V)

. - J

NEW NBS PUB

MAR 3 1 1976

NBS MONOGRAPH 1 50

U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards

Liquid-in-Glass Thermometry
NATIONAL BUREAU OF STANDARDS

The National Bureau of Standards 1 was established by an act of Congress March 3, 1901.

The Bureau's overall goal is to strengthen and advance the Nation's science and technology

and facilitate their effective application for public benefit. To this end, the Bureau conducts

research and provides: (1) a basis for the Nation's physical measurement system, (2) scientific and technological services for industry and government, (3) a technical basis for equity in trade,

and (4) technical services to promote public safety. The Bureau consists of the Institute for Basic Standards, the Institute for Materials Research, the Institute for Applied Technology,

the Institute for Computer Sciences and Technology, and the Office for Information Programs.

THE INSTITUTE FOR BASIC STANDARDS provides the central basis within the United

States of a complete and consistent system of physical measurement; coordinates that system

with measurement systems of other nations; and furnishes essential services leading to accurate and uniform physical measurements throughout the Nation's scientific community, industry,

and commerce. The Institute consists of the Office of Measurement Services, the Office of

Radiation Measurement and the following Center and divisions:

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for Radiation Research: Nuclear Sciences; Applied Radiation — Laboratory Astrophysics 2 — Cryogenics 2 — Electromagnetics 2 — Time and Frequency 2

. THE INSTITUTE FOR MATERIALS RESEARCH conducts materials research leading to improved methods of measurement, standards, and data on the properties of well-characterized

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1 Headquarters and Laboratories at Gaithersburg, Maryland, unless otherwise noted; mailing address Washington, D.C. 20234.

3 Located at Boulder, Colorado 80302.
Liquid-in-Glass Thermometry

Jacquelyn A. Wise

Institute for Basic Standards

National Bureau of Standards

Washington, D.C. 20234

(Supersedes NBS Monograph 90)

U.S. DEPARTMENT OF COMMERCE, Rogers C. B. Morton, Secretary

James A. Baker, III, Under Secretary

Dr. Betsy Ancker-Johnson, Assistant Secretary for Science and Technology

NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Acting Director

Issued January 1976
Library of Congress Cataloging in Publication Data

Wise, Jacquelyn A.

Liquid-in-Glass Thermometry.

(NBS Monograph; 150)

Supersedes NBS monograph 90. Calibration of Liquid-in-Glass

Thermometers, by J. F. Swindells. Bibliography: p. Supt. of Docs. No.: C13.44:150

1. Thermometers and Thermometery—Calibration. I. Swindells,

James F. Calibration of Liquid-in-Glass Thermometers. II. Title.

III. Series: United States. National Bureau of Standards. Monograph; 150. QC100.U556 No. 150 [QC271.8.C3] 389'.08s [536'.51] 75-619230

Nat. Bur. Stand. (U.S.), Monogr. 150, 30 pages (Jan. 1976)

CODEN: NBSMA6

National Bureau

U.S. GOVERNMENT PRINTING OFFICE

WASHINGTON: 1976

For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402

(Order by SD Catalog No. C13.44:150). Price 85 cents. (Add 25 percent additional for other than U.S. mailing).
Contents

Page

1. Introduction 1

2. Thermometer Calibration Services at the NBS 1

2.1. Kinds of thermometers accepted for calibration 1 2.2. Preliminary examination 2

2.3. Reports of Calibration 2

2.4. General instructions to applicants for tests 2

a. Initial arrangements 2

b. Shipping instructions 5

3. Definitions 5

4. Temperature Scales and Standards ... 6

5. Calibration 8

5.1. Equipment .. 8

a. Ice Bath 8

b. Steam Bath 8

c. Comparison Liquid Baths 9

5.2. Determination of scale corrections 11

5.3. Corrections for emergent stem 13

a. Measurement of emergent-stem temperature 13

b. Formula for total-immersion thermometers 14

c. Formula for partial-immersion thermometers 15

d. Formula for calorimetric thermometers 16

e. Formula for Beckmann thermometers .. 16

5.4. Number and choice of test points 16

6. Common Thermometers and Factors Affecting Their Use 17

6.1. Total-immersion thermometers .. 17

6.2. Partial-immersion thermometers 17

6.3. Low-temperature thermometers 19

6.4. Beckmann thermometers 19

6.5. Calorimetric thermometers 20

7. Thermometer Design 21

7.1. Materials of construction .... 21

7.2. Scale design and workmanship 21

7.3. Scale dimensions 22

7.4. Reference point 22

7.5. Marking of partial-immersion thermometers 22

8. Special Notes . 23

8.1. Glass changes 23

a. Temporary changes 23

b. Permanent changes 24

8.2. Pressure effects 24

8.3. Lag 24

8.4. Separated columns 25

9. References 26

iii

Liquid-In-Glass Thermometry

Jacquelyn A. Wise

This Monograph, which supersedes NBS Monograph 90, contains information of general interest

to manufacturers and users of liquid-in-glass thermometers. Instructions explaining how to submit

a thermometer to the National Bureau of Standards for calibration are provided, and the techniques

and equipment, such as stirred liquid comparison baths, used in the calibration procedures are

described. A discussion of important principles of acceptable thermometer design and factors affect- ing their use is included. Listed are tables of tolerances reflecting good manufacturing practices

and reasonably attainable accuracies expected with liquid-in-glass thermometers. The calculation of corrections for the temperature of the emergent stem is given in detail for various types of thermometers and conditions of use.

Key words: Calibration; emergent stem; liquid-in-glass thermometer; reference point; stirred liquid

comparison bath; temperature scale.

1. Introduction

It is the responsibility of the • National Bureau of

Standards (NBS) to accurately reproduce the Inter- national Practical Temperature Scale of 1968 [l] 1 as

a basis for the uniform measurement of temperature

throughout the scientific and industrial community of

the United States. Because of this responsibility, NBS

accepts for calibration with reference to this scale

selected types of temperature-measuring instruments

[2] for use as reference or working standards where

precise temperature measurements are required. Certain liquid-in-glass thermometers are among the

instruments accepted.

This Monograph is intended for those who may

wish to submit thermometers for calibration or who

desire information on the use of liquid-in-glass

thermometers for precise temperature measurements.

Practices employed at the NBS in the calibration of

these thermometers are discussed. Also included is a brief discussion of the International Practical Temperature Scale of 1968, a description of the calibration

equipment, and the accuracy capability of liquid-inglass thermometers. Details of good thermometer design

and factors affecting their use are presented in a copious manner.

2. Thermometer Calibration Services

at the NBS

The liquid-in-glass thermometer is one of many

precision instruments calibrated by the NBS. A complete description of calibration services offered by

the NBS appears in NBS Special Publication 250 [2]

which can be obtained by writing to the Office of

Technical Information and Publications, National

Bureau of Standards, Washington, D. C. 20234.

Supplements to NBS Special Publication 250 are issued

periodically indicating any changes in these services.

2.1. Kinds of Thermometers Accepted for

Calibration

Not all thermometers classified as liquid-in-glass are acceptable for calibration by the NBS. In general

they must be of an acceptable design and workman3 Figures in brackets indicate the literature references at the end of this Monograph.

ship, and capable of being placed in the existing cali- bration facilities. The type known as laboratory or chemical thermometers, consisting of a solid stem

with graduation lines and numbers permanently

etched or placed on the stem, are regularly accepted.

Others approved for calibration are Beckmann, cal- orimetric, and enclosed scale (Einschluss) laboratory

thermometers. Industrial or mechanical type thermometers with special mountings can be accepted for

test if they can be inserted in the comparison baths, or if the thermometer can be easily detached from the

mounting.

Any thermometer, such as a household thermometer,

consisting of a paper, plastic or metal mounting containing the scale graduations and attached to the

unmarked glass thermometer by metal clips, is not

acceptable for calibration. Maximum self-registering

mercury-in-glass clinical thermometers are no longer

tested at the NBS.

1
It is advisable to contact the liquid-in-glass thermometry laboratory at NBS if there is any doubt

concerning the acceptability of a thermometer for

calibration. Every effort will be made to assist and

satisfy the needs of the scientific and industrial

community with problems involving temperature

measurement.

2.2. Preliminary Examination

Every thermometer submitted for test must be

uniquely identified by a serial number and pass a preliminary examination before final acceptance. These

thermometers are viewed under a microscope having a magnification of 15 or 20X to assure that the mercury

and capillary are clean. Any foreign matter found in

the capillary or bulb that, in the judgment of the

laboratory personnel, might tend to make the thermometer readings erratic, is reason for rejection.

Glass chips or oxides of mercury in the capillary or bulb are considered foreign matter that can cause

the thermometer to indicate different readings at different periods of time. [For example, if a small

chip of glass is located in the capillary at the 30 °C

indication, each time the mercury column advances

past this point, it could cause the reading of the thermometer to vary for temperatures above 30 °C, because

of different quantities of gas that may be trapped

around the chip. The movement of the chip to different

locations in the capillary, or the trapping of mercury

around the chip when the mercury column recedes,

would also cause erroneous readings.]

Other reasons a thermometer may be ineligible for

test are given below:

fa) Defective design or workmanship.

(b) Part of graduated scale not usable.

(c) Errors in scale graduation or numbering.

(d) Unsuitable bulb glass or inadequate

annealing.

(e) Inadequate gas filling.

(f) Cracks in the glass.

A complete list of all possible causes for rejection

is not feasible. The prime consideration in the preliminary examination is that the thermometer be

capable of precise, reproducible readings.

2.3. Reports of Calibration

In most instances a Report of Calibration will be

issued by NBS for every liquid-in-glass thermometer

submitted for test that is found free from serious

defects as determined by the preliminary examination.

In order to receive a Report of Calibration, the thermometer must be calibrated at two or more calibration

points. If only one point is requested, a Report of Test will be issued.

The Report of Calibration contains the corrections

determined for each point requested and an estimate

of the uncertainties associated with the corrections.

Also stated on the document are the agency or firm

requesting the test, the trade mark and serial number

on the thermometer, the NBS test number and completion date, and explanatory notes defining the

conditions under which the results of the test are

applicable. When necessary, accompanying the Report

of Calibration is a sheet explaining how to calculate

the corrections for emergent stem. If the thermometer

is of the metastatic (Beckmann) type, the report will

be accompanied by a second sheet containing a table

of setting factors (See Sec. 6.4) enabling the user to apply the calibration results for settings other than

the 20 °C setting for which the corrections are re- ported. A facsimile of a Report of Calibration is shown in figures 1 and 2. Any departure from the conditions under which

the corrections were obtained, as stated on the Report

of Calibration, may significantly change the values of

the corrections. Conditions of immersion are particularly important (Sec. 6). It should be emphasized

that the estimates of error assigned to the scale cor- rections do not assure the user of this accuracy in a temperature measurement.

2.4. General Instructions to Applicants

for Tests

Testing will be conducted in accordance with the

policies of NBS as described in NBS Special Publication 250. The cost of calibration will depend on

the number of calibration points requested, the temperature range, and the quantity of thermometers

submitted. For tests not specifically outlined in the

above publication, NBS should be consulted. If the

required measurements appear feasible, and, in the

opinion of NBS, sufficiently important to justify the

work, such tests will be undertaken for a special fee

determined by the nature of the work and time in- volved. In all requests for test the following procedures

and information are pertinent.

a. Initial Arrangements

A letter or purchase order requesting the test must

be sent to NBS either with the thermometer or separately. No work can be undertaken unless both the

thermometer and letter or purchase order have been

received. Information in the request for test should

include the quantity and serial numbers of the thermometers sent, the calibration points required, (See

Sec. 5.4) and the suggested method for return shipment. If it is desired that the thermometer be insured

upon return, a statement to this effect must appear on the request, and a value assigned; otherwise, the

thermometer will be returned uninsured.

NBS will assign a test number to each calibration

request and acknowledge the receipt of the thermometer. On the acknowledgment will be stated the

estimated completion date and estimated cost of

calibration. Any foreseeable difficulty that may be

encountered involving the calibration will be mentioned on the acknowledgment, as well as the name

of someone in the testing laboratory who can be

contacted if questions arise.

2
U.S. DEPARTMENT OF COMMERCE

NATIONAL 3UREAU OF STANDARDS

INSTITUTE FOR BASIC STANDARDS

WASHINGTON, D.C. 20234

REPORT OF CALIBRATION

LIQUID-IN-GLASS THERMOMETER

TESTED FOR: NATIONAL BUREAU UF STANDARDS

DIVISION 22L, SECTION 11

MARKED: SURETY 198692

RANGE: -2 TO +102 DEGREES C IN 0.2 DEGREE

THERMOMETER CORRECTION

READING (IPTS-68)**

-.06 C .06 C

20.00 .13

40.00 .05

60.00 .04

80.00 .06

100.00 .04

** AL L TEMPERATURES IN THIS REPORT ARE BASED ON THE INTERNATIONAL

PRACTICAL TEMPERATURE SCALE OF 1968, IPTS-68. THIS TEMPERATURE SCALE

WAS ADOPTED BY THE INTERNATIONAL COMMITTEE OF WEIGHTS AND MEASURES AT

ITS MEETING IN OCTOBER, 1968, AND IS DESCRIBED IN • • THE INTERNATIONAL

PRACTICAL TEMPERATURE SCALE OF 1968," METROLOGIA, VOL. 5, NO. 2, 35

(APRIL 1969).

ESTIMATED UNCERTAINTIES IN THE ABOVE CORRECTIONS 00 NOT EXCEED 0.05

DEGREE UP TO 102 DEGREES C .

FOR A DISCUSSION OF ACCURACIES ATTAINABLE WITH SUCH THERMOMETERS SEE

NATIONAL BUREAU OF STANDARDS MONOGRAPH 150, L I QUI 0-1 N- GLASS

THERMOMETRY .

IF NO SIGN IS GIVEN ON THE CORRECTION, THE TRUE TEMPERATURE IS HIGHER

THAN THE INDICATED TEMPERATURE; IF THE SIGN GIVEN IS NEGATIVE, THE TRUE

TEMPERATURE IS LOWER THAN THE INDICATED TEMPERATURE. TO USE THE CORRECTIONS PPOPERLY, REFERENCE SHOULD BE MADE TO THE NOTES GIVEN BELOW.

THE TABULATED CORRECTIONS APPLY FOR THE CONDITION OF TOTAL IMMERSION OF

THF BULB AND LIQUID COLUMN. IF THE THERMOMETER IS USED AT PARTIAL IMMERSION, APPLY AN EMERGENT STEM CORRECTION AS EXPLAINED IN THE ACCOMPANYING

STEM CORRECTION SHEET.

TEST NUMBER 31H1-74

COMPLETED 5-9-74

Figure 1. Facsimile of page 1 of a Report of Calibration.

3
PAGE 2

THE TABULATED CORRECTIONS APPLY PROVIDED THE ICE-POINT READING, TAKEN

AFTER EXPOSURE FOR NOT LESS THAN 3 DAYS TO A TEMPERATURE OF ABOUT Z3> DEGREES C (73 DEGREES F), IS -0.06 C . IF THE ICE-POINT READING IS FOUND

TO BE HIGHER (OP LOWER) THAN STATED, ALL OTHER READINGS WILL 3E HIGHER

(OR LOWFR) BY THE SAME AMOUNT. IF THE THERMOMETER IS USED AT A GIVEN

TEMPERATURE SHORTLY AFTER BEING HEATED TO A HIGHER TEMPERATURE, AN ERROR

OF 0.01 ,DFGR EE OR LESS, FOR EACH 10-DEGREE DIFFERENCE BETWEEN THE TWO

TEMPERATURES, MAY BF INTRODUCED. THE TABULATED CORRECTIONS APPLY IF THE

THERMOMETER IS USED IN ITS UPRIGHT POSITION; IF USED IN A HORIZONTAL

POSITION, THE INDICATIONS MAY BE A FEW HUNDREDTHS OF A DEGREE HIGHER.

FOR THE DIRECTOR,

INSTITUTE FOR BA/S TANDARDS

TEST NUMBER 311-11-74

COMPLETED 5-9-74

/ CHIEF, TEMPERATUP

HEAT DIVISION

SECTION

Figure 2. Facsimile of page 2 of a Report of Calibration.

4
b. Shipping Instructions

To assure safe arrival of the thermometers, they

should be packed firmly in their individual cases. A rigid material, such as wooden slats or corrugated

paper, can be wrapped around the thermometer case

as an additional aid against breakage. The package

should contain enough packing material to absorb any

shock that it may receive. Included with each shipment should be a packing list stating the number of

thermometers shipped, the name of the company submitting them, and, if applicable, the company's

purchase order number.

Unless otherwise specified, the thermometers will

be returned via the best method in the judgment of

NBS. Shipping charges, both to and from the NBS,

will be paid by the applicant. All possible care will

be taken in handling thermometers at NBS, but the

risk of damage either in shipment or testing must be

assumed by the agency, firm or individual submitting

them.

3. Definitions

The principle features of a solid-stem liquid-in-glass

thermometer are shown in figure 3. Not all of the

features shown would necessarily be incorporated in

any one thermometer.

-BULB -STEM IE l "" l' "H

CONTRACTION CHAMBER

AUXILIARY_

SCALE IMMERSION

LINE MAI SCALE

Figure 3. Principle features of a solid-stem liquid-in-glass

thermometer.

Bulb: The reservoir for the thermometer liquid.

The bulb of a thermometer will contain a volume

equivalent to a specific number of degrees of the scale

depending upon the coefficients of expansion of the

thermometric liquid and bulb glass. For mercury in a bulb made of "normal" glass, the bulb volume is equivalent to approximately 6,222 times the volume

of a 1 degree length of the capillary on the scale for

Celsius thermometers, or 11,200 times the volume of a 1 degree length of the capillary on the scale for

Fahrenheit thermometers. For organic thermometric

liquids with higher coefficients of expansion than

mercury, the bulb volumes are correspondingly less. Stem: The glass capillary tube through which the

thermometric liquid advances or retreats with changes

in temperature.

Main Scale: The scale graduated in degrees or

multiples or submultiples of degrees; in many in- stances the main scale constitutes the only scale. Auxiliary Scale: A short scale including a reference

temperature such as the ice point, to provide a means

for checking the thermometer for a change in cali- bration with time (see Sec. 7.4). This scale is added

when a suitable reference temperature is not included

in the range of the main scale. Expansion Chamber: An enlargement at the top

end of the capillary bore having a volume equivalent

to not less than the volume of a 20 mm length of un- changed capillary. Smaller chambers are not regarded

as expansion chambers. The expansion chamber is

provided to prevent the buildup of excessive pressures

in gas-filled thermometers as the liquid filling ad- vances toward the top of the scale (see Sec. 7.1).

Contraction Chamber: An enlargement of the capillary bore which serves to reduce a long length of

capillary or to prevent contraction of the entire liquid

column into the bulb. This chamber is introduced

below the main scale or between the main scale and

an auxiliary scale. Reference Point: A reference temperature, such as the ice point or steam point, used periodically to check the thermometer for changes in bulb volume.

(See Sec. 5.2). The reference point can be included

in the main scale or on an auxiliary scale. Total-Immersion Thermometer : A thermometer designed to indicate temperatures correctly when the

bulb and the entire liquid column is exposed to the

temperature being measured. (See the definition for

complete-immersion thermometer.)

Partial-Immersion Thermometer: A thermometer

designed to indicate temperatures correctly when the

bulb and a specified portion of the stem is exposed

to the temperature being measured. The remaining

portion of the stem, referred to as the emergent stem,

will be at the ambient temperature, usually different

from the temperature being measured. Such thermometers are generally marked with an immersion line to indicate the proper depth of immersion.

Complete-Immersion Thermometer : A thermometer

designed to indicate temperatures correctly when the

whole thermometer, including the expansion chamber,

is subjected to the temperature being measured. In gasfilled thermometers the reading will be different for

complete, as compared to total immersion, as a result

of the effect of temperature on the gas pressure in

the thermometer (see Sec. 8.2). Although the differ- ence in readings under the two conditions is particularly significant at high temperatures, it is also

significant at moderate temperatures if the bulb and

expansion chamber are both relatively large.

Calibration Points: The temperatures on the thermometer scale (i.e., 0°C) where calibrations are performed and corrections reported.

5
Accuracy: The accuracy of a measurement refers

to the difference between the measured value and the

true value of the quantity being measured. In this

Monograph the accuracy of a given thermometer refers

to its ability to indicate temperatures correctly on the

International Practical Temperature Scale of 1968 [1]

within the uncertainty stated (See tables 5-12) provided all corrections are applied and the thermometer is used in the same manner as when it was calibrated.

The accuracy attainable is principally limited by the

characteristics of the thermometer itself (See Sec. 6).

Instability of the thermometer glass, capillary forces

at the surface of the thermometric liquid, nonuniformity of capillary bore, and inaccuracies in scale

graduation are among the important factors. With

partial-immersion thermometers, uncertainties in cor- rections for the emergent stem may greatly limit the

accuracy. Observer errors are also involved, but with

care these can usually be made relatively small.

Precision: The precision of measurement refers to the degree of agreement amongst repeated measure- ments at a given time of the same quantity.

4. Temperature Scales and Standards

The scale to which measurements of temperature

should ultimately be referred is the Thermodynamic

Kelvin Temperature Scale (TKTS). Values of temperature expressed on the TKTS are designated by

the symbol T. The unit of temperature is the Kelvin,

symbol K, which is a base unit of the Systeme Inter- nationale (SI), and is defined as "the fraction

1/273.16 of the thermodynamic temperature of the

triple point of water" [3] . Because of the difficulties that are encountered in

the practical realization of the TKTS, it has been

necessary to define and utilize practical temperature

scales. The International Temperature Scale and defining text was first adopted in 1927 and later revised

in 1948. The Eleventh General Conference of Weights

and Measures in 1960 changed the name of the scale to the International Practical Temperature Scale

(IPTS) of 1948 and adopted a revised text of the

scale [4] , although numerically the scale was not

changed. In 1968, in accordance with the power given

to it by Resolution 8 of the Thirteenth General Conference of Weights and Measures, the International

Committee of Weights and Measures adopted the Inter- national Practical Temperature Scale of 1968 [1],

henceforth referred to as IPTS-68. The IPTS-68 re- placed the International Practical Temperature Scale

of 1948 and may be expressed either as a Kelvin scale or as a Celsius scale. The present Celsius scale has its zero 0.01 K below

the triple point of water (essentially the ice point).

The value of a temperature expressed on the Thermodynamic Celsius Temperature Scale is designated by

the symbol t and is related to the value on the TKTS by

t = T - 273.15 K.

The unit of the Celsius Scale is the degree Celsius,

symbol °C, which by definition is equal in magnitude

to the Kelvin.

Values of temperature expressed on the International Practical Kelvin Scale are designated by the

symbol TC8, and values of temperatures expressed on

the International Practical Celsius Temperature Scale

are designated by the symbol £i;8 . The relationship

between Tr,$ and t68 is

Ai8 = T68 — 273.15 K.

The units of Te $ and t 6a , like the thermodynamic

scales, are the Kelvin, symbol K, and degree Celsius,

symbol °C.

Due to the use of more sophisticated equipment and

the ability to measure with more accuracy the defining

fixed points, the new temperature scale more closely

agrees with thermodynamic temperatures. This scale,

IPTS-68, is intended to provide scientific and industrial laboratories throughout the world with a com- mon basis for stating temperatures. Calibrations of

thermometers at NBS, therefore, are made with ref- erence to values of temperature on the IPTS-68.

Shown in Table 1 is the approximate difference in

degrees Celsius between the values of temperature

given by the IPTS-68 and the IPTS-48 [1] . The differ- ences are listed in two separate sections for convenience

and clarity. It can be seen, by studying these values,

that the correction is important if quality control in

the laboratory is to be maintained to the nearest

0.01 °C. If, on the other hand, accuracies no better

than the nearest 0.1 °C are desired, the correction

becomes less significant in the liquid-in-glass thermometer region (—200 to +600 °C) of temperature

measurements.

Although values of temperatures on the IPTS-68

are expressed in degrees Celsius, thermometers that are graduated on the Fahrenheit Scale can be cali- brated with reference to the IPTS-68 by using the

conversion formula:

temperature value in °F = 9/5

(temperature value in °C) + 32

The National Bureau of Standards has been performing calibrations with reference to the IPTS-68

since July, 1969. On all Reports of Calibration and

Reports of Test issued after this date, it has been

clearly indicated that the new scale was used. In the range of temperatures normally covered by

liquid-in-glass thermometry, the IPTS-68 is defined

by four fixed points: the equilibrium between the

liquid and vapor phases of oxygen (normal boiling

point of oxygen) at — 182.962 °C; the equilibrium

between solid, liquid, and vapor phases of water

(triple point of water) at +0.01 °C; the equilibrium

between the liquid and vapor phases of water (nor6
Table 1. — Approximate difference ( t,s — tus), in degrees Celsius,

between the values of temperature given by the IPTS—68 and IPTS—48

la. For the range -180°CtoO°C.

te3 °C 0 -10 -20 -30 -40 -50 -60 -70 -80 -90 -100

-100 0.022 0.013 0.003 -0.006 -0.013 -0.013 -0.005 0.007 0.012 - 0 0.000 0.006 0.012 0.018 0.024 0.029 0.032 0.034 0.033 0.029 0.022

lb. For the range 0 °C to 1070 °C.

f./C 0 10 20 30 40 50 60 70 80 90 100

0 0.000 -0.004 -0.007 -0.009 -0.010 -0.010 -0.010 -0.008 -0.006 -0.003 0.000 100 0.000 0.004 0.007 0.012 0.016 0.020 0.025 0.029 0.034 0.038 0.043 200 0.043 0.047 0.051 0.054 0.058 0.061 0.064 0.067 0.069 0.071 0.073 300 0.073 0.074 0.075 0.076 0.077 0.077 0.077 0.077 0.077 0.076 0.076 400 0.076 0.075 0.075 0.075 0.074 0.074 0.074 0.075 0.076 0.077 0.079 500 0.079 0.082 0.085 0.089 0.094 0.100 0.108 0.116 0.126 0.137 0.150 600 0.150 0.165 0.182 0.200 0.23 0.25 0.28 0.31 0.34 0.36 0.39 700 0.39 0.42 0.45 0.47 0.50 0.53 0.56 0.58 0.61 0.64 0.67 800 0.67 0.70 0.72 0.75 0.78 0.81 0.84 0.87 0.89 0.92 0.95 900 0.95 0.98 1.01 1.04 1.07 1.10 1.12 1.15 1.18 1.21 1.24 1000 1.24 1.27 1.30 1.33 1.36 1.39 1.42 1.44

Examples showing the use of these tables are given below to help clarify any difficulty that may be encountered.

I Standard thermometer reading — 36.56 °C

Correction from NBS Report of Calibration + .06 True temperature IPTS-18 -36.50 °C

Correction from the above table at — 36.50 °C + .02 True temperature IPTS-68 -36.48 °C

II Standard thermometer reading 98.32 °F

Correction from NBS Report of Calibration — .02 True temperature IPTS-48 98.30 °F

Converted correction from the above tables* — .02 True temperature IPTS-68 98.28 °F

*The converted correction is obtained by:

A. Convert the Fahrenheit temperature to Celsius 98.30 °F = 36.83 °C.

B. Find the correction from the table at 36.83 °C. It is -0.01 °C.

C. Convert this correction to Fahrenheit by multiplying by 9/5.

-0.01 °C X 9/5 « -0.02 °F.

mal boiling point of water) at 100 °C; and the equilibrium between solid and liquid phases of zinc

(freezing point of zinc) at 419.58 °C. Temperatures

in the range -182.96 to 630.7 °C are defined in

terms of a standard platinum resistance thermometer

that has been calibrated at the four fixed points, with

interpolations and extrapolations between and beyond

these points accomplished by employing specified

equations [1].

When the highest accuracy is required in a calibration, the thermometer indications are compared di- rectly with temperatures obtained using a standard

platinum resistance thermometer. At NBS all calibrations are performed in this manner, with the exception

of the ice point ( See Sec. 5.2 ) . If a lower accuracy is required, one of several mercury-in-glass thermometers

with ranges and graduated in the intervals listed below may be used as standards for total-immersion

comparisons.

Range

Smallest

graduation

Auxiliary

scale

°C

0 to 50

°C

0.1 0.2

0.1 0.2

0.5

°C

0 to 100 50 to 100 atO

atO

atO

100 to 200

200 to 300

Partial-immersion thermometers, known as "like

standards," can be maintained for the calibration of

thermometers manufactured to similar specifications.

7
These standards are calibrated for stem-temperature

conditions expected to prevail during the use of these

thermometers or for specified stem temperatures. This

use of like standards eliminates the need for many of

the precautions necessary when dissimilar thermometers are compared and permits the direct comparison

of the indications of similar thermometers as long as

the bulbs are at the same temperature and the stem

temperatures are essentially the same for all of the

thermometers under comparison.

All of these liquid-in-glass standards should be

calibrated with reference to the IPTS-68 through

comparisons with a standard platinum resistance

thermometer.

5. Calibration

In most instances, the determination of the liquidin-glass thermometer scale corrections is accomplished

by comparing its scale indications with a known temperature from a platinum resistance thermometer or mercury-in-glass thermometer standards. This comparison is achieved by placing the standard and the

thermometers under test in a series of stirred liquid

comparison baths (See Sec. 5.1c). A discussion of

the equipment needed, the procedure followed, additional corrections that may be necessary, and the

choice of calibration points is given in the following

sections.

5.1. Equipment

a. Ice Bath

An ice bath can be easily assembled and consists

of a container, a siphon tube, ice and distilled water. A Dewar flask, approximately 36 cm deep and 8 cm

in diameter, can serve as a container for the ice. A vessel of this type is preferable, since the melting

of the ice is retarded by the insulating properties of

the Dewar flask. A siphon is placed in the flask to enable excess water to be removed as the ice melts.

The clear or transparent portion of commercially

purchased ice, or ice made from distilled water, can

be used. The ice is shaved or crushed into small chips

measuring 2 to 5 mm. The flask is one-third filled

with distilled water and the shaved ice is added.

This mixture is compressed to form a tightly packed

slush and any excess water is siphoned off. Before

the bath is used, adequate time (15 to 30 min.) should

be given for the mixture to reach a constant temperature throughout.

Ideally there should be as much ice in the flask as

possible, with the small spaces between the chips filled with distilled water. It will be necessary periodically

to add ice and to remove the excess water while the

bath is being used to maintain this ideal consistency.

If care is taken to prevent contamination of the ice

and water, the ice point can be realized to better than

0.01 °C by this means.

b. Steam Bath

A schematic drawing of a steam bath is shown in

figure 4. Steam produced from the boiler circulates

within a double-walled steam jacket permitting free

circulation of steam around the thermometers sus- pended within this space. A provision is made both

for relieving any excess pressure in the space sur- rounding the thermometers and for determining the excess pressure by means of a small differential

manometer.

r

THERMOMETER

SPACE IN —

STEAM JACKET

THERMOMETER

AIRJACKET

CONDENSER

BOILER

'M li

TO HEATING COIL

Figure 4. Schematic drawing of steam bath.

When the steam bath is used as a fixed-point apparatus, a barometer is a necessary accessory, since

the temperature of the steam depends upon the pre- vailing atmospheric pressure. The usual adjustments

are made to the barometer reading, including any

necessary corrections for the value of local acceleration of gravity, for the difference in height between

8
the steam bath and the barometer, and for any excess pressure above atmospheric in the steam jacket. After

the corrected pressure reading is obtained, the temperature of the steam can be derived from the values

given in Table 2. With a barometer accurate to 0.1

mm Hg, this procedure is capable of an accuracy of

0.002 to 0.003 °C (0.004 to 0.005 °F). The Fortin

type barometer will usually suffice for all but the most

exacting measurements.

The steam bath can also be used as a comparison

bath, with the temperature of the steam being determined at the time of test by means of a previously

standardized thermometer. This method, which does

not require the use of a barometer, may be preferable,

particularly when a platinum resistance thermometer

can be used as the standard.

c. Comparison Liquid Baths

At NBS two types of stirred liquid baths are used

for comparison calibrations in the range —110 to 540 °C (-166 to 1004 °F). Each is equipped with a stirring unit to provide a uniform temperature

throughout the medium and a controlled current to the heating coils for proper temperature regulation.

A 5 to 7 cm thickness of insulation surrounding the

baths and an insulated cover is provided to help minimize heat loss. Fitted into the top cover is a holder

containing the thermometers. This holder can be ro- tated, enabling each thermometer to appear in the

field of view of a vertically adjustable telescope at- tached to each bath.

Table 2. — (Thermometric) condensation temperature of steam [5]

[Asterisk (*) indicates change in integer]

Pressure in mm mercury (standard)

p 0 1 2 3 4 5 6 7 8 9

Temperature in degrees of International Practical Temperature Scale of 1968

500 88.674 0.726 0.778 0.830 0.882 0.935 0.987 *0.039 *0.090 * 0.141 510 89.193 .244 .295 .347 .398 .449 .499 .550 .601 .652 520 89.702 .753 .803 .853 .904 .954 * .004 * .054 * .104 * .154 530 90.203 .253 .303 .352 .402 .451 .500 .550 .599 .648 540 90.697 .746 .795 .843 .892 .941 .989 * .038 * .086 * .135

550 91.183 .231 .279 .327 .375 .423 .471 .518 .566 .614 560 91.661 .709 .756 .803 .851 .898 .945 .992 * .039 * .086 570 92.133 .179 .226 .274 .320 .367 .413 .460 .506 .552 580 92.598 .644 .690 .736 .782 .828 .874 .920 .965 * .011 590 93.056 .102 .147 .193 .238 .283 .328 .373 .418 .463

600 93.5079 .5527 .5975 .6422 .6868 .7315 .7760 .8204 .8648 .9092 610 93.9534 .9976 * .0419 * .0860 * .1300 * .1740 * .2179 * .2617 * .3055 * .3493 620 94.3930 .4366 .4802 .5237 .5671 .6105 .6538 .6972 .7404 .7835 630 94.8266 .8696 .9126 .9555 .9985 * .0413 * .0841 * .1268 * .1694 * .2120 640 95.2546 .2972 .33% .3819 .4242 .4665 .5087 .5508 .5929 .6351

650 95.6771 .7190 .7609 .8027 .8445 .8862 .9280 .9696 * .0112 * .0526 660 96.0941 .1355 .1769 .2182 .2595 .3007 .3419 .3830 .4240 .4650 670 96.5060 .5469 .5878 .6286 .6693 .7100 .7506 .7912 .8318 .8724 680 96.9128 .9532 .9936 * .0339 * .0741 * .1143 * .1546 * .1947 * .2347 * .2747 690 97.3147 .3546 .3945 .4343 .4741 .5138 .5535 .5931 .6327 .6722

700 97.7117 .7511 .7906 .8300 .8693 .9085 .9477 .9869 * .0260 * .0651 710 98.1042 .1431 .1821 .2210 .2598 .2986 .3373 .3761 .4148 .4534 720 98.4920 .5305 .5690 .6074 .6458 .6842 .7225 .7608 .7990 .8372 730 98.8753 .9134 .9515 .9896 * .0275 * .0654 * .1033 * .1411 * .1789 * .2107 740 99.2544 .2922 .3298 .3673 .4049 .4424 .4798 .5172 .5546 .5920

750 99.6293 .6666 .7038 .7409 .7780 .8151 .8522 .8893 .9262 .9631 760 100.0000 .0368 .0736 .1104 .1472 .1839 .2205 .2571 .2937 .3302 770 100.3667 .4031 .4395 .4760 .5123 .5486 .5848 .6210 .6572 .6934 780 100.7295 .7656 .8016 .8376 .8736 .9095 .9453 .9811 * .0169 * .0528 790 101.0885 .1242 .1598 .1954 .2310 .2665 .3020 .3376 .3730 .4084

9
The type of bath shown in figure 5 is suitable when

the medium is liquid at room temperature. It consists

of two cylindrical wells of different diameters with

connecting passages at the top and bottom. The heating

coil and stirrer are located in the smaller well, leaving

the larger well unobstructed for the insertion of the

thermometers. The fluid is forced past the heating

coils, through the bottom opening into the larger well,

around the thermometers, and back into the smaller

well through the connecting passage at the top.

STIR DRIVEHEATING —

COILS

AIR SPACE

SPACE

BETWEEN

TUBES

BEARING

THERMOMETER

HOLDER

INSULATION

SUPPORT

Figure 5. Stirred liquid bath.

The bath illustrated in figure 6 is designed for use with a medium that is solid at room temperature. A

bath of this type is used at NBS for high temperature

calibrations. Two coaxial cylinders are arranged in

such a way as to permit the medium to circulate between the walls of the two cylinders and through the

inner cylinder by means of openings at the top and

bottom. The stirring propeller is situated near the

bottom of the inner cylinder, leaving the majority of

the space for the reentrant tubes into which the thermometers are inserted. The heater coils are wound

on the outside of the outer cylinder. Both types of

10

_i

20

_l

'I'fi tit i,

!j «, '.>'<'!

cm

- INSULATION

-TESTING AREA

-AIR SPACE

- HEATING COIL

Figure 6. Stirred high temperature bath using liquid having

freezing point above room temperature.

baths are designed to shield the thermometers from

direct radiation from the heating units.

For calibrations in the range 1 to 99 °C (34 to 210 °F) water is used as the bath liquid. One grade

of petroleum oil is used between 100 and 200 °C

(212 to 392 °F) and a second grade between 200 and

300 °C (392 and 572 °F). The oils must not have

flash points below the highest test temperatures, nor

be too viscous to prevent adequate stirring at the

lower test temperatures.

Calibrations from -1 to -110 °C (30 to -166 °F)

are made in a cryostat similar to the one described

by Scott and Brickwedde [6] . The cryostat, shown in

figure 7, consists of an inner Dewar flask, D, which

contains the bath liquid. This flask is surrounded by

liquid nitrogen contained in the outer Dewar flask, C. The rate of heat transfer between the bath liquid and

the liquid nitrogen is retarded by evacuating the space

10
between the walls of the inner Dewar flask through

the side tube, M, which is connected to a vacuum

system. Vigorous stirring of the bath liquid is maintained by the propeller, I, which circulates the liquid

around the walls of the stirrer tube, P, similar to the

flow of the medium in the high temperature bath.

The temperature of the bath is thermostatically controlled by heater coils, J, wound on the outside of the

stirrer tube. The thermometers are immersed inside

the stirrer tube, thus shielding them from the heater

coils. The bath liquid is a five-component mixture containing by weight 14.5 percent of chloroform, 25.3

percent of methylene chloride, 33.4 percent of ethyl

bromide, 10.4 percent of transdichloroethylene, and

16.4 percent of trichloroethylene. This mixture freezes

at approximately -150 °C (— 238 °F), but readily

absorbs moisture and becomes cloudy at somewhat

higher temperatures. For this reason calibrations are not performed in this bath below — 110 °C

(-166 °F).

A comparison measurement can be made at approximately — 196 °C (boiling point of nitrogen) and — 183 °C (boiling point of oxygen). A silvered Dewar

flask with a narrow transparent vertical strip is used

as a container for the liquid nitrogen or oxygen. The

liquid is agitated by bubbling nitrogen or oxygen gas

in the corresponding liquid through a glass tube with an outlet near the bottom of the flask.

5.2. Determination of Scale Corrections

Thermometers submitted to NBS for test are generally calibrated by starting at the lowest test point

requested and advancing to the higher test points. In most cases the ice point is the lowest point. Ice is packed firmly around the thermometer which has been

placed in an ice bath and immersed to the proper

depth as determined by the type of thermometer. The

thermometer is gently tapped before reading to prevent

the sticking of a falling meniscus. Care is taken not

to tap too vigorously, as this may cause the mercury

to rebound to an erroneously high reading.

The thermometer scale corrections quoted in the

Report of Calibration apply as long as the ice-point

reading remains the same as observed during the NBS

calibration. Subsequent changes in the ice-point reading of the thermometer will result from small changes

in the glass of the thermometer bulb which affects its volume. The volume of the capillary also changes, but

the volume of mercury contained in the stem is so

small, in comparison to the amount of mercury in the

bulb, that changes in the stem volume can usually be

ignored. As a result, changes in the ice-point reading

of the thermometer, taken after an exposure of not less

than 3 days at a temperature of approximately 23 °C

(73 °F), will be reflected by similar changes in readings at each point along the scale. Therefore, when

the correction at the ice point is found to be higher

(or lower) than that observed at the time of calibration, the other reported scale corrections will be higher

11
(or lower) by the same amount. An example is given

below:

Original Corrections from NBS Report

1 emperature Correction

+ 0.011 °C -0.011 °C

10.000 - .015 20.000 - .020 30.000 + .008 40.000 - .033 50.000 .000

A later ice-point reading may be +0.019 °C. This means that the ice-point correction will be —0.019 °C

and a new set of corrections should be made by subtracting 0.008 from all of the original - corrections.

The new table would look as follows:

Temperature Correction

+ 0.019 °C -0.019 °C

10.000 - .023 20.000 - .028 30.000 .000 40.000 - .041 50.000 - .008

Once a thermometer has been calibrated, an ice point

check is all that is necessary to obtain a current cali- bration, provided the thermometer has not been

abused.

Ice-point readings on the thermometers being cali- brated are not taken after each test point on the

scale. For thermometers graduated below 300 °C or 600 °F, ice points are taken before the comparison

calibrations and 3 days (with the thermometer at room

temperature) after the last test point to assure that

the bulb has recovered within acceptable limits. With

thermometers graduated above 300 °C or 600 °F, an

ice point is taken and it is immediately tested at the

highest test point on the scale. After a rest period of

3 days at room temperature a second ice point is taken. The agreement between the first and second

ice point must be within the stated accuracy limit of

the thermometer, or it is deemed unsuitable for cali- bration and no further testing is done.

The ice point is the only test temperature taken in the manner described above. Comparison measure- ments are made with the temperature of the bath

slowly increasing at a steady rate, which does not

exceed one scale division in 3 to 10 minutes [7] . All

thermometers are read using a 10 power telescope,

which is attached to each calibration bath and per- pendicular to the thermometers. The telescope is a

necessity if errors due to parallax are to be avoided.

When a liquid-in-glass thermometer is intended to be used as a standard, an ice point should be taken

after heating it at each test temperature. The adjusted

scale correction is determined by adding the ice-point

reading to the current correction at the corresponding

test temperature. The example shown above is modified

in this way.

Test Current Ice-Point Reading After Adjusted

Temperature Correction Heating to Test Temperature Scale Correction

+ 0.019 °C -0.019 °C +.019 0.000 °C

10.000 - .023 +.019 - .004 20.000 - .028 +.017 - .011 30.000 .000 +.010 + .010 40.000 - .041 .000 - .041 50.000 - .008 -.012 - .020

When this thermometer is used as a standard, the ice

point should again be taken after each calibration

point. To obtain the actual temperature of the bath,

the ice-point correction is added to the appropriate

adjusted scale correction and thermometer reading.

If the calibration temperature is 25 °C, the thermometer reads 24.983 °C, and the ice-point reading taken

after the calibration is +0.014 °C, the actual temperature is computed as follows:

Thermometer reading 24.983 °C

Interpolated Adjusted Scale Correction — .001

Ice-point correction — .014

Actual Temperature of Bath Medium 24.968 °C

This method eliminates the need to wait 3 days for

the bulb to recover and avoids the error due to the

ice-point depression (See Sec. 8.1a) that appears

when a thermometer is heated. The standard can be

used at any time and at any temperature with no con- cern about the change in bulb volume, provided the

ice point is taken after it is used.

It is advisable to use two liquid-in-glass standards

when calibrating, in order to detect reading errors and maintain a cross check of the standards. The

calibration procedure can best be described by following a hypothetical calibration of four thermometers,

T] through T4 . Table 3 shows hypothetical observations taken in

obtaining the corrections applicable to the thermometers at 20 °C. For simplification, all of the entries in

the table reflect perfect thermometer performance with

a temperature rise of 0.01 °C between each observation

and no observer error.

12
Table 3. — Comparison of test thermometers

with liquid-in-glass standards

Ice-point readings of test thermometers

1

T9 1 O 1 ^

Observer A + 0.02 + .02 + .02 - .02

-0.02 - .02

- .02 + .02

+0.02 + .02 + .02 - .02

0.00 Observer B .00 Mean ice points .00

.00

Ice-point corrections

Thermometer comparisons

Observer A reading

left to right 19.87 19.98 19.96 20.02 20.03 19.89 Observer A reading

right to left 19.88 19.99 19.97 20.03 20.04 19.89 Observer B reading

left to right 19.88 19.99 19.97 20.04 20.05 19.90 Observer B reading

right to left 19.89 20.00 19.98 20.04 20.05 19.90 Means 19.88 19.99 19.97 20.03 20.04 19.89,

Ice Points of Standards

Observer A

Observer B

Mean ice points

Ice-point corrections Adjusted scale corrections

-o.oi - .01 - .01 + .01 + .12

-0.08 - .08 - .08 + .08 + .04

Calculations of corrections

Correction to standards

Mean temperature,

each standard

Mean temperature

of all readings

Corrections to test thermometers

+0.13

20.01

+0.02

20.01

+0.04 -0.02 0.03

+0.12

20.01,

The first observations are the ice points of the

thermometers under test. The test thermometers are then mounted in the comparison bath between the two

standards. It is preferable to have two observers

(A and B ) . Observer A reads in the order left to right

as the thermometers appear in the table, and immediately repeats the observations in the order right to

left, while observer B records the data. Observer B

promptly reads in the same manner while observer A

records. The bath temperature is increasing linearly

with time and the observations are spaced uniformly

in time. For this reason the mean of the observations

with any one thermometer will correspond to the

mean temperature value of the comparison bath me- dium during the observations of all of the thermometers. Immediately after the comparison observations,

ice points of the two standards are observed and

recorded. With the ice point data and the adjusted

scale corrections for the standards, the temperatures

indicated by the standards are calculated, and an

overall mean temperature for the observations is obtained. This mean temperature is compared with the

mean of the observations for each thermometer to

obtain a correction to the scale of the thermometers.

The thermometer comparisons are repeated in the same manner at the next higher test point until the calibration is completed.

When a platinum resistance thermometer is used

as a standard, the sequence of observations is the

same, except that the one resistance thermometer is read in place of the separate observations of two liquidin-glass standards. For more information on platinum

resistance thermometers refer to NBS Monograph 126.

Platinum Resistance Thermometry, available from the

Superintendent of Documents, U. S. Government

Printing Office, Washington, D. C. 20402.

5.3. Corrections for Emergent Stem

When a thermometer is calibrated and used under

conditions of total immersion, no difficulty is encountered when the reported scale corrections are to be

applied. The temperature of the thermometer bulb

and the portion of the stem containing the mercury

is definitely defined as the temperature of the bath

medium. The corrections apply as given on the report,

when this thermometer is used at total immersion.

Occasionally it becomes necessary to use a total- immersion thermometer with a portion of the stem

emergent from the bath medium. The temperature of

the environment above the bath, or apparatus containing the thermometer, may differ markedly from

the temperature of the thermometer bulb. It is also

possible to have pronounced temperature gradients

along the length of exposed mercury column. A cor- rection can be calculated to account for the difference

in temperature between the bulb and the emergent

stem. A reliable estimate of the mean temperature of

the emergent stem is required and should actually

be measured. The determination of the stem temperature should be repeated each time the thermometer is used in this way, or the accuracy of the correction

will depend upon the constancy of the environmental

temperature over a period of time. Significant variations in the temperature of the emergent stem may

occur due to air circulation and variations in ambient

temperature, even though the location of the thermometer does not change.

The same situation occurs in the case of partialimmersion thermometers. The reported scale corrections apply only for the indicated depth of immersion

and a particular stem temperature. If the thermometer

is used under conditions other than specified, the

reported scale corrections are no longer applicable,

and a stem temperature correction is required.

The following paragraphs describe methods for

determining stem temperatures and calculating corrections. It will be seen how important the stem

temperature correction is in relation to a desired

accuracy.

a. Measurement of Emergent-Stem Temperature

There are two methods available for measuring the

approximate mean temperature of the emergent stem. The first method consists of placing one or more small

13
auxiliary thermometers near the emergent stem as shown in figure 8(c). For a more accurate measure- ment faden or thread thermometers [8, 9] can he

used. These thermometers have long bulbs measuring

variously 5 to 20 cm, with wall thicknesses and bore

sizes nearly the same as the stem of an ordinary

thermometer. The bulb length is selected to approximate that of the emergent stem whose temperature is to be measured. The stem of the faden thermometer

has a finer capillary than the bulb and is usually

graduated in intervals of 2, 5, or 10 degrees Celsius.

Stem temperature measurements taken at NBS are based upon the use of faden thermometers whenever

possible.

A convenient method for measuring the emergentstem temperature of a total-immersion thermometer

that is used at partial immersion involves the use of a faden thermometer. The top of the faden thermometer bulb is placed on a horizontal plane with the top

of the mercury column of the thermometer whose stem

temperature is being measured. The faden thermometer chosen must have a bulb which is long enough to cover the vertical area of unknown temperature

gradient necessary to be measured. This sometimes

involves placing part of the faden thermometer bulb

in the bath medium, since the top portion of the

medium can be at a temperature different from the

temperature of the total-immersion thermometer bulb.

(This is especially true for measurements above

150 °C). The reading of the faden thermometer will

indicate the mean temperature value of the area sur- rounding the bulb, which is also the mean temperature

value of the adjacent portion of the total-immersion

thermometer stem. A faden thermometer used in this

manner is illustrated in figure 8(a).

If the stem temperature of a partial-immersion

thermometer is to be measured, a similar approach

is followed. In this case it is necessary to measure the

mean temperature from the immersion line to the top

of the mercury column of the partial-immersion thermometer. One or more faden thermometers with

appropriate bulb lengths are chosen to accomplish this

measurement. This procedure is shown in figure 8(b).

77^.

n 1

FADEN THERMOMETER

'BULB

FADEN

- THERMOMETER

BULB

. LIQUID COLUMN

OF THERMOMETER

IMMERSION LEVEL

AUXILIARY THERMOMETERS

..LIQUID COLUMN

OF THERMOMETER

(b) PARTIAL IMMERSION

7777 '/////

(c) PARTIAL IMMERSION

LIQUID COLUMN

OF THERMOMETER

(o) TOTAL IMMERSION

In calculating the emergent stem correction, it is convenient to express the length of the thermometer

stem adjacent to the faden bulb in terms of degrees on the thermometer scale. If a faden thermometer,

having a bulb which is 10 cm long, is used for a stem

temperature measurement, then the number of degrees

corresponding to the 10 cm length must be found by

measuring a portion of the thermometer scale. This

measurement should be made over the portion of the

graduated scale which was adjacent to the faden

thermometer bulb. This is particularly important with

high-temperature thermometers, where the length of a degree is generally not the same throughout the

entire length of the scale. In some instances the adjacent portion of the thermometer stem is not graduated.

This is especially true with partial-immersion thermometers in the area above the immersion line. This

ungraduated length between the immersion line and

the first graduation must be evaluated in terms of

scale degrees and included as part of the distance

covered.

b. Formula for Total-Immersion Thermometers

When a thermometer which has been graduated and

calibrated for use at total immersion is actually used

at partial immersion, the correction for the emergent

stem may be calculated by the general formula,

where

t

stem correction — kn (£ t

- t)

differential expansion coefficient of mercury

(or other thermometric liquid) in the particular kind of glass which the thermometer is made (see table 4),

number of thermometer scale degrees adjacent

to the faden thermometer bulb,

average temperature of n degrees of the thermometer stem (faden thermometer reading),

temperature of the thermometer bulb.

Figure 8. Schemes for measurement of emergent-stem

temperature.

The coefficient k varies for different kinds of

glass, or for different temperature intervals, i.e., differ- ent values of (t, — t). For purposes of computing the

emergent-stem correction, the value of k may be

considered as depending on the average of tx and t. Values of k as the function of {t, + t) /2 for two widely used thermometric glasses are given in table 4. If the kind of glass is not known, it is acceptable to use k = 0.00016 for mercury thermometers graduated in

degrees Celsius and k = 0.00009 for mercury thermometers graduated in degrees Fahrenheit.

The expansions of liquids such as alcohol, toluene,

etc., vary quite rapidly with the temperature causing

k to vary considerably for different temperature in- tervals. An approximate stem correction for such

thermometers may be calculated by setting the value

of k in the above equation as equal to 0.001 for Celsius

thermometers or 0.0006 for Fahrenheit thermometers.

Calculation of the stem correction may be illustrated

by the following example: A total-immersion thermometer indicates a reading of 90 °C in a bath when

1 L
Table 4. — Values of k for mercury-in-glass thermometers

Mean temperature k for "normal" glass k for "borosilicate" glass

2

For Celsius thermometers

0° 0.000158 0.000164

100 .000158 .000164 150 .000158 .000165 200 .000159 .000167 250 .000161 .000170 300 .000164 .000174 350 .000178 400 .000183 450 .000188

For Fahrenheit thermometers

0° 0.000088 0.000091 200 .000088 .000091 300 .000088 .000092 400 .000089 .000093 500 .000090 .000095 600 .000092 .000097 700 .000100 800 .000103

immersed to the 80 °C graduation mark on the scale. A 10 cm faden thermometer placed alongside the

thermometer is adjacent to the scale between the 60

and 90 °C graduations and indicates a stem temperature of 80 C C. For this case n = 90-60 or 30 degrees.

The stem correction is:

0.00016 x 30 (90-80) = +0.048 °C.

This correction is added to the corrected thermometer

reading to obtain the actual temperature of the bath

medium. Note that when the temperature of the emergent stem is lower than the bath temperature, the sign

of the correction is +, since the thermometer would

indicate a higher temperature reading if immersed

properly.

If a faden thermometer was not available in the

above example, the emergent-stem temperature could

be estimated by suspending a small auxiliary thermometer above the bath adjacent to the thermometer.

The bulb of the auxiliary thermometer would be

placed at the center of the emergent stem or at the

85 °C graduation. The reading of the auxiliary thermometer will indicate the approximate mean temperature of the 10 degrees (80° to 90 °C) emergent from

the bath. For this correction the value for n would

be 10. If the auxiliary thermometer indicates a reading of 60 °C, the stem correction would be:

0.00016 x 10 ( 90-60) = +0.048 °C.

This method is not usually as reliable as the method

involving the use of a faden thermometer [9]

c. Formula for Partial-Immersion Thermometers

The scale corrections for partial-immersion thermometers calibrated at NBS are applicable when the

thermometer is immersed to the immersion mark and,

unless otherwise requested, for the unspecified stem

temperatures which prevailed over the comparison

baths at the time of calibration. Frequently it is necessary to report scale corrections which are applicable when specified mean temperatures of the

emergent stem are requested. In such cases the emergent stem temperatures are measured during calibration and the observations are corrected as necessary

to account for any differences found between the

specified stem temperatures and the stem temperatures

observed during test. The magnitude of the stem cor- rection will be proportional to the difference between

the specified and observed stem temperatures, and

may be calculated for Celsius mercurial thermometers

by using the following formula:

stem correction = 0.00016 /; { uv — Ms)

where

Up = specified mean temperature of the emergent

stem ( for which reported scale corrections

apply),

tabs = observed mean temperature of the emergent

stem (faden thermometer reading), n = number of scale degrees equivalent to the

length of emergent stem (including the evaluated area above the immersion line).

15
This formula may also be used to correct the indications of a partial-immersion thermometer, when, during use, the actual stem temperatures differ from the

specified ones for which the scale corrections apply.

d. Formula for Calorimetric Thermometers

The stem correction is often important when thermometers are used for differential temperature measurements, as in calorimetry (Sec. 6.5). The correction

may be computed from the following formula, which

involves the difference between the initial and final

readings, provided the mean temperature of the stem

remains constant.

Stem correction = kd (u + £f — / — t) , where

k = factor for relative expansion of glass and

mercury,

h = initial reading,

tF = final reading,

/ = scale reading to which the thermometer is immersed,

t = mean temperature of the emergent stem,

d = tF — u.

This correction must be applied (added if positive,

subtracted if negative) to the difference of the readings to give the actual temperature difference.

Example: The thermometer was immersed to the

20° mark: the initial reading, U, was 25 °C; the final

reading, tF, was 30 °C; and the stem temperature was

20 °C. The correction is:

0.00016 x 5 (25 +30—20—20) = +0.012 °C.

Since the difference between U and U was 5°, the

actual difference between the initial and final temperature readings was:

tF — ti + correction = 5.012 °C.

e. Formula for Beckmann Thermometers

The formula used to compute the stem temperature

correction for Beckmann thermometers (Sec. 6.4) is similar to the one used for calorimetric thermometers.

The formula given below is applicable provided the

thermometer is immersed near the zero degree indication on the scale and the temperature of the stem

remains constant.

stem correction — kd (S + ti + tr —t) ,

where

k = factor for relative expansion of glass and

mercury,

ti = initial reading,

tr = final reading,

t = mean temperature of the emergent stem,

d = tF — ti S = setting of the thermometer (Sec. 6.4).

A Beckmann thermometer should not be used with

any part of the lower portion of the stem exposed to ambient temperature. Since this part may contain

5 to 10 times more mercury per centimeter than the

graduated portion, a large and uncertain error will

be introduced if this section is not in the bath medium.

If it is unavoidable, and such a thermometer must

be used in this way, the necessary correction may be

computed from the above formula, provided S in the

formula is replaced by 5 + m, where m is the number

of degrees the temperature of the thermometer must

be lowered to bring the meniscus from the zero mark

on the scale to the point of immersion.

If the thermometer is immersed to some point other

than the zero mark, as would ordinarilv be the case with thermometers having the zero graduation at the

top of the scale, the differential stem correction may

be calculated from the above formula if S is replaced

by S + m. The formula is applicable whether the

point of immersion is on the scale or below it, provided

the points at which readings are made are above the

point to which the thermometer is immersed.

5.4. Number and Choice of Test Points

A thermometer is usually calibrated at points spaced

uniformly over the entire range of the main scale. The number of calibration points chosen depends on

the range of scale, graduation interval, and accuracy

desired. The interval between the calibration points

should not be unnecessarily small, nor should it be

so large as to destroy confidence in interpolated cor- rections for temperature values between the calibration

points.

For thermometers not graduated above approximately 200 °C, it is generally accepted that the interval between test points should not exceed 100 scale

divisions, if the corrected temperature values between

the calibration points are to have an expected accu- racy of approximately one-half of one scale division.

If accuracies of one or two-tenths of a scale division are desired, it will be necessary to reduce the calibration interval to every 40 or 50 scale divisions. If a thermometer is graduated above 200 °C, a 40 to 50

scale division calibration interval is required to produce corrected temperature values with expected ac- curacies of approximately one-half of a scale division,

and a 20 to 25 scale division calibration interval is necessary for expected accuracies to be approximately one or two-tenths of a scale division.

The above results were derived from analysis of

calibration data taken on more than 50 thermometers

purchased from 1930 through 1956 for use as laboratory standards. The data indicated that there was considerable variation between individual thermometers

and that scale corrections obtained over a given inter- val for a particular thermometer were not sufficient to predict whether or not more calibration points were

required. The above studies were made with only a few of the many types of thermometers submitted to NBS for calibration, and may not necessarily be

16
applicable to other types. Experience with a particular

type of thermometer seems to be the most reliable

guide in the choice of its calibration points.

If a thermometer is submitted to NBS for calibration and the calibration points are not specified on

the purchase order, it will be tested at a reference

point and at intervals of approximately every 100

scale divisions. A calibration should never consist of

fewer than two points on the main scale, and should

always be tested at a reference point, whether on the

main scale or on an auxiliary scale.

6. Common Thermometers and Factors Affecting Their Use

A listing of tolerances and expected accuracies for

common types of liquid-in-glass thermometers, which

are accepted for calibration, are given in tables 5

through 12. The scale tolerances shown are chosen to be indicative of good manufacturing practice. When

a thermometer is manufactured, small errors in pointing (marks placed on a blank thermometer at various

temperatures to be used as guides for the placement

of the graduation lines) and graduating are inevitable.

These graduation marks are also subject to variations

due to the inherent properties of the glass. The toler- ances must be sufficiently restrictive to insure a satis- factory high-grade thermometer, and at the same time

not cause undue manufacturing difficulties. In addition to the scale tolerance limit, the error in

any temperature interval should not exceed 5 percent

of the nominal value of the interval. The purpose of

this requirement is to eliminate thermometers having

large corrections of alternating signs, which lead to uncertainties in the interpolation of scale corrections

between the calibration points.

The word "accuracy" used in these tables refers to the best values attainable in the use of thermometers

when all corrections are applied. The accuracy bounds

may seem broad in some instances, but the definite

limitations of liquid-in-glass thermometry become ap- parent when all factors are considered. For example,

if the scale is expanded by reducing the diameter of

the capillary, a practical limit is reached beyond

which capillary forces, in combination with the elasticity of the thermometer bulb, will prevent a smooth

advance or retreat of the mercury column. The move- ment of the mercury meniscus may be erratic and

occur in steps appreciably large in comparison to the

graduation interval. This is particularly true when

the temperature of the medium is decreasing. Less

rigid bulbs (relatively large diameters and/or thin

walls), as well as capillaries of small diameters, may

cause large "meniscus jumps." Excessively elliptical or flattened bores are not recommended for the same

reason. Therefore, increasing the length of a degree on the scale, for practical bulb sizes, improves thermometric performance only to a certain point. Beyond

this point precision of reading may readily be mistaken

for accuracy in temperature measurement. A study of

the effects of bulb and capillary dimensions on thermometer performance, made by Hall and Leaver [10],

provides valuable guidelines for design purposes.

Other factors such as ice-point changes, unless ex- actly accounted for, and differences in external pres- sure may also account for inaccuracies much greater

than the imprecision with which a scale having 0.1 or

0.2 degree graduations may be read.

6.1. Total-Immersion Thermometers

Thermometers pointed and graduated by the manufacturer to indicate correct temperatures when the

bulb and the portion of the stem containing the thermometric liquid are subjected to the temperature being

measured are known as total-immersion thermometers.

While these thermometers are designed for immersion

of all the mercury, it is not desirable to immerse the

portion of the stem above the meniscus. The heating

of this portion to high temperatures could cause ex- cessive gas pressures resulting in erroneous readings

and possibly permanent damage to the bulb. In practice, a short length of the mercury column

often must be left emergent from the bath or medium

being measured so that the meniscus is visible. If the

temperature difference between the bath medium and

its surroundings is large, an appreciable temperature

gradient may exist around the thermometer stem near

the surface of the bath. This condition becomes more

serious when a total-immersion thermometer is intentionally used at partial immersion. If either situation

exists, an emergent stem correction, as explained in

section 5.3b, will be necessary. The correction may be

as large as 20 Celsius degrees (36 Fahrenheit degrees)

if the length of the emergent liquid column and the

difference in temperature between the bath and the

space above it are large. Tolerances and accuracies

expected of total-immersion thermometers are given

in tables 5 and 6.

6.2. Partial-Immersion Thermometers

In many instances the use of a total-immersion

liquid-in-glass thermometer for temperature measure- ments is inconvenient or impossible. For this reason

partial-immersion thermometers are designed with

scales graduated to indicate correct temperatures when

the thermometers are immersed to specified depths. Unless otherwise stated, each Report of Calibration issued

by NBS gives corrections which are applicable for

temperatures prevailing above the comparison baths.

No stem temperature correction is necessary when

17
Table 5. — Tolerances for Celsius total-immersion mercury

thermometers

Temperature range in Graduation Tolerance Accuracy

degrees interval in in in degrees

degrees degrees

Thermometer graduated under 150 °C

°c

0 up to 150

0 up to 150

0 up to 100

1.0 or 0.5

.2

.1

0.5

.4

.3

0.1 to 0.2

.02 to .05

.01 to .03

Thermometers graduated under 300 °C

0 up to 100 Above 100 up to 300 .... 0 up to 100 Above 100 up to 200 ....

| 1.0 or 0.5

i

| 0.5 (

) 1.0

( 0.4

I -5

).l to 0.2

.2 to .3 .02 to .05

.05 to .1

Thermometers graduated above 300 °C

0 up to 300

Above 300 up to 500 .... 0 up to 300

Above 300 up to 500 ....

| 2.0

I 1.0 or 0.5

| 2.0

/ 4.0

j 2.0

( 4.0

0.2 to 0.5

.5 to 1.0 .lto .5

.2 to .5

Table 6. — Tolerances for Fahrenheit total-immersion

mercury thermometers

Temperature range in degreesGraduation

interval in degrees

Tolerance

in degiees

Accuracy

in degrees

Thermometers graduated under 300 °F

32 up to 300

32 up to 300

32 up to 212

2.0

1.0 or 0.5

.2 or .1

1.0

1.0 0.5

0.2 to 0.5 .lto .2 .02 to .05

Thermometers graduated under 600 °F

32 up to 212

Above 212 up to 600 .... | 2 or 1

f 1.0

I 2.0

0.2 to 0.5

.5

Thermometers graduated above 600 °F

32 up to 600 \ e f 4.0 0.5 to 1.0 Above 600 up to 950 .... | 0

\ 7.0 1.0 to 2.0 32 up to 600 ( 9

, ] 3.0 0.2 to 1.0 Above 600 up to 950 .... j zorl

( 6.0 .5 to 1.0

these thermometers are used under conditions similar

to those existing during calibration. However, if conditions differ, especially the temperature of the emergent stem, the necessary emergent stem correction

must be calculated as shown in section 5.3c. An un- steady or irreproducible environment surrounding the

emergent stem, t gether with the inherent difficulty

of estimating or measuring the emergent-stem temperature with sufficient accuracy, can contribute

markedly to the uncertainty of a given thermometer

indication. For these reasons tolerances and accuracies expected of partial-immersion thermometers,

as given in tables 7 and 8, are not as stringent as those for total-immersion thermometers.

Table 7. — Tolerances for Celsius partial-immersion

mercury thermometers

Temperature range in degreesGraduation

interval in degrees a

Toler- ance in degreesAccuracy h

in degrees

Thermometers not graduated above 150 °C

0 up to 100

0 up to 150

1.0 or 0.5

1.0 or 0.5

1.0

1.0

0.1 to 0.3

0.1 to 0.5

Thermometers not graduated above 300 °C

0 up to 100 Above 100 up to 300 ....

1.0

1.0

1.0

1.5

0.1 to 0.3

.5 to 1.0

Thermometers graduated above 300 °C

0 up to 300

Above 300 up to 500 .... j 2.0 or 1.0

f 2.5

\ 5.0

0.5 to 1.0 1.0 to 2.0

Table 8. — Tolerances for Fahrenheit partial-immersion

mercury thermometers

Temperature range in degrees

Graduation

interval in degrees a

Toler- ance in degrees

Accuracy b

in degrees

Thermometers not graduated above 300 °F

32 up to 212

32 up to 300

2.0 or 1.0 2.0 or 1.0

2.0

2.0

0.2 to 0.5

0.2 to 1.0

Thermometers not graduated above 600 °F

32 up to 212

Above 212 up to 600 ....

2.0 or 1.0 2.0 or 1.0

2.0 3.0

0.2 to 0.5

1.0 to 2.0

Thermometers graduated above 600 °F

32 up to 600 Above 600 up to 950 .... | 5.0 or 2.0 j 5.0 X

10.0

1.0 to 2.0

2.0 to 3.0

a Partial-immersion thermometers are sometimes graduated in smaller intervals than shown in these tables, but this in no way

improves the performance of the thermometers, and the listed tolerances and accuracies still apply.

b The accuracies shown are attainable only if emergent stem

temperatures are closely known and accounted for.

18
6.3. Low-Temperature Thermometers

The use of mercury-in-glass thermometers for low

temperature measurements is limited bv the freezing

point of mercury, which is -38.9 °C (-38.0 °F).

This limit may be extended to lower temperatures by

forming an eutectic alloy consisting of mercury and 8.5

percent by weight of thallium. The freezing point of

this alloy is approximately —59 °C (— 74 °F). However, small differences in the quantity of thallium

present have the effect of markedly raising the freezing point of the alloy. It has also been found that some thermometers containing this liquid have behaved erratically in the range of —59 to —57 °C.

Consequently, thermometers using a mercury-thallium

alloy as the liquid should not be used below —56 °C

(—69 °F).

Temperature measurements from —56 °C ( —69

°F) to approximately —200 °C (—328 °F) can be

made by using thermometers containing organic li- quids. Alcohol, toluene, pentane, or other organic

liquids, alone or in mixtures, have been used as fluids

for low temperature thermometers. All of these fluids

have limitations, and thermometers containing organic

liquids are not considered to be as reliable as thermometers containing mercury or mercury-thallium

alloy.

Organic liquids have the disadvantage of wetting a surface and leaving a film on the wall of the capillary

when the liquid column recedes. This may lead to significant errors in the temperature indications if sufficient precautions are not taken. The thickness of

the film on the capillary wall will depend, among other

things, on the viscosity of the liquid, the interfacial

action between the liquid and glass, and the rate at which the thermometer is cooled. Whenever possible

the rate of cooling should be slow with the bulb cooled

first, enabling the viscosity of the organic fluid in

the capillary to be kept as low as possible until the

final temperature is reached. This minimizes the

amount of liquid left on the capillary wall. Sufficient

time should always be allowed to assure complete

drainage. Under adverse conditions this may take an

hour or more.

In addition to good drainage characteristics, a satis- factory low-temperature fluid should not contain water,

dirt, or other foreign material which will separate

from the liquid. Because low-temperature thermometers are frequently designed for use above room

temperature, the vapor pressure of the liquid must

be low to prevent distillation at these higher temperatures. Any dye, added to the fluid for improved

visibility, should be chosen for good color fastness

with respect to light exposure or chemical action with

the organic liquid.

Tolerances and accuracies applicable to low-temperature thermometers are given in tables 9 and 10.

Table 9. — Tolerances for low-temperature total-immersion

thermometers

Temperature

range in degrees

Type of thermometerGraduation

interval in degrees

Toler- ance in degreesAccuracy

in degrees

Celsius thermometers

-35 to 0

-35 to 0 -56 to 0

-56 to 0 -200 to 0

Mercury

do

Mercurythallium. do

Organic,

liquid.

1 or 0.5

.2

.5

.2 1.0

0.5

.4

.5

.4 2.0

0.1 to 0.2

.02 to .05

.1 to .2

.02 to .05

.2 to .5

Fahrenheit thermometers

-35 to 32

-35 to 32

-69 to 32

-69 to 32

-328 to 32

Mercury

do

Mercurythallium. do

Organic,

liquid.

1 or 0.5

.2 lor .5

.2 2 or 1.0

1.0 0.5

1.0

0.5

3.0

0.1 to 0.2

.05 .lto .2

.05

.3 to .5

Table 10. — Tolerances for low-temperature partial-immersion

thermometers

Temperature

range in degrees

Type of ( thermometer

Graduation

interval in degrees

Toler- ance in degreesAccuracy

in degrees

Celsius thermometers

-35 to 0 -56 to 0 -90 to 0

Mercury

Mercurythallium. Organic

liquid.

1.0 or 0.5

1.0 or .5

1.0

0.5

.5

3.0

0.2 to 0.3

.2 to .3

.4 to 1.0

Fahrenheit thermometers

-35 to 32 -69 to 32 - 130 to 32

Mercury

Mercurythallium. Organic

liquid.

1.0 or 0.5

1.0 or .5

2 orl

11

5

0.3 to 0.5

.3 to .5

.8 to 2.0

6.4. Beckmann Thermometers

A metastatic, or Beckmann thermometer, usually of

the enclosed-scale type, is constructed in a manner

that permits mercury to be removed from, or added

to, the bulb, making it possible to use the same thermometer for differential temperature measurements in

various temperature ranges [11]. The scale usually

consists of 5 or 6 Celsius degrees, although some micro

types have a scale containing only 3 Celsius degrees.

19
The "setting" of a Beckmann thermometer refers

to the temperature of the bulb when the reading on

the scale is 0°. When the setting is changed, enabling

the thermometer to be used at a higher or lower temperature range, the quantity of mercury affected by a temperature change is not the same. Therefore, two

equal changes in temperature at different settings cause different indications on the scale, and a "setting

factor" must always be used to convert reading differ- ences into actual temperature differences whenever

the thermometer is used at any setting other than the one at which the scale was calibrated. These setting

factors combine corrections for the different quantities of mercury during equal temperature changes,

and the difference between the mercury-in-glass scale

and the International Practical Temperature Scale of

1968. Table 11 lists setting factors calculated for

thermometers of Jena 16'" 2 glass or, its American

equivalent, Corning normal. The scale calibrations for

Beckmann thermometers as reported by NBS are applicable for a setting of 20 °C. Consequently, the

Table 11. — Setting factors for Beckmann thermometers

Setting Factor Setting Factor

0 °C 0.9935 55 °C 1.0092

5 0.9951 60 1.0102 10 0.9967 65 1.0112 15 0.9984 70 1.0121 20 1.0000 75 1.0129 25 1.0014 80 1.0137 30 1.0029 85 1.0146 35 1.0042 90 1.0154 40 1.0056 95 1.0162 45 1.0070 100 1.0170 50 1.0082

As an illustration, suppose the following observations w

Setting = 25 °C. Lower reading

Stem temperature = 24 °C. Upper reading

Lower

Observed reading = 2.058 Correction from certificate = -(-0.005 Corrected upper reading

Corrected lower reading

Difference r Difference multiplied by setting factor (1.0014)

Emergent stem correction (see accompanying

stem correction sheet)

Corrected difference 1

ere made: = 2.058° = 5.127° Upper

5.127 -0.008

5.119

2.063

= 3.056

= 3.060

= + .004 = 3.064

setting factor is 1.0000 at this temperature. For a set- ting other than 20 °C, the observed temperature differ- ence must be multiplied by the appropriate setting

factor as shown in the example given below the table. For most Beckmann thermometers, the large bulb

is joined to a fine capillary, which is backed by a milk-glass scale, by a capillary of much larger diameter. This large capillary is a source of some uncertainty when the thermometer is used at partial

immersion and this portion is not entirely immersed.

For appropriate emergent-stem corrections refer to section 5.3e. Tolerance requirements for Beckmann thermometers

are given in table 12. Under the heading "Accuracy

of interval in degrees" is given the estimated accuracy

attainable in the measurement of any interval within

the limits of the scale. No tolerances for scale error

are given, although it is desirable that it be no larger

than 0.02 °C over a 1.0 °C interval.

Table 12. — Tolerances for Beckmann and calorimetric thermometers

Type of thermometer

Graduation in- terval in degreesAllowable change

in correction in degrees

Accuracy of interval in degrees

Beckmann 0.01 °C

.01 °C

.02 °C

.05 °F

.1 °F

0.01 over 0.5° interval for setting of 20 °C

0.02 over 1.5° interval 0.02 over 1.5° interval 0.04 over 2.5°

interval 0.15 over a

5°

interval

0.002 to 0.005 ....

.005 to .01

.005 to .01

Bomb calorimetric

Do

Do .01 to .02

Gas calorimetric ... .02 to .05

2 Certain commercial products and instruments are identified in this paper

in order to specify adequately the experimental procedure. In no case does such identification imply recommendation or endorsement by the National Bureau of Standards, nor does it imply that the products or equipment

identified are necessarily the best available for the purpose.

6.5. Calorimetric Thermometers

Calorimetric thermometers include a specialized

group of solid-stem mercury-in-glass thermometers

which are used for accurate differential measurements.

Since the accuracy of these thermometers at any one

temperature is of less importance than the accuracy

of the temperature intervals, no reference point is required.

Table 12 gives the scale error required of some

typical calorimetric thermometers. Like the Beckmann

thermometer, no tolerances for scale error are given,

but it is desirable that the scale corrections be no larger

than approximately five graduation intervals.

20

i
7. Thermometer Design

Reproducibility and accuracy of readings are influenced markedly by the design, choice of materials,

and actual construction of the thermometer. The cali- bration laboratory personnel exercise judgment in

deciding whether individual thermometers are likely to maintain a calibration; however, general recom- mendations for acceptable thermometer design and

construction are given in the following sections.

7.1. Materials of Construction

While the cleanliness of the thermometer bulb, bore,

and liquid filling have a pronounced effect upon the

performance of a thermometer, equally important is the proper choice of the glass from which the thermometer is manufactured. The thermometer, and

especially the bulb, must be made of glass suitable

for use in the temperature range indicated on the stem.

Some types of glasses commonly used in the manufacture of thermometer bulbs and reasonable upper

temperature limits are estimated by Thompson [12]

in table 13. Thompson's estimates are based upon the

work of Liberatore and Whitcome [13]. The results

show that significant changes in bulb volume may

occur if the bulb is heated for long periods of time

at temperatures higher than 130 °C (234 °F) below

the strain point of the bulb glass. The strain point of a

glass is defined as the temperature at which the glass

has a viscosity of 1014 - 5 poises [14]. Thermometers

may be used intermittently, to approximately 70 °C

(126 °F) of the strain point. It should be noted that

the use of a glass with a high strain point, such as

borosilicate glass, results in better thermometer performance and stability even in thermometers used at temperatures much lower than the exposure limits

given in table 13.

Table 13. — Temperature exposure limits for various thermometer glasses a

Strain Exposure limits

point

Continuous Intermittent

°C °C "F T °F

Corning normal 7560 500 370 700 H30* 1-805* Kimble R 6 490 360 680 420 790 Jena 16 III 495 365 690 425 795

Corning borosilicate 8800 529 400 750 460 860 Jena borosilicate 2954 548 420 790 480 900

Corning 1720 668 540 1005 600 1110

Jena Supremax 2955 665 535 995 595 1100

a From reference [12].

b *405 °C or 760 °F if Corning Standard Thermometer 0041

glass is used for the stem.

The thermometer must also be adequately annealed

to enable the bulb volume to remain reasonably stable

and causing only small changes in the thermometer

readings with continued use. This is especially important for a thermometer graduated above 300 °C or 600 F. The quality of the thermometer glass and the

adequacy of the annealing process may be judged by

the stability of the reference-point readings. A method

for testing bulb stability is described in The American

Society for Testing and Materials Method E77.

All high-temperature thermometers should be filled with a dry inert gas such as nitrogen under sufficient

pressure to prevent separation of the mercury at any

temperature indicated on the scale. Total-immersion

thermometers graduated above 150 °C or 300 °F must

be gas filled to minimize the distillation of mercury

from the top of the mercury column. An expansion

chamber at the top of the capillary or a specified

length of unchanged capillary above the highest graduation is essential for thermometers containing a gas. The gas must have an adequate area for compression

when the mercury is advanced toward the top of the

scale; otherwise, excessive pressure in the capillary

will cause the thermometer to burst.

For thermometers graduated below 150 °C or 300 °F a gas filling is optional, but is strongly rec- ommended. The mercury column of a vacuous thermometer will tend to separate easily if the thermometer

is inverted or subjected to a sudden shock.

7.2. Scale Design and Workmanship

Solid-stem thermometers must have the graduation

marks placed directly on the stem and opposite the

enamel back. If the thermometer is of the enclosedscale type, the graduated scale must be securely

fastened to prevent relative displacement between the

scale and the capillary, or a datum line should be

conveniently located to indicate at any time whether

the scale is in its original position. The graduation

marks should be clear cut, straight, of uniform width,

and in a plane perpendicular to the axis of the

thermometer.

The scale should be graduated in 1.0, 0.5, 0.2, or 0.1

degree intervals, or in decimal multiples. The divisions

should be numbered in such a manner that the identification of any graduation is not unnecessarily

difficult. Thermometers with scales graduated in 0.25

degree intervals, or submultiples, are sometimes diffi- cult to read and the discontinuance of their production

is desirable. If the thermometers are graduated in 0.1 or 0.2 degree intervals (or decimal multiples), every

fifth mark should be longer than the intermediate ones and a number should appear at every tenth mark.

Thermometers graduated in 0.5 degree intervals (or

decimal multiples) require three lengths of graduation

marks. These consist of alternating short and intermediate marks, with every tenth line distinctly longer

than the others. A number should appear at every

10th or 20th mark.

21
The scale must not be extended to temperatures

beyond which the particular thermometer glass is suited. A thermometer made of borosilicate glass, for

example, should never be graduated to 500 °C

(932 °F). It would be ruined in a short time if used

at that temperature.

7.3. Scale Dimensions

Although optimum line width depends in some

measure upon the intended use of a particular thermometer, coarse graduation marks do not represent

good design. If the thermometer indications are to be

observed precisely (for example to 0.1 of a division),

the width of the graduation marks should not exceed

0.2 of the interval between the center lines of the

graduations. In instances where the thermometer must

be read quickly or in poor light, and less precision is expected, somewhat wider lines may be acceptable.

The graduation marks must not be too closely

spaced. The closest permissible spacing depends upon

the fineness and clearness of the marks. In no case should the distance between center lines of adjacent

graduation marks on a solid-stem thermometer be less than 0.4 mm. The minimum permissible interval between graduation marks for an enclosed-scale thermometer is 0.3 mm if the lines are ruled on a milkglass scale: otherwise, the minimum is also 0.4 mm.

The minimum in no case represents good design, and

well-designed thermometers will have graduation intervals considerably larger than the specified minimum.

In order for a thermometer to be usable over the

entire range of the scale, the graduation marks must

not be placed too close to any enlargement in the

capillary. Appreciable errors may result if any of the

following conditions exist. (1) There is insufficient

immersion of the mercury in the main bulb or a capillary enlargement; (2) the graduation marks have

been placed over parts of the capillary that have been

changed by manufacturing operations; or (3) the

graduations are so close to the top of the thermometer

that excessive gas pressure results when the mercury

is raised to this level. The distances given below are considered as minimum limits commensurate with

good thermometer design:

fa) A 13 mm length of unchanged capillary

between the bulb and the lowest graduation, if the

graduation is not above 100 °C (212 °F); a 30 mm

length if the graduation is above 100 °C (212 °F).

( b ) A 5 mm length of unchanged capillary between an enlargement and the graduation next below,

except at the top of the thermometer.

(c) A 10 mm length of unchanged capillary between an enlargement, other than the bulb, and the

graduation next above, if the graduation is not above

100 °C (212 0 F) ; a 30 mm length if the graduation

is above 100 °C (212 °F).

(d) A 10 mm length of unchanged capillary above

the highest graduation, if there is an expansion chamber (see definitions, Sec. 3) ; a 30 mm length if there

is no expansion chamber.

7.4. Reference Point

Thermometers graduated above 150 °C or 300 °F,

or precision thermometers with an expected accuracy

of better than 0.1 °C or 0.2 °F when calibrated for

actual temperature measurement, must have a refer- ence point. The effects of changes in the bulb volume

on the thermometer indications may be followed

throughout the life of the thermometer by periodic

testing at the reference point. From the reference point

observations, the thermometer corrections can be kept

current as explained in section 5.2. If a suitable ref- erence point, such as the ice or steam point, is not

included in the range of the main scale, a short auxiliary scale containing a fixed point should be provided.

To prevent the thermometer from being unduly long,

a contraction chamber may be introduced between the

auxiliary scale and the main scale. Any auxiliary scale

must have graduations identical to those on the main

scale, both dimensionally and in terms of temperature,

and they must extend for a short interval both above

and below the reference point. Similarly, when the

main scale ends near a reference point, the graduations

must be continued for a short interval beyond the

reference temperature.

Reference points are not needed on thermometers

intended for differential measurements (such as calorimetric thermometers), nor on thermometers graduated

below 150 °C or 300 °F, if they are not to be cali- brated to an accuracy of better than 0.1 °C or 0.2 °F.

7.5. Marking of Partial-Immersion

Thermometers

Partial-immersion thermometers must be plainly

marked "partial immersion" or the equivalent (for

example, "76 mm immersion"), or a conspicuous line

permanently placed on the stem to indicate the proper

depth of immersion. This line must not be less than

13 mm above the top of the bulb. Special partialimmersion thermometers, made for use in a specific

manner or instrument (for example, viscometers and

flash-point testers where the thermometer is held in a ferrule or other mounting arrangement suited to the

instrument), need not be marked.

22
8. Special Notes

The following brief notes on the characteristic behavior of mercury-in-glass thermometers are added to aid the user in understanding the behavior of these

thermometers, and to better utilize the information

contained in the Reports of Calibration.

8.1. Glass Changes

The changes which occur in the glass of a thermometer bulb after first heating to a high temperature

within the acceptable exposure limits of the glass and

subsequent cooling to ambient temperatures, are an

involved function of time and temperature. They will

depend upon the thermal history of the glass (both

during manufacture and previous use), the time of

exposure to the high temperature, and the rate of

cooling. Evidence from many investigations [13, 15,

16] seems to indicate that when a glass is held indefinitely at some fixed temperature, density (and volume)

changes proceed toward a preferred density corres- ponding to a quasi equilibrium condition characteristic of the particular kind of glass and the temperature.

Since these changes involve molecular rearrangements,

they proceed more rapidly at high temperatures where

the viscosity of the glass is lower, and the molecular

mobility consequently higher. For this reason, a close

approach to quasi equilibrium may be reached in the

order of hours at annealing temperatures, while infinite

time may be required at much lower temperatures.

If a glass that has been heated to a high temperature is allowed to cool rapidly, it will be seen that

equilibrium is not reached at the lower temperatures

during cooling, and an equilibrium density more

nearly corresponding to the high temperature is "frozen" into the glass. This characteristic behavior

of glass has a lasting effect on the performance of

liquid-in-glass thermometers. For the entire lifetime

of the thermometer it may retain a "memory" of the

thermal history at the higher temperatures.

The techniques of good manufacture are designed to produce in the thermometer glass a state which will result in maximum stability for the range of temperature indicated on the scale. To achieve perfect stability

for all conditions of use is not possible in thermometer

manufacture; therefore, changes in the ice-point readings are observed periodically. The changes observed

at the ice point are reflected at all points on the scale

by the same magnitude and sign, since they are the

result of changes in the bulb volume (see Sec. 5.2)

(changes in the stem have very little effect). Because

of this behavior of glass, the changes in the bulb

volume can be either temporary or permanent.

a. Temporary Changes

Upon heating to a high temperature, the bulb of a thermometer will expand from its initial state. After

a short period of time, an equilibrium condition corresponding to that particular high temperature will

appear to be reached. If the thermometer is cooled

slowly through critical temperature regions, the glass

will nearly return to its initial state, and the ice- point reading will show no change. If, on the other

hand, the thermometer is cooled rapidly (such as cooling naturally in still air), the bulb will retain a portion of its expanded condition, and the ice-point

reading will be lower than the reading taken before

heating. This phenomenon is known as "zero, or ice- point depression." Thermometers which have been

heated to high temperatures recover from this ice- point depression in an unpredictable way, and fre- quently there will be no significant recovery after a period of one year at room temperature. Since the

ice-point depression has a reproducible value, ice- point readings may be used reliably to show changes

in the volume of the thermometer bulb with time and

use, provided the thermometer is allowed to cool in

still air and the ice point is taken within a reasonable

period of time, not to exceed one hour, after being

heated.

Thermometers used below approximately 100 °C will

usually exhibit a relatively rapid recovery from the

ice-point depression, and the original bulb volume will recover within the equivalent of 0.01 or 0.02 degrees

C in approximately 3 days. This phenomenon has an important bearing on the precision attainable with

mercury thermometers, and must be taken into consideration, especially in the range of 0 to 100 °C.

If a thermometer is used to measure a given temperature, it will indicate an erroneously low value if it has, within a short period of time, previously been

exposed to a higher temperature. With the better

grades of thermometric glasses the error resulting from

this hysteresis will not exceed (in the interval of

0 to 100 °C) 0.01 of a degree for each 10-degree

difference between the temperature being measured

and the higher temperature to which the thermometer

has recently been exposed. With the best glasses the error may only be a few thousandths of a degree for

each 10-degree difference. The errors due to this

hysteresis become somewhat erratic at temperatures

above 100 °C. For these reasons it is customary, in

precision thermometry, to apply a scale correction

based upon an ice-point reading taken immediately

after the temperature measurement (see Sec. 5.2).

Where the range of temperature is small and the

time between observations is short (as in the use of

calorimetric thermometers), it is more satisfactory,

each time the thermometer is used, to first heat to the highest temperature to be measured, so that all of

the depression has taken place before the observations

are begun. The condition to be observed is that the

time required for observations is so short that no

appreciable recovery shall have taken place during

this time. As this condition is fairly well satisfied in

calorimetric work, and as it is the only one for which

23
consistent measurements of the same temperature

interval can be made repeatedly, calorimetric thermometers should be used in this way.

b. Permanent Changes

A "secular change" in thermometer glasses, which

may progress with time, results in a non-recoverable

decrease in the bulb volume as indicated by an in- crease in the ice-point reading. At room temperature

there may be a gradual change which will continue

for years, but at high temperatures the changes will

be markedly accelerated. With better grades of thermometer glasses the change will not exceed 0.1 °C

over a period of many years, provided the thermometer has not been heated to temperatures above approximately 150 °C. Initially, at high temperatures, the

secular change usually progresses more rapidly, but

with continued heating and time it tends toward a lower rate of change. The rate of secular change will

depend upon the kind of glass used in the thermometer

bulb and the particular heat treatment given the

thermometer in manufacture. Thermometers manufactured according to good practices will evidence

only small secular changes. However, thermometers

made of glass unsuitable for the temperature range

indicated on the scale, or improperly annealed, may

show changes as large as 12 °C or 21 °F after heating

for approximately 200 hours at high temperatures

[17]. Permanent changes in the bulb volume have

also been observed when thermometers have been

repeatedly cycled at low temperatures (between — 30

and +25 °C) [18].

When using thermometers for high temperature

measurements, one must use care to avoid overheating.

After only a few minutes of heating the thermometer

at a temperature higher than its intended range, the

increased gas pressure above the liquid column may

cause a permanent distortion of the bulb resulting in lower thermometer indications.

8.2. Pressure Effects

Since glass exhibits elastic properties, the volume

of a thermometer bulb will change when either the

internal or external pressure changes. Therefore, at a given temperature, the reading of a thermometer in a horizontal position will differ from the reading in a

vertical position. Thermometer readings will also vary

with altitude. Changes of approximately 0.1 °C

(0.2 °F) per atmosphere have been observed for

many thermometers with bulb diameters between 5

and 7 mm. This value can be used with some confidence for estimating the probable effect of an external

pressure change. The effect of change of internal

pressure is approximately 10 percent greater.

Formulas for both external and internal pressure

coefficients have been derived by Guillaume [19]

He found the relation,

yS e = k

where Rt . and Ri are external and internal radii of

the bulb, and k is a constant containing elastic properties of the glass and a conversion factor for expressing the volume change in terms of change of

thermometer reading in degrees. In the above formula,

the external pressure coefficient /? is defined as the

change in scale reading in degrees resulting from a change of 1 mm Hg in external pressure. For Celsius

thermometers, Guillaume found a value of 5.2 X 10-5

degrees C/mm Hg for k, but Hall and Leaver [10],

by experiment, found a value approximately 25 percent

lower for their thermometers. In cases where an ac- curate correction is necessary, the value, f3e , should

be determined experimentally. A simple apparatus for

this determination is shown in figure 9.

Figure 9. Apparatus for measurement of the external pressure

coefficient.

The internal pressure coefficient, is more diffi- cult to determine accurately, but may be calculated

from the value, /?e , by means of the relation,

0, = pe + 1.5 X 10-5

for thermometers in Celsius degrees, or

pi = /?e + 2.7 X 10-5

for thermometers graduated in Fahrenheit degrees.

8.3. Lag

Practically all theoretical treatments concerning

thermometer lag are based on the assumption that

Newton's law of cooling is applicable (that the rate of change in the reading of the thermometer is proportional to the difference between the thermometer

temperature and the bath temperature). Consequently,

when a thermometer is immersed in any medium, it does not indicate the temperature immediately, but

approaches it asymptotically. A detailed discussion

of this subject has been given by Harper [20]

If the temperature of the medium is varying uniformly, the thermometer always indicates what the

temperature was at some previous time. The thermom24
eter readings are said to "lag" behind the temperature

of the medium by an amount which may or may not

be negligible, depending upon the rapidity of the

temperature variation and the physical characteristics

of the thermometer. In this case, the lag, A, may be

defined as the interval in seconds between the time

when the bath reaches a given temperature and the

time when the thermometer indicates that temperature.

This lag is dependent upon the dimensions and material

of the thermometer bulb, the medium surrounding

the thermometer and the stirring rate of the medium.

If a thermometer is suspended in still air, the lag

may be as much as 50 times that of the same thermometer when it is immersed in a well-stirred water

bath. Since the value of the lag for mercurial thermometers is not large (from 2 to 10 seconds in a well-stirred

water bath), it is not generally necessary to correct

for it. For example, if two thermometers, one having

a lag of 3 seconds and another of 8 seconds, are read

simultaneously in a bath with the temperature rising

at a rate of 0.001 degree in 5 seconds, the former will

read 0.001 degree higher than the latter, due to the

lag. In the intercomparison of thermometers, the rate of temperature rise can usually be kept small, making

the lag correction negligible.

A second interpretation of thermometer lag involves

immersing a thermometer in a bath where the temperature of the medium remains constant. A certain

time must elapse before the thermometer reading

agrees with the temperature of the medium to 0.1

of a degree, and still longer for agreement to be

within 0.01 of a degree. In this case the lag, A, is the

time required for the original difference in temperature between the thermometer and bath medium to be

reduced to 1/e (that is 1/2.7) of itself. In a length

of time 4 A the difference will be approximately 1.5

percent of the original difference, and in a length of

time 7 A approximately 0.1 percent. Determinations

of A for solid-stem laboratory thermometers, representative of American manufacture, have yielded values

of approximately 2 to 3 seconds in a well-stirred water

bath. Figure 10 shows the approach of thermometer

readings to the water bath temperature for three

selected thermometers having different values of A.

If the thermometer having A = 2.2 seconds is initially

at 25 °C. and is immersed in a constant temperature

bath at 75 °C, the thermometer reading will be within

0.05 °C (0.1 percent of 50 °C) of the bath temperature in 15 seconds, and within 0.01 °C in 19 seconds.

The curve showing A = 3.1 was obtained for an American Society for Testing and Materials (ASTM)

specification 56C calorimetric thermometer with an

outside bulb diameter of 7.9 mm and a bulb length

of 44 mm. The value of A = 2.2 was found for an ASTM 7C thermometer having bulb dimensions of 5.4

by 12 mm. The third curve, where A = 1.7, was obtained for a bulb with dimensions of 5.4 by 34 mm.

It is probable that most solid-stem thermometers of

American manufacture will have values of A lying

within the range of the three curves shown. It will

be noted that, according to Harper [20] , the value

o.io -

20 25 30

TIME, seconds

40

Figure 10. The approach to temperature in a stirred water bath

for three thermometers with typical lag constants.

of A for a given thermometer in a well stirred oil bath

will be approximately twice its value in a water bath.

For a thermometer which is used to measure temperature changes (as in calorimetry )

, it has been

shown by White [21] that the lag enters into the

observations in such a way as to be eliminated from

the results in applying the usual radiation corrections.

Therefore the lag need not be considered, providing

the initial and final readings are made when the temperature is varying uniformly. This is not strictly

true, however, in the case of some Beckmann thermometers, which have no true value of A, as is ex- plained in the paper referred to above.

8.4. Separated Columns

Many inquiries are received concerning separated

mercury columns which occur especially during shipment. Since no means of avoiding such occurrences has yet been found, some directions for joining the

mercury may be helpful and are described below.

(a) The bulb of the thermometer may be cooled

in a solution of common salt, ice, and water (or other

cooling agent) to bring the mercury down slowly into

the bulb. If the salt solution does not provide sufficient

cooling, carbon dioxide snow (dry ice) may be used.

Since the temperature of dry ice is approximately

25
—78 °C ( —108 °F), and mercury freezes at approximately —40 °C (—40 °F), the mercury will solidify.

Cool only the bulb and never the stem or mercury

column. Moderate tapping of the bulb on a rubber

stopper or similar soft spongy object, or the application of centrifugal force, by swinging the thermometer

in a short arc (i.e. use of centrifugal force), usually

serves to unite the mercury in the bulb. Care must be

taken to warm the top of the bulb first, so that pres- sures in the bulb due to expanding mercury may be

relieved.

(b) If there is a contraction chamber above the

bulb or an expansion chamber at the top of the thermometer, the mercury can sometimes be united by

warming the bulb until the column reaches the sep- arated portions in either enlargement. Great care is necessary to avoid filling the expansion chamber completely with mercury, which might produce pressures

large enough to burst the bulb. (The expansion chamber should never be more than 2/3 full.) Joining the

mercury is more readily accomplished if the quantity

in either cavity has first been shattered into droplets

by tapping the thermometer laterally against the hand.

This procedure should not be used if it requires

the thermometer to be heated above 260 °C (500 °F)

and the bulb should never be heated in an open flame.

(c) As a last resort, especially for thermometers

having no expansion chambers, small separated portions of the column can sometimes be dispersed by

warming into droplets tiny enough to leave space for

the gas to by-pass. The thermometer is heated, and

the droplets are collected by the rising mercury

column.

The procedure for thermometers containing organic

liquids is similar. Separated liquid in the stem can be

vaporized and permitted to drain down the capillary.

Another method consists of gently tapping the stem

above the separation against the palm of the hand,

forcing the organic liquid to break away from the

wall of the capillary and flow down the bore to join

the main column.

Minute gas bubbles, which are sometimes found

along the surface of the mercury in the thermometer

bulb, may be collected by "washing" the bulb with

a large gas bubble. Bring all of the mercury into the

bulb as outlined in section (a). Hold the thermometer

in a horizontal position and gently tap it against the

hand to form a large gas bubble. Force the bubble to travel around the walls of the bulb by rotating the

thermometer and tapping it against the palm of the

hand. When the entire surface has been "washed"

rotate the bubble to the top of the bulb and reunite

the mercury as described above.

All of these manipulations require patience, and

experience is helpful, but they will yield results if care is used. A convenient method of ascertaining

that all of the liquid has been joined is a check of the

ice point or some other reference point on the scale.

9. References

fl] "The International Practical Temperature Scale of 1968,"

Metrologia, Vol. 5, No. 2, 35 (April, 1969).

[2] Calibration and Test Services of The National Bureau of Standards, NBS Spec. Publ. 250 (1970 Edition), Part 5. (Copies available from NBS on request).

[3] Comptes Rendus des Seances de la Treizieme Conference

Generale des Poids et Mesures (1967-1968), Resolutions 3 and 4, p. 104.

[4] Stimson, H. F., The International Practical Temperature

Scale of 1948, J. Res. Nat. Bur. Stand. (U.S.). 65A

(Phys. and Chem.), No. 3, 139-145 (May-June 1961).

[5] Based on the data of Osborne, N. S., and Meyers, C. H., A formula and tables for the pressure of saturated water vapor in the range 0 to 374 °C, J. Res. NBS 13,

1 (1934) RP691.

[6] Scott, R. B., and Brickwedde, F. G., A precision cryostat

with automatic temperature regulation, BS J. Res. 6, 401 (1931) RP284.

[7] American Society for Testing and Materials Designation

E77-72, Calibration at Temperatures Other Than Fixed

Points, Section 11.2.

[8] Buckingham, E., The correction for emergent stem of the mercurial thermometer, Bui. BS 8, 239 (1912) SI 70. [9] Pemberton, L. H., Further consideration of emergent col- umn correction in mercury thermometry, J. Sci. Instr. 41, 234 (1964).

[10] Hall, J. A., and Leaver, V. M., The design of mercury

thermometers for calorimetry, J. Sci. Instr. 36, 183

(1959).

[11] Ween, Sidney, "The Beckmann Differential Thermometer:

Its Principles of Construction and Application," Materials Research and Standards, MTRSA, Vol. 12, No. 8, August 1972, p. 31. [12] Thompson, R. D., Recent developments in liquid-in-glass

thermometry, Temperature, Its Measurement and Control in Science and Industry 3, Part 1 (Reinhold Publishing Corp., New York, 1962) p. 201. [13] Liberatore, L. C, and Whitcomb, H. J., Density changes

in thermometer glasses, J. Am. Ceram. Soc. 35, 67

(1952).

[14] American Society for Testing and Materials Designation

C162-56, Standard Definitions of Terms Relating to Glass and Glass Products.

[15] Lillie, H. R., and Shaver, W. W., Method of tempering

glass, U.S. Patent No. 2,148,630 (Feb. 28, 1939).

[16] Liberatore, L. C, Method of stabilizing the molecular

arrangement of glass thermometers, U.S. Patent No.

2,610,445 (Sept. 16, 1952).

[17] Ruh, E. L., and Conklin, G. E., Thermal stability in ASTM thermometers, ASTM Bui. No. 233, 35 (Oct.

1958).

[18] Martin, W. I., and Grossman, S. S., Calibration drift with

thermometers repeatedly cooled to — 30 °C, ASTM

Bui. No. 231. 62 (July 1958).

[19] Guillaume, C. E., Traite Practique de la Thermometrie,

Gauthier-Villars et Fils, Paris (1889) p. 99. [20] Harper 3d, D. R., Thermometrie lag, Bui. BS 8, 659

(1912) S185. [21] White, W. P., Lag effects and other errors in calorimetry,

Phys. Rev. 31, 562 (1910).

26
NBS-114A (REV. 7-73)

U.S. DEPT. OF COMM.

BIBLIOGRAPHIC DATA

SHEET

1. PUBLICATION OR REPORT NO.

NBS Monogr. 15 0

2. Gov't Accession

No.

3. Recipient's Accession No.

4. TITLE AND SUBTITLE

LIQUID-IN-GLASS THERMOMETRY

NBS MONOGRAPH

5. Publication Date

January 1976

6. Performing Organization Code

7. AUTHOR(S)

Jacquelyn A. Wise __—.

8. Performing Organ. Report No.

9. PERFORMING ORGANIZATION NAME AND ADDRESS

NATIONAL BUREAU OF STANDARDS

DEPARTMENT OF COMMERCE

WASHINGTON, D.C. 20234

10. Project/Task/Work Unit No.

11. Contract/Grant No.

12. Sponsoring Organization Name and Complete Address (Street, City, State, ZIP)

Same as 9.

13. Type of Report & Period

Covered

Final

14. Sponsoring Agency Code

15. SUPPLEMENTARY NOTES

Library of Congress Catalog Card Number: 75-619230

16. ABSTRACT (A 200-word or less factual summary of most significant information. If document includes a significant

bibliography or literature survey, mention it here.)

This Monograph, which supersedes NBS Monograph 90, contains information of general

interest to manufacturers and users of liquid-in-glass thermometers. Instructions

explaining how to submit a thermometer to the National Bureau of Standards for

calibration are provided, and the techniques and equipment, such as stirred liquid

comparison baths, used in the calibration procedures are described. A discussion

of important principles of acceptable thermometer design and factors affecting their

use is included. Listed are tables of tolerances reflecting good manufacturing

practices and reasonably attainable accuracies expected with liquid-in-glass

thermometers. The calculation of corrections for the temperature of the emergent

stem is given in detail for various types of thermometers and conditions of use.

17. KEY WORDS (six to twelve entries; alphabetical order; capitalize only the first letter of the first key word unless a proper name; separated by semicolons)

Calibration; emergent stem; liquid-in-glass thermometer; reference point; stirred

liquid comparison bath; temperature scale.

18. AVAILABILITY [£] Unlimited

I

1 For Official Distribution. Do Not Release to NTIS

l-X 1 Order From Sup. of Doc, U.S. Government Punting, Office

Washington. D.C. 20402. SD Cat. No. C13« 44:15 0

1 I Order From National Technical Information Service (NTIS)

Springfield, Virginia 22151

19. SECURITY CLASS

(THIS REPORT)

UNCL ASSIFIED

21. NO. OF PAGES

30

20. SECURITY CLASS

(THIS PAGE)

UNCLASSIFIED

22. Price

85 cprtts

USCOMM-DC 29042-P74

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interim or final reports on work performed by NBS for

outside sponsors (both government and non-government). In general, initial distribution is handled by the

sponsor; public distribution is by the National Technical

Information Service (Springfield, Va. 22161) in paper

copy or microfiche form.

Order NBS publications (except NBSIR's and Bibliographic Subscription Services) from: Superintendent of

Documents, Government Printing Office, Washington,

D.C. 20402.

BIBLIOGRAPHIC SUBSCRIPTION SERVICES

The following current-awareness and literature-survey

bibliographies are issued periodically by the Bureau:

Cryogenic Data Center Current Awareness Service

A literature survey issued biweekly. Annual subscription: Domestic, $20.00; foreign, $25.00.

Liquefied Natural Gas. A literature survey issued quarterly. Annual subscription: $20.00.

Superconducting Devices and Materials. A literature

survey issued quarterly. Annual subscription: $20.00.

Send subscription orders and remittances for the pre- ceding bibliographic services to National Technical

Information Service, Springfield, Va. 22161.

Electromagnetic Metrology Current Awareness Service

Issued monthly. Annual subscription: $24.00. Send

subscription order and remittance to Electromagnetics

Division, National Bureau of Standards, Boulder,

Colo. 80302.
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