# FINAL REPORT

KILN 6 HF, CO EMISSIONS EVALUATION

prepared for


## Florida Tile Industries, Inc. 1247A1ton Road Lawrenceburg, KY 40342

by



## FBT Environmental Services LLC

6860 Stonepoint Court Paducab, KY 42003 (270) 898-8782

Prepared by: Cliris Gottscballc Project Manager

Test Perforined: Report Issued: January 15-16, 2008 February 20, 2008

# KILN 6 HF, CO EMISSIONS EVALUATION FLORIDA TILE INDUSTRIES, INC. LAWRENCEBURG, KENTUCKY
TABLE OF CONTENTS

EXECUTIVESUMMARY ...........................................................................................................3


### 1.0 INTRODUCTION ..............................................................................................................4


### 2.0 TEST RESULTS AND CONCLUSIONS ........................................................................4


### 3.0 PROCESS DESCRIPTION ..............................................................................................5


### 4.0 SAMPLING PROCEDURES ...........................................................................................5



### APPENDICES
1 Example Calculations and Calculated Test Results
2 Field and Sampling Site Data
3 Calibration Data
4 Analytical Data
5 Process Data

2 Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromnental Services LLC Lawrenceburg, KY Paducah, KY 7anuary 15-16, 2008

# KILN 6 HF, CO EMISSIONS EVALUATION FLORIDA TILE INDUSTRIES, INC. LAWRENCEBURG, KENTUCKY

EXECUTIVE SUMMARY FBT Enviromnental Services, LLC (FBT) was retained by Florida Tile hidushies, Inc. to conduct an einissions evaluation on Kiln 6 at its facility in Lawrenceburg, Kentucicy. Kiln 6 is used to cure green cerainic tile on one of the production lines. The purpose of the evaluation was to measure hydrogen fluoride (HF) and carbon monoxide (CO) einissions from the lcihi. Kihi 6 is divided into two sections, a natural gas fired heating zone and an air-cooling zone. The two sections have separate exhaust vents to the atmosphere. Botli HF and CO emissions were measured in the heating section vent and only HF einissions were measured in the cooling section vent. The evaluation was perfonned January 15-16, 2008. Results are presented in Table 1.

Table 1 Kiln 6 Emissions Summary Heating Cooling Total Two Section Section Sections HF: ppm 21.9 1.9 0.8281 pounds/hour 0.6879 0.1402 CO: ppm 57.1 not pounds/hour 2.515 measured ppm = parts per million volume dry basis

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromnental Services LLC Lawrenceburg, KY Paducah, KY January 15-16, 2008

# KILN 6 HF, CO EMISSIONS EVALUATION FLORIDA TILE INDUSTRIES, INC. LAWRENCEBURG,KENTUCKY

1.0 INTRODUCTION FBT Enviroiunental Services, LLC (FBT) was retained by Florida Tile Industries, Inc., to conduct an emissions evaluation on Kiln 6 at its plant in Lawrenceburg, Kentucicy. Kiln 6 is used to cure green ceramic tile on one of the prodtiction lines. The purpose of the evaluation was to measure hydrogen fluoride (HF) and carbon monoxide (CO) einissions from the lciln. Kihi 6 is divided into two sections, a nattual gas fired heating zone and an air-cooling zone. The two sections have separate exhaust vents to the atmosphere. Both HF and CO emissions were measured in the heating section vent and only HF emissions were measured in the cooling section vent. The evaluation was performed January 15-16, 2008. FBT's test team consisted of Chris Gottschallc, Michael Meadows, and Doug Jones. DataChem Laboratories in Cincimlati, Ohio, analyzed the samples for HF. Sampling was coord'ulated with plant operations by Florida Tile representative Milce Joluiston. Gerald Slucher and Milce Toncray observed the test for the Kentucicy Division for Air Quality (KY DAQ).

2.0 TEST RESULTS Heating section einissions of HF and CO and cooling section einissions of HF are presented in Table 2.1. Stacic gas conditions for each run are presented in Table 2.2. Example calculations and calculated test results are presented in Appendix 1. Field data sheets and sampling site data are presented in Appendix 2. Calibration data is contained in Appendix 3. Analytical results are presented in Appendix 4. Process data is contained in Appendix 5.

4 Florida Tile Industries, Inc., Kiln 6 Test FBT Enviroiunental Services LLC Lawrenceburg, KY Paducah, KY Januaiy 15-16, 2008

### Table 2.1 Kiln 6 Emissions and Stack Gas Conditions

Heating Section Emissions: Cooling Section Emissions: Date: 1-15-08 1-15-08 1-15-08 Time: 1230-1330 1346-1446 1508-1608 Averages Run: K-1 K-2 K-3 HF: ppm 21.3 30.5 13.8 21.9 pounds/liour 0.6656 0.9591 0.4389 0.6879 CO: ppm 57.1 57.2 57.1 

# 1 57.1 

# 1 pounds/liour 2.493 2.518 2.535 2.515 1-16-08 1-16-08 1-16-08 0825-0925 0942-1042 1055-1155 Averages C-1 C-2 C-3
3.5 1.5 0.6 1.9 0.2603 0.1162 0.0442 0.1402

CO Not Measured Total Two Sections

0.8281

Stack Gas Conditions: Velocity, Vs: f s 48.28 47.84 49.13 48.41 Stacic Gas acfm 15,676 15,533 15,953 15,721 FlowRate: lscfm 10,015 10,102 10,187 10,101 Tem ,Ts: ° F 308. 308 309 308 HZO: % 6.3 4.6 6.1 5.7 O': % 19 1 19 19 18.5 CO Z : % 2.0 

# 1 2.0 

# 1 2.0 

# 1 2.0 69.48 69.59 32,866 31,976 32,023 24,845 24,177 24,258 

# P 71.42

220 221 218 1.0 0.8 1.1 20.9 20.9 20.9 0.0 0.0 0.0 Key: ppm = parts per million volume dry basis acfm = actual cubic feet per minute fps = feet per second dscfm = dry standard cubic feet per minute 

### *Note: HF for run C-3 (shaded) was not detected at or above the estimated quantification limit (0.05 mg/sample) for the analytical method. Half the estimated quantification limit is used for emissions calculations.



### 3.0 PROCESS DESCRIPTION Florida Tile manufactures ceramic tile at its facility in Lawrenceburg, Kentlicicy. Line 6 consists of powder and prill storage silos, belt conveyors, a vibrating screen, pneumatic gates, a press, a decorating line, roller Kiln 6, several dust collectors and associated process control equipment. Kiln 6 is used to cure green tile. It has a nattiral gas fired tile heating section followed by a cooling section utilizing air as the cooling medium. Each of the two sections has an exliaust vent to the atmosphere. Kiln 6 has no emissions controls.

4.0 SAMPLING PROCEDURES Sampling and analytical procedures used were USEPA Reference Methods for stationary sources described in the latest edition of CFR 40 Part 60 Appendix A. Methods used are listed below:

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC Lawrenceburg, ICY Paducah, KY January 15-16, 2008

### 4.1 Measurement Sites (Method 1)

Location of ineasurement sites and number of traverse points for velocity and volumetric flow measurements were deterinuied as specified in USEPA Reference Metlzod I, Sanzple and Velocity Traverses for Stationary Sozn°ces.
4.2 Velocities and Volumetric Flow Rates (Method 2) Stacic gas velocities and volumetric flow rates were detennined using IISEPA Reference Metlzod 2, Deterinination of Stack Gas Velocity and Volzrnzetric Flow Rate. Velocities were measured with a S-type pitot tube and temperatures were measured with calibrated type K thermocouples.
4.3 Dry Molecular Weight (Method 3) Diy molecular weight of stacic gases was detennined using USEPA Reference Metliod 3, Gas Analysis for Carbon Dioxide, Oxygen, Excess Air, and Diy Molecular Weiglht. Grab samples of stacic gases were collected during each run and analyzed for oxygen and carbon dioxide with a Fyrite Combustion Gas Analyzer.
4.4 Moisture (Method 4) Moishire content of stacic gases was deternnined using USEPA Metlzod 4, Deterinination of Moistzire Content ii2 

### Stacic Gases.
4.5 Hydrogen Fluoride Emissions (Method 26) Hydrogen fluoride concentrations of stacic gases were determuied using USEPA Reference Method 26, Deternzinatio» ofHydrogen Clzloride Enzissions fi°oin Stationaiy Soan^ces. This method is applicable to HF in addition to HCI. Samples of stacic gas were withdrawn with a vacuum puinp tlirough a glass probe, a heated TFE coated filter, a set of impingers in an ice bath, a silica gel coluinn, and a critical orifice. The first two impingers contained 0.1N H2SO4, the third was empty, and the fourth contained O.1N NaOH. Contents of the first three impingers were recovered and sent to the laboratoiy for analysis by ion chromatography.

6 Florida Tile Industries, Inc., Kiln 6 Test FBT Enviroiunental Services LLC Lawrenceburg, KY Paducah, KY January 15-16, 2008

# APPENDIX 1
EXAMPLE CALCULATIONS

AND
CALCULATED TEST RESULTS

Florida Tile Industries, Inc., Kihi 6 Test FBT Enviromnental Services LLC Lawrenceburg, KY Paducah, KY Januaiy 15-16, 2008

### HF, CO Emissions SAMPLE CALCULATION
CLIENT/PROJECT: SAMPLE LOCATION: DATE: TIME: RUN #: Florida Tile Industries, Inc. ICiln 6 - Heating Section 1-15-08 1230-1330 IC-I
STACIC GAS CONDITIONS
SAMPLE VOLUME: Vinstd (dscf) = Qstd (Lhnin)/28.317(L/ft 3 ) x O (min) x (Pb +Psainp/13.6) / (Pb + Pcal/13.6) = 1.9066
MOISTURE: % H 2 O = 100 x 0.04707 x Vol. Condensate (ml)/ (Vrnstd +(Vol. Condensate x 0.04707) = 6.30
MOLECULAR WEIGHT: Md = .1604 x %CH q + 0.44 x %CO, + .2805 x %C,H q + .3007 x %C,H 6 

### + .28 x%N,+ 0.32 x%0, + 0.28 x%CO = 29.06 Ms = Md x(1 - Bws) +(18.0 x Bws) = 28.36
STACK GAS VELOCITY: Vs(fps) = 85.49 x Cp x Avg (AP ° 

### ' 5 ) x[Ts(°R)/(Ps("Hg) x Ms)] ° ' 5 

### = 48.28
STACK GAS FLOW RATE: Qa (acfin) = Vs x 60 x As(ft') = 15,676 Qstd (dscfin) = Qa x 17.647 x(1%H 2 O/100) x Ps/Ts(°R) = 10,015
EMISSIONS CAL CULA TIONS:
CONCENTRATION: Gaseous Analytes (HF): Cs(Ib HF/dscf) = mg F/Sample x Mw HF/Mw F/ Vmstd (dscf) / 453,592 mg/lb = 1.108E-06 Cs(ppm HF) =1b HF/dscf x 385500000 ft3/Ib / Mw HF = 21.3
EMISSION RATE: Er(lb HF /hr) = Cs(Ib/dscf) x Qstd x 60 = 0.6656 Er(lb CO/hr) = Cs(ppm CO)/10 6 x(Mw (CO) /385.55) x Qstd x 60 = 2.493

Florida Tile Industries,'Inc., Kiln 6 Test FBT Enviromnental Services LLC Lawrenceburg, ICY Paducah, KY January 15-16, 2008HF & CO Emissions CLIENT/PROJECT #: Florida Tile Industries, Inc. SAMPLE LOCATION: Kiln 6- Heating Section Kiln 6- Cooling Section DATE: 1-15-08 1-16-08 TIME (hrs): 1230-1330 1346-1446 1508-1608 0825-0925 0942-1042 1055-1155 RUN #: K-1 K-2 K-3 C-1 C-2 C-3

Static Pressure, "H2O: -0.53 -0.57 -0.75 -0.56 -0.73 -0.78 Barometric Press., "Hg: 29.70 29.70 29.70 29.48 29.48 29.48 Sample Time, O, min: 60.0 60.0 60.0 60.0 60.0 60.0 Orifice Qstd, L/min: 0.931 0.931 0.931 0.931 0.931 0.931 Avg Orifice Temp, To, °F: 70.9 72.8 72.9 76.4 78.0 82.1 Orifice in Pcal, "H2O: -3.9 -3.9 -3.9 -3.9 -3.9 -3.9 Orifice in Psamp, "H 2 O: -17.3 -17.3 -17.3 -17.3 -17.3 -17.3 Avg. Sq. Root DP, "H2O ° ' $ : 0.7038 0.6995 0.7156 1.0582 1.1089 1.0783 Avg Stack Temp, °F: 307.7 308.1 308.9 213.3 219.8 221.1 Cp PITOT : 0.84 0.84 0.84 0.84 0.84 0.84 Circ. Stack? 1=Y,0=N: 1 1 1 1 1 1 DIA (in) if 1, AREA (in') if 0: 31.50 31.50 31.50 37.50 37.50 37.50

0 2

, %: 18.5 18.5 18.5 20.9 20.9 20.9 CO 2

, %: 2.0 2.0 2.0 0.0 0.0 0.0 H,0 (°/n): 6.30 4.56 6.14 1.42 1.03 0.81 Analyte # 1: HF (Metltod 26) Molecular Weiglit: 20 20 20 20 20 20 HF as F, mg/sample: 0.91 1.3 0.59 0.15 0.064 0.025 Analyte # 2: CO (Method 10) Molecular Weight: 28.00 28.00 28.00 CO, ppm: 57.130 57.210 57.100 Not Measured 

### ********************CALCULATED RESULTS******************** Stack Gas Conditions:

Velocity, Vs (fps): 48.28 47.84 49.13 67.86 71.42 69.48 Volume Flow Rate, Qs•(acfm): 15,676 15,533 15,953 31,228 32,865 31,976

(dscfni): 10,015 10,102 10,187 23,754 24,847 24,179 Temperature, Ts ( ° F) : 308 308 309 213 220 221

H Z O 

### (%): 6.30 4.56 6.14 1.42 1.03 0.81 0, (%): 18.50 18.50 18.50 20.90 20.90 20.90 CO, (%): 2.00 2.00 2.00 0.00 0.00 0.00 Static Pressure, ("Hg abs): 29.66 29.66 29.64 29.44 29.43 29.42 Dry Mole Wt, Md: 29.06 29.06 29.06 28.84 28.84 28.84 Stacic Mole Wt, Ms: 28.36 28.56 28.38 28.68 28.72 28.75 Sampling Parameters: Sample Volume; Vm std (dscf): 1.907 1.907 1.907 1.906 1.906 1.906

Stack Area (ft'): 5.4119 5.4119 5.4119 7.6699 7.6699 7.6699 HP Emissions: Concentration (Cs) Ib/dscf: 1.108E-06 1.582E-06 7.181E-07 1.826E-07 7.792E-08 3.044E-08 Concentration (Cs) ppm dry: 21.3 30.5 13.8 3.5 1.5 0.6 Emission Rate (Er) Ib/lir: 0.6656 0.9591 0.4389 0.2603 0.1162 0.0442
CO Emissions: Concentration (Cs) ppm dry: 57.13 57.21 57.10 CO Not Measured Emission Rate (Er) lb/hr: 2.493 2.518 2.535 - - - *Note: HF for run C-3 (shaded) was not detected at or above the estimated quantification limit (0.05 mg/sample) for the analytical method. Half the estimated quantification limit is used for emissions calculations.



### Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC Lawrenceburg, KY Paducah, KY Januaiy 15-16, 2008

### Exhaust Gas Moisture Concentration

CLIENT/PROJECT #: Florida Tile Industries, Inc. SAMPLE LOCATION: Kiln 6- Heating Section Kiln 6- Cooling Section DATE: 1-15-08 1-15-08 1-15-08 1-16-08 1-16-08 1-16-08 TIME (hrs): RUN #: K-1 K-2 K-3 C-1 C-1 C-1

BAROMETRIC, "Hg: 29.70 29.70 29.70 29.48 29.48 29.48 SAMPLE TIME, min: 30.0 30.0 30.0 30.0 30.0 30.0 ACTUAL METER VOLUME, ft 3 : 22.999 23.073 23.023 23.904 23.853 24.171 AVG ORIFICE AII, "H2O: 1.70 1.70 1.70 1.70 1.70 1.70 AVG METER TEMP, °F: 86.2 88.7 89.8 80.3 81.7 83.3 METER GAMMA: 0.979 0.979 0.979 0.979 0.979 0.979 LEAK RATE (0 IF<0.02): 0 0 0 0 0 0 CIRC STACK? 1=Y,0=N: 1 1 1 1 1 I DIA (in) if 1, AREA (in') if 0:

0" %: CO Z

, %: VOL CONDENSATE, ml: 31 22 30 7 5 4


### *****************CALCULATED RESULTS**************** 4
Stacic Gas Conditions: 

### H 2 0 ( 0 /0): 6.30 Sampling Parameters: SAMPLE VOLUME, Vm corr(i1): 22.999 SAMPLE VOLUME, Vm std (dsef): 21.694 4.56 6.14 1.44 1.03 0.82

23.073 23.023 23.904 23.853 24.171 21.665 21.575 22.626 22.519 22.753



### Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC Lawrenceburg, KY Paducah, ICY January 15-16, 2008

# APPENDIX 2
FIELD AND SAMPLING SITE DATA

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromnental Services LLC Lawrenceburg, KY Paducah, KY Januaiy 15-16, 2008

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### Florida Tile Industries, Inc., Kiln 6 Test FBT Envirotuiiental Selvices LLC Lawreliceburg, KY Paducah, KY Jaiivary 15-16, 2008

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### Test FBT Environmental Selvices LLC 

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- Liary 15-16, 2008

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Florida Tile Industries, Inc., Kiln 6 

### Test FBT Environirriental Sci

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### Lawrenceburg, KY Paducali, ICY Jaiivaiy 15-16, 2008

## GAS '1J'ELCd*vfT1'ANL 1!'C7LUMETR'!C FLOV9I RATE Plant: F1a/-r,4-t 

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~ 

### Side 1: ~~=~ 

### Side 2: Wet Bu1b, OF:

~ ` ~ 

### Dry Bulb, OF: Fyrite 07:

~ ~-~ ~ ~ 

### '

, ~ 

### •
~~ 

### COz: ~,,,~~ , /:: ~ 't-G '.'

~ ' t?iN 

### pun g: c - r T 

### ime: oqt 

### Run T: C-

- 5Time: iP0 5 

### Run #: 0- 3 Time; r<<•? 

### Traverse Poir ~t ~ ~ 

### P

in, Na0 

### Sfack Temp.

~ 

### F 

### r:1P

in, Hz0 

### Stack Temp.

°F r~ 

### P

in. H70 

### Stack Temp.

uF

Z~ 

### av 

# z zI 5 z z ~/~z ~ z~ s 

# 5

_ _ (,2 

# ~ ~! -7 l, 

## 3_ -z 

## (~



# zn

6

~ 

### 1 Z 

### u G ~ 

### !,3 Zla !

~ 

### z 2rr

_ 

## lrl 20 

### 5 ~~3 Z-/t 

### a•z-. ~~~ r

5 J .Z z~ ~~ 

### /•2- ~~o

~ 

# -

~ 

# 3 l

~ zl~ ~ •:~-~ 

### z:z.

~ 

### , ~ 

### s z.

~ 

### z-

~ 

### i'-

~~ 

### i"



### I T t. i ll

~

' 

### Hverape: ~~n P= 

### 1,o iy= Ts- 

### z c3r) drt
~ = l,lcycr ~~P=~ tly7 15=

~



### Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC Lawrenceburg, KY Paducab, KY January 15-16, 2008MOISTOZE DATASHEET Method 4 

# k

- tL, ~ 

# 6 -
' 

# F Clie

~ ntfCitv:
~ i L

. L~ tioii: Nleter Box Operator: D~ 

## "Ltc'

~ 

## . :Tovilf-l" 9: 1 A -H@: 

## i ,— Iye r: i 

# 7f

, I Z

Run 9: D Li t c:

-



## b
— Of P b:

— H Pre Test: @ L

0,
Post Test: 

### OV, o a c) ft' @ "Hg 

# -7 H2Ogain: mis + — g iso = tot: 

# Cl. r Tinic ITimel ~ k IS.d A-Jete

Read. "H20

4 ~ IT. ill F

T.011t Exl t Hg 

# I Vnc ,n8go 1 0 

# L

- 

## 7 7

- 

### 7 2 - 

### 9 L S L 5 

### lo

1 

### 5 ' 1 2' 

### 12, 

## 0 20 

# 'S

- 7

_~ -3 Z, o 25 F

- 1 

### Y:-- 

## k2- 3Y Z, C. , [)q01O 30 

## f 41 3, 

# d

Z';
Ruii V7 i", Date: i 

### I 1 

### /-1 /0 Pb: = I f l ~ I li - ~ 1-1 9 PreTest. 0.60 0 W 

### C) 'lig postTest: ft j (t) y, "H HIO gain: 4 

### 0 nits 

# - Clock Time Sam17 Time N-feter Itead. "HA) '

'P irl F T. I GUI X

- F EJT "Hp VaC 

### Ij,)a 0 2,ct 

### ; 1

10



### - 4 :a' Li -3 15 o, 20 25 30

Avg: Run #:

- 2- Date: 1l1646 - Pb: "lig Pre Test: 006 1 @ Post Tm 0. COO ft' @ "Hg FI 2 0 g ain: T lills -1 , 

### ~ ' (sg) = tot Clo-ck Time Sam Ti=mej Nicter Read- ",H:O

AH "F T,„ in 'F T m oui 'T F-xit -Hq Vac 0 

## Y' /S 'U 

### ?0 2'e 5 0 to 

### :"O, 10 5?/ 

### 31 J

- a 15 

### ( , k' -LL -EL "~ 12

~ - 

### 1 , c i 20 

## e-? 2- 25 fi 4 09

, K4 1 

### ? 3 3 1 , cl 30

- 

### it

- , o 0 3

Avg: 

## -'u
Run *': Date: _ Pb:_"l-Ig Pre Test: ft , pi, "H" Post 1est: ft' @ "Hg H2O gain: MIS + = tot:ClockTirne samp 1rime 1%4ptvr

Re-iid. 'TLO

AH - F T m in - F TnOut 

## *F Exit Var, 0 5 10 15 20 2S 

### 30



# FBT

Florida Tile Industries, Inc., ICIn 6 

### Test FBT Enviromiiental Sci vices LLC 

### Lawrenceburg, KY Padticah, KY Januluy 15-16, 2008

### Sainple Port (gas)

Heat Section Exliaust Fan Kiln 6 Heating Section Vent Florida Tile Industries, Inc. Lawrenceburg, KY

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromnental Services LLC Lawrenceburg, KY Paducah, KY January 15-16, 2008

### Cooling Section Cooling Section

Exhaust Fan Exlhaust Fan
Kiln 6 Cooling Section Vent Florida Tile hidustries, Inc. Lawrenceburg, KY

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromiiental Services LLC Lawrenceburg, KY Paducah, ICY January 15-16, 2008Client Florida Tile, Lawrenceburg, KY Site Kiln 6 Heat Section Vent Calculator Cbris Gottsclialk Date 1-14-08 Distance from upstreani disturbance (d) 92" Distance from downstream disriarbance (u) -40' Outside of port to far side of stack (a), in. 35 Outside of port to near side of stack (a), in. 3.5 

# 1 I I'

~ 

## b

a 

## Traverse Point Locator Data

Inside Stack Diameter (a - b), in. 31.5 tlow disturbance

Point # ~

/o from wall to point " fr om wall to point (c) Port lengtb (b) " fr om probe tip to point (b + c) 1 3.2 1.01 3.50 4.51 2 10.5 3.31 3.50 6.81 3 19.4 6.11 3.50 9.61 4 32.3 10.17 3.50 13.67 5 67.7 21.33 3.50 24.83 6 80.6 25.39 3.50 28.89 7 89.5 28.19 3.50 31.69 8 96.8 30.49 3.50 33.99



### Florida Tile Industries,•Inc., Kiln 6 Test FBT Envirotunental Services LLC Lawrenceburg, KY Paducah, KY 7anuary 15-16, 2008

## Traverse Point Locator Data

Client Florida Tile, Lawrenceburg, KY Site Kiln 6 Cooling Section Vent 

# ~ I~ b
Calculator Chris Gottschalk Date 1-15-08 n Distance from upstream disturbance (d) 113 in O 

# ~ a Distance from downstream disturbance (u) 15.5 ft 

# t d

~ Outside of port to far side of stack (a), in. 37.5 Outside of port to near side of stack (a), in. 0 

# ~ - Inside Stack Diameter (a - b), in. 37.5 flow disturbance

Point # % froin wall to point froin wall to point (c) Port length (b) from probe tip to point (b + c) 1 3.2 1.20 0.00 1.20 2 10.5 3.94 0.00 3.94 3 19.4 7.28 0.00 7.28 4 32.3 12.11 0.00 12.11 5 67.7 25.39 0.00 25.39 6 80.6 30.23 0.00 30.23 7 89.5 33.56 0.00 33.56 8 96.8 36.30 0.00 36.30



### Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC Lawrenceburg, KY Paducah, KY Januaiy 15-16, 2008

# APPENDIX 3
CALIBRATION DATA

Florida Tile Industries, Inc., IC'iln 6 Test FBT Enviromilental Services LLC Lawrenceburg, KY Paducali, KY January 15-16, 2008

## APPENDIX 3 CALIBRATION DATA This appendix contains calibration documentation and describes the specific QA/QC procediures einployed by FBT in performing this test. The goal of the QA/QC activities for this project was to ensure, to the highest degree possible, the acctiracy of the data collected. The procedures contained in the Qicality Assurance Harndboolc for Air Pollution Measzn°enzent Systerns: Voluine I.Principles, EPA-60019-76-005, and Volznne III Stationa7y Sozrrces Specific Metbods, EPA600/77-027b are the basis for performance for all testing and related worlc activities.

CALIBRATION OF APPARATUS The preparation and calibration of source sainpling equipment is essential to maintaining data quality. Brief descriptions of the calibration procedures used by FBT follow:
Barometers FBT uses aneroid barometers that are calibrated against a National Weather Service-Type mercurial barometer. Temperature Sensors Bimetallic dial thermometers and Type "K" thennocouples are calibrated using the procedure described in Section 3.4.2 of the Quality Assurance Handboolc. Each temperathire sensor is calibrated over the expected range of use against an ASTM 3C or 3F thennometer.
Pitot Tubes FBT uses Type "S" pitot tubes on sources having significant particulate loadings and on larger ducts. These pitot tubes are constructed according to specifications in CFR 40 Part 60, Appendix A USEPA, Reference Method 2. Pitot tubes meeting these criteria are assigned a baseline coefficient of 0.84 and need not be calibrated. FBT uses standard pitot hibes on smaller sources having insignificant particulate loadings. These tubes are constructed according to USEPA Reference Method 2 specifications. Pitot tiibes meeting these criteria are assigned a baseline coefficient of 0.99 and need not be calibrated.
Differential Pressure Gaulzes FBT uses inclined/vertical manometers to measure differential pressures. These include velocity pressures, static pressures, and orifice pressure differentials. Manometers are selected with sufficient sensitivity to accurately measure pressures over the entire range of expected values. Manometers are leveled and zeroed prior to each run and checiced periodically during the run. Manometers are primaiy standards and require no calibration. Dry Gas Meters and Orifiees Dry gas meters are calibrated using critical orifices as described in USEPA Reference Method 5. Before initial use in the field, a metering system is calibrated over the entire range of operation.

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC Lawrenceburg, KY Paducah, KY Januaiy 15-16, 2008

### After each field use, the metering system is calibrated at a siiigle intermediate setting based on

the previous field test. Acceptable difference for pre-test and post-test dry gas meter coefficient values is ± 5%. Metering systems are also calibrated using a reference dry gas meter. Reference dry gas meters are calibrated using critical orifices. Critical orifices used for sample gas flow 

### control are calibrated using a reference wet test meter. The reference wet test meter is calibrated using ASTM D 1071. Dry gas meters may also be calibrated using critical orifices as described in USEPA Reference Method 5.

ON-SITE MEASUREMENTS On-site QA/QC activities included:
Measurement Sites Prior to sampling, all stacic/duct dimensions are measured to determine measurement site locations, location of test ports, and stacic inside dimensions. Inside dimensions are checiced through all available test ports to ensure uniformity of the stacic cross-sectional area. Verification of Absence of Cyclonic Flow Some flow disturbances such as cyclones, inertial deinisters, and venturi scrubbers tend to induce cyclonic flow. 

### In situations such as these, the presence or absence of cyclonic flow must be determined. Prior to testing, FBT conducts an evaluation to identify duct configurations that may. induce swirl. If these conditions exist the presence or absence of cyclonic flow 

### must be deterinined. A sampling site is acceptable if the average angle of rotation fiom the duct axis required to achieve a null pitot reading is less than 20 0

. 

### Velocity Measurements All velocity measurement apparatus are assembled, leveled, zeroed, and lealc checiced prior to each test run. Static pressure is determined at a single point near the center of the stacic. Lealc checics are perfonned again, at the end of each run. Stacic Gas Component Samplin2 During test runs gas samples are withdrawn from a single point near the center of each test site and analyzed with either a Fyrite combustion gas analyzer or instrumental analyzers to detennine percent concentrations of carbon dioxide and oxygen. The sample train is assembled and lealc checiced before sainpling. Instrumental analyzers are calibrated with appropriate calibration gases. Linearity, system bias, zero and calibration drift, and response time checics are also done with these gases.

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC Lawrenceburg, KY Paducah, KY January 15-16, 2008

### Moisture

Stacic gas moisture may be detennined simultaneously with particulate matter. During sampling, the gas exiting the silica gel impinger or coluinn is maintained below 68 ° F to ensure adequate condensation of the stacic gas water vapor. The total moisture is deternnined volumetrically and/or gravimetrically. Sample Trains The sample trains are asseinbled, equilibrated to required teinperahires and lealc checiced before testing. The nozzle size is determined in the field by malcing triplicate measurements along three different diameters using a dial caliper. The three measurements must vary no more than 0.004 inches between the higlh and low values. At the conclusion of each run, sample trains are lealc checiced at the vacuum specified by the respective Method, typically, the highest vacuum attained during the run. Typical acceptable lealcage rates are 0.02 cubic feet per minute or 4 percent of the average sampling rate (whichever is less), or that specified by the Method used. If appropriate, sainple volume may be adjusted to account for excess sample train lealcs.

Florida Tile Industries, Inc., I{iln 6 Test FBT Envirormlental Services LLC Lawrenceburg, KY Paducah, KY Januaiy 15-16, 2008CRITICAL ORIFICE CALIBRATION
Reference Wet Test Meter: L/A 04444 Wet Test Meter I': 1.006 Pump: Blue/White Thomas-Med

Pre-Test Calibration:

Barometric Pressure, Pbar : 29.36 incbes Hg

Date: 1-8-08 Rotometer* Oririce Q Pin Ori6ce Pout Orifice Vref Tref Pref No.: R-1 Time Orifice # (L/min) (in H Z O) (in IIg) (L) ( ° F) (in H2O) L/min O (min)

0.932 -3.9 -18.6 6.00 68 -0.16 0.7 6.350 016 0.932 -3.9 -18.6 6.00 68 -0.16 0.7 6.350

0.932 -3.9 -18.6 6.00 68 -0.16 0.7 6.350 Average 0.932 -3.9 Pre test Q= new orifice -3.9

Post-Test Calibration:

Barometric Pressure, Pbar : 29.42 inches Hg Date: 1-23-08 Rotometer* Oritice Qstd Pin Orifice Pout Orifice Vref Tref Pref No.: R-1 Time Orifice # (L/min) (in H Z O) (in Hg) (L) ( ° I) (in II20) L/min O (min)

0.930 -3.9 -19.0 6.00 65 -0.16 0.7 6.417 016 0.930 -3.9 -19.0 6.00 65 -0.16 0.7 6.417

0.930 -3.9 -19.0 6.00 65 -0.16 0.7 6.417 Average 0.930 -3.9 Post test Qstd = 0.933 % diff = 0.3% Pre-Post Avg Qstd = 0.931

Q= I' x Vref x Tstd ( ° R) x(Pbar + Pref/13.6) /(Tref ( ° R) x Pstd x O) Q=17.647 x I' x Vref x(Pbar+ Pref/I3.6) /((Tref ( ° F) + 460) x O) Where Pstd = 29.92 inclies Hg and Tstd = 68 ° F or 528 ° R Tstd/Pstd = 528/29.92 = 17.647

Calibration Perforined By: Cluis Gottsclialk



### Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC Lawrenceburg, KY Paducah, KY January 15-16, 2008

### PRE-TEST METER CALIBRATION

MB #: LL-1 BAROMETRIC PRESS: 29.72 in. hg DATE: 10-6-07 DGM PRETEST y: 0.9789 PLANT: Florida Tile REFERENCE y: 1.0096 PERFORMED BY: Gottschalk RUN 1 RUN 2 RUN 3 VACUUM ("Hg) 6.00 6.00 6.00 DGM AH ("H20) 3.00 3.00 3.00 Reference Pnn ("H20) -4.40 -4.40 -4.40 Initial Ref. ft 3 575.660 581.508 588.342 Final Ref. ft 3 581.508 588.342 594.188 Initial DGM ft 3 104.683 110.855 118.043 Final DGM ft 3 110.855 118.043 124.198 Ref T M ° F 70.0 70.5 71.0 DGM T M ° F 75.5 76.0 77.0 Time, min: 6.0 7.0 6.0

Net Reference ft 3 

# = 5.848 6.834 5.846 Net DGM ft 3 

# = 6.172 7.188 6.155

I

- ' 

# = 0.9490 0.9522 0.9521 % A = -3.1 -2.7 -2.7 OH@ 

# = 1.767 1.763 1.770



### Pretest I' 

# = 0.9789 

### New I' 

# = 0.9511 

# % A 

# = -2.8 Average OH@ 

# = 1.766 Calculations: 1' = (Vref 

### x I'ret 

### x (Pbar + 

### Pm + 13.6) x (Td + 460)) = (Vd (Pb + ( 

### AH = 13.6)) x (Tref+ 

### 460)) OH@ = 0.0317 x OH / Pbar 

### (Td + 460)) x((Tref + 

### 460) 

### x 0 / Vref) 2



### Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromnental Services LLC Lawrenceburg, KY Paducah, KY Januaiy 15-16, 2008

### POST-TEST METER CALIBRATION

MB #: LL-1 BAROMETRIC PRESS: 29.43 in. hg DATE: 1-21-08 DGM PRETEST y: 0.9789 PLANT: Florida Tile REFERENCE y: 1.0096 PERFORMED BY: Gottschalk RUN 1 RUN 2 RUN 3 

### VACUUM ("Hg) 4.0 4.0 4.0 DGM AH ("H20) 1.85 1.85 1.85 Reference Pnn ("H20) -2.70 -2.70 -2.70 Initial Ref. ft 3 663.128 668.590 674.032 Final Ref. ft 3 668.590 674.032 679.858 Initial DGM ft 3 545.268 550.670 556.071 Final DGM ft 3 550.670 556.071 561.884 Ref T M ° F 41.0 46.0 50.0 DGM T M ° F 38.0 42.0 46.0 Time, min: 7.0 7.0 7.5

Net Reference ft 3 

# = 5.462 5.442 5.826 Net DGM ft 3 

# = 5.402 5.401 5.813

I , 

# = 1.0032 0.9978 0.9926 % A = 2.5 1.9 1.4 AH@ 

# = 1.650 1.682 1.698


### Pretest 

# r 

# = 0.9789 

### New 

# r 

# = 0.9979 % 0 = 1.9 Average OH@ 

# = 1.676 Calculations: I' = (Vref 

### x i'ref 

### x (Pbar + 

### Pm = 13.6) x (Td + 460)) = (Vd (Pb + ( 

### AH = 13.6)) x (Tref + 

### 460)) AH@ = 0.0317 x AH / Pbar 

### (Td + 460)) x((Tref 

### + 460) x 0 / Vref) 2



### Florida Tile Indtistries, Inc., Kiln 6 Test FBT Enviromnental Services LLC Lawrenceburg, ICY Paducah, ICY Januaiy 15-16, 2008

# APPENDIX 4
ANALYTICAL DATA

Florida Tile Industries, Inc., IGIn 6 Test FBT Enviromnental Services LLC Lawrenceburg, KY Padticah, KY 7anuary 15-16, 2008

# DA CHEM
E.E."F LABOiLATORIES. INr

### Test Pepc)rt-_ P , a E-1 1 

### c , f 

### 2 

### 1•28/08

Suhmitted '_'o: C.'hris Gottschalk FET 

### F_'nv

-

ironmental Services LLC 6860 

### Ston

~ 

### poir-jc C Q I_jrt .Paducah, KY 4 4' Q 0 1 3
R6ference IData: 

### Sample Locatium: Sample Type: 

### Client samnle No. P0 

### Methad •cference: Sample Set IDJ": DATACHEM 

### Lab No.: Datc- Poceived: Prepar

- ation Da

~ 

### ;e: Analysis Date: Hydrogan Fluorida 

### Kiln 6, 

### 1. 1 1orida l'i-le, Lai•ircriceburcl, KY R-K! through Blank 10 9 ,15 EPA 

### Mothod 26 08-L-0255 08-0151'1 ttirough H-01521 ' 0 1 / 

### 2 '1 1 / 'C , 8 0- 1 /22/06 01/22/08 

### Sampl.c. condition wap acceptaL-.)J,c uplon re,-ce.ipt except ',%rhere nctc!d, Analysis Iads completed 

### on a Diancx 1(. 7 2000 Ion Chromatograph clilipped 

### ait!

- L a Dionex ASIB-AGIS 

### column aiicl zi conductance detector. Compound idenu-1-fication is based upcdi

- i rettent,!.ofi ti-me 

### matching oiilv. Any compound wUh a similar re•ention time 1 4il' Ante2ff,2x.-

-

_ , . 

### The r'cSUlts 

### arc provided i-n Lhc- enc

- losed dafa t.lble. E ? 'e S LJ4 I t a 

### relate only ito the Llems tested aiici' arc not blank cnrrected. 1`rds rei

-

_-crt shall not be - 

### roproduced except in full, wi-tl

- iouL the writteti L:pprova.[ cif 'che labaral'.or,/.

J.'j, 

### Trent !,ack

~ 

### kn_ 4

~ 

### 1YSI *

. 

# ~ i 

# ~~~ ._`.. 

# ~ _. 

# v r 

### vieweZl

CINC;NNATI CPFICF '381.1 r 3LENDALE-MILF(IRD ROAD CIPXMNATI. OHIO <5242-3796 Sl 9 735•5335, FAX 513 732-5347 lhtST COAST OFFICE 11 SANTA YOFWA COtJRT NOVAI'O, CALWORMA 94945 500 2 , 10-807 1. FAN 415 89341169



### Florida Tile Industries, Inc., Kiln 6 Test FBT Environrnental Scivices LLC Lawrenceburg, ICY Padi-icah, KY 

### Jaiiiialy 15-16, 2008

### Tp-s , l: Fcpo- ,- t Page 2 c1f , 2 

### Sample TD: 08-L-0255 

## Data Table Hydrogen Fluoride

Cli-ent ID 

### Lab ID Impinger Volume(ML) 

### racj / s 

### amp 10 

### mg/sample Duplicate 

### R , -[ , ;j 

### t) 8 

### 15 - 1- 7 C. 

### -, -1— ---

0.91 0 

### .` 9 

### " 6 — 

### R-'K2 iD Ei - 0 1511 8 

### 1 S 

### 6. 1.3 1.3 

### R - 08-01519 

### 48, 0.59 0.99



### 8 - 0 15 

### 2 Cl 40. 0.15 0.15 

### r' , - C" 

### 2 08-01521 O.063 

### R - C-2 08-01622 

### 4 

### r. 1.1 D 

### B ], 

### ar) k (J8-01.523 

### tdlJ ND

EQL 0 . 

### C) El 

### NI) i.mcdi.cutv`t: analytc , was not dctc

~ 

### ctc

- -d nt or abovc

- tho c`;timaLo .L inii-t (EQT.) .

- f


## T irc'n(: Rac Analyst

Florida Tile Industries, Inc., ICIn 6 

### Test FBT Enviroi

- niiental Selvices LLC 

### Lawrenceburg, KY Paducah, KY Jaiiiialy 15-16, 2008

## ANALYTfCAL REQUEST SL CHAJN OF CUSTODY FI3T L;nvironmental Serwices LLC: LAttORr1TORY 6860 StouepointCourt DatnCliem l.,at,aratories Yadacnh. KY 42003 4385 Cilendale-N-lilford Road (270) 89$-fi7S2 Fax:(270) 898!)694 Cincinnuti, (_7hio 45242-37(Ki

ClA'iE&mPPBD POF$f.hiPLE& ti:.MP113TYPB 1 1 I:qFE,1T 1 1441dES+TlUIvfL'01

1 7 liquids Kiln 6 Florida'I'ile -- t;011 UA:rnt-rrr.i<sraN 1065 Chris C3ottscl3alk Lawrencebur•r„ 1:Y

1. AnulVre per USE['A ReFcrenee Nleiliod 26r^. tt+r 1I1" as nnteLt. j?Rl{)RlTY SAn•tPLE N-teasurc antt r4P

~ rrsnmplc volunms. I.l:T1.1RT ~



## ~ ~~ ~~ ~ ~ vrn<na: L 

## ~ xt str K.r.taxc.

izusx 1'ES Nf)



### x 

## ~
SAbiPLE # SAA•1PL,E CC)N'1'All\'E12 r1vALYSES i

~ F'QLIITZI3L}

77ATE DFSCRIT'TION
St j (:

~ R-K1 Impingrcr samples hCF nfl via USEI'A 26 t51

~ IZ-K2 in 8 oz Liottles
CJ

~~ i2UR-Cl

~ z1R-C3 

### l5L3t3ltuiTt

CCIAIN 

## C3F CUSTC}DY RF,QUEST S;aMPl-Es DEL,tVERED BY: U.S. n•IAII-, _ rr1)1:a/(JPS x Cour.IH. _ OTrER_,

I'URPo41: Ft;Nt CUST03:)Y CF1Alv'G6 ~ KGiLINC?111S1-IEI) 13Y: (S1GN,

~ '1•URH) RECEIVI;D f3Y: (SIGN:ITURi;) 

### 1-17-05 Analysis

_. _.



### Florida Tile Indtistries,.Inc., Kiln 6 Test FBT Enviromnental Services LLC LawrenceUurg, KY Paducah, KY January 15-16, 2008

### Calibration Error Test at Run 1. STRATA Version 1.2.1 Operator: Chris Gottschalk Plant Name: Florida Tile Location: Lawrenceburg, KY

Reference Cylinder Numbers Zero Low-range Mid-range High-range CO N2 CC58793 CC92028
Date/Time 1/15/2008 Analyte CO Units ppm Zero Ref Cyl 0 Zero Avg -0.13 Zero Error% 0.1 Low Ref Cyl 80.6 Low Avg ' 

### 80.82 Low Error% 0.1 Mid Ref Cyl 200 Mid Avg 200.6 Mid Error% 0.3 High Ref Cyl High Avg High Error°/a 7:07:00 PASSED

Initial System Bias Check for Run 1. STRATA Version 1.2.1 Operator: Chris Gottschalk Plant Name: Florida Tile Location: Lawrenceburg, KY

Reference Cylinder Numbers Zero Span CO N2 CC92028
Date/Time 1/15/2008 7:11:27 PASSED Analyte CO Units ppm Zero Ref Cyl 0 Zero Cal -0.13 Zero Avg -0.31 Zero Bias% 0.1 Zero Drift% Span Ref Cyl 200 Span Cal 200.6 Span Avg 200.59 Span Bias% 0 Span Drift%



### Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC Lawrenceburg, KY Paducah, KY January 15-16, 2008Test Run 1 Begin. STRATA Version 1.2.1

Operator: Chris Gottschalk Plant Nami Florida Tile Location: Lawrenceburg, KY CO CO ppm ppm 1/15/2008 12:29:58 61.08 1115/2008 13:14:02 54.7 1/15/2008 12:29:59 61.34 1/15/2008 13:15:02 55 1/15/2008 12:30:00 61.85 1/15/2008 13:16:02 55.41 Begin calculating run averages 1/15/2008 13:17:02 55.28 1/15/2008 12:31:02 63.06 1/15/2008 13:18:01 55.37 1/15/2008 12:32:01 61.22 1/15/2008 13:19:02 55.84 1/1512008 12:33:02 57.81 1/15/2008 13:20:01 55.03 1/15/2008 12:34:02 55.62 1/1512008 13:21:02 55.03 1/15/2008 12:35:02 55.79 1/15/2008 13:22:01 55.23 1/15/2008 12:36:02 54.9 1/15/2008 13:23:02 55.41 1/15/2008 12:37:01 54.82 1/15/2008 13:24:01 54.78 1/15/2008 12:38:02 55.06 1/15/2008 13:25:02 54.14 1/15/2008 12:39:01 55.91 1/15/2008 13:26:02 52.58 1/15/2008 12:40:02 55.04 1/15/2008 13:27:01 52.49 1/15/2008 12:41:02 56.14 1/15/2008 13:28:02 53.32 1/15/2008 12:42:02 56.61 1/15/2008 13:29:02 53.85 1/15/2008 12:43:02 57.68 1/15/2008 13:30:02 54.1 1/15/2008 12:44:01 55.77 Average of Test Run CO 1/15/2008 12:45:02 55.43 ppm 1/1512008 12:46:01 55.49 1/15/2008 13:30:02 56.12 1/15/2008 12:47:02 56.75 Test Run 1 End 1/15/2008 12:48:02 58.24 1 /15/2008 12:49:01 58.49 1/15/2008 12:50:02 58.66 Final System Bias Check for Run 1. STRATA Version 1.2.1 1/15/2008 12:51:01 58.94 Operator: Chris Gottschalk 1/15/2008 12:52:02 58.2 Plant Name: Florida Tile 1/15/2008 12:53:02 57.28 Location: Lawrenceburg, KY 1/15/2008 12:54:02 56.73 Reference Cylinder Numbers 1/15/2008 12:55:02 57.51 Zero Span 1/15/2008 12:56:01 57.26 CO N2 CC92028 1/15/2008 12:57:02 54.07 1/15/2008 12:58:01 54.24 Date/Time 1/15/2008 13:39:43 PASSED 1/15/2008 12:59:02 54.5 Analyte CO 1/15/2008 13:00:02 56.14 Units ppm 1/15/2008 13:01:01 57.68 Zero Ref Cyl 0 1/15/2008 13:02:02 58.42 Zero Cal -0.13 1/15/2008 13:03:01 58.24 Zero Avg -0.78 1/15/2008 13:04:02 58.01 Zero Bias% 0.3 1/15/2008 13:05:02 '57.85 Zero Drift% -0.2 1/15/2008 13:06:01 56.89 Span Ref Cyl 200 1/15/2008 13:07:02 56.7 Span Cal 200.6 1/15/2008 13:08:01 56.13 Span Avg 194.99 1/15/2008 13:09:02 55.75 Span Bias% 2.8 1/15/2008 13:10:02 55.21 Span Drift% -2.8 1/15/2008 13:11:02 55.38 1/15/2008 13:12:02 54.84 Ini Zero Avg -0.31 1/15/2008 13:13:01 54.89 Ini Span Avg 200.59 Run Avg 56.12 Co -0.54 Cm 197.79 Correct Avg 57.13



### Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromilental Services LLC Lawrenceburg, ICY Paducah, KY 7anuaiy 15-16, 2008Test Run 2 Begin. STRATA Version 1.2.1

Operator: Chris Gottschalk Plant Nam( Florida Tile Location: Lawrenceburg, KY CO CO ppm ppm 1/15/2008 13:46:43 2.48 1/15/2008 14:33:02 55.7 1/15/2008 13:47:43 12.03 1/15/2008 14:34:02 63.26 1/15/2008 13:48:43 51.8 1/15/2008 14:35:02 69.45 Begin calculating run averages 1/15/2008 14:36:02 68.75 1/15/2008 13:50:02 55.59 1/15/2008 14:37:03 64.28 1/15/2008 13:51:02 55.78 1/15/2008 14:38:02 63.44 1/15/2008 13:52:03 55.39 1/15/2008 14:39:03 63.48 1/15/2008 13:53:02 55.13 1/15/2008. 14:40:02 62.99 1/15/2008 13:54:02 55.25 1/15/2008 14:41:02 59.51 1/15/2008 13:55:02 55.3 1/15/2008 14:42:02 58.11 1/15/2008 13:56:02 55.8 1/15/2008 14:43:02 58.36 1/15/2008 13:57:03 55.65 1/15/2008 14:44:03 58.36 1/15/2008 13:58:02 56.01 1/15/2008 14:45:02 59.25 1/15/2008 13:59:03 56.16 1/15/2008 14:46:02 59.55 1/15/2008 14:00:02 54.93 1/15/2008 14:47:02 59.36 1/15/2008 14:01:02 54.88 1/15/2008 14:48:03 58.99 1/15/2008 14:02:02 53.8 1/15/2008 14:49:02 58.69 1/15/2008 14:03:02 53.5 Average of Test Run CO 1/15/2008 14:04:03 54.18 ppm 1/15/2008 14:05:02 55.38 1/15/2008 14:49:02 55.39 1/15/2008 14:06:02 56.9 Test Run 2 End 1/15/2008 14:07:02 57.65 1/15/2008 14:08:03 58.14 1/15/2008 14:09:02 58.24 Final System Bias Check for Run 2. STRATA Version 1.2.1 1/15/2008 14:10:02 58.91 Operator: Chris Gottschalk 1/15/2008 14:11:02 57.47 Plant Name: Florida Tile 1/15/2008 14:12:02 53.72 Location: Lawrenceburg, KY 1/15/2008 14:13:03 50.98 Reference Cylinder Numbers 1/15/2008 14:14:02 50.48 Zero Span 1/15/2008 14:15:03 53.1 CO N2 CC92028 1/15/2008 14:16:02 55.34 1/15/2008 14:17:02 58 Date/Time 1/15/2008 14:57:19 PASSED 1/15/2008 14:18:02 59.47 Analyte CO 1/15/2008 14:19:02 60.16 Units ppm 1/15/2008 14:20:03 59.8 Zero Ref Cyl 0 1/15/2008 14:21:02 59.54 Zero Cal -0.13 1/15/2008 14:22:02 58.85 Zero Avg 0.06 1/15/2008 14:23:02 57.28 Zero Bias% 0.1 1/15/2008 14:24:02 56.21 Zero Drift°/a 0.4 1/15/2008 14:25:03 56.55 Span Ref Cyl 200 1/15/2008 14:26:02 56.47 Span Cal 200.6 1/15/2008 14:27:03 47.67 Span Avg 194.1 1/15/2008 14:28:02 31.54 Span Bias% 3.3 1/15/2008 14:29:02 24.51 Span Drift% -0.4 1/15/2008 14:30:02 25.27 1/15/2008 14:31:02 33.93 Ini Zero Avg -0.78 1/15/2008 14:32:03 42.92 Ini Span Avg 194.99 Run Avg 55.39 Co -0.36 Cm 194.54 Correct Avg 57.21

Florida Tile Industries, Inc., Kiln 

### 6 Test FBT Enviroiunental Services LLC Lawrenceburg, KY Paducah, KY January 

### 15-16, 2008Test Run 3 Begin. STRATA Version 1.2.1 Operator: Chris Gottschalk Plant Nami Florida Tile Location: Lawrenceburg, KY CO CO ppm ppm 1/15/2008 15:03:19 55.13 1/15/2008 15:50:04 56.74 1/15/2008 15:04:19 56.13 1/15/2008 15:51:04 56.91 1/15/2008 15:05:19 56.17 1/15/2008 15:52:04 56.45 Begin calculating run averages 1/15/2008 15:53:03 56.18 1/15/2008 15:07:04 56.63 1/15/2008 15:54:04 56.15 1/15/2008 15:08:03 57.07 1/15/2008 15:55:04 42.39 1/15/2008 15:09:04 56.16 1/15/2008 15:56:04 27.56 1/15/2008 15:10:04 54.5 1/15/2008 15:57:03 32.47 1/15/2008 15:11:04 54.06 1/15/2008 15:58:04 39.85 1/15/2008 15:12:04 54.13 1/15/2008 15:59:04 49.01 1/15/2008 15:13:03 54.81 1/15/2008 16:00:04 60.57 1/15/2008 15:14:04 55.77 1/15/2008 16:01:04 62.63 1/15/2008 15:15:03 56.15 1/15/2008 16:02:03 61.34 1/15/2008 15:16:04 56.7 1/15/2008 16:03:04 61.87 1/15/2008 15:17:04 56.64 1/15/2008 16:04:04 62.02 1/15/2008 15:18:03 56.68 1/15/2008 16:05:04 61.72 1/15/2008 15:19:04 56.91 1/15/2008 16:06:04 61.04 1/15/2008 15:20:03 56.53 Average of Test Run CO 1/15/2008 15:21:04 56.64 ppm 1/15/2008 15:22:04 56.71 1/15/2008 16:06:04 54.57 1/15/2008 15:23:04 56.51 Test Run 3 End 1/15/2008 15:24:03 56.37 1/15/2008 15:25:04 56.38 1/15/2008 15:26:04 56.05 Final System Bias Check for Run 3. STRATA Version 1.2.1 1/15/2008 15:27:04 56.27 Operator: Chris Gottschalk 1/15/2008 15:28:04 56.14 Plant Name: Florida Tile 1/15/2008 15:29:03 56.19 Location: Lawrenceburg, KY 1/15/2008 15:30:04 56.19 Reference Cylinder Numbers 1/15/2008 15:31:03 56.15 Zero Span 1/15/2008 15:32:04 55.77 CO N2 CC92028 1/15/2008 15:33:04 56.17 1/15/2008 15:34:04 55.44 Date/Time 1/15/2008 16:20:42 PASSED 1/15/2008 15:35:04 52.51 Analyte CO 1/15/2008 15:36:03 49.29 Units ppm 1/15/2008 15:37:04 47.51 Zero Ref Cyl 0 1/15/2008 15:38:04 46.34 Zero Cal -0.13 1/15/2008 15:39:04 46.95 Zero Avg -1.63 1/15/2008 15:40:04 46.04 Zero Bias% 0.8 1/15/2008 15:41:03 47.21 Zero Drift% -0.8 1/15/2008 15:42:04 50.26 Span Ref Cyl 200 1/15/2008 15:43:04 54 Span Cal 200.6 1/15/2008 15:44:04 57.12 Span Avg 192.11 1/15/2008 15:45:04 60.83 Span Bias% 4.2 1/15/2008 15:46:03 62.46 Span Drift% -1 1/1/2008 15:47:04 61.46 1/15/2008 15:48:04 59.9 Ini Zero Avg 0.06 1/15/2008 15:49:04 57.5 Ini Span Avg 194.1 Run Avg 54.57 Co -0.79 Cm 193.11 Correct Avg 57.1



### Flor'ida Tile Industries, Inc., Kiln 6 Test FBT Enviroiunental Services LLC Lawrenceburg, KY Paducah, KY January 15-16, 2008

# APPENDIX 5
PROCESS DATA

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC Lawrenceburg, KY Paducah, KY Januaiy 15-16, 2009

### Jan 15, 2008:

Time 12:30 - 13:30 13:45 - 14:45 15:00 - 16:00 Average

Heating section temps Range 1206 C 1205 - 1208 C 1208 C 1207 - 1209 C 1207 C 1205 - 1208 C Average Cooling section temps Range 179C 179-180C 180C 179-180C 180C 179

- 

### 181 C

Volume of materials through Kiln 12:30 - 13:30 10609 Ibs 13:45 - 14:45 10130.4 Ibs 15:00 - 16:00 10904.4 Ibs



### The Kiln temps are computer controlled. The set point is 1206. The average temps for the dates requested are as follows;

16 Jan '08

8:30 — 9:30 1207
9:45 — 10:45 1206
11:00 — 12:00 1206
Mike J.

Florida Tile Industries, Inc., Kiln 6 Test FBT Envirormlental Services LLC Lawrenceburg, KY Paducah, KY January 15-16, 2008