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NATL INST OF STANDARDS & TECH R.I.C.

All 101 9861 44

Goodwin, Robert D. (/Thermophyslcal prop QC100 .U556 '170 1982 C.2 C.I NBS-PUB-C NBS

PUBLICATIONS

to Q

Or /

NBS MONOGRAPH 170

U.S. DEPARTMENT OF COMMERCE/National Bureau of Standards

>Q

100

No, 170

1932

C.2

Thermophysical Properties of

Propane from 85 to 700 K

at Pressures to 70 MPa
NATIONAL BUREAU OF STANDARDS

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Mr aTAHXiAMBm

LOBEABT

Thermophysical Properties of Propane 29 (33?

from 85 to 700 K at Pressures to 70 MPa ^

Robert D. Goodwin and William M. Haynes

Thermophysical Properties Division

National Engineering Laboratory

National Bureau of Standards

Boulder, CO 80303

DATE DUE

Demco, Inc. 38-293

U.S. DEPARTMENT OF COMMERCE, Malcolm Baldrige, Secretary

NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Director

Issued April 1982
Library of Congress Catalog Card Number: 82-6'005I4

National Bureau of Standards Monograph 170

Nat. Bur, Stand, (U.S.). Monogr. 170. 249 pages (Apr. 1982) CODEN: NBSMA6

U.S. GOVERNMENT PRINTING OFFICE

WASHINGTON: 1982
Contents

Page

1. Introduction 1

2. Physical Properties and Their Formulation . ; . , 7.

?.l Fixed-Point Values 2

2.2 Melting Line and Vapor Pressures 3

2.3 The Orthobaric Densities 3

2.4 The Virial Equation 4

2.5 The Equation of State ..... 5

2.6 The Ideal Gas Functions 8

2.7 Thermal Loop Computations 8

2.8 The Heats of Vaporization 9

2.9 Saturated Liquid Enthalpies and Entropies 9

2.10 Dielectric Constants 10

3. Computational Methods 11

3.1 The Homogeneous Domain 11 3.2 The Saturated Liquid 12

3.3 The Compressed Liquid 13

3.4 Fugacity Coefficients 13

3.5 Simplified Computation 13

4. Tests and Comparisons 13

4.1 Specific Heats 14

4.2 Sound Velocities 14

5. Tables of Physical and Thermodynamic Properties 14

5.1 Calculated P-p-T Isochores and Isotherms 14

5.2 The Joule-Thomson Inversion Locus 15

5.3 Thermophysical Properties of the Saturated Liquid 15

5.4 Thermophysical Properties Along Selected Isobars 15

6. Acknowledgments 15

7. References 17

APPENDIX A. Symbols and Units 26

APPENDIX B. Conversion of Units 28

APPENDIX C. Fixed-Point Values for Propane 29

APPENDIX D. Propane Properties Reference Index 30

APPENDIX E. Computer Program 35

iii
List of Figures

Page

Figure 1. Density-temperature diagram of propane 54

List of Tables

Table 1. Comparisons of vapor pressure data with eq (2) 55

Table 2. Comparisons of saturated liquid density data with eq (3) . . 60

Table 3. Comparisons of saturated vapor density data with eq (4) . . 65

Table 4. Comparisons of virial coefficients with eq (5) 68

Table 5. Behavior of coefficients of equation of state for

propane (eq (6)) 71

Table 6. Calculated P(p) critical isotherm of propane 72

Table 7. Comparisons of experimental P-p-T data of propane with

eq (6) . . . . , 73

Table 8. Comparisons of data for ideal gas functions with eq (7). . . 123

Table 9. Interpolated ideal gas functions from eq (7) 125

Table 10. Comparisons of heat of vaporization data with eq (9) . . . . 126

Table 11. Enthalpies of saturated liquid propane from eq (10) .... 128

Table 12. Entropies and specific heats of saturated liquid propane

from eq (11) . 129

Table 13. Comparisons of dielectric constant data with eq (12) .... 130

Table 14. Comparisons with saturated liquid specific heats 136

Table 15. Comparisons with C and C data 139

V p Table 16. Comparisons with velocity of sound data 143

Table 17, Calculated P(T) isochores of propane 151

Table 18. Calculated P(p) isotherms of propane 164

Table 19. The Joule-Thomson inversion locus for propane 185

Table 20. Thermophysical properties of saturated liquid propane ... 186

Table 21. Thermophysical properties of propane along isobars 188

Iv
THERMOPHYSICAL PROPERTIES OF PROPANE FROM 85 TO 700 K AT

PRESSURES TO 70 MPa

Robert D. Goodwin and William M. Haynes

Thermophysical Properties Division

National Engineering Laboratory

National Bureau of Standards

Boulder, Colorado 80303

Thermophysical properties of propane are tabulated at integral

temperatures over the entire range of fluid states from 85 to 700 K along isobars to 70 MPa by using a modified form of the nonanalytic

equation of state. These tables, along with a table for the saturated

liquid, include values for density, compressibility factor, internal

energy, enthalpy, entropy, heat capacities, fugacity, sound velocity,

dielectric constant, and isochore and isotherm derivatives. In

addition to the equation of state, equations are presented for vapor

pressures, orthobaric vapor and liquid densities, ideal gas properties,

virial coefficients, dielectric constants, heats of vaporization,

melting pressures, and orthobaric liquid specific heats, enthalpies, and

entropies. Coefficients were determined by a least squares fit of

selected experimental data, including several new sets of data not

included in previous propane correlations. Comparisons between

experimental and calculated values are given, including those for sound

velocities, heat capacities, P-p-T data, etc.

Key words: Densities; dielectric constants; enthalpies; entropies;

equation of state; fugacities; internal energies; isobars; isochores;

isotherms; Joule-Thomson inversion; latent heats of vaporization; melting

line; orthobaric densities; propane; specific heats; vapor pressures;

velocities of sound.

1. Introduction

The present work is a revision and extension of a previous provisional

report [32] from this laboratory. Since that report many new data have become

available. These include: P-p-T compressibility data [25,42,94,95,102]; some

new vapor pressure data [57,66,94,95]; new specific heats [34] and sound

velocities [107] for the saturated and compressed liquid; and new dielectric

constant data [42,45] for the saturated and compressed liquid. Other

correlations (and compilations) for propane [9,16,20,27,41,59, 83,84,86,90,106]

should be noted. However, most of these correlations are now outdated with the

availability of new and accurate data, often in regions in which data did not

previously exist.

1
In the present work a new procedure is employed for selecting the critical

density, and the nonanalytic equation of state has been modified from previous

applications [30-33,35,36,38]. Derived heats of vaporization are used to obtain

enthalpies and entropies of the saturated liquid, such that the free energy of

vaporization is zero. Thermodynamic functions for the compressed liquid then are obtained by use of these derived properties from the triple point to the critical

point temperature.

Computations in computer programs (Appendix E) for the present work have

been conducted in units of the bar, the mol , and the liter. However, SI units

are used throughout this report in tables and equations. Pressures are given in

MPa, densities in kg/m-^, and temperatures in K. For thermal properties, the

mol is used for amounts of substance. Symbols and units used in this report

appear in Appendix A and conversion factors in Appendix B. Fixed-point values

used here are in Appendix C. References for the principal physical properties of

propane are collected in Appendix D. Computer programs for calculation of

thermophysical properties of propane are in Appendix E. The density-temperature

diagram for propane is presented in figure 1, where the upper, left-hand corner

shows the freezing liquid line.

2. Physical Properties and Their Formulation

2.1 Fixed-Point Values

These values are listed in Appendix C.

(a) The Triple Point. The temperature (T^ = 85.47 K) is adopted from

Das and Eubank [20]. The pressure is given by the present vapor-pressure eq (2).

The liquid density is assigned for consistency with data in eq (3). The vapor

density is from eq (4) for saturated vapor densities. (In recent work [70] on the triple point temperature of propane, including an investigation of two solid

phases, a value of T^ = 85.52 K was reported.)

(b) The Boiling Point. The temperature is from vapor-pressure eq (2) at a pressure of 1 atm = 0.101325 MPa. Liquid and vapor densities are from eqs (3)

and (4).

(c) The Critical Point. Our selected temperature was found to be the same

as reported independently by Thomas and Harrison [95]. The pressure, at first

found from the vapor-pressure equation by simultaneous fitting with P-p-T data,

fell between values obtained from two propane samples of Thomas and Harrison, and

2
thereafter the vapor pressure equation was constrained to this value. The

critical density was derived by the liquid volume fraction procedure of

Van Poolen [101] using the orthobaric densities of Thomas and Harrison [95]. It

is about one percent higher than that derived by Thomas and Harrison and is

consistent with the value selected in the correlation of Das and Eubank [20].

2.2 Melting Line and Vapor Pressures

(a) The F-lelting Line. Experimental pressures from about two to ten

kilobars were reported by Reeves, Scott, and Babb [74] as constants for the Simon

eq (1). Their extrapolation to zero pressure gave T^ = 35.3 K. As their

uncertainty in T was at least 1 K, the selected triple-point temperature from Das

and Eubank [20] is used here. Melting pressures (P^) in MPa are given by

the relation,

where P^ = 1.6895 x 10"^^ MPa, T^ = 85.47 K, P^ = 718 MPa, and c = 1.283.

(b) The Vapor Pressures. Data used for adjusting eq (2) appear in the

first part of table 1. Other data, weighted zero, appear in the continuation.

The low pressure data with ID = 80 are newly derived via thermal loops [32] by use of new saturated liquid specific heats formulated up to 290 K by Goodwin

[34]. (See section 2.7.) Define the argument, x = "'"/T^,; then vapor pressures

(P^) in MPa are given by the relation,

£n(P^-10) = a/x + b + c -x + d-x^ + e-x^ + f-(l - x)^ , (2)

where e = 1.35 and, from least squares analysis,

a = - 8.7227 80250 d = 12.6857 90059

b = 19.2030 78280 e = - 3.8065 42924

c = -15.6106 38913 f = 1.8832 14505

The critical-point slope dP^/dT (0.08113 MPa/K) was constrained to equal the

slope of the critical isochore from the equation of state at the critical point,

(9P/3T)^.

2.3 The Orthobaric Densities

(a) The Saturated Liquid Densities. Data used for adjusting eq (3) appear

in the first part of table 2. Other data appear in the continuation. If the

3
dependent variable is defined by y(p) = (p^ - Pc)/(Pt " ^ ^'^ defined by

x(T) = (T^ - T)/(T^ - Tj.), then the equation for saturated liquid densities is

F ? y = X + (x' - x) '[a + b'x + c*x"] , (3)

where z - 0.35 and, froni least squares analysis,

a = 0.7643 89673 c = -0.1 150 01817.

b = 0.0094 57047

Equation (3) is constrained to a triple-point liquid density of 16.630 mol/L, such

that the calculated densities at low temperatures are consistent with the most recent

and most reliable data sets [45,64,68,75].

(b) The Saturated Vapor Densities. Data used for adjusting eq (4) appear

in the first part of table 3. Data at ID = 1 are derived from the vapor-pressure

and virial equations. Other data, weighted zero, appear in the continuation of

table 3. The following, new formulation of the compressibility factor for

saturated vapor utilizes the vapor-pressure equation, and yields l^-'-^'X as

a behavior needed when integrating the thermodynamic equation of state.

Let ; (Z^ - 1) where is value of the compressibility factor at the

critical point, and define the arguments, n(T) = Pg(T)/P^, x(T) e T/T^, and

u(T) E (1 - x). The saturated vapor densities, e P^(T)/(Z^»R»T) , then are given by ^ Z^(T) = 1 + A^'n-x"^-f(x) , (4)

where

f(x) E 1 + u^-[a + b'x + c-x^ + d'x"^] , (4a)

e = 0.35, and, from least squares analysis,

a = 5.439 73368 c = 23.871 0761

b = -20.029 7592 d = -10.105 1069

Column, F(Z), in table 3 gives the experimental residual,

2.4 The Virial Equation

This equation of state usually is accurate at densities up to p^/5 when

truncated as follows

4
Pv/RT = 1 + B^(T)-p^ + C^(T)-p^ + . . . (5)

The second and third coefficients, B^(T), C^(T), here are dimensionless through

use of reduced density and temperature, p^ = p/p^. x = "^/^c*

^^ta have been

collected in two excellent monographs [24,71]. Table 4 compares selected data

with the following fitting functions developed here for propane

B^(T) = B^ + B^/x + B3/x^ , (5a)

C^(T) = (1 - Tq/T).[C^/x + yx^j , (5b)

where

T = 342.250 K B^ = -0.458 0172

0 3

B^ = 0.478 4915 = 0.215 0050

B^ = -1.230 0138 = 4.798 6166

In present work, only the second coefficient has been used: in thermal loop

computations; to synthesize P-p-T data for adjusting the equation of state;

and to obtain saturated vapor densities via the vapor-pressure equation.

2.5 The Equation of State

Appendix D and table 7 summarize P-p-T data of propane. Inclusion of the

recent data of Ely and Kobayashi [25], Thomas and Harrison [95], and of

Haynes [42] provides a dense coverage of the P(p,T) surface for propane at

3 densities up to 740 kg/m (16.8 mol/L), and at temperatures from 90 to 523 K.

The present equation of state is modified from earlier forms [30-33,35,36,

38]. It is nonanalytic, yielding a maximum in specific heats Cy(p,T) at the

critical point.

P = P^(p) + p^-R*-[T - T^(p)] + p^ R*T^-F(p,T) , (6)

where F(p,T) e B(p) •<i>(p,T) + C(p) •*(p,T) . For any density, obtain the coexistence temperature T^(p) by iteration

from eqs (3) or (4) for the orthobaric densities. Place this in the vapor

pressure eq (2) to obtain P^(p) = P^[T^(p)]. Densities, p^ = P/^c' reduced

at the critical point. The gas constant for eq (6) therefore is redefined,

R* 5 (0.0083145) -p^, MPa/K.

5
The temperature-dependent functions in eq (6) are defined as follows.

Hp J) = x^.exp [b'd - T^/T)] - x^^ , (6a)

where b e (1 - 3) (1 - 3)^^^^, x 5 T/T^, and x^ = ^o^^^^'^c'

^'(p,T) - ^(P,T)/^^(P) - 1 , (6b)

where ^^(p) is obtained from >{^(p,T) merely by replacing T with T^(p), and

Mp J) E 1 - (co - J^/r^)/{] - 1/t^) , (6c)

where a)(p,T) e [I - 0(p)/T]. A value for 3 vyas found by trial. The locus of

temperatures inside the coexistence envelope is

9(p) = T^(p)«exp[- a.f(p)] , (6d)

where

f(p) = IP, - ll^/((Pt)r -

(P|.)^ = P^/Pq is a constant, and refers to liquid density at the triple

point. The parameter a is to be found by trial.

The density-dependent coefficients of eq (6) have been developed tediously

by trial with data for propane;

B(p) E 3^ + Q^'pI (6e)

and

C(p) E C-,-(p^ - l)-(p^ - CQ)-exp(- Y-pJ) , (6f)

where parameters and y at^e to be found by trial.

The parameters and coefficients of eq (6) for propane are

a = 1, 3 = 0.70, Y = 0.15, n = 1.1,

= 0.4565 0524 198 C^^ = 2.2

82 = 0.1582 2653 715 ' = -0.2490 4576 736

Table 5 gives behavior of coefficients B(p), C(p).

Behavior of the calculated critical isotherm near the critical density is

shown in table 6. In particular, the slope (8P/3p .)y is seen to have no

r , L \q

6
negative values. (Densities in table 5 are reduced at the liquid triple point,

= p/p^.) Table 7 gives deviations of experimental densities and pressures

from the equati on-of-state surface for most available data. Data not used for

adjusting the equation of state include those of Tonilinson [98], Deschner and

Brown [22], Teichmann [94], and of Warowny, et al . [102].

Some of the preliminary data of Thomas and Harrison [95] (for T > T^) that were used in the fit of the equation of state were subsequently adjusted as a result of a small air impurity (0.004 percent) in their sample gas. The maximum

change in pressure was 0.017 percent while the average change was 0.004 percent.

Such a small change has negligible effect on the equation of state. Comparisons

with the corrected data of Thomas and Harrison are given at the end of table 7.

The preliminary data, which were used in the fit but do not appear in the table, are represented by data points 720-931 missing from the table. For temperatures

less than T^, most of the data of Thomas and Harrison (designated in table 7 as points 1460-1988) were obtained with a different sample and they made no adjustments to this data.

On the first page of table 7, a summary of comparisons of P-p-T data with

values calculated from the equation of state is given. For the isochores of

Thomas and Harrison, deviations in the table are those for the corrected data.

For the preliminary data the density and pressure deviations are 0.43 and 0.32

percent, respectively, or approximately the same as those for the corrected

data.

An explanation for some of the large density deviations in table 7 (e.g.,

data points 1626, 1640, etc.) that are exhibited when the data of Thomas and

Harrison [95] are compared with the equation of state should be noted. These

data points were taken extremely close to the liquid-vapor coexistence boundary.

Although the pressure deviations were relatively small (maximum of 0.15 percent)

when compared to the equation of state, the pressure deviations were of sufficient magnitude in some regions of experimental data such that the calculated

density fell on the wrong side of the "dome" and gave a liquid instead of a vapor

density, or vice versa.

It should be noted that the functional form of the equation of state for

propane given here also has been used in current work on isobutane [37] and

normal butane [43]. Identical nonlinear parameters, except for small differences

in Y, have been obtained for all three fluids in optimizing this equation to

available P-p-T data.

7
2.6 The Ideal Gas Functions

Chao, et al . [13] calculated ideal gas thermodynamic properties using

spectroscopic data and compared results for the specific heat with other sources. A plot of their c'^(T) is linear at low temperatures, changing to the

P usual sigmoid shape at high temperatures, a behavior that we could not represent

analytically. Their enthalpies are represented by use of the arguments

X = T/lOO and u = X 1/3.

(H° - H^)/RT = 4 9xp(- £/x)- 2 A./u^

i=0

^ (7)

where R = 8.31434 J/(mol'K), e = 3, and

A.^0 ^3

A„ = -585.32814 A.

A

24.11012

94.40550

= 980.124065

= -673.64094

= 170.42778 ^2 —— -5

Specific heats are C^(T) = dH^/dJ, but the entropies require numerical

integration (SUBROUTINE IDEAL, Appendix E),

.T S°(T) = S°(300) + f C°'dT/T

300 P (7a)

where S°(300)/R = 32.552. Table 8 presents the data used for adjusting

eq (7), and table 9 gives interpolated results from eq (7).

2.7 Thermal Loop Computations

At temperatures from the triple- to the normal boiling-point, new data have

been derived for vapor pressures, saturated vapor densities, and for heats of

vaporization by thermal loop computations including AH and AS for saturated vapor

and for saturated liquid. The procedure given by Goodwin [32], and more generally by Yarbrough and Tsai [103], used virial eq (5), ideal gas functions

eq (7), the heat of vaporization of Kemp and Egan [53] at the normal boiling

point, and the following formulation of the specific heats of Goodwin [34] for

the saturated liquid from the triple point to 290 K. Define x = T/369.80, then

C^(T) = A^-x/(l - x)^

5 ^ E

i = 2

A^ 'x i-2

(8)

i n J/(mol 'K) , where

8
e = 0.7 A3 = 48.U1034

A^ = - 1 .77942 A4 = -100.24355

A^ = 77 .12878 A. = 135.42504

2 b The rms relative deviation is 0.13 percent for the 76 data points. (The

temperature, 369.80 K, was used as a reducing parameter for x in the original

thermal loop computations. Since the fit of the specific heats is independent of

the selected temperature over a wide range, it has not been changed to the

critical temperature selected in the present work.)

Results for the vapor pressures appear in table 1 at ID = 80, and for the

heats of vaporization in table 10 at ID = 40. Saturated vapor densities from the

thermal loop computations are replaced in table 3 at ID = 1 by derived data from

the fitted vapor-pressure eq (2) and the virial eq (5).

2.8 The Heats of Vaporization

Table 10 shows the "fit" of selected data. Those at ID = 40 are derived via

thermal loops (section 2.7). Those at ID = 41 are from the Clapeyron equation.

The formulation of these data in kJ/mol uses argument x(T) e (T^ - T)/(T^ - T^)

;

^vap

" A^-x + (x^ - x)-[A2 + A3-X + A^-x^] , (9)

where

e = 0.38 A3 = 6.252 384

A^ = 24.840 848 A^ = -12.156 857

A2 = 24.166 535

The uncertainty of at least 0.5 percent in derived data for Q^^^ at the higher

temperatures will affect compressed liquid thermofunctions at these temperatures,

because we use Q^^^ to compute AH and AS across the "dome," from saturated

vapor to liquid along isotherms.

2.9 Saturated Liquid Enthalpies and Entropies

Data for saturated liquid enthalpies and entropies have been derived at

temperatures from the triple- to the critical -poi nt by use of the ideal gas

functions, the equation of state, and the formulated heats of vaporization. The

enthalpies then have been formulated, as shown in table 11. Define the

variables

X i (T, - T)/(T^ - Tj) . y E (H^ - H^)/(H^ - H^) ,

9
when the enthalpies, H (T), are described in J/inol by

o

y = X + (x^^ - x) • E A.-x'""'' , (10)

i = 1

^

where e = 0.37, = 0.001 J/mol , = 33082.187 J/mol and

A. = 0.2998 57304 = -0.9494 39705

1 b

Ao = 0.3868 58687 A^ = 0.1462 98673

2 6

A3 = -0.6240 97828 A^ = 0.1113 75514

A4 = 1.0360 03301

The formulation of saturated liquid entropies in J/(mol'K) is shown in

table 12. Let x s (T^ - T)/(T^ - T^) and y = {S^ - ^c^^^^t

' ^c^

8 .

-, y = X + (x' - x)- Z A.-x^-' , (11)

i = l

^

where e = 0.32, S. = 82.56147 J/(mol-K), S = 234.72617 J/(inol -K) , and

A^ = 0.1263 07708 A^ = 14.0277 6880

A^ = -0.7539 54622 A. = -20.6289 4506

2 D A3 = 1.2532 70427 A^ = 16.0117 8434

A^ = -5.9696 10330 ^8 " " 5. 4110 8275

Specific heats along the saturated liquid path follow froin the relation,

C^(T) = T*dS^/dT, in J/(molM(), as given in the last column of table 12. For

the thermal computations, these derived C^(T) values are replaced by our formulation of experimental data, given below in section 4.1.

All of the above saturated liquid formulations for H^(T), S^.(T), and

C^(T) are used to compute thermodynamic properties for compressed liquid

states at T <

2.10 Dielectric Constants

Table 13 presents experimental and calculated dielectric constants, e, for

the saturated vapor [89] and liquid [45,89] and for the compressed liquid [42] of

propane. These data are formulated via the CI ausi us-Mossotti function,

CMF = [(e - l)/(e + 2)]/p, cm"^/mol (12a)

10
The following formulation has been used to tabulate e along isobars in table 21

at temperatures extrapolated up to 450 K, and at pressures up to 70 MPa. Define

the variables,

X ^ V\ . = P/P^ ,

where P is in MPa, when

CMF = + A2*P^ + A3-p^ + A^*£n (1 + 1/x) + A^-P/10 (12b)

A^ = 15.562 6310 A^ = 0.5107 4051

A2 = 0.385 3141 A5 = -0.0045 1412

A3 = -0.150 9977

Data at high pressures have a diminished weighting as seen in table 13. The rms relative deviation for 260 points is 0.048 percent in the CMF, and 0.018 percent

for the dielectric constants.

Comparisons are not given in table 13 for data not used in the fit to

eq (12). The dielectric constants of Pan, Mady, and Miller [69] at temperatures

from 91 to 115 K differ from those calculated from eq (12) by approximately 0.8

to 1.0 percent while those from Thompson and Miller [96] and Luo and Miller [62]

at temperatures between 220 and 288.7 K agree v^fithin 0.1 percent with values

calculated from eq (12).

3. Computational Methods

The numerical values for E and H in this report are based on the assigned

value, E = 0 at the liquid triple-point, obtained by use of the arbitrary value,

E^ = 21,888.910 J/mol. Specific heats of Kemp and Egan [53] could be

integrated to give the solid at T = 0 as reference state.

3.1 The Homogeneous Domain

The homogeneous domain of figure 1 includes all regions which can be

attained along isotherms starting at zero density without crossing the

vapor-liquid "dome," and without passing very close to the critical point at

T > Tc.

Computations start with ideal gas thermodynamic functions at zero density,

and then continue by integrating along isotherms by use of the equation of state

in the following relations,

11
AE = f

[P - T.0P/3T)].dp/p^ , (13)

= - T- y 0^P/3T^)-dp/p^ , (14)

AS = R-£n[P°/(pRT)] +/ [R - ( 3P/9T) /p] -dp/p . 0

(15)

Equation (15) is for use with initial entropies in hypothetical ideal gas states

at P^ = 1 atm (0.101325 MPa) . For all other initial states,

AS = - y 0P/9T)-dp/p^ . (15a)

In each (p,T) state, reached by above integrations, the following are computed,

H = E + P'v , (16)

Cp = + T-(9P/3T)^/OP/9p)/p- , (17)

and

'/ = Cp.(9P/9p)/C^ . (18)

3.2 The Saturated Liquid

At temperatures from the triple point up to the critical point, thermofunctions for the saturated vapor are obtained via eqs (13) through (16). Then

eq (9) is used for the heat of vaporization, Q^^p* to compute

AH = - Q , AS = AH/T , (19)

such that the free energy of vaporization, AF = AH - T'AS, is zero (see

section 2.9). Having obtained H and S for the saturated liquid, E = H - P-v is

computed.

The single-phase specific heat, Cy(p,T), at the saturated liquid boundary,

is obtained via eq (23) for C^(T), given below, and the thermodynamic relation,

C^(p,T) = C^(T) + T.(9P/9T).(dp^/dT)/p^ , (20)

where p^^ is density of the saturated liquid. Values for Cp(p,T) and W(p,T) on this boundary follow from eqs (17) and (-18). For liquid at the normal boiling

point, the following values have been obtained,

12
= 231 .068 K, = 13135.9 J/i,iol

,

Ej^ = 13128.2 J/mol , = 171 .288 J/(mol- K)

3.3 The Compressed Liquid

Starting with above values for E, S, and on the saturated liquid

boundary, eqs (13), (14), and (15a) are used to integrate along isotherms, and

then H, C , and W are obtained via eqs (16), (17), and (18).

P 3.4 Fugacity Coefficients

The fugacity coefficients in table 21 were computed along isotherms relati

to properties in hypothetical ideal gas states at a pressure, P*^ = 1 atm

(0.101325 MPa)

,

(f/P) = (P°/P)-exp [AF/RT] . (21)

For any (P,T) point, the isothermal free energy change is

AF = (H - E°) - H° - T-(S - S°) , (22)

in which the arbitrary value of was added to tabulated values of H(P,T)

such that E(P,T) = 0 for liquid at the triple point.

3.5 Simplified Computation

Given the subroutines of Appendix E, it is necessary first to call

SUBROUTINE PVTDATA, to place constants in common statements. To obtain the

density in mol/L at a given T,i< and P,bar, it is necessary merely to write the

instruction DEN = FINDENF(T,P) for single-phase domains. Coexisting densities

are given by the functions DENG.ASF(T) and/or DENLIQF(T), and the vapor pressure

in bar by PSATF(T).

For thermodynamic properties, the subroutine SIMPLE here is an example of

how to use the general subroutine THERMO (see Appendix E)

4. Tests and Comparisons

In the provisional report, Goodwin [32] compared some enthalpy differences

and residual specific heats with derived results of independent authors, i.e.,

Kuloor, et al . [59], Eubank, et al. [27], to ensure freedom from gross errors. These now are omitted, as present properties are comparable with the earlier

work. Following are some comparisons of experimental specific heats and speeds

of sound with calculated values.

13
4.1 Specific Heats

Table 14 gives a comparison of saturated liquid specific heats, taken from

the report by Goodwin [34]. These are formulated with coefficients revised for

the present critical temperature of 369.85 K; for the range froin T^ to T^

with X = T/T^, the saturated liquid specific heats, in J/(mol*i(), are given by

(23)

8.275 839

-19.926 387

51 .208 621

Table 15 gives comparisons of C and C data of Ernst [26], Goodwin [34],

V p and Yesavage [104,105] with calculated values.

4.2 Sound Veloci ties

Table 16 gives comparisons of velocity of sound data with calculated values

for the saturated liquid results of Rao [72] and of Younglove [107], and for the

single-phase measurements of Lacam [60] and of Younglove [107]. The differences

approaching 6 percent at low temperatures have required a careful scrutiny of the

calculated derivatives used in the computation of the sound velocity. The

calculated values of (3P/3p) in table 18 agree well with plots of Haynes [42]

isotherms at low temperatures, and the calculated values of ('aP/3T) in table 17

agree with plots of the Ely and Kobayashi [25] isochores. The uncertainty of up

to 3 percent in the C^(p,T) data in table 15 thus corresponds to an estimated

maximum uncertainty of about 2 percent in the calculated speeds of sound at low

temperatures. For saturated liquid, the present calculated values fall between

those of Rao [72] and Younglove [107].

5. Tables of Physical and Thermodynamic Properties

5.1 Calculated P-p-T Isochores and Isotherms

Tables 17 and 18 give a selection of isochores and isotherms computed by

equation of state (6). These are essential to examine behavior of the P(p,T)

surface. They are a useful supplement to the isobars of table 21 for

interpolating P-p-T values and their derivatives.

C^(T) = A^-x/d

where

e = 0.7

A^ = 6.636 737

A2 = 80.767 32

i=2

^

14
The tables of isechores show that the isochore curvatures are qualitatively

consistent with a maximum in the specific heat Cy(p,T) at the critical point.

The isotherm tables show that 8P/9p is nonnegative and that pressure increases

monotonical ly with density along isotherms.

5.2 The Joule-Thomson Inversion Locus

Table 19 gives the P-p-T locus of the JT inversion, (9T/9P)^ = 0,

obtained from equation of state (6) under the condition T»(3P/3T) = p*(9P/3p).

This table has been computed to temperatures well above those of P-p-T data, to

show approach to a maximum in P-T coordinates.

5.3 Thennophysical Properties of the Saturated Liquid

Table 20 gives physical and thermodynamic properties of the saturated liquid

computed by methods of section 3. (Properties of the saturated vapor can be

obtained from Table 21 from values given at the coexistence boundary for each

isobar.)

5.4 Thermophysical Properties Along Selected Isobars

Table 21 gives physical and thermodynamic properties on isobars, computed by

methods of section 3. These tables are extrapolated above the maximum

temperature and pressure of P-p-T data used for adjusting the equation of state.

Small discontinuities may be detected at T^ = 369.85 K along isobars at

P > P^ = 4.24746 MPa due to a change in the paths of computation (section 3).

The first line of each table refers to freezing liquid on the P(T) melting

line. Each table at P < P contains a blank line for the transition from

c saturated liquid to vapor, as seen by the abrupt decrease of density. Dielectric

constants are extrapolated above maximum experimental temperatures and pressures

(see section 2.10 and table 13).

6. Acknowledgments

Roland H. Harrison and R. H. P. Thomas of the Department of Energy,

Bartlesville Energy Technology Center kindly communicated the results of their

extensive P-p-T measurements before publication of their data. Many staff

members of the Thermophysical Properties Division of the National Bureau of

Standards have contributed valuable suggestions, references, and documents.

Robert D. McCarty contributed the essential least-squares program, providing for

constraints. James F. Ely indicated the new numerical integration procedure, and

the simple method for obtaining fugacities. Lambert J. Van Poolen assisted with

15
the procedure for liquid volume frdctions. Neil A. Olien and the Cryogenic Oata

Center have been of invaluable assistance in supplying references and in

obtaining documents. Special thanks go to Karen A. Bowie for her diligence and

expertise in the preparation of the manuscript and tables for publication.

Finally, we express grateful appreciation for support of this work by the Gas

Research Institute.

16
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by means of a mass spectrometer, J. Phys. and Colloid Chem. 55^, 733

(1951).

[98] Tomlinson, J. R. , Liquid densities of ethane, propane, and ethane-propane

mixtures. Technical Publication TP-1, Natural Gas Processors Assoc., 808

Home Federal Bldg., Tulsa, Okla. 74103 (Feb 1971).

[99] Tsai, Cheng-Hsiung, Low temperature phase equilibrium for systems

containing a pure condensed phase, Thesis, Tennessee Technological Univ.,

College of Engineering, Cookeville, Tn. 38501 (Jun 1971).

[100] Van der Vet, A. P., (Dutch-Shell Labs., Amsterdam), Density,

compressibility, expansion of light hydrocarbons and of light hydrocarbon

blends. Congress Modial du Petrol. II, 515, Paris (1937).

[101] Van Poolen, L. J., Analysis of liquid volume and liquid mass fractions at

coexistence for pure fluids, Nat. Bur. Stand. (U.S.) NBSIR 80-1631 (May,

1980).

[102] Warowny, W. , Wielopolski, P. and Stecki, J., Compressibility factors and

virial coefficients for propane, propene and their mixtures by the Burnett

method, Physica 91 A, 73 (1978).

24
[103] Yarbrough, D. W. and Tsai , C.-H., Vapor pressures and heats of

vaporization for propane and propene from 50 K to the nonnal boiling

point. Advances in Cryogenic Engineering Vol 23, 602 (1977).

[104] Yesavage, V. F., The measurement and prediction of the enthalpy of fluid

mixtures under pressure, Ph.D. Dissertation, Dept. of Chemical and

Metallurgical Engineering, Univ. of Michigan (Nov 1968).

[105] Yesavage, V. F., Katz, D. L. and Powers, J. E., Thermal properties of

propane, J. Chem. Eng. Data ]± (2), 197 (Apr 1969).

[106] Young, S., On the boiling points of the normal paraffins at different

pressures, Proc. Roy. Irish Acad. 38B (4), 65 (1928).

[107] Younglove, B. A., Velocity of sound in liquid propane, J. Res. Nat. Bur.

Stand. (U.S.) 86 (2), 165 (1981).

[108] Ziegler, W. T., The vapor pressures of some hydrocarbons in the liquid and

solid state at low temperatures, Nat. Bur. Stand, (U.S.) Tech. Note No. 4

(May 1959), PB 151363.

[109] Ziegler, W. T., Kirk, B. S., Mull ins, J. C. and Berquist, A. R.,

Calculation of the vapor pressure and heats of vaporization and

sublimation of liquids and solids below one atmosphere pressure.

VII. Ethane, Tech. Report No. 2, Proj. A-764, Eng. Expt. Sta., Georgia

Inst. Technology, Atlanta, Georgia (Dec 1954).

[110] Zwolinski, B. J., et al.. Selected values of properties of hydrocarbons

and related compounds, American Petroleum Institute Research Project 44,

Thermodynamics Research Center, Texas A&M University, College Station,

Texas 77843 (loose leaf data sheets, extant 1972).

25
APPENDIX A. Symbols and Units

Subscripts c and t refer to critical and liquid triple points.

Subscripts g and i refer to saturated vapor and liquid.

Subscript a refers to liquid-vapor coexistence (usually the liquid).

Subscript r refers to reduced parameter.

Subscript o refers to reference state property.

Subscript m refers to melting line.

Subscript b refers to normal boiling point.

Superscript o refers to ideal gas state property,

expt refers to experimental value,

calc refers to calculated value.

(3P/9T)p isochore derivative, MPa/K

(9P/3p)-|- isotherm derivative, MPa^m^/kg

(32p/3T^)p isochore curvature, MPa/K^

a,B,Y,n nonlinear parameters in the equation of state

a,b,c,d,e,f coefficients defined in various equations

Aq Zj, - 1 in saturated vapor density equation

A^- coefficients defined in various equations

b (1 - B) + (1 - B)^''- in equation of state

B(p),C(p) density-dependent coefficients in the equation of state

B(T),C(T) second and third virial coefficients

Bp(T),C^(T) reduced second and third virial coefficients

c exponent in Simon equation

Cy(p,T) molal heat capacity at constant volume, J/(mol*K)

Cp(p,T) molal heat capacity at constant pressure, J/(molMC)

C^(T) molal heat capacity for saturated liquid, J/(mol*K)

CMF CI ausi us-Mossotti function, cm-^/mol

E(p,T) the internal energy, J/mol

E° 21,888.910 J/mol (arbitrary)

e exponent in various equations

e dielectric constant

f/P fugaci ty/pressure ratio

f(p) used in definition of 9(p)

f(x) defined in saturated vapor density equation

F(p,T) defined in the equation of state

F(Z) defined in the saturated vapor density equation

Hq enthalpy for ideal gas state at T = 0

26
APPENDIX A. (Continued)

H(p,T) the enthalpy, J/mol

J the joule, 1 N*in

JT Joule-Thomson

L the liter, 10"^

mol 44.09721 grams of propane (C^^ = 12 scale)

(jj(p,T) defined in the equation of state

P pressure, MPa

P^ melting pressure, MPa

P^(T) the vapor pressure, MPa

P^(p) P(j[T^(p)], vapor pressure as a function of density

n(T) Pa(T)/Pc

$(p,T) function in the equation of state

^(p,!) function in the equation of state

Qygp '^^vap'

^'^^ '^^^^ vaporization, J/rnol

R^^) the gas constant, 8.3145 J/(mol-K), 0.0083145 MPa-L/( mol 'K)

R* 0.0083145 -pc, MPa/K

p density, kg/m3

Pp q/Qq, density reduced at the critical point

pp ^ p/Pf density reduced at the triple point

S(p,T) the entropy, J/(mol*K)

T temperature, K

Tq constant

T|^(p) liquid-vapor coexistence temperature, K e(p) defined locus of temperatures

u(T) defined in various equations

V 1/p, molar volume, m^/kg

W(p,T) the velocity of sound, m/s

x(T) T/Tc for the equation of state

x(T) variously defined for other equations

Xjj(p) l^{p)/J^, reduced temperature at coexistence for the equation

of state

y defined in various equations

Z compressibility factor

The gas constant is increased slightly in value from earlier work in view

of the recent report of Rowlinson and Tildesley [78].

27
APPENDIX B. Conversion of Units

In the following table the molecular v/eight oT propane is given by

mol . wt. = 44.09721 g/inol . Also, 1 cal^^ - 1 cal (thermochemi cal ) = 4.184 J and 1 BTUj-p = 1 BTU (International Table) 1055.056 J.

To convert from To

Pressure, MPa

Volume, m^

Density, kg/m'-

Molar energy, J/mol

Molar entropy, J/(molM<)

bar

atm

kg/ cm Ib/in^

liter (L)

ft^

g/cm"^

mol/L

^b/fV'

MPa 'm^ /kg

bar*L/mol

cal.(.|^/mol

BTU

J j/ lb

BTUjy/(lb-°F)

Multiply by

10.

9.86923

10.1972

145.038

1000.

35.3147

0. 001

1 . / (mol . wt .)

0.062428

0.001/(mol . wt.)

0.01

^ 0.239006

0,429923/(mol . v/t.)

0.238846/ (mol . wt.)

r

28
APPENDIX C. Fixed-Point Values for Propa

Critical Point

4.24746 MPa

= 220.5 kg/m3 (5.00 rnol/L)

= 369.85 K

Normal Boi 1 ing Point

P = 0.101325 MPa

T = 231 .068 K

Py = 2.416 kg/m^ (0.05478 mol/L)

= 581 .04 kg/rn3 (13.176 mol/L)

Triple Point

P^ = 1 .6895 X 10"^^ MPa

= 85.47 K

Py = 1.0484 X 10"^ kg/m^ (2.3775 x 10"^^ mol/L)

p^ = 733.34 kg/m3 (16.630 mol/L)

29
APPENDIX D. Propa

Melting Line

Reeves [74]

Babb [1]

Properties Reference Index

Date Pressure Range, MPa

1964 200 - 1000

1970 75 - 1050

Vapor Pressures Date Temperature Ra

Burrell [8] 1916 149 229

Maass [53] 1921 230 250

Dana [19] 1926 210 323

Sage [81] '

• 1934 on /I 294 359

Beattie [3] 1935 323 348

Kemp [53] 1938 166 231

Deschner [22] 1940 302 Tc

Gill i land [29] 1940 315 358

Cherney [14] 1949 303 323

Reamer [73] 1949 313

Tickner [97] 1951 105 165

Clegg [15] 1955 323 Tc

Helgeson [46] 1967 278 361

Carruth [11,12] 1973 95 179

Mousa [66] 1977 335 Tc

Teichmann [94] 1978 325 363

Kratzke [57] 1980 312 368

Thomas [95] 1982 258 Tc

Thermal loops (This report) 1982 h 230

Saturated Liquid Densities Date Temperature Range, K Maass [63] 1921 195 - 249

Dana [19] 1926 273 - 329

Sage [81] 1934 294 - 369

Van der Vet [100] 1937 283 - 323

Deschner [22] 1940 303 - Tc

' Carney [10] 1942 228 - 333

NGAA [67] 1942 227 - 333

Reamer [73] 1949 313 - Tc

Clegg [15] 1955 323 - Tc

30
APPENDIX D. (Continued)

Saturated Liquid Densities Date Temperature Range,

Francis [28] 1957 293

Seeman [85] 1963

~7 278 - 299

Helgeson [46] 1967 o "7 r> 278 - 361

Klosek [56] 1968 on89 - 1 33

Shana'a [87] 1968 1 1'\0 lUo

Jensen [48] 1969 93 TOO - 133

Sliwinski [88] 1969 ooo coo - 309

Tomlinson [98] 1971 2/8 O T O - 313

Kahre [50] 1973 o ~7 n 278 - 328

Rodosevich [75] 1973 91 - 115

McClune [64] 1976 93 - 173

Haynes [44] 1977 100 - 289

Ely [25] 1978 166 - 288

Orrit [68] 1978 87 - 244

Thomas [95] 1982 258 - 369

Saturated Vapor Densities Date Temperature Range,

Dana [19] 1926 290 - 323

Sage [81] 1934 294 - 369

Deschner [22] 1940 303 - Tc

Reamer [73] 1949 313 - Tc

Clegg [15] 1955 323 - Tc

Helgeson [46] 1967 278 - 361

Sliwinski [88] 1969 283 - 369

Thomas [95] 1982 323 - 369

Virial/vapor pressure equations (This

report)

1982 90 - 330

Virial Coefficients Date Temperature Range,

Sage [81] 1934 294 - 377

Beattie [2] 1937 370 - 548

Jessen [49] 1938 273 - 323

Deschner [22] 1940 303 - 609

Cherney [14] 1949 323 - 398

Reamer [73] 1949 311 - 511

31
Virial Coefficients

Bottornley [5]

Kretschmer [53]

Gunn [39]

Dawson [21]

McGlashan [55]

Kapallo [52]

Bre'wer [6]

Strein [93]

Hahn [40]

Warowny [102]

Thomas [95]

Compressibility Data

Sage [81]

Beattie [2]

Burgoyne [7]

Deschner [22]

Cherney [14]

Reamer [73]

Dawson [21]

Dittmar [23]

Kahre [51]

Huang [47]

Tomlinson [98]

Ely [25]

Teichmann [94]

Warowny [102]

Haynes [42]

Thomas [95]

Virial equation (This

report)

APPENDIX D. (Continued)

Date Temperature Range, K 1950 295

1951 303

1958 311 - 510

1960 243 - 348

1962 295 - 413

1963 244 - 321

1967 248 - 298

1970 295 - 493

1974 211 - 493

1978 373 - 423

1982 323 - 523

Date Range of T, K Range of P, MPa

1934 294 378 0.17 - 20.7

1937 369 548 2.4 - 31.0

1940 243 293 0.5 - 6.0

1940 303 609 0.1 - 14.2

1949 323 398 1 .1 5.0

1949 311 511 0.1 - 69.0

1950 243 348 0.05 - 0.18

1962 273 413 1.0 - 103.5

1964 233 350 0,9 - 9.8

1966 173 273 7.0 - 35.0

1971 278 328 1.06 - 13.8

1978 166 324 0.26 - 42.8

1978 323 573 2.77 - 60.9

1978 373 423 0.3 - 6.3

1982 90 300 0.6 - 37.5

1982 258 623 0.6 - 40.0

1982 270 600 0.4 - 1 .0

32
APPENDIX U. ( Conti nued)

specific Heats Date Type Range of T, K Dana [19] 1926 Ca(T) 242 - 292

Sage [80] 1935 C°(T) 294 - 444

Beeck [4] 1936 273 - 573

Sage [82] 1937 Cp(T) 294 - 444

Kemp [53] 1938 Ca(T) 90 - 230

Kistiakovysky, Lacher [54] 1940 Cp°(T) 148 - 258

Kistiakov/sky, Rice [55] 1940 272 - 369

Dailey [18] 1943 CO(T) 335 - 693

Rossini [76] 1947 CO(T) 339 - 422

API 44 [110] 1952 100 - 1000

Cutler [17] 1965 Ca{T) 91 - 105

Yesavage [104,105] 1969 Cp(T,P) 116 - 422

Ernst [26] 1970 Cp(T,P) 293 - 353

Chao [13] 1973 com Spectroscopic

Goodwin [34] 1978 Ca(T) 86 - 360

Goodwin [34] 1978 Cy(T,p) 90 - 337

Heats of Vaporization

Dana [19]

Kemp [53]

Sage [79]

Staveley [91]

Helgeson [46]

Yesavage [104,105]

Carruth [11]

Thermal loops (This report)

Clapeyron equation (This report)

Date Temperature Range, K 1926 234 - 293

1938 231

1939 313 - 348

1950 185 - 213

1967 311 - 330

1969 231 - 367

1970 111 - 237

1982 230

1982 90 - 360

Sound Velocities Date Temperature Range, K Lacam [60] 1956 293 - 498

Rao [72] 1971 140 - 230

Younglove [107] 1981 90 - 300

33
Dielectric C onstants

Sliwinski [39]

Pan [69]

Thompson [96]

Luo [62]

Haynes [42,45]

I

APPENDIX D. (Continued)

Date Temperature Ran ge, K 1969 293 - 370

1975 91 - 115

1980 228 - 230

1981 220 - 289

1982 90 - 300

34
APPENDIX E. Computer Program

PROGRAM PRTHRMB { INPUT , OUTPUT)

C REVISION OF PROPANE THERiMOFUNCTIONS , RDG/NBS, START JAN. 26 , 1981.

COMMON GK,GKK, Bl ,B2 ,83 ,84 ,B5 , C1,C2,C3, E1,E2,E3, ER, IX COMMON/1 /AL , BE , GA , D E , EP , ET , DCRT , TCRT , PORT , DGAT , DTRP , TTRP , PTRP

C0MM0N/3/DPDT,D2P0T2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,D0SDT

C0MM0N/4/XBl,XB2, XC1,XC2, XE1,XE2, DXBDR,DXCDR,DXEDR

COMMON/6/ TSAT, THETA, PSAT

COMMON/8/ IN, IK, P,T,DEN, E,H,S, CV,CP,CSAT, W,WK

COMMON/9/ ONG,EG,HG,SG, CVG,CPG,WG, DPGDT,DPGDD

COMMON/11/ DELS, DELCV

C0MM0N/12/ZCRT,ZCALC,D7DT, ZSAT,DZSDT, ZFX , FRT,DFRTDT

COMMON/21/ TPS{70)

COMMON/95/ PIS, DIS, OPTIS, DPDIS

COMMON/99/ TI,EZZ, EZ,SZ,CVZ, HZ,CPZ

DIMENSION HZA(70), SZA(70), PP(99)

DATA(WM=44. 09721) ,(PA=1. 01325), {GJ=8. 3145)

C NOTE MOL. WT. HERE IS FOR PROPANE.

1 FORMATdS, 2F10.0)

2 F0RMAT(I5, 3F10.0)

3 F0RMAT(8I10)

5 FORMAT(IX)

9 F0RMAT(8F10.0)

14 FORMATdHl 13X * PROPANE ISOBAR AT P =* F10.6, 4H MPA / ) 16 FORMAT{ 9X1HT 8X3HDEN 9X3HDEN 8X1HZ 5X5HDP/DT 5X5HDP/DD

2 8X1HE 8X1HH 8X1HS 6X2HCV 6X2HCP 9X3HF/P 5X1HW 4X5HDIEL. /

3 9X1HK 6X5HM0L/L 7X5HKG/M3 9X 5X5HMPA/K 1X9HMPA-M3/KG

4 4X5HJ/M0L 4X5HJ/M0L 2X7HJ/M0L/K 1X7HJ/M0L/K 1X7HJ/M0L/K

5 12X 1X5HM/SEC 4X5HC0NST ) 17 FORMATdX F9.3, Ell. 4, E12.5, F9.5, F10.6, F10.5,

1 2F9.1, F9.3, 2F8.2, E12.5, 16, F9.5)

20 F0RMAT(lH116XnEST IDEAL FNCTNS*/17X 3HT,K 7X3HHZA 7X3HSZA ) 21 FORMATdOX F10.2, FlO.l, F10.3)

80 CALL PVTDATA

CALL PEEK $ CALL ISOTHRM

C COMPUTE THERMOFUNCTIONS ON ISOBARS. START ON THE MELTING LINE.

C NOTE, ISOBAR P=PCRT OK, BUT ISOTHERM T=TCRT IS EXCLUDED.

C ISOBARS AT P UNDER PORT TRAVERSE THE DOME.

C NOTE USE OF QVAP ,DATA, TO CROSS THE ,DOME,.

C NOTE USE OF CSAT ,DATA, FOR SPECIFIC HEATS IN COMPRESSED LIQUID.

C NOTE TPS(IK) USED BY COMPRES.

C GET FUGACITIES, F/P, VIA H,S, HZ(T),SZ(T). (J.F.ELY).

C SAVE HZA(70), SZA(70) FROM 90 THRU 700 K.

85 DO 86 J=9,70 $ TI = 10*J $ CALL IDEAL $ HZA(J) = HZ

86 SZA(J) = SZ

87 PRINT 20 $ DO 88 J=9,70 $ T = 10*J

88 PRINT 21, T, HZA(J), SZA{J)

89 CALL JTLOCUS $ CALL TABLIQ

90 IN = 1 $ NI = 57 $ READ 9, ( PP( I ) ,1=1 ,NI

)

91 DO 300 I=IN,NI $ IK = I $ LS = 0

92 P = PPd) $ IF(I.EQ.28) P = PCRT

93 PK = P/10 $ PRINT 14, PK $ PRINT 16

100 T = FINDTMF(P) $ CALL COMPRLQ $ V=1/DEN $ IW=W

35
101 Z = P/OEN/GKK/T $ DIE = DIELF(DEH,T,P)

102 TI = T $ CALL IDEAL $ GIB = H-EZZ-HZ - T*(S-SZ)

103 XP = EXP(GIB/GJ/T) $ FOP = XP*PA/P $ CALL COM

104 PRINT 17, T,DEN,DIS,Z, DPTIS,DPOIS, E,H,S,CV,CP, FOP, IW, DIE

105 IT = T/10 $ IF{P.LT.PCRT) 110,180

C CASES FOR P LESS THAN PORT.

110 TPS(IK) = TS = FINOTSF(P) $ l( = L = 0

111 DO 150 J=l,99 $ T = JT = 10*(IT+J)

112 IF(T.LT.TS) 113,117

113 CALL COMPRES $ V = 1/DEN $ IW = W

114 Z = P/DEH/GKK/T $ DIE = DIELF(OEN ,T,P

)

M =JT/10 $ GIB = H-EZZ-HZA(M) - T*{S-SZA(M))

XP = EXP(GIB/GJ/T) $ FOP = XP*PA/P $ CALL CON

115 PRINT 17, T,DEN,DIS,Z, DPTIS,DPDIS, E,H,S,CV,CP, FOP, IW, DIE

116 GO TO 150

117 LS = LS + 1 $ IF(LS.EQ.l) 120,130

C CASE FOR SATURATED LIQUID AND VAPOR.

120 T = TS $ CALL COEXIST $ V=1/DEN $ VG=1/DNG $ IW=W $ IWG=WG

121 Z = P/DEN/GKK/T $ ZG = P/DNG/GKK/T

122 DIEL = OIELF(DEN,T,P) $ DIEG = DIELF(DNG,T,P)

123 TI = T $ CALL IDEAL $ GIB = H-EZZ-HZ - T*{S-SZ)

124 FOP = EXP(GIB/GJ/T)*PA/P $ CALL CON

125 PRINT 17, T,DEN,DIS,Z, DPTIS,DPDIS, E,H,S,CV,CP, FOP, IW, DIEL

126 PRINT 5 $ DIS=ONG*WM $ DPTIS=DPGDT/10 $ DPDIS = DPGDD/IO/WM

127 PRINT 17, T, DNG,DIS,ZG,DPTIS, DPDIS, EG, HG,SG,CVG,CPG, FOP, IWG, DIEG

128 T = JT

C CASES FOR THE HOMOGENEOUS DOMAIN.

130 IF(JT.GT.500) 131,132

131 K = K+1 $ T = JT = JT + 10*K $ IF( JT.GT.700) 300,132

132 CALL GENIUS $ V=1/DEN $ IW=W $ Z = P/DEN/GKK/T

133 IF(T.GT.450) 134,135

134 DIE = 0 $ GO TO 136

135 DIE = DIELF(DEN,T,P)

136 M =JT/10 $ GIB = H-EZZ-HZA(M) - T*(S-SZA(M))

137 XP = EXP(GIB/GJ/T) $ FOP = XP*PA/P $ CALL CON

141 PRINT 17, T,DEN,DIS,Z, DPTIS, DPDIS, E,H,S,CV,CP, FOP, IW, DIE

150 CONTINUE

C FOR P.GE.PCRT, CASES FOR T.LT.OR.T.GT.TCRT.

180 TPS(IK) = TCRT $ K = L = 0

181 DO 250 J=l,99 $ T = JT = 10*(IT+J)

182 IF(T.LT.TCRT) 190,210

C CASE A FOR T LESS THAN TCRT.

190 CALL COMPRES $ V = 1/DEN $ IW = W

191 Z = P/DEN/GKK/T $ DIE = DIELF(DEN,T,P)

192 M =JT/10 $ GIB = H-EZZ-HZA{M) - T*(S-SZA(M))

193 XP = EXP{GIB/GJ/T) $ FOP = XP*PA/P $ CALL CON

194 PRINT 17, T,DEN,DIS,Z, DPTIS, DPDIS, E,H,S,CV,CP, FOP, IW, DIE

195 GO TO 250

C CASE FOR T ABOVE TCRT, HOMOGENEOUS DOMAIN.

210 IF(JT.GT.500) 211,220

211 K = K+1 $ T = JT = JT + 10*K $ IF(JT.GT.700) 300,220

220 CALL GENIUS $ V=1/DEN $ IW=W $ Z = P/DEN/GKK/T

221 IF(T.GT.450) 222,223

222 DIE = 0 $ GO TO 224

36
223 DIE = DIELF(DEN,T,P)

224 M =JT/10 $ GIB = H-EZZ-HZA(M) - T*{S-SZA(M))

225 XP = EXP(GIB/GJ/T) $ FOP = XP*PA/P $ CALL CON

226 PRINT 17, T,DEN,DIS,Z, DPTIS,DPDIS, E,H,S,CV,CP, FOP, IW, DIE

250 CONTINUE

300 CONTINUE

999 STOP $ END

SUBROUTINE COEXIST

C GIVEN T AT COEXISTENCE, GET BOTH VAPOR AND LIQUID FUNCTIONS.

C FOR VAPOR, GET DNG,EG,HG,SG, CVG,CPG,WG, DPGDT,DPGDD, - C FOR LIQUID, GET DEN,E,H,S, CV,CP,CSAT,W. DPDT,DPDD.

C COEXIST CALLED BY COMPRLQ. P NOT USED, MUST NOT CHANGE.

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT,TCRT,PCRT, DGAT,DTRP ,TTRP ,PTRP

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT

COMMON/8/ IN, IK, P,T,DEN, E,H,S, CV,CP,CSAT, W,WK

C0MM0N/9/DNG,EG,HG,SG, CVG,CPG,WG, DPGDT.DPGDD

COMMON/11/ DELS, DELCV

COMMON/99/ TI,EZZ, EZ,SZ,CVZ, HZ,CPZ

DATA (Q=l. 01325) ,(G=0. 083145)

1 FORMATdHO 9X *T EXCEEDS TCRT IN COEXIST. * / ) 2 IF(T.GT.TCRT) 3,4

3 PRINT 1 $ STOP

4 PS = PSATF(T) $ DNG = DB = DENGASF(T)

5 TI = T $ CALL IDEAL $ M=15 $ DA=L=0

6 EG = EZZ + EZ + EDELF(L,M,T,DA,DB) $ HG = EG + 100*PS/0B

7 SG = SZ + DELS - 100*G*AL0G(Gn*DB/Q)

8 IF(T.EQ.TCRT) 9,11

9 PX = PVTF(T,DB,1) $ DPGDT = DPDT $ DPGDD = DPDD

10 CPG = CVG = WG = 0 $ GO TO 15

11 CVG = CVZ + DELCV $ PX = PVTF(T,DB,1)

12 CPG = CVG + 100*T/DPDD*(DPDT/DB)**2 $ WG = SQRT( WK*CPG*DPDD/CVG)

13 DPGDT = DPDT $ DPGDD = DPDD

C NOW TRAVERSE THE ,DOME, USING QVAP ,DATA,.

15 DEN = DL = DENLIQF(T) $ DDLDT = DDSDT $ QV = QVAPXF{T)

16 H = HG - QV $ S = SG - QV/T $ E = H - 100*PS/DL

C THIS RETURN AT 16+ USED ONLY WHEN CALLING SSATFIT, HSATFIT.

17 IF(T.EQ.TCRT) 18,19

18 PX = PVTF(T,DL,1) $ CP=CV=CSAT=W=0 $ RETURN

19 CSAT = CSATXF(T) $ PX = PVTF(T,DL,1)

22 CV = CSAT + 100n*DPDT*DDLDT/DL/DL

23 CP = CV + 100*T/DPDD*(DPDT/DL)**2

30 W = SQRT(WK*CP*DPDD/CV) $ RETURN $ END

SUBROUTINE COMPRES

C SAVES COMPUTER TIME INTEGRATING COMPRLIQ AT T.LT.TCRT.

C FOR T = INTEGER MULTIPLES OF 10 K. FIRST ISOBAR USES COMPRLQ.

C FOR SUCCEEDING ISOBARS, START ON PREVIOUS ISOBAR, EXCEPT - C AT TEMPS GE TPS(IK-l) ON PREVIOUS ISOBAR, MUST USE COMPRLQ.

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT, TCRT, PORT, DGAT,DTRP ,TTRP ,PTRP

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT, DPDD, DPDR,DTSDR,DTHDR, DDSDT

COMMON/8/ IN, IK, P,T,DEN, E,H,S, CV, CP, CSAT, W,WK

37
COMMON/11/ DELS, DELCV

C0W10N/21/ TPS(70)

DIMENSION DK(50) ,EK(50) ,SK(50) ,CK(50)

1 FORMAT (IHO 9X *! G.E. TCRT IN COMPRES. * / ) 2 IF(T.GE.TCRT) 3,4

3 PRINT 1 $ STOP

4 J = T/IO $ IF(T - 10*J) 5,6

5 CALL COMPRLQ $ RETURN

6 IF(IK.EQ.IN) 7,9

7 CALL COMPRLQ

8 DK{J)=DEN S EK(J)=E $ SK(J)=S $ CK{J)=CV $ RETURN

C INTEGRATE FROM OLD DEN TO NEW DEN ON GIVEN ISOTHERM - C EXCEPT IF T EXCEEDS OLD TMAX , USE COMPRLQ.

9 IF(T,GE.TPS{IK-1)) GO TO 7 10 DA=DK(J) $ DK(J) = DEN = DB = FINDENF(T,P) $ N = 13

11 EK(J) = E = EK(J) + EDELF(1,NJ,DA,DB) $ H = E + 100*P/DB

12 SK(J) = S = SK(J) + DELS $ CK(J) = CV = CK(J) + DELCV

C GET NEW DP/DT, DP/DD, CP, W. 15 PX = PVTF(T,DB,1) $ CP = CV + 100*T/DP0D*( DPDT/DB)**2

30 W = SQRT(WK*CP*DPDD/CV) $ RETURN $ END

SUBROUTINE COMPRLQ

C GIVEN P,T FOR COMPR.LIQ. AT T.LT.TC, GET DEN AND FUNCTIONS.

C REVISED TO USE HSATF, SSATF, CSATXF, BUT NOT COEXIST. TIMESAVER.

C INTEGRATE ALONG ISOTHERM T FROM SATLIQ UP TO POINT (P,T).

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT , TCRT , PORT, DGAT ,DTRP ,TTRP ,PTRP

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT

COMMON/8/ IN, IK, P,T,DEN, E,H,S, CV,CP,CSAT, W,WK

COMMON/11/ DELS, DELCV

1 FORHATdHO 9X *T NOT UNDER TCRT IN COMPRLQ.*/)

2 IF(T.GE.TCRT) 3,4

3 PRINT 1 $ STOP

C GET PSAT, DENLIQ, AND SATLIQ FUNCTIONS FOR START.

4 PS = PSATF(T) $ DL = DENLIQF{T) $ DDLDT = DDSDT

6 HS = HSATF(T) $ ES = HS - 100*PS/DL $ SS = SSATF{T)

C . 7 IF(T.GT.340) 8,9

C 8 CVS = CVSATF(T) S GO TO 10

9 PX=PVTF(T,DL,0) $ CVS = CSATXF{T) + 100n*DPDT*DDLDT/DL/DL

C INTEGRATE UP TO POINT (P,T).

10 DB = FINDENF(T,P) $ DX = DB - DL $ IF(DX.GT.O) 11,20

11 M = 14 $ E = ES + EDELF(1,M,T,DL,DB)

12 H = E + 100*P/DB $ S = SS + DELS $ CV = CVS + DELCV

13 PX = PVTF{T,DB,1) $ CP = CV + 100n/DPDD*(DPDT/DB)**2

14 W = SQRT(WK*CP*DPDD/CV) $ DEN = DB $ RETURN

20 DEN=DL $ E=ES $ H=HS $ S=SS $ CV=CVS $ PX = PVTF(T,DL,1)

21 CP = CV + 100*T/DPDD*{DPDT/DL)**2 $ W = SQRT( WK*CP*DPDD/CV

)

30 RETURN $ END

SUBROUTINE CON

C CONVERT TO SI UNITS FOR P, DEN, DP/DT, DP/DD,

C0MM0N/3/DPDT,D2PDT2, DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR, DDSDT

C0MM0N/8/IN,IK, P,T,DEN, E,H,S, CV,CP,CSAT, W,WK

38
COMMON/95/ PIS, DIS, OPTIS, OPOIS

DATA (WM = 44.09721)

1 PIS = P/10 $ DIS = DEN*WM

2 DPTIS = DPDT/10 $ DPDIS = DPDD/IO/WM

9 RETURN $ END

FUNCTION CSATXF(T)

PROPANE, J/MOL/K, RDG, NBS J. RES. 83(5) 449, (1978).

COEFFS, ADJUSTED FOR NEW TCRT = 369.85,

CS = A1*X/(1-X)**E + A2 + A3*X + A4*X2 + A5*X3.

DIMENSION A(5)

DATA (E=0.7) ,(TCRT=369.85)

DATA(A = 6.636737, 80.76732, 8.275839, -19.926887, 51.208621)

1 FORMATdHO 9X *CSATXF, T.GT.TCRT. * / ) 2 IF(TCRT-T) 3,4,5

3 PRINT 1 $ STOP

4 CSATXF =0 $ RETURN

5 X = T/TCRT $ CS = A( 1 )*X/{ 1-X )**E $ DO 6 K=2,5

6 CS = CS + A{K)*X**(K-2) $ CSATXF = CS $ RETURN $ END

FUNCTION CUBER.T(X)

CUBE ROOT MISSING FROM 6600 COMPUTER LIBRARY.

1 E = 1.0/3.0 $ IF(X) 2,3,4

2 CUBERT = -ABS(X)**E $ RETURN

3 CUBERT =0.0 $ RETURN

4 CUBERT = X**E $ RETURN $ END

FUNCTION DELTAF(T,D)

GET (T*DP/DT - D*DP/DD) FOR THE J-T INVERSION CURVE.

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT, TCRT, PORT, DGAT,DTRP,TTRP,PTRP

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT

1 IF(T-TCRT) 2,4,4

2 DL = DENLIQF(T) $ IF(D-DL) 3,3,4

3 DELTAF = l.OE+100 $ RETURN

4 P = PVTF(T,D,1)

5 DELTAF = ABS (T*DPDT-D*DPDD) $ RETURN $ END

FUNCTION DENGASF(T)

PROPANE SAT. VAPOR DEN, MOL/L, (DCRT=5.00), RDG, FEB. 19, 1981.

DESIGNED FOR ZSAT = 1 AT LOW DENSITIES, 5/29/77.

USE ZSAT # PS/DS/GK/TS WITH VAPOR PRESSURES, AND ZCRT.

Z = 1 + (ZCRT-1)*PI*F(X)/X/X, X # T/TCRT, AND - F(X) = 1 + UE*(A1 + A2*X + A3*X2 + . . ), U = (1-X).

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT, TCRT, PORT, DGAT,DTRP ,TTRP ,PTRP

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT

C0MM0N/12/ZCRT,ZCALC,DZDT, ZSAT,DZSDT,ZFX, FRT,DFRTDT

DIMENSION AV(4)

DATA (GKK = 0.083145)

DATA (EG=0.35) ,{NFG=4)

DATA(AV = 5.43973368, -20.0297592, 23.8710761, -10.1051069)

39
1 FORMATdHO 9X *T EXCEEDS TC IN DENGASF. * / ) 2 IF(TCRT-T) 3,4,5

3 PRINT 1 $ STOP

4 DENGASF = DCRT $ ZFX = 1 $ DDSDT = l.OE+100 $ RETURN

5 ZN = ZCRT-1 $ PC = PCRT $ P = PSATF{T)

0 PI = P/PC $ PIT = DPSDT/PC $ TC = TCRT

7 X = T/TC $ X2=X*X $ U - 1-X $ UE=U**EG $ UEl = -EG*UE/U

8 Y = Yl = 0 $ DO 10 K=1,NFG- $ L = K-1 $ XL = X**L

9 Y = Y + AV(K)*XL S Yl = Yl + AV{K)*L*XL/X

10 CONTINUE $ ZFX = F = 1 + UE*Y $ Fl = UE*Y1 + UE1*Y

15 ZCALC = ZSAT = Z = 1 + ZN*PI*F/X2

15 DZSDT = DZDT = ( PI*{ F1-2*F/X ) /TC + F*PIT)*ZN/X2

17 DENGASF = P/T/Z/GKK

18 DDSDT = (DPSDT - P/T - P*DZDT/Z) /T/Z/GKK $ RETURN $ END

FUNCTION DENLIQF(T)

PROPANE SAT. LIQUID DEM, MOL/L, {DCRT=5.00), RDG, FEB. 19, 1981.

DEN = DCRT + YNL*{X + {XE-X)*Y), YNL # DTRP - DCRT.

Y # Al + A2*X + A3*X2 + A4*X3.

C0MM0N/3/DPDT,D2PDT2, DPSDT, DPMDT,DPDD,DPDR,DTSDR,DTHDR, DDSDT

DIMENSION AW(3)

DATA (EL=0.35) ,(NFL=3)

DATA (TTRP=35.47) , { TCRT=369 .85 ) , ( DCRT=5.00) ,{ DTRP=16 .63)

0ATA(AW = 0.764389673, 0.009457047, -0.115001817)

1 FORMATdHO 9X *DENLIQF = 0, T EXCEEDS TCRT. * / )

'

2 IF(TCRT-T) 3,4,5

3 PRINT 1 $ STOP

4 DENLIQF = DCRT $ DDSDT = -l.OE+10 $ RETURN

5 XN=TCRT-TTRP $ X={ TCRT-T) /XN $ X2 = X*X $ DXDT = -1.0/XN

6 XE = X**EL $ U = XE - X $ Ul = EL*XE/X - 1 7Y1=Y=0 $ DO 9 K=1,NFL $ L = K-1 $ XL = X**L

8 Y = Y + AW{K)*XL S Yl = Yl + AW{K)*L*XL/X

9 CONTINUE $ YNL = DTRP - DCRT

11 DENLIQF = DCRT + YNL*{X + U*Y)

12 DDSDT = YNL*{1 + U*Y1 + U1*Y)*DXDT $ RETURN $ END

FUNCTION DIELF(D,T,P)

PROPANE CONSTS., RDG, MARCH 23, 1981, VIA HAYNES DATA.

CM,RMSPCT = 0.048, E,RMSPCT = 0.018.

CM = Al + A2*R + A3*R2 + A4*LN(1+B/X) + A5*PI.

DIMENSION A(5)

DATA (8=1.0) ,{DCRT=5.00) ,(TCRT=369.85)

DATA(A = 15.562631, 0.38581410, -0.15099771,

1 0.51074051, -0.0045141181)

1 R = D/DCRT $ X = T/TCRT $ G = AL0G(1+B/X) $ PI = P/100

2 CM = A(l) + A(2)*R + A(3)*R*R + A(4)*G + A(5)*PI

3 Z = CM*D/1000 $ DIELF = (2*Z+1 ) /{ 1 .0-Z)

5 RETURN $ END

FUNCTION EDELF(L,M,T,DA,DB)

GET CHANGE OF E, S, CV WITH DENSITY ALONG ISOTHERMS.

40
C GET EOELF, DELS, DELCV FROM DA TO DB OM ISOTHERM T.

C ROMBERG NUMERICAL INTEGRATION VIA - C CARNAHAN/LUTHER/WILKES, APPLIED NUMERICAL METHODS, P. 90,

C JOHN WILEY AND SONS, INC., N.Y., 1969.

C NOTE, VALUE OF LD CONTROLS CONVERGENCE LIMITS.

C NOTE, NMAX = M, NK = FINAL, TOTAL SUBDIVISIONS OF INTERVAL DX

.

C0MM0N/1/AL,RE,GA,DE,EP,F.T, DCRT,TCRT,PCRT, DGAT,DTRP,TTRP,PTRP

C0MM0N/3/DPDT ,D2PDT2 , DPSDT , DPMDT ,DPDD ,DPDR ,DTSDR ,DTHDR , DDSDT

COMMON/11/ DELS, DELCV

C0MM0N/12/ZCRT,ZCALC,DZDT, ZSAT,DZSDT, ZFX, FRT,DFRTDT

DIMENSION E(20), S(20), C(20)

DATA (LD=2) ,(01=0.00001) ,(G=0. 083145)

1 F0RMAT{1H09X*EDELF L =*I2,5H, N =13, 5H, T = F8.3,6H, DA =E10.4,

1 6H, DB =E10.4, 6H, LD =12//

2 lOX IHN 7X5HEDELF 8X4HDELS 7X5HDELCV ) 2 FORMATdHO 9X 6HEDIF =F10.3, 8H, SDIF =F10.5, 9H, CVDIF =F10.3)

3 F0RMAT(6X 15, F12.3, F12.5, F12.3)

4 FORMATdHO 9X *EDELF NG AT TCRT FOR CV AT DEN NEAR OR GT CP.*/)

C FOR DA=0 AND DB.LE.DI, IDEAL GAS, EDELF=DELS=DELCV=0

.

C FOR DA=0 AND DB.GT.DI, START ROMBERG WITH DA = DI, - C TO AVOID INFINITIES IN ORDINATE FUNCTIONS AT DA = 0.

5 NK = 1 $ DM = DCRT/2 $ DZ = 0.98*DCRT

9 ZK = 1.0 - 1/ZCRT $ RK = 100*G*TCRT/DCRT

10 IF(L.EQ.O) 11,14

11 IF(DB.LE.DI) 12,13

12 EDELF = DELS = DELCV =0 $ RETURN

13 DA = DI

C GET FIRST TRAPEZOID AREA, E(l) ETC., FROM DA TO DB.

14 DX = DB - DA $ P = PVTF(T,DA,0) $ IF(DA.LT.DM) 16,17

16 EA = RK*(ZK*ZSAT*ZFX + FRT - T*DFRTDT) $ GO TO 18

17 EA = 100*(P-T*DPDT)/DA/DA

18 IF(L.EQ.O) 19,20

19 SA = -RK*DFRTDT $ GO TO 21

20 SA = -100*DPDT/DA/DA

21 CA = -100n*D2PDT2/DA/DA

22 P = PVTF(T,DB,0) $ IF{DB.LT.DM) 23,24

23 EB = RK*( ZK*ZSAT*ZFX + FRT - T*DFRTDT) $ GO TO 25

24 EB = 100*{P-T*DPDT)/DB/DB

25 IF(L.EQ.O) 26,27

26 SB = -RK*DFRTDT $ GO TO 28

27 SB = -100*DPDT/DB/DB

28 CB = -100n*D2PDT2/DB/DB

29 E{l)=(EA+EB)*DX/2 $ S(l)={SA+SB)*DX/2 $ C(l)=(CA+CB)*DX/2

C INTERVAL HALVING, GET E{N+1), ETC.

30 DO 60 N=1,M $ K = N + 1 31 JM = 2**N - 1 $ DXN = DX/2**N $ E(K) = S(!<) = C(K) = 0

33 DO 45 J=1,JM,2 $ NK = NK+1 $ DN = DA + J*DXN

34 P = PVTF(T,DN,0) $ IF(DN.LT.DM) 35,36

35 EB = RK*(ZK*ZSAT*ZFX + FRT - T*DFRTDT) $ GO TO 37

36 EB = 100*(P-T*DPDT)/DN/DN

37 IF(L.EQ.O) 38,39

38 SB = -RK*DFRTDT $ GO TO 40

39 SB = -100*DPDT/DN/DN

40 CB = -100n*D2PDT2/DN/DN

41
41 E{K) = E(K) + EB $ S(!<) = S(K) + SB $ C(K) = C(K) + CB

45 CONTINUE $ E{K) = E(N)/2 + E{K)*DXN

46 S(!<) = S(N)/2 + S(K)*DXIJ $ C(K) = C(N)/2 + C(K)*DXN

TEST FOR CONVERGENCE.

50 ED=ABS(E(K)-E(N)) $ SD=ABS(S(K)-S(N))

53 IF(ED.LT.0.4/LD) 54,60

54 IF(SD.LT.0.002/LD) 55,60

55 IF(T.EO.TCRT.AND.DB.GT.DZ) GO TO 57

56 IF(CD.LT.0.04/LD) 57,60

57 EDELF = E(K) S DELS = S{K) $

60 CONTINUE $ N = M $ NM = N-1

61 PRINT 1, L, N, T, DA, DB, LD

62 PRINT 3, NM,E(NM) ,S(NM) ,C(NM)

64 PRINT 3, NP,E(NP) ,S(NP) ,C(NP)

99 STOP $ END

$ CD=ABS(C(K)-C(N))

DELCV = C(K)

$ NP = N+1

RETURN

PRINT 3, N,E(N),S(N),C(N)

PRINT 2, ED, SD, CD

FUNCTION FINDENF(T,P)

C ON ISOTHERM T, FIND DEN, MOL/L, TO MINIMIZE (P-PC) VIA EQNSTATE.

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT ,TCRT ,PCRT, DGAT ,DTRP ,TTRP ,PTRP

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT

DATA (GKK = 0.083145)

41 FORMATdHO 9X *FINDENF = 0, FAILS TO CONVERGE. * / ) 42 FORMATdHO 9X *FINDENF = DCRT, DP/DR ZERO OR NEG. * / ) 43 FORMATdHO 9X *FINDENF = 0, DOUBLE-VALUED AT P = PSAT. * / ) DM = 1.05*DTRP

IF(P.GT.O) 1,35

1 IF(T-TCRT) 2,5,8

2 DG=DENGASF(T) $ DL=DENLIQF(T) $ PS=PSATF(T) $ IF(P-PS) 3,32,4

3 D = DG/2 $ GO TO 11

4 0= {DL+DTRP)/2 $ GO TO 11

5 DG=DL=DCRT $ PS=PCRT $ IF(P-PS) 6,33,7

6 D = DCRT/2 $ GO TO 11

7 D = 2*DCRT $ GO TO 11

8 IF(T,LT. 450.0) 9,10

9 PC = PVTF{T,DCRT,0) $ IF{P-PC) 6,33,7

10 0 = DCRT

11 DO 30 J=l,50 S DP=P-PVTF{T,D,1) $ IF{ABS (DP/P)-1.0E-7) 31,31,12

12 IF(DPDD.GT.O) 13,34

13 DD = DP/DPDD $ IF{ABS ( DD/D)-1 .OE-7 ) 31,31,14

14 n = D + DD $ IF{D.GT.O.O) 16,15

15 D = P/GKK/T $ GO TO 30

.. 16 IF(D.GT.DM) 17,18

17 D = DM $ GO TO 30

18 IF(T-TCRT) 19,24,30

19 IF(P.LT.PS) 20,22

20 IF(D.GT.DG) 21,30

21 D = DG $ GO TO 30

22 IF(D.LT.DL) 23,30

23 D = DL $ GO TO 30

24 IF{P.LT.PCRT) 25,27

25 IF(D.LT.DCRT) 30,26

26 D = DCRT - 0.02 $ GO TO 30

42
27 IF{D.GT.DCRT) 30,28

28 D = OCRT + 0.02

30 CONTINUE $ PRINT 41 $ STOP

31 FINDENF = D $ RETURN

32 PRINT 43 $ STOP

33 FIMDENF = DCRT $ RETURN

34 FINDENF = DCRT $ PRINT 42 $ RETURN

35 FINDENF=0PDT=D2PDT2=0 $ DPDD=GKK*T $ DPDR=DPDD*DTRP

36 RETURN $ END

FUNCTION FINDTMF{P)

C GIVEN P ON THE MELTING LINE, FIND T FOR PROPANE.

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT,TCRT ,PCRT, DGAT ,DTRP ,TTRP ,PTRP

DATA (A=7180.0) ,(E=1.283)

1 X = (P-PTRP)/A + 1 $ FINDTMF = TTRP*X**(1 .0/E) $ RETURN $ END

FUNCTION FINDTSF(P)

C GIVEN VAPOR PRESSURE P, ITERATE T TO MINIMIZE (P-PC).

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT, TCRT, PORT, DGAT,DTRP ,TTRP ,PTRP

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT

1 FORMATdHO 9X *FINDTSF = 0, FAILS TO CONVERGE. * / ) 2 FORMATdHO 9X *FINDTSF = 0, P EXCEEDS PORT. * / ) 3 IF(P-PCRT) 4,11,12

4 T = 300 $ DO 9 J=l,50 $ DP = P - PSATF(T) $ ADP = ABS (DP)

5 IF(ADP/P-l,0E-7) 10,6,6

6 IF(ADP/DPSDT/T-1.0E-7) 10,7,7

7 T = T + DP/DPSDT $ IF(T-TCRT) 9,9,8

8 T = TCRT

9 CONTINUE $ PRINT 1 $ STOP

10 FINDTSF = T $ RETURN

11 FINDTSF = TCRT $ RETURN

12 PRINT 2 $ STOP $ END

SUBROUTINE GENEOUS

C GIVEN P,T FOR THE HOMOGENEOUS DOMAIN - C GET DEN AND FUNCTIONS AT ANY TEMPERATURE.

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,D0SDT

COMMON/8/ IN, IK, P,T,0EN, E,H,S, CV,CP,CSAT, W,WK

COMMON/11/ DELS, DELCV

COMMON/99/ TI,EZZ, EZ,SZ,CVZ, HZ,CPZ

DATA (0=1.01325) ,(G=0. 083145)

3 TI = T $ CALL IDEAL $ IF(P.GT.O) 4,10

4 DEN = DB = FINDENF{T,P) $ M=15 $ DA=L=0

5 E = EZZ + EZ + EnELF(L,M,T,DA,DB) $ H = E + 100*P/DB

6 S = SZ + DELS - 100*G*AL0G(G*T*DB/Q)

7 CV = CVZ + DELCV $ PX = PVTF(T,DB,1)

8 CP = CV + 100n/DPDD*(DPDT/DB)**2

9 W = SQRT(WK*CP*DPDD/CV) $ RETURN

10 DEN=S=0 $ E = EZZ + EZ $ H = E + 100*Gn $ CV=CVZ $ CP=CPZ

12 W = SQRT{WK*CP*G*T/CV) $ RETURN $ END

43
SUBROUTINE GENIUS

C VALID ONLY FOR THE HOMOGENEOUS [30MAIN.

C SAVES COMPUTER TIME WHEN TABULATING FUNCTIONS ALONG ISOBARS.

C SAVES D£N,E,S,CV ALONG ISOBARS FOR USE IN INTEGRATING TO NEXT

C HIGHER ISOBAR. VALID ONLY FOR MONOTONICALLY INCREASING ISOBAR

C PRESSURES, AND AT TEMPS. T = INTEGER MULTIPLES OF 10 K. C0MM0N/3/DPDT,D2PDT;?,DPSDT,DPMDT,DPDD,DPDR,0TSDR,DTHDR,DDSDT

COMMON/8/ IN, IK, P,T,DEN, E,H,S, CV,CP,CSAT, W,WK

COMMON/11/ DELS, DELCV

DIMENSION DK(70) ,EK(70) ,S:<(70) ,CK(70)

1 FORMATdHO 9X *GENIUS T NOT INTEGRAL. * / ) 2 J = T/10 $ IF(T - 10*J) 3,4

3 CALL GENEOUS $ RETURN

4 IF(IK.EQ.IN) 5,9

5 CALL GENEOUS

6 OK(J) = DEN $ EK(J) = E $ SK(J) = S $ CK(J)=CV $ RETURN

C INTEGRATE FROM OLD DEN UP TO NEW DEN ON GIVEN ISOTHERM.

9 DA = DK(J) $ OK{J) = DEN = DB = FINDENF(T,P) $ N = 14

11 E1({J) = E = EK(J) + EDELF(1,N,T,DA,DB) $ H = E + 100*P/DB

13 SK{J) = S = SK(J) + DELS $ CK(J) = CV = CK{J) + DELCV

C NOW GET NEW DP/DT, DP/OD, CP, W.

15 PX = PVTF(T,DB,1) $ CP = CV + 100*T/DPDD*(DPDT/0B)**2

30 W = SQRT(lfK*C?*DPDD/CV) $ RETURN $ END

FUNCTION HSATF(T)

C PROPANE SATLIQ ENTHALPY, J/MOL.

C DEFINE YH # (H-HC) /( HT-HC) , X # (TC-T)/{TC-TT) , WHEN - C YH = X + (XE-X)*(A1 + A2*X + A3*X2 + . . .)

DIMENSION AH(7)

DATA (NFH=7) ,(EH=0.37) ,(TTRP=85.47) ,(TCRT=369.85)

DATA (HTRP = 0.001),(HCRT = 33082.187)

DATA(AH = 0.2998573044, 0.3868586865, -0.6240978276,

1 1.036003301, -0.9494397054, 0.1462986734, 0.1113755135)

1 FORMATdHO 9X 3HT =F10.5, * IN HSATF{T).*/)

2 IF(T.GT.TCRT) 3,4

3 PRINT 1, T $ STOP

4 X = (TCRT-T)/(TCRT-TTRP) $ IF(X.LE.O) 5,5

5 HSATF = HCRT $ RETURN

5 V = X**EH -X $ FX=X $ DO 7 K=1,NFH

7 FX = FX + V*AH(K)*X**(K-1)

8 HSATF = HCRT - (HCRT-HTRP)*FX $ RETURN $ END

SUBROUTINE IDEAL

C PROPANE IDEAL GAS (1 ATM) THERMOFUNCTIONS VIA CHAO (1973).

C (HZ-HZZ)/RT = 4.0 + (A + B/Q + C/Q2 + D/X)*EXP(-E/X) , WHERE - C X # T/lOO, Q # CUBERT(X).

COMMON/99/ TI, EZZ, EZ,SZ,CVZ, HZ,CPZ

DIMENSION A(6)

DATA (E=3.0) ,(R=8. 31434) ,(SI=32. 552)

DATA(A = 24.11012, 94.40550, -585.32814,

1 980.124065, -678.64094, 170.42778)

1 X=TI/100 $ Q=CUBERT(X) $ DQDX=Q/3/X $ XP=EXP(-E/X)

2 H = 4.0 $ SUM = SMI =0 S DO 7 K=l,6

44
3 H = H + A(K)*XP*Q**(1-K) $ L = 4-K $ QL = Q**L

4 SUM = SUM + A(K)*QL $ SMI = SMI + A(K)*L*QL*DQDX/Q

7 CONTINUE $ CP = 4.0 + {E*SUM/X/X + SM1)*XP

C S = S(300) + INTEGRAL(CD/X)*DX FROM T=300 UP TO TI

.

10 N = ABS(TI-300)/4 +4 $ DX = (X-3)/N $ S = SI

12 DO 20 J=1,H $ X = 3.0 + (J-0.5)*DX $ Q = CUBERT{X)

14 DQDX = Q/3/X $ XP = EXP(-E/X) $ SUM = SMI = 0

15 DO 19 K=l,6 $ L=4-K $ QL= Q**L

16 SUM = SUM + A(K)*QL $ SMI = SMI + A(K )*L*QL*DQDX/Q

19 CONTINUE $ CPX = 4.0 + (E*SUM/X/X + SM1)*XP

20 S = S + CPX*DX/X

C CONVERT TO DIMENSIONED RESULTS, JOULES, MOLES, KELVINS.

22 CPZ = R*CP $ SZ = R*S $ HZ = R*TI*H

23 CVZ = CPZ - R $ EZ = HZ - Rni $ RETURN $ END

SUBROUTINE ISOTHRM

C PRINTOUT THE CRITICAL ISOTHERM.

C0MM0N/1/AL,BE,GA,DE,EP,ET, OCRT,TCRT,PCRT, DGAT,DTRP,TTRP,PTRP

C0MM0N/3/DPDT,n2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT

C0MM0N/4/XBl,XB2, XC1,XC2, XE1,XE2, DXBDR,DXCDR,DXEDR

COMMON/6/ TSAT, THETA, PSAT

DATA (WM = 44.09721)

1 FORMATdHl 14X *THE CRITICAL ISOTHERM, PROPANE* //

1 6X6HTC,K = F7.2, 12H, DC,KG/M3 = F9.4, lOH, PC,MPA = F10.7/ 6X

2 *AT THE CP., DPS/DT =*F9.6, 9H, OP/DT =F9.6, * MPA/K.* //

3 6X4HD/DC 9X5HTS/TC 9X5HPS/PC 10X4HP/PC 9X5HDP/DR 4X6HDTS/DR

4 4X6H0TH/DR 4X6HDPS/DR 4X6HDXB/DR 4X6HDXC/DR ) 2 F0RMAT(2X F8.3, 3F14.10, F14.9, 5F10.5)

3 PC = PVTF(TCRT,DCRT,0) $ PCS = PCRT/10 $ DCS = DCRT*WM

DPST = DPSDT/10 $ DPT = DPDT/10

4 PRINT 1, TCRT, DCS, PCS, DPST, DPT $ DO 8 J=l,41

5 DR = 0.895 + 0.005*J $ DN = DR*DCRT

6 PR = PVTF(TCRT,DN,1)/PCRT $ DPSDR = DPSDT*DTSDR

7 TSN = TSAT/TCRT $ PSN = PSAT/PCRT

DPDR = DPDR/10 $ DPSDR = DPSDR/10

8 PRINT 2, DR, TSN, PSN, PR, DPDR, DTSDR ,DTHDR , DPSDR, DXBDR,DXEDR

9 RETURN $ END

SUBROUTINE JTLOCUS

C THE JOULE-THOMSON P-V-T LOCUS FOR PROPANE.

C DERIVE THE J-T INVERSION CURVE. USE ROUTINE DELTAF( T ,DI )

.

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT, TCRT, PORT, DGAT,DTRP,TTRP,PTRP

DIMENSION DK(60) ,DN{60) ,TT(60) ,PP(60)

DATA {A=2. 77755) ,( 8=0.60625) ,( TZ=500 .0) ,( WM=44 .09721

)

1 FORMATdHl 16X nHE JOULE-THOMSON INVERSION LOCUS FOR PROPANE* //

2 17X 3HT,K 8X2HDI 5X5HKG/M3 5X5HP,MPA

3 7X 3HT,K 8X2HDI 5X5HKG/M3 5X5HP,MPA ) 2 FORMATCIOX 110, 2F10.1, F10.3, 110, 2F10.1, F10.3)

C SAVE INITIAL, TRIAL DENSITY, DK(I) = DI.

5 TA = 290 $ NP = 52

6 PRINT 1 $ DO 25 1=1, NP $ DX = 0.8

7 T = TA + 10*1 $ U = T/TZ S DK(I) = DI = EXP(A-B*U)

45
10 IF(T-TCRT) 11,12,12

11 iU = DENLIQFd) $ IF(DI.LT.DL) 23,12

12 SS = DELTAF(T,DI) $ DO 20 IT=1,14

14 D=DI-DX $ SL=DELTAF(T,D) $ D=DI+OX S SP=DELTAF(T,D)

15 IF(SS-SL) 18,16,16

16 IF(SP-SL) 19,17,17

17 SS = SL $ DI = DI - OX $ GO TO 20

18 IF(SS-SP) 20,20,19

$

19 SS = SP $

20 DX = DX/2

21 GO TO 25

23 TT(I) = T

25 CONTINUE

26 DO 35 J=1,N

27 IT = TT{J) S

28 DKJ = WM*DK(J)

29 DKK - WM*DK{K)

30 PPJ = PP{J)/10

35 PRINT 2

40 RETURN

DI = DI

TT(I)

DX

T $ ON(I) = DI S ?P(I) = PVTF(T,DI,0)

DK(I) = DN{I) = PP(I) = 0

N = NP/2

$ K = J + N ITT = TT(K)

$ DMJ = WM*DN{J)

$ DNK = WM*DN{K)

$ PPK = PP(K)/10

IT, DKJ,DNJ, PPJ, ITT, DKK, DNK, PPK

$ END

SUBROUTINE PEEK

EXAMINE BEHAVIOR OF THE PVT COEFFICIENTS,

B(S) # Bl + B2*S2, E(S) # El*( S-1)*(S-ER)*EXP(-GA*S**IX)

.

WHERE, R # DEN/DTRP, S # DEN/DCRT.

COMMON GK,GKK, Bl ,B2,B3,B4,B5, C1,C2,C3, E1,E2,E3, ER,IX

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT,TCRT,PCRT, DGAT ,DTRP ,TTRP ,PTRP

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT

COMMON/6/ TSAT, THETA, PSAT

DATA (WM = 44.09721) , (EX = 1.10)

4 FORMATdHl 14X ^EQUATION OF STATE COEFFS., PROPANE * //

1 15X 6HTTRP =F7.3, 8H, TBLP =F9.4, 8H, TCRT =F8.3, * K* /

2 15X 6HPTRP =E12.6, 8H, PBLP =F8.6, 8H, PORT =F9.6, * MPA* /

3 15X 6HDTRP =E11.5, 8H, DLBP =E11.5, 8H, DCRT =E11.5, * KG/M3* /

3 15X 6HDGAT =E11.5, 8H, DGBP =E11.5, * KG/M3* /

3 15X *DPS/DTB,MPA/K =* Ell. 5, QVAPB,KJ/MOL =* F7.3//

4 15X 4HIX =12, 6H, EX =F5.2, 6H, ER =F5.2, *, S # DEN/DCRT* /

5 15X 4HAL =F10.7, 6H, BE =F10.7, 6H, GA =F10.7/

6 15X 4HDE =F10,7, 6H, EP =F10.7, 6H, ET =F10.7//

7 15X 4HB1 =F14.11, 6H, B2 =F14.11, 6H, B3 =F14.11/

8 15X 4HC1 =F14.11, 6H, C2 =F14.11, 6H, C3 =F14.11/ ) 5 FORMATdSX 4HD/DC 6X4HTSAT 5X5HTHETA 4X6HPS,MPA 9X1HB 9X1HC ) 6 F0RMAT(9X F10.2, 2F10.3, F10.4, 2F10.5)

8 TB=FINDTSF(1. 01325) $ DGB=DENGASF( TB) $ DLB=DENLIQF( TB)

9 QB = TB*DPSDT*(1/DGB - 1/DLB)/10.0

PTR = PTRP/10 $ PBLP = 0.101325 $ PCR = PCRT/10

DTR = DTRP*WM $ OLBI = DLB*WM $ OCR = DCRT*WM

DGA = DGAT*WM $ DGBI = DGB*WM $ DPSB = DPSDT/10

10 PRINT 4, TTRP,TB, TCRT, PTR, PBLP, PCR, DTR, DLBI,DCR, DGA, DGBI, DPSB, QB,

1 IX,EX,ER, AL,BE,GA,DE,EP,ET, B1,B2,B3, E1,E2,E3

11 PRINT 5 $ N = 10*DTRP/DCRT + 1 12 DO 20 J=1,N $ S = 0.1*J

13 DN = S*DCRT $ S2=S*S $ SN=S-1 $ SX = S**IX

46
14 SR = 1 $ IF(ER.GT.O) SR = S-ER

16 B = Bl + B2*S2

17 E = (El + E2*S)*SN*5R*EXP(-GA*SX)

19 TSAT=TS=TSATF{ON) $ TH=THETAF{ DN) $ PS=PSATF(TS) $ PIS=PS/10

20 PRINT 6, S, TS,TH,PIS, B,E $ RETURN $ END

FUNCTION PMELTF(T)

C PROPANE MELTING LINE, BAR, VIA REEVES, SCOTT, AND BABB(JR),

C J. CHEM. PHYS. 40(12), 3662 (1964).

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT,TCRT,PCRT, DGAT ,DTRP ,TTRP ,PTRP

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT

DATA (A = 7180.0) ,(E = 1.283)

1 X = T/TTRP $ XE = X**E $ PMELTF = PTRP + A*(XE-1)

2 DPMDT = A*E*XE/X/TTRP $ RETURN $ END

FUNCTION PSATF(T)

C PROPANE VAPOR PRESSURE, BAR, RDG, FEB. 19, 1981. (DCRT=5.00).

C LN{P) = Pl/X + P2 + P3*X + P4*X2 + P5*X3 + P6*(1-X)**EPP.

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,D0SDT

DIMENSION PJ(6)

DATA (EPP = 1.35)

DATA ( TTRP=85 .47 ) , ( TCRT=369 .85 ) , ( DCRT=5 .00) , ( DTRP=16 .63

)

DATA(PJ = -8.722780250, 19.203078280, -15.610638913,

1 12.685790059, -3.806542924, 1.883214505)

1 FORMATdHO 9X *T ABOVE TCRT IN PSATF(T). * / ) 4 X = T/TCRT $ V = 1.0 - X $ IF(V) 7,8,9

7 PRINT 1 $ STOP

8 Z = Zl = 0 $ GO TO 10

9 Z = V**EPP $ Zl = -EPP*Z/V

10 PL = PJ(6)*Z $ PLl = PJ(6)*Z1

11 DO 13 K=l,5 $ L = K-2 $ XL = X**L

12 PL = PL + PJ(K)*XL $ PLl = PLl + PJ(K)*L*XL/X

13 CONTINUE $ PSATF = EXP(PL)

15 DPSDT = PL1*PSATF/TCRT $ RETURN $ END

SUBROUTINE PVTDATA

C PROPANE EOS CONSTANTS, RDG/NBS, FEB. 19, 1981. (DCRT=5.00).

COMMON GK,GKK, Bl ,B2 ,B3 ,B4 ,B5 , C1,C2,C3, E1,E2,E3, ER, IX C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT, TCRT, PORT, DGAT, DTRP,TTRP, PTRP

COMMON/8/ IN, IK, P,T,DEN, E,H,S, CV,CP,CSAT, W,WK

C0MM0N/12/ZCRT,ZCALC,DZDT, ZSAT,DZSDT, ZFX, FRT,DFRTDT

COMMON/99/ TI,EZZ, EZ,SZ,CVZ, HZ,CPZ

10 WM = 44.09721 $ TTRP = 85.47 $ TCRT = 369.85

12 DCRT = 5.000 $ DTRP = 16.630

13 PTRP = PSATF(TTRP) $ PORT = PSATF(TCRT)

20 GKK = 0.083145 $ GK = GKK*DCRT $ ZCRT = PCRT/DCRT/GKK/TCRT

21 IX = 2 $ AL = 1.0 $ BE = 0.7 $ GA = 0.15 $ DE = 0

22 EP = 0 $ ER = 2.20 $ ET = 1.1

23 Bl = 0.45650524198 $ B2 = 0.15822653715

24 El =-0.24904576736 $ B3=B4=E2=E3=0

25 DGAT = DENGASF(TTRP) $ WK = 100000/WM $ EZZ = 21888.910

47
99 RETURN $ END

FUNCTION PVTF(T,D,M)

PROPANE EQNSTATE, PVTF = P,BAR. SIMPLIFIED, FEB. 12, 1931.

NOTE, M=0 RETURNS DP/DT, D2P/DT2. n=l RETURNS ALSO DP/DD.

P-PSAT = S*GK*(T-TSAT) + S*S*GK*TCRT*F( S ,T) , WHERE - F{S,T) # B(S)*XBF(S,T) + £( S)*XEF( S ,T) , AND - B(S) # Bl + B2*S2, E{S) # El*( S-1 )*{ S-ER)*EXP( -GA*S**IX)

.

WHERE, R # DEN/DTRP, S # DEN/DCRT.

COMMON GK,GKK, Bl ,B2,B3,B4,B5 , C1,C2,C3, E1,E2,E3, ER,IX

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT,TCRT,PCRT, DGAT ,DTRP ,TTRP ,PTRP

C0MM0N/3/DP0T,D2PDT2,0PSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDS0T

C0MM0N/4/XBl,XB2, XC1,XC2, XE1,XE2, DXBDR ,DXCDR ,DXEDR

COMMON/6/ TSAT, THETA, PSAT

C0MM0N/12/ZCRT,ZCALC,0ZDT, ZSAT,DZSDT,ZFX , FRT,DFRTDT

1 S = 0/DCRT $ S2=S*S $ SN=S-1 $ SR=S-ER $ SX=S**IX

5 GK = DCRT*Gi<K $ TC = TCRT $ DSDR = DTRP/DCRT

6 RG = S*GK $ GKT = GK*TC

7 TSAT=TS=TSATF{D) $ PSAT=PS=PSATF( TS) $ THETA=THETAF(D)

8 XB = XBF(T,D) $ XE = XEF{T,D)

9 B = B1*S2 + B2*S2*S2

10 XP = EXP(-GA*SX) $ SM = S2*SN*SR $ E = E1*SM*XP

12 F = B*XB + E*XE $ Fl = B*XB1 + E*XE1 $ F2 = B*XB2 + E*XE2

13 PVTF = PS + RG*(T-TS) + GKT*F $ FRT=F/S2 $ DFRT0T=F1/S2/TC

14 DPDT = RG + G!<*F1 $ D2PDT2 = GK*F2/TC $ IF(M) 15,30

15 BD = (2*B1 + 4*B2*S2)*S*DSDR

16 XPl = -IX*GA*SX/S $ SMI = (SN+SR)*S2 + 2*S*SN*SR

18 ED = E1*(SM*XP1 + SM1)*XP*DSDR

20 Fl = B*DXBDR + BD*XB + E*DXEDR + ED*XE

26 DPDR = {DPSDT"RG)*DTSDR + (T-TS)*GK*DSDR + GI<T*F1

27 DPDD = DPDR/DTRP

30 RETURN $ END

FUNCTION QVAPXF{T)

PROPANE QVAP, J/MOL, RDG/NBS, FEB. 20, 1981.

QVAP = A1*X + (XE-X)*(A2 + A3*X + A4*X2 + . . ). X # {TC-T)/(TC-TT), XE # X**E.

DIMENSION AQ(4)

DATA (NFQ=4) ,(EQ=0.38) ,(TTRP=85.47) ,(TCRT=369.85)

DATA(AQ = 24.840848, 24.166535, 6.252384, -12.156857)

1 FORMATdHO 9X *1 EXCEEDS TCRT IN QVAPXF(T). * / ) 2 IF(TCRT-T) 3,4,5

3 PRINT 1 $ STOP

4 QVAPXF = 0 $ RETURN

5 XN = TCRT - TTRP $ X = (TCRT-T)/XN $ XE = X**EQ

6 F = 0 $ DO 7 K=2,NFQ

7 F = F + AQ(K)*X**{K-2) $ Q = AQ(1)*X + (XE-X)*F

10 QVAPXF = g*1000 $ RETURN $ END

SUBROUTINE SIMPLE

FOR ANY GIVEN T,K AND P,MPA, CONVERT TO P,BAR, AND USE SUBROUTINE

48
C THERMO (OR ENTRIES THEREIM) TO GET THERMOPHYSICAL PROPERTIES.

C THEN CONVERT TO MPA, AND KG/M3 IN PRESENT ROUTINE.

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT, DPDD ,DPDR ,DTSDR,DTHDR,DDSnT

COMMON/8/ IN, IK, P,T,DEN, E,H,S, CV,CP,CSAT, W,WK

COMMON/99/ TI,EZZ, EZ,SZ,CVZ, HZ,CPZ

DATA (R=0. 083145) ,(GJ=8. 3145) ,(PA=1. 01325) ,(WM=44. 09721)

14 FORMATdHl 18X *TEST OF THERMO AT P,MPA =* F8.5/

1 19X ^DENSITIES KG/M3, HEATS J/MOL. * / ) 16 F0RMAT{6X4HPMPA 9X1HT 6X3HDEN 8X1HZ 5X5HDP/DT 5X5HDP/DD

1 8X1HE 8X1HH 8X1HS 6X2HCV 6X2HCP 5X1HW 9X3HF/P 5X4HDIEL ) 17 FORMATdX F9.4, F10.3, F9.2, F9.5, F10.5, F10.6, 2F9.1, F9.3,

1 2F8.2, 16, E12.5, F9.5)

C LET US EXAMINE A SUBCRITICAL ISOBAR.

19 PMPA = 3.5

20 P = 10*PMPA $ PRINT 14, PMPA $ PRINT 16

21 DO 90 J=l,39 $ TIK = T = 110 + 10*J

22 CALL THERMO $ IW = W $ Z = P/OEN/R/T

C GET DIEL. CONST., AND FUGACITIES.

25 GIB = H-EZZ-HZ -T*{S-SZ) $ FOP = EXP(GIB/GJ/T)'*^PA/P

26 IF(T.GT.450) 27,28

27 DIE = 0 $ GO TO 30

28 DIE = DIELF(DEN,T,P)

C CONVERT PRESSURES, DENSITIES, AND DERIVATIVES.

30 PMPA=P/10 $ DEN=DEN*WM $ DPDT=DPDT/10 $ DPDD=DPDD/10/WM

31 DPMDT = DPMDT/10 $ DPSDT = DPSDT/10 $ DDSDT = DDSDT*WM

40 PRINT 17, PMPA, T, DEN, Z, DPDT,DP0D, E,H,S, CV,CP,IW, FOP, DIE

90 CONTINUE $ RETURN $ END

FUNCTION SSATF(T)

C PROPANE SATLIQ ENTROPY, J/MOL/K.

C CONSTRAINED AT TRIPLE AND CRITICAL POINTS.

C Y # (S-SCRT)/(STRP-SCRT), X # (TC-T)/( TC-TT)

.

C Y = X + (XE-X)*(A1 + A2*X + A3*X2 + . . . ).

DIMENSION AS(8)

DATA (NFS=8) ,(ES=0.32) ,( TTRP=85.47) , ( TCRT=369 .85)

DATA (STRP = 82.56147) , (SORT = 234.72617)

DATA(AS = 0.1263077082, -0.7539546213, 1.253270427, -5.96961033,

1 14.0277688, -20.62894506, 16.01178434, -5.411082748)

1 FORMATdHO 9X 3HT =F10.5, * IN SSATF(T). * / ) 2 IF(TCRT-T) 3,4,5

3 PRINT 1, T $ STOP

4 SSATF = SORT $ RETURN

5 YN = STRP-SCRT $ XN = TCRT-TTRP

. 6 X = (TCRT-T)/XN $ XE = X**ES $ V = XE - X

7 Y = X $ DO 8 K=1,NFS

8 Y = Y + V*AS(K)*X**{K-1)

9 SSATF = SORT + YN*Y $ RETURN $ END

SUBROUTINE TABLIQ

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT,TCRT,PCRT, DGAT,DTRP ,TTRP ,PTRP

C0MM0N/3/DPDT,D2PDT2, DPSDT, DPMDT, DPDD, DPDR,DTSDR,DTHDR, DDSDT

COMMON/6/ TSAT, THETA, PSAT

49
COMKiON/8/ IN, IK, P,T,DEN, F.,H,S, CV,CP,CSAT, W,WK

C0MM0N/9/DNG,EG,HG,SG, CVG,CPG,WG, DPGDT,DPGDD

C0MM0M/12/ZCRT,ZCALC,DZDT, ZSAT,DZSDT,ZFX , FRT,DFRTDT

COMMON/99/ TI,EZZ, EZ,SZ,CVZ, HZ,CPZ

DIHEMSION DSA(60) ,TSA(60) ,PSA(60) ,DLT(60) ,DPT(60) ,DP0(60)

DATA ( G=0. 083145) ,(WM=44. 09721)

-. 4 FORMATdHl 13X ^PROPERTIES OF SATURATED LIQUID PROPANE* //

1 14X IHT IIXIHP 3X5HDEN,L 7X5HDEN,G 5X3HZ,L 5X3HZ,G

?. 5X6HDPS/DT 3X6HDDL/DT 3X5HDP/DT 6X5HDP/DD /

3 14X IHK 9X3HMPA 3X5HKG/M3 7X5HKG/M3 16X

4 5X5HMPA/K 2X7HKG/M3/K 3X5HMPA/K 2X9HMPA-M3/KG ) 5 F0RMAT{5XF10.3, E12.5, F8.2, E12.5, 2F8.5, E11.4,F9.4,F8.4,E11 .4)

11 FORMATdHl 13X ^PROPERTIES OF SATURATED LIQUID PROPANE * //

1 14X IHT 4X5HQ,VAP 8X1HE 8X1HH 8X1HS

2 6X2HCV 6X2HCS 6X2HCP 6X3HF/P 6X1HW 4X5HDIEL. /

3 14X IHK 4X5HJ/M0L 4X5HJ/M0L 4X5HJ/M0L 2X7HJ/M0L/K

4 1X7HJ/M0L/K 1X7HJ/M0L/K 1X7HJ/MQL/K IIX 5HM/SEC 4X5HC0NST ) 12 F0RMAT(5X F10.3, 3F9.1, F9.3, 3F8.2, F9.5, 17, F9.5)

C FOR PAGE ONE OF TABLIQ.

C REPLACE T = 230 BY B.P. AT J = 30.

120 NP = 58 $ PRINT 4

121 DO 150 J=1,NP $ IF(J.EQ.l) 122,123

122 T = TTRP $ GO TO 139

123 IF(J.EQ.30) 124,125

124 T = FIN0TSF( 1.01325) $ GO TO 139

125 IF(J.EQ.NP) 126,128

126 T = TCRT $ DSA(J)=DG=DL=DCRT $ DLT{J) = DDLDT = 0

127 VG = VL = 1.0/DCRT $ ZG = ZCRT $ GO TO 141

128 T = 80 + 5*J

139 DSA(J) = DL = DENLIQF(T) $ DLT(J) = DDLDT = DDSDT

140 DG = DENGASF(T) $ ZG = ZSAT $ VG = 1/DG $ VL = 1/DL

141 TSA(J) = T $ PX = PVTF(T,DL,1) $ DPT(J)=DPDT $ DPD{J)=DPDD

147 PSA(J) = PS = PSAT $ Z = PS/DL/G/T

148 PS=PS/10 $ DPSDT=DPSDT/10 $ DPDT=DPDT/10 $ DPDD=DPD0/10

149 DL=DL*WM $ DG=DG*WM $ DDLDT=DDLDT*WM $ DPDD = DPDD/WM

150 PRINT 5, T,PS, DL,DG, Z,ZG, DPSDT, DDLDT, DPDT,DPDD

C PAGE 2, TABLIQ. AVOID COEXIST, TIMESAVER.

C USE COEXIST AT ALL TEMPERATURES.

150 PRINT 11 $ DO 180 J=1,NP $ T = TSA(J) $ P = PSA(J)

161 CALL COEXIST $ DL = DEN $ IV/ = W

162 DIEL = DIELF{DL,T,P) $ QX = QVAPXF(T)

C GET FUGACITY COEF., (F/P), VIA HZ, SZ, HG, SG.

C NOTE, 01 = 0.00001 MOL/L IN EDELF.

170 GIBS = HG-EZZ-HZ - T*(SG-SZ)

171 GJ = 100*G $ XP = EXP(GIBS/GJ/T) $ FOP = XPn.01325/P

172 IF(DNG.LE. 0.00001) FOP = 1.0

180 PRINT 12, T,QX, E,H,S, CV,CSAT,CP, FOP, IW, DIEL

999 RETURN $ END

C

c

c

SUBROUTINE THERMO

FOR COMPUTATION AT ANY (T,P) POINT.

ASSUMES AN ISOTHERM IH SINGLE-PHASE ONLY.

CASES FOR ISOTHERMS BELOW, EQ., ABOVE TCRT.

50
C GIVEN (T,P), RETURNS DEN, E,H,S, CV,CP,W, DPDT, DPOD.

C ENTRIES BELOW FOR PHASE BOUNDARIES ASSUME A GIVEN ISOBAR P, OR - C ENTRIES BELOW FOR PHASE BOUNDARIES ASSUME A GIVEN ISOTHERM, T. COMMON/l/AL ,BE ,GA,nE ,EP ,ET, DCRT , TCRT ,PCRT, DGAT ,DTRP ,TTRP ,PTRP

C0MM0H/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT

COMMON/8/ IN, IK, P,T,DEN, E,H,S, CV,CP,CSAT. W,WK

COMMOH/9/ ONG,EG,HG,SG, CVG,CPG,WG, OPGDT,DPGDD

COMMON/99/ TI,EZZ, EZ,SZ,CVZ, HZ,CPZ

1 FORMAT! IHO 9X ^THERMO, P.GE.PMELT. * / ) 2 FORMATdHO 9X *THERMO DOUBLE-VALUED AT P = PSAT. * / ) 3 FORMATdHO 9X *THERMO, DEN GE. DCRT AT T = TCRT. * / ) 10 IF{T-TCRT) 11,20,25

C SUBCRITICAL ISOTHERMS.

11 PM = PMELTF(T) $ IF(P.GE.PM) 12,13

12 PRINT 1 $ CALL COMPRLQ $ TI=T $ CALL IDEAL $ RETURN

13 PS = PSATF(T) $ IF(P-PS) 14,15,16

14 CALL GENEOUS $ RETURN

15 PRINT 2 $ RETURN

16 CALL COMPRLQ $ TI = T $ CALL IDEAL $ RETURN

C THE CRITICAL ISOTHERM.

20 CALL GENEOUS $ IF(DEN.LT.DCRT) RETURN

21 CP = CV = W = 0 $ PRINT 3 $ RETURN

C ISOTHERMS AT T ABOVE TCRT.

25 CALL GENEOUS $ RETURN

C THERMOM FOR GIVEN ISOBAR AT THE MELTING LINE, GET T. C RETURNS T,DEN, E,H,S, CV,CP,W, DPMDT,DPDT,DPDD.

ENTRY THERMOM

40 T = FINDTMF(P) $ PM = PMELTF(T) $ CALL COMPRLQ

41 TI = T $ CALL IDEAL $ RETURN

C THERMOL FOR GIVEN ISOBAR AT SATURATED LIQUID LINE, GET T. C RETURNS T,DEN, E,H,S, CV ,CP ,CSAT ,W, DPSDT,DDSDT, DPDT,DPDD.

ENTRY THERMOL

43 T = FINDTSF{P) $ CALL COEXIST $ RETURN

C THERMOV FOR GIVEN ISOBAR AT THE SATURATED VAPOR LINE, GET T.

C RETURNS T,DEN, E,H,S, CV,CP,W, DPSDT,DDSDT, DPDT,DPDD.

ENTRY THERMOV

45 T = FINDTSF(P) $ CALL COEXIST $ DEN=DNG $ E=EG $ H=HG $ S=SG

47 CV=CVG $ CP=CPG $ W=WG $ DPDT=DPGDT $ DPDD=DPGDD $ RETURN

C THRMM FOR ISOTHERM AT THE MELTING LINE, GET P. C RETURNS P,DEN, E,H,S, CV,CP,W, DPMDT, DPDT, DPDD.

ENTRY THRMM

50 P = PMELTF(T) $ CALL COMPRLQ $ TI=T $ CALL IDEAL $ RETURN

C THRML FOR ISOTHERM AT SAT. LIQ. LINE, GET P.

C RETURNS P,DEN, E,H,S, CV,CP,CSAT,W, DPSDT,DDSDT, DPDT, DPDD.

ENTRY THRML

55 P = PSATF(T) $ CALL COEXIST $ RETURN

C THRMV FOR ISOTHERM AT SAT. VAPOR LINE, GET P.

C RETURNS P,DEN, E,H,S, CV,CP,W, DPSDT,DDSDT, DPDT, DPDD

ENTRY THRMV

60 P = PSATF{T) $ CALL COEXIST

61 DEN=DNG $ E=EG $ H=HG $ S=SG $ CV=CVG

62 CP=CPG $ W=WG $ DPDT=DPGDT $ DPDD=DPGDD

99 RETURN $ END

51
FUNCTION THETAF(DEN)

THETA = TSAT*EXP(U(S))

.

LET Q = {S-1)/(ST-1) , WHERE ST = OTRP/OCRT, THEN - IF S < 1, U = AL*Q**3, IF S > 1, U = -AL*Q**3,

C0MM0N/1/AL,BE,GA,DE,EP,ET, OCRT,TCRT,PCRT, DGAT,DTRP,TTRP,PTRP

C0MM0N/3/DPDT,02PDT2,0PSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT

COMMON/6/ TSAT, THETA, PSAT

1 S = DEN/DCRT $ DSOR = DTRP/DCRT $ C = DSOR-1

2 Q = (S-l)/C $ Q2 = Q*Q $ U = AL*Q*Q2

3 Ul = AL*3*Q2*DS0R/C $ IF(Q) 5,9,4

4 U = -U $ Ul = -Ul

5 XP = EXP(U) $ THETAF = TSAT*XP

6 DTHDR = (TSAT*U1 + DTSDR)*XP $ RETURN

9 THETAF = TCRT $ DTHDR =0 $ RETURN $ END

FUNCTION TSATF(DEN)

ITERATE T TO MINIMIZE (DEN-DCALC) VIA DENGASF(T), DENLIQF(T).

IF ITERATION FAILS, PRINTOUT ONCE ONLY AND STOP AT K = 2.

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT, TCRT, PORT, DGAT,DTRP,TTRP,PTRP

C0MM0N/3/DPDT,02PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR, DTHDR, DOSDT

DATA (0=2. 0),(FN=6. 3890561)

NOTE, FN # EXP{Q) - 1.0.

1 FORMATdHl 14X *TSATF(DEN) FAILS AT DEN =* E15.7//

1 15X 5HDCALC 13X2HDD 10X5HDDSDT 13X2HDT 12X3HT,K ) 2 F0RMAT(5X 5E15.7)

3 K = 0 $ D = DEN

4 S = D/DCRT $ YN = TCRT/TTRP-1 $ IF(D-DCRT) 5,30,6

5 ST=DGAT/DCRT $ F=AL0G( S)/ALOG( ST)*{ ( 1-S) /( 1-ST) )**2 $ GO TO 7 6 ST=DTRP/DCRT $ U={ ( S-1 ) /( ST-1 ) )**3 $ F=(EXP(Q*U)-1)/FN

7 T = TCRT/(YN*F+1)

8 DO 20 J=l,50 $ IF{D-DCRT) 9,30,10

9 DC = DENGASF(T) $ GO TO 11

10 DC = DENLIQF(T)

11 DD = D - DC $ IF(ABS(DD/D) .LT.l.OE-7) 25,12

12 DT = DD/DDSDT $ IF( ABS{DT/T) .LT.l .OE-7) 25,13

13 T = T + DT $ IF(T) 14,14,15

14 T = TTRP $ GO TO 18

15 IF{T.LT.TCRT) 18,16

16 T = TCRT - 0.05

18 IF(K.EQ.l) PRINT 2, DC, DD, DDSDT, DT, T

20 CONTINUE $ K = K+1 $ IF{K.NE.l) STOP

21 PRINT 1, DEN $ GO TO 4

25 TSATF = T $ DTSDR = DTRP/DDSDT $ RETURN

30 TSATF = TCRT $ DTSDR = 0 $ RETURN $ END

FUNCTION XBF(T,D)

XBF(R,T) # (X**BE)*EXP{A*(1-TS/T)) - XS**BE, WHERE - X # T/TC, XS # TS/TC, A # (1-BE) + SQRT(l-BE),

X3F = U*EXP(A*V) - US, U # X**B, US # XS**B, V # (1-TS/T).

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT, TCRT, PORT, DGAT,DTRP,TTRP,PTRP

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR, DTSDR, DTHDR, DDSDT

C0MM0N/4/XBl,XB2, XC1,XC2, XE1,XE2, DXBDR,DXCDR,DXEDR

52
COMMON/6/ TSAT, THETA, PSAT

1 B = BE $ BN = 1-B $ A = BN + SQRT{BN)

2 TC=TCRT $ TS=TSAT $ X=T/TC $ XS=TS/TC $ XS1=DTSDR/TC

3 U = X**B $ Ul = B*U/X $ U2 = -BN*U1/X

4 US = XS**B $ USl = B*US*XS1/XS

5 V = 1-TS/T $ VIR = -DTSDR/T $

6 P = EXP(A*V) $ 7 PIR = P1*V1R $

8 XBF = U*P - US $ XBl = U*P1X +

9 XB2 = U*P2X + 2*U1*P1X + U2*P $

10 RETURN $ END

VIX = TS/T/X $ V2X = -2*V1X/X

PI = A*P $ P2 = A*P1

PIX = P1*V1X $ P2X = P1*V2X + P2*V1X*V1X

U1*P

DXBDR = U*P1R - USl

FUNCTION XEF(T,D)

C ULTRA REVISION, MARCH 29, 1981.

C XEF = H(R,T)/HS(R) - 1.0,

C H{R,T) # 1 - (W-WE/E)/(1-1/E), E = ET.

C X#T/TC, F#TS/T, W#(1-TH/T), WE#W**E

C A = DE B = 1-A C = EP E = ET.

C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT,TCRT,PCRT, DGAT,DTRP,TTRP,PTRP

C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT

C0MM0N/4/XBl,XB2, XC1,XC2, XE1,XE2, DXBDR, DXCDR,DXEDR

COMMON/6/ TSAT, THETA, PSAT

E = ET $ EK = E/(E-1) $ TC = TCRT

TS = TSAT $ TH = THETA $ X = T/TC

W = 1.0 - TH/T $ IF(W) 30,30,4

CONTINUE

WIR = -DTHDR/T $

WE = W**E $ WEI

7 WEIX = WE1*W1X $

8 H = 1 - EK*(W-WE/E) $

9 HIX = -EK*(W1X-WE1X/E)

WIX = TH/T/X $ W2X = -2*W1X/X

= E*WE/W $ WEIR = WEI^WIR

WE2X = WE1*W2X + (E-1)*WE1*W1X*W1X/W

HIR = -EK*(W1R-WE1R/E)

$ H2X = -EK*(W2X-WE2X/E)

IF(WS) 11,11,12

$ GO TO 16

10 WS = 1.0 - TH/TS $

11 HS = 1 $ HSl = 0

12 WSl = (TH*DTSDR/TS - DTHDR)/TS

13 WSE = WS**E $ WSEl = E*WSE*WS1/WS

14 HS = 1 - EK*(WS-WSE/E) $ HSl = -EK*( WSl-WSEl/E)

16 U = 1.0/HS $ UlR = -U*HS1/HS

17 P = H*U $ DXEDR = H*U1R + H1R*U

18 XEl = H1X*U $ XE2 = H2X*U $ XEF = P - 1 $ RETURN

30 XEF = XEl = XE2 = DXEDR =0 $ RETURN $ END

53
ooooooooo oooooooo

54
Table 1. Comparisons of vapor pressure data with eq (2). Data sources and ID numbers: (l)Tickner, (2)Carruth, (3)Maass, (4)Dana, (e))Saqe, 7 ) Beatt i e.

(9) Kemp, (11 )Deschner, (12)Reamer, ( 13)Cherney, (14)C egg, ( 1 7)Helgeson , ( 19)611 1 i 1 and

,

(20)Burrel 1(25)Thomas, (30)Mousa, (35)Kratzke, (78)Teichmann, (80)Therma Loop s

1 D We ight Temp. T/Tc Pa(expt) Pa(oalc) Oiff. dPa/dT

K MPa MPa % MPa/K

80 .053 OP. 4 /(J O T 1 AA ItZOAOC AA . 1 6808t-09 I^OACI" AA. 1 689DE-09 -. 52 .688E-1

80 .059 yu.uuu • z43j4 A A "70 1 n AA .96721 b-09 A ^' o c c r" AA .958D5t-09 -. 14 .353E-09

80 .066 95.000 .25686 .54 1 72E-08 .54 1 Z3E-08 . 09u ? . 176E-08

80 .073 1 00 .000 .27038 .25 185E-07 .25 139E-07 1 ft . 730E-08

80 .081 1 A C AAA .28390 AAOA~7C~ A "7 .9989 /t-07 AA^ATI" AT .99697E-07 . ?nA u .260E-07

80 .088 t 1 A AAA 1 1 u • ouo O A*7 yl O .zy /4Z ~Z A CnAC AtT .3451 1 E-06 . 17 .814E-07

80 .097 lie AAA .J 1 uy4 lA^IOC AC

.051oE-0d . 1 3 .227E-06

80 .105 1 OA AAA . jz44d OACA^tr ACT •Z9504L-05 OA/IOICT AC

. 2948 1 E-05 .08 .574E-06

80 .1 14 1 O AAA Z"Z7n7 .3j /y / T/C'Z'ZC AC ~7>10AyiC" AC .74804t-05 .04 . 133E-05

80 .124 1 "Z. A AAA z c 1 yt A. 1 7534 E-04 .00 .286E-05

80 .133 1 C AAA T ^ C A 1 .38308L-04 .38316E-04 -.02 .574E-05

80 . 143 1 >1 A AAA 140.000 .37853 , 78644t-04 .IQol 1 E-04 . 1 09E-04

80 .154 14D.U(JU .39205 . 1 Dz74 L-03 ICOTAH AT

. 1 5279E-03 -.04 .195E-04

80 .164 1 c:n Ann 1 5U. UUU •4U DD

9Q99ACr A'Z 009"Zi::C AZ .ZOZ3DE-U3 -.03 .334E-04

80 .176 1 DP . UUU <1 1 Q AO .4 1 yuy ylAOOAC C\X o4yooOt--UD A no A7C AT .4yoy /E-U3 -. 02 .547E-04

80 . 187 1

1 An nnn uU. UUU .4j)Zfc) 1 Q/1 AO 1 C A'Z

• o4Dy I t-Uj OA 7AAF A'Z. 04 /UUt-Uj -.01 .865E-04

80 .199 1

1 O

R nnn J . UUU .440 1 J . 1 JODDt-UZ 1 "^QA/ F A9 . 1 JO04t-UZ .00 . 132E-03

9 .202 1 f^f^ 1 on 1 DD . 1 yu

yt yj QTyl .44yj4 1 R/i Q nr n9 . 1 D4oUt-UZ 1 c^ c: 1 9 F A9 . 1 DD 1 Zt-UZ -.21 . 145E-03

80 .21 1 i7n 1 / U. nnn UUU .4 DyOD 91QAXC n9 . z 1 yODt—uz 9 1 Q ROF n9 • z lyDyt-uz .02 .195E-03

9 .220 1 /-). J^:U A AO A9 .4DODZ 90T'^nP A9 . zy_)_)Ut-uz 9Q'^nQF n9 . zyjuot-uz .08 .249E-03

80 .224 17R 1 / -).UUU nnn yl7'^ 1 A ';'^7A'iF_n9 .J J / ODt—UZ . J>'^^7RAF J / DO t—n9UZ .02 .281E-03

9 .236 17Q Pj19 /I O . HODZU .^yoDuc-uz 4QRRnF-n9 . 4Qft7RF-n9 HyO / O u—UZ -.06 .390E-03

80 .237 iftn 1 OU .UUU nnn • H OODO o DU J 1 H C— UZ c;A/Q7p_n9 . ju'+y / F— UZ .03 .394E-03

9 .257 1Q7 T/17

. DUODD .0s79^nF_n9 /ZDUt—UZ . Q79QAF_n9 0 / zyo t—UZ -.05 .621E-03

80 .264 ion 1 yu .UUU nnn •D 1 D /Z 1 AK 1 AF_n. 1 UD I DC—U

1 n R 1 9 F_ n 1 . 1 UD 1 ZF— U

.04 .724E-03

80 .278 iQR m nnn UUU •i979/l . DZ

Zh . 1 HOyJU—U 1 1 d(^ft7F-n 1 . 1 HDO / F—U

.04 .954E-03

9 .278 1 Q C IT 1 . DZ / Dy 1 A QA"^F_n 1 « 1 4oU Jt—U 1 1 ylfl 1 9F_n 1 . 1 40 1 Zt—U

-.06 .960E-03

80 .292 zuu. 9nn nnn UUU n7A • D4U /O 9n 1 /I nF n 1 . ZU 1 4Ut-U

9n 1 '^TF n 1 . ZU 1 Jjt-U

.03 . 123E-02

9 .301 9n9 Q 1

zuz . y 1

<=iy1PA"^

. D400

.z jyo /t—u

.ZDyyjt— 9"^QQ'^F — n 1 u

-.02 .142E-02

80 .307 9nR ZUP . nnn UUU . DD4ZO 97 1 97F_nl • Z / 1 Z / t—U

97 11 QF n

s z / 1 1 y c—u.03 . i57E-02

9 .322 onQ oo^; R A7An • DO /OU 7 c~7 1A F n 1 • DO 1 / 4 1 -U

'^c:70QF ni ._>D /yot-u 1 -.07 .196E-02

80 .322 o 1 n nnn z 1 U.UUU . Do /oU z c A COET A 1 .DDyDZt-U

z cr CiA AC n 1 . jDy44t-U

.02 . 197E-02

9 .338 o 1 >! no o

z 1 4 . yoz .Dol z / ylAOOylC A1 .4Doo4b-Ul jIAOAZir A1 .45oyDt-U

-.02 .244E-02

80 .338 o 1 c: nnn Z 1 J. UUU c Q 1 -zn

. Do 1 JZ A AOyl y1 F A 1 .40y44t-U

A AQ'Z7F A 1 . 4oyj / t-u

.02 .244E-02

80 .354 oon nnn ZzU.UUU C O y1 O ^ .Dy4o4 Anyi AAC A 1 .DU4oUt-U

AAylCCC A1 .bU4DDE-U

.01 .298E-02

9 .355 o on o cn ZZU.ZDy . 59554 A 1 O 1 OC A 1 .512 lzt-01 AITZIET A1 .5 1 z3 1 E-01 -.03 .301 E-02

80 .370 ZZP. UUU iC AO "Z C .OOODD .7588zt-01 *7AOQ/l[r A1

. /5oo4h-(Jl -.00 .360E-02

9 .370 90(^ AOQ zz 5. uyy AAQ A9 . dUodz "771~7nC A1

. / / 1 /yt-ui 779"ZQF A 1 . / /zjot-U

-.08 .362E-02

9 .383 zzo.oUo A 1 O A C .0 lOOD AI^O^C A1

.y 1 4o4h-Ul A1CAZC A1.y 1 Dy3E-ui -. 12 .413E-02

80 .387 TZ A AAA 230.000 .62 187 .96624E-01 .96633E-01 -.01 .431 E-02

9 .392 231 .462 .62583 1 A"2AOC" 1 AA

. 1 030zE+00 lATIACiAA. 1 031 OE+00 -.08 .453E-02

25 .487 O CQ 1 C A ZDO . 1 5U A ATAA .by /yy OA 1 "7AC_i_AA OA 1 CIC-LAA .09 . 101E-01

25 1 .000 zo3 . 1 50 .7 1 1 50 "2/1 C/IAET lAA .34549t+00 "Z A COOC lAA .3452zE+<jO .08 .1 14E-01 25 1 .000 268. 1 50 .72502 .40623E+00 .40601 E+00 .05 . 129E-01

25 1 .000 273. 1 50 .73854 .47462E+00 .47447E+00 • U .145E-01

25 1 .000 0~70 1 CA

z /o . 1 DO .75206 .55125t+00 C C 1 1 O [T 1 AA .551 18E+00 • 01 . 162E-01

25 1.000 283. 1 50 .76558 .63672E+00 /""I/^TI CiAA .53671 E+00 .00 .180E-01

25 1 .000 O O O 1 C A 288. 1 50 .77910 .73159E+00 1 lAA .731 67E+00 . U I .200E-01

25 1 .000 293. 1 50 .79262 .83650E+00 Ct T d ^ Cr~ lAA .83665E+00 -.02 .220E-01

25 1 .000 OOO 1 CA zyo. 1 DO o A A 1 y1 .80514 ACOAOCj AA .9D20zh+00 A COOAC_i_AA .9d2z9E+00 -.03 .242E-01

25 1 .000 303. 1 50 .8 1 966 1 A"70AC 1 A 1 . 1 0789E+0

1 A"? AO C* 1 A 1 . 1 0792 E+O

-. 03 .266E-01

35 1 .000 3 1 1 .974 .84351 1 "71 ^OI~ lAI

. 13318E+01 . 1 3327E+01 -.07 .310E-01

35 1.000 312.360 .84456 ^ T A A C r" lAI

. 1 3446E+0

. 1 3447E+0

-.01 .312E-01

25 1.000 "7 1-7 1 CA J 1 J. 1 DU o» A An .o4D0y 1 "Z A A9F_1_A 1 . ijoyzb+ui 1 "ZAAC^F J.A 1 . 1 joyDt+u

-.03 .316E-01

35 1 .000 317.143 .85749 .14993E+01 .15000E+01 -.05 .338E-01

35 1 .000 322. 120 .87095 . 16743E+01 . 16751E+01 -.05 .366E-01

7 1.000 323.150 .87373 .17122E+01 .17131E+01 -.05 .372E-01

25 1.000 323.150 .87373 .17130E+01 .17131E+01 -.00 .372E-01

35 1.000 327.660 .88593 .18861E+01 .18870E+01 -.05 .399E-01

25 1.000 333. 150 .90077 .21164E+01 .21 158E+01 .03 .435E-01

35 1.000 333 . 545 .90184 .21331E+01 .21330E+01 .00 .437E-01

35 1.000 337.944 .91373 .23309E+01 .23318E-f01 -.04 .467E-01

35 1.000 342.679 .92654 .25606E+01 .25609E+01 -.01 .501E-01

25 1.000 343.150 .92781 .25862E+01 .25846E+01 .06 .504E-01

55
Table 1. (Continued)

.

Data sources and ID numbers: (l)Tickner, (2)Carruth, (3)Maass, (4)Dana, (6)Sage, (7)Beattie,

(9)Kemp, ( 1 1 )Deschner, (12)Reafner, (13)Cherney, (14)Clegg, ( 17) He I geson , ( 19)Gi I I i land,

(20)Burrei I , (25)Thomas, (30)Mousa, (35)Kratzke, (78)Teichmann , (80)Thermal Loops.

1

1 nu Wont? I

1 (T K + y n 1 Tsfnp • 1 / 1 C

ni f f riP /rIT

r\ MPa MPa MPa /K 35 1 .000 347,773 .94031 .28265E+01 .28259E+01 .02 ,540E-01

7 1.000 348.150 .94133 .28485E+01 .28463E+01 .08 ,543E-01

25 1.000 348 . 1 50 .94133 .28486E+01 .28463E+01 .08 ,543E-01

25 1 .000 353. 150 .95485 .31309E+01 .31281E+01 .09 ,585E-01

35 1.000 353.423 ,95558 .31451E-K)1 .31441E+01 .03 ,587E-01

35 1.000 357.564 .96678 ,33962E+01 .33948E+01 .04 ,625E-01

25 1 .000 358. 1 50 .96837 .34352t+01 7/I'2 .343 16t-K) 1 . 1

1

.630E-0

1

35 1 .000 369.876 .98 1 01 .37371E+01 . 37373E+01 -.01 ,679E-01

1 .000 363. 1 50 .981 88 -37633E+0

1

.37594E+n

1

. 1

0

25 1 .000 365. 1 50 .98729 . 390 1 8E+ni .38983E+01 .09 .707E-01

35 1 .000 366- 1 30 .98994 .39665E+01 .39681 E+0

1

-.04 .720E-0

1

25 1 .000 367. 1 50 .99270 .40450E+01 .40423E+01 ,07 .734E-01

35 1 .000 357. 583 .99387 ,40727E+01 .40742E+01 -,04 .741 E-01 25 1 .000 368. 150 .99540 .41 185E+01 .41 165E+01 ,05 .751E-01

25 1 .000 369. 1 50 .9981

1

.4 1935E+01 .41926E-K) 1 .02 .772E-01

25 1 .000 369.650 .99946 .42316E+01 .42316E+01 .00 .788 E-01

1 .000 369.750 .99973 -423Q3E+0

1

.42395E+0

1

-.00 .794E-0

1

1 0.000 105.350 .28485 ,13330E-06 .10921E-06 22.06 .283E-07

1 0.000 108.250 .29269 ,26660E-06 .22667E-06 17.61 .554 £-07

1 0.000 1 12.450 .30404 ,66660E-06 .60685E-06 9.85 .136E-06

1 0.000 115.750 ,31296 ,13330E-05 ,12453E-05 7.04 ,263E-06

1 0.000 1 19.250 .32243 ,26660E-05 .25447E-05 4.77 .503E-06

1 0.000 124.350 .33622 ,66660E-05 ,66588E-05 .11 .120E-05

1 0.000 128.350 .34703 ,13330E-04 .13346E-04 -. 12 .224E-05

1 0.000 132.850 .35920 .26660E-04 ,27600E-04 -3.40 .429E-05

1 0.000 139.150 .37623 .66660E-04 .69900E-04 -4.64 .979E-05

1 0.000 144.350 .39029 , 13330E-03 , 14057E-03 -5.17 .181E-04

1 0.000 149.950 .40543 ,26660E-03 .28069E-03 -5.02 .332E-04

1 0.000 158,150 .42761 ,66660E-03 .69949E-03 -4.70 .733E-04

1 0.000 164.750 .44545 .13330E-02 .13538E-02 -1.54 .129E-03

2 0.000 94,540 .25562 .68500E-08 .46579E-08 47.06 .153E-08

2 0.000 99,780 .26979 .30650E-07 .23579E-07 29.99 .688E-08

2 0.000 105,150 .28430 , 12190E-06 . 10368E-06 17.58 .270E-07

2 0.000 1 10,650 ,29918 .43650E-06 .40193E-06 8.60 .936E-07

2 0.000 1 17.420 ,31748 .17800E-05 . 17616E-05 1.05 .360E-06

2 0.000 127.720 ,34533 .1 1360E-04 ,12000E-04 -5.33 .204E-05

2 0.000 134.150 ,36271 .31250E-04 ,33703E-04 -7.28 ,512E-05

2 0.000 143.740 ,38864 .1 1960E-03 ,12989E-03 -7.92 ,169E-04

2 0.000 155.720 .42104 .50660E-03 ,53976E-03 -6. 14 ,586E-04

2 0.000 162,450 ,43923 ,10390E-02 .10830E-02 -4.06 .107E-03

2 0.000 173,580 .46933 .29920E-02 .29962E-02 -.14 ,254E-03

2 0^000 178.650 .48303 .45700E-02 .45409E-02 .64 .360E-03

3 0.000 229.750 .62120 ,11426E+00 .95561E-01 19.57 .427E-02

3 0.000 230,250 ,62255 .11599E+00 .97716E-01 18.70 ,435E-02

3 0.000 230,850 .62417 .1 1919E+00 .10035E-K)0 18.77 .444E-02

3 0.000 234,750 .63472 .13999E+00 .1 1887E4O0 17.77 .506E-02

3 0.000 242.300 .65513 . 18238E+00 .16214E+00 12.48 .644E-02

3 0.000 250.050 .67608 .26944E+00 .21824E+00 23.46 .808E-02

4 0.000 210.330 , 56869 ,36837E-01 .36599E-01 .65 .200E-02

4 0.000 216.410 .58513 .50689E-01 .50477E-01 .42 .258E-02

4 0.000 216,470 .58529 ,50822E-01 .50632E-01 ,37 .259E-02

4 0.000 221.640 .59927 .65835E-01 .65504E-01 .51 .318E-02

4 0.000 227.250 .61444 .85753E-01 .85335E-01 .49 .391E-02

4 0.000 231.080 .62479 .10181E+00 .10138E+00 .42 ,447E-02

4 0.000 235.040 .63550 .12050E+00 . 12034E+00 .13 .5nE-02

4 0.000 235.090 .63564 .12082E+00 .12060E+00 ,18 ,512E-02

4 0.000 242.730 ,65629 .16520E+00 . 16493E+00 ,16 .652E-02

4 0.000 249.070 .67344 .21041E+00 .21043E+00 -.01 .786E-02

4 0.000 256,290 .69296 .27238E+00 .27326E+00 -.32 .958E-02

4 0.000 267.280 .72267 .39303E+00 .39490E+00 -.47 ,126E-01

4 0.000 272.120 .73576 ,45903E+00 .45972E+00 -, 15 ,142E-01

4 0.000 275.630 .74525 .50529E+00 .51 145E+00 -1 ,21 ,153E-01

4 0.000 282.670 .76428 .62542E+00 .62810E+00 -,43 .178E-01

56
Table 1. (Continued).

Data sources and ID numbers: (l)Tickner, (2)Carruth, (3)Maass, (4)0ana, (6)Sage, (7)Beattie,

(9)Kemp, (IDDeschner, (12)Reamer, (13)Cherney, (14)Clegg, ( 17 )Hei geson , ( 19)Gi I 11 land,

(20)Burrell, (25)Thomas, (30)Mousa, (35)Kratzke, (78)Te ichmann , (80)Thermal Loops.

u

Wiis I n K *t* Wfc; 1 y 1 1 1 T©rnp • 1 / 1 c P 1 1 r \ 0

ni f f HP /rIT MPa MPa tp lira/ i\

4 0.000 283.300 .76599 .63648E+00 .63942E+00 -.46 .181E-01

4 0.000 291.080 .78702 .78607E+00 .79193E+00 -.74 .212E-01

4 0.000 298.080 .80595 .94352E+00 .95059E+00 -.74 .242E-01

4 0.000 307.090 .83031 . 1 1644E+01 . 1 1876E+01 -1.95 .285E-01

4 0.000 315.210 .85226 .14232E+01 .14358E+01 -.87 .327E-01

4 0.000 323.490 .87465 .17023E+01 .17258E+01 -1.36 .374E-01

4 0.000 323.490 .87465 .17065E+01 .17258E+01 -1.12 .374E-01

6 0.000 293.930 .79473 ,86180E+00 . 85398 E+00 .92 .224E-01

6 0.000 301 .090 .81409 .10352E+01 . 10255E+01 .94 .256E-01

6 0.000 307.480 .83136 . 12066E+01 . 1 1987E+01 .66 .287E-01

6 0.000 313.320 .84715 .13790E+01 . 13749E+01 .30 .317E-01

6 0.000 318.590 .86140 .15513E+01 .15494E+01 .12 .345E-01

6 0.000 323.370 .87433 . 17237E+01 .17213E+01 .14 .373E-01

6 0.000 327.930 .88666 . 18961E+01 . 18978E+01 -.09 .401E-01

6 0.000 332.090 .89790 .20684E+01 .20701 E+01 -.08 .428E-01

6 0.000 336.090 .90872 .22408E+01 .22464E+01 -.25 .454E-01

6 0.000 339.870 .91894 .24132E+01 .24231 E+01 -.41 .481E-01

6 0.000 343.480 .92870 .25855E+01 .26013E+01 -.61 .507E-01

6 0.000 346.930 .93803 .27579E+01 .27807E+01 -.82 .533E-01

6 0.000 350.090 .94657 .29303E+01 .29532E+01 -.78 .559E-01

6 0.000 353.090 .95468 .31026E+01 .31246E+01 -.70 .584E-01

6 0.000 355.870 .96220 .32750E+01 .32903E+01 -.47 .609E-01

6 0.000 358.590 .96956 .34474 E+01 .34594E+01 -.35 .635E-01

6 0.000 361.260 .97677 .36197E+01 .36324E+01 -.35 .662E-01

6 0.000 363.760 .98353 .37921 E+01 .38012E+01 -.24 .690E-01

6 0.000 366.260 .99029 .39645E+01 ,39775E+01 -.33 .721E-01

6 0.000 368.760 .99705 .41369E+01 .41627E+01 -.62 .763E-01

1 0.000 301.950 .61641 .10536E+01 . 10477E+01 .56 .260E-01

1 0.000 302.950 .81912 .10807E+01 .10739E+01 .63 .265E-01

1 0.000 304.610 .82360 . 1 1248E+01 . 1 1 185E+01 .56 .273E-01

1 0.000 306.680 .82920 .n829E+01 .1 1760E+01 .59 .283E-01

1 0.000 308.350 .83372 . 12317E+01 .12239E+01 ,64 .291E-01

1 0.000 31 1.490 .84221 .13246E+01 .13178E+01 .52 .307E-01

1 0.000 311.490 .84221 . 13249E+01 . 13178E+01 .54 .307E-01

1 0.000 315.480 .85299 .14500E+01 .14446E+01 .37 .329E-01

1 0.000 318. 150 .86021 .15471E+01 . 15343E+01 .84 .343E-01

1 0.000 318.280 .86057 .15474E+01 .1 5388E+01 .56 .344E-01

1 0.000 324.940 .87857 .17798E+01 .17806E+01 -.05 .383E-01

1 0.000 330.600 .89388 .20098E+01 .20071 E+01 ,13 .418E-01

1 0.000 330,600 .89388 .20107E+01 .20071 E+01 . 18 .418E-01

1 0.000 333.960 .90296 .21596E+01 .21512E+01 .39 .440E-01

1 0.000 336.650 .91023 .22749E+01 .22720E+01 .13 .458E-01

1 0.000 340.120 .91962 .24561E+01 .24351 E-i-01 .86 .482E-01

1 0.000 340.120 .91962 .24539E+01 .24351E+01 .77 .482E-01

1 0.000 344.640 .93184 .26778E+01 .26606E+01 .65 .516E-01

1 0.000 348.240 .94157 .28709E+01 .28512E+01 .69 .544E-01

1 0.000 351 .640 .95076 .30683E+01 .30408E+01 .90 .572E-01

1 0.000 358.010 .96799 .34289E+01 .34227E+01 .18 .629E-01

1 0.000 361.120 .97640 .36292E+01 .36231 E+01 .17 .660E-01

1 0.000 361. 120 .97640 .36320E+01 .36231E+01 .24 .660E-01

1 0.000 363.200 .98202 .37687E+01 .37628E+01 .16 .683E-01

1 0.000 363.450 .98270 .37828E+01 .37799E+01 .08 .686E-01

1 0.000 365.470 .98816 .39048E+01 .39209E+01 -.41 .71 lE-01

1 0.000 368.850 .99730 ,41585E+01 .41696E+01 -.27 .765E-01

0.000 368.970 .99762 .41813E+01 .41787E+01 .06 .767E-01

2 0.000 313.483 .84759 .13790E+01 . 13801E+01 -.08 .318E-01

2 0.000 332.039 .89777 .20684E+01 .20679E+01 .02 .427E-01

2 0.000 339.594 .91819 .24132E+01 .24098E+01 .14 .479E-01

2 0.000 346.428 .93667 .27579E+01 .27540E+01 .14 .529E-01

2 0.000 352.706 .95365 .31026E+01 .31022E+01 .01 .581E-01

2 0.000 358.261 .96867 .34474E+01 .34386E+01 .26 .631E-01

2 0.000 363.594 .98309 .37921 E+01 .37898E+01 .06 .688E-01

2 0.000 368.372 .99600 .41369E+01 .41332E+01 .09 .755E-01

3 0.000 303.150 .81966 .10801E+01 . 10792E+01 .08 .266E-01

57
Table 1. (Continued).

Data sources and ID numbers: (l)Tickner, (2)Carruth, (3)Maass, (4)Dana, (6)Sage, (7)Beattie,

(9)Kemp, ( 1 1 )Deschner , (12)Reamer, (13)Cherney, (14)Clegg, ( 17)Helgeson, ( 19)Gi I I i land,

(20)Burrell , (25)Thomas, (30)Mousa, (35)Kratzke, (78)Teichmann, (80)Thermal Loops.

1

D

Weight Temp, T/Tc Pg ( expt) Pg ( ca 1 c

)

D 1 1 1

.

dP(j/dT

K MPa MPa % MPa/K

13 0.000 323.150 .87373 .17154E+01 .17131E+01 .14 ,372E-01

14 0.000 323.150 .87373 .17154E+01 .17131E+01 . 14 ,372E-01

14 0.000 333.150 .90077 .21 197E+01 .21 158E+01 .18 .435E-01

14 0.000 343.150 .92781 .25909E+01 .25846E+01 .24 .504E-01

14 0.000 348. 150 .94133 .28533E+01 .28463E+01 .24 .543E-01

14

- 0.000 353. 150 .95485 ,31390E+01 .31281E+01 .35 .585E-01

14 0.000 358.150 .96837 .34400E+01 .34316E+01 .25 .630E-01

14 0.000 363.150 .98188 .37683E+01 .37594E+01 .24 .683E-01

14 0.000 368.150 .99540 .41239E+01 .41 165E+01 ,18 .751E-01

17 0.000 277.594 .75056 .54470E+00 .54223E+00 .46 . 160E-01

17 0.000 283.150 .76558 .63980E+00 ,63671 E+00 .48 .180E-01

17 0.000 288.706 .78060 .74330E+00 .74284E+00 .06 .202E-01

17 0.000 294.261 .79562 .86180E+00 .86141E+00 .05 .225E-01

17 0.000 299.817 .81064 .99350E+00 .99332E+00 .02 .250E-01

17 0.000 305.372 .82566 .1 1397E-K)1 .1 1394E+01 .03 .276E-01

17 0.000 310.928 .84069 .13010E+01 .13006E+01 .03 .304E-01

17 0.000 316.483 .85571 .14789E+01 .14778E+01 .07 .334E-01

17 0.000 322.039 .87073 . 16734E+01 . 16721E+01 .08 .366E-01

17 0.000 327.594 .88575 .18857E+01 .18844 E+01 ,07 .399E-01

17 0.000 333.150 .90077 .21 188E+01 .21158E+01 , 14 ,435E-01

17 0.000 338.706 .91579 .23718E+01 .23676E+01 .18 .472E-01

17 0.000 344.261 .93081 .26462E+01 .2641 lE+01 .19 .513E-01

17 0.000 349.817 .94583 .29434E+01 ,29380E+01 .18 .556E-01

17 0.000 355.372 .96085 .32654E+01 .32601E+01 .16 .604E-01

17 0.000 360.928 .97588 .36184E+01 .36105E+01 .22 .658E-01

19 0.000 314.817 .85120 .14065E+01 . 14229E+01 -1. 16 .325E-01

19 0.000 330.372 .89326 .20271 E+01 .19976E+01 1.48 ,416E-01

19 0.000 34 5.372 .93382 .27441E+01 .26985E+01 1.69 ,521E-01

19 0.000 357.594 .96686 .34060E+01 .33967E+01 .27 ,625E-01

20 0.000 148.950 .40273 .40000E-03 .24915E-03 60.54 ,299E-04

20 0.000 154.850 .41868 .80000E-03 .49082E-03 62.99 .540E-04

20 0.000 163.950 .44329 .20000E-02 .12537E-02 59.53 .121E-03

20 0.000 172.650 .46681 .40000E-02 .27678E-02 44.52 .237E-03

20 0.000 179.850 .48628 .66660E-02 .49909E-02 33.56 .390E-03

20 0.000 190.350 .51467 .13332E-01 .10768E-01 23.81 .739E-03

20 0.000 196. d50 . 53224 . 19998E-01 . 16540E-01 20.91 .105E-02

20 0.000 202.050 .54630 .26664E-01 .22794E-01 16.98 .136E-02

20 0.000 210.250 .56847 .39997E-01 .36439E-01 9.76 . 199E-02

20 0.000 215.450 .582 53 .53329E-01 .48044E-01 1 1 ,00 .248E-02

20 0.000 219.950 .59470 .66661E-01 .60306E-01 10.54 .298E-02

20 0.000 223,750 .60497 .79993E-01 .72482E-01 10.36 .344E-02

20 0.000 225.550 .60984 .86660E-01 ,78886E-01 9.85 .368E-02

20 0.000 227.050 .61390 .93326E-01 .84556E-01 10.37 .388E-02

20 0.000 228.050 .61660 .97325E-01 ,88509E-01 9.96 ,402E-02

20 o.ooc 229.050 .61931 .10133E+00 .92606E-01 9.42 ,417E-02

30 0.000 334.780 .90518 .22001E+01 .21875E+01 .58 ,445E-01

30 0.000 337.360 .91215 .23186E+01 ,23047E+01 .60 .463E-01

30 0.000 340.510 .92067 .24651E+01 .24540E+01 .45 .485E-01

30 0.000 346.730 .93749 .27883E+01 ,27700E+01 .66 .532E-01

30 0.000 350.470 .94760 .29955E+01 .29745E+01 .71 .562E-01

30 0.000 353.620 .95612 .31652E+01 .31556E+01 .30 .589E-01

30 0.000 357.820 .96747 .34242E+01 ,34108E+01 .39 .627E-01

30 0.000 362.280 .97953 .37296E+01 .37004E+01 .79 ,673E-01

30 0.000 365.570 .98843 .39541E+01 .39281 E+01 .66 ,712E-01

30 0.000 367.850 .99459 .4T159E+01 .40941 E+01 .53 ,746E-01

30 0.000 369.740 .99970 .42537E+01 .42387E+01 ,36 .793E-01

78 0.000 324.754 .87807 .17728E+01 .17735E+01 -.04 .382E-01

78 0.000 328.078 .88706 .19041 E+01 .19037E+01 .02 .402E-01

78 0.000 331.356 .89592 ,20393E+01 .20389E+01 .02 .423E-01

78 0.000 333.900 .90280 ,21496E+01 .21486E+01 .05 .439E-01

78 0.000 335.669 .90758 .22278E+01 .22274E+01 .02 .451E-01

78 0.000 337.878 .91355 .23285E+01 .23288E+01 -.01 .467E-01

78 0.000 340,292 .92008 .24433E+01 .24434 E+01 -.01 .484E-01

78 0.000 342.939 .92724 .25742E+01 .25740E+01 ,01 .503E-01

58
Table 1. (Continued)

.

Data sources and ID numbers: (l)Tickner, (2)Carruth, (3)Maass, (4)Dana, (6)Sage, (7)Beattie,

(9)Kemp, ( 1 1 ) Deschner , (12)Reamer, (13)Cherney, (14)Clegg, ( 17 ) Hel geson , ( 19)Gi I I i land,

(20)Burrell, (25)Thomas, {30)Mousa, (35)Kratzke, (78)Teichmann, (80)Thermal Loops.

1

D

We ight Temp, T/Tc P^( expt) P(j(cal c) Di f f

.

dP(j/dT

K MPa MPa % MPa/K

1R10 u» uuu lit;

. y D D 1 £. . jL do / UHTU 1 • ZOO DZ ctu 1 on

78 0.000 348.087 .94116 .28434E+01 .28429E+01 .02 .542E-01

78 0.000 350.680 .94817 .29866E+01 .29863E+01 .01 .564E-01

78 0.000 352.559 .95325 .30930E+01 .30937E+01 -.02 .579E-01

78 0.000 354.824 .95937 .32279E+01 .32271E+01 .02 .599E-01

78 0.000 358. Ml .96834 .34310E+01 .34310E+01 .00 .630E-01

78 0.000 353.426 .98263 .37776E+01 .37783E+01 -.02 .686E-01

Number of data points used in fit = 81; rms pressure deviation = 0.056^.

59
Table 2. Comparisons of saturated liquid density data with eq (3).

Data sources and ID numbers: (l)Maass, (2)Van der Vet, (3)NGAA, (4)Sage, (5)Reamer, (7)Clegg,

{8)Francis, (ll)Seeman, ( 1 2)Hel geson , (13)Klosek, {14)Shana'a, (15)Jensen, ( 16)S I iwinski

,

( 17)Toml inson, (18)Kahre, ( 19)Rodosevich, (20)Haynes, (2 1 ) Deschner , (22)0rrit, (23)McClune,

(24)Ely, (25)Thomas, (34)Carney, (36)Dana.

ID Weight Temp. (VT)/(Tc-Tt) Dens i ty (expt) Density (calc) Di f f

.

dP£/dT

IN mo 1 / L kn/ C m3.K' ^

1 finn 1 6 .607 . \)D -11 . n"^ni UJU 1 99 1 nnn on^U .

1

1 nnuu \\J m J £- L. f £~0 9 J 1 109. S7 - nn -1 n97'^

11 Q2/ 1 nnn 91 nin .98052 16.485 726.96 727.64 -.09 - 1 .0265

23 1 .000 93 . 1 50 .97299 1 6.442 725.05 725.44 -. 05 -1 .0250

22 1 .000 96.040 .96283 15.385 722. 52 722.48 .01 -1 .0230

23 1 .000 98 . 1 50 .9554

1

16.331 720. 17 720.33 -.02 -1 .02 16 19 1 .000 1 no. 01

0

\ \J\J % \ \J .94887 16.291 718.41 7 1 8.43 -.00 -1 .0205

£-\J 1 nnn inn n7s .94864 16.307 719.07 718.36 . 1

0

-1 .0205

1 nnn 1 nn QRn . 94546 16.272 7 1 7 . 54 7 1 7.44 .01 -1 .01 99

1 nnn 1

1 n'^ U_J .

1

1 ^n Q'^7R'^ Ifi 917 71 R 11 71 R 99 - n9 -1 niRR

C,\J 1 nnn ins nvs 16. 187 71 81 713 7fi OR -1 ni78

99 1 nnn infi 1 UO . i7n 1 / u Q979 1 Ifi 1 R? 719 9R 71 9 1 R . niU 1 -11 . ni7'^ U 1 ID

1 A. 1 nnn 1

t nRUO .

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1 e nnn uuu 11 noUO .

1

i JURn .^ZUZIJ Q9n9 R 1ft 1 nR 71 n 17 7 1 n 14 . nnUU -1I . nift4 U 1 OH

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1 • nnn uuu ins 1 UO .

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JV . Q9n9S yZUZ-3 1ft ID. 1

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1 P. 4 1 1 <C7A z: A 579.50 z: 7 A 7/1 5/9. /4 n 0 ~. Uz - 1 n 1 T 1

1 .U 1 3

1

oo 1 nnn 1 .UUU 1 3o.43U Q 1 Z "7-7 .0 13 /

/

1 e A no 1 P.4Uo 5 /y .4P cm Ad 5/9.45 nn -.UU - 1 ni "ZO

1 . U 1 JZ on 1 nnn 1 . UUU 1 /I n me .ou /yy 1 e "Z7e

1 P.3 /P X7Q nn 5/0. UU C~l~l 7Q 0 / / . /y n'z

• Uj 1 n 1 zft -1 .U 1 JO

9"^ 1

1 nnn . UUU 1 y| 7 1 en 1 1 DU 7Q7 1 7 » ly 1 \ 1

1 R OOft 1 p.zyo ^^7,1 en 0 /4

.

PU A7y1 ft7 0/4.0/ - n"^ .Uj - 1 n 1 ^ R 1 . U 1 4P

99 1

1 nnn . UUU 1 y1 -7 Q on 7Q/1 R7 . /y4 D /

1 e OQO 1 P. ZOZ £17 Z Q 7 0/3.0 / Z:7Z QO 0 /j. yz n 1 -. U 1 - 1 n 1 4 R 1 .U 1 40

9n 1

1 nnn • UUU 1 /I c n 7 R 7on/i n . / yu4u 1 R 0 RQ 1 p . zpy ft70 Q7 0 /Z.O

/

t^~io 70 0 /z. /z no .UZ - 1 n 1 R9 1 . U 1 PZ

9'^ 1

1 . nnn UUU 1 / Q 1 Rn . / /ypy 1 R 1 QO 1 P. 1 OZ DOy .40 ftfto ooy.DUAn — n9 . UZ _i n 1 ft

R

— 1 .U 1 DP

99 1

1 « nnn uuu 1 1

n

1 'f 7 . D 1 U 7 7/1 / ft . / /44D 11 RP .

1

1 AR40 ftftR ODO . nnUU ftftR ODO. 1 1

1

1

_ AO .uz - 1

I • nU 11 79/ z 9nzu 1

1 . nnn uuu 1 sn nT^i •II779R9 ZoZ 1 R \ AC\ 1 P. 1 4U ftft7 00 (\X / . 0J> ftft7 DO ft 4 / . 04 __ A A — . UU -1— 1 •un 1

1 7R/ P

9'^ 1

1 »uuu nnn 1 c-z 1 en 1 _)J>. 1 3U 7COA 1 • /DZU

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1 R nft7 1 P.UO/ OD4.4Z ftft/ R

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_— n 1 . u 1 -1— n IQI I •u 1 y

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1 . nnn uuu 11-39. RR npn UoU • / PPZZ 1

1 P.UZP R n9R ODZ . PP ftft9 ODZ Ryl

. P4 .UUnn —1 n9n'^ 1 •UZUJ

OXCD 1

1 .uuu nnn 1 RR 1 Rn 1 30 . 1 J\J • /444j \ A OR 1 14 .yp

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ftRQ 9Q Dpy .zy ftRQ DPy.4UAd _ AO — . uz —11 •uzz^ n994

99 1

1 . nnn uuu 1 An R/i n 1 DU. y'JU 7'^f^n9 • / jOUZ 1 ^ QAQ 1 4 .oyo Rf; OR opo.yo ftRft DPD.yOQft nn .UU _i— 1 •UZ^ n94i

1

ZJ

1

1 . nnn uuu 1 1 Rn . /ZO04 ] A Q XA 1 4. 0 J4 ft R^ 1

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DP4. 1

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ftOP4R4 9R . ZO —— .uzn? -1 n9ft9 1 •UZDZ 94Z^ 1

1 . nnn uuu ono 1 Dj. ouy 7 1 7/1 Q . / 1 /4y \ A 77ft 14./ / 0

ftR 1 ftn OP 1 . DU ft e 1 c c DPI . PP n 1 .u 1 —1— n9Rft 1 •UZOD

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1 nnn . UUU 1 A R n IO!5.y4U 7 1 7n'7

. /

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/Uj 1 y1 7 70 \H m 1 1

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c 1 Af\ OP 1 .4U ft R 1 AO OP 1 .4Z nn -.UU _i— 1 • n9R7 UZO

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OTZJ 1 nnn 1 .UUU 1 Q 1 en 1 DO . 1 5U 7nooiC • /UyzD 1 ^ 710 14. / 1 0CACi no 54y.UZ ft/1 A 1 ^ D4y. 14 -. noUZ — 1 n"^nR 1 .UjUO

ooZZ 1 nnn 1 .UUU 1-7 1 ^ 1 n 1 / 1 .4 1 UftQ7Qn .oy /oU 1 ^ en 1 4 . DPy / AC\ D4D.4U ft^ e 77 04 Dm 1

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- 1 n'^4 1

1 . UJ4 1 23 1.000 173.150 .69168 14.595 643.59 543.97 -.06 - 1.0360

24 1.000 176.472 .68000 14.525 640.50 640.53 -.00 -1 ^0399

22 1.000 182.340 .65936 14.385 634.33 634.40 -.01 -U0475

24 1.000 184.294 .65249 14.340 632.34 532.35 -.00 -K0503

22 1.000 187.800 .64016 14.254 628.55 528.66 -.02 -K0556

24 1.000 191.936 .62562 14.155 624.21 524.28 -.01 -K0623

22 1.000 193.300 .62082 14.120 622.57 622.83 -.03 -U0647

24 1.000 198.748 .60167 13.991 516.96 517.00 -.01 -K0747

22 1.000 198.890 .601 17 13.986 616.72 616.85 -.02 -1 ^0750

20 1.000 200.000 .59726 13.955 61 5.42 61 5.66 -•04 -1.0771

24 1.000 204.329 .58204 13.857 61 1.05 510.97 .01 -1 ^0860

22 1.000 204.540 .58130 13.847 610.62 610.75 -•02 -1.0865

60
Table 2. (Continued).

Data sources and ID numbers: (l)Maass, (2)Van der Vet, (3)NGAA, (4)Sage, (6)Reamer, (7)Clegg,

(8)Francis, (IDSeeman, (12)Helgeson, (13)Klosek, (14)Shana'a, (15)Jensen, ( 1 6)S I i w i nski

,

( 17)Toml inson, (18)Kahre, ( 19) Rodosev Ich , (20)Haynes, (21 )Deschner , (22)0rrit, (23)McClune,

(24)Ely, (25)Thomas, (34)Carney, (36)Dana.

ID Weight Temp. (Tc-T)/(Tc-Tt) Density (expt) Density (calc) Diff. dp„/dT

K mo 1 /L kg/m3 kg/rn3 kfi/ f m3.K ^

22 1 .000 210.020 .56203 13.710 604.59 604.75 -.03 - 1 .0989

24 1 .000 21 1 .320 .55746 13.696 503.95 603 .33 . 1 0 -1 . 1020

22 1 .000 2 1 6.020 . 54093 1 3. 559 597.92 598. 12 -.03 - 1 . 1 138 24 1 .000 918.200 .53327 13.517 596.04 595.59 .06 -11 . 11 19fi 1 7 u 222.040 . 5 1 976 1 3.405 591.12 591 "S7 - . 04UH -1 I'^O'^ 24 1 .000 975. B76 .50627 13.31

5

587. 1

7

587. 01 . 03U-/ -1 141fl 99 1 nnn 227.360 5ni n5 1 3.268 5R5 Ofi 5R5 "^1 - . 04u^ - 1 1 4fi4 94 1 nnn 9'^l R75 4R51R 1 _J . 1 u

~ 5Rn 71 5ftn 1

0

1 1 - 1 1 fi 1 1 22 1 nnn 232.910 .48 1 54 1 3. 1 20 578 . 56 578.90 -.05 -11 . 1fi47 1 U*T / 24 1 .000 235. 183 .47355 1 3.073 576.47 575. 24 . n4Ut -1 179fi 99 1 nnn 9'^5 fiin . 4H 79n4 / t. UH- 1 n5i 575 40 575 74 . UH -1 1747 99 1 nnn 9'^R ^_?0 . 4nn *tUU 4fi99'^ 1 9 Q75 579 1

4

579 4 5 _ AC

. U J -1 1R44 90 1 nnn 94nU . nnn UUU 4 5fift1 1 9 097 57n n5 J570/ U. J-J 55 -—. nouy — 1 lOOi^i I.I y\JD 99 1 nnn 941i . iftn 1 OU 4 594fi 19 00'';

I . y U_) JUG 5fiR •yOOR joy. 5fiQ 141 H - 0"^

. UJ) - 1 1 0 R 1i . \y J

\

99 1 nnn 94"^J . Qfin ^OU 449fi 1 1 9 R9Q yOj 5fi5 . 70/U ifi 5 7ft — . U 1 —— 1 90fi'^ 1 . ZUDJ

94 1 nnn 94C.^ fiu . 9fin ^uu 4'^4 5Q 19 77"^ 5fi''i 97 -/U_/ 5^"^ . 09u^ . 04U4 -1I . z9150 1 jy

94 1 nnn 947 555 4"^nn4 1 9 749 5fi 1 ft7 5fi 1 44 . ORuo - 1 99 1

5

1 . ZZ 1 1? 94 1 nnn 94Q 59^^ 49"^! 9 11 9^ . fiRO uo ^ 550 5"^ J Jy • J J J550Jy n'^ % UJ . 00U^ -1 9'701 94 1 nnn 9S7 QQ

1

1 9 44fi 54R R4 54ft 44 . 07U / — 1

1 • z9700 /uy 9^ 1 nnn 9 5fi 1 5n 19 4 15 54 7 47 54ft 94 - 1

4

-1 71

M

1 nnn OCT 1 c;n

. -) / 3^U 191 ^ . 970 Z /U c^A 1 A7 J't 1 .oz — . 1 H

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7

— 1 . zyo / 94 1 nnn 9fi7 7'^7 ^5Qn7 19 155 5'^fi 0 1 5^ 5 ftn .UH04 _i xocjc;

1 • D£- J J 9^ 1 nnn 9fift .

1

1 -JU 5n ^57fi9 19 1 9fi 1 ^ . 1 ^U 5'^4 79 5'^ JJ) 5J» 95 - 1

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. I u -11 ^9ft1 . jzo

1

1 . 000 970 ^ / u . nnn uuu ^51 1 1 1 9 07^ 5'^9 40 5'^9 7ft - . 07u / -1 "'I'^Ofi I . jy u 95 1 .nnn 973 i~ 1 J • 11 -'U 50 ^4nn4 1 1 0R9 59R "^7 59ft 5"^ - 0"^ -1 "^fiOl 24 1 .000 277.971 .32309 1 1 .837 52 1 . 9 7 -'t. 57 11 . ony\j . niU 1 -11 . -J^o'^o yJ y 25 1 .000 278. 1 50 .32246 1 1 .828 59 1 5R 59 1 fi5 - . 01u 1 -1 '^059 1 9 ^y Jc. 20 1 .000 280.000 .3 1 595 1 1 .762 518.68 51 9.05 -.07 -1 .4090

25 1 .000 283. 1 50 .30487 1 1 .670 514 61 514 57 . 01U 1 16 1 .000 283.200 .30470 1 1 .563 514.30 514.50 -. 04 -1 .4341

24 1 .000 287. 784 . 28858 1 1.518 507.93 507.84 .02 - 1 .4729

25 1 .000 288. 1 50 .28729 1 1 . 507 507.43 507.30 .02 -1 .4762

25 1 .000 293. 150 .26971 1 1 .338 499. 97 499. 81 .03 -1 .5232

15 1.000 293. 190 .26957 1 1 .336 499.90 499.74 .03 -1 .5236

25 1 .000 298. 1 50 .25213 11 . 1 64 492.30 492.06 .05 -1 .5757

16 1 .000 303. 1 50 .23455 1 0.983 484.30 484.04 .05 -1 .6345

25 1 .000 303. 1 50 .23455 1 0.981 484.23 484.04 .04 - 1 . 534 5

16 1 .000 3 13. 1 20 . 1 9949 1I 0.600 \J 9\J \J\J 467.44 467.07 .08 -1 .7764

25 1 .000 31 3. 1 50 . 19938 1 0. 586 466.81 467.01 -.04 -1 .7759

16 1 .000 323. 1 20 . 1 54 32 10. 1 76 448.73 448.40 .07 -1 .9663

25 1 .000 323. 1 50 . 1 6422 1 0. 1 72 44RO . ^U5fi 44R "^4

. 05U J -1 .9670

16 1 .000 333. 1 1

0

.12919 9.714 49R ^fi A71/ . _/u 5n • z.70u -2 .2360

95 1 nnn ^^^ 1 5n 1 9Qn5 0y fiOfi . u^D 497 57 497 4 1 . 04UH -9 7^7'^

\ \> 1 nnn D"iD . UOU 004 1 0 1 l^7 40^ 7R 40'^ 4UJ 9fl . ZO .

1

1 9Z -9Z fi5ft7 . 0 JO 1 9*^ ^ J 1 nnn OQTQQ Q 1/1/1 /lO'^ 99 ACiX hu no J. uy . 07U-J —9— «POf\ Z . DOZD

1 o 1 nnn J40 . UOU .U lOJJ 0.0 JC) joy TOO 7/1

. /

4

TftQ 99 _>oy . zz 1 t; . 1 J—9—Z .yO'+U QR40

1 nnn 07fi^ 1 0 . 0/-J joy • 1

0

TQQ n 1 _>oy.u 1 OA _9— z . 0R04 y oy*t 16 1.000 353.090 .05894 8.459 373.45 373.16 .08 -3.4619

25 1.000 353.150 .05872 8.458 372.97 372.95 .01 -3.4691

11 fiu 1

1 . nnn uuu J -^O 5ft . inn 1 uu ft 099 "^SA 09 - . ORUO -4 95'^fi 25 1.000 358. 150 .041 14 8.020 353.56 353.81 -.04 -4.2643

16 1.000 363.1 10 .02370 7.459 328.90 329.17 -.08 -5.9214

25 1.000 363.150 .02356 7.450 328.52 328.93 -. 12 -5.9427

25 1.000 365. 150 .01653 7. 145 315. 12 315.75 -.20 -7.3725

25 1.000 367.150 .00949 5.756 297.92 298.45 -.18 -10.3851

16 1.000 368.100 .00615 6.488 286. 10 287.23 -.39 -13.6269

25 1.000 368. 150 .00598 6.485 285.97 285.54 -.20 -13.8779

16 0.000 369.100 .00254 6.080 268.10 269.86 -.65 -23.3214

25 1.000 369. 150 .00246 6.082 268.20 268.67 -.18 -24.3714

16 0.000 369.600 .00088 5.669 250.00 253.99 -1 .57 -47.1839

1 0.000 194.950 .61502 14.146 623.80 621.07 .44 -1.0676

61
Table 2. (Continued).

Data sources and ID numbers; (l)Maass, (2)Van der Vet, (3)NGAA, (4)Sage, (6)Reanier, (7)Clegg,

{8)Francis, (ll)Seeman, ( 12)Helgeson, (13)Klosek, (14)Shana'a, (15)Jensen, ( 16)S I i wl nski

,

( 17)Toml inson, (18)Kahre, ( 19)Rodosev ich , (20)Haynes, (21 )Deschner , (22)Orrit, (23)McClune,

(24)Ely, (25)Thomas, (34)Carney, (36)Dana.

ID We ight Temp. (Tc-T)/(Tc-Tt) Dens i ty ( expt) Density (calc) Di ff. dPn/dT

X,

l\ mo 1 / L Kg/fTi-'

X. kg/mJ % Kg/ ( m9«i\

)

1 0.000 O A yi OCA 204. 850 C 0 AO 1 . 5802

1

1 "z 000 1 3.880 1 0 yl A 612.40 yT 1 A yl 1 510.41 .33 -1 . 0872

0.000 209.950 .56228 1 "z ~r /I A 13.749 606. 30 604.84 .24 -1 .0987

0. 000 O 1 "Z C CA 213.550 . 54927 1 "Z c1 3«o55 602.20 CAA T C 500.75 .24 -1 . 1077

A AAA 0. UOU zi 4.450 C y: yl C .54545 Cf\ 1 Z A 501 .30 CAA 0 ~7 599.87 • 24 -1.1 097

]

A AAA 0 . 000 O 1 A O CA CO "7 y? ^

• 52 /45 C A C ~7A 595. /U CAT 0 yi 593.84 T 1 • 31 1 1 0 yl 1 -1 . 1241 A A A^~i 0. 000 oo C OAA 225. 200 C AOiC C CO A 0 A 5139.20 587.78 .24 -1 . 1397

A AAA 0.000 00"7 OCA /.iL 1 .25U CA 1 yl yl . 50 1 44 1 "z Tr\c\ 13.309 c 0 yr A A 5o5.yU 585.44 o25 - 1 . 1451 0.000 230.750 ^ 0 A 1 "Z .4oy 1

3

13»2z3 583. 1

0

58 1 .4

1

.29 -1 . 1 574

A AAA 0. 000 O "Z ^ yl C A 234.4 50 yl "7 1 0 .4/512 it: 1 1 yt

1 3o 1 14 C~7 0 'Z A 5/8.30 C~7 T 1 A 577. 10 .21 -1 . 1700

A AAA 0.000 0*2 0 OAA 23o.oU0 yl c AO "z .450o3 1 "z n n c

1 3.005 573. 50 571 .98 .27 -1 . 1859

A AAA 0. 000 O /I "Z A C A 243.050 ;! yl C 00 «445oo 10 0 no

1 z.oyz 568. 50 565.90 .28 -1 .2025

0.000 O yl o ^ c A 248.650 .4261

9

1 0 ~7"Z "Z 12.733 561 .50 550. 10 .25 -1 .2253

Z. A AAA O Q "Z 1 CA Zo3. 1 PO "Z A/1 .3040

/

1 1 . 0 /y C 1 C AA 5 1 5. UU c 1 yl c~7 514.5/ AO .08 -1 .4337

Z. A AAA 0.000 OA'Z 1 CA zy3. 1 5U .Z5y/1 11 "Z yl 01 1 .34o CAA yl A 500.40 / A A 01 499.0

1

1

0

. Iz -1 .5232

/

A AAA OQO 1 CA zyo. 1 5U 9 C9 1 "Z .zpz Ij 11 1 7Q 1 1 • 1 /o A 9 A A 4yz . yu yl 09 AC 4yz.U5 1 -7 • 1 /

1 C "7 C "7 -1 .5/5/

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A AAA U.UUU ZA'Z 1 c;a

_)U_) . 1 DU 9 "Z / c c .Z J4 J

J

1 A OQ/1

1 u. yy4 yl Dyi QA 404 • oU AQA A/I 4o4 .U4 1 c • 15 1 C"Z yl c -1 .5349

oz. A AAA U.UUU z A Q 1 C^A jUtS. 1 DU »z 1 oyo 1 A Q 1 "Z

1 U»o 1

J

>1 7A DA 4 /O.OU yl ~7 C "7A 4 /P. /U O'X *Z3 1 ~7A 1 A -1 . /OlO

A. A AAA U.UUU "Z 1 "Z 1

c; A _) 1 J. 1 3U 1 QQZ Q . 1 yyj)o 1 A ^AQ 1 u.ouo yl A 7 Q A 40 /.oU yl C7 A 1 40 / . U

1

1

7

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6. u. UUU X 1 D 1 c;n J 1 0 . 1 3U 1 1 en 0 1 0 1 OU in A AG 1 u.4uy yl C A AA 43y. UU yl C7 Q

1

4 3 / . y 1 OA 1 Q cyi c -\ .0549

U. UUU zo-z 1 CA J)Z J. 1 J\j . 1 D4ZZ 1 n 1 f(9

1 u. 1 oz 44y yl yl Q nn . UU 440 AAQ XA . _)4 . 1 9 — 11 . QC7n yo /u

1.D U. UUU o-iA 7Af; Z_>U. /UD * 4oyzy 1 J.ZUJ c D9 9A DOZ • ZU 90 1. 4D 1 'Z _ 1 1 C79

J U. UUU o^z; QOQ Z J J . 7Z0 4 77Qfi 1 ^. 1 1

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C7P yl A 9 /O . 4U R77 7

1

9 / / . / 1 1 9 • 1 Z

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1 9Z . Qn'^ 7 U-? CCQ AA ZJoy . UU - CCQ ZQ 9D0.^0 1 1 -1I . 1Q7fi 1 y / 0 nU . nnn UUU 7/1C Q17 « 4 J)0 1

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191 Z.Ofl 1

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CC -z CC 909 . 90 • 97Z / - 1

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1 Z . / 1 _> CCA C A 90U • DU 9DU. CCA 1 71 / nfl • uo —1— 99fin 1 . ZZDU

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1 9 "^IQQ CC C CA Z)39.0U 999. UZ in • 1 u

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1 .Z49 1 J nU e nnn UUU occ ^79 /I A9CC 1

1 Z.9 9ZZ R99 CC9 9 A 99 1 7fi 1 . /

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1 A ~7 AO 10. /Uo yl "70 OA 4 /Z.2U A ir\ AO 4 /U.92 0'7

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XJ A AAA U.UUU "ZX Z 1 C A 333. 1 5U 1 0 A A C

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A AAA U.UUU "ZA1 AO/ ju 1 . uy4 0/1 1 "7D .Z4 1 /o 11 1 yl "Z 11.1 43 yt A 1 "z c 4y 1 .35 yi Q"7 X~I 4o / .3 / Q 9 .oZ - 1 CAA/ 1 . ouy4

AH A AAA U. UUU "Z A"7 AQX jU / .4oj 0 1 0^ 1 . z 1 y3

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1 A Q AA lu.cjyy /OA C A 4oU. 5U yl "7 C Q'Z 4 /5.o3 70 . /y - 1 .5y 1

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A4 A AAA U.UUU "Z 1 "Z "Z 1 "7 313.31 /

1 n 0 ~7 A

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A4 A AAA O.UOU "Z 1 0 C A yl 318. 594 1 0 AO /I . 18024 10.455 46 1 .49 457.09 AC .96 -

1 0 70A 1 .0 /zy 4

A AAA U.OUU Z 0 Z "Z ~7 1 . 1 6344 10.276 453. 1

4

447.91 1.17 -1 .971

9

4 A AAA U.UUU 3z / .y2o 1 yl "7 yl 0

. 1 4 /42 1 A A 0 0

1 0.088 444 . 84 438.68 1 .40 0 A 0 'Z 1 -2.0831

4

A AAA 0. OUU Z Z 0 AA i1 332.094 1 "Z 0~7 "7 . 1 327 / A A A'Z 9.905 436.71 429. 75 1

1 aOZ 0 0 A'Z Z -2 .zU33

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A AAA U. UUU XX An yi 3jD.Uy4 1 1 Q ~7A m\ 1 0 /O 9. 705 427.96 420.67 1 .73 0 "Z yl 1 A -2.3410

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A AAA U. UUU 'Z'ZA 0~70 339.0 /2 1 A C yl 0

. 1 0542 9. 504 yl 1 A 11 419.1

1

41 1 .54 1 0 yl 1 .84 ~2 .4978

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A AAA U.UUU "z>i "z yi Q'z j4j.4o3 A AO "70 .oyz /2 A 0 AO 9.298 409.99 402.20 1 Ay!

1 .94 0 c 0 1 1 -Z.5ol

1

4 A AAA 0. UUU X A AO 0 34o.y2o .08060 9.088 400.76 392 .61 2.08 0 0 A 0 0 -2 .8988

A4

A AAA O.UOU "Z CA An yl 35U.Uy4 .06947 8.884 391 .75 383.04 2.27 -3. 1 522

4

A AAA U.UUU Z C "Z AA j1 353. Uy4 .05892 8.568 382.21 373. 14 0 AT 2.43 -3.4624

4 0.000 355.872 .04915 8.456 372.87 353.02 2.71 -3.8440

4 0.000 358.594 .03958 8.228 362.82 351.89 3.10 -4.3522

4 0.000 361.261 .03020 7.973 351.59 339.33 3.61 -5. 1 198

4 0.000 363.761 .02141 7.708 339.88 325.19 4.52 -5.2966

4 0.000 366.261 .01262 7.406 326.58 306.88 5.42 -8.7034

4 0,000 368.761 .00383 7.009 309,06 276.85 n.63 -18.3934

6 0.000 313.480 .19822 10.609 467.82 466.43 .30 -1.7822

6 0.000 324.480 .15954 10.141 447.20 445.71 .33 -1.9973

6 0.000 332.040 ,13296 9.778 431 .19 429.87 .31 -2.2015

6 0.000 339.590 . 1 054

1

9.395 414.31 412.25 .50 -2.4850

6 0.000 346.430 .08235 8.975 395.75 394.04 .43 -2.8542

6 0.000 352.710 .06027 8.524 375.88 374.46 .38 -3.4178

62
Table 2. (Continued).

Data sources and ID numbers: (l)Maass, (2)Van der Vet, (3)NGAA, (4)Sage, (6)Reamer, (7)Clegg,

(8)Francis, (ll)Seeman, ( 1 2)He I geson , (13)Klosek, (14)Shana'a, (15)Jensen, ( 1 6) S li w I nski

,

( 17)Tomi inson, (18)Kahre, ( 19)Rodosevich, (20)Haynes, (21 ) Deschner , (22)0rrit, (23)McClune,

(24)Ely, (25)Thomas, (34)Carney, (36)Dana.

ID We i ght Temp

.

^ ' C ' ' ^ c T Dens i ty ( expt) Dens 1 ty ( ca 1 c

)

Di f f

.

d Pj^/d T K mol/L kg/m3 kg/m3 $ kg/(m3.K)

6 0.000 358.260 .04076 8.036 354.37 353.34 .29 -4.2880

6 0.000 363.590 .02201 7.471 329.46 326.26 .98 -6. 1918

6 0.000 368.370 .00520 6.632 292.45 283.35 3.21 -15.1457

7 0.000 323. 150 .16422 10.150 447.59 448.34 -. 17 -1.9670

7 0.000 333. 150 .12905 9.550 421.13 427.41 -1.47 -2.2373

7 0.000 343.150 .09389 8.980 395.99 403.09 -1 .76 -2.6626

7 0.000 348. 150 .07631 8.630 380.56 389.01 -2. 17 -2.9894

7 0.000 353.150 .05872 8.300 366.01 372.95 -1 .86 -3.4691

7 0.000 358. 150 .041 14 7.860 346.60 353.81 -2.04 -4.2643

7 0.000 363. 150 .02356 7.320 322.79 328.93 -1.87 -5.9427

7 0.000 368. 150 .00598 6.410 282.66 286.54 -1 .35 -13.8779

8 0.000 293. 1 50 .26971 1 1.350 500.50 499.81 .14 -1 .5232

1

0.000 278. 160 .32242 1 1 .851 522.60 521.63 . 19 -1 .3953

10.000 283. 140 .30491 1 1 .686 51 5.30 514.59 .14 -1 .4336

1

0.000 285. 150 .29432 1 1.586 51 0.90 51 0.24 . 13 -1 .4587

1

0.000 289.160 .28374 1 1.482 506.30 505.81 .10 -1.4853

1

0.000 293. 1 50 .26971 1 1.342 500. 15 499.81 .07 -1 .5232

1

0.000 295.150 .26268 1 1.271 497.00 496.74 .05 -1 .5435

10.000 297. 150 .25564 1 1.200 493.90 493.63 .05 -1 .5647

1

0.000 299.180 .24851 1 1.125 490.60 490.43 .03 -1 .5872

12 0.000 277.594 .32441 1 1 .891 524.34 522.42 .37 -1 .391

12 0.000 283. 1 50 .30487 11.718 516.73 514.57 .42 -1.4337

12 0.000 288.706 .28534 1 1.532 508.52 506.48 .40 -1.4812

12 0.000 294.261 .26580 11.345 500.27 498.1

.43 -1.5344

12 0.000 299.817 .24627 n . 1 39 491.21 489.42 .37 -1 .5945

12 0.000 305.372 .22673 10.935 482.19 480.37 .38 -1 .6630

12 0.000 310.928 .20719 10.722 472.80 470.92 .40 -1 .7418

12 0.000 316.483 .18766 10.484 462.29 461.00 .28 -1 .8338

12 0.000 322.039 .16812 10.241 451 .60 450.52 .24 -1.9427

12 0.000 327.594 .14859 9.985 440.31 439.37 .21 -2.0742

12 0.000 333. 150 .12905 9.713 428.30 427.41 .21 -2.2373

12 0.000 338.706 .10952 9.423 415.52 414.43 .27 -2.4461

12 0.000 344.261 .08998 9.095 401.06 400.10 .24 -2.7261

12 0.000 349.817 .07044 8.697 383.49 383.91 -.11 -3.1274

12 0.000 355.372 .05091 8.235 363.15 364.92 -.49 -3.7665

12 0.000 360.928 .03137 7.757 342.06 341.01 .31 -5.0051

13 0.000 88.706 .98862 16.542 729.45 730.00 -.08 -1.0284

13 0.000 94.261 .96909 16.420 724.07 724.30 -.03 -1 .0242

13 0.000 99.817 .94955 16.296 718.61 718.62 -.00 -1.0206

13 0.000 105.372 .93002 16.168 712.95 712.96 -.00 -1.0176

13 0.000 1 10.928 .91048 16.042 707.39 707.32 .01 -1 .0153

13 0.000 1 16.483 .89095 15.914 701.76 701 .68 .01 -1 .0136

13 0.000 122.039 .87141 15.787 696. 16 696.05 .02 -1 .0125

13 0.000 127.594 .85187 15.656 690.37 690.43 -.01 -1 .0121

13 0.000 133. 150 .83234 15.525 684.62 684.81 -.03 -1.0123

15 0.000 93 . 1 50 .97299 16.446 725.20 725.44 -.03 -1 .0250

15 0.000 103. 150 .93783 16.212 714.90 71 5.22 -.05 -1 .0188

1

5

0.000 1 13. 150 .90267 15.967 704.10 705.06 -. 14 -1 .0145

15 0.000 123. 150 .86750 15.743 694.20 694.93 -.10 -1 .0123

15 0.000 133. 1 50 .83234 15.516 684.20 684.81 -.09 -1 .0123

17 0.000 278,150 .32246 11.835 521 .90 521 .65 .05 -1 .3952

17 0.000 283.150 .30487 11.679 515.00 514.57 .08 -1 .4337

17 0.000 288. 150 .28729 11.513 507.70 507.30 .08 -1 .4762

17 0.000 293.150 .26971 11.345 500.30 499.81 .10 -1 .5232

17 0.000 298. 150 .25213 11.171 492.60 492.06 .11 -1.5757

17 0.000 303.150 .23455 10.989 484.60 484.04 .12 -1 .6345

17 0.000 308.150 .21696 10.803 476.40 475.70 .15 -1.7010

17 0.000 313.150 .19938 10.608 467.80 467.01 .17 -1 .7769

18 0.000 277.550 .32457 1 1.850 522.55 522.48 .01 -1.3908

18 0.000 288.750 .28518 11.491 506.70 506.41 .06 -1 .4816

18 0.000 299.850 .24615 11.110 489.90 489.37 .11 -1 .5949

18 0.000 310.950 .20712 10.696 471.65 470.88 .16 -1.7422

63
Tabl e 2. (Continued)

Data sources and ID numbers: (l)Maass, (2)Van der Vet, (3)NGAA, (4)Sage, (6)Reamer, (7)Clegg

(8)Francis, (ll)Seeman, ( 1 2)Hel geson , (13)Kiosek, ( 14) Sliana' a, (15)Jensen, ( 16) S I i wi nski

,

( 17)Toml inson, (18)Kahre, ( 19)Rodosevich, (20)Haynes, ( 21 ) Deschner , (22)0rrit, (23)McClune,

(24)Ely, (25)Thomas, (34)Carney, (3&)Dana.

ID We i g ht Temp

(T -T)/(T^-T+) Dens i ty ( expt) Density (calc) Di f f

dPj^/dT K mol /L kg/m3 kg/m3 % kg/(m3.K)

18 0.000 327,550 . 14874 9.941 438.35 439.46 -.25 -2.0731

20 0.000 288.706 .28534 1 1 .479 506. 19 506.48 -.06 -1 .4812

21 0.000 303» 1 50 .23455 1 1 .017 485.82 484.04 .37 -1 .6345

21 0.000 308. 1 50 .21696 10.851 478.50 475.70 .59 -1 .7010

21 0.000 313. 150 . 19938 1 0.692 471 .49 467.01 .96 -1 .7769

21 0.000 318. 1 50 .18180 10.500 463.02 457.91 1.12 -1 .864 5 21 0.000 323. 1 50 . 16422 10.302 454,29 448.34 1 .33 -1 .9670

21 0.000 328. 150 .14663 10.075 444.28 438.21 1.38 -2.0890

21 0.000 333. 1 50 .12905 9.842 434,00 427.41 1 .54 -2.2373

21 0.000 338.150 .1 1 147 9.570 422.00 415.78 1 .50 -2 .4226

21 0.000 543. 150 .09389 9.252 408.00 403.09 1 .22 -2.6626

21 0.000 348.150 .07631 8.896 392.30 389.01 .85 -2.9894

2! 0.000 353. 150 ,05872 8.527 376,00 372.95 .82 -3.4691

21 0.000 358.150 .04114 8.078 356.20 353.81 .68 -4.2643

21 0.000 363.150 .02356 7.529 332.00 328.93 .93 -5.9427

21 0.000 368.150 .00598 6.644 293.00 286.54 2.25 -13.8779

34 0.000 227.594 .50023 13.284 585.80 585.04 ,13 -1,1471

34 0.000 233, 150 ,48069 13.139 579.40 578.62 .14 -1 ,1655

34 0.000 238,706 .461 16 12.990 572.80 572.09 .12 -1, 1856

34 0,000 244.261 ,44162 12.835 566.00 565.44 .10 -1,2075

34 0.000 249.817 .42209 12.681 559.20 558.67 .10 -1,2315

34 0.000 255.372 .40255 12.522 552.20 551.76 .08 -1.2577

34 0.000 266.483 .36348 12.209 538.40 537.46 .18 -1.3180

34 0.000 277. 150 .32597 11.883 524.00 523.04 .18 -1.3879

34 0.000 288,706 .28534 11.504 507.30 506.48 . 16 -1.4812

34 0.000 310.928 .20719 10.708 472.20 470.92 .27 -1 .7418

34 0.000 322,039 . 16812 10.273 453.00 450.52 .55 -1.9427

34 0.000 333.150 .12905 9.783 431.40 427,41 .93 -2.2373

JO 1

1 7£, n'^'^ . yj-jj ^JU , ou

36 0.000 278.150 .32246 1 1.878 523,80 521,65 .41 -1 .3952

36 0.000 283. 150 .30487 1 1 . 720 516,80 514,57 .43 -1.4337

36 0.000 290. 150 .28026 1 1 .482 506,30 504.33 .39 -1 .4944

36 0,000 293.150 .26971 1 1.389 502,20 499.81 .48 -1 .5232

36 0.000 297.150 ,25564 11.248 496,00 493.63 .48 -1,5647

36 0.000 300.150 ,24509 1 1 . 1 53 491.80 488.89 .60 -1.5984

36 0.000 315.150 .19235 10.577 466.40 463.43 .64 -1.8103

36 0.000 321.150 .17125 10,091 445.00 452.23 -1 .60 -1.9239

36 0.000 323.150 .16422 10.232 451 .20 448.34 .64 -1.9670

36 0.000 327.150 .15015 10.046 443.00 440.29 .62 -2.0627

36 0.000 329.150 .14312 9.958 439. 10 436.1.69 -2.1 163

Number of data points used in f it = 120; rms dens i ty deviation = 0,074^.

64
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67
Table 4. Comparisons of virial coefficients with eq (5).

Second virial coefficients of propane

Data sources and ID numbers ( I )McGI ashan , (2)Kapallo, (3)Dymond/Smith , (4)Strein, (5)Hahn

(7)Gunn, (8)Brewer, (9)Beattie, ( 10) Bottom ley, (ll)Cherney, ( 12)Deschner , (13)Jessen,

( 14)Kretschmer , {15)Reamer, (16)Sage.

ID Weight Temp. T/Tc B Bp(expt) Buccal c) Di ff

.

Diff

.

K cm3/mo 1 %

5 .146 21 1.300 .5713 -844.00 -4.2200 -4. 1843 -.0357 -.85

5 .464 231 .200 .6251 -680.00 -3.4000 -3.4051 .0051 .15 2 .095 244.000 .6597 -610.00 -3.0500 -3.0159 -.0341 -1.13

8 .418 248. 150 .6709 -579.00 -2.8950 -2.9043 .0093 .32

5 .332 251.500 .6800 -567.00 -2.8350 -2.8188 -.0162 -.58

3 .470 260.000 .7030 -526,00 -2.6300 -2.6184 -.01 16 -.44

3 .209 270.000 .7300 -478.00 -2.3900 -2.4093 ,0193 .80 2 .082 273.000 .7381 -477.00 -2.3850 -2.3516 -.0334 -1.42

8 ,574 273. 150 .7385 -468.00 -2.3400 -2.3488 .0088 .37

13 .976 273. 160 .7386 -470.00 -2.3500 -2.3486 -.0014 -.06

5 .224 273.800 .7403 -471 .00 -2.3550 -2.3366 -.0184 -.79

3 .206 285.000 .7706 -424.00 -2. 1200 -2.1406 .0206 .96

16 .012 294.270 .7956 -4 17.56 -2.0878 -1 .9966 -.0912 -4.57

10 .029 295.210 .7982 -407.90 -2.0395 -1.9828 -.0567 -2.86

1 .274 295.400 .7987 399.00 -1 .9950 -1 .9801 -.0149 -.75

4 .434 296. 100 .8006 -396.00 -1 .9800 -1.9699 -.0101 -.51

2 .326 297.000 .8030 -394.00 -1 .9700 -1.9570 -.0130 -.66

8 .995 298 . 1 50 .8061 -388.00 -1.9400 -1.9407 .0007 .04

3 .359 300.000 .8111 -380.00 -1.9000 -1 .9149 -0149 .78

12 .059 303. 160 .8197 -382.04 -1.9102 -1 .8719 -.0383 -2.05

12 .039 303.160 .8197 -384.00 -1 .9200 -1 .8719 -.0481 -2.57

14 .009 303.160 ,8197 -395.00 -1.9750 -1.8719 -.1031 -5.51

1 .225 306.500 .8287 -369.00 -1.8450 -1 .8281 -.0169 -.93

4 .818 308.000 ,8328 -360.50 -1.8025 -1 ,8089 .0064 .35

7 .012 310.900 .8406 -335.80 1.6790 -1 ,7727 .0937 5.28

15 .011 310.940 .8407 -335,49 -1,6775 -1.7722 .0947 5,34

15 .007 310.940 .8407 -330,00 -1 .6500 -1 .7722 .1222 6.89

16 .005 310.940 .8407 -381,80 -1.9090 -1.7722 -.1368 -7.72

3 .270 315.000 .8517 -341.00 -1 .7050 -1 .7232 .0182 1.06

1 .870 317.600 .8587 -339,00 -1.6950 -1.6930 -.0020 -.12

2 .043 321.000 .8679 -340,00 1.7000 -1 .6546 -.0454 -2.75

11 .214 323. 160 ,8738 -329,62 -1.6481 -1.6308 -.0173 -1.06

13 .866 323. 160 ,8738 -325,00 -1.6250 -1 .6308 ,0058 .36

1 .064 327.600 .8858 -324.00 -1.6200 -1.5836 -.0364 -2.30

15 .033 327.600 .8858 -305.44 -1 .5272 -1 .5836 ,0564 5.56

15 .036 327.600 .8858 -306.00 -1.5300 -1.5836 .0536 3.39

16 .003 327.600 .8858 -353.45 -1.7673 -1 .5836 -.1836 -1 1 .60 3 .671 330.000 .8923 -310.00 -1 .5500 -1.5589 .0089 .57 4 .255 332.900 .9001 -309.00 -1 .5450 -1 .5298 -.0152 -.99

1 .325 337.800 .9133 -299.00 -1.4950 -1.4825 -,0125 -.84

15 .191 344.270 .9308 -280. 15 -1 .4008 -1 .4232 .0224 1.58

15 .230 344.270 .9308 -280.60 -1.4030 -1 .4232 .0202 1.42

16 .004 344.270 .9308 -316,71 -1.5836 -1 .4232 -. 1604 -1 1.27 7 .216 344.300 .9309 -280.40 -1.4020 -1.4229 .0209 1.47

1 .207 347.900 .9407 -274.00 -1.3700 -1 .3914 .0214 1.54

12 .029 348. 160 .9414 -289. 13 -1.4457 -1.3892 -.0564 -4.06

12 .016 348. 160 .9414 -293.00 -1 .4650 -1.3892 -.0758 -5.46

3 .901 350.000 .9463 -275.00 -1.3750 -1.3735 -.0015 -.11

4 .285 353.800 .9566 -271.20 -1 .3560 -1.3420 -.0140 -1 .05

1 .242 357.900 .9677 -265.00 . -1.3250 -1.3091 -.0159 -1.22

15 .897 360.940 .9759 -256.06 -1 .2803 -1 .2854 .0051 .40

15 .999 360.940 .9759 -256.80 -1.2840 -1.2854 .0014 .11 16 .005 360.940 .9759 -283.74 1 .4187 -1.2854 -. 1333 -10.37

1 .513 368.200 .9955 -244.00 -1.2200 -1.2314 .01 14 .92 9 .461 369.970 1.0003 -245.58 -1 .2279 -1.2187 -.0092 -.76

9 .014 369.970 1 .0003 -260.00 -1.3000 -1.2187 -.0813 -6.67

9 .326 373. 160 1.0089 -241.82 -1 .2091 -1 .1963 -.0128 -1 .07

9 .058 373.160 1.0089 -247.00 -1.2350 -1. 1963 -.0387 -3.24

11 .734 373. 160 1.0089 -240. 15 -1 .2008 -1 .1963 -.0045 -.37

12 .075 373. 160 1.0089 -245.98 -1 .2299 -1.1963 -.0336 -2.81

12 .014 373.160 1.0089 -256.00 -1.2800 -1 . 1963 -.0837 -7.00

4 .248 373.400 1,0096 -242. 10 -1.2105 - 1 . 1 946 -.0159 -1.33

68
Table 4. (Continued).

Second virial coefficients of propane

Data sources and ID numbers; ( 1 )McGI ashan , (2)Kapallo, ( 3)Dymond/Sm i th , (4)Strein, (5)Hahn,

(7)Gunn, (8)Brewer, (9)Beattie, ( 10)Bottomley, (IDCherney, ( 12)Deschner , (13)Jessen,

( 14)Kretschmer , (15)Reamer, (16)Sage.

ID We ight Temp. T/Tc B Br(expt) Br.(cal c)

r Di ff

.

Diff.

K cm3/mol %

3 .923 375.000 1.0139 -237.00 -1.1850 -1 .1836 -.0014 -.12

7 .310 377.600 1 .0210 -235-90 -1.1795 -1. 1661 -.0134 -1. 15

15 .492 377.600 1.0210 -234.95 -1.1748 -1. 1661 -.0087 -.74

15 .586 377.600 1 .0210 -234.60 -1.1730 -1. 1661 -.0069 -.59

16 .008 377.600 1.0210 -254.72 -1 .2736 -1 .1661 -.1075 -9.22

1 .218 377.700 1.0212 -229.00 -1.1450 -1. 1654 .0204 1.75

12 .266 380.960 1.0300 -225. 18 -1 .1259 -1 .1439 .0180 1.57

1 . 100 388.500 1.0504 -213.00 -1.0650 -1 .0963 .0313 2.85

4 .709 394.000 1.0653 -213.70 -1 .0685 -1 .0633 -.0052 -.49

9 .908 398. 160 1.0765 -208.26 -1.0413 -1.0392 -.0021 -.20

9 .260 398. 160 1.0765 -21 1.00 -1 .0550 -1.0392 -.0158 -1 .52

11 .959 398.160 1.0765 -207.21 -1.0361 -1.0392 .0031 .30

12 .460 398. 160 1 .0765 -209.79 -1 .0490 -1 .0392 -.0098 -.94

12 .015 398. 160 1.0765 -224.00 -1.1200 -1.0392 -.0808 -7.78

3 .952 400.000 1.0815 -206.00 -1.0300 -1 .0288 -.0012 -.12

1 . 169 400. 100 1 .0818 -201.00 -1.0050 -1 .0282 .0232 2.26

15 .125 410.940 1.1111 -199.07 -.9954 -.9697 -.0256 -2.64

15 .106 410.940 1.1111 -199.60 -.9980 -.9697 -.0283 -2.92

4 .987 413.800 1.1188 -191.10 -.9555 -.9551 -.0004 -.05

9 .987 423. 160 1. 1441 -181.48 -.9074 -.9090 .0016 .16

9 .706 423. 160 1.1441 -183.00 -.9150 -.9090 -.0060 -.65

12 .111 423. 160 1.1441 -187.36 -.9368 -.9090 -.0278 -3.05

12 .017 423.160 1. 1441 -197.00 -.9850 -.9090 -.0760 -8.36

3 .914 430.000 1 . 1 626 -176.00 -.8800 -.8773 -.0027 -.31

4 1 .000 433.100 1.1710 -172.60 -.8630 -.8633 .0003 .04

15 .147 444.270 1 .2012 -167.93 -.8397 -.8155 -.0241 -2.96

15 .125 444.270 1.2012 -168.40 -.8420 -.8155 -.0265 -3.25

7 .207 444.300 1.2013 -167.00 -.8350 -.8154 -.0196 -2.41

9 .903 448.160 1 .21 17 -159.30 -.7965 -.7996 .0031 .39

9 .999 448.160 1.21 17 -160.00 -.8000 -.7996 -.0004 -.04

4 .953 453.500 1.2262 -156.20 -.7810 -.7785 -.0025 -.32

3 .909 470.000 1.2708 -143.00 -.7150 -.7175 .0025 .35

9 .669 473.160 1.2793 -140.04 -.7002 -.7065 .0063 .89 9 .400 473. 160 1.2793 -139.00 -.6950 -.7065 .0115 1.62

12 .100 473. 160 1.2793 -147.44 -.7372 -.7065 -.0307 -4.35

12 .021 473. 160 1.2793 -155.00 -.7750 -.7065 -.0685 -9.70

4 .983 474.900 1 . 2840 -140.00 -.7000 -.7005 .0005 .07

15 .315 477.600 1.2913 141 .40 -.7070 -.6914 -.0156 -2.26

15 .241 477.600 1.2913 -142.00 -.7100 -.6914 -.0186 -2.70

4 .971 493.300 1 . 3338 -128.10 -.6405 -.6410 .0005 .07

9 .297 498. 160 1 .3469 -122.45 -.6123 -.6262 .0140 2.23

9 .163 498.160 1.3469 -121 .00 -.6050 -.6262 .0212 3.39

3 .658 500.000 1.3519 -123.00 -.6150 -.6208 .0058 .93

7 .787 510.900 1.3814 -1 17.20 -.5860 -.5895 .0035 .59

15 1.000 510.940 1 .3815 -1 18.19 -.5910 -.5894 -.0016 -.27

15 .868 510.940 1.3815 -1 19.00 -.5950 -.5894 -.0056 -.95

9 .471 523. 160 1 .4145 -109.57 -.5479 -.5564 .0086 1 .54

9 .356 523. 160 1.4145 -109.00 -.5450 -.5564 .01 14 2.05

12 .902 526.380 1 .4232 -110.70 -.5535 -.5481 -.0054 -.99

12 .490 526.380 1.4232 -108.00 -.5400 -.5481 .0081 1 .48

9 .498 548 . 1 60 1.4821 -97.55 -.4878 -.4952 .0074 1.50

9 .240 548. 160 1.4821 -96.00 -.4800 -.4952 .0152 3.06

3 .574 550.000 1.4871 -97.00 -.4850 -.4910 .0060 1.21

12 .51

1

570.460 1.5424 -91 .89 -.4595 -.4465 -.0129 -2.90

12 .821 570.460 1 . 5424 -89.00 -.4450 -.4465 .0015 .34

12 .040 609.320 1.6475 -85. 19 -.4260 -.3728 -.0532 -14.26

Number of data points = 118; rms deviation = 1.20^.

69
Table 4, (Continued).

Third virial coefficients of propane

Data sources and ID numbers: (1 )McGlashan, (2)Kapal lo. (3)Dymond/Smith, (4)Strein, (5)Hahn

(7)Gunn, (8)Brewer, (9)Beattie ( 10)Bottomley, (IDCherney, (12)Deschner , (13)Jessen,

(14)Kretschmer, ( 1 5)Reamer , (1 6 )Sage.

ID Wei gilt Temp. T/T_ C Cr.(expt) Cp(cal c) Dif f

.

K ( cm3 /mo 1 )

2

16 .002 294.270 .7956 -10510. -.2628 -2.4978 2.2350

12 .163 303.160 .81 97 -62760. -1 .5690 -1 .7060 .1370

15 .469 310.940 .8407 -54120. -1 .3530 -1 .1762 -.1768

15 .065 310.940 .8407 -65000. -1 .6250 -1 .1762 -.4488

16 .006 310.940 .8407 861. .0215 -1 . 1 762 1.1977

11 .755 323.160 .8738 -22470. -.5618 -.571

1

.0094

15 .329 327,600 .8858 -23530. -.5883 -.4044 -.1838

15 .523 327.600 .8858 -14000. -.3500 -.4044 .0544

16 .003 327.600 .8858 59710. 1 .4928 -.4044 1 .8972

15 .722 344.270 .9308 -1 725. -.0431 .0416 -.0848

15 .912 344.270 .9308 2000. .0500 .0416 .0084

16 .009 344.270 .9308 42550. 1 .0638 .0416 1 .0221

12 .023 348.160 .9414 29980. .7495 .1 141 .6354

15 .523 360.940 .9759 741 3. .1853 .2921 -.1068

15 .837 360.940 .9759 13000. .3250 .2921 .0329

16 .052 360.940 .9759 28280. .7070 .2921 .4149

9 .41 7 369.970 1 .0003 1 9450. .4863 .3751 .1112

9 .997 373.160 1 ,0089 15890, .3973 .3978 -.0006

11 .576 373. 160 1 .0089 191 20, .4780 .3978 .0802

12 .556 373.160 1 .0089 19260, .481 5 .3978 .0837

15 .453 377.600 1 .0210 1 2430, .3108 .4247 -.1 140

15 .207 377.600 1 .0210 90 00. .2250 .4247 -.1997

16 .751 377.600 1 .0210 14520. .3630 .4247 -.0617

12 .967 380.960 1 .0300 18290. .4573 .4417 .01 55

9 .469 398.160 1 .0765 15550. .3888 .4940 -.1053

1

1

.658 398.160 1 .0765 16920. .4230 .4940 -.071

0

12 .696 398.160 1 .0765 17160. .4290 .4940 -.0650

15 .992 410.940 1.1111 20000. .5000 .5060 -.0060

15_ .426 410.940 1.1111 25000. .6250 .5060 .1190

9 .357 423.160 1 .1441 14960. .3740 .5039 -.1299

12 .563 423.160 1 .1441 16800. .4200 .5039 -.0839

15 .995 444.270 1 .201

2

191 90. .4798 .4817 -.0020

15 .564 444.270 1 .2012 23000. .5750 .4817 .0933

9 .425 448.160 1 .21 17 1461 0. .3653 .4760 -.1108

9 .607 473.160 1 .2793 14370. .3593 .4339 -.0747

12 .774 473.160 1 .2793 15430. .3858 .4339 -.0482

15 .957 477.600 1 .2913 181 20. .4530 .4259 .0271

15 .535 477.600 1 .2913 21000. .5250 .4259 .0991

9 .689 498.160 1.3469 13090. .3273 .3887 -.061

5

15 .877 510.940 1 .3815 16365. .4091 .3662 .0429

15 .195 510.940 1 .381

5

23000, .5750 .3662 .2088

9 .910 523.160 1 .4145 12780. .3195 .3456 -.0261

12 1 .000 526.380 1 ,4232 13840. .3460 .3403 .0057

9 .998 548.160 1 .4821 12630. .3158 .3065 .0092

12 .900 570.460 1 .5424 12540. .3135 .2757 .0378

12 1 .000 609.320 1 .6475 9373. .2343 .2305 .0038

Number of data points = 46.

I 70
Table 5. Behavior of coefficients of equation of stafe for propane (eq (6)).

d/d ^ ' a0 ~ o B(p) C(p)

K K i^Pa

.10 300.609 283.690 1 .01 33 .45809 -.46999

.20 328.350 31 5 .259 1 .91 47 .46283 -. 39609

.30 344.408 335.148 2.6487 „ 47075 -.32679

.40 354.668 348.633 3.21 78 .481 82 -.26259

.50 361 .308 357. 737 3.635f .49606 -.20390

.60 365 .501 363.647 3.923'. .51 347 -. 1 51 01 .70 367.994 367.205 4. 1 0'''8 .53404 -.1 041

3

.80 369.291 369.056 4, 2033 .55777 -.06335

.90 369.780 369.750 4.2^1 8 .58467 -.02867

1 .00 369. 850 369. 850 4.247 .61 473 0.00000

1.10 369.774 369.745 4*24! .64796 .02285

1 .20 369.305 369.071 4.2046 .68435 .0401

3

1 .30 368.1 43 367.354 4. 1 1 60 .72391 .0521

9

1 .40 366.050 364.193 3.9624 .76663 .05939

1 .50 362.843 359.257 3.7385 .81 251 .06220

1 .60 358.390 352.291 3.4467 .861 57 .061 07

1 .70 352.604 343.1 23 3.0963 .91 378 .05650

1 .80 345.429 331 .657 2.701

5

.9691

6

.04902

1 .90 336.837 31 7.879 2.2806 1 .02770 .0391

3

2.00 326.818 301 .853 1 .8536 1 .08941 .02734

2.10 31 5.374 283.721 1 .441

1

1 .15428 .01 41

4

2.20 302.51

8

263.703 1 .0625 1 .22232 .00000

2.30 288.274 242.095 .7342 1 .29352 -.01464

2.40 272.683 219.261 .4677 1 .36789 -.02939

2.50 255.802 1 95.627 .2686 1 .44542 -.04389

2.60 237.713 171 .671 .1346 1 .5261

2

-.05782

2.70 218.534 147.900 .0562 1 .60998 -.07092

2.80 198.415 124.827 .0183 1 .69700 -.08298

2.90 177.545 102.943 .0042 1 .78719 -.09381

3.00 156.139 82.685 .0006 1 .88054 -.10330

3.10 134.434 64.403 .0000 1 .97706 -.1 1135

3.20 1 12.662 48.340 .0000 2.07674 -.11793

3.30 91 .042 34.622 .0000 2.17959 -.12302

3.40 69.762 23.256 .0000 2.28560 -.12665

71
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72
Table 7. Comparisons of experimental P-p-T data of propane

with eq (6).

Summary of P-P-T data comparisons.

Range of Data No. of Deviations

Authors T(K) P(MPa) p ( kg/m3

)

Po i nts Ap/p, rms AP/P,mean

(.%) (%)

Beattie [21 369-548 2.4 - 31.0 44-441 106 0.46 0.36

Deschner [221 303-609 0.1 - 14.2 1-418 236 1.28 0.92

Cherney [141 323-398 1.1 - 5.0 17-1 14 25 0.27 0. 17 Reamer [ 73 1 31 1-51 1 0- 1 - 69.0 1-576 306 0.32 0.82 Dawson [ 21

1

243-348 0.05- 0.18 1-3 18 0.20 0. 18 Dittmar [231 273-413 1.0 -103.5 320-590 325 0.21 1.41 TomI inson [981 278-328 1.06- 13.8 452-530 40 0.11 4.01

Ely [251 166-324 0.26- 42.8 508-651 222 0.06 4.62

Teichmann [94] 323-573 2.77- 60.9 108-461 148 0.69 0.83

Warowny [1021 373-423 0.3 - 6.4 5-170 51 0.83 0.24

Haynes [42] 90-300 0.6 - 37.5 493-741 196 0.07 8.27

Thomas [951

i sochores 370-623 2.0 - 40.0 35-486 215 0.43 0.32

i sotherms 258-370 0.6 - 35.7 35-549 51

1

1.41 2.24

Virial equation

(this report) 270-600 0.4 - 1.0 8.8 34 0.20 0.18

Total number of points used in fit = 1946

Overall rms density deviation = 0.76$

Overall mean pressure deviation = 2.41$

73
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7)Toml i nson , (24)Ely, (26)Dittmar, (XXXX)Haynes, ( 51 , 52 )Thomas, (78)Teichmann,

(79)Warowny.

ID Data Ternp

.

Dens i ty De n s i ty L/O 1 1 -J 1 ) y p

•^expt P , ca 1 c

f^p C^Cl C 1 1

1 1 Co o U Point expt

Kg/ irr ca 1 c D i f f

.

D 1 f f

.

No

.

K nv-, 1 /I rsy/ Ml MPa MPa p

1 . 1 00 270.000 9nn 8.82 -.05 .4057 .4055 .04

2 .1 00 9R0 .000 oon C5 • OZ 8. 82 -.06 .4242 .4240 .05

3 . 1 00 990.000 9 no o « oz 8.83 -.08 .4425 .4422 .08

4 . 1 00 300.000 . 9nn zuu O • DZ 8.83 -. 1

1

.4607 .4602 . 1

0

5 . 1 00 31 0.000 . 9nn zuu o • oz 8.83 -. 1

4

.4787 .4781 .13

5 .1 00 390.000 . 9zuuno RO • R9OZ 8.83 -. 1

7

.4967 .4959 .16

7 , 1 00 330.000 9on R R9 8.84 -.1

9

. 51 45 .51 36 . 1

8

8 .100 340.000 9 no R R9 8.84 -. 21 .5323 .5313 .20

9 . 1 00 350.000 'JOO Q Q9 o» oz 8.84 -.22 .5500 .5489 .21

1 n . 1 00 o» OZ 8.84 -. 24 .5677 .5664 .22

1

1

1 on "^7n onn . ^UU O • OZ R R4 - . 94Z.H 9"^

1 9 1 on -'OU . uw onn O • OZ -.25 .601 4 .94 • i. H

\ 3 • 1 00 390.000 oon Q Q9 O •OZ 8.84 -.25 .6203 .61 88 .24

1 4 . 1 00 400.000 . ZUU 0» OZ 8. 84 -. 26 .6378 .6362 .25

id in nnn O AA O • OZ O . 0*T . o ^ ^ — . U ^ -JO

1

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1

1 So 1 no nnn .200 8»82 R R/1 - 9S . 707'S / u / . / u ^o • 94Z H

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7

. ZJ) 90^.\J 1 no 4f^n nnn O AA .zuu Q QO CS« OZ R R4 - 9"^

. Z --J • 74/ H 11 Q^ . 7409 / H UZ. 9"^. Z-J 21 . 1 00 470. ono O AA Q QO O . OZ 8.84 -.93 . 7591 .7574 . 22

9? 1 no 4Rn nnn O AA . ZUU Q QO O.OZ flO. R4OH _ oo . z ^ • 77fi4 / / VJH • 774 / / H 7/ * z99z

9"^ 1 nn 4Qn nnn O AA Q QO O . OZ RO . 9AOH . Z 1 7Q1 Q • 91Z 1 24 . 1 00 ^nn.nnn OAA .zUU Q QO O.OZ 8.84 -.21 .81 08 .8092 .20 25 . 1 00 sin. nnn .200 8.82 R.R4 O . OH -.90 .8280 .8264 . 1 9

26 .100 520.000 .200 8.82 8.84 -.19 .8452 .8436 .19 27 ,100 530.000 .200 8.82 8.84 -.18 .8623 .8608 .18 28 .100 540.000 .200 8.82 8.83 -.17 .8795 .8780 .17 29 .100 550.000 .200 8.82 8.83 -.17 .8966 .8952 .16 30 .100 560.000 .200 8.82 8.83 -.16 .9138 .91 24 .15

31 .100 570.000 .200 8.82 8.83 -.15 .9309 .9295 .15

32 .100 580.000 .200 8.82 8.83 -.14 .9480 .9467 .14

33 .100 590.000 .200 8.82 8.83 -.13 .9651 .9638 .13 34 .100 600.000 .200 8.82 8.83 -.12 .9822 .9810 .12

74
Table 7. (Continued)

Data sources

( 1 3)Chern8y,

(79)Warowny.

and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(1 7)Toml Inson, (24)Ely, ( 26 )D i ttinar , (XXXX)Haynes, ( 51 , 52 )Thomas, (78)Teichmann,

ID Data

Point

No.

Weight Temp,

K

Dens i ty

expt

mol/L kg/irr

Dens I ty

calc

kg/m^

Dens I ty

Diff.

Pexpt

MPa

Pcah

I'^a

Pressure

Di ff

.

%

2 35 1 .000 243.150 .045 1 .99 1 .99 -. 1

1

.0887 .0886 .10

2 36 1 .000 243.150 .060 2.63 2.63 -.02 .1 161 .1 160 .02

2 37 1 .000 258.150 .060 2.62 2.63 -.09 .1237 .1236 .09

2 38 1 .000 258.150 .045 1 .99 1 .99 -.11 .0945 .0944 .11 2 39 1 .000 273.150 .071 3.12 3.12 -.16 .1 552 .1550 .15

2 40 1 .000 273.150 .045 1 .99 1 .99 -.19 .1003 .1001 .19

2 41 1 .000 273.150 .060 2.63 2.63 -.14 .1316 .1314 .14

2 42 1 .000 288.150 .059 2.62 2.62 -.16 .1386 .1383 .16

2 43 1 .000 288.150 .021 .91 .91 -.26 .0490 .0489 .26

2 44 1 .000 288.150 .045 1 .99 1 .99 -.18 .1060 .1058 .18

2 45 1 .000 288.150 .071 3.12 3.12 -.19 .1643 .1640 .19

2 46 1 .000 288.150 .037 1 .63 1 .64 -.28 .0874 .0872 .27

2 47 1 .000 323.1 50 .037 1 .63 1 .64 -.22 .0983 .0981 .22

2 48 1 .000 323.150 .070 3.09 3.10 -.25 .1838 .1834 .24

2 49 1 .000 323,1 50 .021 .91 .91 -.12 .0551 .0551 .12

2 50 1 .000 323.150 .045 1 .99 1 .99 -.25 .1 193 .1 190 .25

2 51 1 .000 348.150 .060 2.62 2.63 -.27 .1694 .1690 .27

2 52 1 .000 348.150 .045 1 .99 2.00 -.34 .1290 .1286 .34

75
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Dsschner, (5)Reainer,

(l3)Cherney, ( 1 7 )Tom I inson , (24)Ely, (26)0 ittmar , (XXXX)Haynes, (51 ,52 )rhomas, ( 78 )Te ichmann

,

(79)Warowny.

ID Data Weight Temp. . Dens i ty Dens i ty Dens i ty Pexpt Pcalc Pressui

Point expt

kg/in^

calc Di ff. Dif f

.

No. K mol/L kg/m-^ % MPa MPa %

13 53 1 .000 323.150 .474 20.88 20.91 -.15 1 .0801 1 .0788 .13

13 54 1 .000 323.150 .494 21 .79 21 .82 -.16 1 .1 186 1 .1171 .13

13 55 1.000 323.150 .5 33 23.48 23.54 -.25 1 . 1 896 1.1872 .20

13 56 1 .000 323.150 .559 24.63 24.65 -.08 1 .2341 1 .2334 .06

13 57 1 .000 323.150 .577 25.46 25.53 -.26 1 .2686 1 .2660 .20

13 58 1 .000 323.150 .608 26.82 26.88 -.21 1 .3203 1 .3181 .16

13 59 1 .000 323.150 .631 27.81 27.88 -.25 1 .3578 1.3552 .19

13 60 1 .000 323.150 .695 30.63 30.74 -.34 1 .4601 1 .4565 .25

13 61 1 .000 323.150 .773 34.10 34.21 -.34 1 .5756 1 .5719 .23

13 62 1 .000 323.150 .872 38.44 38.66 -.57 1 . 7094 1 .7031 .37

13 63 1 .000 373.1 50 .383 16.90 16.95 -.27 1 .0832 1 .0805 .24

13 64 1 .000 373.1 50 .406 17.92 17.97 -.28 1 .1419 1 . 1 390 .26

13 65 1 .000 373.150 .462 20.36 20.41 -.25 1 .2797 1 .2769 .22

13 66 1 .000 373.150 .534 23.57 23.60 -.15 1 .4540 1 .4521 .13

13 67 1 .000 373.150 .634 27.98 28.02 -.15 1 .6840 1 .6819 .13

13 68 1 .000 373.150 .781 34.42 34.45 -.09 1 .9971 1 .9956 .08

13 69 1 .000 373.150 1 .014 44.71 44.67 .09 2.4429 2.4446 -.07

13 70 1 .000 373.150 1 .447 63.79 63.58 .34 3.1 127 3.1192 -.21

13 71 1 .000 373.150 2.520 111.11 110.91 .18 4.0733 4.0757 -.06

13 72 1 .000 398.150 .535 23.61 23.67 -.24 1 .5847 1 .581

3

.22

13 73 1 .000 398.150 .636 28.06 28.10 -.15 1 .8431 1 .8407 .13

13 74 1 .000 398.150 .784 34.58 34.60 -.06 2.2018 2.2007 .05

13 75 1 .000 398.150 1 .021 45.04 44.98 .13 2.7267 2.7295 -.11

13 76 1 .000 398.150 1 .464 64.57 64.25 .50 3.5565 3.5688 -.34

13 77 1 .000 398.150 2.580 113.79 113.26 .47 4.9781 4.9893 -.22

76
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reanier,

(13)Cherney, ( 1 7 )Tom II nson , (24)Ely, (26)Dittmar, (XXXX )Haynes, (51 , 52 )Thomas, ( 78 )Te ichmann

,

( 79) Warowny

.

Data Point

No.

Weight Temp.

K

Dens i ty

expt

mol/L kg/nr

Dens I ty

calc

kg/rrr

Dens i ty

Diff. expt

MPa

cal c Pressur

Diff.

3 78 1 .000

3 79 1 .000

3 80 1 .000

3 81 1 .000

3 82 1.000

3 83 1 .000

3 84 1 .000

3 85 1 .000

3 86 1.000

3 87 1 .000

3 88 1 .000

3 89 1 .000

3 90 1 .000

3 91 1 .000

3 92 1 .000

3 93 1 .000

3 94 1 .000

3 95 1 .000

3 96 1 .000

3 97 1 .000

3 98 1 .000

3 99 1 .000

3 1 00 1 .000

3 101 1 .000

3 1 02 1 .000

3 103 1 .000

3 104 1 .000

3 105 1 .000

3 106 1 .000

3 107 1 .000

3 108 1 .000

3 109 1 .000

3 110 1 .000

3 111 1 .000

3 112 1 .000

3 113 1 .000

3 114 1 .000

3 115 1 .000

3 116 1 .000

3 117 1 .000

3 118 1 .000

3 119 1 .000

3 120 1 .000

3 121 1 .000

3 122 1 .000

3 123 1 .000

3 124 1 .000

3 125 1 .000

3 126 1 .000

3 127 1 .000

3 128 1 .000

3 129 1 .000

3 130 1 .000

3 131 1 .000

3 132 1 .000

3 133 1 .000

369.960 .999

373.150 .999 398.150 .999

423.150 .999

448.150 .999

473.150 .999

498.150 .999 523.150 .999

548.150 .999

369.960 1.499

373.150 1.499

398.150 1.499

423.150 1.499

448.150 1.499

473.150 1.499

498.150 1.499

523.150 1.499

548.150 1.499

369.960 1.998

373.150 1.998

398.150 1.998

423.150 1.998

448.150 1.998

473.150 1.998

498.150 1.998

523.150 1.998

548.150 1.998

373.150 2.498

398.150 2.498

423.150 2.498

448.150 2.498

473.150 2.498

498.150 2.498

523.150 2.498

548.150 2.498

369.960 2.998

373.150 2.993

398.150 2.998

423.150 2.998

448.150 2.998

473.150 2.998

498.150 2.998

523.150 2.998

548.150 2.998

373.150 3.497

398.150 3.497

423.150 3.497

448.150 3.497

473.150 3.497

498.150 3.497

523.150 3.497

548.150 3.497

369.960 3.997

373.150 3.997

398.150 3.997

423.150 3.997

44.06 43.62

44.06 43.83

44.06 43.95

44.06 43.97

44.06 43.97

44.06 43.99

44.06 44.02

44.06 43.94

44.06 44.01 66.09 65.33

66.09 65.54

66.09 65.68

66.09 65.68

66.09 65.72

66.09 65.76

66.09 65.80

66.09 65.68

66.09 65.87

88.12 87.76

88.12 87.33

88.12 87.44

88.12 87.45

88.12 87.55

88.12 87.61 88.12 87.71

88.12 87.78

88.12 87.86

110.16 109.65

110.16 109.38

110.16 109.46

110.16 109.59

110.16 109.70

110.16 109.31

110.16 109.94

110.16 110.05

132.19 132.47

132.19 132.13

132.19 131.61

132.19 131.62

132.19 131.82

132.19 132.63

132.19 132.17

132.19 132.31

132.19 132.43

154.22 154.49

154.22 153.87

154.22 153.87

154.22 154.14

154.22 154.35

154.22 154.55

154.22 154.71

154.22 154.85

176.25 178.48

176.25 176.55

176.25 175.63

176.^5 175.88

1 .02 2.3659

.53 2.4085

.26 2.6770

.22 2.9354

.21 3.1887

.16 3.4400

.10 3.6892

.28 3.9284

.13 4.1 776

1.17 3.1087

.85 3.1 715

.62 3.61 12 .62 4.0317

.57 4.4441

.50 4.8504

.44 5.251

7

.63 5.6367

.33 6.0430

.41 3.6295

.91 3.7044

.78 4.3357

.77 4.9386

.66 5.5293

.59 6.1079

.48 6.6314

.39 7.2478

.30 7.8101

.46 4.0581

.71 4.8940

.63 5.6975

.52 6.4818

.42 7.2518

.31 8.0128

.19 8.7677

.10 9.5154

-.22 4.1300

.05 4.2708

.44 5.3287

.43 6.3429

.28 7.3380

-.33 8.3472

.02 9.2874

-.09 10.2480

-.18 1 1 .2005

-.17 4.3884

.23 5.6752

.23 6.9144

.05 8.1364

-.09 9.3432

-.21 10.5398

-.32 1 1 .7274

-.41 12.9068

-1 .25 4.2486

-.17 4.4502

.35 5.9650

.21 7.4443

2.3838 -.75

2.4131 -.40

2.6826 -.21 2.9408 -.18

3.1945 -.18

3.4448 -.14

3.6927 -.09

3.9385 -.26

4.1826 -.12

3.1302 -.69

3.1877 -.51 3.6257 -.43

4.0505 -.46

4.4642 -.45

4.8706 -.41 5.2716 -.38

5.6682 -.55

6.0613 -.30

3.6361 -.18

3.7201 -.42

4.3554 -.45

4.9640 -.51 5.5559 -.48

6.1361 -.46

6.7074 -.39

7.2719 -.33

7.8308 -.26

4.0642 -.15

4.9111 -.35

5.7193 -.38

6.5048 -.35

7.2746 -.31 8.0328 -.25

8.7813 -.16

9.5235 -.08

4.1284 .04 4.2713 -.01 5.3386 -.19

6.3583 -.24

7.3516 -.19

8.3268 .24 9.2886 -.01 10.2398 .08

11.1822 .16 4.3874 .02 5.6802 -.09

6.9230 -.12

8.1392 -.03

9.3372 .06

10.5214 .18 11.6944 .28 12.8582 .38 4.2470 .04

4.4496- .01 5.9729 -.13

7.4531 -.12

77
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7 )Tom I i nson, (24)Ely, (26)D ittinar, (XXXX )Haynes, (51 ,52)Thomas, (78)Teichmann,

(79)Warowny.

ID Data Po i nt No.

1 34

;

155 136

1 37

138

139

140

141 142

143

144

145

146

147

148

149

150

151 152

153

154 155 156

157 158

159

160

161 162

163

164

165

166

167

168

169

170

171 172

173

174

175

176

177 178

179

180

181 182

183 184

185 186

187

Weight

1 .000

1 .000

1 .000

1 .000

1 ,000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

0.000

0.000

1 .000

1 .000

1 .000

1 .000

1.000

1 .000

1 .000

0.000

0.000

1 .000

1 .000

1.000

1 .000

1 .000

1 ,000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

Temp.

K

448.150

473.150

498.1 50 523.150

548.150

373.150

398.150

423.150

448.1 50 473.150

498.150

523.150

548.1 50 373.150

398.1 50 423.150

448.150

473.150

498.150

523.150

548.150

369.960

373.150

398.150

423.150

448. 150 473.150

498.150

523.150

548.150

369.960

373.150

398.150

423.150

448.150

473.150

498.1 50 523.150

548.1 50 369.960

373.1 50 398.150

423.150

448.150

473.150

493.150

369.960

373,150

398.1 50 423.150

448.150

369.960

373.150

398.150

Dens i ty

expt

mot/L kg/nr

3.997

3.997

3.997

3.997

3.997

4.496

4.496

4.496

4.496

4.496

4.496

4.496

4.496

4.996

4.996

4.996

4.996

4.996

4.996

4.996

4.996

5.995

5.995

5.995

5.995

5.995

5.995

5.995

5.995

5,995

6.994

6.994

6.994

6.994

6.994

6.994

6.994

6.994

6.994

7.994

7.994

7.994

7.994

7.994

7.994

7.994

8.993

8.993

8.993

8.993

8.993

9.992

9.992

9.992

1 76.25

176.25

1 76.25

176.25

176.25

198.28

198.28

198.28

198.28

198.28

198.28

198.28

198.28

220.31

220.31

220,31

220.31

220.31

220.31

220.31

220.31

264.37

264.37

264.37

264.37

264.37

264.37

264.37

264.37

264.37

308.44

308.44

308.44

308.44

308.44

308.44

308.44

308.44

308.44

352.50

352.50

352.50

352.50

352.50

352.50

352.50

396.56

396.56

396.56

396.56

396.56

440.62

440.62

440.62

Dens I ty ca Ic kg/nr

176.27

176.53

176.78

177.00

177.29

196.07

196.75

197.39

198.01

198.43

198.73

199.00

1 99.21 212.79

217.08

218.50

219,42

220.00

219.04

219.56

221 .08 264.89

256.35

259.68

261 .66 262.81

263.54

264.01

264.37

264.65

307.03

305.84

305.85

306.68

307.34

307.98

308.11

308.31

308.48

351 .48

351 .23

351 .03

351 .51 351 .78 352.07

352.20

395.92

395.64

395.74

395.85

395.72

440.44

440.03

439.81

Dens i ty

Diff.

expt

MPa

ca I c MPa

Pressure

Diff.

%

- .01 8.91 15 8.9107 .01 -. 1

6

1 0.3655 1 0. 3522 . 1

3

-.30 1 1 .81 25 1 1 .781

2

.27 -.42 1 3. 2523 13,1 996 .40 -.59 1 4.6942 1 4.6087 .59 1.13 4.4826 4,4857 -.07

.78 6.2305 6.2498 -.31

.45 7.9652 7.9874 -.28

.14 9.6998 9.7101 -.11 -.07 1 1 .4284 1 1 .421

1

.06 -.23 1 3.1 510 1 3.1 221 .22 -.36 1 4.8694 14.8140 .37 -.47 16.5808 16.4973 .51 3.54 4.5049 4.51 49 -.22

1 .49 6.4959 6.5403 -.68

.83 8.5133 8.5629 -.58

.41 10.5439 10.5812 -.35

.14 12.5765 1 2.5940 -.14

.58 14.5108 14.6004 -.51 .34 16.5352 16.5999 -.39

-.35 18.6691 18.5919 .42 -.19 4.2708 4.2702 .01 3.13 4.5758 4.5980 -.48

1 .81 7. 1657 7.2565 -1 .25

1 .04 9.8680 9.9698 -1 .02

.60 12.61 70 12.7048 -.69

.32 1 5.3862 1 5.4493 -.41

.14 18. 1 61

5

18. 1961 -.19

.00 20.9408 20.9410 -.00

-.1

1

23.71 82 23.681

0

.16

.46 4.4725 4.4878 -.34

.85 4.891

0

4.9268 -.73

.85 8.3826 8.4810 -1.16

.57 1 2.01 92 12.1 299 -.91

.36 15.7246 1 5.8219 -.61

.1 5 1 9.4328 1 9.5351 -.27

, 1

1

23.21 15 23.2569 -.19

.04 26.9585 26.9794 -.08

-.01 30.7045 30.6972 .02

.29 5.5587 5.6039 -.81 .36 6.1504 6.2121 -.99

.42 10.9472 1 1 .0694 -1.10

.23 15.9019 16.0195 -.73

.20 20.9044 21 .01 44 -.52

.12 25.9493 26.0295 -.31 .09 30.9832 31 .0500 -.22

.16 9.0068 9.0845 -.86

.23 9.81 23 9.9297 -1.18

.21 16.4623 16.6064 -.87

.18 23.1301 23.3383 -.68

.21 29.8676 30.0913 -.74

.04 17.3357 17.3862 -.29

.14 18.3824 1 8.5461 -.88

.19 27.3699 27.6442 -.99

78
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reanner

(13)Cherney, ( 17)Toml inson, (24)Ely, (26)0ittmar, (XXXX)Haynes , ( 51 , 52)Thomas (78 )Te ichmann

,

(79)Warowny.

D Data Point

No.

Weight Temp.

K

Dens i ty

expt

mol/L kg/mDens i ty ca I c kg/m^

Dens i ty

Diff. expt

MPa

cal c MPa

Pressure

Diff.

%

26

26

26

2626

262626

2626

26

26

262626

26

262626

26

2626

26

26

26

26

2626

2626

26

26

2626

2626

2626

26

2626

26

26

2626

26

2626

26

26

26

26

2626

2626

188

189 190

191 192

193 194 195

196

197 198

199 200

201 202

203 204

205

206

207

208

209

210

211 212

213

214 215

216

217

218

219

220

221 222 223

224 225

226

227 228

229

230

231 232

233

234 235

236

237

238 239

240

241 242

243

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

1.000

1.000

1.000

1.000

1.000

1.000

1.000

1.000

1 .000

1.000

1.000

1 .000

1.000

1.000

1.000

1.000

1.000

1.000

1.000

1.000

1.000

1 .000

1.000

1 .000

1.000

1 .000

1.000

1.000

1.000

1.000

1.000

1 .000

1.000

1.000

1.000

1 .000

1.000

1.000

1.000

1.000

1.000

1.000

1.000

1.000

1.000

373. 150 383. 150 393. 150 403. 150 413. 150 363. 150 373.150

38 3.150

393.150

403. 150 413. 150 363. 150 373.150

383. 150 393. 150 403. 150 413. 150 353. 150 363. 150 373.150

383 . 1 50 393. 150 403. 150 413.150

353. 150 363. 150 373. 150 383.150

393. 150 403.150

413. 150 343.150

353.150

363. 150 373.150

383.150

393. 150 403. 150 413.150

343. 150 353.150

363.150

373.150

383.150

393.150

403.150

413. 150 343. 150 353.150

363.150

373.150

383. 150 393. 150 403. 150 413.150

333.150

7.257

7.257

7.257

7.257

7.257

7.710

7.710

7.710

7.710

7.71 0 7.710

8. 164 8.164

8. 164

8. 164

8. 164

8. 164 8.617

8.617

8.617

8.617

8.617

8.617

8.617

9.071

9.071

9.071

9.071

9.071

9.071

9.071

9.298

9.298

9.298

9.298

9.298

9.298

9.298

9.298

9.524

9.524

9.524

9.524

9.524

9.524

9.524

9.524

9.751

9.751

9.751 9.751

9.751

9.751

9.751

9.751

9.978

320.00

320.00

320.00

320.00

320.00

340.00

340.00

340.00

340.00

340.00

340.00

360.00

360.00

360.00

360.00

360.00

360.00

380.00

380.00

380.00

380.00

380.00

380.00

380.00

400.00

400.00

400.00

400.00

400.00

400.00

400.00

410.00

410.00

410.00

410.00

410.00

410.00

410.00

410.00

420.00

420.00

420.00

420.00

420.00

420.00

420.00

420.00

430.00

430.00

430.00

430.00

430.00

430.00

430.00

430.00

440.00

331.01

326.39

325.33

324.36

323.52

349.40

347.56

345.91

345.96

343.35

343.43

366.03

363.96

363.50

364.00

363.34

362.74

380.82

381.36

381 .32

381 .94 382.27

381.77

381 .91 400.11

401 .42 401.47

401 .40 401.28

401 .13

400.98

409.26

410.01

410.99

41 1.01 410.95

410.86

410.75

411 .03 419.02

420.08

420.16

420.15

420.53

420.41

420.29

420.52

430.09

430.03

429.91

430. 18 430.37

430. 17 429.98

430.42

439.77

-3.33

-1 .96

-1 .64

-1 .34

-1 .09 -2.69

-2. 18 -1.71 -1.72

-.97

-1.00

-1 .65 -1.09

-.96

-1.10

-.92

-.75

-.22

-.36

-.35

-.51

-.59

-.46

-.50

-.03

-.35

-.37

-.35

-.32

-.28

-.24

.18 -.00

-.24

-.25

-.23

-.21

-.18

-.25

.23 -.02

-.04

-.04

-.13

-.10

-.07

-.12

-.02

-.01 .02 -.04

-.09

-.04

.00 -.10

.05

5.3937

6.8647

8.4337

10.0028

1 1.5718

4.2169

5.9821

7.7473

9.6105

11.2776

13. 1409 4.9033

6.8647

8.9241

1 1.0815

13. 1409 15.2003

3,5304

5.8840

8.2376

10.6892

13.1409

15.4945

17.9462

5.0014

7.8453

10.5912

13.3370

16.0829

18.8288

21 .5746

3. 1381 6.0801

9.1202

12.0622

15.0042

17.9462

20.8882

23.9282

4.2169

7.4531

10.5912

13.7293

16.9655

20. 1036 23.2418

26.4780

5.7859

9. 1202 12.4544

15.8868

19.3191

22.6534

25.9876

29.5180

3.9227

5. 1269 6.6492

8.1975

9.7631

11.3411

3.9629

5.6812

7.4395

9.2223

1 1 .0223

12.8350

4.6147

6.6189

8.6547

10.7121

12.7852

14.8699

3.4836

5.7809

8. 1 146 10.4727

12.8483

15.2369

17.6352

4.9903

7.6760

10.3864

13. 1 144 15.8552

18.6054

21.3622

3.2105

6.0794

8.9770

1 1.8944

14.8261 17.7681

20.7174

23.6714

4.3406

7.4407

10.5627

13.7002

16.8486

20.0047

23. 1657 26.3296

5.771

1

9.1 145 12.4742

15.8451

19.2237

22.6071

25.9931

29.3797

3.9617

5.20

3.24

2.88

2.45

2.03

6.41 5.30

4. 14 4.21 2.32

2.38

6.25

3.71

3.1 1 3.45

2.78

2.22

1.34

1.78 1.52 2.07

2.28

1.69

1 .76

.22 2.21

1 .97

1 .70 1.44 1.20

.99 -2.25

.01 1.60

1.41 1.20

1.00

.82

1 .08 -2.85

.17

.27

.21 .69

.49

.33 .56

.26 .06

-. 16 .26 .50 .20

-.02

.47 -.99

79
Table 7. (Continued)

Data sources and ID numbers: (l)Virlal Equafion, (2)Dawson, (3)Bedhtie, (4)Deschner, (5)ReaiTier,

(I.5)Cherney, ( 1 7 ) Tom I i nson , (24)Ely, (26 )D i t htiar , (XXXX)Haynes, ( 51 , 52 )Tho(nas, ( 78 ) fa ichmann

,

( 79)Warowny

.

1 D Data We i ght Temp

.

Dens ity

'^o i n t expt

No • I\ mo i /L kg/ in

26 244 1 .000 343. 1 50 9.978 440 .00 26 245 1 .000 353. 1 50 9.978 440.00

26 246 1 .000 363.1 50 9.973 440.00

26 247 1 .000 373.1 50 9.978 440.00

26 243 1 .000 383. 1 50 9.978 440.00

26 249 1 .000 393 . 1 50 9.978 440 .00 26 250 1 .000 403. 1 50 9.973 440c 00

26 251 1 .000 41 3. 1 50 9.978 440.00

26 252 1 .000 333.1 50 10.205 450.00

26 253 1 .000 343.150 10.205 450.00

26 254 1 .000 353.150 10.205 450.00

26 255 1 .000 363.150 1 0.205 450.00

26 256 1 .000 373.1 50 10.205 450.00

26 257 1 .000 383.150 1 0.205 450.00

26 253 1 .000 393. 1 50 10.205 450.00

26 259 1 .000 403.1 50 10.205 450.00

26 260 1 .000 41 3.1 50 10.205 450.00

26 261 1 . 000 323. 150 10.431 450.00

26 262 1 .000 333. 1 50 10.431 460.00

26 263 1 .000 543.150 10.431 460.00

26 264 1 .000 353. 1 50 10.431 460.00

26 265 1 .000 363.150 10.431 460.00

26 266 1 .000 373. 1 50 1 0.431 460.00

26 267 1 .000 383. 1 50 1 0. 431 460.00

26 263 1 .000 393. 1 50 1 0.431 460.00

26 269 1 .000 403 . 1 50 1 0.431 480.00

26 270 1 .000 41 3.1 50 1 0.431 460.00

26 271 1 .000 313.150 1 0.658 470.00

26 272 1 .000 323. 1 50 1 0.658 470.00

26 273 1 .000 333. 1 50 1 0.658 470.00

26' 274 1 .000 343. 1 50 1 0.658 470.00

26 275 1 .000 353. 1 50 1 0.658 470.00

26 276 1 .000 363. 1 50 1 0.658 470.00

26 277 1 .000 373 . 1 50 1 0.658 470.00

26 278 1 .000 383. 1 50 1 0.658 470.00

26 279 1 .000 393. 1 50 1 0.658 470.00

26 280 1 .000 403. 1 50 1 0.658 470.00

26 281 1 .000 41 3. 1 50 1 0.658 470.00

26 282 1 .000 313.1 50 10.885 480.00

26 283 1 .000 323.1 50 1 0.885 480.00

26 234 1 .000 333.150 10.885 480.00

26 285 1 .000 343.150 1 0.885 480.00

26 286 1 .000 353.1 50 10.885 480.00

26 287 1 .000 363 . 1 50 10.885 480.00

26 283 1.000 373.150 10.385 480.00

26 289 1 .000 383.150 10.835 480.00

26 290 1 .000 393.1 50 10.835 480.00

26 291 1 .000 403.150 10.885 480.00

26 292 1 .000 413.150 10.885 430.00

26 293 1 .000 303.150 11.112 490 . 00

26 294 1 .000 313.150 11.112 490.00

26 295 1 .000 323.150 11.112 490.00

26 296 1 .000 333.150 11.112 490.00

26 297 1 .000 343.150 11.112 490.00

26 298 1 .000 353.150 11.112 490.00

26 299 1 .000 363.150 11.112 490.00

Dens i ty ca I c kg/m^

440.03

440. 15 439.31

439.87

439.90

439.62

439.37

439.43

449.22

449.53

449.45

449.32

449.20

449.39

449.02

449.45

449.13

459.54

459.89

459.44

459.38

459.61

459.27

458.74

459.21

453.99

459.21

469.55

469.48

469.03

469.33

469.00

468.98

463.97

463.98

468.79

463.84

469.08

478.83

479.03

473.92

478.84

479.01

478.96

473.93

478.92

479.29

479.14

479.17

488.63

483.96

439.23

489.25

439.23

489.33

439.20

Dens i ty

iff. expt Pcalc PressureD i f f

.

MPa To

.Ul 7 1 1 A 13 .(Jo 11.1/ yo 11 1 jI .J 1

1 4 . / 1 UU 1 A 7t^<^01 4 • ID^dL

•7 1 .Uj 1 O XXO A

1 o . jjo4

.02 21 .9669 21 .9969 -.1 4 .09 o c: A Ci~t~t z5.4y /j 25 .62 1

3

A O -.48

1 A • 1 4 29.0277 29.2457 -.75

. 1 3 32.6561 32.8586 -.65

.17 5.6879 5 .8507 -2.78

.09 9.61 05 9.71 06 -1 .03

.1 2 1 3.4351 1 3.5808 -1 .07

.1 5 1 7 .2597 1 7 . 4572 -1.13

.1 8 21 .0843 21 .3369 -1.13

.14 25.0070 25.21 75 -.84

.22 28. 7335 29.0970 -1 .25

.1 2 32. 7542 32.9739 -.57

.19 36.4307 36.8466 -.99

.10 3.9227 4.0265 -2.53

.02 3.1 395 8. 1683 -.35

.12 1 2. 1602 1 2.31 35 -1 .29

. 1

4

1 6.2790 1 6.4734 -1.18

.09 20.4959 20.6299 -.65

. 1

6

24.5166 24. 7857 -1 .09 .28 28.4393 28.9390 -1 .73

. 1 7 32. 7542 33.0881 -1 .01 .22 36. 7749 37.231

6

-1 .23

. 1 / 40.9:^1 0 41 .3686 A1 -.91

. 1

C

1 .961

3

2.0694 -5 . 22

. 1

1

6.3743 6.5168 -2.19

.zO 1 u • Doyz 1 A CSC AO -Z .5o

1 A

• 1 4 1 ^ • ZUUJ 1 D • 4z4o 1 -1 .4d

1 y • ^1 1 A O "7 AO1 9. o /yz 1

. 22 23. 9282 24 .3309 -1 .55 Zo . j4

1

Z Zo t 1 1 1^ - 1 RO 1 . Dz

• ZZ jZ . /y4Z J J. Z\ oo 1 AC\ -\ .4U

.26 j/.Ooyl J 1 .o5z4 -1 . DO .25 41 .4821 42 .0775 1 A ^ -1.41

.20 45.9932 46. 4932 -1 .08

.24 4. 41 30 4 . 7554 -7.20

.20 9.21 83 9.5356 -3 .33

.23 1 3.9254 1 4.31 44 -2.72

.24 13.6326 1 9.0895 -2.39

.21 23.4379 23.8590 -1 .77

.22 28.1451 23.6213 -1 .66

.22 32.8523 33.3751 -1 .57

.22 37.5595 33.1 191 -1 .47

.15 42.4623 42.3525 -.91

.18 47.0719 47.5743 -1 .06

.17 51 .7791 52.2839 -.97

.28 2.451

7

2.8842 -1 5.00

.21 7.6492 8.0183 -4.60

.16 12.3467 13.1463 -2.28

.15 1 7.9462 18.2665 -1 .75 .15 23.0456 23.3776 -1 .42

.14 28.1451 28.4782 -1.17

.16 33.1465 33.5671 -1 .25

80
Table 7. (Continued)

Data sources and ID numbers: (l)VIrlal Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reainer,

(13)Cherney, ( 1 7)Tom 11 nson, (24)Ely, (26)Dittmar, (XXXX)Haynes, (51 ,52 )Thomas, (78)Teichrnann,

(79) Warowny

.

ID

26

26

2626

2626

2626

26

26

2626

26

26

2626

2626

2626

2626

2626

26

26

2626

2626

2626

2626

26

26

26

26

26

26

2626

26

26

2626

2626

2626

2626

2626

2626

Data Point

No.

300

301 302

303

304

305

306

307

308

309

310

31 1 312 313

314

315 316

31 7 318

319

320

321 322 323

324

325

326

327

328

329

330

331 332

333

334

335 336

337

338

339

340

341 342

343

344

345 345

347

348

349

350

351 352

353

354

355

Weight

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1.000

1 .000

1 .000

1.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .hoo

1 .000

1 .000

1 .000

1 .000

1 .000

Temp.

K

373.150

383.1 50 393.150

403.150

413.150

303.150

313.150

323.150

333.1 50 343.150

353.1 50 363.1 50 373.150

383.150

393.1 50 403.150

413.150

293.150

303.150

313.150

323.150

333. 150 343.150

353.150

363.150

373.150

383.150

393.150

403.150

413.150

293.150

303.150

313.150

323.150

333.150

343.150

353.150

363.150

373.150

383.150

393.150

403.150

413.150

293.150

303.150

31 3.150

323.150

333.150

343.150

353.150

363.150

373.150

383.150

393.150

403.150

413.150

mol/L

1 .1 12 1.112

1.112

1.112

1 .112

1 .339

1 .339

1 .339

1 .339

1 .339

1 .339

1 .339

1 .339

1 .339

1 .339

1 .339

1 .339

1 .452

1 .452

1 .452

1 .452

1 .452 1.452

1 .452

1 .452

1 .452

1 .452

1 .452

1 .452

1 .452

1 .565

1 .565

1 .565

1 .565

1 .565

1 .565

1.565

1 .565

1 .565

1 .565

1.565

1 .565

1 .565

1 .679

1 .679

1 .679

1 .679

1 .679

1 .679

1 .679

1 .679

1 .679

1 .679

1 .679

1 .679

1 .679

Dens ity

expt

kg/m-'

490.00

490.00

490.00

490.00

490.00

500.00

500.00

500.00

500.00

500.00

500.00

500.00

500.00

500.00

500.00

500.00

500.00

505.00

505.00

505.00

505.00

505.00

505.00

505.00

505.00

505.00

505.00

505.00

505.00

505.00

510.00

510.00

510.00

510.00

510.00

510.00

510.00

510.00

510.00

510.00

510.00

510.00

510.00

515.00

515.00

51 5.00

51 5.00

51 5.00

515.00

51 5.00

515.00

51 5.00

51 5.00

51 5.00

51 5.00

51 5.00

Density

ca Ic kg/rrr

489.29

489.22

489.03

489.18

489.19

498.86

498.93

499.02

499.12

499.04

499.01

499.00

499.18

499.07

499.13

499.08

498 . 93 503.73

503.80

504.10

504.18

504.10

504.06

504.22

504.08

504.12

504.19

504.15

504.13

503.90

508.96

509.21

509.26

509.34

509.26

509.07

509.23

509.27

509.19

509.27

509.25

509.14

509.18

513.95

514.17

514.21

514.29

514.39

514.21 514.37

514.27

514.34

514.43

514.42

514.33

514.27

Dens I ty

DIff

.

expt cal c Pressure

Diff

.

% MPa IvPa %

.15 38.2459 38.6436 -1 .03

.16 43.2473 43.7066 -1 .05

.20 48. 1507 48.7555 -1.24

.17 53.2501 53.7898 -1 .00

.17 58.2515 58.8087 -.95

.23 5.9821 6.4211 -6.84

.21 1 1 .4738 1 1 .9256 -3.79

.20 16.9655 17.4172 -2.59

.18 22.4572 22.8951 -1 .91 .19 27.8509 28.3586 -1 .79

.20 33.2445 33.8068 -1 .66 .20 38.6382 39.2389 -1 .53

.16 44.1299 44.6545 -1.17

.19 49.4255 50.0528 -1 .25

.17 54.81 92 55.4335 -1 .11 .18 60.1 148 60.7962 -1.12

.22 65.3123 66.1405 -1 .25

.25 2.2555 2.7362 -1 7.57

.24 7.9434 8.4476 -5.97

.18 13.7293 14.1433 -2.93

.16 19.41 72 1 9.8230 -2.05

.18 25.0070 25.4861 -1 .88

.19 30.5967 31 .1321 -1 .72

.16 36.2846 36.7604 -1 .29

.18 41 .7763 42.3705 -1 .40

.17 47.3661 47.9619 -1 .24

.16 52.9559 53.5342 -1 .08

.17 58.4476 59.0870 -1 .08

.17 63.9394 64.6201 -1 .05 .22 69.2349 70.1331 -1 .28

.20 4.3149 4.7483 -9.13

.16 10.2970 10.6587 -3.39

.15 16.1 810 16.5498 -2.23

.13 22.0650 22.4218 -1 .59

.14 27.8509 28.2744 -1 .50

.18 33.5387 34.1073 -1 .67

.15 39.4227 39.9200 -1.25

.1 4 45.2087 45.7124 -1.10

.16 50.8965 51 .4839 -1.14

.14 56.6824 57.2344 -.96

.15 62.3703 62 . 9636 -.94

.17 67.9601 68.671 2 -1 .04

.16 73.6479 74.3572 -.95

.20 6.4724 6.9507 -6.88

.16 12.6506 13.0641 -3.17

.15 18.7307 19. 1550 -2.21

.14 24.8108 25.2236 -1 .64 .12 30.8909 31 .2701 -1 .21 .15 36.7749 37.2942 -1 .39

.12 42.8551 43.2959 -1 .02

.14 48.7391 49.2748 -1 .09

.13 54.721

1

55.2308 -.92

.11 60.7032 61 .1638 -.75

.1

1

66.5872 67.0736 -.73

.13 72.3731 72.9601 -.80

.14 78.1590 78.8232 -.84

81
Table 7. (Continued)

Data sources and ID numbers: (HVirial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7)Tomli nson, (24)Ely, (26)0ithnar, (XXXX)Haynes. (51 , 52 )Thomas, (78)Teichmann,

(79)Warowny.

ID

26

26

2626

26

26

2626

2626

2626

2626

26

26

2626

2626

2626

2626

26

26

2626

2626

2626

2626

2626

2626

2626

2626

2626

26

26

2626

26

26

2626

2626

2626

Data Point

No.

356

357

358

359

360

361 362

363

364

365

365

367

368

369

370

371 372

373

374

375

376

377

378

379

380

381 382

383

384

385

386

387

388

389

390

391 392

393

394

395

396

397

398

399

400

401 402

403

404

405

406

407

408

409

410

41 1

We i ght

1.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

] oOOO

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1.000

1 .000

1.000

1 .000

1 .000

1 .000

Temp.

K

283.150

293.150

303.150

313.150

323.150

333.150

343.150

353.150

363.150

373.150

383.1 50 393.150

403.150

413.150

283.150

293.1 50 303.150

313.150

323.150

333.150

343.150

353.150

363.150

373.150

383.150

393.1 50 403.150

413.1 50 273.150

283.150

293.150

303.150

313.150

323.1 50 333.150

343.150

353.150

363.150

373.150

383.150

393.150

403.1 50 413.150

273.150

283.150

293.150

303.150

313.150

323.150

333.150

343.150

353.150

363.1 50 373.150

383.150

393.150

moi/L

11 .792

11 .792

1 1 .792

1 1 .792

1 1 .792

11 .792

1 1.792

1 1 .792

1 1 .792

1 1 .792

11 .792

Dens i ty

expt

11

11

1

1

1

,792

.792

.792 ,906

1 1 .906

1 1 .906

1 1 .906

1 1 . 906

1 1 .906

1 1 .906

1 1 .906

1 1 .906

1 1 .906

1 1 .906

1 1 .906

1 1 .906

1 1 .906

12.019

12.019

12.019

12.019

12.019

12.019

12.019

12.019

12.019

12.019

12.019

12.019

12.019

12.019

12.019

12.132

1 2 . 1 32 12.132

1 2.132

12.1 32

1 2 . 1 32 12.132

12.132

12.132

12.132

12.132

12.132

12.132

kg/m'^

520.00

520.00

520.00

520,00

520.00

520.00

520.00

520.00

520.00

520.00

520.00

520.00

520.00

520.00

525.00

525.00

525.00

525.00

525.00

525.00

525.00

525.00

525.00

525.00

525.00

525.00

525.00

525.00

530.00

530.00

530.00

530.00

530.00

530.00

530.00

530.00

530.00

530.00

530.00

530.00

530.00

530.00

530.00

535.00

535.00

535.00

535.00

535.00

535.00

535.00

535.00

535.00

535.00

535.00

535.00

535.00

Dens i ty

calc

kg/m-^

51 9.00

519.14

519.12

519.32

519.38

519.31

519.29

519.44

519.48

519.42

519.52

519.41

519.45

51 9.40

524.59

524.45

524.73

524.69

524.71

524.62

524.71

524.83

524.85

524.90

524.86

524.86

524.78

524.74

529.56

529.50

529.68

529.73

529.67

529.81

529.84

529.78

529.76

529.77

529.82

529.69

529.79

529.73

529.70

534.84

534.88

534.82

534.82

534.73

534.83

534.95

534.99

535.06

535.16

535.08

535.04

535.03

Dens i ty

Dtff

.

expt

MP a

ca I c MPa

Pressure

Dif f

.

.19 2.5497 3.0055 -15.16

.17 8.9241 9.3532 -4.59

.17 15.2003 15.6740 -3.02

.13 21 .5746 21 .9690 -1 .80

.12 27.8509 28.2388 -1 .37

.13 34.0291 34.4836 -1 .32

.14 40.2073 40.7035 -1 .22

.11 46.4835 46.8984 -.88

.10 52.6617 53.0684 -.77

.11 58.7413 59.21 33 -.80

.09 64.9200 65.3332 -.63

.11 70.9021 71 .4279 -.74

.11 76.9822 77.4975 -.66

.12 82.9643 83.5420 -.69

.08 5.1 975 5.4033 -3.81

.10 1 1 .6699 1 1 .9662 -2.48

.05 18.3384 1 8.4989 -.87

.06 24.81 08 25.0026 -.77

.06 31 .2832 31 .4780 -.62

.07 37.6575 37.9257 -.71

.05 44 .1 299 44 .3459 -.49

.03 50.6023 50.7386 -.27

.03 56.9766 57. 1041 -.22

.02 63.351

0

63.4424 -.14

.03 69.6272 69.7536 -.18

.03 75.5035 76.0377 -.18

.04 82.0817 82.2948 -.26

.05 88.2598 88.5250 -.30

.08 .9807 1 . 1 990 -18.21

.09 7.7473 8.01 79 -3.38

.06 14.61 19 14.8006 -1.27

.05 21 .3785 21 .5497 -.79

.06 28.0470 28.2666 -.78

.04 34.8136 34.9523 -.40

.03 41 .4821 41 .6075 -.30

.04 43.0526 48.2325 -.37

.05 54.6230 54.8277 -.37

.04 61 .1935 61 .3933 -.33

.03 67.7640 67.9295 -.24

.06 74.1383 74.4364 -.40

.04 80.7087 80.9143 -.25

.05 87.0831 87.3633 -.32

.06 93.4574 93.7836 -.35

.03 3.7265 3.81 35 -2.28

.02 10.7873 10.8602 -.67

.03 17.7500 17.8674 -.66

.03 24.7128 24.8375 -.50

.05 31 .5774 31 .7724 -.61 .03 38.5401 38.6731 -.34

.01 45.5029 45.5404 -.08

.00 52.3675 52.3750 -.01

-.01 59.2322 59.1773 .09 -.03 66.0968 65.9476 .23 -.02 72.7653 72.6862 .11 -.01 79.4339 79.3935 .05

-.01 86.1024 86.0697 .04

82
Table 7. (Continued)

Data sources and ID numbers: (l)Vlrial Equation, (2)Dawson, (3)Beattle, (4)Deschner, (5)Rearner,

(13)Cherney, ( 1 7 )Tom I i nson , (24)£ly, (26)Dithnar, (XXXX )Haynes, (51 , 52 )Thomas , ( 78 )Te Ichmann,

( 79)V/arowny

.

U Da+a We i g h

+

Temp

.

Densi ty Dens i ty Dens 1 ty expt ' ca 1 c Pressur

0*-v T 1-1 + rO 1 nt expt ca 1 c A t ^ < U 1 T T . InO • I\ I /I Kg/ fiT kg/

m

Mra Mr a

Oj^ ZO / 1 o 4 1 Z1 AAn yl A'^ 1 CA 4UJ • 1 5U 1 o 1 zo 1 Z .

1

jZ czc; AA 5 j5 «UU cz^ QX 5 j4 • yo A1 .01 QO X70Q yz .D /Zo QO 7 1 CI yz . / 1 51 - A C .05 ZO 4 1 J 1 «L)UU yl 1 X 1 A 4 1 J . 1 5U 1 o 1 zo 1 Z .

1

jZ (^Zc: AA 5j5 .UU C Z c A 1 5 J)5 .U 1 A A -.UU AA Z yl 1 yt yy . J 4 1 4 AQ ZOQA yy . jzyy A 1 .01 ZD 4 1 4

1 AAA 1 .uuu 0 7"^ 1 c:a Z / J . 1 5U 1 O O / X 1 Z . Z40 c / A AA 54U.UU c ^ A A1 54U .Ul - AA .UU X xxoc D .DD05 X X xoc D .DDZ5 AQ .oy ZD 41 P

1 AAA 1 .UUU O Q Z 1 C^A Zo3 . 1 5U 1 o O / X 1 Z.Z4D A AA 54U.U0 C Z A 07 539.9/ AA .00 1 Z AO c yt 1 j.yz54 1 Z O yt 1 7

1 3.y4i /

1

0

-. 1

2

ZD ^ 1 X 4 1 D

1 AAA OQ"Z 1 c;A zyJ > 1 5u 1 o O / X 1

.Z4d / A AA 54U.UU C yl A A1 54U.UI .UU 0 1 1 QOyI Z 1 . 1 oZ4 O 1 17 QA Z 1 . 1 / oU AO . uz ZO 41 /

1 AAA 1 • UUU XCiX 1 c:A JUJ . 1 5U 1 O O y1 X 1 Z

.

Z4d K ^ A AA 54U .UU C zo QX 5jy.yo A 1 .U 1 OQ Z ^ 1 O Zo . J 4 1 Z OQ Z7yt A Zo . J /4U 1 0 -. 1 z Zo 41 o

1 AAA 1 .UUU z 1 "Z 1 c; A j1 J . 1 50 1 O O 4 X

1 Z.Z40 540 .00 C Z A AX 5-?y .yo A1 .Ul Z C K A A 1 DO .5001 Z C C Z 1 X 35 .5316 AA -.09

ZD 41 y

1 AAA 1 .UUU Z O "Z 1 K A JZ J • 1 5U 1 2.246 540.00 C yt A A 1 54U .Ul AA -.UU 42 .6589 42.6520 A 0 .02

26 420 1 AAA 1 .000 333 • 1 50 1 2. 246 540 .00 539.98 .00 49. 71 97 49. 7363 -.03

26 421 1 .000 343. 1 50 1 2.246 540.00 540. 1

0

-.02 56.8786 56. 7852 .16

26 422 1 .000 353 . 1 50 1 2.246 540.00 540.04 -.01 63. 841

3

63.7993 .07 26 423 1 .000 363. 1 50 1 2.246 540.00 540. 1

2

-.02 70.9021 70.7789 .17 26 424 1 .000 373. 1 50 1 2.246 540.00 540. 1

4

-.03 77 .8648 77 . 7247 . 1

8

26 425 1 .000 383. 1 50 1 2.246 540.00 540.27 -.05 84 .9256 84 .6369 .34

26 426 1 .000 393 . 1 50 1 2.246 540.00 540.25 - .05 91 .7902 9 1 . 5 1 60 .30 26 427 1 . 000 403. 1 50 1 2.246 540.00 540.1

7

-.03 98.5568 98 .3623 .20

26 428 1 .000 273. 1 50 1 2.359 545 .00 545.08 -.01 9.8067 9.7575 .50 26 429 1 .000 283. 150 12.359 545.00 545.12 -.02 17.3578 17.2741 .48

26 430 1 .000 293. 150 1 2.359 545.00 545.09 -.02 24.81 08 24 .7444 .27 26 431 1 .000 303. 1 50 1 2.359 545.00 545.1

2

-.02 32.2639 32.1 71

1

.29 26 432 1 .000 31 3. 1 50 1 2.359 545.00 545. 19 -.04 39.7169 39.5562 .41 26 433 1 .000 323. 1 50 1 2.359 545 .00 545. 1

9

-.04 47.071

9

46.901

3

.36

26 434 1 .000 333 . 1 50 1 2.359 545.00 545.24 -.04 54.4269 54.2074 .41 26 435 1 .000 343. 1 50 1 2.359 545 .00 545.32 -.06 61 .781 9 61 .4753 .50

26 436 1 .000 353. 1 50 1 2.359 545.00 545.23 -.04 68.9407 68.7059 .34 26 437 1 .000 363.1 50 1 2.359 545.00 545. 1

9

-.03 76.0996 75. 8998 .26 26 438 1 .000 373. 1 50 1 2.359 545 .00 545.27 -.05 83.3565 83.0573 .36 26 439 1 . 000 383.1 50 1 2.359 545 .00 545 .30 -.05 90 .51 54 90.1 792 .37 ZD 440 1 AAA 1 .000 393. 1 50 1 2. 359 545 .00 545 .35 -.06 97.6742 97. 2658 .42 ZD 441 1 AAA 1 .oou OTZ 1 C A Z /J . 1 50 1 O A 70

1 Z .4 /z 550.00 550.32 -.06 1 3.3370 1 3 . 1 1 05 1 .73

ZD 44Z 1 AAA 1 .uuu O 0 1 1 CA Zo3. 1 5U 1 O A 70

1 Z .4 // CCA AA 550.00 CCA yl O 550.42 -.08 21.1 824 OA OX Ayt ZO .8694 1 C A1 .50 ZD 44J

1 AAA 1 .uuuOA Z 1 C A zy3. 1 5U 1 2 . 4 72 550 .00 550 .44 -.08 O O AO AX 28 .9295 28 .5786 1 0 z

1 .23

ZD AAA 444 1 AAA 1 .uuu

Z A "Z 1 C A 3U3. 1 5U 1 O A 70

1 Z .4 /Z 550.00 550. 52 AA -.09 36 .6769 z X 0 yl AA 36.Z40y 1 OA 1 .ZO ZD 445 1 AAA 1 . 000 31 3. 1 50 1 2.472 550.00 550.52 -.10 44.3261 43 .8586 1 .07

Zd /I ylX 44d 1 AAA 1 .uuu zo "Z 1 C A 3Z3. 1 50 1 O A 70

1 Z.4 /Z 550 .00 550.58 1 A -. 1 0

C 1 A 7 CO 51 .9 /5Z CI >i z zo 51 .433Z 1 AC 1 .05 oxZo yt yt "7 44 /

1 AAA 1 .uuu Z'ZZ 1 C^A jjj . 1 5U 1 2.472 550.00 CCA yl 7 550.4

/

AA -.uy C A yl OO Z 59 .4Zo3 CO AXX A 5o.yDDU 7 Q

. /o oxZD 44o yl yl Q 1

1 AAA .uuu XAX 1 l^A J4j . 1 5U 1 O yt 70 1 Z.4 /Z CCA AA 55U .UU CCA XA 55U.DU — . 1

1

X 7 A 7 7C D / .U / /5 XX yt C QA Oo .45oU QZ .yj oxZD A AO 44y 1 AAA 1 .uuu zc;z 1 A j5 J . 1 5U 1 O yl 70 CCA A A 55U.UU CCA CO 55U . 5o -. 1 A1 0

1 A C Z A C

/4 • 5 jU5 7Z A1 AA ID . yi 00 Q yl .o4 oxzo 45U 1 AAA 1 . uuu ZX Z 1 C^A JD J . 1 5U 1 O A 70

1 Z.4 /Z 550.00 CCA CA 5 5 U . 5U - AA .oy Q 1 Q QC Col .oo55 Q 1 ZO 07 0 1 . jZZ / XQ .oy oxZD yl c: 1 451 1 AAA I .uuu Z 7Z 1 CA 3 /3 . 1 5U 1 2.472 550.00 550 .47 A O OA O yt A C by. Z4U5 00 X AX A 00.0959 y; 1 .01 oxZo yl c^O 45Z 1 AAA 1 .uuu z o z 1 P: A JOJ . 1 50 1 O A 70

1 Z .4 /z 550.00 550. 55 1 A -.10 AX X AZX 96 .6936 AX AZ Z

1

y5.0331 X A .5y oxZD 45 J

1 AAA 1 .uuo 07 Z 1 C A 273 . 1 50 1 O O X

1 Z.5oD 555 .00 555.57 -. 1

0

17. 161

6

1 6. 7339 0 C X

Z .56 oxZo y! Kyi 454 1 AAA 1 .oou O O Z 1 C A Zo3 . 1 50 12.586 555.00 555 .57 -.10 25 .2031 24 . 7401 1 07 1 .0 / oxzo yl 455 1 AAA 1 .uuu OAZ 1 CA zy3 . 1 50 12.586 555.00 555 .53 1 A -. 1 0 33. 1 465 zo X AZ Z 3Z .5933 1 Z A 1 .3y

26 456 1 .000 303.150 12.586 555.00 555.55 -.10 41 .0899 40.5964 1 .22 26 457 1 .000 313.150 12.586 555.00 555.61 -.11 49.0333 48.4516 1 .20 26 458 1 .000 323.150 12.586 555.00 555.62 -.11 56.8786 56.2607 1.10

26 459 1 .000 333. 150 12.586 555.00 555.67 -.12 64.7239 64.0252 1 .09

26 460 1 .000 343.150 12.586 555.00 555.57 -.10 72.3731 71 .7461 .87 26 461 1 .000 353.150 12.586 555.00 555.53 -.09 80.0223 79.4244 .75 26 462 1.000 363.150 12.586 555.00 555.60 -.11 87.7695 87.0609 .81 26 463 1 .000 373.150 12.586 555.00 555.62 -.11 95.4187 94.6565 .81 26 464 1 .000 383.150 12.586 555.00 555.60 -.11 102.9698 102.21 18 .74 26 465 1 .000 273.150 12.699 560.00 560.67 -.12 21 .1824 20.6403 2.63

26 466 1 .000 283.150 12.699 560.00 560.60 -.11 29.4200 28.8991 1 .80 26 467 1 .000 293.150 12.699 560.00 560.71 -.13 37.7556 37.1014 1 .76

83
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7)Toml inson, (24)Ely, (26 )D i ttrnar , (XXXX)Haynes, ( 51 , 52 )Thomas, ( 78 ) fe Ichmann

,

( 79) Warowny

.

D Data Weight Temp. Dens I ty DensI ty Dens I ty ^expt '^ca ! c Pressu Point expt calc DIff. DIff.

No. K mol/L kg/m^ kg/m-^ % MPa MPa %

26 468 1 .000 303.150 12.699 560.00 560.77 -.14 45.9932 45.2503 1 .64 26 469 1 .000 313.150 12.699 560.00 560.68 -.12 54.0346 53.3482 1 .29 26 470 1 ,000 323.150 12.699 560.00 560.82 -.15 62.2722 61 .3970 1 .43 26 471 1 .000 333.150 12.699 560.00 560.74 -.13 70.2156 69.3981 1.18

26 472 1 .000 343.1 50 12.699 560.00 560.70 -.12 78.1590 77.3530 1 .04 26 473 1 .000 353.150 12.699 560.00 560.70 -.12 86.1024 85.2625 .99 26 474 1 .000 363.150 12.699 560.00 560.66 -.12 93.9477^ 93.1278 .88 26 475 1 .000 373.1 50 12.699 560.00 560.73 -.13 101 .891

1

100.9497 .93 26 476 1 .000 273.150 1 2.813 565.00 565.75 -.13 25.4973 24.8429 2.63

26 477 1 .000 283.150 12.813 565.00 565.62 -.11 33.9310 33.3595 1 .71 26 478 1 .000 293.150 12.813 565.00 565.66 -.12 42.4628 41 .8162 1 .55 26 479 1 .000 303.150 1 2.81

3

565.00 565.66 -.12 50.3965 50.2161 1 .35

26 480 1 .000 313.150 12.813 565.00 565.71 -.13 59.3302 58.5619 1.31 26 481 1 .000 323.150 12.813 565.00 565.63 -.1 1 67.5678 66.8554 1 .07 26 482 1 .000 333.150 1 2.813 565.00 565.60 -.11 75.8054 75.0984 .94 26 483 1 .000 343.1 50 12.81

3

565.00 565.61 -.1

1

84.0430 83.2923 .90 26 484 1 .000 353.150 12.813 565.00 565.58 -.10 92.1 825 91 .4381 .31 26 485 1 .000 363 . 1 50 1 2.81

3

565 .00 565.59 -. 1

1

1 00.3220 99.5371 .79

26 486 1 .000 273.1 50 1 2.926 570.00 5 70.80 -.14 30.1064 29.3552 2.56

26 487 1 .000 283.150 12.926 570.00 570.70 -.12 38.8343 38 . 1 349 1 .83 26 488 1 .000 293.1 50 12.926 570.00 570.68 -.12 47.5623 46.8513 1 .52 26 489 1 .000 303.1 50 1 2.926 570.00 570.62 -.11 56.1921 55.5076 1 .23

26 490 1 .000 313.150 12.926 570.00 570.62 -.11 64.8220 64.1065 1 .12 26 491 1 .000 323.150 12.926 570.00 570.59 -.10 73.3537 72.6501 .97 26 492 1 .000 333.150 12.926 570.00 570.60 -.10 81.8855 81 .1401 .92 26 493 1 .000 343. 150 12.926 570.00 570.50 -.09 90.2212 89.5780 .72 26 494 1.000 353.150 12.926 570.00 570.51 -.09 98.6549 97.9653 .70 26 495 1 .000 273.150 13.039 575.00 575.81 -.14 35.0097 34.191

0

2.39

26 496 1 .000 283.150 13.039 575.00 575.75 -.13 44.0319 43.2393 1 .83 26 497 1 .000 293.1 50 13.039 575.00 575.66 -.11 52.9559 52.2208 1 .41 26 498 1 .000 303.150 13.039 575.00 575.55 -.10 61 .7319 61 .1389 1 .05 26 499 1 .000 313.150 13.039 575.00 575.50 -.09 70.6079 69.9962 .87 26 500 1 .000 323.150 13.039 575.00 575.50 -.09 79.4339 78.7951 .81 26 501 1 .000 333.150 13.039 575.00 575.47 -.08 88.1618 87.5373 .71 26 502 1 .000 343.150 13.039 575.00 575.41 -.07 96.7916 96.2246 .59

26 503 1 .000 273.150 13.153 580.00 580.69 -.12 40.1092 39.3645 1 .89 26 504 1 .000 283.150 13.153 580.00 580.57 -.10 49.3274 48.6870 1 .32 26 505 1 .000 293.150 13.153 580.00 580.51 -.09 58.5457 57.9391 1 .05 26 506 1 .000 303.150 13.153 580.00 580.36 -.06 67.5678 67.1244 .66 26 507 1 .000 313.150 13.153 580.00 580.34 -.06 76.6880 76.2456 .58 26 508 1 .000 323.150 13.153 580.00 580.30 -.05 35.7101 85.3051 .47 26 509 1 .000 333.150 13.153 580.00 580.24 -.04 94.6342 94.3049 .35 26 510 1 .000 343.150 13.153 580.00 580.15 -.03 103.4602 103.2468 .21 26 51 1 1 .000 273.150 13.266 585.00 585.53 -.09 45.5029 44.8904 1 .36

26 512 1 .000 283.150 13.266 585.00 585.44 -.07 55.0153 54.4927 .96 26 51 3 1 .000 293.150 13.266 585.00 585.33 -.06 64.4297 64.0210 .64 26 514 1 .000 303.150 13.266 585.00 585.20 -.03 73.7460 73.4790 .36 26 515 1 .000 313.150 13.266 585.00 585.21 -.04 83.1604 82.8696 .35 26 516 1 .000 323.150 13.266 585.00 585.13 -.02 92.3786 92.1951 .20 26 51 7 1 .000 333.150 13.266 585.00 585.03 -.00 101 .4988 101 .4579 .04 26 51 8 1 .000 273.150 13.380 590.00 590.09 -.02 50.8965 50.7836 .22 26 519 1 .000 283 . 1 50 13.380 590.00 590.02 -.00 60.7032 60.671

4

.05 26 520 1 .000 293.150 13.380 590.00 589.95 .01 70.41 17 70.4816 -.10

26 521 1 .000 303 . 1 50 13.380 590.00 589.93 .01 80.1203 80.21 79 -.12

26 522 1 .000 313.150 13.380 590.00 589.83 .03 89.6328 89.8833 -.28

26 523 1 .000 323.150 13.380 590.00 589.71 .05 99.0472 99.4805 -.44

84
Table 7. (Continued)

Data sources and ID numbers: (l)VIrlal Equation, (2)Dawson, (3)BeattIe, (4)Deschner, (5)Rea(ner,

(13)Cherney, ( 1 7)Toml inson, (24)Ely, (26)Dittmar, (XXXX)Haynes, (51 ,52 )Thomas, (78)TeIchmann,

(79)Warowny

.

ID

1201 1202

1203

1204

1205

1206

1207

1208

1209

1210

1001 1002

1003

1004

1005

1006

1007

1008

1009

1010

1011 1012

501 502

503 504

505 506

507 508

509 510

511 512

513 514

601 602

603

604 605

606

607

608

609

610

611 612 613

614

401 402

Data

Point

Noo

524

525

526

527

528

529

530

531 532

533

534

535 536

537 538

539

540

541 542 543

544

545

546

547

548

549

550

551 552

553

554

555 556

557

558

559

560

561 562 563

564

565

566 567

568

569

570

571 572 573

574 575

We ight

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

Temp.

K

90.000

90.000

90.000

90.000

90.000

90.000

90.000

90.000

90.000

90.000

100.000

100.000

100.000

100.000

100.000

100.000

100.000

100.000

100.000

100.000

100.000

100.000

1 10.000

1 10.000

1 10.000

110.000

110.000

110.000

1 10.000

1 10.000

110.000

1 10.000

1 10.000

1 10.000

1 10.000

1 10.000

120.000

120.000

120.000

120.000

120.000

120.000

120.000

120.000

120.000

120.000

120.000

120.000

120.000

120.000

130.000

130.000

Density

expt

mol/L kg/rrr

16.799

16.775

16.751 16.726

16.701 16.675

16.648

16.621

1 6.594

16.567

16.594

16.561 16.530

16.503

16.476

16.448

16.420

16.397

16.374

16.356

16.338

16.321

16.376

16.347

16.318

16.288

16.259

16.229

16.201 16.178

16.155

16.131

16.1 14 16.098

16.087

16.082

16.180

16.141

16.104

16.073

16.041 16.008

15.977

15.952

15.923

15.897

15.878

15.862

15.853

15.848

15.958

15.922

740.78

739.73

738.67

737.59

736.48

735.31

734.15

732.96

731 .76 730.57

731 .74 730.23

728.94

727.74

726.53

725.29

724.05

723.04

722.03

721 .24 720.46

719.70

722.15

720.84

719.57

718.26

716.96

71 5.67

714.41

713.39

712.39

71 1 .35 710.60

709.89

709.40

709.18

713.50

71 1 .78 710.16

708.76

707.36

705.91

704.54

703.45

702.18

701 .02 700.17

699.45

699.08

698.84

703.72

702.13

Density

calc

kg/m-^

739.91

738.86

737.79

736.71

735.62

734.52

733.40

732.26

731 .12 729.95

730.90

729.55

728.29

727.13

725.95

724.76

723.55

722.57

721 .58 720.58

719.82

719.06

721 .41 720.10

718.88

71 7.63

716.37

71 5.14

713.97

712.97

71 1 .93 710.85

710.09

709.35

708.85

708.61

712.77

71 1 .12 709.54

708.21

706.86

705.48

704.14

703.06

701 .79 700.63

699.74

699.00

698.62

698.39

703.31

701 .74

Density

DIff

.

expt cal c Pressure

DIff.

1

f> Mra Mra elP

j4 . /zl

4

"7 t;A 1 c; - / .DD

.1 ^

t: 1 o T0

1

31 . z /ol t A 1 O AA 34. 1 zOO -8.33

1 o z / .

0

j4d .D /yb A O T -9 . Z /

1 o .1 I z4. jy 1

J

0"7 1 O 1 z / . 1 ol

5

1 A O

1 o . 1 z zU. 94 /9 23 .6556 -1 1 .45

1 1 . 1 1 1 / .D04O 1 A AOA C 19.9806 -1 2 . 39

1 r\ ^ A A(C1 c; 1 <^ 1

A

1 b. JO /4 1 A f\Ci

.(jy 1 A ^

1

1 O "70 AQ 1 z. /zUo -10.53

.09 "7 1 *7C >1 / . 1 /34 A 1 AA/^ 9 . 1 096 -21 .23

.08 3.7326 5.5597 -32.86

. 1 1 35 . 7539 38.3478 -6.76

.10 31 .621

9

33.8520 -6.59

.09 27.8341 29.8013 -6.60

.08 24.391

0

26. 1906 -6.87

.08 20.9477 22 .6289 -7.43

.07 1 7.5047 19.0268 -8.00

.07 14.0615 1 5.4877 -9.21

.07 1 1 .3072 1 2.6299 -1 0.47

.06 8.5527 9.8048 -1 2 .77 .09 5.7985 7.6069 -23.77

.09 3.7328 5.4530 -31 .55 .09 1 .6670 3.3899 -50.82

.10 34.9955 37.1324 -5.75

.10 31 .2768 33.3625 -6.25

.10 27.8332 29.7598 -6.47

.09 24. 3900 26. 1 237 -6.64

.08 20.9466 22 .5535 -7.12

.07 1 7 .641

3

1 9.0598 -7.44

.06 1 4 .5424 1 5 .6992 -7.37

.06 1 1 .9258 1 3.031

8

-8.49

.07 9.2401 10.441

1

-1 1 .50

• 07 6. 4857 7.7448 -1 6.26

.07 4 .5578 5 .8500 -22.09

.08 2.6985 4.0601 -33.54

.08 1 .4591 2. 8237 -48.33

.08 .8761 2.2849 -61 .66

.10 36.3748 38.3563 -5.17

.09 31 .9673 33.7323 -5.23

.09 27.8350 29.4408 -5.45

.08 24.391 9 25 .8077 -5.49

.07 20.9485 22.2216 -5.73

.06 1 7.5053 18.5722 -5.74

.06 14.1999 15.1895 -6.52

.06 1 1 .5833 1 2.5220 -7.50

.05 8.5533 9.4667 -9.65

.06 5.7991 6.7266 -13.79

.06 3.7334 4.7320 -21 .10

.06 2.0118 3.0527 -34.10

.07 1 .151

2

2.2083 -47.37

.07 .6141 1 .6608 -63.02

.06 35.3418 36.3798 -2.85

.06 31 .4162 32.3954 -3.02

85
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)3eattie, (4)Deschner, (5)Reainer,

(13)Cherney, ( 1 7)Tom I i nson, (24)Ely, (26)Dittinar, (XXXX)Haynes, ( 51 , 52 )Thomas, (78)Teichrnann,

(79)Warowny

.

1 u Data We 1 g n r Temp

.

Dens i ty Dens i ty Dens i ty pexpt '^cal c Pressur

Po i n t expt ca 1 c

n I ^ i U 1 tt • D i f f

.

No • K mol/L kg/m-" % MPa MPa %

403 575 1 .000 130.000 IK OO A "7 A A CO /UU •DO 700.34 .05 27.9727 28.8070 -2.90

404 577 1 .000 130.000 1 c oci":

1 0 mODJ £! AA 1 698.85 .04 24.391

7

25.1302 -2.94

40P 0 fo ] •UUU 1 'Zr\ AAA 1 * UU'J 1 £^ Q O 1 £ A"7 glQ by / •DO £f\~I /A 69 / .40 • 04 A A r\ A a A 21 .6014 -3.02

A 0 /y 1 r\r\f\ 1 "^A AAA 1 J»U« UUU 1 D • /4D oy4 • J) / iUdA 10 A "Z •Oj ^ t c 1 1 "z 1 3.5 1 13 1 3.9329 -3.03

hU I DoU 1 AAA 1 •UU'J 1 "^A AAA i jU^UUU 1 c "71 A

oy--> • 1 o AO A"?

• U^ 1 A ~T C A 1 u» /9Dy 11 1 AAO 11.1 99z -3 .95

A HQ Q 1 1 AAA 1 •UUU 1 XC\ AAA 1 J>U« UUU 1 D •oyu oyt «00 oyi .D? A , •U^ / .oo4 / 0. JDO

/

ll AO -6 .Oz

A AO Doz 1 AAA 1 .UUU 1 "^A AAA 1 -->U 9 UUU ! 0 •ODD OA QO oyu • oz 690 .55 A>1

• U4 K A Cl AO y •494o C A >! 1 1 O.U41

1

A T

1

-y . 71 4 1 U RQ ^ 1 AAA 1 •UUU 1

! D\J "^A

• AAA UUU 1 A/1

«

1 0 • D^O AQA Dvu • ARur> Doy. /5 •U4 3» /333 4. J /yu 1 A *7K -1 4 . /j 4 1 1 !!) CS4 1 AAA 1 •UUO 1 "^A AAA 1 _>U •UUU Doy • ^4 QQ A1 Doy .Ui Af^

• U-) 0 \ A Ac; / • 1 4y9 z . o54

/

0 A "7A -z4. /O 4 1 Z OoO 1 AAA 1 •UUU 1

1 JU"^A• AAA UUU I 0 © OZ

(iOQ AO DoV • UZ Dod . oy At^

• U J

1 A (-.rid

1 • 4DUy 0 1 1^ "7Q Z. 1 D /O X 0 1 -jz . ol 4 1 J

1

1 eUUJ AAA 1

1 J)U "^A AAA UUU 1

1 sJ • A9n ozu DOO

•

/

DoO .40 Ac;• U9 • y /oy 1 ^ "7 AQ 1 .0 / Uo -41 .41

zl 1 4 JO 1 ! • UUU 1

1 J)U "7A• AAA UUU (-'•DID ftPR U 00 ft/1 9 j'-r <CQO OA DOO .zy • ARU -> • OZ / /

1 7R97 1 . jjZ / —J J .DU

/ U 1 1 nnn t HU • UUU 15.769 695.36 fiQ4 D . Q1^

1

• Aft UO _?D 7ft • 7PR1 / 00 1 J^7/ . RS74 0J m —9Z .OZR9

1 \j ^. 1 c UUU 1 HU 9 \J\J\J 15.727 693.50 fiQ^ U 1 . t D • nsU J JZ"^9 ft'^iftn • D JDU JWJ . 44'=iQ ^'t jy -9Z ^fi . JD

703 590 1 .000 140.000 1 (SR4 u " 1 . u_/ 691 .37 .04 28.5239 29. 11 91 -2.04

704 591 1 .000 140.000 ^RQ 77 689.55 .03 24.3920 24.8962 -2.03

140 000 fiRR 000 1 . 1 J f^RR ooo. 00UU • 09uz 90z u . Q4R7 y+o / 91z 1 . 9RR7 zoo

/

-11 .OUfiO /VJD 1 non 1

1 40'4U . 000 UUU DOO .

(=;Rf=. 000 . 41H

1

. 09uz 1 7 SOSfi 1 7 7^04 -1 "^R 1 .JO 707 140 1 H U » 000 UUU fiRS U Q ^ •.00UU fiR4 Q'^ D OH . . 01U 1 1 4 ^^7R 1 4 Alf^i. 7nfl / uo Jy J 1 onn 1

1 40HU . OOO UUU 1 ^ ^04 fifl'^ u 0^ . 70/ u (oR'^ D OJ 9OJ .U011 1 1 fiR9 1 1 7409 — . 7R/ J 7nQ 1 nno 140 1 H U . 000 UUU IS 4 74 ^iR9 "^4 DOZ . JZ • 00UU R0 .o^RQ77/

/

R0 . Q'^ftl )7JO 1 • *t J

71 n "107 1 000 1

1 40^U . 000 UUU 1 R 44Q !=,fl1 97 fiRI QO 1 . Z91

1

.U011 u . DZ D. / JZ-\J -11 .00RR

71 1 / 1 1 1 ooo 1

\ 40H\J * ooo UUU 11 Sy s ^ZO DOU .ZJ ftRO DOU 1 1 • I 1 • 09uz 4 «HZZ 4991

1

4 fiS74 J . OSU J

71 O jyy 1 AAA 1 >1 A AAA 1 4U. UUU IK y1 A7 1 o 4U / 0 / y .4z D /y . ZP A"^ .U J

0Z. 7AOR /UUP J.U4^

J

—— 1

1 11 . 94Z4

71"^ DUU 1

1 .UUU AAA 1

1 4U« y1 A AAA UUU 1 D . jy

/

D / o . yp A 7Q 79 D /O . /Z A"^ \ *DO /D 9z . 111 1 Q9yz — 91 '^1 Z 1 .J 1 71^ / 1 4 DU 1 1

1 . AAA UUU 1 Af\ AAA 1 4U . UUU 1 5 . joy D /O .0

1

^;7« "^7 D /O. J / A"^ Q7Q1 • y /y 1 1 o44jj ——JZ^9 1 ft . 1

D

oU 1 ^ AO DUZ 1 AAA 1 .UUU 1 ^A AAA 1 DU .UUU 15.354 677.06 e^^c QQ D / D » yo A1 • UI JO .44 JO Xii; AOQQ jD.Dzyy — • J 1 802 603 1 .000 160.000 1 K "^A/

1 5 . J>U4 0 /4 . 00 674.82 .01 31 .9674 32.0922 -.39

803 604 1 .000 160.000 1 C O C Q

1 5 .z5o D /Z.OZ 672.78 .01 27.8352 27.9097 -.27

oU4 1 AAA 1 .UUU 1 A AAA I DU oUUU 1 5 . z 1 0

c "7 1 A£: D / 1 . UO A/ D / 1 «U4 AA .UU '-) A XQ91 z4 . jyz

1

9^ /I "Z A z4 • 4J)4U _ 1-7 — . 1 / 805 606 1 .000 1 A AAA 1 60.000 1 5 . 1 78 669.31 669. 26 A1 .01 OA A ^ Q "7 zU. y4o

/

01 A y1 A"? Z 1 • U4U3 - / A .44 806 607 1 .000 1 A AAA 160.000 1 5. 1 37 667 .48 667 .45 A

1

.01 1 7 .5056 IT C; TAA 1 / •!? /OU T -7 -.37

807 608 1 .000 1 60 .000 1 5 .094 665.60 665.59 .00 1 4.0623 1 A AOAC1 4 .0805 -.13

808 609 1 .000 1 60 .000 1 5.059 654.06 664.07 -.00 1 1 .3080 1 1 . 2808 0 >i .24 809 61

0

1 .000 1 A A A ^

1 60 .000 1 5 .024 652.51 662.52 -.00 8.5534 8. 5273 .31 81

0

61

1

1 .000 160.000 1 4-988 660.92 660.94 -.00 5.7992 5. 751

1

0 A .84

81

1

612 1 .000 1 60.000 1 4.960 659. 70 659.74 -.01 3. 7335 3.6738 1 ^01 .62

81 2 61 3 1 .000 160.000 1 4.938 658.72 658. 72 -.00 2.01 1

9

2.0056 .32 813 61

4

1 .000 1 60 . 000 1 4.924 658.08 658. 10 - .00 .9791 .951

7

2 .88

901 61 5 1 .000 1 80.000 14.963 659.84 659.89 -.01 37.4764 37.3754 .27 AAO yoz 61 6

1 AAA 1 .UUU 1 O A AAA 1 oO.UUU 14.912 657.56 65 / .DD A1 -.01 7 -7 ~z. A AX J J. j44j "7 1 TKA J J . 1 /j4 1^0

. 5z 903 61 7 1 .000 180.000 14,858 655.21 655.36 -.02 29.2121 28.9623 .86 904 618 1 .000 180.000 14.804 652.80 652.99 -.03 25.0803 24.7507 1 .33 905 619 1 .000 180.000 14.749 650.40 650.55 -.02 20.9483 20.6943 1 .23 906 620 1 .000 1 80.000 14.701 648.28 648.46 -.03 1 7.5052 17.2164 1 .68 907 621 1 .000 180.000 14.653 646.17 646.35 -.03 14.1308 13.8317 2.16

908 622 1 .000 1 80.000 14.613 644.37 644.55 -.03 1 1.3076 1 1 .0336 2.48

909 623 1 .000 180.000 14.571 642.53 642.74 -.03 8.5530 8.2277 3.95

910 624 1 .000 180.000 14.528 640.64 '640.90 -.04 5.7988 5.41 82 7.03

91

1

625 1 .000 180.000 14.495 639.19 639.48 -.05 3.7330 3.3175 12.52

912 626 1 .000 180.000 14.462 637.75 638.03 -.04 1 .6671 1 .2636 31 .93 913 621 1 .000 180.000 14.452 637.28 637.55 -.04 .9786 .6002 63.04

85
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)8eattle, (4)Deschner, (5)Rearner,

(13)Cherney, (1 7)Tom! inson, (24)Ely, (26)0 ittmar, (XXXX)Hayne3, (51 , 52 )Thomas, (78)Teichmann,

(79)Warowny

.

10 Oata

Point

No.

Vie i ght Temp.

K mo

Dens i ty

expt

/L kg/m^

Dens i ty

calc

kg/nr

Dens I ty

DIff

.

expt

MPa

cal c

iMPa

Pressure

Dif f

.

2901 2902

2903

2904

2905

2906

2907

2908

2909

2910

2911 2912

628

629

630

631 632

633

634

635

636

637

638

639

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

200.000

200.000

200.000

200.000

200.000

200.000

200.000

200.000

200.000

200.000

200.000

200.000

14.535

14.484

14.431 14.378

14.322

14.265

14.206

14.158

14.109

14.060

14.022

13.984

640.95

638.70

636.38

634.02

631 .57 629.04

626.45

624,33

622.19

619.99

618.32

616.64

640.72

633.57

636 .36 634.09

631.74

629.33

626.83

624.77

622.65

620.47

618.73

61 7.06

.04

.02

.00 -.01 -.03

-.05

-.06

-.07

-.07

-.08

-.08

-.07

34. 7203

31 .2770

27.8334

24.3903

20.9469

17.5038

14.0606

1 1 .3062

8.5516

5.7974

3.7317

1 .6657

35.0966

31 .4860

27.3681

24.2837

20.6993

17.0986

13.5460

10.7260

7.9584

5.21 18 3.1679

1 .1720

-1 .07 -.66

-.12

.44

1 .20

2.37

3.80

5.41 7.45

1 1 .24

1 7.80

42.13

3001 3002

3003

3004

3005

3006

3007

3008

3009

3010

3011 3012

640

641 642

643

644

645

646

647

648

649

650

651

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

220.000

220.000

220.000

220.000

220.000

220.000

220.000

220.000

220.000

220.000

220.000

220.000

14.129

14.070

14.010

13.950

13.889

13.826

13.761 13.704

13.645

13.584

13.537

13.490

623.05

620.46

617.82

61 5.17

612.48

609.70

606.82

604.30

601 .69 599.00

596.96

594.38

623.03

620.58

618.06

61 5.44

612.74

609.93

607.00

604.57

602.06

599.45

597.42

595.34

.00

.02

.04

.04

.04

.04

.03 .04

.06 .07

.08 .08

34 . 7208

31 .2774

27.8339

24.3908

20.9474

17.5043

14.0610

11 .3067

8.5521

5.7979

3.7321

1 .6662

34.7474

31 .1005

27.5096

24.0357

20.6331

17.2305

13.8545

1 1 .0074

8.1566

5.3387

3.2695

1 .2194

-.08

.57 1.18

1 .48

1 .52

1 .59

1 .49 2.72

4.85

8.60

14.15

36.64

3101 3102

3103

3104

3105

3106

3107

3108

3109

3110

3111

31 12

652

653

654

655 656

657

658

659

660

661 662

663

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

240.000

240.000

240.000

240.000

240.000

240.000

240.000

240.000

240.000

240.000

240.000

240.000

13.738

13.669

13.598

13.527

13.454

13.379

13.301 13.236

13.166

13.093

13.035

12.976

605.80

602.75

599.65

596.51

593.28

589.95

586.54

583.65

580.56

577.36

574.82

572.21

605.27

602.48

599.58

596.56

593.41

590.12

586.66

583.77

580.75

577.58

575.10

572.52

.09

.05

.01 .01 .02 .03

.02 .02

.03 .04

.05 .05

34.7217

31 .2784

27.8348

24.3916

20.9432

17.5052

14.0619

1 1 .3076

8.5530

5.7983

3.7331

1 .6672

35.3947

31 .61 1 4 27.9215

24.3384

20.8073

17.3376

13.9383

11 .1980

8.3877

5.6033

3.5014

1 .4215

-1 .90

-1 .05

-.31

.22

.68 .97

.89

.98 1.97

3.40

6.62

17.28

3201 3202

3203

3204

3205

3206

3207

3208

3209

3210

321 1 3212

3213

3214

664

665

666

667

668

669

670

671 672

673

674 675

676

677

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

260.000

260.000

260.000

260.000

260.000

260.000

260.000

260.000

260.000

260.000

260.000

260.000

260.000

260.000

13.320

13.245

13.166

13.101 13.034

12.964

12.393

12.818

12.739

12.676

12.611

12.543

12.472

12.422

587.38

534.05

580.60

577.73

574.75

571 .69 563.52

565.25

561 ,75

558.98

556.09

553.12

549.98

547.77

537.38

584.13

580.34

573.05

575.15

572.13

568.96

565.64

562.15

559.40

556.52

553.51

550.35

543.14

.00

.02 .04

.06 .07

.03 .08

.07 .07

.08 .03

.07

.07

.07

34.7213

31 .2780

27.3346

25.0301

22.3253

19.5709

16.8163

14.0619

1 1 .3076

9.2417

7.1760

5.1 103 3.0445

1 .6673

34.7204

31 .1370

27.5377

24.7671

21 .9556

19.1867

16.4449

13.7433

11 .0035

8.9328

6.3732

4.3477

2.8122

1 .4397

.00

.45 .89

1 .26

1 .63 2.00

2.26

2.32

2.76

3.46

4.41 5.42

8.26

15.31

3301 3302

673

679

1 .000

1 .000

275.000

275.000

13.01 7 12.934574.00

570.35

573.35

570.31

.03

.01 34.7209

31 .2776

34.8709

31 .3188

-.43

-.13

87
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)38attle, (4)Deschner, (5)Reainer,

(13)Cherney, ( 1 7)TomI inson, (24)Ely, (26 )0 i ttinar , (XXXX)Haynes, (51 ,52 )Thoinas, ( 78 )Te Ichmann,

( 79) 'Warov/ny

.

ID Data Weight Temp. Dens ity Dens i ty Dens i ty pexpt P— 1 ^ ca 1 c Pressu Point expt calc Diff. Diff.

No. K .noi/L kg/m-' kg/m-^ % MPa MPa %

3303 680 1 .000 275.000 12.846 566.49 566.58 -.02 27.8341 27.7497 .30 3304 681 1 .000 -"lie /^/^ /"N 275 .000 12.774 563.28 563 .46 -.03 25.0796 24.9305 .60 3305 682 1 .000 2 75.000 12.697 559.89 560.19 -.05 22.3248 22.0817 1 .10 3306 683 1 .000 275.000 12.61

7

556.39 556.75 -.07 19.5704 19.2874 1 .47 3307 684 1 .000 275.000 12.536 552.80 553.13 -.06 16.8157 16.5724 1 .47 3308 685 1 .000 275.000 12.451 549.05 549.31 -.05 14.061

2

13.8837 1 .28 3309 686 1 .000 275.000 12.361 545.09 545.24 -.03 1 1 .3070 1 1 .2077 .89 3310 ,687 1 .000 275.000 12.288 541 .88 542.01 -.02 9.2410 9.1659 .82 3311 688 1 .000 2 75.000 12.210 538.43 533.59 -.03 7.1752 7.0791 1 .36 3312 689 1 .000 275.000 12.127 534.74 534.98 -.04 5.1095 4.9791 2.62

3313 690 1 .000 275.000 12.051 531 .43 531 .79 -.07 3.3880 3.2015 5.82

3314 691 • 1.000 275.000 11 .974 528.01 528.41 -.08 1 .6665 1 .4695 13.41

3401 692 1.000 290.000 12.702 560.13 560.22 -.02 34.7213 34.6376 .24 3402 693 1 .000 290.000 1 O f^OQ

1 ^.DUO Ojy . y

/

556.29 -.06 31 .2781 31 .0094 .87 3403 694 1 .000 290.000 12.511 551 .69 552.12 -.08 27.8346 27.4860 1 .27 j4U4 oy? ! ©UUU ^yj •UUU 12.428 548.06 •"• 1 u

1 3405 696 1.000 290.000 12.342 544.25 544.90 -.12 22.3255 21 .8570 2.14

3406 697 1 .000 290.000 12.251 540.24 540.99 -.14 19.571

0

19.0643 2.66

3407 698 1.000 290.000 12.156 536.06 536.82 -.14 16.8164 16.3323 2.96

3408 699 1 .000 290.000 12.057 531 .66 532.38 -.13 14.0622 13.6379 3.11 3409 700 1 .000 290.000 1 1 .949 526.92 527.59 -.13 1 1 .3077 10.9363 3.40

3410 701 1 .000 290.000 1 1 .864 523.17 523.74 -.11 9,2418 8.9475 3.29

3411 702 1 .000 290.000 1 1 .773 519.15 519.63 -.09 7.1761 6.9438 3.34

3412 703 1 .000 290,000 1 1 .672 514.71 515.20 -.10 5.1104 4.8915 4.47

3413 -704 1 .000 290.000 1 1 .581 510.69 511 .23 -.10 3.3888 3.1678 6.98

3414 705 1 .000 290.000 1 1 .486 506.50 506.94 -.09 1 .6674 1 .4977 11 .33

2801 706 1 .000 300.000 12.493 550.92 551 .07 -.03 34.7209 34.6014 .35 2802 707 1 .000 300.000 12.395 546.57 546.84 -.05 31 .2776 31 .0625 .69 2803 708 1 .000 300.000 12.288 541 .86 542.36 -.09 27.8341 27.4645 1 ,35

2804 709 1 .000 300.000 12.201 538.02 538.55 -.10 25.0795 24.7096 1 .50 2805 710 1 .000 300.000 12.109 533.99 534.52 -.10 22.3248 21 .9737 1 .60 2806 711 1 .000 300.000 12.01

1

529.64 530.23 -.11 19.5703 19.2037 1 .91 2807 712 1 .000 300.000 1 1 . 904 524.93 525.64 -.14 16.8157 16.4035 2.51 2808 713 1 .000 300.000 1 1 .790 519.92 520.70 -.15 14.061

3

13.6454 3.05

2809 714 1 .000 300.000 1 1 .670 514,61 515.34 -.14 1 1 .3070 10.9489 3.27

2810 715 1 .000 300.000 11 .573 510.32 510.98 -.13 9.2410 8.9427 3.34

281

1

716 1 .000 300.000 1 1 .462 505,42 506.26 -.17 7.1 752 6.8236 5.15

2812 717 1 .000 300.000 11.348 500.42 501 .12 -.14 5.1095 4.8428 5.51 2813 718 1 .000 300.000 1 1 .265 496.73 497.40 -.13 3.7324 3.4948 6.80

2814 719 1 .000 300.000 11.174 492.75 493.40 -.13 2.3551 2.1398 10.06

88
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattle, (4)Deschner, (5)Reainer,

(13)Cherney, ( 1 7 )Toml inson , (24)Ely, ( 26 )D I ttinar , (XXXX )Haynes, (51 ,52 )Thomas, ( 78) Telchmann,

( 79) Warowny

.

D Data Weight Temp. Dens i ty Dens i ty Dens I ty P

©xpi" ^ca 1 c Pr essui Point expt calc DIff

.

Dif f

.

No. K mol/L kgArr' kg/wr % MPa f4^a %

24 932 1 .000 288.263 11 .518 507.93 507.82 .02 .9950 1 .0384 -4.18

24 933 1 .000 288.981 1 1 .518 507.92 507.80 .02 1 .4087 1 .4541 -3.12

24 934 1 .000 291 .393 1 1 .518 507.91 507.76 .03 2.7986 2.8591 -2.12

24 935 1 .000 293.489 1 1 .518 507.89 507.72 .03 4.0067 4.0744 -1 .66 24 936 1 .000 296.555 1 1 .517 507.87 507.68 .04 5.7744 5.8539 -1 .36 24 937 1 .000 300 . 1 04 11 .516 507.84 507.64 .04 7.8212 7.9082 -1.10

24 938 1 .000 303.696 1 1.516 507.82 507.61 .04 9.8936 9.9888 -.95

24 939 1 .000 307.131 1 1 .51

5

507.79 507.58 .04 1 1 .8760 1 1 .9708 -.79

24 940 1 .000 310.771 1 1.515 507.77 507.57 .04 13.9780 1 4.0735 -.68

24 941 1 .000 314.179 11 .514 507.74 507.56 .04 15.9460 16.0341 -.55

24 942 1 .000 31 7.799 1 1 .514 507.72 507.56 .03 18.0380 1 8.1 195 -.45

24 943 1 .000 321 .470 11 .513 507.69 507.56 .03 20.1600 20.2263 -.33

24 944 1 .000 277.973 1 1 .837 521 .97 521 .90 .01 .5517 .5835 -5.45

24 945 1 .000 278.268 1 1 .837 521 .97 521 .90 .01 .7419 .7741 -4.16

24 946 1 .000 280.501 1 1 .836 521 .95 521 .89 .01 2.1805 2.2070 -1 .20 24 947 1 .000 283.701 11 .836 521 .93 521 .88 .01 4.2392 4.261

1

-.51 24 948 1 .000 288.949 11.835 521 .88 521 .87 .00 7.6082 7.6135 -.07

24 949 1 .000 294.597 1 1 .834 521 .84 521 .85 -.00 11 .2241 1 1 .2173 .06 24 950 1 .000 299.983 1 1 .833 521 .80 521 .84 -.01 14.6620 14.6428 .13 24 951 1 .000 308.342 1 1 .832 521 .74 521 .80 -.01 19.9780 19.9412 .18 24 952 1 .000 319.913 1 1 .830 521 .65 521 .76 -.02 27.3000 27.2340 .24 24 953 1 .000 267.752 12.155 536.01 535.79 .04 .4041 .5227 -22.69

24 954 1 .000 268.361 12.155 536.00 535.78 .04 .8370 .9521 -1 2.09

24 955 1 .000 269.31

8

12.155 536.00 535.78 .04 1 .5169 1 .6348 -7.21

24 956 1 .000 270.036 1 2.155 535.99 535.78 .04 2.0268 2.1413 -5.35

24 957 1 .000 271 .190 12.155 535.98 535.77 .04 2.8457 2.9581 -3.80

24 958 1 .000 273.224 12.154 535.96 535.77 .04 4.2877 4.3946 -2.43

24 959 1 .000 275.321 12.154 535.95 535.76 .04 5.7722 5.8794 -1 .82 24 960 1 .000 277.531 12.153 535.93 535.75 .03 7.3345 7.4365 -1 .37

24 961 1 .000 280.521 12.153 535.90 535.74 .03 9.4447 9.5375 -.97

24 962 1 .000 283.740 1 2 . 1 52 535.88 535.73 .03 1 1 .7120 1 1 .8018 -.76

24 963 1 .000 287.984 12.151 535.84 535.71 .02 14.6930 14.7714 -.53

24 964 1 .000 293.573 12.150 535.80 535.69 .02 18.6070 18.6775 -.38

24 965 1 .000 299.091 12.149 535.75 535.67 .02 22.4570 22.51 34 -.25

24 966 1 .000 304.757 12.148 535.70 535.64 .01 26.3950 26.4392 -.17

24 967 1 .000 312.701 12.147 535.64 535.59 .01 31 .8910 31 .9273 -.11

24 968 1 .000 323.740 12.145 535.55 535.52 .01 39.4790 39.5054 -.07

24 969 1 .000 258.574 12.446 548.83 548.46 .07 .7550 .9794 -22.91

24 970 1 .000 260.283 12.446 548.82 548.47 .06 2.0907 2.3072 -9.38

24 971 1 .000 264.687 12.445 548.78 548.49 .05 5.5231 5.7107 -3.29

24 972 1 .000 269.204 12.444 548.74 548.50 .04 9.0289 9.1889 -1 .74 24 973 1 .000 273.221 12.443 548.70 548.50 .04 12.1340 12.2680 -1 .09 24 974 1 .000 278.846 12.442 548.65 548.50 .03 16.4630 16.5672 -.63

24 975 1 .000 283.771 12.441 548.61 548.50 .02 20.2350 20.3188 -.41

24 976 1 .000 288.215 12.440 548.57 548.48 .02 23.6230 23.6893 -.28

24 977 1 .000 293.359 12.439 548.53 548.46 .01 27.5270 27.5819 -.20

24 978 1 .000 297.819 12.438 548.49 548.43 .01 30.8960 30.9413 -.15

24 979 1 .000 300.501 12.438 548.46 548.42 .01 32.9150 32.951

5

-.11 24 980 1 .000 305.386 12.437 548.42 548.38 .01 36.5800 36.6151 -.10

24 981 1 .000 310.827 12.435 548.37 548.33 .01 40.6410 40.6767 -.09

24 982 1 .000 250.200 12.689 559.53 559.02 .09 .7767 1 .1235 -30.87

24 983 1 .000 251 .067 12.688 559.52 559.04 .09 1 .51 43 1 .8463 -1 7.98

24 984 1 .000 251 .924 12.688 559.51 559.05 .08 2.2426 2.5600 -1 2.40

24 985 i .000 253.890 12.688 559.49 559.08 .07 3.9104 4.1969 -6.83

24 986 1 .000 258.31

1

12.687 559.45 559.14 .06 7.6451 7.8699 -2.86

24 987 1 .000 263.206 12.686 559.40 559.19 .04 1 1 .7550 11.9142 -1 .34

89
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equati

(13)Cherney, ( 1 7 )Tom I i nson , (24)£ly, (26)Dittm

(79)Warowny.

D Data Weight Temp

.

Dens I ty

Point expt

No. K mol /L kg/m^

24 988 1 .000 263.259 1 2.686 559.40

24 989 1 .000 268.01

4

1 2.685 559.36

24 990 1 .000 276.292 1 2.683 559.28

24 991 1 .000 283.434 1 2.681 559.21

24 992 1 .000 294.455 1 2.679 559. 1

1

24 993 1 .000 247.621 1 2.742 561 .87 24 994 1 .000 247. 734 1 2.742 561 .87 24 995 1 .000 248.490 1 2 .742 561 .87 24 995 1 .000 248.673 1 2. 741 561 .86

24 997 1 .000 249.31

0

1 2 . 74

1

561 .86

24 998 1 .000 250.333 1 2.741 561 . 85 24 999 1 . 000 251 .088 1 2. 741 561 . 84 24 1 000 1 .000 252 .974 1 2. /40 561 .oZ 24 1 001 1 .000 255 . 995 1 2. 740 561 . 79 24 1 002 1 .000 258. 548 1 2 . 739 561 .77 24 1 003 1 .000 263 .440 1 2 . 738 561 .72 24 1 004 1 .000 268. 1 97 1 2 . 737 561 .68

24 1 005 1 .000 273.360 1 2.736 561 .63 24 1 006 1 .000 278.376 1 2. 735 561 .58

24 1007 1 .000 283.231 1 2. 734 551 .53 24 1 008 1 .000 288.691 1 2.733 561 .48

24 1 009 1 .000 293.107 1 2. 732 561 .44 24 1 01

0

1 .000 297.847 1 2.731 561 .40 24 101 1 1 .000 247.820 1 2.773 563.26

24 1 012 1 .000 248.646 1 2.773 563.26

24 1013 1 .000 250.345 12.773 563.24

24 1014 1 .000 252.1 31 1 2.772 563.22

24 101 5 1 .000 254.247 1 2.772 563.20

24 1 016 1 . 000 256.785 1 2.771 563.18

24 101 7 1 .000 259.61

9

12.771 563.15

24 101 8 1 .000 262.510 1 2.770 563.12

24 1 01 9 1 .000 265.495 12.769 563.09

24 1 020 1 .000 268.1 71 1 2. 769 563.07

24 1021 1 .000 271 .181 1 2.768 563.04

24 1 022 1 .000 276.240 1 2.767 562.99

24 1023 1 .000 281 .440 1 2.766 562.94

24 1 024 1 .000 286.945 1 2 . 765 562.89

24 1025 1 .000 286.968 1 2.765 562.89

24 1 026 1 .000 291 .062 12.764 562.85

24 1 027 1 .000 296.653 1 2.763 562 .80 24 1 028 1 .000 235.542 1 3.073 576.47

24 1 029 1 .000 236. 1 63 1 3.072 576.46

24 1030 1 .000 237.1 16 1 3.072 576.45

24 1 031 1 .000 237.986 13.072 576.44

24 1 032 1 .000 239.626 13.072 576.43

24 1033 1 .000 242.193 13.071 576.40

24 1034 1 .000 245.592 13.070 576.37

24 1035 1 .000 249.203 13.070 576.33

24 1036 1 .000 252.921 13.069 576.29

24 1037 1 .000 256.51

8

13.068 576.25

24 1038 1 .000 260.718 13.067 576.21

24 1039 1 .000 264.442 13.066 576.17

24 1040 1 .000 267.990 13.065 576.13

24 1041 1 .000 232.965 13.169 580.70

24 1042 1 .000 234.603 13.168 580.69

24 1043 1 .000 234.672 13.168 580.69

on, (2)Dawson, (3)BeattIe, (4)Deschner, (5)Reamer,

ar, (XXXX)Haynes, ( 51 ,52 )Thomas, ( 78 )Te Ichmann

,

Density Density '^exot ^calc Pressure

caic Diff. ^ Diff.

Wq/w? % MPa MPa %

559. 19 .04 1 1 .7830 1 1 .9417 -1 .33

559.22 .03 15.7660 15.8760 -.69

559.23 .01 22.61 20 22.6495 -.17

559.21 -.00 28.4990 28.4958 .01 559.13 -.00 37.3690 37.3553 .04

561 .45 .08 .2571 .5525 -53.47

561 .45 .08 .3546 .6493 -45.39

561 .46 .07 1 .0065 1 .2965 -22 .37

561 .46 .07 1 . 1 642 1 .4460 -1 9.49

c it 1 yi *7 .0 /1 "7 1 Z A

1 . / I 30 1 .yyoy 1 Z Ait -1 3.96

561 .48 .07 2.5934 2 .8580 -9.26

561 .49 .06 3.2424 3.4955 -7 .24

561 .51 .06 4.O6I I

C A 0 AZ 5.0693 A AQ 561 . 53 .05 1 .4466 /.63/4 0 C A -2 . 50

561 .55 .04 y .6241 9.7889 1 IT Q -1 .60

561 . 58 .02 1 3. 781

0

1 3. 8879 -.11

561 . 59 .0^ 1 / . / 930 1 / . ooZ^) -.39

561 .60 .01 22. 1 250 22. 1 530 -.13

561 . 59 - .00 26 .3070 26 .301

4

.02

561 .57 -.01 30.3300 30. 2986 . 1 0

561 .53 -.01 34.8260 34.7805 . 1 3

561 .49 -.01 38.4390 38.391

7

.1 2 561 .44 -.01 42. 2950 42.2569 .09 563.03 .04 1 .5453 1 .7064 -9.44

563.04 .04 2.261

4

2.41 96 -6.54

563.05 .03 3.7322 3.8702 -3.57

563.06 .03 5 .2754 5.3930 -2.18

563 .07 .02 7.0999 7.1 962 -1 .34

563.08 .02 9.2327 9.3570 -.79

563.09 .01 1 1 . 7 1 30 1 1 .7576 -.38

563.10 .00 14.1 840 1 4 .2002 -. 1 1 563.10 -.00 16.7280 16.71 60 .07 563.1

1

-.01 1 9.0010 1 8.971

1

.16 563.1

1

-.01 21 .5500 21 .4952 .25 563.10 -.02 25.8150 25.7229 .36 563.08 -.02 30. 1 730 30.0506 .41 563.05 -.03 34.7600 34.61 46 .42 563.05 -.03 34.7790 34.6338 .42 563.02 -.03 38.1 720 38.01 22 .42 562 .97 -.03 42.7790 42.61 27 .39 576.24 .04 .4570 .6449 -29. 1 3 576.25 .04 1 .0563 1 .2257 -13.82

576.27 .03 1 .9745 2.1205 -6.89

576.29 .03 2.81 12 2.9358 -4.24

576.32 .02 4.3844 4.4775 -2.08

576.36 .01 6.8363 6.8728 -.53

576.39 -.00 10.0630 10.0417 .21 576.42 -.02 13.4660 13.3880 .58 576.43 -.02 16.9440 16.8206 .73 576.42 -.03 20.2830 20.1276 .77 575.39 -.03 24.1490 23.9797 .71 576.35 -.03 27.5490 27.3777 .63 576.29 -.03 30.7630 30.6017 .53 580.12 .10 1 .1792 1 .6707 -29.42

580.14 .09 2.7885 3.2595 -14.45

580.14 .09 2.8562 3.3267 -14.14

90
Table 7. (ConMnued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)BeattIe, (4)Deschner, (5)Rearner,

(13)Cherney, ( 1 7 )Tom I I nson , (24)Ely, (26)Dittmar, (XXXX )Haynes, ( 51 , 52 )Thomas, (78)Teichmann,

(79) Warowny

.

D Data Weight Temp

.

Dens I ty Dens I ty Dens 1 ty pexpt ca 1 c Pressur

Point expt ca Ic DIff. DIff.

No. K mol/L kg/rr' kg/fn-^ i MPa MPa %

24 1044 1 .000 236.343 13.168 580.67 580.16 .09 4.4938 4.9357 -8.95

24 1045 1 .000 238.154 13.167 530.65 580.18 .08 6.2641 5.6770 -6.18

24 1046 1 .000 239.793 13.167 580.63 580.19 .08 7.8622 8.2479 -4.68

24 1047 1 .000 242.380 1 3.166 580.60 580.22 .07 10.3770 10.7225 -3.22

24 1048 1 .000 245.001 13.166 580.58 580.23 .05 12.9150 1 3.2315 -2.39

24 1049 1 .000 249.556 13.165 580.53 580.26 .05 17.3020 17.5603 -1 .47 24 1050 1 .000 254.065 1 3 . 1 64 580.48 580.26 .04 21 .6150 21 .8236 -.96

24 1051 1 .000 258.913 13.163 580.43 580.26 .03 26.221

0

26.3885 -.63

24 1052 1 .000 263.566 13.151 580.38 580.25 .02 30.6100 30.7468 -.44

24 1053 1 .000 268.61

8

13.160 580.33 580.21 .02 35.3390 35.4606 -.34

24 1 054 1 .000 273.058 13.159 580.28 580.18 .02 39.4660 39.5783 -.28

24 1055 1 .000 226.866 13.315 587.16 587.03 .02 1 .1 092 1 .2271 -9.60

24 1056 1 .000 228.670 13.315 587.14 587.05 .01 2.9726 3.0503 -2.55

24 1 057 1 .000 230.980 13.314 587.12 587.09 .01 5.351

4

5.3837 -.50

24 1058 1 .000 234.058 1 3.313 587.08 587.12 -.01 8.5084 8.4694 .45 24 1059 1 .000 237.362 13.313 587.06 587.1

5

-.02 11.8810 1 1 .7900 .77 24 1060 1 .000 242.108 1 3.31

1

587.00 587.19 -.03 16.6960 16.5067 1.15

24 1 061 1 .000 247.394 13.310 586.94 587.22 -.05 22.01 90 21 .7355 1 .30 24 1062 1 .000 250.1 51 1 3.309 586.91 587.23 -.05 24.7790 24.4515 1 .34 24 1 063 1 .000 254.663 13.308 586.86 587.23 -.06 29.2690 28.8779 1 .35 24 1064 1 .000 258.294 13.307 586.82 587.22 -.07 32.8600 32.4248 1 .34 24 1065 1 .000 261 .963 13.306 586.76 587.21 -.08 36.4690 35.9737 1 .38 24 1066 1 .000 265.574 13.306 586.74 587.19 -.08 40.0010 39.4955 1 .28 24 1067 1 .000 21 8.855 13.516 596.03 595.70 .06 .7779 1 . 101 4 -29.37

24 1068 1 .000 219.585 13.516 596.02 595.71 .05 1 .5821 1 .8853 -16.08

24 1069 1 .000 221 .230 13.516 596.00 595.74 .04 3.3908 3.551

0

-7.13

24 1070 1 .000 223.680 13.515 595.98 595.77 .03 6.0763 6.2828 -3.29

24 1071 1 .000 226.125 13.514 595.95 595.81 .02 8.7463 8.8900 -1 .62 24 1072 1 .000 227.750 13.514 595.93 595.83 .02 10.5150 10.6179 -.97

24 1073 1 .000 228.861 13.514 595.92 595.84 .01 1 1 .7220 1 1 .8008 -.67

24 1074 1 .000 229.601 13.514 595.91 595.85 .01 12.5250 12.5842 -.47

24 1075 1 .000 231 .940 13.51

3

595.88 595.88 .00 15.0560 15.0571 -.01 24 1076 1.000 234.664 13.512 595.85 595.91 -.01 17.9930 17.9328 .34 24 1077 1 .000 238.083 13.51 1 595.81 595.93 -.02 21 .6610 21 .5256 .63 24 1078 1 .000 242.385 13.510 595.76 595.96 -.03 26.2480 26.0254 .86 24 1079 1 .000 246.702 13.509 595.71 595.97 -.04 30.8200 30.5180 .99 24 1080 1 .000 251 .325 13.508 595.66 595.98 -.05 35.5820 35.3086 1 .06 24 1081 1 .000 256.596 13.507 595.60 595.97 -.06 41 .1820 40.7376 1 .09 24 1082 1 .000 21 1 .641 13.696 603.95 603.33 .10 .4075 1 .0574 -51 .47 24 1083 1 .000 212.694 13.696 603.94 603.35 .10 1 .5320 2.2571 -27.70

24 1084 1 .000 214.101 13.695 603.92 603.37 .09 3.2652 3.8500 -1 5.19

24 1085 1 .000 21 7.902 13.694 603.87 603.43 .07 7.6602 8. 1 396 -5.89

24 1086 1 .000 222.089 13.693 603.82 603.49 .05 1 2.4730 12.8420 -2.87

24 1087 1 .000 225.450 13.692 603.78 603.53 .04 16.3140 16.5964 -1 .70 24 1088 1 .000 230.231 13.691 603.72 603.61 .02 21 .7740 21 .9035 -.59

24 1089 1 .000 235.520 13.689 603.66 603.63 .01 27.7060 27.7432 -.13

24 1090 1 .000 241 .297 13.688 603.59 603.66 -.01 34.1 620 34.0721 .25

24 1091 1 .000 244.776 13.687 603.55 503.57 -.02 38.0220 37.8649 .41 24 1092 1 .000 247.542 13.586 603.51 603.58 -.03 41 .0760 40.8589 .53 24 1093 1 .000 205.755 13.857 61 1 .05 61 0.99 .01 1 .7549 1 .8348 -3.81 24 1094 1 .000 207.297 13.856 61 1 .03 51 1 .02 .00 3.6605 3.5728 -.33

24 1095 1 .000 209.435 13.856 61 1 .01 61 1 .06 -.01 6.2801 6.2222 .93 24 1096 1 .000 212.526 13.855 610.97 61 1 .11 -.02 10.0490 9.8797 1 .71 24 1097 1 .000 216.578 13.854 610.91 51 1 .18 -.04 14.9560 14.6384 2.17

24 1098 1 .000 220.157 13.853 610.87 61 1 .22 -.06 19.2590 18.8327 2.26

24 1099 1 .000 225.334 13.851 610.80 61 1 .27 -.08 25.4320 24.8468 2.36

91
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)8eattie; (4)Deschner, (5)Rea(ner,

(13)Cherney, (1 7)Toml inson, (24)Ely, (26 )D i ttmar, (XXXX)Haynes, (51 ,52 )Thomas, ( 78 )Te ichrnann

,

(79)V/arowny

.

ID

24

24

24

2424

24

24

24

2424

24

2424

2424

24

24

24

242424

24

24

2424

24

2424

24

2424

2424

24

24

2424

24

24

2424

2424

24

24

2424

2424

2424

24

2424

Data

Po I nt No.

11 00

1 101

1 102

I 103

1 104

1 105 1106

1 107

1 108

1109

1110

1111 1112 1113

1114

1115

1116

1117

1118

1119

1 120

1121

1 122

1 123

1124

1 125

1 126

1 127

I I 23 1129

1130

1 131 1132

1133

1134

1 135

1 136

1 137

1 138

1139

1140

1141 1142

1143

1144

1145

1 146

1147

1 148 1149

11 50

1 151

1 152 1153

Wei ght

1.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 ,000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

Temp.

K

227.547

230.819

235.224

237.320

199.157

200.472

202.81

7

206.391

210.980

216.347

21 6.464

221 .205

225.885

231 .094

192.61

5

193.111

195.904

197.140

199.390

202.609

205.926

209.500

213.137

215.014

21 7.285

220.119

1 84.715

185.973

187.723

189.954

194.865

198.151

204.051

208.548

213.736

177.351

179.819

181 .543

183.330

187.888

190.854

194.795

198.915

201 .433

204.618

166.227

167.461

168.747

1 71 .053

174.434

178.373

182.557

187.796

189.817

Dens i ty

expt

mol/L kg/nr

13.851

13.850

13.848

13.848

13.991

13.990

13.990

13.989

13.987

13.986

13.985

13.984

13.983

13.981 14.155

14.155

14.154

14.154

14.153

14.152

14.151

14.150

14.149

14.148

1 4.147

14.146

14.340

14.339

14.339

14.338

14.336

14.335

14.333

14.332

14.330

14.524

14.523

14.523

14.522

14.521

14.520

14.51

8

14.517

14.516

14.515

14.776

14.776

14.776

14.775

14.773

14.772

14.770

14.768

14.768

610.78

610.73

610.68

610.65

616.96

616.94

616.91

61 6.86

616.80

616.73

616.72

616.66

616.60

616.53

624.19

624.19

624.15

624.13

624.10

624.05

624.01

623.96

623.91

623.88

623.85

623.81

632.34

632.32

632.30

632.26

632.19

632.14

632.05

631 .99

631 .91 640.48

640.44

640.41

640.39

640.32

640.27

640.21

640.15

640.11

640.06

651 .60

651 .58

651 .56

651 ,52

651 .46

651 .39

651 .32

651 .24

651 .21

Dens i ty

calc

kg/m^

61 1 .28

61 1 .29

61 1 .30

61 1 .30

61 7.01

61 7.04

61 7.08

61 7.16

61 7.23

61 7.29

61 7.26

61 7.10

61 7.32

61 7.32

624.28

624.29

624.36

624.39

624.44

624.50

624.55

624.60

624.64

624.65

624.67

624.68

632,36

632.40

631 .97 632.49

632.60

632.66

632.75

632.79

632,82

640.55

640.62

640.67

640.71

640.81

640.87

640.94

640.99

641 .01 641 .03

651 .57

651 .61 651 .65 651 .73

651 .82

651 .92 652.00

652.08

652.10

Dens i ty

Diff

.

expt

MPa

cal c MPa

Pressure

Diff.

-.08 28.0520 27.4169 2.32

-.09 31 .9060 31 . 1 770 2.34

-.10 37.0550 36.2358 2.26

-.11 39.4890 38.6247 2.24

-.01 .5378 .4838 11.16

-,02 2.2353 2.1 1 78 5.55

-.03 5.2383 5.0287 4,1 7 -.05 9,7993 9.4371 3.84

-.07 1 5.6020 1 5 .0640 3.57

-.09 22.3260 21 .5934 3.39

-.09 22.4300 21 .7241 3.25

-.07 28.031

0

27.4494 2.12

-.12 34.0430 33.0622 2.97

-.13 40.3660 39.2628 2.81 -.01 .9162 .8001 1 4.52

-.02 1 .5904 1 .4585 9.05

-.03 5.3735 5,1041 5.28

-.04 7.0407 6.7082 4.96

-.05 1 0.0650 9.6273 4.55

-.07 1 4.3660 1 3.7738 4.30

-.09 1 8.7680 1 8.0378 4.05

-. 1

0

23.4770 22.5969 3.89

-. 1

2

28.2320 27.2110 3.75

-, 1 2 30-6720 29. 5762 3. 71 -.13 33.6100 32.4378 3.61

-. 1

4

37 .2570 35.991

7

3,52

- .00 .61 63 .5835 5 .63

-.01 2. 4300 2.3255 4.49

.05 4.2992 4.7519 -9.53

ft 1 'M^ 7 fli "^0 4 1 IS 1 1 1 n 4 .01 - 09. \ y • 1 ^ j\j 1ft QR41

- 1 1 ^- 1 * ^ J j\j 26 .91 83 3 .85

"^4 1 470 ^ 71 -.14 41 . 2 1 40 39 .7878 3.58

-.01 1 ,3550 1 .2502 8.38

5.1 580 4.8634 5.44

-.04 7.7509 7.3727 5.13

-.05 1 0.4590 9.9802 4 .80 -.08 17.3130 16.5602 4.55

-.09 21 .7350 20.8033 4.48

-.11 27.5610 26.4145 4.34

-.13 33.5930 32.2424 4.19

-.14 37.2500 35.7785 4.11 -.15 41 .8440 40.2308 4.01

.01 .7033 .7554 -6.91 -.00 2.7642 2.7174 1.72

-.01 4.9045 4.7569 3. 10 -.03 8.7235 8.3916 3.95

-.06 14.2790 13.6830 4.36

-.08 20.6850 19.7969 4.49

-.10 27.41 10 26.2425 4.45

-.13 35.7200 34.2506 4.29

-.14 38.8920 37.3200 4.21

92
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)8eattie, {4)Deschner, (5)Reainer,

(13)Cherney, ( 1 7 )Tom I i nson , (24)Ely, ( 26)D i ttmar , (XXXX)Haynes. (51 ,52 )Thomas, ( 78 )Te Ichmann

,

(79)Warowny.

ID Data Point

We i ght Temp. Dens i ty

expt Dens ity ca I c Dens i ty

Diff

.

expt ca I c Pressure

Diff.

No. K mol /L k Q/m 1 11 a MPa l^lr a f>

J 1 1 54 1 .000 31 0.928 .040 1 •15 1 .76 . 1 U 1 J .

1

1 01u 1 nu . 9Qzy

J 1 1 S'S 1 .000 31 0.928 .054 2,40 2 .40 . j^ . 1 J / y .

1 "^7'i 1 J / J ^9 . JZ

c;J 1 1 ^ifi "SI n Q9R . U ft4 • JD .zuoo 9nftR 90(=;i . Z UD I . 99

c

J

1 1 R7 1

1 . nnn uuu _??11 0u . Q9R y z o .III 1 1 1 A PQ A4 • Q1y

!

— . jyTO . 97RR Z / 90 . 97A R Z / 40 . T79 / cJ

1 1

1 1 ^ o 1 nnn ?i

1 nu . qoR ^zo »

1

1 AO4U ft 1 R ftD • ZU9n . 4U .944 / T/ T/ . 94J4 .JOTR

c

J 1 1 1

1 • nnn uuu _) t U . "Z o .

1

1 70/ u 7 AO 7/ • R99Z - . An4U .419/ 41 T7 . A14 91 1 Z 1 17 .9 /

c;J

1 1 AO 1

) . nnn uuu

71J 1 fiu . Q9q yzo . Z9T9J5Z in 9"^ 1 n 9ft 1 U» ZD —~ • JT7/ .9910 R R 1 R/Q7 T/ • j4

11^1 1 1 D 1 1

1 nnn . uuu 71 n Q7Q J 1 u . yzts . 9Q7 zy /

1 19 1 j> • 1 z IT 1 R 1 9 • 1 9 ~.zo .Doyj .00 lO 9R «Z9

1 1 1

1 .uuu nnn J 1 u . yzo . JOD TRA 17 A1 1 / • U

1

~ •U9 Q^^1 R • DDI 0

R/^ 1 R • OD 1 9 A/ .U4

1 1

1 1 OJ 1

1 . nnn uuu J)Z11 nu . Q9R yzo .40/ R11 91 99 91Z 91 1 -Z I .U4 1 AT/ 9 1 .Uj4Z 1 OT/

A

1 •Uj40 -. U4

c0 1 1 D4 1 nnn 1 . uuu X\ n Q7Q J 1 u . yzo in 7 1 n 1 u » / 1 u

A 79 9Q 4 / z ©zy A 71 9R 4 / 1 •Z9 99 • ZZ 1 T7Qn I.J/ yu 1 i^T / A 1 .DJ4U 1 R XI -1 9.0I

1M1 d5 1 .UUU ji u . yzo 1 A 7Q7 1 U . /oz! 4 /9 • 4o A 1A A"? 4 /4 • U9 T 1 .31 O A^: O /I z .uoo4 z. 4491 1 R >l 1 -1 9.41

J 1 1 DO 11 • nnn UUU J 1 u . yzo 1 n QTA 1 U

.

OjU A~I~I c; "7 4 /0«D9 1 O . 1 y

O 7R7n z . / 9 /y T AAQO J .Uuoz 0 T -O.JZ

c

J 110/ 1 nnn 1 . UUU J) 1 u • yzo 1 n QQR 1 U • 009 A Qr\ Cil 4oU • U

I

A "TO 1 A 4 /y • 14 1 R . 1 0T / / 7/1 J. 44 /4 J. oy4y -0X 7A . /U

D

1 1

1 1 DO 1

1 .UUU nnn J 1 u .y zo 1 n QT7 1 u .yj / 4oZ • J)U yl Q 1 R1 4o I • 9

1

1 / 1 Ttf;o 4 . 1 jDy / T -7T T 4 .9 /3j -9.41 R /II c 1 1 ^^Q

1 1 csy

1 nnn 1 .UUU Tin 07 Q J 1 u. yzo 1 1 OT9 1 1

.

UjZ 4oD

•

4d yl QR OR 4o9 .yp 1 A • 1 U

R R 1 R Q 9.91 90 R X Q A yl 9 .D0U4 7 AO -z .yU

1 1 /u 1 nnn 1 .UUU Tin Q7Q _5 1 u . yzo 11 191 1 1 . 1 Z 1 4yu • 4

1

y1 OA AR 4 yu 07 . u / ^ OA/ Q D.oy40 7 A7TT / . UZJJ -11 QT .09

I> 1171 1 1 /

1

1

1 . nnn uuu "71 n 09Q J 1 u. yzo 11 99/1 1 t . Zz 4 4y4 • yo A QlA 11 n/ • U4 Q \ Q/ 0 • O 1 04 R ^^RQ9 o.ooyz — R

1

— . 0 1 c 1 1 77 1

1 . nnn UUU Tin Q9 Q J 1 u . yzo 1 1 T9/^ 1 1

.

jZD 4y y • 44 4yy A OQ 1 T

•

1

D

o#^

• UD 1 O T / 7 1

1 U. j4Z

1

1 A / 71 A 1 U . 4 / 1 U -11 7T .ZJ

c 1 1 7T 1 nnn 1 .UUU Tin Q7 Q J 1 u .yzo 11 / on i 1 . 4UU 9UZ • by RAT 1 Q 9U9 • 1

D

1 o1 U1 7 A^^R Q 1 Z.U090 11 Q R7

/

1 1 .09Z4 1 OA 1 .oU

-)

1 1 1

A

1 1 /4 1

1 .UUU nnn Tin Q7Q J 1 u» yzo 11 / QT 1 1 . 4 yJ

^r\£^ 9Q \)K)o • /y RA^C no 9Uo •yo — »U4 IT 7 D OR 1 J . / o y9 IT 7 A/ 1 9 . /U4D .Dz

J

1 1 7'=i 1

1 . nnn uuu .3Tin1 u. Q9R yzo 1 1 RR7 9Uy •D4 R1 A RR 9 1 U • 99 • 1 0

1 c CI T9 19.91 jZ 1

1 R9 . OATQ U09y 9 QR z • yo

I? 1 1 7fi 1 1 /D 11 .uuu nnn ^

T 1

1 nu . Q9R yzo 1 1 (^4R 1 1 .040 ^1 ft"^ R9

1

1 9

T • QTy_5 — Oft . UD 1 7 9Tf^Q 1 / . z joy 1 7 ARTA 1

/

.UOjU . onyu

_> 1177 11// 11 . nnn uuu J?T11 nu . Q9R yz 0

1

1 1

1 . 7TA /94 9

SI1 7/ • >m49 R91

1 7/ •

^

1 A4 .UDn^ 1R QftOfi 1 0 . youo in 1 T1 R 1 y . 19 19 — . oy

1

) 11 7R/ o 11 . nnn uuu _Pt;i n Q'Jfl 1 u. ^zo 1II./ 1 7R^OJ 9 1 ^ • 9 7 R9A 9ZU 1 Q • 1 y _ •

1

t 9Z 90ZU .004J ^^R4T z90u . JTTQR jy

9

1

1 . 7n/u

J 1 1 7Q 11 . nnn uuu J

T1

1 Au • Q9q y z o 11 11 . Q49 y 4Z =19^ 9ZD ft9 • OZ R9R 9Z 9 • Q9yz 1 T . 1 J Z4. 9A 1 T1 1 J 1

D

9AZ4 . R7R4 9 / 94 -11 . R10 1 J 1 1 RD 1

1 . nnn uuu J)T11 Au. qOR ^zo 19t Z . nRn U 9U 99 1 #99 "^T 99 11 •

1

1 Q

y

• nTUJ 9z. 7t m\jR 7Qn 1 yu 97Z i=;R7T / .OO ID — TQ . 9 :?

I 1 R1 II o 1 1

1 . nnn uuu J

T1i nu. 09Q yzo 19 1 / R 1 Z . 149 R'^ 999R RQ • 90 R990Tft 1 A • 1

U

_~ 1 A . 1 u J

T11 n9A/ . UZ04 Tn ^^Ri / 9U.09 1

4

1 99 1 . ZZ

1

1 11 R9OZ 1

1 . nnn uuu _3T11 nU . Q9fl 7ZO 1

1 Z9 . Z9R7J / 94 U • 9U R / A iCQ 94U • oy — • nTUJ 9T44.4/A7TRJO D^* D^L t\j - • A^^ 4 J

RJ 1

1 . nnn uuu ->Tin1 u . Q9R yzo 11 Z9 . 47R 4 / ^ 99U • 1

U

RAQ 94y • OP'Jo 1 fl . 1 o A14 1 • JD09 TfiRR A94Z . 9RA'^ Z94

J

-9Z .

1

1 nu

c:

-J 1 1 RA 1

1 . nnn uuu j>T11 nu. Q9R yzo 1 9 f^TR 1 Z . D9 9 RR99 7/•ID1ft RRft 99D ft/1 • D4 . nouy AO 9ATT 40. Z099 AR40 . 7^^RT /D09 — 1

1 . nAU4

J 1 1 R^ 1

I . nnn uuu T1I Au . Q9R yz O 11 Z9 . 77R / / O Rft"^ RA 909 • 9U RftT 9D9 R"^ • 99 - . niU 1 RR 1RR1 99 . 1 90 1 RR99 .

1

1 Z99R1

I

. Ofi UD

J 11 1 Rft 1 11 . nnn uuu ^1 n Q9R 1 ^ . yuu •=iftQ 1 n SftQ 91 - 1 . 1

J

p.-) O Z . nR9H U JZO ftl D 1 .

1

1 RRO OOU 11 . 41^ 1 5 1 1 fl7 1

\ . nnn uuu ^10 09R 1 nsR 9 / 9 • 09 '=)7'S 7ft .U011 f^R DO . Q47fi yH / Q oy . uJ JO - 1 9

J 1 1 RR 11 • nnn uuu T97 t;Q4 n'^R 1 ftft I • DO 1 ftft

1 •OD _ . 97Z / .

1

1 niU 1 J 1 01 1 . 1 U 1 1 . 97z /

I? 1

1 11 RQoy 11 a nnn uuu T9 7 .jZ / .9y4 nRi .U9 1 9 9"7 z • z / 9 9Q Z • Zo _ -2 A . jU .

1 T70 1 J / y .19/9 1 T7R . jUTO

c

I? 1 1 on 1 1 yu 1

1 .uuu nnn T97 RQ/ JZ / . ?yH n7R .U /O 9 • 49 T A A Dm 44 .94 . 9nAR ZUDO . 9nX9 ZUDZ TT • 9J

->

1 1 Q1 1 1 y 1 1

1 .uuu nnn T97 RQ/ jz / . yy4 .

1 nR 1 U9 4 •D 1 4 • D9 _ -7^ JO 97R R . Z / 9 0 97/ R .Z /40 • TRJ9

e 1 1 Q7 1 1 yz 1 nnn 1 .UUU T97 RO/1 jZ / . Dy4 1 T9 . 1 JZ R QO 9 • OZ R OA 9 • o4 TQ -.JO T y1 / 7 .344 / T / TR « j4j9 TX » JD

D

1 1 Q"^

1 1 yj 1 nnn 1 . UUU T9 7 R O/ jZ / . !)y4 1 iCA. 1 dU "7 r\A ~7 AT TO -.JO A 1 T7 .419/ / 1 99 .4 1 ZZ • jD

c

-)

1 1 o>i

1 1 y4 1 nnn 1 .UUU T97 RQ<1 JZ / . 9y4 917 • Z 1 / Q R "7 y •9 / y • Di

7-7 — • J / R R 1 .9910 R / 07 . 94y / TR • J J

->

1 1 OR 1 1 yy 1 nnn i . UUU T97 RQ/ jz / . py4 977 .Z / /1 9 91 1 Z • Z 1 1 9 OR 1 Z • Z9 -. j4 .ooyj ^;r7t .00 ID Tl • J 1 5 1196 1 .000 327.594 .356 15.68 15.72 -.29 .8618 .8597 .25

5 1197 1 .000 327.594 .440 19.38 19.42 -.16 1 .0342 1 .0328 .14

5 1198 1 .000 327.594 .629 27.72 27.67 .20 1 .3790 1.3811 -.15

5 1199 1 .000 327.594 10.018 441 .76 440.57 .27 2.0684 2.2573 -8.37

5 1200 1 .000 327.594 10.1 15 446.03 444.77 .28 2.7579 2.9769 -7.36

5 1201 1 .000 327.594 10.198 449.71 448.61 .25 3.4474 3.6568 -5.73

5 1202 1 .000 32 7.594 10.275 453.12 452.14 .22 4 . 1 369 4.3365 -4.60

5 1203 1 .000 327.594 10.416 459.33 458.51 .18 5.51 58 5.7086 -3.38

5 1204 1 .000 327.594 10.538 464.69 464.14 .12 6.8948 7.0363 -2.01

5 1205 1 .000 327.594 10.675 470.73 470.42 .06 8.6184 8.7062 -1 .01

5 1206 1 .000 327.594 10.805 476.46 476.05 .09 10.3421 10.4741 -1 .26

5 1207 1 .000 327.594 10.905 480.88 481 .16 -.06 12.0658 1 1 .9649 .84

5 1208 1 .000 327.594 1 1 .015 485.72 485.86 -.03 13.7895 13.7346 .40

5 1209 1 .000 327.594 1 1 . 1 06 489.75 490.22 -.10 15.5132 15.3191 1 .27

93
Table 7. (Continued)

Data sources and ID numbers: (l)VIrial Equation, (2)Dawson, (3)3eattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7 )Tom I i nson , (24)Ely, (26 )D i ttinar, (XXXX)Haynes, (51 ,52)Thomas, (78)Teichmann,

( 79) Warowny

.

) Data We I a h t Temp

.

Dens i ty D^^n I 1 1 o ( 1 y np^ l-'O Hot n c i + \/ 1 y p . •^expt P 1

' ca! c

1^ r* c c 1 1 r~ o Point expt c a 1 c iff. D i f f • No • K moi /L kg/irr k g/ m"^ MPa MPa t

5 1 210 1 cOOO 327.594 11.212 494,41 494 .29 .02 1 7.2369 1 7.291

1

-.31

5 1 21

1

1 .000 327 .594 1 1 .300 498.30 498.1

1

.04 1 8.9606 19.0484 -.46

5 1 21

2

1 .000 327.594 1 1 .388 502.18 501 .71 .09 20.6843 20.91 63 -1.11

5 1 21 3 1 .000 327.594 1 1 .532 508.54 508.38 .03 24.1316 24. 2238 -.38

5 1214 1 .000 327.594 1 1 .662 514.25 51 4,44 -.04 27.5790 27.4680 .40

5 1 21 5 1 .000 327.594 1 1 .768 518.94 520,01 -.21 31 .0264 30.341

2

2,26

5 1 21 6 1 .000 327.594 1 1 .906 525.02 525,18 -.03 34.4738 34.3580 ,34

5 121 7 1 .000 327.594 12.150 535.77 534.54 .23 41 .3685 42.3382 -2,29

5 1 21 8 1 .000 327.594 12.315 543.04 542.87 .03 48.2633 48.41 70 -,32

5 1219 1 .000 327.594 12.475 550.12 550.39 -.05 55.1581 54.8964 .48

5 1 220 1 .000 327.594 12.623 556.64 557.27 -.11 62.0528 61 .3997 1 .06

5 1221 1 .000 327.594 1 2.805 564.67 563.61 .19 68.9476 70.1477 -1 .71 5 1222 1 .000 344.261 .036 1 .58 1 .58 -.25 .1013 .101

1

.25

5 1 223 1 .000 344.261 .049 2.15 2.16 -.27 .1379 .1375 .27

5 1224 1 .000 344.261 .074 3.25 3.26 -.31 .2068 .2062 .30

5 1 225 1 .000 344.261 .099 4.37 4.38 -.32 .2758 .2749 .32

5 1226 1 .000 344.261 .125 5.50 5.52 -.34 .3447 .3436 .33

5 1 227 1 .000 344.261 .151 6.65 6.68 -.33 ,41 37 ,41 24 ,32

5 1 228 1 .000 344.261 .204 9.01 9.04 -.33 ,5516 ,5499 .31

5 1 229 1 .000 344.261 .260 1 1 .45 1 1 .49 -.30 .6895 .6875 ,28

5 1 230 1 .000 344.261 . 332 1 4,63 1 4.67 -.24 .861 8 .8600 ,22

5 1 231 1 .000 344.261 .408 1 7.98 1 8.01 -.1

6

1 .0342 1 .0327 ,14

5 1 232 1 .000 344 .261 .573 25.25 25. 24 .06 1 ,3790 1 .3797 -,05

5 1 233 1 .000 344.261 .986 43.47 43.09 ,89 2,0684 2.0808 -,59

5 1 734 1 .000 344.261 9. 1 41 403.09 401 .57 ,38 2,7579 2. 8840 -4,37

R 1 93'5 1 .000 344 .9fi1 9.293 409. 78 409.21 , 1

4

3.4474 3.5050 -1 ,64

J 1 P'^fi ( ^_>o 1 non 344 9fi1 9. 433 41 5.98 41 ^ ^1 1 n 4 1 3ftQ 4 1 ftS4 -11 , 1ft 1 D

RJ 1 9'S7 1 nnn 344 . 9fi1 9.659 425 . 92 49S Oft "SI ^9. 5. "5081 1 4

RJ 1 1 nnn 344 9fi1 9. 847 434 .24 434 43 - n4 D , O ^HO ft ftftnQ . 4QH ^

RJ 1 'J'^Q 1 nnn 344 9ft

1

1 0.049 443. 1

5

443 9R - n3 ftO , ftl w 1 ft4 OH ft SQ1 Q , J \ RJ 1

1 94.n Z M-W 1 nnn 344 9ft1 1 0. 229 451 .08 4Rn P3 , nfi DD in 3491 11 nD , 4n33 HU_?_J - RQ

RJ 1

t 941 ZH 1 1 nnn 344 9ft1 1 0.374 457.48 4S7 47 nn 1 9 nfti^ft 1 Z , ^w/D^ O 1 9 n7nQ - . n4DH

RJ 1 949 1 nnn 344 9fi1 1

1 nU • 'i9n _^ZD 4ft3 HD^ . Q97Z 4ft3 4n 1 1 , 1 1 1 3 7flQR 131 J . Q4fl1 ^H O t -11 .

1

1 4H

RJ 1 94"^ 1 nnn 344 . 9ft1 ZD 1 1

1 n^ . ft43 DH^ 4ftQ HD ^ • -J33J 4AR HDO , RnOU 1 1 . 1 1 1I R> . R11 _JZ 39 1R1 J . ftQ9ft D^Z D -1 1

4

t . 1 H

R 1 944 1 nnn 344 9ft1 in 7S7 474 34 4 7^^ 7R 1 T

• 1 ^ 1 7 9'^ftQ 1 7 4R"^7 -1I . ZH94

R 1 94R 1

I . nnn \}\)\} J^HH 344 . ZO9ft11 in R71 470 3q A19. "^3

. Z99Z 1ft Qftnfi 1 O . ^QUD 1Q TTR/l -9Z .

1

1 4H

R

J 1 94(^ 1 nnn 344 9i=\l 1 n q43 4ft9 H OZ , S7/ 4R9 ^OZ ftl

, D i — ni 90 (^H4'^ 9nZU .D«ic\i / u

/

n7

RJ 1 947 1 nnn -JHM- 344 9ft1 . ZD 1 11 .141 491 .28 4Qn 4n 1 R 94ZH 1 31 ft . I 1 D 94ZH . R4ftft -/HDO -11 . ftQ D^

RJ 1 943 1 nnn 344 9fi1 1 1 .282 497.49 4Q7 3R . n9DZ 97Z / .

'i^ 7/ Qn^D 97Z / . ft3ftft D_-'UD . Z 1 RJ 1

1 94Q Z. H ^ 1 nnn ^'+'+ 344 a 9fi1 ZD t 1 1 .407 503.02 Sn3 79 - 1 4 31 n9ft4 30 . ft9ft1 DZ. D 1 1 31 RJ 1 9sn 1 nnn 344 9fi1 11 .551 509 ,37 RnQ "i"! - n3 34 473R _^34H . 3ft 74/ H . J 1 RJ 1 9^11 1 ^ V 1 1 nnn ^HH 344 . ZD9ft11 1 1 .81

8

521 . 1

3

SI Q 07 e Z99Z 41 3fiftS 49HZ . 1

1 QQn " J'D -1 .Q7

RJ 1 9S9 1 nnn 344H . 9fi1 Z. D t 12.009 529.56 S9Q 19 na 4ft HO. 9fi33 Z. D_-'_^ 4ft HO . ft19ft D 1 ^D - 79

5 1 253 1 .000 344 .261 12.182 537.18 537 ,32 -.n3 55 , 1 581 55 .0349 ,22

5 1254 1 .000 344.261 12.344 544.32 544.77 -.08 62,0528 61 .6206 ,70

5 1255 1 .000 344.261 12.518 551 .99 551 .59 .07 68.9476 69,3690 -.61

5 1256 1.000 360.928 .034 1 .50 1 .51 -.23 .1013 ,1011 .23

5 1257 1 .000 360.928 .047 2.05 2.06 -.26 .1379 ,1375 .26

5 1258 1 .000 360.928 .070 3.09 3.10 -.30 .2068 .2062 ,29

5 1259 1 .000 360.928 .094 4.15 4.17 -.30 .2758 .2750 .30

5 1260 1 .000 360.928 .118 5.22- 5.24 -.32 .3447 .3437 .31

5 1261 1 .000 360.928 .143 6.31 6,33 -.31 .41 37 .4124 .30

5 1262 1,000 360.928 .193 8.52 8,55 -.30 .5516 ,5500 .29

5 1263 1 .000 360.928 .245 10.80 10,83 -.29 .6895 ,6876 .27

5 1264 1 .000 360.928 .312 13.75 13,78 -.24 .8618 ,8600 .22

5 1265 1 .000 360.928 .381 16.82 16,84 -.16 1 .0342 1 ,0327 .15

94
Table 7. (Continued)

Data sources and ID numbers: (l)Virlal Equation, (2)Dawson, (3)BeattIe, {4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7 )Toml i nson , (24)Ely, (26 )D i ttrnar, (XXXX)Haynes, (51 ,52 )Thomas, ( 78 )Teichmann

,

( 79) Warowny

ID Data Point

No.

1266

1267

1268

1269

1270

1271 1272 1273

1274

1275

1276

1277

1278

1279

1280

1 281 1282

1283

1284

1285

1286

1287

1288

1289

1290

1291 1292

1293

1294

1295

1296

1297

1298

1299

1300

1301 1302

1303

1304

1305

1306

1307

1308

1309

1310

131

1312

1313

1314

1315

1316

1317

1318

1319

1320

1321

Weight

1 .000

1 .000

1.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000 1.000

1 .000

1 .000

1 .000

1.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1.000

1 .000

1 .000

1 .000

1 .000

1 .000

Temp.

K

360.928

360.928

360.928

360.926

360.928

360.928

360.928

360.928

360.928

360.928

360.928

360.928

360.928

360.928

360.928

360.928

360.928

360.928

360.928

360.928

360.928

360.928

350.928

360.928

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

377.594

Dens i ty

expt

mol/L kg/rrr

.530 .877

1 .342 2.103

8.1 71 8.731

9.063

9.363

9.602

9.792

9.971 10.114

10.262

10.398

10.492

10.71

10.886

1 1 .062

1 1 .1 91

1 1 .501

1 1 .696

1 1 .883

1 2.056

12.248

.033

.044

.067

.090 .113

.136

.184

.232

.295 .359

.495

.801

1 .1 73

1 .658

2.397

7.050

7.951 8.509

8.886

9.152

9.385

9.568

9.746

9.908

10.021

10.281

10.475

10.649

10.827

1 1 .144

1 1 .385

1 1 .595

23.36

38.69

59.16

92.74

360.32

385.03

399.64

412.90

423.42

431 .79

439.71

445.99

452.52

458.53

462.67

472.59

480.03

487.80

493.47

507.14

515.76

524.01

531 .66 540.09

1 .43

1 .96 2.95

3.96

4.97

6.00

8.09

10.23

12.99

15.83

21 .83

35.34

51 .74 73.13

105.72

310.88

350.61

375.23

391 .85 403.59

413.84

421 .93 429.78

436.92

441 .91 453.36

461 .90 469.58

477.46

491 .44 502.05

51 1 .32

Dens i ty

calc

kg/in-'

23.36

38.49

58.33

92.13

359.03

383.38

398.36

412.03

422.74

431 .64 439.32

445.10

452.20

457.74

462.84

471 .99 480.03

487.25

493.80

505.38

515.43

524.35

532.38

539.71

1 .44

1 .96 2.96

3.97

4.99

6.02

8.12

10.26

13.02

15.86

21 .83 35.21

51 .31 72.24

104.58

306.76

349.34

374.26

390.65

403.12

413.31

421 .97 429.55

436.30

442.41

453.15

462.43

470.62

477.97

490.82

501 .82

51 1 .49

Dens i ty

Dif f

.01 .53

1 .33 .67

.36

.43

.32

.21 .16

.03 .09 -.02

.07

.17 -.04

.13 -.00

.1

-.07

.35 .06 -.07

-.14

.07 -.21 -.25

-.30

-.29

-.29

-.29

-.27

-.26

-.21 -.16

-.02

.38

.82

1 .23 1.08

1 .34

.36

.26

.31 .12

.13

-.01

.05 .14 -.11

.05 -.11 -.22

-.11 .13

.05 -.03

expt

MPa

1 .3790

2.0684

2.7579

3.4474

4.1369

5.51 58

6.8948

8.6184

10,3421

12.0658

13.7895

15.5132

1 7.2369

18.9606

20.6843

24.1316

27.5790

31 .0264

34.4738

41 .3685

48.2633

55.1581

62.0528

68.9476

.1013

.1379

.2068

.2758

.3447

.4137

.5516

.6895

.8618

1 .0342

1 .3790

2.0684

2.7579

3.4474

4.1369

5.51 58 6.8948

8.61 84 10.3421

12.0658

13.7895

15.5132

17.2369

18.9606

20.6843

24.1316

27.5790

31 .0264

34.4738

41 .3685

48.2633

55.1581

cal c MPa

1 .3790

2.0768

2.7802

3.4552

4.1884

5.5444

7.0368

8.7463

10.4644

12.0953

13.8835

15.4835

17.3327

19.2171

20.6241

24.3768

27.5764

31 .3039

34.2948

42.51 30 48.5028

54.8780

61 .3999

69.3186

.1011 .1376

.2062

.2750

.3438

.4125

.5502

.6878

.8601

1 .0327

1 .3788

2.0747

2.7741

3.4720

4.1543

5.5936

5.9618

8.7052

10.4912

12.1383

13.8880

15.5044

1 7.2926

19.1280

20.5376

24.2044

27.3723

30.5683

34.2206

41 .7344

48.4178

55.0327

Pressure

Diff

-.01 -.40

-.80

-.23

-1 .23 -2.28

-2.02

-1 .46 -1.17

-.25

-.68

.19 -.55

-1 .33 .29

-1 .01

.01 -.39

.52

-2.59

-.49

.51

1 .06 -.54

.21 .24

.30

.28

.28

.28 .26 .24

.20

.15

.01 -.30

-.58

-.71 -.42

-1 .39

-.95

-1 .00

-1 .42 -.60

-.71 .06 -.32

-.88

.71 -.30

.76

1 .50

.74 -.88

-.32

.23

95
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Bedttie, (4)Deschner, (5)Reamer,

(13)Cherney, (1 7)Toml inson, (24)Ely, (26)Dittmar, (XXXX )Haynes, ( 51 , 52 ) Thomas, ( 78)Telchmann

,

(79)Warowny.

Data WeigPit Temp

.

Dens Ity Dens i ty Dens i ty '^expt '^ca 1 c Pressu

Point expt calc Diff

.

Diff.

No. K mol /L % MPa MPa %

5 1 322 1 .000 377.594 1 1 . 779 519.43 520 . 1

4

-.14 0 n CT 0 0 62.0528 61 .4565 .97

5 1 323 1 .000 377 . 594 1 1 .969 COT 01 52 / . oi 52 7 .98 -.03 68.9476 68.7931 .22

5 1 324 1 .000 41 0.928 A 7 A .030 1 TO

1 .3/ 1 TO1 • 32 -.20 .1013 .1011 .20

5 1 325 1 .000 riA "I .U4 1 1 "70

1 . /y 1 OA 1 .oU 00 -.Zz 1 T7n . 1 J /y 1 T7£C• 1 J /D 0

1

.Zl

5 1 326 1 .000 41 0» 9zo .061 0 7A 2. /O 0 71 Z . /I oc -.25 .2068 0 A^ T .2063 .25

5 1 327 1 . 000 41 J. yzo AQO T XO 3.0Z T XT J.OJ ot; -.ZD 0 7C Q

. Z /5o 07(^1 .Z /51 0^ .ZD

5 1 328 1 .000 41 0. 923 1 AT . 1 U-5 4 . 54 A C C 4.55 0^ -.26 X A At .344 / T >1 T 0 .3438 .25

c5

1 TOO 1 AAA 1 O A

. 1 Z4 AT 3.4 /

c; Ad 5 . 4y — .ZD A 1 T7 .4 1 J / A 1 O^^ .41 Zo o<^

. Zo

1 JJV 1 AAA 1 .UUU /tin noQ .ID/ "7 T^ /.JO 7 TP / . JO _ ocZj C C 1 A .J J 1 0

C CAT . J jUj 0/1

. Z4

1 X"^ 1 1 AAA 1 .UUU yi 1 n QOQ 0 1 A .Z 1 UQ OQ Qy TA . ju — 0/1 . Z4 .Doyj .00 /y OT .Z J

1 T TO 1 AAA 1 .UUU A \ r\ noQ . Zoo 1 1 7T 1 1 . /J 1 1 7C^

1 1 . /J — . ZU .00 1 0

Q/^ AO .ODUZ 1 Q . 1 y

1 TXX 1 J1 AAA 1 . UUU 4 1 'J • TOT 1 >1 0 T 1 4 . Z5 - 1 7 1 .Uj4Z I .UjZD 1 . I D

1 TT /I 1 AAA 1 .UUU A^r\ OOD 4 1 u • yzo y1 /A .44U 1 Q /I 0 1 y .4z 1 Q AX 1 y .4j —- A7 .u /1 T7QA 1 « J /yu 1 T7 Q

1

1 .J /HI A^^ .uo

5

1 T T C

1 335 1 AAA 1 .OUU A ^ r\ noo .Dy4 T A 1 TA 7 jU. 5 /

1 c . 1 J 0 A^Q/! z .Uoo4 0 A71 A Z .U /I U -. 1 T

1 J

5 1 336 1 AAA 1 .UUU /1 1 n ooQ 41 U •Vzo . y /o AX 10 4 J . 1 / 4z .yo T 7

. J / 0 7C 7Q z . /5 /y Z . /ooZ - T A . jU

1 TT 7 1 AAA 1 .UUU A 1 n OOQ 1 T A

1

1 . J)U 1 T^; 0 1 .JO R 7 A 1 J / . U 1 .DU T / /t 7/1 J .44 m T ^^^T1 J .40J

!

_ . c 4 J

5

1 1 T O

1 33o 1 AAA 1 .UUU 41 u» yzo 1 .0 /5

"7 T 07 /3.8/ 7T XA /J . j4 71 A 1 T/^Q 4 . 1 jDy A 1 C 71 4 . 1 J / 1 _-.4yAd

5 1 339 1 AAA 1 .UUU ^ 1 n noo 41 j« yzo O O A 2.DOO 110 1 A

1 1 0. 1

y

117 y1 0

1 1 / . 4Z • DO c c 1 CO 5.51 JO C CTC1 5 . J j51 -. TCj5

5 1 340 1 .000 /1 1 n noo 41 0» yzo y1 000 4 . 228 1 06.43 IOC A 7

1 85.0 /

-7T

. /3 0 A/1

0

D .oy4o ^ A1 A7 6 .91 y

/

T C -.35

5 1 341 1 .000 A ^ r\ noo 41 'J .yzo ^ A^ T 6 . 063 OCT 7 TO 26 / . 38 0 T £ K 263 .65 1 y1 1

1 .41 0 £C 1 0 y1 D.61 84 0 70 7A 8. /z /y 1 0 c -1 .25

5 1 342 1 .000 ^ 1 n no o

41 0. 928 7.060 31 1 .35 308. 51 .92 1 0.3421 1 A A A1 01 0.491 8 -1 .43

5 1 343 1 .000 yi 1 n noo 41 0.928 7.625 336.26 335.49 .23 1 2.0658 12.1 259 -.50

5 1 344 1 .000 41 0.928 8.072 355 .93 354.40 .43 1 3.7895 1 3.9524 -1.17

5 1 345 1 .000 it 1 n noo 41 0.928 8.381 369.60 368.97 .1 7 15.51 32 1 5 .5964 -.53

5 1 346 1 .000 /I 1 n noo 410.928 8.657 381 .77 330.86 .24 1 7 .2369 1 7.3822 -.84

5 1 347 1 .000 J* 1 n noo 41 0. 928 3.889 391 .96 390 .93 .25 18.9606 1 9. 1 524 -1 .00

5 1 348 1 .000 ji 1 n noo 41 0. 928 9.064 399.68 399.69 -.00 20.6843 on ^00^ 20 .5826 .01

5 1 349 1 .000 ii 1 A noo

41 0.928 9. 397 41 4.37 414.45 -.02 24. 1 31

6

24. 1 1 09 .09

5 1 350 1 .000 41 0.928 9.675 426.62 426.66 -.01 27.5790 27.5575 .04

5 1 351 1 .000 41 0.928 9.892 436.19 437. 1

2

-. 21 31 .0264 30. 7001 1 .06

5 1 352 1 .000 41 0.928 10.114 445.98 446.30 -.07 34.4738 34.3495 .36

5 1 353 1 .000 >i 1 no o41 0.928 1 0.488 462. 49 461 .91 .1 3 41 .3685 41 .651

7

-.68

5 1 354 1 .000 41 0.928 1 0.778 475.26 474.96 .06 48. 2633 48. 4397 -.36

5 1 355 1 .000 410.928 1 1 .032 486.48 486. 21 .05 55. 1 581 55.3331 -. 32

5 1 356 1 .000 41 0.928 1 1 .249 496.06 496. 1

4

-.02 62.0528 61 .9966 .09

5 1 357 1 .000 1 n no o41 0.928 11 .470 505.81 505.05 .1 5 68.9475 69.5758 -.90

5 1 358 1 .000 444.261 .028 1 .22 1 .22 -.1 8 .1013 .1011 . 1

8

5 1 359 1 .000 444 .261 .038 1 .66 1 .66 -.20 .1 379 . 1 376 .20

5 1 360 1 .000 444.261 A C "7 0 >1 A 2 .49 2.50 -.24 .2068 .2064 .23

5 1 35 1 1 . 000 444 . 261 .U /D T T T J. JJ 3.34 '-.25 .2758 .2751 .24

1

1 3d/ 1 AAA 1 .UUU AAA OiCI 444 . ZD 1 .095 4.18 A 1 A 4.19 0 c -.25 .3447 T A TA .3439 0 c .25

5

1 T.C^'X

1 J>D-5 1 AAA 1 .UUU AAA O^; 1 444

.

Zo\ .114 R AT 5 .U J

K AC 5.05 0£: -.ZD A \ T 7 A 1 0£ .41 ZD oc .Z5

5 1 J04 1 AAA 1 . UUU AAA O^

1

444. /iol .153 6.76 6.77 -.25 .5516 .5503 .24

1 'Xe^^

1 S>OD 1 AAA 1 . UUU AAA 1 444

.

Zo

\

.193 8.50 Q CO 0. jZ 0 >1 -.Z4 .Doy5 .00 /y OT .Zj

5 1366 1 .000 444.261 .243 10.71 10.73 -.21 .8518 .8501 .20

5 1367 1 .000 444.261 .294 12.96 12.99 -.18 1 .0342 1 .0325 .17

5 1368 1 .000 444.261 .399 17.58 17.60 -.09 1 .3790 1 .3778 .08

5 1369 1 .000 444.261 .620 27.32 27.30 .10 2.0584 2.0702 -.09

5 1370 1 .000 444.261 .857 37.81 37.70 .29 2.7579 2.7649 -.25

5 1371 1 .000 444.261 1.115 49.16 48.93 .48 3.4474 3.461 1 -.40

5 1372 1 .000 444.261 1 .395 61 .51- 61 .13 .61 4 . 1 359 4.1571 -.49

5 1373 1 .000 4U.26] 2.040 89.95 89.27 .76 5.51 58 5.5460 -.54

5 1374 1 .000 444.261 2.816 124.20 123.71 .39 6.8948 6.9124 -.25

5 1375 1 .000 444.261 3.956 174.44 174.26 .10 8.5184 8.6244 -.07

5 1376 1 .000 444.261 5.069 223.54 222.19 .61 10.3421 10.3962 -.52

5 1377 1 .000 444.261 5.91 5 260.84 260.34 .19 12.0658 12.0919 -.22

96
Table 7. (Continued)

Data sources and ID numbers: (l)VIrial Equation, (2)Dawson, (3)Beattie, (4)Descliner, (5)Reainer,

(13)Cherney, (1 7)Toml inson, (24)Ely, (26 )D I ttinar , (XXXX)Haynes, C?! ,52 )Thotnas, (78)Teichmann,

(79)Warowny

.

) Data We i ght Temp

.

DensI ty Dens i ty Dens i ty '^expt ""calc Pressure

Point expt ca 1 c D i f f

.

DIf f

.

No. K mol/L 1 / T kg/m-^ kg/m^ % MPa r-lPa %

5 1378 1 .000 444.261 6.603 291 .20 289.35 .64 1 3.7895 1 3.9169 -.92

5 1379 1 .000 444.261 7.106 313.35 31 1 .52 .59 15.5132 15.6761 -1 .04

5 1380 1 .000 444.261 7.471 329.44 329.04 .12 1 7.2369 1 7.2809 -.25

5 1381 1 .000 444.261 7.803 344.09 343.37 .21 18.9606 19.0553 -.50

5 1382 1 .000 444.261 8.061 355.48 355.47 .00 20.6843 20.6365 -.01

5 1 383 1 .000 444.261 8.51 4 375.44 375.12 .08 24.1315 24. 1949 -.26

5 1384 1 .000 444.261 8.856 390.54 390.77 -.06 27.5790 27.5233 .20

5 1385 1 .000 444.261 9.1 41 403.1

1

403.81 -.17 31 ,0264 30.8279 .64

5 1386 1 .000 444.261 9.407 414.81 41 5.00 -.05 34.4738 34.4100 .19

5 1387 1 .000 444.261 9.854 434.53 433.61 .21 41 .3685 41 .7488 -.91

5 1388 1 .000 444.261 10.195 449.55 448.81 .17 48.2633 48.6333 -.76

5 1389 1 .000 444.261 10.431 462.20 461 .70 .11 55.1581 55.4449 -.52

5 1 390 1 .000 444.261 1 0.724 472.90 472.94 -.01 62.0528 62.0301 .04

5 1391 1 .000 444.261 10.975 483.96 482.92 .22 68.9476 69.7098 -1 .09

5 1392 1 .000 477.594 .026 1.13 1.13 -.17 .1013 .1 012 .17

5 1393 1 .000 477.594 .035 1 .54 1 .54 -.19 .1379 .1376 .19

5 1 394 1 .000 477.594 .052 2.31 2.32 -.22 .2068 .2064 .22

5 1 395 1 .000 477.594 .070 3.09 3.10 -.24 .2758 .2751 .24

5 1396 1 .000 477.594 .088 3.88 3.89 -.25 .3447 .3439 .25

5 1 397 1 .000 477.594 .106 4.66 4.67 -.25 .4137 .41 27 .25

5 1 398 1 .000 477.594 .1 42 6.25 6.26 -.25 .5516 .5502 .25

5 1 399 1 .000 477.594 .1 78 7.85 7.87 -.25 .6395 .6878 .24

5 1 400 1 .000 477.594 .224 9.87 9.90 -.22 .861 8 .3600 .22

5 1 401 1 .000 477 .594 .270 1 1 .92 1 1 .95 -. 21 1 .0342 1 .0321 .21

5 1 402 1 .000 477.594 .365 16.10 16.13 -.1 5 1 .3790 1 .3770 . 1

4

5 1 403 1 .000 477 .594 .562 24.80 24. 79 .03 2 .0684 2.0690 -.03

5 1 404 1 .000 477.594 . 770 33.96 33 .89 . 21 2.7579 2 .7631 -. 1

9

5 1 405 1 .000 477 .594 .990 43.64 43.47 .40 3.4474 3 .4595 -.35

5 1 406 1 .000 477 .594 1 .221 53 .83 53.56 .49 4.1 369 4, 1 544 -.42

5 1 407 1 .000 477.594 1 .724 76.01 75 .55 .62 5.51 58 5.5433 -.50

5 1 408 1 .000 477.594 2.284 1 00 .74 1 00.22 .51 6.8948 6.9220 -.39

5 1 409 1 .000 477 . 594 3.058 1 34.83 1 34 .68 . 1

1

8.61 84 8.6258 -. 08

5 1 41

0

1 .000 477.594 3.864 1 70.39 1 70. 81 -.24 1 0.3421 1 0.3220 .20

5 1 41 1 1 .000 477.594 4.636 204.43 204.66 -. 1

1

1 2.0658 1 2.0535 .10

5 1 41

2

1 .000 477.594 5.31 8 234.49 234.00 .21 1 3.7895 1 3.821

1

-.23

5 1 41 3 1 .000 477.594 5.881 259.32 258.88 .1 7 15.51 32 15.5464 -.21

5 1 414 1 .000 477.594 6.381 281 .39 279.81 .57 1 7.2369 1 7.3807 -.83

5 1 41 5 1 .000 477.594 6.774 298.73 297.44 .43 1 8.9606 19.0983 -.72

5 1 41

6

1 .000 477.594 7.090 31 2.67 312.46 .07 20.6843 20.7106 -.1 3

5 141 7 1 .000 477.594 7.652 337.45 336.75 .21 24.1316 24.2444 -.46

5 1 41

8

1 .000 477.594 8.076 356.14 355.83 .09 27.5790 27.6426 -.23

5 1 41 9 1 .000 477.594 8.416 371 .14 371 .46 -.09 31 .0264 30.9486 .25

5 1 420 1 .000 477.594 8.728 384.89 384.70 .05 34.4738 34.5272 -.15

5 1 421 1 .000 477.594 9.247 407.79 406.32 .36 41 .3635 41 .901

0

-1 .27

5 1422 1 .000 477.594 9.635 424.87 423.66 .29 48.2633 48.7981 -1 .10

5 1423 1 .000 477.594 9.961 439.25 438. 18 .25 55.1581 55.71 55 -1 .00

5 1424 1 .000 477.594 10.234 451 .31 450.69 .14 62.0528 62.4160 -.58

5 1425 1 .000 477.594 10.505 463.25 461 .72 .33 68.9476 69.972 7 -1 .47

5 1426 1 .000 510.928 .024 1 .05 1 .06 -.16 .1013 .1012 .16

5 1427 1 .000 510.928 .033 1 .44 1 .44 -.19 .1379 .1376 .19

5 1428 1 .000 510.928 .049 2.16 2.16 -.21 .2068 .2064 .21

5 1429 1 .000 510.928 .065 2.88 2.89 -.24 .2758 .2751 .23

5 1430 1 .000 510.928 .082 3.61 3.62 -.25 .3447 .3439 .25

5 1431 1 .000 51 0.928 .099 4.34 4.36 -.26 .4137 .4126 .26

5 1432 1 .000 510.928 .132 5.81 5.83 -.27 .5516 .5501 .27

5 1433 1 .000 510.928 .165 7.30 7.32 -.27 .6895 .6876 .27

97
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reainer,

(13)Cherney, ( 1 7 )Tom 1 i nson, (24)Ely, (26)Dittmar, (XXXX)Haynes, ( 51 , 52 )Thomas, ( 78 )Te ichmann

,

( 79) Warowny

.

1 UaTa we 191)1 Temp

.

Dens i ty De n s 1 1 y Density ^expt cal c Pressui

rO 1 ni expt ca 1 c U 1 T T . D i f f . No • t\ mo i /l_ kg/

m

kg/in To Mi-'a Mra ifP

1 yl

1 4 j4 f •UUU CIA QOQ • OHQ ZUO Q 1 y . i D y . 1 y -.zo ox 1 Q .001 0 • o!?y / 0 c .25

c; 1 1 c>

1 4_>V 1 r\C\r\

1 • UUU D 1 u . yzo 1 1

1 11 . nsU9 1 1 riR _ Of:. ZD 1 .U94Z 1 •\jD i 0 .Z9

c

1 4_)D 1 sUUU ^1 n QOQ 3 1 u . y^o . J)_> /

1

1 A RQ 4 . 00 ^ A Q1 1 4 • y 1 _— 00 • zz 1 ^7 OA 1.9/ yu 1 X 1

1 • J fO\ 0 1

c;D 1 4J> /

1 r\c\r\

1 « UUU • SIJ I A0 99Z Z . 7ft / Q 99zz . 7R/o 9 riftR4 z . UDtS4 0 nt^fxK z • UboD .uy

c

J

1 A'^ii.

1 *+_?0 11 • nnn UUU S 1 A QOQ ICY? 9U^n . Qsy9 9u"^n . QAy 4 C'A . 04 9 7S 7Q 0 7RPQ — .U4

J 1 1"^Q1 y 1

1 • non vJU J 1 ^ •y^O .oy V j>y .40 Jy .

1 Q _> . 4 4 / 4 - . 171 /

c: 1 /I /I n 1 9 UUU CIA 090 1

1 . nos uy9 4R40 . zy9Q An40 1 S . 1 9 . 9U A 1 ^ftQ 4 • 1 9oy A 1 /I Qn _— 97 .Z /

1 All 1

1 aUUU CI A QOQ 1 SI Q ftft DO Qft . yO ftft DO ft7 . D / .4A 7/ S9.91SI SR9o !->->0-? —— .4/II

1 c;J

1

1 A&O 11 • nnn UUU K 1 A QOQ y I u . y z 0 1 Q7'^1 . y Rft 00 . QQyy Rft 00. SQ9y /1ft

. 40 ft QQ/D D . 0 y4 0 0 • b^Z 1 Z — . 90

1=; 1 14'^ 1 1

1 • nnn UUU SIJ 1 0w . Q7R0 9Z . S9 7R/ 0 1 1 ft7 1 1 9 .0 / 1 19.90 . 9SZ ^ R0.01ftl R404 — . 91Z 1 c

J

1

1 444 11 • nnn UUU CIA Q90 1 u . yzo 9 .Z9o 9SQ 1 49 .Dy 1414 1

1 . Al4

/

11.9/S 7 1 n "^/i 91 1 U . 94/ 1 1 U • 4 / /J) —— 1

1 • 9Qzy

p; 1 AAii 1 44 J 1 nnn t u . 0 "S RS9 1 ftQ R7 1 ftQ "^S . 9 1 1

1 Z9 . nftSR U09 0 11 Z9 • nofl^i Ui'OO - . Z97/

1 440 11 ©UUU nnn sin Q9R 4.413 1 94.61 11 QSy 9 . AA44 • 49 119./7RQS oy9 1 J) • / J>ZU .4ZAO

R-/ 1 J.d. 7 1t • nnn UUU 4.951 218.31 9 1 R Q

1

Z I 0 0 ^ 1 - . z97/ 1 S S 1 ^9 . 9U

5 1448 1 .000 510.928 5.431 239.43 239.72 -.10 1 7.2369 1 7.2163 .12

5 1449 1 .000 510.928 5.865 258.62 258.12 .19 13.9606 19.0108 -.26

5 1450 1 .000 510.928 6.223 274.41 274.36 .02 20.6843 20.6903 -.03

5 1451 1 .000 510.928 6.845 301 .86 301 .48 .13 24.1316 24.1857 -.22

5 1452 1 .000 510.928 7.331 323.28 323.17 .04 27.5790 27.6000 -.08

5 1453 1 .000 510.928 7.725 340.65 340.99 -.10 31 .0264 30.9551 .23

5 1454 1 .000 510.928 8.076 356.13 356.03 .03 34.4738 34.4973 -.07

5 1455 1 .000 510.928 8.650 381 .45 380.42 .27 41 .3685 41 .7036 -.80

5 1456 1 .000 510.928 9.095 401 .06 399.76 .33 48.2633 48.7816 -1 .06

5 1457 1 .000 510.928 9.462 41 7.27 41 5.80 .35 55.1581 55.8480 -1 .24

5 1458 1 .000 510.928 9.771 430.87 429.53 .31 62.0528 62.7765 -1.15

5 1459 1 .000 510.928 10.054 443.36 441 .55 .41 63.9476 70.061

4

-1 .59

98
Table 7. (Continued)

Data sources and ID numbers: (I)Vlrial Equation, (2)Dawson, (3)BeattIe, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7 )Tom I I nson , (24)Ely, (26)0 ittrnar, (XXXX)Haynes, ( 51 , 52 )Thomas, (78 )TeIchmann

,

(79)Warowny

.

ID

51

51

5151

5151

5151

51

51

5151

51

51

5151

5151

5151

5151

5151

5151

51

51

5151

5151

5151

5151

5151

51

515151

51

51

51

51

51

51

5151

51

51

51

51

5151

Data Point

No.

1460

1461 1462

1463

1464

1465

1466

1467

1468

1469

1470

1471 1472

1473

1474

1475

1476

1477

1478

1479

1480

1481 1482

1483

1484

1485

1486

1487

1488

1489

1490

1491 1492

1493

1494

1495

1496

1497

1498

1499

1500

1501 1502

1503

1504

1505

1 506

1507

1508

1509

1510

1 51

1

1512

1513

1514

1515

Wei ght

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

Temp

.

K

258.150

258.150

258.150

258.150

263.150

263.150

263.150

263.150

268.150

268.150

268.150

268.150

268.150

268.150

273.150

273.150

273.150

273.150

273.150

273.150

273.150

273.150

273.150

273.150

273.150

273.150

273.150

273.150

278.1 50 278.150

278.150

278.150

278.150

278.150

278.1 50 283.150

283.150

283.150

283.150

283.150

288.150

288.150

288.150

288.150

288.150

288.150

288.150

293.150

293.1 50 293.150

293.1 50 293.150

298.1 50 298.150

298.150

298.150

Dens i ty

expt

mol/L kg/m^

12.435

12.440

1 2.446

12.451

12.289

12.294

12.299

12.310

12.139

12.144

12.150

12.156

I 2 . 1 62 12.173

I I .989

12.000

12.012

12.01

7

12.017

12.023

12.028

12.034

12.039

12.049

12.050

12.097

12.1 96 12.299

1 1 .831

1 1 .838

1 1 .843

1 1 .849

1 1 .855

1 1 .860

11 .865

1 1 .675

1 1 .681

1 1 .687

1 1 .692

1 1 .698

1 1 .51

1

1 1 .51

7

1 1 .517

11 .523

1 1 .529

1 1 .529

1 1 .534

1 1 .343

1 1 .348

11 .354

1 1 .360

1 1 .366

1 1 .169

1 1 . 1 70

11 . 1 75

1 1 . 1 76

548.33

548.57

548.82

549.06

541 .91 542.13

542.35

542.82

535.30

535.52

535.78

536.05

536.31

536.78

528.69

529.18

529.70

529.91

529.93

530.16

530.42

530.65

530.87

531 .32

531 .37 533.45

537.81

542.35

521 .73 522.02

522.26

522.52

522.76

523.01

523.22

514.82

515.08

51 5.35

515.59

-51 5.86

507.59

507.86

507.87

508.13

508.38

508.38

508.63

500.20

500.42

500.68

500.95

501 .19

492.54

492.55

492.81

492.83

Density

calc

kg/m^

549.02

549.23

549.39

549.66

542.52

542.77

543.00

543.47

535.75

536.00

536.21 536.41

536.64

537.13

528.79

529.27

529.72

530.01

529.99

530.26

530.49

530.77

531 .00

531 .55

531 .50 533.83

538.32

542.94

521 .77 522.01

522.25

522.50

522.76

523.02

523.29

51 4.75

514.99

51 5.24

515.48

515.75

507.46

507.72

507.70

507.96

508.22

508.23

508.48

500.04

500.35

500.62

500.92

501 .19

492.27

492.20

492.52

492.45

Dens i ty

Diff

.

-.13

-.12

-.10

-.11

-.11 -.12

-.12

-.12

-.08

-.09

-.08

-.07

-.06

-.07

-.02

-.02

-.00

-.02

-.01 -.02

-.01 -.02

-.02

-.04

-.02

-.07

-.09

-.11 -.01

.00 ,00

.00

.00 -.00

-.01

.01 .02

.02 .02

.02 .03

.03 .03

.03

.03 .03

.03

.03

.01

.01 .01 .00 .06

.07 .06

.08

'"^expt MPa

.7657

.8954

.9944

1 .1605

.7452

.8841

1 .0164

1 .2898

.6689

.8035

.9160

1 .0203

1 .1464

1 .4105

.6027

.8360

1 .0585

1 .201

5

1 .1917

1 .3303

1 .4442

1 .5876

1 .7040

1 .9843

1 .9581 3.1820

5.6784

8.4537

.6083

.7163

.8239

.9378

1 .0579

1 .1764

1 .3027

.7093

.8100

.9146

1 .0168

1 .1283

.7919

.8901 .8835

.9827

1 .0851

1 .0873

1 .1866

.9185

1 .0261

1 .1206

1 .2290

1 .3234

1 .0177

.9958

1 .0975

1 .0742

^cal c MPa

.3440

.4888

.6426

.7888

.3962

.5206

.6456

.91 27 .4297

.5495

.6337

.8290

.9681

1 .2206

.5528

.7925

1 .0475

1 .1554

1 .1649

1 .2797

1 .4080

1 .5240

1 .6374

1 .8690

1 .8920

2.9791

5.3852

8.0844

.5897

.7210

.8306

.9494

1 .0602

1 .171

7

1 .2722

.7402

.8483

.9596

1 .0639

1 .1764

.8432

.9464

.9486

1 .0480

1 .1457

1 .1479

1 .2439

.9747

1 .0504

1 .1446

1 .2394

1 .3246

1 .1047

1 . 1 082

1 .1892

1 .1980

Pressure

Diff.

122.57

83.19

54.75

47.1

1

88.10

69.82

57.42

41 .32 55.66

46.24

33.99

23.08

18.41 15.55

9.03

5.49

1 .05 4.00

2.30

3.95

2.57

4.17

4.07

6.17

3.49

6.81 5.44

4.57

3.16

-.66

-.81

-1 .22 -.22

.40 2.40

-4.18

-4.52

-4.69

-4.42

-4.09

-6.08

-5.95

-6.87

-6.23

-5.29

-5.28

-4.61 -5.77

-2.32

-2.10

-.84

-.09

-7.88

-10.15

-7.71

-1 0.33

99
Table 7. (Continued)

Data sources and ID numbers: (l)Viriat Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Rea(ner,

(13)Cherney, ( 1 7)Tomi inson, (24)Ely, (26 )0 i ttrnar , (XXXX )Haynes, (51 ,52 )Thomas, ( 78 ) fe ichmann

,

(79)Warowny.

ID

51

51

51

51

51

51

5151

5151

5151

5151

5151

51

51

5151

5151

51

51

5152

52

5252

52

52

5252

52

52

52

5151

51

515151

5151

5151

5151

51

51

5151

51

5151

51

Data Point

No.

1516

1517

1513

1519

1 520

1521 1522

1523

1524

1525

1 526

1527

1528

1529

1530

1531 1532

1533

1534

1535

1 536

1537

1538

1539

1540

1541 1542

1543

1 544

1545

1546

1547

I 548

1549

1550

1551 1552

1553

1554

1555

1556

1557

1558

1559

1560

1561 1562

1563

1564

1565

1566

1567

1568

1569

1570

1571

We i ght

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 ,000

1 .000

1.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

Temp.

K

298.150

298.150

298.150

298.1 50 298.150

298.150

298.150

298.150

298.1 50 298.150

298.150

298.150

298.150

303.150

303.150

303.150

303.150

303.150

303.150

303 . 1 50 303 . 1 50 303.150

303.1 50 303.150

303.150

303.150

303.150

303.150

303.1 50 303.150

303.150

303.150

303.1 50 303.150

303.150

303.150

313.150

313.150

313.150

313.150

313.150

313.150

313.150

323. 150 323.150

323.150

323.1 50 323.150

323.150

323.150

323,150

323.150

323.1 50 323.150

323.150

323.150

Dens i ty

expt

mol/L kg/iir

11 .177

1 1 .181

I 1 . 1 82

1 1 . 1 88

I I . 1 94

1 1 . 1 94

1 1 .249

11 ,302

1 1 .423

1 1 . 500

11 .523

1 1 .592

11.679

10.984

10.989

10.995

1 1 .001

1 1 .007

1 1 .008

1 1 .020

11.110

1 1 .252

1 1 .353

1 1 .441

1 1 .527

10.983

10.939

10.996

1 1 .007

1 1 .01

5

1 1 .137

1 1 . 1 80

1 1 .260

1 1 .302

1 1 .362

1 1 .537

10.596

10.602

10.609

10.61 5 10.621

10.628

10.634

.800

.820

.840

.850

.860

.870

.875 .876

10.1 79 10.179

10.179

10.185

10.185

492-.85 493.05

493.08

493.35

493.64

493.64

496.03

498.39

503.71

507.12

508.14

51 1 .19

515.00

434.35

484.59

484.35

485.1

1

485.38

485.42

485.96

489.91

496 . 1

7

500.65

504.50

508.31

484.33

484.60

484.87

485.40

485.73

491 .10

492.99

496.52

498.38

501 .05 508.77

467,27

467.54

467,81

468.08

468.38

468.69

468.91

35.28

36.16

37.04

37.48

37.92

38.36

38.59

38.61 448.85

448.85

448.86

449.1

1

449.13

Dens i ty

calc

kg/ nr

492.44

492.85

492.79

493 . 1

0

493.30

493.32

495.77

498.14

503.50

507.01

508.00

51 1 .15

51 5.00

484.11

484.40

434,68

484,97

485.24

485.12

485.66

489.82

496.03

500.58

504.51

508.41

484.24

434.55

484.34

485.36

485.65

491 .07 492.94

496.54

498.45

501 .03 508.96

467.38

467.65

467.92

468.17

468.45

463.60

468.94

35.39

36.30

37.19

37.64

38.08

38.53

38.75

38.76

448.65

443,73

443,60

449,01

448.87

Dens i ty

Diff. expt

MPa

ca I c MPa

Pressure

Diff.

.08 1 .0729 1 .2050 -1 0.97

.04 1 .2035 1 ,2670 -5 .01 .06 1 . 1 851 1 .2777 -7.24

.05 1 .282 3 1 .3632 -5.93

.07 1 .3494 1 .4601 -7.58

.07 1 .3546 1 .4601 -7.23

.05 2. 1679 2.2565 -3.92

.05 2.9922 3.0789 -2,81

.04 4.9970 5.0808 -1 ,65

.02 6.41 83 6. 4669 -.75

.03 6. 8399 6 .8973 -.83

.01 8.2207 8.2388 -.22

-.00 1 A A 1 A T 10.010/ 1 0.0092 • 01 .OD 1 1 A 1 1 1.1011 1 ^ C ~7A

1 .16/0 -5 ^65

r\A .U4 1 1 O 1 1 "i'X. It

1 »15 15 -4^38

.U4 1 T1 OT -3. /y

1 .J>40D 1 . JO / 1 o oo -z • yz

• Uj 1 AO AQ 1 . 4Z4cS 1 .4DDD o Qc: -Z •oD

»Ub 1 Al "7c: c o o -5 •o / .UD 1 . 54oo 1 .DJO

/

-5.3/

O QC:^Q

Z . ODDO _- 1 1 A 1 . 1 u

.U-> 4. y JD4 — 1 AA -I .uu

• Ul D •d4DD A A"^ O .D /4j -.41 — , nnuu O • Z4UO O . Z JOO «UJ

Qy .ooyu QQQn • 4!3

1 • 1 J /D 1 1 iCO y11 .

1

oZ4 O 1 T -Z . 1 J

Al .01 1 O O CO 1 O / A y1 1 .Z404 1 o o -1 .ZZ

A 1 1 "Z AO 1

1 .3Uol 1 "Z 1 O A 1 . 3 1 by oo -•OZ

Al

• Ul 1 . 4d1 4

1 yl 71 "Z

1 , 4 / 1 J -•D / AO .02 1 .13450 1 CiC O "7 1 Al^ -1 .45

A 1 • 01 3.231

4

3 ,2407 -.29

.01 3.8543 3,8736 -. 50 -.00 5 . 1 231 5. 1 157 . 1

5

-.01 5.8301 5,8027 .47

.00 6.8244 6.8309 -.10

-.04 1 0. 1 807 1 0.0949 • 85

-.02 1 .4533 1 .4281 1 ^77 -.02 1 .51 49 1 .4892 1 ^72 -.02 1 .5776 1 .5520 1 ^65 -.02 1 .6349 1 .61 52 1 .22 -.02 1 .7015 1 .6835 1 .07

.02 1 .7347 1 .7559 -1 .20

-.01 1 .3153 1 .8099 .32 -.33 1 .61 27 1 .6091 .22 -.37 1 .6402 1 .6361 .25 -.40 1 .6668 1 .6625 .26 -.41 1 .6799 1 .6754 .27 -.42 1 .6928 1 .6882 .27 -.43 1 .7056 1 .7009 .28 -•42 1 .71 13 1 .7071 .27 -.40 1 .7122 1 .7078 .26

.04 1 .7664 1 .8014 -1 ^94

.03 1 .7307 1 .8014 -1.15

.06 1 .7575 1 .3038 -2.57

.02 1 .8238 1 .8473 -1 .00 .06 1 .3046 1 .851

3

-2.52

100
Table 7. (Continued)

Data sources and ID numbers: (l)Virlal Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, (1 7)Toml Inson, (24)Ely, (26)Dittmar, (XXXX )Haynes, ( 51 , 52 )Thomas, (78)TeIchmann,

(79)Warowny.

ID

5151

515151

51

5151

51

51

51

51

5152

52

5252

52

5252

5252

52

52

5252

52

52

52

51

5151

5151

5151

5151

51

5151

51

5151

5151

5151

5151

51

5151

51

51

51

Data Point

No.

1572

1573

1 574

1575

1576

1577

1578

1579

1 580

1581 1582

1583

1584

1585

1585

1587

1588

1589

1590

1591 1592

1593

1594

1595

1596

1597

1598

1599

1600

1601 1602

1603

1604

1605

1606

1607

1608

1609

1610

161

1

1612

1613

1614

1615

1616

1617

1618

1619

1620

1621 1622

1623

1624

1625

1626

1627

Weight Temp.

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

0.000

1 .000

K

323.150

323.150

323.150

323.150

323.150

323.150

323.150

323.150

323.1 50 323. 150 323.150

323.150

323.150

323.150

323.150

323.150

323.150

323.150

323.150

323.150

323.1 50 323.150

323.150

323.150

323.150

323.150

323.150

323.150

323.150

333.150

333.1 50 333.150

333.150

333.150

333.150

333.150

333.150

333.150

333.150

333.150

333.1 50 333.150

333.150

333.150

333.150

333.150

333.150

343.150

343.150

343.150

343.1 50 343.150

343.150

343.150

343.1 50 343.150

Den si ty

expt

mol/L kg/nr

10.186

10.191

10.191

10.197

10.197

10.203

10.203

10.209

10.209

10.210

10.250

10.500

10.750

.800

.800

.820

.840

.850

.860

.870

10.182

1 0 . 1 88 10.194

10.200

10.206

10.498

1 1.034

11 .504

1 1 .998

.800 .900

1 .000

1 .050

1 .060

1 .075

1 .100

1 .120

1 .122

9.699

9.704

9.710

9.716

9.722

9.728

9.734

9.740

9.746

.800

1 .000

1 .200

1 .300

1 .350

1 .400

1 .425

1 .448

9.149

449.1

7

449.39

449.40

449.65

449.66

449.91

449.93

450.17

450.21

450.22

452.00

463.02

474.04

35.28

35.28

36.16

37.04

37.48

37.92

38.36

448.99

449.26

449.53

449.79

450.07

462.92

486.58

507.29

529.09

35.28

39.69

44.10

46.30

46.74

47.40

48.51 49.39

49.48

427.69

427.92

428.19

428.44

428.71

428.97

429.23

429.50

429.76

35.28

44.10

52.92

57.33

59.53

61 .74 62.84

63.85

403.44

Dens i ty

calc

kg/m

448.82

449.16

449.15

449.48

449.45

449.78

449.70

450.06

449.94

449.89

451 .73 462.85

473.96

35.40

35.40

36.29

37.19

37.63

38.08

38.53

448.55

448.87

449.18

449.46

449.74

462.82

485.57

507.86

530.13

35.34

39.77

44.22

46.48

46.91 47.58

48.70

49.59

49.66

427.51

427.76

428.04

428.30

428.53

428.82

429.08

429.33

429.59

35.31 44.13

52.98

57.43

59.66

61 .91 63.04

403.1

1

403.35

Dens i ty

Diff

.

"expt cal c Pressure

Diff.

MPa MPa tn

.08 1 .7970 1 .8586 -3.32

.05 1 .8570 1 .8976 -2.14

.06 1 .8544 1 .8992 -2.36

.04 1 .91 33 1 .9434 -1 .55

.05 1 .9083 1 . 9458 -1 .93 .03 1 .9660 1 .9895 -1.18

.05 1 .9525 1 .9944 -2.11

.03 2.01 71 2.0376 -1 .00

.06 1 .9952 2 .0434 -2.36

.07 1 .9867 2.0459 -2.89

.06 2. 3253 2 .3746 -2 .08

.04 4.6856 4.7256 -.85

.02 7.6467 7 .6697 -.30

-.35 1 .61 29 1 .6091 .24

1 fiOQI .73 -.37 1 .6402

1 fi69S -.40 1 .6799 .96

1 fiRR9 97 -.43 1 ,7056 1 .7009 .98

1

0

1 .7489 1 R9'iS -4 94

. ^

" 11 . RDS'i OvJ ^ J 1 R740 -"^ fill

. ORuo 1 Q991 -^ 9'i n? 1 Q1 nn 1 QftRQ -9 QQ

• 01\j 1

1 .QSR7 9 01 RS -9 Qft

• n?u^ AH . ft7RR D / OO

91 1 1 /IfiQI 1 1 R494

- 1 1 91 9RfiS 90i-\J * QRRR -70CJ0 11 .HZ49

- .20 35.0469 34.2992 2.18

-. 1

9

1 .7004 1 -fiQRI .1

. zz 11 . R44Q OH- Hi' 1 R499 . 1 4 -.28 1 .9755 1 .9720 .18 -.33 2.0358 2.031

7

.20 -.35 2.0475 2.0432 .21 -.36 2.0646 2.0602 .21 -.39 2.0925 2.0878 .22 -.41 2.1 1 42 2.1093 .23

-.37 2. 1 1 58 2.1114 .21 .04 2.1 278 2.1 508 -1 .07

.04 2.1 595 2.1 807 -.97

.03 2.1 955 2.21 46 -.86

.03 2.2288 2.2471 -.81

.04 2.2577 2.2810 -1 .02 .03 2.2961 2.31 51 -.82

.03 2.3301 2.3495 -.82

.04 2.3625 2.3841 -.91 .04 2.3966 2.4185 -.91 -.09 1 .7859 1 .7847 .07 -.07 2.0890 2.0881 .04 -.11 2.3408 2.3393 .06 -.18 2.4484 2.4461 .09

-.22 2.4977 2.4949 .11 -.28 2.5442 2.5407 .14 -.32 2.5663 2.5625 .15 84.16 2.5856 2.5818 .14

.02 2.6054 2.6132 -.30

101
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, (1 7)Toml Inson, (24)Ely, (26)Dittmar, (XXXX )Haynes, (51 ,52 )Thomas, (78)Teichmann,

(79)Warowny.

ID

5151

51

51

5151

51515252

52

52

52

52

5252

52

52

52

51

5151

51

5151

51

5151

51

51

51

51

5151

5151

5152

52

5252

52

5252

5151

5151

5151

5151

51

51

5151

Data

Point

No.

1623

1629

1630

1631 1632

1633

1634

1635

1636

1637

1638

1639

1640

1641 1642

1643

1644

1645

1646

1647

1648

1649

1650

1651 1652

1653

1654

1655

1656

1657

1658

1659

1660

1661 1662

1663

1664

1665

1666

1667

1663

1669

1670

1671 1672

1673

1674

1675

1676

1677

1678

1679

1680

1681 1682

1683

Weight

1 .000

1 .000

1.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

0.000

1 .000

1 .000

1 ,000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

Temp.

K

343.150

343.150

343.1 50 343.150

343.150

343.150

343.150

343.150

343.150

343.150

343.150

343.150

343.150

343.150

343.150

343.150

343.150

343.150

343.150

348.150

343.150

348.150

348.150

348.150

348.150

348.150

348.150

348.150

348.150

348.150

343.150

348.150

348.150

348.150

348.150

348.150

348.150

348.150

348.150

348.150

348.150

348.150

348.150

348.150

353.150

353.150

353.150

353.150

353.150

353.150

353.150

353.150

353.150

353.150

353.150

353.150

Density

expt

mol/L kg/nr

9.155

9.160

9.165

9.171

9.1 77 9.182

9.188

9.193

1 .300

1 .350

1 .400

1 .425

1 .448

9.147

9.152

9.158

9.164

9.169

9.1 75 .800

1 .000

1 .400

1 .500

1 .550

1 .600

1 .625

1 .650

8.829

8.834

8.840

8.844

8.850

8.855

8.860

8.865

9.000

9.500

.800

9.001

9.501 9.999

10.499

1 1 .000

1 1 .500

.800

1 .000

1 .500

1 .700

1 .800

1 .850

1 .900

8.462

8.467

8.472

8.477

8.481

403.69

403.94

404.17

404.42

404.67

404.92

405.15

405.40

57.33

59.53

61 .74 62.84

63.85

403.34

403.60

403,84

404.09

404.33

404.59

35.28

44.10

61 .74 66.15

68.35

70.56

71 .66

72.76

389.33

389.57

389.81

390.01

390.25

390.47

390.71

390.94

396.88

41 8.92

35.28

396.94

41 8.96

440.91

462.97

485.05

507.1

1

35.28

44.10

66.15

74.97

79.37

81 .58 83.78

373.14-

373.35

373.58

373.79

374.01

Densi ty

calc

kg/m^

403.58

403.82

404,06

404.32

404.56

404.81

405.03

405.26

57.42

59.66

61 .90 63.05

403.11

403.13

403.41

403.64

403.89

404.16

404.37

35.30

44.09

61 .76 66.21

68.45

70.71

71 .84 72.97

389.23

389,46

389.71

389.93

390.16

390.39

390.61

390.84

396.55

418.51

35.30

396.48

413.53

440.79

463.09

485.48

507.89

35.29

44.07

66.07

74.97

79.45

81 .72 83.99

373.14

373.35

373.57

373.80

374.00

Dens i ty

DIff.

.03 .03

.03

.02 .03

.03

.03 .04 -.17

-.21 -.26

-.33

-84.16

.05

.05

.05

.05 .04

.05 -.06

.01 -.03

-.10

-.15

-.21 -.25

-.28

.03

.03

.02

.02

.02 .02

.02 .03 .08

.10 -.06

.12 .10

.03 -.03

-.09

-.15

-.04

.06 .12 -.00

-.10

-.17

-.25

0.00

.00 .00 -.00

.00

expt

MPa

2.6247

2.6445

2.6651

2.6868

2.7077

2.7290

2.7479

2.7680

2.4483

2.4976

2.5440

2.5665

2.5856

2.5880

2,6108

2.6294

2.6504

2.6732

2.6914

1 .8282

2.1447

2.6310

2.7241

2.7666

2.8065

2.8255

2.8438

2.8604

2.8745

2.8907

2.9048

2.9200

2.9348

2.9496

2.9642

3.3770

5.6828

1 .8281 3.3717

5.6861 9.5096

15.3466

23.8349

35.6945

1 .8701 2.2000

2.8177

2.9904

3.0621

3.0945

3.1246

3.1365

3.1462

3.1561

3.1667

3.1760

cal c MPa

2.6341

2.6546

2.6746

2.6954

2.7170

2.7385

2.7589

2.7807

2.4461

2.4949

2.5407

2.5625

2.5818

2.6049

2.6261

2.6462

2.6677

2.6882

2.7100

1 .8273

2.1448

2.6305

2.7227

2.7647

2.8039

2.8225

2.8405

2.8668

2.8815

2.8969

2.9100

2.9257

2.9402

2.9557

2.9713

3.4025

5.7387

1 .8273

3.4076

5.7436

9.5358

15.3066

23.6406

35.2172

1 .8696

2.2009

2.3194

2.9903

3.0609

3.0926

3.1219

3.1365

3.1463

3.1564

3.1665

3.1763

Pressure

Dif f

.

-.36

-.38

-.36

-.32

-.34

-.35

-.40

-.46

.09

.11 .13

.16

.15 -.65

-.58

-.63

-.65

-.56

-.69

.05

-.01

.02 .05

.07

.09

.11 .12 -.23

-.24

-.21 -.18

-.20

-.18

-.21 -.24

-.75

-.98

.04

-1 .05

-1 .00

-.28

.26

.82

1 .36

.03 -.04

-.06

.00

.04 .06

.09

.00

-.01 -.01

.01 -.01

102
Table 7. (Continued)

Data sources and ID numbers: (l)VIrlai Equation, (2)Dawson, (3)8eattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7)Tom 11 nson, (24)Ely, (26 )0 i ttrnar , (XXXX)Haynes, (51 , 52 )Thomas, ( 78)re ichmann

,

(79)V/arowny

.

ID

51

51

5151

51

51

5151

5151

5151

5151

5151

51

51

51

51

5151

5151

5151

5151

5151

5151525252

52

52

52

52

5252

51

5151

51

5151

51

51

51

5151

5151

5151

Data Point

No.

1684

1685

1686

1687

1688

1689

1690

1691 1692

1693

1694

1695

1696

1697

1698

1699

1 700

1701

1 702 1703

1 704 1705

1706

1707

1708

1709

1 710

171

1

1 712 1713

1 714 1715

1 716 1717

1718

1719

1 720

1721 1722

1 723

1 724 1725

1 726

1727

1728

1729

1 730

1731

1 732

1733

1 734

1735

1 736

1737

1 738

1739

We i ght

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1.000

1 .000

1 .000

1 .000

1.000

1 .000

Temp.

K

353.150

353.150

353.150

358.150

353.150

358.150

358.150

358.150

358.1 50

358.150

358.1 50 358.150

358.150

358.150

358.150

358.150

358.150

358.150

363.1 50 363.150

363.150

363.150

363.1 50 363.150

363.1 50 363.150

363.1 50 363 . 1 50 363.150

363.150

363.150

363.150

363.150

363.150

363.150

363.150

363.1 50 363.150

363.1 50 363.1 50 363.150

365.150

365.150

365.150

365.150

365.150

365.150

365.150

365.150

365.150

365.150

365.150

365.150

365.150

365.150

365.150

mol/L

8.486

8.491 8.496

.800

1 .000

1 .500

1 .900

2.000

2.100

2.200

2.225

8.025

8.030

8.034

8.039

8.043

8.048

8.052

.800

1 .000

1 .500

2.000

2.500

2.550

2.600

2.630

2.650

7.467

7.476

7.483

7.500

7.507

2.000

2.500

2.550

2.600

2.630

2.650

7.462

7.466

7.470

.800

1 .000

1 .500

2.000

2.000

2.500

2.500

2.700

2.700

2.750

2.750

2.800

2.800

2.850

2.850

Dens i ty

expt

kg/m

374.23

374.44

374.66

35.28

44.10

66.15

83.78

88.19

92.60

97.01 98,12

353.88

354.08

354.28

354.48

354.68

354.88

355.08

35.28

44.10

66.15

88.19 no. 24

1 1 2.45

1 14.65

1 15.98

116.86

329.29

329.66

330.00

330.71

331 .05 88.19

1 10.24

112.45

114.65

1 15.98

1 16.86

329.05

329.25

329.42

35.28

44.10

66.15

88.19

88.19

110.24

1 10.24

119.06

1 19.06

121.27

121 .27

123.47

123.47

125.68

125.68

Density

ca Ic kg/m^

374.22

374.44

374.63

35.28

44.05

65.98

83.68

88.16

92.68

97.26

98-42

354.13

354.31

354.52

354.70

354.88

355.06

355.25

35.28

43.97

65.91 87.93

1 10.44

1 12.74

1 15.06

1 16.46

1 1 7.39

329.89

330.23

330.85

331 .19

331 .50 87.92

1 10.45

112.76

1 15.08

1 16.49

117.45

329.50

329.70

329.83

35.28

44.04

65.58

87.87

87.85

1 10.1 7

1 10.10

119.32

1 19.22

121 .63

1 21 .52 123.95

123.82

126.31

126.16

Dens I ty

Diff

.

.00

.00

.01 -.02

.10

.25

.13

.04 -.08

-.25

-.31 -.07

-.06

-.07

-.06

-.05

-.05

-.05

-.01

.29 .36

.30 -.18

-.26

-.35

-.41 -.45

-.18

-.17

-.26

-.14

-.13

.31 -.19

-.27

-.37

-.44

-.50

-.14

-.14

-.13

-.00

.14 .87 .37

.39

.07

.13

-.21 -.13

-.30

-.21 -.39

-.28

-.50

-.38

'"^expt MPa

3.1865

3.1964

3.2056

1 .91 1

7

2.2547

2.9101

3.2525

3.3162

3.3717

3.4196

3.4304

3.4408

3.4461

3.4521

3.4574

3.4627

3.4682

3.4738

1 .9532

2.3062

3.0010

3.4504

3.7063

3.7231

3.7385

3.7470

3.7524

3.7735

3.7787

3.7882

3.7935

3.7985

3.4504

3.7064

3.7232

3.7386

3.7472

3.7527

3.7676

3.7707

3.7726

1 .9697

2.3306

3.0289

3.5035

3.5032

3.7780

3.7774

3.8456

3.8450

3.8593

3.8587

3.8717

3.871

1

3.8831

3.8824

cal c MPa

3.1865

3.1967

3.2072

1 .91 15 2.2563

2.91 41 3.2541

3.3166

3.3708

3.41 72 3.4277

3.4336

3.4394

3.4452

3.4509

3.4569

3.4628

3.4688

1 .9531 2.31 1

1

3.0071

3.4545

3.7048

3.7210

3.7359

3.7441

3.7493

3.7645

3.7700

3.7751

3.7860

3.7914

3.4545

3.7048

3.7210

3.7359

3.7441

3.7493

3.761

1

3.7640

3.7664

1 .9697

2.3330

3.0439

3.5088

3.5088

3.7787

3.7787

3.8440

3.8440

3.8572

3.8572

3.8693

3.8693

3.8801

3.8801

Pressure

Diff.

-.00

-.01 -.05

.01 -.07

-.14

-.05

-.01

.03

.07

.08

.21 .19 .20

.19

.17 .16

.15

.00 -.21 -.20

-.12

.04

.05 .07 .08

.08 .24

.23

.35 .20

.19 -.12

.04 .06

.07

.08 .09

.17

.18 .16

.00 -.10

-.49

-.15

-.16

-.02

-.03

.04

.03

.05 .04 .06

.05 .08 .06

103
Table 7. (Continued)

Data sources and ID numbers: (1)Virial Equation, (2)Dawson, {3)8eattie, (4)Deschner, (5)Reaffler,

(13)Cherney, (1 7) TomI i nson, (24)Ely, (26 )0 i ttinar , ( XXXX )Haynes, (51 ,52)Thomas, ( 78 ) Te ichmann

,

( 79 )Warowny

.

ID

515151

51

51

51

5151

5151

5151

5151

51

51

5151

5151

5151

5151

5151

51

51

5151

5151

5151

5151

5151

51

51

5151

51

51

515151

51

5151

51

51

5151

51

51

Data Point

No.

1740

1 741

1 742 1743

1744

1745

1 746

1747

1 748

1749

1 750

1 751

1 752

1753

1 754 1755

1 755 1757

1 758 1759

1760

1761

1 762

1763

1 764

1765

1766

1767

1 763

1769

1 770

1771 1772 1773

1 774

1775

1 776

1777

1 778

1779

1 780

1781

1 782

1783

1784

1785

1786

1787

1788

1789

1 790

1791

1 792

1793

1794

1795

Weight Temp.

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

0.000

0.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1.000

i .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

0.000

0.000

1 .000

1 .000

1 .000

K

365.150

365 . 1 50 365.150

365.150

365.150

365.150

365.150

365.150

365.150

365 . 1 50 365.150

365.150

365.150

365 . 1 50 365.1 50 367.150

367.150

367.150

367.150

367.150

367.150

367.150

367.150

367.150

367.150

367.150

368.150

368.150

368.150

368.150

368.150

368.150

368.1 50 368.150

368.150

368.150

368.150

368.150

368.150

368.150

368.150

368.150

368.1 50 369.150

369.150

369.150

369.150

369.150

369.1 50 369.150

369.150

369.150

369.150

369.150

369.150

369.150

Dens i ty

expt

mol/L kg/m-'

2.900

2.900

7.163

7.167

7.1 70 7.170

7,184

7.184

7.192

7.192

7.200

7.200

7.207

7.207

7.214

2.500

3.000

3.100

3.200

3.250

3.270

3.290

6.769

6.772

6.775

6.798

.800

1 .000

1 .500

2.000

2.500

3.000

3.200

3.300

3.350

3.400

3.450

3.500

6.499

6.502

6.505

6.508

6.51

1

2.500

2.500

3.000

3.500

3.700

3.750

3.800

3.850

3.900

3.920

6.1 12 6.115

6.1 18

127.83

127.88

315.86

316.03

316.18

316.18

316.80

316.80

317.15

31 7.16

317.48

31 7.48

31 7.80

31 7.80

31 8.13

110,24

132.29

136,70

141 .11 143.32

144.20

145.08

298.47

298.62

298.76

299.78

35.28

44.10

66.15

88.19

1 10.24

132.29

141 .11 145,52

147.73

149.93

152.14

154.34

286.57

286.70

286.84

286.97

287.10

1 10.24

1 10.24

132.29

154.34

163.16

165.36

167.57

169.77

171 .98

1 72.86

269.54

269.66

269.78

Dens i ty

calc

kg/m-^

128.63

128.49

316.61

316.82

316.88

316.87

317.42

31 7.40

31 7.76

31 7.77 318.01

318.06

318.31

318.36

318.66

1 10.06

132,76

137.39

142.08

144,47

298.47

298,89

299,47

299.59

299.73

300.51

35,28

44.03

65.86

87.77

1 10.00

132.55

141 .71 146.35

148.68

151 .03

153.36

155.75

287.68

287.81

287.89

288.04

288.15

109.91

109.95

132.41 155.14

164.54

166.47

168.79

1 71 .11 268.91

269.38

270,58

270,61

270,75

Dens i ty Diff

.

-.58

-.47

-.24

-.25

-.22

-.22

-.20

-.19

-.19

-.19

-.17

-.18

-.16

-.17

-.17

.16 -.36

-.50

-.69

-.80

-51 .69

-51 ,46

-,33

-.33

-.32

-.24

.00

.15 .43

,48

,22

-,20

-.42

-.57

-.64

-.73

-.80

-.91 -.39

-.38

-.37

-,37

-.36

.31 .27 -.09

-.51 -.84

-,67

-.72

-.78

-36,05

-35.83

-.39

-.35

-.36

' expt

MPa

3.8930

3.8925

3.9065

3.9085

3.9091

3.9090

3.9146

3.9143

3.9180

3.9182

3.9206

3.921

1

3.9237

3.9243

3.9275

3.8498

4.0024

4.0201

4.0343

4.0403

4.0424

4.0444

4.0473

4.0480

4.0487

4.0529

1 .9944

2.3629

3.0910

3.581 8 3.8852

4.0478

4.0840

4.0973

4.1029

4.1079

4.1 121 4.1 158

4.1 199

4.1203

4,1205

4,1210

4,1213

3,9199

3,9204

4.0928

4.1 713 4,1857

4,1877

4,1898

4.1915

4.1929

4,1934

4.1947

4,1948

4.1949

^cal c MPa

3,8899

3,8899

3.8993

3.9009

3.9023

3.9023

3.9083

3.9083

3.9118

3.91 19 3.9151

3.91 51 3.9184

3.9185

3.9218

3.851

5

4.0004

4.01 77 4.031 7 4.0375

4.0396

4.0416

4.0424

4.0431

4.0438

4.0489

1 .9944

2.3656

3.0987

3.5392

3.8876

4.0465

4.0820

4.0952

4.1007

4.1056

4.1099

4.1137

4.1 166

4.1170

4 . 1 1 74 4.1177

4.1 181 3.9234

3.9234

4.0922

4.1697

4.1841

4.1866

4.1887

4.1 906

4.1921

4.1926

4.1935

4.1 937

4.1938

Pressure

Diff.

.08

.06 .18

.20

.17

,17

.16

.15 .16

.16

.14

.15

.14

.15 .14 -.04

.05 .06

.07

.07

.07 .07

.12 .12

.12 .10 -.00

-.11 -.25

-.21 -.06

.03

.05 .05

.05 .05

.05

.05 .08

.08

.08 .08

.08 -.09

-.08

.02 .04

.04

.03 ,02

,02

,02

.02 .03

.03 .03

104
Table 7. (Continued)

Data sources and ID numbers: (l)Viria' Equation, (2)Dawson, (3)BedttIe, <4)Deschner, {5)Reainer,

(13)Cherney, (1 7)Toml inson , (24)Ely, ( 26 )D i ttmar , (XXXX)Haynes, ( 51 , 52 )Thomas, ( 78 )Te iciimann

,

{79)Warowny.

51

51

51

5151

51

5151

51

51

51

515151

51

5151

51

5151

5151

5151

5151

51

51

5151

5151

5151

51

5151

51

51 5151

51

5152

5252

5252

52

52

5252

5252

52

52

Data

Point

No.

1 796

1797

1 798

1799

1800

1801 1802

1803

1804

1805

1 806

1807

1808

1809

1810

181

1812

1813

1 814

1815

1816

1817

1818

1819

1 820

1821 1822

1823

1 824

1825

1826

1827

1828

1829

1830

1831 1832

1833

1834

1835

1836

1837

1838

1839

1 840

1841 1842

1843

1844

1845

1846

1847

1848

1849

1850

1851

Weight

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

Temp.

K

369.150

369.1 50 369.150

369.150

369.150

369.1 50 369.150

369.1 50 369.150

369.150

369.150

369.650

369.650

369.650

369.650

369.650

369.650

369.650

369.650

369.650

369.650

369.650

369.650

369.650

369.650

369.650

369.650

369.650

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.750

369.770

369.770

369.770

369.770

369.770

Densi ty

expt

mol/L kg/rrr

6.121

6.1 23 6.126

6.129

6.129

6.134

6.139

6.145

6.199

6.251 6.500

3.000

3.250

3.500

3.750

3.800

3.850

3.900

3.950

4.000

5 . 703

5.733

5,757

5.781 5.781

5.792

5.805

5.829

3.950

4.000

4.050

4.100

4.150

4.200

4.300

5.574

5.608

5.623

5.623

5.642

5.669

5.699

5.758

4.000

4.300

5.554

5.565

5.577

5.588

5.633

5.680

4.000

4.150

4.200

4.250

4.300

269.90

270.02

270.14

270.26

270.26

270.49

270.73

270.97

273.37

275.65

286.63

132.29

143.32

154.34

165.36

167.57

169.77

171 .98 174.18

176.39

251 .49 252.82

253.86

254.90

254.91

255.43

255.96

257.03

174.13

176.39

178.59

180.30

183.00

185.21

189.62

245.80

247.23

247.97

247.98

248.78

249.98

251 .31 253.89

176.39

189.62

244.92

245.42

245.91

246.41

248.42

250.46

176.39

183.00

185.21

187.41

189.62

Dens i ty

calc

kg/m-^

270.78

270.89

271 .01 271 .02

271 .03

271 .25

271 .42

271 .59 273.51

275,36

285.43

132.39

143.67

154.97

166.13

168.32

170.49

172.66

1 74.99

177.26

252.54

253.38

254.02

254.73

254.88

255.1

255.52

256.33

174.86

1 77.24

1 79.03

181 .47 183.67

185.37

191 .27 245.14

246.41

246.22

246.22

248.48

249.24

250.27

251 .92 177.65

191 .61 248.98

248.98

249.1

249.11

250.53

251 .54 177.70

184.61

186.88

189.21

191 .74

Density

Diff

-.32

-.32

-.32

-.28

-.28

-.28

-.25

-.23

-.05

.10

.42 -.07

-.24

-.41 -.46

-.45

-.42

-.39

-.46

-.49

-.42

-.22

-.07

.07

.01 .13

.17

.27 -.38

-.48

-.24

-.37

-.36

-.09

-.86

.27 .35

.71 .72 .12

.30

.41 .78

-.71

-1 .04

-1 .63

-1 .43

-1 .29

-1 .09 -.84

-.43

-.74

-.87

-.89

-.95

-1.11

'^expt

4.1950

4.1951

4.1 953

4.1953

4.1953

4.1956

4.1 958

4.1960

4.1988

4.201

4.2277

4.1155

4.1662

4.1988

4.2178

4.2203

4.2225

4.2244

4.2261

4.2275

4.2319

4.2321

4.2323

4.2326

4.2327

4.2328

4.2329

4.2333

4.2324

4.2340

4.2351

4.2363

4.2371

4.2377

4.2390

4.2395

4.2397

4.2397

4.2397

4.2401

4.2403

4.2405

4.2410

4.2343

4.2390

4.2402

4.2402

4.2402

4.2402

4.2406

4.2409

4.2356

4.2388

4.2395

4.2400

4.2405

'^cal c MPa

4.1939

4.1941

4.1942

4.1943

4.1 943

4.1946

4.1 949

4.1952

4.1 985

4.2024

4.2320

4.1 149

4.1649

4.1974

4.2168

4.2195

4.2218

4.2238

4.2255

4.2270

4.2316

4.2319

4.2323

4.2327

4,2327

4.2329

4.2331

4.2336

4.2319

4.2335

4.2348

4.2359

4.2369

4.2376

4.2387

4.2396

4.2398

4.2400

4.2400

4.2401

4.2404

4.2408

4.2417

4.2335

4.2387

4.2395

4.2396

4.2396

4.2397

4.2401

4.2406

4.2348

4.2382

4.2390

4.2396

4.2401

Pressure

Diff.

.02

.02

.03 .02 .02

.02

.02

.02

.01 -.01 -.10

.01 .03

.03 .02

.02

.02

.01 .01

.01

.01 .00 .00 -.00

-.00

-.00

-.00

-.01

.01

.01 .01

.01 .01 .00

.01 -.00

-.00

-.01 -.01 -.00

-.00

-.01 -.02

.02

.01 .02

.01

.01 .01

.01 .01 .02

.01

.01 .01

.01

105
Table 7. (Continued)

Data sources and ID numbers: (l)Vlrial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7 )Torn I i nson, (24)Ely, (26)Dittinar, (XXXX )Haynes, (51 ,52 )Tho(Ttas, (78)Teichmann,

(79)Warowny.

j1 U d ) a W(3 I nh + Tenip

.

Dens i ty rio n c T ^v/ L/C M o 1 1 y

L/ytlc? 1 1 y p , "^expt p Pressur

rCJ I1 nM +r expt c a 1 c n i -f -f U 1 T T . Ntj • Ki\ mo 1 /L k y/fTi k m tA" r\ra i^B a

s? 1 852 1 .000 369. 770 4.350 191 .82 1 94. 08 -1.16 A 94nR A 94n'i n 1

\ J J 4.440 1 95 . 79 244 .56 -11 Q-? . Q4^H 4 941 9 4H . 94nQ

Z

.Uni1

1 nnn "SfiQ 7 7n 5.544 244 .46 947 ^^7 -1 1

7

I.I/ 4H . 9417 z H 1 / 4H . 9419 Z H 1 Z n 1 J £- 1 855 1 .000 369. 770 5. 566 245.43 94R 1 1 -1 nR 4 9 41 R 4H. 941 ZH 1 4

H

•\jni1

1 Q55 1 .000 "^ftQ. 77n 5.611 247.42 94Q 1 9 - fiR 4 9491 4H . 9417 Z H 1 / . ni\j 1

1 ftS7 1 nnn ^fiQ 77n 5.655 249.37 9'in 4R . HH 4 . Z9494 H Z ^4- 4 949

1

H . Z f Z 1 ni 52 1 858 1 .000 359, 770 5 .703 251 .50 251 .77 . 1 1

1 1 4+ . 949R <1 H Z O 4H . 9497 Z HZ

/

nn

52 1 859 1 . 000 369.790 4.020 1 77 .29 178.58 _, 73 4H . Z

9"^^ 7R/ J 4H . 9Z^U^fi 7

/

. n9^z

52 1 860 1 .000 369. 790 4.221 1 86 . 1 5 1 87.72 - .R4 AH . 9411 Z H I 1 4H . Z94n7 H w / ni 52 1 861 1 .000 369. 790 4.272 188.37 -.16 . 1 o 4. 241

3

4H . Z941H 1 ^ nn

52 1 862 1 .000 369.790 4.322 1 90.59 1 92.14 -.81 4.2420 4.2417 ni 52 1 863 1 .000 369.790 4.372 192 .80 1 94.92 -1 .09 4.2423 4.2421 .01 52 1 864 1 .000 369.790 4.423 1 95.02 1 96.99 -1 .00 4.2425 4 .2423 .00

52 1 865 0.000 369. 790 4.486 197.83 242 .23 -1 8. 33 4,2428 4.2426 .00 52 1 866 1 .000 369. 790 5.51 9 243.38 246.00 -1 .07 4.2433 4.2429 .01 52 1867 1 .000 369.790 5.563 245.32 247.10 -.72 4.2435 4.2431 .01 52 1 868 1 .000 369.790 5.609 247.32 247.93 -.24 4.2436 4 .2435 .00 52 1869 1 .000 369.790 5.654 249.34 249.46 -.05 4.2440 4.2440 .00

52 1 870 1 .000 369.790 5.701 251 .40 251 .08 .13 4.2445 4.2446 -.00

52 1871 1 .000 369.810 4.000 1 76.39 1 77.64 -.71 4.2382 4.2374 .02

52 1 872 1 .000 369.81

0

4.200 1 85.21 1 86.38 -.63 4.2421 4.2417 .01 52 1873 1 .000 369.81

0

4.300 189.62 191 .02 -.74 4.2432 4.2429 .01 52 1 874 1 .000 369.810 4.350 1 91 .82 1 93.07 -.64 4.2436 4.2434 .00

52 1875 1 .000 369.81

0

4.400 1 94 . 03 195.65 -.83 4.2439 4.2437 .00

52 1 876 1 .000 369. 81

0

4.450 1 96.23 1 98.52 -1 .15 4.2441 4.2439 .00 52 1 877 0.000 369.81

0

4.530 199.76 241 . 1

1

-17.15 4. 2444 4.2442 .01 52 1 878 1 .000 369.810 5.473 241 .35 244.37 -1 .24 4.2448 4.2445 .01 52 1 879 1 .000 369.81

0

5.517 243 .27 244. 78 -.51 4.2449 4.2447 .00

52 1 880 1 .000 369.810 5.561 245.24 246. 1

7

-.38 4 .2451 4.2449 .00 52 1 88

1

1 .000 369.81

n

5.629 248.23 248. 1

8

.02 4.2455 4.2455 -.00

52 1 882 1 .000 369. 81

0

5.699 251 .30 250.54 .30 4.2462 4.2464 -.01 52 1 883 1 .000 369.830 4. 000 1 76. 39 1 77.79 -.79 4.2396 4. 2387 .02 52 1 884 1 ,000 369. s'sn 4 . 200 1 85. 21 1 86 .45 -.66 4.2435 4.2431 .01 52 1 385 1 .000 A "snn 1 RQ fO 1 Qi nR - 7fi 4H . 9447 Z HH / 4,2444 .01 52 1 886 1 .000 369. R^n 4 .400 1 94 .03 1 95 ,57 - . 84 4.9453 H . ZH 4 .2451 .00

J u t oo /

1 nnn A 4sn 1 Qfi 9"^

I •S.J 1 QR 1 n - . Q4^H H. ZH 4 94S4 nn

J 1 RRf! 1 nnn A snn 1 QH AA 9nn Ri -1 n4 4 94'i7 AH . lA'^fk ZH-JD nn

-/ 1

1 SRQ 007 n nnn 4,572 201 .61 9"=;^ n7 -1 4 fin 4 94'iQ 4H . 94'i7 ZH ^

/

nn

1 RQO 1 nnn 5 .351 941 97 -9 1 Q 4H • 94fi9 ZHDZ 4 94RO ni

1 nnn 47^ 949 RiS - fi'^ 4H . 94fi4 Z HUH 4H . 9Z 4fi9 HUZ nn

1 892 1 .nnn 94"^ 9'S 94"^ QI - 97 4H . 94fi'i ZHO^ 4H . 94fi4 ZH UH .nn

11 RQ'^ O ^J 1 nnn • OJ u 5 .561 94^ 9n 94^ ZH_/ • 77/ / 4H . ZHDO 94fiR 4H . 94fi7 Z HU / nn

52 1 894 1 .000 5.606 247.20 947 ZH "^R

/

mjj — nfi 4H . 9479 ZH /

Z

4H . 9471 Z H / 1 nn

52 1 895 1 nnn 5.675 250.24 94Q 4S ^9 . JZ 4H . ZH9477/

/

4H . Z947Q H / 7 - . ni\j 1 52 1896 1 .000 369.840 4.000 176.39 177.61 -.69 4.2402 4.2393 .02 52 1897 1 .000 369.840 4.200 185.21 186.71 -.80 4.2443 4.2438 .01 52 1898 1 .000 369.840 4.400 194.03 195.96 -.99 4.2461 4.2458 .01 52 1899 1 .000 369.840 4.450 196.23 197.88 -.83 4.2463 4.2461 .00

52 1900 1 .000 369.840 4.500 198.44 199.86 -.71 4.2464 4.2463 .00 52 1901 1 .000 369.840 4.550 200.64 205.97 -2.59 4.2466 4.2464 .00

52 1902 0.000 369.840 4.600 202.85 234.49 -13.49 4.2467 4.2465 .00 52 1903 1.000 369.840 5.300 233.^0 240.24 -2.72 4.2470 4.2467 .01 52 1904 1 .000 369.840 5.340 235.49 241 .12 -2.34 4.2471 4.2467 .01 52 1905 1 .000 369.840 5.382 237.32 240.70 -1 .40 4.2471 4.2468 .01 52 1906 1 .000 369.840 5.450 240.35 241 .81 -.60 4.2472 4.2470 .00 52 1907 1 .000 369.840 5.499 242.51 243.66 -.47 4.2474 4.2472 .00

106
Table 7. (Continued)

Data sources and ID numbers: (l)VIrial Equation, (2)Dawson, (3)BeattIe, (4 )Desciiner , (5)Reamer,

(l3)Cherney, (1 7)Tomi Inson, (24)Ely, (26 )D 1 ttrnar , (XXXX)Haynes, ( 51 , 52 )Thomas, (78)Teichmann,

(79)Warowny

.

52

51

51

5151

51

5151

5151

5152

52525252

52

525252

52

52

5252

5252

525252

52

52

52

52

52

52

52

5252

52

5252

52

5252

52

525252

5252

52

52

5252

52

52

Data

:=oInt No.

1908

1909

1910

1911 1912

1913

1914

191 5 1916

191 7 1913

1919

1920

1921

1 922

1923

1924

1925

1926

1927

1923

1929

1930

1931 1932

1933

1934

1935

1936

1937

1933

1939

1940

1941 1942

1943

1944

1945

1946

1947

1948

1949

1 950

1951

1 952

1953

1954

1955

1956

1957

1958

1959

1960

1961 1962

1963

Wei gilt Temp.

1 .000

1 .000

1 .000

1 .000

1 ,000

1 .000 0.000

0.000

0.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

0.000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

1 .000

369.840

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.850

369.860

369.860

369.860

369.860

369.860

369.860

369.860

369.860

369.860

369.860

369.860

369.860

369.860

369.860

369.870

369.870

369.870

369.870

369.870

369.870

369.870

369.870

369.870

369.870

369.870

369.870

369.870

mol/L

5.600

4.000

4.200

4.400

4.600

4.800

5.000

5.000

5.200

5.400

5.600

4.000

4.200

4.400

4.450

4.500

4.550

4.600

4.750

4.900

5.000

5.100

5.150

5.150

5.300

5.350

5.400

5.500

5.600

4.000

4.147

4.400

4.600

4.700

4.800

4.900

5.000

5.100

5.200

5.300

5.400

5.500

5.600

4.000

4.200

4.400

4.600

4.700

4.800

4.900

5.000

5.100

5.200

5.300

5.400

5.500

Dens i fy

expt

kg/in^

246.96

1 76.39

185.21

194.03

202.85

21 1 .67 220.49

220.49

229.31

238.13

246.94

176.39

1 85.21 194.03

1 96.23

198.44

200.64

202.85

209.46

216.08

220.49

224.90

227.10

227.10

233.72

235.92

238.13

242.53

246.94

176.39

182.87

194.03

202.85

207.26

21 1 .67 216.08

220.49

224.90

229.31

233.72

238.13

242.53

246.94

176.39

185.21

194.03

202.85

207.26

21 1 .67 216.08

220.49

224.90

229.31

233.72

238.13

242.53

Dens I ty

calc

kg/m-'

246.74

177.04

185.29

193.06

197.69

198.93

199.95

199.20

199.49

228.29

241 .74 177.64

1 86.54

195.62

197.92

200.27

201 .99 207.91

233.13

233.93

236.22

236.65

237.78

237.05

239.00

238.72

239.27

242.97

246.01

177.46

183.83

194.48

202.38

216.54

206.69

228.90

223.53

232.66

232.66

234.40

238.52

241 .76

245.46

177.46

186.08

194.97

203.41

207.20

218.31

224.98

230.36

231 .39 232.24

234.72

237.13

241 .52

Dens I ty

Diff

.

.09 -.37

-.04

.50 2.61 6.40

10.27

10.68

14.94

4.31 2.15

-.70

-.71 -.82

-.85

-.92

-.67

-2.43

-10.15

-7.63

-6.66

-4.97

-4.49

-4.20

-2.21 -1.17

-.48

-.18

.38

-.61 -.52

-.23

.23 -4.29

2.41 -5.60

-1.36

-3.34

-1 .44 -.29

-.16

.32

.60 -.60

-.47

-.48

-.28

.03 -3.04

-3.96

-4.29

-2.81 -1.27

-.43

.42 .42

'' expt

MPa

4.2479

4.2404

4.2445

4.2464

4.2470

4.2471

4.2472

4.2471

4.2471

4.2475

4.2480

4.2408

4.2449

4.2468

4.2470

4.2472

4.2473

4.2474

4.2475

4.2476

4.2476

4.2477

4.2477

4.2477

4.2478

4.2478

4.2478

4.2482

4.2487

4.241

4

4.2447

4.2474

4.2480

4.2483

4.2482

4.2483

4.2483

4.2484

4.2484

4.2484

4.2486

4.2489

4.2495

4.2420

4.2462

4.2481

4.2488

4.2490

4.2491

4.2491

4.2492

4.2492

4.2492

4.2493

4.2494

4.2498

' cal c

f-Fa

4.2480

4.2400

4.2445

4.2466

4.2473

4.2475

4.2475

4.2475

4.2475

4.2477

4.2489

4.2400

4.2445

4.2466

4.2468

4.2470

4.2472

4.2473

4.2474

4.2475

4.2475

4.2475

4.2475

4.2475

4.2475

4.2476

4.2477

4.2481

4.2489

4.2406

4.2443

4.2473

4.2481 4.2482

4.2482

4.2483

4.2483

4.2483

4.2483

4.2484

4.2486

4.2490

4.2498

4.241

3

4.2459

4.2480

4.2488

4.2490

4.2490

4.2491

4.2491

4.2491

4.2492

4.2493

4.2495

4.2499

Pressure

DIf f

.

-.00

.01 .00 -.00

-.01

-.01 -.01

-.01

-.01 -.01 -.02

.02

.01 .00

.00

.00

.00 .00 .00

.00 .00

.00

.01 .00

.01 .00

.00 .00 -.00

.02

.01 .00 -.00

.00 -.00

.00 .00

.00

.00

.00 .00 -.00

-.01 .02

.01 .00

.00 -.00

.00

.00 .00

.00

.00

.00 -.00

-.00

107
Table 7. (Cont-inued)

Data sources and ID numbers: (])Virial Equation, (2)Dawson, (3)Beai-He, (4)Deschner, (5)Reamer,

(l5)Cherney, (1 7)Toinl I nson, (24)Ely, ( 26 )D i ttrnar , (XXXX )Haynes, ( 51 , 52 )Thomas, ( 78 ) Teichinann

,

(79)Warowny

.

ID Data We i gh h Temp

.

Dens i ty Dens i ty Dens i ty pexp h ca 1 c Pressure

Point expt calc Diff

.

Diff.

No • K mol /L kg/m kg/

m

% MPa MPa %

52 1964 1 .000 369.870 5.600 246.94 245.43 .62 4.2504 4.2507 -.01

51 1965 1 .000 369.900 4.000 1 76.39 1 76.78 -.22 4.2435 4.2432 .01

51 1966 1 .000 369.900 4.200 185.21 135.09 o06 4.2479 4.2479 -.00

51 1967 1 .000 369.900 4.560 201 .08 1 95 . 1 0 3.07 4.2503 4.2510 -.01

51 1968 1 .000 369.900 4.600 202.85 197.04 2.95 4.2506 4.251

1

-.01

51 1969 1 .000 369.900 4.700 207.26 198.85 4.22 4.2508 4.251

3

-.01

51 1 970 1 .000 369.900 4.800 21 1 .67 198.34 6.72 4.2507 4.2514 -.02

51 1971 1 .000 369.900 4.900 216.08 1 97.21 9.57 4.2506 4.251

4

-.02

51 1972 1 .000 369.900 5.000 220.49 201 .63 9.35 4.2510 4.2515 -.01

51 1973 0.000 369.900 5.100 224.90 199.76 12.58 4.2509 4.2516 -.02

51 1974 0.000 369.900 5.200 229.31 202.26 13.37 4.2510 4.2517 -.02

51 1975 1 .000 369.900 5.300 233.72 21 5.53 8.44 4.2514 4.2513 -.01

51 1976 0.000 369.900 5.400 238.13 207.64 14.68 4.2513 4.2521 -.02

51 1977 1 .000 369.900 5.600 246.94 240.84 2.54 4.2524 4.2535 -.03

51 1978 1 .000 369.900 5.800 255.76 251 .63 1 .64 4.2549 4.2569 -.05

51 1979 1 .000 370.150 2.500 110.24 109.39 .32 3.9553 3.9591 -.10

51 1980 1 .000 370.150 3.000 132.29 132.30 -.00 4.1376 4.1376 .00

51 1981 1 .000 370,150 3.500 154.34 154.33 -.31 4.2262 4.2249 .03

51 1982 1 .000 370.150 4.000 1 76.39 1 76.66 -.15 4.2596 4.2594 .01

51 1983 1 .000 370.150 4.500 198.44 194.37 1 .83 4.2683 4.2691 -.02

51 1984 1 .000 3 70.1 50 4.750 209.46 201 .37 4.02 4.2696 4.2706 -.02

51 1985 1 .000 370.150 5.000 220.49 205.72 7.18 4.2702 4.2718 -.04

51 1986 1 .000 370.150 5.250 231 .51 212.74 8.82 4.2710 4.2730 -.05

51 1987 1 .000 370.150 5.500 242.53 227.02 6.83 4.2725 4.2750 -.06

5! 1988 1 .000 370.150 6.000 264.58 259.93 1 .79 4.2845 4.2898 -.12

108
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer

(13)Cherney, ( 1 7)Tom I i nson (24)Ely, (26)Dittmar, (XXXX)Haynes, ( 51 , 52)Thomas, ( 78)Te ichmann

,

(79)Warowny.

ID Data Weight Temp. Density Density Density ^expt '^calc Pressure

Point expt calc Diff. Diff.

No. K mol/L kg/m^ kg/m^ % MPa MPa %

17 1989 0.000

17 1990 0.000

17 1991 0.000

17 1992 0.000

17 1993 0.000

17 1994 0.000

17 1995 0.000

17 1996 0.000

17 1997 0.000

17 1998 0.000

17 1999 0.000

17 2000 0.000

17 2001 0.000

17 2002 0.000

17 2003 0.000

17 2004 0.000

17 2005 0.000

17 2006 0.000

17 2007 0.000

17 2008 0.000

17 2009 0.000

17 2010 0.000

17 201

1

0.000

17 2012 0.000

17 2013 0.000

17 2014 0.000

17 2015 0.000

17 2016 0.000

17 2017 0.000

17 2018 0.000

17 2019 0.000

17 2020 0.000

17 2021 0.000

17 2022 0.000

17 2023 0.000

17 2024 0.000

17 2025 0.000

17 2026 0.000

17 2027 0.000

17 2028 0.000

322.594 10.259

324.817 10.257

327.594 10.254

318.706 10.439

323.150 10.434

327.594 10.429

313.706 10.619

320.928 10.611

327.594 10.603

309.261 10.816

314.817 10.810

320.372 10.802

325.928 10.796

304.261 10.997

313.150 10.986

322.039 10.975

298.150 11.183

305.372 11.173

313.706 11.162

322.039 11.151

293.150 11.364

298.150 11.357

308.150 11.343

316.483 11.332

298.150 11.532

299.817 11.547

303.150 11.525

308.706 11.517

282.594 11.724

284.261 11.722

291.483 11.710

298.150 11.700

303.150 11.693

277.594 11.880

285.928 11.866

291.483 11.857

298.150 11.847

280.372 12.038

285.928 12.029

291.483 12.020

452.40 451.56

452.29 451.41

452.16 451.30

460.31 459.51

460.09 459.27

459.87 459.09

468.29 467.57

467.90 467.21

467.56 466.92

476.97 476.40

476.67 476.06

476.36 475.79

476.07 475.49

484.95 484.34

484.44 483.85

483.95 483.42

493.13 492.60

492.69 492.19

492.21 491.74

491.73 491.30

501.13 500.68

500.81 500.39

500.20 499.86

499.70 499.43

508.54 508.21

509.17 509.61

508.23 507.93

507.88 507.64

517.01 516.63

516.89 516.52

516.37 516.11

515.95 515.73

515.63 515.42

523.87 523.54

523.27 523.06

522.87 522.75

522.43 522.37

530.83 530.84

530.43 530.49

530.04 530.20

.19 2.0774

.19 2.91 10 .19 3.9672

.17 2.0864

.18 3.8638

.17 5.6523

.15 1.7382

.15 4.8022

.14 7.631

1

.12 1.9140

.13 4.4064

. 12 6.9085

.12 9.3913

.13 1 .7127

. 12 5.9412

.1 1 10. 1567

.11 1. 1238

.10 4.7615

.10 8.9370

.09 13.0890

.09 1.1445

.08 3.8100

.07 9.1 162 .05 13.5096

.07 6.9272

-.09 8.5157

.06 9.7195

.05 12.8125

.07 1 . 1625

.07 2. 1484 .05 6.4383

.04 10.3635

.04 13.2765

.06 1.0563

.04 6.2501

.02 9.6864

.01 13.7792

-.00 6.5769

-.01 10.1780

-.03 13.7881

2.2342 -7.02

3.0809 -5.52

4.1402 -4.18

2.2552 -7.49

4.0467 -4.52

5.8351 -3.13

1.9070 -8.85

4.9781 -3.53

7.8069 -2.25

2.0652 -7.32

4.5778 -3.74

7.0777 -2.39

9.5736 -1.90

1.8918 -9.47

6.1290 -3.06

10.3414 -1.79

1.2935 -13.12

4.9342 -3.50

9.1134 -1.94

13.2597 -1.29

1.3031 -12.17

3.9649 -3.90

9.2563 -1.51 13.6266 -.86

7.0698 -2.02

8.3215 2.33

9.8542 -1.37

12.9268 -.88

1.3245 -12.23

2.3107 -7.02

6.5580 -1.82

10.4706 -1.02

13.3815 -.78

1.2104 -12.74

6.3549 -1.65

9.7503 -.65

13.8113 -.23

6.5729 .06 10.1461 .31 13.6958 .67

109
Table 7. (Continued)

Data sources and ID numbers; (l)Virlal Equation, (2)Dawson, (3)Beattie, (4 ) Desciiner , (5)Reamer,

(13)Cherney, ( 1 7 )Tom li nson , (24)Ely, (26)Dittmar, (XXXX)Haynes , ( 51 ,52)Thomas, ( 78)Te ichmann

,

(79)Warowny.

ID Data Weight Temp. Density Density Density ^expt ^calc Pressure

Point expt calc Diff. Diff.

No. K mol/L kg/m^ kg/m^ % MPa MPa %

4 2029 0,000

4 2030 0.000

4 2031 0.000

4 2032 0.000

4 2033 0.000

4 2034 0.000

4 2035 0.000

4 2036 0.000

4 2037 0.000

4 2038 0.000

4 2039 0.000

4 2040 0.000

4 2041 0.000

4 2042 0.000

4 2043 0.000

4 2044 0.000

4 2045 0.000

4 2046 0.000

4 2047 0.000

4 2048 0.000

4 2049 0.000

4 2050 0.000

4 2051 0.000

4 2052 0.000

4 2053 0.000

4 2054 0.000

4 2055 0.000

4 2056 0.000

4 2057 0.000

4 2058 0.000

4 2059 0.000

4 2060 0.000

4 2061 0.000

4 2062 0.000

4 2063 0.000

4 2064 0.000

4 2065 0.000

4 2066 0.000

4 2067 0.000

4 2068 0.000

4 2069 0.000

4 2070 0.000

4 2071 0.000

4 2072 0.000

4 2073 0.000

4 2074 0.000

4 2075 0.000

4 2076 0.000

4 2077 0.000

4 2078 0.000

4 2079 0.000

4 2080 0.000

4 2081 0.000

4 2082 0.000

4 2083 0.000

4 2084 0.000

303.150 .041 348.150 .035

373,150 .033

380.950 .032

303.150 .083

348,150 .071 303.150 .126

380.950 .098

303.150 .171 348.150 .145

303.150 .217

373.150 .170

380.950 .165

398.150 .158

303.150 .266

348.150 .223

303.150 .317

303.150 .371 348.150 .304

303.150 .429

303.150 .493

348.150 .389

373.150 .355

380.950 .343

398.150 .327

348.150 .480

348.150 .577

373.150 ,562

380.950 .539

398.150 .506

348,150 .680

348.150 .792

348.150 .915

373.150 .796

380.950 .758

398.150 .709

348.150 1.052

348.150 1.208

373.150 1.065

380.950 1.006

398.150 .928

348.150 1.398

348.150 1.617

373.150 1.391 380,950 1,292

398,150 1,172

373,150 1,807

380.950 1.641 398,150 1.451 373.150 2.436

380.950 2.099

398.150 1.776

373,150 5.216

380.950 2.738

398.150 2.161 373.150 6.656

1,79 1,80

1.55 1.56

1.44 1.45

1.41 1.42 3,64 3,67

3,13 3,16

5,55 5.59

4.30 4.34

7.53 7.59

6.40 6.45

9.59 9.66

7.48 7.53

7.28 7.35

6.95 7.00

11.73 11.83

9.82 9,90

13.99 14.09

16.38 16.48

13.40 13.51 18.93 19.00

21.73 21.68

17.17 17.31 15.66 15.75

15.15 15.33

14.41 14.50

21.17 21.33

25.42 25,62

24,78 24,84

23,78 24.07

22.29 22.58

29.99 30.22

34.92 35.19

40.33 40.64

35.08 35.08

33.44 33.79

31.25 31.37

46.39 46,71

53.28 53.65

46.97 46.93

44.35 44.80

40,92 41,02

61.66 61.91

71.29 72.55

61,33 61,23

56.99 57,64

51,69 51,77

79,68 79.91

72.35 73.36

64.00 63.99

107,41 109,24

92.57 94.24

78.3.1 78.25

230.02 248.93

120.74 127.28

95.28 95.54

293.50 294.08

-.80 . 1013

-. 74 .1013

-.78 .1013

-.83 .1013

-.79 .2027

-.79 .2027

-,81 .3040

-,98 .3040

-,80 .4053

-.78 .4053

-.82 .5066

-.66 .5066

-1.03 .5066

-.75 .5066

-.79 .6080

-.77 .6080

-.71 .7093

-.59 .8106

-.81 .8106

-.34 .9119

.21 1.0133

-.83 1 .0133

-.54 1 .0133

-1 .20 1,0133

-.62 1 .0133

-.77 1 ,2159

-.76 1 .4 186

-. 27 1 ,5199

-1 .22 1 .5199

-1 ,28 1 .51 99

-.75 1 . 62 1

2

-.76 1 .8239

-,75 2.0265

-,01 2.0265

-1 ,04 2.0265

-.38 2.0265

-.69 2,2292

-.70 2.4318

,09 2.5331

-1,00 2.5331

-.24 2.5331

-.42 2.6345

-1,73 2.8371

.17 3.0398

-1.13 3.0398

-.15 3.0398

-.29 3.5464

-1,37 3.5464

.02 3.5464

-1.67 4.0530

-1.78 4.0530

.07 4.0530

-7.59 4.5596

-5.14 4.5596

-.27 4.5596

-.20 4.7623

. 1005 .80

. 1 006 .74 .1005 .78 .1005 .83

.201

1

.77

.201 1 .78 ,3016 .77

,301

1

.96 .4023 .76

.4023 .76 .5028 .76

.5034 .64 ,5016 1.00 .5030 .73 .6036 .71 .6036 .73 .7049 ,62

.8066 ,50

.8046 ,74 .9094 .27 1.0149 -.17

1.0058 .74

1 .0083 .49

1 .0020 1. 12

1 .0074 .58

1 .2079 .66 1.4096 .63

1 .5164 .23

1 .5037 1 .08

1 .5025 1 . 16 1.6115 .60

1 .8 1 34 .58 2.01 56 .54 2.0264 .01 2.0091 .87 2,0199 .33 2,2190 .46

2,4217 .42 2,5348 -.07

2,5139 .77 2,5283 .19 2,6287 .22 2,8164 .73 3.0430 -.11

3.0161 .79

3.0363 ,11

3.541

1

.15 3.5174 .83 3,5468 -.01 4,0299 .57 4,0185 .86

4,0547 -.04

4,5284 .69 4,4818 1.74 4,5528 .15 4.7571 .11

110
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7)Tom I i nson , (24)Ely, (26)Di ttmar, (XXXX)Haynes , ( 51 ,52)Thomas, (78)Teichmann,

(79) Warowny.

ID Data Point

No.

Weight Temp.

K

Dens i ty

expt

mol/L kg/mDens i ty ca Ic kg/m^

Dens i ty

Dif f. ^expt

MPa

ca I c MPa

Pressure

Dif f.

2085

2086

2087

2088

2089

2090

2091 2092

2093

2094

2095

2096

2097

2098

2099

2100

2101 2102

2103

2104

2105

2106

2107

2108

2109

21 10 2111

21 12 2113

21 14 2115

21 16 2117

21 18 2119

2120

2121 2122

2123

2124

2125

2126

2127

2128

2129

2130

2131 2132

2133

2134

2135

2136

2137

2138

2139

2140

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

373. 150 373.150

373. 150 380.950

398. 150 373. 150 380.950

398. 150 380.950

380.950

373.150

380.950

398. 150 373.150

380.950

398.150

373.150

380.950

398.150

373.150

380.950

398.150

373.150

380.950

398. 150 373.150

380.950

398. 150 373.150

380.950

398.150

373.150

380.950

398.150

373.150

380.950

398. 150 373.150

380.950

398. 150 373.150

380.950

398.150

373.150

380.950

398.150

373.150

380.950

398. 150 373. 150 380.950

398.150

373.150

380.950

398.150

398.150

6.881

7.065

7.213

4.076

2.641

7.675

6.078

3.287

6.472

6.774

8.007

6.906

4.134

8.235

7.325

5.044

8.409

7.637

5.774

8.565

7.862

6.320

8.673

8.051

6.734

8.806

8.229

7.084

8.917

8.369

7.359

9.016

8.491

7.599

9. 109 8.602

7.774

9. 186 8.698

7.939

9.257

8.787

8.082

9.320

8.876

8.204

9.376

8.960

8.315

9.431

9.038

8.412

9.486

9.120

8.501

8.656

303.45

31 1 .56

318.06

179.74

1 16.44

338.43

268.01

144.94

285.40

298.72

353.1

1

304.55

182.30

363.12

323.03

222.42

370.79

336.78

254.60

377.71

346.67

278.68

382.43

355.04

296.93

388.31

362.87

312.38

393.20

369.04

324.53

397.57

374.43

335.08

401 .70

379.32

342.80

405.07

383.55

350.10

408. 19 387.47

356.41

410.97

391.42

361.77

413.46

395.10

366.67

415.87

398.55

370.96

418.31

402. 15 374.85

381.70

303.69

310.98

316.91

203.65

1 17.53

336.86

280.62

146.83

295.54

306.54

349.73

311.11

184.72

359.44

328.55

223.59

367.34

340.91

255.72

374.05

350.59

279.93

379.91

358.59

297.88

385.12

365.44

31 1.73

389.83

371 .45 322.88

394. 14 376.82

332.19

398. 12 381.68

340.18

401.81

386. 13 347.17

405.27

390.24

353.39

408.51

394.06

359.01

41 1.58

397.63

364. 13 414.49

400.99

368.83

417.25

404.16

373.19

381.06

-.08

.18 .36

-1 1 .74 -.93

.47 -4.49

-1.29

-3.43

-2.55

.97

-2. 1 1 -1.31

1.02 -1.68

-.52

.94

-1 .21 -.44

.98 -1.12

-.44

.67 -.99

-.32

.83 -.70

.21 .86 -.65

.51 .87 -.63

.87 .90

-.62

.77

.81 -.67

.84 .72 -.71

.85

.60 -.67

.77

.46 -.64

.70

.33 -.61

.58 .25 -.50

.44

.17

4.8636

4.9649

5.0663

5.0663

5.0663

5.5729

5.5729

5.5729

5.7755

5.9782

6.0795

6.0795

6.0795

6.5861

6.5861

6.5861

7.0928

7.0928

7.0928

7.5994

7.5994

7.5994

8. 1060

8. 1060

8. 1060 8.6126

8.6126

8.6126

9.1 193

9. 1193

9.1 193 9.6259

9.6259

9.6259

10.1325

10. 1325

10.1325

10.6391

10.6391

10.6391

11.1458

11. 1458 11.1458

1 1.6524

1 1 .6524

1 1.6524

12.1590

12. 1590

12.1590

12.6656

12.6656

12.6656

13. 1723

13. 1723 13.1723

14. 1855

4.8606

4.9739

5.0881

4.9509

5.0442

5.6259

5.4473

5.5444

5.6303

5.8286

6.2424

5.9374

6.0491

6.8106

6.4027

6.5697

7.3438

6.9071

7.0726

7.9082

7.3814

7.5692

8.3447

7.8705

8.0753

8.9499

8.4143

8.6394

9.5117

8.9092

9.2028

10.0607

9.3943

9.8010

10.6234

9.8804

10.3155

1 1 . 1 1 66 10.3399

10.8709

1 1.6003

10.8007

1 1 .41 15 12.0564

11.2983

1 1.9203

12.4833

1 1.7969

12.4273

12.9157

12.2950

12.9080

13.3720

12.8472

13.3749

14.2734

.06

-. 18 -.43

2.33

.44 -.94

2.31

.51 2.58

2.57

-2.61

2.39

.50 -3.30

2.86

.25

-3.42

2.69

.28 -3.91

2.95

.40 -2.86

2.99

.38 -3.77

2.36

-.31 -4.13

2.36

-.91 -4.32

2.47

-1 .79 -4.62

2.55

-1 .77 -4.30

2.89

-2.13

-3.92

3.19

-2.33

-3.35

3.13

-2.25

-2.60

3.07

-2. 16 -1.94

3.01

-1 .88

-1 .49 2.53

-1.52

-.62

111
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reanier,

(13)Cherney, ( 1 7 )Tom 11 nson , (24)Ely, ( 26)D i ttmar , (XXXX)Haynes, ( 51 ,52)Thomas, (78)Teich(nann,

(79)Warowny.

1

D

Data Weight Temp. Dens i ty Dens i ty Dens i ty p

''^expt p^ca 1 c Pr essui Po i nt expt ca i c u 1 T T . U 1 T T , No. K mol /L 1 / 3 kg/m^ of ilra d

To

4 2141 0.000 423. 1 50 .029 1.27 1 9Q 1 . zo

-7-7 1 A 1 T 1 AA C

. 1 UUD .77

4 2142 0.000 473. 1 50 .026 1.13 1 i A 1.14 -.76 ,1013 . 1 006 ,76

4 2143 0.000 526.370 .023 1.02 1 .03 -.77 .1013 . 1005 .77

4 2144 0.000 423. 1 50 .087 3.85 3.88 -. 76 .3040 .301

7

.75

4 2145 0.000 473, 1 50 .078 3.43 3.45 -.78 .3040 ,3016 .77

4 21 46 0.000 526.370 .070 3.07 3.09 -.83 .3040 ,301 5 ,83

4 2 147 0.000 423. 1 50 .147 6.50 D. D4 7 A -. /U . DUOD CA zo

, DU3z £ 0 ,00

4 2148 0.000 A TZ 1 CA 4 /3 . 1 50 .131 5.76 a OA D.oU 7/1 -. /4 AAA • DUDD C AOA 7 ^ ,74

4 2149 0.000 526^370 .1 17 5. 14 c 10 D. lO 0 7 -.0 / ,5066 C AO'Z

, 5023 ,85

4 21 50 0.000 423. 1 50 .304 13.39 1 "Z AC 13.46 -, 55 1 A 1 Z "Z

1 .0133 1 . 0079 ,53

4 2 1 51 0.000 473. 150 .266 1 1 .75 1 1 . 82 -.59 1 .0133 1 ,0074 .58

4 21 52 0. 000 525.3/0 .236 10,41 1 A C^A

1 U. DU Q 1 1 A 1 "Z "Z

1 .0 1 33 1 A A c: z1 ,UUD3 7 A

. /y

4 2 1 53 A AAA A ox 1 c:a 4ZJ . 1 5U .469 20.69 9 A 70 zu, /y -.4yA Q 1 . D 1 yy 1 1 "Z A 1 , D

1

jU A A .40

Z 1 54 A AAA 4 /_> . 1 DU .408 17.99 1(5 A7 10 , U / — A 1 .4 1 1 . D 1 yy 1 R 1 >1 A 1 , D 1 4U "ZQ

. jy

4

o 1 A AAA u.uuu £^9A X~7A DZD. J /U .359 1 5.82 1 D,y4 -. /J 1 c; 1 QQ 1 • D 1 yy 1 RAQO 1 , Duyz 7

1

4

O 1 c^^^ Z 1 30 n AAA u. uuu R7A A RA D /U.4DU .328 14,46 1

1 A RA 4 , DO —— fi7 . D /

1

1 , D

R 1

1 QQyy 1 RAQQ 1 , Duyy .00AA

4 Z 1 D / A AAA u. uuu /I 9"^ 1 Rn 4Z J. 1 DU .646 28.47 9ft "=10 ZO , Dy —— .4A 1

1 9 n9A s Z , UZOD 9 n 1 Q

1

z , u 1 y 1 z 7

A4 Z 1 DC) A AAA u. uuu /I"7X 1 RA 4 / J . 1 DU .555 24.49 OA RR Z4 « DD — OX,

. ZD 9 n9A R Z , UZO D 9z , n999 uzzz 9 1 .Z 1 4 z 1 A AAA U. UUU R9A "^7n DZD . J) /U .485 2 1 .39 9 1 R

1

Z 1 , D 1 — . DD 9Z , n9A UZOD 9z, nu 1 RQ 1 Dy . D J

4 Z 1 DU U» UUU R7n A'^n D / U. 4 DU .44

1

19.47 11 Qy , ^1D / , DZ 9Z ,UZD n9A D 9z, nU 1

I AA0^ . snDU

4 Z 1 D 1 u. uuu hZ3 .

1

1 cnDU .835 36.81 DO, y 1 9Z S^'^ 1 , DDD

1

9Z '^97n , DZ /

u

. Z*+ 9A

4 9 1 (^9 Z 1 OZ nu.uuu nnn /I7T 1 CA 4 /-> . 1 DU .709 3 1 .24 D 1

! • Z97/ _ 1 A, 1 U Z , DDD

I

9 Cl-Z AQ

z , jDuy .uyno

A4 9 1 A'^ Z 1 OJ) nu . nnn uuu 'i?^ DZD ^7n

.

J lU .614 27.09 97Z / 0 9nZU _ Ar\ — U Z , DDD

I

7 'S9'^A <^ , Jc,D\> . _30 Z 1 nu» nnn uuu D /U.^DU .557 24. 57 ZH .DO Z,9 R'^^ 1

1 9 'S7AS 4

9 1 AR Z 1 D J A AAA u.uuu /1 9T 1 t^A 4Z_>» 1 DU 1 .038 45.78 H D.O / -— .10IS Z A ZQO J , uDyo z Az c:^ 1 A

4

9 1 ^^^^ Z 1 DO A AAA u. uuu 4 /D . 1 DU .868 38.26 "^ft 97 JO . Z / — n 1 .u 1 J, u jy

0

j,UjyD n"^Q c; n 1 .u 1

/I 4

9 1^7 Z 1 0 / A AAA u. uuu DZD. J /U .747 32.94 7 A9 J J.UZ _— 97 . z / J, u jyo n'^97 D , U JZZ .ZD7 R

A4

9 1 Z 1 Do A AAA u. uuu C7A A c^n D /U.4DU .675 29.77 9Q Q*^ zy .OD -. 9nzu D. ujyo X (\XA 1 D, U J4

1

1 Q , 1 y

4

9 1 An z 1 oy A AAA U.UUU /I 9 "Z 1 t^A 4Z J. 1 DU 1 .258 55.46 DD. Do -.10 X cry! A^ J. D404 z 1 c D,D4 1 D1 A

, 1

4

4 Z 1 /U A AAA U.UUU / 7"? 1 c:a 4 /D. 1 DU 1 .034 45.60 4D. DD 1 9 . 1 Z

Z c^yl A/1 D. D4d4 Z c: c AA D, DDUU 1

A

4

9 1 "7 1 Z 1 / 1 A AAA U.UUU c:9A T7A DZD. J /U ,883 38.92 Do.yo -.10 D.D4D4 X ^A 1 9 J,D4 1 Z1 R , 1 D 4 Z 1 /z A AAA U.UUU c; 7 A /] c A

D /U. 4DU .795 35.06 "ZC^ A7 JD.U/ A 1 -,U 1 •z C/i £:a J. D4o4 Z c^/1 AA D. D4dU A 1 ,U 1 4 Z 1 /3 A AAA U.UUU /I 9'Z 1 t^A 4Zd. 1 DU 1 .498 66.06 AA 1 c; DO, 1 D

1 z -,13 4.UDDU A A/1 0 1 4.U4y

1

1 A , 1 U

4 2 1 74 0.000 473. 1 50 1 .207 53.24 CT 1 "Z 53, 13 ,2 1 4, 0530 /I Az: A z 4,0603 1 0 -, 18 4 2175 0.000 526.370 1.021 45.04 45.07 -, 05 4.0530 4,051

0

,05

4 2176 0.000 570.450 .917 40.44 40.39 , 14 4.0530 4,0583 1 z -, 13

4 2177 0.000 609.31

0

.846 37.31 37. 13 ,47 4.0530 4,071

4

-,45

4 2 1 78 0.000 423. 1 50 1.766 77.89 77.84 ,07 4.5596 4,5617 -,05

4 21 79 0.000 473. 1 50 1.389 61 .27 61 .05 ,36 4. 5596 4,5733 -,30

4 2180 0.000 526.370 1.164 51.31 51 .30 ,02 4.5596 4,5604 -,02

4 2181 0.000 570.450 1 .041 45.88 45.78 ,23 4,5596 4, 5696 -,22

4 2182 0.000 423. 1 50 2.064 91.02 90.88 . 16 5.0663 5,0716 -. 1

1

4 2183 0.000 473. 1 50 1 .580 69.66 69.34 .47 5.0663 5,0856 -.38

4 2 1 84 0.000 526.370 1.309 57.72 57.67 .08 5.0663 5,0698 -.07

4 2185 0.000 570.450 1.165 51 .38 51 .24 .28 5.0663 5,0793 -.26

4 2186 0.000 609.310 1.070 47. 18 46.89 .61 5.0663 5,0957 -.58

4 2187 0.000 423, 150 2.392 105.50 105.56 -.06 5.5729 5,5707 .04

4 2188 0.000 473.150 1.777 78.36 78.01 .45 5,5729 5,5929 -.36

4 2189 0.000 526.370 1.456 64.20 64. 19 ,02 5.5729 5,5741 -.02

4 2190 0.000 570.450 1.291 56.95 56.78 ,29 5.5729 5,5879 -.27

4 2191 0.000 423. 150 2.751 121.30 122. 17 -,71 6.0795 6,0544 .41

4 2192 0,000 473. 150 1.981 87.35 87.08 ,31 6.0795 6.0942 -.24

4 2193 0.000 526.370 1.606 70.83 70.85 -,03 6.0795 6.0779 .03

4 2194 0.000 570.450 1.418 62,54 62.40 ,23 6.0795 6.0923 -.21

4 2195 0.000 609,310 1.297 57.18 56.82 ,64 6.0795 6. 1 165 -.60

4 2196 0.000 423.150 3.150 138,88 140.82 -1,37 6.5861 6.5360 .77

112
Table 7. (Continued)

Data sources and ID numbers; (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7 )Tom I i nson , (24)Ely, (26)Dittmar, (XXXX)Haynes, ( 51 ,52)Thomas, (78)Teichmann,

(79)Warowny.

ID Data

Point

No.

2197

2198

2199

2200

2201 2202

2203

2204

2205

2206

2207

2208

2209

2210

221

1

2212

2213

2214

2215

2216

2217

2218

2219

2220

2221 2222

2223

2224

2225

2226

2227

2228

2229

2230

2231 2232

2233

2234

2235

2236

2237

2238

2239

2240

2241 2242

2243

2244

2245

2246

2247

2248

2249

2250

2251 2252

We ight

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

Temp.

K

473. 150 526.370

570.450

423.150

473. 150 526.370

570.450

609.310

423.150

473.150

526.370

570.450

423.150

473. 150 526.370

570.450

609.310

423. 150 473.150

526.370

570.450

423. 150 473. 150 526.370

570.450

609.310

423. 150 473.150

526.370

570.450

423.150

473.150

526.370

570.450

609.310

423. 150 473.150

526.370

570.450

423.150

473.150

526.370

570.450

609.310

423.150

473.150

526.370

570.450

423. 150 473.150

526.370

570.450

609.310

423.150

473. 150 526.370

Density

expt

mol/L kg/m^

2.193

1.760

1.547

3.596

2.414

1.916

1.676

1.525

4.076

2.642

2.074

1.806

4.558

2.876

2.235

1.937

1.755

5.004

3.1 18 2.399

2.070

5.389

3.362

2.566

2.203

1.987

5.740

3.607

2.733

2.334

6.056

3.854

2.901

2.468

2.218

6.340

4. 100 3.068

2.601

6.589

4.347

3.234

2.735

2.448

6.815

4.591

3.400

2.869

7.017

4.834

3.563

3.001

2.676

7. 184 5.070

3.728

96.70

77.59

68.21

158.56

106.46

84.47

73.90

67.26

179.76

1 16.50

91.46

79.66

200.98

126.83

98.57

85.40

77.38

220.65

137.48

105.79

91.26

237.64

148.24

1 13. 16 97.13

87.60

253.12

159.05

120.52

102.94

267.06

169.94

127.92

108.83

97.80

279.59

180.81

135.28

1 14.71 290.57

191 .67 142.60

120.59

107.95

300.51

202.44

149.92

126.52

309.41

213.18

157.10

132.33

1 18.02

315.80

223.57

164.39

Dens i ty

calc

kg/m^

96.58

77.66

68.09

161 .20 106.50

84.62

73.84

66.91

182.37

1 16.81 91.72

79.67

203.00

127.46

98.94

85.56

77.14

222. 1

1

138.37

106.28

91.50

239.42

149.44

1 13.71 97.49

87.50

254.90

160.54

121.22

103.53

268.58

171 .54 128.77

109.59

97.94

280.60

182.32

136.33

1 15.67

291. 18 192.77

143.88

121.75

108.42

300.54

202.81

151 .39

127.83

308.89

212.42

158.81 133.89

1 18.88

316.39

221.58

166.13

Dens i ty

Diff

.

.13 -.09

. 18 -1.64

-.04

-.17

.08

.53 -1.43

-.27

-.27

-.01

-.99

-.49

-.37

-. 18 .31 -.65

-.65

-.45

-.26

-.74

-.80

-.49

-.37

.12 -.70

-.93

-.57

-.56

-.56

-.93

-.66

-.70

-. 14 -.36

-.83

-.77

-.83

-.21 -.57

-.89

-.95

-.44

-.01

-.18

-.97

-1.03

.17 .35 -1.08

-1.16

-.72

.13

.90 -1.05

^expt

MPa

6.5861

6.5861

6.5861

7.0928

7.0928

7.0928

7.0928

7.0928

7.5994

7.5994

7.5994

7.5994

8. 1060

8. 1060

8. 1060

8. 1060

8. 1060 8.6126

8.6126

8.6126

8.6126

9. 1 193

9. 1 193

9. 1 193

9. 1 193

9. 1 193 9.6259

9.6259

9.6259

9.6259

10.1325

10. 1325

10.1325

10.1325

10.1325

10.6391

10.6391

10.6391

10.6391

1 1.1458

,1458

,1458

,1458

,1458

1 1.6524

1 1.6524

1 1.6524

1 1.6524

12.1590

12.1590

12. 1590 12.1590

12. 1590 12.6656

12.6656

12.6656

1 1

,

11,

11,

11,

""^ca I c MPa

6.5924

6.5807

6.5970

7.0289

7.0907

7.0821

7.0979

7. 1281 7.5369

7.5843

7.5816

7.5984

8.0550

8.0764

8.0802

8.0929

8.1293

8.5723

8.5715

8.5796

8.5923

9.0646

9.0645

9.0817

9.0887

9. 1294 9.5644

9.5578

9.5790

9.5769

10.0731

10,0584

10.0756

10.0669

10. 1 193 10.5939

10.5673

10.5690

10.5591

1 1.1 148

1 1.0917

1 1.0593

1 1 .0490

1 1.0999

1 1.6503

1 1.6334

1 1.5530

1 1.5428

12. 1924

12. 1998 12.0419

12.0286

12.0755

12.6947

12.7791

12.5444

Pressure

Diff.

-.10

.08 -.16

.91 .03

. 15 -.07

-.50

.83 .20

.23

.01 .63

.37 .32

.16 -.29

.47

.48 .39 .24

.60 .60

.41 .34

-. 1

1

.64

.71 .49

.51 .59

.74 .56

.63 .13

.43

.68

.66 .76 .28

.49

.78 .88

.41 .02

.16

.86

.95 -.27

-.33

.97

1.08 .69 -.23

-.89

.97

113
1

Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7 )Tom I i nson , (24)Ely, (26)Dittmar , (XXXX)Haynes , ( 51 ,52 )Thomas, {78)Teichmann,

(79)Warowny,

1 n1 U uaxa We i 9

'^'^ Tsmp • Dens i ty U" M b 1 1 y

ri£i n c 1 TV/ Uciib 1 1 y P^expt p^cal c Pressui Po i nt expt C 9 1 C U 1 T T , U 1 T T . INO . fS mo 1 / L kg/

m

kg/ l^'lrd rtra Jo

i\ 4 U.UUU J /U»4!)U 3.134 138.22 1 "^Q on 1 0

1

\ ^ •OuDO 1.14

4 2254 0.000 423. 150 7.336 323.50 323.19 .10 13.1723 13. 1965 -. 18 4 2255 0.000 473.150 5.299 233.66 230.30 1.46 13. 1723 13.3747 -1.51

4 2256 0.000 526.370 3.890 171.52 173.32 -1 .04 13. 1723 13.0446 .98

4 2257 0.000 570.450 3.266 144.04 145.88 -1.26 13. 1723 13.0157 1.20

4 2258 0.000 609.310 2.903 128.03 129.27 -.96 13.1723 13.0506 .93

4 2259 0.000 423. 150 7.468 329.32 329.39 -.02 13.6789 13.6728 .04

4 2260 0.000 473. 150 5.518 243.35 238.59 1.99 13.6789 13.9819 -2.17

4 2261 0.000 526.370 4.054 178.75 180.36 -.89 13.6789 13.5619 .86

4 2262 0.000 570.450 3.398 149.84 151 .78 -1 .28 13.6789 13.51 17 1.24

4 2263 0.000 423.150 7.585 334.47 335.08 -.18 14. 1855 14. 1286 .40

4 2264 0.000 609.310 3,127 137.88 139.53 -1.18 14. 1855 14.0217 1.17

114
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7)Tom I i nson , (24)Ely, (26)Dlttmar, (XXXX)Haynes, ( 51 , 52) Thomas, (78)Teichmann,

(79)Warowny.

ID Data Weight Temp. Dens i ty Dens i ty Dens i ty V n "i" v>A|J 1 p . Pressor

Point expt cal c Diff

.

Diff.

No. K mol/L kg/m-^ kg/m-' % MPa MPa %

79 2265 0.000 373.150 3.851 169.83 178.91 -5.07 4.4549 4.4352 .44

79 2266 0.000 373.150 2.457 108.34 108.45 -.10 4.0431 4.0417 .03 79 2267 0.000 373. 150 1.566 69.07 68.85 .31 3.2664 3.2724 -. 18 79 2268 0.000 373. 150 1.000 44.09 44.05 .09 2.4176 2.4191 -.06

79 2269 0.000 373.150 .638 28. 13 28. 16 -.11 1.691

1

1 .6895 .10

79 2270 0.000 373. 150 .407 17.93 17.97 -.23 1. 1423 1. 1400 .20 79 2271 0.000 373. 150 .259 1 1.43 1 1.47 -.28 .7553 .7533 .26

79 2272 0.000 373. 150 . 165 7.28 7.31 -.30 .4923 .4909 .28 79 2273 0.000 373. 150 .105 4.65 4.66 -.30 .3188 .3179 .29

79 2274 0.000 393. 190 3.405 150. 13 150.66 -.35 5.3854 5.3788 .12 79 2275 0.000 393. 190 2.446 107.86 107.69 .16 4.6967 4.7002 -.07

79 2276 0.000 393.190 1.756 77.43 77.24 .25 3.9155 3.9214 -.15

79 2277 0.000 393. 190 1 .261 55.62 55.57 .08 3. 1362 3. 1381 -.06

79 2278 0.000 393. 190 .906 39.96 40.00 -. 1

1

2.4358 2.4337 .09 79 2279 0.000 393.190 .651 28.70 28.77 -.24 1.8496 1.8458 .21 79 2280 0.000 393. 190 .467 20.60 20.67 -.32 1.3820 1.3780 .29 79 2281 0.000 393.190 .335 14.79 14.84 -.35 1.0207 1.0174 .32 79 2282 0.000 393.190 .241 10.62 10.66 -.36 .7477 .7451 .34 79 2283 0.000 407.500 3.749 165.34 169. 19 -2.27 6.4103 6.3445 1.04 79 2284 0.000 407.500 2.651 1 16.89 1 16.78 .10 5.3802 5.3830 -.05

79 2285 0.000 407.500 1.903 83.92 83.73 .23 4.4409 4.4473 -.14

79 2286 0.000 407.500 1.367 60.29 60.24 .08 3.5410 3.5431 -.06

79 2287 0.000 407.500 .982 43.32 43.38 -.13 2.7448 2.7420 .10 79 2288 0.000 407.500 .706 31.12 31 .21 -.28 2.0825 2.0775 .24 79 2289 0.000 407.500 .507 22.35 22.43 -.36 1.5552 1.5502 .32

79 2290 0.000 407.500 .364 16.04 16. 10 -.39 1. 1480 1.1438 .36 79 2291 0.000 407.500 .261 11. 51 1 1.56 -.39 .8404 .8373 .37

79 2292 0.000 407.430 2.812 124.01 123.69 .26 5.5377 5.5449 -.13

79 2293 0.000 407.430 1.791 78.97 78.54 .55 4.2594 4.2747 -.36

79 2294 0.000 407.430 1.140 50.28 50. 17 .22 3.081

1

3.0863 -. 17 79 2295 0.000 407.430 .726 32.02 32.05 -.10 2.1303 2.1285 .09 79 2296 0.000 407.430 .462 20.39 20.44 -.27 1.4294 1 .4259 .24 79 2297 0.000 407.430 .294 12.98 13.02 -.33 .9409 .9380 .31 79 2298 0.000 407.430 .187 8.26 8.29 -.34 .61 18 .6098 .33 79 2299 0.000 422.970 2.742 120.92 120.64 .24 6.0287 6.0369 -.14

79 2300 0.000 422.970 1 .969 86.84 86.42 .49 4.8951 4.91 13 -.33

79 2301 0.000 422.970 1.414 62.36 62. 15 .33 3.8646 3.8744 -.25

79 2302 0.000 422.970 1.016 44.79 44.76 .07 2.9772 2.9789 -.06

79 2303 0.000 422.970 .729 32. 17 32.21 -.14 2.2502 2.2474 .13 79 2304 0.000 422.970 .524 23.10 23. 16 -.27 1.6766 1.6725 .25

79 2305 0.000 422.970 .376 16.59 16.65 -.34 1.2364 1.2325 .32

79 2306 0.000 422.970 .270 1 1.91 1 1.96 -.36 .9051 .9020 .35

79 2307 0.000 422.970 .194 8.55 8.58 -.36 .6588 .6565 .35 79 2308 0.000 423.020 1.613 71.14 70.69 .64 4.2539 4.2735 -.46

79 2309 0.000 423.020 1.158 51.07 50.90 .34 3.3068 3.3157 -.27

79 2310 0.000 423.020 .832 36.67 36.65 .05 2.5168 2.5179 -.04

79 231

1

0.000 423.020 .597 26.33 26.37 -. 14 1.8850 1.8825 .13 79 2312 0.000 423.020 .429 18.90 18.94 -.25 1.3945 1.3913 .23 79 2313 0.000 423.020 .308 13.57 13.61 -.31 1.0237 1.0207 .30 79 2314 0.000 423.020 .221 9.75 9.78 -.33 .7467 .7443 .32 79 2315 0.000 423.020 .159 7.00 7.02 -.33 .5422 .5404 .32

115
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)8eattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7)Tom I i nson , (24)Ely, (26)Dittmar, (XXXX)Haynes , ( 51 ,52)Thomas, (78)Teichmann,

(79)Warowny.

ID Data Weight Temp. Density Dens i ty Dens i ty ^expt '^ca 1 c Pressui

Point expt ca 1 c Di f f

.

Di f f

.

No. K mol/L kg/m-* kg/m-' % MPa MPa at

f>

78 2316 0.000 322.972 10.456 461 .10 460.52 .12 4.0710 4.2016 -3. 1 1 78 2317 0.000 328. 168 10.452 460.92 460.35 ,13 6. 1869 6.3270 -2.22

78 2318 0.000 332.609 10.449 460.78 460.21 ,12 7.9977 8. 1433 -1 .79 78 2319 0.000 337.762 10.445 460.62 460.06 . 1 2 10,0989 10.2485 -1 .46

78 2320 0.000 342.618 1 0.442 460.47 459.94 . 1

1

1 2.0814 12.2303 -1 .22

78 232 i 0.000 347. 144 10.439 460.33 459.82 , 1 1 13,9231 14.0747 -1 .08 78 2322 0.000 352.944 1 0.435 460. 15 459.66 . 1 1 16.2821 16.4344 -.93

78 2323 0.000 363. 122 10.428 459.84 459.40 .09 20.41 50 20.5634 -.72

78 2324 0.000 372.349 1 0.422 459.56 459. 1

5

,09 24. 1420 24.2915 -.62

78 2325 0.000 382.692 10.41

5

459.25 458.86 .09 28.2987 28.4532 -.54

78 2326 0.000 393.048 1 0.408 458.94 458.55 .09 32.434

1

32.5981 -.50

78 2327 0.000 403. 1 68 10.401 458.64 458.24 .09 36.4506 36.6286 -.49

78 2328 0.000 4 1 4.877 10.393 458.30 457.87 ,09 4 1 .0620 4 1 ,2645 -.49

78 2329 0.000 428.006 10.384 457.91 457.73 ,04 46,3353 46,4240 -. 19 78 2330 0.000 446. 1 59 10.372 457.38 456.82 . 12 53. 1897 53,4955 -.57

78 2331 0.000 465,974 10.359 456.79 456.36 , 1

0

60.8626 61 . 1220 -.42

78 2332 0.000 327.800 10.298 454. 1

1

453.27 . 19 4.4479 4.6246 -3,82

78 2333 0.000 337.927 10.291 453.79 452.95 . 18 8.3701 8.5693 -2.32

78 2334 0.000 345.864 10.285 453.54 452.74 . 18 1 1 ,4481 1 1 .6574 -1 .80 78 2335 0.000 355. 196 10.279 453.26 452.50 .17 15,0664 15.2826 -1 .42

78 2336 0.000 367,383 10.270 452.90 452.20 . 15 19,7797 20,0013 -1.11

78 2337 0.000 375.052 10.265 452.67 452.00 .15 22,7350 22,9607 -.98

78 2338 0.000 384.818 10.259 452.39 45 1 .74 . 14 26.4836 26.7158 -.87

78 2339 0.000 394.641 10.252 452, 10 451 .47 .14 30.2325 30.4770 -.80

78 2340 0.000 402.913 10.247 451 .86 451 .23 . 14 33.3753 33.6306 -.76

78 2341 0.000 416.717 10.238 451 .46 450.82 .14 38.5825 38.8657 -.73

78 2342 0.000 432.648 10.227 451 .00 450.32 . 15 44.5345 44.8589 -.72

78 2343 0.000 453.599 10.214 450.40 449.63 .17 52.2548 52.6584 -.77

78 2344 0.000 472,842 10.201 449.84 448.96 .20 59.2384 59.7383 -.84

78 2345 0.000 330.263 9.973 439.77 438.99 .18 2.7707 2.8935 -4.25

78 2346 0.000 341.713 9.965 439,41 438.55 .20 6.7553 6.9167 -2.33

78 2347 0.000 352.841 9,957 439.09 438.25 .19 10.6530 10.8328 -1 .66 78 2348 0.000 363.696 9.950 438.77 438.01 . 18 14.4640 14.6504 -1.27

78 2349 0.000 377.648 9.941 438.38 437.69 .16 19.3554 19.5471 -.98

78 2350 0.000 397,297 9.929 437.83 437,21 .14 26.21 15 26.4104 -.75

78 2351 0.000 412.796 9.919 437.40 436,81 .13 31 .5790 31 .7896 -.66

78 2352 0.000 431.026 9.907 436.89 436,30 .14 37.8361 38.0707 -.62

78 2353 0.000 448.440 9.897 436.41 435,79 .14 43.7474 44.0194 -.62

78 2354 0.000 463.694 9.887 435.99 435.32 . 16 48.8692 49. 1862 -.64

78 2355 0.000 480.702 9.876 435,52 434,77 . 17 54. 5166 54.8963 -.69

78 2356 0.000 496.299 9.867 435.09 434.25 . 19 59.6332 60.0842 -.75

78 2357 0.000 330.963 9.940 438.33 437.52 .18 2.7872 2.9129 -4.31

78 2358 0.000 331 .814 9.939 438.30 437.49 . 18 3.0816 3.2087 -3.96

78 2359 0.000 336.848 9.936 438. 14 437,29 . 19 4.8 135 4.9583 -2.92

78 2360 0.000 34 1 .988 9.932 437.99 437. 12 ,20 6.5880 6.7472 -2.36

78 2361 0.000 347.723 9.928 437.82 436.95 .20 8.5731 8,7450 -1 .97 78 2362 0.000 355.121 9.924 437.60 436.77 .19 1 1. 1422 1 1.3224 -1.59

78 2363 0.000 368.842 9.915 437.21 436.46 .17 15.91 17 16.0991 -1.16

78 2364 0.000 383.023 9.906 436.81 436.14 .15 20.8327 21.0224 -.90

78 2365 0.000 402.762 9.893 436.27 435.66 .14 27,6429 27.8412 -.71 78 2366 0.000 422.783 9.881 435.71 435.14 .13 34.4894 34.7048 -.62

78 2367 0.000 443.127 9.868 435.15 . 434.56 .14 41 .3682 41.6160 -.60

78 2368 0.000 342.839 9.231 407.08 406.41 .16 2.7845 2.8447 -2. 12 78 2369 0.000 350.822 9.226 406.86 405.98 .22 4.9609 5.0550 -1 .86 78 2370 0.000 361.070 9.220 406.59 405.67 .23 7.7955 7.9133 -1.49

78 2371 0.000 369. 188 9.215 406.37 405.51 .21 10.0616 10. 1875 -1.24

116
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Rearner,

(13)Cherney, ( 17 )Tom I i nson , (24)Ely, (26)Dittmar, (XXXX)Haynes, (51 , 52) Thomas, ( 78 )Te ichmann

,

(79)Warowny.

1 D Data We i g ht Temp, Dens i ty Dens i ty Dens i ty ^expt p"ca 1 c Pr essur

Po i nt expt ca 1 c Di f f

.

Di f f

.

No. K rtD l/L kg/m kg/m-^ a MPa MPa

78 2372 0.000 376.679 9.21

1

406. 1

8

405,37 .20 12. 1606 1 2.2905 -1 .06

78 2373 0.000 386. 501 Q 9ns 4ns Q"^ 405,20 .18 14,9208 15.0510 -.87

7R 2374 0.000 407. 554 Q 1 Q'^ 4ns 4n 404.84 .14 20,8432 20.9555 -.58

7ft 7375 0 000 432. 150 Q 1 7Q 4n4 7R 404.35 . 1

1

27,7374 27.8505 -.41

7R 2376 0. 000 457.260 Qy 1 fiS m \\J J 4n4 1 s 403.79 .09 34 , 7087 34.8212 - 39

7ft 0.000 481 .93

1

Q 1 SI hUJ . -) J 403. 19 .09 4 1 ,4846 4 1 . 5072 - ?Q

7ft 51 1 .431 Qy 1 • \ DH 4n7 Rn 402,42 • 09\jy 49,4692 49.5225 - "^1 7R n nnn 54R 961 y* % \ 4n 1 Rft 4ni "^7 1 9 SQ 4 1 R4 SQ ftsns _ • 7R n nnn 354 671 R Sfi9 ^7 7 Sfi / / . JD S7fi fi9 9S fi4ni _j . fionR L> yKj<D 7R 9'^R 1 n nnn R SS7 ^77 ^d ^7fi ns ^4 S 74 ^ S -1 7R n nnn 376.625 R ssn "^77 n'^ 375, 73 35 8.5296 ft fi4RQ _ 1

1 • 7R n nnn ^Q? ft"^R R SA9 _) / D . 00 ^7S S"^ • D\) 191 z . 9'^9n z_^zu 1 Z . _?OH O - 1 07

7ft 9'^ft4 n nnn dnQ ?nn O . P Jj) ZTC 9Q J / 0

.

s , 9SZ J 1 S C)Q7Q 1 Jmyyiy 1

1 O. MIS i J \ J - • o_? 7R Z.9'^ftS JO J n nnn H-'Z . ^ R S9

1

'^7S 7/1

-J 1 J •KJ 1 1 ft • 1 o 91 '^9.11 Z 1 . -^O / / 91 Sin''; _ cr-t • J 1 7ft / o n nnn H 1 . UvJ 1 R S 1 1 "^7 S 1 ^74 77 1 4 9SZ J . 7RR7 / oo

/

9s onin - ^."^ • 7R n nnn 472.31

1

R snn ^74 R4 374 ,4

1

1 1 , 1 1 "^n SIRS ^n ft99ft uzzu _ T/l 7R 73ft8 n nnn 497.096 ft AR7 "^74 97 y^ nQ "^fi 1 S1Q J^fio . z.94ftfi *T ou _ 97

7R 7"^RQ 0 nnn 52 1 . 1 48 R d7S '^T'^ 7"^ ^7"^ 49 , nR*_/o 41 Sfin4 4 1 fiSft'^ 78 2390 0.000 546. 1 98 RQ . 4fi9 t UZ 372.86 nR 47 19Q7 47 9'^ns - 9 1 78 2391 0.000 570.278 8.450 372.61 372.30 ,08 52.4 1 34 52. 5324

78 2392 0.000 364.812 7.541 332. 52 331 .63 ,27 4.0534 4.0800 -.4

1

78 2393 0.000 376.448 7. 535 332 .28 330. 1

5

.65 5.9058 5. 9747 -1.15

78 2394 0.000 392.791 7.528 331 .95 329.97 .60 8,5004 8.7020 -1.17

78 2395 0.000 412.648 7.519 331 . 56 330.09 ,45 1 1 .9520 12.051

9

-.91

78 2396 0.000 432.534 7.510 33 1 . 16 330. 15 .31 1 5.3480 1 5.4477 -.55

78 2397 0.000 452.553 7. 501 330.77 330. 1

1

.20 18.7801 18.8508 -.43

78 2398 0.000 473.034 7.492 330.37 329.98 .12 22.2902 22.3457 -.25

78 2399 0.000 492.234 7.483 329.99 329.80 .06 25. 5709 25.6024 -. 12 78 2400 0.000 51 2.405 7.474 329.60 329.57 .01 29.0010 29.0057 -.02

78 2401 0.000 530.760 7.466 329. 24 329.34 -.03 32. 1055 32,0843 .07 78 2402 0.000 550. 128 7.458 328.86 329.06 -.06 35.3592 35.3 1 19 . 13 78 2403 0.000 569. 593 7.449 328.48 328.77 -.09 38.6055 38.5319 , 19 78 2404 0.000 369.350 6.587 290.47 287.83 .91 4,2500 4,27 17 -.27

78 2405 0.000 378. 140 6. 584 290,32 284.88 1 .91 5.2858 5,3462 -1.13

78 2406 0.000 393.489 6. 578 290. 05 285.70 1.52 7. 1701 7,2734 -1 .42

78 2407 0.000 413.546 6 57n 289,71 286.74 1 ,04 9.7096 9,8312 -1 .24

78 2408 0.000 432. 1 29 U. J\JJ 9RQ 4n 287.32 .72 12,0990 12,2175 -.97

78 2409 0.000 452.677 9fiQ zo y •\JnsJ 987 6R .48 1 4,7586 14.8615 -.69

78 24 1

0

0.000 473. 033 Sd7 9Rfl 7

1

zoo . /

1

287.84 ,30 17,3975 17.4781 -.45

78 241

1

0.000 491 .232 ft sdn 9RR ZO O . 4nH VJ 287.89 , 18 1 9.7553 19.8108 -.28

78 24 1

2

0.000 51 0.749 ZOO 9RR »\jn71 287.86 ,07 22,2751 22.3024 -. 12 78 24 13 0.000 530.884 fi S9S Z.O 79,11 • 741 H 28 7 . 78 -,02 24,8659 24.8595 .03

78 24 1

4

0.000 550.233 6.518 287.41 287.66 -. 09 27,3423 27 .3020 . 1

5

78 2415 0.000 570.645 6.510 287.07 287.49 -. 1 5 29.9378 29.8617 .25

78 2416 0.000 373.371 6.002 264.69 255.53 3.59 4.5957 4.6220 -.57

78 2417 0.000 384.040 5.997 264.45 257. 17 2.83 5.6751 5.7453 -1.22

78 2418 0.000 393. 158 5.992 264.25 258.51 2.22 5.6267 6.7173 -1.35

78 2419 0.000 412.539 5.984 263.88 260.23 1.40 8.6919 8.7995 -1.22

78 2420 0.000 432.549 5.976 263.53 261.18 .90 10.8549 10.9587 -.95

78 2421 0.000 451.584 5.969 263.22 261.69 .59 12.9243 13.0137 -.69

78 2422 0.000 472.918 5.961 262,88 261 .99 .34 15,2462 15.3121 -.43

78 2423 0.000 492.382 5.953 262,49 262. 14 ,13 17.3626 17,3940 -.18

78 2424 0.000 51 1.062 5.948 262,30 262.18 ,05 19.3858 19,3994 -.07

78 2425 0.000 530.956 5.941 261.97 262.18 -.08 21.5355 21,51 19 .11 78 2426 0.000 550.999 5.934 261 .66 262.1

1

-.17 23.6887 23.5292 .25

78 2427 0.000 573.416 5.926 261,31 262.00 -.26 25.0839 25.9808 .40

117
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7)Tom I i nson , (24)Ely, (26)Dittmar, ( XXXX)Haynes , ( 51 ,52)Thomas, (78)Teichrnann,

(79)Warowny.

ID Data We Ight Temp. Dens i ty Dens i ty Dens i ty pexpt pca 1 c Pressure

Point expt ca 1 c DiffDiff.

No. K mol/L kg/m-^ kg/m-' % MPa MPa %

78 2428 0.000 378.257 5.014 221.09 214.26 3. 19 4.9067 4.9317 -.51

78 2429 0.000 387.620 5.010 220.92 215.93 2.51 5.6512 5.6926 -.73

78 2430 0.000 397.884 5.006 220.73 216.97 1.74 6.4733 6.5245 -.79

78 2431 0.000 412.591 5.000 220.50 217.90 1.19 7.6571 7.7131 -.73

78 2432 0.000 432.441 4.994 220.20 218.63 .72 9.2588 9.3099 -.55

78 2433 0.000 451 .915 4.987 219.93 219.04 .41 10.8290 10.8680 -.36

78 2434 0.000 472.446 4.981 219.66 219.29 .17 12.4804 12.5009 -.16

78 2435 0.000 492.229 4.975 219.40 219.43 -.01 14,0664 14.0642 .02 78 2436 0.000 51 1.521 4.970 219.15 219.48 -.15 15.6053 15.5790 .17

78 2437 0.000 530.931 4.964 218.90 219.49 -.27 17. 1466 17.0930 .31 78 2438 0.000 550.497 4.958 218.64 219.46 -.37 18.6917 18.6090 .44

78 2439 0.000 572.459 4.952 218.36 219.38 -.47 20.4148 20.2977 .58 78 2440 0.000 372.414 3.733 164.60 164.21 .24 4.3777 4.3787 -.02

78 2441 0.000 383. 158 3.729 164.46 163.52 .57 4.9839 4.9904 -. 13 78 2442 0.000 393.257 3.727 164.33 163.39 .58 5.5395 5.5501 -.19

78 2443 0.000 412.606 3.721 164,08 163.37 .44 6.5841 6.5979 -.21

78 2444 0.000 432.037 3.716 163.86 163.43 .26 7.6162 7.6282 -.16

78 2445 0.000 452.165 3.71 1 163.64 163.48 .10 8.6722 8.6783 -.07

78 2446 0.000 472.712 3.706 163.43 163.50 -.04 9.7389 9.7355 .03

78 2447 0.000 492.367 3.702 163.23 163.50 -. 17 10.7498 10.7350 .14 78 2448 0.000 51 1.981 3.697 163.04 163.48 -.27 1 1 .7501 1 1 .7223 .24

78 2449 0.000 531 .510 3.693 162.85 163.44 -.36 12.7383 12.6961 .33 78 2450 0.000 551.623 3.689 162.66 163.38 -.45 13.7487 13.6902 .43

78 2451 0.000 569.383 3.685 162.49 163.33 -.52 14.6348 14.5605 .51 78 24 52 0.000 383. 172 2.474 109. 1

108.37 .69 4.3809 4.3932 -.28

78 2453 0.000 393.351 2.472 109.03 108.10 .86 4.7103 4.7294 -.40

78 2454 0.000 403.287 2.471 108.95 107,85 1.02 5.0237 5.0504 -.53

78 2455 0.000 413.008 2.469 108.87 107.75 1.03 5.3277 5.3590 -.58

78 2456 0.000 432.821 2.465 108.71 107.67 .96 5.9379 5.9745 -.61

78 2457 0.000 452.480 2.462 108.55 107.62 ,86 6.5319 6.5712 -.60

78 2458 0.000 472.835 2.458 108.39 107.59 .74 7.1382 7. 1778 -.55

78 2459 0.000 492.354 2.455 108.25 107.57 .64 7.71 19 7.7506 -,50

78 2460 0.000 512.363 2.452 108.11 107.54 .54 8.2936 8.3302 -,44

78 2461 0.000 532.459 2.449 107.98 107.50 .44 8.8719 8.9056 -.38

78 2462 0.000 551.517 2.446 107.85 107.46 .36 9.4157 9.4454 -.31

78 2463 0.000 570.948 2.443 107.72 107.42 .28 9.9653 9.9908 -.26

118
Table 7. (Continued)

Data sources and ID numbers: (l)Vlrial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 17)Toml inson, (24)Ely, (26)0ittmar, (XXXX)Haynes, ( 51 ,52)Thoma5, ( 78 )Te ichmann , (79)Warowny.

1 D Data we 1 gnt Temp

.

Dens i ty Dens i ty Dens i ty ^expt '^ca 1 c Pressu

Po i nt expt ca 1 c U 1 T T o U 1 r t . No

.

w

l\ mo 1 /L 1 / 3 kg/m-' kg/m'^ % Mra MPa %

52 z4d4 1 AAA 1 . UUU joy .oDU .800 35.28 T C OT A T .U J

O AA"7A z. UU /y o A A oyl Z.UUo4 A X -.03

CO 1 AAA 1 .UUU J / J . 1 DU .800 35.28 c o~j A X • U J

O AT CA Z.U j5U O AT CC Z. AT -. U3

KO 1 AAA 1 . UUU jyo • 1 pu .800 35.28 X R OA A C .UD z. zjoy z. Zj /y A^ -.U4

CO z4d /

1 AAA 1 .UUU ^ O X 1 RA 4Zj. 1 3U .800 35.28 c o^; J J. Ct) Ayi .U4 o /» T C C O A XCX Z.4303 AT -. U3

CO z4do 1 AAA 1 • UUU A A Q 1 RA 440. 1 3U .800 35.28 AT • Uj O eiX \ A Z.Oj 14 Z.OjZU -. AOuz

CO z4Dy 1 AAA 1 . UUU 4 /_) . 1 5U .800 35.28 -. A A UU O QO C"7 Z. oZ 5 / O QO C^ Z.oZ 5o A A .uu

CO Z4 /U A AAA U.UUU T^TQ OCA joy .03U .800 35.28 X C 0"7 A"? .Uj O AA"7Q z.uu /y O AAQyl Z.UUo4 -. ATU J CO O/I "7 1 ^:4 /

1

A AAA U. UUU ^"7T 1 c;A J / J . 1 5U .800 35.28 XC O"? -55. Z. 1 AT .Uj O AT CA Z. UjI3U O AT CC Z. UjD5 -. ATU3

CO52 A AAA U.UUU 70Q 1 CA 3yo . 1 DU .800 35.28 T C O^^ 35. ZD A C .U5 o o T^^n Z.Z3Dy O O T"7n A A -.U4

CO52 Z4 / JA AAA U.UUU yl OT 1 c: A 4yc3. 1 5U .800 35.28 TC O^^ A A .U4 O AX Cyl Z.4354 O y1 T i^T Z. 43d3 Ad -. U4

52 2474 0.000 A A O 1 CA 44o. 1 5U .800 35.28 V c 0"7 AO .02 2.53 1

5

O £ T OA 2.5320 -.02

52 2475 0.000 473 . 1 50 .800 35.28 35. 28 -. 01 2.82 58 2.8256 .01 52 2476 1 .000 498. 1 50 .800 35.28 35.29 -.02 3,0182 3.0 176 .02

52 2477 1 .000 523. 1 50 .800 35.28 35.29 -.04 3.2096 3. 2083 .04

52 2478 1 .000 548. 1 50 .800 35.28 35.30 -.06 3.3998 3.3980 .05

52 2479 1 .000 573. 1 50 .800 35.28 35.30 -.08 3.5894 3.5868 .07 52 2480 1 .000 598. 1 50 .800 35.28 35.31 -. 1

0

3.7783 3.7748 .09 52 2481 1 .000 623. 1 50 .800 35.28 35.32 -. 1

2

3.9657 3.9621 . 1

2

52 2482 0.000 498. 1 50 .800 35.28 35.29 -.02 3.0183 3.0176 .02

52 2483 0.000 523. 1 50 .800 35.28 35.29 -.04 3.2095 3.2083 .04 52 2484 0.000 548. 1 50 .800 35.28 35.30 -.06 3.4001 3.3980 .06

52 2485 0.000 573 . 1 50 .800 35.28 35.31 -.08 3.5894 3.5868 .07

52 2486 0.000 598. 1 50 .800 35.28 35.31 -.10 3.7784 3.7748 . 10 52 2487 0.000 623. 1 50 .800 35.28 35.33 -. 1 5 3.9579 3.962

1

. 1

5

52 2488 1 .000 359.850 1.000 44. 10 44.02 . 18 2.3808 2.5840 -.13

52 2489 1 .000 373. 1 50 1.000 44. 10 44.01 .19 2.4161 2.4195 !4 52 2490 1 .000 398. 1 50 1.000 44.10 43.99 .23 2.5793 2.6843 1

9

52 2491 1 .000 423. 1 50 1 .000 44. 10 44.00 .23 2.9371 2.9427 -. 19 52 2492 1 .000 A A ci 1 cr\ 448. 1 50 1 .000 44. 10 44.00 .21 3. 1 908 3. 1955 -. 18

C O 2493 1 .000 473. 1 50 1 .000 44. 10 44 .02 . 1

8

3.44 1

9

3.4472 -. 16 CO z4y4 1 AAA 1 .UUU A no 1 CA 4yo. 1 50 1 .000 44. 10 44.03 1 c

. 1 5

T ^ AA T 3.5903 T A CT 3.6953 1 T -. 1

3

CO 2495 1 AAA 1 .000 COT 1 CA 523. 1 50 1 .000 44. 10 44 .05 . 1 1 3.9372 3.94 1

3

-.10

CO ^490 1 AAA 1 .000 Cyl o 1 c

A

54o. 1 50 1.000 44. 10 A A A "7 44.07 A 1 .07 A 1 O OA 4. 1 829 4. 1857 -.07

CO z4y /

1 AAA 1 .000 C T T 1 C A 5/3. 150 1 .000 44.10 44.07 .05 4. 4265 4.4287 -.05

CO ^4yo 1 AAA 1 .UUU CAO 1 CA 59o. 1 50 1 .000 44. 10 44. 09 AO .Uz 4.5695 A C ~tf\C 4.5 /Oo A O -. 02

CO52 2499 1 .000 623. 1 50 1.000 44. 10 44.10 -.00 4.91 16 4.91 14 .00

CO 2500 1 .000 369.850 1.500 66. 15 65.84 .47 3.1210 3. 1 295 -.28

CO O CA 1 2501 1 .000 373. 1 50 1 .500 66. 15 65.81 .51 3. 1795 3 . 1 8 92 -.30

CO 1 AAA 1 . UUU tCtO 1 CA 1.500 66. 1 5

C C ~7T 55. 73 £i O .62 T C 1 T O 3.51 32 T C O O "7 3.528 7A T -.43

CO O C AT 2503 1 AAA 1 .000 A^t 1 cr\ 423. 1 50 1.500 66. 15 65.74 ilO .62 4.0344 A AC OA 4.0529 A C -.45

CO 2504 1 .000 A A Q 1 C A 448. 1 50 1.500 66. 15 65.77 .57 4.4470 4.4670 -.45

CO52 2505 1 .000 473. 1 50 1.500 66.15 65.82 .50 4.8537 4.8738 -.41

52 2506 1 .000 498. 1 50 1.500 66. 15 55.86 .43 5.2557 5.2751 -.37

52 2507 1 .000 523. 1 50 1.500 66.15 65.90 .37 5.6538 5.6721 -.32

52 2508 1.000 548. 150 1.500 66. 15 65.95 .29 6.0496 6.0656 -.25

52 2509 1.000 573.150 1.500 66.15 65.98 .24 6.4416 5.4561 -.22

52 2510 1.000 598.150 1.500 66. 15 66.02 .19 6.8318 5.8442 -.18

52 2511 1.000 623.150 1.500 66. 15 65.07 .12 7.2222 7.2302

52 2512 1.000 369.850 2.000 88. 19 87.72 .54 3.6258 3.5344 -.24

52 2513 1.000 373.150 2.000 88. 19 87.66 .60 3.7111 3.7215 -.28

52 2514 1.000 398. 150 2.000 88. 19 87.50 .79 4.3375 4.3574 -.46

52 2515 1.000 423.150 2.000 88.19 87.54 .74 4.9421 4.9667 -.49

52 2516 1.000 448.150 2.000 88.19 87.50 .58 5.5318 5.5591 -.49

52 2517 1.000 473.150 2.000 88.19 87.58 .58 5.1120 6.1399 -.45

52 2518 1.000 498.150 2.000 88.19 87.78 .47 6.6860 6.71 18 -.38

52 2519 1.000 523.150 2.000 88.19 87.87 .37 7.2538 7.2768 -.32

I

119
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 1 7)Tom I i nson , (24)Ely, {26)Dittmar, (XXXX)Haynes, ( 51 , 52 )Tiiomas, ( 78)Te ichmann

,

(79)Warowny.

ID Data We ight Temp. Dens i ty Density Dens i ty ^expt ^ca 1 c Pressu

Point expt caic Diff. Diff.

No, K mo!/L kg/m-^ kg/m^ i MPa MPa %

52 2520 1.000 548.150 2,000 88'. 19 87.94 .28 7.8167 7.8363 -.25

52 2521 1.000 573. 150 2.000 88. 19 88.02 .19 8.3764 8.391

1

-.18

52 2522 1.000 598.150 2.000 88. 19 88.08 .13 8.9310 8.9421 -,12

52 2523 1.000 623. 150 2.000 88. 19 88.15 .05 9.4853 9.4896 -,05

52 2524 1.000 369,850 2.500 1 10.24 109.87 .34 3.9444 3.9484 -.10

52 2525 1.000 373, 150 2.500 1 10,24 109.73 .47 4.0591 4.0653 -.15

52 2526 1.000 398. 150 2o500 1 10,24 109.44 .73 4.8954 4.9130 -.36

52 2527 1.000 423. 150 2,500 1 10,24 109.52 .66 5.6994 5.7220 -.39

52 2528 1.000 448,150 2.500 110.24 109.65 .54 6.4842 6.5083 -.37

52 2529 uooo 473,150 2,500 1 10,24 109,79 .41 7,2567 7.2789 -.31

52 2530 1.000 498.150 2.500 1 10.24 109.93 .28 8.0199 8,0378 -.22

52 2531 1.000 523. 150 2,500 1 10.24 1 10.05 .17 8.7750 8.7877 -.14

52 2532 1.000 548.150 2,500 110.24 1 10.17 .06 9.5247 9.5301 -.06

52 2533 1.000 573.150 2.500 1 10.24 1 10.27 -.03 10.2688 10.2663 .02

52 2534 1.000 598.150 2.500 110.24 1 10.36 -.11 1 1.0080 10.9972 .10

52 2535 1 .000 623.150 2.500 1 10.24 1 10.46 -. 19 1 1 .7452 11.7235 .18 52 2 536 1,000 369.850 3.000 132.29 132.30 -.01 4.1240 4.1240 .00

52 2537 1.000 373. 150 3.000 132.29 132.03 .20 4,2701 4.2720 -.04

52 2538 1.000 398.150 3.000 132.29 131.60 .53 5,3284 5.3404 -.22

52 2539 1 .000 423.150 3,000 132.29 131.73 .42 6.3461 6.361

1

-.24

52 2540 1.000 448,150 3,000 132.29 131.92 .28 7.3417 7.3554 -.19

52 2541 1.000 473, 150 3,000 132,29 132.10 .15 8.3227 8.3317 -.11

52 2542 1,000 498.150 3,000 132.29 132.29 -.00 9.2945 9.2945 .00

52 2543 1 oOOO 523.150 3,000 132,29 132,45 -.12 10.2570 10.2466 .10

52 2544 1,000 548.150 3,000 132,29 132.60 -.23 1 1.2133 1 1. 1901 .21 52 2545 1.000 573.150 3,000 132.29 132,72 -.32 12, 1623 12. 1262 .30

52 2546 1.000 598. 150 3,000 132.29 132,80 -.38 13.1034 13.0558 .36

52 2547 1,000 623.150 3,000 132,29 132,94 -.49 14.0474 13.9798 ,48

52 2548 1,000 369.850 3.500 154,34 154,88 -.35 4,2097 4.2084 .03

52 2549 1.000 373.150 3,500 154,34 154,34 ,00 4.3878 4.3878 -.00

52 2550 1.000 398.150 3.500 154,34 153.78 .37 5.6739 5.6819 -.14

52 2551 1,000 423. 150 3.500 154,34 153,99 .23 6.9174 6.9260 -, 12 52 2552 1,000 448.150 3,500 154.34 154,25 .06 8.1404 8.1434 -,04

52 2553 1.000 473. 150 3.500 154.34 154,49 -.10 9.3497 9.3427 .07

52 2554 1 ,000 498. 150 3.500 154.34 154.69 -.23 10.5481 10.5282 .19 52 2555 1,000 523.150 3.500 154.34 154,89 -.35 1 1.7390 1 1.7026 .31 52 2556 1,000 548, 150 3.500 154o34 155,07 -,47 12.9239 12.8676 .44

52 2557 1.000 573.150 3.500 154.34 155,20 -.55 14. 1002 14.0245 .54

52 2558 1.000 598.150 3.500 154.34 155,33 -.63 15.2713 15. 1742 .64 52 2559 1.000 623.150 3.500 154,34 155.47 -.73 16.441

1

16.3175 .76 52 2560 1.000 369.850 4.000 176.39 177.04 -.37 4.2404 4.2400 .01 52 2561 1.000 373.150 4.000 176,39 175.89 .28 4.4488 4.4499 -.02

52 2562 1.000 398.150 4.000 176,39 175.57 .47 5.9642 5.9746 -.17

52 2563 1.000 423,150 4.000 176.39 176.00 ,22 7.4470 7.4564 -.13

52 2564 1.000 448. 150 4.000 176.39 176.39 -.00 8.9157 8.9156 .00

52 2565 1.000 473,150 4.000 176.39 176.78 -.22 10.3773 10.3588 .18 52 2566 1.000 498.150 4.000 176.39 176.99 -,34 1 1 .8249 11.7893 .30

52 2567 1.000 523.150 4.000 176.39 177.23 -.48 13,2688 13.2093 ,45

52 2568 1.000 548.150 4.000 176.39 177.43 -.59 14.7061 14.6201 .59

52 2569 1.000 573.150 4.000 176.39 177.59 -.68 16.1355 16.0225 .71 52 2570 1,000 598.150 4.000 176.39 177.74 -.76 17.5605 17.4173 .82

52 2571 1,000 623.150 4.000 176.39 177.89 -.84 18.9818 18.8050 .94 52 2572 1.000 369.850 4.500 198.44 195.20 1.66 4.2467 4.2470 -.01

52 2573 1.000 373.150 4.500 198.44 195.26 1.63 4.4815 4.4859 -.10

52 2574 1,000 398. 150 4.500 198.44 196.62 .93 6.2288 6.2518 -.37

52 2575 1.000 423.150 4.500 198.44 197.57 .44 7.9697 7.9914 -.27

120
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer

(13)Cherney, ( 1 7 )Tom I i nson , (24)Ely, ( 26)D i ttmar , ( XXXX)Haynes , ( 51 , 52)Thonrias , ( 78)Te ichmann , (79) Warowny.

ID Data We ight Temp. Dens ity Dens i ty Dens i ty '^expt '^ca 1 c Pressur Point expt ca 1 c Diff, Diff.

No. K - mol/L kg/tTK kg/m-' d

/» MPa MPa %

52 2576 1.000 448. 150 4.500 198.44 198. 17 ,14 9,7057 9,7 160 -.1 1 52 2577 1.000 473. 150 4.500 198.44 198.67 -.12 1 1 .4409 1 1 .4290 .10

52 2578 1.000 498 . 1 50 4.500 198.44 199.03 -.30 13. 1699 13. 1321 .29

52 2579 1.000 523. 1 50 4.500 198.44 199.31 -.44 14.8935 14.8260 ,46

52 2580 1 .000 548. 150 4.500 198.44 1 99 . 58 -.57 16.6146 16.51 14 .63

52 2581 1.000 573.150 4.500 198.44 199,77 -.67 18.3266 18.1886 .76

52 2582 1.000 598. 150 4.500 198.44 199.95 -.76 20.0345 19.8581 .89

52 2583 1.000 623. 150 4.500 198.44 200.11 -.84 21.7373 21.5199 1.01

52 2584 0.000 369.850 5.000 220.49 0.00 0.00 4.2471 4.2475 -.01

52 2585 OcOOO 373.150 5.000 220.49 212.08 3.96 4,5040 4,5152 -.25

52 2586 0.000 398 . 1 50 5.000 220.49 216.99 1.61 6,4948 6.5427 -.73

52 2587 1.000 423. 150 5.000 220.49 218.71 .81 8.5190 8.5677 -.57

52 2588 1.000 448. 150 5.000 220.49 219.69 .36 10.5551 10.5885 -.32

52 2589 1.000 473.150 5.000 220.49 220.34 .07 12.5957 12.6038 -.06

52 2590 1.000 498. 150 5.000 220.49 220.82 -. 15 14.6367 14.6128 .16

52 2591 1.000 523. 150 5.000 220.49 221.20 -.32 16.6766 16.6148 .37

52 2592 1.000 548.150 5.000 220.49 221.51 -,46 18.7128 18.6095 ,56

52 2593 1.000 573.150 5.000 220.49 221 .76 -,58 20.7449 20.5964 .72

52 2594 1.000 598.150 5.000 220.49 221.96 -,66 22.7683 22.5754 .85

52 2595 1 .000 623.150 5.000 220.49 222. 17 -,76 24.7930 24.5465 1.00

52 2596 0.000 369.850 5.500 242.53 235.74 2.88 4.2476 4.2481 -.01 52 2597 0.000 373. 150 5.500 242.53 230.75 5,1 1 4.5295 4.5479 -.40

52 2598 0.000 398 . 1 50 5.500 242.53 237.86 1.97 6.7960 6.8693 -1.07

52 2599 1.000 423. 150 5.500 242.53 240.07 1.03 9. 1393 9.2164 -.84

52 2600 1.000 448. 150 5.500 242.53 241.26 .53 11.51 15 1 1.5721 -.52

52 2601 1.000 473. 150 5.500 242.53 242.05 .20 13.8985 13.9296 -.22

52 2602 1.000 498. 150 5.500 242.53 242.61 -.03 16.2915 16.2850 .04

52 2603 1.000 523. 150 5.500 242.53 243.04 -.21 18.6861 18.6361 .27

52 2604 1.000 548. 150 5.500 242.53 243.40 -.35 21 .0802 20.981

1

.47

52 2605 1.000 573. 150 5.500 242.53 243.67 -.47 23.4690 23.3188 .64

52 2606 1.000 598. 150 5.500 242.53 243.89 -.56 25.8510 25.6486 .79 52 2607 1 .000 623. 150 5.500 242.53 244.1

1

-.65 28.2330 27.9699 .94

52 2608 0.000 369.850 6.000 264 . 58 261 .67 1.11 4.2564 4.2593 -.07

52 2609 0.000 373. 150 6.000 264.58 255.97 3,36 4.5749 4.5986 -.52

52 2610 0.000 398.150 6.000 264 . 58 259.96 1,78 7. 1710 7.2507 -1 .23

52 261

1

1.000 423. 150 6.000 264.58 262.06 ,96 9.8831 9.9777 -.95

52 2612 1.000 448. 150 6.000 264.58 263.26 .50 12.6421 12.7167 -.59

52 2613 1.000 473. 150 6.000 264.58 264.04 ,21 15.4241 15.4650 -.26

52 2614 1.000 498.150 6.000 264.58 264.58 ,00 18.2157 18.2159 -.00

52 2615 1.000 523. 150 6.000 264.58 265.02 -.17 2 1 . 0 1 48 20.9648 .24

52 2616 1.000 548.150 6.000 264.58 265,37 -.30 23.8137 23.7088 .44

52 2617 1 .000 573. 150 6.000 264.58 265.64 -.40 26.6083 26.4460 ,61 52 2618 1.000 598. 150 6.000 264.58 265,88 -.49 29.3984 29. 1748 .77

52 2619 1.000 623. 150 6.000 264.58 266.08 -.56 32. 1819 31 .8943 ,90

52 2620 1.000 369.850 6.500 286.63 284,42 .78 4.3046 4.3135 -.21

52 2621 1.000 373.150 6.500 286.63 282.13 1.60 4.6751 4.7038 -.61

52 2622 1.000 398. 150 6.500 286,63 283.07 1.26 7.6783 7.7722 -1 .21

52 2623 1 .000 423.150 6.500 286.63 284,60 .71 10.8232 10.9201 -.89

52 2624 1.000 448.150 6.500 286.63 285.62 .35 14.0320 14. 1022 -.50

52 2625 1.000 473. 150 6.500 286.63 286,28 .12 17.2683 17.3007 -. 19 52 2626 1.000 498. 150 6.500 286.63 286,72 -.03 20.5151 20.5054 .05

52 2627 1.000 523 . 1 50 6.500 286.63 287, 12 -, 17 23.7767 23.7102 .28

52 2628 1.000 548. 150 6.500 286.63 287,39 -,26 27.031

1

26.9107 .45

52 2629 1 .000 573. 150 6.500 286.63 287,71 -,38 30.2999 30. 1040 .65 52 2630 1.000 598.150 6.500 286.63 287,89 -,44 33.5433 33.2881 .77

52 2631 1.000 623.150 6.500 286.63 288,06 -,50 36,7846 36.4616 .89

121
Table 7. (Continued)

Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,

(13)Cherney, ( 17)Toml inson, (24)Ely, (26)Dittmar, (XXXX)Haynes , (51 ,52)Thomas, (78)Teichmann,

(79)Warowny.

1 D Data Weight Temp, Dens i ty Dens i ty Dens i ty '^expt ^ca 1 c Pressui Po i nt expt ca 1 c U 1 T T , U 1 t T , No. K mo 1 /L Kg/m-^ Kg/m^ % Mra MPa %

52 2632 1 .000 369.850 7.000 308.68 307.00 ,55 4.4573 4,4755 -,4 1 52 2633 1 .000 373. 1 50 7.000 308.68 306. 19 ,81 4.8957 4.9303 -, 70

52 2634 1 .000 398. 1 50 7.000 308.68 306.35 ,76 8.4013 8.4904 -1 ,05

52 2635 1 .000 423. 150 7.000 308.68 307.33 .44 12.0598 12. 1455 -,71

52 2636 1 .000 448. 1 50 7.000 308.68 308.09 ,19 1 5.7907 1 5,8436 -,33

52 2637 1 .000 473. 150 7.000 308.68 308.61 ,02 19. 5549 19, 5630 -,04

52 2638 1 .000 498. 1 50 7.000 308.68 308.97 -.09 23.3317 23,2910 . 1

7

52 2639 1 .000 523. 1 50 7.000 308.68 309.23 -, 18 27. 1 102 27,0197 ,34

52 2640 1 .000 548. 150 7.000 308.68 309.47 -.26 30,8952 30.7437 .49

52 2641 1 .000 573. 150 7.000 308.68 309.74 -.34 34.6896 34.4593 .67

52 2642 1 .000 598. 150 7.000 308.68 309.90 -,39 38.4597 38, 1639 .78

52 2643 1 .000 369.850 7.500 330.73 329.49 ,37 4.8221 4,8512 -.60

52 2644 1 .000 373. 1 50 7.500 330.73 329.22 ,46 5.3442 5,3857 -.77

52 2645 1 .000 398. 150 7.500 330.73 329.36 .42 9.4625 9,5405 -.82

52 2646 1 .000 423.150 7.500 330.73 330.03 ,21 13.7340 13,7944 -.44

52 2647 1.000 448. 150 7.500 330.73 330.42 ,09 18.0595 18,0953 -.20

52 2648 1.000 473. 150 7.500 330.73 330.87 -.04 22.4403 22,4191 .09

52 2649 1 .000 498. 150 7.500 330.73 331 . 13 -, 12 26.8214 26,7514 .26

52 2650 1.000 523.150 7.500 330.73 331.34 -. 18 31.2082 31.0832 .40

52 2651 1.000 548. 150 7.500 330.73 331 .50 -.23 35.5902 35.4082 .51 52 2652 1.000 573.150 7.500 330.73 33 1 . 72 -.30 39.9842 39.7222 ,66

52 2653 1.000 369.850 8.000 352.78 351 .87 ,26 5.5551 5.5955 -,72

52 2654 1.000 373.150 8.000 352.78 351 .84 ,27 6. 1798 6.2259 -,74

52 2655 1 .000 398. 150 8.000 352.78 352.00 .22 1 1 .0271 1 1 .0931 -,59

52 2656 1.000 423. 150 8.000 352.78 352.42 .10 16.0100 16.0528 -,27

52 2657 1 .000 448. 150 8.000 352.78 352.79 -.00 21 .0590 21 .0572 .01 52 2658 1 .000 473. 1 50 8.000 352.78 353.03 -.07 26. 1301 26.0818 .19

52 2659 1 .000 498. 150 8.000 352.78 353.20 -.12 31 .2060 31.1118 .30

52 2660 1.000 523. 1 50 8.000 352.78 353,34 -. 16 36.2829 36. 1374 .40

52 2661 1 .000 369.850 8. 500 374.83 374,05 .21 6,8600 6.9189 -.85

52 2662 1 .000 373. 1 50 8.500 374.83 374, 16 . 18 7,6085 7,6628 -.71

52 2663 1 .000 398. 1 50 8. 500 374.83 374,51 .09 13,3324 13.3719 -.30

52 2664 1 .000 423. 1 50 8.500 374.83 374,65 .05 1 9. 1 292 1 9. 1 583 -, 1

5

52 2665 1 .000 448. 1 50 8. 500 374.83 374,73 .02 24.961

7

24.9806 -,08

52 2666 1 .000 473. 1 50 8. 500 374.83 375. 10 -.07 30.8828 30.81 56 ,22

52 2667 1 .000 498. 1 50 8.500 374.83 375. 19 -. 10 36.7519 36.6491 ,28

52 2668 1 .000 369.850 9.000 396.87 396,40 .12 9.0356 9.0937 -.64

52 2669 1 .000 373. 1 50 9.000 396.87 396.43 . 1

1

9.9131 9.9700 -.57

52 2670 1 .000 398. 150 9.000 396.87 396.94 -.02 16.6730 16.661

7

.07

52 2671 1 .000 423. 150 9.000 396.87 396.82 ,01 23.3965 23,4083 -.05

52 2672 1 .000 448. 150 9.000 396.87 396.98 -,03 30.2048 30. 1757 . 10 52 2673 1 .000 473. 150 9.000 396.87 397. 10 -,06 37.0155 36.9435 . 19 52 2674 1 .000 369.850 9.500 418.92 418.79 ,03 12.4364 12.4614 -.20

52 2675 1.000 373. 150 9.500 418.92 418.99 -.02 13.5032 13.4902 ,10

52 2676 1.000 398. 150 9.500 418.92 418,85 ,02 21 .2979 21 .3154 -,08

52 2677 1.000 423. 150 9.500 418.92 418.98 -.01 29. 1850 29.1674 ,06

52 2678 1.000 448.150 9.500 418.92 418.99 -.02 37.0435 37.0195 .06

52 2679 1.000 369.850 10.000 440.97 440.96 .00 17.4363 17.4398 -.02

52 2680 1.000 373. 150 10.000 440.97 440.91 ,01 18.6257 18.6426 -.09

52 2681 1.000 398.150 10.000 440.97 441.11 -,03 27.8096 27.7624 ,17 52 2682 1.000 423.150 10.000 440.97 441.25 -.06 36.9863 36,8764 .30

52 2683 1.000 369.850 10.500 463.02 463,22 -.04 24,6078 24.5320 ,31 52 2684 1.000 373.150 10.500 463.02 463,28 -.06 26,0340 25.9316 ,39

52 2685 1.000 398.150 10.500 463.02 463,33 -.07 36,6584 36.5180 ,38

52 2686 1.000 369.850 1 1.000 485.07 485.50 -.09 34.5614 34.3368 .65 52 2687 1.000 373.150 1 1.000 485.07 485.54 -.10 36,2066 35.9576 .69

122
Table 8. Comparisons of data for ideal gas functions with eq (7).

Propane ideal gas functi

Temp. C°/R Diff

.

(H°

K expt. ca I c. i expt.

50.000 4.096 4.084 .296 4.014

100.000 4.967 4.987 -.409 4.254

150.000 5.868 5.854 .230 4.645

200.000 6.743 6.730 .201 5.059

273.150 8.268 8.289 -.250 5.707

298. 150 8.852 8.874 -.246 5.946

300.000 8.892 8.917 -.285 5.964

400.000 1 1 .308 11 .297 .089 6.998

500.000 13.542 13.519 .170 8.088

600.000 15.479 15.477 .014 9.162

700.000 17.160 17. 172 -.070 10.138

800.000 18.614 18.634 -.103 1 1 . 1 52 900.000 19.888 19.898 -.050 12.054

1000.000 21.000 20.996 .016 12.894

1 100.000 21.971 21 .957 .063 13.677

1200.000 22.821 22.803 .081 14.404

1300.000 23.556 23.552 .018 15.080

1400.000 24.200 24.219 -.076 15.709

1500.000 24.764 24.816 -.210 16.294

Number of points = 19, rms deviation for C? = 0.19

S° = 0.006?.

i

I

I

i

I

ji

1

I

from Chao, et a I . [131

)/RT Diff. S°/R Diff.

cal c. % expt. cal c. %

4.013 .024 22.353 22.355 -.009

4.254 -.001 25.433 25.433 -.001

4.647 -.045 27.622 27.625 -.010

5.056 .066 29.429 29.426 .01

1

5.706 .017 31 .749 31 .746 .008 5.947 -.016 32.498 32.497 .004 5.965 -.017 32.549 32.552 -.010

7.002 -.047 35.442 35.444 -.006

8.087 .01 1 38.210 38.208 .004 9.159 .033 40.852 40.850 .004 10.186 .019 43.368 43.367 .003

1 1 . 1 53 -.006 45.758 45.757 .002

12.056 -.017 48.023 48.027 -.008

12.896 -.015 50. 182 50. 182 .000 13.677 -.003 52 . 2 30 52.229 .002 14.403 .005 54. 177 54. 176 .002

15.079 .010 56.034 56.032 .005 15.708 .007 57.801 57.802 -.002

16.296 -.008 59.491 59.494 -.003

rms deviation for H = 0.03?; rms deviation for

123
Table 8. (Continued)

Propane ideal gas specific heats

Data sources and ID numbers: (2)A.P.I.44, (3)Beeck, (4)Sage, ( 5 )K i st i akowsky/Lacher

,

(6)Kistiakowsky/Rice, (7)Dailey, (8)Ernst, (9)Rossini.

ID Temp. C°/R Diff.

K expt. calc %

2 100.000 4.952 4.987 -.72

2 298.150 8.842 8.874 -.36

2 700.000 17.210 17.172 .22

2 1000.000 21 .050 20.996 .26

3 273.150 7.770 8.289 -6.68

3 373.150 10.135 10.665 -5.23

3 473.150 12.420 12.947 -4.24

3 573.150 14.433 1 4.978 -3.78

4 294.300 8.81 7 8.783 .39

4 310.900 9.088 9. 177 -.97

4 327.600 9.350 9.576 -2.42

4 344.300 9.617 9.976 -3.74

4 360.900 9.893 10.374 -4.85

4 377.600 10.165 10.771 -5.96

4 394.300 10.432 1 1 .164 -7.02

4 410.900 10.704 11.551 -7.91

4 427.600 10.970 1 1 .934 -8.78

4 444.300 1 1 .242 12.311 -9.51

5 148.200 5.883 5.825 .99

5 157.800 6.059 5.983 1 .26

5 213.100 7.045 6.986 .85

5 219.000 7.131 7.105 .37

5 258.000 7.926 7.944 -.22

6 272.380 8.037 8.271 -2.92

6 300.370 8.796 8.926 -1 .47

6 334.050 9.642 9.731 -.92

6 368.550 10.487 10.556 -.65

7 334.700 9.878 9.746 1 .34

7 360.100 10.236 10.354 -1 .16

7 387.800 10.875 1 1 .012 -1 .26

7 452.600 12.61

6

12.496 .95

7 521 .000 14.035 13.953 .59

7 562.000 14.644 14.765 -.83

7 603.300 15.479 15.537 -.37

7 693.200 16.918 17.065 -.86

8 293.150 8.740 8.755 -.17

8 313.150 9.154 9.230 -.83

8 333.150 9.658 9.709 -.53

8 353.150 10.151 10.188 -.37

9 338.706 9.840 9.842 -.03

9 352.594 10.186 10.175 .11 9 366.483 10.528 10.507 .20 9 380.372 10.869 10.836 .30

9 394.261 11 .206 1 1 .163 .38

9 408.150 11 .537 1 1 .487 .43 9 422.039 1 1 .857 1 1.807 .42

124
Table 9. I nterpo I ated ideal gas functions from eq ( 7 )

.

S°

K J /mot J/mo 1 J/(mol 'K) J/(mol 'K) J/( mo 1

•

80 2076.0 2741 .1 202.599 29.75 38.07

90 2382.

1

31 30.4 207. 1 82 31 .48 39.79

100 2705.3 3536.8 21 1 .461 33.15 41 .47 110 3044.8 3959.4 21 5.488 34.73 43.04

120 3399.6 4397.3 21 9.297 36.21 44.53

130 3768.9 4849.7 222.91

8

37.63 45.94

140 4152.0 531 6.0 226.373 39.00 47.31 150 4548.8 5796.0 229.683 40.36 48.67

160 4959.3 6289.6 232.868 41 .73 50.05

170 5383.5 6797.0 235.944 43.1 3 51 .45 180 5822.1 7318.7 238.925 44.58 52.90

190 6275.3 7855.1 241 .825 46.08 54.40

200 6743.9 8406.8 244.654 47.64 55.95

210 7228.3 8974.3 247.423 49.25 57.57

220 7729.2 9558.3 250.139 50.93 59.24

230 82 47 .0 101 59.3 252.81

1

52.65 60.97

240 8782.4 10777.8 255.443 54.43 62.74

250 9335.7 11414.3 258.041 56.25 64.56

260 9907.4 12069.1 260.609 58.1

1

66.42

270 10497.9 12742.8 263.1 51 60.00 68.31

280 1 1 107.5 13435.5 265.670 61 .92 70.23

290 1 1736.4 141 47.5 268.168 63.86 72.18

300 1 2384.8 1 4879.1 270.648 65.83 74.1 4 310 13053.0 15630.4 273. 1 1

2

67.80 76. 1 2 320 13740.9 16401 .5 275.560 69.79 78.

n

330 14448.8 17192.5 277.994 71 .78 80.1 0 340 1 51 76.6 1 8003.5 280.414 73.78 82.09

350 15924.3 18834.4 282.823 75.77 84 .08 360 16692.0 1 9685.1 285.219 77.76 86.07

370 1 7479.4 20555.7 287.605 79.74 88.05

380 1 8286.7 21446.1 289.979 81 .71 90.02

390 191 13.6 22356.2 292.343 83.67 91 .98 400 1 9960.0 23285.8 294.696 85.62 93.93

410 20825.9 24234.7 297.039 87.55 95.86

420 21 710.9 25203.0 299.372 89.46 97.78

430 2261 5.1 261 90.3 301 .695 91 .36 99.68

440 23538.1 27196.4 304.008 93.24 101 .56 450 24479.9 28221 .3 306.31

2

95.1 0 103.42

460 25440.1 29264.7 308.605 96.94 105.26

470 26418.6 30326.4 31 0.888 98.76 107.07

480 27415.2 31406.1 31 3. 161 100.56 108.87

490 28429.7 32503.7 315.424 102.33 1 10.65

500 29461 .8 33619.0 317.677 104.09 1 12.40

510 3051 1 .3 34751 .6 319.920 105.82 114.13

520 31578.0 35901 .5 322.1 53 107.52 1 15.84

530 32661 .7 37068.3 324.375 109.21 1 1 7.52 540 33762.1 38251 .9 326.588 1 10.87 119.19

550 34879.1 39451 .9 328.790 1 12.51 120.82

560 36012.3 40668.3 330.981 114.13 122.44

570 37161 .5 41900.7 333.163 1 15.72 124.04

580 38326.6 43148.9 335.334 1 17.29 125.61 590 39507.3 44412.8 337.494 1 18.84 127.16

600 40703.4 45692.0 339.644 120.37 128.68

610 41914.6 46986.3 341 .783 121 .87 130.19

620 431 40.7 48295.6 343.91

2

1 23.36 131 .67 630 44381 .6 49619.7 346.031 124.82 133.13

640 45637.0 50958.2 348.139 126.26 134.57

650 46906.7 5231 1 .0 350.236 127.67 135.99

125
Table 10. Comparisons of heat of vaporization data with

eq (9). Data sources and ID numbers; (l)Dana , (2)Kemp, (3)Sage, (4)Staveley,

( 5 ) He 1 geson

,

(6)Yesavage, (7)Carruth, (40)Thermal Loops, (4 1 )C 1 apeyron .

ID Weight Temp. Heat of Vapor i zat i on Dif f K kj/mo

1

% expt. ca 1 c. 40 1 .000 85.470 24.824 24.841 -. U / 40 .999 90.000 24.622 24.628 _ no 40 .997 95.000 24.401 24.398 Cl 1 40 .995 100.000 24. 183 24. 172 .U4 40 .993 105.000 23.967 23.952 .Ud 40 .992 1 1 0.000 23.754 23.735 .Uo

7 .991 1 10.946 23.719 23.695 . 1

0

40 .990 1 1 5.000 23.544 23.522 .09

7 .988 1 18.342 23.391 23.382 .04 40 .988 120.000 23.335 23.313 A A .09 40 .986 125.000 23. 129 23. 107 .09

7 .985 125.739 23.068 23.077 -.04

40 .983 130.000 22.925 22.904 .09

7 .982 133. 135 22.770 22.778 -.03

40 .981 135.000 22.722 22.703 .08 40 .979 140.000 22.520 22.504 .07 7 .979 140. 532 22.460 22.483 -. 10 40 .976 145.000 22,320 22.307 .06

7 .975 147.928 22. 182 22. 192 -.05

40 .974 1 50.000 22. 121 22. 1 1

1

.05

40 .97 1 155.000 21.923 21.916 .03

7 .971 1 55.324 21 .887 21.903 -.07

40 .969 160.000 21 .725 21.721 .02

7 ,967 162.721 21 .631 21.616 ,07

40 .966 165.000 21 .528 21 .527 ,01

40 .963 170.000 21.331 21.332 -.0

1

7 .963 170. 1 1

7

21.326 21.328 -,01

40 .960 175.000 21.133 21.137 -.02

7 .958 177.514 20.989 21.038 -.23

40 .956 180.000 20.935 20.940 -.03

7 .9 53 184.910 20.745 20.746 -.00

40 .953 185.000 20.736 20.742 -.03

40 .949 190.000 20.536 20.543 A"2 -.03

7 .947 192.306 20.459 20.450 A c; 40 .945 195.000 20.334 20.340 -.03

7 .942 199.703 20.144 20. 148 AO 40 .941 200.000 20.129 20.135 -.03A 40 .937 205.000 19.922 19.927 -.03AT

7 0.000 207.099 20.014 19.839 o o •oo 40 .933 210.000 19.712 19.716 AO -.02

7 .928 214.496 19.504 19.522 A A - .(jy 40 .928 21 5 » 000 19.498 19.500 A 1 -.01

40 .923 220.000 19.280 19.279 .0

1

7 .921 221 .892 19.189 19. 194 -.03

40 .917 225.000 19.057 19.053 ,02

7 .912 229.288 18.857 18.855 .01 40 .912 230.000 18.830 18.822 .04 40 .910 23 1 ,000 18.783 18.775 ,04

7 .903 236.685 18.500 18.503 -.02

41 -.998 90.000 24.562 24.628 -,27

41 .995 100.000 24. 157 24. 172 -.06

41 .991 1 10.000 23.744 23.73 5 ,04

41 .986 120.000 23.328 23,313 ,06

41 .982 130-000 22.914 22,904 ,04

41 .977 140.000 22.504 22,504 -.00

41 .971 150.000 22. 100 22, 11

1

-,05

41 .965 160.000 21 .703 21.721 -.08

41 .959 170.000 21.310 21,332 -,10

41 .951 180.000 20.918 20,940 -,10

41 .944 190.000 20.525 20,543 -,09

41 .935 200.000 20,124 20,135 -.06

41 .925 210.000 19,713 19,716 -.01

41 .914 220.000 19.285 19,279 .03

125
Table 10. (Continued).

Data Sources and ID numbers: (l)Dana, (2)Kemp, (3)Sage, (4)Staveley,

(5) Hel geson

,

(6)Yesavage, (7)Carruth, (40)Thermal Loops, (4 1 ) C 1 apeyron

,

1 U We 19''' Temp

.

Heat of Vapor i zation Di ff K kj/mo

1

% expt. ca 1 c

.

41 .902 230.000 1 0 . 0J /

1 ft ft99 Oft 41 .888 240.000 1 ft "^fi? 1ft ^dn 19

41 .872 250.000 17 ft'iR 1

1 7/ %0R9QiLy 1 A

41 .853 260.000 17 1 n 17 9H'^ 41 .831 270.000 16.720 16.696 .14

41 .805 280.000 15.078 15.062 .10

41 .774 290.000 15.377 15.372 .04

41 .736 300.000 14.608 14.514 -.04

41 .687 Tin c\r\ f\ 31 0.000 13.757 13.775 -. 13 41 .625 T~i r\ r\r\r\ 320.000 12.808 12.834 -.20

A 1 4

1

.541 "21 r\ r\r\r\ 330. 000 11.733 11.760 -.23

41 .426 ~i A r\ r\r\r\ 340.000 10.480 10.499 -.19

41 .264 350. 000 8.941 8.946 -.05

A 1 41 .052 ic r\ r\ r\r\ 350.000 6.821 5.805 .22

1 0.000 234.070 1ft d4i 1ft fi9Q 1 n 1

1 0.000 237.750 1 ft 4 S 1 99

1 0.000 241 .830 1 ft 949 1ft 94Q

1 0.000 247.100 17 ft7'^ 1 7 QR 11

/

•yO 1 - fin

1 0.000 253.740 17 ft 1 Q 17 fi9Q 11 nft . uo

1 0.000 261 .210 1 7 .397 17.214

1 0.000 269. 100 16 .855 16.751 .58

1 0.000 275.420 1 5.330 1 5.359 - 1

8

1 0.000 279.890 16.524 16.069 2.83

1 0.000 281.8 50 15.814 15.939 -.78

1 0.000 285.530 1 5.738 1 5.588 .32

1 0.000 287.150 15. 795 15.575 1 .41

1 0.000 292.200 1 5.355 15.211 .95

1 0.000 292.700 15.595 15. 174 2.78

2 0.000 231.090 18.780 18.771 .05

3 0.000 312.817 1 3.527 1 3. 521 .78 3 0.000 312.983 1 3.649 13.505 1 .06 3 0.000 316.206 13.360 1 3.204 1.18

3 0.000 315.372 1 3.551 13. 189 2.75

3 0.000 316.483 1 3.551 13. 178 2.83

3 0.000 315.539 13.282 1 3. 173 .83

3 0.000 318.928 13.171 12.940 1 .78 3 0.000 320.983 1 3. 127 1 2.735 . nft uo

3 0.000 321. 150 12.718 '^4 3 0.000 327.983 1 2. 284 1 1 .989 2.45

3 0.000 328.094 12.224 1 1 .977 2.07

3 0.000 335.594 1 1 .297 1 1 .082 1 Q4

3 0.000 335.650 1 1 "^44 11 n7s 9 4^^ 3 0.000 345.706 1 n 9ns S 54 3 0.000 346.039 in 1 ftft Q ftn7 D . n4UH 3 0.000 348.150 Q f=i4ft y . 4 1 S 4 0.000 185.000 9n fion 90 749 - 9S

4 0.000 213.200 1 Q fifin 1 Q 'i7ft 49

5 0.000 310.928 13.651 13.592 -.30

5 0.000 322.039 1 2.592 1 2.627 - 9ft 5 0.000 327.594 1

1 1

1 . QftQ yO

y

19 n'^'^ - ""ifi . _J D 5 0.000 330.372 11 1 9 11 7 17 - .oyftQ 6 0.000 231 .094 18.778 IR10./77 1 / 1 • n4u^

6 0.000 253.206 17 1 4ft 17 1 on 9ft 6 0.000 285.928 IS I'^A 47

6 0.000 301.317 14I H . 517 ij 1 / 1 4 .508 .75

6 0.000 313.428 13.633 13.465 1 .25

6 0.000 323.428 12.649 12.483 1.33

6 0.000 331 .817 1 1 .624 1 1.547 .67

6 0.000 339.483 10.578 10.570 .07

6 0.000 345.205 9.512 9.581 -.72

6 0.000 352.428 8.405 8.500 1.12

6 0.000 358.039 7.216 7.304 1 .20 6 0.000 363.372 5.873 5.787 1 .49

6 0.000 357.039 4.449 4,198 5.99

Number of data points used in fit = 76; rms deviation = 0.083?.

127
Table 11. Enthalpies of saturated liquid propane from

eq (10).

Temp. Ha' (eq (10)) Di ff

.

K J /mo 1 J /mo 1 %

90.00 391.6 391 .5 .018

100.00 1253.4 1253.4 -.003

1 10.00 2113.2 2113.3 -.004

120.00 2973.0 2973.0 .000

130.00 3834.6 3834.5 .003 140.00 4700.4 4700.3 .002

1 50.00 5572.6 5572.6 .000

160.00 6453.6 6453.7 -.001

1 70.00 7345.6 7345.7 -.001

180.00 8250.5 8250.7 -.002

190.00 91 70.5 9170.5 -.000

200.00 10106.9 10106.8 .001 210.00 11061 .1 1 1060.9 .002

220.00 12034.5 12034.3 .002 230.00 13028.3 13028.2 .001 240.00 14043.7 14043.9 -.001 250.00 1 5082.5 1 5082.6 -.001

260.00 161 45.6 161 45.9 -.002

270.00 1 7235.5 1 7235.6 -.000

280.00 18354.0 18353.9 .000

290.00 19504.4 19504.1 .002 300.00 20690.5 20690.3 .001 310.00 21918.3 21918.2 .000

320.00 23196.1 23196.4 -.001

330.00 24537.1 24537.6 -.002

340.00 25963.5 25963.4 .000

350.00 2751 7.5 27516.8 .002 360,00 29314.7 29315.0 -.001 369.85 33082.2 33082.2 0.000

Number of points = 28; rms deviation = 0.004|.

Derived from idea! gas functions, the equation of state, and the formulated

heats of vaporization.

128
Table 12. Entropies and specific tieats of saturated liquid

propane from eq (11).

T©rnp • o 0 g I eq Ml;; u 1 T 1 •

1/t\ 1 /I m(?l . k'^ J/ ^ mo 1 • t\ j J/ \ mo 1 • (\

;

P J/ L mo 1

Ai • DO 1 oz . po

1

n nnn u .uuu Q 7 Ryl 0 / . !54 yu . uu 0 / • U / H 07 A7n 0 / . u /U nn R R70 / • ORU J

1 nn nn y D .

1

1 Q7y / QCy D .

1

1 Q7y / nnn .uuu 00. n A ORZP

1 1 u . uu 1 n/i xoA 1 U4 • jyo — • nnx UUJ OD.O Q R P7/

1

1 onzu.uunn 1 1 1 Hf^A I 1 1 .004 11 1

1 1

1 .ODD PAA _ AA 1 . UU 1 Q R QP 0 J .00

1 ^n nn 110./ ZJ J 110 7 K

1

nn 1 • UU 1 RA ox

1 >i n nn 1 4U.UU 1 0 R 1 A R 1 0 R 1 AX 1 Z 3 . 1 D J nno .uuz oDOA Q A .00

1 (^n nn 1 T 1 1 Q c:

1 J 1 . 1 oD 1x1 1 QyJ1 J 1 . 104 nn 1 .UU 1 Q7 7 1 0 / . / 1

1 An nn 1 dU.UU 1 T A C377 1 TA Q77 nnn -»uuu 00Q Q 7 R . / D

1 ~7n nn 1 / U • UU 1 4z .zyz 1 /I 0 OQX 1 4z . zyj nn 1 -.UU 1 QO OA oy . yo

ion nn loU.UU 1 yi 7 yl 7 1

1 4 / .4 / 1 1/17 >1 7X 1 4 / .4 /_) - nn 1 .UU 1 01 X 0 y 1 » jZ

1 0A nn 1 yu. UU 1 CO A AO 1 c; 0 >1 KA I 5Z . 4DU -. AA 1 UU 1 00 D 1 yz . 0

1

onn nn ZUU.UU 1 R 7 0 R 1 1 R7 OR 1 nnn • UUU Oyl / R y4 .4 D o 1 n nn Z 1 U . UU 1 1 AAO 1 D 1 . yUz 1 A 1 on 1

1 D 1 .yu 1 nn 1 .UU 1 OA on yo. ZU oon nA Z/CU.UU 1 oo.4z

1

1 A A yl on 1 OD.4ZU nn 1 • UU 1 00 AO yo .Uo

O "Z A AA ZjU.UU 1 7n 00/1

1 /U.oZ4 1 ~7n 00 1 /U. oZ

J

An 1 .UU 1 inn A7 lUU. U

/

O /I A AA Z4U.UU 1 /5. 1 ZD 1 T R 1 0 R

1 / 5. 1 Z3 AAA .UUU 1 AO 1 A

1 UZ . 1 0 oc n nn Z5U. UU 1 7n Txn 1 "7 n "Z yl A 1 / y . 34U AAA -.UUU 1 A /I X R

1 U4. 35

o^;n An /COU.UU 1 0 J.4 /o 1 Q "7 yl "7 7

1 o3.4 / / - A A 1 ,UU 1 1 A A A ~7 IUD.O / 0"7 A AA 2 / 0 . 00 lo /. 548 187, 549 AA 1 -.001 1 AA 1 R luy . 1

5

OO A AA zoU.OU 1 A 1

1 y

1

.5dd 1 A 1 R £C ~7 ly 1 .50/ AAA -.UUU 111 OA 1 1 1 .80 290.00 195.544 195.543 .001 114.87

300.00 199.496 199.495 .001 1 18.33 310.00 203.440 203.439 .001 122.41 320.00 207.401 207.401 -.000 127.39

330.00 21 1 .412 21 1.415 -.001 133.79

340.00 215.532 215.533 -.001 142.79

350.00 219.870 219.867 .002 157.85

360.00 224.725 224.727 -.001 194.14

369.85 234.726 234.726 0.000

Number of points = 28; rms deviation = 0.001?.

^ Derived from ideal gas functions, equation of state, and formulated heats

of vaporization.

129
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135
Table 14. Comparisons with saturated liquid specific heats.

sources and 1 D numbers

:

(l)Dana, (2)Kemp, (8)Cut-ler, (30)Yesavage, (XXX) Good

w

n.

ID Weight Temp. Cq, J/(mol»K) Di f f

.

K expt ca 1 c %

106 1 .000 85.598 83.95 84.10 -.17

239 1 .000 85.723 83.83 84.10 -.32

240 1 .000 86.395 83.93 84. 13 -.24

107 1 .000 86.622 84.29 84.14 .17

201 1 .000 86.763 84.32 84 . 1

5

.20

108 1 .000 86.836 83.81 84.15 -.41

241 1 .000 87.064 84.04 84.16 -.15

109 1 .000 87.856 84.15 84.20 -.06

242 1 .000 87.870 84.33 84.20 .15 110 1.000 88.871 84.1 7 84.25 -.09

243 1 .000 88,931 84.28 84.25 .03

2 1.000 89.720 84.55 84.29 .31

1 1

1

1 .000 89.379 84,48 84.30 .22 30 1 .000 90.000 34.04 84,30 -.31 202 1 .000 90.366 84.53 84.32 .25

8 1 .000 91,060 83.97 34.35 -.45

1 12 1 .000 91 .366 84.54 84.37 .20

113 1 .000 93.321 84.73 84.46 .32

8 1 .000 93.430 84.22 84.47 -.29

203 1 .000 95.166 84.78 84.55 .27

2 1 .000 95.530 84.76 84.57 .22

114 1 .000 95.750 84.73 84.58 .18

8 1 .000 95.760 84.48 84.58 -.13

8 1 .000 98.060 84.14 84.70 -.66

115 1 .000 99,797 84.94 84.79 .18 30 1 .000 100.000 34.86 84.80 .07

8 1 .000 100.330 84.06 84.81 -.89

204 1 .000 101.406 85.10 84.87 .27

2 1 .000 101 .960 85.09 84.90 .22

8 1 .000 102.570 84.73 84.93 -.24

116 1 .000 104.646 85.25 85.04 .24

8 1 .000 104.780 85.06 85.05 .01 205 1 .000 108.461 85.43 85.25 .21 2 1 .000 108.500 85.43 85,26 .20

30 1 .000 1 10.000 85.85 85.34 .60 117 1 .000 1 10.300 85.53 85.36 .20

2 1 .000 1 15.160 85.30 85.64 .19

206 1 .000 115.393 85.79 85.66 .16

1 18 1 .000 1 16.889 85.81 85.75 .08 30 1 .000 120.000 86.72 85.94 .91 2 1 .000 121 .970 86.18 86.06 .14

207 1 .000 122.132 86.18 86.07 .12 119 1 .000 124.009 86.20 86.19 .01 208 1 .000 128.738 86.51 86.51 -.00

2 1 .000 128.900 86.56 86.52 .04 30 1 .000 130.000 87.42 86.60 .95

120 1 .000 131 .003 86.69 86.67 .03 209 1 .000 135.238 86.92 86.97 -.06

2 1 .000 135.950 87.23 87.02 .23

121 1.000 137.870 87.14 87.17 -.03

136
Table 14. (Continued)

.

sources and ID numbers: (l)Dana, (2)Kemp, (8)Cutler

,

(30)Yes3vage, (XXX)Goodwln

ID Weight Temp. , .J/(mol«K) Oi ff. K expt ca 1 c % 30 1 .000 140.000 88.04 87.33 .82 210 1 .000 141 .629 87.35 87.45 -.12

2 1 .000 142.790 87.44 87.54 -.13

122 1 .000 145.757 87.68 87.78 -.12

21

1

1 .000 147.902 87.87 87.96 -.10

2 1 .000 149.740 88.15 88.11 .04 30 1 .000 150.000 88.67 83.14 .61 123 1 .000 152.350 88.16 88.34 -.20

212 1 .000 154.093 88.32 88.49 -.19

2 1 .000 156.850 88.69 88.74 -.05

124 1 .000 158.858 88.77 88.93 -.18

30 1 .000 160.000 89.38 89.03 .39 213 1 .000 160.343 88.97 89.07 -.11

2 1 .000 164.390 89.36 89.46 -.11 125 1 .000 165.298 89.30 89.55 -.28

214 1 .000 166.378 89.58 89.66 -.08

30 1 .000 170.000 90.24 90.03 .24 126 1 .000 171.647 90.11 90.20 -.10

2 1 .000 172.020 89.86 90.24 -.42

215 1 .000 172.363 90.21 90.28 -.08

216 1 .000 178.276 90.82 90.93 -.12

2 1 .000 179.090 90.74 91 .02 -.31 127 1 .000 179.354 90o90 91 .06 -.17

30 1 .000 180.000 91 .26 91 .13 .14 217 1 .000 184.114 91 .46 91 .62 -.17

128 1 .000 185.534 91 .67 91 .79 -.13

2 1 .000 185.900 91 .66 91 .83 -.19

218 1 .000 189.882 92.19 92.34 -.16

30 1 .000 190.000 92.46 92.35 .12 129 1 .000 191 .643 92.48 92.56 -.09

2 1 .000 194.280 92.79 92.91 -.13

219 1.000 195.603 93.01 93.09 -.09

130 1 .000 197.686 93.21 93.33 -.18

30 1 .000 200.000 93.83 93.70 .14

2 1 .000 200.940 93.84 93.83 .00 220 1 .000 202.405 93.74 94,05 -.33

131 1 .000 204.154 94.13 94.30 -.18

2 1.000 207.090 94.26 94.74 -.51 221 1 .000 209.358 95.04 95.09 -.06

30 1 .000 210.000 95.35 95.20 .16

132 1 .000 21 1 .041 95.39 95.36 .03

2 1 .000 213.100 95.43 95.69 -.27

222 1 .000 216.234 96.25 96.21 .05 133 1 .000 217.854 96.43 96.48 -.05

2 1.000 219.250 96.27 96.72 -.47

30 1 .000 220.000 97.04 96.85 .20 223 1 .000 222.998 97.34 97.38 -.04

134 1 .000 224.592 97.55 97.66 -.12

2 1 .000 224.960 97.48 97.73 -.26

224 1 .000 229.651 98.54 98.61 -.07

2 1 .000 229.810 98.28 98.64 -.37

137
Table 14. (Continued).

sources and ID numbers: ( 1 )Dana, (2 )Kemp, (8) CutI er

,

(30 ) Yesavage, (XXX)ooodwin •

ID We ight Temp. , J / ( mo 1 • K

)

Di f f

.

K expt ca 1 c %

30 1 .000 230.000 98.92 98.68 .25 135 1 .000 231 .245 98.90 98.92 -.02

225 1 .000 236. 231 99.81 99.91 -. 1 0 136 1 .000 238.095 100.16 1 00 . 30 -.1 4 30 1 .000 240.000 1 00.99 100.70 .29

1 0.000 241 .760 99.82 1 01 .08 -1 .25 226 1.000 242.764 101 .25 1 01 .30 -.05

1 37 1 .000 244.560 101 .75 101.69 .05

1 0.000 246.880 96.49 1 02.22 -5.60

30 1 .000 250.000 1 03.31 1 02.95 .35

1 38 1 .000 250.946 103.20 1 03 . 1

7

.03

1 0.000 252.820 1 00. 55 1 03.62 -2.96

1 0.000 255.330 100.74 1 04.24 -3.36

139 1 .000 257.248 104.75 1 04.73 .02 30 1.000 260.000 1 05.89 1 05.44 .43

1 0.000 261 .550 105.72 105.85 -.13

1 40 1 .000 263.551 106.27 1 06.40 -.12

1 0.000 264.740 97.79 1 06.72 -8.37

1 0.000 266.440 1 06. 27 1 07. 20 -.87

1 0.000 269.060 1 07.20 107.95 -.70

1 41 1 .000 269.931 108.1

5

1 08.21 -.05

30 1 .000 270.000 1 08.77 1 08.23 .50

1 42 1 .000 275. 292 1 09.98 1 1 A 1 C 110.15 -. 1 5

1 0.000 276.430 1 07.01 1 1 0. 20 0 OA -2.89

1 0.000 275 . 780 1 1 1 .44 S 1 A 7 1

1 1 0.31 1 AO

1 .02 30 1 .000 280.000 111 .98 1 1 1 .36 .56

1 43 1 .000 282 .595 111 11 1 .96 1 1 /.z4 - . Z5

1 0.000 287.550 1 0 7 . 75 1 1 4 .00 -5.48

1 44 1 .000 288. 81

3

1 1 4.09 1 1 4.46 -.33

30 1 .000 290.000 1 1 5.57 1 1 4.91 .57

1 0.000 291 .590 1 1 0.89 1 1 5 .52 -4 .01 30 1 .000 300.000 1 19.60 1 18.99 .52 30 1 .000 310.000 124.22 123.76 .37 30 1 .000 320.000 129.70 129.53 .13

30 1 .000 330.000 136.63 136.83 -.15

30 1 .000 340.000 146.28 146.85 -.39

30 1.000 350.000 162.17 162.81 -.39

30 1 .000 360.000 199.63 198.91 .36

Number of data points = 139; rms deviation = 0.29^.

138
Table 15. Comparisons with and Cp data.

Cr, data of Ernst (26)

T = 293. 15 K

Pressure Dens i ty Cn, J/(mol'K) Diff. Cp - Cp, J/(mol.K) Diff. MPa I<g/m3 expt ca 1 c % expt ca 1 c %

n on 72.67 72.80 - 1 7 n nn n nn

.90 73.06 73. 13 • \jj 39 . -j^ .06

1.81 73.51 73.50 .01 .84 .7 1 . 1

3

1 Q^l 3 .68 74.47 74.39 • 1

1

1 .80 1 . 59 .21 6.62 76.32 76.09 .30 3.65 3.29 .36 .4903 9.74 78 .48 78 .35 . 16 5.81 5.56 .25 .6374 13.10 81.13 81 .43 -.36 8.46 8.63 -.17

.7845 16.75 84.57 85.79 - 1 .42 1 1 .90 1 3.00 -1.10

T = 313.15 K

0.0000 0.00 76. 1

1

76.74 -.83 0.00 0.00 0.00

.0490 .84 76.53 77.01 -.63 .42 .21 .15 .0981 1 .69 76 .95 77.31 -.46 .84 .56 .28

. 1961 3.42 77.79 77.97 -.23 1 .68 1 .23 .45 .3432 5. 12 79.19 79. 18 .02 3.08 2.43 .65 4903 8.95 80.63 80.66 - .04 4. 52 3.92 .60 .6374 1 1 .93 82.44 82.49 - .06 6.33 5 .74 .59

. 7845 1 5.08 84.61 84.75 -. 1

7

8. 50 8.0

1

.49

1 Q fi9 88.01 88.74 1 1 90 1 2.00 -.10

11.1/1 7fiR OO 93.18 94.49 -1 "SQ 1 7 07 17.75 -. 68

T = 333.15 K

0.0000 0.00 80.30 80.72 -.53 0.00 0.00 0.00

.0490 .79 80.55 80.95 -.49 .25 .22 .03 .0981 1.58 80.93 81 .19 -.32 .63 .46 .17

1 Q^^1 • 1 yo 1 81 .54 81 .71 - 9

1

1 94 .70 9fi s 7n 82.56 82.62 - 07 9 9fi 1 ftQ .-J / o • 83.56 83.68 _ 1 c \ 9fi 9 Qfi

• /

1 1 nn 85.00 84.93 •uo 4 7n 4 9 1 4Q

• / Oh-_? 1 ft9 1 J» oz 86.45 86.39 • U / O . 1 J J 90 / . 4RHO

• you /

1 7 7R 88.65 88.73 —— • OQuy O. U 1 ^4

1 1 7fift 1 • 1 / OO 99 H"^ 91.28 91 .67 - A9 1 n Qfl 1 U . 70 1 n Q4 n4

1 "^790 9*^ ft"^ 94.95 95.44 - ^ 1 14 ftR 1 H . D J 14 71 . UD

T = 353.15 K

0.0000 0.00 84.40 84.71 -.37 0.00 0.00 0.00

.0490 .74 84.59 84.90 -.37 .19 .19 -.00

.0981 1 .49 84.79 85.10 -.36 .39 .39 .00

.1961 3.01 85.36 85.52 -. 19 .96 .81 .15 .3432 5.34 86.19 86.23 -.05 1.79 1 .52 .27 .4903 7.75 86.97 87.05 -.09 2.57 2.34 .23 .6374 10.23 88.01 87.96 .05 3.61 3.25 .36 .7845 12.79 89.02 89.00 .02 4.62 4.29 .33 .9807 16.36 90.65 90.59 .07 6.25 5.88 .37 1.1768 20.10 92.39 92.45 -.06 7.99 7.74 .25 1.3729 24.06 94.37 94.66 -.30 9.97 9.95 .02

Number of data points of Ernst [261 = 40, mean deviation = 0.30$.

139
Table 15. (Continued).

Cp dat.3 of Yesavage [104,105]

P = 1.7237 MPa

Torn n - Lyfe?!! b 1 ry Up , J / 1 .no 1 •l\

;

Di f f

.

K kg/(n3 ©xpi" ca t c %

1 16.483 702.41 85.79 85.67 .14

144.261 674.46 87.64 87.58 .07

172.039 646.27 89.85 90.1

1

-.29

199.817 61 7.30 93.17 93.48 -.33

??7 .5Q4 ^oo

Q7 7Q y / .yo -. 20

255 ,372 1 c\A c\e^

1 U4 .(jy -.03

283. 1 50 119 7'=;

1 \ i. m 1

J

110 1 1 z. /D A1 -.03

31 0.928 1 9R 41 1 ZO . 1 1 Z D . O'J 1 .27

^4 (Si's 1 m Ri^;

1 . Uz -1.14

U'J • H O-' Z^ . /U yy. 1 u -.21

Ji?^ . ZD 1 ZD. '4 1 1 Uz .(J J 1 00 . DO 1 .36

r - J. 44/4 Mra

1

1 1ID.« AW^ *+OJ? 70/UJ)^ . 141 4 85 .63 .41

1 44.261 675.36 R7 > 1 0 172.039 647.40 89.67 89.98 -.35

199.817 618.74 92.80 93.27 -.50

227.594 588.77 97.60 97.62 -.02

255.372 556.63 103.51 103.45 .05 283.150 520.96 1 12.18 111.49 .62 310.928 479.14 124.17 123.55 .51 338.706 423.88 150.37 147.55 1 .91 366.483 82.76 157.57 165.81 -4.97

394.261 63.07 122.14 120.50 1 .36

422.039 53.88 114.02 1 14.63 -.53

P = 6.8948 MPa

116.483 704.58 85,98 85.54 .51 144.261 677.14 87.64 87.35 .32 172.039 649.60 89.48 89.74 -.29

199.817 621.53 92.62 92.87 -.27

227.594 592.39 97.05 96.97 .08 255.372 561.50 102.77 102.35 .41 283.150 527.90 110.15 109.44 .64

310.928 490.05 118.82 119.12 -.25

338.706 444.87 133.21 133.40 -.14

366.483 384.03 159.23 156.08 1.97

394.261 267.62 267.53 262.28 1.96

422.039 155.32 176.38 177.78 -.79

140
Table 1!3. (Continued).

Cp da ha of Yesavage (104,1051

P = 10.342 1 MPa

Temp. DensI ty Cp , J / ( mo 1 •K) 0 i f f

.

K kg/nv5 expt cat c %

1 16.483 705.99 86. 1

6

85. 46 .82 144.261 678.87 87.82 87.22 .69

172.039 651 .75 89.85 89.52 .38 199.31

7

624.22 92.44 92.52 -.09

227.594 595.82 96.68 96.41 .28 255.372 566.02 102.03 101 .42 .60 283.150 534.12 108.49 107.86 .58 510.928 499.13 1 16.42 116.18 .21 338.706 459.52 126.20 1 26.99 -.63

366.483 412.55 1 39.30 136.65 1 .90 394 .261 352 . 95 1 59.96 164.44 -2.80

422.039 276.85 1 77.68 180.32 -1 .49

P = 13.7895 MPa

11 6.483 707.38 86.16 85.38 .91 144.261 680.57 88.01 87.09 1 .05

1 72.039 653.84 90.22 89.31 1 .01 199.81 7 626.81 92.44 92.19 .26

22 7.594 599.10 96.31 95.91 .42 255.372 570.25 101 .29 100.63 .65 283.1 50 539.76 107.20 106.60 .56 310.928 506.97 1 13.84 1 14.05 -.13

333.706 471 .06 122.51 123.17 -.54

366.483 430.88 131 .55 128.97 1 .96 394.261 385.05 146.13 147.46 -.92

Number of data points of Yesavage [104,1051 = 58; mean deviation = 0.74$.

i'

j

I

t 141
Table 15, (Continued).

Cy data of Goodwin [341

ID Weight Temp. Dsns i ty Cy, J/(mol •K) iff.

K kg/m3 expt ca 1 c %

145 1 .000 296.740 497.86 74.25 73.32 1.25

146 1 .000 301 .507 497.55 74.20 74.23 -.04

147 1 .000 307.514 497.15 75.28 75.41 -.18

148 1 .000 313.479 496.76 76.27 76.62 -.46

149 1.000 319.395 496.40 77.31 77.87 -.72

150 1 .000 325.273 496.01 78.14 79.13 -1 .27

151 1 .000 331 .118 495.61 79.22 80.43 -1 .52 152 1 .000 336.944 495.26 80.26 81 .72 -1 .82

801 1 .000 278.582 526.92 70.78 70.35 .60 802 1 .000 284.558 526.43 71 .75 71 .39 .51 803 nooo 290.482 525.99 72.82 72.44 .52 804 1 .000 296.874 525.51 73.98 73.62 ,48

805 1 .000 303.743 524.98 75.23 74.94 ,39

806 1.000 310.524 524.49 76.47 76.30 .22 807 - 1.000 317.249 523.96 77.67 77.69 -.02

808 1 .000 322.550 523.57 78.69 78.83 -.18

228 1.000 256.127 554.43 67.50 67.31 ,28

229 1 .000 258.883 554.21 68.04 67.72 ,47

230 1 .000 262.933 553.86 68.83 68.33 .72

231 1 .000 268.252 553.38 69.77 69.16 .88 232 1.000 273.524 552.93 70.50 70.00 .71 233 1 .000 278.769 552.45 71 .33 70.86 .56 234 1.000 283.978 552.01 72.26 71 .74 .72 235 1 .000 289.142 551 .52 73.34 72.65 .94

901 1 .000 238.1 72 575.87 66.22 65.37 1.28

902 1 .000 242.833 575.42 66.28 65.99 .43 903 1 .000 248.402 574.85 67.18 66.75 .64 904 1 .000 254.401 574.28 68.15 67.59 .83 905 1 .000 260.329 573.70 69.08 68.44 .92 906 1 .000 265.728 573.13 70.11 69.24 1 .23 907 1 .000 270.590 572.69 70.98 69.99 1.39

301 1 .000 216.834 600.38 64.02 63.58 .69

302 1 .000 220.658 599.99 64.05 64.02 .05 303 1 .000 224.436 599.55 64.27 64.46 -.29

304 1 .000 223.198 599.10 64.87 64.90 -.04

305 1 .000 231 .931 598.71 65.45 65.34 .16 306 1 .000 235.624 598.27 66.07 65.79 .42 307 1 ,000 239.291 597.87 66.66 66.25 .61 401 1 .000 188.878 ' 630.46 61 .48 61 .92 -.72

402 1 .000 192.681 629.93 61 .84 62.28 -.71 403 1 .000 196.572 629.40 62.23 62.65 -.63

404 1 .000 200.423 628.91 62.78 63.02 -.39

405 1.000 204.255 628.39 63.27 63.39 -.20

406 1 .000 207.852 627.90 63.83 63.75 .13

501 1 .000 156.982 663.40 60.08 60.91 -1 .38 502 1 .000 160.668 662.83 60.36 61 .19 -1 .38 503 1 .000 164.253 662.25 60.80 61 .46 -1 .09 504 1 .000 167.802 661 .68 61 .15 61 .73 -.95

505 1 .000 171 ,318 661 .1 1 61 .60 62.00 -.64

601 1 . 000 1 26.412 693.69 59.78 60. 71 -1 . 56

602 1 .000 129.030 693.21 60.02 60.88 -1 .44

603 1 .000 131 .699 692.68 60.22 61 .05 -1 .37 604 1 .000 134.41

8

692 . 1

9

60.41 61 .21 -1 .33 605 1 .000 137.115 691 .66 60.60 61 .37 -1 .28

701 1 .000 100.334 7V9.62 60.49 61 .21 -1 .20

702 1 .000 102.729 71 9.09 60.76 61 .35 -.97

703 1 .000 105.095 718.56 60.85 61 .48 -1 .03

704 1 .000 107.444 718.08 60.99 61 .60 -.99

Number of Cy data points of Goodwin [341 = 58; mean deviation = 0.89^.

142
Table 16. Comparisons with velocity of sound data.

Velocities of sound from Younglove [107]

Temp. Pressure Dens I ty Ve 1 . of Sound, m/s Iff.

K MPa kg/mJ expt cal c % 90.00 34.332 739.94 2205.4 2096.3 5.20

90.00 31 . 431 738. 90 21 96.2 2086.5 5.26

90.00 29.537 738.32 21 90.8 2081 .0 5.28

90.00 28. 713 738.06 21 88.8 2078.6 5.50

90.00 OK 1 "ZO 2p . 1 3z /3o. ys 21 79.0 2068.2 5. 36 90.00 23.31

7

736.37 21 73.7 2062.9 5.37

90.00 17.218 734. 42 21 55.

5

2045.

1

5. 45 90.00 1 4.584 733.57 21 49.0 2037.4 5.48

90.00 11 >1 1 Q1 1 .41

o

0 1 ZO 1 21 3o.

1

0 AOO 1 zOzo.

1

C 4 0 5.42 yu.uu o

«

ooj /j\ .DO 0 1 "ZO 0 Z 1 JZ .z

0 AOA zUzU .D 5. 5Z yu.uu D. U4y Tzr\ 1

A

0 1 0 "Z T Zl ZJ.

/

0 Al 0 "Z ZUI Z.J 5.54 OA AA y<j. 00 O QAT TO A £.A 0 1 1 >! 0 z 1 1 4.

z

0 AAO 0 zOUz.o 5.55

1 AA AA J"> . 3D / 01 ^ "Z "Z Z 1 4J . JOAZ/1 A R "ZT

1 AA AA 1 UU.UU ^ y . yy 1 70Q A1 0 1 "Z A 7 OA1 Q A zu 1 y.y C /I Q 5 . 4o

1 AA AA 1 00.00 ^ 1 "I ZD.Ol -5 "70 T OQ /z / .OO 0 1 OA Q zl zO.o OAAA C zuoy .

5

c c >1 5.54

1 AA AA 1 00 . 00 z3.3jo /ZO. // 0111 1 Zl I 1 . 11 AA A "Z

1 yyy .3 C C A 5 .5y

1 A A AA OA TAR 0 1 AO A Zl Uz .U 1 AQ A 0 1 yby.y C "Z

1 AA AA 1 00.00 1 "7 1 O"? /z4.d3 OAno 0 zuyz .

z

1 ATA O

, 1 y /y .y 5.0/

1 00.00 1 4.272 723.53 0 AO'Z A zUoj .

4

1 A T A A

1 y /o.y C T1 5. /I

1 00.00 1 1 . 703 722.71 2075 .4 1 952 .9 5.74

1 00.00 o. 5 /z T0 1 CO 721 .59 0 AiC C C zODD .

D

1 ACO A 1 y5z .

y

C Tt; 5. /D

1 00.00 5.731 720.55 2056.3 1 A >1 Z A

1 y43.

y

C TO

1 00.00 2.91

1

71 9.52 2046.

5

1 935.

0

5.77

1 1 0.00 34.556 721 .26 2082.4 1 975.8 5.39

1 1 0.00 31 .729 720.26 2073 .5 1 966.6 5.44

1 1 0.00 28.901 71 9.26 2065 .0 1 AC T A

1 95 / .4 C C A 5.50

1 1 0.00 26. 1 1

6

71 3.26 2056.

3

1 948.

2

5.55

1 1 0.00 25.1 22 71 7.90 2053.6 1 945.0 5 .58

1 1 0.00 23.877 71 7.44 2049.4 1940.8 5.59

1 1 0.00 20.485 71 5.20 2038.7 1 929.6 5.65

1 1 0.00 1 7.505 71 5.09 2028.9 1919.6 5.69

1 1 0.00 14.464 71 3.94 201 8.3 1 909.4 5 .73

1 1 0.00 1 1 .682 71 2.87 2009.5 1 900.0 5. 76

1 1 0.00 8.647 71 1 .70 1 999.3 1 889.7 5 .80

1 1 0.00 5.821 71 0.59 1989.6 1880.1 5.83

1 1 0.00 3.031 709.48 1 979.9 1 870.5 5.85

1 20.00 34.725 71 2. 1 5 2022.8 1920.8 5.31

1 20.00 31 .000 71 0.75 201 1 .

1

1 908.0 5.40

1 20.00 28.663 709.86 2003.0 1 899.9 5 .43

1 20.00 24.899 708.41 1 989.9 1 886.8 5 .46

1 20.00 20.438 706.65 1975.2 1 871 .

1

1 20.00 1 7.354 705 .42 1 964.4 1 860.

1

c 1

1 20.00 1 4 . 1 94 TA A 1 "Z 704. 1

3

1 AC "Z 0

1 y53 .z

1 OA Q Q

1 o4o.

0

•OP 120.00 11 .756 703.13 1944.4 1840.0 5.68

120.00 8.661 701 .84 1933.2 1828.7 5.71 120.00 5.368 700.44 1921 .8 1816.6 5.79

120.00 3.069 699.45 1912.4 1808.1 5.77

140.00 34.903 694.12 1905.1 1815.8 4.92

140.00 32.285 693.00 1395.5 1805.8 4.96

140.00 28.943 591 .55 1882.9 1793.0 5.02

140.00 26.339 690.41 1873.1 1782.9 5.06

140.00 22.925 688.89 1859.9 1769.4 5.11 140.00 20.345 687.72 1850.1 1759.2 5.17

143
Table 16. (Continued).

Velocities of sound from Younglove [107]

Temp

Pressure Dens i ty Vel . of Sound, m/s Di ff K MPa kg/m3 expt cal c %

140.00 17.664 686.49 1839.3 1748.4 5.20

140.00 14.149 684.84 1825.1 1 734.1 5.24

140.00 11 .218 683.45 1813.0 1722.1 5.28

140.00 8.444 682.10 1801.6 1 710.5 5.32

140.00 5.864 680.83 1790.6 1699.7 5.35

140.00 3.332 679.57 1779.5 1688.9 5.36

160.00 34.565 676.08 1788.3 1713.9 4.34

160.00 31 .986 674.83 1777.3 1 703.0 4.39

160.00 28.855 673.29 1764.7 1689.6 4.44

160.00 26.279 672.00 1753.7 1678.5 4.48

160.00 23.072 670.36 1739.5 1664.4 4.52

160.00 20.151 668.85 1726.9 1651 .4 4.57

160.00 17.530 667.46 1715.1 1639.5 4.61 160.00 14.481 665.82 1 701 .0 1625.5 4.64

160.00 8.699 662.61 1673.7 1598.4 4.71 160.00 2.970 659.29 1645.1 1570.6 4.75

180.00 34.078 658.06 1674.7 1614.5 3.73

180.00 31.939 656,88 1664.7 1604.5 3.75

180.00 29.069 655.27 1651 .3 1590.9 3.80

180.00 26.357 653.73 1638.4 1577.9 3.84

180.00 • 23.460 652.04 1624.0 1563.7 3.85

180.00 20.351 650.19 1608.5 1548.2 3.89

180.00 17.298 648.33 1593.2 1532.7 3.95

180.00 14.624 646.67 1579.4 1518.9 3.99

180.00 11.422 644.62 1562.0 1502.0 4.00

180.00 8.599 642.77 1546.2 1486.7 4.00

1 80 .00 5.902 640.96 1551 .6 1471 .9 4.05

180.00 2.978 638.95 1514.5 1455.4 4.06

200.00 34.672 640.69 1568.8 1522.8 3.02

200.00 34.484 640.53 1569.1 1521 .9 3.10

200.00 31 .631 638.80 1554.5 1507.2 3.14

200.00 29.363 637.35 1542.6 1495.3 3.16

200.00 25.937 635.12 1524.4 1477.0 3.20

200.00 24.001 633.83 1513.9 1466.5 3.23

200.00 20.329 631 .32 1493.4 1446.1 3.27

200.00 1 7.287 629.17 1475.7 1428.7 3.28

200.00 14.327 627.03 1458.2 141 1 .4 3.31 200.00 1 1 .454 624.88 1440.7 1394.2 3.33

200.00 8.259 622.42 1420.4 1374.5 3.34

200.00 5.175 619.96 1400.2 1354.9 3.34

200.00 2.291 61 7.59 1380.8 1336.1 3.35

220.00 35.007 623.23 1468.0 1432.6 2.47

220.00 32.297 621 .32 1452.6 1417.4 2.49

220.00 29.240 619.10 1434.9 1399.8 2.51 220.00 26.325 616.92 1417.6 1382.5 2.54

220.00 23.450 614.71 1400.0 1365.1 2.56

220.00 20.294 61 2.21 1380.2 1345.5 2.58

220.00 17.341 609.79 1361 .1 1 326.5 2.60

220.00 14.416 607.31 1341 .3 1307.2 2.60

220.00 1 1 .278 604.55 131 9,3 1285.8 2.60

220.00 8.261 601 .79 1297.4 1264.5 2.60

220.00 5.215 598.88 1274.4 1242.3 2.59

220.00 2.502 596.19 1252.9 1221 .7 2.56

240.00 34.746 605.29 1366.8 1341 .5 1 .89

144
Table 16. (Continued).

Velocities of sound from Younglove [1071

Temp. Pressure Dens i ty Ve 1 . of Sound, m/s Di f f K MPa kg/nP expt ca 1 c % 240.00 32.790 603.72 1354.8 1329.4 1.91 240.00 29. 186 600.73 1332.0 1306.6 1 .94 240.00 26.744 598.63 1316.0 1290.6 1.96

240.00 23.703 595.94 1295.4 1270.2 1 .98 240.00 20.621 593 . 1

0

1273.9 1248.9 2.00

240.00 1 8 . 1 27 590.72 1255.7 1231 .0 2.01 240.00 14.415 587.03 1227.4 1203.4 1.99

240.00 11 .607 584.09 1205.3 1 181 .6 2.01

240.00 8.064 580.20 1 175.7 1 152.9 1 .98 240.00 5. 102 576.75 1 149.6 1 127.6 1 .95 240.00 2.345 573.38 1 123.7 1 103.0 1 .88 260.00 35.001 587.63 1273.8 1256.0 1 .42 260.00 32. 123 584.98 1254.5 1236.5 1 .45 260.00 29.341 582.32 1235.1 1217.1 1.48

260.00 26.676 579.68 1215.7 1 197.9 1 .48 260.00 26.220 579.22 1212.3 1 194 .6 1 .48 260.00 23.713 576.63 1 193.4 1175.9 1 .49 260.00 20.287 572 .93 1166.5 1 1 49.3 1 .50 260.00 17.384 569.63 1 142.7 1 125.7 1 .51 260.00 14.786 566 .53 1 120. 1 1 103.8 1 .48 260.00 1 1 .579 562.50 1091 .5 1075.4 1 .50 260.00 5 .843 554.60 1 034.5 1020.3 1 .40 260.00 2.867 550.07 1 001 .4 989.0 1 .25 280.00 34.560 559. 15 1 1 O 1 c

1 181.5 1 168.5 1 1 r\1 . 10 280.00 32. 1 36 DDD.PO 1 1d3.4 1 1 50.

/

1.11

OO A A A 280.00 29.397 553 .57 1 1 >1 o c

1 1 4z .0 1 1 on o 1 1 "2 1.13

280.00 26.225 559.91 11 17.3 1 1 04.6 1.15

280.00 23. 573 556 .69 1 095 .3 1082.6 1.17

O O A A 280.00 20.751 553. 10 1070.5 1058.2 1.15

280.00 17.696 548.99 1042.4 1030.5 1.16 280.00 13.668 543. 14 1002.4 991 .5 1.10

280.00 1 1 .297 539.43 977.5 967 .0 1 .08 280.00 8.576 534.88 946.8 937.2 1 .03 280.00 5.555 529.40 910.0 90 1 .6 .93 280.00 1 .922 522.03 860.

1

854.3 .67 300.00 34.752 551 . 10 1098.2 1089.2 .83 300.00 31 .349 546.93 1071 .2 1061 .7 .89 300.00 29.489 544.55 1055.7 1045.

1

.92 300.00 28.732 543.55 1049.0 1039.6 .90 300.00 25. 120 538.61 1017.2 1007.7 .95 300.00 24.397 537.57 1010.4 1001 .0 .94 300.00 22. 137 534.23 989.

1

979.7 .95 300.00 20.804 532. 18 976.0 955.7 .97 300.00 19.782 530.57 965.7 955.5 .97 300.00 17.730 527.20 944.2 935.3 .95 300.00 17.569 526.93 942.3 933.5 .92 300.00 14.537 521.59 908.5 900.4 .90 300.00 14.149 520.87 904.0 896.0 .90 300.00 1 1.832 516.40 876.2 868.5 .88 300.00 1 1 .200 515.12 868.4 860.7 .89 300.00 9.608 51 1 .78 847.4 840.4 .82 300.00 8.167 508.57 827.6 821.1 .79 300.00 5.831 502.97 792.5 787.7 .62 300.00 5.504 502.14 787.5 782.7 .61 300.00 3.189 495.86 748.6 745.7 .38

Number of data points of Younglove [1071 = 162; rms deviation = 3.91^.

145
Table 16. (Continued).

Saturated liquid velocities of sound from Young love 1107]

Temp

Pressure Density Ve 1 . of Sound, m/s Diff.

K MPa kg/mi expt cal c %

90.000 .96855E-09 728.67 2106.2 1994.6 5.30

100.000 .25139E-07 718.44 2037.6 1925.7 5.49

110.000 ,3451 1E-06 708.26 1969.2 1860.0 5.54

120.000 .29481E-05 698.12 1900.8 1796.7 5.48

130.000 .17534E-04 687.99 1832.6 1735.0 5.32

MO. 000 .78671E-04 677.87 1764.9 1674.6 5.12

150.000 .28235E-03 667.72 1697.4 1614.9 4.86

160.000 .84700E-03 657.51 1630.3 1555.8 4.57

170.000 .21959E-02 647.23 1563.3 1497.0 4.24

180.000 .50497E-02 636.85 1496.5 1438.3 3.89

190.000 .10512E-01 626.33 1430.0 1379.7 3.52

200.000 .20133E-01 615.66 1364.4 1320.9 3.19

210.000 .35944E-01 604.78 1298.5 1261.9 2.82

230.000 .96633E-01 582.27 1 167.1 1142.8 2.09

250.000 .21783E+00 558.44 1036.5 1021.8 1.42

260.000 .31060E+00 545.88 971.6 960.4 1.16

270.000 .43042E+00 532.78 905.4 898.3 .79

290.000 ,76931E+00 504.56 775.1 771.5 ,47

Number of saturated liquid data points of Younglove [107] = 18; rms deviation = 4.02^.

Saturated 1 iqu id velocities of sound from Rao 1 721

Temp. Dens i ty Vel . of Sound, m/s Diff.

K kg/m3 expt cal c %

140.000 677.87 1528 1674 -9.52

145.000 672,80 1499 1644 -9.71

150.000 667.72 1469 1614 -9.91

155.000 662.62 1439 1585 -10.13

160.000 657,51 1409 1555 -10.37

165.000 652.38 1379 1526 -10.62

170.000 647.23 1350 1496 -10.89

175.000 642.06 1320 1467 -1 1.17 180.000 636.85 1290 1438 -1 1.47

185.000 631.61 1260 1409 -11.78

190.000 626.33 1230 1379 -12.10

195.000 621.02 1200 1350 -12.44

200.000 615.66 1 171 1320 -12.79

205.000 610.25 1 141 1291 -13.16

210.000 604.78 1111 1261 -13.54

215.000 599.26 1081 1232 -13.93

220.000 593.67 1051 1202 -14.33

225.000 588.01 1021 1 172 -14.75

230.000 582.27 992 1142 -15.18

Number of data points of Rao [72] = 19; mean deviation = 11.99^.

146
Table 16. (Cont-1 nued)

.

Velocl+Ios of sound from L acam louj

T —

1 - OQQ 1 R 1/ zyo .15 !\

Pressure Uens 1 ty vel . of Sound, m/s U 1 ft . MPa kg/(tv5 expt ca 1 c

1 ^\^ "^x

1 « ij 1 jJ) ^ OO 7 4yz • Z 5 70 A 11 4

71 A /I y RQ

/ AR 4y5 .35 7 y1 O

/ 4z 717 737 R C .55

;l AO o o 4yo. zo 758 7R C 755 .38 4.0530 K A 1 Ac: 5'Jl .05 1 /4 77 1 / /I 7 O .32

4. j5 /U CA1 Qc; 5U1 .o5 7 7 O

/ /o 7 7^; oo • ZZ

5 .Uooj AT 5Uj .do 7 AA /yu 7Q7 TR . 35

A "7 OK o.u /y? CA^; 1 A 5Ud. 1

y

OU4 QAO oUz oo • ZZ

/ • uy/co RAQ RA 5Uo .5y Q1 A oi y

Q 1 ^ Ol D OQ .Zo

Q 1 r\£^r\ o • 1 'Jou CIA OA 51 u.yu o3 3QXf\ o3U OQ • Zo O 11 =^1 7 17 5 1 J>. 1 Z

Qil 7 04 / £3/ A 044 XA • J>4

1 A 1 "^oc;

1 U. 1 jZ? m R 7R 51 5 . Z5 oDU QR 7 05 / r X • J J

1 'J f^C^^i^

1 Z .O05O CO A OQ 5ZU. Zo PQ'7 oyj ODO .50

15.1 ybo CO /I QX 5Z4. yj OO /I yz4 Q1yi O

7 7 » 1 1

1 /• / ji

y

ROQ 5Zy Ofi .ZD y5j Qyl A y44 QA •y4 on Of^^A /U » ZOjU RT"^ XO 5j J . jZ Q7Q y /y yoy •y4

0 ^i T R/l 54UA 77 . /

/

1 A1 7 1 A 1 7 _ AR •U5 30.3975 547.49 1070 1061 .81 35.4638 553.63 1110 1102 .72 40.5300 559.30 1146 1140 •52 50.6625 569.51 1214 1209 •35

fin 7Qsn 1 97'i 1

1 z979/ z

1 7

^ OD . UO 1

t J-J ^^l1 »n9

Q1 Afinn 1

1 JOM- '^RA • Vm* J

Q1 1 09=1 1 H JZ _ 1 Q

1 U 1 . JZ fin 7 7ft 1 HOZ 1 HO 1

T -

1 _3Z-^ . t J I\

O AO*^"^ RA 1 1 RRO 55Z RRQ 550

11 cc -ZQ

\J O 1 J OJ - 7fl 40U . 1

z

fins DUO fino • zo

A '^R7n 40idfil

1 ^R . 45 D 1 5

fil D fi

1 O

— • 9RZy

A<^fi"< 3 .UODJ 404 . 4Z *^''?0 DjZ (^X 1 • U 1 0 .u /yD 4DO. JO ^;ro d5z fiRO D5Z _ AQ •uo

~7 AQ9 Q / 70 Afi 4 /Z .Uo fi70 fi71 0 / 1 •uzno

o 1 A^A o . 1 UdU 4/5 >1 7 R AQ •4y QR oy5 oyu 7A oil y» 1 1 yj >1 7Q 7X 4 / O . / J 7AQ /uy 7A7 • 97Zj

1 A 1 "ZO R y1 Q 1 "70 40 1 . /O 70 7 /z / 70 X /Z J

>1*7 • 4j

1 Z.DDDD /loo ~7^ lob /ol RO • 5Z

15.1 yob vIOR A1 4y5 .Ul QA'^ oU3 /yo 7Q

17 7 7 1 Q R AA fiQ QXA oj4 QOQ ozo • OJ

7A 0<;RA ZU« Zt35U RAR QQ 5U5. oo 004 QRQ 050 • OJ

Z5 .J J 1 J

R 1 R 1 Q 5 1 5. 1 O :^ 1 oQ1 9 y 1 z . R^50

7A '7Q7'^ JU . j>y / 5 RO X X~I yoD yo 1 • 4j

35.4638 530.71 1011 1006 .43 40.5300 537.37 1052 1048 .37

50.6625 549.1

7

1126 1123 •24 60.7950 559.43 1192 1 190 • 12 70.9275 568.54 1252 1251 •02

81 .0600 576.77 1308 1308 -.02

91 .1925 584.29 1360 1360 -•06

101 .3250 591 .22 1408 1410 -.15

147
Table 16. (Continued).

Velocities of sound from L acam [601

T = 398.15 K

Pressure Density Vel. of Sound, m/s DIff

.

MPa kg/rn3 expt cal c %

1 .0133 14.50 266 271 -1 .99

2.0265 31 .37 251 255 -1 .66 3.0398 51 .77 234 237 -1 .36

4.0530 78.25 212 216 -1 .97 4.3570 88. 18 205 209 -2 .08 5.0663 1 1 7.53 192 1 92 -.51 6.0795 184.72 182 183 -.70

7.0928 255.72 223 214 3.61 8.1060 297.38 273 262 3.73

9, 11 93 322.88 313 306 3.53

10.1325 340.13 356 344 3.17

12.6656 368.33 433 420 2.80

15.1988 388.02 493 480 2.45

17.7319 402.65 542 531 1 .96 20.2650 41 4.55 589 575 2.31 25.3313 433.45 661 650 1 .57 30.3975 448.32 723 71 4 1.18

35.4638 460.69 788 770 2.22

40.5300 471 .31 827 820 .74

50.6625 489.04 914 909 .49

60.7950 503.61 990 986 .34 70.9275 516.04 1056 1055 .05

81 .0600 526.93 1117 1118 -.09

91 .1925 536.65 1174 1175 -.14

101.3250 545.44 1226 1229 -.27

T = 423.15 K

1 .0133 13.46 277 282 -1 .81 2.0265 28.59 265 269 -1 .61 3.0398 45.87 252 255 -1 .55 4.0530 66.15 238 241 -1 .49 4.3570 73.02 233 237 -1 .74 5.0663 90.88 223 226 -1 .60 6.0795 122.1

7

213 213 -.31 7.0928 161 .20 211 209 .80

8.1060 203.00 218 220 -1.14

9.1193 239.42 243 242 .40

10.1325 268.58 275 268 2.28

12.6656 316.39 352 341 3.07

15.1988 345.24 41 5 405 2.38

1 7.7319 365.56 468 459 1 .80 20.2650 381 .26 51 5 506 1 .56 25.3313 404.99 597 587 1 .63 30.3975 422.89 660 654 .81 35.4638 437.37 716 713 .36 40.5300 449.59 75 7 765 -1 .18 50.6625 469.59 854 857 -.43

60.7950 485.72 931 937 -.65

70.9275 499.33 1000 1007 -.76

81 .0600 51 1 .14 1064 1071 -.72

91.1925 521 .61 1 124 1130 -.57

101 .3250 531 .02 1 180 1 185 -.43

148
Table 16. (Continued).

Velocities of sound from Lacam [601

T = 448.15 K

Pressure Dens i +y vel Mra kg/iTv5 expt

1 . U 1 JJ

O Q 7 ZO / Z . U/C O J ZD. J / 9 71^ Z /9 J . Ujyo 4 1 • ?y ZDZ

Do . jy Z9(J 4 . /U D4 . 1 U

9 yl 7 z4 /

!3 .UDDJ / / . 04 9 >1 1 z41

D .u /yj yy .yj 9ZJO

"7 AQOQ 1 ZP . Z

J

Z94

Q01 n^n .

1

udu 1 c^"^ 07 1 3 J . Z / z 99

Q 11 Q'^ y. 1 1 y^ 1 uz . 1 Z

9 7 Q ZJO

in 1 "^^s zvjy . ZD 9/1 Z4 7/ 9^'^ (CO ZDJ>.O0 jU4

15.1988 301 .13 364

1 7.7319 327.55 417

20.2650 347.46 463

25.3313 376.53 540

30.3975 397.69 UV o 35 .4638 414.41

40.5300 til o . 790

50.6625 450.60 81

0

60 . 7Q50 468.32 RRR

70. 9275 483. 1

0

QSR

RiCJ 1 .nfifin . \J\J\J\J 4Q'S . R9 1 099

Q1 1 Q?'! SOT (T^ 1

1 nH9 uoz

1 01 . 3250 51 7.06 1 1 38

1 t / J . I J

1 01 "V^ 1

1 11 . 39oz 9QQ z yy

94Z4. 95 zyu 9Qn

9 7 JO .z / ZoU

RX 1 X 971 z / 1 4 • J? J /U 9 / . 04 zoy

Oy • J4 Z04

D • U / Q7 AQ 9RQ zjy

1 UD . 9U Z JD

19 7 Af^

1 Z / . 40 Z99

Q 11 QT 1 4y . 44 z9D

in 1 "^0=% 171 R/1

1 / 1 94 9^1 ZD 1

1 0 ^^^R^^ 1 Z • DDVO 99 1 RQ ZZ 1 . 90 901 zy 1 1 R 1 QQQ yoo ZD9*^1 rii

1 .U 1 J J / 17.7319 291 .23 380

20.2650 314.61 424

25.331

3

348.69 500

30.3975 373.09 564

35.4638 392.05 621 40.5300 407.57 674

50.6625 432.19 767

60.7950 451 .47 846

70.9275 467.39 916

81 .0600 481 .01 980

91 .1925 492.93 1040

101 .3250 503.56 1096

DIff

.

cal c

292 -1.74

281 -2.44

271 -3.59

260 -4.32

257 -4.28

250 -3.78

240 -1.83

233 .19

232 1 .04 239 -.54

252 -2.36

298 1.70

352 3.16

404 3.01

451 2.41 533 1.13

603 .79 663 .51 717 .35

811 -.17

892 -.49

964 -.64

1029 -.70

1088 -.62

1144 -.54

301 -.81 293 -1 .04 284 -1.74

276 -2.13

274 -1 .99 268 -1 .81 261 -.91 255 .20 252 1.01 253 1.03

258 .80 288 .87 327 2.96

369 2.69

412 2.67

491 1 .64 560 .57

621 -.10

676 -.31

771 -.53

852 -.82

925 -1 .04

991 -1.13

1051 -1.09

1107 -1.01

149
Table 16. (Continued).

Velocities of sound from Lacam (601

T = 498.15 K

Uc^ 1 1 o 1 1 y 01 OOUIIU y (ll/

0

u 1 T T , fir a ex pt ca 1 C h

1 . u 1 J J 1111.101 1 n — mil ^n 1 _ R9

9Q 'i ~. DO

A ns'^io £.00 9Qn — Q9

H . / u . 'J / <CO / _ ft9 P . UDDj in 9P9 9Q^ - .csy 97P 97 Q "^n

/ . uy/o y4 . J / 97/ 97yl

I. /4 nc; -•UP

c 1 n^A 0 • 1 UDU 111 /19 97^ 97 1 • / 1 y . 1 1 yJ

1 90 17 1 zy • 1

/

97X Z /U • yo

1/17 9D 14 / . ZO 97 c: 979 Zl Z. no

1 on on 1 yu »yy zyj 9nn .80

15.1 ybo 90Q f^>1 1 n J 1 y

1 0^ 1 .06

1 "7 "7 1 n o c^n "^c Z5y .3o Xi^n 3dU 1 .oo 20.2650 284.50 395 389 1.47 25.3313 322.27 465 461 .84 30.3975 349.50 529 527 .29 35.4638 370.53 586 587 -.22

40.5300 387.62 640 641 -.23

50.6625 414.44 734 736 -.34

60.7950 435.22 814 818 -.58

70.9275 452.25 885 891 -.74

81 .0600 466.73 948 957 -1.00

91.1925 479.34 1009 1017 -.89

101.3250 490.54 1065 1074 -.85

Number of data points of Lacam 1601 = 174; mean deviation = 1.06^.

150
Table 17. Calculated P(T) tsochores of propane.

Temp. Pressure

K MPa

305.514 1 . 1 433

310.000 1 . 1 704

318.000 1.2178

326.000 1 .2644

334.000 1 .3102

342.000 1 .3555

350.000 1.4004

358.000 1 .4449

366.000 1 ,4890

374.000 1 .5328

382.000 1 .5764

390.000 1 .6197

398.000 1 .6629

406.000 1 .7059

414.000 1 . 7487

422.000 1 .7913

430.000 1 .8338

438.000 1 .8762

446.000 1 .9185

454.000 1 .9607

462.000 2.0028

470.000 2.0448

478.000 2.0867

486.000 2.1286

494.000 2.1 703 502.000 2.2120

510.000 2.2537

51 8.000 2.2953

526.000 2.3368

534.000 2.3783

542.000 2.4197

550.000 2.461

1

558.000 2.5024

566.000 2.5437

574.000 2.5850

582.000 2.6262

590.000 2.6674

598.000 2.7085

606.000 2.7496

614.000 2.7907

622.000 2.8318

630.000 2.8728

638.000 2.9138

646.000 2.9548

654.000 2.9957

662.000 3.0366

670.000 3.0775

678.000 3.1 184 686.000 3.1593

694.000 3.2001

Propane 1 sochore at 25 kg/irr^

1 sotherm

L'tjr 1 vo T 1 ve

.79392 .03402

.80096 .Q3544

.31 244 .03 78L .82279 .0401

6

.83222 .04233

.84086 .04455

.84882 .04667

.85620 .04376

.86306 .05081 .86946 .05285

.87546 .05483

.881 08 .05680

.88637 =05876

.89136 .06071 .89607 .06263

.90052 .06455

.90475 .06645

.90876 .06834

.91257 .07023

.91621 .0721

0

.91967 .07396

.92297 .07582

.92613 .07767

.9291

5

.07952

.93204 .081 35 .93481 .0831

9

.93747 .08501 .94002 .086 R4 .94247 . U O OvJ_/ .94483 CiQCiAl .94 71

0

nQ99P

.94929 DQ/IOR

.95139 • \J^ J oo .95342 .U^ / DO

• 95538

.95727 1 ni 97 .95910

.96087

.96258

.96423 . 1 0840

.96583 .11018

.96738 . 1 1 1 96

.96889 .1 1373

.97034 .11550

.97175 .11727

.97312 .11904

.97446 .12080

.97575 .12257

.97700 .12433

.97822 .12609

1 C /^V\ r- 1^

1 sochore

L/feJl 1 Va r 1 V© Curvature

I'lr a / r\ MPa /k* 2 ("ira/N

— nrinn99fl .00599 — . nonni UUUU 1 0

J

.00587

.00577 — nooni Oft ~ . uuuuuoo

.00558 — nnnnnfti .00554 . V W»J L/V-' .00550

.00546

.00543

.00541 -.000003?

.00538 -.0000028

.00536

.00534 -.0000023

.00532 -.0000021

.00531 -.000001

9

.00529 -.000001

8

.00528 -.000001

6

.00527 -.000001

5

.00526 -.000001

4

.00524 000001

.00523 - 0000019

.00523 -.000001

1

.00522 - 000001

o

.00521 - 000001

.00520 — OOOOOOQ

.0051

9

— • ooooooo UUUU*^'U>

. nnVJU '=ii J 1 Qy ~ • UUUUUUo

• \J\JJ I o — • uuuuuuo

nnsi 9. 9\J\J J 1 O _ C\c\(\c\r\(\n "•UUuUUU

/

.nnsi

7

• uuuuuu

nnsi ft " •uuuuuu

• UUUUUUD

. UU J 1 J ~ •UUUUUUO

—•UUUUUUD

. \J\JD 1 J — .UUUUUUD

.'Jv J 1 ^ ""• UUUUUUD

— •UUUUUuI?

— • OOOOOOR UUUUUU-)

.00513 -.0000004

.0051

3

-.0000004

.00512 -.0000004

.00512 -.0000004

.00512 -.0000004

.0051

1

-.0000004

.00511 -.0000004

.0051 -.0000003

.00511 -.0000003

.00510 -.0000003

151
Table 17. (Continued).

Propane I sochore at 50 kg/in-

! sotherm 1 sochore 1 sochore

Temp. Pressure Z Der I vat i ve Der i vat 1 ve Curvature

K MPa iMPaTn3/kg ^Pa/K MPa/K^

333.423 2.1277 .67690 .02371 .01 412 -.000081

9

334.000 2.1 358 .67831 .02 395 .01 408 -.0000787

342.000 2,2463 .69670 .02707 .01357 -.000051

1

350.000 2.3534 .71 324 .02996 .01 322 -.0000377

358.000 2.4581 .72832 .03269 .01 296 -.000029/

356.000 2.5609 .7421

8

.03533 .01 274 -.0000243

374.000 2.6621 .75501 .03789 .01256 -.0000203

382.000 2.7620 .76694 .04039 .01 241 -.00001 74 390.000 2.8608 .77808 .04283 .01229 -.0000150

398.000 2.9586 .78851 .04524 .01 217 -.00001 32 406.000 3.0556 .79831 .04760 .01207 -.00001 16

41 4.000 3.1518 .80754 .04994 .01 199 -.00001 04

422.000 3.2474 .81625 .05225 .01 191 -.0000093

430.000 3.3423 .82449 .05453 .01 184 -.0000084

438.000 3.4368 .83230 .05679 .01177 -.0000076

446.000 3.5307 .83971 .05904 .01 171 -.0000069

454.000 3.6242 .84676 .06126 .01 166 -.0000063

462.000 3.71 73 .85348 .06347 .01 161 -.0000058

470.000 3.8100 .85988 .06566 .01 157 -.0000054

478.000 3.9024 .86599 .06784 .01 153 -.0000050

486.000 3.9945 .87182 .07001 .01 149 -.0000046

494.000 4.0863 .87741 .0721

7

.01 1 45 -.0000043

502.000 4.1 777 .83276 .07432 .01 142 -.0000040

510.000 4.2690 .88789 .07645 .01 1 39 -.0000037

51 8.000 4.3600 .89281 .07858 .01 136 -.0000035

526.000 4.4508 .89754 .08070 .01 1 33 -.0000033

534.000 4.5413 .90209 .08281 .01131 -.0000031

542.000 4.631

7

.90646 .08491 .01 128 -.0000029

550.000 4.7219 .91067 .08701 .01 1 26 -.0000028

558.000 4.8119 .91 472 .08910 .01 1 24 -.0000026

566.000 4.9018 .91 863 .091 1

8

.01 122 -.0000025

574.000 4.991

4

.92240 .09326 .01 1 20 -.0000023

582.000 5.081

0

.92604 .09533 .01118 -.0000022

590.000 5.1 704 .92955 .09740 .01117 -.0000021

598.000 5.2596 .93295 .09946 .01 1 15 -.0000020

606.000 5.3487 .93623 .101 52 .01113 -.000001

9

61 4.000 5.4377 .93941 .10357 .01 1 12 -.000001

9

622.000 5.5266 .94249 .10562 .01 1 10 -.0000018

630.000 5.6154 .94546 .10766 .01 109 -.0000017

638.000 5.7041 .94835 .10970 .01 108 -.0000016

646.000 5.7926 .951 14 . 1 1 1 73 .01 106 -.0000016

654.000 5.881

1

.95386 .1 1377 .01 105 -.0000015

662.000 5.9694 .95649 .1 1579 .01 104 -.0000015

670.000 6.0577 .95904 .11782 .01 103 -.000001

4

678.000 6.1459 .96152 . 1 1 984 .01102 -.0000014

686.000 6.2339 .96393 .12185 .01 101 -.0000013

694.000 6.3219 .96626 .12387 .01 100 -.0000013

152
Table 17. (Continued).

Propane I sochore at 100 kg/ir^

1 sotherm 1 sochore 1 sochore

Temp. Pressure Z Der i vat i ve Der 1 vat 1 ve Curvature

K MPa r>^a'm3/kg MPa/K MPa/K^

358.586 3.4591 .51 162 .00877 .03366 -.0003702

366.000 3.7013 .53634 .01224 .03190 -.0001643

374.000 3.9519 .56042 .01558 .03085 -.0001056

382.000 4.1957 .58253 .01875 .03013 -.0000780

390.000 4.4344 .60304 .02182 .02957 -.000061

7

398.000 4.6692 .62220 .02481 .02913 -.0000507

406.000 4.9007 .64018 .02776 .02876 -.0000428

41 4.000 5.1294 .6571

2

.03067 .02844 -.0000368

422.000 5.3558 .67311 .03355 .02816 -.0000321

430.000 5.5801 .68826 .03640 .02792 -.0000233

438.000 5.8026 .70263 .03922 .02771 -.0000253

446.000 6.0235 .71629 .04202 .02752 -.0000227

454.000 6.2429 .72930 .04481 .02734 -.0000205

462.000 6.461

1

.741 71 .04753 .02719 -.0000187

470.000 6.6780 .75357 .05033 .02704 -.0000171

478.000 6.8938 .76490 .05307 .02691 -.0000157

486.000 7.1086 .775 75 .05580 .02679 -.0000145

494.000 7.3225 .7861

5

.05851 .02668 -.0000135

502.000 7.5355 .79613 .06122 .02658 -.0000125

510.000 7.7477 .80571 .06391 .02648 -.00001 17 518.000 7.9592 .81492 .06660 .02639 -.0000109

526.000 8.1700 .82378 .06928 .02630 -.0000103

534.000 8.3801 .83231 .07195 .02622 -.0000097

542.000 8.5896 .84052 .07461 .0261

5

-.0000091

550.000 8.7985 .84844 .07726 .02608 -.0000086

558.000 9.0069 .85608 .07991 .02601 -.0000082

566.000 9.2147 .86345 .08254 .02595 -.0000078

574.000 9.4220 .87058 .08518 .02589 -.0000074

582.000 9.6289 .87746 .08780 .02583 -.0000071

590.000 9.8353 .88412 .09042 .02577 -.0000068

598.000 10.0413 .89056 .09304 .02572 -.0000065

606.000 10.2468 .89679 .09565 .02567 -.0000062

614.000 10.4520 .90283 .09825 .02562 -.0000060

622.000 10.6568 .90868 .10085 .02557 -.0000057

630.000 10.8612 .91435 .10344 .02553 -.0000055

638.000 1 1 .0652 .91 985 .10603 .02549 -.0000053

646.000 1 1 .2690 .92518 .10861 .02544 -.0000051

654.000 1 1 .4724 .93036 .11119 .02540 -.0000049

662.000 1 1 .6754 .93538 .11376 .02537 -.0000043

670.000 1 1 .8782 .94027 .1 1633 .02533 -.0000046

678.000 12.0807 .94501 .11889 .02529 -.0000045

686.000 12.2829 .94962 .12145 .02526 -.0000044

694.000 12.4848 .95411 .12401 .02522 -.0000042

153
Table 17. (Continued).

Propane I sochore at" 150 kg/m1 sotherm 1 sochore 1 sochore

Temp. Pressure Z Der I vat i ve Derivative Curvature

K MPa r<Pa'm3/kg MPa/K MPa/K^

367.611 4.0763 .39207 ,00180 .05500 -.0014623

374.000 4.41 44 .41733 .00465 .051 72 -.0002530

382.000 4.821

.44630 ,00795 .05027 -.0001355

390.000 5.2201 .47326 ,01124 .04937 -.0000942

398.000 5.6123 .49859 ,01452 .04871 -.0000 725 406.000 5.9999 ,52252 ,01781 .04819 -.0000588

414.000 6.3037 .54520 ,02111 .04776 -.0000494

422.000 6.7643 ,56675 .02441 .04740 -.0000425

430.000 7.1 421 ,58728 ,02771 .04708 -,0000372

438.000 7.51 76 .60686 .031 03 .04630 -.0000331

446.000 7.8909 ,62557 ,03434 .04655 -.0000297

454.000 8.2624 .64348 ,03766 ,04632 -.0000269

462.000 8.6321 .66063 ,04098 ,04611 -.0000246

470.000 9.0003 ,67708 .04430 ,04593 -.0000226

478.000 9.3669 ,69287 ,04762 ,04575 -.0000210

486,000 9.7323 ,70805 .05094 ,04559 -.0000195

494.000 10.0964 ,72264 .05426 ,04544 -.0000182

502.000 10.4593 ,73669 .05759 ,04530 -.00001 71 510.000 10.8212 .75022 ,06090 .04516 -.0000162

518.000 11.1820 .76326 ,06422 .04504 -.00001 53 526.000 1 1 .5418 .77584 ,06754 ,04492 -.0000145

534.000 1 1 .9007 .78798 .07086 ,04481 -.0000138

542.000 1 2.2587 .79970 .07417 .04470 -.0000132

550.000 12.61 59 .81 103 .07748 .04459 -.0000126

558.000 12.9722 .82199 ,08079 ,04450 -.0000121

566.000 13.3278 .83258 ,08409 .04440 -.00001 17 574.000 13.6826 .84283 ,08739 .04431 -,0000112

582.000 14.0368 .85276 ,09069 .04422 -,0000108

590.000 1 4.3902 ,86238 ,09399 .04414 -.0000105

598.000 14.7429 .87170 ,09728 .04405 -.00001 01 606.000 1 5.0950 ,88073 .10057 .04397 -.0000098

61 4.000 15.4465 ,88950 .10385 .04390 -.0000095

622.000 15.7974 ,89800 .10713 .04382 -.0000093

630.000 16.1476 ,90626 .11041 .04375 -.0000090

638.000 1 6.4973 ,91427 .11368 .04368 -.0000088

646.000 16.8465 ,92206 .1 1695 .04361 -.0000086

654.000 1 7 . 1 950 .92963 .12022 .04354 -.0000084

662.000 17.5431 ,93698 .12348 ,04347 -.0000082

670.000 17.8906 .94413 .12674 ,04341 -.0000080

678.000 13.2376 ,95109 . 1 2999 .04335 -,0000078

686.000 18.5841 ,95786 . 1 3324 ,04328 -,0000076

694.000 18.9302 .96445 .13648 ,04322 -,0000075

I

154
Table 17. (Con M nued)

.

Propane I sochore af 200 kg/irr^

1 o<j 1 rtcJi III 1 socnore 1 sochore

Temp 1 1 ^17 O O U 1 c 2 nor* I \/ S4'f" I uoi 1 vdT 1 vr3 Curval'ure

K MPa MPa • m3 /k n MPa/K MPs /K 2

369.794 4 .2430 .30427 . 00004 n74Q4 — Dl fil 07^^ . V t O 1 / ^ 374 .000 4. 5495 .32258 .001 70 n79 9Q - . AnA1f^A7 WUU ! 04 / 382.000 5. 1 241 .35571 .0051

9

• 0 71 48 390.000 5.6941 •3871 7 .008R7 • 071 04 - nnnodRA

398. 000 6.261

1

.41717 • 01 266 0 7n 79 - nnnn'^Rn 406 .000 6.8258 .44583 • 1 "J > n7nA7 - nAnn9QA

41 4.000 7.3886 .47327 .02050 •07025 -.nnnfi9R9

422.000 7.9499 .4995 7 .02450 n7nnf^ - nnnn99R

430.000 8 • 5097 .52479 .02855 — . nrion9nfi UUUUZUD

. WJ Z U-J • UD^ / -> - AAAAI Q1 9.6254 .57231 • UU ^ JO in 1 ai s . U4UO^ • U Q y4 4 - AAAAI 71

• O 1 DZO nARDR • UD VJ) 1 _ AAAA 1 ft >1 ~. UUUU 1 04

A7n nnn 1 1 9QnA .U4yz nAQ9 j> • uoy i o _— AAAAI R Q • UUUU 1 90

/17Q nnn 1 1 • O J 7nA t U4 • n^^onA UD^UD — .UUUU AAA A 1 Rt 99

&.9,fs nnn 1 7 ^Q'S'^ .O /o_?4 • \JJ / D4 • U D O V4 — . AAAAI UUUU 1 AQ4y

AQA nnn 1

1 "?Z QA^A

•

^HOH .Dy4y

/

» uo 1 oo ni^^QPO • UDOO^C _~. AAAAI UUUU A R 1 49

^c\o nnn 1 /IQf^A . 71 70R / 1 /yv A Aft 1 A n*^Q 7n •UDO /U _—.UUUU AAAAI A 9 1 4Z Kin nnn 1 '4 . U4^0 A 7A"^^ nf^QRQ • UDo^y .—.UUUU AAAA11 jy

c 1 Q nnr\ D 1 o •UUU 1 4 . 5 yJ y

1 A H 1 . /4 / 1 1 A7/1 c^Q •Udo4o AAAA 117 -•UUUUl 9

/

5/0 • UUU 1 D . 1 4 1 J

7£^ T TC^ A7QQ>1 A AA A 1 1

C

-.00001 99

yj)4 •UUU 1 3. oo /y 7 70A c; AQ'^ An •UOOZD AAAA1 11 -.UUUUl 33

c_)hZ / 9 •UUU nnn 1 O'^'^R

1 D . Z JJJ 7Q/10R . /y4zD AQ 7TR • UO /j9 •UOO 1

D

_— AAAAI 1^ .UUUUl J 1 -?yU» nnn UUU ^ f: 11 OA •ouoy QnpQ7

/

AQ1 ftl »uy 1 D

1

•UOoUD _ AAAAI 9Q —.UUUUl zy

t^t^^Q nnn OOo* UUU 1 7 "^OOyl

1 / . JZZ4 • csz jzj AQC Q7 70c;

• Uo /V!) - AAAAI 9Q .UUUUl ZO

cjs;^: yOD« nnn UUU 1 / .00-50 .OJ /U4 1 AA1 A

• 1 UU 1 4

n^^ 7Q^ • Uo loO _— AAAA1 9ft

. UUUU 1 zo

A nnn I O . 4UoU Qcn A'^ •

1

1 AAw44UAA • n^^77R UO / /9 —— AAAAI 9R .UUUU 1 Z9 Kp9 !?dZ •UUU nnn \ o . y4yo . 00J4z 1 AQftft • 1 UODO • Uo /D9 _ AAAAI 9

/

—. UUUU 1 Z4 son^U • nnn UUU 1 Q AQr>A 1 y . 4yu4 . o /OUZ. 1 1 9QT n^; 7c=;c; • uo / 00 _ AAAAI 9"^ —.UUUU 1 Z9

c^QQ pyo • nnn UUU zu .

U

jU J .OotSz ?

1 1 71 Q • 1 1 / 1 y • Uo /4-? _ AAAAI 9

1

— . UUUU 1 Z

1

ftnf=^ OUD • nnn UUU 9nz'j . SftQ7 jDy / .yuu 1

/

•

1

1 91Z 1 AR49 n^ 77^^ • uo / J>D —— .UUUU AAAAI1 9AZU

(^1 A nnn 91 1 nH9 Q1 IftR • n^UD 77f^ / D 622.000 21 .6459 .92285 .12996 .06717 -.00001 18 630.000 22.1829 .93373 .13421 .06707 -.00001 17 638.000 22.7191 .94431 •13845 .06698 -.00001 16 646.000 23.2545 .95460 .14270 .06689 -.00001 15 654.000 23.7893 .96460 .14694 .06680 -.00001 14 662.000 24.3233 .97434 .151 17 .06671 -.00001 13 670.000 24.8566 .98381 .15540 .06662 -.00001 12 678.000 25.3892 .99303 .15963 .06653 -.00001 1

1

686.000 25.9210 1 .00201 .16385 .06644 -.00001 10 694.000 26.4522 1 .01076 .16807 .06635 -.0000109

155
Table 17. (Continued).

Propane I sochore at 220.486 kg/in^

1 sotherm 1 sochore 1 sochore

Temp. Pressure Z Der ivatlve Derivative Curvature

K MPa MPa '103 /kg MPa/K MPa/K^

369.850 4.2475 .27625 0.00000 .081 13 -.0000000

374.000 4.5841 .29484 .001 73 .081 12 -.0000007

382.000 5.2331 .32953 .00554 .08111 -.0000020

390,000 5.8819 .36278 .00958 .08109 -.0000031

398.000 6.5306 .39469 .01378 .08106 -.0000041

406.000 7.1 789 .42533 .01808 .08103 -.0000051

414.000 7.8270 .45477 .02247 .08098 -.0000059

422.000 8.4747 .48306 .02692 .08093 -.0000067

430.000 9.1 219 .51028 .03143 .08088 -.0000074

438.000 9.7687 .53648 .03598 .08081 -.0000080

446.000 10.4149 .56171 .04057 .08075 -.0000086

454.000 1 1 .0606 .58603 .04519 .08068 -.0000091

462.000 1 1 . 7057 .60947 .04984 .08060 -.0000096

470.000 12.3502 .63208 .05452 .08052 -.0000100

478.000 12.9941 .65390 .05921 .08044 -.0000104

486.000 13.6373 .67497 .06392 .08036 -.0000107

494.000 14.2798 .69533 .06864 .08027 -.00001 10 502.000 14.9216 .71 500 .07338 .0801

-.00001 13 510.000 15.5627 .73402 .07813 .08009 -.00001 15 518.000 16.2030 .75242 .08288 .08000 -.00001 18 526.000 16.8426 .77022 .08764 .07990 -.00001 19 534.000 17.4814 .78746 .09241 .07981 -.0000121

542.000 18.1195 .80416 .09718 .07971 -.0000122

550.000 18.7568 .82033 .10195 .07961 -.00001 24 558.000 19.3932 .83601 .10673 .07951 -.0000125

566.000 20.0289 .85121 .11151 .07941 -.00001 26 574.000 20.5638 .86595 .11 629 .07931 -.0000126

582.000 21 .2979 .88025 .12106 .07921 -.00001 27 590.000 21 .9311 .89413 .12584 .07911 -.0000127

598.000 22.5635 .90761 .13061 .07900 -.00001 28 606.000 23.1952 .92070 .13539 .07890 -.0000128

614.000 23.8260 .93342 .14016 .07880 -.00001 28 622.000 24.4560 .94578 .14492 .07870 -.0000128

630.000 25.0851 .95779 .14969 .07859 -.00001 28 638.000 25.7135 .96947 .15445 .07849 -.0000128

646.000 26.3410 .98083 .15920 .07839 -.00001 28 654.000 26.9677 .99188 .16396 .07829 -.0000127

662.000 27.5936 1 .00264 .16870 .07819 -.0000127

670.000 28.2187 1.01311 . 1 7344 .07808 -.0000127

678.000 28.8430 1 .02330 .17813 .07798 -.00001 26 686.000 29.4664 1.03323 .18291 .07788 -.0000126

694.000 30.0891 1 .04290 .18764 .07778 -.00001 25

156
Table 17. (ConHnuod).

Propane I soci

Temp. Pressure Z K MPa

369.676 4.2336 .24295

374.000 4.6430 .26337

382.000 5.4146 .30070

390.000 6.1939 .33692

398.000 6.9777 .37193

406.000 7.7646 .40572

414.000 8.5539 .43833

422.000 9.3450 .46979

430.000 10.1374 .50014

438.000 10.9307 .52943

446.000 11 .7248 .55771 454.000 12.5193 .58501 462.000 13.3142 .61 137 470.000 14.1091 .63685

478.000 14.9041 .66147

486.000 15.6989 .68528

494.000 16.4935 .70831 502.000 17.2878 .73058

510.000 18.0816 .75215

518.000 18.8750 .77302

526.000 19.6678 .79324

534.000 20.4600 .81 283

542.000 21 .2516 .83182

550.000 22.0425 .85022

558.000 22.8326 .86807

566.000 23.6220 .88539

574.000 24.4106 .90220

582.000 25.1983 .91851 590.000 25.9852 .93435

598.000 26.7712 .94973

606.000 27.5563 .96468

614.000 28.3405 .97921 622.000 29.1238 .99333

630.000 29.9061 1 .00706

638.000 30.6875 1 .02041

646.000 31 .4680 1 .03341 654.000 32.2474 1 .04605

662.000 33.0259 1 .05836

670.000 33.8034 1 .07034

678.000 34.5799 1 .08200

686.000 35.3554 1 .09337

694.000 36.1300 1 .10444

re ah 250 kg/m1 sotherm 1 sochore 1 sochore

Der I vati ve Der Wat I ve Curvature

MPaMti3/kg MPa/K MPa/K'^

.00022 .09181 .0104534

.00249 .09563 .0002745

.00708 .09703 .0001 114

.01 193 .09773 .0000696

.01695 .09819 .0000490

.02209 .09853 .0000362

.02733 .09878 .0000272

.03264 .09897 .0000205

.03802 .09911 .0000152

.04344 .09922 .00001 10 .04891 .09929 .0000075

.05441 .09934 .0000045

.05995 .09937 .0000020

.06551 .09937 -.0000002

.071 10 .09936 -.0000021

.07670 .09934 -.0000037

.08232 .09930 -.0000051

.08795 .09926 -.0000064

.09359 .09920 -.0000075

.09924 .09914 -.0000085

.10490 .09907 -.0000094

.1 1056 .09899 -.0000102

.11622 .09890 -.0000109

.12189 .09831 -.00001 15 .12756 .09872 -.0000120

.13323 .09862 -.00001 25 .13890 .09852 -.0000130

.14457 .09841 -.0000133

.15024 .09831 -.0000137

.15590 .09820 -.00001 40

.16156 .09303 -.0000143

.16721 .09797 -.00001 45 .17287 .09785 -.0000147

.17851 .09773 -.00001 49 .18415 .09761 -.0000150

.18979 .09749 -.00001 51 .19542 .09737 -.0000152

.20104 .09725 -.0000153

.20665 .09713 -.0000154

.21226 .09700 -.0000155

.21786 .09638 -.0000155

.22346 .09675 -.0000155

157
Table 17. (Continued).

Propane I sochore at 300 kg/iir

1 sotherm 1 sochore 1 sochore

Temp. Pressure Z Der I vat ive Der i vat ive Curvature

K MPa MPa 'm-^ /kg MPa/K MPa/K^

366.998 4.0312 .19419 .00514 .12483 .0021808

374.000 4.9319 .23313 .01 167 . 1 3096 .0004539

382.000 5.9914 .27728 .01887 .13365 .0002542

390.000 7.0678 .32038 .02614 .13533 .0001 743

398.000 8.1 554 .36226 .03349 .13653 .0001296

406.000 9.251.40285 .04091 .13744 .0001004

414.000 10.3540 .44214 .04839 .13816 .0000794

422.000 1 1 .4616 .48016 .05592 . 1 3873 .0000635

430.000 12.5733 .51694 .06349 .13918 .0000509

438.000 13.6883 .55250 .071 09 .13955 .0000407

446.000 14.8059 .58689 .07872 .1 3984 .0000323

454.000 15.9256 .6201 4 .08637 .14007 .0000253

462.000 17.0469 .65231 .09404 .14025 .0000192

470.000 18.1694 .68343 .101 72 .14038 .0000141

478.000 19.2928 .71355 .10942 .14047 .0000096

486.000 20.4169 .74269 .1 1712 .14053 .0000057

494.000 21.5413 .77090 .12483 .14057 .0000023

502.000 22.6659 .79822 .13254 .14057 -.0000008

510.000 23.7904 .82468 .14025 .14055 -.0000034

518.000 24.9147 " .85031 .14796 .14052 -.0000058

526.000 26.0336 .87516 .15567 .14046 -.0000079

534.000 27.1620 .89924 .16338 . 1 4039 -.0000097

542.000 28.2848 .92259 .1 7108 .14031 -.0000114

550.000 29.4069 .94524 .17878 .14021 -.0000129

558.000 30.5282 .96721 .18647 .14010 -.0000142

566.000 31 .6485 .98853 .19415 . 1 3998 -.0000154

574.000 32.7679 1 .00923 .20183 .13985 -.0000165

582.000 33.8862 1 .02933 .20949 .13972 -.0000174

590.000 35.0033 1 .04884 .21 715 .13958 -.0000183

598.000 36.1 194 1 .06781 .22479 . 1 3943 -.00001 90 606.000 37.2342 1 .08623 .23243 .13927 -.0000197

614.000 38.3477 1 .10414 .24005 .1391

-.0000203

622.000 39.4599 1 .12155 .24767 . 1 3895 -.0000209

630.000 40.5708 1 .13848 .25527 .13878 -.0000214

633.000 41 .6804 1 .15495 .26286 .13861 -.0000218

646.000 42.7885 1 . 1 7098 .27043 . 1 3843 -.0000222

654.000 43.8952 1 .1 8657 .27800 .13825 -.0000225

662.000 45.0005 1 .20175 .28555 .13807 -.0000228

670.000 46.1043 1 .21652 .29309 .13789 -.0000230

678.000 47.2067 1 .23091 .30061 .13770 -.0000232

686.000 48.3075 1 .24493 .30312 .13751 -.0000234

694.000 49.4069 1 .25858 .31562 .13733 -.0000236

158
Table 17. (Continued)

.

Propane I sochore at 350 kg/in1 sotherm 1 sochore 1 sochore

Temp. Pressure Z Derivative Der I vati ve Curvature

K MPa MPaTn^/kg MPa/K MPa/K^

359.023 3.4870 .14717 .02596 . 1 7976 .0010206

366.000 4.7602 .19709 .03639 .18469 .00051 42 374.000 6.2518 .25330 .04771 .18796 .0003294

382.000 7.7650 .30802 .05881 .19020 .0002378

390.000 9.2935 .36109 .06980 .19186 .0001812

398.000 10.8337 .41 248 .08074 .1931

4

.0001 420

406.000 12.3830 .46218 .09164 .19416 .0001129

414.000 13.9396 .51 022 .10251 .19497 .0000903

422.000 1 5.5021 .55665 .11 335 .19561 .0000 723 430.000 1 7.0691 .601 52 .1 241

8

.1961 3 .0000575

438.000 1 8.6399 .64488 .13498 .19654 .0000451

446.000 20.21 35 .68677 . 1 4576 .19686 .0000346

454.000 21 .7894 .72727 .15653 . 1 9710 .0000257

462 .000 23. 3669 .76642 .16727 .1972 7 .00001 80

470.000 24.9456 .80427 .1 7800 . 1 9739 .00001 13 478.000 26.5250 .84088 .18870 .19745 .0000054

486.000 28. 1 047 .87629 . 1 9938 . 1 9748 .0000003

494 .000 29 .6845 .91 056 .21 004 . 1 9746 -.0000042

502.000 31 .2640 .94373 .22068 . 1 9741 -.0000082

51 0.000 32.8430 .97584 .231 29 .19733 -.00001 1

7

51 8.000 34.421

3

1 .00694 .241 88 . 1 9722 -.00001 49

526.000 35.9985 1 .03707 .25245 .19709 -.00001 77 534.000 37.5747 1 .06626 .26299 . 1 9694 -.0000202

542.000 39. 1 496 1 .09455 .27351 .19677 -.0000224

550.000 40.7230 1 . 1 2 1 98 .28401 . 1 9658 -.0000244

558.000 42.2949 1 . 1 4858 .29448 .19638 -.0000262

566.000 43.8651 1 . 1 7438 .30492 . 1 961

7

-.0000278

574.000 45.4335 1 .19942 .31 534 .19594 -.0000292

582.000 47.0000 1 .22372 .32574 . 1 95 70 -.0000304

590.000 48.5647 1 .24731 .3361

1

.19545 -.000031

6

598.000 50.1 272 1 .27022 .34645 .1 9519 -.0000326

606.000 51 .6877 1 .29247 .35677 .19493 -.0000335

61 4.000 53.2461 1 .31409 .36706 . 1 9466 -.0000342

622.000 54.8023 1.33510 .37733 .19438 -.0000349

630.000 56.3562 1 .35553 .38758 .1 9410 -.0000356

638.000 57.9079 1 .37538 .39779 .19381 -.0000361

646.000 59.4572 1 .39469 .40799 .19352 -.0000366

654.000 61 .0043 1 .41348 .41816 .19323 -.0000370

662.000 62.5489 1 .43175 .42830 .19293 -.0000373

670.000 64.0912 1 .44954 .43842 .19263 -.0000376

678.000 65.6310 1 .46685 .44851 . 1 9233 -.0000379

686.000 67.1684 1 .48371 .45858 .19203 -.0000381

694.000 68.7034 1 .50012 .46862 . 1 91 72 -.0000382

159
Table 17. (Continued).

Propane Isochore at 400 kg/m1 sotherm 1 sochore 1 sochore

Temp, Pressure Z Der i vati ve Der i vat i ve Curvature

K NPa MPa.m3/kg MPa/K MPa/K^

344.298 2.6430 . 10178 .07761 .26305 .0005614

350.000 4.151 1 .1 5726 .08994 .26579 .0004125

358.000 6.2892 .23293 .10663 .26857 .0002 939 366.000 8.4463 .30598 .12291 .27061 .0002207

374.000 10.6176 .37642 . 1 3890 ,272 16 .0001698

382 .000 12.7999 .44428 .15469 ,27336 .0001320

390.000 14.9907 .50965 .17032 .27429 .0001025

398.000 17. 1881 .57261 .18581 ,27502 .0000788

406.000 19.3905 .63325 ,20118 .27557 .0000593

414.000 21 .5967 .69168 .21545 .27597 .0000431

422.000 23.8057 .74797 .23162 .27626 .0000293

430.000 26.0167 .80223 .24670 ,27645 .0000175

438.000 28.2287 .85454 .26171 ,27655 .0000074

446.000 30.44 12 .90499 .27664 .27657 -.000001

4

454.000 32.6536 .95365 .29149 .27653 -.0000091

462.000 34.8655 1 .00062 .30628 .27643 -.00001 58 470.000 37.0763 1 .04596 .32100 .27628 -.0000217

478»000 39.2858 1 .08974 .33565 ,27608 -,0000270

486.000 41.4935 1 .13203 .35024 ,27585 -,0000316

494.000 43.6992 1 .17290 .36477 ,27558 -,0000356

502.000 45.9027 1.21241 ,37924 .27528 -,0000392

510.000 48.1036 1.25061 .39366 .27495 -,0000424

518.000 50.3018 1 .28756 .40802 ,27460 -,0000453

526.000 52.4971 1 .32332 .42232 .27423 -,0000478

534.000 54.6894 1 .35793 .43657 ,27384 -,0000500

542 .000 56.8785 1 .39 1 44 .45076 ,27343 -,000051

9

550.000 59.0642 1 .42389 .46490 .27301 -,0000537

558.000 61 .2465 1 .45533 .47899 .27257 -,0000552

566.000 63.4253 1 .48580 .49303 ,27212 -,0000565

574.000 65.6005 1.51534 .50703 .27167 -,0000577

582.000 67.7719 1 .54398 .52097 .27120 -.0000587

590.000 69.9396 1 .57176 .53486 .27073 -,0000596

Propane 1 sochore at 450 kg/m^

322.304 1 .6818 . 06 1 50 . 17785 .38324 ,0002389

326.000 3.0999 . 1 1 207 .18875 .38406 ,0002047

334.000 6. 1782 .21801 .21 188 .38545 .0001480

342.000 9 . 266

1

.31933 .23454 .38646 .0001059

350.000 12.3608 . 4 1 624 .25682 .387 17 .0000732

358.000 15.4603 .50898 .27879 .38765 .0000467

366.000 1 8.5627 .59776 .30047 .38793 .0000249

374.000 21 .6668 .68279 .32192 .38806 .0000065

382.000 24.7713 .76427 ,343 14 .38805 -.0000090

390.000 27.8752 .84240 .36418 .38792 -.0000224

398.000 30.9777 . 9 1 734 ,38502 .38769 -.0000339

406.000 34.0781 .98926 .40571 .38738 -.0000439

414.000 37 . 1756 1 .05833 .42623 ,38699 -.0000526

422.000 40.2698 1 . 12468 .44660 .38654 -.0000602

430.000 43.3601 1.18846 .46684 .38603 -,0000669

438.000 46.4461 1.24979 .48694 .38547 -,0000727

446.000 49.5275 1,30880 .50691 .38487 -.0000778

454.000 52.6040 1.36560 .52676 .38423 -.0000823

462.000 55.6751 1 ,42031 .54650 ,38355 -.0000862

470.000 58.7408 1,47300 .56612 .38285 -.0000896

478.000 61.8007 1 .52380 .58563 .38212 -.0000926

486.000 64.8546 1.57278 .60504 .38137 -.0000952

494.000 67.9025 1.62002 ,62434 ,38060 -.0000975

502.000 70.9442 1.66562 .64355 .37981 -.0000994

160
Table 17. (Continued).

Propane I sochore at 500 kg/rn^

1 sotherm 1 sochore 1 sochorG

Temp. Pressure z Der i vat i ve Der i vat i ve Cu rv3 "fur© K MPa MPa. m3 /kg MPa/K MPa/K^

293. 022 .8338 .03018 .34842 .5 5777 - 0001 17S

1 .3738 .04957 .35223 .55216 - 000 1 Mf\

?Q8- 000 3.5815 . 1 2748 .36772 .55168 -.000 1 187 502.000 5.7873 .20327 .38309 .55120 -.0001 207

5O6.OOO 7.991

1

.27701 .39834 .55072 -.0001731

310.000 10. 1930 .34878 .41348 .55022 -.0001 260

314.000 12.3929 .41865 .42851 .54971 -.0001291

318.000 14.5907 .48669 .44343 .54919 -.0001 324

322.000 16.7863 .55297 .45826 .54865 -.0001358

326.000 18.9798 .61756 .47300 .54810 -.0001391

330.000 21. 1711 .68051 .48764 .54754 -.0001424

334.000 23.3601 .74188 .50220 .54696 -.0001457

338.000 25.5468 .80172 .51668 .54637 -.0001489

342.000 27.731

1

.86009 .53107 .54577 -.0001520

346.000 29.9129 . 9 1 704 .54539 .54515 -.000 1550 350.000 32.0923 .97261 .55963 .54453 -.0001579

354.000 34.2691 1 .02684 .57380 .54389 -.0001606

358.000 36.4434 1 .07979 .58790 .54324 -.0001632

362.000 38.61 51 1.13150 .60194 .54259 -.000 1657 366.000 40.7841 1. 18199 .61 590 .54192 -.0001680

370.000 42.9504 1 .23132 .62980 .54 124 -.000 1702 374.000 45. 1 140 1 .27951 .64364 .54056 -.0001723

378.000 47.2749 1 .32661 .65742 .53986 -.0001743

382.000 49.4329 1.37264 .671 14 .53916 -.0001761

386.000 51 .5881 1 .4 1765 .68480 .53846 - .000 1778 390.000 53.7405 1.46165 .69840 .53774 -.0001794

394.000 55.8901 1 .50468 .71 195 .53702 -.0001808

398.000 58.0367 1.54677 .72544 .53629 -.0001822

402.000 60. 1804 1 . 58794 . 73888 9 J -J J 406.000 62.321

2

1 .62823 .7 5227 .53483 -.000 1 846

4^ 1\ 0.000 \J % \J \J\J 64.4590 1 .66765 .76561 - 000 1RS7 414.000 66.5939 1 #70624 .77890 .53334 - OOOIftfifi 418 .000 68.7758 1 ,74401 .797 14 - 000 1ft7S 477 000 1 TROQQ Rns'^'5 S'^ 184 - OOOIftP"^

1 ^ophorp at *S^n kn/m^

256.764 . 2778 .01043 6 1 =553 .788 13 - OOOfiSOO

758.000 1 .2512 .04676 .62 175 .78733 -.000fi"^8fi 767.000 1fi178 fi4 1 87 .

/

OHO J

- 000f\0^f\ 7 'i'^ni 777QR fifi 1 7Q - 000S77(^

910 000 in1 \j %\jfi'ss's J J J . 00 1 00 78077 - • OOO^^'^sl UUU J J J 1 274.000 1 3,7720 .48469 .70141 .77805 -.OOOS'^"^"^ 278.000 16.8800 .58552 .72105 .77595 -.0005 157 282.000 19.9797 .68321 .74059 .77392 -.0005005

286.000 23.0715 .77790 .76001 .77195 -.0004872

290.000 26. 1 554 .86971 .77933 .77002 -.0004756

294.000 29.2317 .95878 .79854 .76814 - .0004654

298.000 32.3005 1 .04522 .8 1 765 .76630 -.0004564

302.000 35.3621 1 . 12913 .83666 .76449 -.0004485

306.000 38.4 165 1 .21062 .85556 .76271 -.0004414

310.000 41 .4638 1 .28979 .87437 .76095 -.0004350

314.000 44.5041 1.36673 .89308 .75923 -.0004293

318.000 47.5376 1.44153 .91 169 .75752 -.0004241

322.000 50.5643 1.51426 .93021 .75583 -.0004193

326.000 53.5843 1.58501 .94863 .75416 -.0004 150 330.000 56.5976 1.65385 .96697 .75251 -.00041 10 334.000 59.6044 1.72085 .98522 .75088 -.0004073

338.000 62.6047 1.78609 1 .00338 .74925 -.0004038

342.000 65.5985 1.84961 1.02146 .74764 -.0004005

346.000 68.5858 1.91 148 1.03945 .74605 -.0003975

350.000 71.5669 1.97177 1.05736 .74447 -.0003946

161
Table 17. (Continued).

Propane I sochore at 600 kg/m1 sotherm 1 sochore 1 sochore

Temp. Pressure Z Der i vat ive Deri vati ve Curvature

K MPa MPa.m3/kg MPa/K MPa/K2

214.330 .0453 .00187 1.00752 1.12014 -.0016196

218.000 4.1460 .1681

1

1.031 1

1

1.11437 -.0015252

222.000 8.5915 .34209 1.05677 1.10846 -.0014356

226.000 13.0141 .50901 1.08236 1.10287 -.0013576

230.000 17.4149 .66929 1 .10786 1.09758 -.0012895

234.000 21.7951 .82332 1.13327 1.09255 -.0012297

238.000 26.1556 .97143 1.15857 1.08774 -.001 1769

242.000 30.4972 1.1 1396 1.18376 1.08312 -.001 1301 246.000 34.8208 1.25120 1.20883 1.07869 -.0010884

250.000 39.1270 1.38344 1 .23378 1.07441 -.0010512

254.000 43.4163 1.51 uyz 1 O CO <C 11 .z5oDl 1 .07027 -.0010177

258.000 47.6893 1.63390 1.28332 1.06626 -.0009875

262.000 51.9466 1.75259 1 .30790 1 .06237 -.0009602

266.000 56. 1884 1.86719 1.33236 1.05858 -.0009354

270.000 60.4153 1.97791 1 .35669 1.05488 -.0009127

274.000 64,6276 2.08493 1.38089 1.05128 -.0008919

278.000 68.8256 2.18841 1.40497 1.04775 -.0008727

Propane 1 sochore at 650 kg/m^

167.316 .0017 .00008 1 .55418 1.60092 -.0037221

168.000 1.0962 .05324 1.55969 1.59840 -.0036695

170.000 4.2857 .20570 1.57585 1.59121 -.0035237

172.000 7.4612 .35395 1.59203 1.58429 -.0033889

174.000 10.6231 .49815 1.60825 1 .57764 -.0032640

176.000 13.7719 .63847 1.62448 1.57123 -.0031482

178.000 16.9082 .77507 1.64073 1 .56504 -.0030406

180.000 20.0322 .90807 1.65698 1.35906 -.0029405

182.000 23.1446 1.03762 1.67324 1.55328 -.0028473

184.000 26.2455 1.16385 1.68949 1.54767 -.0027603

186.000 29.3354 1 .28689 1 .70573 1.54223 -.0026791

188.000 32.4145 1.40684 1 .72196 1.53695 -.0026031

190.000 35.4833 1.52381 1 .73817 1.53182 -.0025319

192.000 38.5419 1.63792 1.75437 1.52682 -.0024652

194.000 41.5906 1.74926 1.77054 1.52195 -.0024025

196.000 44.6298 1.85793 1.78668 1.51721 -.0023436

198.000 47.6595 1 .96402 1.80280 1 .51258 -.0022882

200.000 50.6802 2.06761 1.81889 1.50805 -.0022359

202.000 53.6918 2. 16879 1.83495 1.50363 -.0021866

204.000 56.6947 2.26764 1.85098 1 .49931 -.0021400

206.000 59.6891 2.36423 1.86697 1.49507 -.0020959

208.000 62.6751 2.45863 1.88293 1.49092 -.0020541

210.000 65.6528 2.55091 1 .89885 1.48685 -.0020145

212.000 68.6225 2.641 15 1.91473 1.48286 -.0019769

214.000 71.5843 2.72939 1 .93057 1.47894 -.001 9412

162
Table 17. (Continued).

Propane I sochore at 700 kg/rn1 sotherm 1 sochore 1 sochore

Temp« PrGSSure 7 Der i vat i ve Der i vat i ve Curvature

K Mra Mra» mJ/Kg MPa/K MPa/K^

110 1 >! 1 AAAA • UUUU .00000 0 "Z A A CO 0 7 TAAO 2.33998 -.0093942

1 ZU • (JUL) 4

•

ddjD ./ /JO 1 z^ 3z / 3U 2.32298 AAO AA C A -• uoyyui^y

1 •UUU Q A£: 1 A

0 •yo ly . / 0 7 >i c c >i z •34do4 2.30565 A A 0 yi 00 C -.0084286

1 Z4« UUU I J. z>z>o I .o2o j4 Z^30DZ

1

0 00 A 0 /I 2. 28924 AA T A AC C -.0079955

1 26.000 1 0 • 1 1 y4 1 AO A Cj^r

1 .00 956 0 "Z 0 cn

A

2.38599 2.27365 -.00760 1

8

128.000 0 o 1 0 ZZ« OP 1

0

1 t A AO 0

1 .34082 2.40593 2.25881 nn "1 0 A on -.0072429

130.000 27.1551 1 .58265 2.42602 2.24465 -.0069151

132.000 71 C'Tif\0 5 1

.

ojOo 1 0 1 C C ~71 . 0 1 55 / 2.44622 2. 23 1 1

3

n AC c 1 c

n

-.00561 50 134.000 36.0800 2.04004 2.46652 2.21818 -.0063398

136.000 40.5039 2.25650 2.48690 2.20575 -.0060867

138.000 44.9034 2.46534 2.50734 2. 19382 -.0058536

1 4U«UU(J 4y • z / y4 /• oDoy-? Z • !)Z /oz 0 1 0 0 "Z "Z z« ioz33 AA CC "Z 0 /I -• UUDo3o4

i4z«UUU c; T tf^ OA -)^.o^zy Z«OD ID / z •!)4o34 2.17125 n A C >t ~IC\ A - .0054394

1 >f /] Ann 1 44» UUU 0 1

•

yD4 / X A/1 Q Q R -)• U4y oD 0 Rf^ QQ "7 Z • DDOO / 0 1 ^;A Ci^ Z. 1 oU Z>o AA CO C C A -.U052550

1 4d .UUU DZ © Z / !)4 7 0 T 1 "7*7 J .Z^ 1 /

/

0 CO n /I 0 z • I:)oy4z z .

1

dUzz - AA C A 0 Z 0 .0050o3o

1 4o •UUU J>«4U / /4 z^ouyy

D

0 \ A no 0 Z • 1 4Uzz -

AA >1 A 0 /I ^ . UU4y 245

I IPU •UU'J / U .O J)OP J • D / ouz Z •0_)U!?U Z • 1 _)U!?Z — .UU4 1 IOC

,3

kg/rn

Q c >1 "7 A ol? #4 /U AAAA • UUUU A AAAA •UUUUU 7 A 1 0 RQ -5 •u 1 z-)y

7 1ACO"7 J • i Udz / - AO A 1 AO 7 .U2U 1 U2

J

Q AAA 00 • UUU 1 ^ /I T

• 1 JOZ 1 "Z A 1 "7"^ X 3» U 1 /J) J

7 AO R "7 X 3 • uy 3 / ^ - A 1 0^~7yl A . U 1 95 /4U

D "7 AAA 0 / .UUU 4 • /zyi3

7 AT 1 mD^D lO J •Uzd4o J^U /D44 AID OA C"7 -.u loyuD

/

Q Q AAA 00 .UUU / • /yo / •d4U /o AT RQ R T AR*7QA ^. uz> /yu - A 1 Q 1 Q ^ A .(J 1 0 1 o5U

c>y .UUU 1 U •Oh!?D QQ 1 XO • 00 1 _>Z J •U4 -340 J) •U'fUUD _— n 1 7 R 1 1 7 .U 1 / -) 1 1 J OA AAA yu» UUU 1 1 1 R 1

-2 ARROO U!3pzy •7 AOOQ"7 ^ .UZZo / - A 1 Q 7Qn . U 1 5o /tSU A 1 AAA y 1 .UUU iconic 1 D»oy 1 0

1 ~Z. A ^A C

1 •34z4!? 7 AC CZ 1 "Z AACOA 3«uuDzy A 1 C 007 A -.0 ]52o30

AO AAA 92.000 1 A 00 AO 19.8898 1 • 563 56 3,07551 0 nAAOA 2 .99029 -.01 57236

93.000 22 .8723 1 •77868 "2 AO C 0 0 0 A *7 ^ 0 "Z z .9 /4o3 A 1 C 1 n "7 1 A A AAA 94 .000 25 .8396 1 AO 0 AC

1 .98805 T AA C A r\ 3. 09540 0 A C A 0 0 2.95988 A 1 /I ~T A 1 A -.01 4701

0

95.000 28.7922 2.19191 3. 10706 2 .94542 n 1 yi TZ "7 0 - .0 1 42332

96.000 31 .7306 0 TA f\ A A 2.39044 3. 1 1 785 2.93141 AIT "7A 1 0 -.0 1379 1

8

y / .000 34.5552 0 c 0 7 0 c 2.58385 "Z 1 00 *7C 3. 1 28 /5 0 A 1 "7 0 T 2.9 1 /83 A 1 T T "7 >1 "7 - .Ul 33 /4

/

98.000 37 .5664 2.77233 3. 13977 2.90465 A 1 OA 0 A >1 -.0129804

99.000 A r\ A ^ A ^ 40.4646 2.95605 3. 1 5089 0 0 n 1 0 c 2.89 186 n 1 oc mT -.01 26073

1 A A AA A

1 00. 000 43.3502 3. 13518 3. 16210 2.87943 n 1 0 0 C T A -.0122539

101.000 46.2236 3.30989 3.17339 2.86735 -.01 19190

102.000 49.0850 3.48033 3.18476 2.85559 -.01 16012

103.000 51.9349 3.64664 3.19620 2.84414 -.01 12995

104.000 54.7734 3.80897 3.20770 2.83298 -.01 10128 105.000 57.6009 3.96745 3.21925 2.8221

1

-.0107402

106.000 60.4177 4. 12221 3.23086 2.81 150 -.0104807

107.000 63.2240 4.27336 3.24251 2.801 14 -.0102336

108.000 66.0201 4.42103 3.25421 2.79103 -.0099980

109.000 68.8061 4.56533 3.26594 2.781 14 -.0097733

110.000 71 .5824 4.70636 3.27770 2.77148 -.0095588

163
Table 18. Calculated P(P) isotherms of propane

.

Propane 1 sotherm at 90 K

1 sotherm 1 sochore 1 sochore

Dens ity Pressure Z Der i vat i ve Der 1 vat i ve Curvature

kg/m3 MPa MPa .m3/kg MPa/K MPa/K^

.00 .0000 1 .00000 .01697 .00000 -.0000000

728.67 .0000 .00000 2.89905 2.97836 -.0178732

728.75 .2195 .01775 2.90152 2.97906 -.0178557

729.37 2.0393 .15477 2.92199 2.98482 -.0177125

730.00 3.8720 .31257 2.94261 2.99065 -.0175726

730.62 5.7176 .461 16 2.95338 2.99554 -.0174358

731.25 7.5762 .61055 2.98431 3.00250 -.0173021

731.88 9.4480 .76074 3.00539 3.00853 -.0171716

732.50 1 1 .3329 .91 173 3.02652 3.01462 -.0170440

733.12 13.2313 1.06354 3.04801 3.02077 -.0159195

733.75 15. 1430 1 .21617 3.06956 3.02698 -.0157979

734.37 17.0682 1.36963 3,09126 3.03326 -.0166792

735.00 19.0071 1 .52392 3.1 1312 3.03959 -.0165634

735.62 20.9597 1.67904 3.13514 3,04599 -.0164505

736.25 22.9261 1.83501 3.15733 3.05244 -.0163404

736,88 24.9065 1.99183 3.17967 3.05895 -.0162331

737.50 26.9009 2. 14950 3.20218 3.06552 -.0161285

738. 12 28.9091 2.30801 3.22485 3.0721

5

-.0160266

738.75 30.9318 2.46740 3.24769 3.07883 -.0159274

739.37 32.9688 2.52767 3.27059 3.08555 -.0158308

740.00 35.0202 2.78881 3.29386 3.09235 -.0157368

740.62 37.0851 2.95084 3.31721 3.09919 -.0156454

741.25 39. 1667 3.11375 3.34072 3.10508 -.0155565

741 .88 41.2621 3.27758 3.36440 3.1 1303 -.0154702

742.50 43.3723 3.44229 3.38826 3.12002 -.0153864

743.12 45.4974 3.50792 3.41229 3.12707 -.0153050

743.75 47.6377 3. 77447 3.43649 3. 1 34 16 -.01 52260

Propane 1 sotherm at 100 K

.00 .0000 1 .00000 .01885 .00000 -.0000000

718.44 .0000 .00000 2.66954 2.72428 -.0140068

718.75 .8380 .06184 2.67912 2.72726 -.0139584

720»00 4.21 10 .31019 2.71758 2.73928 -.0137706

721.25 7.6324 .55125 2.75675 2.75151 -.0135912

722.50 1 1 . 1 03

1

.81504 2.79633 2.76393 -.0134201

723.75 14.6235 1.07161 2.83644 2.77655 -.0132570

725.00 18.1944 1.33099 2.87707 2.78937 -.0131018

726.25 21.8164 1 .59321 2.91824 2.80238 -.0129542

727.50 25.4904 1.85831 2.95996 2.81555 -.0128141

728.75 29.2166 2.12631 3.00222 2.82893 -.0126814

730.00 32.9961 2.39725 3.04503 2.84247 -.0125557

731 .25 36.8294 2.67118 3.08841 2.85518 -.0124370

732.50 40.7173 2.94812 3.13236 2.87005 -.0123251

733.75 44.6605 3.22812 3. 17689 2.88409 -.0122198

735.00 48.6598 3.51 122 3.22201 2.89828 -.012121

1

736.25 52.7158 3.79744 3.26772 2.91253 -.0120287

737.50 56.8295 4.08583 3.31404 2.92713 -.01 19424

738.75 61 .001

1

4.37940 3.36096 2.94176 -.0118523

740.00 55.2319 4.67524 3.40851 2.95654 -.01 17880

741.25 69.5226 4.97435 3.45670 2.97145 -.01 17196

164
Table 18. (Continued).

Propane Isotherm at 1 10 K

Dens ity

kg/m3

.00

708.26

708.75

710.00

711. 25 712.50

713.75

715.00

716.25

717.50

718.75

720.00

721.25

722.50

723.75

725.00

726.25

727.50

728.75

730.00

731.25

732.50

Pressure

MPa

.0000

.0000

1.2165

4.3362

7.5015

10.7130

13.9713

17.2768

20.6302

24.0321

27.4830

30.9835

34.5342

38.1358

41.7888

45.4938

49.2515

53.0628

56.9277

60.8473

64.8222

68.8530

1 .00000

.00000

.08276

.29446

.50852

.72495

.94378

1.16504

1 .38874

1.61492

1 .84361

2.07482

2.30859

2.54494

2.78390

3.02550

3.26976

3.51673

3.76641

4.01884

4.27406

4.53208

I sotherm

Derivative

MPa.m3/kg

.02074

2.46350

2.47767

2.51395

2.55067

2.58783

2.62544

2.66351

2.70203

2.74102

2.78048

2.82041

2.86083

2.90173

2.94313

2.98503

3.02743

3.07034

3.1 1377 3.15773

3.20222

3.24726

Isochore

Derivative

MPa/K

.00000

2.50201

2.50672

2.51881

2.53106

2.54347

2.55604

2.56877

2.58165

2.59468

2.60786

2.621 18 2.63464

2.64824

2.65198

2.67584

2.68984

2.70396

2.71821

2.73257

2.74705

2.76165

Isochore

Curvature

MPa/K^

-.0000000

-.01 1 1736

-.01 1 1217 -.0109942

-.0108 726 -.0107568

--.0106465 -.0105417

-.0104422

-.0103479

-.0102587

-.0101745

-.0100951

-.0100205

-.0099506

-.0098852

-.0098243

-.0097677

-.0097154

-.0096673

-.0096233

-.0095833

.00

698.12

698.75

700.00

701.25

702.50

703.75

705,00

706.25

707.50

708.75

710.00

71 1.25 712.50

713.75

715.00

716.25

717.50

718.75

720.00

721.25

722.50

723.75

725.00

.0000

.0000

1 .4457

4.3335

7.2640

10.2382

13.2564

16.3190

19.4266

22.5797

25.7787

29.0243

32.3169

35.6571

39.0453

42.4822

4 5.9682

49.5040

53.0900

56.7269

60.4152

64.1556

67.9485

71 .7946

Propane

.99999

.00000

.09144

.27361 .45782

.64413

.83253

1 .02305

1.21572

1.41054

1 .60754

1.80675

2.00817

2.21 184 2.41778

2.62600

2.83652

3.04938

3.26459

3.48217

3.70215

3.92455

4.14940

4.37670

sotherm at 120 K

.02263

2.27593

2.29310

2.32730

2.36189

2.39687

2.43225

2.46803

2.50420

2.54079

2.57778

2.61520

2.65303

2.69128

2.72997

2.76909

2.80865

2.84865

2.88910

2.93001

2.97138

3.01322

3.05552

3.09831

.00000

2.30506

2.31 105 2.32298

2.33505

2.34726

2.35960

2.37207

2.38467

2.39739

2.41024

2.42321

2.43629

2.44950

2.46282

2.47626

2.48980

2.50346

2.51722

2.53109

2.54506

2.55913

2.57330

2.58757

-.0000000

-.0090397

-.0089937

-.0089059

-.0088224

-.0087429

-.0086675

-.0085959

-.0085282

-.0084642

-.0084038

-.0083470

-.0082937

-.0082438

-.0081972

-.0081540

-.0081 139 -.0080770

-.0080432

-.0080125

-.0079847

•.0079598

-.0079378

.0079186

165
Table 18. (Continued),

Propane Isothenn at 140 K

1 sotherm 1 sochore 1 sochore

Dens ity Pressure Z Der i vat i ve Der ivati ve Curvature

kg/m3 MPa MPa.m3/kg MPa/K MPa/K^

.00 .0001 .99985 .02639 .00000 -.0000000

.0001 .00000 1 .94295 1.96937 -.0061040

678.75 1.7229 .09616 1 .96429 1 .97729 -.0060730

680.00 4. 1973 .23383 1 .99480 1.98860 -.0060311

681.25 6.7100 .37313 2.02563 2.00001 -.0059915

682.50 9.2615 .51408 2.05678 2.01 152 -.0059541

683.75 1 1.8521 .65667 2.08825 2.02312 -.0059189

685.00 14.4823 .80093 2.12004 2.03482 -.0058858

686.25 17, 1524 .94687 2.15216 2.04662 -.0058547

687.50 19.8628 1.094 50 2.18460 2.05850 -.0058257

688.75 22.6140 1 .24384 2.21738 2.07049 -.0057986

690.00 25.4064 1.39489 2.25049 2.082 56 -.0057735

691.25 28.2404 1.54769 2.28395 2.09472 -.0057503

692.50 31 .1 164 1.70222 2.31774 2.10697 -.0057290

693.75 34.0349 1.85853 2.35187 2.1 1932 -.0057095

695.00 36.9963 2.01660 2.38635 2. 13175 -.0056918

696.25 40.0010 2. 17647 2.421 19 2.14426 -.0056759

697.50 . 43.0494 2.33814 2.45637 2.15687 -.0056617

698.75 46. 1421 2.50163 2.49192 2. 16956 -.0056492

700.00 49.2794 2.66695 2.52782 2.18233 -.0056384

701.25 52.4617 2,8341

1

2.56409 2.19518 -.0056293

702.50 55.6897 3.0031

4

2.6007/ Z . 2 Oo 1

2

-.00562 1

7

703.75 58.9636 3. 17404 2.63773 2.221 14 -.0056158

705.00 62 .284

1

3.34684 2.675 1

1

2.23423 -.00561 1

5

706.25 65.6516 3.52155 2.71287 2.24741 -.0056087

707.50 69.0664 3.69818 2.75101 2.26066 -.0056074

. ^

Propane 1 sotherm at 160 K

.03 .0008 .99896 .0301

1

.00001 -.0000000

657.51 .0008 .00004 1 .65218 1.69146 -.0042366

658.75 2.0638 .10385 1 .67891 1 .70179 -.0042167

660.00 4.1795 .20991 1.70616 1.71229 -.0041980

661 .25 6.3293 .31728 1 .73368 1 .72287 -.0041806

662.50 8.5138 .42598 1 .76147 1.73352 -.0041645

663.75 10.7331 .53601 1 .78953 1 .74425 -.0041495

665.00 12.9877 .64739 1.81787 1.75505 -.0041358

666.25 15.2779 .76012 1 .84650 1 .76592 -.0041233

667.50 17.6041 .87421 1.87540 1.77687 -.0041 1 19 668.75 19.9665 .98968 1.90458 1 .78789 -.0041017

670.00 22.3656 1.10653 1.93405 1.79899 -.0040926

671 .25 24.8018 1 .22477 1 .96381 1 .81016 -.0040845

672.50 27.2753 1 .34441 1.99385 1.82140 -.0040776

673.75 29.7865 1.46547 2.02419 1 .83271 -.0040716

675.00 32.3359. 1.58795 2.05482 1.84409 -.0040668

676.25 34.9237 1.71 186 2.08574 1.85554 -.0040629

677.50 37.5502 1.83721 2.1 1697 1 .86707 -.0040600

678.75 40.2162 1 .96402 2.14849 1 .87866 -.0040582

680.00 42.9217 2.09229 2.18032 1.89033 -.0040573

681.25 45.6671 2.22204 2.21245 1 .90206 -.0040574

682.50 48.4529 2.35327 2.24489 1.91386 -.0040584

683.75 51 .2795 2.48600 2.27764 1.92573 -.0040603

685.00 54.1472 2.62023 2.31070 1 .93766 -.0040632

686.25 57.0564 2.75598 2.34407 1 .94967 -.0040670

687.50 60,0075 2.89326 2.37777 1.96174 -.0040717

688.75 63.0009 3,03208 2.41 178 1 .97387 -.0040773

690.00 66.0371 3.17244 2.44612 1.98607 -.0040837

691 .25 69.1 164 3.31437 2.48079 1 .99834 -.0040910

156
Table 18. (Continued).

Propane Isotherm at 180 K

1 QO"f*hof"m 1 \ 1 lot 111 1 c^*\/^Krti~o 1 OL/^ 1 \S 1 c/^/^ri/^^Q

1 boc^iiurtJ Den s i ty Pressure z Hpp LyC7l Iv/rii" 1 V Q 1

1

1 \tf^ vv? RciP I i \/o \JK3\ 1 V O 1 1 VC L*U 1 VCl 1 Ul fcS kg/fn3 MPa MPa •m3 /kn |yipa/f< Fir o/ r\

. 15 .0050 .99585

636.85 .0050 .00023 1 .39334 I • ^ ^ JJ c. - nn9Qft 1

1

637.50 .9157 .04232 1 .40575 1 .46049 -.0099779

638.75 2.6879 .12399 1 .4297o 1 .47007 -.0029703

640.00 4.4902 .20672 1 .45405 1 .^1912 -.002964

1

641 .25 6.3231 .29054 1 .47856 1 .48942 -.0029587

642.50 8. 1867 .37544 1 .50331 1 .49919 -.0029540

643.75 10.081

5

.46143 1 .52830 1 .50902 -.0029500

645.00 12.0076 .54853 1 .55354 1 .51891 -.0029468

646.25 13.9654 .63673 1 .57903 1 .52886 -.0029442

647.50 1 5.9553 .72605 1 .60476 1 .53887 -.0029423

648.75 17.9774 .8 1649 1 .63075 1 .54894 -.002941

1

650.00 20.0322 .90807 1 .65698 1 .55906 -.0079405 • \J\J C P^\J^ 651 .25 22. 1 200 1 .00078 1 .68347 1 .56925 -.0099405

652. 50 24.2410 1 .09464 1 .71022 1 .57950 - .00794 1

7

653.75 26 .3957 1 . 1 8966 1 .73722 1 .58981 - • nn9Q49's £.y ^ £. J 655.00 28.5842 1 .28584 1 .76447 - 0099444

656.25 "50.8069 1 .38319 1 .79199 1 .61 061 -.0099469

657.50 33.0643 1 .48172 1 .81977 1 .62 1 09 -.0099500

658 .75 35.3565 1 .581 43 1 .8478

1

1 .63164

1 .68234 1 .87612 1 .64224 - 009Q5ftO 661 .25 40.0469 1 .78446 1 .90470 1 .65290 - • 0099678 \J\J £-7 \J£-\j

663.75 44.8809 1.99232 1.96265 1.67441 -.0029741

665.00 47.3525 2.09809 1 .99204 1 .68524 -.0029806

Rfil 1 . OU 1

t

9 90'iOQ 9 09 1 70 - 009Qft77

667.50 52.4069 2.31334 2.05163 1 .70709 -.0029952

868.75 54.9903 2.42284 2.08185 1.71810 -.0030034

670.00 57.61 16 2.53360 2.1 1234 1 .72917 -.0030120

671 .25 60.2712 2.64563 2.14312 1.74030 -.0030212

672.50 62.9695 2.75893 2.17418 1 .75148 -.0030309

673.75 65.7068 2.87352 2.20553 1.76272 -.003041

1

D / . UU DO . 'toj J 9 9*^7 1

A

- .UU_)Ui> 1 0 O / O . ^ J 71 9QQQ 9 9fiQnQ - OO'^Ofi'^1

1

1 3^c;nthprm 1 1 III atcj 1 Z.UU 900 Kr\

. 0901 UZU 1 O'^fiflR . u_?oo^ .UUU 000 1

1 0

u

- .uuuuuuu 0000000

fil "5 fifi 0901 nnoft? 11 . 16045 1 UU*T ^ 1 .251 19 -.0070997

617 . 50 9 1 RTR 1 . 1 9146 1 .96400 -.0070990

5.2 198 1 .23427 1 ,28 1 56 -.0071 004

622.50 8 .3599 • JJ\J 1 1 . 27794 1 .29932 -.007 1034

fi9R 00 111 1 .ftO 1

1 09uz 4Q9ft 1 1 "^9940 1 179ft - . 007inR9 U Ui. 1 uo^

fi97 "SO 1/1 QV^I • /

/

1

1 . _?o ^fi7QA / y^ - . 009 UUZ. 1

1 11 4fi •+ u

c-io DjU.UU00 io 4c;n7 1 0 .'t 3U / • II OOJ> 1 A 1 A9Q - . 0091994 U UZ. 1 ^Z. H

(^^9 SO 99 OAS'^ Q9497 I .HO 1 J J I.J/ ^-JO - 0091318

fi'^S 00 9S 7SQ9 1 "509 7'5 1.391 15 -.0021 426

637.50 29.5947 1.23106 1 .55885 1.41013 -.0021548

640.00 33.5542 1.39031 1 .60892 1.42931 -.0021684

642.50 37.6401 1.55354 1.65994 1 .44869 -.0021833

645.00 41 .8547 1.72080 1 .71 194 1.46827 -.0021995

647.50 46.2006 1 .89214 1 .76492 1.48806 -.0022171

650.00 50.6802 2.06761 1.81889 1.50805 -.0022359

652.50 55.2959 2.24728 1 .87388 1.52825 -.0022560

655.00 60.0504 2.431 19 1.92988 1.54865 -.0022774

657.50 64.9462 2.61941 1 .98692 1 .56925 -.0023001

660.00 69.9859 2.81 197 2.04500 1.59005 -.0023239

167
Table 18. (Continued).

Propane Isotherm at 220 K

Isotherm 1 sochore 1 sochore

Dens i ty Pressure Z Der i vat i ve Der i vati ve Curvature

kg/m3 MPa MPa •m3/kg MPa/K MPa/K^

1 .50 .0605 .97418 .03937 .00029 -.0000002

593.67 .0605 .00245 .94999 1.07129 -.0014563

595.00 1.3397 .05428 ,96935 1 .07964 -.0014605

597.50 3.8091 .15369 1 .00626 1.09542 -.0014691

600.00 6.3717 .25601 1 .04395 1 . 1 1 137 -.0014788

602.50 9.0295 ,36129 1.08244 1.12749 -.0014894

605.00 11 .7846 .46958 1 . 1 2 1 72 1.14379 -.0015009

607.50 14.6388 .58091 1.16182 1 .16026 -.0015133

610.00 17.5944 .69534 1.20274 1. 17691 -.0015265

612.50 20.6532 .81289 1 .24449 1 . 19373 -.001 5405

615.00 23.8175 .93363 1 .28709 1 .21072 -.0015554

617.50 27,0894 1.05758 1 .33054 1.22790 -.0015710

620.00 30.4710 1 . 1 8480 1 .37485 1 .24525 -.0015874

622.50 33.9644 1.31534 1.42004 1 .26278 -.0016046

625.00 37.5719 1 .44922 1 .46611 1 .28049 -.0016225

627.50 41 .2957 1 .58651 1.51308 1 .29838 -.0016413

630.00 45. 1380 1 .72725 1 .56095 1 .31645 -.0016607

632.50 49. 1012 1.87148 1.60974 1 .33470 -.0016810

ODDUU c;-z 107c jD • \o / D

— nn 1 7n

•UU I q / u 1 y 637.50 57.3993 2. 17059 1.7101

1.37176 -.0017237

640.00 61 ,7389 2.32558 1 .76172 1.39056 -.0017462

DU • Z.UO /

1 ft 1 d7P. .'JUl 1 \jy J 645.00 70.81 11 2.64663 1 .86782 1.42871 -.0017935

Propane 1 sotherm at 240 K

2.50 .1091 .96423 .04207 .00049 -.0000003

3.43 .1479 .95125 .04087 .00068 -.0000007

570.55 .1479 .00573 .75993 .91069 -.0009718

572.50 1.6519 .06377 .78402 .92161 -.0009819

575.00 3.6513 .14033 .81555 .93575 -.0009953

577.50 5.7303 .21928 .84779 .95003 -.0010092

580.00 7.8908 .30065 .88074 .96446 -.0010235

582.50 10.1346 .38448 .91441 .97904 -.0010382

585.00 12.4635 .47081 .94882 .99378 -.0010533

587.50 14.8793 .55968 .98397 1.00866 -.0010689

590.00 17.3839 .65112 1 .01986 1 .02370 -.0010849

592.50 19.9792 .74517 1 .05653 1.03889 -.001 1012

595.00 22.6672 .84187 1.09396 1 .05424 -.001 1 180 597.50 25.4497 .94126 1 .13217 1.06974 -.001 1352

600.00 28.3287 1.04337 1.17118 1.08541 -.001 1528 602.50 31 .3063 1.14825 1.21098 1,10123 -.001 1708

605.00 34.3843 1.25594 1.25160 1.1 1721 -.001 1892

607.50 37.5649 1.36647 1.29304 1 . 1 3336 -.0012080

610.00 40.8502 1 .47988 1 .33530 1 .14967 -.0012273

612.50 44.2422 1.59622 1.37841 1.16614 -.0012470

615.00 47.7430 1 .71553 1 .42237 1 .18277 -.0012671

617.50 51 .3547 1.83784 1.46719 1.19957 -.0012877

620.00 55.0796 1 ,96319 1.51288 1 .21654 -.0013087

622.50 58.9199 2.09164 1.55945 1.23368 -.0013302

625.00 62.8776 2.22321 1 ,60691 1 ,25098 -.0013521

627.50 66.9552 2.35795 1.65527 1.26845 -.0013745

630.00 7 1 . 1 547 2.49590 1.70454 1 .28609 -.0013974

168
Table 18. (ConMnued)

.

Propane Isot-herm at 260 K

1 so fhertn 1 sochore 1 sochory

Pressure z Der i vat I ve Der I vat 1 ve Cu r vatuce

kg/ MPa r-Pa • in5/kg MPa/K MPa/K^

2.50 .11 88 .96925 .04609 .00048 -.0000001

5.00 .2305 .94022 .04322 .001 00 -.0000009

6.90 .3106 .91 774 .04095 .00143 -.0000023

545.88 .3106 .01 161 .5891

9

.76557 -.0005947

547.50 1 .2778 .04761 .60574 .77359 -.0006052

550.00 2.8246 .1 0476 .631 80 .78608 -.000621

4

552.50 4.4373 .1 6383 .65843 .79869 -.0006377

555.00 6.1175 .22485 .68578 .81 1 43 -.0006541

557.50 7.8668 .28784 . 71 373 .82429 -.0006705

560.00 9.6867 .35285 .74232 .83729 -.0006872

562.50 1 1 .5789 .41990 .771 57 .85043 -.0007039

565.00 1 3.5451 .48903 .801 49 .86369 -.0007207

567. 50 1 5.5869 .56027 .83208 .87710 - .0007376

5 70.00 1 7.7061 .63365 .86335 .89064 -.0007547

572.50 1 9.9043 . 70921 .89533 .90432 -.000771

9

575.00 22.1833 .78697 .92800 .91 81 4 -.0007893

577.50 24. 5449 .86698 .961 39 .93210 -.0008068

580.00 26.9909 .94927 .99551 .94620 -.0008245

582.50 29.5230 1 .03387 1 .03036 .96045 -.0008424

585 .00 32. 1 433 1 .1 2082 1 .06595 .97484 -.0008605

587.50 34.8534 1 .21 01

5

1 . 1 0229 .98938 -.0008787

590 .00 37.6553 1 .301 39 1 . 1 3940 1 .00406 -.0008972

592.50 40.5510 1 .39609 1 . 1 7727 1 .01890 -.0009160

595.00 43.5423 1 .49278 1.21593 1 .03388 -.0009349

597.50 46.6313 1 .59199 1 .25538 1.04902 -.0009541

600.00 49.8199 1 .69376 1 .29563 1 .06430 -.0009736

602.50 53.1101 1 .79813 1.33663 1 .07974 -.0009933

605.00 56.5040 1 .9051

3

1 .37856 1 .09534 -.0010133

607.50 60.0036 2.01480 1 .42126 1 . 1 1 1 09 -.0010335

610.00 63.61 10 2.12718 1 .46481 1 .12699 -.0010541

612.50 67.3284 2.24230 1.50920 1 .14305 -.0010749

615.00 71 .1577 2.36020 1 .55445 1 .15927 -.001 0961

169
Table 18. (Continued)

.

Propane 1 sothenn at 280 K

1 sotherm 1 sochore 1 sochore

Den s i ty Pressure Z Der i vat i ve Der I vat i ve Curvature

kg/ ir^ MPa M'^a • [(v5 /k g MPa/K MPa/K^

2.50 .1 234 .97312 .05006 .00048 -.0000001

5.00 .2504 .94841 .04747 .00099 -.0000005

7.50 .3657 .92367 .04483 .00153 -.0000014

1 0.00 .4745 .89871 .0421

5

.00211 -.0000032

1 2.50 .5764 .87345 .03940 .00274 -.0000065

1 2.64 .581 8 .87206 .03925 .00277 -.0000068

51 9.05 .5818 .021 23 .43728 .63300 -.0002899

520.00 1 .0001 .03643 .44501 .63709 -.0002971

522. 50 2.1 385 .07752 .46575 .64795 -.0003157

5 2 5 . 00 3.3293 .1 201

2

.48703 .65891 -.0003340

527. 50 4.5741 . 1 6425 .50883 .66999 -.0003521

530.00 5.8740 .20993 .531 19 .681 1 8 -.0003699

532. 50 7.2305 .25720 .55410 .69243 - .0003875

535 .00 8.6449 .30607 .57758 .70390 -.0004050

53 7.50 1 0. 1 1 88 .35659 .601 63 .71 543 -.0004223

540.00 1 1 .6536 .40877 .62626 .72 709 -.0004395

542 .50 1 3 .2506 .46265 .651 49 .73886 -.0004567

545.00 1 4.91 1

5

.51 825 .67732 .75076 -.0004738

547. 50 1 6.6378 .5 7561 .70377 . 76273 -.0004908

550.00 1 3 .4309 .63475 .73083 .77493 -.0005078

552.50 20.2925 .69570 . 75853 .78720 -.0005243

555.00 22.2241 .75849 .78686 .79960 -.000541

3

557 .50 24.22 73 . 8231

5

. 31 585 . 81 21

3

-.0005588

560.00 26.3039 .88971 .84549 .82479 -.0005759

562.50 28.4553 .95820 .87530 .83758 -.0005930

565.00 30.6334 1 .02866 .90679 .85050 -.00061 02 567.50 32.9899 1.10111 .93847 .86356 -.0006275

570.00 35.3763 1 . 1 7559 .97084 , .87675 -. 0006443

572.50 3 7.3446 1 .25212 1.00391 .89003 -.0006623

5 75.00 40.3965 1 .33074 1 .03770 .90355 -.0006798

577.50 43.0338 1 .41 143 1 .07222 .91 715 -.0006975

580.00 45.7582 1 .49437 1 .1074 7 .93090 -.00071 53 582.50 48.571 7 1 .57944 1 .1 4346 .94478 -.0007333

585.00 51 .4761 1 .66674 1 .18020 .95831 -.000751

4

587.50 54.4733 1 .75628 1 .21 771 .97298 -.0007696

590.00 57.5653 1 .8481

0

1 .25593 .98730 -.0007831

592.50 60.7539 1 .94224 1 .29503 1.00176 -.0008067

595.00 64.041

1

2.03873 1 .33488 1 .01636 -.0008255

597.50 57.4289 2.13759 1 .37552 1 .031 11 -.0003445

600.00 70.9194 2.23888 1 .41697 1 .04601 -.0008637

170
Table 18. (Continued).

Propane Isotherm at 298.15 K

Dens 1 ty

kg/m3

5.00

10.00

15.00

20.00

20.69

Pressure

MPa

.2682

.5123

.7321

.9274 .9523

.95428

-91 132 .86823

.82489

.81893

I sotherm

Der i vati ve

MPaTTi3/kg

.05123

.04640

.04152

.03659

.03591

I sochore

Derivative

MPaA

.00098

.00207

.00328

.00466

.00487

I sochore

Curvature

MPa/K^

-.0000003

-.0000018

-.0000056

-.0000143

-.0000162

492.06

495.00

500.00

505.00

510.00

515.00

520.00

525.00

530.00

535.00

540.00

545.00

550.00

555.00

560.00

565.00

570.00

575.00

580.00

585.00

.9523

1 .9078

3.6643

5.5938

7.7059

10.0102

12.5169

15.2363

18.1792

21.3570

24.7809

28.4630

32.4155

36.6509

41.1823

46.0231

51 .1868

56.6876

62.5399

68.7586

.03443

.06856

.13036

.19704

.26878

.34576

.42819

.51625

.61015

.71011

.8 1 633

.92902

1.04841

1.17471

1.30817

1.44900

1.59743

1.75372

1.91809

2.09080

.31561 .33459

.36830

.40385

.44131

.48075

.52225

.56587

.61 169 .65978

.71020

.76304

.81837

.87625

.93676

.99998

1 .06598

1.13483

1.20660

1 .28138

.52153

.53258

.55167

.571 14 .59103

.61 134 .63208

.65326

.67490

.69701

.71959

.74266

.7 6623

.79030

.81488

.83999

.86562

.89179

.91851 .94579

.0000534

.0000785

.0001 188 .0001568

.0001930

.0002279

.0002618

.0002950

.0003277

.0003600

.0003921

.0004241

.0004561

.0004883

.0005206

.0005532

.0005862

.0006196

.0006535

.0006879

Propane I sotherm at 300 K

5.00 .2700 .95482 .05161 .00098 -.0000003

10.00 .5161 .91245 .04682 .00206 -.0000017

15.00 .7382 .87002 .04200 .00327 -.0000053

20.00 .9361 .82741 .03714 .00464 -.0000131

21.70 .9979 .81284 .03546 .00515 -.0000177

489.13 .9979 .03607 .30407 .51057 -.0000307

490.00 1.2660 .04567 .30950 .51379 -.0000384

495.00 2.8929 .10332 .34157 .53243 -.0000804

500.00 4.6846 .16564 .37542 .55144 -.0001196

505.00 6.6502 .23281 .411 12 .57085 -.0001567

510.00 8.7990 .30501 .44873 .59067 -.0001922

515.00 1 1.1408 .38244 .48833 .61092 -.0002266

520.00 13.6858 .46529 .52999 .63159 -.0002600

525.00 16.4443 .55374 .57378 .65272 -.0002928

530.00 19.4272 .64802 .61977 .67430 -.0003251

535.00 22.6458 .74832 .66803 .69635 -.0003571

540.00 26.1115 .85485 .71864 .71887 -.0003888

545.00 29.8 3 62 .96783 .77166 .74188 -.0004206

550.00 33.8322 1 .08748 .82717 .76539 -.0004523

555.00 38.1 121 1.21402 .88524 .78940 -.0004842

560.00 42.6890 1.34766 .94594 .81392 -.0005163

565.00 47.5761 1.48865 1.00936 .83897 -.0005487

570.00 52.7872 1 .63722 1.07555 .86454 -.0005815

575.00 58.3364 1.79360 1.14460 .89065 -.0006147

580.00 64.2381 1 .95802 1 .21658 .91731 -.0006484

585.00 70.5072 2.13074 1.29156 .94452 -.0006826

171
Table 18. (Continued).

Propane I sotherm at 320 K

1 sotherm 1 sochore 1 sochore

Density Pressure Z Der i vat ive Der i vat ive Curvature

kg/m--' |vpa MPa • 17)3 /kg Mra/I\ Mra/K

5.00 .2896 .96001 .05569 .00098 -.0000002

10.00 .5571 .92329 .051 30 .00203 -.000001

1

15.00 .8027 .88695 .04696 .00319 -.0000031

20.00 1.0268 .85089 .04267 .00445 -.0000067

25.00 1 .2295 .81513 .03844 .00584 -.0000126

30.00 1.4112 .77966 .03425 .00737 -.0000224

35.00 1 .5721 .74445 .03009 .00 907 -.0000395

35.90 1 .5988 .7381

4

.02934 .00939 -.0000439

454.43 1.5988 .05831 .18978 .39604 .0002105

455.00 1.7071 .06218 .19226 .39777 .0002042

460.00 2.7243 .09816 .21485 .41316 .0001530

465.00 3.8580 .13751 .23883 .42886 .0001077

470.00 5.1151 .18038 .26427 .44489 .0000666

475.00 6.5032 .22691 .29122 .461 28 .0000288

480.00 8.0299 .27726 .31974 .47803 -.0000067

485.00 9.7033 .33159 .34990 .49516 -.0000404

490.00 11 .5317 .39005 ,38177 .51267 -.0000726

495.00 13.5239 .45282 .41540 .53059 -.0001038

500.00 15.6888 .52005 .45086 .54892 -.0001341

505.00 18.0357 .59192 .48822 .56767 -.0001637

510.00 20.5742 .66862 .52753 .58684 -.0001929

515.00 23.3144 .75031 .56888 .60646 -.0002217

520.00 26.2665 .83719 .61233 .62651 -.0002503

525.00 29.4413 .92944 .65 794 .64703 -.0002787

530.00 32.8496 1 .02726 .70579 .66800 -.0003071

535.00 36.5030 1 . 1 3084 .75594 ,68945 -.0003355

540.00 40.4130 1 .24037 .80847 .71 137 -.0003641

545.00 44.5918 1 .35608 .86346 .73377 -.0003927

550.00 49.0518 1 .47815 .92096 .75667 -.0004216

555.00 53.8057 1 .60680 .98106 .78007 -.0004508

560.00 58.8668 1 .74224 1 .04382 .80398 -.0004804

565.00 64.2485 1 .88469 1 .10932 .52840 -.0005102

570.00 69.9647 2.03437 1 .17763 .85335 -.0005406

172
Table

Propan

Density Pressure Z

kg/m-5 MPa

5.00 .3091 .96433

1 0.00 .5976 .9321

4

15.00 .8660 .90055

20.00 1.1147 .86943

25.00 1 .3443 .83876

30.00 1.5550 .80856

35.00 1 .7475 .77882

40.00 1.9220 .74953

45.00 2.0791 .72069

50.00 2.2190 .69230

55.00 2.3424 .66434

59.00 2.4293 .64224

41 1 .22 2.4293 .09215

41 5.00 2.8079 .10554

420.00 3.3701 .12517

425.00 4.0065 .14705

430.00 4.7223 .1 7131 435.00 5.5230 .19805

440.00 6.4144 .22741 445.00 7.4024 .25948

450.00 8.4934 .29442

455.00 9.6939 .33234

460.00 1 1 .0106 .37338

465.00 12.4506 .41767

470.00 14.0214 .46536

475.00 15.7305 .51659

480.00 17.5859 .57150

485.00 19.5958 .63026

490.00 21 .7687 .69300

495.00 24.1 134 .75989

500.00 26.6392 .83109

505.00 29.3555 .90676

510.00 32.2721 .98708

515.00 35.3990 1 .07221 520.00 38.7469 1 .16233

525.00 42.3265 1 .25762

530.00 46.1489 1 .35826

535.00 50.2256 1 .46443

540.00 54.5686 1 .57632

545.00 59.1900 1 .6941

3

550.00 64.1024 1 .81806

555.00 69.3186 1 .94829

18. (Continued).

e I sotherm at 340 K

1 sotherm 1 socliore 1 sochore

Der i vat i ve Der i vat i ve Curvature

MPaTTi3/kg MPa/K MPa/K^

.05972 .00097 -.0000002

.05567 .00202 -.0000008

.051 70 .00314 -.0000021

.04781 .00435 -.0000042

.04402 .00565 -.0000075

.04031 .00704 -.00001 21 .03668 .00854 -.0000184

.0331

5

.01 01

4

-.0000270

.02969 .01 185 -.0000390

.02632 .01368 -.0000559

.02302 .01566 -.0000814

.02042 .01 736 -.0001 1 34

.09518 .28646 .0004850

.10536 .29545 .0004259

. 1 1 969 .30755 .000361 2

.1 3504 .31991 .0003072

.15147 .33254 .0002606

. 1 690

1

.34548 .0002193

.18774 .35873 .0001 81

9

.20769 .37232 .0001 475

.22892 .38624 .0001 154

.251 48 .40051 .0000851

.27544 .41 515 .0000562

.30083 .4301

5

.0000284

.32773 .44552 .0000014

.3561

8

.461 28 -.0000248

.38625 .47743 -.0000506

.41 799 .49397 -.0000759

.45147 .51093 -.0001010

.48675 .52829 -.0001 258

.52388 .54607 -.0001505

.56295 .56428 -.0001751

.60401 .58292 -.0001997

.6471 3 .60200 -.0002244

.69238 .62153 -.0002492

.73982 .64151 -.0002741

.78953 .661 95 -.0002992

.84157 .68286 -.0003245

.89602 .70424 -.0003500

.95295 .72610 -.0003759

1 .01243 .74845 -.0004021

1 .07453 .771 29 -.0004287

173
Table 18. (Continued).

Propane Isotherm at 350 K

1 sotherm 1 sochore 1 sochore

Density Pressure Z Der i V at i ve Der ivati ve Curvature

kg/m3 MPa MPaTn5/kg MPa/K MPa/K^

5.00 .3188 .96623 .061 73 .00097 -.0000001

10.00 .6177 .93599 .05783 .00201 -.0000007

1 5.00 .8973 .90643 .05402 .00312 -.0000018

20.00 1 .1580 .87738 .05030 .00431 -.0000035

25.00 1 .4004 .84882 .04667 .00558 -.0000061

30.00 1 .6249 .82075 .0431

4

.00694 -.0000096

35.00 1 .8320 .79316 .03971 .00838 -.0000142

40.00 2.0221 .76605 .03636 .00990 -.0000202

45.00 2.1958 .73941 .03311 .01 152 -.0000279

50.00 2.3534 .71 324 .02996 .01322 -.0000377

55.00 2.4955 .68755 .02689 .01502 -.0000503

60.00 2.6225 .66233 .02393 .01692 -.0000669

65.00 2.7350 .63761 .02107 .01892 -.0000892

70.00 2.8334 .61 337 .01 831 .02104 -.0001 210

75.00 2.9183 .58963 .01565 .02330 -.0001701

76.97 2.9482 .58039 .01 462 .02425 -.0001981

383.34 2.9482 .1 1654 .05595 .23168 .0006864

385.00 3.0435 .11979 .05895 .23498 .0006467

390.00 3.3618 .13062 .06849 .24504 .0005488

395.00 3.7296 .14308 .07880 .25530 .0004735

400.00 4.1 511 .15726 .08994 .26579 .0004125

405.00

' 4.6305 .17325 .10195 .27654 .0003614

410.00 5.1721 .191 16 .1 1487 .28757 .0003171

415.00 5.7808 .21 108 .12876 .29889 .0002780

420.00 6.4614 .23312 .14366 .31051 .0002426

425.00 7.2191 .25740 .15961 .32245 .0002101

430.00 8.0593 .28401 . 1 7666 .33471 .0001799

435.00 8.9876 .31308 .19485 .34731 .0001 51

4

440.00 10.0098 .34473 .21425 .36025 .0001243

445.00 1 1 .1321 .37907 .23489 .37353 .0000983

450.00 12.3608 .41624 .25682 .38717 .0000732

455.00 13.7026 .45635 .2801

1

.401 18 .0000487

460.00 15.1643 .49954 .30480 .41555 .0000248

465.00 16.7530 .54594 .33095 .43029 .000001

4

470.00 18.4763 .59569 .35861 .44542 -.0000218

475.00 20.341

7

.64893 .38784 .46093 -.0000447

480.00 22.3573 .70581 .41869 .47684 -.0000674

485.00 24.531

5

.76646 .451 24 .4931

4

-.0000901

490.00 26.8727 .83104 .48554 .50986 -.0001 126

495.00 29.3899 .89970 .52165 .52698 -.0001352

500.00 32.0923 .97261 .55963 .54453 -.0001 579

505.00 34.9894 1 .04991 .59956 .56250 -.0001806

510.00 38.091

2

1.13178 .64149 .58090 -.0002034

515.00 41 .4078 1 .21838 .68549 .59975 -.0002264

520.00 44.9497 1 .30988 .73164 .61903 -.0002496

525.00 48.7279 1 .40645 .77999 .63877 -.0002730

530.00 52.7534 1 .50828 .83063 .55897 -.0002967

535.00 57.0380 1 .61554 .88361 .67963 -.0003207

540.00 61 .5936 1 .72842 .93901 .70076 -.0003449

545.00 66.4323 1 .84710 .99690 .72237 -.0003696

550.00 71 .5669 1 .97177 1 .05736 .74447 -.0003946

174
Table 18. (Continued).

Propane Isotherm at 360 K

1 sotherm 1 sochore 1 sochore

• -1- Dens 1 ty rressure L Der Wat i ve Der i vat i ve Curvature

kg/ i^a Mra • nv/ Kg Mra/I\ Mra/l\

10.00 .6377 .93953 .05997 .00200 -.0000006

20.00 1.2009 .88463 .05274 .00428 -.0000030

R'^1 7Q .UUDcSP — .UUUUU /o 7RnQn nnQ79 — OOOni RQ

9.4 f!4n • 7"^1 RQ . \J J J J\J 01 9Qn — nnon9Hi

9 7RRR • fiR4 7ft • \) £^ 1 KJ f 01 ^"^7 - n0004'=iR 70 nn n9ni 9 — nnnn 71

4

Rn nn 3. 2385 .59639 .ni 7fii n94i fi - nnni oq7

90.00 3 .3928 ,55537 .01 331 .02849 - .noni 799

1 nn . nn 3.5064 .51 657 .00949 .0331

9

1 05 .05 3.5498 .49781 .00773 .03579 -.nnn4995

345. 52 3.5498 .1 51 36 .02308 . 1 7379 .001 0800

350.00 3.6630 .1 541

8

.02749 . 1 8069 .0008996

3.9928 .16340 .03884 .1 9646 .nnnfS4Rn 370.00 4 ,4477 • 1 7709 .05254 .21 305 •nnnsnfi9

5. 0525 .1 9588 .06888 .23062 .noo4oa7

390.00 5 . 8352 .22043 .ORfllR .24930

4nn nn 6. 8269 .251 44 -1 1 07"^ • I I \j 1 ^ .2691

4

0009797

41HIV-'. n nn R nfil R ?RQfiR 9Qn91 00091 Q9

420.00 9.5773 .33594 • 1 6692 . -* 1 £. J J 0001 70R

A'^n nn 11 41 44 "^Qi n7 0001 9S7

4/1 n nn 1 fil 7R ^f^1 97 OOOOR9f^ 450.00 16.2357 .53153 ,3^11A .0000409

460.00 19.3205 .61878 .33369 .41566 -.0000002

470.00 22.9290 .71872 .38902 .44510 -.0000409

480.00 27.1221 .83244 .45069 .47609 -.0000817

490.00 31 .9654 .96107 .51916 .50868 -.0001228

500.00 37.5296 1 .10580 .59493 .54292 -.0001645

510.00 43.8900 1 .26785 .67851 .57885 -.0002069

520.00 51 .1276 1 .44852 .77043 .61653 -.0002502

530.00 59.3283 1.64914 .87125 .65601 -.0002947

540.00 68.5840 1 .871 12 .98151 .69734 -.0003405

175
Table 18. (Continued).

Propane I sotherm at 365 K

1 sotherm 1 sochore I ^nr hnr

e

Den s i ty Pressure z Der i vat i ve Der i vat i ve Curvature

Wa MPaTTi3/kg MPa/K MPa/K^

10.00 .6477 . 94 1 20 .061 03 .00200 -.0000005

20.00 1 .2223 .88802 .05394 .00426 -.0000027

30.00 1 .7280 .83694 .04726 .00681 -.0000071

40.00 2.1687 .78780 .04095 .00965 -.00001 43 50.00 2.5481 .74051 .03501 .01 277 -.0000248

60.00 2.8701 .69506 .02945 .0161

5

-.0000394

70.00 3.1386 .651 50 .02432 .01 979 -.0000592

80.00 3.3581 .60993 .01965 .02367 -.0000861

90.00 3.5333 .57045 .01548 .02776 -.0001232

100.00 3.6693 .5331

7

.01 180 .03207 -.0001 769

1 1 0.00 3.7711 .49814 .00864 .03658 -.0002620

1 20.00 3.8436 .46541 .00595 .041 34 -.0004220

1 29.01 3.8877 .43786 .00388 .04602 -.0007955

31 6.85 3.8877 .1 7829 .00970 . 1 4060 .001 621

4

320.00 3.9208 .1 7804 .01 135 . 1 4449 .001 3495

330.00 4.0638 .1 7894 .01 751 .1 5699 .000901

3

340.00 4.2763 .1 8276 .02528 .17013 .0006853

350.00 4.5758 .18997 .03494 .18416 .0005525

360.00 4. 9823 .201 1

0

.04674 .19918 .0004589

370.00 5.51 87 .21 673 ,06095 .21 525 .0003865

380.00 6 . 2 1 03 .23747 .07785 .23245 .0003268

390.00 7.0856 .26399 .09773 .25081 .0002750

400.00 8.1 758 .29700 . 1 2089 .27038 .0009283

41 0.00 9.51 54 .33723 .1 4766 .291 21 .0001 851 420.00 1 1 . 1 421 .38548 .1 7837 .31 334 .0001 441 430.00 1 3.0971 .44258 .21 337 .33680 .0001 045

440.00 15.4251 .50940 .25304 .36164 .0000657

450.00 18.1748 .58687 .29777 .38791 .0000274

460.00 21 .3988 .67595 .34797 .41564 -.0000108

470.00 25.1539 .77766 .40407 .44487 -.0000492

480.00 29.5015 .89307 .46653 .47566 -.0000880

490.00 34.5073 1 .02328 .53581 .50805 -.0001 273

500.00 40.2421 1 .16948 .61242 .54209 -.0001674

510.00 46.7817 1 .33287 .69686 .57781 -.0002084

520.00 54.2071 1.51473 .78967 .61528 -.0002505

530.00 62.6047 1 .71 638 .89139 .65454 -.0002938

176
Table 18. (Continued).

Propane Isotherm at 369.85 K

1 soi'h©rm 11 ^ophnrp \_> 1 1 v./ 1 ^ 1 cinrhnr*^

L/C?! lot 1 y

\ \ ^ ^ ^ U I z l-'^t 1 V U 1 1 V/ u 1 V a 1 u L ^

k g/ni3 MPa MPa • m3 /k g MPa/K MPa/K^

1 0.00 .6574 .94275 .06206 .00200 -.0000005

20.00 1 .2429 .891 1

8

.0551

1

.00425 -.0000025

30.00 1 .7609 .841 72 .04856 .00678 -.0000066

40.00 2.21 53 .7941

8

.04238 .00958 -.00001 30

50.00 2 . 6098 .74848 .03657 .01 265 -.0000272

fin 00 2.9480 .70457 .031 1

4

.01 598 -.0000346

70.00 3.2339 .66249 .0261

2

.01 953 -.0000507

80.00 3.471

9

.62234 .021 55 .02329 -.000071

2

90.00 3-666fi .58421 .01 747 .02724 -.0000970

1 00 00 3.8229 .5482

1

.01 388 .031 34 -.0001 294

1 1 0.00 3.9458 .51 439 .01 078 .03556 -.0001 703

1 70 00 4.0402 .48281 .0081

7

.03989 -.0007278

4 1 1 n7 9 H J -JH J nnfini . n449R UHH ZQ - nnn?Qi

1 Art nn 4 1 fil 7 49fi9R nn49'i n4R79 • \J\J\J -) 1

1 "in nn A. 1 Q71 .401 24 .00287 .0531

7

m \J\J\j J 1

1 fin nn 4 99n'^ nni R9 ns7fii

1 10 00 4 9'^44 ^'i 71 Q nni nfi nfi9nn — OOlOOfiS

1 Rn nn 4 9499 ^^7Qfi nnn'i4 .UDD-J Of^fi,'', 1

1 - noi RAO"^

1 on nn 4 94^R '^9n4'=; 00077 9\Jn7n4R / \JHO 9nn nn 4^ . 9479 Z*t /z Tn4R9 nnnnfi 9\Jn744S I^HJ - 00'=i'^P7P Tin nn 4 94 74 9Qnn4 nnnn i 019.00 99n nn 4^ . Z4947^/ J . 97fiRfi Z / DOD . uuuuu nRi n4 —/I 07Q9 997

'j'^n nn 4H . 947^ Z4 / . 9fi4R9 ZD^ OZ nnnni 9\JOJ^ nR'^QSJ • 01U 1 Q^709 / uz 94n nn 4 947Q . Z9'S'^RI JJO 1 OOOOQ nR7QR • 00f=^4'^QS UUU*+_/7^

£.9RnJ\) 9\J\J nn 4 94Q7 94'^7fi nnn'^i .UnQ97Q J7Z / ^ 00'^A"^"^'=i • UUJJ'f-JJ? 9 fin nn 4 9RCin 9'^4fiR nnn 7Q nQR'';4 • 00999^7 UUZ Z Z J / 97n.nn 4 .2668 . 99fifi1 .nni fi'i . 1 0466 .001 ftO'^R 09,0.00 4. 2896 .21 969 .00301 . 1 1 1 76 001 9"^4S 290.00 4. 3292 .21 407 .00504 .1 1 96 8 .OOOQQ'^4 • WWW-? *-t ^nn 00 .20999 .00790 . 1 2846 000R947

31 0.00 4 .4907 .20773 .01 1 80 .13812 .0007000 • WWW / www 320.00 4.6332 .20762 .01 692 . 1 4872 .0006035

330.00 4.8339 . 21 006 .02349 . 1 6028 .0005259

340.00 5.1 085 .21 546 .031 73 . 1 7284 .000461

2

350.00 5.4748 .22431 .04188 .18645 .0004057

360.00 5.9533 .2371

4

.05420 .201 1

3

.0003565

370.00 6.5669 .25451 .06895 .21 694 .00031 1

9

380.00 7. 341

3

.27704 .08641 .23389 .0002706

390.00 8.3051 .30537 . 1 0687 . 25203 .000231

6

400.00 9. 4897 .34021 . 1 3063 .271 41 .0001 942

41 0.00 1 0.9298 .38228 . 1 5802 .292 04 .0001 578

420.00 1 2.6634 .43236 . 1 8937 .31 398 .0001 220

430.00 1 4.731

7

.491 29 .22504 .33726 .0000866

440.00 17.1798 .55990 .26539 .361 93 .000051

2

450.00 20.0564 .63913 .31082 .38801 .0000157

460.00 23.4145 .72992 .361 74 .41556 -.0000202

470.00 27.3110 .83328 .41 858 .44462 -.0000566

480.00 31 .8074 .95025 .48180 .47522 -.0000936

490.00 36.9698 1.08193 .55187 .50742 -.0001314

500.00 42.8692 1.22949 .62928 .541 27 -.0001701

510.00 49.5816 1 .39412 .71455 .57680 -.0002099

520.00 57.1883 1 .57708 .80822 .61407 -.0002508

530.00 65.7758 1.77967 .91082 .65312 -.0002929

177
Table 18. (Continued).

Propane Isotherm at 375 K

1 -^yj <^n+hprm \ 1 1^ 1 Ml 1 <^t~>r'hnP(=» 1 co^hor"*^

L/c;i 1 o t 1 y

\ \ c?o 0 Ul C Lvc?) 1 V a 1 1 vc LyCT 1 V a 1 1 vo Vm*

1uiir* V/Vol?^ ui1 r~ 0

k 9/m-^ rir a IT a

.

llr rrO //Ifr\ n

y

rli a / 1\ rli a / r\

1 0.00 ,5677 . 94434 .0631

5

.001 99 -.0000005

1 . 2648 .89439 .05633 .00424 - nnnnn9'^

1 7QS7 .04992 nnfi7's 40.00 2. 2645 .80067 .04389 .00952 -.00001 1

R

50.00 2.6746 . 75655 .03820 .01 254 -.00001 99

60.00 3.0298 .71 41

8

.03289 .01 581 - .0000306

70.00 3 .3339 .67359 .02799 .01 929 -.0000439

80.00 3.591

0

.63484 .02351 .02295 -.0000601

90.00 3.8057 .59805 .01 951 .02679 -.0000799

1 00-00 3.9827 .56328 .01 598 .03075 -.0001 01

9

1 1 0.00 4 . 1 2 70 .53062 .01 294 .03481 -.0001 • \J\J \J \ 958 £- J \J

1 20.00 4.2431 .50008 .01 036 .03895 -.0001 523

1 30.00 4 .3356 .47168 .00821 .0431

2

-.0001797

1 40.00 4.4086 .44537 .00646 .04731 -.0002057

1 50.00 4.4660 .42108 .00507 .051 48 -.0002272

1 60.00 4.5110 .39874 .00399 .05563 -.0002400

1 70.00 4.5466 .37825 .0031

8

.05975 -.0002397

1 80 .00 4. 5755 .35951 .00263 .06385 -.0002227

1 90.00 4.5998 .34240 .00228 .06796 -.0001881

200.00 4.621

7

.32683 .0021

2

.0721

4

-.0001 377

2 1 0 . 00 4.6428 .31 268 .00211 .07643 -.0000752

220.00 4.6642 .29985 .0021

8

.08090 -.0000045

230.00 4.6866 .2881

9

.00232 .08560 .0000792

240.00 4.71 09 .27761 .00257 .09059 .0001 521 4.7388 .26809 .00304 .09593 .0009302

9f^n no A 779Q . 1 ni 74 .0003000

970 no H . 0 1 D / . ^ 1 nnsn"^ 1 nRnQ nnn^'^'^4 4 ft7'=)"^ .nnfi7Q . 1 1 i^i n .noo3q"5i

9Qn on 941 fi4 .nnQ94 . 1 2284 .00041 96

s . nfi^i UD_? 1 ni 9Rfi 1 "^1 AO onnAi

Tin nn • Z.D 1 DO . u 1 D y_> 1 4nR"'i •UUUfuou

TOO nn n99'i'i •

1

\ S1J \ 11 Qy nnn"^Qi i . UUU-^ -7 1 1 j?j>u ~k~kr\ • onuu 949R1 • nnn"^ftRf^ UUU-JOOD

j)4U. ~^AC\ nnuu ^ nO/l 1 D. UU4

1

.Z4y 94Q7fi/D n'^RAn 1 74flfl . 1 / 400 • nno"^A97 UUU_J*IZ / j>9U T^^n • nnuu 0

.

9^;n9'^ . n4Qi U4y 1 n

u

.

1

i RR9Q oozy nnn^^i a9k • UUUJ> 1 40

j>DU TfiA .uunn D. J? -) 974 7^^ •UDnfti1 QQyy . 9n97R zuz /

0

nnn9RS i J-?7n/ u .uunn 7 f^RRn . zy->o / n77'^'^ 91 R'^IQ . z 1 aj>y .UUUZ!-)9y nnn9RSQ

joK) ?QA « nnuu ^1 R1 Q .Uy94U nQRAn 9 ^'Sl ft.

Z

j9 I 0 nnn99'=jft "^on nn j)yu. uu Q ^;n^n y . DUDU "^/t RXR • J'4dJ>9 . 1 1 D4o . Z 9 J 1 J nnm qr"^ • uuu 1 yi!>_> /'tuu nn . nnuu 1 n RRQQ "^RSnA 1 4nRQ 979 '^^

. Z / Z J> J .uuu nnm! DH J

At \

1 nu • nnuu 400QO • 4zoyo .

1

1 f^RQ4 DO y4 . 9Q97Q z y z / y nnm '^'\a • uuu 1 JJ>H 4ZAic\u .uunn 1 A 9P1

Q

. 4 ou yJ . 9nnQ7 zuuy

/

. J 1 490 nnm ni q •UUU 1 u 1

y

A~KC\ 4j)u • nnuu 1 0 .4Dy / . SAl !-)4 1 7n/U . 3 J /D / •uuuu /uu

440.00 19.0443 .61 215 .27841 .36215 .0000375

450.00 22.0549 .69316 .32458 .38806 .0000045

460.00 25.5543 .78569 .37627 .41543 -.0000293

470.00 29.6000 .89071 .43389 .44431 -.0000638

480.00 34.2535 1 .00927 .49792 .47473 -.0000992

490.00 39.5813 1 .14245 .56882 .50674 -.0001355

500.00 45.6545 1 .29139 .64709 .54038 -.0001728

510.00 52.5494 1 .45727 .73324 .57572 -.00021 13 520.00 60.3474 1.64134 .82781 .61278 -.0002510

530.00 . 69.1355 1.84488 .93134 .65161 -.0002920

178
Table 18. (Continued).

Density Pressure

kg/m3 MPa

10.00 .6777

20.00 1.2859

30.00 1 . 8294

40.00 2.31 19 50.00 2.7371

60.00 3.1085

70.00 3.4298

80.00 3.7050

90.00 3.9387

100.00 4.1353

110.00 4.2996

120.00 4.4361

130.00 4.5492

140.00 4.6429

150.00 4.7209

160.00 4. 7866

1 70.00 4.8428

180.00 4.8924

190.00 4.9377

200.00 4.9810

210.00 5.0242

220.00 5.0686

230.00 5.1154

240.00 5.1654

250.00 5.2208

260.00 5.2846

270.00 5.3609

280.00 5.4550

290.00 5.5735

300.00 5.7246

310.00 5.9183

320.00 6.1663

330.00 6.4824

340.00 6.8825

350.00 7.3851

360.00 8.0107

370.00 8.7829

380.00 9.7277

390.00 10.8739

400.00 12.2535

410.00 13.9014

420.00 15.8559

430.00 18.1588

440.00 20.8555

450.00 23.9952

460.00 27.631

1

470.00 31 .8207

480.00 36.6259

490.00 42.1133

500.00 48.3542

510.00 55.4253

520.00 63.4081

Propane Isotherm at 380 K

1 *^o1"h(^rm -J Vi* 1 1 1 1 1 1 z Der '-'Vi'l 1 \/ri+ V (J 1 r

1 \/^ ypa • m3 /k n

.94583 .06421 .89739 .05752

.85109 .051 24

.80669 .04533

.76404 .03977

.72308 .03457

.68384 .02976

.64639 .02537

.61080 .021 44

.5771

6

.01 797

.54554 .01 496

.51 595 .01 241 .48840 .01 028

.46286 .00853

.43927 .0071

3

.41 754

.39760 .00525

.37935 .00471 .36271 .34760

.33392

.321 56 .00455

.31041 .30039 DO'S? .291 47 .28368 .00693

.27712 .00842

.271 91 .26824 .01 333

.26633 .01 706

.26646 .02 1 87 .26895 .02795

.27416 .03553

.28253 .04481 .29449 .05604

.31057 .06948

.33131 .08539

.35729 . 1 0404

.38915 . 1 2573

.42755

.47322 . 1 7945

.52691 .21 21

5

.58940 .24919

.661 55 .29097

.74422 .33786

.83836 .39028

.94494 .44867

1 .06497 .51348

1 .19954 .58519

1 .34976 .66428

1 .51680 .75129

1 .70190 .84673

1 Z>\J ^O(^hor"*a \j \ \\J\ c 1 sochor©

Hi^r" L-'C/i I \/?*+ 1 \icx 1 V a 1 1 V t? Curvature

MPa/K MD ^ /I/ 2

.001 99 •UUUUUU4

.00423

.00672

.00946 "• UUUU 1 (Jo .01 245 — nnnni qa

.01 566 UUUU^: / J

. 0 1 908 — •UUUUJJO /

.02642 — AAAAC7I

.03029 _ AAAA D"^ c; .03425 — nnAiAA*^

_ AAA 1 1 T K .04235 — AAA1 "KOQ ,04645 _ AAA 1 yl c:0 "•UUU

1

• \) j\j j\j "•UUU

1

Dl

1

. U J^OO "• UUU

1

d3o

." AAA 1 ylCn •UUUl 4Dy

_ AAA 1

"7 1 0 "•UUUl D\ 0 —~ AAA1 AQQ •UUU 1 UOO

0 71 fi"^ AAAA "7 00 -• UUUU /oo AAAA A "•UUUU4.54

_ AAAAAT"? "• UUUUU^

/

. \JO^ OD AAA A "ZOT

• UUUU-59J

noi 1 A •0000846

AA A 1 1 A"Z

• UUUl j>\j5

1 n9Rf^ •UUUl /42

1 OQ/IR A A AO 1 "Z *^ .00021 36

1 1 f^f^A . 1 1 D04 AAA 0 /I ^0 .0002452

.. 1\ li.^^^ J\J AAAO"7A(C .UUUz /Uo

. 1 ^"^1 1 AAAOO A .UUUzooO

.. 1

1 ^i-J J A A AO AO

A

.uuuzy^y

AAAOAO

A

. 1641

5

nnn9R/i q

. 1 7641 nnno7o r . uuuz / z 9

. 1 8970 AAAOC/r-z .UUUZDuJ

.20408 .uuuz j)oy .21 956 AAAO 1 c:o

. £- -JDZ \} AAA 1 A1

T

.UUUl yi

/

AAA \ CC~} •UUUlDD

/

9 7-? no AAA 1 it AC .UUUl 4U5

. ^ 1 A A A 1 1 TO •UUU 1

1

dZ .uuuuo4y AAAAQ/I Q

.0000557

.36231 .0000256

.38806 -.0000054

.41527 -.0000373

.44397 -.0000702

.47422 -.0001041

.50605 -.0001391

.53951 -.0001752

.57466 -.0002125

.61 152 -.000251

1

179
Table 18. (Continued).

Propane Isotherm at 390 K

1 sotherm 1 sochore 1 sochore

Dens i ty Pressure Z Der i vat i ve Der ivati ve Curvature

kg/nn3 MPa MPa-niS/kg MPa A MPa A2

20.00 1 .3281 .90305 .05987 .00421 -.0000019

40.00 2,4050 .81800 .04817 .00935 -.0000091

60.00 3.2638 .73975 .03784 .01542 -.0000224

80.00 3.9294 .66795 .02898 .02222 -.0000407

100.00 4.4344 .60304 .02182 .02957 -.0000617

120.00 4.8137 .54552 .01640 .03731 -.0000809

140.00 5.1012 .49551 .01260 .04530 -.0000928

160.00 5.3270 .45277 .01020 .05351 -.0000920

180.00 5.5171 .41682 .00900

' .05202 -.0000759

200.00 5.6941 .38717 .00887 .07104 -.0000454

220.00 5.8773 .36330 .00956 .08084 -.0000042

240.00 6.0802 .34452 .01087 .09175 .0000441

260.00 6.3202 .33057 .01342 .10413 .0000950

280.00 6.6314 .32208 .01814 .1 1848 .0001409

300.00 7.0678 .32038 .02614 .13533 .0001743

320.00 7.7077 .32755 ,03874 .15523 .0001902

340.00 8.5586 .34632 .05753 . 17867 ,0001882

360.00 10.0621 .38010 ,08432 ,20609 ,0001707

380.00 12.0984 .43297 .121 16 .23785 ,0001412

400.00 14.9907 .50965 .17032 .27429 ,0001025

420.00 19.0099 .61552 .23429 .31573 .0000568

440.00 24.4795 .75659 .31585 .36246 .0000053

460.00 31.7816 .93957 .41807 .41482 -.0000513

480.00 41.3627 1.17187 .54434 .47313 -.0001 128 500.00 53.7405 1 .46165 .69840 .53774 -.0001794

520.00 69.5108 1 .81785 .88428 .60901 -.0002512

Propane Isotherm at 400 K

20.00 1.3701 .90830 .06220 .00419 -.0000017

40.00 2.4992 .82844 .05096 ,00928 -.0000079

60.00 3.4169 .75509 .04103 .01521 -.0000187

80.00 4.1497 .68776 .03249 .02185 -.0000331

100.00 4.7273 .62580 .02556 .02903 -.0000485

120.00 5.1832 ,57270 .02030 ,03651 -.0000514

140.00 5.5500 .52563 .01663 .04451 -.0000683

160.00 5.8580 .48545 .01438 .05273 -.0000663

180.00 6.1339 .45183 .01341 .06138 -.0000543

200.00 6.4024 .42445 .01363 .07055 -.0000332

220.00 5.6855 .40293 .01481 .08080 -.0000051

240.00 6.9995 .38670 .01676 .09210 .0000278

260.00 7.3657 .37563 ,02017 .10490 .0000628

280.00 7.822^ .37042 ,02599 .1 1964 .0000956

300.00 8.4288 .37253 ,03534 .13678 ,0001213

320.00 9.2684 .38403 .04956 . 1 5683 ,0001360

340.00 10.4538 .40767 .07019 .18028 ,0001378

360.00 12.1307 .44679 .09904 .20755 ,0001270

380.00 14.4833 .50536 ,13811 .23907 ,0001050

400.00 17.7382 .58798 .18966 .27517 ,0000736

420.00 22. 1695 .69988 .25619 .31618 .0000344

440.00 28.1041 .84690 ' .34047 .35243 -.00001 14 460.00 35.9271 1.03557 .44557 .41425 -.0000631

480.00 46.0882 1.27310 .57489 .47197 -.0001202

500.00 59.1089 1.56747 .73217 .53593 -.0001828

180
Table 18. (Continued).

Pro pa n e Isotherm at 420 K

1 sotherm 1 sochore 1 sochore

Dens ity Pressure Z Der i vat i ve Der i vati ve Curvature

kg/m3 MPa MPa .m3/kg MPa/K MPa/K-^

20.00 1 .4535 .91774 .06680 .00416 -.0000013

40.00 2.6834 .84712 .05641 .00914 -.0000060

60.00 3.7178 .78245 .04723 .01489 -.0000138

80.00 4.5808 ,72306 .03929 .02129 -.0000235

100.00 5.2994 .66919 .03283 .02823 -.0000332

120.00 5.9047 .62136 .02796 .03561 -.0000407

140.00 6.4284 .57983 .02467 .04341 -.0000442

160.00 6.9013 .54467 .02286 .05168 -.0000425

180.00 7.3522 .51579 .02248 .06052 -.0000353

200.00 7.8097 .49309 .02349 .0701

1

-.0000231

220.00 8.3002 .47642 .02573 .08067 -.0000070

240.00 8.8458 .46543 .02904 .09248 .0000120

260.00 9.4739 .46013 .03415 . 10581 .0000321

280.00 10.2307 .46139 .04210 .12105 .0000514

300.00 1 1 .1843 .47078 .05404 . 1 3860 .0000671

320.00 12.4276 .49042 .07131 .15889 .0000768

340.00 14.0824 .52303 .09545 .18239 .0000787

360.00 16.3032 .57187 .12823 .20950 .0000719

380.00 19.2822 .64076 .17161 .24065 .0000564

400.00 23.2533 .73409 .22783 .27620 .0000326

420.00 28.4976 .85681 .29937 .31651 .0000012

440.00 35.3486 1 .01448 .38899 .361 93 -.0000370

460.00 44.1981 1 .21331 .49976 .41279 -.0000814

480.00 55.5027 1.46015 .63510 .46944 -.0001317

500.00 69.7906 1.76259 .79874 .53222 -.0001879

Propane 1 sotherm at 450 K

20.00 1.5778 .92977 .07360 .00413 -.0000010

40.00 2.9552 .87074 .06435 .00899 -.0000042

60.00 4 . 1 590 .81697 .05620 .01455 -.0000094

80.00 5.2103 .76761 .04913 .02072 -.0000156

100.00 6.1334 .72288 .04342 .02743 -.0000216

120.00 6.9573 .68332 .03924 .03464 -.0000261

140.00 7.7138 .64939 .03668 .04236 -.0000282

160.00 8.4352 .62135 .03573 .05066 -.0000275

180.00 9.1539 .59937 .03643 .05965 -.0000238

200.00 9.9036 .58361 .03881 .06951 -.0000175

220.00 10.7170 .57413 .04276 .08043 -.0000091

240.00 1 1.6234 .57080 .04817 .09265 .0000007

260.00 12.6589 .57383 .05585 .10642 .00001 1

1

280.00 13.8798 .58424 .06690 .12208 .0000209

300.00 15.3655 .60365 .08254 .13996 .0000286

320.00 17.2212 .63427 .10414 .16046 .0000329

340.00 19.5812 .67877 .13325 .18397 .0000324

360.00 22.6127 .74031 .17159 .21090 .0000261

380.00 26.5196 .82252 .22114 .24164 .0000136

400.00 31.5475 .92954 .28407 .27656 -.0000054

420.00 37.9881 1 .06601 .36286 .31603 -.0000307

440.00 46.1856 1.23713 .46024 .36041 -.0000622

460.00 56.5421 1 .44869 .57930 .41005 -.0000996

480.00 69.5247 1.70710 .72344 .46531 -.0001427

181
Table 18. (Continued).

Propane Isotherm at 500 K

1 sotherm 1 sochore 1 sochore

Dens i ty Pressure Z Der i vat 1 ve Der ivat i ve Curvature

kg/m3 MPa MPa .nn3/kg MPa/K MPa/K^

20.00 1.7830 .94565 .08473 .00409 -.0000006

40.00 3.4002 .90168 .07719 .00882 -.0000026

60.00 4.8766 .86212 .07059 .01418 -.0000057

80.00 6.2300 .82604 .06493 .02012 -.0000093

100.00 7.4823 .79367 .06054 .02660 -.0000127

120.00 8.6621 .76568 .05771 .03364 -.0000155

140.00 9.8023 .74268 .05661 .04127 -.0000171

160.00 10.9390 .72521 .05738 .04958 -.0000174

180.00 12.1 108 .71368 .06015

' .05868 - -.0000164

200.00 13.3590 .70851 .06504 .06873 -.0000143

220.00 14.7262 .71002 .07200 .07992 -.00001 13 240,00 16.2522 .71830 .08100 .09244 -.0000079

260.00 17.9859 . 73378 .09296 .10653 -.0000044

280.00 19.9982 .75760 .10906 .12248 -.0000016

300.00 22.3847 .79147 .13061 .14057 -.0000000

320.00 25.2683 .83759 .15902 .16^15 -.0000006

340.00 28.8019 .89856 .19588 .18455 -.0000042

360.00 33. 1 71

.97739 .24294 .21114 -.00001 13 380.00 38.6002 1.07749 .30213 .24129 -.0000226

400.00 45.3520 1.20266 .37563 .27535 -.0000384

420.00 53.7371 1 .35716 .46589 .31370 -.0000589

440.00 64.1 173 1.54571 .57563 .35667 -.0000844

Propane Isotherm at 550 K

20.00 1 .9867 .95788 .09569 .00406 -.0000004

40.00 3.8386 ,92539 .08968 .00872 -.0000018

60.00 5.5794 .89671 .08453 .01395 -.0000039

80.00 7.2257 .87097 .08027 .01974 -.0000063

100.00 8.7985 .84844 .07726 .02608 -.0000086

120.00 10.3270 .82986 .07589 .03300 -.0000107

140.00 1 1 .8468 .81599 .07643 .04055 -.0000121

160.00 13.3982 .80749 .07909 .04883 -.0000130

180.00 15.0258 .80497 .08408 .05795 -.0000132

200.00 16.7784 .80897 .09161 .06805 -.0000129

220.00 18.7073 .81997 .10168 .07932 -.0000124

240.00 20.8623 .83823 .11431 .09193 -.00001 17 260.00 23.3036 .86429 .13052 .10612 -.00001 13 280.00 26.1151 .89939 .15155 .12212 -.00001 16 300.00 29.4069 .94524 .17878 .14021 -.0000129

320.00 33.3174 1.00400 .21368 .16069 -.0000158

340.00 38.0160 1.07820 .25788 .18387 -.0000209

360.00 43.7061 1.17072 .31314 .21009 -.0000286

380.00 50.6282 1 .28476 .38142 .23969 -.0000394

400.00 59.0642 1.42389 .46490 .27301 -.0000537

420.00 69.3419 1 .59206 .56602 .31039 -.0000717

182
Table 18. (Continued).

Propane Isotherm at 600 K

1 sotherm 1 sochore 1 sochore

Density Pressure Z Der i vat i ve Der i vat i ve Curvature

kg/m-> NPa MPa .rrp/ kg MPa/K MPa/K^

20.00 2. 1893 .95760 . 10653 .00404 -.0000003

40.00 4.2724 .94414 . 101 95 .00864 -.000001

3

60.00 6.2725 .92409 .098 18 .01378 -.0000028

80.00 8.2055 .90665 .09529 .01947 -.0000046

100.00 10.0927 .89214 .09369 .02571 -.0000064

120.00 1 1 .9648 .88135 .09385 .03254 -.0000081

140.00 13.8605 .87514 .09610 .04002 -.0000095

160.00 15.8246 .87425 .10073 .04825 -.0000106

180.00 17.9076 .87940 . 10803 .05734 -.00001 14 200.00 20.1653 .89125 .1 1825 .06743 -.0000121

220.00 22.6576 .91036 .13145 ,07869 -.0000128

240.00 25.4434 .93710 .14771 .09130 -.0000135

260.00 28.5936 .97212 .16811 .10546 -.0000147

280.00 32.2042 1.01666 .19397 .12140 -.0000165

300.00 36.3982 1.07246 .22670 .13939 -.0000192

320.00 41 .3284 1 . 14162 .26786 .1 5969 -.0000233

340.00 47. 1796 1.22659 .31908 ,18260 -.0000291

360.00 54. 1709 1 .3301

1

.38219 .20843 -.0000370

380.00 62.5595 1 .45524 .459 15 ,23749 -.0000474

Propane 1 sotherm at 650 K

20.00 2.391

1

.97549 . 1 1 730 ,00403 - .0000002

40.00 4.7029 .95934 . 1 1 406 ,00858 -.000001

0

60.00 6.9585 .94630 . 1 1 1 62 ,01 366 - .0000022

80.00 9. 1737 .93566 . 1 1 008 ,01 927 -.0000036

100.00 1 1 .3707 .92779 . 1 0990 .02542 -.0000050

120.00 13.5823 .92353 .11161 .032 18 -,0000055

140.00 15.8504 .92379 . 1 1 561 .03959 -,0000078

160.00 18.2244 .92938 . 1 2226 ,04776 -,0000091

180.00 20.7606 .94109 .13189 ,05680 -,0000102

200.00 23.5220 .95963 .14482 ,06684 -,00001 14 220.00 26.5760 .98566 .161 14 .07805 -,0000127

240.00 29.9908 1.01962 .18100 .09060 -,0000143

260.00 33.8473 1 .06221 .20554 .10468 -,0000162

280.00 38.2525 1.1 1471 .23612 .12051 -,0000188

300.00 43.3420 1.17883 .27422 .13834 -,0000223

320.00 49.2819 1.25661 .32143 .15842 -,0000270

340.00 56.2712 1 .35042 .37945 .18103 -.0000331

360.00 64.5440 1.46290 .4501

1

.20646 -.0000409

j

183
Table 18. (Continued).

Propane Isotherm at 700 K

1 sotherm 1 sochore 1 sochore

Dens ity Pressure Z Der i vat i ve Der i vat! ve Curvature

kg/m3 NPa MPa -m^/kg Wa/K MPa/K^

20.00 2.5922 .98202 .12800 .00402 -.0000002

40.00 5.1309 .971 88 .12604 .00854 -.0000008

60.00 7.6391 .96465 .12490 .01356 -.0000017

80.00 10.1329 .95967 .12468 .0191

-.0000029

100.00 12.6360 .95739 .12592 .02520 -.0000041

120.00 15.1834 .95866 .12920 .03188 -.0000054

140.00 17.8206 .96443 .13497 .03923 - .0000067

160.00 20.601

.97556 .14364 .04733 -.0000080

180.00 23.5881 .99288 .15561 .05631 -.0000094

200.00 26.8501 1 .01 71

.17123 .06629 -.0000108

220.00 30.4627 1 .04912 . 1 9066 .07742 -.0000125

240.00 34.5027 1 .08923 .21408 .08988 -.00001 44 260.00 39.0606 1 .1 3826 .24268 .10385 -.0000168

280.00 44.2541 1 .19749 .27789 .1 1954 -.0000198

300.00 50.2304 1 .26859 .32123 .1 3718 -.0000237

320.00 57.1685 1 .35358 .37434 .1 5703 -.0000286

340.00 65.2806 1 .45473 .43894 .17933 -.0000347

184
Table 19. The Joule-Thomson inversion locus for propane.

Temp. Dens i ty Pressure

K kg/in3 MPa

300 491.

1

1 .607

310 485.4 4.875

320 479.8 7.952

330 474.2 10.847

340 468.6 13.574

350 463.1 16.143

360 457.7 18.564

370 452.3 20.848

380 447.0 23.001

390 441.7 25.030

400 436.5 26.945

410 431.4 28.749

420 426.3 30.449

430 421.2 32.051

440 416.2 33.558

450 41 1 .3 34.976

460 406.3 36.309

470 401.5 37.561

480 396.7 38.734

490 391.9 39.835

500 387.2 40.862

510 382.5 41.823

520 377.9 42.716

530 373.3 43.549

540 368.7 44.319

550 364.1 45=031

560 359.6 45,688

570 355.2 46.289

580 350.7 46.839

590 346.3 47.337

600 341.9 47.787

610 337.5 48.191

620 333.2 48.548

630 328.8 48.862

640 324.5 49.132

650 320.3 49.363

660 316,0 49.552

670 311.7 49.705

680 307.5 49.819

690 303.3 49.899

700 299.1 49.945

710 294 .9 49.957

720 290.8 49.940

730 286.6 49.892

740 282.5 49.814

750 278.4 49.71

1

760 274.4 49.582

770 270.3 49.430

780 266.3 49.255

790 262.3 49.060

800 258.4 48.846

810 254.4 48.615

185
Table 20. Thermophys ica I properties of saturated liquid propane.

Temp. Pg P £

K MPa kg/in3

85.470 .16895E-09 733.34

90.000 .96854E-09 728.67

95.000 .54123E-08 723.55

100.000 .25139E-07 718.44

105.000 .99697E-07 713.34

110.000 .34511E-05 708.26

115.000 .10618E-05 703.18

120.000 .29480E-05 698.12

125.000 .74804E-05 693.06

130.000 .17534E-04 687.99

135.000 .38315E-04 682.93

140.000 .78671E-04 677.87

145.000 .15279E-03 672.80

150.000 .28235E-03 667.72

155.000 .49897E-03 662.62

160.000 .84700E-03 657.51

165.000 .13864E-02 652.38

170.000 .21959E-02 647.23

175.000 .33756E-02 642.06

180.000 ,50497E-02 636.85

185.000 .73689E-02 631.61

190.000 .10512E-01 626.33

195.000 .14687E-01 621.02

200,000 .20133E-01 615.66

205.000 .27119E-01 610.25

210.000 .35944E-01 604.78

215.000 .46937E-01 599.26

220.000 .60455E-01 593.67

225.000 .76884E-01 588.01

231.068 .10133E+00 581.04

235.000 .12014E+00 576.46

240.000 .14785E+00 570.55

245.000 .18025E+00 564.55

250.000 .21783E+00 558.44

255.000 .26111E+00 552.22

260.000 .31060E+00 545.88

265.000 .36685E+00 539.41

270.000 .43042E+00 532.78

275.000 .50186E+00 526.00

280.000 .58177E+00 519.05

285.000 .67072E+00 511.91

290.000 .76931 E+00 504.56

295.000 .87816E+00 496.97

300.000 .99790E+00 489.13

305.000 .11292E+01 480.99

310.000 .12726E+01 472.53

315.000 .14289E+01 463.70

320.000 .15988E+01 454.43

325.000 .17829E+01 444.67

330.000 .19822E+01 434.30

335.000 .21973E+01 423.21

340.000 .24293E+01 411.22

345.000 .26792E+01 398.07

350.000 .29482E+01 383.34

355.000 .32377E+01 366.31

360.000 .35498E+01 345.52

365.000 .38877E+01 316.85

369.850 .42475E+01 220.49

^9

.10484E-07 .00000 1.00000

.57076E-07 .00000 1 .00000

.30216E-06 .00000 1 .00000

.13333E-05 .00000 1.00000

.50358E-05 .00000 1.00000

.16639E-04 .00000 1.00000

.48970E-04 .00000 1.00000

.13030E-03 .00000 .99999

.31740E-03 .00000 .99998

.71538E-03 .00000 .99996

. 15054 E-02 .00000 .99992

.29807E-02 ,00000 .99985

.55902E-02 .00001 .99974

.99876E-02 .00001 .99957

. 17085E-01 .00003 .99932

.28105E-01 .00004 .99896

.44633E-01 .00007 .99847

.68659E-01 .0001

1

.99781

. 10262 E+00 .00016 .99695

.14941 E+00 ,00023 .99585

.21243E+00 .00033 .99447

.29556E+00 .00047 .99279

.40319E+00 .00054 .99076

.54018E+00 .00087 .98835

.71 191E+00 .001 15 .98552

.92419E+00 .00150 .98223

. 11833E+01 .00193 .97847

.14961E+01 .00245 ,97418

. 18696E+01 .00308 .96935

.24158E+01 .00400 .96270

.28305E+01 .00470 .95791

.34347E+01 .00573 .95125

.41338E+01 .00691 .94393

.49376E+01 .00828 .93593

.58570E+01 .00983 .92720

.69037E+01 .01 161 .91774

.80903E+01 .01361 .90752

.94307E+01 .01587 .89651

. 10940E+02 .01840 .88470

.12636E+02 .02123 .87206

. 14537E+02 .02438 .85858

. 16665E+02 .02788 .84424

.19045E+02 .03177 .82900

.21704E+02 .03607 .81284

.24676E+02 .04082 .79573

.27999E+02 .04608 .77762

.31720E+02 .05188 .75845

.35898E+02 .05831 .73814

.40603E+02 .06543 .71658

.45931E+02 .07335 ,69358

.52006E+02 .08220 ,66892

.59004E+02 .0921

5

,64224

.67188E+02 .10347 ,61301

.76974E+02 .1 1654 .58039

.89094E+02 .13205 .54292

. 10505E+03 .15136 .49781

.12901E+03 .17829 • .43786

.22049E+03 .27625 .27625

1 sochore 1 sotherm

dP(j/dT dPg^/dT Der i vati ve Der i vat i vi MPa/K kn/f m3.K

1

MPa ,m3 /kn .6882E--10 -1.031

1

3,1063 ,3013E+01

,3532E--09 -1 .0274 2,9784 .2899E+01

, 1757E--08 -1.0237 2,8469 ,2781 E+01

,7304E.-08 -1.0205 2,7243 .2670E+01

,2605E--07 -1 .0178 2,6096 .2564 E+01 .8145E--07 -1.0156 2.5020 .2464E+01

.2273E--06 -1 .0140 2.4007 .2368E+01

.5744E--06 -1.0128 2.3051 .2276E+01

, 1 33 1 E--05 -1 .0122 2,2145 .2188E+01

,2859E'-05 -1 .0121 2,1287 .2103E+01

.5742E--05 -1 .0126 2,0471 .2022 E+01 ,1087E--04 -1.0136 1 ,9694 . 1943E+01

. 1950E--04 -1.0152 1,8952 ,1867E+01

.3337E--04 -1 .0174 1 ,8243 . 1793E+01

.5475E--04 -1 .0203 1,7565 .1722E+01

.8646E'-04 -1 .0237 1,6915 . 1652E+01

. 1319E--03 -1.0278 1 ,6290 , 1585E+01

. 1952E--03 -1.0326 1.5690 ,1519E+01

,2808E--03 -1 .0381 1.51 12 ,1455E+01

,3938E--03 -1 .0443 1.4555 ,1393 E+01 ,5398E--03 -1.0513 1.4018 ,1333 E+01

,7244E--03 -1 .0591 1.3499 , 1274E+01

.9536E--03 -1 .0677 1 .2997 .1216E+01

,1234E--02 -1.0771 1,2512 ,1 160E+01

.1571E--02 -1 .0875 1 ,2042 .1106E+01

. 1970E--02 -1.0988 1,1585 .1053E+01

.2439E'-02 -1.1111 1 , 1 143 ,1001 E+01 .2982E--02 -1.1246 1.0713 .9500E+00

.3604E--02 -1 . 1391 1 .0295 ,9006E+00

.4473E--02 -1.1584 .9803 ,8424E+00

.5106E--02 -1.1720 .9493 ,8056E+00

.5995E--02 -1 . 1905 .9107 .7599E+00

.698 IE--02 -1 .2106 ,873 1 .7155E+00

.8068E--02 -1.2323 ,8364 .6722E+00

.9259E--02 -1 .2559 ,8006 .6301 E+00

.1056E--01 -1.2815 ,7656 .5892E+O0

.1196E--01 -1 .3093 ,7314 .5495E+00

.1348E--01 -1.3396 ,6979 .51 09 E+00

.1512E--01 -1.3727 .6651 .473 5E+00

,1687E--01 -1 .4090 .6330 .4373E+00

. 1873E--01 -1 .4489 .6015 .4022E+00

.2072E--01 -1 .4930 .5707 .3683E+00

.2284E--01 -1.5420 .5403 .3356E+00

.2508E--01 -1 .5966 .5106 .3041 E+00

.2745E--01 -1,6581 .4813 .2737E+00

.2995E--01 -1 ,7278 .4525 ,2445E+00

.3259E--01 -1 ,8078 .4241 ,2166E+00

.3538E--01 -1 ,9004 ,3960 .1898E+00

.3831E--01 -2,0095 .3683 , 1642E+00

.4141E--01 -2, 1403 .3409 .1399E+00

.4468E--01 -2,3008 .3136 .1 169E+00

.4815E--01 -2.5037 .2865 .9518E-01

.5184E-01 -2,7709 ,2592 .7484E-01

.5579E--01 -3.1437 .2317 .5595E-01

.6009E--01 -3,71 16 ,2035 .3863E-01

.6486E--01 -4,7195 .1738 .2308E-01

.7047E--01 -7,2322 ,1406 .9697E-02

.81 13E--01 ,0811 0.

186
Table 20. (Continued).

Heat of Temp. Vap.

K J/mo

I

85.470 24840.8

90.000 24627.8

95.000 24397.6

100.000 24172.3

105.000 23951.6

110.000 23735.1

115.000 23522.5

120.000 23313.3

125.000 23107.3

130.000 22904.0

135.000 22703.1

140.000 22504.2

145.000 22307.0

150.000 22111.0

155.000 21915.9

160.000 21721.4

165.000 21526.9

170.000 21332.2

175.000 21136.8

180.000 20940.4

185.000 20742.4

190.000 20542.6

195.000 20340.4

200.000 20135.5

205.000 19927.3

210.000 19715.5

215.000 19499.6

220.000 19279.0

225.000 19053.3

231.068 18771.8

235.000 18584.5

240.000 18340.2

245.000 18088.6

250.000 17828.9

255.000 17560.7

260.000 17283.0

265.000 16995.2

270.000 16696.4

275.000 16385.7

280.000 16062.1

285.000 15724.5

290.000 15371.6

295.000 15001.9

300.000 14613.9

305.000 14205.6

310.000 13774.8

315.000 13318.6

320.000 12833.7

325.000 12315.9

330.000 11759.6

335.000 11157.5

340.000 10499.3

345.000 9769.9

I 350.000 8945.7

j 355.000 7985.7

I 360.000 6806.1

365.000 5175.8

, 369.850 0.0

I nterna

I

Energy Enthalpy

J/mo I J/mo

I

.0 .0 391.5 391.6

822.9 822.9

1253.4 1253.4

1683.4 1683.4

2113.2 2113.2

2543.0 2543.0

2973.0 2973.0

3403.4 3403.4

3834.6 3834.6

4266.9 4266.9

4700.4 4700.4

5135.5 5135.5

5572.5 5572.5

6011.8 6011.9

6453.6 6453.6

6898.0 6898.1

7345.5 7345.6

7795.2 7796.4

8250.4 8250.7

8708.3 8708.8

9169.9 9170.7

9535.7 9635.7

10105.6 10107.0

10579.9 10581.9

11058.6 11051.3

11542.1 11545.5

12030.1 12034.6

12523.1 12528.9

13128.2 13135.9

13524.2 13533.4

14032.5 14043.9

14545.1 14550.2

15055.4 15082.6

15590.1 15611.0

16120.7 16145.8

16657.3 15687.3

17200.0 17235.6

17749.1 17791.1

18304.7 18354.2

18867.3 18925.1

19437.3 19504.5

20014.9 20092.8

20600.7 20690.6

21195.3 21298.8

21799.6 21918.3

22414.5 22550.4

23041.1 23196.2

23680.9 23857.7

24336.0 24537.2

25008.8 25237.8

25703.0 25963.5

25423.6 26720.4

27178.4 27517.6

27981.5 28371.2

28861.6 29314.7

29903.9 30444.9

32232.7 33082.2

Entropy Cy

J/(mol .K) J/(mol -I 82.561 61.54

87.074 51.43

91.767 61.22

96.197 61.05

100.397 60.89

104.394 60.77

108.210 50.67

111.854 60.59

115.374 60.54

118.753 60.50

122.013 60.50

125.165 60.51

128.220 60.54

131.185 60.60

134.068 60.68

136.877 50.77

139.616 60.89

142.292 61.03

144.908 61.20

147.471 51.38

149.983 61.59

152.448 61.82

154.870 62.07

157.251 62.34

159.594 62.54

161.902 62.96

164.177 63.31

166.421 53.69

168.535 64.09

171.288 64.61

172.987 54.97

175.125 55.45

177.242 55.97

179.339 65.51

181.416 67.09

183.476 67.69

185.519 68.34

187.547 59.02

189.563 69.73

191.566 70.48

193.550 71.28

195.544 72.11

197.523 72.99

199.496 73.91

201.468 74.88

203.440 75.90

205.417 76.97

207.401 78.10

209.397 79.29

211.412 80.54

213.454 81.86

215.532 83.26

217.663 84.74

219.870 86.32

222.195 88.01

224.725 89.85

227.718 91.80

234.726

C o Cp

J/(mol .K) J/(mol .K) 84.09 84.09

84.30 84.30

84.54 84.54

84.80 84.80

85.05 85.05

85.34 85.34

85.53 85.53

85.94 85.94

86.26 86.25

86.50 86.50

86.95 86.95

87.33 87.33

87.72 87.72

88.14 88.14

88.57 88.57

89.03 89.03

89.52 89.52

90.03 90.03

90.56 90.57

91.13 91 .14

91 .72 91 .74 92.35 92.37

93.01 93.03

93.70 93.73

94.43 94.47

95.20 95.25

96.00 95.07

96.85 96.94

97.74 97.86

98.88 99.04

99.66 99.85

100.70 100.93

101 .79 102.08

102.95 103.30

104. 16 104.59

105.44 105.97

106.80 107.44

108.23 109.00

109.75 1 10.68

1 1 1.36 1 12.48

1 13.08 114.42

1 14.91 116.52

1 16.87 1 18.81

1 18.99 121.32

121.27 124.08

123.76 127. 15 125.50 130.52

129.53 134.58

132.94 139.17

136.83 144.61 141.38 151.27

145.85 159.69

153.70 170.94

152.81 187.08

176.11 213.03

198.91 263.85

254.84 418.67

Fugac i ty/ Ve I . of Pressure Sound Rat io m/s

1 . uuuuu 9n97

1 .uuuuu 1 yy^

1

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244
NBS-n4A (REV. 2-8C) U.S. DEPT. OF COMM. 1. PUBLICATION OR 2. Performing Organ. Report No. 3. Publication Date BIBLIOGRAPHIC DATA

REPORT NO. SHEET (See insiructions) NBS Monogr. 170 April 1982

4. TITLE AND SUBTITLE

THERMOPHYSICAL PROPERTIES OF PROPANE- FROM 85 TO 700 K AT PRESSURES TO 70 MPa

5. AUTHOR(S)

Robert D. Goodwin and William M. Haynes

6. PERFORMING ORGANIZATION (If joint or other than NBS. see instructions]

NATIONAL BUREAU OF STANDARDS

DEPARTMENT OF COMMERCE

WASHINGTON, D.C. 20234

7. Contract/Grant No.

8. Type of Report & Period Covered

Final

9. SPONSORING ORGANIZATION NAME AND COMPLETE ADDRESS (Street. City. State, ZIP)

Same as No. 6

10. SUPPLEMENTARY NOTES

Library of Congress Catalog Card Number: 82-600514

I I Document describes a computer program; SF-185, FIPS Software Summary, is attached.

11. ABSTRACT (A 200-word or less factual summary of most significant information. If document includes a significant

bi bl iography or literature survey, mention it here) Thermophysical properties of propane are tabulated at integral temperatures over the

entire range of fluid states from 85 to 700 K along isobars to 70 MPa by using a modified form of the nonanalytic equation of state. These tables, along with a table

for the saturated liquid, include values for density, compressibility factor,

internal energy, enthalpy, entropy, heat capacities, fugacity, sound velocity,

dielectric constant, and isochore and isotherm derivatives. In addition to the

equation of state, equations are presented for vapor pressures, orthobaric vapor and

liquid densities, ideal gas properties, virial coefficients, dielectric constants,

heats of vaporization, melting pressures, and orthobaric liquid specific heats,

enthalpies, and entropies. Coefficients were determined by a least squares fit of

selected experimental data, including several new sets of data not included in

previous propane correlations. Comparisons between experimental and calculated

values are given, including those for sound velocities, heat capacities, P-P-T data,

etc

.

12. KEY WORDS (Six to twelve entries; alphabetical order; capitalize only proper names; and separate key words by semicolons)

Densities; dielectric constants; enthalpies; entropies; equation of state; fugacities; internal energies; isobars; isochores; isotherms; Joule-Thomson inversion;

latent heats of vaporization; melting line; orthobaric densities; propane; specific

heat s ;

vapor pre ssure s;—velocitieo of sound.

ISrAVAlLABTlTlTY

[XI Unlimited

I I For Official Distribution. Do Not Release to NTIS

I^I Order From Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402.

}(Xj Order From National Technical Information Service (NTIS), Springfield, VA. 22161

14. NO. OF

PRINTED PAGES

249

15. Price

$19.50

USCOMM-DC 60d3-PeO



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NOTE: The principal publication outlet for the foregoing data is the Journal of Physical and Chemical Reference Data (JPCRD)

published quarterly for NBS by the American Chemical Society

(ACS) and the American Institute of Physics (AIP). Subscriptions,

reprints, and supplements available from ACS, 1 155 Sixteenth St., NW, Washington, DC 20056.

Building Science Series—Disseminates technical information developed at the Bureau on building materials, components,

systems, and whole structures. The series presents research results,

lest methods, and performance criteria related to the structural and

environmental functions and the durability and safety characteristics of building elements and systems.

Technical Notes—Studies or reports which are complete in themselves but restrictive in their treatment of a subject. Analogous to monographs but not so comprehensive in scope or definitive in treatment of the subject area. Often serve as a vehicle for final reports of work performed at NBS under the sponsorship of other government agencies.

Voluntary Product Standards—Developed under procedures

published by the Department of Commerce in Part 10, Title 15, of

the Code of Federal Regulations. The standards establish nationally recognized requirements for products, and provide all concerned interests with a basis for common understanding of the

characteristics of the products. N BS administers this program as a supplement to the activities of the private sector standardizing

organizations. Consumer Information Series—Practical information, based on NBS research and experience, covering areas of interest to the con- sumer. Easily understandable language and illustrations provide

useful background knowledge for shopping in today's tech- nological marketplace. Order the above NBS publications from: Superintendent oj Documents, Government Printing Office. Washington, DC 20402. Order the following NBS publications—FIPS and NBSlR's—from

the National Technical Information Services. Springfield. VA 22161

.

Federal Information Processing Standards Publications (FIPS

PUB)—Publications in this series collectively constitute the Federal Information Processing Standards Register. The Register

serves as the official source of information in the Federal Govern- ment regarding standards issued by NBS pursuant to the Federal Property and Administrative Services Act of 1949 as amended.

Public Law 89-306 (79 Stat. 1127), and as implemented by Executive Order 1 1717 (38 FR 12315, dated May II, 1973) and Part 6

of Title 15 CFR (Code of Federal Regulations).

NBS Interagency Reports (NBSIR ) —A special series of interim or

final reports on work performed by NBS for outside sponsors

(both government and non-government). In general, initial dis- tribution is handled by the sponsor: public distribution is by the National Technical Information Services, Springfield, VA 22161,

in paper copy or microfiche form
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