.

33
Division 533, Technical Activities (cont'd)

SURF-II is a dedicated synchrotron radiation facility, consisting of

a 300 MeV electron storage ring, a 10 MeV microtron injector, and

associated synchrotron radiation beam lines. It produces radiation in a narrow, intense, highly polarized beam with a continuous and accurately

known spectrum from the infrared through the visible and into the far

ultraviolet. SURF-II is unique among synchrotron light sources by virtue

of its uniform and precisely known circular orbit. This allows accurate

determination of all the spectral and geometrical properties of the

radiation and hence its use as an absolute radiometric standard.

This facility serves staff from our own Division, users from other

NBS Divisions, and outside users in radiometric standards and calibration

work, optical physics research, surface science, biochemistry,

spectroscopy, and other research areas utilizing far ultraviolet

radiation. It fills a growing demand for radiation in the ultraviolet

and soft x-ray region of the electromagnetic spectrum. Of the 11 liqht

ports at SURF, 6 are now instrumented for user applications and for

calibration of optical instruments and transfer standard photodiodes.

Some of these ports are shared by more than one experimental station.

Three of the remaining ports are utilized for beam current monitoring,

electron counting, and machine diagnostics. Most experiments and

calibrations can run simultaneously, unless they require special beam

parameters.

The polarized electron scattering facility is used to produce and

measure beams of spin polarized electrons and is available for

collaborative research by NBS and outside scientists in areas of mutual

interest on a time-available basis. Three separate, ultra-high vacuum instruments are available. The polarized electron beams have currents in excess of 1 uA, with an optically reversible polarization at energies less

than 1 KeV and with an energy resolution of =0.15 eV.

These electrons are used to probe spin dependent scattering

interactions between polarized electrons and surfaces or polarized

electrons and atoms. The electron-surf ace scattering capability can be

used to determine surface structure or study surface magnetic phenomena

and their dependence on temperature, composition, adsorption, etc. The

electron-atom scattering capability can be used to probe spin-orbit and

exchange interactions in electron scattering and to completely determine

the parameters of a selected collision process.

In relatively new research directions, an electron polarization

microscope consisting of special electron spin detectors and a scanning

electron microscope is being used to probe magnetic structure of

technologically important materials on a sub-micron scale. A scanninq

tunneling microscope has also been constructed to apply the phenomenon of

34
Division 533, Technical Activities (cont'd)

surface-vacuum-surface electron tunneling to investigations on an atomic

scale of the nucleation and growth of thin films on clean metallic and

semiconductor surfaces.

As can be seen in the following sections, the Division staff has been

active in publishing research papers, providing calibration services,

presenting invited talks, sponsoring conferences, providing consultation

services, and participating in technical and professional committees. We

have also been very active in technical collaborations within NBS and with

universities, industry, and other government agencies. Highlights of the

past year include:

1. The new technique of scanning electron microscopy with electron

polarization analysis (SEMPA) was used to make unique, unprecedented

high resolution (10 nm) measurements of the magnetic microstructure

of advanced magnetic recording materials, in coll aborat ion with 3

industrial research organizations.

2. The orbiting electron energy of SURF-II was increased from 282 MeV to

300 MeV. This results in a significant gain in photon flux at the

soft x-ray end of the synchrotron radiation spectrum. The

improvement is a factor of 2 at 5 nm. This improvement in flux will

allow an extension of calibration services to shorter wavelengths and

will allow atomic/molecular, solid state, and surface physics

experiments up to, and beyond, the important carbon K edge at 4.3 nm.

3. A new soft x-ray measurement program was implemented at SURF-II and

the Brookhaven-NSLS in collaboration with the U. of Tennessee and

ORNL. Measurements utilizing a new, state-of-the-art, soft x-ray

emission spectrometer were made to study radiation damage mechanisms

in fragile solid materials (the alkali halides, LiF and NaCl).

4. A new, high energy measurement capability and beamline was commissioned at SURF-II to extend our user program in surface science

and ultraviolet photoemission spectroscopy to higher photon energies.

The new measurement system was utilized by the NBS Surface Science

Division and by a new user team from Yale U. and U. of Central

Florida studying electron correlations in the simultaneous

photoionization and excitation of helium, He + hv - He+ + e.

5. An updated SURF Users

1

Guide was completed, replacing an earlier

version published 10 years ago.

6. Documentation of the far UV detector calibration service was completed and submitted for publication in a special NBS SP 250

series.

35
Division 533, Technical Activities (cont'd)

7. A new collaboration between Division staff and staff from Los Alamos,

Argonne, and Daresbury was planned to enable complementary and

coordinated photoionization studies to be done at the SURF- 1 1

,

Brookhaven/NSLS, and Daresbury synchrotron radiation facilities.

8. Division staff are a part of a Materials Research Group (MRG) that

will be funded by NSF to study surface magnetism at NSLS using the

techniques of spin polarized photoemission and molecular beam

epitaxy. The group consists of 11 principal investigators from 8

major laboratories representing industry, universities, and

government 1 aboratories.

9. Fifteen major visiting scientist collaborations were active in FY86:

three in the Far UV Physics Group; four in the Electron Physics

Group; and eight in the Photon Physics Group.

10.

For the third year in a row, work in the Division is being recognized

with an I R- 100 award , shared jointly with colleagues from the

U. of Tennessee and ORNL for the development of a soft x-ray emission

spectrometer that can measure weak radiation with efficiencies 1000

to 10,000 higher than conventional spectrometers in the energy range

20 eV to 1 KeV.

FAR UV PHYSICS GROUP

The Far UV Physics Group is characterized by the development of

radiometric techniques and standards for far ultraviolet radiation and by

research on measurement methods utilizing far ultraviolet radiation. The

NBS electron storage ring, SURF- II, is operated for radiometric research

and calibrations of spectrometer systems and transfer standard detectors,

and as a source of V UV/soft x-ray radiation for user-groups within NBS and

outside. Additionally, off-SURF experimental research and development in

radiometry is carried out, and transfer standard detectors are calibrated

and supplied in the wavelength region 115-250 nm.

SURF-II Operations and Improvements (L. Hughey and J. Pollard)

The NBS Synchrotron Ultraviolet Radiation Facility (SURF-II) achieved

another milestone in performance in December 1985 by reaching an operating

energy of 300 MeV. The increase in the energy of the stored electron beam

from 282 to 300 MeV results in a significant gain in photon flux at the

soft x-ray end of the synchrotron radiation spectrum, in the wavelength

region from 20 nm down to about 4 nm. The increase in photon flux density

at 5 nm, for example, is about a factor of two, and useful flux from SURFII is now available to below 4 nm (300 eV) . This significant advantage

allows an extension of the spectral region covered by the radiometric

activities of SURF-II and allows atomic/molecular, solid state, and

36
Division 533, Technical Activities (cont'd)

surface physics experiments up to and beyond the important carbon K edge

at 4.3 nm.

In the past, the operating energy had been limited to 282 MeV by the

magnet cooling and the radio frequency accelerating systems, both of which

had been originally designed for 240 MeV. The addition of a second heat

exchanger and installation of an RF system capable of twice the output

power has overcome these limitations.

The new RF system has also improved beam lifetime and the beam

dynamics of the circulating electron beam by stabilizing a troublesome

longitudinal bunch oscillation. With the old RF system these oscillations

were present at all beam currents greater than 19 mA. In initial tests,

the beam was phase stable to more than 160 mA. The system will be further

improved by replacing a phase-shifter and coaxial attenuator that are

still not optimized. This stability opens the door to a new class of

experiments at SURF-II involving the measurement of fluorescence on the

picosecond time scale.

Average beam current achieved from August 1985 through June 1986 was over 85 mA. SURF-II provided beam to users 92.5% of the scheduled beam

time. The scheduled user beam time is 9 hours per day, Tuesday through

Friday. Mondays are used for maintenance, improvements, and continuing

assessment of the machine's radiometric parameters.

SURF-II Users Program (R. Madden)

A new Users' Guide for SURF-II has been prepared and is now

available. This revision was made to reflect several major improvements

at the SURF-II facility. This guide replaces one written more than ten

years ago and is intended to provide most of the information a new user at

SURF-II will require.

The many changes that have taken place at the facility include

notable improvements. These include an increase in operating energy of

the electron storage ring from 240 MeV to 300 MeV and an increase in

circulating electron beam current from 10 mA to over 100 mA (with a maximum of 200 mA to date). All flux output curves for the synchrotron

radiation from the storage ring as well as the various spectrometers on line have been updated. While the earlier handbook described only the

three beamlines which were instrumented at that time, the current handbook

covers the eight beamlines in use today. The beamline descriptions

include the single original spectrometer, which is still in place, as well

as three new instruments of advanced design which were placed on SURF-II

only in the last two years.

37
Division 533, Technical Activities (cont'd)

In addition to sections on machine description, beamline layouts, vacuum requi rements, and guest scientist arrangements, the new Users 1 Guide has been expanded to cover characteristics of synchrotron radiation,

safety requirements, listings of places to stay in the area, maps, etc.

As shown in the accompanying table, SURF-II users were active during

FY86 in the areas of spectrometer calibrations, surface science, atomic

and molecular physics, radiation effects in solids, and UV and soft x-ray

optical physics. Those technical activities in the table that are indicated as collaborations with Radiation Physics Division staff are described in more detail in other sections of this report.

In a new thrust to reach out to potential SURF-II users, Division

staff and users presented a series of five papers at a workshop sponsored

by the Materials Science Advisory Committee of the Southeastern

Universities Research Association (SURA). These presentations described

opportunities for doing solid state research, surface science, and

materials science using VUV and soft x-ray radiation at SURF-II. One of

the presentations, by a U. Tennessee SURF-user, highlighted the advantages

of making measurements at SURF-II in preparation for more extensive

measurements at larger national facilities, in this case at the Brookhaven

NSLS.

SURA is a consortium of 34 universities from the southeastern part of

the country. Its Materials Science Advisory Committee is presently

investigating materials research opportunities at existing synchrotron

radi at ion f aci lities.

SURF-II USER ACTIVITIES

Spectrometer Calibrations

© 18 user groups involved in solar physics, astronomy, plasma

diagnostics, atomic physics, and standards development.

Surface Science

© Users from NBS Center of Chemical Physics interested in

photon-stimulated desorption studies of ion desorption mechanisms

and energetics.

Atomic and Molecular Physics

© Users from Yale U. and U. of Central Florida interested in

measuring electron correlation effects in the simultaneous

photoionization and excitation of helium.

38
Division 533, Technical Activities (cont'd)

© Users from the U. of Maryland and NRL interested in developing a very high spectral resolution radiation measurement capability for

molecular physics applications.

o Users from the U. of Maryland and Howard U. (with 533.06)

interested in polarized fluorescence of excited molecular systems.

o Users from LANL and Argonne National Labs (with 533.06) interested

in angle resolved photoelectron spectroscopy of excited molecular

systems.

Solid State Studies

© Users from ORNL and the U. of Tennessee (with 533.06) interested

in the electronic structure of fragile materials and layered

compounds.

UV and Soft X-Ray Optics

® Users from GSFC interested in the optical properties of highly

reflecting multilayer devices.

Far UV Detector Calibrations (R. L. Canfield and N. Swanson)

A new detector calibration system at SURF-II came on-line during FY

86 and is routinely producing a number of Outgoing calibrations of

photodiode standards in the 5-50 nm spectral region, using the photoionization of rare gases as an absolute reference standard. This system has

achieved the design goals of rapid throughput and improved accuracy,

resolution, and flexibility, having also been used to make preliminary gas

absorption and optical properties studies.

The calibration facility features dual, toroidal grating

monochromators optimized for the 3-60 nm region. This, taken together

with an upgrade in the SURF-II storage ring from 284 MeV to 300 MeV

orbiting electron energy, results in much greater flux levels at the soft

x-ray wavelengths than available previously. Another feature that

promotes greater precision and accuracy is a carousel arrangement allowing

up to 5 detectors to be calibrated in a single measurement protocol.

In the 52-254 nm region transfer standards are calibrated in other

Group lab facilities, referencing to the photoionization of rare gases at short wavelengths with spectral extension to the longer wave-lengths using

a thermopile. A total of 21 calibrated transfer standards or recal ibrat ions of previously supplied standards were provided for 18

outside user groups, as well as several NBS staff, serving such fields as solar physics, aeronomy, plasma diagnostics, astronomy, and solid state

physics. Documentation of the NBS far ultraviolet detector calibration

39
Division 533, Technical Activities (cont'd)

activity has been completed and will soon be published as an NBS Special

Publication (SP 250-2).

Spectrometer Calibrations (S. Ebner and T. Hall)

The large spectrometer calibration facility at SURF- I I was active for

32 weeks during FY86, during which 18 user groups conducted instrument

calibrations for use in plasma diagnostics, solar physics, etc. This

facility uses the calculable radiant flux from SURF-II as a radiometric

standard and enables users to characterize absolute instrument response in

the 4-400 nm spectral region. Users were from NASA/GSFC, North Carolina

State U., Johns Hopkins U., LASP/U. of Colorado, NRL, and NBS. NASA

support for this facility continues.

One of the highlights of this calibration program was the pre- and

post-flight calibrations of the radiation responsivity of the Solar

Ultraviolet Spectral Irradiance Monitor (SUSIM) experiment. SUSIM is a space shuttle experiment that flew for the second time in July, 1985, with

one of the NRL principal investigators as astronaut payload-specialist.

Surface Science (T. Madey, R. Stockbauer, and R. Kurtz)

We have supported at SURF-II the establishment by the NBS Surface

Science Division of an experimental capability to study adsorbed molecules

on surfaces. These studies use several SURF-II monochromators and an ultrahigh vacuum system. Photon stimulated desorption (PSD) of ions is

being studied to understand desorption mechanisms and energetics.

Variable wavelength ultraviolet photoemission spectroscopy (UPS) is also

utilized to characterize the surface species formed upon adsorption of the

molecules on clean metal and oxide substrates. Ion desorption mechanisms

for ionically and covalently bonded adsorbates are investigated.

During the past year, the beamline was upgraded with the installation

of a laminar profile, ion-sketched grating and an in-situ photon monitor.

The laminar profile grating greatly reduces the second order light from

the monochromator . Since the PSD data are greatly affected by higher

order radiation, this will greatly reduce the corrections which must be

made to the data. The in situ photon monitor will allow an independent

and real-time determination of the photon flux incident on the sample.

This will reduce the uncertainty in PSD measurements, since the data must

be normalized to the photon flux.

Several important studies were conducted last year. The first was

the continuation of a study of PSD from a single crystal of T i

0

2

. This

compound is used as a model system for the theory of Auger-stimulated

desorption. It was found that ions desorb more readi ly from a defect

surface than from the nearly perfect surface. This is contrary to what

40
Division 533, Technical Activities (cont'd)

current theory predicts and shows the competition between electronic state

and geometrical structure. The reduced coordination of the oxygen atom

with the Ti cation gives an enhanced ion yield and shows the importance of

geometry in the desorption probability.

Another study involved PSD from CO adsorbed on a Cr(110) surface. It was found that at low coverage the CO either lies flat or at a very

inclined angle to the surface. At higher coverages or with coadsorption

with oxygen, the CO stands upright. Presently, photon stimulated ion

desorption from the inclined or upright CO is being studied.

An electron photoemission study is underway to observe chemically

induced phase transitions on a single crystal V0

2

. This crystal undergoes

a semiconductor-metal phase transition as it is neated above room temperature. The study will determine if the transition can be induced at room temperatures by the adsorption of a molecule such as CO.

Very High Resolution Spectroscopy at SURF-II (M. Ginter and R. Madden)

The installation of a very high resolution 6.65 m normal incidence

monochromator is continuing at SURF-II. Researchers from the U. of

Maryland and the NRL are the principal investigators on this project with

partial support from the NSF. The goal of this project is to carry out

research on the dynamics of energy transfer in atoms and molecules with an energy resolution that is a factor of ten better than photometric

instruments currently in service at synchrotron radiation facilities. In

a collaborative effort, a similar instrument is being installed and

converted to photometric studies at the KEK Photon Factory in Japan.

These instruments will cover the 30-200 nm spectral range with resolving

powers of 2xl05

. In addition, our instrument will provide highly

polarized radiation to study atomic and molecular systems (polarization > 98% for wavelengths >60 nm).

This instrument is now installed at SURF-II. The beamline and its

optics have been commissioned. Polarization studies of the collection

optics have confirmed the high degree of polarization of the radiation

entering the spectrometer. U. of Maryland and NRL staff intend to put the

spectrometer into operation by spring, 1987. The instrument is now under

vacuum and detection systems are being prepared for use. Expected NBS

users of this instrument are from the Centers for Radiation Research,

Basic Standards, and Chemical Physics. Outside users expressing interest

in using this facility are from NRL, U. of Maryland, ORNL, Yale, Argonne,

SUNY Binghamton, Ohio State, U. of Nebraska, Harvard College Observatory,

Imperial College, and the Bhabha Atomic Research Center of India.

41
Division 533, Technical Activities (cont'd)

ELECTRON PHYSICS GROUP

The Electron Physics Group has ongoing research efforts in electron

collision physics including electron-surf ace interactions, surface

magnetism, electron interaction theory, electron polarization phenomena,

electron-atom and electron-molecule collisions, and electron optics and

instrumentation. The wide applicability of electron-based measurement

technologies allows us to contribute to the solution of many diverse

scientific and technological problems.

This year we have continued to increase and focus our efforts toward

the study of microscopic phenomena and their influence on the macroscopic

properties of surfaces. As in the recent past, a major emphasis is on magnetic phenomena and structure. We are in the process of adding a scanning Auger microprobe facility to our effort which will greatly

increase our capabilities in the study of magnetic mi crostructure.

Additionally, most of our experiments are being adapted to the use of the

technique of molecular beam epitaxy to grow thin over-layer films,

permitting us to study interfacial phenomena.

Electron-Atom Collision Studies (M. Kelley, J. McClelland, and

B. Waclawski)

The general aim of this project has been to study electron-atom

collisions under conditions where all important parameters in the

collision process have been experimentally determined. These "complete"

or fully specified experiments provide a stringent test of our current

understanding of electron-atom collision physics. Such interactions as the exchange or the spin-orbit interaction are separately observed.

Following our first work on near-threshold ionization and the optical

pumping preparation of polarized sodium beams, we began a study of

spin-polarized superelastic scattering. Our initial superelastic

measurements were conducted using linearly polarized laser light to excite

the atoms. This yielded the very surprising result that large spinasymmetries were observed despite the fact that the excited states were

not spin polarized. The explanation of this effect required an understanding of the coupling between the orbital angular momentum of the

scattered electron, the orbital angular momentum of the target electron,

and the target electron's spin. We also observed that the spin asymmetry

depended on the relative quantum mechanical phases of the excited magnetic

sublevels as prepared by the optical pumping. Work is currently underway

to understand this from a theoretical point of view.

Most recently we have made measurements using circularly polarized

light. In this case the atoms appear in a pure excited state - the

electron spin and angular momentum (as well as the nucleus spin) have

maximal orientation either parallel or anti-parallel to the incident

laser. A measurement of the spi n-asymmetry under these conditions gives

42
Division 533, Technical Activities (cont'd)

the maximum possible information on the scattering process because pure

state-to-state scattering is realized. Very dramatic effects occur such

as a large difference in the behavior between scattering to the left and

scattering to the right, and a very rapid change of the scattering

asymmetry from positive to negative near a scattering angle of -30° for

electrons with 9 eV incident energy.

Our current efforts consist of formulating a theoretical basis for

understanding the above data and making measurements at other incident

electron energies and scattering angles to identify systematic trends and

additional effects. Future plans call for beginning measurements on spin-polarized elastic electron scattering.

Scanning Electron Microscopy with Polarization Analysis (SEMPA)

(R. Celotta and J. Unguris)

Scanning Electron Microscopy with Polarization Analysis (SEMPA) is

the name we have given to a technique we have developed to explore

sub-micron magnetic domain structures. When an electron beam is incident

on a magnetic material, spin-polarized secondary electrons are emitted.

The electron spin polarization of these electrons is simply proportional

to the spin polarization of the valence electrons in the solid.

Therefore, a measurement of the polarization of the secondary electrons

yields a direct measurement of the magnetization in the region of the

sample probed by the incident electron beam. We have added electron

spin-polarization analyzers to a scanning electron microscope in order to

measure the magnetic structures present with high spatial resolution. We

not only obtain the usual topographic map of a material, but also

simultaneously and independently image the magnetic microstructure of the

surface. The spatial resolution of the two images is the same,

approximately 10 nm. Because SEMPA is a new technique, much of the early

work has involved developing and perfecting the instrumentation and

performing a series of exploratory experiments to test capabilities of the

method. This involved the development of a new kind of electron

spin-polarization analyzer based on the spin-orbit interaction in the

scattering of 150 eV electrons from an evaporated Au film. This detector

is much more compact and simpler to use than previous detectors.

So far we have successfully imaged magnetic microstructures in the

following materials: (1) Fe-3% Si single crystals; (2) Permalloy thin

films; (3) Permalloy thin-film recording heads (provided by Control Data

Corporat ion) ; (4) CoN i sputtered films (provided by Kodak); and (5)

various Fe-based metglasses (provided by the Naval Surface Weapons Center

and Allied Chemical). Work in progress involves the study of magnetic

microstructure in Co single crystals and in evaporated Fe films. We are planning to use SEMPA to investigate a variety of micromagnetics systems

in great detail. Of primary scientific interest are two-dimensional

magnetism in thin films and surfaces, magnetic structure within domain

43
Division 533, Technical Activities (cont'd)

walls, and the magnetic structure of sub-micron devices. These are reflected in systems with immediate technological implications such as magnetic recording media, thin film memory devices, magnetic domain

dynamics, new fine-grained magnetics for electrical motors, and the

magnetism of layered materials.

Finally, in order to meet the demand for these types of measurements,

we are in the process of adapting another electron microscope for

spin-polarization analysis. This microscope will include a scanning Auger

microprobe and will therefore be able to give us a map of the chemical

composition of the surface along with the topographic and magnetic

images.

We are working to build joint research efforts with industry, other

government 1 aboratori es, and universities. We have received a multitude

of samples from major corporations interested in exploring the

applicability of this new technique to outstanding scientific and

technological problems of concern. We are in the process of establishing

research agreements with a number of industri al/university/government

laboratories to pursue specific illustrative research problems using this

new technique. We expect these collaborative efforts will prove to be

scientifically fruitful, intellectually stimulating, and mutually

benef ici al

.

This is a collaboration project with staff from the Micro and Optical

Metrology Group of the NBS Center for Manufacturing Engineering.

Scanning Tunneling Microscopy (D. Pierce, R. Dragoset, R. Young, and

S. Mielczarek)

In a small pilot program, we are operating a scanning tunneling

microscope to better our understanding of the nucleation and growth of

thin films on clean metallic and semiconductor surfaces. We have

successfully operated the instrument in air, scanning gold and pyrolytic

graphite surfaces, and we have measured the regular structure of a mechanically fabricated diffraction grating. While working in a high vacuum environment, we studied the result of the diamond-turning process

used to fabricate extremely smooth mirrors. We have now completed the

installation of this system in a standard ultra-high vacuum surface

analysis chamber which allows, in addition to scanning tunneling

microscopy, LEED, Auger spectroscopy, ion-sputtering, and sample

installation, heating, cooling, and cleaning. The control of sample

cleanliness and preparation available to us in this new system should

permit us to observe surface topography with atomic resolution.

Our primary experimental interest is the character i zat ion of

thin-film growth structures. Our initial plans include obtaining atomic

resolution on a single crystal surface, e.g. Si(lll), and observing

surface changes after sub-monolayer deposition of an evaporant. We will

attempt to perform evaporation in situ in order to scan the same area of

the surface before and after evaporation. We hope to correlate changes in

44
Division 533, Technical Activities (cont'd)

surface structure after evaporation with the character of the surface

before deposition (e.g. defects).

Inverse Photoemission (D. Pierce, L. Klebanoff, and R. Jones)

Cur work on the scattering of spin-polarized electrons from surfaces

continues with a high level of activity. By using our polarized electron

gun to observe the effects of the exchange interaction, we are able to sense the local net alignment of spins in the surface of a ferromagnet.

The short mean free paths for elastically scattered electrons make this

technique extremely surface sensitive, unlike neutron scattering.

Although in its infancy, inverse UV-photoemission has emerged as a very useful new method of gaining an understanding of the electronic

structure of surfaces in general, and of ferromagnet ic surfaces in

particular. When it is used with the complementary method of

photoemission spectroscopy, it is possible to gain a complete picture of

the electronic structure of surfaces.

The direct process, i.e., spin-polarized, angle-resolved, and

energy-resolved photoemission, is normally observed using a high intensity

synchrotron radiation source, a UV monochromator, an electron energy

analyzer, and a spin polarization detector. We have demonstrated that it

is possible to do the inverse experiment, where spin-polarized electrons

at a specific energy and angle of incidence are scattered from a target

and the UV photons at a selected wavelength are detected. With a nickel

(110) single crystal target, we demonstrated that only minority spin

electrons are absorbed into unfilled d-bands and give rise to UV photons.

This type of experiment allows one to observe the spin-polarized unfilled

states near the Fermi level. By varying the angle of incidence we also

measured the dispersion of these bands.

We have recently completed an investigation of the clean Ni(001)

surface and the c(2x2) adsorption systems, O/Ni ( 001) and S/Ni ( 001) . For

clean Ni(001), we found a minority-spin character for the unoccupied 3d

band, but an essentailly non-magnetic character for the Ni 4sp band.

These spin-dependent results confirm previous spectral assignments made

for Ni(001). No spin splitting of the 4sp band was found for Ni(001), in

contrast to the splitting observed for N i (110) . No spin dependence of the

Ni(001) image potential surface state was found. Our investigations of

Ni (001) chemisorption yielded surprising results. No evidence was found

for a c(2x2) oxygen- i nduced antibonding state at the surface Brillouin

zone center, r. This finding is in direct contradiction with the

published experiments of Scheidt and theoretical predictions. The

chemisorbed oxygen does not significantly affect the spin dependence, and

hence the intrinsic magnetization, of the observed minority-spin 3d

spectral peak.

45
Division 533, Technical Activities (cont'd)

Chemisorbed sulfur produces qualitatively different results. The

presence of a c(2x2) sulfur overlayer produces a small intensity

enhancement at the Ni 3d inverse photoemission peak, and reduces the

observed spin dependence of the peak by four-fold. These variations

suggest the possible existence of a sulfur-induced unoccupied state of

major i ty spin character just above the Fermi level at r. Such a state

would play a central role in the mechanism by which sulfur destroys

surface magnetism.

Electron Transport Theory (D. Penn)

Three theoretical topics were explored during this past year. Recent

experiments using polarized electron beams and spin-polarized detection

have stimulated a detailed theoretical analysis of the spin-dependent

scattering process. Our conclusion is that free electron-like Stoner

excitations contribute predominantly to the scattering process. The

free-electron Stoner excitation is an electron-hole pair excitation

consisting of a d-hole of given spin and an electron in a free

electron-like state of opposite spin. This differs from the usual Stoner

excitation in which the electron is in a d-state. The model us£d

demonstrated that the electron-hole pair excitations which contribute

significantly to exchange scattering have free electron-like final states

as opposed to those of the usual d-character. Thus, creation of a free-electron Stoner excitation is far more likely than the usual type of

Stoner excitation.

Despite the importance of the inelastic mean free path, experimental

values for a given material are generally available only in a limited

energy range and the measured values are subject to relatively large

uncertainties. On the theoretical side the situation is no better. With

the exception of free electron materials such as Az, the mean free path

has not been calculated from first principles. The primary missing

ingredient is the dielectric response function which depends on the energy

and momentum lost by an electron in a collision. Thus, existing

calculations are semi-phenomenological and, because of experimental

problems, it is difficult to assess how well the theories actually work.

During the past year the mean free path has been calculated based on

a model dielectric function whose form is motivated by the use of the

statistical approximation. In the limit that the momentum transfer is

zero, the model dielectric function is set equal to the measured optical

dielectric function which has been measured for a wide variety of

materials in synchrotron radiation studies. The results are calculated

values of the mean free path for electron enerqies in the range of 5 eV to

10 keV for Cu, Ag, and Au.

46
Division 533, Technical Activities (cont'd)

Also developed was a theoretical formulation of the screening problem

at an interface. This calculation, from the start, has the main features

of the geometrical situation built in. The focus is on the influence of

the geometry on the effective Coulomb interaction between two charged

particles. This geometrical influence generally enters on two levels.

Provided one properly includes the presence of an interface (global

level), one can go very far in using a bulk response function. The local

geometrical information then enters as a correction in most cases (in some situations it is crucial) to the calculation based on the bulk response

function. The result is a completely general expression for the Coulomb

interaction between two test particles in the presence of an interface in

which the local and global effects of the geometry are separated. The

potential is given for the two test-particles outside, inside, or on either side of the interface, and appropriate limits are investigated.

Polarized Photoemission Studies of Magnetic Systems (R. Celotta and

D. Pierce)

Last year we mentioned a new effort in collaboration with AT&T Bell

Laboratories and Brookhaven National Laboratory to employ spin-polarized,

angle-resolved photoemission to study surface magnetism. This pilot

effort has been greatly expanded in scope by the addition of a large

number of prominent col laborators to form a Materials Research Group

(MRG). The NSF-supported MRG consists of eleven principal investigators

from the following institutions: AT&T Bell Labs, NSLS-Brookhaven National

Laboratory, Argonne National Laboratory, Northwestern U., Rice U.,

U. of Texas at Austin, Naval Research Laboratory, U. of California at

Irvine, and our own Group at NBS. The focus of the effort will be to

study both bulk materials and epitaxial ferromagnetic mono-, b i - , tri- and

multi-layer materials. Investigations will include ground state magnetic

properties, testing local density theory predictions, surface magnetic

critical phenomena, spin-dependent photo-excitation, and energy- and

wave-vector- resolved electron spectroscopy. Because of the increasing

importance of interfaces and multi-layered structures, the experimental

station will include a molecular beam epitaxy apparatus for fabricating

unique magnetic multi-layered structures. A component of this research

will be aimed at improving the photon flux available from the U-5 beam

port on the NSLS UV storage ring. Our MRG has been designated as an insertion device team and will be installing a new undulator to provide a greatly enhanced photon flux for use in spin-polarized photoemission

experiments

.

This effort in understanding exotic magnetic structures will complement

our effort in magnetic mi crostructure (SEMPA) and physical and electronic

mi crostructure (STM) and greatly enhance our ability to understand the

macroscopic physical properties of matter through study of their

microscopic structure.

47
Division 533, Technical Activities (cont'd)

PHOTON PHYSICS GROUP

The Photon Physics Group investigates the interaction of

electromagnetic fields on atoms and molecules in various environments in

support of radiation measurements and standards programs important to NBS

and the outside technical community. This work includes theoretical and

experimental studies on the electronic structure of atomic and molecular

systems in field free environments and in strong external fields. The

group has specialized in ionization phenomena and in nonlinear or multiphoton laser-atom interactions. Studies are currently focused on molecular excitation dynamics, shell contraction in atoms, multiphoton

transitions, atoms in high electric and magnetic fields, and the structure

of highly excited atoms. Collaborative work is directed toward

ultrasensitive analysis through resonant multiphoton ionization, the

measurement of picosecond VUV pulses by nonlinear cross correlation

techniques, the development of a laser plasma VUV source, and the

identification of highly excited atomic states suitable for a soft x-ray

laser. For many of the activities, synchrotron radiation from NBS-SURF-II

is used as a source of tunable vacuum ultraviolet and soft x-ray

r ad i at ion.

Ultrasensitive Trace Analysis (T. Lucatorto, C. Clark, R. Bonanno, and

C. Johnson)

This is a collaborative effort with the Mass Spectrometry Group in

the NBS Center for Analytical Chemistry having the goal of developing a resonance ionization mass spectrometr ic (RIMS) capability with sub

part-per-b i 1 1 ion isotopic abundance sensitivity. Present thermal

ionization mass spectrometers have an ultimate isotopic abundance

sensitivity of about one part in 107

. By putting isotopic selectivity

into the resonance ionization step, we hope to improve the overall

sensitivity by three to five orders of magnitude. Since the optical

isotope shift for most elements is in the range of 0.1 to 5 GHz, this

selectivity can only be achieved by a high resolution laser system used in

a Doppler-free mode.

We have completed development on a high resolution pulsed dye amplifier having a bandwidth of about 150 MHz and output energy of 25 mj. The

new system was used to make the first measurements of the 9 Be: 1J Be

isotope shifts in several two-phcton transitions (2s2 1 S -*• 2s5s L S,

2s6s 1 S, 2s7s 1 S, 2s5d *0, 2s6d 1 D). The isotopic selectivity observed in

the ionization process was greater than 1:3000, but this cannot at the

present time be translated into a related enhanced abundance sensitivity

(~ 1: 10 10

) because of a limitation of the overall sensitivity (~1:107

) due to the present low efficiency of sample utilization. To overcome this

problem, we have recently begun studies on pulsed laser desorption as a method of atomization matched to the duty cycle of the ionization laser.

Initial results are very promising.

48
Division 533, Technical Activities (cont'd)

Two new-postdoc projects related to this work are a krypton ion-beam

isotope separation experiment and an experiment on laser-induced

colli sional ionization.

The krypton work actually has two goals: in the short term the

radiation from the charge exchange and laser excitation section of a reci rcul ati ng ion beam will be investigated as a potential VUV standard

source; the long term calls for the efficient reci rcul ation of laserexcited, laser-ionized krypton in a mass spectrometer storage ring for

isotopic abundance analysis in the sub-part-per-tri 11 i on range. This work

has been developed into a collaboration with the Radiometric Physics

Division.

Studies of laser-induced colli sional ionization are being done in a collaborative effort with the U. of Maryland. The initial experiments

to measure the associative ionization process, Na*(3p) + Na + h v Na„ +

e, using, for the first time, a cw laser to control the process. Sucn

measurements should prove to be much more reliable and accurate than

previous measurements made with pulsed lasers, and should yield knowledge

on charge exchange rates that could have deleterious effects on the

selectivity of several resonance ionization mass separation schemes.

Photoabsorption of Laser-Ionized Species (T. Lucatorto, C. Clark,

J. M. Bridges, C. Cromer, and B. Sonntag)

Our group has a unique capability to measure the VUV photoabsorption

(between 8 nm and 65 nm) of laser-excited and laser-ionized atoms. The

instrumentation includes a state-of-the-art VUV spectrometer with a 1024

channel photoelectric detector, a 20 ns pulsed VUV source, and several

MW-scale, pulsed, tunable dye lasers. During this year we have added a high temperature (up to 2500 C) heat-pipe oven and a mode-locked Nd:YAG

laser capable of powers of 0.3 GW for durations as short as 30 ps. The

new heat-pipe oven will allow us to study a large number of the transition

and rare earth metals, and the new laser will enable us to produce sub-ns

VUV pulses.

Photoabsorption studies of laser-excited and laser-ionized atoms have

uncovered the dramatic effects of relatively small changes in electron

screening on orbital collapse. In collaboration with a visiting scientist

from the University of Hamburg, we have completed measurements of the

3p-photoabsorption of the calcium ground state (Ca: 4s 2 ^q) , the lowest

excited states (Ca: 4s4p 3 P

0

, 1>2 ), and the ion ground state

(Ca + : 4s 2s ) . The absorption spectrum of the excited state shows a marked qualitative difference from the absorption spectrum of both the

neutral ground state and the ion. An explanation for these changes

49
Division 533, Technical Activities (cont'd)

is being sought by several theorists (C.W. Clark and A.W. Weiss at NBS and

a visiting scientist from Royal Holloway College, London).

Our latest experimental work has been the 3p-photoabsorpt ion of the

manganese ground state (Mn: 3d5 4s 2 6 S), the excited states

( Mn : 3d 5 4s4p 8 P), and the ion (Mn +

: 3d 5 4s 7 S). The objective of this

research is to explain why the 3p-photoabsorpt ion in chromium

(Cr: 3d 5 4s 7 S), which displays a wel 1 -developed Rydberg series, differs

so much from the analogous photoabsorption in manganese (Mn: 3d 5 4s 2 6 S),

which has a single strong broad resonance and several much weaker

features. The photoabsorption results of the manganese ion

(Mn +

: 3d 5 4s 7 S which is isoelectronic to Cr: 3d 5 4s 7 S) show structure

which is qualitatively unlike both the chromium and neutral manganese

results. Obviously the difference in screening between the Mn + and Cr

has a crucial influence on the structure of the 3d5 - and 3d 6 -based

configurations which play a central role the 3p-photoabsorption spectrum.

We are pursuing a theoretical explanation of the effect.

Another aspect of this program, in collaboration with the Atomic arid

Plasma Radiation Division, includes the development of laser-produced

plasmas as intense, pulsed VUV sources. Our initial work was aimed at

providing relative spectral irradiance measurements for several target

materials of practical interest ( A 1 , Cu, Sn, Sm, Yb, W, and Pb). We have

recently begun to make absolute spectral irradiance measurements on a spectrometer calibrated at SURF-II in preparation for an intercompar i son with the PTB group in Germany who are using the BESSY synchrotron as the

calibration standard for their irradiance measurements. The goals of the

PTB-NBS collaboration are to develop the 1 aser-produced plasma as a standard source and to develop criteria for the laser parameters to ensure

maximum reproducibi 1 ity and reliability. An especially interesting task

will be the comparison of results obtained with the NBS Q-switched ruby

laser, the PTB Q-switched Nd:YAG laser, and the new NBS mode-locked Nd-YAG

system. The Q-switched systems produce pulses with a large amount of time

structure which varies considerably from shot to shot, while the

mode-locked system produces almost transform-limited pulses. The question

which will be addressed is the importance of short term temporal

fluctuations in the non-linear process generating the VUV plasma

emi ssion.

Angle Resolved Photoelectron Spectroscopy (ARPES) (A. Parr and J. Hardis)

The high resolution ARPES experiment has been reinstalled on the

two-meter normal incidence beamline at SURF-II. The instrument has been

outfitted with position sensitive detectors, new internal electrostat ic

shielding, a movable gas jet, and enhanced pumping. The instrument

utilizes the high spectral resolution made possible by the small beam size

at SURF-II. With this capability we will make high resolution studies of

50
Division 533, Technical Activities (cont'd)

selected molecular systems to enhance our understanding of molecular

photoionization dynamics.

A new multi-tasking computer system has been installed to run the

experiment and allows for improved data acquisition, real-time display,

and printing. This will improve cumulative data capability by as much as

a factor of 2. Additionally, an improved data reduction capability using

a micro-Vax-II has been implemented and will improve the quality and speed

of analysis significantly.

Polarized Fluorescence Studies (D. Ederer)

A series of studies has been carried out at SURF- I I using the

polarization of the synchrotron radiation beam as a probe of molecular

autoionization. These studies showed that the polarization of the

fluorescence from excited states is a direct probe of the photoionization

dynamics and of the asymmetry signatures of autoionization resonances.

The original apparatus has been modified, and a new optical bench has been

constructed to more fully exploit the high flux capabilities at SURF -II.

These modifications improve our measurement capability in the following

ways:

a) It is possible to study polarized fluorescence from molecular gases;

b) Electric fields can be applied to study threshold shifts and Stark

effects;

c) Wavelength-dispersed fluorescence can be measured;

d) A t ime-of-f 1 ight mass spectrometer has been added to detect ionic

fragmentation products that result when a molecule interacts with a photon; this module will be especially useful for use with the pumpprobe experiments that are planned.

+ First measurements have been made on the alignment of 0

2 and a paper

on the subject is currently in preparation. We are presently seeking

support for experiments to derive the heat of formation of important

atmospheric molecular species by measuring the fluorescence of

dissociative products. This work is a collaboration with the U. of

Maryland and Howard U.

Laser Prepared States (Pump-Probe Experiments) (D. Ederer and A. Parr)

A new class of experiments are being planned which will utilize both

lasers and synchrotron radiation to ionize specially-prepared excited

atomic and molecular states. We have purchased a mode-locked Nd:YAG

laser for this application, but still require a doubler and a Q switch to

51
Division 533, Technical Activities (cont'd)

complete the laser system. The hardware for the polarized fluorescence

experiment will be adapted to these experiments, as will be the high

resolution photoelectron spectrometer

.

In the interim it has been possible to continue a collaborative

research program at LURE in Orsay, France. This experiment consists of a toroidal grating monochromator connected to the ACO storage ring at Orsay,

France. A ring dye laser, stabilized to 20 MHz bandwidth, was used to

pump ground state atoms to the excited states in the atomic vapor. The

output of the monochromator and the laser intersect at right angles in the

sensitive volume of the electron spectrometer . An effusive beam of metal

vapor intersects these photon beams, and the photoelectrons produced in

the interaction zone are detected in the electron energy analyzer. This

collaborative effort has achieved several major goals:

a) We have published a Physical Review Letter reporting the oscillator

strength of autoionizing resonances • in sodium produced by transitions

of the type 2p6 3p->2p5

( 2 P 3/2 n/2 ) 3s3 P(

1

> 3p )

•

b) We have completed the measurements of the partial photoionization cross section from the 5d metastable state in barium vapor and have reported

the partial 5d cross section over the energy range 15-150 eV.

c) We have completed a book chapter for advances in Atomic and Molecular

Physics entitled "Photoionization and Collisional Ionization of Laser

Excited Atoms Using Synchrotron Radiation." In addition to scientists

from LURE, researchers from the Laboratory Aime Cotton, the Service de

Physique des Atoms et des Surfaces, CEN/Saclay, and SUNY-Stony Brook are also involved in this work.

Soft X-Ray Emission Spectroscopy Using Synchrotron Light Excitation

(D. Ederer and T. Callcott)

In a collaborative project between NBS, the U. of Tennessee, and the

ORNL, a new soft x-ray emission spectrometer was installed at NBS- SURF- 1 1 to study radiation damage mechanisms in fragile solid materials, such as the alkali halides (LiF, NaCl).

The soft x-ray spectrometer is unique. It is specially designed to

measure very low intensity radiation, with efficiencies 1000 to 10,000

higher than conventional spectrometers . This great improvement permits

measurements to be made with weaker sources, and/or with better spatial

and spectral resolution, and/or in less time (minutes instead of days).

Thus, when used to measure x-ray fluorescence from irradiated samples, it

will permit unprecedented measurements on low level impurities and damage

in solids, or on some time-dependent processes on surfaces.

52
Division 533, Technical Activities (cont'd)

The fluorescence spectra provide important information about the

electronic states of all the light elements (ZOO). These elements are abundant and technologically important. The measurements can be used to

study the properties of alloys, material impurities, clusters, surface

layers, organics, and other fragile materials. The initial studies at

SURF- 1 1 were on systems of interest to materials scientists, such as the

alkali halides which are commonly used as UV excimer laser windows.

After a productive year at SURF- II, the instrumentation was moved to

the NSLS facility at Brookhaven in March, 1986, where the full wavelength

range of the instrument, 50 nm to 1.2 nm (20 eV to 1 KeV), could be

exploited. At NSLS we are now studying: the electronic structure of

dilute aluminum-magnesium and aluminum-lithium alloys, important as an electrolyte in advanced batteries; bonding in alkali halides and layered

compounds, to obtain a better understanding of surface layers; and thin

films of aluminum implanted with rare gas atoms, to try to understand the

physics of the band structure of the solid rare gases. In this work, we will be entering into new collaborations with scientists from the U. of

Utah, the U. of Hawaii, and the U. of Connecticut. Based on the

performance of the instrument and the preliminary results obtained so far, we have proposed additional studies of boundaries and interfaces in

silicon compounds, doped silicon crystals, and other systems of importance

in the fabrication of semiconductor devices. Another area that can be

explored with this measurement capability is the emission spectra of solid

inert gases, their alloys, and impurities embedded in the rare gas

matrix.

The uniqueness of these developments has attracted considerable

attention, and the soft x-ray measurement capability has been recognized

by a 1986 I R- 100 award from Research and Development magazine. The award

was granted jointly to NBS, ORNL, and the U. of Tennessee for developing a soft x-ray emission spectrometer that can measure weak x-ray emission

spectra with efficiencies 1000 to 10,000 higher than conventional

spectrometers in the energy range 20 eV to 1 KeV.

Development of a Measurement Program to Use the Time Structure of the

Electron Beam at SURF (D. Ederer, R. Madden, and L. Hughey)

We are planning a measurement program that makes use of the time

structure of the radiation beam at SURF- II. Many important technical

phenomena take place on a time scale between 10“9 and 10" 13 seconds. For

example, typical chemical reactions and molecular vibration times are in

this time domain. In fact there is a whole new scientific research area devoted to studying phenomena occurring on the picosecond time scale.

Synchrotron radiation from SURF-II is a source of pulsed (1 ns) VUV

radiation that allows excitation in a "gentle" enough way that chemical

reactions can be easily induced. Once this sample of excited molecules is

53
Division 533, Technical Activities (cont'd)

produced, it can be synchronous ly probed by a laser locked to the storage

ring radio frequency.

The first step in this program is to study the SURF- 1 1 electron bunch

profile and its stability. To carry out this objective we have ordered a laser moae-lockea to the ring frequency. During the coming year, we expect to determine the dynamics of the beam to understand what time

resolution can be achieved. We are going to try to use alkal i -hal ide

excitons as the time correlator to relate the time history of the

synchrotron pulse to the laser pulse.

We have submitted a proposal to the Air Force Office of Scientific

Research on this topic, because we believe the technique could have

important consequences for studying all types of pulsed VUV sources. We

have established a cooperation with the U. of California at Berkeley and

with Bell Laboratories to achieve some of these measurement goals. This

work will be performed also in collaboration with staff from the Far UV

Physics Group.

Electric Field Effects (E. Saloman and D. Kelleher)

This program studies the effect of electric fields on the absorption

cross sections and autoionization rates of atoms and molecules. While

awaiting the availability of the U. of Maryland/NRL high resolution

spectrometer at SURF- II, we have continued our study of the effect of

electric fields on autoionizing Ba states using multi-color, multi-photon

laser excitation. Three dye lasers are used to reach odd parity states,

and two dye lasers are used to reach even parity states. We have measured

the Stark manifold of the 5d 3/2 82. autoionizing states in Ba. Due to the

non-spher ical 5d ion core, the manifold is more complex than for similar

6 s n£ bound states. Calculations of the Stark manifold in jK coupling are

in good agreement with the experimental observations for both

polarizations. We are currently planning an experiment to study the

effects on the autoionization rates of coupling the autoionizing state to

an unpopulated bound state.

This work is a collaboration with the Atomic and Plasma Radiation

Division .

X-Ray Attenuation Cross Sections (E. Saloman and M. Berger)

The NBS data base of experimental attenuation coefficients (total

absorption cross sections) was compared to cross sections obtained using

two widely used sets of absorption cross section values: the

semi-empirical set of recommended values produced by Henke et al. and a theoretical set of recommended values calculated by Scofield (and extended

at our request down to 0.1 keV). This comparison was carried out, in both

54
Division 533, Technical Activities (cont'd)

tabular and graphical form, over the energy range 0.1-100 keV. We

evaluated whether Scofield's calculation should be subject to a renormal i zat ion from a Hartree-Sl ater to a Hartree-Fock atomic model and

determined that the experimental data tend to argue against such

renormal ization. A bibliography of the NBS data base has been produced in

conjunction with this comparison. The results of this work are due to

appear as NBS Internal Reports.

We are now evaluating the possibility of calculating these cross

sections ourselves using state-of-the-art relativistic wave function

codes. This work is a collaboration with the Ionizing Radiation Division

and the Atomic and Plasma Radiation Division.

Atomic and Molecular Theory (C. Clark)

Theoretical work in the Photon Physics Group deals primarily with

atomic absorption in the far ultraviolet/soft x-ray region, and with

multiphoton processes. The main focus of this work is upon multiplyexcited states. Such states often make dominant contributions to these

processes, and their basic physics is in many respects still poorly understood.

Ab initio calculations and analysis of data on photoabsorption by Ca,

Ca+

, Cr, Mn, and Mn + in the 3p excitation region (~50 eV) , are being

carried out in conjunction with the experimental work of the group.

Studies of multiphoton processes in the past year have been concerned

with the excitation of doubly-excited states of. alkaline earth atoms,

particularly Be and Mg. These states are of direct interest to the

group's ultrasensitive trace analysis effort, but they are also of

interest as relatively simple prototypes of multiply-excited states.

During the year, an analysis of the Mg 3p2 X S autoionizing state was com- pleted; this was a natural extension of the work done previously on the

analogous 2p2 X S state of Be. Current work on Be is concerned with the 1 D Rydberg series in the discrete spectral region, which interacts strongly

with the 2p2 X D state. The 10 Be: 9 Be isotope shifts in this series have

been shown to be very sensitive to the degree of configuration interaction, and an experimental program to measure them is being carried out in

collaboration with the NBS Center for Analytical Chemistry.

Other work on multiphoton processes has investigated the possibility

of observing two-photon absorption at 18.2 nm, using the soft x-ray laser

at the Princeton Plasma Physics Laboratory. Several promising candidate

experiments have been identified. A new initiative to convert large

photoionization computer codes to calculate two-photon absorption processes in complex atoms has been started, in collaboration with a visiting

55
Division 533, Technical Activities (cont'd)

scientist from Royal Holloway and Bedford New College of the U. of London

( Engl and)

.

A review of atomic negative ion resonances is underway in collaboration with the Australian National U.. This has resulted in some new classification schemes for these resonances, which are thought to indicate

more accurately the'nature of electron correlations than previous schemes

have done. It is anticipated that a comprehensive review article will be

completed late in 1986.

Studies of the role of orbital term dependence and electron correlation in core-excited states for complex atoms have continued, with attention to d- she 1 1 excitation of atoms in the rare-earth transition region

(Cs through Ce) . The effects of term dependence in excited f states have

been found to be more extensive than was thought previously. Most other

work in this field has concentrated on the role of the dipole exchange

interaction; in configurations such as p

5 d and d9 f, this interaction is*

strongly repulsive in the optically favored ( 1 P° ) channel, and it causes

the excited orbital to lie much further away from the open-shell core than

would be predicted in the standard average-of-conf igur at ion approximation.

This effect is responsible for the placement of most of the photoabsorption oscillator strength in the continuous, rather than the discrete,

portion of the atomic spectrum.

Our work has ‘Shown that other interactions can also have such an effect. In the d

9 f configuration, for example, the direct quadrupole and

exchange quadrupole interactions produce potential barriers in the 1 G’ and

1 F° channels respect i ve ly. Similar effects occur in the p5 f and sf

configurations. Although these states cannot be excited by

photoabsorption because of dipole selection rules, they do figure

prominently in electron-impact excitation. Analysis of electron energy

loss data, done in collaboration with groups from the U. of Innsbruck

(Austria) and York (England), has identified some of these non-dipole

excitations. We believe that a comprehensive study of excitation channels

in this energy region will contribute to the understanding of those which

are specifically relevant to photoabsorpt ion. In particular, observation

of similar phenomena in dipole and non-dipole allowed channels may resolve

the issue of whether the "giant resonances" in atomic photoabsorption are due to collective oscillations of an electron shell.

56
SPONSORED WORKSHOPS, CONFERENCES, AND SYMPOSIA

Division 533, Radiation Physics

C. W. Clark organized a Symposium on Physics of X-ray Lasers, 1986 Annual

Meeting of the Optical Society of America.

D. T. Pierce was Vice Chairman of the Gordon Conference on Electron

Spectroscopy, Wolfeboro, NH, July 14-18, 1986.

57
INVITED TALKS

Division 533, Radiation Physics

1. Bonanno, R.E., "Ultrasensitive Laser Isotope Analysis of Krypton in

an Ion Storage Ring," Lawrence Livermore Laboratory, Livermore, CA,

January 29, 1986.

2. Bonanno, R.E., "Multiphoton Excitation of Autoionizing States of Magnesium," Atom Sciences and Oak Ridge National Laboratory, Oak Ridge,

TN, February 26, 1986.

3. Bonanno, R.E., "Multiphoton Excitation of Autoionizing Stages of Magnesium," Lawrence Livermore National Laboratory, Livermore, CA, April

9, 1986.

4. Bonanno, R.E., "Resonance Ionization Mass Spectrometry: Applications

in Atomic Physics and Analytical Chemistry," Department of Chemistry,

William Paterson College, Wayne, NJ, April 22, 1985.

5. Bonanno, R.E., "Ultrasensitive Laser Isotope Analysis of Krypton in an Ion Storage Ring," Resonance Ionization Spectroscopy Conference,

Swansea, Wales, September 9, 1986.

6. Celotta, R.J., "New Techniques in Microscopy: Scanning Tunneling and

Polarized Electron Microscopy," Pittsburgh Conference on Analytical

Chemistry and Applied Spectroscopy, Atlantic City, March 10-14, 1986,

NJ.

7. Celotta, R.J., "Viewing Surface Magnetism," Research Advisory

Committee Staff Research Seminar Series on Magnetism, NBS, January

17, 1986.

8. Celotta, R.J., "New Methods of Electron Microscopy," Colloquium,

Joint Institute for Laboratory Astrophysics, Boulder, CO, April 21,

1986.

9. Celotta, R.J., "New Techniques in Microscopy: Scanning Tunneling and

Polarized Electrons," Spring Symposium of the New England Society for

Electron Microscopy, Woods Hole, MA, May 10, 1986.

10.

Celotta, R.J., "Surface Measurement by Electron Polarization and

Scanning Tunneling Microscopy," Vacuum '86 Processing Technology,

Nashua, NH, June 9, 1986.

58
Division 533, Invited Talks (cont 1 )

11. Celotta, R.J., "Electron Polarization Microscopy and Scanning

Tunneling Microscopy: New Ways to Image Surfaces," Joint Meeting of

American Vacuum Society and IEEE Magnetics Society, Rochester, NY,

June 12, 1986.

12. Clark, C.W., "Excited Atoms in Electric and Magnetic Fields,"

Chemical Physics Seminar, University of Maryland, College Park, MD,

October 2, 1985.

13. Clark, C.W., "Autodetaching States of Negative Ions," First

International Conference on Laser Science, Dallas, TX, November 18,

1985.

14. Clark, C.W., "Rydberg States in Electric and Magnetic Fields,"

Physics Colloquiim, University of Delaware, Newark, DE, December 4,

1985.

15. Clark, C.W., "Highly Excited Atoms in Electric and Magnetic Fields,"

Australian National University, Canberra, Australia, January 23,

1986.

16. Clark, C.W., "Autodetaching States of Negative Ions," University of

Tasmania, Hobart, Tasmania, Australia, January 29, 1986.

17. Clark, C.W., "Multiphoton Excitation of Autoionizing States,"

Workshop on Multiphoton Ionization of Atoms by Strong Fields,

University of Paris, Orsay, France, April 29, 1986.

18. Clark, C.W., "Doubly-Excited States of Negative Ions and Atoms,"

Mathematics Colloquiim, Royal Holloway and Bedford New College,

University of London, Egham, Surrey, England, June 13, 1986.

19. Clark, C.W., "Giant Resonances in the Transition Regions of the

Periodic Table," NATO Advanced Study Institute on Giant Resonances in

Atoms, Molecules, and Solids, Les Houches, France, June 18, 1986.

20. Ederer, D.L., "Photoionization from Excited States: A Technique to

Understand Atomic Correl at ions, " Advanced Light Source (ALS)

Workshop, Berkeley, CA, November 13, 1985.

21. Ederer, D.L., "Synchrotron Radiation as a Tool to Aid the Study of

Atomic Collisions," Advanced Light Source (ALS) Workshop, Berkeley,

CA, November 14, 1985.

22. Ederer, D.L. "Autoionizing Resonances: Peaks, Valleys, and

Correl at ion, " Southeastern Section of the American Physical Society,

Athens, GA, December 2-3, 1985.

59
Division 533, Invited Talks (cont'd)

23. Ederer, D.L., "Autoionizing Resonances: Peaks, Valleys, and

Correlation," University of Central Florida, Orlando, FL, April 24,

1986.

24. Ederer, D.L., "Laser-Synchrotron Pulse-Probe Experiments,"

Southeastern Universities Research Association (SURA), Synchrotron

Radiation Workshop, Atlanta, GA, May 12-16, 1986.

25. Hardis, J.H., "Photoionization of H

2 ," Center for Basic Standards,

NBS Colloquium, April 23, 1986.

26. Johnson, B.C., "Transition Probability of the A1 II 2669 A Intersystem Line," Goddard Space Flight Center, Greenbelt, MD,

January 13, 1986.

27. Johnson, B.C., "Experimental Studies of Laser-Induced Collisions,"

University of Nevada, Reno, NV, June 24, 1986.

28. Kelley, M.H., "Spin Dependence in Scattering of Spin-Polarized

Electrons from Optically Pumped Sodium Atoms," Annual Meeting of the

American Physical Society, Division of Atomic, Molecular, and Optical

Physics, Eugene, Oregon, June 20, 1986.

29. Klebanoff, L.E., "Photoelectron Spectroscopy Studies of Cr (001

)

Surface Magnetism," International Workshop on’the Magnetic Properties

of Low Dimensional Systems, Taxco, Mexico, January 7, 1986.

30. Lucatorto, T.B., "Transient State Spectroscopy in the VUV:

Instrumentation and Applications," Princeton University, Princeton,

NJ, December 10, 1985.

31. Lucatorto, T.B., "Observation of Conventionally Inaccessible Atomic

Continua," University of Virginia, Charlottesville, VA, March 26,

1986.

32. Lucatorto, T.B., "The Photoionization of Excited States and Ions

Using Many Photon and Multiphoton Technigues," University of Toronto,

Canada, April 8, 1986.

33. Lucatorto, T.B., "High-Resolution Laser Techniques in Resonance

Ionization Mass Spectroscopy," Department of Energy Workshop,

Seattle, WA, April 29, 1986.

34. Madden, R.P., "SURF-II, Programs and Opportunities," Synchrotron

Radiation Facilities Workshop, Brookhaven National Laboratory, Upton,

NY, October 17, 1985.

60
Division 533, Invited Talks (cont'd)

35. Madden, R.P., "SURF-II Beamline for VUV and X-Ray Research Related to

Materials Science," Southeastern University Research Association

(SURA), Synchrotron Radiation Workshop, Atlanta, GA, May 12-16,

1986.

36. McClelland, J.J., "Spin Polarized Superelastic Scattering from

Sodium," Joint Institute of Laboratory Astrophysics, Boulder, CO,

October 1986.

37. Ott, W.R., "NBS-SURF II: Characteristics and Opportunities for

Research," Southeastern Universities Research Association (SURA),

Synchrotron Radiation Workshop, Atlanta, GA, May 8-9, 1986.

38. Ott, W.R., "XUV Radiometric Standards at NBS," SPIE 30th Annual

Technical Symposium, San Diego, CA, August 17-22, 1986.

39. Parr, A.C., "Future Directions for Atomic and Molecular Physics,"

Workshop on Advanced Soft X-Ray and Ultraviolet Synchrotron Source,

University of California, Berkeley, CA, November 13-15, 1985.

40. Parr, A.C., "Photoionization Studies Using Synchrotron Radiation,"

Hebrew University, Jerusalem, Israel, February 3, 1986.

41. Penn, D.R., "A General Expression for the Coulomb Interaction in the

Presence of a Surface," American Physical Society, Las Vegas, Nevada,

March 31, 1986.

42. Pierce, D.T., "Spin Polarized Inverse Photoemission in Panel on Experimental Methods in Surface Magnetism," International Colloquium

on Magnetic Films and Surfaces, Asilomar, CA, September 2, 1985.

43. Pierce, D.T., "Investigations of Surface Magnetism Using Spin

Polarized Inverse Photoemission," Mexican National Conference on Surfaces and Interfaces, Monterrey, Mexico, October 18, 1985.

44. Pierce, D.T., "Spin Polarized Electron Studies of the Magnetic

Properties of Thin Films and Surfaces," Control Data Corporation,

Minneapolis, MN, October 28, 1985.

45. Pierce, D.T., "Spin Polarized Electron Studies of the Magnetic

Properties of Thin Films and Surfaces," Universidade Feral

Fluminense, Niteroi, Brazil, December 4, 1985.

61
Division 533, Invited Talks (cont'd)

46. Pierce, D.T., "Investigation of Surface Magnetism Using Spin

Polarized Electrons," Centro Brasileiro de Pasquisas Fisicas, Rio de

Janeiro, Brazil, December 6, 1985.

47. Pierce, D.T., "Magnetic Properties of Surfaces Investigated by Spin

Polarized Electron Beams," International Worksnop on the Magnetic

Properties of Low Dimensional Systems, Taxco, Mexico, January 6,

1986.

48. Pierce, D.T., "Electron Spin Polarization Analyzers," National

Science Foundation, Materials Research Group (NSF/MRG) Site Visit,

Brookhaven National Laboratory, Upton, NY, March 24, 1986.

49. Pierce, D.T., "Spin Polarized Electron Phenomena," Naval Research

Laboratory, Washington, DC, May 14, 1986.

50. Pierce, D.T., "Surface Magnetism-Experimental Studies Using

Electrons," Defense Advanced Research Projects Agency (DARPA)

Workshop on Magnetism and Magnetic Materials, La Jolla, CA, July 21,

1986.

51. Pierce, D.T., "Scanning Electron Microscopy with Polarization

Analysis," Physics Seminar, University of California, La Jolla, CA,

July 22, 1986.

52. Pierce, D.T., "Spin Polarized Auger Spectroscopy and SEMPA Studies of

Magnetism at Surfaces, Stanford Electronics Laboratory Seminar,

Stanford University, Stanford, CA, July 25, 1986.

53. Unguris, J., "Spin Polarized Electron Studies of Magnetic Materials,"

Kodak Research Laboratories, Rochester, NY, October 16, 1985.

54. Unguris, J., "Magnetic Imaging Using Scanning Electron Microscopy

with Polarization Analysis," Magnetics Technology Center Seminar,

Carnegie-Mellon University, Pittsburgh, PA, October 29, 1985.

55. Unguris, J., "Magnetic Microstructure Study Using Scanning Electron

Microscopy with Polarization Analysis," American Physical Society,

Las Vegas, NV, March 1986.

62
PUBLICATIONS

Division 533, Radiation Physics

Berry, H.G., and Hardis, J.E., Measurements of the ls2s 3 S, -ls2o3 P

c

, 2 Wavelengths in Heliumlike Neon, Phys. Rev. A 33_, 2778 (1986)."

Bizau, J.M., Wuilleumier, F., Ederer, D.L., Keller, J.C., LeGouet, J.L.,

PicquS, J.L., Carre, B., and Koch, P., Oscillator Strength Measurements of

Even Parity Autoionization Resonances in Neutral Sodiim from Combined

Synchrotron Radiation Laser Excitation, Phys. Rev. Lett, _55_, 1281 (1985).

Bizau, J.M., Cubaynes, D., Gerard, P., Wuilleumier, F.J., Picque, J.L.,

Ederer, D.L., Carre, B., and Wendin, G. , Experimental and Theoretical

Determinations of the 5d Photoionization Cross Section in Laser-Excited

Bar inn Atoms Between 15 eV and 150 eV Photon Energy, Phys. Rev. Lett. 57,

306 (1986).

Bonanno, R., Boulmer, J., and Weiner, J., On the Determination of the

Absolute Rate Constant for Associative Ionization in Crossed Beam Collisions Between Na 3

2 P, /7 Atoms, Comments on Atomic Molecular Physics 16,

109 (1985). ~

Bonanno, R.E., Clark, C.W, and Lucatorto, T.B., Multiphoton Excitation of

Autoionizing States of Mg : I : Lineshape Studies of the 3p2 X S State, Phys.

Rev. A 34, (1986)

.

Bridges, J.M., Cromer, C.L, and Mcllrath, T.J., Investigation of a Laser

Produced Plasma VUV Light Source, Appl. Opt. 25_, 2208 (1986).

Celotta, R.J., New Techniques in Microscopy: Scanning Tunneling and

Polarized Electron Microscopy, Abst. for Pittsburgh Conference (1985).

Celotta, R.J., Review of "Polarized Electrons at Surfaces" by J. Kirschner, Appl. Opt. 25_, 1860 (1986).

Clark, C.W., Autodetaching States of Negative Ions, Proceedings of the

First International Conference on Laser Science , ed. R.C. Stwalley

(American Institute of Physics, NY 1986).

Clark, C.W., Littman, M.G., Mcllrath, T.J., Miles, T., Skinner, C.H.,

Suckewer, S., and Valeo, E., Possibilities for Achieving X-ray Lasing

Action by Use of High-Order Multiphoton Processes, J. Opt. Soc. Am. B 3,

371 (1986).

Cook, W.E., and Cromer, C.L., Multichannel Quantum Defect Theory and an Equivalent N Level System, Phys. Rev. A 32, 2725 (1985).

63
Division 533, Publications (cont'd)

Cooper, J.W., and Clark, C.W., Field Effects on Rydberg Atoms, J. Res.

Nat. Bur. Stds. 90, 316 (1986)

.

Dragoset, R.A., Young, R.D., Layer, H.P., Mielczarek, S.R., Teague, E.C.,

and Celotta, R.J., Scanning Tunneling Microscopy Applied to Optical

Surfaces, Opt. Lett. 11, 560 (1986).

Feigerle, C.S., Seiler, A., Pena, J.L., Celotta, R.J., and Pierce, D.T.

,

CO Chemisorption on Ni(llO): Effect on Surface Magnetism, Phys. Rev.

Lett. 56, 2207 (1986).

Galvez, E.J., Livingston, A.E., Mazure, A.J., Berry, H.G., Engstrom,

L., Hardis, J.E., Somerville, J.P., and Zei, D., Measurement of the

2

3 S-,-2 3 P, Transition Wavelength in Helium-like Ti 20 +

, Phys. Rev. A 33,

366} (19§6). —

Hill, W.T., Quenching of Resonant Laser-Driven Ionization by High Buffer

Gas Pressures, J. Phys. B JL9_ , 359-368 (1986).

Jones, R.K., Absolute Total Cross Sections for the Scattering of Low

Energy Electrons by CC1 U , CCUF, CC1 9 F 9 , CC1F, , and CFU , J. Chem. Phys.

84, 813 (1986).

Keller, J., Bonanno, R., Wang, M.-X., DeVries, M., and Weiner, J., Determination of Internal Energy Distribution in Na^* Produced by Associative

Ionization Collisions in Crossed Beams, Phys. Rev. A _33, 1612 (1986).

Kelley, M.H., Celotta, R.J., and McClelland, J.J., Spin Dependence in

Super- elastic Electron Scattering From Excited Sodium, Proc. of

Department of Energy (DoE) Atomic Physics Contractor's Meeting (1986).

Klebanoff, L.E., Baca, A.G., Schulz, M.A., Paparazzo, E., and Shirley,

D.A., The Initial Oxidation of Cr(001), Surf. Sci. 171 , 255 (1986).

Klebanoff, L.E., Robey, S.W., Liu, G., and Shirley, D.A., Photoelectron

Spectroscopy Studies of Cr(001) Near-Surface and Surface Magnetism, J. Magn. Mag. Mat. 54-57 , 728 (1986).

Klebanoff, L.E., and Shirley, D.A., Surface Dependence of the Cr(001) 3s

Photoemission Lineshape, Phys. Rev. B, Vol. 33 , 5301 ( 1986).

Krause, M.O., Svensson, W.A., Carlson, T.Z., Leroi, G., Ederer, D.E.,

Holland, D.M.P., and Parr, A.C., Photoeffect in the 4d Subshell of Atomic

Silver Between 14 and 140 eV, J. Phys. B _18, 4069 (1985).

Kowalski, M.P., Fritz, G.G., Cruddace, R.G., Unzicker, A.E., and

Swanson, N., Quantum Efficiency of Cesium Iodide Photocathodes at Soft

X-Ray and Extreme Ultraviolet Wavelengths, Appl. Opt. 25_, 2440 (1986).

64
Division 533, Publications (cont'd)

McClelland, J.J., Kelley, M.H., and Celotta, R.J., Electron-Atom Collision

Studies Using Optically State Selected Beams: Superelastic Scattering,

Abst. of Contributed Papers for ICPEAC XIV (1985).

McClelland, J.J., Kelley, M.H., and Celotta, R.J., Spin Dependent

Superelastic Scattering from Pure Angular Momentum States of Na(3P),

Phys. Rev. Lett. _56_, 1362 (1986).

McClelland, J.J., Kelley, M.H., and Celotta, R.J., ERRATUM - Spin

Dependent Superelastic Scattering from Pure Angular Momentum States of

Na(3P) , Phys. Rev. Lett. 56, 2771 (1986).

Mcllrath, T.J., and Lucatorto, T.B., Techniques for Studying

Autoionization in Isoelectronic and Isonuclear Sequences, Proc. of

Workshop on Some Aspects of Autoionization in Atoms and Small Molecules,

Argonne, Illinois, May 1985.

Mcllrath, T.J., Sugar, J., Kaufman. V., Cooper, D., and Hill, W., LaserDriven Ionization of Cs and Absorption Spectrum of Resultant Cs + Vapor, J. Opt. Soc. B 3 , 398 (1985).

Moore, L.J., Fassett, J.D., Travis, J.C., Lucatorto, T.B., and Clark,

C.W., Resonance Ionization Mass Spectrometry of Carbon, J. Opt. Soc. B 2_, 1561 (1985).

Ott, W.R., Canfield, L.R., Ebner, S.C., Hughey, L.R., and Madden, R.P.,

XUV Radiometric Standards at NBS, SPIE Proc. 689 , 178 (1986).

Parr, A.C., Synchrotron Radiation: Applications to Chemistry, book

chapter in New Directions in Chemical Analysis , Ed: B.L. Shapiro (Texas A

& M University Press, College Station, TX 1985).

Parr, A.C., and Ebner, S.C., SURF-II Users' Guide, March (1985).

Penn, D.R., Ape 11, S.P., Girvin, S.M., Spin Polarization of Secondary

Electrons in Transition Metals; Theory, Phys. Rev. B _32_, 7753 (1985).

Penn, D.R., Ape 11, S.P., and Girvin, S.M., Spin Polarized Secondary

Electrons: Theory, J. Magn. Mag. Mat . , 54-57 , 1041 (1986).

Pierce, D.T., Seiler, A., Feigerle, C.S., Pena, J.L., and Celotta, R.J.,

Spin Polarized Inverse Photoemission Studies of Surface Magnetism and

Electronic Structure, J. Magn. Mag. Mat., 54-57, 3638 (1986).

65
Division 533, Publications (cont'd)

Rakowsky, G., Coherent Synchrotron Relaxation Oscillation in an Electron

Storage Ring, IEEE Trans. Nucl. Sci. NS- 32 , #5 2377 (October 1985).

Saloman, E.B., Cooper, J.W., and Mehlman, G., Photoabsorption Cross

Section of Barium from 237.9 to 120 nm, Phys. Rev. 32, 1878 (1985).

Saloman, E.B., Cooper, J.W., and Kelleher, D.E., Studies of Electric Field

Effects on Barium Autoionizing Resonances, Ed: Nayfeh and Clark, Atomic

Excitation and Recombination in External Fields , Gordon and Breach Science

Publishers (1985)

.

Seiler, A., Feigerle, C.S., Pena, J.L., Celotta, R.J.,. and Pierce, D.T.,

Chemisorption Induced Changes in Surface Magnetism and Electronic

Structure: Oxygen on Ni(llO), Phys. Rev. B 32_, 7776 (1985).

Snyder, J.J, Lucatorto, T.B., Debenham, P.H., and Geltman, S., Ultrasensitive Laser Isotope Analysis in an Ion Storage Ring, J. Opt. Soc. B 2, 1497

(1985).

Sonntag, B.F., Cromer. C.L., Bridges, J.M., Mcllrath, T.J., and Lucatorto,

T.B., Laser-XUV Excited State Spectroscopy, Proc. of the Third Topical

Meeting on Short Wavelength Coherent Radiation: Generation and Applications (Monterey, CA, March 1986).

Southworth, S.H, Parr, A.C., Hardis, J.E., and Dehmer, J.L., Channel

Coupling and Shape Resonance Effects in the Photoelectron Angular Distributions of the 3a -1 and 2a,. -1 Channels of N9 , Phys. Rev. A 33, 1020

(1986).

9 ~

Taylor, K.T., Clark, C.W., and Fon, W.C., Electron Scattering by Neon in

Resonance Regions, 5. Phys. B ^8 (1985).

Unguris J., Hembree, G.G., Celotta, R.J., and Pierce, D.T., High

Resolution Magnetic Mi crostructure Imaging Using Secondary Electron Spin

Polarization Analysis in a Scanning Electron Microscope, J. of Microscopy,

139, RP1 (1985).

‘

Unguris, J., Hembree, G.G., Celotta, R.J., and Pierce, D.T.,

Investigations of Magnetic Microstructures Using Scanning Electron

Microscopy with Spin Polarization Analysis, J. Magn. Mag. Mat., 54-57 , 1629 (1986)

.

Unguris, J., Pierce, D.T., and Celotta, R.J., Low Energy Diffuse

Scattering Electron Spin Polarization Analyzer, Rev. Sci. Instrum. _57_, 1314 (1986).

66
PUBLICATIONS IN PREPARATION

Division 533, Radiation Physics

Bonanno, R.E., Snyder, J.J., Lucatorto, T.B., Debenham, P.H., and Clark,

C.W., Ultrasensitive Laser Isotope Analysis of Krypton in an Ion Storage

Ring, Proc. of the Third International Conference on Resonance Ionization

Spectroscopy, September 8-12, 1986 (to be published).

Callcott, T.A., Tsang, K.L., Zhang, C.H., Ederer, D.L., and Arakawa, E.T.,

A High Efficiency Soft X-ray Emission Spectrometer for use with Synchrotron Radiation Excitation, Rev. Sci. Inst, (to be published).

Canfield, L.R., New Far Ultraviolet Detector Calibration Facility at NBS,

Appl. Optics (in preparat ion)

.

Canfield, L.R., and Swanson, N., Far Ultraviolet Detector Documentation,

NBS SP 250-2 (in preparation).

Celotta, R.J., and Pierce, D.T., Polarized Electron Probes of Magnetic

Surfaces, Science (to be published).

Dragoset, R.A., Young, R.D., Layer, H.P., Mielczarek, S.R., Teague, E.C.,

and Celotta, R.J., Scanning Tunneling Microscopy Applied to Optical

Surfaces, Applied Optics (in press).

Hembree, G.G., Unguris, J., Celotta, R.J., and Pierce, D.T., Magnetic

Microstructure Imaging by Secondary Electron Spin Polarization Analysis,

Proc. of the 44th Meeting of the Electron Microscopy Society of America

(to be pub 1 i shed)

.

Hill, W.H., Sugar, J., Cheng, K.T., and Lucatorto, T.B., Absorption

Spectrum of Ba*+ : 5p^ > 5p^ns,nd, to be submitted to J. Opt. Sci. B (in

preparat ion)

.

Hubbell, J.H., Gerstenberg, H.M. and Saloman, E.B., Bibliography of Photon

Total Cross Section (Attenuation Coefficient) Measurements 10 eV to

13.5 GeV, NBS IR (to be published).

Jimenez-Mier, J., Caldwell, C.D., and Ederer, D.L., Oscillator Strength

Distribution of Fluorescence from Photoionization Produced He+(n=2), Phys.

Rev. Lett, (in preparation)

.

Johnson, B.C., Smith, P.L., and Parkinson, W.H, Transition Probability of

the A1 II 2669 Angstroms Intersystem Line, Astrophys ical Journal,

September 15, 1986 (in press).

67
Division 533, Publication in Preparation (cont'd)

Kelleher, D.E., and Saloman, E.B., Stark Effect of Rydberg States with

Anistropic Ion Cores, Phys. Rev. (in preparat ion)

.

Keller, J.W., Ederer, D.L., and Hill, W. Ill, Polarized Fluorescence from

the A and B States on 02+, Phys. Rev. A (in preparation).

Kostkowski, H.J., Lean J.L., Saunders, R.D., and Hughey, L.R., Comparison

of the NBS SURF and Tungsten Ultraviolet Irradiance Standards, submitted

to Applied Optics, May 1986.

Klebanoff, L.K., Photoelectron Spectroscopy Studies of C.r(OOl) Surface

Ferromagnetism, Proc. International Workshop on Magnetic Properties of Low

Dimensional Systems, Taxco, Mexico, January 6-9, 1986 (to be published).

Klebanoff, L.E., Baca, A.G., Schulz, M.A., Paparazzo, E., and Shirley,

D.A., Dissociative Adsorption of CO and 0

? on Cr(100), and Cr(lll) in the

Temperature Range 300-1175K, Surf. Sci. (to be published).

Klebanoff, L.E., Tobin, J.G., Robey, S.W., and Shirley, D.A., The

Development of a Three-Dimensional Valence Band Structure in Ag Overlayers

on Cu(001), Phys. Rev. B (in preparation).

Klebanoff, L.E., Jones, R.K., Pierce, D.T. and Celotta, R.J.,

Spin-Polarized Inverse Photoemission Study of Ni(001) and Its

Chemisorption, Phys. Rev. B (in preparat ion)

.

Lucatorto, T.B., Hutchinson, J.M.R, and Whitaker, T.J., Exploiting the

Optical Isotope Shift for Ultrasensitive Isotopic Analysis with Lasers,

Proc. of the 1986 Annual Meeting of the American Nuclear Society (Reno,

NV, June 1986) (to be published).

McClelland, J.J., Kelley, M.H., and Celotta, R.J., State Selection in

Electron-Atom Scattering: Spin-Polarized Electron Scattering from

Optically Pumped Sodium, Proc. XIII Symposium on Physics of Ionized Gases,

Sibenik, Yugoslavia (to be published).

Parr, A.C., Southworth, S.H., and Dehmer, J.L., Shape Resonance Effects in

Photoionization of NO, Phys. Rev. (in preparat ion)

.

Parr, A.C., Dehmer, J.L., Hardis, J.E., and Southworth, S.H., Asymmetry

Parameters for Vibrat ional ly Resolved H

2

, Phys. Rev. (in preparat ion) .

Parr, A.C., Dehmer, J.L., Poliakoff, E., and Leroi, G., Polarization of

Fluorescence and Carbon Disulfide, J. Chem. Phys. (in preparat ion)

.

68
Division 533, Publications in Preparation (cont'd)

Penn, D.R., Free Electron Like Stoner Excitations in Fe, J. of Appl. Phys

.

(to be pub 1 i shed)

.

Penn, D.R., and Apell, P., A General Expression for the Coulomb

Interaction in the Presence of a Surface (submitted to Phys. Rev.).

Penn, D.R., Electron Mean Free Path Calculations Using a Model Dielectric

Function (submitted to Phys. Rev. Lett.).

Penn, D.R., Evidence for Free-Electron Like Stoner Excitation (submitted

to Phys. Rev. Lett. )

.

Penn, D.R., and Apell, P., Theory of the Effective Coulomb Interaction in

the Presence of a Surface, Solid State Communications (in preparation).

Pierce, D.T., Magnetic Properties of Surfaces Investigated by Spin

Polarized Electron Beams, Proc. of International Workshop on the Magnetic

Properties of Low Dimensional Systems, Taxco, Mexico, Springer-Verlag (to

be pub 1 i shed)

.

Pierce, D.T., Polarized Electrons at Surfaces, J. Opt. Soc. book review

(to be pub 1 i shed)

.

Saloman, E.B., and Hubbell, J.H., Critical Analysis of Soft X-ray Cross

Section Data, submitted to Nucl. Instr. and Meth.

Saloman, E.B., and Hubbell, J.H., X-ray Attenuation Coefficients (Total

Cross Sections): Comparison of the Experimental Data Base with the Recommended Values of Henke and the Theoretical Values of Scofield for Energies

between 0.1-100 KeV, NBS IR 86-3431 (in press).

Southworth, S.H., Parr, A.C., Hardis, J.E., Dehmer, J.L., and Holland,

D.M.P., Calibration of a Monochromator/Spectrometer System for the

Measurement of Photoelectron Angular Distributions and Branching Ratios,

submitted to Nucl. Instr. and Meth.

Tsang, K.L., Zhang, C.H., Callcott, T.A., Ederer, D.L., and Arakawa, E.T.,

Fluorescence Emission From Lithium Fluoride by Synchrotron Radiation Excitation, Phys. Rev. B (in preparation).

Wuilleumier, F.J., Ederer, D.L., and Picqu£, J.L., Photoionization and

Collisional Ionization of Laser Excited Atoms Using Synchrotron Radiation,

chapter in "Advances in Atomic and Molecular Physics," Volume 23 (to be

published)

.

69
TECHNICAL AND PROFESSIONAL COMMITTEE PARTICIPATION

Division 533, Radiation Physics

Robert J. Celotta

Member, General Committee, International Conference on the Physics of

Electron and Atomic Collisions.

Member, NBS Computer Network Committee.

Member, NBS PC Committee.

Member, NML EEO Committee.

Charles W. Clark

Member, Technical Program Committee, Optical Society of America 1986

Annual Meeting.

Member, Organizing Committee, IV International Conference on Multiphoton Processes.

Member, Organizing Committee, Atomic Spectra and Collisions in

External Fields II (Satellite Meeting of the XV International Conference on the Physics of Electronic and Atomic Collisions).

Chairman, Local Organizing Committee, 1988 Annual Meeting of the

Division of Atomic, Molecular, and Optical Physics of the American

Physical Society.

David L.Ederer

Member, Education Committee of the Optical Society of America.

Michael H. Kelley

NBS Advisory Group for Graphics.

NBS Atomic Physics Colloquium Committee.

Local Organizing Committee

Physical Society, Division

for 1988 Annual Meeting of the American

of Atomic, Molecular, and Optical Physics.

70
Division 533, Technical and Professional Committee Participation and

Leadership (cont'd)

Thomas B. Lucatorto

Advisory Panel, 1986 Conference on Laser Techniques in the Extreme

Ultravi olet

.

Co-chairman, 1989 International Conference on the Physics of Electron

and Atomic Col lisions.

Member, Program Committee, Resonance Ionization Spectroscopy

Conference Series.

Robert P. Madden

Chairman, International Committee for the International Conference on VUV Radiation Physics.

Member, Synchrotron Radiation Center Users' Advisory Committee for

the Stoughton Storage Rings (Tantalus and Aladdin) of the University

of Wisconsin.

Member, Advisory Editorial Board on Optics Communication .

Member, Middle Atmospheric Program International Working Group on Solar Spectral Irradiance Measurements.

Member, Council of U.S. Synchrotron Radiation Laboratory Directors.

Member, International Committee of the International Conference on X-Ray and VUV Synchrotron Radiation Instruments.

Member, Advisory Committee for the Laboratory of Laser Energetics,

University of Rochester, Rochester, NY.

Member, Optical Society of America Objectives and Policy Committee.

Member, Synchrotron Radiation Facility Working Group (Department of

Energy)

.

Member, Interagency Group for Intense Light Sources.

Member, Synchrotron Radiation Source and Research Development

Committee.

71
Division 533, Technical and Professional Committee Participation and

Leadership (cont'd)

Wi 1 1 i am R. Ott

Member, International Working Group for Middle Atmosphere Program on Solar Spectral Irradiance Measurements, 1981-1986.

Chairman, NBS-CRR Calibrations Advisory Committee.

Chairman, NBS-NML Performance Review Panel.

Daniel T. Pierce

Executive Committee, Surface Science Division of the American Vacuum

Society.

Chairman, American Vacuum Society, Surface Science Division, 1986

Nominating Committee.

Local Arrangements Committee, 6th International Conference on Solid

Surfaces, Baltimore,, MD, October 1986.

International Organizing Committee of the International Colloquium on Magnetic Films and Surfaces.

International Advisory Committee, 9th European Conferences on Surface

Science, Lucerne, Switzerland, 1987.

National Science Foundation Materials Research Group for Spin

Polarized Photoemission.

72
MAJOR CONSULTING AND ADVISORY SERVICES

Division 533, Radiation Physics

1. R.J. Celotta and D.T. Pierce consulted on the production and detection

of polarized electrons with researchers from Brookhaven, AT&T Bell

Labs, Bell Communications Corporation, University of Texas, Princeton,

Kimball Physics Corporation, Rice University, University of Oklahoma,

City College of New York, MIT, Argonne National Laboratory, Jet

Propulsion Laboratory, Perkin Elmer Corporation, and the Naval

Research Laboratory.

2. C.W. Clark advised a group at Princeton Plasma Physics Laboratory on atomic physics problems associated with x-ray laser development.

3. D.L. Ederer consulted with R. Freeman from AT&T Bell Laboratories on establishing a collaboration on laser-synchrotron, pulse-probe

experiments and time-resolved spectroscopy at SURF- 1 1

.

4. T.B. Lucatorto consulted with R. Falcone of the University of

California (Berkeley) on estalishing a collaboration to establish an ultrashort XUV measurement capability at NBS.

5. T.B. Lucatorto advised R. Falcone of the University of California

(Berkeley) on spectroscopic measurements needed to understand x-ray

laser emission from laser-produced plasmas, and proposed a collaboration to provide such measurements.

6. W.R. Ott consulted with P. Smith of Harvard College Observatory, M.

KUhne of PTB, D. Nettleton of NPL, and M. Van Hoosier of NRL on recent developments in VUV radiometry and new possibilities for

radiation standards.

7. A.C. Parr consulted with S. Southworth of Los Alamos, J. Dehmer of

Argonne National Labor ator ies , and J. West of the Daresbury

Synchrotron Radiation Laboratory on establishing a joint program on photo- ionization of molecules using synchrotron radiation.

8. D.T. Pierce consulted with R. O'Handley, MIT, on electron spin

polarization analyzers and interfacing to experiments.

9. D.T. Pierce consulted with G. J. Lapeyre and C. Quing, Montana State

University, on construction of a GaAs spin polarized electron source.

73
Division 533, Major Consulting and Advisory Services (cont'd)

10. D.T. Pierce consulted with W. Dinan and R. York, Continuous Electron

Beam Accelerator Facility, (CEBAF), Newport News, V A, on using a GaAs

cathode for the accelerator.

11. D.T. Pierce participated in Office of Naval Research meeting, Purdue

University, entitled "Research Opportunities in Magnetism for Naval

Applications."

74
JOURNAL EDITORSHIPS

Division 533, Radiation Physics

R.J. Celotta, Series Editor, Methods of Experimental Physics.

D.T. Pierce, Editorial Board, Review of Scientific Instruments.

D.T. Pierce, Editorial Board, Journal of Electron Spectroscopy and Related

Phenomena.

75
TRIPS SPONSORED BY OTHERS

Division 533, Radiation Physics Division

R. E. Bonanno presented a talk at Atom Sciences, Inc., Oak Ridge,

TN, February 26, 1986.

R. E. Bonanno presented a talk at Lawrence Livermore National Laboratory,

Livermore, CA, April 9, 1986.

R. E. Bonanno visited William Paterson College and presented a talk,

Wayne, NJ, April 22, 1985.

R. E. Bonanno attended the Resonance Ionization Spectroscopy (RIS)

Conference and presented an invited talk, Swansea, Wales, September 9,

1986.

R. E. Bonanno collaborated with Jeff Paisner at Lawrence Livermore

National Laboratory, Livermore, CA, August 19-22, 1986.

R. J. Celotta presented a talk at the 1986 Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, Atlantic City, NJ, March

10, 1986.

R. J. Celotta presented a colloquium to the Joint Institute for Laboratory

Astrophysics, Boulder, CO, April 21, 1986.

R. J. Celotta presented a talk to the New England Society for Electron

Microscopy, Woods Hole, MA, May 10, 1986.

R. J. Celotta presented a talk to the Vacuum '86-Processing Technology

Conference, Nashua, NH, June 9, 1986.

R. J. Celotta presented an invited talk to the Joint Meeting of the

American Vacuum Society and IEEE Magnetics Society, Rochester, NY,

June 12, 1986.

C. W. Clark consulted on X-Ray Laser Development at Pnnceton Plasma

Physics Laboratory, Princeton, NJ, November 14, 1985.

C. W. Clark gave a seminar at the University of Delaware, Newark, DE,

December 1, 1985.

C. W. Clark consulted on X-Ray Laser Development at Pnnceton Plasma

Physics Laboratory, Princeton, NJ , December 19, 1985.

C. W„ Clark worked on a review article in collaboration w’th Dr. Stephen

Buckman, Australian National University, Canberra, Australia, January

19-23, 1986.

76
Division 533, Trips Sponsored by Others (cont'd)

C. W. Clark attended the Fourth Australian Conference on Atomic and

Molecular Physics and Quantum Chemistry and gave a lecture, Tasmania,

Australia, January 24-27, 1986.

C. W. Clark attended the Fourth International Symposium on Quantum Optics

and presented a paper, Hamilton, New Zealand, February 9-14, 1986.

C. W. Clark consulted on X-Ray Laser Development at Princeton Plasma

Physics Laboratory, Princeton, NJ, March 13, 1986.

C. W. Clark attended a workshop organizing committee meeting, and

presented a paper, European Center for the Calculation of Atomic and

Molecular Properties, Orsay, France, April 29, 1986.

C. W. Clark consulted on X-Ray Laser Development at Princeton Plasma

Physics Laboratory, Princeton, NJ, May 27, 1986.

C. W. Clark gave an invited lecture at the NATO Advanced Study Institute

on Giant Resonances in Atoms, Molecules, and Solids, Les Houches, France,

June 18, 1986.

D. L. Ederer gave a talk at the University of Central Florida, Orlando,

FL, April 23, 1986.

B. C. Johnson visited the Center for Astrophysics and consulted with W.H.

Parkinson, P.L. Smith, and D.W. Dugnette on a collaborative experiment,

Cambridge, MA, February 26-March 6, 1986.

B. C. Johnson visited the Department of Physics at the University of

Nevada, Reno, NV, June 23-25, 1986.

T. B. Lucatorto attended the program committee meeting on Short Wavelength

Coherent Radiation and visited Roger Falcone, Lawrence Berkeley

Laboratory, Berkeley, CA, January 9-10, 1986.

T. B. Lucatorto presented a colloquium at University of Virginia,

Charlottesville, VA, March 25-27, 1986.

T. B. Lucatorto presented a seminar at the University of Toronto, Toronto,

Canada, April 8, 1986.

R. P. Madden attended an Advisory Committee Meeting, University of

Rochester, Rochester, NY, February 27-28, 1986.

77
Division 533, Trips Sponsored by Others (cont'd)

A. C. Parr visited Daresbury Laboratory to consult with John West,

Warrington, England, February 15-23, 1986.

D. T. Pierce presented a talk at Control Data Corporation, Minneapolis,

MN, October 28, 1985.

D. T. Pierce presented a talk to the Physical Electronics Division, Perkin

Elmer Corp., Minneapolis, MN, October 29, 1985.

D. T. Pierce presented a talk to the International Workshop on the

Magnetic Properties of Low Dimensional Systems, Taxco, Mexico, January

6-9, 1986.

D. T. Pierce presented a talk to the Defense Advanced Research Project

Agency (DARPA) Workshop on Magnetism and Magnetic Materials, La Jolla, CA,

July 21, 1986.

78
CALIBRATION SERVICES PERFORMED

Division 533, Radiation Physics

Type of Service

Customer

Type*

SP 250

Item No.

Number of

Calibrations

or Tests

Far UV radiometric

transfer standard

detectors (photodiode calibrations)

1,4-8 N.A. 21

Spectrometer calibrations using SURF

as an absolute source 5-7 N.A. 28

Totals 49

*Column 2: 1, calibration labs; 2, hospitals; 3, nuclear energy

establishments; 4, industry; 5, US government labs; 6, DoD

labs; 7, universities; 8, foreign governments.

79
SPONSORED SEMINARS AND COLLOQUIA

Division 533, Radiation Physics

Cohen, M.L., Physics Department, University of California at Berkeley,

"Predicting New Solids and Superconductors," April 25, 1986.

Cooke, W., University of Southern California, Los Angeles, CA, "Branching

Ratios of Short-Lived States," February 18, 1986.

Chubb, S., Naval Research Laboratory, Washington, DC, "Structural and

Electronic and Magnetic Structure Study of Chemisorption Bonding:

C ( 2X2 ) 0/N i (001) ," December 18, 1985.

Erickson, W.C., University of Maryland, College Park, MD, "Observation of

High Rydberg States in the Interstellar Medium," November 8, 1985.

Fain, S.C., University of Washington, Seattle, WA, "Structures and Phase

Transitions of Oxygen on Graphite," March 14, 1986.

Ferret, T., Lawrence Berkeley Laboratory, Berkeley, CA, "Resonant Effects

in Core Level Photoionization of Molecules," March 12, 1986.

Guntherodt, G., University of Cologne, Cologne, West Germany,

"Spin-Resolved Photoemission of Epitaxial Layers ( Fe/W( 1 10) ) and

Adsorbates (Ni(110): o,s)," June 27, 1986.

Harmin, D.A., University of Colorado, Boulder, CO, "Field Enhancement of

Dielectronic Recombination," October 18, 1985.

Hayman, C., Lawrence Livermore Laboratory, Livermore, CA, "Laser Isotope

Separation Spectroscopy as Applied to Gd," October 1, 1985.

Hertel, I.V., Department of Physics, Institute for Molecular Physics, Free

University of Berlin, West Berlin, West Germany, "Alignment and

Orientation in Collisions of Laser Excited Atoms with Electrons, Ions,

Atoms, and Molecules," February 18, 1986.

Hubert, A., University of Erlangen, Erlangen, West Germany, "Domain

Observation with a Digitally Enhanced Kerr Microscope," June 26, 1986.

Kelly, H., University of Virginia, Charlottesville, VA, "Recent Many Body

Photoionization Calculations," January 13, 1986.

80
Division 533, Sponsored Seminars and Colloquia (cont'd)

KYihne, M., Physikalisch Technische Bundesanst alt , West Germany, "VUV

Radiometry at the PTB Laboratory," September 2, 1986.

Leventhal, J., University of Missouri, St. Louis, MO, "Ionization of

Rydberg Atoms," February 13, 1985.

Mills, D., Cornell University, Ithaca, NY, "Laser Pump and X-ray Probe

Experiments at CESR," January 6, 1986.

Morgan, J.D., University of Delaware, Newark, DE, "The 1/Z Expansion for

Atoms, November 1, 1985.

Nicolaides, C.A., National Hellenic Research Foundation, Athens, Greece,

"Theory of Doubly-Excited States and the Wannier Ionization Law," October

17, 1985.

Paisner, J., Lawrence Livermore Laboratory, Livermore, CA, "Review of

AVLIS/Work on Process Development for Laser Isotope Separation,"

January 6, 1986.

Pouey, M., CNRS-University Paris Sud, France, "Stigmatic XUV Plane and

Spherical Grating Spectrometers," October 18, 1985.

Prybyla, J., Department of Chemistry, Brown University, Providence, RI,

"Phase Diagrams, Surface Structure and Desorption Kinetics for the

Hydrogen on Molybdenum (100) Chemisorption System," April 15, 1986.

Schnatterly, S., University of Virginia, Charlottesville, VA, "Band

Structure Studies by Soft X-ray Emission Spectroscopy," January 15, 1986.

Seigmann, H.C., ETH-Zurich, Switzerland, "Magnetic Measurements with

Electrons," March 13, 1986.

Sharma, J., Naval Surface Weapons Laboratory, Silver Spring, MD, "XPS

Study of Explosives," November 15, 1985.

Sheorey, V.B., Physical Research Laboratory, Ahmedabad, India, "Fluctuation Properties of Regular and Irregular Spectra and Quantum Chaos,"

January 14, 1986.

Tersoff, J., IBM, "Theory of the Scanning Tunneling Microscope," November

27, 1985.

81
Division 533, Sponsored Seminars and Colloquia (cont'd)

van der Brugt, P.J.M., North Carolina University, Raleigh, NC, "Shape

Resonances and the Excitation of Helium Autoionizing States by Electrons,"

May 20, 1986.

Wells, 0., IBM Watson Research Center, Yorktown Heights, New York,

"Studies of Magnetic Samples in the SEM," February 12, 1986.

Whitaker, T., Batelle Northwest Laboratories, Richland, WA, "HighResolution Resonant Ionization Spectroscopy," November 14, 1985.

Wuilleumier, F., University Paris Sud, France, "Present Status and Future

Developments of the Laser-Synchrotron Radiation Ionization Studies,"

November 7, 1985.

82
TECHNICAL ACTIVITIES

Division 534, Radiometric Physics

Introduction

The Radiometric Physics Division of the Center for Radiation Research

is the primary unit within NBS for carrying out the traditional Bureau

role of promoting accurate, meaningful, and compatible optical radiation

measurements in the near-uv, visible, and near-ir spectral regions.

Measurement services, as well as research and development, in these areas

are essential to the U.S. defense, aerospace, health, lighting,

photographic, and other industries for product development, quality

control, and to assure a competative position in world markets.

Government agencies, such as DoD and NASA, also reply on the NBS

measurement base for high-technology applications involving radiometry and

spectrophotometry in the above-mentioned regions.

The Division was organizationally subdivided into four Groups during

FY 1986:

Spectroradiometry and Optical Pyrometry . Conducts applied research

to develop new instrumentation and to improve and extend radiometric

and pyrometric standards and calibration procedures.

Spectrophotometry . Provides

measurements, standards, and

Develops new methods for the

media and components.

h i gh- accuracy spectrophotometr i

c

measurement assurance procedures,

radiometric characteri zat ion of optical

Photodetector Physics and Metrology . Develops new, detector-based

radiometric standards and methods to complement and extend

traditional, source-based radiometry.

Radiometric Measurement Services . Provides, improves, and extends

radiometric and photometric calibrations, implements measurement

assurance programs, and participates in radiometric intercomparisons.

As will be seen from the following reports of the four Group Leaders, each

Group produced important results during the fiscal year.

Fiscal year 1986 was a year of transition for Division 534. Three

employees, Alfred Criqler, John Shumaker, and John Ward, have retired

during the year. Russell Yokley has also retired, but agreed to continue

working on infrared radiometry on a contract basis. We have filled one

of the vacancies left by these retirements by hiring Mr. Gasem Jaafari, a physicist with previous experience in blackbody physics and radiation

83
Division 534, Technical Activities (cont'd)

thermometry. Two junior physicists at the postdoctoral level, Dr.

Jonathan Hardis and Dr. Alan Midgall, will join the Division at the

beginning of FY 1987. As a further measure, several changes in personnel

assignments and group responsibilities were made.

The Spectroradimetry and Optical Pyrometry Group has begun to

implement the new spectroradiometry effort of the NBS Process and Quality

Control Initiative. James J. Snyder, formerly with the NBS Center for

Basic Standards, joined the Division for several months, and was given the

assignment to identify new research directions for the Group. He

formulated plans for five projects.

Laser Heterodyne Densitometry,

XUV Absolute Radiometry,

IR Heterodyne Pyrometry,

Fourier Spectroradiometry,

Rydberg Atom IR Detection,

which are expected to bring new impetus to radiometry through the

exploration of new technologies. James Snyder also undertook a survey of

national needs for low-background infrared calibrations and negotiated

contracts to develop a cryogenic radiometer for such calibrations at NBS.

Although Snyder has left the Division to accept a position in private

industry, new activities in these areas have started with newly hired

scientists and with technical advice from Tom Lucatorto of Division 533.

The Spectrophotometry Group has again increased the number and volume

of Standard Reference Materials produced. Victor Weidner developed a new technique in sintering halon mixtures and has applied it to produce new SRM's for reflectance and fluorescence measurements. The Group also

conducted transmittance intercomparisons with the National Physical

Laboratory of the U.K., and the Physikalisch-Techische Bundesanstalt of

the FRG, both of which have now developed reference spectrophotometers

patterned after the NBS high-accur acy spectrophotometer desiqned by

Klaus Mielenz and Kenneth Eckerle.

The responsibilities of the Photodetector Physics and Metrology Group

have been broadened to include the development and implementation of

metrological applications of detectors in addition to performing basic

research. The Group has already made significant progress in detector

metrology, especially in the international intercompar ison of silicon

detectors conducted by Edward Zalewski under the auspices of the

Consultative Committee on Photometry and Radiometry (CCPR) and in the

low- light level radiometry project headed by Schaefer. FY 1986 was the

last year of the Division's Quantum Radiometry project, and consequently

our previous efforts in developing non-radi ometric measurement technqiues,

characterization methods, and theoretical descriptions of semiconductor

photodiodes have been transferred to the Semiconductor Electronics

84
Division 534, Technical Activities (cont'd)

Division (727) of the NBS Center for Electronics and Electrical

Engineering. Jon Geist has transferred to Division 727, and both

Divisions (534 and 727) have agreed to collaborate in research on semiconductor devices suitable for radiometric measurements. The

responsibi 1 ity for the development and radiometric calibration of solid

state detectors will remain in Division 534. Schaefer has been appointed

Acting Group Leader, and the Group will be merged with the

Spectroradiometry and Optical Pyrometry Group in FY 1987.

The Radiometric Measurment Services Group has achieved excellent

agreement with measurements made by other leading national standardizing

laboratories in an international intercomparison of luminous intensity and

luminous flux, also conducted by the CCPR. In collaboration with the

Photodetector Physics and Metrology Group, it has demonstrated better than

0.5% agreement between detector- and source-based photometric scales in a filter radiometry experiment conducted by Robert Bruening and in joint

efforts with Hungarian radiometri sts. Donald McSparron has led the

Division's participation in the NBS-wide effort to prepare comprehensive

documentation of calibration and measurement services.

The Division as a whole continued to be actively engaged in

collaborative efforts with other standardizing 1 aboratories, professional

societies, and standards organizations at the national and international

levels. For example:

o Our exchange program with the Physikal isch-Technische Bundesanstal

t

(PTB) is now in its third year. Robert Saunders and James Walker

both worked in Braunschweig during FY 86, and Dr. Metzdorf from PTB

will join us as a guest scientist later this year.

o Jack Hsia was elected as a Director of the Inter-Society Color

Council. Mielenz was elected Director of Division 2, "Physical

Measurement of Light and Radiation," of the International

Commission on Illumination (CIE).

o Mielenz organized an international conference on "Advances in

Standards and Methodology in Spectrophotometry" in collaboration

with the US Council for Optical Radiation Measurements (CORM) and

the UV Spectrometry Group of the UK. Several Division employees

presented invited lectures at this conference.

The number of guest scientists who work in our laboratories on projects of mutual interest has again been substantial:

Dr. Joaquin Campos Acosta from the Institute of Optics in Madrid, Spain,

made linearity measurements in the infrared of pyroelectric and HgCdTe

detectors on the new C0

2 laser-based detector characterization facility.

85
Division 534, Technical Activities (con't)

Mr. Gyorgy Andor from the Hungarian Office of Measures worked on filter

detector spectral radiometry and the realization of a detector-based

photometric scale.

Messrs. Sheng-Tsong Chang and Chang-Long Chang from the National Science

Council of Taiwan participated in the development of spectrophotometr ic

standards.

Dr. Gyula Deszi from the Hungarian Office of Measures (OMH) performed a detector intercomparison to check NBS and OMH detector scale agreement,

and to compare photopic detectors with the NBS photometric scale.

Dr. Gyorgy Eppledauer from the Institute for Technical Physics of the

Hungarian Academy of Science worked on international detector

intercomparisons, and the low light level detector radiometry program.

Professor He Ming-Gao from the Institute for Electric Light Sources of

Fudan University, Shanghai, PRC, collaborated on the intermediate

laboratory support program for geometrically-total spectral flux.

Mr. Kemal Kumcu from TUGAM - Marmara Research Institute, Turkey, worked on the CW ring dye-laser facility and aided in characterization measurements

of a high quality NPL interference filter with this facility.

Mr. Fred Nicodemus, Catholic University of America, Washington, DC, edited

the Self-Study Manual on Optical Radiation Measurements.

Mr. Yoshihiro Ohno of the Matsushita Electric Industrial Company in Osaka,

Japan, worked on characterizing the throughput of small integrating

spheres for measurments of geometrically total luminous flux.

Dr. Janos Schanda from the Hungarian National Academy of Sciences (MFKI)

participated in photometric detector intercomparisons with our division.

Dr. Masura Tsudagawa from Ritsumeikan University in Japan aided in the

characteri zat ion and extension of detector scales into the near infrared

region, using an electrically calibrated radiometer. He studied the use

of such detectors as Ge and InP/InGaAs.

Mr. Zhang Rui-Rong of the Shanghai Institute of Technical Physics,

Peoples' Republic of China made measurements of detector reflectance,

cleaning procedures, and the effect on stability.

Their contributions to our programs are acknowledged with thanks.

86
Division 534, Technical Activities (cont'd)

Spectroradiometry and Optical Pyrometry (J. J. Snyder, A. R. Schaefer)

Infrared Radiometry

Yokley has almost finished the characterization of the new heat-pipe

blackbody constructed at the beginning of last year to meet the needs of

the infrared radiation thermometry community. Both sodium-filled (500

U C to 1100’C) and mercury-filled (200°C to 350°C) units have been prepared.

Snyder conducted a survey of the needs of the defense community in the

area of low background long wavelength infrared (LWIR) calibration

capability. The LWIR capability which Yokley had established a number of

years ago is no longer available. It was determined that a reinstatement

of this capability in-house would require an inordinate effort. To meet

the future growing needs of the LWIR community, the Army USADC/SDI Command

has funded the development of a low background LWIR calibration facility

in our Division at NBS. Progress to date includes conceptual design of

the cryogenic chamber and closed cycle helium refrigerat ion system to

provide necessary cooling capacity. Work is also progressing on design of

an electrically calibrated cryogenic radiometer necessary for use in the

facility. Yokley has also been active in these areas. In addition,

Joel Fowler and Schaefer have recently become involved in this effort.

Spectroradiometry

Saunders and Shumaker have made further progress in the absolute gold

point determination experiment. Saunders characterized an electrically

calibrated absolute radiometer and compared it to the PTB radiometer scale

while a guest worker there. The results were quite encouraging, with

absolute agreement within 0.3%. Since that time the entire measurement

sequence necessary to determine the gold point has been performed, after

assembling all the necessary apparatus. In connection with this project,

Saunders and Shumaker have developed a computer controlled gold-point

blackbody possessing stable freezing and melting times of an hour. This

is a factor of four better than previous efforts at NBS. This experiment

is now in its final stages. The conclusion of this effort may be somewhat

delayed due to the recent retirement of Shumaker.

Migdall worked with Snyder in moving and setting up the helium/neon laser

version of the heterodyne densitometer prior to Snyder's departure. It is

expected that work will proceed on this project beginning in October. In

addition, Zalewski is interested in pursuing LWIR laser heterodyning on the C0

2

1 aser f aci 1 ity.

Saunders and Ohno developed techniques and built an ion and dye-laser

based apparatus for measuring the absolute spectral power throughput of

integrating spheres. The device was also used to measure the relative

87
Division 534, Technical Activities (cont'd)

spectral response of several detector-f i Iter combinations. The results of

this work were used to confirm data taken on the spectral response

comparator described later in this report.

Geist, Saunders, and Jeanne Houston investigated the effects of detector

biasing in the UV. This work was made possible by the use of the newly

developed spectral response comparator. Results from these measurements

have helped lead to the development of better detectors in the UV spectral

region.

In collaboration with the Radiation Physics Division Regina Bonanno has

been doing postdoctoral research with Snyder, constructing the ion charge

exchange facility. This apparatus is in the final stages of becoming

operational, and Bonanno hopes to complete the intended feasibility

studies before leaving NBS in early October. Her intent is to investigate

the single-pass laser ionization efficiency and effectiveness of charge

exchange in populating a desired metastable state in Kr necessary for

certain isotopic analysis schemes to work. The longer term goal for this

facility is to generate a known amount of XUV radiation for a measured

number of visible photons produced. It is also anticipated that Hardis

will spend a substantial effort on this project.

88
Division 534, Technical Activities (cont'd)

Spectrophotometry (J. J. Hsia)

The Spectrophotometry group is responsible for:

(1) Establishing and improving high-accuracy spectrophotometric

,

spectrof luorimetric and densitometric scales in the National

Mesurement System by developing new instrumentation, establishing new

measurement capabilities, and improving basic standards.

(2) Disseminating these scales by developing transfer standards and

standard materials, establishing measurement assurance programs,

performing calibration services, and providing consultation to the

measurement community.

(3) Studying and developing new methods for radiometric character i zat i on

of optical media and components for scientific research and for

emerging technologies.

FY 1986 has been a productive year for the Group in terms of

research, development and measurement services. Major accomplishments in

the areas of UV-V I S-NIR spectrometry, infrared spectrometry,

spectrof luorimetry, transmission densitometry, and standard committees are presented below.

UV-VIS-NIR* Spectrometry

Measurement Services

Calibrations, standards, and testing methods in the wavelength range

from 200 nm to 2.5 ym are needed to serve many industries including:

optics, non-destructive testing, energy, safety, space, agriculture,

appearance, photography, printing, textiles, paint, and chemicals.

Weidner and Patricia Barnes provided special calibrations of spectral

transmittance, specular reflectance, and diffuse reflectance. Eckerle

provided measurement assurance services for transmittance and Hsia

provided calibrations of gloss samples.

Two documents have been completed describing the instrumentation,

standards, and techniques used in the measurement of spectral reflectance

(Weidner and Hsia) and spectral transmittance (Eckerle, Hsia, Mielenz, and

Weidner). Detailed descriptions are provided of the reference and transfer

instruments, instrument calibration, establishment of scales, measurement

procedures, and estimation of uncertainties. These two documents will be

published as NBS special publications.

89
Division 534, Technical Activities (cont'd)

Transmittance

The seven qlass filters in the set of transmittance standards

developed by Eckerle for the NBS measurement assurance program, have

proved to be very useful. Weidner used these filters at 548.5 nm and 770

nm to establish the linearity of the transfer spectrophotometer for the

visible and near infrared spectral regions. Eckerle used them to perform

an intercomparison with the Munsell Laboratory at the Rochester Institute

of Technology as a step toward the establishment of a secondary

calibration laboratory. Eckerle also started intercomparisons using this

set of filters with George Freemen of the National Physical Laboratory,

Great Britain and with E. Sutter of the Physikalisch-Technische

Bundesanstalt , Federal Republic of Germany. Both laboratories have

recently completed the development of high accuracy spectrophotometers for

transmittance.

Andor investigated the spectral transmittance of V(x) filters using

the NBS high accuracy spectrophotometer for transmittance.

Reflectance

Pressed polytetraf 1 uoroethylene (PTFE) powder has been widely used

for reflectance standards since Weidner and Hsia published their paper in

July 1981 in the Journal of Optical Society of America. The PTFE powder

has very high spectral reflectances from 200 nm to 2500 nm. Laboratories

in NASA and USDA have consulted Weidner on producing large size PTFE

plates for use as reflectance standards in their particular

applications.

One of the frequent requests from instrument manuf acturers and users

has been a set of gray reflectance standards with diffuse surfaces to

check the linearity of spectral ref lectometers. Weidner has successfully

produced uniform gray diffusers for reflectance below 50%, with sintered

mixtures of PTFE and carbon-black powders. For a sintered mixture with

reflectance above 50%, uniform reflectance was difficult to achieve

because the required amount of carbon black powder to mix with the PTFE

powder is small.

Weidner and Barnes completed the production of SRM 1920 rare-earth

oxide mixtures as wavelength standards for spectral ref lectometers in the near infrared range. These standards will soon be issued by the Office of

Standard Reference Materials. SRMs 1920 are especially useful for those

instruments that can only be used to measure the reflectance of samples.

These instruments are generally used to evaluate constituents such as protein, moisture, etc. in grains.

90
Division 534, Technical Activities (cont'd)

Automation Conversion

The reference spectrophotometer for reflectance has been the basic

instrument used by NBS to establish U.S. national scales of specular re- flectance, 6°/hemispherical reflectance factor and 45/0° reflectance

factor. Marvin Wu, a summer student from Brown University, started the

conversion of the data acquisition and control units to use the IBM-GPIB

system. The conversion involved such hardware as a microcomputer, digital

voltmeter, lock-in amplifier, relay module, stepper motor drivers and

software using the T BASIC language.

Infrared Spectrometry

Many requests for measurement services in the infrared spectral

region have been received from instrument manufacturers, the optical

industry, the glass industry, and DoD related industries. The purpose of

the long-wavelength infrared spectrometry project is to establish the

infrared measurement capabilities from 2.5 to 25 um, especially from 3 to

5 ym and from 8 to 14 um, for transmittance, diffuse reflectance and

specular reflectance. The plan is to develop dual systems with both

Fourier transform (FT) and dispersive infrared spectrometers.

Weidner has tested the signal throughput of the specular reflectometer with a liquid-nitrogen cooled HgCdTe detector and found it

satisfactory. The spectral reflectance and transmittance of germanium

filters of 2, 4, and 6 mm thickness were measured from 2 to 2.5 ym on the

transfer spectrometer . The calculated internal transmitt ances were near

100% which confirmed that the germanium had no absorption in certain wavelengths in the infrared region. These filters will be used to check the

specular reflectance and transmittance measurements of the FT-IR spectrometer and the transmittance measurements of the dispersive spectrometer

.

For the diffuse ref lectometer which uses an ellipsoidal mirror, a small averaging sphere with a gold-coated sand-blasted inner surface was designed and constructed. This averaging sphere, when used with the

nitrogen-cooled HgCdTe detector, did not produce enough signal to allow

meaningful measurements. A new design was produced with a hemispherical

dome shaped shell over the detector. The infrared radiation was thus

focused on the detector. The newly designed detector was checked.

Because a leak developed between the dome and the detector, the detector

was sent back to have it resealed.

The determination of large attenuations poses difficult problems for

many users. The idea of using a sphere-chain attenuator (SCA) is to

measure the attenuation of one or two spheres and to calculate the

attenuation of a chain of many spheres. Hsia has collaborated with

Ohno on the modeling of an SCA. The assumptions were a Lambertian wall

coating and uniform luminance on the sphere wall. The modeling was

91
Division 534, Technical Activities (cont'd)

performed for different sphere arrangements, sphere parameters, and

coating reflectances. The modeling was also performed for different

methods of calibrating the SCA. The results of the modeling provided

information on optimum sphere arrangements and calibration methods.

Spectrof luor imetry

The purpose of this project is to develop measurement methods and

transfer standards in order to assess the performance of instruments for

fluorescence measurements applicable to analytical chemisty, non- destructive testing, and appearance measurements.

Weidner has successfully produced sintered mixtures of inorganic

phosphors and PTFE powder. Four kinds of mixtures were sintered that

yielded recei ver-system corrected, normalized emission spectra in the

blue, green, yellow, and orange wavelength regions of the visible

spectrum. The spectral properties of PTFE made it ideal for this

application because of its low absorption in the ultraviolet and visible

spectral regions.

Eckerle and Chang investigated the fluorescence properties of these

sintered fluorescence samples. They investigated the effects of the

following parameters on the normalized emission spectra: excitation

wavelength, ultraviolet exposure, temperature, and concentration of the

phosphors. They also investigated the uniformity of these samples. The

investigations were undertaken to search for possible reference materials

for use as fluorescence standards.

Transmission Densitometry

Measurements of transmission density are used for quality control of

photographic and printing products and for non-destructive testing.

Laurance Fink produced x-ray step tablets (SRM 1001) and photographic

step tablets (SRM 1008) used in the calibration of transmission

densitometers for transmission densities from 0 to 4 and microcopy

resolution charts for determining the resolving power of photographic

systems. Reflection step tablets (SRM 2061) which have been calibrated by

Fink, are also available from the Office of Standard Reference materials

for reflection densities from 0 to 2.

The reference transmission densitometer has been constructed with the

unique feature that the transmission density of a sample is inversely

proportional to the fourth power of the ratio of the sample-in distance to

the sample-out distance. The receiver, built to conform to the new ANSI

Standard PH2. 19-1986, was found to produce non-uniform flux on the

photomultiplier. A new receiver has been designed by Fink and built by

the machine shop. This receiver consists of an opal glass, a sample plate

92
Division 534, Technical Activities (cont'd)

with grooves for applying vacuum or pressure, a small section of

specular-aluminum cone, and an averaging sphere. A photomultiplier with a high sensitivity GaAs (Cs) photocathode has been ordered. This

photomultiplier has a relatively flat spectral response in the visible

region. A compound filter with a spectral transmission resembling the CIE

standard luminosity function will be used over the new detector.

Standards Committees

Hsia served both as an Associate Director and the Secretary of CIE

Division 2 on Physical Measurement of Light and Radiation. He also served

as a member of Committee TC2-14 on Transmittance and Reflectance. As the

Chairman of Committee TC2-11 on gonioref lectometry, he has planned a world

wide investigation of the gonioref lectance properties of standard

reference materials, specially PTFE and BaSC^ powders.

Hsia also served as a Director on the Board of the Inter-Society

Color Council, an inter-di scipl inary organization of more than 20

scientific, artistic and industrial societies which have common

measurement problems in color and appearance.

At the CORM/UVSG Spectrophotometry Conference in Oxford, England,

Hsia was invited to speak on "National Scales of Spectrometry in the U.S.",

Mielenz on "Fluourescence Spectometry in Analytical Chemistry and Color

Science", and Schaefer on "Tunable Dye Laser Spectrometry"

.

Julius Cohen's standard test method for minimum resolvable

temperature differnce (MRTD) has been approved by subcommittee ASTM E7.10

on other NDT Methods. He has also completed a draft on "Fundamentals and

Applications of Infrared Thermography for Nondestructive Testing".

93
Division 534, Technical Activities (cont'd)

Photodetector Physics and Metrology (J. C. Geist, A. R. Schaefer)

Photodetector Calibrations

Houston, Saunders, and Zalewski have made proqress on the detector sDectral response comparator. A new light proof box was designed and

installed to enclose the detector compartment. Changes were made in the

optics in the detector compartment to allow better focussing with improved

precision resulting. Saunders is currently converting computer support

for the facility from the old eight-bit system to the newer more flexible

sixteen-bit PC computer system.

Andor and Zalewski designed a set of absorbing glass filters which will be

used for absolute detector based, narrow-band filter spectroradiometry

.

It is expected that absorbing glass narrow-band filters will be more stable and uniform than the interference filter spectroradiometer such as that used previously by Bruening. The absolute base will be 100% quantum

efficient detectors for longer wavelength measurements using promising new photodiodes now available. In addition, they are working to realize an absolute photometric scale based on 100% quantum efficient detectors with

a carefully designed photopic glass filter.

Better quality detectors for use in radiometry are becoming available.

Raj Korde of United Detector Technology, Inc. (UDT) has developed a device

which has high quantum efficiency and is apparently very stable in the UV.

These devices can be irradiated for several days with over 1 mW per square

cm of 254 nm wavelength radiation with no apparent change in quantum efficiency. A special UV calibration of several of these new detectors has

recently been completed by Houston and Zalewski for UDT and Optronics

Laboratories. Both companies have experienced problems with UV detector

calibration instability - changes as large as 20% in a few months. They

have agreed to work with NBS over the next few years to monitor the UV

calibration of these new detectors.

Recently Professor Schwartz of Purdue University has made proqress in

producing high quality germanium photodiodes for the near infrared spectral region. The devices have been measured at the University of Arizona

Optical Sciences Center, and appear to have a very high internal quantum

efficiency of essentially 100% from 0.7 to 1.5 ym.

Geist continued to cooperate with Petroff of Rockwell International on modeling of blocked impurity band silicon detectors.

Intercompar i sons

Zalewski and Douglas Thomas, have obtained some very interesting initial

results in the CCPR Detector Intercompar i son. Seven national laboratories

were sent a pair of photodiodes, one inversion layer and one PN device.

94
Division 534, Technical Activities (cont'd)

They were asked to determine the quantum efficiency of these two detectors

at 632.8 nm. The detectors were first measured at NBS, and then measured

again upon their return. The range of agreement for the majority of the

laboratories (six out of eight including NBS) was within ±0.15% for the

inversion layer type of photodiode. These excellent results were clouded

somewhat by the fact that the quantum efficiency of some of the detectors

had changed during transport. It appeared, however, that the change

occurred between the first NBS measurement and that done at the other

laboratory; i.e., on the outward leg of the trip. The PN layer devices

seemed to show better stability than the inversion layer devices.

Water Bath Blackbody

The water bath blackbody described in last year's annual report has been

finished and delivered to the Air Force CCG. This apparatus appears to

successfully meet a need for ambient background LWIR calibrations. In view of its success, the Navy CCG has furnished support to construct

another such device. Plans are underway to construct two such devices, in

order to maintain an in-house capability. Also under consideration is an effort to construct an LWIR radiometer capable of characterization of such

blackbody sources.

Low Light Level Detector Radiometry

This was a very successful year for the low light level prograto. Schaefer

and Patraick Tobin finished the ultra-high precision low light level

radiometer character!’ zat ion facility which provides total light and

vibration isolation and a high degree of thermal mechanical stability.

The facility instrumentation is controlled with a personal computer.

Schaefer used the new semiconductor parameter testing instrument to select

good candidate detectors for use in the stellar radiometer at Lick

Observatory for stellar brightness and planetary detection studies. This

radiometer was designed in collaboration with A. Young of San Diego State

University and W. Borucki of NASA Ames Research Center, and fabricated at NBS.

Fowler and Geist designed and constructed a very stable high gain

amplifier, which produced a gain of 101

1

V/A with a stability of better

than 0.1%. Schaefer characterized and tested the final assembly of the

radiometer, amplifier, and chosen detectors on the low light level

facility, using tritium activated phosphorescent light sources. At

current levels of 1 - 10 pA, relative amplified detector signal

stabilities of ~5 * 10 -4 were obtained with 4 minute integration periods.

Schaefer, Fowler, and Tobin then took the radiometer and amplifier

assembly to Lick Observatory at Mt. Hamilton, CA. With the assistance of

William Borucki and Lori Allen, they installed the instrumentation on the

Lick 19- inch twin astrograph telescope. Several nights worth of

95
Division 534, Technical Activities (cont'd)

measurements yielded relative star brightness determinations on pairs of

stars with a precision better than 1:103

, which surpassed initial

expectations. It is anticipated that with the adoption of cooled

detectors and amplifiers, the precision will be increased further. The

favorable results of this work resulted in a Letter of Commendation from

David Brocker, Chief of the Space Sciences Division of the NASA Ames

Research Center.

Spectral Radiometry

The high quality NPL/Anders interference filter loaned to NBS for

evaluation by Neal Fox of NPL has been examined with the tunable ring

dye-laser detector characteri zation facility. Schaefer and Kumcu used DCM

dye to characterize the 20 nm half bandwidth 676 nm filter described in

last year's annual report. Apparently these filters do indeed represent a new level of uniformity in transmittance, with peak transmittance

variations of less than 0.5% over large areas of the filter using a 4mm

diameter beam. This is at least a factor of five better than typical

results seen on earlier filters.

These filters helped make possible the fine intercomparison results

between NPL and the PTB BESSY electron storage ring reported in Applied

Optics by Fox, Key, Riehle, and Wende. In an experiment similar to one conducted earlier by NBS, they intercompared a silicon/filter radiometer,

which had been calibrated against their electrically calibrated cryogenic

radiometer, to the predicted spectral radiant flux from the BESSY ring.

The experiment was performed at 676 nm and 799 nm, with an agreement of

+0.13% and -0.10%, respect ively, and a combined uncertainty of 0.3%.

LIDAR Simulator

Fowler and Tobin, working with Geist, finished setting up the LIDAR

simulation facility described last year, in suport of the NASA Langley

Research Center's Differential Absorption LIDAR (DIAL) program. The

device employs a computer controlled acousto-opt ical modulator to generate

a signal on a laser beam selected from a variety of available and/or user programmable waveforms. Using transient digitizers, the device can determine the linearity of detectors under various transient responses,

such as l/(time) 2

. This is important to determine the influence of such

effects as ground return pulses on detectors used in LIDAR measurements.

NASA Langley will oversee the operation of the facility in Hampton, VA,

when completed.

96
Division 534, Technical Activities (cont'd)

Radiometric Measurement Services Group (D.A. McSparron)

This Group provides a firm measurement base for the Nation's optical

radiation community (defense and aerospace, instrument manufacturers and

commercial calibration 1 aboratories, lighting and photographic industries,

research institutions, etc.)- To accomplish this objective, the Group:

(1) Maintains measurement scales and provides, improves and extends

NBS calibration services for the basic pyrometric, radiometric,

and photometric guantities: radiance temperature, spectral

radiance, spectral irradiance, detector spectral responsivity,

luminous intensity, luminous flux, and color temperature.

(2) Engages in activites such as intercomparisons, measurement

assurance programs, intermediate laboratory support programs,

consultations, and ad hoc experiments that will insure that

measurements made in laboratories outside NBS have acceptable

levels of accuracy.

Calibration Services

Direct calibration billings increased by 3.5%, but directly funded

calibration work for other government agencies decreased by 30% due to

budgetary cut-backs. The combined effect was a decrease in calibration

volume of 6%.

Walker implemented the Saunders-Shumaker sphere technique for

realizing the NBS scale of spectral irradiance on FASCAL. This method

replaces the previous lamp-mirror image system with the exit port of a water-cooled averaging sphere. The new system eliminates the tedious

al ignment-stabi 1 ization-real igment measurement sequence required by the

old system. Utilizing this sphere technique, Walker extended the spectral

irradiance scale to cover the spectral region from 1600 nm to 2400 nm. Type FEL, 1000-watt quartz-halogen lamps are presently available

calibrated from 250 nm to 2400 nm as a special test. This extended

spectral range will be available on a routine basis early next fiscal

year.

Documentation

A major part of the Group's effort this year has been devoted to

preparing complete documentation of the various calibration services

offered. This is part of a Bureau-wide effort to document all NBS

calibration activities. The documents prepared addressed the quantities

measured, services offered, equipment and procedures used, and particular

attention was paid to the preparation of complete uncertainty statements.

The following calibration areas were addressed: pyrometry (William Waters,

Walker, and Albert Hattenburg), spectral radiance ( Walker, Saunders, and

97
Division 534, Technical Activities (cont'd)

Hattenburg), spectral irradiance (Walker, Saunders, John Jackson, and

McSparron), photometry (Robert Booker and McSparron), and detector

spectral response (Zalewski).

Intercomparisons

At the 1982 meeting of the Consultative Committee on Photometry and

Radiometry (CCPR) plans were formulated for an international

intercomparison of the photometric units of luminous intensity and

luminous flux. These intercomparisons are of particular interest, since

they are the first attempt to evaluate quantitatively the effects of the

recent redefinition of the photometric units. During the year, NBS

completed its measurements and received preliminary results of the

intercomparison from the International Bureau of Weights and Measures.

The indicated range of agreement for both quantities is about 2%. The

next meeting of the CCPR will take place in October, 1986 and worldwide

results will be available at that time.

The visit by Schanda presented an opportunity to compare the NBS

detector-based radiometric scales with the source-based scales. Schanda

brought a V(x) corrected silicon detector that had been manufactured and

calibrated in Hungary. This detector was calibrated for absolute spectral

response on the NBS spectral response comparator. It was then calibrated

with the NBS working group of luminous intensity standards. The agreement

was slightly better than 0.5%. Comparison with the Hungarian scales

awaits remeasurement of the detector.

Calibration Facilities Upgrade

Waters is implementing the Jeffery Tapping design of a new photoelectric pyrometer for performing radiance temperature calibrations.

This instrument will replace an earlier facility in realizing the

International Practical Temperature Scale (IPTS) above the gold point.

The new pyrometer employs refractive optics, an extended-red

photomultiplier detector, and interference filters which restrict the

bandpass to about 1 nm. External vacuum tungsten strip-lamps are used to

reproduce small multiples of the gold-point spectral radiance rather than

the internal lamp used previously. The detector is operated under

measured linear conditions in realizing higher multiples of the qold-point

spectral radiance, making the use of absorbing glasses unnecessary. The new pyrometer is presently in operation as a comparator for calbration

ribbon-filament tungsten strip-lamps from 800°C to 2300°C at 655 nm. In the near future, a gold-point blackbody will be added to the facility to

permit independent temperature scale real i zat ions.

Considerable progress has been made in the modernization of the

luminous intensity and color temperature facilities. Certain components

of the present facilities are over 60 years old and replacement parts must

98
Division 534, Technical Activities (cont'd)

be hand machined on a custom basis. This causes delays and sometimes

forces compromises. Booker has designed a replacement for the current

photometric bench. The new facility is based on a double rail and

carriage system with Charles Popenoe-designed goniometric lamp mounts.

These components, structural hardware, and new power suplies have been

purchased and are ready for assembly. The selenium photocells presently

used will be replaced with photopical ly-corrected silicon photodiodes. An

evaluation of initial prototypes has begun. When the new photometric

bench is complete it will permit more accurate alignment of sources,

detectors and components, and will facilitate better control of the

luminous intensity calibration service. Modernization of the color

temperature comparator has been undertaken to improve reliability and

quality control. Two silicon photodiodes fitted with red and blue filters

respectively have been mounted in recessed tubes attached to a 20 cm diameter integrating sphere. Ronald Wilkinson and Booker have begun an evaluation of 3 different instruments based on the red-to-blue ratio

principle for transferring color temperature calibrations. The instruments

differ in the filters and in the detection systems used. The instruments

are a Pritchard telephotometer, the red- and blue- filtered silicon

photodiodes, and a photomultiplier with revolving red and blue filters.

New instrumentation is expected to be brought on line in the first half of

next year.

Spectral Flux Standards

The development of geometrical ly-total spectral flux standards

continues. This program was initiated in response to a request from the

lamp manufacturing industry and is being coordinated through the Lamp

Testing Engineer's Conference (LTEC). NBS agreed to develop both

incandescent and non-incandescent standards of geometrically total

spectral flux to ensure the accuracy of the industry-derived photometric

scales for high-intensity discharge lamps. Ward and Bruening have been

setting up the equipment to be used for measuring the goniometric

distribution of the lamps. Special lamps have been purchased to serve as incandescent standards and they are being further modified to make them

suitable for measurement. Professor He has completed the spectral

characterizat ion of a large number of commercially available 400-watt

high-pressure sodium lamps. From these, he has selected a group of 12

lamps to be used as the non-incandescent standards.

Photometric Research

Bruening has expanded the work on detector-based filter radiometry to

include the use of 100% quantum efficient silicon photodetectors with

interference filters to realize a luminous intensity scale. A detectorbased scale is an alternative to the present source (blackbody) based

scale. The agreement in luminous intensity values obtained form these two

bases ranges from +0.5% to -0.1% for the 7 lamps tested.

99
Division 534, Technical Activities (cont'd)

Ohno completed his project on alternatives to goniometry for

generating geometrically-tot al flux standards. Last year, through

computer simulation, the theory of the integrating sphere was extended to

include asymmetrical baffle positioning as well as taking account of the

effects of multiple baffles. More recently, this theoretical work has

been experimental ly verified. Four minature lamps were calibrated first

by the traditional goniometric method on a small instrument built

specially for this purpose by Ohno. They were then calibrated in a sphere

configured as indicated by the computer simulations, against a spectral

irradiance standard operated external to the sphere. The agreement

between the two methods was better than 0.5%. This work verifies the

feasibility of realizing geometrically total flux scales without recourse

to distribution photometry.

100
INVITED TALKS

Division 534, Radiometric Physics

Hsia, J.J., "National Scales of Spectrometry in the U.S.", Joint UVSG/CORM

Conference on Spectrometry , Oxford University, Oxford, England, September

14-17, 1986.

Mavrodineanu, R., "Chemical Standards for Calibration Purpose", Joint

UVSG/CORM Conference on Spectrometry , Oxford University, Oxford, England,

September 14-17, 1986, in collaboration with CIE.

McSparron, D.A., "Radiometric Calibration Services of the National Bureau

of Standards", Satellite Calibration Workshop, Phoenix, Arizona, March

1986.

McSparron, D.A., "Radiometry Measurement Capability at NBS", 1986

Conference on Precision Electromagnetic Measurements, June 1986.

Mielenz, K.D., "Fluorescence Spectrometry in Analytical Chemistry and

Science", Joint UVSG/CORM Conference on Spectrometry, Oxford University,

Oxford, England, September 14-17, 1986.

Schaefer, A.R., "Tunable Dye Laser Spectrometry", Joint UVSG/CORM

Conference on Spectrometry, Oxford University, Oxford, England, September

14-17, 1986.

Walker, J.H., "Realization of Spectral Radiance and Spectral Irradiance

Scales at NBS", September 1986, Physikal i sch-Techni sche Bundesanst alt

,

Braunschweig, West Germany.

Zalewski, E.F., "Absolute Photon Flux Measurements", Department of Physics

Seminar, Towson State University, March 1986.

Zalewski, E.F., "Interpolation of Silicon Photodiode Quantum Efficiency as

an Absolute Radiometric Standard", 1986 Conference on Precision

Electromagnetic Measurement, June 1986.

101
PUBLICATIONS

Division 534, Radiometric Physics

Cohen, J., "Introduction to Fourier Transform Spectoscopy", NBS

IR 86-3339, March, 1986.

Geist, J., "Nyquist Noise in Current Carrying, Non-linear Circuit

Elements", Applied Phys. or Proc. of IEEE

Geist, J., Zalewski, E. F., Tong-Boa, Li., Province, S., "The Quantum

Yield of Silicon in the Near-Ultraviolet", Phys. Rev. Lett.

Geist, J., "Silicon Photodiode Physics as a Basic for Accurate

Radiometry", 1985 International Conference on Solid-State Sensors &

Actuators

Kostkowski, H., Lean, J., Saunders, R.D., and Hughey, L., "Comparison of

The NBS SURF and Tungsten Ultraviolet Irradiance Standards", Applied

Optics, October 1986.

Mickelson, M. E., Larson, L. E., Fowler, J., "Radiometric Calibration

Procedures Using the NBS MARBLE Electronics Package", NBS Technical Note.

Saunders, R.D. and Shumaker, J.B., "Applied Function of a Prism-Grat ing

Double Monochromator" , Applied Optics, October 15, 1986.

Saunders, R. D., Shumaker, J. B., "Studies of the Apparatus Function of a Pr i sm-Grat ing Double Monochromator" , Applied Optics.

Schaefer, A.R., Saunders, R.D., and Hughey, L.R., "Intercomparison Between

Independent Irradiance Scales Based on Silicon Photodiode Physics,

Gold-point Blackbody Radiation, and Synchrotron Radiation", Optical

Engineering 25, 892, (July, 1986).

Snyder, J.J., "Laser Heterodyne Densitometer", Proceedings of the

Conference on Lasers and Electro-Optics.

Weidner, V. R., Mavrodi neanu, R., Eckerle, K. L., "Sintered Mixture of

Phosphors in Po lytetraf luoroethylene Resin for Fluorescence", Appl. Opt.

25, 832 (1986).

Weidner, V., Hsia, Eckerle, Exploratory Research in Reflectance and

Fluorescence Standards at the National Bureau of Standards, Optics News

(Published by the Optical Society of America).

102
Division 534, Publications (cont'd)

Weidner, V. R., Mavrodineanu, R., Mielenz, K. D., Velapoldi, R. A.,

Eckerle, K. L., and Adams, B., Holmium Oxide Solution Wavelength Standard

form 240 to 640 nm- SRM 2034, NBS Special Publication 260-102, 1-56, July

1986.

103
PUBLICATIONS IN PREPARATION

Division 534, Radiometric Physics

Booker, R.L. and McSparron, D.A., Photometric Calibration Procedures,

1986, NBS Special Publication SP 250-16.

Bruening, R.J., Spectral Irradiance Scales Based on Filtered Absolute

Silicon Photodetectors, Applied Optics.

Cohen, J., Fundamental and Applications of Infrared Thermography for

Nondestructive Testing. A chapter of a book.

Eckerle, K.L., Hsia, J.J., Mielenz, K.D. and Weidner, V. R., Regular

Spectral Transmittance Measurements: Documentation and Description of

Services, (WERB approved) NBS Special Publication SP 250-6.

Fowler, J., Belzer, B., Water Bath Black Body Operating Instructions, NBS

Technical Note.

Geist, J., Fowler, J.B., A Water Bath Blackbody for the 5 to 60 Celsius

Temperature Range: Performance Goal, Design Concept and Test Results.

Geist, J., Blocked Impurity Band IR Detector Self-Calibration: Proposal,

Applied Optics.

Geist, J., Nofzigar, M.J., Olsen, G.H., Feasibility of Detector

Self-Calibration in the Near Infrared, Digest of Technical Papers

Conference on Precision Electromagnetic Measurements 1986.

Geist, J., Photodiode Operating Mode Nomenclature, Applied Optics.

Kostkowski, H. J., Lean, J. L., Saunders, R. D., Hughey, L. R., Comparison

of the NBS SURF and Tungsten.

McSparron, D., Tibbits, T., Krizek, D., Spectral Effects on the Use of

Photon Flux Sensors for Measurement of Photosynthetic Photon Flux in

Controlled Environments (in press).

Popenoe, C.H., and Yokley, C.R., Manual of Construction and Control of a Heatpipe Blackbody Source (Sodium and Mercury) Manufactured for the Air

Force by NBS.

Saunders, R.D., Shumaker, J., and Walker, J.H., Spectral Irradiance Scale,

Metrologi

a

Schaefer, A.R., and Fox, N.P., Tunable Dye Laser Spectrometry, Proceedings

of Advances in Standards and Methodology in Spectrophotometry , Oxford,

1986.
Division 534, Publications in Preparation (cont'd)

Snyder, J., Helmcke, Morinaga, Mensing, Glaser, New Ultra-High Resolution

Dye Laser Spectrometer Utilizing Passive Reference Resonator, Proceedings

from the PEM.

Walker, J.H., Saunders, R.D., and Hattenburg, A.T., The NBS Scale of

Spectral Radiance, (being submitted to Metrologia, WERB approved).

Walker, J.H., Saunders, R.D., and Hattenburg, A.T., Spectral Radiance

Calibration at NBS, (Calibration Documentation), WERB approved, SP 250-1

Walker, J.H, Saunders, R.D., Jackson, J.K., and McSparron, D.A., Spectral

Irradiance Calibration at NBS, NBS Special Publication SP 250-20.

Waters, J., Walker, J.H., and Hattenburg, A.T., Radiance Temperature

Calibrations at NBS, (Calibration Documentation), (WERB approved) NBS

Special Publication SP 250-7.

Weidner, V.R., A Wavelength Standard for the Near Infrared Based on the

Reflectance of Rare-Earth Oxides (in press).

Weidner, V.R. and Hsia, J.J., Spectral Reflectance Measurements:

Documentation and Description of Services, (WERB approved) NBS Special

Publication SP 250-8.

Weidner, V., A Gray Scale of Diffuse Reflectance for the Wavelength Range

250-2500nm, Letter to the Editor of Applied Optics.

Zalewski, E. F., Gladden W. K., Interpolation of Silicon Photodiode

Quantun Efficiency as an Absolute Radmetric Standard, Digest of Technical

Papers Conference on Precision Electromagnetic Measurements 1986.

Zalewski, E.F., The NBS Photodetector Spectral Response Calibration

Transfer Program, NBS Special Publication SP 250-18.

105
TECHNICAL AND PROFESSIONAL COMMITTEE PARTICIPATION AND LEADERSHIP

Division 534, Radiometric Physics

Robert Booker

Member, U.S. National Committee of the CIE

Robert J. Bruening

President, National Captial Section of the Optical Society of America

Technical Professional Society

Julius Cohen

Member, ASTM E-07 Committee on Nondestructive Testing, Section

E-07. 10.04 on Infrared Methods.

Kenneth L. Eckerle

Member, ASTM E- 13 Committee on Molecular Spectroscopy, Subcommittee

E- 13. 03 on Infrared Spectroscopy, Subcommittee E-13.01 on Ultraviolet

and Visible Spectroscopy, Subcommittee E- 13 .06 on Luminescence.

Jon C. Geist

Member IMEDO 10002 on Photon Detectors.

Albert Hattenburg

Member, CORM technical committee on Array Radiometry.

Jack J. Hsia

Director, Inter Society Color Council.

Assoicate Director, CIE Division 2 on Physical Measurement of Light

and Radiation.

Chairman, CIE TC 2-11 Technical Committee on Goniophotometry .

NBS Representative, ANSI PH2 on Photographic Sensitometry and PH2-28

on Densitometry.

Member, ASTM D- 1 .26 Subcommittee on Optical Properties of Paint,

Varnish, Lacquer and Related Products.

106
Division 534, Technical and Professional Committee Participation and

Leadership (cont'd)

Jack J. Hsia (Cont'd)

Member, ASTM E- 12 Committee on Appearance of Materials

( Spectrophotometry, colorimetry and geometric properties).

Member, ASTM E- 13 Committee on Molecular Spectroscopy, Subcommittee

E-13.01 on Ultraviolet and Visible Spectroscopy, E-13.03 on Infrared

Spectroscopy, and E- 13 .06 on Molecular Luminescence.

Member, ASTM E-07.03 Task Group for Fluorescent Penetrant Measurement

St andards

.

Secretary, CORM/NBS Task Force on Spectrophotometry

.

Donald A. McSparron

Consultant, CIE Technical Division II on Physical Measurement of

Light and Radiation.

Member, ANSI Z311 on Photobiological Safety of Lamps and Liqhting

Systems

.

Member, Illuminating Engineering Society (IES), Testing Procedures

Committee.

Member, Lamp Testing Engineers' Conference.

Klaus D. Mielenz

Secretary, U.S. National Committee of the CIE.

Director, CIE Division 2.

Member, ASTM E- 13 Committee on Molecular Spectroscopy, Subcommittee

E-13.06 on Molecular Luminescence.

Member, IES, Nomenclature, Subcommittee C012.

Vice Chairman, CORM, TASK Force on Spectrophotometry

.

Member, IES Committee on Nomenclature.

Member, OSA International Affairs Committee.

107
Division 534, Technical and Professional Committee Participation and

Leadership (cont'd)

Robert D. Saunders, Jr.

Member, ANSI Z311 on Photobiological Safety of Lamps and Lighting

Systems

.

Member, IES Committee of Photobiology.

A. Russell Schaefer

Member, CIE TC2-06 Technical Committee on Absolute Spectral

Responsivity.

Douglas B. Thomas

Member, ASTM Committee E44 on Solar Energy Conversion.

Wi 1 1 i am R. Waters

Member, ASTM Committee E-20 on Temperature Measurement.

Edward F. Zalewski

Chairman, CIE TC2-06 Technical Committee on Absolute Spectral

Responsivity.

Member, CIE Committee Div. 02 on Physical Measurement of Light and

Radi at ion.

Member, U.S. National Committee of the CIE.

Member, OSA Ines Medal Award Selection Committee.

108
JOURNAL EDITORSHIPS

Division 534, Radiometric Physics

Zalewski, E.F., International Advisory Board, Optica Pura y Aplicada

109
STANDARDS COMMITTEE MEETINGS

Division 534, Radiometric Physics

CORM Directors Meeting, Department of Commerce, January 28, 1986.

USNC Technical Council and Executive Committee Meeting, NBS, March 18-19,

1986.

CCG Meetings, NBS, May 27-30, 1986

110
STANDARDS WRITING

Division 534, Radiometric Physics

J. Cohen, New Standard Test Method For Minimum Resolvable Temperature

Difference for Thermal Imaging Systems, ASTM E- 07 . 10.04 on Infrared

Methods. (Approved by Subcommittee Votes, August 1986)

J. Cohen, New Definitions of Terms Relating to NDT by Infrared

Thermography. (Approved by Subcommittee Votes, August 1986)

111
MAJOR CONSULTING AND ADVISORY SERVICES

Division 534, Radiometric Physics

J. Geist and E. Zalewski advised Naval Research Laboratory on the

selection of the best photo-sensors to measure laser radiation directed at

a spaceborne target: LDEF/ITS Mission.

J. J. Hsia provided consultation to S. Mohan of Indian Institute of

Science on specular reflectance measurements of thin films.

J. J. Hsia advised Sol Glicker of NASA Goddard Space Flight Center on developing a goniophotometer to measure bidirectional reflectance

distribution function.

J. J. Hsia and V. R. Weidner provided consultation to Roy Berns of The

Rochester Institute of Technology on reflectance measurements of NBS

supplied gray diffusers.

J. J. Hsia provided consultation to Roger McCleary of Eastman Kodak on diffuse transmittance measurement methods.

D. A. McSparron served as a consultant to the Growth Chambers and

Controlled Environments Working Group of the American Society for

Hort icultural Science on optical radiation measurements in plant growth

chambers.

D. A. McSparron and J. H. Walker provided consultation and advice to

representat ives of Negretti Aviation on appropriate measurements and

standards to establish traceability of their infrared pyrometric

measurements for the jet turbine industry.

V. R. Weidner provided consultation to Sadegh Siahatgon and Sandra Holder

of Naval Sea System Command on specular reflectance measurements on multi 1 ayer mirrors.

E. Zalewski provided consultation to the Countermeasures Branch of the

U.S. Army Tank Automotive Command, on photodetector linearity in the near infrared region and associated transmittance measurement problems.

112
STANDARD REFERENCE MATERIALS

Division 534, Radiometric Physics

1.

SRM 1001, X-Ray Film Step Tablet

For calibration of optical densitometers and similar equipment used

in the photographic, graphic arts, and x-ray fields. Certified for

optical densities from 0 to 4.

2.

SRM 1008, Photographic Step Tablets

For calibration of optical densitometers and similar equipment used

in the photographic and graphic arts fields. Certified for optical

densities form 0 to 4.

3.

SRM 1010a, Microcopy Resolution Tests Charts

For determining the resolving power of microcopy systems.

4. SRM 2061, Reflection Step Tablets

For calibration of reflection densitometers and similar equipment

used in the photographic and graphic arts fields. Certified for

optical density from 0 to 2.

5. SRM 2019 and 2020, White Ceramic Tile for Directional-Hemispherical

Reflectance from 350 to 2500 nm. SRM 2021 and 2022, Black Porcelain Enamel for DirectionalHemi spherical Reflectance from 280 to 2500 nm. SRM 2015 and 2016, White Opal Glass for Directional-Hemispherical

Reflectance from 400 to 750 nm.

For use in calibrating the reflectance scale of an integrating sphere

ref lectometer.

6. SRM 2003b, First Surface Aluminum Mirror for Specular Reflectance

from 250 to 2500 nm. SRM 2011, First Surface Gold Mirror for Specular Reflectance from 600

to 2500 nm. SRM 2023, 2024, and 2025 Second Surface Aluminum Mirror for Specular

Reflectance from 250 to 2500 nm.

For use in calibrating the photometric scale of specular

ref lectometers.

7. SRM 2009, 2010, 2013, 2014 Didymium-Oxide glass as Wavelength

Standards between 400 and 760 nm.

113
Division 534, Standard Reference Materials (cont'd)

8. SRM 2034 Holmium oxide in Perchloric Acid Solution as Wavelength

Standards between 241 and 640 nm.

9. SRM 1920 Near Infrared Reflectance Wavelength Standards from 740-2000

nm. (In preparation).

114
MEASUREMENT ASSURANCE SERVICES

Division 534, Radiometric Physics

1. Transmittance MAP Service

Provides a means for a laboratory to assess the accuracy of its

spectral transmittance measurement capabilities from 92% to 0.1% in

the visible region.

2. Retroref lectance MAP Service for Coefficient of Luminous Intensity

Provides a means for a laboratory to assess the accuracy of its

coefficient of luminous intensity measurement capabilities for bead

sheeting and prismatic cube-corner retroref lectors and to assess the

conformity to the spectral specification of its retroref lectometers.

115
CALIBRATION SERVICES PERFORMED

Division 534, Radiometric Physics

Number of

Type of Service Customer SP250 tests

Pyrometry 7.4 A 40

thru G

Defense & Aerospace 25

Instrument & Cal labs 6

Lighting & Photography 3

Electrical & Materials 6

Spectroradi omet ry 7.5 A 23

thru J

Defense & Aerospace 8

Instrument & Cal labs 8

Lighting & Photography 1 Foreign 3

Electrical & Materials 3

Photometry 7.7 A 32

thru R

Defense & Aerospace 17

Instrument & Cal labs 6

Lighting & Photography 6

Foreign 2 Electrical & Materials 1

Spectrophotometry 7.8 A 24

thru I

Defense & Aerospace 7 Instrument & Cal labs 7 Lighting & Photography 2 Electrical & Materials 8

119

116
TRIPS SPONSORED BY OTHERS

Division 534, Radiometric Physics

J. J. Hsia, Laboratory visits to Hungary, partially sponsored by Protocol

Agreement between NBS and Hungarian National Office of Measures, Budgapest

and Institute of Technical Physics in Hungarian Academy of Sciences,

Budapest.

E. F. Zalewski, sponsored by the U.S. Army Tank Command, Countermeasures

Branch, travel to Warren, Michigan to consult on photodetector linearity

measurements, February 24-26, 1986.

117
SPONSORED SEMINARS AND COLLOQUIA

Division 534, Radiometric Physics

Dr. W. Borucki, "Photometric (Radiometric) Search for other Solar

Systems", Radiometric Physics Division Photodetector Physics and Metrology

Group Seminar, October 1985.

118
TECHNICAL ACTIVITIES

Division 535, Radiation Source and Instrumentation

CW Accelerator Research (Microtron) (P. H. Debenham)

The joint NBS-Los Alamos project of "Research on CW Electron

Accelerators Using Room-Temperature RF Structures" began seven years ago

with the goal of developing a technology base for cw electron accelerators. Many significant technical advances have been made as a part of

this project, which is funded by DoE. Among the earliest contributions

was the unexpected experimental discovery that the disk and washer accelerating structure sustains transverse deflecting modes that make it un- suitable for use in a recirculating accelerator. 1 We then developed a reliable room temperature accelerating structure with a high cw voltage

gradient. 2 This structure has been adopted with minor modifications by

the University of Illinois for their proposed 450 MeV cascaded microtron. 3 The structure also provides an important part of the engineering data base

for high-gradient cw rf structures for applications outside nuclear physics being pursued at Los Alamos and elsewhere.

Our 100 keV beam line with its unique chopper-buncher system has been

adopted by two microtron laboratories (University of Illinois and Mainz

University) and will be used at CEBAF. Our unique design for racetrack

microtron (RTM) end magnets is an important advance in achieving high

field uniformity over a large area. The University of Illinois has had

exact copies of our end magnets built for their microtron. Our beam profile scanner design has been sent to many laboratories, and is being used

by The University of Saskatchewan and MIT.

An essential part of this research project is the design, construction and operation of a demonstration accelerator. The demonstration

accelerator, as shown in Figure 1, consists of a 5 MeV injector feeding a racetrack microtron. In the microtron, a pair of 180° end magnets recirculate the beam through a 12 MeV linac 15 times for an energy gain of

180 MeV. The control system for the demonstration accelerator is fully

1 L .M. Young and J.M. Potter, "Deflecting Modes in the DAW Structure for

the Racetrack Microtron," Los Alamos National Laboratory, Accelerator

Technology Division, Group AT-1 memorandum No. AT-1: 82-59 (March 17,

1982)

.

2 L .M. Young and J.M. Potter, "CW Side-Coupled Linac for the Los Alamos/NBS

Racetrack Microtron," IEEE Trans. Nucl . Sci . NS-30 , 3508 (1 983).

3 L.S. Cardman et al , "Nuclear Physics Research with a 450 MeV Cascade

Microtron," unpublished (1 986).

119
120

Figure

1

Plan

view

of

the

demonstration

accelerator.
Division 535, CW Accelerator Research (Microtron) (cont'd.)

functional. The rf power system is unique and simple: a single, 450 kW cw klystron powers four accelerating sections with independent phase and

amplitude control of each section. The rf system is in place and has been

operated to power the 5 MeV injector linac. It is temporarily inoperative

while the klystron power supply is modified for reliable operation. The

injector is complete and has produced a 5 MeV cw electron beam with an energy width of 11 keV. Extensive measurements of the injector beam properties will be made as soon as the rf system is again operational. The

end magnets have been field-mapped, are aligned, and are ready to operate.

The 12 MeV linac is aligned in place between the end magnets, has been vacuum and low-power tested, and will be high-power tested when the rf

system is operational.

In the future, this project will continue to make important contributions to science and technology. CEBAF has expressed much interest in

several aspects of our project. The performance measurements of our injector are directly applicable to their injector, and CEBAF personnel

intend to participate in the measurements. They also plan to gain operational experience on the demonstration accelerator prior to commissioning

their accelerator. The project includes measurements of the threshold

current for beam breakup (BBU) in the demonstration accelerator early in

1988. The measurements will be used to validate the computer program

which is used to calculate the BBU threshold current for CEBAF, and will

be available in time to influence design decisions.

The demonstration accelerator, when completed at NBS in mid 1988,

will be the

# only 200 MeV cw electron accelerator in the US and will have

the highest cw current and power in the world. Naturally, such a unique

facility is attracting a good deal of interest. NBS is committed to supporting a nuclear physics research program based on the RTM and is developing plans for a high energy dosimetry program.

There is also a good deal of interest in using the high power, low

emittance beam of the RTM as a free-el ectron laser (FEL) driver. An 0NRfunded study concludes that the RTM becomes an excellent FEL driver if the

present thermionic cathode electron gun is replaced with a laser-driven

photocathode for higher peak current. Modification of the RTM for FEL

operation will not be part of the present project.

In order to have three simultaneous cw electron beams with different

currents, CEBAF needs an injector that can modulate the beam current in

three successive micropulses with good dynamic range. A photocathode

injector can meet this requirement, and CEBAF is very interested in having

us develop a prototype photocathode system for them and test it with the

RTM.

In summary, this project has made many significant contributions and

promises to make many more. In the remainder of this report we describe

121
Division 535, CW Accelerator Research (Microtron) (cont'd.)

in detail the technical accomplishments of the project in FY 1986. This

year we produced a 5 MeV electron beam for the first time with the demonstration accelerator injector. The properties of this beam appear to be

excellent. Definitive injector beam measurements have been pushed to the

beginning of FY 1 S87 by the need to modify the klystron power supply in

the rf system for reliable operation.

Meanwhile, preparations have been underway for transporting the injector beam to the RTM for one and two passes through the RTM linac.

Components of the 5 MeV beam transport line and the RTM linac axis beam

line are in procurement. The RTM linac was installed, aligned, and con- nected for rf power. The field of the second end magnet was mapped and

found to be satisfactory, and both end magnets were aligned. The control

system has been modified for improved reliability and is being expanded

for one- and two-pass RTM operation. STRACE, the RTM raytracing program,

was improved for better accuracy and was used to find a linac-to-end magnet spacing that will give a good longitudinal phase space match between

the injector and RTM.

A. Injector

1. Introduction

The RTM injector consists of an electron gun in a 100 kV terminal, a 100 keV beam transport line, a 5 MeV injector linac, and a 5 MeV beam

transport line. The performance of the 100 keV stage was measured previously, and in November 1985 the injector linac accelerated a cw beam to 5 MeV for the first time. Repeated failures of the klystron power supply

unfortunately prevented operation of the injector linac after November,

leaving both development of wirescanners for 5 MeV electrons and definitive measurements of 5 MeV beam properties incomplete. Nonetheless, the

5 MeV beam properties appear to be excellent, judging from spot sizes on viewscreens. The 5 MeV measurements will be resumed as soon as the klystron power supply is operational. Meanwhile, we are procuring all components needed to complete the 5 MeV beam transport line, which will be

assembled immediately after completion of the injector beam measurements.

2. Injector Beam Tests

During the fall of 1985, the 5 MeV injector was operated on a schedule of three two-week periods between periods of construction in the RTM

room. Preliminary injector beam measurements were done using the first

stage of the 5 MeV transport system, shown in Figure 2. During these

runs, the phase and amplitude controls of the high power rf system were de-bugged, the injector linac was conditioned under power, and the

computer-control 1 ed conditioning system brought into operation. In addition, the wi rescanner and rf beam monitors were tested, with the beaminduced signals being transported to the main control room through a

122
M U 1 . ^ ill J

‘ - c V \

• . \o i

„Ai ".1 h.i

0 •

r im

B j; \ i

-jM ^ 0 V"|l

Figure 2 Photo of the first stage of the 5 MeV beam transport system

as viewed from above the exit of the injector linac. The

beamstop and viewscreen in the 45° beam line are in a temporary position for the injector beam measurements.

123
Division 535, CW Accelerator Research (Microtron) (cont'd.)

computer-controlled remote coaxial switch for the first time. After optimizing the capture section and the preaccelerator phases with a pulsed

beam, we obtained a 5 MeV pulsed beam. After conditioning the linac further with a low-current cw beam, we obtained a low-current, 5 MeV cw

beam.

The injector beam tests were begun by first finding the correct phasing of the capture section with respect to the bunched beam, for minimum

energy spread at near maximum energy gain, with the preaccelerator off.

This condition was determined by using the dispersion in the first 45°

dipole magnet (Dl) in the 5 MeV transport system. Figure 3 shows the beam

spot on a view screen 54 cm from the exit of the magnet. The energy

spread, as defined by the width of the beam spot, is reduced by a factor

of three when the buncher is turned on with the correct relative phase.

The magnetic field required in Dl corresponds to a beam energy of

1.25 MeV.

Next, the preaccelerator was conditioned to a level that would sus- tain a moderate energy gain, and the preaccelerator phase was adjusted to

provide the minimum energy spread at near maximum energy gain, by the same technique used for the capture section. From the width of the beam on the

viewscreen and the known magnet dispersion, the energy spread was estimated to be 11 KeV. Further optimization, over a range of beam energies,

beam current, and buncher amplitude, is planned.

We next began conditioning the linac with a low-current cw beam. On

November 8, a 40 yA cw beam was accelerated to 5 MeV and dumped into the

0° beam stop. Further conditioning for acceleration of high-current cw beams was underway when, on November 18, the klystron power supply failed.

After it is repaired, injector beam measurements will resume.

3. 5 MeV Transport and RTM Axis Beam Lines

After the injector beam measurements have been completed at the end

of FY86, the remaining section of the 5 MeV beam transport line and RTM

axis beam line will be assembled in order to begin one-pass and two-pass

operation of the RTM. The 5 MeV transport line is shown in Figure 4.

Detailed design of all magnets for these beam lines was completed in this

year, and all magnets and power supplies are either on hand or in procurement. An assembled 30° dipole magnet is shown in Figure 5. All wire and

cable needed to connect these beam lines to the power supplies and the

control system are on order or in hand.

Because most of these magnet designs are tightly constrained, we have

ended up doing the steel design and fabrication in house. Coils were fabricated to our specifications by vendors through competitive bidding.

All magnets will be mapped prior to installation.

124
(b) Buncher off

Figure 3 Image of the 1.25 MeV beam spot on a viewscreen 54 cm from

the 45° exit of dipole magnet, D1 , (a) with the buncher on and (b) with the buncher off. The irregularities in the

spot shape are due to fiducial marks on the viewscreen.

Momentum dispersion is horizontal in these photos.

125
€t; -

RTM f

=£

ACC.

INI ACC.

X* 1 NJ s \A \ Jl T

U*—D3

W6- tr=rP^'

Figure 4 Plan view of the 5 MeV beam transport line from the injector

to the RTM.

126
fee

!a' f v “ \

127

Figure

5

30°

Dipole

magnet

D4

for

5

MeV

beam

transport

line.

The

magnet

is

shown

actual

size.
Division 535, CW Accelerator Research (Microtron) (cont'd.)

Vacuum chambers for the 15° and 30° magnets, D3, D4 and D5 will consist of curved sections of 1" OD seamless, 300-series stainless steel

tubing. Permeability measurements on this material showed that bending to

the required radii had no measurable effect on the original permeability

of less than 1.05. Rectangular cross sections are required for the vacuum chambers in the remaining dipole magnets on these beam lines. To avoid

distortions in the dipole magnetic fields, the rectangular vacuum chambers

will be made of copper, brazed to non-magnetic stainless steel flanges or adapter rings.

B. Microtron

1 . Introduction

The microtron consists of a 12 MeV linac, two end magnets, beam lines

to recirculate the beam through the linac, and a beam line to extract the

beam and measure its properties. In FY 1 986 we concentrated on preparing

the microtron for one-pass and two-pass operation, which requires everything but the return beam lines and the extraction beam line. The 12 MeV

linac was installed, aligned, vacuum tested, and connected to the rf system. The second end magnet was mapped and found to have acceptable field

quality, and both end magnets were aligned. Both the main power supply

for the end magnets and the power supply for the active field clamps passed final acceptance tests at NBS. All magnets on the linac axis beam line

are in procurement, and many vacuum components of the microtron are on hand

.

2. End Magnet Field Mapping

The end magnets were designed to generate a uniform field in the

operating range 0.8 T to 1.2 T with a field uniformity such that the phase

error (i.e., path length error) on every orbit is less than 2°. The fiell

of end magnet El, presented in last year's annual report, is considerably

more uniform than required. The field of end magnet E2 was mappal in

October 1985, with the results shown in Figure 6. The orbi t-average!

spatial field variation in magnet E2 is roughly four times greater than

El, yet the fields of the two magnets together produce a calculated phase

error of less than 2° on every orbit. This means that the RTM will operate over the design end magnet field range of 0.8 T to 1.2 T with the end

magnets as built, without shimming.

The reason for the different field quality of these two magnets is

not obvious. The end magnet vendor first delivered magnet E2, then two

magnets of the same design and specifications to the University of

Illinois, and finally magnet El. The field quality of the University of

Illinois magnets is intermediate between that of El and E2. Since all

four magnets were made to the same specifications, the improvement in

field uniformity with production order can probably be attributed to the

vendor's increased experience with time.

128
X (CM)

Figure 6 Contour plots of (aB/B 0 ) x 104 as measured for end magnet E2.

From top to bottom,

B

0 is 0.8, 1.0, and 1.2T. Negative contours

are shown as broken lines.

129
Division 535, CW Accelerator Research (Microtron) (cont'd.)

3. End Magnet Alignment

The most stringent requirement on the alignment of the end magnets is

that any misalignment must be compensated with the steering magnets on the

return beam lines. The strength of these return-line steering magnets is

limited to 125 gauss*cm by the requirement that the power supply noise

(typically 10 -3

) should make a negligible contribution to beam emittance.

This requirement limits the tolerable end magnet misalignment to no more

than 0.05 mrad in all planes.

The end magnets have been aligned with the required accuracy. The

poles of both magnets were leveled using a theodolite and a back-lighted,

high precision optical target which could be moved over the entire pole

surface. Our measurable accuracy was ±25 ym (±.001 in) everywhere, which

is three times better than needed. Perpendicularity to the linac axis

beam line and parallelism between the two magnets were achieved using a theodolite and an optical ly-fl at , front-surface, 8" diameter mirror and

autocol 1 imating over 12 m. Our accuracy of measurement was ±125 ym

(±.005 in), which is many times better than needed.

4. 12 MeV Linac Alignment

The 12 MeV linac has been installed and aligned in the RTM room. The

alignment was done using a theodolite and a lighted optical target, which

was moved through the center bore of the structure one cell at a time.

With this method, we found a ±0.5 mm cell-to-cell misalignment from manu- facturing which effectively reduces the through diameter from 10 mm to

9 mm. In order to further refine our measurements we set up a 1 cm diameter alignment laser on the nominal beam line. The collimated beam

measured on a target at the output end of the structure was 9 mm. This was further collimated with a 0.5 mm diameter hole on the structure

centerline and this was autocol 1 imated with the mirror used for magnet

alignment. The laser light was not visible around the edges of the 0.5 mm diameter.

5. Extraction Hole

A ten inch diameter hole for the extraction beam line has been drilled from the north wall of the RTM room into the magnet room. The alignment requirement of ±2 inches was easily exceeded. The hole has been

plugged temporarily to allow operation of the L-band linac with the RTM room occupied.

130
Division 535, CW Accelerator Research (Microtron) (cont'd.)

C. RF System and Structures

1. Introduction

During FY 1986, the rf system was completed with the shipment of the

12 MeV RTM linac from Los Alamos to NBS and its installation in the RTM

room. Cooling water and waveguide connections were also completed. Beam

tests performed on the injector linac confirmed the calculations and

measurements made at Los Alamos of the effective shunt impedence (ZT2

) of

the side-coupled structure. The RF control system has operated very reliably and is currently being completed to include the 12 MeV linac and its

associated temperature controls, power monitors, and waveguide power

splitters and phase shifters. Unfortunately, problems have continued with

the klystron power supply. However, a replacement of improved design for

the troublesome part, the variable transformer, has been ordered and is

scheduled for installation in November 1986.

2. RF Power

The rf power system consists of a 65 kV DC power supply, a 450 kW cw klystron, a crowbar unit, and an rf circulator to protect the klystron

from reflected power. The 65 kV DC 16. 5A power supplies at Los Alamos and

NBS have a history of problems, listed in Table 1. Most of these problems

have been corrected either by us or by the power supply manufacturer.

However, one component, the variable transformer (PVT), has failed repeatedly and seems to be under-engineered.

The variable transformer is a 13.8 k V line-to-line (8 kV to ground),

oil immersed autotransformer design. Its failure mode consists of severe

arcing at the sliding brush assembly contacts of the autotransformer

,

which burns through the transformer windings. After the last failure in

January 1986, it was examined by high voltage transmission experts in the

Electrosystems Division at the National Bureau of Standards. Their opinion is that the turn- to-turn voltage of the PVT was too high, and that once arcing initiates across the brush assembly the oil breaks down and

accelerates the frequency and severity of the arcing, which ultimately

destroys the transformer. The power supplies built for our project were

among the first to use the 13.8 kV PVT built by this manufacturer. Later

units built for the storage ring at Cornell have similar problems. We

therefore felt that rebuilding the PVT as before would not solve the problem, as the design is not suitable for such high voltages.

With the assistance of Dr. Wagih Fam, on leave from the University of

Halifax, Nova Scotia, Canada where he is the Electrical Engineering

Department Chairman, replacement designs for the PVT were sought from both

the original manufacturer of the power supply and from other manufacturers

of high voltage, high power supplies. Four different technologies were offered by six different companies. These designs used induction voltage

131
Division 535, CW Accelerator Research (Microtron) (cont'd.)

Table 1 Hipotronics 65 kV-16.5 A Power Supplies, February 12, 1986

Los Alamos

Summer 81 Power supply installed.

December 81 Power supply commissioned, with crowbar modified at Los

Alamos. Output voltage ripple is 15%.

Spring 83 New PVT with balancing windings installed. Ripple is re- duced to 2%. Original PVT returned to Hipotronics to be

modified for NBS.

April 84 PVT failure. Balancing windings moved, shorted. PVT re- turned to Hipotronics for repair.

Summer 84 Rebuilt PVT installed with reinforced balancing windings.

Used successfully for injector linac power tests.

September 85 PVT removed and sent to NBS.

NBS

Fall 81 Power supply installed.

October 83 PVT replaced with former Los Alamos PVT with balancing windings added. Original PVT returned to Hipotronics.

September 84 PVT returned to Hipotronics for reinforcement of balancing

wi ndi ngs.

November 84 PVT returned to NBS without modification. Hipotronics

claims strength of balancing windings is adequate.

April 85 Power supply turned on for first time.

August 85 PVT failure. Balancing winding for one phase moved, shorted. Main windings for two phases burned through at brush

contact. PVT returned to Hipotronics for repair.

October 85 Power supply turned on with Los Alamos PVT installed.

November 85 Los Alamos PVT failed. All main windings burned through at

brush contact. PVT returned to Hipotronics for repair.

January 86 Rebuilt NBS PVT installed. Power supply operated for two

days before PVT failed.

132
Division 535, CW Accelerator Research (Microtron) (cont'd.)

regulators, multiple tap changing under load tran sformer-swi tch assemblies, very large 13.2 k V conventional variable autotran sformer s with low

turn-to-turn voltages, and lower voltage variable transformers used in a bucking mode against the incoming line voltage. It was determined that

the first three options would be either too expensive ($80K - $150K) and/

or take to long to contract, build and install (20 - 60 weeks). The original manufacturer offered to build a bucking transformer design for $20K.

It will consi st of:

1. PVT Model 60A260-260Y14

Input: 2600 V, 3 <f>, 60 Hz, 690 KVA

Output: 0-2600 V @ 150 A, Wye Connected

2. Isolation Transformer

Pri. 13.2 kV 0 690 kVA, 3 <j> , 60 Hz, Delta Connected

Sec. 2600 V @ 150 A, Wye Connected

3. Buck/Boost Transformer

Pri. 1500 V 0 690 kVA, 3 <j> , 60 Hz, Delta Connected

Sec. 4600 V @ 50 A

and connected as shown in Figure 7. The manufacturer will connect up the

controls and interlocks to be compatible with the existing system. We

believe this represents the best solution to be had given the time and

money constraints. The manufacturer' s reputation for the lower voltage

variable transformers is good. Also, as it is a bucking design, the variable transformer is isolated from surges and has only 690 kVA flowing

through it rather than 1.2 MVA. The contract was let May 16, 1986, and

the replacement unit is scheduled for installation in September 1986.

3. Injector Linac and Controls

The RTM injector linac consists of a 1 m capture section followed by

a 2.7 m preaccelerator section. The injector linac has been operated with

beam at full voltage (5.0 MeV). Initial beam measurements show that the

preaccelerator has an effective shunt impedence (ZT2

) of 93 ± 10% Mft/m, in

agreement with the voltage gradient measurements done at Los Alamos.

The rf control system has operated very well the past year. We have

developed an auto conditioning/power turn on program. For normal operation, this program automatically raises the power level in two linac sec- tions from zero to full operating levels in a few minutes. The program

raises the forward power and monitors both reverse power and vacuum for

each linac. It also varies the frequency of the klystron to allow faster

starts when the linac structures are cold and have a higher resonant frequency. The program is invaluable both during rf conditioning and normal

power turn-on. The program will be modified so all four linac sections

can be run up together.

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Division 535, CW Accelerator Research (Microtron) (cont'd.)

The power splitters, phase shifters, waveguide, and controls have all

been installed for the 12 MeV linac and are currently being wired up.

4. 12 MeV Linac

The final two 4 m linac sections for the main RTM were shipped to NBS

from Los Alamos in February 86 and installed in the RTM room. Once at

NBS, they were vacuum leak tested, and the cooling water system was tested

for leakage. The two tanks then were connected to the rf system and water

cooling lines were installed. Figure 8 shows the completed installation.

Once the klystron power supply is repaired, rf conditioning and power

testing of the 12 MeV linac will begin.

D. Beam Diagnostics

During FY 1986, construction of beam diagnostics equipment for the

RTM beyond the injector line was initiated. The final two rf phase, current and position monitors were constructed and shipped to NBS, where they

await installation at each end of the RTM linac. All parts for the con- struction of 20 viewscreen mechanisms and 20 wi rescanners were purchased,

and construction of subassemblies and electronics has been initiated.

Wire scanners were tested using the 5 MeV beam from the RTM injector

linac. Ground loops produced 20 - 100 mV of noise on the signals observed

in the control room, which is a 150 m wire run from the RTM room. This

noise was reduced to less than 2mV (or less than 50 ym in position resolution of the beam) by "floating" the oscilloscope used in these tests by

means of a ground i sol ator/monitor. This technique was also found to be

necessary for the rf beam monitor signals. Ultimately, the wi rescanner

signals will be digitized in the electrical service cubicle adjacent to

the RTM room, where ground loop noise is not a problem.

The wi rescanners were also used this year by an atomic physics group

at NBS to detect a 200 nA 2 keV Xe + beam. Also, blueprints of the wi re- scanner were sent to CEBAF at their request for consideration for use with

the new 4-6 GeV electron accelerator.

E. Control System

1. Introduction

As stated in last year's report, most of the basic control system

(shown in Figure 9) has been installed and operationally tested. The only

remaining major subsystem not completed is the wire-scanner diagnostic

system. Present plans call for the construction of this system in FY 87.

During the past year work on the control system has been directed

toward the design and installation of various device interfaces to the

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Division 535, CW Accelerator Research (Microtron) (cont'd.)

existing secondary stations in preparation for one- and two-pass beam

tests, diagnosis and correction of system problems uncovered during our initial 5 MeV beam tests, and development of high level application code

for the primary station CP/M subsystem.

2.

Analog Signal Switching

A large number of analog signals must be routed to the primary station from the accelerator, including viewscreen television and current

monitoring signals, aperture currents, and rf beam monitor signals. While

the number of analog signals exceeds 68, no more than 14 signals can be

viewed at the primary station at one time.

A custom coaxial matrix switch assembly was designed and assembled,

from commercially available modules, to route up to 14 of these analog

signals, under operator control, for display at the primary station console. This assembly was installed in the rf secondary station and interfaced to it. Input/output driver code was written to allow operator se- lection of the analog signal combinations to be routed to the primary

station console. This system was used successfully for our initial 5 MeV

beam tests and will be expanded to accommodate full accelerator operation.

3. Active Field. Cl amp Power Supply

Final acceptance testing of the dual -channel , 300 A power supply for

the end magnet active field clamps included installation and operational

testing of the IEEE-488 bus control input. This required modification of

the vendor- supplied controller configuration code and connection to our existing end magnet power supply control and monitoring system. Functional testing of the 488 bus control of the dual channel supply was success- fully completed in late 1985.

4. Motor Drives for End Magnet Movement

For two-pass beam tests, it will be necessary to move end magnet El

parallel to the linac axis for phasing the one-pass, 17 MeV beam with the

main accelerator for the second pass. We have selected and tested a stepping motor and a commercial electronic motor drive module which together

move the end magnet rapidly and with a setting accuracy of 50 pm. A single IEEE-488 bus connected to the injector secondary station will handle

the control and monitoring of the end magnet position, current, and magnetic field. This system will be complete with the delivery of a position

monitor and the development of the IEEE-488 bus input/output driver soft- ware for the secondary station.

138
Division 535, CW Accelerator Research (Microtron) (cont'd.)

5. Vacuum Control and Interlock Systems

The design of the RTM vacuum control and interlock systems was reported in last year's annual report. At that time, the injector portion

of the two systems had been installed, wired, and used for the 5 MeV beam

tests. After completion of the initial 5 MeV beam tests, device input/

output panels were installed to facilitate the connection of RTM devices

to the interlock and vacuum control system. The injector portion of these

systems was rewired to the I/O panels and the overall wiring of the system

d ressed

In parallel with rewiring of the injector section, the design, wire

list preparation and wiring for both one- and two-pass operation and com- plete accelerator operation is now in progress. No problems are anticipated in having these systems operational and tested in time for the

scheduled one- and two-pass beam tests.

6. RF Power Control and Conditioning Program

In addition to the Fortran coded functions described in last years

report, we have now developed a moderately complex Fortran coded application program to ramp up the rf power to operating levels in two linac

sections at more than two to three times the rate the same operation could

be performed by the operator. Similar gains were observed for rf power • conditioning of the structures. Since this function requires the nearly

simultaneous control of three parameters, namely, rf power, power split

between the two structures, and frequency, and the monitoring of many

more, it was an obvious operating function for programmed control. This

rf control program will be expanded to include the control and monitoring

functions for the two sections of the 12 MeV linac once they are placed in

operation. With the increased number of control and monitored parameters

required by the addition of the 12 MeV linac, this program will be essential for RTM rf system power conditioning and ramping up to operating rf

power 1 evel s.

7. Improved Control from the Primary Station

During initial rf power conditioning and 5 MeV beam tests, erratic

control system operation from the primary station was discovered when

attempting to control devices at the end of the data base list in the rf

secondary station. Subsequent tests showed this behavior was related

solely to control of devices beyond approximately 120 entries in the data

base, and was even more evident when attempting to read or write to devices from the primary station CP/M subsystem with high level language

application programs, such as the previously discussed rf power control

program.

139
Division 535, CW Accelerator Research (Microtron) (cont'd.)

The problem was determined to be caused by insufficient delay in the

wait loops of the primary stati on-to- secondary station link servicing

routines in the primary station. Reliable operation was achieved by increasing the delays of both the primary station main code data link read/

write requests and the correspond i ng CP/M link input/output requests from

5 ms to 30 ms. Although this modification to the primary station software

does decrease the response time of the control system at the primary station, the required change is small enough that it is not perceptible to

the operator.

The overall source of this problem is the linear search algorithm

used by the secondary station link service request code. Namely, primary

station control/data update request service response times from the sec- ondary stations are a linear function of the specified data position in

the database list. Thus, as the data base size of an individual secondary

station increases, the worst case (last item in the listing) service re- quest time increases proportionately.

8. Small Magnet Power Supplies

We have developed a design for a 1 A, 15 VDC, bipolar, dual-channel

power supply for the many small steering and focusing magnets on the RTM.

Two hundred-eight of these supplies were fabricated by a commercial vendor

and were tested at Los Alamos for correct operation with the RTM control

system. In the past year these power supplies were operated with magnets

on the 5 MeV beam transport line, and intolerable current oscillations

were observed. After investigating alternate designs to overcome these

oscillations, we decided that the most practical solution was the simple

addition of a shunt capacitor of approximately 1 pF. This solution limits

the output current fluctuations to less than a part in 10 3.

F. Accelerator Theory

1. Introduction

Computer modeling of the RTM is done on the NBS central computing

facility to determine design and operating parameters of the RTM and to

study the performance characteri sties of the machine. At present, accelerator physics codes PTRACE, STRACE, TRANSPORT and TRIM are running on the new NBS central computers, with BEAMRAD expected to be running by the end

of FY 1986. Two major improvements were made in STRACE: first, the correct first-order (transverse) motion for a standing-wave (SW) linac has

been incorporated; second, the accuracy of the longitudinal motion calculations in linac sections has been improved. A spacing between end magnet

El and the RTM linac was found which results in a longitudinal phase space

match between the injector and the RTM.

140
Division 535, CW Accelerator Research (Microtron) (cont'd.)

2. Conversion to New Computer System

In 1985 NBS replaced its UNIVAC 1100 computer system with a CYBER 205

supercomputer serviced by a CYBER 855 front-end computer. This required

that we learn two new operating systems and convert our programs to run on the new system. Our old versions of PTRACE, STRACE and TRIM were converted to run on the CYBER 855 and/or the CYBER 205, but a new version of

TRANSPORT that runs on the CYBER 855 was obtained from Fermilab. BEAMRAD

should be running on the new system by the end of FY86. We have seen a significant improvement in both speed and accuracy on the CYBER 205. For

example, on a particular problem that was run on the UNIVAC 1100 and on the CYBER 205, STRACE used about one tenth the cpu time on the 205 than it

did on the 1100. We also ran a large magnet-design problem, using TRIM,

on the 205 that had been previously run on the 1100 and compared the output from both runs. The slightly jagged, non- physical magnetic field

distribution calculated on the 1100 became smooth on the 205, indicating a reduction in computational error.

3. Improvements in Program STRACE

Two major improvements were made in STRACE: the correct first-order

transverse motion in a SW linac has been incorporated , and the accuracy of

longitudinal motion calculations in linac sections has been improved.

The transverse particle motion in the old version of STRACE was that

of a traveling wave (TW) linac, which is a poor representation of a SW

linac. As demonstrated in last year's annual report to DoE (Appendix K),

STRACE underestimated transverse focusing in a SW linac by two orders of

magnitude. A new subroutine called SWACC, which stands for Standing Wave

Accelerator, was written this year to replace the old TW linac subroutine

FEACC. SWACC calculates the transverse particle motion in a SW rf linac

correctly to first order using a modified version of the first order

transverse transfer matrix derived by E.E. Chambers. 4 (We chose to use particle momentum rather than energy as a variable.) A comparison between PARMELA and the improved version of STRACE showed an agreement within 11%.

STRACE calculations of acceleration from 4.7 to 10.5 MeV in a four

meter linac section produce errors of about 15 keV in energy and .8 degrees in phase if the section is treated as a single element in the calculation. By subdividing a four meter linac section into smaller mathematical units, errors were reduced to acceptable levels. These errors are greatest at low energies in long linac sections where the assumption of

4 R.E. Rand, "Recirculating Electron Accelerators," Accelerators and

Storage Rings Vol . 3, Harwood Academic Publishers, 1984.

141
Division 535, CW Accelerator Research (Microtron) (cont'd.)

linear phase shift of the beam particles with respect to the rf wave is

invalid. The new accelerator subroutine SWACC automatically breaks up the

longitudinal integration into steps such that the phase shift in the first

step is less than the specified maximum, DPHMX (a new input parameter).

The default value of DPHMX is 2 degrees, which has proved to be adequate

for most calculations.

4. Longitudinal Phase Space Matching of Injector Output to RTM

Input

A spacing between the RTM linac exit and the effective field boundary

of end magnet El was found which resulted in a match between the injector

and the RTM. Optimization of the longitudinal beam dynamics in the RTM

resulted in a fixed 1 Ott keV*deg longitudinal phase space ellipse at 23

MeV, midway between the two 4 m linac sections. Several particles on this

ellipse were raytraced backwards, through the 17 MeV turnaround , to the

linac entrance. The resulting figure in longitudinal phase space at 5 MeV

encloses a region into which the injected beam must fit for proper matching to the RTM. The range of shapes and orientations of this figure was investigated by varying the spacing between the linac exit and end magnet

El. An optimal spacing was found for a good match between the injector

and RTM, as shown in Figure 10. Injector linac output phase space, con- structed from PARMELA calculations for nominal preaccel erator phase, was sheared by 0.08 deg/keV to obtain a match. The required shear will be

accomplished in the 5 MeV transport line by ad justi ng. the field in Q5.

Free Electron Laser Facility (S. Penner)

A study was initiated in FY 1986 to investigate the suitability of

the NBS RTM as the electron beam source for a free electron laser (FEL).

The study was funded by the Office of Naval Research, and performed in

collaboration with Drs. Phillip Sprangle and Cha-mei Tang of the Naval

Research Laboratory (NRL).

An FEL extracts energy from an electron beam in the form of a coherent beam of nearly monochromatic radiation. The principle of operation is as follows: A relativistic electron beam is passed through a "wiggler,"

wherein an array of magnets produces a periodic strong transverse magnetic

field. The electron beam emits synchrotron radiation in a narrow cone

centered on its direction of propagation through the wiggler due to the

transverse oscillations of the electrons in the magnetic field. Synchrotron radiation from successive periods of the wiggler will be coherent

when the wavelength, X, of the radiation satisfies the relationship
AE

(KeV)

-2 -1 0 1 2

A<p (Deg)

Figure 10 Longitudinal phase space plots of the beam at the

entrance to the linac for the best match between injector

and RTM. The shaded region represents the injector beam

particles (from PARMELA), for nominal preaccelerator

phase, after undergoing a .08 deg/keV shear in the 5 MeV

transport line. It is contained within the RTM longitudinal acceptance for 10 keV-deg.

143
Division 535, CW Accelerator Research (Microtron) (cont'd.)

where A wis the wiggler period, y is the electron energy in units of electron rest energy, and K is the "wiggler parameter" which is proportional

to the strength of the magnetic field and is typically of order unity.

The "spontaneous, coherent" radiation is reflected back through the

wiggler by a mirror, then reflected again to copropagate with the electron

beam. Beam electrons are bunched at the optical wavelength by the electromagnetic fields of the radiation, and thus emit still more radiation.

(In a quantum mechanical analysis of the process, additional coherent

radiation is stimulated by the presence of the original radiation, hence

the use of the term laser in describing the device.) In travelling once through the wiggler, the radiation field is amplified with some "gain,"

the necessary energy being extracted from the electron beam. If the gain

per pass is greater than the sum of all losses per pass, the radiation

will build up on successive passes until saturated equilibrium occurs. Losses are due to mi rror reflectivity, diffraction effects, and the "outcoupling" of some of the radiation for some, presumably useful, purpose.

The expected small energy spread, emittance, and beam stability of

the RTM are very important factors in FEL performance. The operating

energy range of the RTM is suitable for producing radiation in the wave- length range of about 0.25 ym to 10 ym spanning the range from the near

UV, through the visible and near IR. The emitted light is extremely intense (hundreds of watts, time averaged, for a 100 kW electron beam) and

nearly 100% spatially coherent. The light beam has the same time structure as the electron beam, i.e. pulse lengths of a few picoseconds, and

its frequency bandwidth should be just the transform limit of the pulse

length (<0.1% in the visible region). In addition to the fundamental

laser radiation, significant amounts of spontaneous coherent radiation are emitted at the odd harmonics of the fundamental. For some applications,

useful amounts of radiation would be available at wavelengths of order 30 nm. The combination of high power, easy tuneability over a very large

range, spatial coherence, reasonably small bandwidth and a continuous

train of very short pulses makes an FEL an extremely useful tool for a very wide variety of applications including photochemistry, surface

science, atomic and molecular physics, and biophysics.

The ONR-funded feasibility study showed that the gain of an FEL based

on the design peak current of the RTM would be marginal (i.e. 1-3 percent

per pass) even with a very long, precise, and expensive wiggler. The

problem is the relatively small peak current of the CW microtron, 140 mA,

limited by the available RF power at design beam energy. We examined the

possibility of increasing the peak current by recapturing some of the

electron energy in the RTM by beam recirculation. This proved not to be

useful because of the small longitudinal phase space acceptance of the RTM

(compared to the degraded longitudinal emittance of the beam which has

generated laser light). Vie next considered enhancing the peak current

without increasing the average current by injecting electrons during only

144
Division 535, CW Accelerator Research (Microtron) (cont'd.)

a fraction of the RF cycles, i .e. by not filling every RF "bucket." For

example, if we fill only one bucket in 24, the average current is within

the power limit for peak current up to 3.4 A. With peak currents in

excess of 2 A, the FEL single-pass (small signal) gain is in the range

10-20% with a 3.6 m long wiggler, having a 2.8 cm period for wavelengths

in the range 0.25 - 2 urn. For longer wavelengths, a shorter wiggler is

used. There are several possible methods for generating the required

pulses of electrons for subharmonic injection. The method which appears

most attractive is to use a short-pulse mode-locked laser operating at a subharmonic of the RF frequency to produce electrons by photoemission from

a suitable cathode material.

In response to an announcement by the Strategic Defense Initiative

Office (SDIO) of the possibility of funding for a facility for performing

research in biomedical and materials sciences applications of FELs, we have performed a preliminary design and cost study and submitted a proposal to develop an FEL facility at NBS using the RTM. The proposal, developed jointly by NBS and NRL, requests $4.9 million from SDIO over three

years. NBS would, in addition, supply a new laboratory building, three

staff scientists salaries, RTM operation as needed to test and calibrate

the FEL, and some general purpose equipment. The new laboratory, a 2000

ft2 building located above the existing linac facility, would house the

experiments using the FEL radiation. Since it would be shielded from the

underground space containing the RTM and FEL, there would be no significant background radiation from the RTM (or linac) in this area. We are proposing that the FEL radiation be used by NBS staff and external collaborators for programs in atomic physics, molecular spectroscopy, biophysics, surface sciences, and FEL technology. Outside users from such

institutions as the Uniformed Services University of the Health Sciences

(USUHS) and Electro-Optics Branch of the Center for Devices and Radiological Health of FDA have expressed interest and enthusiasm for using the

facility for biomedical research applications.

145
LINAC OPERATIONS (J. Broberg)

Division 535, Radiation Source and Instrumentation Division

The MBS Electron Linac v/as designed in 1 960 with maximum flexibility

in order to support a wide variety of program activities of interest to

NBS. Due to the changes in program directions the linac has been used

mostly for neutron cross section standards and radiography. We also have

supplied beam to a group from Pennsylvania State University for calibration of nuclear detectors.

The Linac Operations staff has in spite of its relatively small size,

continues to achieve a highly commendable operating efficiency as described below. The staff operates and maintains the facility as well as designs, constructs, and installs new equipment to improve operations and

extend the capability of the Linac and the beam handling system. The

Mechanical Instrumentation Group within the Division provides help by

maintaining the integrity of the vacuum and cooling systems of both the

Linac and beam handling system as well as designing, constructing, and

installing mechanical components. All but 140 hours of beam time was run for the Neutron group; that was used by Pennsylvania State University. We

have supplied 1275.0 hours to actual beam time to the Neutron group at an efficiency approaching 90% (exact efficiency figures are difficult to

calculate due to many canceled scheduled times and running nonscheduled

runs for the Neutron program). The unscheduled maintenance of 86.0 hours,

through August 31, is broken down and summarized by system in Table I. The small amount of unscheduled maintenance is due in part to having extra

periods during no operation to do preventive maintenance.

The RTM is operational to an extent that testing is now necessary,

and since the building water cooling system will not permit both the Linac

and the RTM to operate simultaneously, their operations must be scheduled

jointly. The long range plan is to operate the Linac approximately 1/3 of

the time and the RTM 2/3 of the time. With our operational staffing and

assuming an 80% efficiency of operation this should give us about 1200

hours of Linac beam time and about 2400 hours of RTM time a year.

146
Division 535, Linac Operations (con'd.)

TABLE I

LINAC OPERATIONS

FY 86

LINAC: Total unscheduled maintenance 86.0 hours

System:

Modul ators 34.4 hours 40.0%

Injector 21 .5 hours 25.0%

RF Drive 4.3 hours 5.0%

Vacuum 8.6 hours 10.0%

No other system or item over 2%.

BHS: Total unscheduled maintenance 5.0 hours.

Balance of total unscheduled maintenance, 12.2 hours, due to air

conditioning and power outage.

147
INSTRUMENTATION SERVICES

Division 535, Radiation Source and Instrumentation

Electronic Instrumentation Maintenance and Construction (J.K. Whittaker & J. Owen)

Provision of electronics instrumentation maintenance and construction

services for the experimental programs of the Center for Radiation

Research is a continuing responsibility of the Radiation Instrumentation

Group in the Division. Instruments designed and constructed during 1985

number about 85 and maintenance has involved about 67 instruments.

Instrumentation Design and Construction (J.K. Whittaker, N.D. Wilkin, A.B.

Marel la, & J. Owen)

Design and construction of experiment and system control and interlock instrumentation is a continuing and important element of the

Radiation Instrumentation Group activities. Examples of this instrumentation this year include: automatic sample changer redesign and construction (used in the manufacture of SRMs); design, construction and modification of instrumentation for the State Regional Calibration Centers (for

x-rays); computer controlled specimen manipulator for an electron microscope; alpha-particle detector system (computer controlled) using RAM cell

upset; wire-chamber detector for an electron spectrometer; microcomputer

system integration and applications; microcomputer CAD system integration

and test; pul se-rad i oly si s data acquisition instrumentation; miscellaneous

computer systems, communication links, interlock systems, detector electronics, and radiation monitors

Instrumentation Support for Physics and Chemistry Projects (J.K.

Whittaker, N.D. Wilkin, & A.B. Marella)

Consulting and systems instrumentation has been provided to scientists in programs relating to neutron physics, electron physics, surface

electron physics, x-ray dosimetry, radiation chemistry, vacuum ultraviolet

physics (SURF), analytical chemistry, and physical chemistry. In addition, very considerable support has been provided for RTM projects, one Group technician being assigned full-time to the project with extra as- sistance on a requirements basis apart from the systems noted above.

Application of microcomputers for many laboratory and office requirements continues, available financing limiting the number. The new wire

chamber detectors for electron physics is nearly complete with all the

(micron-sized) wire, having been soldered into place and nearly all physical construction problems solved. The first generation of an alpha- particle detection system has been delivered. This used the individual bitcells of an unencapsulated dynamic RAM to detect the radiation. Further

148
Division 535, Instrumentation Services (cont'd.)

development of this system will be undertaken. Initial studies have been

started for the automation of the NBS standard microcal orimetry system for

X-ray dosimetry.

The Group continues to operate the HP 9845-based computer-aided

design (CAD) system available to all NBS personnel. A second HP 9836-

based system has been brought on-line for Group CAD operations. The

intense use of these CAD facilities has enabled the Group to maintain

effective productivity in the face of a labor shortage. There also is

an opportunity to use computer-aided engineering (CAE) software and hardware to enhance the effectiveness of Group personnel. It is estimated

that the total cost of present CAD systems was recovered in no more than 9

months of operation. New CAE systems should be even more cost effective.

The Tektronix software development system has been delivered and is

operational. This is a joint operation between Group and RTM personnel.

Further expansion of the system to include more advanced emulation facilities (for the 68020 microcomputer) and for a digital analysis system with

multichannel digital timing analysis (with software recognition facility)

is an excellent opportunity.

Consultation by the Group expert staff continues to be important - not only to CRR but to other Centers in NBS. The cooperative AID program

with the Egyptian National Institute of Standards and the Egyptian Organization for Standards and Quality Control has now been successfully completed with Whittaker spending 3 weeks in Cairo with these two organizations in July 1986.

The cooperative program with Harry Diamond Laboratories continues

very successfully with seven mi crocomputer systems and two mi crocomputerbased CAD systems being delivered. The consultation component of this

program has been most productive.

Mechanical Instrumentation Services (D. Mohr)

Mechanical instrumentation services were provided for the Center for

Radiation Research in connection with its particle accelerators and its

experimental programs. The services provided consisted of design and

construction of new equipment and facilities as well as maintenance and

modification of existing equipment to improve performance and reliability.

Instrumentation Design and Construction (D. Mohr)

Design and construction of mechanical devices is an ongoing and

important element of the mechanical instrumentation group activities.

Examples of these devices built this year are: 15° and 30° high precision

dipole magnets for the RTM 5 MeV injection beam line; four dipole magnets

149
Division 535, Instrumentation Services (cont'd.)

for the RTM main accelerator axis; numerically controlled linear motion

assembly for the 30 ton RTM end magnets; precision optical alignment fixtures for the RTM end magents and the 12 MeV RTM main accelerator.

Installation and Maintenance of Facilities (D. Mohr)

Another major element of our activities is installation and maintenance of major facilities. Examples this year are: installation and

alignment to ±.002" of the RTM 12 MeV main accelerator; installation of

the RF drive system to the RTM main accelerator including both power

splitters and phase shifters; rebuilt a Model 12 electron gun for the NBS

linac; rebuilt vacuum pumps for SURF, Linac and the 3 MeV Van de Graaff;

maintained the mechanical and vacuum equipment on the linac to allow in

excess of 90% beam efficiency.

The group staff continues to provide consultation service to other

groups in CRR and other NBS organizations. The staff is also consulted by

people outside NBS who build and operate accelerators worldwide.

The single CAD/CAM workstation is operational and has allowed us to

design six precision magnets this year. Lack of funds prevented the

installation of a second needed unit this year. The full potential of

this technology will only be realized when several more units are operational .

150
RADIATION INSTRUMENTATION STANDARDS (L. Costrell)

Division 535, Radiation Source and Instrumentation

The Division provides national leadership in the standardization of

nuclear instrumentation. The standards work falls into three categories

as follows: (a) National Voluntary Standards - The Division plays an active role in the development and processing of Standards of the Institute of Electrical and Electronic Engineers (IEEE) and the American

National Standards Institute (ANSI) and participates in the associated

policy boards. L. Costrell serves as Chairman of ANSI Committee N42 on Radiation Instruments and as Secretary of the IEEE Nuclear Instruments and

Detectors Committee. In these capacities he has processed a considerable

number of ANSI and IEEE standards, serves on the ANSI Nuclear Standards

Board, and i s a member of its Planning Committee.

(b) ance of instrument

ies, primarily for

NIM Committee Standards - This involves development and maintenstandards, in cooperation with the National Laboratoruse in nuclear applications. NBS has the management

for this work, with L. Costrell serving as Chairman of the

The Nuclear Instrumentation Module (NIM) system has been

universally in the U.S. and is a continuous coordination

contact with numerous laboratories and manufacturand maintenance are provided in the

CAMAC (Computer Automated MeasureLaboratories and

re spon sibil ity

NIM Committee,

adopted nearly

requirement involving

ers. Similar management, direction

U.S. with regard to the international

ment and Control) system that is utilized in the National

in a large number of other laboratories and installations

world. A third system for which the Division has similar

is the FASTBUS high speed modular data acquisition system

physics and other applications. The FASTBUS development

throughout the

responsibil ity

for high energy

has been a major

effort with commercial equipment now available and systems in operation

in preparation in numerous laboratories in the U.S., Europe, and Japan.

or

The preparation of reports for the above systems involves a number of

individuals and laboratories. Coordination and processing, as well as writing of some sections, is handled by the National Bureau of Standards.

The documents are usually issued as Reports of the Department of Energy

and then processed as Standards of the Institute of Electrical and Electronics Engineers (IEEE), the American National Standards Institute

(ANSI), and the International Electrotechnical Commission (IEC).

151
Division 535, Radiation Instrumentation Standards (cont'd.)

The Nuclear Instrument Module (NIM) system1 ’ 2 has had a phenomenal

acceptance in laboratories and industry throughout the world. There is a continuous coordination requirement involving contact with numerous laboratories and manufacturers and the resolution of questions that arise. In order to allow and encourage exploitation of technological development

without impairing compatibility and interchangeability, continued vigil- ance and direction is essential and is provided. The shift from discrete

components to integrated circuits and the increasing use of computers and

mi coprocessors necessitates continued accommodation to those devices.

Work is proceeding on updating the NIM standard in the light of developments and practice. Also, the division continues to provide information

regarding the CAMAC standards. 3

The FASTBUS standard, previously issued as a Department of Energy

Report, 4 has been updated and issued as a standard of the Institute of

Electrical and Electronics Engineers (IEEE) and the American National

Standards Institute (ANSI). 5 Processing as an international standard of

the IEC is also progressing with the draft currently being balloted by the

National Committees.

The NIM and CAMAC standard instrumentation projects have resulted in

a savings of at least 1.9 billion 1982 dollars according to a study con- ducted for the Department of Energy by a firm of economics consultants. 6 The study report states that the 1.9 billion dollars is considered to be a minimum figure conservatively arrived at on the basis of available data.

1.7 billion dollars is attributed to the NIM system initiated by the

1 "Standard Nuclear Instrument Modules," AEC (now DOE) Report T

I

D-20893

(Rev 4), July 1974 (currently under revision).

2 "Standard NIM Digital Bus (NIM/GPIB)," Department of Energy Report

D0E/ER-01 73 , August 1983.

3 CAMAC Instrumentation and Interface Standards, IEEE Publication SH08482,

Library of Congress Catalog No. 8185060 (ANSI/IEEE Std s 583, 595, 596,

675, 683, 726, 758).

4 "FASTBUS Modular High Speed Data Acquisition and Control System," DOE

Report D0E/ER-0189, December 1983.

5 "FASTBUS Modular High Speed Data Acquisition and Control System,"

ANSI/IEEE Std 960-1986.

6 "Benefit Analysis of Selected Accomplishments of DOE's Office of Health

and Environmental Research," Final Rpnort R&-166, November 29 , 1982 , Ecosometrics, Inc. (M. Lago, M.J. Ram sd ell, S.F. Knapp, S.I. Siddique,

Bethesda, MD.)

152
Division 535, Radiation Instrumentation Standards (cont'd.)

Center for Radiation Research 7 and the balance of 200 million dollars to

the CAMAC instrumentation system developed by the ESONE Committee of

European Laboratories with the active collaboration of the U.S. NIM

Committee and the CRR. The report adds: "The benefits were estimated

only if they could be documented from the literature or telephone con- tacts. There are a number of other direct and indirect benefits associated with the use of CAMAC and NIM interfaces which were not considered in

this analysis because no measureable data were available." The total

worldwide savings can be reasonably projected to be double the U.S sav- ings.

(c) International Electrotechnical Commission - L. Costrell serves

as Technical Advisor to the U.S. National Committee of the IEC for IEC

Committee TC45 on Nuclear Instruments. He serves as Chief U.S. Delegate

to TC45, as Chairman of the Working Group on Detectors and as a member of

the working groups on Interchangeability and on Terminology. Numerous IEC

draft documents were prepared and reviewed resulting in a number that were

published and others that are to be published. These include documents

that are technically identical to the NIM and CAMAC standard s.

1 ,2 ,3

Similarly, the FASTBUS document being processed as an international standard i s to be technically identical to ANSI/IEEE Std 960-1986 5 and the

international standard on test procedures for germanium semiconductor

detectors i s to be technically identical to ANSI/IEEE Std 325 that is to

be published soon.

7 "Standard Modules for Nuclear Instrumentation," NBS Report 8137,

December 5, 1963, L. Costrell.

153
INVITED TALKS

Division 535, Radiation Source and Instrumentation

Ayres, R.L., "Control System for the NBS Microtron Accelerator," Second

International Workshop on Accelerator Control Systems, Los Alamos, New

Mexico, October 7, 1985.

Costrell, L., Short Course, "FASTBUS Modular High-Speed Data Acquisition

and Control System", National Science Symposium, San Francisco,

California, October 22, 1985.

Costrell, L., "Standard Modular Instrumentation Systems Developed for the

Nuclear Field," The Institute for Standardization of China, Beijing, The

People's Republic of China, May 13, 1986.

Costrell, L., "Development of the Scintillation and Semiconductor

Radiation Detectors", The Institute for Standardization of China, Beijing,

The People's Republic of China, May 14, 1986.

Costrell, L., Short Course, "FASTBUS Modular High-Speed Data Acquisition

and Control System," Los Alamos National Laboratory, Los Alamos, New

Mexico, September 16 - 17, 1986.

Cutler, R.I., and Wilson, M.A., "Report on NATO Advanced Study Institute

on High Brightness Accelerator," NBS Nuclear, Radiological and Accelerator

Physics Seminar, Gaithersburg, Maryland, September 18, 1 986.

Penner, S., "Linacs for Microtrons and Pulse Stretchers," 1986 Linear

Accelerator Conference, Stanford, California, June 5, 1986.

154
PUBLICATIONS

Division 535, Radiation Source and Instrumentation

Department of Energy NIM Committee, L. Costrell, Chairman and Project

Leader, ANSI/IEEE Std 960-1986: "FASTBUS Modular High-Speed Data

Acquisition and Control System", The Institute of Electrical and

Electronics Engineers, Library of Congress No. 85-081331, 1986.

Martin, E.R., Trout, R.E., Wilson, B.L., Ayres, R.L., and Yoder, N.R.,

Control System for the NBS Microtron Accelerator, Proceedings of the

Second International Workshop on Accelerator Control Systems, Los Alamos,

New Mexico, October 7-10, 1985.

Penner, S., Linacs for Microtrons and Pulse Stretchers, to be published in

the Proceedings of the 1986 Linear Accelerator Conference, Stanford,

California, June 2-6, 1986.

Tang, C-M., Sprangle, P., Penner, S., Kincaid, B.M., Freeman, R.R.,

Proposal for FEL Experiments Driven by the National Bureau of Standards'

CW Microtron, Proceedings of the 7th International Free Electron Laser

Conference, Tahoe City, California, September 8-1 3, 1985.

155
PUBLICATIONS IN PREPARATION

Division 535, Radiation Source and Instrumentation

Cutler, R.I., Owen, J.C., and Whittaker, J.K., Performance of Wire Scanner

Beam Profile Monitors to Determine the Quittance and Position of High

Power CW Electron Beams of the NBS-Los Alamos Racetrack Microtron (in

preparation)

.

Cutler, R.I., and Young, L.M., Performance of the High Power RF System of

the NBS-Los Alamos Racetrack Microtron (in preparation).

Debenham, P.H., Penner, S., Wilson, M.A., and Bruce, S.S., Injection

Chicane Magnets for a Racetrack Microtron (in preparation).

Maruyama, X.K., Penner, S., Tang, C., and Sprangle, P., Proposal for a Free Electron Laser Driven by the National Bureau of Standards' CW

Microtron (in preparation).

Penner, S«, RF Linac Based Free Electron Lasers (in preparati on)

.

Tang, C.M., Sprangle, P., Penner, S. and Maruyama, X.K., Analysis of FEL

Performance Utilizing the National Bureau of Standards' (NBS) CW Microtron

(in preparation)

.

Wilkin, N.D., Downing, G., and Whittaker, J.K., Alpha Particle Detector

Using RAM Cell Upset (in preparation).

Wilson, M.A., Ayres, R.L., Cutler, R.I., Debenham, P.H., Lindstrom, E.R.,

Mohr, D.L., Penner, S., Rose, J.E., Young, L.M., and Stovall, J.,

Performance of the 5 MeV Injector for the NBS-Los Alamos Racetrack

Microtron (in preparati on)

.

Wilson, M.A., Debenham, P.H., Penner, S., and Bruce, S.S., Orbit Reversing

Magnets for the NBS-Los Alamos Racetrack Microtron (in preparation) .

156
TECHNICAL AND PROFESSIONAL COMMITTEE PARTICIPATION AND LEADERSHIP

Division 535, Radiation Source and Instrumentation

Robert L. Ayres

Member, ANSI Technical Committee N42.2 on Procedural Standards for

Calibration of Detectors for Radioactive Materials

Member, CRR Word Processing Task Force

Member, IEEE P1014/VMEbus Standard Committee

Member, NBS RIF Assignment Panel

Member, Science and Technical Pool, Science Panel, Committee on Interagency Radiation Research and Policy Coordination (CIRRPC)

Member, NBS Storeroom Committee for ADP

U.S. Representative, Life Sciences Working Group of the International

Committee for Radionuclide Metrology

Louis Costrell

Chairman, ANSI Technical Committee N42, Nuclear Instruments

Chairman, DoE National Instrumentation Methods (NIM) Committee

Chairman, NBS Inventions and Patents Committee

Chairman, IEC/TC45 Working Group-9 on Radiation Detectors

Chief U.S. Delegate, International Electrotechnical Commission (IEC),

Technical Committee on Nuclear Instruments (IEC/TC45)

Member, ANSI Technical Committee N41, Controls, Instrumentation, and

Electrical Systems for Nuclear Power Generating Stations

Member, IEC/TC45 Working Group-1 on Classification and Terminology

Member, IEC/TC45 Working Group-3 on Interchangeability

Member, 1985 Particle Accelerator Conference Organizing Committee

Member, U.S. National Committee of International Electrotechnical

Commission (IEC)

157
Division 535, Technical and Professional Committee Participation and

Leadership (cont'd.)

Secretary, Institute of Electrical and Electronics Engineers Nuclea

Instruments and Detectors Committee of IEEE Nuclear and Plasma

Sciences Society (IEEE/NPSS)

Technical Advisor, U.S. National Committee of IEC

Philip H. Debenham

Member, DoE POISSON Working Group

Member, SDIO review team for the Neutral Beam Test Facility and the

Radiation Effects Facility at Brookhaven National Laboratory

Member, Small Business Innovation Research Review Panel

Member, 1987 Particle Accelerator Conference Program Committee

Participant, Workshop on "CEBAF Spectrometer Magnet Design and

Technol ogy"

Samuel Penner

Chairman, 1 987 Particle Accelerator Conference

Member, Organizing Committee for 1986 Heavy Ion Fusion Symposium

Member, Organizing Committee for 1986 Linear Accelerator Conference

Julian K. Whittaker

Member, ASTM Committee D-22 on Methods of Sampling and Analysis of

Atmospheres

Member, DoC Industry and Trade Administration, Electronic Instrumen

tation Technical Advisory Committee

158
Division 535, Technical and Professional Committee Participation and

Leadership (cont'd.)

Neil D. Wilkin

Member, Editing Committee for IEEE Nuclear and Space Radiation

Effects Conference Publication

Member, Electronics Storeroom Committee, NBS

Senior Member, Institute of Electrical and Electronics Engineers

Mark A. Wilson

Member, Organizing Committee for Heavy Ion Fusion Symposium,

Washington, DC, May 27-29, 1986

159
MAJOR CONSULTING AND ADVISORY SERVICES

Division 535, Radiation Source and Instrumentation

1. R. Ayres serves as a member of the U.S. Pharmacopoeia Convention

Advisory Panel to the Subcommittee on Radiopharmaceuticals.

2. S. Penner and M. Wilson continue to provide Accelerator Technology

and Assessment and Oversight for DARPA.

3. S. Penner serves as a consultant to the U.S. Army Strategic Defense

Command on particle accelerator issues related to programs in Free

Electron Lasers and Neutral Particle Beam Weapons.

4. S. Penner i s on a part time detail for one year to the Department of

Defense, acting as Scientific Advisor to the Director, Innovative

Science and Technology Office, SOI.

5. J. Whittaker serves as a consultant on instrumentation and instrumentation maintenance and repair to AID for the Egyptian Government

Standards Laboratories.

6. J. Whittaker serves as a consultant on electronics instrumentation

and instrumentation repair and maintenance to the University of

Petroleum and Minerals, Dhahran, Saudi Arabia.

7. N. Wilkin serves as consultant on mi crocomputers and semiconductor

radiation hardness testing to Harry Diamond Laboratories.

8. N. Wilkin serves as consultant on microcomputer control of fuze

instrumentation for Harry Diamond Laboratories.

160
SPONSORED SEMINARS AND COLLOQUIA

Division 535, Radiation Source and Instrumentation

NBS Nuclear, Radiological & Accelerator Physics Seminar, "Technology

Options for CEBAF," Christoph Leemann, Continuous Electron Beam

Accelerator Facility, Gaithersburg, Md., November 1, 1985.

NBS Nuclear, Radiological & Accelerator Physics Seminar, "Large Momentum

Transfer Electron Scattering and the Compression Modules of Nuclear

Matter," Joseph Speth, KFA Julich & University of Bonn, Gaithersburg, Md.

,

July 2, 1986.

161

TECHNICAL ACTIVITIES

Division 536, Ionizing Radiation

The functions of the Ionizing Radiation Division are summarized in

the following table:

» Provides primary national standards, dosimetry methods, measurement

services, and basic data for applications of ionizing radiation (x

rays, gamma rays, electrons, neutrons, and radioactivity, etc.) in such areas as:

- Radiation protection of workers and the general public

- Radiation therapy and diagnosis

- Nuclear medicine

- Radiography

- Industrial radiation processing

- Nuclear energy

- National defense

- Environmental protection

• Conducts theoretical and experimental research on the fundamental

physical and chemical interactions of ionizing radiation with matter to

provide the competence for:

- Developing improved understanding of the physical stage of the

interaction of ionizing radiation with matter

- Developing an understanding of basic mechanisms involved in

radiation-induced chemical transformations and the parameters that

influence the yields of short-lived intermediates, final chemical

products, and biological effects

- Developing improved methods for radiation measurement, dosimetry,

and radiography

- Developing improved primary ionizing radiation standards

- Producing highly accurate standard reference data for ionizing

radiation or radioactive materials

9 Provides essential standards and measurement support services to the

National Measurement Support System for Ionizing Radiation that

provides calibrations and measurement quality assurance services to:

- Medicine

Industry

- States

- Other Federal Agencies

163
Division 536, Technical Activities (cont'd.)

© Develops and operates wel 1 -character! zed sources of electrons, photons,

and neutrons to provide:

- Primary radiation standards and fields

- Wel 1 -characterized beams of radiation for research on radiation

interactions and for measurement methods development.

The group structure (with leaders) of the Ionizing Radiation Division is:

Ionizing Radiation Division (R. S. Caswell)

Office of Radiation Measurement (E. H. Eisenhower)

Radiation Theory (M. J. Berger)

Radiation Chemistry & Chemical Dosimetry (M. G. Simic, Acting)

Neutron Measurements & Research (0. A. Wasson)

Neutron Dosimetry (J. A. Grundl)

Radioactivity (D. D. Hoppes)

X-ray Physics (J. W. Motz)

Dosimetry (R. Loevinger).

Some of the thrusts of the Ionizing Radiation Division at this time are:

(1) radiation chemistry and chemical dosimetry; (2) planning a facility

for high-energy electron and photon dosimetry using the microtron; (3) a new technique for high sensitivity in radioactivity measurement, SIRIS

(sputter-induced resonance ionization spectroscopy); (4) documentation of

all our existing calibration services; (5) improvement of our national

measurement standard for radon and measurement compatabi 1 ity among leading

national laboratories; (6) automation of standards facilities and calibration services; and, (7) measurement quality assurance of ionizing radiation measurements throughout the nation using an intermediate-level

laboratory network.

Office of Radiation Measurement

The function of the Office of Radiation Measurement is to promote the

dissemination to federal, state, and local radiation control programs, and

to the medical, industrial, and defense communities, of the measurement

standards and technology required for reliable measurement of ionizing

radiation. The Office assists the technical organi zational components of

the Ionizing Radiation Division in monitoring the radiation measurement

needs of these national user groups, and in activities undertaken to meet

national needs. The latter include methods for improving the consistency

of field measurements with the national physical measurement standards,

through a national system of secondary standards 1 aboratori es. The Office

maintains liaison with organizations that conduct measurement-intensive

programs in the areas, of radiation safety, energy, health, and environmental contamination. Examples are the Nuclear Regulatory Commission,

Department of Energy, Food and Drug Administration, Environmental

Protection Agency, Health Physics Society, and the Conference of Radiation

164
Division 536, Technical Activities (cont'd.)

Control Program Directors. The Office participates in collaborative

programs with these organizations to satisfy specific measurement quality

assurance requi rement s. Another function of the Office is to provide the

chairman for American National Standards Committee N43, concerned with

equipment for non-medical applications of ionizing radiation.

Survey Instrument Calibration Laboratories (E. H. Eisenhower)

The quality of measurements made for radiation protection is of

increasing concern to radiation workers, employers, and regulatory

agencies. An instrument used to make these measurements must be calibrated periodically in order to achieve adequate accuracy.

During the meeting of its Executive Board on June 29, 1986 the Health

Physics Society approved the implementation of a national program whereby

it will accredit laboratories that calibrate ionizing radiation survey

instruments. This program is an outgrowth of a workshop held by NBS in

July 1984, and was developed in response to demand from the radiation

measurement community. The Society plans to accredit laboratories at the

secondary and tertiary levels, using technical criteria developed collaboratively with the NBS Office of Radiation Measurement to evaluate their

qualifications and performance. It is estimated that as many as 12

secondary laboratories will be accredited, and that up to 40 may be

accredited at the tertiary level. NBS will be represented on the team

that will do on-site assessments of secondary laboratories and will

periodically test their calibration performance. These secondary laboratories will, in turn, assess candidate tertiary laboratories and test

their performance. Accredited laboratories at both levels will follow

approved, documented procedures for providing calibration services and

routine quality control. The program is expected to become operational in

January 1987 and will be self-supporting through fees payed

by accredited laboratories. Initially, laboratories will be accredited

for calibrations with x and gamma radiation; neutron and beta radiation

will be added in the future.

Directory of Calibration Laboratories (H. T. Heaton & E. H. Eisenhower)

In cooperation with the Radiation Measurements Committee of the

Conference of Radiation Control Program Directors, the Office has revised

the 1981 "Directory of Commercial Calibration Services for Ionizing

Radiation Survey Instruments". The revised directory contains information

provided by 95 laboratories in response to a questionnaire. This

information is presented in three tables. The first lists each company by

name, state, number and types of radiation sources available for

calibrations (alpha, beta, gamma, x, and neutron), whether repair services

are offered, and pertinent limitations on services. The second table

provides detai 1 ed information about the calibration services provided by

each company, including type of radiation source, range of intensities and

165
Division 536, Technical Activities (cont'd.)

energies available, method used, and claimed calibration accuracy. The

third table shows the name of each company contact, plus address and

telephone number. Introductory material includes definitions of terms

(calibration, accuracy, survey instrument, transfer standard), the fundamentals of measurement quality assurance (MQA), and character!' sties of

radiation sources. The 1981 version of this directory was prepared in

response to numerous requests about the availability of calibration

services, and has proved to be very useful. It is now outdated and will

be replaced by the new, improved version.

State-Operated Calibration Laboratories (H. T. Heaton & E. H. Eisenhower)

The Office is continuing its interaction with five states

( IL,SC ,WA,CA,AR) to establish laboratories for calibrating ionizing radiation instruments used in state and local radiation control programs.

Their capability includes x-ray and gamma-ray calibrations at levels suitable for radiation protection and diagnostic applications. When any of

these laboratories meets documented criteria, it will be accredited by the

Conference of Radiation Control Program Directors (CRCPD).

The first laboratory that achieved accreditation, in June 1984, is

located in Springfield, IL. To date it is the only laboratory accredited

for both x-ray and gamma-ray calibrations. The radiation sources include

3 Ci and 30 mCi 137 Cs calibrators, and a 150 kV x-ray machine. During the

past year this laboratory calibrated instruments for eight state radiation

control programs. All of these states requested gamma-ray calibrations

and two of them requested x-ray calibrations. This laboratory recently

purchased a computer and is developing familiarity with its use.

The laboratory in Seattle, WA was the second to be accredited by the

CRCPD, in September 1986, but this accreditation is only for gamma-ray

calibrations with 3 Ci and 30 mCi 137 Cs sources. Permanent installation

of the 150 kV x-ray machine is proceeding slowly due to limited funding

from the Washington radiation control program. This laboratory has been

calibrating instruments for both the Washington and Oregon control

programs.

The Columbia, SC laboratory has successfully completed the first

performance test for calibrations using a 150 kV x-ray machine. A draft

procedures manual has been prepared and an application for accreditation

has been submitted to the CRCPD. Once accreditation for x-ray calibrations has been received, installation of the 3 Ci and 30 mCi 137 Cs sources

will begin.

During the past year the laboratory in Sacramento, CA was remodeled

for better space utilization and environmental control. The old manually

operated 50 Ci 137 Cs source was replaced with a new pneumatically operated

166
Division 536, Technical Activities (cont'd.)

unit consisting of three 137 Cs sources of 100 Ci , 3 Ci , and 130 mCi . There is also a system with four remotely insertable attenuators to

provide 16 combinations for attenuation values between 2 and 8000. A

computer was installed during the past year, and a computer program for

x-ray and gamma-ray calibrations is being tested for suitability.

Specific laboratory parameters necessary to use the computer code are being measured, and a procedures manual is being prepared. Collaboration

with personnel from the California Division of Measurement Standards

continues to provide procedures for basic supportive measurements.

In Fayetteville, AR two sites are being developed as calibration

laboratories. High-level neutron and gamma-ray calibrations will be done

at a former experimental reactor facility (SEF0R), and low-level gamma,

beta, neutron and x-ray calibrations are planned at the Engineering

Experiment Station. Both bare and heavy-water moderated 252 Cf neutron

sources are available at the SEF0R site, where room return has been determined for various instruments. At the Experiment Station, room return for

the bare californium source was recently measured to be between 5 and 9

percent for the instruments of interest. Calibration cross checks for the

bare source show agreement to about 1 percent. Monte Carlo calculations

for two source encapsulations have been carried out. These calculations

show a significant anisotropy in the equatorial plane. A performance test

for neutron calibrations is planned for next fiscal year.

Each state-operated laboratory except Arkansas has had its electrometer and picoampere source modified so they can be calibrated using a computer code. All these electrometers and picoampere sources have been

recalibrated to provide baseline data for the routine quality control

programs used to monitor such system components.

Computer Codes for Instrument Calibration (H. T. Heaton)

Two computer codes have been written primarily to assist the stateoperated laboratories in calibrating various pieces of equipment. The

first code was written so that each laboratory can calibrate its electrometer and picoamper source in-house. This procedure required modifications

to this equipment to provide the additional signals necessary. The zener voltage for the digital voltmeter used to read the feedback circuit in the

electrometer is provided as a voltage standard. The output resistors of

the picoampere source are calibrated against a known 0.01 percent resistor

using an iterative procedure. The calibrated picoampere source is then

used to calibrate the coulomb and current ranges of the electrometer. The

computer code provides information on how the various components should be

set to perform this calibration and analyses the data to determine the

appropriate factors.

167
Division 536, Technical Activities (cont'd.)

The second computer code was developed for calibrating instruments in

x-ray and gamma-ray fields. The code consists of three major parts. The

first part provides procedures and analysis for the routine QC measurements necessary to ensure that all of the equipment used in the calibration procedure is operating within statistical control since the time it was calibrated. The current version of the code has QC procedures for

monitoring the el ectrometer/pi coampere source, x-ray machine output for

given conditions, gamma source output, in-house test instrument calibration, and environmental parameters in the laboratory. The second part of

the code determines the measured field from the x-ray machine and the

calculated field at a given distance- on a given day from the gamma source. This calculation is based on a non-linear regression analysis to experimental measurements using a model which includes build-up in air, attenuation in air, inverse square dependence, and an approximate term to account

for wall return. The last part of the code provides information on calibrating specific types of instruments for x rays and gamma rays and

calculates the cal ibration/correction factor from the measured data. The

code warns the operator if the statistical spread in a given set of

measurements is greater than expected, if the measured field from a selected x-ray beam at the expected current is not within preselected limits,

and if the correction factors for the RADCAL 1015 X-ray Monitor (the

instrument most commonly used by state radiation control programs for

their compliance measurements) for selected x-ray beams is not within

normal variation from the historical data set.

Measurement Theory (R. Colle)

The Office's expertise in the treatment and reporting of measurement

uncertainties continues to be very useful to groups both within and external to NBS. In the past year, many individuals and groups have been

assisted by the Office. In particular, an Office staff member critically

evaluated the uncertainty statements provided in the calibration reports

of several Divisions, gave presentations to two groups within NBS, and

served on a "panel of experts" at the 1986 International Conference on Precision Electromagnetic Measurements.

A staff member of the Office has also been selected to chair a newly

established Working Group on the Expression of Measurement Uncertainties

under the aegis of the International Standards Organization. This group

has been charged with developing a document, based upon the CIPM recommen- dations, which will provide guidance on the expression of measurement

uncertainties for use within standardization, calibration, laboratory

accreditation, and metrology services.

168
Division 536, Technical Activities (cont'd.)

Radon (R. Col 16 & J. M. R. Hutchinson)

The continuing concern about exposure of the public to radon and

radon progeny throughout the United States has resulted in increased

interest in the quality of radon measurements. In response to this

concern, the Office has continued its activities toward developing new transfer standards and to maintaining liaison interactions with other

radon measurement laboratories.

For the development of new transfer standards, the Office continues

to collaborate and conduct laboratory studies with staff members of the

Radioactivity Group. These collaborative projects included the continuing

work on developing a radon flux density standard; the design of an upgraded and expanded primary measurement system which will serve as the

replacement for the national standard for radon measurements; and

preliminary studies for an independent verification of the primary

measurement system calibration.

The Office provides oversight for the overall project to develop a flux density standard. This project was initially funded in part by an interagency agreement with the Environmental Protection Agency. The 40-cm

diameter prototype is now fully operational. Following completion of the

gas-phase studies described in last year's report, the source was loaded

with a radium solution in June. This was preceded by a determination of a complete set of diffusion model parameters for the prototype; modifications for new polyethylene-stainless steel seals in the prototype; fabrication and testing of a new small-volume accumulation chamber which seals

to the top of the prototype; and development of loading procedures and a final calibration protocol for the prototype. The first preliminary

calibration for the constrained flux density was recently completed. Many

additional calibrations and performance evaluations will have to be

performed, of course, before the efficacy of the standard is demonstrated.

Each test on the standard requires nearly a month-long measurement period

because of the long time required to reestablish a steady-state after a change in the boundary conditions of the source. In addition, further

work on verifying the diffusion model for the prototype will have to be

performed. This verification is necessary since a mathematical model must

be used to relate the constrained to unconstrained flux density.

The NBS primary radon measurement system consists of four pulse ionization chambers and ancillary gas-handling and -purification equipment,

and serves as the national standard for radon measurements. This system

is not only the underpin to the entire NBS radon program, but is also

169
Division 536, Technical Activities (cont'd.)

essential for maintaining the quality of radon measurements made throughout the U.S. The existing system has been maintained, for over 40 years,

to accurately measure radon against both national and international radium

standards. Unfortunately this ancient system is rapidly becoming inoperable. Parts of the instrumentation are original (dating back to the early

1940' s) and are now obsolete. Only two of the extant chambers are operable, and both of these have leaks that are increasing in seriousness.

The gas-handling manifold has over the years undergone many repairs and

modifications, and at present is merely patched together. The chamber

backgrounds are nearly intolerable because of the 40-year accumulation of

deposited 210 Pb (a radioactive progeny in the 222 Rn decay chain), and as a result, it is now impossible to perform measurements at typical concentration levels. Because of the importance of this national standard and its

existing state, the Office initiated, in collaboration with the

Radioactivity Group, plans for its replacement.

The design of an upgraded, modernized and expanded system has been

completed, and funding is being sought. This work would include refurbishing the four existing chambers, fabrication of four new chambers and

two ZnS(Ag) scintillation cells, and construction of a new dual manifold

for gas purification and transfers.

Some preliminary studies to perform an independent verification of

the primary measurement system calibration by gamma-ray spectrometry have

recently been undertaken. This independent verification is being performed because of a major calibration discrepancy among several leading radon

laboratories including NBS. In the past year, the Environmental

Protection Agency established a voluntary Measurement Proficiency

Evaluation and Quality Assurance Program for commercial radon measurement

vendors. This program which is being administered by EPA relies upon the

calibration services of several national laboratories which should be

related to the national standard maintained by NBS. Unfortunately, a recent intercomparison of radon measurements by these laboratories has

revealed a serious discrepancy in calibrations. EPA has also tentatively

accepted the calibrations of one of these discrepant laboratories for its

radon MQA program. This situation can have highly visible implications.

For example, as part of the MQA program, EPA is generating a list of

"acceptable" radon measurement laboratories that perform assays for homeowners and other private individuals likely to be affected by the presence

of environmental radon. These laboratories will not be on the "accepted"

list if their calibrations differ from the presently accepted calibration

-- even if they agree with NBS! Given the public sensitivity to the problem of radon, it is crucial to have a generally accepted calibration. It was felt that a demonstration and verification of the pulse ionization

chamber calibrations by an independent measurement method would help

resolve the existing problem. Studies demonstrating the feasibility of

performing these independent measurements by gamma-ray spectrometry have

170
Division 536, Technical Activities (cont'd.)

been completed. Funding, both internal and external to NBS, is presently

being sought to complete this work which would resolve the extant calibration di screpancies.

In addition to these laboratory studies, the Office continues to

coordinate the interactions and measurement intercomparison activities

between NBS and other radon measurement 1 aboratories, such as the DoE

Environmental Measurements Laboratory, the DoE Technical Measurements

Center (operated by Bendix in Grand Junction, Colorado), two EPA laboratories at Montgomery and Las Vegas, the U.S. Bureau of Mines Denver

Research Center, and national laboratories including Lawrence Berkeley

Laboratory, Argonne National Laboratory, Oak Ridge National Laboratory,

and Mound Laboratory.

The Office also continues to advise and collaborate with personnel in

state radiation control programs and in other laboratories on radon

measurement and calibration procedures. In the past year, this included

advising EPA in drafting interim radon measurement protocols, and serving

on an informal advisory task force that assisted in establishing EPA's

radon MQA program.

Personnel Dosimetry (E. H. Eisenhower)

The national quality assurance program for personnel dosimetry, which

is administered by the NBS National Voluntary Laboratory Accreditation

Program (NVLAP), has now completed three years of routine operation. At

this time, 42 dosimetry processors have been accredited and several more

have submitted applications. The Nuclear Regulatory Commission continues

its preparation of a final rule that would requi re its licensees to use only accredited processors. Several states have al ready included such a requi rement in their rules, and more of them intend to do the same.

Technical support and guidance for this program continue to be

provided by the Office and the Dosimetry Group. In January 1986 the

proficiency testing laboratory became Battelle Pacific Northwest

Laboratories (PNL), which replaced the University of Michigan whose

contract expired in February. This required the Office to coordinate and

conduct an on-site evaluation of the PNL facility and its procedures, and

to prepare an extensive report of that evaluation. The Office continues

to provide the chairman of an interagency committee that guides and

coordinates this national program. An NBS internal report that summarizes

the program and the first two years of testing was prepared during the

past year.

171
Division 536, Technical Activities (cont'd.)

Committee Activities (R. Coils, E. H. Eisenhower, & H. T. Heaton)

The Office serves on two major interagency committees concerned with

environmental radon exposure. The first is the Radon Workgroup of the

Interagency Committee on Indoor Air Quality (ICIAQ). This group recently

updated its report on the status of current federal activities and priorities for radon research in the U.S. It also drafted a report on the

development of a national indoor radon assessment plan and the appropriate

Federal role in conducting this large-scale project. The second committee

is the Science Subpanel on Radon Protection and Health Effects of the

Committee on Interagency Radiation Research and Policy Coordination

(CIRRPC). The Radon Subpanel was one of the first five working groups

formed by the CIRRPC Science Panel. A report by this subpanel was completed this year, and was accepted by CIRRPC. The report highlights

five major radon issues in the U.S. and presents recommendations for

addressing these issues. As part of this effort, the Office participated

in briefing the Acting Science Advisor to the President, the Staff of the

White House Office of Science and Technology Policy, and the full CIRRPC

membership.

The Office is represented on another CIRRPC Science Subpanel, on the

Scientific Basis of Radiation Protection Standards. This group is in the

process of reviewing ICRP Report 26, which is a basic report on international recommendations for radiation protection. Four issues have been

identified by the group, the first of which is the recommendation that the

quality factor for neutrons be increased by a factor of two. The subpanel

is planning a workshop on this issue and will prepare its report shortly

thereafter.

As an outgrowth of a workshop held at NBS in July 1984, the Office

has organized the Joint Planning Committee for Radiation Survey

Instruments and Calibration. The purpose of this committee is to plan and

guide implementation of a national instrument testing program and the

establishment of a system of secondary standards laboratories in the private sector. Membership is balanced among agencies and organizations in

the private, state, and federal sectors to achieve a broad perspective.

Two subcommittees have been created to address the major areas of concern:

instrument testing and secondary laboratories.

Participation in American National Standards Committee N43, Equipment

for Non-Medical Radiation Applications, has continued as chairman of the

main committee and as members of writing groups. The committee received

its accreditation from ANSI, and a vice-chairman was elected. The subcommittee on irradiators completed draft standard Safe Design and Use of

Panoramic, Dry Source Storage Gamma Irradiators (Category II). It wi

I

1 be

submitted to the N43 committee for ballot in the near future.

172
Division 536, Technical Activities (cont'd.)

A new ASTM writing group chaired by the Office was formed to prepare

a standard practice for performance of calibration laboratories for radiation dosimetry in industrial testing and processing. This standard practice will contain the performance criteria to be met by laboratories that

provide calibration services for the measurement of high-level doses in

radiation processing and electronic device hardness testing. It is hoped

that these criteria will be used as the basis of a laboratory accreditation program in this area. A second draft of the standard practice has

been prepared.

I. Radiation Theory Group

Neutron Transport and Dosimetry (C. M. Eisenhauer)

Calculations and measurements in the exposure rooms adjoining the

TRIGA reactor at the Armed Forces Radiobiology Research Institute (AFRRI)

have continued. Kerma rates inferred from measurements with neutron

activation detectors and tissue equivalent ionization chambers agree to

about 15%.

The MCNP Monte Carlo code obtained from Los Alamos National

Laboratory has been made fully operational on the CYBER 855 computer.

Monte Carlo calculations have been made for widely-varying problems such as absorbed gamma-ray dose in small quartz parallelepipeds, neutron

sources, transport of neutrons in a D

2 0 sphere, and air scatter effects on calibration of neutron sources. The code is not yet operational on the

CYBER 205 computer.

A manuscript has been written on the subject of air-scatter corrections for calibration of four standard neutron sources defined by ISO. It will be submitted for publication in Radiation Protection Dosimetry, an international journal.

A report has been prepared, describing computer codes for calculating

reduction factors in buildings for initial gamma ray and neutrons from

nuclear weapons.

Ratio of Positron to Electron Bremsst rahl ung (S. M. Seltzer & M. J. Berger)

The calculations of bremsstrahl ung cross sections have been extended

to positrons. The first systematic study has been made of differences

between the radiative energy loss of positrons and electrons. It has been

found that the positron/electron energy-loss ratio obeys a simple scaling

law, being expressible rather accurately as a function only of the

quantity T/Z, where T is the incident-particle kinetic energy and Z is the

atomic number of the scatterer. This scaling law makes it possible to

obtain the energy loss for positrons without further detailed calculation,

using extensive existing electron bremsstrahl ung data.

173
Division 536, Technical Activities (cont'd.)

Photon Cross Section Calculation on PC (M. J. Berger)

A database and a computer program have been developed with which one

can calculate, on a personal computer, accurate x-ray and gamma-ray cross sections for coherent and incoherent scattering, photoabsorption and pair

production, in the energy region from 1 keV to 100 GeV. The program can be

used to obtain these cross sections for a standard energy grid, or for any

desired list of energies, for all elemental substances and for mixtures or compounds of any desired composition. It is a special feature of the program that in the case of compounds and mixtures the output automatically

includes cross sections at and immediately below all the energies corres- ponding to absorption edges for all the atomic constituents. The program,

developed in FORTRAN 77 on an IBM XT, has also been found to work on many

other compatible XT and AT machines. The hardware requirements are modest;

a 256K memory and a 8087 mathematical coprocessor are sufficient. The

required input base (in compressed binary form) is stored on one floppy 5 1/4" disk. The running time for a typical cross section table (approx. 100

energies) is only a small fraction of a minute.

Microdosimetric Event-size Distributions in Water (M. J. Berger)

Microdosimetric calculations have been performed to provide the

physics input for the study of the effects of ionizing radiation on living

matter. Using accurate, new cross sections for proton-impact ionization,

calculations have been made of the statistical fluctuations of energy

depositions (event sizes) in small targets in a water medium. These calculations were made for spherical targets with various diameters up to 1 micron, for incident protons with energies between 0.5 and 20 MeV.

Similar results were also obtained for incident proton spectra that result

from irradiations with 14-MeV or 20-MeV neutrons. Previous calculations in

the literature have been carried out mainly in the conti nuous- si owi ngdown approximation, that is, disregarding the energy-loss straggling of

protons. In the present work the straggling was taken into account by the

Monte Carlo method. Furthermore, the calculations included the modification of the event-size spectra due to the transport of energy into and out

of the target region by secondary electrons (delta rays).

Space-Shielding Calculations (S. M. Seltzer, M. J. Berger, & G. Barnea)

Radiation transport calculations, based on Monte Carlo methods, have

been made to study the shielding of spacecraft against electrons and, in

particular, secondary bremsstrahl ung originating in the shield. This work was undertaken in response to NASA concerns over the radiation hazards to

on-board personnel and/or critical electronic components during the longer

space missions planned for shuttle and space-station projects. Using a Monte Carlo code that treats three-dimensional structures, quantitative

results have been obtained for radiation environments expected in typical

174
Division 536, Technical Activities (cont'd.)

shuttle and geosynchronous orbits. These results indicate that the radiation dose can be reduced three-fold by replacing an aluminum shield by a composite shield of the same total mass that incorporates an inner lining

of lead.

Geometrical Transformation for Electron/Photon Transport Calculations

(S. M. Seltzer)

An approximate procedure has been developed to transform depth-dose

distributions in simple slab targets so as to obtain the spatial distribution of dose in spherical target configurations for space-shielding calculations. Emphasis is placed on the determination of electron and

bremsstrahl ung dose, which would otherwise require more costly threedimensional Monte Carlo calculations. For the el ectron-bremsstrahl ung

problems tested, results from the procedure require only a fraction of the

computer time and are found to agree to within 10-20 percent as compared

to direct, three-dimensional Monte Carlo calculations.

Critical Analysis of X-Ray Attenuation Coefficients 0.1 to 100 keV

(E. B. Saloman, J. H. Hubbell, & M. J. Berger)

X-ray attenuation coefficients extending into the soft x-ray region,

down to 0.1 keV, are increasingly required for the analysis of material

properties by techniques such as XRF (x-ray fluorescence), PIXE (proton or particle induced x-ray emission), and electron microprobe analysis.

Measured x-ray attenuation coefficient data from the published literature

and from other sources are collected on a continuing basis by the NBS

Photon and Charged Particle Data Center. These approximately 20,000 data

points, covering the photon energy range 10 eV to above 10 GeV, have

recently been computerized, and also documented in an indexed bibliography

of about 500 source references. A comparison has been carried out, in

both graphical and tabular form, over the energy range 0.1 to 100 keV

between the above experimental data base and two other photoionization

cross section data sets. One of these is a recommended semi-empirical set

(0.03 to 10 keV) by Henke et al . , and the other is the theoretical set

(1 to 1500 keV) calculated by Scofield using a Hartree-Sl ater atomic

model, and extended by Scofield at our request down to 0.1 keV. There has

been some disagreement over whether Scofield's results should be subject

to Hartree-Sl ater-to-Hartree-Fock renormalization. The present comparisons suggest that the renormalization does not improve agreement with

measurements, at least in the majority of cases. The comparisons identify

materials and energy regions where measurements are poor or non-existent,

also where present theoretical models are inadequate, such as near absorption edges.

175
Division 536, Technical Activities (cont'd.)

Critique of X-Ray Attenuation Coefficient Measurement Techniques. The

International Union of Crystallography X-Ray Attention Project

( J. Hubbel 1

)

Cry stal 1 ographic analysis in either routine industrial o

r in research

applications requires reliable photon cross section data for quantitative

interpretation of diffracted x-ray intensities. For a number of technically important materials such as silicon and copper, photon cross section

evaluations by the NBS Photon and Charged Particle Data Center have disclosed discrepancies between measurements well in excess of claimed uncer- tainties, and between available measured and theoretical x-ray attenuation

coefficients. As proposed by the Data Center, the Commission on Crystallographic Apparatus of the International Union of Cry stall ography

inaugurated an X-Ray Attenuation Project, for which the Data Center serves

as Secretariat, aimed at resolving the serious discrepancies in the data

in the literature. The Project Chairman D. C. Creagh (Australia) has

fabricated well -characterized absorber samples of silicon, copper, carbon

and germanium and distributed them to 23 cooperating laboratories in 11

countries for measurements of x-ray attenuation coefficients using different techniques. Several of these new measurements have now appeared in

the published literature. The first Project report, co-authored with

Project Chairman Creagh and now accepted for publication in Acta

Crystal 1 ographica A, presents and compares results for single-crystal

silicon measurements by 12 laboratories using eight different experimental

configurations. Of these configurations, in the region 4 to 50 keV the

preferred arrangement appears to be a stable x-ray tube source, followed

by a collimator, the absorber sample, a diffraction crystal monochromator,

another collimator, and an Si (Li ) detector with associated multi-channel

analyzer. Comparison also of these measurements with available theoretical cross sections suggests that for such a highly-ordered substance

as single-crystal silicon, in the regions 25 to 50 keV discrepancies of 5 to 8 percent can be removed by replacing the Rayleigh (coherent) scattering cross section with thermal diffuse scattering in compositing the

theoretical x-ray attenuation coefficient.

Charged-Parti cle Spectra and Kerma Factors (J. J. Coyne, H. M.

Gerstenberg, R. S. Caswell, & E. J. Axton)

Methods have been developed for the systematic tabulation of the

energy spectra of charged particles released in neutron interactions with

tissue or tissue-equivalent solids and gases. The spectra treated include

both the initial spectra resulting from the nuclear interactions and the

energy-degradation spectra resulting from the inelastic Coulomb scattering

of the released charged particles as they slow down to rest. The computational apparatus has been prepared for an extensive compilation which will oe useful for biophysicists engaged in the modeling of radiation effects.

Kerma factors (which are in effect energy-weighted integrals over the

initial spectra) have been calculated for H,C,N and 0 in neutron energy

176
Division 536, Technical Activities (cont'd.)

bins 200 keV wide, covering the region from 0 to 20 MeV, and also for 76

logarithmic bins extending from thermal energies to 2 MeV. The information generated includes the contribution to the kerma factors from different particles and from different reactions. A study of cross sections and

kerma factors in carbon, particularly above 5 MeV, is being carried out

using a least-squares analysis method including correlations.

Microdosimetry for Neutrons (J. J. Coyne; H. M. Gerstenberg; R. S.

Caswell; & W. Wilson, Pacific Northwest Laboratory)

The analytical transport theory developed at NBS uses the continuoussi owing-down approximation to calculate energy deposition in small sites

by secondary charged particles released in neutron interactions with tissue. Efforts are now underway to refine the method by including the

effects of energy-loss straggling of protons, and the effects of energy

transport by secondary electrons released in proton-impact ionization

events. Two approaches are being used: (a) the incorporation of straggling information into the analytical method; and (b) independent Monte

Carlo calculations. Measurements and calculations for cavity sizes much

smaller than 1 micron show that the effects of transport of secondary

electrons outside the cavity become much more important. A joint project

with Pacific Northwest Laboratory to do microdosimetry calculations using

proton particle track structure results is underway.

II. Radiation Chemistry and Chemical Dosimetry Group

The program of the group deals with kinetic and mechanistic investigations of radiation effects in chemical and biological systems, from the

early physical interaction of radiation and matter to final biological end

points, and the dosimetry of radiation effects at various steps. Visiting

personnel are indicated with an asterisk.

A. Radiation Chemistry (M. G. Simic, W. L. McLaughlin, E. P. Hunter,

L. R. Karam, M. M. Dizdaroglu, D. S. Bergtold*, M. AlSheikhly*, & M. F. Desrosiers*)

The associated chemical and biological processes are studied from a kinetic and mechanistic point of view at a molecular level. That approach

requires investigation of transient free-radical species by fast kinetic

techniques (pulse radiolysis), product measurement by a variety of analytical techniques (GC/MS, HPLC, spectroscopy, etc.), and characteri zati on of bio-effects by suitable bio-chemical techniques (centrifugation, electrophoresis, chromatography, etc.). The investigations are conducted in

both simple and complex model systems, as well as in cells. Cells are

used because no model systems can mimic the mi croenvi ronment of DNA in

living systems.

177
Division 536, Technical Activities (cont'd.)

The major emphasis of the research is on damage and repair of DNA.

Since DNA is associated with proteins (histones) and is attached to mem- branes, some aspects of radiation chemistry of amino and fatty acids also

are being investigated.

DNA (M. Dizdaroglu, L. Karam, D. Bergtold*, S. Jovanovic*, & M. Simic)

The research has been focused predominately on the mechanisms of DNA

base damage, crosslinking of DNA with proteins, and the measurement of the

resulting products. Crosslinking appears to be one of the major effects

in cells. The mechanisms and consequences of crosslinking, however, are

not yet understood because of measurement problems. The measurement of

products of DNA damage (e.g. thymine glycol, 8-hyd roxy -guanine , etc.) is

utilized for the development of post- irradiation biochemical and biological dosimetry. Irradiation parameters (dose, dose rate, temperature,

state, C> 2

, etc.) are of critical importance since the effects of radiation

can be qualitatively and quantitatively altered by them. The effects of

quality of radiation (LET) are not investigated at present. However, the

study of the effects of low energy protons and a-particles, as well as high energy high Z nuclei (BEVALAC), are in a planning stage.

Relevance and Impact . This research is expected to have an impact

in radiation biology, radiation therapy of cancer, cancer etiology, risk

assessment, and radiation protection. Specifically, it is relevant to:

assessment of damage by low-LET radiations (y- and x-rays, electrons) vs. a-particles (e.g. radon), and development of standards for individual

biological sensitivity to radiation. Unique facilities and expertise at

NBS provides new approaches in the study of the biological effects of

radiation.

Proteins and Subcomponents (L. Karam, M. Desrosiers*, M. Dizdaroglu, & M. Simic)

The research has been focused predominantly on the hydroxylation of

aromatic amino acids and dimer formation induced by radiation. The

measurement methodologies for hydroxylated products (e.g. o-Tyr) and

dimers have to be developed for ppb quantities in the presence of large

numbers of other products and amino acids.

Relevance and Impact. This research is relevant to safety assess- ment of irradiated foods and the development of post irradiation

dosimetry.

178
Division 536, Technical Activities (cont'd.)

Lipids (M. AlSheikhly* & M. Simic)

Mechanisms of radiation induced autoxidation of lipids are being

studied by pulse radiolysis and oxygen uptake (utilizing oxygen electrode)

in aqueous solutions. Since irradiation of aqueous solutions provides a definable number of initial reactive species, it is possible to measure

accurately the length of chain reactions. Pulse radiolysis measurements

provide kinetic and spectroscopic parameters of the relevant lipid

transients.

Relevance and Impact . Autoxidation of lipids is relevant in meat

irradiation processing and the storage of foods. Pulse radiolysis mea- surements in meats provide important kinetic information lacking so far.

Antioxidants (E. P. Hunter, S. Jovanovic*, M. AlSheikhly*,

M. Desrosiers* & M. Simic)

The kinetic and mechanistic features of natural and man-made antioxidants are not fully understood. Pulse radiolysis measurements provide

important features (kinetic parameters, redox potentials) for the selection of the most suitable antioxidants for a particular system. The

experiments conducted are geared toward acquisition of such predictability. The emphasis is on phenolic and heterocyclic antioxidants and tneir

reaction with DNA, protein and lipid radicals.

Relevance and Impact Antioxidants act as radi oprotectors and anticarci nogens and in both cases the mechanism of action is not understood.

The impact of this work is in food preservation, protection from radiation

and chemical carcinogens, and human physiology. NBS is the only institution in the U. S. dealing with the kinetic aspects of antioxidants.

Chemical Dosimetry (W. L. McLaughlin, M. G. Simic, B. Radak*, M.

AlSheikhly*, L. Karam, M. Desrosiers*, M. Farahani*, W. Warasawas*, M.

Khan* & M. Hussmann*)

.

The NBS mission to develop and apply the most appropriate radiation

measurement systems to the nation's needs requires that novel chemical

systems be explored and tested in practice for that purpose. Chemical

reactions are appropriate for both steady-state and real-time dosimetry.

A carefully selected group of chemical systems is being investigated

systematically in terms of kinetic and mechanistic properties in order to

design novel and successful dosimeters relevant for many radiation measurement requirements in fields of current interest, e.g. clinical and

diagnostic medicine, agriculture, electronics, materials, environmental

179
Division 536, Technical Activities (cont'd.)

technology, space and defense, and radiation protection. Efforts are also

being made to develop accurate and precise chemical dosimeters as marketable SRM's for particular nationwide applications.

Underway is a program of applied research on chemical dosimeters for

(a) wide dose-range applications (10-2 to 108 Gy); (b) mixed radiation

fields (low and high-LET fields, e.g. gamma-rays plus neutrons, and

charged particles); (c) reference-standard transfer systems (calibrations).

Steady State Dosimetry (W. L. McLaughlin, M. Farahani*, W. Warasawas*, & M. Hussmann*)

A group of chemical systems has been singled out for practical use over wide dose ranges of interest in radiation applications. Those being

developed and applied include several inorganics (dichromate solutions,

alkali halides, and glasses) and organics (plastics, dyed plastics, aromatics; polycyclic systems; radiochromic solutions; optical waveguide

systems). It is also important to find solid answers to problems in the

accurate measurement at both high and low doses of mixed field radiations

in environmental and personnel protection, medicine and research (e.g.

accelerator beams); as well as a wide variety of industrial and agricultural applications.

Real-Time Dosimetry (W. L. McLaughlin, B. Radak*, W. Warasawas*, & M.

Khan*)

Convenient active dosimeters are lacking for many applications, in

particular, for in-vivo measurements during radiation diagnostics or therapy and for remote telemetering applications in industrial processing.

Optical waveguide dosimeters should be developed for medical applications,

in order to help solve the sparing of healthy tissue and more effective

clinical use of radiation. Solid-state dosimeters are being developed as telemetering systems to control and improve the quality of industrial

radiation processing. These include the development of certain semiconductors and calorimeters tied to radiation resistant transmi tters. Such

systems may also prove valuable for high-resolution radiation imaging as

real time devices. They may also have practical use in space and defense

appl ications.

Chemical Dosimetry Mechanisms (W. L. McLaughlin, M. G. Simic,

M. AlSheikhly & M. Khan*)

In many instances, the mechanisms of potential and/or proposed chemical dosimeters are not understood. The mechanisms are most conveniently

studied by pulse radiolysis, which also provides information about the

kinetics and activation energies. For example, complete kinetics and

mechanistic description of a widely-used dosimeter in irradiation

180
Division 536, Technical Activities (cont'd.)

technology, based on the rad i at ion- induced conversion of radiochromic dyes

from the leuco form (no color) to the developed dye (bright, strong

color), is not presently available. In particular, the effect of irradiation parameters (concentration, dose, dose-rate, atmosphere, dielectric

constant of the solution, temperature, etc.) is of critical importance for

the development and ultimate acceptance of a dosimeter as a standard.

These studies would assist in the development of new and specific

chemical dosimeters for application in industry, defense, space program,

medicine, and radiation protection.

Post Irradiation Dosimetry (PIP). (L. Karam, M. Desrosiers*, M. Simic)

There are numerous instances when the knowledge of the delivered

radiation dose is required either immediately or long after the exposure.

For example, proof that suspected foods have or have not been irradiated

is required by food processors and wholesalers for purposes of regulation

of import/exports. Reliable measurements which can indicate that irradiated foods have not received radiation dose in excess of the legal limits

are needed by regulatory agencies. The discovery of o-Tyr in irradiated

chicken meat may be utilized for the development of suitable PID for

meats.

Accidental exposure of personnel to radiation has occurred in some cases without an adequate on-line dosimeter being present, accentuating

the need for the development of novel concepts in real-time dosimetry and

PID for such circumstances.

Measurements of the total energy delivered (J) to a patient in radiation therapy would be useful information to a therapist. The possible

presence of unique radiolytic products, URPs, or specific markers, in the

urine of irradiated patients or personnel in space (e.g. thymine glycol,

5-hydroxymethyl uracil, etc.) is under investigation.

Achi evements

DNA

1. Radiolytic products of DNA base damage can be measured with a newly developed GC/MS methodology at a 10-100 fmol level. The ion select

approach is 10-100 times more sensitive than previously utilized methodologies. (Dizdaroglu, Bergtold)

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Division 536, Technical Activities (cont'd.)

2. Redox potentials of DNA bases, hitherto not known, were determined by pulse radiolysis. These are important in the assessment of

oxidative damage to DNA and intramolecular energy cascade within DNA.

(Jovanovic, Simic)

3. Guanyl and adenyl radicals which are generated on one electron

oxidation of the correspond!' ng DNA bases, in contrast to OH radical

adducts, were found not to react with oxygen. This unexpected phenomenon

has been explained by strong delocalization (resonance) of the unpaired

electron of the radicals. (Jovanovic, AlSheikhly, Simic)

Proteins

Redox properties of tryptophan, one of the essential amino acids,

were determined and the mechanisms of i ntramol ecul ar electron transfer

between Trp and Tyr were described. This is important for the understanding of the direct action of radiation on proteins. (Jovanovic, Hariman,

Simic)

Li pids

Chain autoxidation of linoleic acid has been investigated as a function of concentration and temperature in aqueous solutions by measuring oxygen consumption. A steep increase in chain length observed above

45°C may be an important factor in hyperthermia (cancer therapy) where

cells die also at an increased rate above the same temperature.

(AlSheikhly, Simic)

Antioxidants

1. Redox potential E

7 =0 .36V was measured for 5-OH-Trp. Antioxidants

of this class have been suggested by the author as endogenous physiological antioxidants. They may protect neural receptor sites and act as radioprotectors as well. (Simic, Jovanovic)

2. Neutralization of peroxy radicals by sulfhydryls has been found

to be a redox process. This observation contrasts previous beliefs that

sulfhydryl radioprotectors act as H atom donors. (Simic, Hunter)

Steady State Dosimetry

1. Advances in the development of optical waveguide (OWG) dosimeters

have been made for the following specific applications: (a) in-vivo

medical dosimetry in real time; (b) pulse-radiolysis dosimetry at low

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Division 536, Technical Activities (cont'd.)

doses per pulse; (c) food irradiation dosimetry; (d) emergency dosimetry.

This work is supported in part by the Federal Emergency Management Agency.

(McLaughlin, Radak, Warasawas)

2. Work is continuing in the development of important SRM chemical

dosimetry systems for high-dose applications in industrial radiation

processing. These will greatly assist industrial radiation users to

achieve measurement quality assurance, for example, in the radiation

sterilization of medical devices and the radiation treatment of foods.

(McLaughl in)

3. Novel chemical dosimeters have been developed at NBS for practical applications over wide dose ranges (10 -3 to 108 Gy). These include:

(a) sublimation systems (e.g. camphor, thymol, borneol); (b) polyethylene;

(c) bromophenol blue; (d ) dyed and undyed polyhal ostyrenes. International

dosimetry intercomparisons of some of these systems, along with calorimetery and conventional radiochromic dosimeters, are being conducted to

determine their best utilization. (McLaughlin, AlSheikhly, Warasawas,

Hussmann)

Chemical Dosimetry Mechanisms

1. The mechanisms of radiolytic dye formation, which constitutes the

largest commercial utilization of chemical dosimetry, are being successfully explored for the first time. Pulse radiolysis is providing data

which may explain how these systems respond in terms of dye yield, without

undergoing rate dependence of response. (AlSheikhly, McLaughlin,

Farahani

)

PID

The discovery that o-Tyr, a suggested marker for irradiation

treatment of meat, is present in unirradiated chicken breast made its use

in PID questionable. o-Tyr, however, was not found in the unirradiated

meat fiber, indicating its presence only in the sarcoplasm of meat. On

irradiation, o-Tyr was found in the meat fiber, providing a base for the

development of a first PID for meats. (Karam, Simic)

III. Neutron Measurements and Research

This group is concerned with measurements of neutron interactions

which depend strongly on the neutrons' energy. The interactions require

neutron spectroscopic capability from 0.005 eV to 50 MeV —over ten decades

of energy. The largest program is devoted to a continuing international

183
Division 536, Technical Activities (cont'd.)

effort to push the accuracy of reference neutron cross sections into the

±1 percent (1 SD) range. Although the group has made significant contributions to this effort, much work remains in selected neutron energy

regions to achieve this important goal. This activity, which is jointly

supported by the U.S. Department of Energy, includes both an extensive

experimental effort as well as coordination of the evaluation of the

neutron cross section standards for the United States. These standards

form the basis for nearly all neutron nuclear data since these data are measured relative to the standards. Hence they supply large leverage

since an improvement in the accuracy of the standards will improve the

accuracy of the entire data base without an extensive remeasurement

effort. Other programs are concerned with the development and exploration

of analytical techniques based on the unique features of the neutron's

interaction with matter. Both the standards and analytical studies

require a significant component of fundamental neutron research. The

group possesses the unique combination of highly trained technical staff

and research facilities to continue to produce significant leadership in

these areas. The MBS facilities used are the 100-MeV linac dedicated

pulsed neutron source, 3-MV positive ion electrostatic accelerator, 100

keV neutron generator, and nuclear research reactor. In response to

requests from other programs within NBS, a 6-MeV y-ray radiation facility

and a Rutherford Backscattering Analyzer for surface studies have been

implemented at the positive-ion accelerator. A technical description of

the group's activities and significance of its success in completing

projects follows.

235 U(n,f) Cross Section from 0.02 to 1000 Electron Volts (R. A. Schrack)

The Neutron Measurements and Research Group has undertaken a measurement of the shape of the neutron induced fission cross section from .02 to

1000 eV where there have been large discrepancies (on the order of 7 percent) in the reported values of these integrals. This measurement is

being undertaken to help resolve the current discrepancies in this

important cross section standard.

Measurements made here with the urani urn-boron fission chamber in late

1985 indicated that the configuration of the chamber caused the energy

resolution of the uranium fission chamber to be much poorer than that of

the boron chamber. This difference in resolution caused errors in the

uranium cross section calculation. The chamber was redesigned to eliminate geometrical sources of resolution broadening. There are now two

separate uranium fission chambers together with the boron chamber in the same housing. All chambers now have separate electrical connections to

implement this important development. Measurements made with the new chamber confirm its improved resolution and flight-path compensation.

184
Division 536, Technical Activities (cont'd.)

To verify the understanding of the chamber operation, a computer

program was developed to synthesize the resolution of the system, taking

into account the time distribution of the neutron generation as well as the spatial distribution of the uranium and boron foils. Using this

synthesizer code together with a data analyzer code, the proposed experimental measurements of the uranium integral cross sections were simulated.

These simulations enabled one to determine the errors induced by various

parameter changes. The results of these studies were used to select the

parameters for the experiments.

Detailed studies and preliminary diagnostic measurements indicate

that all major sources of background and electronic drifts have been

understood. The urani urn-boron fission chamber is now at a point of development to begin long runs at the dedi cated-pul sed neutron source to

acquire the data leading to a more precise measurement of the 235 U fission

cross section.

Acquisition of a Microcomputer System (R. A. Schrack)

The Neutron Measurements and Research Group has acquired an AT&T

PC6300 microcomputer to provide additional computational and editorial

facilities for the members of the group. A survey of the available types

of "IBM-compatible" personal computers was made in collaboration with

other computer users at the Bureau. In addition to determinations of

reliability and operational convenience, an extensive comparison was made

of computational speed and accuracy. A variety of program types were run to test the relative speed of simple operations, access time, etc. The

relative merits of the different computers tested varied slightly from one test to another. A widely used test that reflects the different test

results is the Sieve of Eratosthenes (an algorithm for finding prime

numbers). The table below shows the results obtained for this test.

Speed of Computers Relative to the IBM PC/AT

IBM IBM AT & T

PC/AT PC/XT Deskpro 6300

microprocessor (80286) (8088) (8086) (8086)

without coprocessor 1.00 2.54 1.17 1.12

with coprocessor 1.00 1.18 0.63 0.58

It should be noted that the speed of the PC/AT with the coprocessor

is 16 times greater than the speed without the coprocessor. From the

tabulated results one can see that when used with a coprocessor the two

8086 computers had greater speed than the 80286 computer. This is a surprising result and is caused by the relatively inefficient coprocessor

available for the 80286. In addition to the speed advantage there is a

185
Division 536, Technical Activities (cont'd.)

price advantage; for the 8086 computers, that is considerable. In addition, the AT & T computer has twice the screen resolution of any of the

other machines. The group has purchased the AT & T computer and found it

to be compatible with all commercial software.

Multi-Particle Accelerator for Neutron and High-LET Radiation Research

(R. G. Johnson)

In June 1986 the IAEA sponsored an advisory group meeting in

Leningrad, USSR on neutron source properties. The final report on the

preliminary design study of a linear induction accelerator for neutron and

high-LET radiation research was presented at this meeting.

This preliminary design study was carried out as part of the analysis

of neutron and high-LET radiation research program at NBS conducted by the

Center for Radiation Research staff. Subsequent to that program analysis,

the accelerator design study has been updated to include the most recent

technological advances for induction linacs.

The developments in this technology both before and after our initial

study have significantly improved the practicality of induction linacs for

moderate-energy high-current accelerator applications. Of primary significance is the development of magnetic pulse compression techniques and

the related development of iron-based metallic glasses.

The target parameters of the preliminary design were chosen with many

considerations in mind and represent in most cases only modest requests of

the technology. The accelerator was designed to accelerate up to 250 A of

electrons to 100 MeV with a pulse structure of 100-ns maximum length at

repetition rates up to 1000 Hz. Because of the versatility of induction

linacs, protons and other light ions can also be accelerated with currents

limited only by space charge effects. The design includes provision for

accelerating protons and deuterons at maximum currents of 2.5 A and 1.2 A,

respecti vely

.

This accelerator would be a powerful and versatile tool for neutron

and high-LET radiation research. Both continuous and quasi -monochromatic

beams of neutrons would be available and the light ions could be used

directly.

Data Acquisition Computers (R. G. Johnson)

FY-86 was the first year of operation without a maintenance contract

on the three Harris /5 data acquisition computers. Although we have been

able to keep all three computers running, implementation of replacement

systems is becoming critical. The computer system chosen for the replacement is a Charles River Data Systems UV2403FT computer. This computer is

based on the Motorola MC68000 mi coprocessor and the VME bus. Following

186
Division 536, Technical Activities (cont'd.)

the initial purchase of one of these systems (delivered in October 1985),

the purchase of two additional boards have completed the basic hardware.

The first of these boards provides the interface between CAMAC and the VME

bus. The second board contains 4 Mbytes of error correcting memory which

will allow two-parameter data to be stored in memory.

The CRDS computer has been installed in the counting room used for

linac neutron measurements and the software (written in assembly language)

for the CAMAC-VME interface has been entered into the computer. Several

European laboratories, most notably CERN, have adopted very similar hardware for data acquisition. Consequently software for the interface is

public domain. Testing of the software has just been started. After

validation of the interface drivers, the data acquisition software which

will be written in a higher-level language (FORTRAN and/or C) can be

written.

In FY-87 a request for a second computer system, needed for positive

ion accelerator neutron measurements, will be made.

Detectors for Neutron Scattering in the eV Region (R. G. Johnson)

In the last few years a new source of neutrons for condensed matter

studies has been developed at several facilities around the world. These

sources are based on high-current high-energy proton accelerators which

produce neutrons by spallation. The facilities which are now partially or fully operational include: IPNS at Argonne National Laboratory, KENS at

KEK in Japan, WNR-PSR at Los Alamos National Laboratory, and SNS at

Rutherford Appleton Laboratory in the UK.

Since these new sources are accelerator-based, they are by nature

pulsed. Consequently, instruments using neutron time-of-fl i ght are being

developed to take full advantage of this characteristic. Furthermore, to

preserve the time structure, the neutrons are lightly moderated as compared to steady-state reactor sources. Although there i s d i sagreement

on how to compare reactor sources with the new pulsed sources in the

thermal region, it is clear that the new sources provide much higher

fluxes of neutrons in the eV region.

Traditionally neutron scattering measurements have been confined to

energies below a few hundred meV primarily because of the rapidly decreasing flux from fission reactors above these energies. Spallation neutron

sources on the other hand provide a high flux of neutrons well above 1 eV.

It is expected that the opening of this energy range to condensed matter

studies will provide information to many fields. The studies which may be

interesting have been the subject of several reviews and a recent international workshop. However, considerable instrument development is necessary before full advantage of measurements at eV energies can be realized.

The instruments developed for reactor sources are not in most cases suitable for extension to the eV region.

187
Division 536, Technical Activities (cont'd.)

One of the general methods to extend inelastic neutron scattering

measurements to higher energies is to use low energy neutron resonances to

define one energy in the scattering process. The other energy can be

defined by neutron time-of-fl ight . This general method can be implemented

in several ways in direct geometry (monochromatic energy defined before

the scattering) or indirect geometry (monochromatic energy defined after

the scattering). In these studies in our group a particular method in

indirect geometry is investigated. Specifically, since resonances of

interest are primarily capture resonances, a foil of the material which

has the desired resonance is placed next to a detector which detects

prompt capture y rays (or other secondaries). This instrument is called a Resonance Detector Spectrometer (RDS).

Capture resonances in the eV range occur in medium to heavy nuclei.

Prompt y rays following capture have a complicated spectrum with energies

up to the binding energy of the added neutron, typically 6-8 MeV. The

intensity of the y lines falls by an order of magnitude as the energy

increases. Secondary radiation in the form of electrons and x rays are created since many of the low energy y lines have high internal conversion

coefficients. As with most detectors, desirable qualities of detectors

for RDS are high efficiency and good background rejection. Two promising

candidates for such detectors have been tested here: a bismult germanate

(BGO) scintillator and a high-purity germanium (HPGe) detector. The BGO

scintillator is used to detect prompt capture y rays while the HPGe

detector is used to detect low energy y rays and secondary x rays.

To test these detectors simple recoil scattering from an aluminum

sample at 90° was used. Three different resonance foils were included in

the tests: indium ( 1.457 eV), tantalum (4.28 eV), and gold (4.906 eV).

The tests were performed using the Neutron Time-of-Fl i ght Facility (NTOFF)

at the NBS Dedicated Pulsed Neutron Source.

Recently a method which improves the signal to background ratio for

the HPGe detector has been implemented. The method relies on the fact

that in the internal conversion process both an electron and an x ray are emitted. By detecting the electron with high efficiency in coincidence

with the x ray an improvement in the signal to background ratio of 5.5 has

been observed.

The principal conclusion of these studies is that the planar HPGe

detector appears to be the best detector for future developments in RDS

i nstrument s.

188
Division 536, Technical Activities (cont'd.)

International Intercomparison of Neutron Flux Measurement Capability at

500 keV (A. D. Carlson, R. G. Johnson, & 0. A. Wasson)

A final report on the NBS participation in an international intercompariscn of neutron flux measurement capability sponsored by the

Consultative Committee for Ionizing Radiations (CCEMRI) at BIPM was

prepared and sent to AERE Harwell, the organizing laboratory last year.

This intercomparison which uses a large 235 U fission ionization chamber

allowed both linac and 3 MV Positive Ion accelerator neutron facilities to

be used. The detector efficiencies measured at 500 keV at the linac and

facilities at NBS agree well within the 1.7 percent total error for each

measurement. During the past year measurements have been completed at

three additional laboratories to bring the total participation to seven

1 aboratories. It is anticipated that this intercompari son will be

completed during the next year and that the analysis of the results will

lead to an improvement in the 235 U(n,f) standard cross section.

Development of a Radiation Spectrum Unfolding Capability on the NBS

Central Computer' (K. C. Duval 1

)

A general capability to conduct Radiation Spectrum Unfolding analyses

has been established on the NBS Central Computer. The spectrum unfolding

analyses, which requires a substantial allocation of computer memory,

significantly benefits from the increased computing power of the new NBS

high-speed super computer. A fairly extensive collection of computer

codes has been assembled for the spectrum unfolding analyses consisting of

routines to generate Nal, Dual Thin Scintillator (DTS), and Black Detector

response functions, two spectrum unfolding routines including the widely

recognized FERDoR code (developed at Oak Ridge National Laboratory), a least squares fitting routine, a routine to generate simulated detector

data, and several data handling routines. The programs are currently

running in the interactive and batch mode on the Cyber 855 and the Cyber

205 super computer. The spectrum unfolding capability has been utilized

thus far for analysis of gamma-ray and neutron radiation spectra, for both

monoenergetic and continuous sources, using measured and simulated pulse

height data. A typical large problem analyzed was 255 pulse height channels and 90 energy bins. Considerable effort has been devoted to developing the expertise required to properly formulate the unfolding problem in

terms of determining the appropriate energy versus pulse height mesh,

smoothing, gain and zero adjustment of data, and 'a priori' constraints

for each specific problem. Although peculiarities are evident in each

particular problem, the analysis package has been developed with enough

flexibility to handle a large class of radiation spectrum unfolding problems. It is expected that a number of refinements and improvements in the

software package will continue.

189
Division 536, Technical Activities (cont'd.)

The development of a Radiation Spectrum Unfolding capability on the

NBS central computer originated as a result of the need to unfold Nal

pulse height data for characterization of the NBS 6 to 7 MeV photon field

and also because of the recent interest in the DTS detector for neutron

spectrum unfolding. In neutron spectral determinations, spectrum unfolding is applicable when timing information is not available for utilization

of time-of-fl ight methods. Some spectral determinations in which spectrum

unfolding is applicable are in measurements involving passive detectors

such as activation foils, slow response detectors such as moderating

devices, and spectral determinations at small source to detector

distances. The Radiation Spectrum Unfolding analyses is expected to be

increasingly useful as the interest in high energy CW accelerators for

production of high yield gamma-ray and neutron sources grows. The spectra

produced from high energy beams generally contain less structure and a larger contribution from broad energy continua which usually result from

interactions of high energy electrons and break-up reactions. Spectrum

unfolding methods are well suited for analysis of broad slowlyvarying spectra.

Developments in the Character!

- zati on and Utilization of the Dual Thin

Sci nti 1 1 ator (K. C. Duval 1

)

The development of new and improved radiation measurement methods is

essential for achievement of higher accuracy standard cross section data.

The DTS is a unique detector being developed independently here at the NBS

for neutron flux and spectrum measurements in the 1 to 15 MeV energy

region. Currently, most high accuracy neutron flux determinations in this

energy range rely on measurements with proton recoil telescopic (PRT)

devices which suffer from extremely poor sensitivity. The DTS detector

may be utilized to obtain a high accuracy neutron flux determination while

maintaining a good sensitivity to fast neutrons.

Further improvements in the DTS response have been recognized when

the detector is operated in the sum coincidence mode which produces a highly peaked response function. The peaked response function provides an improvement over the conventional rectangular response function normally

obtained with thin organic scintillators by allowing better peak channel

definition and extrapolation to zero pulse height.

The unique detection mechanism employed in producing the DTS sum coincidence response is also of interest. Present detection processes

used to overcome the poor characteristics of the rectangular response

function modify the proton recoil energy distribution by geometrical

constraints (PRT) which suffer from poor sensitivity or by total absorption (Black Detector) which requires larye detector dimensions. The DTS

sum coincidence response utilizes the constraint of the recoil partice

range to restrict the detector geometry without significantly reduciny the

detector sensitivity. Although a Monte Carlo calculation of the DTS

190
Division 536, Technical Activities (cont'd.)

response is available, a detailed analytic evaluation of the sum coincidence response characteristics has been done. The analytic approach has

allowed the detection process in the DTS sum coincidence mode to be better

understood and has been instrumental in identifying areas of further

improvement.

Another important area being investigated for DTS detector utilization is in neutron spectrum unfolding. The peaked response function

obtained with the DTS sum coincidence is expected to provide a significant

improvement over spectrum unfolded results produced with the conventional

rectangular response functions. Although spectrum unfolding methods are considered well established, an extensive search of the literature indicates that neutron spectrum unfolding methods have been applied almost

exclusively to the rectangular response functions of organic scintillators. We have therefore undertaken a program to compare spectrum unfolded

results from DTS rectangular and sum coincidence response functions. The

widely recognized FERDoR unfolding code (developed at Oak Ridge National

Laboratory) is being utilized along with the calculated DTS response functions and simulated pulse height data.

The objective is to verify the dependence of spectrum unfolded results on response function shape, determine the magnitude of the effect, and

further understand the mechanism behind the expected error amplification

associated with the response function shape. Preliminary results have

indicated that differences in unfolded results can be observed for identical problems using different response functions. A result that was rather

unexpected is that the spectrum unfolded results depend not only on the

shape of the response functions, but also on the detector efficiency

curve. The optimum detector for use with spectrum unfolding analyses

would therefore have peaked response functions and a steeply decreasing

efficiency with increasing neutron energy.

Utilization of the NBS Dual Thin Scintillator Neutron Detector for

Activation Cross Section Measurements (K. Zasadny, G. F. Knoll, U. of

Michigan; 0. A. Wasson, R. G. Johnson & K. C. Duvall)

The value of the Dual Thin Scintillator Neutron Detector for precise

neutron fluence measurements in the 1-15 MeV energy region continues to be

recognized by other 1 aboratories. This detector is being used to determine the neutron fluence incident on the samples for new 14 MeV neutron

activation cross section measurements at the 125 beV neutron generator

facility at the University of Michigan. Previous measurements were compared to a commonly used 56 Fe(n,p) reference cross section. These new measurements will combine these techniques and further reduce the systematic errors which will produce more accurate cross sections. These cross

sections are applied in many areas of neutron dosimetry and spectral

measurement

.

191
Division 536, Technical Activities (cont'd.)

Neutron Detector Characterization (K. Kudo, ETL, Japan & A. Carlson)

Measurements have been made of the response of a neutron detector

which should become a standard for the determination of neutron flux

(fluence) in the MeV neutron energy region. The detector provides good

timing and pulse height unfolding capability.

Measurements have been made in the MeV energy region of the neutron

response functions of this 5 cm diameter x 5 cm thick NE-213 detector at

the NBS linac neutron time-of-fl ight facility. The detector has also been

studied experimentally at PTB, Braunschweig, W. Germany and ETL, Ibaraki

,

Japan. These measurements should allow a determination of the consistency

of results obtained under different experimental conditions and comparisons with calculated response functions. The present measurements were obtained in a two-parameter mode (pulse-height and time-of-fl ight) . The

neutron flux determined from the time-of-fl ight data will be compared with

the result obtained from unfolding the pulse height data.

International 235 U Fission Foil Mass Intercompari son (I. Schroder,

D. M. Gilliam, A. D. Carlson, S. W. Bright, & J. M. R. Hutchinson)

In the measurement of neutron fission cross sections, one of the

larger uncertainties is associated with the mass determination of the

fissionable deposit. Inconsistencies in determinations of the fission cross sections may be a result of systematic errors associated with the

measurement of the deposit mass.

As part of a study to check the consistency of mass scales at a number of laboratories throughout the world, two 235 U deposits from the

Khlopin Radium Institute (KRI) in Leningrad, USSR were made available

through the assistance of the IAEA for measurements at NBS and ANL. These

deposits are directly traceable to foils used in very precise measurements

of the 235 U(n,f) cross section made in a collaborative effort by KRI and

the Technical University of Dresden (TUD), GDR.

The study undertaken at the NBS consisted of two parts. One consisted of the measurement of the alpha-decay rates of the two 23 5 U samples

(KRI VI and KRI-XV) with a low geometry counting spectrometry facility.

The other consisted of the measurement of the total alpha disintegration

rate of the samples employing a 2n al pha-counter.

A comparison of the 235 U mass determinations shows that the NBS re- sults by the two separate methods, the low geometry results from ANL, and

the KRI values all agree within their stated uncertainties. In addition,

Poenitz has determined values for the KRI samples based on an intercomparison of measurements of foils from a number of contributing laboratories.

The input data included the masses quoted by the contributing laboratories, masses derived from low geometry alpha counting and relative 2*

192
Division 536, Technical Activities (cont'd.)

alpha and fission ratio measurements. The values he obtained in this

evaluation are 760.2 ± 1.4 for KRI-VI and 893.0 ± 1.8 for KRI-XV. The

outcome of the KRI mass scale determination will have a direct effect on the KRI-TUD fission cross section measurements and their uncertainties.

This effort should contribute to the long- sought objective of 1% accuracies for this cross section.

235 U(n,f) Measurements from 3-25 MeV Neutron Energy (A. D. Carlson,

0. A. Wasson & P. W. Li sowski , LANL)

There is a need for improved measurements of the 235 U(n,f) cross

section in the upper MeV energy region where this cross section standard

is not well known. An experiment is planned at the new white source facility at WNR (Target-4) in LANL. This source will be capable of producing very intense beams of high energy neutrons which are required for

this measurement. The portion of the Target-4 facility construction which

is required for this experiment is expected to be completed late this

summer. The design of the fission experiment has been completed. The

various components of the experiment either exist at the present time or are being worked on. However since this is a new facility the entire

experiment, including the flight path tube, collimators, end station, and

detectors must be set up before experimental tests can be begun. It is

expected that the flight path tube, collimators and end station will be in

place in September. The fission detector is an existing LANL fission

chamber for which new fission deposits are being made at ORNL which are expected in September. The neutron flux detector is an annular proton

telescope which was built at NBS. Work is in progress to improve the

timing of this detector. The work so far has been focused on conditioning

the Si (Li) detector so that it will function at very high voltages so as to reduce the collection time. A protective system for the detector was designed and fabricated.

The first phase of the experiment will involve tests of the detector

systems and measurements of fission cross section ratios at the LANL Van

de Graaff facility in October. Following this testing period the detectors will be set up at the WNR facility for cross section measurements.

The ENDF/B-VI Neutron Cross Section Standards Evaluations (A. D. Carlson,

W. P. Poenitz, ANL; G. M. Hale, LANL; R. W. Peelle, ORNL)

Plans have been made for a new version, the sixth, of the U.S.

Evaluated Nuclear Data File, ENDF/B. The individual evaluations are all

critically dependent on the new evaluations of the neutron cross section

standards. The standard evaluation process for this new version is more

thorough and logically consistent than that used in earlier versions. The

primary effort is focused on a simultaneous evaluation using generalized

least squares, R-matrix evaluations and a procedure for combining the

193
Division 536, Technical Activities (cont'd.)

results of these evaluations. The simultaneous evaluation is important to

this process since ratio measurements in addition to shape and absolute

determinations are treated properly. Correlations within and among experimental data sets are also taken into account. Also the output results

from the thermal constants evaluation by Axton, including the associated

vari ance-covari ance matrix, has been used as input for this evaluation.

The R-matrix evaluations provide a method which allows charged-particle

measurements involving the same compound nuclei ( 7 Li and U B) to be

included in the evaluation process. These evaluations also provide a smooth meaningful expression for the energy dependence of the cross sec- tions. Independent data bases are used in the simultaneous and R-matrix

evaluations. The combining procedure is used to combine the information

obtained from these analyses in a proper way to form the final evaluation

and its vari ance-covari ance matrix. The standards being evaluated are

6 Li(n,t), 10 B(n,a 1 ),

10 B(n,a), 197 Au(n,y), and 235 U(n,f). Evaluations for

the important reactions 238 U(n,y), 238 U(n,f), and 239 Pu(n,f) are also

being performed.

Considerable progress has been made on this process. One complete

"pass" has occurred. The output results from the R-matrix and simultaneous evaluations have been combined successfully. Preliminary investigations indicate that except for the 10 B cross sections, the conditions for

the combination procedure working properly have been satisfied.

Proposals for handling the 10 B cross sections are under investigation. Near final results are expected to be presented at a meeting at

ORNL in September 1986. However, smoothing/fitting of the capture and

fission data, and phase 1 and phase 2 data testing must be completed

before the evaluations will be available for distribution.

Measurements of the 1Q B(n,a) 7 Li to 6 Li(n,t)4 He Cross Section Ratio from

1-100 ke~V (A. D. Carlson H. E. Cooper)

The 10 B(n,a) 7 Li to 6 Li(n,t) 4 He cross sections are neutron cross sec- tion standards up to ~ 100 keV. It has become clear recently that significant improvements are necessary for these cross sections, particularly

for the 10 B(n,a) 7 Li reaction. Significant improvements in the data base

will occur with accurate determinations of the cross section ratio.

Towards this goal measurements are now beginning at the 20 m station of

the NBS neutron TOFF. The experimental set up is similar to that used for

the ratio measurements of these cross sections in the eV energy region.

The 10 B detector is the same one used previously (a 10 B plated ionization

chamber). The 6 Li detector involves the same basic assembly as was used

in the previous investigation except the natural Li glass detector has

been replaced with one enriched in 6 Li. This modification significantly

reduces the percentage of gamma-ray background. Exploratory runs are being made to measure the backgrounds, examine detector recovery at high

neutron energies, check detector resolution, and determine counting

rates.

194
Division 536, Technical Activities (cont'd.)

Advances in the Use of 3 He in a Gas Scintillation Counter (J. W. Behrens,

Ma Hongchang, IAE, Beijing, PRC; & 0. A. Wasson)

For several decades it has been suggested that the 3 He(n,p)T reaction

should be utilized for detecting neutrons over the entire range from thermal energies to MeV energies. In fact, this reaction has been suggested

as a possible standard. The reaction has a Q value of 764 keV and is

easily detected in both a gas proportional counter (gpc) and gas scintillation counter (gsc). The use of 3 He in gpc's is rather common today;

however, its use in gsc's is rare, in spite of the improved timing resolution available from the latter. A possible reason for this is the sensitivity of the uv photons to trace organic impurities in the gas. At the

NBS, we constructed a

3 He/Xe gsc which operated for over two years on its

original high-purity gas fill without any continuous gas purification.

This step marks a significant advance toward the possible standardization

of the 3 He(n,p)T reaction.

Our first gsc was studied at the NBS 10 MW reactor, 3 MV positive ion

accelerator, and 120 MeV electron linac over the past two years. The gas

mixture of 3 He and xenon was contained in a right circular cylinder of

length 250 mm and diameter 100 mm. Total pressure of the gas mixture was

held constant at 30 psia. Photomultiplier tubes (RCA 8850) were mounted

onto the end windows consisting of pyrex glass coated on the cell's inner

surface with a 30 microgram/ cm2 coating of d i phenyl sti 1 bene. The gas

mixture was varied from 5 percent Xe to a final 50 percent Xe composition.

Light collection more than doubled as the composition was varied, while

holding the total pressure at 30 psia.

Light collection degraded less than 10% over the two year period that

this gsc was tested. Light collection degradation was determined by com- paring the 3 He(n,p)T peak with the single-photoelectron peak. The gsc had

a resolution of ~ 55 percent (FWHM) on the 3 He(n,p)T peak and typically

required 25 keV/photoel ectron

.

Our second gsc contained several improvements. The number of pyrex

window/photomultiplier tube modules (pw/pmt modules) was doubled and the

cell size was reduced. The cell consisted of a cube with 150 mm sides.

Four faces of the cube contained the pw/pmt modules; whereas, the remaining two faces were for neutron beam entrance and exit. With a 238 Pu

a-source mounted in the center of the cell, with 30 psia xenon, and with 3

pw/pmt modules looking at the source, a resolution of 10 percent (FWHM) was measured for the 5.5 MeV a-particle peak. A total of ~ 800 photoelectrons represented the a-particle peak for a conversion rate of ~ 7 keV/photoel ectron. Next, the second gsc was tested using neutrons from

the thermal column of the NBS reactor. For this test, a gas mixture of

12 percent 3 He, 88 percent Xe was used at a total pressure of 22.5 psia.

The gsc had a measured resolution of ~ 32 percent (FWHM) on the 3 He(n,p)T

peak

.

195
Division 536, Technical Activities (cont'd.)

In order to meet the needs of keV-energy neutron cross section

measurements, a resolution of <. 20 percent (FWHM) on the 3 He(n,p)T peak is

required. This might be accomplished with one further modification to our design. Namely, we would use 10 cm diameter pyrex windows and z 7.5 cm diameter photomultipliers instead of the present 3" diameter pyrex windows

and 2“ diameter (RCA 8850) photomultipliers. Work is presently in

progress on incorporating this improvement into our design.

Future measurements at the NBS might include absolute determination

of the 3 He(n,p)T cross section at 0.5 MeV using the NBS "Black Detector"

at the 3 MV positive ion accelerator and at 2.5 MeV using the associatedparticle technique at our 200 k V neutron generator. The shape of the cross section could be measured at our 120 MeV linac dedicated pul sedneutron source using a time-of-fl i ght technique for the neutron energy

range from thermal to 3 MeV. Improved gsc performance and accurate

measurement of the 3 He(n,p)T cross section are crucial steps toward

elevating this reaction to a viable standard level.

Topical Fission Conference Planned (J. W. Behrens & 0. A. Wasson)

The NBS plans to host a topical conference at its Gaithersburg,

Maryland site to acknowledge, "Fifty Years With Nuclear Fission." This

conference will be held April 26-28, 1989 and will have both invited and

contributed papers from an estimated 250 participants. The NBS presently

has the American Nuclear Society as a co-sponsor and will seek other

appropriate cosponsors (DoE, APS, etc.). A newsletter, announcing the

conference and giving an outline of its scope, will be distributed after

January 1, 1987.

Fission Cross Section Systematics (J. W. Behrens)

Work on the fission cross section systematics for a total of over 40

isotopes of uranium, neptunium, and plutonium has been completed. A publication of this portion of the study is near completion and will be

submitted to Nuclear Science and Engineering. The work will then continue

by extending into the light actinide region where a total of over 20

isotopes of thorium and protactinium will be examined.

IV. Neutron Dosimetry Group

This group is engaged in the development and application of standard

and reference neutron fields as permanent facilities for neutron dosimetry

standardization, for neutron detector calibrations, and for reaction rate

cross section measurements. Strong interactions with outside organizations, both in the federal and private sector, are important programmatic

characteri sti c s . Contact for information regarding individual tasks is

J. Grundl .

196
Division 536, Technical Activities (cont'd.)

Neutron Personnel Dosimetry (R. Schwartz & D. Gilliam)

Several types of activity are carried on under this rubric. These

include use of the NBS standard neutron fields for routine calibrations,

for non-routine testing, development, and calibrations of new types of

neutron instrumentation, and for quality control measurements of production instruments. As part of a contract with the Armed Forces Radiobiology Research Institute (AFRRI), we have also been developing a tissue

equivalent proportional counter (TEPC) system to determine neutron dose as

a function of energy deposited, and have designed and directed the building of neutron check source facility.

(1) Routine calibrations were carried on at about the same rate as

in previous years and with about the same overall results: for every

instrument that reads essentially correctly, there seems to be one that

doesn't work at all. Badly calibrated instruments seem to be the rule

rather than the exception. For all of these activities, significant

improvements in the Californium Irradiation Facility this year have made

the system easier and more foolproof to use. Likewise, required

documentation for this calibration service has been completed and reviewed

up to the Center level. The document is approximately 35 pages long, and

includes detailed discussions of the corrections to the data and

uncertainties, as well as a description of the facility and the various

calibration procedures.

(2) We have been working with Yale University in the development of

a new type of neutron dosimeter, and with the Battel le Pacific Northwest

Laboratory in the development of a remmeter based on a TEPC.

(3) The first operational tests of our TEPC system were conducted at

the AFRRI TRIGA reactor early this year. Although this two day run was

only intended to test feasibility, the system ran well enough that useful

results were obtained. Neutron data were taken free in air, and in the

center of 14- cm and 20-cm diameter phantoms. A lead shield essentially

eliminated the gamma dose. As anticipated, attempts to take data without

the lead shield were unsuccessful due to the enormously high count rate of

the gammas. Also as anticipated, the data clearly showed that the neutron

dose rate went down, and the gamma-to-neutron dose ratio went up, as we went from air to thin phantom to thick phantom. This is easily understandable in view of the shielding provided by the phantom, and the gammas

produced by radiative capture in the hydrogen of the phantom. The data

also showed, however, that the shape of the neutron part of the "y-curves"

(i.e., curves of y versus yd(y), where y is the lineal energy and d(y) is

the probability density of absorbed dose in y) were essentially identical

for the three conditions when properly normalized. This was not at all

obvious a priori and the result suggests that future cal cul ati onal effort

might best be spent on understanding the gamma part of the dose, rather

197
Division 536, Technical Activities (cont'd.)

than the neutron, since to first order, the shape of the neutron part does

not seem to change. The magnitudes of the neutron and gamma doses can be

accurately measured with the appropriate tissue equivalent ion chambers.

Some interesting details in the measured spectra suggest the need for

further experimental investigation. Fine structure in the peak of the

20-cm phantom data was just within the 2 percent statistical uncertainty

of the data points. Although it is considered unlikely that the structure

is real, the measurements should be repeated with higher statistical

precision. Also some slight energy shifts among the spectra may not be

due to drifts in TEPC gain.

(4) The AFRRI check source cask has been received from the vendor

and is now in place in their Standards Laboratory. The californium source

was shipped from Savannah River and transferred to the cask by the end of

September after some unusual safety, security, and administrative questions had been settled.

(5) New fission chamber monitors for the AFRRI exposure rooms have

been fabricated and tested. These monitors will provide a direct measure

of neutron exposure over the full range of the Triga reactor dose rates,

without sensitivity to gamma ray background. Based on a double ionization

chamber arrangement, these monitors will establish exposures with a precision of 1 percent for power levels as low as 1 kW and irradiations as short as 1 minute, or alternatively, will monitor exposure rates at a power level of 1 MW with less than 1 percent deadtime correction.

(6) A meeting of ISO TC 85/SC 2 ("Radiation Protection") was held at

the PTB, Germany. At this meeting we saw the final printed version of the

ISO Draft International Standard ( I SO/ D IS 8529) "Neutron Reference Radiations for Calibrating Neutron Measuring Devices ... ." This was the

culmination of several years work on the part of the Working Group, and is

to be voted on by the Member Bodies of ISO (ANSI, in the case of the

United States) by December 5. At this meeting we also pretty much

finished a second standard, "Procedures for Calibrating ... Neutron

Measuring Devices ... ." Some details need to be worked out, but it is

anticipated that these can be settled within the next few months.

The first meeting of the ICRU Report Committee on Practical

Determination of Dose Equivalent i s to be held in France in mid-September.

At this meeting work will begin on a report covering the measurement of

dose equivalent in terms of the new specifications for environmental and

individual monitoring promulgated by the ICRU.

198
Division 536, Technical Activities (cont'd.)

Dosimetry for Materials Performance Assessment (E. D. McGarry, G. Lamaze,

& J. Grundl

)

(1) First time ever production of neutron fluence standards with

30-year 137 Cs activity occurred this year. Neutron fluence standards are neutron sensors (activation foils generally) in which a radioactive

species relevant for dosimetry is induced by irradiation in a standard

neutron field. The NBS Cavity Fission Source was used to expose 238 U to a certified neutron fluence of about 2 x 1016 n/cm2 which is sufficient to

produce a measurable 30-year 137 Cs fission-product activity. These

fluence standards are used to verify commercial neutron fluence measurements made with similar uranium foil dosimeters, such as are used in

reactor pressure vessel surveillance.

(2) In the past year, requests for benchmark calibrations of sulfur

dosimeters have increased. These particular activation dosimeters have

been used for many years as a neutron fluence monitor for radiation hard- ness testing of electronics. To ensure that experimenters at different

irradiation facilities are making consistent neutron dose assignments,

several facility managers have requested benchmark calibrations with NBS

fission neutron sources. This year, sulfur irradiations for AFRRI,

Sandia, White Sands, and Aberdeen Proving Grounds have been performed at

the Californium Fission Neutron Irradiation Facility. A special feature

of sulfur activation is that it emits only beta rays. This complicates

the specification of an effective calibration fluence because of the cor- relation between neutron field gradients and beta absorption in the sulfur

detector pellets. Monte Carlo calculations have been performed to calculate a beta absorption vs. gradient correction factor for several

different size sulphur pellets.

(3) Quality assurance measurements were performed to verify masses

of fissionable deposits used for solid state track recorder (SSTR) neutron

dosimeters. SSTR's are mica disks which register tracks of fission fragments from an adjacent fissionable material. Although SSTR's are an attractive technique for doing dosimetry in remote and hostile environments, very small amounts of fissionable material are required and mass

determination can be a difficult problem. At NBS mass assay was accomplished by means of a fission rate intercomparison. Back-to-back deposits

in a dual NBS fission chamber were compared with NBS Fissionable Isotope

Mass Standards (FIMS).

(4) Quality assurance measurements of tantalum impurity in niobium

were performed for several commercial and government laboratories using

the thermal neutron irradiation facility at the reactor. The

92 Nb( n ,n ' ) 92m

Nb react ion for fast-neutron dosimetry results in an x-ray

emitting state with a 16-year half-life. If significant quantities

(>20 ppm) of tantalum are generated in a neutron field with an appreciable

slow neutron component, the tantalum becomes radioactive and decays with

emission of the same energy x-ray as the 92m Nb.

199
Division 536, Technical Activities (cont'd.)

(5) An executive summary document is being prepared for the Nuclear

Regulatory Commission which will delineate the accomplishments of a multi - laboratory program to improve surveillance dosimetry for reactor pressure

vessels. NBS participation in the development of this document has become

more prominent this year. A member of the group, in fact, was singled out

by the funding agency and an executive committee of laboratory project

managers to prepare a critical review of the 8-year old Reactor Pressure

Vessel Irradiation Surveillance Improvement Program. The review was presented at an international gathering of power reactor safety experts.

Neutron Source Strength Calibration Facility (E. D. McGarry & E. Boswel 1

)

NBS provides routine calibration of neutron source emission rates.

Source strengths of 1.5 x 105 to 5 x 109 n/s are calibrated against a radium-beryllium photoneutron . standard source, NBS-I, to an accuracy of

about 1.2 percent by the manganeous sulfate bath technique.

(1) Within the last 12 months the NBS MnS04 Bath calibration facility has undergone extensive upgrading of radiation shielding, of source handling procedures, and of automated data processing. A new shield wall

reduces personnel exposures by a factor of at least 100 incurred while

loading and unloading sources into the MnS04 bath. Improvements include a slave manipulator for remote-source handling behind a water filled plexiglass window installed in a floor-to-ceiling shield wall. In addition, a programmable robot arm allows automated source-to-bath insertion and

removal. Automated data processing includes mi cro-computer data collection and data reduction programs. Within the last 18 months a DEC

PRO-350, with a 33 megabyte hard storage disk, has been successfully

interfaced with MnS04 Bath electronics. Recalibrations of the Bath after

the upgrading effort showed no change to within 0.4 percent.

(2) NBS has completed participation in an international comparison

of neutron source strength determination methods. The NBS result for a source of nominally 2 x 10 7 n/s emission rate was reported with an accuracy of ±0.9 percent which was within 0.5 percent of the best "world

average". Results from 13 laboratories were evaluated and reported by

E. J. Axton, of the National Physics Laboratory, Teddington, England. The source involved now resides at NBS.

(3) Routine source strength calibration services are now back in

operation. As of 1 August 1986, three sources have been calibrated for

outside users. No outside-user backlog now exists; however, about six NBS sources await recalibration and four outside requests for neutron source calibrations work have been received.

An important in-house source calibration involves the 2S2 Cf

Spontaneous Fission Neutron Source, NS-100, which played a major role in

200
Division 536, Technical Activities (cont'd.)

the determination of the 252 Cf fission-spectrum-averaged fission cross

section of 235 U. About one-half of the uncertainty in that measurement is

associated with the source strength of NS-100.

(4) An unusual source-strength calibration has been carried out for

the University of Arkansas to assist them in establishing a regional

personnel -dosimetry calibration laboratory and to make possible a measurement of the fission-spectrum-averaged cross section for the

92 Nb( n ,n ' ) 92fT1 Nb reaction. For the latter measurement, a 32-mg 252 Cf

source, one of the largest in the country (7.5 x lO 10 n/s) was employed.

This source cannot be handled or calibrated at the NBS MnS04 facility

because of its intensity. An alternative two-step calibration was carried out as follows: 1) A second, 5 x 10 9 n/s source was procured with

encapsulation (and therefore scattering and absorption) identical to the

32-mg source. This source was calibrated in the NBS MnS04 bath. 2) A

direct on-site intercomparison of the 5 x io 9 and the 7.5 x lo 10 sources

was accomplished at Arkansas with NBS fission chambers, equipment and

personnel

.

(5) Source strength calibration documentation, now required by NBS

for all calibration and test services, has been drafted and submitted to

the Laboratory for review arid acceptance.

Integral Neutron Cross Section Measurements (G. Lamaze, D. Gilliam,

J. Grundl, & E. D. McGarry) T

(1) The Department of Energy (DOE) is sponsoring a multi -1 aboratory

effort to measure fission-spectrum-averaged cross sections of a relatively

new reaction of interest for high fluence (>10 16 n/cm2

) neutron dosimetry.

The reaction is 92 Nb(n ,n

1 ) 92lT1 Nb with a 16-year half-life. Many laboratories are involved because high fluence, standard-neutron-field irradiations are required and because the 92m

Nb is an x-ray emitter which complicates the activity determination. NBS has completed a 30-day, 10 17 n/cm2 irradiation in the Cavity Fission Source for this project. The NBS

Radioactivity Section will participate in the x-ray activity determinations together with the INEL Laboratory in Idaho, the University of

Arkansas, and Harwell Laboratory in England. The 30-day irradiation in

the NBS Cavity Fission Source, an essential component of the measurement,

was six times longer than any previously performed with this source. A

notable goal of the irradiation was successfully achieved: The 235 U fission disks were handled with minimal personnel radiation exposure.

(2) Our productive and pleasant collaboration with the University of

Virginia Department of Nuclear Engineering and Engineering Physics is

continuing. Professor Tom Williamson is presently analyzing data taken at

201
Division 536, Technical Activities (cont'd.)

NBS during his sabbatical year. A paper on the measurement of photofission cross sections in the NBS neutron driven gamma ray field will be

presented at the 6th ASTM-Euratom Symposium on Reactor Dosimetry. Photofission cross sections of 237 Np, 235 U, 238 U, and 232 Th were measured in

both iron and cadmium capture gamma ray fields* These cross sections are important for correcting the neutron response of fission dosimeters used

in all areas of materials performance assessment under stress of radiation. Professor Williamson and his students have also continued their

analysis of data on the 93 Nb(n,n') spectrum-averaged cross section for

235 U fission neutrons. Niobium foil materials were irradiated in the

Cavity Fission Source of the NBS Reactor in exposures of six and four days

duration. The activity of each foil is measured by comparing the number

of counts with the counts from NBS SRM 4267-8, a

93IT1 Nb activity standard.

Preliminary results indicate an overall 3 percent uncertainty. Final

results will be presented at the 6th ASTM-Euratom Symposium on Reactor

Dosimetry.

(3) Integral tests of 10-100 keV-range neutron activation cross sections for Au , In, and Cu have been begun at the Intermediate Energy

Standard Neutron Field (ISNF) facility at the reactor thermal column. In these tests, the neutron fluence rate is determined by a 239 Pu fission

chamber monitor. Subsidiary measurements are being made to check for

suspected problems of epi -thermal neutron leakage through the penetration

for the monitor chamber stem. The neutron field near the penetration has

been mapped by exposing of activation foils in the region of the penetration and comparing the results with foils activated in the ISNF with the

penetration closed.

(4) The spectrum integrated helium generation cross section for 10 B in the NBS Intermediate-Energy Standard Neutron Field (ISNF) was measured

by the HAFM technique some time ago and found to be discrepant with prediction by a surprising 10 percent. A paper was presented last year which

investigated this discrepancy and others related to it. Since then some preparations have been made to make an independent measurement of this

cross section in ISNF with the NBS double fission chamber. Such an active

measurement in the high-intensity gamma fields within the NBS reactor

thermal column poses severe experimental problems. The reaction products

( 7 Li recoil and alpha particle) which can be nicely resolved in a thermal

beam outside of the thermal column cannot yet be adequately discerned in

the ISNF arrangement inside of the thermal column. It may be necessary to use a Cf fission neutron source to drive the ISNF geometry in order to

perform this measurement. There is good reason to carry out this measurement, if at all possible, because of the basic importance of the 10 B reac- tion as a standard against which many other cross sections are measured

and the confidence which exists concerning the 1/v shape of the reaction

cross section.

202
Division 536, Technical Activities (cont'd.)

Benchmark Neutron Field Development and Application (6. Lamaze, E. D.

McGarry, D. Gilliam, & J. Grundl)

(1) Several man months of effort were spent this year in documenting

the calibration services offered in association with the MBS Fission

Neutron Irradiation Facilities. Two documents, now in the NBS review

process, will be published as NBS Internal Reports. They describe two

services: Activation Foil Irradi ations-Cal i fornium Fission Sources

(44080C) and Activation Foil Irradiation-Cavity Fission Sources (44090C).

The documents describe the characteristics, theory and operation of these

benchmark neutron fields, including the traceability of their calibration

to NBS-I. Available neutron fluences are given along with the uncertainty

of relevant exposure parameters. The documents also detail operating

procedure for performing irradiations in the hope of establishing some institutional memory.

(2) The Neutron Dosimetry Group is responsible for compiling a Compendium of benchmark neutron fields for reactor dosimetry. The compendium describes standard and reference neutron fields which are used to

benchmark neutron dosimetry measurement methods. The latest edition of

the Compendium distributed this year as a 130-page NBS internal report,

describes three NBS Standard Neutron Fields and includes an evaluation of

measured and calculated reaction cross sections for each of them.

(3) In parallel with the development of a compendium, .and in support

of the development of control 1 ed-envi ronment benchmark neutron fields by

the Surveillance Dosimetry Improvement Program, a new ASTM standard for

benchmark referencing is being drafted for ASTM Subcommittee E10.05. Work

on the draft is about 70 percent complete and balloting is expected this

fall.

(4)

As part of a study to check the consistency of isotopic mass

scales at a number of laboratories throughout the world, two 235 U deposits

from the Khlopin Radium Institute ( KRI ) in Leningrad, USSR were made

available through the assistance of the IAEA for measurements at NBS and

Argonne National Laboratory (ANL). The study undertaken at the NBS

consisted of two parts. One consisted in the measurement of the alphadecay rates of the two 235 U samples (KRI VI and KRI-XV) with a low

geometry counting spectrometry facility. This method gave results with an accuracy of ±0.4 percent (la). The other consisted of the measurement of

the total alpha disintegration rate of the samples employing a 2tt alphacounter by the Radioactivity Groups. This second measurement gave results

with uncertainties in the range of 0.8 percent (la). The results by the

two separate methods at NBS, results from low geometry alpha counting at

ANL, and the KRI values all agree to within their stated error limits.

This effort should contribute to the long-sought objective of 1 percent

accuracies for the 235 U fission cross section. Results will be reported

at the ANS Winter Meeting in Washington.

203
Division (5) 536, Technical Activities (cont'd.)

The Fission Neutron Irradiation Facilities have been used to

benchmark neutron dose and energy distributions performed by NBS in the

specimen exposure rooms at the Armed Forces Radiobiological Research

Institute (AFRRI) Reactor. Both active detectors ( 235 U and 237 Np fission

chambers) and passive detectors (S, Ni , In, Rh, and Fe activation detectors) are involved. Results of these measurements have been analyzed

using the NBS codes DETAN and SPAD to determine neutron spectrum, fluence

and kerma for different shield wall configurations in the AFRRI exposure

room.

(6) The gamma counting facility of the Neutron Dosimetry Group was

improved this year by the upgrading of the Digital Pro-350 computer to the

model Pro-380. The faster processor of this model has greatly reduced the

time needed to analyze gamma spectra. No other major changes were made in

either software or hardware in this facility as it has now achieved the

level of "routine" operation. One new operational feature is the routine

weekly calibration of the primary detector to check that there has been no change in the efficiency of the detector. This assures that the traceability of the cavity fission neutron fluences to NBS-I is maintained. A

backup detector and analysis system is now also in routine use for measuring very low activity samples.

(7) The NBS collection of Fissionable Isotope Mass Standards (FIMS)

along with a variety of absolute fission chambers are maintained for fast

neutron field characterization measurements. The FIMS collection com- prises reference deposits and working deposits of eight different fissionable nuclides. The masses of the reference deposits are known to accur- acies of ±0.4 percent to ±2.5 percent (with 68 percent confidence). The

distinct energy thresholds for these various fission detectors permit

broad-group energy analysis as well as total neutron fluence rate determinations. Activities in maintenance of the FIMS collection this year

included calibration of new working deposits of 238 U and relocation of the

alpha assay system in newly allocated laboratory space.

Smaller Projects

(1) Preliminary work in support of a proposed neutron life-time

experiment has begun. The responsibility of the Neutron Dosimetry Group

in the proposed experiment would be the determination of the average

linear density of neutrons in the neutron beam, downstream from an electromagnetic proton trap. A detachable neutron detector would be absolutely calibrated in a series of subsidiary measurements employing both

cold neutron beams and thermal neutron beams. The active neutron detector

will consist of a thin 10 B deposit, viewed by four surface barrier detectors. A study of possible materials for the backing of the 10 B deposit

has been made, and thin (0.38 mm) crystalline silicon wafers have been

chosen as the backing material. These si ngl e-cry stal backings will scatter thermal neutrons less than half as much as would the thinnest possible

204
Division 536, Technical Activities (cont'd.)

A1 backing (0.13 mm). Furthermore, these crystal wafers are extremely

smooth, flat, and rigid, so that good solid angle reproducibility and

stability can be maintained.

(2) Two members of the group have been very active in ASTM Committee

E-10 on Nuclear Technology. Dale McGarry is the principal author of the

new standard on Benchmark Referencing and is a member of the planning

committee for the 6th ASTM-Euratom Symposium on Reactor Dosimetry, to be

held in Jackson Hole, WY in 1987. George Lamaze is the Vice-Chairman and

acting Secretary of subcommittee E10.05 on Nuclear Radiation Metrology and

is the Secretary of the planning committee for the Jackson Hole

Symposi urn.

(3) The National Atomic Museum in Albuquerque, NM has requested

advice and consultation regarding the development of a comprehensive display of the realities of nuclear energy. The exhibit will center around

highlights of history and the demonstration of operating devices related

to that history. NBS participation is through membership on a Steering

Committee made up of representatives from selected nuclear energy laboratories and the American Nuclear Society. Efforts at NBS will be directed

mainly toward the preparation of display texts and oral presentations

which can challenge viewers of varying interests and backgrounds.

(4) A continuing problem with gamma-ray fluence measurements in

mixed neutron and gamma radiation environments is the neutron sensitivity

of the gamma-ray sensor. This is particularly true of new types of

thermoluminescent detector materials (TLD) such as BeO and Aji 2 0

3

. In a program initiated by the SCK/CEN Laboratory, Mol, Belgium, the NBS along

with the English Berkeley Laboratory are cooperating in a TLD neutron

sensitivity experiment. Conventional 7 Li F TLDs and BeO and Aa 2 0

3 TLDs

have been exposed to a bare 235 Cf source for three hours and their

response compared to a 10-day exposure to the same source surrounded by a 14-cm thick lead sphere. With the lead, the gamma dose from a californium

source is reduced by a factor of about 10 to something less than 5 percent. The irradiations have been completed and the TLD materials

returned to England and Belgium for evaluation.

(5) NBS personnel traveled to ORNL to participate in an absolute

power level determination of a special reactor core assembled for a nuclear nonprol i feration study. The power level was determined from fission rate measurements made with a miniature, needlelike, sealed fission

chamber which could be positioned down among the fuel plates of the core elements. The absolute mass of 235 U in the fission chamber was determined

before hand at the NBS reactor thermal column by comparison of its fission

rate to that of an NBS fission chamber with a deposit of known mass.

(6) Prototype fi ssi on- sci nti 1 1 ation counters devel oped by Lawrence

Livermore National Laboratory (LLNL) were calibrated in tests at the

205
Division 536, Technical Activities (cont'd.)

reactor thermal column. The neutron sensitivity data provided by these

tests was used by LLNL scientists to make crucial settings of the recording oscilloscopes prior to weapons tests at the Nevada site in March,

1985. These data are also being used in interpretation of the test

results.

(7) An experimental 7 Li F gamma dosimeter has been supplied under

contract to the Babcock & Wilcox company for test exposure in the Oconee

II nuclear reactor plant. This depleted 7 Li F crystal is shielded by an enriched 6 Li-glass enclosure and sealed in a welded aluminum capsule.

Calibration tests with NBS 60 Co gamma sources will be made for other

crystals from the same batch, and neutron sensitivity tests will be

carried out using the cavity fission source.

V. Radioactivity Group

Introducti on

Development of new techniques and basic calibrations were emphasized

this year, with quality-assurance programs and Standard Reference Material

production and distribution retaining importance. Operators' manuals for

the alpha-particle and gamma-ray calibration services were broadened to

include introductory material sufficient to describe the procedures to the

general public and prepared for publication. Data handling and analysis

were enhanced, and a new low-level gamma-ray spectrometry system designed.

Interactions with instrument manufacturers, power-plant radiochemistry

personnel, and radiopharmaceutical manufacturers and users were extended.

The following paragraphs provide further details about selected topics.

BIPM Intercomparison of I09 Cd Activity Measurements (C. F. Ballaux,

B. M. Coursey, & D. D. Hoppes)

Measuring the activity (decays per second) of 109 Cd is complicated by

the el ectron-capture decay to a 40-s 88-keV state that decays largely by

internal conversion. However, the weak 88-keV gamma ray provides one of the

few useful efficiency-calibration points in this energy region for gamma-ray

spectrometry systems routinely used to measure mixtures of radionuclides.

This combination of challenge and utility, plus some previous international

calibration discrepancies, led to the distribution of a common solution to some 20 national and international standardizing laboratories under the

sponsorship of the Mesure des Radionucleides section of the Comite

Consultatif pour les Etalons de Mesure des Rayonnements Ioni sants of the

Bureau International des Poids et Mesures. Participants were invited to

measure the emission rate of either the x and gamma rays (per unit solution

mass), in addition to the activity concentration. The resultant value of

the probability per decay for these photons could then be used to relate

SRMs calibrated for activity or photon-emission rate.

206
Division 536, Technical Activities (cont'd.)

Measurements were performed at NBS in March, 1986, with the assistance of a guest scientist from the Studiecentrum voor Kernenergie in Mol,

Belgium. The experiments and their results are:

( 1 )

( 2 )

(3)

(4)

(5)

( 6 )

The emission rate of conversion electrons from BIPM 109 Cd

sources was measured with a liquid-scintillation counter, with

the small correction for a gamma-ray contribution calculated

from a literature value for the total -conversion coefficient and

calculated values for the efficiency. The value was

5.721 x 106 s^g -1 ± 0.49 percent.

The emission rate of gamma rays was measured with a small

diameter-well Nal(Tl) spectrometer for which the efficiency was calculated and checked. The value was (2.191 ± 0.010) x 105 s-ig' 1

.

The two above results were added to give an activity concentration of (5.940 ± 0.028) x 106 Bq g -1

. The ratio of the two

results was used to give a total -conversion coefficient, a, of

26.11 ± 0.17. The feeding to 109m Ag is nearly complete, so the

gamma-ray probability per decay, Py, is simply (1 + a)

0.03689 ± 0.00024.

-l or

An activity concentration for the 109 Cd was derived from comparison of gamma-ray rates with the beta-particle-emitting analog

109 Pd activity-calibrated with the liquid scintillator, using

the total -conversion coefficient measured above to evaluate the

1 ° 9

m

Ag efficiency. The value was 6.006 x 106 Bq g” 1 ± 0.48

percent. A

109 Pd half life of 13.404 ± 0.008h was measured by

following the decay for 11 half lives on a germanium gamma-rayspectrometry system.

The gamma-ray probability per decay for the 109 Pd solution was derived from the activity measured in (4) and a gamma-rayemission rate measured with the Nal(Tt) well counter.

Py

= 0.03648 ± 0.00031.

A tentative measurement of the 109 Cd conversion-el ectron rate was made with a thin-film source pressed between two cooled

Si (Li) detectors. The value was 5.729 x 106 s^g"1 ± 1.1

percent.

Large Area Source Calibration Technique (J. M. R. Hutchinson)

The program to develop traceability of U.S. Air Force alpha-particle

field measurements is virtually complete. Large area 238 Pu sources

mounted on conducting backings have been examined for response as a function of vertical and horizontal position, aperture size and shape, etc.

207
Division 536, Technical Activities (cont'd.)

The objective of providing a calibrated response for the Radiac Calibrator

with an uncertainty less than ± 10 percent appears to be achievable. Some

preliminary measurements to characterize the x-ray and 1 ow-energy-photon

response of the calibrator have been initiated.

Experiments with Resonance Ionization Mass Spectrometry (J. M. R.

Hutchinson & K. G. W. Inn)

NBS has collaborated with Atom Sciences, Incorporated and Colorado

State University in developing a new technique called Sputter Initiated

Resonance Ionization Mass Spectrometry (SIRIS) for ultrasensitive measurement of trace amounts of nuclides. Our particular interest is in the use

of this technique for the measurement of radionuclides in soils, sediments, and other naturally occurring materials as a means of providing

calibrations of radionuclide concentrations in the NBS natural matrixstandards. The technique will have many other applications in other areas

such as industry and medicine.

Recently, we have sought to place this mass spectrometric technique

on a sound basis for quantitation of materials. A major, in fact the

major, source of uncertainty in many instances in measurements conducted

using other mass spectrometric techniques is traced to isotope fractionation, especially when the isotope dilution technique is being applied for

the calibration. For example, fractionation of molybdenum isotopes in the

usual sputter-initiated mass spectrometry (SIMS) is approximately one percent per a.m.u. and 10 percent per a.m.u. in beryllium in conventional

thermal ionization mass spectrometry. Special techniques, including calculated estimates containing significant uncertainties, are used to over- come these problems and are often not really satisfactory.

In SIMS, the fractionation is associated in the literature with the

ionization process. Since SIRIS utilizes neutrals, there is hope that

fractionation will not be a problem, since the ionization occurs by the

totally different and controllable process of laser excitation. (Generally we try to saturate the transitions.) If this were the case, it would

be a highly significant finding in the development of ultrasensitive

technol ogy

.

The problem of molybdenum isotope fractionation in SIRIS from a metallic source has been under study by our group recently. A time-offlight mass spectrometer replaced the magnetic one in SIRIS. A spectrum

readout is shown in Fig. 1. The fractionation results are shown in Fig.

2. The even isotopes taken separately from the odd isotope data show no fractionation whereas the odds differ from the evens by about 15 percent.

In all likelihood, this is associated with hyperfine splitting in the

odd-A's. In the future, we will investigate the specific role hyperfine

splitting plays in fractionation in SIRIS and attempt to develop techniques to avoid measurement uncertainties associated with this effect.

208
Mo SIRIS 0 degree sample no lens

200 - 600 1000

FIG. 1

209
MOLYBDENUM

SXRIS/NBS

ABUNDANCE

MOLYBDENUM

SIRIS/NBS

ABUNDANCE

0-99

LiPP.._.

l.pl

-

0.90

0.95

1.00

1

MASS (AMU)

92 93 94 95 96 97 98 99 100

MASS (AMU)

FIG. 2

210
Division 536, Technical Activities (cont'd.)

10 Be- 9 Be Isotopic Ratio Standard (K. G. W. Inn, J. M. R. Hutchinson, and

B. M. Coursey)

The tandum accelerator mass spectrometry (TAMS) coirmunity has been

engaged in ultra-sensitive isotopic ratio measurements of 10 3e/ 9 3e for

significant geochronology studies. An isotopic ratio standard is being

prepared in cooperation with Oak Ridge National Laboratory and TAMS users

to bring consistency to the TAMS community. The master material was isotopically enriched for 10 Be and mass analyzed by secondary-ionization

mass spectrometry at Oak Ridge National Laboratory. At NBS, the master

material has been further characteri zed by 1

i quid- sci nti 11 ati on measurements and will be mass analyzed by thermal -i oni zati on mass spectrometry

.

All of this information on the master material will be used for a high

precision half-life evaluation of 1

0

Be ; to date, the half life of 10 Be is

known only to ± 20 percent. The master material has been diluted with

high-purity single-crystal 9 Be in sequential steps to a 2400 g solution

containing 5 mg of Be/g solution, and a 10 Be/ 9 Be ratio of 3 x 10" 11

. The

dilution has been confirmed by liquid scintillation counting down to the

second-to-the-1 ast dilution (10 -9

). The final dilution step will be

confirmed through an interlaboratory comparison of TAMS users.

Distributions of Calibrated Samples by Commercial Pharmaceutical

Laboratories in FDA-Organized Quality-Assurance Exercises (B. M. Coursey

and J .M. Calhoun)

In order to assess the quality of measurements of radioactivity in

nuclear medicine, the Center for Devices of the F.D.A. has organized

quality assurance programs in which commercial laboratories select a fraction of their normal customers to receive a standardized sample in the

normal container; for example, "m

Tc in saline solution in an injection

syringe. NBS personnel coordinate the calibration aspects of the

program.

In the first exercise, completed this year, Syncor, Inti, distributed "m

Tc in syringes. Responses were received from 172 customers. The cus- tomers' values, obtained primarily with commercial dose calibrators, were

compared with the known values from the Syncor calibration laboratory:

141 values within ± 5%

164 values within ± 10%

169 values within ± 20%

The US Pharmacopaei a requires ± 10 percent accuracy on injected doses.

In the second exercise, initiated this year, Dupont/NEN Products

distributed the heart-imaging agent 201 Tz in their usual serum vials to 62

customers. Earlier this year Dupont calibrated their ionization chambers

in the serum-vial geometry with NBS standard solutions. In July NBS

personnel visited the Dupont laboratory to review the calibration records

211
Division 536, Technical Activities (cont'd.)

and the protocol for distribution. Eight vials were sent to NBS for

measurements with commercial dose calibrators and Radioactivity Group

ionization chambers. The average for the Dupont activity for the 8 vials was 0.5% higher than NBS (the worst deviation was + 0.9%). As with the

earlier Syncor exercise, Dupont's customers' results will be forwarded to

the FDA for evaluation, with individual identities not revealed.

U.S, /Spain Joint Project for the Development of Liquid-Scintillation

Techniques for the Standardization of Radionuclides (B. M. Coursey,

A. Grau Malonda*, E. Garci a-Torano* , J. M. Los Arcos*, M. T.

Martin-Casal lo*)

The NBS and the JEN (Madrid) are in the third year of a 5-year joint

project, sponsored by the US/Spain Joint Committee for Scientific and

Technological Cooperation to improve the accuracy of liquid-scintillation

techniques. The first year dealt with the standardization of pure-betaemitting radionuclides and the second year with el ectron-capture (EC)

decay radionuclides. Two extensive computer codes, EFFY2 for beta emitters and VIAS for EC-decay nuclides, have been implemented on the NBS

CYBER 855 and the JEN UNIVAC. Separate Monte Carlo programs have been

written to compute wall distortions for high-energy electrons, and interaction probabilities for x and gamma rays. The computer work in the third

year will entail i ncorporati ng these routines into programs EFFY2 and

VIAS, which will allow us to compute efficiencies for e-y emitters ( 59 Fe,

203 Hg) and EC-decay nuclides ( n Mn, 201 Tji )

.

The experimental liquid-scintillation measurements associated with

this project are closely coordinated with the computations to allow us to

verify the usefulness of the programs. Measurements on beta emitters

during this year include 10 Be, 32 P, 33 P, 89 Sr, 109 Pd and 114 In. A publication describing earlier results for 63 Ni and 241 Pu is in preparation. A

paper on 14 C appeared this year. A publication has also been prepared

describing the standardization of 9941 Tc, which decays by an isomeric

transi tion.

Techniques are also being developed for the measurement of radionuclide mixtures and impurities:

radiostrontium 82 Sr, 85 Sr, 89 Sr, 90 Y radiophosphorus 32 P, 33 P radioindium U1 ln, 114m

In

The experimental phase of these studies is complete but further refinements to the programs will be necessary before we can match the computed

and observed spectra.

*Guest scientists from Junta de Energia Nuclear, Madrid

212
Division 536, Technical Activities (cont'd.)

Activity Measurements and Decay-Scheme Studies of 82 Rb. (D. D. Hoppes,

B. M. Coursey, and F. J. Schima)

Positron-emission tomography for medical imaging makes use of shortlived radionuclides in order to minimize radiation dose to the patient. A

system for delivering positron-emitting 76-s 82 Rb from a generator loaded

with 25-d 82 Sr was developed in the early 1980s, and radiopharmaceutical

companies in the Atomic Industrial Forum cooperative quality-control program with NBS asked that basic activity calibrations be developed for

these radionuclides.

The 82 Sr decays by pure electron capture, which rules out the usual

schemes using cascade radiations to effect a direct calibration. Measurement of the 82 Sr - 82 Rb equilibrium mixture in the past had used gamma-ray

spectrometry of the 511-keV photons from the annihilation of positrons

with a maximum energy over 3 Mev. The fraction of electron capture relative to positron emission is calculated to vary from 0.03 for the dominant

ground state branch to 700 for high excited states, hence a calibration

based on positron measurement requires a knowledge of the branching to

excited states. A further complication to annihilation-radiation measurements of the equilibrium mixture is the presence of large, often dominant,

amounts of a 85 Sr impurity with a 514-keV gamma ray. The short half life

of separated 82 Rb complicates measurements of that radionuclide, and make

transference of NBS calibrations to simple instruments such as dose calibrators in nuclear-medicine clinics impossible.

However, an isolated 776-keV gamma ray can be measured readily on spectrometry systems with efficiencies calibrated as a function of energy,

if its gamma-ray probability per decay can be established. This was a primary goal of measurements performed at NBS in 1983 on both equilibrium

mixtures and separated 82 Rb, with the assistance of guest scientist Yang

Dongliang of the Peoples Republic of China.

In that series of measurements, liquid-scintillation counting of the

positrons was also used, with an apparent discrepancy of about +5 percent

with respect to the annihilation-radiation measurements. Measurements of

the relative probability of gamma rays from 82 Rb established the decay

branchings to higher levels, and the change in the emission rate of the

776-keV gamma ray from the equilibrium mixture with time yielded a half

life of 25.36 ± 0.03 days.

Although preliminary results from the National Physical Laboratory in

the UK seemed to support the annihilation-radiation results, we felt that

further measurements were required in order to understand our earlier

discrepancy. In late 1985, relatively pure 82 Sr- 82 Rb was obtained and

measured by both 1 i quid- sci nti 1 1 ation counting and germanium spectrometry

of the 511-keV photons, with additional geometries used to probe the substantial correction for annihilation in flight with the latter method.

213
Division 536, Technical Activities (cont'd.)

The earlier discrepancy was substantiated, which suggests that quantitative measurements of high-energy positrons may need further investigation. However, use of either resultant value for the probability per

decay for the 776-keV gamma ray, or a simple average, will lead to

improved routine analysis of radiopharmaceutical s. The two gamma-rayprobability values are 0.152 ± 0.003 (positron rate from annihilation

radiation) and 0.145 ± 0.002 (liquid-scintillation counting of the positrons), where the uncertainties are root-mean-square combinations of all

suspected components estimated as approximations to one standard

deviation.

Distribution of Radioactivity Standard Reference Materials (SRMs) and

Measurement Services

The following table sumarizes explicit interactions which propagated

basic NBS activity calibrations between August 1, 1985 and July 31, 1986.

Total Radioactivity SRMs di stri buted 816

SRMs under the AIF program

for nuclear medicine 217

Scheduled Calibrations 35

Special Measurements 70

Traceability exercises

including EPA, FDA, NRC,

and commercial firms 128

The traceability exercises carried out with the regulatory agencies,

radiopharmaceutical manufacturers, and suppliers of commercial reference

materials test the ability of a laboratory to supply an activity value for

a sample of a radionuclide before the NBS calibration is known. The exer- cises do not, except in special cases or by inference, test or investigate

the general quality-control procedures within the laboratory, which would

be a much more ambitious undertaking.

VI . X-Ray Physics Group

Radiology and Radiography Standards and Measurement Methods

(J. H. Sparrow)

The X-Ray Physics Group has performed evaluations of D0D high energy

radiological inspection systems.

At the request of the Navy Department, this program carries out the

following tasks:

214
Division 536, Technical Activities (cont'd.)

1) Measure and cal i brate every 12 to 18 months the x-ray outputs of

approximately ten 16 MeV Linear Accelerators used by DOD for radiological inspection systems.

2) Propose radiological procedures to determine image quality achieved

during production and refitting inspections of missiles; approximately

every 6 to 12 months, perform an on-site audit of the radiological

image quality achieved at the various DOD facilities and at the

various DOD product manufacturers; participate in the development of

radiological penetrameters which are used as image quality indicators;

and participate in new design of a test specimen used to evaluate both

image quality and system performance for high energy CT radiological

inspection systems.

3) Assist in the integration of old and new radiological methods, (film,

real-time, and tomography), to assure that adequate image quality is

achieved during routine inspections.

4) Propose radiographic equipment which can be used at the DOD facilities

and DOD vendors to monitor x-ray beam energy fluence and beam

positions.

Dental Fluoroscopy and Tomography (J. H. Sparrow & C. E. Dick)

In cooperation with the National Institute of Dental Research and the

Army Institute of Dental Research, the X-Ray Physics Group is developing

different types of real-time intra-oral x-ray imaging sensors which will

be used in the development of a digital dental tomographic system. One

type of x-ray sensor that has been developed and tested consists of an x-ray scintillator and a coherent fiber optic bundle which transmits the

dental image out of the mouth to a video camera system. A second type of

x-ray sensor under development consists of a semiconductor wafer with a pixel array that will have a spatial resolution of 5 line pairs per mm. The video output signals from these sensors will have specialized electronic equipment and software which are presently under development. With

this equipment, the imaging system will have the capability of image

processing, storage and transmission. In addition, special x-ray sources

are under development which will permit the imaging system to produce

dental tomographic images with x-ray exposure times less than 1 second.

Digital Energy Subtraction Imaging for Biomaterials (C. E. Dick)

In many medical x-ray imaging tasks, the specific structures and pathologies to be examined are cluttered with interfering images of surrounding

structures and exhibit insufficient contrast relative to the surroundings

to be successfully imaged with conventional techniques. To overcome these

difficulties, a program is underway to utilize the differential absorption

of different energy photons to provide a difference signal between the

215
Division 536, Technical Activities (cont'd.)

object of interest and the surrounding medium. In general, this requires

photon beams with larger energy difference than previously employed. In addition, other aspects of digital subtraction techniques are being

pursued including the maximization of the image difference signal using

contrast media and image processing techniques^

In order to provide photon beams with large average energy differences, a method has been developed for generating quasi- monoenergeti c beams with

sufficient intensities for imaging systems. These beams are generated by

selective filtration of typical diagnostic x-ray spectra. In addition, a computer algorithm has been developed which will predict with reasonable

accuracy the effects of filters on diagnostic spectra and thus ameliorates

the amount of experimental data that must be taken.

To record the images, a digital imaging system consisting of an image

intensifies a tv camera, and a digital image processing system has been

assembled. Preliminary testing of this system indicated that the resolution of the original image intensi fi er-camera system was insufficient for

the imaging tasks being considered and the image processing system lacked

the necessary flexibility to facilitate digital enhancement. In the past

year this system has been considerably enhanced by replacing the image

intensifier with a new imager-camera system which has increased sensitivity and variable magnification. At the present time, a new image processing system is under development based on the use of a personal computer as

a host for a dedicated pipeline processor and image storage system. As in

the original system, archival storage will be provided by the use of

Winchester type hard disk systems.

Finally, a collaborative program has been completed with an industrial

guest worker to examine the properties of various compounds to be used as image contrast media. This program examined the physical properties of

halogenated, rare earth, and heavy metal compounds to determine a systematic basis for their use in such methodologies as digital subtration

angiography (DSA).

4-MeV Van de Graaff Accelerator (C. E. Dick)

The 4-MeV Van de Graaff accelerator is now in use as a pulsed electron

source for studies in pulsed radiolysis. Electron beam pulses with a width of 0.5 microsecond and a pulse current of up to 0.5 Ampere are being

utilized in preliminary experiments on the production of free radicals in

chemical systems. Currently, construction is underway on quadrupole

focussing elements to permit the production of line shaped beams to maximize the amount of electron beam current along the optical analysis axis.

Additionally, a toroidal beam monitor has been developed to measure the

pulsed beam current without interference with the electron beam.

216
Division 536 Technical Activities (cont'd)

HIGH-DOSE RADIATION CALIBRATION

Services Documentation (J. C. Humphreys)

Documentation has been developed that describes the calibration

services available at NBS for the standardization of high absorbed dose

measurements of ionizing radiation (pertinent to photons and electrons,

but not neutrons or heavy ions). Detailed descriptions are given of the

gamma-ray irradiation facilities available, the dosimetry procedures and

dosimetry systems employed, and uncertainty assessment of all facets of

the service. Internal quality control procedures and techniques relevant

to these calibration services are given.

Industrial Radiology (R. C. Placious)

One of the many needs in industrial radiology that we have responded

to is the development of standards related to quantification of performance evaluation image forming radiographic/radiologic systems. For example, we are now involved in developing both the procedures and the

materials for measuring image quality at very low (30 kV) and very high

(4-25 MeV) energies. We produced a draft document for the high energy

image quality measurement which is based on nearly 500 individual tests

throughout the country. The first revision

for peer review . The low energy effort is

development and we are presently working on

and the prescription for beam quality. These two energy regions are of

great industrial interest. Much inspection of composite materials is done

at low energies while walled metal containers (vessels, casks, armor

plate) need to be inspected with high energy radiation sources; (see

Radiologic Inspection of Thick Walled Shipping Containers elsewhere in

this report). We have received requests to assume a key role in the

development of other radiologic standards. These include:

of this has now been submitted

not yet at this stage of

the design of the test device

1. Voltage Calibration of X-Ray Sources (for users)

2. Microfocus Radiography and Sources

3. Digital/Real Time Performance Standards

Radiology for Thick Walled Shipping Casks (R. C. Placious)

Sandia Laboratories has asked NBS to prepare a report on the flaw detection limits in the nondestructive inspection for special nuclear

materials. The radiographic/radiologic part of this work was prepared in

the X-Ray Physics Group of the Ionizing Radiation Division. In addition

to providing flaw detection sensitivity, the report recommended the best

procedure to follow for a given type of flaw.

217
Division 536, Technical Activities (cont'd.)

The impetus for this relates to requests that the United States switch to

monolithic cask structures for both economic and safety reasons. Such

structures are permitted in Europe, but not yet in the United States (by

NRC).

VII. Dosimetry Group

Use of ionizing radiation is becoming ever more widespread in modern

society. The exposure of humans can be purposive (medical) or incidental

(occupational), but both require close control to ensure that the radiation is efficacious in the one case, and harmless in the other. Such control can only be achieved with reliable measurement. With the increased

use and the improved knowledge of radiation effects, the need for more

accurate measurement is constantly increasing. The measurement of ionizing radiation for the purpose of controlling a radiation effect falls in

the field of radiation dosimetry. The Dosimetry Group has the responsibility for providing an up-to-date basis for reliable measurement in dosimetry of ionizing radiation, principally in medicine and radiation protection. This program involves: (1) establishment and maintenance of the

national primary dosimetry standards; (2) dissemination of the units

established by those standards by means of calibration services and

measurement quality assurance programs; (3) research in measurement technology as necessary for any part of the program; and (4) participation in

the relevant national and international activities of the community of

radiation users.

X-ray and Gamma-ray Calibration and Measurement Assurance Services

(J. T. Weaver, P. J. Lamperti , & E. L. Bright)

Calibration services for x-ray and gamma-ray measuring instruments

continues at approximately the same rate as the previous year.

The 100-kV computer program used on the DEC 1123 minicomputer has

been modified with more overlays, which reduces memory requirements so that a later version of the operating system can be used; all data is now

stored on a hard disc. These changes allow the 100-kV and the 300-kV

calibration programs to store data on the same file. Use of a hard disc

and the NBS net allows faster and more reliable data transfer to the host

Cyber 355.

Measurement assurance tests have been carried out with the five AAPM

therapy-level accredited calibration laboratories and the Center for

Devices and Radiological Health. A small but significant error was uncovered in one of the AAPM laboratories by this test. In these measurement assurance tests,, the test equipment is shipped around to all the

laboratories before return to NBS, using the check methods devised for

218
Division 536, Technical Activities (cont'd.)

the particular equipment being used. Traceability to NBS is maintained by

such a measurement test, without the necessity of returning the local

standard to NBS, unless the test shows it to be necessary.

The Navy thermoluminescence dosimetry (TLD) measurement assurance

program, sponsored by the Space and Naval Warfare Systems Command,

continues. NBS receives boxes of 15 TLDs from the Naval Surface Weapons

Center and irradiates 12 of them to known exposures with 137 Cs gamma

rays. The boxes are dispatched to designated Naval units for readout, the

results of which are returned to NBS for data reduction and comparison to

NBS exposures. The results are sent to the sponsoring agency, who

schedules a retest or recalibration for any TLD readout instruments that

indicate exposures that differ from the NBS exposure by more than ± 13%.

About 275 such boxes, containing 3300 exposed dosimeters, were dispatched

during FY86. Also a 120-Ci 137 Cs source was calibrated for the Navy on three ranges.

Fifteen brachytherapy sources (small -size sources used in medicine

and industry) were calibrated. In order to do this, the data on the NBS

137 Cs sources was reevaluated and new values assigned. An uncertainty in

the brachytherapy calibration, relating to the influence of the source

size and shape on the scattered radiation, was resolved by comparing

measurements in the concrete brachytherapy calibration trough with calibrations made under free-air conditions.

The documentation of the NBS calibration procedures for x-ray and

gamma-ray measuring instruments has been completed. This extensive document (> 120 pages), covering 20 years of development of exposure standards

and measurement techniques, has been accepted by the appropriate review

authorities.

A guest scientist from China has been trained in exposure calibration methods, and a graduate student in the Radiation Sciences program at

Georgetown University has served a short internship on dosimetry calibration methods.

The Dosimetry Group provided assistance to the Federal Emergency

Management Agency (FEMA) for an energy-dependence study of prototype

personnel dosimeters, and also to the Department of the Army, Redstone

Arsenal, for special high exposure for testing of prototype TLD dosimeters. The Dosimetry Group was called upon on very short notice to provide consultation and assistance to E.G.& G. , Idaho Falls, concerning a high-priority personnel protection measurement problem, which involved

selection of instruments, calibration beam qualities, and provision of

calibrations for various instruments under a variety of conditions.

219
Division 536, Technical Activities (cont'd.)

High-Energy Electron and Photon Measurement-Assurance Services

(C. G. Soares)

Users of medical linear accelerators for cancer teletherapy need

assurance that their machines are delivering the required radiation

dosage. To meet this need-, NBS offers a measurement assurance service

that involves mailing to the users passive dosimeters to be irradiated in

a prescribed geometry and returned to NBS for evaluation. For this

service, ferrous-ferric (Fricke) dosimeters are used at present.

There were four mailings of Fricke dosimeters in FY86, involving

62 sets of participants. Two batches of dosimeters were prepared. In principal, each dosimeter can be used as many times as it takes to accumulate 200 to 300 Gy (20 to 30 krad). In order to conserve time, and thus

cost to the participants, the tests are administered simultaneously to as many participants as the batch size permits. To handle the increase in

volume that the service has experienced in the last few years, 60 new cells have been purchased, which, when successfully worked into the

system, will allow an increase in the number of cells per mailing, and

possibly a decrease in the number of mailings per year. It is planned to

augment this chemical dosimetry service with a TLD service, if technical

problems connected with the required extensive automation can be solved.

Documentation on the NBS procedures for the Fricke measurement assur- ance service has been completed and accepted by the appropriate review

authorities.

Standard Monoenergetic Electron Beams (C. G. Soares)

NBS has been requested by the radiation protection community to

establish standards for and assist in the development of methods of

measuring the beta-particle radiation fields that are found in nuclear

power installations. Beta-particle detection instrumentation is currently

being calibrated using only broad-spectrum radionuclide sources. In order

to determine instrument response as a function of energy in detail, NBS

has developed a set of accel erator-produced nearly monoenergetic electron

beams. Measurements made of response functions of various instruments has

indicated that the monitoring system that has been employed restricts the

reproducibility of such measurements to an unacceptably high level (10-15

percent). This is caused by changes in the field shape between the time

when the off-axis monitor is calibrated and when the instrument response

is measured. To try to overcome this difficulty, a new monitoring and

control system was designed and constructed during FY86. This system

consists of four off-axis monitors that feed back to beam steerers that

control the field shape dynamically. While construction of the system

hardware is complete, software is still being fine-tuned; it is not yet

known if the system will be successful at increasing measurement

reproducibil ity

.

220
Division 536, Technical Activities (cont'd.)

Beta-particle Source Calibration and Associated Measurement Assurance

Services (J. S. Pruitt)

NBS provides the only calibration available in the United States for

ophthalmic beta-particle applicators, which are sources of 90 Sr+ 90 Y encapsulated in stainless steel so that only the energetic beta particles of

90 Y are emitted. These applicators are used for treating various medical

conditions on the anterior surface of the eye. In response to requests

from the radiation-protection community, NBS is establishing a calibration

facility for broad-beam beta-particle sources of 90 Sr+90 Y,

147 Pm, and 204 T1

.

The NBS extrapolation chamber has been used to calibrate four ophthalmic applicators for absorbed dose to water at the applicator surface.

In conjunction with these calibrations, quality assurance techniques have

been devised and implemented using the NBS ophthalmic applicator (SN 0258)

in a reproducible position. The SN 0258 current is reproducible to well

within 1 percent, a small fraction of the stated uncertainty of calibrations which is ±15 percent.

The two PTW extrapolation chambers have been used to measure a com- plete depth-dose curve for 147 Pm in polyethylene terephthal ate. One of

these chambers still has the 2.61 mg/cm2 graphite-coated entrance window

with which it was originally supplied, but the other has been changed to a 0.7 mg/cm2 aluminized polyethylene terephthal ate window in order to reduce

the extrapolation necessary to obtain calibrations at zero absorbed depth.

The dependence on source distance has been carefully measured for the

147 Pm source in an effort to evaluate the correction needed for attenuation in the extrapolation chamber air gap.

A trip was made to Battel 1 e-Paci fic Northwest Laboratory to inspect

their facilities for making beta-particle calibration measurements and to

compare depth-dose curves measured at BPNL and NBS for a special 90 Sr+90 Y source encapsulated with a titanium window. The results of this comparison are incomplete at the time of writing because the BPNL experimental

setup is still underdevelopment.

Perturbation measurements as a function of source distance have been

started with the 147 Pm source. These measurements lead to a correction

for scatter from the side walls of the PTW extrapolation chamber. This

correction was measured by the PTB for the standard distance of 200 mm

only.

Documentation on the NBS procedures for calibration of ophthalmic

applicators has been completed and accepted by the appropriate review

authorities.

221
Division 536, Technical Activities (cont'd.)

Absorbed-dose Calorimetry (S. R. Domen)

Medical and industrial applications of ionizing radiation are quantified in terms of the physical quantity absorbed dose, which is the

energy absorbed per unit mass in the material of interest. The calorimeter, which measures absorbed energy in terms of a temperature rise, is the

logical standard of absorbed dose. NBS has developed a series of calorimeters, as part of a program to provide reliable national measurement

standards for absorbed dose. The two most recent are a graphi te-i n-water

calorimeter for radiation at medical -1 evel intensities, and a polystyrene

calorimeter for radiation at industrial intensities.

The graphi te-i n-water calorimeter was designed to allow determination

of water absorbed dose, while avoiding the uncertainties associated with

the radiation chemistry of laboratory water. Measurement with that calorimeter have shown good agreement with earlier measurements using other

calorimeters. A redetermination of the NBS standard of absorbed dose is

in progress, involving three kinds of NBS calorimeters and suitable ionization chambers.

The med ical -1 evel NBS graphite calorimeters require evacuation to

obtain adequate thermal isolation of the calorimeter core. The polystyrene calorimeter was designed for use at atmospheric pressure in highlevel radiation fields. It measures the .temperature rise in a polystyrene

cylinder of variable radius, and from this it is possible to calculate the

absorbed dose to polystyrene and other low-atomic-number materials. It has been used to determine the absorbed dose rate in the NBS 60 Co pool

source, by putting the calorimeter in a stainless- steel cylinder that is

a replica of the cylinder used to irradiate materials being studied. The

measured dose rate was in agreement within 1 percent with that measured

earlier using a relatively complicated evacuated graphite calorimeter.

Dosimetry of High-Energy Photon and Electron Beams (L. J. Goodman,

C. G. Soares, & R. Loevinger)

It is proposed to use the electron beam of the NBS racetrack microtron to produce collimated beams of high-energy photons and electrons,

which will simulate those used clinically for cancer therapy. These beams

will be used in a research project to test the adequacy of current protocols to provide accurate dosimetry measurements. The tests consist of

measurements of photon fields and electron fields to compare dosimetry

with ionization chambers calibrated according to prescribed protocols with

dosimetry performed with an absorbed-dose calorimeter.

This work will use a separate beam line to transport the electron

beam to a transmi ssion window from which the beam will enter a target and

collimator assembly. Accelerator beam parameters will range from about

180 uA at 5 MeV to about 1 pA at 35 MeV. Calculations indicate that it

222
Division 536, Technical Activities (cont'd.)

may not be necessary to shield other instrumentation in the room from this

experiment. When the collimated beams are operational, the need for

shielding will be reevaluated and shielding will be installed if necessary. All apparatus, except for the beam line to the target, has been

designed, cost estimates have been obtained, and funding is being sought.

Development of Dosimetry Standards for Neutron Therapy (L. J. Goodman,

D. M. Gilliam, S. R. Domen, J. J. Coyne, & R. S. Caswell)

The aim of this work is to improve the accuracy and consistency of

measurements of absorbed dose for neutron radiation therapy by providing

national dosimetry standards and improved data on neutron interactions

with tissue and tissue-equivalent materials. Neutron radiation therapy

is being clinically tested at several centers in the United States, and

also other centers worldwide. The U. S. dosimetry standards base must be

accurate and consistent with the international standards system in order

to provide good physical dosimetry to ensure the success of the neutron

therapy trials, and to facilitate the exchange of information between

institutions. The role of NBS in providing neutron dosimetry standards

will be similar to the long-established role for photon radiation

standard s.

The technical approach is to develop a tissue-equivalent (TE) ionization chamber coupled with a neutron-insensitive gamma-ray dosimeter as the working national standard. Using neutrons with an energy of 15 MeV,

this method of neutron dosimetry will be compared against a TE calorimeter, and against neutron kerma determined from monoenergetic neutron

fluence measurement combined with calculated kerma factors to obtain a check between three independent methods of neutron absorbed dose determination. The comparison of the ionization chamber and fluence methods will

be performed using the monoenergetic neutrons obtained from the NBS 3-MV

positive-ion Van de Graaff accelerator. The comparison of the ionization

chamber and calorimetric methods will require very high neutron dose rates

due to the lower sensitivity of calorimeters and will be performed at a suitable remote site. Agreement between the three independent methods,

and intercompari sons with the Bureau International des Poids et Mesures

and with other national standards 1 aboratories, will assure the accuracy

and consistency of the U. S. dosimetry standards for neutron therapy. The

properties of all dosimeters for this project have been studied, and the

instruments have been calibrated twice. At the time of writing, a comparison with BIPM instruments is in progress.

The experimental standards program will be supported by a theoretical

neutron dosimetry program aimed at improving the knowledge of physical

data and the correction factors needed to interpret the experimental

measurements. Such data and factors include: kerma factors, W (mean

energy per ion pair), and mass stopping powers.

223
SPONSORED WORKSHOPS, CONFERENCES, AND SYMPOSIA

Division 536, Ionizing Radiation

B„ M. Coursey, 0. D. Hoppes, and L. L. Lucas organized a meeting of com- mercial suppliers of radioactivity calibration materials, representatives

of nuclear power plant radiochemistry departments, NRC enforcement personnel, and officers of the Atomic Industrial Forum to discuss possible NBS

involvement in quality assurance programs for power-plant monitoring.

NBS, February 3, 1986.

Symposium "Antioxidants" organized by M. S. Simic at the 34th Radiation

Research Society Annual Meeting at Las Vegas, Nevada, April 13-17, 1986.

W. L. McLaughlin sponsored workshop on Electron Beam Dosimetry for

Association for the Advancement of Medical Instrumentation (AAMI), May 19,

1986.

NBS, Laboratoire Metrologie des Rayonnements Ioni sants, and International

Committee for Radionuclide Metrology co-sponsored Low-level Environmental

Radionuclide Metrology Symposium of the International Committee for

Radionuclide Metrology, Grenoble, France, June 3, 1985. (Proceedings

Published as EML Report No. 452, editors H.L. Volchok, J. M. R. Hutchinson

and N. A. Chieco.)

Stephen M. Seltzer organized and co-chaired with J. W. Behrens two

invited/contributed sessions, "Charged-Particle Transport Calculations:

Methods and Applications, I and II," at the annual meeting of the American

Nuclear Society, Reno, Nevada, June 15-20, 1986.

CRR conducted a full day workshop on Food Irradiation Technology for a group of about 50 Food and Drug Administration plant inspectors. It was organized and chaired by J.C. Humphreys. Senior CRR staff covered such

topics as basic radiation interaction mechanisms, effects of radiation on biological materials, radiation processing plant operations, quality

control procedures, calibration and use of dosimetry systems, and aspects

of health physics in processing plants. Tours of several radiation and

research facilities were conducted, NBS, July 24, 1986.

224
INVITED TALKS

Division 536, Ionizing Radiation

Berger, M. J., "Energy Loss and Range of Electrons," IAEA Advisory Group

Meeting on Nuclear and Atomic Data for Radiotherapy and Radiobiology,

Rijswijk, The Netherlands, September 16-20, 1985.

Bergtold, D., "Analysis of DNA Damage and Repair During Aging,"

Gerontology Research Center, National Institute of Aging, Baltimore, MD,

March 18, 1986.

Calhoun, J. M., "The Role of Radioactivity Reference Materials in the

Quality Assurance of Radiopharmaceuticals," The Laboratory Instrument and

Equipment Conference and Exhibition, Chicago, Illinois, October 1, 1985.

Carlson, A. D., "Nuclear Data Standards for ENDF/B-VI," Nuclear Data

Section of the International Atomic Energy Agency, Vienna, Austria,

January 3, 1986.

Carlson, A. D., "Status of the ENDF/B-VI Standards," CSEWG Meeting,

Brookhaven National Laboratory, Upton, NY, May 23, 1986.

Caswell, R. S., "Scientific Activities of the Committee on Interagency

Radiation Research and Policy Coordination," Board on Radiation Effects

Research, National Academy of Sciences, Washington, D.C., December 6,

1985.

Caswell, R. S., "Scientific Activities of the Committee on Interagency

Radiation Research and Policy Coordination," White House Science Panel

Briefing, NEOB, Washington, D.C., March 21, 1986.

Caswell, R. S., (with J. J. Coyne, H. M. Gerstenberg, and R. B. Schwartz),

"Refinement of Neutron Energy Deposition and Microdosimetry Calculations,"

International Conference on Fast Neutron Physics, Dubrovnik, Yugoslavia,

May 27, 1986.

Caswell, R. S., "Neutron Energy Deposition in Biological Materials,"

Institute for Medicine, Kernforschungsanl age , Julich, West Germany,

June 3, 1986.

Caswell, R. S., "Neutron Energy Deposition in Biological Materials,"

Central Bureau of Nuclear Measurements, Euratom, Commission of the

European Communities, Geel , Belgium, June 11, 1986.

Col 1 ^ , R. "Development of Transfer Standards for Radon Measurements,"

Physics Department, Colorado State University, Fort Collins, CO, September

24, 1985.

225
Division 536, Invited Talks (cont'd.)

Col 16, R. "Measurement Uncertainties: Philosophies, Theories and the Role

of Subjective Estimation," Graduate School of Public Health, University of

Pittsburgh, January 29, 1986.

Coll$, R. "Views on the Meaning and Treatment of Measurement

Uncertainties," Western Pennsylvania Chapter of the Health Physics

Society, Pittsburgh, PA, January 29, 1986.

Coils, R. "NBS Radon Measurement Standards," Conference on Indoor Radon in

the Mid-Atlantic States, George Mason University, Fairfax, VA, May 13,

1986.

Coils, R. "Panel on Measurement Uncertainties," 1986 International

Conference on Precision Electromagnetic Measurements, NBS, Gai thersburg

,

MD, June 27, 1986.

Coursey, Bert M., "Standardization of Radionuclides by the Method of 4tt b L iquid Scintillation Efficiency Tracing," American Chemical Society,

Memphis, Tennessee, October 9, 1985.

Coursey, B. M., "The Standardization of Pure-Beta-Particle Emitting

Radionuclides," American Nuclear Society Meeting, November 12, 1985.

Coursey, B. M., "Standardization of Radionuclides Using Liquid Scintillation Counting Techniques," Beckman Instruments, Fullerton, CA, April 19,

1986.

Coyne, J. J., "Secondary Charged Particle Spectra and Kerma Calculations,"

IAEA Advisory Group Meeting on Nuclear and Atomic Data for Radiotherapy an Radiobiology, Rijswijk, The Netherlands, September 16-20, 1985.

Dizdaroglu, M., "Oxidative Base Damage in DNA," University of Medicine,

New Jersey Medical School, Newark, NJ, October 23, 1985.

Dizdaroglu, M., "Characteri zati on of Oxidative Base Damage to DNA,"

Gerontology Research Center, National Institute of Aging, Baltimore, MD,

March 18, 1986.

Dizdaroglu, M. "The Use of Gas Chromatography-Mass Spectrometry for

Characterization of DNA Base Damage at Low Radiation Doses," The 34th

Annual Meeting of the Radiation Research Society, Las Vegas, NV, April 14,

1986.

Dizdaroglu, M., "Radiation-Induced Damage to DNA and Its Detection at Low

Radiation Doses," Health and Safety Research Division, Oak Ridge National

Laboratory, Oak Ridge, TN, April 21, 1986.

226
Division 536, Invited Talks (cont'd.)

Dizdaroglu, M., "Detection of Free Radical -Induced Damage to DNA at

Biologically Relevant Levels," The Johns Hopkins University, School of

Hygiene and Public Health, Baltimore, MD, April 24, 1986.

Dizdaroglu, M., "Detection of Radiation-Induced Damage to DNA at Low

Radiation Doses," Cancer Research Campaign, Gray Laboratory, Mount Vernon

Hospital, Northwood, Middlesex, UK, July 10, 1986.

Dizdaroglu, M., "Characterization of Radi at i on -Induced Damage to DNA,"

Lawrence Berkeley Laboratory, Berkeley, CA, July 24, 1986.

Dizdaroglu, M., "Radiation-Induced Formation of Cyclic-Purine Nucleosides

in DNA," Lawrence Berkeley Laboratory, Berkeley, CA, July 25, 1986.

Gilliam, D. M., "Absolute Neutron Flux Determi nation--A Problem for the

Measurement of t-," Workshop on the Investigation of Fundamental

Interactions witn Cold Neutrons, NBS, Gaithersburg, MD, November 14, 1985.

Goodman, L. J., "Neutron Dosimetry," Radiobiology Concepts Lecture, Armed

Forces Radiobiology Research Institute, Bethesda, MD, October 15, 1985.

Grundl , J. A., "Pursuing Public and Professional Perception of Nuclear

Energy With the Smithsonian Lady Godiva Replica and Demonstration/Display,

Banquet Presentation at Fast Burst Reactor Workshop, Albuquerque, NM,

April 7, 1986.

Hoppes, D.

and "U.S.

Institute

Institute

Institute

D., "Gamma-Ray Spectrometry," "NBS Radioactivity Measurements,

Traceability Requirements for Radioactivity Measurements,"

of Atomic Energy (Beijing), Shaanxi Provincial Research

for Preventive Medicine, Sichuan University, and the National

of Metrology (Beijing), China, October 10-21, 1985.

II

Hoppes, D. D., "Gamma Spectroscopy and Related Activities in the

National Bureau of Standards Radioactivity Group," Nuclear Data Users'

Group Meeting, Southport, North Carolina, May 14, 1986.

Hubbell, J. H., "Radiation Physics Programs at the NBS," Rudjer Boskovic

Institute, Zagreb, Yugoslavia, October 10, 1985.

Hubbell, J. H., "Photon Cross Sections 1 keV to 100 GeV: Current NBS

Compilation," American Nuclear Society Winter Meeting, San Francisco,

California, November 11, 1985.

Hubbell, J. H., "Nuclear Cross Sections and Their Applications," Student

Chapter, American Nuclear Society, U.S. Naval Academy, Annapolis, MD,

December 5, 1985.

227
Division 536, Invited Talks (cont'd.)

Hutchinson, J. M. R., "Low-level Radioactivity Measurements at NBS,"

Instituto de Rad i oprotecao E Dosimetria, Rio de Janeiro, Brazil, October

2, 1985.

Hutchinson, J. M. R., Inn, K. G. W., Parks, J. E., Beekman, D. W., Spaar,

M. T., and Fairbank, W. M., "Investigation of Matrix Effects or Isotope

Dilution in SIRIS Measurement of Uranium in Soils," Advanced Laser

Technology for Chemical Measurement Workshop, Seattle, WA, April 28,

1986.

Hutchinson, J. M. R., Lucatorto, T. B., and Witaker, T. L., "Exploiting

the Optical Isotope Shift for Ultrasensitive Isotopic Analysis with

Lasers," American Nuclear Society, Reno, NV, June 26, 1986.

Hutchinson, J. M. R., Parks, J. E., Beekman, D. W., Moore, L. J., Schmitt,

H. W., Sparr, M. T., Taylor, E. H., and Fairbank, W. M., "Progress in

Analysis by Sputter Initiated Resonance Ionization Spectroscopy," Third

International Symposium on Resonance Ionization Spectroscopy," Swansea,

UK, September 7, 1986.

Inn, Kenneth G. W., "The National Bureau of Standards Natural -matrix

Envi ronmental -1 evel Radioactivity Standard Reference Materials," Low Level

Measurements of Actinides and Long-lived Radionuclides in Biological and

Environmental Samples Meeting, Lund, Sweden, June 10, 1986.

Johnson, R. G., "Mul ti -Parti cl e Accelerator for Neutron and High-LET

Radiation Research," IAEA Advisory Group Meeting on Neutron Source

Properties, Leningrad, USSR, June 9, 1986.

Johnson, R. G., "Detectors for Neutron Scattering in the eV Region,"

Condensed Matter Physics Seminar, Rutherford Appleton Laboratory, Didcot,

UK, June 18, 1986.

'

Lamaze, G. P., "Calibration and Applications of NBS Standard Neutron

Fields," Univ. of Virginia, Dept, of Nuclear Engineering and Engineering

Physics - Seminar, Charlottesville, V A, February 6, 1986.

Loevinger, R., "The NBS Primary Standard of Absorbed Dose," Radiation

Science Seminar, Georgetown University Graduate School, Washington, DC,

October 2, 1985.

Loevinger, R., "Quantities, Units, and Standards for Radiology," Annual

Meeting of the American Association of Physicists in Medicine, Lexington,

KY, August 4, 1986.

McGarry, E. D., "LWR-PV Surveillance Dosimetry Improvement Program

Overview," Fourteenth Water Reactor Safety Information Meeting, NBS,

October, 1985.

228
Division 536, Invited Talks (cont'd.)

McLaughlin, W., "Food Irradiation Technology Overview," Preservation

Technology Meeting, FMC Central Engineering Laboratories, Santa Clara, CA,

September 26, 1985.

McLaughlin, W., "High-Dose Dosimetry," UK Panel on Gamma-Ray and Electron

Irradiation, University of Oxford, Oxford, England, October 3, 1985.

McLaughlin, W., "Radiochromic Response to Ionizing Radiation: Kinetics

and Temperature Effects," Chemistry Division Seminar, Atomic Energy

Research Establishment, Harwell, England, October 7, 1985.

McLaughlin, W., "Radiation Dosimetry by Means of Infrared

Spectrophotometry of Polyethylene," Physics Dept. Seminar, Royal Military

College of Science, Shrivenham, England, October 11, 1985.

McLaughlin, W., "Dosimetry as a Means of Quality Control in Industrial

Radiation Sterilization," to the staff of IOTECH, Inc., Northglen,

Colorado, October 1, 1985.

McLaughlin, W., "Dyed Cellulosics for High-Dose Dosimetry," Laboratory for

Radiation and Polymer Science, University of Maryland, College Park, MD,

December 4, 1985.

McLaughlin, W., "Dosimetry as a Means of Quality Control in Electron Beam

Sterilization of Medical Devices," Meeting of the Sterilization Standards

Committee of Association for the Advancement of Medical Instrumentation,

Hyatt Arlington, Arlington, VA, January 21, 1986.

McLaughlin, W., "Dosimetry for Regulatory and Routine Control in Radiation

Applications," Departments of Energy, Health, and Environment in Bangkok,

Thailand, March 7, 1986.

McLaughlin, W., "Dosimetry for Measurement Quality Assurance," Division of

Foods, International Atomic Energy Agency, Vienna, Austria, March 19,

1986.

McLaughlin, W., "Real-time Telemetering of Dosimetry Data for Radiation

Processing Applications," Chemistry Division, AERE Harwell, Atomic Energy

Research Establishment, Harwell, Oxfordshire, UK, June 13, 1986.

McLaughlin, W., "Basic Dosimetry and Quality Control," Food and Drug

Administration Training Course, NBS, July 24, 1986.

McLaughlin, W., "Radiation Dosimetry and Dosimetry for QA in Industrial

Sterilization by Ionizing Radiation, Industrial Sterilization Symposium,

Round Lake, IL, Sept. 17 & 18, 1986.

229
Division 536, Invited Talks (cont'd.)

Simic, M., "Discrimination Between Direct and Indirect Effects of

Radiation," Case Western University, Cleveland, OH, August 8, 1986.

Simic, M., "Chemistry of Irradiated Foods," Interagency Collaborative

Group on Environmental Carcinogenesis, Bethesda, MD, September 24, 1986.

Soares, C. G., "Calibration of Beta-Particle Radiation Protection

Instrumentation," Radiation Protection Dosimetry Course, Harvard Medical

School, Boston, MA, May 13, 1986.

Wasson, 0. A., "Neutron Measurements at NBS," Physi kal i sch-Techni sche

Bundesanstal t , Braunschweig, Federal Republic of Germany, November 8,

1985.

Wasson, 0. A., "Progress in Neutron Measurements at NBS," Central Bureau

for Nuclear Measurements, Geel , Belgium, November 18, 1985.

Wasson, 0. A., "Recent Fission Cross Section Standards," XVth

International Symposium on Nuclear Physics-Nuclear Fission, Gaussig,

German Democratic Republic, November 11-15, 1985.

230
PUBLICATIONS

Division 536, Ionizing Radiation

Al-Sheikhly, M. and Simic, M., Superoxide Radical Generation in Radiation

Induced Autoxidation of Fatty Acids, in Superoxide and Superoxide

Dismutase in Chemistry, Biology, and Medicine, ed . G. Rotilio, Elsevier,

NY (1986) p. 32.

Alberts, W. G., and Schwartz, R. B., Comparison of the Filtered-Neutron

Beams at the NBS and PTB Reactors by Cali brat iang a Spherical Remmeter,

Proc. Fifth Symposium on Neutron Dosimetry, September 17-21, 1984, Munich,

Germany, EUR 9762 EN l (1985).

Alter, H., McLaughlin, W. L. et.al , Glossary of Terms in Nuclear Science

and Technology , American Nuclear Society (1986).

Barnea, G., Seltzer, S. M., and Berger, M. J., Transport of Electrons and

Associated Bremsstrahl ung Through a Composite Aluminum-Lead Shield with

Applications to Spacecraft Shielding, NBSIR 86-3429 (1986).

Barnea, G. and Dick, C.E., Monte Carlo Study of X-Ray Scattering in

Transmission Radiography (13) 4, (1986).

Berger, M. J., Energy Loss Straggling of Protons in Water Vapor, Radiat.

Protection Dosimetry 13_, 87-90 (1985).

Bobrowski, K., Dzierkowska, G., Grodkowski, J., Stuglik, Z., Zagorski, Z.

P., and McLaughlin, W. L., A Pulse Radiolysis Study of the Leucocyanide of

Malachite Green Dye in Organic Solvents, J. Phys. Chem. 89, 4358-4366

(1985).

Carlson, A. D., Poenitz, W. P., Hale, G. M., and Peelle, R. W., The

Neutron Cross Section Standards Evaluations for ENDF/B-VI, Radiation

Effects 96, 87 (1986).

Carlson, A. D., New Measurements of the Ratio of the 10 B(n,a) to 6 Li(n,t)

Cross Sections in the eV Energy Region, Radiation Effects 96^, 109 (1986).

Caswell, R. S., J. J. Coyne, and H. M. Gerstenberg, Recent Improvements in

Neutron Energy Deposition Calculations, Proc. Fifth Symp. on Neutron

Dosimetry , EUR 9762, CEC Luxembourg, 1985, pp. 255-262.

Caswell, R. S., Nuclear Data for Biomedical Applications, Radi ati on Effects, Proc. Conf. Nuclear Data for Basic and Applied Science, 94, 1-11

(1986).

231
Division 536, Publications (cont'd.)

R. S. Caswell and J. J. Coyne, Neutron Kerma Values, Physics in Medici ne and Biology Encyclopedia , Pergamon Press (Oxford), 1985, p. 521.

Chen, W., Jia, H. and McLaughlin, W. L., Response of Radiochromic Film

Dosimeters to Electron Beam in Different Atmospheres, Proceedings of

International Symposium on High-Dose Dosimetry, Vienna, ( IAEA, Vienna,

1985) pp. 345-356.

Coursey, B. M., Malonda, A. Grau, Garci a-Torano, E., and Los Acros, J. M.,

Standardization of Pure-Beta-Particle-Emitting Radionuclides, Trans. ANS

50, 13-15 (November 1985).

Coursey, Bert M., NBS Standard Reference Materials of Pure-Beta-Parti cl e- Emitting Radionuclides, American Laboratory, 150-151, (November 1985).

Coursey, B. M., Mann, W. B, Grau Malonda, A., Garcia-Torano, E., Los

Acros, 0. M., Gibson, A. B., and Reher, D. , Standardization of Carbon-14

by 4ir$ Liquid Scintillation Efficiency Tracing with Hydrogen-3, Appl

.

Radiat. Isot. J7, No. 5, 403-408 (1986).

Dick, C. D., Polansky, D., Soares, C. G., and Seltzer, S. M., Radiation

Measurements on a Portable 1.5 MeV Electron Linac, NBSIR 85-3209 (1985).

Dizdaroglu, M., Formation of an 8-Hyd roxyguani ne Moiety in

Deoxyri bonucl eic Acid on y-I rrad i at i on in Aqueous Solution, Biochemistry

24, 4476-4481 (1985).

Dizdaroglu, M. and Simic, M. G., Radi at ion -Induced Crosslinking of

Pyrimidine Oligonucleotides, Radiat. Phys., Chem. _26, 309-316 (1985).

Dizdaroglu, M., Simic, M., and Karam, L., Chemical Analysis of Irradiated

Foods, Trans. Am. Nucl . Soc., JL0 (1985).

Dizdaroglu, Holwitt, E., Hagan, M. P., and Blakely, W. F., Formation of

Cytosine Glycol and 5,6-Di hyd roxycytosi ne in Deoxyribonucleic Acid on Treatment with Osmium Tetroxide, Biochem. J. 235, 531-536 (1986).

Dizdaroglu, M., and Bergtold , D. S., Characteri zation of Free RadicalInduced Base Damage in DNA at Biologically Relevant Levels, Anal.

Biochem. 156, 182-188 (1986).

Dizdaroglu, M., Free Radical -Induced Formation of an 8,5

-Cycl o-2 ' - deoxyguanosi ne Moiety in Deoxyri bonucl ei c Acid, Biochem. J. 238 , 247-254

(1986).

Dizdaroglu, M., Characterization of Free Rad i cal -Induced Base Damage in

DNA by the combined Use of Enzymatic Hydrolysis and Gas ChromatographyMass Spectrometry, J. Chromatogr. 367 , 357-366 (1986).

232
Division 536, Publications (cont'd.)

Duvall, K. C., Soares, C. G., Heaton, H. T. Jr., and Seltzer, S. M., The

Development of a 6 to 7 MeV Photon Field for Instrument Calibration, Nucl . Instrum. Methods BIO, 942 (1985).

Duvall, K. C. and Johnson, R. G., The Development of the Dual Thin

Scintillator (DTS)S in the 1+2 Coincidence Configuration as a Neutron

Spectrometer, Radiation Effects 95, Nos. 1-4, 319 (1986).

Eisenhauer, C., Hunt, J. B., and Schwartz, R. B., Calibration Techniques

for Neutron Personal Dosimetry, Radiation Protection Dosimetry _10, 43-57

(1985).

Eisenhauer, C., Grundl, J., Cassapakis, C., and Verbinski, V., Use of

Threshold Activation Detectors to Obtain Neutron Kerma for Biological

Irradiations, Reactor Dosimetry , Proceedings of the Fifth ASTM-EURATOM

Symposium on Reactor Dosimetry, Geesthacht, West Germany, September 1984,

D. Reidel, The Netherlands (1984).

Eisenhower, E. H., The Concept of Secondary Laboratories, Proceedings of

the Workshop on Radiation Survey Instruments and Calibrations, PNL-SA13346 (1985).

Eisenhower, E. H., The Interagency Committee on Occupational Radiation

Protection Measurements, Proceedings of the Workshop on Radiation Survey

Instruments and Calibrations, PNL-SA-13346 (1985).

Eisenhower, E. H., Secondary Standards Laboratories: An Overview,

Proceedings of the Workshop on Radiation Survey Instruments and

Calibrations, PNL-SA-13346 (1985).

Fu, C., Yang, M. H., Gabbard, F., Schima, F. J., and Thonnard, N., Silicon

as an Implantation Host for Radioactivity Studies, Bull. Am. Phys. Soc.

31, 798 (1986).

Gilliam, D. M., Grundl, J. A., Lamaze, G., Eisenhauer, C. M., McGarry,

E. D. , and Fabry, A., Cross Section Measuremnets in the U235 Fission

Spectrum Neutron Field, Reactor Dosimetry , Proceedings of the Fifth ASTMEURATOM Symposium on Reactor Dosimetry, Geesthacht, West Germany,

September 1984, D. Reidel, The Netherlands (1984).

Gilliam, D. M., and Lamaze, G. P., Absolute Neutron Flux Determination - A Problem for the Determination of i n

. Proceedings of Workshop on The

Investigation of Fundamental Interactions with Cold Neutrons, NBS-SP 7 11,

36 (1986).

Gladhill, R. L., Horlick, J., and Eisenhower, E. H., The National

Personnel Radiation Dosimetry Accreditation Program, NBSIR 86-3350,

(1986).

233
Division 536, Publications (cont'd.)

Grundl , J. A., Pursuing Public and Professional Perception of Nuclear

Energy With the Smithsonian Lady Godiva Replica and Demonstration/Display,

Proc. of Fast Burst Reactor Workshop, Albuquerque, NM (1986).

Grundl , J. A. and Eisenhauer, C. M., Compendium of Benchmark Neutron

Fields for Reactor Dosimetry ~ Standard Neutron Field Entries, NBSIR 85-

3151 (January 1986).

Hannah, K. W. and Simic, M. G., Long-Term Preservation of Bacon by High

Energy Electrons, Radiat. Phys. Chem. _25, 167 (1985).

Heaton, II, H. T., Implementation of CRCPD Accreditation Criteria in State

Calibration Laboratories, Proceedings of the Workshop on Radiation Survey

Instruments and Calibrations, PNL-SA-13346 (1985).

Hubbell, J., Radiation Gauging, in the Encyclopedia of Materials Science

and Engineering, M. B. Bever, ed., MIT Press, Cambridge, Mass. (1986),

p. 4040-4042.

Hunter, E. P. L., and Simic, M. G., Use of an Optical Multichannel

Analyzer for Recording Absorption Spectra of Short-Lived Transients, Rev.

Sci. Inst. 56, 2199-2204 (1985).

Hutchinson, J. M. R., Mullen, P. A., and Col 16, R., The NBS Radon-In-Water

Standard Generator, Nuclear Instruments and Methods in Physics Research

A247 , 385-9 (1986).

Hutchinson, J. M. R., Coll£, R., Inn, K. G. W., and Mullen, P. A., Low

Level Measurements at NBS, in Environmental Measurements Laboratory Report

EML-452, pp. 31-3 (1986).

Johnson, R. G., Conceptual Design of an Induction Linac for Neutron

Research, Radiation Effects _95_, Nos. 1-4, 291 (1986).

Johnson, R. G. and Schrack, R. A., Nondestructive Evaluation of M732

Promixity Fuzes, NBSIR 85-3259 (1985).

Jovanovic, S. V. and Simic, M., Tryptophan Metabolites as Antioxidants,

Life Chemistry Reports _3> 124-130 (1985).

Jovanovic, S. V., Neta, P., and Simic, M. G., One-Electron Redox Reactions

of Pyrazol in-5-0nes, A Pulse Radiolysis of Antipyrine and Analogues,

Molecular Pharmacology 28, 377 ( 1985).

Jovanovic, S. and Simic, M., Repair of Tryptophan Radicals, J. Free

Radicals in Chemistry and Biology JL, 125-129 (1985).

234
Division 536, Publications (cont'd.)

Jovanovic, S. V. and Simic, M. G., One-Electron Redox Potentials of

Purines and Pyrimidines, J. Phys. Chem. 90, 974-978 (1986).

Jovanovic, S. V., Harriman, A., and Simic, M., Electron Transfer Reactions

of Tryptophan and Tyrosine Derivatives, J. Phys. Chem. 90,- 1935-1939

(1986).

Karam, L. R., Simic, M. G., and Dizdaroglu, M., Free Radical -Induced

Cross-Linking of Polydeoxythymidyl ic Acid in Deoxygenated Aqueous

Solution, Int. J. Radiat. Biol. 49, 67-71 (1986).

Kim, L., Pratt, R. H., Seltzer, S. M., Berger, M. J., Ratio of Positron

to Electron Bremsstrahl ung Energy Loss: An Approximate Scaling Law, Phys.

Rev. A33, 3002 (1986).

Kronenberg, S., McLaughlin, W. L. and Siebentritt, C. R., Radiochromic

Leuko Dye Real-Time Dosimeter, One-Way Optical Waveguide, US Patent

4,489,420 (Dec. 18, 1984); Canadian Patent 1,197,024 (November 19, 1985).

Loevinger, R., The New AAPM Protocol, Radiotherapy & Oncology _4, 295-296

(1985).

McGarry, E. D., Gilliam, D. M., Lamaze, G., Ei senhauer, C. M., and

Fabry, A., The U.S. U235 Fission Spectrum Standard Neutron Field

Revisited, Reactor Dosimetry , Proceedings of the Fifth ASTM-EURAT0M

Symposium on Reactor Dosimetry, Geesthacht, West Germany, September 1984,

D. Reidel, The Netherlands (1984).

McLaughlin, W. L., Miller, A., Abdel-Rahim, F., and Prei singer, T.,

Plastic Film Materials for Dosimetry of Very Large Absorbed Doses,

Transactions of 5th International Meeting on Radiation Processing, San

Diego, Radiat. Phys. Chem. _25, 729-748 (1985).

McLaughlin, W. L., Humphreys, J. C. and Wenxiu, Chen, Response of

Radiochromic Film Dosimeters to Gamma Rays in Different Atmospheres,

Transactions of 5th International Meeting on Radiation Processing, San

Diego, Radiat. Phys. Chem. _25, 793-805 (1985).

McLaughlin, W. L., Radak, B. B., and Farahani , M., Measurement Quality

Assurance in the Radiation Treatment of Foods, Transactions of American

Nuclear Society Meeting, pp. 8-9 (1985).

Miller, A. and McLaughlin, W. L., Measurement of Absorbed Dose and Dose

Distributions, Radiat. Phys. Chem. _27 (1986).

Neta, P., and Simic, M., Free Radical Chemistry of Natural Products, in

Chemical Changes in Food During Processing , eds. T. Richardson and J. W.

Finley, AVI Publishing Co., Westport, Conn. (1985) p. 63.

235
Division 536, Publications (cont'd.)

Radak, B. B., McLaughlin, W. L., and Simic, M. G., Enhanced Sensitivity of

Chemical Dosimeters Using Liquid-Core Optical Waveguides, Nucl . Instr.

Methods A243 , 201-206 (1986).

Rageh, M. S. I., El-Assy, N. B., Ashry, M., and McLaughlin, W. L., Optical

and Electrical Analysis of Blue Polymethyl Methacrylate for High-Dose

Dosimetry, Radiat. Phys. Chem. 27_, 127-131 (1986).

Rahim, F. Abdel, Eid, S. A., Souka, N. and McLaughlin, W. L., The

Radiolysis of Bromophenol Blue in Aqueous Solutions, Radiat. Phys. Chem.

27, 211-217 (1986).

Robertson, J. S., Berger, M. J., Jones, J. P., Lathrop, K. A.,

Poston, J. W., Vanek, K. N. , and Zamenhof, R. G. , The Experimental Basis

for Absorbed-Dose Calculations in Medical Uses of Radionuclides, NCRP

Report 83 (1985) pp. 109.

Saloman, E. B. and Hubbell, J. H., X-Ray Attenuation Coefficients (Total

Cross Sections): Comparison of the Experimental Data Base with the

Recommended Values of Henke and the Theoretical Values of Scofield for

Energies between 0.1-100 keV, NBSIR 86-3431 (1986).

Schwartz, R., Experiences in Calibration of Neutron Survey Instruments,

Proc. Workshop on Radiation Survey Instruments and Calibrations, July

10-12, 1984, Gaithersburg, fid., PNL-SA-13346 (November 1985).

Seltzer, S. M. and Berger, M. J., Bremsstrahl ung Spectra from Electron

Interactions with Screened Atom Nuclei and Orbital Electrons, Nucl.

Instr. Methods B12, 95-134 (1985).

Simic, M., and Hunter, E., Antioxidants, in Chemical Changes in Food

During Processing, eds. T. Richardson and J. W. Finley, AVI Publishing Co,

Westport, Conn. (1985) p. 107.

Simic, M. G., International Conference on Mechanisms of DNA Damage and

Repair, J. Res. NBS 90, 321 (1985).

Simic, M. G., Introduction to Mechanisms of DNA Damage and Repair, in

Mechanisms of DNA Damage and Repair , eds. M. G. Simic, L. Grossman and A. C. Upton, Plenum Press, NY (1986) p. 1 .

Simic, M., and Jovanovic, S., Free Radical Mechanisms of DNA Base Damage,

in Mechanisms of DNA Damage and Repair , eds., M. Simic, L. Grossman and A.

C. Upton, Plenum Press, NY (1986) p. 39.

Soares, C. G., Predicting Beta Particle Response of Instruments from their

Response to Monoenergetic Electrons, Rad. Protect. Dosim. 14, 113-115

(1986).

236
Division 536, Publications (cont'd.)

Wasson, 0. A., Carlson, A. D., and Duvall, K. C., Analysis of the Effect

of Random Events on the 14 MeV 235 U(n,f) Cross Section Measurement,

Radiation Effects 96_, 9 (1986).

Whitburn, Kevin D., Hoffman, Morton Z., Brezniak, Nina V., and Simic,

Michael G. , Mechanisms of Li yand-to-Metal Intramolecular Electron Transfer

in Cobalt ( III )-Amine Complexes Containing a Coordinated Radica, Inorganic

Chemistry 25, 3037-3043 (1986).

237
PUBLICATIONS IN PREPARATION

Division 536, Ionizing Radiation

Abdel -Rehim, F., Zahran, A. H., Ezzedin, F. M., and McLaughlin, W. L.,

Manganese-Activated "Cabal" and "Libal" Glasses for High-Dose Dosimetry SP

(to be submitted to Radiation Physics and Chemistry).

AlSheikhly, M. and McLaughlin, W. L., A Pulse-Radiolysis Study of the

Mechanism of Radiolytic Dye Formation in Liquid Solutions of Hexa

( hyd roexyethyl ) Pararosani 1 i ne Cyanide (to be submitted to the Journal of

the American Chemical Society).

Ballaux, C„, Coursey, B. M., and Hoppes, D.D., Standardization of and

Selected Decay Data for Palladium-109 and Cadmium-109 (in preparation).

Barnea, G., Berger, M. J., and Seltzer, S. M., An Optimization Study of

El ectron-Bremsstrahl ung Shielding for Manned Spacecraft, J. of Spacecraft

and Rockets (in press).

Barnea, G. and Dick, C. E., Coupled Electron/Photon Monte Carlo Calculations of X-Ray Scattering with Application to Industrial Radiography.

(Accepted for publication in NDT International).

Behrens, J. W., Ma Hongchang, and Wasson, 0. A., Advances in the Use of

3 He in a Gas Scintillation Counter (to be published in Transactions of the

American Nuclear Society).

Behrens, J. W., On the Systematics of Neutron-Induced Fission Cross

Sections in the MeV Range, Part 1: Uranium, Neptunium, and Plutonium

Isotopes (to be submitted to Nuclear Science and Engineering).

Berger, M. J., Energy Loss and Range of Electrons, Proc. IAEA Advisory

Group Meeting on Nuclear and Atomic Data for Radiotherapy and

Radiobiology, September 16-20, 1985, Rijswijk, The Netherlands (in

press)

.

Brenner, D. J., Zaider, M., Coyne, J. J., Menzel , H. G., and Prael , R. E.,

The Evaluation of Non-Elastic Neutron Cross-Sections on Carbon Above

14 MeV, Nucl . Sci. Eng. (in press).

Caswell, R. S., Coyne, J. J., Gerstenberg, H. M., and Schwartz, R. B.,

Refinement of Neutron Energy Deposition and Microdosimetry Calculations,

Proc. of the International Conference on Fast Neutron Physics , Dubrovnik,

Yugoslavia, May 25-31 , 1986 (in press).

Coursey, B. M., Lucas, L. L., Grau Malonda, A. and Garci a-Torano , E., The

Standardization of Plutonium-241 and Nicrel-63 (in preparation) .

238
Division 536, Publications in Preparation (cont'd.)

Coursey, B. M., Hoppes, D. D., Schima, F. J., and Unterweger, M. P., The

Standardization of Samori um-153, Int. J. Appl . Radiat. Isotopes, Part A,

(in press).

Coyne, J. J., Gerstenberg, H. M., and Hennen, L. A., Secondary Charged

Particle Spectra and Kerma Calculations, Proc. of IAEA Advisory Group

Meeting on Nuclear and Atomic Data for Radiotherapy and Radiobiology (in

press)

.

Dias, M. S., Carlson, A. D. Johnson, R. G., and Wasson, 0. A., Application

of the Dual Thin Scintillator Neutron Flux Detector in a 235 U(n,f) Cross

Section Measurement (in preparation).

Dizdaroglu, M., (invited paper). The Purification of Polypeptide Samples

by Ion-Exchange Chromatography on Silica-Based Supports, Hi gh-Performance

Liquid Chromatography in Biotechnology, Ed. W. S. Hancock, J. Wiley, New

York (in press).

Dizdaroglu, M., (invited paper). The Use of Capillary Gas ChromatographyMass Spectrometry Chemical Characterization of Free Radical -Induced Damage

in DNA, Biotechniques (submitted).

Dizdaroglu, M., Dirksen, M. L., and Robbins, J. H., Identification of an 8,5' -Cycl o-2‘ -deoxyguanosi ne Moiety in DNA Isolated from y-Irradiated

Human Cells Biochemistry (submitted).

Dizdaroglu, M. (invited paper), Chemical Determination of Oxidative Damage

to DNA, Handbook of Biomedicine of Free Radicals and Antioxidants, Eds. J.

Miquel, H. Weber and A. Quintanilha, CRC Press, Boca Raton (submitted).

Domen, S. R., and Ba, W.-Z., A Polystyrene Absorbed -Dose-Rate Calorimeter

(in review).

Domen, S. R., Advances in Calorimetry for Radiation Dosimetry, in The

Dosimetry of Ionizing Radiation , Chap. 2, Vol . 2, eds. K. R. Kase,

B. Bjarngard, F. H. Attix, Academic Press, New York (in press).

Domen, S. R., Convection Currents in a Water Calorimeter, Letter, Phys.

Med . Bi ol . (in press)

.

Domen, S. R. and McDonald, J. C., A-150 Plastic Radiometric Calorimeter

for Charged Particle and Other Radiations, Nuc. Inst. Meth. (in press).

Dooley, M. A., Goodman, L. J., Zeman, G. H., Schwartz, R. B., and

Eisenhauer, C. M. , NBS-AFRRI Ionization Chamber Intercomparison in Mixed

Neutron and Gamma-Ray Radiation Fields, Report of the Armed Forces

Radiobiology Research Institute, Bethesda, MD (in press).

239
Division 536, Publications in Preparation (cont'd.)

Duvall, K. C., Wasson, 0. A., and Johnson, R. G., Characteristics of the

Dual Thin Scintillator in the Sum Coincidence Mode (in preparati on)

.

Ehrlich, M., The Fricke Dosimetry Service of the NBS SP 250-4 (in press).

Ehrlich, M., Pruitt, J. S., and Soares, C.G., Calibration of Beta-Particle

Radiation Protection Instrumentation at the NBS, SP 250-19 (in

preparati on)

.

Eisenhauer, C. and Grundl , J., First Evaluation of ISNF Spectra Based on Interlaboratory Computation, LWR PV Progress Report, NUREG/CR (in press).

Fiorito, R. B., Raleigh, M., and Seltzer, S. M., Current Density Monitor

for Intense Relativistic Electron Beams, (in press)

Grau Malonda, A., and Coursey, B. M., Calculation of Beta-Particle Counting Efficiencies for Liquid Scintillation Systems with Three Phototubes

(in preparation).

Grau Malonda, A. and Coursey, B. M., The Standardization of Techneti um-99m

by Liquid Scintillation Efficiency Tracing (in preparati on)

.

Grundl, J. A., Procedure for Derivation of Neutron Exposure Parameters

from Integral Detector Data, Sixth ASTM-EURATOM Symposium on Reactor

Dosimetry (in preparation)

.

Hoppes, D. D., Coursey, B. M., Schima, F. J., and Yang Dongliang, NBS

Decay Scheme Measurements of Stronti um-82-Rubid i um-82 (in preparation)

.

Hubbell, J. H., Gerstenberg, H. M., and Sal Oman, E. B., Bibliography of

Photon Total Cross Section (Attenuation Coefficient) Measurements 10 eV to

13.4 GeV, NBSIR (in press).

Hutchinson, J.M.R., Alpha-Particle Calibrations at NBS (to be submitted as

an NBS Special Publication).

Hutchinson, J.M.R., Inn, K. G.W., Parks, J. E., Beekman, D. W., Spaar,

M. T., and Fairbank, W. M., Investigation of Matrix Effects and Isotope

Dilution in SIRIS Measurements in Soils (submitted to Nuclear Instruments

and Methods).

Hutchinson, J.M.R., and Ballaux, C., Measurement of Gamma-Ray Emission

Rate of 109 Cd with a Well-Type Nal(Tl) Detector, Int. J. Appl . Radiat.

Isotopes (in press).

Inn, Kenneth G.W., The National Bureau of Standards Natural -matri

x

Envi ronmental -1 evel Radioactivity Standard Reference Materials (in

preparati on)

.

240
Division 536, Publications in Preparation (cont'd.)

Johnson, R. G., Detectors for Neutron Scattering in the eV Region (in

preparation)

.

Johnson, R. G., Mul ti -Parti cl e Accelerator for Neutron and High-LET

Radiation Research, Proceedings of the IAEA Advisory Group Meeting on Neutron Source Properties, June 9-13, 1986, Leningrad, USSR (in press).

Jovanovic, S., A1 -Shei khl y , M., and Simic, M., Adenyl and Guanyl Radicals

Do Not React with Oxygen.

Karam, L. R., Dizdaroglu, M. and Simic, M. G., Intramolecular Hydrogen

Abstraction by Thymine Radicals from the Sugar Moiety in Thymine Oligoand Polynucleotides, Radiat. Res. (in preparation).

Kronenberg, S., McLaughlin, W. L. and Siebentritt, C. Radiological

Instrument, U.S. Patent Serial No. 06778,120, Filing Date September 20,

1985.

Lamaze, G. P. and Gilliam, D. M., The Use of Prompt Gamma as a Fluence

Rate Monitor in Neutron Beam Experiments (in preparation).

Lamperti, P. J., Loftus, T. P., and Loevinger R., Calibration of X-ray

and Gamma-ray Measuring Instruments at the NBS, SP 250-17 (in

preparation)

.

Loevinger, R., Budinger, T. F., and Watson, E., MIRD Primer for Absorbed

Dose Calculations , The Society of Nuclear Medicine, New York (in press).

Lumbroso, P. and Dick, C. E., A systematic Study of the Efficacy of

Various Radiographic Contrast Media, (in publication).

McLaughlin, W. L. Radak, B. B., Silverman, J., Liu Zhan Jun, Miller, A.,

Rat sberg-Pedersen , W., and Charlesby, A., High-Density Polyethylene Film

Dosimetry by Infrared Spectrophotometry of Tran svi nyl ene Unsaturation (to

be submitted to Radiation Physics and Chemistry).

McLaughlin, W. L., Humphreys, J. C., and Chappas, W. J., Radiochromic

Transfer Dosimetry for Validation and Commissioning of Industrial

Radiation Processes (to be presented at and published in proceedings of

6th International Meeting on Radiation Processing).

McLaughlin, W. L. and Chappas, W. T., Cellulose Diacetate Film Dosimeters

(to be presented at and published in proceedings of 6th International

Meeting of Radiation Processing).

McLaughlin, W. L., Abdel Rehim, F. and Prei singer, T., Temperature

Dependence of Response of Radiochromic Film Dosimeters to Electron Beams

(to be submitted to Radiation Physics and Chemistry).

241
Division 536, Publications in Preparation (cont'd.)

McLaughlin, W. L., Abdel Rehim, F. and Prei singer, T., Effect of Vacuum

and Various Gases on the Response of Radiochromic Film Dosimeters to

Electron Beams (to be submitted to Radiation Physics and Chemistry).

McLaughlin, W. L. and Humphreys, J. C., Graphite Calorimetry for Calibration of 10-MeV Electron-Beam Absorbed Doses (to be submitted to NBS

Journal of Research)

.

McLaughlin, W. L., Dosimetry for Food Irradiators, Invited book chapter in

book entitled, Technology of Low Dose Irradiation of Foods (to be

publ i shed by Elsevier, London).

Nath, R., Anderson, L., Jones, D., Ling, C., Loevinger, R., Williamson,

J., and Hanson, W. , Specification of Brachytherapy Source Strength -- A

Report by Task Group 32 of the Radiation Therapy Committe of the AAPM,

American Institute of Physics (in preparation).

Pruitt, J. S., Calibration of Beta-Particle Ophthalmic Applicators at the

NBS, SP 250-15 (in preparation).

Radak, B. B., McLaughlin, W. L., Simic, M. G., and Warasawas, W., RealTime Dosimetry with Liquid Optical Waveguides (to be submitted to Int. J. Applied Radi at. Isotopes).

Radak, B. B., McLaughlin, W. L. and Simic, M. G., Liquid Core Optical

Waveguides Applied to Spectrophotometry (to be submitted to the Review of

Scientific Instruments).

Schrbder, Ivan, Gilliam, David M., Carlson, Allan D. , Bright, Sandra W.,

and Hutchinson, J. M. Robin, International 235 U Fission Foil Mass Intercomparison, Transactions of the American Nuclear Society (in press).

Seltzer, S. M., Conversion of Depth-Dose Distributions from Slab to

Spherical Geometries for Space-Shielding Applications, IEEE Transactions

on Nuclear Science (in press).

Seltzer, S. M. and Berger, M. J., Bremsstrahl ung Energy Spectra from

Electrons with Kinetic Energy 1 keV-10 GeV Incident on Screened Nuclei and

Orbital Electrons of Neutral Atoms with Z = 1 - 100, Atomic Data & Nucl

.

Data Tabl es (i n press)

.

Simic, M., and Hunter, E. P., Reactions Mechanisms of Peroxy and

C-centered Radicals with Sulfhydryls (submitted).

Simic, M., and Taylor, K., Free Radical Mechanisms of Meat Oxidation, in

Flavor Quality of Fresh Meat: Warmed-Over Flavor , eds. A. J. St-Angelo and

M. E. Bailey, Academic Press (1986).

242
Division 536, Publications in Preparation (cont'd.)

Soares, C. G., Bright, E. 1., and Ehrlich, M., Difficulties Encountered

with some High-Atomic-Number Personnel Dosimeters Irradiated On-Phantom

with Low-Energy Photons (in preparation).

Soares, C. G., and Pruitt, J. S., Status of Beta-Particle Calibration

Studies at NBS, Proceedings of the Beta Dosimetry Workshop, Department of

Energy, Albuquerque, NM, January 1986 (in press).

Warasawas, W., Al-Sheikhly, M., Radak, B. B., and McLaughlin, W. L.,

Optical Waveguide Dosimetry for Gamma Radiation in the Dose Range 10" 2 and

105 Gy (to be submitted to Nuclear Instruments and Methods).

Warasawas, W., and McLaughlin, W. L., High-Dose Dosimetry by Sublimation

of Crystalline Organic Compounds (to be submitted to Radiation Physics and

Chemi st ry )

.

Wasson, 0. A., Recent Fission Cross Section Standards, Proceedings of the

XVth International Symposium on Nuclear Physics-Nuclear Fission, Gaussig,

German Democratic Republic (in press).

Weaver, J. T., Loftus, T. P., and Loevinger, R., Calibration of Brachytherapy Sources at the National Bureau of Standards, NBSIR and NBSSP (in

preparation)

.

Williams, J., Cogburn, C., Hodgson, L., West, L., McGarry, E. D., Lamaze,

G. , Gilliam, D., Grundl , J., Coursey, B., Rogers, J. W., and Gherke, R.

,

Measurements of Fission Spectrum Averaged Cross Sections for the

93 Nb(n,n'

)

93 Nb Reaction (in preparation).

Williamson, T. G., Lamaze, G. P., and Gilliam, D. M., Calibration of a Neutron Driven Gamma Ray Source, (in preparation).

Williamson, T. G., Ayers, T. A., Hammersten, W. L., and Lamaze, G. P.,

Nb(n,n') Cross Section Measurement in a Fission Spectrum (in

preparati on)

.

Williamson, T. G., Lamaze, G. P., Gilliam, D. M., and Eisenhauer, C. M.,

Iron and Cadmium Capture Gamma Ray Photofission Measurement s , American

Nuclear Society Topical Conference on Theory and Practice in Radiation

Protection and Shielding.

243
TECHNICAL AND PROFESSIONAL COMMITTEE PARTICIPATION AND LEADERSHIP

Division 536, Ionizing Radiation

James W. Behrens

Member, Cross Section Evaluation Group Committee on Data Status Requests (CSEWG).

Chairman, Nuclear, Atomic, and Radiation Committee, Isotopes and

Radiation Division, American Nuclear Society.

Chairman, Transuranic Task Force, Isotopes and Radiation Division,

American Nuclear Society.

Chairman, Organizing Committee, Topical Conference on Fifty Years

With Nuclear Fission to be held at NBS April 26-28, 1989; cosponsors

are NBS and ANS, at present.

Martin J. Berger

Member, International Atomic Energy Agency Advisory Group on Nuclear

and Atomic Data for Radiotherapy and Radiobiology.

Chairman, International Commission on Radiation Units and

Measurements (ICRU), Committee on Stopping Power.

Member, National Council on Radiation Protection and Measurements

(NCRP) Committee #52 on Conceptual Basis on Dosimetry.

Member, NCRP Committee #55 on Experimental Verification of Internal

Dosimetry.

Member, Naval Research Advisory Committee, Naval Surface Weapons

Center Review Panel

.

Jacquel ine M. Cal houn

Member, National Measurements Laboratory Minority Advisory Panel.

EEO Counselor, NBS, two-year appointment, January 19, 1984 through

January 19, 1986.

Allan D. Carlson

Member, Cross Section Evaluation Working Group (CSEWG).

Member, Evaluation Committee of CSEWG.

244
Division 536, Technical and Professional Committee Participation and

Leadership (cont'd.)

Allan D. Carlson (cont'd.)

Chairman, Standards Subcommittee, CSEWG.

Member, Data Status and Requests Subcommittee of CSEWG.

Randall S. Caswell

Chairman, Science Panel, Committee on Interagency Radiation Research

and Policy Coordination (CIRRPC), Office of Science and Technology

Pol icy.

Alternate Member, CIRRPC, Office of Science and Technology Policy.

Member, Consultative Committee for Ionizing Radiations (CCEMRI),

Conference General e des Poids et Mesures, Paris, France.

Chairman, Section on Neutron Measurements (Section III), CCEMRI,

Conference Generale des Poids et Mesures, Paris, France.

Member, National Council on Radiation Protection and Measurements

(NCRP)

.

Member and Secretary, International Commission on Radiation Units and

Measurements (ICRU).

Sponsor, ICRU Report Committee on Stopping Power.

Sponsor, ICRU Report Committee on Absolute and Relative Dosimetry at

High Doses.

Sponsor, ICRU Report Committee on Material Equivalent and Tissue

Substitutes.

Sponsor, ICRU Report Committee on C

x

.

Sponsor, ICRU Report Committee on Characteri zation of Irradiation for

Materials Effect Studies.

Sponsor, ICRU Report Committtee on Clinical Dosimetry for Neutrons

(Physi cs)

.

Member, Radiation Research Accelerator Facility (RARAF) Scientific

Advisory Committee, Columbia University.

Member, Program Committee for the Sixth Symposium on Neutron

Dosimetry, Munich (Neuherberg) , October 12-16, 1986.

245
Division 536, Technical and Professional Committee Participation and

Leadership (cont'd.)

Randall S. Caswell (cont'd.)

Member, Organizing Committee, Second International Conference on Anticarcinogenesi s and Radiation Protection, March 3-12, 1587.

Ronald Col 1

e

Member, Science Subpanel on Radon Protection and Health Effects,

Committee on Interagency Radiation Research and Policy Coordination.

Member, Radon Working Group, Interagency Committee on Indoor Air

Qual ity

.

Chairman, International Standards Organization, Working Group on Expression of Measurement Uncertainties.

Bert M. Coursey

Member, International Committee for Radionuclide Metrology (ICRM)

Life Sciences Working Group.

Member, ANSI Committee N42.02 on Nuclear Instruments, Procedural

Standards for Calibration of Detectors for Radioactive Measurements.

J. Joseph Coyne

Member, CIRRPC Subcommittee on High LET Radiation.

Member, European Community Dosimetry Group (EURADOS) Committee 1: Tissue-Equivalent Proportional Counters as an Instrument for

Radiation Protection.

Member, EURADOS Committee 4: Computational Methods and Benchmark

Calculations in Radiation Protection.

Member, International Atomic Energy Agency Advisory Group on Nuclear

and Atomic Data for Radiotherapy and Radiobiology.

Charles E. Dick

Member, Technical Organizing Committee, International Conference on the Application of Accelerators in Research and Industry, Biannual

conference held in even numbered years at North Texas State

University, Denton, Texas.

246
Division 536, Technical and Professional Committee Participation and

Leadership (cont'd.)

Chari es M. Ei senhauer

Member, CIRRPC Science Panel.

Member, National Council on Radiation Protection and Measurements

(NCRP) Task Group on Atomic Bomb Survivor Dosimetry: SC-40 Biological

Aspects of Radiation Protection Criteria.

Member, ASTM Subcommittee E10.05 on Nuclear Radiation Metrology.

Member, NAS-NRC Advisory Committee on the Radiation Effects Research

Foundation Subcommittee: Panel on the Reassessment of A-Bomb

Dosimetry.

Member, ANS Standards Committee Working Group on Gamma-Ray

Attenuation Data.

Elmer H. Ei senhower

Alternate Representative, ANSI N44, Equipment and Materials for

Medical Radiation Applications.

Chairman, ANSI N43, Equipment for Non-Medical Radiation

Appl ications.

Chairman, Interagency Committee on Occupational Radiation Protection

Measurements.

Resource Person, Conference of Radiation Control Program Directors,

Committee on Radiation Measurements.

Department of Commerce Representative, Interagency Working Group on Occupational Exposure Guidance.

Member, ASTM Subcommittee E10.04 on Radiation Protection

Method ol ogy

.

Chairman, ASTM Task Group El 0 . 07 . 05 on Performance of Calibration

Laboratories for Radiation Dosimetry in Industrial Testing and

Processi ng

.

Member, ASTM Committee E10 on Nuclear Technology and Applications.

Member, Science Subpanel on Scientific Basis for Radiation Protection

Standards, Committee on Interagency Radiation Research and Policy

Coordination.

247
Division 536, Technical and Professional Committee Participation and

Leadership (cont'd.)

Elmer H. Ei senhauer (cont ! d.)

Member, Committee on Secondary Calibration Laboratories for Survey

Instruments, Health Physics Society.

Leon J. Goodman

Member, Report Committee on Clinical Dosimetry for Neutrons,

International Commission on Radiation Units and Measurements.

Consultant, Report Committee on Material Equivalents and Tissue

Substitutes, International Commission on Radiation Units and

Measurements.

. Consultant, American Association of Physicists in Medicine, Radiation

Therapy Committee Task Group No. 18, Fast Neutron Beam Dosimetry

Physics.

James A. Grundl

Member, Steering Committee for Developing ASTM Standards for Reactor

Dosimetry, NBS, March 1985.

Member, ASTM Subcommittee E10.05 on Nuclear Radiation Metrology.

Secretary, Steering Committee for Lady Godiva Display at the National

Atomic Museum.

H. Thompson Heaton, II

Alternate Representative, ANSI N43, Equipment for Non-Medical

Radiation Applications.

Member, ANSI N43-3, Subcommittee for Gamma Irradiators.

Member, ANSI N43-9, Subcommittee for Electron Microscopes.

Resource Person, Conference of Radiation Control Program Directors,

Committee on Radiation Measurements.

Dale D. Hoppes

Member, International Committee for Radionuclide Metrology (ICRM)

Alpha-, Beta, and Gamma-Ray Spectrometry Working Group.

Member, Atomic Industrial Forum (AIF)-NBS Standards Program

Committee.

248
Division 536, Technical and Professional Committee Participation and

Leadership (cont'd.)

Dale D. Hoppes (cont'd.)

Member, International Committee of Weights and Measures (BIPM),

Consultative Committee on Standards for Measuring Ionizing

Radiations, Subcommittee Section II: Radionuclide Measurements.

Member, ANSI Subcommittee N42.2 on Procedural Standards for

Calibration of detectors for Radioactive Materials.

John H. Hubbell

Chairman, General Radiation Protection Section, Health Physics

Society Standards Committee.

Chairman, American Nuclear Society (ANS) Radiation Protection and

Shielding Division, ANS-6 Ad Hoc Committee on SI Units,

Member, ANS Isotopes and Radiation Division Nuclear, Atomic, and

Radiation Data Committee; Organizer and Chairman of sponsored

sessions: "Atomic and Radiation Data and Applications," for November

1987 ANS Meeting.

Member, ANS Isotopes and Radiation Division Industrial Radiation

Measurement Applications Committee.

Executive Councilor, International Radiation Physics Society.

Secretary, X-ray Absorption Task Group, International Union of

Crystallography Commission on Crystal 1 ographi c Apparatus.

Member, Cross Section Evaluation Working Group (CSEWG) Subcommittee

on Shielding.

J. C. Humphreys

Secretary, ASTM E10.07 Subcommittee on Ionizing Radiation Dosimetry

and Radiation Effects on Materials and Devices.

Member, ASTM FI. 11 on Electronics Hardness Assurance and AAMI (Association for the Advancement of Medical Instrumentation) subcommittee

on radiation sterilization of medical devices and products.

J. M. Robin Hutchinson

Chairman, International Committee for Radionuclide Metrology (ICRM)

Subcommittee on Low-Level Techniques.

249
Division 536, Technical and Professional Committee Participation and

Leadership (cont'd.)

J. M. Robin Hutchinson (cont'd)

Member, American National Standards Institute (ANSI) Committee on Nuclear Instruments and Detectors.

Secretary, ANSI Subcommittee N42.2 on Procedural Standards for

Calibration of Detectors for Radioactivity Measurements.

Kenneth G.W. Inn

Member, ASTM Committee C26.05.01 Methods of Test, Test Methods,

Environmental Methods.

George P. Lamaze

Vice-Chairman and Acting Secretary, American Society for Testing

and Materials (ASTM), Subcommittee E10.05, Nuclear Radiation

Metrol ogy

.

Chairman, Membership Subcommittee, ASTM Committee E10, Nuclear

Technology and Applications.

Secretary, Planning Committees for the 6th ASTM-Euratom Symposium

on Reactor Dosimetry.

Robert Loevinger

Member, BIPM Consultative Committee for Standards for Measurement of

Ionizing Radiation, Section I, X- and Gamma-Rays and Electrons.

Member, Medical International Radiation Dose Committee, Society of

Nuclear Medicine.

Consultant, American Association of Physicists in Medicine (AAPM)

Radiation Therapy Committee.

Member, AAPM Radiation Therapy Committee Task Group 3, Accredited

Dosimetry Calibration Laboratories.

Member, AAPM Radiation Therapy Committee Task Group 32,

Brachytherapy

.

Wilfrid B. Mann

Consultant, International Commission on Radiation Units and

Measurements (ICRU).

250
Division 536, Technical and Professional Committee Participation and

Leadership (cont'd.)

Wilfrid B. Mann (cont'd)

Member, ANSI -INMM Work Group INMM 8.04 Calibration Technique for the

Calorimetric Assaying of Plutonium-Bearing Solids applied to

Nuclear Materials Control.

Honorary Council Member, National Council on Radiation Protection

and Measurements (NCRP).

Chairman, NCRP Committee 18A on Standards and Measurement of Radioactivity for Radiological Use.

Life Member, International Committee for Radionuclide Metrology.

Emmert D. McGa rry

Member, ASTM Committee E10; Subcommittee E10.05 on Nuclear Radiation

Metrol ogy

.

Chairman, Awards Committee of ASTM Subcommittee E10.05.

Member, Planning Committee for the 6th ASTM-Euratom Symposium on Reactor Dosimetry.

William L. McLaughlin

Chairman, International Commission on Radiation Units and

Measurements (ICRU), Committee on Absolute and Relative Dosimetry at

High Doses.

Technical Advisor, ICRU Committee on Chemical Dosimetry.

Member, American Nuclear Society (ANS), Subcommittee for Nuclear

Terminology and Units, ANS-9.

Chairman, ANS-9. 1 Subcommittee, Health Physics and Dosimetry.

Member, ASTM E10.07, Ionizing Radiation Dosimetry and Radiation

Effects on Materials and Electronic Devices.

Technical Advisor, Association for the Advancement of Medical

Instrumentation, Subcommittee on Radiation Sterilization of Medical

Devices, Task on Radiation Dosimetry.

Member, ANS 9.2, Subcommittee on Shielding of the Nuclear

Termi nol ogy

.

251
Division 536, Technical and Professional Committee Participation and

Leadership (cont'd.)

William L. McLaughlin (cont'd)

Technical Advisor, ISO WG-1, Nuclear Energy Terminology, Task on the

ISO TC/85, Committee on Nuclear Energy.

Technical Advisor, Council of Europe Parliamentary Assembly, Work

Group on Aerospace Physiology, Medicine, and Radiation Measurement.

Technical Advisor, Council of Europe Parliamentary Assembly, Work

Group on Space Biophysics.

Member, R & D Associates Committee on Irradiated Food Products.

Member, International Atomic Energy Agency, Advisory Group on High

Dose Measurement and Stand ardizatign for Radiation Processing.

Member, Association for Advancement of Medical Instrumentation, Working Group on Radiation Sterilization Dosimetry.

Technical Advisor, National Council on Radiation Protection and

Measurement, Scientific Committee 63, Radiation Exposure Control in a Nuclear Emergency.

Science and Technology Consultant, Committee on Interagency Radiation

Research and Policy Coordination (CIRRPC).

Member, Advisory Panel on Electron Beam Dosimetry for Industrial

Radiation Processing, International Atomic Energy Agency.

Member, Organizing Committee, International Workshop on Identification and Dosimetry of Irradiated Food, Federal Republic of Germany's

Office of Radiation and Environmental Health and Federal Health

Office, November 16-21, 1986.

Member, Industrial Panel on Status of Electron and Gamma-Ray

Dosimetry for Radiation Processing.

Member, Organizing and Program Committees, 6th International

Conference on Radiation Processing, Ottawa, Canada, May 31- June 5,

1987.

Robert C. Placious

Advisor to Center for NDE, Iowa State University, Ames Iowa.

252
Division 536, Technical and Professional Committee Participation and

Leadership (cont'd.)

Robert B. Schwartz

Member, International Standards Organization (ISO) Technical

Committee 85 (Nuclear Energy), Subcommittee 2 (Radiation Protection),

Working Group 2 (Reference Radiations).

Member, International Commission on Radiation Units and Measurements

(ICRU) Report Committee on Measurements of Dose Equivalent.

Stephen M. Seltzer

Member, International Commission on Radiation Units and Measurements

(ICRU), Committee on Stopping Power.

Michael P. Unterweger

Member, ASTM Committee D22 on Sampling and Analysis of Atmospheres.

Oren A. Wasson

Member, Department of Energy Nuclear Data Committee.

253
MAJOR CONSULTING AND ADVISORY SERVICES

Division 536, Ionizing Radiation

A. Carlson reviewed a neutron detector program for the DOE Small Business

Innovation Research Program.

R. Col 16, as part of an informal advisory task force, assisted the U.S.

Environmental Protection Agency in establishing a radon/radon progeny

measurement proficiency evaluation and quality assurance program.

R. Col 1 $ advised and assisted staff members in various NBS Divisions on the treatment and reporting of measurement uncertainties.

C. E. Dick consulted with Dr. M. J. Moran, Lawrence Livermore National

Laboratory, Livermore, CA on the use of low energy Van de. Graaff

Accelerators in the production of coherent transition and Smith Purcell

radi ation.

C. E. Dick consulted with Mr. H. E. Boesch, Harry Diamond Laboratory,

White Oak, MD on the use of electron beams for radiation hardness testing

of electronic components.

C. *E. Dick consulted with members of the Center for Chemical Physics, NBS

on the utilization of the pulsed electron Van de Graaff beam for experimental programs in pulsed radiolysis.

C. E. Dick consulted with B. Rich, L. Johnson, D. Martz, EG&G, Idaho Falls

National Engineering Laboratory (INEL), Idaho Falls, Idaho on calibration

of beta-ray spectrometers, survey instruments and extrapolation chambers.

C. E. Dick consulted with Dr. H. Mendlowitz and Dr. S. Glass, Howard

University, Washington, DC, on coherence effects in Cherenkov radiation.

S„ R. Domen consulted with G. K. Svensson of the Radiation Therapy

Department, the Harvard Medical School, who needed detailed advice on construction of a water calorimeter for measurement of absorbed dose.

E. H. Eisenhower performed an analysis for the Federal Emergency

Management Agency of a problem with sealed radiation sources that were leaking. His analysis helped to convince the supplier to replace all of

the procured sources.

E. H. Eisenhower responded to a request from the Nuclear Regulatory

Commission to evaluate proposed new regulations and suggest an improved

versi on.

254
Division 536, Major Consulting and Advisory Services (cont'd.)

D. M. Gilliam advised and assisted Babcock and Wilcox (B&W) in preparation

of high-level dosimeters for measurements in mixed gamma and neutron

radiation fields at commercial nuclear reactors. These measurements are being made for assessing the integrity of reactor pressure vessels and

understanding radiation shielding for reducing personnel exposure.

D. M. Gilliam and G. P. Lamaze carried out tightly scheduled tests on new neutron counters developed at Lawrence Livermore National Laboratory for

use in underground weapons tests at the Nevada test range.

D. M. Gilliam developed new exposure room neutron monitors for the Armed

Forces Radiobiological Research Institute reactor.

H. T. Heaton, II advised New York Power Authority on procedures for setting up a radiation calibration laboratory and on a method for calibrating

their el ectrometer.

H. T. Heaton, II consulted with Conam Inspection on appropriate methods

they could use to determine the field from their gamma source.

H. T. Heaton, II consulted with Commonwealth Edison on radiation instrument calibration and QA procedures.

H. T. Heaton, II advised Oak Ridge National Laboratory on procedures for

setting up a radiation calibration laboratory for photons.

J. C. Humphreys and W. L. McLaughlin advised the upper management of FMC

Corporation, San Jose, California, on the relative merits of radiation

processing of food products in order to help them decide whether FMC

should be heavily involved in this new industry.

K. G. W. Inn participated in meetings to evaluate the state-of-the-art

bioassay as a measure of radiation exposure with emphasis on time and

factors. He participated in the following meetings:

DOE Radiobioassay and Internal Dosimetry Workshop, Albuquerque, NM,

January 20-27, 1986.

Task group meetings of the Oak Ridge Associated Universities for the

National Cancer Institute, Albuquerque, NM, February 10-11, 1986;

Washington, DC, May 12-13, 1986; Oak Ridge, TN, April 8-10, 1986;

and Albuquerque, NM, September 15-18, 1986.

Track Etch Analysis evaluation meeting for the National Cancer

Institute, Brookhaven National Laboratory, NY, July 29-30, 1986.

255
Division 536, Major Consulting and Advisory Services (cont'd.)

P. J. Lamperti provided consultation to the Federal Emergency Measures

Agency; to the Department of the Army, Redstone Arsenal; and to E.G.&G.,

Idaho Falls; concerning selection of instruments and beam qualities for

various radiation studies and calibrations.

R. Loevinger served as consultant to the Dosimetry Section of the

International Atomic Energy Agency at a meeting of the Scientific

Committee of the Secondary Standard Dosimetry Laboratory Network, in

Vienna, Austria, May 12-16, 1986.

E. D. McGarry participated in the absolute power calibration of a special

non-proliferation core tested by Argonne National Laboratories at Uak

Ridge National Laboratory.

E. D. McGarry provided consultation and 235 U deposit calibration for

special Cadarache-bui It fission chambers used in the non-prol i ferati on core-power measurement.

E. D. McGarry provided consultation to Materials Engineering Branch of the

Nuclear Regulatory Commission regarding benchmarking of pressure vessel

surveillance dosimetry.

W. L. McLaughlin and J. C. Humphreys advised Travenol Laboratories, Round

Lake, Illinois, on specific performance characteri sti cs of various dosimetry systems and quality assurance procedures used by the company to

produce sterilized medical goods.

W. L. McLaughlin, Dr. George Hsieh, FMC Corp., Santa Clara, CA. With J.

C. Humphreys, assisted in briefing staff at FMC on radiation processing

technology and food irradiation processing.

W. L. McLaughlin, Dr. Dan Sloan, Dr. Marshall Cleland, IOTECH, Inc.,

Northglen, CO. Supplied temperature-dependence data for response of radiation processing dosimeters, namely radiochromic films, red Perspex, and

Fricke dosimeters.

W. L. McLaughlin, Alicia Jarboe, Food Safety Inspection Service, USDA.

Supplied food irradiation information and dosimetry procedures for

measurement quality assurances.

W. L. McLaughlin, Dr. Stan Stern, Naval Surface Center, White Oak, MD.

Provided wide-dose-range dosimetry systems and data, for emergency dose

mapping of personnel areas. Described NBS calibration and special dosimetry services.

256
Division 536, Major Consulting and Advisory Services (cont'd.)

W. L. McLaughlin, Dr. William Murray, National Electrical Manufacturers

Association. Detailed discussion of high resolution radiation imaging and

diagnostics systems and methods for precise measurement of output of radiation sources and for both diagnostic imaging and cancer therapy.

W. L. McLaughlin, Thomas Fisher, Radiation Sterilizers, Inc., Atlanta, GA.

Described detailed procedures for correcting high-dose dosimeter response

for temperature dependence, in order to improve on-line dosimetry accuracy

in radiation processing.

W. L. McLaughlin, Dr. Barry Fairand, Radiation Sterilizers, Inc.,

Westerville, OH. Provided a white paper on the energy dependence of

dosimeter response and an argument for the use of 60 Co calibration in

137 Cs irradiator applications, without the need for energy -dependence

correction factors.

W. L. McLaughlin, Dr. Louise Miles, Naval Surface Weapons Center, White

Oak, MD. Supplied thei r dosimetry group with calibrated opti-chromic

dosimeters and literature for use in fast retrieval of dose mapping data

in naval facilities.

W. L. McLaughlin, Dr. Scott Smith, North American Science Associates,

Northwood, OH. Provided them with radiochromic dye solutions for monitoring the irradiation of microbial samples, in order to devise a protocol in

the study of survival curves in microbiological studies.

W. L. McLaughlin, Dr. James Love, 3M Co., St. Paul, MN. Devised a means

for electron beam dosimetry in samples passing a very high speed under

extended low-energy (190 keV) electron beams.

W. L. McLaughlin, Dr. Michael Terpilak, Nuclear Lectern Associates,

Columbia, MD. Devised a means for standardizing the irradiation of alkali

halide powder samples to high doses of gamma radiation.

W. L. McLaughlin, Dr. Clement Bourgault, Insul-Tab, Inc. Determined

response characteristics of dyed cellulose diacetate film dosimeters for

very high doses of low-energy electron beams.

W. L. McLaughlin, Dr. Elaine Boudos, IRT Corp., San Diego, CA. Supplied

temperature dependence data and test procedures for radiochromic film

dosimeters, for use in linac electron beams, for applications in doping of

semi-conductors and lithography.

W. L. McLaughlin, Dr. Vincent Lasko, Johnson and Johnson, Co., East

Wind son, NJ. Devised a means of 3-dimension dose mapping in wide webbings

irradiated on a belt conveyor using 0.8 MeV electron beams.

257
Division 536, Major Consulting and Advisory Services (cont'd.)

W. L. McLaughlin, Dr. Becky M. Eubank and M. G. Arudi, 3M Co., Memory

Technologies Group, St. Paul, MN. Devised a means of continuous, telemetering monitoring of the irradiation processing of wide video and audio

tape by low-energy electron beams which resulted in the development of a new film type.

W. L. McLaughlin, Janet New, Datascope Corp., Oakland, NJ. Provided

literature and dosimetry methods for sterility control in sterilization of

medical devices by ionizing radiation.

W. L. McLaughlin, Dr. Joseph Rothleder, California Department of Food and

Agriculture, Sacramento, CA. Supplied a detailed protocol for calibration

of food irradiation dosimeters, as a standard test procedure in the regulation of food irradiation plants in California.

W. L. McLaughlin, Ellen Holman, INDA, Association of Navel Fabrics

Industry, Washington, DC. Provided detailed information on the use of

standardized dosimetry as means of quality control in the radiation

processing of textiles.

W. L. McLaughlin, Doris Boesch, ALZA Corp., Palo Alto, CA. Detailed

discussions of environmental effects and correction factors for improving

the accuracy of chemical dosimeters used in radiation processing.

W. L. McLaughlin, Dr. Arnold Fero, Westinghouse Corp., Pittsburg, PA.

Supplied calibrated LiF chip dosimeters and response data for determining

large doses and dose mapping data around spent-nuclear fuel elements.

W. L. McLaughlin, Dr. Michael Fogerty, Medical Sterilization, Inc.,

Syosset, NY. Provided consultation on the response of dye dosimeters and

their proper use in electron beam sterilization of medical devices.

W. L. McLaughlin, Dr. George Lotze, National Institutes of Health. Gave

invited lecture and consultation on food irradiation technology and

methods of measurement quality assurance.

W. L. McLaughlin, Dr. Mel Dollar and Dr. Pai san Loarianie, Food

Irradiation Section, IAEA, Vienna. Devised a protocol for standard i zi ng

the radiation processing of a variety of food stuff requiring different

dose levels and irradiation procedures.

W. L. McLaughlin, Dr. S. V. Nablo, Energy Sciences, Inc., Woburn, MA.

Devised a method for correcting for temperature effects in thin-fi lm

dosimeters irradiated at very high dose rates with low energy electrons in

inert gases and in vacuum.

258
Division 536, Major Consulting and Pdvisory Services (cont'd.)

W. L. McLaughlin, Dr. Thomas Keim, General Electric Research & Development

Center, Schenectady, NY. Consultation on methods of radiation processing

with electron beams, and measurement techniques to achieve quality

control

.

W. L. McLaughlin, Dr. Marge Bruce, Wyle Laboratories, Huntsville, AL.

Provided dosimetry methods and materials for electron beam depth-dose

studies and quality control.

W. L. McLaughlin, Dr. R. D. Weir, Boeing Aerospace Company, Seattle, WA.

Devised method for standardizing the response of optical -qual ity lithium

fluoride specimens to high doses of gamma rays and electric beams.

W. L. McLaughlin, Dr. Michael Saylor, Isomedix, Inc., Parsippany, NJ.

Consultation on dosimetry methods for measurement of absorbed dose at

interfaces of different materials.

W. L. McLaughlin, Dr. Marcia Bova, I IT Corp., Knoxville, TN. Described

details of method of measurement of absorbed dose by electrochemical

methods and selective ion complexing using fluoride ferric ion aqueous

solutions.

W. L. McLaughlin, Dr. James Asbrock, Hughes Aircraft Corp., San Diego, CA.

Devised a method for mapping and calibrating their large 60 Co gamma-ray

source.

W. L. McLaughlin, Dr. Roy Modjewski, PPG Industries, Oak Creek, WI.

Devised dosimetry methods for measurement of very high doses of low-energy

electrons (200 keV), and dose-rate dependence studies.

W. L. McLaughlin, Dr. K. Mizasawa, Nissen High Voltage Co., New York, NY.

Consultation on NBS method for measurement of absorbed dose distribution

in electron-beam irradiated high voltage wires and cables, using thin

radiochromic films.

W. L. McLaughlin, Dr. Alejanda Jaidar and Prof. A. de la Piedad,

Department of Physics, University of Mexico. Provided information on electron spin resonance of amino acids and radiation- sensitive dyes for

electron beam dosimetry.

W. L. McLaughlin, Dr. Kenneth Hannah, Columbia Research Corp.,

Gai thersburg , MD. Supplied details of radiochromic and cellophane film

response characteristics, as a means of mapping three-dimensional dose

distributions in polymers irradiated by 3-MeV electrons.

W. L. McLaughlin, Dr. Thomas Legbandt, Barcel Corporation, Anaheim, CA.

Devised a method for measuring depth-dose and iso-dose contours in

electron-beam irradiated wire and cable.

259
Division 536, Major Consulting and Advisory Services (cont'd.)

W. L. McLaughlin, Ruth Garcia, Harry Schaeffer, Converters, American

Hospital Supply Corp., El Paso, TX. Supplied details of temperature

dependence and humidity dependence of radiochromic film response.

W. L„ McLaughlin, Dr. Robert Davis, South Atlantic Area Stored -Product

Insects R&D Lab, USDA. Consultation on dosimetry methods for achieving

measurement quality assurance in the radiation disinfestation of grain.

W. L. McLaughlin, Dr. G. M. Meaburn, National Marine Fisheries Service,

Charleston, SC. Supplied literature and detailed dosimetry information

for food irradiation technology and engineering.

W. L. McLaughlin, Linda Edwards, Chemical Manufacturers Association,

Washington, DC. Conducted radio interview on NBS research activities in

food irradiation and the development of post-i rradiation dosimetry

method s.

W. L. McLaughlin, Laura Beck, E-Beam Services, Cranbery, NJ. Provided

detailed information on the temperature dependence, humidity effects, and

dose-rate effects between electron beam and gamma-ray response of radiochromic dosimeters, as compared with other working dosimeters in radiation

processi ng

.

W. L. McLaughlin, Prof. Ralph S. Becker, University of Houston, Houston,

TX. Supplied literature and dosimeter materials for chemical dosimetry at

high radiation doses.

W. L. McLaughlin, Singer Company, Librascope Division, Glendale, CA.

Devised method for irradiation of LiF and LiB4 0

7 over very wide dose and

dose-rate ranges.

W. L. McLaughlin, Dr. George L. Tingey, Battel le Northwest, Hamford , WA.

Consultation on dosimetry methods for quality control in food irradiation

at commercial and pilot plants.

W. L. McLaughlin, Dr. James Forsell, Northern California Transplant Bank,

San Francisco, CA. Consultation on the use of standardized dosimetry for

sterility control and validation in radiation sterilization of surgical

equipment and prosthetic devices.

W. L. McLaughlin, David Stern, Radiation Technology, Inc., Whippany, NJ.

Supplied details of several types of chemical dosimeters and how they are

used successfully over broad ranges of absorbed dose.

W. L. McLaughlin, Dr. J. Barber, Childrens Hospital, Washington, DC.

Assisted in the planning of a transplant experiment, where pharangea!

tissue is irradiated prior to implanting.

260
Division 536, Major Consulting and Advisory Services (cont'd.)

W. L. McLaughlin, Prof. Brian Methe, Rensselear Polytechnical Institute,

Troy, NY. Devised means for accurate irradiation of thermoluminescent

alkali halide powders to absorbed doses over wide ranges of doses and dose

rates.

W. L. McLaughlin, Dr. Todd Hess, Mead Imaging, Inc., Miami sburg, OH.

Assisted the development of a radiation monitor for quality control in

industrial radiation curing plants.

W. L. McLaughlin, Dr. Jeffrey Beck, Ethican, Inc., Sommerville, NJ.

Provided temperature dependence data and consultation in order to correct

response of dosimeters used under extreme environmental conditions in the

radiation sterilization of prosthetic devices and surgical sutures.

W. L. McLaughlin, Dr. Lois Jones, Becton-Di cki n son Co., Research Triangle

Park, NC. Consultation on the design and equipment needs for setting up a central dosimetry laboratory for the company.

W. L. McLaughlin, Acme United Corporation, Fairfield, CN. Consultation on the performance and methods of preparation of aqueous chemical dosimeters

(e.g. ferrous-cupric) for standardizing the radiation sterilization of

medical gauze products.

W. L. McLaughlin, Dr. Brian Ives, Sion International, Inc., Richland, WA.

Provided data and protocols for measurement quality assurance in pilotscale and production level food irradiation.

W. L. McLaughlin, Dr. Steven Smith, Kendal 1 -McGaa , Irvine, CA. Assisted

in setting up dosimetry and dose mapping procedures for assessing quality

control in heterogeneous plastic products irradiated by 12 MeV electron

beams.

W. L. McLaughlin, Dr. William Fitzgerald, Travenol Laboratories, Round

Lake, IL. Consultation on traceable dosimetry methods to achieve quality

assurance in the radiation sterilization of medical devices.

R. B. Schwartz provided consultation and advice to members of the faculty

of the U.S. Naval Academy on setting up a tissue-equivalent proportional

counter system.

R. B. Schwartz tested and calibrated proton recoil counters for Dr.

Chartier of the Centre d' Etudes Nucleaires, Fontenay-Aux-Roses, France.

R. B. Schwartz provided calibration and quality control irradiations for

the Naval Surface Weapons Center area monitors.

R. B. Schwartz provided advice to Dr. Joseph Shonka of Atlan-Tech, Inc.,

on setting up a D

2 0-moderated Cf source for doing quality assurance

measurements on dosimetry for nuclear power plants.

261
Division 536, Major Consulting and Advisory Services (cont'd.)

R. B. Schwartz provided consultation and neutron beam irradiation to

Battel le Pacific Northwest Laboratory for developing a remmeter based on a tissue equivalent proportional counter.

R. B. Schwartz provided consultation and neutron irradiation service for

Prof. Robert Apfel of Yale University to assist in the development of a novel type of neutron personnel dosimeter.

R. B. Schwartz participated in a neutron dosimetry intercomparison with

Battel le Pacific Northwest Laboratory and Lawrence Livermore National

Laboratory.

Stephen M. Seltzer provided consultation and collaboration on electron

transport techniques with members of the Spanish Junta de Energia Nuclear

in support of a joint effort between NBS and Spain to develop general and

accurate methods for the measurement of radioactivity of a radionuclide in

a scintillating liquid.

Stephen M. Seltzer provided consultation to the National Physical

Laboratory (England) on calculations of energy spectra and transmission

curves of high-energy photon beams from the NPL Linac used for x-ray beam

cal cul ations.

Stephen M. Seltzer advised staff members at British Aerospace (England)

and Alcatel Espace (France) on space-shielding calculations.

Stephen M. Seltzer provided electron and positron stopping powers, ranges

and radiation yields to the Physi kal i sch-Techni sche Bundesanstal t (Germany) for use in PTB's beta-source calibrations.

Stephen M. Seltzer provided consultation on Monte Carlo modeling for

electron/photon transport calculations to staff members of Los Alamos

National Laboratory, Naval Surface Weapons Laboratory, and Sandia National

Laboratories.

Stephen M. Seltzer provided consultation on x-ray fluorescence calculations to staff at NASA's Goddard Space Flight Center.

262
JOURNAL EDITORSHIPS

Division 536, Ionizing Radiation

B. M. Coursey, Editor, International Journal of Radiation Applications and

Instrumentation, Part A. Applied Radiation and Isotopes.

B. M. Coursey, Editor, International Journal of Radiation Applications and

Instrumentation, Part B. Nuclear Medicine and Biology.

W. B. Mann, Editor-in-Chief for North America, International Journal of

Radiation Applications and Instrumentation, Part A. Applied Radiation and

I sotopes.

W. B. Mann, Editor-in-Chief for North America International Journal of

Radiation Applications and Instrumentation, Part B. Nuclear Medicine and

Biol ogy.

W. L. McLaughlin, Editor, International Journal of Applied Radiation and

Isotopes.

W. L. McLaughlin, Editor, International Journal of Radiation Applications

and Instrumentation, Part A. Applied Radiation and Isotopes.

W. L. McLaughlin, Editor, International Journal of Radiation Applications

and Instrumentation, Part C. Radiation Physics and Chemistry.

W. L. McLaughlin, Editoral Board, Radiation Physics and Chemistry.

J. W. Motz, Editor, Computerized Radiology.

M. G. Simic, International Editorial Board, Free Radicals in Biology and

Medici ne.

263
TRIPS SPONSORED BY OTHERS

Division 536, Ionizing Radiation

Berger, M. J., sponsored by the International Atomic Energy Agencytraveled to Rijswijk, The Netherlands to participate in an Advisory Group

Meeting on Nuclear and Atomic Data for Radiotherapy and Radiobiology

(September 16-20, 1985).

R. S. Caswell, sponsored by Columbia University, traveled to Irvington,

New York to attend meeting of the Scientific Advisory Committee to the

Radiological Research Accelerator Facility (RARAF) (January 27, 1986).

R. S. Caswell, sponsored by the International Atomic Energy Agency

traveled to Dubrovnik, Yugoslavia to attend International Conference on Fast Neutron Physics and present invited paper (May 25-June 1, 1986).

R. S. Caswell, sponsored by the Kernforschungsanl age Juelich GMBH,

traveled to the Institut fur Medizin, Julich, West Germany to present an invited lecture (June 2-4, 1986).

R. S. Caswell, sponsored by the Commission of European Communities,

traveled to the Bureau Central de Mesures Nucleaires, Geel , Belgium, to

present an invited lecture (June 11, 1986).

R. S. Caswell, sponsored by the International Commission on Radiation

Units and Measurements, traveled to Bad Honnef, West Germany to attend the

annual meeting (September 5-13, 1986).

B. M. Coursey gave an invited talk at Beckman Instruments, Fullerton,

California, with the host organization covering all expenses (April 17,

1986).

B. M. Coursey attended the Editorial Board Meeting of the International

Journal of Applied Radiation Isotopes, Oxford, England. Air travel and

living expenses were provided by Pergamon Press, Oxford, England (June

5-6, 1986).

B. M. Coursey visited NEN Products/Dupont at the request of USFDA and

DuPont in order to audit distribution of secondary standards of

201 T1 radiopharmaceuticals as part of a measurements assurance exercise,

N. Billerica, Massachusetts. Expenses were covered by DuPont (July

27-28, 1986).

J. J. Coyne, sponsored by the International Atomic Energy Agency, traveled

to Rijswijk, The Netherlands to participate in an Advisory Group Meeting

on Nuclear and Atomic Data for Radiotherapy and Radiobiology (September

16-20, 1985).

264
Division 536, Trips Sponsored by Others (cont'd.)

, sponsored by Lawrence Berkeley Laboratory, Berkeley, CA,

ted talks and discussed recent developments in the field of

radiation chemistry of DNA at Berkeley (July 1986).

M. Dizdaroglu, sponsored

gave two invi

D. D. Hoppes lectured and held laboratory discussions in the Peoples

Republic of China at the Institute of Atomic Energy, Shaanxi Provincial

Research Institute for Preventive Medicine, Sichuan University, and the

National Institute of Metrology. The host organizations covered all

living expenses (October 1985).

J. H. Hubbell traveled to Zagreb, Yugoslavia to present invited talk,

"Radiation Physics Programs at the NBS," at the Rudjer Boskovic Institute.

Subsistence expenses were provided by the Institute (October 10, 1985).

J. M. R. Hutchinson traveled to Rio de Janeiro to work with the Instituto

de Radioprotecao E Dosimetria on a joint project for measuring low-level

environmental materials using direct gamma-ray counting and activation

analysis was covered by the host organization (September 15-0ctober 4,

1985)

.

K. G. W. Inn participated in meetings to evaluate the state-of-the-art of

bioassay as a measure of radiation exposure with emphasis on time and dose

factors. He participated in the following meetings with the Oak Ridge

Associated Universities covering all expenses:

DOE Radiobioassy and Internal Dosimetry Workshop, Albuquerque, NM

(January 20-22, 1986).

First task group meeting of the Oak Ridge Associated Universities for

the National Cancer Institute, Albuquerque, NM (February 10-11, 1986).

Task group meeting for the National Cancer Institute, Oak Ridge

Associated Universities Facilities, Oak Ridge, TN (April 8-10, 1986).

Trach Etch Analyser evaluation meeting for the National Cancer

Institute, Brookhaven National Laboratory, NY (July 29-30, 1986).

Task group meeting for the National Cancer Institute, Albuquerque,

NM (September 15-18, 1986).

R. G. Johnson, sponsored by the International Atomic Energy Agency,

traveled to Leningrad, USSR to present an invited paper and to participate

in an Advisory Group Meeting on Neutron Source Properties (June 9-13,

1986)

.

R. G. Johnson, sponsored by Rutherford Appleton Laboratory, traveled to

Didcot, UK to give a talk, "Detectors for Neutron Scattering in the eV

Region (June 18, 1986).

265
Division 536, Trips Sponsored by Others (cont'd.)

L. Karam, fellowship sponsored by the Imperial Cancer Research Fund,

London, UK. (June-Sept. 1986).

R. Loevinger traveled to Vienna, Austria to serve as consultant to the

Dosimetry Group of the International Atomic Energy Agency at a meeting of

the Scientific Committee of the Secondary Standard Dosimetry Laboratory

Network. The trip was paid for by the IAEA (May 12-16, 1986).

W. L. McLaughlin, sponsored by FMC Corp., Santa Clara, CA, to give an invited talk on food irradiation technology to the staff of FMC Corp.

(September 1985).

W. L. McLaughlin, sponsored by IAEA to conduct an international dosimetry

and calorimetry intercomparison at Ri so National Laboratory, Denmark,

Harwell, UK, and National Physical Laboratory, Teddington, UK (October

1985)

.

W. L. McLaughlin, sponsored by IOTECH, Inc. to perform commissioning and

QA dosimetry in a new radiation sterilization plant in Northglen, CO.

(October 1985).

W. L. McLaughlin, sponsored by IAEA to attend advisory panel meeting at

the IAEA, Vienna, Austria (February 1986).

W. L. McLaughlin, sponsored by IAEA to conduct dosimetry training food

irradiation technology at the Office of Atomic Energy for Peace, Bangkok,

Thailand ( February-March 1986).

W. L. McLaughlin, sponsored by IAEA to give an invited lecture on dosimetry for food processing by ionizing radiation at Food Irradiation

Section, IAEA, Vienna (March 1986).

W. L. McLaughlin, sponsored by AERE, Harwell, to conduct international

dosimetry intercomparison and give lecture on telemetering dosimetry (May

1986)

.

W. L. McLaughlin, sponsored by Pergamon Press Publishers, to attend

Editorial Meetings at Oxford, England (June 1986).

R. B. Schwartz, sponsored by the International Commission on Radiation

Units and Measurements (ICRU), traveled to Paris, France, to attend first

meeting of ICRU Report Committee on Measurement of Dose Equivalent

(September 15-16, 1986).

S. M. Seltzer organized and chaired two invited/contributed sessions,

."Charged-Particle Transport Calculations: Methods and Applications, I and

II," at the Annual Meeting of the American Nuclear Society, Reno, Nevada

(June 15-20, 1986).

266
Division 536, Trips Sponsored by Others (cont'd.)

M. G. Simic, sponsored by the University of Texas, Austin, TX, gave talk

"The Chemistry of Irradiated Foods" (February 21 , 1986).

M. G. Simic, sponsored by the Swiss Institute for Experimental Cancer

Research, Lausanne, Switzerland, gave a talk, "Mechanisms of Free Radical

Damage to DNA and Chemical Repair" (March 3, 1986).

M. G. Simic, sponsored by the World Health Organization, Lyon Cedex,

France, "Mechanisms of Free Radical DNA Damage Implications for Risk

Assessment" (March 4, 1986).

M. G. Simic, sponsored by Max Planck Institut fur Strahl enchemi e , MUlheim,

West Germany, gave talk, "Reduced Reactivity of Resonance Stabilized Free

Radicals Towards Oxygen (March 7, 1986).

M. G. Simic, sponsored by New York University Medical Center, New York,

NY, gave a talk, "Mechanisms of Radiation Damage to DNA and Risk

Assessment" (March 12, 1986).

M. G. Simic, sponsored by The University of Akron, Akron, OH, gave a talk,

"Antioxidants" (April 1, 1986).

M. G. Simic, sponsored by Ruder Boskovic Institute, Zagreb, Yugoslavia,

gave a talk, "Mechanisms of DNA Damage and Repair" (June 2, 1986)

M. G. Simic, sponsored by Institut fur Strahl enhygi ene , Oga, Neuherberg,

Germany, gave a talk, "Possible Approaches in Post-Irradi ation Dosimetry

of Meats" (June 3, 1986).

M. G. Simic, sponsored by Belgrade University, Belgrade, Yugoslavia, gave

a talk, "Mechanisms of Autoxidation and Antioxidant s" (June 11, 1986).

M. G. Simic, sponsored by Case Western University, gave a talk, "Discrimination Between Direct and Indirect Effects of Radiation (August 8, 1986)

0. A. Wasson, sponsored by the Technical University of Dresden, traveled

to Gaussig, German Democratic Republic to present an invited paper and

deliver a conference summary at the XVth International Symposium on Nuclear Physics-Nucl ear Fission (November 11-15, 1985).

267
STANDARD REFERENCE MATERIALS

Division 536, Ionizing Radiation

Radioactivity Group Standards Issued - 1 August 1985 through 31 July 1986

SRM Radi onucl ide Principal Use

44171-E Indi um-111 Calibration of instruments

for activity measurements

of radiopharmaceuticals

4410H-K Technetium-99m II

4423L Stronti um-90-Yttri um-90 II

4407J Iodi ne-125 II

4401L-L Iodi ne-131 II

4412L-K Molybdenum-99 II

4415L-J Xenon-133 II

4416-G Gal 1 ium-67 II

4404L-I Thai 1 i um-201 II

4400L-H Chromi um-51

II

4940C Promethium-147 solution For use i n cal ibrati ng

instruments for measurement

of this nuclide in reactor

waste samples

4928C Sulfur-35 solution in vitro nuclear medicine

4932F Mercury-203 solution calibration of Ge(Li) and

NaI(T£) gamma-ray detectors

4904G Americium-241 point source calibration of alpha-particle

detectors

4940 Plutonium-241 solution beta particle standard for

mixed plutonium assays

4267 Ni obi um-93m x-ray standard for neutron

dosimetry

4926C Hydrogen-3 solution calibration of liquidscintillation counters

4332B Americium-243 solution for calibration of alphaparticle aetectors for use in

nuclear fuel cycle assays

268
CALIBRATION SERVICES PERFORMED

Division 536, Ionizing Radiation

Neutron Dosimetry Group

No. of

Type of Service Customer SP 250 Tests

Certi fi ed Univ. of Arizona 8.1R 1 FI uence AFRRI 8.1R 6

Standards AFRRI 8.1Q 1

Total 8

Neutron Personnel Calvert Cliffs 8.1J 21

Protection Carolina P&L 8.1J 4

Instrumentation Univ. of Wisconsin 8.1H 3

Arkansas P&L 8.1J 2

U. S. Air Force 8.1J 1 Omaha Public Power 8.1J 1 U. S. Army 8.1J 12

Illinois Power 8.1J 4

WPPSS 8.1J 2

Barlett Nuclear Corp. 8.1J 1 Eberline Instr. Corp. 8.1J 2

Total 52

Neutron Source Naval Surface Weapons Lab 8.1A 1 Calibration Argonne Nat 1 1 Lab 8.1A 1 Alan Tech 8. IB 1 Univ. of Arkansas 8. IB

U.S. Air Force, Newark 8.1A 1

Total 5

^Covered under other agency contract

**Special 32-mg calibration,, performed by NBS in the field relative to a 5-mg source calibrated in 1985

269
Division 536, Calibration Services Performed (cont'd.)

II. Radioactivity Group

August 1, 1985 to August 1, 1986

Scheduled

Ca1ibrations ( l

) Non-scheduled Tests

Number Total Number

of Fee of

Sources $K Sources

Category

Alpha-Particle Sources 30 25.4 8

8.2 H, I, J

Beta-Particle Point Sources -- -- 6

and Gases ( 85 Kr)

8.2 P, Q, R

Gamma-ray Solutions, Point 5 4.1 39

Sources, and Gases ( 133 Xe)

Mixed Radionuclide Sources, -- -- 16

Solutions, Point sources

and Gases( *)

Other Services -- -- --

35 29.5 69

Footnote

(!) Multiple sources under one Test Folder are counted as multiple calibrations. Replicate samples are not considered as separate sources. For

example, Amersham submits 2 each of 3 different source forms. This is

counted as 3 samples.

270
Division 536, Calibration Services Performed (cont'd.)

III. X-Ray Physics Group

Customer Type of No. of No. of Tests

Cl assi fication Service Customers Performed

Industri al

:

A 26 155

medical product B 8 35

sterili zation C 1 1

Industri al

:

A 3 28

electronic hardness B 6 74

testi ng C 0 0

Industri al

:

A 7 43

polymer B 0 0

modification C 4 5

National Laboratory : A 0 0

electronic B 2 78

hardness testing C 0 0

Dept, of Defense: A 1 22

electronic B 0 0

hardness testing C 0 0

Secondary A 0 0

Cal ibration B 1 10

Laboratory C 0 0

University: A 1 4

research B 1 3

C 0 0

Subtotal

s

A 38 252

B 18 200

C _5 6

Grand Totals 61 458

Service Code Type of Service SP 250

A Irradiate Dosimeters 49010S

B

C

Supply Transfer Dosimeters

Special measurements

49020S

(8.6B

49050S

Number

(8.6A)

49030S

8.6C)

(8.6F)

271
Division 536, Calibration Services Performed (cont'd.)

IV. Dosimetry Group and X-Ray Physics Group

Customer SP 250 Number of

Type of Service Type* Item No, Tests

Calibration of x-ray 1-7 46010-50 266

and y-ray measuring

instruments, and

irradiation of TL

dosimeters

Calibration of y-ray 2-6 47010-40 24

and 3 -particle sources

Chemical dosimetry 2 48010-20 150

measurement assurance

service for electron

beam

High-dose irradiation 3-7 49010-50 408

and interpretation

Irradiat. of TLDs and Navy N.A. 281

prep, of units for

shipboard measurement

Instrument calibration 5 N.A. 30

and evaluation

Total

s

1160

*Column 2: 1, calibration labs; 2, hospitals; 3, nuclear energy establishments; 4, industry; 5, US government labs; 6, DoD labs;

7, universities.

272
SPONSORED SEMINARS AND COLLOQUIA

Division 536, Ionizing Radiation

John H. Barrett, National Physical Laboratory (NPL), Teddington, UK,

"Dosimetry by Means of Aqueous Potassium Dichromate Solutions," September

24, 1985.

J. E. Burns, NPL, Teddington, U.K., "High-energy Dosimetry Program of the

National Physical Laboratory", April 15, 1986.

Arne Miller, Ri s0 National Laboratory, Roskilde, Denmark, "Calorimetry

Standards for High Dose Radiation Measurements," November 21, 1985.

Z. P. Zagorski, Radiation Laboratory, University of Notre Dame, "Pulse

Radiolysis Studies of Solid Hydrates," November 22, 1985.

Katsuhisa Kudo, Electro-technical Laboratory, Ibaraki, Japan, "Neutron

Standards Measurements at the Electro-technical Laboratory," December 19,

1985.

S. T. Manson, Georgia State University, Atlanta, "Photoabsorption in the

Soft X-Ray Range: The State of Our Knowledge," January 16, 1986.

J. Kosanetzky, Philips Research Laboratory, Hamburg, West Germany, "X-Ray

Diffraction Computerized Tomography," January 31, 1986.

Marco Zaider, College of Physicians & Surgeons of Columbia University, New

York, NY, "Reconciliation of Track Structure and Radiation Chemistry,"

March 13, 1986.

M. Qui ntiliani, Instituto Tecnologie Biomediche, Italy, "Radiation

Chemistry of Glutathion," April 10, 1986.

Harry Ing, Chalk River Nuclear Labs, Ontario, Canada, "The Bubble-Damage

Polymer Detector - A New Tool for Radiation Detection," April 17, 1986.

Alex Sevanian, University of Southern California, Los Angeles, CA, "The

Cytotoxic and Mutagenic Properties of Cholesterol Oxidation Products,"

April 23, 1986.

Marc Desrosiers, Argonne National Laboratory, Argonne, IL, "Detection of

Transient Organic Radical Cations Produced in Pulse Radiolysis. TimeResolved Fluorescence Detected Magnetic Resonance," April 28, 1986.

K. H. Chadwick, Biology Division, European Economic Community, "Comparison

of Ultraviolet and Ionizing Radiation Effects on Mammalian Cell Survival,"

May 12, 1986.

273
Division 536, Sponsored Seminars and Colloquia (cont'd.)

Jeff Stephens, The James Franck Institute, The University of Chicago,

Chicago, IL, "Degradation of Slow Electrons in Molecular Gases," May 29,

1986 o

M. P. R. Waligorski, Institute of Nuclear Physics, Krakow, Poland,

"Particle Track Physics I. The Radial Distribution of Dose Around the

Path of a Heavy Ion," and Particle Track Physics II, "Neoplastic Cell

Transformation by Heavy Ions," June 25-26, 1986.

Jean Cadet, Centre d'Etudes Nucleairesde Grenoble, France, "Photo-and

Radiation Chemistry of Purine Nucleosides," July 1 , 1986.

Clemens von Sonntag, Max Planck Institut Fuer Strahzenchemie, West

Germany, "Sulfur Radical Reactions Related to Radiation Protectors," July

10, 1986.

Emmanuel Riklis, Nuclear Research Center, Negev, Israel, "Biochemical

Approach to Radiation Protection through DNA Repair," July 14, 1986.

Alex DeVolpi, Argonne National Laboratory, Argonne, IL, "AccidentalCoincidence Corrections," August 22, 1986.

D. J. Brenner, Columbia University School of Medicine, New York, "Nuclear

Models and Neutron Data for Light Elements," August 28, 1986.

Alfred Frank Fuciarelli, Cross Cancer Institute, Edmonton, Alberta,

Canada, "Detection and Modification of Radiation Damage in Nucleic

Acids," September 22, 1986.

Kri shan K. Sud , University of Jodhpur, Jodhpur, India, "Distorted-Wave

Born-Approximation Pair Production Calculations in the Intermediate Energy

Range," September 26, 1986.

274
TECHNICAL ACTIVITIES

Division 530.01 - Nuclear Physics

The Nuclear Physics Group conducts fundamental research in

theoretical nuclear and particle physics, and experimental studies of

intermediate energy electro- and photo-nuclear reactions. This activity is

in support of the Center's role in carrying out research necessary for

improved understanding of nuclear radiation processes and of the

interaction of radiation and particles with matter. Theory activities are carried out by M. Danos, L.C. Maximon, S. Meshkov, and J.S. O'Connell,

while experimental work is carried out by W.R. Dodge, E. Hayward, J.W.

Lightbody Jr., and X.K. Maruyama. The experimental effort is currently

focussed on experiments at the MIT/Bates and other laboratories, user activities and planning for CEBAF, as well as implementation of a beam

line to do nuclear physics with the cw microtron now under construction at

NBS by the Accelerator Research Group. Theoretical efforts include

studies of coincidence electron scattering processes. Coulomb distortion

and dispersive effects in electron scattering, neutrino reaction rates,

quark gluon plasmas and related phenomena, and the spectroscopy of

elementary particles using QCD. Approximately two-thirds of our theory

effort is related to intermediate energy nuclear physics, the balance in

high energy physics. This summary covers our activities during FY86.

The Nuclear Physics Group research program addresses priority

questions in nuclear theory and experiment and, therefore, requi res forefront facilities and a constant exchange of ideas and strong interplay

with other laboratories and researchers in the field. The group is

continuing with plans to develop a beam line for nuclear physics with the

200 MeV racetrack microtron (RTM). Research with this facility will be

conducted by our own group as well as by outside users. Experiments with

the linac have been phased out, except for calibration activities such as

a recent experiment to determine the response of a stacked

lead/scintillator total absorption counter to 50-100 MeV electrons. (This was done for a large external group involved in an approved Fermi lab

experiment.) In addition to planning a facility for electro-nuclear

coincidence experiments, the group is participating in forefront electroand photo-nuclear experiments using high energy accelerators at MIT and

Mainz, and is involved in planning the next generation electron

accelerator (CEBAF), aimed at exploring the QCD/nuclear physics interface.

Strong user involvement at other labs, including MIT/Bates, CEBAF, and

others, is considered an essential part of maintaining an active and

balanced research program.

The NBS research program profits greatly from the participation of

guest workers and collaborators (university faculty and graduate

students), who extend our resources and bring in new ideas. This year many

visitors and guest workers contributed to our programs. The list of

scientific colleagues who have had extensive visits to NBS include:

275
Division 530, Technical Activities (cont'd)

Everett Fuller, retired NBS Nuclear Physics Group employee; Miles McCord

from the Catholic University of America; Dennis Skopik from the University

of Saskatchewan, Canada; Bent Schroder from the University of Lund,

Sweden; Haaken Olsen from the University of Trondheim, Norway; Berndt

Muller, University of Frankfurt, West Germany; Johann Rafel ski , University

of Cape Town, South Africa; Ray Lewis (and co-workers) from Pennsylvania

State University; Jurgen Ahrens from the University of Mainz, West

Germany; Reiner Schneider from the University of New Hampshire and the

University of Mainz, West Germany; and Fred Gilman, SLAC. We encourage

these involvements and, additionally, have an extensive seminar program

which brings outside speakers to NBS.

In addition to guest worker scientists visiting NBS, a few members of

the Nuclear Physics Group have had extensive stays at other nuclear

laboratories: M, Danos , Centre d'Etudes Nucleaire de Saclay, France;

Institute for Theoretical Physics, University of Frankfurt, West Germany;

Institute of Theoretical Physics and Astrophysics, University of Cape

Town, South Africa; L. Maximon, Centre d'Etudes Nucleaire de Saclay,

France; J.S. O'Connell , Lewes Center for Physics (Lewes, DE); S. Me shkov , Aspen Center for Physics (Aspen, CO); Institute for Theoretical Physics of

the University of California at Santa Barbara; E. Hayward

,

Oxford

University Nuclear Physics Laboratory, England. These vi si ts provide

valuable new insights to our current research and often provide the

perspective to plan and direct our future research activities. In the

following sections we outline the groups primary research activities of

the past year. This list includes research planning and development for

the RTM, experimental activities at other laboratories, electromagnetic

nuclear physics theory, nuclear theory, elementary particle physics, and

miscellaneous activities.

Research Plans for the NBS/LANL RTM . The Nuclear Physics Group has

submitted a proposal to the DoE for 450K$ in supplemental funding with

which the necessary equipment for development of a nuclear physics beam

line could be designed, constructed, and installed. The proposal received

favorable reviews and recommendations for support, however, because of the

lack of uncommitted FY86 funds, it could not be funded at this time. The

proposal is currently being held by the DoE in an active status. We feel

that researchers outside of NBS will also be interested in this facility,

particularly while CEBAF is in its construction phase. We base this on the impressive efforts with modest energy cw electron facilities at the

University of Mainz (180 MeV), the University of Illinois (100 MeV), and

the University of Saskatchewan (300 MeV). The nuclear research groups at

these institutions enjoy high priorities at their respective funding

agencies for doing work which will now be addressable, in a cost effective

way, with the NBS/LANL microtron as well.

276
Division 530, Technical Activities (cont'd)

At the present time we are converting the electrodisintegration

spectrometer to an electron spectrometer. A new vacuum manifold has been

fabricated to allow proper positioning of a vertical drift chamber in the

focal plane. The VDC is presently under cnstruction at NBS. The printed

circuit board was designed and layed out with an in-house CAD system and

fabricated locally. Wires were put in and tensioned singly by hand.

Centering accuracy is roughly the PC board milling accuracy (25 microns,

non-accumul ative) plus an additional 50 microns for positioning the wires

within the centering holes. We have purchased amplifier/discriminator

cards and TDCs from LeCroy and are planning a delay-line readout patterned

after an Illinois design.

The spectrometer has a 5.6 msr solid angle and a 12 percent momentum

acceptance. This spectrometer is a double focussing type (n=l/2 and

beta=3/8), with a bend radius of 45.7 cm, a 120 degree bend angle, and

D/M=1.9 cm/percent. The magnet has pole edges which are curved to reduce

pole edge saturation effects and was designed to operate at central

momenta up to 215 MeV/c. A single solid state telescope and a single high

purity germanium detector are currently under development in-house for use

in detecting hadronic reaction products in coincidence with scattered

electrons. We expect that production experiments could best be done with

an array of solid state detectors. Our proposal to DoE provides for a scattering chamber which could house such an array and provide rotation

and gimbaling degrees of freedom.

We have reserved space for experiments not involving the magnetic

spectrometer, such as work with a high flux bremsstrahl ung beam. For such

work a 45 degree dump magnet will be available in the switchyard area. Given the very high current capabilities of the microtron, 550 ua at 185

MeV, we can contemplate low cross section bremsstrahl ung experiments, or polarization studies using off-axis bremsstrahl ung and very thin

radiators. A comparison of 2 H and 3 He photodisintegration, measuring

polarization asymmetry as well as the full 3-body break-up of 3 He could

provide an interesting test of our understanding of two-body processes in

nuclei. Proton scintillator telescopes and a neutron detector would have

to be developed for such an experiment to cover the full range of 3-body

kinematics. Recalling that the quality of polarization measurements scales

as the square of the polarization and linearly with intensity, with our higher beam intensity we are in a position to be competitive with

polarization studies based on photon tagger set-ups. At present there are

no plans for a photon tagging system such as at Illinois and Mainz,

although space for such a device could be made available.

A good example of possible research with the RTM recently came out of

Mainz. This work is in the area of giant resonances, in particular,

studies' of the E0, El, and E2 resonances in 28 <^ . Separated absorption

277
Division 530, Technical Activities (cont'd)

strength energy profiles have been obtained for the different multi poles

in the various possible decay channels. For the dipole resonance the

resultant integrated strength is consistent, within rather large

uncertainties, with either the Stei nwedel -Jensen or the Goldhaber-Tel 1 er model. Hopefully, with more effort one could reduce these uncertainties

to the point of discriminating between the various models, which in fact

have rather dramatic differences in transition charge and current

densities - SJ being more surface peaked, while GT is more of a bulk

nuclear motion effect. We would pursue similar studies when the microtron

comes on-line. As outlined in our proposal to the DoE, there are now detailed continuum shell model calculations for the giant E0, El, and E2

resonances in 16 0 with which to compare our data. The 12 C and 16 0 systems,

along with a heavier system for sake of comparison, would be the focus of our initial efforts with the microtron. We would extend the momentum

transfers slightly beyond the Mainz limit.

External Activities. In addition to operating the microtron for nuclear

research, however, we wish to continue our nuclear research activities

external to NBS. We feel that a healthy balance should exist between our internal and external activities because a microtron based program is

necessarily restricted in energy and in the type of physics we can address. We view such a facility as having a substantial window of

opportunity for interesting nuclear physics, but most certainly, when

CEBAF comes fully on-line, we will shift our emphasis to higher energy

experiments. Even at this time, most of the NBS Nuclear Physics Group is

engaged in activities at Bates and other major labs, and some are directly

acting in support of CEBAF. In order to give some perspective to the

extent of our external involvements it is appropriate at this point to

inject a summary of our current experimental activities outside NBS.

We recently prepared and successfully defended a proposal to study

the 3 He(gamma,2p) reaction using a cw bremsstrahl ung beam at the

Saskatchewan stretcher ring facility in Saskatoon. This work will be

carried out using the 10 ua beam expected late this year. If successful,

we could continue this work at NBS when the microtron beam becomes

available. The goal of the experiment is to look for evidence of

three-body effects in nuclear photodisintegration. Laget has estimated

that without three-body effects the (gamma, 2p) process should be down by

two orders of magnitude from the (gamma, pn) process. By selecting

kinematics that suppress the dominant one- and two-body dipole and

quadrupole breakup amplitudes, we hope to get an estimate of the magnitude

of three-body effects. We have chosen to look at kinematics where the

final neutron lab energy is essentially zero and the two protons emerge

opposed to each other near 90 degrees in the cm system. For these

278
Division 530, Technical Activities (cont'd)

kinematics there is no electric dipole moment in the final state; and,

since the initial state is an s-state, there can be no El absorption

strength. There is additionally no E2 absorption strength at 90 degrees,

except by virtue of finite detector size, nor is there any Ml absorption

strength by an s-state diproton system. Meson exchange effects are also

highly suppressed in the diproton system. By choosing energies below pion

threshold we have a kinematically complete experiment when the proton

energies and angles are measured, even when a bremsst rahl ung beam is used.

Our plan is to use two plastic scintillator DE-E telescopes for this

measurement, which should provide sufficient particle identification to

separate 2- body and 3-body breakup processes. We feel that the additional

use of polarized gammas from off-axis bremsstrahl ung may provide an extra

handle on the nature of any background processes related to the dominant

quasideuteron absorption process. Collaborating in this experiment with

the NBS group are researchers from the University of Saskatchewan, the

University of. Regina, and the University of Lund.

(J.W. Lightbody and J.S. O'Connell).

Recently, another area of investigation has arisen which has drawn

our attention, namely the search for axions. According to Pecci and Quinn,

fundamental CP invariance in strong interactions arises by coupling of

fermion fields to an assumed scalar or pseudoscalar field. Axions are the

quanta of this field, and the search for such particles is currently a very important and active area. Recently Tsai proposed that axion

bremsstrahl ung in electron scattering may be an important process in which

to search for evidence for these particles. Several members of our Nuclear Physics Group are examining the details for such an experiment

based on a cw electron beam, in which axion decay into an

el ectron-positron pair with a characteri Stic energy spectrum is the

signature. Maximal sensitivity appears to occur for electrons with

energies just below the threshold for neutral pion production, or about

130 MeV. A good emittance beam delivering 50 ua i s required, and the cw characteristic should allow clean detection of the el ectron-posi tron pair

in coincidence, possibly with a pair spectrometer. The key to this

experiment is to magnetically dump the beam immediately following the

target, and then provide sufficient absorber to contain the

electromagnetic shower and still allow the axion to escape before it

decays. Limits on the axion lifetime and coupling constant can therefore

be obtained. A proposal by members of the NBS group is being prepared in

collaboration with H. Olsen of the University of Trondheim, and will be

submitted to the appropriate facilities.

(W.R. Dodge, E. Hayward, and X.K. Maruyama)

In another recent development, members of our group are collaborating

with H. Weller and M. Whitton of Duke University in an experiment to

study the D-state in 4^e

. This experiment uses the beam of polarized

279
Division 530, Technical Activities (cont'd)

deuterons provided by the 88" Berkeley cyclotron. These particles are captured by the deuterons in a CD2 target and the ground-state capture

gamma rays are detected over an angular range extending from 45 to 135

degrees. NBS has provided one of the two detector systems used in this

experiment. This data are now being analyzed.

(W.R. Dodge and E. Hayward).

As we phased out our work on the NBS Electron linac, our work at the

MIT/Bates laboratory has increased greatly over the past several years.

The list of currently active experiments in which we are involved, or those in final stages of analysis include:

(1) 238 U(e,e'f) in the delta resonance region,

(2) 52 Cr(e,e') 180 degree scattering,

(3) 3 H, 3 He(e,e')

,

(4) (e,e'p) quasielastic studies using polarized electrons,

(5) (e,e'p) ,(e,e'alpha) giant resonance decay,

(6) (e,e'p) quasielastic studies of attenuation lengths,

(7) (e,e'p) quasielastic studies of current operators,

(8) transition radiation studies.

The 238 U(e,e'f) work is in collaboration with the University of Lund

and University of New Hampshire nuclear physics groups. Preliminary data

have been taken. When the fission data are integrated to give the partial

contribution to the inclusive results we obtain a rather flat spectrum in

energy loss. This is in contrast to the result expected on the basis of

arguments that all knockout and delta processes at this energy loss should

lead to fission. Apparently in the quasielastic scattering process at

this momentum transfer there is insufficient residual interaction to

induce fission. However, in the delta region we appear to arrive at the

full inclusive cross section, consistent with the delta damping strongly

into many-body channels, and thus providing the residual energy required

to induce fission. More data will be taken during the next running cycle

at Bates, including data on 233 U. (W.R. Dodge, J.W. Lightbody, J.S.

O'Connell, X.K. Maruyama).

The 52 Cr(e,e') 180 degree scattering experiment to study properties

of the first 2+ state transverse form factor is in final stages of

analysis. These data have been taken in collaboration with J. Flanz of

MIT and R. Lindgren of the University of Virginia. Data have been taken

at momentum transfers between 0.5 and 1.2 fm -1

. The preliminary results

have been compared with shell model calculations by R. Mooy of Urexel

University, and also with a result obtained from the measured longitudinal

form factor using the continuity equation to relate the transverse and

longitudinal form factors. The shell model results use effective charges

of 2. 16e for protons and 1.16e for neutrons. Both the shell model and

phenomenological model fail to predict sufficient transverse strength.

DWBA calculations are planned. (J.W. Lightbody and X.K. Maruyama).

280
Division 530, Technical Activities (cont'd)

The 3 H, 3 He(e,e') experiment is a collaboration involving many of the

Bates users, too numerous to mention here. The target was a cooled gas

system developed at Bates, and was operated near 45 K. at a pressure of

approximately 220 psia. Data were taken at electron beam energies between

100 and 815 MeV, and for scattering angles between 54 and 134 degrees. The

data are being analyzed at Bates and at UVA. The primary results will be

improved radii determinations, threshold measurements to compare with

breakup calculations, quasielastic measurements, and measurement of the

delta production cross section. Together with earlier measurements on the

deuteron and recent Saclay data on 3 H, these data should provide a data

base with which stringent tests of few-body calculations can be made.

(W.R. Dodge, J.W. Lightbody, and X.K. Maruyama).

A proposed (e,e'p) experiment to measure the pol ari zation-rel ated

,

fifth structure function in the quasielastic region was deferred until

detector development could be made and a reliable polarized electron beam

was available. Work is continuing to develop large area, high-purity Ge

detectors, and to see if such detectors can be made to operate in the

Bates beam environment. Directors reserve beam time at Bates will be used

in the fall for this effort. Protons of 135 MeV kinetic energy will be

detected at backwards angles in the Ge detectors, and electron

coincidences will be sought in the ELSSY spectrometer. Recirculator

energies will be required. Calculations in support of this experiment

have been performed by VanOrden of the University of Maryland using a relativistic potential model. (W.R. Dodge and J.S. O'Connell).

In collaboration with the University of Maryland, the University of

Mew Hampshire, Stanford, and MIT we are determining the feasibility of

measuring the (e,e'p) and (e,e'alpha) cross sections for 12 C and 16 0 in

the GDR excitation region. Initial studies made two years ago seemed

encouraging, but runs made in May 1985 indicated severe beam halo

problems. Progress in reducing the beam halo has been made recently by

observing the beam on a series of ZnS screens with holes in the center

through which the most intense part of the beam could pass. The most

recent tests indicate that the proposed experiments may indeed be possible

at Bates. (W.R. Dodge)

.

The A-dependence of the ratio of (e,e'p) coincidence to (e,e‘) events

was measured in July of this year to determine the macroscopic attenuation

of 140 MeV nucleons. This was a collaborative study involving Argonne

National Laboratory, Northwestern University, MIT, the University of

Maryland, Mount Holyoke College, and NBS. The 0HIPS spectrometer was used

to detect 600 Me V/c electrons in coincidence with 400 to 600 MeV/c protons

detected in the BIGBITE spectrometer. The data from this experiment are presently under analysis and should provide information on proton

propogation in nuclei which is essential for the analysis of many

processes, including pion absorption and inclusive proton induced

reactions. (X.K. Maruyama).

281
Division 530, Technical Activities (cont'd)

In collaboration with the University of Maryland, the University of

New Hampshire, and MIT we are attempting to measure the density dependence

of the electromagnetic current operators by comparing the q-dependence of

the (e,e'p) cross sections in 12

q

and 63 Cu at constant energy transfer,

proton energy, and recoil momentum. The experiment was scheduled to run in

June 1985, but because of linac problems data were only taken at one angle

pair around the q-di recti on) . Following an aborted attempt to run in June

of this year, the experiment will be rescheduled for the fall. (W.R.

Dodge)

.

In collaboration with M.A. Piestrup of Adelphi Technology, M.J.

Moran of LLNL, and B.L. Berman of George Washington University, the use of

transition radiation as a source of hard x-rays for applications is being

investigated. A Bates experiment is planned for this fall to demonstrate

that high fluxes of x-rays can be obtained from high average current

electron beams at moderate energies. The goal of the preliminary

experiment will be (1) to measure the absolute flux of x-rays from foil

stacks of transition radiators, and (2) to destructively test these stacks over long periods of time. Potential applications for transition

radiation include uses for angiography, x-ray lithography, beam

diagnostics, and particle detection. (X.K. Maruyama)

In addition to the above active areas of investigation, we are preparing an expanded paper describing our earlier work (in collaboration

with the University of Lund, MIT, and UNH) on the excitation of the delta

resonance by forward angle electron scattering (J.S. O'Connell et

al . ,PRL53, 1984. ) The expanded work will contain the complete data set

including data taken at 537 MeV as well as the 730 MeV data. Details of

the data analysis and comparison to delta-hole model calculations by Koch

and Ohtsuka will be presented. The delta-hole calculations were found to

underestimate the measured cross sections in the resonance region by about

20 percent, but describe the shape rather well.

(W.R. Dodge, J.W. Lightbody, X.K. Maruyama, and J.S. O'Connell)

Electromagnetic Nuclear Theory Activities . In connection with the

design of tagged photon systems, a detailed analysis of the fully

differential cross section and polarization for bremsstrahl ung has been

carried out for small angles and high energies of the final electron and

photon. In addition, simple, analytic closed form expressions have been

developed for the angular distribution of the scattered electron

(integrated over photon angles) including the effects of atomic screening.

In addition to studies of bremsstrahl ung , analysis of electron and

positron scattering from nuclei is being carried out in collaboration with

experimentalists at the University of Illinois and at the Division of High

Energy Nuclear Physics, Saclay, France. Investigation has continued into

the photo and pionic disintegration of few body systems ( 2 H, 3 H, 'He),

particularly in the region dominated by the isobar (200-400 MeV). The aim

282
Division 530, Technical Activities (cont'd)

is the formulation of a relatively simple model for these reactions, for

comparison with currently existing data, in particular, the recent

experimental data on the radiative capture of polarized protons by

deuterons. (L.C. Maximon)

In addition to the above investigations, work is going on in

connection with the momentum transfer dependence of the quasi -el astic peak

position observed in electron scattering. This effect, observed for 4 He

and 12 C , can be related to the concept of effective mass and in turn to

momentum dependence in the mean field experienced by the knock-out

nucleon. This work is being carried out in collaboration with the

University of Lund photo-nuclear group. In a collaboration with E. Dressier of Penn State, a calculation of the ( e ,

e

1 Nir ) cross section is

being carried out within the context of the Fermi gas model. This type of

calculation will be useful for estimating counting rates for experiments

planned for CEBAF and other cw electron beam facilities. The delta

resonance is a composite pi -N system and dominates pi on and photon

reactions at intermediate energies. Its production, propogation, and

subsequent decay into the pion-nucleon channel is therefore of great

importance. In collaboration with T. Gaiser of the Bartol Research

Foundation, work has continued on calculating the spectra of leptons

generated by cosmic ray neutrinos. (J.S. O'Connell)

Finally, in connection with CEBAF planning, we are examining the

prospects for studying the two-nucleon knockout reaction with the high

energy beams planned for CEBAF. We are looking at the various known

processes that contribute to this reaction, including final state effects,

meson exchange currents, as well as initial state two-body correlations.

We are also examining the processes that will form the experimental

backgrounds to the two-nucleon knockout reaction. We have modeled the

proton electro-production process including quasi-free knockout, delta

production and decay, and quasi-deuteron breakup. We have also modeled

the single arm electron scattering process in the quasi-free and delta

production regions. Through these efforts we hope to find the sensitivity

of the various measurable structure functions to the processes of

interest, using this as a guide to plan measurements at CEBAF.

(J.W. Lightbody and J.S. O'Connell)

During this year the problem of the polarizability of the nucleon has

been addressed. This quantity is of fundamental importance relating to

basic predictions of QCD, and plans are being drawn for the experimental

study of both the electric and magnetic polarizability using the new generation cw electron machines. The photonuclear absorption cross section

of the proton is dominated by the delta-resonance, a magnetic dipole

state. This resonance overlaps an electric dipole continuum and is

followed at' higher energies by other pion-nucleon resonances of electric

dipole and quadrupole character. It is difficult to reconcile what we know

283
Division 530, Technical Activities (contd)

about the total photo-absorption cross section with the results of earlier

and somewhat imprecise photon scattering experiments, which conclude that

the electric polarizability is ten times the magnetic polarizability. The

theoretical answer to this problem might lay in a proper treatment of

retardation effects. Experimentally, the magnetic polarizability should

be better determined. One possibility is to use a linearly polarized

photon beam and measure the scattering intensity along the polarization

direction. (E. Hayward).

Nuclear Theory . The activities described in this section were carried

out by M. Danos and co-workers. In the past, nuclear forces have been

treated by computing a nucleon-nucleon 2-body force in terms of meson

exchanges between point nucleons treated in second order perturbati on

,

although it was realized that these nucleons were not point particles but

in fact occupied a large part of the volume of nuclei. Now the origin of

nuclear forces must be rethought in terms of the underlying quark

structure. There are two aspects to this problem. First, the short range

part of the interaction must be re-done in terms of explicit quark degrees

of freedom. The model available for this treatment is the bag model.

However, two-nucleon interactions in this model have six quarks in the

bag, and if an exchanged meson is included then there are seven quarks and

an anti -quark. There are many-body correlations among the quarks. A

program to investigate these forces has been started.

To replace the ad hoc boundary conditions of the bag model by a correct description of the hadron vacuum interface in fact requires a solution, or at least a semi -quantitative understanding, of the

confinement problem. In fact, it is nuclear physics which will have to

yield information on the confinement effect. As a first step one must

achieve an understanding , i.e., a description, of the vacuum itself

before considering the interface. It is widely believed that the

confinement in QCD, in analogy with superconducti vi ty , results fron the

existence of a physical vacuum which is removed from the remainder of the

spectrum by an energy gap, which exhibits a Mei ssner-Ochsenfeld effect,

and which can not be described by perturbative quantum field theory. More

particularly, it is believed that these characteristics of the physical vacuum result from the infrared properties of QCD. Utilizing these

considerations, an attempt is underway to construct a model of the QCD vacuum with the techniques developed in the context of superconductivity

theory.

The other aspect concerns the long-range part of the interaction,

i.e., that part where the microscopic structure of the vertex is

unimportant. There the many-body aspects of the system nucleonplus-mesons have to be accounted for, which are neglected in the presently

employed perturbation treatment of the nuclear force. This proper

description requires that the nucleus be treated as a relativistic

many-body system. A program of such a treatment is underway.

284
Division 530, Technical Activities (cont'd)

A new emerging field of nuclear physics concerns the question of

explicit manifestations of QCD effects in nuclear reactions. A promising

approach is the observation of a quark-gluon plasma in the high energy

collision of two heavy nuclei. Diverse aspects of this subject are being

expl ored

.

An example of the importance of quarks in the nucleus is a recent

study in which experiments at SLAC and CERN have been used to show that

between 2 and 10 percent of the quark wave function occupies the nucleus

as a whole rather than being correlated into individual nucleons.

(M. Danos.)

Elementary Particle Theory . The elementary particle theory program

under S. Meshkov is varied, with activity on several fronts. The ongoing

QCD program was strengthened by an active participation in the Nuclear

Chromodynamics Workshop at the Institute for Theoretical Physics (ITP) at

the University of California, Santa Barbara. A comprehensive, up to date

review of Glueballs and Meson Spectroscopy was prepared while at ITP and

presented at the 1986 Aspen Winter Physics Conference. Stimulated by this

review and interactions at ITP, Meshkov, Palmer, and Pinsky have examined

recent data on the iota/E system to elucidate the quark/glue nature of

this particle (or particles). In a recent paper, they find that a considerable simplification is achieved when the system is viewed as comprised of at least two states: a high mass iota around 1460-1500 MeV

with JPC=0 _+ and a low mass E around 1420 MeV with JPC=0“+ or 1 ++

. The

iota has a considerable admixture of glue in its wave function and its

quark content is near the el ectromagnetically "inert" mixture uu+dd-5ss. A

number of experimental tests are proposed which will shed light on this

complex and interesting system.

A new area of research, the production of neutral vector meson pairs

by photon-photon interactions, was started at ITP-UCSB in collaboration

with S.J. Brodsky of SLAC. A crossing symmetric description of gamma-gamma

production of neutral rho meson pairs and other vector meson pairs was

formulated which describes both the energy dependence and the production

angular dependence for these processes (in agreement with experiment) in

terms of the Yennie shrinking photon method which successful ly descri bes

electroproduction. (S. Meshkov)

Miscellaneous Activities . During the past year members of our staff

have participated extensively in outside activities. J.S. O'Connell has

been chairman of the MIT/Bates User Group and has been heavily involved in

planning and review matters associated with that lab. He has also

delivered, lectures at the European Intermediate Energy Nuclear Physics

Summer School in Bochen, West Germany, helped organize the Three-Nucleon

Conference held at George Washington University, and helped run the Lewes

Center for Physics in Lewes, DE. J.W. Lightbody has been involved with the

285
Division 530, Technical Activities (cont'd)

CEBAF effort in an advisory role as well as in running the (e,e'2N)

working group at the CEBAF Summer Workshop. He has delivered lectures at

the NSF sponsored National Intermediate Energy Nuclear Physics Summer

School held at Georgetown University and participated in the Program

Advisory Committee activities of the Saskatchewan Linear Accelerator

Laboratory. M. Danos has been heavily involved in a workshop on muon catalyzed fusion held at NBS. E. Hayward has been a member of the

Executive Board of the American Physical Society, the SURA Board of

Trustees, and the SURA Committee on Science and Technology. S. Meshkov has

been heavily involved in running the Aspen Center for Physics in Aspen, CO.

J.W. Lightbody and X.K. Maruyama have been involved in writing proposals,

including developing background material, to other agencies for funding of new facilities. Every member of the group has given lectures at other

institutions and participated heavily in user activities. The theorists of

the group have, in addition to carrying out their own research, provided

guidance and advice to the experimental members of the group whenever

needed

.

We feel that the Nuclear Physics program addresses the long range NBS

goals in nuclear research, and there is a growing vitality from measured

involvement with the larger nuclear research community. The theoretical

efforts cover the full spectrum of current interest in nuclear research.

The experimental effort represents a healthy balance between in-house

research and research at other facilities.

286
SPONSORED WORKSHOPS, CONFERENCES AND SYMPOSIA

Division 530.01 , Nuclear Physics Group

Meshkov, S., Nuclear Chromodynamics Workshop, Institute for Theoretical

Physics, UCSB, September 2, 1985 - February 2, 1986.

Meshkov, S., Aspen Winter Physics Conference, January, 1986.

Meshkov, S., VIII International Workshop on Photon-Photon Collisions,

April , 1986.

Meshkov, S., Aspen Center for Physics, June 23 - Sept. 15, 1986, including

Superstring Workshop.

Meshkov, S., DPF Superconducting Supercol 1 ider Planning Meeting, Snowmass,

CO., June 23 - July 11, 1986.

Meshkov, S., XXIII International Conference on High Energy Physics,

Berkeley, CA, July 16 - July 23, 1986.

Meshkov, S., Keystone Center, Keystone, CO - National Advisory Committee

on Future Funding of U.S. Science and Technology R & D, August 24-25,

1986.

287
INVITED TALKS

Division 530.01, Nuclear Physics Group

Danos, M., "Prospects of Muon Catalyzed Fusion", University of Maryland,

December, 1985.

Danos, M., "The QCD Vacuum", Maratea, Italy, June, 1986.

Danos, M., "The QCD Vacuum", University of Bonn, Dept, of Physics, June,

1986.

Danos, M., "The QCD Vacuum", University of Basel, Dept, of Physics, June,

1986.

Dodge, W. R., "Early Results of the MIT-Bates 3^ and 3up Experiment",

University of Maryland, Physics Department, April 1 1 ,

1 986.

Hayward, E., "Nuclear Photon Scattering" at the Nuclear Physics

Laboratory, Oxford, England, November 12, 1985.

Hayward, E., "Photon Scattering Measurements" before the Nuclear

Interactions Group of the U.K. in Edinburgh, Scotland, November 13, 1985.

Hayward, E., "Photon Scattering" at the University of Lund, Sweden, May

27, 1986.

Lightbody, J. W., Jr., "Deep Inelastic Electron Scattering", Memphis State

University, Physics Department Colloquium, February 13, 1986.

Lightbody, J. W., Jr., "Experimental Aspects of Electron Scattering",

Georgetown University, Washington, DC, National Summer School for

Intermediate Energy Physics, sponsored by the NSF, June 12 and 1 3, 1986.

Lightbody, J. W., Jr., Introductory talk for the (e,e'2N) Work Group;

Summary talk for the (e,e'2N) Working Group, CEBAF Summer Workshop,

Newport News, VA, June 23-27, 1986.

Lightbody, J. W., Jr., "Modeling Electron and Proton Yields at Electron

Accelerators", Lewes Center for Physics, Lewes, DE, July 14-25, 1986.

Lightbody, J. W., Jr .," Interpretation of Quasi Elastic and Delta Resonance

Electron Scattering Data In Terms of Modified Nucleon Charge

Distributions", CEBAF Summer Study Group, July 10, 1986.

288
Division 530, Invited Talks (cont'd)

Maruyama, X. K., "Cerenkov Radiation", Saskatchewan Accelerator

Laboratory, University of Saskatchewan, Saskatoon, Canada, October, 1985.

Maruyama, X. K., "Microwave Cerenkov Radiation", Nuclear Physics Seminar,

Drexel University and University of Pennsylvania, Drexel University,

Philadelphia, PA., June, 1986.

Maruyama, X. K., "Cerenkov Radiation as a Diffraction Phenomena", Bates

Accelerator Laboratory Seminar, MIT, Middleton, MA, June 27, 1986.

Maruyama, X. K., "Non-Nuclear Photon Generation with Ultra-Relativistic

Electrons", AERE, Harwell, England, August 30, 1986.

Maximon, L. C., "The Study of Coulomb and Dispersive Effects by the

Comparison of Positron and Electron Scattering from Nuclei", Division of

High Energy Nuclear Physics, CEN, Saclay, France, January 8, 1986.

Maximon, L. C., "Tagged Photons", Lewes Center for Physics", Lewes,

Delaware, July 22, 1986.

Maximon, L. C., "Polarization Properties of Tagged Photons", Saskatoon

Linear Accelerator Laboratory, Saskatoon, Saskatchewan, Canada, September

23, 1986.

Meshkov, S., Lecture Series on "Glueballs and Meson Spectroscopy", Nuclear

Chromodynamics Workshop. Discussed work on stringlike behavior of Heavy

Quarkonia in NCD Workshop. Institute for Theoretical Physics, Univ. of

California, Santa Barbara, (USCB), September, October, November, 1985.

Meshkov, S., "Glueballs and Meson Spectroscopy", Elementary Particle

Physics Seminar, U. C. Irvine, January, 1986.

Meshkov, S., "Glueballs and Meson Spectroscopy", Summary Talk, Aspen

Winter Physics Conference, Aspen, CO, January 19, 1986.

Meshkov, S., "Glueballs and Meson Spectroscopy", Elementary Particle

Seminar, Ohio State Univ., Columbus, Ohio, March, 1986.

Meshkov, S., "Applications of Amplitude Factorization to yy Production of

Vector Meson Pairs", VII International Workshop on Photon-Photon

Collisions, College de France, Paris, France, April, 1986.

Meshkov, S., "Implications of the yy and yp Decays of the Iota", VII

International Workshop on Photon-Photon Collisions, College de France,

Paris, France, April, 1986.

Meshkov, S., "Report on Nuclear Chromodynamics Workshop at ITP-UCSB",

Center for Radiation Research Seminar, NBS, March, 1986.

289
Division 530, Invited Talks (cont'd)

Meshkov, S., "Glueballs", Colloquium, Brookhaven National Laboratory,

Upton, NY, May, 1986.

O'Connell, J. S., "Nuclear Electromagnetic Response in the Delta Region",

University of Georgia, Athens, GA, December 2, 1985.

O'Connell, J. S., "Neutrino Reactions", University of Saskatchewan,

Saskatoon, Canada, February 10, 1986.

O'Connell, J. S., "CW Bremsstrahl ung Reactions", Lake Louise, CAP Meeting,

Canada, February 12, 1986.

O'Connell, J. S , "Nuclear Electromagnetic Response in the Delta Region",

University of Saskatchewan, Saskatoon, Canada, February 14, 1986.

O'Connell, J. S., "What's New in Cosmic Rays", George Washington

University, Washington, DC, March 6, 1986.

O'Connell, J. S., "Photodisintegration of Helium-3 and the Three Nucleon

Force", George Washington University, Washington, DC, April 25, 1986.

O'Connell, J. S., "Atmospheric Neutrinos", APS Meeting, Washington, DC,

May 1, 1986.

O'Connell, J. S., "Momentum Dependence of the Nucleon's Effective Mass",

Center for Physics, Lewes, DE, July 8, 1986.

O'Connell, J.S., "How to Make a Coincidence Measurement", Bosen, West

Germany Summer School, September 2, 1986.

O'Connell, J. S., "Deep Inelastic Electron Scattering", University of

Mainz, West Germany, September 10, 1986.

290
PUBLICATIONS

Division 530.01 , Nuclear Physics Group

Buskirk, F.R., J.R. Neighbours and X.K. Maruyama, Radiation Produced by

the Modulated Electron Beam of a Free Electron Laser, Naval Postgraduate

School, Monterey, California, Report NPS-61 -86-01 3 (1986).

Danos, M., Irreducible Density Matrices, NBSIR 85-3270 (1985).

Danos, M. and A. Johnson, Quarks in the Nuclear Ground State, J. Phys. G.

12, LI 3 (1986).

Gaisser, T. K. and J. S. O'Connell, Interactions of Atmospheric Neutrinos

in Nuclei at Low Energy, Physical Review D34, 822 (1986).

Dodge, W. R., E. Hayward, M. N. Martins, and. E. Wolynec, (e,p) and e,a)

reactions in 90 Zr, Phys. Rev. C32, 781 (1985).

Dodge, W. R., An estimate of the proton yield from quasi-elastic

scattering on 16 0 at an incident electron energy of 800 MeV, in the Proc.

of Xlth Europhysics Divisional Conference on Nuclear Physics with

Electromagnetic Probes , edited by S. Methfessel, Bochum, July 1985).

Dodge, W. R. and E. Hayward, Siegert's Theorem and Nuclear

Electrodisintegration, Phys. Rev. C33, 1251 (1986).

Electrodisintegration Experiments and Virtual Photon Spectra in

Proceedings of the Fifth Course of the International School of

Intermediate Energy Nuclear Physics, edited by R. Bergere, S. Costa, and

C. Schaef (World Scientific Publishing Co., Singapore, 1986) p. 132.

Fishbane, P.M., P. Kaus and S. Meshkov, Do Heavy Quarkonia have Stringlike

Behavior?, Phys. Rev. D.

, _33 , 852 (1986).

Kohmura, T., T. Suzuki, M. Cauvin, V. Gillet, and M. Danos, Shell Model

Interaction Energies in a Relativistic Hamiltonian Formulation, Part I; Nucl . Phys. (1 985).

Lightbody, J. W., Jr., Summary (e,e'2N) Working Group, CEBAF Summer

Workshop, Newport News, VA, June 23-27, 1986.

Martins, M. N., E. Hayward, G. Lamaze, X. K. Maruyama, F. J. Schima and E.

Wolkynec, Experimental Test of the Bremsstrahl ung Spectrum, proceedings

of the Conference on Nuclear Physics with Electromagnetic Probes, Xlth

Europhysical Divisioanl Conference, Paris, 188 (1985).

Neighbors J. R. and X. K. Maruyama, Onset of Cerenkov Radiation, Proc.

Annual SDIO/DARPA/Services Propagation Review (1985).

291
Division 530, Publications (cont'd)

Neighbors, J. R.,F. R. Buskirk, and X. K. Maruyama, Emmission Threshold

for Cerenkov Radiation, Naval Postgraduate School, Monterey, California,

Report NPS-61 -85-005, (1985).

Maruyama, X. K„, J. R. Neighbours and F. R. Buskirk, Electron Beam Bunch

Profile Determination through Cerenkov Radiation, IEEE Transactions on Nuclear Science, 32 , 1 994 (1 985).

Maruyama, X. K., J. R. Neighbours, F. R. Buskirk, D. D. Snyder, M.

Vujaklija, and R. 6. Bruce, Observation of Microwave Cerenkov Radiation as

a Diffraction Pattern, J. Appl . Phys. 60, 518 (1986).

Maruyama, X.K., F. R. Buskirk, J. R. Neighbours, R. D. Fitzpatrick, P. F.

Cromar and J. E. Mark, Study of Off-Axis Radiation Energy Deposition from

10 MeV Electrons Traversing Through Water, Liquid Nitrogen and Air, Naval

Postgraduate School, Monterey, California, Report NPS-61 -86-001 , (1986).

Maruyama, X. K., F. R. Bukskirk, J. R. Neighbours, Microwave Cerenkov

Radiation as a Diffraction Phenomenon, submitted to the Proceedings of the

Conference on the Application of Accelerators in Research and Industry (to

be published in Nuclear Instruments and Methods (1987)).

Cha-mei Tang, P. Sprangle, S. Penner, X. K. Maruyama, Proposal for FEL

Experiment Driven by the National Bureau of Standards's CW Microtron,

Proceedings of the 8th International Free Electron Laser Conference,

Glasgow (1986) (to be published in Nuclear Instruments and Methods

(1987)).

292
PUBLICATIONS IN PREPARATION

Division 530.01 , Nuclear Physics Group

Brodsky, S. J. and S. Meshkov, "Application of Amplitude Factorization to

YY Production of Vector Mesons Pairs", (to be submitted to Phys. Rev.

Letters) .

Buskirk, F. R., J. R. Neighbours and X. K. Maruyama, Radiation Produced by

the Modulated Electron Beam of a Free Electron Laser, Proceedings of the

8th International Free Electron Laser Conference, Glasgow (1986) (to be

published in Nuclear Instruments and Methods (1987)).

Dodge, William R., Diffraction virtual photon spectra partitioned

according to the four structure functions of the (e,e'X) cross section for

all electric and magnetic multipoles in the long wave limit. To be

submitted to the Proceedings of the Conference of the Application of

Accelerators in Research and Industry at Denton, Texas, November 10-12,

1986, and to the Physical Review.

J. Flanz and J. W. Lightbody, Jr., 180°- Electron Scattering from the 2 + State in 52 Cr.

L. S. Cardman, S. P. Fivozinsky, J. W. Lightbody, Jr., X. K. Maruyama, S.

Penner,* P. Trower, S. Williamson, Elastic Electron Scattering from 12 C.

Maximon, L. C., Physics Reports "Tagged Photons" (in press).

Meshkov, S., "Glueballs and Meson Spectroscopy" (Proceedings of Aspen

Winter Conference, 1986).

Meshkov, S., W. F. Palmer and S. S. Pinsky, "The L/E System", submitted

to Physical Review Letters.

O'Connell, J. S., W. R. Dodge, J. W. Lightbody, Jr., X. K. Maruyama, J.

0. Pdler, K. Hansen, B. Schroder, A. M. Bernstein, K. I. Blomqvist, B.

H. Cottman, J. J. Comuzzi, R. A. Miskimen, B. P. Quinn, J. H. Koch, and

M. Ohtsuka, Electromagnetic Excitation of the Delta Resonance in Nuclei.

Schroder, B. and J. S. O'Connell, Momentum Dependence of the Nucleon

Effective Mass as Measured in Quasi-Free Electron Scattering.

293
TECHNICAL AND PROFESSIONAL COMMITTEE PARTICIPATION AND LEADERSHIP

Division 530.01 , Nuclear Physics Group

Hayward, E. V., Executive committee of the Division of Nuclear Physics of

the American Physical Society.

Hayward, E. V., SURA Borad of Trustees.

Hayward, E. V., Science and Technology Committee of SURA.

Lightbody, J. W., Jr., Member, Program Advisory Committee, Saskatchewan

Accelerator Laboratory, Saskatoon, Saskatchewan, Canada.

Lightbody, J. W., Jr., Member, National Advisory Board, CEBAF, Newport

News, VA.

Lightbody, J. W., Jr., Member, Technical Advisory Committee, MIT/Bates

Linear Accelerator.

Lightbody, J. W., Jr., Member, Board of Directors of the CEBAF User

Group.

Lightbody, J. W., Jr., Chairman-Elect, CEBAF User Group.

Maruyama, X. K., Member, Minority Advisory Committee, National Measurement

Laboratory, National Bureau of Standards.

Meshkov, S., Member, Advisory Board, Aspen Center for Physics, Aspen, Co.

Meshkov, S., Member, Organizing Committee for Winter Conference, Aspen

Center for Physics, Aspen, CO.

Meshkov, S., Chairman, 1987 Program Committee, Aspen Center for Physics,

Aspen, CO.

Meshkov, S., Chairman, 1986 Colloquium Committee, Aspen Center for

Physics, Aspen, CO.

Meshkov, S., Member, Interagency Seminar Series (Wash).

Meshkov, S., Member, Fermilab - organizing committee for Fermilab Low

Energy Antiproton Facility Workshop.

Meshkov, S., Member, National Advisory Committee on Future Funding of U.S.

Science and Technology R + D, Keystone Center, Keystone, CO.

294
Division 530, Technical and Professional Committee Participation and

Leadership (cont'd)

Meshkov, Chaired Session on Hadron Physics at Washington, DC, APS Meeting,

April, 1986.

O'Connell, J. S., National Bureau of Standards- Editorial Board, Research

Advisory Committee.

O'Connell, J. S., American Physial Society- Nominating Committee, Division

of Nuclear Physics and Editorial Advisory Board for Physical Review C.

O'Connell, J. S., Bates Linear Accelerator Center - Program Advisory

Committee, Director's Advisory Board, Users Group-President

.

O'Connell, J. S., Lewes Center for Physics - Governing Board.

295
TRIPS SPONSORED BY OTHERS

Division 530.01 , Nuclear Physics Group

Danos, M., Centre d' Etudes Nucleaire de Saclay, France.

Danos, M., Institute of Theoretical Physics and Astrophysics, University

of Cape Town, South Africa.

Danos, M., Institute for Theoretical Physics, University of Frankfurt,

West Germany.

Danos, M., Los Alamos National Laboratory, Los Alamos, New Mexico.

Dodge, W. R., MIT/Bates Linear Accelerator, to participate in

col 1 aborati ve experiments, January 12-21 , 1986; February 9-18, 1986; March

3-1 7, 1986; March 24-April 3, 1986.

Hayward, E. V., round-trip air fare to London, England sponsored by the

Science and Engineering Research Council.

Hayward, E. V., Trip to Edinburgh, Scotland was sponsored by the U. K.

Nuclear Interactions Groups.

Lightbody, J. W., Jr., Memphis State University, colloquium, February

13-14, 1986.

Lightbody, J. W., Jr., CEBAF Summer Workshop, Chaired Working Group, June

23-27, 1986.

Lightbody, J. W., Jr., University of Saskatchewan, Program Advisory

Committee Meeting, Nov. 7-12, 1985.

Lightbody, J. W., Jr., MIT/Bates Accelerator Advisory Committee Meeting,

September 12-13, 1985.

Lightbody, J. W., Jr., CEBAF National Advisory Board Meeting, September

12-13, 1985.

Lightbody, J. W., Jr., CEBAF National Advisory Board Meeting, January

10-11, 1986.

Lightbody, J. W., Jr., CEBAF National Advisory Board Meeting, September

18-19, 1986.

Lightbody, J. W., Jr., MIT/Bates Linear Accelerator to participate in

collaborative experiments January 17-28, 1986; March 22-27, 1986.

296
Division 530, Trips Sponsored by Others (cont'd)

Maruyama, X. K., Naval Postgraduate School, Monterey, California, to

consult on energy deposition of relativistic electrons in matter, January,

1986. Trip sponsored by Naval Postgraduate School.

Maruyama, X. K., MIT/Bates to participate in the tritium/ 3 He electron

scattering experiment. Trip sponsored by MIT*. January, February, March,

1986.

Maruyama, X. K., University of Saskatchewan to present a talk. Sponsored

by University of Saskatchewan, October, 1985.

Maruyama, X. K., Drexel University, Philadelphia, PA, to present talk

sponsored by Drexel University, June, 1986.

Maruyama, X. K., Lawrence Livermore National Laboratory to participate in an experiment on transition radiation, July, 1986.

Maximon, L. C., trip to Center for Nuclear Studies, Saclay, to consult and

work with experimentalist and continue collaboration on elastic and

inelastic electron scattering, and the production of monoenergetic proton

beams, at the Saclay Linear Accelerator, Saclay, France, December 20, 1985

to February 7, 1986.

Maximon, L. C., trip to Brookhaven National Laboratory to consult with

experimentalists and plan experiments on photon scattering,

September 10-12, 1986.

Maximon, L. C., trip to Saskatoon Linear Accelerator Laboratory,

Saskatoon, Saskatchewan, Canada, to consult with experimentalist and plan

for the design of a photon tagging system, September 23-30, 1986.

Meshkov, S., trip to Aspen Winter Conference to present invited summary

talk, sponsored by UCSB, January, 1986.

Meshkov, S., trips to Ohio State University to present seminar and to work

on collaborative research, sponsored by Ohio State University, March

1 7-31 ,1 986 and May 5-7, 1986.

Meshkov, S., trip to Brookhaven National Laboratory to present colloquium,

sponsored by Brookhaven National Laboratory, May 19-21 , 1986.

Meshkov, S., trip to present seminar at UC Irvine, sponsored by UCSB,

January, 1986.

Meshkov, S., trip to participate on the National Advisory Committee on Future Funding of U.- S. Science and Technology R & D at Keystone Center,

Keystone, CO, sponsored by Keystone Center, August, 1986.

297
SPONSORED SEMINARS AND COLLOQUIA

Division 530.01 , Nuclear Physics Group

Berman, Barry L., Department of Physics, George Washington University,

"Coherent Transition Radiation", December 12, 1985.

Buskirk, J., Dept, of Physics, Naval Postgraduate School and Mack,

Joseph, Los Alamos National Laboratory, "AF Cherenkov Radiation as a Beam

Signature at Phermex", February 27, 1986.

Meshkov, S., Nuclear Chromodynamics Workshop, March 14, 1986.

Reiner Schneider-Rueck, Bates Linear Accelerator Center, "Coincidence

Experiments in the Giant Resonance", April 1, 1986.

Lei si , H. J., Swiss Institute for Nuclear Research, "Muonic and Pionic

X-Ray Experiments with Crystal Diffraction Spectrometry, May 1 5, 1986.

Gilman, Frederick, Stanford Linear Accelerator Center, "Search for Neutral

Leptons", May 23, 1986.

Speth, Joseph, Los Alamos National Laboratory, "Large Momentum Transfer

Electron Scattering & the Compression Modules of Nuclear Matter", July 2,

1986.

Detlev Bohle, THS Darmstadt, "Properties of an Orbital Ml Excitation Mode

in Nuclei", August 21 , 1986.

Rule, D. W., Naval Surface Weapons Center, "Transition Radiation

Diagnostics for Intense Charge Particle Beams", August 21, 1986.

McDonald, K. T., Dept, of Physics, Princeton University, "Observation of

Interference Between Cerenkov and Synchrotron Radiation", September 11,

1 986.

298
LIST OF ACRONYMS

AAMI

AAPM

ACO

AERE

AFRRI

AIF

ALS

ANL

ANS

ANSI

APS

ASTM

AVS

Association for the Advancement fo Medical Instrumentation

American Association of Physicists in Medicine

Orsay Electron Storage Ring/France

Atomic Energy Research Establishment (U.K.)

Armed Forces Radiobiology Research Institute

Atomic Industrial Forum

Advanced Light Source

Argonne National Laboratory

American Nuclear Society

American National Standards Institute

American Physical Society

American Society for Testing and Materials

American Vacuum Society

BaSO.

BBU

BESSY

Beval ac BGO

BIPM

BPNL

Barium Sulfate

Beam Breakup

Berlin Electron Storage Ring Facil ity/Germany

Name of a heavy ion accelerator at Berkeley

Bismult generator

Bureau International des Poids et Mesures (France)

Battel 1 e-Pacific Northwest Laboratory

CAD

CAE

CAM

CAMAC

CCEMRI

CCG

CCPR

CEBAF

CEN

CERN

CESR

CIE

CIPM

CIRRPC

CNRS

C0 2 CORM

CRCPD

CRDS

CRR

Cs

CSEWG

CW

Computer-aided Design

Computer-aided Engineering

Computer-aided Manufacturing

Computer Automated Measurement and Control

Consultative Committee for Ionizing Radiations

Combined Calibration Group

Consultative Committee on Photometry and Radiometry

Continuous Electron Beam Accelerator Facility/Newport News

Center for Nuclear Energy, Sac! ay, France

European Center for Nuclear Research (Switzerland)

Cornell Electron Storage Ring/U.S.A

Internatinal Commission of Illumination

Comnittee International des Poids et Mesures

Committee on Interagency Radiation Research and Policy

Coordination

French National Center for Scientific Research

Carbon Dioxide

Council for Optical Radiation Measurements

Conference of Radiation Control Program Directors

Charles River Data System

Center for Radiation Research

Cesium

Cross Section Evaluation Working Group

Continuous Wave

299
DARPA

DCM

DIAL

DNA

DOE

DOS

DSA

DTS

Defense Advanced Research Project Agency

A specific laser dye

Differential Absorption LIDAR

Deoxyribos nucleic acid

Department of Energy

Disk Operating System

Digital Subtration Angiography

Dual thin scintillator

EC

ENDF

EPA

ETH

ETL

EURADOS

Electron Capture

Evaluated Nuclear Data File

Environmental Protection Agency

Swiss Federal Institute of Technology

Electro-Technical Laboratory (Japan)

European Community Dosimetry

FASCAL

FDA

FEL

FEMA

FERDoR

FIMS

FOS

FRG

FT

FWHM

FY

Facility for Automatic Spectroradi ometric Calibrations

Food and Drug Administration

Free Electron Laser

Federal Emergency Management Agency

(computer code)

Fissionable Isotope Mass Standards

Faint Object Spectrograph

Federal Republic of Germany

Fourier Transform

Full Width at Half Maximum

Fiscal Year

GaAs

GC/MS

GPIB

GSFC

Gallium Arsenide

Gas chromatography/mass spectrometry

General Purpose Interface Bus

Goddard Space Flight Center

HAFM

HgCdTe

HP

HPGe

HPLC

Helium Accumulation Fluence Monitor

Mercury Cadmium Telluride

Hewlett Packard

High-purity germanium detector

High performance liquid chromatography

IAEA

IBM

ICIAQ

ICPEAC

International Atomic Energy Agency (Vienna)

International Business Machines Corp.

Interagency Committee on Indoor Air Quality

International Conference on the Physics of Electron and

Atomic Collisions

ICRM

ICRU

International Committee for Radionuclide Metrology

International Commission on Radiation Units

and Measurements

I EC

IEEE

INEL

International Electrotechnical Commission

Institute of Electrical and Electronic Engineers

Idaho National Engineering Laboratory

300
INMM

INSF

I/O

IPNS

IPTS

IRISO

ITP-UCSB

Institute for Nuclear Materials Management

Intermediate Energy Standard Neutron Field

Input/Output

Intense Pulsed Neutron Source

International Practical Temperature Scale

Infrared

International Organization for Standards

Institute for Theoretical Physics - University of

California, Santa Barbara

JAERI

JEN

JET

JILA

Japan Atomic Energy Research Institute

Junta de Energia Nuclear (Spain)

Joint European Torus

Joint Institute of Laboratory Astrophysics

KEK

KENS

KRI

National Laboratory for High Energy Physics (Japan)

High Energy Neutron Source (Japan)

Khlopin Radium Institute (USSR)

LANL

LASP

LDEF/ITS

Los Alamos National Laboratory

Laboratory for Astronomy and Space Physics/U. of Colorado

Long Duration Exposure Facility/Integrated Target

Satellite

LEED

LET

LIDAR

LINAC

LLNL

LTEC

LURE

Low Energy Electron Diffraction

Linear Energy Transfer

Laser Detection and Ranging System

Linear Accelerator

Lawrence Livermore National Laboratory

Lamp Testing Engineer's Conference

Laboratory for the Use of Energetic Radiation/Orsay,

France

LWIR Long Wavelength Infrared

urn mm

MCNP

MFKI

MIT

MQA

MRG

MRTD

Mi crometer

Mi 1 1 i meter

(computer code)

Research Institute for Technical Physics (Hungary)

Massachusetts Institute of Technology

Measurement quality assurance

Materials Research Group

Minimum Resolvable Temperature Difference

NASA

NAS-NRC

NATO

NAVLAP

NBS

NBS-PC

NCRP

National Aeronautical and Space Administration

National Academy of Sciences-National Research Council

North Atlantic Treaty Organization

National Voluntary Laboratory Accreditation Program

National Bureau of Standards

NBS-Personal Computer

National Council on Radiation Protection and Measurements

301
NDT

NIM

NIR

nm

NML

NPL

NRL

NRRS

NSF

NSLS

NTOFF

OD

OMEGA

OMH

ONR

ORNL

OSA

PC

PID

PN

PNL

PRC

PRT

PSD

PTB

PTFE

PTW

QED

RAM

RARAF

RDS

RF

RTM

SCA

SCK-CEN

SDIO

SEM

SEMPA

S IRIS

SLAC

SNS

SPIE

SRC

Non-Destructive Testing

Nuclear Intrumentation Module

Near Infrared

Nanometer

National Measurement Laboratory

National Physical Laboratory

Naval Research Laboratory

Near resonance Rayleigh scattering

National Science Foundation

National Synchrotron Light Source

Neutron Time-of-Fl i ght Facility

Outside Diameter

24 Beam Laser Facility at Rochester

Hungarian Office of Measures

Office of Naval Research

Oak Ridge National Laboratory

Optical Society of America

Personal Computer

Post irradiation dosimetry

p on n type silicon junction

Battel le Pacific Northwest Laboratories

Peoples Republic of China

Proton recoil telescopic

Photon Simulated Desorptign

Physikalisch Technische Bundesanstal t (West Germany)

Polyetraf luoroethylene

Physikalisch Technische Werkstatten

Quantum electrodynamics

Random Access Memory

Radiological Research Accelerator Facility

Resonance detector spectrometer

Radio Frequency

Racetrack Microtron

Sphere-Chain Attenuator

Studiecentrum voor Kernenergie-Centre d'Etude de l'Energie

Nucleaire (Belgium)

Strategic Defense Initiative Office

Scanning Electron Microscope

Scanning Electron Microscopy with Electron Polarization

Analysis

Sputter Initiated Resonance Ionization Mass Spectrometry

Stanford Linear Accelerator Center

Spallation Neutron Source

The Society for Photo-Optical Instrumentation Engineers

Synchrotron Radiation Center, UK

302
SRM

SSTR

STM

STOS

SUNY

SURA

Standard Reference Material

Solid State Track Receiver

Scanning Tunneling Microscope

Space Telescope Optical Simulator

State University of New York

Southeastern Universities Research Association

SURF & SURF-II Synchrotron Ultraviolet Radiation Facility

SUSIM

SW

Solar Ultraviolet Spectral Irradiance Monitor

Standing Wave

TAMS

TEPC

TEXT

TLD

TRIGA

TUD

TW

Tandum Accelerator Mass Spectrometry

Tissue Equivalent Proportional Counter

Texas Experimental Tokamak

Thermoluminescent Detector

(research reactor design made by General Atomic)

Technical University of Dresden (East Germany)

Traveling Wave

UDT

UK

UNH

UPS

USADC/SDI

USOA

USUHS

U V

UVA

UVSG

United Detector Technology, Inc.

United Kingdom

University of New Hampshire

Ultraviolet Photoemission Spectroscopy

U.S. Army Defense Command/Strategic Defense Initiative

United States Department of Agriculture

Uniformed Services University of Health Sciences

Ultraviolet-Wavelength Range 200-400 nm University of Virginia

Ultraviolet Spectrometry Group

VUV

VIAS

VIS

VME

Vacuum Ultraviolet-Wavelengths less than 200 nm (computer code)

Vi si bl e (computer bus system)

XT A type of personal computer

XUV

XUV

Extremely Far Ultraviolet

Soft X-Ray Wavelength Range, 10-50 nm

WNR-PSR Weapons Neutron Source-Proton Storage Ring

303
.

.
N BS-1 14A (rev. 2 -ec> U.S. DEPT. OF COMM. 1. PUBLICATION OR 2. Performing Organ. Report No. 3. Publication Date BIBLIOGRAPHIC DATA

SHEET (See instructions)

REPORT NO.

NBSI R-86/3441 NOVEMBER 1986

4. TITLE AND SUBTITLE

Technical Activities 1986

Center for Radiation Research

5. AUTHOR(S)

Chris E. Kuyatt

6. PERFORMING ORGANIZATION (If joint or other than N&S, see instructions)

national bureau of standards

DEPARTMENT OF COMMERCE

WASHINGTON, D.C. 20234

7. Contract/Grant No.

S. Type of Report & Period Covered

9.

SPONSORING ORGANIZATION NAME AND COMPLETE ADDRESS (Street. City, State, ZIP)

10.

SUPPLEMENTARY NOTES

| | Document describes a computer program; SF-185, FIPS Software Summary, is attached.

11.

ABSTRACT (A 200-word or less factual summary of most significant information. If document includes a significant

bi bliography or literature survey, mention it here)

This report summarizes research projects, measurement method development,

calibration and testing, and data evaluation activities that were carried

out during Fiscal Year 1986 in the NBS Center for Radiation Research.

These activities fall in the areas of atomic and plasma radiation,

radiation physics, radiometric physics, radiation sources and instrumentation,

ionizing radiation, and nuclear physics. 12.

KEY WORDS (Six to twelve entries; alphabetical order; capitalize only proper names; and separate key words by semicolon s) Atomic radiation, ionizing radiation; measurement support; nuclear radiation,

plasma radiation; radiation instrumentation, radiation measurements; radiation

physics, radiation sources; radiometric physics.

13. AVAILABILITY

(_}(J Uni imited

| 1 For Official Distribution. Do Not Release to NTIS

I I Order From Superintendent of Documents, U.S. Government Printing Office, Washington, D.C.

20402.

I ^1 Order From National Technical Information Service (NTIS), Springfield, VA. 22161

14. NO. OF

PRINTED PAGES

311

15. Price

$28.95

USCOMM-OC 8043-P90