PUBLICATIONS

National Bureau of Standards

NBS Special Publication 685

Compiled Thermodynamic Data

Sources for Aqueous and

Biochemical Systems:

An Annotated Bibliography (19301983)

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U.51
he National Bureau of Standards' was established by an act of Congress on March 3, 1901. The

Bureau's overall goal is to strengthen and advance the nation's science and technology and facilitate their effective application for public benefit. To this end, the Bureau conducts research and provides: (1) a

basis for the nation's physical measurement system, (2) scientific and technological services for industry and

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The Bureau's technical work is performed by the National Measurement Laboratory, the National

Engineering Laboratory, the Institute for Computer Sciences and Technology, and the Center for Materials

Science.

The National Measurement Laboratory

Provides the national system of physical and chemical measurement;

coordinates the system with measurement systems of other nations and

furnishes essential services leading to accurate and uniform physical and

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• Basic Standards2

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Provides technology and technical services to the public and private sectors to address national needs and to solve national problems; conducts research in engineering and applied science in support of these efforts; builds and maintains competence in the necessary disciplines required to carry out this research and technical service; develops engineering data and measurement

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Conducts research and provides measurements, data, standards, reference

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: Some divisions within the center are located at Boulder, CO 80303. 'Located at Boulder, CO, with some elements at Gaithersburg, MD.
NBS Special Publication 685

Compiled Thermodynamic Data

Sources for Aqueous and

Biochemical Systems:

An Annotated Bibliography (19301983)

Robert N. Goldberg Sponsored by: Center for Chemical Physics Design Institute for National Measurement Laboratory Physical Property Data

National Bureau of Standards Project 811 Gaithersburg, MD 20899 American Institute of Chemical Engineers

New York, NY

December 1984

U.S. Department of Commerce

Malcolm Baldrige, Secretary National Bureau of Standards

Ernest Ambler, Director
Library of Congress U.S. Government Printing Office Catalog Card Number: 84-601131 Washington: 1984

National Bureau of Standards

Special Publication 685

Natl. Bur. Stand. (U.S.), Spec. Publ. 685, 106 pages (Dec. 1984)

CODEN: XNBSAV

For sale by the Superintendent

of Documents,

U.S. Government Printing Office, Washington, DC 20402
iii

ABSTRACT

This is a selected and annotated bibliography of sources of compiled and

evaluated chemical thermodynamic data relevant to biochemical and aqueous

systems. The principal thermodynamic properties considered herein are Gibbs

energy and equilibrium data, enthalpies of formation and reaction, heat

capacities and entropies, and the corresponding partial molar and excess

properties. Derived quantities used in calculating the above are also

included. Transport and mechanical data have also been identified to a lesser

degree. Included in the annotations to the data sources are brief descriptions

of the types of properties tabulated, the classes of materials dealt with, and

the degree of completeness of the compilations.

Keywords: Aqueous systems; bibliography; biochemical systems; enthalpy data;

entropy data; equilibrium data; excess properties; Gibbs energy data; heat

capacity data; partial molar properties; review articles; thermochemistry;

thermodynami cs
iv

INTRODUCTION

"There is a growing need for reliable thermodynamic data for both

scientific and practical purposes. However, the existence of a desired piece

of data in the primary literature does not guarantee its recovery by an interested user. Indeed the recovery process may be a decidedly non-trivial

as well as a time consuming matter. At one time this problem was, in large

part, managed by periodic review articles, monographs, and the International

Critical Tables. The National Standard Reference Data System, CODATA, and

other coordinating organizations are helping to provide current compilations.

However, the preparation of new reviews is sufficiently complex that there are

at any give time many subject areas that do not have current compilations

available. In this circumstance earlier reviews are an important resource for

the technologist or scientist. Unfortunately, the proliferation of such works

and the enormity of the available literature have made even the recovery of

review and compilation articles a matter of some difficulty. It is to help

solve this problem for one small part of our science that we have prepared

this annotated bibliography of thermodynamic data sources relevant to

biochemical and aqueous systems. These two areas are mutually complementary.

In environmental problems such as water quality control, and in the

utilization of aqueous systems with respect to energy resources and the

processing of material resources, the aqueous systems of interest very often

include the same substances and require the same information as in the study

of biochemical systems. In addition to information on the aqueous solutions,

the properties of the pure substances are often required in order to establish

reference points for interrelating various systems. Thus, this bibliography

is a selective listing of sources of thermodynamic information for pure

substances and aqueous solutions, selected for their particular relevance to

these kinds of problems."

The above quotation is from NBS Special Publication 454 and it contains

the principle upon which both that publication and this one, the successor to

it, are based. The identification and collection of sources of compiled thermodynamic data was begun by the late George Armstrong at the National Bureau of

Standards at least ten years ago. The author joined him in this task several

years ago and with him co-authored NBS Special Publication 454 on this subject

in 1976. Many of the descriptions of older works in this Bibliography are taken directly from Special Publication 454. The intervening years have seen

a remarkable growth in the subject matter of this Bibliography and a revision

of it was suggested by the Design Institute for Physical Property Data of the

American Institute .of Chemical Engineers which also helped in providing the

necessary funding for the project. A "review of reviews" which the reader

might also wish to consult is the chapter by E. F. G. Herrington in "Chemical

Thermodynamics: Volume I" (see item [90]).

The scope of the present work remains essentially that of Special

Publication 454. The general aim is to assist the reader in locating those

publications which contain thermochemical data which can best serve his needs.

Equilibrium data is taken in its most general sense and includes equilibrium

constants, enthalpies, entropies, heat capacities, volumes, and partial molar

and excess property data. To a much lesser extent, transport and other

properties have been included. Unfortunately, much of the data on biochemical

systems is scattered throughout much of the literature and there is a need for
definitive reviews and compilations in several areas such as- enzyme-catalyzed

reactions and on the denaturation of enzymes and nucleic acids. This need is

all the more pressing due to the growing importance of bio-engineering and its

industrial importance. Because of this, various chapters and short reviews in

books on biochemistry have been included in this bibliography.

The entries are listed in alphabetical order by first author or by the

editor. There are a few cases in which the work of a research group, or the

volumes of a multi-volume work are kept together and entered under the name of

the principal researcher, the editor, or the institution. All authors have

been cited in the author index and it should be consulted if an article is not

found where expected.

Each annotation contains a brief summary of the contents of the book or article cited. Specifically, the nature and state of the substances dealt

with, the extent of coverage, and .whether the given property values have been

compiled, selected, or critically evaluated is stated. Also, whenever a meaningful statement on temperature range can be made, it has been included.

For some large compilations the ranges are too different for individual

systems to make any statement practical, and for them, the authors have

usually attempted to cover the full range of the data. It is hoped that the

contents of the annotation is sufficient to permit the reader to select those

references which most directly apply to his own needs.

The present bibliography identifies 162 different sources for the reader

to consult. Unfortunately, many of the books cited are out-of-print, not in

English, or in report form (many of the U.S. government sponsored reports are available from the National Technical Information Service, Springfield,

Virginia 22161). The reader is urged to exercise care and judgment when

combining formation properties from different sources when calculating equilibrium constants and enthalpies of reaction. There are several reasons for

this precaution: (1) different reference states may be used for the elements,

(2) there are different conventions regarding standard states, (3) equilibrium

"constants" may be concentration dependent, and (4) different thermodynamic

pathways may have been used to calculate tabulated formation properties. The

safest approach here is to calculate equilibrium constants (or enthalpy and

entropy changes) from the formation properties given in one reference and then

to combine them with similar data calculated or found in other references.

The alphabetical subject index that follows the main section of 'this

bibliography gives an indication of thermodynamic properties, physical or chemical processes, classes of substances, and, in a few cases, individual

substances for which information is to be found herein. It is not practical

to give an exhaustive index to the contents of the individual references.

Hence the absence of a piece of information in the index does not necessarily

mean its absence in the references. This is particularly true with respect to

particular substances, which the reader should assume are not listed except by

chance of title or abstract.

It is not possible to claim completeness for this bibliography and

somewhat arbitrary decisions have been made as to whether or not to include a specific item. The author would appreciate comments from interested readers

concerning data sources omitted from this bibliography.
vi

The author thanks Drs. William Evans, David Garvin, and Vivian Parker

for their comments on this bibliography and Beverly S. Geisbert for her

excellent clerical work on the manuscript.
1

BIBLIOGRAPHY

[1] Alberty, R. A. Standard Gibbs Free Energy, Enthalpy, and Entropy Changes as a Function

of pH, and pMg for Several Reactions Involving Adenosine Phosphates

Journal of Biological Chemistry 244, 3290 (1969).

The standard Gibbs energy, enthalpy, and entropy changes for the hydrolysis of

adenosine-5' -triphosphate to adenosine-5 1 -diphosphate are computed as a function of pH and magnesium ion concentration at 25 °C. A critical evaluation

of the relevant literature data is included. Also see item [120]

**********

[2] Armstrong, G. T. , Domalski, E. S. , Furukawa, G. T. , Reilly, M. L.

,

Wilhoit, R. C. and others

A Survey of Thermodynamic Properties of the Compounds of the Elements

CHNOPS - A Series of Eighteen Reports

(National Bureau of Standards Reports No. 8521, 8595, 8641, 8906, 8992,

9043, 9089, 9374, 9449, 9501, 9553, 9607, 9883, 9968, 10070, and 10291,

published during the years 1964 to 1970, U. S. Department of Commerce,

Washington, D.C.)

This series of reports is a survey of the thermodynamic properties of selected

compounds of biological importance containing the elements carbon, hydrogen,

nitrogen, oxygen, phosphorus, and sulfur. Included in these reports are heat

capacity data; heats and Gibbs energies of formation; vapor pressure data;

tables of thermodynamic functions; Gibbs energies, entropies and enthalpies of

solution and dilution; and thermodynamic properties of mixed solvent systems.

Except for the tables of thermal functions, the data refer to 25 °C or nearby

temperatures. References to sources of data in the literature are included.

Some of the data contained in these reports formed the basis of Domalski 's enthalpy of combustion tables (see item [29]) and of Wilhoit' s tables (see

item [15]). The remainder of the material in these reports has not appeared

in press elsewhere. The NBS Chemical Thermodynamics Data Center has a complete set of these reports available for examination.

**********

[3] Ashcroft, S. J. and Mortimer, C. T. Thermochemistry of Transition Metal Complexes

(Academic Press, London and New York, 1970).

This book surveys the literature to 1968 on energy changes for processes

involving transition metal complexes including both organic and inorganic

ligands. A critical review of the thermochemical data for over 1500 systems

of complexes is given. Comparable data from various sources are shown in

juxtaposition. Values of AH, AG, and AS for various stages of complex

formation are usually listed for processes in aqueous solution at or near 25 °C.

A

fH°, AfG°, AfS° for crystalline complex substances are given where available.

In many instances correlations of the data for various metals with a single

ligand, and for various related complexes of a given metal, are given graphically or by means of bond-energy estimates based on the data.

**********
2

[4] Baes, C. F. , Jr. and Mesmer, R. E. The Hydrolysis of Cations

(John Wiley and Sons, New York, 1976)

This book on the chemistry of hydrolysis of inorganic cations contains a substantial amount of equilibrium data pertinent to hydrolysis reactions. For

each of the elements which produces a cation or cations in aqueous solution,

the available equilibrium data for the hydrolysis reaction(s) at or about 298

K has been critically assessed in order to obtain "best" values for equilibrium constants and quotients applicable to a given medium. When available,

AH and AS data for the hydrolysis reactions are also presented. The data,

with references and comments, is arranged under the element of interest.

**********

[5] Barner, H. E. and Scheurman, R. V. Handbook of Thermochemical Data for Compounds and Aqueous Species

(John Wiley and Sons, New York, 1978)

This book presents thermodynamic properties for a wide variety of ions and

complexes in aqueous solution over a range of temperature (typically 25 to

300 °C). Most of the properties were calculated from data at 25 °C, much of

which was taken from the National Bureau of Standards Technical Note 270 (see

item [149]). Phase transition data were taken from the book by I. Barin and

0. Knacke, "Thermochemical Properties of Inorganic Substances" (SpringerVerlag, Berlin, 1973). The extension of the 25 °C data to higher temperatures

was done using estimation schemes such as those developed by C. M. Criss and

J. W. Cobble (J. Am. Chem. Soc. 85, 5390 (1964)) and H. C. Helgeson (J. Phys.

Chem. 71, 3121 (1967)).

**********

[6] Bates, R. G. Determination of pH, Theory and Practice (Second Edition)

(John Wiley and Sons, New York, 1973)

This book, the primary topic of which is the establishment of an operational pH

scale, contains several tables of interest. Tabulated are the ion product of

water from 0 to 60 °C, the vapor pressure, density, and dielectric constant of

water from 0 to 100 °C, dielectric constants of pure liquids, and pH values of

several aqueous buffer systems.

**********

[7] Battino, R. Volume Changes on Mixing for Binary Mixtures of Liquids

Chemical Reviews 71, 5 (1971).

This critical and extensive review deals with both the volume changes asso- ciated with the mixing of binary mixtures of liquids and partial molar volumes

at infinite dilution of various solvent systems, aqueous and non-aqueous. The

temperature range cited is that at which the experimental measurements have

been performed. Included is a detailed discussion of the experimental methods

used for measurements and associated theoretical developments. The coverage
3

of the available literature appears to be very thorough. There are 427

references to the primary literature.

**********

[8] Battino, R. , and Clever, H. L. The Solubility of Gases in Liquids

Chemical Reviews 66, 395 (1966)

This thorough and detailed review contains a discussion of experimental methods

for the measurement of gas solubilities in all types of liquids, including water.

Tabulated are the solubilities of oxygen, nitrogen, and argon in water at one atmosphere pressure and from 0 to 50 °C. Also to be found herein is an extensive

table listing sources of gas solubility data in the primary literature. Although

the tables do not give selected values, the authors have given their assessment

of the reliability of the data to be found in the listed sources by means of a coding scheme. There are 686 references to the primary literature. Also see item [154].

**********

[9] Beezer, A. E. (editor)

Biological Microcalorimetry

(Academic Press, London and New York, 1980)

This book contains fourteen chapters on various topics related to calorimetry

as applied to biochemical and biological systems. The coverage of topics

is very broad and includes bacteria, cells, microorganisms, drugs, membranes,

and enzymes. While there are few tables of thermodynamic data in this book,

many of the chapters contain useful collections of references to the

literature pertinent to the topic of the individual chapter.

**********

[10] Benson, S. W.

Thermochemical Kinetics:

Methods for the Estimation of Thermochemical Data and Rate Parameters

(Second Edition)

(John Wiley and Sons, New York and London 1976)

This monograph gives tables of necessary data and descriptions of methods of

their use for calculating AH

f

, C , and S at 25 °C for gas phase molecules and

radicals and for extrapolating tHem to higher temperatures. The procedures

can be applied to hydrocarbons, oxygen-containing compounds, nitrogencontaining compounds, polycyclic structures, haloalkanes, organo-sul f ur compounds, organo-metal 1 ic compounds, polycyclic substances, and deal principally with organic compounds.

**********

[11] Benson, S. W. , Cruickshank, F. R. , Golden, D. M. , Haugen, G. R.

,

O'Neal, H. E. , Rogers, A. S. , Shaw, R. and Walsh, R. Additivity Rules for the Estimation of Thermochemical Properties

Chemical Reviews 69, 279 (1969)
4

This lengthy technical article gives procedures for calculating the properties

A

f

G°, S°, C° for organic compounds in the gas phase. Parameters for calculating C *are given for the temperature range from 300 to 1500 K. The

availability of C as a function of temperature allows calculation of AfG° and

S° at the same temperatures. The necessary constants for making the calculations are given for individual chemical groupings in some 38 tables. Many

classes of functional groups and molecular conformations are included.

Examples are given comparing calculated and observed values. Agreements of 1

kcal-mol-1 (4.184 kJ-mol" 1 ) or better in A

f

G° and 1 cal -mol -1 *K -1 or better in

C° and S° are generally found. Also see item [10] which supersedes this

article.

**********

[12] Bichowsky, F. R. and Rossini, F. D. The Thermochemistry of the Chemical Substances

(Reinhold Publishing Corporation, New York, 1936)

Although outdated, this book still provides useful references to the older

thermochemical literature. Tabulated are A^H° and enthalpy of transition

values for the elements and their compounds, with the data for carboncontaining compounds being terminated at two carbon atoms. It should be noted

that the data pertain to a temperature of 18 °C and to diamond, rather than

graphite, as the standard state for carbon; the yellow form is the reference

state for phosphorus. The yellow form is thermochemically identical to the

white form which fs the reference state used in the NBS Thermochemical Tables

[149]. The data upon which this book was based were used in preparing NBS

Circular 500, see item [131].

**********

[13] Bondi, A. Physical Properties of Molecular Crystals, Liquids, and Glasses

(John Wiley and Sons, New York and London, 1968)

This monograph is designed for use by chemical engineers in estimating

physical properties needed in design calculations, as well as by physical

chemists and synthetic chemists who need to understand the relationship

between structure and physical properties. Correlations of several kinds are described in the text. These are then restated as methods for estimation of

the properties.

Substances considered include non-polar and polar gases, non-polar and polar

liquids, associated liquids, crystalline solids, glasses, polymers, and

polymer melts, as well as others. Procedures given include many variants,

depending upon the properties given as initial information. Among the

properties for which procedures are given are: density, heat capacity,

enthalpy, entropy, enthalpy and entropy of fusion, enthalpy of vaporization,

vapor pressure, cubical thermal expansion coefficient, bulk modulus, Young's

modulus compressibility, thermal conductivity, rotational diffusion constant,

relaxation times, mass diffusion, viscosity, and others.

**********
5

[14] Boublik, T. , Fried, V. and Hala, E. The Vapour Pressures of Pure Substances

(Elsevier, New York, 1973)

Data are presented in the form of constants for the Antoine equation for the

temperature dependence of the vapor pressures of 806 substances in the normal

and low pressure region. Almost all of the substances contain carbon. Experimental data from selected original sources are given, together with smoothed

values obtained from the Antoine equations at the same temperature, and the

absolute and percentage deviations. Standard deviations are calculated. A

standard boiling point is calculated for each substance.

**********

[15] Brown, H. D. (editor)

Biochemical Microcalorimetry

(Academic Press, New York and London, 1969)

This book contains seventeen chapters on subjects concerning heat measurements

and their relationship to biology and biochemistry. Also see the 1980 volume

of this same series, item [63]. Several of the articles contain tabulations

of data:

Author(s) Title of Chapter

R. C. Wilhoit Thermodynamic Properties of Biochemical

Substances

This chapter (no. II) includes several tables: (1) Selected values of thermodynamic properties (A^G°, A^H° , S°, and C°) for about 120 important biochemical

species or compounds; (2) Enthalpies and 6ibbs energies of formation of

adenosine phosphoric acid species relative to H 2 ADP 1_ at 25 °C; (3) AH° and

AG° for six important biochemical processes; and (4) Partial molar properties

(L2 , L ls C x ) of aqueous glucose, glycerol, glycine, and urea at 25 °C.

S. Ono and K. Takahashi Chemical Structure and Reactions of Carbohydrates

This chapter (no. IV) has a table of enthalpies of i somerization of eleven

carbohydrates and a table given enthalpies of hydrolysis of aqueous a-1,4 and

a-1,6 glucosidic linkages in several glucosides at 25 °C.

T. Ackermann Physical States of Biomolecules: Calorimetric

Study of Helix-Random Coil Transitions in Solution

This chapter (no. VI) contains a tabulation of cal orimetrically determined

enthalpy values accompanying conformational changes of macromol ecul es in solution

(26 references) and their transition temperatures.
6

H. D. Brown Calorimetry of Enzyme-Catalyzed Reactions

This chapter (no. VII) contains a summary of calorimetric enthalpy values for

enzyme catalyzed systems (21 references) at or near 25 °C.

**********

[16] Chapman, T. W. and Newman, J. A Compilation of Selected Thermodynamic and Transport Properties of

Binary Electrolytes in Aqueous Solution

(U. S. Atomic Energy Commission Report UCRL- 17767 (1968))

Data from the literature on the properties of sixty-one common binary inorganic

electrolytes at various temperatures are tabulated with appropriate references.

The properties include the density, viscosity, transference number, diffusion

coefficient, and the activity coefficient.

**********

[17] Chariot, G. Selected Constants - Oxidation-Reduction Potentials of Inorganic Substances

in Aqueous Solution

(Butterworths , London, 1971)

This reference work, prepared under the auspices of the IUPAC, contains

selected values of electrochemical potentials relative to the assigned zero value of the standard hydrogen electrode at or near 25 °C. Entries are given

for about 350 inorganic systems. The literature coverage is through 1967.

**********

[18] Christensen, J. J. , Eatough, D. J. and Izatt, R. M. Handbook of Metal Ligand Heats and Related Thermodynamic Quantities

(Second edition)

(Marcel Dekker, New York, 1975)

This handbook gives tabulated values of thermodynamic functions in aqueous

solution. Enthalpies are given for equilibria involving metal ions and

ligands, together with the related thermodynamic quantities log K, AS,, and

AC , where available. The body of the book consists of a table (414 pp.) in

wh?ch are summarized the published literature values up to 1974, classified

according to ligand. In addition, the appropriate reaction, the method, and

conditions of measurement of AH are given. The temperatures are also specified

and are in the vicinity of 25 °C. Both inorganic and organic ligands, and

complexes of about seventy metallic elements are given. A seven page guide to

the use of the table and indexes is given. The table is indexed by author, by

ligand formula, and by metal. An index of synonyms and a chronological list of

references are also given.

**********

[19] Christensen, J. J., Eatough, D. J. and Izatt, R. M. The Synthesis and Ion Binding of Synthetic Multi dentate Macrocyclic

Compounds

Chemical Reviews 74, 351 (1974)
7

This review article contains, in addition to a discussion on the synthesis,

kinetic, and structural parameters, a referenced compilation of log K, AH, AS,

and AC data at or near 25 °C for the interaction of inorganic cations with

synthetic multidentate macrocyclic compounds. Each entry in the table of

thermodynamic data includes the ionic strength, solvent system, and method of

measurement used in obtaining the data.

*********

[20] Christensen, J. J., Hansen, L. D. and Izatt, R. M. Handbook of Proton Ionization Heats and Related Thermodynamic Quantities

(John Wiley and Sons, New York, 1976)

This book is a compilation of enthalpies, entropies, and pK values for the

proton ionization of (mostly) organic compounds in water. For each of

the approximately 600 compounds covered in this handbook is given the

AH, AS, and pK for the proton ionization, the method and conditions of

measurement, and some brief remarks. The temperatures are also specified

and are at or near 25 °C. Literature references are also given for each

compound.

**********

[21] Clark, W. M. Oxidation-Reduction Potentials of Organic Systems

(The Williams and Wilkins Company, Baltimore, 1960)

This 584 page monograph contains a comprehensive discussion on the determination

of the electrochemical potentials of organic systems with emphasis both on theory and experimental practice. Included are approximately 100 tables of

critically evaluated oxidation and reduction potentials for organic and

biochemical systems through about 1960. Included are the qui nones, phenols,

anilines, porphyrins, nicotinamide-adenine di nucleotide, and nicotinamideadenine dinucleotide phosphate systems, and several others. The author has,

in most cases, specified the conditions to which the data refer.

**********

[22] Clarke, E. C. W. and Glew, D. N. Journal of the Chemical Society Faraday Transactions I 76, 1911 (1980)

Debye-Hlickel limiting slopes for the osmotic coefficient in water are presented as a function of temperature (0 to 150 °C). The recommended values

were derived from literature measurements of the static dielectric constant

and density of water.

**********

[23] CODATA Recommended Key Values for Thermodynamics 1977

(CODATA Bulletin No. 28 (1978) and Tentative Set of Key Values for

Thermodynamics: Parts VI, VII, and VIII, CODATA Special Reports:

No. 4 (March 1977), No. 7 (April 1978), and No. 8 (April 1980))

(CODATA Secretariat, Paris)
8

These are reports by the CODATA (Committee on Data for Science and Technology

of the International Council of Scientific Unions) Task Group on Key Values

for Thermodynamics in which are presented recommended values for the

quantities A

fG° (298.15 K) , S° (298.15 K) , Af H° (298.15 K) , and H°

(298.15 K) - H° (0 K) for w 180 of the thermichemical ly more important

elements and compounds, including some aqueous species, mostly electrolytes.

These bulletins supersede earlier CODATA reports of this group. The

recommended values are based on a completely new evaluation of all pertinent

data available at the time of publication. Consequently, they should not be

used indiscriminately with data from earlier self-consistent tables, such as Wagman et al. or Medvedev et al . , items [93] and [149]. The earlier publications in this series include CODATA Bulletins 5, 10, 17, and 22 published,

respectively, in 1971, 1973, 1976, and 1977. They are useful for the refer- ences which they contain to the source literature from which the recommended

key values were obtained.

**********

[24] Coetzee, J. F. and Ritchie, C. D. (editors) (in two volumes)

Solute-Solvent Interactions

(Marcel-Dekker , New York and London, 1969 and 1976).

Relevant chapters are:

Author(s) Title of Chapter

J. W. Larson and L. G. Hepler Heats and Entropies of Ionization (Vol 1,

Chapter 1)

This is a detailed review and evaluation of the enthalpies, Gibbs energies,

entropies, and heat capacity changes accompanying ionization of organic acids.

Included are eleven tables of data on various types of acids, including the

carboxylic acids, phenols, anilinium ions, ammonium ions, the amino acids,

barbituric acids, and several inorganic acids. The authors also discuss the

interpretation of the data in terms of molecular considerations. The tabulated

data refer to 25 °C and standard state conditions. There are 224 references.

E. M. Arnett and D. R. McKelvey Solvent Isotope Effect on Thermodynamics of Non- reacting Solutes

(Vol. 1, Chapter 6)

This is a general and extensive review dealing with differences in thermodynamic properties between light and heavy water systems. The properties

dealt with include Gibbs energies and enthalpies of transfer and solubilities;

systems for which data are tabulated include the more common inorganic

electrolytes and ions, alcohols, amides, amino acids, and several non- electrolytes.

P. M. Laughton and R. E.Robertson Solvent Isotope Effects for

Equilibria and Reactions (Vol. 1,

Chapter 7)
9

Included in this review are tabulated values giving differences in pK

values for weak acids in light and heavy water.

C. V. Krishnan and H. L. Friedman Enthalpies of Transfer for Solutes

in Polar Solvents (Vol. 2, Chapter 3)

The chapter reviews the existing experimental data for standard enthalpies

and entropies of solution of pure substances in various solvents and gives

derived entropies of transfer of molecules, ions, and groups from one solvent

to another and from the gas phase to water. The data are summarized in 22

tables and cover both inorganic and organic substances, electrolytes and non- electrolytes. There are 146 references to the literature.

**********

[25] Cohn, E. J. and Edsall , J. T. (including chapters by J. G. Kirkwood,

H. Mueller, J. L. Oncley, and G. Scatchard)

Proteins, Amino Acids, and Peptides: As Ions and Dipolar Ions

(Hafner Publishing Co., New York and London, 1965)

This book contains a general discussion of the physical chemistry of proteins,

amino acids, and peptides. Most of the chapters contain references to the

source literature where one can find specific pieces of thermodynamic data.

Tables in this book of particular interest to this bibliography are:

(1) activity coefficients of amino acids and peptides, (2) solubilities of

amino acids in water and other solvents, (3) the influence of CH2 groups upon

the interactions between dipolar ions, (4) enthalpies of ionization of amino

acids and peptides, and (5) thermodynamic functions (AG°, AH°, AS°, and AC°)

for the ionization of amino acids. Also see entry [24]. p **********

[26] Conway, B. E. Electrochemical Data

(Elsevier, New York, 1952)

This monograph is a comprehensive (359 pp.) collection of data on various

aspects of pure and applied electrochemistry, relating to organic and 'inorganic

substances, both solid and in solution. Data are presented in tabular form,

in ten chapters, introduced with references to data sources and explanations

of approach. Physical properties include densities and vapor pressures of

various aqueous solutions, dielectric constants, dipole moments, and other

properties. Relative partial molar enthalpies and activity and osmotic

coefficients, conductance values, ionic mobilities, transference numbers and

diffusion coefficients are tabulated. There is a chapter on dissociation

constants, solubilities, and buffer solutions. The chapter on properties of

electric double layers contains tables of electrokinetic potentials and

properties of various interfaces including ones of such biological interest as the mammalian red blood cell. The biologist would also find relevant the

section on transport and general properties of colloids and macromolecular

electrolytes, including extensive tables of mobilities for such compounds as
10

hemoglobins, serum albumins, and red blood cells, among others. Electrode

chemistry tables include a compilation of data on reversible electrode

processes:

liquid junction potentials, half-cell potentials, and electrochemical equivalents for certain elements. A chapter on electrode kinetics gives a critical

selection of the available determinations of the parameters of a number of

electrode reactions.

**********

[27] Covington, A. K. Electrolyte Solutions Bulletin

(University of Newcastl e-Upon-Tyne , 1971 to present)

This is a current awareness bulletin that provides titles and references of

"recent papers covering all aspects of the physical chemistry and structure of

electrolyte solutions, the methods used in these studies including spectroscopy, equilibrium (but not kinetic processes), electrode systems. pH, ion

selective and reference electrodes."

**********

[28] Cox, J. D. and Pilcher, G. Thermochemistry of Organic and Organometall ic Compounds

(Academic Press, London and New York, 1970)

This monograph is a critical compilation of thermochemical data for the title

field published since 1930. The enthalpies of formation at 298.15 K of some 3000 substances are listed, with estimates of error. Where enthalpies of

vaporization are known or can be reliably estimated these are listed and in

these cases the enthalpies of formation of both gaseous and condensed phases

are given. Extensive introductory material presents experimental procedures

for reduction of experimental data of the type found in the book. Applications

of thermochemical data are given, and there is a section on methods of estimating enthalpies of formation of organic compounds. Also see items [29] and

[116].

**********

[29] Domalski, E. S. Selected Values of Heats of Combustion and Heats of Formation of Organic

Compounds Containing the Elements C, H, N, 0, P, and S Journal of Physical and Chemical Reference Data 1, 221 (1972)

Selected values of the enthalpies of combustion and enthalpies of formation of

719 organic compounds at 298.15 K are reported. The selected values are augmented

by commentary and original source references. The Wiswesser Line Notation is

also given for each compound. The methods used in updating older work are described.

**********

[30] Domalski, E. S. , Evans, W. H. and Hearing, E. D. Heat Capacity, Entropies, and Some Phase Transition Properties of

Organic Compounds in the Liquid and Solid Phases

Journal of Physical and Chemical Reference Data, Volume 13,

Supplement No. 1, 1984. (286 pp.)
11

This extensive review gives heat capacities and entropies for approximately

1400 organic compounds in the liquid and solid phases at or near 25 °C. Values

for enthalpies and entropies of phase transitions are also included. The

literature coverage is from 1881 through most of 1982 and there are detailed

references given to the source literature.

**********

[31] Domalski, E. S. , W. H. Evans and T. L. Jobe, Jr., (principal

contributors)

Thermodynamic Data for Waste Incineration

(The American Society of Mechanical Engineers, New York, 1979)

This 160 page monograph presents thermodynamic data for materials which are chemical mixtures, polymers, composite materials, solid wastes, and substances

not easily identifiable by a single stoichiometric formula. The thermodynamic

properties given are heats of reaction and transitions, heat capacities and

heat contents, and vapor and sublimation pressures. Included is a material

name and property index which covers approximately 600 materials, many of

which are of biological interest, and including data on animals.

**********

[32] Dorsey, N. E. Properties of Ordinary Water-Substance

(Reinhold Publishing Corporation, New York, 1940)

This classic book is an exhaustive and critical compilation of the physical

properties of water as reported in the literature through the year 1938.

Essentially every physical property of pure water is covered. Although there

is little emphasis on aqueous solutions, the solubilities and diffusion

constants of selected gases in water are treated. Also see [134].

**********

[33] Dymond, J. H. and Smith, E. B. The Virial Coefficients of Gases

(Clarendon Press, Oxford, 1980)

This book is a critical compilation of the virial coefficients of about 300

gases at various temperatures. Included are references to the original

sources as well as, in some cases, standard deviations and estimated inaccuracies for the data. This revised edition also includes data on gaseous

mixtures

.

**********

[34] Fasman, G. D. (editor)

Handbook of Biochemistry and Molecular Biology

(CRC Press, Cleveland, Ohio, 1976)

This compilation is a revision and an expansion of the 1968 edition (see item

[140]). Many of the earlier contributions have been revised. The three

sections on the solubilities of fatty acids by K. S. Markley are in the
12

volume "Lipids, Carbohydrates, and Steroids" on pages 496 and 497. All of the

other articles cited in item [140] appear in the volume "Physical and Chemical

Reference Data" between pages 107 and 366. Items of interest which did not

appear in the earlier edition are as follows:

Author(s) or Source Item

E.D. Mooz Data on the Naturally Occurring Amino Acids

(Proteins, p. 111-174)

These tables include pK values for the amino acids at or near 25 °C.

D. B. Dunn and R. H Hall Purines, Pyrimidines, Nucleosides, and

Nucleotides: Physical Constants and

Spectral Properties

(Nucleic Acids, p. 65-215)

These tables include pK values for these materials at 25 °C.

Interunion Commission on Recommendations for Measurement

Bi ©thermodynamics and Presentation of Biochemical

Equilibrium Data.

(Physical and Chemical Reference

Data, p. 93-103)

This important report gives a set of recommendations pertinent to the

measurement and treatment of biochemical equilibrium data.

N. Langerman Enthalpy, Entropy, and Free Energy Values

for Biochemical Redox Reactions.

(Physical and Chemical Reference

Data, p. 121)

This table summarizes AG, AH, and AS values for 14 biochemical redox reactions

at 25 °C.

**********

[35] Florkin, M. and Mason, H. (editors)

Comparative Biochemistry, Volume II. Free Energy and Biological Function

(Academic Press, New York and London, 1960)

This book contains several chapters dealing with the use of Gibbs energy data

in biochemistry. The following chapters contain references to and/or tabulations of thermochemical data:

Authors Title of Chapter

M. R. Atkinson and R. K. Morton, Free Energy and Biosynthesis of

Phosphates (Vol. 1, Chapter 1)
13

This chapter contains a tabulation of Gibbs energies and equilibrium

constants for various metabolic processes involving phosphates. The

temperature, pH, magnesium ion concentration, and appropriate literature

references are given.

L. F. Leloir, C. E. Cardini and

E. Cabib

Included in the discussion are some

to the biosynthesis of saccharides.

Utilization of Free Energy for the

Biosynthesis of Saccharides

(Volume 1, Chapter 2)

references to equilibrium data relevant

P. P. Cohen and G. W. Brown, Jr. Ammonia Metabolism and Urea Biosynthesis

(Volume 1, Chapter 4)

In their discussion of ammonia metabolism, the authors have used other com- pilations of thermodynamic data to compute Gibbs energy changes for these

processes.

**********

[36] Fox, D. , Labes, M. M. and Weissberger, A. (editors)

Physics and Chemistry of the Organic Solid State

(John Wiley and Sons, Interscience Publishers, New York 1963)

E. F. Westrum, Jr. and J. P. McCullough Chapter 1. Thermodynamics of Crystals

In addition to discussion of thermodynamic properties of organic substances

and their measurement, this chapter (178 pp.) gives tables of entropy of

fusion, and vapor pressures and a table of thermodynamic data sources for

about 800 organic compounds (798 references).

**********

[37] Franks, F. (editor)

Water-A Comprehensive Treatise (in five volumes)

(Plenum Press, New York and London, 1972 to 1975)

This treatise consists of forty-six chapters dealing with water and aqueous

solutions. Although concerned with all aspects of water, several chapters

contain extremely useful summaries of thermodynamic data. Among these are:

Author(s) Title of Chapter

F. Franks The Properties of Ice (Vol. 1, Chapter 4)

Tabulated are the ionic equilibrium constant and transport properties of ice

at -10 °C.
14

G. S. Kell Thermodynamic and Transport Properties

of Fluid Water (Vol. 1, Chapter 10)

Included is the density of water as a function of temperature, the vapor

pressure, specific heat, partial molar volume, critical properties, and

viscosity of water from 0 to 500 °C and to 8 kbar. Also see items [43]

and [134].

K. Todheide Water at High Temperatures and Pressures

(Vol. 1, Chapter 13)

This chapter is an extensive tabulation of the high temperature properties of

water. Included are the specific volume, fugacity, Gibbs energy and enthalpy

of formation, entropy, viscosity, thermal conductivity, dielectric constant,

and ion product of water. The temperature and pressure ranges are 0 to

1000 °C and up to 250 kbar. Also see items [43] and [134].

F. Franks and D. S. Reid Thermodynamic Properties

(Vol. 2, Chapter 5)

Given are AG°, AH°, AS° , and AC° for the solution of hydrocarbons, alcohols,

and rare gases *in water at 25 °cP

H. L. Friedman and C. V. Krishnan Thermodynamics of Ionic Hydration

(Vol. 3, Chapter 1)

Tabulated are single-ion entropies of about 110 diatomic and polyatomic ions

in water; Gibbs energies, enthalpies, and entropies of hydration of monatomic

ions at 25 °C; partial molar volumes of about 120 common ions at 25 °C; ionic

partial molar heat capacities of ions; Gibbs energies of transfer of inorganic

electrolytes from H 2 0 to D 2 0; and calorimetrically determined enthalpies of

solution of salts in H 2 0 and D2 0.

D. Eagland Nucleic Acids, Peptides, and Proteins

(Vol. 4, Chapter 5)

Thermodynamic parameters for coil -» helix and homopolymer -» coil helix

transitions of amino acids in aqueous solution are tabulated.

H. L. Anderson and R. H. Wood Thermodynamics of Aqueous Mixed Electrolytes

(Vol. 3, Chapter 2)
15

Included are data on the enthalpies and excess Gibbs energies of mixing of

about 24 mixed electrolyte systems in water at 25 °C.

**********

[38] Fredenslund, A., Gmehling, J. and Rasmussen, P. Vapor-liquid Equilibria Using UNIFAC

(Elsevier Scientific Publishing Company, Amsterdam, 1977)

This book describes the UNIFAC (an acronym formed from Universal QuasiChemical Functional Group Activity Coefficient) procedure for estimating

activity coefficients of non-electrolytes in fluid mixtures and the use of

these activity coefficients for the prediction of vapor-liquid equilibria. The

estimation scheme is based upon a group-contribution method. The methodology

is clearly described with examples of its use and with computer programs

listed in the Appendix to the volume. There is also a chapter which describes

a procedure for estimating the second virial coefficients of gases. The

coverage of materials and functional groups includes alcohols, alkanes,

ethers, organic acids, ketones, aldehydes, amines, hydrocarbons, and nitrogen

compounds.

**********

[39] Freeman, R. D. (editor)

Bulletin of Chemical Thermodynamics

(Thermochemistry, Inc. , Oklahoma State University, Stillwater, OK

74078)

Each annual issues (volume 25 appeared in 1982) of the Bulletin is a current

awareness index to, and a comprehensive bibliography of, articles that pertain

to chemical thermodynamics (broadly interpreted) and that were published in

the previous calender year. The index is arranged by chemical substance and

identifies the thermodynamic property reported for each substance; numerical

data are not given. Four subdivisions of the index cover inorganic

substances, organic substances, organic mixtures, and biochemical and

macromolecular systems. Also included in each Bulletin is a section of

Reports, on "work completed but not yet published", from a large number of

laboratories located worldwide, a bibliography of recently published books

related to thermodynamics, and a section of miscellaneous items of interest to

the thermodynamic community. The early volumes of the "Annual Review of

Physical Chemistry", published since 1950 by Annual Reviews, Inc., contained

bibliographic information for general thermochemistry and the thermodynamics

of electrolyte solutions; these articles were, in part, the forerunners of the

Bulletin. From 1965 to 1976 the Bulletin had the title "Bulletin of

Thermodynamics and Thermochemistry" and was published by the University of

Michigan under the editorship of E.F. Westrum, Jr.

**********

[40] Freir, R. K. Aqueous Solutions: Data for Inorganic Compounds (in two volumes)

(Walter de Gruyter, Berlin and New York, 1976 and 1977)

This very well organized and easy-to-use handbook contains a wealth of thermodynamic data on aqueous solutions. There are 1300 solutions for which data

is given. The solutes are both inorganic and organic, and include data on biochemical substances when available. Properties given are densities,
16

solubilities, equilibrium constants, Gibbs energies of formation, electrochemical potentials, conductivities, pH values, species-composition diagrams,

and vapor pressures. The most serious shortcoming of this handbook is the

absence of specific references to the literature sources of the data. The

bulk of the text is in German.

[41] Goldberg, R. N. , Staples, B. R. , Nuttall , R. L. and Arbuckle, R. A Bibliography of Sources of Experimental Data Leading to Activity or Osmotic Coefficients for Polyvalent Electrolytes in Aqueous Solution

(NBS Special Publication 485, U. S. Government Printing Office, Washington,

D.C. , 1977)

This is a bibliography of sources of experimental data that can be used to

calculate either activity or osmotic coefficients of polyvalent electrolyes

in water at the temperatures (0 to 100 °C) for which the data exist. The

compounds are arranged according to the standard thermochemical order of

arrangement. There are approximately 400 references to the source literature.

[42] Gurvich, L. V., Veits, I. V., Medvedev, V. A., Khachkuruzov , G.A.

,

Yungman, V.S., Bergman, G.A. et al. "Termodinamicheskie Svoistva

Individual 1 nykh Veschestv" (Thermodynamic Properties of Individual

Substances) *V. P. Glushko, general editor Volume I, parts 1 and 2 (1978);

Volume II, parts 1 and 2 (1979); Volume III, parts 1 and 2 (1981);

Volume IV, in press. (Izdatel 1 stvo "Nauka", Moscow, 1979).

This extensive work is a critical evaluation and collection of the thermodynamic properties of the elements and their compounds. The properties

tabulated are C°, (G°-H°(0))/T, S°, and H°-H°(0) and log 10 K where K for gases

is the equilibrium constant for the reaction of forming the given compound

from its atoms; for solids K refers either to vaporization or to atomization.

The temperature range for which the data are given is 100 K to the highest

temperature for which data exist, the temperature intervals being in

steps of 100 K. There are extensive discussions of the sources from which the

data have been taken, the computational procedures, and also, references to

the source literature. Also see item [144]. The contents of the four volumes

are:

Volume Contents

**********

**********

I 0, H(D,T), F, CI, Br, I, He, Ne, Ar,

Kr, Xe, Rn, S, N, and P

II C, Si , Ge, Sn, and Pb

III B, H, Ga, In, Tl , Be, Mg, Ca, and Ba

IV Cr, Mo, W, V, Nb, Ta, Ti , Zr, Hf,

Sc, Y, La, Th, U, Pu, Li, Na, K, Rb, and Cs.
17

[43] Haar, L. , Gallagher, J. S. and KeH , G. S. A Thermodynamic Surface for Water: The Formulation and Computer Programs

(NBSIR 81-2253, National Bureau of Standards, Washington, D.C., 1981)

Haar, L. , Gallagher, J. S. and Kell , G. S. The Anatomy of the Thermodynamic Surface of Water: The Formulation and

Comparisons with Data

(The American Society of Mechancial Engineers, New York, 1982)

Haar, L. , Gallagher, J. S. , and Kell, G. S. NBS-NRC Steam Tables

(Hemisphere Press, Washington, DC, 1984)

The 1981 article summarizes the development of a thermodynamic surface for

water with which all thermodynamic properties for the fluid states can be

calculated from the freezing line to 1000 K and up to 1 GPa in pressure. The

discussion is very brief, but gives references to earlier work and indicates

that a more detailed publication is forthcoming. Given are coefficients of

the Helmholtz function which define the surface. Plots of heat capacity,

enthalpy, and speed of sound are included.

The 1982 report contains a computer program which can be used to calculate

twelve thermodynamic properties of water and steam over the range 0° C < t < 1000 °C and 0 < p < 1000 MPa. The properties include the Helmoltz function,

the pressure, entropy, isochoric and isobaric heat capacity, the 2nd virial

coefficient, and the speed of sound. Also see item [134].

The book in press contains tables, with documentation, for all of the

equilibrium properties of water and steam for which reliable data exist.

Also included in the book are tables of transport and mechanical property data

such as the surface tension, the viscosity, and the thermal conductivity. The

temperature range which the data tables extend is 0 °C < t < 2500 °C and the

pressure range is 0 < p < 3000 MPa.

**********

[44] Hala, E. , Wichterle, I., Polak, J. and Boublik, T. Vapour-Liquid Equilibrium Data at Normal Pressures

(Pergamon Press, Oxford, 1968)

This book contains correlated vapor-liquid-equilibrium data on mixtures

(mostly binary but with some mul ticomponent systems). The correlations are done using any one of several approaches: The Antoine equation for a pure

component, van Laar and Margules equations for mixtures. In all cases the

source(s) of the experimental data is given. The coverage of systems ( 400)

is very broad and it includes aqueous, nonaqueous, and organic-inorganic

mixtures.

**********

[45] Hamer, W. J. (editor)

The Structure of Electrolytic Solutions

(John Wiley and Sons, New York, 1959)
18

This book contains several chapters relevant to this bibliography. They are:

Author(s) Title of Chapter

C. W. Davies Incomplete Dissociation in Aqueous Salt

Solutions (Chapter 3)

Tabulated are values of -log 10 K at 25 °C for the pairing in aqueous solution

of eighteen common inorganic cations with thirty-eight of the more common inorganic and organic anions.

E. Lange Heats of Dilution of Dilute Solutions

of Strong and Weak Electrolytes

(Chapter 9)

This chapter contains a discussion of the theoretical interpretation and

calculations of heats of dilution of electrolytes of various charge types with

some information on non-electrolytes and weak electrolytes. Data from the

literature are presented in graphical form. Included are data for eighteen

inorganic electrolytes and seven inorganic non-electrolytes at 25 °C.

H. S. Harned Diffusion and Activity Coefficients of

Strong and Weak Electrolytes

(Chapter 10)

Tabulated are the activity coefficients, obtained from diffusion data, for

twenty common aqueous electrolyte systems at 25 °C.

F. H. Spedding and G. Atkinson Properties of Rare Earth Salts in

Electrolytic Solutions

(Chapter 22)

Tabulated are the equivalent conductances, transference numbers, activity

coefficients, densities and partial molar volumes, apparent molar com- pressibilities, heats of solution and dilution for the rare earth salts in

aqueous solution at 25 °C.

**********

[46] Hamer, W. J., and DeWane, H. J. Electrolytic Conductance and the Conductances of the Halogen Acids in

Water

(NSRDS-NBS 33, U. S. Government Printing Office, Washington, D.C., 1970)

This monograph contains a detailed evaluation of equivalent conductance data

for hydrofluoric, hydrochloric, hydrobromic, and hydroiodic acids in water at

various concentrations from -20 to +65 °C.
19

[47] Hamer, W. J. and Wu, Y. C. The Activity Coefficients of Hydrofluoric Acid in Water from 0 to

35 °C

Journal of Research of the National Bureau of Standards 74A, 761 (1970)

This very detailed review on hydrofluoric acid contains critically evaluated

data for the activity coefficient of HF as a function of molality and temperature (0 to 35 °C), equilibrium constants for the ionic association

reactions characteristic of HF, calculated pH values, and calculated concentrations of the pertinent ions.

**********

[48] Hamer, W. J. and Wu, Y. C. Osmotic Coefficients and Mean Activity Coefficients of Uni-Univalent

Electrolytes in Water at 25 °C

Journal of Physical and Chemical Reference Data 1, 1047 (1972)

This evaluation gives values for the osmotic coefficients and mean activity

coefficients of seventy-nine uni-univalent electrolytes in aqueous solution at

25 °C, with values expressed on the molality scale. The data from the literature were fitted, by statistical procedures, to equations which express the

quantities as functions of electrolyte concentration. Literature references

are given to fifty-one additional uni-univalent electrolytes. Also see item

[159].

**********

[49] Harned, H. S. and Owen, B. B. The Physical Chemistry of Electrolytic Solutions (3rd Edition)

(Reinhold Publishing Corporation, New York, 1958)

This book (about 800 pp.) is a treatise on the physical chemistry of electrolytic solutions with coverage of both equilibrium and non-equilibrium properties

The book includes tables of values of the equivalent conductance, dissociation

constants, transference numbers, diffusion coefficients, relative apparent molar

heat contents, activity coefficient, pH values, densities, and activity coefficients for many of the more common inorganic and organic electrolyte solutions.

**********

[50] Harned, H. S. and Robinson, R. A. Mul ticomponent Electrolyte Solutions

(Pergamon Press, Oxford, 1968)

This monograph deals with the theoretical and experimental aspects of multicomponent and largely inorganic electrolyte solutions, with emphasis upon the

measurement and interpretation of activity coefficients, heats of mixing, and

volume changes accompanying mixing. There is a useful bibliography of activity

coefficient data for mixed electrolyte systems. We note, for the reader's

information, the following monographs published in the same series of books

(The International Encyclopedia of Physical Chemistry and Chemical Physics)

and which deal principally with theory or methods of measurement pertinent to

electrolyte solutions:
20

Author Title of Volume

E. A. Guggenheim and R. H. Stokes Equilibrium Properties of Aqueous

Solutions of Single Strong Electrolyt

R. H. Stokes and R. Mills Viscosity of Electrolytes and

Related Properties

E. J . Ki ng Acid-Base Equilibria

**********

[51] Hawkins, D. T.

Physical and Chemical Properties of Water:

A Bibliography: 1957-1974

(Plenum Press, New York, 1976)

This bibliography consists of 3600 references to the literature that deal with

physical properties of pure water or dilute aqueous solutions. The papers are arranged by category of properties. Categories include thermodynamic properties,

transport data, densities, acoustical, electrical, magnetic, and radiation

properties. The bibliography covers the years 1957 to 1974. There is an author and keyword index. A bibliographic listing covering the years 1969 to

1974 appeared in the Journal of Solution Chemistry, 4, 621 (1976).

[52] Helgeson, H. C. , Kirkham, D. H. and Flowers, G. C.

Theoretical Prediction of the Thermodynamic Behavior of Aqueous

Electrolytes at High Pressures and Temperatures: IV. Calculation

of Activity Coefficients, Osmotic Coefficients, and Apparent

Molal and Standard Relative Partial Molal Properties to 600 °C

and 5 kb

American Journal of Science 28J, 1249 (1981)

This 268 page article is concerned with the prediction of the thermodynamic

properties of aqueous electrolyte solutions at high temperatures and pressures.

There is an extensive discussion of the fundamental thermodynamics of. solutions

and a discussion of theoretical concepts and models which have been used to

describe electrolyte solutions. There is a very extensive bibliography ( 600

citations) which contains valuable references to specific systems of interest.

Some specific tables of interest to this bibliography contain Debye-Huckel

parameters at 25 °C, standard state partial molar entropies and heat capacities

at 25 °C, and parameters for calculating activity coefficients, osmotic

coefficients, relative apparent and partial molar enthalpies, heat capacities,

and volumes at 25 °C.

**********

**********

[53] Hepler, L. G. and Hopkins, H. P., Jr.

Thermodynamics of Ionization of Inorganic Acids and Bases in

Aqueous Sol ution.

Reviews in Inorganic Chemistry ]_> 303 (1979)
21

The review contains a general discussion of the thermodynamics of aqueous

acid-base chemistry. The systems which are discussed are pure water, C0 2 +

H 2 0, NH3 + H 2 0, hydrofluoric acid, phosphoric acid, hydrogen sulfide, S0 2 +

H 2 0, sulfuric acid, H 2 Cr04 , H 2 Cr2 0 7 , iodic acid, and aqueous metal cations.

This article cites values AG°, AH°, and AC° for the ionizations of these

various acids. ^ **********

[54] Hepler, L. G. and others

Thermochemistry of the Transition Metal Elements and Their Compounds

This series of papers contain critical reviews and selections of thermochemical

data for the transition metal elements and their compounds. Tabulated are selected values of A^G°, A^H°, S°, and electrode potentials at 25 °C. Each

article contains a discussion of the data upon which the selections have been

made and the references to the source literature. The papers in the series are:

Authors

R. N. Goldberg and L. G. Helper

Title of Paper

Thermochemistry and Oxidation Potentials

of the Platinum Group Metals and Their

Compounds

Chemical Review 68, 229 (1968)

L. M. Gedansky and L. G. Hepler Thermochemistry of Silver and Its

Compounds

Engelhard Industries Technical Bulletin IX, No. 4, 117 (1969)

L. M. Gedansky and L. G. Hepler Thermochemistry of Gold and Its Compounds

Englehard Industries Technical Bulletin X, No. 1, 5 (1969)

L. M. Gedansky, E. M. Woolley and Thermochemistry of Compounds and Aqueous

L. G. Hepler Ions of Copper

Journal of Chemical Thermodynamics 2, 561 (1970)

J. 0. Hill, I. G. Worsley and Thermochemistry and Oxidation Potentials

L. G. Hepler of Vanadium, Niobium, and Tantalum

Chemical Reviews 71, 127 (1971)
22

L. G. Hepler and G. Olofsson Mercury: Thermodynamic Properties

Chemical Equilibria, and Standard

Potential

s

•Chemical Reviews 75, 585 (1975)

J. G. Travers, I. Dellien and

L. G. Hepler

Scandium: Thermodynamic Properties,

Chemical Equilibria, and Standard

Potentials

Thermochimica Acta 15, 89 (1976)

L. G. Hepler and P. P. Singh

Thermochemica Acta 16, 95 (1976)

Lanthanum: Thermodynamic Properties,

Chemical Equilibria, and Standard

Potential

s

I. Dellien, F. M. Hall and

L. G. Hepler

Chemical Reviews 76, 283 (1976).

Chromium, Molybdenum and Tungsten:

Thermodynamic Properties, Chemical

Equilibria, and Standard Potentials

T. A. Zordan and L. G. Hepler

Chemical Reviews 68, 737 (1968)

Thermochemistry and Oxidation

Potentials of Manganese and Its

Compounds

**********

[55] Hirata, M. , Ohe, S. and Nagakama, K. Computer Aided Data Books of Vapor-Liquid Equilibria

(Kodansha Limited and Elsevier Scientific, Tokyo and New York, 1975)

This large volume (933 pages) contains tables, plots, and parameters pertinent

to vapor-liquid-equilibria (VLE). VLE data for sslOOO binary systems have

been collected and treated by computer to obtain the tables and system graphs

presented. References to the primary literature are included along with a detailed compound index. The coverage of compounds is very broad and includes

a wide variety of organic mixtures and 30 organic-water mixtures.

**********
23

[56] Horsley, L. H. Azeotropic Data (in three volumes)

Advance in Chemistry Series No. 6, 35 and 116

(American Chemical Society, Washington, D.C., 1952, 1962 and 1973)

This series is concerned with the properties of azeotropic mixtures, specifically boiling temperatures, pressures, vapor-liquid equilibrium data, and

compositions. Each of the volumes contains references to the source literature for each of the system catalogued. In terms of coverage of

mixtures, the series is comprehensive for both binary and ternary mixtures and covers both inorganic and organic materials. The most recent volume contains

a section dealing with the prediction and calculation of azeotropic mixtures.

**********

[57] Horvath, A. L. Reference Literature to the Critical Properties of Aqueous Electrolyte

Sol utions

Journal of Chemical Information and Computer Sciences T_5, 245 (1975)

This bibliography gives references to the critical properties of aqueous

electrolyte solutions. The bibliography covers » 75 solutions and has 85

references.

**********

[58] Horvath, A. L. Reference Literature to Solubility Data between Halogenated Hydrocarbons

and Water

Journal of Chemical Documentation 1_2, 163 (1972)

This is a bibliography giving 103 references to solubility data for halogenated

hydrocarbons (C 1 to C 6 ) in water. References are given for approximately 100

compounds.

**********

[59] Ingraham, L. L. and Pardee, A. B. Free Energy and Entropy in Metabolism

in Metabolic Pathways, Volume I (D. M. Greenberg, editor)

(Academic Press, New York, 1967)

This chapter contains a general discussion of the thermodynamics of metabolic

processes, with the (uneval uated) data itself being presented in the course of

the discussion. The emphasis is almost entirely upon Gibbs energy changes

measured under physiological or near physiological conditions. There are 143

references to the primary literature.
24

[60] Izatt, R. M. , Christensen, J. J. and Rytting, J. H. Sites and Thermodynamic Quantities Associated with Proton and Metal

Ion Interaction with Ribonucleic Acid, Deoxyribonucleic Acid, and Their

Constituent Bases, Nucleosides, and Nucleotides

Chemical Reviews 71, 439 (1971)

This review contains twenty-three pages of tables of thermodynamic data (log

K, AH, AS, and AC ) pertinent to the interaction of protons and metal ions

with the nucleic icids and their molecular components together with the

methods and experimental conditions (pH, temperature, ionic strength) used in

their determination. There are 229 references.

**********

[61] Janz, G. J. Thermodynamic Properties of Organic Compounds

Estimation Methods, Principles, and Practice (revised edition)

(Academic Press, New York and London, 1967)

This well-established monograph discusses computation of thermodynamic properties

such as heat capacities, entropies, enthalpies and Gibbs energies by statisticalmechanical methods, by methods of structural similarity, by methods of group

contributions, by methods of group equations, and by methods of generalized

vibrational assignments. The chemical properties: enthalpy of formation, and

enthalpy of combustion are treated in terms of bond energies and group increments

Some 78 tables are given of increments, group contributions, and bond contributions as specifically needed for estimation of particular properties.

**********

[62] Janz, G. J. and Tomkins, R. P. T. Non-Aqueous Electrolytes Handbook (in two volumes)

(Academic Press, New York, 1972)

These volumes contain extensive tabulations of physical data pertinent to

non-aqueous solvents, both single solvent and mixed solvent systems. The

properties that are tabulated include melting point, boiling point, dielectric

constant, viscosity, specific conductance, density, transference number,

solubility, enthalpy of solution and dilution, E° values for electrochemical cell

vapor pressure, pol arographic data, ligand exchange rate, and spectroscopic data.

The vast majority of the approximately 300 solvent systems dealt with are

organic. There is a substance-property index, and sources of data are referenced

**********

[63] Jones, M. N. (editor)

Biochemical Thermodynamics

(Elsevier Scientific Publishing Co., Amsterdam, 1979)

This book is divided into eleven chapters, each on a topic pertinent to

biochemical thermodynamics and written by an expert on that topic. Each

chapter contains useful references to papers in the literature which

contain, tabular summaries of thermodynamic data pertinent to the theme of

that chapter. The chapters and authors are:
25

Author(s)

M. N. Jones

F. Franks

W. Pfeil and P.

H. J. Hinz

D. S. Reid

M. N. Jones

S. J. Gill

M. Monti and I. Wadso

G. C. Krescheck

Title of Chapter

The Scope of Thermodynamics in Biochemistry

Aqueous Solution Interactions of Low Molecular

Weight Species - The Applicability of Model

Studies in Biochemical Thermodynamics

L. Privalov Conformational Changes in Proteins

Conformation Changes in Nucleic Acids

Thermodynamics of Aqueous Polysacharide Solutions

The Thermal Behavior of Lipid Systems and

Biological Membranes

Ligand Binding of Gases of Hemoglobin

Calorimetric Studies in Blood Cells

Thermochemical Studies on Bacterial and

Mammalian Cells

A. G. Lowe

B. Crabtree and

Energetics of Muscular Contraction

D. J. Taylor Thermodynamics and Metabolism

**********

[64] Jordan, T. E. Vapor Pressure of Organic Compounds

(John Wiley and Sons, Interscience Publishers, New York, 1954)

This is a comprehensive compilation (266 pages) of vapor pressure data for

organic compounds. Included are tables on the hydrocarbons, alcohols,

aldehydes, esters, ketones, acids, phenols, and metal organic compounds. Data

for each compound are shown in graphical form, i.e. vapor pressure as a function of temperature. References to the data sources in the literature are

given.

**********

[65] Joshi , R. M. and Zwolinski, B. J. Heats of Polymerization and Their Structural and Mechanistic

Imp! i cations

in Vinyl Polymerization, Volume 1, Part I, edited by G. E. Ham

(Marcel Dekker, New York, 1967)

The authors discuss experimental methods used to measure and derive enthalpies

of polymerization. A listing of experimental data on enthalpies of polymerization is provided for 81 organic polymerization reactions. Other tables give

enthalpies. of formation, enthalpies of vaporization, entropies, Gibbs
26

energies, equilibrium constants, rate constants and activation energies at

25 °C for a variety of polymerization processes. A discussion of the

structural influence upon the enthalpy of polymerization is also given. At

the end of the chapter, 164 references are cited.

**********

[66] Kaimakov, E. A. and Varshavskaya, N. L. Measurement of Transport Numbers in Aqueous Solutions of Electrolytes

Russian Chemical Reviews (Uspekhi Khimii) 35, 89 (1966)

This review article summarizes the various methods available for the measure- ment of transference numbers. The authors have included a table which

summarizes available (thru 1966) transport number data for aqueous electrolyte

solutions, including references to the source literature.

**********

[67] Karapet'yants s M. Kh. and Karapet 'yants , M. L. Thermodynamic Constants of Inorganic and Organic Compounds

(Ann Arbor Humphrey Science Publishers, Ann Arbor and London, 1970)

Translated from the Russian:

"Osnovnye Termodi namicheskie Konstanty Neorganicheski kh i Organicheski kh

Veshchestv"

(Izdatel 1 stvo "Khimiya" , Moscow, 1968)

This book is a compilation of A^G°, AH°, S°, and C values at 298.15 K for

about 4000 substances in the condensed and gaseous^phases , and in aqueous

solution. Covered are not only the inorganic elements and their compounds,

but also data for the organic compounds through 34 carbon atoms. The authors

point out that their tabulated values do not always form a self-consistent

system of thermodynamic data. There are 2733 references.

**********

[68] Kaufmann, D. W. (editor)

Sodium Chloride

(Reinhold Publishing Corporation, New York, 1960)

This monograph, published under the auspices of the American Chemical Society,

has in its Appendix a useful compilation of the physical properties of aqueous

sodium chloride solutions. Included are essentially all of the measured

equilibrium and transport properties of this system at various temperatures

and pressures. The data are well referenced.

**********

[69] Kazavchinskii , Ya. Z. , Kessel 'man, P. M. , Ki rill in, V. A.,

Riukin, S. , Sheindlin, A. E. , Shpil'rain, E. E. , Sychev, V. V. and

Timrot, D. L. (edited by V. A. Kirillin)

Heavy Water-Thermophysical Properties

(U. S. Department of Commerce, National Technical Information Service,

Spri/igfield, VA 1971)

Translated from the Russian:

"Tyazhelaya voda. Teplof izicheskie Svoistva"

(Gosudarstvennoe energeticheskoe izdatel' stvo, Moskva-Leningrad, 1963)
27

This treatise is an exhaustive compilation of physical data on heavy water

(deuterium oxide). Some of the more relevant properties that are covered

include densities, critical constants, vapor pressures, enthalpies of transition, viscosity, and thermal conductivity, equation of state, and tables of

thermodynamic properties as functions of temperature and pressure.

**********

[70] Keenan, H. J., Keyes, G. F. , Hill, P. G. and Moore, J. G. Steam Tables - Thermodynamic Properties of Water, Including Vapor, Liquid,

and Solid Phases (International Edition, Metric Units)

(John Wiley and Sons, New York, 1969)

This book presents the results of a reassessment and correlation of the

thermodynamic data for water. It supersedes the Keenan and Keyes Tables of

1936. Values are tabulated for the specific volume, internal energy, and

enthalpy, as functions of temperature and pressure. Also given are data for

vapor- liquid and vapor- sol id equilibrium, superheated vapor, and the com- pressed liquid. Mollier and temperature-entropy charts are included along

with charts of heat capacity of liquid and vapor, Prandtl number, and

isentropic expansion coefficient. The data and tables are discussed in an appendix of 25 pages and a list of 37 references is given. Also see items

[43] and [134] for other correlations.

**********

[71] Kertes, A. S. (editor-in-chief)

Solubility Data Series

(Pergamon Press, New York, 1979 to 1981)

This eighteen volume series, prepared under the auspices of the IUPAC, is a part of a continuing project concerned with the preparation of a comprehensive, critical compilation of data on solubilities in all physical systems

including gases, solids, and liquids. The volumes which have been issued to

date, with their titles and editors, are:

Editor(s) Title Volume Numbers

H. L. Clever Helium and Neon - Gas Solubilities 1

H. L. Clever Krypton, Xenon, and Radon - Gas Solubilities

2

M. Salomon Silver Azide, Cyanide, Cyanamides,

Cyanate Sel enocyanate and Thiocyanate

3

H. L. Clever Argon 4

C. L. Young Hydrogen and Deuterium 5/6

R. Batti no Oxygen and Ozone 7

C. L Young Oxides of Nitrogen 8

W. Hayduk Ethane 9

R. Batti no Nitrogen and Air 10

B. Scrostai Alkali Metal and Alkaline-Earth 11

and C. A. Vincent Metal and Ammonium Hal ides.

Amide Solvents

0. Popovych Tetraphenyl borates 18
28

The following volumes are planned for future publication:

Z. Gal us and Metals in Mercury 12

C. Guminski

C. L. Young Oxides of Nitrogen, Sulfur and Chorine 13

Nitrogen 14

Hydrogen Hal ides in Non-Aqueous Solvents 15

R. Battino

H. L. Clever and

W. Gerrard

A. L. Horvath

E. Wilhelm and

Halogenated Benzenes

Hydrogen, Deterium, Fluorine and

Chlorine

16

17

C. L. Young

In general, for each system covered in this series, the preparer, who is

identified, gives the following information: the components in the system,

the intensive variables, the experimental values of the solubility, the

experimental methodology and source and purity of materials, a discussion of

the evaluation procedure, estimates of error, and literature citations.

[72] Kirgintsev, A. N. , Trushnikova, L. N. , and Lavrenteva, V. F. Solubilities of Inorganic Substances in Water

(in Russian)

(Izdatelstvo Khimiya, Leningrad, 1972)

This book consists of aqueous phase diagrams of pure salts in water. The

phase diagrams cover the composition and temperature ranges for which the data

exist. The diagrams are particularly useful in assessing the regions of

stability of the various inorganic hydrates and in obtaining solubilities. The

authors have included references to the source literature from which the data

have been obtained. The coverage of inorganic salts spans the periodic chart.

There are data for 1200 inorganic salts which are indexed in the Appendix to

the book.

[73] Kortum, G. , Vogel , W. and Andrussow, K. Dissociation Constants of Organic Acids in Aqueous Solution

(Butterworths , London, 1961)

This book is a compilation of 1056 dissociation constants of organic acids in

aqueous solution, presented in tabular form. Introductory and explanatory

remarks are in both German and English. Remarks in the Table are in German.

Part I is a critical discussion of techniques for measurements of dissociation

constants by conductance, electrometric, catalytic and optical methods. Each

method is classified and assigned a code in Part II, which deals with use of

the tables, and methods of calculation. The Tables themselves are arranged by

acid class including: aliphatic and alicyclic carboxylic acids, aromatic

carboxylic acids, phenolic acids, and other acids and special classes. The

Tables contain the name, chemical formula, and thermodynamic dissociation

constant K of each acid, the temperature (°C) of measurement, the range of

concentration over which the measurements were made, code for the method of

measurement, calculation procedure and any corrections made, a critical

evaluation of the quality of the measurement, and the source reference. All

**********

**********
29

data were drawn from the literature, covering the period between 1927 and

1956, and are referenced in a classified reference list. A compound index is

provided.

**********

[74] Kragten, J. Atlas of Metal- Li gand Equilibria in Aqueous Solution

(Ellis Horwood, Chichester, England, 1978)

This book contains «750 pages of predominance, or species-composition diagrams,

for aqueous solutions involving 45 metals and 25 common ligands. Most of the

thermodynamic data was taken from Si 11 en and Martell and from Smith and

Martell (see items [89] and [137]).

**********

[75] Krebs, H. A. and Kornberg, H. L. , with appendix by K. Burton

Energy Transformations in Living Matter

(Springer-Verlag, Berlin, 1957)

The main part of this monograph surveys the various biochemical pathways by

which living systems utilize energy. In the Appendix are (1) Tables of Gibbs

energies of formation of ninety-eight compounds of biological importance, (2)

Gibbs energies and electrochemical potentials of important biological oxidationreduction reactions, and (3) Gibbs energy changes accompanying the processes

of glycolysis and alcoholic fermentation, the tricarboxylic acid cycle, and

hydrolysis. The source of data is given for each entry.

**********

[76] Landol t-Bornstei

n

Numerical Data and Functional Relationships in Science and Technology

Several volumes in the Landol t-Bbrnstei n series contain data relevant to this

bibliography. They are:

Author(s) Title of Volume Location

G. Beggerow Heats of Mixing and Solution New Series, 'Group IV,

Volume 2

This very extensive volume (695 pages) contains data on heats of mixing,

solution, and dilution for both organic and inorganic substances. The

coverage of substances spans the periodic chart and includes both binary

and multi-component mixtures. The data on each system include the components

of the mixture, the temperature, the composition, the enthalpies, and the

appropriate literature citations.

(K.-H. Hellwege, editor, Springer-Verlag, Berlin, 1976)
30

J. D'Ans, H. Surawski Densities of Binary, Aqueous New Series, Group IV,

and C. Synowietz Systems and Heat Capacities Volume 1

of Liquid Systems

This 123 page section contains extensive tables of the specific heats of

binary, and a few ternary, aqueous systems at the temperatures and molalities

for which data exist. The authors include plots of the data and references to

the source literature.

(K.-H. Hellwege, editor, Springer-Verlag, Berlin, 1977)

W. Auer, H. D. Baer, Kalorische Zustandsgrb'ssen 6th Edition, Volume 2,

K. Bratzler, F. Burhorn, Part 4

H. Kientz, 0. Kubachevski,

Fr. Losch, A. Neckel , H. Nelkanski, Kl . Schaffer,

and R. Wienecke

This volume contains thermal properties: molar heat capacity, entropy,

enthalpy, enthalpy of formation, Gibbs energy of formation, in the standard

state, and enthalpies of phase changes for many organic and inorganic

substances in SI units. The dependence of thermal functions and heat capacity

upon temperature is given for many substances. Some other thermodynamic

quantities are 'given. Extensive tables are given of group contributions to

enthalpies of formation and the Gibbs energies of formation of organic

substances (gases) in kcal-mol -1 and kJ-mol -1

. Many of the heat capacity

data are presented in diagrams. This series also includes tables of freezing

point depressions, conductivities, transference numbers, and densities for

aqueous systems.

(K. Schafer and E. Lax, editors, Springer-Verlag, Berlin, 1961)

J. Weishaupt Thermodynamic Equilibria of New Series, Group IV,

Boiling Mixtures Volume 3

This volume deals with the thermodynamic vapor- liquid equilibrium of binary

and multi component mixtures. The coverage of systems extends across the

periodic chart. The mixtures are adequately indexed and the reference to

the primary literature given. The information given on a typical system

includes tables of equilibrium temperatures as a function of the mole

fractions of the components at a given pressure with accompanying figures.

(H. Hausen, editor, Springer-Verlag, Berlin, 1976)

**********

[77] J. A. Larkin (editor)

International Data Series B. Thermodynamic Properties of Aqueous Organic

Systems

(Engineering Sciences Data Unit, London, 1978 and 1979)
31

This part of the International Data Series deals with the thermodynamic

properties of approximately 100 aqueous organic systems. Tabulated are excess properties (G, H, C, and V), vapor-liquid equilibrium data, and vapor pressures

as a function of composition. Each table is prepared by an individual con- tributor and includes, in a very neat tabular form, the tables of property

values, the correlating equations and their coefficients, the methods of

measurement, a brief discussion, and the appropriate references to the

literature.

**********

[78] Latimer, W. M. The Oxidation States of the Elements and Their Potentials in Aqueous Solution

(second edition)

(Prentice-Hall, Englewood Cliffs, New Jersey, 1959)

This book contains extensive tables of A^G°, A^H° , S° values for the elements

and their compounds as well as electrode potential diagrams calculated from the

tabulated A^G° values, from other measurements, and estimates when appropriate.

Many of the tabulated data were taken from National Bureau of Standards

Circular 500 (see item [131]). The appendices include activity coefficient

data for 77 strong electrolytes and a discussion of methods whereby entropies

may be estimated.

**********

[79] Lewis, G. N. and Randall, M. (revised by K. S. Pitzer and L. Brewer)

Thermodynamics

(McGraw-Hill, New York, 1961)

This standard textbook on chemical thermodynamics contains an Appendix (no. 4)

of selected data for aqueous electrolyte solutions. Compiled are activity

coefficients, Debye-Huckel parameters, relative partial molar enthalpies, and

relative partial molar heat capacities for about 70 of the most common

electrolytes in aqueous solution at 25 °C. More recent Debye-Huckel

parameters are to be found in the pages of Pitzer, Peiper, and Busey and of

Bradley and Pitzer (see item [121]) and the paper of Clarke and Glew, item

[22].

**********

[80] Leyendekkers, J. V. Thermodynamics of Seawater

(Marcel Dekker, New York and Basel, 1976)

This book deals with the thermodynamic properties of seawater as a multicomponent electrolyte solution. Each chapter covers a thermodynamic property of

seawater and its constituents. There are chapters on the fundamentals of

thermodynamics, the entropy, the volume, the expansibility, and the compressibility.

Included in each chapter is a discussion of the methods for calculating or estimating the desired property with tables of values of experimental and

calculated properties. There are extensive references to the primary
32

literature. The author has indicated that a second volume was to be published,

but it has not yet appeared in print. Also see [126].

**********

[81] Linke, W. F. Solubilities: Inorganic and Metal -Organic Compounds —A Compilation of

Solubility Data from the Periodical Literature. Volume I: A-Ir,

Volume II: K-Z

(Volume I: D. Van Nostrand Co. , Princeton, New Jersey, 1958 ) (Volume II: American Chemical Society, Washington, D.C., 1965)

These two volumes (total of 3401 pages) are comprehensive compilations of

mostly unevaluated solubility data for inorganic and metal-inorganic compounds.

Both aqueous and non-aqueous solvent systems are included. The temperatures and

compositions given cover the ranges for which experimental data exist. References

are given to the data sources. These two volumes had their origins in the

solubility compilations begun by A. Seidell in 1907.

**********

[82] Lobo, V. M. M.

Electrolyte Solutions: Literature Data on Thermodynamic and Transport

Properties

(Coimbra Editora, Coimbra, Portugal, 1975)

This monograph is a compilation of physical property data on aqueous salt

solutions. The properties tabulated are the density, the conductance,

transference number, viscosity, diffusion coefficient and the activity

coefficient. The monograph contains data on approximately 70 binary systems

at temperatures and compositions for which experimental data exist and

includes an index and references to the sources of the data.

**********

[83] Long, C. (editor)

Biochemists Handbook

(D. Van Nostrand Co. , Princeton, New Jersey, 1961)

This reference book contains several tables of thermochemical data:

Author(s) Title of Section

S. P. Datta and A. K. Grzybcwski pH and Acid-Base Equilibria

(pages 19 to 58)

This section contains a discussion of pH scales and the el ectrometric

measurement of pH, tables of assigned pH values for various buffered

solutions, and tables (about 600 entries) of thermodynamic acid dissociation

constants of weak organic acids (some as a function of temperature).
33

K. Burton Free Energy Data and OxidationReduction Potentials

(pages 93 to 95)

This section contains some revisions and additions to Burton's earlier tables

(see, in this bibliography, the book by Krebs and Romberg, item [75]).

**********

[84] Long, F. A. and McDevit, W. F. Activity Coefficients of Non-electrolyte Solutes in Aqueous Salt Solutions

Chemical Reviews 5J_, 119 (1952)

This review article is concerned with the effect of salts on the activity

coefficients of non-electrolytes. There is an extensive discussion of both

the theoretical and experimental procedures used in the study of this

phenomena. There is an extensive appendix to the article which lists salt

effects on non-polar electrolytes («100 systems). The article has 180

references.

**********

[85] MacKay, D. and Shiu, W. Y. A Critical Review of Henry's Law Constants for Chemicals of Environmental

Interest

Journal of Physical and Chemical Reference Data 1_0, 1175 (1981)

This is a critical review and tabulation of Henry's Law constants, vapor

pressures, and solubilities in water of 150 organic substances of environmental importance. The compounds include gaseous, liquid, and solid alkanes,

cycloal kanes , alkenes, alkynes, monoaromatics , polynuclear aromatics,

halogenated alkanes, alkenes and aromatics, and selected pesticides. Nearly

all of the data refer to 25 °C.

**********

[86] Maczynski, A., Maczynska, Z. , Rogalski, M. , Skrzecz, A., and

Dunajska, K. Verified Vapor-Liquid Equilibrium Data (in four volumes)

(PWN - Polish Scientific Publishers, Warsaw, 1976 to 1979)

This four volumes series contains vapor-liquid equilibrium data (i.e.,

compositions of vapor and liquid phases as functions of temperature and

pressure) covering the regions for which experimental measurements exist. The

systems are almost entirely organic. The data have been recalculated into SI

units and have been smoothed in many cases, often using the Redl ich-Ki ster

equation. There are detailed references to the source literature and there is an alphabetic index of the systems covered. The four volumes are:
34

Author(s) Title

A. Maczynski Binary Hydrocarbon Systems

A. Maczynski, Z. Maczynska, and

M. Rogalski

Binary Systems of Hydrocarbons

and Related Non-Oxygen Compounds

A. Maczynski, Z. Maczynska, and

A. Skrzecz

Binary Systems of Organic Compounds

Containing Halogen, Nitrogen and

Sul fur

A. Maczynski, Z. Maczynska, T. Treszczanowicz, and K. Dunajska

Binary Systems of Hydrocarbons and

Oxygen Compounds Without Alcohols

and Acids

**********

[87] Marcus, Y. , Kertes, A. and Yanir, E. Equilibrium Constants of Liquid-Liquid Distribution Reactions (in three

vol umes)

(Butterworths, London, 1974 and 1977)

This three volume series contains equilibrium data on 1 i quid- 1 i quid distribution

reactions. The equilibria of concern include: distribution, dissociation

and aggregation of the extractant, reactions of the extractant with diluents

and with other solvents, extraction of the water, equilibria of the extraction

metal ions, and extraction of metal ions with the extractant as the ligand.

Volumes 1 and 2 cover organophosphorous extractions and alkylammonium salt

extractants, respectively. Volume 3 deals with distribution reactions of

carboxylic and sulfonic acid extractants, and the distribution of inorganic

acids, salts, and complexes between aqueous solutions and both inert solvents

and solvents which have oxygen donor atoms. Each reaction entry includes the

equilibrium constant, the temperature for which the data exists, the conditions,

and a reference(s) to the source literature.

[88] Marshall, W. L. and Franck, E. U. Ion Product of Water Substance, 0-1000 °C, 1-10,000 bars

New International Formulation and its Background

Journal of Physical and Chemical Reference Data 10, 295 (1981)

The ion-product of water is represented as a function of temperature (0 to

1000 °C) and pressure (1 to 10,000 bars) by an equation with adjustable

parameters which have been determined by least-squares procedures using data

from the literature. The paper also contains the background for the international formulation for the ion-product of water as issued by the International Association for the Properties of Steam in May 1980. Also see [108].

**********
35

[89] MarteH, A. E. and Smith, R. M. Critical Stability Constants. Volume 1: Amino Acids

(Plenum Press, New York, 1974)

Smith, R. M. and MarteH, A. E. Critical Stability Constants. Volume 2: Amines

(Plenum Press, New York, 1975)

MarteH, A. E. and Smith, R. M. Critical Stability Constants. Volume 3: Other Organic Ligands

(Plenum Press, New York, 1977)

Smith, R. M. and MarteH , A. E. Critical Stability Constants. Volume 4: Inorganic Complexes

(Plenum Press, New York, 1976)

and

Martell, A. E. and Smith, R. M. Critical Stability Constants. Volume 5: First Supplement

(Plenum Press, New York, 1982)

Volume 1 contains selected values of log K, AH, and AS at 25 °C for the interaction

of inorganic metal and hydrogen ions with several classes of organic ligands.

The organic ligands dealt with are the ami nocarboxyl ic acids, iminodiacetic acid

and its derivatives, peptides, aniline carobyxlic acids, pyridine carboxylic

acids, peptides, and several other miscellaneous ligands. The data are critically selected from the literature rather than being simply compiled.

Each selected datum contains a reference to the primary literature. This 469

page volume contains a ligand formula and name index.

Volume 2 is similar in arrangement to Volume 1. The organic ligands dealt

with are the aliphatic, secondary, and tertiary amines, azoles, azines, and

the amino phosphorous acids.

Volume 3 contains the organic ligands which are not contained in Volumes 1

and 2. These ligands include carboxylic and phosphorous acids, phenols,

alcohols, amides, amines, halides, and many others.

Volume 4 is similar in arrangement to the earlier volumes. The ligands dealt

with are the hydroxide ion, some of the transition metal ligands (vanadium,

chromium, molybdenum, tungsten, and others) and ligands of the Groups III

through VII elements.

Volume 5 is a supplement to the first four volumes and serves to make the

coverage of the literature more current. Also see item [137].

**********

[90] McGlashan, M. L. (editor)

Chemical Thermodynamics (in two volumes)

(The Chemical Society, London, 1971 and 1978)
36

This two volume series contains reviews of the current literature pertinent

to several specialized areas of chemical thermodynamics. Each chapter is

written by a specialist in that area and includes many useful references to

the primary literature. The chapters and their authors are:

Volume 1

M. L. McGlashan

E.F.G. Herrington

Title of Chapter

The Scope of Chemical Thermodynamics

Thermodynamic Quantities, Thermodynamic Data,

and their Uses

A. J. Head Combustion and Reaction Calorimetry

J. F. Martin The Heat Capacities of Organic Compounds

J.D. Cox and I. W. Lawrenson The p, V, T Behavior of Single Gases

J. F. Counsell Modern Vapourflow Calorimetry

D. Ambrose Vapour Pressures

S. G. Frankiss and

J. H. S. Green

0. Kubaschewski , P. J. Spencer

and W. A. Dench

Volume 2

K. N. Marsh

T. M. Letcher

C. L. Young

G. M. Schneider

F. L. Swinton

A. G. Williamson

C. M. Knobler

R. L. Scott

C. P. Hicks

Statistical Methods for Calculating Thermodynamic

Functions

Metallurgical Thermochemistry at High Temperatures

The Measurment of Thermodynamic Excess Functions

of Binary Liquid Mixtures

Activity Coefficients at Infinite Dilution from

Gas- Li quid Chromatography

Experimental Methods for Studying Phase Behavior

of Mixtures at High Temperatures and Pressures

High-Pressure Phase Diagrams and Critical

Properties of Fluid Mixtures

Mixtures Containing a Fluorocarbon

Specific Interactions in Nonelectrolyte Mixtures

Volumetric Properties of Gaseous Mixtures

Critical Exponents for Binary Fluid Mixtures

A Bibliography of Thermodynamic Quantities for

Binary Fluid Mixtures
37

[91] McMeekin, T. L. The Solubility of Biological Compounds

in "Solutions and Solubilities," Part I. (M. R. J. Dack, editor)

(John Wiley and Sons, New York, 1975)

This chapter contains a discussion on systematic studies on the solubilities

of proteins and lipids. The author has attempted to relate solubility to

structure and has included several tables and plots giving solubilities of

amino acids, proteins, lipids and fatty acids. There are 62 references to the

1 i terature.

**********

[92] McMillen, D. F. and Golden, D. M. Hydrocarbon Bond Dissociation Energies

Annual Reviews of Physical Chemistry 33, 493 (1982)

This review article contains "best" values of bond-dissociation energies at

298.15 K of hydrocarbons and their nitrogen, oxygen, sulfur, halogen, and

silicon derivatives. There is also some limited data on inorganic molecules.

The tables include data on A^H° of the related radicals. The authors provide

references to a dozen earlier reviews on this subject and there are 242

references to the source literature. Also see item [162].

**********

[93] Medvedev, V. A., Bergman, G. A., Gurvich, L. V., Yungman, V. S. , Vorob'ev,

A. F. , Kolesov, V. P. and others (V. P. Glushko, general editor)

Thermal Constants of Substances (Volumes 1 to 10)

(in Russian)

(Viniti, Moscow, 1965 to 1982)

This extensive series represents many years of effort by numerous Russian

thermodynami cists engaged in the critical evaluation of thermodynamic data.

Included in the tables are carefully selected values of A^G° , A^H°, S°, H-j--Hq,

and C at 298.15 K for the elements and their compounds including many aqueous

speciis. Also given are dissociation energies of gases and enthalpies of

phase changes. There are extensive references to the primary literature from

which the tabulated values were obtained. Carbon and its compounds are covered

up to two carbon atoms. The coverage and arrangements of substances is similar

to that used in the NBS Tables of Chemical Thermodynamic Properties (see item

[149]).

**********

[94] Meites, L. (editor)

Handbook of Analytical Chemistry

(McGraw-Hill Book Co., New York, 1963)

This treatise on analytical chemistry contains several useful tabulations of

thermochemical data. Some of these tabulations are taken directly from other

sources cited in this bibliography and are not included below:
38

Author(s) Title of Section

V. E. Bowers and R. G. Bates Equilibrium Constants of Proton-transfer

Reactions in Water

(Section 1, Table 1-10)

Tabulated are pK values at 15, 25, and 35 °C for about 200 organic and

inorganic acids; no literature references are given.

L. Meites Formal Equilibrium Constants of Protontransfer Reactions at Finite Ionic Strength

(Section 1, Table 1-11)

This section contains a tabulation of pK values at 25 °C for a selected series

of about 150 acids, and bases. These data were taken from Bjerrum, Schwarzenbach,

and Si 11 en, "Stability Constants of Metal Complexes," Part I, The Chemical Society

London, 1957 which was later revised by Sillen and Martell (see item [1373). Also

given are tables of acid dissociation data pertinent to ethanol-water and

methanol -water mixtures.

D. A. Aikens and C. N. Reilley Formation Constants of Metal Complexes

(Section 1, Table 1-17)

Tabulated are log K values for the binding of the more common inorganic metal

ions to 55 ligands. AH and AS values are also given for four ligands. Literature references are given.

**********

[95] Merrill, A. L. and Watt, B. K. Energy Value of Foods: Basis and Derivation

Agriculture Handbook No. 74

(U.S. Government Printing Office, Washington, D.C., 1955)

Watt, B. K. and Merrill , A. L. Composition of Foods: Raw, Processed, Prepared

Agriculture Handbook No. 8 (revised)

(U. S. Government Printing Office, Washington, D.C., 1963)

This pair of monographs provides numerous composition and energy values for

food and foodstuff ingredients. It should be noted, of course, that the

Calorie used in food energy values is one kilocalorie (4.184 kJ) as used in

thermochemistry. In Agriculture Handbook No. 74, Part I gives a discussion of

the sources of food energy in terms of organic compound class, and of the

experimental determination of enthalpies of combustion. Parts II, III, and IV

apply the data to physiological processes. An appendix gives composition and

enthalpy of combustion of foods. Tables 1 to 5 and table 24 give enthalpies

of combustion of specific food items or component substances. Care should be

used in, taking values from the numerous tables, as correction factors have
39

sometimes been applied to adjust for physiological processes. These

adjustments are indicated by footnotes. In Agriculture Handbook No. 8,

Appendix A is of particular interest as it gives notes on energy values and

nutrients, including (adjusted) enthalpies of combustion of many foods and

food ingredients.

**********

[96] Milazzo, G. and Caroli, S. Tables of Standard Electrode Potentials

(John Wiley and Sons, New York, 1978)

This book contains extensive tables of standard electrode potentials covering

the periodic chart. For each electrode reaction is given the standard

potential, the temperature and the pressure, the solvent, and a literature

reference. Occasionally the temperature coefficient of the electrode

potential is given together with an estimate of uncertainty. Much of

the tabulated data is taken from secondary sources (such as item [149]).

**********

[97] Miller, D. G. Application of Irreversible Thermodynamics to Electrolyte Solutions.

I. Determination of Ionic Transport Coefficients for Isothermal

Vector Transport Processes in Binary Electrolyte Systems.

Journal of Physical Chemistry 70, 2639 (1966)

II. Ionic Coefficients for Isothermal Vector Transport Processes in

Ternary Systems. ^

These papers derive equations relating fundamental isothermal transport

coefficients (£..'s) to experimentally measurable quantities for electrolytes

in a neutral solvent. £..'s for the most common aqueous ionic solutions are calculated from critically

1 reviewed data.

**********

[98] Millero, F. J. The Partial Molal Volumes of Electrolytes in Aqueous Solutions.

Compilation of the Partial Molal Volumes of Electrolytes at Infinite

Dilution, V° and the Apparent Molal Volume Concentration Dependence

Constants, S* and b , at Various Temperatures, in

Water and Aqueous Solutions, R. A. Home (editor)

(John Wiley and Sons, Interscience Publishers, New York, 1972)

This chapter (no. 13 in this book) is concerned with the measurement and

interpretation of partial molar volumes and their concentration and temperature dependence. Included are tables of the partial molar volumes of the common inorganic and organic electrolytes (about 200 systems) as well as values of the partial molar volumes of the more common inorganic and organic

ions (about 100 species). The data refer to temperatures from 0 to 200 °C.

Also see items [99] and [123].

**********

[99] Millero, F. J. The Molal Volumes of Electrolytes

Chemical Reviews 71, 147 (1971)
40

This is a detailed and thorough review article dealing with molar volumes of

electrolytes in water. Included is a history and discussion of theoretical

developments associated with molar volumes. Tabulated are the partial molar

volumes of the common (about 50) inorganic and organic ions in water at

temperatures ranging from zero to 200 °C. Also is given partial molar volume

data for non-aqueous systems. There are 366 references to the literature.

Also see item [98] and [123].

**********

[100] Mishchenko, K. P. and Pol toratzki i

, G. M. Aspects of the Thermodynamics and Structure of Aqueous and Non-Aqueous

Electrolyte Solutions

(in Russian)

(Izdatelstvo Khimia, Leningrad, 1968)

This 350 page monograph contains extensive discussions and correlations

(theoretical and empirical) of existing experimental data on enthalpies, Gibbs

energies, and entropies, of solution and ionization of inorganic acids, bases,

and salts in water and selected organic solvents. Heat capacities, enthalpies,

Gibbs energies, and entropies of the substances and their ions in solution are also discussed. Extensive use is made of diagrams relating observed properties

to periodic groupings of the elements. The monograph contains numerous small

tables of properties of limited groups of substances. A summary compilation

of selected values of thermodynamic properties occupies 43 pages, giving A.G0

, A

fH°, S° and C° of pure and dissolved inorganic substances in their standard

state at 25 °C? selected enthalpies of solution at 25 °C, enthalpies of

dilution of common acids, bases, and salts at 25 °C, and heat contents and

partial molar heat capacities for selected salts vs. concentration and temperature in water, methanol, ethanol , and a few other organic solvents.

**********

[101] Morss, L. R. Thermochemical Properties of Yttrium, Lanthanum,

and the Lanthanide Elements and Ions

Chemical Reviews 76, 827 (1976)

This review presents tables of values of A^H0

, and S° at 25 °C for the aqueous

ions of yttrium, lanthanum, and the lanthanide elements based upon both

experimental measurement data and a group correlation scheme.

**********

[102] Nancollas, George H. Interactions in Electrolyte Solutions

(Elsevier, Amsterdam, 1966)

This monograph contains a general discussion of the methodology, kinetics,

mechanisms, structural features, and general thermodynamic trends of ionic

association reactions in solution. In the Appendix there are several tables

of thermodynamic functions for ion-association reactions with references to

the source literature.

**********
41

[103] Naumov, G. B. , Rhyzhenko, B. N. and Khodakovsky, I. L. Handbook of Thermodynamic Quantities

(in Russian)

(Atomizadat, Moscow, 1971)

This reference book contains a compilation of thermodynamic data for about 2000

chemical compounds and aqueous ions (mostly inorganic). The thermodynamic

properties tabulated are A

f

G°, AJH°, S°, and C° at 298.15 K, electrode potentials, enthalpies and entropies for phase traniitions, A

fG° of inorganic aqueous

ions from 25 to 350 °C, partial molar heat capacities from 10 to 130 °C, and the

partial molar volumes of aqueous electrolytes at high temperatures and pressures. There are 1550 references given to the primary literature and to the

literature evaluations of others.

**********

[104] National Bureau of Standards Electrolyte Data Center

A series of papers, published in the Journal of Physical and Chemical

Reference Data from 1977 to 1981.

This series of papers contains evaluations leading to recommended values of

activity and osmotic coefficients and excess Gibbs energies of aqueous

electrolyte solutions at 298.15 K. The data are presented both in tabular

form as a function of molality and as coefficients of several correlating

equations. The correlations are detailed and include a careful statistical

analysis of the data and references to the source literature. The data cover

the entire composition range for which data exist and include most of the

electrolytes of charge type 12 and 21 (also see items [48], [121], [124], and

[128]). The papers in the series are:

Author(s) Title of Paper

B. R. Staples and R. L. Nuttall The Activity and Osmotic Coefficients of

Aqueous Calcium Chloride at 298.15 K

Journal Physical and Chemical Reference Data 6, 385 (1977)

R. N. Goldberg and R. L. Nuttall Evaluated Activity and Osmotic Coefficients for

Aqueous Solutions: The Alkaline Earth Metal

Hal ides

Journal of Physical and Chemical Reference Data 7, 263 (1978)

R. N. Goldberg, B. R. Staples and

R. L. Nuttall

Evaluated Activity and Osmotic Coefficients for

Aqueous Solutions: Iron Chloride and the

Bi-univalent Compounds of Nickel and Cobalt
42

Journal of Physical and Chemical Reference Data 8, 923 (1979)

R. N. Goldberg Evaluated Activity and Osmotic Coefficients fo

Aqueous Solutions: Bi-univalent Compounds of

Lead, Copper, Manganese, and Uranium

Journal of Physical and Chemical Reference Data 8, 1005 (1979)

R. N. Goldberg Evaluated Activity and Osmotic Coefficients fo

Aqueous Solutions: Bi-univalent Compounds of

Zinc, Cadmium, and Ethylene Bis

(Trimethylammounium) Chloride and Iodide

Journal of Physical and Chemical Reference Data K), 1 (1981).

R. N. Goldberg Evaluated Activity and Osmotic Coefficients fo

Aqueous Solutions: Thirty-Six Uni-Bivalent

Electrolytes

Journal of Physical and Chemical Reference Data 10, 761 (1981)

B. R. Staples Activity and Osmotic Coefficients of Aqueous

Metal Nitrites

Journal of Physical and Chemical Reference Data JO, 765 (1981)

B. R. Staples Activity and Osmotic Coefficients of Aqueous

Sulfuric Acid

Journal of Physical and Chemical Reference Data 1_0, 779 (1981)

**********

[105] Nyvlt, J. Solid-Liquid Phase Equilibria (Elsevier, Amsterdam, 1977)

This 246 page monograph contains tables of solubilities as a function of

temperature of approximately 350 compounds to form binary and ternary

mixtures. The substances are mostly inorganic and include only 22 organic

compounds. Also included are enthalpies of solution of the substances into

pure water. The author does not give references to the primary literature.

**********
43

[106] Getting, F. L. , Medvedev, V., Rand, M.H. and Westrum, E.F., Jr. (editors)

The Chemical Thermodynamics of Actinide Elements and Compounds

(International Atomic Energy Agency, Vienna, 1976 to present)

This series of books contains thermodynamic data (heat capacities, formation

properties, thermal functions, vapor pressures, and many other properties)

for the actinide elements and their compounds. In addition to extensive

tables of data there is also a discussion of the sources from which the

data have been taken and the calculations performed. Parts 2 and 3 contain

data on the aqueous ions of the actinide elements. To date, the parts

which have been published are:

Author(s) Title Part No.

F.L. Oetting, M.H. Rand and The Actinide Elements 1

R. J. Ackermann

J.\ Fuger and F. L. Oetting The Actinide Aqueous Ions 2

E. H. P. Cordfunke and Miscellaneous Actinide Compounds 3

P. A. G. O'Hare

P. Chioti, V. V. Akhachinski j,

I. Ansara, and M. H. Rand The Actinide Binary Alloys 5

Parts 4 (Chalcogenides) , 6 (Carbides), 7 (Pnictides), and

8(Halides) are scheduled for publication in 1983.

**********

[107] Ohe, S. (editor)

Computer Aided Data Book of Vapor Pressure

(Data Book Publishing Co., Tokyo, 1976)

This lengthy book (2000 pages) contains extensive plots of vapor pressures for

various pure substances, both organic and inorganic, as a function of temperature as well as the constants of the Antoine equation. Included is a substance index and references to the literature.

**********

[108] Olofsson, G. and Hepler, L. G. Thermodynamics of Ionization of Water Over Wide Ranges of Temperature

and Pressure

Journal of Solution Chemistry 4, 127 (1975)

This review ties together equilibrium and thermal data to obtain "best" values

for AG°, AH°, AC° , AV° , and Ak° (the isothermal compressibility change) for

the ionization o? water over the temperature range 0 to 300 °C and the pressure

range 1 to 8000 atmospheres. Also see item [88].
44

[109] Parker, V. B. , Staples, B. R. , Jobe, T. L. , Jr. and Neumann, D. B. A

Report on Some Thermodynamic Data for Desulfurization Processes

(NBSIR 81-2345, National Bureau of Standards, Washington, D.C., 1981)

This report contains values of thermochemical properties and processes pertinent

to coal gas desulfurization. Substances covered include solutions formed from

the aqueous ions; OH , SO*-, HSO3, SOI", CO2 -

, HCO3, H , Mn2+, Fe2+

, Mg2+,

Ca 2+

, Na , and K and include solid, liquid, aqueous and gaseous compounds or species formed from these ions. Properties given are AfG°, AfH°, S°, C°

(Hj-HL), L y

±

, and $ at 298.15 K. Predicted values of AG°, AH° , AS°, Rnd

AC* for important desulfurization processes were calculated from the formation

properties. These data are consistent with the data in item [149].

**********

[110] Parker, V. B. The Thermochemical Properties of the Uranium-Halogen Containing Compounds

(NBSIR 80-2029, National Bureau of Standards, Washington, D.C. , 1980)

This report contains a detailed evaluation of the thermochemistry of 142 uraniumhalogen containing compounds. The properties given are A

f H°, AfG°, S°, C°, and

(H

T

-H

0

), all at 298.15 K, and A

f

H° at 0 K. The analysis of much of the dita

involves the consideration of the aqueous chemistry of uranium containing

compounds (also see item [149]). The recommended values are consistent with

the C0DATA scale (item [23]).

**********

[111] Parker, V. B. Thermal Properties of Aqueous Uni-univalent Electrolytes

(NSRDS NBS 2, U.S. Government Printing Office, Washington, D.C, 1965)

This monograph is a review of the heat-capacity, enthalpy-of-solution, and

enthalpy-of-di 1 ution data on simple 1-1 electrolytes, organic and inorganic,

in aqueous solutions. From the critical analysis of this data, tables of

selected "best" values of apparent heat capacities, and enthalpies of dilution

are given, as well as selected values of the enthalpies of solution to the

infinitely dilute solution. Also included is a review of data on the enthalpies

of neutralization of monobasic acids which has led to a selected "best" value

for the enthalpy of ionization of water. Data on each property are introduced

with a discussion of methods employed in reducing the data to a standard form

and are listed by compound, in the order: acids, ammonium and amine salts,

silver salts, and salts of the alkali metals. For each compound are listed the

various investigations, with the temperature and range of concentrations measured

Graphs of molar heat capacity and molar enthalpy as functions of concentration

are also included, for aqueous solutions of many of the compounds discussed. In

addition, there is an abbreviated listing, by compound, of review and compilation

papers on the thermal properties of the aqueous uni-univalent electrolytes.

These and other references are also listed alphabetically in a separate reference

section with 652 entries. The chosen "best" values at 25 °C for each parameter

and compound are arranged in a series of 21 tables.
45

[112] Parker, V.B., Wagman, D. D. and Garvin, D. Selected Thermochemical Data Compatible with the CODATA Recommendations

(NBSIR 75-968, National Bureau of Standards, Washington, D.C., 1976)

Selected thermochemical properties, A

fG°, AfH°, S° , (all at 298.15 K) , AfH°

(0 K), and H (298.15 K) - H (0 K), are" given for 384 substances (almost f

entirely inorganic) including many of the more commonly encountered aqueous

species. The selected values are intended to be compatible with the current

CODATA recommendations on key values for thermodynamics (see item [23]).

**********

[113] Parsons, R. Handbook of Electrochemical Constants

(Academic Press, New York, 1959)

This handbook contains extensive tables of data for the more common inorganic

and organic aqueous electrolyte solutions. Properties covered include dielectric constants, activity coefficients, relative partial molar enthalpies,

equilibrium constants, solubility products, conductivities, electrochemical

potentials, Gibbs energies and enthalpies of formation, entropies, heat

capacities, viscosities, and diffusion coefficients, Unfortunately, only a few of the tables contain references to the sources of the data.

**********

[114] Pauling, L. The Nature of the Chemical Bond (third edition)

(Cornell University Press, Ithaca, New York, 1960)

This well established monograph provides general information about the nature

of chemical bonding in (principally) inorganic compounds which is fundamentally

very important for the estimation of enthalpies of formation, but not always

easily applied.

**********

[115] Pedley, J. B. (editor)

Computer Analysis of Thermochemical Data (CATCH Tables)

(University of Sussex, Brighton, England, 1972 to 1974)

These thermochemical tables consist of enthalpies of formation at 298.15 K

calculated from thermochemical data networks. Included are appropriate

references to the literature and estimated errors in the enthalpies of formation. An interesting and important feature of this scheme is that the

tables can be readily updated by computer. These tables contain a substantial

amount of data for aqueous species. The following tables have been published:

Author(s) Element(s) Year

J. D. Cox Halogen Compounds (Fluorine,

Chlorine, Bromine, Iodine)

1972
46

G. Pi 1 cher Nitrogen 1972

A. J. Head Phosphorus 1972

J. B. Pedley and

B. S. Iseard

Si 1 icon 1972

D. S. Barnes Chromium, Molybdenum and

Tungsten

1974

**********

[116] Pedley, J. B. and Rylance, J. Sussex - N. P. L. Computer Analysed Thermochemical Data:

Organic and Organometal 1 ic Compounds

(Sussex University, Brighton, England, 1977)

This book contains enthalpy data on « 4000 compounds and 5000 chemical

processes involving organic and organometall ic compounds. Much of the

processing of the data was done by computer (see item [150]). Properties

which are presented include enthalpies of combustion, formation, sublimation,

vaporization, and reaction. It is also a revision of the values published by

Cox and Pilcher (item [28]). There are « 450 references to the sources from

which the data were taken.

[117] Perrin, D. D. Dissociation Constants of Inorganic Acids and Bases in Aqueous Solution

(Butterworths , London, 1969)

This short (163 pp.) monograph is a compilation of dissociation constants of

217 inorganic acids and bases. The classes of compounds include not only con- ventional acids and bases, but also hydrated metal ions and free radicals,

such as hydroxyl , the only criterion being gain or loss of a proton or hydroxyl ion. The data are organized into a single table listing the com- pounds, preceded by a brief introduction to the use of table, and a section on methods of measurement and calculation. The methods are classified as con- ductometric, el ectrometri c , optical, or other. Elements and compounds are listed in decreasing extent of protonation. pK values are, wherever possible,

obtained by extrapolation to zero ionic strength. The table also gives the

temperature of each measurement, remarks as to ionic strength, concentration,

and any other factors relating to pK, coded references to method of measurement, the procedure used in evaluating the constants and any corrections taken

into consideration, and the literature references. There are approximately

1100 references listed alphabetically by author.

**********

**********

[118] Perrin, D. D. Dissociation Constants of Organic Bases in Aqueous Solution

(Butterworths, London, 1965)
47

This book contains values of dissociation constants for organic bases in

aqueous solution. The bases are arranged under the headings aliphatic,

alicyclic, aromatic, heterocyclic, natural products, dyes and indicators,

substances lacking a basic nitrogen atom, and miscellaneous. Accompanying the

data entry for each base is the temperature, method of measurement, formula,

assessment of the measurement, and the appropriate reference. There are 3790

data entries in this book. Also see item [73].

**********

[119] Phillips, R. Adenosine and the Adenine Nucleotides. Ionization, Metal Complex

Formation, and Conformation in Solution

Chemical Reviews 66, 501 (1966)

This article is a detailed review of the thermodynamics, kinetics, and structural

characteristics of adenosine and the adenine nucleotides in solution. Both log K and enthalpy data are tabulated for protonation and metal-ion binding reactions

to adenosine and the adenine nucleotides. The conditions are given under which

the tabulated data are applicable, namely, ionic strength, temperature, supporting

electrolyte, pH, method of measurement, as well as references to the original

data source. **********

[120] Phillips, R. C. , George, P., and Rutman, R. J. Thermodynamic Data Jor the Hydrolysis of Adenosine Triphosphate as a Function of pH, Mg2 Ion Concentration, and Ionic Strength

Journal of Biological Chemistry 244, 3330 (1969)

This article deals with the computation of the Gibbs energy change for the

hydrolysis of adenosine-5 1 -triphosphate to adenosi ne-5 1 -diphosphate as a function of magnesium ion concentration, pH, and ionic strength at 25 °C.

A critical evaluation of the existing data pertinent to this computation is

included. References to 24 papers are given. Also see item [1].

**********

[121] Pitzer, K. S. and others

Thermodynamics of Electrolytes

(A series of papers published in several journals)

This series of papers contains an extensive array of correlated data on aqueous

electrolyte solutions, much of it having been calculated using the system of

equations given in paper I in this series. The contents of these papers

have been summarized by Pitzer in a chapter in the book edited by Pytkowicz

(see item [123]). The data include activity and osmotic coefficients, relative

apparent molar enthalpies and heat capacities, excess Gibbs energies,

entropies, heat capacities, volumes, and some equilibrium constants and

enthalpies. Systems of interest include both binary solutions and multicomponent mixtures. While most of the data pertain to 25 °C, the papers on sodium chloride, calcium chloride, and sodium carbonate cover the data at the

temperatures for which experiments have been performed. Also see items [48],

[104], and [124].
48

The papers in this series which contain data relevant to this bibliography

are:

Pitzer, K.S.

Thermodynamic Properties of Aqueous Solutions of Bivalent Sulphates

Journal of the Chemical Society, Faraday Transactions II 68, 101 (1972).

Pitzer, K.S. and Mayorga, G. Thermodynamics of Electrolytes. II. Activity and Osmotic Coefficients for

Strong Electrolytes with One or Both Ions Univalent

Journal of Physical Chemistry 77, 2300 (1973).

Pitzer, K.S. and Mayorga, G. Thermodynamics of Electrolytes. III. Activity and Osmotic Coefficients

for 22 Electrolytes

Journal of Solution Chemistry 3, 539 (1974).

Pitzer, K.S. and Kim, J.J.

Thermodynamics of Electrolytes IV. Activity and Osmotic Coefficients for

Mixed Electrolytes

Journal of the American Chemical Society 96, 5701 (1974).

Pitzer, K.S. and Silvester, L.F.

Thermodynamics of Electrolytes. VI. Weak Electrolytes Including H 3 P0

Journal of Solution Chemistry 5 , 269 (1976).

Pitzer, K.S. , Roy, R.N. and Silvester, L.F.

Thermodynamics of Electrolytes VII. Sulfuric Acid

Journal of the American Chemical Society 99, 4930 (1977).

Silvester, L.F. and Pitzer, K.S.

Thermodynamics of Electrolytes. 8. High-Temperature Properties,

Inclduing Enthalpy and Heat Capacity, with Application to Sodium Chloride

Journal of Physical Chemistry 81, 1822 (1977).

Pitzer, K.S., Peterson, J.R. and Silvester, L.F.

Thermodynamics of Electrolytes. IX. Rare Earth Chlorides, Nitrates and

Perchlorates.

Journal of Solution Chemistry 7, 45 (1978).
49

Silvester, L.F. and Pitzer, K.S.

Thermodynamics of Electrolytes. X. Enthalpy and the Effect of Temperature

on the Activity Coefficients.

Journal of Solution Chemistry 7, 327 (1978).

Pitzer, K.S. and Silvester, L.F.

Thermodynamics of Electrolytes. II. Properties of 3:2, 4:2, and Other

High- Valence Types

Journal of Physical Chemistry 82, 1239 (1978).

Bradley, D.J. and Pitzer, K.S.

Thermodynamics of Electrolytes 12. Dielectric Properties of Water and DebyeHuckel Parameters to 350 °C and 1 kbar

Journal of Physical Chemistry 83, 1599 (1979).

Pitzer, K.S. and Peiper, J.C.

Activity Coefficients of Aqueous NaHC03

. Journal of Physical Chemistry 84, 2396 (1980).

Peiper, J.C. and Pitzer, K.S.

Thermodynamics of Aqueous Carbonate Solutions Including Mixtures of

Sodium Carbonate, Bicarbonate, and Chloride

Journal of Chemical Thermodynamics 14, 613 (1982).

Rogers, P.S.Z. and Pitzer, K.S.

Volumetric Properties of Aqueous Sodium Chloride Solutions

Journal of Physical and Chemical Reference Data 11, 15 (1982).

Pitzer, K.S.

Theory: Ion Interaction Approach in "Activity Coefficients in Electrolyte

Solutions," R.M. Pytokowicz (editor)

(CRC press, Boca Raton, Florida, 1979).

See item [123]

Roy, R.N., Gibbons, J.J,, Peiper, J.C. and Pitzer, K.S.

Thermodynamics of the Unsymmetrical Mixed Electrolyte HCl-LaCl 3

Journal of Physical Chemistry, 87, 2365 (1983).
50

deLima, M.C.P and Pitzer, K.S.

Thermodynamics of Saturated Aqueous Solutions Including Mixtures of

NaCl , KC1 , and CsCl

Journal of Solution Chemistry, 12, 171 (1983).

deLima, M.C.P. and Pitzer, K.S.

Thermodynamics of Saturated Electrolyte Mixtures of NaCl with Na2 S04 and with MgCl 2 Journal of Solution Chemistry, 12, 187 (1983).

Phutela, R.C. and Pitzer, K.S.

Thermodynamics of Aqueous Calcium Chloride

Journal of Solution Chemistry, 12, 201 (1983).

Pitzer, K.S., Peiper, J.C. and Busey, R.H.

Thermodynamic Properties of Aqueous Sodium Chloride Solutions

Journal of Physical and Chemical Reference Data, in review

**********

[122] Pourbaix, M. (and others)

Atlas of Electrochemical Equilibrium in Aqueous Solution

(Pergamon Press, Oxford, 1966)

This book contains tabulations of Gibbs energy of formation data for many of

the principal compounds of the inorganic elements. Electrochemical potentials

and their dependence on pH, are calculated for many important couples. Much

of the Gibbs energy data is taken from the evaluations and compilations of

others. Of particular utility are the species-composition or predominance

diagrams which appear in this book.

**********

[123] Pytkowicz, R. M. (editor) Activity Coefficients in Electrolyte Solutions

(in two volumes) (CRC Press, Boca Raton, Florida, 1979)

This two volume series has several chapters dealing with various aspects

of electrolyte solutions. The chapters which contain tables of thermodynamic

data and/or a particularly useful collection of references to such literature

are:

Author Title of Chapter

K. S. Pitzer Theory: Ion Interaction Approach

This chapter (no. 7 in Volume I) contains a summary of much of the

research done by K. S. Pitzer and his collaborators on the development
51

of models for electrolyte solutions and on the representation of thermodynamic properties of electrolyte solutions in terms of these models.

The tables in this chapter include: Debye-H'uckel parameters for the

osmotic coefficient, enthalpy, and heat capacity as a function of

temperature; parameters for the activity and osmotic coefficients of

approximately 270 aqueous strong electrolytes at 25 °C; parameters for

the relative apparent molar and excess enthalpy of «• 90 strong electrolytes

at 25 °C; a table of parameters for the activity and osmotic coefficients

of w75 binary mixtures with and without common ions and with up to three

solutes present; and parameters for the thermodynamic properties of

aqueous NaCl and H2 S04 as a function of temperature. The author has

included references to his earlier papers which also contain valuable

data on electrolyte solutions (also see item [121]).

F. J. Mi Hero Effects of Pressure and Temperature on Activity Coefficients

This very extensive (99 pages) chapter (no. 2 in Volume II) contains a general discussion of the effects of temperature and pressure on activity

coefficients for both binary and mixed electrolyte solutions. Properties

of interest are the partial molar volume, expansibility, compressibility,

heat capacity, and enthalpy. There is also an excellent discussion of

methods of estimating partial molar properties in mixed electrolyte

solutions. 'There are 226 references to the literature. Tables of data

are presented for: Debye-Hiickel limiting law slopes for the apparent

molar volume, enthalpy, heat capacity, expansibility, and compressibility

as a function of temperature; parameters for the partial molar volumes

of 30 aqueous electrolyes at 25 °C; parameters for the partial molar

expansibility of ten electrolytes at 25 °C; parameters for the partial

molar compressibilities of 33 electrolytes at 25 °C; values of the

activity coefficients of aqueous NaCl solutions at 25 °C as a function

of pressure (up to 1000 bars); parameters for the partial molar enthalpies

of 59 electrolytes at 25 °C; parameters for the partial molar heat

capacities of 140 electrolytes at 25 °C; and tables giving compositions

and the partial molar properties of average seawater.

M. Whitfield Activity Coefficients in Natural Waters

This long (147 pages and 266 references) and very detailed chapter (no.

3 in Volume II) contains a very extended discussion of the thermodynamics

of mixtures of aqueous electrolyte solutions with emphasis upon the

properties of natural waters. There is a very extensive collection of

tables in this article (116 in total) and the contents of this many

tables is not easily summarized in our survey. Included are the following:

association constants for the formation of ion pairs and weak acids;

activity coefficients for both the ions and major components of sea water; formation constants for the binding of heavy metals to several

anions found in sea water; gas solubilities including carbon dioxide in sea water; solubilities of polychlori nated biphenyls in sea water;
52

Setchenow coefficients for hydrocarbons and for volatile solutes in sea water; the osmotic coefficient and density of sea water as a function of

temperature and salinity. Thermodynamic solubility products of minerals

in brines; the activity coefficient of carbon dioxide in sea water;

speciation calculations on copper, zinc, cadmium, and lead in sea water; excess Gibbs energies of mixing of electrolyte solutions at 25 °C; and

pairwise and triplet interaction terms for electrolyte solutions in

terms of various models.

**********

[124] Rard, J. A., Habenschuss, A. and Spedding, F. H. A Review of the Osmotic Coefficients of Aqueous H2 S04 at 25 °C

Journal of Chemical and Engineering Data 2]_> 374 (1976)

and

A Review of the Osmotic Coefficients of Aqueous CaCl 2 at 25 °C

Journal of Chemical and Engineering Data 22, 180 (1977)

These two articles are critical evaluations of experimental data leading to

values of the osmotic coefficients at 25 °C of the two reference electrolytes

calcium chloride and sulfuric acid. Also see items [104] and [121].

**********

[125] Reid, R. C. , Prausnitz, J. M. , and Sherwood, T. K. The Propertfes of Gases and Liquids, Their Estimation and Correlation

(third edition)

(McGraw-Hill, New York, 1977)

This lengthy monograph discusses various methods available for calculation of

estimating properties of materials, and then provides recommendations for

action with respect to each kind of property. Included in the book are procedures for making estimates of critical constants, normal boiling temperatures,

Lennard-Jones potential parameters, compressibility factors and equations of

state, liquid molar volumes and densities, and vapor pressures. Estimates of

enthalpies of vaporization, of ideal-gas heat capacities, and of enthalpies

and Gibbs energies of formation are treated. For real fluids variations of

enthalpy, entropy, internal energy, and heat capacity with pressure are treated.

Some methods are given for estimating the properties of fluid mixtures. Surface

tension and the transport properties-viscosity, diffusion coefficient "and

thermal conductivity-are discussed. Numerous tables present comparisons of

observed and calculated properties. The Appendix contains tables of

thermodynamic properties of many organic compounds.

**********

[126] Riley, J. P. and Skirrow, G. (editors)

Chemical Oceanography (in six volumes)

(Academic Press, New York and London, 1975 and 1976)

This six volume series contains 34 chapters on various topics related to

chemical oceanography. Contained in these chapters is a wealth of chemical

and physical information on the properties of sea water and its constituents
53

as well as useful references to the primary literature. Several topics of

thermodynamic interest are the solubilities of gases and salts, chemical

speciation of the major and minor constituents of sea water, densities,

activity and osmotic coefficients, expansibilities, isothermal compressibilities,

velocity of sound, heat capacities, and transport and optical properties of sea water. The Appendix contains a useful series of tables of many of these

properties. Also see [80]. **********

[127] Geological Survey Bulletins

Robie, R. A. , Hemingway, B. S. and Fisher, J. R. Thermodynamic Properties of Minerals and Related Substances at 298.15 K

and 1 Bar (10 5 Pascals) Pressure and at Higher Temperatures

Geological Survey Bulletin 1452

(U.S. Government Printing Office, Washington, D.C., 1978)

and

Hemingway, B. S. , Haas, J. L. , Jr., and Robinson, G. R. , Jr.

Thermodynamic Properties of Selected Minerals in the System

Al 2 0 3 -Ca0-Si02 -H2 0 at 298.15 K and 1 Bar (10 5 Pascals)

Pressure and at Higher Temperature

Geological Survey Bulletin 1544

(U.S. Government Printing Office, Washington, D.C., 1982)

The 1978 publication is a 456 page monograph containing selected values for

the entropy, molar volume, and for the enthalpy and Gibbs energy of formation

for the elements, 133 oxides, and 212 other minerals and related substances at

298.15 K. Thermal functions are also given for those substances for which

heat-capacity or heat-content data are available. The thermal functions are tabulated at 100 K intervals for temperatures up to 1800 K. The monograph

includes detailed references to the source literature and a compound index.

Also see items [42] and [144].

The 1982 publication is a supplement to Geological Survey Bulletin 1452. It

contains a survey of thermodynamic data for minerals in the system

Al 2 0 3 -Ca0-Si02 -H2 0 and tabulated values for C° , (H°-H° (298.15 K))/T, (G°-H°

(298.15 K))/T, A

f

H°, and A

f

G° from 298.15 to 2800 K. The calculations are

well documented both as to computational procedures and the sources of data.

**********

[128] Robinson, R. A. and Stokes, R. H. Electrolyte Solutions. The Measurement and Interpretation of

Conductance

,

Chemical Potential and Diffusion in Solution of Simple Electrolytes

(Second edition)

(Butterworths , London, 1965)

In this, the revised second edition of a monograph first published in 1955,

the first part presents a fundamental discussion of aqueous organic and

inorganic electrolyte solutions. Included is a discussion of ionizing

solvents (i.e. water), electrolytic conductivities and transport numbers, the
54

measurement and interpretation of chemical potentials; the theory of diffusion

(emphasizing conductance and viscosity in concentrated solutions), and methods

of measurement of diffusion coefficients. The final third of the text deals

primarily with characteristics of specific electrolyte solutions, including

weak and mixed electrolytes, and strong acids, and includes an extensive (98

pp.) appendix with approximately 75 tables of osmotic and activity coefficients,

standard cell potentials (E°) in various organic solvents, ionic radii, and

ionization constants of organic acids in aqueous solution, and other information. The narrative is supplemented with graphs, tables, equations, and

references.

[129] Rosenblatt, David H. (editor)

Research and Development of Methods for Estimating Physicochemical

Properties of Organic Compounds of Environmental Concern (in two volumes)

(Arthur D. Little, Cambridge, Massachusetts, 1981)

These two volumes contain twenty-six chapters, each one dealing with a method

for estimating a physico-chemical property of environmentally important

organic compounds. For the most part, each chapter provides: "(1) a general

discussion of the property and its importance in environmental considerations,

(2) an overview of available estimation methods, (3) a description plus step--

by-step instructions for each selected method, (4) worked-out examples for

each method, (5) a listing of sources of available data on the property, (6) a list of symbols uSed, and (7) the cited references." The chapters in the

book are:

Author(s) Title of Chapter

W.J. Lyman Octanol /Water Partition Coefficient

W.J. Lyman Solubility in Water

W.J. Lyman Solubility in Various Solvents

W.J. Lyman Adsorption Coefficient for Soils and Sediments

S.E. Bysshe Bio-concentration Factor in Aquatic Organisms

J.C. Harris and M.J. Hayes Acid Dissociation Constant

J.C. Harris Rate of Hydrolysis

J.C. Harris Rate of Aqueous Photolysis

K.M. Scow Rate of Biodegradation

W.J. Lyman Atmospheric Residence Time

C. F., Grain Activity Coefficient

C.E. Rechsteiner, Jr. Boiling Point
55

C E Rprh?tpi npr UI • neat ui vd(jur 1z.aL.1u1l

C F fir* ui aa ii n1

1

Uarn^y vapui P^oc n C39UI c i iro

c

R. G. Thomas 1 1 1 villus VUluLI 1 1 La L IUII 1 rum riaLci

R. G. Thoma <> Vnl at 1 1 1 7at 1 nn "frrim ^ni

1

v \j 1 a u 1 1 1 jl a \r 1 \j it 1 1 u 111 ou 1 1

W. A. Turkpr anri 1 H. NpI kpn niffll^inn u 1 1 1 us iuii Popf uut 11f T! n'ontc l 1 ciitb inill nil Air» aanrl 11 U Wa+av» Water

JWall*H Hannn 1 IQUUU "i1 aUIn1 FTr 1 ach dill Pft r U 1

1 nt1 1 isC UInf Diir*a rule Cnhc + anrac jUL)5tanCcS

L • H1 1 B M C 1 IXC 1 1 UCIIS 1 I, ICS ui vapui 3 , L 1 LJU 1 Us dnu OUIlUS

C F fira UI u i1 IIn OUI 1 dLc 1 cils 1 Ull

C. F. Grai n T nt p rf

a

1 11 i j a r^ i1 aa 11 Tpn^inn 1 ens iuii with w 1 11 1 Water na Lc l

C F fira ui a ii n1

1

L 1 L|U 1 u visuusl Ly

J D RiU 1 rkptt 1 INC I* L» Upat ranan'tu

J.D. Birkett Thermal Conductivity

1 u L. M. Nel ken and J

.

nU. di rKett Dipole Moment

L.H. Nel ken Index of Refraction

**********

[i3o; Rossini, F. D. , Pi tzer, K. S. , Taylor, W. J. , Ebert, J. P. Kilpatrick, J. E. , Beckett, C. W. , Williams, M. D. and Werner, H. C. Selected Values of Properties of Hydrocarbons

National Bureau of Standards Circular C461

(U. S. Government Printing Office, Washington, D.C. 1947)

and

Rossini, F. D. , Pitzer, K. S. , Arnett, R. L. , Brown, R. M. and

Pimentel , G. C. Selected Values of Physical and Thermodynamic Properties of Hydrocarbons

and Related Compounds

(Carnegie Press, Pittsburgh, Pennsylvania, 1953)

This monograph resulted from the work of American Petroleum Institute (API)

Research Project 44. In the 1953 revision, values are given for 40-odd

physical and thermodynamic properties of several hundred hydrocarbons in

metric and U. S. Customary units. The data in most instances represent

selected values from careful studies, many of which were done in connection

with the same API Research Project. Experimental data are supplemented by

theoretical calculations or empirical correlations. References to the source

data and a bibliography are given.
56

[131] Rossini, F. D. , Wagman, D. D. , Evans, W. H. , Levine, S. , and Jaffe, I. Selected Values of Chemical Thermodynamic Properties

National Bureau of Standards Circular 500

(U. S. Government Printing Office, Washington, D.C., 1952)

This was for many years the most comprehensive authoritative compilation of

thermochemical data at 298.15 K for inorganic substances. All inorganic

substances and organic substances containing two carbon atoms or fewer per

molecule are included if thermodynamic data exist for calculating one of the

properties tabulated. Properties tabulated in Part I are AfG° (0), AfH° (0),

A

f

H° (298.15 K), A

f

G° (298.15 K) , log K

f

, S° (298.15 K), anS C° (298.15 K).

Properties tabulated in Part II are temperature, pressure, entRalpy change,

entropy change and heat capacity change for transition, fusion, and vaporization processes. The data from original sources were critically evaluated and

functions tabulated, maintaining internal consistency by the relationship:

A

f

G° (298.15 K) = A

f

H° (298.15 K) - TA

f

S° (298. 15K). The sources of data for

each data item are listed and a bibliography is included. Part I has been

superseded by the NBS Tables of Chemical Thermodynamic Properties (see [149]).

Much of the data in Part II cannot be found readily elsewhere.

**********

[132] Saline Water Conversion Engineering Data Book - 1975

(National Technical Information Service, Springfield, Virginia, 1975)

This very large (707 pages) book was produced by the M. W. Kellogg Company for

the Office of Saline Water of the U. S. Department of the Interior. The book

contains a large amount of miscellaneous engineering information pertinent to

examples of engineering and cost calculations, materials of construction,

and process flow diagrams for distillation, freezing, reverse osmosis, and

electrodialysis. Included in the tables of physical property data are heat

capacities, enthalpies, vapor pressures, solubilities, equilibrium constants,

critical properties, and mechanical and transport properties. Materials of

interest include sea water and aqueous solutions formed from sodium chloride,

magnesium chloride, calcium sulfate, calcium carbonate, magnesium sulfate, and

hydrocarbons. Much of the data is presented in graphical form with references

to the source from which it was taken.

**********

[133] Sanderson, R. T. Chemical Bonds and Bond Energy

(Academic Press, New York and London, 1971)

This book contains a general discussion of the calculation of bond energies

and gives details of calculations performed on 850 different kinds of bonds

in more than 500 compounds. Although the bond energies refer to the gaseous

state, they are still useful in applications to aqueous systems. The Appendix

contains a table of bond energies and enthalpies of formation. The chemical

bonds are both inorganic and organic in nature. Also see items [11] and [92].
57

[134] Schmidt, E. Properties of Water and Steam in SI Units

(Springer-Verlag, Berlin, 1982)

This book contains tables of the properties of water and steam from 0 to

800 °C and from 0 to 1000 bar which have been calculated using a set of

equations accepted by the members of the Sixth International Conference on the Properties of Steam in 1967. Properties which are tabulated include the

pressure, specific volume, density, specific enthalpy, specific heat of

evaporation, specific entropy, specific isobaric heat capacity, dynamic

viscosity, thermal conductivity, the Prandtl number, the ion-product of water,

the dielectric constant, the isentropic exponent, the surface tension and Laplace

coefficient. Also see items [43] and [70].

**********

[135] Serjeant, E. P. and Dempsey, B. Ionization Constants of Organic Acids in Aqueous Solution

(Pergamon Press, New York, 1979)

This critical compilation of pK values is a supplement to an earlier

monograph by Kqrtum, Vogel , and Andrussow (see item [73]). This volume

extends the literature coverage to the end of 1970 and summarizes data for

some 4500 acids. In conjunction with the Kortum compilation, the total

number of acids covered is 5500. Each entry includes the name of the

substance, its molecular formula, pK value; the temperature, method of measurement, an assessment of reliability, and references to the literature.

**********

[136] Silcock, H. (editor) Solubilities of Inorganic and Organic Compounds (in

three volumes) (Pergamon Press, Oxford, 1979)

Translated from the Russian: "Spravochnik po rastvorimosti

(Izdatel 1 stvo Nauka, Moscow, 1969)

This three volume series is an extension of the work of Stephen and Stephen

(see item [142]). These volumes cover ternary and mul ticomponent systems of

inorganic substances.

**********

[137] Sillen, L. G. and Martell, A. E. Stability Constants of Metal Ion Complexes, Section I: Inorganic Ligands,

Section II: Organic Ligands (Second edition)

(Special Publication No. 17, The Chemical Society, London, 1964

and Supplement No. 1, Special Publication No. 25, 1971)

With the publication of this second edition of Stability Constants, the

Chemical Society combined two previously separate volumes into one, two-part

volume (745 pp.), the first covering constants of inorganic ligands, the

second, organic ligands. Both sections include all data published up to the

end of 1960 and some from 1961 to 1963; the scope of the inorganic section has

been extended to cover redox equilibria and the extraction of inorganic
58

ligands into nonaqueous solvents. The data are organized into separate

tables, each table summarizing the data for the association of one particular

ligand with all the metallic ions which have been studied in conjunction with

it. Method of measurement, composition, and temperature of the media to which

the data refer, are given for each ligand-metal pair. Acid dissociation

constants of the ligands are recorded by including the hydrogen ion as one of

the cations with which the ligands associate. Redox equilibria are represented

by including the electron as a ligand, and hydrolysis of metallic ions is

described by regarding the hydroxyl ion as one of the ligands.

The arrangement of material is now more uniform than in the two parts of the

first edition, but there remain minor differences of presentation between the

inorganic and the organic section. In the inorganic table, 80 ligands are ordered according to group in the periodic system; metal ions are arranged

within each inorganic ligand table, in the same order. In the organic section,

the ligands (1028) are in order of their empirical formulae, and the metallic

ions in the alphabetical order of their international symbols. Methods of

measurement are given, with 42 separate methods alphabetized and coded in the

introduction; the medium is usually aqueous. Equilibrium constants are given

in both tables. The organic section includes consecutive or stepwise constants,

K, whenever possible, and cumulative or gross constants, (3, if they are the

only quantities determined, or if the sequence of stepwise constants is

incomplete. The inorganic table includes equilibrium constants for consecutive

and cumulative reactions, solubility constants, acid constants and base

constants. Certain special constants are also given; e.g. K - equilibria

involving a gas. 'Both tables give enthalpy and entropy changes, and symbols

relating to the references which are listed at the end of each table. Each of

the metals, inorganic ligands and organic ligands are indexed alphabetically,

with appropriate table number, at the end of the book.

The first edition was authored by J. Bjerrum, G. Schwarzenbach , and L. G. Si 11 en and was published in two parts by the Chemical Society of London: (1)

"Organic Ligands," Special Publication No. 6 (1957) and "Inorganic Ligands,"

Special Publication No. 7 (1958).

The supplement to the second edition of "Stability Constants of Metal-Ion

Complexes" is a review of pertinent literature published between the

completion of the 1964 Tables and the end of 1968, including also some data

published before the completion of the 1964 Tables, but omitted from them. In

the organic part, a change of policy has been initiated; rather than being

omitted, results seeming incomplete or of dubious validity are now included in

the tables, with critical comments. The section "How to Use the Tables" has

been brought up-to-date; a few methods have been added. Limits of error are

now sometimes given. A new feature in the organic section is a Functional

Group Index, covering also the 1964 Tables, and a table of 34 macromolecular

organic ligands, including albumin, DNA, RNA, and insulin. Also see item [89]

for the continuation of these compilations by Martell and Smith.

**********

[138] Skinner, H. A. (editor)

MTP International Review of Science - Volume 10

Thermochemistry and Thermodynamics

(Butterworths , London, 1972)
59

Although this book contains few tables of thermodynamic data, it does contain

several chapters of interest. These chapters are:

Author(s) Chapter

I. Wadso Biochemical Thermochemistry

R. F. Jameson Thermodynamics of Metal-Complex Formation

G. Pilcher Thermochemistry of Chemical Compounds

K. P. Mishchenko Thermodynamics of Electrolyte Solutions

B. J. Zwolinski and J. Chao Critically Evaluated Tables of

Thermodynamic Data

The last article provides a very useful guide to much of the evaluated

thermodynamic data that are not covered in this bibliography.

**********

[139] Smi th-Magowan, D. and Goldberg, R. N. A Bibliography of Sources of

Experimental Data Leading to Thermal Properties of Binary Aqueous

Electrolyte Solutions (NBS Special Publication 537, U.S. Government

Printing Office, Washington, D.C., 1979)

This is a bibliography of sources of experimental data that can be used to

calculate either relative apparent molar enthalpies or apparent molar heat

capacities of aqueous electrolyte solutions. The compounds are arranged

according to the standard thermochemical order of arrangement. There are approximately 300 references to the source literature.

**********

[140] Sober, H. A. (editor)

Handbook of Biochemistry-Selected Data for Molecular Biology

(The Chemical Rubber Co., Cleveland, Ohio, 1968)

This compendium contains the following twenty-three tables of thermochemical

data. This Handbook appeared in revised form in 1976 (see item [34]).'

Author(s) or Source Table

From "The Chemistry of the Amino Acids Coefficients of Solubility Equations

and Proteins," C.L.A. Schmidt (editor) of Certain Amino Acids in Water

Charles C. Thomas Co., Springfield, IL (Section B, page B-3)

Solubility data for 34 amino acids are fitted to equations giving the

solubility as a function of temperature.
60

J. 0. Hutchens Heat Capacities, Absolute Entropies

and Entropies of Formation of Amino

Acids and Related Compounds

(Section B, page B-5)

C°, S°, and A

f

S° at 25 °C are tabulated for 28 amino acids, 3 peptides,

^proteins, and 3 related substances.

J. 0. Hutchens and E. P. K. Hade, Jr. Solubilites of Amino Acids in Water

at Various Temperatures

(Section B, page B-10)

The solubilities of 18 amino acids are tabulated at four different temperatures

from 1 to 40 °C.

J. 0. Hutchens Heats of Combustion, Enthalpy and

Free Energy of Formation of Amino

Acids and Related Compounds

(Section B, page B-7)

Enthalpies of combustion and formation and Gibbs energies of formation

at 25 °C are tabulated for 45 amino acids and related compounds.

J. 0. Hutchens

The heats of solution for 37 amino acids at

J. 0. Hutchens

Gibbs energies of solution and formation at

Heats of Solution of Amino Acids in

Aqueous Solution at 25 °C

(Section B, page B-ll)

25 °C are tabulated.

Free Energies of Solution and Standard

Free Energies of Formation of Amino

Acids in Aqueous Solution at 25 °C

(Section B, page B~13)

25 °C are given for 18 amino acids.

J. 0. Hutchens Activities of Amino Acids and

Peptides at 25 °C

(Section B, page B-14)

Molar activity coefficients at 25 °C are tabulated as a function of molality

for 14 amino acids.
61

From K. S. Markley, "Fatty Acids. Solubility of Fatty Acids in Water

Part I," second edition, (Section E, page E-13)

Interscience , New York (I960)

The solubilities of 13 fatty acids in water at five temperatures from 0 to

60 °C are tabulated.

From K. S. Markley, "Fatty Acids.

Part I," second edition,

Interscience, New York (I960)

The approximate solubilities of water in

various temperatures is given.

Approximate Solubilities of Water

in Saturated Fatty Acids at Various

Temperatures

(Section E, page E-13)

thirteen saturated fatty acids at

From K. S. Markley, "Fatty Acids. Solubility of Simple Saturated

Part I," second edition, Triglycerides

Interscience, New York (I960) (Section E, page E-14)

Tabulated are solubilities of five saturated triglycerides in various non- aqueous solvents and at a variety of temperatures.

From K. S. Markley, "Fatty Acids. Solubilities of Mixed Triacid

Part I," second edition, Triglycerides at 25 °C

Interscience, New York (1960) (Section E, page E-15)

Solubilities of four mixed triacid triglycerides in four non-aqueous

solvents are tabulated.

P. A. Loach Oxidation-Reduction Potentials,

Absorbance Bands and Molar

Absorbance of Compounds in

Biochemical Studies

(Section J, page J-27)

Oxidation-reduction potentials at ambient temperatures are tabulated for

an assortment of 253 couples frequently encountered in biochemical studies

with appropriate references.

Oxidation-Reduction Potentials of

Hemoproteins and Metall oporphyri ns (Section J, page J-35)

R. W. Henderson and T. C. Morton
62

Oxidation-reduction potentials are tabulated for 241 hemoproteins and

metal loporphyrins at various temperatures.

R. M. Izatt and J. J. Christensen Heats of Proton Ionization and

Related Thermodynamic Quantities

(Section J, page J-49)

This section is an extensive tabulation of enthalpy and entropy changes and

pK values for organic and biochemical systems with 323 references to the

1 i terature.

G. C. Krescheck Calorimetric AH Values Accompanying

Conformational Changes of Macromolecules in Solution

(Section J, page J-140)

Tabulated are AH values accompanying the conformation changes of 25

macromol ecul ar systems.

W. P. Jencks Free Energies of Hydrolysis and

Decarboxylation

(Section J, page J-144)

A discussion is given of standard states appropriate to biochemical thermodynamics. Tabulated are Gibbs energies of hydrolysis of esters of acetic

acid and related compounds, of thiol esters, amides, phosphates, and of

glycolysis (and of decarboxylation).

W. P. Jencks and J. Regenstein Ionization Constants of Acids

and Bases

(Section J, page J-151)

Given is an extensive tabulation of pK values for ionization of several

hundred acids and bases with 116 references to the literature.

R. G. Bates Measurement of pH

(Section J, page J-190)

and

Buffer Solutions

(Section J, page J-195)

pH values have been assigned to several important buffer systems.
63

N. F. Good, G. D. Winget, W. Winter, Properties of Some New

T. N. Connolly, S. Izawa, and R. M. M. Singh, Buffers for Biochemistry

5, 472 (1966) Biological Research

(Section J, page J-195)

Tabulated are pK values with temperature coefficients and metal-buffer

binding constants for several buffers useful for biological research.

**********

[141] Stary, J. and Preiser, H. Equilibrium Constants of Liquid-Liquid Distribution Reactions.

Part IV: Chelating Extractants

(Pergamon Press, Oxford and New York, 1978)

This 228 page volume summarizes equilibrium constants for liquid-liquid

distribution equilibrium constants up to the end of 1972. Each table includes

the extractant and its extractable metal complexes, and the distribution

equilibrium constants and extraction constants. The aqueous phase metal

complex formation constants are not included and the reader is referred to

items and in this bibliography for sources of this type of data. References

to the primary literature are included.

**********

[142] Stephen, H. and Stephen, T. (editors)

Solubilities of Inorganic and Organic Compounds (in five volumes)

(Pergamon Press, Oxford, 1963 and 1964)

This series, which has been translated from the Russian, consists of five

volumes (about 5500 pages) and is a selection from the literature of data on the solubilities of elements, inorganic compounds, and organic compounds in

binary, ternary, and multi-component systems. References are given to sources

of data in the literature. The data are unevaluated and refer to temperatures

for which experimental data exist. Also see the three volume extension edited

by Si 1 cock [136].

**********

[143] Stull, D. R. Vapor Pressure of Pure Substances. Organic Compounds

Industrial and Engineering Chemistry 39, 517 (1947)

and

Vapor Pressure of Pure Substances. Inorganic Compounds

Industrial and Engineering Chemistry 39, 540 (1947)

These articles contain evaluated vapor pressure data on over 1200 organic and

300 inorganic compounds. Given for each compound are those temperatures at

which the compounds has a given vapor pressure.
64

[144] Stull, D.R. and Prophet, H. (project directors) JANAF Thermochemical

Tables (second edition) NSRDS-NBS 37

(U.S. Government Printing Office, Washington, D.C., 1971)

This extensive volume contains values of C°, S°, (G°-H° (298.15 K))/T, H°-H°

(298.15 K), A

f

H°, A

f

G°, and log 10 K, where R is the equilibrium constant for

the reaction of forming the given compound from its elements. The temperature

range for which the data are given is 0 K to the highest temperature for which

the data exist, the temperature intervals being in steps of 100 K. For each

compound given there is a concise and detailed discussion of the data upon

which the accompanying table is based and references to the source literature.

The volume contains data for a 1200 elements and compounds in the crystalline,

liquid and gaseous states. It should be noted that the reference state for

phosphorus is the red form. While most of the substances are inorganic, there

is also some coverage of organic materials up to five carbon atoms. Three

supplements to the JANAF tables have appeared in the Journal of Physical and

Chemical Reference Data for a total of 1322 tabulations involving 35 elements

and their compounds. Also see [42]. The supplements are:

Author(s) Reference

M.W. Chase, Jr. , J.L. Curnutt, A.T. Hu Journal of Physical and Chemical

H. Prophet, A.N. Syverud and L.C. Walker Reference Data 3, 311 (1974).

M.W.Chase, Jr. , J.L. Curnutt, H. Prophet Ibid 4, 1 (1975)

R.A. McDonald and A.N. Syverud

M.W. Chase, Jr., J.L. Curnutt, Ibid 7, 793 (1978)

R.A. McDonald and A.N. Syverud

M.W. Chase, Jr., J.L. Curnutt, Ibid 11, 695 (1982)

J.R. Downey, Jr., R.A. McDonald,

A.N. Syverud, and E.A. Valenzuela

**********

[145] Stull, D. R. , Westrum, E. F. and Sinke, G. C. The Chemical Thermodynamics of Organic Compounds

(John Wiley and Sons, New York, 1969)

This monograph is divided into three parts. The first part gives the

theoretical basis and principles of thermodynamics and thermochemistry, some experimental and computational methods used, and some applications to

industrial problems. The second part gives thermal and thermochemical

properties in the ideal gas state from 298.15 to 1000 K. In this section, the

sources of data are listed and discussed and standardized tables are presented

for 918 organic compounds. Values of C°, S°,-(G - H°(298.15 K))/T, H°-H°(298.15

K), A

f H°, Af

G°, and log K are given enthalpy of formation, entropy, and

consistent values of A

f

G°^and log K of organic compounds at 298.15 K. In excess of 4000 compounds are listed? including a few inorganic compounds. In one chapter there is a brief discussion of methods of estimating thermodynamic

quantities.
65

[146] Tatevskii, V. M. , Benderskii, V. A. and Yarovoi , S. S. Rules and Methods for Calculating the Physico-Chemical Properties of

Paraffinic Hydrocarbons

(Pergamon Press, New York and Oxford, 1961)

Translated from the Russian:

"Zakonomernosti i metody rascheta f izikokhimicheskikh svoisty

parafionvykh ugl evodorodov"

(Gostoptekhi zdat , Moscow, 1960)

This monograph is a summary and a consolidation of the results of some years

of work by Tatevskii and others, extending and elaborating some procedures

introduced by Rossini and others. Properties calculated include: molar

volume, molar refraction, vapor pressure, enthalpy of formation from atoms or elements, Gibbs energy of formation, and enthalpy of combustion. Three

different methods are used. Tables of constants and illustrations of the

accuracy cf the methods are given.

**********

[147] Timmermans, J. Physico-Chemical Constants of Pure Organic Compounds (in two volumes)

(Elsevier, Amsterdam, 1950 and 1965)

These two volumes contain tables of physical data for pure organic compounds.

The arrangement of the data is by compound. Properties tabulated include vapor

pressure, boiling point, triple point, viscosity, specific heat, critical

constants, density, compressibility, refractive index, enthalpy of vaporization,

and dielectric constant.

**********

[148] Timmermans, J. The Physico-Chemical Constants of Binary Systems in Concentrated Solutions

(in four volumes)

(John Wiley and Sons, Interscience Publishers, New York, 1959)

These volumes contain extensive tabulations of physical data relevant to

concentrated solutions of binary systems, both organic and inorganic. The

properties that are tabulated include dielectric constant, viscosity,,

equivalent conductivity, surface tension, diffusion and thermal diffusion

coefficients, vapor pressure, specific heat, electrochemical data, enthalpy of

combustion, enthalpy of dilution and solution, transition enthalpies, and

other properties. These books contain extensive tabulations of data pertinent

to water and electrolyte solutions. The data are well organized and there is

a general compound index as well as references to the original data sources. The literature coverage is through the year 1957.

**********

[149] Wagman, D. D. , Evans, W. H. , Parker, V. B. , Schumm, R. H.

,

Halow, I., Bailey, S. M. , Churney, K. L. , and Nuttall , R. L. The NBS Tables of Chemical Thermodynamic Properties

Journal of Physical and Chemical Reference Data 11, Supplement No. 2

(1982)
66

This 392 page volume is the most recent comprehensive compilation in English

of critically evaluated thermochemical data at 298.15 K for inorganic

substances and for organic substances containing one or two carbon atoms. The

values are in joules and refer to a standard state of 0.1 MPa. The coverage

is approximately 14,000 substances. The properties tabulated are AfH° (0),

A.G° (298.15 K), A

f

H° (298.15 K) , H° (298.15 K) - H° (0), S° (298.15 K) , and

C* (298.15 K). The data from original sources have been critically evaluated

aRd "best" values selected for the properties tabulated, maintaining internal

consistency by the relationships AfG° (298.15 K) = Af H° (298.15 K) - TAfS°

(298.15 K), and A

f

H° (298.15 K) - A

f

H° (0) = I (H° (£98.15 K) - H° (0))T This

volume contains an excellent discussion dealing with the construction, use,

and history of thermochemical tables. This volume supersedes NBS Circular 500

(item [131]). Also see item [93].

The NBS Tables of Chemical Thermodynamic Properties is a new edition of NBS

Technical Note 270, "Selected Valued of Chemical Thermodynamic Properties."

The values in the Technical Notes were in calories and refer to a standard

state of one atmosphere. The 1982 NBS Tables also contain some changes,

additions, and corrections to the Technical Note. Although superseded by the

1982 NBS Tables, the NBS Technical Note 270 is still relevant to

thermochemists since many papers in the literature from the years 1965 to 1982

made use of the values tabulated in the Technical Note. The Technical Note

was issued in eight parts from 1965 to 1981 and was published by the U.S.

Government Printing Office, Washington, D.C. The parts of the Technical Note,

the years of publication and their contents are:

Technical Note Authors Year of Publication

270-1 Wagman, D. D. , Evans, W. H. , 1965

Parker, V. B. , Halow, I., Bailey, S. M.

,

and Schumm, R. H.

Tables for the elements 0, H, He, Ne, Ar, Kr, Xe, Rn, F, CI, Br, I, At, S,

Se, Te, Po, N, P, As, Sb, Bi , and C.

270-2 Wagman, D. D. , Evans, W. H. , Halow, I., 1966

Parker, V. B. , Bailey, S. M. , and

Schumm, R. H.

Tables for the elements Si, Ge, Sn, Pb, B, Al , Ga, In, and Tl.

270-3 Wagman, D. D. , Evans, W. H. , Parker, V. B. , 1968

Halow, I., Bailey, S. M. , and Schumm, R. H.

This part combined parts 1 and 2 into one volume and superseded them. Tables

for Zn and Cd were also added.
67

270-4 Wagman, D. D. , Evans, W. H. , Parker, V. B. 1969

Halow, I., Bailey, S. M. , and Schumm, R. H.

Tables for the elements Hg, Cu, Ag, Au, Ni , Co, Fe, Pd, Rh, Ru, Pt, Ir, 0s,

Mn, Te, Re, Cr, Mo, and W.

270-5 Wagman, D. D. , Evans, W. H. , Parker, V. B. 1971

Halow, I., Bailey, S. M. , Schumm, R. H. , and

Churney, K. L.

Tables for the elements V, Nb, Ta, Ti , Zr, Hf, Sc, and Y.

270-6 Parker, V. B. , Wagman, D. D. , and Evans, W. H. 1971

Tables for the elements Be, Mg, Ca, Sr, Ba, and Ra.

270-7 Schumm, R. H. , Wagman, D. D. , Bailey, S. M. , 1973

Evans, W. H. , and Parker, V. B.

Tables for the elements Lu, Yb, Tm, Er, Ho, Dy, Tb, Gd, Eu, Sm, Pm, Nd,

Pr, Ce, and La.

270-8 Wagman, D. D. , Evans, W. H. , Parker, V. B. , 1981

Schumm, R. H. , and Nuttall, R. L.

Tables for the elements U, Pa, Th, Ac, Li, Na, K, Rb, Cs, and Fr. Additions

and corrections to the series are given in an appendix.

**********

[150] Wagman, D. D. , Schumm, R. H. and Parker, V. B. A Computer-Assisted Evaluation of the Thermochemical Data of the

Compounds of Thorium

(NBSIR 77-1300, National Bureau of Standards, Washington, D.C., 1977)

This report presents a computer-assisted evaluation of the thermochemical

properties of compounds of thorium. Values of A

f

H° , A

fG°, S° are tabulated at

298.15 K for the compounds and aqueous species of thorium. There is also a "reaction catalog" which gives values of AG°, AH°, and S° for individual

processes or substances and upon which the tabulated formation properties are

based. This report also contains thermal functions and includes references to

the primary literature.
68

[151] Washburn, E. W. (editor-in-chief)

International Critical Tables of Numerical Data, Physics, Chemistry,

and Technology

(McGraw-Hill Book Company, New York, 1930)

At the time of publication this seven volume series was the most comprehensive

source of thermochemical and other data in existence. Essentially all

equilibrium and transport properties and classes of materials were covered.

The Critical Tables, although now superseded by modern compilations and

evaluations of data, still remain useful for references to the older

literature. The tables are arranged according to property with groups of

tables being arranged according to discipline. One volume of this series is an index of the materials whose properties are dealt with.

**********

[152] Wichterle, I., Linek, J. and Hala, E. Vapor-Liquid Equilibrium Data Bibliography (and two Supplements)

(Elsevier, Amsterdam, 1973, 1976, and 1979)

These three books contain references to the source literature on vaporliquid equilibrium data for inorganic and organic mixtures. The first

volume covers the literature through 1972, the second through 1975, and the

third through 1978. The compounds are arranged alphabetically except for

the carbon containing compounds. The preparation of the two Supplements has

been computerized to make updating more efficient. The series contains 6700

references to the source literature.

**********

[153] Wilhelm, E. Battino, R. and Wilcock, R. J. Chemical Reviews 77, 219 (1977)

This paper is a critical review of the low-pressure solubility of 57 gases in

liquid water and in heavy water. The solubility of each gas is given in terms

of the coefficients of an equation which can be used to calculate the

solubility at a given temperature. Also given are AG°, AH° , AS° , and AC°

values for the solution process at various temperatures and at one atmosphere

partial pressure of the gas. The authors give extensive details concerning

their correlations and include references to the literature.

**********

[154] Wilhelm, E. and Battino, R. Thermodynamic Functions of the Solubilities of Gases in Liquids at 25 °C

Chemical Reviews 73, 1 (1973)

This review article contains selected values for the solubility, entropy, and

enthalpy changes in solution for 16 gases in 39 non-aqueous solvents. Also

given are the coefficients of polynomial expressions for the Gibbs energy of

solution for a gas in a given solvent as a function of temperature. See also

item [8].
69

[155] Wilhoit, R. C. and Zwolinski, B. J. Handbook on Vapor Pressures and Heats of Vaporization of Hydrocarbons

and Related Compounds (API 44 - TRC)

(Thermodynamics Research Center, Texas A and M Research Foundation,

College Station, Texas, 1971)

This handbook gives data for 680 hydrocarbons, 95 carbon-sulfur compounds, and

water from 0 to 150 °C. It is indexed by compound name, and by boiling point.

**********

[156] Wilhoit, R. C. and Zwolinski, B. J. Physical and Thermodynamic Properties of Aliphatic Alcohols

Journal of Physical and Chemical Reference Data, Volume 2,

Supplement No. 1, 1973

This review contains critically evaluated values of the vapor pressure, heat

capacity, enthalpies of transition, entropies, thermodynamic functions for the

real and ideal gases, densities, refractive indexes, and critical properties

for 722 alcohols in the carbon range C x to C 50 . This comprehensive review is

420 pages long and lists 2036 references.

**********

[157] Wisniak, J. Phase Diagrams, A Literature Source Book (Parts A and B)

(Elsevier, New York, 1981)

These two volumes contain extensive references (circa 18,000) to phase

diagrams in the literature. The systems covered include organic and inorganic

materials and aqueous systems. The coverage extends over the entire periodic

chart. The systems are arranged in order of increasing carbon and hydrogen

with the remaining elements in alphabetical order.

**********

[158] Wisniak, J. and Tamir, A. Mixing and Excess Thermodynamic Properties: A Literature Source Book

(Elsevier, Amsterdam, 1978)

This book contains approximately 6000 references to excess mixing property

data for mixtures of all types, including electrolyte, non-electrolyte, and

metallurgical systems. The appropriate references to the literature are given

for each mixture. The coverage of materials encompasses the entire periodic

chart and also includes ternary, quaternary, and multi-component mixtures.

**********

[159] Wu, Y. C. and Hamer, W. J. Electrochemical Data. Part XIV. Osmotic Coefficients and Mean Activity

Coefficient of a Series of Uni-Bivalent and Bi-Univalent Electrolytes in

Aqueous Solutions at 25 °C. Part XVI. Osmotic Coefficients and Mean

Activity Coefficients of a Number of Uni-Trivalent and Tri-Uni valent

Electrolytes in Aqueous Solution at 25 °C

(NBSIR No. 10052 and 10088, National Bureau of Standards, 1969)
70

These reports give values for the osmotic and mean ionic activity coefficients

of uni-bivalent , bi-valent, uni-trivalent, and tri-univalent electrolytes in

aqueous solution at 25 °C. In each case, the values tabulated are those calculated by fitting the literature data to the equation for the excess Gibbs energy,

and represents a good fit to the experimental data. Literature references are included. Also see item [48].

**********

[160] Yatsimirskii (or Jazimi rski ) , K. B. Thermochemie von Komplexverbidungen

(Akademie-Verlag, Berlin, 1956)

translated by Georg Crull from the Russian

"Thermochimia Complexnik Coedinenie"

(Akad. Nauk. CCCP, Moscow, 1951)

This monograph contains correlations of thermochemical data of complex com- pounds in terms of gas, crystal, and solution models emphasizing ionic radii.

More than 1400 substances are considered. In summary tables, 52 metal

cations, 33 neutral ligands, and 25 anions have enthalpies of formation

listed, usually for gaseous and aqueous state. The compounds formed from

these ions and ligands are listed usually with the enthalpy of formation of

the crystal, and for many of them enthalpies of solution at infinite dilution

are given. The chapters discuss and give tables and correlations of hydration

enthalpies of cations, anions and some amine salts, ion entropies in solution,

enthalpies of formation and solution, energies of gas and crystal ions,

binding energies of H 2 0, NH 3 and other molecules to central metal ions in

gaseous complex ions and similar binding energies.

**********

[161] Yatsimirskii, K. B. , and Vasil'ev, V. P. Instability Constants of Complex Compounds

(Consultants Bureau, New York, 1966 and Pergamon Press, New York, 1960)

This volume contains an extensive tabulation of equilibrium data (K and -log K)

and enthalpies of formation for processes involving the more common ions and

ligands in aqueous solution. Specified are the temperature, ionic strength,

and method of measurement with reference(s) to the appropriate literature.

The tables contain instability constants for 138 predominantly inorganic

compl exes. **********

[162] Kerr, J. A. Strengths of Chemical Bonds

in CRC Handbook of Chemistry and Physics, 64th Edition, 1983-1984

(CRC Press, Inc., Boca Raton, Florida, 1983)

This 20 page compilation (pages F-176 to F-195 in the "Handbook of Chemistry

and Physics") contains values of bond strength in diatomic and polyatomic

molecules, enthalpies of formation of gaseous atoms from the elements in their

standard states, and enthalpies of formation of free radicals. The data refer

to 298.15 K. The coverage of bond types is extensive and there are references

to the source literature. Also see item [92].
71

All ~T" I I /"\ r-v AUTHOR INDEX

Ackermann, R. J.

i nc 10b Chapman, T. W. 16

Ackermann, T.

1 r 15 Chariot, G. 17

Aikens, D. A. 94 Chase, M. W. , Jr. 144

Hit I _ 1 • • II \i Akhachinski j , V. v. 106 Chi oti , P. 106

Alberty, R. A.

T1 Christensen, J. J. 18,19,20,60,140

Ambrose, D. 90 Churney, K. L. 149

Anderson, H. L. 61 Clark, w. M. 21

Andrussow, K.

T n 73 Clarke, E. C. W. 22

A T Ansara, I.

t r\ c 106 Clever, H. L. 8,71

Arbuckle, R.

A 1 41 Cobble, J. W. 5 Armstrong, G. T. 2 Coetzee, J. T.

O A 24

Arnett, E. M. 24 Cohen, P. 0. 35

Arnett, R. L. 130 Cohn, E. J. 25

Asncroft, S. J. 3 Connolly, T. N. 140

Atkinson, G. 45 Conway, B. E. 26

Atkinson, M. R.

O C 35 Cordfunke, E. H. P. 106

Auer, W.

-7/- / D Counsel 1 , J. F. 90

Covington, A. K. 27

Baehr, H. D. 76 Cox, J. D. 28,90 , I 15

Baes , C. F. , Jr. 4 Crabtree, B. 63

Bailey, S. M. 149 Criss, C. M. 5 O • T Barin, I. 5 Cruickshank, F. R. 11

Barner, H. E. 5 Curnutt, J. L. 144

Barnes, D. S. 115

Bates, R. G. b ,94 ,140 r\ I ft _ t D Ans, J.

"7 /T 76

Battmo, R.

"7 O "71 ICO 1C/1 7 ,8,71 ,153 ,154 Datta, S. P. 83

Beckett, C. W. ion loO Davies, C. W. 45

Beezer, A. E. 9 Dewane, H. J.

/I c 46

Beggerow, G. 76 Delima, M. C. P. 121

Benderskii, V. A. 1 A C 14b Delnen, I.

r

- 71 54

Benson, S. W. in ii 1U ,11 Dempsey, B. 135

Bergman, G. A. ao no 42 ,93 Dench, W. A. 90

Bichowsky, F. R. 12 Domal ski , E. S. 2 ,29 ,30 ,31

Birkett, J. D. 129 Dorsey, N. E. 32

Bjerrum, J.

TOT 137 Downey, J. R. , Jr.1 /I 71 144

Bondi , A.

1 O 13 Dunajska, K. 86

Boubnk, T.

1 71 71 71 14 ,44 Dunn, D. B.

0 ^ 34

Bowers, V. A. 94 Dytnond, J. H. 33

Bratzler, K. 76

Brewer, L. 79 Eagland, D. 37

Brown, G. W. 35 Eatough, D. J.

TO IO 18 ,19

Brown, H. D.

t r~ 15 Ebert, J. P. ion 13U

Brown, R. M. 130 Edsal 1 , J. T. 2b

Burhorn, F. 76 Evans, W. H. OO Ol ITIO. 30 ,31 ,131 ,149

Burton, K. 75,83

Busey, R. H. 121 Fasman, G. D. 34

Bysshe, S. E. 129 Fisher, J. R. TOT 127

Florkin, M. 0 c 00

Cabib, E. 35 Flowers, G. C. 52

Cardini , C. E. 35 Fox. D. 36

Carol i, S 96 Franck, E. U. 88

Chao, J. 138 Frankiss, S. G. 90
72

Franks, F. 37,63 Hemingway, B. S. 127

Fredenslund , A. 38 Henderson, R. W. 140

Freeman, R. D. 39 Hepler, L. G. 24,53,54,108

Freiser, H. 141 Herri ngton, E. F. G. 90

Fried, V. 14 Hicks, C. P. 90

Friedman, H. L. 24,37 Hill, J. 0. 54

Frier, R. K. 40 Hill, P. G. 70

Fuger, J. 106 Hinz, H. J. 63

Furukawa, G. T. 2 Hirata, M. 55

Hopkins , H. P. , Jr. 53

Gallagher, J. S. 43 Home, R. A. 98

Galus, Z. 71 Horsley, L. H. 56

Garvin, D. 112 Horvath, A. L. 57,58,71

Gedansky, L. M. 54 Hu, A. T. 144

George, P. 120 Hutchens, J. 0. 140

Gerrard, W. 71

Gibbons, J. J. 121,127 Ingraham, L. L. 59

Gill , S. J. 63 Iseard, B. S. 115

Glew, D. N. 22 Izatt, R. M. 18,19,20,60,140

Glushko, V. P. 42,93 Izawa, S. 140

Gmehling, J. 38

Goldberg, R. N

.

41,54,104,139 Jaffe, I. 131

Golden, D. M. 11,92 Jameson, R. F. 138

Good, N. E. 140 Janz, G. J. 61,62

Grain, C. F. 129 Jazimirski, K. B. 160,161

Green, J. H. b. Jencks, W. P. 140

Grzybowski , A. K. 83 Jobe, T. L. , Jr. 31,109

Guggenheim, E. A. 50 Jones, M. N. 63

Guminski , C. 71 Jordon, T. E. 64

Gurvich, L. V. 42,93 Joshi , R. M. 65

Haar, L. 43 Kaimakov, E. A. 66

Haas, J. L. , Jr. 127 Karapet 'yants , M. L. 67

Habenschuss, A. 124 Karpet 'yants , M. Kh. 67

Hade, E. P. K. , Jr. 140 Kaufmann, D. W. 68

Hagopian, J. H. 129 Kazavchinski i , Ya. Z. 69

Hala, E. 14,44,152 Keenan, H. J. 70

Hall , F. M. 54 Kell, G. S. 37,43

Hall , R. H. 34 Kerr, J. A. 162

Halow, I. 149 Kertes, A. S. 71,87

Ham, G. E. 65 Kessel 'man , P. M. 69

Hamer, W. J. 45 ,46 ,47 ,48,159 Keyes, F. G. 70

Hansen, L. D. 20 Khachkuruzov, G, A. 42

Harned, H. S. 45,49,50 Khodakovsky, I. L. 103

Harris, J. C. 129 Kientz, H. 76

Haugen, G. R. 11 Kil patrick, J. E. 130

Hausen, H. 76 Kim, J. J. 121

Hawkins, D. T. 51 King, E. J. 50

Hayduk, W. 71 Kirgintsev, A. N. 72

Hayes, M. J. 129 Kirillin, V. A. 69

Head, A. J. 90,115 Kirkham, D. H. 52

Hearing, E. D. 30 Kirkwood, J. G. 25

Hel geson , H. "C 5,52 Knacke, 0. 5 Hellwege, K.-H. 76 Knobler, C. M. 90

Kolesov, V. P. 93
73

Kornberg, H. L.

"7 r* 75 Mesmer, R. E. 4

Kortum, 6. 73 Milazzo, G. 96

Kragten, J. 74 Miller, D. G. 97

Krebs, H. A. 75 Mi Hero, F. J. 98,99,123

Krescheck, G. C. 63 , 140 Mil 1 s , R. 50

Knshnan, C. V. 24 ,37 Mischenko, K. P. 100,138

Kubaschewski , 0.

—j s- r\r\ 76,90 Monti , M. 63

Moore, J. G. 70

Labes, M. M. 36 Mooz, E. D. 34

Lange, E.

A C Morss, L. R. 101

Langerman, N. 34 Mortimer, C. T. 3 Larkin, J. A. 77 Morton, R. K. 35

Larson, J. W.

O A 24 Morton, T. C. 140

Latimer, W. M. 78 Mueller, H. 25

Laughton, P. M. 24

Lavrenteva, V. F.

"772 Nagakama, K. 55

Lawrenson, I. W. 90 Nancollas, G. H. 102

Lax, E.

-7 Clb Naumov, G. B. 103

Leloir, L. F. 35 Neckel , A. 76

Letcher, T. M. 9U Ne 1 kanaki , H

.

76

Levine, S. 131 Nelken, L. H. 129

Lewis, G. N. 79 Neumann, D. B. 109

Leyendekkers , J. V. 80 Newman, J. 16

Li nek, J. ICO 152 Nuttal 1 , R. L. 41 ,104,149

Linke, W. G. 81 Nyvlt, J. 105

Loach, P. A.

1 A A 140

Lobo, V. M. M. 0 Hare, P. A. G. 106

Long, C. 83 O'Neal , H. E. 11

Long, r. A. o4 Oetting, F. L. 106

Losch, Fr.

-7 £/6 Ohe, S. 55 ,107

Lowe, A. G. 63 Olofsson, G. 54 ,108

Lyman, W. J. 129 Oncley, J. L. 25

0no, S. 15

MacKay, D. 85 Owen, B. B. 49

Maczynska, Z. 86

Maczynski , A. 86 Pardee, A. B. 59

Marcus, Y. 87 Parker, V. B. 109,110,111,112,149,150

Markley, K. S. 140 Parsons, R. 113

Marsh, K. N. 90 Pauling, L. 114 • Marshall , W. L. 88 Pedley, J. B. 115 ,116

Martel 1 , A. E. 89,137 Peiper, J. C. 121

Martin, J. F. 90 Perrin, D. D. 117 ,118

Mason, H. 35 Peterson, J. R. 121

Mayorga, G. 121 Pfeil , W. 63

McCullough, H. P. 36 Phillips, R. C. 119,120

McDevit, W. F. 84 Phutela, R. C. 121

McDonald, R. A. 144 Pilcher, G.

nft "I 1 C 1 OO 28 ,115 ,138

McGlashan, M. L. 90 Pimentel , G. C. 130

McKelvey, D. R.

O A 24 Pitzer, K. S. McMeekin, T. L. 91 Polak, J. 44

McMillen, D. F. 92 Poltoratzkii , G. M. 100

Medvedev, V. A. 42,93,106 Popovych, 0. 71

Meites, L. 94 Pourbaix, M. 122

Merrill , A. L. 95 Privalov, P. L. 63

I
74

Prophet, H. 144 Silvester, L. F. 121

Pytkowicz, R. M, 123 Singh, P. P. 54

Singh, R. M. M. 140

Rand, M. H. 1U6 r ' L. o o Sinke, G. C.

i A r 145

Randal 1 , M.

"7 n 79 Skinner, H. A. 138

Rard, J. 124 Skirow, G. 126

Rasmussen, P. do Skrzecz, A. 86

Rechsteiner, C. E., Jr. Smith K. n. 89

Regenstein, J. 1 a n Smith, h. d . 33

Reid, U. b. Smi th-Magowan , D. 139

Reid, R. C.

IOC 125 Sober, H. A. 140

Reilly, C. N. 94 Spedding, F. H. 45 ,124

Reilly, M. L.

o

2 Spencer, P. J. 90

Rhyzhenko, B. N. 103 Staples, B. R. 41 ,104,109

Riley, J. P.

1 o c 126 Stary, J. 141

Ritchie, C. D. 24 o a, i_ ii Stephen, H. 142

Riukin, S. c n 69 Stephen, T. 1 /l o 142

Robertson, R. t. O A 24 Stokes, R. H. PA 1 OO 50 ,128

Robie, R. A. 1 O 7 12/ StU II, U . K. 143 ,144 ,145

Robinson, G. R. , Jr.

i o "7 127 r* . . . — i - ii Surawski , H. 76

Robinson, R. A.

r A too 50 ,128 Swinton, F. L. 90

Rogal ski , M.

n /r 86 Sychev, V. V. 69

Rogers, A. S. 11 Synowietz, C.

~7 /? 76

Rogers, P. S. Z.

1 O 7 12/ Syverud, A. N. 144

Rosenblatt, D. H. ion 1Z9

Rossini, F. D. 12 ,130 ,131 Takahashi , K. 15

Roy, R. M.

1 1

i

121 Tamir, A. ipo 158

Rutman, R. J.

1 O A 120 Tatevski l , V. M.i /i r 146

Rylance, J. 116 Taylor, U. J. c o 63

Rytting, J. H.

r o 60 Taylor, W. J. ion 130

T L> — _ _ o O Thomas, R. G.

1 o n 129

Salomon, M.

"7 1 71 Timmermans, J.

1 A ~7 1 /IO 147 ,148

Sanderson, R. T.

i o o 133 Timrot, D. L. 69

Sarjeant, E. P.

i o r* 135 Todheide, K. 37

Scatchard, G. 25 Tomkins, R. P. T. 62

Schafer, D.

i /i n 140 Travers, J. G. 54

Schaffer, K. 76 Treszczanowicz , T. 86

Scheuerman , R. V. 5 Trushmkova, L. N.

"7 O 72

Schmidt, C. L. A. 140 Tucker, W. A. 129-

Schmidt, E. 134

Schneider, G. M.

o r\ 90 Valenzuela, E. A. 144

Schumm, R. H.

1 / a 1 r~ o 149 ,150 Varshavskaya , N. L. 66

Schwa rzenbach , G. 137 Vasil 'ev, V. P. 161

Scott, R. L. 90 Veitz, I. V. 42

Scow, K. M. 129 Vincent, C. A.

T i 71

Scrosati , B. 71 Vogel , W. 73

Seidel 1 , A. 81 Vorob'ev, A. F. 93

Shaw, R. 11

bhei nd 1 1 n , A. t

.

69 Wadso, I. CO 1 OQ 0 0,1 JO

Sherwood, T. K. 125 Wagman, D. D. 112,131,149,150

Shiu, W. Y. 85 Walker, L. C. 144

Shpi 1' rai n , E. E. 69 Walsh, R. 11

Silcock, H. 136 Washburn, E. W. 151

Sillen, L. G. 137 Watt, B. K. 95

I
75

Weisberger, A. 36

Weishaupt, J. 76

Werner, H. C. 130

Westrum, E. F., Jr. 36,39,106,145

Whitfield, M. 123

Wichterle, I. 44,152

Wienecke, R. 76

Wilcock, R. J. 153

Wilhelm, E. 8,71,153,154

Wilhoit, R. C. 2,15,155,156

Williams, M. D. 130

Williamson, A. G. 90

Winget, G. D. 140

Winter, W. 140

Wisniak, J. 157,158

Wood, R. H. 37

Woolley, E. M. 54

Worsley, I. 6. 54

Wu, Y. C. 47,48,159

Yanir, E. 87

Yarovoi, S. S. 146

Yatsimirski , K. B. 160,161

Young, C. L. 71,90

Yungman, V. S. 42,93

Zordan, T. A.

Zwol inski , B. J.

54

65,138,155,156
76

SUBJECT INDEX

This index gives an indication of thermodynamic properties, physical or

chemical processes, classes of substances, and, in a few cases, individual

substances for which information is to be found herein. It is not practical

to give an exhaustive index to the contents of the individual references.

Hence the absence of a piece of information in the index does not necessarily

mean its absence in the references. This is particularly true with respect to

particular substances, which the reader should assume are not listed except by

chance of title or abstract.

acetic acid esters

hydrolysis

acid constants

see also equilibrium constants

acids, inorganic

dissociation constants

thermodynamics in water (and

nonaqueous solvents)

acids, organic

decarboxylation

dissociation constants

hydrolysis of esters

vapor pressures

acids, strong

actinides

thermodynamic data

activation energies

polymerization

activity coefficients

amino acids

bib! iography

from chromatographic measurements

from diffusion data

inorganic electrolytes

multicomponent electrolyte solutions

non-electrolytes

organic electrolytes

peptides

rare earths

sodium chloride in water

strong electrolytes

uni-polyvalent electrolytes

uni-univalent electrolytes

140

137

53 ,111,117 ,135 ,137,140

100,111

140

20 ,24 ,53 ,73 ,83 ,94 ,135 ,137 ,140

140

64

128

93,106,149

65

25,140

41

90

45

16 ,26,48,49,50,52,104,121 ,128

50,121,123

38,84

26,48,49,104,121,128,129

140

45

68,121

78,79,104,121,128

159

48

adenine nucleotides 119
77

adenosi ne 119

adenosine-5 1 - diphosphate 1,15,120

adenosine-5 1 -triphosphate 1,15,120

adsorption coefficients 129

albumin 26,137

alcohols

application of UNIFAC

Gibbs energy changes

thermodynamic properties

vapor pressures

38

75

156

64

aldehydes

application of UNIFAC

vapor pressures

38

64

alicyclic organic bases

dissociation constants 118

aliphatic organic bases

dissociation constants 118

alkali metal salts

thermodynamics of solutions 100

alkaline earth metal halides

activity and osmotic coefficients 104

al kanes

application of UNIFAC 38

solubilities 85

alkenes and alkynes

solubilities 85

alumina-lime-silica water

thermodynamic properties 127

amides

hydrolysis 140

amines

application of UNIFAC 38

amino acids

activities 140

enthalpies of combustion 140

enthalpies of solution 140

entropies and enthalpies of formation 140

Gibbs energy of formation 140
78

Gibbs energy of formation in solution

Gibbs energy of solution

heat capacities, entropies

ionization thermodynamics

solubil ities

thermodynamics in aqueous solution

ammonia

metabol ism

140

140

140

24,34

91,140

25,37

35

ammonium ions

acid ionization thermodynamics

anil ines

redox potentials

anilinium ions

acid ionization thermodynamics

animal

s

cal orimetry

Antoine equation

aqueous electro \ytes

aromatic organic bases

dissociation constants

azeotropic data

bacteria

cal orimetry

barbituric acids

ionization thermodynamics

base constants

see also equilibrium constants

bases

see also acids

inorganic

organic

thermodynamics in water (and

non-aqueous solvents

bibl iography

thermodynamic data

water

binary (two component) systems

inorganic

organic

physical data

solubilities in

24

21

24

31

44,107

16,24,37 ,100,104,111 ,121

118

56

24

137

94,100,111 ,117,140

94,118,140

53,100,111

138

51

148

148

148

148
79

binding constants

see also equilibrium constants

metal -buffer complexes

biochemical pathways

biosynthesis

Gibbs energy changes

boiling point

estimation

organic compounds

bond energies

buffer solutions

calcium chloride

activity and osmotic coefficients

carbohydrates

isomerization and hydrolysis

carboxylic acids

see acids, .organic

cations

thermodynamics of hydrolysis

eel 1 s

chelating agents

C, H, N, 0, P, S compounds

chromium compounds

thermochemistry

coal-gas desulfurization

cobalt chloride

activity and osmotic coefficients

CODATA (key values for thermodynamics)

colloids

transport properties

combustion energy

complexes, metal -ligand

inorganic ligands

organic ligands

composite materials

140

63,75

35

125

147,155

10,11,92,114,133,162

26 ,83,140

104,121,124

15

4

9,63

141

2,29

54,93,149

109

104

23,112

26

2,28,29,95 ,116

3,18,137

3,18,137

31
80

compressibil ity

aqueous electrolytes 45,123

of seawater 80,126

organic compounds 147

conductance

aqueous electrolytes 26,40,45,46,49,82,128

binary systems 148

non-aqueous electrolytes 62

conformational changes

proteins 63

nucleic acids 63

copper compounds

thermochemistry 54,93,149

creatine

enthalpy of combustion and formation 140

Gibbs energy of formation 140

heat capacity, entropy, entropy of formation 140

creatinine

enthalpy of combustion and formation 140

entropy of formation 140

Gibbs energy of formation 140

heat capacity, entropy 140

critical properties

bibliography 57

estimation 120,125

organic compounds 147

water 37

cycloal kanes

solubilites 85

Debye-Huckel parameters 22,52,79,121,123

density

alcohols 156

aqueous electrolytes 40,45

estimation 129

inorganic electrolytes 16,26,49,52,76

non-aqueous electrolytes 62

organic compounds 147

organic electrolytes 49,76

water 37

deoxyribonucleic acid 60,137

desalination 132

deuterium oxide

physical properties 62

thermodynamic properties of electrolytes 37
81

dielectric constants

aqueous electrolyte solutions

binary systems

non-aqueous electrolytes

organic compounds

solvents

water

diffusion constants

binary systems

estimation

inorganic electrolytes

organic electrolytes

dilution, enthalpy of

dipole moments

dissociation constants

aqueous electrolytes

inorganic acids and bases

1 igands

organic acids, aqueous

organic bases

distil lation

distribution reactions

26

148

62

147

26

37,134

148

129

16,26,45,49,82,97,128

26,49,128

93,100,111,149

26,129

26,45,49

117

137

73,83

118

132

87,141

drugs

calorimetry

dyes and indicators bases

dissociation constants

electrochemical data

binary systems

electrochemical potentials

biological oxidation-reduction reactions

chromium compounds

copper compounds

gold compounds

in non-aqueous electrolyte solutions

in organic solvents

inorganic substances

lanthanum compounds

manganese compounds

mercury compounds

molybdenum compounds

platinum metal compounds

scandium compounds

silver compounds

vanadium, niobium, and tantalum compounds

tungsten compounds

118

26

148

75

54

54

54

62

128

17,39,96,122

54

54

54

54

54

54

54

54

54
82

electrode processes

electrodialysis

electrolytes

aqueous and non-aqueous

critical properties

current aqareness bulletin

data handbook

dilution of

equilibrium constants of

Gibbs energies, enthalpies, heat

capacities, and entropies

heat capacity

in seawater

irreversible thermodynamics

molar volumes

mul ti component systems

non-aqueous

osmotic coefficients

oxidation-reduction potential

sodium chloride

sol ubil ities

thermodynamics of mixing

uni-polyvalent

uni -univalent

viscosity

energy transformations in living matter

energy values of foods

enthalpy

apparent molar

combustion

enthalpies of salts, acids and

bases vs temperature and concentration in

water and organic solvents

estimation

inorganic compounds

organic compounds

partial molar

water

enthalpy change

binding of metal ions to organic ligands

complex formation

conformational change of macromolecules

di 1 ution

26

132

16,26,40,49,52,82,104,121 , 128,138

79,100

57

27

130

93,45,111,149,162

3,18,24,60,73,75,83,94,117,

118,137,140

3,18,24,37 ,60,75,76,93,131 , 137,139,149,162

76,111

80

66,97

98,99

37,50

62

48,128,159

21 ,75,78,137

62,

81 ,140,142

37

159

48,111

50

75

95

49

28,29,116

52 ,100 ,121 ,111 ,139

13,61

42

41

26,79

42,134

89

18,60,100

140

2 ,45,62,76,100,111 ,131 ,139,

148,149
83

formation

formation, estimation

hydration of ions in water

hydrolysis

ionization

mixing electrolyes

multidentate macrocyclic compound

polymerization

protonation of adenosine and

adenine nucleotides

protonation of nucleic acids,

nucleotides and nucleosides

protonation of organic ligands of

sol ution

solution of hydrocarbons,

alcohols, and rare gases in water

solution for non-aqueous

electrolytes

transfer

2,3,4,10,11,12,15,23,28,29,

37 ,41 ,48,54,61 ,67,76 ,78,93,

100,101,103,106,109,110,112,

115,116,127,130,131,133,140,

144,145,149,150,160,161

10,11,125,76,146

37,160

4

20,24,25,53,100,108,111,140,147

37,76

19

65

119

60

92

2,24,45,76,93,100,105,111 , 131,140,148,149,153,160,162

37

62

24

radical

s

entropy 2,10,11,15,41,67,144

actinide compounds 106

alcohols 156

amino acids and related compounds 140

aqueous species 93

chromium compounds 54

copper compounds 54

dissolved acids, salts, bases in 52,100

water and non-aqueous solvents

estimation 10,11,13,61,78

gold compounds 54

hydrocarbons 130

hydrolysis 4

inorganic compounds 5 ,76 ,93 , 109 , 1 10 ,-1 12 , 131 ,149,162

key values 23

lanthanide compounds 101

manganese compounds 54

mercury compounds 54

molybdenum compounds 54

organic compounds 67,76,93,131,145,149,162

platinum metal compounds 54

scandium compounds 54

seawater 80

silver compounds 54

single ion 37

thorium compounds 150

tungsten compounds 54

vanadaium, niobium, and tantalum compound 54

water 37
84

entropy change

binding of metal ions to

organic ligands

complex formation

dilution

formation

hydration of ions in water

ionization

multi dentate macrocyclic

compounds

polymerization

protonation of nucleic acids

nucleotides, and nucleosides

protonation of organic ligands

sol ution

solution of hydrocarbons, alcohols

and rare gases in water

transfer

89

3,18,60

2

54,140

37

24,100,140

19

65

60

89

2,24,100

37

24

enzyme-catalyzed reactions

equilibrium constants

actinide compounds

acid-base

for amines

for amino acids

for distribution reactions

for inorganic complexes

formation

hydrolysis

in seawater

ion-pai ring

metal ion-ligand

multi dentate macrocyclic compounds

of polymerization

proton transfer reactions

protonation of adenosine and adenine

nucleotides

protonation of nucleic acids,

nucleotides, and nucleosides

9,15,75,140

106

50,53,83

89

89

87,141

5 ,39,74,101 ,137,161

43,44,131,145,149

4

80

45,102

18,60,94,137

19

65

94

119

60

esters

Gibbs energies of hydrolysis

estimation, properties (various kinds)

ethanol as solvent

thermodynamic properties of acids,

bases, salts in

140

5 ,10,11 ,13,28,38,56,61 , 78,125,129,145,146,160

100

ethanol -water mixtures

acid dissociation in 94

excess properties 77,90,104,121,123,158
85

expansibil ity

of seawater

extractants

fatty acids

sol ubi 1 i ties

fermentation

Gibbs energy change

food and foodstuff ingredients

composition and energy values

fugacity

water

gases

diffusion constants in water

non-polar, properties estimation

polar, properties estimation

solubility in water

Gibbs energy

biological .systems

estimation

seawater

Gibbs energy change

ammonia metabolism

biol ogical oxidation- reduction

reactions

biosynthesis of saccharides

decarboxylation

dilution

fermentation

formation

formation (estimation)

glycolysis

hydration of ions in water

hydrolysis

ionization

metabolic processes

mixing electrolytes

phosphates hydrolysis

polymerization

solution

solution of gases

solution of hydrocarbons,

alcohols, and rare gases in water

transfer

tricarboxylic acid cycle

urea biosynthesis

80,123,126

87,141

91,140

75

95

37

32

13,125

13,125

32,153

83

61

80

2,3,15,74

35

75,83

35

140

2,100

75

2,3,15,37,43,54,67,75,

78,93,100,101,103,106,109,110,

112,122,127,130,131,76,140,144,

145,149,150,162

10,11,125,76,146

75

37

4,140

24,53,108,135

35,75,83

37

1,35,120

65

2,24,100,140

153

37

24

75

35
86

gl asses

see solids

glucose

partial molar properties 15

gl uosides

hydrolysis 15

glycerol

partial molar properties 15

glycine

partial molar properties 15

glycolysis 75

glycosides

hydrolysis 140

gold compounds

thermochemistry 54,93,149

group contributions 10,11,61,76

half-cell potentials 26,78

halogenated hydrocarbons

solubility in water 58

heat capacity 15,43,144

actinides 106

alcohols 156

amino acids and related compounds 140

binary systems 148

C,H,N,0,P,S compounds 2

dissolved acids, salts, bases in 24,52,76,100,109,139

water and non-aqueous solvents

estimation 10,11,13,61,125,1-29

minerals 127

organic compounds 30

partial molar 79,103

seawater 126

solid wastes and composite materials 29

uni-univalent electrolytes 111

uranium-halogen compounds 110

water 37 ,43,134

heat capacity change

complex formation 18,60

hydration of ions in water 37

ionization 24,53,108

multidentate macrocyclic 19

compounds
87

protonation of nucleic acids 60

nucleotides, and nucleosides

solution of hydrocarbons, 37,153

alcohols, and rare gases in water

heat content

see enthalpy

heat of formation

see enthalpy changes of formation

heavy water

see deuterium oxide

helix-random coil transition 15

Helmholtz function

for water 43

hemoglobin 26,63

hemoproteins

oxidation-reduction potentials 140

Henry's Law constant 85

(also see equilibrium constants)

heterocyclic organic bases

dissociation constants 118

hydrobromic acid

conductance data 46

hydrocarbons

application of UNIFAC 38

bond energies 92

solubilities in water 58

hydrochloric acid

conductance data 46

hydrofluoric acid

conductance data 46

hydroiodic acid

conductance data 46

hydrogen ion concentration 1,35

hydrolysis 1,15,75

metal ion hydrates 137

of ATP and ADP 120

thermodynamics 4
88

hydro xyl ion

as a ligand 117,137

ice

ionic equilibrium constant 37

transport properties 37

index, substance-property 39

indicator bases

dissociation constants 118

inorganic

bond energies 133

electrolytes 16,26,93,78,98,100,111,128

1 igands (also see ligands) 131,149

inorganic compounds

chemical bonding 18

current awareness bibliography 39

solubilities 71,81,136,142

thermodynamic properties 12,17,39,40,76,93,105,106,

127,131,149

inorganic ligancts see ligands

instability constants

see equilibrium constants

insulin 137

interface potentials 26

intermolecular forces

estimation 125

International Critical Tables 151

ionic strength, effects 60,94,120

ionic transport coefficients 97

ionization constants (also see acid dissociation

constants and equilibrium constants)

acids and bases 20,94,135,140

of water 88,108,134

organic acids 128

iron chloride

activity and osmotic coefficients 104

irreversible thermodynamics 82,97,126
89

isoentropic exponent

of water 134

isomerization

carbohydrates 15

isotope effects 24

ketones

application of UNIFAC 38

lanthanide compounds

thermochemistry 54,93,101,149

Laplace coefficient

of water 134

Lennard-Jones potential

see intermolecular forces

ligands 3 ,18,89 ,94,137

1 ipids

solubilities 91

1 i quids

properties estimation 13,125

liquid-junction potentials 26

macromolecules

as ligands 137

current awareness bibliography 39

helix-random coil transitions 15

transport properties 26

magnesium ion (effects) 1,35,120

manganese compounds

thermochemistry 54,67,93,149

Margules equation

correlated data for mixtures 44

melting point

non-aqueous electrolytes 62

membranes 9,63

mercury compounds

thermochemistry 54,67,93,149

metabolic processes 59,63,75
90

metal complexes

equil ibrium data

hydrated ions

with buffers

with nucleic acids, nucleotides

and nucleosides

metal loporphyrins

oxidation-reduction potentials

metal lurgy

metal -organic compounds

sol ubi 1 i ties

thermodynamic properties

methanol as solvent

.thermodynamic properties of salts,

acids and bases in

methanol -water mixtures

acid dissociation in

microorganims

mineral

s

mixed electrolytes

mixed solvent, systems

mixtures, fluid

correlated data

current awareness bibliography

estimation of properties

mobil ities

ionic

proteins

molar volume

see volume

molybdenum compounds

thermochemistry

mul ti -component systems

solubilities in

multidentate macrocyclic compounds

muscular contraction

74,89,137

3,10,18,94,137,138,161

117

60

140

158

81

10,28,64,116

100

94

9

127

121,128

2,62,94

44,55,76,86,90

39,90

90,125

26

26

54,93,149

142,158

19

63
91

NAD (nicotinamide adenine dinucleotide)

redox potentials 21

NADP (nicotinamide adenine dinucleotide phosphate)

redox potentials 21

natural product bases

dissociation constants 118

nickel chloride

activity and osmotic coefficients 104

niobium compounds

thermochemistry 54,67,94,149

nitrites

activity coefficients 104

nitrogen compounds

enthalpy of formation 28,67,93,145,149

non-aqueous solvents

electrolytes in 100

metal -ligand complexes in 137

solubilities in 81

non-electrolytes

activity coefficients 84

heat capacities 76

non-polar gases

see gases

nucleic acids 137

nucleosides 34,60

nucleotides 34,60

nutrients

see foods

oceanography 126

organic bases

dissociation constants 118

organic compounds 3,7,20,26,28,29,30,36,61,67,

67,73,76,85,86,90,116,133,143,

147

application of UNIFAC 38

CI or C2 93,131,149

current awareness bibliography 39

solubilities 71,136,140
92

organic electrolytes

molar volumes 98

properties 128

thermodynamic quantities 111

organic ligands

see ligands

organo-metal 1 ic compounds

see metal organic compounds

osmosis, reverse 132

osmotic coefficients

bibliography 41

calcium chloride 104,124

inorganic electrolyte 26,40,48,52,104,121,123

organic electrolytes 26,128

sulfuric acid 104,121,124

theoretical 22,79,121

uni -polyvalent electrolytes 159

jni -univalent electrolytes 48

oxidation-reduction potential

s

biochemical systems 34,75,83

hemoproteins and metal loporphyrins 140

organic systems 21

selected " 140

partial molar volumes

see volume

partition coefficients 129

peptides

activities in aqueous solution 140

enthalpy of combustion and formation 140

Gibbs energy of formation 140

heat capacities, entropies 140

thermodynamics in aqueous solutions 25

partition coefficients 129

pesticides

solubilities 85

pH

acid-base equilibria 83

aqueous solutions 39

ATP hydrolvsis 120

buffers 6,140

determination of 6

effect on oxidation reduction

potentials 78

effects on reactions 1,35,60
93

phase diagrams

aqueous systems

bib! iography

71 ,72 ,81 ,127 ,136 ,142

157

K" are f v^ancif innc

organic compounds

phenols

acid dissociation constants, aqueous

ionization thermodynamics

redox potentials

phosphates

Gibbs energy and biosynthesis

hydrolysis

phosphorus compounds

thermochemistry

phosphoric acid

activity and osmotic coefficients

photolysis

estimation of

physiological energy use

pK values (also see equilibrium constants and

dissociation constants)

acids and bases

buffers

isotope effects

platinum metal compounds

thermochemi stry

polar gases

see gases

polarographic data

for non-aqueous electrolyte

sol utions

30

73

24

21

35

140

67,93,115,149

121

.29

95

20 ,34,94,117 ,140

140

24

93,54,67,149

62

polymers

polymerization processes

properties

properties estimation

polysaccharides

porphyrins

redox potentials

potential diagrams (emf)

elements and compounds

65

29

13

63

21

78
94

Prandtl number

of water 134

pressure, effect of

on enthalpy, entropy, internal energy,

heat capacity, estimation

125

proteins

heat capacities, entropies

thermodynamics in solution

140

25

proton transfer reactions

equil ibriumconstants , aqueous 94

purines

ionization thermodynamics 34

pyri mi dines

ionization thermodynamics 34

quinones

redox potentials 21

radical

s

enthalpies of formation 10,92,

rate constants

polymerization 65

red cells

mobilities 26

Redl ich-Kister equation 86

redox potentials

see oxidation-reduction potentials

refractive index

alcohols 156

estimation of 129

organic compounds 147

residence time 129

ribonucleic acid 60,137

saccharides

biosynthesis and Gibbs energy 35

salts (also see electrolytes)

thermodynamic properties in water, 100

methanol , enthanol and other

organic solvents

thermal properties of 111

uni-univalent in solution
95

scandium compounds

thermochemi stry

seawater

thermodynamic properties

serum albumin

mobil i ty

Setchenow coefficients

silicon compounds

enthalpy of formation

silver compounds

thermochemistry

sodium carbonate and bicarbonate

solution thermodynamics

sodium chloride (also see seawater)

soils and sediments

discussion of properties

solid wastes

sol ids

crystalline, properties estimation

glasses, properties estimation

solubil ities

amino acids

biochemical substances

elements, inorganic compounds,

organic compounds

fatty acids in water

gases in liquids

halogenated hydrocarbons in water

in non-aqueous electrolytes

in seawater

triglycerides

water in fatty acids

solubility constants

(also see equilibrium constants)

speciation calculations

speed of sound

spectroscopic data

for non-aqueous electrolyte solutions

54

80 ,123,126,132

26

123

35 ,67,93,115 ,149

52

121

68,121,132

129

29

13

13

26 ,39 ,71 ,72 ,81 ,85,105 ,129,

136,157

25,91,140

91

142

140

7,153

58

62

126

140

140

89,137

1 ,39,74,122,123,126

43,126

62
96

stability constants

see equilibrium constants, binding constants,

metal complexes

steam - see water

structure, relation to physical properties

sublimation pressures

solid wastes and composite materials

sulfur compounds, organic

sulfuric acid

activity and osmotic coefficients

surface tension

binary systems

estimation of

water

tantalum compounds

thermochemi stry

ternary systems

solubilities in

thermal conductivity

estimation of

water

thermal functions

thiol esters

hydrolysis

thorium

thermochemi stry

transference number

in non-aqueous electrolytes

inorganic electrolytes

organic electrolytes

transitions

coil and helix

homopolymer to coil helix

inorganic

transition metal complexes

see metal complexes

10,13,61,129

31

155

104,121,123,124

148

125

134

54,67,93,149

142

129

37,134

41,90,106,127,144

140

150

62

16,26,49,76,82,97

26,49,76

37

37

5,12,131,144

transport coefficients, ionic 66,95,97,126,128,132
97

tricarboxylic acid cycle

Gibbs energy changes

triglycerides

sol ubi 1 i ties

tungsten compounds

thermochemistry

UNIFAC

uranium halogen compounds

thermodynamic data

urea biosynthesis

enthalpy of formation and

combustion

Gibbs energy of formation

partial molar porperties

vandadium compounds

thermochemi stry

van Laar equation

correlated data for mixtures

vapor-liquid equilibria

vapor pressure

alcohol

s

aqueous electrolyte solutions

binary systems

C,H,N,0,P,S compounds

estimation

mul ti -component systems

non-aqueous electrolyte solutions

organic compounds

solid wastes and composite materials

water

virial coefficients

viscosity

binary systems

estimation

inorganic electrolytes

non-aqueous electrolytes

organic compounds

water

75

140

54,93,149

38

93,110,149

140

35

140

140

15

54,67,93,149,162

44

38,44,55,56,77,86,107

156

26,39

55,56,148

2

13,125,129,146

44,55,56

62

2,14,36,64,76,77,85,86,

90,107,129,143,147,155,

29

37,134,155

33,38,43

148

13,125,129

16,82

62

147

37,134
98

volume changes

on hydration of ions in water 37

on mixing liquids 7 on ionization of water 88,108

volumes, molar

aqueous ions and electrolytes 52,98,99,103

liquids, binary mixtures 7,90

liquids, estimation 125

water 98,99,134

water

bibliography 51

ionization of 88,108

treatise on 32,37

thermodynamic properties 43,70,134

vapor pressure and enthalpy of 155

vaporization

yttrium

thermochemi stry 93,101,149
NBS-114A (rev. 2-6C) *7rhs

*

U.S. DEPT. OF COMM. BIBLIOGRAPHIC DATA

SHEET (See instructions)

1. PUBLICATION OR

REPORT NO.

NBS/SP-685

2. Performing Organ. Report No. 3. Publ i cation D ate

December 1984

/c c

4. TITLE AND SUBTITLE

Compiled Thermodynamic Data Sources for Aqueous and Biochemical Systems

Annotated Bibliography (1930-1983)

An

5. AUTHOR(S)

Robert N. Goldberg

6. PERFORMING ORGANIZATION (If joint or other than NBS, see instructions)

NATIONAL BUREAU OF STANDARDS

DEPARTMENT OF COMMERCE

GAITHERSBURG, MD 20899

7. Contract/Grant No.

8. Type of Report & Period Covered

Final

9. SPONSORING ORGANIZATION NAME AND COMPLETE ADDRESS (Street. City, State. ZIP)

Design Institute for Physical Property Data

Project 811

American Institute of Chemical Engineers

New York, NY

10. SUPPLEMENTARY NOTES

Library of Congress Catalog Card Number: 84-601131

J

Document describes a computer program; SF-185, FIPS Software Summary, is attached.

11. ABSTRACT (A 200-word or less factual summary of most si gnificant in formation . If document includes a significant

bi bliography or literature survey, mention it here)

This is a selected and annotated bibliography of sources of comniled and evaluated

chemical thermodynamic data relevant to biochemical and aqueous systems. The

principal thermodynamic properties considered herein are Gibbs energy and equilibrium data, enthalpies of formation and reaction, heat capacities and entropies, and

the corresponding partial molar and excess properties. Derived quantities used in

calculating the above are also included. Transport and mechanical data have also been

identified to a lesser degree. Included in the annotations to the data sources are brief descriptions of the types of properties tabulated, the classes of materials

dealt with, and the degree of completeness of the compilations.

12. KEY WORDS (Six to twelve entries; alphabetical order; capitalize only proper names; and separate key words by semicolons)

aqueous systems; bibliography; biochemical systems; enthalpy data; entropy data;

equilibrium data; excess properties; Gibbs energy data; heat capacity data; partial

molar properties; review articles; thermochemistry; thermodynamics.

13. AVAILABILITY

QX] Unlimited

777 For Official Distribution. Do Not Release to NTIS

7^] Order From Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402. 7 Order From National Technical Information Service (NTIS), Springfield, VA. 22161

14. NO. OF

PRINTED PAGES

106

15. Price

USCOMM-DC 6043-PSC

JL-

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