FINAL REPORT 

KILN 6 HF, CO EMISSIONS 

EVALUATION 

prepared for 

Florida Tile Industries, Inc. 

1247A1ton Road 

Lawrenceburg, KY 40342 

by 

FBT Environmental Services LLC 

6860 Stonepoint Court 

Paducab, KY 42003 

(270) 898-8782 

Prepared by: 

Cliris Gottscballc 

Project Manager 

Test Perforined: Report Issued: 

January 15-16, 2008 February 20, 2008 
KILN 6 HF, CO EMISSIONS 

EVALUATION 

FLORIDA TILE INDUSTRIES, INC. 

LAWRENCEBURG, KENTUCKY 

TABLE OF CONTENTS 

EXECUTIVESUMMARY ...........................................................................................................3 

1.0 INTRODUCTION ..............................................................................................................4 

2.0 TEST RESULTS AND CONCLUSIONS ........................................................................4 

3.0 PROCESS DESCRIPTION ..............................................................................................5 

4.0 SAMPLING PROCEDURES ...........................................................................................5 

APPENDICES 

1 Example Calculations and Calculated Test Results 

2 Field and Sampling Site Data 

3 Calibration Data 

4 Analytical Data 

5 Process Data 

2 

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromnental Services LLC 

Lawrenceburg, KY Paducah, KY 

7anuary 15-16, 2008 
KILN 6 HF, CO EMISSIONS 

EVALUATION 

FLORIDA TILE INDUSTRIES, INC. 

LAWRENCEBURG, KENTUCKY 

EXECUTIVE SUMMARY 

FBT Enviromnental Services, LLC (FBT) was retained by Florida Tile hidushies, Inc. to conduct 

an einissions evaluation on Kiln 6 at its facility in Lawrenceburg, Kentucicy. Kiln 6 is used to 

cure green cerainic tile on one of the production lines. The purpose of the evaluation was to 

measure hydrogen fluoride (HF) and carbon monoxide (CO) einissions from the lcihi. Kihi 6 is 

divided into two sections, a natural gas fired heating zone and an air-cooling zone. The two 

sections have separate exhaust vents to the atmosphere. Botli HF and CO emissions were 

measured in the heating section vent and only HF einissions were measured in the cooling 

section vent. The evaluation was perfonned January 15-16, 2008. Results are presented in Table 

1. 

Table 1 Kiln 6 Emissions Summary 

Heating Cooling Total Two 

Section Section Sections 

HF: 

ppm 21.9 1.9 

pounds/hour 0.6879 0.1402 0.8281 

CO: 

ppm 57.1 not 

pounds/hour 2.515 measured 

ppm = parts per million volume dry basis 

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromnental Services LLC 

Lawrenceburg, KY Paducah, KY 

January 15-16, 2008 
KILN 6 HF, CO EMISSIONS 

EVALUATION 

FLORIDA TILE INDUSTRIES, INC. 

LAWRENCEBURG,KENTUCKY 

1.0 INTRODUCTION 

FBT Enviroiunental Services, LLC (FBT) was retained by Florida Tile Industries, Inc., to 

conduct an emissions evaluation on Kiln 6 at its plant in Lawrenceburg, Kentucicy. Kiln 6 is 

used to cure green ceramic tile on one of the prodtiction lines. The purpose of the evaluation was 

to measure hydrogen fluoride (HF) and carbon monoxide (CO) einissions from the lciln. Kihi 6 

is divided into two sections, a nattual gas fired heating zone and an air-cooling zone. The two 

sections have separate exhaust vents to the atmosphere. Both HF and CO emissions were 

measured in the heating section vent and only HF emissions were measured in the cooling 

section vent. 

The evaluation was performed January 15-16, 2008. FBT's test team consisted of Chris 

Gottschallc, Michael Meadows, and Doug Jones. DataChem Laboratories in Cincimlati, Ohio, 

analyzed the samples for HF. Sampling was coord'ulated with plant operations by Florida Tile 

representative Milce Joluiston. Gerald Slucher and Milce Toncray observed the test for the 

Kentucicy Division for Air Quality (KY DAQ). 

2.0 TEST RESULTS 

Heating section einissions of HF and CO and cooling section einissions of HF are presented in 

Table 2.1. Stacic gas conditions for each run are presented in Table 2.2. 

Example calculations and calculated test results are presented in Appendix 1. Field data sheets 

and sampling site data are presented in Appendix 2. Calibration data is contained in Appendix 3. 

Analytical results are presented in Appendix 4. Process data is contained in Appendix 5. 

4 

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviroiunental Services LLC 

Lawrenceburg, KY Paducah, KY 

Januaiy 15-16, 2008 
Table 2.1 Kiln 6 Emissions and Stack Gas Conditions 

Heating Section Emissions: Cooling Section Emissions: 

Date: 1-15-08 1-15-08 1-15-08 

Time: 1230-1330 1346-1446 1508-1608 Averages 

Run: K-1 K-2 K-3 

HF: 

ppm 21.3 30.5 13.8 21.9 

pounds/liour 0.6656 0.9591 0.4389 0.6879 

CO: 

ppm 57.1 57.2 57.1 1 57.1 

pounds/liour 2.493 2.518 2.535 1 2.515 

1-16-08 1-16-08 1-16-08 

0825-0925 0942-1042 1055-1155 Averages 

C-1 C-2 C-3 

3.5 1.5 0.6 1.9 

0.2603 0.1162 0.0442 0.1402 

CO Not Measured 

Total Two 

Sections 

0.8281 

Stack Gas Conditions: 

Velocity, Vs: f s 48.28 47.84 49.13 48.41 

Stacic Gas acfm 15,676 15,533 15,953 15,721 

FlowRate: lscfm 10,015 10,102 10,187 10,101 

Tem ,Ts: °F 308. 308 309 308 

HZO: % 6.3 4.6 6.1 5.7 

O': % 19 1 19 19 18.5 

COZ : % 2.0 1 2.0 1 2.0 1 2.0 

69.48 69.59 

32,866 31,976 32,023 

24,845 24,177 24,258 P

71.42 

220 221 218 

1.0 0.8 1.1 

20.9 20.9 20.9 

0.0 0.0 0.0 

Key: ppm = parts per million volume dry basis acfm = actual cubic feet per minute 

fps = feet per second dscfm = dry standard cubic feet per minute 

*Note: HF for run C-3 (shaded) was not detected at or above the estimated quantification limit (0.05 

mg/sample) for the analytical method. Half the estimated quantification limit is used for emissions 

calculations. 

3.0 PROCESS DESCRIPTION 

Florida Tile manufactures ceramic tile at its facility in Lawrenceburg, Kentlicicy. Line 6 consists 

of powder and prill storage silos, belt conveyors, a vibrating screen, pneumatic gates, a press, a 

decorating line, roller Kiln 6, several dust collectors and associated process control equipment. 

Kiln 6 is used to cure green tile. It has a nattiral gas fired tile heating section followed by a 

cooling section utilizing air as the cooling medium. Each of the two sections has an exliaust vent 

to the atmosphere. Kiln 6 has no emissions controls. 

4.0 SAMPLING PROCEDURES 

Sampling and analytical procedures used were USEPA Reference Methods for stationary sources 

described in the latest edition of CFR 40 Part 60 Appendix A. Methods used are listed below: 

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC 

Lawrenceburg, ICY Paducah, KY 

January 15-16, 2008 
4.1 Measurement Sites (Method 1) 

Location of ineasurement sites and number of traverse points for velocity and volumetric flow 

measurements were deterinuied as specified in USEPA Reference Metlzod I, Sanzple and 

Velocity Traverses for Stationary Sozn°ces. 

4.2 Velocities and Volumetric Flow Rates (Method 2) 

Stacic gas velocities and volumetric flow rates were detennined using IISEPA Reference 

Metlzod 2, Deterinination of Stack Gas Velocity and Volzrnzetric Flow Rate. Velocities were 

measured with a S-type pitot tube and temperatures were measured with calibrated type K 

thermocouples. 

4.3 Dry Molecular Weight (Method 3) 

Diy molecular weight of stacic gases was detennined using USEPA Reference Metliod 3, Gas 

Analysis for Carbon Dioxide, Oxygen, Excess Air, and Diy Molecular Weiglht. Grab samples of 

stacic gases were collected during each run and analyzed for oxygen and carbon dioxide with a 

Fyrite Combustion Gas Analyzer. 

4.4 Moisture (Method 4) 

Moishire content of stacic gases was deternnined using USEPA Metlzod 4, Deterinination of 

Moistzire Content ii2 Stacic Gases. 

4.5 Hydrogen Fluoride Emissions (Method 26) 

Hydrogen fluoride concentrations of stacic gases were determuied using USEPA Reference 

Method 26, Deternzinatio» ofHydrogen Clzloride Enzissions fi°oin Stationaiy Soan^ces. This 

method is applicable to HF in addition to HCI. Samples of stacic gas were withdrawn with a 

vacuum puinp tlirough a glass probe, a heated TFE coated filter, a set of impingers in an ice bath, 

a silica gel coluinn, and a critical orifice. The first two impingers contained 0.1N H2SO4, the 

third was empty, and the fourth contained O.1N NaOH. Contents of the first three impingers 

were recovered and sent to the laboratoiy for analysis by ion chromatography. 

6 

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviroiunental Services LLC 

Lawrenceburg, KY Paducah, KY 

January 15-16, 2008 
APPENDIX 1 

EXAMPLE CALCULATIONS 

AND 

CALCULATED TEST RESULTS 

Florida Tile Industries, Inc., Kihi 6 Test FBT Enviromnental Services LLC 

Lawrenceburg, KY Paducah, KY 

Januaiy 15-16, 2008 
HF, CO Emissions 

SAMPLE CALCULATION 

CLIENT/PROJECT: 

SAMPLE LOCATION: 

DATE: 

TIME: 

RUN #: 

Florida Tile Industries, Inc. 

ICiln 6 - Heating Section 

1-15-08 

1230-1330 

IC-I 

STACIC GAS CONDITIONS 

SAMPLE VOLUME: 

Vinstd (dscf) = Qstd (Lhnin)/28.317(L/ft 3 ) x O (min) x (Pb +Psainp/13.6) / (Pb + Pcal/13.6) = 1.9066 

MOISTURE: 

% H2 O = 100 x 0.04707 x Vol. Condensate (ml)/ (Vrnstd +(Vol. Condensate x 0.04707) = 6.30 

MOLECULAR WEIGHT: 

Md = .1604 x %CHq+ 0.44 x %CO, + .2805 x %C,Hq+ .3007 x %C,H6+ 

.28 x%N,+ 0.32 x%0, + 0.28 x%CO = 29.06 

Ms = Md x(1 - Bws) +(18.0 x Bws) = 28.36 

STACK GAS VELOCITY: 

Vs(fps) = 85.49 x Cp x Avg (AP ° '5 ) x[Ts(°R)/(Ps("Hg) x Ms)] °' 5= 48.28 

STACK GAS FLOW RATE: 

Qa (acfin) = Vs x 60 x As(ft') = 15,676 

Qstd (dscfin) = Qa x 17.647 x(1%H 2 O/100) x Ps/Ts(°R) = 10,015 

EMISSIONS CAL CULA TIONS: 

CONCENTRATION: 

Gaseous Analytes (HF): 

Cs(Ib HF/dscf) = mg F/Sample x Mw HF/Mw F/ Vmstd (dscf) / 453,592 mg/lb = 1.108E-06 

Cs(ppm HF) =1b HF/dscf x 385500000 ft3/Ib / Mw HF = 21.3 

EMISSION RATE: 

Er(lb HF /hr) = Cs(Ib/dscf) x Qstd x 60 = 0.6656 

Er(lb CO/hr) = Cs(ppm CO)/10 6 x(Mw (CO) /385.55) x Qstd x 60 = 2.493 

Florida Tile Industries,'Inc., Kiln 6 Test FBT Enviromnental Services LLC 

Lawrenceburg, ICY Paducah, KY 

January 15-16, 2008 
HF & CO Emissions 

CLIENT/PROJECT #: Florida Tile Industries, Inc. 

SAMPLE LOCATION: Kiln 6- Heating Section Kiln 6- Cooling Section 

DATE: 1-15-08 1-16-08 

TIME (hrs): 1230-1330 1346-1446 1508-1608 0825-0925 0942-1042 1055-1155 

RUN #: K-1 K-2 K-3 C-1 C-2 C-3 

Static Pressure, "H2O: -0.53 -0.57 -0.75 -0.56 -0.73 -0.78 

Barometric Press., "Hg: 29.70 29.70 29.70 29.48 29.48 29.48 

Sample Time, O, min: 60.0 60.0 60.0 60.0 60.0 60.0 

Orifice Qstd, L/min: 0.931 0.931 0.931 0.931 0.931 0.931 

Avg Orifice Temp, To, °F: 70.9 72.8 72.9 76.4 78.0 82.1 

Orifice in Pcal, "H2O: -3.9 -3.9 -3.9 -3.9 -3.9 -3.9 

Orifice in Psamp, "H2O: -17.3 -17.3 -17.3 -17.3 -17.3 -17.3 

Avg. Sq. Root DP, "H2O ° '$ : 0.7038 0.6995 0.7156 1.0582 1.1089 1.0783 

Avg Stack Temp, °F: 307.7 308.1 308.9 213.3 219.8 221.1 

Cp PITOT : 0.84 0.84 0.84 0.84 0.84 0.84 

Circ. Stack? 1=Y,0=N: 1 1 1 1 1 1 

DIA (in) if 1, AREA (in') if 0: 31.50 31.50 31.50 37.50 37.50 37.50 

02 , %: 18.5 18.5 18.5 20.9 20.9 20.9 

CO2 , %: 2.0 2.0 2.0 0.0 0.0 0.0 

H,0 (°/n): 6.30 4.56 6.14 1.42 1.03 0.81 

Analyte # 1: HF (Metltod 26) 

Molecular Weiglit: 20 20 20 20 20 20 

HF as F, mg/sample: 0.91 1.3 0.59 0.15 0.064 0.025 

Analyte # 2: CO (Method 10) 

Molecular Weight: 28.00 28.00 28.00 

CO, ppm: 57.130 57.210 57.100 Not Measured 

********************CALCULATED RESULTS******************** 

Stack Gas Conditions: 

Velocity, Vs (fps): 48.28 47.84 49.13 67.86 71.42 69.48 

Volume Flow Rate, Qs•(acfm): 15,676 15,533 15,953 31,228 32,865 31,976 

(dscfni): 10,015 10,102 10,187 23,754 24,847 24,179 

Temperature, Ts ( °F) : 308 308 309 213 220 221 

HZO (%): 6.30 4.56 6.14 1.42 1.03 0.81 

0, (%): 18.50 18.50 18.50 20.90 20.90 20.90 

CO, (%): 2.00 2.00 2.00 0.00 0.00 0.00 

Static Pressure, ("Hg abs): 29.66 29.66 29.64 29.44 29.43 29.42 

Dry Mole Wt, Md: 29.06 29.06 29.06 28.84 28.84 28.84 

Stacic Mole Wt, Ms: 28.36 28.56 28.38 28.68 28.72 28.75 

Sampling Parameters: 

Sample Volume; Vm std (dscf): 1.907 1.907 1.907 1.906 1.906 1.906 

Stack Area (ft'): 5.4119 5.4119 5.4119 7.6699 7.6699 7.6699 

HP Emissions: 

Concentration (Cs) Ib/dscf: 1.108E-06 1.582E-06 7.181E-07 1.826E-07 7.792E-08 3.044E-08 

Concentration (Cs) ppm dry: 21.3 30.5 13.8 3.5 1.5 0.6 

Emission Rate (Er) Ib/lir: 0.6656 0.9591 0.4389 0.2603 0.1162 0.0442 

CO Emissions: 

Concentration (Cs) ppm dry: 57.13 57.21 57.10 CO Not Measured 

Emission Rate (Er) lb/hr: 2.493 2.518 2.535 - - - 

*Note: HF for run C-3 (shaded) was not detected at or above the estimated quantification limit (0.05 mg/sample) 

for the analytical method. Half the estimated quantification limit is used for emissions calculations. 

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC 

Lawrenceburg, KY Paducah, KY 

Januaiy 15-16, 2008 
Exhaust Gas Moisture Concentration 

CLIENT/PROJECT #: Florida Tile Industries, Inc. 

SAMPLE LOCATION: Kiln 6- Heating Section Kiln 6- Cooling Section 

DATE: 1-15-08 1-15-08 1-15-08 1-16-08 1-16-08 1-16-08 

TIME (hrs): 

RUN #: K-1 K-2 K-3 C-1 C-1 C-1 

BAROMETRIC, "Hg: 29.70 29.70 29.70 29.48 29.48 29.48 

SAMPLE TIME, min: 30.0 30.0 30.0 30.0 30.0 30.0 

ACTUAL METER VOLUME, ft3 : 22.999 23.073 23.023 23.904 23.853 24.171 

AVG ORIFICE AII, "H2O: 1.70 1.70 1.70 1.70 1.70 1.70 

AVG METER TEMP, °F: 86.2 88.7 89.8 80.3 81.7 83.3 

METER GAMMA: 0.979 0.979 0.979 0.979 0.979 0.979 

LEAK RATE (0 IF<0.02): 0 0 0 0 0 0 

CIRC STACK? 1=Y,0=N: 1 1 1 1 1 I 

DIA (in) if 1, AREA (in') if 0: 

0" %: 

COZ , %: 

VOL CONDENSATE, ml: 31 22 30 7 5 4 

*****************CALCULATED RESULTS**************** 4 

Stacic Gas Conditions: 

H2 0 ( 0/0): 6.30 

Sampling Parameters: 

SAMPLE VOLUME, Vm corr(i1): 22.999 

SAMPLE VOLUME, Vm std (dsef): 21.694 

4.56 6.14 1.44 1.03 0.82 

23.073 23.023 23.904 23.853 24.171 

21.665 21.575 22.626 22.519 22.753 

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC 

Lawrenceburg, KY Paducah, ICY 

January 15-16, 2008 
APPENDIX 2 

FIELD AND SAMPLING SITE DATA 

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromnental Services LLC 

Lawrenceburg, KY Paducah, KY 

Januaiy 15-16, 2008 
16 

Yg DATA SurwT 

Cliunt: 1:1,A Date: ~ P .0 Orifice it: 

Site: k , L-o Operator: RotorneterM: 

Run#' Leak Ck pre: ✓ T L i b c F's: 

Rr,j ,r post: Pi- obc: 

Procedilre (tilbes, bag):_2LL2~  Analdes: 

Sampling Piirkimeters 

'rime VaCULU11 FloW 

cciiiiiii 

r 

Teiiii) F 

Tiiiie 

Clock ?i Sample 

Vaciiijtli 

TIg 

Flow 

cdriiin 

ofifige 

Clock Sample 1'etiij) 'F 

0 

5 

35 /7j c 

?d L) 6 ?A-17 40 L) 

45 ?;z 

15 ` 7) 50 lq, 70D 

20 

25 

14 7 

30 19Z5 F Avg 'f'criip: I -1 0 "I 

Clielit: Date: 

tfJfiol )? 

Site: Operator: — fff-- 

Ruri #: j~'_2 LeakCk 

I'L- 2!-/e) post: 

IlrocedLIYC (tLibes, bag): Aiial}qes: 

Samplitign Parameters 

OriFice 11': 

Rotoiiieter 41 : 

Tube iis: 

Probe: 

vx) 

l'blic N.'acuLL111 

"I-Tq 

Flow 

I ccfiiiili 

OH fiecl 

0 1'einp 'T 

'Fillic 

Clock Saiiiple 

Viz~,, 

"I Lv 

Flow 

Clock Sample ccimil 

0 

/Z:f 

3 _5 

5 40 /q 

10 

ZO 

200 

i__ . 

15 57, 50 

55 

60 

20 

25 

Iq _r 7 

jq ;5 W I : 

30 1 cl ~ L 76 L) 6,6 Avg 'remp: 

Florida Tile Ind-Listries, Inc., ICiln 6 Test FBT Envirolu-ilental Selvices LLC 

Lawrenceburg, ICY Paducah, KY 

Janualy 15-16, 2008 
916 

METHOD J-9 DATA SIIEE'F 

Client: Date: Orifice 4: 

Site: > Operator: Rotorneter 4: 

Ruii Leak Ck pre: Tube 4s: 

post: Probe: 

Procedkire (ttibes, ba –g)' Analvtes: — 141 ir-- 

Stiiiipliiio Parameters 

Tiine aeLtwii 

Clock Saiiiple H 

Ftow 

cc/min 

Oii 1-ic n 4(J 

Teiiij) "F 

Tiiiie Vacuum Flow 

( cclinin 

orifice/ 

4 V ~ a ,A7,o 

Clock Smiplc blHg reiiip t; 

0 

5 

35 -/ / 9d 0 

i,no f / -73 1267 -2, 40 

ft) 45 

15 7,) 

7,)D 

-3 

24✓ 

50 

$

5 /5; "C 2 6 L) 

73 

?0 

30 

60 

Av-g Tem 

Clielit: FL4, Date: 

Site: 

Run 4: 

I -I LI' 

ProcudLire (tubes, baig): 

Operator: 

Leat.:Ck pre: 

Post: 

A na I ytes: 

Samplinfy Parameters I 

TLibe #s: 

Probe: 

Tiiiie 

Clock S. pie 

vacuu.11 

-T~ 

1 1 1.11- 

ccJmin 

Orfflec 

't'einp "F 

Tijiie Vzictlkijll Flow (DriFice 

Clock Sample "Hg co-min 'I'eillp *F 

o 15 

5 40 

45 

50 

25 60 

30 Avg rcmp: 

~ 

... ....... . 

Florida Tile Industries, Inc., Kiln 6 Test FBT Envirotuiiental Selvices LLC 

Lawreliceburg, KY Paducah, KY 

Jaiivary 15-16, 2008 
GAS VELOCITYANDVJ 

FlodduTilu{udnatrieu Iou, ~Oo6Tuo F 8TBov~ouozoot~ Sur ~oco LLC 

Luwrc000bor~ KY ~ yuduoab,DY 

}uouacyl5-l6.2OO8 
NIOISTURE DATA 5HEE7 

Niellio(i 4 

Locarion: 

:)perator: rkAi= N-leter Box #: C L I AH@!; F: 

Run -#: Date: L 5 Jfa' ~ Pb: 15--74 'Hg 

Pre Test: 0 ft,(ag, lio 1.11B 

ri ) @ Post Test o, r) D () q "HL 

H2O gain: a. o mls + 11 (sg) = tot: 

Run A: fiLl- Date: . 15SA,03 pb: 'IC1.7' "Fig 

Pre -rest-, o,ob O ft' @ t L? 

Post Test: @ ~z 71. 

FL20 gain: J(j 11ls g (sg) = tot-, 

Clork 

' Timc 

Samp 

Time 

Metur 

Read- 

"110 F 'r 

it' 

F 

T.Out 

r 

EJ'L 

111-1g 

VaC 

Clock 

Tirne 

SaniT 

Time 

Met 

ReacL 

14zO 

" All 

'F 

-l", it) 

°F 

T~put 

'T 

Exit 

- 'Hg 

VLIC 

o (/OP. 0 — VT~yl L/ 

5 yA-IY- 30 L) 

lo I -Lc, 1~ 4 I/ ~30 

15 kq /, 4 0 15 L[7 /. -7 W -'I 

20 14V5_5) 1) /,-7 97 92 qo 

2-1 36 A L2 SQ 25 li'4;L-410 ct q i 33 

30 30 4Y4-j-Yq 

779 -70 

Run 9' Y-- 3 Date: 2oT+~ln D~ Pb: Y,rf, -7 1) "Hg 

Pre Test 0ds ') fY OLL, /o ITIg 

Post Test: d, CIL-10 1r3 @ 5- 

11H

~ 

H20 .1ain: ZY 11AS + 9 g (St-) = tat: 

Clock Sniiii Mcfer 

Rend. 

"i-ho 

Al-T IT~, 

'r 

in 

'TT,,ou( 'F 

Exit 

"Hg 

Vac 

0 

5 

10 

15 L) J, 

2CI I - 2 cf2.. 1 22, 

25 S26 J-f? 2- 

3 0 

p, ~ Av,,:: V.1 I -.-T 7; 

~~ _= 

FB - 

Florida Tile Ind-Listries, Inc., ICIn 6 Test FBT Environmental Selvices LLC 

Lawrenceburg, ICY Paducah, KY 

Jaii-Liary 15-16, 2008 
M•THOD 26 DATA — Two Runs 

C"c" Date: Oririce#: 614 

1lotometer 

[~ Un 4: Leak- Ck pre: • — : r -2 . 3 

Pbar 7 .9 -it post: Probe: -5, C0111POL111d(S): H r 

Sampling Parameters 

Time VaCUL1111 Fkrw Oririce 

Teiiip'F 

Tinic 

Clock Sample 

Vartlum 

I-1 9 

Flo w 

cclmin 

7 

Oririce 

5~ —1 4e. "— CIOCL. 1'errip F 

0.12,5 

sampho 

0 

5 5 40 '5 2 

5' 45 

15 50 

?o 55 

25 19,5 &0 qz- 5 60 F~ 6 5 

30 i 1 9,5 Z66F— Pr, Al- Temp: 

Cliciat: Date:'C ' -,g Orifice # 

Site: RotojiieteiLeLLk Ck pre: ✓ r q-- 7 , 

P113T post: Pi-obe 

C.ompoimd(s): 1 -4 t:- 

Sampflug Parameters 

1-1 a, cci'iiiiii 'I'eiiip 'F Clock samplc 

in Flow 

"I I celmin 

Oriitcc 

Clock Samplc 'I'eillp "F 

D 0 -7 s.. 14/zb8 I 35 z( Q 

5 7~l 40 1.5 9 

10 r-o -7 ~ Z65 45 o 

15 -2glw 50 --)cg ,) 7 t, c7 

'2 

5 

tg-o 60 5- 

69 Avc, Teiiip- - 70 ' 0 

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromilental Sel vices LLC 

Lawrenceburg, KY Paducah, ICY 

Jaiivaiy 15-16, 2008 

b t /- 

12- —) 
ivIETHOD 26 DATA — Two Runs 

Cl'cllt: DaLo: Orifce 9: 01(-, 

Oper3tor: 12)$t1~t RotonieLer P: 

Ruli A"': LeLik- Ck pre: a,14-,*,-i : 

pkil 'z S. f-f 1? post: Probe: 

Compound(s): 

Samplina Pa•ameters 

Tiiiie VEICLItIrIl Flow, Orifice 

Temp" 1 7 

'I'iillc V11CULArn 1 7 1ciAv 

cce'iiiiii 

Orifice 

Clock Sample Clock Sample 11J. t, 'I'eiiip "F 

6?-/ 2-7 -Z 35 - 1 01,5 -2 0,2 

RZ 40 --2 C~(-o e"—~ z -2 1 

10 610 Y, 4' 

50 

~0 

~ 9- T 

~~~~

15 2~ zj 

20 2--1 til 

25 60 115 13 

30 Avg 1'eiiip: 1 

Dale: oriricc #r: 

Site: Operator: Rotometer #: 

Izilli 4: Leak Ck pre: 

1) Nr post: Probe: 

Compound(s): 

Sampling Varameters 

y -111 4 

Plo' 

cc/iiiiii 

Orifice 

1'eiiip "F 

'I'iliie VacULIIII Flmv 

cc/iiiiii 

Orifice 

Clock Sample Clocli Teiiip "F 1 Sample 11 lg 

0 35 

5 40 

15 50 

-)0 5-5 

25 

30 

60 

Avc, 'I'eii 

Florida Tile Industries, Inc., Kiln 6 Test FBT Environirriental Sci-vices LLC 

Lawrenceburg, KY Paducali, ICY 

Jaiivaiy 15-16, 2008 
GAS '1J'ELCd*vfT1'ANL 1!'C7LUMETR'!C FLOV9I RATE 

Plant: F1a/-r,4-t Date: r —j B- n 23 

Sampling Location: f/ ~~ ~ Cvol, ~~ ~~ G~ . Leak Chec3c: ✓ ~ 

Run ~: ~ _ { C - ~ ~ t]perators: 

Barorretric Pressure —n Hg: - Static Pressure, ° HaO: 

TC r: _ Pitot Tuh,o Pitot T ube Cp: 

Stack 7imensfon, i, Diameter t~ Side 1: ~~=~ Side 2: 

Wet Bu1b, OF: ~` ~ Dry Bulb, OF: Fyrite 07: ~~-~~~', ~• ~~ COz: ~,,,~~ , 

/::~'t-G '.' ~'t?iN 

pun g: c - r Time: oqt Run T: C- -5Time: iP0 5 Run #: 0-3 Time; r<<•? 

Traverse 

Poir~t ~ 

~P 

in, Na0 

Sfack Temp. 

~ F 

r:1P 

in, Hz0 

Stack Temp. 

°F 

r~ P 

in. H70 

Stack Temp. 

uF 

Z~ av 

z zI 5 z z ~/~z ~ z~ s 

5 _ _ (,2 ~ ~! -7 l, 3_ -z (~ 

zn 

6 

~ 1 Z u G ~ !,3 Zla ! ~ z 2rr 

_ lrl 20 5 ~~3 Z-/t a•z-. ~~~ r 

5 J .Z z~ ~~ /•2- ~~o 

~ - ~ 3 l~

zl~ ~ •:~-~ z:z. ~ , ~ s z. ~ z- 

~ 

i'- ~~i" 

I T Hverape: ~~n t. i ll ~' P= 1,o iy= Ts- z c3r) drt~= l,lcycr ~~P=~ tly7 15= 

~ 

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC 

Lawrenceburg, KY Paducab, KY 

January 15-16, 2008 
MOISTOZE DATASHEET 

Method 4 

k-tL,~ 6-' F 

Clie~ntfCitv: ~ i L.L~ tioii: 

Operator: D~"Ltc'~ . :Tovilf-l" Nleter Box 9: 1 A-H@: i,—Iye r: i 7f, IZ 

Run 9: D Li t c: -b —Of P b: —H 

Pre Test: 0, @ L 

Post Test: OV, o a c) ft' @ "Hg 

H2Ogain: mis + —g iso = tot: -7 

Cl.r 

Tinic ITimel 

~ k IS.d A-Jete 

Read. 

"H20 

4~ IT. ill 

F 

T.011t Exl t 

Hg 

I Vnc 

,n8go 1 0 L -7 7 -7 2- 9 L SL 

5 

lo 

1 5 '1 2' 12, 0 

20 'S- 7 _~-3 Z, o 

25 F -1 Y:-- k2- 3Y Z, C., 

[)q01O 30 f 41 3, 

d 

Z'; 

Ruii V7 i", Date: i I 1 /-1 /0 Pb: = If l~ Ili- ~1-1 9 

PreTest. 0.600 W C) 'lig 

postTest: ftj (t) 

y, 

"H 

HIO gain: 40 nits - 

Clock 

Time 

Sam17 

Time 

N-feter 

Itead. 

"HA) ' 'P 

irl 

F 

T.IGUI X 

-F 

EJT 

"Hp 

VaC 

Ij,)a 0 2,ct ;1 

10 -4:a' Li -3 

15 o, 

20 

25 

30 

Avg: 

Run #: -2- Date: 1l1646- Pb: "lig 

Pre Test: 0061 @ 

Post Tm 0. COO ft' @ "Hg 

FI20 gain: T lills -1, ~ ' (sg) = tot 

Clo-ck 

Time 

Sam 

Ti=mej Nicter Read- 

",H:O 

AH 

"F 

T,„ in 

'F 

Tmoui 

'T 

F-xit 

-Hq 

Vac 

0 Y' /S 'U ?0 2'e 

5 0 

to :"O, 10 5?/ 31 J-a 

15 (, k' -LL -EL "~ 12~- 1 , ci 

20 e-? 2- 

25 fi 4 09, K4 1? 3 3 1 , cl 

30 - it- , o03 

Avg: -'u 

Run *': Date: _ Pb:_"l-Ig 

Pre Test: ft , pi, "H" 

Post 1est: ft' @ "Hg 

H2O gain: MIS + = tot: 

ClockTirne 

samp 

1rime 

1%4ptvr 

Re-iid. 

'TLO 

AH 

-F 

Tm in 

-F 

TnOut 

*F 

Exit Var, 

0 

5 

10 

15 

20 

2S 

30 

FBT 

Florida Tile Industries, Inc., ICIn 6 Test FBT Enviromiiental Sci vices LLC 

Lawrenceburg, KY Padticah, KY 

Januluy 15-16, 2008 
Sainple Port 

(gas) 

Heat Section 

Exliaust Fan 

Kiln 6 Heating Section Vent 

Florida Tile Industries, Inc. 

Lawrenceburg, KY 

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromnental Services LLC 

Lawrenceburg, KY Paducah, KY 

January 15-16, 2008 
Cooling Section Cooling Section 

Exhaust Fan Exlhaust Fan 

Kiln 6 Cooling Section Vent 

Florida Tile hidustries, Inc. 

Lawrenceburg, KY 

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromiiental Services LLC 

Lawrenceburg, KY Paducah, ICY 

January 15-16, 2008 
Client Florida Tile, Lawrenceburg, KY 

Site Kiln 6 Heat Section Vent 

Calculator Cbris Gottsclialk Date 1-14-08 

Distance from upstreani disturbance (d) 92" 

Distance from downstream disriarbance (u) -40' 

Outside of port to far side of stack (a), in. 35 

Outside of port to near side of stack (a), in. 3.5 

1 I I'~ b 

a 

Traverse Point Locator Data 

Inside Stack Diameter (a - b), in. 31.5 tlow disturbance 

Point # ~ /o from wall to point " from wall to 

point (c) Port lengtb (b) " from probe tip to point (b + c) 

1 3.2 1.01 3.50 4.51 

2 10.5 3.31 3.50 6.81 

3 19.4 6.11 3.50 9.61 

4 32.3 10.17 3.50 13.67 

5 67.7 21.33 3.50 24.83 

6 80.6 25.39 3.50 28.89 

7 89.5 28.19 3.50 31.69 

8 96.8 30.49 3.50 33.99 

Florida Tile Industries,•Inc., Kiln 6 Test FBT Envirotunental Services LLC 

Lawrenceburg, KY Paducah, KY 

7anuary 15-16, 2008 
Traverse Point Locator Data 

Client Florida Tile, Lawrenceburg, KY 

Site Kiln 6 Cooling Section Vent ~ I~ b 

Calculator Chris Gottschalk Date 1-15-08 n 

Distance from upstream disturbance (d) 113 in 

O 

~ a 

Distance from downstream disturbance (u) 15.5 ft t d 

Outside of port to far side of stack (a), in. 37.5 ~ 

Outside of port to near side of stack (a), in. 0 ~- 

Inside Stack Diameter (a - b), in. 37.5 flow disturbance 

Point # % froin wall to point froin wall to 

point (c) Port length (b) from probe tip to 

point (b + c) 

1 3.2 1.20 0.00 1.20 

2 10.5 3.94 0.00 3.94 

3 19.4 7.28 0.00 7.28 

4 32.3 12.11 0.00 12.11 

5 67.7 25.39 0.00 25.39 

6 80.6 30.23 0.00 30.23 

7 89.5 33.56 0.00 33.56 

8 96.8 36.30 0.00 36.30 

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC 

Lawrenceburg, KY Paducah, KY 

Januaiy 15-16, 2008 
APPENDIX 3 

CALIBRATION DATA 

Florida Tile Industries, Inc., IC'iln 6 Test FBT Enviromilental Services LLC 

Lawrenceburg, KY Paducali, KY 

January 15-16, 2008 
APPENDIX 3 

CALIBRATION DATA 

This appendix contains calibration documentation and describes the specific QA/QC procediures 

einployed by FBT in performing this test. The goal of the QA/QC activities for this project was 

to ensure, to the highest degree possible, the acctiracy of the data collected. The procedures 

contained in the Qicality Assurance Harndboolc for Air Pollution Measzn°enzent Systerns: Voluine I. 

Principles, EPA-60019-76-005, and Volznne III Stationa7y Sozrrces Specific Metbods, EPA600/77-027b are the basis for performance for all testing and related worlc activities. 

CALIBRATION OF APPARATUS 

The preparation and calibration of source sainpling equipment is essential to maintaining data 

quality. Brief descriptions of the calibration procedures used by FBT follow: 

Barometers 

FBT uses aneroid barometers that are calibrated against a National Weather Service-Type 

mercurial barometer. 

Temperature Sensors 

Bimetallic dial thermometers and Type "K" thennocouples are calibrated using the procedure 

described in Section 3.4.2 of the Quality Assurance Handboolc. Each temperathire sensor is 

calibrated over the expected range of use against an ASTM 3C or 3F thennometer. 

Pitot Tubes 

FBT uses Type "S" pitot tubes on sources having significant particulate loadings and on larger 

ducts. These pitot tubes are constructed according to specifications in CFR 40 Part 60, Appendix 

A USEPA, Reference Method 2. Pitot tubes meeting these criteria are assigned a baseline 

coefficient of 0.84 and need not be calibrated. 

FBT uses standard pitot hibes on smaller sources having insignificant particulate loadings. 

These tubes are constructed according to USEPA Reference Method 2 specifications. Pitot tiibes 

meeting these criteria are assigned a baseline coefficient of 0.99 and need not be calibrated. 

Differential Pressure Gaulzes 

FBT uses inclined/vertical manometers to measure differential pressures. These include velocity 

pressures, static pressures, and orifice pressure differentials. Manometers are selected with 

sufficient sensitivity to accurately measure pressures over the entire range of expected values. 

Manometers are leveled and zeroed prior to each run and checiced periodically during the run. 

Manometers are primaiy standards and require no calibration. 

Dry Gas Meters and Orifiees 

Dry gas meters are calibrated using critical orifices as described in USEPA Reference Method 5. 

Before initial use in the field, a metering system is calibrated over the entire range of operation. 

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC 

Lawrenceburg, KY Paducah, KY 

Januaiy 15-16, 2008 
After each field use, the metering system is calibrated at a siiigle intermediate setting based on 

the previous field test. Acceptable difference for pre-test and post-test dry gas meter coefficient 

values is ± 5%. Metering systems are also calibrated using a reference dry gas meter. Reference 

dry gas meters are calibrated using critical orifices. 

Critical orifices used for sample gas flow control are calibrated using a reference wet test meter. 

The reference wet test meter is calibrated using ASTM D 1071. 

Dry gas meters may also be calibrated using critical orifices as described in USEPA Reference 

Method 5. 

ON-SITE MEASUREMENTS 

On-site QA/QC activities included: 

Measurement Sites 

Prior to sampling, all stacic/duct dimensions are measured to determine measurement site 

locations, location of test ports, and stacic inside dimensions. Inside dimensions are checiced 

through all available test ports to ensure uniformity of the stacic cross-sectional area. 

Verification of Absence of Cyclonic Flow 

Some flow disturbances such as cyclones, inertial deinisters, and venturi scrubbers tend to induce 

cyclonic flow. In situations such as these, the presence or absence of cyclonic flow must be 

determined. Prior to testing, FBT conducts an evaluation to identify duct configurations that 

may. induce swirl. If these conditions exist the presence or absence of cyclonic flow must be 

deterinined. A sampling site is acceptable if the average angle of rotation fiom the duct axis 

required to achieve a null pitot reading is less than 20 0 . 

Velocity Measurements 

All velocity measurement apparatus are assembled, leveled, zeroed, and lealc checiced prior to 

each test run. Static pressure is determined at a single point near the center of the stacic. Lealc 

checics are perfonned again, at the end of each run. 

Stacic Gas Component Samplin2 

During test runs gas samples are withdrawn from a single point near the center of each test site 

and analyzed with either a Fyrite combustion gas analyzer or instrumental analyzers to detennine 

percent concentrations of carbon dioxide and oxygen. The sample train is assembled and lealc 

checiced before sainpling. Instrumental analyzers are calibrated with appropriate calibration 

gases. Linearity, system bias, zero and calibration drift, and response time checics are also done 

with these gases. 

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC 

Lawrenceburg, KY Paducah, KY 

January 15-16, 2008 
Moisture 

Stacic gas moisture may be detennined simultaneously with particulate matter. During sampling, 

the gas exiting the silica gel impinger or coluinn is maintained below 68 °F to ensure adequate 

condensation of the stacic gas water vapor. The total moisture is deternnined volumetrically 

and/or gravimetrically. 

Sample Trains 

The sample trains are asseinbled, equilibrated to required teinperahires and lealc checiced before 

testing. The nozzle size is determined in the field by malcing triplicate measurements along three 

different diameters using a dial caliper. The three measurements must vary no more than 0.004 

inches between the higlh and low values. 

At the conclusion of each run, sample trains are lealc checiced at the vacuum specified by the 

respective Method, typically, the highest vacuum attained during the run. Typical acceptable 

lealcage rates are 0.02 cubic feet per minute or 4 percent of the average sampling rate (whichever 

is less), or that specified by the Method used. If appropriate, sainple volume may be adjusted to 

account for excess sample train lealcs. 

Florida Tile Industries, Inc., I{iln 6 Test FBT Envirormlental Services LLC 

Lawrenceburg, KY Paducah, KY 

Januaiy 15-16, 2008 
CRITICAL ORIFICE CALIBRATION 

Reference Wet Test Meter: L/A 04444 

Wet Test Meter I': 1.006 

Pump: Blue/White Thomas-Med 

Pre-Test Calibration: 

Barometric Pressure, Pbar : 29.36 incbes Hg 

Date: 1-8-08 

Rotometer* 

Oririce Q Pin Ori6ce Pout Orifice Vref Tref Pref No.: R-1 Time 

Orifice # (L/min) (in HZO) (in IIg) (L) (°F) (in H2O) L/min O (min) 

0.932 -3.9 -18.6 6.00 68 -0.16 0.7 6.350 

016 0.932 -3.9 -18.6 6.00 68 -0.16 0.7 6.350 

0.932 -3.9 -18.6 6.00 68 -0.16 0.7 6.350 

Average 0.932 -3.9 Pre test Q= new orifice -3.9 

Post-Test Calibration: 

Barometric Pressure, Pbar : 29.42 inches Hg 

Date: 1-23-08 

Rotometer* 

Oritice Qstd Pin Orifice Pout Orifice Vref Tref Pref No.: R-1 Time 

Orifice # (L/min) (in HZ O) (in Hg) (L) ( ° I) (in II20) L/min O (min) 

0.930 -3.9 -19.0 6.00 65 -0.16 0.7 6.417 

016 0.930 -3.9 -19.0 6.00 65 -0.16 0.7 6.417 

0.930 -3.9 -19.0 6.00 65 -0.16 0.7 6.417 

Average 0.930 -3.9 Post test Qstd = 0.933 % diff = 0.3% 

Pre-Post Avg Qstd = 0.931 

Q= I' x Vref x Tstd ( °R) x(Pbar + Pref/13.6) /(Tref ( °R) x Pstd x O) 

Q=17.647 x I' x Vref x(Pbar+ Pref/I3.6) /((Tref ( °F) + 460) x O) 

Where Pstd = 29.92 inclies Hg and Tstd = 68 °F or 528 °R 

Tstd/Pstd = 528/29.92 = 17.647 

Calibration Perforined By: Cluis Gottsclialk 

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC 

Lawrenceburg, KY Paducah, KY 

January 15-16, 2008 
PRE-TEST METER CALIBRATION 

MB #: LL-1 BAROMETRIC PRESS: 29.72 in. hg 

DATE: 10-6-07 DGM PRETEST y: 0.9789 

PLANT: Florida Tile REFERENCE y: 1.0096 

PERFORMED BY: Gottschalk 

RUN 1 RUN 2 RUN 3 

VACUUM ("Hg) 6.00 6.00 6.00 

DGM AH ("H20) 3.00 3.00 3.00 

Reference Pnn ("H20) -4.40 -4.40 -4.40 

Initial Ref. ft3 575.660 581.508 588.342 

Final Ref. ft3 581.508 588.342 594.188 

Initial DGM ft3 104.683 110.855 118.043 

Final DGM ft3 110.855 118.043 124.198 

Ref TM °F 70.0 70.5 71.0 

DGM TM °F 75.5 76.0 77.0 

Time, min: 6.0 7.0 6.0 

Net Reference ft3 = 5.848 6.834 5.846 

Net DGM ft3 = 6.172 7.188 6.155 

I-' = 0.9490 0.9522 0.9521 

% A = -3.1 -2.7 -2.7 

OH@ = 1.767 1.763 1.770 

Pretest I' = 0.9789 

New I' = 0.9511 

% A = -2.8 

Average OH@ = 1.766 

Calculations: 

1' = (Vref x I'ret x (Pbar + Pm + 13.6) x (Td + 460)) = (Vd (Pb + (AH = 13.6)) x (Tref+ 460)) 

OH@ = 0.0317 x OH / Pbar (Td + 460)) x((Tref + 460) x 0 / Vref)2 

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromnental Services LLC 

Lawrenceburg, KY Paducah, KY 

Januaiy 15-16, 2008 
POST-TEST METER CALIBRATION 

MB #: LL-1 BAROMETRIC PRESS: 29.43 in. hg 

DATE: 1-21-08 DGM PRETEST y: 0.9789 

PLANT: Florida Tile REFERENCE y: 1.0096 

PERFORMED BY: Gottschalk 

RUN 1 RUN 2 RUN 3 

VACUUM ("Hg) 4.0 4.0 4.0 

DGM AH ("H20) 1.85 1.85 1.85 

Reference Pnn ("H20) -2.70 -2.70 -2.70 

Initial Ref. ft3 663.128 668.590 674.032 

Final Ref. ft3 668.590 674.032 679.858 

Initial DGM ft3 545.268 550.670 556.071 

Final DGM ft3 550.670 556.071 561.884 

Ref TM °F 41.0 46.0 50.0 

DGM T M °F 38.0 42.0 46.0 

Time, min: 7.0 7.0 7.5 

Net Reference ft3 = 5.462 5.442 5.826 

Net DGM ft3 = 5.402 5.401 5.813 

I, = 1.0032 0.9978 0.9926 

% A = 2.5 1.9 1.4 

AH@ = 1.650 1.682 1.698 

Pretest r = 0.9789 

New r = 0.9979 

% 0 = 1.9 

Average OH@ = 1.676 

Calculations: 

I' = (Vref x i'ref x (Pbar + Pm = 13.6) x (Td + 460)) = (Vd (Pb + (AH = 13.6)) x (Tref + 460)) 

AH@ = 0.0317 x AH / Pbar (Td + 460)) x((Tref + 460) x 0 / Vref)2 

Florida Tile Indtistries, Inc., Kiln 6 Test FBT Enviromnental Services LLC 

Lawrenceburg, ICY Paducah, ICY 

Januaiy 15-16, 2008 
APPENDIX 4 

ANALYTICAL DATA 

Florida Tile Industries, Inc., IGIn 6 Test FBT Enviromnental Services LLC 

Lawrenceburg, KY Padticah, KY 

7anuary 15-16, 2008 
DA 

CHEM E.E."F LABOiLATORIES. INrTest Pepc)rt-_ 

P ,a E-1 1 c, f 2 

1•28/08 

Suhmitted '_'o: C.'hris Gottschalk 

FET F_'nv -ironmental Services LLC 

6860 Ston ~ poir-jc C QI_jrt 

.Paducah, KY 

4 4' Q 0 13 

R6ference IData: 

Sample Locatium: 

Sample Type: 

Client samnle No. 

P0 

Methad •cference: 

Sample Set IDJ": 

DATACHEM Lab No.: 

Datc- Poceived: 

Prepar- ation Da ~;e: 

Analysis Date: 

Hydrogan Fluorida 

Kiln 6, 1.1 1orida l'i-le, Lai•ircriceburcl, KY 

R-K! through Blank 

10 9,15 

EPA Mothod 26 

08-L-0255 

08-0151'1 ttirough H-01521' 

0 1 / 2 '11/ 'C,8 

0-1 /22/06 

01/22/08 

Sampl.c. condition wap acceptaL-.)J,c uplon re,-ce.ipt except ',%rhere nctc!d, 

Analysis Iads completed on a Diancx 1(.7 2000 Ion Chromatograph 

clilipped ait!-L a Dionex ASIB-AGIS column aiicl zi conductance detector. 

Compound idenu-1-fication is based upcdi-i rettent,!.ofi ti-me matching 

oiilv. Any compound wUh a similar re•ention time 14il' Ante2ff,2x.--_, . 

The r'cSUlts arc provided i-n Lhc- enc- losed dafa t.lble. E?'e S LJ4 I t a 

relate only ito the Llems tested aiici' arc not blank cnrrected. 

1`rds rei-_-crt shall not be- roproduced except in full, wi-tl -iouL the 

writteti L:pprova.[ cif 'che labaral'.or,/. 

J.'j, 

Trent !,ack 

4 ~kn_ ~ 1YSI*. ~i~~~._`..~_. v

r vieweZl 

CINC;NNATI CPFICF 

'381.1 r 3LENDALE-MILF(IRD ROAD 

CIPXMNATI. OHIO <5242-3796 

Sl 9 735•5335, FAX 513 732-5347 

lhtST COAST OFFICE 

11 SANTA YOFWA COtJRT 

NOVAI'O, CALWORMA 94945 

500 2,10-807 1. FAN 415 89341169 

Florida Tile Industries, Inc., Kiln 6 Test FBT Environrnental Scivices LLC 

Lawrenceburg, ICY Padi-icah, KY 

Jaiiiialy 15-16, 2008 
Tp-s, l: Fcpo-,- t 

Page 2 c1f, 2 

Sample TD: 08-L-0255 

Data Table 

Hydrogen Fluoride 

Cli-ent ID Lab ID Impinger 

Volume(ML) 

racj / s amp 10 mg/sample 

Duplicate 

R ,-[,;j t) 8 15 -1- 7 C.-, -1— 0.91 --- 0 .`9"6 — 

R-'K2 iD Ei - 0 1511 8 1 S6. 1.3 1.3 

R - 08-01519 48, 0.59 0.99 

8 - 0 15 2 Cl 40. 0.15 0.15 

r', - C" 2 08-01521 O.063 

R - C-2 08-01622 4 r. 1.1 D 

B ], ar) k (J8-01.523 tdlJ ND 

EQL 0 . C) El 

NI) i.mcdi.cutv`t: analytc,was not dctc ~ ctc--d nt or abovc - tho c`;timaLo 

.L inii-t (EQT.) . 

- 

f 

Tirc'n(: Rac 

Analyst 

Florida Tile Industries, Inc., ICIn 6 Test FBT Enviroi-niiental Selvices LLC 

Lawrenceburg, KY Paducah, KY 

Jaiiiialy 15-16, 2008 
ANALYTfCAL REQUEST SL 

CHAJN OF CUSTODY 

FI3T L;nvironmental Serwices LLC: LAttORr1TORY 

6860 StouepointCourt DatnCliem l.,at,aratories 

Yadacnh. KY 42003 4385 Cilendale-N-lilford Road 

(270) 89$-fi7S2 Fax:(270) 898!)694 Cincinnuti, (_7hio 45242-37(Ki 

ClA'iE&mPPBD POF$f.hiPLE& ti:.MP113TYPB 1 1 I:qFE,1T 11441dES+TlUIvfL'01 

1 7 liquids Kiln 6 

Florida'I'ile -- t;011 UA:rnt-rrr.i<sraN 

1065 Chris C3ottscl3alk Lawrencebur•r„ 1:Y 

1. AnulVre per USE['A ReFcrenee Nleiliod 26r^. tt+r 1I1" as nnteLt. j?Rl{)RlTY SAn•tPLE 

N-teasurc antt r4P ~ rrsnmplc volunms. I.l:T1.1RT~ 

~~ ~ ~~ 

~ ~ vrn<na: L ~ xt str K.r.taxc. izusx 1'ES Nf) 

~ 

x 

SAbiPLE # SAA•1PL,E CC)N'1'All\'E12 r1vALYSES i~ F'QLIITZI3L} 

77ATE DFSCRIT'TION 

Stj(:~R-K1 Impingrcr samples hCF nfl via USEI'A 26 

t51 ~ IZ-K2 in 8 oz Liottles 

CJ ~~i2UR-Cl 

~z1R-C3 

l5L3t3ltuiTt 

CCIAIN C3F CUSTC}DY RF,QUEST 

S;aMPl-Es DEL,tVERED BY: U.S. n•IAII-, _ rr1)1:a/(JPS x Cour.IH. _ OTrER_, 

I'URPo41: Ft;Nt 

CUST03:)Y CF1Alv'G6 

~ KGiLINC?111S1-IEI) 13Y: 

(S1GN,~'1•URH) 

RECEIVI;D f3Y: 

(SIGN:ITURi;) 

1-17-05 Analysis 

_. _. 

Florida Tile Indtistries,.Inc., Kiln 6 Test FBT Enviromnental Services LLC 

LawrenceUurg, KY Paducah, KY 

January 15-16, 2008 
Calibration Error Test at Run 1. STRATA Version 1.2.1 

Operator: Chris Gottschalk 

Plant Name: Florida Tile 

Location: Lawrenceburg, KY 

Reference Cylinder Numbers 

Zero Low-range Mid-range High-range 

CO N2 CC58793 CC92028 

Date/Time 1/15/2008 

Analyte CO 

Units ppm 

Zero Ref Cyl 0 

Zero Avg -0.13 

Zero Error% 0.1 

Low Ref Cyl 80.6 

Low Avg ' 80.82 

Low Error% 0.1 

Mid Ref Cyl 200 

Mid Avg 200.6 

Mid Error% 0.3 

High Ref Cyl 

High Avg 

High Error°/a 

7:07:00 PASSED 

Initial System Bias Check for Run 1. STRATA Version 1.2.1 

Operator: Chris Gottschalk 

Plant Name: Florida Tile 

Location: Lawrenceburg, KY 

Reference Cylinder Numbers 

Zero Span 

CO N2 CC92028 

Date/Time 1/15/2008 7:11:27 PASSED 

Analyte CO 

Units ppm 

Zero Ref Cyl 0 

Zero Cal -0.13 

Zero Avg -0.31 

Zero Bias% 0.1 

Zero Drift% 

Span Ref Cyl 200 

Span Cal 200.6 

Span Avg 200.59 

Span Bias% 0 

Span Drift% 

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC 

Lawrenceburg, KY Paducah, KY 

January 15-16, 2008 
Test Run 1 Begin. STRATA Version 1.2.1 

Operator: Chris Gottschalk 

Plant Nami Florida Tile 

Location: Lawrenceburg, KY 

CO CO 

ppm ppm 

1/15/2008 12:29:58 61.08 1115/2008 13:14:02 54.7 

1/15/2008 12:29:59 61.34 1/15/2008 13:15:02 55 

1/15/2008 12:30:00 61.85 1/15/2008 13:16:02 55.41 

Begin calculating run averages 1/15/2008 13:17:02 55.28 

1/15/2008 12:31:02 63.06 1/15/2008 13:18:01 55.37 

1/15/2008 12:32:01 61.22 1/15/2008 13:19:02 55.84 

1/1512008 12:33:02 57.81 1/15/2008 13:20:01 55.03 

1/15/2008 12:34:02 55.62 1/1512008 13:21:02 55.03 

1/15/2008 12:35:02 55.79 1/15/2008 13:22:01 55.23 

1/15/2008 12:36:02 54.9 1/15/2008 13:23:02 55.41 

1/15/2008 12:37:01 54.82 1/15/2008 13:24:01 54.78 

1/15/2008 12:38:02 55.06 1/15/2008 13:25:02 54.14 

1/15/2008 12:39:01 55.91 1/15/2008 13:26:02 52.58 

1/15/2008 12:40:02 55.04 1/15/2008 13:27:01 52.49 

1/15/2008 12:41:02 56.14 1/15/2008 13:28:02 53.32 

1/15/2008 12:42:02 56.61 1/15/2008 13:29:02 53.85 

1/15/2008 12:43:02 57.68 1/15/2008 13:30:02 54.1 

1/15/2008 12:44:01 55.77 Average of Test Run CO 

1/15/2008 12:45:02 55.43 ppm 

1/1512008 12:46:01 55.49 1/15/2008 13:30:02 56.12 

1/15/2008 12:47:02 56.75 Test Run 1 End 

1/15/2008 12:48:02 58.24 

1 /15/2008 12:49:01 58.49 

1/15/2008 12:50:02 58.66 Final System Bias Check for Run 1. STRATA Version 1.2.1 

1/15/2008 12:51:01 58.94 Operator: Chris Gottschalk 

1/15/2008 12:52:02 58.2 Plant Name: Florida Tile 

1/15/2008 12:53:02 57.28 Location: Lawrenceburg, KY 

1/15/2008 12:54:02 56.73 Reference Cylinder Numbers 

1/15/2008 12:55:02 57.51 Zero Span 

1/15/2008 12:56:01 57.26 CO N2 CC92028 

1/15/2008 12:57:02 54.07 

1/15/2008 12:58:01 54.24 Date/Time 1/15/2008 13:39:43 PASSED 

1/15/2008 12:59:02 54.5 Analyte CO 

1/15/2008 13:00:02 56.14 Units ppm 

1/15/2008 13:01:01 57.68 Zero Ref Cyl 0 

1/15/2008 13:02:02 58.42 Zero Cal -0.13 

1/15/2008 13:03:01 58.24 Zero Avg -0.78 

1/15/2008 13:04:02 58.01 Zero Bias% 0.3 

1/15/2008 13:05:02 '57.85 Zero Drift% -0.2 

1/15/2008 13:06:01 56.89 Span Ref Cyl 200 

1/15/2008 13:07:02 56.7 Span Cal 200.6 

1/15/2008 13:08:01 56.13 Span Avg 194.99 

1/15/2008 13:09:02 55.75 Span Bias% 2.8 

1/15/2008 13:10:02 55.21 Span Drift% -2.8 

1/15/2008 13:11:02 55.38 

1/15/2008 13:12:02 54.84 Ini Zero Avg -0.31 

1/15/2008 13:13:01 54.89 Ini Span Avg 200.59 

Run Avg 56.12 

Co -0.54 

Cm 197.79 

Correct Avg 57.13 

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviromilental Services LLC 

Lawrenceburg, ICY Paducah, KY 

7anuaiy 15-16, 2008 
Test Run 2 Begin. STRATA Version 1.2.1 

Operator: Chris Gottschalk 

Plant Nam( Florida Tile 

Location: Lawrenceburg, KY 

CO CO 

ppm ppm 

1/15/2008 13:46:43 2.48 1/15/2008 14:33:02 55.7 

1/15/2008 13:47:43 12.03 1/15/2008 14:34:02 63.26 

1/15/2008 13:48:43 51.8 1/15/2008 14:35:02 69.45 

Begin calculating run averages 1/15/2008 14:36:02 68.75 

1/15/2008 13:50:02 55.59 1/15/2008 14:37:03 64.28 

1/15/2008 13:51:02 55.78 1/15/2008 14:38:02 63.44 

1/15/2008 13:52:03 55.39 1/15/2008 14:39:03 63.48 

1/15/2008 13:53:02 55.13 1/15/2008. 14:40:02 62.99 

1/15/2008 13:54:02 55.25 1/15/2008 14:41:02 59.51 

1/15/2008 13:55:02 55.3 1/15/2008 14:42:02 58.11 

1/15/2008 13:56:02 55.8 1/15/2008 14:43:02 58.36 

1/15/2008 13:57:03 55.65 1/15/2008 14:44:03 58.36 

1/15/2008 13:58:02 56.01 1/15/2008 14:45:02 59.25 

1/15/2008 13:59:03 56.16 1/15/2008 14:46:02 59.55 

1/15/2008 14:00:02 54.93 1/15/2008 14:47:02 59.36 

1/15/2008 14:01:02 54.88 1/15/2008 14:48:03 58.99 

1/15/2008 14:02:02 53.8 1/15/2008 14:49:02 58.69 

1/15/2008 14:03:02 53.5 Average of Test Run CO 

1/15/2008 14:04:03 54.18 ppm 

1/15/2008 14:05:02 55.38 1/15/2008 14:49:02 55.39 

1/15/2008 14:06:02 56.9 Test Run 2 End 

1/15/2008 14:07:02 57.65 

1/15/2008 14:08:03 58.14 

1/15/2008 14:09:02 58.24 Final System Bias Check for Run 2. STRATA Version 1.2.1 

1/15/2008 14:10:02 58.91 Operator: Chris Gottschalk 

1/15/2008 14:11:02 57.47 Plant Name: Florida Tile 

1/15/2008 14:12:02 53.72 Location: Lawrenceburg, KY 

1/15/2008 14:13:03 50.98 Reference Cylinder Numbers 

1/15/2008 14:14:02 50.48 Zero Span 

1/15/2008 14:15:03 53.1 CO N2 CC92028 

1/15/2008 14:16:02 55.34 

1/15/2008 14:17:02 58 Date/Time 1/15/2008 14:57:19 PASSED 

1/15/2008 14:18:02 59.47 Analyte CO 

1/15/2008 14:19:02 60.16 Units ppm 

1/15/2008 14:20:03 59.8 Zero Ref Cyl 0 

1/15/2008 14:21:02 59.54 Zero Cal -0.13 

1/15/2008 14:22:02 58.85 Zero Avg 0.06 

1/15/2008 14:23:02 57.28 Zero Bias% 0.1 

1/15/2008 14:24:02 56.21 Zero Drift°/a 0.4 

1/15/2008 14:25:03 56.55 Span Ref Cyl 200 

1/15/2008 14:26:02 56.47 Span Cal 200.6 

1/15/2008 14:27:03 47.67 Span Avg 194.1 

1/15/2008 14:28:02 31.54 Span Bias% 3.3 

1/15/2008 14:29:02 24.51 Span Drift% -0.4 

1/15/2008 14:30:02 25.27 

1/15/2008 14:31:02 33.93 Ini Zero Avg -0.78 

1/15/2008 14:32:03 42.92 Ini Span Avg 194.99 

Run Avg 55.39 

Co -0.36 

Cm 194.54 

Correct Avg 57.21 

Florida Tile Industries, Inc., Kiln 6 Test FBT Enviroiunental Services LLC 

Lawrenceburg, KY Paducah, KY 

January 15-16, 2008 
Test Run 3 Begin. STRATA Version 1.2.1 

Operator: Chris Gottschalk 

Plant Nami Florida Tile 

Location: Lawrenceburg, KY 

CO CO 

ppm ppm 

1/15/2008 15:03:19 55.13 1/15/2008 15:50:04 56.74 

1/15/2008 15:04:19 56.13 1/15/2008 15:51:04 56.91 

1/15/2008 15:05:19 56.17 1/15/2008 15:52:04 56.45 

Begin calculating run averages 1/15/2008 15:53:03 56.18 

1/15/2008 15:07:04 56.63 1/15/2008 15:54:04 56.15 

1/15/2008 15:08:03 57.07 1/15/2008 15:55:04 42.39 

1/15/2008 15:09:04 56.16 1/15/2008 15:56:04 27.56 

1/15/2008 15:10:04 54.5 1/15/2008 15:57:03 32.47 

1/15/2008 15:11:04 54.06 1/15/2008 15:58:04 39.85 

1/15/2008 15:12:04 54.13 1/15/2008 15:59:04 49.01 

1/15/2008 15:13:03 54.81 1/15/2008 16:00:04 60.57 

1/15/2008 15:14:04 55.77 1/15/2008 16:01:04 62.63 

1/15/2008 15:15:03 56.15 1/15/2008 16:02:03 61.34 

1/15/2008 15:16:04 56.7 1/15/2008 16:03:04 61.87 

1/15/2008 15:17:04 56.64 1/15/2008 16:04:04 62.02 

1/15/2008 15:18:03 56.68 1/15/2008 16:05:04 61.72 

1/15/2008 15:19:04 56.91 1/15/2008 16:06:04 61.04 

1/15/2008 15:20:03 56.53 Average of Test Run CO 

1/15/2008 15:21:04 56.64 ppm 

1/15/2008 15:22:04 56.71 1/15/2008 16:06:04 54.57 

1/15/2008 15:23:04 56.51 Test Run 3 End 

1/15/2008 15:24:03 56.37 

1/15/2008 15:25:04 56.38 

1/15/2008 15:26:04 56.05 Final System Bias Check for Run 3. STRATA Version 1.2.1 

1/15/2008 15:27:04 56.27 Operator: Chris Gottschalk 

1/15/2008 15:28:04 56.14 Plant Name: Florida Tile 

1/15/2008 15:29:03 56.19 Location: Lawrenceburg, KY 

1/15/2008 15:30:04 56.19 Reference Cylinder Numbers 

1/15/2008 15:31:03 56.15 Zero Span 

1/15/2008 15:32:04 55.77 CO N2 CC92028 

1/15/2008 15:33:04 56.17 

1/15/2008 15:34:04 55.44 Date/Time 1/15/2008 16:20:42 PASSED 

1/15/2008 15:35:04 52.51 Analyte CO 

1/15/2008 15:36:03 49.29 Units ppm 

1/15/2008 15:37:04 47.51 Zero Ref Cyl 0 

1/15/2008 15:38:04 46.34 Zero Cal -0.13 

1/15/2008 15:39:04 46.95 Zero Avg -1.63 

1/15/2008 15:40:04 46.04 Zero Bias% 0.8 

1/15/2008 15:41:03 47.21 Zero Drift% -0.8 

1/15/2008 15:42:04 50.26 Span Ref Cyl 200 

1/15/2008 15:43:04 54 Span Cal 200.6 

1/15/2008 15:44:04 57.12 Span Avg 192.11 

1/15/2008 15:45:04 60.83 Span Bias% 4.2 

1/15/2008 15:46:03 62.46 Span Drift% -1 

1/1/2008 15:47:04 61.46 

1/15/2008 15:48:04 59.9 Ini Zero Avg 0.06 

1/15/2008 15:49:04 57.5 Ini Span Avg 194.1 

Run Avg 54.57 

Co -0.79 

Cm 193.11 

Correct Avg 57.1 

Flor'ida Tile Industries, Inc., Kiln 6 Test FBT Enviroiunental Services LLC 

Lawrenceburg, KY Paducah, KY 

January 15-16, 2008 
APPENDIX 5 

PROCESS DATA 

Florida Tile Industries, Inc., Kiln 6 Test FBT Environmental Services LLC 

Lawrenceburg, KY Paducah, KY 

Januaiy 15-16, 2009 
Jan 15, 2008: 

Time 

12:30 - 13:30 

13:45 - 14:45 

15:00 - 16:00 

Average 

Heating section 

temps Range 

1206 C 1205 - 1208 C 

1208 C 1207 - 1209 C 

1207 C 1205 - 1208 C 

Average 

Cooling section 

temps Range 

179C 179-180C 

180C 179-180C 

180C 179 - 181 C 

Volume of 

materials 

through Kiln 

12:30 - 13:30 10609 Ibs 

13:45 - 14:45 10130.4 Ibs 

15:00 - 16:00 10904.4 Ibs 

The Kiln temps are computer controlled. The set point is 1206. The average temps for 

the dates requested are as follows; 

16 Jan '08 

8:30 — 9:30 1207 

9:45 — 10:45 1206 

11:00 — 12:00 1206 

Mike J. 

Florida Tile Industries, Inc., Kiln 6 Test FBT Envirormlental Services LLC 

Lawrenceburg, KY Paducah, KY 

January 15-16, 2008