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NBS TECHNICAL NOTE 653

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*"*CA U O* *
NATIONAL BUREAU OF STANDARDS

The National Bureau of Standards 1 was established by an act of Congress March 3, 1901. The Bureau's overall goal is to strengthen and advance the Nation's science and technology

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Gut;;;.! t;-f -^# :,:-''

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Wk

(6C

The Thermophysical Properties

of Methane, from 90 to 500 K at

Pressures to 700 Bar

R. D. Goodwin

Cryogenics Division

Institute tor Basic Standards

US. National Bureau of Standards

Boulder, Colorado 80302

•'•tAU O* *

U.S. DEPARTMENT OF COMMERCE, Frederick B. Dent. Secretary

NATIONAL BUREAU OF STANDARDS. Richard W Roberts. Director
National Bureau of Standards Technical Note 653

Nat. Bur. Sland. (U.S.). Tech. !Nole 640, 280 pages (April 1974)

CODEN: !NBT!\AK

For sale by ihe Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402

(Order by SI) Catalogue No.C 13.46:653). 82.25
CONTENTS

Page

1. INTRODUCTION 1

2. PHYSICAL PROPERTIES AND THEIR REPRESENTATION 3

2. 1 Fixed -Point Constants 3

2. 2 Melting Line and Vapor Pressures 3 2.3 The Orthobaric Densities 4 2.4 The Virial Equation 6

2. 5 The Equation of State 6 2.6 Representation of C (T) at 18.5 mol/t 8

3. COMPUTATIONAL METHODS 9

3.1 The Homogeneous Domain 9

3. 2 The Vapor-Liquid Transition 10

3.3 Representation of E (T) and S (T) 11 a a 3.4 Circumventing the Critical Domain 12

4. COMPARISON OF DERIVED AND EXPERIMENTAL PROPERTIES 12

4. 1 Heats of Vaporization 12

4.2 Specific Heats C (T), C (p , T), C (p , T) 13

4.3 Speeds of Sound W (T), W(p,T) 13 a

5. TABLES OF PHYSICAL AND THERMODYNAMIC PROPERTIES 13

5. 1 Calculated P-p-T Isochores and Isotherms 13

5. 2 The Joule -Thomson Inversion Locus 14

5.3 Thermophysical Properties of the Saturated Liquid 14

5.4 Thermophysical Properties Along Selected Isobars 14

6. TABLES IN BRITISH ENGINEERING UNITS 14

7. COMMENTS ON UNCERTAINTIES 14

8. ACKNOWLEDGMENTS 15

9. REFERENCES 1&
Appendix A,

Appendix B,

Appendix C.

Appendix D,

Appendix E.

Figure 1

Table 1-A

Table 1-B

Table 1-C

Table 2-A

Table 2-B

Table 3. Table 4. Table 5. Table 6. Table 7. Table 8. Table 9. Table 10

Table 11 Table 12

Table 13

Table 14

Table 15

Table 16

Table 17

CONTENTS (continued)

Symbols and Units

Fixed-Point Values

Conversion of Units

List of new Data

Computer Programs

LIST OF FIGURES

Density-temperature phase diagram

LIST OF TABLES

The saturated vapor densities

The saturated liquid densities

The vapor-liquid saturation temperatures

The second virial coefficient

The third virial coefficient

Summary of P-P-T data

Comparison of experimental and calculated P-p-T values

Comparison of specific heats for saturated liquid ....

Comparison of specific heats, C (P,T)

Comparison of specific heats, C (P,T)

ir Comparison of speeds of sound for saturated liquid . . . Comparison of speeds of sound, W(p, T)

Calculated P(T) isochores

Calculated P(p) isotherms

The Joule-Thomson inversion locus

Thermophysical properties of the saturated liquid ....

Thermophysical properties along isobars

The Joule-Thomson inversion locus

Thermophysical properties of the saturated liquid ....

Thermophysical properties along isobars

21

22

23

24

25

42

43

45

46

49

50

51

52

79

80

85

87

88

90

117

134

135

137

205

206

209

: Tables in British engineering units
ABSTRACT

Thermophysical properties of methane are tabulated at uniform temperatures from 90.68 to 500 K along isobars to 700 bar. A novel equation of state is employed for the first time, having origin on the vapor-liquid coexistence boundary.

Computations are based almost entirely on ideal gas specific heats and experimental P- p-T data via the equation of state, without weighting to data for derived

properties. Good agreement with such data confirms validity of the equation and

method. New P- P-T data are reported at 0.3 to 1.7 times the critical density.

Key words: Densities; enthalpies; entropies; equation of state; internal energies;

isobars; isochores; isotherms; Joule-Thomson inversion; latent heats of vaporization; melting line; orthobaric densities; PVT data; specific heats; speeds of sound;

vapor pressures

.

1. INTRODUCTION

Methane is the major component of natural gas, and hence of great economic

importance. For the processes of liquefaction, separation, storage, pumping, transport

and custodial transfer there is required a knowledge of physical and thermodynamic properties. For mixtures, some properties can be approximated by those of pure methane.

For computations on the properties of LNG mixtures, the dominant thermodynamic data

required again are those of methane . In the following work it is possible to test the thermodynamic computations against experimental data for specific heats, heats of vaporization,

and speeds of sound available over wider ranges than for other components of LNG . Some

of the experimental data obtained here on methane, for example the saturated liquid densities,

also have been useful to others for calibrating experimental apparatus.

Extreme accuracy is needed in physical and thermodynamic properties data for

engineering plant design, as demonstrated recently by Zudkevitch [73] . Two monographs

on methane [61, 72] show, however, that low temperature data necessary for thermal

computations either are non-existent or are inaccurate. In view of the importance of the lowtemperature, liquid states of methane and natural gas, our objective has been to supply the

needed properties data directly by experiment, and then to produce a set of self-consistent

tables of thermodynamic functions over the entire range of fluid states

.

* This work was carried out at the National Bureau of Standards under sponsorship of The

American Gas Association.
This report culminates three years of work in acquiring available physical properties data, in performing experimental measurements, and in formulating these data for

use in thermal computations. Nearly all of these formulations are new: designed to be

consistent with critical-point behavior. Where appropriate, they are constrained both at

the triple point and at the critical point for consistency in the derived thermodynamic

network . New physical properties data which we have measured or derived are listed in

Appendix D

.

Our new equation of state is a contribution to the present task . An outstanding

feature is that it originates on the vapor-liquid coexistence boundary, thus eliminating

the long-standing problem of consistency between equations of state and this independentlyderived locus. The equation also is consistent with the nonanalytic behavior of C ( ,T)

about the critical point. It has only nine coefficients to be found by least squares from

experimental P- p -T data, and these will be similar for most simple substances [30] . As

compared with equations which employ a much greater number of arbitrary coefficients, we

believe the present form to be advantageous for thermal computations because the derivatives,

2 2 SP/9T, 9 P/dT , and dP/oO are more likely to be simple, monotonic functions of the independent variables, as demonstrated below by computed tabulations. We believe that a

proper behavior of these derivatives is more important than the mere "representation" of

experimental P-p-T data. In particular, experimental data from different laboratories often

must be used which are not accurate, as proven by their lack of consistency. An equation

of state with excess freedom then is most likely to give serious irregularities in the derivatives . As a reward for minimizing the number of arbitrary coefficients, we find in the present

work that derived properties such as specific heats and speeds of sound, calculated "a priori"

via the equation of state, do agree with experimental data within combined uncertainties,

without any weighting of the equation of state to such data. This accomplishment, we believe,

never before has been realized. It suggests that where such data do not exist experimentally,

they might be estimated with some reliability via the present type of equation of state.

Symbols and units of this report are given in Appendix A. Temperatures are on the

kelvin scale of IPTS-1968 [l] . Pressures are related to the International System by use

of the bar, 1 bar = 10 Newton/square meter [ 3] . For the engineer we have computed
tables in British engineering units at integral pressures in psi and integral temperatures

on the Fahrenheit scale . The conversion of units is given in Appendix C . Deviations in

this report are expressed uniformly as the departure of an experimental value, Y, from

the smooth function for a calculated value, Y n , in the form for relative deviation

calc

in percent, 100 • (Y-Y j )/Y .

2. PHYSICAL PROPERTIES AND THEIR REPRESENTATION

2 . 1 Fixed-Point Constants

Selected values for the triple- and critical-point constants are listed in Appendix B .

The triple-point temperature and pressure are from our vapor-pressure equation [52 ]. The

liquid density is an extrapolation of our accurate, saturated liquid densities [30] to the

triple-point temperature. The vapor density is given by eq (4-c) of this report.

The critical-point temperature is from an analysis of dielectric constants by Verbeke [68

The pressure is given by the vapor-pressure equation (3) below. The density is selected within

the uncertainty in [68] to minimize the mean of relative pressure deviations via the present

equation of state

.

2.2 Melting Line and Vapor Pressures

These pressures P(T) are reported in [52] , where they are compared with other

data. Melting pressures are formulated by the Simon equation

P/P

t = 1 + A • [(T/Tt ) G - 1] , (1)

with constants e = 1.85, A = 16,259.1. The precision is better than 0.1 percent in pressure [ 52 ]

.

Densities of the freezing liquid were obtained at three points to a maximum pressure of 220 bar at intersections of our experimental isochores with the melting line, as reported in [23] . They are represented within the precision of 0.02% in density by our simple

expression

(d/d

t ) = (T/Tt

) 1/4

. (2)
Our recent vapor pressure measurements are compared with other data in [52] . Our

vapor pressure equation (3) is adjusted for the value of T in the present report. Define

the argument x(T) = (1-T./T)/(1-T,/T ), when the equation is

t t c

£n(P/P ) = a- x + b- x

2 + c- x

3 + d- x- (1 -x)

3/2

(3)

a = 4.7774 8580, c = -0 . 5678 8894,

b = 1.7606 5363, d = 1.3278 6231.

The rms deviation for 103 points is 0.014%.

2.3 The Orthobaric Densities

The data were reviewed in [26]. We now have omitted data near the critical point in

finding coefficients for the fitting functions, equations 4-a, 4-b, 4-c , because these data are

least accurate, and the fitting functions in the critical region are influenced only slightly by

these data. We include all data, however, in the comparison tables 1-A, 1-B , 1-C. Identifications in these tables are: ID = 1 for vapor densities obtained from the virial and vapor pressure

equations [ 23]; ID = 1 for liquid densities obtained from our isochore intersections with the

vapor pressure equation [30]; ID = 2 for vapor densities via the virial equation of this report;

ID = 5 for data of Jansoone et al. [ 39]; ID = 6 for data derived via Ricci et al . [ 53]; and ID = 7

for privately-communicated data of O . B . Verbeke [68] Some of the latter data are assigned

two temperatures, differing by 0.02 K, due to uncertainties between different laboratories.

Identifications given by three or four digits are for densities via our dielectric constant measurements [ 29].

a) For the saturated vapor, define the variables —

X (T) = (T -T)/(T -T), u(T) = (T /T-1)/(T /T.-l) . C C t C C l

The function now is—

e 4/3 5/3 £n(p/o)=a-x +b-x+c-x +d«x +e-x-u, (4-a)

c

e = 0.46, c = -8.657 3409,

a = -2.703 6003, d= 5.264 0362,

b = 3.166 1552, e = -3.526 9034.

The comparisons are given in table 1-A .
b) For the saturated liquid we use x(T) as defined above, and also,

2/3 4/3 2 W(x) = a.(l-x )+b-(l-x ) + c.(l-x ),

in a function which is constrained both at the triple- and at the critical-points --

(p-p )/(p -p ) = x

e .exp[W(x)J , (4-b)

e = 0.36, b = 0.0483 8475,

a = -0.1788 6OI65, c - -0.0184 8987.

The comparisons are given in table 1-B.

c) The single-valued function T (p), given by eq (4-c), is used for the equation

of state. Densities are obtained by iteration, using eqs (4-a) and (4-b) only to find the

initial density. Define the variables.

Y(T ) = (T /T -1)/(T /T -1), a c o c t

U(cr) s expj^e-a- (a-a )/|a-l|J ,

10

1/3 2/3 V"^ a i- 4 W(p) = A + A^-tnfp) + A

3 -p + A

4 /(l+E-p ) + / , A - " P i=5

where a = d /d is a constant, s = 1/2, and E = 8. The function now has the simple form,

t t c

Y(T

a

) = U(a) • [l + (p-l) • W(p)] (4 _ c)

Aj = 0.8432 0686,

A = 0. 1597 2304,

A = 0.9783 7869

A4

= 0. 2865 4081

A5 =-1.7150 5402,

The comparisons are given in table 1-C.

The exponential form, U(ct), used for T (p) in eq (4-c) was developed to give a well-behaved critical isotherm (non-negative slopes, BP/9p) for all reasonable assignments

(within the experimental uncertainties) of the critical point (p , T ) in the equation of state (6! c c Whereas the thermal computations circumvent this near-critical region, the equation of state is tied to the saturation boundary described as a function of density by eqs

(4-c) and (3). This may be the reason that we find the greatest deviations from experimental P-p-T data along isochores near the critical density, table 4.

A

6

= 10. 8869 3606,

A?

= -32. 4204 8700

A8

= 63. 1616 6459,

A

9

= -62. 7209 242,

A 10 = 25. Q249 8181.
2.4 The Virial Equation

For the virial equation of state,

2 Pv/RT = 1 + B(T)-a + C(T)-a +... (5)

the second and third coefficients, B(T) and C(T), here are dimensionless via reduced density, a = d/d . We reduce the temperature, x = T/T , at the triple point. Sources of

c t selected data in Tables 2-A, 2-B are: ID1 = Douslin [17], ID2 = Hoover [37], ID3 = Byrne [8], ID4 = Pope [51], and ID5 = Sengers [56]. The virial coefficients are formulated

by completely new functions as follows,

B(T) = [B + B

2 /x

1/2 + B

3 /x + B

4

/x + B /x ]

• f(x) (5-a)

where

1/4

f(x) = 1 - (T IT)

o

T = o B l =

505.

16

K,

974 318,

B 2

= -80 055 038,

B

3

= 123. 540 958,

B4

=: -92. 601 354,

B 5

: 42. 974 121.

The third virial coefficient is represented by

C(T) =[c

i /x 1/2 + C

2 /x

2 + C

3 /x

4 + C

4 /x ]

• f(x), (5-b)

where

f(x) = 1 - T

o /T,

c

l = 36 212, c 2

= .83 584,

T = 139.922K,

o

C - 18.69 531,

C4

= 9. 15 517.

In the above equations we have defined the arguments, (1/x) , such that they have a maximum value of unity at the triple point. We therefore may keep the same number of

decimal digits in all of the least-squares coefficients. In this way one may ascertain that

the constants given here contain more than a sufficient number of digits for the precision

of data in tables 2-A and 2-B.

2. 5 The Equation of State

Experimental compressibility (P-p-T) data are given in various ranges by several

publications [9, 1 7, 30, 3 2, 39, 41 , 44, 49, 54, 65, 66, 72] . Michels 1 data [49] are reviewed by

Douslin [17]. Compressed liquid data of van Itterbeek [65], as well as those found in the

monograph by Zagoruchenko [72], appear to be of lower accuracy than needed for thermal

computations

.
Data reproduced in the present report are summarized by table 3. For adjusting our equation of state we have used only three sets of data: 1) as computed by our virial

equation; 2) our published data [30] and our new data given in this report; and 3) the data

of Douslin et al. f 1 Tl

The present equation of state is novel in that it originates on the vapor-liquid

coexistence boundary. The melting line, however, is not a part of this equation of state.

It must be introduced independently.

By means of our function T (p), eqn (4-c), we obtain the vapor-liquid coexistence

temperature for any density (isochore). Placing this in the vapor-pressure equation gives

the coexistence pressure P [T (p)]. This defines the equation of state as a function of

density on the vapor-liquid coexistence boundary. By subtraction we shift the origin to

this boundary.

This novel equation of state may be written in concise form by use of the variables,

x(T) = T/T , x (p) = T (p)/T , C 0" 0" C

Y(P,p,T)= (Z-l)-x/p, Y (p)= (Z -l)-x /p , a a o as follows

(6)

(Y-Y ) = B(p)-X, (p,T) + C(p)-X (P.T) + D(p)-X (p,T),

a b c a where B(p), C(p), D(p) are polynomial coefficients to be found by least squares, and the

X.(p, T) are functions both of density and temperature as a consequence of subtracting the

values at coexistence,

X

b(p,T)s x.[l-exp(-p&)]- x

G .[l-exp(-p/xCT )] ,

X (p, T) = 1/x - 1/x , c a

X,(P, T) = [l-uu -tn( 1+1 /a))]/ u - Fl-u) "tn(l+l/(B )~|/u . d L JLa aJa

The last of these functions gives nonanalytic behavior for C (p, T) about the v

critical point by use of the variables,

u(p,T) = T/6(p) , u)(P,T) = 6-(u-l) ,

u (p) =T (P)/6(p) , id (p) = 5.( U -1) , a a o a

where 6 is an arbitrary constant, 6(p) is our locus of temperatures [18] inside the "dome"

of figure 1

7
(p) = T

ct (d) • exp

I -a . | a - 1 | 3 ] ,

and T (p) is given by eq (4-c) above. As described also in [26, 30], this is an empirical

equation which is qualitatively consistent with the experimental behavior of C (p, T)

about the critical point.

The coefficients of (6) result from tedious investigations of various combinations

of polynomials,

B(p) = B + B • p, o 1 C(p) s C + C • p + C • p + C_ • p 3

, o 1 L 5 D(p) = (CT-1) • (D + D • p + D • p 2

). o 1 d. For application of the least squares technique, each of the above polynomials is multiplied

throughout by its temperature-dependent factor, X.(p,T) from eqn (6), to give nine leastsquares coefficients.

The constants for eq (6) are

a = 0.2, 3 = 7, & = 1,

C

2

= -22. 5567 15826,

12. 2896 65719,

D = o

0. 9937 50233,

D =

1 -1. 2430 35021,

D

2

= 0. 3185 23715.

B = 1. 5991 01971,

o B = 2.4837 86733,

C = -1.0760 88156,

o C = 10.4821 92754,

Table 4 gives a comparison of the experimental and calculated densities and

pressures. The reader should note that op/?T and op/SP become infinite at the critical

point. Density deviations therefore should be ignored in the critical region 0. 95 < T/T < 1. 1 For compressed liquid at low temperatures the derivative oP/Sp becomes extremely large,

such that small experimental errors in density -will yield (via the equation of state) deviations of calculated pressures greatly exceeding the accuracy of pressure measurements.

In this domain the equation of state should be used only to find p(P, T).

2. 6 Representation of C (T) at 18. 5 mol/i

v For use below in 3. 4 we have adjusted experimental specific heats of several runs

by Younglove [71] to the density of 18. 5 mol/jj, and then have represented these data by use of the argument, x(T) = T/9(p), 9 = 164. 1171 K:

8
C /C° = 1 + a/x + b/x2 + c/x

3 /(x-l)°- \ (7) V V

a = 0. 472 950, b = -0. 502 717, c = 0. 214 2134

where C (T) is the ideal gas specific heat as tabulated in [21], and as calculated by our SUBROUTINE IDEAL reproduced in Appendix E.

3. COMPUTATIONAL METHODS

The numerical values for E and H in this report are on the same absolute basis

as those of Tester [61], obtained by use of E° = (4. 1868)- (2191 . 3) J/mol. This not only

permits a direct comparison of results; it also precludes negative values for these functions

in compressed liquid states.

3.1 The Homogeneous Domain

With reference to figure 1, we start our computations with ideal gas values described in T21] as a function of temperature at zero density, and then integrate along isotherms by use of the equation of state in the following relations,

AE=y [p _ T-OP/oT)] .dp/p

2

, (8)

AC

v

= -t7*(S P/oT 2 )-dp/p

2

, (9)

AS = R.<e,n[p°/(pRT)]+y [R-(oP/oT)/p] • dp /p . (10)

Equation (10) is for use with initial entropies in hypothetical ideal gas states at P° = 1 atm.

In the compressed liquid at T< T we use

c

AS = -/(Bp/9T).dp/p

2 (10-a)

In each (p, T) state, reached by above integrations, we compute

H = E + P/p , (11)

C =C + T-(oP/BT)

2 /(9p/op)/p , (12) P VW = C .(oP/Sp)/C . (13)

p v
3.2 The Vapor-Liquid Transition

At T< T of figure 1 we traverse the vapor-to-liquid "dome" by use of the Clapeyrc

equation, and Av = (v -v ), AH = T. (dP/dT). Av , (14)

AE = AH - P- Av , (15)

AS = AH/T (16)

where (dP/dT) is slope of the vapor pressure curve. We then obtain the specific heat of

liquid along the coexistence path via

C (T) = T-(dS /dT) . (17) a o The single-phase specific heats C (P,T) maybe estimated on the saturated liquid boundary

from the following difference [55] ,

C (p,T) = C (T) + T.(oP/3T).(dp ,/dT)/p

2

, (18) v cr i, *j

where (dp, /dT) is the (negative) slope of saturated liquid density vs T. Each term on

the right of (18) approaches infinity at the critical point, where the accuracy of computation

vanishes. For this and other reasons we have computed around the critical point, by use of

experimental C data at 18.5 mol/t, as discussed below for the cross-hatched region

v

of figure 1 .

10
3.3 Representation of E (T) and S (T) r a a Having computed these functions for saturated liquid, we give them analytical

representations to avoid repetitive integrations. The following representations are accurate

within 0.001% at any point, and each gives an rms deviation less than 0.0005% for 52 points at T < T^ T . For consistency in the thermal network we compute C (T) by eq (17), above.

For internal energy, use these variables

x(T) = (T -T)/(T -T ) , c c t

Y(E) = (E-E

t )/(E

c -E

t

) ,

9 . ,

e «-^ . i-2

W(x) sA -x.-tnd+B/x) + A -x + Va.-x

i=3

when the function is

B = 0. 10,

e = 0. 19,

E =

t 3471. 853,

E = c 10819. 568,

Y(E) = (l-x).exp[W(x)] , (19)

-9.7180 4579,

17. 1576 6593,

• 16.5038 8861,

7. 7926 2156,

-1.3662 1087.

A =

1 -0.0294 0994, A5 A2

= -01915 4778, A6 A3

= -0.6745 4649, A7 A4

^ 3. 1155 4755, A8 AQ For the entropy, define x(T) as above, and also

Y(S) = (S-S

t)/(Sc -S

t

).

e 1/2 V^ i-2

W(x) = A .x.-tn(l+l/x) + A„-x + A -x + > A.-x

i=4

when the function is

Y(S) = (l-x)-exp[W(x)] , (20)

e = 0.19,

St = 67.87 832,

S c

= 120.46 263,

A 1 = -0. 1566 0939,

A2

= -0. 1727 1532,

A3- 0. 0687 0234,

A4

= 1. 6874 3215,

A5 = -5. 3312 1801,

A6

= 9. 0640 7137,

A7

= -7 5434 7331,

A8

= 2 4352 9834.

11
3.4 Circumventing the Critical Domain

The computations of section 3 become inaccurate along isotherms near T . As

c T-^T" the heats of vaporization become increasingly uncertain, and the accuracy obtained C + from eq (18) vanishes. As T-* T the slopes and curvatures of isochores are insufficiently

well known to give reliable results. We therefore have used the following procedure to compute around the critical point into the cross-hatched region of figure 1: We select the isochore of experimental specific heats at p

' = 18.5 mol/X, which

intersects the liquid-vapor boundary at T = 174.516 K. We then select T = 220 K oba b

taining - -

E(p', T ) = 9874.3 J/mol, S(p', T ) = 113. 912 J/mol/K.

d b By use of (7) for C (p', T) we then integrate down to any T < T< T , v a b

.T T

AE f C

v .dT, AS ==// C -dT/T

T, 'T

v

We finally integrate along isotherm T as described among eqs (8) through (13). For the

cross-hatched region of figure 1 we thus obtain all of the thermofunctions without crossing

the "dome" near T , and without passing close to the critical point at T> T . c c

In the above computation around the critical point (on isotherm T and then along

isochore p of figure 1) we wish, for consistency, to obtain values of functions for the

saturated liquid at T which agree with values obtained by computing across the vapora

liquid "dome" on isotherm T To obtain agreement for the internal energy, E, and for a

the entropy, S, it is necessary to multiply the specific heats along isochore p , eq (7), by

the factor 0. 9737. This adjustment of about 2. 6% is larger than the estimated uncertainty

in experimental, single-phase specific heats T71]. One must remember, however, that

until recently it was considered by many that specific heats computed via the second de2 2 rivative 9 P/3T from an equation of state were "good" if they were within 10% of the

experimental measurements.

4. COMPARISON OF DERIVED AND EXPERIMENTAL PROPERTIES

4. 1 Heats of Vaporization

This property is notoriously difficult to measure accurately, and results from

two laboratories are not in good agreement [36, 70]. Their data have been tabulated in [21],

Present results agree best with those of Hestermans and White [36], namely within about

12
two percent at worst (high temperature). At 100 K our heat of vaporization of 8512 J/mol

is in excellent agreement with the experimental value, 8514 ± Zl J/mol, obtained by

Cutler and Morrison [11].

4. 2 Specific Heats, C (T), C (p, T), C (p, T)

CT V p

Specific heats C (T) on the coexistence path have been derived from heat capacitymeasurements on the two-phase, liquid-vapor system by use of existing vapor pressure

and saturated liquid density data [71]. Results therefore are not directly experimental,

and may have greater uncertainty than the observations [31]. These recent data of

Younglove are compared with our derived results in table 5. The maximum deviations

between calculated and measured C (T) are about two percent. Cutler and Morrison [111 a give specific heats of the saturated liquid from 93. 95 to 106. 96 K. Our calculated value

of 53. 31 J/mol/K at 95. 85 K may be compared with 54. 13 from [71], and with 53. 43 at

95. 77 K from [11].

Experimental specific heats C (p, T) for compressed fluid methane [71] are compared with our derived results in table 6. The maximum deviations between calculated and

measured C (p, T) are about four percent.

Specific heats at constant pressure C (p, T) have been measured with a flowP calorimeter over a wide range of conditions. These data are smoothed and interpolated [40].

Table 7 gives these data on the first row of each isotherm. The second row was computed by

present methods. Except near the critical point the maximum deviations between calculated

and measured C (p, T) are about two percent, which we consider to be excellent.

P

4. 3 Speeds of Sound, W (T), W(p, T)

Tables 8 and 9 compare experimental speeds of sound for saturated [63] and compressed liquid [64] methane with our calculated results. In eqn (13) of section 3, above,

we have seen that this calculation is complicated. It is based on all previous calculations

via the derived specific heats. In view of this complexity, we consider that the agreement

within two percent between calculated and measured speeds of sound is good, and supports

our use of the present, simple form of equation of state.

5. TABLES OF PHYSICAL AND THERMODYNAMIC PROPERTIES

5. 1 Calculated P-p-T Isochores and Isotherms

A selection of calculated isochores and isotherms is given by tables 10 and 11. They are useful to examine behavior of the surface generated by the equation of state, and

to supplement the isobars of table 14 in obtaining P-p-T values and their derivatives.

Table 11 includes derivatives with respect to density of functions composing the equation

of state, to verify that the analytical expressions used for these derivatives are correct.

13
5. 2 The Joule -Thorns on Inversion Locus

Tables 12 and 15 give our calculated P-o-T locus for the J. T. Inversion,

(9T/5P) = 0. These results are obtained from the equation of state under the condition, H

T- (SP/9T) - p • (oP/op). They are in good agreement with earlier results [24, 61],

considering sensitivity of the computation and engineering requirements.

5. 3 Thermophysical Properties of the Saturated Liquid

Tables 13 and 16 give physical and thermodynamic properties for the saturated

liquid. Column headings are interpreted on the first pages of these tables. Results are

similar to our earlier tabulation [24] except at T > 160 K where the effect of our recently

measured vapor densities is evident. Saturated vapor volumes and heats of vaporization are smaller than in [24] by up to 1. 5 percent as T -> T . At temperatures above T = c a

174. 5 1 6 K, however, we have computed around the critical point as described in section

3. 4.

5. 4 Thermophysical Properties Along Selected Isobars

Tables 14 and 17 give physical and thermodynamic properties on isobars, as computed by methods of section 3. Explanations for the tables are given on the first pages.

These tables are extrapolated beyond the range of P-p-T data used for adjusting the equation

of state (T ~ 400 K, P ~ 350 bar).

6. TABLES IN BRITISH ENGINEERING UNITS

Thermophysical properties in engineering units are given in tables 15, 16, and

17 at integral temperatures on the Fahrenheit scale and at integral pressures in psi. The

conversions of units, given in Appendix C, are taken from [3, 48]. Explanations for the

tables are given on the first page of each table.

7. COMMENTS ON UNCERTAINTIES

For the important saturated liquid densities, the precision of about 0. 01% in

representation by eq (4-b) greatly exceeds the estimated absolute accuracy of about 0. 1%

in the data.

For other P-p-T data, the differences between calculated and experimental values are detailed by table 4. Greatest experimental uncertainties of about 0. 1% occur in the

determination of density. Deviations of table 4 are no greater than 0. 1% over most of

the P-p-T surface. Approaching the critical point, however, they become much greater

(up to about 1. 0%) over the critical region: 0. 9 < T/T < 1. 2, 0. 3 < p/p < 1. 7. The

c c equation of state (6), however, is qualitatively correct in the behavior of its derivatives

about the critical point. We may generalize by the statement that the densities of table 14

(isobars) are accurate to 0. 1% except in the critical region.

14
The absolute accuracy of thermodynamic functions, computed by equations of

section 3, necessarily is less than that of P-p-T data, due to the use of derivatives of

the P-p-T surface, and especially to taking differences, eq (8). This fact, mentioned

in [22], places extreme demands on the equation of state. The accuracy of enthalpy

differences is estimated by comparing our specific heats at constant pressure with

experimental data in table 7. Except very close to the critical point (190. 5 K, 46. bar),

the differences mostly are no greater than 2%. With this exception, therefore, we

estimate the accuracy of enthalpy differences in table 14 (isobars) to be about 2%.

The experimental specific heats C from [71] were estimated to be accurate to

0. 5%, except approaching the critical point. For the saturated liquid, however, we

mentioned above that other data used to derive C (T) could produce higher uncertainty.

a Table 5 shows maximum deviations of about 2% near 145 K. We estimate the accuracy

of our calculated C (T) to be 1%. Excepting the critical region, we estimate the accuracy

of our calculated C (p , T) to be about 3%, and of C (p,T) to be about 2%. v ' p

The experimental speeds of sound were estimated to be accurate to a few tenths

of one percent [63, 64]. As our results in tables 8, 9 differ by a maximum of about 2%, we conclude that calculated values in table 14 (isobars) have an accuracy of 2%.

8. ACKNOWLEDGMENTS

We are indebted to The American Gas Association for generous support of this

work, to Robert D McCarty for the essential least-squares program [38, 47], and to Dwain

E. Diller and Lloyd A. Weber for discussions and valuable suggestions.

15
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18
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20
Appendix A. Symbols and Units

Subscripts c and t refer to critical and liquid triple points.

Subscripts g and £ refer to saturated vapor and liquid.

Subscripts a or s refer to liquid-vapor coexistence (usually the liquid).

01, 3,6 non-linear constants in the equation of state B, C, D, density-dependent coefficients in the equation of state C (p ,T), molal heat capacity at constant volume, J/(mol-K)

C (p , T), molal heat capacity at constant pressure, J/(mol'K)

p

CCT (T), molal heat capacity for saturated liquid, J/(mol*K)

d, density, mol/-t

E(p, T), the internal energy, J/mol

H(p,T), the enthalpy, J/mol

J, the joule, 1 N-m,

I, the liter, 10 _3m3

, mol, 16.043 grams of methane (C =12 scale)

5 2 P, pressure in bars, 1 bar = 10 N/m

Q , AH , the heat of vaporization, J/mol

vap vap

R, the gas constant, 8. 31434 J/(mol* K),

0.0831434 bar--L/(mol-K),

p, d/d. density reduced at the liquid triple point

a, d/d density reduced at the critical point

S(p,T), the entropy, J/(mol-K)

T, temperature, K, on the IPTS-1968, [1]

v, 1/d, molal volume, -t/mol

W(p,T), the speed of sound, meters /second

x, T/T , temperature reduced at the critical point

Z, Pv/RT, the "compressibility factor"

21
Appendix B. Fixsd-Point Values

Triple Point

d = 0.01567865 raol/l, vapor

d = 28. 1470 mol/t, liquid

P = 0. 11590 atm

= 0. 117435675 bar

T = 90.680 K (IPTS-1968)

Critical Point

d = 10.0 mol/X

c P = 45.98825 bar

c T - 190.555 K (IPTS-1968)

c

These values were used for the thermodynamic computations

exactly as given.

22
Temperature,

Pressure,

Volume,

Mol. Wt., CH ., 4

Mass,

Appendix C. Conversion of Units

Reference [3]

1.8 Rankine (R) = 1 Kelvin, (K)

14. 69595 psi = 1 atm = 1. 01325 bar

1 cu ft = 28. 31685 liter, (I)

1 mol = 16.043 gram, (g), (CT

_ scalej

1 lb (avoir. ) = 453. 5924 g

12

Density, CH,,

Isochore slope,

Isotherm slope, CH,,

1 lb/cu ft

1 PSI/R

1 PSI-cu ft/lb

0. 998 470 mol/-l

0. 1241 056 bar/K

0.0690 5319 bar.-L/mol

Energy 1 BTU

Specific energy for methane, 1 BTU/lb

Specific entropy and heat

capacity for methane,

Speed of sound,

1 (BTU/lb)/R

1 ft/s

1054. 350 joule, (J)

37. 291 055 J/mol

67. 123 912 (J/mol)/K

0. 30480 m/s

23
Appendix D. List of New Data

1. The melting pressures, [52].

2. The vapor pressures. [52]

3. Freezing liquid densities, [23].

4. Saturated liquid densities, [30].

5. Saturated vapor densities, [29].

6. P-p-T compressibility data [30].

7. P-P-T compressibility data [this report].

8. Dielectric constants on isotherms [29],

9. Dielectric constants for saturated liquid [29].

10. Dielectric constants for saturated vapor [29].

11. Specific heats C (T) for saturated liquid [71].

1 2. Specific heats C (P , T) over a wide range [ 71]

24
Appendix E. Computer Programs

05/14/73

PROGRAM METHERM5

C COMPUTE METHANE THERMOFUNCTIONS, JANUARY, 1973.

COMMON B1,B2, C1,C2, Z3,0+, E1,£2,E3

C0MM0N/1/AG,AL,BE, JE,GK, DCRT , PCRT , TORT , DTRP, PTRP, TTRP

COMMON/3/DP0T,02P0T2,DPSJT,DPMDT,DPDD,DPOR,DTSDR,0THDR

COMMON/8/ P,T,0EN, E,H,S, CV,CP,k, WK

COMMON/9/ CSAT

C0MM0N/99/TI,£ZZ, EZ,SZ,3VZ,HZ,CPZ

DIMENSION PP(99) ,CF(99) ,CY(99)

1 F0RMATU7, F9.3, 55X F3.3)

2 FORMATdHl 1/X COMPARISON OF METHANE CSAT, J/MOL/K * //

1 18X 2HID 7X3HT,< aX+HCSAf tX^HCALC bX<+HPCNT)

3 F0RMATd5X 15, 3F1J.3, F10.2)

k F0RMAT(2X 13F6.0)

5 FORMAT(IX)

6 F0RMATd5, F8.G, 15X F9.0, Frf.G, FO.O)

7 FORMATdHl 17X *COMPARIS3N OF MlTHANE CV, J/MOL/K * //

1 18X 2HI0 7X3HT,K 5X5HP,3AR 5X5HM0L/L 4XbHC,XPTL hX6HC,CALC

2 6X-+HPCNT)

8 F0RMAT(15X 15, 5F10.3, F1C.2)

9 FORMATdHl <»<+X ^COMPARISONS OF CP(J/MOL/K) FOR METHANE* //

1 13X 7HP.BAR = 13F8.2/ 1JX hHT , K ) 10 FORMATdHO 9X F1J.3, 13F3.2)

11 FORMAT(20X 13F8.2)

12 FORMATdHl 16X COMPARISON, SPEEDS OF SOUNC, SATURATED LIQUID METH

1ANE*//17X3HT,< 5X5HP,8AR 5X5HM0L/L 5X5HM/3EC 5X5HCALCD fcX<+HPCNT)

13 FORMATdHl 15X COMPARISON, SP>_iD5 OF SOUND, COMPRESSED LI0.UID MET

1HANE*//17X3HT,K 5X5H?,3A* 5X5HHQL/L 5X5HM/SEG 5X5HCALCD oX^HPCNT)

It* FORMATdCX FlO-2, 2F10.3, 2F10.1, Flu. 2)

15 FORMAT(bFlQ.u)

16 FORMAd//////// 1H1 18X METHANE ISOBAR AT P =*F6.1, + H 9AR//

1 19X 1HT 6X3HDEN 6X3HVOL 5X;»HDP/DT 5XSHQP/DD 8X1HE 8X1HH 8X1HS

2 oX2HCV 6X2HCP 5X1HW /

3 15X 5HDEG K 4X5HM0L/L XSHL/MOL 5X5HBAR/K 1 X9HB AR- L/ MOL <+X5HJ/MOL

« *X5HJ/M0L 2X7HJ/M0L/K 1X7HJ/M0L/K 1X7HJ/MOL/K 1X5HM/SEC ) 17 FORMATdflX F10.3, F9.3, -9. 5, F1C.H, F10.3, 2F9 . 1 ,F9 . 3 , 2F6. 2 ,Fu . ) 18 FORMATdCX FlO.3, F9.5, F9.3, F1C.6, Flu. 3, 2F9. 1 , F9. 3 , 2F8. 2 ,F6 . > C

C CONSTANTS OF EQNSTATe-8, 5/11/73, AT 10. h6, NF = 9.

C NOTE ARBITRARY CONSTANT, OE , IN PSI, XEF(T,D).

20 TTRP = 9J.b80 i DTRP = 23.W7 » PTRP ^u . 1 17 4356 75

21 TCRT=190.555 % DCRT=1G.G) I PCRT=P3ATF (TCRT

)

22 AG=AL=a«2 * BE=7 % OZ=l £ GKK= 0. 16 31*3H % GK=DTRP^GKK

23 Bi = 1.599101971 B 62 = 2.-»8378b733 I CI = -1. 760 88156

24 C2 = 10.48219275-* J 33 = -2 2.556 715826 T Ck - 12 ..289665719

25 El = 0.9937502^3 i tZ - - 1

2-+3C 35C 21 I E3 = C. 313523713

28 OP=l. 01325 $ EZZ=4. 1865*2191. 3 J WK = 10 GQOO /lb. 043

29 QPP = 14.69595/QP $ TA = 174.516 S TB = 22C

C

C DERIVE THE J-T INVERSION }URVE,

99 CALL JTLOCUS

C TABULATE THE SATURATED LI }UIO FUNCTIONS.

100 CALL TABLIQ

CC COMPUTE THERMOFUNCTIONS O'l ISOBARS -

25
METHERM5 05/l<+/73

C EVERY ISOBAR STARTS OM TH

C ISOBARS AT P UNDER PC*T T C SPECIAL CASES FOR REGION

C LET THE FIRST IS03AR )E A li*9 NI = 67 $ PP(1) = °TRP

150 READ 15, (PP(I) ,1=2,^1)

151 00 300 1=1, NI $ P = PP

152 CALL MELTHERM $ 7 = 1/

153 PRINT 17, T,DEN,7, OPDT,

15** IT = T/5 S IFtP.LT.PCR

I MELTING LINE AT T UNDER TCRT.

<A7ERSc THE DOME.

X AT TA=T=T8, DEN ABOVE DCRT.

T P = PTRP.

(I) $ PRINT 16f P OEN

DPOD, E,H,S, C7,CP,W

T) 155,200

CASES FOR P LLSS THAN PCR

155 TS = FINDTSF(P) % TX = 156 DO 199 J=l,99 $ T = JT

157 IF(T.LT.TA) 158,175

NORMAL CASES FO« P UNDER

158 If(T.LT.TS) 159,161

CASE FOR COMPRESSED LIQJI

159 CALL THRMOLIQ $ 7=1/

lbC PRINT 17, T,DEN,7, OPDT,

151 IF(T.LT.TX) 152,183

CASE FOR SATURATED LliUIO

162 IF(I.EQ.i) 163, lo** 163 PRINT 5 $ GO TO 165

16*» CALL SATLQTRM $ 7=1/

165 PRINT 17, T,DEN,\/, OPDT,

166 CALL SATGSTRM $ 7=1/

167 IFCP.LT.20.0) 163,169

168 PRINT 18, T,DEN,V, D

;D DT,

169 PRINT 17, T,DEN,V, D-^DT,

170 T = JT * GO TO 133

CASES FOR P UNDER PCRT , T 175 IF(T.LT.TS) 176,17d

CASE FOR COMPR. LIQ. AT T 176 CALL THERMOX * V = I/O

177 PRINT 17, T,DEN,7, OPDT,

178 IF(T.LT.TX) 179,183

CASE FOR SAT.lIU. IN *E5I

179 CALL THERMXL S 7 = I/O

160 PRINT 17, T,DEN,7, D=»DT,

181 CALL SATGSTRM J 7=1/

162 PRINT 17, T,0EN,7, DPDT,

CASES FOR HOMOGENEOUS DOM

183 IF(JT-3J0) 188,188,13'+

16i+ K = K+l S 185 IF(JT-<+GG)

186 L = L+l $

187 IFUT-500)

188 CALL THRMOGAS S 169 IF (P.i.T.20.0) 19U,

190 PRINT 18, T,DEN,7,

191 PRINT 17, T,OEN,7,

199 CONTINUE

f = JT = JT 168,188,136

T = JT = JT

188, 138, 3J0

7 = 1/

191

OPDT,

DPDT,

r.TS+5 i K = L =

= 3*(IT+J)

PCRT, T UNOtR TA.

D AT T UNDER TA.

DEN

DPDD, E,h,S, CV,CP,H i GO TO 199

AND VAPCR.

DEN

OPOD, E,H,5, C7,CP,W t PRINT E JEN

DPDD, E,H,S, C7,CP,W J GO TO 170

J POD, E,H,S, C7,CP,W

07ER TA, IN REGION X.

A = T = TSAT IN REGION X. £N

DPDD, E,H,S, C7,CP,W S GO TO 199

ON X, ANC SAT. 7AP0R.

EN

)PDD, E,H,S, CV,CP,W 8 PRINT 5 JEN

DPDD, E,H,S, CV,CP,W 1 T = JT

UN, D UNDER DG, OR T 07ER TC

t 5*K

* 1G*L

DEN

DPDO, E,H,S, C7,CP,W f GO TO 199

DPUO, E,H,S, C7,CP,W

CASES FOR P GRtATER THAN ^CRT.

26
METHERM5 05/1A/73

200 <=L = £ 00 230 J=l,99 $ T= JT=5 * ( IT+ J ) $ IF(T.LT.TB) 201,220

201 IF(T.LT.TA) 202,205

202 CALL THKMOLIQ $ \l = 1/DEN

2U3 PRINT 17, T,OEN,V, DPDT,DPOD, E,H,S, CV,CP,W $ GO TO 230

2J5 IF(T.LT.TCRT) 211,206

206 PX = PVTF(T,OCRT) S IF(P.GT.PX)' 211,223

CASE FOR REGION X AT TA = T = TB, P ABOVE CRITICAL ISOCHORE.

211 C4LL THERMOX Si V - i/OEN

212 PRINT 17, T,0EN,V, OPDT,JPOO, E,H,S, CV,CP,W $ GO TO 230

CASES FOR HOMOGENEOUS DOMAIN, D UNDER DG, Ok T OVER TC.

220 IFUT-300) 225,225, ?21

221 K = K*l $ T = JT = JT 5*K

222 IF(JT-<+00> 225,225,223

223 L = L*l $ T = JT = JT f 10*L

22* IF(JT-500) 225,225,3JL

225 CALL THRMOGAS $ V = 1/ OEN

226 PRINT 17, T,OEN,V, DPGT,0P3D, E,H,S, CV,CP,I*

230 CONTINUE

300 CONTINUE

999 STOP $ END

SUBROUTINE JTLOCUS

UERIVE THE J-T INVERSION ^URVE. USE ROUTINE DEL T AF ( T , DI )

DIMENSION TTC99) ,PPU9> ,3N(99)

OATA (OCRT = 10.C) , ( TCRT=1 90

555)

1 F0RMAT(1H1 loX *THE JOUl-I- THOMSON INVERSION LOCUS FOR METHANE*//

1 17X3HT,K 5X5HP,BAR ?X5Hl0i_/L 7X3H1,K 5X5HP,BAR 5X5HMOL/L)

2 F0RMAT(1CX F10.U, 2F10.2, F10.Q, 2F1C.2)

9 PRINT 1 $ 00 25 1 = 1,68 5 T- = 155 5*1 * OX = 1.6

10 01 = DCRT*(2.7G816 - 0.

J263* T/TCRT > i IF(T-TCRT) 11,12,12

11 OL = OENLIQF(T) $ IF(OI-Dl) 25,12,12

12 SS = DELTAF(T,DI)

13 00 20 IT=1,15

H* D=OI-DX J SL=0ELTAF(T,3) f D=DI+l"1X S SP =CELT AF ( T , 0)

15 IF(SS-SL) 16, lb, Id

16 IF(SP-SL) 19,17,17

17 SS = Si. J 01 = 01 - OX $ GO TO 20

18 IF(SS-SP) 20,20,19

19 SS = SP J 01 = 01 + OX

20 OX = OX/2 * = JI t P = PVTF(T,0>

21 IF(T-TCRT) 22,23,23

22 PS = PSATF(T) $ IF(P-PS) 25,23,23

23 TT(I)=T i PP(I)=P K ON(I)=0

25 CONTINUE

2fc 00 29 J = l,3<+

29 PRINT 2, TT( J) ,PP< J) , ON ( J) , TT < J + 3<+) , PP ( J + 3k ) , CN ( J+ 3k)

30 RETURN £ END

FUNCTION DELTAF(T,0)

GET (T*OP/QT - 0*OP/JJ) FDR THE J-T INVERSION CURVE.

COMMON/ 3/OPQ T, D2 PD T2, OPS JT, 0PM DT,OPOD, DP OR, DTSO*,OTHDR

DATA <OCRT=10. 0) , ( TCRT=1 90 . 555

)

1 IF(T-TCRT) Zjk,k

2 OL = DENLIOF(T) S EF(O-DL) 3 , <+ , <

3 OELTAF = 1.0E+010 * RETURN

< p = PVTF(T,D) $ PX = OPDRF(T,D)

5 OELTAF = A3SF(T*DP0T-D*DPD0) * RETURN S END

27
05/1^/73

SUBROUTINE TABLIQ

TABULATE THE SATURATED

COMMON/ 1/ AG f AL,BE,OE,

C0MM0N/3/DPDT,02PDT2,

COMMON/8/ P,T,OEN, E,

COMMON/9/ CSAT

1 FORMATdHl 13X *PROPE

2 FORMATdUXlHT 7X1HP 5

1 3X6HD0L/DT 3X;>HQ,VAP

2 10X5HDEG K 5X3H3AR 3 3 2X7HMOL/L/K 3X5HJ/M3

5 1X7HJ/MOL/K 1X7HJ/M3

3 F0RiAT(7X 3F8.3, F9.-+

9 TA = 17H.516 S PRIM

10 DO 30 J=l,52 $ IF(J

11 TT = TTRP $ GO TO 1 12 IF(J.EQ.52) 13, lh

13 TT=TCRT $ DG=DL=DCR

1U TT = 88 + 2*J

15 DG = FINDSATF(TT,0)

16 OL = FINDSATF<TT,1)

17 PS = PSATF(TT) S Q

18 IF(TT.LT.TA) 19,21

19 S = SSATF(TT) $ E ^ 20 GO TO 23

21 P = PS $ CALL THER1

22 OGLDT=CSAT=CV=CP=W=0

23 PX=PVTF (TT,DL) J PX 2k CV = CSAT + 100*TT*OP

25 CP = CV + 10G*TT/DP3O

2b W = SQRTF(WK*CP*OPOD/

30 PRINT 3, TT,PS,DL, \/G,

99 RETURN $ END

LI1UID FUNCTIONS.

G<, DCRT,PCRT,TCRT, OTRP, PTRP, TTRP

DPSJT,DPMDT,OPOO,DPDR,OTSDR,DTHDR

H , S , C V , C P , W , WK

RTIES OF SATURATED LIQUID METHANE* / ) X3H0EN ^Xi>HV,GAS <*X5HV,LIQ 3X5H0P/DT

7X1HE 7X1HH 7X1HS 6X2HCV cX2HCS 6X2HCP6X1HW/

X5H-10L/L <+X5HL/MOL <+X5HL/M0L 3X5HBAR/K

L 3X5HJ/MOL 3X5HJ/MOL 1X7HJ/M0L/K

L/< 1X7HJ/MOL/K 2X5HM/SFC )

, F3.5, F6.<4, F9.«t, 3F8.1, F8.3, 3F8.2, F/.Q)

T 1 i PRINT 2 •EQ.l) 11,12

c.

VG=VL=l/OG GO TO 17

% VG = 1/DG

I VL = 1/UL

= 130*TT*DPSDT* (VG-VL)

ESATF(TT) H + 1GC*PS*VL

XL $ IF(J.EQ.52) 22,23

$ GO TO 30

=DPDRF (TT,DL) S OULDT = DTRP/DTSDR

Dr*DDLOT/DL**2

*(0P0T/0L)**2

CV)

VL, DPSOT,DDLDT, Q,E,H,S, CV,CSAT,CP,W

FUNCTION FINDTMF(P)

GIVEN MELTING PRESSURE P, ITERATE T TO MINIMIZE (P-PC).

COMMON/ 3/DPOT, 02PDT2 , DPS 3T , DPMOT , DPQD , DPDR

,

OTSDR , DTHDR

FORMATdHO 9X *FINOTMF = 0,

T = 100 S DO 6 J=l,50 4 IF(ADP/P-1.0E-6) 7,7,k

IF(AOP/DPMDT/T-1.0E-o) 7,7,5

T = T DP/DPMUT

CONTINUE $ FINOTMF =0 S

FAILS TO CONVERGE)

OP = P-PMELTF(T) J

/ ) AOP = AtfSF (OP)

FINOTMF = T RETURN

PRINT 1 $ END

RETURN

FUNCTION FINOTSF (P)

GIVEN VAPOR PRESSURE P, ITERATE T TO MINIMIZE (P-PC).

COMMON/l/AG,AL,BE,OE,G<, OCkT , PCRT , TCRT , OTRP, PTRP, TTRP

C0MM0N/3/UPDT,D2PDT2,DPSDT,DPM0T,0PDJ,DP0R,DTSDR,0THDR

12

3

56

789

10

11

12

FORMATdHO

FORMATdHO

IF(P-PCRT)

T = 150 $

IF(ADP/P-1.

0,

0,

9X 'FINOTSF

9X *FIN0T5F

,11,12

00 9 J=l,50

Ol-6) 13,10,6

IF (AOP/DPSDT/T-l.OE-o) 13,10,7

T = T + DP/DPSDT £ IF(T-TCRT)

T = TCRT

CONTINUE $ FINOTSF = J FINOTSF = T $ RETURN

FINOTSF = TCRT $ RETJRN

FINOTSF = $ PRINT 2 i

FAILS

P oXC:

TO CONVERGF

EDS PCRT. *

/

/ )

)

$ OP = P - PSATF(T) I AOP = ABSF(OP)

9,9

PRINT 1 RETURN

RETURN S END

28
05/l<t/73

kZ

k3

123<

5

6

789

10

11

12

13

1<* 15

16

17

18

19

20

21

22

23

Zk

25

26

27

26

30

31

32

33

Sk

FUNCTION FI

ON ISOTHERM

COMMON/1/AG

C0MM0N/3/0P

FORMATdHO

FORMATdHG

FORMATdHO

OM = OTRPM

OG=FINUSATF

= OG/2 $

D = (DL+DM)

OG=OL=DCRT

= OCRT/2

= 2»0CRT

IF(T.LT.3Q0

PC = PVTFd

= DCRT

00 30 J = l,5

IF(OPOO) 3k

DO = OP/OPO

= 00

= 0.001

IF(D.GT.DM)

= OTRP S IF (T-TCRT)

IF(P.LT.PS)

IF(D.GT.OG)

= DG $

IF(O.LT.DL)

D = OL I IFCP.LT.PCR

IF(D.LT.DCR

= DCRT - IFU.GT.DCR

= OCRT +

NDENF(T,P)

T, FIND DEN, MOL/L, TO MINIMIZE (P-PC) VIA EQNSTATE.

,AL,6E,U£,G<, DCRT, PORT, TCRT, DTRP, PTPP, TTRP

0T,02PDT2,DPS:)T,UPMDT,DPDD,DP0R,0TSDR,DTHDR

9X »FINO£iMF = C, FAILS TO CONVERGE. * / ) 9X 'FINDEMF = DCRT, DF/DR ZERO OR NEG. * / ) 9X *FINDEMF = 0, U0U8LE-VALUE0 AT P = PSAT. * / ) T/TTRP)**G. 25 $ IF(T-TCRT) 2,5,8

(T,G) J DL=FI JDSATF(T,1)

GO TO 11

% PS = PSATF (T>« IF(P-PS) 3,32,^

/2

$

$

.0)

$ GO TO

PS=PCRT

GO TO 11

GO TO 11

9,10

11

£ IF(P-PS) c,33,7

DCRT) IF(F-PC) 6,33,7

CONTINUE

FINDENF = FINDENF = FINDENF = FINDENF =

$ DP = P-OPOR<r <T,0) * IF<ABSF(OP/P)-1.0£-6) 31,31,12

f 3k, 13

D $ IF (ABSF (DD/0)-l.lJE-3) 31,31,1*.

$ IFtD.GT. 0.001) 16,15

$ GO TO 3G

17,18

GO TO 30

19, 24, 30

20,22

21, 30

GO TO 30

23,30

GO TO 30

T) 25,27

T) 30, 2o

u-0 2 $ GO TO 3 T) 30,28

0.02

FINDENF = $ PRIM kl

I RETURN

« PRINT -+3 J RETURN

CRT i R£TUR^

CRT S PUNT hZ I RETURN J END

RETURN

05/1h/73

FUNC

c DENSI

c LN(D/

c U = ( DIME

DATA

DATA

1 FORM

2 IF (T

3 U=(T

5 F = 6 OENG

7 DENG

8 DENG

VAPOR, MOL/L . A*.*Q**5 + A5*U*W

(TC-T)/ (TC-TT)

TION DENGASF(T)

TIES OF SATURATED METHANE

DO = A1*W**E + A2*W + A3

TC/T-1)/(TC/TT-1) , W = NSION A(5)

(TTRP=9 0.68) , (TCRT=190.55&) , I DCRT = 10.0) , <E = 0. -+6) (A = -2.7036003, 3.1561552, -8.6573-.Q9, ?.26*tOJ62,

ATdHO 9X *DENGAiF = 0, T EXCEEDS TCRT.*/)

-TCRT) 3,7,8

CRT/T-l)/(TCRT/rTRP-l) J W= ( TCRT-T) /

(

TCRT-TT RP) *

-3.526903**)

Q=CUJERTF ( W)

A(1)*W*»E + A(2)*W + A(3)»Q**<+ + A(h)*Q**5 + A(i^)*U*W

ASF = OCRT*EXPF(F) ? RETURN

ASF = DCRT * RETJRN

ASF = $ PRINT 1 $ XETURN £ END

29
05/1W73

FU

ITc

M = CO

CO

FO

FO

If

IF

DO

8 or

9 JO

10

11 IF

12

13 IF

Ik

15 IF

16

17 IF 18

20 CO

21 FI

22 FI

23 FI

NCTIO

RATE

a FO

MMON/

MMON/

RMATt

RMAT(

(T-TC

(M.EQ

= DEN

= OEN

20 J 00 =

= OT

=(O.GT

= 0.0

(O.LT

= OCR

(O.GT

= 30.

(O.GT

= OCR

NTINU

NOSAT

NDSAT

NOSAT

IN FINDS

OEN TO

IR VAPOR

1/AG,AL

3/DPDT,

1H0 9X

1H0 9X

;rt> *,2

0) 5,6

IGASF(T)

ILIQF(T)

'1,50

DTSOR/D

VOTDD

DD * .0.001)

Gl I .DCRT)

:t - o.o .30.0)

X G .DCRT)

IT + 0.0

t F = D

= OCR

=

S DT

TRP

$ IF

IF (rl 13,1

GO TO

20, It

2 $

16,17

TO

20,13

2INOSA

J

T $

S PR

GJ TO 7 =T-T3ATF(D) J IF ( A3SF ( DT/T ) -1. GE-6 ) 21,21,8

S IF(DTDO.EQ.0. 0) 22,9

(ABSF (DO/D)-1.0E-6) 21,21,10

.EQ. 0) 11,15

2 20

GO TO 2

2J

TF = 3 $ PRINT 1 $ RETURN

RETURN

RETU ?N IMT 2 S RETURN I END

35/l<*/73

MOL/L.

B* (1-Qh)

FUNCTION DENLIQF(T)

C OENSITIES OF SATURATED LIJUID METHANE,

C (D-DC)/(DT-OC) = (W**E)*EXP(A* (1-Q2) « C W = (TC-T)/ (TC-TT) , Q = CUBERTF(W).

DATA <TTRP=9G.b8> , < T ;RT=190 . 55 5) , (DCRT=1U.0) , OATA <E = 0. 36), (A =-0. 178630165), (6= J. 0<*838<+75)

1 FORflATdHQ 9X 'OENLIQF = 0, T EXCEEDS TCRT.*/)

2 IF(T-TCRT) 3,7,8

3 W = (TCRT-T) /(TCRT-TTRP) % Q = CUBERTF(W)

5 F = AM1-Q*»2) B*(1-Q*W) + C*(l-W**2)

6 OENLIQF = DCRT + ( OT^P-DCRT ) *E XPF ( F

) *W**E S

7 OENLIQF - DCRT £ RETURN

8 OENLIQF = % PRINT 1 $ RETURN £ END

+ C* (1-W2)

)

(DTRP=28.ii*7)

, <C=-0. 018^6937)

RETURN

05/1W73

FUNCTION PMELTF(T)

METHANE SOLID-LIQUID MELTING PRESSURl, BAR.

COMMON/l/AG,AL,3E,0E,GK, DCRT , PCRT , TCRT , DTRP, PTRP, TTRP

COMMON/ 3/DPDr,02PDT2, DPS DT , DPMDT , DPOD, DPDR , DTSDR , DTHDR

OATA (QP=1. 01325) , (E=1.65) , (A = 188*».^3)

X = T/TTRP % XE = X**E S AQ = A*QP

PMELTF = PTRP + AQMXE-1)

OPMOT = AQ*E*XE/X/TTRP $ RETURN t END

30
05/14/73

FUNCTION PSATF(T)

C METHANE VAPOR PRESSURE Ml\ PRYDZ/GOOOWIN DATA, NOV., 197C

C NOTE, PRESSURE IN BARS, 1.01325 BAR/ATM.

COMMON/3/ DPDT,02PDT2, DPS DT , DPMDT ,OPDD,DPDR, DTS OR, OTHDR

0ATA(TTRP=9G.66) , < TCRT = U0 . 55 5 ) , (PTRP=C . 117*35675)

DATA IP l=i*. 7 774 8 58 0) ,(P2=1.760o5 36 3),(P3=-G.56 78 8894>

OATA <P4=1. 32786231)

1 FORMATdHO 9X *P3ATF = 0, T EXCEEDS TC'KT. */)

2 XK=1-TTRP/TCRT S X = (1 -TTRP/T ) / XK % Q = l-X I IF-(Q) 3 , - , 5 3 PSATF = DPSDT = $ PRINT 1 $ RETURN

4 W = Wl = $ GO TO 6

5 U=SQRTF(Q) S W=Q*U S Wl=-3*U/2

6 QXDT=TTRP/XK/T**2 S Z = X*W $ Zl = X*W1 W

7 F = P1*X P2*X**2 P3*<**3 + P4*Z

8 Fl = PI + 2*P2*X + 3*P3*X*»2 + P4*Z1

9 PSATF=PTRP*£XPF(F) S OPS DT=Fl* PSATF* DXDT f RETURN % END

5/14/7 3 FUNCTION TSATF(DEN)

C LIQUIO-VAPOR SATURATION T£MP£RATURES OF HtTHANE.

C NOTE EXPONENTIAL U(S). ION., (TC/T- 1 ) / ( TG / TT- 1 ) = U<S>*Z<<).

C U(S) = EXPCFS/2), F5 = S* (S-ST) /AFS (S-l ) , Z(k) = 1+ < R- 1 ).» W (R) , C W = Al + A2*LN(R) + A3*Q *• A4/ ( 1 + d*Q2 ) + A5*R + . . * AlC*Ro.

C0MM0N/3/DPDT,D2PDT2,DPS 3T , OPMQT , DPOO, DPDR, DTSDR ,DTHDK

OIMENSION A(10)

OATA (E = 8.0)

OATA <TTRP=9G.6 8) , ( TCRT= 190 . 555) , < OCRT= 1 . C ) , <OTRP= 28. 14 7)

DATA(A = 0.84320666, 0.1597-2304, 0.97837869, C. 26654061,

1 -1.71505402, 10.88693605, -32 . 420 48 70 G , b 3. lb lbb459

,

2 -62. 72090242, 25.92*98131)

1 R=OEN/OTRP $ S=DEN/o:RT £ OS = S-l $ IF (QS.EQ. Q. ) 3 C ,

2

2 AS = ABSF(QS) $ ST=OSDR=OTRP/DCRT S. YN = TCRT/TTRP - 1 3 X = S*(S-ST) $ XI = 2*S - ST £ V = 1/AS $ VI = -V/QS

4 FS = X*V i FS1 = (X*V1 Xl*V)*DSOR

5 U = EXPF(FS/2) J Ul = J*FSl/2 I Q = CUBERTF(R) 1 02 = Q**2

6 X = 1/(1+E»02) $ XI = -2*E/3/0*X**2

7 H = A(l) + A(2)*L0GF(R) *- A(3)*Q A(4)*X

8 Wl = A(2)/R + A(3)/3/Q2 + AU)»X1

9 00 10 <=5,10 S W = W + A(K) *R**(K-h)

10 Wl = Wl + (K-4)*A(<)*R**(K-5)

11 Z = 1 * W»U-1) % Zl = W * (R-1)*W1

12 F = U*Z $ Fl = U*Z1 + U1*Z I X = 1 f YN*F

13 T5ATF = TCRT/X * OTSDR = -YN*F1* TSATF/X I RETURN

30 TSATF = TCRT £ OTSDR = $ RETURN J END

05/14/73

FUNCTION CVGF(T)

C METHANE CV , J/MOL/K, AL0N3 THE 16.5 MOL/L ISOCHORE.

C CV/CVZ = 1 + A/X * d/<? + C/X3/ (X-1)**E, X = T/TH.

COMMON/ 99/ TI,EZZ,EZ, SZ,CVZ,HZ,CFZ

DATA (E = 0.1) , (TH = lo4, 11/1) , (G = 0.9737)

DATA (A = C. 47 294 996 ) , C B=- J .

5

027 1717 ) , (C= 0.21421338)

1 TI = T $ CALL IDEAu $ X = T/TH i X3 = X*»3

2 F = A/X B/X*»2 C/X3/ (X-1)**E

3 CVGF = G*C\/ZM1 + F) J RETURN $ END

31
05/14/73

FUNCTION PVTF(T,DEN>

VIA EQN5TATE, YIELDS P,9A*, ALSO DP/DT, D2P/DT2.

COMMON Bl,82, CI ,C2 ,C3 , C-+ , El,E2,E3

COMMON/l/AG,AL,BE,DE,GK, DCRT , PCRT , TCRT , DTRP, PTRP, TTRP

C0MM0N/3/DP0T,D2PDT2,DPS JT , DPMOT , DPDD, DPDR , DTSDR, DTHDR

C0MM0N/4/XBl,XB2,XCl,XC2,XDl,XD2,X£l,XE2

COMMON / 5/ TSAT, DXBDR, OXC JR, OXDDR , DXE DR

1 3=0EN/0CRT $ R=DEN/OTRP 5 R2=R»*2 i R3=R**3

2 TS = TSAT = TSATF(QEM) S PS = PSATF(TS)

3 XB = X9F(T,DEN) $ XC = XCF(T,OEN) J XE = XEF(T,DEN)

5 B = Bl + B2*R $ C = CI + C2*R + C3*R2 Ch*R3

6 E - (S-l)MEl < E2*R + E3*R2>

9 F = B»X3 C*XC « E*XE 5 Fl = B*XB1 + C*XC1 + E*XE1

11 FZ = 8*XB2 C*XC2 E*X£2 I YS = (PS/R/GK/TS - 1)*TS/TCRT/R

15 PVTF = (T+R* (F+YS) *T3RT) *R*G< i OPOT = ( 1+R*F1 ) *R*GK

17 02P0T2 = R2*GK»F2/TC*T $ RETURN J END

05/14/73

FUNCTION DPDRF(T,DEN)

VIA EQNSTATE, DPDRF = P.84R. YIELOS ALSO DP/DR, DP/DD.

COMMON B1,B2, CI , C2 ,C3,C-» , E1,E2,E3

COMMON/l/AG,AL,BE,DE,G<, DCRT , PCRT , TCRT , OTRP, PTRP, T TRP

C0MM0N/3/DP0r,02PDr2,DPSDT,DPM0T,DP00,DP0R,0TSCR,DTH0R

C0MM0N/5/TSAT, DXBOR, DXC Jk, DXDOk, DXEOk

1 X = T/TCRT J S=D£N/OCRT $ DSOR = DTPP/DCRT

2 R = OEN/DTRP 4 RZ=1**2 $ R3=R**3

3 TS=TSAT=TSATF(DEN) J XS=TS/TCRT J PS=PSATF(TS)

< XB = XdF(T,DcN) $ XC = XCF(T,DEN) S X£ = XEF(T,DEN)

5 B = dl + B2*R $ 3D = 3?

b C = CI + C2*R + C3*R2 * Zk*R3 $ CD = C2 + 2*C3*R + 3*C4**2

8 U = S-l $ \i = El + E2*R + C3*R2 « VI = £2 ?*£3*R

9 £ - U*V J ED = U*V1 + V*DSDR J F = B*XB + C*XC + E*XE

11 Fl = 8*DXB0R B0*X9 C*DXCDR CO'XC £*DXEDR EO*XE

15 YS = (PS/R/GK/TS-1) »XS/R

16 YS1 = (TS - R»OTSDR * (OPSOT*OTSDR - 2*PS/R> /GK) /TCRT

17 Q = R*(F+YS)/X <S OPDR = GK*T*

(

1+2*Q+ ( R2* Fl +Y S 1 ) /X

)

20 OPOO = DPDR/DT«P £ DPJRF = R*GK*T*(1+Q> ? RETURN $ END

Jp/14/73

FUNCTION THETAF(DEN)

C LOCUS OF TEMPS., INSIDE THE DOME, FOR THE EONSTATE.

C THETA = TSAF»£XP (U(S) )

C IF 3 < 1, U = AGMS-1)**J. IF S > 1, U = -AL* (S-l) **3.

C YIELOS ALSO THE FIRST DERIVATIVE RSP. TO RHOEQEN/OTRP.

COMMON/l/AG,AL,B£,OE,GK, DCRT , PCRT , TCRT , DTRP, PTRP , TTRP

C0MM0N/3/DPDT,D2PDT2,DPS')T,DPMDT,0PUD,DPDR,DTSDR,DTHDR

C0MM0N/5/TSAT, DXBOR,OXCJR,DXODR,OXEOR

1 S = DEN/DCRT I DSD< = JTRP/DCRT

2 Q=S-1 S Q2 = Q**2 i 33=Q**J * IF(Q) 3,8, h

3 U = AG*Q3 8 Ul = 3*AG*12*DSDk « GO TO 3 < U = -AL*Q3 i Ul = -3*AL*Q2'DSDR

5 XP = EXPF(U) X THETAF = TSAT*XP

7 OTHOR = (TSAT»U1 + DTSDR)*XP $ RETURN

8 THETAF = TCRT S OTHDR =0 i RETURN I END

32
35/l<+/73

FUNCTION XBF(T,D)

C FOR THE EQUATION OF STATE - C X3 = X»(1-EXP(-BE/X) ) - X3»(1-EXP(-BE/XS) )

COMMON/l/AG,Al, BE, OE,GK, DCRT , PCRT , TCRT , QTRP, PTRP, TTRP

C0rtM0N/3/DPDT,D2PDT2,DP5DT, DPMOT , OP DO, DP OR, OTSOR , DTHDR

C0MM0N/WXB1,XB2,XC1, XC2 , XOl , X02 , XE1 , XE2

C0MM0N/5/TSAT, OXBDR, DXCOR, DXDOR

,

OXEOR

1 X=T/TCRT $ XS=1SAT/TCRT 5 DXSDR=CTSOR/T CRT

2 U = BE/X $ Ul = -U/X S U2 = -2*U1/X

3 US = BE/XS $ US1 = -JS/XS

<+ XP=£XPF(-U) $ L = 1-XP S Zi=Ul*XP S Z2= { U2 -Ul* *2 ) *X

5 PHI = X*Z $ X81 = Z+X*Zl * X62 = X*Z2 + 2*Z1

6 XPS=£XPF(-U3> $ IS - 1-XPS A ZS1 = USl*XPS

7 PHS = XS*ZS $ DX30R = - ( X S* ZSl* ZS) * DX SDR

8 XBF = PHI - PHS S RETURN 5 END

5 Al <+ / 7 3 FUNCTION XCF (T,D)

C FOR THE EQUATION OF STATE - C XCF = 1/X - 1/XS, X = T/TC.

C0MM0N/1/AG,AL,B£,Q£,GK, DCRT , PCRT , TCRT , DTRP, PTRP, T TRP

COMMON/ 3/DP0T, 02 PDT2, DPS.3T , OPMDT , OPDD, DP OR, OTS OR, DTHDR

C0HM0N/<f/X81,XB2,XCi,XC2,XJl,X02,XEl,XE2

CQMM0N/5/T3AT, OX80R,DXCJR,0XDQR,DXEQR

1 X = T/TCRT $ XS = TSAT/TCRT

2 XCF = 1/X-l/XS $ XC1 = -1/X**2 S XC2 = -2*XC1/X

3 DXCOR = 0TSDR/TCRT/X3**2 $ RETURN f END

3t>/l<+//3

12

3k

56

9 10

FU

NOT

PSI

U = CO

CO

CO

CO

TS

UUl

w

V

z

5=

11 PW

12 IF 13 Z =

1<* G 15 PZ

20 XE

22 XE 23 DX 30 RE

NOTION XE

E CONSTAN

= (1-W*L

T/TH, W MHON/1/AG

HM0N/3/DP

MM0N/*/X8

MM0N/5/TS

= TSAT

= T/TH $

X = TCRT/

= DEMU-1

= TS/TH

= OE* (V-l

GW=GHl=GW

LOGFQ+ 1/

=1-GW $ P (Z) 13,13

GZ=GZ1=0

= LOGFQ + = 1-GZ

F = PW/U

2 = PW2X/

EOR = PW1

TURN J

F<T,

T IN

N(l +

= D »AL,

DT,D

1,XB

AT,

$ T U2

TH

) $

$ V

) $ 2 = w) i W1X =

£ 1/Z)

S P

- PZ

u

- R/U

LN

D)

PSI,

1/W) ) / E* (U-l

BE, OE,

2PDT2,

2,XC1,

DXBOR,

H = TH

= U**

$ Ul*

wix

2 = V*

7.1 -

£ G}

GW = W*

-GW1*4

GO TO

$ j Zl = - /V %

2*PW1<

- PA*'J

D

W = OE* (U-l) , Z = DE* (V-l).

U, XEF = (PSI-PSISAT) = PW/U - P7/\J,

) , V = TS/TH, Z = DE* (V-l) . G<, DCRT, PCRT, TCRT, D TRP , PTPP , TTRP

OPS JT,OPMDT,DPDD,DPOR,DTSDR, DTHDR

XC2,XD1, XD2 ,XE1 ,X£2

DX-G JRtOXDDR, OXEOR

ETAF(O)

2 S U3 = U**3

= -U*DTHDR/TH

= D-;*U1X $ W1R = D-_*U1R 2 $ VI = (DTSDR-V*OTHDR) /TH

D£*V1 $ IF(W> 9,9,10

TO 11

G $ GW1 = G-1/ (1+-W) ? GW2=-1/W/ ( 1 + W) **2

IX 5 PW1R=-GW1»W1R I PW2X=-GW2*W1X**2

GZ1 = G - 1/ (1+Z)

15

Z = Z*G

GZ1*Z1

x-:i = pwix/u - pw*uix/u2

*U1X/U2 « 2*PW*U1X**2/U3

1R/J2 - PZ1/V + PZ*V1/V2

33
SUBROUTINE IOEAL

C METHANE IDEAL GAS THERMOF JNC TIONS (TI ) AT ONE ATMOS.

COMMON/99/ TI,EZZ, EZ ,SZ , CV Z, HZ, CPZ

DATA ( R = 8. 31 43) , (E = 5. 02256), (A Z= 18. 85248 4) , (Ai=2. 5996981),

1 (A2 =1.4449418) , < A 3=-l. 8*72 716) , (A4=0. 8211 218) , ( A5 = 4. 72 C 790 7 ) 1 X=TI/4Q0 $ i=CUBERTF(X) £ a2=Q**2 J U = E/X J XP=EXPF(U>

2 Z = U/(XP-1) i EZ = Al + A2»Q + A3*Q2 A4*X + A5*Z

3 CVZ = Al 4*A2*Q/3 5M3*Q2/3 2»A4*X A5*XP»Z**2

4 FU = Z - LOGFC1-1/XP)

5 SZ = AZ + LOGF(TI/60) + Al*LOGF(X)

6 SZ = SZ + A2*Q + 5*A3*Q2/2 + 2*A**X A5*FU

C CONVERT TO DIMENSIOMEJ RESULTS IN - JOUL ES , MOL ES ,KEL V INS.

7 HZ = R*TI*(1+EZ) X CPZ = R*(1+CVZ)

8 EZ = R*TI*EZ $ CVZ = R*C\/Z « SZ = R*SZ

9 RETURN $ END

FUNCTION ESATF(T)

C INTERNAL ENERGY, SATD.LIGl. METHANE, J/MOL.

C EQN., Y(E) = (1-X) *EXPU(X) ) , WHERE - C Y(E) = (E-ET)/(EC-ET) , X(T) = ( TC-T ) /

(

TC-TT ) , AND - C W(X> = Al*X»LN(l + 3/X) + A2*X**C + A3*X . . * A9*X7.

OIMENSION A(9)

DATA <TTRP=9 0.o8> , ( TCRT= 190 . 5 55) , (8=0.1) ,(C = 0.19)

OAT A (ETRP=3 47 1.85 3)

,

<EC*T= 10 819 .56 8

)

OATA(A = -0. 029»+099'+, -0. 1915«f778, -0.67454649 , 3.11554755,

1 -9.71804579, 17.157^6593, -16. 5 C 388 Se 1 , 7.79262156, -1,36621087)

1 FORMATdHO 9X 'ESATF = 0, T EXCEEOS TCRT. * / ) 2 XN = TCRT-TTRP £ VN = £CRT-ETRP I X = (TCRT-D/XN

3 U = 1-X S IF(X) 4,5,6

4 ESATF =0 $ PRINT 1 £ RETURN 5W=Z=0 $ GO TO 7 6 W = X*LOGF U+B/X) £ Z = X»*C

7 F = A(1)*W + A(2)*Z S DO 8 J = 3,9

8 F = F + A(J) X**(J-2)

9 ESATF = ETRP «- YN*U*EXPF(F> * RETURN I END

FUNCTION SSATF(T)

C ENTROPY AND CSAT, SAT3.LU. METHANE, J/MOL/K. DtFINt - C X(T) = (TC-T)/(TC-TT) , Y (S ) = < S-ST )

/

(SC-ST ) , Q = X»»(l/2).

C EON., Y(S) = Il-XI*£XP{4)f WHL RE - C W(X) = A1*X*LN(1 + 1/X) + A^*QQ + A3*Q + A**X2 + . . + A3*y . COMMON/9/ CSAT

DIMENSION A(8)

DATA <TTRP = 9Co8), ( TCRT= 190 . 55 5) , <E=J,19)

DATA (STRP=6 7. 8 7 832 ) , (SC *T= 12 . 4626 3 ) OATA(A = -0.15660933, -0.17271532, 0.06tJ7J234, 1.687*3215,

1 -5.33121801, 9.06407137, -7.54347331, 2. 43529834)

1 FORMATdHO 9X *SSATF = J, T EXCEEDS TCRT. * / ) 2 XN = TCRT-TTRP £ YM = 3CRT-STKP £ X = (TCRT-T)/XN

3 U = i-X t OXDT = -1/XN i IF(X) «* , 5 ,

6

4 SSATF = CSAT =0 £ PRI U 1 £ RETURN

5XG = Q = QQ. = J JO T] D

b b = LOGFU + 1/X) £ XG = X*G i XG1 = G-l/d+X)

7 j=S^RTF(X) S Q1=J.5/1 C UU = X**£ $ Oil = E*QQ/X

8 F = A(1)*XG + A(2)*H A(3)*Q £ DO 9 K=4,8

9 F = F + A(K) *X*MK-2> £ XP = EXPF(F)

10 SSATF = STR? <- YM*J»<P $ IF(X.EQ.O.J) 1p,11

11 Fl = A(1)*XG1 A(2)*Q31 A(3)»Cil £ DC 12 K = 4,6

12 Fl = Fl + (K-2)*A(K)»X** (K-3)

14 CSAT = T»YN*(U*F1-1)'XP*3XDT S RETURN

15 CSAT =0 t RETURM £ END

34
Q5/1W73

SUBROUTINE MELTHERM

GIVEN P, GET T, DEN, ETC. » FOR FREEZING LIQUIO AT T L.T. TCRT.

UOMMON/l/AG,AL ,8E,0E,GK, DCRT , PCRT , TCRT , OTRP, PTRP , T TRP

C0MM0N/3/DPDT,D2PDT2,DPSDT,0PMDT,DPDD,DPDR,0TS0R,DTH0R

COMMON/8/ P,T,OEN, E,H,S, CV,CP,W, WK

COMMON/9/ CSAT

1 T = FINDTMF(P) $ DL = F INDS ATF (T , 1

)

2 E=£SATF(T) $ S=S3ATF(T) * PX=P VTF <T , OL ) i DDL OT=DTRP/ OTSDR

3 CV = CSAT + 1CD*T*DP3T*D0LDT/DL**2

NOW INTEGRATt FROM SAT. Hi. UP TO THE FREEZING LIQUID.

< DEN = DM = DTRP*<T/TTRP>**Q.25 * N = '+ + 5MDM-DL)

5 E = E + ESUMFCN,T,DL,DM) £ H = E + 1GC*P/DM

6 S = S + SSUMF(U,N, T, JLiOD * CV = CV CSUMF ( N , T , OL , DP ) 7 PX = PVTF{T,DM) t PX = DPURF(T,DM)

8 CP = CV + 1JQ*T/JP'DD* (OP:DT/DM)**2

9 W = SQ.RTF{WK*CP*QPOD/CV) ? RETURN 3> END

OS/Ih/73

SUBROUTINE SATGSTRM

GIVEN P, GET T, DEN, ETC, FOR THt SATURATE VAPOR.

COMMON/1/AG, AL,BE,DE,GK, DCRT , PCRT , TGRT , DTRP, PTRP , TTRP

COMMON/3/DPOT,D2PDT2,D=:, SJT,DPMDT,DPOD,DPDR,DTSCR,DTHDR

COMMON/tt/ P,T,DEN, E,H,S, CV,CP,W, WK

COMMON/ 99/ TI,EZZ, E Z, SZ , C VZ , HZ ,CPZ

DATA <DA=0. 0) ,(QP=1. J 1325) , <GC = 0.0831^3 <) TI = FINDTSF(P) % 5ALL IOcAL

OG = FINDSATF(T,J) i N = 3 + 2*JG

EZZ + EZ + E5U:1F(N,T,DA,DG) % H = £ 10C*P/OG

SZ - 100*GC*LOGF(GC*T»DG/QP> + SSUMF (1 , N , T , A, DG)

Q.G2MT-TCRT) *»2 * IF<X.LT.3.0) 6,7

N + 3Q*EXPF(-X)

CVZ + CSUMFCN, T,DA, OG)

= PVTF{T,DG) $ 3 X = OPDRF(T,DG)

CV + 100»T/OPDD* (0P}T/DG)**2

SQRTF(WK*CP*DPDO/CV) J RETURN % HND

05/l<+/73

SUBROUTINE SATLQTRM

GIVEN P, GET T, DEN, ETC., FOR THE SATURATED LIQUID.

C0MM0N/1/AG,AL,8E,JE,GK, DCRT , PCRT , TCRT , DTRP, PTRP ,

T

TRP

COMMON/ 3/DPDT,D2PDT 2, DPS DT , DPMOT ,DPDD, DPOR , DTSDR,DTHDR

COMMON/8/ P,T,DEN, E,H,S, CV,CP,W, WK

COMMON/9/ CSAT

1 T = FINDTSF(P) $ OEN = OL = FI NDSATF ( I , 1

)

2 E = ESATF(T) $ S = S3ATF(T) i H = E + 10G*P/DL

3 PX = PVTF(T,DL) J P X = DPDRF(T,DL) $ JDLOT = OTRP/DTSDR

k CV = CSAT + luu»T*0PJT*JJLDT/0L**2

6 CP = CV + 1QO»T/OPODMOPDT/DL>**2

9 W = SQRTF(WK*GP*L)Pl)D/CV) S RETURN $ END

1 T =

2 DEN

3 E =

« S =

5 X =

6 N =

7 CV =

8 PX = 9 CP = 10 w =

35
05/14/73

SUBROUTINE THRMOGAS

C GIVEN P,T, GET DEN AND FUNCTIONS FOR HOMOGENEOUS DOMAIN.

COMMON/l/AG,AL,BE,DE,GK, DCRT , PCRT , TCRT , DTRP, PTRP , TTRP

COMMON/3/DPOT,D2PDT2,DPS:)T,DPMDT,DPDD,DPDR,DTSDR,DTHDR

COMMON/8/ P,T,DEN, E,H,S, CV,CP,W, WK

COMMON/ 99/ TI,EZZ, EZ, SZ ,CVZ , HZ ,CPZ

DATA (OA = 0. G),(QP = 1.J 1323), (GC=Q. 063143 <*) 1 TI = T $ CALL IDEAL

2 DEN = OB = FINOENF(T,P) J H = 5 * 2*DO

3 w = EZZ + £Z + ESUMF(N,T,DA,DB) S H = E + 100*P/DB

4 5 = SZ - 1UO*GC*LOGF(GC*T*DB/QP) SSUMF (1 , N ,T , DA, DB

)

5 Q = (OB/DCRT-1) **3 * 0.3 = ABSF (Q) - Q

6 X = 0.02MT-TCRT)*»2 + J'QD $ IFU.LT.3.0) 7,8

7 N = N 30*EXPF(-X)

8 C\/ = CVZ + CSUMF(N,T,DA, 3B) $ PX = PVTF(T,DB)

9 PX = OPDRF(T,DB) f CP = CV 1 G G* T/DPDDM DPOT/ DB) **2

10 W = SQ.RTF(WK*CP*DPUD/CV) $ RETURN % END

SUBROUTINE THRMOLIQ

C GIVEN P,T, GET DEN AND FUMCTIONS FOR COMPR.LIQ. AT T L.T. TCRT.

COMMON/l/AG,AL,BE,DE,GK, DCRT , PCRT , TCRT , DTRP, PTRP

,

TTRP

C0MM0N/3/DPDT,D2P0T2,DPS3T,DPMDT,DPDD,DP0R,DTSDR,DTHDR

COMMON/8/ P,T,DEN, £,H,S, CV,CP,W, WK

COMMON/9/ CSAT

1 DL = FINDSATF1T, 1) 5 DEN = DB = FINDENF(T,P)

3 E = ESATF(T) •$ S = SSATF(D $ PX=P VTF <T , DL ) % DDLDT = DTRP/ DTSOR

5 CV = CSAT 10G*T*DPDT*D'DLDT/OL**2

C NOW INTERGATE FROM SAT. LI). INTO THE COMPR. LIQUID.

6 N = 5 5*(Db-DL)

7 E = E' + ESUMF(N,T,DL,DB) $ H = E + 10U*P/DB

8 S = S + SSUMF (u ,N, r,JL,Dl)

9 G\l = C\l + CSUMF (N,T,0L,O3>

10 PX = P\/TF(T,DB) S PX = DPDRF(T,D8)

11 CP = CV 10GM/OPDO* (OPDT/DG)**2

12 W = SQRTF(WK*CP*OPDD/CV) S RETURN $ END

SUBROUTINE THERMOX

C REGION X FOR DEN ABOVE DC«T, AND TSAT(18.t>> = T = 220 K.

C GIVEN P,T, GET DEN AND THIRMOFUNCTIONS

.

C E = £A, S = SA AT 220 K AND 18.5 MOL/L.

C FIRST INTEGRATE ALONG ISOCHORE 18.5, THEN ALONG ISOTHERM T. COMMON/ 3/DPDT, 02PD T 2, DPS DT , DPMDT , DPDD , DPOR , DTSDR, DT HOP

COMMON/8/ P,T,DEN, E,H,S, CV,CP,W, WK

DATA (TTRP = 9u.o6) , ( TCRT= 190 . 5 55) , (DCRT = 10.0) , < DTRP = 2 8. 14 7)

DATA (0A=18.5),(EA=917^.3),(SA=113.912)

1 E=EA J S=SA $ TR=220-T S N=5+TR/2 i OT=-TR/N

2 DO 4 J=1,N i TJ = 223 * <J-0.5)*OT $ CX = CVGF(TJ)

3 E = E + CX'DT $ j = 5 * CX*DT/TJ

4 CONTINUE * OtN = OJ = FINDENF(T,P)

C NOW INTEGRATE ALONG ISOTHERM T.

5 N = 5 3*A8SF(DB-0A) * S = S + SSUMF ( , N , T, DA , DB

)

6 E = E + ESUMF<N,T, JA,03) $ H = E + lOQ'P/DB

7 X = 0.02*(T-TCRT)**2 3* ( Dd/DCRT- 1

) * * 2 « IF(X.LT.3.0) 8,9

8 N = N - 30*EXPF (-X)

9 CV = CVGF(T) «• CSUMF(N,T,DA,DB)

10 PX = PVTF(T,OB) $

3 X = DPDRF(T,DB)

11 CP = CV + 100*T/DPDD* (DPJT/D3)**2

12 W = SQRTF(WK*CP»DPDO/CV) I RETURN $ FND

36
Q5/lk/73

SUBROUTINE THERMXL

C iGIVEN P, GET T,OEN,

c INTEGRATE ALONG ISO

COMMON/ 1/AG,AL, BE,

COMMON/3/DPOT,L)2PO

COMMON/8/ P,T,UEN,

COMMON/9/ CSAT

OATA (DA=18.5> , (EA

1 T = FINDTSF(P) I 2 N = 5 + TR/2 S

3 DO 5 J=1,N J TJ

k E = E * CX*OT $

5 CONTINUE $ DEN = C 1 iOvt INTEGRATE ALONG

6 N = 5+3*ABSF (DL-OA

7 S = S + SSUMF(C,N,

8 CSAT = CV = CP = W 9 X = 0.Q2MT-TCRT)*

10 N = N + 30*EXPF(-X

11 CV = CVGF(T) + GSU

12 PX = PVTF(T,OL) J 13 CSAT = CV - 10G*T*

Ik CP = CM + 100M/OP

15 M = SQRTF(WK*CP»DP

ETC., FOR SAT.LIQ. IN REGION X. CHORE 18.5, THEN ALONG ISOTHERM T DOWN TJ OL

.

OE,GK, DCRT,PCRT,TCRT, OTRP, PT RP

,

TTRP

T 2, DPS DT, DP MUT,DPDO, DP OR, DTS OR, DTHDR

E,H,S, CV,CP,W, WK

= 9S?-+. 3) , (SA = 113. 912)

E = £A S 3 = SA $ TR = 22G-T

T = -H/N

= 220 * <J-0.5)»DT S CX = CVGF(Tj)

S = S * CX*DT/TJ

DL = FINUSATF (T,l)

ISOTH£RM T FROM OA DOWN TO OL

.

) $ £ = E+cSUMF (N,T,DA,DL) T T,DA,DL) i IFXT.EQ.TCRT) 6,9

= 5 RETURN

*2 $ IFtX.LT.3. 0) 10 ,11

)MF(N,T,DA,DL)

PX = DPURF(T,Dl) ? JDLiJT = DTRP/DTSDR

OPDT*Z)JLDT/DL**2

DO* (OPJT/DL) **2

DO/CV) J RETURN S END

H = F+1JC*P/D1

05/14/73

FUNCTION CSUMF(N,T,DA,08)

DELTA CV = -T*lNTEGRAi_ ( O2P/0T2 > /C**2 > * DO.

COMMON/3/DPDT,D2PDT2,DPS'JT, DP MO T , OPOD, DP OR , DTS OR , DTHDR

OX = (DB-DAV/N * C3UMF =0 8 DO 5 J=1,N

n M - OA a f I _ i-i Cl«i1v f O - DllTC IT nkll DN = DA (J-u.5)*UX £ P = PVTF(T,ON)

CSUMF = CSUMF - D2PDT2*DX/DN**2

CSUMF = 100*T*CSUMF « RETURN £ND

05/l<t/?3

FUNCTION ESUMF (N,T,DA,D8)

C GET DELTA E OVER DENSITY *ANGE FRO* DA TO OP.

C DELTA E = INTEGRAL

(

J -T* (DP/01) ) *DX/DN**2.

COMMON/ 3/DP T, U2PO T 2, DPS 3T , DPMOT ,DPDD, OP OR, DTS OR, DTHDR

2 OX = (OB-DA)/N ? ESUMF = 0.0

3 OO 5 J=1,N £ DN = JA t (J-0.5)*DX 3 P = PVTF(T,DN>

5 ESUMF = ESUMF + (P-T* DPDT ) * DX/UN**

2

9 ESUMF = lGO'cSllMF 5 RETURN f END

FUNCTION SSUMF(L,N,T,DA, JB)

DENSITY-DEPENDENT CHANGE JF S FROM DA TO OB.

DELTA S = INTtGRAL (3K-( JP/DT) /UN)*DX/DN.

COMMON/l/AG,AL,BE,OE,GK, DCRT , PCPT , TCRT , DTRP, PTRP , T TRP

COMMON/ 3/DPDT,D2PDT 2, DPS JT, DPMOT, DPDD,DPDR, DTS OR, DTHDR

SSUMF = C 4 UX = (OB-DA) /N % IF(L.EQ.Q) H,2

GC = GK/DTRP $ DO J J = 1,N % DN=OA+ ( J- . o

)

* OX J P = PV1F(T,DN)

SSUMF = SSUMF (GC- JPOT/DN

)

*DX/DN I GO TO 9 00 5 J=1,N $ ON = JA + (J-0. ;>)*DX $ P = PVTF(T,ON)

SSUMF = SSUMF - DPDT*DX/ON* *2

SSUMF = 100*SSUMF £ RETURN S END

37
05/16/73

PROGRAM METHERM6

C COMPUTE METHANE THERMOFUMCTIONS IN ENGINEERING UNITS.

C NOTE. OCRT=10. 01532 LB/CUFT, TCRT=342.999 R, PCRT=667.003 PSI.

C NOTE. DTRP = 28. 19012 LB/CUFT, TTRP = 163. 224 R, PTRP = 1.7C326 PSI.

COMMON B1,B2, CI ,C2 ,C3,C4 , E1,E2,E3

COMMON/l/AG,AL,BE,OE,GK, DCRT , PCRT , TCRT , OTRP, PTRP, TTRP

COMMON/3/DPDT,D2PDT2,DPS0T,0PMDT,0PD0,DP0R,0TS0R,OTHDR

COMMON/7/ TR,TF, CN,VS

COMMON/8/ P,T,DEN, E,H,S, CV,CP,W, WK

COMMON/9/ CSAT

COMMON/ 99/ TI f EZZ, EZ, SZ,CVZ , HZ,CPZ

DIMENSION PSK99)

14 FORMAT(IX)

15 FORMAT(8F10.0)

16 F0RMAT(1H1 13X *METHANE ISOBAR AT P = * F8.1, * PSI* //

1 14X1HT 8X1HT 6X3HDEN 6X3HVOL 4X5HDP/0T 6X5H0P/00

2 7X1HE 7X1HH 8X1HS 7X2HCV 7X2HCP 5X1HW /

3 10X5HOEG F 4X5HDEG R 2X7HLB/CUFT 2X7HCUFT/LE 4X5HPSI/R

4 1X10HPSICUFT/LB 2X6HBTU/LB 2X6HBTU/LB 1X8HBTU/LB/R

5 1X8HBTU/LB/R 1X8HBTU/LB/R 2X4HFT/S ) 17 F0RMAT(6X 2F9.3, F9.3, F9.5, F9.3, F11.2, 2F8.2, F9.5, 2F9.3,F6.0)

18 F0RMAT(6X 2F9.3, F9.4, F9.4, F9.4, F11.2, 2F8.2, F9.5, 2F9.3,F6.0)

19 F0RMATC6X 2F9.3, F9.5, F9.3, F9.5, F11.2, 2F8.2, F9.5, 2F9.3,F6.0)

C CONSTANTS OF EQNSTATE-8, 5/11/73, AT 10.46, NF = 9.

C NOTE CONSTANT, DE, IN PSI, XEF(T,D).

20 TTRP=90.68 $ PTRP=0. 1 17435675 % DTRP=28.147 * QP*1. 01325

21 TCRT=190.555 t OCRT=10.0 J PCRT=PSATF ( TCRT

)

22 AG = AL = 0.2 t BE = 7 t DE = 1 <? GKK = 0. 0831434 t GK = DTRP*r.KK

23 Bl = 1.599101971 % B2 = 2.483786733 $ CI = -1.076088156

24 C2 = 10.482192754 t C3 = -22.556715826 f C4 = 12.289665719

25 El = 0.993750233 t E2 = -1.243035021 I E3 = 0.318523715

27 EZZ = 4.1868*2191.3 f WK = 100000/16.043

28 QPP = 14.69595/QP J TA = 174.516 $ TB = 220

C DERIVE THE J-T INVERSION CURVE.

99 CALL JTLOCUS

C TABULATE THE SATURATED LIQUID FUNCTIONS.

100 CALL TABLIQ

CC COMPUTE THERMOFUNCTIONS ON ISOBARS - C EVERY ISOBAR STARTS ON THE MELTING LINE AT T UNOER TCRT.

C LET THE FIRST ISOBAR IE AT P = PTRP.

C ISOBARS AT P UNDER PCRT TRAVERSE THE DOME.

C SPECIAL CASES FOR REGION X AT TA=T=TB, DEN ABOVE DCRT.

140 NI = 65 t PSK1) = PTRP*QPP

141 READ 15, (PSKI) ,1 = 2, NI)

142 DO 300 1 = 1, NI $ PRINT 16, PSKI) * P = PSKD/QPP

143 CALL MELTHERM $ CALL CONVERT J V = 1/DFN

145 PRINT 17, TF,TR,DEN,V, OPDT,DPOD, E,H,S, CV,CP,W

146 IT = TF/10 - 1 * IF(P.LT.PCRT) 154,200

C

C CASES FOR P LESS THAN PCRT.

154 K=L=0 J TS=FINDTSF(P) * TX = TS * 10/1.8

155 DO 199 J=l,99 t JT=10*(IT+J) $ T=TT= 27 3. 15+ ( JT-32 ) /l .

8

157 IF(T.LT.TA) 158,175

C NORMAL CASES FOR P UNOER PCRT, T UNDER TA.

38
METHERM6 05/16/73

158 IF(T.LT.TS) 159,161

C CASE FOR COMPRESSED LIQUID AT T UNDER TA.

159 CALL THRMOLIQ I CALL CONVERT I V = 1/DEN

160 PRINT 17, TF,TR,DEN,\/, DPDT,DPDD, E,H,S, CV,CP,W t GO TO 199

161 IF(T.LT.TX) 162,183

C CASE FOR SATURATED LIQUID AND VAPOR.

162 IF(I.EQ.i) 163,164

163 PRINT 1<+ t GO TO 166

164 CALL SATLQTRM S CALL CONVERT J V = 1/DEN

165 PRINT 17, TF,TR,OEN,V, DPDT,OPDD, E,H,S, CV,CP,W S PRINT 14

166 CALL SATGSTRM * CALL CONVERT * V = 1/DEN

167 IF(P.GT.IO.O) 168,169

168 PRINT 18, TF,TR,DEN,V, DPDT,DPOD, E,H,S, CV,CP,W t GO TO 170

169 PRINT 19, TF,TR,DEN,7, DPDT,DPOD, E,H,S, CV,CP,W

170 T = TT * GO TO 133

C CASES FOR P UNOER PCRT, T OVER TA, IN REGION X. 175 IF(T.LT.TS) 176,178

C CASE FOR COMPR. LIQ. AT TA = T = TSAT IN REGION X.

176 CALL THERMOX $ CALL CONVERT $ V = 1/DEN

177 PRINT 17, TF,TR,DEN,V, OPDT,DPDD, E,H,S, CV,CP,W % GO TO 199

178 IF(T.LT.TX) 179,183

C CASE FOR SAT. LIQ. IN REGION X, AND SAT. VAPOR.

179 CALL THERMXL $ CALL CONVERT ? V = 1/OEN

180 PRINT 17, TF,TR,DEN,V, Q?DT,DPDD, E,H,S, CV,CP,W $ PRINT 14

181 CALL SATGSTRM « CALL CONVERT ? V = 1/OEN

182 PRINT 18, TF,TR,DEN,V, OPDT,DPDD, E,H,S, CV,CP,W $ T = TT

C CASES FOR HOMOGENEOUS DOMAIN, D UNDER DG , OR T OVER TC.

183 IF(JT.GT.SO) 184,188

18*t K = K+l $ JT = JT+10*K $ T = 273.15 + (JT-32)/1.8

185 IF(JT.GT.240) 186,183

186 L = L + l $ JT = JT+20*L $ T = 273.15 + (JT-32)/1.8

187 IF(JT.GT.44Q> 300,133

188 CALL THRMOGAS $ CALL CONVERT $ V = 1/DFN

189 IF(P.GT.IO.O) 190,191

190 PRINT 18, TF,TR,OEN,V, 0°DT,DPDD, E,H,S, CV,CP,W 3 GO TO 199

191 PRINT 19, TF,TR,DEN,V, DPDT,DPOD, E,H,S, CV,CP,W

199 CONTINUE

C

C CASES FOR P GREATER THAN »CRT.

200 K=L = $ DO 230 J = l,99 I JT = 10MIT+J) J T = 273. 15+ ( JT-32 ) /l .

8

201 IF(T.LT.TB) 202,220

202 IF(T.LT.TA) 203,205

203 CALL THRMOLIQ J CALL CONVERT t V = 1/DEN

204 PRINT 17, TF,TR,DEN,V, OfDT,DPDD, E,H,S, CV,CP,W * GO TO 230

205 IF(T.LT.TCRT) 211,205

206 PX = PVTF(T,DCRT> « IF(P.GT.PX) 211,225

C CASE FOR REGION X AT TA = T = TE, P ABOVE CRITICAL ISOCHCRE.

211 CALL THERMOX $ CALL CONVERT « V = 1/OEN

212 PRINT 17, TF,TR,DEN,V, DPDT,DPDD, E,H,S, CV,CP,W t GO TO 230

C CASES FOR HOMOGENEOUS DOMAIN, D UNDER DG , OR T OVER TC.

220 IFUT.GT.80) 221,225

221 K = K+l $ JT = JT+10*K J T = 273.15 + (JT-32)/1.8

222 IFUT.GT.240) 223,225

223 L = L+l % JT = JT+20»L ? T = 273.15 + (JT-32J/1.8

224 IFUT.GT.440) 300,225

225 CALL THRMOGAS J CALL CONVERT J V = 1/DEN

226 PRINT 17, TF,TR,DEN,V, DPDT,DPDD, E,H,S, CV,CP,W

230 CONTINUE

300 CONTINUE

999 STOP $ END

39
05/16/73

SUBROUTINE JTLOCUS

DERIVE THE J-T INVERSION CURVE. USE ROUTINE DELTAF ( T, 01 )

OIMENSION TT<99> ,TF<99) ,PP<99) ,DN<99>

OATA (DCRT=10.0) , ( TCRT=190 . 555)

1 FORMATC1H1 16X *THE JOULE-THOMSON INVERSION LOCUS FOR METHANE*//

1 12X 3HT,F 5X3HT,R 2X5HP,PSI 2X7HL8/CUFT

2 9X 3HT,F 5X3HT,R 2X5HP,PSI 2X7HLB/CUFT ) 2 FORMATC3X 2(F12.2, F8.2, F7.0, F9.2))

8 PRINT 1 J 00 25 1=1,62 $ TF(I) = -180 + 10*1

9 TT(I) = *»59.67 + TF(I) S T = TTCD/1.8 $ DX = 1.6

10 01 = DCRT* (2.70816 - 0.70263*T/TCRT) 5 IF(T-TCPT) 11,12,12

11 OL = DENLIQF(T) « IF(DI-DL) 25,12,12

12 SS = DELTAF(T,DI)

13 DO 20 IT=1,15

Ik D=DI-OX $ SL=DELTAF (T,0) $ D=OI+DX $ SP = OE LT AF ( T , D)

15 IF(SS-SL) 18,16,16

16 IF(SP-SL) 19,17,17

17 SS = SL J DI = DI - DX t GO TO 20

18 IF(SS-SP) 20,20,19

19 SS = SP I DI = DI + DX

20 DX = DX/2 $ D = DI S P = PVTF(T,D)

21 IF(T-TCRT) 22,23,23

22 PS = PSATF(T) t IF(P-PS) 25,23,23

23 PP(I) = l«».50377t»*P S ON(I) = 1.001532*0

25 CONTINUE

28 DO 29 J=l,31

29 PRINT 2, TF(J) , TT < J ) , PP (J) ,DN(J)

,

1 TFU+31) , TTU + 31) ,PP(J+31) ,DN(J + 31)

30 RETURN J END

05/16/73

FUNCTION DELTAF(T,0)

GET (T*DP/DT - 0*DP/DO) FOR THE J-T INVERSION CURVE.

COMMON/ 3/DPOT,02PDT 2, OPSDT, DPMCT

,

DPDO, DPDR , DTSDR , DTHDR

OATA (DCRT=10.0)

,

<TC^T=190 . 555)

1 IF(T-TCRT) 2,«»,<+

2 DL = DENLIQF(T) J IF(D-DL) 3,k,k

3 DELTAF = 1.0E+010 t RETURN

k P = PVTF(T,D) $ PX = DPDRF(T,D)

5 DELTAF = ABSF <T*DPOT-D*D°DD ) « RETURN t END

SUBROUTINE CONSAT

CONVERT SAT.LIQ. PROPERTIES TO BRITISH UNITS.

C0MM0N/3/0PDT,02P0T2,DPS3T,0PM0T,DPD0,DP0R,0TS0R,0TH0R

C0MM0N/6/TT,PS,DL,D0LDT,VG,VL,Q

COMMON/7/ TR,TF, CN,VS

COMMON/8/ P,T,OEN, E,H,S, CV,CP,W, WK

COMMON/9/ CSAT

DATA (EK = 37. 2910 55) , (SK=67

123912 ) , (DK = 1 . 00 15 32

)

1 TR = 1.8*TT $ TF = 32 + 1 . 8* (TT-273. 15

)

2 PS = 1<».503775*PS i 0°SDT = 8 . 057652<+*DPSDT

3 DL = DK*DL * DOLDT = . 556^0657*ODLDT

k VG = VG/DK $ VL = VL/DK $ Q=Q/EK $ E=E/EK t H=H/EK

5 S=S/SK S CSAT=CSAT/SK * CV=CV/SK J CP=CP/SK

6 W = 3.2808^*W S CN = 0.0578176*CN t VS = 0.067197*VS

9 RETURN t END

40
SUBROUTINE CONVERT

CONVERT FROM SI TO BRITISH UNITS.

COMMON/ 3/DPDT,D2PDT2,DPSQT,DPM0T,DPDO, DP DR , DTSOR , DTHOR

COMMON/7/ TR,TF, CN,VS

COMMON/8/ P,T,OEN, E,H,S, CV,CP,W, WK

OATA (EK = 37.291055) , (SK = 67.123912)

1 TR = 1.8*T J TF = 32 + 1 . 8* ( T-273. 15)

2 DEN = 1.001532*DEN t E = E/EK $ H = H/EK

3 S = S/SK * CV = CV/SK $ CP = CP/SK

< W = 3.2808<»»W $ CN = Q.0578176*CN $ VS = 0.067197*VS

5 DPDT = 8.057652^*DPOT « DPOO = 1<*. <*81591* DPOD

9 RETURN $ ENO

SUBROUTINE TABLIQ

TABULATE THE SATURATED LIQUID FUNCTIONS.

COMMON/l/AG,AL,BE,OE,GK, DCRT , PCPT , TCRT , DTRP, PTRP, TTRP

COMMON/ 3/0PDT,D2PDT 2, DPSOT, OPMOT , DPDO, BPOR, DTSOR ,DTHDR

COMMON/ 6/TT, PS, OL , DDL DT , VG , VL ,

Q

COMMON/7/ TR,TF, CN,*/S

COMMON/8/ P,T,OEN, E,H,S, CV,CP,W, WK

COMMON/9/ CSAT

1 FORMATdHl 13X *PROPERTIES OF SATURATED LIQUID METHANE* / ) 2 FORMAT (l^XlHT 8X1HT 3X1HP 5X3HDEN <*X5HV,GAS <*X5HV,LIQ 3X5H3P/DT

1 <fX6HODL/DT 3X5HQ,VAP / 10X5HOEG F <*X5HOEG R 6X3HPSI 1X7HL3/CUFT

2 2X7HCUFT/LB 2X7HCUFT/LB 3X5HPSI/R 1 X9HLB/CUFT /R 2X6HBTU/LB ) 3 F0RMATC6X 3F9.3, F3.3, F}.<*, F9.5, F3.<+, F10.5, F8.2)

* FORMATd^XlHT 8X1HP 7X1HE 7X1HH 8X1HS 7X2HCV 7X2HCS 7X2HCP 6X1HW /

1 10X5HDEG F 6X3HPSI 2X6H3TU/LB 2X6HBTU/L3 1X8H8TU/LB/R

2 1X8HBTU/L8/R 1 X8H3T'J/L B/R 1X8HBTU/LB/R 3XUHFT/S ) 5 F0RMAK6X 2F9.3, 2F8.2, F9.5, 3F9.3, F7.0)

FOR PAGE 1 OF TABLIQ.

9 TA = 17i».516 $ PRINT I $ PRINT 2 10 DO 25 J=l,37 t IF(J.EQ.l) 11,12

11 TT = TTRP I GO TO 15

12 IFU.EQ.37) 13,1^

13 TT = TCRT $ OG=DL=OCRT S VG=VL=1/DG $ GO TO 17

±k FT = -300 5»J S TT = 273.15 (FT-32)/1.8

15 DG = FINOSATF(TT,0> t VG = 1/DG

16 OL = FINDSATF(TT,1) $ JL = 1/DL

17 PS = PSATF(TT) % Q = 1 3 0* TT*DPSDT* ( VG- VL

)

18 IFU.EQ.37) 19,20

19 DDLOT = t GO TO 2<t 20 TS = TSATF(DL) f DDLDT = DTRP/DTSDR

2k CALL CONSAT

25 PRINT 3, TF,TR,PS, DL,VG,VL, DPSDT

,

DGLDT,Q

FOR PAGE 2 OF TABLIQ.

30 PRINT 1 $ PRINT c» $ 00 50 J=l,37 f IF(J.EC.l) 31,32

31 TT=TTRP J PS=PTRP S DL=DTRP * GO TO 38

32 IF(J.EQ. 37) 33,35

33 TT=TCRT $ PS=PCRT $ Z V = CS AT=CP=W=0

3k S=SSATF(TT) t E=ESATF(TT) J H = £ 100*PS/DCRT J GO TO <f9 35 FT = -300 + 5»J J TT = 273.15 + (FT-32)/1.8

36 PS = PSATF(TT) I DL = FINOSA TF (TT , 1

)

37 IF(TT.GT.TA) ^5,38

38 S = SSATF(TT) $ E = ESATF(TT) $ H = E + 100*PS/DL

39 PX = PVTF(TT,DL> « DDLOT = DTRP/DTSDR

kQ CV = CSAT + 100*TT*DODT*0DLDT/DL**2 ? PX = DPDRFCTT,DL>

<*1 CP = CV + 100*TT/DP0O*(OPDT/DL)**2

«f2 W = SQRTF(WK*CP*OPOD/CV> $ GO TO <t9 1*5 P = PS I CALL THERHXL

k9 CALL CONSAT

50 PRINT 5, TF,PS, E,H,S, CV,CSAT,CP, W 99 RETURN $ END

41
>-H

(/) Z

LdO

18.5 mol/

1

a c b

TEMPERATURE

Figure 1. Density-temperature phase diagram.

42
Table 1-A. The saturated vapor densities

10 T,K MOL/L CALCD PCNT

2 90.680 0.0157 0.0157 -0.03

i 91.000 3.0163 0.C163 0.09

2 92.000 3.0183 0.C183 -0.02

2 91*. 000 J. 0229 0.0229 0.01

1 95.000 J. 0255 0.0255 0.15

2 96.0C0 3.0283 0.0283 -0.00

2 98.000 3.0 347 0.0347 0.02

2 100.000 3.0422 0.0421 0.03

2 102.000 3.0538 0.C508 0.02

1 103.000 1.0557 0.0556 0.17

2 104.000 3.0608 G.C608 C.02

2 106.000 0.0722 0.0721 0.02

1 107.000 3.0736 0.0784 0.23

2 108.000 3.0851 0.0851 0.01

2 110.000 3.0997 0.0997 0.00

1 111.000 3.1081 0.1078 0.32

2 112. OuO 3.1162 0.1162 -0.00

2 111*. 000 Q.1347 0.1347 -0.01

1 115. 000 J. 1452 0.1447 0.33

2 116.000 3.1553 0.1553 -0.01

2 118.000 3.1731 0.1782 -0.C1

1 119.000 3.1912 0.1905 0.36

2 120.000 3.2035 0.2035 -0.O1

2 122.000 3.2314 0.2314 -0.01

1 123.000 3.247 3 0.2464 0.35

2 124.000 3.2621 0.2622 -0.01

2 126.000 3.2958 0.2959 -0.01

1 127.000 3.3151 0.3139 0.38

2 128.000 3.3327 0.3327 -0.01

2 130.000 3.3730 0.3730 -0.00

1 131.000 3.3961 0.3945 0.41

2 132.000 3.4169 0.4169 -0.00

2 134.000 3 .4646 0.4646 0.00

1 135. COO 3.49 20 0.4899 0.42

2 136.000 3.5154 0.5164 0.G0

2 138.000 0.5725 0.5725 0.01

1 139.000 3.6049 0.6023 0.43

2 11+0.000 3.6334 u.6333 0.01

2 142.000 0.6992 0.6991 0.00

1 143.000 0.7370 0.7340 0.41

2 144.000 3.7733 0.7703 G.00

2 146.000 J. 8471 0.e471 -0.00

1 147.0 3.8911 0.8878 0.37

2 148.000 0.9331 0.9301 -0.01

2 150. OLO 1.0136 1.C198 -0.01

1 151.000 1.0704 1.C672 0.30

2 152.000 1.1154 1. 1165 -C.02

2 154.000 1.2239 1.2211 -0.02

1 155.000 1.2730 1.2765 0.20

2 156.000 1.3338 1.3340 -0.02

2 158.000 1.4560 1.4562 -0.01

1 153.000 1.5221 1.5210 0.07

2 160.000 1.5834 1.5884 0.00

2 162.000 1.7322 1.7317 0.03

1 163.000 1.8063 1.8079 -0.09

2 164.000 1.8336 1.8874 0.07

2 166.000 2.3533 2.0567 C.13

1 167.000 2.1408 2.1471 -0.29

2 168.000 2.2465 2.2416 0.22

161b 169.067 2.3438 2.3472 0.07 1614 169.270 2.3687 2.3679 0.03

912 169.417 2.3858 2.3830 0.12

43
Table l-A. The sa .urated vapor densities (continued

ID T,K MOL/L CALCO PCNT

1612 169.it68 2.3331 2.3883 -0.01

910 169.601 2.t05* 2.*021 0.1*

908 lt>9.79i» 2.*236 2.*223 0.06

1 171.000 2.5388 2.5526 -0.5*

1716 173.088 2.7972 2.797* -C.01

1711* 173.290 2.8203 2.8225 -C.08

1712 173. *b9 2.8*57 2.6*75 -0.06

1J12 173. *73 2.8*30 2.8*55 0.09

1 J 10 173.675 2.3700 2.8711 -0.0*

10 08 173.857 2.8935 2.89** -0.03

1 175.000 3.0199 3.0*62 -0.87

1815 177. 09* 3.3501 3. 351* -0.0*

181* 177.292 3.3801 3.3823 -0.C6

111* 177.328 3.3853 3.3879 -0.05

1312 177. *85 3.*108 3.*128 -0.06

1112 177.509 3.*219 3.*16b 0.13

1110 177.700 3.*602 3.**72 0.38

1915 181.105 -+ . o63 *.C659 0.01 191* 181.30* -t.1077 *.1072 0.01

1213 181.389 *.1269 *.1250 0.05

1912 181.506 4.1*36 *.1*98 -C.01

1211 181.589 +.1636 *.1675 -0.05

1209 181.768 .2042 *.2062 -0.05

1515 183.117 *.5212 *.5188 0.05 151* 183.322 4.570* *.5700 0.01

1512 183.51* 4.6139 *.6189 0.00 1316 18*. 125 •+.7822 4.781* 0.02 2108 18*. 087 *.7825 *.7710 0.2*

2107 18*. 285 +.8263 *.8258 0.01

13 1* 18*. 370 *.8*62 *.6*98 -0.07

2106 18*.*71 -.8797 *. 8786 0.02

1312 18*. 510 *.8876 *.8898 -0.0*

6 165.030 5.0330 5.0**5 -0.13

6 186.030 5.38*0 5.37*8 0.17

2238 186.103 5.*077 5.*007 0.13

1<»16 185.129 5.*096 5.*101 -0.01

1-+1* 186.319 5.*795 5.*798 -0.01

2207 186. 30* 5.*827 5.*7*2 0.15

22G6 186. 5C1 5.5571 5.5*87 0.15 1*12 186.518 5.5591 5.5552 0.07

6 187.031 5.785C 5.7628 O.hO

6 188.031 6.2750 6.239* 0.57

2308 188.1*0 6.2930 6.2988 -0.09

2307 188.3*3 6.*067 6.*150 -0.13

23G6 188.5*5 6.5278 6.5382 -0.16

6 189.032 6.9130 6.8756 0.61

5 189.765 7.5510 7.566* -C.20

5 189.785 7.5510 7.5906 -0.52

5 190.0*6 7.9350 7.9525 -0.22

5 190.066 '.9350 7.9850 -0.63

6 190.032 7.960G 7.9303 0.37

7 190. 070 3 . J 7.9916 G.ll

7 190.170 3.1700 8.1692 0.01

7 190-270 8.3600 8.3799 -0.2*

5 190.279 8.3920 8.*011 -0.11

5 190.299 8.3920 8.**97 -0.69

7 190.370 8.6210 8.6**9 -0.29

7 190. *70 9.0000 9.02*8 -0.28

5 190. *80 9.1610 9.C758 0.93

5 190.500 9.1610 9.1917 -0.3*

5 190.52* 9.6860 9.3708 3.25

NP 123, RMSPCT = 0.376

44
Table 1-B. The saturated liquid densities

10 T,K MOL/L CALCO PCNT

5 190.530 1C. 059 10.790 -7.27

5 190.515 10.796 10.936 -1.30

5 190.442 11.357 11.362 0.04

5 190.1*62 11.357 11.270 0.86

7 190.470 11.410 11.229 1.59

7 190-370 11.790 11.628 1.37

5 190.316 11.824 11.786 0.32

5 190.336 11.824 11.730 0.79

7 190.270 12.070 11.904 1.38

7 190.170 12.270 12.123 1.20

5 190.048 12.397 12.346 G.41

5 190.068 12.397 12.312 C.68

7 190.070 12.440 12.309 1.05

6 190.032 12.474 12.373 0.81

5 189. 7l7 12.879 12.830 C.38

5 189.311 13.310 13.255 C.34

5 189.331 13.300 13.236 G.48

& 189.032 13.578 13.506 0.53

ll<t 188.000 14.234 14.242 0.29

5 188.031 14.235 14.223 0.44

5 187.469 14.532 14.549 C.22

5 187.489 14.532 14.538 0.30

3 187.031 14.8 56 14.779 0.38

113 186. CCO 15.236 15.260 0.18

6 186.030 15.312 15.246 0.36

6 185. Q3C 15. 710 15.655 0.35

112 184.000 16.054 16.031 C.14

6C + 184. DC 1 6 . J 6 16.031 C.18

111 180. OCO 17.249 17.230 0.11

603 180.000 17.2 54 17.230 0.14

1 175.053 16.390 18.389 o.co

110 175. 0^0 18.417 18.400 C.C9

602 175.000 18.420 18.400 0.11

109 170. 0C0 19.337 19.372 0.08

1 169.326 19.492 19.492 -o.uo

108 165.000 20.234 2C.219 0.07

1 163.659 20.428 20.431 -C.C1

107 160. 00 2G.991 20.981 0.05

1 157.199 21.379 21.378 0.00

106 155.000 21.o3b 21.678 0.04

1 151.553 22.130 22.129 0.00

105 150.000 22. 329 22.325 0.02

601 150.000 22.332 22.325 0.C3

1 145.448 22.330 22.880 o.co

104 1h5.0CO 22.932 22.933 -0.00

103 140. uod 23.530 23.508 -C.03

1 139.352 23.578 23.580 -0.01

102 135.000 24. 0+1 24.055 -C.C5

1 133.878 24.176 24.174 0.01

1 133.773 24.186 24.185 0.00

101 130.000 24.558 24.578 -0.G8

1 129.657 24.611 24.613 -0.G1

1 125. B25 24.999 24.999 -0.00

1 121.893 25.388 25.384 C.01

1 117.746 25.782 25.779 0.01

1 113.772 26.146 26.149 -0.01

1 109.611 26.527 26.526 0. 00

1 105.165 26.916 26.920 -0.02

1 101.434 27.243 27.244 -0.00

1 97.173 27.605 27.607 -0.01

1 93.512 27.910 27.913 -o.ci

P = 61, RMSPCT = 1.055

45
Table 1-C. The vapor-liquid saturation temperatures

ID T,K CALC PCNT MOL/L CALC PCNT OTS/DD

2 90.68G 90.681 -0.00 0.0157 0.0157 0.01 539.6170

1 91.000 91. 01

-0. 01 0. 0163 0.0163 0.12 523.2873

2 92.000 92. 003 0. 00 0.0163 0.0183 -0.00 477.9297

2 9*. GOO 94.003 -0. 00 0.0229 0. 0229 0.00 40 0.7747

1 95.000 95.013 -0.01 0.0255 0.0255 0.14 367.8597

2 96.000 95.998 0.0G 0.0283 0.0283 -0.02 339.1716

2 98.000 98.000 0. 00 0.0347 0.0347 -0.00 289.3527

2 100. GOO 10 J. 301 -G.00 0.0422 0.0422 0.01 248.7637

2 102. GOO 102.303 -0.G0 0.05G8 0.G508 0. 30 215.4135

1 103. GOO 103.017 -0. 02 0.0557 0. 0556 0.15 200.7235

2 104. COO 104.001 -0. OG 0.0608 0.0606 0.01 187.7496

2 106.000 1G6.001 -G.GO 0.0722 0. 7 22 0.01 164.6375

1 107. GOO 107.027 -0.03 0.0786 0. 0784 0.22 154.2492

2 108. GOO 108. 001 -O.G0 0.0851 0.0851 0.01 145.1854

2 110.000 110. 303 0.03 0.0997 0.0998 -0.00 128.7044

1 111. GOO 111.042 -0. 04 0.1081 0. 1078 0.32 121.1022

2 112.000 112.003 0. 00 0. 1162 0. 1162 -0. 00 114.6394

2 114.000 113.999 0.00 0.1347 0.1347 -0.01 102.5721

1 115. GOO 115.047 -0. 04 0.1452 0. 1447 0.34 96.9191

2 llo.GOO 115.999 0.00 0.1553 0.1553 -0.01 92.1464

2 118. COO 117. 999 0. 00 0.1781 0. 1782 -0. 01 83.0959

1 119. COO 119.055 -0.05 0.1912 0.1905 0.37 78.7909

2 120. COC 119.999 0. 00 0.2035 C. 2 35 -0.01 75.1942

2 12 2.0 121.998 c.oo 0.2314 0.2314 -0.01 68.2622

1 12 3. GOO 123. 058 -0. 05 0. 247 3 3. 2464 0.36 64.9313

2 124. COO 123.939 0. 03 0.2621 0. 2621 -0.01 62.1479

2 126.000 125.999 0.00 0.295 8 0.2958 -0.00 56.7308

1 127.C0 127.067 -0.05 0.3151 0.3139 0.39 54.0902

2 128. COO 128.003 -0. 00 0. 3327 0.3327 0.00 51.9089

2 13u .000 130.301 -C. 00 0.3730 0. 3730 0.01 47.5991

1 131.000 131.076 -0.06 0. 3961 3.3944 0.42 45.4697

2 132.000 132.302 -0.00 0.4169 0.4168 0.01 43.7308

2 134.000 134.302 -0. OG 0.4646 0.4645 0.01 40.2444

1 135.000 135.082 -0. 06 0.4920 G. 4899 0.43 38.5C38

2 136.000 136.003 -C.OO 0.5164 C.5163 0.02 37.0898

2 138.000 138.004 -0.00 0.5725 C. 5724 0. 02 34.2259

1 139.000 139.087 -0.06 0.6049 0.6022 0.44 32.7830

2 140.003 140.004 -0. 00 0.6334 0.6333 0.02 31.6170

2 142.000 142.303 -0.03 0.6992 0.6991 0.02 29.2325

1 143. COO 143. 08o -0. 06 0.7370 0.7339 0.42 28. 0250

2 144.000 144.002 -0.00 0.77C3 0.7702 0.01 27. 0461

2 146. GOO 146.001 -0.00 0.8471 0.8471 0.00 25.0355

1 147. GOO 147.083 -0. 05 0.8911 G. 8878 0.37 24.0165

2 148. COO 147.999 C 00 0.9301 0. 9301 -0. 00 23. 1816

2 150.000 149.997 0.00 1.0196 1.G198 -0.02 21.4675

1 151.0 151.064 -0. 04 1.0704 1.0673 0.29 20.6035

2 152.000 151.994 0.00 1.1164 1. 1166 -0.03 19.8781

2 154. GOO 153.992 0. 01 1. 2209 1. 2213 -0.03 18.4009

1 155.000 155.041 -0.C3 1.279U 1.2767 0.18 17.6668

2 156.000 155.991 0.01 1.3338 1.3343 -0.04 17.3241

2 158.000 157.991 0.01 1.4560 1.4566 -0.04 15.7372

1 159. COO 159. 013 -0. 01 1. 5221 1. 5214 0.34 15.1133

2 16 0.00 159.993 0. 00 1.5884 1.5889 -0.33 14.5308

2 162.000 161.998 G. 00 1.7322 1.7323 -0.01 13.3960

1 163. COO 162.971 0.G2 1.8C63 1. 8085 -0.12 12.8693

2 164. GOO 164. 303 -0.00 1.8886 1.8880 0.03 12.3245

2 166. GOO 166.02-f -0. 01 2.3593 2.0573 0.10 11. 3C85

1 167.000 166.927 0. 04 2.1408 2.1476 -0.32 10. 8703

2 168. COO 168.047 -0.03 2.2465 2.2419 0.20 10. 3399 1616 169.067 169.083 -0.01 2.3488 2.3475 0.06 9.8630 1614 169.270 169.276 -C. 00 2.3687 2.3681 0.02 9.7740

912 169.417 169.442 -0.01 2.3858 2.3832 0.11 9.6985

46
Table 1-C. The vapor-liquid saturation temperatures (continued)

10 T,K CftLC PCNT MOL/L CALC PCNT OTS/DO

1612 169.468 169.464 0.00 2.3881 2.3885 -0.02 9.6884

910 169.601 169.631 -0.02 2.4054 2.4022 0.13 9.6130 9J8 169. 794 169.806 -0.01 2.4236 2.4224 0.05 9.5345

1 171.000 170.876 0. 07 2.5368 2.5525 -0.54 9. 0586 1716 173.088 173.091 -0.00 2.7972 2. 7969 0.01 8. 1034 1714 173.290 173.277 0.01 2.8203 2. 8219 -0.06 8.0246 1712 173.489 173.483 0.01 2.8457 2.8469 -0.04 7.9391 1012 173.473 173.498 -0. Gl 2. 8480 2. 8449 0.11 7.9314

1G10 173.675 173.672 0.00 2.8700 2.8704 -0.02 7.8584 10u8 173.857 173.855 0.00 2.8935 2.8937 -0.01 7.7813

1 175.0 174.813 0.11 3.0199 3.0453 -0.64 7.3825 1816 177.094 177. 093 0. 00 3. 3501 3.3502 -0.00 6.4505 isi4 177.292 177.285 0. 00 3.38C1 3.3811 -0.03 6. 37 28 111-t 177.328 177.325 0.00 3. 3 86 3 3.3868 -0.01 6.3568 1812 177.485 177.483 0.00 3.4108 3.4116 -0.02 6.2942 1112 177.509 177.543 -0. G2 3.4209 3.4154 0.16 6.2686 1113 177.700 177.783 -0. 05 3.4602 3.4460 0.41 6. 1701 1916 181.105 181.108 -0.00 4.0663 4.0657 0.02 4.8413 191H 181.30 4 181.307 -0. 00 4. 1077 4. 1071 0.01 4.7619 1213 181.389 181.398 -O.G0 4.1269 4. 1250 0.05 4.7256 1912 181.506 181.505 G.GO 4. 1496 4.1499 -0.01 4.6829 1211 181.589 181.579 0.01 4.1656 4. 1677 -0.05 4.6531 12u9 181.768 181.753 0. 01 4.2042 4.2065 -0.05 4.5819 1516 183.117 183.122 -0. 00 4.5212 4.52G0 0.03 4.0358 1514 183.322 183.318 0.00 4.57G4 4.5713 -0.02 3.9569 1512 183.514 183.508 o.co 4.6189 4.6204 -0.03 3. 8805 1316 184.125 18*. 122 0.00 4.7822 4.7831 -0.02 3.6335 2108 184. C87 184.123 -0. G2 4.7825 4.7727 0.21 3.6331 2107 184.285 184.283 0.00 4.8263 4. 8276 -0.03 3.5694 1314 184.370 184.351 0.01 4.8462 4. 8515 -0.11 3.5408 2106 184.471 184.469 0.00 4.8797 4.6803 -0.01 3.4931 1312 134.510 18*.<+97 0.01 4.8876 4.8915 -0.08 3.4820

o 185.030 185.005 0.01 5.0380 5.0458 -0.15 3.2759

b 186.030 186.062 -0. 02 5. 3840 5. 3731 0.20 2.6434 2208 186.103 186.123 -0.01 5.4077 5.3986 0.17 2.8158 1416 186.129 186.134 -0.00 5.4096 5.4078 0.03 2.8136 141H 186.319 186. 323 -0.00 5.4795 5.4762 0.06 2.7334 2207 186. 30h 186.3 37 -G. 02 5.4827 5. 47C7 0.22 2.7298 2206 18o.501 186.537 -0.G2 5.5571 5.5436 0.24 2.6467 1412 186.518 186.542 -0.01 5.5591 5.5500 0.16 2.6445

t> 187.031 187.114 -0.04 5.7860 5.7515 0.60 2.4C42

6 188.031 188.17-+ -G. 08 6.2750 6. 2026 1.15 1.9420 2308 188.140 188.209 -0.G4 6.2930 6. 2574 0.57 1.9262 23L7 188.343 188.423 -0. 04 6.4G67 6. 3636 0.67 1.8278 2306 188.545 188.633 -0.05 6.5278 6.4748 0.81 1.7257

6 189.032 189.249 -0. 11 6.9180 6.7702 2.14 1.4101

5 189.765 189.984 -0. 12 7.5510 7.3317 2.90 G.9129

5 189.785 189.984 -0. 10 7.5510 7.35C2 2.66 0.9129

5 190.046 190.277 -0.12 7.9350 7.62C9 3.96 0.6103

5 19 0.066 190.277 -0. 11 7.9350 7.6444 3.66 0.6103

6 190.032 190.292 -0. 14 7.9600 7.6047 4.46 0.5909

7 19 0.070 190.315 -0.13 8.000C 7.6492 4.38 0.5599

7 190.170 190.399 -0.12 8.1700 7.7766 4. 82 0.4313

7 190.270 190.468 -0. 10 8.3600 7.9244 5.21 0.2978

5 190.279 190.477 -0. 10 8.392 7.9391 5.40 0.2769

5 190.299 190.477 -0.09 8. 3920 7.9728 5.00 0.2769

7 190.370 190.52+ -0.08 6.6200 8. 1066 5.96 0. 1461

7 190.473 190.553 -0.04 9.000G 8.3676 7.03 0.0 2 26

5 190.480 190.555 -0.04 9.1610 8. 4032 8.27 0.0056

5 190.500 190.555 -0.03 9.1610 6.4851 7.38 0.0G56

5 190.524 190.555 -0. 02 9.6860 8. 6164 11.04 0. 0000

5 190.530 190.555 -0.01 10.3593 11. 4638 -13.97 -0.0000

5 190.515 190.555 -0.02 10.7960 11.5780 -7.24 -0.0018

47
Table 1-C. The vapor-liquid saturation temperatures (continued)

10 T,K CALC PCNT MOL/L CALC PCNT OTS/DD

5 190. **2 190.539 -0. 05 11. 3670 11. 9013 -*.70 -0. 0800

5 190. *62 190.539 -0.0* 11.3670 11. 8315 -*.09 -0. 0800

7 193. *70 190.535 -0. 03 ll.*100 11.80C9 -3.*3 -0.0930

7 190.370 190. *73 -0. 05 11.7900 12.1022 -2.65 -0.2*80

5 190.316 193. *6* -0.08 11.82*0 12.2228 -3.37 -0.26*8

5 190.336 190. *6* -0.07 11.82*0 12. 18C1 -3.01 -0.26*8

7 190.27 190.383 -0.06 12.0700 12. 3127 -2.01 -0.3960

7 190.170 190.292 -0.06 12.2700 12.*827 -1.73 -0.5116

5 190.0*8 190.223 -0. 09 12. 3970 12.6587 -2.11 -0.5876

5 190.068 190.223 -0.08 12.3970 12.6316 -1.89 -0.5876

7 19 0.07 193.197 -0. 07 12.**00 12.6289 -1.52 -0.6136

o 190. C32 190.175 -0.08 12.*7*0 12.6799 -1.65 -0. 63*2

5 189.707 189. 868 -0.09 12.8790 13.051* -1.3* -0.8835

5 189.311 189. **2 -0. 07 13.3000 13.*109 -0.83 -1.1*36

5 189.331 189. + *2 -0.06 13. 3000 13.39*3 -0.71 -1. 1*36

6 189.032 189. 1 J J -0.0* 13.5783 13.6292 -0.38 -1.31*9

lit 188.000 188.318 -0.01 1*.2837 1*.29*2 -0.07 -1.7510

6 188.031 18 8.316 0. 01 1*.2850 1*. 2763 0.06 -1.7518

5 187. *69 187. *68 0.00 1*.5820 It. 5816 0.00 -1.9381

5 187. *89 187. +69 0.01 1*.5820 1*.5713 0.07 -1. 9381

b 187.031 186.955 0.0* 1*.8360 1*.7999 0.2* -2.0998

113 186.000 185.9** 0. 03 15.286* 15.2629 0.15 -2.393*

6 186.030 185. 906 0.07 15.3020 15.25C0 0.3* -2.*038

185.030 18*. 873 C 09 15.7100 15. 6*98 0. 38 -2.6790

112 184.100 183.903 0.05 16.0539 16.0221 0.20 -2.9185

6G* 18*. COO 183.893 0. 06 16.3599 16.0221 0.2* -2.9227

111 180.000 179.893 0.06 17.2*91 17.2222 0.16 -3.8051

60 3 183.00 179. 873 0. 07 17.25*0 17. 2222 0.18 -3.8089

1 175.053 175.3*3 0. 01 18.3903 18.3872 0.02 -*.7202

110 175. COO 174.91-* 0. 05 1B.*167 18. 3985 0.10 -*.7*22

6u2 175.000 17*. 896 0.06 18.1.20* 18.3985 0.12 -*.7*52

lu9 170.000 lb9. 921 0. 05 19. 3869 19. 3726 0.07 -5.5531

1 169.326 169.333 -0. 00 19.*920 19. *932 -0.01 -5.6*17

10 8 165. COO 16*. 917 0.05 20.2335 20.2203 0.07 -6.2671

1 163.659 163.682 -0.01 20.*28G 20.*316 -0.02 -6.*305

107 16J.G00 159.932 0. 0* 20.9906 20.9808 0.05 -6.9001

1 157.199 157.193 0.01 21.3790 21.3777 0.01 -7.2206

1C6 155.000 15*. 936 0. 0* 21.6858 21. 6772 0.0* -7.*71*

1 151.553 151.537 0.01 22.1300 22. 1280 0.01 -7.8305

Up 15 3.0 1*9.962 0.03 22.3292 22.32** 0.02 -7.9901

6C1 150.000 1*9.9*2 0.0* 22.3316 22.32** 0.C3 -7.9920

1 1*5. **a 1*5. +*3 0. 01 22.8800 22.8791 0.00 -8.*268

10* 1*5.C0 1*5. 0G1 -0. 00 22.9320 22.9321 -0.03 -8.*677

103 1*0 .000 1*0.365 -0.05 23.t999 23. 5073 -0.03 -8.9116

1 139.352 139.367 -0.01 23.5780 23.5797 -C.01 -8.9723

102 135.000 135.126 -0.09 2*. 0*1* 2*. 05*9 -0.06 -9. 3310

1 133.878 133.86+ 0.01 2*. 1760 2*. 17*5 0.01 -9.*3*7

1 133.773 133.769 0. 00 2*. 1860 2*. 1656 O.CO -9.**2*

101 130. GOO 130.202 -C.16 2*. 5581 2*. 5789 -0.08 -9.7282

1 129.657 129.687 -0.02 2*. 6110 2*. 61*0 -0.01 -9.7688

1 125.825 125.839 -0. 01 2*. 9990 25. 000* -0.01 -10.06*8

1 121.893 121.856 0. 02 25.3880 25.385* 0.01 -10.3589

1 117.71*6 117.727 0.02 25.7820 25.7802 0.01 -10.6521

1 113.772 113.801 -0.03 26.1*6 26.1*87 -0.01 -10.9166

1 139.611 109.591 0. 02 26.5270 26.5252 0.01 -11.1833

1 105.165 105.193 -0.02 26.9160 26.9182 -0.01 -ll.**0*

1 101. *3* 101. h 16 0. 02 27. 2*30 27. 2*1* 0.01 -11.6*03

1 97.173 97.165 0.01 27.6050 27.60*3 0.00 -11.8390

1 93.512 93.532 -0.02 27.9100 27.9116 -0.01 -11.9836

NP = 18*, TSRMSPCT = 0.0*5, ONRMSPCT = 2.185

48
Table 2-A. The second virial coefficient

5. 050000000+002 1.697^31768+0 01 -8. 005503820+-001

1. 235409580 + 002 -9.2601351+05 + 01 i+. 2971+12052+001

ID T,K T/TT B* CALC PCNT

3 110.830 1.22221 -3.3010 -3. 311+3 -0.1+0

3 112.1+30 1.23985 -3.1990 -3.2037 -0.15

3 ll<+.i+i+C 1.26202 -3.0780 -3. 0750 0.10

3 116.780 1.28783 -2.9550 -2. 9379 0.58

3 121. 240 1.33701 -2.71+50 -2.7085 1.35

1* 126.571 1.3958C -2.1+227 -2.1+780 -2.23

3 128.830 1.42071 -2. 1+1+30 -2. 3918 2.11+

2 131.920 1.45479 -2.21+00 -2. 2831 -1.89

<+ 135.981+ 1.49960 -2.1520 -2. 151+0 -0.09

k 147. 581 1.6271+9 -1.8500 -1. 8505 -0.03

k 158.916 1.75249 -1.6151 -1.6181+ -0.21

5 168.000 1.8 5 267 -1.1+750 -1. 1+636 0.78

< 173.507 1.9134+0 -1.3763 -1.3800 -0. 27

5 176.000 1.94089 -1.31+90 -1. 31+1+3 0.35

3 173. 4 40 1.96780 -1.3220 -1. 3106 0.87

5 184.000 2.02911 -1.2380 -1. 2 380 0.00

2 191.090 2.10730 -1.1631 -1. 1527 0.90

«t 191.129 2.10773 -1.11+29 -1. 1523 -0.81

5 192. COO 2.11731+ -1.1390 -1. 11+23 -0.29

5 200.000 2.20556 -1.0510 -1. 0558 -0.1+6

2 200.030 2.20539 -1.0668 -1. 555 1.07

3 202.520 2.23335 -1.031+0 -1. 0302 C.37

5 210.000 2.3158'+ -0.9530 -0. 9586 -0.59

5 220.000 2.42611 -0.8660 -0. 8719 -C.67

3 221.130 2.U3858 -0.8580 -0. 8626 -0.51+

5 230.000 2.53639 -0.7890 -0.791+1 -C.64

5 240.000 2.61+667 -0.7200 -0.721+0 -0.56

2 240.020 2.61+689 -0.7272 -0.7239 0.1+6

3 243.820 2.68880 -0.7030 -0.6991 0.56

5 260.000 2.86723 -0.6020 -0.6035 -0.25

1 273.150 3.01221+ -0.5335 -0. 5361 -0.1+8

2 273.150 3.01221+ -0.5328 -0. 5361 -0.61

3 273.170 3.0121+6 -0.5370 -0. 5360 0.19

5 280.000 3.08778 -0.5050 -0.501+1 0.17

1 298.142 3.28785 -0.1+282 -0. 1+281+ -0.01+

5 300.000 3.30 831+ -0.4230 -0.1+213 O.i+l

1 303.141 3.31+298 -0.1+091 -0. 1+095 -0.1C

5 320.000 3.52889 -G. 3540 -0. 3515 0.72

1 3 2 3.1U0 3.56352 -0.31+23 -0. 31+15 0.24

5 340.000 3.71+91+5 -0.291+0 -0. 2920 0.70

1 348.143 3.83925 -C.2736 -0. 2702 0.15

5 360.000 3.97000 -0.21+20 -0. 21+07 0.55

1 373.150 i+. 11502 -0.2100 -0. 21G6 -0.29

5 330.000 4.19056 -0. 1970 -0. 1959 0.55

1 398.160 i». 39082 -0.1587 -0. 1598 -0.71

5 i+OO.OOO 4. 1+1112 -C.1570 -0. 1561+ 0.1+0

1 423.170 4. 66663 -0.111+0 -0. 1157 -1.1+5

1 448.182 4. 9421+6 -0. 0756 -0. T765 -1.18

5 (+50.000 k. 96251 -0.071+0 -0. 0738 C.25

1 473.193 5.21827 -0.01+16 -0. Ci+11 1.25

3 136. 740 1.50791+ -2.1890 -2. 1315 2.70

3 148.280 1.63520 -1.8770 -1. 831+7 2.31

5 160.000 1. 761+1+5 -1.6190 -1.5987 1.27

3 162.300 1.78981 -1.581+0 -1. 5580 1.67

2 215.030 2.37131 -0.9259 -0. 9138 1.33

i <+98.203 5.1+91+08 -0. 0116 -0. 0085 36.85

NP = 50, RMSPCT = 0.786

49
Table 2-B. The third virial coefficient

39. 92200 G. 36212 0. 83584+ 18. 69531 9. 15517

10 T,K T/TT C* CALC PC NT

k 135.984+ 1.4+996C -0.14*97 -0. 14*97 0. 00

< 14+7.581 1.6274+9 0. 1950 0. 195P 0.02

k 191.129 2.10773 0. 3990 0. 3990 -0.00

1 273.150 3.0122** 0. 2620 0. 2634* -0.54+

1 298.14+2 3.28785 0.2370 0. 2358 0.52

1 303.14+1 3.34+298 0.2320 0. 2310 C.42

1 323. mc 3.56352 0.2150 0. 214*4* 0.30

1 34+8. l<+3 3.83925 0.1975 0.1976 -0.06

1 373.150 <+. 11502 0. 1834* 0. 1844 -0.52

1 398.160 4*. 3 92 8 2 0.1727 0. 17 37 -0.55

1 ^23.170 <+. 66663 0. 164*0 0. 164*9 -0.53

1 4^8.182 <+. 94+24+6 0.1535 0. 1575 0.60

1 t+73.193 5.21827 C. 15 14 0. 1513 C.04+

1 t+98.203 5.4+94+08 0. 14*65 0. 14*60 C.33

i» 126.571 1.3958C -2. C500 -0. 7277 161.70

i* 158.916 1.75249 G.3580 0. 3399 5.33

k 173. 5C7 1.91340 0.4*3 81 0.4+010 9.26

2 191.090 2.10730 0.4,74*1 0. 3 99C 18.81

2 2QQ.0 3U 2.20589 0. 4+351 0. 3860 12. 71

2 215.0 30 2.37131 0.4,169 0. 3586 16.27

2 2<+0 .020 2.64689 0.3508 0. 3125 12.25

2 273. 15G 3. 0122*. C. 2670 0. 2634+ 1.34+

HP = !<, RMSPCT = C393

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51
Table 4. Comparison of experimental and calculated P-P-T values

The following pages compare experimental P-P-T (compressibility) data with

densities and pressures computed by the equation of state (6). The first column identifies sources of the data (as in table 3) --

ID = 2, Via Virial and Vapor-Pressure equations;

ID = 3, Vennix [66];

ID = 4, van Itterbeek [65];

ID = 6, Douslin [17];

ID = 8, Kvalnes [41];

ID = 10, Cheng [9];

ID = xxx, xxxx, this laboratory [30],

The equation of state was adjusted only to data of ID - 2, 6 and this laboratory.

Remaining data validate our extrapolation to higher pressures. Density deviations should

be ignored near the critical point, and pressure deviations should be ignored for compressed liquid at low temperatures for reasons given in the text. A few of Vennix' data

near the critical point have spurious, extreme density deviations because our computer

search assigns the opposite phase via eq (6), (i.e. vapor vs. liquid).

52
METHANE EQUATION OF STATE

T,K MOL/L CALCO O.PCT

2 150.000 1.0000 1.0007 -0.07

2 155. 000 1. 0000 1.0038 -0.08

2 160.000 1. 0000 1.0007 -0.07

2 165.000 1.0000 1.0006 -0.06

2 170.000 1.0000 1.003* -0.0*

2 175.000 1.0000 1.0003 -0.03

2 lad. 000 1.0000 1.0031 -0.01

2 185.000 1. 0000 1.0030 -0.00

2 1*0.000 1. 0000 0.9339 0.01

2 195.000 1.0000 0.9338 0.02

2 200.000 1.0000 0.9338 0.02

2 205.000 1.0000 0.93 38 0.C2

2 210.000 1.UO0O 0.9397 0.03

2 215.000 1.0000 3.9998 0.02

2 220.000 1.0000 0.9338 0.02

2 225.000 1.0000 3.99 38 0. 02

2 230.000 1.0000 0.9398 0.02

2 235.000 1.0000 0.9339 0.01

2 240.000 1. 0000 0. 3339 0.01

2 2it5.000 i. oooo 3.99 39 0.01

2 250.000 1.0000 1.0030 0.00

2 255.000 1.0000 1.0000 0.00

2 260.000 1.0000 1.0030 -0.00

2 265. 000 1. 0000 1.0000 -0.00

2 270.000 1. 0000 1.0031 -0.01

2 170.000 2. 0000 1.9396 0.02

2 175. 000 2. 0000 1.9993 0. 0*

2 180.000 2. 0000 1.9390 0.05

2 165.000 2.0000 1.9938 0.06

2 130.000 2.0000 1.9956 0.07

2 195.000 2. OOuO 1.9936 0.07

2 200.000 2. 00G0 1.99 3 5 U.07

2 205.000 2.0000 1.9936 0.07

2 210.000 2.0000 1.9937 0.O7

2 215.000 2.0000 1.3338 0.06

2 220.000 2.0000 1.99 3 0.05

2 225.000 2. 0000 1.9992 0.0*

2 230.000 2.C000 1.993* 0.03

2 235.000 2.0000 1.9995 0.02

2 2 1*0 .000 2.0000 1.9997 0.01

2 2*5. 000 2. 0000 1.9939 0.01

2 250.000 2.0000 2.0000 -0.00

2 255.000 2.0000 2.0032 -0.01

2 260.000 2.000U 2.0033 -0.01

2 265. 000 2. 0000 2.0 3 0* -0.02

2 270.000 2. 0000 2.003* -0.02

NP = *6, ONRMSPCT = 0,,039, P1EANPCT =

P,8AR CALCD P,PCT

10.260 10.255 0.05 10.7** 10. 736 0.06 11.222 11. 216 0.C6 11.696 11.690 0. 05 12.165 12. 161 0. 04 12.632 12.629 0.02

13.0 96 13.095 0.01 13.559 13.559 0.00

1*. 020 1*. 021 -0. 01 14.479 1*.*61 -0. 01 1*.937 1*.9*0 -0.02

15.39* 15.398 -0. C2 15.851 15.85* -0. 02 16.306 16.31C -0.02

lb. 761 16. 7b* -0.02

17.215 17. 216 -0. 02 17.668 17.671 -0. 02

18. 120 16. 123 -0.0 1 18.572 18.57* -0.01

19.023 19. 025 - • G 1 19. *7* 19.475 -0. 00 19.92* 19.92* -0.00 20.373 20.373 0.00

2D. 822 20.822 0.00 21.271 21.27C 0.01 20.616 20.618 -0.01 21.663 21.666 -0.C3

22.697 22.70F -0. 04 23.721 23.732 -0. 0* 24.737 2*.75C -0.C5

25.745 25.760 -0. Ob 26.7*8 26.763 -0. 06 27.7*6 27.761 -0. 06 28.739 28.75i- -0. 05 29.729 29.7*3 -0.05

30.715 30.726 -0.04

31.698 31. 709 -0.03

32.677 32.686 -0. 03 33.654 33.661 -0.02

34.629 3*.o33 -0. 01 35.601 35.602 -0.01

36.570 36.570 0. 00 37.537 37.53* 0.01 38.502 38.497 0. 01 39.*65 39.*56 0.02 *0.*26 *0.*18 0.02

53
METHANc EUUATION OF STATE

D T,K MOL/L CALCD O.PCT P,BAR CALCC P.PCT

3 172.527 2.5593 2 • 5643 -G.19 24.660 24.634 J. 11

3 174.691 2.5593 2.56 49 -0.22 25.283 25.251 0.13

3 177.203 2.5686 2.56+8 -0.24 25.994 25.956 0. 14

3 183.176 2. 5680 2.5b51 -0.28 27.666 27.ol7 O.ld

3 190.532 2.5577 2.5o35 -0-23 29.676 29.631 0. 15

3 191.849 2.66 6 8 2.5639 -0.28 3 0.0 38 29.981 0. 19

3 203. aa<* 2.5555 2.3o21 -0.26 33.048 32.986 0.19

3 213. GUI 2.5543 2.5613 -0.24 35.672 35.60? 0.18

3 217.864 2.6537 2.55 94 -0.22 3b. 931 3b. 8b7 0.17

3 223.831 2.5530 2.5535 -0.22 38.461 38.415 0.17

3 233.546 2.6518 2.55 7 3 -1.22 40 .990 40.918 0. 18

3 239.797 2.5512 2 .55 53 -0.20 42.590 4 2 . 5 2 f 0. Id

3 252.833 2.6499 2.5536 -0.15 45.897 45.838 0.13

3 2o3.399 2.54o7 2.5519 -0.13 48.559 48.506 0. 11

3 273.380 2.5474 2.5632 -0.11 51 . 058 51.006 0. 1 u 3 190.429 6. 4670 5.3216 2.25 44.720 44. 893 -0. 39

3 19u. 532 o. 468b o.3256 2.21 44.814 44.96? -0.39

3 208.574 6.4614 5 . f.50 0.24 6J.27C 60. 334 -0. 11

3 223.234 6.4571 n . +550 0.02 72.346 72.353 -0.01

3 2 J-r.ttO 6.4539 5.456 8 -0.05 81.433 81. 409 J. 03

3 243.733 6.46 8 5.4570 -0.10 88.913 86.851 0. ? 3 243.773 6.4508 j • 43 >5 -0.09 88.939 83.883 0.06

3 251.376 6.4483 i. 45 56 -0.11 95.018 94.937 0.08

3 262. 190 6.4452 j.4527 -a. 12 103. bOl 103.505 0.09

3 272.155 Q.4421 3.4j08 -0.13 111.478 111. 35? 0. 11

3 272.185 6.4421 j. 4503 -0. 13 111.494 111.376 0. 1 1 3 190.052 7.2329 D.9"4 3.53 44.989 45.132 -0. 32

3 190.532 7.2348 7.0176 3.00 45.493 45.631 -0.30

3 190.750 7.2329 7.01 31 2.96 45.7 10 45.856 -0.32

3 191.032 7.2341 7.3 347 2.76 46 . LI 01 4b. 145 -0. 31

3 193.325 7.2316 '.1156 1.59 -.8.336 48.4b2 -0.2b

3 197.737 7.23C-. '.173? 0.79 52.722 52. 826 -0. 20

3 202.753 7.2285 7.2J31 0.39 57.627 57. 70? -0. 1 J 3 203.224 7.2266 7.2134 0.18 62.9C9 62.956 -0. 07

3 212.165 7.225-. 7.2231 0.07 66. c89 66.712 -0. 03

3 217.136 7.2235 7.2237 -0.00 71.421 71. 42C 0- 00

3 222.926 7.2217 7.2273 -0. 08 76.909 76. 376 J. 04

3 23J.050 7.2192 7.2233 -0.13 83.614 83.548 0. C8

3 237 .336 7.2167 7.2276 -U.15 90.432 90.338 0.10

3 242.709 7.2148 7.2233 -0. 15 95. 4J4 95. 326 0. 11

3 248.444 7.2129 7.22-.7 -U.16 100.757 1 C . o 3 3 0. 12

3 250. 194 7. 2123 7.2241 -0.16 102.376 102.249 0. 12

3 253 . 445 7.2111 7.22>7 -0.16 105.378 106.247 0-12

3 253.642 7.2092 '.2239 -0.16 110. 172 110. 029 0.13

3 2o3.050 7.2079 7.21 44 -O.lD 114.229 114. 08C 0. 13

3 263.301 7.2061 7.2175 -0.16 119.049 118.891 0.13

3 273.171 7.2C42 7.2153 -0.15 123.604 123.340 0.13

3 191.032 9.O404 4.51-.6 13.47 46.579 46.673 -0.20

3 191.551 9.8370 3.10 34 7.40 47.318 47.416 -0.21

3 192.938 9.8364 9.50U 3.39 49.282 49.400 -0.24

3 195 .243 9.6351 3.6600 1.76 52.5t>3 52.696 -0.25

3 197.562 9.8345 3.7151 1.21 55.870 5 6.016 -0.25

54
METHANE EQUATION OF STATE

ID T,K MOL/L CALCO D,PCT P.BAR CALCC P,PCT

3 200.<«11 9.8333 9.7715 0.63 59.977 60.083 -0.18

3 202.829 9.8320 9.7753 0.58 63.417 63.541 -0.20

3 206.370 9.8301 J. 7939 0.37 68.503 68.607 -0.15

3 213.503 9.8270 9. 8151 0.12 78.7^1 78.623 -0.07

3 223.647 9.8220 9.8260 -0.04 93.389 93.363 0.03

3 236.398 9.8158 9. 82 45 -0.13 111.767 111.649 0.11

3 248.147 9.8108 9.8255 -0.15 128.674 128.499 0.14

3 255.163 9.8071 9.8224 -0.16 138.749 138.543 0. 15

3 273.167 9.7990 9.8115 -0.13 164.504 164.284 0.13

3 191.032 10.2157 8.8057 13.79 46.607 4b.o95 -0. 19

3 190.839 10.2128 8.5593 16.19 46.342 46.408 -0.14

3 191.040 10.2128 8.8045 13.79 46.bl8 46.707 -0.19

3 191.229 10.2128 9.2097 9.82 46.900 46.986 -0.19

3 191.t28 10.2128 9.3866 8.09 47.188 47.284 -0.20

3 191.820 10.2128 9.6095 5.91 47.762 47.B67 -0.22

3 192.076 10.2128 9.5636 5.33 48.131 48.249 -0.24

3 193.522 10.2115 3.8983 3.07 50.263 50.407 -0.29

3 195.158 10.2109 10.0060 2.01 52.700 52. 854 -0.29

3 197.92b 10.2096 10.0779 1.29 56.836 57.004 -U. 30

3 200.575 10.2084 13.1137 0.93 60 .814 60.985 -0.28

3 204.037 10.2065 13.1425 0.63 bb. 036 66.196 -0.24

3 207.855 10.2047 13.1577 0.46 71.799 71.954 -0. 22

3 207.855 10.2047 10.1681 0.36 71.833 71.954 -0. 17

3 213. 044 10.2022 13.1786 0.23 79.o91 79.795 -0.13

3 233.386 10. 1922 10.1984 -0.06 IIO.088 110.633 0.0 5

3 252.887 10.1829 10.1934 -0.10 140. 387 140. 24£ 0. 10

3 273.016 10.1729 13.1825 -0.09 170.925 170. 75C 0. 10

3 273.058 10.1729 13.1324 -0.09 170.967 170.814 0. 10

3 190.532 11.1588 7.7126 30.88 -.5.834 45.953 -0.2t

3 191.032 11.1582 9.3291 lb. 39 40.643 40.755 -0.24

3 191.848 11. 1543 10.6174 4.81 47.983 48.091 -0.22

3 191.873 11.1543 13.54J8 6.45 4b. 09 48. 132 -0.2b

3 193.248 11. 1537 10.7939 3.18 50.248 50.410 -0. 32

3 195.110 11.1531 13.9238 2.01 53.340 53.525 -0. 35

3 197.300 11.1516 13.9776 1.56 56.992 5 7. 2 It -0.39

3 199.216 11. 1506 11.0123 1.24 60.228 60.462 -0.39

3 200.901 11.1500 11.0356 1.03 63.092 63.329 -0. 38

3 203.064 11.1487 11.0i57 0.83 66.782 67.021 -0.36

3 207.564 11.1462 11.0837 0.54 74.516 74.737 -0.29

3 213.197 11.1431 11.1064 U.33 84.266 84.44b -0.22

3 213.204 11. 1431 11.1073 0.32 84.282 84.460 -0. 21

3 213.212 11.1431 11.1067 0.33 84.293 84.474 -0.21

3 223.184 11.1375 LI. 1237 0.12 101. DOC 101.763 -0. 10

3 233.161 11.1325 11.1300 0.02 119.122 119.l4fc -0.02

3 243.137 11.1269 11.1297 -0.03 136.601 136.566 0.G3

3 253.153 11.1219 11.1246 -0.02 154.123 154.063 0.03

3 263.124 11. 1163 11.1188 -0.02 171.554 171.510 0.03

3 273.092 11.1113 11.1139 -0.02 188.977 18 8.924 U. C3

3 273.150 11.1113 11.1064 0.04 188.927 189.026 -0.05

3 191.032 11.7666 10.3152 12.33 46.701 46.826 -0.27

3 192.498 11.7625 11.5148 2.11 49.295 49.402 -0.22

3 195.840 11.7c07 11.6275 1.13 55.256 55.412 -0.28

3 198.182 11.7594 11.6592 0.85 59.511 59.683 -0.29

55
METHANE EQUATION OF STATE

ID T,K HOL/L cal:o O.PCT P.BAR CALCO P,PCT

3 203.434 11.75b3 11.6938 0.51 69.192 69.37C -3.26

3 212. 034 11.7513 11.7257 0.21 85.308 85.436 -0.15

3 212.035 11.7513 U.72i8 0.21 85. 310 85.*37 -0. 15

3 222.632 11.7451 1 1 . 7 4 a g 0.04 105.407 105.441 -0. 03

3 233. 402 11.7395 11.7*32 -G.G3 125.956 125. 91fc 0.03

3 233.403 11.7395 11.7446 -0.04 125.973 125.918 0.04

3 237.033 11.7370 11.7**6 -0.06 132.922 132.832 0.07

3 237. 034 11.7370 11.7**3 -U.06 132.920 132.833 0.07

3 2*3.378 11.7332 11. 7*16 -0.07 1*5.053 144.937 0. 08

3 243.381 11.7332 11.7410 -0.07 145.050 144.943 0.07

3 253.284 11.7283 11.7352 -J. 06 163.987 163.875 0.07

3 2o3.449 11.7220 11.7278 -0.05 183.402 183.291 0.06

3 268.300 11.7195 11.7254 -0.05 192. o83 192. 5o2 0. 06

3 263.300 11.7195 11.7251 -0.05 192.678 192.562 0. 06

3 272.694 11.7170 11.7216 -0.04 2 01.0-jO 200.949 J.C5

3 272.695 11.7170 11.7215 -0.04 2 01.049 200.951 0.G6

3 272.698 11.7170 11.7211 -G.03 201. 0*6 200.957 0. 04

3 190.032 12.6681 7.5715 41.16 45.2 36 45.326 -0.20

3 191.032 12.8675 12.7901 0.60 47.247 47.306 -0. 13

3 190.532 12.8681 12.7514 0.91 40.239 46.312 -0.16

3 19J.703 12. 8636 1Z.7931 0.55 46.599 4b. 648 -0.11

3 191.454 12.6636 12.8027 0.47 48. 097 48.153 -0. 12

3 192.397 12.8630 12.7839 0.64 49.969 50.066 -0.19

3 196.505 12.6605 12.8326 U.22 58.521 5ft. 587 -3.11

3 203.573 12. 8562 12.8560 0.00 73.04? 73.643 -0.00

3 209.295 12.8524 12.36 59 -0.09 86. 110 86.039 0.C8

3 218. o22 12.8468 12.8679 -0.16 Iu6.bb2 106.492 0.18

3 228.103 12.8406 12.8641 -0.18 127.755 127.474 0.22

3 238.550 12.8343 12.8578 -0.18 151.093 150.735 0.24

3 245.920 12.6294 12.8*99 -0. 16 167.5*6 167.186 0.21

3 252.972 12.8250 12.3450 -C.16 183.347 182.951 0.22

3 260.108 12.8206 12.8333 -0. 14 199.300 198. 91C 0.20

3 267.312 12.6163 12.83J8 -0.11 215.373 215. 019 0. 16

3 27*. 151 12.8119 12.8226 -G.08 230.576 230.292 0.12

3 188.969 13.7516 13.7450 0.04 43.866 43. 864 -0.C2

3 189.258 13.7510 13. 7*39 0. 02 44.5L2 44. 501 -0.01

3 189.767 13.7510 13.7474 0.03 45.639 45.64* -0. 01

3 190. J32 13.7545 13.7*98 0.03 40.240 40. 248 -0.02

3 190.172 13.7504 13.7455 0.04 46.549 46.557 -0.02

3 191.032 13.7539 13.75+4 -0.00 43.523 48.522 0.00

3 190.447 13.7504 13.7433 0.01 47. 177 47.181 -0. 01

3 190.532 13. 7545 13.7530 0.01 47.379 47. 381 -0.C1

3 1-90.736 13.7504 13.7437 0.01 47.8*0 47.843 -0.C1

3 191.075 13.7497 13.7513 -0.01 48.615 48.611 0. 01

3 192.892 13.7465 13.7528 -0.03 52.817 52.306 0.C2

3 195.0*8 13.7473 13.7573 -0.07 57.893 57.869 0.06

3 195.065 13. 7*73 15.7p>6 -0.06 57.928 57.899 0.C5

3 197. 100 13.7460 13.7637 -0.11 62. 787 62.727 0. 10

3 203.010 13.7441 13.7o51 -0.15 o9.812 b9.704 0.15

3 203.322 13.7416 13.7639 -0.21 77.904 77.726 0.23

3 207.197 13.7392 13.77 33 -0.23 87.439 87.202 0.27

3 213.323 13.7348 13.7743 -0.29 102.706 102.320 0.36

3 222.792 13. 728b 13. 7o i9 -0.28 126.432 125.931 0.40

56
METHANE EQUATION OF STATE

10 T,K MOL/L CALCO 0,PCT P.8AR CALCO P.PCT

3 227.846 13.7254 13.7630 -0.27 139.174 138.615 0.40

3 233.272 13.7217 13.7581 -0.27 152.884 152.272 0.40

3 23d. 506 13.7180 13.7518 -0.25 166.109 165.479 0.38

3 242.985 13.7148 13.74o6 -0.23 177.429 176. 78fc 0.3o

3 2*8.766 13.7111 13.7388 -0.20 192.026 191.409 0.32

3 253.111 13.7086 13.7S55 -0.18 203.005 202.412 0.29

3 258.314 13.7049 13.7273 -0.16 216.145 215.573 0.2o

3 2b2.932 13.7018 13.7222 -0.15 227.811 227.255 0.2*

3 267.819 13.6966 13.7150 -0.13 240.117 239.614 0.21

3 267.886 13.6966 13.7150 -0.13 240.266 239.784 0.21

3 273.153 13.6949 13.7100 -0.11 253.551 253. 086 0.18

3 187. 6i*9 14.9705 14.9416 0.19 *3.274 43.375 -0.23

3 188.927 14.9699 1*.95 3 7 0.13 4b . 7 7

1

46. 649 -0.17

3 190.532 14.9732 1*. 9519 0.10 51.216 51.285 -0.1*

3 191.453 14.9680 1*.9620 0.04 53.786 53.616 -0.06

3 194.804 14.9655 14.9737 -0.03 o3.256 o3.221 0.06

3 199.611 14.9618 1+.9615 -0.13 77.104 76.930 0.23

3 203.054 14.9593 1*.98 5 2 -0.17 87.135 86.868 0.31

3 207.627 14.9562 It. 9830 -G.21 100.574 100.163 0.39

3 212.935 14.9524 1*.9372 -0.23 116.265 115.759 0.44

3 221.360 14.9462 1*.9816 -0.2* 141.310 1*0. 67C 3.45

3 228.637 1*.9*06 1*.97*3 -0.23 163. 016 162.304 0.44

3 236.599 14.9350 14.9652 -0.20 186.801 186. 064 3.39

3 245.086 14.9267 l*.95+2 -0.17 212. 1*0 211.429 0.3*

3 233.068 14.9225 l-t.9**4 -0.15 235.968 235.281. 0.29

3 260.836 It. 9169 1*.9326 -0.11 259. 036 258.498 3. 21

3 268. 824 14.9113 14.9213 -0.07 282.716 282.341 0.13

3 275.154 14.9063 1*.9137 -0.05 301.472 301. 17e 0. 10

3 183.351 16.5234 16 . 4653 0.35 38.252 38.709 -1.19

3 185.267 16.5215 lo.*o39 0.32 4*. 6 64 45.360 -1.06

3 189.259 16.5164 lo.*336 0.23 58.970 59.402 -0.73

3 190.532 16.5223 lo.*839 0.23 63.513 63.981 -0.74

3 13*.* 19 16.51*0 lo.*931 0.13 77.509 77.81C -0.39

3 198.420 16.5109 16.*9*7 0.10 91.963 92.232 -0.29

3 201.3*4 16.5084 16.5050 0.03 101.638 101.7 3fc -0. 10

3 207.770 16.5026 15.4933 0.G2 12b. 173 126.246 -0.0b

3 213.666 16.*978 16. -.937 -0.01 1*7.882 1*7. 859 0. 02

3 222.393 16.4903 la. 4911 -0.01 181.824 181.79° 0.01

3 232.812 16.4822 lo.4816 0.00 216.350 218.371 -0.01

3 241.295 16.*754 lo.4735 0.01 2*9.578 249.653 -0.03

3 25*. 531 lo.t648 10.-.572 0.05 298.027 298. 372 -0. 12

3 261.826 16.4586 16.4477 0.07 324.594 325. 12*- -0. 16

3 267.883 16.4536 16.-.*01 3.08 346.584 347.284 -0.20

3 272.981 16.4492 16.4329 0.10 364.997 365.878 -0.2*

3 179.140 17.5640 17.53*3 0.17 33. 0*4 33.416 -1.13

3 179.830 17.5634 17.5336 0.17 35.8*9 36.237 -1. 08

3 181.008 17.5622 17.5324 0.17 40.651 41.064 -1.02

3 164.441 17.5590 17.5311 0.16 5*. 773 55.227 -0.63

3 190.532 17.5595 17.5279 0.18 60.090 80.733 -0.60

3 196.384 17.5465 17.5232 0.14 104.601 105.209 -0.58

3 200.537 17.5447 17.5261 0.11 122.244 122.740 -0.41

3 208.822 17.5379 17.52*3 0.08 157.42b 157. 85fc -0.27

3 217.044 17.5304 17.5173 0.07 192.276 192.756 -0.25

57
METHANE equation of state

10 T,K MOL/L CALCO D.PCT P.8AR CALCD P.PCT

3 225.022 17.5235 17.5071. 0.09 225.971. 226.639 -0.29

3 233.079 17.5160 17.1*980 0. 10 259. 9o3 260.790 -0.32

3 2<40.996 17.5092 17.1*878 0.12 293.223 29+. 297 -0.37

3 250.735 17.5005 17. + 7+7 0.15 333.921. 335.357 -0.+3

3 258. b+6 17.4936 17.4601* 0.19 366.598 3o8.58C -0.5 +

3 266.750 17.1*868 I7.t+Ji* 0.21 1.00.092 + 02.1*85 -J. 60

3 27+. 303 17.1.799 17.1*392 0.23 1*31.136 +33.901 -0.6 +

3 182.8 31* 18.1*688 18.1*293 0.32 b5.518 66.971. -2.22

3 162,631* 18. +888 19. + 292 0.33 65. +91 66.97+ -2.2b

3 175.629 18.1*956 18.1*331 0.34 31.3 76 32.556 -3.76

3 178.081 18.4931 18.1*311 0.31* 1.2.935 i*i*. 22t -3.01

3 188.292 18.1.838 13.1*237 0.30 91.6i*6 93.222 -1.72

3 190.532 18. -.871 19. +231 0.32 102.1.01 10+. 183 -1.7 +

3 193.630 18.1*788 18.+2T4 0.28 117.303 116.966 -1.42

3 198.667 18.1*738 13.1*258 C.26 1+1.558 1+3.283 -1.22

3 203.156 18. +695 1:1. +2 3 7 0.25 163. 161 16i*. 966 -1.09

3 208.21+ 18.1.651 13. <*2 34 0.21* 187.511 189. +07 -1. C 1 3 212. + 2 + 18.1*6 7 16.4152 0.21* 2 7.69H 209.701 -0.97

3 218.758 18.1*551 13. 4107 0.21* 238.0+9 2+0.23+ -0.92

3 223.7i»2 18.t501 13.1*050 0.2<+ 261.867 261*. 179 -0.88

3 229.135 18. 1*1*52 13.3991 0.25 287. +65 290. 057 -0.89

3 233.395 18.1*1*11. 13.39*0 0.26 307.683 310. +5E -0.90

3 237.607 18.1.377 13.3338 0.27 327.596 330.561 -0.91

3 2+3.055 18.1*321 13.3817 u.27 353.252 356. +9C -0.92

3 2h6. 039 18. -.277 18.37+5 0.29 376.587 360.163 -0.95

3 253.126 18.1*227 11.3677 0.30 +00.3+8 +0+.213 -0.97

3 263.283 18. i*13l. 13.35+2 0.32 ++7.525 +52.030 -1.01

3 272.927 18. it0i*7 13.3+30 0.35 +91.8+0 +97.120 -1.07

3 172.566 19.99o2 19.9196 0.38 55.009 57.665 -5.19

3 178. +60 19.9899 19.9112 0.39 90. 082 93. +25 -3.71

3 186.850 19.9812 19.9039 0.39 139. 7bl 143.593 -2.71*

3 190.532 19.9838 19.9036 0.<*2 161. 5+4 165. 92£ -2.71

3 196.0 89 19.9719 19.8952 0.36 19+. 310 198. b63 -2.25

3 20-.. 181 19.9631 19.8872 G.38 2-.1.785 2+6.590 -1.99

3 211.525 19.9557 19.3831 0.38 281*. 629 289.837 -1.63

3 219.063 19.9476 19.8715 0.38 328.253 333.915 -1.72

3 227.105 19.9395 19.8606 0.1*0 37+. 3+1 380.662 -1.69

3 235.300 19.93H* 19.8532 0.1.1 +21. 001 +27.972 -1.6b

3 24+.17+ 19.9220 19.8335 0.1*3 +70.891 +78.751 -1.67

3 253.828 19.9120 19.82 J8 0.1.1. 52+. 859 533.539 -1.65

3 259. 3i«3 19.9Cbi* 19.3151. 0.1*5 555. ++1 561.. 625 -1.65

3 267.733 19.8977 19.7996 C+9 601.053 611.585 -1.75

3 27+. 489 19.8909 19.7922 0.50 b38.125 6+9. 1+f -1.73

3 172. 7b6 21.2132 21.1201. .+i* 113.831 119.516 - + .99

3 176.889 21.2088 21.11+9 u • + + 1+2.805 1+8.92+ - + . 28

3 181. o69 21. 2032 21.11 )i* 0.1* <+ 176.336 182.788 -3.66

3 189.783 21.1939 21.09)0 0.1.5 232.523 239.806 -3. 13

3 19J.532 21.2000 21.0 932 0.1.3 237.772 2+5.586 -3.29

3 197.315 21.1858 21.0913 u. + 5 2 8+. 3 87 292.251 -2.77

3 20+. 169 21. 1763 21.0653 0.1*1* 331.269 339.5+1 -2.50

3 212. b++ 21.1689 21.07o3 O.i*** 388.576 397. +59 -2.29

3 226. +30 21. 1509 21.3560 0.1*5 +93. +6+ 503.735 -2.0 8

3 235.778 21. 11.28 21. + oG U • +6 5+1. 550 552.567 -2. 03

3 2+7.360 21. 1303 21.3291. 0.i*8 61o. 52o 626.871 -2.00

3 2 52.992 21.121.1 21.0235 0.1*9 c52.311 665. +02 -2. 01

3 lb8.753 22.+109 22.31+9 0.43 169. +22 177.799 - + .9 + 3 180.116 22.3972 22.3038 0.42 262.665 271.877 -3.60

3 188.528 22.3672 22.29*6 3.1.1 330. +50 3+0.295 -2.98

3 190.532 22.3918 22.2923 j • i*i* 3+6.+-.C 357. 215 -3. 11

3 196.791 ZZ.377Z 22.2331 0.1*0 396.392 +06.5+0 -2.56

3 204.366 22.3679 22.2833 0.39 +55.919 +o6.+87 -2.32

3 211.255 22.3598 22.2725 0.39 509. +C3 520. ++7 -2.17

3 218.293 22.3517 22. 2o + 7 C.39 563.516 575. 03e -2. C +

3 22o.285 22.31*17 22.25+1 0.39 62+. 075 636.262 -1.95

3 23+. +20 22.3321. 22.2+13 0.1*0 b85.032 b98.015 -1.90

HP 276, DNRMSPCT = 3.971, P1EANPCT = 0.o26

58
METHANE EQUATION OF STATE

10 T,K NOL/L CALCD D.PCT P.BAR CALCD P,PCT

4 114.524 26.1376 26.1262 0.04 8.945 10.848 -21.28

4 114.524 26.3609 26.3539 0.04 *7.517 49.285 -3.72

k 114.524 26.5104 26.5C-t8 0.02 75.421 76.*65 -1.36

4 114.524 26.6581 25.6549 0.01 103.824 104.451 -0.6

4 114.524 26.8046 25.30*2 0.00 133.256 133.336 -0.06

4 n't. 524 26.9535 26.9515 0.01 163. *36 163.841 -0.25

4 11*. 524 27. 1032 27.1075 -0.02 196.656 195.721 0.48

4 114.524 27.2643 27.2692 -0.02 232.450 231.342 0.48

<t 114.524 27.4311 27.4391 -0.03 271.554 269.669 0.69

l» 114.524 27.O091 27.6123 -0.01 312.987 312.186 0. 26

<• 119.420 25.6812 25.6658 0.06 8.328 10.64C -27.76

* 119.420 25.8345 25.9091 0.10 30.274 34.267 -13.19

4 119.420 26.0308 26.0055 0.09 62.146 66.202 -6.53

4 119.420 26.2681 26.2495 0.07 104.007 107.328 -3.19

4 119.420 26.5034 26.4939 0.04 149.093 150.912 -1.22

If 119.420 26.7480 26.7*39 0.02 198.372 199.213 -3.42

4 119.420 27.0051 27.0070 -0.01 253.748 253.336 0. 16

It 119.420 27.2546 27.2833 -0.12 316.910 309.143 2.45

(t 124.917 25.2010 25.14*2 0.23 9.796 17.*2t -77.89

4 12*. 917 25.4421 25.3976 0.17 4*.9o0 51.433 -14.40

<• 124.917 25.6911 25.6533 0.13 8*. 186 89.350 -6.13

4 124.917 25.9383 25.91)6 0.11 125.190 129.872 -3.74

4 124.917 26.1725 23.16 37 0.05 168.629 17 0.976 -1.27

It 124.917 26.*264 23.4233 0.01 217.985 218.572 -0.27

* 12*. 917 26.6966 2o.7337 -0.02 273.638 272. 787 3.31

4 130.987 24.5924 24.5737 0.08 15.025 17.214 -14.57

<t 130.987 24.6361 2*. 8290 0.03 46.2*6 47.150 -1.95

4 130.987 25.1307 25.37 32 0.21 79.3 44 d6.654 -9.21

4 130.987 25. 352* 25.3279 3.10 115.200 118.863 -3.18

4 130.987 25.5826 25.6019 -0.08 157.736 154.633 1.97

4 130.987 25.8251 25.85 36 -0.13 200.714 194. 93C 2. 88

4 130.987 26.0879 2o.l238 -0.16 249.306 2*1.722 3.C4

4 130.987 26.3657 26.4062 -0.15 302.874 294.827 2.66

4 134.328 24.1949 24.1473 0.20 6.891 11.923 -73.02

4 13*. 328 24.3807 2.. 33*0 0.19 27.123 32.403 -19.47

4 134.328 24.6433 2*. 5962 0.19 57.831 63.641 -10.05

4 134. 328 24.9029 2*. 8533 0.18 91.296 97.266 -6.54

4 134.328 25.1534 25.1219 0.13 127.826 132.397 -3.58

4 134.328 25.4059 25.3734 0.11 166.2 55 170.539 -2.58

It 13*. 328 25.6634 25.6*60 0.07 209.466 212. 388 -1.39

It 134.328 25.9323 25.9231 0.04 257.678 259.330 -0.64

<t 134.328 26.2171 2a. 20*3 0.05 310.290 312.791 -0.81

4 139. Obi 23.7344 23.6811 0.22 12.524 17.586 -40.42

4 139.061 23.9958 23.9*18 0.22 38.254 43.881 -14.71

It 139.061 24.2618 24.2118 0.21 O7.490 73.20e -8.47

4 139.061 24.5236 2*.*750 0.19 98.761 104.689 -6.0

4 139. Obi 24.7801 2*. 7366 0.18 132.3 00 138.154 -*.43

It 139.061 25.0332 25.03 30 0.13 169.001 173.822 -2.85

4 139.061 25.2934 25.2730 0.09 209.662 213.327 -1.75

<t 139.361 25.5571 25.5*88 G.03 254.969 256.366 -0.56

it 139.061 25.8465 25.83 97 0.03 306.000 307.237 -0.40

4 1*5.556 22.9848 22.9253 0.26 12.996 17.661 -35.90

59
METHANE EQUATION OF STATE

10 T,K MOL/L cal:d D,PCT P ,OAR CALCD P.PCT

4 145.556 23.2623 23.1979 0.28 35 276 4C.885 -15.90

4 1*5.556 23.5355 23.4750 0.26 60 368 66. 181 -9-63

4 145.556 23.8146 23.7458 0.29 87 .361 94.632 -8.32

4 lt5 .556 24.0836 2+.0138 0.27 117 186 124. o55 -6.37

4 lt5.556 24.3522 24.2871 0.27 1 + 9 .131 157.295 -5.47

4 145 . 556 24. 6202 24.5569 0.26 184 .018 192.616 -4.67

1» 145.556 24.8961 2+.S323 0.26 ZZl 583 231.956 -4.21

1* 145.556 25.1794 25.1130 0.24 265 ,891 275. b43 -3.67

It 1+5.556 25.4706 25.4150 0.22 314 581 324. 117 -3. 03

4 150.750 22.6157 22.5234 0.39 31 021 37.422 -20.63

It 150.750 22.6932 22.3029 0.39 51 385 59.239 -14.17

<» 150.750 23. 1664 23. 07 37 0.38 75 115 82.993 -10.49

It 150.750 23.4373 23.3511 0.37 100 392 108.897 -3. 47

It 150.750 23.b995 23.o252 0.32 128 071 136.284 -6.41

4 150.750 23.9630 23.3331 C.31 157 + 54 loe.210 -5. 56

It 150. 750 24.2248 24.1533 0.27 190 oco 198.424 -4.4 3

"t 150.750 24.4972 2-1.435 0.25 22o 137 234.670 -3.77

4 150.750 24.7733 2t.7136 0.22 266 405 274.367 -2.99

>t 150.750 25.0576 25.0038 0.21 309 8c2 318. 46t -2.73

It 153.238 21.5318 21.3950 0.64 22 .8 95 30.151 -31.69

V 153.238 21.8341 21.69 31 0.62 39 627 47.766 -20.55

It 158. 238 22.1371 22.0 32 0.58 53 951 67.73C -1+.69

4 153.238 22.4371 22.31)7 0.5o SO 251 89.892 -12.01

It 158.238 22. 7293 22.6111 0.52 103 898 113.907 -9.b3

It 158.238 2 3 . 1 7 1 22.90 29 0.50 129 358 140.019 -8.24

It 153.238 23.3008 23.1938 0.45 157 625 168.279 -0. 7o

It 153.238 23.5838 25.-t94b 0.38 189 080 199.076 -5.29

It 159.238 23.8720 23.7933 C.33 223 624 233.244 -4.30

t 153.238 24.1692 24.3 953 0. 31 261 723 271.536 -3.7b

It 158.238 24.4708 2-t.407l 0.26 304 591 313. 60C -3.C2

4 lo5.316 20.-.637 20.38+7 0.39 30 556 33.649 -10. 12

It lb5.816 20.7641 2 J. 66 3 0.46 42 201 46.508 -10.21

4 lt>5.816 21.0624 2). 3630 0.45 56 2b9 ol . 064 -8.5o

It lo5.S16 21.3570 21.25+1 0.48 71 4bl 77.373 -3.27

4 lop. 81o 21. c5G6 21.52 37 3.5o 37 6 39 95.592 -8.83

It 165.816 21.9356 21.3039 0.58 106 2 76 115.284 -8.48

4 lo5.816 22.2193 22.0725 fl.DO 125 484 136. 9b4 -9.1s

4 165.816 22.5012 22.3333 0.72 1+6 70b I0O.68I -9.52

It 165.816 22.7790 22.6035 0. 77 169. 6 35 186. 266 -9.68

t lo5 . 81o 23.0595 22.3o76 0.83 194 903 214.443 - 10. C 3 4 lo5.816 23.3427 23.1326 u.90 222. 178 245. 365 -10.45

It 165.316 23.6300 23.40+0 0.96 252 431 279.481 -10.72

4 165.816 23.9143 23.7052 0.87 288. 859 315.989 -9.39

4 171.020 19.460b 13.4322 0.15 30. 512 31.299 -2.56

4 171. 020 19. 7578 19.737b 0.10 39 620 40. 274 -1.65

It 171.020 20.0678 2J.0 537 0.17 49 881 51. 157 -2.56

it 171.020 20.3741 21.33+6 0.19 61 85b b3. 549 -2.74

it 171.020 20.6778 23.5314 0.22 75. 316 77.579 -3. 00

It 171. 020 20.9802 2J.3216 0.23 90. 173 93.386 -3.56

4 171.020 21.2743 21.20 31 0.33 106 293 110.649 -4. 10

It 171.020 21.5629 21.4829 0.37 124 080 129. 50C -4.37

It 171.020 21.8464 21.75)9 C.45 1+2. 859 150.132 -5. 09

it 171.020 22.1273 22.0216 0.48 163 662 172.301 -5.28

60
METHANE EQUATION OF STATE

ID T,K MOl/L CALOD D.PCT P,BAR CALCP P.PCT

4 171.320 22.ifl20 22.2yl3 0.54 186.3 01 197 .078 -5.78

4 171.020 22.6901 22.5597 0.57 210.832 223 .499 -6.01

4 171.020 22.9769 22.8351 0.62 2^8. 168 253 135 -b.28

k 171.020 23.2672 23.1122 0.67 268.002 285 736 -6.62

4 171.020 23.6605 23.3958 0.71 300.808 321 .453 -6. 86

4 172.812 18.9036 13.8931 0.03 26.918 27 038 -J. 45

4 172.812 19.21/1 19.2037 U.07 34.176 34 523 -1. 02

4 172.812 19.5431 19.5216 0.11 43. Ill 43 769 -1.53

<t 172.312 19.8661 19.8411 0.14 53.641 54 607 -1. 80

<t 172.812 20. 1873 20.1525 0.17 65.532 66 966 -2.19

<f 172.812 20.6019 2J.4593 0.21 78.943 30 944 -2.54

f 172.812 20.6125 20.7o22 0.24 93.956 96 631 -2.64

4 172.812 21.1163 21.0558 0.28 110. 311 113 652 -3.21

<f 172.812 21.4142 21.3556 0.27 123.956 132 844 -3. 01

4 172.812 21.7122 21.6420 0.32 148.7 29 153 877 -3.4o

<f 172.312 22. 0066 21. 9151 0.42 169.458 17 6 8 23 -4. 35

4 172.812 22.3015 22.2U30 0. 44 193. 398 202 108 -4.50

4 172.812 22.5999 22.4855 0.51 219.091 230 142 -5. 04

if 172.812 22.8996 22.7721 0.56 247.494 260 914 -5.42

«f 172.312 23.2035 23.0o57 0.59 279.157 294 940 -5.65

if 172.812 23.510b 23. 3535 0.65 313.431 332 346 -6. 03

if 179.526 17.851if 17.7993 0.29 38.288 39 085 -2. 06

if 17 9.526 18. iem 18.13.>5 0.26 f 3 .914 44 601 -2. 02

if 179.526 18.5168 13. 45 7 7 0. 32 50. 375 51 669 -2.61

if 179.526 18.6it23 18.7921 0.27 58,367 59 689 -2.26

if 179.526 19. 1674 19.1120 0.29 67. 3?2 69 048 -2.52

"f 179.526 19.4852 19.4~275 0.30 77.bl3 79 651 -2.63

if 179.526 19.801o 19.7332 0.33 89. 123 91 759 -2.96

if 179.526 20.1110 20.3 4i4 0.33 102.227 105 226 -2.93

if 179.526 20.H182 2J.3451 0.36 116.557 120 303 -3.21

if 179.526 20. 7228 20.5332 G.41 132.223 137 0o7 -3.66

4 179.526 21.0225 20.9337 0.44 lf9.605 155 437 -3.90

If 179.526 21.3201 21.21 90 U.47 166.544 175 639 -4.21

If 179.526 21.ol79 21.5079 0.51 189.445 197 92S -4.48

If 179.526 21.9164 21.7932 0.54 212.479 222 472 -4.7

If 179.526 22.2163 22.3372 0.58 237.559 249 486 -5.02

If 179.526 22.5175 22.3779 0.62 265 . 059 279 lot -5.30

If 179.526 22. 3227 22.67 36 .67 295.185 311 815 -5.63

If 183.221 16.3228 13.2771 0.28 53.258 53 698 -0. P3

If 188.221 16.6622 la.6343 0.17 57.034 5? 363 -0.56

If 188.221 17. 0016 13.9/28 0.17 61.386 61 794 -0.67

If 188.221 17. 3388 17.3135 0.15 6o • 632 67 6C -0.64

If 188.221 17.0728 17.5437 0. 14 72.749 73 229 -0. 66

If 188.221 18.0034 17.9718 0.18 79.651 30 383 -3.92

if 188.221 18.3308 13.2951 0.19 B7.679 38 olC -1.06

If 183.221 18.3604 13. 32f

5

0.20 88.439 39 414 -1. 1G

If 188.221 18.6839 13.6366 0.25 97.425 98 895 -1.51

If 188.221 19. 0009 H. 9571 0.23 107.955 109 504 -1.43

If 188.221 19.3151 19.2o73 C.25 119.512 121 421 -1.60

If 133.221 19.6290 19.5536 0.4 131.343 134, 879 -2.69

If 133. 221 19.9390 19.3457 0.47 145.061 149 706 -3.20

If 188.221 20.2511 23.1621 0.44 161 .461 166. 409 -3. to

If 188.221 20.5427 20 .4532 0.41 178.513 183. 700 -2. 91

If 188.221 20.8468 23.7525 0.45 197.206 203 580 -3. 23

4 188.221 21.1497 21.0474 0.43 217.789 225. 3 83 -3.49

If 188.221 21.4551 21.3413 0.63 243.259 249 50 8 -3.85

4 138.221 21.7581 21.0373 0-55 2o4.984 Z75. 693 -4.04

If 188.221 22. 0546 21.9315 0.56 291.744 303 015 -4.07

NP = 163, ONRMSPCT = 0.3o6, PMEANPCT = 6.545

61
METHANE EQUATION OF STATE

ID T,K MOL/L CALGO O.FCT P.8AR CALCO P.PCT

6 273.150 0. 7500 0.7511 -0.01 16.376 16.37* 0.01

6 298.1*2 0.7500 0.7500 -0.00 18.020 18. 019 0.00

b 303.1*3 0.7500 0.7500 0.00 18.3*7 18.3*7 0.00

6 323. 1*0 0. 7500 0.7*99 0.02 19.b5b 19.659 -0.02

6 3*8.1*3 0.7500 0.7*99 0.01 21.292 21.295 -0. 01

o 373.1a0 0.7500 0.7*99 0.01 22.925 22.928 -0.01

b 398. lbO 0.7500 3.7500 0.00 2*. 657 2*. 558 -0. 00

6 273.150 1.0000 1.0003 -0.03 21.558 21.552 0.03

b 298.1*2 1. 0000 1.0001 -0.01 23.786 23.783 0.C1

6 303.11*3 1.0000 1.0002 -0.02 2*. 232 2*.22t 0.02

323.11*0 1.0000 1.00 JO 0.00 2b. OCb 26. OOfc -0. 00

6 3*8.1*3 1.0000 1.0030 0.00 28.221 28.222 -0.00

6 373.150 1.0000 1.0030 0.00 30.*31 30.*32 -0.C

6 398. lbO 1.0000 1 . J -coo 32.637 32.636 0.00 273.150 1.5000 1.5010 -0.06 31.539 31.520 0. Ob

6 29d.l<»2 1.5000 1.5036 -0.0* 3*. 993 3*. 981 0.C3

6 303.11.3 1.5000 1.5 J 3 6 -0.0* 35.b85 35.b71 0.0*

6 323.1i«0 1.5000 1.5031 -0. 01 38.*27 38. *2* 0. CI

6 3<*8.1i*3 1.5000 1.5J31 -0.00 *1.852 *1. 861 0. CO

D 373.150 1.5000 1.5031 -0.01 -.5.267 *5.26i- 0.01

b 396. lbO 1.5000 1.5033 -0.02 *8.676 *8.otS 0.C2

D 273.150 2. 0000 2.0017 -0.09 *1.053 *1. u21 0. 06

6 298.11*2 2. 0000 2.003d -0.0* *5.80* *5.787 0.0*

6 303.11*3 2.0000 2.00 38 -0.0* *6.7p3 *b.73C 3.0*

6 323.11*0 2. 0000 2.00 J* -0.02 50.530 50.521 0.C2

6 3-*8. li*3 2. 0000 1.9998 0.01 55.222 55.22fr -0.01

6 373.150 2.0000 2.0033 -0.02 59.920 59.911 0.C1

6 398.160 2.0000 2.3003 -0.01 6*. 582 6*. 573 0.01

6 273.150 2.5000 2.5018 -0.07 50.139 5C ioa O.Oo

6 298. 1<*2 2.5000 2.50 J5 -0.02 56. 2b3 56.252 0.02

b 303.1i*3 2.5000 2.50 J5 -0.02 57 .*o5 57.*7fc 0.C2

6 idS. Uu 2.5000 2.*J97 0. 01 b2. 3*3 62. 3*9 -0. CI

6 3i*8.1i*3 2.5000 2.*J9* 0.02 68.390 68.*0fc -0. C2

6 373.150 2.5000 2.*i99 0.00 7*.*2* i'*.427 -0.00

6 398.160 2.5000 2 .i*9 39 0.01 80.*11 60.*15 -0.01

b 273.150 3.0000 3.0010 -0.03 58. 8*2 ?&.<SZ* O.C 3 b 298.11*2 3.0000 2.9J37 0.01 o6.*15 66.*21 -0. CI

b 303.11*3 3. 0000 3.033* -0.01 67.9*0 67.932 0.01

b 323.140 3. O0G0 2.9939 0.0* 73.926 73.952 -O.C*

b 3*8.1i»3 3.0000 2.9936 0.05 81.391 81.*29 -0.06

b 373.150 3.0000 2.9J92 0.03 88.835 88. 856 -0.02

b 398.160 3. 0000 2.99 37 0.01 96.229 9b. 239 -O.C 1 b 273.150 3.5000 1. 5007 -0.02 b7.222 67.21C 0. C2

b 298.1h2 3.5000 3.*988 0.03 7b. 307 76.331 -0.03

6 303.1*3 3.5000 3. 5000 -0.00 76. 1*6 78.1*6 0.00

b 323.1H0 3.5000 3.*980 0.06 65. 32* 85.370 -0. 05

b 3i*8. 1*3 3.5000 3.*977 0.07 9*. 279 9*. 338 -0.0b

b 373.150 3.5000 i.*386 CO* 103.203 103.2*3 -0.0*

b 398. lbO 3.5000 3.*935 0.01 112.073 112.088 -0.01

b 273.150 i«. 0000 *.0 J 03 -0.01 75.307 75.303 0.01

b 298.11*2 H.0000 3.993* 0.0* 85.992 86.023 -0.0*

b 303.1*3 h.0000 5.99 9 3 0.02 88.1*2 88. 155 -0. 01

62
METHANE EQUATION OF ST'.TE

T,K MOL/L ;aloo O.PCT P,BAR CALCD P,PCT

6 323.140 4. 0000 3 .9974 0.06 96.585 96.042 -0.06

6 348.143 4. COOO i .9958 0.08 10 7.094 107.176 -0.08

6 373.150 4. 0000 3 9931 0.05 117.577 117.630 -0. 05

6 398. lbO 4. 0000 3 .99 34 0.01 127.993 128. Oil -0.01

6 273.150 4.5000 + .50 J6 -0.01 63. 156 83.147 0. 01

6 298. li»2 4.50G0 * .*935 0.03 95.511 95.539 -0. 03

b 303. 143 4. 5000 * 4999 0.00 96. 002 98.004 -0. 00

b 323.140 4.5000 4 .4934 0.04 107.779 107.815 -0.03

6 348. 143 4.5000 * ,*973 0.06 119.920 119.990 -0.G6

6 373.150 4. :>0G0 * .4930 0.G4 132.013 132. 07G -0.C*

6 398. lbO 4. 5000 * 5 37 -0. 02 144.083 1*4. 060 0.02

b 273.150 5. UOCO 5 ,0 010 -0.02 90.802 9G.786 0.02

6 298.142 5.0000 + 9931 0.02 104.911 104.926 -0. 02

6 303. 1*3 5.0000 5 ,0332 -0.00 107.7*5 107.7*2 0.00

6 323.140 5. OGOO * .9938 0.02 118.912 118. 94C -0.02

6 3*8. 143 5. 0000 4 9930 J.U4 132.781 132. 834 -0. 04

6 373.150 5.0000 + ,9938 G.02 146.583 1*6. 6ie -0.02

6 398. lbO 5.U0G0 5 .0015 -0.03 160 . 3*6 loG. 29t 0. G3

b 273.150 5.5000 5 .5029 -0.05 98.315 98.272 0.C4

6 293.142 5.50G0 3 .5010 -0.02 114.261 11*. 243 0. 02

b 3J3.1*3 5. aOOO 5 5015 -0.03 117. 449 117.421 0.02

b 323. 1*0 5.5000 5 .4932 0.03 130.030 130.071 -0. C 3 b 3*8.143 5.50G0 j 49 32 C.01 145.7*6 145.767 -0.01

6 373.150 5.5000 5 .4334 0.01 161.321 161.338 -0. 01

6 393. lbO 5.50G0 3 30 3 1 -0.06 176.887 176.765 0.G6

b 273.150 b. 0000 3 0017 -0.03 105 .b60 105. b55 0.G2

6 298.142 6. 0000 3 0025 -0. 04 123.585 123.536 0.04

6 303.143 6.0000 6 0032 -0.05 127.160 127.097 0. 05

6 323.140 6.00G0 5 9* 37 0.01 141.261 1*1.268 -0.C1

b 3*3.143 6.0000 3 .00 16 -0.03 158.896 158. 85* 0.0 3 b 373.150 6. GOOO 6 .33 33 -0.01 176. 308 176.296 0.01

b 398. lbO 6. GOuG 3 JO iO -0.05 193.701 193.600 0. 05

6 273.150 6.5000 O .50*9 -0.08 113. 057 112. 986 0. G6

b 298.142 6. 5000 3 5J38 - J . uo 132,9*1 132. 87G 0.05

b 303.143 6.5000 3 ,50+6 -0.07 136.921 136.828 0.G7

b 323.140 6.50G0 3 50*3 -0.G7 152.692 152.593 0.06

b 3*8.1*3 6.50G0 3 50 13 -G.02 172.195 172. 16C 0. C 2 b 373. 150 6. 5000 6 5 3 35 -0.01 191.585 191.570 0.01

b 393. lbO D.5000 3 .5057 -0.G9 211.015 210.818 0.09

b 273.150 7.00GO 7 .0121 -G.17 120. *94 120.316 0.15

b 298.1*2 7.0000 7 .00i2 -0.09 142.411 142.294 J. 08

b 303.1*3 7. UOOO 7 .0039 -0. 10 146.809 146.671 Q. 09

b 323.140 7.00GO 7 +4 -0 .06 lb*. 208 lo4. 107 O.Cb

6 3*8.1*3 7. oOOO 7 ao + i -0.0b 185. 8e5 185.753 0. Go

b 373.150 7. GOOG 7 .0039 -0.06 207.3*7 207.225 O.Cb

b 398. lbO 7. 0000 7 .0053 -0.08 223.706 2 2 8.516 0. 08

b 273.150 7.50G0 7 .5137 -C.14 127. 854 127.696 0.12

b 298.142 7. 5000 7 .5039 -0.12 162. 040 151.868 0.11

b 303.1*3 7.5000 7 ,53 +9 -0.06 15o.763 156.685 O.Cb

b 323.140 7.5000 r ,5038 -0.05 175.9t>6 175.875 0.05

6 343-143 7.5000 7 5037 -0.05 199.807 199.703 0.05

6 373.150 7.5000 7 .5030 -G .04 223. 44G 223.3*2 0. G4

b 398. lbO 7.5000 7 .5074 -0.10 247.053 246.776 G. 11

63
METHANE EQUATION OF STATE

T,K MOL/L CAL^D O.PCT Pi, BAR CALCD P.PCT

o 273.150 8. U0G0 3.0151 -0.19 135.,*10 135.182 0.17

6 298. 1*2 8.GG00 3 . 1 J 8 -0.1* 161.,873 161.658 0. 13

6 303. U3 8. 0000 3.0095 -0.12 167.,135 166.936 0.12

b 323.1<«0 8.0000 3.0071 -0.09 188.,1*2 187.968 0.09

b 3*8.1*3 8.0000 3.00** -0.05 21*,,218 21*. 091 0.C6

6 373.150 a. oooo 1.0022 -0.03 2*0.,078 2*0.005 0.03

b 398. 160 8. COCO 3. 0035 -0.11 266. 023 265.69* 0.12

6 273.160 8.^000 3.5156 -0.18 1*3., 090 1*2.8*7 0.17

b 293.1*2 8.50uG 3.511* -0.13 171.,979 171.7*5 0.1*

b 303. 1*3 8.5000 3.5136 -0.12 177.,736 177.506 0.13

6 323. 1*0 8.50 3.5J76 -0.09 200,,673 200. *7£ 0.10 3*8.1*3 3.5000 3. 5059 -0.07 229., 193 229.013 0.G8

b 373.150 8.5000 3.50 30 -G.0* 257,,*27 257. 32C 0.0*

b 398.160 8.5000 3.5095 -0.11 285,,758 285.376 0.13

b 273.150 9. 0000 9.0190 -0.21 151,,0 95 150.787 0.20

6 298.1*2 9.00G0 3.0111 -0.12 182,,*70 182.232 0.13

b 303. 1*3 9. 0000 9.0101 -0.11 188,,733 188.506 0.12

b 323.1*0 9. 0000 9.30 91 -0.10 213,,759 213. 516 0.11

b 3*8.1*3 9. 0000 9.0056 -G . Go 2**,,766 2**. 589 0.C7

b 373.150 9.0000 9.033b -0.01 275.,*3* 275. *13 0.01

b 398. 160 9.0000 9.0039 -0.07 306,,209 305.959 0.08

b 273.150 9.5000 9.5127 -0.13 159,, 3G7 159. C92 0.1* 298.1*2 9.5000 9.5u39 -0.09 193,, *23 193.223 3. 10

b 303. 1*3 9.5000 9.505* -CO* 2G0. 116 200. 035 0. c * b 323.1*0 9.5000 9.5062 -0.06 227,, 3c6 227.193 0.08

b 3*8.1*3 9.5000 9.5025 -0.03 261,,0?* 2o0.939 0. C 3 b 373.150 9.5000 9.5G17 -0.02 2 9*,,*7e 29*.*13 0.02

b 398.160 9.5000 9.53o5 -0. 07 327. 865 327.577 0. 09

b 273.150 10.0000 10.0036 -0.09 167,,979 167.826 0. 09

b 298.1*2 10.0000 13.0015 -u.01 20*.,825 20*. 790 3.02

6 303.1*3 10.0GOO 9.9972 0.G3 212,,100 212.169 -0.0 3 b 323. 1*0 10. 0000 9.9930 u.02 2*1,, b3* 2*1.593 -0.02

b 3*8.1*3 10.0000 9.997G 0.03 278, C*8 276.155 -0.0*

b 373.150 10. uOGO 9.9959 0.0* 31*.,25C 31*. *17 -3.05

b 398.160 10.0000 10.303* -0.03 35U,, *9* 350. 33t 0. 05

b 273. 150 10.5C0G 19.*931 0.02 177,, 002 177.037 -0.02

b 298.1*2 10.5000 13.*978 C.02 216,,938 216.992 -0.0 3 b 303.1*3 10.5000 13. *9 57 0.06 22*,i 8C5 22*. 97C -3. C7

6 323.1*0 10.5000 13.*932 0.0b 256, 572 256. 7R3 -0. 08

b 3*8.1*3 10.5000 13.*9?0 G.08 296., 01* 296.313 -0.10

b 373.150 10.5000 13.*935 0.09 335,,101 335.512 -0.12

b 398.160 10. 5000 13.*J95 0.01 37*., 301 37*.32e -0.0 1 b 273.150 11. 0000 ii . o a a i -0.00 186. 780 136.779 0.00

b 298.1*2 11. 0G00 13.9922 0.07 229.,b88 229.893 -3.09

b 303.1*3 11.0000 13 .992* 0.07 238., 292 238.503 -0.09

b 323.1*0 11. 0000 10.9910 0.08 272.,539 272.836 -0. 11

b 3*8. 1*3 11. 0000 13.9332 Q. 11 315. J31 315. *9* -0.15

b 373.150 11. GOCo 13 .93 9* 0.10 357.,297 357.786 -0. 1*

b 398.160 11. OCGO 10.9976 0.02 39 9.,523 399.6*6 -0.C3

b 273.150 11.5000 ll.*957 0.03 197,,051 197.122 -3. 0*

b 298. 1*2 11. 5000 11 .*956 0.0* 2*3.,*51 2*3.675 -0.05

b 303.1*3 11.5000 11. *3 3* u.10 252. 507 252.851 -0. 1*

b 323.1*0 11.5000 ll.*91* 0.G7 289.,5*2 289.6** -0.10

b 3*8.1*3 11.5000 U.*33* J. 1* 33? , Id* 335.798 -0.21

b 373.150 11.5000 ll.*932 0.09 380,,36b 381 .3^,3 -3.13

b 273.150 12. 0000 12.301* -0.01 208,.211 208.179 0.C2

b 298.1*2 12. 0000 11.9931 G. Ob 257,.950 258. lot -0.08

b 303.1*3 12.0000 11.9918 0.u7 267 .883 268. 1*1 -3.10

b 323. 1*0 12. 0000 11.9397 G.09 307 .555 307.9*0 -3.13

b 3*3.1*3 12. 0000 11. 9839 0.13 356 .651 357. 369 -0. 20

b 373.150 12. OOGO 11.9921 0.07 *Q5 ,932 *06. 3*1 -0. 10

b 273.150 12.5000 12.5072 -0 .Ob 220 .275 220. 097 3.08

b 293.1*2 12.5000 12. *9 93 0.01 273,.7 88 273. 81C -0. 01

b 303.1*3 12. 5000 12.*917 0.07 28* .252 28*. 536 -3. 10

o 323.1*0 12.5000 12.*920 0.06 326,,97* 327. 291 -0.10

b 3*8. 1*3 12.50GC 12.*917 G.07 379,.993 380. 367 -3.10

NP 171, ONRMSPCT = 3-065, P1EANPCT = 0.05*

64
METHANE EQUATION OF STATE

10 T,K MOL/L CALOD O.PCT P.BAR CALCD P,PCT

8 203.081* 0. 060* 3.060* -0.0 + 1.013 1. 013 0.0*

8 223. 21*9 0.051*9 J .05+8 0.06 1.013 1.01* -0.06

8 2*8.175 0. 0*93 0.0*93 0.02 1.013 1. 013 -0.02

8 273.150 0.0**7 J.0++7 -0.01 1.013 1.013 0.01

8 298.11*2 0.0*09 0.0*09 -0.01 1.013 1.013 0.01

8 323.11*0 0. U378 0.0378 -0.02 1.013 1.013 0.02

8 373.150 0. 0327 J. 0327 -0.02 1.013 1.013 0.02

8 1*23.170 0.0288 J. 0238 -0.01 1.013 1. 013 0. 01

8 473.193 0.U258 J. 0258 -0.00 1.013 1.013 0.0

8 203-081* 1. 3818 1. 3870 -0.38 20.265 20.200 0.32

8 223.21*9 1.206* 1.2092 -0.07 20.265 20. 252 0.06

8 298.11*2 0.8*79 D.8+58 0.13 20.265 2U.2 90 -0. 12

8 203.081* 2.27U1 2.2696 -0.86 30.397 30.201 0.65

8 223.21*9 1.9191 1.3265 -C.38 30.397 30.300 0.32

8 2*8. 175 1.6396 1.6*11 -0.09 30.397 30. 372 0. C6

8 273.150 l.+*22 l.**25 -0.02 30.397 30. 392 0.02

8 323.11*0 1.1757 1.1752 0.0* 30.397 30.*09 -0.0*

8 373.150 1. 000* J .9989 0.16 30 .397 30. +** -0.15

8 1*23.170 0.8729 0.1717 0.1* 30. 397 30.**1 -0.1*

8 1.7 3.193 0.775C 0.77+7 0.0* 30. 397 30. +09 -0. 0*

8 203.081* 3.*113 3.*516 -1.16 *0.530 *0.227 0.75

8 223.21*9 2.732* 2.7+70 -0.53 +0 .530 +0. 362 0.*1

8 2*8.175 2.2722 2.2767 -0.20 *U. 530 *0.+6C 0.17

8 273.150 1.973* 1.9736 -0.01 *0.p30 *0.526 0.01

8 298.11*2 1.75*1 1.75+7 -O.03 *0 .530 +0.519 0.03

8 323.1-*0 1.5853 1.5862 -J. 05 *0.630 *0.509 0.0 5

8 203.081* 5. 0533 5 . 15+* -2.00 50.662 5L.187 0.9 + 8 223.21*9 3. 68*5 3 .7 u 50 -0.56 50 .662 50. *62 o.*o

8 273.150 2.5315 2.5312 0.01 50 .062 50.b66 -0.01

8 373.150 1.6653 1.6837 U.10 50.6fc2 50.712 -0. 10

8 i*23.170 l.*597 1.+5 95 0.01 50 .ot2 50.666 -a. oi

8 1*73.193 1.2919 1.2923 -0.0* 50.6b2 50. 6*5 0-0 + 8 203.081* 7.9718 1.39 J 2 -5.25 60. 795 59. 86* 1.63

8 223.2i*9 +.8339 +.3315 -0.36 60 .795 60.65* 0.23

8 2*8.175 3.70*7 3.7135 -0.2* 60.795 oO.cdl 0.19

8 273.150 3. 1161 5.1158 0.01 60.795 60.801 -0. 01

8 298.11*2 2.718* 2.7217 -0.12 60 . 795 60.726 0.1 1 8 323.11*0 2.*350 2. +337 0.05 60 .7 95 60.82* -0.0 5 d 1*23.170 1.7532 1.75*6 -U.08 60.795 60.7+8 0.08

8 i*73.193 1.5505 1.5509 -0.02 60.795 60.78C 0.02

8 203.061* 9.982b 1J.D716 -6.90 65. aol 6+.2*e 2.*5

6 2 3.0 81* 11.8896 12. +3+5 - + •58 70. 927 69. 119 2.55

8 223.2i*9 6. 1860 6.23 92 -0.63 70.927 7 0.5 85 0.*6

8 203.081* 13.9975 1+.30+* -2.19 61 . UcO 78. 81C 2.76

8 223.21*9 7.7710 7.3712 -1.29 81. 060 80.+7C 0.73

8 2>*8.175 5.3793 5.*037 -C*5 81. 060 60.787 0. 3*

8 273.150 *. 3636 '+.36 56 -0.0* 81 . OoO 81. 03C 3. 0*

8 298.11*2 3.7389 3.7-*27 -0.10 81.060 80.987 0.09

8 323.11*0 3.3109 3.313* 0.01 81.0c0 81.071 -0.C1

8 223.21*9 9.*350 9.5707 -1.** 91. 192 90.3*6 0.93

8 203.081* 15.9266 15.0o29 -0.86 101.325 99.18* 2. 11

8 223.2*9 10.9398 11. Jo 32 -1.13 101.325 100. *22 3.89

65
METHANE EQUATION OF STAT:

T,K MOL/L cal;o O.PCT P.BAR CALCL P.PCT

8 2*8.175 7.2518 7. 30 35 -0.71 101.325 100.788 0.53

8 273.150 5.69*9 5.7061 -0.20 101.325 101. 159 0. lb

a 296.1*2 *.7990 *.3075 -0.13 101.325 101.16fc 0. 16

8 323. 1*0 *. 2U*8 *. 20 9i -u. 10 101. 325 101. 227 0.10

8 203.08* 16.9028 17.0852 -1. 08 121.590 117. 3bb 3.*7

8 223.2*9 13. 1G53 1 5.28o2 -1.38 121.590 119.526 1.70

8 2*6.175 9. 1316 9 . 2 1 J 5 -0.6b 121.590 120.705 0.73

8 273.150 7. 0576 7 . 3867 -U • *1 121.590 121.163 0.35

8 298.1*2 5. 880b 5.3953 -0.25 121.590 121. 317 0.22

8 323.1*0 5. 1121 5.11 92 -0.1* 121.590 121 .*31 0.13

8 203.08* 17.6717 17.3222 -0 .85 1*1.855 137.26* 3.2*

8 223.2*9 1*. 5*71 U. 7 j J5 -1.05 1*1 .855 139.237 1.85

8 2*8.175 10. 7931 1 J.3j55 -0.67 1*1.856 1*0. 890 0.66

8 273.150 6.3962 3.*J61 -I .*6 1*1.655 1*1.237 0.**

8 296.1*2 6.95** 0.9769 -0.32 1*1.855 1*1. *29 0.30

8 323.1*0 6. 0156 o . J 2 o 1 -0.17 1*1. a^s 1*1. 62C 0.17

8 203.08* 13.2772 18.*052 -0.70 162. 120 157.312 2.97

8 223.2*9 15.5521 15.o^79 -C .9* 162. 120 156.769 2.07

8 2*8.175 12. Into 12.2*?5 -0.79 162. 120 160.563 0. 9fc 8 273.150 9.6370 9.5733 -a. 1*1 162.120 161. **1 0.*2

a 298.1*2 7.9959 i.adiz -0. 3* lo2.12G 161.576 0. 3*

8 323.1*0 6.9022 6.91** -0.18 lo2. 120 161. 637 0.17

8 205.08* 18.7732 18.8913 -0.63 162.385 177. 167 2. 87

8 223.2*9 16.3*6* 16 • *o55 -0.72 182. 385 176.965 1.66

a 2*6.175 13.2*22 15. 3.;>5* -0. 65 182.385 18C. Ill 1.25

6 273.150 10. 7591 10.7780 -0.' 8 162. 365 162.016 0.20

8 298. 1*2 8.97*3 i. J071 -0.37 162. 365 181. o62 0.39

8 323.1*0 7.7605 7.7711 -0.1* 182.365 182. 129 0. 1*

8 373.150 6. 19*6 :>.2J96 -0.10 182.365 182.202 0.10

6 203.08* 19.210* 19.311* -0.52 202.650 197. 56e 2.51

8 223.2*9 16.9755 17. J9 J3 -0.68 202. b50 198.6*2 1.98

8 2*6.175 1*.15*7 1*.255* -0.72 202.650 200. 152 1.23

6 273.150 11.7211 LI .75*1 -0.28 2C2.65C 201.915 0.36

8 296.1*2 9.6855 9.9095 -0.2* 2C2.650 202.087 0.28

8 323.1*0 8.5699 6.56*9 -0.17 202.650 202.266 0.19

8 373.150 6. 6*03 5 . 65 i3 -0.22 2 2 . 6 S 202. 176 0.23

8 *23.170 5.7691 5.76*1 -0.26 202. O 50 202. 089 0.26

8 •73.193 5. 03o3 5.0*5* -0.18 202.650 202. 25? 0. 19

8 203.08* 20.0835 2J .1jo9 -0.*2 253.313 2*7.78 1 2. 16

8 223.2*9 18.20.j3 16.26*7 -0.45 253.313 2*9. 266 1.59

8 2*6.175 15.0229 15.9211 -0.62 253.313 2*9. 731 l.*l

8 273.150 13. col* 13.7025 -0.30 253. 313 252. 050 0. 50

8 298.1*2 11.6075 11.8376 -0.25 253. 313 252. *26 O.o5

8 323.1*0 10.375* 1J . 33 32 -0.12 253.313 252.916 0.16

6 373.150 8.3661 3.3651 -0.2* 253.313 252.613 0.28

8 *73.193 b. 17*7 6.1906 -0.26 253. 313 252.57* 0.29

8 2 J 3. 8* 20.7751 20.85J1 -0.36 303.975 297.925 1.99

8 223.2*9 19.0963 19.1771 -0.*1 303.975 298.989 1.6*

8 2*8.175 17. u283 17.10 +6 -f.*5 303.975 300. 25C 1.23

8 273.150 15.0906 15.12 j* -0.16 303.975 302. o37 0.37

8 298.1*2 13. 3339 1 5 . 3 b j 2 -0.2* 3U3.975 302.773 o.*o

8 323.1*0 11.6878 11.89 32 -0.05 303.975 303. 77t 0. 07

8 373.150 9.7327 9.7*23 -u . 10 303.975 303.59* 0.13

66
METHANE EQUATION OF STATE

10 T,K MOL7L CALJD D,PCT P GAR CALCD P.PCT

8 423.170 8.2645 3.29*0 -0.36 303 975 302.674 0.43

6 473.193 7.2369 7.2ol5 -0.31 303 975 302.865 0.37

S 203.084 21.8555 21.9229 -0.31 405 300 398.076 1.78

8 223. 249 20.44*3 2J.5051 -0.29 405 300 400. 047 1.30

8 248.175 18.7101 13.7744 -0.34 405 300 400.609 1.16

8 273.150 17. 0890 17.11+9 -0.15 + 05 300 403.685 0.40

8 296.142 15. 55b8 15.5774 -0.13 + 05 30C 404. 1+9 0.28

8 323.140 It. 1884 14.2021 -0.10 405 300 404.586 0.18

6 373.150 11.9826 11.9798 0.02 405 300 405.442 -0.04

8 423.170 10. 3595 10 .3o+4 -0.05 + 05 300 405. 033 0.07

8 473.193 9.1334 9.1j52 -0.36 + 05 300 403.406 0.47

8 203. 084 22.6624 22.7od1 -0.46 50b 625 493. 032 2.68

8 223.249 21.4329 21.4)90 -0.31 50o 625 499. 13e 1.48

8 248.175 19.9278 19.971G -G.22 50o d25 502.467 0.c2

8 273.150 18.5015 13.5062 -0.C3 506 625 506.229 0. 08

8 298.142 17.1165 17.1324 -0.09 506 >b25 505.421 0.24

8 323.140 15.6521 15.3717 -0.12 50o 625 505.255 0.27

8 373.150 13.7378 13.7233 0.07 506 ,625 507. 24f -0.12

6 -.23.170 12.0596 12.0610 -C.01 506 625 506.537 0.C2

a 473.193 10.7489 10.7735 -0.23 t?06 ,625 504.941 0.33

8 203.084 23.3596 23. +o99 -0.47 607 950 590. 98L 2.79

8 223.249 22.2294 22.30 11 -0.35 607 ,950 597.261 1.75

8 2+8.175 20.8o23 20.91+4 -0.25 607 950 601.807 1. 01

8 273.150 19.5734 13.5810 -0.04 607 950 607.149 0. 13

8 298.142 18.3049 18.32+8 -0.11 607 9v0 606. 061 0.31

8 323.140 17. 1425 17.1584 -C.09 607 950 606.5+5 0.23

8 373.150 15. 1352 13.1212 0. 09 607 950 609. 079 -0. 19

8 423.170 13.4603 13.46 52 -0.07 607 950 607.249 0. 12

8 473.193 12. 1247 12.1452 -0.17 607 950 60b. 313 0.27

8 203.084 23.9594 2+.0732 -0.50 709 275 688.301 2.96

8 223.249 22.9159 22.9958 -0.35 709 275 696.725 1.77

8 248.175 21.6406 21.7 J00 -0.27 709 275 701.031 1.16

8 203.084 24.4532 2+.61 95 -0.68 310 oOO 778.233 3.99

8 223.249 23.4668 2i.59?6 -0.56 alO bCC 787.505 2.65

8 248.175 22.2969 >2.3f76 -0. 36 810 600 797.806 1.58

8 273.150 21.1777 21.2125 -0. lo 810 600 605.566 0.62

8 298.142 20. 0986 20.1116 -0.06 810 bOO 808.673 0.21

8 323.140 19. 0499 1 9 . 7 i 9 -0.16 810 600 806.862 0.4b

8 373.150 17.2472 17.2324 0.09 310 bOO 612.271 -0.21

6 423.170 15.6727 15.6u37 0.04 610 600 811.239 -0.08

8 473.193 It. 3403 14.35+1 -0.10 810 600 809. 144 0.18

8 203.084 24.9163 25. 1J70 -0.77 911 9 25 871.132 4.47

8 223.249 23.9639 2+.1355 -G.63 9.11 925 382.275 3.25

8 248.175 22.8601 22.9732 -0.51 911 925 891.365 2.25

8 203.084 25. 3296 25.5529 -0.88 1013 250 961.450 5. 11

8 223.249 24. •55b 2+.62J2 -0.69 1013 250 977.377 3. 54

8 246.175 23.4024 23.51+3 -0.48 1013 250 991. 336 2.16

8 273.150 22.3610 22.4553 -0.42 1013 250 99D.203 1.68

8 298. .42 21.4062 21.4530 -0.22 1013 250 1005.343 0.78

8 323.140 20.4724 20.5103 -0.19 1013 250 1007.204 0.60

8 373.150 18.6247 13.80+9 0.11 1013 250 1016.155 -0. 29

6 •+23.170 17.33cl 17.32 36 0.04 1013 250 1014. 142 -0. C9

6 473.193 16.0518 15.0 6 26 -0.07 1013 ,250 1011.309 0.14

NP = 158, DNRMSPCT = 0.927, P-IEANPCT 0.811

67
METHANE EQUATION OF STATE

10 T,K MOL/L CAL3D O.PCT P BAR CALCD P,PCT

10 111.230 27.9096 27.7366 0.62 287 000 33C *3C -15.13

10 111.230 28. 3o-t 28.1320 0.*3 *02 000 *35. *02 -8.31

10 111.230 28.727* 23.6a 38 0.** 519 000 555. 859 -7. 10

10 111.230 29.3c00 29.2876 0.25 726 000 7*8 629 -3. 12

10 121.190 26.7237 20.7359 0.07 218 000 221 629 -1.66

10 121.190 27.2628 27.2*57 0.07 335 .000 339. **3 -1. 33

10 121.190 28.o779 23.771* -0. 33 7*6 000 717 882 3.77

10 121.190 29.21*1 29. 5 3 93 -0.63 9*2 000 883 15 8 o.25

10 121.190 29.7000 33.0231 -1. 10 11** 000 1038 585 9.21

10 131.790 27.1518 27.33^2 0.20 *65

000 *77. 92^ -2.78

10 131.790 27.7008 27. 6b53 0.12 b07 000 615 1*2 -1.51

10 131.790 28.177U 23.17'6 -0.00 7*6 000 7*7 769 0. 03

10 131.790 28.60*1 23. 6ol6 -0.20 892 000 67* 3*5 1. 98

10 131.790 29.o3oO 2 3.15'* -0.*2 10*8 000 1009 132 3.71

10 li.3.820 26.H131 23. *0 38 0.01 *83 000 *83 708 -0.15

10 1*3.820 27.2926 27.3*5 7 -0.19 7 05 000 691. 261 1.95

10 1*3.320 28. 1373 23.27 91 -0.50 968 000 925 5*fc *.3*

10 156.960 25.5297 23.6325 -0.*0 *95 GoO *75 *25 3.95

10 156.960 26. 1575 2o.22*C -0.25 617 000 602 *79 2.35

10 15o.9b0 26.7451 25.37 m -0.*7 769 000 737. 990 *. 03

10 156.960 27 .371*6 27.5527 -0.65 951 oOO 901 *ie 5.21

10 Io7.ol0 2*.*616 2*.*o37 -u.03 *15 00 *13 773 0.30

10 167.610 25.2653 25. 3o 3b -0.17 550 000 551 797 l.*6

10 lo7.610 26. 1370 2o.2l7l -0.31 751 000 732 6*6 2. **

10 167.610 26.838* 26.3525 -0.*6 3 3o 000 933 38? 3.*8

10 179.290 2* . 160* 2. .1537 0.00 *88 000 *68 Ill -0.C2

10 179.290 25.5*93 25.6153 -0.26 756 000 7*3 o*E 1.89

10 179.290 26. 5111 23.6*20 -o.*9 1003 000 969 062 3.38

10 192.870 22. 0b0* 21.99 (8 0.30 33~t 000 3*0 782 -2.03

10 192.870 23.56*9 23.5oo5 C.08 5 29 0-0 531 75* -0.52

10 192.8 70 2*. 6*27 2*.6ol9 -0.08 71* 000 710 368 0.51

10 192.870 25. 7998 25.895* -0.3b 979 000 956 b&6 2.29

10 212. J00 21. 2*u* 21.25J9 -0.05 *J1 000 399 97* 0.26

10 212.000 22.7739 -"2.3011 -0.12 56o oco 532. 1** 0.6b

10 212.000 23.7*17 25.3133 -0.29 7*6 7 in 02C 1.61

10 212.000 2*. 7*63 2+.3?55 -G.*3 950. 300 927 097 2.*1

10 225.070 20.olul 23.62 59 -0.07 ^26 000 *26 o97 0.3C

10 225.070 22.2519 22.3239 -0.35 o25 000 61* 392 1.70

10 225.070 23.*797 23.576* -0.*1 823 000 805 795 2. 09

10 225.070 2*. 7219 2*. 3723 -0.61 1067 uOO 1053 005 3. 13

10 237.570 17.9*37 17.3*53 -0.01 302 000 301. 912 0.03

10 237.570 21. *638 2l.*d51 -0.10 bOb 000 63 3 3^3 0.**

10 237.570 23.5, 93 23.5*27 -0.27 9*b uOO 933. 8*6 1.28

10 2*9. *30 18. 8076 13.7o3* 0.22 *11 0G0 *1* 071 -0.75

10 2*9. *3Q 20.6016 23 .5115 -0.05 581 000 579 693 0. 19

10 2*9. *30 21.8579 21.8833 -0.10 7 ** 000 7*0 7*9 0.**

10 2*9. *30 23- 0256 23. 0653 -0.2b ->^2 000 931. i7U 1.15

10 2ol.550 17.91*7 17.3937 0.09 *G7 000 *03 06* -0. 27

10 2ol.550 19.*bcb 13.*o27 0.02 533 000 533 37t -0.07

10 2ol .550 20.7512 23.80 11 -0.2* o80 00 673. 75* 0. 92

10 261.550 21.7628 21.6*o7 -0.39 82o OCC 813 157 1.55

10 261.550 22.7583 22.8751 -0.51 1001. ooc 979. *21 2.1o

10 278. 710 15. 775* 15. 70 37 0.*2 3*3 000 351. 227 -0.93

10 278.710 18. 1752 13.1132 0.36 500 OCC 535, 269 -1.05

10 278.710 19.51oC 1 3.**33 0.35 o2* ceo 631 21* -1. lo

10 278.710 20.7211 20. 6 9.'8 0.11 77* 000 777. 15* -o.*i

10 278.710 22.1268 22.1*71 -0.06 959 oOO 995. 763 0. 32

10 293. mo 16. 7963 13. 31U -0.03 *65 000 *o* 086 0.20

10 293. *10 18. 6*t£ 13. 37o6 -0.16 o*0 OCC 63b. 895 0.*9

10 293. -+10 20. 1776 23 . lo 31 0.05 791 uuC 792. 250 -0. lb

10 293. *10 21.2089 21.23 32 -0.1* -)'*7 oco 9*2 166 o.e i 10 303.290 1*.2227 1*.22 53 -C.03 369. ooc 3o8. 625 0.C5

10 303.290 16.o69* 1 o . o a 2 6 -0.03 51b 000 515. 02C 0.19

10 309.290 19. *570 13. *3 35 0.31 oo7 oco 672. 3*3 -0.88

10 309.290 19.92oo 13.917* O.05 d*7 000 8*8. *77 -0.17

10 303.290 21.2721 21.2931 -0.08 1056 oCO 105*. 889 0.29

NP = bb, ONRMSPCT = 3.329, P1EANPCT = 2.037

68
METHANE EQUATION OF STATE

ID T,K MOL/L CALCD 0,PCT P,BAR CALCD P.PCT

4101 176.000 2.9954 3.0uh7 -0.31 27.962 27.919 0. 15 4102 180.000 2.9936 3.0035 -0.33 29.335 29.263 0.18

4103 184.000 2.9918 3.3020 -0.34 30.683 30.o24 0. 19 4104 188.000 2.9901 2.9 9 37 -0.32 32. 008 31.946 0. 19 "105 192.000 2.9883 2.9974 -0.30 33.316 33.253 0. 19 •106 196.0 00 2.9865 2.9951 -0.29 3h.610 34. 546 0.19

h107 200.000 2.9846 2.9926 -0.26 35.890 35.827 0.17

4108 20H.000 2.9831 2.9901 -0.24 37.158 37.098 0. 16 4109 208.000 2.9813 2.9877 -0.21 38.H17 38.359 0.15

tllO 212.000 2.9796 2.9851 -U- 19 39.665 39.612 0.13

4111 216.000 2.9779 2.3328 -0.17 40.907 40. 657 0. 12 4112 220.000 2.9761 2.9806 -0.15 42.142 42. 094 0.11

Hi 13 225.000 2.9739 2.3776 -0.12 n3.b73 43.631 0.10

4114 230. 300 2.9717 2.97h9 -0. 10 45. 196 45. 159 0.08

4115 240.300 2.96 7 5 2.96 36 -0.08 46.219 48. 189 0. C6

^1 lb 250.000 2.9630 2.96h3 -0.0H 51.203 51.185 0.04

tl 17 260.000 2.9585 2.93 31 -0.02 5h. IdO 54.152 0.01

Hi 18 270. 000 2. 9540 2.9538 0.01 57.089 57.092 -0.01

Hi 19 280. 000 2.9H95 2.9438 0.02 59.996 60. 006 -0.02

Hi 20 290.000 2.9450 2. 9h54 0.05 62.072 62.902 -0. 05

Hi 21 300.000 2.9hC2 2.93 32 0.03 d5.7h8 65. 768 -0. 03

40 01 184.000 3.9782 3.9524 0.65 35. 156 35.25C -0.27

h002 188.000 3.9756 5.9632 0.39 37.096 37.162 -0.18

40 03 192.000 3.9730 3.9627 0.26 38.989 39. 039 -0.13

hOQ4 196. 000 3.97C5 3.9724 -0.05 HO- 900 40.889 0.03

4005 200.000 3.9683 5.97 54 -0.13 42.750 42. 719 0.07

hOOo 20h.OO0 3.9654 3.9730 -0.11 44.556 44.52t 0.C7

40 07 208.000 3.9629 3.3o72 -0.11 Hb

.

3h9 46. 318 0. 07 h008 212.000 3.9bOH 3.96+1 -0.10 48.124 48. 095 0.06 hOG9 216. 000 3.9579 3.9611 -0.08 1+9.8 85 49. 859 0.05

4010 220.000 3.9554 3. 957

8

-C.Ob 51.632 51.610 0.04

hOII 225.000 3.9522 3.9539 -0.0H 53. 800 53. 784 0.03

4012 23U.000 3.9490 3.943? -0.02 55.949 55.942 0.01

4013 2nd. 000 3.9427 5.9h17 0.03 60.204 60.216 -0.C2

h014 250.000 3.9363 3.9339 0.06 64.407 64.439 -0.05

H015 260. 000 3. 9300 3.92 65 0.09 68.568 68.bl7 -0.07

HO lb 270.000 3.9235 3.91 36 0.12 72.682 72.754 -0. 10 h017 280.000 3.9170 3.9114 0.14 76.756 76.853 -0.12

40 18 290.000 3.9104 3.90HH 0.15 80.805 80.915 -0.14

H019 300.000 3.9036 3.8975 0.16 84.819 34.942 -0.15

3901 138. 000 4.9304 +.8971 0.68 40.276 4U.3bl -0.21

3902 192.000 H.9269 4.9U18 0.51 42.770 42.851 -0.19

3903 196.0 00 H.9236 +.90 53 0.37 45.221 45. 292 -0. lb

39 Oh 200.000 4.9202 '+.9032 0.24 47.641 47.695 -0.11

3905 204. 300 4.9169 +.9105 0.13 50 .0 36 50. 068 -0.06

3906 208.000 4.9135 +.9122 0.03 52.4C9 52.416 -0. 01

39 07 212. 000 4.9102 h . 9 1 3 3 -0.00 54 . 744 54.743 0.00

39 08 216.000 4.9069 H.9071 -0.00 57.052 57.051 0.00

3909 220.000 4.9035 h.9020 0.03 59. 330 59. 341 -0. 02 3910 225.000 H.8994 +.8938 C.01 62.178 62.183 -0.01

3911 230.300 4.8952 h.89h3 0.02 64.995 65.003 -0.01

3912 2hJ. 000 4.8868 4.88-t6 O.OH 70.563 70.58fc -0. 03

69
METHANE EQUATION OF STATE

10 T,K MOL/L cal:o D.PCT P.8AR CALCD P.PCT

3913 250-000 *. 87o* *.8750 0.07 76. 060 76. 101 -0.05

391* 260.000 *.8699 *.8o5l 0.10 81.*91 81.555 -0.08

3915 270.000 *. 861* *. 85 5* 0.12 86.867 86*95* -0. 10 3916 260.000 *.8527 *.8*59 0.1* 92.190 92.301 -3. 12 3917 290.000 *. 8**0 *.83o7 0.15 97.*69 97.599 -0.13

3918 3u0.000 *.8353 *.82f* 0.16 102. b99 102.850 -0. 15 3601 192.000 5.9*78 5.9130 0.*9 *5.371 *5.*27 -0.12

3802 19o.3 00 5.9*35 5.9259 0.30 *8.*93 *8. 539 -0. C9

38 03 20J.000 5.9392 5.9273 0.20 51.565 51.59* -0. 08

38 0'* 20*. 000 5.9350 5.92:11 0.12 5*. 580 5*.o07 -0.05

38 05 208.000 5.9307 5.9237 0.03 57.577 57.58t -0.02

3806 212. 000 5.926* 3.9255 -0. 00 63.538 60.537 3.00

38 7 216. J00 5.9222 5.9232 -u.02 63.*71 63.*6£ 0.01

3808 220.000 5.9179 5.9136 -0.01 66. 376 66. 371 0.01

3809 225.000 5.912c 5.9137 -0.02 09.966 69. 97

0. 01

36 10 230. 000 5.9072 5.9331 -0.02 73.565 73.558 0.01

3811 2*0.000 5.6965 5.8958 0.01 80.6*1 80.6*6 -0.01

3812 253.000 5.8857 5.8835 0.0* 87.631 37.656 -0.03

3813 260. OuO 5.87*9 5.8712 0.06 9*. 5*2 9*. 589 -0. 05 381* 270.000 5.86*0 5.8531 0.08 101.38* 101. *5* -3.07

3615 260.000 5. 8531 5. 3* 3 8 0.11 108.156 108.255 -0.09

36 16 290.000 5.8*22 5.8352 0.12 11*. 673 11*. 99* -0. 11 3817 300.000 5. 8312 5.32 58 C13 121.53* 121. B73 -0. 11 3701 192.000 6.9818 3.9278 0.77 *6.8*5 *6.900 -3. 12

37 02 19^.0 00 6.9765 3 . 9* 5* U.*5 50.b61 50.71* -0. 10 3703 200.000 6.9712 3.9532 0.26 5*.*06 5*. *5C -0.08

37 0* 20*. 000 6.9659 6.9571 0.13 58.110 58.137 -3.05

37 05 208.000 6.9607 3.9577 0.0* Dl.77* 61.786 -U.C2

37 06 212.000 6.9555 3.9571 -0.02 65.*10 65. *03 3. CI

37 07 216.000 6.9502 3.9539 -0.05 69. 013 68.995 3.03

37 08 223.000 6.9*50 3.9*98 -0.07 72.591 72.563 3. 0* 3709 225.000 6.938* 6.9* 58 -0.08 77.032 76.996 3.05

3710 230.000 6.9317 6.33o7 -0.07 81.*37 31.*01 0.0*

3711 2*0.000 o. 918b 3.9212 -0.0* 93.158 90. 13* 3. C3 3712 250.000 6.9053 3.93 55 -U.02 98.789 98.77e 3. 01 3713 2o0.000 6.8920 5.3919 0.02 10 7.322 107.336 -3.0 1 371'* 270.000 6.6766 3.3758 0.03 115.791 115.817 -0.02

37 15 280. 300 6.8653 3.3o22 0.0* 12*. 17* 12*. 222 -0.0*

3716 290.303 6.6521 3.3-32 0. 06 132. *89 132.556 -3.05

3717 300.000 6.8369 3.33*6 0.0b 1*0.737 1*0.620 -0.06

36 01 192.000 7.97 8 9 7.3*50 1.68 *7.528 *7.590 -0. 13 3602 196.000 7.9726 7.9151 0.72 52. Oil 52.075 -0.12

3603 230.300 7.966* 7.9312 .** 56.*lt 56.*79 -0.11

36 0* 20*. 000 7.9601 7. 933* 0.27 60 .7 Hi. 60.83* -0. 09

36 05 208.300 7.9539 7.9*26 0.1* 65. 120 65. 156 -0-C5

36 06 212.000 7.9*76 7.9*58 0.02 69.**2 o9.**9 -3. 01

36 07 21o.0Q0 7.9*13 ?.9*38 -0.03 73.730 73.719 0. 02 3oC8 223.300 7.9350 7.9*9 2 -0.07 7 7.995 7 7.9oe 3.0*

36 09 225.000 7.9271 7.9335 -0.08 83.292 83.252 3.05

3ol0 230.000 7.9192 7.9239 -0.13 88.565 8 8.510 3. 06 3oll 2*0.000 7.903* 7.9131 -0.08 99.012 96.953 0.06

3612 250.000 7.8676 7 .8928 -0.07 109. 3c0 109.30* 0.C5

3613 260.000 7.8718 7.8735 -0.05 119.61* 119.567 0.0*

70
METHANE EQUATION OF STATE

ID T,K MOL/L CALCD O.PCT P,BAR CALCD P,PCT

3614 270.000 7.8561 7.8532 -0.03 129.779 129.748 0.02

3615 280. 000 7.8405 7.8*12 -0.01 139.858 139.846 0.01

3616 290.000 7.8251 7.82-t5 0.01 149.653 149.864 -0.01

3617 300.000 7.8100 7.8033 0.02 159.769 159.803 -0.02

3501 192.000 9.0890 9.0165 0.80 47.891 47.906 -0. 03

33 02 196.000 9.0817 9.0434 0.45 53.082 53.118 -0.07

35 03 200. 000 9.0743 9.04o6 0.31 58.237 58.281 -0.07

3504 204.000 9.06o9 9.0**5 0.25 63.3b4 63.416 -0.08

3505 208.000 9.0595 9.0514 0.10 66.502 68.530 -0.04

35 06 212.000 9.0520 4.0491 0.03 73.615 73.626 -0.02

35 07 216.000 9. 0445 9.3->54 -0.01 78.711 78.707 0.01

3508 220.000 9.0369 9.0420 -0.06 83.600 83.773 0.03

35 09 225. 000 9.0275 9.0343 -0.06 90.129 90.085 0.05

3510 230.000 9.0160 9.0 265 -0.09 96.439 96.376 0. 06 3511 240.000 8.9990 9.0072 -0.09 106.970 108.894 0.07

3512 250.000 8.9801 6.9855 -0.07 121.398 121.325 0.06

3513 26U. 000 6.9614 8.9656 -0.05 133.727 133.670 0.04

35 14 270.000 8.9429 3.9456 -0.03 145.970 145.927 0.03

3515 260.000 8.9249 3.9258 -0.01 158. 114 158.098 0. 01 3516 290.000 8.9072 6.9067 0.01 170. 170 170. 18C -0. 01 3517 300.000 8.8900 8.8338 0.01 182.149 182.174 -0.01

3401 192.000 10.2380 10.0595 1.74 48. 104 48.141 -0.08

3*02 196.000 10.2296 10.1056 1.21 54. 020 54.133 -0.21

34C3 200.000 10.2210 10.1274 0.92 59.983 60. 141 -0. 26 3404 204.000 10.2123 1J.1412 0.70 65.977 66. 155 -0.27

34 05 208. 000 10.2035 13.1497 0.53 71.990 72. 170 -0.25

34 06 212.000 10.1947 10.1539 0.40 78.012 78.183 -0.22

34 07 216.000 10.1658 U .1547 0.31 84.035 84.193 -0.19

34 8 220.000 10.1769 10.1539 0.23 90.060 9C. 196 -0.15

3409 225.000 10.1657 10.1*33 0.17 97.568 97.690 -0. 12 3*10 230. 000 10.1545 10.1*17 0.13 105.066 105.170 -0.10

3411 240.000 10.1320 13.1230 0.09 119.985 120. 079 -0. 08 3412 250.000 10. 1100 13.1016 0.06 134.809 134.913 -0.08

3413 260. 000 10. 0882 10.0805 0.08 149.544 149. 66C -0.08

3414 270.000 10.0671 10.0583 0.09 16*. 165 164.317 -0.09

34 15 280.000 10.0466 13.0374 0.09 176.700 178.881 -J. 10 3416 290.000 10.0270 13.0170 0.10 193.133 193.354 -0.11

3417 300.000 10.0061 3.9976 0.11 207.474 207.729 -0.12

3301 192.000 11.1113 11.07*9 0.33 48.322 48.331 -0. 02 3302 196.000 11.1019 10.98 7 8 1.03 54.855 54.97C -0.21

3303 200.000 11.0923 10.9993 0.84 61.513 61.686 -0.26

33 04 204. 000 11. 0825 11.0134 0.62 63.249 68.439 -0.28

3305 208.000 11.0725 11.0189 0.48 75.017 75.214 -0.26

3306 212.000 11.0625 11.0130 0.45 81.773 82.002 -0.28

3307 216.000 11.0523 11.0139 0.30 88.609 88.795 -0.21

33 08 220.000 11.0422 11.0153 0.24 95.415 95.591 -0.18

3309 225.000 11.0294 11.0076 0.20 103.913 104. 082 -0.16

5310 230.000 11. 0167 13.9935 0.17 112.402 112.566 -0.16

3311 240.000 10.9914 10.9732 0.12 129.341 129.493 -0.12

3312 250.000 10.9667 10.95 39 0.12 146. 170 146.349 -0. 12 3313 260.000 10.9428 10.9299 0.12 162.909 163.122 -0.13

3314 270.000 10.9198 10.9054 0.12 179.5*8 179.804 -0. 14 3315 28J. 000 10.8978 10.8830 0.14 196.070 196.388 -0.16

71
METHANE EQUATION OF STATE

ID T,K MOL/L CALCD D,PCT P.BAR CALCD P.PCT

331b 290.000 10.8769 10.8612 0.14 212.497 212.875 -0.18

3317 330.000 10.8570 10.8438 0.15 228.828 229.259 -0. 19 3201 192. 000 12.0697 12.1348 -0.54 48.685 48.652 0.07

32 02 196.0 00 12.0591 12.0128 0.38 56.033 56.098 -0.12

3203 200.000 12.0481 12.3017 0.39 63.57* 63. 685 -0.17

320* 20*. 000 12.0370 11.9994 0.31 71.216 71. 344 -0. 18

32 05 208.000 12.0256 11 .9954 0.25 78.913 79.047 -0.17

32 06 212.000 12. 0142 11.9914 0.19 86.654 86.779 -0.14

32 07 216.000 12.002b 11.9873 0.13 9*.*28 9*. 529 -0.11

32 08 220.000 11.9912 11.9797 0.10 102.201 102.289 -0.09

3209 225.000 11.9767 11.9678 0.07 111.912 111.993 -0. 07 3210 230.000 11.9624 11.95*9 0.06 121.617 121.69fc -0. 06 3211 240.000 11.93*2 11.9277 0.06 140.985 1*1. 072 -0.06

3212 250.000 11.9068 11.8990 0.07 160.255 160.381 -0.08

3213 26U.000 11. Od08 11.8710 0.08 179.425 179.606 -3.10

32 1* 270.000 11. 8562 11 .8**4 0.10 198.490 198.744 -3.13

3215 280 .000 11.8330 11.8192 0.12 217. *-,2 217.777 -3. 15 3216 290.300 11.8112 11.7956 0.13 236.293 236.710 -3.18

3217 300.000 11.7906 11.7739 0.14 255.031 255.528 -0.20

3101 192.000 12.9815 13.0233 -0.37 49.455 49. 395 0.12

3102 19o.000 12.9695 12.9752 -0.04 57.790 57.776 3. C2 3103 200.000 12.9570 12.9575 -0.03 66. 328 66. iZt 0.00

3104 204. 000 12.94*2 12.9*90 -0.04 7*. 993 74.971 . C 3 3105 208.000 12. ^313 12.9399 -0.07 83.726 83.o75 0.0c

310b 212. QUO 12. 9184 12.92 96 -0.09 92.499 92.419 0.09

3107 216.000 12.9053 12.9193 -0.11 101.304 101.167 0. 12 3108 220.000 12.8923 12.9375 -0.12 110. 116 109.971 0. 13 3109 225.000 12.8761 12.3932 -0.11 121. 115 120.959 0.13

3110 23J.000 12.8600 12.8733 -0.10 132.115 131.947 0.13

3111 2*0. 000 12. 8266 12.9389 -0.08 154.057 153.895 0.11

3112 250.000 12.79H6 12.8053 -0.05 175.900 175.779 0.07

3113 260.000 12.7708 12.7736 -0.02 197.638 197. 577 3-03

3114 270.000 12.7448 12.74*1 0.01 219.261 219.280 -0.01

3115 280.000 12.7205 12.7152 0.03 2<.0.753 2*0. 67t -3. 05 3116 290.000 12.b980 12.6906 0.06 2c2.130 262.358 -0.09

3117 300.000 12.6767 12.6670 0. 08 283.387 283.7lt. -3.12

3001 192.000 1*.2336 1*.2136 0.14 52.052 52.119 -0.13

3002 196.0 00 14.2188 1*.23*4 -0.11 62.209 62. 133 0.12

30 3 20J.OOO 14.2038 1*.2278 -0.17 72.451 72.296 0.21

30 04 20*. 000 14. 1866 1*.2175 -0.20 82.785 82.559 0.27

30 05 208.000 14.1733 14.2053 -0.23 93.177 92.880 J. 32

30 06 212.000 14. 1580 1+.1923 -C.24 103.608 103. 24G 0.36

30 07 216. 0U0 14. 1427 1*.1769 -0.24 11*. 0*0 113.623 0.37

3008 220. 000 14. 1275 U.1612 -0.2* 124.478 124.019 0.37

3009 225.000 14. 1U88 14.1439 -0.23 137.516 137. 022 0.36

30 10 233.000 14. 0906 1*.12 J5 -0.21 150.534 150. 02C 0.34

3011 240.000 14. 0557 14.0811 -0. 18 175.506 175.976 0. 30 3012 250.000 14.0233 1*.0436 -0.14 202.352 201.861 0. 24 3013 2o0.000 13.9939 14.0036 -0.10 228.062 227.655 0. 18

30 14 273.303 13.96e9 13.97 64 -0.C7 253.635 253.338 0.12

30 15 280.000 13.9421 13.9469 -0.03 279.069 278.901 3. 06 3016 290.303 13.9190 13.91 91 -0.00 30*. 333 304.328 3.00

3017 300.000 13.8972 13.89*5 0.02 329.483 329.597 -0.03

72
METHANE EQUATION OF STATE

10 T,K MOL/L CALOD D.PCT P,,BAR CALCO P,PCT

2901 190.000 15.3796 15.3591 0.13 51,,866 51.991 -0.24

2902 194.000 15.3621 15.3622 -0.00 63,,787 63.786 0.00

2903 198.000 15.3444 15.3597 -0.10 75,,861 75.711 0. 20 2904 202.000 15.32b7 15.3521 -0.17 88,,012 37.719 0.33

2905 206.000 15.3088 15.3438 -0.21 100,,201 99.775 J. 42

29 06 210.000 15.2911 15.3255 -0.23 112,,378 111. 862 0.46

2907 215.000 15.2692 15.3 47 -0.23 127.,596 126.989 0.48

29 08 220.000 15.2478 15.2828 -0.23 142,.792 142.120 0.47

2909 230.000 15.2071 15.2431 -0.22 173,,125 172.356 0.44

2910 240.000 15.1701 15.1931 -0.18 203,,2 87 202.521 0.36

2911 250-000 15.1369 15.1597 -0.15 233,,313 232.595 0.31

2912 260.000 15.1069 15.12*5 -u.12 2o3,,178 262.553 0.24

2913 270.000 15.C797 15.0920 -0.08 2 92,,861 292.376 0.16

2914 280.000 15.0546 15.0b27 -0.05 322, 396 322. 046 0.11

2915 290.000 15. 0313 15.0342 -0.02 351,.677 351.539 0.04

28 01 186.000 16.2733 16.2612 0.07 45,,617 45.715 -d.22

2802 190.000 16.2543 16.2533 0.01 59,,078 59.089 -0.C2

2803 19*. 000 16.2348 16.2*29 -u. 05 72,,660 72.579 0. 14

28 04 198.000 16.2151 15.2305 -0.09 86,,363 86.1*40 0.26

2805 202.000 16.1953 15.21+0 -0.12 100,,048 99.739 0.31

2806 206.000 16.1755 15.1970 -0.13 113,,751 113.354 0.36

2807 210.000 16. 1562 16.17 96 -0.14 127.,454 126.977 0.37

28 08 215.000 16. 1328 15.1515 -0.11 144,,4C4 144. 003 0.28

28 09 220.000 16. 1098 16.13+0 -0.15 161,,607 161.002 0. 37 2810 230.000 16.0677 15.0936 -0.14 195,,626 194.946 0.3 5 2811 240.000 16. 0302 16.0493 -0.12 229,.438 228.78? 0.26

2812 250.000 15.9971 15.0128 -0.10 263,,114 262.507 0.23

2813 2o0.000 15.9676 15.9731 -0.07 296,,5 39 296.090 0,15

281*. 270.000 15. 9*08 15.9*52 -0.03 329,,757 329.503 0. 08

27 01 182.000 17.2858 17.2732 0.04 41,,322 41.416 -0.23

2702 186.000 17.2636 17.2635 0.00 56 , ,948 56.949 -0. CO 2703 190.000 17.2416 17.2489 -0.04 72,,675 72.549 0.17

27 04 194.0 00 17.2194 17.2232 -0.05 86,,3*6 38. 173 0. 20

27 05 198.000 17.1973 17.2100 -0.07 10*.,080 103. 801 0.27

2706 202.000 17.1754 17.1953 -0.09 119,,774 119.412 0.30

2707 206.000 17.1539 17.1713 -0.10 135,.462 135.001 3.3*

2708 210.000 17. 1331 17.1511 -0.10 151,.080 150.569 0. 34

27 09 215.000 17. 1084 17.1279 -0.11 170,,602 169.994 0.3b

2710 220.000 17.08*8 17.1044 -0.11 190,, 33 189.371 0.35

2711 230.000 17.0424 1 7 . o 3 4 -0.11 226.,723 228. 023 0.31

2712 240.000 17. 0056 17.0237 -0.09 2b7,,186 2o6.524 0.25

2713 250.000 16.9731 lj.9833 -0.07 305,,4*2 304. 85C 0. 19

27 14 260.000 16.9441 15.9513 -0.04 343,,357 342.973 0.11

26 01 176- QUO 18.3840 18.3815 0.01 32., 172 32. 217 -0.14

26 02 180.000 18.3570 13.3553 0.00 50,,437 50.*53 -0. 3 2603 184.000 18.3320 18.3311 0.00 68 , ,691 68.711 -0. 03

26 04 188.000 18.3070 13.3061 0.00 86,,906 86.929 -0.03

2605 192.0 00 18.2810 13.2821 -0.01 105,,089 105.057 0.C3

26 06 19b. 000 18.2560 13.2589 -0.02 123,,2 27 123. 136 U. 07 2607 200.000 18.2320 13.2354 -0.02 141,,311 141. 163 0.11

26 08 205.000 18.2030 13.2099 -0. 04 163., 860 163.604 0. 16

26 09 210.000 18.1750 13.1844 -0.05 186,,312 185.937 0.20

2610 215.000 18.1500 13.1633 -0.06 208,,6 87 208.243 0.21

73
METHANE EQUATION OF STATI

10 T,K MOL/L CALCD O.PCT P.QAR CALCO P.PCT

2611 220. 000 18.1270 18.1330 -0.06 2J1.002 230.496 0.22

2612 225..000 18.1060 Id. 1159 -0.06 253.237 252.704 0.21

2613 230,.000 18.08o0 18.0970 -0-06 275.393 274.828 0.21

2614 235.,000 18.0680 18.0732 -0.06 297.479 296.925 0.19

2615 240. 000 18.U520 I3.0o04 -0.05 319.488 319.006 a. 15 2ol6 245.,000 18. 0360 13.0413 -0.04 341.402 340.966 0.13

2501 170. 000 19.5060 19.*d78 0.09 26.367 26.867 -1.90

2502 174.,000 19.4750 19.4553 0.10 47.743 48. 346 -1.27

2503 178,,000 19.*460 1 J. 42 + 0.11 69.007 69.746 -1.C7

2504 182.,000 19.4170 19.3929 0.12 90.117 90.999 -0.98

2505 186. 000 19. 388G 19.3o35 0.13 111.128 112.093 -0.87

25 06 190, 000 19.3590 13.3362 0.12 132.061 133.021 -0.73

2507 19*,,000 19.3320 19.3137 0.11 152.913 153.871 -0.63

2508 198.,000 19.3070 19.2863 0.11 173.668 17*. 653 -0.57

25 09 202,,000 19.2830 19.2655 0.10 194.349 195.331 -0.51

2510 205,,000 19.2660 19.2*77 0.09 209.838 210.792 -0.45

2511 210,,000 19.2400 19.22 J2 0.U9 235.576 236.507 -3.4C

2512 215,,000 19.21O0 1 9 . 2 J J 4 0.08 261.206 262.122 -0.35

2513 220,,000 19.1950 19.1796 0.03 286.762 287.716 -0.33

2514 225.,000 19.1750 19.1631 0.08 312.214 313.185 -0.31

2515 23J,,000 19.1570 19.1*14 0.08 337.542 338.603 -0.31

2401 16*.,000 20.*25G 20.*?>9 0.01 20.288 20. 365 -3. 33 2402 168,,000 2 0.3890 20.3859 0.01 44.689 44.775 -0.19

24 3 172,,000 20.3570 20.3511 0.03 63.823 o9. 083 -0.38

2*04 176,,000 20.3240 29.3157 0.04 92.700 93.091 -0.42

2i*05 180, 000 20.2920 2J.2820 0.05 116.390 116.890 -0.43

2406 184,,000 20.2600 20.2511 J.0* 139.966 1*0. 436 -0.34

2407 188,,000 20.2310 2J.2224 0.04 163.416 163. 896 -0.29

2408 192,,000 20.2060 29.1950 0.05 186. 77o 187.362 -0.31

2409 196., 000 20.1780 2J.1723 0.03 210.084 210.432 -0.17

2*10 200,,000 20.1550 20.1537 u.02 233.321 233. oOO -0.12

2411 204,,000 20. 1340 20.1338 G.02 25b. 494 256.708 -0.08

2*12 208,,000 20.1150 2J.1125 a. 01 279.599 279.772 - . b 2413 212,.000 20.0970 20.0955 0.01 302. o29 302.739 -3. 04

24 14 21o,,000 20.0800 20.0794 0.00 325.569 325.617 -0.C1

24 15 220,,000 20.0650 23.3o*3 0.00 348. *34 3*8. *92 -0.02

2301 158,,000 21.3710 21. 3700 0.00 19.836 19.88t -0.25

2302 lo2,, 000 21.3320 21.3297 0.01 47.5 37 47.661 -0.26

2303 166,.000 21.29*0 21.2332 0.03 74.747 75. 077 -0.4*

2304 170,,000 21.2580 21.2*78 0.05 101.595 102.215 -0.61

23 05 17*., 000 21.2230 21.2111 0.06 128.287 129. 041 -0.59

23 06 178,,QU0 21.1890 21.1/75 0.05 154.807 155.574 -0.50

2307 182 .000 21.1580 21.1*72 .05 181.216 181. 971 -0.42

2308 186., 000 21.1290 21.1233 0.04 207.556 208. 194 -0.31

2309 190,,000 21.1030 21.0961 0.03 233.818 234.344 -0.23

2310 19*.,000 21.0800 21.07+6 0.03 260.026 260. *65 -J. 17 2311 198,.000 21.0590 21.05*6 0.C2 286.118 286.478 -0. 13 2312 202,.000 21.0400 21.0365 0.02 312.140 312.433 -0.09

2313 20o.,000 21. 0220 21.0196 0.01 338.043 338.256 -0. C6

22 01 152,,000 22.1250 22.1227 0.01 1*.593 14.736 -0.98

2202 lso ,000 22. 0800 52.0775 0.01 45. 88 *5.250 -0.3b

2203 160,.000 22.0400 22.0311 0.04 74.923 75.642 -0.83

2204 1 o4

,

.000 22.0010 21.9873 0.06 10*. 403 105.392 -0.95

74
METHANE EQUATION OF STATE

ID T,K HOL/L CALCD O.PCT Pi,BAR CALCD P.PCT

22 05 I08.OOO 21.9620 21.9479 0.06 133,,692 134.753 -0.79

22 06 172.000 21.9290 21.9119 0.08 162,,772 16*. 117 -0.83

2207 176.000 21. 6920 21.6800 0.05 191,,756 192.73fc -0.51

2208 180. 000 21.8620 21.8517 0.05 220.. 648 221.523 -0.40

2209 184.000 21.8360 21.3273 0.0* 249,,520 250.292 -0. 31 2210 188.000 21.8120 21.8055 0.03 278,,308 278.907 -0.22

2211 192.000 21.7910 21.7850 0.02 307,,015 307.491 -0.1 6 2212 196.000 21.7720 21.7678 0.02 335,,575 335.984 -0.12

2101 lf»6.0 00 22.6730 22.3726 0.00 13,,127 13.157 -0.23

2001 ltd. JO 23.5700 23.5719 -0.01 12,,2 62 12.091 1.39

2102 150.000 22.62*0 22.82*7 -0.00 40 , ,703 *6. 6*4 0. 13 2103 154. 000 22.7820 22.7757 0.03 79,,462 79.988 -0.66

2104 156.000 22.7390 22.7290 0.0* 111,,7 36 112.601 -0.77

2105 162.000 22.0980 22.6873 0.05 143,, 810 144.773 - . b 7 2106 loo. 000 22.6600 22.650 0.04 175,,712 176.6*2 -0.53

2107 170. 000 22.0260 22.6176 0.04 207,,555 208.368 -0.39

2108 17f*. 000 22.5960 22.5895 0.03 239,,330 239. 98t -0. 27 2109 176. 000 22.5700 22.5656 0.02 271. 112 271.565 -0.17

2110 182.000 22.5*60 22.5**2 0.01 302,,767 302.958 -0. 06 2111 186.000 22.5250 22.52*8 0.00 334,,2 82 334. 3CC -0.01

2002 1**. 000 23.5180 23.521* -0.01 48,,910 48.565 0.66

20 03 1*8.000 23.*720 23.4o91 0.01 84. 500 84.782 -0.33

20 0<» 152.000 23.*260 23.4195 0.03 119,,526 120. 162 -0.55

2005 156.000 23.3830 2i.3754 0.03 15*,,350 155.139 -0.51

20 06 160. 000 23.31*30 23.3369 0.03 189,,067 189.720 -0.35

2007 lot. dOO 23.3080 23.30*0 0.02 223,,762 224.208 -0.20

2008 166.000 23.2780 23.2759 0.01 258,i*40 258.680 -3. 09 2009 172.000 23.2520 23.2515 0.00 293,, 040 293. 094 -0.02

2010 176.000 23.2280 23.2335 -0.01 327.,578 327.271 0. 09 1901 13f».0U0 2i*. 1630 2*. 1826 0.00 6,,861 6.906 -0.69

19 02 138.000 2*. 1250 2*. 1291 -0.02 46,,383 *5.935 0.9b

1903 142.300 2*. 0760 2*. 0736 0.01 64,,630 84.901 -0.32

19 0<* lto. 000 2*. 0270 2*. 0211 0.02 122. 240 122.915 -0.55

1905 150.000 23.9810 23.97*8 0.03 159,,6 56 160.366 -0.46

1906 154.000 2 3.91*0 23.9351 0.02 197,, 040 197.038 -0.30

1801 13-+. 000 2*. 17*0 2*. 1729 0.00 5,,8*1 5.957 -1.99

1802 136.000 2*. 1*10 2*.l*o6 -0.02 25.,770 25.168 2.34

18 03 138.000 2<*. 1150 2*. 1138 -0.02 45.,258 44.650 0.90

18 Of* 1*0.000 2*. 0900 2*. 0912 -0.00 64,,512 64.384 0.20

1805 142.0 00 2*. 0660 2*. 0621 0.02 83,,3*8 3 3.7 84 -0.52

18 06 1*1*. 000 2*. 01*20 24.03*8 0.03 102,,134 102.947 -0.80

18 7 11*6.000 2i*. 0170 2*. 0098 0.03 120,,944 121.767 -0.68

1806 1*6.000 23.99*0 23.9863 0.03 139,,702 140.595 -0.64

1809 150.000 2 3.9710 23.9639 0.03 158,,374 159.209 -0.53

1810 152.000 23.9500 23.9*33 0.03 177,,053 177.856 -0.45

1811 15*. 000 23.9310 23.92** 0.03 195,,747 196.549 -0.41

1812 156.000 23.9120 23.9068 0.02 214,,417 215.059 -0.30

1813 158.000 23.8930 23.8890 0.02 232,,888 233.390 -0.22

18 If* 160.000 23.8770 23.87*7 0.01 251,,6 36 251.926 -0.11

1815 162.000 23.8620 23.8611 0.00 270,,317 270.426 -0. c* 1816 16*. 000 23.6*90 23.3*3* 0.00 268,,962 289.034 -0.02

1817 166. 00 23.8360 23.3375 -0.01 307.,b9* 307.499 0.0b

1818 168.000 23.82*0 23.8273 -0.01 326.,391 325.958 0.13

75
METHftNE EQUATION OF STAT£

10 T,K MOL/L calco O.PCT P,8AR CALCD P.PCT

1819 170-000 23.8120 23.8172 -0.02 3**. 966 3**. 286 0.20

1701 130.000 2*.b050 2*. 6098 -0.02 7.2 86 6.72* 7.71

17 02 132.000 2*. 5720 2*. 5822 -0.0* 28.230 27.02* *.27

17 03 13*. 000 2*. 5*60 2*. 5s 38 -0.03 *8.781 +7.8*7 1.92

17 0* 136- 000 2*. 5190 2*. 52*2 -0.02 68. 89* 68.262 0.92

1705 138.000 2*.*9*0 2+.+9+0 0.00 88.639 88.6** -0. 01 1706 1*0.000 2*.*690 2+ .+o53 0.01 108.*25 108. 761 -0.31

1707 1*2.000 2*.**30 2+.*+35 0.01 128.176 128. +9£ -0. 25 1708 1**.000 2*.*190 2+.*160 0.01 1*7.856 1*8.236 -0.26

1709 1*6.000 2*. 3960 2*. 3933 0.01 167 .516 167.866 -0.21

1710 1*6.000 2*. 37*0 2*. 3726 G.01 187.222 187.399 -0.09

1711 150.000 2*. 35*0 2-.. 3536 0.00 20b. 921 206. 976 -0. 03 1712 152.000 2*. 3350 2*. 3362 -0.00 22o.6** 226. *8* 0.07

1713 15*. 000 2*. 3170 2*. 31 3* -0.01 2*6.119 2*5.929 o.oa

171* 15o.OOO 2*. 3010 2*. 30+3 -0.01 265.906 265. *59 0.17

1715 158.000 2*.2bo0 2*. 2912 -0.C2 285.671 28*. 951 0.25

1716 160.000 2*. 2730 2*. 27 3* -0.03 305. *59 30*. 655 0. 3u 1717 162.000 2*. 2600 2*. 2631 -0.03 325. 155 32*. 002 0. 35 1718 16*. 000 2*. 2*80 2*. 2533 -0.0* 3**. 921 3*3. *38 0.*3

1601 126.000 2*.99b0 2*. 9930 -0.01 + .7 95 + .537 5.38

16 02 126.000 2*.96G0 2*. 9b 3* -0.0* 26.7+C 25.527 *. 5*

lo03 130.000 2*. 9330 2*. 3+ J 2 -b. 03 *8.275 *7.339 1.9*

lbO* 132.000 2*. 9050 2*. 91 36 -J. 02 69.**2 68.70C 1. 07 1605 13*. 000 2*. 8790 2*. 383* -0.01 90.206 90.016 0.21

1606 13o.000 2*. 8520 2*. 352 0.00 110.901 110.907 -0.01

lo07 138.000 2*. 8260 2*. 62+8 0.00 131. *37 131.6*5 -0.12

1608 1*0.000 2*. 6010 2+.7;i35 0.01 152. 0+6 152.2*7 -0. 13

16 09 1*2.000 2*. 7770 2+. 7762 0.00 172. bl9 172.72* -J. 06 1610 1**.000 2*. 75*0 2+.75+9 -0.00 193. 223 193. 09C 0. 07 1611 l*b.000 2*. 73*0 2*. 735 5 -0.01 213.859 213.0*1 0.10

1612 1*3. 000 2*.715u 2+.713* -0.01 23*. 593 2 3 * . 1 1 G 0.21

1613 1*8.000 2*. 71*0 2+.7132 -0.02 2 3 . . 5 6* 233.966 0.25

161i» 150.000 2*. 6970 2+.7 2* -0.0? 255.29* 25*. 508 0.31

1615 152.000 2*. 6610 2+.6 130 - . i 276.02* 27*. 99* 0.37

1616 15*. 000 2*. 6660 2+.67+* -0.03 296.66* 295. *36 0.*2

1617 156. 000 2*. 6520 2+.6b20 -0.0* 317.3*6 315.8*2 0.*7

1618 158. 000 2*. 6390 2+.6509 -0. 05 338. 030 336.22* 0.5 3 1501 122.000 25. 3860 25.33*2 0.01 3.*82 3.731 -7. 1 + 1502 12*. 000 25.3*80 25.3526 -0.02 2o.lfc8 25.^22 2.*7

1503 126.000 25.3200 25.3233 -0.01 +8.81* +8.3*H 0. 9b

150i» 128. 000 25.2930 25.2638 0.02 70. 3b3 70.960 -0.85

15 05 130.000 25.2660 25.2590 0.03 92.218 93.236 -1.10

15 0b 132.000 25.2390 25.2312 0.03 11*. 039 115. 166 -1.0 1 1507 13*. 00 25.2120 25.2050 0.03 135.786 136. 623 -0. 7o 1508 13*. 00 25.2110 25.2052 0.02 135.81* 136.675 -0.63

15U9 136.000 25. 18*0 25.173* 0.02 157.173 158. 007 -0.53

1510 138. 000 25.1600 25.135* 0.02 173.801 179. +97 -0.39

1511 1*0. 000 25. 1370 25.13*2 0.01 200. *30 200.862 -0.22

1512 1*2.000 25.1160 23. 1152 0.G0 222.1** 222.271 -0. 06 1513 1**.000 25.0970 25.0978 -0.00 2*3.665 2*3.739 0.05

151i» 1*6.000 25.0800 25.0823 -0.01 265.6*3 265.283 0.1*

1515 1*8. 000 25.06*0 25.063* -0.02 287. *62 286. 76* 0.2*

1516 150.000 25.0*90 25.0558 -0.03 309.282 308. 192 0. 35

76
METHANE EQUATION OF STATE

10 T,K MOL/L :alcd D.PCT P BAR CALCD P,PCT

1517 152.000 25. 0350 25 + 37 -0.03 330 937 329. 578 0. 43

1518 154.000 25.0220 25 .0510 -0.04 352 7 26 350 934 51

14 01 118.000 25.7770 25 .7765 0.00 4 740 + 315 -1. 56

1402 120.000 25.7390 25 .7**1 -0.02 28 *87 27 70F 2. 75

1403 122. 000 25. 7100 23 .7116 -0.01 51 814 51 664 48 1404 124.000 25.6820 25 .6763 0.02 74 303 75 169 -1 19 1405 126.000 25. 6540 25 .o+ 51 0.03 97 196 98 + 4C -1 26 1406 128.000 25.0250 25 .6177 0.03 120 010 121 173 -0. 97 1407 130. 000 25.5980 25 .5916 0.03 142 8 46 143 87P -0 7Z 1408 132. 000 25.57*0 25 . 5o67 0.03 165 554 lbo 735 -0 7 1 1*09 13*. 000 25.5500 25 5**1 0.02 188 320 139 260 -0 51

It 10 136.0 00 25.5240 25 .32 32 0.00 211 062 211 196 -0 06 ltll 138.000 25.5030 25 .50 + 3 -0.01 2 33 855 233 o43 09 1+12 138.000 25.5030 25 .5018 0.00 233 445 23 3 643 -0 ca 1*13 1*0.000 25.*8*0 25 *851 -0.00 25o 331 256 151 7 WW 142.000 25.46=0 2^ .47 05 -0.02 279 330 278 569 2 7 1415 1++.000 25.4500 25 . *5 56 -C.03 302 209 301 081 37 Wlfa 1*6.000 25.4350 25 ,4**9 -0.0 + 325 227 323 532 52

It 17 148. 000 25. 4220 25 + 338 -0.05 348 1*8 3+6 107 59

1301 114.000 26. 1420 2o 1*52 -0.01 * 106 3 581 12 73

1302 116. 000 2o. 1030 2o 1118 -0.03 28 896 27 421 5 10 1303 118.000 26.0720 2o , J 7 7 -0.02 52 9l8 52 137 1 57

13 04 120. 000 26. 04*0 26 0*J6 0.01 7o 358 76 926 -u 74 1305 122.000 26. 0140 2d . JU 93 0.02 100 162 100 965 -0 80 1306 12*. 000 25.9850 25 .3300 u.02 123 929 124 77t -0 63

13 07 126.000 25.9560 25 .9328 0.01 147 o55 148 211 -0 36 1308 128.000 25.*290 25 .9273 0.01 171 3 38 171 bZl -0 1 7 13 09 130.000 25.90*0 25 .9U*5 -0.00 195 123 195 039 04 1310 132.000 25.8810 Zz> .8837 -0.01 218 955 218 474 22 1311 132.000 25. 8800 23 8813 -C.01 218 534 218 296 11 1312 134.000 25.8590 Z'} ,8638 -0.01 242 441 2+1 772 28 1313 136.000 25. 8400 2 5 8*54 -0.02 2o6 4 + 26 5 306 43 13W 138.000 25.O220 25 .3316 -0.0* 290 *74 238 737 60 1315 1*0. 000 25. 8070 25 .8137 -0.05 314 577 312 445 68

1316 1*2.000 25. 792C 25 3056 -O.Oo 338 290 335 902 79

1201 110.000 26.5190 2d 5135 0.00 5 935 6 027 -1 56 1202 112.000 26.*800 26 *8*5 -0. 02 31 8 39 31 022 2 57

1203 114.000 26.4490 2j .4451 0.01 56 444 56 963 -0 92

12 04 116.000 26.*190 2o ,+105 G.03 81 G54 82 612 -1 92

12 05 118.000 26.3880 23 .3734 0.04 105. 870 107 625 -1 66

12 06 120.000 26.3570 26 3*36 0.03 130 o59 132 203 -1 18

1207 122.000 26.3270 2d 3208 0.02 155. + 0G 156 5*P -0 7 + 1208 12*. 000 26.2990 2d 2952 0.01 180 154 130 866 -0 + 1209 126.000 2o.27*0 26 2719 0.01 204 975 205 3o6 -0 19 1210 128.000 26.2510 26 ,2511 -0.00 229. 892 229. 883 o. 00 1211 130.000 26.2300 2d .2325 -0.01 254. 906 254. 438 0. 18

12 12 132.000 26.2110 2o 2151 -0.02 280 025 2 79. 062 0. 35 1213 13*. 000 26.1930 26 2016 -0.03 305. 214 303 551 J. 54

12 W 13*. 000 26.1920 25 2033 -0.03 30*. 967 303. 358 0. 53

1215 136.000 26.1760 26 .1875 -0.04 330 185 327. 952 0. 66

1101 106.000 26.9010 2d 9036 -0.01 12, 022 11. 503 4. 32 1102 108.000 26.8640 26 8636 -0.02 33 986 38 088 2, 30 1103 110.000 26.8330 26 8294 0.01 64. 5 91 o5. 306 -1. 10

77
ID T,K MOL/L C + L ;o O.PCT P,BAR CALCf P.PCT

11 0% 112.000 26.B01G 23.7934 0.03 90. 3 C C 91.804 -1.67

1105 114. 00Q 26.7o8C 2o.7615 b.03 116.122 117. cb6 -1.28

1106 116.000 26. 7360 23.7237 0.02 141.871 143. 133 -0.89

1107 119.000 26.70cU 25.7013 0.02 167. o53 lo8. oO? -J. 57 HOB 120.000 26.6790 25.67 55 G.01 193.539 13+.239 -3.3c

1109 122.000 26. 6530 2o.6524 b. 00 219. 542 219.6fci -0.0b mo 124.000 26.630 3 2j.6325 -0.01 2t5.820 2+5.307 u. 21 nil 124.000 2 6.6310 2j.o316 -0.03 245.

o

7 6 2 + 5. 5U J. G7 1112 126.000 26.0100 2o.61+2 -0.02 272. G-9 271.169 0.32

1113 128. 000 26.5920 2o.5 9 37 -0.03 293.510 297. 133 G.<-. 6 1114 130.000 26. p740 2.>. 5650 -0.04 3 25. 'J 2 322.7+4 0.7 J 1115 132.000 26. 669u 2d. 5722 -0.05 351.423 548 . obi b. 79 1001 102.000 27.232b 27.2 Sit 0.00 8.+7t e . o i c -1.60

1002 104.000 27. 1920 27.1352 -0.01 35.489 35.626 1.62

1003 Ub. 000 27 . 16C0 27.15+6 0.32 b3. 334 54. 119 -1.72

1004 108.000 27. 1270 27. 1170 0.04 33.515 91.633 -2.37

10 05 110.000 27.0930 27.1d?7 0.04 Ho. 218 118. 391 -1. i7

10 06 112.000 27. 0600 27.3510 0.03 142.937 144.8 39 -1.3 i 1007 lit. 000 27. u290 27.0214 0.03 169.612 171.216 -3.93

1008 116.000 27. 0010 23.9950 j.C2 196. 4o0 137.757 -0.65

10G9 116. 000 27. 0010 26.9950 0. 02 196. 471 197. 757 - . o 5 1010 118.000 2o.97b0 23.9717 0.02 223. 5oP 224.+91 -0.4 1 1011 120.000 26.952b 2a. 9513 0.00 250 .862 251. 014 -3.0b

1012 122.000 26.9310 2o.9i 53 -0.01 276.278 277.779 0.16

1013 124. 000 26.9120 26. 3130 -0.02 335.898 304. 59£ 0.43

10 14 126.000 26.8950 2o.90 39 -0 . b3 333.424 331.484 3.56

901 98.000 27. 5860 27.5 3 67 -0.00 12.457 12.201 1.26

902 100.000 27.3480 27 .5a 3 8 -0.01 41. 407 +0. 777 1.52 903 102.000 27.5160 27.5064 j. 03 68.o96 73.41P -2.6 1 9 04 10*. GOO 27.t810 27.+73G 0.04 9o.2?0 98.769 -2.59

905 106.000 27. 4470 27.-3+9 O.Ot 12+. 02 126.731 -2.20

906 108.000 27.4130 27.4025 0. 04 151.756 154. 136 -1.57

907 110.000 27.3820 27.3730 b.03 179. o+9 181. 681 -1. 1 3 908 112.000 27.3530 27.3470 0.02 207.794 209. lo> -O.bb

909 llt.000 27.3280 27. 3239 0. 01 236. 148 237. 07E -0. 39 910 116.000 27.3050 27.3040 0.00 2o4.752 264.979 -0.09

911 116.000 27.3050 27.30+6 .GO 2bt.8 94 264.979 -0.0 3 912 lid. 000 27.2650 27.2o71 -0.C1 293. bl2 293.133 0.16 913 120 .000 27. 2b60 27.2716 -u.02 322.4+6 321. 104 3.42 601 94.000 27.90Gb 27.9017 -0.01 7.513 7. 112 5.3 + 802 96.000 27.3580 27.8o23 -0.02 37.517 36. +83 2.7o

803 98.000 27.6250 27.8176 0.03 65.617 67.284 -2.70

804 100. 000 27. 7890 27. 776b 0.04 94.061 96.685 -2.79

805 102.000 27.75.j0 27.7+16 u. + 122.725 125.437 -2.21

80b 104.000 2 7.7190 2^.7078 U .04 151. 363 154.046 -1,76

807 106.000 27.o8cG 27.6V3 0.03 130.222 182.310 -1.1c

808 108.000 27.6570 27.6512 u.02 209.351 210. 97C -0. 11 809 110.000 27.6300 27.6255 U.Ol 233.728 239.377 -0.35

810 112.000 27.6070 27 .6u50 0.00 268. 394 268.642 -3. 09 811 lit. 000 27.5860 27.53 33 -0.01 298. 261 297. 711 0.18 812 116.000 27.5670 27 .5733 -0.02 326.347 325.813 0.47

601 92.000 28.2090 23.2134 -O.02 -t.123 +2.993 2.56

602 94.000 26.1750 23.1j56 0.03 72.852 7+.997 -2.94

603 96.000 28. 1370 26.125t 0.04 102.5+3 135.238 -2.1 3 604 98. 000 26. 1010 23.06 35 0.0 + 132.363 135. 23T -2.21

605 10 J. 000 28. GocO 2 3.3553 0. bt 162. 180 lo+. 904 -1. bO 606 10 J. 300 28. ObbO 23.3553 3.04 162. 190 164. 9G». -l.o7

607 102.000 28. O3t0 23.02.5 0.C3 192.2-3 19+. o52 -1.25

oue 104.000 28. COtU 27.3+77 b.02 222. ov7 224. 30T -0.72

609 106.000 27.9760 27. 97+7 0.01 263. 551 254. 38fc -J. 33 610 106.000 27.95=0 27.3p+8 0.00 28+. 5+1 284. o95 -3. u2 611 110.000 27.9350 2'. 9330 -0.01 313.018 315.247 . 24 612 112.000 2 7.9160 27.92 3b -0.03 3+7.627 345.56c J . 5c 7C1 94.000 28. 3910 26. 3734 3.04 128. 133 131.226 -2.41

702 9o.000 28.35-0 23. 3+37 j. Ot 15 8.893 13 1 . O+C -1. 75 703 96.000 26.3210 23.3115 0.03 189. 3Hb 192.421 -1.33

704 100. 000 28.2900 23.2635 0.02 221. 3j6 223.0/2 - j . 1 7 05 102.000 26.2640 23.2535 3.02 253.222 254. 422 -3.47

706 lOt.OOO 28. 2400 23.23 30 u.GO 285. ++0 265. 706 -3.C9

707 106.000 28. 2190 23.2221 -0.01 318. 049 317. 229 J. 26

7 08 106. 300 26.2000 23.2058 -0.02 350 .306 348. 75C J. 52 514 3o.5U0 28.552b 23.5338 0.00 22+.93B 225. 2p7 -0. 1 + 515 37.000 26. 5450 21.3++3 u.00 233. 128 233. 30t -o.oa

516 98.000 28.5310 21.5323 -3.00 249.643 249.285 3.14

517 100.000 28.5070 26.51 )6 -0.01 282.843 291. 8ol 0.35

518 100. 000 28. 5070 23.5139 -0.01 282.935 281.661 3. 36 519 102.000 28. t860 2A. +924 -0.02 316. +33 314. 651 0.6o

520 104.000 28.4660 26.4757 -0.04 350.093 347. 134 3.85

NP = p54, ONKMSPCT = 19+, °16ANPCT - 0. + 97

78
Table 5. Comparison of specific heats for saturated li

ID T,K CS4T CALC PC NT 201 95.402 54.240 53.240 1.84

if 01 95.846 54.131 53.307 1.52

202 99.021 54. 6+7 53.833 1.49

302 101.651 54.877 54.300 1.05

•+G2 101.961 54.790 54.356 0.79

203 102.574 54.836 54.465 0.79

204 106.831 55.632 55.204 0.72

303 108.219 55.533 55.417 0.30

It 03 108.800 55.315 55.507 -0. 35 205 112.604 56.075 56.064 0.02

304 115.165 56.434 56.410 0.04

206 119.117 56.810 56.922 -0.20

305 122.474 57.237 57.365 -0.14

4 05 123.367 56.996 57.488 -0.86

207 125.766 57.6+5 57.835 -0.33

406 130.765 58.245 58.673 -C.73

208 132.274 58.774 58.964 -0.32

10 01 132.751 58.879 59.060 -0.31

302 135.455 58.930 59.643 -1.21

1002 137. 8C5 59.729 60.206 -0.80

903 139.970 59.698 60.770 -1.80

SOI 144.305 60.560 62.029 -2.43

904 144.401 60.929 62.059 -1.85

802 148.500 62.033 63.402 -2.21

905 148.881 a2.035 63.534 -2.47

1003 150.824 64.014 64.224 -0.33

803 152. 809 63.838 64.962 -1.67

906 153.157 64.048 65.096 -1.64

1004 155.542 65.246 66.040 -1.22

8 04 157.043 65.435 66.668 -1.88

907 157.355 65.569 66.802 -1.88

1005 159.127 66.935 67.593 -1.C3

805 161.181 67.733 68.583 -1.25

908 161.483 67.898 68.737 -1.24

1306 163.136 68.379 69.622 -1.82

402 163.782 S9.936 69.992 -0.08

407 165.128 70.865 70.813 0.07

80s 165.249 70.534 70.891 -0.51

909 165.548 70.745 71.085 -0.48

1007 166.549 71.756 71.768 -0.02

807 169.253 73.960 73.918 0.06

910 169.565 74.411 74.201 0.28

223 170.157 74.696 74.762 -0.09

1008 170.197 75.369 74.801 0.75

408 170.251 75.575 74.854 0.95 403 171.097 76.320 75.721 0.79

803 173.180 78.5+0 78.212 0.42

911 173.480 79.194 78.619 0.73

701 173.505 78.678 78.654 0.03

216 174.032 79.623 79.406 0.27

1JQ9 174.429 31.334 80.G04 1.64

409 175.228 32.128 81.734 0.48

404 176.295 84.253 83.641 0.73

8 09 177.029 85.456 85.096 0.43

221 177.420 37.382 85.925 1.67

702 177.902 86.730 87.003 -0.25

1J10 178.557 38. 641 88.579 0.07

200 180.613 95.067 94.560 0.53

217 181.034 36.349 96.0 28 0.33

703 181.645 98.844 98.346 0.50 1011 182.572 133.442 102.372 1.03

222 184.222 113.330 111.643 1.49

704 185.271 121.769 119.693 1.71

201 186.127 132.153 128.276 2.93

1012 187.577 141.359 150.568 -6.51

218 187.633 156.439 151.752 3.03

79
Table 6. Comparison of specific heats C (P,T), J/(mol • K)

10 r,K P.B4R MOL/L C, XPTL CCALC PCNT

2209 200.342 56. 917 7.991 35.351 34.277 3. 04 2203 201.339 58.:»7 7.991 35.004 33.9C7 3. 13 2210 207.65'* 35.217 7.988 33.153 32.179 2.94

22U + 208.168 o5.562 7.988 33.141 32.116 3. 09 2211 215.1*02 73.451 7.984 31.732 30.992 2.33

2212 222.937 31.598 7.980 31.046 30.243 2. 59 2205 222.993 31.658 7.980 31.059 30.239 2.64

2205 230.373 49.593 7.977 30.698 29.757 3.07

2213 230.454 39.670 7.977 30.381 29.753 2.07

2207 237.534 97.229 7.973 30.419 29.448 3. 19

2211* 238.128 97.852 7.973 30.198 29.428 2.55

2209 244. 733 131*. 831 7.970 30.045 29.252 2.64

2216 252.790 113.436 7.966 28.913 29.138 -0.78

2218 266.31*9 127.671 7.959 29.785 29.135 2. 18 1505 195.780 53.853 10.175 39.3 25 36.351 7. 56 1506 202.601 5 1» . a + s 10.171 34.818 33.283 4.41

1502 203.11*2 04.857 10.171 34.032 33.142 2.61

1507 209.526 7i*. i*26 10.166 32.879 31.911 2.94

1503 209.853 71*. 915 ID. 166 33.320 31.864 3.50

1504 216.813 85.365 10.161 32.185 31.052 3.52

1508 216.1*67 31*. 845 10.161 31.750 31.0 85 2.09

15u9 223.396 35.256 10.157 31.318 30.266 3.36

1510 230.790 136.373 10.151 30.432 29.784 2.13

1511 237.756 116.844 10.147 29.998 29.492 1.69

1512 2.1*1*. 636 127.181 10.142 29.857 29.316 1.81

1513 251.1*88 137.466 10.137 29.650 29.226 1.43

1514 259. <+u 3 1+9.331 10.131 29.632 29.207 1. 44 1515 266.151* 159.433 10.126 29.560 29.249 1. 05 1517 282.516 193.843 10.114 29.922 29.528 1. 32 1518 289.11*6 193.696 10.110 29.964 29.699 0.69

1519 295.822 233.596 10.105 30.170 29.899 0.90

219 195.627 55.318 11.838 37.165 34.952 5.95

223 196.581 57.055 11. 839 36.177 34.474 4.71

2 24 203.921* 70.601 11.832 33.223 32.299 2.78

2 25 211.370 34.550 11.826 31.908 31.207 2.20

205 215.626 32.534 11.822 31.148 30.790 1.15

226 218.787 98.572 11.819 30.922 30.54C 1. 24 206 223.653 137.819 11.815 30.609 29.963 2. 11 227 226.191 112.653 11.813 30.347 29.800 1. 60 207 231.675 123.117 11.808 30.155 29.527 2.08

2 28 233.566 126.729 11.806 3u. 130 29.454 2. 24 208 239.625 138.319 11.801 30.043 29.279 2.54

229 240.923 1+0.833 11.800 29.653 29.252 1.35

209 2i*8.73i* 155.761 11.792 29.6G4 29.153 1.52

210 257.1*53 172.459 11.784 29.5 34 29.151 1. 30 211 266.957 190.643 11.775 29.632 29.25C 1.29

212 276.531* 2J8.934 11.766 29.702 29.436 0.90

214 296.361* 246. 6+7 11.748 30.098 30.C32 0.22

301 201*. 751 77.746 13.088 32.393 31. 334 3.27

302 212.016 93.924 13.080 31.485 30.589 2.84

303 219. 2d5 110.2+2 13.073 30.868 30.106 2.47

80
Table 6. Comparison of specific heats C (p,T), J/(mol . K) (continued)

10 T,K P.BAR MOL/L C,XPTL CCALC

304 226.524 126.697 13.065 30.478 29.480

305 234.072 143.831 13.057 30.165 29.211

306 241. 245 160.256 13.050 29.985 29.077

307 248.387 176.530 13.042 29.965 29. 034

309 262.566 2J8.987 13.026 29.918 29.148

310 276.780 241.398 13.011 30.309 29.456

313 276. 944 241.772 13.010 30 .114 29.463

31** 283.783 257.318 13.003 30.147 29.668

311 290.591 272.756 12.995 30.375 29.901

312 297.427 238.216 12.987 30.687 30.161

501 191.539 52.228 14.388 34.U42 32.384

528 195.039 61.226 14.383 32.765 31.654

502 198.638 70.602 14.379 32.000 31.12C

5 20 200.323 75.028 14.377 31.660 30.919

503 205.816 39.577 14.371 31.171 30.405

521 208.733 97.366 14.366 30.940 30.196

504 212.954 108.696 14.362 30.585 29.949

522 217. 1C3 119.884 14.356 30.292 29.757

505 220.066 127.901 14.353 30.152 29.434

523 225.394 142.360 14.346 30.0 32 29.195

506 227.167 147.130 14.344 30.067 29.135

524 234.287 156.574 14.334 29.826 28.969

507 234.417 156.928 14.335 29.805 28.967

508 241.372 185.9)2 14.326 29.647 28.903

525 242.493 188.952 14.324 29.585 28.900

509 248.293 204.791 14.317 29.485 28.913

510 255.197 223.622 14.308 29.500 28.983

511 262.143 242.543 14.299 29.656 29.103

514 265.537 251.779 14.294 29.681 29.178

512 269.538 262.650 14.289 29.689 29.278

515 273.495 273.386 14.284 29.885 29.39C

513 277.494 234.223 14.278 29.877 29.514

516 281.439 294.892 14.273 30.061 29.646

517 289.349 316.229 14.262 30.557 29.940

1601 185.501 +2.477 16.038 32.608 31.345

1602 187.587 +9.323 16.035 32.198 3 0.994

16 03 189.591 55.934 16.032 31.832 30.727

1504 191.595 52.532 16.0 29 31.732 30.506

1518 192.871 56.824 16.024 31.410 30.384

1605 193.605 69.272 16.026 31.163 30.319

1606 195.615 75.989 16.023 31.0 41 30.158

1607 197.622 32.719 16.020 31.157 30.018

1606 199.628 89.464 16.017 30.831 29.895

1619 200.031 90.821 16.011 30.746 29. 872 1620 209.230 121.946 15.996 30.246 29.476

1609 217.964 151.399 15.986 29.793 29.255

1611 223.224 159.616 15.977 29.830 28.908

1610 223.903 171.930 15.976 29.834 28.89C

1622 229.421 190.754 15.964 29.842 28.787

1612 229.453 190.871 15.967 29.795 28.787

1623 239.424 224.878 15.948 29.681 28.745

PCNT

3.28

3. 16

3. 03 3.11 2.58

2. 81 2.16

1. 59

1. 56 1.71 4.87

3. 39 2.75

2.95 2.46

2.41

2. 06 1.77

2. 38 2.79

3. 10 2.87

2.81 2.51

2. 32 1.94

1.75

1.86

1.70

1. 38 1.66

1.22

1. 38 2.02

3.87 3.74

3.47 3.86

3.27

2.71 2.85

3.66

3. 03

2. 84 2.54

1. 81

3. 09

3. 16 3.53

3.38

3.15

81
Table 6. Comparison of specific heats C (P,T), J/(mol • K) (continued)

10 T,K P.BAR MOL/L CXPTL CCALC PCNT

1613 241.503 231.959 15.948 29.748 28.756 3.34

loll* 21*7.521 252.433 15.939 29.715 28.816 3. C3 1615 253. 1*1.3 2*2.535 15.929 29.742 28.914 2.79

161b 259.333 232.473 15.919 29.869 29.044 2. 76 1617 265.198 312.270 15.910 29.856 29.203 2.19

1625 269. i*l»7 326.572 15.901 29.942 29.335 2. 03 701 187.91.7 51.079 16.103 32.040 30.863 3.67

707 188.669 53.489 16.102 31.992 30.768 3.83

721 191.577 63.234 16.097 31.546 30.447 3.48

702 195.118 75.175 16.092 31.068 30.147 2.96

708 195.637 76.929 16.091 31.042 30.109 3. 00 720 199.1W0 88.817 16.086 30.673 29.885 2.57

703 202.277 99.508 16.081 30.672 29.722 3. 10 709 202.632 110. 720 16.080 30.443 29.706 2.42

704 209.1*08 123.921 16.070 30.2C6 29.447 2.51

710 209.569 124.473 16.070 30.260 29.442 2. 70 711 216. *94 148.231 16.059 29.913 29.266 2.16

705 216.509 1+8. 334 16.059 29.877 29.266 2.05

711 223.352 1M.938 16.048 29.807 28.892 3.07

706 223.900 173.795 16.047 29.782 28.878 3. 03 713 230.1*37 196.326 16.037 29.642 28.767 2.95

714 237.251 219.796 16.026 29.731 28.736 3.35

715 2i*i*. 01*8 2+3. 173 16.015 29.596 28.773 2.78

716 250.777 266.259 16.004 29.629 28.865 2.58

717 257. i*2i* 288.998 15.993 29.692 29.000 2.33

718 261*. 035 311.538 15.982 29.946 29.173 2.58

719 270-623 333.917 15.971 29.851 29.379 1.58

1309 18>t. 761* 45.449 16.723 31.721 30.621 3.47

1301 187.826 56.698 16.717 31.357 30.298 3.38

1310 190.103 55.399 16.714 31.150 30.108 3.34

1302 194.733 32.255 16.706 30.685 29.808 2.86

1311 195.1*1*5 84.934 16.706 30.679 29.769 2.97

1303 201.094 135.956 16.696 30.196 29.518 2. 25 1323 202.937 112.841 16.693 30.239 29.452 2.60

1312 206.062 124.532 16.688 30.204 29.357 2.81

130"* 206.122 124.756 16.689 30.023 29.355 2.22

1324 208.680 134.336 16.683 30.184 29.289 2.96

1305 210.401 1+0.798 16.681 29.882 29.25C 2.11

1313 211.348 144.339 16.679 29.987 29.230 2.52

1325 214.143 154.318 16.674 29.8>*7 29.179 2.24

1306 215.024 158.123 16.673 29.640 29.164 2.26

1314 216.658 154.252 16.670 29.924 29.14C 2.62

1326 219.582 175.218 16.665 29.727 29.103 2.10

1327 225. 0C3 195.5+5 16.655 29.749 28.775 3.27

1317 232.337 223.339 16.643 29.585 28.703 2.98

1318 237.J57 2-.2.891 16.633 29.651 28.707 3.18

1319 243.097 263.174 16.624 29.802 28.752 3.52

1320 248.519 283. 339 16.614 29.686 28.832 2.88

1321 253.921 333.370 16.604 29.831 28.940 2.99

1322 259. 3u<* 323.264 16.595 29.913 29.075 2.80

411 187.325 58.459 17.007 31.221 30.119 3.53

82
Table 6. Comparison of specific heats C (P,T), J/(mol • K) (continued)

ID T,K P.34R MOL/L C, XPTL CCALC PCNT

101 193.924 83.993 16.997 30.513 29.705 2. 65 406 196.587 94.337 16.992 30.399 29.583 2.68

413 203.953 123. 025 16.978 30 .119 29.332 2.61

414 211.988 154.390 16.964 3D. 033 29.160 2. 91

"+15 219.901 135.232 16.950 29.782 29. 063 2.41

'tis 227.768 215.952 16.936 29.698 28.715 3. 31 417 235.598 2+6.397 16.922 29.7 43 26.693 3.53

416 245.293 233.931 16.904 29.635 26.786 2.87

419 252.926 313.338 16.890 29.667 28.932 2. 48 1801 178.581 37.972 18.086 31.280 30.072 3.66

1802 181.649 51.836 18.080 30.991 29.854 3.67

1803 186.224 72.545 18.068 30.598 29.610 3.23

1804 192.299 130. J83 16.056 30.377 29.382 3. 28 1805 198.354 127.540 16.044 30.090 29.225 2.87

1805 204.379 154.828 18.032 29.958 29.119 2.60

1807 210.370 131.915 18.019 29.803 29.05C 2.53

1808 216.641 210.137 18.006 29.741 29.010 2.46

1309 222.620 237.053 17.994 29.812 28.747 3.57

1810 228.488 263.318 17.982 29.742 28.696 3.51

1811 234.304 239.242 17.97 29.683 28.708 3. 28 1812 240.990 318.931 17.955 29.841 28.776 3.56

1709 172.603 40.332 19.500 30.637 29.495 3.73

1710 178.550 73.439 19.486 30.586 29.587 3. 27 1701 181.613 90.419 19.479 30.306 29.476 2.74

1711 184.637 137.182 19.472 30.262 29.388 2.89

1702 187.628 123.725 19.465 30.094 29.317 2.58

1712 190.680 140.564 19.457 30.082 29.257 2.74

1703 193.640 156.857 19.450 30.021 29.210 2. 70 1713 196.693 173.622 19.443 29.980 29.171 2.70

17 04 199.616 139. b30 19.435 29.918 29.141 2.60

1714 202.661 236.260 19.428 29.976 29.117 2.87

1705 205.568 222.086 19.421 29.798 29.100 2. 34 1715 208.615 238.633 19.413 29.854 29.089 2.56

1706 211.480 254.140 19.406 29.844 29.084 2.55

1716 214.522 270.555 19.398 29.783 29.084 2.35

1707 217.573 286.970 19.391 29.752 29.089 2. 23 1717 220.387 332.058 19.384 29.837 28.882 3.20

1708 223.411 318.216 19.376 29.789 28.850 3. 15 807 161.140 19.394 21.312 30.545 30.771 -0.74

801 165.189 68.455 21.296 30.567 30.409 0.52

808 166.828 80.175 21.295 30.509 30.231 0.91

802 171.921 116.374 21.278 30.496 29.683 2.67

809 172.488 120.333 21.278 30.337 29.633 2.32

810 178.091 159.845 21.261 30.308 29.803 1.67

803 178.582 163.284 21.257 30.276 29.786 1.61

811 183.640 198.575 21.244 30.225 29.661 1.87

804 185.182 239.230 21.237 30.195 29.631 1.87

812 189.153 236.719 21.227 30.237 29.568 2.21

805 191.734 254.462 21.217 33.176 29.536 2.12

813 194.626 274.250 21.210 30.230 29.507 2. 39 806 196.229 298.774 21.197 30.140 29.48C 2. 19

83
Table 6. Comparison of specific heats C (P,T), J/(mol • K) (continued)

ID T,K P.B4R MOL/L C.XPTl CCALC PCNT

8 lit 200.378 311. 310 21.192 30.110 29. +69 2.13

2109 153.96+ 30.6+6 22.126 31.0+0 31.271 -0.75

2101 157.876 52.133 22.113 30.931 31.219 -0. 93 2102 162.200 96.526 22.098 30.800 30.966 -0.5+

2133 166. +97 130. +32 22.083 30.832 30. 5++ 0.93

2101* 170.767 163.6+7 22.069 30.716 30.070 2.10 2105 175.011 196.789 22.05+ 30.567 30.193 1.22

2105 179.31+ 229.91+ 22.0+0 30.615 30.038 1.88

21u7 183.51+ 261.932 22.025 30. +32 29.933 1.6+

2108 187. 7C1 293.689 22.011 30. + 68 29.856 2.01

1+06 1+6.828 ++. +59 22.933 31.31+ 31.5+9 -J. 75

1 + 07 155.536 13+. 131 22.907 31.098 31.680 -1.67

11*02 155.969 117.9+2 22.906 31. 1C0 31.67+ -1. 8 + It 01 156.936 life. ++9 22.900 31.0+2 31.653 -1.97

1*08 162.130 161.835 22.883 30.958 31.36+ -1. 31 1*03 162.565 165. +98 22.881 30.925 31. 328 -1. 30

1 + 09 168.6+8 217.953 22.858 30.923 30.678 0.79

1 + U + 169.076 221.618 22.856 30 .826 30.628 0.6+

1 + 10 175.122 272.935 22.83+ 30.798 30.550 0.81

1 + 05 175.530 276.3+7 22.832 30.898 30.531 1.19

2001 139.0 73 +5. 399 2+.008 31.796 31.731 0. 2C 20 02 1+3.270 38.559 23.990 31.655 31.988 -1. 05 2J03 1+7. ++8 130.92+ 23.972 31.612 32.213 -1.90

230+ 151.599 172. +91 23.95+ 31. +37 32. 352 -2. 91 2305 155.908 215.13+ 23.935 31.550 32.3+8 -2.53

2305 160.011 255.2 09 23.917 31.258 32.165 -2. 90 2307 16+. 072 29+. ++5 23.903 31.267 31.811 -1.7+

901 130.508 3+.766 2+.785 32.662 31.993 2.05

909 131.693 + 8. 379 2+.772 32. +5+ 32. 0+1 1.27

9 Oh 132.69+ 59.8+2 2+.767 32. +79 32.083 1.22

902 13+. 136 76.278 2+.761 32.166 32.1+8 0. 06 910 137.159 110. +10 2+.7+6 32.080 32.29+ -0.67

903 139.337 13+. 756 2+.735 31.9+9 32. +08 -1. ++ 911 1+2.5+7 170.330 2+.720 31.911 32.580 -2.10

905 1+3.713 163.112 2+.715 31.96+ 32.6+1 -2. 12 912 1+7.666 228.55+ 2+.695 31.785 32.830 -3.29

907 1+9.12+ 2+1.915 2+.689 31.732 32.871 -3.59

913 153.185 235.371 2+.670 31.728 32.933 -3.80

908 15+. +73 299. 329 2+.66+ 31.839 32.92+ -3.+1

1201 121.160 6+.+S+ 25.872 33.1+5 32.926 0.66

1202 12+. 223 13+. c9 + 25.855 32.958 33.003 -0. 1 + 1203 127.262 1++.031 25.838 32.757 33.065 -0.9+

120+ 130.27+ 182. +1+ 25.822 32.691 33. 130 -1.3+

1101 110.867 ++. 963 26.655 33.910 33. +13 1.+7

1103 111.855 59.633 26.6+9 33.72+ 33. +96 0.68

1106 111.917 50.51+ 26.6+9 33.789 33.501 0.85

1102 116.030 120.523 26.62+ 33.557 33.7+f -0.56

11C7 117.051 135.151 26.618 33. +78 33.786 -0.92

110 + 122.089 236.336 26.588 33. +15 33.398 -1.+5

1108 122.09+ 236. +53 26.588 33. 311 33. 898 -1.76

1109 127. 10C 275. +51 26.559 33.18C 33.9+2 -2. 30 1105 127.123 2"'5.7S9 26.558 33.210 33.9+2 -2. 20 130+ 102. +2+ +8.+1+ 27.388 3+.+28 33.505 2.68

1301 105.029 90.9+8 27.371 3+.2b7 33.88C 1. 13 1305 107 . + 66 129.912 27.355 3+.129 3+.170 -0. 12 1002 110.058 170.735 27.338 3+. 0+9 3+.+11 -1. C6 1306 112. + + 6 237.816 27.322 3+.035 3+.573 -1.56

1303 115.1+2 2+9. P13 27.305 33.999 3 +.6 9U -2. + 1307 117.361 282. + 91 27.290 33.879 3+.751 -2.58

1912 92.592 + 0.2f» 26.16+ 35.326 33.339 5.63

1901 92.609 +0.5+0 28.16+ 35. +15 33. 3+C 5. 86 1937 93.793 52.36+ 28.155 35.166 33. +92 + . 81 1902 95. +65 92.859 26.1+3 35.C03 33.731 3.63

1913 95.63+ 95. 385 28. 1+1 35. 020 33.756 3. 61 1908 96.575 11+. 525 28.13+ 3+.B98 33.913 2. 62 1903 98.31.1 1+3. 313 28.122 3+.913 3+.161 2.15

1909 99.515 15+.+35 28.11+ 3+.830 3+.3+U 1. +0 19U+ 101.123 192.536 28.102 3+.S39 3+.580 0. 7 + 1913 132.319 213.335 28.C93 3+.710 3+.7+6 -0.10

1905 133.902 2 + C. 152 28.082 3+. 793 3U. 9+8 -0. +5 1911 105.10+ 250. 311. 28.C7+ 3+.6j0 35.C67 -1. +1 1906 106.665 256.2 32 26.0b3 3+.6++ 35.2+7 -1. 7U

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Table 8. Comparison of speeds of sound for saturated liquid

T,K P.BAR MOL/L M/SEC CALCO PCNT

94. 05 0.178 27.857 1509.0 1543.3 -2.27

94. 36 0.185 27.841 1507.0 1540.1 -2.20

96.17 0.228 27.689 1489.8 1521.2 -2.11

98.50 .294 27.492 1466.6 1496.4 -2.03

101.79 .414 27.211 1433.

9

1460.7 -1.87

10 5.45 0.590 26.893 1400.0 1421.0 -1.50

109.09 0.818 26.572 1363.8 1381.7 -1.31

112.79 1.113 26.238 1326.8 1342.3 -1.17

116.07 1.439 25.937 1293.3 1307.7 -1. 11 119.78 1.869 25.588 1256.0 1268.6 -1.01

123.81 2.491 25.199 1214.5 1226.1 -0.96 127.96 3.250 24.787 1170.3 1181.7 -0.98

131.97 4.135 24.375 1127.2 1138.0 -0.95

136.17 5.240 23.929 1081.0 1090.9 -0.91

140.23 6.499 23.481 1035.3 1044.

C

-0. 64 144.49 8.043 22.992 986.7 993.6 -0.7C

149. 01 9.955 22.448 933.3 938.9 -0.60

153.78 12.306 21.839 875.7 880.0 -0.49

158.02 14.7C9 21.263 822.2 826.8 -0.56

162.81 17.810 20.552 759.1 765.2 -0. 80 lo7.50 21.275 19.839 694.3 702.2 -1.14

172.02 25.051 18.997 628.2 63b.

8

-1.37

176.44 29.195 18.085 556.1 562.6 -0.84

179.47 32.313 17.360 5C6. C 509.

6

-0.7C

182.51 35.686 16.538 449.0 451.6 -0.58

185.93 39.800 15.292 374.3 378.6 -1.14

187.55 41.878 14.540 331.5 339.0 -2.27

189.60 44.640 13.156 273. 276.5 -1.27

87
Table 9. Comparison of speeds of sound, W(p , T)

T,K P.BftR MOL/L M/SEC CALCD PCNT

1 1 1 . 33 1.125 2fe.3'2 1340.9 1357.9 -1.27

1 1 1 . 33 5.046 26.394 1345.0 1360.8 -1.18

111.33 9.808 26.421 1349.6 1364.3 -1.09

111.33 19.728 26.477 1358.7 1371.5 -0.94

111.33 29.37+ 26.530 1367.0 1378.3 -0.83

111.33 39.324 26.514 1376.6 1385.3 -0.63 111.33 49.132 26.636 1384.8 1391.9 -0.51

111.33 58.839 26.637 1393.1 1398.4 -0.38

111.33 68.151 26.736 14C2.1 1404.5 -0.17

111.33 75.690 26.775 14C8.5 1409.3 -0.C6

125.09 2.8C7 25.C74 12C0.6 1212.6 -1.00 125.09 5.299 25. j93 1202.9 1215.2 -1.02

125. 09 10.1u2 25. 129 12C9. 1220.1 -0.92

125.09 19.910 25.292 1220.8 1229.9 -0.75

125.09 29.577 25.273 1232.1 1239.4 -0.59

125.09 39.172 25.3+1 1242.7 1248.5 -0.47

125.09 48.636 25.497 1253.8 1257.3 -0.28

125.09 59.235 25. +79 1265.1 1266.9 -0.14

125.09 68.465 25.5+1 1275.0 1275.0 0. 00 125.09 77.959 25.603 1285.0 1283.2 0.14 125.09 87.747 25.o56 1295.0 1291.4 0.27 125.09 97.B80 25.73C 13C5.2 1299.8 0.41 1*0.02 6.475 23.516 1038.5 1046.6 -0.78

140.02 11.115 23.557 1045.0 1053.5 -0.81

140.02 19.860 23.652 1059.5 1066.2 -0.63

140.02 29.810 23.755 1075.0 1080.1 -0.47

143. 02 39.344 23.851 1089.1 1092.8 -0-34

140.02 49.3C5 23.947 1104.0 1105.7 -0.15

140.02 58.991 24.038 1117.9 1117.6 0. 01 140.02 68.354 24.124 1130.6 1129.1 0.14 14U.02 78.932 24. 218 1145.3 1141.4 0.34

140.02 88.355 24.299 1157.0 1152.0 0.43 1+0.02 97.880 24.378 1169.5 1162.5 0.60 140.02 106.087 24. ++6 1178.7 1171.3 0.63

140. 02 110.343 24.430 1183.9 1175.7 0.69

15 5. 4+ 13.579 21.627 854.0 860.4 -0.75

155.44 21.451 21.757 872.9 876.6 -0.66

155. +4 29.151 21.898 891.3 895.6 -0.48

155.44 39.811 22.058 915.1 917.6 -0.27

155. 44 49.528 22.213 935.5 936.3 -0.08

155.44 59.295 22.352 954.5 954.0 0.05

155. 4* 67.371 22.451 970.5 968.0 0.26 155.44 78.426 22.533 990.5 986.1 0.44

15 5.44 88.761 22.730 10C7.7 1002.3 0.54 155.44 97.779 22.836 1022.5 1015.8 0.66 155.44 108.418 22.957 1038.6 1031.

C

0.73 155.44 118.145 23.053 1053.6 1044.4 0.87 155.44 127.771 23.154 1068.6 1057.2 1.06

155. 44 137.701 23.255 108C.9 107C.G 1.01 155.44 147.732 23. 354 10 94.9 1082.4 1.14 155.44 155.939 23.443 1105.5 1092.3 1.2C

88
Table 9. Comparison of speeds of sound, W(p,T) (continued)

T,K P+BAR MOL/L M/SEC CflLCD PCNT

170.75 21+.021+ 19.239 61.6. 8 656.2 -1.1+5 170.75 30.012 19.1+58 672.2 683.2 -1.6<*

17 3.75 39.567 19.735 710.2 720.1+ -1.1+1+ 17 0. 75 1+9.153 20.058 71+3.7 752.7 -1.22

17 0.75 62.0 Ll 20.378 782.7 790.5 -1.00

170.75 78.1+26 20.732 826.0 832.1+ -0.77

17 0.75 88.761 20.930 81+9.9 856.0 -0.71

170.75 98.285 21.130 871.1 876.2 -0.58

17 0.75 106.898 21.21+5 890.3 893.1+ -0.35

170.75 116.726 21.1+32 909.0 912.0 -0.33

170.75 126.960 21.556 927.0 930.1+ -0.36

170.75 135.775 21.682 91+1+.1 91+5.1+ -0.H+

173.75 1*»6. Ill 21.823 961.1+ 962.2 -0.09

170.75 156.11+2 21.951+ 977.9 977.8 0.01 170.75 168.706 22.110 995.3 996.5 -0.12

170.75 182.892 22.278 1015.6 1016.1+ -0.08

185.91 1+5.211 16.2+8 1+50.0 1+56.1+ -l.i+l 185.91 50 .031+ 16.756 1+91+.8 1+99.8 -1.00

185.91 59.336 17.-+ 40 556.2 561.2 -0-9C

185.91 68.860 17.950 603.0 609.3 -1.05

185.91 78.932 18.3*9 61+6.6 651.2 -0.72

185.91 89.267 18.71+7 685.6 688.1 -0.37

185.91 98.083 19.021 707.1+ 716.0 -1. 22 135.91 108.111+ 19.238 733.7 71+1+.8 -1.52

185.91 118.21+6 19.531 766.8 771.1+ -0.6C

185.91 132.533 19.870 800.6 805.3 -0.59

185.91 11+8.137 20.180 836.3 838.8 -0.30

185.91 158.878 20.376 856.1 860.1 -0.1+6 185.91 173.570 20.621+ 881+.2 887.2 -0.31+ 185.91 183.396 20.778 901.8 9C1+.3 -0.28

190. 03 1+5.525 13. 157 261+.2 285.9 -8.20

190.03 1+7.751+ li+. i+10 31+0.2 357.2 -5.00

190.03 52.91+2 15.511+ 1+15.6 1+30.2 -3.51

190.03 59.528 16.286 1+82.3 1+88.1 -1.20

190. 03 68.1+05 16.930 539.8 51+1+.9 -0.95

193.03 77.919 17.521+ 590.9 592.6 -0.29

190.03 88.558 18.035 631+.5 636.7 -0.35

190.03 101.021 18.1+53 677.7 680.5 -0.1+2 190.03 113.1+81+ 18.81+8 715.7 718.1+ -0.38

190.03 125. 7i+i+ 19.177 7i+8.8 751.6 -0.38

190.03 137.903 19.<+58 778.2 781.1+ -0.1+1 190.03 150.366 19.737 807.2 809.1+ -0.27

190.03 163.336 19.392 833.3 836.2 -0.35

190.03 175.090 20.235 855.1 858.9 -0.1+5 190.03 187.350 20.1+13 878.5 881.2 -0.3C

190.03 199.712 20.609 900.5 902.3 -0.2C

89
Table 10. Calculated P(T) isochores

The following pages give P(T) along isochores, as computed by the equation of

state (6). The third column DP/DD is the isotherm slope (Sp/op) in units of the bar and

2 2 mol/'t. The last two columns give the isochore slopes and curvatures 5P/3T, d P/3T ,

in units of the bar and K.

These tables show that the isochore curvatures are qualitatively consistent with

a maximum in the specific heat C (P , T) near the critical point. v

90
METHANE ISOUHORE 1.0 MOL/L

T,< P,3AR OP/ 10 OP/DT 02P/OT2

154.0 10.642 8.511 0.0962 -0. 00019

162.0 11.4UD 9.334 0.0949 -0. 00014

170.0 12.161 10.2 35 0. C939 -0..00011 178.0 12.9U9 11.069 3. 0931 -0 . C0009

186.0 13.651 11.890 0. 0925 -0. 00007 194.0 14.369 12.712 0. 0920 -0. 00006 202.0 15.123 13.535 0. 0916 - J

.

00005 210.0 15.854 14.302 0.C912 -0., OOOOh

218.0 16.583 15.0 33 0. 0909 -0. 00004

22o.O 17.308 15.479 U. 0906 -0. 00003

lit. 18.032 16. oil 0.090* -0.,00003 242.0 18.754 17.439 0. 0901 -0..00003 250.0 19.475 18.215 0. 0900 -0,,00002 258.0 20.194 18.9 57 0. 0898 -0.. 00002

266.0 20.911 19.7i7 0.089d -c,.00002 27*. 21.628 20.524 0.0895 -0,.00002 282.0 22.343 21.239 0.0893 -0.,00002 290.0 23.057 22.052 0.0892 -0. OC002 298.0 23.770 22.613 0. 0891 -0,.00001 306.0 24.463 23.573 0. 0890 -0.. 00001

314.0 25.194 24. 330 0.0889 -0,.00001 322.0 25.905 25.047 0. 0888 -0,. OOG01 330.0 26.615 25.8-fl 0.0887 -0,.00001 338.0 27.324 26.5 35 0. 0886 -o. 00001 346.0 28.032 27.347 0. 0685 -0,,00001 354.0 28.740 28.0 37 0. 0884 -0. 00001 362.0 29.447 28. 3 + 6 G. C884 -0,,00001 370.0 30.154 29.595 0. 0883 -0. 00001 378.0 30.860 30.3+1 0.0832 -0.. 00001 386.0 31.565 31.037 0. 0881 -0., 00001 394.0 32.270 31.632 0.0831 -0..00001

methane: ISOCHORl 2.0 MOL/L

T,K P,6AR DP/3D DP/OT D2P/0T2

170.0 20.618 6. 7 54 0.2115 -0. 00G65

178.0 22.292 7.7 45 0.2072 -0. 00045

186. 23.936 8. 7i8 0.2040 -0. 00L34

194.0 25.558 9.724 0.2016 -0. 00027 202.0 27.1b3 10.oi2 0. 1997 -0. 00022 210.0 28.754 11.534 0.1981 -0. 00018

218.0 30. 33* 12*494 0.1968 -0,. G0015 226.0 31.904 13. 3 35 0. 1957 -0. 00013

23*. 33.46b 14.233 0. 1948 -0. 00011 242.0 35.021 15.174 0.1939 -0,.00010 250.0 3o.570 16. 5h 0. 1932 - < 00009

256.0 38.112 16.926 0. 1925 -0,,00006 266.0 39.650 17. 7 38 0. 1919 - u. 00007 274.0 41.184 18.534 0.1914 -0,,00007 282.0 42.713 19.526 0.1909 -0. 00006

290.0 44.238 20. 335 0.1904 -0. 0000c 298.0 45.7b0 21.2+0 0. 1900 -0. 00005 30o.O 47.278 22. 3 33 0. 1896 -0. 00005 314.0 48.793 22.9+2 0. 1892 -0. 00005

322.0 50.305 23.739 0. 1688 -0.,00004 330.0 51.615 24. o33 0. 1885 -0. 00004 338.0 53.321 25. 475 0. 1832 -0. 00004

3->a. 54.825 26. 314 0. 1678 -0. 00004

354.0 5o.327 27.152 0.1875 -a. 00004

362.0 57.826 27.9 36 0. 1872 -0. 00004

370.0 59.322 2 8. 019 0. 18o9 -0. 00004 373.0 60.817 29.650 0.1867 -0. 00003

366.0 62.309 50. +'8 0. 10 64 -0,, 0000 3

3 9h.O 63.799 31. 3 J5 0. 1861 -0. 3

91
METHANE ISOCHORE 3.0 MOL/L

T,K P,B«P OP/ JO UP/QT 02P/DT2

173.0 28.b31 4.9oG u 34*0 -u. 00149

I80.O 31.3*3 6.114 0.33*5 -0. 00095

194.0 33.992 ^.210 0.3281 -0. 00066 202.0 36.597 8. 271 0. 323* -0. 00052 210.0 39.169 9.3)8 0. 3197 -0. O0U41 218.0 41.715 10.327 U. 3168 -0.00033

22o.O *4.239 11.533 0.31** -0. GGC23

2 5*. 3 46.7*6 12.328 0. 3123 -0. 0002*

242.0 49.236 13.314 0.3105 -0.00020

250.0 51.715 14.2 52 0. 3090 -0. 00018

258.0 54.1ol 15.254 0.3077 -0.00016

26b. 56.637 lb. 2 50 0.30o* -0. 00U14

27*. 59.085 17.1 31 0.3053 -0. CoC13 282.0 61.623 18. 1*8 J. 3C*3 -0. GJG12 290.0 63.954 19. 131 0.3034 -0. 00011 298.0 66.378 20.0+9 0. 3025 -0. 00011

30b. 68.795 20. 334 0. 3017 -0.00010

31*. 71.2U5 21.936 0. 3009 -u. 0UU09

322.0 73.610 22.874 0.30J2 -0. 00G09

330.0 76.009 23.3 59 0.2995 -G.00C09

338.0 78. 4C2 24.7+1 0.2988 -0. 00008

3*6. 80.790 25.D70 0.2982 -0. 00008 354.0 83.173 26. 5 36 0.2975 -0. 00006

362.0 85.551 27.52C 0. 29b9 -0. 00008

370.0 87.923 2B.++0 0.2963 -0.00007

378.0 90.292 29.358 0. 2957 -0.00007

386.0 92.655 50.2^3 0.2952 -0. 00007

3 9*. 95.014 51.135 0.2946 -0. 00007

METHANE ISOCHORE *.0 MOL/L

T,K P,BAR DP/ JD DP/D1 02P/OT2

186.0 36.3G0 3.872 0.43*1 -0. 0G227

194.0 40-112 5. 339 0. <.700 -0. G0137 232.0 43.834 6.2 iB u.4609 -U. 00 j95 210.0 47.493 7.* 33 0.*543 -0. C0071 218.0 51.1C7 6.517 G.4493 -G. 0G056

226. 54.684 9.ot6 0. 4452 -0. 00G45 234.0 36.232 10. 7J3 0.4419 -0. 00038 242.0 61.756 11.732 G.4391 -0.00032

250.0 65.26U 12.333 J. 43o7 -0.00 02 8 258.0 68.745 13.918 C.434o -0. 0O025 266.0 72.215 l*.9f8 C.4328 -0.00022

274.0 75.67C 16.033 0.4311 -0. 00G20 282.0 79. 112 17. 334 u.4295 -0. 03019 230.0 82.543 18.151 0. 4231 - u . 1

7

298.0 85.y62 19.1^4 0.42o8 -0. 00016 3J6.0 89.371 20.214 0.1-255 -0.00015

31*. 92.770 21.250 0.4243 -0. 00G15

322.0 96.1oG 22.233 0.4231 -0. 00014

330. 99.541 23. 312 0.4220 -0. 00014

338.0 102.913 24. 338 U.4210 -0. 00013 3*6.0 106.27b 25.3>1 3.4199 - . G 1 3 354.0 109.631 26. 331 0.4139 -0.00013

3o2.0 112.978 27.338 0.4179 -0. 00C12 370.0 lib. 318 2b. *11 j.4169 -C. C0012

378.0 119.6*9 29. -.21 J. 4160 -0. 0U312 386.0 122.973 30.428 0.415J -0. G0012

3 94.0 126.269 51.* 52 0. <-!<+! -3. GuC12

92
METHANE ISOUHORt 5.0 MUL/L

T,K P,8AR DP/ JO DF/DT 02P/DT2

166.0 39.236 2.076 0.65*5 -0. 00569

190.0 *1.815 2.772 0.6366 -0. 3*6 19*. **.337 3.t26 0. 6250 -0. 002*5

198.0 *o.819 *.058 0.616* -0. 00187

202.0 *9.271 *.677 3.6098 -0. 001*9

206.0 51.699 5.2 38 U.60*3 -0. 00123 210.0 5*. 107 5. 891 0.5998 -0. 0010*

21*. 56.*98 6.*90 0.59o0 -0. 00089

218.0 58.875 7.0 35 0.5926 -0. 00076

222.0 61.2*0 7.o77 0.5897 -0. 00069

226.0 63.593 6.257 0.5871 -0. 00061 230.0 65.937 8.85* 0.58*8 -0. 00055

23*. 68.272 9.*39 0.5e27 -0, 00050 238.0 70.599 10. 023 U. 5808 -0. 000*6 2*2.0 72.919 10.606 0.5791 -0. 000*2

2*6.0 75.232 11.187 0.5775 -0. 00039

230.0 77.539 11. 738 O.E7oO -0. 00036

25*.

G

79-8*0 12.3*7 0.57*6 -0. 0003* 258.0 82.135 12.925 0.5733 -0, 00032

262.0 8*.*26 13.3 13 0.5720 -0. 00030 266.0 86.712 1*.079 0.5709 -0. C0028 270.0 88.993 l*.o55 0.5697 -0. 00027

27*. 91.270 15.230 0.5667 -0. 00026 278.0 93.5*2 15.8J5 0.5677 -0. 00025

282.0 93.811 16.378 0. 5667 -0. 00C2*

286.0 98.076 16.951 0.5657 -0. 00023 290.0 100.337 17.52* 0. 56*8 -0. 00C23

29*. 102.59* 18.095 0.5639 -0. C0022 298.0 10*. 8*8 18.356 0.5631 -0. 00021 302.0 107.099 19.236 0.5622 -0 C0021 30o.O 109.3*6 19.805 0.561* -0 00020 310.0 111.590 20.37* C.5606 -0. C0020

31*. 113.831 20.9*2 0.5598 -0 C0020

318.0 116.069 21.509 0.5590 -0 00019

322.0 118.303 22. 0?5 0.5562 -0 00019

326.0 120.535 22.6+1 0.5575 -0. 00C19

33J.0 122.763 23.205 0.5567 -0 00019

33*. 12*. 989 23.7 j9 0.5560 -0, 00018

338.0 127.211 2*. 333 0.5553 -0 C0016

3*2.0 129. *31 2*. 895 0.55*5 -0. 00018

3*6.0 131.6*7 25.V57 0.5538 -0 00018

350.0 133.861 26.0 17 0.5531 -0 00018

35*. 136.072 26.377 0.55 2* -0 00018 358.0 138.260 27.136 0.5517 -0 00018

362.0 1*0. *86 27.595 0.5510 -0. 00016 366.0 1*2.688 28.252 0.5503 -0, 00017 370.0 1**.888 28.809 0. 5*9o -o. 00017

37*. 1*7.085 29. 33* 0.5*39 -0 00017

378.0 1*9.279 29.919 0.5*82 -0 00017

382.0 151. *70 30.+73 0.5*75 -0. 00017 386.0 153.659 31. J26 0.5*68 -0 00D17

390.0 155.6*5 51.578 0.5*61 -0 00017

39*. 158.028 32.129 .5*55 -0 C0017

398.0 160.208 32.330 0.5**8 -0 C0017

93
METHANE ISOCHORE 6.3 MOL/L

T,K P BAR DP/ 3D CP/DT 02P/0T2

190.0 -.3 917 1. 531. u , 610* -0. PC727

134.0 47 112 2. 1 34 J. 7892 -0. C0396 198.0 50 241 2. 353 0. 77o3 -0. 3263 202.0 5 3 327 3. 5 JO 7670 -0. 00200 206.0 56 33G 4. 139 a. 7630 -0. 00157 210.0 59 406 4. .'7 4 J. 7543 -3. C0128

21*. 62 41b 5. 4 J7 7496 - Q. 00107 218.0 65 40b 6. 038 7456 -0. 03391 222.0 68 382 6. jo6 7 + 22 -0. 00079 226.0 71 345 7. 2 37 7393 -0. 070 230.0 74 296 7. 926 J

7366 -0. u 062 234.0 77 233 3. o ? 4 J 73 + 3 -0. 00056 233.0 80 171 9. 132 7322 -0. 00051 242.0 83 096 9. o 10 u 7302 -0. C0C46 246.0 86 013 10. *38 7285 -0. C3343 250.0 38 924 11. j 56 72o8 -0. 000*0

25*. 91 828 1 1. 6 3 4 7253 -0. 00037 253.0 94 .726 12. 322 7236 -0. 00035

262.0 97 619 12. 3 + 9 7225 -0. 00C33

266. 100 506 13. iTb 7212 -0. 00 032 270.0 1J3 388 14. 2J4 7200 -0. 3 3 274.0 106 ,266 14. 331 j 7188 -0. U C 2 9 278.0 109 138 15. 457 7176 -0. C3326 282.0 112 007 16. 34 3 7165 -3. 00027 286.0 114 371 16 ; 10 7154 -0, 001.27 290.0 117 730 17, 3 35 71+4 -0. 00026 294.0 120 586 17. 961 a 71 34 -0. 00026

293.0 123 .437 18 ?36 7123 -0 00025

302.0 126 .205 19 210 j 7113 -0. 00025

30o.O 129 .128 19. 8 34 a 7104 -0. 00024

310.0 131 .967 20. 458 709+ . -3. 3 024 314.0 134 803 21. J31 7084 -0 00024

318.0 137 ,b35 21 703 ,7075 -0, 0002 + 322.0 140 463 22. 325 7065 -0. 03024

326.0 143 287 22 9 + 6 7056 -0 00023

330.0 14b 108 23 3 56 a 7047 -3 00023

334.0 148 ,925 24, 136 ,7037 -o. t0C23 338.0 151 736 24. 3 35 ,7028 -0 00U23

3*2.0 154 .5*7 25 *23 ,7019 -0 00023

346. 157 353 26 + G ,7009 -0 00023

35J.0 160 165 26 o5e Q 7000 - u 00023

3:54.0 162 .953 27 272 .6991 -0 00023

358.0 165 .7,7 27, 337 ,6982 -0 00023

362.0 168 .538 28 pjl ,6973 -0 00023

366.0 171 .325 29. 1 14 c963 -0 00023 370.0 174 .109 29 726 .6954 -0 00023 374.0 176 889 50. 3 37 69 + 5 -o. C0023

378.0 179 .665 30 947 .6936 -0 OO023

382.0 182 437 31 556 6927 -0 00023

336.0 185 .20b 32 165 3 ,6917 -0 00023 39J.0 187 971 32 ,•72 .6908 -3 00023 394.0 190 763 33. 378 6899 -3 00023

393.0 193 .490 33 933 J 6890 -0 C0023

94
METHANE ISOCHORE 7.0 MOL/L

T,K P,BAR DP/DO DP/DT 02P/DT2

190.0 44.962 0.323 0. 9975 -0. 01927

194.0 48.647 1.329 0.,9560 -0. 00568

196.0 52.642 1. 398 0.,9410 -0. 326 202.0 50.383 2. iol o. 9 3 3 2 -0. 00223

20b. 60.086 3. 324 0.,9225 -0. 00167 210.0 63.765 3. 918 0.,9166 -0. 00131

21*. o7.422 4. 654 J, 9119 -0. 00106 218.0 71.0ol 5.322 0.,9030 -0. 00089 222.0 74.667 5. j 93 0. 90 + 7 - 0. 00076 226.0 76.300 6. jo5 0,,9019 -0. 00066 230.0 81.903 7.139 0,,8994 -0. O0C58

234.0 85.496 8 .-015 0..6973 -0. C0052 238.0 89.081 8.o93 0. 8953 -0. 000*7

242.0 92.659 9.372 0,,8935 -0. 00043

246.0 96.229 10.052 0,,8919 -0. 00039

250.0 99.794 10.733 J •,8904 -0.,00037 254.0 103.352 11.415 0,,ee89 -0. 00035

258.0 106.905 L2. a 38 . ,8876 - 0. 00033 262.0 110.453 12.732 0,,8863 -0., 0O032

266.0 113.995 13. + 67 0,, 8850 -0. 00031 2/0.0 117.533 14. 152 0,,8838 -0.,00030 274.0 121.066 14.6 58 J,,8827 -0., 0OG29

278.0 124.595 15.623 0,,8615 -0,,00028 262.0 128.118 16.209 0. 8804 -0. 00028

286.0 131.638 16.336 0,,8793 -0.,00028 290.0 135.153 17.512 0.,8762 -0., 00027 294.0 138. b63 18.268 0,,6771 -0., 00027 298.0 142.169 18. 954 o.. 8760 -o. 00027

302.0 145.671 19.640 0.,6749 -0. 00027 306.0 149.169 20.326 0.,8739 -0. 00027

310.0 152.662 21.011 0,,8728 -0.,00027 314.0 156-151 21.636 0. 8717 -o. 0UG27

318.0 159.636 22.311 0,,8706 -0,, 0U027

322.0 163.116 23.0d4 0,,6695 -0,,00027 326.0 166.592 23.7+8 0,, 8684 -0,,00027 330.0 170.063 24.431 i ,8673 -0,,00028 334.0 173.530 25. 113 0,,6662 -0,,00028 338.0 176.993 25.7 34 0,,8651 -0,, 00028

342.0 180.451 2b. +75 0,.8640 -0,,00 02 8 346.0 183.904 27.155 0,,8628 -0,, 00028 350.0 187.354 27.3 S4 0,,8617 -0,,00028 354.0 190.798 26.512 0,, 8606 -0,, 00029

358.0 194.238 29.139 0,,859+ -0., 00029

362.0 197.673 29.856 a..6583 -0,, 00029 366.0 201. Iu4 30.5+1 0,,8571 -0,,00029

370. 204.530 31.215 0,, 8559 -0,,00029 374.0 207.952 31.338 0,.6548 -0,,00029 378.0 211.368 52.5^1 u .8536 -o.,00030 382.0 214.780 13.232 0,,8524 -0,,00030 356.0 218.168 3 3.902 0.,8512 -0,,00030 390.0 221.590 3+.570 0,,8500 -u,, 00030 394.0 224.988 35.218 0.. 8436 -0,,00030 396.0 228.381 35.934 0,,8476 -0,, 00030

95
METHANE ISOCHORE B.O MOL/L

T,K P.8AR OP/JD OP/OT 02P/OT2

191*. *9.8e5 [1.7:55 1. 1253 -0. 00635

198.0 5*. 327 l.*21 1, 1080 -0. 00302 202.0 58.739 2. 100 1. 098* -0. 00190 206.0 63.119 2.7 90 1. 0921 -0. 0013* 210.0 67.*78 3.*30 1. 087* -0. 00101

2 It. 71.820 *.137 1 0639 -0.00079

218.0 76.150 *.9U 1 G810 -0. 00Gb*

222.0 80.*69 5.631 1 0787 -0. C005* 226.0 8*. 780 6.355 1, 0767 -0. 000*6 230.0 89.G83 7.035 1. C750 -0. 000*0

23*. 93.380 7.818 1 0735 -0. 00036

238.0 97.671 8. 55* 1. G721 -0. 00033

2*2.0 101.957 9.23* 1 0708 -0. 00030 2*6.0 106.237 1C.036 1 0o97 -0. 00028 250.0 110.51* 10.731 1 C686 -0. G0027

25*. 11*. 786 11.528 1. 0675 -0. 00026

258.0 119.05* 12.276 1 0665 -0. 00026

262.0 123.318 13.026 1 065* -0.OOC25

266.0 127.577 13.778 1 06** -0. 00025 270.0 131.833 1*.5 31 1. 063* -0. 00025

27i*. 136.085 15.23* 1 062* -0. OU025 278.0 1*0.332 16.039 1. 061* -0.00025

282.0 1**.576 16.79* 1, 060* -0.00026

286.0 1*8.815 17.550 1 0593 -0. 00026 290.0 153.051 18. 336 1. 0583 -0. 00027

29*. 157.282 19.052 1 0572 -0. 00027

298.0 161.508 19.819 1. 0561 -0. 00028

302.0 165.730 20.575 1. 0550 -0. 00028

306.0 169.9*8 21.332 1 C539 -0. 00029

310.0 17*.lbl 22.088 1. 0527 -0.00U29

31*. 178.370 22.8** 1, 0515 -0.00030

318.0 182.57* 23.599 1 0503 -0. 00030

322.0 186.773 2*. 35* 1 0*91 -0. 00031 326.0 190.967 2 5.139 1 0*79 -0.00031

330.0 195.156 25.363 1. C*66 -0. 00032

33*. 199.3*0 26.616 1 0*53 -0. 00032

338.0 203.518 27.369 1. 0**0 -0. 00033

3*2.0 207.692 28.120 1 C*27 -0. 00033 3*6.0 211.860 28.871 1. 0*1* -0. 0003*

350.0 216.023 29.621 1. 0*00 -0.0003*

35*. 220.180 30.359 1 0386 -0. 00035 358.0 22*. 332 31.117 1 0372 -0.00035

362.0 228. *78 31.86* 1. 0358 -0. 00036

3o6.0 232.618 32.639 1 03** -0.00036

370.0 236.753 33. 35* 1, 0330 -0. 00036

37*. 2*0.882 3*. 097 1, 0315 -0. 00037

378.0 2*5.005 3*. 839 1. 0300 -0. 00037

382.0 2*9.122 35.530 1. 0285 -0.00037

386.0 253.233 36.319 1, 0270 -U. 00038

390.0 257.338 37.357 1, C255 -0. 00036

39*. 261. *38 37. 733 1. 02*0 -0. 00038

398.0 265.531 38.528 1. C225 -J. 00038

96
METHANE ISOCHORE 9.0 MOL/L

T,K P.BAR DP/ JD OP/OT D2P/DT2

19*. 50.*7c 0.532 1.2689 -0. 0C395

193.0 55.609 1.21* 1.2790 -0. 00158

202.0 60.715 1.929 1.27** -0. 00086 206.0 65.80b 2. o66 1.2717 -0. 00053

210.0 70.889 3.*19 1.2699 -o. 00035

21*. 75.966 *. 116 1.2687 -0. U002* 213.0 81.039 *.963 1.2679 -0. 00016 222.0 86.110 5.7*6 1.2673 -0. 0001* 226.0 91.178 6.5*2 1.2668 -0. 00011 230.0 96.2** 7.3*2 1.266* -0. 00010

23*. 101.309 6.1*6 1.2660 -0. 00009

233.0 106.372 8.956 1.2656 -0. 00009

2*2.0 lll.*3* 9. 773 1. 2652 -0. 00010 2*6.0 116. *9* 10.592 1.26*8 -0, 00010 250.0 121.552 11. *1* 1.2b** -0,, 00011 25*. 126.609 12.239 1.2639 -0..00012 253.0 131.66* 13.0 57 1.263* -0.i 0001*

262.0 136.71b 13.896 1.2b28 -0, 00015 266.0 1*1.766 1*.728 1.2622 -0. 00016

270.0 1*6.81* 15.531 1.2615 -0. C0018

27*. 151.658 16.395 1.2608 -0, 00019

278.0 156.900 17.231 1.2600 -0. G002C 232.0 161.938 16. 068 1.2591 -0.. 00C22

2 86.0 166.973 18.935 1.2582 -0. 00023 290.0 172.00* 19.7*2 1.2573 -0. 00025

29*. 177.031 20.530 1.2563 -0. C0C26

298.0 182.05* 21.419 1.2552 -0., 00027 302.0 187.073 22.2*7 1.25*1 -0. 00029

306.0 192.067 23.095 1.2529 -0,, G0G30

310.0 197.096 2 3.933 1.2517 -c. 00031

31*. 202.100 2*. 771 1.250* -0. 00032

318.0 207.100 25.608 1.2*91 -0.,00033 322.0 212.093 26. +** 1.2*78 -0.i 0003*

326.0 217.082 27.230 1.2*6* -0.,00036 330.0 222.0b* 28.115 1. 2**9 -o. 00037

33*. 227.0*1 28.9*9 1.2*3* -0.,00038 338.0 232.012 29.733 1.2*19 -0. 00038

3*2.0 236.976 30.615 1.2*0* -0., 00039

3*6.0 2*1.935 31. **6 1. 2388 -0. 000*0 350.0 2*6.887 32.277 1.2372 -0. 000*1

35*. 251.832 33. 1 J5 1.2355 -0., 000*2

358.0 256.771 33.933 1.2338 -0. 000*3

362.0 261.702 3*. 759 1.2321 -0. 000*3

3 66.0 266.627 35.53* 1.2303 -0., 000*4 370.0 271.5*5 36.*36 1.2286 -0. 0*5

37*. 276. *56 37.230 1.2268 -0,, 000*5 378.0 281.359 38. 050 1.22*9 -0. 000*6 382.0 286.255 38.859 1.2231 -0. 00046 386.0 291.1** 59.636 1. 2212 -0. 000*7 390.0 296.025 *0.502 1.2193 -0,,000*7

39*. 300.899 *1. 316 1. 217* -0. 000*8

398.0 305.765 '+2. 128 1.2155 -0.. 000*8

97
.1ETHANE IS0CH3R£ 1 . MOL/L

T,K P ,BAK D°/ 1C OF/OT 02P/0T2

1^,0 51.,00/ • 5 + C 1.+P32 0. 8 5 198.0 5b,.a*b 1.275 l.*6l* 3,,00077 202.0 62,,698 2. J56 1.4b4+ 0. 00070 206.0 68 .5ol 2.335 l.*b/0 0. t j 210.0 /*,,*3* 3.o 9b 1. 4693 o. C0057

21*. 80,.316 4.5 + 3 1.4/16 0. 00051 216.0 8b,,206 5. + J4 1.4/36 0. 00C46 222.0 92,.11* t.276 l.*/52 0. OOCO

22o.O 98,,008 7. 157 1.4/6/ J. 035 230.0 103,.91/ 6. 0*/ 1.4780 u. 00030

23*. 109,.b31 8.9 + 3 1.4/91 0. 00025

233.0 115 ,/50 9. 8*5 1.4300 0.,00020 2*2.0 121 , .6/1 10. /52 1.430/ 0. OOOlo

21*6.12/,.595 . 11. ob* 1.4813 0., CC012

250.0 133,,521 12.579 1. 481/ 0. 00006

25*. 139,,*46 13.* ii 1.4819 0., C0Q04 258.0 1*5,.3/c 1*. +?0 1. 4820 0. 00001 262.0 151,.305 15.3+* 1.4620 -0.,00003 2o6.0 15/,,232 lc.2/0 1.4818 -0. 0000b 2/0.0 163 .159 1/. 1 J/ 1. 4815 -0.,00009

27*. 169,.08* 18. 12/ 1.4811 -o. 00ol2 2/8.0 1/5,.0o8 19. j5Z 1.4806 -0.,C0G15 282.0 180,,929 19. 938 1.4/99 -0, 0018 266.0 lSo,,6*/ 2C.920 1.4/92 -0.,0u02C

290. 192., Zo2 31.852 1.4/83 -o. 00023

29*. 198,,b/3 22. 73* 1.47/3 -0., 00025

298.0 20*,,560 23.717 1.4763 -0.,00028 302.0 210,,*63 2*.d+9 1.4751 -0., 00030 306.0 21o,,381 25.531 1.4739 -0., 00032

310.0 222,,2/* 26.512 1.472b -0. CG03*

31*. 228,,lc2 27.**3 1.4/12 -0., 00C3b

316.0 23*,,0*3 28.3/3 1.4697 -0.,00038 322.0 239,,919 29.333 1.4682 -0.,00039 326.0 2*5,,/89 30.2 il 1.4666 -0., 0UC*1

330.0 251,,632 51.158 1.46*9 -0. 000*3

33*. 25/,.506 32.03* 1.4631 -a., 00044

338.0 263,,35/ 3 3 . J J 9 1.4613 -0. G0G*6

3*2.0 269,,196 33.913 1.4595 -c, 00047

3*6.0 2/5,,033 3*. 855 1.45/6 -0., 00046 350.0 280, 869 35. //6 1. 4556 -0. 0005C

35*. 286,,6/7 36.D35 1.4536 -0. 00051 358.0 292,,*B8 37.612 1.4515 -0. C0G52

362.0 298,,290 36.526 1. 4*94 -0.,00053 366.0 30*.,C63 59. ++2 1. 44/3 -0. 0005*

3/0.0 309,,8o8 + 0. 354 1.1*1*51 -0. 00055

37*. 315,,6** +1.234 1.4429 -0, 00056 3/8.0 321,,*11 +2.173 1.4*06 -0. 00o57

332.0 32/,,169 +3. 0/9 1. 4383 -o. 00058

336.0 332,,918 +3. 933 1.4360 -0.,00058 390.0 338,,t57 + *. 3 36 1.433/ -0. 00059

39*. 3**,.38/ +5.736 1.4313 -a., G006C 398.0 35U, 10/ +6.o3* 1.4289 -0. 00060

98
METHANE ISOCHORE 11.0 MOL/L

T,K P,BAr< DP/ 3D DP/DT 02P/0T2

19*. 51.571 0.,601 1.6*20 C , 03707

193.0 58.183 1. *17 1.6620 0. 00376

202.0 6*. 858 2,,237 1.67*6 3. 00266 236.0 71.576 3, 1 92 1.68*0 0. 00207 210.0 78.327 *.,122 1. &915 0. 00169

21*. 85.10c 5. 071 1.6976 0. 001*1 218.0 91.907 6, 3 36 1. 7029 3. 00120 222.0 98.728 7,,013 1.7073 0.,00102 226.0 105.565 8..3 31 1.7111 0. 00088 230.0 112. *15 8. 938 1.71*3 a. 00075

2Si*. 119.278 10. 332 1 .

'< 1 7 1 0.,03 06* 238.0 126.152 Hi 13 1.719* 0. 0005*

2*2.0 133.033 12.,329 1.721* 3.,000*5 2*6.0 139.922 13. 350 1. 7230 3. 00036

250.0 1*6.817 1*. 375 1.72*3 0., 00029

25*. 153.716 15. 133 1.7253 0. 00022

258.0 160.619 16.,13* 1.7261 0. 00016 262.0 167.525 17. 1d7 1.7266 3,, 00010 266.0 17*.*32 16..2 )2 1.7269 3. 0030* 270.0 181.339 19,,2 39 1.7209 -0,,00001 27*. 188.2*7 20.,277 1.7268 -0., 00306

2f8. 195.153 21,,315 1.7265 -0.,00010 282.0 202.058 22. 355 1.7260 -0. 00015

286.0 208.961 23. 3 3* 1.7253 -0. 00019

290.0 215.861 2*.,* 3* 1 . 72*5 -o. 00022 294.0 222.757 25. *73 1.7235 -0. 00026 298.0 229.6*9 26. 512 1.722* -0., 00U30 302.0 236.536 27. 551 1.7212 -0. 00033

306.0 2*3. *18 28. 539 1.7198 -0. 00036

310.0 250.29* 29,,o26 1.7183 -0., 00039

31*. 257.16* 30. 652 1.7167 -0. 000*2

318.0 26*. 027 31. o37 1.7150 -0. 000**

322.0 270.88* 32. 7 30 1.7131 -o. 000*7

326.0 277.733 33.,732 1.7112 - 0.,003*9 330.0 28*. 573 3*.,7 33 1.7092 -0.,00051 33*. 291. *06 35.,822 1.7071 -3., 00053

333. 298-230 36. 3*9 1.7 0*9 -o. 00056

3*2.0 305.0*6 37. 875 1.7027 -0. 00057 3*6.0 311.852 38..8 38 1.7C0* -0. 00059

350.0 318.6*0 39. 920 1.6979 -0.,00061

35*. 325. *35 *0. 939 l.o955 -3. 0QC63

358.0 332.212 *1. 957 1.6929 -0. C006*

362.0 338.979 *2. 372 1.6903 -0,, 00066

366.0 3*5.735 *3.,935 1.6877 -0. 00067 370.0 352. *B0 **., 335 1.6850 -0.,00068

37*. 359.215 + 6. 03* 1.6822 -0. 00370 373.0 365.938 *7. 3 39 1.679* -0. 00C71

382.0 372.650 + 8. 013 1.6766 -0. 00072 386.0 379.351 *9.,313 1.6737 -0. 00373

390.0 386.039 50. 3 12 1.6708 -0. 0007*

39*. 392.716 51. 3 37 1.6678 -0. 00375

3 98. 399.382 52. 000 1. 6o*6 -o. 00376

99
METHANE ISOCHORE 12- J MOL/L

T,K P.BAR OP/ 3D OP/OT D2P/OT2

19*. 52.2a9 913 1. 6516 G. 01322

196.0 59.779 1 855 1. 8692 (1. C0699

202.0 67.36* 2 6 37 1. 9123 0. 00*81 206.0 75.0&6 932 t. 9290 0. 365 210.0 82.811 * 9o2 1 9*20 0. 00292

21*. 90.601 6. 0*2 1. 962o 0. 00239

216.0 96.*30 7 157 1. 961* 0. 00200 222.0 106.290 8 2*5 1 9637 0. 00169

226.0 11*. 176 9 363 1, 97*9 0. 1 * 3 230.0 122.089 10 *30 1 9802 0. 00121

23*. 130.019 11 62* 1 98*7 0. 00103 238.0 137. 9o5 12 75* 1 9885 0. 00087 2*2.0 1*5.926 13 909 1 9917 0. 00073

2 to. 153.896 15 058 1. 99*3 0. CO 06 250.0 161.860 16 211 1 9965 U i 000*9

25*. fl 169.869 1.7 3o6 1 9982 0. 00038

256.0 177. 8c5 18 52* 1, 9995 < G0029

262.0 185.865 19 653 2 0005 0. 00020 266.0 193.8o6 20 8** 2 CD12 0. 00012 270.0 201.87* 22 336 2 0015 0, 00005

27*. 209.880 23 .158 2 C015 -0. 00002 273.0 217.886 2* 3 30 2 0013 -0. 00009

262.0 225.890 25 *93 2 0009 -0. 0001* 286.0 233.892 26 o55 2, 00C2 -J 03020 290.0 2*1.891 27 316 1 9993 -o. 0C25 294.0 2*9.886 28 977 1 9982 -0. CU030 298.0 257.87b 30 1 37 1 9969 -0. 00C35

302.0 265. 861 31 2 15 1 995* -0, 00C39

306.0 273.839 32 *52 1 9937 -o. 000*3

310.0 281.810 33 608 1 9919 -0, 000*7

31*. 289.77* 3* 761 1 9900 -0, 00051

318.0 297.730 35 913 1 9879 -0. 0005*

322.0 305.677 37 063 1 9856 -o- 00057

326.0 313.61* 38 211 1 9833 -0. 061 330.0 321.5*3 39 357 1 9808 -0 00063

33*.0 329. *£1 *0 531 1 9762 -0. 00066

338. 337.368 *1 6*2 1 9755 -o. GU069

3*2.0 3*5.26* *2 731 1 972/ -0. 00071 3*o.O 353.1*9 *3 917 1 9698 -0. 0007*

350.0 361.022 *5 ,050 1 ,9o68 -0 00076

35*. 368.68* *6 131 1 9637 -o. 00078

358.0 376.732 *7 339 1 960o -0 00080 362.0 38*.5b6 *8 * 3* 1 9573 -0, 00082 366.0 392.391 *9 ^56 1 95*0 -0 00083 370.0 *00.2uu 5C 675 1 9507 - 00085

37*. *07.996 51 792 1 9*72 -3 00087

378.0 *15.7?8 iZ . 935 1 9*37 -0 00O88

382.0 *23.5*b 5* .015 1 ,9*02 -0 00089

386.0 *31.299 55 122 1 9366 -0 00091 390.0 *39.03e 56 .225 1 9329 -0 00092

39*. **6.7b3 57 ,326 1 ,9292 -0 0C93

393.0 *5*.*72 58 .*23 1 ,9255 -0 0009*

100
METHANE ISOCHORE 13.0 MOL/L

T,K P ,BflR OP/ID OP/OT 02P/DT2

190.0 45 .342 0.642 1.,9949 3. 06151

194.0 53 .601 1.330 2,,1098 0. 0159b

198.0 62., 145 3. on 2, 1581 0. 00936 202.0 70 .844 4.1 96 2,, 1894 0.. 0Co59 206.0 79 .650 5.413 2, 2124 0. 00503

210.0 88,,537 6.648 2,,2303 0,, 00400 214.0 97 ,488 7.897 2. 2448 o. 00327 218.0 106,.492 9. 159 2, 25o7 0. C 27 1 222.0 115,.539 10.430 2.,2666 , 00227 226.0 124,.623 11.710 O ,2750 0. 00191 230.0 133 .737 12. 995 2,,2820 0.,0 0161 234.0 142,,877 14.236 2,,2879 0. 00136 238.0 152,,039 15.581 2,,2929 0. 00114

242.0 161,.219 16.880 2,,2970 0. 00094

246. 170.,414 18.181 2.,3005 J., C0077

250.0 179,,622 19.433 2,,3032 0. 00062 254.0 188,,839 2 0.788 2,,3054 0. 00G48 258.0 198,.064 22.0 93 2,,3071 0. 3 6 262.0 207..295 23.398 2.,3083 0., 00025 266.0 216,,530 24. 704 2. 3091 . 00014

270.0 225,,7o8 26.009 2,,3095 a,,00005 274.0 235.,00o 2 7 . 314 2. 3095 -o. 00004 278.0 244,.243 28.617 2,,3091 -0,, 00012 282.0 253,,478 29.919 2, 3085 -0. 00020 286.0 262,,710 31.220 2,, 3076 -0. G0U27 290.0 271,,938 32.520 2. 3064 -0. 00033

2 94.0 281,.161 33.317 2.,3049 -0. 00040 298.0 290,,377 35.112 2,,3032 -0., 00045 302.0 299,,5Bb 3 6.405 2,,3013 -0, 00051

306.0 308.,787 37.o96 2. 2991 -0. 00056

310.0 317,.979 38.934 2,,2968 -0. 00061 314.0 327,,161 40.270 2. 2943 -0. 00065 318.0 336,,333 4l. ;53 2,,2916 -0. 00069

322.0 345.,494 42.332 2,,2888 -0. 00073

326.0 354.,643 +4. 109 2. 2858 -0. 00077

330.0 363,,780 4 5.333 2,,2826 -0,. C0C80 334.0 372,,904 40.654 2.,2793 -0. 00064

338.0 382,,015 47.921 2.,2759 -0,.C0087 342.0 391,,111 49. 185 2. 2724 -0. 00090

346.0 400,,193 3C.445 2,,2687 -0. 00093

353.0 409, 261 51.752 2. 2650 -o. 00095 354.0 418,,313 52.956 2.,2611 -0. 00098 358.0 427,,350 5 4.206 2. 2571 -0. 00100 3b2.0 436,,370 55.452 2.,2531 -0. 001C2 366.0 445, 374 56. o 34 2. 2490 -o. 00104

370.0 454,,3b2 5 7.933 2. 2447 -0, 00106

374.0 463,,332 59.156 2. 2405 -0. 00108

378.0 472,,2b5 60.399 2.,2361 -0. 00110 382.0 481. 221 61.626 2. 2317 -0. 00112

38o.O 490.,139 62.349 2. 2272 -0. 00113

390.0 499.,038 64.058 2. 222b -0. 00 114 394.0 507. 919 5 6.233 2. 2180 -o. 00116

398.0 516,,782 Db.494 2. 2134 -0. 00117

101
.1ETHANE ISOCHORE 1*.J MOL/L

T,K P dAR D 3 /0C DP/OT 02P/DT2

190.0 1*0 636 2 106 2.3515 0. C3016 ln.O 5b 229 3. 590 2.*357 0. 01528

198.0 66 078 5 J 35 2. *853 0. 0101*

202.0 76 092 6 *78 2.5200 0. 007*7

.:0o.o 86 227 7 927 2.6*63 0. 00580

210. 96 *55 9 3 32 2.6671 0.0 0-.6 5 21*. 106 753 10. 8*3 2.5839 0. 00380 218.0 117 123 12 309 2.6978 0. 00315 222.0 127 537 13 77 8 2.tC93 0. 00262 226.0 137 99* 15 251 2.6139 0.00219

230.0 1*8 *8fa 16 726 2.6269 0. 00183

23*. 159 006 18. 202 2. 6 3 3o 0. 00152

238.0 169 553 19 o79 2.fc391 0. C0125

2*2. J 180 119 21. 157 2.t*37 a . 1 2 2*6. 190 702 22. t> 3* 2. 6*73 0.00O82

25U.Q 201 297 2* 110 2.fc5u2 0. 00063

25"+. 211 902 -> :, 536 2.652* 0. 000*7

2S8.0 222 .515 27 O3C 2.c6'«0 0.00032

262. 233 133 28 p32 2. 6550 J. 00019

266. 2*3 755 30 J 02 2.6555 0. G0006 270.0 25* 377 31 *70 2.6555 -0.00005

27*. 26* .998 52 935 2.c551 -0.00015

278. 275 617 3* 306 2.65*3 -0. 00U25 282.0 286 ZZZ 55 858 2.6531 -0. 00G3<« 286.0 296 8*2 57 315 2.651b -0. 000*2 290.0 307 ,**5 38 7s8 2.6*98 -0. 0005C

Z9«f.a 318 .0*0 *0 218 2.6*77 -0. 00057 298.0 328 62c *1 665 2.6*52 -0. 00063

302.0 33^ .201 *3 108 2.6*2o -0. 00C70 306.0 3*9 ,766 •»* 5*7 2.6397 -0. C0076

310.0 360 .318 *5 912 2.6365 -0. 00081

31*. 370 85b + 7 *13 2.6332 -0. C0086 318.0 381 ,38* *8 8*1 2.6297 -0. 00C91

322.0 391 895 50 26* 2.6259 -0. 00096

326.0 *02 .391 51 633 2.6220 -0. 0010C 330.0 *12 871 33 J 07 2.6179 -0.0010*

33*. *23 .33* 5* 508 2.fcl37 -0. 0U108

338.0 *33 780 55 91* 2.6093 -0. 00111 342.0 *** ,209 57 315 2.6 0*8 -0. 00115 3*6.0 *5* 619 58 712 2.L002 -0. 00118

350.0 *65 010 50 10* 2.595* -0. 00121

35*. *75 .382 51 *02 2.5905 -0. 0012*

358.0 *85 ,7Sk 32 875 2.5855 -0. 00126

362.0 *96 065 3* 253 2. 560* -0. 00129

366.0 506 ,377 o5 627 2.6752 -0. 00131 370.0 516 667 56 06 2.5699 -0.00133

37*. 526 936 38 360 2.56*6 -0. 00135

378.0 537 183 59 719 2.5591 -0. 00137

382.0 5*7 ,*Ci9 71 073 2.553b -0.00139

386-0 557 612 72 tli 2.5*80 -0. 001*1 390.0 567 ,793 rz 737 2.5*23 -0. 001*2

3 9*.0 577 ,9 = 1 75 107 2.5366 -0.00 1** 398.0 588 ,085 7 6 ,-,+2 2.5308 -0.001*5

102
METHANE ISOCHORE 15. G MOl/L

T,K P.BflR DP/3D DP/OT D2P/DT2

190.0 49.939 4 729 2.7734 0. 01990

19*. 6 1 . 1 7 C 6 524 2. 8376 0. 01307 198.0 72.615 8 273 2.8822 0. 952 2J2.0 84.213 10 003 2.9155 0. 00731 206.0 95.929 LI 7 12 2.941b 0. C0580 210.0 107.739 13 *35 2.9624 0. 469 214.0 119.624 15 1+2 2.9794 0. 364 218.0 131.570 16 8+6 2.9934 0. 00316 222.0 143.567 18 34b 3. C049 0, 261 226.0 155.606 20 2 + 2 3.0144 0. 00215 230.0 167.680 21 934 3.0222 Q. 00176

23t.O 179.782 23 623 3. 0285 0. 00143

238.0 191.906 26 30 8 3.0337 0. 00114

242.0 204.050 26 959 3.0377 0. 00089 246.0 216.207 26 o56 3.0408 0. 00067 250.0 228.376 3 333 3. 0431 0. 00047

254.0 240.550 32 07 3. 0446 0, 00029

258.0 252.731 33 670 3.0454 0. 00012 262.0 264.913 35 329 3. 0456 -0, 00002 266.0 277.094 36 933 3. 0452 -0, 00016 270.0 289.274 58 632 3.0443 -0. 00028 274.0 301.449 40 277 3. 0430 -0. 00039

273.0 313.617 41 916 3.0412 -0. 00050 282.0 325.778 3 550 3. 0390 -0. 059 286.0 337.929 45 179 3. 0365 -0. 00068 290.0 350.069 6 8)3 3. G336 -0. 00077

294.0 362.197 4 8 421 3. C303 -0. 00084 298.0 374.311 50 034 3. 0268 -0. 00092

302.0 386.411 51 64l 3. 0230 -0, 00098

30o.O 398.495 53 2 + 3 3. 0189 ~ u« 00105

310.0 410.562 54 839 3.0146 -0 00111 314.0 422.612 56 4 30 3.0101 -0 00116 318.0 434.643 58 015 3.0053 -c. 00122 322.0 446.654 59 535 3. 0004 -0. 00126

326.0 458.645 51 158 2.9952 -0. 00131

330.0 470.616 62 736 2.989y -0 00135

334.0 482.564 34 299 2.<3844 -0. 00139 338.0 494.491 33 855 2.9787 -0. 00143

342.0 50o.394 57 406 2.9729 -0. 00147

346. 518.274 68 951 2.9670 -0. 15 350.0 530.130 70 439 2.9609 -0 00153

354.0 541.961 72 022 2.9547 -0. 00156

358.0 553.767 73 550 2.94 84 -0, 00159

362.0 565.548 75 071 2.9420 -0 00162 366.0 577.303 7b 5 36 2.9354 -0 00164 370.0 589.031 78 ib 2.9288 -0 00167

374.0 600.733 79 599 2.9221 -a. 00169

378.0 612.408 31 097 2.9153 -0. 00171 332.0 624.056 -32 538 2.9085 -0. 017 3 386.0 635.676 34 074 2.9U15 -0, 00174 390.0 647.268 35 553 2.8945 -0 00176 394.0 668.832 57 027 2.8674 -0, 00176

398.0 670.367 38 4 95 2. 8803 -0. 00179

103
1ETHANE ISOCHORE 16. MJL/L

T,K P ,6AR DP/ 3D OP/OT 02P/0T2

13O.0 *3 67* 6. .' 7 3.2038 0. 020*6

130.0 56 >b32 8.971 3.2713 0. 01397

19i». b9 618 11.037 3.3133 c. 01031

191.0 63 171 13.155 3.355* 0. 00793

202. 9b 651 15.1 31 3.383b 0. 00626 206.0 110 232 17.235 3.*361 0. 00502

210.0 123 89* 19.230 3.*2*1 0. 0*06

21*. 137 621 21.179 3.*388 0. 00330 2ia.a 151 *01 23. 1*6 3.*507 0, 267 222.0 165 22* 25. 131 3.*603 0. 00216

226.0 179 081 27.0** 3.*680 0. 00172

230.0 192 9ct> 28.977 3.*7*2 o. 0013*

23*. 206 872 30.931 3.*789 0. 00102

238.0 220 795 32.815 3.*82* 0. C0C7*

2*2.0 23* 730 3*. 720 3.*8*8 0. 000*9

2*6.0 2*8 .672 5b.ol7 3.*863 0. 00027 250.0 262 619 38.535 3.*870 0. C0007

25*. 276 5o7 *0. 33* 3.*869 -0. BOOH

258.0 290 .513 *2.255 3.H861 -0. 00027 262.0 30* *55 + *. 118 3.*8*7 -0. 000*2 266.0 318 ,390 +5.973 3.*827 -0. 00056 270.0 332 316 +7. 820 3.*803 -0. 00066

27*. 3*6 .231 *9.659 3.*773 -0. 00079 278.0 360 13* 51. +30 3.*739 -0, 0CC90 282.0 37* ,022 53.313 3.*701 -0. C0100

28s. 387 89* 55. 129 3.*b59 -0, 00109

290.0 *01 7*9 56.937 3.*bl* -0. 00117

29*. *15 585 58.737 3.*566 -0, 00125

298.0 *29 *01 60.530 3.*51+ -0. 00132 302.0 **3 196 o2. 315 3.**60 -0 00139

306.0 *56 969 i*.0 92 3.**03 -0. 001*6

310.0 *70 719 65.852 3.t*3*'* -0. 015 2 31*. *8* .*** 67.o25 3.*282 -0. 00157

318.0 *98 1** 69.380 3.*218 -0. 00162

322.0 511 618 71.127 3.*152 -0 C0167

326.0 525 ,*65 72.367 3. *08* -0. 00172

330.0 539 .085 7*.oJ0 3.*01* -0, 00176

33*. 552 67b 76.325 3.39*3 -0 00181

338.0 566 .239 78.0*3 3.3870 -0 0018*

3*2.0 579 772 79.753 3.3795 -0 00 166 3*6.0 593 ,275 31. -.57 3.3720 -0. 00191 350.0 606 ,7*8 33.152 3.36*2 -0 00195

35*. 620 189 3*. 8+1 3.356* -0 00198

358.0 633 .598 36.522 3. 3*8* -0 00200

362.0 6*6 .976 38.1 36 3.3*0* -o. 00203

366.0 660 .321 39.863 3.3322 -0 00205

37J.0 673 .633 91.522 3.3239 -0. 00208

37*. 686 ,912 33. 1 75 3. 3156 -0 00210

104
METHANE ISOGHORE 17.0 MOL/L

T,K P.BAR DP/OD DP/OT D2P/0T2

162.0 38.182 10.2*2 3.7459 0. 01746

186.0 53.291 12.872 3. 6051 0. 01255

190.0 66.603 15.310 3.8497 0. 943

1 94. 84.067 17.819 3. 8819 0.00729

198.0 99.648 20.2)7 3.9077 0. 00571 202.0 115.321 22.556 3.9281 . 45 2 206.0 131.067 24.873 3.9*4 2 0. 358 210.0 146.870 27.162 3.9569 0. 282 21*. 162.719 29.426 3. 9670 0. 00220 218.0 178.603 51.oo9 3. 97*7 0. 00168

222.0 194.514 33.353 3.9805 0. 00124

226.0 210.445 36.098 3.9847 0. 00087 230.0 226. 390 38.287 3.9875 0. 00054

234.0 242.343 -f 0. t59 3.9891 0. 00026 238.0 258.301 42.617 3.9897 0. 00001 242.0 274.260 **.750 3.9892 -0. 00021

246.0 290.214 *6.390 3.9860 -0. 00041 250.0 306.162 *9. 0J7 3.9860 -0. 00059 254.0 322.101 51.111 3.9833 -0.00075

258.0 338.028 53.202 3.9800 -0. C0090 262.0 353.940 55.212 3.9761 -0.0010*

266.0 369.836 57.350 3.9717 -0. 00116 270.0 385.713 59.436 3.9668 -0. 00127

274.0 401.570 jl.452 3.9615 -0. 00138

278.0 417.404 63.*37 3.9556 -0. 00148

282.0 433.215 56.511 3.9497 -0. 00157 28o.O 449. 001 57. 524 3.9433 -0. 00165 290.0 464.761 69.528 3.9365 -0. 00173

29*. 480.493 71.521 3.9295 -0. 00160 298.0 496.196 73.?J4 3.9221 -0. 00187

302.0 511.870 75. -.77 3.9145 -0. 00193

306.0 527.512 77.440 3.9067 -0.00199

310.0 543.123 79.394 3.8986 -0.00205

314.0 558.700 31.338 3.8903 -0. 00210

318.0 574.2*5 83.272 3.8818 -0.00215

322.0 589.754 35.197 3.8731 -0.00220

326.0 605.229 37.113 3.8642 -0. 00224

330.0 620.667 39.020 3.6551 -0. 0C22e

33*. 636-070 90.917 3.8459 -0. 00232

338.0 651.435 9 2.805 3.6366 -0. 0023b

342.0 66b. 762 94.634 3.8271 -0. C0239

346.0 682.051 96.555 3.8175 -0. 242 350.0 697.302 98.416 3.8077 -0.0J245

105
1ETHANE ISOCHORE 18.0 MOL/L

T,K P-.,8AR DP/GO OP/OT 02P/DT2

178.0 3*,,76b 15.826 r.*0*3 0. 01270 182.0 52.,*75 16. 628 *.**80 0. 00938 186.0 70,,335 21.725 *. *806 J . C 7 6 190.0 88,,310 2*.5t0 4.5053 0. 00537

19*. 106,,370 27.293 *.52*2 0. 00*09

198. 12*,,*97 25. 3 92 *.£38* 0. 00308

202.0 1*2,,b7 J 32.6*7 *.5*91 0. CO 22 6 206.0 160,,885 J5.2o2 *.5568 0. 00162

210.0 179,,12* 37.8+3 *.5622 0. 00108

21*. 197,.360 4 C . 3 9 2 *.5656 0. 00063 218.0 215,,6*7 *2.91* *.5673 0. 00025

222.0 233,,917 *5.*38 *. 5676 -0.00009

226.0 252,,18b *7. 879 <. 5ob7 -0. 00037 23J.0 270,.*50 50.327 4.56*7 -0. 00062

23<f.a 288,,703 5 2.753 *.561d -0. 0008* 233.0 306,,9*3 55. 159 *. 553u -0.0010*

2*2.0 325,,166 57.5*6 *.5535 -0. 00121 2*6.0 3*3,,370 59.915 4.5*83 -0. 00137

250.0 361,,552 62.257 4.5*25 -0. 00152

25*. 379,,710 6*. 601 *.5362 -0. 00165 258.0 397,,8*1 66.920 *. 529* -0. 00176

262.0 *15,.9** 69. 222 *.5221 -0. 00187

2o6.0 *3*,,017 71.510 *.61** -0. 00197 270.0 *52,,059 73.733 *.5063 -0. 00207

27*.

3

470 . 068 76. j+2 *.*979 -0. 00215 278.0 *88,,0*2 78.237 *.*891 -0. 00223

282.0 505,,980 30.r>16 *.*800 -0. 00231 286.0 523,,882 32.7 36 ,.*707 -0. 00238 290.0 5*1..7*5 8*. 9*1 *. *610 -0. 002**

29*. 559,.570 37.133 *.*511 -0.00250

298.0 577,.35* 39.313 *.*4l0 -0. 0026fc 302.0 595,,097 91.*31 *.*30b -0. 262 306.0 612,,799 33.o36 4.4201 -0. U02b7 310.0 630,,*58 95. 730 4.4093 -0. 271 31*. 6*8,,073 97.912 4. 398* -J. 00276

318.0 b65,.6** 190.0 32 *.3872 -0. 00280

322.0 683. 171 132.1*1 *. 3759 -0. 00284

106
METHANE ISOCHORE 19. MOL/L

T,K P ,BAK DP/OO OF/OT 02P/0T2

174.0 35,.346 24.033 5.1773 0.,00717 178.0 5b .106 27. -+53 5. 2016 0,, 00508

182.0 76,,949 JO. 719 5.2187 u,, 00354

186.0 » 97 ,848 33.899 5.2304 0,, 00237

190.0 118, 786 37.036 5.2380 0., 00146

194.0 139 .748 41. 052 5.2423 0,, 00074

198.0 160,.722 +3.0+2 5. 2441 0,, 00016

202.0 181 .698 +5.935 5. 2438 -0. 00031 20o.O 202,.6e9 +8. 333 5.2+17 -0. 0071 210.0 223,.630 51.7+2 5.2332 -0.,00104 214.0 244,,573 54.555 5.2335 -0. 00 132 218.0 265,.496 57.334 5.2277 -0,, 00156 222.0 286.,39 + 30.111 5.2211 -0. 00176

226.0 30 7,.263 d2.8+0 5.2136 -0., 00194

230. 328,.102 jb. 541 5.2055 -0. 00210 234.0 348,,907 36.216 5.1968 -0., 00224

238.0 369,.676 70.337 5.1876 -0. 00237 242.0 390,.407 73.494 5.1779 -0. 00248

21+6.0 411,,099 76.0 39 5.1678 -0. 00259

250.0 431,,749 78.o33 5.1572 -0., 00268

254.0 452. 356 31-2+7 5. 1463 - o. 00276

258.0 472,,919 3 3.731 5. 1351 -0.. 00284

262.0 493,,437 36. 316 5. 1236 -0. 00292

2o6.0 513,,907 36.823 5.1118 -0,,00299 270.0 534..331 31. 313 5. 0997 -0. 00305

271*. 554,,705 33.735 5. C874 -0. 00311 278.0 575,,029 96.2+0 5.07+8 -0., 00316 282.0 595.,303 36.630 5.G621 -0. 322 286.0 615. 526 101. 133 5. C491 -0.,00 327 290.0 635,,696 13 3.512 5. 0360 -0. 00331

29*. 655,,613 105.935 5.0226 -c. 00336

298.0 675,,877 108.233 5.0091 -0. 340 302.0 695. 686 110.647 +.9954 -0.,00 34 4

METHANE ISOCHORE 20.0 MOL/L

T,K P ,BAR DP/30 I3P/OT 02P/0T2

170.0 + 2,,456 35. o32 o , 0608 0. 00112 174.0 66,.704 39,,310 6,,0629 -0., 00001

173.0 90,,953 + 2.,315 6,, Ooll -0., 00086

182.0 115,,188 + b., + 32 c

,

,0563 -0..00150 186.0 139,, + uO + 9. 371 6,, 0492 -o. 00200

190.0 163,,560 53,,242 6,, 0404 -0,,00239

19 + . 137,,722 56,,351 o,, 0332 -0,, Gb270

198.0 211,,820 59,,335 o,, 0189 -0.,00294 202.0 235,,872 o3. J38 6, 0068 -0. 00313

206.0 259,,874 56,,156 5,,9939 -0,. 00329

210.0 283,,823 39, 279 5 , ,9805 -0.. Gb3+2

214.0 307,,717 72, 353 5

,

, 9665 -0. 00353 213.0 331,,554 75. 3 31 5, 9522 -o. 362 222.0 355,,334 73.,333 6,,9376 -u., 00370 226.0 379,,055 31, S?3 5,,9226 -0, 00377 230.0 402,,715 34,,333 5,,9G75 -0., 00363

23 + . + 26,,31 + 37. 213 ;>

,

8920 -o. 00388

238.0 449,,851 30.,0 95 5,, 87o4 -G. 00392

2 + 2.0 473,,325 32., 351 5

,

8607 -0. 397

2 46.0 496,.736 35. 732 5,, 8 + 47 -G, CG+Ul 250.0 520,,083 3 8. p39 5

«

, 8286 -o. 00 + 04 254.0 5 43,,3o5 131., 373 5.,8124 -0., 00408 258.0 5o6,,582 134. 135 5

.

,7960 -0. 00 + 11 262.0 589,,733 10t>.,875 5.,7795 -0. 00414 266.0 612. 818 139. 5 94 6. 7629 -0. 0G417 270.0 635.,836 112.,234 5., 7462 -0. 00419 274.0 658.,767 114. 9'4 5

.

7294 -0. G0-.22 273.0 681,,671 117. o35 5., 7124 -0. 00425

1 07
METHANE ISOCHORE 21. MOL/L

T,K P ,BAK OP/ 3D DP/OT 02P/OT2

loO.O 16 .79 4 *4 o*4 7 0785 -0. 00454

162.0 30 .9*1 + 6 733 7 Co91 -0. 00489

164.0 45 .070 48 329 7 0590 -J. C0518

166. 59 177 50 8

7 5 7 0*8*. -0. 00541

lol.O 73 .263 52. 331 7 0374 -0. 00560 170.0 87 327 54 331 7 U261 - u. 00575

172.0 101 .307 56. 345 7 0144 -0. 00587

i7*.o 115 ,3b* 58 735 7 0026 -0. 00597

176.0 129 .377 dO 733 D 990o -0. C0bC4

178.0 143 3*6 &2. 600 O 9784 -o. C0610

180.0 157 .291 54 477 O 9662 -0. 0061*

182.0 171 211 66. 535 D 9539 -0. 00ol7

16-.. 185 .106 68 175 6 9*15 -0. C0cl8

186.0 198 977 69. 338 b 9291 -o. 00619

188.0 212 .823 71 834 b 9167 -0. 00bl9

190.0 226 ,644 73. o 3 5 6 904* -0. 00619

192.0 240 .4*0 75. 370 b 8920 -c. 00ol7

194.0 254 212 77. 132 6 8797 -0. 00616

196.0 267 .959 78 379 6 6674 -0. 00614

198.0 281 681 30, 613 6 8551 -0. 00&12

200.0 295 .379 32. 335 6 8*29 -0. C0609

202.0 309 053 34. 044 b 8307 -0. 00507

2Jt. 322 702 35. 7*1 6 818b -0. 00b04

206.0 336 327 37 *?7 6 8066 -0. 00602 208.0 349 ,929 39. 132 o 79*6 -0. 00599

210.0 363 506 30 766 b 7826 -0. 00596 212.0 377 059 32 *20 b 7707 -0. 00593

21*. 390 589 34, 064 6 7589 -0. G0591

21o. 404 .09* 35, 638 6 7471 -0. 00588

218.0 417 .577 97 323 b 7353 -0. 00585 220.0 431 036 38, 939 6 7237 -0. 00583 222.0 444 472 100, 5*6 6 7120 -0. 0C580 22*. 457 .88* 102, 1+4 b 7005 -0. C0p78

226. 471 273 103. 734 6 6689 -0. 0J576 228.0 43* 6*0 1J5. 316 o e774 -0. 00573

230.0 497 983 13b. 830 6 6660 -0. 00571 232.0 511 30* 138, *56 c 6546 -0. 00569

234.0 524 .602 110. 014 b 6432 -0, 00567

236.0 537 877 Ill 566 6 6319 -a. 00565

238.0 551 129 113 11C b 620b -0. 00^63

240.0 56* 359 11*. 6 +6 6 c094 -o. 00662 242.0 577 .567 lib 176 b 5981 -0. 00560

24*. 590 752 117. 730 6 5870 -0. 00559

246.0 603 915 119 216 6 5758 -0. 0C557

2*8.0 617 055 120. 726 6 5647 -0. 00656 250.0 630 173 122 230 6 5536 -0. 565 252.0 643 269 123. 7?8 £ 5*26 -0. 55* 254.0 656 343 125. 219 O 531* -0. 00553 256.0 669 395 126. 734 6« 5204 -0. 00a52 258.0 682 425 128. 134 6 5094 -0. 00551 260.0 695 432 129. o58 b 4983 -0, 00550

108
METHANE ISOCHO.RE 22.0 MOL/L

T,K P.BAR DP/3D OP/OT 02P/0T2

154.0 23.629 61. 470 8.,2331 -0. 01305 156.0 40.069 63.,7 51 a,, 2071 -0. 01292

158.0 56.457 o5. 9 56 3., 181* -a. 01277

160.0 72.795 ?8. 13* 8., 1561 -o. C1261

162.0 89.082 70. 321 3., 1310 -0. 01243

164.0 105.319 72. 431 8., 1063 -0. 01224

166.0 121.507 74. 574 3,, 0820 -0, 01205

163.0 137.61.7 76. j 3 3 8. 0581 -o. 01166

170.0 153.740 78.,729 8,,0346 -0, 01167

172.0 169.766 80. 772 6., 0115 -0. 01147

174.0 185.786 82. 734 7.,9887 -0. 01128

176.0 201.7*1 84. 7 95 7. 9663 -0. 01109

178.0 217.652 86. 778 7.,9443 -0, 01090 180.0 233.519 88. 7+2 7..9227 -0. 01072

182.0 2*9.3*3 30. 688 7.,9015 -0. 01054

18*. 265.125 92. ol8 7. 880b -0. 01036 186.0 280. 8b5 34. 531 7,,8600 -0., 01019

188.0 296.565 id. + 29 7., 8398 -Q. 010C3

190.0 312.225 38,,312 7,,8199 -0., 00987 192.0 327.6*5 130. 13C 7.,8003 -0. 971 194.0 343.426 102.,035 7,, 7811 -0. U0956

196.0 358.970 133,, 876 7

.

,7621 -0. 941 198.0 374.475 135,,734 7,,7434 -0., 00927

203.0 369.943 137, 520 7,,7250 -0. 00914

202.0 405.375 139..324 7,,7068 -0., 00901

20*. 420.771 111.,116 7. 6689 -u. 00889

206.0 436.131 112,,337 7,,6713 -0., 00677

208.0 451.456 114, 367 7,,6539 -0. 00665 210.0 466.747 lib.,427 7,,6367 -0.,00654 212.0 482.003 118. 176 7.,6197 -0. 0C844

214.0 497.226 119.,915 7,,6029 -0., 00834

216.0 512.415 121.,6 + 5 7,,5864 -0. 00824

218.0 527.571 123,,335 7,,5700 -0,,00615 220.0 542.695 125. 076 7.,5538 -0. 00606

222.0 557.766 126.,778 7.,5377 -0, 00797

22*. 572.8*6 128.,471 7,,5219 -0., 00789

226.0 587.67* 130.,156 7,,5062 -0., 00782

228.0 602-871 131. 833 7,, 4906 -0., 00774

2 33. 617.836 133..531 7,,4752 -0., G07b7

232.0 632.772 135.,162 7,,4599 -0.,00761

23*. 647.676 136.,315 7,, 4448 -0.,00754 236.0 662.551 138. 460 7.,4297 -0. 00748

238.0 677.395 140.,0 38 7,,4148 -0., 00742 2*0.0 692.210 1*1., 729 7,,4000 -0. 00737

109
METHANE 1S0CH0RE 23.0 MOL/L

TtK P ,BftR dp/:d OP/OT 02P/DT2

1*6.0 i3 .115 3G 355 9 55o* -a. 02359

1*8.0 + 2 181 32 7ib 9. 5099 -0. C2293

150.

Q

bl 156 15 1 + 3 9 *6 + 7 -o. C2226

152.0 80 u*l 37 *38 9. *208 -0. 02165

15*. 98 839 19 3J2 9 37 81 -0. 02105

156.0 117 55* 32 036 9. 336b -c. 020*6

158.0 136 18b 3* 3*3 9. 29b2 -0. C1989

160.0 15* 739 9b 57* 9. 2570 -o. C1935

162.0 173 215 93 71U y 2188 -0, C1862

16*. 191 615 no 953 9. 1817 -0. 01831 166.0 209 9 + 2 133 122 9 1*55 -0. 01783

163.0 228 .198 135 251 9. 110* -0. 01736

170.0 2*6 38* 137 378 9 C761 -0. 01691 172.0 26* 5C3 U9 +76 9. 0*27 -0. 016*8

17*. J 282 55b 111 >55 9. 0101 -0 01b07

176.3 300 .5** 113 615 8 978 + -0. 01568

178. 318 i*7\i lib 659 8 9*7* -0. 01530 180.0 336 33* L17 636 i 9172 -0 01*9*

182.0 35* 139 119 b 3b 3 3877 -0. 01*59

13*.

3

371 ,885 131 691 3 8588 -0. 01*26 186.0 389 575 123 o71 8 8306 -0. 139* 138.0 *07 2U3 125 o37 8 8031 -0. 01363

190.0 *2* 788 127 539 8 7761 -0. 0133*

192.0 **2 313 129 528 8 7*97 -0. 01307

19+. *59. 787 151 *5* 8. 7238 -J. 01280

196. k77 209 133 ,367 3 6985 -0 01255

193.0 *9* 561 1>5 258 8 6736 -0 01230 200.0 511 .90* 1 37 157 6 6*93 -0. 01207

202.0 529 .178 139 036 8 6253 -o. 01185

20*. 5*6 *05 1 + m a t018' -0. 0116*

206.0 563 58b 1 + 2 759 8 5788 -0, on**

208.0 580 721 1 + * 635 8 6561 -0. 0112*

210.0 597 .810 l*b **1 8 5338 -0 01106 212.0 61* 856 1 + 6 267 8 5118 -0 01088

21*. 631 858 150 33 8. -902 -0. 01072 216.0 6*8 817 151 890 8 *69u -0 01056

218.0 665 73* 153 6 39 3 **80 -0. 010*0 220.0 682 609 155 + 78 8 *273 -0 01026 222.0 699 . * H + 157 259 8 *070 -a. 01012

110
METHANE ISOCHORE 24.0 MOL/L

T,K P ,BAR OP/OO OP/DT 02P/0T2

136.0 10 ,481 Ul. 550 11.1141 -0. 03823

134.0 32 ,634 134 112 11.0391 -0. 03681

L4U.0 54 639 136 o27 10.9668 -0. C3547

142.0 76 503 139 138 10.8972 -0.03419

144.0 98 229 111. 556 10.8300 -0.03296

146.0 119 ,824 113 973 10.7653 -0. 03180

143.0 141 292 116. 3 50 1U.7028 -0. 03070

150.0 162 .637 lie 719 10.6424 -0. 02964

152.0 183 863 121 052 10.5842 -0. 02364

154.0 204 975 123. 359 10.5278 -u. 02769

156.0 225 976 125. 6 + 2 10.473h -0. 02d7R

158.0 246 670 127 9J3 10.4207 -0. 02591 160.0 267 660 130. 1+1 10.36 37 -0. 02509 162.0 288 ,350 132 358 10. 3203 -0. 02430 164.0 308 942 134 555 10. 2725 -0. 2 355

166. 329 440 136 753 10.2261 -0.02284

163.0 349 .847 138. 892 10.1811 -0. 02216

170.0 370 166 1+1 34 10. 1374 -0. 02152

172.0 390 398 1 + 3. 158 10.0950 -0. 02090

174.0 410 547 1 + 5 2j6 10. 0538 -0. 02032

176.0 430 ,614 147 358 10.0137 -0.01976

178.0 450 602 1 + 9. 435 9.9747 -0.01923

180.0 470 514 151. 498 9.9368 -0. 01872

182.0 490 350 153. 5 + 6 9.8999 -0.01823

184.0 510. 114 155. ?31 9.8639 -0.01777

186.0 529 806 157. 632 9. 8287 -0.01733

188.0 549 429 159. 611 9.7945 -0. 01691

190.0 568 985 151. o37 9.7bll -0. 1652 192.0 588 474 163, 592 9.7284 -0. 01613

194.0 607 899 165. 565 9.6965 -0.01577

196.0 627. 261 lo7. 527 9.6653 -0. 01543

198.0 646 561 169 478 9.63+8 -0.01510

200.0 665 800 171. + 18 9.60+9 -0.01+78

202.0 684 9B1 173. 348 9.5757 -0. 01448

METHANE ISOCHORE 25.0 MOL/L

T,K P,BAR OP/JD OP/DT 02P/DT2

126.0 5.050 128. 311 1 2.8973 -0. 05794

128.0 30.730 130, 935 12.7840 -0 05544

130.0 56.189 133. 522 ]12.6755 -a. 05308

132.0 81.435 136 073 12.5715 -0, 05086

13 + . 106.478 138. 5 92 12.4719 -0. + 87t 136.0 131.326 141. 079 112.3764 -0. 04578

138.0 155.986 1 + 3. 537 2.2848 -0. 0+490

140.0 180.467 1 + 5. 966 1.2.1967 -0. 04513

142.0 204.776 1 + 8. 3o9 12. 1122 - 0. 04145

144.0 228.918 150. 746 ] 2.0309 -0. C3987

146.0 252.901 153. 39 1.1.9526 -0. C3637

148.0 276.731 155, + 29 1.3773 -3. G3695

150.0 300.412 157. 737 1ul. 8048 -o. 0356C 152.0 323.952 16 U24 11.7349 -0. 03432 154.0 347.354 152. 231 1LI. 6675 -0 03311

156.0 370.623 164 538 11.6024 -0. 03196

158.0 393.765 166 758 1.1.5396 -0. G3087

160.0 41b. 763 166 379 1 1.4789 -0. C2984

162.0 439.682 171 174 LI. 42 2 -0. 02886

164.0 462. 4o5 173 352 LI. 3634 -0. 02793

166.0 485.137 175. 515 i.1.3085 -0. 027C4

163.0 507.700 177 6o3 LI. 2552 -0, 02620 170.0 530.159 179. 736 1.1. 2036 -0. 2 540 172.0 552.515 HI 316 LI. 1536 -0. 02464

17 + . 57+. 774 184 022 1.1. 1050 -0. C2392

17o.O 596.937 15b 116 .1.0579 -0. 2 323 178-0 619.006 138 136 LI. 0121 -o. 02257

180.0 640 .98b 130 264 l0.967u -0 C2195

182.0 662.878 132. 321 LO.92+3 -0 02136

184.0 684.684 134 357 .0.8821 -0 2 08C

111
MtTHANE ISOCHORE 26.0 HOL/L

T,K P,,aaR DP/OO OP/OT D2F/0T2

116.0 10,,520 161. 524 It. 91)1 -0. Cb42G 117.0 25.,398 1:>2. 320 14. 8360 -0. G8213

118.0 40,,193 15<*. 108 14. 7549 -0. 08012 119.0 54,.906 155. 337 It, 6757 -0. 07818

120. 69,.645 l30. 6 58 14, 5985 -0. C7o30 121.0 84. 106 1:>7. 921 14. 6231 -0. 7 4"*8 122.0 98,,592 139. 177 14, 4495 -D. 07272

123.0 113,,006 170. 425 14. 3776 -0. 07102

12*. 127,,348 171. o55 14.,3075 -0. 0o936

125.0 141, 621 172. 899 14. 2389 -0. 06776 12o.O 155,,826 171*. 125 14., 1719 -0. 06621 127.0 169,,965 1,'5. 3*5 14, 1064 -0. 0o471

128.0 184,,039 ire. :>58 1«*.,0425 -0. 06326

129.0 198.,050 177. 765 13.,9799 -0. 06184

130.0 212.,000 173. 966 13. 9138 -0. 06G47

131.0 225,,888 130. 151 13.,8590 -0. 05916

132.0 239.,718 131. 350 13. 8005 -o. C6786

133.0 253,.490 182,,5 S3 13,,7432 -u. 05661 134.0 267,,205 133. 710 13.,6872 -0. 05539

135.0 280.,865 134. 333 13,,6324 -0. 051.22 136.0 294.,470 136. G+9 13. 5736 -o. 05307

137.0 308,.023 137..211 13,,5263 -0. 05196

138.0 321,,523 138. 36 8 1 3.,4748 -0. 05089

139.0 334,,973 139,,520 13,,4245 -0. C4984

1*0. 348.,372 130. 567 13. 3752 -0. 04882

1 1*1.1] 361,.723 191. 3 09 13,, 3268 -0. 04784

11*2.0 375,,026 192,,9*7 13,,2795 -0. 04688

143.0 388,.283 194. 030 13,,2331 -0. 04594

1<*+ 401,.493 H5, 2 09 13. 1876 -0., 04604

1<*5.0 4l4,,658 19b. J3<* 13,,1430 -0,. 04416

li*6.0 427,,779 1)7. 454 13,,0993 -0, 04330

147.0 440,.857 198.,571 13,,C664 -c., 042<*

7

1%8.0 <*53,,892 199. 633 13,,0143 -0.. 04166 149.0 466,,8bo 20 0,.792 12,,9731 -0.. 04087

150.0 i*79,,838 201,.397 12,,9326 -0,. 04U1 151.0 492,.751 2]2., 998 12,,8928 -0. C3936

152.0 505,.624 204,,095 12,.8539 -0., 03863

153.0 518,,459 2J5,,199 12,.8156 -0. 379 3 15».0 531..256 20b,,230 12 ,7780 -0,, 03724

155.0 544..015 207. 357 12,,7411 -o. 03657 156.0 556,.738 208,,i*50 12,,7048 -0., 03592 157.0 569.,425 Zi^i,.531 12,,6692 -0., 03a29

158.0 532,,0 77 210.,6)8 12.,6343 -0, 031.67 159.0 594.,694 211. 632 12., 5999 -0. 034C7

160.0 607,.277 212,,753 12.,5b51 -0,, 0331*9 161.0 619 ,826 213,,821 12.,5329 -0.. 03292

162.0 632 ,343 214,, 335 12,,5003 -0. 03236

163.0 644.,827 215, 947 12,, 4682 -o. 03182

164.0 657,.279 217,, 007 12,,4366 -0. 03130 lo5.0 669.,701 218,.053 12,,4056 -0. 03078

166.0 682,,091 219,, 116 12,,3751 -0.,03029 167.0 694,.451 220. 157 12., 3450 -0.,02980

112
METHANE ISOGHORE 27. J MOL/L

T,K P ,BAR OP/OD OF/OT D2P/0T2

105.0 13,.940 230,,236 17,,3004 -0.,12219 106.0 31,,180 201,,+75 17,, 1799 -0. 11661

107.0 48..3U1 212,,657 17,, 0626 -0.,11556 108.0 65,.307 20 3. 834 16.,9 + 88 -0. 11242

109.0 82,,200 2:5., J 5 16,,8379 -0.. 10940

110.0 98,,983 206,,170 lb,,7299 -0. 10648

111.0 115, 661 207.,329 16,,6249 -0., 1 36 7 112.0 132,,234 208. + 34 lc,,5226 -0. 10096

113.0 146,,707 209.. o33 16,,4229 -0,. 09634

114.0 165,.081 210.,7 T 7 lo.,3259 -0., C9^81

115.0 181,.359 211,,916 16,,2313 -D.,09337 116.0 197,.544 213, 050 lo.,1391 -0. 09101

117.0 213,.638 214,.130 16,,0492 -0. 08673

119.0 229,.643 215..306 15,,9616 -o. 08653 119.0 245,,562 216,.4 27 15,,8762 -0. 844 120.0 261,,396 217,. 544 15,,7928 -0. 08234

121.0 277,,148 218,.657 15.,7115 -0. 08035

122.0 2 92,.820 219. 757 15. 6321 -o. 07842

123.0 308,,413 220.,872 15,,5545 -0.. 07655

124.0 323,,930 221. 974 15,,4790 -0. 07+75

125.0 339,.372 223.,072 15,,4051 -0. 07300 126.0 354. 741 224. 156 15. 3329 -0,,07131 127.0 370,,038 225.,257 15,.2625 -0..06967 128.0 385,,266 226. 3+5 15.. 1936 -0., C6808

129.0 400,,426 227. + 29 15.,1263 - 0. C6654

130.0 415. 519 228.,511 15,,0605 -0.,06505 131.0 430,,547 229. 589 14,,9962 -0,.06 36 132.0 445,,512 230. 5 55 14.,9333 -0.. 06220

133.0 460.,414 231. 737 14,,8718 -0.. 06084 134.0 475,,256 232. 807 1 + ,,8116 -0.. C5952 135.0 490,,036 233. 873 14,,7527 -0. 05624

136.0 504.,762 234. 938 14. 6951 -0. 05700 137.0 519.,429 235. 339 1 + ,,6387 -0. 05579

138.0 534,,040 237. 058 14.,5835 -0.. 05462 139.0 548, 596 238. 114 14. 5294 -o. 05349

140.0 563,,099 239. 158 14,,4765 -0., 05239

141.0 577,,549 2*0. 220 14.,4247 -0. 05132

142.0 591,,948 2+1.,2a9 14,,3739 -0.. 05028

143.0 606. 297 2+2. 316 14. 3241 -0. + 927 144.0 620,,597 243. 351 14.,2753 -0. 04829

145.0 634,,846 2+4. 403 14.,2275 -0..04733 146.0 649,,052 2 + 5, + + 4 14.,1806 -0. 04641

147.0 663. 210 2 + 6. 432 14. 1347 -0.,04550 148.0 677.,322 1^7. 518 14.,0896 -0., 04 + 63 149.0 691,,369 2 + 8. 552 14., + 54 -0.. + 376

113
METHANE I50CH0RE 27.5 MOL/L

T,K p BAR DP/OD OP/OT 02P/OT2

99.0 11 423 221. 454 16. 6804 -0. 14645

100. 30 030 222 5 33 18. 5342 -0. 14406

101.0 48 493 223. 6J9 18. 3922 -0. 13986

102.0 66 816 224 680 18 2544 -0. 13582

103.0 85 003 225 7 + 8 18 1205 -0. 13194

104.0 103 056 226 813 17. 9904 -0. 12 821 105.0 120 .985 227 875 17. 6640 -0. 12461

106.0 138 787 228 933 17 7412 -0. 12115

107.0 156 469 229 988 17 6217 -0. 11782

108.0 174 032 231 0+1 17 6055 -0. 11461 109.0 191 481 232 090 17 3924 -0. 11151 110.0 208 .818 ^Z3 137 17 2824 -0 10853

111.0 226 04b 234 161 17 1754 -a. 10565

112.0 243 169 235 223 17 C711 -0. 1C287

113.0 260 190 256 2o2 Id 9o96 -c. 10019

llt.O 277, 110 237 238 lb. 8707 -0. 09760 115.0 293 932 238 ,333 16 7744 -0. 09511

119.0 310. 659 239 3s5 16 6805 -0. 09269

117.0 327 29*. 2+0 395 lo 5889 -0. 09C36

116.0 343 838 2-fl + 23 Id 4997 -0. 08811 119.0 360 29h 2 + 2 4 + 9 16 4127 -0. 06593

120.0 376 664 2 + 3 473 16 3276 -0. 06383 121.0 392 950 2+4 + 95 lb 2450 -0. 08179

122.0 409 154 245 515 16 1642 -0. 07982 123.0 425 279 2 + b 534 16 0853 -0. 07792

124.0 441 .326 2 + 7 551 16 C083 -0. 07608

125.0 457 296 2+8 566 15 9332 -0. 07429 126.0 l»73 .193 249 579 15 6597 -0. 07256

127.0 489 Olo 250 p}l 15 7880 -0. 07089

126.0 504 769 251 601 15 7180 -0. 06927

129.0 520 453 252 510 15. 6495 -0. 06770 130.0 5 36 .069 25.3 ol7 15 5825 -0 06618

131.0 551 618 254 623 15 5171 -0. C6470

132.0 567 lu3 255 628 15 45 31 -o. 06327 133.0 582 ,525 256 .631 15 3906 -0. 0618e

134.0 597 885 257 632 15 3293 -0 C6C54

135.0 613 184 258 o33 15 2695 -0 C5923

136.0 628. 424 259 o32 15 2109 -0. 05797 137.0 643 .607 250 .630 15 1535 -0 05674

138.0 658 732 2ol 627 15 G974 -0. 05555

139.0 673 802 262 o23 15 0424 -0 C5439

1^0.0 688 .817 263 ol8 14 9886 -o. C5327

114
UlTHANE ISOCHORE 28.0 MOL/L

T,K P ,BAR OP/ JD OP/DT D2P/DT2

93.0 11 .234 2 + 3 8/0 20 1629 -0. 17994

9+.0 31 308 244 7/6 19 9856 - 0. 17429

95.0 51 .207 2 + 5 o37 19 8142 -0 16888

96.0 70 .938 2 + 6 595 19 6479 -0. 16 369 97.0 90 505 2 + 7 .534 19 48o6 -0. 15 871 98.0 109 913 2+8 413 19 3305 -0. 15 393 99.0 129 .167 249 323 19 1788 -0. 14934

100.0 148 272 230 233 19 0317 -0 1+493

101.0 167 .232 251 .1 + 3 18 8889 -0 14069

102.0 186 051 252 054 18 7503 -0. 13662 103.0 204 734 252 965 18 6156 - . 13270 10^.0 223 284 253 8/6 16 4648 -0. 12893

105.0 241 .705 254 738 18 3577 -0. 12531

106.0 260 .000 255 ,/JO 18 2342 -0. 12162

10/. 278 174 256 613 18 1140 -0. 11846

108.0 296 230 257 526 17 9972 -0. 11522

109.0 314 170 25 8 + + 17 8836 -0. 11210

110.0 331 998 259 354 17 7730 -o. 1J909

111.0 349 717 23 258 17 6654 -0 10619

112.0 367 329 261 133 17 5606 -0, 10339

113.0 384 639 252 IB 17 4586 -0. 10069

114.0 402 .247 2o3 014 17 3592 -0. 09808

115.0 419 558 2a3 930 1/ 2624 -0. 09556

116.0 436 773 264 5 + / 17 1680 -0. C9314

117. 453. 895 255 /64 17. 0761 -0. 09079

118.0 470 926 266 631 lo 9864 -0. 08852

119.0 487 668 257 ,599 lb 8990 -0. Q8o33

120.0 50*. 725 268 517 16 8137 -0. 8+21 121.0 521 497 2o9 + 35 16 7306 -0. 08216

122.0 538 186 270 354 16 6494 -0. 08018 123.0 554 796 27 1 2/4 lb 57 2 -0. 07826

124.0 571 327 27 2 194 lo. 4928 -0. 07641 125.0 587. 782 273 114 16. 4173 -0. 07461

126.0 604 163 274 035 16 3436 -0. 07267 127.0 620 47C 274 956 lo 2716 -0 07119

128.0 636 706 2/5 8/7 16 2012 -0, 0o956 129.0 652 873 2/6 799 lo. 1325 -0. 06798

130.0 668 972 277 .721 16 0652 -0. 06645

131.0 685 004 276 6 + 3 15 9995 -0. C6 + 96

115
METHANE ISOCHORE 28.3 MOL/L

T,K Pi,BAR DP/ID OP/OT D2P/OT2

96.0 200,,9b/ zrz. 049 20. 0519 -0. 16227

97.0 220,,939 27 3. 7ib 19. 6921 -0. 1p732

93.0 240,,753 274. 437 13. 7372 -0. 15258

99.0 260,,i»lb 275. 134 19. 5869 -0. 1*802

1QO.0 279,.929 275., 3)5 19. 4411 -0. 14364

101.0 299,,299 27c. 6 12 19. 2996 -J. 13943

102. 318,.529 277,,333 19.,lb22 -G. 13 539 103.0 337. 624 278. 039 19. 0288 -0. 13150 104.0 356,.5o8 278,,339 18. B991 -0., 12776

105.0 375,,424 279. 534 18. 7732 - 0. 12416

106.0 394,,135 210., 332 18.,b508 -a., 12G69

107.0 412,,72b 231. 035 18. 5318 -o. 11735

lOti.O 431,.200 231. 342 Id,,4160 -0. 11414

109.0 449,.560 232. o)3 18. 3035 -0. 11104

110.0 467,.oGtt 233.,338 18,,1939 -0., 10806 111.0 485,,9^8 234. 137 18. 0873 -0,, 10518

112.0 503,,984 234, 339 17,,9835 -0, 10240 113.0 521,.916 235. 635 17,,8825 -0,, 09972

114.0 539,,7 + 9 236,, <:'. 17.,7840 -0.,09714 115.0 557,.465 237,,2*6 17,,fc8d2 -0,, 09464

116.0 575,,126 238, 032 17,,5947 -0,, 09223

117.0 592 .675 236,, 821 17,,5037 -0,, G8991 118.0 610,.135 239,,613 17,,41,9 -0,, 0B7t6

119.0 627,.506 290,,4)9 17,,3283 -0.,0 8549

120.0 644,,792 231,,2)7 17,,2439 -0,, G8338

121.0 661 .994 232,, J)6 17,, 1615 -0,, 0O135

122.0 679,.lit 292,,812 17. 0812 -0., 07939

123.0 69o,.157 233,.619 17,,0027 -0,, 07749

METHANE ISOCHJRE 29.0 MOL/L

T,K P .BAR DP/JO DF/DT D2P/OT2

103.0 482,,144 2 3 9 . 7 19. 3503 -0. 12817 104.0 501,,430 299. 619 19.2239 -0. 12-5?

105.0 520,,593 3 0.177 19.1012 -0. 12101

106. 539, 634 300. 7+2 16.9819 -0. 11763 107.0 558,.558 301. 317 18. 8659 -0. 11437

108.0 577,,3b7 331.3 99 10.7531 -0. 11124 109.0 59o,.065 3)2.438 18.6434 -0. 10822 110.0 614,,655 3)3. 03b 13. 5366 -0. 1053G 111.0 633,,139 3J3.6 30 18.4327 -0. 10250 112.0 651,.521 3)4.3)2 18.3316 -0. 09979

113.0 669,,8u3 3)4.921 18.2331 -0.09718

114.0 687.,988 335. 5+6 18.1372 -0. 09466

116
Table 11. Calculated P(p) isotherms

The following pages give P(p) isotherms, as computed by the equation of state (6).

The third column DP/DD is the isotherm slope (9P/op) in units of the bar and mol/-t. The

fourth column DP/DT is the isochore slope (3P/ST) in units of the bar and kelvins. Remaining columns validate the analytical expressions used to compute derivatives of functions composing the equation of state.

These tables show that BP/^o is non-negative, and that it increases monotonically

with density to pressures about twice those used for adjusting the equation of state.

117
METHANE ISOTHERM 95.0 DEG. K MOL/L P.BAR DP/DD OP/OT XB DXB/OO xc DXC/DD xo OXD/OO

27.

8

3.195 234.390 19.6246 0.001 0.063 -0.003 -0.253 -0.000 -0.016

27.9 26.919 240.069 19.7214 3.007 0. 063 -0.029 -0.26 -0.002 -0.014

26.0 51.207 245.687 19.8142 0.013 0.063 -0.055 -0.268 -0.003 -0.013

28. 1 76.054 251.229 19.9030 0.020 0.063 -0.082 -0.276 -0.004 -0.012

28.2 101.450 256.682 19.9878 0.026 0.063 -0.111 -0.281* -0.005 -0.010

28.3 127.386 262.030 20.0684 0.032 0. 06<4 -0.139 -0.29 3 -0.006 -0.009

28.<4 153.852 267.256 20.11*1*7 0.039 0. 064 -0.169 -0.302 -0.007 -0.008

METHANE ISOTHERM 100.0 DEG. K

MOL/L P,6AR DP/DO OP/DT XB OX8/D0 XC DXC/OD XD OXO/DO

27. 4 8. 059 216.886 18.4249 0.002 0.062 -0.008 -0.225 -0.001 -0.017

27.5 30.030 222.533 18.5342 0.008 0.062 -0.031 -0.232 -0.002 -0.016

27.6 52.565 228.159 18.6403 0.015 0. 062 -0.054 -0.239 -0.004 -0.014

27.7 75.661 233.753 18.7i.32 0.021 0.062 -0.079 -0.246 -0.005 -0.013

27.3 99.314 239.304 18.8428 0.027 0.063 -0.104 -0.25 3 -0.006 -0.012

27.9 123.520 244. 8C1 18.9390 0.033 0.C63 -0.129 -0.260 -0.007 -0.010

28.0 148.272 250.233 19.0317 0.01*0 0.063 -0.156 -0.268 -0.006 -0.009

28.1 173.564 255.585 19.1210 0.046 0.063 -0.183 -0.276 -0.009 -0.008

28.2 199.386 260.845 19.2066 O.f 52 0.C63 -0.211 -0.284 -0.010 -0.007

28.3 225.729 265.995 19.2866 0.059 0.064 -0.240 -0.29 3 -0.011 -0.006

28. 4 252.581 271.022 19.3667 0.065 0. 064 -0.269 -0.30 2 -0.011 -0.005

28.5 279.929 275.905 19. 4411 0.071 0. 064 -0.300 -0.311 -0.012 -0.004

28.6 307.757 280.628 19.5115 0.078 0.064 -0.332 -0.321 -3.012 -0.304

28. 7 336.048 285.169 19.5779 0.C84 0.064 -0.364 -0.331 -0.012 -0.003

28.8 364.784 289.506 19.6403 0.091 0.064 -0.398 -0.341 -0.013 -0.002

METHANE ISOTHERM 105.0 DEG.

MOL/L P.BAR OP/DO DP/DT XB DXB/OD XC DXC/OD XD OXO/DO

27.0 13.940 200.286 17.3004 3.004 0.C60 -0.013 -0.20 2 -3.001 -0.019

27.1 34.245 205. 805 17.4184 3.013 0.061 -0.034 -0.20 7 -0.003 -0.317

27.2 55.101 211.331 17.5338 3.016 0.C61 -0.055 -0.213 -0.005 -0.015

27.3 76.511 216.857 17.6466 3.022 0.061 -0.077 -0.219 -0.006 -0.014

27.4 98.472 222.374 17.7567 0.028 0.062 -0.099 -0.225 -0.007 -0.013

27.5 120.985 227.875 17.8640 0.035 0.062 -0.122 -0.232 -0.009 -0.011 27.6 144.047 233. 350 17.9686 0.041 0.062 -0.145 -3.239 -0.010 -0.010

27.7 167.654 238.790 18.0703 0.047 0. 062 -3.169 -0.24 6 -0.011 -0.009

27.8 191.803 244.184 18.1691 0.053 0. 063 -0.194 -0.253 -0.012 -0.008

27.9 216.489 249.521 18.2650 0.063 0. 063 -0.220 -0.260 -0.012 -0.007

28.0 241.705 254.788 18.3577 0.066 0. 063 -0.246 -0.26 8 -0.013 -0.006

28. 1 267.444 259.973 18.4474 0.072 0.063 -0.274 -0.276 -3.013 -0.005

28.2 293.696 265. 061 18.5338 0.079 0.063 -0. 302 -0.284 -0.014 -0.334

28.3 323.452 270.036 18.6170 0.085 0.064 -0.330 -0.29 3 -0.014 -0.003

28.4 347.699 274.883 18.6968 0.091 0.064 -0.360 -0.302 -0.015 -0.003

28. 5 375.424 279.584 18.7732 0.098 0.064 -0.391 -0.311 -0.015 -0.002

26.6 403.610 284.119 18.8461 0.104 0.064 -0.422 -0.321 -0.015 -0.001

28. 7 432.241 288.468 18.9155 0.110 0.064 -0.455 -0.331 -3.015 -0.001

28.8 461.297 292.610 18.9811 0.117 0.064 -0.489 -3.341 -0.015 -0.000 28.9 493.756 296.521 19.0431 0.123 0.064 -0.523 -3.352 -0.015 0.300 29.0 520.593 300.177 19.1012 0.130 0.064 -0.559 -0.36 3 -0.015 0.001 29.1 553.781 303.550 19. 1554 0.136 0.064 -0.596 -0.374 -0.015 0.001

118
METHANE ISOTHERM 110.0 DEC K

OL/L P.BAR OP/DD OP/DT XB OXB/OD XC DXC/OD XO DXD/OO

26.5 2.608 179.1*30 16.1222 0.001 0.059 -0.002 -0.176 -0.000 -0.022

26.6 20.816 18i». 725 16.21*79 0.006 0.059 -0.020 -0.181 -0.002 -0.020

26.7 39.551* 190.052 16.3716 0.012 0. 059 -0.038 -0.186 -0.001* -0.018

26.8 58.827 195.1*05 16.1*931 0.018 0.060 -0.057 -0.191 -0.006 -0.017

26.9 78.636 200.779 16.6126 0.021* 0.060 -0.076 -0.196 -0.007 -0.015

27.0 98.983 206.170 16.7299 0.030 0.060 -0.096 -0.202 -0.009 -0.011* 27.1 119.870 211.571 16.81*51 0.036 0.061 -0.116 -0.207 -0.010 -0.012

27.2 11*1.298 216.975 16.9579 0.01*2 0.061 -0.137 -0.213 -0.011 -0.011

27.3 163.265 222.376 17.0685 0.0i*9 0.061 -0.159 -0.219 -0.012 -0.010

27. i» 185.772 227.766 17.1767 0.055 0.062 -0.181 -0.225 -0.013 -0.009

27.5 208.818 233.137 17.2821* 0.061 0.062 -0.201* -0.232 -0.011* -0.008

27.6 232.399 238.1*79 17.3857 0.067 0.062 -0.228 -0.239 -0.015 -0.007

27.7 256.512 21*3.783 17.1*865 0.073 0.062 -0.252 -0.21*6 -0.C15 -0.006

27.8 281. 15** 21*9.038 17.581*7 0.080 0.063 -0.277 -0.25 3 -0.016 -0.005

27.9 306.318 251*. 232 17.6802 0.086 0.063 -0.302 -0.260 -0.016 -0.001* 28.0 331.998 259.351* 17.7730 0.092 0. 063 -0.329 -0.26 8 -0.017 -0.003

28.1 358.186 261*. 389 17.8630 0.098 0.063 -0.356 -0.276 -0.017 -0.002

28.2 38i». 872 269.325 17.9502 0.105 0.063 -0.381* -0.281* -0.017 -0.002

28.3 1.12.01*7 271*. ll*«* 18.03i*i* 0.111 0.061. -0.1*13 -0.293 -0.017 -0.001

28. i» 1*39.697 278.831 18.1157 0.117 0.061* -0.1*1*3 -0.302 -0.C18 -0.001

28.5 1*67.808 283.368 18.1939 0.121* 0. 061* -0.1*73 -0.311 -0.018 -0.000

28.6 i»96.365 287.736 18.2690 0.130 0.061* -0.505 -0.321 -0.018 0.000 28.7 525.31*9 291.911* 18.31*09 0.137 0.061* -0.537 -0.331 -0.017 0.001 28.8 55i..7i»l 295.881 18.1*095 0.11.3 0.061* -0.571 -0.31*1 -0.017 0.001 28.9 581*. 517 299.613 18.1*71.8 0.150 0. 061* -0.606 -0.35 2 -0.017 0.002

29.0 6H*. 655 303.086 18.5366 0.156 0.061* -0.61*1 -0.36 3 -0.017 0.002

29.1 61*5. 12"5 306.272 18.5950 0.162 0. 061* -0.678 -0.371* -0.017 0.002 29.2 675.898 309.11*3 18.61*97 0.169 0.061* -0.716 -0.386 -0.017 0.003

METHANE ISOTHERM 115.0 OEG.

MOL/L P.BAR OP/DD DP/DT XB DXB/OD xc DXC/DD XO OXD/DD

0.1 0.929 9.007 0.0085 0.026 -0.671. -0.075 2.022 -0.058 1.1.15 26.1 11.830 165.222 15.131*6 0.001. 0.057 -0.010 -0.159 -0.001 -0.023

26.2 28.605 170.271 15.2633 0.009 0.057 -0.026 -0.163 -0.001. -0.021

26.3 1*5.886 175.363 15.3901* 0.015 0. 058 -0.01*3 -0.167 -0.006 -0.019

26.1* 63.679 180.1*96 15.5158 0.021 0.058 -0.060 -0.172 -0.OO8 -0.018

26.5 81.986 185.665 15.6395 0.027 0.059 -0.077 -0.176 -0.009 -0.016

26.6 100.813 190.867 15.7615 0.033 0.059 -0.095 -0.181 -0.011 -0.015

26.7 120.161 196.098 15.8817 0.039 0.059 -0.113 -0.186 -0.012 -0.013

26.8 11*0.033 201.353 16.0001 0.01.5 0.060 -0.132 -0.191 -0.013 -0.012

26.9 160.1*32 206.628 16.1166 0.051 0. 060 -0. 151 -0.196 -0.011. -0.011

27.0 181.359 211.916 16.2313 0.057 0.060 -0.171 -0.202 -0.015 -0.009

27.1 202.815 217.212 16.31*1.0 0.063 0.061 -0.192 -0.207 -0.016 -0.008

27.2 221*. 802 222. 5C9 16.1*51*7 0.069 0.061 -0.213 -0.213 -0.017 -0.007

27.3 21.7.317 227.800 16.5631* 0.075 0.061 -0.231* -0.219 -0.018 -0.006

27.1* 270.361 233.078 16.6699 0.081 0.062 -0.257 -0.225 -0.018 -0.005

27.5 293.932 238.333 16.771*1* 0.087 0.062 -0.279 -0.232 -0.019 -0.001* 27.6 318.027 21.3.557 16.8766 0.093 0.062 -0.303 -0.239 -0.019 -0.001* 27.7 31*2.61*2 21.8.71.0 16.9765 0.100 0. 062 -0.327 -0.21*6 -0.020 -0.003

27.8 367.773 253.871 17.071*2 0.106 0.063 -0. 352 -0.253 -0.020 -0.002

27.9 393.1*11* 258.938 17.1695 0.112 0.063 -0.378 -0.26 -0.020 -0.001

28.0 1*19.558 263.930 17.2621. 0.118 0.063 -0.1+01* -0.26 8 -0.020 -0.001

28.1 1.1*6.197 268.833 17.3527 0.125 0.063 -0.1.31 -0.276 -0.020 -0.000

28.2 1*73.321 273.632 17.1.1.06 0.131 0. 063 -0.1.59 -0.281* -0.020 0.000 28.3 500.919 278.311 17.5258 0.137 0.06<( -0.1.88 -0.293 -0.020 0.001

28.1* 528.979 282.856 17.6083 0.11.1. 0. 061. -0.518 -0.302 -0.020 0.001 28.5 557.1*85 287.21.6 17.6882 0.150 0.061. -0.549 -0.311 -0.020 0.002

28.6 586.1.22 291.1.61. 17.7652 0.157 0. 061. -0.580 -0.321 -0 .020 0.002 28.7 615.772 295.1*89 17.8393 0.163 0.061. -0.613 -0.331 -0.019 0.002

28.8 61*5.513 299.299 17.9105 0.169 0.061* -0.61*6 -0.31*1 -0.019 0.003

28.9 675.621. 302.871 17.9787 0.176 0.061* -0.681 - . 35 2 -0.019 0.003

119
METHANE ISOTHERM 120.0 DEG. K

IOL/L P.BAR DP/DD DP/DT XB OXB/DD XC OXC/DD XD OXO/OD

0. 1 0.971 9.442 0.0085 0.052 -0.674 -0.144 2.022 -0.107 1.219

0.2 1.888 8.896 0.0174 0.001 -0.400 -0.003 1.012 -0.003 0.921 25.6 6.756 147.421 14.0313 0.002 0.055 -0.005 -0.140 -0.001 -0.025

25.7 21.734 152.153 14.2125 0.007 0. 056 -0.019 -0.143 -0.003 -0.024

25.8 37.189 156.938 14.3424 0.013 0.056 -0.033 -0.147 -0.006 -0.022

25.9 53.124 161.774 14.4711 0.019 0. 056 -0.048 -0.151 -0.008 -0.020

26.0 69.51.5 166.658 14.5985 0.024 0.057 -0.063 -0.15 5 -0.010 -0.018

26.1 86.457 171.589 14.7245 0.030 0. 057 -0. 079 -0.159 -0.011 -0.017

26.2 103.861. 176.564 14.8492 0.036 0.057 -0.095 -0.163 -0.013 -0.015

26. 3 121.771 181.581 14.9724 0.041 0.058 -0.112 -0.167 -0.014 -0.014

2b. 4 11.0.182 186.635 15.0943 0.047 0.059 -0.129 -0.172 -0.016 -0.013

26.5 159.099 191.724 15.2146 0.053 0. 059 -0.146 -0.176 -0.017 -0.011

26.6 178.528 196.844 15.3334 0.059 0.059 -0.164 -0.181 -0.018 -0.010

26. 7 198.1.69 201.991 15.4507 0.065 0.059 -0.182 -0.186 -0.019 -0.009

26.6 218.927 207.161 15.5664 0.071 0.060 -0.201 -0.191 -0.020 -0.008

26.9 239.902 212.347 15.6804 0.077 0. 060 -0.220 -0.196 -0.021 -0.007

27.0 261.396 217.544 15.7928 0.083 0.060 -0.240 -0.20 2 -0.021 -0.006

27.1 283.1.11 222.747 15.9034 0.089 0. 061 -0.261 -0.207 -0.022 -0.005

27.2 305.91.6 227.949 16.0123 0.095 0.061 -0.282 -0.213 -0.022 -0.004

27.3 329.001 233.143 16.1194 0.101 0. 061 -0.303 -0.219 -0.023 -0.003

27.4 352.571. 238.320 16.2245 0.107 0. 062 -0.326 -0.225 -0.O23 -0.002

27. 5 376.661. 243.473 16.3278 0.113 0.062 -0.348 -0.232 -0.023 -0.002

27.6 401.267 248.592 16.4291 0. 120 0. 062 -0.372 -0.23 9 -0.023 -0.001 27.7 426.381 253.667 16.5284 0.126 0. 062 -0.396 -0.246 -0.023 -0.000

27.8 451.999 258.687 16.6257 0.132 0. 063 -0.421 -0.253 -0.023 0.000 27.9 478.116 263.641 16.7208 0.138 0.063 -0.447 -0.26O -0.023 0.001 28.0 504.725 268.517 16.8137 0.145 0.063 -0.473 -0.26 8 -0.023 0.001

28.1 531.816 273. 300 16.9044 0.151 0. 063 -0.500 -0.276 -0.023 0.002 26.2 559.381 277.977 16.9929 0.157 0. 063 -0.528 -0.284 -0.023 0.002 28.3 587.408 282.532 17.0790 0.164 0. 064 -0.557 -0.29 3 -0.023 0.003 28.4 615.883 286.948 17.1627 0.170 0. 064 -0.587 -0.302 -0.022 0.003 28.5 644.792 291. 2C7 17.2439 0.176 0.C64 -0.618 -0.311 -0.022 0.003 28.6 674.118 295.290 17.3226 0.183 0. 064 -0.649 -0.321 -0.022 0.004

METHANE ISOTHERM 130.0 OEG. K

MOL/L P.BAR DP/DO OP/DT X9 OXB/OD XC DXC/OO XD DXO/OO

0.1 1.056 10.3C7 0.0085 0.105 -0.674 -0.266 2.022 -0.182 0.937

C.2 2.061 9.8C0 0.0173 0.054 -0.400 -0.126 1.012 -0.104 0.678 0.3 3.016 9.294 0.0264 0.020 -0.294 -0.044 0.671 -0.042 0.587 24.6 6.139 116.881 12.1560 0.001 0.051 -0.002 -0.110 -0.001 -0.031

24.7 18.031 120.954 12.2869 0.006 0. 052 -0.013 -0.113 -0.004 -0.029

24.8 30.332 125. 086 12.4171 0.011 0.052 -0.025 -0.116 -0.006 -0.027

24.9 43.050 129.275 12.5466 0.017 0. 052 -0.037 -0.118 -0.009 -0.025

25.0 56.189 133.522 12.6755 0.022 0. 053 -0.049 -0.121 -0.011 -0.023

25.1 69.756 137.825 12.8035 0.027 0. 053 -0. 061 -0.124 -0.014 -0.021 25.2 83.756 142.185 12.9308 0.033 0.054 -0.373 -0.127 -0.C16 -0.020

25. 3 98.195 146.600 13.0574 0.038 0.054 -0.086 -0.130 -0.017 -0.018

25.4 113.078 151.070 13.1831 0.043 0.054 -0.099 -0.133 -0.019 -0.016

25.5 128.410 155.593 13.3079 0.049 0.055 -0.113 -0.137 -0.021 -0.015

25.6 144.198 160.169 13.4319 0.054 0.055 -0.127 -0.140 -0.022 -0.014

25.7 160.446 164.796 13.5551 0.060 0.056 -0.141 -0.143 -0.024 -0.012

25.8 177.159 169.472 13.6772 0.065 0. 056 -0.155 -0.147 -0.025 -0.011

25.9 194.342 174.196 13.7985 0.071 0. 056 -0.170 -0.151 -0.026 -0.010

26.0 212.000 178.966 13.9188 0.077 0. C57 -0. 186 -0.155 -0.027 -0.009

26.1 230.137 183.779 14.0380 0.082 0.057 -0.201 -0.159 -0.C27 -0.008

26.2 248.757 188.633 14.1563 0.088 0. 057 -0.217 -0.163 -0.028 -0.007

26.3 267.864 193.524 14.2734 0.094 0.058 -0.234 -0.16 7 -0.029 -0.006

26.4 287.463 198.450 14. 3894 0.100 0.058 -0.251 -0.172 -0.029 -0.005

26.5 307.555 203. 4C8 14.5043 0.105 0.C59 -0.268 -0.176 -0.030 -0.004

26.6 328.145 208.392 14.6181 0.111 0.059 -0.286 -0.181 -0.030 -0.003

26.7 349.235 213.400 14.7306 0.117 0. 059 -0.304 -0.186 -0.030 -0.002

26.8 370.826 218.426 14.8419 0.123 0.060 -0.323 -0.191 -0.030 -0.001 26.9 392.920 223.465 14.9518 0.129 0. 060 -0.343 -0.196 -0.031 -0.001

27.0 415.519 228.511 15.0605 0.135 0. 060 -0. 362 -0.202 -0.031 0.000 27.1 438.623 233.558 15.1678 0.141 O. 061 -0.383 -0.207 -0.031 0.001 27.2 462.231 238.600 15.2737 0.147 0. 061 -0.404 -0.213 -0.030 0.001 27.3 486.342 243.630 15.3781 0.153 0. 061 -0.426 -0.219 -0.030 0.002 27.4 510.956 248.638 15.4811 0.160 0.062 -0.448 -0.22 5 -0.030 0.302 27.5 536.069 253.617 15.5825 0.166 0.062 -0.471 -0.232 -0.030 0.003 27.6 561.678 258.558 15.6824 0.172 0.062 -0.494 -0.239 -0.030 0.003 27.7 587.779 263.450 15.7807 0.178 0.062 -0.518 -0.246 -0.029 0.004 27.8 614.366 268.282 15.8772 0.184 0.063 -0.543 - . 25 3 -0.029 0.004 27.9 641.433 273.043 15.9721 0.191 0.063 -0.569 -0.26 -0.028 0.004 28.0 668.972 277.721 16.0652 0.197 0.063 -0.595 -0.268 -0.028 0.005

28.1 696.974 282.301 16.1566 0.203 0.063 -0.623 -0.276 -0.027 0.005

120
METHANE IS0THER1 140.0 DEC

MOL/L P.BAR DP/ DO OP/DT XB OXB/DD XC OXC/OO XD DXD/OO

0.1 1.140 11.167 0.0084 0.157 -0.674 -0.371 2.022 -0.238 0.743

0.2 2.233 10.693 0.0172 0.106 -0. 400 -0.230 1.012 -0.177 0.522 0.3 3.279 10.221 0.02 62 0.072 -0.294 -0.148 0.671 -0.129 0.440

0.4 4.278 9.71.9 0.0356 0.046 -0.237 -0.091 0.499 -0.088 0.398

0.5 5.229 9.275 0.0453 0.024 -0.199 -0.046 0.395 -0.049 0.376

0.6 6.132 8.799 0.0554 0.006 -0.173 -0.011 0.326 -0.012 0.364 23.6 14.850 92.1.69 10.4649 0.004 0.047 -0.008 -0.088 -0.003 -0.035

23.7 24.269 95.925 10.5908 0.009 0. 048 -0.017 -0.090 -0.007 -0.033

23.8 34.037 99.436 10.7164 0.014 0.046 -0.026 -0.092 -0.010 -0.031

23.9 44.158 103. 0C4 10.8418 0.019 0.048 -0.036 -0.094 -0.C13 -0.029

24.0 54.639 106.627 10.9668 0.024 0.049 -0.045 -0.096 -0.016 -0.027

24.1 65.485 110. 308 11.0915 0.028 0.049 -0.055 -0.099 -0.018 -0.025

21*.

2

76.703 114. 01.4 11.2159 0.033 0.050 -0.065 -0.101 -0.021 -0.023

2i*. 3 88.296 117.837 11.3399 0.038 0.050 -0.075 -0.10 3 -0.023 -0.021

24.4 100.272 121.687 11.4636 0.043 0.050 -0.085 -0.105 -0.025 -0.020

24.5 112.635 125.593 11.5869 0.048 0.051 -0.096 -0.108 -0.027 -0.018

24.6 125.392 129.556 11.7097 0.054 0.051 -0.107 -0.110 -0.028 -0.017

24.7 138.549 133.575 11.8322 0.059 0.052 -0.118 -0.113 -0.030 -0.015

2<*. 8 152.109 137.650 11.9542 0.064 0.052 -0.130 -0.116 -0.032 -0.014

24.9 166.080 141.780 12.0757 0.069 0.052 -0.141 -0.118 -0.033 -0.013

25.0 180. i»67 H.5.966 12.1967 0.074 0.053 -0.153 -0.121 -0.034 -0.011

25.1 195.275 150. 2C7 12.3173 0.080 0.053 -0.166 -0.124 -0.035 -0.010

25.2 210.510 154. 501 12.4373 0.085 0.054 -0.178 -0.127 -0.036 -0.009

25.3 226.177 158. 848 12.5567 0.090 0.054 -0.191 -0.130 -0.037 -0.008

25. 4 242.282 163.248 12.6756 0.096 0.054 -0.204 -0.133 -0.038 -0.007

25.5 258.829 167.698 12.7938 0.101 0.055 -0.218 -0.137 -0.038 -0.006

25.6 275.823 172.199 12.9115 0.107 0.055 -0.231 -0.14 -0.039 -0.005

25.7 293.270 176.748 13.0284 0.112 0.056 -0.246 -0.143 -0.039 -0.004

25.8 311.174 181.343 13.1447 0.118 0.056 -0.260 -0.147 -0.040 -0.003

25.9 329.540 185.984 13.2603 0.123 0.056 -0.275 -0.151 -0.040 -0.002

26.0 348.372 190.667 13.3752 0.129 0.057 -0.290 -0.155 -0.040 -0.001

26.1 367.675 195.390 13.4892 0.135 0.057 -0.306 -0.159 -0.040 -0.000

26.2 387.1.52 200.151 13.6025 0.141 0.057 -0.322 -0.16 3 -0.040 0.000 26.3 "07.706 204.947 13.7150 0.146 0.058 -0.339 -0.167 -0.040 0.001 26.4 1*28. 4i»2 209.774 13.8266 0.152 0.058 -0.356 -0.172 -0.040 0.002 26.5 1*1*9.662 214.629 13.9373 0.158 0.059 -0.373 -0.176 -0.040 0.002 26.6 471.369 219. 5C8 14.0471 0.164 0.059 -0.391 -0.181 -0.039 0.003 26.7 1.93.561* 224.406 14. 1560 0.170 0.059 -0.409 -0.186 -0.039 0.003

26.8 516.250 229.319 14.26 38 0.176 0. 060 -0.428 -0.191 -0.039 0.004

26.9 539.428 234.242 14.3707 0.182 0.060 -0.447 -0.196 -0.038 0.004

27.0 563.099 239.168 14.4765 0.188 0. 060 -0.467 -0.202 -0.038 0.005 27.1 587.262 244.092 14.5812 0.194 0. 061 -0.488 -0.20 7 -0.037 0.005 27.2 611.917 249.007 14.6848 0.200 0. 061 -0.509 -0.213 -0.037 0.005 27.3 637.063 253. 9C5 14.7873 0.206 0.061 -0.530 -0.219 -0.036 0.006

27. i» 662.697 258.778 14.8886 0.212 0.062 -0.552 -0.22 5 -0.036 0.006

27.5 688.817 263.618 14.9886 0.218 0.062 -0.575 -0.232 -0.035 0.006

121
METHANE ISOTHERM 150.0 DEC K MOL/L P,BAR DP/OO OP/OT X8 OXB/DO xc DXC/OO XD DXD/DO

0.2 2.405 11.577 0.0171 0.159 -0.400 -0.321 1.012 -0.231 0.413

0.4 (.632 10.693 0.0353 0.098 -0.237 -0.181 0.499 -0.162 0.302

0.6 6.682 9.810 0.0546 0.058 -0.173 -0.101 0.326 -0.106 0.265 0.8 8.556 8.931 0.0752 0.027 -0.138 -0.046 0.238 -0.055 0.251

1.0 10.255 8.062 0.0971 0.002 -0.114 -0.004 0.186 -0.005 0.248

22. 4 15. 442 67.547 8.7568 0.003 0.042 -0.005 -0.069 -0.003 -0.041

22.6 29.514 73.205 8.9927 0.012 0. 043 -0.019 -0.072 -0.011 -0.037

22.8 ''.738 79.070 9.2287 0.020 0.044 -0.034 -0.075 -0.018 -0.033

23.0 61.156 85.143 9.4647 0.029 0.045 -0.049 -0.078 -0.024 -0.029

23.2 78.809 91.428 9.7007 0.038 0.045 -0.065 -0.081 -0.029 -0.025

23. 4 97. 71(1 97.927 9.9366 0.047 0. 046 -0.082 -0.085 -0.034 -0.022

23.6 117. 994 104.640 10.1723 0.057 0.047 -0.099 -0.088 -0.038 -0.019

23.8 139.612 111.571 10.4076 0.066 0.048 -0.117 -0.092 -0.042 -0.016

24.0 162.637 118.719 10.6424 0.076 0.049 -0.136 -0.096 -0.045 -0.013

24.2 187. 114 126.087 10.8767 0.086 0. 050 -0.156 -0.101 -0.047 -0.011

24.4 213.086 133.673 11.1102 0.096 0.050 -0.176 -0.105 -0.049 -0.008

24.6 240.598 141.479 11.3428 0.106 0.051 -0.198 -0.110 -0.050 -0.006

24.8 269.692 149.501 11.5744 0.116 0.052 -0.220 -0.116 -0.051 -0.004

25.0 300.412 157.737 11.8048 0.127 0.053 -0.244 -0.121 -0.052 -0.002

25.2 332.801 166.163 12.0338 0.137 0.054 -0.269 -0.127 -0.052 -0.001

25.4 366.899 174.832 12.2613 0.148 0.054 -0.295 -0.133 -0.052 0.001 25.6 402.747 183.675 12.4870 0.159 0. 055 -0. 322 -0.140 -0.052 0.002 25.8 440.381 192.702 12.7109 0.170 D.056 -0.351 -0.147 -0.051 0.004

26.0 479.836 201.897 12.9326 0.182 0. 057 -0.381 -0.155 -0.050 0.005 26.2 521.150 211.242 13.1520 0.193 0.057 -0.413 -0.16 3 -0.049 0.006

26. 4 564.344 220.714 13.3686 0.205 0.058 -0.446 -0.172 -0.048 0.006 26.6 609.442 230.286 13.5830 0.216 0.059 -0.481 -0.181 -0.C47 0.007 26.8 656.462 239.923 13.7941 0.228 0. 060 -0.519 -0.191 -0.045 0.008

METHANE ISOTHERM 160.0 DEC K

MOL/L P.BAR DP/DD DP/DT XB OXB/00 XC oxc/oo XD OXD/OD

0.2 2.57 6 12.456 0.0171 0.211 -0.400 -0.400 1.012 -0.274 0.332

0.4 4.984 11.623 0.0351 0.151 -0.237 -0.261 0.499 -0.219 0.235

0.6 7.225 10. 794 0.0541 0.110 -0. 173 -0.181 0.326 -0.176 0.200 0.8 9.302 9.974 0.0741 0.080 -0.138 -0.125 0.238 -0.138 0.183

1.0 11.216 9.168 0.0952 0.055 -0. 114 -0. 083 0.186 -0.102 0.175

1.2 12.970 8.380 0.1174 0.033 -0.098 -0.050 0.151 -0.067 0.172 1.4 14.569 7.611 0. 1409 0.015 -0.085 -0.022 0.126 -0.033 0.173

21. 16.794 44.644 7.0785 0.001 0.036 -0.001 -0.052 -0.001 -0.048

21.2 26.152 48.966 7.2918 0.006 0.037 -0.012 -0.054 -0.010 -0.044

21.4 36.393 53.476 7.5062 0.016 0.036 -0.022 -0.056 -0.018 -0.040

21.6 47.555 58.176 7.7218 0.023 0.039 -0.034 -0.058 -0.026 -0.C36

21.8 59.676 63.068 7.9384 0.031 0.040 -0.046 -0.061 -0.033 -0.032

22.0 72.795 68.154 8.1561 0.039 0.040 -0.058 -0.063 -0.039 -0.029

22.2 86.951 73.437 8.3747 0.047 0.041 -0.071 -0.066 -0.044 -0.025

22.4 102.183 78.919 8.5942 0.056 0. 042 -0.085 -0.069 -0.049 -0.022

22.6 118.532 84.601 8.8144 0.064 0. 043 -0. 099 -0.072 -0.053 -0.019

22.8 136.037 90.485 9.0354 0.073 0.044 -0.113 -0.075 -0.057 -0.016

23.0 154.739 96.574 9.2570 0.082 0.045 -0.128 -0.078 -0.060 -0.014

23.2 174.680 102.869 9.4790 0.091 0. 045 -0. 1^4 -0.081 -0.062 -0.011

23.4 195.901 109.372 9.7015 0.100 0.046 -0.161 -0.085 -0.064 -0.009

23.6 218.443 116.084 9. 92M 0.109 0.047 -0.178 -0.088 -0.066 -0.007

23.8 242.349 123.007 10.1469 0.119 0.048 -0.196 -0.092 -0.067 -0.005

24.0 267.660 130.141 10.3697 0.128 0.049 -0.215 -0.096 -0.068 -0.003

24.2 294.419 137.487 10.5924 0.138 0. 050 -0.235 -0.101 -0.068 -0.001

24.4 322.669 145.046 10.8148 0.148 0.050 -0.256 -0.105 -0.068 0.001 24.6 352.451 152.816 11.0368 0.158 0. 051 -0.277 -0.110 -0.068 0.002

24.3 383.809 160.794 11.2582 0.169 0.052 -0.300 -0.116 -0.067 0.004

25.0 416.783 168.979 11.4789 0.179 0.053 -0.323 -0.121 -0.066 0.005 25.2 451.414 177.365 11.6987 0.190 0.054 -0.348 -0.127 -0.065 0.006 25.4 487.742 185.946 11.9175 0.201 0.054 -0.374 -0.133 -0.064 0.007 25.6 525.805 194.713 12.1352 0.212 0.055 -0.402 -0.140 -0.062 0.008

25.8 565.639 203.653 12.3514 0.223 0.056 -0.430 -0.147 -0.061 0.009

26.0 607.277 212.753 12.5661 0.234 0. 057 -0.460 -0.155 -0.059 0.009 26.2 650.749 221.992 12.7791 0.245 0.057 -0.492 -0.163 -0.057 0.010 26.4 696.082 231.349 12.99C2 0.257 0.C58 -0.526 -0.172 -0.055 0.010

122
METHANE ISOTHERM 170.0 DEC K

IOL/L P,BAR DP/DD OP/DT XB DXB/OD xc DXC/DD XD DXD/OO

0.2 2.746 13.330 0.0170 0.263 -0.400 -0.471 1.012 -0.307 0.270 0.4 5.333 12.543 0.0349 0.203 -0.237 -0.331 0.499 -0.264 0.184 0.6 7.764 11.762 0.0537 0.163 -0.173 -0.251 0.326 -0.230 0.153

0.8 10.039 10.990 0.0733 0.132 -0.138 -0.195 0.238 -0.201 0.137

1.0 12.161 10.235 0.0939 0.107 -0.114 -0.153 0.186 -0.175 0.127

1.2 14.134 9.499 0.1154 0.086 -0.C98 -0.120 0.151 -0.150 0.122 1.4 15.962 8.785 0.1379 0.068 -0. 085 -0.092 0.126 -0.126 0.120

1.6 17.649 8.092 0.1614 0.051 -0.076 -0.069 0.107 -0.102 0.119

1.8 19.200 7.419 0.1859 0.037 -0.068 -0. 049 0.093 -0.079 0.119

2.0 20.618 6.764 0.2115 0.024 -0.061 -0.032 0.081 -0.055 0.120 2.2 21.907 6.124 0.2383 0.013 -0. 055 -0.016 0.072 -0.030 0.123

2.4 23.069 5.499 0.2664 0.002 -C.050 -0. 003 0.064 -0.006 0.126

19. 4 24. 017 26.105 5.5047 0.001 0.029 -0.001 -0.037 -0.001 -0.052

19.6 29.536 29.105 5.6881 0.007 0.030 -0.009 -0.038 -0.011 -0.048

19.8 35.670 32.270 5.8735 0.013 0.031 -0.016 -0.040 -0.021 -0.044

20.0 '42.1*5 5 35.602 6.0608 0.019 0. 032 -0.025 -0.042 -0.029 -0.041

20. 2 49.923 39.106 6.2500 0.025 0.033 -0.033 -0.044 -0.037 -0.038

20. 4 58.109 42.782 6.4412 0.032 0. 034 -0.042 -0.045 -0.044 -0.035

20.6 67.047 46.636 6.6343 0.039 0.034 -0.051 -0.047 -0.051 -0.031

20.8 76.775 50.668 6.8293 0.046 0.035 -0.061 -0.049 -0.057 -0.028

21.0 87.327 54.881 7.0261 0.053 0.036 -0.071 -0.052 -0.062 -0.026

21.2 98.739 59.277 7.2246 0.060 0.037 -0.082 -0.054 -0.067 -0.023

21. 4 111.050 63.858 7.42 4 8 0.068 0.038 -0.093 -0.056 -0.071 -0.020

21.6 124.295 68.625 7.6266 0.076 0.039 -0.104 -0.058 -0.075 -0.017

21.8 138.512 73.562 7.8299 0.083 0.040 -0.116 -0.061 -0.078 -0.015

22.0 153.740 78.729 8.0346 0.091 0.040 -0.128 -0.063 -0.081 -0.013

22.2 170.017 84.068 8.2406 0.100 0.041 -0.141 -0.066 -0.083 -0.010

22. 4 187.380 89.600 8.4479 0.108 0.C42 -0.155 -0.069 -0.085 -0.008

22.6 205.870 95.328 8.6563 0.116 0.043 -0.169 -0.072 -0.087 -0.006

22.8 225.525 101.254 8.8657 0.125 0.044 -0.183 -0.075 -0.087 -0.004

23.0 246.384 107.378 9.0761 0.134 0.045 -0.199 -0.078 -0.088 -0.002

23.2 268.489 113.703 9.2872 0.143 0.045 -0.214 -0.081 -0.C88 -0.000

23. 4 291.879 120.229 9.4990 0.152 0.046 -0.231 -0.085 -0.088 0.001 23.6 316.594 126.959 9.7114 0.161 0.047 -0.248 -0.088 -0.088 0.003 23.8 342.676 133.894 9.9243 0.171 0.048 -0.266 -0.092 -0.087 0.004

24.0 370.166 141.034 10.1374 0.181 0. 049 -0.285 -0.096 -0.086 0.006

24.2 399.104 148.379 10.3508 0.191 0.050 -0.305 -0.101 -0.085 0.007 24.4 429.531 155.929 10.5642 0.201 0.050 -0.326 -0.105 -0.083 0.008

24. 6 461.489 163.684 10.7776 0.211 0.051 -0.347 -0.110 -0.082 0.009

2 "i.8 495.018 171.641 10.9908 0.221 0.052 -0.370 -0.116 -0.080 0.010 25.0 530.159 179.796 11.2036 0.231 0.053 -0. 393 -0.121 -0.078 0.011 25.2 566.950 188.146 11.4160 0.242 0. 054 -0.418 -0.127 -0.076 0.011 25.4 605.429 196.682 11.6277 0.253 0.054 -0.444 -0.133 -0.073 0.012 25.6 645.634 205.395 11.8387 0.264 0.055 -0.472 -0.140 -0.071 0.012

25.8 687.598 214.275 12.0488 0.275 0.056 -0.500 -0.147 -0.068 0.013

123
METHANE ISOTHERM 180.0 DEG. K OL/L P.BAR OP/OD OP/DT XB OXB/DD xc DXC/DD XO OXD/DD

0.5 7.009 13.085 0.0440 0.234 -0.199 -0.349 0.395 -0.285 0.129

1.0 13.095 11.275 0.0930 0.159 -0. 114 -0.215 0.186 -0.232 0.093 1.5 18.305 9.588 0.1470 0.112 -0. 080 -0.142 0.116 -0.189 0.082 2.0 22.705 8.034 0.2063 0.077 -0.061 -0.094 0.081 -0.149 0.079 2.5 26.358 6.594 0.2709 0.050 -0.048 -0.059 0.060 -0.109 0.078

3. 29.316 5.256 0. 31*12 0.028 -0. 039 -0.032 0.046 -0.070 0.080 3.5 31.630 it.OH 0.4178 0.010 -0. 032 -0.012 0.037 -0.029 0.083

17.5 36.109 12.746 4.0606 0.006 0. 021 -0.006 -0.024 -0.014 -0.048

18. 43.599 17.343 4. <»278 0.017 0.023 -0. 019 -0.027 -0.036 -0.041

16.5 53.591 22.770 "..8110 0.029 0.025 -0.033 -0.030 -0.055 -0.036

19.0 66.519 29.098 5.2109 0.042 0. 027 -0. 049 -0.034 -0.072 -0.030

19.5 82.849 36.385 5.6271 0.056 0. 030 -0.067 -0.038 -0.C85 -0.025

20.0 103.073 ".<., 68U 6.0590 0.071 0.032 -0.087 -0.042 -0.096 -0.019

20.5 127.708 54.036 6.5058 0.088 0.034 -0.109 -0.046 -0.105 -0.014

21 .0 157.291 64. 477 6.9662 0.105 0.036 -0.133 -0.052 -0.111 -0.009

21.5 192.372 76.037 7.4390 0.124 0.038 -0. 160 -0.C57 -0.114 -0.004

22.0 233.519 88.742 7.9227 0.144 0. 040 -0.191 -0.063 -0.115 -0.000

22.5 281.309 102.616 8.4160 0.164 0. 043 -0.224 -0.070 -0.114 0.004

23. 336.33'* 117.686 8.9172 0.186 0.045 -0.261 -0.078 -0.111 0.007 23.5 399.198 133.973 9.4247 0.209 0. 047 -0. 302 -0.087 -0.107 0.010 24.0 470.514 151.498 9.9368 0.233 0. 049 -0.348 -0.096 -0.101 0.012 24.5 550.903 170.268 10. 4517 0.258 0. 051 -0.399 -0.108 -0.095 0.014

25.0 6140.986 190.264 10.9676 0.284 0. 053 -0.456 -0. 121 -0.087 0.015

METHANE ISOTHERM 190.0 DEG. K

MOL/L P,8AR OP/DD DP/DT XB OXB/OD XC DXC/DD XO DXO/OO

0.5 7.448 14.010 0.0438 0.286 -0. 199 -0.405 0.395 -0.317 0.100

1.0 14.021 12.297 0.0922 0.211 -0.114 -0.271 0.186 -0.277 0.067

1.5 19.766 10.7C7 0.1452 0.164 -0. 080 -0.198 0.116 -0.247 0.056

2.0 24.750 9.249 0.2028 0.129 -0. 061 -0.150 0.081 -0.221 0.051 2.5 29.034 7.907 0.2647 0.102 -0. 048 -0.115 0.060 -0.196 0.046

3.0 32.674 6.668 0.3311 0.080 -0.039 -0. 088 0.046 -0.172 0.046

3.5 35.718 5.529 0.4016 0.062 -0. 032 -0.067 0.037 -0.150 0.045

4.0 38.220 4.496 0.4762 0.048 -0.026 -0.051 0.029 -0.128 0.043 4.5 40.233 3.575 0.5546 0.036 -0. 021 -0.038 0.023 -0.107 0.041

5.0 41.815 2.772 0.6366 0.027 -P. 017 -0.028 0.019 -0.C87 0.039 5.5 43.024 2.08* 0.7219 0.019 -0.014 -0.019 0.015 -0.068 0.037

6.0 43.917 1.504 0.8104 0.012 -0.011 -0.013 0.012 -0.050 0.035

6. 5 44.544 1.021 0.9021 0.007 -0.009 -0.006 0.009 -0.033 0.033

7. 44.952 0.623 C.9975 0.003 -0. 007 -0.003 0.007 -0.C17 0.031 7.5 45.180 0.301 1.0996 0.000 -0. 005 -0. 000 0.005 -0.002 0.028 13.0 45.342 0.642 1.9949 0.001 0.005 -0.001 -0.005 -0.007 -0.024

13.5 45.806 1.254 2.1663 0.004 0.007 -0.004 -0.007 -0.019 -0.026

14. 46.636 2.106 2.3515 0.008 0.008 -0.008 -0.008 -0.032 -0.027

14.5 47.961 3.247 2.5534 0.012 0. 010 -0. 013 -0.010 -0.046 -0.027

15.0 49.939 4.729 2.7734 0.018 0.012 -0.018 -0.012 -0.059 -0.027

15.5 52.757 6.615 3.0126 0.024 0.C13 -0.025 -0.014 -0.073 -0.027

16.0 56.632 8.971 3.2713 0.031 0.015 -0.032 -0.016 -0.086 -0.025

16.5 61.818 11.868 3.5500 0.039 0.017 -0.041 -0.019 -0.098 -0.024

17. 68.603 15. 380 3. 8487 0.048 0. 019 -0.051 -0.021 -0.110 -0.022

17.5 77.313 19.580 4.1672 0.058 0. 021 -0.062 -0.024 -0.120 -C.019

16.0 88.310 24.540 4.5053 0.069 0. 023 -0. 075 -0.027 -0.129 -0.017

18.5 101.991 30.329 4.8625 0.081 0.025 -0.089 -0.030 -0.137 -0.014

19.0 118.786 37.0C6 5.2380 0.094 0.027 -0.105 -0.034 -0.143 -0.010

19.5 139.155 44.628 5.6310 0.108 0.030 -0.123 -0.038 -0.147 -0.007

20.0 163.580 53.242 6.0404 0.123 0. 032 -0.143 -0.042 -0.150 -0.003

20.5 192.568 62.886 6.4653 0.140 0.034 -0.165 -0. 046 -0.150 0.000 21.0 226.644 73.595 6.9044 0.157 0.036 -0.189 -0.052 -0.149 0.004 21.5 266.345 85.395 7.3563 0.176 0.038 -0.216 -0.057 -0.147 0.007 22.0 312.225 98.312 7.8199 0.196 0.040 -0.246 -0.063 -0.143 0.010 22.5 364.847 112.369 8.2936 0.217 0. 043 -0.280 -0.070 -0.137 0.012

23.0 424.788 127.589 8.7761 0.238 0.045 -0.316 -0.078 -0.130 0.015 23.5 492.634 143.996 9.2658 0.261 0.047 -0.358 -0.087 -0.122 0.016

24.0 568.985 161.607 9.7611 0.285 0.049 -0.403 -0.096 -0.114 0.018 24.5 654.443 180.429 10.2604 0.310 0.051 -0. 454 -0.108 -0.105 0.019

124
METHANE ISOTHERM 200.0 OEG. K

IOL/L P.BAR OP/DD DP/DT XB OXB/OD XC OXC/OD XD OXO/OD

0.5 7.885 li*. 930 0.01*37 0.338 -0.199 -0.1.55 0.395 -0.31*1* 0.077

1.0 li*.9«»0 13.305 0.0917 0.263 -0.111* -0.321 0.186 -0.315 0.01*7 1.5 21.211 11.8C1 0.11*38 0.216 -0.080 -0.21*8 0.116 -0.291* 0.036

2.0 26.763 10.1*29 0.2001 0.181 -0.061 -0.200 0.081 -0.278 0.031 2.5 31.659 9.169 0.26 01* 0.151. -0.01*8 -0.165 0.060 -0.263 0.027

3.0 35.91.9 8.009 0.321.5 0.132 -0.039 -0.138 0.01.6 -0.250 0.025

3.5 39.683 6.9i*«* 0.3921 O.lli. -0. 032 -0.118 0.037 -0.238 0.022

1..0 1*2.910 5.979 0.1.629 0.100 -0.026 -0.101 0.029 -0.228 0.020

it.

5

45.680 5.120 0.5366 0.088 -0.021 -0.088 0.023 -0.219 0.017

5.0 1*8.01*8 .369 0.6129 0.079 -0.017 -0.078 0,019 -0.211 0.015

5.5 50.067 3.721* 0.6913 0.071 -0. Oil. -0.070 0.015 -0.201* 0.012

6.0 51.789 3.178 0.7713 0.065 -0.011 -0.063 0.012 -0.198 0.010

6.5 53.259 2.717 0.8527 0.059 -0.009 -0.058 0.009 -0.191* 0.008

7.0 51*. 518 2.330 0.9351 0.055 -0.007 -0.051* 0.007 -0.190 0.005

7.5 55.600 2.008 1.0181* 0.052 -0.005 -0.050 0.005 -0.188 0.003

8.0 56.538 1.759 1.1027 0.050 -0.003 -0.01*8 0.003 -0.188 -0.000

8.5 57.375 1.6C6 1.1881* 0.01.9 -0.001 -0.01*7 0.001 -0.189 -0.003

9.0 58.161* 1.569 1.2761* 0.01.9 -0.000 -0.01*7 0.000 -0.190 -0.003

9.5 58.955 1.602 1.3676 0.01*9 -0.000 -0.01*7 0.000 -0.191 -0.001

10.0 59.770 1.661 1.1*629 0.01*9 0. 000 -0.01.7 0.000 -0.191 0.000

10.5 60.619 1.739 1.5631 0.01*9 0.000 -0. 01.7 -0.000 -0.191 0.001

11.0 61.511* 1.81*7 1.6689 0.01.9 0. 000 -0.01.7 -0.000 -0.190 0.003

11.5 62.1*79 2.031 1.7813 0.01*9 0.001 -0.01.7 -0.001 -0.188 0.001* 12.0 63.570 2.361 1.9018 0.050 0.002 -0.01.8 -0.002 -0.186 0.003

12.5 6V. 871 2.875 2.0321* 0.051 0.003 -0.01.9 -0.003 -0.185 0.002

13.0 66.1*79 3.595 2.1751 0.053 0.005 -0.051 -0.005 -0.185 -0.000

13.5 68.501* 1*. 51.1* 2.3318 0.056 0.007 -0.051. -0.007 -0.185 -0.002

lit. 71.067 5.756 2.501.0 0.060 0.008 -0.058 -0.008 -0.187 -0.003

11..5 71*. 310 7.271 2.6930 0.061* 0.010 -0.063 -0.010 -0.189 -0.001* 15.0 78.397 9.11*0 2.8999 0.070 0.012 -0.068 -0.012 -0.191 -0.005

15.5 83.519 11.1*21 3.1256 0.076 0.013 -0.075 -0.011* -0.193 -0.005

16.0 89.897 11*. 177 3. 3704 0.083 0. 015 -0. 082 -0.016 -0.195 -0.005

16.5 97.786 17.1*75 3.631*6 0.091 0. 017 -0.091 -0.019 -0.198 -0.001* 17.0 107.1*71* 21.386 3.9185 0.100 0.019 -0.101 -0.021 -0.199 -0.003

17.5 119.286 25.980 i*.2218 0.110 0.021 -0.112 -0.021* -0.201 -0.002

18. 133.579 31.325 I*. 5i*l»l 0. 121 0.023 -0.125 -0.027 -0.201 -0.000

18.5 153.71*6 37.1*85 it. 8852 0.133 0.025 -0.139 -0.030 -0.201 0.002

19.0 171.210 1*1*. 519 5.21*1.2 0.11*6 0. 027 -0.155 -0.031* -0.199 0.001* 19.5 195.1*20 52.1*80 5.6201. 0.160 0.030 -0.173 -0.038 -0.196 0.006

20.0 223.852 61.1*13 6.0130 0.176 0.032 -0.193 -0.01*2 -0.193 0.009

20.5 257.001 71.351* 6.1.208 0.192 0.0 31* -0.215 -0.01*6 -0.188 0.011

21.0 295.379 82.335 6.81.29 0.209 0.036 -0.239 -0.052 -0.181 0.011* 21.5 339.511* 91*. 382 7.2780 0.228 0.038 -0.266 -0.057 -0.171* 0.016

22.0 389.91*3 107.520 7.7250 0.21*8 0.01*0 -0.296 -0.063 -0.166 0.018

22. 5 1*1*7.219 121.771 8.1825 0.269 0.01*3 -0.330 -0.070 -0.156 0.019

23.0 511.901* 137.157 8.61.93 0.290 0.045 -0.367 -0.078 -0.11*6 0.021 23.5 581*. 570 153.701 9.1239 0.313 0.01*7 -0.1.08 -0.087 -0.135 0.022

2^.0 665.800 171.1.16 9.601.9 0.337 0.01.9 -0.1.53 -0.096 -0.121* 0.022

125
METHANE ISOTHERM 210.0 OEG. K

MOl/L P.BAR DP/DD OP/DT XB DXB/DO xc DXC/OO XD DXD/OO

.5 8.322 15.81.1. 0.01.36 0.390 -0. 199 -0.500 0.395 -0.366 0.058

1.0 15.851. H.. 302 0.0912 0.315 -0. 111. -0.367 0.186 -0.31.5 0.031

1.5 22.6<*<* 12.879 0.11.28 0.268 -0.080 -0.291. 0.116 -0.333 0.020

2. 28.751* 11. 581. 0.1981 0.233 -0.061 -0.21.5 0.081 -0.321. 0.015 2.5 3<».2i»6 10.399 0.2572 0.206 -0.01.8 -0.210 0.060 -0.317 0.012

3.0 39.169 9.308 0.3197 0.181. -0.039 -0.181. 0.01.6 -0.312 0.009

3.5 1*3.569 8.309 0.3855 0.166 -0. 032 -0. 163 0.037 -0.308 0.007

If.Q 1*7.1.93 7.1.03 0.1.51.3 0.152 -0.026 -0.11.7 0.029 -0.305 0.005

1*. 5 50.989 6.596 0.5258 0.11.0 -0. 021 -0.131. 0.023 -0.303 0.003

5.0 5<*.107 5.891 0.5998 0.131 -0. 017 -0.123 0.019 -0.302 0.001 5.5 56.897 5.286 0.6760 0.123 -0.011. -0.115 0.015 -0.302 -0.000

6.0 59.1.08 i*. 77*. 0.751.3 0.116 -0.011 -0.108 0.012 -0.302 -0.001

6.5 61.685 1..31.5 0.831.5 0.111 -0.009 -0.103 0.009 -0.303 -0.002

7.0 63.765 3.968 0.9166 0.107 -0.007 -0.099 0.007 -0.301. -0.003

7. 5 65.681. 3.699 1.0008 0.101. -0. 005 -0. 096 0.005 -0.305 -0.003

8.0 67.1.78 3.1.90 1.0871. 0.102 -0.003 -0.091. 0.003 -0.307 -O.OOi* 8.5 69.192 3.389 1.1769 0.101 -0. 001 -0.093 0.001 -0.309 -0.005

9.0 70.889 3.1.19 1.2699 0.101 -0.000 -0.093 0.000 -0.311 -O.OOi. 9.5 72.626 3.538 1.3672 0.101 -0.000 -0.093 0.000 -0.313 -0.001

10.0 7i*.<*3<i 3.696 1.1.695 0.101 0.000 -0. 093 0.000 -0.313 o.noo 10.5 76.328 3. 886 1.5773 0.101 0. 000 -0.093 -0.000 -0.313 0.001 11.0 78.327 1..122 1.6915 0.101 0.000 -0.093 -0.000 -0.311 O.OOi. 11.5 80.1.66 1..1.55 1.8127 0.101 0.001 -0.093 -0.001 -0.309 0.006

12.0 82.811 1..962 1.91.20 0.102 0.002 -0.093 -0.002 -0.306 0.006 12.5 85.1.61. 5.6S6 2.0808 0.103 0.003 -0.095 -0.003 -0.303 0.006 13.0 88.537 6.61.8 2. 2303 0.105 0.005 -0. 097 -O.0O5 -0.300 0.007

13.5 92.155 7.870 2.3920 0.108 0.007 -0. 100 -0.007 -0.296 0.007

1<».0 96.1.55 9.3e2 2.5671 0.112 0. 008 -0.101. -0.008 -0.293 C.007

1«». 5 101.591 11.221 2.7569 0.116 0.010 -0.108 -0.010 -0.290 0.007 15.0 107.739 13.1.35 2.9621. 0.122 0.012 -o. in. -0.012 -0.286 0.007 15.5 115.097 16.071. 3.181.6 0.128 0.013 -0.120 -0.011* -0.282 0.008

16.0 123.891. 19.200 3.1.2M 0.135 0. 015 -0.128 -0.016 -0.278 0.008 16.5 131.. 388 22.871. 3.6815 0.11.3 0. 017 -0.137 -0.019 -0.271. 0.009

17.0 11.6.870 27.162 3.9569 0.152 0.019 -0.11.6 -0.021 -0.269 0.010

17. 5 161.663 32.130 1..2506 0.162 0.021 -0.158 -0.021. -0.261. 0.011

18.0 179.121. 37.81.3 1..5622 0.173 0. 023 -0. 170 -0.027 -0.258 0.012 18.5 199.61.1 1.1.. 362 1..8916 0.185 0.C25 -0.185 -0.030 -0.252 0.011. 19.0 223.630 51.71.2 5.2382 0.198 0.027 -0.200 -0.031. -0.21.5 0.015

19.5 251.535 60.031. 5.6011. 0.212 0. 030 -0.218 -0.038 -0.237 0.017

20.0 283.823 69.279 5.9805 0.227 0. 032 -0.238 -0.01.2 -0 .228 0.018

20 .5 320.979 79.513 6.371.5 0.21.1. 0. C 31. -0.260 -0.01.6 -0.218 0.020 21.0 363.506 90.766 6.7826 0.261 0. 036 -0.285 -0.052 -0.208 0.022 21.5 1.11.919 103.063 7.2037 0.280 0.038 -0. 312 -0.057 -0.197 0.023

22. 1.66. 71.7 116.1.27 7.6367 0.300 o. oun -0. 31.2 -0.063 -0.185 0.021. 22.5 528.527 130.879 8.0801. 0.320 0.01.3 -0.375 -0.070 -0.172 0.025 23.0 597.810 11.6.1.1.1 8.5338 0.31.2 0. 01.5 -0.1.12 -0.078 -0.160 0.026 23.5 675.156 163.133 8.9955 0.365 0.01.7 -0. 1.53 -0.087 -0.11.7 0.026

126
METHANE ISOTHERM 220. DEC

MOL/L P.BAR DP/DO OP/DT XB DXB/DD XC DXC/DD XO OXO/OO

0.5 8.757 16.751* 0.01*35 0.1*1*1 -0.199 -0.5<*1 0.395 -0.385 0.01*3 1.0 16.761* 15.290 0.0908 0.367 -0. Hi* -0.1*08 0.186 -0.371 0.017

1.5 2%. 067 13.91.2 0.11*19 0.319 -C. 080 -0. 335 0.116 -0.365 0.008

2.0 30.728 12.720 0.1965 0.281* -0.061 -0.286 0.081 -0.362 0.003

2.5 36.805 11.605 0.251*7 0.257 -0.0i»8 -0.251 0.060 -0.362 -0.000

3.0 1*2.31*7 10.580 0.3161 0.236 -0.039 -0.225 0.01*6 -0.362 -0.002

3.5 1*7.399 9.61.2 0. 3807 0.218 -0. 032 -0.201* 0.037 -0.361* -0.001*

<t.O 52.001. 8.793 0.1*1*82 0.201* -0.026 -0.188 0.029 -0.366 -0.006

«*.5 56.208 8.038 0.5181* 0.192 -0.021 -0.175 0.023 -0.370 -0.007

5.0 60.059 7.381 0.5911 0.182 -0.017 -0.165 0.019 -0.373 -0.008

5.5 63.606 6.821 0.6663 0.171* -0. Oil* -0.156 0.015 -0.377 -0.008

6.0 66.896 6.353 0.71*39 0.168 -0.011 -0.150 0.012 -0.381 -0.008

6.5 69.973 5.968 0.8238 0.163 -0.009 -0.1i«i* 0.009 -0.386 -0.008

7.0 72.876 5.657 0.90 6 3 0.159 -0.007 -0.11*0 0.007 -0.389 -0.007

7.5 75.6<*2 5.1.20 0.9915 0.156 -0.005 -0.137 0.005 -0.393 -0.007

6.0 73.311 5.270 1.0798 0.151* -0.003 -0.135 0.003 -0.396 -0.006

8.5 80.932 5.21.0 1.1716 0.153 -0. 001 -0.131* 0.001 -0.399 -0.006

9.0 83.575 5. 351. 1.2676 0.153 -0.000 -0.131* 0.000 -0.1*01 -0.001* 9.5 86. 30^ 5.571 1.3683 0.153 -0.000 -0.131* 0.000 -0.1*03 -0.001

10.0 89.151. 5.839 1.1.71.1. 0.153 0.000 -0.131* 0.000 -0.1.03 0.000 10.5 92.150 6.151 1.5865 0.153 0.000 -0.131* -0.000 -0.1.03 0.001 11.0 95.315 6.523 1.7052 0.153 0.000 -0. 131* -0.000 -0.1.01 0.001* 11.5 98.691 7.0C9 1.8311 0.153 0.001 -0.13<* -0.001 -0.399 Q.006

12.0 102.356 7.689 1.9652 0.151* 0.002 -0.135 -0.002 -0.395 0.008

12.5 106.1*21 8.610 2.1081* 0.155 0.003 -0.136 -0.003 -0.391 0.009 13.0 111.010 9.791. 2.2619 0.157 0.005 -0.138 -0.005 -0.386 0.011

13.5 116.262 11.262 2.1.266 0.160 0.007 -0.11*1 -0.007 -0.380 0.012

l<t. 122.321* 13.01.3 2.6038 0.161* 0.C08 -0.11.5 -0.008 -0.371. 0.013 H.5 129.363 15.173 2.791.1* 0.168 0.010 -0.11.9 -0.010 -0.367 0.011* 15.0 137.563 17.696 2.9991* 0.173 0. 012 -0.155 -0.012 -0.360 0.015 15.5 11*7.133 20.6F2 3.2196 0.180 1.C13 -0.162 -0.011* -0.352 0.016

16.0 158.307 21*. 125 3.1.558 0.187 0.015 -0.169 -0.016 -0.3i*<* 0.017 16.5 171.350 28.11.5 3.70ei. 0.195 0.017 -0.178 -0.019 -0.335 0.018

17. 186.555 32.781. 3.9778 0.201* 0.019 -0.188 -0.021 -0.326 0.019 17.5 20<».2'»7 38.103 i.. 261*3 0.213 O.f 21 -0.199 -0.02% -0.316 0.020

18.0 221.. 782 1.1.. 161* i*.5677 0.221* 0. 023 -0.212 -0.027 -0.305 0.021 18.5 2i*8.5<*5 51.021* 1..8879 0.236 0. 025 -0.226 -0.030 -0.291* 0.023

19.0 275. 91.8 58.736 5.221.5 0.250 0.C27 -0.21*2 -0.031* -0.283 0.021* 19.5 307.1.31 67.31*7 5.5771 0.261* 0. 030 -0.259 -0.038 -0.271 0.025 20.0 31.3.1*52 76.896 5.91.1.9 0.279 0.032 -0.279 -0.01*2 -0.258 0.026

20.5 38<*. 1.89 87.1*18 6. 3271. 0.296 0.031* -0.301 -0.01*6 -0.21*1* 0.027

21.0 1*31.036 98.939 6.7237 0.313 0. 036 -0.326 -0.052 -0.230 0.028 21.5 1.83.599 lll.i*e5 7.1328 0.332 0.038 -0.353 -0.05 7 -0.216 0.029

22.0 51.2.695 125.076 7.5538 0.351 0.0t»0 -0.383 -0.063 -0.201 0.030 22.5 609. 852 139. 733 7.9856 0.372 0.01.3 -0.1*16 -0.070 -0.186 0.030

23.0 682.609 155.1*78 8.1*273 0.391* 0.01.5 -0.1.53 -0.078 -0.171 0.030

127
METHANE ISOTHERM 21.0.0 DEC

MOL/L P.BftR DP/DD DP/DT XB OXB/OD XC OXC/OD XO DXD/OO

0.5 9.625 18.561* 0.01*33 0.51.1. -0. 199 -0.613 0.395 -0.1*1«» 0.018

1 .0 18.571* 17.21.5 0.0902 0.1.70 -O.lli. -0.1.80 0.186 -0.1*12 -0.003

1.5 26.890 16.039 0. 11.05 0.1.22 -0. 080 -0.1.07 0.116 -0.U15 -0.011

2.0 3<*.633 11..953 0.191*1 0.387 -0.061 -0.359 0.081 -0.1*22 -0.015

2.5 <«1.859 13.968 0.2510 0.360 -0.C8 -0.321* 0.060 -0.1.30 -0.017

3.0 1*8.615 13.068 0.3110 0.338 -0.039 -0.297 0.01*6 -0.1.39 -0.019

3.5 5<».9<»1 12.21.9 0. 3739 0.321 -0. 032 -0.276 0.037 -0.U 1.9 -0.020

<t.O 60.877 11.513 0.1.398 0.306 -0. 026 -0.260 0.029 -0.1.59 -0.020

I..5 66.1.69 10.867 0.5085 0.295 -0.021 -0.21.7 0.023 -0.1.69 -0.020

5. 71.760 10.315 0.5799 0.285 -0. 017 -0.237 0.019 -O.t.79 -0.020

5.5 76.799 9.859 0.651*1 0.277 -0. Oil* -0.228 0.015 -0.1.88 -0.019

6.0 81.631* 9.1.96 0.7312 0.271 -0. Cll -0.222 0.012 -0.1.97 -0.017

6.5 86.310 9.222 0.8112 0.266 -0.009 -0.216 0.009 -0.505 -0.015

7.0 90.871 9.032 0.89<*i« 0.262 -0.007 -0. 212 0.007 -0.512 -0.013

7. 5 95.357 8.927 0.9810 0.259 -0.005 -0.209 0.005 -0.518 -0.011

8.0 99.811* 8.921* 1.0715 0.257 -0.003 -0.207 0.003 -0 .523 -0.009

8.5 10i*.303 9.060 1.1661 0.256 -0.001 -0.206 0.001 -0.527 -0.007

9.0 108.903 9.365 1.2651. 0.256 -0.000 -0.206 0.000 -0.530 -0.001* 9.5 113.690 9.795 1.3700 0.256 -0.000 -0.206 0.000 -0.531 -0.101

10. 118.710 10,298 l.i*80i* 0.256 0.000 -0.206 0.000 -0.531 0.000 10.5 123.998 10.868 1.5970 0.256 o.coo -0.206 -0.000 -0.531 0.001

11. 129.591 11.520 1.7201. 0.256 0.000 -0.206 -0.000 -0.530 0.001* 11.5 135. 5i*2 12.31't 1.8513 0.256 0.001 -0.206 -0.001 -0.527 0.007

12.0 l'»1.9'»'» 13.336 1 .9901 0.256 0.002 -0.207 -0.002 -0.523 0.010 12.5 li*8.92i* H..633 2.1378 0.258 0.003 -0.208 -0.003 -0.517 0.013

13. 156.627 16.230 2.29 51 0.260 0.005 -0.210 -0.005 -0.510 0.015 13.5 165.208 18. 11.9 2.1*627 0.263 0.007 -0.213 -0.007 -0.501 0.018 1U.0 17i».83i» 20.i»18 2.61*15 0.266 0.008 -0.217 -0.008 -3.1.92 0.321

1«*.5 185.690 23.071 2.8323 0.271 0.010 -0.222 -0.010 -0.1.81 0.023

15.0 197.976 26. 11.9 3. 0358 0.276 0.012 -0.227 -0.012 -0.1.69 0.025 15.5 211.917 29.698 3.2528 0.282 0.013 -0.231* -O.Oli* -0 .1.56 0.027

16.0 227.761 33.769 3.1*837 0.289 0. C15 -0.21.1 -0.016 -O.i. i*2 0.029 16.5 21*5.782 38. ^lU 3.7292 0.297 0. 017 -0.250 -0.019 -0.1.27 0.031

17.0 266.281 1.3.690 3.9896 0.306 0.019 -0.260 -0.021 -0.1*11 0.032

17.5 289.587 1*9.653 i*.2651 0.316 0. 021 -0.271 -0.021* -0.391. 0.031* 18.0 316.057 56.355 it. 5558 0.327 0.C23 -0.281. -0.027 -0.377 0.035 18.5 31*6. 07<t 63.850 i*.e618 0.339 0. 025 -0.298 -0.030 -0.360 0.036

19.0 380.01*6 72.183 5.1828 0.352 0.027 -0.311. -0.031* -0.31*2 0.037 19.5 i»18.i*0<* 81.397 5.5185 0.367 0.030 -0. 332 -0.038 -0.323 0.037

20.0 '61.596 91.527 5.8686 0.382 0. 032 -0.351 -0.01*2 -0.301* 0.038 20.5 510.088 102.601 6.2321. 0.398 0. C3<. -0. 371* -0.01*6 -0.285 0.038

21.0 56i*.359 11I..61.6 6.6091. 0.1.16 0.036 -0. 398 -0.052 -0.266 0.039

21.5 62<».900 127.682 6.9988 0.1.31. 0.038 -0.1*25 -0.057 -0.2i»6 0.039

22. 692.210 11.1.729 7.1.000 0.1.51. 0.01.0 -0.1*55 -0.063 -0.227 0.038

128
METHANE ISOTHERM 260.0 DEC K

MOL/L P,BAR OP/DO DP/DT XB DXB/DO XC DXC/DD XD DXD/DO

0.5 10.491 20. 364 0.0432 0.646 -0.199 -0.675 0.395 -0.437 0.001

1.0 20.373 19.180 0.0897 0.572 -0.114 -0.541 0.186 -0.442 -0.017

1.5 29.689 18.105 0.1395 0.524 -0.080 -0.468 0.116 -0.452 -0.024

2.0 38.497 17.146 0.1924 0.489 -0.061 -0.420 0.061 -0.465 -0.027

2.5 46.852 16.285 0.2484 0.462 -0.048 -0.385 0.060 -0.480 -0.029

3.0 54.796 15.506 0.3073 0.440 -0.039 -0.358 0.046 -0.494 -0.030

3.5 62.370 14.804 0.3693 0.423 -0.032 -0.337 0.037 -0.509 -0.030

<».o 69.614 14.184 0.4342 0.408 -0.026 -0.321 0.029 -0.524 -0.030

4.5 76.569 13.651 0.5019 0.396 -0.021 -0.308 0.023 -0.539 -0.029

5.0 83.261 13.214 0.5726 0.387 -0.017 -0.298 0.019 -0.553 -0.027

5.5 89.799 12.875 0.6463 0.379 -0.014 -0.289 0.015 -0.566 -0.025

6.0 96.173 12.635 0.7232 0.373 -0.011 -0.263 0.012 -0.578 -0.022

6.5 102.451 12.491 0.8033 0.368 -0.009 -0.278 0.009 -0.588 -0.020

7.0 108.680 12.440 0.8869 0.363 -0.007 -0.273 0.007 -0.597 -0.016

7.5 114.907 12.487 0.9744 0.360 -0.005 -0.270 0.005 -0.605 -0.013

8. 121.186 12.651 1.0659 0.359 -0.003 -0.268 0.003 -0.611 -0.010

8.5 127.585 12.972 1.1620 0.358 -0.001 -0.267 0.001 -0.615 -0.007

9.0 134.190 13.481 1.2631 0.357 -0. 000 -0.267 0.000 -0.618 -0.004

9.5 141.090 14.135 1.3696 0.357 -0. 000 -0.267 0.000 -0.619 -0.001

10.0 148.340 14.881 1.4820 0.357 0.000 -0.267 0.000 -0.620 0.000

10.5 155.986 15.714 1.6008 0.357 0.000 -0.267 -0.000 -0.619 0.001

11.0 164.072 16.650 1.7264 0.357 0. 000 -0.267 -0.000 -0.618 0.004

11.5 172.663 17.750 1. 8593 0.357 0. 001 -0.267 -0.001 -0.615 0.008

12.0 181.86". 19.104 2.0001 0.358 0.002 -0.268 -0.002 -0.610 0.011 12.5 191.817 20.760 2.1494 0.359 0.003 -0.269 -0.003 -0.604 0.015

13. 202.679 22.746 2.3078 0.361 0.005 -0.271 -0.005 -0.595 0.018

13.5 214.621 25.082 2.4760 0.364 0.007 -0.274 -0.007 -0.585 0.022

li*. 227.824 27.796 2.6546 0.366 0.008 -0.278 -0.008 -0.574 0.025 14.5 242.486 30.922 2.8442 0.373 0.010 -0.283 -0.010 -0.560 0.028

15.0 253.822 34.500 3.0456 0.378 0.012 -0.288 -0.012 -0.545 0.032 15.5 277.068 38.573 3.2591 0.384 0.013 -0.295 -0.014 -0.529 0.034

16. 297.485 43.187 3.4855 0.391 0.015 -0.302 -0.016 -0.511 0.037

16.5 320.35i» 48.394 3.7250 0.399 0.017 -0.311 -0.019 -0.492 0.039

17.0 345.986 54.243 3.97 81 0.408 0. 019 -0.321 -0.021 -0.472 0.041 17.5 374.713 60.787 4.2450 0.418 0.021 -0.332 -0.024 -0.451 0.042

18.0 406.896 68.073 4.5258 0.429 0.023 -0. 345 -0.027 -0.429 0.044

18.5 ''2.918 76.149 4.8207 0.441 0.025 -0.359 -0.030 -0.407 0.045

19.0 483.184 85.056 5.1294 0.454 0. 027 -0.375 -0.034 -0.385 0.046

19.5 528.119 94.832 5.4519 0.468 0.030 -0.393 -0.038 -0.362 0.046

20.0 578.165 105.507 5.7878 0.484 0.032 -0.413 -0.042 -0.339 0.046

20.5 633.780 117.109 6.1368 0.500 0.034 -0.435 -0.046 -0.315 0.046

21.0 695. 432 129.658 6.4983 0.518 0. 036 -0.459 -0.05 2 -0.29 2 0.046

METHANE ISOTHERM 280.0 OEG. K

MOL/L P.BAR DP/DD DP/DT XB OXB/DD XC DXC/DD XD DXD/DD

0.5 11.354 22.155 0.0431 0.746 -0.199 -0.727 0.395 -0.454 -0.013

1.0 22.164 21.098 0.0894 0.672 -0. 114 -0.593 0.186 -0.465 -0.028

1.5 32.471 20.148 0.1387 0.624 -0.080 -0.520 0.116 -0.481 -0.034

2.0 42.331 19.311 0.1910 0.589 -0. 061 -0.472 0.081 -0.498 -0.037

2.5 51.798 18.570 0.2463 0.562 -0. 048 -0.437 0.060 -0.517 -0.038

3.0 60.914 17.909 0.3046 0.541 -0.039 -0.410 0.046 -0.536 -0.038

3.5 69.720 17.325 0.3658 0.523 -0.032 -0.390 0.037 -0.555 -0.037

4.0 78.253 16.822 0.4299 0.509 -0. 026 -0.374 0.029 -0.573 -0.036

4.5 86.556 16.408 0.4970 0.497 -0.021 -0. 361 0.023 -0.591 -0.034

5.0 94.677 16.092 0.5672 0.487 -0.017 -0.350 0.019 -0.608 -0.032

5.5 102.665 15.879 0.64 5 0.480 -0. 014 -0.342 0.015 -0.623 -0.029

6.0 110.573 15.770 0.7171 0.473 -0.011 -0.335 0.012 -0.637 -0.026

6.5 118.453 15.767 0.7971 0.468 -0. 009 -0. 330 0.009 -0.649 -0.022

7.0 126.357 15.866 0.8810 0.464 -0.007 -0.326 0.007 -0.659 -0.019

7.5 134.338 16.076 0.96 8 8 0.461 -0.005 -0. 323 0.005 -0.668 -0.015

6.0 142.455 16.417 1.0609 0.459 -0.003 -0.321 0.003 -0.674 -0.011

8.5 150.783 16.930 1.1577 0.458 -0.001 -0.320 0.001 -0.679 -0.008

9.0 159.420 17.649 1.2596 0.458 -0. 000 -0.319 0.000 -0.682 -0.005

9.5 168.459 18.531 1.3670 0.458 -0.000 -0. 319 0.000 -0.684 -0.001

10.0 177.968 19.522 1.4803 0.458 0.000 -0.319 0.000 -0.684 0.000 10.5 187.999 20.616 1.5999 0.458 0.000 -0.319 -0.000 -0.684 0.001 11.0 198.606 21.835 1.7263 0.458 0.000 -0. 319 -0.000 -0.682 0.005

11.5 209.864 23.236 1.8598 0.458 0.001 -0.320 -0.001 -0.679 0.008

12.0 221.888 24.912 2.0011 0.459 0.002 -0.320 -0.002 -0.674 0.012

12.5 234.830 26.914 2.1506 0.460 0.003 -0.322 -0.003 -0.667 0.016

13.0 248.861 29.268 2.3089 0.462 0.005 -0.324 -0.005 -0.658 0.020 13.5 264.161 31.997 2.4764 0.465 0.007 -0.327 -0.007 -0.647 0.024

14.0 280.925 35.128 2.6538 0.469 0. 008 -0.330 -0.008 -0.634 0.028

14.5 299.362 38.694 2.8415 0.473 0.010 -0.335 -0.010 -0.618 0.032

15.0 319.699 42.734 3.0402 0.478 0.012 -0.341 -0.012 -0.601 0.036

15.5 342.182 47.288 3.2502 0.485 0.013 -0.347 -0.014 -0.583 0.039

16.0 367.080 52.402 3.4721 0.492 0. 015 -0.355 -0.016 -0.562 0.042

16.5 394.685 58.124 3.7062 0.500 0.017 -0. 363 -0.019 -0.541 0.045

17.0 425.313 64.500 3.9528 0.509 0.019 -0.373 -0.021 -0.518 0.047

17.5 459.302 71.578 4.2122 0.518 0.021 -0.384 -0.024 -0.494 0.049

18.0 497.016 79.404 4.4846 0.529 0.023 -0.397 -0.027 -0.469 0.050

18.5 538.838 88.019 4.7701 0.541 0.025 -0.411 -0.030 -0.443 0.051

19.0 585.173 97.462 5.0685 0.555 0.027 -0.427 -0.034 -0.417 0.052

19.5 636.443 107.766 5.3798 0.569 0. 030 -0.445 -0.038 -0.391 0.053

20.0 693.087 118.958 5.70 39 0.584 0.032 -0.465 -0.042 -0.365 0.053

129
METHANE ISOTHERM 300.0 DEC K MOL/L P.8AR DP/OD OP/DT XB OXB/DO xc DXC/OD XD DXO/OO

0.5 12.216 23.91.0 0.01.31 0.81.5 -0.199 -0.772 0.395 -0.1.68 -0.023

1.0 23.91.9 23.003 0.0891 0.771 -0.111. -0.639 0.186 -0.1.83 -0.037

1,5 35.237 22.172 0.1380 0.723 -0.080 -0.566 0.116 -0.503 -0.01.1 2.0 kb.mo 21.1.51. 0.1899 0.688 -0. 061 -0.517 0.081 -0.521. -0.01.3 2.5 56.707 20.830 0.21. 1.7 0.661 -0. 01.8 -0.1.82 0. 060 -0.51.6 -0.01.1. 3.0 66.983 20.286 0.3023 0.61.0 -0.039 -0.1.56 0.01.6 -0.568 -0.01.1. 3.5 77.006 19.819 0.3629 0.622 -0.032 -0.1.35 0.037 -0.590 -0.01.3 U.O 86.815 19.1.31. 0.1.261. 0.608 -0.026 -0.1.19 0.029 -0.611 -0.01.1 k.S 96.1.55 19.11*2 0.1.930 0.596 -0.021 -0.1.06 0.023 -0.631 -0.039

5.0 105.971. 18.951 0.5627 0.586 -0.017 -0.396 0.019 -0.61.9 -0.036

5.5 115.1.21. 18.868 0.6355 0.579 -o. on. -0.387 0.015 -0.667 -0.U33

6.0 121..861 18.898 0.7118 0.572 -0.011 -0.381 0.012 -0.682 -0.029

6.5 134.3I.1 19.01.1 0.7917 0.567 -0. 009 -0.375 0.009 -0.695 -0.025

7.0 11.3.921 19.297 0.8755 0.563 -0.007 -0.371 0.007 -0.707 -0.020

7.5 153.659 19.675 0.9633 0.560 -0.005 -0.368 0.005 -0.716 -0.016

8.0 163.620 20.197 1.0556 0.558 -0.003 -0.366 0.003 -0.723 -0.012

8.5 173. 887 20.907 1.1526 0.557 -0.001 -0.365 0.001 -0.728 -0.008

9.0 18<..56l. 21.838 1.251.7 0.557 -0. 000 -0.365 0.000 -0.731 -0.005

9.5 195.755 22.91*7 1.3622 0.557 -0.000 -0.365 0.000 -0.732 -0.001

10. 207.532 2i». 183 1.1.757 0.557 0.000 -0.365 0.000 -0.733 0.000 10.5 219.957 25.538 1.5951. 0.557 0.000 -0.365 -0.000 -0.732 0.001 11.0 233.093 27.032 1.7218 0.557 0. 000 -0.365 -0.000 -0.731 0.005 11.5 21.7.022 28.727 1.8552 0.557 0. 001 -0.365 -0.001 -0.728 0.009

12.0 261.869 30.716 1.9961 0.558 0.002 -0.366 -0.002 -0.722 0.013 12.5 277.796 33.051 2.11.50 0.559 0.003 -0.367 -0.003 -0.715 0.017

13.0 29^.983 35.759 2.3023 0.561 0.005 -0.369 -0.005 -0.705 0.022 13.5 313.621 38.862 2. 1*681. 0.561. 0. 007 -0. 372 -0.007 -0.693 0.026

14.0 333.915 1.2.387 2.61.39 0.568 0. 008 -0.376 -0. 008 -0.679 0.031 14.5 356.083 1.6.366 2.8293 0.572 0.010 -0.380 -0.010 -0.663 0.035

15.0 380.363 50.838 3.021.9 0.577 0.012 -0.386 -0.012 -0.6I.1. 0.039 15.5 1*07.010 55.81.3 3.2313 0.581. 0.013 -0.393 -0.011. -0.621. 0.01.3 16.0 1.36.302 61.4.23 3.1.1.88 0.591 0.015 -0.1.00 -0.016 -0.602 0.01.6 16.5 468.537 67.621. 3.6777 0.599 0.017 -0.1.09 -0.019 -0.578 0.01.9 17.0 501.. 037 71.. 1.91 3.9183 0.608 0.019 -0.1.19 -0.021 -0.553 0.051 17.5 51.3.11.6 82.069 4.1710 0.618 0.021 -0.1.30 -0.021. -0.526 0.051. 18.0 586.231 90. 398 i.. 1.358 0.628 0. 023 -0. 1.1.3 -0.027 -0.1.99 0.055 18.5 633.677 99.519 1..7129 0.61.1 0.025 -0.1.57 -0.030 -0.1.71 0.056

19.0 685.888 109.1.67 5.0023 0.651. 0.O27 -0.1.73 -0.031. -0.1. 1.3 0.057 METHANE ISOTHERM 320.0 OEG. K

MOL/L P,BAR OP/DD DP/DT XB OXB/OO XC DXC/DO XD DXD/DO

0.5 13.076 25.719 0.01.30 0.91.3 -0. 199 -0.812 0.395 -0.1.78 -0.032

1.0 25.727 2i». 898 0.0886 0.868 -0.111. -0.679 0.186 -0.1.98 -0.01.3 1.5 37.992 2i*. 161 0.1375 0.821 -0.080 -0.605 0.116 -0.521 -0.01.7 2.0 1*9.928 23.578 0.1889 0.786 -0.061 -0.557 0.081 -0.51.5 -0.01.9 2.5 61.586 23.068 0.21.32 0.759 -0.01.8 -0.522 0.060 -0.569 -0.01.9 3.0 73.009 22.61.0 0.3001. 0.737 -0. 039 -0.1.95 0.01.6 -0.591. -0.01.8 3.5 8<.. 239 22.290 0.3601. 0.720 -0.032 -0.1.75 0.037 -0.617 -0.01.7

li.O 95.313 22.025 0.1.231. 0.705 -0.026 -0.1.59 0.029 -0.61.0 -0.01.5

1..5 106.279 21.855 0.1.895 0.693 -0.021 -0.1.1.6 0.023 -0.662 -0.01.2 5.0 117.186 21.792 0.5586 0.681. -0. 017 -0.1.35 0.019 -0.682 -0.039

5.5 128.090 21.81*3 0.6311 0.676 -0. Oil. -0.1.27 0.015 -0.701 -0.035

6.0 139.01.9 22.011. 0.7070 0.670 -0.011 -0.1.20 0.012 -0.717 -0.031

6.5 150.121. 22.306 0.7866 0.661* -0.009 -0.1.15 0.009 -0.731 -0.026

7. 161.376 22.723 0.8701 0.660 -0.007 -0.1.11 0.007 -0.71.3 -0.022

7.5 172. 869 23.272 0.9577 0.657 -0. 005 -0.1.08 0.005 -0.753 -0.017

8.0 181.. 671. 23.977 1.0497 0.655 -0.003 -0.1*06 0.003 -0.760 -0.013

8.5 196.879 21..881* 1.11*65 0.651. -0.001 -0.1*05 0.001 -0.766 -0.009

9. 209.597 26.026 1.21*85 0.651. -0.000 -0.1*05 0.000 -0.769 -0.005

9.5 222.938 27. 362 1.3558 0.651. -0. 000 -0.1*05 0.000 -0 .770 -0.002

10.0 236.982 28.838 1.1*690 0.651. 0. 000 -0.1.05 0.000 -0.771 0.000 10.5 251.798 30. i*i*9 1.5883 0.651. 0.000 -0.1.05 -0. 000 -0.770 0.002

11.0 267.1.57 32.211. 1.711.1 0.651. 0.000 -0.1.05 -0.000 -0.769 0.005 11.5 281*. oi*8 3«». 196 1.61.68 0.651* 0,001 -0.1.05 -0.001 -0.765 0.009

12.0 301.701* 36.1.69 1.9868 0.655 0.002 -0.1.05 -0.002 -0.760 0.013 12.5 320.597 39.146 2.131.1. 0.656 0. 003 -0.1.07 -0.003 -0.752 0.018

13.0 340.915 1*2.193 2.2902 0.658 0.005 -0.1.09 -0.005 -0.71.2 0.023

13.5 362.859 1*5.653 2.1.51.5 0.661 0. 007 -0.1.12 -0.007 -0.730 0.027

11*. 386.61.1 1.9.553 2.6278 0.665 0.008 -0.1.15 -0.008 -0.715 0.032

li..

1*12.1.90 53.925 2.8105 0.669 0. 010 -0.1.20 -0.010 -0.697 0.037

15.0 1.1.0.651 58.806 3.0029 0.675 0.012 -0.1.26 -0.012 -0.678 0.01.1 15.5 1.71.387 6«*.235 3.2051. 0.681 0. 013 -0.1.32 -0.011. -0.656 0.01.5 16.0 501.. 981. 70.251. 3.1.185 0.688 0.015 -0. 1.1.0 -0.016 -0.633 0.01.9 16.5 51.1.71.7 76.907 3.61.21. 0.696 0.017 -0.1.1.8 -0.019 -0.607 0.052

17.0 582.001. 81.. 236 3.8771. 0.705 0.019 -0.1.58 -0.021 -0.580 0.055 17.5 626.103 92.283 1..1238 0.715 0.021 -0.1.70 -0.021. -0.552 0.057

18.0 671.. 1.13 101.088 1..3616 0.726 0.023 -0.1.82 -0.027 -0.523 0.059

130
METHANE ISOTHERM 31.0.0 DEC K MOL/L P,BAR OP/DD OP/DT XB DXB/DO XC DXC/DO XD OXD/DD

0.5 13.936 27.1*93 0.01.29 1.039 -0.199 -0.81*7 0.395 -0.1*87 -0.038

1.0 27.501 26.783 0.0886 0.961* -O.IH* -0.71<* 0.186 -0.510 -0.01*9 1.5 40.736 26.177 0.1370 0.916 -0. 080 -0.61*0 0.116 -0.535 -0.052

2.0 53.698 25.685 0.1881 0.882 -0.061 -0.592 0.081 -0.561 -0.053

2.5 66.1*37 25.288 0.21*20 0.851* -0.01*8 -0.557 0.060 -0.588 -0.053

3.0 79.000 2i*. 971* 0.2987 0.833 -0.039 -0.531 0.01*6 -0.611* -0.052

3.5 91.<*25 2i*. 7i*0 0.3582 0.815 -0.032 -0.510 0.037 -0.61*0 -0.050

<>.o 103.751. 2i*. 591. 0.1*207 0.801 -0.026 -0.1*91. 0.029 -0.661* -0.01*8

«i.5 116.036 21*. 51.8 0.1*862 0.789 -0.021 -0.1.81 0.023 -0.687 -0.01*5

5. 128.321 21*. 611* 0.551.9 0.779 -0.017 -0.1*70 0.019 -0.709 -0.01*1 5.5 11.0.670 2I..8C0 0.6269 0.772 -0. OH* -0. 1*62 0.015 -0.728 -0.037

6.0 153. H.3 25.111. 0.7023 0.765 -0. 011 -0.1*55 0.012 -0.71*5 -0.032

6.5 165.805 25.557 0.7815 0.760 -0.009 -0.1*50 0.009 -0.760 -0.027

7.0 178.722 26.135 0.861.5 0.756 -0.007 -0. i*i«6 0.007 -0.773 -0.022

7.5 191.961. 26.855 0.9517 0.753 -0.005 -0.i»i*3 0.005 -0.783 -0.018

6.0 205.606 27.71.1. 1.01.31. 0.751 -0.003 -0.1*1*1 0.003 -0.790 -0.013

8.5 219.7i*l» 28.81.7 1.1397 0.750 -0.001 -0.1*1*0 0.001 -0.796 -0.009

9. 23<t.<*95 30.199 1.21.12 0.750 -0.000 -O.i*i»0 0.000 -0.799 -0.005

9.5 21*9.977 31.758 1.31.79 0.750 -0.000 -0.1*1*0 0.000 -0.801 -0.002

10.0 266.279 33.1.71 1.1*601. 0.750 0. 000 -0. i*i*0 0.000 -0.801 0.000

10.5 283.1*73 35.333 1.5789 0.750 0.000 -0. 1*1.0 -0.000 -0.801 0.002

11.0 301.639 37. 362 1.7038 0.750 0.000 -0.1*1.0 -0.000 -0.799 0.005 11.5 320.871* 39.621. 1.8351. 0.750 0.001 -O.i. 1.0 -0.001 -0.796 0.009

12.0 3i»1.318 1.2.212 1.97i»l 0.751 0. 002 -0. i*i*0 -0.002 -0.790 0.013

12.5 363.11*9 1.5.179 2.1202 0.752 0. 003 -0. 1.1*2 -0.003 -0.782 0.018

13.0 386.565 1.8.553 2.271.2 0.751* 0.005 -0.1*1*1* -0.005 -0.772 0.023

13.5 1*11.771* 52.356 2.1.363 0.757 0.007 -0.i*i*7 -0.007 -0.759 0.028

H..0 1.38.997 56.615 2.6071 0.761 0.008 -0.1*50 -0.008 -0.71*3 0.031*

l<f.5 1*68.1*70 61.361 2.7868 0.765 0.010 -0.1*55 -0.010 -0.725 0.038

15.0 500.1* 1*5 66.631 2.9758 0.770 0.012 -0.1*61 -0.012 -0.705 0.01*3 15.5 535.195 72.1.61* 3.171.6 0.777 0.013 -0.1*67 -0.011* -0.682 0.01.7 16.0 573.009 78.899 3.3833 0.781* 0.015 -0.1.75 -0.016 -0.657 0.051 16.5 61<*.201 85.979 3.6023 0.792 0.017 -0.1*63 -0.019 -0.631 0.055

17.0 659.103 93.71.6 3.8318 0.801 0.019 -0.1*93 -0.021 -0.603 0.058

METHANE ISOTHERM 360.0 OEG. K

MOL/L P,BAR OP/DD OP/DT XB DXB/DO XC Dxr/oo XD DXD/OD

0.5 11*. 791. 29.262 0.01*29 1.132 -0. 199 -0.378 0.39 5 -0.1.95 -0.01*1. 1.0 29.271 28.659 0.0881* 1.058 -0.111. -0. 71*5 0.186 -0.519 -0.053

1.5 1.3.1.71 28.162 0.1365 1.010 -0.080 -0.672 0.116 -0.51.7 -0.056

2.0 57.1.51 27.778 0. 1873 0.975 -0.061 -0.623 0.081 -0.575 -0.057

2.5 71.265 27.1.91 0.21*0 8 0.91*8 -0. 01.8 -0.588 0.06O -0.603 -0.056

3.0 81*. 957 27.269 0.2971 0.927 -0. 039 -0.562 0.01.6 -0.631 -0.055

3.5 98.568 27.171 0.3561 0.°09 -0.032 -0.51*1 0.037 -0.658 -0.053

I*. 112.11.2 27.11*1. 0.1.181 0.895 -0. 026 -0.525 0.029 -0.683 -0.050

it.

5

125.729 27.221 0.1.832 0.883 -0.021 -0.512 0.023 -0.708 -0.01*7 5.0 139.383 27.1*16 0.5513 0.873 -0.017 -0.501 0.019 -0.730 -0.01*3 5.5 153.166 27.738 0.6228 0.865 -0.011. -0.1.93 0.015 -0.750 -0.038

6.0 167.11.3 28.191* 0.6977 0.659 -0.O11 -0.1.86 0.012 -0.768 -0.033

6.5 181.383 28.789 0.7763 0.651. -0.009 -0.1.81 0.009 -0.781. -0.028

7. 195.956 29.528 0.8588 0.850 -0.007 -0.1.77 0.007 -0.796 -0.023

7.5 213.936 30.1*19 0.91.55 0.81.7 -0.C05 -0.1*71* 0.005 -0.807 -0.018

8.0 226.1.06 31.1*91 1.0365 0.81.5 -0.003 -0.1*72 0.003 -0.815 -0.013

8.5 21*2.1*65 32.788 1.1323 0.81*1* -0.001 -0.1*71 0.001 -0.820 -0.009

9.0 259.237 31.. 31.6 1.2330 0.8i*i* -0.000 -0.1*71 0.000 -0.821. -0.005

9.5 276.81*8 36.125 1.3389 0.8i*i. -0.000 -0.1*71 0.000 -0.825 -0.002

10.0 295.390 38.070 1.1.505 0.81.1. 0.000 -0.1*71 0.000 -0.825 0.000 10.5 31i».9<»5 1.0.177 1.5680 0.81*1* 0.000 -0.1*71 -0.000 -0.825 0.002

11.0 335.597 1.2.1.65 1.6917 0.81.1. 0.000 -0.1*71 -0.000 -0.821. 0.005

11.5 357.1.50 1.I..998 1.8219 0.8i*i. 0.001 -0.1.71 -0.001 -0.820 0.009

12.0 380.652 1.7.872 1.9590 0.81.1. 0.002 -0.1.71 -0.002 -0.811. 0.011. 12.5 1.05.388 51.11.0 2.1033 0.81*6 0.003 -0.1.73 -0.003 -0.806 0.019

13.0 1.31.862 5i*. 829 2.2551 0.81*8 0.005 -0.1.75 -0.005 -0.796 0.021. 13.5 1.60.291 58.962 2.1.11*9 0.851 0.007 -0.1.78 -0.007 -0.782 0.029

11*. 1.90.902 63.565 2.5830 0.851* 0. 008 -0.1.82 -0.008 -0.766 0.035

11..

5

523.939 68.669 2.7596 0.859 0.010 -0.1*86 -0.010 -0.71.8 0.01*0 15.0 559.661 71*. 311 2.91*52 0.861* 0.012 -0.1.92 -0.012 -0.727 0.01*5 15.5 598.31.6 80.528 3.11*00 0.870 0.013 -0.1.98 -0.011* -0.703 0.01.9 16. 61*0.291 67.360 3.3i*<*i* 0.878 0. 015 -0.506 -0.016 -0.678 0.053 16.5 685.815 91*. 61*8 3.5586 0.885 0. 017 -0.515 -0.019 -0.650 0.057

131
METHANE ISOTHERM 380.0 DEG. K

MOL/L P,BAR DP/DO DP/DT XB DXB/OO XC OXC/DD XO OXD/OD

0.5 15.651 31.027 0.01*28 1.221* -0.199 -0.906 0.395 -0.501 -0.01*8 1.0 31.036 30.528 0.0882 1.150 -0. ll«i -0. 773 0.186 -0.527 -0.056

1 .5 1*6.197 30.135 0.1361 1.102 -0.080 -0,699 0.116 -0.556 -0.059

2.0 61.190 29.857 0. 1866 1.067 -0.061 -0.651 0.081 -0.586 -0.059

2.5 76.070 29.678 0.2397 1.01*0 -0. 0i*8 -0.616 0.060 -0.616 -0.059

3.0 90.883 29.587 0. 2956 1.018 -0. 039 -0.590 0.01.6 -0.61*5 -0.057

3.5 105.671 29.582 0.351.2 1.001 -0. 032 -0.569 0.037 -0.673 -0.055

<. 120.1*81 29.673 0.1.157 0.986 -0.026 -0.553 0.029 -0.699 -0.052

<».5 135.363 29.873 0.1*8 2 0.975 -0.021 -0.51.0 0.023 -0.721* -0.01*8 5.0 150.375 30.196 0.51.78 0.965 -0. 017 -0.529 0.019 -0.71.8 -0.0i*i» 5.5 165.581 30.653 0.6188 0.957 -0 . Oil* -0.521 0.015 -0.768 -0.039

6.0 181.052 31.252 0.6931 0.951 -0.011 -0.511* 0.012 -0.787 -0.031* 6.5 196.858 31.998 0.7711 0.946 -0.009 -0.509 0.009 -0.803 -0.029

7. 213.075 32.896 0.8530 0.9i*2 -0.007 -0.505 0.007 -0.616 -0.021. 7.5 229.781 33.958 0.9390 0.939 -0. 005 -0.502 0.005 -0.827 -0.019

8. 21*7.061* 35.209 1.0293 0.937 -0.003 -0.500 0.003 -0.835 -0.011. 8.5 265.030 36.698 1.121*2 0.936 -0. 001 -0.1.99 0.001 -0.81.0 -0.009

9. 283.808 38.1*60 1.221.0 0.935 -0. 000 -0.1.99 0.000 -0.81*1* -0.005

9.5 303.529 1*0. i*5i* 1.3290 0.935 -0.000 -0.1*99 0.000 -0.81*5 -0.002

10.0 321*. 291 1*2.626 1.1.395 0.935 0.000 -0.i*99 0.000 -0 .81.6 0.000 10.5 3i«6.183 i*i*. 972 1.5557 0.935 0.000 -0.1*99 -0.000 -0.81.5 0.002

11.0 369.295 1.7.511 1.6780 0.935 0.000 -0.1*99 -0.000 -0.81*1* 0.005 11.5 393.738 50.309 1.8067 0.936 0.001 -0.i*99 -0.001 -0.81*0 0.009

12. <*19. 664 53.1.60 1.91*20 0.936 0.002 -0.1*99 -0.002 -0.831* 0.011. 12.5 1*1*7.266 57.019 2.081*3 0.938 0.003 -0.501 -0.003 -0.826 0.019

13.0 1*76.755 61.013 2.2339 0.91.0 0.005 -0.503 -0.005 -0.815 0.021. 13.5 508.355 65.1*63 2. 3911 0.91*3 0.007 -0.506 -0.007 -0.802 0.030 14.0 51.2.299 70.397 2.5561* 0.91.6 0.008 -0.509 -0.008 -0.785 0.035

11..

5

578.837 75.81.5 2.7298 0.951 0. 010 -0. 511* -0.010 -0.766 0.01.1 15.0 613.235 81.81.3 2.9119 0.956 0.012 -0.520 . -0.012 -0.71*5 0.01*6 15.5 660.778 88.1*28 3.1028 0.962 0.013 -0.526 -0.011. -0.721 0.050

METHANE ISOTHERM 1.00.0 DEG.

MOL/L P.BAR OP/DO OP/OT XB OXB/DD XC DXC/OD XO OXO/DO

0.5 16.507 32.789 0.01.28 1.314 -0. 199 -0.931 0. 395 -0.506 -0.052

1. 32.798 32.390 0.0880 1.21*0 -0. 111. -0.798 0.186 -0 .531* -0.059

1.5 1*8.915 32.098 0.1357 1.192 -0.080 -0. 725 0. 116 -0.565 -0.062

2.0 6i*. 915 31.923 0.1859 1.157 -0.061 -0.676 0.081 -0.596 -0.062

2. 5 80. 855 31. 850 0.2387 1. 130 -0.01*8 -0.61.1 0.060 -0.626 -C.061

3.0 96.780 31.867 0.291.2 1.108 -0. 039 -0.615 0.01*6 -0.656 -0.059

3.5 112.737 31.975 0.3521. 1.091 -0. 032 -0.591* 0.037 -0.685 -0.057

4.0 128.772 32.183 0.1.131. 1.076 -0.026 -0.578 0.029 -0.713 -0.053

If. 5 litk. 939 32.5C1* 0.1.771. 1.061. -0.021 -0.565 0.023 -0.739 -0.050

5. 161.298 32.951. 0.5i*l*l* 1.055 -0.017 -0.551. 0. 019 -0.762 -0. 0i»5 5.5 177.916 33.51.5 0. 611*8 1.047 -0.011. -0.51.6 0.015 -0.781. -0.01*0 6.0 191*. 868 3i*. 285 0.6885 1. C*l -0.011 -0.539 0.012 -0.803 -0.035

6.5 212.228 35.181 0.7659 1.036 -0.009 -0. 531* 0.009 -0.819 -0.030

7.0 230. C75 36.237 0.81*70 1.031 -0.007 -0.530 0.007 -0.832 -0.021* 7.5 21*8.1*93 37.1*66 0.9322 1.028 -0.005 -0.527 0.005 -0.81.3 -0.019

8. 267.575 38.895 1. 0217 1.027 -0. 003 -0.525 0.003 -0.851 -0.011* 8.5 287.1*30 1.0.572 1.1157 1.026 -0. 001 -0. 521* 0.001 -0.857 -0.009

9.0 308.195 1.2.533 1.211.6 1.025 -0.000 -0.521. 0.000 -0.861 -0.005

9.5 330.001* 1*1*. 736 1.3181. 1.025 -0.000 -0.521. 0.000 -0.862 -0.002

10.0 352.961* 1*7.132 1.1.277 1.025 0.000 -0.521* 0.000 -0.862 0.000 10.5 377.167 1.9.712 1.51.25 1.025 o.coo -0.521. -0.000 -0.862 0.002

11.0 1*02.710 52.1*96 1.6633 1.025 0. 000 -0.521. -0.000 -0.861 0.005

11.5 1*29.708 55.550 1.7902 1.025 0.001 -0.521. -0.001 -0.857 0.009

12.0 1*58. 321 58.970 1.9236 1.026 0.002 -0.521* -0.002 -0.851 0.011. 12.5 1*88.71*8 62.811 2.0638 1.027 0.003 -0.526 -0.003 -0.81*3 0.019

13.0 521.207 67.098 2.2110 1.029 0. 005 -0.528 -0.005 -0.832 0.025 13.5 555.925 71.855 2.3656 1.032 0.007 -0.531 -0.007 -0.818 0.031

li*. 593. 11* i* 77.1C7 2.5279 1.036 0.008 -0.535 -0.008 -0.801 0.036

11*.

5

633.120 82.886 2.6982 1.01.1 0. 010 -0.539 -0.010 -0.782 0.01.2 15.0 676.121* 89.226 2.8767 1.01.6 0.012 -0.51.5 -0.012 -0.760 0.01.7

132
METHANE ISOTHERM 1,20.0 OEG. K

MOL/L P.BAR OP/DO DP/OT XB OXB/DD XC DXC/DD XD dxd/od

0.5 17.362 31,. 51.7 0.01,27 U<»02 -0. 199 -0.951, 0.395 -0.510 -0.055

1.0 3ft. 556 3i». 2i.it 0.0878 L. 327 -O.lli, -0. 820 0.186 -0.51,0 -0.062

1.5 51.625 31,. 051 0.1353 L.280 -0.080 -0.71.7 0.116 -0.572 -0.061, 2.0 68.627 33.977 0. 1853 L.2i»5 -0. 061 -0.699 0.081 -0.601, -0.061, 2.5 85.619 3 ft. 008 0.2378 L.218 -0.01,8 -0.661, 0.060 -0.635 -0.063

3.0 102.650 3i».131 0.2928 L.196 -0. 039 -0. 637 0.01,6 -0.666 -0.061

3.5 119.766 31,. 31,9 0.3506 L.178 -0.032 -0.617 0.037 -0.696 -0.058

tt.O 137.017 31,. 672 0.1,111 I. 16ft -0.026 -0.6O0 0.029 -0.721, -0.055

ft.

5

15ft. ft58 35.111, 0.1,71,6 1.152 -0. 021 -0.587 0.023 -0.750 -0.051

5.0 172.153 35.690 0.51,11 1.11,3 -0.017 -G.577 0.019 -0.775 -0.01,6 5.5 190.172 36.1,13 0.6108 L.135 -0. Oil. -0.569 0.015 -0.797 -0.01,1 6.0 208.592 37.292 0.6839 L.128 -0.011 -0.562 0.012 -0.816 -0.036

6.5 227.ft92 38.335 0.7605 L.123 -0.009 -0.557 0.009 -0.832 -0.030

7.0 2ft6.955 39.51,7 0.81,0 9 L. 119 -0.C07 -0.553 0.007 -0.61,6 -0.025

7.5 267.069 1.0.91.2 0.9253 )L.116 -0.005 -0.550 0.005 -0.857 -0.019

e.o 287.931 1,2.51.5 1.0139 L.llft -0.003 -0.51,8 0.003 -0.865 -0.011, 8.5 309.657 i*i*. 1,06 1.1069 i .113 -0.001 -0.51,7 0.001 -0.871 -0.009

9.0 332.387 1,6.563 1.201,7 1.113 -o.coo -0. 51.6 0.000 -0.875 -0.005

9.5 356.263 1.8.973 1.3073 1.113 -0. 000 -0.51,6 0.000 -0.876 -0.002

10.0 381.391, 51.581, 1.1,152 11.113 0. 000 -0.51*6 0. 000 -0.877 0.000 10.5 1*07.879 5ft. 391 1.5286 1 .113 0.000 -0.51,6 -0.000 -0.876 0.002

11.0 1,35.821 57.1,13 1.61,77 ] .113 0.000 -0.51,6 -o.ooo -0.875 0.005

11.5 1,65.339 60.717 1.7728 1..113 0.001 -0.51,6 -0.001 -0.871 0.009

12.0 1,96.801 61,. 398 1.901*2 1 • Hi, 0. 002 -0. 51,7 -0.002 -0.865 0.011, 12.5 529.809 68.511 2.01,22 J .115 0.003 -0.51,8 -0.003 -0.857 0.020

13.0 565.188 73.083 2.1870 J .117 0.005 -0.551 -0.005 -0.61,6 0.025

13.5 602.972 78.135 2.3389 1 .120 0.007 -0.553 -0.007 -0.832 0.031

11*. 61,3.1,08 83. 695 2.1,983 1 .121, 0. 008 -0.557 -0.008 -0.815 0.037

1ft.

5

686.757 89.792 2.6653 1 .128 0.O10 -0.562 -0.010 -0.795 0.01,2

METHANE ISOTHERM 1,50.0 OEG.

MOL/L P.BAR DP/ DO DP/DT XB TJXB/DG XC OXC/DD XO DXD/DO

0.5 18.61,3 37.178 0.01*27 1.529 -0.199 -0.981, 0.395 -0.516 -0.059

1.0 37.188 37.015 0.0876 1.1.55 -O.llt. -0.851 0.166 -0.51,7 -0.065

1.5 55.677 36.961, 0.131,8 1.1.07 -0. 080 -0. 777 0.116 -0.580 -0.066

2.0 7i». 172 37.036 0. 181, 1, 1.372 -0. 061 -0.729 0.081 -0.611. -0.066

2.5 92.731 37.217 0.2361, 1.31,5 -0.01,8 -0.691, 0.060 -0.61.6 -0.065

3.0 111.1,06 37.1,97 0.2909 1.323 -0.039 -0.668 0.01,6 -0.678 -0.063

3.5 130.21,5 37.877 0.31,80 1.306 -0. 032 -0.61,7 0.037 -0.709 -0.060

ft.O 11,9.302 38.368 0.1.079 1.292 -0. 026 -0.631 0.029 -0.738 -0.056

ft.

5

168.635 38.986 0.1,705 1.280 -0. 021 -0.618 0.C23 -0.765 -0.052

5.0 188.312 39.71.8 0.5362 1.270 -0.017 -0.607 0.019 -0.790 -0.01,7 5.5 208.1,08 1.0.666 0.6050 1.262 -O.Oli, -0.599 0.015 -0.812 -0.01,2 6.0 229.005 1,1.750 0.6770 1.256 -0. Oil -0.592 0.012 -0.83? -0.037

6.5 250.188 1,3.010 0.7525 1.251 -0,009 -0.587 0.009 -0.81,9 -0.031

7.0 272.01,5 1,1,. 1,51 0.8317 1.21,7 -0. 007 -0.583 0.007 -0.863 -0.025

7.5 29<». 671 1,6.087 0.911,8 1.21,1. -0.005 -0.580 0.005 -0.871, -0.020

8.0 318.170 1.7.91,6 1.0019 1.21,2 -0.003 -0.578 0.003 -0.883 -O.Oli, 8.5 31,2.66 3 50.077 1.0931, 1.21,1 -0.001 -0.577 0.001 -0.889 -0.009

9.0 368.299 52.518 1.1893 1.21,1 -0. 000 -0.577 0.000 -0.892 -0.005

9.5 395.226 55.228 1.2901 1.21,1 -0.000 -0.577 0.000 -0.891, -0.002

10.0 1,23.562 58.153 1.3959 1.21,1 0.000 -0.577 0.000 -0.891, 0.000 10.5 1.53.1.11* 61.289 1.5069 1.21,1 0.000 -0.577 -0.000 -0.891, 0.002

11.0 1,81,. 890 61,. 657 1.6231, 1.21.1 0. 000 -0.577 -0.000 -0.892 0.005 11.5 518.120 68.321 1.71,57 1.21,1 0.001 -0.577 -0.001 -0.889 0.009

12.0 553.277 72.379 1.871,0 1.21,1 0.002 -0.577 -0.002 -0.883 0.011, 12.5 590.573 76.885 2.0085 1.21,3 0.C03 -0.579 -0.003 -0.871, 0.020

13.0 630.21,1 81.865 2.11,96 1.21,5 0.005 -0.581 -0.005 -0.863 0.026

13.5 672.522 87.31,3 2.2975 1.21*8 0.007 -0.581, -0.007 -0.81,8 0.032

METHANE ISOTHERM 500.0 OEG. MOL/L P.BAR DP/DD OP/OT X8 OXB/OO xc OXC/OO XD DXD/OD

0.5 20.775 ftl.5ft8 0.01.26 1.731 -0.199 -1. 026 0.395 -0 .523 -0.065

1.0 ftl.559 ft 1 . 6 C 3 0.0872 1.657 -0.11ft -0.893 0.186 -0 .557 -0.069

1.5 62.398 ftl.777 0. 13ft0 1.609 -0. 080 -0.820 0.116 -0 .591 -0.070

2.0 83.357 1*2.081 0. 1830 1.57ft -0. 061 -0. 771 0.081 -0 .626 -0.069

2.5 10ft. 1,98 1*2.501 0.231.3 1.51.7 -0. 0ft8 -0. 736 0.060 -0 660 -0.068

3.0 125.876 1.3.029 0.2979 1.526 -0.039 -0.710 0.0ft6 -0 .69ft -0.065

3.5 lft7.5<»5 1*3.668 0.31,1,0 1.508 -0.03? -0.689 0.037 -0 725 -0.062

i».0 169.56ft ftft.ft30 0.1.027 l.i*9ft -0.026 -0.673 0.0?9 -0 .756 -0.058

ft.

5

191.998 1*5. 331 0-i»6ftl 1.1*82 -0. 021 -0. 560 0.0?3 -0 .78ft -0.05ft 5.0 21ft. 922 1*6.390 0.5283 l.ft72 -0. T17 -0.650 0.019 -0 .809 -0.0ft9 5.5 233.ftl7 ft7.621 0.5955 l.ft6ft -0.01ft -0.6ftl 0.015 -0 ,83? -0.0ft3 6.0 262.573 1*9. 035 0.6658 1.1*58 -0.011 -0.635 0.012 -0 .853 -0.038

6.5 2B7.ftB5 50.61.2 0.739ft 1.1*53 -0.009 -0.629 0.009 -0 .870 -0.032

7.0 313.2ft9 52.ft50 0.816ft l.ft i»9 -0. 007 -0.625 0.007 -0 88ft -0.026

7.5 339.970 5ft. i»72 0.8972 l.itft6 -0. 005 -0.622 0.005 -0 .896 -0.020

8.0 367.762 56.738 0.9818 l.ftftft -0.003 -0.620 0.003 -0 .90ft -0.01ft 8.5 396.757 59.298 1.070ft 1. ft ft 3 -0.001 -0.619 0.001 -0 .910 -0.009

9.0 1,27.116 62.190 1. 1633 l.fti.3 -0.000 -0.619 0.000 -0 91ft -0.005

9.5 1,58.996 65.371. 1.2607 1. ftft3 -0.000 -0.619 0.000 -0 916 -0.002

10.0 1,92.529 68.796 1. 36 2 8 l.fti.3 o.roo -0.619 0.000 -0 916 0.000 10.5 527.831 72.ft52 1.1*697 l.fti*3 0.000 -0.619 -0.000 -0 .916 0.002

11.0 565.023 76.362 1.5916 l.fti.3 0.000 -0.619 -0.00 -0 .91ft 0.005 11.5 60ft. 2ft7 80.593 1.6993 l.fti.3 0.001 -0.619 -0.001 -0 910 0.009

12.0 6ft5.687 85.21.1 1.8223 l.ftft3 0.002 -0.620 -0.002 -0 90ft 0.015 12.5 689.567 90.362 1.9511 l.ftft5 0.003 -0.6?1 -0.003 -0 896 0.020

133
Table 12. The Joule-Thomson inversion locus

T,K P,8AR MOL/L T,< P.RAR MOL/L

160 1*1*. 51 21. 55 330 499. 31 15.41. 165 69.92 21. 53 335 501.. 06 15.26

170 9t. 12 21. 12 31.0 508.44 15.12

175 117. 19 20. 91 3*5 512. -5 14.96

iao 139. 22 2 0.71 350 51C 08 14.80

1.85 160.26 20. 50 355 519. 37 14. 64

190 180. *(i 20. 3C 360 522.30 14.46

195 199. b9 20. ID 3b5 524.87 14.32

2uQ 218. 17 19. 91 370 527. 11 14. U

205 235.90 19. 71 375 529. CI 15.99

210 252.91 19. 52 380 53 U . -.,7 13.83

215 269.23 19. 33 385 5 31.81 13.67

220 28*.. 91 19. 15 390 532.72 13.51

225 299.9b 13. 97 395 533.30 13. 3<- 230 31i». 41 13.79 1.00 533.56 13. If 235 328.28 13. il <»05 533.50 13.02

2<*0 341.59 18. +3 1.10 533.11 12. 8t 2*5 354. 36 13. ?5 1.15 532.40 12. o

c 250 366. 50 13. 08 420 531. 36 12.52

255 378.33 17. 91 1.25 529.99 12. 36 260 389.56 17.71* 430 528.28 12. 19 265 1*00.29 l 7

. 57 1.35 526. 22 12. 02 270 410.55 17. -»U I* 40 523. nl 11.85

275 42u. 3t 17. 23 i»If5 521. 04 11.67

280 1*29.67 17. 07 450 517.93 11.50

285 i*38. 54 Id. 9C -.55 514.51 11. 32 290 4fO. 98 16. 7i* 460 510. 81 11.14

295 454.97 15. 57 465 506.93 10.97

300 4b2.53 Id. +1 470 5 2.96 10.79

305 1.69.68 16.25 475 498.95 10.62

310 476. 4 1 15. 99 430 494. 94 10. fE 315 482.73 15. 92 485 1*90. 96 10.28

320 i»88. b5 15. 76 490 437 . 01 10. 1? 325 494. 18 15. iO 495 *S3. 10 9.96

134
Table 13. Thermophysical properties of the saturated liquid

For the following table we have used the Clapeyron equation to make the vapor

liquid transition at temperatures T < T = 174.516 K. For higher temperatures

we have computed around the critical point as described in section 3.4 of the text, with aid

from figure 1

.

Column headings have the following interpretations--

DP/DT = dP/dT, vapor pressure,

DDL/DT = dp^/dT , saturated liquid,

Q, VAP = AHva

p,heat of vaporization,

CV = CV

(P,T),

CS = C (T), a CP = C (P, T). P

135
Table 13. Thermophysical properties of the saturated liquid

T P DEN V.GiS l/.LIQ OP/OT DDL/OT Q.VAP £ H S Cl/ D£G K BAR MOL/L L/MJL L/MOL BAR/K MOL/L/K J/MOL J/MJL J/MOL J/MOL/K J/.1JL/K 90.68u 0.117 28. 1%7 63. 7837 0. 03553 0. 0151 -0. 0828 6720. l 3*71 9 3%72. 3 67 876 35. 10 92. OuG 0.139 28. 036 5% 7052 0. 03567 0. 0173 -0. 0831 8692. l 3537. 8 3536. 3 68 6*1 33. 02

9%. 003 0.177 27. 671 %3 7**9 0. 03588 0. 0211 -0. 0636 86*8. 9 3638. 9 3639. 5 69 779 32. 96

9b. 000 0.223 27. 703 35 3*19 0. 03610 0. 025- -0. 06*1 860*. 5 37%1, 2 37-2. 70. 899 3?. 96

96. 000 0.279 27. 53* 23 6252 0. 03632 0. U30 3 -0. 08*7 6558. 9 38%% 9 38%5. 9 72 002 32. 99

100. 000 0.3%5 27. 36% 23 7210 0. 0365% 0. 0359 -0. 085% 8511. 7 39%9 g 3951. 1 7 3 390 53. 0* 102. 000 G.%23 27. 193 19 5818 0. 03677 G. 0%2 2 -0. 0861 8%63. %055 9 %057. % 7* lo3 3 >. 06

104. J 0.515 27. 020 16 *565 0< 03701 0. 0*93 -c. 0669 8%12. 6 *163 1 %165. 75 222 33. 1 1 10b. 000 0.D21 2c. 8%5 13 3591 0, 33725 0. 0571 -0. 0878 8360. % %271 3 %273. 6 76 2d7 3 3. 12 106. 003 0.7%3 Zc. do9 11 7532 0. 03750 0. 0657 -0. C667 830b. 5 %380 % %383. 2 77 299 33. 13 110. 0G0 0.86% 2b. %90 10 3250 0, 03775 0. 0751 -0 0636 8250. 7 %%90 % %%93. 8 78 .318 33 06 112.000 1.0*% 26. 310 3 6036 0. 03801 0. 085% -0 0906 8193. %601 2 %6'35. 2 79 ,32* 32. 98

114. bud 1.22b 26. 126 7 %2%% 0. 03627 0. 0966 -0 0917 8133. 5 %712 7 %717 % 80 313 32. 89 lib. 000 l.%31 25. 9%3 o *399 G. 0^855 G. 1087 -0 0928 8C71. 9 %82* 9 %830 % 61 ,298 32 7o 116. 000 1.662 25. 756 5 6131 0. 3 86 3 0. 1218 -0 09*0 6008. % *937 7 *9*%. 2 82 2o7 32. 63

120. 000 1.919 25. 567 + 91*6 . 03911 0. 1356 - 0. 0953 75*2. 7 5051 ,1 5058 b 83 ,ZZ3 32. %3 122.000 2.205 Z5. 375 -t 3213 0. 039%1 0, 1507 -0 0966 767%. 6 5165 1 5173 6 6* 1-36 32 3Z 12%. 000 2.523 25. 180 3 81*8 0. 03971 c lbo7 -0 0980 780*. 7 5279 7 6269. 7 86 132 32 17 12b. 00 J 2.873 2-,. 963 3 .3832 a. 0*003 0. 1837 -0 0995 7732. 1 539* 9 5*0b. % 8b 026 3Z 02 126.000 3.258 2%. 763 3 3 56 0. 0%035 2017 -0 1010 7157, 5510 8 5523. 9 86 9*0 31. S3 130. 000 3.681 2%. 579 -> 6812 0. 0*Cb9 G, 2208 -0 1026 7679. 2 5627 3 56*2. 2 67 3** 31 75 132.000 *.1%2 2-. 372 Z ,3931 0. 0%103 0. 2*09 -0 10%3 7%98. 5 67%% E 5761. 5 68 7*1 31 6% 13%. 000 %.6%5 2%. 162 z ,1528 0. 0%139 2621 -0 1061 7%1%. 8 5662 6 5881 6 69 630 31 53 13b. OoJ 5.191 23. 9%7 1 9339 0*176 0. 28*3 -0 1080 7327. 8 5981 % 6033. 1 90 512 31 *7 138.000 5.7o3 23. 729 1 7*o9 0. 0*21* 307b -0 1100 7237. * 6101 .2 6125 e 91 ,338 31 -.2 1*0.000 o.%22 23. 507 1 5731 0. j*25* o. 3321 -0 1121 71%3. % 6222 G 62*9 3 92 ,239 31 36 1%2.000 7.112 23. 261 1 ,%335 0%295 3576 -0 11%% 70*5. 5 b3%3 6 637% % 93 125 31 35 1%%. 000 7.853 23. 050 1 293% 0*338 38*2 -0 1168 69*3. 6 b%b6 8 6500 9 93 937 Jl 33 L%6.00G 8.6%9 22. 813 1 ,1805 0%383 *120 -c 119% 6637. 3 b?90 ,9 6628 8 9* .8*5 31 31 1*8. J 9.502 22. 572 1 0751 0. d%%30 G. *%09 -0 ,1222 6726. 5 6716 ,3 6756 % 95 ,731 31 29 150. 000 10.%1% 22. J2-. J 98 J6 Q 0%%79 %71C -0 1252 6fl0. 6 6e%3 C 6839 6 96 55% 31 2a 152.000 11.387 22. 071 3 ,8955 0%531 G 5022 - 1285 6%90. 1 b971 7022 b 97 ,%0b 31 22 l^.Cuu 12.*23 21, blO 3 ,8138 0. 0*585 G 53*6 -c 1321 b3o3. 9 710C 5 7l?7 % 96 2p6 31 15 15b. 0U0 13.526 21. 5%2 J .7% 3% 0%fc%2 5683 -0 1360 6^32. 1 7231 ,% 729% 2 99 ,105 31 05 156. 000 1%.697 21. 2bb 08 j5 0%702 C 6031 -c 1%03 609*. 2 7363 6 7% 53 99 .95* 3 ) 9 i lbO. 0U

J

15.939 20. 961 .62 3% 0*76b Q b333 -0 1%51 59*9. 8 7%97 ,9 7673 9 ICO .80% 3.; 7 3 162. GOO 17.235 20. c8j J 5773 3 Ijh6 3* 67b7 -0 1505 5793. 5 7633 6 7717 2 101 05 5 3 j 60

lb%. OuQ 18.6%7 20 o78 1 .5237 ,0%907 7155 -0 .1565 5639. 5 7771 ,6 7863 .1 102 .508 3 J *0 166.000 20.116 2i u59 J ,%8al 0*985 7557 -0 163% 5%72. 1 7911 ,6 8G11 9 103 . 366 3~f 19 166. 000 21.b71 19 72* 3 . **6 05G70 G 7973 -0 ,1713 5295 - 605% ,G 8163 a 10* .229 2 i ,99 170. 000 23.308 19. 373 J ,*J 32 05162 6*0% -0 1805 5108. 1 8199 ,3 8319 7 105 .101 2 i 81 172. 000 25.03% 19. 001 a ,3750 05263 6851 -0 1913 %908. 6 63*8 2 e%79 .9 105 .936 23 ,69 17%. 000 2t>. 850 18. c06 3 .3*3% U3375 9316 -0 20%1 %t9%. 8 8501 2 8t*5. c 106 838 2 i 67 17b. 000 28.761 16 183 .3159 05500 9798 -0 ,2198 %%63. 9 8660 ,% 8618 6 107 .31% 3 j 19 176. 000 30.771 17 725 J ,26il 036*2 1 30 1 -0 2393 %212. 6826 3 8999 9 108 .776 3J 3 6 180. 000 32.863 17 222 3 .25 39 05606 1 ,0626 -0 .26*3 3933. 5 9000 .7 9191 , 6 109 .779 33 b- 182.000 35.103 lb 662 3 .23*9 Gb002 1 1377 - 2977 3620. * 9166 .0 9 3 96 7 110 .859 31 ,06 16%. 000 37.%35 lb. 022 a .2136 062%1 1 1958 -0 3%53 3259, 9 9386 .6 9620 3 111 .933 51 72 166.000 39.888 Is 263 3 .1835 06652 1 2579 -0 ,%205 2830. 1 9610 ,2 9671 5 113 .256 32 77

168. 000 *2.%71 1% 29* 3 .lolb , Ub996 1 ,3257 -0 ,5690 226% 7 987* .3 10171 % 11% . 7o6 3, 75 190. 000 *5. 199 12 721 J 1321 .07861 1 ,%06% -1 .2723 1%30 1 10258 .3 10613 ,b 116 .998 %1 .07 190. 55a %5.986 lJ UuO . 1J 30 10000 1 **51 a 106*1 ,2 11301 1 120 .5/*

cs J/MOL/K

52.7%

52.33

53.05

53. 33 53 . oi> 5-. 01 5*. 3o 6-. 72 55.0o

55.33

53. c9 55.96

56. 2o

5b. 52 5b. 73 57.0%

57.33

57.58

67. 37 58.19

53.53 56.91 59.32

F9. 77 60.25

6J. 76 fcl.3% 61.9-

62.37

6 5.23

6 5.93

6*. 6b

6 3 . * 2 6b. Z3

6 7.08 66.00 69.01

70. 1Z 71. 39 72. 3 = 7* .61 7c. 73 79.3b

t 3 . u 9 87.23

92.5 9 49.81

llu . 19 126.05

16 J --7 326.27

CP J/MOL/K

52.75 52.65

53.07

53.36 53.69

5-. 05 5%.%1

5*. 78 55. 13 55. %7 55.80

5b. 11 56. %0 56.69

56. 98 57.28

57.58

57. 9C 58.2%

68.62

59.03

59. %8 59.97 60.52

1.11 61.75

62. %5

63. 2u 6*. 01 6%. 68 b5.80

bb. 30 57.37 j b9.03

70.30 j 71.71 73.29

7 3.10 77.20 79.70 82.72

66. *7 91.19

97.72

106. 7% lib. 71 132.60

157.71

203.50

315. *1 1130. 911

136
Table 14. Thermophysical properties along isobars

The following pages give physical and thermodynamic properties along selected

isobars, as computed by methods of section 3 of the text.

The first table is for the triple -point pressure, P = 0. 117 436 bar ( 1 . 70326 psi).

The first line of each table refers to freezing liquid on the P(T) melting line.

Each table at P< P contains a blank line for the transition from saturated liquid

to vapor, as seen by the abrupt decrease of density.

Table headings for partial derivatives have the following interpretations--

DP/DT s SP/ST,

DP/DD = dP/dp.

The specific heat interpretations are--

CV = Cv

(p,T),

CP = C (P,T). P

* These tables are extrapolated beyond the range of P-p-T data used for adjusting the

equation of state (T - 400 K, P~ 350 bar).

137
M£THANE ISOBAR IT P = 0.117 436 BAR

T OtN VOL DP/DT OP/OO E H S C\l CP H Oi:g k MOL/L L/MOL BAK/K BAR-L/MCL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K 1/StC

90. 680 28.1*7 0. 03553 20. 72*9 25C 15* 3*71. 9 3*72. 3 67. 878 33. 10 52. 7s 15/3

90 , 680 0. 015o8 63. 781 0. 301310 7. *3* 11*29. 1 12178. 1 16 .. 0*2 25. 35 33. 5/ 2*9

93.,000 G. 01*95 66. 876 0, 0012*9 7, 801 11538. 5 12323. lo5. o03 25. 03 33. E 5 25 3 103..300 u < 31*19 70. *52 0.,001185 6. 22* 1166*.,9 12*92. 2 167. 32 2 25. 02 33. *9 2o2

135. 000 o. 01351 7*. 025 0.,001127 6,,6*7 11791., 1 126oG,,5 168.,955 25. 31 33. *3 2i>i 110. 303 0. 31289 77. 593 0. 001u7* 9. 066 11917. 3 12828. 5 170. 510 25. 30 53. *5 27 j 115,,000 0.,01232 31. 159 0..001027 9,,*d9 120*3,,* 12936., 5 171. 996 25. 00 33,,*2 2dl

123. 300 0. 0118G 3*. 722 o. 000963 9. 909 12169,,* 131o*.,* 173.,*18 2*. 99 33,,h] 2B/

125,,000 0. 31133 dd. 283 0. 0009** 10 . ,329 12295. * 13332,,2 17*. 781 2U, 99 33, 39 295

130..300 c. 01389 91. 8*3 0. 000907 10,,7*8 12*21,,* 13*99,,9 170. 091 2*. 99 53,, 33 29 4 135..300 0. 010*8 95. *01 0.,300873 1 1.,167 12 5*7,,3 13b67.,0 177.,350 Zi*. 99 S3. 3/ 3 j wo. OGU 0. 01G11 98. 957 0. G0u6*l 11,,585 12673.,1 13835,,2 178., 5o* 2*. 9 9 33,,3/ 311 1*5,,300 0. 0097a 132. 513 0., 003612 12,,30* 12799., G 1*032,,9 179. 735 2*. 99 33,,37 31c

150,.300 0, 009*3 136. G5d 0,,00078s 12,.*22 1292*..8 1*170,,5 180. 806 25. 30 33, 37 321 155,,000 c.,00912 139. 621 0. 000759 12, 8 39 13050.,7 1,338,, 1 181. 960 25. 31 33, 37 327

163.,000 0. 0088* 113. 17* 0.,000735 13,,257 13176.,6 1*536,,7 183.,020 26, 02 53. 33 332 lo5 , ,000 0. 00857 116. 727 3,,300713 13,,575 13302, c 1,0/3,,3 18*., 0*7 26, 33 33, 39 33'

170,,300 G. 00831 120. 279 0.,000b92 1*.,092 13*28,, 5 1*3+1,.3 185,,0** 25,,3* 33,,,3 3*2

175..300 0. G0808 123. 830 o., 00Go72 1*. 509 1365*.,5 15036,,7 18o,,012 2 5 , ,36 S3.,Hl 3*/

130,,300 0., 00785 127. 381 0.,000o53 1*.,927 13680,,e 1517b,.5 186,, 95* 26..38 53 ,*5 3jZ

ltJ5,,300 0..0076* 130. 931 0., 00053b 15,, 3* + 13606,,8 1 33**,* 18/,,87 26,, 1 1 3 3 . ,*5 3-} 7 190 , , 300 G,. 007** 13*., *dl 0,, 000619 15,.761 13 933,. 2 15512,.5 183,,7t2 25,,13 33,, * ^ (6 I 195., 300 0. 00/2* 138. 031 o. 00uoC3 16., 178 1*059,,7 15630,ib 189,,633 25,. 1/ 33,,6 1 3o j 233,,300 0., 00/06 1*1. 530 0., 300568 16.,59* l*18o.,3 133-.9.,0 19j,,*ai 25,,21 33 ,53 3/1 z^5,,300 0. 00689 1*5.,129 0,, CCC573 17,,011 1*313, 2 16017,,5 191,, 310 25,,25 3 5,,6 i 37.

213,,300 0.,00b73 1*8. 673 0,, OOGscG 17,,*28 1***0,2 1 fc 1 3 6 ..3 192. 121 25. 30 53. 6* 3d J 215.. 300 G. 00o5? 152,,227 0,,0035*7 17,,ds5 1*567,,6 16355,,3 192,,913 26,, 3c 33,,7 J 3d* 22 3,. 303 0., 006*2 155. 775 0,, 00053* lo.,261 1*695., 2 16 52*.,6 193,,686 25,, «2 (3,,76 389

225,,300 0.. 00628 159. 323 0,, 3 5?Id,, o7o 1*623,,2 Ib6 J*,, 2 19*., **d ?6,,*° 53,,03 3 3 j 23u,,300 0.,00614 lo2.,871 0,, C C a 1

19,,39* 1*951. 5 1683*.,2 195. 192 25. 57 33, 91 3 3.' 235., JQU 0,, GOoOl 166,,*19 3,.O005G0 19.,511 15C80,,2 1703*.,o 195,,92 2 26,,66 53 .93 *01

2hJ , , 300 0,, 3o56c 169. 967 0,, 000*89 19.,927 15209,, 3 17235 ,* 19o,,b39 25.,75 3*.. 03 * 5 2*3,,000 0,,3u57b 173, 51* 0,,003*79 20., 3** 15339,,0 173/6,,6 197,, 3*3 26,,o5 5*.,1 J ,3 3 250,,000 G.,005cs 177., 061 0.,300*70 20..760 15*69., 1 i75*e.. * 19a,, G3* 25. 96 3* , 2 i *13

Zoi,.330 0., 0035* HO., 63d 0,,000*61 21,,177 16599,,8 17720,,8 19a,, 71* 26.,37 3, * J *1.' 260 , , 300 0.,003*3 Id*. 135 0,, 000*52 21,,393 15 7 31,,0 178 i 3,,7 193,,3&^ 2b.,20 5* ,E 5 *2l

2o5,,3u0 0,, 0G533 137. 702 0,, u**3 22,,009 15862,,9 180o7

,2 2 C J , ,0*2 26,, S3 5 - , , c c -?3

270., 303 0. 00523 191. 2*3 0., 000*35 22., *2o 15995. 5 102*1., * 203,,b92 26,,*7 3*.,73 *2;

Z73,.300 0., 00313 1 *<t. 7 90 0,,000*27 22,,8*2 16123,, 6 l«*lb .* 201,, 331 26,,61 5* , 5* * 3 7 283..000 0,, 005G* 1 id. 3*2 0,,000*19 2 i,,25d lc262

,8 18532.,0 201.,9o2 26,, 77 56 . . 1 j *3^

2d5,,300 0., 00 *95 2 3 1., ddo 0,.000*12 23., o 7* 16397,,6 1 87o8., 5 202,,535 26.,93 35. 2-. * f .. 293.. OOu 0. 00*0 7 235. ^,35 o,, 000*05 2*.,091 lbi 33,,2 139*5..8 20 i,,203 27,. 10 56 , ,* 3 **5

Z-i-i ,300 0,.00*73 23d,.981 0,, 00 j398 2 *,,507 16669,,7 1912 3 ,9 20 i,,837 27,,28 35,. to * * 3UJ .000 c,, 00*71 212,.527 0,,000391 2* .923 16807.. 1 19302., 3 20*.,*36 27,,*6 55., 79 *3 J 313..300 0,,00-55 219,.619 0,,000379 25,,756 17 Ge*

.7 19o53.,8 205., 58c 27. 85 5b.- 13 ".5/ 323 . 300 0,,00**1 226,,711 0,. 000367 26 .568 17366,,H 20028 .7 203,.7*1 26 .27 5 6 . 59 *o i 33i,, ObO G,, 0l*28 233,, 602 0.,000356 27,,*20 17652,,2 2C337,,9 20/.,37* 28,, /l 57 . ,u 3 *^ j 3*0 .000 0,,00*15 2*0,,89* 0., 0003*5 20 ,252 17 9*2,, b 207/1., 6 208 .986 29,,17 57 , * 3 *7o

353 .300 0,.00*03 2*7,,985 o.. 0G0335 29.. 08s 16237., 7 211*9.,9 213.. 080 29.,o5 57 . 5 7 *32

3o0 .300 G,,00 39 2 255,,075 0..000326 29 .91/ 18537.,7 21533 .2 211., 13/ 30,,15 53.,*3 <03

370 .000 0,,0038 1 2o2,, 166 0.,000317 3o . .7*9 168*2..8 21921.i 5 212,,218 3 0.,o7 58 .93 ,9*

383 .000 0,,00 371 269,,256 0,,000309 31 .581 19153., 1 22315,,1 213,, 2o5 31,,20 59..52 *'3 ) 393,.000 0,,00 36 2 276,, 3*6 0,, 000301 32 ,*13 19*o8.,e 2271*.,1 21*., 296 3 1,,75 * . , C 503

*33..000 G,,00353 283.,*36 0,,000293 33,.24.5 19789,.9 231ie.,5 215,, 320 32, 30 + o.• b2 510 *20 .000 0.. 00336 297,,616 .000279 3* .909 20**9,. 239** .1 21/,,329 33,,*3 '4 1 .75 521 **0 .030 G,,00321 311.,795 0,, 000267 36,,57* 21130,,9 2*792,,5 219,, 298 3L,,58 *2 ,93 532

* O .000 0,, 0G3G7 325,,973 0,.000265 38 .238 21835,.9 256o*..0 221,,230 35,,7* **.. 6 5*2 *30 . 300 0,, 0029* 3*0. 151 0,. 0002** 39 .901 2256*.. 1 2655 8

.6 223,,130 36,,90 *5.,22 552 530 .300 0,, 00282 35*., 328 0.,000235 *1 .565 23315..3 27*76.,

22*.,999 36,,05 *6., 3,' 562

138
METHANE ISOBAR AT P = 0.5 BAR

T DEN VOL DP/DT DP/DD E H S CV CP U OEG K MOL/L L/MOL BAR/K 6AR-L/M0L J/MOL J/MOL J/MOL/K J/MOl/K J/HOl/K 1/SE.3 90,,690 28.11.8 0. 03553 20.7236 250,,205 3*72., 3*73.,7 67,,88 33,,10 52,,75 1576

95,.000 27.789 0.03599 19.6133 233.,73* 3689,,6 3691,.* 7J,, 338 32,,96 53,,23 153*

100.,000 27.365 0. 03651* L 8. 3 8 59 21*,.90* 39*9,,6 3951,, * 73,,088 33.,0* 6*., 05 1*0 'J 103,.701 27. u*6 0.03697 L7.5167 201,.267 *1*7,,0 *1*8,,8 73,, 06* 33,,11 5*.,72 1**3

103,,701 0.05919 lo. 895 0,, 306001 8,,269 11719,,2 12563,,9 156,,2ol 25,,23 3*,, 1 3 26*

105,.000 0.0561*2 17. 119 0,.00*932 8,,386 11752,,* 12608,,* 15o,,68 6 25,,22 3*., 1* 2oo

110,. J00 0.05562 1 7 . 97 8 0,i 00*b86 8,.831 11880., 1 12779,,0 153., 271 25. 17 3*., Ul 273

115,, J00 0.05309 18. 83* 0,.0C-**65 9,,271 12007,,3 129*9,,0 153.,731 25, 13 33, 90 279

120,.000 0.05060 19.687 .001*266 9,,709 1213*.,2 13116,,6 161., 222 25, 10 33., 82 23o

125,,000 0.01*869 20.537 0,. 00*085 10,, 1** 12260,,9 13237.,8 162..c01 25. 36 33. 7a 292

130,,000 0. 0*o7b 21. 385 0,, 003919 10,,577 12387,,i* 1 3*5b.,7 163,, 92* 26, 37 53,,70 293

135,,000 0. 0i*<*96 22.232 0,.003767 11,,008 12513,,7 13b26,,3 16 5,,195 25.,36 3 3 , , CO 30*

1-tO.,000 0. 0^333 23. 077 0,, 003627 11.,*37 12639. 9 13733..8 16o. *18 26. 35 33,,63 339

1-.5,,000 0.0*181 23.920 0,, 003*97 11,,865 12766., 1 139o2,,1 167,,596 25,,35 33,,b3 31 -j 150,,000 0. 01.038 2*.7o3 0,, 003376 12,,292 12892.,1 1*130,,3 163,, 73 6 25,,35 33, 58 32C 155 , , 000 0. 03906 25. 6J5 0,, 00326* 12.,718 13018. 1 1*298.,* 169,,637 25,,35 33, 5 5 326

16.0,,000 0.03781 26. i*-*b 0,.003159 13,,1** 131**,, 1 1 **o6 , ,* 17J ,902 25.,35 53,, 5 5 331

165,,000 C. 03b65 27.286 0,, 003U61 13,,568 13270,,1 1*63*,,1* 171,,935 25,,06 53,,5* 33o

170,,000 0. 03556 28. 125 o,, 002968 13..992 13396,,1 1*802,.3 172,,936 25,,07 53,,6* 3*2

175,.000 0. 031*53 28.96-. 0,, Q02682 1*,,*15 13522,,1 1*970,,3 173,,938 25,,39 S3,,5h 3*7

180,,000 0. 03355 29. 802 0,.002600 1*,,837 13 6*8,,2 15138,,3 17-,,, 85 3 25,,10 33,, 5 5 352

165., 000 C 03261* 30. 6*0 .002723 15,.269 1377*.,3 15306,.3 175,,77 3 26,,13 33,,57 3 56 190,,000 0.03177 31.1*77 0,, 002660 15,,681 13900,,6 15*7*., * 17o., bo 8 25, 16 33.,69 3bl

195,,000 0. 03095 32.31* 0,,002561 16,,102 1*027,,0 156*2,,7 177,,5*1 26,,19 33, 61 36u

2 0,,000 0.03016 33. 151 0,.002515 16,,523 1*153. 5 15811.,1 173,, 392 25. 23 33. 6* 371

205,, 000 0.029i*2 33.987 002*53 16,,9** 1*280,,2 15979,,6 179,,22 3 25,,27 33,,68 375

210,,000 0.02872 3*. 823 o,.00239* 17,,3b* 1**07,,2 lbl*8,, * 183,,035 26,,32 53,,72 380

215,,000 0. 02801. 35.659 0,, 002336 17,,76* 1*53*,,1* 16317,.* 183,,630 25,,37 3 5,,77 3d, 220. 000 0. 027i*C 36. 1*95 o,, 00228* 18,,2C* 1*661. 9 16*3b.,6 181., 607 26,,** 33,,6 5 366

225,,000 0.02679 37. 33J 0,,002232 18,,o23 1*789,,7 16656,,2 182., 368 25,,51 53., 9 395 23U.,000 0.02620 38. 165 0,,002183 19,,0*3 1*917,,8 16826., 1 163,,11* 25,, 56 53,, 9^ 597 235.,000 G.0256* 39. 050 0,.002136 19,,-*c2 15C*o., * 1699c, * 183,, 8*5 25. 67 3*., U5 *Q1

2*0,,000 C. 0251U 39.835 0,.002092 19,,381 15175,,3 1715 7,.1 18*,, 5o3 25,,76 3*,, 1* -0 > 2*5,,000 0. 02*59 +0.670 0,, 0020*8 20,,299 1^30*.,8 1?333,,3 185,, 26 8 25,,3L 3*,, 2* *U :> 250., J00 0. 2i*0 9 +1. 50* 0,.002007 20,,718 151-3*,,7 175J9..9 185,, 9o0 25,,97 3*,, 3~ *1 5 255. 000 0. 02362 +2. 339 0,. J0iye7 21,,137 165o5,,2 17682,.2 18o,, 6*1 i6,, u 6 3*,,*5 *17

260,,000 0. 0231b *3. 173 0,, 001929 21,,5 55 1569o,,3 1785 5,,0 187,,312 26,,20 3*,, 5 7 *21

2b5.,000 0.02272 <*i». 007 0,.001893 21,,973 15828,,0 18028,,* 167,,971 26,,33 3*,,73 *2:> 270,,000 0.02230 **• 61*1 0,, 001857 22,,391 16960,,1* 18232,,* 188,,621 26,,*7 3*.,6* -.2 J 275,,000 0.02189 *5.675 0.,001623 22,,809 16093,( c. 18377,,2 189,,26 2 26,,o2 5*,,93 -.32 260. 000 0.02150 -.6.509 0,, 001791 23,,227 16227,,3 18552,,7 189,,693 26,,7? 35,,13 *3^

235,,000 0.02112 +7. 3*2 0,,001769 23,,6*5 16361,,9 18729,,0 193,,517 26,,9* 35,,2 3 -3 3 290,,0 00 0.02076 *8. 176 0,, 001726 2-*,,062 161.97,, * 18936,,1 191,,13 2 27,,11 35 , ,*o -r* 5 295.,000 0.0201*0 *9. 009 0,,001c99 2*.,*80 16633- 6 1908*.,1 191. 7*0 27. 26 35. 6* **o

300,,000 0.020C6 *9. 8*3 0,,001670 2*.,398 16770,,8 19253,,0 192,, 3*0 27,,*7 56 . ,82 * 5 j 310,,000 0. 0191*1 51.509 a,, 001616 25, 732 17C*8., 1 19o23,,5 195,,521 2 7.,36 3b. 21 *5 7 320,,000 C. 01861 53. 17c 0,,001566 26,,567 17329,,3 19938,,1 19-,,,677 28. 27 36.,62 -03

330. 000 0. 01823 5*. 8*2 0,,001518 27,,*01 1761*.,6 20356,,9 195,,810 28. 71 57,,0 j *73

3i*ti,,000 0.01770 5c 506 0,,0G1*?3 28,,236 1790*.,8 207 50,,2 19 j,,923 29, 17 37,,52 „7o

350,,000 0.01719 58. 17* 0,,001*31 29,,069 16199., 5 21108,,2 198.,018 2°.,66 58,,00 -.82 360.,000 0.01b71 59. 839 o,, 001391 29.,9u3 18*99. 1 21*91. 193. 395 3C 16 38,,53 *33

370,,000 0.01o26 61.505 0,,001363 30.,736 16803,,8 21679,,0 203,, 157 30, o7 39, 01 *9*

380.,000 C. 01563 63. 170 0,,001317 .. 31.,570 19113.,7 22272,,2 201.,20* 31. 21 59. 5* *9 J 390.,000 0.015*2 6*. 835 0,.0012R* 3i,,*Q3 19*29.,0 2267 0., 8 202. 233 31. 75 -tO. 39 5U5

1.00,,000 0.01501* 36.500 0,,001251 33,,236 197*9.,8 2307*.,8 20 3,, 26 32,,30 *3, 6* 511 *20.,000 0.01i*32 69. 630 0,, 001192 3*.,902 20*08.,1 23699,,6 205, 27 33. ** *1, 77 521

41*11, 000 0. 01367 73. 160 o.. 001137 36,,566 21089,,3 2*7*7,,3 207,,2*0 3*. 59 *2.,92 532

i»60.,000 0.01307 76. 1*89 0,,001068 38,,233 21793,,6 25618,,0 209,,17 3 35, 75 -**, C8 5*2

1*80.,000 0.01253 79. 817 0,,0010*2 39,,898 22521.,0 26511.,9 211. 073 36. 91 *5. 23 552

500.,000 0.01203 83. 1*6 0,,001001 *1.,563 23271.,6 27*28.,9 212. 9*3 38. 06 *6. 3d 5b2

139
M£ THANE IS03AR AT P 1.0 BAR

T UEN VOL DP/DT OP/DD E H S CV CP A D£G K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MCL/K J/MOl/< 1/SEC

90. 703 29. 1*9 0.03553 20.7220 250. 272 3*72. 1 3*75.,7 67, 832 33. 11 52. 75 15 7,' 95. 000 27. 791 0.05598 19.615* 233. 656 3689.,0 3692,,6 70,,333 32,,96 53,,20 153 + 100. 000 27. 367 0. 03b5* 18. 3665 215. 036 39*9. 3952. 7 73. 082 33. 0* o *

.

+ 1*81

105. 000 26.935 0.03713 17.2222 196. 69* *21o

,

,5 *220,,2 75. 7*1 33. 12 5*. 95 1*26

110. 000 26. *9l 0.03775 16. 11C9 178. 956 4*90. 3 4494,,0 76. 317 33. 06 35,.7 3 1372

111. *7Z 26.358 0.0379* 15.7932 173.,861 4571.,9 ^57 5.,7 79.,0b0 33. 01 56. 03 l35o

111.,"72 0.11170 6.953 0.00954b 8,,631 11686.,* 127dl,> 6 152.,69 7 26, 42 3*, 8 5 272

115. 000 0. 1079* 9.265 0.0 9198 6,,962 11977. 9 1290*,,3 153. 780 25. 35 3*. 67 275

120.,000 0. 10306 9. 703 0.008753 9,,*25 12106,,9 13077,,2 155,,251 25,,28 5 * , , + 7 283

125,,000 0.09863 10. 139 . 006356 9. 882 12235. 3 132+9.,3 156. 65* 25. 23 3*. 31 2d9

130.,000 o.o9*58 10.573 0.007996 10,,33h 12363,,3 13*20,,6 157,,997 25, 19 3 + , 13 2 jo 135. 000 0. 0906/ 11. 01* 0. 007670 10, 762 12*90,,9 13591,, * 159. 285 25, 16 3*, 03 302 1*0. JOO C. 067*6 11. 43* 0.007371 11. 227 12618,,2 137ol,.7 16 . ,52 3 25,,1* 3 + , ,00 33 8 ltp. 000 0. 08*30 11. 8o3 0. 007096 11, 068 127*5. 3 13931,,6 161. 715 25,,12 33,,93 313

150.,000 0.06137 12.290 0. 00oB42 12,,108 12872,,2 1 * 1 J 1

,

,2 162,, 6o5 25,, 11 53,, 87 319

155.,000 0. 07864 12.717 . 00bb07 12, 645 12999,,0 1*270,.6 165, 975 25,, 11 33, 6 5 32-j 160.,000 C

.

07bG4 13. 1*2 0.00o3e8 12,,980 13125,,6 1**39,.8 165,,0*8 25,,11 33. 79 33J

lo5. 000 0. 07371 13. 567 Q. 00bl8* 13,,414 13252,,1 1*638,.8 16o,, 067 25, 1 1 33,, 7 7 33?

1/0.,000 0.071*6 13.990 0. 005993 13,,8*6 13378,,6 1*777,,7 167. C95 25, 11 13,,75 3*1

175.,000 0. 0693o 1*. *1* 0. 00581* 1*.,277 13505,,1 1*9+6, 5 163,,073 25,,12 53,,73 3*o

It) J

.

000 0. 067*0 1*. 837 0. 0G56*b 1*. 7G7 13631. 6 15115,,3 169. 023 25., 1* 33,,7 5 351

las.,000 0.0655"* 15.259 0.005*87 15,,136 13758,,1 1523*,.0 169,,9*7 25, 16 53 , 73 35o

1 JO,,000 C. 0o377 15. 631 0.0 05337 15,,56* 1388*.,7 15*52,,8 170,.6+7 26,,18 33, 7 + 3oJ 145,, 000 0. 06210 lb. 102 0.005196 15,,991 1*011,,* 15621,.6 171,,723 26.,21 33,,73 3a5

200,,000 0. 06052 lb. 523 0.005062 16,,*18 1*138,,2 15790,,5 172,,57 8 2 5.,25 S3,,77 37^ 205. 000 0. 05902 16. 9** 0. 00*935 lb. 8** 1*265,,2 15939,.6 17 3, 412 25,,29 33,,80 315 210,,000 0.05759 17.36* 0. 00*81* 17,,269 1*392,,* 16128,.8 17*,,227 25, 3* 13, 8* 37 i 215,,000 0.05623 17.73* 0.00*699 17,,693 1*519,,8 16298,,2 175,,02* 25, 39 33, 83 33*

220,,000 0.05*93 16.20* 0.00*590 16,,118 1*6*7..5 1 6*6 7

,

.9 175. 80 3 25. *6 33. 93 333

225. 000 0. 05369 18.62* 0.00**65 18,,5*1 1*775,,* 16637,.6 17 j,,557 25,,52 33, 99 392

230,,000 0.05251 19. 0*3 0. 00436b 18,,96* 1*903,,e 1 6 S 3 8 .1 177,,31 + 25.,60 3*.,05 397

235,,000 0.05138 19. 433 0.00*291 19,,367 15 3 2,, * 16978,.7 17 8,, 0*8 25., 68 3*,,1* *C1

2*0,,000 0.05030 19.832 0.00*199 19,,810 15161,,5 171*9,.7 17b, 767 25. 77 3*. 22 *05

2*5,,000 0. 0*926 20. 30J 0.00*112 20,,232 15291,,1 17321,.1 179,,4/4 25,,87 5*., 31 40 9 250,,000 0. 0*826 20.719 . 00*026 20,, b5* 15*21,,2 17*93,.1 18J,, lo 8 25, 98 3*.,41 + 1 i 255,,000 0. 0*731 21. 138 0. 0039*6 21,,075 15 551,.6 17665, 5 160,,050 2t,,09 5*,,52 *17

260,,000 0. 0*o39 21. 556 0. 003871 21. *9o 15662,,9 17638,, 5 181. 522 26. 21 3*,. t + 42 1 2o5,.000 0. 0*551 21.975 0.003797 21,.917 1661*.,7 18012 .2 18 2,, 133 26., 35 5* ,7a -25

2/0,,000 C. 0**6o 22. 393 0. 00372b 22,,338 159*7,,2 18136,, * 182,, 634 26, *8 5*. 9 ) *23

275,.000 C.0*38* 22.611 0.0G3b67 22,.759 lbC60 , .3 183ol,.* 183,,-75 26,,63 55,, 0* + 32 280,,000 0. U*305 23. 229 0. QG3p°l 23. 179 1621*,,2 18537,,1 184,,108 26,,78 35,,14 4 3b 2B5,.000 0. 0*229 23.6*7 0.003527 23,,599 163*8,, g 13713,.5 16*. 732 26,,95 35., 35 43 + 290,.000 C. 0*155 2*. O63 0.003*65 2*,,019 16*8*.,3 18890 .8 185,, 3*8 27,, 1 1 5 5,,51 + 45 295,.000 0.0*085 24.432 0.003*C6 2*,,*39 1&620,,7 190o8,,9 185. 95 7 27. 29 55. 63 4* 'J 300,,000 L. 0401b 2*. 900 0.0033*9 2*..358 16757,.9 192*7 .9 186,,55 6 27.,47 35,,86 + 50 31 j,,000 C. 03a8b 2 5.7 35 0.003239 25,,o97 17035,,2 19608,,7 187,,7+0 27. 66 3o.,25 + 5 -j 320,,000 0. 0376* 2d. 570 0.003137 2b,,535 17316, t 19973 .it 188,,897 2f-,,28 56,, CD + 65

330,,000 0. 036*9 27. *0* 0. 0030*1 27. 373 17602. 203*2. * 19J. 032 28. 72 37. 09 4d9

3 + 0,,000 0.035*1 28. 256 0.002951 2b,,210 17892,,0 20715,,9 191, 1*6 29. 18 37,,55 476

35o , ,000 0. 03**0 29. 073 0. 002866 29,,0*6 18186,,7 2109*,,0 192. 2 + 1 29, 06 58,,0 3 462

360,,000 0. 033** 29. 9Jb 0. 002786 29.,863 16*86.,3 21*77,,0 193. 320 30. 16 38,,53 43B

370,.000 0.03253 30.7*0 0.002710 30,,719 16791,,0 21355,.1 19*,, 332 30. 06 39, + 44 + 360 .ooo 0.03167 31.57* 0.002638 31,,55* 19101,,0 22258,,3 195,,43 31,,21 3 9, 5 7 49 i 390 . 000 0. 030bb 32.407 0.00257G 32,.390 19*16,.2 22657,.0 196,,465 31.,76 + 0.,11 505

too,, 000 Q. 03006 33. 2*1 0. 002506 33. 225 19737,,0 23061,,0 197,,488 32, 31 + 0,,66 511 *20 .000 0. 02665 5*. 907 0. 002366 3*..694 20395,,3 2 363 6,.0 199,,496 33, + * -.1,,73 521

4 + 0,.000 0.0273* 36.573 0.002277 36,,563 21076,,if 2*7 53,,7 201,,46 9 3*. 59 + 2. 93 5 52 hoO .000 0. 2bl6 38.236 0.002177 38,.231 21780,.6 25o3 *,.* 20 3,,*03 35. 76 + <«,,09 5 + 2 *8J,, 000 0. 0250b 39. 90* 0. 002066 39, 899 22507,,9 26*98,.3 205.,30* 36. 91 *5,,25 652 500 .000 0. 0240b 41.569 0. 002002 41.,565 23258,,* 27*15,,2 207, 17* 38. 06 + 6 , ,40 ?$2

140
METHANE IS03A* AT P 1.5 BAR

T OEN VOL DP/OT OP/DO C H S CV CP A OEG K MOL/L L/MOL BArt/K 8AR-L/M0L J/MOL J/MOL J/MOL/K J/MOL/K J/MOl/K -i/sec

90,.715 28.150 0.03552 20.7203 250,.339 3472.,3 3477.,6 67..884 33. 11 52. 7* 1577

95,,000 27.793 0. 03598 19.6175 233,,978 3688.,5 3693,,9 70,.327 32,,96 i3, 19 153*

100,,000 27.370 . 0365* 18.3911 215,,168 3948.,5 3954,,0 73,,076 33,,05 54. 03 1481

105,,000 2b. 937 0. 03712 17.2252 196,,833 4215.,9 4221,.4 75,,735 33,,13 5*

.

,9* l*2o

110.,000 2b.*94 0. 03774 16. 1144 179,.104 4489.,5 4495,,2 78. 310 33, 06 55,,73 1372

115,,000 26.03? 0.03841 15. 0526 162,,057 4768,,5 4774,,2 80.,807 32,,33 56,, 55 1319

116.,621 25.886 0. 03863 14. 7180 15b,,687 *859.,8 *8j5,,6 81,,b00 32,,72 56, 73 1302

116,,621 0. 16213 b.168 0.01399* 8,,800 11991.,4 12916,,6 150. 6*8 25. ol 35. *5 27o

120. 300 0. 15695 6.372 0.013498 9,,131 12080.,3 13036,,0 151,,65 7 25,,4° 35.,21 2o0

12p,, OOu 0.14992 6.670 0.012838 9,,613 12210,, 5 13211,,4 153,,089 25,,40 34,,93 287

130,,000 0. 1*355 6.965 0. 012250 10,,06b 12340,,7 13385,, 5 15*., 454 25, 33 34,,72 29*

135,,000 0.13775 7.260 0.011722 10.,552 12469. 6 13556.,8 155., 761 25. 28 34. 5* 30 140,,000 0.13242 7.652 0.011243 11,,012 12598,,4 13731,,2 157,,015 25,,24 34,,43 3 Gu 1*5,,000 0. 12752 7. 8*2 . 010806 11,,466 12726,,7 13903,,0 158,,22 25,,21 34,,29 312 150,,000 G. 12298 8.131 0.010405 11,,920 12654,, 5 14074,,2 159,,3dl 25,,19 34,,19 318

155,,000 0. 11878 8.419 0. 010035 12,,3 69 12982.,2 142*5.,0 16 0,,50 1 26. 17 34. 12 323

160,,000 C. 1148b 8.705 3.009692 12,,814 13109.,6 14415.,5 161,,533 25.,16 34,, 05 329

lo5,,000 0.11120 6.992 0.009374 13,,258 13236,,8 1*535,,7 16 2,,630 25,,16 34. CO 3 3 * 170. 000 0. 10778 9. 27a 0. 009077 13,,699 13364,,0 147?5.,7 16 3,,644 25,,16 33,,96 339

175,,000 0.10457 9.563 0.008799 1*,,136 13491,,0 1*925,,5 16*.,62 8 25, 16 33,,93 3*2

180,,000 0. 1015s 9. 847 .008539 14.,375 13618,, 15095,,1 165,,584 25,,18 33, 91 363

165,,000 0.09O71 10. 131 0.008294 15,,011 137*5,,0 15254,p 7 loo ,,512 26,, 19 33. 69 355

190., 000 0. 09b02 10.414 0.008064 15,,445 13872,,1 1 -j 4 3 4 , ,2 167,,416 25,,21 33,,63 3o0 195,,000 0. 9 346 10.637 0. 007846 15.,s7d 15999,, 2 1560 3,,7 16d,,297 25.,24 33,,89 3 o-> 2U0,,000 0. 09108 10.980 0.007641 lb,,310 14126,,3 15773,,3 169,, 156 26, 26 33,,91 36 i 205,,000 0.08879 11.262 0.007**b 16,,741 1*253. 7 15 9*3., 169. 99 2 25. 32 33. 93 37*

210,,000 C. UOoDi 11.544 0.007261 17,,171 14381.,1 16112,,7 173., 810 25,,36 33,,95 37 i 215,,000 0. 08*56 11. 62o 3.007086 17,,6C1 14506.,8 16232,,7 171,,610 25.,41 33.,99 3 3 3 22J ,,000 0.082b0 12. 10 7 0.006919 18,,029 14636,. 16452,,8 172,,391 25,,*7 3*,, 0* 387

225,,000 0.08072 12.388 0.00b760 18. *57 14765. 16623.,2 173, 157 25. 54 34. 03 392

230,,000 0. 07893 12.659 0. (J 66 8 16.,884 14893., 5 16 793,,9 173,,907 25,,62 34,, 15 35 = 235.,000 0.07722 12.950 0.006463 19.,310 15022,, 4 1695*.,9 17*.,6*2 25, 70 34, 22 4U j 240,,000 0. 0755O 13. 230 0.00d324 19,,73b 15151,,7 1 7156,,2 175.,36 3 2E,,79 3-,,30 -0 5 2 1 5

.

,000 0. 07*02 13. 611 0. 006191 20. lb2 16261. 5 1 7 3 J 8 . 176. 071 25. 39 34,,33 40 3 250,,000 0.07251 13. 791 0.006064 20,,567 15411,,7 17430,,3 176,,767 25.,99 34,,4d 413

255 , ,000 0.07107 i*. on 0. 0059*2 21,,0 11 15542,, 4 17653,,1 17'., 45 1 26.,10 34,,59 417

2b0,,000 U. 0b9b8 14. 351 0. 005625 21,,*35 15673,,6 17326,,4 179,,12* 2c , ,23 34,, 7 <-2u 265, 000 0. 06835 14. b30 0.. 005713 21.,35 9 15605. 7 18030. 3 17a,,786 26,,36 34,,83 424

270,,000 0.06707 14.910 0. 0Q6o05 22, 282 1E938.,3 18174.,8 173. 438 26. *9 34,,96 *23

275,,000 C. 6 583 15. 193 0.006501 22,,705 16071,, 6 1B350.,0 18 J., 081 26,,64 35,, Id 432

280,,000 0. 0b465 15.469 0.005*01 23,,128 16205.,b 1852 5,,9 180,,715 26,,79 35,,2* 43?

285,, 300 0. U6350 15. 746 0. 0053G* 23.,55 16340,,4 1870 2,,6 181,,34 26,,95 3b.,43 43 J 290,,000 0. 06239 16. U2d 0. 005211 23,,972 16475,,9 18830,,1 181.,95 7 27,,12 35.,5o **3

295,,000 0. 0bl32 16. 307 0.005121 2*,,394 lb£12,,4 19058,, 4 162.,5o6 27,, 30 35., 73 446

300,,000 0.06029 16.53o 0.005034 2*.,816 16749,,7 19237,,6 183.,lo8 27. *8 35. 91 *5 j 310. 300 0. 05833 17. 1*4 0. 004869 25,,658 17027,,2 19596,,8 184,,35 2 27,,3? 3d,,29 4:,j 320,,000 0.05649 17.701 . 004712 26,,5 00 17308,,6 199o3,,3 185,,510 28,,29 36,,70 463

333,,000 0. 05*77 18.259 .004670 27,,340 17594,,3 2G333,,1 18o. 646 26. 72 37, 13 4o > 3*0,,000 0.05315 18. 816 0. 0C**34 28,,180 1788*,,4 20706.,8 197. 761 29. 19 37. 6 3 476

350, 000 0. 05162 19.373 0. 00*306 29,,020 18179,,3 21085.,2 188,,857 29, o7 36,,06 432 3o0 , ,300 0.0501b 19.93J 0. 004165 29,,859 18479,, 21*68,, * 189,,937 30. 17 38, 5o 46o

370,,000 0. 0*881 2C.486 0.004071 30,.697 18783,,3 21856,,7 191,, ooc 30.,o9 39.,07 49*

380,,300 0.04752 21. 0*3 0.003962 31,,535 19093. e 22250, 2 192. 049 31. 22 39. 5d *5 -i 390 .000 0.04630 21.599 0.003860 32,,373 19409,,i 22649,,0 193,, 084 31, 76 40. 13 50 o 400,,000 0.04514 ZZ. 155 0. 003763 33,,210 19730,, 23053,,2 19*., 107 32..31 *0,.63 311

420 , ,000 0. 04298 23.267 0. 3562 34,,863 2 388,,4 23876,,5 196,,119 33,,*5 *1,,61 621

440,,000 0.04102 2*. 379 0. 003418 36.,565 21C69.,6 2472b.,4 198. 091 34. b0 *2. 95 532

4o0,.000 0.03923 25.490 0. 003268 38,,226 21773,,6 25597,,3 2L0,, 025 31,,7b ** , 11 6*2

480,,003 0.03759 26.601 0. 003131 39,,B9o 22601.,2 26*91,, 4 201.,92 7 36,,92 *5. 2b 562

500,,300 0.03c09 27.712 0. 003006 41,,565 23251,,7 27406.,5 20 3,,798 38,,07 *6,,41 5b2

141
METHANE IS08A3 AT P = 2.0 6AR

T OEN VOL DP/OT OP/DO E H S CM CP W Q£& K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/10L/K J/MOl/K J/10L /< 1/StC 9J.728 28. 151 C. 03552 20.716? 250.40b 3472.4 3479.5 67.686 33.12 52. 7* 157? 95.000 27. 79b 0.05598 19. c 196 23+. 100 3t88. 3695.2 7 0.32 2 32.97 53. 19 153 + 100. 000 27.372 0.03653 lo. 3937 215.299 3947. 9 3955.2 7 3.07 1 33.35 5*. 03 1461

105. 000 26.940 C. 05712 17.2263 196.973 *215.2 +222.6 75.729 33.13 54i 93 1 + 2

T 110.000 26.497 0.03774 lb. 1179 179.251 4463.6 4496.4 73.304 33.07 35. 73 1373

115. 000 26. 040 0. 058*3 15.0566 162.212 4767.7 4775.3 60.800 32.83 5b. 64 131J 120. OOQ 25.568 0. 03911 1*. 0365 145.897 5C51.0 i058.8 8 3.22 2 32.46 >1

2? 126'j 120.588 25.511 0. 03920 13.9214 14+.02o 5G64.5 5092.* 83.502 32. +3 57. 3b 126J

120.588 C. 21140 *.730 .016414 6.387 12Cb3.5 13014.5 149.205 25.72 36. 01 27d 125.000 0.20270 4. 933 0. 017557 9.33b 12185.9 13172. o 153. *92 25.59 35. 63 285 130.000 0.1937b 5. 161 J . Glbc99 9.632 12317.7 133+9.9 131.863 25. + 8 35. 30 291 135.

jO C- 18566 5. 33b 0. 015937 10.317 124*8.

13525.8 153.210 25.40 35. 05 2 90 140.000 0. 17628 5.60 9 0. 013253 10.795 12578.7 137J 0.5 15+. 431 25.35 3*. t + 30- 1+5.000 C. 17151 5. 831 J. 31*63* 11.266 12703. 1 13874. 3 155.700 25. 3G 34. 67 313 150.000 C. 16 52 7 b. 051 . J14G69 11.731 12637.1 14 0+7.3 15o.873 25.26 3 * . 53 31o 155. 000 0. 1594* b. 273 0. 0135T1 12.192 12965.7 1*219.7 158.004 25.24 3*. 42 322

1 6 . J 0.15413 6.*36 0.U13074 12.648 13G9*.0 1*331.6 159.095 25.22 3*. 32 328

lo5. 000 G. 14914 6. 70? 0. 012b32 13.101 13222.0 1 45 j 3 , i 163. 150 25.21 54. 25 355 173. 000 0. 14448 6.921 0.012222 13.551 13349.9 1+73*. 1 161. 171 25.21 34. 13 333 175. JOO C. 14011 7. 137 0. 0116 39 13.990 13477.5 1*934.9 162.161 25.21 5*. 1 5 3--. 180.000 0. lioUl 7.352 0.011*81 1 * . *43 1 Jt05. 1 15075.5 163.122 25.21 3*. 5 3+9 185.000 0.13216 7. 567 . 011145 l*.86fc 13732.6 152+c.O 16+. 056 25.23 3* 07 3 5- 190.000 0. 12852 7. 731 0. 010830 15.32c 13863. 1 1541o.3 lc+. 9o4 25.25 3*. 05 359 195. 300 0. 1250b 7. 945 0. ulJ533 15.7 65 13967.6 1 5 5 3 6 .

165.649 26.27 3- -. 3c-. 200-000 0. 12183 8. 2J8 0. 01u252 16.203 1*115.

15756.6 165.710 25.30 54 G4 36 i 205.000 0. 11875 8. 421 . 009967 1 o . b 3 9 1*242.9 15927.1 167 .551 25.34 3* &5 37 3 210.000 0.11583 8. 63t . 3 9736 17.07* 14370.7 16097.5 166. 372 25.36 3* G 7 37 j

2 1 5 . J 0.1130s 8. 6*6 0.009*97 17.508 l-.*98.7 162o7.9 169. 17+ 25. *3 5* 1 j 33 5 220.000 0. Ilu40 9. 058 3.009271 1 7.941 14627 .0 lc438.o 169.958 25.49 3* 1 + 3 8 i 225.000 0.1078b 9.270 . 009055 18.372 1*755 . 3 166J 9 .3 170.726 25.56 3* 19 5-Jl 230.000 0. 10547 9.432 0.006649 1 6 .BG 3 l,6e+.3 lc730.b 171.478 25.63 3* .2 + 39o 235. 000 0. 10317 9.633 0. 3C3653 19.233 15013.4 16952.0 172.215 2 5.71 5 4 31 *3 j 240. 000 G. 10097 9.904 3

0C84tb 19.a63 15142. 9 17123.8 172.938 25. 8C 3* 33 + 3 + 2+3.000 G. 0988b 10. 115 . 306267 23.091 15272.9 1 729b. 17 3.648 25.90 34 47 * u 5 250 .000 G. 09c6 + 10. 32c .008115 2G.519 15*G 3.3 1 7-o8.b 17+. 3+5 2fc.O0 3 + 6o + 12 255. JOO C. 09*90 1G.537 0. 0075-50 20.9*7 15534.3 176+1.7 175.031 26.12 3 + . 3 5 4 1c 2oO. 000 0. 09304 10. 7*6 . 007793 21.37* 15665.3 17315.3 17^.705 26.24 3 + 77 *2 J 2o5. 000 0. 0912c 10.953 0. 0076*1 21.800 15797.9 17939.5 17b. 366 26.37 5 + . 89 -.2 + 270.000 u. u895* 11. 169 . 007*95 22.22c 15930. b 181o4. 3 177.022 26.50 36 . 02 423 275.000 G. 08766 11. 37i 0. 07 3 55 22.651 lb06*. G 16339.8 177.666 2£ .65 55 . 15 432 2bO . 000 G. 08o29 11.589 . 007220 23.076 16198.2 16516.0 176.300 26.60 35 Si 1 33 285 . JOO 0.08475 11. 799 u. 307090 23.501 lc333. 1 18b92-9 176.926 26.96 35 . *5 4 3 9 290.000 0.08327 12.009 . 06965 23.925 16468. 6 13870. b 179.5*4 27.13 55 . bl * - 2 295. OOO G. 08164 12. 219 0. 00b6** 2 + . 349 16605.- 193+9.2 18 3 . 15 4 27.31 55 . 73 **-, 300.000 G. G8L*c 12.429 0.006728 2*. 772 16742.8 19228.6 183.757 27. *9 56 . 93 *-':) 310.000 0. 07783 12.6*8 . 006506 25.618 17C20.5 19590.1 181.942 27.38 5 6 . 3 5 '13 3 320. JUj

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3c

37

• 7 + .17 -6 5 + o 9 3t0. OQO 0. 0709C 14. 1J5 0. 005922 26. 150 17678. 3 2Qb99-2 185.355 29.19 3? . 62

.1,3

4 7 > 350 .000 . 0668b 14.523 0.00576U 26.993 18173.3 21077.9 18o. 453 29. bb 3 6 * 6 2 360 . J 00 . 0bc93 1*. 9+1 0.005588 29.634 16*73. 1 21451.

18 7.533 3C. 18 30 . 5

') * i 370. JOO 0.06511 15.359 . G5*35 30.67:, 18773. 1 218+9.9 183.597 30.69 5 9 1

*9 + 380 . 000 0. 06338 15. 7?? 0.005290 31.515 19068.2 22243.6 189.646 31.22 39 . c2 * 9 9 390.000 0. 06175 lb. 195 0. 305152 3 2.355 19403.7 226+2.7 193.C.83 31.77 + . 1& 5o3 400 . 000 0.0b020 lb. 613 0.005022 33.19* 1972*.

230+7.1 191.706 32.32 + . 7 I 5 13 621

5 32 420. 000 0. 05732 17. 4*7 0. 00*761 3*. 871 20363.2 23872.7 193.719 33.45 + 1 . 83 440. 000 G. 05*70 16.232 0.00*561 36.546 21C64.5 2*720.9 193.692 3*.b0 + 2 . 9 7 *oO .000 G. 05231 19. lib 0. 304361 3o.219 21768.9 25592.2 19 7.627 3 5.76 + + . 1 3 5*2

552 480 . 000 C. 05013 19.950 0.00*178 39.892 22*9b. 5 2c*86.5 199. 530 36. 92 *3 . 23 500.000 0. 04812 20.783 0.004010 41.563 23247. 1 274J3.8 201.401 38.07 *6 . 42 56 2

1 42
METHANE ISOBAR AT P = 3.0 BAR

T DEN VOL OP/OT OP/DD E H S CV CP W OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K 1/StC 90.754 28.153 0.03552 20.7154 250.539 3472. 7 3433.4 67 69 33. 12 52 73 1577 95.000 27.799 0.03597 19.6238 234.344 3687 3697.8 70 311 32. 98 53 13 153^ 100.000 27.377 0. 03653 18. 3988 215.562 3946, 8 3957.7 73 059 33, 06 54 02 1462 105.000 2b. 945 0.03711 17.2344 197.253 4214, 4225.1 75. 717 33, 14 5* 92 142 7 110.000 26.502 0. 03773 16.1250 179.545 4487. 4 4498.8 7i. 291 33. 06 55 7o 1374 115.000 26.046 0.03839 15. 0647 162.520 4766 1 4777.6 80 787 32 84 5o 51 1320 120.000 25.574 0.03910 14. 0476 146.218 5049, 2 50o0.9 83 207 32. *9 67 25 1267 125.000 25.084 0.03937 13.0660 130.649 5336 6 53-»8.6 85 560 32 09 58 06 121* 12o.681 24.915 0. 0*014 12.7462 125.577 5434. 3 54-*6.3 85 33 6 31. 97 56 37 1196 126.681 C. 30803 3.246 0.027276 6.940 12178 8 13152.8 147 17* 2 5 98 3 7 09 282

1 JO. 000 G. 29829 3. 352 0.02o263 9.302 12269. 4 13275.2 1*0 128 25 35 3b 63 237 135.000 0.28492 3. 510 0. 024913 9.633 12404. 4 13*57.3 149 502 25, 70 36 19 294

1 1*0.000 0.27287 3.665 0. 023728 10.349 12537 9 13b37.3 150. 812 25 58 35 81 30 145.000 0.26193 3. 818 0.022674 10.853 12670 2 13815.6 152 "063 25 50 35 61 307 150.000 0.25193 3.969 0.021727 11.347 12801 7 13992.5 153 2o 3 25. 44 35 27 313 155.000 0. 24274 4.120 0.020868 11.833 12932 5 14168.4 154 416 25 39 35 07 313 loO. 000 0.23426 4.2b9 0. 020085 12.313 130o2 7 14343.3 155 526 25 35 34 9 325 165. 000 0. 22640 4.417 0.01936b 12.786 13192 4 14517.4 156 598 25 32 34 76 331 170.000 0.21909 4. 56-* 0. 018703 13.254 13321 7 14691. 157 634 25. 30 34 65 33d 175.000 0.2122? 4.711 0.016069 13.719 13450 7 1*864.0 153 637 25 29 34 5 3 3*2 130.000 Q. 20589 4. 857 0.017518 It. 179 13579 5 15036.6 15 9 610 25 29 3* 43 34? 165.000 0.19991 5.002 0.01o964 14.636 13708 2 15208.9 160 554 2 5 3G 3* 42 352 190.000 0.19426 5.147 0.016486 15.090 13836 7 15330.9 161 471 25 31 34 3 3 357 195.000 0.16897 5.292 0.016017 15.541 13965 1 15552.7 162 363 25 33 34 3* 3o2 200.000 0.16396 5.436 0. 015577 15.990 14093 6 15724.* 163 23 3 25 36 3" .3? 3o7 205. 000 C 17922 5.530 0. 015162 16.437 14222 1 15896.0 16* ,080 26 39 34 .31 1,71 210.000 0.17473 5.723 0.014769 16.361 14350 6 16067.6 164 907 25 43 3 4 32 377 215.000 0.17047 5. 866 . 14396 17.324 14479 3 16239.2 165 715 26 46 34 .33 381 220.000 0.16641 b. 009 0.01-*046 17.7b6 14608. 2 16410.9 166 504 25. 53 3* 35 38o 225.000 0.16255 6. 152 0.013711 13.20b 14737 3 16582.8 167 177 25 oG 34 33 39 230.000 0. 1506B 6.294 0. 013393 13.644 14866 6 16754.9 163 033 25 o7 54 43 39j 235.000 0.15537 6.43o 0. 013090 19.061 14996 3 16927.2 166 774 25 75 34 49 393 2*0.000 0. 15201 6.578 0. 012801 19.516 15126 3 17099.8 169 501 25 63 3h 55 40 3 245.000 0. 14660 6.720 0. 012525 19.953 15256 7 17272.8 17J 21* 25 93 34 63 403 250.000 0.14573 6. 862 0.012260 20.387 15367 6 174*6.1 170 914 26 Ho 3* 71 412 255.000 0.1*279 7. 003 0. 0120C6 20.820 15513. 9 17619.9 171 b02 26 14 34 80 416 260.000 0.13996 7. 145 0.011765 21.252 15650 6 17794.2 172 279 26 26 3* 91 42 2o5.000 0.13725 7.2 8o 0.011533 21.084 15783 3 17939.1 172 945 2b 39 35 2 42* 270.000 0. 13464 7.427 0.011310 22.115 15916 4 131**.

5

173 60 1 26 53 35 1* 427 275.000 0.13213 7.568 0.011096 22.545 lb050 1 18320.6 17* 24 7 26 67 35 zr 431 280.000 0.12972 7.709 0.010890 22.975 16184 6 18*97.3 17* 884 26 82 35 41 -tis, 265.000 0.12739 7.650 0.010691 23. -+04 16319 8 1867*.

7

175 612 26 9 8 35 56 43? 290.000 0. 12515 7. 990 0. QlOsGO 23.832 16465 8 18853.0 176 132 27 15 35 71 442 295. 00 0. 12298 8.131 0. 010316 2*. 260 lo592. 7 19032.0 176 743 27 33 35 83 ** j 300.000 0.12090 8.272 0.010138 24.687 16730 4 19211.8 177 348 27 51 3b .05 4*9 310.000 0.11o93 8.552 0. 0098C0 25.541 17008 5 19574.3 173 536 27. 39 Jb 42 *5d 320.000 0.11321 8.833 0.009485 26.392 17 290 6 199*0.5 179 699 28 31 36 82 4 c i 330. 000 0.10973 9. 113 0. 00*190 27.242 17576 9 20310.8 180 838 28. 75 37 2* 4b i 340.000 G.10o46 9.393 0.006912 28.091 17867 6 20685.3 181 95 6 29 21 37 69 475

350. 000 0.10336 9.673 0.003652 28.939 18162 9 21064.8 183 056 29 69 38 16 462 360.000 0.10047 9.953 0.008406 29.785 18463 1 21**8.9 134 137 3 19 38 65 *0 3 370.000 0.09773 10.232 0.008174 3u .b31 18768 3 21838.0 135 20 3 30 70 3 9 15 493 380.000 0.09513 10.512 0.007955 31.475 19G78 7 22232.2 186 254 31. 23 39 63 433 390.000 0.09267 10.791 0.0 7747 32.319 19394 5 22631.7 187 292 31 76 *0 21 50? 400.000 0. 09U34 11. 070 0.007550 33.162 19715 6 2303b.

6

186 317 32. 3 3 40 7o 51J 420.000 0.08b00 11.628 0.007165 34.845 2G374 .7 2 3 863.0 19J 332 33 *6 *1 ,87 521 440. 000 0.03207 12. 185 0. 006854 36.526 21056 5 24711.9 192 306 34 61 43 01 53d 460.000 0.07846 12.742 0. 0G6552 38.206 21761 2 25583.3 19* 243 35 77 *4 lb 542 480.000 0.07520 13.299 0.006276 39.883 22489 1 26476.6 196 147 36 93 *5 31 552 500.000 0.07218 13. 855 0. 006022 41.559 23240 27396.5 198 02 36 08 *6 ,45 562

143
HE THANE ISOUAR AT P = <*.0 BAR

r OEN VOL OP/DT OP/DO E H S CV CP A DEG K MOL/L L/MOL 6AR/K BAR-L/MOL J/MOL J/MOL J/-IOL/K J/MOl/K J/10L./< •I/SEC -30.780 28.155 0.05552 20.7121 250 673 3S73. 3i*d7 2 67 89i* 33 13 52 73 1677 95.000 27.603 0.03597 19.o280 231., 5e7 3 6 6o. 3700, 3 70. 300 32. 99 5i 17 1535

100. 000 27.381 0. 05652 16.1.01.0 215, 821* 39S5. 6 396 2 73 0S8 33. 07 5S CO 1S82 105.000 20.950 0. 03711 17.21*05 197 532 1.212. 7 1.227 5 75 705 33 15 5S 90 l-*23 110.000 26.508 0.05772 16. 1321 179 839 SSbb SOI 1 7s 276 33 09 55 7h 137- 115.000 26.052 0. 03838 15. 0727 162. 827 S76S. 5 •.779 9 60. 773 32 85 56 S9 1321 120.000 25.581 0.03909 li«. 0566 1«*6 539 501*7 5 5063 1 e3 19 3 32 50 j7 22 12o3 125.000 25.092 0. 05985 13.0781 130 963 633h 6 5350 6 85 5 SS 32 10 58 03 1215 130.000 2".. 582 .0*068 12.1319 116 139 5626 6 56*2 8 87 839 31 75 59 02 1160

13l.i*03 2S.S3S 0. 0'*093 11.8711. 112 098 6709 S 5725 .8 88 i»7«t 31 o7 59 3S 11S-. 131. -.03 O.s033s 2.1*79 0.03o25£ 6 903 12256 8 132+8 ,5 11,3 72S 2fc 21 38 IS 28s 135.000 0.38933 2.569 0. 03-737 9 322 12357 3 13381, ,7 11,0 7s6 26 at. 57 57 29o

11*0.000 0. 37172 2.690 0. 032892 9. 863 121.91* 9 13570 ,9 11.6 101 25 86 36 95 297 1S5.0GO 0.35592 2. 810 0.331266 10 *2S 12630 6 13731* ,i* 11*9 389 25 73 36 S7 30* 150.000 0.31*162 2.927 . 02^866 10 951 1276i* 9 13936 ,8 150 619 25 63 56 9 310 155.000 0.32858 3. :•* 5 0.028597 11 •65 12898 2 11.115 5 151 797 25 55 35 7 9 31o lbJ.000 0.31663 3.158 0.0271*61 11 970 13030 5 11.233 ,8 152 929 25 •+9 35 i> •* 323 lop.000 0.30561 3.272 0.0261*09 12 i*65 13162 1 li.-. 70 9 15-. 020 25 + S 35 33 323 170.000 0.2951.1 3.385 0.325s55 12 95* 13293 1 l'.bt? 1 155 u72 25 1.1 3 5 16 33-, 175.000 0.28593 3.1*9 7 0.021*578 13 1*36 13S23 6 11.822 ,5 156 088 25 39 5 5 01 3*0 ldO.000 0.27709 3.609 0.023766 13 913 13553 7 11.997 3 157 073 25 36 51* 69 3s> 185.000 0.26882 3.720 0.023013 is 385 13t83 6 15171 »

158 028 25 37 31, 6 351 190. 000 0.26107 3.630 0.022311 m 852 13813 2 153S5 ,3 158 95 6 25 38 Ik 72 35o 195.0 00 0.25379 3. 9i*0 0.021665 15 31b 139-*2 6 15518 8 159 856 25 39 3-, bb 3ol 200.000 0.2*692 i*. 050 0.02101.0 15 777 1*072 15692 ,0 160 733 25 •1 3-» ,b2 3oo 205.000 0.21*01*-* -. 159 0.020-62 16 23s 1-.201. 3 158o5 a lbl 587 26. -.i. 3 it 59 371 210.000 0.231*31 S.258 0.019918 Id 669 11*330 7 lb037 ,8 162 1.20 25 1*8 3S 57 j7b

215.000 0.228i*9 if. 376 Q.019SG3 17 1<*2 11,1.60 1 16210 ,7 lb3 231. 25 52 3S 56 36u 220.000 0.22298 •+. h85 0.018917 17 ,592 li,589 , 6 16333 ,5 16-* ,02fl 25 57 3s 57 385 225. JJj G. 21773 S.593 0.018<*56 18 01.0 11*719 3 16556 ,1* lb-* 806 25 63 3S 5 i 39J 230.000 0.2127"* **. 701 0.018016 18 1*66 Is6s9 3 16729 , 5 165 566 25 70 3S t3 39 + 235.000 0.20796 i*. 606 0.017bG2 Id ,931 11.979 ,5 16902 .7 166 311 25 re 3s 67 356 2*0. 000 0. 2u3i*i* l». 915 0. J172C5 19 37i. 16110 17076 ,2 167 0i*2 25 86 3<* 71 S j > 2<*5.000 0.19910 5. 023 0. 01d827 19 816 1521+0 9 17250 ,0 167 758 25 9 6 3S 7 3 •Of 250.000 0. 19i*9i. 5. 130 O.Olb'+eb 20 256 15372 2 17h2i» .1 168 1,6 2 26 06 3-. 8o -11 255. 000 0. 1909b 5. 237 u. 01bl21 20 b95 1660h. 17598 7 169 153 26 17 5S .95 (#15 260. 000 0.18715 5.3t3 0.015790 21 133 15636 3 17773 ,7 16 J 833 26 29 35 0* SH

2o5.000 0. 183i*9 5.1*50 J . G15S7S 21 570 15769 2 179*9 ,2 170 50 1 26 i*l 35 13 S2 5 21*0.0 00 0.17997 5.55o 0.015170 22 00b 15902 6 18125 2 171 159 26 55 35 27 -2^ 275.000 0.l7b59 5. 663 0.01S379 22 1.1.1 lfc036 8 18301 9 171 808 26 69 35 39 S31 230.000 0.1733H 5.769 0.01h599 22 875 16171 6 18S79 ,2 172 H-*b 26 8S 35 53 S3-, 285.000 C. 17021 5. 875 0. 011,329 23 309 16307 1 16657 ,2 173 C76 27 00 35 c7 -3d 290.000 0.16719 5.981 0. 011*070 23 7i.l 16SS3 <* 18635 9 173 698 27. 17 35 82 s-,2 295.000 0. loi*28 b. 087 0.013820 21. 173 16580 5 19015 ,i* 17* 312 27 3<t 55 9ti SS -> 300.000 G. 1611.7 b.193 0.013579 2S ot. 16718. 5 19195 7 17s 918 27 53 56 15 S-, ) 310.000 0.15611* 6.1*05 0.013122 26 -.6 5 16997 2 19559 .0 176 109 27 91 3c 51 -»5o 320. 000 0. 15115 6.616 0.012o96 26 323 17279 a 19926 ,1 177 27 S 28 32 36 90 So2 330.000 0.11*61.6 6.827 0.012297 27 179 17566 5 20297 2 173 1.16 26 76 37 32 So -j 3<*0. 000 0. 11.209 7. 038 0.011923 2o 03i* 17e57 6 2C672 ,6 179 537 29 22 37 7o -73

350. 000 0. 13797 7. 2nd 0. 011572 28 88o 16153 3 21052 5 18C 638 29 70 38 22 '.0 1 360 .000 0. 131*08 7.S5 6 0. 01121.1 29 736 161,53 8 211*37 2 181 721 30 20 38 71 S3.- 370.000 0. 1301*0 7.669 0.010928 30 588 18759 i« 21826 ,9 182 78 9 30 72 39 21 S93 380.000 0.12o92 7. 879 0.01C&33 31 •36 19 070. 1 22221 6 183 6-*l 31. 25 39 73 S9:t 390.000 0.123b3 8.039 0.010351* 32 ,28S 19366 1 22621 6 18i* 88 31 79 -.0 25 5J5 "00.000 0.12051 8. 293 0. 010069 33 130 19707 6 23026 9 18p 906 32 3S •0 80 51j ••20.000 0. 11H71 8.716 0.00969O 3i* ,821 20367 ,2 2365', ,2 187 92i. 33 .7 -.1 91 521 SsO. 000 0.10945 9. 136 0. 009161* 3b 308 21G*»9 l* 21*703 ,9 189 900 31, 62 S3 05 532

<*60.000 0. 10<*b6 9.555 0. 00371.9 36 .192 2175S 5 25576 • 191 839 35 78 •*S 20 5m2 S60.000 0. 10027 9.973 0.006379 39 87s 221.82 8 261.71 ,9 193 7S-* 36 9*. *5 3 + 552 500.000 0.09o2i* 10.391 0.008039 i*l ,55s 23231* 27390 ,2 195 618 38 09 + 6 S8 562

144
ME THANE ISOBAR AT P 5.0 BAR

T DEN VOL DP/DT DP/OO E H S CV CP A OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL. J/MCL J/HOL/K J/MOL/K J/HO 1. ,/K •1/SEC

90,,805 28.157 0. 03552 20. 7G88 250.806 3*73.,3 3*91,,1 67.,899 33.,1* 52. 72 1577

95.,000 27.608 0.03596 19.o322 23+. 830 368*,,9 3702,,9 70.,289 33.,00 33. lo 153s

100., 000 27.38b 0. 03652 18. *092 216.066 39*+,• 5 396 2,.8 73,,237 33,,08 53,,99 1*83

105,,000 26.955 0. 03710 17.2*66 197.810 *211,,* + 230,,0 75,,693 33, 16 3 + , 8 3 1 + 23 110,,000 26.513 0.03772 lo. 1391 180.132 **8*.,6 *503,,5 78,,266 33,,1G 55,,72 1375

115,,000 26.058 0. 03838 15. 0806 163.13* *763.,0 + 78 2. 2 80. 759 32. 86 56. *7 1322

120,,000 25.588 0.03908 1*. 0656 1*6.859 50*5,,7 5065.,2 63.,178 32,,50 5 7 . 19 12o^

125,,000 25. 100 0. 0393 + 13.0382 131.316 5332,,7 5352,, 6 85,,529 32,, 1 1 67.. 9 j 1213

130,,000 2+.590 G. + 067 12.1*32 llo.+86 562*., 3 56+ + , ,7 87,, 822 31. 76 58. 93 llol

135,,000 2*. li5o 0. 0*157 11.22*9 102.327 5921,,7 59+2,,* 93,, 070 31. 51 oU,.23 llu.

135,,319 2*. 021 0. + 153 11. lo72 101. **6 5 9*0,,6 5961,.6 90,,212 31, 50 oO,, 3 1 1131

135. 319 0.+9616 2. 007 0. 0*3+12 8. 817 12315.,8 13319.,* 1* + , 585 26,,** 39,,11 263

1*0,,000 0. *76*9 2. 133 0. 0*2872 9.391 12**9.,1 13500,.7 1 + 5,,90 2 26.,16 38,, 30 293

1+5,,000 Q.*5396 2.203 0.0*0»57 9.976 1258a,,9 13o30,,3 1*7,,233 25. 96 37. 53 300

ISO,,000 0. + 3+69 2.301 0.0385*9 10.5*0 12726., 5 13876,,8 1*6,,*98 25. 8* 37. 03 33 7 155,,000 0.*1727 2.397 0.03o762 11.086 12862,,5 1*050,,8 1*9,,705 26,,72 36, 59 31 + 163,,000 G.+01*2 2.*91 0.0352G5 11.617 12997,,2 1+2+2,,8 153,, 8b 1 25,,6* 3b,,23 32 J lo5.,000 0.3869G 2.585 . 033766 12.137 13130,,9 1++23,.2 151..971 25,, 3 7 55. 9 + 32o

170.,000 0. 37353 2.677 0-032+58 12.o*7 13 263,,7 1*60 2,.3 153,, 0*0 25,,52 35,,7 ) 332 175.,000 0. 36116 2.7o9 0. 031321 13.1*8 13395,,9 1*760,,3 15 + , , 072 25. + 9 35,,53 333

180,,000 0. 31.967 2. 860 0.0302*0 13.6*3 13527,,* 1+957,,3 155,,070 25,, + 6 35,, 33 3+3

135,,000 0. 3389c 2. 95J 0. 0292*1 1+. 130 13t53,,6 15133,,7 15b., 336 25. + 5 35,,13 3+^

190,,000 0.32895 3. 0*0 0. U28315 1*.612 13789,,* 15339,,3 156,,97 3 25,, + 5 36,, 08 35 + 195,,000 0.31956 3. 129 0.027*53 15.089 13919,,9 15*3*,,5 157,,833 25, *5 3 + , 33 3ud 200,,000 0.3107+ 3. 218 0. 026c+7 15.562 1+050,, 2 15b5 9,,3 153,, 7o8 25. *7 3*. 92 3b 3 205,,000 0. 302*2 3. 307 0.025693 1 3.031 1*180 , ,* 15833,,7 15 J,,629 25, + 9 >*,,87 37 J 210,,000 0.29+67 3. 395 0.02518+ lb.+9b 1*310., 6 loOO 8,,0 16 J,, *6 9 25,,52 3 + , , 63 373

215,,000 C. 28715 3.*33 0.02+517 16.959 1***0.,8 lol32., 161., 288 25. 56 3 + , 51 373

220,,000 0.28011 3.570 0.023686 17.*18 1*571,,0 lb356,.1 162,, 088 25,,61 3 + ,63 38 + llj,,000 0. 273*2 3.657 0.023291 17.875 1*701,, + 1653 0,,1 162,,371 25.,57 3 + , , 6u 363 230,,000 0.26707 3.7++ 0.022726 18.329 1+831,,9 1673+,,1 163,.036 25,.7* 3*., 02 3 9.3 235., 000 0. 26102 3.831 0.022190 16.761 1*962,,7 16678,.3 16 + ,,385 25,,61 3*., 65 311

2 + 0.iUOO G.2562+ 3.910 0.021680 19.231 15093,,6 17052,,7 165,, 119 25,,69 3*.,90 + 02 2*5,,000 0.2*97'* *. 00 + 0.021195 I3.68O 15223.,2 17227,.3 165,.839 25,,99 3*,,95 *Co

250,, 0G0 0. 2++*7 *. 09 0. 02G732 20. 126 15357,,0 17+02,.2 166,.5*6 26,,09 35,,G2 + 10 255,,000 0.239*3 *. 177 0.020290 20.571 15*89,,2 1757 7,,5 167,.2+0 2b,,19 35,, U + 1, 260,,000 0.23*60 *.263 0. 019868 21.015 15622,,C 17753,.2 167,.92 3 26,,31 35,, lo *1 3 2o5

,

,000 0.22997 + .3 + 8 0.019*t+ 21. +57 15755.,2 17929,, + lb6.,59* 2b. + * 36,, 23 + 22 270,,000 0.22553 *.*3* 0.019076 21.898 15889.,1 16136,,1 159,.25* 26,,57 3 5 , , 33 *26

276,,000 0.2212b + .520 0.01870+ 22.338 16G23.i 5 16263,. + 169,,905 26,,71 35.,51 *3 2oG,,000 0.21715 + .605 0.0163*6 22.777 16158,.7 18*61,,2 173,,5+6 2c,,8c 35,. c + -.3 + 285.,000 0.21320 *.690 0. 018iiC5 23.215 lb29*., 5 18639,.8 171,.176 27,,az 36,,73 + 33 290,,000 0.20939 + .776 0.017675 23.651 16*31,,2 18819,,0 171,,80 1 27,,19 35,,92 * + l 295,,000 0.20572 *. Sol 0.017357 2+.087 16568,,6 1899 9,,1 172,,1*17 27,,36 36,,Co *• -* ~J 300.,000 0.20218 + . 9+c 0. 017052 2*. 522 16706,, 9 19179.,9 173., 02* 27. 5* 36. 2 + + +3 310,,000 G. 195*7 5.116 0.016*72 25.390 16986,,1 195++.,1 17 + , ,219 27.,93 36,, bu + 33 320,,000 G. 18919 5.236 0.015932 2 6.255 172o9,,1 19912,,0 175,,386 26,,3* 3b,,93 + o2 330.,000 C. 18332 5. *55 0.015+27 27.117 17556,,3 20283,.3 17c.,531 28.,77 37., 3 c + o9

3*0.,000 0.17780 5.62* 0.01*95* 27.977 178*7,.6 20659,.9 177,,65 3 29.,23 if . ,83 ^7'j 350,, 000 0.17262 5.793 0.01+509 28.835 181*3,,9 210+G , ,5 173,,75 7 25.,71 38, 23 + 81 360.,000 0.16773 5. 962 0.01*051 29.S-91 18**+,,9 21+25,,9 179,,8+2 3C,,21 38,,77 + 87 370., 000 0. 16312 6. 131 0. 013697 30.5*6 18750,.8 21816,,1 180,,911 30,,73 39,,27 *93

360.,000 0.15675 6. 299 0.013325 31.399 19061.,8 22211,i 3 181,, 56 5 31,,26 39,,73 + 39 390,,000 0.15*62 6.*67 0.012973 32.250 19378,,1 22oll,,8 183,.005 31,,30 + 0,,31 5G3

*G0. 000 0.15070 6.636 0.012639 33.101 19fc99,,9 23017,,7 18 + ., 033 32,,36 + 0,,63 510

*20,,000 C. 1*3** 6.972 0.012021 3*. 796 2G360,,0 238+5,,8 18 -j,, 052 33,, + 8 + 1,,90 521

+ *0,,000 0.13685 7.307 0.011*62 36. +91 21G*2,, 6 2*636,,2 163,,030 3*,,o3 + 3,,09 532

*60,,000 0.13085 7.6+2 0.01G953 38.180 217*8,,2 255a9,,5 189.,971 36,,79 + *. 23 5 + 2 *80,,000 0.12535 7.977 0.010*88 39.867 22*76,.9 2b+o5 , .6 191,,677 36,,95 + 5 , , it 552

500,,000 0.12031 8.312 O.OlOOfcl *1.551 23228,,* 2733*,.5 193,.753 38,,09 + 6,,51 562

145
ME THANE ISOBAR AT P = 6.0 BAR

T DEN VOL OP/DT OP/DO E H S C\l CP H OEG K MOL7L L/MOl BAR/K BAR-L/MOL J/MOl J/MOl J/ 10L/K J/MOl /K J/MOl /< 1/SEC

30 d31 28.159 0.03551 20.7U55 250. 9*0 3*73. 6 5*3*. 9 67. 90 3 33. 1* 52 71 1577

95 ObO 27.812 0.0 3 596 19.636* 235. 072 3683. 9 3705.5 70 279 35, 00 53, 15 153o

100 000 27.390 0. 03651 lb. *1*3 216 3*8 39*3 * 39o5.3 73 025 55. 09 53 98 1*83

105. 000 2b. 960 0. 03709 17.2527 198. 088 *210. 2 *232.* 7p 681 33. 17 5*. 83 1*29

110 000 26.519 0. 03771 16. 1*61 180 *26 **83. 2 *5J5.9 73 25 3 33 10 55 70 1376

115 000 26.065 . 3 837 15.GS66 163 **1 *761. * *73*.* 8 7*6 32 87 56 *5 1323

120. 000 25.595 0.03907 1*. G7*5 1*7 179 50**. 5067.* 63 16 3 32. 51 57 17 1270

125 .000 25. 107 0.03983 13.0983 131 6*9 5330. 7 555*. b 85 513 32 12 57 96 1217

130 000 2*. 599 0. 0+065 12. 15** lib. 833 6622. 1 56*6 .5 87 80* 51, 77 58 9* llb2

135 000 2*. 066 0.0*155 11.2375 1C2 689 5919. 1 59**. u 90 051 31 52 o0 13 HOo

138. 696 23.o53 G. + 226 10.5737 92 628 61*3 2 bl63.5 91. 69 2 31, *0 ol 53 1062

13d. o9b 0.59307 1.63b 0. 05*76* 8 = 98 12362. 13373.6 1*3. b*0 26 o5 + 2o 2 So

li*0 000 0.5d501 1.709 0.053855 670 121.00 3 13*25.9 1* + 015 26, 56 39 9? 233 145 000 0. Siobl 1. 797 0- 050596 9 507 125** 8 13622.6 1*5 397 26 28 58 88 29) 150 Qua 0. 53153 1. 881 0. 0*7863 1G 112 12686. 3 13815.1 l*o 701 26 07 3d 09 3u3 155 .000 0.50911 1. 96* 0.0*5*77 ia 693 12625 5 1*00*. 1*7 9*0 25 92 37 *9 51u 160 000 C. '868b 2. 0*o 0. 0*3388 n 25* 12962 9 1*190.2 1*9 122 25 80 37 00 517 lo5 .000 0.*7u*s 2.126 0.0*1528 n .800 13C98 .6 1*37*. 2 15 25i- 25 71 36 bl 32* 170 000 C. *5359 2. 205 0. 3 98 5* 12 333 13233 6 1*556.* 151 3*2 25 b* 36 23 330 175 000 0.*3807 2.233 0. 038337 12 655 13367 5 1*737.1 152 39 25 59 56 02 5 5 j ISO 000 C.*2372 2.360 0.036952 13 368 13500 6 1*916.6 155 *Q2 25 56 35 80 5*? Ids 000 0. 1*1039 2.*37 0.033679 15 .072 13633 1 15095.2 15* 530 25 53 35 tl 5*7 190 000 0.39796 2.513 0. 03*505 1* 369 13765 1 15272.0 15? 32 8 25 52 35 *o 555 195 000 0.38631. 2.588 0.033*17 1* 860 13896 6 1 6**9.

6

13b 2*7 25. 52 35 3 + 553 200 .000 0.3751.5 2.663 0.032*0* 15 3*o 1*G28 1 1562b. 2 157 1*1 25 53 35 2* 3o^ 205 .000 0.36520 2.738 0.031*58 15 826 1*159 3 15802.2 15 3 010 25 55 35 16 5b3 210 000 0.35555 2. 813 0. 03U573 16 302 1*290 3 15977.8 15d 856 25 57 55 1] 57 ( 215 0G0 0. 3*0*3 2. 887 0.02*7*1 16 775 1**21 3 16153.2 I5y 681 25. 61 55 Co 375

220 000 C. 33781 2.960 0. J28957 17 2*3 1*552. 3 16328.* 160 *8 7 25. 06 35 G \ 3o 3 225 .000 0.32963 3.03* 0.028218 17 709 1*663 3 165J 5.b 161 27* 25 71 55 02 533 230 000 0.321B6 3.107 0.027519 18 171 1*81* 5 1667 8.7 162 0** 25 77 3p 03 5+2 235 .000 0.311*1*7 3. 180 0.026856 18 631 1*9*5 9 16dp3.8 162 797 25 8* 3 5 L + 39,' 2*d 000 0. 3u7** 3.253 0. J2b227 19 U88 15077. 5 17029-1 163 536 26. 33 35 03 *01

ZW'i .000 0.30073 3. 325 0. u25629 19 5** 162G9 * 1720*. 6 16 + 259 26 02 55 12 * J j 250 000 0.29*32 3. 39d 0.025G60 19 997 153*1 7 17580.3 16* 969 26. 11 56 1 3 mo

255 0G0 G. 28619 3.*70 0.02*517 20 **8 15*7* * 17556.* lc5 667 Zi. 22 55 2j + 1 + 260 000 0.28232 3.5*2 0.023998 20 .897 15607 .6 17732.8 165 35 2 2b 3* 35 35 *13 2o5 000 0.27670 3.61* 0.023503 21 3*5 157*1 2 17309.7 167 025 26 *6 35 *2 *2.? 270 .000 0.2713C 3. 686 .023C28 21 791 15875 C 18 087.0 167 c36 26 59 55 62 *2-j 275 .000 0.26613 3.738 0. 022573 22 236 16010 3 1826*. 9 168 3+1 26 73 35 6^ *3 j 2d0 000 0. 26115 3.829 0.022137 22 .679 161*5 8 18**3.* 163 98* 26 88 35 76 *3* 2d5 .000 0.25636 3.901 0.021718 23 121 16282 18622.5 163 618 27 G* 35 63 + 5," 290 .000 C. 25175 3.972 0.021316 23 562 16*19 16802.3 170 2** 27 21 36 C3 + +1 295 .000 0.21*731 *. 0*3 0.020928 2 + 002 lc55o 7 18982. d 170 861 27 58 3b 13 + * j 300 .000 0.21*303 *. 115 0.02j555 2* **1 lb695 3 1916*. 1 171 *70 27 56 36 5 + + +1 310 .000 0.23h91 *.257 0.019650 25 31o lb975 19529.2 172 66 6 27 9* 3o 63 + 5y 320 .000 C. 22733 *.393 0.019192 26 186 17256 6 1933d. 17 5 .838 26 55 37 06 + 62 330 .000 0.22023 * . 5* 1 0.018579 27 056 17E*o 2 2027 0.6 17 ». 9d5 28. 79 17 i*7 + b 3 3*0 .000 0.21358 *.6B2 0.01800* 27 922 17838 2 206*7 .* 17o 110 29 25 S7 90 "7 j 350 .000 0.20733 *. 823 0.017*65 28 765 1613* 7 21026.7 177 215 29 73 3d 3o + 31 360 .000 0.201*3 *. 96* 0. 016958 2y .b*b 18*36 .0 21*1*. b 173 30 2 30 23 38 83 + 37 370 000 0. 19568 5. 105 J. 016*81 3u 605 167*2 3 218J6-* 17 3 373 30 7* J9 3 3 + 93 380 .000 0. 19U62 5.2*6 0. 01b030 31 362 19C53 7 22201.3 180 *2 8 31 27 59 8 + + 33 390 .000 0.18565 5.387 0.0156C* 32 218 19370 3 2 2602.5 181 *70 31 81 + 5u 50 v *G0 .000 0.18093 5.627 0.0152C0 33 072 19t92 3 25008. o 182 +98 32. 56 + G 90 51 j tZJ 000 0. 17219 5. 808 0. 01**53 3* .775 20353 25857.6 16* 52 33 *9 *2 00 521 **0 .000 0.16i*26 6. 038 0. 013778 3b *7* 21036 1 2*bd6.8 18b 500 3*. 6* + 5 15 352

«*60 .000 0. 15701. o. 368 0.01316* 38 ,169 217*2 1 25562. d 183 **2 35 8G + * 26 3*2 *30 .000 . 150-*-* 6. 6*7 0.012o02 39 .860 22*71 ,2 2c*59.5 190 35 36 95 *5 * j 5^3

500 000 0. 1*1.37 6.926 0.012088 *1 .5*8 23223 1 27379.0 192. 22 7 38. 10 *o 5* 6b2

146
ME THANE ISOBAR AT P 7.0 BAR

T DEN VOL DP/CT DP/OD E H S CV CP A OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/rlOL/< 1/SEC

90,,857 28.1bl 0. 03551 2 0.70 22 261,,073 3*73,,9 3*38,.8 67,.907 33,,15 32.,71 157 7 95,,000 27. 816 0. 03595 19. c*G6 235,,315 3662,,9 3738,.1 70,,26 8 33,,01 53,,1* 1537

100,,000 27.395 0. 03650 18.*19* 216..609 39*2,,2 3967,,6 73,, 31* 33,,10 53.,97 l*d*

105,.000 20.965 0. 5708 17.2588 193 .366 *208,,9 *23* ,9 75,,669 33,,18 5<*. 85 1*33

110,, J00 26.52* 0. G377J 16.1531 180,,718 **81,,8 *508,.2 78,.2*0 33,,11 55,,69 1373

115,.000 26. 071 0. 0383o 15. 0966 163,.7*7 *759.,9 *786,.7 83 .732 32 .88 56,, *3 132*

120,.000 25.O02 0. 03906 1*. 0835 1*7.,*96 50*2.,2 5069,.6 83., 1*9 32,,52 57 , , 1* 1271

125,,000 25.115 0.03982 13. 1063 131,,981 5328,,7 5356,,6 85,, *9 7 32,.13 57.,93 1213

130,,000 2*. 607 0. 0*06* 12.16E6 117,,179 5619,,9 56*8,.3 87,,787 31,,78 5 8. 90 1163

135., 000 2*. u75 0. 0*15* 11.2501 103,.0*9 6916,,6 59*6,. 6 90,.03 2 31,,53 63,,13 1107

1*0,,000 23.51* 0. 0*253 10. 3561 69,, 533 6220,,3 6250,.1 92,.2*6 31,,38 61,,72 1 3*6

1*1,,685 23.317 0. 0*239 10 .0585 85 .102 632*.,6 635*..6 92,, 989 31,, 35 62. 3* 1 2 7

1*1,,685 0. 6883c l.*5 3 0. 0o*396 8.,567 12393.,9 13*15,,8 1*2,.825 26..86 *1, 35 287

1*5,.000 0.66*bl 1.505 0.0615*6 9.,013 12*98,,0 13551,,3 1*3,,77j 26.,61 *0 , ,*1 292

150.,300 0.63266 1.531 0.057869 9,.666 126**,,0 137a0,,* 1*3,, 121 2c,.33 39,.31 30 u 155

.

,000 0.60*** 1.65* 0.05*7*9 10,,28b 12786,,8 139**,,9 1*6,.396 26,,13 38,,*9 337

loO..000 0.57922 1. 72o 0. 0520*6 10,.680 12927,, 2 1*135,,7 1*7., 636 2?,.96 37,,65 51*

lo5,.000 0.556*6 1.797 0.0*9b68 11,,*55 13G65,,6 1*323,. 6 1*3 ,7o* 25 ,36 37 .3* 321 170,,000 0.5357* 1. 867 0.0*7550 12,,012 13202,, 6 1*50 9,,2 1*9,, 87 3 25 .77 36,,92 32a

175,,000 0.51678 1.935 .0*5o*5 12,.556 13338,, * 1*632,,9 15 J,.938 25,,70 3c,.66 33* 180.,000 0.*9932 2. 003 0.0*3917 13., 088 13*73,,2 1*375,,1 151,,9o* 25,,o5 36,,29 3*0 1S5,,000 G.*8316 2. 07J 0.0*23*0 13,,609 13607,,2 15u56 .0 152,.955 26 ,62 36 ,1)3 3*o 190.,000 C.*6816 2. 136 .0*0892 1*.,122 137*0,,5 15235,,7 15 i,,91* 25.,60 36,, 6 6 351 195,,000 0.*5*17 2.232 0.03955c 1*.,28 13 873,, * 15*1*..6 15*.,6*3 25..59 55,, 7 a 35 7 200,,000 0.**106 2.2o7 0. 038317 15,,12o 1*005,,8 15592,.6 155.,7*6 25,,59 3 6 , ,57 3c2

205.,000 0. *2861 2. 332 0. 03716* 15,,619 1*137,,9 15770,.3 156,.623 25,,60 35,,*6 367

210,,000 0.*1726 2.337 . 03b068 16,, 106 1*269,,8 159*7,.* 157,,*76 25,.63 35,,33 372 215.,000 0. *Uo38 2. *51 0. 035079 16,,569 1**01., 6 1612*. 2 158., 338 25,.66 3b,, 31 377 220.,000 0. 39610 2.525 0. 03*132 17,,067 1*533.,* 16300,.6 15 i,,119 -> a .70 35 ,27 582

225,,000 0.38637 2.588 0. 0332*0 17,.5*2 I*6c5.,1 16*76,,9 159,,911 25,, 75 33,,2* 367 230,,000 0.37713 2.652 0.032398 Id,,012 1*797,,0 lb653,,1 16 0,,686 25,,31 35,,23 331

2 35.,000 0. 3o837 2.715 0. 031602 18,,*eo 1*928,,9 10829,,2 161.,*** 25.,ae 36,, 2* 39 s 2*0,,3 00 0.36002 2. 77d . 0308*6 16,,9*5 16061,,1 17005,.5 162,,186 2

C , ,96 55,,2c *j,j 2*5. 000 C 35207 2. 8*0 0. 030131 19.,*C7 15193. 6 17131,,8 162.,913 26,,36 35.,23 *u > 250,,000 0.3***9 2.933 0.029*50 19.,867 15326., * 1735e.,* 163 , ,26 26,,1* 35,, 3* * 3 255 , ,000 0.3372* 2.965 0. 02do02 20,,32* 15*59. 6 17536,,2 16*,,327 26,,25 35,, *0 -.13 260,,000 0. 33u31 3.027 0.028183 20.,779 15593,,2 17712,,* 165

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, 015 26,,3b 3 5 , ,*7 *17

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~* 270., 000 0. 31731 3. 152 0. 027027 21. 08* 15661,,9 180o8,,0 16 6,, 33 7 26,,o2 36,,66 *2 5 275,,000 0.31120 3.213 . 02o*oc 22,,13* 15 997.,1 182.6,,5 167,,012 26,,76 35, 76 hZr) 280.,000 0.3053* 3.275 0. D25967 22,,362 16133,, 18*25,, 5 167,,657 2fc , ,90 35.,6 7 m5

285. 000 C 29970 3.337 0.025*70 23,,023 16269,, 5 18605,,2 lo3,,29 3 27,,06 36,, 03 k37 230. 000 0.29*27 3.338 0. 02*992 23,,*7* 16*0o. 8 18735.,5 163,,92 27,,23 36. 1* **1

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330,,000 0.2572* 3. 887 0. 021753 26.,996 17636. 2 20257,, 5 173,,673 2 8,,80 37.,55 * 6 i 3*0.,000 0.2*9*3 *. 009 0. 021075 27., 867 17828. 6 2C635. 3 17*. 800 29. 26 37,,97 *73

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*0Q.,000 C. 21118 *. 735 0.017772 33,,0** 1968*.,9 22999,,6 181.,196 32,,37 *0,,93 510

*2Q. 000 G. 20095 4.976 0.01o395 3*,, ("5* 203*6.,0 23329,,5 18 3,,22 3 33.,50 *2. 0* 521

**0,,000 0.19168 5.217 0. 016102 36,,*59 21029. 7 2*631.,5 185. 20* 3*. o6 *3, 13 532

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*80. 300 C 17653 5.637 Q. 01*723 39. 85* 22*65.,6 2b*53,,5 163.,05 7 36, 96 *5

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147
HE THANE ISO 3AR AT P 8.0 BAR

T DEN VOL DP/CT OP/DO £ H S CV CP A OEG K MOL/L L/MOL BAR/K 3AR-L/M0L J/MOL J/MOL J/MOL/K J/MOL/K J/10L /< *I/SEC 9a 882 28. 163 C. 3 551 23.0990 251 20b 3W* 2 35J2 .6 67 911 33. 16 52 7J 1573

95 JOO 27.020 0.0359+ 19.6++7 235. 557 3681. 9 3710 6 70. 25 7 33. 02 5 3 13 1537

luJ 000 27. hOO . 03650 18. 1.21,6 216 870 39*1 1 3970 .3 73 003 33 11 53 9o 1*8+

105 000 2o. 970 0. 03708 17. 261.8 198 6** + 207. 7 *237 3 75 65 7 33 19 5* 85 1 + 31 lid 000 26.530 0. 03769 16. 1600 161 Oil *i*80 5 + 510 6 73 228 33 12 55 67 1377

113 000 26.077 0.03835 15.101*5 16 + 053 *758 3 + 739 80, 719 32, 89 56 + 1 132 + 120 000 25.o08 0.03905 li*. 092i* 1 + 7 817 50*0 5 5071 7 83. 13 + 32, 53 57 12 1272

125 000 25. 122 0. 03981 13. ne3 132 313 5326 8 5358 b 83 + 3 1 32 1 + 57 9 1219

130 000 2*.bl6 . 0-*062 12. 17t8 117 52* 5617 6 6 65 1 87 ?70 31 79 58 8b 1163

135 000 2 + . U85 . 0+152 11. 2c2o 103 + + 691 + 59+7 3 9 013 31 5 + oC C3 1109

1*0, 000 23.625 . + 251 10. 37 CI 89 910 b217 + 6251 ,+ 92 226 31. 39 51 65 10 + 9

1 ++ 379 23. u06 0. 0*3+7 9.bG15 7o 535 6*90 2 6525 .0 9* 150 31 33 o3 35 995

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150. ooc 0. 7 3 86 7 1. 351. 0. 066711* 9 2C0 12599. 3 1 3a32 3 1+3 692 26 o3 + G 7 + 29j

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135 000 0. 3?737 1.79+ 0. Qi.9236 1 3 3 + 2 13580 7 16 01b 151 69 8 25 71 36 6 3 3 + + 190 000 0. 3396u 1.853 . 01*71*66 13 .872 13715 i* 1519 8 .0 152 66 9 25 68 3o 2 3 35\i 195 000 0.52309 1.912 0. 0+j677 1 + 392 138*9 5 13376 9 153 60 9 25 06 36 03 3 33 200 JCO 0.50768 1.97: 0. 01**392 1* 9 0* 13983 1 15356 9 15 + 52 2 5 65 3 5 ,91 3bl 2d5 000 G.+9327 2. 027 0. 043015 15 *09 1 + 116 3 15738 1 153 + 05 25 66 35 73 3bo 210 000 0. + 797* 2.081* 0. 0*1733 15 908 1*2*9 1 15916 7 15o 236 25 08 36 67 371 215 JOO 0. *670o 2. 1 + 1 . 0*0536 lb , + Cl 1*381 8 lb-0 9* 8 157 10 + 26 70 35 6 3 37o 220 000 . + 550 2. 195 0. 3-j + l* 16 09u 1*511* 3 16272 ,6 157 92 1 25 7 + 36 .5' 3 31 225 ooo G . *+3b3 2. 25i» u. J333L0 17 373 1 + f + o 8 16*5 15 3 719 25. 79 35 , + 7 3oo 230 JuO 0.*329G 2. 310 . 037367 17 853 1 + 7/9 3 16627 3 159 +9 6 25 85 36 + 3 391 235 000 0. *227G 2.36o . 03o*30 16 323 1 + 911 9 1630* 5 160 2o0 25 91 35 + + 393 2*0 000 0.41301 2. i*21 .0335*3 18 ,801 150** ,7 16931 .7 ltl 007 26 99 35 , + -> - - j 2*5 000 0. *03?8 2.1*77 0. 03+7U3 19 27u 16177 7 17158 9 lbl 738 26 06 3 5 + 7 + + 250 000 0. 39*99 2.532 0. 03390* 19 7 3b 16311 U 1733b * 162 + 55 2t 17 36 6 o + 9 2s5 000 0. 38659 2.587 . 0331+5 20 200 15+++ c 1751 + 16 3 138 26 27 35 6 5 + 13 260 000 0.37857 2.6 + 2 0.032*22 20 .661 15578 ,7 17o91 ,9 163 8+9 2c 39 35 62 + 17 2o5 OoG 0. 37089 2.69o 0. J31732 21 120 15713 2 17370 2 16* 526 26 61 35 6 ) + 21 270 000 0. 36351* 2.751 0. 031u73 21 5 7 6 168 + 3 3 lo0+ 8 9 163 19b 26 6 + 35 78 + 23 275 000 0. 356*9 2. 605 . 030**2 22 031 16933 ,9 18226 165 85L 26 76 3 6 83 + 2 i 280. 000 0.3+972 2. 65 9 0. 029839 22 + 3 + It 120 1 13 + J 7 7 16 -j 501 26 93 35 9 i + 33

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,' 290 000 0.33D95 2. 96 3 . 02870* 23 365 1639+ 6 137o8 8 It 7 76 3 27 ? cr 3 6 2 + + + U 293 000 0.33093 3.022 0.028171 23 .833 lb 53 3 .0 18950 * 168 389 27 + 2 3b 39 + -,+ 300 000 0. 32513 3. 07o 0.027o58 2* ,28u 16672 1 19132 ,7 16 9 002 27 oC So 5'* + 1*9 31o 000 0. 31*1* 3.193 .02ooe9 23 170 16953 1 9 + 99 7 17 j 23 5 27 98 3b 87 + 33 32^ 000 0. 30389 3. 291 6.023769 26 .055 17237 6 19O70 1 171 331 28 36 37 2 3 + c2 330 QUO 0. 29*32 3. 39d 0. 02+950 2b 936 17626 2 202+ + ,* 172 533 28 62 37 b2 + 63

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350 000 0.27b92 3.611 0. 023*31 26 667 18116 l. 210J5 3 17 + 771 29 76 36 . + 9 -.81 360 ,000 0.2o9QG 3. 713 0. 3227i*l 29 558 18*13 5 21392 5 175 36 2 30 26 36 96 + 87 370 JOO 0.26152 3. 621* 0. 022092 30 + 25 18725 c 2173 + 5 17^ 936 30 76 39 -t -1 + 93 380 000 C.25**o 3. 93 J 0.021*80 31 292 19037 c 22181 + 177 995 31 29 39 95 + 9 J 390 .000 0.2+778 + . 03o 0.020902 32 .165 19o5* .8 22333 l* 179 039 31 83 + L + b 5 03

* jO .000 0. 2i»li»5 i*. 11*2 . 02035b 33 .016 19677 1* 22990 7 160 0/ 32 38 + 99 510

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<»<tfl 000 0.21912 <*.56i* . 016*33 3o . + + + 21C23 .3 c +67 •» .3 18* 030 3L 06 + 3 20 5 3? ^dO 000 0.2091*6 i*. 77-* 0. 017oG* 33 1*9 21730 2 255+9 ,b 186 026 35 81 + * 33 543 48 000 G.200b2 + . 985 0. 0168*8 39 8*9 22*60 C 26++? 7 187 936 36 97 + 5 * 7 553 500 000 0.19251 5. 19-* 0.016156 1*1 5*6 23212 7 273o8 3 161 815 38 12 + 6 5 9 5o3

148
METHANE IiOBArt AT P 9.0 BAR

T DEN VOL DP/OT DP/OD E H S CV CP W OEG K M0L7L L/MOL 6AR/K 8AR-L/M0L J/MOL J/MOL J/iCL/K J/MCL/K J/10i_/K "1/SEC 90.908 23.165 0. 03551 20.6957 251 339 3474 5 5506 5 67 915 33 16 52 69 1576

95.000 27.825 0. 03594 19.6489 235 798 3680 8 3713 2 70 246 33 03 53 12 1537 100.000 27.404 0.03649 18.4297 217 131 3940 .0 3972 8 72 991 3 3 12 53 94 143?

1J5. 000 26.975 0. 03707 17.2708 156 .921 4206 4 4239 8 75 645 33 20 ?4 83 1451

110. 000 26.535 0. 03769 16.1670 181 ,303 4479 1 4513 78 215 3 3 13 55 6? 1373 115.000 26. 063 0. 0383 + 15. 1124 164 359 4756 8 47-31 ,3 6 705 32 9 56 3 8 132-j 120.000 25.C15 0. 03904 14. 1013 148 136 5038 7 6u73 9 83 120 32 54 5 7 09 1273 125.000 25. 130 0.03979 13. 1283 132 644 5324 8 536 6 35 46 6 32 15 57 6 7 1220 130.000 2t. 624 O.O+Ool 12.1879 117 868 5 615 4 5652 67 75 3 31 60 53 62 llco 135.000 24.095 0. 0+150 11.2751 103 769 5911 5 5 94 8 9 8 9 995 31 55 60 03 llu3 140.000 23.S36 0. 04249 10. 3841 90 28b 6214 5 6 25 2 8 92 205 31 4 61 sy 1051 1^5.000 22.942 0. 04359 9.5090 77 348 £526 2 656 5 4 94 399 31 33 •j 3 53 53 + 140.639 22.713 0. 0+403 9. 1898 72 710 tt43 3 6633 ,0 95 204 31 31 64 37 9o5 146.339 0. 88112 1. 136 0.084441 3 230 12452 9 13474 3 141 465 27 26 43 6 + 237 150.000 0.85034 1. 17b 0.060540 3 711 12551 9 1 3ol 3 142 371 26 97 42 41 292 155.000 0.d0739 1.239 0.075344 9 |4?5 12703 8 13318 »

5

1 + 3 736 26 o2 4O 9 + 301 loO. 000 0.76992 1. 299 0. 071010 10 97 12851 4 1402 u 4 1<*5 016 26 38 39 8? 303 165.000 0.73673 1. 357 0. 067304 10 735 12995 14217 5 l4o 231 26 19 39 02 31c 170.000 0. 70b99 1.41 + .064076 11 347 13137 9 1441 9 147 366 26 05 38 36 323 175.000 0.68009 1.470 0.061225 11 938 13277 9 14O01 3 143 490 25 94 37 62 323 180. JOO 0. 65558 1.625 0.058o78 12 512 13416 4 14739 3 149 549 25 86 37 3 9 53o 185. 000 0.63309 1.530 0.05o382 13 071 13553 7 14975 3 16 j 56 8 25 30 37 03 342 190.000 0.61236 1. 633 0. 054297 13 618 13 689 9 15159 • 6 151 55 2 2 5 7£ 36 75 3+) 195.000 0. 59315 1. 63o 0. 05239G 14 153 13625 .3 153 + 2 6 152 50 2 25 73 36 43 3 5'+ 200.000 0.57529 1.733 0. 050637 14 680 1396J 1 15524 5 15 3 423 25 72 56 2

7 3=9 205.000 0.55361 1.790 . 0490 17 15 196 14094 3 16705 4 154 317 25 72 36 11 3o5 210.000 C. 54299 1. 842 0.047514 1p 706 14223 1 15835 6 155 185 25 73 35 97 370 215.000 0.52833 1.893 0. 04oll5 16 212 14361 6 160o5 1 15 6 030 2 5 75 3 5 86 37 j 220.000 0.51452 1. 944 . 04430c Id 711 14495 15244 2 15o 354 25 79 3 5 7 ! 3d J 225.000 0.50149 1.994 0.043580 17 204 14t28 2 1642 2 9 157, 65 7 25 83 35 71 385 230.000 0.48917 2. 044 0.042427 17 o92 14761 .5 16601 3 153 44 1 25 39 35 67 39J 235.000 0.4774+ 2. 34 0. J41341 18 17b 14694 7 167.'

5

6 15 3 20 8 25 95 35 6-, 3 94 240.000 . 46041 2. 144 .040315 lo b55 1 5 C 2 8 1 169 j 7 8 15 i S5 6 2t 02 35 6-> 399

2 + 5. 000 0. 45580 2. 194 u . U39344 15 132 15161. 7 17135 9 16 3 69 3 26 11 35 65 40 + 250.000 0. 44503 2. 243 J . 038423 19 oC6 15295 q 17314 2 161 413 2t 20 35 67 40 3 255.000 C. 43626 2.292 0. 037549 20 075 15429 7 17492 7 162 120 26 30 3 5 7 1 4 12 260.000 0.42711 2.341 0.03b716 20 542 16564 2 17671 4 162 814 26 41 35 7"' 4l~ 265.000 a.kxo3f 2. 390 0.035923 21 0b 15699 1 1785 3 16 3 496 26 53 35 a j 421 270.000 0.41000 2. 439 0. 035167 21 469 15834 c 18029 7 16 + 166 26 66 5 5 91 42> 275.000 0.40198 2. 433 0.034443 21 929 15970 6 18209 5 16 + 826 26 80 30 1 42 3 230. 000 0. 39429 2. 536 0. 033752 22 366 16107 2 16339 8 165 476 26 95 56 11 432 285.000 0.38690 2. 535 0.033089 22 842 16244 4 13570 6 16o 116 27 10 3b 23 4 5 -j 290.000 0.37980 2.633 0.032453 23 296 16382 4 13752 1 16o 7,7 27 26 36 3 5 44 295.000 0. 37296 2.631 0.031643 23 749 16521 1 18934 2 167 370 27 44 5b 49 4 -» -, 300.000 C 36o36 2. 729 0. 031257 24 20U lb£60 5 19117 167 934 27 ol 5c 6 + 447 310. JOO 0. 35393 2.625 0.030151 25 097 16942 19434 9 16 9 191 27 99 3 6 9 c 4'J-, 320.000 C. 34232 2.921 0. 029124 25 989 17227 1 19856 2 17 370 28 4G 3 7 31 461 330.000 0. 33149 3.017 0.02811:9 26 876 17516 2 20231. 3 171 524 26. 83 37. 7 5 4c3 340.000 I. 32134 3.112 0.027276 27 759 17809 5 20610 3 172 655 29 29 38 11 475 330.000 0. 31181 3.2J7 0.026441 23 638 18107, 3 20993 6 173 7ob 29 77 38 65 431 3o0.000 0. 30285 3.302 0. 025o57 29 514 18409 7 21331, 5 174. 35 9 30. 26 3 9 02 487 370.000 0.29n4l 3.397 0.C24920 30 367 18717 1 21774 17 5 934 30. 78 39 5 J 49 3 380.000 0.28644 3.491 0.024226 31 257 19C29 5 22171 5 176. 99 4 31 30 4O 00 499 390.000 0.27690 3.686 0.023570 32 124 19347 1 22574 1 173 04 31 84 + 51 £0 5 400.000 0.27175 3. 680 0.02296C 32 989 19670 22931 9 17 9. 072 32. 39 + 1 + 510 420.000 0.25653 3. 863 0.0216C5 34 713 20332. 3 23813 5 131 101 33 52 42 15 521 440.000 0.2465b 4. 056 0.020772 3b 429 21C17 24bo7 1 18j 03 6 34 67 43. 24 532 460.000 0.23567 4. 243 0.019835 38 139 21724 3 255+3 2 185 C33 35 32 44 57 54 3 480.000 0.22572 4.430 0.018980 39 844 22454 £ 2o44 1 8 18o 945 36. 9 8 + 6 55 553 500.000 0.21658 4.617 0.016197 41 544 23207 6 27353 1 183 825 38 13 + 6 62 5c J

149
ME THANE ISOBAR AT P = 10.0 BAR

r OEN VOL 0P/6T OP/DO £ H S cv CP H OEG > MOL/L L/MOL BAK/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOl/K J/ 10 ,/K 1/SEC

90 .933 28.1o7 C. 03550 20.O92* 251 471 3474 9 3510 .4 67 919 33 17 5Z b9 1576

93 .000 27.829 0. 03593 19.6530 236 .0 39 3679 .6 3715 .6 7j .23 6 33 04 53 11 1533

1J J ,0u0 27. *09 . 036*0 18.4348 217 391 3938 9 3975 .3 72 .930 33 12 53 93 1435

105 000 26.960 0.03706 17.27b9 199 198 4205 ,2 *2*2 • 3 7 5 ,633 33 .20 5* .82 1-32

llu .000 26.5*1 0. 03768 16. 1739 181 59* 4477 7 *515 . H 7d 202 33 14 55 .63 1379 115 .000 26.089 0. 03833 15. 1203 16* 06* 4755 ,2 47 93 5 80 .69 2 32 91 5b 36 132o 120 000 25.D22 0. U3903 14.1102 li+8 * 5 * 5037 5076 .0 S3 . 105 32 56 57 .06 127 + 125 .000 25. 136 0. 03978 13. 1382 132 .975 5322 ,9 53 = 2 .7 3 3 .-50 32 .16 57 .83 1221 130 000 24. 633 0. + 050 12. 1990 118 212 5613 .2 565 3 .6 B7 . 736 31 81 5a .73 1167

135 ,000 24. 1U 0. + 1-9 11.2675 10* 127 5909 C 5950 .5 89 .976 31 ,55 59 .98 1111

1*0 OOu 23.647 0. G*24/ 10

.

39ei 90 662 6211 6 625* .1 92 184 31 *1 •31 62 10 52 1*5 .000 22.955 G . 0-356 9.>248 77 7-3 6522 6 65 j t . * 9- .37 5 31 34 63 45 991 1*9 1J8 E2.h35 0. u-*57 d. 81*2 67 4 79 b78o 3 68 30 .9 9a .174 31 28 55 33 9 3d

1*9 108 0.97d9o 1. 021 . C9+yC6 8 052 12472 i« 1 3*9 3 .9 14 J .659 27 *5 ** 6o 2dj 150 000 • 96863 1. 032 0. 0935*5 8 198 12501 .3 13533 >6 1-1 ,125 27 35 + .• .*2 ?33 155 J 00 0. 91ol2 1. G92 0. 06odb2 8 970 12659 C 13 750 6 142 .5*8 26 91 42 . 45 297 16j 000 0.871U2 1. 1*8 .081*57 9 orto 12611 1 13959 1 143 672 26 oO -1 3 3 a

1o5 000 0. 8316* 1.203 . G7bo9o 13 361 12959 1 lMlol . 6 1*3 ,119 2c 37 3 9 .99 ' 313 170 000 0. 796*8 1. 25o 0. 072975 11 003 131U* 14359 3 146 300 26 20 39 17 32] 175 000 0.76499 1. 30/ 0.0695*8 11 621 13246 * 14553 .7 147 426 26 07 id 52 32' 180 000 0.73o46 1. 35d 0. 06d511 12 217 13367 1-^** 9 14d 50 3 25 97 37 59 5 5 + 185 000 G. 7101*1 1. 40o . 0b3793 12 796 13526 ,1 1*933 .7 149 ,53 8 25 90 37 » 5 C 3-

J

190 000 0. o6&49 1 . * 5 7 0. U61336 1 3 361 13t63. 9 1512 6 150 ,535 2 5 64 3 7 21 3^3 195 ooo 0.66441 1.505 0.05910* 1 J 912 13800 7 16305 151 *97 25 61 3c 93 3-^d 200 000 0.61*39'+ 1. 553 0.057059 1* + 53 13936 7 16*69 o 152 426 25 79 3b 65 S33 20» 000 G.b2*8o l.bO J 0.055177 1- 98* 14072, 156/2 ,- 153 330 25 78 36 — 5 3iS 210. 000 0. b07u/ 1. 6*7 0. 053*3b 15 5C7 14206 9 15654 ,1 15 + 206 25 79 io 2d 3j ) 215 000 0. 59037 1. o9-. 0.051819 lb J22 1*3*1 3 16035 2 15 3 05 6 25 80 3b l- 3 7- 22u U JO C. 574o9 1.7*0 0. 050312 Id 530 1*1-75 c 16215 6 155 8od 26 d3 io 3 5 7 , 225 JOj 0.55991 1.73o .0*8903 17 033 14e09. = 1639s 3 15 o 697 25. d7 3 5 95 3o- 230 000 C. 51+595 1.832 0. 34/561 17 530 14/43 5 16575 1 157 43b 25 92 36 81 >d j 235, 000 0.5J274 1. b77 0. 046337 18 022 1*877. * 16734 3 lid 25 6 25 96 35 65 Si-, 2*0 000 C.52u22 1.922 . 043165 Id 510 16011 * 16933 7 16 i 012 26. 06 35 63 35 3 2*5. 000 C. 50832 1. 9o7 0. U**057 18 993 151*5 5 1/112 8 15 J 761 26. 14 35 83 - j 3 250 000 O.*9701 2. 012 . 043JG8 19 473 15279 9 17292 Id j u75 26 23 35 8 + *.!/ 2?5 000 G. 48622 2. 057 0. 0*2013 19 9*9 15*1*. 6 1 7*71 3 161 183 26. 33 3 5. 87 -12 2o0 000 0. t7s9j 2. 101 0. J*lot7 2o 423 165-9 6 1765 ,7 161 882 26 - - 35 9? -It 2o5- 000 G. *6blG 2. 1 + 5 0. 0*0167 2b 893 15685. 17830. * 162 5o6 26 56 35 5d 42| 270 000 o. *567 o 2. 190 J. G393C9 21 3tl 15e20 9 18010 5 lb i Z^i 26 o9 36 D5 + 2- 275 000 G.**7fc9 2.23* 0. o3d*90 21. 82o 159=7 3 1 8191 16 3 902 26. d2 3b 1- *2J

280, 000 u.*39U6 2.273 .037707 22 288 1609* 3 18 3 7 1 9 16- 33* 26. 97 36 23 *3| 285. 000 0. t3ui'? 2. 321 0. 036957 22 7*9 16231 9 16353 3 165 196 27 12 36 34 4 ;1 290 000 0.42280 2. 3o3 O.U3b239 23 208 16370. 1 16736 3 165 829 27. 28 3o 4 J --..i 295 ^\Ji C .41315 2.409 0.035560 23 06- 16509 2 18917 9 16o 454 27 *5 Sb 60 - - > 300. oso 0.40777 Z.-r5Z .03-889 2*. 119 lct*8. 9 19101 3 167 070 27. o3 3 b 7-t -* 7 310 000 C. 39383 2.539 0.033bs2 25 024 16931 19470 .2 l6o 279 26. 01 37 03 *5 * 320 000 . 36L06 2.62o 0.o32*C5 25 923 17216, 7 19d + 2 * 169 -61 28 42 37 *a -cl 330. 000 0. 3687-+ 2. 712 0. 031*lu 26. 81b 17506 2 20218 2 17 J 618 28. 35 37. 7 3 46o 340 000 0. 3571.0 2.790 . 030*07 27 705 178O0 205 9 6 171 751 29 30 3 e 19 w,

- + 3s0. 000 G. 3*c7b 2. 83* 0.029*69 28 590 16098. 2 20932 172. 8b4 29. 7b id. 62 4 )! 360. 000 0. 336?o 2.969 0.028589 29. *7U 18*01. G 21370 5 173 959 30. 26 39 03 46,' 37J. 000 G.3273* 3.05;. .027763 30. 3*8 18708. 7 21763 6 173. 03o 30. 79 39. 53 49 > 38u ooo 0. 31045 3.1*0 0. 02o964 31 222 19021. 5 22161 7 17 3 098 3 1, 32 +C. 05 4 i i 390 000 0.3100'. 3. 225 0.02o250 32 093 19339. * 22564 8 177 145 31. 65 - c

a. 7 50 i mjo.. 000 G. 30208 3 . 3 1 J 0.023335 32 962 19662. 6 2Z^73 17d. 178 32. 41 *1. 3 51 1 42u 0.0 0.28735 3.480 0. 02*2/5 3* 692 20325, 5 Z3dd<5 o 180 209 33. 53 *2 17 6 22

H'+O 000 C. 271.02 3.6*9 0. 023119 36. -15 21010. 6 24b30. 182. 196 34. 38 -3. 29 532 4o0 000 C.2615C 3. 818 0.022072 38 130 21713. 5 25536 d Id-. 1*5 35. 83 --. 40 5* 5 *80. 000 G. 25082 3. 987 u. 021117 39. 340 22**9. 1 ?6*3b 1 19o. 058 36. 99 + 5. 53 55 3 500 ooo 0.240b6 4.155 0.0202*3 41 5** 23202 5 27337 9 187 94 3e. 13 - c fc3 5b 3

1 50
METHANE ISOBAR AT P = 12.0 BAR

T CIEN VOL DP/DT OP/OD E H S CM CP W OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/St'C 90.985 28.171 0.03550 20.b859 251.736 3*75. 5 3518. 1 67. 928 33. 19 52. 67 1578 95.000 27.837 0.03592 19.6613 236.521 3677. 8 3720..9 70. 21* 33. 06 33. 09 153 3 100.000 27.1*16 0. 036t7 18. 1*1*1.9 217.911 3936,,6 3930,1* 72. 95 7 33.• 1* 53. 91 lt8o 105.000 26.990 0.03705 17.2869 199.751 *202. 7 *2*7,,2 75.,609 33.,22 5*. 79 1*33 110.000 26.552 0. 03766 16. 1878 182.176 **7*. 9 *520. 1 78,.177 33. 16 56,,60 1380 115.000 26.101 0.03831 15.1360 165.273 1*752., 1 *79B,,1 8J. 60 5 32. 92 56. 32 1328 120.000 25.635 0.03901 It. 1279 1*9.068 5033,,6 508C.. * 83..076 32. 57 57, 01 1275 125.000 25.153 C. 039^6 13.1380 133.635 5319.,0 5366 , ,7 83,,*19 32. 17 p7. 77 1223

130. 000 2*. 650 0. 0+G57 12.2211 116.899 5608.,9 5o57.,5 87.,702 31..32 58..70 1169 135.000 2t. 123 0. 0*11*5 11.3122 lOt. 8*2 590*.,0 5953,,8 89..939 31. 57 59. 69 1113

lt*0.000 23.569 0. 0-*2i*3 10. l*2E8 91.*10 6205.,9 6256,18 92,.1*3 31. *3 61. *0 1055 lts.aoo 22.980 0.0+352 9.6sfc2 78.530 6516.,1 o56 6,,* 9*. 32 9 31. 35 o3. 23 99 + 150. 000 22.31*9 0. + 1*75 8.6961 66.123 o836.,7 6890,,i* 96,,512 31. 27 06..62 930 153.198 21.91b 0. + 563 8.1*68 58.393 70*8.•** 7103,,1 97,,915 31..18 37,,t3 8 87 153.198 1. 17836 0.6*9 0.116826 7.676 12*99.,9 13516,,3 13+,,790 27,,3* + 7,,t5 28o 155.000 1.15192 0. 668 0. 1132C7 7.997 12561. 13602. 7 1*0. 333 27,,61 + b,,33 26-i loO.OOO 1. 08719 0.920 0. 10*7*5 8.822 1272*.,3 13628,,1 1*1,,76 9 27,,13 *3,,95 29a 165.000 1. 03215 0. 969 0. 09793* 9.562 12880. 9 1*0*3. 5 1*3. 095 26,,79 *2,,23 507 170.000 0.981*33 1. 015 0. 092256 10.293 13C32. 6 1*251.,7 1**,. 338 26. 5* *1. 05 315 175.000 C. 91*209 1.061 0. 087*06 10.968 13160.,7 1**5*.,* 1*5 , ,51* 26,,35 *0. 09 322 180.000 0.90t32 1. 106 0.083192 11.613 13326,,0 1*65 2,,9 l*o,,632 26,,21 39,,33 330 185. 000 0.87022 1. 1*9 0. 079*75 12.235 131.69..0 1*8*6,,0 1*7,,701 26,,10 38,,71 33b 190.000 0.83919 1.192 0.076159 12.837 13610..3 150*0,,2 11*8,.726 26,,02 33,,21 3t j 195.000 0.81076 1.233 0.07317* 13.*22 13750,,1 15230,,2 1*9,,713 25,,96 37,,60 3^ i 200.000 G. 78*56 1.275 0.070*t6 13.993 13888. 8 15*18,.* 150., 66 b 25. 93 S7. to 355 205.000 0.76031 1. 315 0.067992 1*.551 l*02o,,6 1660*,,9 151.,587 25,,90 37,.1/ 361 210. J00 0.73776 1. 3p3 0. 065720 15.099 1*163., c 15790,.1 152,,*80 25,,90 36,,93 3co 215. 000 0.71673 1. 39s 0. 063623 15.637 1*300. 1597*. 3 153,,3*7 25,,91 36,, 7* 372 220.000 0.69703 l.*35 d. 061678 16.167 1**36.,0 16137,,6 15*., 189 26,,93 36,.58 3 77 225.000 0.67853 l.i*7* O.G598c9 16.688 1*571,> 6 163*0,,2 155.. 010 25.,96 3b . tr> 362 230.000 0.66112 1.513 0.058178 17.20* 1*707,,1 16522,.2 155.,810 26,,00 36,,3o 387 235.000 0. 6l*<*k8 1.551 0. 05659* 17.713 1*61.2,,u 16 7 3,,8 15o.,591 2b,,06 56,,28 392 2*0.000 0.6291'* 1.569 0.055106 18.21c 1*977,, 7 16885,.0 157,, 355 2t,,12 36,. 2 5 397 2t5.000 G. 611*1*1 1.628 0.05370* 18.71* 15113,,0 17066,.1 158,,101 2b,,20 5 6 ,20 toi 250.000 0.60u*2 1 • 66o U. 052361 19.208 152*8,,5 172*7 ,,1 153,,333 26,,29 3b,, 19 *0 j 255.000 0.58712 1.703 0. 051129 19.b97 1538*,,2 17+2o,.1 159,,5*9 2t,.38 3t .2C *lu 260.000 0. 57i*i»i. 1. 7*1 0. 0*99*2 20.183 1652J. 2 17o09,,1 lbO,,25 3 26,,*9 36,,23 tip 265. 000 0.562.56 1.778 0. 0*8815 20.b65 15fc55.,5 177.0,,1* 160,,9+3 26,.61 36 . 27 *19 270.000 0.55081 1.816 0.0*77*2 21.1*3 15793,,2 17971..8 161.,621 26,,73 36.. 3.3 *2b 275.000 0.5397c, 1. 653 0.0*6720 21.019 1593J,,* 18153,,3 162,,289 26.,87 36,,*o *2 7 280.300 0.52919 1.690 0.0*571*5 22.092 16C68,,2 18335,.8 162,.9*5 27.. 01 3d . te *31 285.000 0.51905 1. 927 0. 01**61* 22.562 16206,> 5 18516,.5 163,,692 27,.16 3o,,53 *3? 290.000 0.50932 1.96 3 0.01*3923 23.029 163*5.,5 18701,, 6 16*,.229 27,,32 36,,69 *3 3 295.000 0.1*9997 2. 000 0. ut3069 23.1+9* lb*B5,,2 18885,. * 16*..857 27,,*9 ic.61 t*3 300.000 0.*9G98 2.037 0.0*2260 23.957 16625,,6 19069,,8 165.. *7 7 27,,o7 3b.. 9 + t*7

310. 000 0.1*7399 2.110 0.0*0710 2*. 877 16908,.9 19**0 .6 166..693 26,.0* 37 .23 *6* 320.000 0.1*5620 2. 182 0.03928* 25.790 17195,,6 19811.,,6 167,,880 28,, *5 37 ,5 7 tgl 330.000 U,t4^1) 2.255 0.037962 26.696 17*8o,.2 20192..0 169,,0*2 26 .68 57 .93 to3 340.000 0.1*2973 2.327 0.036730 27.597 17780.,9 20573,.3 17u,.180 29.,33 36 . 33 *7 + 350.000 0.1*1681* 2.399 0.032580 28.*92 18079,.9 2 958,,7 171,,297 29 ,81 .56.,7o tb 1 360.000 Q. *U*73 2.1*71 0.03*503 29.383 18383,> 6 213+8.,5 172,.395 30,,30 39,,20 t87

370. 0G0 0. 39333 2.5i»2 0.033*92 30.270 18692.,0 217*2,.9 173.,1*7 6 3C,.81 39,.67 + 93 380.000 0.38258 2.61* 0.0325*1 31.153 19005.,5 221+2..1 17*.,5*0 31,, 3* *0,. lb t99 390.000 0.3721*2 2.685 0.031o*5 32.032 1932*.,0 225*6,.2 175,,59 31,,68 *0 .67 5d3 too. 000 0.36280 2.756 0.03 0799 32.908 196*7,.9 22955 ,5 17o,.626 32,,*3 + 1., 19 5U

t20.000 0.31*503 2. 898 0.0292*0 3*. 652 20311,,9 23789 .6 176,. 66 1 3 3,.55 + 2 .26 522

1*1*0.000 0.32896 3. C*0 0. 027837 30.387 20998,,0 2*6*5..9 180,.65 2 3*..70 *3,.35 532

ttoO.OOO 0.31436 3.181 0.026665 38.112 21706..6 2552*..1 182..60* 35 .85 * .t7 5*3 tao.000 0.30102 3. 322 0.025*07 39.831 22*38,,3 26*2*.,7 18*..520 37,,00 + 5.,69 553 500.000 0.28860 3.*63 0.02*3*9 *1. 5** 23192,.<* 273*7..6 18o..*0* 38..15 + 6 . .71 5o3

151
H£ THANE ISO 3Ar< AT P = 14. G BAR

T DEN VOL DP/OT OP/OD E H S CV CP W OcG K MOL/L L/MOL eArf/K 8AR-L/M.0L J/MOL J/MOL J/-10L/K J/MOL/K J/50L/K •l/SEC 41.036 28.175 . 055*9 20. o793 252 001 3476 1 3525 a 67 936 33 20 52 66 1576

45. JO J 27.8*o 0. 03591 19.6695 237, 001 3t75 8 372b i 70 19 3 33 07 53 07 154J

101). 000 27.427 . 0364b 18.4550 21o 429 3934 4 39d5 4 71 935 33 16 53 89 1487 105.000 27.000 0. 0570* 17. 30C8 200 302 4200, 2 *252 l 75 565 33 24 54 7o 143* 110.000 26.563 0. C37o5 16.2015 182 757 *472 2 4 52 * 9 73 152 33 18 55 6/ 1381 115.000 20.113 0. 03829 15.1516 165 881 *7*9. 1 *802. 7 80 o36 32. 94 56 23 1324 120.000 25.649 0.05834 14. 1454 149 .721 5030 1 5034 7 83 U48 32 59 = b 9 a 1277 125.000 25.167 0. 03973 13. 177b 13-. 293 5315, 2 53/G 3 85 388 i? 19 57 71 122 = 130.000 24.bb6 0. G-.G5* 12.2431 11 9 563 £604. 5 56o 1 3 87 66 9 31 3* = 8 62 1171 13=.0o0 24. 142 . 04142 11. 3367 105 556 6 699 1 = 957 1 6 4 902 31 59 49 73 111 = 1*0.000 23. =91 0.G.239 10.*533 92 155 c200. 2 6259 6 92 102 31 *4 ol 2 7 1053

145. J OU 23.UC6 0. 4 347 9.5872 79 313 6509 6 6570 4 9* 283 31 37 t>3 12 99/ 150.000 ZZ.37i . G*4o9 8.7316 66 9? 3 6829 689 1 5 9o 46 31 29 = 5 40 93* 155. 000 21-. 696 0.0*609 7. b774 5* 966 7160 9 7225 * 93 b49 31 11 58 Z7 8o,' 15b. 82* 21.43u . 046 = 5 I

.

5o3o 50 o99 7285, 7 7351 1 94 455 31 01 = 9 54 8*2

15o.82<* 1. 38353 0.723 . 14017* 7 28b 12615 1 1352 7 133 837 28 23 = 32 23 = IdO.OCO 1.32o68 0.75* 0.132146 r 891 12627. 5 13d82 8 13 9 82 27 78 *7 9) 291 lb5.000 1.25032 U.80U 0.121993 6 .757 12795 ,5 13915 2 141 .251 27 28 45 21 30 1 170.000 1. 1859* 0.843 0. 113O70 9 550 12955 6 1413c 3 1*2 571 26 92 * 3 3 5 310 175.000 1. 13027 0. 885 0.107131 10 .291 13110 ,7 1*3*9 lH 1*3 .606 26 67 *1 ,9* 31 3 ISO. 00 J 1. 08129 0.92 = 0. 101399 10 491 13261 6 14556 3 14* 97 2 2o. 47 40 87 3Zi 185. 000 1. 0376* 0. 9o* 0. 096431 11 ocli 13409 3 14756 5 1*0 030 2e 3Z *G 3 332 140.000 0.99831 1. 002 0.092061 12 303 13 55* 5 1*956, 9 147 138 26 21 39 3 = 334 195.000 0.962bG 1. 054 0. 08O172 12 923 13697 8 15152 2 143 153 26 13 5H 7 ) 34 = 200.000 0.92492 1.075 j. 084678 13 526 13e33 4 153** 4 1*4 129 26 07 3d 33 332 205.000 G. 89986 1.111 0. 081514 1* .113 13979 8 15635 6 151 071 26. 03 37 95 3s 5 210.000 0.8720b i. 1*7 0. 7 8t28 14 dP7 1*119 2 15724 6 150 981 26. 02 37 6* 3o * 215. 000 0.8*62* 1. 152 0. 075981 15 248 14257 7 15912 1 151 864 26 1 37 39 37j 220.000 0.8221b 1. 21 = 0. 07 55*1 15 8CG 1*395 c 160 48 4 152 721 2fc 02 37 lc 57 = 225.000 0. 799b4 1.251 0.071280 Id 3*1 1*F33 ,0 16233 .8 153 554 26 05 3c 99 380 230. 004) 0. 77044 1. 285 0. 069178 lb .875 1*670 164o8 4 154 365 26 08 36 85 3 8 = 235. JOO 0. 75860 l. 318 0.067217 17 *G1 i4e0o 6 lo652 3 155 156 26 13 36 7 5 3 4

r

) 2*0.000 0.739B3 1. 3iZ 0. 06=360 1 7 421 14943 4 16=35 8 155 92 9 26 19 3t 65 3 4 = 2*5.000 0.72208 1. 385 0.063o56 18 *3* 16080. U 17018 9 l5o c8* 26. 26 56 54 4u J 250. 000 0.70527 1.418 0.062033 lb ,942 15216 7 17201 ,7 167 42 3 26 35 56 66 4 = 255.000 G. 68931 1.451 0. G605GI 19 *44 15363 C 1736* 5 153 147 26 *4 5o 5 * 40 J 260.000 0.67413 1. 433 . 054u53 19 942 15490 5 1 75o7 2 15d 856 2fc 54 3c , =3 -1 « 2o?.000 0.6=968 1.51c 0. 057dP1 20 *3b 15627. 7 1773G 154 553 26 06 56 c j * 1

J

27O.000 0. o4589 1.543 . 05o376 20 92c 16 765 4 17452 3 160 236 26 78 36 LI 422 275. 000 C. 63272 1.580 0.055139 21 *12 16903 4 16116 1 16J 90 9 26 91 3b l>7 *2; 2d0.000 D . 6 2 1

3

1.613 0.053459 21 39* 16C42 1 3249 ,b 161 57 27 05 5c 7- 43j 285. 000 0.60606 1. 6*5 0. 052633 22 37* 16161. 1 18*83 5 162 221 27 2 3 6 02 4 34 240.000 0.59b50 1.676 0.051758 22 850 16320 8 lbo = 7 8 ltc bo2 27 36 3o HZ 4 33 235.000 0. 56=4G 1.708 0. 050/29 23 32* 16461 1 13652 7 163 *94 27 = 3 57 > 4*2 300.000 0.57*74 1.740 0. 04^7*5 23 795 1l602 2 19038 1 lo- 117 27 7G 57 1 = -,,- 310.000 G. 55*b2 1. 803 . 0*7394 2* 731 16b8b 7 19*1G 9 lb = 34 28 oo 37 42 453 32J.00O U. 5334 = 1. 866 0. 04bl87 25 b57 1717* 5 19786 7 16o 533 26 48 37 7* 4o0 330.000 0.51b57 1. 928 .04-.OC5 2o 577 17 4o6 1 2Clo5 6 167 700 26. 91 30 , 46/

3*0 . 00 0.5U23- 1.991 0. 0*3135 27 489 17'61 7 205*8, 6 163 8*2 29. 3o 38 48 *7*

350. 000 G. 48715 2. oi3 0.041764 2o .395 18061 6 20935 5 16 J 96 4 29 83 3 8 6 ) 480 3o0 . 00 0.*72b9 2.114 . 040483 29 29o 1 6 366, 1 2132b 6 171 G5 5 30, 33 59 5 5 -3/ 370.000 C. 45944 2. 17o 0. 039261 30 192 18675 3 21722 2 17? 149 3C. 34 59 7 i *4 j 380.000 . 4*b85 2.233 0.038153 31 8* 16989 * 22122 5 173 217 31 36 *0 27 49 4 330.000 0.43492 2.293 0.037090 31 .971 19308 7 ZZ5Z7 7 17* 26 9 31 90 * 7 7 = 03 400.003 0.42 363 2. 3^1 0. O36068 32 855 19633 2 22337 9 17 = 308 32 45 *1 28 5 1 J 42 J.000 0. 40278 2.483 0.03*243 34 ol3 2G298 3 23774 1 177 348 33, 57 -.2 o* 522 4*0.000 0.38395 2. 60 = 0. 0325e5 36 359 20985 5 2*o3 1 6 17 4 342 34. 71 *3 4 5 532 40O.OOO 0.36o85 2.726 0. 031064 3d 096 21695 1 25511 * 181 297 35 87 -.4 5* 5*3

*8J .000 0.35124 2.8*7 0.029720 39 ,823 22427 5 26413 3 163 216 37 02 *5 L = 5 53 500.000 C.33o94 2.968 0.026*74 41 ,54* 23182 4 27337 5 185 102 38. 17 -6, 76 5o3

152
ME THANE ISO 3AR AT P = 16.0 BAR

T OEN VOL DP/OT DP/DO E H S CV C? W OEG K MOL/L l/MOL BAR/K BAR-l/MOl J/rlOL J/MOL J/-IOL/K J/MOL/K J/MOL./< M/SEC

91,,087 28.179 0. 3 549 20.6728 252,,265 3476,,7 3533,,5 67.,945 33.,21 52,, 6 3 1579

95,,000 27.85* 0.03590 19.6776 237., 480 3673. 8 3731.,2 70, 171 33. 09 53, 03 1541

Ida,.000 27.436 0.03645 16.4651 218.,946 3932,,2 3990,,5 72,,912 33,,18 i3,, 8? 1*39

10p,,000 27.010 0.03702 17.3127 200,,852 4197,,6 4257 , ,0 75,,56 2 3Z,,26 54,,73 1433

110,,000 26.574 0. 03763 16.2152 183,,336 *469,,4 4529,.6 73,,127 33.,19 55,,53 1383

115,.000 26. 125 0. 03828 15. 1671 16b.,487 4746,, 4807.,3 80.,611 32. 96 56,, 24 1331

120,.000 25.o62 0.03897 14.1629 150,,353 5026,,7 5089,,1 63,,019 32.,60 56,,91 1279

125,,000 25.182 0.03971 13.1972 134,,949 5311,,3 5374,,9 85,,357 32,,21 5 7 , , b5 1227

130,,000 24.683 0.04 051 12.2649 120,,265 5600,,2 5665

,

.0 87,,635 31,,66 53,,55 117*

135.,000 2h. 161 0. 0+139 11. 3610 10o.,264 6694. 2 5960.,4 Hi. 865 31,,61 59,,70 1113

140,.000 23.ol2 0. 04235 10.4805 92,.896 6194.,6 62=>2,.4 92., 061 31,,46 51,, 15 lOol

1*5,,000 23.031 0.0*342 9.0179 80,,091 6503,,0 6572,,5 9-.,,238 31,,39 62. 9c 10 01 150,,000 22.408 . 0*4b3 6. 7ot6 67,,77o 6621,,3 t392,,7 9s.,-.08 31,,30 o5,,13 93 J 155,.000 21.732 0. 0*601 7. 9180 55,,867 7151.,6 7225,.3 93,,639 31,,12 o7,,95 872

160,,000 20.982 0. G47oo 7. 0595 44,.267 7497,,6 7573,,9 10 J,,802 30,,78 71,, 7 J 302

lod,,0 95 2 0.96 7 0. 0*7b^ 7. 0431 4+,,060 7504,,3 7580,,6 100,,644 3C,,77 ,'1,,73 80

160.,0 95 1.59544 0.627 0.165104 ,887 12620.<5 13523., 4 137. 96* 26. o2 53. 52 233

lo5,,000 1.49066 0.671 0.150025 7,,87o 12700.,9 13774,,1 139,,507 27,,88 *9,, 09 294

170,,000 1.40433 a. 712 0. 138365 8,,770 12672,, 5 1*01 1,,9 14J , ,92 7 27,,37 -.6, 20 30 4 175,,000 1.33152 0.751 0. 129084 9,,563 13G35,,9 14237,.5 142,,236 27,,02 -»*,, 17 313

180..000 1.26874 0. 788 0.121381 10.,351 13193. 4 1445*,,5 143. 458 26. 76 42. 63 321

185,.000 1.21363 0.824 0.114637 11,.072 13346,,5 14oo4 ,9 14*.,oll 26,.57 *1,,53 323

190.,000 1. lo456 0. 859 0.109172 1 1,,758 13496.,3 1*870,,2 I43,,706 26,,42 40.,62 iii

195,,000 1. 12U46 0. 892 0.104195 12,.417 13643,,4 15071,,* 14o,,7^1 26,,31 39,,89 3,3 200.,000 1. 08u42 0. 926 0. 099771 13., 054 13786.,4 152o9,,3 147., 754 26,,23 39,,29 34 i 205,,000 1.04384 0.958 0.096799 1 3,,671 13931,,7 154o4,,5 14o,,718 26,,17 33,,80 355

210,,000 1.01020 0. 990 0.092205 1*.,271 14073,,6 15657,,5 144,,648 26,,14 38,,43 3ol 215,,000 0.97911 1. 021 0.086930 1-.,,357 1421*,, 4 158*8,.6 150,, 5*7 2t.,12 36,, 15 3c"

220. 000 0.95G25 1. 052 0. 085926 15, 431 14354.,4 16038,.1 151,,419 26,,12 37 .73 373

225,,000 0.92335 1. 063 0. 083161 15,,993 14493,,6 16226,i 4 152,,2o5 26,, 14 37., 5 5 373

23J,,000 0. 69818 1. 113 0.080.60.0 lo,, 546 14632 , ,3 16*13 ,7 153,, 08 8 26,,17 37,,36 334

235,,000 0.87*56 1.1*3 0.07o220 17,,069 14770,, 6 lcbO 0,.1 153,,890 26. 21 37,, 21 339

2*0. 000 0.85236 1. 173 0. u76G00 17,.025 14903,,7 16785,.8 154,,672 26,,26 S7,,C 3 394

245,, 000 0.83141 1. 2J3 0. 073923 18,,153 15046,,6 16971,.0 15 j,,436 26,, 33 37,,00 3* 3 250.,000 0.81161 1. 232 .071973 16,,o75 15164,, 5 17155,.9 15b,, 163 26,,*1 3b, 94 *0*

255.,000 0.79284 1.261 0.070138 19,,191 15322,,4 173*0,,4 15o..914 26. 50 36,,93 4u3

2o0.,000 0. 77503 1.290 0. 066407 19,.702 16460,,4 17524,.9 157,,630 26,,o0 36,,83 41 3 2b5,,000 0.75810 1. 319 0.066771 20,,2C7 15593,, 7 177J9,,3 153,,33 2 2fc,,71 36,,63 4 1/ 270,,000 0.74197 1. 3 + d 0.065220 20,, 708 15737,,3 17693,,7 159,, 022 26,,33 3b,,90 *21

275,,000 0.72658 1. 3,7 o 0.063749 21,,2C5 15676. 2 18o7e,,3 153.,699 26,,96 3b.,94 42j

260,,000 0.71189 1.405 0.062350 21,,697 16013,,6 13263,.1 16J , ,365 27,,10 (7,, 30 430

285,,000 0.69783 1.433 0. 061018 22,,16o lol55,, 5 18**8,,3 161,,021 27,,24 37., 07 434

290,,00 0.68437 1.461 0. 059748 22,,672 lb295,,9 lo63 3

,

.6 161,, bob 27,,*0 37,, 15 *33

295.,000 0. 6714b 1.489 0. 058534 23.154 16436,,9 18619,,8 162,. 302 27. 57 37. 2 j 442

300,,000 0.659U8 1.517 0.057374 23,,634 16576,,7 19036,.3 lo2,,929 27,,74 37,, 36 4*p

310,,000 0.63573 1.57 3 0.055198 2*.,56* lb66*., 4 19381,,1 16*.,15 8 28,,11 37.,62 *53

320,,000 0.61410 1.626 0.053194 25,,525 17153,,3 19758,.8 Ic5.,357 28,,51 37,,92 *6

330. 000 0.59399 1.684 0. 051342 2b.,*57 174*5. 9 20139,,6 166,,529 26,,94 56,,25 4o7

34a,,000 0.57524 1.738 0. 049623 27,,381 17742,,5 20523,,9 167,,676 29,,39 36,,63 474

350,,000 0.55770 1.793 0.048023 28,,299 16043,,3 20912,,2 163,,80 2 29,,36 39,, 3 40 j 3o0.,000 0.54126 1. 646 0.046529 29,.210 183*8,. 5 2130*,.6 169,,907 30,,35 39,, *b 4 87 370. 000 0.52581 1-9J2 0. 045131 30. 116 16658,, 5 217.11,,4 17 0,,994 30,,36 39,,91 49 3 380,,000 0.51126 1.956 0. 043818 31,,ul5 18973,,4 22102,,9 172, 065 31,.38 + 0,, 33 499

390,,000 0.49753 2.010 0.042564 31,,911 19293,,3 225J9,,2 173,,120 31.,92 40,, 33 50 3

if 00,,000 0.48455 2. 064 .041421 32,,802 19618,, 4 22920,,5 17*.,161 32. *7 4l. 33 313

420,.0 00 0. 46060 2. 171 U. 039263 3*.,573 20264,,7 23758,,5 176,,205 33,,59 *2 . ,43 522

440.,000 0.43898 2.27 8 Q.0373b4 3c,,332 20972,,9 24617,,8 173,,204 34,,73 + 3. 51 533

460,,000 0.41936 2. 385 0.035O30 33,,079 21683,,5 25496,,9 18J., lb2 36,,89 4 4 , ,61 543

460,,000 0.401*7 2.*91 0.03*055 39,,816 22416,,7 26402,,1 182. 084 37. 04 45

.

71 553

500, 000 0. 36506 2.597 0.032618 41,.545 23172,,4 27327,.4 183,,97 3 38.,18 *6.,82 5b3

153
ME THANE IS03AF{ AT P = 18.0 BAR

T DEN VOL DP/OT OP/OD E H S CV CP A D£ G K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL /K J/MOL/< 1/S£C

91. 138 28.182 035*8 20.6o63 252. 528 3W77. 3 35*1. 2 C 7 a 953 33. 23 52. e + 1579

95. 000 27. 8d3 U3539 19.6857 237. 957 3671. 8 373b. * 70. 15 33. 11 53. 0* 15*1

100. 000 27. **6 036** 18.*750 219. *61 3929. 9 3935. 5 72. 890 33. 19 j3 6-. 1*90

105. 000 27.020 03701 17.32*5 201. *01 *195. 3 *261. 9 75. 53 8 33. 27 5*. 71 1*37

110 000 26. 565 03762 16.2286 183, 91* **66. 7 *53*. * 73. 102 33. 21 55, 60 138-+ lis. 000 2b. 137 03626 15. 1826 167. 091 *7*3. *811. 9 8 J. 585 32. 98 56, 20 1332 WO 000 25.075 .03895 1*.1803 150, 982 5023, 3 5093. * 62. 99 32. 62 56 8b 1281 125 000 25.197 .03969 13.2166 135, 603 5307. 5 6 379. 85. 326 3?. 23 57, 55 1229

130 000 2*. /GO . + 0*9 12.2866 120 9** 5595. 9 56o 8 8 87, £01 31. 86 58 *7 117c

135. 000 2*. 16C + 13o 11. 3852 106. 971 5689. 3 5963. 7 89. 828 31. 62 59, 63 1121

1*0 000 23.63* . 0*231 10.5076 93 633 6189 6265 2 92. 021 31. *8 j1 03 106*

1*5 000 23.056 .0-+337 9.6*83 80 Bfc5 6*96. 6 657*. 6 9*. 193 31. *0 62. 60 1 Q J-+ 150, 000 22.*38 .0**57 8.6011 68 59s 6813 7 6893. 9 9o. 357 31. 32 o* 96 9*2

155. 000 21. 7b6 0*59* 7.9580 5o 7*0 71*2. 6 7225. 2 96. 529 31. 13 o7. 65 877

loj. 000 21.027 . U*756 7. 1071 *5. 213 7*86. 3 7571 9 100, 730 30. 79 71. 2? 807 103 08* 20.521 . 0-+873 6.57C3 38 220 7708 3 7796 1G2. 117 30 *9 7h 2* "02

lo3. 8 + 1. 8150s 0. 531 0. 191786 6. + 79 12517. 3 13509. 137. 1*9 29. 03 57. 13 232 165 000 1. 76139 0.568 0.18358* o 917 1269* 13ol6 J 137 601 26 6* 5* 55 237 170 000 1.6*372 0.608 0.16c627 7 9** 12781, 1 13376 2 139. 35* 27. 91 -.9 90 293 175 OoO 1. 5*0** 0. 6*6 0. 15376C .856 12955 3 1 + 117 ,7 1*:. 755 27 ,3 tt 91 307

160. 000 l.*6836 0.661 0.1*3*55 9 691 13120 9 1*3 + 6 7 1*2. 0*6 27. 06 + >+ 61 31? 165 000 1.39935 0. 715 0.13*909 lu *69 13280 * l*5ob 7 1*3 251 26 83 *3 25 32 + 190 000 1. 3306G 0.7*7 0.127c'-* 11, 20* 13*35 * 1*779, 9 l*t. 338 26. 6* -.2 05 3 32 195 J00 1. 28*93 0. 778 0. 121353 11 905 1356o 9 1*987 .7 1*5 *o8 26 50 *1 11 33 9 200. 000 1.23650 0. 809 0.116625 12 577 13735 6 15191 3 1*6 *99 26 39 *0 3 + 3*o 205 000 1. 19257 0. 839 0.110910 13 225 13882 1 15 391 * 1*7 *67 26 32 39 72 353 210 000 1.152*3 0. 666 0.10o*99 13 .85* 1*026 .8 15588 ,7 1*8. *38 26 26 39 21 35 9 215 .000 1. 11553 0. 89o 0. 102507 1* *65 1*170 1 1576 3 7 1*9 35 5 26 23 id 73 3c> 220 000 1. 081** 0.92 5 0.098870 15 061 1*312 2 1597b 7 15J 2*3 26 22 38 *3 371

<:25 .000 1.0*976 0.953 0.095537 15 .6*5 1**53 ,5 16166 .1 151 10 3 26 23 38 1* 377 23i JOQ 1. 02026 0.980 0.092*65 16 216 1*59* 15358 ,2 151 939 26 25 37 90 332 235 000 0.99269 1. 007 0. 089o22 16 778 1*733 9 165*7 2 152 752 26 29 37 ,7T 3U7 2*0 000 0.96680 1.03* 0. 086980 17 330 1*873 5 16735 3 153 6-+* 26 3* 37 5-+ 392 2tS .000 0.9*2** 1. 061 0.08*516 17 673 15012 7 16922 7 15* 316 26 *0 37 h 2 39 7 250 000 0.919*7 1. 068 0. U82211 Id *10 15161 9 171J9 5 155 072 2 6 *7 37 33 -.02 255 .000 0.89775 1. 11* 0. 0800^7 18 939 15291 1729 c 155 810 2 6 56 37 26 *d7 2ou .000 0.87717 1. 1*0 0.076011 19 .*62 15*30 1 17*62 .2 15a 533 26 o5 S7 22 *12 2o5 J JO 0. 85763 1. 166 0.076091 19 979 l35b9 * 17668 2 157 2-+2 2c 76 3

7 2 nlo

270 .000 G. 83906 1. 192 0. 07*276 20 *91 15708 9 1785* .2 157 937 26 ,06 37 ,20 *20

27 j 000 C. 82136 1. 217 0.072?5b 20 999 158*8 6 180*0 2 156 b2 27 00 37 22 *2j 260 .000 0.60**6 1.2*3 0.07092* 21 .501 15 989 .0 18226 ,* 159 291 27 1* 37 26 -.29 235 000 0. 78a3b 1.258 0.069373 22 ,00u 16129 .6 18-.12 .9 159 95 1 27 29 37 32 * 3 3 290 000 0.77293 1. 29* 0.067695 22 ,*9* lb270 .8 16599 .6 16J oJO 27 ** 37 33 ^37

2 95 000 0. 7561o 1. 319 0. 066*86 22 985 16*12 ,6 13766 ,8 161 2*0 27 on 37 *7 ^1

30u 000 0.7*399 1. 3** 0.0651*1 23 .*73 16555 lb97* * 161 671 27 76 37 67 **i

310 .000 0.71733 1. 39-. 0.062622 2* .*39 168*1 ,9 19351 3 163 107 28 1* 57 61 *3?

320 000 0. 692ob 1.*** 0.060308 25 .393 17132 .1 19730 .7 16* 311 28 5* 3 8 .09 *oJ SSi 000 C.6o976 l.*93 0.068173 26 .338 17*25 7 20113 3 165 *89 26 96 38 *2 *o,* 3-+0 .000 0. 6*8*3 1.5*2 0. 05ol95 27 27* 17723 2 20*99 2 166 0*1 29 *1 36 73 *73

35J . J00 0.62850 1.591 0. 05*356 28 .202 1802* .9 20666 .9 167 770 29 .69 39 17 + 0'J JoU .000 0.6096* 1.6*0 0.052o*3 29 .123 16331 21282 .6 166 879 30 38 39 59 *8o 370 .000 0.59231 1. 660 0.0510*1 3J .038 166*1 .6 21630 .7 16 9 ,970 30 ,66 +0 .C3 •+93 380 000 0.57582 1.737 0.0*9639 30 9*7 16957 3 22083 3 171 0** 31 ,*1 '+0 .53 4 33 390 .000 0.56027 1. 785 0.0*8126 31 .851 19277 .9 22*90 ,7 172 102 31 9* -.0 93 50; *00 .000 0.5*557 1.833 0.0*6799 32 ,750 19e03 ,7 22902 .9 173 1*6 32 *9 *1 *8 51

J

•28 000 0.516*6 1. 929 0.0**361 3* .53* 20271 .1 237*2 .8 175 ,19* 33 .01 *2 ,61 522

**3 .000 0.*9*05 2.02* 0.0*2175 3o • 3C5 20960 * 2*60 3 8 177 197 3* 75 + 3 53 53i

*60 .000 0.*7189 2.119 0. 0*0202 36 .062 21E71 .9 25*8o ,3 173 156 35 90 + * 68 5 + 3 *80 .000 0.*517C 2.21* 0.038*13 39 ,609 22*05 9 26390 8 181 083 37 06 -.5 76 55-+ 5u0 000 0.*3322 2.30o 0. 03b781 *1 .5*b 23162 .* 27317 .3 182 97* 38 20 *o 67 5o*

154
METHANE ISOBAR AT P = 20.0 BAR

T OEN VOL OP/OT OP/OO E H S CV CP W OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K -i/se; 91.189 28.186 .035*8 20.6598 252.791 3*78.0 35*8.9 67,.961 33,.2 + 52 .62 1579 95.000 27.871 .03588 19.6938 238. *33 3669.8 37+1.5 70 .129 33 .13 53 .02 15 + 2 1J0.0OO 27.*55 .036*2 18.*850 219.975 3SZ7.7 + 000. 6 72 .86 8 33 .21 53 . 82 1*91 105.000 27. 030 0.. 03700 17. 3362 201.9*8 +192.9 *266.9 75..515 33..29 5*..63 l + 3o 110.000 26.596 . O3760 16.2*2* 18*.*91 + + 6+. *539.2 73 .077 33,.23 5 5 ,+7 138 j 115.000 26.1*9 0., 0382* 15.1960 167.69* *7*0.0 *816.* 80..55 8 32 ,99 56., 16 13 3 + 120.000 25.089 0,.03893 1+.1976 161.610 6C20.0 5097.8 82..96 2 32..6* 56.. 82 1283 125.000 26.212 0.•0396b 13.2359 13o.256 5303.7 5333.1 85 .295 32,.25 57,,63 1231 130.000 2*. 71b 0.. 0*0*6 12.3061 121.621 6591.6 5672.5 67,.56 8 31..90 53 ,*0 1176 135.000 2*. 199 0..0+132 11. +092 107.675 588*.

5

5937.1 89,.792 31,,o + 59,.61 112 +

1 -.0.000 23.655 0..0+227 10.53** 9+.3C8 tl83.5 62o8.0 91.. 931 31 .50 60-.92 1067 1+5.000 23.060 0..0*333 9.676* 81.635 6*90.2 657b.

3

9*,.1*8 31 ,*2 o2 , b5 10U7 150.000 22. +67 0.. ++51 6.8353 69. +07 6606.2 6896.2 96,.306 31 . 33 6* .75 9 + -j 155.000 21.803 0..0+587 7.997* 57.606 7135.

6

7226.3 93,.+7 31,,15 67..35 861 160.000 21.071 0,. 0+7+6 7. 1637 +6. 1^9 7*75.2 7570.1 10 J..659 30 ,79 70 . 76 615 165.000 20.238 0,. 0*9*1 6.2861 3*. 935 7636.3 7936.7 102..909 30 , 30 75 .66 753 165.8*3 20. u6* 0.,0*979 o. 1353 33.058 7900.5 3000.1 10 3..298 30 ,21 77..C2 725 165.8+3 2.0*3 0,,+3936 0.220* 6.06 + 12506.7 13+85.5 136,,37* 29 . + 5 61 .27 230 170.000 1. 911 0..523*2 0.1399 7.055 12678.9 13725.8 137,.806 28 • ir 5*,.95 291 175.000 1.785 0.,5o035 0. 1818 6.066 12867.5 13936.2 133,, 327 27 ,9C 50 , 37 322 180.000 1.662 0,i 59**1 U. 1680 9.007 130*3.3 1+232.

1

1 + 0,, 702 27,,+* + 7,,33 311 185.000 1.596 ,62c*8 0. 1569 9.851 13210.5 1++63 .5 1*1,. S7 27 . 12 + 5,. 27 32 j 190.000 1.522 o..6570o 0.1*77 lO.o+O 13371.6 1*635.7 1*3,,15 5 26,,66 + 3,,69 32 a 195.000 l.*57 0.,636*8 0.1398 11.385 13526.0 1+901.0 1*+ , .273 26,,70 + 2.,*7 33o 200.000 1.399 0,,71*98 0. 1329 12.095 13680.9 15110.3 1*3,,336 26,,56 + 1,.50 3 + 3 205. 000 1.3*6 0..7*271 0. 1269 12.777 13830.9 1531b.

3

1*0,,351 26,,*7 *0,, 11 35u 210.000 1.299 0.,76981 0. 1216 13. +35 13978.7 15518.3 1*7,, 32* 26,, + + u ,09 557 215.000 1.256 0,,79636 0. llc.6 1+.072 1*12*.

6

15717.

+

1*3,,261 26,,35 39,, 65 3c 3 220.000 1.216 0,622+5 0.112* 1+.692 1*269.2 1591*. 1*9,,166 2t.,33 39.. 13 3o 3 225. uOO 1. 179 o. 8+613 C. 108* 15.297 1**12.5 161J8.7 150,, 0*1 26,,32 36,,7o 37 5 230 . Ml} 1.1*5 0,,873+5 0. 10*8 15.883 1*55*.

9

16301.3 15 J,,839 26.,3* 3 6,,*7 360 235.000 1.113 0., 698*6 0.101* 16. +67 1*696.

6

16*93.5 151.,71 + 26. 37 58, 22 33o 2*0.000 1.083 0,,92319 0. 0983 17.036 1+637.7 1663*.

1

152. 516 26. + 1 38., 02 391 2*5. JOO 1. 055 Oc,9*767 0.095+ 17.595 1*978.+ 16373.7 153,,299 26.,*6 37,,86 3 36 250.000 1.C29 0.,97192 0.0928 18.1*5 15118.9 170j2.7 15+,,0o2 26,,53 37,,73 + ul 255.000 1.00* 0,. ^9596 0. 0902 18.68b 15259.2 17251.

1

15*..808 26.,61 37,,65 + 0o 2o0.000 0.961 1.,01982 0. 0879 19.22+ 16399.5 17*39.

1

155..538 26. 71 37, 5 7 + 11 2o5.000 0.958 1,,0*35 0. 0866 19.753 15539.8 1762b.

8

15a,,253 26,,81 37 , 5 3 *15 270.000 0.937 1., 0670+ 0. 0835 20.276 15680.3 1781*.* 156,.955 26..92 37. 51 *2J 275.000 0.917 1,, 090*2 0. 0816 20.79+ 15821. 1 18001.9 157.,6*3 27.,05 37,,51 *2-, 280. JOO 0.898 1.,11368 0. 0797 21. 306 169b2.2 13139-5 153. 319 27. 18 37. 63 *25 285.000 0.860 1., 13681 0.0779 21.31* 16103.7 18377.3 15a.,96* 27,,33 57. 57 + 32 290.000 0.862 1.,15983 0. 0762 22.318 162+5 •

6

185o5.3 159. 633 27. *8 37. 63 + 5o 295.000 0.6*5 1., 1327* 0. 7 +6 22.817 16388.1 18753.6 160.,23 1 27,,5* 37,,7 + ••0 300. 000 0.82 9 1. 2J556 0. 0730 23.313 16531.2 189+2.3 16 0. 916 27. 81 37, 7 9 + + * 310.000 0.799 1.,25 92 0. 0702 2*. 29+ 16819.

+

19321.3 162. 156 26. 18 38, 01 + 5 2 320.000 0.772 1.,23597 0.0o75 25.2c3 17110.7 19732.7 163. 369 26. 57 33. 27 + 59 330.000 0.7*6 1.,3*073 0.0651 26.220 17*05.+ 20086.9 16 + .,55 1 26. 99 38..53 + 65 3*0.000 0.722 1. 33523 0. 0629 27.168 17703.9 20*7*.* 165. 708 29..* + 38,.9 3 + 73 350.000 0.700 1,,+2952 0. 0606 28.107 18006.5 20366.6 166. 8*2 29. 91 39. 31 *O0 3o0. JOO 0.679 1,,*7363 0. 0588 29.038 18313.5 21260.7 167. 955 3C. *0 39. 72 + 3 -j 370.000 0.659 1.,51750 0.0570 29.962 18625.0 216o0.0 169. 0-.9 3G. 91 + 0. 15 -S3 380.000 0.6*1 1. 5ol2* 0. 0553 30.879 189+1.3 22063.7 170. 126 31. *3 + 0. 61 *93 390.000 0.623 1. 6J*83 0. J537 31.791 19262.5 22*72.2 171. 187 31. 97 + 1. 3 505 hOO.000 0.607 1. 6+829 0. 0522 32.697 19688.9 22865.5 172. 233 32. 51 + 1. 5 3 511 420.000 0.57o 1.,73+8* 0.0*95 3+.+96 20257.5 23727.2 17 + . 286 33. 63 + 2. 60 5 22

<**0. 000 0.5*9 1. 82097 0.0*70 3b. 278 209+7.8 2*589.7 176. 29 3 3*. 77 *3. bo 5 35 *60.000 0.52* 1. 90676 0. 0**8 36.0*6 21660.3 25*73.3 178. 257 35. 92 + +. 7 + 6 + + *80. JOO 0.502 1. 9922* 0.0*28 39.802 22395.1 26 37 9.6 180. 135 37. 07 + 5. 6 + 55 + 500. JOO 0.*81 2.,077*6 0.0*10 +1.5*7 23152. * 273J7.3 182. 078 38. 22 + b. 93 5o +

155
ME THANE ISOOAR HT P = 22.0 BAR

T DEN VOL DP/CT OP/DO E H S CM CF H OES K MOL/L L/MOL bAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL /K J/10. /K i/st;

91 240 28.19G G36+ 7 20.6534 253 053 3478 6 3556.6 67 97 33 26 52 61 1580

95 000 27.679 0. 03537 19. 7018 236 908 3 667 3 37+6.7 7 j 107 33 14 53 00 15 + 3 10J J00 27. 4o4 0. 03o41 18.4949 220 .488 3925 5 4005.6 72 64 6 33 23 53 BJ 1492

135 ouo 27. 040 0. 03696 17.3+79 202 + 93 4190 t 4271.8 7z> 491 33 31 34 6 5 143 i 110 300 26.6C6 03756 16.2559 185 0b6 4461 .3 +5+-.G 73 052 33 25 55 43 1387

113. 000 26. 161 0. 03822 15.2133 168. 29o 4737 + 32 1.1 83 531 33 31 5b 12 1333

1211 000 26.702 0. 03831 14.2148 152 236 5016 6 5102.2 82 934 32 66 36 77 126 + 125 300 25.226 0. 0595 + 13.2651 13o 9C6 5300 5337.2 85 26 5 32 26 57 47 1233

130 000 24. 733 0. O + U + 3 12.3295 122 296 5667 4 567 6.3 87 536 31 91 58 33 1180

135. 000 24. 217 0. 0+129 11. +330 106 377 6679 7 597 0.5 89 75b 31 66 59 42 112d

1«iO 000 23.076 0. 04224 10.5oC9 95 099 6178 6270.9 91 9+1 31 51 oO 6 J 10o:>

1 + p 300 23. 105 + 328 9.7062 82 4C1 o463 9 6579.1 9 + 104 31 44 o2 50 1011

150 000 22. 495 0. + 445 6.0691 7u 215 6798 8 689o.6 96 ,256 31 35 6 4 56 9+9 155 300 21. 837 0. + 579 8. G363 58 + 66 7124 ,7 7225.5 93 412 31 16 37 03 865

160 000 21. 114 c G + 736 7.1995 47 076 746 + 3 75o6.5 100 59 3C 8G 70 3Z 913 lo5 OUO 2U.295 + 927 6. 3422 3 5 962 7822 8 7931.2 102 62 2 30 29 75 11 7+3

168. 411 19.b53 05083 5.73C7 26 455 6G83 6 8135.5 10 + 407 29 95 60 2

T o83

lo3 Ifll 2.2<J2 43822 0.2513 5 o4 2 12469 1 1 3433. 1 135 62 7 29 89 3D 07 27 3 170 000 2.216 4j141 U.24C4 c 7b 12fco2 1 353 3 . 1 13 230 29 + 3 o2 33 235

175 JOO 2.046 a 46695 0.2144 7 266 12770 6 llo+b.5 137 910 26 . + 7 5 4 92 293

180. 000 1. 91h 5225" 0. 1957 8 29 + 12959 6 1+109.3 13* + 00 27 66 5C 53 3G j 165 .000 1.806 55369 u. 1612 9 ,215 15136 ,3 14354. + 140 743 27 + 4 + 7 65 31C

19j 000 1.716 53303 0. lo94 1 0t4 1330 + 5 1+587.2 1+1 935 27 14 + 5 50 32 3 195 000 l.o3 7 6110 + 0.1596 10 .650 13466 6 1-610.9 1 + 3 ,1+7 2 6 91 + + 00 33 3 203 000 1.567 63799 0. 1512 11 609 13C24 1 15027.7 14 + 2+5 26 75 4 2 7i 340 zai 000 1. 6Uo 33411 J. 1439 12 326 13773 1 15239.1 143 289 26 o2 + 1 61 347 210 300 1.45 63953 G. 1375 13 .014 1 3929 2 15++0. 1 14o 287 26 53 + 1 G i 35 + 215 OGO 1.400 71436 0. 1317 13 o79 1 + 378 156+9. 1-7 2 + 5 26 4? -0 39 361 220 300 1.354 75869 0. 1266 14 323 14225 .1 16850.2 146 167 26 44 3 9 86 367 225 000 1.311 G 75259 0. 1219 1 + 94J 14370 7 1 -0 + 6 .+ 1+3 058 26 + 2 39 + 2 37 i 230 ouo 1.272 76611 0. 1176 15 .561 14515 1 162+4. 149 92 26 43 3 9 Cc 373

2 5? 000 1.236 80931 0.1137 16 158 1 + 658 ,£ 16+39.1 150 757 2c + 5 38 7o 38 + z*o. 000 1.202 c. 65221 0. 1161 lo 744 14601 4 loo32.3 151 570 26 48 36 51 39j 245 000 1.170 65485 0. 1067 17 318 14943 6 16324.3 152 362 26 53 38 31 395 250 000 1. 14C 0. 37725 0. 10 3o 17 883 15C85 z. 17015.4 153 134 26 60 38 15 40 J 255 300 1. 112 899+5 . 1 C 7 16 , + 39 15227 17206.8 153 889 26 o7 38 G2 403

2bu. 300 1. G85 c 921 + 5 0. 0960 lo 988 16363 c 17335.7 154 o26 26 76 37 93 41J 2o5 000 1. 060 9 + 327 0.0 9?

4

I3 = 29 16509 9 17535 .1 153 348 26 86 37 60 + 1- 270 300 1. G3b 9o49 + 0. 0930 20 063 16651 5 17774.3 15b 055 26 97 57 82 41 1 275 300 1.014 0. 936 + 0.09C8 2G 591 16793 2 17963. + 15b 749 27 09 37 6 J 423 260 .300 0.99 2 1 3J734 0. 0686 21 ,114 16935 ,2 13152.4 157 430 27 ii 37 81 42' 285 000 U.972 1, 02910 G

.

U6t6 21 o31 lo077 5 183+1.5 156 9 9 27 37 37 b3 + 32 290 000 0.952 1 05C24 G

.

G547 22 143 16220 2 1853U.3 153 758 27 52 3' 6d + 3o 293 000 0.93 3 1 0M28 G. 0828 22 b51 163b3 c 1872G.3 159 40 6 27 66 37 9 + 4+

J

300 .000 0.916 1 09222 0. ooll 23 156 16607 3 18910.2 16 04 4 27 65 38 ul + + 310 000 0. 862 1 13362 0. 0776 2 + 151 1679o 8 19291.2 lol 293 26 21 38 21 + 52 320 000 0.O51 1 17539 U. 0749 25 133 17089 3 19o7+.5 162 51G 28 oO 33 + o 45-3 330 . JOO 0. 822 1 21608 0. U721 2b 1C + 17385 1 2 j 06 G. 5 163 698 29 02 36. 7 5 + bo

3<t0 000 0.796 1 25632 0. 0696 27 063 17684 6 2 ++9.

6

16 + 859 29 + 7 59 L8 473

350 OGO 0.771 1 29733 O.Go73 26 013 17988 1 206+2.2 I63 997 29 94 3 9 43 + 3 J 360 .300 0.748 1, 5376 + 0.G6E1 28 953 16295 8 21236.7 167 114 30 43 59 65 48o 370 .QUO 0.72o 1 37777 0. J630 29 ,887 16608 1 21b39.2 168 212 3G 93 + 27 4^2

330 000 0.705 1 417 7 3 0. Ooll 3U 813 18925 2 220+4.2 lo ) 292 31. 45 + 0. 72 49 ) 390 .000 o.beb 1 45754 0. 0594 31 732 19247 ,1 22453.7 170 356 31 99 + 1 19 3 03

i*O0 .000 O.066 1 + 9722 0. 0577 32 646 19674 1 226o6. 171 4G4 32. 53 + 1. 63 511 420 .00 0.634 1 57621 0. 0646 34 458 20243 9 23711.6 173 462 33 65 + 2 6^ 522

4 + 3 300 0.604 1 65479 0. 0519 3o 252 2G935 2 2+575.8 173 472 34 79 + 3. 7 + 635 4o0 000 0.677 1 73301 0. 0+94 38 030 21648 7 254ol.3 177 44 35, 94 + +

.

81 5 + + 480 000 0.552 1 8109 + 0. J472 39 795 22364 3 263o6.4 179, 370 37 09 45 90 554

-.0 ouo 0.529 1. 36860 0.0452 41 549 23142 4 27297.3 181. 266 38. i3 + 6. 93 5o +

156
METHANE IS03AR AT P : = 2*.0 BAR

T OEN VOL OP/DT GP/DD c

H S CV CP A 0E& < MOL/L L/MOL 8AR/K 8AR-L/M0L J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SHC

91,.291 28.19* 0,.055*7 20.6*69 253.315 3*79,. 2 356* .3 67,.97 8 33.,27 j2-. 6] 1633

^5 . uUO 27.888 0,, 0358o 19.7098 239.381 3665 .8 3751 .8 70 .086 33,,16 52,.98 15 + + 10 .000 27.*73 0,, 036*0 18.50*7 221.000 3923,.3 + 010 .7 72,.82 3 33,,25 53,,77 1 + 93

105..000 27.050 0,.03697 17.3596 203.038 *188 , + 276 ,7 75,,*&8 33,.33 5*,,63 1**0

110,.000 26.617 0,, 03757 16.2693 185.639 **58., 6 *5*8 .3 73,. 027 33,, 26 55. + 3 1383

115 .000 26.173 0,.03821 15.2285 168.896 *73*,.0 *d25 .7 80 .505 33,,03 5 b , 08 133 7 120,, 000 25.715 0,,03889 1*. 2319 152.861 5013,.3 5106 .6 82 .905 32,,67 5 D . ,72 128 j 12 3,.000 25.2*1 0,,039o2 13.27*2 137.55* 5296,,2 5391 .3 85 .23* 32,,28 i7

,

,*1 125?

130,.000 2*. 7*9 0,.0*0*1 12.3507 122.969 5683,,2 6630 .1 67 .502 31. 93 53.,26 118 3 13s,.000 2*. 236 0,, 0*126 ll.*566 109.076 587*,,9 5973 .9 8 9,,720 31,,68 59. 33 1128

1*0,,000 23.D97 0,, 0+220 10. =673 95.826 6172,,6 6273 .8 91,,902 31,,53 60,,b9 1072

1*5 , ,000 23. 129 0,, 0*32* 9.7378 83.16* 6*77,,6 6581,.3 9+,. OoO 31,, + 5 o2,,35 101 + 150,.000 22-52* o,. 0***0 8.9025 71.018 b791,.5 b398,, U 96,.206 31,,36 6 *

,

,36 953

155,.000 21.871 0,, 0*572 8. J7*6 59.318 7116,,Q 7225 .7 93 .355 31,,17 5b,,79 89u

150,,000 21. 156 0,, 0+727 7. 2*** *7.991 7*53,,7 7557 .1 10 -J,,522 30,,31 o9,,91 82 + lo5,,000 20. 35U 0,,0+91* b.3969 36.95* 7609,,1 7 927,.1 102 .737 30,,29 ~? *

,

,*2 752

170.,000 19. 399 0., 05155 5. 50*1 26.095 8192,,9 6316,.6 105,,0o2 29,,31 32,,25 67J

170,,81* 19.22* 0,,05 20 2 5. 3508 2*. 330 8258,,0 8332,.9 103,,**9 3C,, 13 8*,,63 652

1/0,,81* 2. =32 0,,39*95 0.28*o 5.21* 12*6*.,7 13*12,.6 13*.. 897 3C. 35 71. 73 277

175.,000 2.338 0.,*2765 0.2630 6.362 12662,,0 13638,.* 13->,,+93 29,,17 61,,25 28 J 180,,000 2. loo 0.,*>163 J. 2272 7.5*3 12869,, 6 13976,,5 133,, lib 26, 3* 5*.,58 301

185,,000 2.031 0,, * 3 2 3 3 0.2082 8.557 13G56.,9 l*23o,»

5

139,,553 27,,60 pi).,51 311 100,,000 1.92 0,,52085 0.1932 9.*7* 13233. 7 1++33..7 l*d., 8ol 27. *2 + 7. 7 * 321

195,.000 1.825 0,,5+781 0. 1810 13.322 13*02,,* 1*717,.1 1 + 2,, 073 27,,15 *5 , , 72 329

2J0,,000 1. 7*3 0,,57 35 8 0.1708 11.118 13565,,2 1*9*1,,8 1*5 ,211 2b,,9* * + , , 2J 3 37 205,,000 i.o71 0. 598+1 0. lol9 11.372 13723., 5 15159,,7 1* + , , 237 26,,79 + 3,, 00 3 + v 210,.000 1.60o 0,,c22*7 O.lb+2 12.593 13878,,3 lp 372,,2 1*5,,311 26,,66 + 2 , 3 352

215,,000 1.5*8 0,,6*591 o . l*; * 13.28o 1*030,,3 15530..5 1 * o , .291 26,,60 + 1., 27 358

220,,000 l.*95 0,, oo830 0.1*1* 13.955 1*180,,1 15735,.2 1*7,,233 2c,, 5 5 + 0,, b + 3',-j 225. 000 1. **7 o.. 6912* 0. 1359 1*.60* 1*328..1 15987,.1 1*8,. 1*0 26,,52 *0,, 12 371 230,,000 l.*02 0,, 71328 0. 1309 15.235 1**7*.,6 1613d,, 5 1*3,, 017 26.,52 39.,63 37 r 235,,000 1.361 c,, 75*97 j,12fc* 15.851 1*620.,1 1633*,,0 1*9,,866 26,,53 39,,32 Hi

2*0,,000 1.322 0,, 7->t3o 0.1222 1& .*5* 1+76*., 6 16579,.8 150 , ,c91 2fc., 56 39. 2 3 89 2*5,.000 1. 286 o., 7 7 7*8 0.118* 17.0** 1*906 , ,* lb77*..3 151,, +9 3 26,,d0 58,,78 39 + 250,.000 1.253 0,, 73835 0. 11*8 17.b23 15051,, 5 169o7,,7 152,,27^ 2 6,,66 jS.,r 3 3* ) 2p5,,000 1.221 0., 81901 C. 1116 10.193 1519*., 5 1 716 , ,2 15 3., 037 26, 73 38. + 2 *J + 260,,000 1.191 0,,839*6 J. 106* 18.75* 15337,,2 17 351,.9 153.,781 2t. 82 3o. 29 *0 9 2o5., 000 1. 163 o. 8597* 0. 1065 19.307 15*79.,6 175*3,,2 15 + . ,510 26,,91 33,, 2 Hi j 27J,,000 1.137 0,,87985 0. 1028 19.852 15622,, u 1773*,,0 165,,223 27, 02 3 b . 1 + + 13 275.,0 00 1. Ill 0,, 8 3 982 0.1002 20.391 15765,, 1 1732*.,6 155,, 92 3 27, 1* 3 6, 1 3 + 22 233,,000 1.U87 0.,9196+ 0.0978 20.923 15908. 1811a.,1 15o. 609 27. 27 38. 09 *27

283., 000 1.065 0.,9393* 0. J955 21.*5U 16051,,1 163J5,,o 157,,26 3 27, *1 38, 13 + 31 290,, J 00 1. 0*3 0,,95892 0. 0933 21.971 1619*. 7 18*96.,1 157.,9*6 27. 5 6 58, 1 i *3j

295,,000 1. 022 c,,978*0 0. 0*12 22.*8o 16338,,7 18636.,9 158,, 596 27.,72 3 8.,17 + 3 i 300,,000 1.002 0., 93777 0.G893 22.999 16*83. 2 18877.,9 159. 2*0 27. 89 33. 2 + + * 5 310,,000 0.9bS 1,,0562* C. 0856 2*. 010 1677*., 1 19261,,1 160 . ,+9 7 26. 2 + 58. + 1 *51

320,, JOO 0.931 1. 07*37 0. 0823 25.0 0b 17067.,'a 196+6,,3 161,,72U 28. o* 58. 6 + *53

330,,000 0. 899 1., 11222 J. 0792 25.989 1736*. 7 2003*.,0 162.,913 29. 05 38, 92 *oo

3*0,,000 0. 87 1. 1 + 932 0. 076* 26.959 17665. 2 20*2 *

,

,7 16 + . 07 9 29. 50 39. 23 *7 5 350,, JOO 0.8*2 1.,13718 0.0738 27.920 17969,,6 20818,,8 155., 222 29. 96 3 9. 59 *3 j 3o0, JOO 0.817 1,,22*35 0. 071* 28.370 18278.,2 21216,, 6 166,,3*2 3U. *5 39. 93 *e j 370,, JOO 0.793 1,, 26133 0. 0691 29.813 16591.,3 21ol8,,5 lb7., *+3 3C, 96 + 0. 39 *92

380.,000 0.770 1. 2981* 0.0670 30- 7U7 18909. 1 2202*. 6 168. 526 31. *6 + . 8 3 *99

390..JOO 0.7*9 1., 55*81 0.0o51 31.675 19231,,7 22*35,,2 169.,593 32. Jl + 1. 3J 5 J 5 + J J,, JOO 0.729 1,,3713* 0. 0632 32.59b 19559. * 22850., 6 17U.,6*5 32. 56 + 1. 77 511 *20,,000 0. t>93 1,,***03 0.0598 3+.*21 2&230,,3 2 369 6,,0 172,,707 33, o7 + 2. 78 522

**J.,000 0.D59 1. 51651 0. 0568 36.226 20922. 7 2*5ol,,8 17 + . ,721 3h. 61 + 3 82 553

+60,,00J J.63u 1,,53823 0.05*1 38.015 21637.,0 25**6,,6 17c.,692 35. 96 + + . 83 5* + *80,,000 U.o02 1.,65986 0. 0516 39.789 22373. 6 2b357,,3 178,,b25 37. 11 + 5. 96 55 + 500,,000 0.578 1.,75122 0.0*9* *1.551 23132,,* 27287.,3 180.,52 3 38. 25 + 7. + 5o +

157
M£'rHANE ISO BAR AT P = 26. G BAR

T DEN VOL DP/DT DP/DO E H S CV CP A OZG k M0L7L L/MOL BAR/K 9AR-L/M0L J/MOL J/MOL J/MOL/K J/MOL/K J/10L/K M/SEC

91. 342 28.198 0. 03546 20.6*0* 253 576 3*79. 8 3572 1 67 986 33, 29 52 5 9 1580

95 000 27.896 0, 03585 19.7177 239 853 3663, 8 3757 73, 065 33 ie 52 97 15 + 5 103. 000 27.*82 0. 03639 18.51*5 221 510 3921, 1 *015 8 72 801 33. 26 JS 75 149 + 105. 000 27.060 03696 17.3712 203 581 4185 6 4281 7 75 *+ + 33 34 54 6 1 + 41 110. 000 26.628 03755 16.2827 166 211 4455. 9 4553 6 73. 002 33. 28 55 37 139J

115. 000 26.185 G3819 15.2*37 16 9 *9* *731 *830 3 80 47 9 33 05 56 + 13 39 120. 000 25.728 0. 036*7 14.2489 153 484 5009. 9 5111 82 877 32 69 56 67 1283

125 000 25.25o 0. 03960 13.2932 133 201 5292 5 5 39 5 5 85 20* 32 30 57 36 123-

130 000 24.765 + G33 12.3718 123 6*t 5579 563* 67 *69 31. 95 56 19 113j

135. 000 2*. 254 0. 0+123 11. *8C1 109 772 5 670. 2 5977 * 89. 685 31. 69 59 25 1131

1*0 000 23.716 0i»216 10.613* 9b 553 6167 2 6276 8 91 852 31 55 oO 53 1075 U5 . 000 23. 153 0, + 319 9.7o70 83 922 6*71. * 6533 7 9* 016 31. *7 o2 22 1017

150 000 22.552 G 0**34 8.9355 71 815 o784. 2 b699 p 9d 157 31. 38 64 17 95 7 155. 000 21.905 0. 0*565 0. 1123 60 16* 7lu7 * 7226 1 93 29 6 31 19 6b 52 69 + loj 000 21.197 0*718 7.2885 48 898 7**3 2 75o5 8 1G 455 30 82 59 51 829

lo5 000 20.*03 + 901 d.*5U2 37 9*2 7795 8 7923 3 102 655 3C 29 ?3 7o 759

170 000 19. *7* G 5 1 3 5 5.5727 27 2C2 617*. 7 8306 2 1C + 95 2 29 79 80 9o 679

173 077 18.792 0. 05321 *. 9912 20 o25 8*29 5 85o7 8 lOo *o3 3G 09 39 29 613

173 077 2.79b 0. 35772 0. o208 * 77? 12*33 5 1 3 ou 3 6 13 + 175 30 35 *8 55 275 175 000 2.678 37339 J. 30G6 5 398 1253d 1350b 9 13 + 99 9 30 11 7 95 2 62 180 000 2. *4o 0. + J877 0.2637 6 7** 127o7 8 13830 7 13d 82* 26 92 59 9 + 2<ij 185 000 2.27s * 59bl 0.2385 7 871 12971 4 1*11* * 138 379 28. 21 54 04 307 190 J00 2.136 43771 C. 219* 6 808 13153 6 1*37* 7 139 7o7 27 73 50 30 317 195 000 2.02* ".9395 0.20*3 9 776 13335 G l*ol9 3 1*1. 038 27. 39 + 7 7H 32o 200 000 1.927 51882 0. 1917 10 o21 13503 8 1*832 8 1*2 220 27 15 5 7 6 33 + 205 000 1.843 5*2j3 0. 1811 11 *15 13667 G 15077 3 1*3 332 26 96 + + 31 3 + 2 210, 000 1.766 53560 0. 1720 12 170 13625 9 15296 + 1* + 385 2 c 33 + 3 15 3* i 215 000 1.701 587*8 C. Io40 12 892 13981 3 155J9 3 1*5 390 26. 73 + 2 23 3 b j 22 U. 000 1.640 0. 6 959 0. 1569 13 587 1*13* 1 15719 l*o. 351 2t. 06 + 1 4' 3o3 225 00 1.585 63081 0. 1505 1* 259 1*28* 6 15 92* 7 1*7. 27c 2b o2 4 J 85 3o9 23J 000 1.535 65161 a. 1*1.8 1* 912 1*433 5 16127 7 1*3. lo8 26. ol + 33 375 235 J 00 1 . TOO 67205 0. 139b 15 5*6 1*560 9 16323 ,2 1*9 031 2c 61 39 91 331 2*0. 000 1. 445 o. 69216 0. 13*8 lb lfco 1*727 2 lo526. 8 1*9. 867 26. 53 39 55 367 245 ,000 1.404 71200 0. 1304 Id 772 1*872 6 1672 3 3 15 68 26 67 39 2t 39 2 250, 000 1.3o7 0. 73156 U. 12t3 17 36o 15C17, * 16919 5 151. *70 26 73 39 G2 393 255 000 1.332 0, 75G94 0.1226 17 950 15161 7 1711* ,1 152 2+1 2fc 79 38 83 + 03 2b0 000 1.299 77009 0. 1191 18 523 153G5 6 173Q7 9 152 993 26 87 56 o7 403

2o5 000 1.267 739J6 0.1158 19 088 15**9 * 17530 9 15 i 729 26. 97 36 55 *12

270 000 1.236 G 8J737 0. 1127 19 6** 15593 G 17b93 5 15* 449 2 7 07 58 *7 417 275 000 1.210 82652 0.1G98 20 193 1573o 7 17835 7 155. 15* 27 19 38 *1 422 280 000 1. 183 8 + 502 0. 1071 20 ,735 1568J .6 13077 , 6 15 5 8*6 27 31 36 33 42; 2a5 000 1.158 8o3*0 0.10*5 21 271 1602* 6 18 2o9 5 156. 52 5 27, •5 53 3' *3 J 290 JUG 1. 13* 83166 G .1021 21 8C1 16169 164ol 3 157 132 27 60 56 33 + 3? Z^o .000 1.111 8J982 0.0998 22 ,326 16 313 8 18653 3 157 8*9 27 7b 38 41 *39 30J 000 1. 089 ,9l73o 0.G976 22 3*6 16*59 1 16846 ,5 158 495 27, 92 3o 46 445 310 000 1. 049 95353 0. G936 23 872 16751 3 19230 8 159 75 8 26 28 38 61 451 320 JOO 1.011 93 91o 0. 0898 2* 681 170*6 2 19bl 6 160 937 28 o7 3o 62 453

330 000 . 97 o 1 02435 0.0865 25 87 o 173** 2 20007 5 162 166 29 06 39 09 4od

3*0 .000 0.94* 1 03929 0.0833 26 858 17f*5 7 20399 6 163 357 29 53 39 39 + 7 i 350 000 0. 9m 1 09399 G. 08G5 27 ,826 17951 .0 20795 ,* 16 + 50* 29 99 39 7 3 + 7 i 360 000 0. 88b 1 12650 0. 0776 28 789 18260 5 2119* 6 165 628 30 *6 40 11 43j

370 .000 0.660 1 lo281 0. 0753 29 7*0 1857* * 21597 7 16d 733 30 9 6 +

c > 452

380 JuO 0.835 1 19696 0. 0730 30 o83 18e92 9 22035 167 819 31 50 + 95 *99

390 000 0.612 1 .23097 0.0708 31 ,616 19216 .3 22*lo ,8 163 888 32 03 + 1 *? 5 03 too 000 0. 791 1 25483 0. u686 3? 5*6 195** ,6 22833 ,1 169 9*3 32 58 41 67 611 420 000 0.751 1 53220 0. 0650 3* 385 20216 7 23630 * 17 2 009 33 05 + 2 65 522

<<t0 ,000 0.715 1 3991* 0. Gol7 36 2C2 2L910 2 2*5+7 9 17* 027 34 33 + 3 89 533 *o0 .000 0.o82 1 , *557* 0.0588 38 0C1 21625 ,5 25*36 ,* 176 002 35. 96 + 4 93 5 + * i»80 000 0.653 1 53203 0.0561 39 ,78* 22362 9 263*6 1 177 937 37 12 46 03 55* 500 .000 0.626 1 596do 0. 5 3b 41 55* 23122 * 27277 * 17 9 838 38 26 + 7 10 5o5

158
ME1rHANE ISO BAR AT P = 28.0 8A R

T DEN VOL OP/DT DP/00 E H S CV CP W OcG K MOL/L L/MOL BAR/K BAR-L/MOl J/MOL J/MOL J/MOL/K J/MOL/K J/'10L/< M/SEC

91.393 28.202 0.,035*6 20. 63+0 253.837 3*80.,5 3579.8 67. 995 33. 30 52. 57 1581 95.000 27.905 0,,0358* 19.7256 2*0.32* 3661,,8 3762.2 70,, 0* + 33, 20 52. 93 15+3 100.000 27. +91 0,,03638 18.52+3 222.018 3919.,0 *020.8 72,,779 33, 28 53. 73 1*95 105.000 27.070 Oc, 0369* 17.3827 20*. 123 + 153,,2 *236.6 75.,+21 33.,36 i + . ,67 1+ + 3 110.000 26.o39 0, 0375* 16.2960 186.782 *+53., 3 *558.* 77. 978 33. 30 55.,3* 1391 115.000 26.196 0,,03817 15.2588 170.092 *728,,0 +8 3 +.9 80.,+53 33, 06 56. 13+J 120.000 25.7*1 0,, 03635 1*.2658 15*. 105 5006.,6 5115.* 82.,8*9 32, 71 56. 63 1290 125.000 25.270 0,,03957 13. 3121 136.8*6 5288,,8 5399.6 8p,,17* 32,,32 57,,3J 12 39 130.000 2*. 781 0. + 035 12. 3928 12*. 309 557*. 8 P637.8 87,,*3 7 31. 97 38.,12 1187 135.000 2*. 272 0.,0+120 11.503+ 110. +66 58b5,,5 593C.8 89,,6*9 31, 71 59,, lo 1133 140.000 23.739 0., + 213 10.639* 97.275 6161,,8 6279.8 91.,82 3 31, 56 oO.,*7 10 7 3 lt»5.000 23. 176 0,,0*315 9.7960 8*.67o d+65 , ,2 6536.0 93,,97 3 31.,*9 62,,08 1020 150.000 22.579 0.- 0**29 8.9682 72.608 6777,,1 690 1.1 96,,109 31.,39 3 3.,93 9oJ 155.000 21.93 6 0,, C + 558 6. 1+96 61.00* 7098,,9 7226.6 98,,2*3 31.,20 06, 23 893 loO.UOO 21.237 0.,0+709 7.3319 *9.7 96 7+32,,9 756+.

7

100.,349 30.,83 j9.. 13 33 + 165.000 20. +55 0., 0+889 6.5023 38.917 7782,,8 7919.7 102,,57* 30. 30 73. 1 + 765 170.000 19. 5*6 o., 05116 5.6369 28.287 8157,.1 8300.

+

10*.,8+6 29.,77 7 9.,79 637 175.000 18.+lu 0,,05*32 +.0926 17.750 8577,,3 3729.+ 107,,33 30,,13 9*. 13 5 83 175.216 18.353 0., 05**9 *.o+63 17.293 8 597,,2 87*9.6 107,, ++6 30,,15 35. 15 533 173.216 3.C75 0.,32520 0. 3603 *.332 12395. * 13305.9 133. +5 2 31. 38 3b. 92 273 160.000 2.763 0.,33187 0.3072 5.877 1265*.,3 13667.5 135,,+90 29,,6 + o7, + 9 233 165.000 2.6*1 0,,39352 0.2729 7.1*9 12878,,+ 13930.2 137,,20 + 28,,66 56,.53 302 190.000 2.372 Oc, *2160 0.2*8+ 3.2 + 1 13073,,5 1+259.0 133,,691 28.,08 53,,37 312 195.000 2.235 0.,++7*0 0. 2296 9.2ie 1326*.,1 1*516.9 1 + j,, 031 27. 06 + 9,,93 322 200. 000 2.120 Oc,*7161 0.21+3 11). 116 13+39,,9 1+760.

+

1 + 1,,26 + 27, 36 + 7.,56 331 205.000 2.022 Oc,-3*63 0.2016 10.95+ 13608,.6 1+993.5 1 + 2,,+15 27. 1 + + 5. 75 339 210. 000 1.935 Oc 51671 0.1908 11.7*5 13771,.8 15216.5 1 + 3,,500 26,,96 + + , , 36 3 + f 215. 000 1.869 0,,53805 0. 181* 12.*98 13931,, 15+37.5 1**,,530 26,,36 + 3,,25 35 + 220.000 1.790 c., >5876 0.1731 13.220 1+086,, 9 15651.5 1*5.,51 + 26..76 + 2. 35 3ol 225.000 1.727 0.,5'896 0.1658 13.916 1+2+0,,3 15 8ol.

3

l + o.,+5 7 26. 73 + 1,,62 363 230-000 1.670 0,,53871 0.1592 1*.590 1+391,,5 16067.9 1 + 7,, 365 26.,70 + 1,,02 37 + 235.000 1.616 0.,61808 U.1532 15. 2* + 1+5*1,,1 16271.7 1*6,,2 + 2 26,,70 + 0,,62 383 2*0.000 1.570 i,63712 0. 1*78 16.681 1*689,,3 16*73.3 1*9,, 091 26,,71 *C,,11 38j 2*5.000 1.52 5 0,,65586 0.1*28 lo. 503 1+836., 5 10O72.9 1 + 9. 91 + 26. 7 + 39. 7o 391 250.000 1.+8 3 0,,67*3* 0.1382 17.112 1+982,.8 16871.0 150,, 71 + 26,,79 39,,+3 39o 255.000 1.*** 0.,63260 C.13+0 17.709 16123.t c 17067.8 151,, <*9i* 26,,85 39,, 25 + 02 260.000 l.*07 0.,7106+ 0. 1300 18.295 15273,,7 172o3.5 152,,25"* 26,,93 39,,Uo + 07 265.000 1.373 0.,728*9 0. 1263 18.871 15+13,,7 17+58.+ 152,,99 7 27.,02 38. 91 + 12 270.000 1.3*0 0,,7+617 0.1229 19. +39 15 663,,+ 17052.7 153,,723 27,,12 33,, 8J + lo 275.000 1.309 0,,7a369 0.1197 19.998 15708,.2 173+6.5 15 + , ,*3* 27,,23 38,,72 + 21 260.000 1.260 0.,7.1108 0.1166 20.550 15853,.0 180+0.0 155., 131 27.,36 38, o7 + 25 265. 000 1.253 o., 79633 0.1138 21.096 15997,,9 18233.3 155,,815 27.,*9 38,,6 + + 3J 290.000 1.226 0..615+6 0. 1111 21.53* 161*3,,2 16+26.5 15o,,*87 27,,6 + 33,, D + ".3 + 293.000 1.201 Oc,8 3-2+7 0.1085 22.167 16283,,8 18619.7 157,, 1*8 27,,79 38.,06 + 38 300.000 1.177 0., 8+938 O.lOtl 22.695 16*3*., 8 18813.0 157.,798 27.,96 38,.69 + + 2 310.000 1.133 0,,36293 0. 1016 23.735 16728,,+ 19230.6 159,.069 28,,31 38,,82 + 53 320.000 1.092 0,,9161+ 0. 0975 2*. 758 1702+,,5 19539.7 160,,30* 28,,70 i9., 01 + 53 330.000 1 . u5* 0.,9+905 0. 0938 25.765 17323,,6 1993 1.0 161,,508 29,.11 39,,2o + 65 3*0.000 1.019 0,,93171 0. 09G3 26.758 17626.,2 20375.0 162. 68* 29. 55 39, 55 + 72 350.000 0.98 6 1.,01+13 0. 0872 27.739 17932,( 13 20772.0 163,,835 30,,02 39,,83 + 73 3oJ.OOO 0.956 1,, + 635 0. 08+2 28.709 162*2,,8 21172. 16*.,9o + 3C,,50 + 0,,2- + 35 370.000 0.927 1,,07838 0.0815 29.069 16557,,5 21577.0 16o.,072 31,,00 + 0,,6 + + 92 380.000 0.901 1., 11025 0. 0790 30.620 18876,,8 21985.5 167., 161 31. 52 + 1,,Oo + 93 390.000 0.876 1..1+197 0.0766 31.563 19200,,8 22398.3 163,,23 3 32,, 06 *1,,61 505 hOO.OOO 0.652 1,,17355 0. 07** 32.*98 19529,,8 22815.7 169,,290 32.,6 3 + 1,,57 511 +20.000 0.609 1,,23635 0. 0703 3*. 350 20203,.1 2366 + .

9

171,. 3ol 33,,71 + 2,.95 622 **0.000 0.770 1., 29872 0. 0667 36.178 20897,,6 2+53*. 173.,383 3*.,85 *3,,97 533 H60.000 0.736 1,, 35075 0.0635 37.987 21613,.9 25*23.9 175,, 361 35,,99 + 5,, 02 5 + + *80.000 0.7C3 1,,+22*7 0. 0605 39.779 22352,,1 2fc335.0 177,,29 9 37,,1* *6,,09 55p 500.000 0.67* 1,,*3392 0.0579 +1.557 23112,.5 272o7.5 179.,20 2 38,,28 *7,,lo 5o5

1 59
Mt rHANE ISOdAR AT P = 30.0 BAR

T DEN VOL DP/OT DP/DD E H S CV CP W DEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/10L/K •t/SEO 91 + ** 28.20b G35*5 20.6276 25*. 097 3*61 1 3537 .5 68 .003 33 31 52 66 1681

95 000 27.913 G 03583 19.7335 2*0.793 3659 8 3767 3 73 02 3 33 21 52 93 15+'

100. 000 27.500 03636 18.53*0 222.526 3916 8 4025 9 72 757 33 30 53 71 l*9o

105. JjO 27. u79 0. 03693 17.39*2 20*. 663 *1B0 8 4291 6 75 39 8 33 38 5* 55 144 + 110 000 26.o+9 0. 03752 16.3092 187.351 4450 6 *5o3 2 77 ,953 33 31 55 33 1392

115. 000 26.208 03816 15.2738 170.687 *725 ,1 *839 5 83 426 33 08 55 9o 13*2

123. 000 25. 75* U3833 1*.2B27 15*. 72* 5003 3 5119 .8 82 821 32 73 56 ,58 1291 125 000 25.28* 03955 13.3309 139. *89 5285 1 5*33 .8 85 1** 32 33 57 2 + 12 + 1 1 JO 000 2*. 797 0*G 33 12.*137 12*. 975 5570 7 5691 7 67 404 31 98 53 ,05 lld9 135 000 2*. 290 G 0*117 11.5265 111.158 5860 8 593* 3 89 61* 31 73 59 G6 HJj mo 000 23.759 + 239 10.6o51 97.99* 6156 .5 62d2 .8 91 78 5 31 58 S3 37 lOdl

1«*5 000 23.200 0*310 9.82*7 85.*27 6*59 1 6538 * 93 ,93 31 50 31 9 + 1023

150 000 22.o07 0**23 9. 00G5 73.396 6770 G o9J2 7 9q ,060 31 i*l o3 .81 9c + 155 000 21.970 0, 0*552 6. 186* 61.837 7090 6 7227 1 93 137 31 21 66 Gl 903 160 000 21.277 0*700 7.37*5 5G.o65 7*22 8 756 3 .8 10 J 325 30 8 + q8 76 83:1 165 JOG 2 0.50= 0*877 6.5532 39.880 7773 2 7916 5 102 495 3G 30 7? 55 772

170 000 19. 61o 05G98 5. 7028 29.351 31*0 .2 8293 .1 10 + . 7** 29 .76 73 .71 696

175. 000 18.519 05*00 *. 7819 13.982 8551 7 8713 7 107 178 30 07 91 .6 + 6jJ

177 .2*5 17.902 05686 *.3190 14.298 8762 8 8930 * 103 403 30 29 102 + 3 5 + 9

177 2*5 3.37* 296*1 0. *G39 3.878 123*9 5 1 3238 8 132 719 31 98 97 + 3 271 IdO 000 3.13* 319J* 0.3611 4.913 12521 ,9 13*79 .0 13 + 06* 3C 59 79 22 282 ld5 000 2.837 35250 0.3128 0.362 12775 .6 13833 1 136 036 29 2 + o4 , + 3 29o 190 000 2.625 3310 0.2O09 7.5e9 12992 5 1*135 5 137 619 28 + 7 57 1 + 30j 195 000 2.*59 0. * J66o 0.2573 8.6*5 13189 2 1**39 1 139 0*1 27 96 52 6 + 31) 200. 00 2.323 0. *30*3 0.2387 9.603 13373 1*66 * 3 1*0 333 27 oO + 9 53 323 205 000 2. zua *523* 0.2235 10.488 13 5*7 ,9 l*90o * 1*1 528 27 3* *7 35 337 210. 000 2.109 +7*21 J. 2107 11.317 13716 1 15138 8 1*2 6*8 27 1* + 5 b7 3 + + 215 000 2.021 + 9 + 76 0.1997 12.103 13fc79 * 15363 7 1*3 707 27 OC + + > 36 352

220, 000 1.9*3 G sl+o* 0. 19G1 12.85* 14G38 7 15532 6 1** 71* 26 90 + 3 29 35 9 225 000 1.873 53397 0. 1817 13.57* 1*195 15796 9 1*3 677 26 8* + 2 4 + 36o

2 30 000 1.O09 35233 0. 17*2 1*.270 1*3*8 8 lo037 3 1*0 60 2 26 8G -.1 7 + 372 235 000 1. 750 0. 57129 . 167* 1*.944 1*500 6 1621* 5 1*7 493 26 78 + 1 lo 37J

2*0. 000 1.&97 0. 539*0 0. 1612 15.598 1*650 9 16*19 1 1*3 35 + 26 79 + 3 68 38 + 2*5 000 1.6*7 60720 . 1556 1q. 237 1*799 8 15621 5 1 + 9 16 9 26 31 + 23 393 250. 000 1.6G1 0. 62*7* 0. 150* I0.86G 1*9*7 8 16822 1*9 999 26 86 39 93 39?

255. 000 1.558 0. 6*203 0.1*57 17.471 15G95 17021 .1 15 J 768 26 91 39 61 401

2oO. JOO 1.517 0. 63911 0. 1*13 18. 070 152*1. 6 17218 9 151 556 2b 99 39 + 6 *0o 2o5 000 l.*79 67630 0.1372 13.658 15387 7 17*15 7 152 306 27 37 39 26 *11

270 000 1. + + + 0. 69271 0. 1333 19.237 15533. 6 17611 8 153 039 27, 17 39 1 + 41 275 000 1. + 10 G. 7J92o 0.1297 19.807 15€79. * 17SJ7 2 153 756 27 26 39 0* + 20 230. 000 1.378 o. 72567 0. 126* 20. 368 15625 2 180J2 2 15 + 459 27 40 38 97 4 2'; 285. 000 1.3*8 0. 7*19* 0. 1232 20.923 15971 1 1819o 9 155 1*8 27 5* 3d 92 + 29 290 OGO 1.319 0. 75809 0. 12C2 21.*7u lbll7 2 18391 5 155 625 27 08 38 93 43 + 295 000 1.292 77*12 0. 117* 22.011 16263 6 13536 156 +9 27 83 33 93 + 33 300 000 1.266 7 9 5 0. 11*7 22.5*7 lo*10 * 18730 5 157 1** 27 99 3d 93 + + 2 310 000 1.217 0, 82163 0. 1098 23.601 16705 L 19170 2 153 +21 28. 36 39 U3 + 53 320 000 1. 173 0. 8523o 0.1053 2*. 637 17C02 6 195ol 3 159 663 28 73 39 20 + 53 330. 000 1. 131 . 3J330 0. 1012 25.656 17303 1995*. 4 16J. 873 29. 1* 39 + 3 + b-> 3*0 000 1.09* 91**3 0.097* 26.o61 17 606 6 20350 1 162 05 + 2°. 56 39 73 472

3ji, 000 1.058 0. 9**93 0. 09^0 27.652 17913. 9 207*8. 6 163. 209 30. 3* + 02 + 79 360. 000 1.025 97517 0.0908 28.631 18225 1 2115G, 6 16 +. 3*1 30. 53 + 3d + di 370 000 0.995 1 J3522 0. 0678 29.600 185*0 6 21556, 3 165 *5 3 31 33 + 7o + 92 330 000 0.966 1. 03511 0.0850 30.559 18860 6 219o5 9 16o. 5*5 31. 55 + 1 13 + 9 i 390, 000 0.93 9 1, Oa + 35 0.082* 31.509 19185 3 22379. 9 167. 621 32. 08 + 1 62 53 j hUO 000 0.91* 1 09**5 0. 0800 32.452 19515 22798 3 163, 680 32. 62 + 2 07 511 420 JOO 0.867 1, 15329 0. 0756 3*.31o 2G169. 5 236+9. 3 173. 756 33. 73 + 3. + ?22 *+0 00 0.82b 1 21170 0.G717 3o.l56 20885 1 2*520. 2 172 781 3*. 37 + +

.

05 53 + + oO. 000 0. 788 1. 2o97o 0. 0682 37.975 21602. 3 25*11. 5 17*. 762 3e. 01 + 5- 9 6 + + <tdO JliJ 0.753 1 32752 0.0o50 39.776 223*1 * 2 6 323. 9 176. 73* 37 16 + 6 15 555 500 JOO 0. 722 1. 33532 0.0622 41.561 23102, 5 27257. 6 178 609 36. 30 + 7. 21 56?

160
methane: isobar at p = 32.0 BAR

T DEN VOL DP/DT OP/OO E H S CV CP W DEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/.10L/K 1/SEC

91. 495 28.210 0. 03545 20.6211 254.357 3481.8 359 5.2 68,.011 33,,33 52,,55 1581 95.000 27.921 0.03582 19.7413 241.261 3657.9 3772.5 70,,002 33,,23 52,,91 154 7 100.000 27.509 0.03635 16.5437 223.032 3914.6 4031.0 72,.73 5 33,,31 53,,69 1497 105.000 27.089 0.03692 17.4056 205.202 4178.

4

429b.

5

75,,375 33.,40 54.,52 14 + 5 110. 000 26.66U 0.03751 16.3224 187.919 4448.0 45o8.0 77,,92 9 33,.33 35 ,27 1394 115.000 26.220 0.03814 15.2887 171.281 4722.

1

48+4.2 80,,40 33,,10 55,,93 13+3 120.000 25.767 0. 03881 14.2994 165.342 5000. 1 5124.3 82,,794 32,,74 56,.53 1293 129.000 25.299 0.03953 13.3495 140.130 5281.5 5408.0 65,, 114 32, 35 57,, 19 1243 130.000 24.813 0. 04030 12.4344 125.640 5566.6 5b 9 5.

5

87,,372 32,,00 57,,93 1191 135.000 24.308 0.04114 11.5495 111.847 5856.1 5987.8 8 9,,57 9 31,,75 58,,99 1138 140.000 23.779 0.0-f205 10.b906 98.710 6151.2 6235.8 91,,746 31,,o0 oO,.20 1083 145.000 23.223 0. 04306 9.8532 86.174 6453.

1

6590.9 93,.887 31,,52 61,,81 102o 150.000 22.634 0.04416 9.0325 74.180 6763.0 6904.4 95,,013 31,,43 63,,63 963 155. JOO 22.002 0. 0+545 8.2227 62.664 7062.3 7227.8 98,,133 31,,23 65,,77 9u7 160.000 21.316 0. 0+691 7.4lb4 51.567 7412.9 75o3.0 100,,261 30,,85 68,,41 8 + + 165.000 20.555 0. 0+855 6. b030 40.831 7757.

8

7913.4 102,,417 30,,30 72,,03 ?7i 170.000 19.683 0.05081 5. 7647 30.396 8123.8 323d. 4 10 + ,,644 29,,74 77.,72 70 + 175.000 18.621 0.05370 +.6663 20.175 6527.7 8699.5 107,,035 30,,02 69,,25 612 179.176 17.43 5 0. 05736 4.C00b 11.61+ 8927.7 9111.2 109,,36 30,,51 111,,7 + 51^ 179.176 3. b96 0.2705b 0.4523 3.415 12295.2 13161.0 131,,96 5 32,,65 111,,24 269 180.000 3.595 0.27818 0. 4332 3.790 12358. 13248.2 132,,45 32,,01 1U0,,93 273 165.000 3.172 0.3152+ 0.3b01 5.554 12659.9 13668.6 13 + ,> 756 29. 93 72,, 6 + 29u 190.000 2.901 0.3+47+ 0. 3176 6.906 12899.1 14002.3 136,,536 28,, 91 ol,,69 304 195.000 2.699 0. 37056 0.2678 8.055 13109.6 1+295.3 136,, 059 26,,28 9 5

,

, 81 31i 200,000 2.537 0. 39410 0.2651 9.079 13302.9 14564.0 139,, 419 27,,85 51 ,69 325 205.000 2. +03 0.+lo07 0.2+69 10.015 13 484,

8

l+81b.2 140.1 665 27. 54 + 9,, 1 + 33 + 210.000 2.289 0.43688 0.2318 10.887 13658.6 15056.6 141,,824 27..31 4 7 , 10 3+2 215. 000 2. 189 0.45679 0.2191 11.7U7 13626.3 152d8.0 142,,913 27,,15 + 5,,63 35 u 220.000 2.101 0.47597 0. 2060 12.487 13989.

4

15512.5 143,,94 5 27,,03 + 4,,30 357 225.000 2.022 C. 49457 0. 1983 13.233 14148.

8

15731.4 144.,929 26. 95 + 3,, 33 364 230.000 1.951 0.612do 0.1897 13.951 14305.3 15945.6 145,,872 26,,90 + 2,,49 371 235.000 1.88b 0.53033 0. 1620 14.645 14459.5 16156.6 146.,778 26,,87 41., 83 377 240.000 1. 82b 0.5476+ 0,1751 15.318 14611.9 1c3o4.3 147,,65 3 26,,87 + 1,,23 363 245.000 1.771 Q.534o3 U. 1666 15.973 14762.7 165o9.5 148,,49 9 26,,69 + 0.,82 33 3 250.000 1.720 0.5613-+ . 1630 16.612 14912.4 16772.6 14 9,,320 26,,92 + 0,,4 + 39 + 255,000 1.673 0.59780 Cl. 1577 17.236 15061.1 16974.0 15J,,117 26,,98 + 0,, 12 + 00 260.000 1.629 0.614J+ J. 1528 17.648 15209.1 17174.0 15 0,,894 27,,04 39,,67 40i 265.000 1.587 0.63008 0. 1462 18. +48 16356.5 17372.8 151,,651 27,,13 39,,66 410 270.000 1.548 O.b+595 0. 1440 19.038 15603.6 1757 0.6 152,, 39 1 27,,22 39,.49 415 275.000 1.511 0.66165 0. 1400 19.618 16650.5 177o7.8 153,, 114 27, 33 39.,36 + 2 J 280. 000 1.477 0.67720 0.1363 20.189 15797.3 17 9o4.3 153,,82 3 27,,45 39,,27 42 + 285.000 1. t44 0.6 J 26

2

0.1328 20.753 15544.1 16160.5 15 + ,,517 27,,58 39,,20 42^ 290.000 1.413 0.7J791 0. 1295 21.309 16091.1 18356.4 155., 198 27,,72 39,, 16 433 295.000 1.383 0.72 30 8 0.12o4 21.858 16238.

3

185?2.2 155. 86 3 27. 87 39. 15 + 37 300.000 1.355 0.73615 0. 1235 22.401 16385.8 18747.9 155.,526 28.,03 39,, 16 442 310. 000 1.302 0.7o801 0. 1181 23.470 lbfc82.3 19139.9 157.,611 28, 38 39.,2 + + 50 320.000 1.254 0.7 9752 0. 1132 24.519 16580.9 19533.0 159., 059 26. 7b 39. 3 3 45o 330.000 1.210 0.82673 0. 1067 2p.550 17282.4 19927.9 160,,27 4 29.,17 39,,60 + CP 340-000 1.169 0. 85568 0. 104b 2o.5b5 17587.0 20325.2 161.,46 29. bl 39,,65 472 350.000 1.131 0. 36439 0. 1008 27.566 17895.2 20725.3 162.,62 30,,07 + 0,,17 479 360.000 1.095 0.91290 0. 0974 28.555 18207.3 21126.6 163,,756 30,,55 + 0,,51 46o 370. JOO 1.062 0.9+122 0.0941 29.532 18523.6 21535.

5

16 + . 87 1 31. 05 + 0. 83 492 380.000 1.032 0.9o938 0.0911 30.500 18844.4 21946.4 165,,967 31,,57 41,,29 499 390.000 1.003 0. J9736 0. 0683 31.+57 19169.8 22361 .5 167,,045 32. 10 + 1. 72 5 -j 400.000 0.97s 1.02525 0.0857 32.407 19500.1 22780.9 163.,107 32. 64 + 2. 17 611 420.000 0.925 1. 08052 0.0810 34.284 20175.9 2 363 3.8 170.,187 33.,75 43..13 52J 440.000 0. 861 1.13556 0.0767 36.134 20872.5 24506.3 172.,217 34.,86 44, 13 53 + 460. 000 0.84 1. 19016 0.0729 37.963 21590.7 25399.2 174., 20 1 36,,03 45.. la 545 480.000 0.604 1.2+4+5 0.0695 39.773 22330.6 26312.9 17o. 145 37. 17 46. 21 555 500.000 0.770 1.29848 0.0665 41.566 23092.6 27247.7 178.,05 3 36.,31 47. 21 565

161
METHANE IS03flfi AT P = 34.0 BAR

T DEN VOL OP/OT OP/OO £ H S CV CP H OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/rtO,. /< "l/SEC 91. 546 28.214 0. 035*4 20.6147 254. bib 3482.4 3602.9 63.020 33.34 52. 5* 1581 95.000 27.929 0. 03510 19.7*91 241.728 3655.9 37/7.7 69.981 33.25 52. 90 15 + 8 100. 000 27.518 o. 03634 18.5533 223.537 3912.5 4036.0 72.713 33.33 53. 67 1496 105.000 27.u99 0. 03690 17.H170 205.740 4176.0 4301.5 75.352 33.41 54. 50 1440 110.000 26.671 0. 03749 16.3355 186.486 *445. 3 4572.8 77.504 33.35 55. 2* 1395 115.000 26.232 0. 03812 15.3036 171.874 *719.2 +848.8 83. 375 33.12 55. 89 1345

120. 000 25.780 0. 03879 14.3161 156.959 4996.8 5128.7 82.766 32. Z6 56. 49 1295 125.000 25.313 0. 03951 13.3681 1*0.769 5277.8 5*12.2 85.085 32.37 57. 13 1245 130.000 24.829 0. 04028 12.4550 126.302 5562.5 5639.4 8 7.34 32.02 37. 92 1193

135. 000 24.326 0. 0*111 11.5724 112.534 5851.5 5931.3 8^.544 31.76 58. 91 1141 140.000 23.000 0. 0*202 10.7160 99.423 6146.0 b288.9 91.708 31.62 oO. 16 108o

14>5. 000 23.246 0. 0*302 9. 8814 86.918 b447.1 6593.4 93.845 31.53 sli 63 1029 150.000 22.661 0*413 9. 0641 74.959 6756.1 6906.1 95.965 31. +4 o3. 46 9/1

155.000 22.034 0, 0*538 8.2585 63.48b 7074.2 7228.5 98.079 31.24 65. 5 + 911 loQ.000 21.355 0*683 7.4577 52.*41 7403.1 7562.3 100.198 30.86 68. 07 849 165.000 20.604 0. + 853 6. 6517 41.770 7745.6 7910./ 10 2.342 30.31 /I. 48 73* 1/0.000 19.748 05064 5. 8247 31.424 8108.0 8280.2 10*. 54

8

29.74 7b. 80 711 175. U00 13.718 0. 053*3 4. y46* 21.336 8504.8 3odb.5 10b. 900 29.97 37. 25 622 180.000 17.325 0. 05772 3.9353 11.315 8977.7 9174.0 109. 645 3C.53 112 61 5lo 181.019 16.945 0. 05901 3.O907 9.217 9093.5 9294.2 110.311 30.83 124. OU 481 181.019 4.048 0. 2 + 70 + 0.5068 2.943 12230.9 130/0.8 131.177 33. *3 129 8 + 2o,' 185.000 3.565 0. 28052 0.4182 4.644 12525.3 13479.1 133.410 30.32 35 bo 23, 190.000 3.206 o. 31187 0.3597 b.185 12796.6 13357.0 135.426 29.43 68 09 293 193.000 2.957 0. 33821 0.3217 7.444 13024.* 14174.3 137.075 28.64 59 t + 311 200.000 2.764 0. 3ol7* 0.2938 8.54* 13229. C 1445 8.9 136.516 26.12 5* 57 321 205.000 2.60 8 c, 38343 0.2721 9.536 13419.0 1*722.7 139.819 27.76 51 15 331 210.000 2.t76 43381 0.2543 10.452 13599.0 14972.0 141.021 27.49 48 od 34 j 215.000 2.363 42319 0.2395 11.310 13771.7 15210.5 142. 1*4 27.30 + 6 62 3*3 220.000 2.264 **179 0.2268 12.120 13938.8 15*40.9 143.203 27.16 + 5 37 35p

225.000 2.175 0, 45975 0.2157 12.893 14101.6 15664.8 14*. 209 27.06 + + 22 362 230. 000 2. 09b 47719 3.2060 13.634 14 261.1 15333. o 145.1/1 27.00 43 29 36)

235.000 2. 024 43417 0. 1973 1*.349 14417.8 16U98.0 1 + 0. 093 26.96 *2 53 3/o

240.000 1.958 51078 0. 1895 15.040 14572. 3 16309.0 140.582 26.95 *1 93 332 2*5.000 1.897 5270o 0. 182* 15.712 1-725.1 1651/. 1 147.8*0 26.96 *1 37 3oo 250.000 1.841 54304 3.1760 lo . 366 14876.5 16/22.9 143.6/1 26.99 40 94 393 255.000 1.790 35878 0. 1701 17.004 1502o.8 16926./ 149. */8 27.04 + 53 393 260 .000 1.741 57428 0. 164b 17.o29 1517b. 3 1/128.8 153.263 27.10 + ,23 *a* 265.000 1.69c 5 8 958 0.15 96 18.241 15325.0 17329.6 151. 028 27.18 + + 403 270.000 1.654 63 47 0.1549 18.841 154/3.3 1/529.3 151. ZZ5 27.27 39 85 + 1 + 275.000 l.ol4 bl965 0.1505 19.*32 15621.3 1//28.1 152.505 27.38 39 ,69 + 19 280.000 1.576 63445 0.1465 20.013 15769.2 1/926.3 153.219 27.49 39 5 7 424 285.000 1.541 64911 0. 1426 20.586 1591/. 18123.9 153.918 27.62 59 4>= + 23 290.000 1.507 3ii3o5 0.1390 21.151 16064.8 18321.2 15+. 605 27.76 39 43 433 295.000 1.475 ,67807 0.1356 21.708 16212.9 18518.3 155.2/8 27.91 39 40 437 300. 000 1. +4* b3238 0. 1324 22.259 16361.2 18/15.3 155.941 28.07 39 43 441 310.000 1.388 72071 0. 1265 23.342 16659.1 19109.5 157.233 28. *1 3 9 45 4+ 1 320.000 1.336 7*870 0. 1212 24.404 lb959.0 19504.6 153.468 28.79 39 53 457 330.000 1.288 ,77638 0.1163 25.*47 17261.6 1990 1.3 159.708 29.20 39 77 + 63 3*0. 000 1.244 83380 0.1119 26.472 1756/. 3 20330.3 160.899 29.64 40 ,02 k7Z 350.000 1.203 .83099 0. 1078 27.484 1/676.5 20731.9 162.063 30.10 + 31 47 i 360.000 1.166 ,85797 J. 1040 26.481 18189.5 21136.6 163.204 30.58 + C .6 + 40o 370.000 1.13C . 11476 0.1005 29.*67 18506.7 21514.9 16*. 322 31.08 *1 01 + 92 380.000 1.097 .91139 0.0973 30.442 18628.2 21926.9 165.421 31.59 41 Hi 499 390.000 1.066 .9378o 0. u943 31.407 1915*. 4 223*3.1 16o.502 32.12 *1 83 505 400.000 1.037 .96420 0.0915 32.364 19485.3 227o3. 6 16 7.5b

/

32. b6 *2 .27 511 420.000 0.98* 1 .01651 0. 0863 34.253 20162.2 23618.* 169.652 33. 77 + 3 21 523 440.000 0.936 1 .05839 0. 0818 36.114 20859.9 24432.5 1/1.685 34.90 + + 21 53 + toO. 000 0.893 1 . 1.1993 0.0777 37.953 21579.1 25336.8 173.672 36.05 *5 .23 545 480.000 0.854 1 .17116 0.0741 39.771 22319.9 26301.9 175.619 37.19 *6 .27 5«

500.000 0.816 1 . 22213 0. 07C8 41.572 23082.6 2/237.9 17/. 530 38.33 + 7 .33 5bb

162
ME THANE ISOBAR AT P == 36.0 BAR

T DEN VOL DP/DT OP/DO £ H S CV CP W DEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K "l/SEC 91.597 28.218 0,, 035** 20.6083 25*. 87* 3*83,,1 3610,• 6 68,,028 33.,36 52,,53 1582 95.000 2 7.93 6 0,.03579 19.7568 2+2.193 365*,.0 3782,.8 69,,96 33,,26 i>Z,. 88 15*9 100.000 27.527 0.i 03633 18. 5628 22+. 0*0 3910,.3 *0+l,.1 72,.691 33,,35 53,,65 1*99 105.000 27.109 0,,03689 17.*283 206.276 *173,,6 + 306,,* 75,.32 9 33,,*3 5*,,*7 1**7 110.000 26.681 0,,037*8 16.3*85 189.051 ***2,,7 *577,,6 77,,860 33.,37 55,,21 139o 115.000 26.2*3 0,,03811 15.316* 172. +65 + 716,.3 + 853,,5 60., 3+9 33,,13 55

,

85 13*5

120. 0U0 25.792 0,,03877 1*.3326 156.57* + 993,.6 5133,.1 82,,738 32,,78 56,,** 1296 125.000 25.327 0,,039*8 13.3665 1*1. *07 5 27*,,2 5+16,,* 85,,055 32,,39 57,, 08 12*6 130.000 2*. 6*5 0,,0+025 12.*755 126.963 5558,,* 57J3,,3 87,,308 32,,03 57,,65 1195

135. OOu 2*. 3** 0,,0+108 11.5950 113.218 58*7., 599*,,8 89..509 31, 78 58. 63 11*3 1*0.000 23.820 0.,0*198 10.7*11 100.13* 61*0,.8 6291 .9 91,,67 31,,63 30,,05 1089 1*5.0 00 23.269 0,, + 298 9.909* 87.658 6**1,,2 6595,.9 93,,803 31,,55 61,,55 1032 150.000 22.687 0,,0+*08 9. 095* 75.73* 67*9,,2 6937,.9 95.,918 31.,*6 63. 29 975 155.000 22.065 0., 0*532 8.2939 6*. 302 7066,,2 7229..3 96 ,026 31 ,25 65 ,31 915 160.000 21.393 0,, + 675 7.*963 53.307 7393,,5 75ol,,7 10 0,, 136 30,,87 q7,, 7 + 85 + 165.000 2Q.051 0,, 0*8*2 6.699* *2.699 7733,.8 7906,,1 102,,267 30,.31 70,,93 783 170.000 19. 810 0., 050*8 5.8830 32.*36 6092,.6 827*.,3 10*.,+5* 29,,73 75,,95 713 175.000 18.809 0,,05317 5.0228 22.*68 8*83,,1 8o7* ,5 106,,771 29,,93 95,,*9 632

160 .000 17.*91 0,,05717 +. 05** 12.673 89*0,, 1 91 + 5,.9 109,, *2 5 30,,37 106,,68 52 7 162.701 16. *2 3 Oc, 06089 3.3866 7.089 9262,.3 9+81,,5 111,.27 + 31,,28 1 + 0,,93 ..0 182.781 *.*38 o. 22532 0.5691 2.*65 1215+,,4 12965,.6 130,,339 3*,,35 156 , ,2* 26 + 185. 000 *. 051 0.,2*638 0. +9*6 3.609 12360,,3 132+9,,0 131,,881 32,,11 108,,55 27i 190.000 3.551 0,,29158 O.*051 5.*18 12681,,9 13695,,6 13*,,265 30,,05 76,,59 293 195.0 00 3.238 0,,30888 0.3597 6.810 12932,, 5 1*0++., 5 13b., 078 29, 0* 0*. 39 307 200.000 3.006 0.,3 326 3 0. 3253 7.995 13150,,9 143*8,,* 137,,617 28,,*1 57 ,73 319 205.000 2.823 0,,35*20 0.2992 9.050 13350,,* 1+625,,5 138,,986 27,,98 53,,*2 323 210.000 2.072 0,,37*27 0.2763 10.01* 13537,, * 1+89*.,7 1 + 0., 235 27,,68 50,,43 337 215.000 2.5*3 0,,39323 0. 2611 10.910 13715.,5 15131,,1 141, 395 27.,*5 + 8., 22 3 + 6 220.000 2.*31 0.,*113* 0.2*65 11.753 13887.,0 15367,,8 1*2,,*83 27,,29 + 6..53 35 3 225.000 2.332 0,,*2876 0.2339 12.553 1*053,, 5 15597,,0 1*3,,513 27,,17 + 5,,20 361 230.000 2.2** 0,,++563 0.2229 13.319 1*216.,0 15820,,2 1* + , , *9 5 27,,10 + 4 , ,11 363 235.000 2.16* 0. *6 20 2 0.2131 1*.05* 1*375,,* 16038,,6 1*5,, *3* 27.,05 + 3,,26 37 + 2*0.000 2.092 0.,*7801 0.20** 14.765 1*532,,3 16253,,1 1*6,,337 27, 03 + 2,,5 + 381 Z^5. 000 2.026 0,,*3366 0.1965 15.*53 1*687,, 1 I6+0*,,3 1*7,,20 8 27,,03 + 1,,95 38 7 250.000 1.965 0,,50901 0. 1693 16.123 1*8*0,, 3 16672,,7 1*8,,050 27,,06 + 1,, + 6 39? 255. 000 1.908 0..52*10 0. 1828 16.775 •

• 1*992. 2 16879. l*d,,867 27,,10 41,,05 39 3 260.000 1.855 0,,53895 0.1768 17.*12 151*3,,2 17083,, * 1*9,,661 27,,16 + 0,,71 + 03 265.000 1.806 0., J5359 0. 1712 18.036 15293,,3 17286,,2 150,,43* 27,,23 + 0.,*3 + Ji 270.000 1.760 0.,56805 O.I06I 16.6*8 16+*2,,8 17*87,,8 151,,187 27,,32 + 0.,21 41 + 275.000 1.717 0. 56233 0. 1613 19.2*9 15592,,0 17686,,* 151,,92 3 27.,*2 *0,,03 *13 260.000 1.677 Oc,536*7 0. 1568 19.8*0 157*0,,9 17838,,1 152,,6*3 27,,54 39,, 66 + 23 285.000 1.038 0<,610*6 0.1526 2U.*22 15889,,6 18087,,3 153,, 3+8 27,,66 39,,73 423 2^0.000 1.602 0.,62*32 u.1+87 20.995 16038,,* 18236,,0 15 + , ,039 27. 80 39. 7 *32

295. 000 1.567 0. 63807 0. 1*50 21.561 16167,,3 18*3*.,* 15*,,718 27,,95 39,,66 437 300. 000 1.53* 0.,65171 0. 1*15 22.119 16336,, 5 18662., 6 155.,38 + 28. 10 39. 6 + 4*1 310.000 l.*73 0,,67869 0. 1351 2 3.217 16635,,8 19079,,1 156,,69* 28, 45 39,,67 ** 3 320.000 1.418 0,,73 532 0.1293 2+.291 16937. 1 19*76. 2 157. 9+5 28. 82 39. 77 *57

330. 000 1.367 0,,73165 0.12*0 25.3*5 172*0.,9 1987*.,8 159.,171 29..23 39,,95 4o ? 3*0.000 1.320 0,,75771 0.1192 2d. 362 175*7,,6 20275.,* 160.,367 29,. 66 + . ,16 + 72 350.000 1.276 0,,7835+ 0.11*8 27.*03 17657.,8 20676.,5 161.,536 30.,12 + 0,,*o + 79 360. 000 1.236 0.,80916 0.1107 28.*10 18171,,7 2106*.,7 162,,fa80 30. 60 40., 76 48 3 370.000 1.19b 0.,83*59 0. 1070 29.*04 18*89.,7 21*9*.,2 163. 60 2 31. 10 + 1.. 13 492 380.000 1. 163 0.,85995 0. 1035 30.367 18812,,0 21907,,5 16 + . ,90* 31,,61 + 1,,52 49:) 390.000 1.130 0.,98*97 0.1003 31.359 19138. 8 2232*. 7 165. 98 8 32. 1* *1. 9 + 50 5 *00.000 1.099 0,,9099* 0.0972 32.322 19*70,, 5 227*6,,3 167,,055 32. 68 + 2, 37 511 *20.000 1.0*2 0.,95953 0. 0917 3*. 223 201*8, 6 23632. 9 169. 1+5 3 3. 79 + 3. 30 523 **0.000 0.991 1,, 00870 0. 0869 36.096 208*7,,* 2**78,,7 171., 181 3*.,92 + + . ,23 53 + *60.QO0 0.9*6 1., U5751 0.0825 37.9*3 21567. 5 2537*. 5 173. 172 36. 06 + 5.,30 5 + 5 480.000 0.90* 1,, 10602 0. 0766 39.770 22309.,2 2629 0,,8 175,, 122 37, 21 + 6. 3* 55o 500.000 0.866 1.,15*27 0.0751 *1.579 23072,,7 27228,,0 177,,035 38. 3* + 7. 36 56o

163
ME THANE ISO JAR AT P : 38.0 BAR

T OEN tfOL OP/DT DP/DO E H S CV CP M OEG K MOL/L L/MOL BAk/K BAR-L/MOl J/MOL J/MOL J/MOL/K J/MOL/K J/MO;./< -1/SlO 91 b48 28.222 035*3 20.6020 255.132 3*83 7 3518 .4 63 037 33 37 52 51 1562

95 000 27. 9*o 03578 19.76*5 2*2. b57 3652 373d 69 939 33 28 >2 65 1553

100 000 27.536 056 52 18.572* 22*. 5*2 3908 2 43 + 6 2 72 66 9 33 37 53 63 153 3 1J5 ,000 27.110 ,03b33 17. -,396 206.811 4171 3 *311 . * 75 306 33 45 54 + + 14*3 110 000 2b.o9 2 C 037*6 16.3615 189.615 444J 1 4582 ,4 77 85 6 33 38 55 13 1333

115 000 2b. 255 05609 15. 3331 173.05* *713 * 4638 1 80 32 3 3 3 15 55 61 13*3

183 000 25. 805 5 875 1*.3491 157.187 *993 3 5137 .6 82 711 32 dG 3D *3 1296

125 ,000 25. 3<tl 039*6 1 5.40*9 1*2.0*3 5273 6 6*20 6 85 326 32 *0 37 05 12*3 130 .000 24.861 , 0*022 12.4958 127.621 555* * 57J7 .3 87 277 32 35 57 7 9 1193

135 000 2*. 361 , 0*105 ll.bl76 113.900 58*2 * 5996 .* 89 47 5 31 80 3d 75 1145

i<»0 000 23. 340 ,0*135 10. 7o61 100.842 tl35 7 d295 .1 91 633 31 65 59 9o 1091

1*5 000 23. 292 0*293 9.9372 68.395 6*35 3 6596 >* 93 7o2 31 37 51 42 13 3 3 150 .000 22.713 0**33 9. 1264 76.50* b742 * 690 9 7 93 872 31 *7 Q i 1 5 97d

155 000 22.096 0*526 8. 32b9 65.112 7C58 2 7230 2 97 973 31 27 o5 09 91 9 160 ,000 21. ",3 ,0*666 7.5383 5*.16o 738* 75o 1 .3 100 37 5 30 68 •3 7 45 65 3 lo5 UUO 20.698 0*831 6.7*62 4 3.618 7722 1 7935 7 102 195 3C 32 70 53 793

170 000 19.871 05032 5.9397 33.*32 6C77 7 325 8 9 13* 36 3 29 72 73 15 72j

1/5 003 18.89b 05292 S. 0959 23.573 6*62 4 3bo3 5 106 6*7 29 90 3 3 .89 b*2 iaa 000 17.6*2 c , 05663 *.lo31 13.968 8905 9 9121 3 109 22 5 30 24 132 5*2

13+ 469 15.657 , 0s33o 3.0861 5.216 9*36 .6 967o .3 112 268 31 92 135 87 411

lo + •69 4. 860 • 20*93 3.0*17 1.965 12062 6 128+1 3 12 3 423 35 50 19b 23 2c2 lap J00 4.726 G ,21158 0.6102 2.3** 12132 7 12936 ,7 129 9*5 3L *5 lob .CI 265 190 000 3.952 25307 0. *o88 4.591 12650 2 13511 .9 133 017 30 d3 d9 07 233 195 .000 3.5*6 2-1198 0.4329 b.l*S 12832 * 13933 .9 135 05* 29 50 70 * + 302 200 000 3.266 3J621 0. 36C0 7.431 13C67 8 1*231 * 13o 713 26 73 ol 45 315 205 .000 3.051 u ,32731 0.3285 8.55* 13278 * 1*52* .1 138 159 28 23 3b 02 32> 210 000 2. 876 3*769 0. 3039 9.370 13*73 3 1*79* ,5 139. 46 2 27 37 52 37 335 215 J00 2.730 ,3o633 3.2839 10.507 13657 5 153 + 9 5 1*3 t62 27 61 -9 7 3 3**

220 000 2.o0 4 3:1*03 0.2672 11.38* 13833 8 15293 1 1*1. 782 27 + 3 *7 77 352 225 000 2. 49* *3G39 0. 2529 12.21* 1*00*. 2 15528 .0 1*2 838 27 29 46 2 4 35 J 230 2.39b 4173a 0. 2*C5 13.00* 1*170 15756 1*3 8*0 27 20 + 5 01 3bo

235. JCO 2.3u8 *3323 0.2295 13. 761 1*332 2 15978 5 1* + 79 8 27 14 + 4 2 37 5 2*3. 000 2.229 *869 0.2198 14.491 1*491 6 16196 ,6 1*5 71b 27 1 1 + 3 21 379

2*5. 000 2. 156 0. *j378 0.2110 13.197 1*6*3 6 lo41G 9 1*6 600 2? 11 + 2 65 303

250 J 00 2.090 *785o 0.2031 15.862 1*803 7 16b22 2 1*7 45 3 27 13 + 1 9-9 391 235 000 2. U28 43338 0.1958 16.6*8 14957 3 16d31 1*3 28 27 16 + 1 5 3 3if 260 000 1.971 53735 0.1892 17.199 15109, 8 17037 7 1*9 393 27 22 + 1 IS 4u 5 2o5 000 1. 918 521*0 0.1831 17.835 13261 3 172*2 ,6 1* i 86* 27 29 43 6 4 43 S 273 000 1.86b 53527 0.1773 18.*56 15412. 1 l?4+6 1 153. 62 5 27 37 + u 63 *1 5 275 000 1.822 5*896 0.1723 19.069 156b2 * 176 + 3 5 161 3b7 27 47 + .37 413

2dQ, 000 1.778 5o250 0.167* 19.673 16712. * 178+9 9 152 09 3 27 58 + 2 3 *25 285 000 1.736 57589 0. 1628 20.261 15862 2 16050 6 152. 33 3 27 71 + U 0/ 4 8 7 290 000 1.697 53916 u. 1685 20.8*3 lbOll 9 18250 7 15 5 *99 27 34 59 93 4 52

2 95 000 1.660 60230 0. 15*5 21.1*16 lblbl. 7 lb + 50 * 15*. 132 27 99 39 .92 *3„

300, 000 1.625 0, 61533 0. 1507 21.982 Ib311 7 186*9 9 15*. 833 28. 14 39 3d 4*1 310 000 1. 56u 6 + 110 0.1*38 23.09* 16612 5 190 + 8 7 155. 160 28 *8 39 8 3 -.* ) 320. 000 1.500 jd652 G. 1375 2*. 161 16915. 1 19**7 9 157. 42 6 28. 85 39 97 4P? 330 000 1.446 G 6916* 0. 1318 25.2*7 17220 1 198*6 3 153 66 29 26 + 12 + C.5 3*0, 000 1.39c 0. 716*8 0. 1266 2b. 29* 17527. 9 20250. 5 159. 861 25. o9 *G 3* *72

3a0 .000 1.349 7*110 0. 1219 27.32* 17839 2 l)655 2 161 03* 30 15 *3 63 *73 360 000 1.306 76550 0.1175 28.3*0 18153. 9 21062 7 162. 182 30. o3 a. 91 43a

370 000 1.26b 73971 0. 1135 29.3*3 16*72 7 21*73 ,6 163. 307 31. 12 *1 26 -.92 380 000 1.229 0, 8137o 0. 1098 3C.333 18795. 7 21838 16*. 413 31. b4 *1 6 4 439 39J 000 1. 19* 83766 0. 1063 31.313 19123. 3 2230o + 165. *99 32. 17 42 u * 335 400 000 1.161 851*1 0.1031 32.282 19*55 6 22729 16o. 5b9 32. 70 *2 47 511 42 0., 000 1.101 0, 93656 3.0972 3*. 19b 20135. 23587. 5 168. 66 3 33. 81 *3. 39 523 4+0 000 1. 0*7 93529 0.0920 3d. 376 2083* 8 2**6* 9 173 704 34. 94 44 3c 53* 463 000 0. 998 1, J3167 0. 067* 37.936 21555. 9 25362 2 172. 698 36. 36 + 5

.

3 7 5*3

*83 000 0. 95* 1. C*77* .a832 39.771 22298. 5 26279 9 17*. 651 37. 23 + 6. *0 5so

300 .000 0.91* 1 09356 3. 0795 41.587 23G62. 7 27218. 3 176. 566 38. 36 + 7 4* 566

164
ME THANE ISCIBA,UT P := 40.0 b;iR

T DEN VOL DP/DT DP/DD L H S CV CP W DEL, K MOL/L L/MOL BAR/K BAR-l/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K VSEC

91..699 28.226 .03543 20.5956 255.389 3484..4 3626 .1 68,,045 33,,39 52.,50 1582

^1

5

.000 27.954 . 03577 19.7721 243.119 3650,.1 3793..2 69..918 33,.30 52,.65 1551

100.. 000 27.545 0,. 03630 18. 5818 225.043 3906.. 1 4051,.3 72,.647 33,,38 53,,61 1501

105 .000 27.126 .03686 17.4508 207.345 4168 .9 431b..4 75,.283 33,,46 54,,42 145J

110 .000 26.702 .037+5 16.3744 190.177 + 437 ,5 + 537 .3 77.,832 33.. + 55..15 139'd 115.,000 2o.26b 0,. 03607 15.3+77 173.642 + 710,. 5 + 862..8 80,,297 33,,17 55,.78 13 + 9 120.. 000 25. 016 o,. 03873 14. 3655 157.798 4987 .1 5142 .1 82 .684 32,,81 56 . 36 130J

125..000 25.355 0..03944 13.4231 142. o77 5267..0 5424 .8 84 .996 32,,42 56,, 97 1250

130..000 24.876 0,. 0-+Q2Q 12.5160 128.278 5550.,4 5711.,2 37,,245 32,,07 57,,72 1200 135 .000 2*. 379 .0*102 11.6400 11+. 580 5837,.9 6032 .0 89,. +40 31,, 81 58,.67 1148

1 + J . . 000 23. 859 o,. 0+131 10.7908 101.547 6130,, 6 6298,.2 91,,595 31,,57 59,,67 10 94

1 + 5,, 000 23.315 0.. 04289 9.9647 89.126 6429,,5 6601 .0 93,,720 31,,58 61..30 1 C .3 S 150.,000 22. 739 0,, 04398 9.1571 7 7.271 6735,,7 6311,, b 95,,326 31,,49 62,,97 931

155,.000 22.127 0,.0+519 8. 3b35 65.917 7C50., 4 7231,.2 97,.92 1 31,.28 OH,. 87 923

160., 000 21.467 0,.0+656 7.5778 55.017 7374,,7 75;ol,.0 10 J,, 015 30,,89 67,, 13 863

165,,000 20. 743 0,,0+821 6.7922 44.527 7710,,7 79J 3,,6 102,, 123 30,, 3 2 70,, 5 301

170,,000 19.930 0,,05018 5.9949 34.415 8063,,2 »2o3,,9 10 + , ,274 29,.72 74,,41 7 Si 175,,000 18.97 9 0,, 05 2o9 5. loci 24.656 8442,,5 Sb53,,3 10b,,52 6 29, 87 32. 46 651

130,, JOO 17.779 0,, 05o25 4.2634 15.211 8874,,4 9039,.4 109,, 041 30,, 14 33,, Id 55o

185.,000 15.920 0,, 06231 3. 1361 5.815 9440 , ,1 963 1,,3 112,,281 31,,o7 155,,12 + 21 186,.089 15.225 0,, 0o568 2. 7348 3.586 9620,,6 93d 3 , , 5 113,,317 32,,34 2Jb,, + 3 '37?

186., 089 5.393 o,. 135 + 1 0. 7267 1.507 11950,,1 12631,.7 123,,411 37,,00 2o2,,45 2?i

190,,000 4.436 0,,2254+ 0. 5443 3.687 12393,,0 13294..7 131,,62 2 31,,86 1J9 ,+6 281

195,,000 3.891 0,, 25698 0.+527 6. + 55 12721,,7 137+9,,7 133,,967 30.,03 76.,43 233

2U J,,000 3.54 b 0,,23202 0. 3984 6.851 12 979,.0 1+107,.0 13 5,.797 29.,09 6 5

,

. 9 + 311

2ii5., 000 3.292 0,, 3J331 0. 3o03 8.050 13202,,7 14418..0 137,,333 26,,49 59,. Ul 322

210,,000 3. 090 0,, 323o0 0.3314 9.121 1340o,,6 14701.,2 138., 698 26,,07 54,,55 332

215,,000 2.92 4 0,,3+201 0.3U82 10.102 13597.,6 1+965.,7 13*..9+3 27..78 51,,42 3 + 1 220,,000 2.783 0,,35933 0.2890 11.015 13779,,2 15216,,6 141,,098 27,,57 + 9 , 11 35J 225.,000 2.66 , ,37596 0. 2728 1 1.37 + 13953,,9 15+5 7,,7 142,, 131 27,, + 1 + 7,, 3 + Hi

230,,000 2.552 0,,3*190 0. 2588 12.690 14123,,2 16630,.8 1 + 3,,205 27,,30 + 5,,95 36?

236,,000 2. +65 o, 43731 0.2465 13. +70 1+268., 4 15917.,6 14 + . , 181 27., 23 + 4,, 83 372

240.,000 2.36b 0,,42229 0.2357 14.219 14450,,3 16139,,4 145,, 115 27,,20 43.,92 373 245.. JOO 2.289 , ,43639 0.22&0 14.942 14609., 5 16357,,1 1 + 6,, 012 27,,18 + 3,,1 7 38 5 250 ,.000 2.216 0,,45117 0.2172 15.b43 14766.,7 16571,,3 l + o,,876 27,,19 + 2,. 5 + 391 255. 000 2. 15i, o. 45517 0. 2093 16.32+ 14922. 1 16732. 7 1 + 7,,715 27,,23 + 2,, 3 39o

2oj ,,000 2.086 0,,47832 0. 2020 16.988 15076,,1 16991,,8 143,,527 27,,27 + 1,, 6 3 402

265,.000 2.031 0,,432+5 0. 1953 17.636 15229,, 1 17198,,9 149,,316 27,,34 + 1.,25 + u 7 270,, 000 1. 977 0. 5J579 0.1692 lo.271 15381.,2 1740 4,,3 150,, 084 27,,42 + 0,,95 + 12 275. 000 1. 927 o. 5189+ J. 1635 16.692 15532,, 7 17608,,5 150,,833 27,,52 + 0., 7 1 417 280.,000 1.880 0..53195 0.1762 19.503 15683.,8 17611,,6 151,, 5o5 27,,63 + u , ,52 422 285,,0 00 1.836 0,, 5 + 43U 0.1732 20.103 1583+,, 6 16013,,8 152,, 231 27,,75 + 0,,37 42 7 290..000 1.79* 0., bit~i->2 0.1686 20.o93 16985.,3 18215.,4 152.,982 27. 88 ,0. 26 + 32 295. 000 1.754 0. 57013 0. 1642 21.275 16135.,9 18416,,4 153,,670 28,,02 + 0,, 18 43o

300. JOO 1. /lb 0..53262 0. loOl 21.8+8 16286.,7 13617,,2 15+., 345 28. 18 + 0. 1 3 4 + 310. 000 1.647 0. 60730 .1526 22.974 16589., 1 19018.,3 155., 6b 26..51 + . 1J 4+ s 320.,000 1.583 G,,63162 0.1+58 24.07+ 16693.,0 19419. 5 15o. 934 26. 89 + 0. 16 457

330. 000 1. 52 5 0.,65565 U.1397 25.151 17199.,2 19821.,8 153,,171 29, 29 4U. 30 464

itH.,000 1.+72 0.,67940 0. 1342 26.208 17508.,1 20226,,7 159,,37 7 29.,72 + 0,,50 + 72 350. 000 1.423 0. 7 291 0. 1291 27.246 17820. 3 20631.,9 16a. 555 30. 17 + U,,75 47:1 360..000 1.377 0.,72622 0.12++ 28.273 18136. 210+0. 9 161. 707 30. 65 + 1. 05 4 3o 370..000 1.335 0.. 74934 0.1201 29.284 18455. 6 21453.,0 162..836 31. 15 41. 38 + 92 3aa. 000 1.295 0. 77229 0.1161 30.261 18779. 5 213o8. 6 16 3. 9+4 31. 36 + 1. 75 493

390. 000 1.258 0..7950 9 0. 1124 31.26o 19107. 6 22236. 1 165.,034 32..19 + 2.,15 50?

<t00. 000 1.223 0. 81775 0. 1090 32.24+ 19440. 8 22711. 7 16o. 106 32. 73 + 2. 57 511

<*20,,000 1.159 0..85270 0.1027 34.169 20121.,3 23572. 1 168. 205 33. 63 + 3, 4 8 623 4h0. 000 1. 102 0. 9J724 0.0972 36.063 20822. 3 24451. 2 17a. 25 34. 96 44. 44 53? 4o0..000 1.051 0..951+2 0.0922 37.929 215+4. 3 25350. 172. 247 36. 10 + 5. 44 546

480..000 1.005 0. 39530 0.0878 39.772 22287. 7 2626 8. 9 174. 203 37. 24 46. 46 65u

500. 000 0.96 3 1. 03892 0. 0838 41.596 23052. 8 272J8. 5 17o. 120 38. 38 + 7. 49 56o

165
Ml rHflNE ISOBAR AT P = 44.0 BAR

T DEN VOL DP/OT DP/DO E H S ZM CP H OEG K MOL/L L/MJL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/10L/K M/SEC

91.801 28.23* 0. 035*2 20.5829 255.902 3*85. 7 36*1.5 63 062 33. *2 ^2 43 1583 95.000 27.971 0. 03575 19.7373 2**. 0*0 36*6, 2 3803.5 69 877 33 33 52 81 1553

iuo. ooo 27.bo2 0. 03629 18.D006 226.0*1 3901 8 *0ol.* 72 60* 33 *2 53 53 1503 105.000 27. 1*7 G3b3* 17.4731 206. *C8 *16*. 2 *32c. 3 75 23 7 33 50 3* 3' 1*52

110. 000 26.723 0. 037*2 16.*001 191.298 4432. 3 *597.J 77 783 33 *3 55 09 1*02 115.000 26.289 0. 03804 15.3768 17*. 81* 4704, 8 *372.1 8J 2*6 33 20 55 71 1352 120.000 25.8*3 0. 03870 14.3961 159.017 4980. 6 5151.0 82 629 32 85 36 27 1 3 J 3 125.000 25.383 0. 039*0 13.*593 1*3.9*0 5259. 9 5*33.3 8* 93 8 3? *5 56 .87 125-. 130.000 2*. 907 0. 0*015 12. 5561 129.585 55*2. * 5719.1 87 182 32 10 57 6J 120* 135.000 24.413 0. 0*096 11.68*3 115.933 5629. bJJ9.2 89 37 2 31 85 58 52 1152 1*0. 0U0 23.698 0*13* 10.3398 102.9*9 6120 5 630*. b 91 52 1 31 70 59 63 1093

1*5. JOO 23.359 0. 0*231 10.0190 90.586 6*18. 6606.3 93 639 31. ol ol uo 10*4

150. J00 22. 791 0. 0*388 9.217b 78.?91 6722 5 6915. o 95 735 31 52 62 .66 583 155. JOO 22. 167 u < 0*507 8.*314 67.512 7035 7233.3 97 818 31 31 3* *o 931

loO. 000 21.538 0. 0*6*3 7.6550 5o.701 7356. 5 75o0.7 99 897 30 91 06 56 *72 lo5.000 2 0.831 0*801 6.8815 4c. 319 7688. 6 7899. 8 101 98* 30 33 o9 21 812 170. 000 20.0*3 0*989 6.1013 36.3*0 8035, 2 825*. 8 10* 103 29 71 73 05 7*3 1/5.0 00 19. 13* 03226 5.2969 26.756 6*05 3635.0 106 30* 29 83 79 98 669

130 . JOO 18. 023 055*8 *. **51 17.57* 6617 9 <*Uo2.0 103 709 29 98 -iZ 26 5ol 195.000 16. *7* 0, 06070 3.*627 8.752 9320 2 9587.3 111 586 30 87 12* 25 *b9 139.136 13.551 0, 07380 2.1*36 1.006 10C62, * 10337.1 11 5 85 2 37 03 507 5* 293 139.13b 6.839 0. 1*621 0.98*1 0.566 11612 8 12256.1 123 737 42 92 73* 2 3 2*o

190. 000 6. 056 o. loSll 0.8206 1.445 1168* 3 12610.8 127 6J8 36 62 278 05 261 195. JOO *. 7*5 21073 0.562* 3.966 12*53 6 1333C.3 131 cl 6 31 ** 135 5J 23 3 2UJ.000 *. 186 25830 0.*9G2 5.6*4 12773 7 1382 9.5 13 5 690 29 41 78 46 304 205. JOO 3.823 2o 156 0.*332 7.016 13C38, 1 1*189. 135 6b6 29 06 6b 53 317 210. 000 3.552 23152 0.39 26 3.21J 132o* 8 1*503.5 13 7 132 28, 51 39 75 327 215.000 3.337 b 24959 0. 3613 9.26^ 13*71 7 1*7^0.4 133 53 2 26 13 55 ?1 337 220.000 3. 159 316ol 0. 3363 10.273 13665 c 1 505o .

5

139 765 27 86 32 1 3 3 * o 225.000 3.007 53258 0.3155 11.195 1381*9 7

' ?313. 1 1*0 9u9 27 66 *9 7 i 35* 230.000 2.875 3*78 3 u. 2978 12.06* 140Lo 6 1555 7.3 1*1 963 27 52 .7 93 362 235. JOO 2.759 0. 3o2*9 0.2826 12.850 1*198, 5 15793.5 1*2 99 9 27 *2 * o 55 36i

21*0.000 2.655 0. 37667 0.2b92 13.680 1*366 1L023.3 1*3 .967 27 36 -. 5 1*1 37c 2*5.000 2.561 o. 390** 0.257* 1*. 440 1*53J 162*6.0 1** 893 27 3* 4* 47 383 250.000 2.476 4J336 0. 2*68 15.173 1*691 3 16*66.3' 1*5 733 27 33 4 3 70 363 255.000 2.398 *1698 0.2373 15.88* 1*850 5 16685.2 l*b 6*2 27 35 + 3 7 3 93 260.000 2.326 0. *298* C.2286 lo. 57* 15GG7. 9 16899.2 1*7 *7 3 27 39 + 2 5* *31 2o5. 000 2.260 **2*7 0.2206 17.2*7 15163 8 17110.7 1*3 279 2? *5 '+? I 3 4J3

27 J. JOO 2.196 *5490 0.213* 17. 30* 15318 7 1732G.2 1*9 062 27 52 *1 73 411 275.000 2.1*1 *o 7 1* 0.206b 16.5*7 151.72 7 17528. 1 1*9 625 27 61 *1 .43 *lo 280. JOJ 2.0 87 0. *'922 0.20C* 19.17c 1562o. 1 1773*. 6 150 570 27 72 1 13 *21 235. JOO 2.036 49 11* 0. 19*6 19.795 15779 179*0.0 151 297 27 83 4 98 4Zu 290. am 1.966 5J293 J. 1892 2o.*02 15931 D 161*1..

5

152 038 27 96 *0 83 431 295.000 1.9*3 51*60 0. 16*1 21.000 1608* 1 183*0.* 152 7J5 28 10 -J 71 •.35 300.000 1.901 52616 0. 1793 21.589 16236 6 13551. 7 153 388 28 25 .0 6 2 ** j 310.000 1.822 54895 0.1706 22.7*2 165*2 13957.* 15* 719 28 58 -0 54 **3 320. 000 1.750 57140 0. 1629 23.866 lc848 7 193a2.9 156 006 26 95 *0 5 o 457 330.000 1.685 53353 0. 1556 2*. 966 17157 * 19766.9 157 255 29 35 40 t i 46* 3*0.000 l.o25 6L539 0. 1*95 2b. 0** 17*66 c 2J17b.2 153 471 29 77 * 82 472 350.000 1.570 D3701 0.1*37 27.103 17782 6 20535.5 159 b58 3G 23 *1 tj * *79 3oO.OOQ 1.519 t58*2 0.138* 28.1*5 18103 2 2 9 9 7.2 16 818 30 70 *1 32 *8o 370.000 1.471 6796* 0. 1335 29.172 18*21 5 21411.9 161 95* 31 20 *1 c3 493

3 8 . J 1.42 7 7J069 0. 1289 30.185 167*7 21830.0 163 069 31 71 *1 93 4 9 3 39J.000 1.386 ,72159 0.12*8 31.165 19076 7 22251.7 16* 16* 32 2 3 *2 37 5J5

1*00. 000 1.3*7 7*235 0. 1208 32.17* 19*11. 22o77.* 165 2*2 32 77 ., 3 77 512

-.20. 000 1.276 73352 0. 1138 3*. 122 2009*. 1 235*1.5 167 35 33 37 43 65 524

<*<*0.000 1.213 .82*26 0. 1076 36.036 20797 2 2**23.9 169 *02 35 JO ** 63 535

ho j . JOO 1.157 8d*65 0. 1020 37.920 21521 1 25325.6 17 1 *0 6 36 1* .5 53 5*o 480.000 1.105 ,9J47* 0.0971 39.779 22266. 3 262*7.2 173 36 7 37. 28 +6 59 557 500. JOO 1. 059 9**58 0. 0926 41.617 23032 9 27189.1 175, 28 9 38. *1 *7 61 567

166
ME THANE ISOBAR IT P = = 48.0 BAR

T DEN VOL OP/DT DP/DD E H S CV CP W OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL /K J/MOL/K M/SEO

91 .902 28.241 03541 20.5702 256.413 3487.0 3656.9 68. 079 33, 44 oZ 4o 1533

95 .000 27.987 ,03573 19. 8023 244.956 3642.4 3313.9 69. 835 33. 36 52 73 1554

100 .000 27.580 ,03626 18.6193 227.033 3897.6 4071.6 72 561 33 45 5 3 52 1505

105 ,000 27.166 03681 17.4951 209.466 4159.6 4336.3 75. 192 33, 53 54 32 145 + 110 .000 26.744 03739 16.4255 192.413 4427.2 4606.7 77, 736 33. + 7 5 5 03 14Q + 115 ,000 26.312 03801 15.4055 175.980 4699. 1 4831.5 80. 196 33. 23 55. 6 + 1355

120 ,000 25.868 03856 14.4303 160.230 4974.5 5160.0 82. 575 32 88 56 19 130 5 125 .000 25.411 0i935 13.4952 145.196 5252.9 54+1.8 8 + 680 32. + 9 56 77 1253

130 .000 24.938 ,0+010 12.5958 130.884 553+. 6 5727.1 67, 120 32, 14 57 47 1203

135 000 24.448 04090 11.7280 117.277 5620.2 6016.5 89 305 31, 88 58 37 1157

140 000 23.937 + 178 10. 8881 104.340 6110.6 6311.0 91. 448 31 73 5 9 49 110 + 145 000 2 3.40 3 + 273 10.0724 92.030 6406.7 a611.8 93 556 31 b6 jO 81 10u>0 150 ,000 22. 8*1 + 378 9.2770 80.296 b709.6 6919.7 95. 646 31. 55 o2 36 99:> 155 000 22.246 + 495 8. +978 69.088 7020.0 7235.8 97 718 31 33 o4 07 938 160 000 21.606 + 628 7.7300 58.359 7338.6 7560.9 99 782 30 93 56 02 331 165 ,000 20.91D + 731 6.9677 48.076 7667. 3 789c. 8 101, 8+9 30. 35 afi 44 822 17d 000 20.150 0. + 963 6.2028 36.219 6008.7 6246.9 103, 939 29. 71 71 86 753 175 000 19.276 03187 5. +230 28.788 8370.2 3619.2 10b 095 29 79 77 89 685

180 000 18.237 05483 +.b076 19.809 6767.8 9031.0 103, 414 29 86 87 86 603 165 ,000 16.873 ,05 927 3.7110 11.328 9231.4 9515.9 111 07 30. 44 1J9 4 + 50 + 190 000 14.512 0o891 2.5584 3.278 9897.3 10228.1 114 66 3 33 01 213 16 363 195 000 6. 043 1?543 0.7927 2.317 12063.4 12857.7 128 548 33, 82 178 C4 27o 200 000 ".98 9 20 04 + 0.6112 4.364 12535.6 13437.7 131 792 3C 97 99 4 + 29o 205 000 4.441 22517 0.5220 5.956 12 850.9 13931.7 133 936 29. 74 77 23 311 210 .000 4.069 2+576 0.4640 7.286 13108.9 14238.5 135 65 7 29 oO 49 3ii 215 000 3.788 26 + 00 0.+218 3.462 13336.

+

1 + 60 3.6 137 14 28 51 Oil 01 3 33 220 000 3.563 23069 0. 3o90 9.531 13544.9 1+332.2 138 467 28 17 55 ,c9 3 + 3 225 000 3.375 23627 0. 3o25 10.616 13740. 4 15162.5 139 682 27. 92 52 6 3 351 230 .000 3.215 ,31101 0. 3403 11.443 13926.5 15419.3 140 811 27 74 5U 2o 35 9 235 000 3.076 32509 0.3215 12.317 1+105.6 15666.0 141. 872 27 62 + 3 4s 3o7 2*0 000 2.953 33863 0. 3052 13.149 14279.2 15904. o 142, 677 27 54 -.7 03 37 + 2*5 000 2.843 35173 0. 2909 13.94b 14443. 5 16136.3 143. 834 27 49 + 5 .88 331 250 000 2.744 36445 0.2782 14.712 14614.4 1636 3.7 14 + 751 27 47 + 4 9 + 337 255 000 2.b54 37b86 G.2b68 15.452 14777.5 lc586.4 145 63 3 27 + 8 + 4 lo 39 i 260 000 2.571 36899 0.2565 16.170 1+938.5 16805.

6

146 484 27 51 + 3 .52 393 265 000 2.495 o, 43087 0.2472 16.368 15097.6 17021.8 147 308 27 56 42 93 40;

270 .000 2.424 41255 0.2386 17.547 15255.3 17236. o 148 107 2 7 52 + 2 5 + + 1J 275 000 2.356 + 2<t03 0.23C8 13.211 15412.0 174+7.3 146 884 27 71 + 2 17 41u

260 000 2.297 4353 + 0.2235 18.861 15567.7 17657.3 149, 64 1 27 80 + 1 eo + 21 265 000 2.240 + + 6+9 0. 2168 19.497 15722.8 17366.0 15J 380 27 92 41 61 42o

2 30 000 2.186 45751 0.2105 20.122 15877.5 18073.6 15 1 102 26 04 + 1 41 + 30 295 0Q0 2.135 1*68 + 0.2047 20.735 16031.9 18230.2 151 808 26 18 + 1 25 435

300 000 2.087 +7917 0.1992 21.339 16186.1 18+8D.1 152. 501 2 8. 32 + 1 13 44 J 310 000 1.998 D, 500+0 0.1892 22.520 16494.7 18896.6 153 84 7 28 66 40 99 443

320 000 1.918 52127 0.1603 23.669 16604.2 19306.3 165 147 29 01 + 96 + 5 o 330 000 1.646 5+182 0.1724 24.791 17115.3 19716.1 156 40 8 29 40 + 1 01 + D +

3 + 000 1.779 5o210 0.1661 25.890 17 428.7 2012b. 8 157 634 29 83 + 1 1 + + 72 350 000 1.718 58214 0.1686 26.967 17744.9 20539.2 158 830 30 28 41 34 47 + 360 000 l.fafal 60197 0.1526 28.026 18064.4 2 963.3 159 99 8 30 75 + 1 53 46d 3/0 000 1.609 0, 62161 0.1471 29.068 18367.4 21371.1 161 141 31, 24 41 ,88 + 93 380 000 1.660 0. 6+108 0. 1420 30.096 18714.

+

21791. o 162. 262 31 75 + 2 21 49^

390 000 1.514 J5039 0.1373 31.109 19045.6 22215.5 163 36 3 32 27 + 2 66 50o 400 000 1.472 67957 0.1329 32.111 19381.3 2?b+3. 3 16 + 44 6 32 61 + 2 ,97 512

420, 000 1.391. c, 71757 0.1250 34.082 2C066. 8 23511.1 16b. 56 3 33. 91 43 83 52 + 440 .000 1.324 75515 U. 1181 36.015 20772.1 24396.3 168. 623 35 03 4 4 73 53=, 460 000 1.262 79233 0. 1119 37.917 21498.0 2530 1.+ 170 63 4 36. 17 45 71 547 480 0-0 1.206 82931 0.1064 39.791 222h4.9 26225.6 172, 600 37. 31 + 6 ,71 557

500, 000 1.155 0, 8o598 0. 1015 41.643 23C13. 1 27169.8 17 + . 52 7 38. + 4 47 72 5b3

167
ME THANE ISO 8A(t AT P = 52.0 BAR

T OE.N VOL DP/DT OP/DO £ H S CV CP A OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOi./K 1/SEC 92.004 28.249 035*0 20.5576 256 922 3488 .3 3o72 > * 63 095 33 4/ 52 + * 158* 95.000 28.003 0, 03571 19.8171 245 867 3638 > 6 332* • 3 69 794 33 + 52 75 155o

100. 000 27. 598 0. 03624 18.b377 228 020 3693 4 4031 .8 71 518 33 48 53 48 1507

105. OuO 27.185 03673 17.5170 210 519 4155 43*6 3 7 5 147 3 3 56 5 + 27 1*5/

110.000 26. 7b5 03736 lo.*507 193 523 4422 1 *blo .4 77 638 33 50 54 97 1407 115.000 2o.33 5 03797 15.4341 177 140 + 693 4 -.890 9 8J 1*5 33 27 55 57 1353

120. 000 25.893 03662 14.4622 161 436 4968 .2 5169 .0 82 521 32 91 3d 13 131 j 125. joa 25.438 03931 13.5306 146 44b 5245 9 5*5 4 8* 82 3 32 52 5 6 b 7 1261 130.000 24.968 0*005 12.6349 132 17b 5526 8 5735 ,1 87 058 32 17 57 ,3b 1212 135.000 2+.*82 0. 0+035 11.7712 113 ol2 5B11 4 6023 9 83 239 31 91 56 23 1161

1*0 .000 23.975 04171 10.9358 105 .722 61 QO .7 6317 .6 91 3/5 31 76 59 31 11J9

it*i. QOO 23. 44.6 *2o5 10, 1250 93 463 o395 5 6617 3 93 *79 31 08 60 bl 105a 150.000 22.890 0*369 9. 3352 81 76b 6696 9 6924 95 ,55 8 31 56 o2 ,03 1001 155.000 22.303 0*48* 8. 5c27 70 644 7005 3 7238 5 97 ol9 31 36 63 73 9*3 160.000 21.675 U4614 7.6031 59 994 7321 5 7531 4 99 6/0 30 96 o5 52 893 165.000 2J.997 0*762 7.0512 49 6P2 7646 7 7894 3 101 718 30 36 o7 Z2 3o2 1/0.000 20. 252 G + 933 6. 300C 40 054 7963 3 82*0 .1 10 3 733 29 71 70 ,70 771 175.000 19.413 05151 5.5399 30 755 8337 b 8605 4 105 898 29 7/ /6 . 13 7 J J 130.000 18.429 05426 4. 7555 21 945 6722 6 903* 8 103 1 + 7 29 // 3 + 39 623 165.000 17. 19* 0581o 3.5162 13 o97 9159 1 9*51 5 110 64 9 30 17 100 31 533 19J. JOO 15. 301 03501 2.9539 b 12b 9713 ,* 10051 .5 113 79 3 31 50 1 + 5 ,83 *21 195. 000 9. 341 lJ7Jo 1, 3433 697 11185 1 117+1 .8 122 54 38 78 ol/ b5 263 200.000 6.067 lo482 0.7822 3 111 12221 7 13076 8 123 333 32 36 139 23 2ii 205.000 5. 181 14302 0.6332 4 898 12633 13636 7 132 09 30 53 93 5 305 210. JGG 4. 656 21*78 0.5*87 365 12935 . t 1*052 i * 13* 094 29 54 /5 3 5 313

215. JOO 4.285 0. 23337 0.4911 7 644 13189 9 14403 4 135 74/ 28 92 j5 8 5 323 22J. JuO 4.000 25003 0. *481 6 79* 13416 6 1 + 716 7 137 168 26 + 9 39 8 ) 33-i 225.000 3.768 2o537 0.4143 9 848 13625 5 15035 4 133 + 65 2e 19 55 6 J 3 + 9 230.000 3.575 27975 J. 3867 10 629 13622 15276 .6 13 9 6/8 27 97 52 82 35 7 235.000 3.409 23338 0. 3o36 11 752 14009 3 li534 8 140 788 2 7 81 5b 5 7 3o5

2 40.000 3.2D4 3 3 642 o. 343o 12 626 14189 7 15733 .1 141 634 27 71 + 3 83 372 2*5.0 00 3.135 c. 31897 0. 3266 13 46U 143b4 8 16023 5 1*2 825 2/ 64 + 7 43 37 3 250.000 3.02U 33113 0. 3115 14 260 14535 7 16257 5 143 7/1 2/ ol + 6 26 33j

255.000 2.916 0. 3-23* 0.298U 15 031 14703 1 15*36 * 14 + 677 2/ ol *5 32 392 2bO. JOO 2.621 3544o 0.2859 15 776 l*6e7 t o lo711 1 + 5 55 27 b2 * + 5 J 393

2o5. 000 2.734 o. 35572 0.2750 lo. 498 15030 4 16932 2 14o 392 27. 66 43 91 404 27J. JOO 2.654 0. 37676 0.2o50 17 201 15191 2 1715 6 3 14,' 208 2/ 72 *3 33 + lu 2/5.000 2.560 33760 0.2559 17 386 15350 6 173o6 1 14/ 99 9 2/ 30 *2 93 4 15 2:10.000 2.511 0. 39826 0.2*76 18 555 15503 8 17 5 7 9 .8 1*3 7o9 2/ 89 *2 5 c + 23

2(15. 000 2.44o 40 877 J, 2398 19 210 156b6 2 1779 1 .6 143 52 28 JO 4 2 23 425 290.000 2.o86 41913 0.2326 19 851 15823 130J2 * 153 25 3 26 12 + 2 01 433 295.000 2.329 4293b 0.2260 20 481 15979 3 18212 150 9b9 28 25 + 1 61 43j 300. 000 2.275 43947 0.2197 21 100 16135 3 16*20 6 151 c/G 28 39 + 1 b3 43:1 31J.0Q0 2. 177 45933 0.2084 22 306 lb447 2 13335 9 153 032 26 71 4 1 44 443 320.000 2. 068 47691 0. 1963 23 *82 16759 6 192*9 9 15 + 3*b 29 07 + 1 3 5 45 j 330. JOO 2.008 43813 0. 1893 24 626 17073 2 196o3 5 155 619 29 46 + 1 3/ 4o + 3*0.000 1.93* 517J7 0. 1812 25 7*4 17388 9 20077 6 15o 856 29 88 + 1 + 7 + /2 350.000 1.866 0. 53577 0.1738 2b 340 17707 2 20433 1 153 06 30 33 41 6 + + / * 360. 000 1. 604 0. 55425 0. 1671 27 916 18028 5 20910 b 159. 23b 30 80 + 1 86 483 370. JOO 1. 747 57255 0. 16C9 28 973 18353 3 21330 5 16J 3o6 31 29 + 2 13 49 3 380.000 l.u93 0. 59068 0. 1553 30 015 18t81. 9 21753. 4 16 1. 514 31. 80 + 2 43 50j

39J.00U l.o43 oJ 8o5 0. 1500 31 042 19014 6 22179 6 162 621 32 32 + 2 79 5Jj 400. JOO 1.59b 0. o2649 0. 1452 32 055 19351 6 22609 4 lo3 709 32 85 + 3 17 512 420. OUO 1.511 55131 0. 1364 34. 046 20039 6 23*31 165 635 33. 95 + + 03 52 + 4*0.000 1.435 0. o9670 0. 1287 3o 001 2C747 2*3o9 9 167 903 35. 07 + * 93 5 3o 460. JOO 1.366 73125 0. 1219 37 919 21474 9 25277 4 163. 920 36, 21 + 5 65 5+7

4 BO.. 00 1.306 0. 75550 0. 1159 39 609 22223 5 262J4 2 171 892 37 34 + 6 83 553 sOO.QQO 1.251 o. 73950 0. 1104 41. 674 22993 3 271a0. 7 173. 824 36. 47 + 7 83 563

168
METHANE IS08AR AT P =: 56.0 BAR

T DEN VOL OP/OT DP/DO E H S CV CP H 0£G K MOL/L L/MOL 6AR/K BAR-L/MOL J/MOL J/MOL J/rtOL/K J/MOL/K J/MOL/K ,-f/SEC 92,.105 28.257 0,,03539 20.5*50 257.429 3*89.-7 3637.,8 68., 112 33. 50 52.,42 158*

95,,000 28.019 0,, 03569 19.8318 2*6.772 363*..8 333*,,7 69,,75 3 33.,43 52,,72 1557

180,,000 27.615 0;,03621 13.6559 229.002 3889,,2 *092,,0 72,,475 33,,52 53,,45 1509

105,,000 27.20* 0,,03676 17. 5386 211.566 4150,,* 4356 , ,3 7i,,102 33,,60 54,,23 1*59

110,.000 26.786 0,,03733 lo.*757 19*. 627 **17. 4626,,1 77,,6*1 33. 53 5*. 92 1410

115,.000 26.357 0,, 3 79* 15.4623 178.295 4687,,9 4900,,3 80,,095 33.,30 55,,5J 1361

120,,000 25.918 0,, 03658 1*.*938 162.637 4962,,0 5173,,1 82,,4q8 32,,95 56,,02 1313

125,,000 25.*65 0,,03927 13.565b 1*7.689 5239,,1 5459,.0 8*.,766 32,,55 5b,,57 1265

130,,000 2*. 999 0., 0*000 12.6736 133. 461 5519,, 1 57*3,,2 86,,997 32.,20 57.,24 1216

135,,000 2*. 515 0,, 04 79 11.6139 119.939 5802,,9 6031,,3 89,,17 3 31,,95 53,, 09 1166

1*0,, 000 2*. 013 0,, 0*15* 10.9627 107.093 6091,,0 6324,,2 91,, 304 31,,30 59,, 1* 111*

1*5,,000 2 3.4B9 0,,0*257 10.1767 9*. 683 638*.,6 c623,.0 93,,*00 31,,71 3 0,,40 10 61 150,,000 22.939 0,, 0*359 9. 392* 83.2b2 668*. * 6928,,5 95. 471 31,,ol 61.,81 1007

155,.000 22.359 0,, 0**73 8.6263 72.163 b990,,9 724 1,,4 97,,523 31,.39 53,,35 953

loO.,000 21. 7*1 0,, 0*600 7. 87** 61.o05 730*,,8 7562,,4 99,, 561 30,,98 65,,05 893

165,,000 21. 076 0,,0*7*5 7.1321 51.499 7 626,,8 7892,,5 101,,592 30,,38 57,,07 8*2

170., 000 20.350 o., 0*91* o. 393* 41.350 7959. 3234,,2 103,,632 29,,72 59,,61 733

175,,000 19.539 0,,05118 5.6506 32.669 6306.,8 8533,,4 10?,,712 29,,75 7*,,55 71*

180 ,,000 18.603 0,,05375 4.8921 23.999 8681,,2 8982,,2 107,,90 2 29,,71 31,,53 641

ias.,000 17. *6* 0,,05726 *. 0989 15.925 9C97,,2 9*17,.8 110., 288 29.,98 }3,,97 553

190,,000 15.926 0.. 0o278 3. 2328 8.600 959*.,4 99*b,.0 113,, 103 30,,33 121,,64 4oJ

195,,000 13.127 0,, 07618 2. 1622 2.301 1U354.,3 10730,,9 117,,43* 33,,ol 263,,49 33

;

200,,000 7.705 0,, 12978 1.0528 1.896 11776,,1 12502,,9 12o,, 150 34,,16 231,, 11 263

205,,000 6.097 0,,lo402 0. 7770 3.887 12372,,9 13291,, * 130., 058 31. *4 117,, 10 3 00 210. 000 5. 333 0. 13750 0.650* 5.47/ 127*0,,6 13790,,6 132,,466 30.,13 37,,15 314

215,,000 4.636 0,.2J670 0.5711 6.8*9 13030,, 3 1*137,,9 13*,,335 29,,35 73,, 09 32^

220.,000 *• 474 0,,22350 0. 61*7 8.075 13279,,6 14531,,2 135,,914 26,,83 o*.,88 3 37 225.,000 4-169 o.i 2387* 0.4717 9.193 1350*,,4 14841,,3 137,,309 28,,46 59,,60 34o

230,,000 3.955 0., 25286 0.4374 lu.229 13712,,8 15128,,8 133,,572 26,,20 55

,

,70 3>s

235,,000 3.757 0,,2j615 0.*091 11.199 13909., 5 154J0,,0 13d,, 739 2b,,01 52 ,8 3 363

2*0,,000 3.587 0,,27879 0.3852 12.115 1*097.,6 15658,,8 1*0,,829 27.. 68 50. 73 371 2*5 •,000 3. *3B ,,29C9j 0.36*6 12.986 1*279,,0 15908,,0 141,,35 7 27,,80 49,,C3 373 250,, 000 3.305 0,,3J253 0.34(7 13.819 1**55,,2 16149,,7 1*2,, 833 27,,75 47.,bb 33j

255,,000 3.166 0,,31389 0. 3309 1*.619 1*627,,3 16335,,1 143,,766 27,,73 *6

,

.55 391 260,,000 3.076 0,,32489 0.3168 15.391 1*796.,1 lo615.,5 14*., 6b 27.,74 *5,,6* 397

265,,000 2.979 Oi, 3 3563 0.3U41 16.139 1*962.,2 168*1,,7 145,,522 27,,77 * 4

.

,83 4u J 270,,000 2. Bb5 ,,3*613 0.2526 16.86* 15126.,2 17064,,5 1*3,,3s 5 27,,82 *4,,25 409

Z7>,,000 2.306 0,, 356*3 0.2622 17.571 15283, * 17234,,4 147,,162 27,,89 *3 , ,72 41*

230,,000 2.728 Oi, 3 3 6 5 * 0.2725 18.259 15**9. 3 175J1,,9 147,,946 27,.96 43, 23 420

285,,000 2.656 0,,37b*9 0.2637 18.932 15609,,1 17717,,4 1*3,,708 28,,08 *2 , ,92 425

290,,000 2.589 0,, 33629 0.2555 19.590 15768.,0 17931,,2 14d,,452 28,,20 *2 , ,62 43J

295,,000 2.52b 0,,33595 0.2*79 20.236 15526,,3 181*3,,7 150,,179 26,,32 .2,,37 *3*

300,,000 2. *6b o., 4 J 550 0. 2*09 20.870 1608*. 2 18355,,0 15J., 83 9 28,,*7 *2,,18 439

310,,000 2.357 0,,42427 0.2280 22.105 16399.,4 18775,,3 152,,267 28,,78 *li,91 4*3

32u , ,000 2.259 0.. »*26b 0.2167 23.303 1671*,,7 19193,,6 153,,595 29,,13 *1,. 77 433

330,,000 2.170 0,,*o073 0.2066 24.469 17031.,G 19611,,1 15*.,880 29,,52 *1.,7* *o*

3*0

.

, 000 2. U90 o. 47852 0. 1975 23.607 173*9,,0 20028,,7 15o,,127 29,,94 41,,80 472

350.,000 2.U16 0,,49607 0.1893 2 6.721 17669,,4 204*7,,3 157,,340 3 0,,38 41,,9* 473

3o0,,000 1. 9*8 0.,513*0 0. 1819 27.813 17992,,6 208o7,,6 15 -J,,524 30,,35 *2.,13 467

370,,000 1.885 G,,53055 0.1750 28.886 18319,,1 21290,,2 159. 682 31. 34 *2. 38 493

330.,000 1.626 0,,5*752 0.1688 29.9*1 166*9,,3 21715,,4 160.,816 31.,84 42..68 5 03 39J,, 000 1.772 0,,5o435 0. 1630 3U.981 16983.,5 221*3,,8 161,,92 9 32,,36 43.. CI 50 7 400,,000 1.721 0,,53103 0.1576 32.007 19321,,9 22575.,7 163., 022 32.,89 *3,,37 513

*2Q.,000 l.c.29 0,,61*0* 0.1*79 3*. 021 20012. * 23*51., 165. 137 33. 99 **. 17 525

*4fl,,000 1.5*6 0,, 6*66* 0.1395 35.993 20722.,0 24343,,2 167,,232 35, 11 *5..06 5 37 *o0,,000 1.47 3 0,,67 83 9 0. 1321 37.928 21*51.,8 25253,,6 169. 255 3fc..24 *5. 99 5*3

480,,000 1.407 0,,7103* 0.125* 39.832 22202,,2 26132.,9 171,,23 3 37.,38 *t

.

,95 553

500,,000 1.3*7 0. 7*25* 0. 1195 41.709 22973. 6 27131. 3 173.. 17 38. 50 + 7. 94 569

169
HE1 HANE ISO JAf, J.T P = 60.0 OAR

T OlN VOL DP/DT OP/DO E H S CV CP H DEG K MOL/L L/MOL BAK/K EUR-L/MOL J/MOL J/MOL J/MOL/K J/MOl/K J/10L/K d/ScC

92. 206 28. 265 0. 553d 20.5325 257.933 3491.0 3703.3 63. 129 33. 53 52. 40 1565

95. 000 20. 036 0, 03567 19.8+63 247.671 3631.0 38+5.1 69. 712 33, + 6 52. tS 1559

100. 000 27. 632 0. 03619 18.6740 229.979 3865.1 4102.3 72. 432 33. 55 53. 41 1511

105 000 27. 223 0. 03673 17. 30CI 212.609 4145.9 4366.3 75 057 33. 63 5 + 13 1461

110. 000 2o. <J06 03731 16.6GG+ 195.726 + 412. 4636.9 77, 594 33. 57 54, 8c 1412

115. 000 2b. 360 0. 03791 15. +903 179. +44 4662.3 +909.8 80. 045 33. 33 55

.

43 136 + 120. JIG 26. 942 0. 03855 14.5251 163.831 4555.9 5187.2 82 415 32. 98 56 94 1316

125 000 25. +92 0. 03923 13.6003 148.926 5232.2 54o7.6 34. 710 32. 59 3b + 3 1263 uo 000 25. 028 0. 03935 12.7119 134.738 5511.6 5751.3 60 937 32 24 5 7 13 122j

135. 000 2 + . 5tb 0. + 07 + 11.8560 121.257 5794.4 o038.6 89. 106 31. 96 37. 55 1170

IhO. 000 24. 050 0+153 11. 290 108.455 6081.5 o331.0 91. 233 31. 83 58. 9 3 1113

1+5 . 000 23. 530 0. + 25u 10.2277 9o.292 6373.9 662 6.8 93. 32 3 31. 7 + 60 19 1067

150. 000 22. 98c 0. + 350 9. ++86 84.724 6672.1 6933.2 95. 386 31 b4 Bl 65 101 + 155. 000 22. + 13 0. 0-. + 62 6.0886 73.705. C976.9 72+4.6 97 42 8 31 + 2 63 02 960 160. 000 21. 805 0. 0456o 7.9440 63.196 7288.5 7553.6 99 454 31 00 64 61 90o

165. 000 21. 153 0. + 727 7.2106 53.169 7607.5 7891.1 101 +6 9 30 + 36 + 6 851

170 000 20 + 4 + 0. G + 891 6.4833 43.611 7935.7 8229.2 103 + 87 29 72 68 93 79,

175. 000 19. 658 c. 05087 5.7569 34.535 6277.6 8582.9 105. 535 29. 73 73 13 723 160 .000 IB 763 05330 5.0194 25.984 8643. 89 3 2. 7 107 67 5 29 b& 79 23 b53 165 000 17. 700 J j 65 +.2609 1O.046 9042.6 9331.6 1C9 96 9 29, 64 39 2+. 58 J 190 000 lo. 3 + G 0. 0ol20 3.4587 10.878 9503. 9370.2 112 574 30 + 3 108 b3 + 92 195 000 14. 307 0. Oj990 2.5646 4.731 10102.9 10522.3 115 959 31 93 1 j 4 3 3 3 9o aoo oco 10, 137 0386 + 1.+900 1.681 11183.9 11775.7 122 296 34 12 231 19 299 205 JOO 7. 272 13751 u. 9696 2.962 12055.3 1283G.3 127 759 32 39 154 bl 29 3 210 JOO 6. 125 13325 0.7742 + .659 12520. 3 13+39.9 130 .747 30 7b 102 7 3 312 215, 000 5. 457 1332o 0.6o41 6.103 12656.0 13955. 132 333 29 80 31 93 323 220 000 if. 992 2J032 0.59u0 7.391 1313 3.0 1+335.0 13 + ,638 29 17 70 75 33- 225 000 4, 639 2155 + 0.5353 3.565 13376.7 l-6s9.9 136 ,1+3 26 74 3 3 ,72 3h+ 230 000 4. 357 22950 0.+928 9.650 13598.8 1+975.8 137 ,48 8 26 43 5 8 92 553 235 .000 <t, 123 24252 0.4583 1G.o6+ 13806. 2 152ol.3 136 716 2b 21 55 + + 361

2 + oso 3. 92 + 23433 0.+296 11.619 1+002.6 15531.6 139 855 26 Ob 32 82 3b9

2 + 5 .000 3. 761 2ot 5o G.+G52 12.525 1+191. G 15790.4 140 ,922 27 95 50 78 377 25J 000 3 599 c 27785 0. 3841 13.390 14373.0 16040.2 141 931 27 89 + 9 ,16 33 + 2p5 000 3. ttj 2367 + 0.3t67 1+.220 1 + '. 5 . 1 1623 2.5 142 391 27 86 + 7 65 39j 2oO 000 3 341 23931 0.3493 15.019 1+723.2 16519.0 1 + 3 809 27 86 -.6 .73 39d 2o5 000 3. 230 0. 3 J959 0. 3346 15.791 1+893. 1 16750. 1 + + 692 27 38 45 b9 403 273 .000 3 129 31963 0.3214 16.539 15C60.4 16978.2 145 5+3 27 92 45 IS 403 275 ooo 3. 03s 3_'9+6 0.3G9+ 17.265 15225.7 172J2.+ 146 365 27 99 + + 5 + 414 260 000 2. 949 3 3909 0.2965 17.973 15369.2 17+23.8 147 lo3 28 07 + *. G3 419

235 000 2. 869 3«65b 0.2885 18. 06+ 15551.4 17642.8 147 ,936 28 16 + 3 60 424 290 .000 2 794 33 718 0.2792 19.339 15712.6 17859.9 143 694 26 27 + 3 25 + 23 293 .000 2 724 ,3o706 0.2706 2G.000 15873.0 18076.4 14:) 430 2b + + 2 55 43 + 300 .000 2, o59 37611 u.2o27 20.649 16C32.9 13289.5 150 150 28 5 + + 2 71 4 39 310 JOO 2 539 39389 0.2483 21.911 16351.5 18714.6 151 ,54 5 26 8 4 42 37 4 + 3 320 .000 2 431 41129 0.2356 23.133 16669. 7 19137.5 152 837 29 19 + 2 1 3 -.5 j 330 .000 2 33 + ,•2837 G.2244 24.321 16988. 7 19558.9 15 + 163 29 57 + 2 11 + 65

3 + .000 2 2 + c , » + 61o 0.21+3 25. +79 17309.0 19980.0 155 44 29 99 + 2 13 472 350 JOu 2 .166 .4ol71 0.2052 26.610 17631.5 2040 1.8 15b 06 3 30 43 42 .24 43 360 000 2 092 478J5 0.1969 27.716 17956.6 2082+.9 157 85 5 30 90 + 2 41 + 87 370 .000 2 024 .4J419 0.18 94 28.806 18284.9 21250.1 169 02G 31 ,38 + 2 .6 3 49 + 300 .000 1 ,96C ,5101o 0. 1825 29.875 16616.7 21677.7 160 loG 31 38 + 2 91 601

390 .000 1 .901 .52599 0.1761 30.928 18952.4 221J8.3 161 279 32 + + 3 22 507

+ 00 .000 1 646 .5+167 0. 1702 31.965 19292.2 225+2.3 162 377 32 93 + 3 67 513

420 .000 1 746 .57269 0. 1596 34.001 19985.2 23+21.3 16 + .522 3 + 03 t H .35 52o

it 10 .000 1 658 6J328 0. 1504 35.990 2Cf 97. u 24316.7 16b 604 36 14 + 5 .21 537 4oO .JOO 1 .57b .63354 0.1423 37.942 21428.7 25230.0 168 ,634 36 28 + 6 .12 5 + 3 480 .JOO 1 307 33 35 0.1350 39.860 22180.9 261ol.9 170 617 37 + 1 + 7 G7 55-i 500 .000 1 443 .6332G 0.1266 41.750 22953.9 27113.1 172 ,558 38 , 5- + 8 .05 570

170
METHANE IS03AR AT P = 65.0 BAR

T DEN VOL DP/DT OP/OD E H S CV CP W :g k MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOl/K J/MOL/K "l/SEC 92 .333 28.27* 03537 20.5169 256.560 3+92 7 3722 6 63 15 33 57 52 37 1586

9? .000 28.056 0356* 19.86*3 2+8.788 3626 .+ 3858 .1 69 661 33 51 52 65 1561

100 . 000 27.65* .03616 18.696* 231.192 3880 .0 4115 .0 72 3/9 33 59 53 36 1513

105 .000 27.2*7 03670 17.5666 213.90* + 1 + 2 *378 8 75 001 33 o7 54 12 1 + 6 + 110 .000 2b. 831 .03727 16. 5310 197.093 + +05 .6 46*6 .1 77 535 33 61 54 .79 1415 115 .000 2o.*0? .03737 15.52+9 180.873 + 675 5 *921 6 79 983 33. 38 55 3^> 1367

120 .000 25.973 . 03850 14.563/ 165.316 4948 3 5138 .6 82 35 33 G2 55 8 + 1320

125 .000 25.526 03918 13.&*32 150.463 5223 8 5*78 ,5 8* 6+0 32 63 56 36 1273

130 .000 25.065 03990 12.7592 136.325 5502 .2 5761 ,5 86 .66 2 3 2 28 56 .93 1225

135 .000 2*. 589 0*067 11.9079 122.89* 5783 9 60 + 6 2 89 027 32 02 5 7 73 1176

1<*0 .000 2*. 096 .0*150 11. 0860 110.1+4 6 069 8 c339 .5 91 1*6 31 37 58 // 1125

1*5 .000 23.582 0*2*1 10. 2903 93.038 6360 6 6b36 3 93 22 8 31 78 59 9 + 107 + 150 .000 23.04!? 0*339 9.5175 86.532 6657 ,2 6939 .2 95 ,282 31 o7 61 .2 + 1021

155 000 2 2.48 0***3 8. 76*8 75.585 6959 7 72+8 9 97 .312 31 45 62 62 9o3

160 .000 21.883 c 0*570 8.0287 65.156 7268 6 7565 6 99 32 3 31 03 o + 09 91j 165 000 21.2*5 + 707 7.3056 55.220 758* 2 7890 1 1C1 32 3G + 2 55 75 66 5 170 .000 20.55c + 8o5 6.591+ +5.7e7 7907 8 822 + .3 103 313 29 73 67 93 83/ 175 300 19.798 05051 5.8609 36.607 8 2+3 .2 8571 5 105 325 29 73 /l 63 /44

130 000 18.9*7 05278 5. 1676 26.385 8593 e 89.1 8 10/ +11 29 61 76 78 c77 135 000 17.959 05568 4. +437 20.56+ 8982 l 93 + * 103 615 29 71 34 74 60 5 190 .000 16.751 05970 3.6972 13.5+7 9 + 10 + 9798 5 112 038 30 10 98 + 3 "52 5 195 000 li>.136 0560/ 2.^106 7.490 9922 8 10352 2 11 + 913 31 00 12/ 27 + 58 200 000 12.5*5 07972 2. 0**6 2.931 106+5 5 11163 7 119 G17 32 o9 213 99 34o 205 000 9.187 0. 1J835 1.3072 2.503 1157+ 9 12232 + 12 + 5+3 33 14 138 ,97 30c 210 JOG 7.317 13666 0.9698 3.797 12203 1 13091. * 128 +46 31. + 9 128 65 311 215 .000 6.339 1577o 0.6025 5.280 12615 4 136*0 8 131 033 30 J j 35 65 322

220 000 5

.

"/ 8 1/521 0.6982 o. bib 12935. 5 1*07*. * 133 027 29 61 79 37 333 225 000 5.250 130*8 0.62+9 7.8*0 13207 ,2 1 + 4+ 5 .3 13* .695 29 09 o9 . 7 5 3 + 2 230 000 *. 895 o. 20*30 0.5695 8.973 13**9 3 1 + 777 2 13d 15 + 26, 73 o3 42 351 235 000 4.b0? 21707 0.5256 10.033 13671 7 15032 6 13/ + 66 28 + 6 38 .96 3o0 2*0 000 4. 366 22905 0.*898 11.031 13679 9 15368 7 138 673 26 28 55 6o 36:) 2*5 000 4. 160 0. 2+0*1 0.*597 11.977 1+077. 8 156+0. 5 139. 793 28 15 53 13 3/j 250 000 3.980 0. 25127 0. 4340 12.879 1*267 7 15901 1+0 646 28 06 5l 15 333 255 000 3. 821 25171 0.+118 13.7*2 1**51 5 16152 6 1 + 1 843 28. 01 + 9 5 6 363 260 000 3.o79 0. 2/131 0. 3922 1*.572 1*630 4 16337 1 1 + 2 792 26 00 + 8 2/ 39o

2o5. 000 3.551 0. 2-3161 0. 37+8 15.373 1 + 805 3 16635 3 1 + 3. 701 28. 01 + 7 21 4 02 2/0. 000 3.435 G 29116 0. 3592 16.1+8 1*9/7 16869 5 144 5/5 28. 04 46 33 403

275, 000 3.328 330*8 0. 3+51 16.900 151*6 2 37099 3 1 + 5 415 28. 10 + 5 6 413

230 000 3.230 0, 3 J 96 0. 332+ 17.631 15313. 3 17325 8 l + o 23 5 28. 17 + 4 99 419

285. 000 3.139 0. 31855 u. 3207 18. 3+4 15 + 78 6 175 + 9 + 1*7 026 26 26 + 4 48 42 + 290 000 3.055 0. 32735 0.3099 19.039 156 + 2 9 177/0 7 14/ 796 26 37 + 4 05 42 9 295 00 2.976 0, 53600 . 3 G 19.720 15606 1/93C, 1+3 5+6 28 + 9 + 3 L3 + 3 + 300 000 2.903 o. 3**53 0. 29C9 20.386 15968 3 18207 7 1*9. 278 26 o2 + 3 + 3 433 310 000 2.766 0. 35125 0.2744 21.681 16291 3 16639 + 150 69 3 2E 92 + 2 9/ 443 320 000 2.6*8 0. 37758 0.2599 22.933 16613. 4 190a7. 6 152 053 29 27 + 2 73 45 7 330 000 2.5*1 c. 33356 0.2*71 2+.1+7 Ib935 6 19*93 9 153 364 29 64 + 2 57 IC'J 3*u. 000 2.443 o. 4J93G 0. 2357 25.329 17259. 19919 + 15* 635 30. 05 42. 55 4/3

350 000 2.35* 424// 0.225* 26. +82 17 56+ 1 2 3*5 1 155. So 9 3C, 49 + 2 61 48 J 3oJ 000 2.273 0. + + 003 0.2161 27. oil 17911. 7 20771 9 15/ 0/1 30. 95 + 2 7 5 + 33 370 000 2.197 0. + 5509 0.2077 26.717 182+2 2 21200. 3 158. 2+5 31. + 4 + 2 95 + 9 + 380 J00 2.128 0. 4o999 0. 1999 29.303 16576. 1 21631 159. 333 31. 94 4 3 20 501 390 000 2. Oo

3

0, 434/3 0. 1928 30.871 16913 6 2206* + 160. 519 32. + 6 + 3 49 503 400 000 2.003 0. 4993* 0.1862 31.923 19255 2 22500 9 161 624 32, 9 9 + 3 82 51 + 420 000 1.893 0. 52819 0.1744 33.98+ 19951. 2 2338*. 5 163. 730 34. 7 + + • 5o 52o

+ 40 ooo 1.797 0. :>5663 0. 16+2 35.996 20665 6 2+26+. 165. 872 35. 19 + 5 4 3 553

+ OU 000 1.71U 0. 53473 0.1552 37.967 21+00, 25200. 8 16/. 90 9 36. 32 + b 23 5 + 9 *30 .0 1.633 0. 6125 + 0. 1*72 33.902 22154, * 26135. 9 169. 699 37. 45 + 7 22 5oU 500 .000 1.562 0, 6*010 0.1*00 +1.808 2 2 929. 3 27089 9 171. 8+6 38. 57 + 3 18 5/1

171
M£ rHANE ISO 3AR AT P = 70.0 BAR

T DEN VOL OP/OT OP/CD L H S CV CP W OEG k MOL/L L/MOL 6AR/K dAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/ 10l/< 1/SEC

92 -.39 28.28". 0. 0353b 20.601+ 259 18 + 3U9 + + 37 + 1 9 63 171 33 60 52 3 5 153-j Jp 000 28.u7fc 03562 19.8619 2 + 9 897 3621 7 3871 ,1 69 ell 33. 55 52 cl 1563

10 a JCO 27 . 676 0< 03613 18.7165 ; 3 2 398 387 + 9 + 127 8 71 32 7 33 o3 63 31 1515

105 .JOO 27.270 3 667 17.6129 215 192 + 13 + 6 -.391 3 7 + 9 + c 33 71 5 + 07 l+o 7 110 OuO 26.857 3 723 16.5612 198 , + 52 + 399 7 + 60G 3 77 + 77 33 o5 5 + 73 1 + 13 115. 000 2b. ".35 0, 03783 15.5591 162 29 + + 668 7 + 933 .5 79 92 2 33. + 2 55 27 1371 120 000 26. JO 3 0. 038 + 6 l+.bul9 166 .792 + 5 + J 8 5210 82 26 5 33 u6 55 75 132 + 125 000 25.559 03913 13.6655 151 .990 5215 5 5 + 89 . + 8 + 570 32 67 56 25 1277

130 000 25. 102 0, 3 981. 12.eG58 137 9 2 5+92 9 5771 6 86 788 32 32 •3b 63 123j 135 ,000 2*. t3u + 060 11.9591 12 + .519 5773 b 6057 8 88 9+7 32 06 57 b2 1181 UJ OUO 2 + . 1+1 0+1 + 2 11. 1+21 111 820 6058 3 63+8 .2 91 JbO 31 91 53 63 1131

Its JO 23. b32 + 231 10. 3617 99 768 bo + 7 7 OC+ 3 9 9 i 13 + 31 82 3 9 70 1080

150 OUO 23.102 0+329 9. 5850 86 322 6 6+2 5 69 + 5 5 9j 179 31 71 oO .95 1C2 1 1 55 .JOO 22. 5%t 0-. + 35 8.8391 77 + + c5+3 7253 5 97 199 31 + 8 o2 25 977 loj .000 21.959 + 551* 8. 1110 67 087 72 + 9 ,3 7536 .1 ^9 196 31 06 S 3 6 J 92a lo5 JOO 21.33-. + b87 7.3975 57 2ib 7561 ,7 7839 .8 101 17c 3C + + 5 5 10 873 170 000 20.C62 + 8+ G 0. 6950 + 7 97o 7881 1 6219 6 103 1 + 6 29 75 j7 3 B2J 175 . OUO 19.53G 05018 5. +956 39 020 621J 7 65ol 9 105 127 29 72 7 35 7 j > laa 00U 19.11= 05231 5. 3063 3L 707 8557 6 892 + 10 7 166 25 57 7 + 7 + 695 lop JOO Id. 188 051.98 +. oG58 2 3 .017 8528 . G 9312 .9 10 9 297 2 C 61 il 2o 62'

190 OOu 17. G89 05852 3. +036 16 07 + 9333 1 97+2 7 111 585 25 88 91 57 55 + 195 JOO 15.710 03356 3.1618 1 G GfcO 9796 132 + 1 6 11 + 160 30 + 6 1J9 59 + 76 200 JOO 13.606 072*3 2. i3l2 5 252 1C370 2 1C377 2 117 396 31 5 + 150 C? 3-3P 205 000 11. Gob 09061 1 .b5Gl 2 978 111+ + + 11773 121 8+5 32 + 7 1 )3 91 335 210 000 8.739 11+ + 3 1. 2208 3 .366 iie+6 1 126+7 .1 123 G32 3 1 95 152 93 313 215 OuO 7.353 1360u 0.971+ + o27 12 3+9 7 133J 1 12 J 115 30 33 11 1 77 32 5 223 000 6.505 0. 1..37 + 0.62+6 5 9t + 12722 2 13796 + 131 399 3C 01 39 23 333 225 JO 5.916 lo90 + 0.7267 7 209 13G27 .0 1+21G 3 133 251 29. + 2 7c 6 3 3 + 2 230 OUO 5. +72 o. 1327 + J.b552 a .370 13292 1+37 1 2 13 + 858 25. Jl o3 + J 351 235 JOO 5.12C 19630 J. 5999 9 + 60 13531 u 1+396 13o ? + b 28 71 •j 2 8J 355

2 + J JOO it. 831 0, 2 J 700 0. 5 5 5+ 1G + 51 13752 6 15201 6 137 52 3 26 + 9 5a 7 3 3u7 2*5 .000 -». 58c 2180 + 0.5187 11 + 69 13961 2 15 + 37 + 133 701 26 33 55 bo 3 7? 250 000 + .376 2285 + J. +877 12 + 01 1 + 159 7 15759 5 139 301 28 23 53 27 532 255 JOO + . 191 23861 J. +610 13 25 + 1 + 350 7 16021 1 + J 836 28 17 51 oi 35a

260 000 + .027 2 + 831 J .+378 1 + 152 1 + 535 8 lb27i 9 1 + 1 01 + 26 1 + -9 nj 39-j 2o5 000 3. 881 0, 25770 0.+173 1 + 979 l+71b. 16519 9 1 + 2. 756 28. l* + 6 Si -» C

7 27J .000 3. 7<tb 2o682 0. 3950 15 779 1 + 892 5 1c7oC 2 1 + 3 65 + 28 16 + 7 So + U3 275 000 3.o27 27571 0. 3626 16 :? 5 *t 15065 8 lc995 8 1 + + 515 28 21 + b 7J + 1 i 200 000 3. sib 28++0 0.3b78 17 3C7 15236 , 7 17227 5 1 + 5 35 + 28 28 + 5 93 + 19 285 000 3.+1 + 29291 0. 35+3 16 + 1 15 + 05 + 17+55 8 1 + 162 28 3b + 5 33 + 2 + 290 ,000 3. 319 30125 0. 3 + 20 16 756 15572 6 17o3 1 + l + o 9+7 26. + 6 + + 67 + 2 1 295 .OUO 3.231 3J9 + o 0. 33G6 19 + 55 15738 + ]79J + 7 1+7 710 28 58 •» + + j + J-. 300 JOO 3.1+9 0. 31753 0.32L1 20 138 15 903 3 1 312c 1 + 3 +5 + 28 71 + »* 10 + 39 310 OOU 3. 000 5333 + 0. 3013 21 . + 66 lb230 .6 1 5 + .2 1 + 9 89 1 25 00 .3 67 4+ rt 320 000 2.667 3+875 0. 28+9 22 7+6 16556 8 13993 151 2o8 29 3 + + 3 ?< +5 7 330 000 2. 7*9 35383 0.27C5 23 98b lb682 5 19 + 29 3 152 r95 29 71 + 3 C + •.c -. 3 + .000 2.6+1 37862 0.2577 25 .191 172C8 .9 19859. 2 153 879 3C 12 + 2 97 + 73 350 JOO 2.51.3 39317 J. 2+62 26 36b 17536, 8 20238. 9 155. 125 3G. 55 + 2. 99 43 1 3o0 000 2. +6 + + J750 u.2358 27 51 + l76oo 8 2u719 3 156 337 31 01 + 3 9 + 33 3/j 000 2.372 + 2163 J.22t3 26 b3o 18199 5 211 31. 157. 52 31. + 9 + 3 2c + J> 380 .000 2.29c c -35o0 0.2177 29 7 + 18535 + 2153 + 7 153. 67o 31. 99 + 3. + 3 5J2 390 .000 2.225 + '+9 + 2 0.2098 30 .82 + 1887 + 9 22020 8 159 809 32 51 + 3 75 5 J J + JJ 00J 2.159 + 6310 0.2025 31 690 15218 2 22+59. 9 160, 921 33. + + '.. Go iij

i.20 .OuO 2. G + u c + 9010 C

.

189+ 33 97b 19917 + 23ii*b 1 lb i 0o7 3 + 12 + + 73 52'

+ + G ,000 1.935 51cS9 0. 1781 36 010 2 G b 3 + . 7 2+251. 6 lD5- 139 35. 13 + 5. 5 3 i5 3 + 60 .000 1.8».2 .5+29+ G. 16c2 38 .000 21371 3 25171 9 167 23 + 36 36 + L + 6

C - , + 80 000 1.758 5o890 0.159+ 39 953 22127 9 26110. 2 15 ). 231 37. + 5 + 7. 37 561

50 .000 l.c82 59i.ol 0.1516 + 1 873 2290 + 8 27Jo7 1 17 1. 183 38. bl .3 32 571

172
METHANE IS03A* AT P = 7 5.0 BAR

T DEN VOL DP/OT DP/OD E H S CV CP W OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/IOl/K -1/SEC

32 585 28.294 03534 20.4859 259.805 3496 1 37ol.2 68. 193 33. b4 52 32 15o7

35 000 28. 096 03559 19.6994 250.998 3617 1 3834.1 69. 5b 33. 59 52 57 15&3

103 000 27.697 03610 18.7403 233.595 3eb9 9 4140.7 72 274 33 67 53 27 1513

1U5 .000 27. 293 U 365-+ 17.6388 21b. 472 4129 1 44J3.9 74 391 33 75 5- 01 14o9

110 ,0C0 2o. 862 03720 16.5911 199.802 4393 6 4b72.6 77 419 33 b9 54 bb 1422

115 .000 26.462 03779 15.5929 183.706 4662 .0 -9-5.- 79. 861 33. -6 55 19 137-

120 000 26. 033 0. 03841 14. 6397 168.260 4933 4 5221.5 82 22 33 10 56 66 1323

125 000 25.592 S9J8 13.7273 153.308 5207 3 550 .4 8- 532 32 71 56 1- 1281

130 000 25. 136 . 03978 12.8518 139.467 5483 8 5762.2 66 714 32 36 5 6 7 2 123-

135 .000 2*. 670 0-05- 12.0095 126.132 5763 5 c067 .

5

83 66 9 3Z 1C 57 47 lldy

IhJ 000 2-. 185 0-135 11.1973 113.481 6045 9 6357.0 93 975 31 95 58 39 1137 145 JOO 23.662 04223 10.4121 101.461 633- 9 6651.6 93 042 31 66 59 48 1087

150 000 23. 156 0*313 9.o512 90.092 bfc28 1 b952.0 95 076 31 75 oO 6 = 10 3 3 155 000 22.O10 0-423 8. 9118 79.27- 6926 7 7258.4 97 088 31 52 61 93 985 160 000 22.032 04539 8. 1911 63.991 723J 6 7571.1 9 1 072 31 09 33 15 935

165 000 21.420 0-669 7. +665 59.217 7543 7890.1 101 C36 30 47 o4 5 38-

170 000 20. 765 0*816 6. 7948 49.943 7655 c 3216.7 102 98 5 29 76 06 .21 832 175 000 20.055 0. + 93o 6. 1126 41.179 8179 9 8553.9 10- 938 29 72 o9 23 773 183 .000 19. 274 05188 6.43bo 32.962 6519 7 69J8.8 106 937 29 5 5 73 00 712

185 000 18. 39= C543b 4.7628 2 5.363 8673 9 92 3 c. 6 10 i 007 29 55 76 44 6-3

190 000 17.376 c, 0575- 4. 0660 18.492 9266 ,1 9697.7 111 199 29 7? 36 59 579

195 000 16. 154 c 05190 3.4102 12.5U2 9f 96 2 10160. 5 113 603 30 14 39 6 3 503 200 000 14.593 0. 05653 2.7300 (.589 10197 2 10711.1 lib 390 30 87 123 10 43. 235 JOO 12.475 08016 2. 0535 -.226 10821 8 11-23.0 11 9 903 31 74 153 22 303

210 000 10. 152 0365J 1.5017 3.750 11603 5 122-7.3 125 876 31 85 154 ,3' 33 7 215 JOO 8. -84 o. 11737 1. 1709 -.306 12066 1295 0.0 127 135 31 13 126 i 2 u 33 J 220, JOO 7.382 13546 0.9711 5.469 12495 1 13511.1 129 765 30 34 39 95 333 225 JOU 6. 636 G 15069 0. 6422 o.695 12637 1 3937.2 131 816 2 9 72 13 6- 34 3 230 JOO 6.089 16423 J. 7507 7.860 13127 .7 1-359.- 133 3-1 29 27 73 7 , 351

235. 000 5. b6- o. 17657 0-6813 6.964 13385 7 14710. 135 049 26 93 3 6 90 3 5 -j 240, 000 5. 319 138 31 G.62o9 10.013 13621 5 15031.5 136 40 3 Zf, o9 3l 99 367 2-5 000 5. 031 c 19875 0.53 24 11.312 13641 3 1533 1.9 137 b42 26 51 58 32 373

250. 000 4.78b 0. 2389- 0.6-52 11.968 14049 1 15616.2 138 790 28 39 55 53 382

255. 000 -.673 o. 21867 0.5135 12.684 14247 9 15637.9 133 86 7 28 31 i3 27 389 2o0 000 -.386 c 22 83 2 3.-862 13.763 14439 5 lul-9.6 1-0 333 26 27 51 43 39s

2t>5. OuO 4.219 G, 23705 0.-622 14.615 14625 4 15-J 3.3 1-1 85 26 26 3 C3 402

270 JOO 4. ufco 0. 2 + 531 0.-4G9 13.436 14806 8 16630.3 142 773 28 26 48 6 3 405 275 000 3.932 25432 0.4220 16. Z3Z 14964 5 16691 .9 143 660 26 32 -.7 63 -1 i 280 003 3.806 2o2o3 .4U49 17.005 15169 2 17128.9 14- 514 26 38 - 7 3 41 J 285, 000 3.b93 0. 2 7 7 5 0.389- 17.757 15331 5 173o2.1 145 339 28 46 -b 3 J 42- 2^0 OUO 3.588 27671 0.3753 16.491 15601 8 17592.1 143 139 26 55 45 7 1 43j 295. JOO 3.490 0. 23652 0. 3b24 19.207 1567J 5 17819.4 14b 916 26 o7 - 3 22 435 300 JOO 3.399 G 23420 0. 3504 19.907 16837 9 1 3044.4 147 b73 28 79 -4 o 1 43? 31u OGO 3.234 o. 33921 0. 3292 21.265 lbl70. 1 18439.2 149 131 29 J8 44 13 44 i 320. 000 3. J86 0. 32383 0. 3107 22.573 loEOO 1 13928.3 150 527 29 41 -3 7 7 -53

33J 000 2.958 0. 33811 0.2946 23.836 lb829 3 193o5. 1 151 869 29 78 -3 61 4 63 3-0. 300 2. 6-.1 0, 35210 0.28C2 25.0tc 17158 7 19799.5 153 16b 30 18 -3 33 47-

350. 000 2.733 3o684 0.2o74 26.261 17 489 4 £0233. 2 154 42 3 30 61 43 37 462

360. 300 2.636 0. 37936 0.2558 27.42e 17821. 9 206o?.l 155. 646 31. 07 -3 43 46 i 370 003 2.547 332b9 0. 2454 23.569 16156 9 21102,1 156 838 31 55 -3 . 67 496

380. 000 2.-64 0. 43535 3. 2358 29.688 1849- 9 21538.8 158. 0J2 32. 5 -3 77 503

390 OiiO 2.387 0. 4183o 0.2271 30.786 18636. 2 21977.7 159 14 2 iZ 66 -- Id 5 0- 40 J 000 2.316 0. 43174 0. 2190 31.8bb 19181 3 22419.3 160 2o0 33 09 - - 31 3l3

iZQ 000 2. 160 0. 45 713 0. 2047 33.977 19683 6 23312.1 162 -3 6 34. 17 -4 99 523

-40. 000 2.074 G. + 3211 0. 1923 36. 033 20603. 8 24219. b 164. 549 35. 28 -5 77 6-J

460. 000 1.973 0. 53676 0. 1814 38. 041 21342 8 261-3.5 166. 602 3 6 40 -o 62 551

480, 000 1.663 0. 5S111 0. 1716 40.010 22101. 5 2o034.9 168. 605 37. 53 7 52 5o2

500. 000 1.801 Q. 5 5 523 0.1633 41.945 22880 3 270-4.5 170. 5b4 38. 65 -8 -5 572

173
ME THANE ISO 3A-I *T P = 8C.0 BAR

T DEN VOL DP/DT DP/DO E H S CV CF W 0E& K MOL/L L/MOL. BAR/K BAR-L/MOL J/MOL J/MOL J/MCL/K J/MOL/K J/-10L/K 1/SE3 92.711 26.3(13 03533 20.4705 260.422 3497 9 3730 5 63 214 33 68 52 30 1333

9->.30Q 28.116 U. 03557 19.9166 252.090 3612. 6 3337 1 6 i 513 33 63 52 3* 1567

1 JO. 000 27.719 0. 33608 18.7019 23*. 784 3 86* 9 *153 5 72 222 33 71 53 23 1520

1j5. 000 27. 31b 03661 l7.bo44 217.743 4123 6 4416 5 7* 837 33 79 53 95 1472

11 J. J00 2d. 907 33717 16.b2U7 201.143 4387. 5 *o3 * 9 77 3o2 33 73 54 63 1*23 115.000 20.489 03775 15.6263 185.110 4655. 3 *95 7 3 7 3 60 1 33 50 55 12 137 3 120.000 26.062 0. 03837 l*.o770 169.718 4 926. 5233 G 82 156 33 14 55 57 1332

12a. 000 25.624 33903 13.7b86 155. Jlo 5199. 2 551 1 4 84 434 32 75 3 O 03 128; 133.000 25. 173 0. 03972 12. 8971 141.323 547* 8 5732 6 66 642 3? *0 5b Si 1239 137.300 2*. 709 0. 0*0*7 12.0592 127.73* 5753. 5 o077 2 88 791 32. 14 5 7 31 1192

140. JOO 2*. 229 0*127 11.2516 116.130 6035 8 6365 ,9 93 891 31 99 56 21 114 3 145. J Ju 23.731 0*214 13.4715 103.179 6322, 5 6659 6 92 95 1 31 89 5 9 25 iagj

13 J . Jud 23.213 + 308 9. 7161 91.845 6614 1 o*56 7 9* 979 31 78 oO 33 10*3 155.000 22.072 0*411 8. 9828 81. U85 b910. 8 7263 o 9o 97 9 31 55 61 56 59 3 loO.OOO 22.104 04524 8.2692 73.868 . 7212. 4 7574 4 93 952 31 13 32 72 9** I63. 000 21.603 0*651 7.3728 61.167 7519 C 7891 10 90C 30 *9 o3 95 69* 170.000 20. 863 0, 0*793 6. 8909 51.*72 7830 9 8214 3 102 633 29 76 o5 u 7 a** 175.000 20. 173 0. 0*957 6.22C8 43.291 8153 6 85*7 2 10* 757 29 73 66 17 787 160.000 19.420 35149 5.5597 35.158 6483 5 3835 9 10 5 722 29 33 71 * i 72-> 165.000 18.58* C5381 *.9G51 27.o37 8633 & 92o4 3 108 7*0 29 *9 7 13 b u r 1*0.000 17.63 3 05671 4.2553 23.823 9206 7 96i0 ,* 11 J P53 29 51 32 7 5 £ Q3 195.0 00 16-520 0o053 3. ol05 14-847 9612 9 13337 1 113 121 29 91 32 6* 533 200.000 15.169 Cd592 2.9740 9.861 1UGo9 1 13 596 5 115 64 8 3 43 136 39 46 i 205.000 13* +56 0'43Q 2. 3529 6.397 1C603 4 11137 8 116 617 31 11 133 86 * U * 210.000 11.394 0i?7o 1.7865 *.372 11222 8 1192* ,9 122 120 31 53 1*9 6 9 3oj

215.000 9.617 13393 1. 3917 4.592 11792 8 12624 ,6 125 414 31 19 12 9 2 4 344 220.000 8.322 12 016 1. 1365 5.23* 12260 13221 3 123 158 30 5 5 139 21 3*2 225.000 7.tlit 1S502 0.9719 6.323 12639 7 13719 8 13 3 *0 29 ib 31 2. 3*o 230.000 6.743 1*831 0.8565 7 .*60 12957 ,5 1*1*3 9 132 2o5 2 9. *9 79 23 3s 5 235. 000 6.235 13039 3.7710 8.558 13235 ,5 1 4516 , 6 133 876 29 14 71 12 361 2*0.000 5.o29 l 7 13o 3.7045 9.510 13486 6 14859 1 135 31 26 37 O 3 3 5 3oJ 2*5.000 5.494 13202 . 6613 10.619 13718 r 15174 o 136 612 28 oP 51 03 37 5 250.000 5.211 19191 O.oOcS 11.586 13936 2 15471 5 137 811 28 34 57 53 362 25?. 300 4.967 23133 0.5694 12.619 14143 1 15753 6 133 929 28 *5 3 3 23 363 263.000 4.754 21G37 3

.

3374 13.417 1*341 7 16024 6 13 9 981 2& *0 > 3 17 39u 265.300 *. 5b5 21908 0. 5095 1*.283 14f33 5 lb23b .1 1* J *7o 2c 3b 51 6 3 *32 270.000 *.39t 0, 22750 0.*85G 15.124 14723 1 16 5*3 1 1*1 927 26. 39 30- 13 *u6 275.000 4.243 25569 0. 4632 15.936 14902 3 16737 8 142 836 26 *2 *i 3 1 41* 260.000 4. 104 0. 2 + 3oo 0.**36 16.723 15081 17030 3 1*3 710 28 *8 + 8 u* *1 J 265.000 3.*77 25 1** 0.*260 17.497 16256 ,9 172o6 ,* 14* 35 3 2 8. 55 -7 2* -2 , 290.000 3. 86u 25935 0.4100 18.246 15430 5 17532 * 145 3o9 28 o4 *6 t. ' 43„

295.000 3.752 0. 25 65 2 C. 3953 18.978 15602 1 17734 3 14o 160 26 75 *6 01 4 » > 303.000 3.66 2 27383 0.3619 19.693 15772 3 179o3 1 l4o 929 28 87 .6 53 4* j 310.000 3.470 23817 c. 35eo 21.375 lol09 2 11*1* 5 14 i *09 29 15 ** 8 3 -*3 320.000 3.310 33238 . 3373 22.413 16**3 2 l

fl.659 9 14 J 82 3 29 *8 *. 3 3 *3 ) 330.000 3.166 31 56o 0.3193 23.702 lb776 3 193J1 2 151 161 29 85 *3 3 J *o/

3tJ.300 3.040 3289* . 3033 2*. 952 17108. 6 197*0 1 152 491 30 25 *3 61 47^ 350.000 2.924 34 19 7 0.2891 26.168 17442 20177 6 153 760 30 o7 4 3 7 3 *02 3o0.00o 2.819 35479 0.2763 2 7.353 17777 1 23 613 * 15* *9 3 31 13 *3 73 4 9 3 370.000 2.722 3 3 741 . 2o*6 2o.511 1811* 3 21053 7 156 194 31 ol * 3 o ) *?r 380.000 2.c32 37987 3.25*3 29.o4e 18454 * 21*33 3 157 3o6 32 ID *4 111) 5 3* 393.000 2.550 33217 0.2447 3U .758 18797 6 21935 156 513 32 51 + * 26 51,

400.000 2.473 .4343* 0.2358 31.862 1914* * 22379 2 159 636 33 14 + 4 3 5 517

".2 J .030 2.335 42832 0.22L1 33.987 19850 23276 5 lbl 327 3* 22 * 3 23 523 **0.300 2.213 *5189 0. 2066 36. 063 2C672 8 2*136 163. 9*7 35. 32 *G 9o 541 4b0.000 2.106 ,47513 3.1948 36.090 21314 3 25115 4 lbs 038 3t_ 45 *b 73 55<2 480.000 2.006 *3608 3. 1343 40.076 22075 2 26359 9 163. 31 8 37. 37 *7. 67 56 j 500.000 1.920 52079 0. 1751 42.024 2265o C 27022 3 169 982 38 o9 *8. I 6 673

174
He. THANE ISOBAR AT P = 85.0 BAR

T OtN VOL OP/OT DP/DO E H S CV CP W OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/HOL/K J/MOL/K J/MOL/K 1/SEo 92.837 28.313 03532 20.4552 261.036 3*99 6 3799 9 68 235 33 71 52 23 1688 95.000 28. 135 0355* 19.9336 253.17* 3608 3910 2 63 461 33 67 52 50 1569 100.000 27.7*0 03605 18.7832 235.967 3859 ,9 *lo6 3 72 17 33 75 53 18 1522

105. 000 27.339 ,0 3658 17.6898 219.007 4118 .2 442 9 .1 7* 783 33 83 53 91 147^ 110.300 2b. 932 03713 16.6*99 202. *79 4381 6 *b97 2 77 306 33 77 > * 63 1428 115.000 26.51b 03771 15.6593 186.506 *6*8 8 49o9 3 79 741 33 54 55 0* 1 381 120.000 26.092 0. 03833 14.7139 171. 170 4913 8 52**. 6 82. 09 3 33. 18 55 46 1336 125.000 25.656 03898 13.8093 156.516 5191 2 5522 5 8* 36 7 32 79 5 5 93 129 3 130.000 25.209 03967 12.9*19 1*2.566 5*66 5833 1 86 570 32 *4 5b 47 12** 135.000 2*. 74b 0*0*1 12. ioe2 129.32* 67*3 .6 6067 1 86 71* 32 18 57 17 1197 1*0.000 2*. 272 0*120 11. 3051 116.766 602* 8 6375 93. 808 32. 02 38 0* 11*3 145.000 23.779 0*205 10.5298 10*. 863 6310 2 665 7 7 92 86 2 31 93 59 = 1093 150.000 23.267 0*298 9.7797 9 3.579 o60J 3 6965 6 9* 862 31 82 oO 14 1050 155.000 22.733 0*399 9.0523 62.67b 6895 2 7269 1 96 67 2 31, 59 61 2* 1001

loO. 000 22. 173 0. 0*510 8. 3*5* 72.721 719* 7 7578. 1 96 833 31, 16 o2 32 952

165. 300 21.56* 0. 0*633 7.656 7 63.066 7*98 6 7892 * 100 768 30 »2 63 43 90- 170.000 20.957 0*772 6. 9838 53.965 7807 2 8212 ,8 102 661 29, 60 3 4 78 f,55 175.003 20.286 0. 0*929 o. 32*6 45. 360 8122 6 65*1 o 10* 58 4 29 74 o7 24 3U0 ISO. 000 19.558 05113 5.6767 37.302 8*50 2 888* 6 105 518 29 52 7 13 7*3 185.000 18.758 05 331 5.0386 29.8*7 8792 92*5 1 106 492 29 45 74 18 b8* 133.000 17.861 05 599 *.*C9* 23.081 9153 .1 9o29 110, 539 29 52 79 69 b23

195. 300 16. 83* 0. 059*0 3.7903 17.113 95*0 9 100*5 9 112 704 29 74 37 51 5o0 230.300 15.626 0. 0o*00 3.1855 12.069 9966 2 10510 2 115 055 30 12 96 9 3 437 20?.300 1*. 166 07058 2.6023 8.093 10**5 3 110*5 3 117 696 30 o5 116 10 437 210. 000 12.417 0. 03053 2.0572 5.550 1C991 6 llb7c 2 12 736 31 11 13* 95 387 215. 300 10.653 09387 1. 6173 5.39* 115*9 .6 123*7 5 123 896 31 16 128 44 3b2 223.000 9.26* 0, 13795 1.3200 5.461 12031 c 129*9 1 126 b6 2 3C. o2 112 42 35* 225.300 8.210 0. 12180 1.1157 5.160 12*39 1 13*7* 3 129 024 30 12 37 56 353 230.300 7.427 0. 13*55 0.9727 7.185 12783 ,5 13928 131 019 29 67 8* 58 3a7 235.000 6.830 0. 1*6*3 0. 6683 8.261 13082 1*326 5 132 733 29 31 75 33 364

2k 3 . 303 6.358 0. 15727 0.7862 9.291 133*9 l*oa5 8 13* 24 6 29. 04 j 8 7* 370 2*5. 1)00 5.972 0. 1374* 0.72*6 10.297 13593 * 1 501b 7 135 611 28 83 53 65 37 7 250.300 5.6*9 0. 1?73* 0.b72* 11.269 13621 4 15326 2 136. 862 28. o9 oO 13 33* 255. 000 5.371 o. H617 0.6288 12.208 1*036 8 15bl9 .3 136 022 26 59 57 21 390 253.030 5.131 0, 13*91 0.591b 13.116 1*2*2 5 15o99 3 139 110 28 52 54 83 397 2o5.000 4.916 2 3 332 0.559* 13.995 1***0 6 16158 8 1*0 137 28. 50 52 . 9 9 403 270.300 *.729 211*5 0.5312 1*.8*7 1*632 5 16*29 6 1*1 112 26 50 51 *4 403 275.300 4.569 0. 21933 0.5063 15.o75 1*819 4 lo633 7 1*2 044 26 53 5 16 415 230.000 4.405 0. 22700 0.4641 lb. 479 15C02 3 16931 6 1*2 933 26 67 * 9 C 3 420 265.000 *.265 0, 2i447 U o *D*1 17.262 15181 9 1717* 9 1*3 799 2ft o4 *8 19 *2a 290.003 4.136 0. 2*178 0.4460 13.02b 15358 8 17*13 9 1** 630 26 13 47 44 4 31 2*5.030 4.017 0. 2 + 89* 0.4295 18.771 15633 5 176*9 5 1*5. 436 28 i3 *b 60 4 3o 330.300 3.907 0. 2i597 . *144 19.499 15706 3 17682 1 146 217 26 95 *b 25 * * 1 310.000 3.706 0. 2o966 0. 3676 20.911 16 C48 1 183*0 2 1*7 720 29 23 * 5 42 *5 J 320.000 3. »3* o. 28 295 0. 3646 22.269 16386 ,3 18791 * 1*9 15 2 29 55 *4 63 45 9 330.300 3.380 0. 23593 0. 3**6 23.560 16722 7 19237 8 150 52b 29 91 *4 * o 46 7 3*3.000 3.2*1 0. 3J85o 0.3270 2*. 851 17C58 * 19631 2 151 850 30 31 * * ,23 -73 350.000 3.116 0. 32097 0. 3113 26.386 1739*. 7 20122. 9 153 130 30. 73 44 11 43 3 360. 3U0 3. 002 0. 33316 0.2972 27.289 17732 3 2056* 1 15* 373 31 19 *4 12 491 370.000 2.69 7 0. 3*515 0.28*6 28.*63 18C71 8 21035 7 155 583 31 66 ** 2J 493 360.003 2.601 0. 35 698 0.2731 29.613 18*1* 21**8 3 15o 76 3 32. 15 ** 33 505 390.000 2.713 o. 3686o 0. 2625 30.7*0 16759 1 21892 8 157 918 32 06 *4 ,65 511 400.000 2.630 0. 38020 0.2529 31.8*6 19107 7 22339 5 159. 349 33 19 ** bJ 510 420.300 2.482 0. 4029* 0.2358 34.005 19616 * 2 32*1 3 161 2*9 34 26 *5 41 530 440.000 2.351 0. *2526 0.2211 36.102 205*2 2 * 1 5 6 6 163. 373 35- 37 * b 1* 5*2 4o0. 000 2.236 o. »*726 0.2083 38.1*6 21285 ,9 25367 o 163 446 36 49 46 95 553 480.000 2.132 0. to 896 0.1970 43.147 220*9 2b035, 2 167 453 37 61 + 7 61 56*

5 0.000 2. 039 0. 43043 0.1869 42.109 22631 8 27030 * 163 433 38. 73 *3 71 573

175
ME'rHANE ISOBAR U P = 90.0 BAR

T DEN VOL OP/DT DP/OD E H S CV CP W Olu K MOL/L L/MOL BAR/K BAR-L/MOL J/HOL J/MOL J/HOL/K J/MOL/K J/MOl /K -1/SEJ 92. 963 28. iZS 0. 03531 20.**G0 261. 6*7 3501. * 3819. 2 b3. 256 33. 75 52. 2 5 1583

15 000 28.156 0. 03552 19.9503 25* 250 3603. 5 3923 2 63. *11 33. 71 52. */ 1571

100. 000 27.761 0. 036J2 18.8u<-2 237. 1*0 3855. *179. 2 72. 119 33. 79 53. 1* 15?s

105 ouo 2 7.36 2 0. 03655 17.71*8 220. 263 *112. 6 *** 1 7 7*. 729 33. 37 53. 65 1*77

110 000 26. 956 0. 03710 Id. 6788 203 806 *375. 6 *7J9 5 77. 2*9 33. 61 5*. *7 1*51

lis. 00J 26.5*3 0. 03767 15.6920 187. 893 *t*2. 2 *931. 3 79. 682 33. 58 5*. 97 1365

120. 000 26. 121 o

.

03628 l*.75u3 172 611 *9ll. 6 5256, 2 82. 030 33. 22 55 39 1339

125 000 25.666 0. 03893 13.8*96 158 006 5183. 3 5533. o 8*. 300 iZ. 83 35. 62 129*

140 000 25. 2<tH 0. 03961 12.9661 1** 10* 5*57. 2 6313 7 8o, *99 32. *8 s o 35 12*3

1 35, 000 2<t'« 78 = 0. 0*03* 12. 1565 130. 90* 5733. 9 6037. 88. 638 32. 22 57. 03 1202

1*0 000 2*. 31* 0. 0*113 11. 3578 118 389 601*. o33* 1 90. 726 32. 06 5/ 0/ 115*

1h5 000 23.o2b c

.

0*197 in. 5871 106 s32 6298. 1 b675 9 92. 77* 31. 97 id, 8* 110s

15J. 000 23.320 0. 0*288 9.8*21 9? 298 658o. 8 o9 7 2 7 9*. 76o 31. 86 59 89 1057 155 000 ZZ. 793 0. 0*387 9. 120* 8* 6*8 6e80 7 27u 9 96. 7o7 31. o2 3 2 9* lu03

loO 000 22.2*1 0. 0**9b 6.*198 7* 551 7 17 7 3 7532 1 98. 718 31. 19 ol 93 5ol

1 55. 000 21.b62 G. 0*cl6 7.7383 b* 980 71-73. 9 733* 3 100. 639 30. 55 6 2 95 91*

i?.o 000 21. 0«»8 0. 0*751 7. J738 55 92* 776* 3 8211 ,9 102 536 29. 02 o * Is 8 Co 175 000 20.39+ 0. 0*933 . *2** *7 363 8095. 8 6557 1 10*. *1S 29. 75 06 39 312 180 JuO 19.689 0. 05079 5.738* 39 393 8*13, 2 8375 3 106 323 29. 52 o9 L 1 7sO Ids JOO 18.920 0. 0528c 5.1c*5 32 002 8753 9226 7 103 26 29. *3 72 60 701 19u OuO 18. Odd 0. 05535 *.5627 25 276 910*. 2 960 2 .3 110 25 2 29. *5 7/ 13 o* 3 H!) OoO 17. 109 5 8*5 3. 95*s 19 315 9*77 2 lGuJ 3 3 112 335 25 ol 03 C 3 58 i 200 000 16. 007 0s2*7 3. 37*1 1* 220 9679 7 10**1 9 11* 55 5 29 90 )2 39 52 5 20s 000 1*. 720 0. 0o793 2.8182 10 100 10321 6 10933 116 96 30 31 1 J* 71 *os

210 000 13.212 075o9 2.297s 7 13* 10812 9 11*9* .1 11 3 683 3 72 119 73 *1 3 21s 000 11. s77 03638 1.8*27 5 793 11337. 2 1211* 6 122 o03 3C 92 12* o7 362 220 000 10. H»i« 03656 i.sot-a s 92* 1 lc23 1 12710 3 125 3*3 30 57 112 ,*3 3c9 ZZi 000 9. 01* 1109* 1.2b97 6 3*9 122*3 * 132*1 9 127 732 30. 18 130 *3 3o3

Ziti .000 8.129 12301 1.0988 7 .083 12608 7 1 371 E ,6 129 616 25 79 i-> 11 3c ) ZS5 000 7.**5 13*33 0.973* 8 055 12926 9 1*135 .8 131 o23 25 *5 79 33 JOJ 2*0 000 6. 90* 1**85 0. 87B1 9 0b2 13209 6 1*513 ,3 133 213 29 IB -"?

5 37 3 2*5 ,000 6. *6* 15*70 0. 8031 10 dbZ 13*66 9 1*339 2 13* c39 26 97 56 6 5 36j 2s0 .000 6.u97 1j*00 0.7*22 11 018 13705 3 15131 .3 13s 9*1 26 32 o2 * 5 3ou 255 000 5. 785 17235 0.6916 11 956 13923 * 15*35 .0 13/ 1** ?e 71 5 9 1 1 3 92 2ou 000 5.516 13130 . o*07 12 ,Ob7 1*1*2 5 1577* .2 133 267 28 0* 5 o , <3 9 395 2o5 000 6.279 c 139** J. 6118 13 751 1*3*5 8 lt.051 .7 139 32 5 28 oO 5*i * 3 *a t 2/0 .000 5.069 19728 0.5797 1* oil 11.5** 2 16319 7 1*0 327 28 60 62 77 *1 J 275 .000 *. 881 20*89 0. 561* 15 **8 1*735 9 16s79 ,3 1*1 28 1 28 b2 jI 3* *ls

280 000 *.711 .21228 0.5262 lc .262 1*923 .0 lo 83 3 .5 1*2 195 28 o7 5 O 1 j *21 285 000 *. 556 219*8 0.5037 17 .05o 15106 .* 17031 .7 1*3 07* 26 73 *9 15 42 s 2iJ .000 *.*15 G .22651 0.*333 17 331 16266 7 17325 .3 1*0 921 26 31 *6 31 * 52 295 .JuO *.286 G 23339 0.*6*9 13 ,5«6 lSi-t* .5 17565 .0 1** .7*1 2e 91 * 7 , 59 *37 300 JOO *. 16* 2*01* 0. **60 19 328 15t*G ,2 176J1 iH 1*5 535 29 03 '*b 99 **2 310 .000 3.9*8 .25327 0. *182 20 .762 15986 .9 16266 . * 1*7 OoO 29 30 *b , 05 *51 320 .JOO 3.759 25630 u.3927 22 ,1*1 16329 3 16723 . * 1*3 511 29 o2 *5 33 *DC 330 .000 3.592 ,2/639 0.3706 ?3 .*73 lbt69 .3 1917* .9 1*9 .90 29 97 * * 9* *o'< 3*0 000 3.**2 2 3u* i 0.3512 2* .763 17C03 ,3 19622 .7 151 .237 30 37 ** • Co *7j 350 .000 3. 306 3J23* 0.33*0 2o .015 173*7 * 2J068 . 5 152 ,530 3C 79 . * 51 *o*

3d0 .000 3.185 ,31397 0. 318b 27 .235 17667 5 20513 .3 153 7a 3 31 2* * * .*7 *9? 370 .000 3.073 .325*1 0.30*7 28 *26 16029 * 2J956 .1 155 001 31 71 4* 51 *9^ 3dQ .000 2. 97 . 53658 0.2922 29 .590 18373 .6 21*33 .8 15o 190 32 21 * * ,L 5 5 > 390 .000 2.879 .3*780 0.28C7 30 .730 16720 7 21851 .0 157 35 1 32 71 * * 61 512 *00 .000 2.7d7 .35 879 0.2702 31 .0*9 19071 ,1 2230G .2 153 ,*09 33 .23 * 5 .0* 5 13 -20 .000 2.o29 ,330*1 0.2617 3* 031 19782 9 23236 6 160 7j0 3* 31 *6 t2 531

**G .000 2.*90 G ,*Jlo2 0.2358 36 .1*7 20511 . 3 2*125 .9 162 ,836 3? *1 *6 3 5 5*5 *oG .000 2.367 •*2251 0.2219 38 .209 21257 .6 250s0 .2 16* 915 36 53 *7 1 t 5 5* *80 .000 2.257 .**311 0.2G97 *G .225 22022 ,9 2b010 .9 166 ,937 37 ,65 .7 .9s 5c5 500 . JOO 2.158 *o3*7 0. 1969 *2 .201 22807 6 26378 .8 168 913 38 77 + 8 .6* 57j

176
METHANE IS03AR AT P = 95. G BAR

T DEN VOL DP/DT DP/DD E H S CV CP H DES K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOi /< 1/SEC

93 69 28.332 G 03530 20.4248 262.254 3503 2 3838 5 68. 277 33. 79 52 23 1590

95 000 26.175 03549 19.9c68 255.317 3599 1 3936. 3 69. 36 2 33. 75 52 43 1572

100 000 27.782 03599 18.8250 238.305 3850 ,1 4192 1 72 0o7 33. 83 53, 13 1527

105 000 27.384 03652 17.7396 221.512 4107 5 4454 4 74 675 33 91 Si 8J 14d3

110 .000 26.961 0, 0370o 16.7074 205.125 4369 8 4721 9 77 193 33 85 54 41 1434

115 .000 26.569 03 764 15.7243 189.273 4635 8 4933 4 7 9 622 33 62 54 9J 1333

120 000 26. 149 03824 I4.78b3 174. G4-+ 4904 5 5267 e 81 96 8 33 26 55 31 1343

125 000 25. 719 038dS 13.6694 159.467 5175 ,4 5544 3 64 234 32 37 55 72 1298

130 000 25.278 0. 03956 13.0298 145.630 5448 6 5824 4 66 429 32 52 5ii 23 1253

135 000 24.824 04026 12.2042 132.472 5724 3 6107 68. 56 3 32 26 5o 89 1207

140 .000 24.356 0410b 11.4097 120.001 6003 4 6333 4 90 646 32 10 5 7 70 1160

145 000 23.673 04169 10.6436 108.188 6286 3 6634 ,2 92 687 32 01 58 63 1112

1?3 000 23.372 0. 04279 9.9034 97.000 6573 g 6980 .0 94 69 2 31. 89 59 66 1064

155 .000 22.851 04376 9. 1871 8b. 401 6865 1 7260 ,8 9o 665 31 66 60 t 5 10 io 160 000 22.307 04483 8. 4925 76.358 7160 6 7586 5 98. 605 31 22 61. 53 969

lo5 .000 21.737 04600 7.8178 66.847 7459 7 789L ,7 100 514 30 57 62 50 923 170 000 21.136 04731 7. 1610 57.853 7762 3 8211 7 102 3 35 29 34 53 57 37o 175 000 20.497 04879 6.5206 49.380 8 07 1 8533 6 1U4 258 29 76 5 62 824 180 000 19.812 05047 5.8952 41.451 6367 8 68o7 3 106 136 25 52 o7 97 771 165 000 19.071 05244 5.2840 34.108 8716 3 9214 5 108 040 29 4l 71 5 717 190 000 18. 258 05 477 4.6671 27.416 9059 .0 9579 ,3 109 986 29 40 75 3 col

195 000 17.354 05762 4. 1062 21.459 9419 9 99o7 3 112 002 29 51 SO 39 6O4

200 000 16.335 05122 3.6453 16.323 9604 c 10316 1 114 122 29 73 37 45 54 7 205. 000 15.172 0. 05591 3.01C3 12.091 10219 5 IO846 7 116. 391 30. 05 3o 61 493 210 .000 13.840 07225 2.5097 d.866 10671 5 11357 9 116 859 30 40 136 29 444 215 000 12. 371 03084 2.0587 6.901 11155 6 11924 5 121 52 5 3C o5 116 94 40 5 220 000 10.952 0, 03131 1.6934 6.463 11635 12502 ,4 124 163 3G 45 111 5' 385 225 000 9.777 0. 10228 1.4277 6.785 12061 4 13033 1 126. 663 30. 17 130. 69 3 7 5 230 000 6. d3G 1132o 1.2324 7.254 12438 13513 9 123 68 2 29 85 31 62 373 235 000 8.L68 12394 1.0657 6.005 12772 1 13949 5 13J 556 29 55 32 71 374

2-+0 000 7.460 13405 0.9740 6.932 13C69 ,6 14343 ,3 132 214 29 29 7 5 09 373 2*5 300 6. 9fco o. l435o 0. 8865 9.690 13339 6 14703 4 133 69 9 29 08 69 21 363 250 .000 o.555 15255 0. 8160 10.838 13568 4 15037 6 135 050 26 93 04 6 7 3S J 255 000 6. 207 lollO 0.7577 11.7tb 13821 2 15351 7 13o 294 28 82 61 11 394

Zofl ,000 5.907 0. lo928 0.7087 12.673 i4G41 ,7 15649 .9 137 -52 28 74 58 27 4JJ 265 ooo 5.b45 17714 0. cb67 13.557 14252 4 15935 3 138 540 26 70 55 9 7 40 3 270 000 5.413 13473 . b303 14.419 14455 4 16210 3 133 568 26 70 54 1 412 275 .000 5.20c 19207 0.p963 15.2fc0 14652 1 &47 6 6 140 545 28 71 52 51 417 280 000 5. 020 19920 0.5701 lb. 081 14643 4 16735 8 141 479 28 75 51 23 423 285 000 4.851 0, 2J614 0.5448 16.082 15030 7 16939 142 376 28 81 50 10 423

290 000 4.697 21292 0.5220 17.665 15214 4 17237 2 143 239 26 69 49 ,13 433 295 ,000 4.555 21955 0.5014 18.431 15395 4 17431 3 144 073 26 99 43 39 43b 300 .000 4.i«24 22604 0.4827 19.180 15573, 9 17721 3 144 860 29 10 47 ~(l 44 3 310 000 4.190 23867 0.4497 20.633 15925 6 16193 146 427 ?9 37 46 fc3 462

320 000 3.986 25089 0.4216 22.031 16272 3 lob55 6 147 896 29 68 4 5 93 4cl

330 000 3.805 26 27 8 0.3973 23.381 lttlo 19112 4 14a 301 30 04 45 42 4o9

340 000 3.645 27-437 0.3760 24.o86 16958 2 19564 8 15J 65 2 3C 43 4 5 08 473

350 OuO 3.500 2*572 0.367 2 25.95B 17300 2 20014 5 151 95 6 30 65 4 4 6 9 485 3o0 000 3.3b9 0, 23635 C.34G4 27.193 17642 9 2u4b2 9 153 219 31 30 44 61 493

370 000 3.249 30776 0.3253 28.399 17987 1 20911 154 447 31 77 44 62 60 3 380 000 3.13 9 0. 31655 0.3116 29.57b 18333 4 21359 7 155 643 32 26 44 92 537 390 000 3.036 32917 0.2992 30.730 16682 4 21839 6 156 612 32. 76 45 G7 513 una 000 2. 944 0. 33966 0.2878 31.661 19034. 6 22231 3 157 955 33 28 45 23 520 420 ,000 2.776 G 36028 0.2678 34.064 19749 6 23172 2 16 177 34 36 45 63 632 44O 000 2.628 0. 33050 .2506 36.200 2U460 7 240 35 5 162 325 35 46 46 51 544 %o0 ,000 2.t98 40039 0.2357 36.279 21229 5 25033 2 164 409 36 57 47 23 55a

4-80 000 2.361 42000 0.2226 40.310 21996 9 25986 9 166 438 37 o9 46 10 56a

500 000 2.27o 0, 43937 0.2110 42.299 22783 5 26957 6 168 419 36 81 48 97 577

177
M£ rhANE ISO 3Af. AT P = 100.0 BAR

T UEN VOL OP/DT DP/DO E H S CV 0° H OtG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K 1/SEC

93. 214 28.342 0. 03528 20. +097 262.858 3505. 3857. 8 6d. 299 33. 82 52 21 169J

35. 000 28. 194 0. 03547 19.9831 256.37b 3594, 7 3949 3 6 3. 312 33. 79 52. 4J 1574

100. JOO 27

.

803 0. 03597 18.d+56 239.463 o8+5

.

3 + 20 + . 9 72. 016 33. 87 53 G6 1523

105. 000 27.<,G7 0. 3 649 17.7641 222.752 4102 2 44o7 74. 62 2 3 3. 95 53 73 1 + 83 110, duo 27. 005 0. 03703 16. 7357 20b. 436 436+. 4734 3 77. 137 33. 69 54 35 1437

115 JOO 26.596 0. 03760 15. 7563 190.645 4629. 4 50 J 5 4 7 9 564 33. 65 5 + 83 1391

120. 000 26.178 0. 03820 14.6219 17p.469 4697. 5 5279. 5 81. 906 3 3, 30 J 6. 22 15 4/ 125 00 25. 761 c, 05663 13.9287 160.960 5167 7 55p6 9 + 168 32, 91 55 63 1302

130. JOO 25. 312 G. G3951 13. 0728 147.146 5440. 5835. 1 So 355 32. 35 56 12 1257

1 33. 000 24.862 0. 04022 12.2512 134. U31 571 + 9 6117, 1 od + 38 32. 29 56 7 5 1212

1*0. JOO 24.398 0. 0+099 11. 4bG8 121.600 6992 9 o + 32 8 90, 566 32. 14 5 7 64 1165

145. 000 23. 319 0. 04181 10. 6991 109.833 6274 6 6692 7 92 601 32. 04 38 4o 1113

150. 000 23. +23 0. 0*269 9.9b37 98.o87 6560 5 6987 5 9 + 399 31, i3 5 9 43 1J 7 j 135. JOO 22.908 0. + 3o6 9.2525 88.137 6850 5 7287 9o 56 + 31. o9 oO 33 1023

lbO, 000 22.372 0. 04470 8.5o36 76.145 7144 2 7531 2 93. 49 4 31 25 j1 25 977

165. 000 21. all + 685 7. 3952 66.085 7+41 7899 5 10 u 39 2 3C 60 o2 08 932

170 000 21.221 + 712 7.2+67 59.753 7740 9 3212 .1 102 258 29 86 o3 C3 8 87 175 JOO 20.597 + 855 0.6136 61.339 80+5. 4 3530 9 10 + 104 29 77 + 52 835

180 JOO 19.930 05017 5.9579 4 3. +64 8358 6 860G 5 105 961 29 32 o7 03 7 8 + 185 OJO 19. 213 5 205 5.3+78 3b. 169 8681 7 52J2 2 107 A33 25 35 5 9 75 7 32

1 JO JOJ 18. +33 05425 +.8139 29.6C8 9C17 9555 ,+ 109 738 25 36 .'3 23 t 73 193 JuO 17. 676 05689 4.2477 23.654 9367 ,7 9936 .6 11 1 697 29 43 7 7 7-3 623

200 000 Id. l24 OoOlo 3.7029 18.382 9737 9 10339 5 113 737 29 60 33 53 33 3 2J5 JOG 15.555 0o429 3. 1849 1+.058 10132 3 10775 2 115 888 29 66 a .95 51,' 210. 000 It. 35-, 0o96o 2.7001 10.650 10 655 3 11252 113 136 30 15 39 92 + 6 3 215 .000 13. U32 07673 2.2561 8.290 110O6 ,4 11773 ,7 12u 641 3C + C us 2 b + 2 3 220 JOO 11. b6 + G 0555 + 1. 879+ 7 .233 11466 3 12322 1 123 lo2 30 28 136 98 403 225 JOO 10. +38 c 3535 1.5B7C 7.302 11894 ,2 128+7 .8 12 3 52 6 30 11 1JC c.7 3 9'., 230 JOO 9.501 10525 1. 3o56 7.ofc4 12276 .9 13329 ,4 12 7 643 29 66 >Z 2 2 304

23'} 000 S.bBo 11510 1.2C38 8.172 12620 ,8 13771 6 123 5+6 29 60 3- 61 3 3 2 2 + d 000 8.021 124o8 1 . l 7 6 3 8.92b 12931 1 1+177 8 13i 256 29 37 7 7 7 3 38-. 2*5 .000 7. -.7* 13393 0.9745 9.81 + 13212 ,6 1-55 J 6 132 793 29 18 71 62 333 250 .000 7.019 ,1+247 0.3936 10.730 13471 .5 14896 .1 134 ld9 2 9 02 -j 7 9 392 255 JOO 6. 635 15072 0.8272 11.641 13712 9 15220 1 135 + 73 28 91 o2 9o 39a 2od 000 6. 304 15863 0.7715 12.p3t 139+0 ,7 1:>527 .0 13c 665 28 3<. ;S . 9'J + 3 265 000 6. 016 15622 0. 7240 13.415 14157 9 15820 1 137 731 28 30 5? 41 4 0:s 270 JOO 5.762 17355 d.6830 14.274 1 + 366 3 Ibid 1 ,8 133 635 2o 78 3 5 3 j 41-, 275 000 5. 636 1306 + J. 6472 15.115 14567 16374 3 13 3 03 + 28 60 33 ,b/ + 1 3 280 JOO 5.332 13753 0.6155 15.938 147b3 6 16639 140 788 26 84 j 2 2-* ".2 + 285 .030 5.14a 13421 0.6874 lo.743 14954 .8 16097 1 141 7U2 28 89 51 05 42 + 290 JOO 4.961 20 77 0.5621 17.531 15142- g 171 + 9 7 1 + 2 531 26 97 5 Z + + 3* 296 000 4.827 20716 0.5392 18.303 15326 , 1 1^337 , 7 1+3 ,+29 29 Ot + 9 .18 + 3 9 3Ju 000 4. t>B6 213 + 2 0.5185 19.059 15507 5 17o+l 7 14 + 2 + 9 29 17 + 8 43 4 4 + 310 .000 4.43 3 22559 J. 4821 20.52o 168o4 .3 1 312 U .2 145 618 29 44 7 , 3: 45 3 320 JOO + .213 23735 0.+512 21.940 16215 .3 1858 8 6 147 336 25 75 + 6

4,' 4d2 330 .000 4.020 2+877 0.+2+6 23.30c le562 7 19050 5 143 726 3 10 + 5 83 + 71

3 + .000 3.847 .25991 0.4013 24.629 16508 ,2 19507 .3 15d ,090 3 49 + 6 5 J -,/ -) 350 000 3.693 27033 0. 3eC8 25.913 17253 1 199ol 1 151 + 06 30 9C + 5 2" + 3- 360 .000 3.653 23147 0. 3b25 27.163 17593 > 5 20413 .1 152 ,t79 31 ,35 + ^ . 15 + 9 + 370 JOO 3.426 23196 0. 3462 28.382 175+4 8 2d8 3 + + 153 916 31 82 + 5 14 501 380 .000 3.308 3J22 7 0. 3314 29.573 18293 3 21316 ,1 I63 120 32 31 + 5 2 u 606

390 .000 3.201 312+ + 0.31O0 30.739 18t4 + 3 2176 6 7 156 29 6 32 81 + 5 3 3 515 400 .000 3.101 . 322+8 0. 3u57 31.882 18998 2 22222 9 15 7 + +6 33 33 45 5, ? 521 420 .000 2.922 .34219 0.2641 34.10o 1971o .4 23138 ,3 15 9 c7 9 34 + C + 6 u + 53 3 440 . J JO 2. 76o .3315 2 C.26 56 36.260 2G450 .2 2 + 065 , 4 161 835 36 50 + 6 ,69 5+3

+ oO .000 2.o26 .3-3051 0.2+96 3o.35b 21201 , 4 25036 .5 lc3 92 7 3f 61 -t .' , + 3 5 3 r* 480 -000 2. 505 33923 0. 23t6 40. +01 21971 .0 259o3 .3 165 ,9o2 37 7 3 46 .25 5o7 300 .000 2.394 .41770 U.2232 42.403 22759 .6 26936 ,b 167 949 3o d5 + 9 1 J 5 73

178
Mt THANc IS08AS AT P = : 110.0 BAR

T DEN VOL DP/DT OP/DU r H S CV CP H DECi K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/IOl/K 1/SuC

93 ,*65 28.361 0,, 0352o 20.3797 26-+,.055 3603,,7 333o,.5 68,,3*1 33,,90 oZ..17 1592

95 .000 28.233 0,,C35*2 20.0150 258,.*69 3 5 85,,9 3975,.5 69,.215 33,,86 52 .3 + 1576

100,,000 27. (>*»«. 0,, 03591 16. 8859 2*1,,75* 3635,.7 *230,.8 71,.915 33,,35 52..93 1533

105,. 000 27.452 0,, 036*3 17. 8123 225,,210 *051,,7 * + 92, * 7*,,516 3*,,03 53,, 00 1*83

110..000 27.053 0,, 05636 lo. 7913 209.. 035 *352, 5 *759,.1 7,',, 026 33,,96 5*,, 2 + 1**2

115,.000 26.6*8 0,, 03753 15. 8192 193,, 365 -+616.,9 5029.. 6 7 d., **8 33. 73 5*.,69 1398

120,.000 2o.235 0,.03812 1*.8920 176,.296 *8o3 ,7 5303 .0 81,. 763 33,,36 6 5 .Do 135 + 125,.000 25.312 0,, 0387* 1*. 0059 163,,680 »152,( 5 = 578,,7 6*.,039 32,,98 55,,* + 1310

130,.000 25.380 0,,039*0 13.157* 150,.152 5*23,,3 535c.7 86,.22 2 32,,63 56 .90 12co

155,.000 2*. 936 0,, 0*010 12. 3*3* 137,• 117 5696,, * 6137., 5 86,.3*2 32,,37 5b,,6J 1221

1*0,.000 2*.*79 0,, 0*035 11. 5c09 12*.,76 6 5972 , * o*21 .8 90,,*10 32,,21 p7 ,2 + 117?

1*5,.000 2*. 008 0,, 0*165 10.8076 113,,07b 6251,,9 6710,,1 92,.+3 3 32,.12 56,, 10 1123

150,.000 23.523 0,,0*251 10.0811 102,.016 6535,,2 7 2,,9 9 + , . *18 32. 00 59,, 1063

155

,

,000 23.020 0,, 0*3** 9.3796 91,,556 6822,.3 73J 0,.1 96,,567 31.,76 59 .65 10 37 loO,,000 22.*97 ,, 0***5 8.7013 81,,o6C 7112,,5 760 1,,* 98,,28C 31,, 31 J u , ,62 9^5

165,.000 21. 953 0,, +555 6. 0**6 72,,30* 7*05,,2 7906,,2 10 J,,156 30,,66 ol,,30 9 + 9 170,,000 21.361. 0,, 0*fc7o 7. *G62 63,,*73 77G0,,1 821*,, 5 101,,99 6 29. 91 62,, 3 5 :> 175 .000 20. 78* 0,, 0*611 o. 7909 65,,163 7998,t c 8527,.7 103,,810 29.,31 o3 ,o7 8 3,' 180,,000 20. 150 0,, 0+963 o. 192G *7,,38o 630-+,,* 3850,,3 105,,c,27 29.,5* •j 5,,*0 3u j 165,, 000 19.*75 0.. 05135 5. ollO *G,.172 6617,,8 9132.,b 107., **7 29,,36 o7 ,60 76 J 190,.000 18.751 0,, 05 33 3 5. 0*66 33,,56* 89*0,,6 952 7,,2 109,,285 29.,31 70,, 6 j 7 5 5 195,,000 17.968 0,, C3300 +.3063 27,,olb 927*.,9 9637,,1 111,, 155 29,,32 .'3 ,7 + 65 3 20 0,,0 00 17.115 0,, 05e + j 3.98fc6 22,,36-+ 9623,, ? 10266,,9 11 3,,073 29. + 2 77 . 9u c33

205.. JOO 16. 183 0,,0ol79 3,*9*2 17,,91o 9967,.8 106o7,.5 115,,056 29.,58 32.,92 5o J 210,, JOO 15.1o3 0,,05595 J. J332 1*.,2*8 10 371,,0 11096,, * 117,,123 29,,78 -16,, 7 3l + 215,, 000 l*.G5d 0,, 07113 2.6090 11,,*21 10773,, 1 11555

,

.6 113,,ZA3 29,, 36 :*-.,,82 +

' - 220,,ouo 12. 895 0., 07755 2.2269 Q,.523 11103.,8 120*1.,9 121. 519 29. 92 38.,93 + * J 225,,000 11.752 0., 01509 1. 9ub0 8,,672 11601,.0 12537.,1 12 5,,7 + 6 29. 36 38 , be -21

230,,000 10. 727 0., G9322 1 . b + 71 8,,706 11987,,9 13013,,* 125,, 63 9 29, 77 32,, u + *lu

235,,000 9. 65 c 0,, 1J1*6 l.-+*72 9,,03* 123*1,,2 13*57.,3 127.,7+8 29. ol 36, c3 * j + 2*0,,000 9.117 0,, 1J969 1.2893 5,,*57 12665,,1 13871,,7 123,,*9* 25. ** 30,, 2 * )1 2*5,, JUO d.*67 0,, 11783 1.1625 10,,025 12963,,9 ] + 2oG,,0 131., 095 29,,29 ?b,, 1 + * j 25 J,,000 7. ^5 2 0,, 12575 1. J697 ID,,76o 132*0,, * l*o23,,6 132,, 5o* 29,,1c 70,,59 * 2 Zoi,,000 7.*97 G. 13336 Q. 975* 11.,593 13*97. 6 1*95 5,,0 133,,917 29,,06 JO , ,23 *0 j 2b J,,000 7. 106 0,, 1+072 U.9G51 12.,4*2 13739,,8 16237,,7 135,,170 2fc, 99 j2,, 5 + 13 2o3,,000 6 • 7o6 G.,1+730 0.8+67 13,,29G 13969,,2 15595

,

,0 136,, 3*1 2 6. 95 dO,, 1 J *15

270,,0 JO o. + o7 0., 15*63 0.79*7 1*.,130 1*168,,6 15839,, o 137. **2 26. 9* 5 7 • 7 3 *1 3 275., 000 6.201 G,,16125 0.7503 1*.,9fcy 1*399,,6 16173,,6 138,,*3* 26, 95 56,, 85 *2 + 280,, JOO 5.96* 0. lo768 0.711* 15,,775 1*6G*,,2 io*+e

,

,7 139,,*76 26.,38 5*.,2 + *2 + 285,, JOO 5.7*9 G.,1739* G. t769 Id,,577 1*803,, 1 1671b.,* 1*0 ,, *2 3 29., J* oZ,, 6

' + 5 + 290,,000 5. 55* G. 1300* G. 6*61 17, 366 1*997. 3 Ib977,,8 1*1, 333 25. 11 3 1

,

,71 + 33 295,, 000 5.376 0., 186)0 O.c-183 18,,1*1 16187,,7 17233.,6 1*2,,208 29. 20 5 u , 71 + + > 30 J , ,000 5.213 0., 1913 + 0.5933 16,,902 1537*,,9 17*35,,2 1*3,,053 29. 31 + 9., c 7 *+ i 310,,000 *.92 2 0.,20317 0. 5*9b 20.,56c 157*1,,9 17 97b,,7 1**.,665 29. 56 + 3. 52 HJi' 320., JOO *.b70 o. 21*12 0.5127 21,,821 16101., 5 13*56,,8 l*o,,169 25..37 *7,,5* *6 5 330,,000 *.+3G 0. ZZh73 J.*811 23. 210 16*56

,

,* 1392 8,, •+ 1*7, 5*a 30. 22 + 6. 63 *7 + 3*0,,000 *.25* 0.,23500 u.*536 2*.,55 8 16 803., * 1939*,,1 1*9,,03 1 3C. bO + ,,3* *31

350.,000 *.079 0.,2+515 0.+295 25. 867 17159. 1 19855. 8 15 J. 36 9 31. 01 + b. 02 *d j 360,,000 3.921 0.,25503 0.*Q82 27,,1*2 17609. c 2031*.,9 151,,66 2 31. *6 + 5.. 63 *5-J 370,, JOO 3. 776 0. 25*72 0.3891 26,,38* 17660

,

,7 20772.,7 152,,917 31. 92 *5. 75 5 + 380,,000 3. 6*6 0., 27*23 0.3719 29,,996 16213.,* 21250,,2 15 + , ,137 32. *1 + 5

,

, 7 6 51 j 390.,000 3.526 o. 28363 0. 356* 30,,786 185b8.,3 21638,,2 155.,326 32. 91 *6,,65 517 MO.,000 3.*1* 0.,29238 0. 3*22 31,,950 16925.,7 221*7,,* 156,,*89 33. *2 6., 00 52 + *20,,000 3.215 c.,31103 0. 3173 3*.,213 19650,, 3 23071.,6 153.,7+3 3*..*9 *u . , *5 5 5,j * tO

,

,000 3. 0*1 c.,32880 0. 2962 36,,*02 20389. 6 2-006. * 16 0. 918 35. 59 + 7. C5 3+3

*60,.000 2.688 0,, 3*62* 0.2779 38,,529 211*5,,7 2*95*.,3 163,. 02* 36. 70 + 7. 73 55 3 *80,,000 2.752 0.,353*0 0.2620 *0.,601 21919.,5 25916.,9 165. 07 3 37. 81 + 8, 53 5 7 j 500,,000 2.629 0. 33G33 0.2*79 *2,,627 22712.,0 2oB95.,7 167.,070 38.,92 + 9,, 35 58 J

179
ME THANE ISO 3Afi AT P = 120.0 BAR

T GEN VOL DP/DT OP/00 E H S CV LP A OEG K MOL/L L/MOL 8AR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K l/SEC

93. 71* 28.360 0. 0152* 20. 3*99 265 239 3512. * 3935 2 63. 36* 3 3. 97 52 1 + 1593

95. 000 26.272 0. 03537 20. 0*60 260. 530 3577. 3 *0 3 1 7 69. ue 33. 9* 32 27 1581

100 JOO 27. U8b 0. 03586 18.9253 2** 013 3826. 3 *256 6 71. 815 3* i2 52 9u 1533

105. 000 27.*9o 0. 03637 17.8595 227 o37 *081. * *517 8 7 + *12 3*. 11 5 3 57 1*93

110 000 27. 101 0. U3690 16.6*56 211 b C* •.3*1, 3 -73* ,1 7b 917 3*. 0* 5 - 13 l+*3

115. 000 26.699 o. 037*5 15.6607 196 055 *eo* 5 505* ,0 79 33 3 33. 61 5* 66 1*0 + 120 000 26.290 0. 0383* 1*. 9bU5 161 089 *870 2 5326 6 81 663 33, *5 3* 91 13ol

125 000 25.873 0. 03665 1-..061* 16o 767 5137 6 5oJ 1 5 83. 912 33 ufc 55 26 1316

130. 000 26.+*6 0. 03930 13.2*00 153 122 5*06. 9 5 87 8 5 8a. 087 32. 70 55 69 1275

135. JOO 25.000 03999 12.*332 1*0 165 5b78 * 6158 ,2 8. 199 32 ** 5o 25 1231

1*0 OOJ 2*. 55o 0. 0*072 11.6563 127 889 5952 c o*+l ,1 90 25 7 32 29 5b 95 II80 145 000 2*.o9b 0. 0*150 1C.9129 116 275 6229, 9 6727 ,9 92. 26 9 32, 19 57 77 11 + 1 IsO JOO 23. fal9 0. 0*23* 10. 19*8 105 293 . 6510. 8 7016 9 9*. 2*2 32, 07 jd 61 1093 155 .000 23.127 0. 0*32* 9.5022 9* 913 6795 1 731* 9 3 177 31 82 59 3 3 1051

lbO 000 22.bl7 0. 0**21 8.8335 85 102 7082 1 7d12 7 93. 07 3 31 37 30 05 1008 165 000 22. 088 0. 0*527 8. 167* 75. 836 7371. 1 791* * 99. 93 30. 71 dO 61 96o 170 .000 21.537 0*6*3 7.5625 67 096 7661 6 8218 .3 101 7*7 29 96 61 20 92*

175 000 2 0.960 0. + 771 6.9561 58 877 795* 7 8527 2 103. 633 29 0* 5 2 6 3 877

ISO 000 20.353 0*913 6.3733 51 18* 825* ,1 88+3 ,7 105 316 29 56 3* + 831

185 JOO 19.713 0. 05073 5.8062 ** 039 8559 5 91o6 .2 107 09* 29. 36 35 65 76>t 190 000 19.033 0525* 5.2631 37 *7* 8*72 3 9502 ,8 106 87 8 29 28 68 03 7 37 195 000 18.306 0. 05*63 *.73S2 31 331 919* 96 + 9 .5 110 679 29. 26 70 71 b69

200 000 17.527 0. 057J? *. 2369 2b 252 9526 10210 7 112. 5J8 29 30 73 63 3*2 205 000 16.690 05992 3.7650 21 675 9fcb9 9 10586 9 11 + 37 6 29 + 77 53 597 210 .000 15.790 0. 05333 3.3212 17 821 10226 8 10966 .3 116 29 3 29 5* 31 6 7 55* 215 JOO 1*.828 0. 0o7*-. 2. 91C8 1* 70b 10596 7 11*06 113 266 29 69 36 03 513 220 JOJ 13. 817 07238 2.537* 12 352 10977 8 118*6 ,3 12 J 29 29 b2 69 fc 9 *0 S 225 ouo 1 2 .

/' 6 a 07620 2.20t2 10 808 11362 3 123J0 6 122 332 29 o3 91 5 9 *3C

230 000 11.797 c 03*77 1.9236 1 J .11* 11739 ,1 12756 .3 12 + 335 2 9. 60 90 L5 *33

2 35 joo 10.902 0. 09172 1.6932 10 133 12095 2 13196 ,9 12o 226 29 52 3 5 *o *23

2^0 000 10.124 0)677 1.5068 10 >*33 12*25 3 13610 6 127 972 29 *2 30 51 ^22 2*5 003 9.*50 11582 1. 359* 10 820 12732 2 1*002 .0 129 587 29 32 76 1 i *19 250 000 6.663 0. 11283 1.236* 11 286 13C19 3 1 + 373 2 131 086 29 23 72 3 + + 17 255 .000 8.352 1197* 1. 13*1 11 .868 13266 9 1*726 .7 132 *83 29 lb 36 71 *ld 2oO 000 7.90b 1>6*8 1. 0*6* 12 olO 13542 9 15030 ,7 133 76* 29 10 3 5 3o -20 2o5 000 7.517 0. 153J* 0.9759 13 387 13783 6 15330 135 001 29 j7 32 + + + 23 270 .JOO 7.17* 13939 0.9139 1* 18* 1*013 2 15686 .8 136 1** 29 06 59 95 + 27 275 000 6. 870 l + 55o 0. 6cL2 1* 983 1*233 5 15930 ,2 137 22* 29 08 57 6 5 *3l 260 000 6.598 15156 3.0133 15 778 1***6 ,2 162 j + ,9 13 8 250 29 11 56 07 *35 2d5 000 6. 353 0. 157*0 0.7719 lb .565 1*652 5 155*1 .* 139 22 9 29 17 5* 53 *39

2JJ JOO 6. 131 15311 0.7350 17 3^3 1*653 6 16810 ,9 1* J 166 29 2* 53 2' + + + 295 .000 5.928 13868 0. 7U19 18 111 15050 2 1707* * 1*1 0o7 29 33 52 16 + + -i 300 .000 5.7*3 17*1* 0.C721 18 869 152*3 1 17332 6 1*1 936 29 *3 51 21 *52

310 .000 5.*13 11*7* 0.620* 20 352 15620 1 17036 .9 1*3 589 29 08 + 9 t,J *bl 320 000 5. 129 0. 19*97 0.5770 21 79* 15986. 3 18327 ,9 1*3 1*8 29 98 *8 57 *69 33J .000 *. 881 23*36 0.5*C0 23 195 16350 7 138J9 .2 1*0 629 30 33 + 7 7 + *77 3*0 .000 *.b61 21*52 0.5060 2* .557 16709 ,2 19283 .5 1 + 8 0*5 30. 71 + 7 15 + 83 350 000 *. *66 22393 0.H8O1 2s 883 17065 7 19752 ,9 1*9 *06 31 12 *b 7 i *92

360 .JOO *.289 2331* J. + 55* 27 175 17*21 3 20219 3 150 719 31 56 + 6 *9 50 3 370 .000 *. 130 2+216 0. *33* 28 . *3o 17777 2 20633 ,1 151 99 32 02 + 6 5 5 507 380 .000 3.96* 0. 25102 0.*137 29 6t9 1813* 1 211*o 3 153. 226 32. 50 + 6 31 513 390 .000 3. 650 c 25973 0.3959 3u .875 10*92 6 21609 .6 15* *29 33 00 + 6 36 523 *J0 .000 3.727 2o632 0. 3797 32 056 16853 8 22073 7 155. 60* 33 32 + 6 *7 62 > *20 .000 3.507 2i51o 0.331* 3* ,353 1958* , 7 230J6 .6 157 880 3* 38 + c 65 5 3<) kka JOO 3.315 o. 3 0162 u. 327* 3d .573 20329 5 239*6 ,9 160 072 35 67 *7 *J 55J *60 .300 3. 1*7 31775 0.3068 36 .727 21090 * £*9J 3 , * 162 193 36 78 + 8 Da 5a? *80 .000 2.997 i 3362 0.2688 *J ,625 21868 5 25672 16* 25* 37 09 + HJ 573 500 .000 2.863 3+92o 0.2730 *2 .87* 226c* 8 26855 .9 16b 26 2 39 00 + 9 6 J 583

180
ME THANE ISOBAR AT P = = 130.0 BAR

T DEN VOL DP/DT DP/DD E H S CV CP A OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/'IOL/K J/MOL/K J/HOL/< M/SEC 93.964 28.398 0,.03521 20.3205 266,,410 3516,,1 3973.9 63,,427 34,,04 52,.10 159 + 95.000 28.310 0.. 03532 20. 0762 2b2,.557 3568.,8 4028. 69., 022 34,,02 52,.21 1585 100.300 27.92d 0.,03581 18.9638 24b,.242 3817 .0 +232.5 71,,715 34,,10 52,, 63 15 + 2 103.000 27.539 0.,03631 17.9056 230,,034 4071,,3 45+3.3 7*,,309 34.,16 53,,43 1493 110.000 27.148 0,,0368* 16.8991 214 142 + 330, 2 +809.1 76,. 810 34. 12 54.. C2 145 + 115. 000 26.750 0,,03738 15.9409 198,.715 4592,,4 3078.4 79,,221 33,,88 54,,43 1411

120. JuO 26.345 0,, 03796 15. 0275 183,,853 4856 ,9 5 35 0.4 81,, 6+4 33,,53 3+

,

,73 1 368 125.000 2 5.93 2 0,, 03856 14.1552 169,,621 5123,,1 5624.4 83,,786 33,,13 55,,09 1323 130.000 25.510 0.. 03920 13. 3206 156,.057 5391,. C 5900.6 85,.95 5 32,,78 55,,49 1283

135. JUO 25.078 0,, 03988 12.5208 143 .175 5660,.8 6179.2 88 ,058 32,,52 56., 02 1240 1-0.000 24.635 G., 0*059 11.7531 130,,971 5 933,,2 6+60 .9 90,.107 32,,36 56.,63 119o

145. 000 24.101 0,,0*136 11.0151 119,.427 6208,.6 67+6.2 92,,110 32,,26 57.. 45 1151

150. 000 23. 713 o. 0*217 10. 3049 106,.517 6487,,2 7035.5 94,,071 32,,13 58,,24 1107

155. 000 23.230 0,, 0*305 9.620b 98,,211 b7b3 .9 7328.5 95 ,992 31,,39 58,,96 10 = * loO.OOO 22.733 0.,0+399 8. 96 8 88,.476 7053,,0 7624.9 97,.674 31,.+4 59,,53 1C22 165.000 22.217 0.,0*501 8.3242 79,.2 92 7333., 6 7923.7 99,,713 30. 77 59. 98 982 170.000 21.682 0,,0*612 7. 7097 70,,o33 7625,,1 3224.7 101,.510 30, 01 50,. 4 , 942 175.000 21.125 0,,0+734 7.1165 62,, + 93 7913,.5 8528.9 103..271 29. 88 61..67 3 9/ 100.000 20.542 0,, 04863 6.5440 54,,373 8207,,3 3840.1 105,,024 29.,59 62,, 38 833 185.000 19.931 0,,05017 5.9921 47,,767 8505,,9 9158.2 106,.7o7 29.,39 o 4

.

, 33 803 190.000 19.287 0,, 05185 5.4613 41,,265 8810,,4 943+.

5

1C6,,507 2°,,27 3D,,19 763 195.000 18. o06 0. 05375 4.9S24 35,,321 9121.,9 9320.6 110,.254 29,,22 53,,33 713 200.000 17.883 0., 05592 4.4672 30,, OOo 9441,,4 10138.3 112,, 014 29,,22 70.. 61 67 i 205. J00 17. 116 0,,058+3 +.GG79 25.,342 9769,,8 10529.3 113,,79 7 29,,27 73,.63 63.

j

210.000 16.301 0.,0513+ 3.5771 21,,345 1C107,, 7 10905.1 115.,60 8 29. 37 76. 7 + 590 215. UOO 15.441 0., 06476 3.1774 18,.020 10455,,1 11297.0 117,,45 2 29.,48 30,, 01 562 220. JOO 14.542 0., 05877 2.81G9 15,,368 10610,,9 11704.9 119,,32 7 29.,39 32., 83 52J 225.000 13.619 0,, 07 343 2.4801 13.,399 11170,,8 12125.3 121,,217 29.,41 35,. 0s + 92 230.000 12.7C2 0. 07 873 2. 1860 12.,13U 11529.,7 12553.

1

123. 097 29. + 2 35. 67 + b i 235.000 11.829 0,,0345+ 1.9376 11.,559 11679.,2 12978.1 124,,92 5 29,,40 53,. 94 4 54 240.000 11.035 <,0:1062 1. 7295 11,,571 12211.,2 13339.2 126.,65 6 29..36 30,.30 + + + 245.000 10.334 0,, 09677 1.5568 11,, o5 1 12522,,7 13730.7 128,,271 29,,30 7 6

,

,3 + + 39 250.000 9.71c 0. 10292 1. 417b 12. 215 12815.,3 14153.

+

129. 777 29. 25 72..81 433 255.000 9.170 b.,10906 1.2992 12,,637 13091,,8 1+5J9.5 131,,187 29..20 39..71 + 3 + 260.000 8.685 0., 11514 1.1989 13,,139 13354,, 1 1+650.9 132,,313 29.,17 136,.67 433 2o5.0GQ 8.255 0,, 1211 + 1.1132 13..755 13603.,7 15176.5 133..761 29. 15 o4. 19 + 3 + 270.000 7.874 0.,12701 1.0397 14,,453 13842,,0 154J3.2 13 + ,,938 29. 16 51..73 43? 275.000 7.534 0.,1,3 27 + 0.97t2 15,,193 1+070,,7 15796.3 13b,.050 29, 18 59,,57 4 + u 230.000 7.229 G.i 13833 0.9207 15,,9*8 1+291,,0 16089.3 137.,106 2 Q ,,22 57,,c9 + *3 235. 000 6. 955 0. 1 + 379 0. 8718 lb. 717 14504,,4 16373.6 133,,113 29.,27 56,, 03 44? 290.000 6.706 0..1+912 0. 3264 17.,46 + 14711,,9 1665 . 5 139,,07o 29. 35 54,,ii 450 295.000 6.479 0.. 15434 0. 7897 16.,21b 14914,,4 lo920.8 140,. 000 29. + 4 i>3,,4 J + 3- 300.000 6.271 •, 159+5 0. 7548 18. 9tl 15112.,8 17135.6 1+ j.. 09 29. 54 '3 2..43 453 310.000 5.904 0.,16933 0.6945 20.,429 15499., 5 17701.5 142,,532 29, 7 9 50. 73 46u 320.000 5.587 0.,17897 0.Q441 21,,664 15876,,1 18202.8 14 + ,,174 30,,09 + 9.. 5 + 47 + 330.000 5.312 0., 13827 0.6013 23.,265 16245.,8 18o93.3 145,,o3 3 30. + 3 + 8. 61 481

3+0. 000 5. 068 o. 19731 0.5645 24,,632 16610,,9 19175.9 147.,124 30. 81 47.,93 439

350. 000 4.851 a. 2J612 0.5324 25.,96b 16973. 19&32.7 148.,30o 31. 22 + 7,.45 + 93 360 .JOO 4.657 0. 21474 0. 5042 27,,269 17333,,8 20125.5 149., 838 31..66 + 7,,13 503 370.000 4.481 0.,22318 0.4791 28. 5 + 2 1769+. 3 2 595.7 151. 126 32. 12 + 6. 9* 51J 380.000 4.320 0. 23147 u.4567 29,,788 18055,,5 21064.6 152., 376 32.,60 + G.. 83 517 390.000 4. 173 0. 23962 0.+365 31..003 18418.,G 21533.0 153. 593 33. 09 + 6. 65 32 3 400.000 4.038 0. 2+764 0.4162 32,,203 16782,,6 22001.9 15 + , ,780 33. bl + 6 ,,93 529 420.000 3.797 0. 2o335 0. 3362 3 + . 528 19619.,7 229+3.3 137., 077 34. 66 47..25 342 440.000 3.568 0. 27669 0. 3593 36,,774 20270,,0 23893.0 159. 286 35. 75 + 7. 75 553 460.000 3.405 0. 29372 0. 3361 33,,953 21035,,6 24854. 161..421 36. 36 + 8, 37 30 + 480.000 3.242 0,,30849 0.3161 41. 073 21618. 25828.

3

163. +95 37. 97 + 9- 08 573 500.000 3.096 0..32303 0.2985 43,,143 22618.,0 26317.4 165,.513 39. 07 + 9. 8* 533

181
ME rHANE ISO BAR AT P = 1+0.0 OA R

T DEN VOL DP/DT OP/DO £ H S CV CP A OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/10'../K -l/SEC 9+.213 28.417 0.03519 20.2913 267.568 3519 9 4012 6 63. 47 34. 12 52. 07 1595 93.000 28.348 0.05528 20. 1055 264-551 3560. 4 4054 2 63 92 7 34. 09 52 16 1583 iao. ogo Z7.^b7 0.03576 19. 0013 248.439 3807 9 4308 5 71. 617 34 18 52 7b 15 + Q 105 , 000 27.583 0. 03625 17.9507 232.401 4061 3 456 8 9 74 20 7 34 26 53 39 1503 11a. ooo 27.19-. 0.03677 16.9512 21o.652 4319. 4 4834 2 7o. 703 34. 19 53 92 1 + 5 + 115.000 26.800 0.03731 15. 9999 201.345 + 580. 6 5103 79. 109 33. 96 54. 31 1417

120. 000 26.399 0. 03788 15.0931 186.586 46+3 9 5374,.3 81 +2 7 33, 60 54 62 1375

125. 000 25.991 0. 03648 14.2274 172.445 5108 9 5647 5 83 66 3 33 21 54 93 1335 130.000 25.574 0. 03910 13.3994 158.960 5375 4 5922 8 85 825 32 85 5 5 3J 1292 135.000 25.147 0.03977 12.6063 14b. 151 5643 7 620 4 87 921 32 39 35 60 12 + 9 1+0.000 24.711 0. 0+047 11.8454 134.014 5914. 4 6+6U. 9 89 961 32. 43 5b 43 120o 145.000 24.2b3 0.04121 11. 1145 122.537 6187 9 6764 9 91 95 4 32 33 5 7 13 1162 150.000 23. 803 0. + 201 10.4117 111 .o93 64o + 4 7052 6 93 904 32. 20 57 90 111 + 155.000 23.331 0.0+28o 9.7352 101.455 6743 7 7343 .8 95 814 31 95 58 55 1077

loJ- OOJ 22. 843 0. G + 37d 9.0835 91.792 7025 7637 ,9 97 631 31 50 39 06 103j

lo5.000 22.341 0. + 47o 8.4556 82.678 7307 5 7934 1 99 604 30 83 59 42 9 + 7 170.000 21.820 0. 0+533 7.6504 7+.092 7590 ,+ 8232 .0 101 293 30 06 59 » 76 953 175.000 21.280 0.0+699 7.2b72 66.021 787 + 6 8532 5 103 022 29 93 6G 8 + 513 180.000 20.719 0.04627 6.7054 58.465 8163 ,4 6839 .1 104 750 29 62 61 67 872 165.000 Zii. 132 0.0+967 6.1650 51.430 845o 2 9131 6 lOo 462 29 41 o3 1 + 830 190.000 19.519 0. 05123 5. b461 4+.935 8753 7 9470 9 108 155 29. 27 34 65 737 195.000 18.875 0.05298 5. 1+96 39.003 9056 8 9798 5 10 9 666 29 19 3b + 1 7 + + 200.000 18.198 0.05495 4.b7b8 33.659 9366 ,1 10135 4 111 57 2 29. 17 58 , + 1 ?01 205.000 17.485 0.05719 +.2292 26.925 9682 7 10433 113 28 9 29. 19 70 oo 661 210.000 16.735 G. 05975 3.8090 24.813 10005 8 108+2 .3 113 020 29 25 7 3 09 622 215.000 15.951 0.06269 3. +176 21.323 10336 ,4 1121 + 1 llo 770 29 34 75 b3 535 220.000 15.135 0.0o607 3.0573 18. +50 10673 ,5 11598 .5 113. 537 29. 22 77 67 55 + 225.000 14.298 0.03994 2.7287 16.187 11013 9 1199 3 1 120 311 29. 23 79 tto 525 230.000 13.45b 0.07432 2. 4334 14.531 11355 3 12395 7 122 08G 29 25 31 G2 501 235.000 12.b32 0.07917 2. 1729 13.470 11692 ,7 12801 123 824 29 26 30 6o h6Z 2*0.000 11.652 0. 03437 1.9483 13.007 12020 >4 13201 6 123 510 29. 26 79 1? 4o3 245.0 00 11. 140 0.03977 1.7586 13.018 12333 3 13530 1 127 113 29 25 7o 15 4j r

J ? ju .000 10.501 0.09523 1.5999 13.282 12629 5 13932 7 123 618 29 23 'Z 91 43 + 255.000 9.932 0.10063 1 .+664 13.630 12910 2 14319 8 130 033 29. 21 39 99 + 51 2oJ.000 9.423 0.10613 1.3528 14.027 13177 .3 14653 1 131 3o6 29 20 37 40 + 4 9 265.000 8.965 0. 1115 + 1.2=51 1+.475 13432 7 14994 2 132 62 8 29. 20 65 b i + + i 270.000 8.554 0. 11691 1.17Co 15.004 13677 ,5 15314 2 133 82 + 29 ZZ 32 92 449 275. uuO 8.184 0.12220 1.0971 15.521 13912 9 1562 3 7 134 96 29 25 5 6 J + 3 U 280.000 7. 850 0. 12739 1. 0328 16.298 1 + 140 ,0 15923 .4 136 040 29 30 59 C3 + 52 285.000 7. 5*8 0.132+1 0.9761 17.006 14359 ,7 16214 + 137 070 29. 3b 5 7 39 + 55 290.000 7.275 0.137+6 0.9259 17.728 14573 1 16 + 97 6 133 G55 29 44 55 9 + 453 295.000 7.025 0.14235 0.8811 18.453 14781 2 1677 + 1 139 000 29 53 5 + b8 461 300 .000 6.Z96 0. 1+71+ 0. 8+09 19.179 1498 + 7 170 + 4 7 139 910 29 64 53 58 46> 310.000 6.391 . 156+6 0.7715 20.618 15360 ,7 17571 ,2 141 637 29 89 51 8

-1 + 72 320. 000 6. U43 0. 165+6 0.7137 22.03+ 157o5. 4 18032 1 143 25 9 3G 19 3C 43 47 J 330.000 5. 740 0.17422 0.bb49 23.425 16142 2 13581 2 14 + 795 30 53 + 9 4 i + 8 j 340.000 5. +73 0. 13272 0.o229 24.767 16513 5 19071 b 14o 259 30. 91 + 6 b7 + 33 350.000 5.23b 0.1UQ0 0.5865 26.121 16681 4 19555 4 147. 661 31. 31 + 8 1^ 5 J JOJ. 000 5.022 C. 19910 0.5545 27. +27 17247 2 20034 o 149. Oil 31. 75 47. 7 3 5j7

37J.000 4.830 0.2070+ 0.5261 23.707 17612 2 20510 8 150. 31b 32, 21 + 7 F 51 + 380. 000 4.b5 5 0.21482 0.50C8 29.960 17977 5 2 935 1 151 581 32. 69 + 7 37 5 2 J 390.000 4.495 0.222+7 0.,781 31.188 183+3. 9 21+58. 5 152. 810 33. 18 + 7. 33 527 400. 000 4.348 0.23000 . 457b 32.393 18711 ,9 21931 9 154 009 33. 69 47 67 333 420.000 4. 08b 0.2+47+ U.4218 3+.739 19455 3 22881 7 15b 32 b 34. 75 + 7. 6 + 3 +

J

440.000 3.659 0.25912 0.3917 37.007 20211 G 2383b b 158. 552 35. 63 + 8. 0:1 533 hoO.OQO 3. b60 0.27319 0. 3b60 39.206 20961 3 248J5 9 160 701 36. 94 + 8 67 567 480.000 3.48 4 0.23700 0.3438 41.346 21767 9 25785 9 162. 767 38. 04 + 9 j + 573 500.000 3.327 0. 30 059 0. 3243 43.433 22571 7 2673U 1 16 + 816 39. 14 50. 08 589

182
METHANE IS08AR AT P = = 150.0 BAR

T DEN VOL DP/DT DP/DD E H S CV CP W OEG K MOL/L L/MOL BAR/K 8AR-L/M0L J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K 1/SEG

9* *61 28.1*36 03517 20.2623 268.712 3523 8 +051.3 68 513 3*. 19 52 0* 1597

95 000 28.386 03523 20.13*0 26o.512 3552. 1 *060.5 68 83 3 3*. 17 52 1 J 1592

100 000 28.007 03571 19. 0380 250. 6C5 3798, 9 +33+. 5 71 52 3*. 25 52 b9 155 3 105 000 27.b25 0. 03620 17. 99^8 23*. 737 *051. *59*.5 7 + 106 3*. 33 53. 31 1507

110 .000 27.2*0 03b71 17.U023 219.131 *308. 7 *359.3 76 598 3m. 26 53 82 1+03 115 000 26.6*9 0, 03725 16. u576 203.9*5 *F68. 9 5127.6 78. 99 9 3*. 03 5* 23 1 + 2 i 120 000 26.*52 0. 03730 15.1573 189. 29G *631, 2 5396.3 61 312 33. 67 5 +

.

+ 9 13 02 125 000 26. 0*8 o. 03839 1*. 2980 175.237 5G95. 5670.6 63. 5+2 33. 28 5*. 77 13 + 1 130 .000 25.636 03901 13.*76* 161.630 5 36 1 59*5.2 85 697 32 92 55 12 1333

135 000 25.215 0. 0396o 12.6898 1*9.091 5627. 6221.9 67 786 32. 56 55 59 1253

1 + 000 2*. 785 0*035 11.9355 137. 02G 5696 1 650 1.3 89 818 32, 50 36 19 1213

1+5 J00 2h. 3*4 o. 0*103 11.2113 125. oG5 6167. 8 6763.9 91 802 32 *0 56. 66 1172

150 000 23.892 0. 0*186 10.515* 11*. 82* c + *2 3 707G.1 93 7 + 2 32. 27 57 57 1130

155 000 23.*28 0*268 9. o + £l 10*. 6*8 6719 3 7359. o 95 6+0 32 02 58 16 1089

160 000 22.951 0*357 9.2C21 95.0*9 6998 1 7631.7 97. +9 + 31. 56 5 8. 62 10*9

le5 000 22.*59 0. 0**53 8. 5822 8d.30U 7277 7 79*5.6 93 303 30 88 56 9 3 1C11

170 JGO 21.952 0. + 555 7.9855 77. +79 7557 3 82*0.6 101 U6* 3G 11 59 1 + 97 + 175 000 21.428 0. 0*o67 7 . + 111 69. +71 7837 7 6537.7 10 2 73 + 29. 97 3O 11 532 ldu ,000 20.885 0. + 788 o. 8588 61.971 8122. 1 88+ j.* 1C + + 89 29. 06 oC 9 6 691 165 0G0 20.320 0*921 6. 3283 5*. 982 8 + 09 7 91+7.9 106 17* 29. *3 62 U7 85 i 1 jj 000 19.733 G5Go8 5.8198 *8.516 6701 2 9*31.* 107 8+6 29 28 o 3 3 + 3 i 195 000 19. 120 0. 05230 5. 3337 +2.569 8997 2 9781.7 109 510 2-3 19 -j * &2 7 to 200 .000 18.+bG 0. 05*1.1 +.8712 37.222 9298 1 10109.6 111 172 29 1* oo + 7 72o 205 .000 17.811 u. 0561* *.*33* 32.*30 960* 5 10**6.

7

112 '83 5 29 1* 36 3 3 66 3 210 000 17. 113 058*3 *. 0217 26.223 991o 6 10793.1 11 + 50 5 29 17 '0 2 7 651 215 000 16.387 06102 3.0376 2*.otG 1023* 1 111+9.5 116 162 29 23 72 33 6 1c 220 000 15. o3t 0. 06 39o 3. 2822 21.551 lu c,5o 6 11516. 117 66 7 ?9 09 ' + 07 563 225 .000 1+.667 c 03726 2.9561 19.06* 10881 7 1189.0.7 119 551 2G 09 75 7--> 55 > 230 000 1*. U89 0. 7 G96 2.ooCl 17.127 11208 1 12272.8 121 230 29 11 7o 96 531 235 000 13.319 G 0750a 2.39+6 15.726 11533 ,0 12659.2 122 .89 2 29 1* 77 + + 51 J 2*0 000 12.573 0. Gf 95* 2. 1601 1*.6*7 11652 + 130+5.5 12* 519 29. 16 7o 88 4 9 + 2*5 000 11.870 G U3*25 1.9565 l*.*fco 12162 i» 13+26.1 12 3 089 29 16 7 5 22 + 82 250 000 11.223 03910 1.7823 1+.+73 12*59 8 13796. 3 127 56 5 29 19 72 7 5 + 7 + 255 000 10.c38 09*00 1.33+2 1+.723 127*3. 3 1+153.

3

123 99 9 29 20 y n C7 + c 9 260 .000 10.111 09890 1.5U78 15.056 13013 8 1 + + 3 f .* 130 335 29 21 o7 6 1 + 03 265 000 9.635 0. 10379 1.3989 15.*39 13272, 9 1+629.8 131 601 29 23 35 + 2 + 6 + 270 000 9.2C3 108o5 1. 30*3 15.659 13522 G 15151.9 132 80 6 29 26 o3 + -63 275 .000 6.811 11350 1.221* 16.329 13762 2 15*o*.7 133 95 3 29 31 3l 67 + 6 5 280 JQO e.+5* 11829 1. 1*65 lb. 67+ 1399* + 15758.3 135 0*9 29 3 6 39 <?3 ".'3 + 285 000 8. 129 12302 1.08*1 17. +87 1 + 219 c 1606*.

a

13o ,097 29 *3 58 + 2 -ci 290 .000 7.833 G 12767 1. 02t9 18.1*+ 1**36 2 1-.333.2 137 131 29 52 56 93 + o7 295 .000 7.562 1322* 0.9758 l6.62o l + t51 3 loo3*.9 136 Go* 29 61 5 5 71 + 7. 300 J00 7.313 156 7 + 0.93GO 19.519 1 + 859 5 1=910.6 138 990 29 72 5* 5 3 + 7 5 310 OuO 6. o?o G 1*550 0. 3512 2 0.91* 1526* 2 1 **+ t, .0 1+0 7 + 8 29 9 8 52 71 + 7 9 320 ouo o. *9* 1539d 0. 7657 22.302 15656 179o6.2 1*2 393 30 26 51 28 h6j 330 .000 6.165 16221 0. 73G* 23.673 160*0 2 16+7 3.

3

1*3 95 8 30 o2 50 19 432 3*0 J00 5.875 17022 . o831 25.023 lb+17. 1897C. 9 1 + 5 *+* 31 OP + 9 37 + 9o 35J 000 5.617 1780* C.o+21 ?o.350 16790 8 19+61.+ l+o 866 31 + o .8 7 6 50 3 3o J ouo 5. 386 135o8 0. 6061 27.652 17161 6 199+6.7 1+8 233 31 84 + 3 3 5 1 2 37J 000 5.177 13316 U . 57 ** 2 6.931 17531 1 20+2 6.5 1 + 9 553 32 30 + 6 + 516

383 000 *. 988 2J050 . 5+61 3G.167 17900 5 20907.9 150 632 32 7ti + 7 o

y 52*

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1

15 3 26 + 33 78 '+7 h 3 635

»*20 000 *.S7 3 22869 0.+582 3*. 989 19391 5 22821.8 15 5 o2G 3 + 83 +.8 01 5*3

* + JOO + .129 2 + 222 G. + 2*8 37.273 2G152 5 23785.6 157 ",6 2 3 5 91 + 8 + 1 5 = 3 HO .000 3.915 255*5 0.396+ 39.*88 2G927 5 2*759.3 160 026 37 01 + 8 9o 57L *83 .000 3.725 268*3 0. 3719 +1.0** 21718 3 257+4.8 162 12 3 38 12 + 9 t J 58 1 50U .000 3.556 23120 G.35b5 *3.7*7 22525 9 2o7+3.9 16 + 162 39 21 5 32 5 92

183
ME1'HANE ISO 3AS. AT P = 160.3 BA R

T DEN VOL OP/DT OP/DO E H S CM C° W OEG K MOL/L L/MOL 6AK/K BAR-L/MOL J/MOL J/MOL J/HOL/K J/MOl /K J/10L/K 1/SEJ

9*. 709 26. *5E 0. 0351* 20. 233b 269. 8*5 3527. 7 +090.0 68. 53 6 3*. 26 52. 01 1593

*5 . 000 28. -.25 0. 03518 20. 1617 266. *40 3 6**. +10o.9 66. 7+C 3*. 2* 32. 3 1593

1 JO 000 2b. 01.7 0. 3565 19. 0738 252 7*0 3790. 1 +360.5 71. +2 3 31., 32 52. t2 155 + lu5

.

000 27.666 0. 0361* 18. 0379 237. 0** 1.0*1. 9 *o2 0.2 7-,. 006 3*. *C 53. 23 1512

llu 000 27.^85 0. 03b65 17. 052* 221 582 *296. 2 *dd* .0 75. +9* 3*. 3* 33 73 1 + 7 j 115. QUO 26.896 0. 03718 lb. 11+2 206. 517 4557. 5 515 2.3 73. 891 3*. 10 5 +

.

C9 1 + 29 120. 000 2o.bG;, 0. 03773 15.22G2 191 96* *fcld. 7 5*22.* 81, 199 33. 75 5 + . 36 1383

123. OuO 26. 106 0. 03831 1*. 3b71 178 000 5081. 3 5o9*.3 63, *23 33. 35 5* 62 1343

130. 000 25.o97 0. 05891 13.3517 16* 670 63*5 . 2 5967.9 83. 571 SZ. 39 5 + 93 13 07 135 000 25.282 0. 05955 12.7713 151 999 3610. 7 62 + 3. 87 65 3 32. 73 a * U 12fco 1*0 000 2*.o5/ 0. 0*023 12.0233 139 991 5878. 2 6521.9 89. 677 32, 37 5 5 97 1223

It 5 JCO 2*. -.22 0. + 095 11. 3056 128 635 61*6 2 680 3.+ 91 65 3 32. *fa 5b 62 113 5 150 000 23.978 0. + 171 10.6163 11/ 912 6 + 2J. 6 703c. 1 95, 633 32. 33 5/ 27 11 + 1 155 000 23.522 0. + 251 9.9 3 38 1C7 79* 6,695 8 737c. 95 *71 32. 08 37 65 11 Jl 160, 000 23.05* 0, 0+33d 9. 3169 96 26 + 6 972. 2 'co6.2 97, 313 31. 62 33 22 1jo2

lo5 000 22. 573 0. 0**30 8.704* 89 2£* 72*9. 1 7957.9 93. 108 50. 9* 33. + 3 1023

170 OuO 22.079 0. + 529 8.1153 80 8 Jl 7525 7 325G.3 100, 855 30. 16 58 59 93 ) 175 000 21.563 G. G + 63o 7.5*91 72 di-9 7bo2 c 45++ .

1C2 55/ 3C. 32 39 *5 9*1 ldj 000 21.0*2 G. 0+752 7.0062 65 399 6083. 1 fi8*3.3 10*. 2*2 29. o9 D 2J 9u 1 185 JCO 20.*97 0. 0*879 c*63* 58 *50 S3oo. 1 91*6.7 105 903 29. + f 51 13 6b J 190 000 19.932 05017 5.9838 52 010 6652 3 9 + 55. 107 5*8 29 30 32 ZZ 83j 195 000 19.3*5 0, 05169 5. 501.8 *6 090 89*2. 2 97o9.2 10 9 160 29. 19 53 C7 79J 200 000 18. 737 05537 5. 0:>30 1.0 70* 923o 1CQ90.0 110 80* 2° 13 5 + 60 n?

2 05 000 18. 10* o. 0552* *. 623* 35 86 + 963* 3 10*18.0 112 *2 + 29 10 ob 33 71* 210 .000 l/.**0 0, 5 7 31 *. 2191 31 3/7 9636 9 1C75*. 1 1 + 0*3 29 11 58 b 1 673

215 OOJ 16.769 5 9o* 3. 3*19 27 8*2 101** 11098.1 115 60 2 29 15 •j 9 b7 6 * 22u 000 16. 065 0j225 3.*d98 2* .61.6 101-5* 9 11*50.0 117 283 29. OC 71 09 61 + 225 000 15.355 0o513 3. 1662 21 981 1L767 6 11609.7 115 897 2b 98 /2 61 563 230 000 l*.o52 j83* 2.6/03 19 62 + HCel 7 1217 5.2 120 60 3 29 7 3 t-5 30 u 235 000 13.911 07189 2.6022 18 .IcO 11395 2 1 25+6.+ 122 096 29 03 7 + 3? 53-) 2*0 000 13.203 0. 0757* 2.3ol9 16 .970 11705 5 12917.3 123 66 2 2" 07 7 ^ 53 52 j 2*5 000 12.523 07985 2. 1+91 lo .231 1 2 -J 7 1523 t .

3

125 188 29 1 1 73 .53 5 j > 2=0 000 11. 083 03*15 1. 9o29 15 90o 12305 1 1 365 1 .6 126 659 29 1* 72 C2 - 3

.

2 5 5 000 11.291 0, 03853 1 .dul9 15 .932 12669 6 lniiJt.b 12o C66 29 17 j 5 95 *1! 2o0 000 10.752 ,09501 1.6632 It .171 128o2 ,5 1 - 3 5 Q . 6 129 + 01 29 20 o7 67 + 3 i 265 000 lu. 261 o. 097 + 5 1 .5*33 lo .i.9o 1312* 3 1*683.6 130 6/0 29 2 + 55 63 + OJ 2/0 ouo 9. 815 G 15139 1.1.389 16 d6 + 1537o 5 1 5 . 7 131 876 29 29 o5 7 J -

' j 275 .000 9.*0o 13631 1. 3*73 17 ,2tb 13620 C 15 320.9 135 031 29 3 + o2 .02 -V

2d0 .000 9.033 0. 11071 1. 2o65 17 7C3 13855 9 16o27.2 13 + 135 29 + 1 >Q 6 J + 7 3 265 .OuO 8.69U L15J7 1. 19*6 Id 192 1*C6* 9 15 92 6.

1

135 19 3 29 + 9 ^9 i -.7 r 290 000 8.375 119*0 1. 13C6 16 ,7*5 11-307 9 lc218.2 15o 20 9 29 58 57 j

• + 73

2 + 5 .000 d. 06o l?3o7 1.0733 19 .361 1*525 3 1 6 5 j + . 137 ,186 29 68 5b . 3 + + 7 5 3J0 000 7.820 12738 1. U218 19 *9Q 1*737 7 16763.8 130 127 29 60 55 .*2 + 31 310 .000 T.ii*7 13611 u.9332 21 .318 15150 5 1752o.l 139 912 30 06 5 3

i 3 +86

320 .000 6.939 1**11 0. 8597 22 .o66 15 6*9 9 l?d55.6 1 + 1 587 3C 36 3 2 i *92 330 .000 o. 5d* 15137 0. 7970 2* ,009 15939 .9 183o9.9 1+5 170 30 71 3 .69 »91

3 + d 000 6.272 159** 0. 7**9 25 339 lb323 1 1637*. 2 1* + b75 31 08 5 1 50 + 3a0 .000 5.99* lo633 0.b991 2b .661 lt7ul 6 19370. 3 1 + b 115 51 + 9 + 9 5 j 6 1 J 360 .000 5. 7*5 G 17*05 0.6591 27 9L6 17C77 1 19861.9 1 + 7 *9 8 31 93 + 3 51 j 370 .000 5.521 .16112 0.6238 29 .218 171-51 .0 223+9.0 1 + 3 ,83 3 32 38 + 8 3 5 5? 5 380 000 5.317 13606 0.6925 30 .*70 1762* * 20833. * 150 12 + 32 86 + 8 .3* 5Zri 390 .000 5. 151 G 1 )*38 0. 5b** 31 .702 18198 1 21316.2 151 579 33 55 + 6 2 + 5 3 5 *u o . JOO *. 9c 1 20159 0.5350 32 .91 + 18672 9 21798.* 162 59 9 33 66 + .21 3 + - *20 .000 *.657 u .21*71 0.+962 35 .280 19328 . 5 227o3. 8 15 + 9s5 3* 91 + 8 37 5 5_' f"*0 000 *. 396 .227*9 U.*585 37 .573 2U09* ,7 2375+.6 16/ 212 36 99 + 8 . 73 553 *60 .300 *.167 2 3 999 0.*275 3 9 .801 2C67 + * 2+71*. 1 159 390 37 09 + 9 2- 3/-

*80 .OuO 3.96 5 .2522* u . *C Oi. 1.1 .969 21669 2 25703.0 161 *9 6 30 19 + 9 .85 30 + 500 .000 3.78- .25*28 0.3770 * + .08* 22*80 5 267J8.9 163 5*7 39 29 50 55 5 + 3

184
METHANE IS03AK AT P = = 170.0 BArt

T OEN VOL DP/DT OP/013 £ H S CV CP A OEG K MOL/L L/MOL BArt/K 8AR-L/M0L J/MOL J/MOL J/'ICL/K J/MOL/K J/10-./< '1/S£C 9+.956 28.1,73 G,,05512 20.2052 270.961 3631,,7 -128,,7 63.,599 34..33 51. 93 1593 95.300 28. 4bG 0., 03514 2 0.1 65 270.335 3535,,9 -133,,2 63., 04 7 34,,32 52.,01 1595

loo. ooo 28. 08b 0. 03550 19. 1087 254.843 3781,,3 4386,.6 71,,328 34,,40 oZ. 5o 153 5 105.300 27. 71C 0.,03609 16. 08C2 239.322 4C32,,4 46-6 , ,9 7 3.,907 34, -7 53. 15 1517 110.000 27. 33b 0.. 5o59 17. 1014 224.004 4287 , ,9 -339,.9 76.,391 34, -1 53. 63 147? 113.000 26. 9*6 0,,01711 16. 169b 209.061 4546,,3 5177,.1 73,,78- 34. 17 5 3. 58 143 J 120. OuO 26.556 0. 03 76o 15. 2819 194.610 4806,, 5 544 6,1

6

81,, 036 33. 32 54. 2 3 1335 125.000 26. 161 0,,05823 14. 4348 18 0.7 33 5068,, 5717,.3 83,, 335 33,,-2 JH . 43 1 3 5 5 130.000 25. 758 0.. 05832 13.6254 167.479 5333,,7 5^90,,7 60,,44 7 33, 06 5-. 73 1313 135.000 25.347 0.,0394 5 12.851G 15-. 87 5 569-,,8 626 5

,

, 5 8/. 523 32.,80 55. 21 1275

143. 300 24.928 0., 0+012 12. 1091 142.927 5863,,8 6542,.8 39,,540 32.,o3 55, 'to 1254 145.000 24.499 0. + 082 11.3975 131. o28 6129,,2 662 3,,1 91.,507 32.,53 56. 3 7 1192 150.300 24. Obi 0,,0+155 10. 7145 120.969 6433,, 713b,• 5 93,,428 32,,-0 5 6

.

, 9 9 1152 155.000 23.013 0.,0+235 10. 0584 110.895 o672. 9 7 3 9 2.,9 95. 33 6 32. 14 57. 6 3 1112 163.300 23.154 0,, 04319 9. 4281 101.409 6947,, 1 7631,.3 97., 137 31,,08 yi 6 . 107-

loS. 300 22.683 0. 0-409 6.6224 92.-72 7221., 5 7971.> 93. 92: 31. OC 37. 9 3 1 J3o 170.000 22.200 0., + 505 O.2405 8-. 062 7495,,3 82ol,.1 103,,652 30.,21 ^B,,G -i 10b- 175.000 21.703 u + 638 7. 661c, 7o. 161 7769., 1 655 2., 4 102. 338 30. 07 56. 6 6 9 b- 180. 000 21. 191 0., 04719 7. 1452 6o.?56 804&,, G 3848,,2 10-.,035 29..73 59. 6 J 92o 165.000 20.663 0.,0+6+0 6.o312 6 1. 344 8325,,0 91-7,,7 103,,e-6 29..49 oG. 3 3 036 l^O.OOO 20. 116 G. + 971 6. 1395 55.-27 06O6, c 9-51,, 5 107.,266 29,,32 61,,2- 853 195. 00 19.555 c 0511 + 5. b/b3 45.313 6691,, 3 976 0,,3 133,,671 25.,20 32,,31 612 200. OuO 18.973 0., 05271 o. 2241 44.112 9173,,8 13074,,6 110.,45 3 25. 12 j 3..53 7 7-t 205.300 16.371 0., 054+3 4. 6016 39.232 9470 ., 1 103:15,.5 112., 046 29..38 ->4. 7 5 733 210.300 17.749 0., 05634 4.-335 3-. 377 97c-,,9 10722, 7 113,,62- 29.,36 06,, 1- 70 5 215.003 17. 109 0. U5645 4. b3b5 31. 0-7 10 06 3,,3 11056,.9 115.,196 29. 10 •3 7,,53 6 73 220.000 lo.45 2 0.,0j078 3.6632 27.730 lu364,,7 11398,, lib.,765 26.,93 o3,,e 9 b-1 225.000 15.782 0. U633o 3. 3619 2-. 913 1 bbo7 , ,3 117.4,, 5 113.,32 2 2o,,90 o3. 69 ol J 233.303 16.10- c., 0!>o2i 3. Let 5 22.57c lb 971,,1 12096,16 119.,80 9 28. 91 /u. 91 6 3 7 235.300 14.426 0., j932 2. 7970 20.701 11274,, 7 12-53,.1 121,, 40 5 26.,95 7 1,,62 5-_5 2* 3 .300 13.75b G ., G'2o9 2. ?52y 19.26c 11576,,3 12812,.1 122., 91 4 20.,99 71,, 69 5- ., 245.000 13. 104 i, G

7 631 2. 3339 16.26b 11673,1 3 13171,.1 12-.,395 29.,34 7 1,,62 5 33 253. 000 12.481 o. 03012 2. 1353 17.o27 12165., 1 13527,,2 125,,83 4 29.,39 /3,,/o 51/

2 oo . 3 b 11.093 0,, 0-1403 1.9679 17.360 124-3,, 3 138/7.,7 127,,222 25, 13 o9,, 3 5 3 'J 3 260.303 11.340 G., 03812 1. 8162 1 7.394 12722,,1 1422 0,,1 123,,552 25,, ie 57., 5 5 5 31 265.303 10.646 0., J21o 1.6676 17.o23 12585,( g 1-553,.0 129,, 82 29.,2- 56,, L - -9" 270.300 10. 390 G. C9623 1. 6739 17.940 13243,,4 1487o,,6 131,,030 29,,30 5 3.,84 4 3-

2 75.3 00 9.969 0., 13031 1.4/38 16.299 13486,, - 15191,.7 132., 186 29, 37 52.,21 4 5 2 283.300 9.563 C.,13435 1. 3o63 I8.066 13725,, 1549-5,.1 135,,294 29,,-4 63,, 7 6 -5* 285.000 9.227 0,,13838 1.30C5 19.105 13957,.0 15799,»

5

13-.,35 7 25. 53 5

.

- - 43: 293. 000 8. c98 0. 11238 1.2360 1

5

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3 '0.000 6.bb4 0,,15097 0. ou82 25.731 16230,1 5 1 3761,.7 143,,9-8 31.,16 5 b

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6

150,. 72 33,.44 48,, 66 63 i (tdo.oao 5.263 0.,11001 0.581U 33.247 ie504.,7 21734,,9 151,,951 33,,94 -3, ol 5-5 420. 300 4. 940 0.,232+5 0.5329 35.0 12 19266,. 1 22737..7 154,, 325 34,,95 -3,, 7 2 5?u

h -+0.000 4.b61 0,,21456 0.-»927 37.910 20C37,, 5 23o35,,0 15t>.,598 36..07 -9. b- 56/ 4oG. 30 4.417 0,,22639 0.4687 40.145 20821,. 7 245/0,,4 153,, 788 37,,16 -9,,52 37 7 "80.000 4.202 0,,25799 0.4294 4 2.522 21620,>6 25656 1

5

163,,90 7 38,,26 30,, 11 53o 500.000 4.010 0,,2+939 0.4039 44.44b 22435, 5 2667 5..2 162,,96 6 39,,36 5C,. 77 593

185
Mc rHftNE IS03AR 4T P = 18C .0 BAR

T OEN VOL OP/OT QP/DD E H S CV CP A OlG MOL/L L/MOL 8AR/K B4R-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/ -10. /K i/se:

95. 202 26.*92 0. 03510 20. 1771 272.066 3535. 7 +lo7.5 68. 6*2 3*. *1 51 9j 160J

100. 000 28.125 0. 555b 19. 1*26 25o.91b .3772. 7 **12.7 71. 233 3*. *7 32. 5 J 15o2

105. 000 27. 751 0. 03603 18. 1215 2*1.569 * 2 3 . 1 *671.7 73. 609 3*. 3* a. ild 1521

110. 000 27.37s 0. G3o53 17. 1*9 + 22b. 398 *277. 7 -935.3 7o. 290 3*. *8 53. 55 1 + 6 113. 000 26.99* 0. 05705 lo. 22*0 211.576 *635. 2 52J2.0 76. o76 3*. 2 + 33 o3 1*+ J 120. 000 26.b07 0. Ji75e 15. 3*23 197.228 + 79*. 5 5*71.0 80. 976 33. 89 5 * 1 1 1*01

125. 000 26.213 0. 05B15 1*. 5011 183. +38 505*. 9 57*1.5 8 5, 189 33. *9 5 * 3 + 136 2 130. JQQ 25.617 05873 13 697b 17U.259 5316. * b013.6 85. 326 33. 13 5* 63 1323

135. J00 25.*11 05935 12. 9290 157.720 5579 2 6287 .6 87 39 5 32. 87 55 03 1233

1*1) 000 2*. 997 0. G + uJl 12. 1929 1*5.331 5 8+3. 9 63o * • 69. + 05 32. 70 55 c ^ 12+5 1*5 000 2*. 37* c + 069 11. + o72 13*. 536 6110 7 66+3.1 91 36 + 32. 59 56 1- 12 J 2 150. 000 2*. 1*3 0. 0*1*2 10. Blul 123.968 6379. 3 7125.3 93 27 7 32, *6 56 72 11 j2 155 J00 23.702 0*219 Id 16C2 .113.95* 6650 8 7+1 0.2 95 1+5 32. 21 37 2J 1123

160. 000 23.251 0. + 331 9 5361 10+.317 6 922 9 7bJ7.1 9o. 9b 6 31. 7* 57 * i lOo j 165. 000 22. 790 0. C + 338 6 53i_7 93.630 7195 C "93*. 3 93 737 31. J5 57 59 10 51 17 J 000 22. 317 0. 04*31 8 3613 8 7.268 7*65 2 6272.3 100 *3 7 30 27 57 61 10 1 3 175 000 21.031 u + 581 7 8091 79. +12 7737 1 35o 1 . o 102 128 30 11 58 31 97 1 180 000 21. 333 + 638 7 279b 72.0*6 6C10 7 6o5*. 5 10 5 778 29 7b 58 67 -)* 2 165, ooo 20.621 + 833 6, 7726 63.168 8286 9150.5 103 *0 29. 5 3 59 5 7 905 190 000 20.293 0*928 2679 58.773 85b3 .3 9*5 0.3 107 000 29 35 3O 33 863 135 JOO 19.75u 071,63 5 6256 52.866 38*3 1 975*. 5 103 530 2 9 21 3l 3 1 3.3? 200. 000 19. 191 03211 5 366 1 * 7 . * 5 2 9125 b 1 U 6 3 . 6 110 1*5 29. 12 o2 32 ? J c 205 0G0 13.C15 0, 05372 * 9697 *2.538 9*10 9 1„377.9 1 1 L 6*7 29 07 o3 <-2 761 210 000 18. 023 055*8 * 37/0 38.125 9699 1 10o37.9 113 239 29 05 j * rd 72 7 215 000 17. *15 057 + 2 + 2065 3*. 213 9993 1 11023.7 11 + 772 29 06 3 5 7 5 ^i5 220 000 16. 79* c C5955 3 3b*e 30.791 10283 ,6 11355.* lie 29 8 26 38 O D . ; i £o; 225 000 16. 161 Obi 3 8 3 5*5* 27.8*3 10577 6 1 1691. b 117 63 6 26 3 + 37 73 63 i 230. 000 15.322 a Oo**2 3 ^507 2 5.356 10672 Q 12032.5 111 3u 7 28 3* 38 6 5 61 i 23s 000 l*.d»l 0o720 2 96C3 2 5 . 3 C 5 11167 9 12377.5 1?J 791 26 38 o9 .32 591 2*0 000 l*.2+6 07020 2 7337 21.671 11*61 b 12725.2 122 25 5 26. 92 39 73 571 2*5 .000 13.b22 073*1 2 5103 2o.*30 11752 5 13J73.9 123 693 28 38 69 7 J 55 ! 250 000 13. 019 07t81 2 3 96 19.56 12G38 9 13*2 1.5 123 u97 29 0* o9 2 5 5 ii 255 000 12.*** 03C3o 2 13 0* 19.0 32 12319 .2 137o5.7 12q +6 29. 10 58 ,37 52* 2o0 000 11.902 03*02 1 9717 16.81+ 12592 1 1+1J*.5 127 776 29 16 o7 ,0 9 51 > 2o5 JOO 11.397 0877* 1 3319 16.357 12856 7 l*+3b. 1 12 3 0*0 29 23 Pj r. t 3 13 270 000 10.930 031 + 9 1 7069 19.06u 13112 9 1*759.7 13u 2+9 2 9 30 33 8 i 5u i 275 JOO 1U.500 tiiZ.2-* 1 cl 05 19.389 13361 C 15075.2 131 + 7 29 3fl o2 3 + 5 j: 280 JOO 10. 103 09693 1 3u*5 19.7+0 13601 ,7 15333.3 132 518 29 *7 30 ,92 3U + 263 000 9. 737 1J27J 1 + 189 2U.119 1383a 15b3*.7 133 53* 29 57 5 9 t j 50 ( 2 9J 000 9.397 106 + 1 1 3*23 20.523 1*C6* .6 1593 0.0 13 + 612 29 o7 53 5 J 5o2 233 .000 9.u82 .11011 1 2733 2 0.9=3 1*267 ,9 1l2j9.9 135 60 3 29 79 37 *o 502 300 JOO 6.769 .11376 1 2109 21.*16 1*506 7 1655*. 8 13 j 5oC 29 91 56 50 5 u2 310 JOO 8.262 1213 + 1 1j29 22. +6+ 1*932 2 17110.9 138 SAh 3C 19 3 * 7j 30, 320 .000 7.60* 1281 + 1 0131 23.679 153++ 3 17b3l. 9 1*0 ,099 30 51 ?3 ,25 50 3 330 .000 7. -.03 ,15539 937 + 2 + . 9 3 137*5 9 16177. 3 1 + 1 719 30 86 52 u 3 512 3*0 .ooo 7.0*9 ,1*187 ,6729 £6.199 16139 6 13o33.+ 1*3 259 31 2* 51 1 . 3 1 ? 350 ,000 6.73 + 1 + 850 8172 27.+bb 16528 C 19201.0 1 + + 731 31 35 5 C

., 3 522

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i»oO .000 *. 663 .21*3o .+905 * 3.521 20769 7 2*626.2 153 217 37 2* + 9 79 53 1 *3J .000 *.*37 .22538 a .+587 +2.702 21572 »

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186
METHANE IS09AR AT P = 190.0 BAR

T OlN VOL OP/DT OP/DO £ H S CV CP •A OEO K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/.10L./< i/SEvJ

93,.,,8 28.510 0,,03506 20.1,92 273,.157 3539., 8 4206.,2 66.,685 34. 48 51. 93 1601

100..000 26. 164 0,, 03551 19.1/61 258,.957 3764,,3 4436,.9 71,, 140 34,,54 52. 4 . 15bo

Iu5 . .000 27.793 0,,0.i598 18.1620 243 ,787 4013,,9 ,697,,6 73,,712 34,,61 33..01 1523

110,,000 27.419 0,, 03 6,7 17.1964 228,,7b3 ,267,, 6 496 0,.7 76,,169 34,,55 53,,4o 1,33

115,. J00 27. 1)1.1 0.. 03698 16.2772 214,, 0b4 4524., 4 522 7.,0 76,,57 3 34,,31 63.,76 144 j 120,.000 26.038 0,,03751 13.4015 199,,619 ,782,,7 5495,, 4 80 , ,36/ 33, 95 54. 00 140 7 123 .000 2b. 270 0,, 03607 14.5661 186,,116 5C42,,1 57o5,,4 63,,075 33,,36 54 , ,21 136^

130,.000 25.c7p c,,0 366 5 13.7683 173,,011 5302,, 4 c 036,.7 85,,20 6 33. 20 54, 47 1339

135,.000 25.474 0,, 03926 13.0u63 160,.536 5564,,0 6309,,9 87,,269 32,,93 54,,'8 5 1291

1,0 , ,000 25. 065 0., 03990 12.2748 148,,7 04 5827,,3 6585,,3 a-i,,27 2 32. 77 5 5 . 3 3 1251

li*5,.000 24.C48 0,, 0,0^7 11.5747 137,,510 6092., 6 c6o3,, 5 91,,224 32,,66 55,.91 1211

130,.000 24.223 0,,0+128 10. 9034 12c,941 63o0,, 1 71,4., 3 93,, 129 32. 53 56. 4/ 1172

1p3,.000 23. 789 0,,0,204 10.2392 116,,974 o629,,4 7428 .0 94,,988 32.,27 5 . 91 113 + loJ , .000 23.3,6 0,, 0,283 9.64C9 107,,5 83 6899,,5 7713,,3 96,, 300 31,,3L 3/.. 15 10 53 lo5,,000 22. o93 0,, 0+3o6 9. C475 96, 740 7169,,4 7999,.4 96,,56 31,, 11 5 7

,

,21 1 Oo,

1/0,, JOO 22. ,29 0. 0,458 3. ,762 50..422 743d. 2 826 5,,3 10 9,,2o7 3C,,32 i7,, 18 1C31

1/3,.000 21.955 0,, 0+553 7.9322 82,,60/ 7706., 4 8371 .8 101,,926 30,, 16 5 7 , 61 995

130 , .000 21. ,69 ,, + 658 7. 40 96 75,,279 7977,, 38o2 , ,0 10 3,, 56 1 29,,32 58,,30 553

165,,000 2 0.970 0,, 0+7o9 6. 9082 66,,,25 8243,,9 9155,.0 105,, I06 29,,57 33,,9.) 922

190.. GoG 20. ,59 0. 0,83o b.,298 62.,054 6522,, 5 9,51,.2 lOo,,746 25,,37 59,,62 885

195,.000 19.934 0,, 0301/ 5.9737 5o,,153 6793,,1 9751,,3 103,, 305 29,,23 d3,, 42 851

2Jj.,u00 19. 39= 0, 0515b 5 . 5 " 50 . ,729 9C73.,9 10055,, 6 109,, 345 29. 14 61, 3 9 31d

205,,J00 18.042 0,,0530,' 5.1290 45..763 9356,,0 111 36,,.4 111,,371 29. 97 52,, 23 782

21j.,000 18. 27a 0. 05<+72 4.7411 41,,324 5o36,,5 10o/8,.2 112,,88 3 25.,04 3 3., 24 74 j 215,, JUJ 17.o95 0,,05 651 4. 37t6 37,,340 9923.,2 1099b.,9 11,,,383 29.,93 3 4 , , 2 -j 718

22u,,000 17.103 0,, 058,7 4. 0367 33,,826 10 209,,9 11320,,7 11 j,, 672 26,, 64 o5,, j 69 5 225,,000 16. 503 0., 05060 3.7184 30., 7^6 10496. 9 116,8..2 117., 343 28. 79 d5 92 6o3

230,.000 15.696 0,, 03291 3. 4244 26,,148 Ib764,, 6 119/9,,8 118,.801 28,,79 6b , 71 b33

235,, 000 15.206 0., 0j5,1 3. 1335 23,,947 11072,, 2 12315,, 1 12U,,24 3 28. 32 5^, 3 6 qIj

2t0,,000 1 4. 66

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,73 3 9, 2,5., 000 1,. U87 0. 07099 2 . b 7 8 b 22.,716 11643. 6 129 92., 4 123., 066 28,,93 67,,92 bit

250,,000 13.505 0., 0/404 2.4/32 21,,640 1192,,, g 13 331.,7 12,,,436 26,,99 _> 1 . ,7, 5ul

255,,000 12.945 ,,0 7 723 2.2oe2 20,,892 12201,, c. 1 3o-j9,,2 1?5,,77 3 29,,06 37. 2 9 34 j 2o0,,000 12.412 0,,03G57 2.1224 20,, ,45 12472,,3 1,00 3,,1 12/,, 070 29.,14 D C 1 ,32 339 2o5 . JOO 11.909 0,, 06397 1. 9746 20..269 1273b,,4 1,331

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,9 12o,, 323 29,,22 o3,, lb 531

2/0,, 000 11.438 0., u3?43 1

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8434 20,,322 12993,, 3 1,65 4

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275,, 000 11.001 0., 09090 1. 7271 20 , ,539 13242,,9 l49o9.,9 130,, C06 29,,39 32,,39 52 1 260,,0 00 10.397 0., 09437 1.62 37 20,,842 13465,, 4 15 2 7 8., 4 131..796 29. ,9 •jl. u3 5i 9 285,, 000 10.221 G,,09734 1.5315 21,,18o 13/21,, 6 15530,.5 132,,66 7 29.,59 5 9.,83 51/

290,,000 9.673 , ,19129 1. 4,88 21,,558 13952. 1 1587o,,6 133,,397 29,,71 1,6,.63 51;

295,,300 9.546 0,, 10 473 1. 3743 21,,951 14177,,6 16167,,, 13,,,892 25.,63 37,. c / 51,

30 J,,000 9.246 0., 1981b 1.3069 22,,366 14393. C 1645 3.,4 133., 85 3 29. 9b 36. 76 51,

310,, J 00 8.099 0., 11495 1.109/ 23,,262 14628.,7 1/012,,8 137.,667 30.,25 5 5 ,

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320,,000 8.220 0,, 12155 1. C918 24,,349 15245,,9 1 7537 , ,2 139.,41b 30..57 ?3.. 7b 51/

330,.000 7.799 0., 12822 1.0092 23,,521 156 52,, 5 18086,,6 141., 051 3 0. 9 3 52. 3 3 52J

3,0.,000 7. ,27 0. 13455 0.9367 26,,740 16051,,1 16609,,4 142.,606 31,, 31 51,, 6 .' 5 2 + 350,.000 7.095 0, 1,095 0. 6779 27.,975 lt4,3,,8 19121,,8 1 , ,

,

,091 31,.73 30,. 83 529

3o0,,000 6.797 0., 1,712 0.8249 29.,21C 16832,, 4 1962 7,,6 145,, 516 32, 16 50,,31 33 + 3/J,.000 6. j2g 0,,15317 0.7783 30, ,39 17213, 2 2 012 8,, 6 14u.. 839 3 2. 0? 4'5 • 9J 559 380 , .000 6.265 0,, 15912 . / 3 / 31,,658 17602,,7 2C626,,0 148,,215 33.,10 ,9.. 61 3,,

390,,000 6. 062 0., 1j497 0. /002 32,,865 17986,, 7 21121,,1 149,,50 1 33,,59 ,9, 4 3 5,9

1*00,, 000 5.856 G.,17 072 0. b671 34,,055 18371.,1 21bl4,,8 15 9,,751 34,,10 ,9,, 3 3 3 2, 420.,000 5.495 0. 16197 . 6 1 1 3b.,405 19143,,9 22601,,4 153,,158 35,,15 ,9,,0/ 5o-j 440,.000 5.183 0. 19 293 0.562/ 38..695 15 925,, 3 23591 , ,0 155,.46 3 6. 22 ,9, 6 2 3 75 460,.000 4.911 0. 29 361+ 0.5227 40.,930 20718,,3 24587,,5 157,,6/6 37, 31 30, b. 5oj

460,,000 4.670 0.,21413 .,863 43,,112 21525,,1 23593,,5 159,,815 38,,41 50. 63 595

50-0,, 000 4. 456 0. 22442 0. 4585 45,,246 22347,.1 2b61 1,.2 161,,89 2 39,,50 51,,2G 60 3

187
METHANE IS03A* AT P = 200.0 3A«

T DEN VOL DP/OT DP/DO E H S CV CP H 0£G K MOL/* L/MOL BAS/K BAR-L/MCL J/rlOL J/MOL J/1GL/K J/MOL/K J/HCk /< •t/SEC 95. o9* 23.528 0. 03505 20. 1215 27*, 236 36*3. 9 *2** 9 6b. 728 3*. 55 51, 91 1603

1JJ. JOO 28.^02 G. 035*o 19. 2086 260. 967 3/55. 9 **65 1 71. 0*7 3*. 61 52. 33 1563

105. 000 27.633 u. 03533 18.2U1S 2*5. 97o *00*. 9 *723 1* 73. 616 3*. 68 iZ. 9* 153J 110.000 27.1,62 0. 036*1 17. 2*25 231 099 *257. 9 *936 2 75. 09 3*. o2 53. 33 1*90 115.000 27. 087 0. G5632 16.3295 21o. 52* ,513. 7 5252 1 73. *7 3* 38 5 3

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b3 1*52

120. JOJ 26. 708 0. 037-*i* 15.*595 202. 382 *771. 1 5520 80. 759 3*. i2 i>3. 83 1*1-. 125.000 26.323 0. 03799 l*.o29b 168, 76o 5029. 5 5739 3 82. 9o3 33. i>2 5,. t 3 137o

1 JO .000 25.932 0. 0385O 13.8375 17 = 736 5288 8 605 G 8, 068 33 27 5* 33 1333 135.000 25.535 0. 0391c 13.08CO 163. 322 55*9. 2 6332 * 87. 1*5 33. JO 5*. t9 1293

1*0. JOG 25.131 0. J979 12.35*9 151 5*5 5611. 1 06O 7 89. 1*2 32 33 55 15 1260 1*5.000 2*.72u 0. 0*0*5 ll.b6C3 1*0 *02 6075. 633* 1 91 087 32. 72 55 70 1221 150.000 2<». 3C1 0. 0*115 10.99** 129 679 63*1. 71o* 92. 98* 32. 59 56 23 1132 155.000 23. 673 0. 0*189 10. 35S7 119 95 66G8. 5 7**6 3 9*. 835 32. 33 56 b. 11*5 160.000 23. ".37 0. 0*2o7 9. 7*29 110 oC7 6876. 8 7 73 C 1 9o. 637 31. 36 56 83 110 3 lo5.000 22.992 0. 0*3*9 9. 1551 101 606 71** c 801* 5 93 387 31. 16 5b 63 10 7 5 170.000 22.536 0. 0*1*37 8.591* 93 527 71,11 2 »236 6 100. 08* 30 37 36 73 10** 175.000 22.07". 0. 0*530 8. 0511 85 7*9 7676. 9 8532 9 101. 730 30. 21 i7 3d 1 J 7 130 .000 21.^99 0*630 7.5337 78 *55 79** 7 8870 7 103 351 29 36 57 77 Hf > 185.300 21.113 0. 0.73o 7 . 0387 7 1 o32 8213 6 91oG 9 10* 9*1 29. oO 58 31 93 3 19J.000 20.ol6 o. 0*651 6. 5b?9 65 275 3*83 8 9*53 ,9 13 '3 50* 29. *1 58 9 3 9j 3 195. 0U0 20.107 0. 0*973 o. 1153 59 l&u 8755 7 -)75C 3 103 0** 29. 26 59 6 3 30 9 200.000 19.586 0. 05106 5.0666 53 3*8 9029 3 lo050 »* 10 9 56 3 29 15 oU *J <5 205.000 19.053 0. 052*9 5.28G7 *a 979 930* 8 1C35* 5 11 1 C65 25, Jb ol 23 3 J 2 210.000 16.506 0, 051*03 *. 3H)71 u- *7* 9582 ? 10662 .8 112 550 2°. 0* 52. 9 77J 215.000 17.95 2 0. 05570 *.5361 *a *29 9861 * 10 9 7 5 * 11* 02 2 29 02 j 2 57 7Jd 220.000 17.387 0. 05752 *. 1978 36 83* 101*2 2 11232 .5 115 *ao 2P 32 o3 63 7 12 225.000 10.613 0, 5 9*3 3. 8822 3 3 678 10*23 llol2 5 llo 918 26. 76 6* 33 6 3 5 2 3 0.000 16.235 j 160 3.5891 30 .9*3 1070* 3 11936 .2 113 3*1 28 75 06 08 661 235.000 15.655 5 33 3 3. 3179 26 ol 1 10985 6 l?2o3 2 113 7*7 26 76 o5 b 7 5.3 J 2*0. 00U 15. 077 G 06633 3. uo82 2o 661 11266 1 12532 7 121. 135 2b 02 06 1 a c 17 2*5 . JbO 1*.505 Go 8 3* 2. 8392 25 072 115*5 12923 a 122. 5JC 2b 38 06 32 59:* 250.000 13.91*6 07171 2.o3C3 23 d22 11621 3 13255 ,5 12 5 8*0 28 95 3b 2 9 5 o i 255.000 13. *G3 c 07*61 2. **Co 22 886 1209* 1 353t .2 125 150 29 03 35 93 56* 260.000 12. 861 07763 2.2o92 22 21.2 123b2 .1 13 31* .8 12^ *2 6 29 12 o 5 ,0 f58 2o5.0U0 12. 381. 0. 01075 2. 11*9 21 36* 12t2* 7 1*239 a 127 bb* 29 21 0* 53 5* } 27J.00G 11.911* 03393 1.9767 21 725 12681 * 1*56 ,0 123 661 25 30 3 5 1 5*2 275.000 ll.i*7i. G 03715 1. 8o32 21 76a 13131 6 1*87* 13d 016 29 *C 52 J 2 557

2o J .0 00 11.061* c ,03039 1.7,28 22 0C1 13375 I, 15133 .1 131 128 29 5C ol C9 5 3 3 285. JOO 10. obi 03362 l.o**l 22 293 13613 2 15*35 .6 132 139 29 o2 5 3 90 55 j 290.000 10.325 36 95 1.5555 22 63b 138*5 3 15732 3 133 231 29 7* 5U 1

1

523 295. JOO 9.993 1JG07 l.*75o 2j .001 1*072 6 16073 .9 13* zn 29 87 57 6 5 jZI 300. JOO 9.b83 1J327 l.*031 2i jeb 11.295 3 163o0 7 135 192 3C OC 56 5, ?2± 310.000 9.121 1096* 1.2771 2* 21* 1*729 3 16 322 2 137 C33 3 30 5=; t*3 525 320.000 8.C.25 11595 1. 1715 25 1*6 15150 7 17*59 6 133 771 30 o3 5 * 11 52o 330.000 6. 16o . 1221o 1.0820 26 .210 15561 7 130J* 9 1*0 *18 3C 9 9 52 93 52*

i')J . Jul) 7.797 G 1282o 1.C055 27 360 15 96* 7 1652 9 ,9 1*1 586 31 38 iZ 5 HZ

350.000 7. i*i»9 13*25 u. 9355 26 .550 16361 , 5 190*c »

?

1*3 ,33 31 8G 5l 30 53j 360. OuO 7. 136 1*013 u. 0621 29 755 16753 9 19556 .5 1** 92 32 23 50 72 5* j 37u.000 o.85* 1*589 0.8316 30 .961 171*3 5 2C061 .* l*o 30 3 32 o9 50 23 5 , 5 3ao. uoo 6.k98 . 15156 0. i86 8 32 .162 17? 31 .3 2 562 .0 1*7 c*0 33 17 9 91 ',5 j 390. 000 o. 3o"* 1571* 0.7*70 33 .35* 1 7918 , c. 21061 .2 l*d 935 33 o7 *9 7 3 5 5*

".JO. 000 o. U9 , lo262 0.7112 3* . 536 18305 9 215 5 8 * 150 13, 3* 17 *9 67 Z? J 1*20.000 5.7b8 ,17336 .6*96 3b .865 1906* . 1 22551 ,3 152 616 35 22 *'J t7 »b 1 **0. JOO 5.**0 G , 13382 0.596* 39 . 1** 19 870 2 235*6 6 15* 931 3fc 29 *9 9 J 579

1*60.000 5. 15<* .13*0* 0.5553 *1 .S7Z 206o7 .5 2*5*8 .3 157 157 3? 38 5 2 3 53 ^ tdO. 000 i«.9ul ,2JhO* 0.5163 1*3 .552 21*73 ,2 25ap9 ,0 153 308 36 *e jC 8 599 500.000 i».676 .21337 0. *ofc3 *5 .o65 22303 7 26531 .0 161 39* 39 5t 5l -J 603

188
ME THANE ISOBAR AT P = 220. G BAR

T OEN VOL DP/DT OP/DD E H S CV CP H D£& K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/ -10L/K J/MOL/K J/'10i-/< M/SEG

96 183 28.565 03501 2G. 0669 27b. 353 3552 3 *322 5 66 815 34 69 51 87 160?

100 000 28.278 03536 19.2712 26*. 89* 3739 6 4517 5 70 86 3 34. 75 52 28 15 7o 105 .000 27.91* 03582 18.2782 250.265 3987 2 4775 3 73 427 3* 82 52 61 1533

110 JOO 27.5*8 03630 17.3320 235.689 *238 8 5037 * 7? 89* 34 75 53 23 15 3 3 115 000 27.178 03679 16.*309 221.363 4*93 .0 53JZ * 76 266 34. 51 53 6 1462

120 000 26.805 03731 15.5723 207. *29 47*8 6 55o9 3 6J 5*7 34 15 3 3 68 l*2o

125 000 26.*27 0373* 1*.7536 193.985 5005 i 5837 6 82 7*2 33 76 53 8* 1389

130 000 26. u** 3 8*0 13. 9719 181.100 5262 3 61J7 8 + 85 7 33 + 5* 05 1352

lis JOO 25.6&o J696 13.22*6 166.812 5520 ,* 6377 9 86 9J3 33 13 5* 3d 131 + 1*0 000 25.261 03959 12. 5101 157.1*2 5779 9 6o5 3 86 63 8 32. 96 5* 81 1 ? 7 o 1*5 000 2*. 06C 0*023 11.8257 1*6. u93 bO*l ,1 692

1

.1 9 82 12 35 55 31 1233

150 .0 00 2*.*51 0*090 11.1700 135. o5b o30* 1 72i}3 9 92 703 32 71 55 79 1231

1j5 000 2*. 03b + 160 10.5*15 125.313 6568 5 7VJ3 6 9 + 539 32. + 5 56 1 + 1165

lbO OGO 23.C13 0*235 9. 9o90 lit. 5*1 6633 3 7 76 5 9o 32* 31 97 56 29 1131

165 JOO 23. 183 0, 0*313 9. 3ol5 107.813 7097 4 6 J + 6 * 98 056 31 27 5b 23 109-J 170 JOO 22.7*3 0*397 8. 8081 99.b0+ 7359 9 3327 1 99 732 3C + 8 56 07 1Gb i 1/5 000 22.29y 0**35 8.278C 91.892 7621 .1 86J 7 7 101 356 3G 31 56 65 103-

180. 000 21.6** 0. + 578 7.77G8 8*.b65 786* 3891 2 102 953 29. 95 5b 8o 1331

166. 000 21.361 0. + 677 7.2859 77.879 61*7 5 317b 5 1C + 516 29 ob 57 27 966 190 ouo 20. 9GS + 783 b.6230 71.553 8*11 8 9 + 04 106 050 29 *7 5 7 7 j 93j

195. 000 20. *27 o. 0*895 6. 3618 65.67G 8677 1 9754 1 10 7 55 7 29 31 58 33 932

200 000 19.937 3 1 D 5.9o2* 60.226 89*3 5 100*7 109 0*0 29 19 5 8 8 3 67 j 205 000 19.*37 0. 05 1*5 5 . 5o*4 55.217 9211 2 103 + 3 1 11 3 502 29 10 5 9 53 3 3 9 210 000 16. 929 c 05233 5. lBfO 50.o*l 9*80 2 1 06+ 2 * 111 9*5 29 05 6 u 2 3 din

215. JOO 18. *13 03*31 *.6331 *c.*93 9750 3 10 9 + 6 1 113 3u9 29 31 oO 67 7iJ 220 000 17. 69G C559J *. *99* * 2 . 7 e * 10021 * 11251 1 11* 776 26 79 51 3 + 75*

225 JOO 17.3bl 0. 057ou *.1870 39.**3 1G292 u 11659 2 Ho 161 26, 73 jl 90 723 230 000 lb. 829 0. 059+2 3. 6953 3b. 515 10562 9 lie/ 1 117 528 2e 70 o2 *5 70- Z35 000 lo.295 0^157 3.o2*0 3 3.965 10833 6 12133 6 118 376 28 72 o2 9 + 63 1 2*0 JuO 15.763 053-* 3. 3725 31.772 11103 7 12*99 + 12J ?06 28 76 33 3 + 6o j 2*5 JOG 15.235 0. C556* -5.1*01 29.917 11372 6 1281c 8 121 515 28 62 6.3 .61 6 + 2 250 JOO 1*. 715 0. G6796 2. 9260 28.380 116*0 1 1313 6 2 122 601 28. 90 o3 7 3 o2j 255 JJO 1*. 205 070+0 2.729* 27.139 11905 1 1 3-*S3 3 12 + Go3 26 99 o3 bo 613 230 JOO 13.71Q 0. 07 29* 2.5*96 2 o . 1 7 3 12167 13 7 71 7 125 238 29 08 63 *4 5^-7 2b5 000 13.232 07557 2.3857 2 5 .*t2 12*25. 2 1*087 9 126 502 29. 18 o3 02 5 35 270. ouo 12.77* 07829 2.2366 2*.963 12679 3 1**0 1 6 127 676 29. 29 o2 43 67 o 275 JOO 12. 337 0310b 2.101* 2*. ('15 12923 7 1^711 9 123 31 + 29 + 1 ol t 9 5o J 260 000 11.92* G G3337 1.S791 2 *. 6 36 13173 2 15018 2 12 3 916 29 53 o Q 84 5c 2 28? UUO 11.53* c. 367 1. 8c65 2*. 719 13*12 7 15320 1 130 96c 29. 5 5 5 j 91 563 290 000 li.lbe 3 95* 1.7685 2*. 927 136*7. 3 15617 3 132 020 29 7 8 58 9o 555

2 95 JJO 10.62* 03239 l.o/BO 25.21* 13677 3 1 5935 3 13 3 02 J 29 92 58 0* 5 -j 1 300 OOJ 10.5G2 0, C3522 1. 5958 25.5*3 1*102 9 16197 8 133. 938 30. 07 5 7 19 63 J 310 JOO 9-91* o. 10037 1. *526 2b. 269 1*5*3. 167b2. 2 135 S39 30 39 ? 5 72 6*3

320 JJJ 9.392 0, 136*7 1.3321 27.061 1*970 8 17313 2 137 568 3 73 5 + 52 5*.' 330 JOO 8.92b 0. 11203 1.229b 27.917 15388 7 17353 3 139 250 3 1. 10 ?3. 5 + 3*7

3*0. JOO 8.509 0, 11752 1. 1*15 28. 8t9 16798 8 1833* * 1* J. 836 31. 50 52 7 3 5*9

35U. JOO 8.13* 12295 1.0652 29.918 16202 9 1890 7 7 1*2 35 3 31. 93 51 9 9 55

1

360. 000 7.795 0. 1?629 G.9987 31.027 16t02 3 19*2* 6 1*3. 839 32. 37 51 + 1 5 5 + 37 i 000 7.*8o 13->5* 0.9*02 32.167 16993 c 1993b * 1*5 212 32, 63 50 97 55 3 380. 000 7.209 0. 13871 J. 8885 33.319 17392 7 20*-* 3 1*6- 566 33. 31 50. C4 5o2

3 90 000 6.95* 0. 1+380 3. 6*23 3*.*73 17785 8 209*9 5 1*7 876 3 3. 81 50 *1 5tj) *00. 000 b.720 1+882 0. 8G10 35.o2* 18178 8 21*52. 8 1*9. 153 34. 32 50. 27 5 73 *20 000 6.303 1586* J. 73G0 37.905 18967 2 22*57 3 151 60 3 35. 36 50 22 57 9 **u JOO 5. 5*5 16822 0.6711 -*G.151 19762 5 23+o3, 3 153 9*3 36. ** 5 G « 4 9 586 *60 JOO 5.632 0. 17757 0.6216 *2.356 2o568 2-*7* 6 l5o 191 37 52 ? 7 j ;<9j ^AO 000 5.35a o. 13b73 0.3792 **. 520 21366. 25*9* 2 153 3o0 38. ol 51 23 60 7 5 0. JOO 5. 109 13573 0.5*27 *6 • o** 22213 3 2652* 2 16 J 1.6 3 39. 70 51 7 9 i 1 -

189
METHANE IS03AR 4T P = 240.0 BAR

T DEN VOL DP/DT OP/DD E H S CV CF W OEG K MOL/L L/M3L BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOl/< 1/SlC

9d 670 28.601 05496 2U. 0133 278 419 3660 8 4400.0 63 902 34 33 51 83 1607

100 QUO 28.353 03527 19. 3308 268 695 3723 7 +570.1 70 683 3 + 88 52 10 1583

105 000 27.993 0, 03572 13.3516 25 + + 33 3970 4d27.4 73 241 34 95 i>2 63 164C

110 .000 27.C32 03619 17. +180 2 + lo9 4220 2 5 3 8.8 75 702 34 38 53 03 1509

115 .000 27.268 3 bo 7 16.528o 226 095 4472 9 5353.0 73 068 34 6 4 53 33 147 i 120 000 2b. 900 03717 15.6810 212 371 472b 9 5619.0 80 34 1 34 28 53 43 1 + 57 125 .000 26.529 037o4 14. 8727 199 1C2 4981 5 5806.2 82 .527 33 38 53 .b2 1 + 01 130 000 26. 153 0. C332t 14. 1012 18o 3bl 6235 8 6I3+.4 8 + b3 3 33 52 53 80 1303

135 .000 25-/72 03830 13. 3640 174 196 6492 6 6424. 86 6b 6 3 3 25 54 .03 1323

i*»a ouo 25. 386 03939 12.6590 162 629 3750 cd 35 . + 08 6:43 33 08 5 + 4 J 1292

145 .000 24.994 0+031 11.9642 151 ,o£9 tG08 .6 c9;>9.u 90 ,5o3 i2 97 5- 95 126 3 150 000 24.596 0. O4O66 11.3379 141 311 6269 1 72+4.9 92 43 3 32 33 55 33 121 i 155 .000 24. 191 + 13 + 10.7188 131 540 6530 6 7522.7 94 25 5 32 56 5 5 69 118 + 160 ouo 23.781 0*205 10. 1256 122 335 6792 3 780 1.5 9 b C25 3? 8 55 7 9 1152

165 ,000 23.364 0-280 9.5573 113 670 7053 1 8030. 3 97 74 31 38 35 67 1121

170 000 22.94u 04359 9. 0129 105 .621 1 311 ,9 8358. 1 9:) 399 30 58 55 45 1092

175 000 22. 510 0. + 443 8.4919 97 8t2 7569 1 3635.3 101 004 30 + i6 85 105 + 180 .000 22.072 + 531 7. 9936 90 b7 + 7827 .6 3915.1 102 .680 3C 04 3D .03 1027 135 ouo 21.&28 o. + b24 7. 5172 83 937 6086. b 9196.2 10 + 121 29 76 36 39 993 190 .000 21. 177 04722 7. Ob 26 77 638 8345 8 9+79.1 10 5 62°. 29 55 5 u 77 9b + 195 000 20. 716 0. + 827 b.b295 71 766 6605 6 976+. 107 109 29 38 57 20 9 55 200 000 20.253 + 938 6.217+ 66 .314 8666 1 10051.2 1C3 5b 3 29 24 5 7 b7 90 3 205 300 19. 781 o. 05055 5. 82b3 61 274 9127 4 103+0.7 10 + 99 3 29 15 38 17 875 210 000 19.302 05131 5. 4338 56 d43 9389 5 10632.9 111 40 1 29 07 58 6 9 5 + + 215 000 18. 818 0531 + 5. 1058 52 413 9652 3 10927.7 112 73 + 29 03 59 23 313 220 .000 Id. 32b 0, 0543b +.776 1 48 576 9915. 7 112?5.2 11 + 157 28 80 59 55 791 225 000 17.035 0. 05b37 + . 4b63 43 .123 1U178 4 ii52«t.a 113 500 28 72 59 9 9 767 230 000 17.339 0. 05757 4. 17 tl 42 040 10 440 9 11325. 1 116 823 26 69 jf + 2 7+ 5 235 000 Id. 842 059 57 3.9G49 39 313 1 C7G3 2 12120.2 113 127 2b 69 !>G 81 721 2*0 000 16. 346 OollS 3.6523 36 92 + 10 965 12433.2 11 i 411 28 73 3l 13 7 U J 2t5 .000 15.654 03303 3.4174 34 356 11226 12739.8 120 c/o 28 79 Dl 43 631 230 000 16. o67 u->5J8 3. 1997 33 089 11485 6 130+7.6 121 919 28 37 Jl 6? cc2 = 5 ouo 14.008 0, 0b717 2. 9984 31 605 11743 8 13333.9 123 1+0 28 9b 1 ts t-1 263 300 1h.-19 0. 06935 2.3127 30 386 11999 7 13bo4.2 124 337 29. 06 ol 62 63 + 2o5 ,000 13.963 0. 071o2 2.o418 29 411 12253 13971.9 12 5 509 29 17 61 42 621 270 000 13.521 0, 7 39b 2. +048 28 061 12503 2 14278.2 126 65 5 29 29 5 1 10 611 275 000 13. b9b 0, 0763b 2.3410 2o 117 12750 1 1-552.7 127 772 29 + 1 oC DO 601 2d0 000 12. t89 o. 07631 2. 2094 2 7 762 12993. 3 1483+ .

7

123 3b 29 54 3 u 12 643 265 000 12.301 0. U3130 2. 0892 27 578 13232 b 13133.7 129 919 29 63 39 43 58.' 2 90 000 11.932 0. 03331 1.9795 27 347 131.63 15+79.5 130 9+8 29. 32 > 3. fc 1 582 295 000 11.582 0. 0365 + 1.07 94 27 o47 13699 5 16771.7 131 9+7 29 97 3« 07 573

3u0 000 11. 252 o. C3638 1.7881 27 063 13927 1 16060.2 132. 916 3U 13 ;7. 33 573 310 000 1U . D45 0. 4394 1.6281 28 + 5- 14371 9 16626.4 13 + 773 3C + 6 55 95 571 320 000 10. 104 0, 9 697 1.4933 29 162 14804 6 1717 9.9 13d 631 3 82 v4 7 3 5bo 330 000 9.618 0, 13397 1. 37 62 29 926 16227. 7 17722.9 138. 20 2 31. 21 53 fc3 667

340 000 9. 101 0. 10692 1.2791 30 743 15643. 2 1625 7.4 13 J. 797 31 ol 53 18 56 7 350 000 8. 784 0. 1133 + 1. 1929 31 bl8 Ic052. 5 1S785.0 1+1 32 7 32 04 52 4o 360

360, 000 8.425 0. 11670 1. 1175 32 575 16468 1 1930 6.9 142 797 32. + 9 51. 9 + 5 7 370 000 8.097 0. 12350 1. 0611 33 o04 16660. 19824. 1 14 + . 214 32. 96 5 1, 62 572

330 000 7.798 0. 12824 0.9922 34 678 17259. 7 20337.5 145. 58 3 33. 45 31 1 3 573 390 000 7.524 0, 13291 0. 9598 36 776 176.68. 2 20846.2 14o 910 33. 94 50 95 57 ( 400 000 7.272 0. 15 762 0.8928 36. 882 18C56. 3 21356.9 143. 198 34. + 5 50 81 5 32 420 000 6.023 0. l + 65b 0. 3121 39 099 16654 2 22371. 150 6/3 36 50 50 72 59U 440 .000 6.436 u 13533 0. 7+53 41 298 19658 23337.0 153. 035 36. 57 50. 86 698 h60 ouo 6.096 0, lb400 0.6892 43 466 2U471 3 24+07.2 155 302 37, ob 5 1 13 bG.' 400 000 5.799 172 + + .0+13 45 6 0b 21296 + 25+34.9 157. 489 36. 75 51 62 615 50J 000 5. 533 o. ld073 0.6000 47 709 22135 26472.6 15 9 c07 39. 83 52. 15 o24

190
METHANE ISOBAR AT P = 2o0.0 BAR

T OEN VOL DP/DT OP/DD E H S CV CP U DEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC 97.156 2 3.63 7 Oi, 05*92 19.96G7 280. *32 3569,,6 •,*r7.5 63.,990 34. 97 51.,80 1609 100.000 28. +27 0. 05513 19.367* 272.371 3708. 2 4622.8 70. 505 35. 01 id. 3 1583 105.000 28.071 0,, 3*562 18.4219 258.49* 3953..3 4879.5 73.,059 35. 08 52. 63 155 + 110.000 27. 71* 0.i0i608 17.5007 2**. 537 4202.,2 51*0.4 75. 514 36. 01 52. 95 1513 115.000 27.355 0., 0565o 16.6226 230.722 4*53.,4 5+03.9 77. 87 3 3*. 77 53. 13 1485

120. 0Q0 26.99* 0.,03705 15.7856 217.210 4705,,9 5o69.0 80,,139 34, 41 53.,30 1440 125.000 26.b2B 0.,03755 1*.9875 204.117 *958.,8 5935.2 82.,317 34. 01 53, 41 1-1 + 130.000 26.259 0,, 03808 14.2257 191.522 5212,,2 6202.

3*,,415 33. 05 53,,&/ 137 9 135.000 25.385 0.,05 863 13.*979 179.477 5466. 3 6*70.7 86. 441 33. 38 53. 63 13*3

11*0.000 25.507 0,.03920 12.8021 168.0 11 5721.,* 6740.? 88,,405 33. 20 54, 19 1307

1+5. ooo 25.123 0.,03980 12.1363 157.137 5977.,8 7012.7 90.,314 33, 09 34, 62 1272 150.000 2*. 735 0,, 0*0*3 11.4988 1*0.854 6235,,7 7286.9 92,, 17 2 32,,94 5 5

,

, 02 123o 155.000 2*. 3*0 0. 0*108 10. 8883 137-148 649*.,6 7562.3 93. 981 3?. o7 55. 29 1203

160. J00 23.9*1 0,,0*177 10 3036 128.002 o753,,5 7839.5 95.,738 32,.19 55., 35 1171 165.000 23.535 Oc,0*2*9 9.7*36 119.392 7C11,,2 8115.9 97,,439 31, 49 35, 1/ 1142 170.000 23.125 0., 0*32* 9.2G75 111.293 7266.,7 8391.0 99,,082 30,,68 3 + , ,93 111 + 175.000 22.708 o., 0**0* 8. o94* 103.680 7520.,4 6oo5 .* 10 0.,67 30,,50 55,,24 1082

Ida. aoo 22.286 0.,0**37 3.2038 96.532 7775.,3 89*1.9 102,,228 3G,,13 55,,40 1052

1(35.000 21.858 0., 0*575 7. 7350 89.828 8G30 ,,0 9219.5 10 3,,7*9 29. 85 55. 64 1. G22 190. 000 21.1*25 0,,0*667 7.2o77 83.551 8284,.9 9+98.* 105,,237 29.,62 55.,93 992 195.000 20.986 0. 0*765 6. 8613 77.689 8540.,0 9776.9 103,,69* 29,,44 56,,27 962 200.000 20.5*2 0,, 0*868 o.*556 72.231 6795,,5 10051.2 103.,123 29,,30 5 6

,

,65 9 33 205.000 20.092 Oc,0+977 6. J7C1 67.168 9051.,5 1 03*5.5 109..52 7 29.,19 57,, 15 9C5 210.000 19.o38 0.,05092 5.704o 62. +92 9307,,8 10651.8 11 J. 907 29. 11 37, 47 3 77 215. 000 19. 160 o., 0521* 5.3588 58.197 956*.,6 1G920.2 112.,264 29,,06 5/

,

,90 86 J 220.000 18.716 0,, 053*3 5. 032* 5*. 274 9821,,7 11210.8 113,,600 2b,,82 58,, 12 32c 225.000 13.253 0,, 05*79 4. 7249 50.712 10 077,,3 11502.2 114,,510 26,,73 58,, 4 6 302 230.000 17.78c c,,05622 4.4360 47.502 10333., 6 117 35. 4 lib, 19 9 26. o9 3 . 81 77 -> 235.000 17.319 0,,0577* 4. Ib51 44.628 10589,.0 12U30.2 117,,467 28,,o9 59 , 1 + 75/

21.0.000 Id. 85* 0,, 05933 3.9117 42.J76 10 8**

,

,0 12336.7 11a,,716 28,,72 59,,45 7 3 < 243.000 16.39C 0,, OjlOl 3.b752 39.331 11093,.3 12634.7 11 3,,94 + 28,,78 39,,73 715 250.000 15.931 o.. 06277 3.451.8 37.875 11351..7 12903.

7

121., 152 28.,35 59,,89 703 255.000 15.*79 0,,Oo*60 3.2499 36.191 11603,,7 13235.5 122,, 340 2e. 94 o , . J OtJ-T 260.000 15. 03* 0,,03652 3.U597 34.761 1185*,,2 1358 3.6 123,,505 29,,05 60,, G 3 to-l 265.000 14.599 0,, 0o650 2.3835 33.569 12102,, 7 13 3 3 3.6 12 + , ,648 29,,16 59,,9o 65c 270. 000 1*. 176 0.. 07 L5+ 2.72C6 32.596 12348.,9 14133.

u

125,,768 29.,29 59,, Oil 044 275.000 13. 766 0,, 07265 2.57G1 31.826 12592,,6 1**31.4 126,,663 29,,42 5 9 ,65 63 + 230.000 13. 368 0,,07*30 2.*31* 31.241 12833,,5 14778.3 127,,933 29, 56 59. 21 t 23 235.000 12.987 G.,077 00 2 . 3u36 30.827 13071,, * 15073.4 128,,57 7 29.,71 ^A<,79 61/

290.000 12.621 o. 0/923 2. 1860 3u .567 13306,,2 15336.2 129,,99 6 29,,86 >&., 32 613 295.000 12.272 0,, 031*9 2.U779 3J.448 13537,, 3 1565 6.5 130,,988 3C,,02 37.,73 60 + 300.000 11.939 0,, 03376 1.97 85 30.455 1 3766,, 3 159+4.

1

131,,955 30,, 16 3 ,' . , 2 4 6 JO 310.000 11.321 0,, 03833 1.8031 30.778 1*214,,1 1651 0.6 13 3.,813 30.,53 56. (,3 59 + 320. 000 10. 765 C,,09239 1.65*2 31.364 14650,.7 170&5.9 135.,575 30,, JO 54,,93 650 330. 000 10.2b* 0.,037*3 1.5269 32.057 15U73,, 17611.1 137.,25 3 31,, 30 5 +

,

, 03 5 8o 3*0.000 9. ell 0,, 10193 l.*171 32.305 15497,,5 131+8.0 138,,856 31,,71 5 3,, 3 + 53o 350.000 9.398 G,.106*0 1.3215 33.593 15911.,9 18o78.4 140., 39 4 32., 15 52,, 75 5 3o 360.000 9.022 0., 1108* 1.2375 34,*21 16321,,7 19203.5 141,, 873 32,,61 52,. 23 53/ 370.000 8.b78 0., 11523 1. 1634 35.3C7 16728,,3 19724.4 1*3,, 3'JO 33,, 08 51,,92 633 360.000 8. 362 0,. 11959 1. 0976 3o.261 17132,> o 2u2*2.0 14 + , ,631 33.,57 51,.62 693 39J.000 8.072 0., 12389 1. 0388 37.267 17536,, 2 0757.1 l4o,, 019 34..07 51,,40 692 MO. 000 7.60* 0., 1281* 0.9861 38.308 17938..6 21270.3 147,,318 34,,58 ;1 . 25 695

1*20.000 7.326 0,, 15o50 G.8955 40.435 187*5,,1 2229*.

J

1*9,,815 35,,o3 5 1,, 15 6 2 4*0.000 6.913 0,, 1**65 0.8207 42.57* 19556,.9 23317.9 15 2,,197 3t,,71 51.i 2 ' 609

+ o J. 000 6.552 0., 1526* 0. 7578 44.700 20377.,1* 2*3+6.

J

15 + , ,482 37,,79 51,,55 61/

1*80.000 6.232 0,, 150*6 0. 70*3 46.803 21209,,2 25331.1 156,,634 38,,38 51 .97 623

5 0.4)00 5.9*7 0., 1681* 0.6582 46.873 22053,.9 26*25.6 158,,816 39,,96 i?,, 43 633

191
ME THANE ISO BAR IT P = : 280. U BAR

T OEN VOL OP/UT OP/OD E H S cv OP W OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MC. /K J/1C../< I/SEC

97. o39 23.o72 < 03438 19.9090 282.394 3678 5 4555.1 69 077 35. 11 51 73 1611

100. 000 28.^00 0. 03509 19.*413 275.919 3693. 1 4675.6 70 330 35. 14 32 01 159 } 10S. 000 2d. 148 0. 03653 16. 4b93 262.432 3937, 1 -931.9 72 979 35. 21 32 *3 1561

110. 000 27. 795 o. 03598 17.56G2 2*6.793 4 18*. 7 519 2.1 75 329 35. 14 52 63 1527

115 J00 27.441 0. 03644 16. 7132 235.24* 443* 6 6455.0 7 7 c92 34 90 33 03 1* 55 120. 000 27.085 0. 03e92 15.8866 221.949 4685. 5 5719.3 7 3 94 2 34 53 5 3 1* 145 9 125 000 26.725 0, 037*2 15.0982 2G9.03* *93o 9 598-. 82 112 34 13 5 3 22 142j

130. 000 26. 362 0. 03793 14. 3*57 19b. 583 5188 o250.7 8 + 202 33 77 53 35 1391

135. JUO 25.995 u . 03847 13.o270 1 8 4 . 6 6 1 1440 e 6517.9 9o 219 33 *9 53 53 1357

1*0 300 2 5.02* . 03933 12.9398 173.295 6693 9 6736.6 S3 174 33 32 5 3 92 1322

145. 000 25.249 0. 039ol 12.2825 162.50* 5 9-8 2 7057.2 90 07 3 33 20 5* 32 1297 150 OuO 24.0O8 0. 0*021 11.6633 152.290 6203 5 7 32 9.8 91 921 33 06 34 63 1253

155. ouo 24. 48 J 0. 0*03* 11. 05G6 142. 645 64bO 3 7oJ3.9 93 716 32 76 54 92 12 20

1 DU 300 24. 09* 0. U + 150 10.*739 13 3.333 o716 6 '878.7 9 3 463 32 3C 5 * 9 + 119

lo5. 000 23. o99 0. U + 220 9.9216 12*. 990 6971 5 8152.9 97 151 31 59 34 73 lloi

173 00J 23. ju U 0*292 9. 3929 116.933 722* 8*25.7 99 790 3C 78 j* 40 11 33 175 ouo 22.89b 0. C+3o8 8. 8670 109. 3b2 747* 6 oo97 . 5 100 35 3 3C 59 5 - 7J 110-

180. 000 22.487 0. + 447 8. *G33 102.247 772o 1 8971.2 101 895 3C 22 3* 6 C I07p

1<J5. juo 22.074 0. + 530 7.9412 96.570 7977 2 92+6.7 103 399 29 93 5* 96 1C43

190 000 21.656 G G-.618 7. 5001 89.313 6223 3 9521.2 1C- 66 8 29 70 55 22 10 17 195 J00 21.234 c. + 7J9 7.u79b 63.-59 6479 .3 9797.9 lGo 306 29 52 3 5 4 9 96 9 200 JOfl 20.800 0. U 6 6. 6793 77.996 8730 5 1007b. 1 107 714 29 37 35 .7 i 951 205 300 20.376 0. 0490 7 6.2907 72.91* 6981 6 1j353.9 109 096 2? 25 5o 11 9 3- 210 J00 19.944 0. 0501* 3. 9376 68.203 9233 * 10637.3 11 3 45 2 29 16 56 45 9 37 215 000 19.508 0. G5126- 3.5953 63.86- 9485 ,1 1092 C* 111 78* 29. 1G 5b ej 691 220 000 19. u6o 0. 05 244 5. 2717 69.659 9736 ,9 11215.3 11 3 G94 26 85 3b 9'+ 833 225 OJQ 18.62 7 c. 05 366 *. 9o63 6o.208 9967 4 11*90.0 11 + 37 7 28 75 6 7 21 B3» 230 000 18. 185 G. C5499 •..676b 52.891 10237 b 11777.4 115 637 26 71 57 49 61 ( 2 3p ouu 17.743 u, 0563o *.4Q81 49.895 1G487 4 12 Jo 5 .

3

11 87 7 28 70 5 7 77 791 2*J JOO 17.302 Op78J 4. 1542 47.206 1G736 7 12333. U 1 16 096 28 73 58 U 3 771

21.5. JUO 16.663 0. G593U 3.9163 44.811 10985 4 12o*5.9 11 9 295 28 78 5A 27 752 250 JuO 10. 429 G.>0B7 3.6939 42.694 11233 3 12937.7 12 474 2e 85 36 .46 73*

2 o5 JOO 15.999 0. 05251 3.*8fcl 40. 840 11460 2 1 323 j.

3

121 633 26 95 56 59 719 260 J JO 15. 375 0. 05420 3.292* 39.233 11725 8 135 2 3.5 122 772 29 05 58 67 70S 2b5 000 15. 160 G^596 3. 1121 3 7 . 6 5 11969 9 1 391c .6 12 3 88 9 29 17 3 8 67 o89

270 ouo It. 75". 0. 06778 2. 9*** 3o.694 12212 2 14110.1 12- 98 5 29 30 38 .c 1 fc-7q 275 . JUO 14. 356 0. 3 965 2. 7886 35.731 12452 b 1**02.6 126 060 29 *4 se 4 7 >6a 260 JOO 13.574 07156 2. 0**1 3-.9S2 12t90 9 1*634.6 127 111 29 56 5A 27 053 285 OUO 13. cU2 G. 07352 2.5112 34.342 1 2926 e 14 9 9 6.3 129 1*0 29 74 56 L i C *-) 290 000 13.2*3 0. 07 551 2.3863 33.887 13160 2 15274.0 129. 1*6 29. 39 57 63 033 295 .JOO 12.89o 07753 2.2715 33.574 13391 1 165o2. 1 130 129 3 Ob 57 31 '; 3 2 3Ju 000 12. 5bo 0. 07958 2. 1654 33.3e9 13619 5 158+7.7 131 039 3C 23 5 91 2 5 310 JOO 11 .9"»6 03371 1. 9764 33.369 14G66 5 lc*12.* 132 9*1 3C 59 36 .03 617 320 JUO 11. 361 o. 03787 1.8145 33.o9o 14S07 i 169oo. 1 13 , 706 30. 98 55 11 -11 330 .000 10 . 6b6 09202 l.b754 3^.272 1*936 4 17514.9 136 338 31 36 3* 27 L 3 3*J 000 1U.*G1 G G3bl* 1.356 3*. 953 15361 9 18053.9 137 99 7 31 81 53 55 60 j 350 300 9.97o 13G2* 1.4501 35.084 15779 .6 1858c* 139 5*1 32 25 5? 99 6 J- 360 OuO 9.587 o. 1 J * 3

1

1. 3579 36.*51 16193 2 19113.8 14 1 u27 32 72 32 5 3 J* 370 000 9.2.50 1J635 1.2763 37.261 lo603 6 19o37.3 142 4ol 33 19 52 19 DU*

36u 000 8.901 1123? 1.2038 3o.088 17 C 12 C 20157.9 143 6 + 9 33 o9 1 1 6- h U 5 39J . JOO 8.397 Uo33 1.1388 36.977 17419 2 20o7o. 3 14 3 196 34 19 3 1 7 3 t jj 4u0 . JOU 8.315 12026 1. 08G5 39.921 17825 9 21193.1 146 604 34 71 51 6 2 6 39

if2a JOO 7.612 12601 0. 9oGl 41.916 186*0 1 22224.3 149 020 3 5 76 51 5 3 ol4*0 000 7.375 c 1 3 659 C.0571 4 3.9 7* 19459 2 23255. 7 151 419 36 63 51 6 - c2'> 460 . JUO 6.992 1 + 301 3. 8275 4o

.

04* 2G286 5 2429 0.

9

153 72 37 92 51 91 o27 480 .000 o • o54 15029 G. 7682 40.114 21124 5 25332.9 153 937 39 00 52 oJ b 3 . 500 000 6.361 137*4 0.7171 5U.144 21975 1 2o333.6 153 092 40. 08 >2 7 3 6*2

192
ME THANE ISC BAR AT P = = 300.0 BAR

T DEN VOL DP/OT OP/DO £ H S CM CP W OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K t/SL'C

96..120 28.707 0,,03483 19.8582 284,.303 3587,.6 4632,.7 69,,165 36.,24 51,,75 1615

1JJ,, 000 28.572 0.,0*500 19. +924 279,,337 3b78,,5 4726,,5 70,,15 8 35. 27 51. 93 1601

105,,000 28.224 0,,03543 18.5538 266 .252 3921,,4 4984,,3 72,,703 35,,34 52,,31 15o5

110,,000 27.675 0,,03587 17. 6566 252,,944 4167. 8 52 + 4.,0 75., 146 35. 26 52

.

71 153v

115..000 27.525 0,, 03633 16.8005 239..o63 4416,,3 5506,.2 77,,496 3?, 02 ?2,,93 1502

120,,000 27. 174 0,,03680 15. 5640 226,,589 4665,,9 5769,,9 7 3,,7 + 9 34, d5 52.,96 1-0 i 125,,000 26.620 0,, 03729 15.2051 213,,655 4915.,8 6034,.3 81,.91 3 3 + , ,25 5 3,, + 1-3^

130,.000 26.-63 0,. 05779 1+. 4616 201..555 5165,,8 6299,.5 83.,995 33. 88 53,,1=> 1-0 + 135,,000 26.102 0,, 03831 13.7514 189..751 5416., 3 65b 5 , ,6 86,, 004 33. ol 53,,36 1370

140,,000 25.738 G,,03865 13.0726 176..484 5667,,5 6833,,1 87,,95 33. + 3 i3,,67 133o

145,,000 25.370 0,,0 5942 12. +232 167,.774 5919,,9 7102,,4 89,,83 9 33,,31 54 , ,0- 1302

150,,000 24.997 0,. C+000 11. 8018 157,,62b 6173,,3 7373,,5 91,,677 33,,17 54,,38 12b i 155,,000 24.621 0,, 0+062 11.2069 146,,040 6427,,5 76 + 6 ,0 93,,464 32, 39 54, 6 3 12 3/ 160,,000 24.240 0,, 0+125 10. 6373 136,.996 6681., 4 7919,,0 95,, 198 32,.40 54,,5 7 120o

165,,000 23.85b 0,,0-tl92 10.0920 130,.477 b933., 6 8191,.3 96.,874 31. 69 54.,32 1131

17J,,000 23.4o7 0,, 04261 9.5700 122,,469 7183,,6 8462,,0 93,,49 30, 88 ?3. 9j 115?

175.,000 23. U7 + 0,,0+334 9. 07 C7 114,,919 7431,,3 6731 , , 5 10 0,, 050 30. b9 54..22 1123

180,,000 22.676 0,, 0+410 8. 5932 107,,63d 7679,, 6 900 2,,7 101,,57 6 30,,31 5 + , ,26 10 9/ 185.,000 22.277 a, + 499 8. 1371 101.,178 7927. 7 9274.• 4 103. 066 30. 02 p4,,41 luo)

190.,000 21.8/3 0,,04572 7.7016 94,,936 6175,,4 95+6..9 10-,,520 29,,78 54,, 6 9 1042

195,,0 00 21.46b 0,,0+658 7.2863 89,,069 6422.,8 9820,, + 105,,940 29. 59 5 +

,

61 101-

200,,000 21.05b c., G + 7+ i 6.6yG7 83,,o23 8670,,2 10095,.0 107,.331 29., + 3 J5,, 5 537

205.,000 20.b42 o. + 8+ + 6.514+ 76,,525 8917,,6 1037C,,9 108,,69 3 29,,31 55,,31 961

210,,000 20.226 0,, C49 + + 6.1570 73,,785 9164,,9 106+8,,1 110., 030 29. 22 55,,59 93j

215,,000 19.606 0,.C50+8 5.6179 69.,392 9412,,2 10926,,8 Ill,,341 29.,15 56,,67 911

220,,000 19.386 0,, 03 156 5. +967 65,,338 9659,,5 1120b,,9 112,,629 28. 39 ->5. 9^ 838

225..000 16.967 0., 05272 5.1931 61,.612 9905,,4 11437,,1 113,,839 28,,79 56,, lo 866

230..000 18. 545 a,.05332 +.906+ 58.,205 10150,,9 11768,,5 115,, 125 28,.73 pb.,39 6 + + 235,,000 18. 124 0,, 05517 +.c363 55..104 10395,,8 1 2 J 5 1

,

,1 116,,341 26,,72 56,,63 62 3 240,,000 17.70'. 0,.056+8 +.3821 52,.299 10640., 3 12334,,3 117.,535 28. 75 56. So o J 5 245., 000 17.287 0,, 05735 4.1432 49,.776 10684,,2 12619.,6 116,,710 28.,79 57,.07 734 250,.000 16.672 0,,05927 3.9191 47,.521 11127.,4 12905,, 5 119,, 6o5 28,,87 5 7 . . 25 7o j 255,,000 lb. 462 0,, 0507 + 3.7U91 45,,520 11369.,8 1319 2,,1 121,, 00 C 2b,,96 57., - J 75 j 260,,000 lb. 1,58 0,,0 3 227 3.5125 43,,759 11611., 1 13+79,,3 122,. 116 29. 07 5 7 . . 4 3 73^

265.,000 15.660 0,, 0o386 3. 32e8 42,,223 11851,,3 13767,,0 123,.211 29,,19 57,, 5- 72 5 270..000 15.270 0,, u6 5 + 9 3.157 2 40,,697 12090,,0 1-054,,7 12 + , ,2«7 29,,32 57 , , 6 + 7o,' 275,,000 l+.68o a,, 0o717 2. 9971 39,,767 12327., 3 14342,.3 125,,3+2 29,, + t 57,,43 cSj

280,,000 l+.61o 0, Go899 2.8479 36.,820 12562.,6 14b29., + 12d., 377 29. 61 57,,37 635

285,,000 14. 155 0,, 07065 2.7089 36.,040 12796,,5 1491v,,9 127,,39 1 29,,77 57,,21 67t

290,,000 13.80 5 0,,07 2-.+ 2.5796 37,, + 15 13C28,,2 1520 1,, 4 123,,33 + 29,,93 57,, CO tCJ

295,,000 13.466 0..07426 2.4593 3o,,932 13257,,9 15+85,,8 129,,357 30,,1C it , 7 5 65 3 300., 000 13. 139 o. 07611 2. 3475 36. 579 13+65. 5 157o8,.6 13 0,,30 8 30.,26 56,,45 652

310,,000 12.521 0..Q798o 2. 1468 3b,,221 13934,,3 1633 0,,2 132,, 149 30. o5 5t>

.

bl b-1 320,,000 11.953 0.. 03356 1.9733 3b,,259 14375,,0 16634,,8 13 3,,910 31 , 05 55. 1J 6 55 330,,000 11.432 0.,037+7 1.8231 3b,,oll 14808.,0 1 7 432,,2 135,,59 + 31.,+fc 5 -

.

33 c2 3 340. 000 10. 95 6 0. 09127 l.b926 37.,17b 15234.,4 17972,,6 13 7,, 2d 7 31.,90 33., 72 626

350,,000 10.52U 0. 0353o 1.5785 37 , ,64 + 15665.,3 16507,,0 133,,75 6 32,,35 >3<, 1" d2 J 360,,000 10.120 0,,03681 1.4762 3a,,562 16072,,1 19036,,4 140., 248 32.,82 62,,73 b21

370.,000 9.752 0., 1J254 1.3894 39.,313 16485. 6 19552.• 141. 688 33. 30 52. 4 5 b21

360,,000 9.412 0,, 10624 1. 3102 40.,091 16897,,5 20064,,8 143.,082 33.,80 52,, 16 c21

390,,000 9.u9b 0,,10 992 1.2393 40,,89b 17308,,0 20605,, 6 14-,,435 34.,31 52., 0J 622

400.,000 8.6C5 0,, 11357 1.1755 41,,737 17718,, 1 21125,,1 145,,75 34.,32 51,,90 62 5 -.20,,000 8.260 0. 12077 1. 0655 43,,554 18539.,3 221o2,,3 143. 281 35. 88 51,. 6j o2o

440.,003 7.823 0., 12784 0.9744 45,,498 19365.,0 23200.,1 15J.,694 36. 96 51, 5o £51

4od,,000 7.420 0,,13477 0.6978 V',495 2G198.,6 2+2+1,,7 15 3,,009 36. 04 >2, 22 637

480,,000 7.064 0.,1+157 0. 6327 49,,503 21042,, 5 23289,,7 155,,239 39.,12 j 2,,c-Q 6--

pOO. 000 b.745 0. 1 + 626 0. 77b7 51,,503 21898. 6 26346. 3 157,,396 40. 20 ?3,,07 661

1 93
ME1 HflNt ISO JA^t 4T P = 320.0 OAR

T OEN VOL OP/DT OP/OO E H S CM CP H DtG K MOL/L L/MOL BAR/K 8AR-L/M0L J/MOL J/MOL J/MOL/K J/MOL/K J/.10L/< I/SEC

98 599 28.71.2 0. 031.79 19.8083 266.162 3596.9 4710.2 64. 25 3 35. 37 51 73 1615

10J. OOQ 28.0+3 0. 03491 19.5+09 282.625 3664.2 4731.

+

69. 98 6 35. 39 51. 85 1607 105 000 28.298 0. 03534 18.6156 26>+.954 3906.0 5036.6 72 529 35 46 52 25 1575

110. 000 27. 95". 0. 03577 17. 7302 256.983 4151.3 529b.

1

74, 97 35, 38 52. 60 15 + 3 115 J00 27. bOo 0. G3622 16. 6648 243.979 4398.6 5557.7 77 312 35. 14 52 7 7 1511

120 000 27.261 0. 036o8 lb. 0781 231.131 4646.8 6820.7 79 5o0 34. 77 52 63 1460 125 .000 26.912 0. 03716 15. 3083 218.582 4895.3 6034.3 81 717 34 37 ?2 67 1446

130 000 2o. 561 0. 037o5 1+. ?736 20b. 432 5143.8 63+8.6 83 792 34 00 52 96 1 + 1 3 13? 000 2b. 206 0. 03616 13.8717 19+. 751 5392.6 ool3.7 a-j 79 + 33 72 53 15 1383

140 000 25. 64b o. 3 669 13.2007 183.583 6642. 1 6880.1 87 732 33. 54 53 43 1350

1 + 3 000 25.48/ 0, 0392* 12.p590 172.95+ 5892.6 71+8.1 89 613 33 42 o3 73 1317

150 000 25. 122 03981 11. 9+49 162.873 614 + . 1 7+17.9 91 4+1 33 27 54 i 1235

155. 000 2+.75+ 0. 04040 11. 3571 153.339 0396.2 7b38.9 93. 218 3 3. 00 5 + . 27 125 + 160 000 24. 382 0. 0-flOl 10.7943 144.340 6647.8 7960.3 94 94 2 32 51 54 23 1225

lo5 000 24. 006 0. 04166 10.2555 135,669 6697.9 8230.9 96 60 7 31. 79 i3 9j 11 + 3 170 000 23.b27 c. + 232 9.7398 127.074 7145.2 3+99.

b

93 212 3 0. 97 5 3 5 3 117 + 175 .000 23.21.1, 0. + 302 9.2+65 12 0.363 7390.

3

87o7.0 99 75 9 30. 76 53 79 11 + 5 160 000 22.859 0. + 375 8. 7747 113.300 7636. 1 90 16.0 101. 274 30. 40 63 81 1113

185 000 22.470 u445G 8. 3239 1Gb. 665 7861.

1

93Jp.2 102 750 3 10 53 9 J 1091

190 000 22. 078 0. + 529 7. 093". 100 . + 36 6125.

7

9575. 1 10 + 189 29 86 54 + 10c- 195 000 21. £8 + 0. 0+612 7. +627 9+.59+ 8369.9 9345.7 105 59 5 29. ol 54 21 1033 200 JOO 21.28? 04696 7. 0914 89.125 8614.0 10117.2 106 970 29 50 5 4 4J 1012 205 000 20.668 04737 6.7188 8+.014 6657.

8

10369.8 10 6 316 ?9 37 5 + 62 987 210 000 20. + 60 + 881 6. 3646 79.249 9101.5 1 Obb 3.

+

10 J .635 29 27 5 + 85 9c2

215 JOO 20. 085 + 979 b. 0263 7+.319 5345. 10936.2 110 92 8 29 20 55 03 9 38 220 000 19.b62 G 03081 5. 7093 70.714 9566.4 1121+.2 112 197 28 93 55 11 916 225 OGO 19.278 05137 5. 4J73 66.926 9830.

3

11490.2 113 437 2e 83 56 27 894 230 JOO 18.87+ 05298 5.1216 63.++1 10071.

e

1 I7o7.0 11 + 65 + 28. 77 55 4-j A73 235 000 18. -.71 0. 0541 + 4. 8518 60.252 10312.4 12J+4.9 115 849 26 75 5 5 6o 853

2 + J 000 13. 069 0563 + 4.6974 57.347 10552.7 12323.7 117 023 28 77 55 fco 633

2 + 5 000 17.670 05659 + . 3577 5+.712 10 792.5 12603.5 118 177 26 82 5c C5 81 + 250 .JOO 17.27J 05 789 4. 1322 52.338 11031.6 12834.2 119 311 28 89 56 23 7 97 255 .JOO 16.081 05924 3.9203 50.209 11270.0 13165.7 120 426 28 98 5c 37 78J 260 000 lb. +95 0. 06063 3.721+ 4o.313 11507.

c

13++7.9 121 52 2 29 09 5 o + 9 "hi 2o5 000 16. Ill 05207 3.5348 46.637 11744.2 13730.5 122 59 9 29 21 56 5 5 75J 270 ooo 15.735 0o355 3.3599 45.168 11979.8 14013.4 12 S 656 29 34 3 o 60 737 275 JOO 15.3b7 0, 06507 3.19t2 43.891 12214.0 1+296.

+

12 + 695 29 + 9 ?6 69 725 280 000 15. 007 0. 0d66 + 3. 0431 42.794 12446.9 14579.3 125 714 29 64 » 6 54 713 285 000 14.b56 0oo23 2.8998 41.864 12678.4 1+861.3 126 714 29 8G 5o + 5 70 3 290 JOO 1%. 315 0, 0598b 2.7o6Q 41.089 12903.2 151+3.7 127 695 25 97 56 32 ^9 + 295 .000 13. 963 07152 2.6409 4G.457 13136.4 1542 4. i 123 656 30 15 p6 16 b3?

300 000 13.662 07320 2. 5242 39.966 13362.9 1570 5.2 129 .599 30 33 55 9c 673

310 .000 13. 052 7 6b 2 2. 3136 39.30+ 13610.7 162b2.5 131 .+26 30 71 55 -9 oi-j 320 000 12. 485 08010 2. 1298 39.059 1+251.7 16814.8 133 179 31 11 5 + 96 65j 330 JOO 11. 961 6 361 1. 9b96 39.152 14to6.

1

173ol.6 13 + 862 31 54 JH 3i 64 i 34a .000 11. +76 ,03712 1.8295 39.517 16114.7 179J2.7 136 47 7 31 98 53 8 + 6 + + 350 .000 1 1. u34 03063 1.7 66 40.073 15 5 3 8.3 18438.5 138 030 32 44 53 3 i 641 360 .000 10.625 09412 1.6983 40.731 16957.8 18969.6 13 + 527 3 2 91 52 .91 63 j 370 .000 10.248 09758 1.5G23 41.436 16374.4 1949 7.0 140 97 2 33 + 3d 59 633 380 .000 9.899 10102 1.4167 42.172 16789.0 20021.7 142 371 33 90 52 3-, c 37 390 .000 9.575 G 10444 1. 3399 42.933 17202.

+

2 5+ -.5 143 ,729 34 + 1 52 20 637

•4UJ JOO 9.271. 1J733 1. 2708 43.71b 17615.5 21066.0 145 05 34. 94 52 12 o36

42J .000 8. 730 11454 1. 161+ 45.364 16442.6 221J7.9 1 + 7 .591 36 00 52 10 C40

+ 40 000 3.251. 12115 1.U622 47.158 19274.3 23151.0 150 017 37 J7 52 2 + o + + 4oJ .000 7.835 1276 + 0. 5668 49.055 20113. 7 24198.2 152 .345 36 16 52 60 649

480 .000 7.1.62 . 13402 0.8978 5J.996 20963.1 25251.7 15 + 587 39 24 52 87 65 + 500 .000 7. 128 . 1+029 0.8366 52.947 2182+.3 26313.

b

156 75 4 + 32 53 33 661

194
MET HANE ISOBAR AT P =- 340.0 BAR

T DEN VOL OP/DT DP/DD E H S CV CP A DEG K MOL/L L/MOL BAR/K BAR-L/MOL J/?10L J/MOL J/MOL/K J/MOL/K J/10L/K :1/SEC 99 076 28.777 03475 19.7593 287 969 3606 3 4737 .8 69 34l 35 50 51 72 161/ 100 .000 28.714 03483 19.5868 285 .782 3 65 .3 + 6 3 4 4 6 9 321 35 52 51 80 1612

103 000 28.372 0, 03625 18.6747 27 3 537 3891 1 5069 5 72 356 35. 58 52. 21 1532

110 .000 28. 031 3566 17.8010 26 914 4135 .3 6348 2 7 + 795 35 50 32 53 1551 IIS 000 27.689 03611 lc.9b£0 248 191 4381 4 5639 4 77 132 35 26 52. 65 1523

120 000 27.347 G 03657 16. 1690 235 .575 + 628 ,4 5871 .7 79 374 3* 89 52 o5 1 + 83 125 000 27. 003 03703 15. +082 223 216 4675 5 6134 6 81 52 6 34 48 32 71 1h5i 130 000 26.657 Q3751 14.6818 211 219 5122 6 639o 63 59 4 34 11 5 2 76 1427

135 000 26.308 5 801 13.9679 199 o62 5369 8 66o2 2 83 589 33 83 52 9 5 1193

1*0 000 25.956 G3853 13.3246 188 594 = 617 ,7 6 92 7 .6 8/ 519 33 65 5 3 22 136 3 145 000 25.601 0. 03906 12.69G1 178 .045 5866 ,4 719 4 .5 89 39 2 33 53 j 3 5 + 1331 150 000 25.243 03951 12. 0830 168 030 6116 7452 9 91 212 33 38 53 8 3 ll'jO 155 ouo 24.682 04G19 11. 5018 158 547 6366 2 7732 6 92 980 33 10 j3 9 3 12 7 3 160 000 2-.. =18 0. 0*079 10.9464 149 591 6615 8 8032 5 9 + 694 32 60 53 92 1242

165 .000 24. 150 0*1*1 10.4128 141 145 6663 6 6271 5 9 o 149 31 89 53 62 121 -j 170 000 23.78U + 205 9.9029 133 1SU 7103 7 8638 5 9,' 9+4 31 6 53 2 3 1132

175 000 23.407 C + 272 9.4151 125 703 7351 ,4 613 + .0 93 410 3 87 53 39 116 + 180 000 23.031 04342 B. 94 85 118 o6G 7594 6 9070 9 13 J 984 3C 48 53 3o 1133 185 000 22.653 0. 0*414 8.5U26 112 040 7637 93 3 7 9 102 4+3 30 ie 33 4 + 1112

190 000 22.272 0*490 6. 0766 105 822 8G76 . 6 9o0 5 . + 101 .87 + 29 94 i3 3 5 1 8 o 195. 000 21. 890 0. 0*568 7.6702 99 964 o320 2 96? 3 5 105 267 29 74 = 3 61 1051 200 000 21.506 0*650 7.2826 94 512 8561 3 101 + 2 3 10 6 626 29 57 53 8 + 10 3.. 205 000 21. 119 0, 0+735 0.9134 89 389 8802 C 10 + 11 9 107 95 9 29 + 4 54 01 1011 210 000 20. 732 0. 0*823 6.5621 8 + o03 90 + 2 ,4 1 oo82 * 139 26 3 29 3 3 34 2 3 937 215 000 20. 344 G + 91& b.2261 80 142 9282 .6 1C953 .9 110 5+1 29 25 5 ** 4 9o + 220 000 19.955 o. 05011 5. 9111 75 994 9522 .5 11226 4 111 79 4 2 8 98 54 3 3 343 225 JOO 19.566 05111 5.6105 72 161 9760 9 11498 b 111 017 2 8 87 5 4 61 921 230 000 19.177 G. 0J21 + 5.3267 08 601 9998 6 117/1 6 11 + 217 28 61 54 67 931

235. 000 18.790 G 05322 5 . 5 b 3 6 6 3 3c 1C235 8 120+5 3 115 395 28 79 5 + 8 + 881 2*0 JOO 18. 40 4 0. 543 + 4. 8017 62 343 10472 5 12320 115 551 28 31 5 5 01 811

2*5. 000 18.020 0. 035+ 3 + . 31)14 59 ol2 10708 7 12595 5 117 £8 7 28 85 55 19 8+ i 250 000 17.639 05639 *. 3348 57 133 10944 2 12871 a 111 804 26 92 5 5 35 6 2.j 255 000 17.261 0. 05793 *. 1213 54 692 11179 2 131*6 9 11 5 931 29 01 55 H 3 60 3 2oJ JOO 16.688 03921 3. 9203 52 87e 11*13 4 13*26 7 123 980 29 11 3 6 61 7 93 265 000 16.620 G. 5Q5 3 3.7313 51 073 11646 9 13705 122 0*0 29 24 55 7J 77 ) 270 000 16.15o 0. 0ol89 3.3=37 49 + 80 lie79 4 13983 7 12 5 082 29 37 55 7 6 7b5

275. 000 15. b02 0. Go326 3. 3868 48 073 12111 142o2 6 124 105 29 52 55 7 9 7 53 280 ouo 15.45* 05471 3 . 2 3 i 2 4o 843 12341 4 1+3 + 1 5 12 5 111 29 o7 35 73 7 + 1 2 85 000 15.113 :>ol7 1. 0833 45 779 12570 7 14820 4 1?3 09 5 29 34 65 75 7 5 3 290 000 14.780 c. 067ob 2.9+56 4 + 36 9 12798. 6 15099 127. 06 7 30 01 = 5 b3 72 3 295 000 14.46o 05917 2.8165 44 102 13025 3 15377 2 128 018 30 19 3

c 1 8 711

3 00 000 14. 142 0. 0/071 2.u965 43 + 67 13250 3 15o54 7 121 95 1 30 16 5 6 + 5 73 3 313 000 13.541 0. C7335 2. + 7b0 42 563 13t9o 7 16237 7 130 764 3C 77 5 5 12 cd i 320. ooo 12.978 0. 0770 = 2. 2833 42 052 1 + 137 2 16757. 132 50 8 31 18 54. 7 i 6/1

330 000 12.466 0. 01029 2.1141 41 6Q9 14572 2 17302 2 11 + 18 5 31 ol 5 4 33 67 1 3-td 000 11.969 0. 01355 1.9o52 42 39 15002 2 173+3 135. 600 32 06 53. b6 cc- + 3s0 000 11.519 01611 1.6340 42 415 15427 e 18379, 5 137 36 6 32. 5? ~>3 + + 65 9 3b0 000 11. 103 o. 09007 1. 7160 42 963 15849 e 18912 133 855 3 3 30 5 3 0/ 3 5 J 37i OGO 10. /16 0. 9 3 3 ii 1.6149 43 olO 16268 9 194+1 14 3 305 33 50 52. 76 65 + 380 000 10. 361 G 03651 1. =229 44 30 + lb686 1 9 9 o 7 4 141 73 9 34 00 5 2 5 3 6 = 5 390, 000 10. 030 0. 397 J 1.4*0* 4 5 028 17102 1 20 + 91 9 141. 071 34. 52 52. 33 653 too 000 9.721 10287 1.3660 45 rii 17517 7 21015, 3 144. 396 35. 34 52 33 65 3 420. 000 9.162 0. 10914 1.2374 47 321 18353. 22G60. 9 146. 9+7 36 11 52. 3 3 c 5 + 440 000 8.671 G. 11633 1.13 4 48 966 19187. 1 23108 3 14 3 3o3 37 19 52 •--. 6 66 460 000 8.23t 0. 121 + 2 1. 0402 60 733 20C31. 7 2 + 16 2 151. 72 1 38. 26 52. 7 + bo J 480 000 7.846 0. 12742 0.9634 62 586 20886 2 25216 o 151. 973 39. 36 5 1 11 663 500 0-0 7.501 0. 13332 0.8973 5 + + 7 + 21762 3 2b235 3 151. 1=0 4G. + 4 53. 5 7 b/1

195
HE rhflNE: iso 3ArI AT P = 361 .0 BAR

T DEN VOL OP/CT P/DO E H s CV CP H OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOl /K J/MOL/K M/SEJ

99 551 28. 812 0. 03*71 19 7111 289 725 3615 9 *865 4 69. 429 35. 62 51 71 If 1 i 1GJ 000 28. 763 0, 0347* 19 b302 288 8G4 3636 7 4837 * 63 65 6 35. 64 51 /- 1617

105 000 28. 4*5 0. 03516 18 7313 276 998 3876 6 5142 2 /2. 19 35. 70 52 1* 1563 na 000 28. 107 . 03556 17 8b91 26- 731 4119 7 5400 6 7 *

.

b22 35. 62 52 *1 1553

115 000 27. 76* G36G1 17 U445 252 3C1 *3b*, 6 5bol 1 7 6 55 6 35. 37 52 5- 1526

120. 000 27. *3l o. 036*6 lb. 2568 239 92* 4f 10. 5 5922. 9 79. 19 2 35. OC 62 67 1-53 125 GOO 27. 092 03691 15 3J*8 22/ 75 o 4856 3 6185 1 81 338 34. 59 62 67 14CJ

130 000 2b. 750 0. 37 36 1* 7oc5 215 91 9 5 10 2 6** 7 a 83 *01 34 22 52 62 1*33 13s 000 26. *07 0. 03767 1* 10G3 20* 468 53*7 8 o/l 1 ,i B5 38 9 33 94 52 7 1-0 8 l<id 000 26. Obi 0. 03837 13 4*43 193 521 559* 1 b9/5 5 8/ 312 33 76 3 3 1 137o

1*5 JOG 25. 712 03689 12 aiea 163 013 5641 2 72*1 3 63 177 33 o3 53 32 13-^

150 000 25. 36G 0, 3 9*3 12 2163 173 1C1 6G8 9 1 750 6 9j 990 3 3. 48 53 59 131-

155 OuO 25. 1 0. 3 999 11 6*15 16 3 b73 6337. 4 7777 92. 750 33. 20 5 3 72 1235

160 000 2*. t*9 0*057 11 0912 154 75* 6585 80*5 5 9* 434 3? 70 6 3 63 1253

lo5. JO 2*. 289 0. 0*117 10 5b*2 146 341 b630. 9 6313 93 100 31. 9 8 53 31 1233

170 000 Z3 92 7 0. 0*179 10 0598 13b *12 7073 8 0576 if 97 68 5 31 16 52 67 1 2 1 j 1/5 000 23 563 0. 0*2*- 9 3 77l 130 9*7 731*. 3 68*2 2 99 21? 3C 96 33 I* 116 3 Ida 000 23 196 0*311 3 1154 123 921 7555 2 910/ 2 100 7j5 30 57 i3 GO 1 1 5 / 185 J 00 ZZ. 627 0. 0*381 8 6740 117 31* 7795 2 53/2 3 102 150 30 26 5 3 03 113?

190 JOO 22 457 0**53 8 2522 111 10 3 803* 5 9637 6 103 573 30 HZ 33 1 1 110 ' 195 000 22 u6* G 0*528 7 6*95 103 2b9 o?73 3 990 3 * 10* 954 29 31 3,3 21 1 JO I 200. GOO 21. 711 c. 0*c06 7. *c?3 99 793 8511 7 1 C 1 3 9 8 1C3 30 3 29. 64 53 3- 1C33 2o5 .000 21 337 0*bd? 7 0992 9* j61 6749 . 6 10*36 ,8 10/ 621 29 30 53 43 1l3- 21J OuO 20. 961 0. 0*771 6. 750* 89 856 6987 1 1 j / J * D 108 912 29. 39 5 3 U3 1011 215 000 20. 585 0. 0*856 b *167 65 .567 922* 4 10 9/3 2 110 176 29 31 6 3 .6 j -33) 220 000 20. 209 0. 0*9*8 b 103- 81 ie3 9*bl 2 112*2 5 111 415 29 04 >3 7 5 lo) 225 000 19. 03* 0. 050*2 5 8u*0 7 7 292 9696 5 11511 3 112 C?4 28 92 53 6 5 --.' 2id OOJ 19. *5S 0. G5139 5 5201 73 686 9931 r 11/31 1 11 3 80 8 ?e 66 5 3 93 927 235 OuO 19 u85 0. 052*0 5 2511 7u 35* 10165 .0 12 031 3 11* 97 1 26. 83 5* .12 907 2*0 000 18. 712 o. 053** * 39r * 6/ 286 10393 5 12322 3 llo 112 28 35 5* 2» 33 3 2*5 000 18. 3*2 0. 05452 * 7355 64 *7l 10t31 4 12534 1 11/ 233 28 39 5* -3 6/ J 250 000 17 97 = c j 5 j 3 * 52 7 9 61 898 1 C Bb3 9 l?8bt 7 119 334 28 95 5* 5-1 853 255 GOO 17. bll 0. 05676 - 3131 59 558 11L95 .6 13139 9 113 4lb 29 0- 3 - 72 83 j 2o0 GOO 17. 251 05797 * 11U3 5 7 *39 11327 13 413 ,9 12 1 *80 29 15 5 * 65 021 2o5 000 lb. d9b 0. 05919 3 9192 55 529 11557 6 13o3o * 121 52 6 29 27 5 - 95 81.

270. 000 lo 5*5 GdG** 3 7392 5 3 617 11787 5 1 3^o3 3 122 56 3 ?9. *C 5 5 .0 3 792

275. GOO It. 201 05172 3 .569b 52 29? 12C16 3 1*238 b 123 5b* 29 55 5 5 03 773

260 JOO 15 6o J Oj30* 3 4101 50 942 122*4 7 1*514 1 1?'* 55b 29 / 1 56 1 I 7c/ 28s GOO 15. 532 0. 0543a 3 2tC0 <-9 75/ 12*71 8 1-785 5 1?3 532 25 86 5 5 11 7 5b 290 000 15. 208 0. 0b57b 3 1166 40 726 12E93 G 15065 1 12b -9 3C 05 33 Co 7* j 29a GOO 1*. 692 0. Do 7 1

5

2 9Bcl 4/ 877 12923 G 153*0 * 127 *3 1 30 23 3 5 .03 73/

300 GOO 1* 564 . = 857 2 3bl4 4/ 061 1 3 1*6 9 15615 4 12o 356 3C *2 3- 9 5 72s 310 .000 13 993 0/l*o 2 o341 43 928 13691 2 1 C 13 3 9 13 j 154 3C 62 5* 7* 71 3 320 000 13. ^,37 . 07**2 2 -33* *3 19- 1-G30 e lc710 .0 131 888 31 24 3 4 46 701 330 GOO 12 91c 0. 077*2 2 2361 4* 616 1*465 8 1/233 .0 133 559 31 JO 5* 1 5 691 3*0 OOG 12 430 030*5 2 0593 44 /4J 14093 6 17732 3 135 170 o2 14 53 61 - 5 3 350 000 11 977 G, 033*9 1 ,9bG* 4- 91o 16323 6 13329 3 133 725 3? ol 53 4 3 6 7-, 3o0 000 11 j5o 0. 0:1653 1 6370 45 30- 15/47 4 188o2 5 1 3 22 8 33 09 3.3 1/ 67*

370 000 11 I6t G3956 1 7271 43 845 lbl68 7 19392 3 13 3 CO 1 3 : 59 3? .93 b 7 1 380 000 10 802 0. C9257 1 6269 46 481 lb588 1 19920 8 141 009 34 IC 52 c i joi

390 .000 1(1 4b4 04557 1 3*0/ 4/ 165 17L06 c LU-.tr, .9 14 2 45 5 J* 62 3 2 3 5 bb i *00 000 10 1*6 0385* 1 *bll 47 877 1742* 5 20971 9 l<t3 704 35 15 52 4/ 6c *2G ,000 9. 57c 1G**3 1 323* 49 358 18261 6 22020 9 143 3** 36 22 5? 4/ on 3 **0 .000 9 071 1102* 1 2067 50 90* 19103 3 230/1 8 14,1 /o8 3 7 30 52 c 5 to)

4oO GOO 8 623 11597 1 1118 52 538 19 952 7 2*127 6 151 13* 38 39 5? 95 o72

l»8fl .000 8 222 G 12162 1 u292 54 .276 2G611 9 75130 ,2 15 < 396 39 *7 53 3 3 c/o 500 000 7 662 12719 9581 56 086 21682 5 2o2bl 3 153 582 40 35 53 73 bol

196
METHANE IS03AR AT P == 330.0 BAR

T OEN VOL DP/DT DP/DD E H S cv CP H OEG K MOL/L L/MOL BAR/K 8AR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL./< "l/SEC iao 025 28.046 03467 19.6638 291 429 3625.6 4943.0 69 617 35. 75 51 c9 1621

10a ,000 28.51d 0. 03507 18. 7854 280 337 3862. 4 5195.0 72. C24 35. 31 52 07 1594

110 .000 28.182 0. 03548 17. 9346 268 + 39 4104.6 5453 . 7 + 45 3 35 73 32 33 1565

115 000 27.848 03591 17. 1202 256 308 43+8. 5 5713.1 7d, 782 35. + 6 52 + 4 1637

120 000 27.514 03635 lb. 3418 24 + 177 4593.1 5974.3 7 9 01 + 35. 11 52 45 1503

125 000 27. 176 0. 03679 15.5983 232 209 . 4e37.7 6235.9 81 155 34 70 52 43 14/3

130 000 26.842 03726 1+. 8680 220 531 "'5 082. 1 6497.3 83. 211 34 33 52 46 1 + +3 135 000 26.503 0. 03773 1+.2092 209 230 5326.5 67o0.3 85 193 34 05 52 5 3 1 + 19 140 000 26. Id 3 0. 03822 13.5603 198 36b 5571.3 7023.3 87 110 33. 66 52 62 1363

145 000 25. 620 o. 03873 12.9394 187 98u 68I0.O 7230. b 90 96 8 33. 74 53 11 1 3 'j 3 150 000 25. +74 a 03926 12.3+53 178 093 6063. 1 7554.0 90 773 33. j& 53 3o 1323

lap 000 25.126 03930 11.7765 168 712 6309.7 7822.0 92 52 5 33. 29 53 46 1300

160 000 24.77d 0. + 036 11.2319 159 836 6555. 5 8089. 3 9 + 22 2 32. 30 53 3/ 1273

lb5 000 24.424 + 094 10. 7104 161 453 6799.5 6356.4 95 660 32. 06 o3 03 1249

173 000 24. U69 0+155 10. 2111 143 549 7040.6 3ol9.3 97 436 31 25 52 6 6 122/

1/5 000 23.712 0. + 217 9.7332 13d 1C2 7273.9 8881.5 96 9?3 31. 05 52 71 12 180 000 23.35+ 0. 0+282 9.27dC 129 091 7617. 7 91+4.3 10 J + 37 3 d5 52 65 117j

185 .000 22.994 + 349 8. 8387 122 494 7755.5 9406.1 101 880 30 34 52 66 1151

190 000 22. 633 0. + 418 8. +207 llD 269 7992.5 9671.5 10 3 235 30 09 32 71 112 7 195 000 22.270 + 430 8. J215 110 457 822o. 9 993 5.3 10 + 65 5 29 36 ->? .79 110 3 200 000 21.9Gc . + 665 7.o406 10 + 977 046+. 3 10139. + 105. 992 29. 71 52 63 10/9

205 .000 21.542 04642 7.2771 99 834 6700 .2 10 4O+.2 10/ 300 29 57 53 UO 10 5'j 210 JGO 21.176 + 722 b.9307 95 13 6935.2 10 729.5 108 57 6 29. + 6 53 13 103 + 215 000 20.013 0. + 805 o. bu 10 90 500 9169.7 1G995.5 109 830 29 37 53 27 1011

220 000 20. + + S o. 0+890 6. 2372 8b 284 94U3.8 11262.1 111 056 29 09 53 20 992 225 000 20.084 04973 S.989u 82 353 9636. 3 11526.3 112 253 26 97 53 27 97 1 an 000 19.721 05071 5. 7059 70 d90 98o8. 11734.9 113 42 4 28 90 53 3 7 952 235 000 19.359 0. 05165 5. +371 75 3C7 10099.2 1 2 d 2 . 11 + 57 3 28 38 53 43 932

2 + 000 18.999 0. 05 26 3 5. 1624 72 172 10329. 12329.8 113 701 28 39 5 3 .63 914

245 000 18.642 05364 +.9411 69 283 10 559.9 125+6.3 116 O08 28 93 i>3 7/ 8?D

250 JQ0 18.286 03469 4. 7127 6d o29 10789. 5 123o7.6 11/ 896 26 99 ?3 91 8 79 255 000 17.93+ a. 0557o 4. + 96b 6 + '2 01 11018.6 13137.5 118 965 29. 06 54 05 362

2o0. 000 17.586 05636 4.2923 61 98/ 11247.2 13408.0 12 J 016 29. 18 54 1/ 04/ 2o5 000 17.242 05600 + . u994 59 979 11475.3 130/9.2 121 049 29 31 5 4 ?i 832 270 000 16.9U3 5 916 3.9172 50 164 11702. 7 13 350 .8 122 064 29 44 5 + .37 olo 275 J00 16.569 0. 0o035 3.7453 6o 533 11929.4 1+222.9 123 06 3 29 59 5 + + 5 60 j 280 000 16.240 Q6157 3.5831 55 076 12165.4 14435.3 124 044 29 75 ->4 6 J 795

285 000 15. 910 0^282 3. +302 53 780 12380.6 l+7o7.8 12j 009 29 92 2 + 62 7 A2 29J 000 15.603 Co40l 3. 28bfl 52 636 12605. C 160+0.5 125 95 7 30 10 ? + j3 771

2 95 000 15.294 0- 06658 3. 1501 51 o38 12823. 5 15313.

1

126 89 30. 2e 34 52 761 300 000 14.993 Got70 3. U221 50 770 13051. 1 1553 5 . o 127 606 30 + 7 5 + 43 762 310 000 14. +13 0. 06933 2.7878 49 396 13+93. 3 1612 9.9 129 590 3C 38 54 3 6 t3o 320 uGO 1 3. 6b4 07213 2.6799 40 450 13931.7 lco/2.5 131 313 31, 30 5 + 17 72 i 330 000 13. 340 0< 07492 2. 3954 47 86b 143bo.

3

17213.2 132 977 31. 75 33 95 712 340 .000 12. 663 07774 2. 2313 47 590 14797.4 17751.5 13 + 584 32 21 53 71 70j

35J 000 12. +10 u 03058 2. 0853 47 578 16225.3 1623 7.3 13b 137 32 09 53 46 6 9 -j 360 .000 11.98b 033 + 3 1.9551 4 7 .786 15653.5 18820.7 137 6+0 33 18 53 22 691

370 000 11.591 0. 03627 1.6388 48 163 16073.5 19351.8 139 095 33. 06 5 3 01 667

380 OuO 11.223 03911 1.7344 40 718 lb«9+.9 19831.0 14 506 3 4 20 52 6 3 68 3 390 000 10. 070 03193 1. d+06 49 344 16915.4 20+06.5 1 + 1 876 34 72 52 o3 d63 400 .000 10.557 0, 09+73 1.5=59 50 017 17335. 5 20935. 1 1+3 209 3 6. 25 5 2 62 632

420 .000 9.973 10027 1.4093 51 438 18175.9 21937.2 145 776 36 32 62 b i d62

4*0 .000 9.457 1J57 + 1.2069 52 .922 19023. 230+1. 3 140 228 37 41 52 81 682 4o0 .000 8.997 0. 11115 1. 1836 54 + 62 19676.7 2+1J0.3 150 532 36 50 33 12 68 + 480 000 8.585 11646 1. 0953 56 083 207+0.1 25166.5 162 65 39 58 ? 3 62 69/ 500 .000 6.21 + 12175 1.0191 57 793 21615.0 262 + 1.

+

155 0+ + 40 66 5 3 98 692

197
ME THANE ISOdAR AT P = = *00.0 BAR

T DEN VOL OP/OT OP/OO E H S CV CP H DEG < MOL/L L/MOL BAR/K BAR-L/MCL J/MOL J/HOL J/HCL/K J/MOL/K J/.10../< i/SEC

1U0.*96 23. OOU 0. 03*63 19.617* 293.083 3 635 5 5020.5 69 606 35 86 51 69 lo23 105.000 28.587 03*98 13. 8370 283.552 36*8 b 52*7.9 71 8o0 35 93 52 OJ 1600 110.000 28.25b 0. 5559 17.9976 272.03* *C89 .8 55 J 5 . 5 7* ,236 35 3* 52 2 5 1572

115. 000 27.925 05581 17. 1933 260.213 4332 8 57o5.2 7o .611 35 59 52 3* 15**

120. JOu 27.595 0362* lb. *2*0 2*3.332 *576 3 6025.3 73 839 35 22 52 3* 1517 125.000 27.26-. 03663 15.0388 23o.570 4619 7 6266.8 8 97* 3* 80 52 30 1*8-3 130. JuO 2c. 932 03713 l*.98t3 225.057 5G62 8 o5*8.

1

83 C26 3* *3 32 32 l*6fl 135.000 26.598 03760 14.31*8 213.389 5305 9 50J9.8 85 002 3* 15 52 43 1*31 ltO.OUO 26.2b<i 05603 13.o7 26 203.132 55*9 3 7072.* So 912 33 96 52 6* 1*J1 1*5. ooo 25.925 03857 13.0562 192.829 5793 ,4 7336.3 83 76* 33 33 52 ,91 1 371 150 . JUO 25. 585 03909 12. 4702 183. 0G6 6033 1 76J1.5 9J 562 33 08 5 3 . 15 13*2 155. JuO 25.2*3 03961 11.9072 173.676 6283 7 8o 7 • o 92 307 33 39 i3 25 131*

160. 000 2*. 899 0. 0*0 lc 11. 3o80 16*. 639 6527 2 6133.7 93 99 6 32 39 53 12 123 i 165.000 2* . 55* 0*073 10.8517 156. *87 6769 ~, 8398.5 95 626 32 17 52 7 3 12o3

170. JOO 2*. 20b 0. 0*131 1J. 3372 1*8.60* 7003 6 8631.1 9/ 19* 31 3* 52 23 12* i 175.000 23.857 0*192 9.3039 1*1.17* 72*5 1 6921.6 93 70 3 31 13 52 * 1 1217

160 . JOO 23.5Gb c * 2 5 * 9.4308 13*. 176 7*61 9 9133.6 103 173 30 7* 52 53 1135 135.000 23.15* 0. 0*319 8. 997* 127.567 7717 o 9**5.2 101 612 30 42 52 32 llo J 190.000 22. 8G1 0*336 6.583G 121.386 7952 t 970 6.9 103 OJ 7 3G 17 52 35 11* > 197.000 22. **7 . 0**55 8. 187C 115.55* 818o 8 9968.8 10* 36 8 29 96 3 2 * 1 1123 200.000 22.U92 < 0*526 !

,

8068 110.070 642J 4 10231.0 105 695 29 78 52 *3 110 J 2u5. J 00 21.736 0. 0*600 7.**79 1C*.910 6c53 c. 10*93.6 106 9*2 29 5* 52 58 10 77 21 J. OOU 21. 3B3 o. 0*677 7. U30 100.082 0666 1 1J75D.7 103 261 29 52 5 2 63 13 5-3 215.000 21.028 0. 0*75o c.7758 95.5*8 9118 2 11020.* 10 3 502 29 *3 32 7 3 10 3* 22J.O0O 20. o?* 0. 0*837 6.4635 91.303 93*9 8 1123*.

7

11

J

717 29 16 52 7 J 101*

22j. JOO 20. 32u 0*921 6 . lbt 3 87.33b 9579. 8 1 15*6. 3 11

1

90 1 29, 03 52 73 995 230.000 19. 9oo 05008 5. 6838 83.637 9809 11812.2 113 Uo2 28 96 52 03 975 235. JOO 19.617 05 098 5.6155 80.196 10037 6 12J76.7 11* 1 *9 28 93 >2 9* 93 j 2*0. JOO 19.266 o. 0519J 5

.

3oC 7 7/. 0U2 10265 6 123*1. 7 11? 315 20 *3 53 L 3 93o 2*5. OuO 18.921 0. 05233 5. 1190 7*. 0*7 10 493 2 126j7.3 lit, 410 28 97 3 19 -321 250. JOO 13.67i 0. 5 333 4. 0898 71.321 1G720 3 12873.6 11/ 436 29 0* 53 3? 90*

255. 000 18.235 05 *3* *.6727 68.61* 109*7 1 31*0.5 110 5*3 29 12 5 3 *3 c o f 2oO. 000 17. 898 0. 05537 *.*c.71 6b. 517 11173 2 13*08.1 11 3 58 3 29 2 3 5 3 6 3 972 2o5. OOJ 17.^6* 0. 0569* *. 2725 6*. 419 11398 9 13d76.3 123 60 * 29 3 5 3 3 c 3 85/ 270. JOO 17.23* 0. 05802 *. C065 62.512 1162* 1 139*5.0 121 609 29 *8 53 79 8* j 275.000 lo. 910 0, 0591* 3.91** 60.765 ne*8 7 1*21*.

2

122 597 29 = 3 3 5 b7 S3 J 2b j. JOO Id. 591 03028 3.7*99 59.229 12G72 7 1**3 3.7 123 666 29 70 33 9* 818 265.000 lc. 277 a. Jil** 3.59** 67.63* 12296. 1 1*753.6 12* 52 3 29 J6 5 3 * -i 8 jo

290.000 15.9c9 0, 05262 3.**76 5c. 590 12518 8 15023.6 125. *6 3 30. 1* 3* o 3 795 295. 000 15. oca 0. 0d383 3.3088 55.*87 127*0 8 152 93.8 126 33 6 30. 33 3*. G 1 765 300. QUO 15.3/3 0. 05505 3. 1778 5*. 518 12962 165o4. J 127 29* 30. 52 5 * G i 77o 310.000 1*. 8G* 0. 0o75? 2.9373 52.9*3 13*02 2 161J*.2 129 066 30. 93 5 3 Hi 7 5 -j 320. JOO 1*. 2b* 0. 07C11 2. 7229 51.797 13839 ? 15o43.6 130 778 31 36 3 3 o 3 7*3 33J. JUO 13. 753 07271 2.5317 51.021 1*273. 1 1713 1.6 132 * j* 31 32 3 i 7 5 7 33 3*3 .000 13.271 0. 07 535 2.3611 50.561 1*70* 1 1/716.2 13* 036 3? 28 33 i, ,» 725 330.000 12.819 0, 07831 2.2G86 5U.371 1513 2. 5 11253. 135 636 32. 77 33 39 71; 3oO. JOO 12.39* 03C68 2.072U 5G.412 16 553 6 18/35.0 13/ 038 3 3 26 j 3 22 7J j 3 / J . J 11.996 0< C3336 1. 9*96 50.650 15983, 19317.5 133, 5** S3 77 53 Go 7 J, 330.000 11.62* 0. 03603 1.8395 51.052 16*06 1 1 38*7.* 139 96 7 3*. 29 5 2 95 701

3-40. JO j 11. 276 o. G3869 1. 7*L2 51.581 16626. * 2037o.l 1*1 33 3* 31 5 2 82 o93 *J0. JOO 10.9*8 C < 313* 1.6605 52.197 17250 * 2J9J*.0 1*2. 667 35 3* 5 2 7 j c97 420. GOO 10. 36* 0. 09658 1 . *^)*9 53.550 18 095 8 21959.0 1*5 2*0 36. *2 52 7/ B i j **0. JOO 9.327 0, 10176 1.3651 5*. 982 189*5. 8 2 3016.1 1*7. 699 37. 5l 32 93 b9o

*oJ. JOO 9. 350 0. 10c8u 1. 2553 56.*f3 19603 5 2*0/6.1 150 05 9 30. 51 3 3. 2/ 59/ *8J .000 8.936 0. 11191 1. 161* 57. 393 2G6/0. 9 251*7.* 152. 336 39 o° j3 6/ 63 J 5J0.000 8.555 0, 1169J 1. 0603 59.597 215*9 6 26225.5 15* 535 *G, 77 3* IS 702

198
Ml THANE ISOBAR AT P = 450.0 BAR

T DEN VOL OP/OT UP/DO E H S CV CP •A DEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

101.,667 28.963 0.,05453 19.6048 296.994 3660.,7 5214.4 69. 827 36. 15 51. 67 1627

105,,000 28.761 0.,03477 18.9561 291.033 3815.,6 5330.2 71,,46 36.,20 51,,87 1612

110., 000 28.437 o. U3517 13. 1449 280.522 4054. 6 5637.1 75,,879 36.,11 52.,03 15S3

115,,000 28.114 0.,03557 17.3653 269.617 4295,,2 5035.8 76., 196 35,,85 52. 13 1563

120,,000 27.792 0.,03596 16.6182 258.301 4536,,2 6155.3 76.,414 35. + 8 52. 9 1537

125,.000 27.471 0., 03640 15.9032 247.079 4776.,9 6415.0 80. 538 36. 06 52. 02 1512

130,,000 27. 146 0., 03633 15.2193 23o.003 5017.,2 6o74.7 82,,57 6 34. 68 51. 99 1465

135,,000 26.62b 0., 03728 14.5650 225.185 6257,,2 693+.

7

8 + , ,5+1 34,, + 52,,07 1 + 53

1*0.,000 26.502 0. 03773 13.9390 21+. 70b 5497.,5 719 5.5 86. 43 8 34,,21 52.,25 143d

145,.000 2b. 176 0,,03820 13.3398 204.621 5738,,2 7457.3 88,,275 34,, J7 52,,48 1 + 02 150.,000 25. 850 0.,03869 12.7661 194. 9o8 5979,,4 7720.2 90,,058 33.,91 52, b3 137-. 155,,000 25.522 0.,03918 12.2165 185.767 6220,,6 7933.9 91,,786 33..62 52. 7 + 1346

160,,000 25.192 0,,03 97 ll.b900 177.027 6461,.0 8247.3 93,,459 33,, 11 52. 53 132 + lop.,000 2*. 061 0..0+G22 11.1855 168.746 bb99,,2 8509.2 95. 071 32. 38 52. 18 1302

170,,000 24.529 0,,04077 10.7021 160.916 6934,,3 8756.8 95.,621 31,,65 51,, 66 1282

175,,000 24. 196 0,,04133 10.2390 153.523 71bo,.6 902D.3 98,, 111 31,,34 51., 7 5 1257

iao,.000 23.062 0,, 04191 9. 7965 146.549 7399,,0 9284.8 93,, 5o7 30,,94 51,,63 123j

185,, J00 23.»28 0,,0+250 9. 3708 139.97+ 7630.,2 95+2.8 100. 981 3C,,62 51, 53 1212

190,,000 23.193 0,, 04312 8.9643 133.779 7 860,,4 980 0.7 102,,357 30,,36 51,,57 119

145.,000 22.656 0.,0+375 0.5764 127.943 8 089,.9 10058.6 103,,c97 3C 1 + 51. 59 116 8 200,,000 22.223 0.. 044 + 8. 2U36 12 2.44 7 8318,.6 10316. 105,, 003 29,,96 51,,63 1147

205,,000 22.180 0., 0+507 7.8+62 117.272 6546,,7 105/+.9 106,,27 9 29,,8C 51,,b3 112o

210,,000 21.85v 0.,0+576 7.5068 112.403 8774.,3 10333.4 10 7., c-2 4 29. 08 51., 7 + 1105

215,,000 21.520 0.,0+647 7.1847 107.323 90C1.,2 110 3 2.3 103,,74 3 2 9. 58 51. 61 ludj

220,,000 21.187 0., 0+720 6.8755 103.519 9227.,5 11351.4 109,,935 29,,30 51,,68 106 7 225,,000 20.856 0.,0+795 6.58C7 99. +79 9452,,2 11&J9.8 111.,G9o 29,,17 51,,63 10 + O 230.,000 20.526 0. + 672 6. 2997 95.o91 9676. 11868.4 112,,232 29,,09 51,,73 1J3j

235,,0u0 20.198 0,, + 951 6.0320 92.145 9699,,2 12127.2 11 5,,346 29,,U6 51,,60 1012

2*0,,000 19.871 0,,05032 5.7772 83.632 10121,,9 12336.4 114,,437 29,,06 51,,8 3 99 + 2*5,,000 19.5+7 0.,05116 5.5347 85.742 1034+.,1 126+6.2 115. 508 29. 09 52., 00 977

250,.000 19.226 0,,05201 5.3041 82.867 10565,.9 12906.5 116,,560 29,,15 52,, 11 961

255..000 18.907 o. 05233 5.0848 80.197 10787,,3 13167.3 Hi'.,59 3 29,,23 52,,23 94 J 260,,000 18.592 0,,05379 4.8765 77.725 11C08,,4 13428.3 113,,609 29,,34 52,,35 93 265,,000 18.26G 0., 05470 4.o765 75. +42 11229,,2 13o90.8 119,,607 29., + 6 52,,47 91:, 270,,000 17.972 0, 05664 4. 49o5 73.339 11449,.6 13953.5 120,,589 29,,59 52,,53 9dl

275,,000 17.668 0., 05660 4. 3120 71. + 09 11669,,6 14210.6 121,,554 29,,74 52,,b3 833

260,,000 17.368 0.,05753 4. 1426 69.o42 11889..3 1+430.3 122,,504 29,,91 oZ,,7j b7i> 265,,000 17. 073 0.,05657 3.9818 68.032 12108.,7 147++.4 123,,439 30,,0b p2.,86 Oc 3 290,.000 16. 783 0.,05958 3.0293 66.569 12327,.6 15008.9 12 + ,,359 30,,26 52. 9 + 852

295,, 000 16.496 0., 06061 3. 6646 65.245 12546,.2 15273.8 125,,26 5 30,,45 53,,01 041

300,,000 16.216 0,, Ooloo 3.5+73 64.052 12764,,3 15530.9 126,,156 30,,65 53,,0 8 51 310,.000 15.c7u 0,,0o379 3.2936 62.032 13199,,3 16J69.9 127,, 897 31. 07 53.. 1 3 315

320,,000 15.157 0,,06698 3.0o53 60.447 13632,. 5 1660 1.5 129,.58 5 31.,52 53,. 17 7)7 330,,000 14.b62 0,, 05820 2.3598 59.2+4 14C6+,,0 17153.2 131,,221 31,,98 53,, 1' 73 + 3*0,,000 14.191 0,,070+7 2.b748 58.372 14493,,9 17oo4.o 132,, 80o 32,, + 6 j3,, 15 77 2 350,,000 13.745 0., 07275 2. 5080 5 7.787 14922,,3 18196.2 134.. 34 3 32,,95 53,,12 762

360,,000 13.6^S 0,,07505 2.3575 57. + 43 15 349,,6 18727.2 135,,8+4 33,,+b 53,,03 75 + 370,,U0fl 12.924 , ,07737 2. 2214 57.323 15776,,0 19257.3 137,,296 33.,96 5 3.. 05 7+7

380.,000 12.546 0.. 07970 2. u983 57.382 16201,,9 19788.2 133,,713 34,,50 5 3,,02 741 390,.000 12.193 0,,03 232 1.9865 57.o00 lb627,,6 20316.3 1+0.,090 35,,04 53,,C1 7 j7

400,.000 11.856 0,, 03433 1. 8849 57.956 17053,, 4 20848.4 141,,+32 3T,,58 53,,02 73 + 420,.000 11.244 0,,0 389+ 1.7079 58.982 17907,,2 21909.+ 144,,020 36. 67 53. Id 7 3d

+ + ,. 000 10.696 0,, 09349 1.5596 60.254 16766,.0 22973.1 145,,494 37,,76 53,,23 72 3 460,,000 10.205 0,,09799 1.4339 61.617 19632,,3 2+0+1.3 143,, B6 9 38,,86 53.,60 72o

460,.000 9.763 0,,10243 1.3263 63.026 20508,, 4 25117.7 151,.159 39,,95 5+

,

,01 729

500,,000 9.361 0,. 1J632 1.2332 6+.+67 21395.,6 2620 2.6 153,,37 3 41.,03 54.,49 731

199
HE THANE IS06A* AT P = 50C .0 eAR

T OEN VOL OP/DT DP/DU c H S CM CP A OEG k MOL/L l/MOL BArt/K BAR-L/MOL J/10L J/MOL J/MOL/K J/MOL/K J/10L /< i/StO

102 826 29. 0*6 0. 03**3 19. 3970 3C0. 586 368o 8 5*08.2 70. 0*8 36. *2 51 67 1631

105, 000 28. 931 0. 03*56 19. 0ol6 297. 687 378* 6 5512.8 71. 072 36. *6 51 7/ 1623

110, 000 26. 613 0. 03*95 Id. 2763 288, 27* *021, 6 57o9.1 73, *85 3fc. 37 51 9- 1602

115. 000 28. 297 o. 0353* 17. 5230 276 159 *260, 1 6027.1 75 795 36. 11 51, 93 1580

12J 000 27. 982 . 0357* lo. 7975 267 06* **93 8 6285.0 73. 005 35 72 51 88 1537

125. 000 27. 669 0. 0361* lo. 1U19 257 027 *737 1 65**.

2

80 121 35. 30 51 77 1533

130, 000 27. 356 0, 03656 15. *357 2*6

.

*25 *97* 8 o802.c 82 150 3*. 92 51 72 1508

135. 000 27. 0*2 0, 03o9d 1*. 7978 23? 987 5212 2 70ol.l 8* 102 3*. 63 51 75 1*83

It J 000 26. 729 0. 37*1 1*. ldt9 225 81U 5**9 6 /320.2 85 98 7 3* ** 51 90 1*5' 1*5 000 26. *1* 0. 03736 13 oul8 215 963 5667 3 Z58G.2 67 812 3* 30 52 13 1*30

150, 000 26. 099 0, 3 832 13. 0*12 20d •93 5925, * Z8*1.2 89 591 3* 13 52 27 1*0-

155 .000 25. 763 03679 12. pu39 19/ *31 6163 5 810 2.8 91 29 6 33 d* 5 2 3) 13/9

loJ 000 25. *6? 0. U3927 11. 9889 18o 79* 6*00 5 8363.9 92 95* 33 33 52 11 135d

lo5 000 25 1*8 0. U3977 11. *951 180 567 o635 2 862 3.5 9* 552 32 59 51 c3 1)3;

170 000 2*. 829 0, 0*C28 11. 0216 172 8 08 6866 8 98du.5 9-3 086 31 75 5 1 1* 151/

1/5 000 2*. plO 0, 0*08u 10, 5677 165 **8 7095 * 913 5.* 97 56 1 31 5* 51 23 129- 18u J00 2* 190 0, 0*13* 10 1325 153 *9* 732* 9391.0 99 001 31 13 51 Uo 12/5

185 000 23, d71 0, 0*189 9, 7155 15 1 926 7551 *t 96*6.0 100 39 9 30 31 5 93 1252

140 000 23, 551 0, 0*2*6 9 3159 1*5 732 7777 .8 9900.8 101 758 30 p* 50 9- 1231 195 OuO 23. 231 0. 0*305 d. 9332 139 d88 8003 ,2 1 0155.5 103 081 30 31 50 93 1210 200 000 22. 912 0, 0*36* d 5668 13* 376 8227 9 10*10.1 10. 37 30 13 50 93 1193 205 000 22, 59* 0. 0**2o 6, 21tl 129 179 6*51 9 1066*.

8

105 62 8 29 97 5 95 11/L 210 000 22. 276 0, U-*39 7. 6807 12* 27 9 6675 .2 10919./ 10a 856 29 8* 50 99 1151 215 000 21. 96G 0. 0*55* 7 5600 119 o60 8897 .8 111/*./ 108 05/ 29 73 51 I 3 1131 220 000 21 D*5 0*620 7 253* 115 308 9119 9 1 1*29.9 109 230 29 -* u 8/ 111- 225 000 21. 331 0.693 6 , 9605 111 210 93*3 ,2 1163*.

2

113 37 3 2 9. 31 5 85 109/ 230 000 21. 019 0. 0*758 b 6808 107 353 9559 ,7 11938.5 11 1 *91 29 23 50 8? 10/

j

23i OuO 20. 709 U*829 6 *138 103 727 9778 6 1219 3.0 112 586 29 19 -> C 9? ICo? 2*0 000 20 *01 0*902 6 1590 1C0 323 9996 9 12**/.

3

11 3 659 29 19 p0 ,99 1C*5 2*p .000 20, 09S 0, 0.97o 5, 915 9 9/ 129 1021* 6 12703.0 11* 711 29 22 j1 03 102 9 250 000 19 792 05053 5 63*1 9* 139 10*32 .3 129:58.

7

115 7** 29 28 -.1 13 1013 2>i 000 19. *91 G 05131 o , -o32 91 3** 1C6*9 6 1321*. 3 116 758 29 36 51 29 99/ 260 000 19, 19* 05210 5. 2s2b 6d 735 1 Boo .5 13*71.6 11/ 7p6 29 t6 5 1 *C 932 265 000 18 899 o. 05291 c 0520 6o 3Co 11C83 3 13/28.9 113 736 29 58 51 52 9oi 270 000 Id. 608 0, 033/. -+ 9bC9 6* 0*9 11299 8 13936.8 11 9 700 29 71 51 6 3 95- 275 000 18. 321 o. 0^*58 *. 6789 61 95/ 11?16 1 1*2*5.2 12 3 6*8 29. 86 51 75 9*1

280 .000 Id. 03/ 055** * 5056 80 021 11732 > 2 1 * 5 * . 2 121 58? 30 03 jl 60 923 Zb3 000 17 /56 05631 * , 3*05 7d 236 119*9 2 1-7 a 3.

8

122 531 3C 20 51 9

' 91

3

290 000 17 *B3 05720 * ld3* 76 .593 12163 ,9 15023.9 123 *05 3C 39 52 7 90- 295 000 17 212 0, 0581C *. 339 75 08/ 12379 5 152a*.

5

12* 29 6 30 58 52 16 833 300 000 16 9*b 05901 3 8915 73 /09 1259* 9 15 5*5 .5 125 1/3 30 /e -, 7 25 8ai 310 OUO lo *27 0oC87 3 o271 71 3 15 13C25 1 I6G06.8 12u 339 31 21 3 2 *3 a 0- 320 000 15 929 0o2?8 3 3B7* 69 357 13*5* 5 16593.5 129 555 31 06 ->2 5 3 0-,' 330 .000 15 , *51 03*72 3 1/02 6/ ,78b 13883 .2 1/119.3 13 J 1/3 32 1* v2 6 J 832 3*0 OuO 1* 993 0a670 2 9733 66 557 1*311 3 176* o.l 1 31 7*6 32 o3 52 7? 81 i 350 .000 1* 557 0?870 2 7^*5 65 027 1*739 . e lbl/3.6 133 27 s 33 13 p2 79 807 360 000 1* 1*2 7 U 7 1 2. o321 6* 95a 1; 166 l ld/Jl .8 13* 7o3 33 65 >2 85 7s7 370 .000 13 7*o 0/275 2 *e** 6* 516 15593 3 19230.6 13? 211 5* 17 52 91 76 3 380 000 13 371 c 0**79 2 3-99 6* 271 16C20 6 19/59.* 13/ b23 3* 71 j2 9/ 7-31 390 OuO 13 015 07633 2 2272 6 * 199 lt**8 .2 20290.0 139 000 35 25 ~j3 0* 77 400 000 12 67 7 0/888 2 1151 6* 277 16876 .6 20820./ 1*0 3** 36 aO 53 12 7 71 420 00J 12 u53 0:1297 1 918* 6* 310 17736 5 21896.0 1*2 9*0 36 90 5 3 31 7 0* **0 .000 11 *91 08703 1 7 3 25 65 736 186.02 * 22953.7 1*3 *2 6 3f 00 i3 r j 7c3 *o0 .000 10. 98* ,0910f 1 oll3 6b 918 19<-/6 1 2*028.3 1*/ 81* 39 10 o3 90 753 *80 .000 10 ,525 .09501 1 *902 6d ,21d 2 359 .6 25110.1 153 116 *0 20 5* J J 7?d 500 .000 10 108 09833 1 385* b9 5tb 2125* .2 2620 0.8 152 3*2 *1 ?7 5* 7

' 7ol

200
METHANE ISOBAR AT P = = 550.0 BAR

T OEN VOL OP/OT OP/DO E H S CV ' CP w DEG K MOL/L L/MOL BAR/K 8AR-L/M0L J/MOL J/MOL J/-10L/K J/NOJK J/MOL/K 1/SEo

10 3..974 29.126 0,,03433 19.2938 303.866 3713,,5 5601,.8 70.,269 36.,66 51. 67 16 34 105,,000 29.097 &,,03437 19. 1640 303.467 3755,,3 56+5 , 5 73,,695 36,,71 51, 71 1652

110,,000 28. 78 + 0,,0347.+ 16.3967 295.260 3990,, 6 5901,,4 73,, 104 36,,61 51,,6 + lcl + 115,,000 28.474 0.,05512 17.cb76 286.116 4227., 1 ol58.,7 75. 408 36. 35 51. 6a 1595

120,.000 28.166 0,. 03550 16.9o32 276.407 4463,,8 6416,.5 77,,611 35,,96 51.,71 157 + 125,,000 27.860 0,,03589 lb. 2865 266. +08 4699..9 667 +

,

,1 79.,719 35. 53 51, 67 1552

130,,000 27.555 0,,03629 15.6373 256.322 4935,1 H e931,.4 81,,7 + 35,,15 51,,48 1533

135.,000 27.250 0. 03670 15. 0149 24b. 300 5170. 3 7138,,7 83,,633 34.,35 51,,49 1503

140,,000 26.945 0,,03711 14.4184 23b. 455 6405,,2 74 + 6,,4 85,,5s7 34..06 51,,61 1 + 32 U5,,000 26.6+G 0.,0375+ 13.8465 22o.869 5640,,3 7704,,9 87,,371 3 + , ,51 51, 7a 1457

150,,000 26.335 0.,03797 13.2982 217.602 5875.,7 7 96 + , ,2 89., 129 3 + . 34 51. 92 1432

155.,000 26.029 0,,03842 12.7723 208.694 6110,,6 8223,,9 90,,832 34.,04 51, 95 1439

luO,,000 25.723 0,, 03688 12.2678 200.171 634+,,9 8 + 83,,1 92,,47 8 33,,53 51. 71 1337

165,,000 25.+lt 0,, 05935 11. 783B 192.0+6 6

C 76,,6 87+0,,6 94,,063 32,.79 51,,2c, 13c3

170,,000 25.109 0.,03983 11.3194 184. 323 6805. 8995.,5 95. 58 5 31. 94 50. 69 135j

175,.000 24.802 0,,04052 10. 8738 17o.998 7030,,4 9248,,0 97,, 046 31,,72 5 0. 73 1323

180,,000 24. 496 0., + G83 10.44c3 170.062 7255,,6 9501,,2 9d,,47 3 31,, 31 50. 5 3 1303

IBS,,000 24.188 0.,0+134 10. 0361 163.503 7479,,9 9753,,8 99.,85 7 30,,99 p0,, + 7 1283

190. 000 23. 881 0., + 187 9.6427 157.304 7702. 8 1G0J5.,9 101.,23 2 30,,71 50. 41 126 9 195.,000 23.575 0,, 04242 9.2655 151.449 7924,,9 Iy257,.9 102,,511 50,, + 3 50. 37 12 + ? 200.,000 23.269 0,,0+298 8.9039 145. 92u 6146,,1 1 0509,,7 10 5,,786 3C,,29 60 , , 3-j 1230

205,,000 22.965 0., + 355 0. 3574 140. o99 8366,,5 107ol,,5 105,,029 30,,13 50. 36 1211

210.,000 22.661 0., + 413 8.2255 135.770 6586,,3 11013,,3 103,,243 3C,,00 50,,37 1192

215.,000 22. ->69 0.,0+473 7.9076 131.116 8805,,4 112o5,,3 107,,423 29,,39 5 ,,40 117 + 220,,000 22.u58 0,, + 533 7.C034 126.722 9023,,0 11517,,3 1&3,, 507 29,,59 jO,, 22 1153

225.,000 21.759 0.,0+59o 7.3122 122.575 9240.,5 11768,,3 109.,715 29. 45 50, 19 11 + 1 230,.000 21.462 0,, 04659 7.0 3 36 118.662 9456,,4 12J19,,2 11 j,, 816 29,,37 5 0,, 19 112 + 235.,000 21.16o 0,,0+725 0. 7o71 114.972 9671,,7 1227 0,,2 111,,89 8 ?9.,33 50,,22 1133

2*0,,000 20.873 0,, 04791 b.5124 111.49+ 9886.,+ 12521,1

4

112,,95 6 25,,3? 50,,28 1C92

245,,000 20.582 0,,0+85 9 o.2d89 108.219 10100,,8 12773,.0 113,.993 29., 35 50,, 35 107u

250,,000 20.294 0,, 0+928 6. 0362 105.138 10314,,8 13025,.0 115,, 31 1 29,, + 30.. + + 1060

255,,000 20.00b 0,, 0*998 5.8139 1C2.24+ 10528,, 5 13277,1 4 Ho,,011 29,, + e 50,,5 + 13 + ; 260.,000 19. 725 0,, G5070 5.o015 99.527 1C742,,1 13530,• 4 116,,99- 29,,58 50,,es 1331

265. 000 19. +46 0., 05143 5. 3967 9b. 982 1&955.,5 13734.,0 117,,9=>0 29,,70 50,,7o 1013

270.,000 19. 169 0,,05217 3.2050 94.oGl 11168,,8 1+038,,1 in,,910 29,, 34 3O . , 33 lu33

275,,000 18.695 0., 05292 5. 0201 92.377 11382,,0 1+292,.6 119,,844 29,,99 51,, 3 99 3 280,,000 18.625 0,,05 369 +.6+36 90.303 11695,,1 1+5+8,.1 12u,,764 3C,,15 51. 12 97"

285. 000 18.359 0. 054+7 +.753 88.376 11808,,2 148J4,,0 121,,670 30,,33 51,,2 + »3

290.,000 18. u96 0.,C352o 4.5142 80. 586 12P21,,2 15060,,5 122,,562 30,,51 5 1,, 3-j 953

29a,,000 17.836 0,, 0-jfcJ6 +.3o06 84.928 12234,,2 15317,.6 123,, +41 3 0,,71 51,.47 942

300.,000 17.583 0,, 05687 4.21+0 83.396 12++7.,2 15575.,2 12 + ., 307 3 0. 92 51. 53 931

310.,000 17.086 0,, 05653 3.94G6 83.685 12673,,G 16092,.1 123,, 002 31.,35 51,,79 911 320,,000 I0.6O6 0,,0o022 3.6914 78. +07 13 293.,9 16610,,9 127,,6+9 31,,31 51.,96 89 + 330,,000 lb. 144 0,, 06194 3. +643 7b. 517 13724,,8 17131,,5 129,,251 3 2,,29 52,, 15 37 3 3*0., OOu 15.701 0,,0o369 3.2572 7+.97+ 14150., B 17653,,6 133.,811 32, 79 52. 3 1 8o3

350,,000 15.276 0,,06546 3. 0682 73.739 14577,,1 18177,, 6 132,, 329 33,, 30 52,.45 351 36J.,000 1+.669 0,,05726 2. 8966 72.775 15003,, 6 16732,,3 133,,30 3 3i,,63 52,.59 6 + G 370.,000 14.480 0,, Go93o 2.7377 72.050 16430,.9 19229,,, 133,,251 3t,,3b 52,.72 830 380 . 000 14. 109 0. 07088 2.5933 71.53+ 16858.,9 19757,,2 13o,,659 34,,90 52,, 35 822

390.,000 13. 75-, 0-,07270 2.46C9 71.203 16267. 7 20236,,4 13d,, 033 36,,45 52,,9d 81 + 400,,000 13.417 G,, 07453 2.3395 71.033 16717,,6 2 81c,.9 139,,376 3b,,00 53,, 12 8o3

•20,, 000 12.789 G,,07819 2.1251 71.099 17561,,8 21382,. 3 141,,975 37,, 11 53, 42 79 9 440,.000 12.220 0,, 0113 + 1.9430 71.6C6 16+53,,1 2295,,,1 1 + + , ,+08 38,.23 63.,7o 792

4oO., 000 11.702 0.. 03546 1.7872 72.452 19333.,0 24053,,0 146,, 3d 6 39,,33 54,, 1'* 7 3,3 1*63,,000 11.231 0.,0390+ 1.6530 73.343 2G222,,9 2612 0,,0 149,,179 4 0,, + 3 5 4. 3 7 7o7 500.,000 10.801 0.,09258 1.5366 74.775 21124,,0 26216,,0 161,,416 41,,51 55,, + 7 8-j

20 1
M£ THAN£ ISOBAR AT P = oOO.O BAR

T DEN VOL OP/DT DP/DO F. H S CM CP A OEG K MOL/L L/MOL BAR/K 8AR-L/MOL J/MOL J/MOL J/+OL/K J/MOl/K J/IOi. /< -l/SEC

1 J3. 111 29.206 0. 03+2 + 19.1951 306. 828 37 + 0. 9 5795. 3 70. +90 36. 88 51. 63 1637

110. 000 28.^52 0. 03+5 + 18.5071 3C1. + 36 3961. 3 6033. 7 72. 73 3 36. 85 51. 75 1625

115. 000 26.6it6 0. 03 + 91 17.7999 293. 358 + 196. 1 6290. 6 73. 033 36. 58 51. 71 160d

120. 000 28.3++ 0. 03528 17. 116+ 28 + . 511 + + 31 65+7. 8 77. 231 36. 18 51 \j

-y 159J

125. 000 29. 0*5 0. 03566 16. +582 275. 211 + 665. 1 680 + 6 79. 332 35. 75 31. + 1570

130. 000 27.7+b 0. C360 + 15.82S.5 265. 69U + 898, 5 70ol 81, 3+6 35. 36 31. 29 1550

135. 000 27. ++9 o. 03t + 3 15.2181 256. 125 5131. 3 7317 2 83. 28 35. 06 31. 27 1523

1+0 000 27.152 0. 03683 1+.6352 2+6 o + 5 5363 9 7573 7 85 1 + 6 3 + 86 51 35 15U3

1 + 5. 000 2o. 655 0. 0372 + 1+. 0759 237. 3 + 9 6596. 6 7830 8 86. 951 3 + . 72 51. 53 1 + dl 150. 000 26.659 0. 03765 13.5391 ?28. 309 5829 5 8036, 7 86. o99 3u. 5 + 51 c2 1 + 53 155. OuO 26.2b2 o. 03803 13.02+0 219. 57 + 6062. 2 83 + o 8 90. 39 2 3h. 2 + 51. 60 l + 5o 160, 000 25.96o 0. 03d51 12.529+ 211 180 6293. 6 36J + + 92. 027 33, 72 3l 3s 1 + 1'j l03 000 25.669 0. 0389o 12.05+5 203, i if a 6522 6 88b0 1 93, cOl 32 98 5C 6~i 1393

170. 000 25.372 0. 039+1 11.5985 195 + 89 67 + 8 3 9113 95 11 1 3Z 13 50 30 1331

175. 000 ii. 07b 0. 03938 11. Ib05 188. 2C5 6970 8 93o3 6 9 j, 561 31 90 3 o 32 1 3o0 iao 000 ZW. 77 + c, + 03b 10. 7+00 181 292 7193 3 961 + 7 97 576 31 + 9 5 1- 13-1 ld5 000 2<i.it6i 0. 0+08 + 10. 3361 17 + 7 + 1 7 + 1 + 5 9865 1 93 3+8 31 16 50 hi 1322

130, 000 24. 168 0. 0+13 + 9.9+6+ 168 539 763 + 5 10115 1 100. odl 30 38 + 9 55 130+ Ub 000 23.893 0. + 135 9.5761 162 d73 7653 ,£ 103o + ,7 101 97 8 3C 65 + 9 93 1235

200. 000 23.599 0. + 237 9. 2169 157 125 8071 7 1061*1 1 10 3 2+1 30 + 5 + 9 07 126' 205 000 23.307 0. + 291 3.3762 151 881 8289 1 lu3a 5 5 10 + + 72 3C 29 + 9 83 12 + 3 210 000 23.015 0. + 3 + 5 d. s+75 1 + 923 8505 6 11112 8 103 = 7 + 30 15 + 9 85 1231

215, 000 22.725 0. + + d.2322 1+2 235 8721 .6 113o2 ,1 103 8+7 3C, 03 + 9 87 1213 220 000 22.+3b c + + 37 7.9300 137 803 8937 ,2 lloll .+ 107 9 3 + 29 7 + + 9 68 1133 ZZi ooo 22. 1 + 9 0. + 515 7.6+03 133 ol3 9150 8 11659 7 103 lib 29 59 + 9 t.3 1132 230 000 21.66'. 0. + 57 + 7.3b28 129 o52 9363 .6 121J7 ,d 110 20 1 2 9 51 + 9 62 11C3

235, 000 21.582 0. + 63 + 7.0 9t9 125 90 8 9575 8 12356 111 268 29 + 6 + 9 b 5 1153 2*0 000 21.301 0. + 635 6.6+22 122 370 9787 . 5 12b0 + .3 112 31 + 29 + 6 + 9 63 113 + 2 + 5 000 21. 022 0. + 757 o.598+ 119 028 9998 9 12855 0- 113 339 29 + 8 + 9 73 11 Id 250 000 20.7+7 0+620 fa. 36+9 115 87 + 1C209 .9 13102 11 + ,3+5 2<< 53 -.9 6-. 110- 255 .000 20. +75 0, + 88 + 6.1+15 112 898 10+20 7 13351 + 115 333 29 61 + 9 9 + 1033 2o3 .000 20.203 + 950 5.927b 110 095 10631 + 13601 .3 116 3J + 29 71 5 u 10 73 2o5 OuO 19.93 5 0501b 5.7229 107 + 56 ioe+2 ,0 13851 .6 117 258 29 33 50 15 loCl 270 000 19. o7C 0, 0503 + 5.6271 10 + 37 + 11052 > c 1 + 132 .9 118 196 29 96 50 2 7 lC-,0 275 .000 i3.+oa 05152 5.3397 102 6 + + 11263 ,1 1 + 35 + » D 113 120 30 11 50 3t 103a

26 J .000 19. 150 05222 5. 1605 ICO + 58 11+73 .7 l+6Jo 9 120 ,029 3 20 50 .52 1C22 265 000 18.895 0, 05292 +. 9889 98 + 12 1166 + 3 1 + 859 8 12J 92 + 3C + 6 50 65 131 j 290 ,000 18.o+3 0, 0533 + +.62+9 9o + 99 11895 15113 .3 121 30o 3 b + 50 17 993 235 000 Id. 395 05 + 36 +.6b79 9 + .715 12105 , 7 153o7 .5 122 675 3C 3 + 3 91 $37

3 u 000 18. 150 05510 +.5177 93 .052 1231o .6 15b22 .3 123 532 31 05 51 . &.' 973 310 .000 17.672 05b59 +.2366 90 073 12733 b lbl33 3 125 209 31 + 9 3l Z! 9 3 320 .000 17.21„ 05811 3.9793 87 519 13161 .2 166+7 .7 126 8+0 31 95 31 5 3 33 3 330 .000 1 6 . 7 b 3 0. 059oc 3

.

7+3b 85 352 1368 + . 5 17163 .8 12d + 28 32 + + 3 1 7? 921

3 + 000 16.332 . 0ol23 3.5277 83 .532 1 + 008 .+ 1 7682 .1 129 976 32 95 51 9f 90 3 350 000 15.910 0a282 3.3298 82 025 1 ++33 2 132J2 5 131 +8 + 33 + 7 52 1 + 892 360 .000 15.521 , 0o++3 3. 1+82 8u 796 1 + 859 .0 1o72 + .8 132 95 6 3 + .00 32 .33 33 J 3/0 .000 15.139 .0^605 2.9815 79 815 152 85 6 192 + 9 1 13 + 392 3 + 5 + 52 62 o7 , 380 .000 1 + . 173 06769 2.8283 79 .053 16713 .8 19775 .2 135 79 5 35 09 52 7 ) «OJ 330 J00 1+.+25 0o933 2.6873 78 + 85 ie 1 + 3 .2 ?u505 p 2 137 166 35 6 + 52 89 6bZ

<t00 .000 1 + . Udt> 07093 2.557+ 73 .089 1657 + ,2 ?0o33 .0 13d .508 3e 20 33 C 3 8+3

+ 20 .000 13.+o2 07+28 2. 3271 77 732 17++1 , i* 21896 + 1+1 107 37 32 53 . + 6 833

<*<*i .000 12.889 .07758 2. 1301 77 ,3+9 1831o 7 22971 .8 1+ i 60 3 36 + + j3r 33 62?

itoO .000 12.36b . 03087 1.9607 78 .336 19201 . 5 2 + 053 .6 1 + 3 008 3 9 55 3 + 31 81 j + d0 .000 11. 867 , 03 + 13 1.61+1 79 .121 2009o .8 251+ + . p 1+3 .32 9 + C 65 5 -, ,73 313 500 .000 11. ++7 0373o 1. 6666 80 .128 21003 b 2b2 + 5 .0 150 .575 + 1 73 55 ,23 813

202
ME THANE ISOBAR AT P == 650.0 BAR

T DEN VOL JP/DT DP/OO E H S CV CP A D :g k MOL/L L/MOL 1 3AR/K 6AR-L/M0L J/MOL J/MOL J/MOL/K J/MOL/K J/"IOl/K •l/SEC 106 .238 29.28+ .03+15 19 10 05 309 . +7 + 3768 8 5936 .5 70 710 37 09 51 6 9 16 + 110 .000 29. 116 03 + 35 16 6039 306 .750 3933 .7 ol66 .1 72 371 37 07 51 71 lo33

115 .000 28.615 ,03+70 17 ,9209 299 .850 + 166 ,9 6+22 .7 7 + 068 36 30 51 63 1619

120 000 28.518 ,05507 17 ,2581 291 .950 + + 00 ,1 679 .+ 7o .86 2 36 + 51 + 5 lcj + 125 .000 28.22+ 035 + 3 16 ol80 283 , + 17 + 632 5 6935 ,6 73 95 8 35 96 51 26 153" 130 000 27.931 03580 16 .0015 27 + ,517 + 86 + .0 7191 .2 80 966 35 57 51 11 1563

135 .000 27.b+0 03616 15 ,+065 265 , + 5 + 509+ ,9 7+ + 6 .5 82 89 + 35 27 51 U7 15 + d 1 + 000 27.351 0365b 1 + 3388 25o .375 5325 + 770 1 .9 8 + 75 2 35 06 51 13 152 7 1+5 000 27.062 03695 1 + 2915 2 + 7 . + 06 5556 .0 7 95 7 .9 8o ,5+8 3 + 91 51 ,26 150p 150 000 2o./73 0. 03735 13 7658 238 62u 5786 7 821 + 5 83 283 3 + 73 51 35 1+83

155 .000 26. +85 03776 13 2b08 230 .081 6017 8 + 71 ,3 89 97 1 3 + + 3 51 31 l + b2 lbO 000 2b. 197 03817 12 7755 221 ,835 62 + 6 1 6727 .3 91 ,59 7 3 3 .90 51 Oo 1+ + 3 lo5 J00 25.909 03660 12 3092 213 ,912 6+72 7 6931 5 93 161 33 16 50 67 1 + 2 5 170 0G0 25.621 c 03903 11 8610 206 ,329 6 6 95 ,8 9232 8 9 + 662 32 30 + 9 9o 1 + 10 175 ,000 25.33+ 039+7 11 + 303 199 .09? 6915 9 9+31 ,6 9 = 102 32 08 + 9 97 139J

130 000 25.0+7 0. 03992 11 0162 192 211 7135 8 9730 9 97 507 31 66 + 9 77 13 72 185 000 2+.761 0. 0+039 10 bl62 185 672 735 + 3 997 9 + 93 869 31 32 + 9 6 + 135 + 190 .000 2+.+75 + 03o 10 2357 179 + 71 7571 7 10227 ,+ 100 19 1 31 01* + 9 6o 133o

195 000 2+.191 c + 13 + 9. 8b81 173 595 7788 1 13 + 75 1 1C1 +7 8 30 81 + 9 50 1319 200 000 23.907 + 133 9. 51+9 166 .030 8003 6 10722 ,5 102 730 30 60 + 9 + 5 1301 205 000 23.62+ 0. 0+233 9 1757 162 7b2 8213 3 10969 7 103 951 30 + + + 9 + + 123 + 210 000 23.3+3 0. + 23 + 8. 8 + 99 157 776 8 + 32 3 11216 ,9 105 1+2 30 29 + 9 + 3 12 = 7 215 000 23. 0o + + 336 8 5370 153 056 86 + 5 7 11+6 + .0 106 305 30 16 + 9 + 3 125 220 000 22.785 o. + 339 6. 2367 1 + 8 589 8858 + 1171 1 .0 107 + +2 29 38 + 9 22 1235

225 J00 22.509 + + + 3 7 9+85 1 + + 359 9069 3 11957 103 5 + 7 29 73 + 9 1 7 122 J 230 000 22.235 c. + V97 7 6719 1 + 35 + 9 27 9 5 12202 6 109 d2 8 29 6 + + 9 15 120 + 235 000 21.963 0, + 553 7 + 06b 13d 563 9 + 89 12++8 ,6 11 J 635 29 oO + S 17 1139

2 + 000 21.b93 0. 0+610 7 1521 132 973 9698 1 12o9 + 5 111 720 29 59 + 9 2 1 117 + 2 + 5 jOO 21. +25 0. 0*637 6 9u79 129 5 75 9906 9 129+0 7 112 736 29 51 + 9 27 115 i 250 000 21.160 + 72b 6 6739 126 359 10115. 3 1 3187 2 113 732 29 6c +

° 3- 11 + p 255. JOO 20.697 0. + 7 85 0. + + 9 + 123 317 10323. 7 13 + 3 + 2 11 + 710 29 7 + + 9 + + 113J 260 000 20.o37 + 8+6 o 23 + 3 120 + + 2 10631 9 1 3681 6 lip 671 29 8 + + 9 ^ ^ Ilia

2o5 uOO 20.379 0. + 907 6 0280 117 725 107+0 1 13929 6 116 615 29 95 + 9 65 1103 270 000 20. 125 0. + 969 5 8303 lip 160 109+8 3 1 + 173 2 117 5 + 5 30 09 + 9 77 1090 275 000 19.873 0. 05032 5 6 + 08 112 7 + 2 11156. 5 1+ + 27 3 118 + 59 30 2 + + 9 69 107 7 280. 000 19. 62+ 0. 0509o 5 • + 592 110 + b + 1136 + 9 l+o77 1 119 35 9 30 + 1 50 ui 105 + 265. JOO 19.379 0. 0515J 5. 2851 108 319 11573 + 1 + 927 6 12 J 2+6 3 58 5 15 10>7

290 000 19. 13o 0, 0522b 5. 1163 106 30 + 11762 G 15176 ,7 121 119 3

y 7 5 29 10 + 1 295. 000 18.897 0. 05292 + • 9563 1C + + 13 11990. 8 15+3 . + 121 980 30 97 5 J + 2 102 1 300 y 00 18.662 05359 + 8050 102 6+1 12199 8 15b32 9 122 82 8 31 16 50 5 o 1019

310 JOO 18.200 0. 05+9 + + 5173 9 9 + 32 12616 5 16139 9 12 + +91 31 62 50 63 993

320. JOO 17.753 0. 05633 + . 2528 9o 6 + 2 13038. 1 1669 9 5 12 6 109 32 09 51 10 979

330 000 17.320 0. 0577 + + . 0097 9 + 232 13+53. 9 17211. 7 127 b85 32 59 5 1 3> 9 52

3 + JOO 16.902 0. 0591o 3, 7660 92 169 13630. 9 17726 6 129 22 2 33 10 51 e.i 9+ -i 35J 000 16. +.99 0. 05061 3. 5602 90 + 19 1-30 + 2 182+3 9 13J 721 33 5 2 51 a-j 932 3o0 000 lb. 110 0. 05207 3 3907 38 952 1+728. 9 187o3 o 132 185 3 + 16 5i 3 91 3 370 000 15.736 0. 05355 3

.

2161 67 73b 15155. 1 19235 6 133 616 3". 71 52 32 9Jd

360 000 15.377 0. 0^503 3. 550 86 751 15562. 9 1 9810 135 01 + 35 26 52 5 5 8 9-3 390 000 15.032 0. 05653 2. 9063 85 966 16012. c 20336. 7 l3o. 332 35. 32 52. 73 38 3 + 00 000 1+.7Q1 0. 05802 2. 7666 85 361 16+++. 1 20836 7 13 7 721 36 39 52 1 88J

+ 20 000 1 + . 078 0. 0710 3 2. 5239 8 + o 1 + 17313. + 21930 + 1+0 319 37. 52 53. +

' 86 7 + + Q . 000 13. 506 0. 07 + J + 2. 3133 8 + . 371 lol91. 9 23 00 + 5 1 + 2. 617 36. o + 53. 9 + 657

+ o0. 000 12.960 0. 0773 + 2. 1313 8 + 5 29 19080. 6 2+038 2 1 + 6 225 39 76 5 + + 3 3 + 9 + 30. 000 12. +96 0. 08002 1. 9731 85 005 19980. + 25131. 3 1+7 553 + 0. 86 5 + . 9 + U + + 500. 000 12.050 0. 03293 1. 8350 85. 73c 20892. 26236. 1 + 9. 80o + 1. 9 + 5 5 + 7 3 + 1

203
ME rHANE IS03AR AT P : : 700.0 BAR

T OEN VOL OP/OT OP/OD E H S CV C

D H OEG K MOL/L L/MOL BAk/K BAR-L/MGL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K 1/SEC

107. 355 29.3bO 0. 03 + 36 19. O1C0 311. 80 + 3797. 3 6131 5 70. 928 37. 27 51 73 16 + 2 113 JOO 29.27a 03 + 16 18.6697 311 137 3907. 6 o238 5 72. 017 37 29 51 7 3 16+ J 115. 000 28.980 0. 3 <*5 1 13.0311 306. 5 + 3 + 139. + 655 + 1 8 7 + . 313 37. Ql 51. 53 1623

120 000 2 8.D6 7 03 + 3b 17.3691 296 689 + 371. 1 6811 ,2 75 50 + 36 61 51 37 ieio

125. JOO 28.39B o. 03521 16. 7669 291. OCO +601. 9 70o6 9 73. 59 6 36. 17 51. 1 + 1602

130 000 28. Ill 3557 lo. lo63 282 786 + 831 7 7321 8 AH 59e 35 77 50 97 156p

135 JOO 27.626 0359"* 15.3875 27 + 277 5060. 7 7576 <t 32 52 35 + 6 50 91 1567

1 + 0. ooo 27. 5*2 03631 15.0305 265. o51 5289 + 7330 9 8 + 37 2 35. 25 >0 95 15+' 1+5 OGO 27.260 G36o6 1+. + 9 + 6 257 037 5518 G 8035 ,9 8o 161 35 10 51 05 1627

150 JOO 26.978 03737 13.9796 2+8 535 57 + o 7 83+1 + 87 693 3+. 92 51 12 150p

135 300 26.697 037+6 13. +6+3 2+0 .220 5975 G 8597 8:1 5o9 3 + 60 51 Oc Udo

160. 300 26. +17 0. 03785 13.0079 232. 1+5 6201. 9 8851 7 91. 137 3 + . 38 50 79 1 + 69 Ib5 JOO 26.137 03626 12. 5*97 22 + .3 + 9 642o 3 91J + 5 92 7 + 2 33 33 50 29 1+53

170 JOO 25.656 03667 12. 1090 216 853 c6 + 7 2 935 + + 9 + 23 + 32 + 7 + 9 6o 1 + 33 175 JOO 25.579 03910 11.6850 209 665 6665 G 9o3 1 ,6 95 .666 32 2^ + 9 CO 1 + 19 180 OCO 25.30G 3 953 11.2770 202 8 + 7082 6 98 + 9 + 97 061 31 82 + 9 + 5 1 + J? 165 300 25.023 3996 U. 88+6 19o 322 7298 8 U096 i 98 + 1 + 31 + 8 + 9 31 133.

190 JOO 2+.7+6 + OhI 10.5070 190 125 7 513 8 103 + 2 6 93 728 31 20 + 9 21 13o7 195 000 2+.+7G 0*037 10.1+37 18 + 2 + 2 7727 6 10538 + 101 005 30 96 + 9 1- 135 D 200 JOO 2 + . 195 c u+133 9. 79 + + 178 b62 79+0 9 1063 + .0 102 2+9 30 75 '+9 ,13 133 i 2J5. JOJ 23.922 + 180 9. + P8 + 173 373 8153 3 11079 5 10 3 + 61 30 5e + 9 07 1317 210 000 23.650 + 228 9. 1353 166 360 836+ 9 1132 + 7 10 + o+3 30 + + + 9 05 130 j 215 000 23.379 0. + 277 6.821,8 163 10 8575 9 11570 .0 105 797 30. 32 + 9 + 123- 22J 000 23. Ill 0. + 327 8.5262 159 106 6786 2 11315 1 10a 92 + 30 02 + 8 6 + 127J

225. 000 2a.8<m + 376 8.239+ 15 + 6 + 1 899 + e 12059 1 106 021 29 37 + 6 77 123p 230 000 22.578 + + 29 7.>r)637 150 797 9202 6 12332 9 10 J 093 29. 78 + 6 75 12 + 1 235 000 22.315 + + 81 7.o989 1 + 6 ,962 9 + 09 8 123+6 7 11J 1+1 29 72 + 8 76 122o

2*0. 000 22.055 + 53 + 7. +++6 1+3 326 9616 6 12740 6 111 168 29 72 + 6 6 3 1211 2+5 000 21.79c + 538 7.20C3 139 879 9823 1 13J3 + 7 112 175 29 7 + + 8 65 1197

250. 000 21.6+u + 6*3 6.9657 136 olO 10C29 + 13279 1 113 163 29 79 -.6 93 1133 255 000 21.286 + 698 6. 7 + C5 133 512 1C235 5 1352 + o- 11 + 132 29 37 + 9 02 1163

260 000 21.035 + 75 + 6.52+2 130 375 1C++1 6 13759 3 lip 085 29 96 + 9 12 1155 2o5 000 20.767 + 811 6. 3166 127 793 106 + 7 7 1+015 2 lib 022 30 38 + 9 23 11+2 270 000 20.51.1 + 868 6.1172 12p 159 10653 .8 1-261 7 lib 9+3 3 22 -.9 ,3p 1123 275 000 20.296 + 927 5.9259 122 o67 11060 1 1 + 538 7 117 8a0 30 37 + 9 + 7 111 j 280 .000 20. 058 G + 93o 5. 7+22 120 310 11266 5 1 + 756 + 113 7+2 30 33 + 9 61 113 + 285 JOO 19.621 05G + 5 5. 5658 118 08 + 11+73 1 150 3 + 6 119 c2 2 30. 71 + 9 7 + 10 92 290 000 19.58b .05106 5.39c5 Up .983 llt79 .9 15253 .8 12J + 88 30 90 + 9 R^ 1093 295 JOJ 19. 355 05167 5. 23+0 11 + 002 11667 15533 6 121 3+2 31 10 5 02 10b j 300 OOJ 19. 127 U5223 5. o7eo 112 137 1209+ + 1575 + 1 122 13 + 31 31 50 1 7 1063 310 JOO 16.661 05353 +.78+3 106 733 12510 1 lc257 2 123 833 31 76 pG + 5 103a

320 JOO 13. 2i*7 05 + 80 +.5135 105 738 12 927 1 lo763 2 125 ++0 32 23 5 J 7p 1313

330 000 17.o27 3 6 9 +.2637 103 .117 133 + 5 5 17d7 2 2 127 006 32 73 51 3 1031

3 + J 000 17. ^21 057 + J +. 0332 10u 839 13765 7 17733 9 123 53 + 33 25 51 32 935

3^0 .000 17.027 c 03673 3.820+ 98 673 1 + 167 5 18296 5 130 02 6 33 78 51 ,c3 970

3o0 . 000 16. cS G 05007 3. 6238 97 191 1+611. 1 13315 9 131. + 33 3L. 32 51 67 957 370 .300 16.28 2 051 + 2 3.++20 96 ?tr 15036 6 19335 9 132 90 6 3 + 67 5 2 1 + 9+>

3S0 OOJ 15.929 0^278 3. 2739 9 + p73 15+6 + 1 19858 7 13 + 302 35, + 3 52 + 1 93 + 390 000 15.569 06 + 15 3.11C1 93 .569 15693. 7 2033 + 135 tb& 36 00 52 t7 92-. too JJO 15.262 Od552 2.9738 92 791 16325 6 20912 137 003 36. 56 52 93 915 "20 .000 1+.6+6 06826 2.7155 91 678 1719o + 21975 8 13 3 698 37. 70 a + i 90J "tO 000 lH. 07b 0710 + 2. +923 91 101 18 077 3 23050 1 1 + 2 097 36 6 + 5 3 93 AAo

+ 60 000 13.550 07360 2.2986 90 950 189o9 2 2 + 135 1 1 + + 508 39. 9b 5 + . 51 873

+ 80 000 13. 06 + 07b5 + 2. 1296 91 1 + 1 19672 7 25230 6 1 + i 8+0 + 1 07 55 05 373

500 JOO 12.615 07927 1.9815 91 o06 2C768 5 2o337 5 1+9. 098 + 2. 15 55 o2 863

204
Table 15. The Joule -Thomson inversion locus

T,F T,R P,PSI LB/CUFT T,F T,R P.PSI LB/CUFT

170.00 289.67 715 21.54 140.0 599.67 7286 15.36

-160.00 299.67 1120 21.30 150. 00 609.67 7358 15. 18 150.00 309.67 1503 21.07 160.00 619.67 7424 15. 00

•140. 00 319.67 1867 20.84 170.00 629.67 7483 14. 83 130.00 329.67 2213 20.61 180.00 639.67 7536 14.65

120. 00 339.67 2542 20.39 190.00 649.67 758 3 14.47 110.00 349.67 2856 20.16 200.00 659.67 7623 14.29 100.00 359.67 3155 19.94 210.00 669.67 7657 14.11 -90.00 369.67 3440 19.73 220.00 679.67 7685 13.93 -80.00 379.67 3713 19.52 230.00 689.67 7707 13.75 -70.00 389.67 3973 19.31 240.00 699.67 7723 13.57 -60.00 399.67 4222 19.10 250.00 709.67 7734 13.39 -50.00 409.67 446 18.90 260.00 719.67 7739 13.21

-**0. 00 419.67 4688 18.70 270.00 729.67 7738 13.03 -30.00 429.67 4905 18.50 280.00 739.67 77 31 12. 84 -20.00 439.67 5113 18.31 290.00 749.67 7718 12.66 -10.00 449.67 5311 18.11 300.00 759.67 7699 12.47

0. 00 459.67 5500 17.92 310.00 769.67 7675 12.29 10.00 469.67 5679 17.73 320.00 779.67 7644 12. 10 20.00 479.67 5851 17.55 330.00 789.67 7607 11.91 30.00 489.67 6013 17.36 340.00 799.67 7563 11.72

40. 00 499.67 6168 17.17 350.00 809.67 7514 11.52 50.00 509.67 6314 16.99 360.00 819.67 7458 11.33 60.00 519.67 6452 16.81 370.00 829.67 7398 11. 13 70.00 529.67 6582 16.62 380.00 839.67 7335 10. 93 80.00 539.67 6705 16.44 390.00 849.67 7271 10.74 90.00 549.67 6820 16.26 400.00 859.67 7206 10.55 100.00 559.67 6927 16.08 410.00 869.67 7142 10.36 110.00 569.67 7027 15.90 420.00 879.67 7078 10. 18 120.00 579.67 7121 15.72 430.00 889.67 7015 10.00 130.00 589.67 7207 15.54 440.00 899.67 6953 9. 83

205
Table 16. Thermophysical properties of the saturated liquid

For the following table we have used heats of vaporization to make the vaporliquid transition at temperatures T < T = 174.516 K. For higher temperatures

a we have computed around the critical point as described in section 3.4 of the text with aid

from figure 1

.

Column headings have the following interpretations--

DP/DT = dP/dT, vapor pressure,

DDL/DT = dp^/dT, saturated liquid

Q, VAP = AH ,heat of vaporization,

CV = C (P,T),

CS = CCT (T),

CP s C (P,T).

206
Table 16. Thermophysical properties of the saturated liquid

T T P OEN V.GAS V,LIQ OP/OT QOL/DT Q,VAP

DEG F OEG R PS I LB/CUFT CUFT/LB CUFT/LB PSI/R LB/CUFT/R BTU/LB 296.446 163.224 1.703 28.190 63.6831 0.03547 0.1216 -0.04606 233.84

290.000 169.670 2.648 27.392 42.4544 0.03585 0.1739 -0.04654 231.78

265. 000 174.670 3.641 27.658 31.7071 0.03616 0.2246 -0.04698 230.11 260.000 179.670 4.911 27.422 24.1032 0.03647 0.2852 -0.04748 228.37

275.000 184.670 6.511 27. 183 18.6191 0.03679 0.3565 -0.04805 226.55 270.000 189.670 8.495 26.941 14.5936 0.03712 0.4394 -0.04868 224.64

265.000 194.670 10.925 26.696 11.5909 0.03746 0.5346 -0.04937 222.64 260.000 199.670 13.863 26.447 9.3177 0.03781 0.6428 -0.05012 220.54

255.000 204.670 17.375 26.195 7.5731 0.03818 0.7646 -0.05094 218.35 250.000 209.670 21.532 25.938 6.2174 0.03855 0.9006 -0.05182 216.05

245.000 214.670 26.406 25.677 5.1514 0.03895 1.0513 -0.05276 213.65 240.000 219.670 32.070 25.410 4.3041 0.03935 1.2171 -0.05378 211.14

235.000 224.670 38.603 25.139 3.6238 0.03978 1.3984 -0.05486 208.50 230.000 229.670 46.080 24.861 3.0725 0.04022 1.5954 -0.05603 205.74 225.000 234.670 54.584 24.578 2.6217 0.04069 1.8086 -0.05727 202.85 220.000 239.670 64.194 24.289 2.2500 0.04117 2.0381 -0.05861 199.80 215.000 244.670 74.993 23.992 1.9412 0.04168 2.2843 -0.06006 196.59 210.000 249.670 87.065 23.688 1.6828 0.04222 2.5473 -0.06162 193.20 205.000 254.670 100.494 23.375 1.4650 0.04278 2.8273 -0.06332 189.62 200.000 259.670 115.366 23.054 1.2803 0.04338 3.1246 -0.06518 185.83 195.000 264.670 131.769 22.723 1.1226 0.04401 3.4395 -0.06723 181.82 190.000 269.670 149.791 22.382 0.9673 0.04468 3.7722 -0.06951 177.57

185.000 274.670 169.522 22. '328 0.8706 0.04540 4.1231 -0.07206 173.05 180.000 279.670 191.053 21.660 0.7693 0.04617 4.4927 -0.07495 168.25

175.000 284.670 214.480 21.278 0.6810 0.04700 4.8813 -0.07825 163.14

170. 000 289.670 239.900 20.877 0.6037 0.04790 5.2897 -0.08208 157.69

165.000 294.670 267.411 20.456 0.5356 0.04689 5.7185 -0.08657 151.87 160.000 299.670 297.121 20.010 0.4754 0.04998 6.1689 -0.09192 145.62 155.000 304.670 329.138 19.535 0.4218 0.05119 6.6419 -0.09844 138.87

150.000 309.670 363.580 19.023 0.3738 0.05257 7.1393 -0.10654 131.52 145.000 314.670 400.575 18.465 0.3306 0.05416 7.6631 -0.11692 123.43 140.000 319.670 440.261 17.348 0.2912 0.05603 8.2165 -0. 13071 114.37

135.000 324.670 482.797 17.149 0.2548 0. 05831 8.8040 -0.15007 104.00 130.000 329.670 528.369 16.331 0.2205 0.06123 9.4328 -0.17958 91.71 125.000 334.670 577.215 15.317 0.1871 0.06529 10.1167 -0.23204 76.35

120.000 339.670 629.684 13.881 0.1520 0.07204 10.8928 -0.37388 54.80 116.671 342.999 667.003 10.915 0.0998 0. 09985 11.6443 0.00

207
Table 16. Thermophysical properties of the saturated liquid (continued)

T P E H S CV CS CP H DEG F PS I BTU/LB 9TU/LB 8TU/TB/R BTU/LB/R BTU/LB/R BTU/LB/R FT/S

296. 446 1.703 93.10 93.11 1.01124 0.493 0.786 0.786 5172 390.000 2.648 97.91* 97.95 1. 04175 0.491 0.791 0.791 5056 285.000 3.641 101.76 101.79 1.06481 0.491 0.797 0.797 4961

280. 000 ".911 10 5.66 105.69 1.08740 0.492 0.804 0.805 4863 275.000 6.511 109.61 109.66 1. 10957 0.493 0.811 0.812 4764 270.00 8.495 113.63 113.68 1. 13135 0.493 0.819 0. 820 4665

265. 000 10.925 117.69 117.76 1.15274 0.493 0.825 0.8 27 4566 260.000 13.863 121.79 121.89 1.17375 0.492 0.832 0. 833 4469 255.000 17.375 125.91* 126.06 1.19439 0.490 0.837 0.840 4372

25 0. 00 21.532 130. 11 130.27 1. 21467 0.488 0.843 0.846 4276

245. 000 26.1*06 134. 33 134.52 1.23460 0.485 0.848 0.852 4180

2<*0. 00 32.070 138.57 138.80 1.25419 0.481 0.854 0.858 4084

235. 000 38.603 142.81* 143.12 1.27347 0.478 0.860 0.865 3988 230.000 i*6. 080 147.15 147.49 1. 29246 0.475 0.866 0.872 3890 225.000 54.584 151.49 151.90 1.31118 0.473 0.873 0. 881 3791

220. 000 64. 194 155.86 156. 35 1.32967 0.471 0.881 0.890 3690 215.000 74. 993 160.28 160.86 1.34 7 96 0.469 0.890 0.901 3588

210. 000 87. 065 164. 75 165.43 1.36606 0.468 0.900 0.914 3483 205.000 100.<*9<* 169.27 170.07 1.38403 0.467 0.912 0.928 3377 200.000 115.366 173.85 174.77 1.40187 0.467 0.924 0.943 3269 195.000 131.769 178.49 179.56 1.41961 0.466 0.937 0. 960 3159

190. 000 11*9.791 183.19 184.43 1.43728 0.466 0.951 0.979 3048 185.000 169.522 187.96 189. 39 1.45490 0.465 0.967 1. 000 2936

180. 000 191.053 192.81 194.44 1.47248 0.463 0.983 1. 023 2822 175.000 214.480 197.74 199.60 1.49005 0.461 1.000 1. 049 2707 170.000 239.900 202.75 204.88 1.50764 0.457 1.020 1. 079 2591 165.000 267.1*11 207.86 210.28 1.52527 0.453 1.042 1. 115 2472 160.000 297. 121 213.07 215.82 1.54302 0.449 1.068 1. 159 2350 155.000 329.138 218.42 221.54 1.56096 0.445 1.101 1. 215 2223 150.000 363.580 223.94 227.48 1.57922 0.442 1.144 1.289 2088 145.000 i*00.575 229.69 233.71 1.59795 0.449 1.208 1.399 1935

1 U0. 000 440.261 235.77 240. 34 1.61757 0.452 1.286 1.548 1781

135. 000 1*82.797 242.26 247.48 1.63833 0.457 1.397 1.776 1617 130.000 528.369 249.37 255.36 1.66088 0.468 1.568 2. 167 1439 125.000 577.215 257.48 264.45 1.68654 0.488 1.878 2.997 1242

120. 000 629.681* 267.78 276.18 1.71933 0.536 2.745 6.085 1007 -116.671 667.003 290.14 302.47 1.79463

208
Table 17. Thermophysical properties along isobars'

The following pages give physical and thermodynamic properties along selected

isobars, as computed by methods of section 3 of the text.

The first table is for the triple -point pressure, P, = 0.117 436 bar ( 1 . 70326 psi).

The first line of each table refers to the freezing liquid on the P(T) melting line.

Each table at P < P contains a blank line for the transition from saturated liquid

c to vapor, as seen by the abrupt decrease of density.

Table headings for partial derivatives have the following interpretations--

DP/DT = Sp/BT,

DP/DD = BP/dp.

The specific heat interpretations are--

CV = C (P,T), v CP = C (P, T).

P

* These tables are extrapolated beyond the range of P-P-T data used for adjusting the

equation of state (T ~ 400 K, P~ 350 bar).

209
METHANE ISOBAR AT P = 1.703 26 PSI

T T OEN VOL CP/OT DP/DO E H S cv CP W OEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LP BTU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S

296. 446 163. 224 28.190 0.0351*7 166.991. 3622.62 93. 10 93.11 1.01124 0. 493 0. 786 5172

296. 446 163. 224 0.01570 63. 683 0. 01056 1 07.65 306. 46 326.57 2.44 3 86 0. 373 0. 500 818

29 0. 000 169.670 0.01510 66. 2<*5 0. 01011* 112.06 308, 91 329.81 2.46322 373 0, 500 834

280. 000 179.670 0.01424 70. 21<* 0. 00956 118. 88 312. 66 334.83 2.49181 0. 373 0. 499 859

27 0. 000 189.670 0.01348 71*. 177 0. 00905 125.67 316, 44 339.84 2.51862 0, 37 3 0. 498 883

26 0. 000 199.670 0.01260 ?8. 135 0. 00858 132.45 320. 20 344.85 2.54442 0, 372 0. 498 906

250. 000 209.670 0.01218 82, 090 0, 00817 139.22 323, 96 349.85 2.56875 0. 372 0, 498 929

240. 000 219.670 0.01162 86. 043 0. 00779 11.5.98 327, 71 354.85 2.59193 372 498 951

230. 000 229.670 0.01111 19 992 0. 0071*5 152.73 331. 47 359.85 2.61403 0, 372 n, 497 972

22 0. 000 239.670 0.01065 93. 91*0 0. 00713 159.47 335. 22 364.85 2.63527 372 a 497 993

210. 000 249.670 0.01022 97 887 0. 00681. 166.20 338. 97 369.84 2.65560 0. 372 0. 497 1014

200. 000 259.670 0. 00982 101. 831 0. 00659 172.93 342. 72 374.84 2.67512 0. 372 49 7 1034

190. 000 269.670 0.00945 105. 775 0. 00633 179.66 346. 47 379.83 2.69390 0, 372 .97 1054

180. 000 279.670 0. 00911 109. 718 n, 00610 186.39 350. 22 384.83 2.71201 0. 373 497 1073

170. 000 289.670 0.00880 113. 659 0. 00589 19 3.11 353. 97 369. 62 2.72947 373 497 1093

160. 000 299.670 0. 00850 117 600 00569 199.82 357 72 394.81 2.74635 373 497 1111

150. 000 309.670 0.00823 131 51*1 0, 00551 206.5<. 361 48 399.61 2.76268 373 498 1130

140. 000 319.670 0.00797 125. 1*80 00534 213.25 365 23 404.81 2.77850 0, 373 498 1148

13G. 000 329.670 0.00773 129 i*19 0. 00517 219.97 366 99 409.81 2.79384 374 498 1165

120. 000 339.670 0.00750 133 358 0, 00502 226.68 372 76 414.82 2.80874 374 499 1183

110. 000 349.670 0.00728 137 296 0, 1* 8 8 233. 38 376 52 419.83 2.62322 375 499 1200

100. 000 359.67 0.00708 11*1 231. 0, 001*71* 21.0.09 380 30 424.84 2 . e 3 7 3 376 500 1217

-90. 000 369.670 0.00689 1<*5 171 0. 001*61 21.6. 80 384. 06 429.86 2.85102 376 501 1233

-80. 000 379.670 0.00671 149 108 0. 001*1*9 253.50 387 86 434.89 2.66439 377 301 1250

-7 0. 000 389.670 0.00653 153 01*5 0. 001*37 260. 21 391 66 439.93 2.87743 378 502 1266

-60. 000 399.670 0.00637 156 982 0, 001*26 266.91 395 47 444.98 2.69018 379 503 1281

-5G. 000 409.670 0. 00621 160. 918 0, 001*16 273.61 399. 26 450.04 2.90263 380 505 1297

-40. 000 419.670 0.00607 161* 851* 0, 001.06 280.32 403 11 455.11 2.91461 382 506 1312

-30. 000 429.670 0.00592 168 790 00396 287.02 406 96 460.19 2.92675 383 507 1327

-20. 000 439.670 0.00579 172 725 0, 00387 293.72 410 82 465. 29 2.93844 385 509 1342

-10. 000 ''9.670 0.00566 176 660 00379 300. 1.2 414. 69 470.41 2.94990 ,387 511 1356

000 459.670 0.00554 130 596 00371 307. 12 418 59 475.55 2.96116 389 513 1370

10. 000 <»69.670 0. 0051*2 181* 531 0, 00363 313. 82 422 50 480.70 2.97221 391 515 13*4

20. 000 1*79.670 0.00531 138 1.66 00355 320.52 426 43 485. 68 2.98308 3 93 517 1398

30. 000 489. 670 0. 00520 192. <.00 0. 0031.8 3 2 7.22 430 39 491.07 2.99 37 7 395 519 1411

1.0. 000 499.670 0.00509 196 335 0031*1 333.92 434 37 496.30 3. 00429 398 522 1425

50 000 509.670 0.00499 200 269 00331* 31.0.61 436 38 501.54 3. 01466 400 524 1438

60. 000 519.670 0.00490 204 201* 0. 00328 347. 31 442 41 506.82 3.02467 403 527 1451

70. 000 529. 670 0.00480 208 138 00321 351.. 01 446 47 512.12 3.03494 406 530 146 3 80. 000 539.670 0. 00i»72 212 072 00316 36 0.71 450 57 517.45 3.044 89 409 533 1476

100 000 559.670 0.00455 ?19 940 00301. 371.. io 458 84 528.21 3. 06440 415 539 1500

120. 000 579.670 0.001.39 227 808 0. 00291. 387.49 467. 25 539-10 3. 08346 o. 422 3 546 1524

140 000 599.670 0.00424 235 ,675 00281. 400.88 475 80 550.13 3.10 212 430 554 1547

160 000 619.670 0.001*11 21.3 51*2 00275 414. 28 484 51 561.32 3. 12041 438 562 1569

180, 000 639.670 0.00398 251 1*09 00266 427.67 493 37 572.66 3.13839 446 570 1591

200. 000 659.670 0.00386 259 275 G, 00258 441 . 06 502 4C 584.17 3. 15605 0. 454 0. 578 1613

220 000 679.670 0.00374 267 li*l 00250 454.45 511 60 595.85 3. 17344 463 587 1634

240 000 699.670 0.00361* 275 007 0, 0021.3 467. 84 520 97 607.71 3. 19059 a 472 0. 596 1654

280 000 739.670 0. 0031*1* 290 739 00230 494.61 540, 27 631.97 3.22423 490 0. ol4 1694

320. 000 779.670 0.00326 306 1.69 0. 00218 521. 39 560. 32 656.98 3. 25707 0. 509 0. 633 1733

360 000 819.670 0. 00310 322 199 00208 548. 16 581 12 682.74 3.28923 5 29 0. 652 1771

if 00 000 859.670 0.00296 337 928 0, 00198 574.94 602 70 709.28 3.32077 548 0. 672 18C7

440 000 399.670 0.00283 353 657 00189 601.71 625. 04 736.58 3.35175 567 0. 691 1843

210
METHANE ISOBAR AT P 5.0 PSI

T T DEN VOL DP/DT DP/DD E H S cv CP H OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB 3TU/LB BTU/LB/R BTU/LB/R RTU/L9/R FT/S 296.435 163.235 28.191 0.03547 166.988 3623.06 93.10 93.14 1.01125 0,,493 0.786 5172 290.000 169.670 27.892 0.03585 159.537 3425.01 97.93 97.96 1.04173 0..491 0.791 5056

280. 000 179.670 27.422 0.03647 148.494 3121.46 105.66 105.69 1.08740 ,492 0.605 4863 279.690 179.980 27.407 0.03649 148.161 3112. 16 105.90 105.94 1.08879 .492 0.305 4857 279.690 179.980 0.04218 23.709 0.02856 116.68 312.06 334.01 2.35702 0.,375 0.506 854

270. 000 189.670 0.03994 25. 040 0.02698 123.51 315.73 338.91 2.38350 0.,374 0.504 878

26 0.000 199.670 0.03787 26.407 0.02555 130.50 319.51 343.96 2.40936 0,, 374 0.503 902 250.000 209.670 0.03601 27.770 0.02427 137.45 323.28 348.99 2.43391 0., 373 0.502 925

240. 000 219.670 0.03433 29.130 0.02311 144.36 327.04 354.01 2.45726 0,,373 0.501 947

230. 000 229.670 0.03280 30.487 0.02207 151. 25 330. 8C 359.03 2.47955 0.,373 0.500 969 220.000 239.670 0.03140 31.842 0.02111 158. 11 334.56 364.04 2. 50086 0.,373 0.500 991 210.000 249.670 0.03012 33.195 0.02024 164.95 3 3 8.31 369.05 2.52128 0., 373 0.499 1012 200.000 259.670 0.02895 34.547 0.01944 171.78 342.06 374.05 2.54 89 0,,373 0.499 1032

190. 000 269.670 0.02786 35. 897 0. 01870 178.59 345.82 379.05 2.55974 0.,373 0.499 1052

180. 000 279.670 0.02685 37. 246 0.01802 185.39 349.56 384.05 2.57791 0,,373 0.*99 1072 170.000 289.670 0.02591 38.594 0.01739 192.18 353.31 389. 05 2.59543 0,, 373 0.499 1091 160.000 299.670 0.C2504 39.941 0.01680 198.96 357.06 394.05 2.61235 0,, 373 0.^99 1110

150. 000 309.670 0.02422 41. 288 0. 01625 205.73 360.82 399.04 2.62872 0,,373 0.499 1128 140.000 319.670 0.02346 42.634 0.01573 212.49 364.57 404.04 2.64459 0,, 374 0.-»99 1147

130. 000 329.670 0.02274 43.979 0.01525 219.25 368. 33 409.04 2.65995 0,, 374 0.499 1164 120.000 339.670 0.02206 45.324 0.01479 226.01 372.08 414.05 2.67488 0., 375 0.500 1182

110. 000 349-670 0.02143 46.668 0.01436 232.76 375.85 419.06 2.68938 0,,375 0.500 1199 100.000 359.670 0.02083 48.012 0.01396 239.50 379.62 424.07 2.70349 0.,376 0.501 1216 -90.000 369.670 0.02026 49.355 0.01358 246. 24 383. 39 429.09 2.71723 ,376 0.501 1233

-8 0.000 379.670 0.01972 50.698 0.01322 252.98 387.18 434.12 2.73062 0.. 377 0.502 1249

-70. 000 389.670 0.01922 52.041 0.01288 259.72 390.97 439.15 2.74368 0.,378 0.503 1265 -60.000 399.670 0.01873 53.384 0.01255 266.45 394.77 •44.19 2.75644 0., 379 0.504 1281

-5 0.0 00 409.670 0.01827 54.726 0.01224 273.18 398.56 449.25 2.76891 0., 381 0.505 1296 -40.000 419.670 0.01784 56.068 0.01195 279.90 402.41 454.32 2.78110 0.,382 0.506 1311 -30.000 429.670 0.01742 57.410 0.01167 286.63 406.24 459.40 2.79305 0., 383 0.508 1326

-2 0.000 439.670 0.01702 58.752 0.01140 293. 35 410.10 464.49 2.e0475 0,, 385 0.509 1341 -10.000 449.670 0.01664 60.093 0.01115 300.07 413.97 469.61 2.81623 0.,3 87 0.511 1356 0.000 459.670 0.01628 61.434 0.01090 306.79 417.86 474.74 2. 82749 0., 389 0.513 1370 10.000 469.670 0.01593 62.776 0.01067 313.50 421.77 479.89 2.B3856 0., 391 0.515 1384 20.000 479.670 0.01560 64.117 0.01045 320.22 425.70 485.06 2.84943 0,, 393 0.517 1396 30.000 489.670 0.01528 65.457 0.01023 326.93 429.65 490.25 2.86013 0,,395 0.520 1411

40. 000 499.670 0.01497 66.798 0.01003 333.65 433.62 495.47 2.87066 0,, 398 0.522 1424 50.000 509.670 0.01468 68.139 0.00983 340. 36 437.62 500.71 2. 88103 0,,400 0.525 1438 60.000 519.670 0.01439 69.479 0.00964 347.07 441.65 505.98 2.89125 0,,403 0.527 1450 70.000 529.670 0.01412 70.820 0.00945 353.78 445.71 511.28 2.90133 0,,406 0.530 146 3 80. 000 539.670 0.01386 72.160 0. 00928 360. 49 449.80 516.61 2.°1127 0,,409 0.533 1476 100.000 559.670 0.01336 74.841 0.00895 373.90 458.06 527.35 2.93080 0,,416 0.540 1500 120.000 579.670 0.O1290 77.521 0.00664 387.31 466.46 538.23 2.94987 0,,422 0.547 1524

140. 000 599.670 0.01247 80.201 0.00835 400. 72 475.00 549.26 2.96 85 3 0.,430 0.554 1547

160. 000 619.670 0.01207 92. 880 0.00808 414.12 483.70 560.43 2.96684 , ,438 0.562 1569 180.000 639.670 0.01169 95.560 0.00782 427.53 492.55 571.77 3.00481 0,,446 0.570 1591 200.000 659.670 0.01133 88.239 0.00759 440.93 501.57 583.26 3.02249 0.,454 0.578 1613

22 0.00 679.670 0.01103 90.918 0.00736 454.33 510.76 594.93 3. 03989 0.,463 0.587 1634 240.000 699.670 0.01063 93.597 0.00715 467.73 520.12 606.78 3.05704 0,,472 0.596 1654 280.000 739.670 0.01011 99.954 0.00676 494. 52 539.40 631.02 3. 09068 0.,490 0.514 1694 320.000 779.670 0.00959 104.311 0.00642 521. 31 559.43 656.01 3.12354 0.,509 0.633 1733 360.000 819.670 0.00912 109.667 0.00610 548.09 580. 22 681.76 3.15570 0. 529 0.653 1771 400.000 859.670 0.00869 115.023 0.00582 574.87 601.78 708.27 3.16725 0.,548 0.672 1807

440. 000 899.670 0. 00831 120.379 0.00556 601.65 624. 10 735.55 3.21823 0,,567 0.691 1843

211
ME THANSi ISOBAR AT P 10.0 PSI

T T OEN VOL DP/OT OP/DO E H S C\l CP W OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/L3/R FT/S

296, 420 163 250 28.191 0. 03547 166.979 3623.73 93 11 93.17 1. 01127 .493 .786 5172

29 ,000 169 670 27.894 0.03585 159.548 3426.22 97 92 97.99 1. 04167 .491 .791 5057

280 000 179 670 27.423 0.03647 148.508 3122.77 105 65 105.72 1. 08734 .492 ,305 4863

270 000 189 670 26.942 0. 03712 138.073 2827.73 113 .62 113.69 1.13133 .493 .820 4665

266 790 192 880 26.784 0. 03734 134.842 2735. 26 116 23 116.30 1.14512 .493 .824 4601

266, 790 192 880 0.07956 12.569 0.05433 122.29 316 28 339.56 2.30317 .377 .513 878

260 000 199 670 0.07666 13.045 0.05223 127. 27 318 88 343.04 2.32088 . 376 511 895

250 000 209 670 0.07278 13.741 0.04945 134.52 322 70 348.14 2.34579 . 375 509 919

240. 000 219. 670 0.06929 14.433 0.04693 141.69 326 5 'J 353.22 2. 36944 .375 ,507 942

230 000 229 670 0.06613 15. 122 0. 04476 148.79 330 29 358.29 2.39197 .374 ,505 965

220, 000 239 670 0.06326 15.809 0.04276 155. 85 334 07 363.34 2.41348 .374 ,504 987

210, 000 249 670 0.06063 16.494 0. 04094 162. 86 337 84 368.38 2.43406 374 503 1008

200. 000 259. 670 0.05822 17.177 0.03927 169.83 341, 61 373.42 2.45381 ,374 502 1029

190. 000 269. 670 0.05603 17.858 0.03775 176.78 345. 37 378.44 2.47278 ,374 502 1049

180. 000 279. 670 0.C5394 18.539 0.C3634 183.70 349. 13 383.46 2.49105 .373 .501 1069

170. 000 289. 670 0.05203 19.218 0. 03503 190.60 352. 89 368.48 2.50866 374 ,501 1088

160 000 299. 670 0.05026 19.897 0.03382 197. 49 356 65 393.50 2.52566 .374 ,501 1108

150. 000 309. 670 0. 04860 20.574 0.03269 204. 35 360. 41 398.51 2.54210 n ,374 501 1126

1<«0. 000 319. 670 0.04706 21.251 0. 03164 211.20 364, 17 403.52 2.55802 .374 ,501 1145

130. 000 329. 670 0.04561 21.927 0. 03066 218. 04 367 93 408.54 2.57344 ,374 501 1163

120. 000 339. 670 0.04424 22.603 0.02973 224.87 371 70 413.55 2.58842 375 501 1180

110. 000 349, 670 0.04296 2 3.27 8 0.02886 231.68 375. 47 418.57 2.60296 .375 501 1198

100. 000 359. 670 0.04175 23.953 0.02804 238.49 379. 24 423.59 2.61711 .376 502 1215

-90. 000 369. 670 0. 04061 24.627 0. 02727 245. 29 383. C2 428.62 2.63088 .377 502 1231

-80. 000 379. 670 0.03952 25.301 0.02653 252.08 386. 80 433.65 2.644 30 377 503 1248

-70. 000 389. 670 0. 03850 25.975 0.02584 258.67 390. 6C 438.70 2.65739 378 504 1264

-60. 000 399. 670 0.03753 26.649 0.02518 265.64 394. 40 443.75 2.67017 379 505 1280

-50. 000 409. 670 0. 03660 27. 322 0. 02456 272.42 398. 21 4 48.81 2.68267 . 381 506 1295

-"0. 000 419. 670 0. 03572 27.995 0.02397 279.19 402, 04 453.88 2.69488 382 307 1311

-30. 000 429. 670 0. 03488 28.667 0.02340 285.95 405 86 458.96 2.70685 383 509 1326

-20. 000 439. 670 0.03403 29.340 0.02286 292.71 409, 74 464. 06 2.71857 385 510 1340

-10. 000 449. 670 0. 03332 30.012 0.02235 299.47 413 61 469.18 2.73006 ,367 512 1355

0. 000 459. 670 0.03259 30.684 0.02186 306.22 417. 5C 474.31 2.74134 389 514 1369

10. 000 469. 670 0.03189 31.356 0.02139 312.97 421. 40 479.47 2.75242 391 516 1383

20. 000 479. 670 0.C3122 32.028 0.02094 319. 71 425. 33 "84.64 2.76331 393 518 1397

30. 000 489. 670 0.03053 32.699 0.02050 326. 45 429. 29 489.84 2.77402 395 520 1411

"0. 000 499. 670 0.02997 33.371 0.02009 333. 19 433. 26 495.06 2.78456 398 523 1424

50. 000 509. 67 0.02938 34.042 0.01969 339.93 437. 2f 500.30 2.79494 400 525 1437

60. 000 519. 670 0.02881 34.713 0.01931 346. 67 441. 29 505.57 2. 80517 403 0. 528 1450

70. 000 529. 670 0.02826 35.385 0.01894 353. 40 445. 35 510.87 2.81526 406 0. 531 1463

80. 000 539. 670 0.02773 36.056 0.01859 360. 13 449. 43 516.20 2. 82521 409 a. 53* 1*75

100. 000 559. 670 0.02674 37.398 0.01792 373.59 457. 70 526.95 2.84475 416 0, 5*0 1500

120. 000 579. 670 0.02581 38.739 0. 01730 337. 03 466. 09 537.83 2. 86 3 84 0. 423 547 1524

I<t0, 000 599. 670 0.02495 40.080 0. 01672 400.48 474. 63 548.85 2.88251 430 554 1547

160. 000 619. 670 0.02414 41.421 0.01617 413. 92 483. 32 560.03 2.90083 0. 438 0. 562 1569

180. 000 639. 670 0.02339 42.762 0.01567 427. 35 492. 17 571.36 2.91881 0. 446 0, 570 1591

200. 000 659. 670 0.02267 44.103 0.01519 440. 78 501. 1° 582.86 2.93649 454 0. 579 1613

220. 000 679. 670 0.02201 45.443 0.01474 454. 20 510. 3e 594.53 2.95390 463 J. 587 1634

240. 000 699. 670 0.02138 46.783 0.01432 467.62 519. 74 606.37 2. 97107 472 0. 596 1654

280. 000 739. 670 0.02022 49.463 0.01354 494.1,5 539. 02 630.61 3. 00472 0. 490 0. 615 1694

320. 000 779. 670 0.01918 52. 142 0.01284 521.28 559. 04 655.59 3.03758 509 0. 634 1733

36 0. 000 319. 670 0. 01824 54.821 0.01221 548. 09 579. 62 681.34 3.06976 0, 529 0, o53 1771

<f00. 000 859. 670 0.01739 57.500 0.01164 574.90 601. 37 707.65 3. 10131 0. 548 0. 672 1807

1*1*0. 000 899. 670 0.01662 60.178 0.01112 601.69 623. 69 735.12 3. 13230 0. 567 0. 691 13*3

212
METHANE ISOBAR AT P = 15.0 PSI

T T DEN VOL DP/DT OP/OD E H S CV CP H OEG F OEG R LB/CUFT CUFT/L8 PSI/R PSICUFT/LB 9TU/LB BTU/L8 BTU/LB/R BTU/L8/R BTU/LB/R FT/S

296.404 163.266 28.192 0.03547 166.970 3624.40 93.11 93.21 1.01130 0.493 0.786 5172 290.000 169.670 27.895 0.03585 159.560 3427. 42 97.91 98.01 1. 04162 0.491 0.791 5057 2S0.000 179.670 27.425 0.03646 148.523 3124. 08 105.64 105.74 1.08728 0.492 0.805 4864

•270.000 189.670 26.944 0.03711 138.091 2829.13 113.61 113.71 1. 13127 0.493 0.820 4666

'260.000 199.670 26.448 0.03781 128.201 2545.13 121.79 121.89 1.17373 0.492 0.833 4469

•258.284 201.386 26.361 0.03793 126.554 2497.60 123.21 123.31 1.18088 0.491 0.836 4435 258.284 201.386 0.11537 8.667 0.07938 125.21 318.97 343.05 2.27230 0.379 0.520 892 •250.000 209.670 0.11037 9.060 0.07566 131.48 322.18 347.34 2.29 318 0. 378 0.516 913 •240.000 219.670 0.10492 9.531 0.07167 138.92 326.02 352.49 2. 31716 0. 376 0.513 937 230.000 229.670 0.10002 9.998 0.06814 146.26 329.84 357.61 2.33995 0.376 0.511 960 •220.000 239.670 0.09558 10.462 0.06498 153.51 333.65 362.71 2.36167 0.375 0.509 982 210.000 249.670 0.09154 10.925 0.06212 160.70 337.45 367.80 2.38243 0. 375 0.507 1004 200.000 259.670 0.08783 11.385 0.05952 167. 83 341.24 372.86 2.40233 0. 374 0.506 1025 190.000 269.670 0.08443 11.844 0.05715 174.92 345.02 377.92 2.4214 3 0.374 0.505 1046 180.000 279.670 0.08129 12.302 0.05496 181.97 348. 8C 382.97 2.43980 0.374 0.504 1066

•170.000 289.670 0.07838 12.759 0.05295 188. 98 352.58 388.01 2.45751 0.374 0.504 1086 160.000 299.670 0.07568 13.214 0. 05109 195.96 356. 35 393.05 2.47459 0. 374 0.503 1105 150.000 309.670 0.07316 13.669 0.04935 202.92 360.12 398.09 2.49110 0.374 0.503 1124 140.000 319.670 0.07081 14.123 0.04774 209. 86 363.89 403.12 2.50708 0. 374 0.503 1142 130.000 329.670 0.06860 14.576 0.04623 216.77 367.66 408.15 2.52256 0.375 0.503 1161 120.000 339.670 0.06654 15.029 0. 04482 223.67 371.43 413.18 2.53758 0.375 0.503 1178 110.000 349.670 0.06459 15.482 0.04349 230.55 375.21 418.21 2.55217 0.376 0.503 1196 100.000 359.670 0.06276 15.934 0.04224 237.42 378.96 423.24 2.56636 0.376 0.503 1213 -90.000 369.670 0.06103 16.385 0.04106 244.28 382.77 428.28 2.58016 0.377 0.504 1230

-80. 000 379.670 0.05940 16.836 0.03995 251.13 386.56 433.32 2.59362 0.378 0.504 1246 -70.000 389.670 0.05785 17.287 0.03890 257.96 390. 36 438.37 2.60674 0.379 0.505 1263

-6 0.0 00 399.670 0.05638 17.737 0.03790 264.79 394.17 443.43 2.61955 0.380 0.506 1279 -50.000 409.670 0.05498 18.188 0.03695 271.61 397.98 448.50 2.63206 0.381 0.507 1294

-40. 000 419.670 0.06365 18.638 0.03605 278.42 401.81 453.58 2.64430 0. 382 0.508 1310 -30.000 429.670 0.05239 19.087 0.03520 285.22 405.66 458.67 2.65629 0.384 0.510 1325

-2 0.00 439.670 0.05119 19.537 0.03438 292.02 409.51 463.78 2.66803 0. 385 0.511 1340 -10.000 449.670 0.05003 19.986 0.03360 298.81 413.39 468.90 2.67954 0. 3 87 0.513 1354

0. 000 459.670 0. 04894 20.435 0.03286 305.59 417.28 474.04 2.69063 0. 389 0.514 1369 10.000 469.670 0.04788 20.884 0.03215 312.37 421. 19 479.20 2.70192 0.391 0.516 1383 20.000 479.670 0.04688 21.333 0.03147 319. 15 425.12 484.38 2.71283 0.393 0.519 1397 30.000 489.670 0.04591 21.782 0.03082 325.92 429. OP 489.58 2.72355 0. 395 0.521 1410

40. 000 499.670 0.04498 22.230 0.03019 332.69 433.05 494.80 2.73410 0.398 0.523 1424 50.000 509.670 0.04409 22.679 0.02959 339.45 437.06 500.05 2.71.449 0.401 0.526 1437 60.000 519.670 0.04324 23.127 0.02901 346.21 441.09 505.3? 2.75473 0.403 0.528 1450 70.000 529.670 0.04242 23.575 0.02846 352.97 445. 14 510.62 2.76483 0.406 0.531 146 3 80.000 539.670 0.04163 24.023 0.02793 359.72 449.23 515.96 2.77480 0.409 0.534 1475 100.000 559.670 0.04013 24.919 0.02692 373.22 457.50 526.71 2.79435 0.416 0.541 1500 120.000 579.670 0.03874 25.815 0.02598 386. 71 465. 9G 537.60 2.81345 0.423 0.547 1523 140.000 599.670 0.03744 26.710 0. 02511 400. 19 474.44 548.63 2.83214 0.430 0.555 1547 160.000 619.670 0.03623 27.605 0. 02429 413.66 483.13 559.80 2.85047 0.438 0.562 1569 180.000 639.670 0.03509 28.499 0.02352 427.12 491.98 571.14 2.86846 0.446 0.571 1591 200.000 659.670 0.03402 29.394 0.02280 440.58 501.00 582.64 2.88615 0.454 0.579 1613

22 0.0 00 679.670 0.03302 30.288 0. 02213 454. 03 510.18 594.31 2.90357 0.463 0.588 1634 240.000 699.670 0.03207 31.182 0.02149 467.47 519.55 606. 16 2.92074 0.472 0.597 1654 280.000 739.670 0.03033 32.970 0.02032 494.35 538.82 630. 4C 2.95441 0.491 0.615 1654

320. 000 779.670 0.02877 34.758 0.01928 521.21 558.85 655.39 2.98723 0.509 0.634 1733

360. 000 819.670 0.02736 36.545 0. 01833 548. 05 579.63 681.14 3.01946 0.529 0.653 1771 400.000 859.670 0.02609 38.331 0.01747 574.89 601. ie 707.65 3.05103 0.548 0.672 1808 440.000 899.670 0.02493 40.117 0.01669 601.71 623. 5C 734.93 3.08202 0.567 0.691 1843

213
ME THflNE ISOBAR AT P 20.0 PSI

T T OEN VOL OP/OT DP/DO E H S CV CP H DEG F OEG R L8/CUFT CUFT/LB PSI/R PSICUFT/LB 8TU/LP 3TU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S

296.388 163.282 28.193 0.03547 166.960 3625. 07 93. 11 93.24 1.01132 0.493 0. 786 5173 290.000 169.670 27.897 0.03585 159.571 3428.63 97. 90 98.04 1. 04156 0.491 0. 791 5058 280.000 179.670 27.427 0.03646 148.537 3125.39 105. 63 105.76 1. 08722 0.492 805 4865 270.000 189.670 26.945 0.03711 138.108 2830.54 113. 60 113.74 1.13120 0.494 0, 320 4666

260. 000 199.670 26.450 0.03781 128.221 2546.61 121. 77 121.91 1.17367 0.492 833 4470 251.750 207.920 26.028 0.03842 120.426 2321.65 128. 65 128.79 1.20762 0. 489 0. 344 4310 251.750 207.920 0. 15028 6.654 0. 10412 126. 98 320. 97 345.61 2. 25064 0.380 526 902 250.000 209.670 0.14885 6.718 0.10302 128.36 321. 65 346.53 2.25 504 0. 380 525 9(16 240.000 219.670 0.14128 7.078 0.09729 136. 10 325. 55 351.76 2.27 938 0. 378 520 931 230.000 229.670 0.13451 7.434 0.09227 143.69 329. 41 356.94 2.30245 0.377 516 955

220. 000 239.670 0.12840 7.788 0. 08781 151. 15 333. 25 362.10 2.32440 0.376 0. 514 978 210.000 249.670 0.12286 8.139 0.08381 158.52 337. 08 367.22 2.34535 0.376 511 1000 200.000 259.670 0. 11780 8.489 0.08020 165.82 340. 89 372.33 2.36540 0.375 510 1021 190.000 269.670 0.11317 8.836 0.07692 173.04 344, 70 377.42 2. 38464 0.375 508 1042

180. 000 279.670 0.10890 9.183 0.07391 180.22 348, 49 382.50 2.40312 0.375 507 1063 170.000 289.670 0.10495 9.528 0.07115 187.34 352. 28 387.57 2.42092 0. 375 506 1083 160.000 299.670 0.10129 9.872 0.06859 194. 43 356 07 392.63 2.43809 0.375 505 1103 150.000 309.670 0.09789 10.216 0.06623 201.48 359. 85 397.68 2. 45468 0. 375 505 1122

140. 000 319.670 0. 09471 10.559 0.06403 208.50 363 63 402.73 2.47072 0.375 505 1140 130.000 329.670 0.09174 10.901 0.06198 215.49 367, 41 407.78 2.48626 0.375 504 1159

120. 000 339.670 0.08895 11. 242 0. 06006 222.47 371. 19 412.83 2. 50133 0.375 .504 1177 110.000 349.670 0.08633 11.583 0.05826 229. 42 374. 9P 417.87 2.51596 0. 376 504 1194

100. 000 359.670 0. 08387 11.924 0.05657 236.35 378. 76 422.92 2.53019 0.376 505 1212 -90.000 369.670 0.06154 12.264 0.05497 243.26 382 55 427.97 2.54403 0. 377 505 1229 -80.000 379.670 0.07934 12.603 0.05347 250. 16 386. 35 433.03 2.55752 0. 378 506 1245 -70.0 00 389.670 0.07726 12.94 3 0. 05205 257. 05 390. 15 438.09 2.57 67 0. 379 506 1262 -60.000 399.670 0.07529 13.282 0.05070 263.92 393. 97 443.16 2.58350 0.380 507 1278 -50.000 409.670 0.07342 13.620 0.04943 270.78 397. 79 448.23 2.59604 0.381 508 1293 -'0.000 419.670 0.07164 13.959 0.04821 277.63 401 62 453.32 2.60831 0. 382 ,509 1309 -30.000 -.29.670 0. 06994 14.297 0.04706 284. 48 405. 47 458.42 2.62031 0.384 510 1324 -20.000 439.670 0.06833 14.635 0.04596 291.31 409 33 463.53 2.63207 0.365 512 1339 -10.000 449.670 0.06679 14.973 0.04492 298. 14 413, 21 468.66 2.64 360 0.387 513 1354 0.000 459.670 0.06531 15. 311 0.04392 304.96 417, 11 473.81 2.65491 0.389 515 1368

10. 000 469.670 0.06391 15.648 0.04296 311.77 421 02 478.97 2.66602 0.391 517 1382

20. 000 479.670 0.06256 15.986 0.04205 318.57 424. 95 484.16 2.67693 0. 393 519 1396

30. 000 489.670 0.06126 16.323 0.04117 325.37 428 91 489.36 2.68767 0.3 96 521 1410

40. 000 499.670 0.06002 16.660 0. 04033 332. 17 432 89 494.59 2.69823 0.398 524 1423 50.000 509.670 0.05883 16.997 0.03953 338.96 436. 90 499.84 2.70864 0.401 526 1436

60. 000 519.670 0.05769 17.334 0.03875 345.74 440 93 505.1? 2.71889 0.403 529 1449

70. 000 529.670 0.05659 17.670 0.03801 352.52 444 99 510.43 2.72900 0.406 532 1462 80.000 539.670 0.05553 18.007 0.03729 359. 30 449 07 515.76 2.73897 0.409 535 1475 100.000 559.670 0.05353 18.680 0.C3594 372. 64 457, 34 526.53 2.75854 0.416 541 1499

120. 000 579.670 0. 05167 19.352 0.03468 386.36 465, 75 537.42 2.77765 0.423 548 1523

140. 000 599.670 0.04994 20.025 0.03351 399. 68 474 29 548.45 2.79636 0.430 555 1546 160.000 619.670 0.04832 20.697 0.03242 413. 38 482, 99 559.64 2.ei469 0.438 ,563 1569 180.000 639.670 0.04680 21.368 0.03140 426. 87 491. 84 570.98 2.83270 0. 446 n 571 1591 200.000 659.670 0.04537 22.040 0.03043 440.36 500 86 582.48 2.85040 0.454 579 1613 220.000 679.670 0.04403 22.711 0.02953 453.83 510. 05 594.16 2.867 83 0.463 588 1634 240.000 699.670 0.04277 23.383 0.02868 467.30 519. 41 606.01 2.88501 0.472 597 1654 280.000 739.670 0.04045 24.724 0. 02712 494. 22 533. 69 630.26 2.91869 0.491 615 1694 320.000 779.670 0.03836 26.066 0.02572 521. 12 558 72 655.25 2.95157 0.509 634 1733 360.000 819.670 0.03649 27.407 0.02445 548.00 579, 50 681.00 2.98376 0.529 653 1771

400. 000 859.670 0.03479 28.747 0.02331 574.86 601 05 707.52 3.01533 0.548 672 1808

440. 000 899.670 0.03324 30.087 0. 02227 601.71 623 37 734.80 3. 04633 0.567 691 1844

214
METHANE ISOBAR AT P = 25.0 PSI

T T OEN VOL DP/OT OP/DD E H S CV CP W DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R eTU/L3/R FT/S 296.372 163.298 28.193 0.03547 166.951 3625.74 93.11 93.28 1.01134 0.493 0.786 5173

290. 000 169.670 27.898 0.03584 159.583 3429.83 97.89 98.06 1.04151 0.491 0.791 5058 260.000 179.670 27.428 0.03646 148.552 3126.70 105.62 105.79 1.08716 0.492 0.304 4865

27 0.000 189.670 26.947 0.03711 138.125 2831. 94 113.59 113.76 1.13114 0.494 0.819 4667 260.000 199.670 26.452 0.03780 128.241 2548. 09 121.76 121.94 1.17360 0.492 0. 833 4471 250.000 209.670 25.939 0.03855 118.835 2276.63 130.10 130.28 1.21462 0.488 0.846 4277

246.365 213.305 25.748 0.03884 115.521 2181.19 133.17 133.35 1.22919 0.486 0.350 4206 246.365 213.305 0.18457 5.418 0.12870 128.11 322.56 347.64 2.23393 0.382 0.532 909 240.000 219.670 0. 17841 5.605 0.12390 133.22 3 25.06 351.01 2.24951 0.381 0.528 925 230.000 229.670 0.16963 5.895 0.11718 141. 07 328.97 356.26 2.27289 0.379 0.523 950 220.000 239.670 0.16175 6.183 0.11129 148.76 332.85 361.47 2.29508 0.378 0.519 973 210.000 249.670 0.15462 6.467 0.10605 156.33 336.71 366.65 2. 31623 0. 377 0.516 996

200. 000 259.670 0.14814 6.750 0.10134 163.79 340.55 371.80 2.33645 0. 376 0.514 1018 190.000 269.670 0.14222 7.031 0.09708 171. 16 344.37 376.92 2.35582 0. 376 0.512 1039 180.000 279.670 0.13678 7.311 0.09319 178.46 348.19 382.03 2.37442 0.375 0.510 1060 170.000 289.670 0.13176 7.590 0.08963 185.70 352. OC 387.13 2.39232 0. 375 0.509 1080

160. 000 299.670 0.12711 7.867 0.08636 192.89 355.80 392.22 2.40958 0.375 0.508 1100 150.000 309.670 0.12279 8.144 0.08333 200. 04 359.59 397.29 2.42623 0.375 0.507 1119 140.000 319.670 0.11877 8.420 0.08051 207.15 363.38 402.36 2.44234 0.375 3.507 1138 130.000 329.670 0.11501 8.695 0.07790 214. 22 367. 18 407.43 2.45794 0. 375 0.506 1157 120.000 339.670 0.11149 8.970 0.07545 221.26 370.97 412.49 2.47306 0.376 0.506 1175 110.000 349.670 0.10818 9.244 0.07316 228.28 374.76 417.55 2.48774 0.376 0.506 1193 100.000 359.670 0.10507 9.517 0.07102 235.27 378.55 422.61 2.50201 0.377 0.506 1210 -90.000 369.670 0. 10214 9.791 0. 06900 242. 24 382.35 427.68 2.51589 0.377 0.506 1227 -80.000 379.670 0.09937 10.063 0.06709 249.20 3 86. 16 432.74 2.52941 0.378 0.507 1244 -70.000 389.670 0.09675 10.336 0.06529 256. 13 389.97 437.81 2.54259 0.379 0.507 1260 -60.000 399.670 0.09427 10.608 0.06359 263.05 393.78 1.42.89 2.55545 0.380 0.508 1276

-50. 000 409.670 0.09191 10. 880 0.06198 269. 96 397.61 447.98 2.56802 0.381 0.509 1292 -40.000 419.670 0.08967 11.152 0.06045 276.85 401.45 453. oe 2.58030 0.382 0.510 1308 -30.000 429.670 0.08754 11.423 0.05899 283.73 405. 3T 458.18 2.59 2 33 0.384 0.511 1323 -20.000 439.670 0.08551 11.694 0.05760 290.60 409.17 463.30 2.60411 0.3 86 0.513 1338

-10. 000 449-670 0. 08358 11.965 0. 05628 297.46 413.05 468.44 2.61565 0. 387 0.514 1353

0.000 459.670 0.08173 12.236 0.05502 304. 32 416.95 473.59 2.62698 0.389 0.516 1367 10.000 469.670 0.07996 12.507 0.05382 311. 16 420.87 478.76 2.63810 0. 391 0.518 1381 20.000 479.670 0.07827 12.777 0.05267 317.99 424. 8CI 483.95 2.64903 0. 393 0.520 1395 30.000 489.670 0.07664 13.047 0.05157 324. 82 428.76 489.16 2.65978 0.396 0.522 1409 40.000 499.670 0.07509 13.317 0.05051 331.64 432.75 494.40 2.67036 0.398 0.524 1423 50.000 509.670 0.07360 13.588 0.04950 338.46 436.75 499.66 2.68077 0.401 0.527 1436 60.000 519.670 0.07216 13.857 0.04852 345.26 440.79 504.94 2.69103 0.403 0.529 1449

70. 000 529.670 0.07078 14.127 0.04759 352.07 444.85 510.25 2.70115 0.406 0.532 1462 80.000 539.670 0.06946 14.397 0.04669 358.66 448.91* 515.59 2.71114 0.409 0.535 1474 100.000 559.670 0.06695 14.936 0.04499 372.45 457.22 526.36 2.73072 0.416 0.541 1499 120.000 579.670 0.06462 15.475 0. 04341 386. 01 465.62 537.26 2.74985 0.423 0.548 1523 140.000 599.670 0.06245 16.014 0.04194 399.56 474.17 5 4 8.30 2.76857 0.430 0.555 1546

160. 000 619.670 0.06042 16.552 0.04057 413.09 482.87 559.49 2.78692 0.438 0.563 1569 180.000 639.670 0.05851 17.090 0.03928 426.62 491.72 570.84 2.80493 0.446 0.571 1591 200.000 659.670 0.05673 17.628 0. 03808 440. 13 500.74 582.35 2.82264 0.454 0.580 1613 220.000 679.670 0.05505 18.165 0.03695 453.63 509.94 594.03 2.84008 0.463 0.58e 1634 240.000 699.670 0.05347 18.702 0.03588 467. 12 519. 3C 605.89 2.85726 0.472 0.597 1654 280.000 739.670 0.05056 19.777 0.03392 494.08 53e.59 630.14 2.89096 0.491 0.615 1694

32 0.0 00 779.670 0.04796 20. 851 0.03216 521. 02 558.61 655. 14 2.92386 0.510 0.634 1733

36 0.0 00 819.670 0.04561 21.924 0.03058 547.93 579.40 680.89 2.95606 0.529 0.653 1771 400.000 859.670 0.04348 22.997 0.02915 574.82 600.96 707.42 2.98764 0.548 0.672 1808

440. 000 899.670 0.04155 24.070 0.02785 601.70 623.27 734.70 3.01864 0.567 0.691 1844

215
ME THANE ISO 8AR AT P = 30.0 PSI

T T OEN VOL DP/OT DP/OD E H S cv CP H OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 8TU/LB BTU/LB BTU/LB/R BTU/LB/R 8TU/L8/R FT/S

296.356 163.314 28.194 0.03547 166.942 3626.41 93. 12 93.31 1. 01136 0. 493 0.786 5173 290.000 169.670 27.900 0.03584 159.594 3431. 03 97. 88 98.08 1. 04145 0. 491 0.791 5059

260. 000 179.670 27.430 0.03646 148.566 3128. 01 105. 61 105.81 1.08711 492 0.804 4866 270.000 189.670 26.949 0.03711 136.142 2833.34 113. 57 113.78 1. 13108 494 0.819 4668 260.000 199.670 26.454 0.03780 128.262 2549.58 121 75 121.96 1.17353 0. 492 0.833 4471 250.000 209.670 25.942 0.03855 118.858 2278. 19 130. 09 130.30 1. 21455 0. 466 0. 345 4278

21*1.71*1* 217.926 25.504 0.03921 111.408 2063.97 137 08 137.30 1.24740 483 0.856 4118

2W1.7ki* 217.926 0.21842 4.578 0. 15324 128. 82 323. 87 349.31 2.22032 0, 383 0.538 915 240.000 219.670 0.21637 4.622 0.15159 130.27 324, 57 350.24 2.22460 0. 383 0.536 919

230. 000 229.670 0.20541 4. 868 0.14296 138.41 328. 53 355.57 2.24831 381 0.530 9^4 220.000 239.670 0.19563 5.112 0. 13546 146.34 332 44 360.84 2.27077 379 0.525 969

210. 000 249.670 0.18684 5.352 0.12885 154. 11 336. 33 366.07 2.29213 0. 378 0.521 992

200. 000 259.670 0. 17886 5.591 0.12295 161.74 340 20 371.26 2. 31252 377 0.518 1014

19 0. 000 269.670 0. 17160 5.828 0.11764 169.26 344 05 376.42 2.33204 377 0.515 1036 180.000 279.670 0. 16494 6.063 0.11282 176.70 347 89 381.57 2.35076 376 0.513 1057 170.000 289.670 0.15880 6.297 0.10842 184. 06 351 71 386.69 2.36876 376 0.512 1077

160. 000 299.670 0.1531* 6.530 0.10438 191.36 355 53 391.80 2.38610 376 0.510 1098

150. 000 309.670 0.14788 6.762 0.10065 198.60 359 34 396.90 2.40284 376 0.509 1117

140. 000 319.670 0.14299 6.994 0.09720 205.79 363, 14 401.99 2.41902 376 0.509 1136

130. 000 329.670 0.13842 7.224 0.09400 212.95 366 94 407.08 2.43467 376 0.508 1155 120.000 339.670 0.13415 7.455 0. 09101 220. 06 370. 75 412.16 2.44985 376 0.508 1173 110.000 349.670 0. 13014 7.684 0.08821 227. 15 374 55 417.23 2.46457 376 3.507 1191 100.000 359.670 0.12637 7.913 0.08559 234.20 378 35 422.31 2.47 888 377 0.507 1209 -90.000 369.670 0. 12282 8.142 0.08313 241.23 382. 16 427.38 2.49280 ,378 0.508 1226

-80. 000 379.670 0.11947 8. 370 0. 08082 248. 24 385 97 432.46 2.50635 378 0.508 1243 -70.000 389.670 0.11631 8.598 0.07863 255.22 389 76 437.55 2.51956 379 3.508 1259 -60.000 399.670 0.11331 8.826 0.07656 262.19 393 61 442.64 2.53245 380 0.509 1275 -50.000 409.670 0. 11046 9.053 0.07461 269.14 397 ,44 447.73 2.54504 ,381 0.510 1291 -40.000 419.670 0. 10776 9. 280 0.07275 276. 07 401. 29 452.84 2.55735 ,383 0.511 1307 -30.000 429.670 0.10519 9.507 0.07099 282.99 405 14 457.95 2.56940 .384 3.512 1322 -20.000 439.670 0.1027* 9.733 0.06931 289.90 409 01 463.08 2.58120 386 0.513 1337

-10. 000 449.670 0.10040 9.960 0.06771 296.79 412 .90 468.23 2.59276 ,3 87 0.515 1352

0. 000 459.670 0.09817 10. 186 0. 06618 303.68 416 80 473.39 2.60411 .389 3.517 1367 10.000 469.670 0.09604 10.412 0.06473 310.55 420 72 -.78.56 2.61524 391 3.518 1381

20. 000 479.670 0.09400 10.638 0.06334 317.41 424. St 483.76 2.62619 393 0.520 1395 30.000 489.670 0.09205 10.864 0.06200 324.27 428, 63 488.98 2.63695 396 0.523 1409

40. 000 499. 670 0.09018 11. 089 0.0607 3 331.12 432 61 494.22 2.64754 o 398 0.525 1422 50.000 509.670 0.08838 11.315 0.05950 337.96 436, 62 499.46 2.65796 401 0.527 1435 60.000 519.670 0.08665 11 .540 0.05833 344.79 440 66 504.77 2.66824 404 3.530 1448 70.000 529.670 0.08500 11.765 0.05720 351.61 444. 72 510.08 2.67836 406 0.533 1461

80. 000 539.670 0.08340 11.99 0.05612 358.43 446 82 515.43 2.68836 409 0.536 1474 100.000 559.670 0.08038 12.44 0.05407 372.06 457, 10 526.21 2.70796 41b 0.542 1499 120.000 579.670 0.07758 12.890 0.05216 385.66 465, 51 537.11 2.72711 423 0.549 1523 140.000 599.670 0.07497 13.339 0.05039 399. 24 474. 06 548.16 2.74584 o. 430 3.556 1546 160.000 619.670 0.07252 13.788 0.04874 412.81 482 76 559.36 2.76420 438 U.563 1569

180. 000 639.670 0.07024 14.237 0. 04719 426.36 491. 62 570.71 2.78222 446 n.;7i 1591 200.000 659.670 0.06809 14.686 0.04574 439.90 500. 64 582.23 2.79994 455 0.580 1612 220.000 679.670 0.06608 15. 134 0.04437 453. 42 509. 84 593.91 2.81739 463 0.588 1634 240.000 699.670 0.06417 15.582 0.04309 466.94 519 21 605.77 2.83458 472 0.597 1654

280. 000 739.670 0.06069 16.478 0.04073 493.94 538. 49 630.03 2.86829 491 0.616 1694 320.000 779.670 0.05756 17.374 0.03862 520.91 558 52 655.04 2.90120 510 0.634 1733

36 0.0 00 819.670 0.05474 18. 269 0.03672 547. 86 579. 32 680.80 2.93341 529 0.653 1771

400. 000 859.670 0.05218 19.163 0.03500 574.78 600 87 707.33 2.96499 548 0.673 18C6

4 40.000 899.670 0.04986 20.058 0.03343 601.68 623. 19 734.62 2.996 01 567 0.691 1844

216
METHANE ISOBAR AT P = 40.0 PSI

T T OEN VOL DP/DT OP/OO F H S CV CP W DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/L6 3TU/L8 BTU/LB/R BTU/LB/R BTU/LB/R FT/S 296.324 163.346 28.195 0.03547 166.924 3627.74 93.12 93.39 1.01140 0.493 0,,786 5173 290.000 169.670 27.903 0.03584 159.616 3433.43 97.87 96.13 1.04134 0.491 0,,791 5060 280.000 179.670 27.433 0.03645 148.594 3130.63 105.58 105.65 1. 08699 0.492 0.,304 4867

270. 000 189.670 26.952 0.03710 138.177 2836.14 113.55 113.83 1.13095 0.494 0,,819 4669

260. 000 199.670 26.458 0.03780 128.302 2552.54 121.72 122.00 1.17340 0.492 0,,833 4473 250.000 209.670 25.946 0.03854 118.904 2281.31 130.06 130.34 1.21441 .488 0,.845 4279

21*0.000 219.670 25.414 0.03935 109.919 2023. 12 138.54 138.83 1.25407 0.482 0..858 4066 234.014 225.656 25.084 0.03987 104.713 1874.80 143.69 143.98 1.27724 0.478 0,,866 3968 234.014 225.656 0.28524 3.506 0.20243 129.43 325.97 351.94 2.19886 0.3 86 0,,549 923 230.000 229.670 0.27912 3.583 0.19735 132.91 327.60 354.14 2.20850 0.385 0,.545 934

220. 000 239.670 0.26514 3.772 0. 18605 141. 37 331.61 359.54 2.23154 0.382 0,,537 95 9 210.000 249.670 0.25269 3.957 0.17628 149.58 335.57 364.88 2.25336 0.381 0,,531 963 200.000 259.670 0.24150 4.141 0.16768 157.58 339.50 370.17 2.27412 0.379 0,,526 1007

190. 000 269.670 0.23135 4.322 0.16003 165.43 343.40 375.41 2.29394 0.378 0.,523 1029

180. 000 279.670 0.22210 4.502 0.15315 173.14 347.28 3 8 0.62 2.31292 0.378 0,,520 1051 170.000 289.670 0.21363 4.681 0.14691 180.75 351.14 385.61 2. 33114 0.377 0,,517 1072 160.000 299.670 0.20582 4.859 0.14122 188.27 354.99 390.98 2.34867 0.377 0,,516 1092

150. 000 309.670 0.19860 5.035 0.13600 195.71 358.83 396.12 2.36556 0.377 0.,514 1112 140.000 319.670 0.19190 5.211 0.13119 203.09 362.66 401. 2£ 2.38188 0.377 0,,513 1132 130.000 329.670 0.18566 5.386 0. 12674 210.40 366.49 406.38 2.39766 0.377 0,,512 1151 120.000 339.670 0.17984 5.561 0.12260 217.67 370. 31 411.49 2.41294 0. 377 0,,511 1170 110.000 349.670 0.17438 5.734 0.11875 224.89 374.13 416.60 2.42776 0. 377 0,,511 1188 100.000 359.670 0.16927 5.908 0.11514 232.07 377.95 421.71 2.44215 0.378 0,,510 1206 -90.000 369.670 0.16445 6. 081 0.11176 239.21 381.77 426.81 2.45615 0.378 0.,510 1223

-80. 000 379.670 0.15991 6.253 0.10859 246. 33 385.60 431.92 2.46977 0. 379 0,,510 1240 -70.0 00 389.670 0.15563 6.426 0.10560 253.41 389.43 437.02 2.48304 0. 380 0,,511 1257 -60.000 399.670 0.15157 6.597 0.10277 260.47 393.26 442.13 2.49599 0.381 0..511 1273

-50. 000 409.670 0.14773 6.769 0.10010 267.51 397.11 447.25 2.50863 0. 382 0,,512 1289 -40.000 419.670 0.14408 6.940 0.09758 274.53 400.96 452.37 2.52098 . 383 0,,513 1305 -30.000 429.670 0.14062 7.112 0.09518 281.52 404.83 457.51 2.53307 0. 384 0,,514 1320 -20.000 439.670 0.13732 7.282 0.09290 288.50 408.71 462.65 2.54491 0. 386 0. 515 1336

-10. 000 449.670 0.13417 7.453 0.09073 295.47 412.61 467.81 2.55651 0. 388 0,,517 1351 0.000 459.670 0.13117 7.624 0.08866 302.41 416.52 472.98 2.567 89 0.390 0,,516 1365 10.000 469.670 0.12831 7.794 0.08669 309. 35 420.45 478.17 2.57906 0.392 0,,520 1360 20.000 479.670 0.12557 7.964 0.08481 316. 27 424.40 483.38 2.59003 0. 394 a. 522 1394 30.000 489.670 0.12294 8.134 0.08301 323.18 428.36 488.61 2.60081 0.396 a,.524 1407

1*0.000 499.670 0.12043 8.304 0.08128 330. 08 432.36 •93.86 2.61143 0.398 i,,526 1421 50.000 509.670 0. 11801 8.474 0.07963 336.97 436.37 499.14 2.62188 0.401 0,,52 9 1434 60.000 519.670 0.11570 8.643 0.C7804 343. 85 440.42 504.44 2.63217 0.404 0,,531 1448 70.000 529.670 0.11347 8.813 0.07652 350.72 444.49 509.76 2.64232 0.407 0,,534 1461 80.000 539.670 0.11133 8.982 0.07506 357.58 448.59 515.12 2.65233 0.410 0.,537 1473 100.000 559.670 0.10729 9.321 0.07230 371.28 456.87 525.91 2.67197 0.416 0,,543 1498 120.000 579.670 0.10353 9.659 0. 06974 384.96 465.29 536.84 2.69114 0.423 0.,549 1522 140.000 599.670 0.10003 9.997 0.06735 398.61 473.85 547.90 2.70990 0.430 0, 557 1546 160.00 619.670 0.09677 10.334 0.06513 412.23 482.56 559.11 2.72828 0.438 0,,564 1568 180.000 639.670 0.09371 10.672 0.06305 425.84 491.43 570.47 2.74633 0.446 0,,572 1591

200. 000 659.670 0.09084 11.009 0.06110 439. 44 500.46 582.00 2.76407 0.455 0.,580 1612 220.000 679.670 0.08814 11.34 6 0.05927 453.01 509.66 593.70 2.78153 0.463 0,,569 1633 240.000 699.670 0.08560 11.682 0.05755 466.57 519. 04 605.57 2.79874 0.472 0.,598 1654

280. 000 739.670 0.0809-f 12.355 0.05439 493.66 536.33 629.85 2.83248 0.491 3. 616 1694

320. 000 779.670 0.07676 13.028 0. 05156 520.70 558.37 654.87 2.86541 0.510 0,,635 1733

360. 000 819.670 0.07299 13.700 0.04901 547.71 579.17 680.64 2.89764 0.529 0,,654 1771 400.000 859.670 0.06958 14.371 0.04671 574.68 600.73 707.18 2.92924 0. 548 0. 673 1808

440. 000 899.670 0.06648 15.043 0.04461 601.63 623. oe 734.48 2.96027 0.567 0. 692 1644

217
METHANE ISOBAR AT P 50.0 PSI

T T DEN VOL CP/DT DP/OD E H S cv CP H DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/Le BTU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S

296. 292 163.378 28. 197 0.0351*7 166.906 3629. 08 93.13 93.1*6 1.0111*5 0. 1.93 0. 786 5171* 290.000 169.670 27.906 0.03581. 159.639 31*35. 83 97.85 98.18 1. 01*123 0. 1*91 0. 791 5061 280.000 179.670 27.1*36 0.0361*5 11*8.623 3133.21* 105.56 105.90 1. 08687 0, i»93 0. 801* 1*868 270.000 189.670 26.956 0.03710 138.211 2838.91* 113.53 113.87 1.13083 0. 1*91* 0. 819 1.671 260. 000 199.670 26.1*62 0.03779 128.31*2 2555.50 121. 7C 122.01. 1.17327 0, 1*92 0. 833 1.1.75 250. 000 209.670 25.950 0. 03853 118.950 2281*. 1*2 130. 03 130.39 1.211*26 i»88 0. 81*5 1.281 21*0.000 219.670 25.1*19 0.03931* 109.972 2026. 37 138.51 138.87 1.25391 0. 1*82 0. 857 1*0 88 230.000 229.670 21*. 861. 0.01*022 101.31*5 1781.32 11*7. 13 11.7.50 1.29239 1.75 0, 872 3891 227.617 232.053 21*. 727 0.01*01*1* 99.335 1721*. 78 11*9.21 11.9.58 1.3011.1 0. "*7U 0. 876 381.3 227.617 232.053 0. 35130 2.81.7 0.25200 129.31. 327.60 353.96 2.18216 389 0. 560 929

220. 000 239.670 0.33719 2.966 0.21*000 136.21 330.73 358.19 2.20009 386 1. 551 91*9 210.000 21.9.670 0.32061 3.119 0.22638 11*1.. 91 331.. 77 363.65 2.2221.3 ,383 51.2 975 200.000 259.670 0.30583 3.270 0.211*59 153. 32 338.77 369.01. 2. 21*360 0. 382 n. 536 999 190.000 269.670 0.29253 3.1*18 0.201*22 161.52 31*2.73 371*. 38 2.26376 380 531 1022

180. 000 279.670 0.2801*7 3.565 0. 19i*99 169.53 31.6.65 379.66 2.28301 379 527 10U5 170.000 289.670 0.2691*7 3.711 0. 18669 177.1.0 350.56 381*. 92 2. 30 11*6 376 0. 521. 1066 160.000 299.670 0.25938 3.855 0. 17918 185. 16 351*. «*«* 390.li. 2. 31919 378 3 521 1087 150.000 309.670 0.25008 3.999 0.17232 192.80 358.31 395.31. 2.33625 378 0. 519 1108

11.0.000 319.670 0.2'»1'»7 If. li*l 0. 16603 200.36 362. 17 1*00.52 2.^5271 377 517 1128 130.000 329.670 0.2331.8 1..283 0.16023 207.85 366.02 1.C5.68 2.36861 377 516 111.7 120. 000 339.670 0.22603 ".. 1*21* 0. 151*86 215. 27 369.87 1*10.83 2.381*01 377 515 1166 110.000 31.9.670 0.21908 i*.565 0.11*987 222.63 373.71 1*15.97 2.39893 378 511. 1185 100.000 359.670 0.21256 <*.705 0. 11*522 229.91. 377.55 1*21.11 2.1.131.1 .378 513 1203

-90. 000 369.670 0.2061*3 -i,«H» 0. H.0B6 237.20 381. 3 9 -.26.21. 2.1.271.8 .379 p13 1220 -80.000 379.670 0.20067 <*.983 0.13679 2i*i*. 1*3 385.23 1*31.37 2. 1*1*117 .379 513 1238

-7 0.000 389.670 0. 19523 5.122 0. 13295 251.62 389.07 1*36.50 2.1*51*50 380 Pl3 1251. -60.0 00 399.670 0. 19009 5.261 0. 12931. 258.77 392.93 1*1.1.63 2.1*6751 381 513 1271 -50.000 1*09.670 0. 18523 5.399 0.12593 265.90 396.78 1.1.6.77 2.1.8020 382 51<* 1287

-1*0. 000 1*19.670 0. 18061 5.537 0.12270 272.99 1*00.65 1*51.91 2.1.9261 .383 515 1303

-30. 000 1*29.670 0.17623 5.67<* 0.11961* 280. 07 1*01*. 53 1*57.06 ?. 501*71* , 3e5 516 1319

-20. 000 1*39.670 0. 17206 5.812 0. 11671. 287. 12 1*08.1.2 i*62.23 2.51661 . 386 517 1331. -10.000 1*1*9.670 0. 16809 5.9i*9 0.11398 291.. 15 1*12. 32 i*67.i*0 2.52625 3*8 516 131,9

0. 000 1*59. 670 0.161*31 6.086 0. 11135 301. 17 1*16.21. 1*72.59 2.53966 . 3 90 520 1364 10.000 1*69.670 0.16069 6.223 0.10885 308. 16 i*20. 18 1.77.79 2.55066 .392 1) 321 1378 20.000 i*79.670 0. 15721* 6.360 0. 1061*6 315. It. i*2i*. 13 1.83.02 2.56186 .391* 3 .523 139 2 30.000 1*89.670 0.15393 6.1.96 0. 101*18 322. 11 1*28. 11 1*88.26 2.57267 . 396 525 11.06 (0.000 i*99.670 0. 15077 6.633 0.10199 329.06 1*32.11 1*93.52 2.58331 .3q9 527 11.20 50.000 509.670 0. 11*773 6.769 0.09990 336.00 1*36. 13 1*98.81 2.59378 .1*01 ] 5 30 ll*3<* 60. 000 519.670 0. H*i»82 6.905 0.09769 31*2.92 1*1*0. 18 501*. 12 2.601.10 .1*01* .532 1..1.7 70.000 529.670 0.11*202 7.01*1 0. 09597 31*9. 81* 1*1*1*. 26 509.1*5 2.611.27 1.07 ] 535 11*60 80.000 539.670 0.13933 7.177 0.091*12 356.71* 1*1*8.36 51i*. 81 2.621*30 .1.10 536 11.73 100. 000 559.670 0.131*25 7.i.i*9 0.09063 370.52 1.56.66 525.63 2.6.1*3 97 .1*16 a 5i»i< 11.97 120. 000 579.670 0.12953 7.720 0.0871*0 381.. 27 1*65. 09 536.57 2.66317 ,i*?3 .550 1522

11*0.000 599.670 0.12511* 7.991 0. C8i*i»0 397.99 i*73.66 51.7.65 2.68196 .1*30 D .557 151.5 16 0.000 619.670 0.12101* 8.262 0.08159 1*11.68 1*82. 38 558.87 2.70037 ,1*38 565 1566

180. 000 639.670 0.11 7 20 8.532 0. 07898 1.25. 31* 1*91.25 570.25 2.718U3 .1*1*6 a .573 1590 200.000 659.670 0. 11361 8.802 0.07652 1.38.98 500.29 581.79 2.73619 .1.55 .581 1612

220. 000 679.670 0. 11022 9.072 0. 071*22 1.52. 61 509. 50 593.1.9 2.75367 .1*63 .590 1633

21*0.000 699.670 0. 10701* 9.31*2 0.C7205 1*66.21 516.88 605.37 2.77090 .1.72 .598 1651. 280.0 00 739.670 0. 10120 9. 881 0.06808 1.93. 38 538.18 529.67 2.801.66 .1*91 617 1691* 320.000 779.670 0.09597 10.1*20 0.061*53 520.1*9 558.23 65U. 71 2.83762 .510 <] 635 1733

360. 000 819.670 0.09125 10. 958 0. 06133 51*7.56 579.01. 660.50 2.86987 .529 .351. 1771

1*00.000 859.670 0.08698 11.1.96 0. 058i*i* 57i*. 59 600.61 707.05 2.9011*8 ,51.8 ,s73 1808

i* 1*0. 00 899.670 0.08310 12.031* 0.05581 601.58 622.91. 731*. 36 2.93253 .567 ,o92 181.1.

218
METHANE ISOBAR AT P = 60.0 PSI

T T DEN VOL DP/DT DP/OD E H S CV CP W DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LP 8TU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S 296.260 163.410 28.198 0.03546 166.887 3630.41 93.13 93.53 1.01149 0.494 0.786 5174 290.000 169.670 27.903 0.03583 159.662 3438.23 97.83 98.23 1.04112 0.491 0.791 5062 280.000 179.670 27.439 0.03644 148.652 3135. 85 105.54 105.95 1.08676 0.493 0.804 4869

27 0.000 189.670 26.959 0.03709 138.245 2841.73 113.50 113.92 1.13071 0.4 94 0.319 4672 260.000 199.670 26.466 0.03778 128.382 2558.46 121.67 122.09 1.17314 0.492 0.333 4476 250.000 209.670 25.955 0.03853 118.996 2287.53 130.00 130.43 1.21412 0.488 0.845 4283

21.0.000 219.670 25.424 0.03933 110. 024 2029.63 138.47 138.91 1.25376 0.482 0.357 4090 230.000 229.670 24.869 0.04021 101.405 1784.72 147.09 147.54 1.29222 0.475 0.372 3894

222. 109 237.561 24.412 0.04096 94.812 1600.25 154. 01 154.47 1.32190 0.471 0.886 3733 222.109 237.561 0.41697 2.398 0.30214 128.80 328.92 355.57 2.16843 0.391 0.570 933 220.000 239.670 0.41209 2.427 0.29782 130.81 329.81 356.77 2.17345 0. 390 0.567 939 210.000 249.670 0.39079 2.559 0.27947 140.07 333.95 362.38 2.19639 0. 367 0.555 966 200.000 259.670 0.37200 2.688 0.26389 148.93 338.02 367.88 2.21802 ' 0. 384 0.547 991 190.000 269.670 0.35522 2.815 0.25037 157.51 342.04 373.31 2. 23854 0. 382 0.540 1015

180. 000 279.670 0.34010 2.940 0.23847 165.85 346. 02 378.68 2.25809 . 381 0.534 1038 170.000 289.670 0.32638 3.064 0.22786 174. 00 349.96 384.00 2.27679 .380 0.530 1061 160.0 00 299.670 0.31385 3.186 0.21831 182. 00 353.89 389.29 2.29472 0.379 0.527 1082 150.000 309.670 0.30234 3.307 0.20965 189.86 357.79 394.54 2. 31196 0. 379 0.524 1103

14.0.000 319.670 0.29173 3.428 0.20175 197.62 361 .68 399.77 2.32857 0.378 0.522 1124 130.000 329.670 0.28189 3.547 0.19449 205.28 365.56 404.97 2.34461 0.378 0.520 1143

120. 000 339.670 0.27275 3.666 0.18780 212. 66 369.43 410.16 2.36011 0.378 0.518 1163 110.000 349.670 0.26422 3.785 0.18160 220.36 373.29 415.34 2.37514 0. 378 0.517 1181 100.000 359.670 0.25625 3.902 0.17583 227.80 377.15 420.51 2.38971 0.379 0.516 1200

-90. 000 369.670 0.24877 4.020 0. 17045 235. 19 381. 01 425.67 2.40386 0.379 0.516 1218 -80.000 379.670 0.24174 4. 137 0.16542 242.53 364.86 430.82 2.41762 0.380 0.515 1235 -70.000 389.670 0.23512 4.253 0.16070 249.82 388.72 435.96 2.43102 0. 380 0.515 1252

-6 0. 00 399.670 0.22886 4.369 0.15626 257.07 392.59 441.13 2.44408 0.381 0.516 1269

-5 0.000 409.670 0.22295 4.485 0.15207 264.29 396.46 446.29 2.45 68 3 0. 382 0.516 1285 -40.000 419.670 0. 21735 4.601 0.14812 271.47 400. 34 451.45 2.46928 0.384 0.517 1301

-30. 000 429.670 0. 21203 4.716 0.14438 278.62 404.22 456.62 2.48146 0. 385 0.517 1317 -20.000 439.670 0.20697 4.832 0.14083 285.75 40e. 12 461.80 2.49337 0. 387 3.518 1333 -10.000 449.670 0.20217 4.946 0.13746 292.85 412.04 467.00 2.50504 0. 388 0.520 1348 0.000 459.670 0.1975d 5.061 0.13426 299.93 415.97 472.20 2.51649 0.390 0.521 1363

10. 000 469.670 0.19321 5. 176 0.13121 306.99 419.91 477.42 2.52772 0. 392 0.523 1377 20.000 479.670 0.18903 5.290 0.12830 314.02 423.86 482.65 2.53875 0. 394 0.524 1391 30.000 489.670 0. 18503 5.404 0.12552 321.04 427. 86 487.91 2.54959 0.396 0.526 1405 40.000 499.670 0.18121 5.519 0.12286 328. C5 431. 87 493.18 2.56025 0. 399 0.529 1419

50. 000 509.670 0.17754 5.633 0.12032 335.03 435.90 498.48 2.57075 0.401 0.531 1433

60. 000 519.670 0.17402 5.746 0.11788 342. 01 439.95 503.80 2.58108 0.404 0.533 1446 70.000 529.670 0. 17064 5.860 0.11554 348.97 444. 04 509.15 2.59127 0.407 0.536 1459 80.000 539.670 0.16740 5.974 0.11330 355. 91 448.15 514.52 2.60132 0.410 0.539 1472 100.000 559.670 0.16127 6.201 0.10908 369.78 456.46 525.35 2.62103 0.4 16 0.545 1497 120.000 579.670 0. 15553 6.428 0.10516 383.59 464.89 536.31 2.64026 0.423 0.551 1521

14G. 000 599.670 0. 15029 6.654 0.10152 397. 38 473.47 547.40 2.65907 0.431 0.558 1545 160.000 619.670 0. 14535 6.880 0.09813 411. 13 482. 20 558.64 2.67751 0.438 0.566 1568 180.000 639.670 0.14073 7.106 0.09497 424.85 491.08 570.03 2.69559 0.446 0.573 1590 200.000 659.670 0. 13640 7.332 0.09200 438.54 500. 12 581.56 2.71337 .455 0.582 1612

220. 000 679.670 0.13233 7.557 0.08922 452.22 509.34 593.30 2.73067 0.464 0.590 1633

240. 000 699.670 0. 12350 7.782 0.08660 465. 87 518.73 605.19 2.74811 0.473 0.599 1654 280.000 739.670 0.12147 8.232 0.08181 493. 11 538. 04 629.51 2.78190 0.491 0.617 1694

320. 00 779.670 0. 11518 8.682 0.07753 520.29 558. 1C 654.56 2.81488 0.510 0.636 1733 360.000 819.670 0.10952 9.131 0.07368 547.42 578.92 680.36 2.8h715 0.529 0.655 1771

400. 000 859.670 0.10439 9.579 0.07019 574.50 600.50 706.93 2.87678 0.548 0.674 1808

44 0. 000 899.670 0.09972 10.028 0.06703 601.54 622.84 734.25 2.90984 0.567 0.692 1844

219
METHANE ISOBAR AT P 70.0 PSI

T T OEN VOL CP/OT DP/DO E H S CV CF M DEG F OEG R L8/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

296.229 163.441 28.200 0.03546 166.869 3631.74 93. 14 93.60 1. 01153 0.494 0.785 5174

29 0.000 169.670 27.911 0.03583 159.684 3440.63 97 81 98.27 1 04101 0.492 0.790 5063 280.000 179.670 27.443 0.03644 148.680 3138.46 105. 52 105.99 1 08664 0.493 0.804 4871

270. 000 189.670 26.963 0.03709 138.280 2844.53 113 48 113.96 1 13058 0.494 0.819 4674

260. 000 199.670 26.469 0.03778 128.422 2561.42 121. 64 122.13 1 17300 0.493 0.832 4478

25 0.000 209.670 25.959 0.03852 119.042 2290.63 129. 97 130.47 1 21396 0.488 0.345 4285 240.000 219.670 25.429 0.03933 110.077 2032.88 138 44 138.95 1 25360 0.482 0.657 4092 230.000 229.670 24.875 0.04020 101.464 1788. 12 147 05 147.57 1 29205 0.476 0.871 3696

220. 000 239. 670 24.292 0. 04117 93. 145 1555.75 155 84 156.37 1 32956 0.471 0.890 3692

217. 241 242.429 24.126 0. 0*145 90.893 1493.69 158 30 158.83 1 33978 0.470 0.896 3634

217. 241 242.429 0.48245 2.073 0.35299 127.94 330 01 356.68 2 15671 0.393 0.581 936 210.000 249.670 0.46349 2.158 0. 33596 135. 04 333. 08 361.05 2. 17364 0. 390 0.570 956 200.000 259.670 0.44018 2.272 0. 31584 144.41 337 24 366.68 2 19579 0. 387 0.558 983 190.000 269.670 0.41955 2. 384 0.29865 153.39 341 32 372.2? 2 21671 . 384 0.549 1006 180.000 279.670 0.40109 2.493 0.28369 162.08 345 36 377.68 2 23658 0. 383 0.543 1032 170.000 289.670 0.38443 2.601 0.27048 170.53 349. 36 363.07 2 25554 0. 381 0.537 1055 160.000 299.670 0.36929 2.708 0.25868 178.79 353 32 388.42 2 27369 0. 380 0.533 1077

150. 000 309.670 0.35543 2.ei3 0.24805 186. 88 357. 26 393.73 2 29112 0. 380 0.529 1098 140.000 319.670 0.34269 2. 918 0.23838 194.84 361 18 399.01 2 30789 0. 379 0.526 1119

130. 000 329.670 0.33092 3. 022 0. 22956 202.68 365 C 404.26 2 32407 0. 379 0.524 1139 120.000 339.670 0.32000 3.125 0.22144 210.42 368 98 409.49 2 33969 0.379 0.522 1159 110.000 349.670 0.30984 3.227 0.21395 218.08 372 87 414.70 2 35482 0. 379 0.521 1178 100.000 359.670 0.30035 3.329 0.2070O --. -2-25.66 376 i 75 419.90 > ,36 94'? 0.379 0.519 1197 -90.000 369.670 0.29147 3.431 0.20054 233. 17 380 62 425.09 2 38372 0.380 0.519 1215

-80. 000 379.670 0.28313 3.532 0.19450 240.62 384 49 430.28 2 39755 0.380 0.518 1233 -70.000 389.670 0.27529 3.633 0.18885 248.02 388 37 435.46 2 41102 0.381 0.518 1250 -60.000 399.670 0.26789 3.733 0.18355 255. 37 39? 25 440.63 2 42414 0.382 0.518 1267

-50. 000 "09.670 0.26090 3.833 0. 17855 262.68 396 1? 445.81 2 43694 0.383 0.518 1283 -40.000 419.670 0.25429 3.933 0.17384 269.95 400 02 451.00 2 44944 0. 384 0.519 1300 -30.000 429.670 0.24801 4.032 0.16939 277.16 403 92 56.19 2 46166 0.385 0.519 1315 -20.000 439.670 0. 24205 4. 131 0. 16518 284. 38 407 83 461.38 2 47362 0.387 0.520 1331 -10.000 449.670 0.23639 4.230 0.16118 291.55 411 76 466.59 2 48533 0.388 0.521 1346 0.000 459.670 0.23099 4.329 0.15738 298.70 415 69 471.81 2 49681 0.390 0.523 1361 10.000 469.670 0.22584 4.428 0.15376 3 5.82 419 6

C 477.04 2 .50807 0. 392 0.524 1376

20. 000 479.670 0.22093 4.526 0. 15031 312. 91 423 6? 482.29 2 51913 0. 394 0.526 1390

30. 000 489.670 0.21623 4.625 0.14703 319.99 427, 61 487.56 2 52999 0.397 0.528 1404 40.000 499.670 0.21174 4.723 0.14389 327. 04 431 63 492.85 2 54068 0.399 1.530 1418

50. 000 509.670 0.20743 4.821 0. 14088 334.08 435 66 498.15 2 55120 .402 0.532 1432

60. 000 519.670 0.20330 4. 919 0. 13801 341.10 439 73 503.49 2 56156 0.404 0.534 1445 70.000 529.670 0.19933 5.017 0.13525 348. 11 443 81 508.84 2 57177 0.407 0.5 37 1458 80.000 539.670 0. 19552 5.114 0.13260 355. 10 447 93 514.22 2 58183 0.410 0.540 1471 100.000 559.670 0.18834 5.310 0.12762 369.04 456 25 525.08 2 60158 0.417 0.546 1496

120. 000 579.670 0. 18167 5.504 0.12301 382.93 464 70 536.05 2 62084 0.423 0.552 1521 140.000 599.670 0.17547 5.699 0.11873 396.78 473 2° 547.16 2 63968 0.431 1.559 1544

160. 000 619.670 0.16969 5.893 . 1 1 47 4 410.59 482. 0? 558.41 2. 65813 0.436 0.566 1567 180.000 639.670 0.16423 6.087 0.11102 424.37 490. 91 569. 81 2 67624 0. 447 0.574 1590

200. 000 659.670 0.15921 6.281 0.10754 438.11 499. 96 581.38 2 69 404 0.455 0.582 1612

22 0.0 00 679.670 0.15445 6.475 0.10427 451.83 509 18 593.11 2 71156 0.464 0.591 1633 240.000 699.670 0.14997 6.668 0.10120 465.53 518 58 605.01 2 728ei 0.473 0.599 1654 280.000 739.670 0. 14176 7.054 0.09558 49?. 85 537. 91 629.34 2. 76263 0. 491 0.617 1694 320.000 779.670 0. 13441 7.44 0.09056 520. 10 557 97 654.41 2 79563 0.510 3.o36 1734

360. 000 819.670 0.12779 7.825 0.08605 547.29 578. 80 680.23 2 82792 0.529 0.655 1772 400.000 859.670 0.12180 8.210 0.08197 574. 42 600. 39 706.81 2. 85957 0.548 0.674 18C6

440. 000 899.670 0.11635 8.595 0. 07826 601. 51 622. 73 734.14 2. 89064 0.567 0.693 1845

220
METHANE ISOBAR AT P 80.0 PSI

T T OEM VOL OP/DT DP/OD F H S C\l CP W OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 9TU/LP 9TU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

•296.197 163.473 28.201 0.03546 166.851 3633. 07 93..15 93.67 1.01157 0. 494 0. 785 5175

290. 000 169.670 27.914 0.03582 159.706 3443.02 97,,79 98.32 1.04090 0.492 0.790 5064 280.000 179.670 27.446 0.03644 148.708 3141. 07 105,,50 106.04 1.08652 0.493 0.904 4872 270.000 189.670 26.966 0.03708 138.314 2847.32 113,,46 114.01 1.13046 0.494 0.819 4675 260.000 199.670 26.473 0.03777 128.462 2564. 37 121. 62 122.18 1. 17287 0. 493 0.832 4480

25 0.0 00 209.670 25.964 0.03852 119.088 2293.74 129,.94 130.51 1.21384 0.488 0.844 4287

24 0.0 00 219.670 25.434 0.03932 110.129 2036.12 136,,40 138.99 1.25345 0.482 0.856 4095 230.000 229.670 24.880 0.04019 101.524 1791.51 147,,01 147.61 1.29188 0.476 0.871 3898 220.000 239.670 24.299 0. 04115 93.212 1559. 30 155. 79 156.40 1.32937 0.471 0.890 3695

•212.860 246.810 23.863 0.04191 87.423 1400.51 162,, 19 162.81 1.35573 0.468 0.906 3543

212. 860 246.610 0.54793 1.825 0.40464 126. 84 330,.94 357.97 2.14645 0.3 96 0.592 938 210.000 249.670 0.53901 1.855 0.39633 129.80 332,,17 359.66 2. 15324 0. 394 0.587 946

200. 000 259.670 0.51056 1.959 0.37074 139.73 336,,43 365.44 2.17596 0.390 0.571 974

190. 000 269.670 0.48565 2.059 0.34927 149. 16 340,.59 371.09 2. 197 32 0.387 0.560 1000 180.000 279.670 0.46353 2.157 0.33081 158.23 344,,69 376.65 2.21755 0.385 0.551 1025

17 0.000 289.670 0.44369 2.254 0.31467 166.99 348. 74 382.12 2. 23679 0. 383 0.545 1049 160. 000 299.670 0.42573 2.349 0.30037 175.52 352,,75 387.54 2.25518 0. 382 0.539 1072 150.000 309.670 0.40938 2.443 0.28756 183. 86 356..72 392.91 2.27280 0.381 0.535 1094 140.000 319.670 0.39439 2.536 0.27599 192. 03 360.,68 396.24 2.28974 .380 0.531 1115 130.000 329.670 0.38058 2.628 0.26546 200. 06 3 64. 61 4C3.54 2. 306C6 0. 380 0.528 1135 120.000 339.670 0.36780 2.719 0.25582 207.97 368.,53 408.81 2.32181 0. 380 0.526 1155 110.000 349.670 0.35594 2.809 0.24695 215.78 372,,44 414.06 2.33704 0. 380 0.524 1175 100.000 359.670 0.34488 2.900 0.23875 223.50 376.,34 419.29 2.35160 0.380 0.523 11Q4 -90.000 369.670 0.33455 2.989 0. 23114 231. 14 380. 23 424.51 2.36612 0. 380 0.522 1212

-80. 000 379.670 0.32486 3.078 0.22404 238.71 384,, 12 429.73 2. 38003 0.381 0.521 1230

-70. 000 389.670 0.31576 3.167 0.21742 246.21 388.,01 434.93 2.39357 0.381 0.520 1248 -60.000 399.670 0.30718 3.255 0.21121 253.67 391.,91 440.13 2.40675 0.362 0.520 1265 -50.000 409.670 0.29909 3. 343 0.20537 261. 07 395. 80 445.33 2.41960 0.383 0.520 12ei -40.000 419.670 0.29144 3.431 0.19987 26 8.4 2 399. 73 450.54 2.43215 0.384 0.521 1298 -30.000 429.670 0.28413 3.519 0.19469 275.74 403. 62 455.75 ?, 44442 0.386 0.521 1314 -20.000 439.670 0.27730 3.606 0.18978 283.01 407.,54 460.96 2.45641 0.367 0.522 1329

-10. 000 449.670 0.27076 3.693 0.18513 290. 25 411. 47 466.18 2.46816 0. 389 0.523 1345 0.000 459.670 0.26454 3.780 0.18071 297.47 415. 42 471.42 2.47967 0. 391 0.524 1360 10.000 469.670 0.25861 3. 867 0.17652 304.65 419. 36 476.67 2.49097 0.393 0.526 1375 20.000 479.670 0.25294 3.953 0. 17252 311. BO 423.,36 •81.93 2.50206 0.395 0.527 1389

30. 000 489.670 0.24753 4. 040 0. 16871 318.94 427,,36 487.21 2.51295 0.397 0.529 1403

40. 000 499.670 0.24236 4.126 0.16507 326. 04 431.,39 492.51 2.52366 0. 399 0.531 1417 50.000 509.670 0.23740 4.212 0.16160 3 3 3.13 435. 43 497.83 2.53421 0.402 0.533 1431 60.000 519.670 0.23265 4.298 0.15827 340.20 439.,5P 503.17 2.54459 0.405 0.535 1444

70. 000 529.670 0.22810 4.384 0.15508 347.25 443.,59 508.54 2.55482 0.407 0.538 1458

80. 000 539.670 0.22372 4.470 0.15203 354. 26 447. 72 513.93 2.56490 0.410 0.541 1471 100.000 559.670 0.21546 4.641 0. 14627 368. 31 456. Of 524.80 2.58468 0.417 0.546 1496 120.000 579.670 0.20781 4.812 0.14095 382.27 *64. 51 535.79 2.60397 0.424 0.553 1520

140. 000 599. 670 0.20069 4.983 0.13602 396.19 473.,10 546.92 2.62284 0.431 0.560 1544 160.000 619.670 0. 19406 5.153 0. 13143 410. 06 461.,85 558.18 2.64132 0.439 0.567 1567

180. 000 639.670 0.18786 5.323 0. 12714 423. 89 490. 74 569.60 2.65945 0.447 0.57 5 1590 200.000 659.670 0.18205 5.493 0.12314 437.69 499. 80 581.18 2.67727 0. 455 0. 583 1611 220.000 679.670 0.17659 5.663 0.11938 451.46 509.,03 592.92 2.69480 0.464 0.591 1633 240.000 699.670 0.17146 5.832 0.11585 465. 19 518. 43 604.83 2.71207 0.473 0.600 1654

280. 000 739.670 0.16205 6.171 0.10939 492.60 537. 77 629.18 2.74592 0.491 0.618 1694 320.000 779.670 0.15364 6.509 0. 10363 519.91 557. 85 654.27 2.77894 0.510 0.636 1734

36 0.0 00 819.670 0.14606 6.846 0.09845 547.16 578,,68 680.10 2.81125 0.529 0.655 1772

400. 000 859.670 0.13921 7.184 0.09377 574. 35 600. 28 706.69 2.84 291 0.548 0.574 1809 440.000 899.670 0.13297 7.520 0.08952 601.48 622,,63 734.04 2.87400 0.567 0.693 1845

221
METHANE ISOBAR AT P 90.0 PSI

T T DEN VOL CP/DT OP/00 E H S CV CP H DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB 3TU/LB BTU/LB/R BTU/LB/R 8TU/L3/R FT/S

296.165 163.505 28.202 0.03546 166.832 3634.40 93. 15 93. 74 1. 01162 0.494 785 5175 290.000 169.670 27.917 0.03582 159.729 3445.41 97. 77 98. 37 1. 04079 0.492 0. 790 5065

280. 003 179.670 27. 449 0.03643 148.737 3143.67 105. 48 106. 09 1.08641 0.493 0. 804 4873

270. 000 189.670 26.970 0.03708 138.348 2850.11 113, 43 114, 05 1. 13034 0.494 618 4676 260.000 199.670 26. 477 0.03777 128.502 2567. 32 121, 59 122. 22 1.17274 0.493 932 4481 250.000 209.670 25.968 0.03851 119.134 2296. 84 129. 91 130. 55 1.21369 0.498 o. 844 4289

21*0. 000 219.670 25.439 0.03931 110.181 2039.37 138. 37 139. 03 1.25329 0.482 o 956 4097 230.000 229.670 24.886 0.04018 101.583 1794.90 146. 97 147 64 1.29171 0.476 370 3901 220.000 239.670 24.305 0.04114 93.279 1562. 85 155. 75 156. 43 1.32919 0.471 889 3698 210.000 249.670 23.690 0.04221 85.209 1342.17 164. 74 165. 44 1. 36600 0.468 913 3484 208.861 250.809 23.617 0. 04234 84.302 1317. 70 165. 77 166. 48 1.37017 0.468 917 3459 208.661 250.809 0.61353 1.630 0.45717 125.56 331 72 358. 88 2. 13729 0.398 603 939

200. 000 259.670 0.58339 1.714 0.42897 134. 88 335. 58 364. 15 2. 15792 0.393 1 586 965

190. 000 269.670 0. 55363 1. 806 0- 40245 144.81 339 83 369 93 2.17977 0.389 a 571 992

180. 000 279.670 0.52753 1.896 0.37998 154.28 344 00 375 59 2.20038 0. 387 561 1018 170.000 289.670 0.50422 1.983 0.36053 163.38 348. If 381 15 2.21993 0. 385 552 1043 160.000 299.670 0.48325 2.069 0.34345 172.20 352 If 386 64 2.23856 0. 363 a 546 1066

150. 000 309.670 0.46422 2. 154 0.32825 180. 79 356 18 392. 08 2.25639 0. 382 a 541 1089

l<t0.000 319.670 0.44685 2.238 0. 31459 189. 18 360 If 397 4f 2.27351 0.381 536 1 1 1 C 130. 000 329.670 0.43090 2.321 0.30223 197.40 364 13 t02 81 2.28997 0. 381 a 533 1131

120. 000 339.670 0.41617 2.403 0.29095 205.49 368. 08 408 12 2. 30586 0. 380 a 530 1152

110. 000 3t9.670 0.40253 2.484 0.28061 213.46 372 01 413 41 2.32120 0.380 a 528 1171

100. 000 359.670 0.38984 2.565 0.27108 221. 32 375 93 418 68 2. 33606 0.381 a 526 1191

-90. 000 369.670 0.37800 2.645 0.26225 229.09 379 84 423 93 2.35046 0.381 a ,525 1209 -80.000 379.670 0.36692 2.725 0.25405 236.78 383. 75 429. 17 2. 36445 0. 381 a 524 1227 -70.000 389.670 0.35652 2.805 0.24640 244.40 387. 66 434 to 2.37805 0.382 a 523 1245 -60.0 00 399.670 0.34674 2.884 0.23925 251.95 391. 57 439 63 2.39130 0.383 522 1263

-50. 000 409.670 0.33751 2.963 0.23253 259.45 395. 4e 444 »5 2.40421 0.38h 522 1279 -'0.000 419.670 0.32880 3.041 0.22622 266.89 399. 39 450. 08 2.41681 0. 385 523 1296 -30.000 429.670 0.32055 3. 120 0.22026 274.29 403 31 -,55 31 2.42912 0. 3 86 523 1312

-20. 000 439.670 0.31272 3.198 0.21464 281.64 4 C / , 25 •£0 54 2.44116 0.367 524 1328 -10.000 ''9.670 0.30529 3.276 0.20932 2 8 8.9": 411. 19 t65. 78 2.45294 0.369 525 134 3 0.000 459.670 0.29823 3. 353 0.20427 296- 24 415. 15 471. 03 2.46449 0.391 a 526 1359

10. 000 469.670 0.29149 3.431 0. 19947 303.48 419 12 476 29 2.47582 0. 393 527 1373 20.000 '79.670 0.28507 3.508 0. 19491 310.70 423, 11 481. 57 7.48694 0. 395 i 328 1368

30. 000 (89.670 0.27894 3.585 0.19056 317.89 427. 12 466. 86 2.49786 0.397 53C 1402

tO. 000 499.670 0. 27308 3.662 0. 18642 325.05 431. 15 492. 17 2.50860 0.399 532 1416 50.000 509.670 0.26746 3.739 0.19246 332. 19 435 20 497 51 2.51916 0.402 a 534 1430 60.000 519.670 0.26209 3.816 0.17867 339. 30 439. 27 502. 86 2.52956 0.405 a 537 1444

70. 000 529.670 0.25693 3.892 0.17504 346.40 443 37 508. 24 2.53981 0.4C8 a 539 1457

80. 000 539.670 0.25198 3.969 0.17157 353.48 447 50 513 64 2.54992 0.411 a 542 1470

100. 000 559.670 0. 24264 4. 121 0.16503 367.58 455 84 524 53 2.56973 0.417 547 1495 120.000 579.670 0.23399 4.274 0.15899 381.62 464 31 535 54 2.58906 0.424 a 554 1520 ltO.000 599.670 0.22595 4.426 0.15339 395.60 472 92 546. 68 2.60795 0.431 a 560 1544 160.000 619.670 0.21846 4.577 0.14819 409.53 481 67 557. 96 2.62645 0.439 568 1567

180. 000 639.670 0. 21146 4.729 0.14333 423.42 490 58 569 39 2.64460 0.447 a 575 1589

200. 000 659.670 0.20491 4.880 0.13879 437.27 499. 64 580. 98 2.66244 0.455 a 583 1611

220. 000 679.670 0.19875 5.031 0. 13454 451.09 508 88 592, 73 2.67999 0. 464 59? 1633

2tO. 000 699.670 0.19296 5.182 0.13054 464. 87 518. 2° 604. 65 2.69728 0.473 a 500 1654

280. 000 739.670 0. 18236 5.484 0. 12324 492.35 537. 64 629 03 2.73115 .491 a bl8 1694 320.000 779.670 0. 17288 5.785 0. 11673 519.73 557, 73 654. 13 2.76420 0.510 637 1734

360. 000 819.670 0.16434 6.085 0. 11087 547.04 578 57 679, 98 2.79652 0.529 656 1772

too. 000 859.670 0.15662 6.385 0.10559 574.28 600. 17 706. 58 2. 92821 0. 548 a. 574 1809 tto.ooo 899.670 0.14960 6.685 0.10079 601.46 622. 54 733. 94 2.85931 0.568 a 693 1845

222
METHANE ISOBAR AT P = 100.0 PSI

T T OEN VOL DP/DT OP/DD E H S CV CP W DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/L8 BTU/LB/R BTU/LB/R BTU/LT/R FT/S

296.133 163. 537 28.204 0.03546 166.814 3635.73 93,,16 93.81 1.01166 0.494 0,,785 5175 290.000 169.670 27.920 0.03582 159.751 3447.80 97,,75 98.42 1.04068 0.492 0,.790 5066

280.000 179.670 27.452 0.03643 148.765 3146.28 105,,46 106.13 1.08629 0.493 0,.804 4674 270.000 189.670 26.97 3 0.03707 138.382 2852. 89 113,.41 114.10 1.13021 0.494 0,,818 4678

260. 000 199.670 26.461 0.03776 128.542 2570.27 121,,56 122.26 1.17261 0.493 0,. 332 4483 250.000 209.670 25.972 0.03850 119.180 2299.94 129,,88 130.59 1.21355 0.488 0,,344 4291

21*0.000 219.670 25.444 0.03930 110.233 2042.61 138,,34 139.06 1.25314 0.482 0,,356 4099 230.000 229.670 24.892 0.04017 101.642 1798. 29 146. 94 147.68 1.29154 0.476 0,.870 3903 220.000 239.670 24.312 0.04113 93.346 1566.40 155,,70 156.46 1.32900 0.471 0,.389 3701 210.000 249.670 23.697 0.04220 85.285 1345.90 164,,68 165.46 1.36579 0.468 0,,913 3488 205.175 254.495 23.387 0.04276 81.460 1243.16 169,,11 169.90 1.38340 0.467 0.,927 3381

205. 175 254.495 0.67934 1.472 0.51064 124. 14 332,,40 359.65 2.12899 0.400 0,,514 940 200.000 259.670 0.65894 1.518 0.49095 129.86 334,,70 362.80 2.14123 0.397 0,,602 956 190.000 269.670 0.62382 1.603 0.45846 140.33 339,, 04 368.73 2. 16363 0. 392 0,,584 964 lao.ooo 279.670 0.59321 1.686 0.43137 150.23 343.,26 374.50 2.18465 0. 389 0..571 1011

170. 000 289.670 0.56613 1.766 0.40819 159.70 347,,45 380.16 2.20453 0. 3 86 0,,561 1036 160.000 299.670 0.54190 1.845 0.38801 168. 82 351,,56 385.73 2.22343 0.385 0,,553 1061

150. 000 309.670 0.52002 1.923 0.37018 177.67 355.,62 391.23 2.24148 0. 383 0,,547 1084 140.000 319.670 0.50012 2.000 0.35425 186.29 359,,64 396.67 2.25878 0. 382 0,.542 1106 130.000 329.670 0.48190 2.075 0.33990 194.72 363.,64 402.06 2.27540 0. 382 0,,538 1127

120. 000 339.670 0.46514 2.15 0.32687 202.99 367. 61 407.42 2.29142 0. 381 0,,534 1148 110.000 349.670 0.44964 2.224 0.31496 211. 12 371.,57 412.75 2.30688 0. 381 0,,532 1168 100.000 359.670 0.43525 2.298 0.30402 219. 13 375. 51 418. 06 2. 32184 0. 381 0.,529 1188 -90.000 369.670 0.42185 2.371 0.29391 227.03 379.,45 423.34 2.33633 0.381 0,,528 1206 -80.000 379.670 0.40933 2.443 0.26454 234.84 383.,37 428.61 2.35040 0.382 0,,526 1225 -70.000 389.670 0.39759 2.515 0.27581 242.57 367.,30 433.87 2.36407 0.382 0,.525 1243 -60.000 399.670 0.38656 2.587 0.26767 250.23 391. 2? 439.12 2. 37738 0. 383 0.,525 1260

-5 0.00 409.670 0.37618 2.658 0.260 04 257.82 395,,15 444.37 2.39035 0.384 0,,525 1277 -40.000 419.670 0.36637 2.729 0.25288 265.36 399.,07 449.62 2.40300 0. 385 0,,525 1294 -30.000 429.670 0.35710 2.800 0.24613 272.84 403,,01 454.86 2.41536 0. 3 86 0,,525 1310 -20.000 439.670 0.34832 2.871 0.23976 280. 27 406. 95 460.11 2.42744 0. 388 0,,525 1326 -10.000 449.670 0.33998 2.941 0.23375 287.66 410,,91 465.37 2.43926 0. 389 0,,526 1342 0.000 459.670 0.33205 3.012 0.22804 295.00 414. 87 470.64 2.45085 0.391 0,,527 1357 10.000 469.670 0.32451 3.082 0.22263 302.31 418,,85 475.92 2.46221 0.393 0,,528 1372

20. 000 479.670 0.31732 3.151 0.21749 309.59 422. 85 481.21 2.47335 0. 395 0,,530 1387 30.000 489.670 0.31045 3.221 0.21259 316.64 426,,87 486.52 2.48430 0. 397 0,, oZZ 1401 40.000 499.670 0.30389 3.291 0.20793 324.05 430. 90 491.84 2.4950 7 0.400 0,,533 1415 50.000 509.670 0.29761 3.36 0.20347 331.24 434,, 9€ 497.16 2.50566 0.402 0,,535 1429

60. 000 519.670 0.29160 3.429 0. 19921 338.41 439,,05 502.55 2.51608 0.405 0,,538 1443 70.000 529.670 0.28583 3.499 0.19514 345.55 443, 15 507.94 2.52635 0.408 0,,540 1456 80.000 539.670 0.28030 3.56 6 0.19123 352.67 4 47,,29 513.35 2.53648 0.411 0,,543 1469 100.000 559.670 0.26987 3.705 0.18389 366.85 455,,64 524.26 2.55632 0.417 0.,548 1495 120.000 579.670 0.26022 3. 843 0.17712 380.96 464,, 12 535.28 2.57568 0.424 0,,554 1519

140. 000 599.670 0.25125 3.980 0.17085 395.01 472. 74 546.44 2.59460 0.431 0.,561 1543 160.000 619.670 0.24289 4.117 0.16502 409.01 481,.50 557.73 2.61312 0.439 0.. 568 1567 180.000 639.670 0.23509 4.254 0.15958 422.95 490. 41 569.18 2.63130 0.447 0.,576 1589

200. 000 659.670 0.22779 4.39 0.15451 436.86 499. 49 580.78 2.64916 0.455 0,,584 1611 220.000 679.670 0.22093 4.526 0.14975 450.72 508.,73 592.54 2.66672 0.464 0,,592 1633 240.000 699.670 0.21443 4.662 0.14529 464.55 518. 14 604.46 2.68403 0.473 0.,601 1654 280.000 739.670 0.20267 4. 934 0.13713 492. 11 537. 50 628.87 2.71792 0.491 0. 619 1694

320.00 779.670 0.19212 5.205 0.12985 519.56 557.,60 553.99 2.75099 0.510 0,,637 1734 360.0 00 819.670 0.18262 5.476 0.12333 546.92 578. 4f 679.85 2.78334 0.529 0,,656 1772 400.000 859.670 0.17403 5.746 0.11743 574.21 600..07 706.47 2.81504 0.549 0,,675 1809

44 0.0 00 899.670 0.16622 6.016 0.11209 601.44 622. 44 733.84 2.84615 0.568 o. 694 1845

223
METHANE ISOBAR AT P = 120.0 PSI

T T OEN VOL CP/DT DP/OO E H S cv CP W DEG F OEG R LB/CUFT CUFT/16 PSI/R PSICUFT/LB 8TU/LP BTU/LB BTU/LB/R BTU/UB/R eTU/L9/R FT/S

296. 069 163.601 28.206 0.03545 166.778 3638. 39 93. 17 93.96 1. 01174 0. 494 0. 785 5176

290. 000 169.670 27.926 0.03581 159.796 3452.57 97. 7? 96.51 1. 04046 , 492 0, 790 5068

280. 000 179.670 27.459 0.03642 148.822 3151.47 105. 42 106.23 1.08606 0. 493 0. 803 4877

270. 000 189.670 26.980 0.03706 138.450 2858. 46 113. 36 114.19 1.12996 0, 494 0. 818 4681

260, 000 199.670 26.489 0.0 3775 128.621 2576.16 121. 51 122.35 1. 17234 493 0. 831 4486

250. 000 209.670 25.981 0.03849 119.271 2306. 12 129. 82 130.68 1.21327 489 0. 943 4295

240, 000 219.670 25.453 0.03929 110.337 2049. 08 138, 27 139.14 1.25283 482 0. 355 4103

230. 000 229.670 24.903 0. 04016 101.760 1805. 05 146. 86 147.75 1.29121 476 0, 869 3908

220. 000 239.670 24.324 0-04111 93.479 1573.47 155. 61 156.53 1. 32863 0. 471 0, 888 3706

210. 000 249.670 23.712 0.04217 85.437 1353.33 164 58 165.52 1. 36538 466 0. 912 3494

200. 000 259.670 23.058 0.04337 77.566 1143.23 173. 82 174.78 1.40176 467 0. 943 3271

198, 538 261. 132 22.959 0.04356 76.425 1113.26 175. 2C 176.16 1.40707 467 0. 948 3237

198. 538 261. 132 0. 81195 1. 232 0.62068 120.98 333 48 360.85 2.11431 404 637 941

190. 000 269.670 0.77128 1.297 0.58032 130.95 337, 36 366.19 2.13442 398 614 967

180. 000 279.670 0.73017 1.370 0.54165 141.84 341 79 372.22 2. 15641 394 594 996

170. 000 289.670 0.69442 1.440 0.50944 152.09 346, C 378.09 2.17 70 3 390 0. 580 1023

160. 000 299.670 0.66286 1.509 0.48194 161.68 350 31 383.84 2.19652 388 569 1049

150. 000 309.670 0.63465 1.576 0.45803 171. 29 354. 47 389.48 2.21505 386 560 1073

140. 000 319.670 0.60921 1.641 0.43693 180. 39 35" 57 395.05 2.23274 385 553 1097

130. 000 329.670 0.58608 1.706 0.41812 189. 25 362. 64 400.55 2.24970 384 548 1119

120. 000 339.670 0.56492 1.770 0.40118 197.90 366 67 406.01 2.26600 383 0, 543 1140

110. 000 349.670 0.54545 1.833 0. 38561 206. 36 370 68 411.42 2.28171 3 83 540 1161

100. 000 359.670 0.52746 1.896 0.37177 214.68 374, 67 416.80 2.29668 382 0. 537 1181

-90. 000 369.670 0.51076 1.95 8 0. 35888 222. 86 378 65 422.15 2. 31156 383 534 12C1

-8 0. 000 379.670 0.49521 2.019 0.34699 2 3 0.93 382 61 427.49 2.32579 383 532 1220

-70, 000 389.670 0.48067 2. 080 0. 33596 238.89 366 57 432.80 2.33961 383 5 3 1 1238

-60. 000 399.670 0.46705 2. 141 0.32571 246.76 390 53 438.10 2.35305 ,384 530 1256

-50. 000 409.670 0.45425 2. 201 0. 31613 254. 55 394 48 443.40 2. 36613 .385 529 1273

-40, 000 419.670 0.44219 2.261 0. 30716 262. 26 398 43 448.69 2.37889 . 366 529 1290

-30. 000 429.670 0.43080 2. 321 0.29874 269.91 402, 39 453.97 2. 39134 , 367 a 529 1307

-20. coo 439.670 0.42003 2.381 0.29082 277.51 406 .36 459.26 2.40351 ,368 !) 329 1323

-10. 000 449.670 0. 40962 2.440 0.26334 285. 04 410 34 464.56 2.41541 .390 530 1339

0. 000 459.670 0.40014 2.499 0.27627 292.53 414 32 469.86 2.42707 392 5 30 1355

10 000 469.670 0.39092 2.558 0.26958 299.97 418 .32 475.16 2.43649 394 5 31 1370

20. 000 479.670 0.36215 2.617 0.26322 307.37 422 .34 480.48 2.44970 3 96 333 1385

30. 000 489. 670 0. 37379 2.675 0. 25718 314.73 426 .37 485.82 2.46071 .398 534 1399

40. 000 499.670 0.36580 2.734 0.25143 322. 06 430 42 491. 17 2.47152 400 536 1414

50 000 509.670 0.35816 2.792 0.24595 329. 35 434 5C 496.54 2.48216 403 538 1426

60 000 519.670 0.35086 2. 850 0.24072 336.62 438 5° 501.92 2.49263 405 540 1441

70 000 529.670 0. 34385 2.908 0.23571 343.85 442 .71 507.33 2.50294 .408 542 1455

80. 000 539.670 0.33714 2.966 0.23093 351. 06 446 86 512.77 2.51310 411 545 1468

100. 000 559.670 0.32450 3. 082 0.22194 365. 41 455 24 523.71 2.53302 417 n ,550 1494

120 000 579.670 0.31281 3.197 0.21366 379. 67 463 74 534.78 2.55244 424 556 1519

140 000 599.670 0.30195 3.312 0. 20600 393.85 472 37 545.96 2.57141 ,431 563 1543

160 000 619.670 0. 29166 3.426 0. 19890 407. 97 481 15 557.29 2.58999 4'9 570 1566

180 000 639.670 0.28243 3.541 0. 19228 422. 03 490 06 568.76 2.60821 .447 577 1569

200 000 659.670 0.27361 3.655 0.18611 436. 04 499 17 580. 38 2.62610 4

c;6 3 585 1611

220 .000 679.670 0. 26534 3.769 0.18033 450. 00 508 .43 592.17 2.64370 464 593 1632

240 000 699.670 0.25757 3.883 0. 17491 463.91 517 85 604.13 2.66104 473 o02 1654

280 000 739.670 0.24334 4.110 0. 16501 491.63 537 .24 628.56 2.69499 .492 a 620 1695

320 ,000 779.670 0.23063 4. 336 0.15620 519. 22 557 36 653.71 2.72811 510 638 1734

36 . 000 819.670 0.21920 4.562 0. 14831 546. 71 578 .23 679.61 2.76049 .530 657 1772

40 000 859.670 0.20887 4.788 0.14118 574.10 599 ,86 706.25 2.79222 ,549 o75 1809

440 ,000 899.670 0.19948 5.013 0.13473 601.41 622 .25 733.64 2.82336 .568 694 1846

224
ME THANE ISOBAR AT P 11*0.0 PSI

T T OEN VOL OP/OT DP/OD E H S CV CP W DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/L'3/R FT/S

296.006 163.661* 28.209 0.0351*5 166.71*1 361*1. 01* 93.16 9i*. 10 1.01183 0.494 0.,785 5177 290.000 169.670 27.932 0.03580 159.81*0 31*57.33 97.68 98.61 1. 04024 0.492 0. 790' 5070

260. 000 179.670 27.1*65 0.0361*1 11*8.878 3156.66 105.38 106.32 1.08583 0.493 0..303 4879 270.000 189.670 26.987 0.03705 138.518 286<*. 02 113.32 111*. 28 1.12972 0.495 0,,818 4684 260.000 199.670 26.1*97 0.03771* 128.700 2582.01* 121.1*6 122.1*1* 1.17208 0.493 0,,331 4490 250.000 209.670 25.990 0.0381*8 119.362 2312. 30 129.76 130.76 1. 21298 0.489 0.,843 4298

240. 000 219.670 25.1*63 0.03927 110. 1*1*1 2055.51* 138. 2C 139.22 1.25252 0.482 0.,855 4107

230. 000 229.670 21*. 911* 0.01*011* 101.877 1811.80 11.6.78 11*7.82 1.29087 0.476 0,,369 3913 220.000 239.670 2i*. 337 0.01*109 93.612 1580.53 155.53 156.59 1.32826 0.471 0,,387 3712 210.000 21*9.670 23.727 0.01*215 85.587 1360.75 161*. 1*8 165.57 1. 36496 0.468 0.i 910 35C1 200.000 259.670 23.076 0.0i*33i* 77.738 1151. 07 173.70 171*. 82 1.40129 0.467 ,941 3276 192.659 267.011 22.565 0.01*1*32 72.01*3 1002.65 180.68 181.83 1.42790 0.466 0.,969 3107 192.659 267.011 0.91*630 1.057 0.73516 117.52 331*. 29 361.69 2.10149 0.408 0.,662 940

190. 000 269.670 0.93009 1. 075 0.71818 120.93 335.56 363.1*3 2. 10800 0.406 0,,652 949 180.000 279.670 0.87572 1.11*2 0.66361* 133. 00 31*0.19 369.80 2. 13117 0.399 0,,623 981 170.000 289.670 0.8291*5 1.206 0.61970 li*i*. 17 3i*i*. 66 375.92 2.15267 0. 394 0,,602 1010 160.000 299.670 0.78922 1.267 0.58301* 151*. 69 31*9.01 381.86 2. 17284 0.391 0.,587 1037 150.000 309.670 0.75370 1. 327 0.55172 161*. 72 353.27 387.67 2.19191 0.389 0,,575 106 3 140. 000 319.670 0.72197 1.385 0. 52i*i*7 171*. 35 357.1*6 393.37 2.21005 0. 387 0.,566 1087 130.000 329.670 0.69335 1.1*1*2 0.5001*3 183.66 361.61 399.00 2.22737 0. 386 0,,55° 1110 120.000 339.670 0.66733 1.1*99 0.1*7899 192.71 365.71 401*. 55 2. 24398 0. 385 o. 553 1133

110. 000 31*9.670 0.6<*352 1.551. 0.1*5969 201.53 369.77 1*10.06 2.25995 0. 384 ,548 1154 100.000 359.670 C62161 1.609 0. 1.1*217 210.16 373.81 1*15.52 2.27534 0.384 0.,544 1175 -90.000 369.670 0.60137 1.663 0.1*2618 218.63 377.83 i*20.9i* 2. 29022 0. 384 0,,541 1195 -80.000 379.670 0.58257 1.717 0.1*1150 226.96 381.81. 1*26.31* 2.30463 0. 384 0,,'538 1214 -70.000 389.670 0.56505 1.770 0.39791* 235.16 385.83 431.71 2.31860 0. 384 0.,536 1233

-60. 000 399.670 0.5V868 1. 823 0.38538 21*3.25 389.82 1*37.07 2.33217 0. 385 0,,535 1252 -50.000 i*09.670 0.53333 1.875 0.37369 251.21. 393.81 1*1*2.1*1 2.34533 0.386 0,,534 1269

-1+0. 1*19.670 0.51890 1.927 0.36 27 8 259. 15 397.79 1*1*7.75 2. 35824 0. 387 0,, 533 1287 -30.000 1*29.670 0.50530 1.979 0.35257 266.97 1*01.77 453. 08 2. 37079 0. 388 0.,533 1304

-20. 000 i*39. 670 0. 1*921*6 2.031 0.31*297 27i». 72 1*05.76 i*58.i*l 2. 38305 0. 389 0,,533 1320 -10.000 1*1*9.670 0.1*8032 2. 082 0. 3339<* 282. 41 409. 7F 463.73 2. 39504 0. 391 0,,533 1336 0.000 1*59.670 0.1*6880 2. 133 0.3251*2 290.01* 1*13.77 469.07 2.40677 0.392 0.,534 1352 10.000 1*69.670 0.1.5786 2.181* 0.31736 297.61 1*17.7° 474.41 2.41826 0. 394 0. 534 1368 20.000 1*79.670 0.1* 1*71*6 2.235 0.30973 305.11. 1*21.82 479.76 2.42953 0.396 0,,536 1383 30.000 1*89.670 0.1.3755 2.285 0.3021*8 312.62 1*25.87 485.12 2.44059 0. 398 0,,537 1397

1*0.000 1*99.670 0.1*2809 2. 336 0.29560 320.06 1*29.91. 490.50 2.45146 0.4C1 0,,338 1412 50.000 509.670 0.41906 2.386 0.28901* 327. 1,6 1*31*. 03 495.89 2.46 215 0.403 3. 540 1426 60.000 519.670 0.1*101*3 2.1*36 0.28279 331.. 82 1*38.11. 501.30 2.47266 0.4C6 0,, 342 1440

70. 000 529.670 0.1*0216 2.1*87 0.27682 31*2. 15 1*1*2. 27 506.73 2.48302 0.409 0,,544 1453

80. 000 539.670 0. 391*21* 2.537 0.27111 31*9.1.5 1*1.6. 1*3 512.19 2.49 322 0.411 0.,547 1467 100.000 559.670 0.37931* 2.636 0. 2601*2 363.96 <*5i*. 83 523.17 2.51321 0.418 0.,552 1493 120.000 579.670 0.36557 2.735 0.25058 378. 37 463.35 534.27 2.53269 0.425 0,,558 1518

11*0.000 599.670 0.35281 2.631* 0. 21*11*9 392.69 1*72.01 545.49 2.55172 0.432 a,,564 1542

160. 000 619.670 0.31*09* 2.933 0.23307 1*06. 91. 1*80. 81 556.84 2.57 34 0.439 0.,571 1565

180. 000 639.670 0.32987 3. 031 0.22521* 1.21. 11 1*89.75 568.34 2.58860 0.448 0,,379 1588 200.000 659.670 0.31952 3.130 0.21791* 435. 23 i*9e.86 579.99 2.60654 0.456 0. 586 1611 220.000 679.670 0.30982 3.228 0.21112 1*1*9.28 508.13 591.80 2.62417 0.465 0., 595 1632

2l»0.000 699.670 0.30071 3.326 0.201*72 1*63.29 517.57 603.78 2.64154 0.473 0. 603 1653

280. 000 739.670 0.261*01* 3.521 0.19305 1*91.17 536.98 628.25 2.67555 0.492 0.,o21 1695

320. 000 779.670 0.2691b 3.715 0.18263 518.89 557.12 653.44 2.70871 0.511 0.,639 1734 360.000 819.670 0.25579 3.909 0.17339 51*6.50 57B.01 679.36 2.74113 0. 530 0,,657 1773

1.00.000 859.670 0.21*371 4.103 0.16502 57 3.99 599.66 706.03 2.77290 0.549 0. 676 1810

1*1*0. 000 899.670 0.23273 i*.297 0. 1571*1* 601.1*0 622.06 733.45 2.80407 0.568 0.,695 1846

225
ME THANE ISOB AR AT P 160.0 PSI

T T DEN VOL DP/DT OP/DO E H S C\l CP N OEG F OEG R L8/CUFT CUFT/LB PSI/R PSICUFT/LB 8TU/LP 8TU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

295.942 163.728 28.212 0.0351*5 166.705 361*3. 69 93. 19 9i*. 21. 1. 01192 0.i*9i* 0.785 5177 290.000 169.670 27.937 0.03579 159.885 3i.62.08 97. 64 98.70 1. 01.002 0.1*92 0.790 5072

280. 000 179.670 27.1*71 0.0361*0 1<*8. 931* 3161.81. 105, 31. 106.1.1 1.08560 0.494 0.803 1*881 270.000 189.670 26.991* 0.03701* 138.585 2869.56 113. 27 111.. 37 1. 1291.7 0.1*95 0.817 i*686 260. 000 199.670 26.501* 0. 03773 128.779 2587.91 121. 1.1 122.52 1.17182 0.1*93 0.831 i*i*93 25 0.0 00 209.670 25.998 0.0381*6 119.1*52 2318.1.6 129. 70 130.81. 1.21270 0.1.89 0.81*2 1*302 21*0.000 219.670 25.1*73 0.03926 110. 5i*i* 2061.99 138. 1*. 139.30 1.25 2 22 0.1.83 0. 854 1*112 230.000 229.670 21*. 925 0.01*012 101.993 1618.53 11.6, 71 11.7.89 1.29051. 0.1.76 0. 868 3918

220. 000 239.670 24. 350 0. 04107 93.71*1. 1587.57 155. 44 156.65 1.32789 0.1*71 0.386 3718 210.000 2i«9.670 23.71*2 0.0i»212 85.737 1368. 13 161* 37 165.62 1. 361.55 0.468 0.909 3507 200.000 259.670 23.093 0.01*330 77.910 1158.88 173. 58 17i.. 86 1.1.0082 0.467 0. 939 3286

190. 000 269.670 22.392 0.01*1*66 70.185 958.22 183. 12 181.. 1.1. 1.1.3701 0.1*66 0.97 8 3053 187.357 272. 313 22. 196 0. 04505 68. 11.9 906.1.1 185, 70 187.01. 1. it 1*660 0.1*65 0. 990 2989 187.357 272. 313 1.0828 0.9235 0.851.5 113. 86 331*. 89 362.25 2.09002 0.1.12 0.638 938 180.000 279.670 1.0316 0.9691. 0.8001 123.66 338. 1.7 367.19 2.10793 0.1.05 0.657 964

170. oao 289.670 0.9723 1. 0285 0.71.06 135.90 31.3. li. 373.61 2.13048 0. 399 0.628 995 160.000 299.670 0.9217 1.0850 0.6921. 11.7.26 347 61* 379.78 2. 1514 1* 0. 395 0.508 1024 150.000 309.670 0.8777 1. 1391. 0.6520 157.96 352. 02 385.78 2.17112 0.392 0.592 1052 140.000 319.670 0. 8388 1. 1922 0.6171* 168.16 356, 32 391.61. 2. 18971* 0. 390 0.380 1077

130. 000 329.670 0. 801*0 1. 21*38 0-5872 177.96 360. 54 397.39 2.2071*7 0.388 0.571 1102 120.000 339.670 0.7726 1. 29i*i» 0.5606 167. 1*3 361*. 71 1*03.06 2.221*1*1 0. 387 0.563 1125

110. 000 31*9.670 0.7 44 1. 31*1*1 0.5368 196.62 368 8*. <*08.66 2.21*066 0.386 0.557 1147 100.000 359.670 0.7178 1. 3931 0.5151* 205.59 372 gt 1*14.21 2.25630 0.385 0.55? 1169

-90. 000 369.670 0.6937 1. !*i*li* 0.1*959 211*. 35 377. 00 419.71 2.27139 0.385 0.51.8 1189 -80.000 379.670 0.6715 1.1*893 0.1*782 222.95 381 05 i»25.18 2.28598 0. 385 0.51*5 1209 -70.000 389.670 0.6508 1.5366 0.1*618 231. i*n 385 09 1*30.61 2.30011 0. 385 3. 5i*2 1228 -6C.000 399.670 0.6315 1.5835 0.1.1*68 239.71 389 11 •36.02 2.31382 0.3 86 0.540 1247

-50. 000 i«09. 670 0.6135 1.6301 0.1*328 21*7.91 393 12 1*1.1. 1*2 2.32715 0. 386 0.539 1265 -40.000 "+19.670 0.5965 1.6763 0.1*198 256. 01 397 H* i*i*6. 80 2. 31*013 0.387 0.538 1283 -30.000 429.670 0.5806 1.7222 .1.076 26i*. 01 1.01. 15 <*52.17 2. 35279 0. 388 0.537 1300 -20.000 1*39.670 0.5656 1.7679 0.3963 271.92 1*05. ie 457.51* 2. 36513 0. 350 0.537 1317 -10.000 i* 49. 670 0.5515 1.3133 0.3856 279.77 i*09 18 1*62.91 2.37720 0.391 0.537 1334 0.000 1.59.670 0.5381 1. 3586 0.3755 287.51. 1*13 21 1*68.27 2.389G1 0. 393 0.337 1350 10.0G0 469.670 0.5253 1.9 36 0.3660 295.25 1.17 25 473.65 2.1.0057 0.395 0.538 1365 20.000 1*79.670 0.5132 1.9l*8i* 0.3570 302.90 1.21. 30 479.03 2.1.1191 0. 397 0.538 138

30. 000 i*89.670 0.5017 1.9931 0.31.85 310.50 i*25 37 1*81.. 1*2 2.1(2303 0. 399 0.540 1395

i*0. 000 i*99.670 0.1*908 2.0376 0.3404 318.05 i*29. 1.5 1*89.82 2.1.3395 0.1*01 0.51*1 1410 50.000 509.670 0.1*803 2. 0820 0.3328 325.55 1*33 55 i*95.2i* 2. 44 1*69 0.1*01* 0.543 142". 60.000 519.670 0.1.703 2.1262 0.3251. 333.02 i*37. 68 500.67 2.1.5525 0.1*06 0.51*1* 1438 70.000 529.670 0.1*608 2. 1703 0.3185 3i»0.i<i* 441, 83 506.13 2.1.6561. 0.1*09 0.547 1452 80.000 539.670 0.1*516 2.211*3 0.3118 31*7.83 1*1*6. OC 511.60 2.1*7589 0.1*12 0.549 1465 100.000 559.670 0. 1*31*1* 2. 3020 0.2993 362. 51 1*51*. i»3 522.63 2.1.9595 0.1*18 0.551* 1492 120.000 579.670 C.i*185 2. 3891* 0.2879 377. 08 1*62. 97 533.76 2.5151.9 0.1*25 0.560 1517

11*0.000 599.670 0.1*038 2. 1*761* 0.2773 391.51. i*71 61. 51.5.01 2.531.57 0.1*32 0.566 1541 160.000 619.670 0.3902 2.5631 0.2675 1.05.91 <*80. 1*6 556.i*0 2.55325 0.1*1*0 0.573 1565

180. 000 639.670 0.3771* 2.51*96 0.2585 1.20.20 1*89 I*? 567.92 2.57155 0.1.48 0.580 1588 200.000 659.670 0. 3655 2.7359 0.2500 k3l*. 1*2 1*98. 51* 579.60 2.58953 0.1*56 0.588 1610 220.000 679.670 0.35i*i* 2. 3219 0.21*21 1.1.8.57 507. 83 591.43 2.60720 0.465 0.596 1632

21*0. 000 699.670 0. 31*39 2.9078 0.231*7 1.62.67 517. 28 603.1*3 2.621.60 0.1*71* 0.304 1653

280. 000 739.670 0. 321*8 3.0791 0.2212 1.90.71 536, 72 627.91. 2.65866 0.1*92 0.622 1695

320- 000 779.670 0.3077 3. 21*98 0.2093 518.57 556, 88 653.17 2.69187 0.511 0.540 1734 360.000 819.670 0.2921* 3.1*201 0.1986 51.6.29 577, 79 679.12 2.721.33 0.530 0.658 1773

1*00. 000 859.670 0.2786 3.5900 0.1889 573.90 599. i*e 705.82 2.75613 0.51.9 0.677 1810

1*1*0.000 399.670 0.2660 3.7595 0.1802 601.39 621. 87 733.26 2.78732 0. 568 0.695 1847

226
METHANE ISOBAR AT P 180.0 PSI

T T OEN VOL CP/DT DP/DD E H S CV CP W OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB 3TU/LB BTU/LB/R BTU/LB/R BTU/L3/R FT/S

295.879 163.791 28.215 0.03544 166.669 3646. 33 93,,20 94.36 1.01200 0.494 0.,785 5178 290.000 169.670 27.943 0.03579 159.929 3466. 82 97,,61 98.80 1. 03980 0.1*93 0.,789 5074

•280.0 00 179.670 27.473 0.03639 148.990 3167.01 105,.29 1 06.51 1.08536 0.494 0,,803 4884 270.000 189.670 27.001 0.03704 138.652 2875. 10 113,,22 114.46 1.12 92 3 0.495 0,,817 4689 260.000 199.670 26.512 0.03772 128.858 2593.77 121,.35 122.61 1.17155 0.494 0., 830 4496 250.000 209.670 26.007 0.03845 119.543 2324.61 129,.64 130.93 1. 21242 0.489 0,,342 4306 240.000 219.670 25.483 0.03924 110.646 2068.42 138,,07 139.36 1.25191 0.463 0,,854 4116 230.000 229.670 24.936 0.04010 102.109 1825.24 146,,63 147.97 1. 29020 0.477 0,,367 3923 220.000 239.670 24.362 0.04105 93.875 1594.59 155,,35 156.72 1.32752 0.472 0,,885 3723

210. 000 249.670 23.756 0. 04209 85.886 1375. 50 164,,27 165.68 1.36414 0.469 0,,908 3514 200.000 259.670 23.110 0.04327 78.080 1166.66 173,,46 174.90 1.40035 0.1*67 0,,938 3293 190.000 269.670 22.413 0.04462 70.383 966.52 182,,97 184.46 1.43647 0.466 0,,975 3062 182.513 277. 157 21.847 0.04577 64.632 821.31 190,,36 191.89 1.46365 0.464 1., 011 2879 182.513 277.157 1.2218 0.3184 0.9790 110.05 335,,31 362.59 2.07953 0.416 0,,715 936 180.000 279.670 1.2001 0.8332 0.9548 113.71 336,,59 364.37 2.08592 0.413 0,,701 946 170.000 289.670 1. 1243 0.8894 0.8743 127.24 341,,51 371.16 2.10973 0.405 0,,660 980 160.000 299.670 1.0612 0.9424 0.8112 13^.56 346., 1° 377.60 2. 13167 0. 399 o. 632 1011 150.000 309.670 1.0071 0.9929 0.7596 151. 01 350,,72 383.81 2.15205 0.395 0,,oll 1040

14 0.000 319.670 0.9600 1.0417 0.7162 161.83 355,,12 389.84 2. 17122 0.392 0,,596 1067 130.000 329.670 0.9182 1.0 891 0.6789 172. 15 359,,44 395.74 2.16939 0.390 Q,,584 1093 120.000 339.670 0.8808 1. 1353 0-6463 182. 06 363. 69 401.53 2.20669 0. 389 0,,575 1117

110. 000 349.670 0.8470 1.1806 0.6174 191.65 367,,8° 407.24 2. 22325 0.387 0,,567 1140 100.000 359.670 0.8162 1.2252 0.5916 200.96 372,,04 412.86 2.23914 0. 387 0,,561 1162 -90.000 369.670 0.7880 1.2690 0.5683 210.03 376,,16 418.46 2.25445 0.3 86 0,, 556 1183 -80.000 379.670 0.7620 1. 3123 0. 5<»71 218.91 380. 25 423.99 2.26923 0.386 0,,552 1204 -70.000 389.670 0.7379 1. 3551 0.5277 227.60 384,, 33 429.49 2. 28353 0.386 0,, 548 1224 -60.000 399.670 0.7156 1.3975 0.5099 236. 15 388.,36 434.97 2.29739 0. 387 0,, 546 1243 -50.000 409.670 0.6947 1.4395 0.4935 244.56 392,,43 440.1*1 2.31086 0.387 0,, 544 1261

-i*0. 000 419.670 0.6 75 2 1. 4811 0.4782 252. 85 396,,47 445.84 2.32395 0.388 0,,542 1279 -30.000 429.670 0.6568 1.5225 0.461*0 261. 03 400,,51 451.26 2.33671 0.389 0,, 541 1297 -20.000 439.670 0.6396 1.5635 0.4507 269. 11 404,,55 456.67 2.34915 0. 390 0,,541 1314 -10.000 449.670 0.6233 1.6044 0.4382 277.11 408,,60 62.07 2.36131 0. 392 0., 540 1331

0. 000 459.670 0.6079 1.6450 0.4266 285.03 412,,65 467.48 2.37319 0.393 0,,540 1347

10. 000 469.670 0.5933 1.6854 0.4155 292.87 416,,71 472.88 2.38482 0.395 0,,541 1363 20.000 479.670 0.5795 1.7256 .4051 300.65 420,,78 478.29 2.39622 0.397 0,,541 1378 30.000 489.670 0.5664 1.7656 0.3953 308.37 424,,86 1*83.71 2.40741 0. 399 o. 542 1393

1*0.000 499. 670 0.5539 1.3055 0.3860 316.03 428,,96 489.14 2.41838 0.401 0,,544 1408

50. 000 509.670 0.5419 1.3452 0.3771 323.65 433,,06 494.58 2.42917 0.404 0,,545 142 3 60.000 519.670 0.5305 1.8849 0.3687 331. 21 437., 22 500.04 2.43973 0.407 0.,547 1437 70.000 529.670 0.5197 1.9243 0.3607 338.73 441. 36 505.52 2.45022 0.409 0. 549 1451

80. 000 539.670 0.5092 1.9637 0.3530 346.21 445,,57 511.02 2.46050 0.412 0.,551 1464 100.000 559.670 0.4897 2.3421 0.3387 361. 06 454.,02 522.09 2.48063 0.418 0,,556 1491 120.000 579.670 0.4717 2.1202 0.3256 375.78 462.,56 533.25 2.50024 0.425 J.,561 1516 140.000 599.670 0.4550 2. 1979 0.3135 390- 38 471. 28 544.54 2.51938 0. 432 o. 567 1541 160.000 619.670 0.4395 2.2754 0.3023 404.88 480. 11 555.95 2.53810 0.440 0, 574 1564

180. 000 639.670 0.4251 2. 3526 0.2920 419.28 489. 09 567.51 2.55645 .448 0.,581 1568

200. 000 659.670 0.4116 2.4296 0.2823 433.61 498,,23 579.21 2.57447 0.456 0,,589 1610 220.000 679.670 0. 3990 2.5063 0.2733 447. 86 507. 53 591.07 2.59218 0. 465 0..597 1632 240.000 699.670 0.3872 2.5829 0.2649 462.05 517, 00 603.09 2.60961 0.474 a.,605 1653

280. 000 739.670 0.3656 2.7356 0.2496 490.25 536.,46 627.64 2.64372 0.492 0.,o22 1695

32 0.0 00 779.670 0. 3463 2. 3877 0.2360 518.25 556.,64 652.90 2.67693 0.511 0.,640 1735 360.000 819.670 0. 3290 3.0394 0.2239 546. 10 577. 57 678.88 2.70948 0.530 0.,659 1773 400.000 859.670 0.3134 3. 1907 0.2130 573.80 599. 25 705.61 2.71*130 0.549 0. 677 1811 440.000 899.670 0.2992 3.3417 0.2031 601.39 621.,69 733.07 2.77 25 3 0.568 0. 696 1847

227
ME THANE ISOB AR AT P 200.0 PSI

T T OEN VOL DP/DT DP/DO F H S cv CP H DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LJ/R FT/S

295.815 163. 855 28.217 0. 0351*1* 166.633 361*8. 97 93. 21 9i*. 53 1. 01209 0. 495 785 5179

290.000 169.670 27.91*9 0.03578 159.973 31*71.55 97. 57 98.89 1. 03958 0, 1*93 789 5076 260.000 179.670 27."+8-+ 0.03638 11*9.01*6 3172.17 105. 25 106.60 1. 08513 1*91* 802 4886

270. 000 189.670 27.009 0.03703 136.719 2880.62 113 18 111*. 55 1. 12898 i*95 817 4692

260. 000 199.670 26.520 0. 03771 128.936 2599.62 121 30 122.70 1, 17129 i*9i* 830 4499 250.000 209.670 26.015 0.0361*1* 119.633 2330.76 129 59 131.01 1. 2121<* ,1*89 842 4310

21*0.000 219.670 25.1*92 0.03923 110.71*9 2071*. 8«* 138, 00 139.1*6 1, 25161 1*83 853 4120 230.000 229.670 21*. 91*7 0.01*009 102.225 1831.95 11*6 55 11*8. 01. 1. 28987 1*77 867 3928

220. 000 239.670 21*. 375 0.01*103 91*. 006 1601.59 155 26 156.78 1 32715 1.72 884 3729 210.000 21*9.670 23.771 0. 01*207 86.031* 1382. 81* 164. 17 165.73 1. 36373 1*69 907 3520 200.000 259.670 23.127 0.0<*32i* 78.21*9 1171*. 1*1 173 31* 171*. 91* 1, 39969 1.67 936 33C1 190.000 269.670 22.434 0.0*1*56 70.578 971*. 78 182 83 181*. 1.8 1. 1.3593 1*66 973 3071

160. 000 279.670 21.672 0. 01*611* 62.921* 782.21 19? 73 191*. i*i» 1 1*7220 .463 1 021 2827

178. D«tl 281.629 21.512 0. 01*61*8 61.1*15 71.5. 15 191. 73 196.1*5 1 1.7937 1*62 1 033 2777

178.0<.l 281.629 1.3637 0.7333 1.1091 106. 11. 335. 5P 362.73 2. 06979 1.20 ,745 934 170.000 289.670 1.2873 0. 7768 1. 0236 118. li. 339. 76 368.52 2. 09007 i*ll 698 964 160.000 299.670 1.2087 0. 8273 0.91*12 131.57 31.1. 66 375.30 2. 11307 1.01. 660 998

150. 000 309.670 1.11*28 0.3750 0.8757 11.3. 67 31.9 35 381.76 2, 131.26 399 633 1026

140. 000 319.670 1. 0861 0.9207 0.8217 155.36 353 ee 387.98 2. 151.05 .395 613 1057 130.000 329. 670 1. 0361* 0. 961*8 0.7759 166. 23 358 3C 391.. 01* 2 17270 , 3 93 598 1083 120.000 339.670 0.9923 1.0077 0.7363 176.62 362 61. 399.96 2. 19040 391 587 1109

110. 000 31*9.670 0.9528 1.01*96 0.7017 186.61 366 91 05.78 2. 20729 389 577 1133 100.000 359.670 0.9169 1. 1906 0.6709 196.26 371 12 1*11.51 2 2231.6 ,388 ,570 1155 -90.000 369.670 0.881*2 1. 1309 0.61*33 205.67 375. 30 1*17.18 2 23900 ,388 ,564 1177 -80.000 379.670 0.851*2 1. 1706 0.6181* 211*. 83 379 1*1* 22.79 2 25398 387 559 1198

-7 0.00 389.670 0. 8266 1.2098 0.5957 223.79 383 55 1*28.36 2. 26 81.5 387 555 1219

-60. 000 399.670 0.8009 1.21+86 0.571*9 232.57 387 65 1*33.89 2. 2821.7 ,388 =552 1238

-50. 000 i*09. 670 0.7770 1. 2869 0.5558 2i*l. 19 391 73 1*39.39 2 29607 ,388 549 1257

-i*0. 000 1*19.670 0.751*8 1. 321*9 0.5381 21*9.68 395 81 44.87 2 30929 ,389 547 1276 -30.000 i*29.670 0.7339 1. 3626 0.5216 258. 01* 399. 87 i*50.3i« 2, 32215 390 5"*6 1294 -20.000 1*39.670 0.711*3 1.1*000 0.5063 266.29 1.03 9J, 1*55.79 2. 331.69 391 545 1311

-10. 000 i*i*9. 670 0.6958 1.1*372 0.1*920 271*. 1*5 1*08 01 1*61.23 2 31*691* , 392 544 1328

0. 000 i*59.670 0.6781* 1. *+741 0.1*786 282.51 1.12 08 66.67 2, 35890 391. 544 1344

10. 000 t69.670 0.6619 1.5108 0.1*660 290. 1.9 1.16 16 1*72.11 2 37061 396 544 1360 20.000 i*79.670 0.61*63 1.51*73 0. 1*51*1 298.1.0 1*20 25 1*77.55 2 382C7 398 545 1376

30. 000 i*89. 670 0.6315 1.5836 0.1*1*28 306.21. t*2i* 35 1*83.00 2. 39331 1*00 545 1391

<40.000 i*99.670 0.6173 1.6198 0.1*322 311.. 02 1*28, t.7 i*88.i*6 2 i«0i*35 402 546 1406

50. 000 509.670 0.6039 1.6559 0.1*221 321.71. 1*32 60 1*93.93 2, 1*1519 404 548 1421 60.000 519.670 0.5911 1.6918 0.1*125 329.1.0 1*36 76 1*99.1*1 2. 42584 407 549 1435 70.000 529.670 0.5789 1.7276 0. 1*031* 337.02 i*i*0 93 501*. 91 2. 1.3633 410 551 1449

80. 000 539.670 0.5671 1.7632 0.391*7 31*1.. 59 445 13 510.U3 2. 1.1.665 413 553 1463

100. 000 559.670 0.51*52 1. 931.2 0.3785 359.61 1*53 61 521.51* 2, 46686 419 558 1490 120.000 579.670 0.5250 1. 901*9 0.3636 371*. 1,8 1*62. 20 532.71* 2. 1.8653 425 a 563 1515

11*0.000 599.670 0.5063 1. 9752 0.3500 389.22 1*70 91 51*1*. 06 2. 50573 433 569 1540

160. 000 619.670 0.1*889 2. 31*52 0.3371* 1*03. 85 i*79. 77 555.51 ?. 52450 440 576 1564 160.000 639.670 0.1*728 2. 1150 0.3257 1*18. 37 1*88, 76 567.09 2. 51.289 448 583 1587 200.000 659.670 0.1+578 2. 181*5 0. 311*9 1*32.80 1*97. 9? 578.82 2. 56095 457 590 1610 220.000 679.670 0. 1*1*37 2.2539 0.301*7 1*1*7. 15 507. 23 590.70 2. 57869 465 598 1632

21*0.000 699.670 0.1*305 2. 3230 0.2953 1.61.1.3 516. 71 602.71* 2. 59615 474 606 1653

280. 000 739.670 0.1*061* ?. 1*608 0.2781 1.89.79 536. 20 627.33 ?, 63033 1.92 o23 1695 320.000 779.670 0. 381*9 2. 5981 0.2629 517.91. 556. 1.1 652.63 2. 66362 511 541 1735

36 0.0 00 819.670 0.3656 2.731*9 0.21*93 51.5.90 577 35 678.61. 2. 69616 530 660 1774

1*00.000 859.670 0. 31*83 2.8711* 0.2371 573.71 599. 05 705.39 2, 72802 549 678 1811

1*1*0. 000 899. 670 0.3325 3.0075 0.2260 601.1.0 621. 5C 732.88 2. 75928 0. 56 8 696 1848

228
METHANE ISOBAR AT P 225.0 PSI

T T DEM VOL DP/DT OP/ DO E H S CU CP W OEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/L8/R FT/S 295.736 163.93*. 28.221 0.035<*3 166.587 3652.27 93.23 94.70 1.01219 0.495 0.784 5179 290.000 169.670 27.956 0.03577 160.027 3477.46 97.52 99.01 1. 03931 0.493 0.789 5078

260. 000 179.670 27.1*92 0.03637 149.115 3178.61 105.20 106.72 1.08485 0.494 0.802 4889 270.000 189.670 27.017 0.03701 138.803 2887.52 113.12 1 14.66 1.12868 0.495 0.316 4695 260.000 199.670 26.529 0.03769 129.033 2606.91 121.24 122.81 1.17097 0.494 0.829 4504 250.000 209.670 26.026 0.03842 119.745 2338.42 129.51 131.11 1.21179 0.490 0.841 4314 240.000 219.670 25.501* 0.03921 110.876 2082.85 137.92 139.55 1.2512 3 0.483 0.852 4126 230.000 229.670 2<». 960 0.04006 102.369 1840.30 146.46 148.13 1.28946 0.477 0. 866 3934 220.000 239.670 2i*. 390 0.01*100 94.168 1610. 32 155. 15 156.86 1.32670 0.472 0.883 3736 210.000 249.670 23.789 0.04201* 86.218 1391.99 164.05 165. 8C 1. 36322 0.469 0.905 3528 200.000 259.670 23.149 0.01*320 78.459 1184. 06 173. 19 174.99 1.39932 0.468 0.934 3310

190. 000 269.670 22.1*59 0. 01*1*53 70.821 985.05 182.65 184.51 1.43527 0.466 0.970 3082 180.000 279.670 21.701* 0.04606 63.210 793.26 192.51 194.43 1.47141 0.463 1.017 2840 172.882 286.788 21. 110 0.04737 57.733 660. 15 199.85 201.82 1.49750 0.459 1.061 2658 172.882 286.788 1.51*56 0.6470 1.2802 101. 16 335.74 362.70 2.05844 0.425 0.785 931 170.000 289.670 1.5105 0.6620 1.2388 105.96 337. 34 364.92 2.06617 0.421 0.761 942 160.000 299.670 1.4067 0.7109 1.1227 121. 10 342.60 372.22 2. 09094 0. 411 0.703 980

150. 000 309.670 1.3221* 0.7562 1.0346 134.63 347.53 379.04 2.11334 0.404 0.665 1013

11*0. 000 319.670 1.2515 0.7991 0.9640 147. 06 352.26 385.55 2.13402 0.399 0.538 1044 130.000 329.670 1.1903 0. 81.01 0.9055 158.69 356.82 391.83 2.15336 0.396 0.516 1072 120.000 339.670 1.1367 0.8797 0.8557 169.72 361. 28 397.93 2. 17161 0. 393 0.603 1098 110.000 349.670 1.0891 0.9182 0.8126 180.25 3 65.65 403.90 2.18893 0.391 0.591 1123 100.000 359.670 1.01*62 0.9558 0.7748 190. 38 369.95 409.77 2.20547 0.390 0.582 1147 -90.000 369.670 1.0071* 0.9926 0.7412 200.19 374.19 415.55 2.22133 0.389 0.574 1170 -80.000 379.670 0.9720 1. 1288 0.7110 209.71 378.40 421.26 2.23658 0.389 0.568 1192

-7 0.000 389.670 0.9395 1.061+1. 0.6837 219. 00 362.57 426.92 2.25128 0. 389 0.563 1212 -60.000 399.670 0.9095 1.0996 0.6588 228.07 386.72 432.53 2.26550 0.389 0.559 1233 -50.000 409.670 0.8815 1.13<*3 0.6360 236.97 390. 85 438.11 2.27928 0.389 0.556 1252

-40. 000 1*19.670 0.8557 1. 1686 0.6150 245.70 394.96 443.65 2.29265 0. 390 0.553 1271 -30.000 1*29.670 0.8315 1.2027 0.5956 254.30 399.07 449.17 2.30566 0.391 0.551 1289

-20.0 00 1*39.670 0.8088 1.2361* 0.5776 262.76 403.17 454.68 2.31832 0. 392 0.55C 1307 -10.000 1*1*9.670 0.7875 1.2699 0.5608 271.11 407.26 460.17 2.33068 0.393 0.549 1324

0. 000 1*59.670 0.7671* 1. 3031 0.5450 279.36 4 1 1 . 36 465.66 2.34274 0. 395 0.548 1341 10.000 1*69.670 0. 71*81* 1. 3362 0.5303 287.52 415.47 471.14 2. 35454 0. 396 0.548 1357 20.000 i*79.670 0.7305 1. 3690 .5164 295.59 419.59 476.62 2.36609 0. 398 0. 548 1373 30.000 1*89.670 0.7131* 1.4016 0.5033 303.58 423.71 482.11 2.37741 0.4C0 0.549 1389

40. 000 1*99.670 0.6973 1.4341 0.4909 311.50 427.85 487.60 2. 38852 0.402 0.550 1404 50.000 509.670 0.6619 1.4665 0.4792 319. 35 432.01 493.11 2.39942 0.405 0.551 1419 60.000 519.670 0.6673 1.4987 0.4681 327. 15 436. 18 498.62 2.41014 0.407 0.552 1433 70.000 529.670 0.6533 1.5308 0.4576 334.88 440.37 504.15 2. 42068 0. 410 0.554 1447

80. 000 539.670 0.6399 1.5627 0.4476 342.57 444.59 509.70 2.43106 0.413 0.556 1461 100.000 559.670 0.611*9 1.6263 0.4289 357.80 453.10 520.66 2.45136 0.419 0.560 1488 120.000 579.670 0.5919 1.6896 0.4118 372.86 461.71 532.11 2.47111 0.426 0.565 1514 1AO.O00 599.670 0.5706 1. 7 524 0.3961 387. 78 470.45 543.47 2.49038 0.433 0.571 1539 160.000 619.670 0.5509 1.8150 0.3817 402.56 479.33 554.95 2.50922 0.441 0.577 1563 180.000 639.670 0.5327 1.8774 0.3683 417.23 488.35 566.57 2.52767 0.449 0.584 1587 200.000 659.670 0. 5156 1.9395 0.3559 431. 79 497.52 578.33 2.54577 0.457 0.592 1610 220.000 679.670 0.1*996 2. 0014 0.3443 446. 27 506.85 590.24 2.56356 0.466 0.600 1632

240. 000 699.670 0.1*81*7 2.0631 0.3335 460.66 516.35 602.31 2.58106 0. 474 0.608 1653 280.000 739.670 0. 1.571* 2.1861 0.3139 489.23 535. 87 626.95 2.61530 0.493 0.625 1695 320.000 779.670 0.1.332 2. 3085 0.2966 517.55 556.11 652.29 2.64866 0.512 0.642 1735 360.000 819.670 0. 1.111* 2.4305 0.2812 545.-66 577. 08 678.34 2.6812* 0.531 0.660 1774 400.000 859.670 0.3918 2.5520 0.2673 573.61 598.80 705.13 2.71315 0.550 0.679 1812

1+140.000 899.670 0.371.1 2.5733 0.2548 601.40 621.27 732.65 2.74443 0.569 0.697 1848

229
METHANE ISOBAR AT P 250.0 PSI

T T OEN VOL CP/DT DP/OD F H S cv CP W DEG F OE& R LB/CUFT CUFT/LB PSI/R PSICUFT/IB BTU/ie "3TU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S

295.657 164. 013 28.224 0.03543 166.542 3655.56 93. 24 94. 88 1. 01230 495 784 5180

290. 000 169.670 27.963 0.03576 160.082 3483. 34 97. 48 99, 13 1. 03904 493 0. 739 5060 280.000 179.670 27.500 0.03636 149.184 3185. 03 105. 15 106, 83 1. 08456 4°4 802 4892

270. 000 189.670 27.026 0.03700 138.886 2894.40 113 06 114. 76 1. 12837 496 816 4699 260.000 199.670 26.539 0.03768 129.131 2614. 19 121. 17 122 92 1 17064 494 829 45C8 250.000 209.670 26.037 0.0 3841 119.856 2346. 06 129. 44 131. 22 1 21144 490 840 4319 240.000 219.670 25.516 0.03919 111.002 2090. 84 137 84 139. 65 1. 25085 483 o. 852 4131

230. 000 229.670 24.974 0.04004 102.512 1848.64 146, 37 148 22 1 28904 477 865 3940

220. 000 239.670 24.406 0.04097 94.330 1619.02 155. 05 156. 94 1 32624 472 332 3742 210.000 249.670 23.807 0.04201 86.401 1401. 11 163, 9? 165. 87 1 36272 ,469 904 3536 200.000 259.670 23.170 0.0+316 78.667 1193. 66 173. 04 175. C4 1. 39875 468 0. 932 3319

190. 000 269.670 22.484 0.04448 71.060 995.26 182. 4P 184 54 1 43461 467 a 968 3093

180. 000 279.670 21.735 0.04601 63.492 e04. 28 192. 30 194. 43 1 47063 463 i 013 2854

170. 000 289.670 20.893 0.04786 55.826 618.89 202 64 204, 85 1 50725 ,457 i 376 2597

168. 119 291. 551 20.721 0. 04826 54. 355 584. 46 204. 66 206. 89 1 51426 ,456 i 392 2546

168. 119 291.551 1.7329 0.5771 1.4616 96. 09 335. 72 362 44 2 04777 430 330 927 160.000 299.670 1.6231 0.6161 1.3311 109.98 340 34 368. 86 2 P6950 419 758 960 15C.O00 309.670 1.5150 0.6601 1.2118 125. CO 345 5° 376. 15 2 09342 410 703 997

it • 319.670 1. 4266 0.7010 1.1199 138.51 350 53 382 98 2 11516 .404 567 1030

130. 000 329.670 1.3518 0.7398 1.0455 150.99 355. 27 3e9. 52 2 13529 399 o41 106C

120. 000 339.670 1.2872 0.7769 0.9834 162.70 359 8f 395 83 2 15415 , 396 ,622 1088 110.000 349.670 1.2303 0. 1128 0.9304 173. 60 364. 34 401. 97 2. 17197 394 o07 1114

100. 000 359.670 1.1796 0.3477 0.6844 184. 43 368 74 407 98 2 1889? ,392 3 595 1139 -90.000 369.670 1. 1341 0. 3818 0.8438 194.66 373. OF 413 88 2 20511 391 n 586 1162 -80.000 379.670 1.0927 0. 9152 0.8077 204. 57 377 34 419. 70 2 22064 , 390 57« 1185 -70.000 389.670 1.0549 0.9480 0.7753 214. 19 381 57 425 45 7 23559 390 572 1206

-6 0.000 399.670 1.0202 0. 3802 0.7459 223.57 385. 77 431 15 2 25002 ,390 567 1227 -50.003 1*09.670 0. 9881 1. 0121 0.7190 232.74 389. 95 4 3b 80 7 26398 390 563 1247

-40. 000 419. 670 0.9583 1. J435 0.6945 241.73 394 1C 4 4 2, 41 2, 27752 391 560 126o -30.000 429.670 0. 9305 1. 0747 0.6718 250. 56 398. 25 448. 00 2 29067 392 557 1285 -20.000 439.670 0.9046 1. 1055 0.6508 259.24 402 38 453 56 2 30347 ,393 3 555 1303 -10.000 449.670 0.8803 1.1360 0.6313 267.79 406 51 h59. 10 2 31594 3 94 554 1321 0.000 459.670 0.8574 1.1663 0.6131 276. 22 410 64 + 64 64 2 32811 ,395 553 1338 10.000 469.670 0. 8353 1. 1964 0.5960 284.55 414. 78 470 16 2. 340C1 ,397 552 1354 20.000 479.670 0.8154 1.2263 0.5801 292.78 418 92 475 69 2 35164 399 3 552 1371 30.000 489.670 0.7962 1.2560 0.5650 300.92 423 07 481, 21 2. 36304 401 553 1386

40. 000 499.670 0.7779 1.2856 0.5508 308.99 427 23 486 74 2 37422 403 3, 553 1402

50. 000 509.670 0.76C5 1. 3150 0.5374 316.98 431. 40 492 28 2 38519 ,405 554 1417 60.000 519.670 0.7439 1. 3442 0.5247 324.90 435 60 497, 83 2 39597 408 555 1431 70.000 529.670 0.7282 1. 3733 0.5127 332.75 439 81 503, 39 2 40657 411 557 1446

80. 000 539.670 0.7131 1.+023 0.5012 340.55 444 04 508. 96 2 41700 413 558 1460

100. 000 559.670 0. 6849 1. 4600 0.4799 356.00 452 58 520 17 2 43739 ,420 3 563 1487 12C.O00 579.670 0.6591 1.5173 0.4605 371.25 461 23 531 47 2 45723 4 26 3 567 1513 140.000 599.670 0.6352 1.5743 .4428 386. 34 469 99 542 87 2 47657 4 33 573 153 8 160.000 619.670 0.6132 1.6309 0.4264 401.28 478. 89 554. 39 2. 495^7 441 C 579 1563

180. 000 639. 670 0.5927 1.6873 0.4113 416.09 487 94 566. 05 2 51397 449 a 586 1586 200.000 659.670 0.5736 1.7435 0.3973 430.79 497. 13 577. 84 2 53213 457 593 1609

220. COO 679.670 0.5557 1.7995 0.3842 445.39 506. 46 589. 78 2. *4996 4F6 501 1632

21*0.000 699.670 0.5390 1.8552 0.3721 459.90 516 00 601 88 2 56750 475 3 ,609 1653 280.000 739.670 0.5086 1.9663 0.3500 488.66 535. 54 626. 57 2. 60162 493 626 1695

320. 000 779.670 0.4815 2.0768 0.3306 517. 16 555. 81 651, 95 2. 63523 512 0. 543 1736 360.000 819.670 0.4573 2. 1869 0.3132 545. 43 576. 81 678. 05 2. 66787 531 661 1774

too. 000 859.670 0. 4354 2. 2966 0.2977 573.50 598, 5? 704, 87 2. 69981 550 0. o80 1812

1*1*0.000 899.670 0.4156 2.4059 0.2837 601.42 621, 04 732. 42 2. 73113 569 o. 698 1849

230
METHANE ISOBAR AT P = 275.0 PSI

T T DEN VOL DP/OT OP/ CD E H S C\l CP W DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 9TU/LB 3TU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S 295.577 164.093 28.228 0.03543 166.497 3658. 84 93.26 95.06 1.01241 0.495 0..784 5161

290. 000 169.670 27.971 0.03575 160.136 3489.22 97.43 99.25 1.03877 0.493 0,,789 5083 280.000 179.670 27.507 0.03635 149.253 3191.44 105. 1C 106.95 1.08427 0.495 0,,301 4895 270.000 189.670 27.034 0.01699 138.969 2901.27 113.01 114.89 1.12807 0.496 0,,316 4702 260.000 199.670 26.549 0.03767 129.227 2621.46 121. 11 123.03 1.17032 0.494 0. 329 4512 250.000 209.670 26.047 0.03839 119.967 2353.69 129.37 131.32 1.21109 0.490 0,,340 4323 240.000 219.670 25.523 0.03917 111.128 2098.81 137.76 139.75 1.25047 0.484 0,,851 4136 230.000 229.670 24.987 0.04002 102.654 1856.95 146.27 148.31 1.28863 0.477 0.,364 3946 220.000 239.670 24.421 0.04095 94.490 1627. 70 154.94 157.02 1.32579 0. 472 0.,881 3749 210.000 249.670 23.824 0.04197 86.582 1410.19 163.80 165.93 1.36221 0.470 0,,903 3544 200.000 259.670 23.190 0.04312 78.873 1203. 23 172.90 175.09 1.39813 0.468 0.,930 3329 190.000 269.670 22.509 0. 04443 71.298 1005.41 182. 30 184.57 1.43396 0.467 0,,965 3103 180.000 279.670 21.766 0.04594 63.771 815.19 192. 09 194.43 1.46986 0.464 1.,009 2867 170.000 289.670 20.933 0.04777 56.164 630.82 202.37 204.80 1.50630 0.457 1., 37 2614 163.666 295.984 20.341 0.04916 51.224 516.49 209.22 211.72 1.52992 0.452 1,,125 2440 163.686 295.984 1.9265 0.5191 1.6541 90.95 335.55 361.98 2. 03761 0.435 0. 380 923

160. 000 299.670 1.8636 0.5366 1.5755 97.99 337.81 365.14 2.04620 0.429 0,,334 939 150.000 309.670 1.7235 0.5802 1.4118 114.88 343.48 373.03 2.07410 0.416 0.,751 980 140.000 319.670 1.6130 0.5200 1.2916 129.67 348.70 380.27 2. 09713 0.409 0,,701 1015 130.000 329.670 1.5218 0.6571 1.1974 143. 10 353. 64 387.11 2. 11818 0.403 0. 567 1048 120.000 339.670 1.4443 0.6924 1.1204 155.56 358.39 393.65 2. 13773 0.399 0.,643 1077 110.000 349.670 1.3769 0.7 26 3 1.0556 167.28 362.99 399.98 2. 15610 0. 396 3,,524 1104 100.000 359.670 1.3174 0.7590 1.0001 178.43 367.49 406.14 2.17348 0.394 0.,610 1130 -90.000 369.670 1.2644 0.7909 0.9516 189. 11 371.90 412.18 2. 19004 0. 393 0,,598 1155 -80.000 379.670 1.2165 0.3220 0.9088 199.41 376. 25 418.11 2.20587 0.392 0,,589 1178 -70.000 389.670 1.1730 0.3525 0.8706 209.38 380.55 423.96 2.22108 0. 392 0,,581 1200

-6 0.0 00 399.670 1.1331 0.8825 0.8362 219.07 384.80 429.74 2.23574 0.391 0,,57 5 1221 -50.000 409.670 1.0 96 5 0.9120 0.8049 228. 52 3 89. 3 435.47 2.24989 0.392 0,,570 1242 -40.000 419.670 1.0625 0.9411 0.7764 237.77 393.23 441.16 2.26360 0.392 0,, 566 1262 -30.000 429.670 1.0310 0.9699 0.7502 246.83 397.42 +46.81 2.27690 0.393 0.,563 1261 -20.000 439.670 1.0017 0.9983 0.7260 255.72 401.59 452.43 2.28983 0.394 0.,561 1299

-10. 000 449.670 0.9742 1. 0265 0.7036 264. 47 405.75 458.02 2.30243 0.395 0,,559 1317 0.000 459.670 0.9484 1.0544 0.6828 273. 09 409.91 463.61 2.31471 0.396 0,,558 1335 10.000 469.670 0.9241 1.0821 0.6633 281.59 414.08 469.18 2. 32670 0. 398 0,,557 1352 20.000 479.670 0.9012 1.1096 0.6451 289.99 418.24 474.75 2.33842 0.400 0..556 1366

30. 000 489.670 0. 8796 1.1369 0.6280 298.28 422.42 460.31 2.34990 0.401 0,,556 1384 40.000 499.670 0.8591 1.1640 0.6119 306.49 426.60 485.88 2. 36116 0.404 3,,557 1400 50.000 509.670 0.8396 1. 1910 0.5967 314.61 430.80 491.45 2.37220 0.406 0,,55 7 1415 60.000 519.670 0.8211 1.2178 0.5823 322.66 435.01 497.03 2. 38304 0.408 0.,558 1430

70. 000 529.670 0. 8035 1. 2445 0.5687 330.64 439.24 502.62 2.39369 0.411 0.,560 1444 80.000 539.670 0.7867 1.2711 0.5558 338.55 443.49 508.22 2.40418 0.414 0,,561 1458 100.000 559.670 0.7553 1. 3239 0.5317 354.20 452. 06 519.48 2.42467 0. 420 0,,565 1486 120.000 579.670 0.7266 1.3764 0.5099 369.64 460.74 530.83 2. 44458 0.427 0.,570 1512

140. 000 599.670 0.7001 1.4285 0.4900 384.90 469.53 542.28 2.46400 0.434 Q.,575 1538 160.000 619.670 0.6756 1.4803 0.4716 400.01 478.46 553.84 2.46296 0.441 0,,581 1562 180.000 639.670 0.6528 1.5318 0.4547 414.96 487.52 565.53 2.50153 0.449 0..588 1586 200.000 659.670 0.6317 1.5831 0.4390 429. 80 496.73 577.35 2.51973 0.458 o. 595 16C9 220.000 679.670 0.6119 1.6342 0.4245 444.52 506. 10 589.32 2.53761 0.466 3,,o02 1631 240.000 699.670 0.5934 1.6851 0.4109 459.14 515.64 601.45 2.55519 0.475 0.,610 1653 280.000 739.670 0.5598 1.7865 0.3864 488. 11 535.22 626.19 2.58958 0.493 0,,627 1695 320.0 00 779.670 0.5299 1.3873 0.3647 516.78 555.51 651.62 2.62 305 0.512 0., 644 1776

36 . 819.670 0.5031 1.9876 0.3455 545.19 576.53 677.75 2.65573 0.531 0..662 1775 400.000 359.670 0.4790 2.3876 0.3282 573.40 598. 3T 704.60 2.68772 0.550 0,,680 1813

440. 000 899.670 0.4572 2.1872 0.3127 601.43 620.81 732.18 2.71907 0.569 0,,699 1850

231
METHANE ISOBAR AT P 300.0 PSI

T T DE^ VOL OP/DT DP/DD E H S CV CP H DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S

295.1*98 16i». 172 28.231 0.03542 166.1*52 3662. 12 93. 27 95.21* 1.01252 0.1.95 0.781* 5182 390.000 169.670 27.978 0.03571* 160.190 31*95.08 97. 39 99.37 1. 0381*9 0.1.91* 0.788 5085

280. 000 179.670 27.515 0.03631* 11*9.321 3197.83 105. 05 107.07 1.08399 0.1*95 0.301 1*898 270.000 189.670 27.01*3 0.03698 139.051 2908. 12 112. 95 115.00 1.12777 0.1.96 0.815 1*706 260.000 199.670 26.558 0.03765 129.323 2628.71 121. 05 123.11* 1.16999 0.1.95 0.828 1*516 250.000 209.670 26.058 0.03838 120.077 2361.30 129. 30 131.1*3 1.21071. 0.1.90 0. 839 1*328

2<t0. 000 219.670 25.51.0 0.03915 111.251* 2106.76 137. 67 139.85 1.25010 0. 1.81. 0.850 1*11.1 230.000 229.670 25.001 0.0*000 102.796 1865.21* 146. 16 11.8.1*0 1.28822 0.1*78 0.363 3952

22 0. 00 239.670 2i*. i*36 0.01*092 91.. 650 1636.31* 151*. 63 157. 11 1.32531. 0.1*73 0.380 3756 210.000 21*9.670 23.81*2 0.01*191* 86.762 11.19. 21* 163. 67 166.00 1. 36171 0.1*70 0.901 3552 200.000 259.670 23.211 0.01*308 79.078 1212.75 172. 75 175.15 1.39762 0.1*68 0.929 3338

190. 000 269.670 22.531* 0.01*1*38 71.533 1015.51 182. 13 181*. 60 1.1.3332 0.1*67 0.962 311* 180.000 279.670 21.796 0.01*588 61*. 01.6 826. 02 191. 66 191*. 1*3 1.1.6910 0.1*61* 1.005 2860 170.000 289.670 20.973 0.01*768 56.1*97 6i*2. 61* 202. 10 201*. 75 1.50537 0.1*58 1.063 2630

16 0.0 00 299.670 20.016 0.04996 1*6.673 1.63.37 213. 03 215.81 1.54288 0.1*1.9 1. 157 2352 159.535 300. 135 19.967 0.05008 1.6.296 1*55. 08 213. 57 216.35 1.51*1.68 0.1*1*9 1.163 2338 159.535 300.135 2.1271 0.1*701 1.8590 85.71. 335. 21. 361.36 2.02783 0.1*1*1 0.936 = 18 150. 000 309.670 1. 9518 0. 5123 1.61*10 101.. 15 31*1. 17 369.63 2.051.98 0.i»2i* 0.811* 962

l<tO. 000 319.670 1.8129 0.5516 1.1*826 120.1.8 31*6. 7L 377.38 2.07962 0.1*11* 0.7*3 1001 130.000 329.670 1.7017 0.5877 1.3630 135.00 351. 92 381*. 57 2.10176 0.1*07 0.697 1035 120.000 339.670 1.6088 0.6216 1.2677 H.8.29 356. 85 391.38 2. 12211 0. 1.03 0.666 1066

110. 000 31.9.670 1.5291* 0.6539 1.1890 160.68 361 59 397.92 2. 11*109 0.399 0.61*3 1095

100. 000 359.670 1.1*600 0.681*9 1.1221* 172. 36 366. 20 1*01*. 25 2. 15895 0. 397 0.625 1122 -90.000 369.670 1.3985 0.7150 1.061*9 183.53 370, 71 1*10.1*3 2.17590 0.395 0.611 111*7 -80.000 379.670 1.31*35 0.71*1*3 1.011*6 191*. 23 375. H. i*16.i*9 2. 19206 0. 391. 0.600 1171 -70.000 389.670 1.2933 0.7729 0.9699 201.. 56 379. 50 i»22. i*i* 2.20751* 0.393 0.591 1191. -60.000 399.670 1.2"*8i* 0.3010 0.9299 211.. 57 383. 82 1*28.32 2.2221*3 0. 393 0.581. 1216 -50.000 1.09.670 1.2069 0. 3 2 86 0.8938 2 21*. 31 386 IP i*3i*. 13 2.23679 0.393 0.578 1237

-< 0.000 1*19.670 1.1686 0. 8557 0.8610 233.82 392. 35 1*39.89 2.25068 0. 393 0.573 1257

-30. 000 1*29.670 1.1331 0.3825 0.8310 21*3. 11 396 56 i*i»5.60 2.261*11. 0. 391. 0.570 1277

-2 0.0 00 1*39.670 1.1001 0. 9090 0.8031* 252. 23 i*00 79 1*51.28 2.27 721 0.391. 0.567 1296

-10. 000 i* i»9. 670 1.0693 0. 9352 0.7779 261.18 i*0i«. 99 -56.91. 2.28992 0.396 0.561. 1311. 0.000 1*59.670 1. 0405 0.9611 0.751*2 269.98 i*09 16 1*62.57 2.30231 0.397 0.563 1332 10.000 1*69.670 1.0131* 0.9868 0.7321 278.66 1*13 37 1*68.19 2.311*1*1 0.398 0.561 1349 20.000 i*79.670 0.9879 1.0123 0.7115 287.21 1*17 5f 1*73.80 2.32622 0.1.00 0.561 1365

30. 000 1*89.670 0.9638 1.0376 0.6922 295.66 1*21 76 1*79. 1*0 2.33779 0.1.02 3.560 1382

1.0. ooo 1.99.670 0. 9i*10 1. 0627 0.671*1 301.. 01 1*25. 97 1*85.00 2.34911 0. <.0i* 0.560 1397 50.000 509.670 0.9191* 1. 0877 0.6570 312.26 1*30, 19 1*90.61 2.36022 0.1*07 0.561 11*13 60. 000 519.670 0.8989 1. 1125 0.61*09 32C.1.1. 1*31*. 1*2 1*96.22 2.37113 0.1.09 0.562 11.28 70. 000 529.670 0.8791* 1. 1372 0.6256 328.51. 1*38, 67 501.81. 2.38181* 0.1.12 0.563 11.1.2 80. 000 539.670 0. 8608 1. 1617 0.6111 336.56 i*i«2 91. 507.1*8 2.39238 0.1*11* 0.561. 11.57 100. 000 559.670 0.8261 1.2105 0.581*3 352.1*2 1*51 55 518.79 2.1.1296 0.1*20 0.568 11.85 120.000 579.670 0.791*3 1.2589 0.5599 368.05 1*60, 25 530.19 2.1.3297 0.1*27 0.572 1511

140. 000 599.670 0.7651 1.3070 0.537 7 383.1*9 1*69 07 541.68 2.1.521.6 0.1.31. 0.577 1537

160. 000 619.670 0.7381 1.351*7 0.5173 398.71* 1*78 02 553.28 2.1.711.9 0.1*1.2 0.583 1562

180. 000 639.670 0.7131 l.i*022 0.1.985 1*13.85 1*87 11 565.00 2.1*9011 0.1*50 0.590 1586 200.000 659.670 0.6899 1. i*i*95 0.1.812 1*28.81 i»96 31. 576.86 2.50836 0.1*58 0.596 1609 220.000 679.670 0.6682 1.1*965 0.1.651 1*1*3.65 505. 73 588.87 2. 52629 0. 1*66 O.oOi. 1631

240. 000 699.670 0.61*79 1.5i*3l* 0.1*501 1*56.38 515 26 601.02 2.51*391 0.1*75 0.612 1653

280. 000 739.670 0.6110 1.6367 0.1.229 1*87.56 53i*. 89 625.81 2.57837 O.i* 9i» 0.628 1696 320.000 779.670 0.5783 1.7293 0.3990 516. 1*0 555 21 651.28 2.61 190 0.512 0.61*5 1736 360.000 819.670 0.51*90 1. 3216 0.3778 5l*i*. 97 576. 2f 677.1*5 2. 6i*i*63 0.531 0.663 1775

1.00.000 859.670 0.5226 1.9131* 0.3589 573. 30 598. 05 70i*. 3i* 2.67665 0.550 0.681 1813

iti.0. 000 899.670 0.1*988 2. 0049 . 31*18 601.1.5 620 56 731.95 2.70801* 0.569 0.699 1850

232
METHANE ISOBAR AT P 325.0 PSI

T T DEN VOL DP/OT OP/OD e H S CU CP H DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/L3/R FT/S

295.419 164.251 28.234 0.03542 166.407 3665.39 93.29 95.42 1.01262 0.496 0.784 5183 290.000 169.670 27.985 0.03573 160.243 3500.92 97.34 99.49 1.03822 0.494 0.788 5088

-280.000 179.670 27.523 0.03633 149.389 3204.21 105. 00 107.18 1.08370 0.495 0.801 4901

270. 000 189-670 27.052 0.03697 139.133 2914.95 112.89 115.12 1.12746 0.496 0.815 4709

26 0.0 00 199.670 26.568 0.03764 129.419 2635.94 120.98 123.25 1.16967 0.495 0.828 4520 250.000 209.670 26.069 0.03836 120.187 2368.90 129.22 131.53 1.21040 0.490 0.839 4333 240.000 219.670 25.552 0.03914 111.379 2114.69 137.59 139.95 1.24972 0. 484 0.850 4146 230.000 229.670 25.014 0.03998 102.937 1673.51 146.09 148.49 1.28782 0.478 0.862 3958

220. 000 239.670 24.452 0.04090 94.808 1644.97 154.73 157.19 1.32489 0.473 0.879 3763 210.000 249.670 23.860 0.04191 86.941 1428. 25 163.55 166.07 1.36122 0.470 0.900 3559 200.000 259.670 23.232 0.04304 79.281 1222. 23 172.61 175.20 1. 39706 0.469 0.927 3347 190.000 269.670 22.559 0.04433 71.766 1025.55 181.96 184.63 1.43268 0.467 0.960 3125 leo.ooo 279.670 21.826 0.04582 64.318 836.77 191.67 194.43 1.46835 0.464 1.001 2893 170.000 289.670 21.011 0.04759 56.824 654.34 201.64 204.71 1.50445 0.458 1.057 2646 160.000 299.670 20. 069 0. 04983 49. 088 476.43 212.68 215.68 1.54168 0.449 1.146 2373 155.626 304.044 19.596 0.05103 45.537 399.36 217.75 220.82 1.55870 0.446 1.207 2239 155.626 304. 044 2.3355 0.1+282 2.0776 80.45 334.79 360.56 2.01831 0.447 1.000 914 150.000 309.670 2.2060 0.4533 1.9094 92.58 338.59 365.87 2. 03564 0. 434 0. 898 942

140. 000 319-670 2. 0291 0.4928 1.6971 110.86 344.62 374.28 2.06238 0.421 0.794 985 130.000 329.670 1.8928 0.5283 1.5447 126.65 350.10 361.89 2.08583 0.412 0.733 1022 120.000 3 39.670 1.7818 0.5612 1.4269 140. 87 355.24 389.01 2. 10709 0.406 0.693 1055 110.000 349.670 1.6883 0.5923 1.3315 153.99 360. 1U 395.79 2. 12675 0. 402 0.564 1065

100. 000 359.670 1.6076 0.5220 1.2520 166.28 364.67 402.31 2.14515 0.399 0.642 1113 -90.000 369.670 1.5369 0.5507 1.1842 177.92 369.

4

C 408.64 2.16252 0.397 0.625 1140 -80.000 379.670 1.4740 0.6784 1.1252 189. 05 374.00 414.83 2.17903 0.396 0.612 1164 -70.000 389.670 1.4174 0.7055 1.0734 199.75 378.44 420.90 2. 19481 0. 395 0.602 1188 -60.000 399.670 1.3662 0.7320 1.0273 210.09 382.82 426.87 2.20994 0. 394 0.593 1211 -50.000 409.670 1.3194 0. 7579 0.9858 220.12 387.15 432.77 2.22452 0.394 0.586 1232 -40.000 419.670 1.2764 0.7834 0.948 3 229. 89 391.45 438.60 2.23859 0.394 0.581 1253

-30. 000 429.670 1.2367 0.8086 0.9142 239.42 395.72 444.39 2.25221 0. 395 0.576 1273 -20.0 00 439.670 1.1999 0.1334 0.8829 248.76 399.97 450.13 2.26542 0. 395 0.573 1292

-10. 000 449.670 1.1656 0.3579 0.8540 257.91 404. 21 455.84 2.27826 0.396 0.570 1310 0.000 459.670 1.1336 0.8821 0.8273 266.90 408.44 461.52 2.29077 0.396 0.567 1328 10.000 469.670 1.1036 0. 9061 0.8025 275.75 412.66 467.19 2.30296 0.399 0.566 1346 20.000 •79.670 1.0753 0.9299 0.7794 284. 46 416. 86 472.84 2. 31487 0.401 0.565 1363 30.000 489.670 1.0487 0.9535 0.7578 293.06 421.10 478.49 2.32652 0.403 0.564 1379 40.000 499.670 1.0236 0. 9770 0.7375 301.55 425.33 -»84.13 2.33792 0.405 0.564 1395 50.000 509.670 0.9998 1. 3002 0.7184 309.94 429.56 489.77 2.34910 0.407 0.564 1411 60.000 519.670 0. 9772 1. 9233 0.7004 318. 24 433.83 495.42 2. 36007 0.410 0.565 1426 70.000 529.670 0.9557 1.0463 0.6834 326.46 438.10 501.07 2.37085 0.412 0.566 1441

60. 000 539.670 0.9353 1. 0692 0.6673 334.59 442. 39 506.73 2.38144 0.415 0.567 1455 100.000 559.670 0.8972 1.1146 0.6375 350.66 451. C3 518.10 2.40212 0.421 0.570 1463 120.000 579.670 0. 6624 1. 1596 0.6106 366.48 459.76 529.54 2.42221 0.427 0.574 1510 140.000 599.670 0.8304 1.2042 0.5860 382. 08 468.61 541.08 2.44177 0.435 0.579 1536 160.000 619.670 0.8009 1.2485 0.5635 397.50 477.58 552.72 2.46 87 0.442 0.585 1561

180. 000 639.670 0.7736 1.2926 0.5428 412.74 486.69 564.46 2.47955 0.450 0.591 1585

200. 000 659.670 0.7483 1. 3364 0.5237 427. 64 495.91. 576.37 2.49785 0.458 0.598 1608

220. 000 679.670 0.7246 1. 3801 0.5060 442.80 505.35 588.41 2.51583 0.467 0. 605 1631 240.000 699.670 0.7025 1.4235 0.4895 457.64 514.92 600.59 2.53349 0.476 0.613 1653 280.000 739.670 0.6623 1.5099 0.4598 487.01 534.57 625.43 2.56802 0.4 94 0.629 1696 320.00 779.670 0.6267 1.5957 0.4336 516.03 554.92 650.95 2.60161 0.513 0.646 1737

360. 000 819.670 0.5949 1.6811 0.4104 544.74 575.99 677.16 2.63438 0.532 0.664 1776 400.000 859.670 0.5662 1.7660 0.3896 573.21 597. 60 704.08 2.66645 0.551 0.682 1814 440.000 899.670 0.5403 1.1507 0.3710 601.47 620. 3t 731.72 2.69788 0.569 0.700 1851

233
ME THANE ISO BAR AT P 350.0 PSI

T T DEN VOL DP/DT OP/DD E H S CV CP H DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/Le BTU/LB 8TU/LB/R BTU/LB/R BTU/L9/R FT/S

295. 340 164. 330 26.238 0.03541 166.362 3668.66 93.30 95.60 1.01273 0.496 0.784 5184 290.000 169.670 27.992 0.03572 160.297 3506.75 97.30 99.61 1. 03795 0.494 0.788 5090 28G.000 179.670 27.531 0.03632 149.457 3210.58 104.95 107.30 1.08342 0.495 0.801 4904 270.000 189.670 27.060 0.03695 139.215 2921.77 112.84 115.23 1.12716 0.497 0.815 4713 260.000 199.670 26.577 0.03763 129.515 2643.16 120.92 123.36 1.16935 0.495 0. 827 4524

250. 000 209.670 26.079 0.03634 120.297 2376. 47 129.15 131.64 1.21005 0.491 0.838 4337

21*0.000 219.670 25.561* 0.03912 111.503 2122.61 137.51 140.05 1.24935 0.464 0.849 4152 230.000 229.670 25.027 0.03996 103.077 1881.76 146. 00 148.59 1.28741 0.478 0.361 3963

220. 000 239.670 2i*. 1*67 0.04087 94.966 1653.56 154.62 157.27 1.32445 0.473 0.877 3769

210. 000 21*9.670 23.877 0.04188 87. 119 1437.24 163.43 166.15 1.36 072 0.470 0.898 3567

200. 000 259.670 23.252 0.04301 79.482 1231.66 172.47 175.26 1.39650 0.469 0.925 3356 190.000 269.670 22.583 0.0*428 71.996 1035.54 181.79 184.66 1.43205 0.467 0.957 3135

160. 000 279.670 21.856 0.04575 64.586 847.45 191.47 194.43 1.46761 0.464 0.998 2905 170.000 289.670 21. 049 0. 04751 57. 145 665.93 2 01.59 204.67 1.50354 0.458 1.051 2662 160.000 299.670 20.121 0.0-*97 49.494 489.31 212.34 215.56 1.540 51 0.449 1.135 2394 151.929 307.71*1 19.225 0.05202 42.920 348.63 221.79 225.16 1.57213 0.443 1.258 2141 151.929 307.71.1 2.5523 0. 3917 2.3115 75. 09 334. 20 359.59 2. 00896 0.453 1.075 9C9 150.000 309.670 2.1*962 0.4006 2.2343 79.81 335.65 361.61 2.01551 0.447 1.023 920

11*0.000 319.670 2.2655 0.4414 1.9415 100.68 342.31 370.92 2.04510 0.428 0.36 96 8 130.000 329.670 2.0972 0.4768 1.7455 118. 01 348.16 379.06 2.07018 0.417 0.776 iooe

120.000 339.670 1. 9642 0.5091 1.5995 133.28 353.54 386.53 2. 09252 0.410 0.723 1043 110.000 31*9.670 1.851*3 0.5393 1.4841 147.20 356.62 393.58 2. 11295 0. 405 3.687 1075 100.000 359.670 1.7603 0.5679 1.3895 160. 12 363.50 400.31 2.13193 0.402 0.561 1105 -90.000 369.670 1.6797 0.5954 1.3097 172.29 368.22 406.81 2.14977 0.399 0.541 1132 -80.000 379.670 1.6081 0.6219 1.2412 183. 86 372.83 413.14 2.16665 0. 397 0.525 1156 -70.000 389.670 1. 51*1*1 0.6476 1.1813 194.94 377.35 419.32 2.18274 0. 396 0.613 1182 -60.000 399.670 1.1*865 0.6727 1.1284 205.61 381. 80 425.40 2. 19814 0.395 0.603 1205 -50.000 i*09.670 1.1*31*1 0.6973 1.0811 215.94 366.19 431.39 2.21293 0.3 95 0.595 1227

-40. 000 i*19.670 1. 3861 0.7215 1.0385 225. 98 390.54 437.30 2.22720 0. 395 0.588 1248 -30.000 1*29.670 1.3420 0.7452 0.9998 235.75 394.86 443.16 2.24 98 0.396 0.583 1269

-20. 000 1*39.670 1.3011 0.7686 0.9645 245. 31 399. 15 448.96 2.25435 0. 396 0.579 1288

-10. 000 1*1*9.670 1.2632 0.^916 0.9321 254.66 403.43 454.73 2.26 7 32 0. 397 0.575 13C7

0. 000 459.670 1. 2278 0. 3145 0.9022 263.84 407.69 460.47 2.27994 0. 398 0.573 1325 10.000 1*69.670 1. 191*7 0.3370 0.8745 272.86 411.94 466.19 2.29224 0.400 0.571 1343 20.000 1*79.670 1. 1636 0. 3594 0.8487 281.74 416. IS 471.88 2.30425 0.401 0.569 1360 30.000 1*89.670 1.1341* 0. 3815 0.8246 290.49 420.44 477.57 2.31598 0.403 0.566 1377

1*0. 000 499.670 1. 1068 0.3035 0.8020 299.12 424.70 483.25 2.32746 0.405 0.568 1393 50.000 509.670 1.0807 0. 9253 Q.7809 307.64 428.96 4 8 8.93 2.33871 0.408 0.568 1409 60.000 519.670 1.0560 0.9470 0.7610 316. 07 433.24 494.61 2.34975 0.410 0.568 1424 70.000 329.670 1.0325 0.9685 0.7421 324. 40 437.52 500.29 2.36053 0.413 0.569 1439

80. 000 539.670 1.0102 0.9899 0.7244 332.65 441.83 505.99 2.37123 0.415 0.570 1454

100. 000 559.670 0.9687 1. 0323 0.6915 348.92 450.50 517.41 2.39202 0.421 0.573 1462 120.000 579.670 0.9308 1.3744 0.6619 364.93 459.27 528.90 2.41219 0.428 0.577 1509

11*0. 000 599.670 0.8960 1.1161 0.6349 380.70 468. 14 540.48 2.43183 0. 435 0.581 1535 160.000 619.670 0.8639 1.1575 0.6102 396.26 477.14 552.16 2.45099 0.442 0.587 1561

180. 000 639.670 0.8343 1.1986 0.5875 411.65 486.27 563.96 2.46972 0.450 0.593 1585

200. 000 659.670 0.8063 1.2395 0.5666 426. 88 495.55 575.88 2.48803 0.459 0.500 1608 220.000 679.670 0. 7811 1. 2602 0.5472 441.96 504.96 587.95 2.50610 0.467 0.607 1631

21*0.000 699.670 0.7572 1. 3207 0.5293 456.91 514.56 600.16 2.52381 0.476 0.614 1653

280. 000 739.670 0.7137 1.+012 0.4968 466.48 534.24 625.05 2.55840 0.494 0.530 1696 320.000 779.670 0.6752 1.4811 0.4683 515.66 554.62 650.61 2.59205 0.513 0.647 1737

360. 000 819.670 0.6403 1.5606 0.4431 544. 53 575.71 676.86 2.62488 0.532 0.565 1776

1*00.000 859.670 0.6099 1.6397 0.4206 573.13 597.55 703.82 2.65699 0.551 0.583 1814

1*1*0.000 899.670 0.5819 1.7185 0.4003 601.50 620.11 731.49 2.68845 0.570 0. 701 1651

234
METHANE ISOBAR AT P = 375.0 PSI

T T DEN VOL DP/DT DP/DO F H S CV CP H DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB 3TU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S 295.260 164.410 2 8.241 0.03541 166.317 3671.92 93.31 95.77 1.C1284 0.496 0.783 5184 290.000 169.670 27.999 0.03572 160.350 3512.56 97. 25 99.73 1.03768 0.494 0.788 5092 280.000 179.670 27.539 0.03631 149.525 3216.93 104.90 107.42 1. 08313 0.495 3.300 4907

270. 000 189.670 27.069 0.03694 139.296 2928.58 112.78 115.35 1.12686 0.497 0.814 4716 260.000 199.670 26.587 0.03761 129.610 2650. 37 120.86 123.47 1.16903 0.495 0.827 4528 250.000 209.670 26.090 0.03833 120.406 2384. 03 129. 06 131.74 1.20971 0.491 0.3 38 4342 240.000 219.670 25.575 0.03910 111.626 2130.50 137.43 140.15 1.24898 0.485 0. 348 4157 230.000 229.670 25.041 0.03993 103.216 1889.98 145.90 146.68 1.28701 0.478 0.361 3969 220.000 239.670 24.482 0.04085 95.122 1662.13 154.52 157.35 It 32401 0.473 0.376 3776 210.000 249.670 23.894 0.04185 87.295 1446. 19 163.31 166.22 1.36023 0.470 0.397 3575 200.000 259.670 23.272 0.04297 79.682 1241. 06 172. 33 175.31 1.39595 0.469 0.323 3364 190.000 269.670 22.607 0.04423 72.224 1045.48 181.63 184.70 1.43142 0.468 0.955 3146 180.000 279.670 21.885 0.04569 64.851 858. 06 191.27 194.44 1.46687 0.464 0.394 2918

170.000 289.670 21.086 0.04742 57.462 677.41 201.33 204.63 1.50265 0.458 1.046 2678

160. 000 299.670 20. 172 0-04957 49.889 502. 02 212. 0C 215.45 1.53937 0.449 1.125 2414 150.000 309.670 19.058 0.05247 41.796 329.64 223.72 227.36 1.57847 0.442 1.279 2102 148.418 311.252 18.852 0.03304 40.422 30?. 37 225.72 229.40 1.58499 0.448 1. 325 2035 148.418 311.252 2.7802 0. 3597 2.5627 69.65 333.49 358.46 1.99970 0.459 1. 162 904

140. 000 319. 670 2.5282 0. 3955 2.2254 89.77 339.75 367.22 2.02746 0.437 0.948 95 130.000 329.670 2.3175 0.4315 1.9694 108.98 346.07 376.03 2.05462 0.423 0. 328 994 120.000 339.670 2. 1574 0.4635 1.7877 125.49 351.

7

C 383.94 2. 07825 0.414 0.759 1032 110.000 349.670 2.0283 0.4930 1.6480 140. 28 357. 04 391.28 2. 09956 0.408 0.713 1065 100.000 359.670 1.9201 0.5208 1.5356 153. 89 362. 08 396.24 2. 11920 0.404 0.681 1096 -90.000 369.670 1.8272 0.5473 1.4422 166.62 366.93 404.93 2.13754 0.4C1 0.657 1124 -80.000 379.670 1.7460 0.5727 1.3627 178.65 371.64 411.41 2.15483 0.399 0.639 1151

-7 0. 00 389.670 1.6740 0.5974 1.2939 190. 13 376. 24 417.72 2. 17124 0. 398 0.624 1176 -60.000 399.670 1.6094 0.6214 1.2334 201.15 380.76 423.91 2. 18692 0.397 0.613 1200

-50. 000 409.670 1.5510 0.6448 1.1797 211.78 385.22 429.99 2. 20195 0.396 0.604 1222 -40.000 419.670 1.4977 0.6677 1.1316 222.09 389.62 *35.99 2.21641 0. 396 0.596 1244 -30.000 429.670 1.4488 0.6902 1.0881 232. 11 393.99 441.91 2.23037 0.397 0.590 1265 -20.000 439.670 1.4038 0. 7124 1.0485 241.89 398. 32 447.79 2.24388 0. 397 0.585 1285 -10.000 449.670 1.3620 0.7342 1.0122 251.45 402.63 53. 62 2.25699 0.398 0.581 1304

0. 000 459.670 1.3231 0.7558 0.9789 260.61 406.93 459.41 2.2697* 0.399 0.57 8 1323

10. 000 469.670 1. 2868 0.7771 0.9481 270. 01 411.21 465.18 2.28214 0.401 0.575 1341 20.000 479.670 1.2528 0.7982 0.9194 279. 05 415.49 470.92 2.29425 0.402 0.574 1358

30. 000 489.670 1.2208 0.3191 0.8928 287.94 419.77 476.65 2. 30607 0.404 0.572 1375

40. 000 499.670 1. 1907 0. 3398 0.8678 296.72 424.05 482.37 2.31763 0.406 0.572 1391

50. 000 509.670 1.1623 0. 8604 0.8445 305.37 428. 34 488.08 2.32895 0.408 0.571 1407 60.000 519.670 1.1354 0. 3808 0.8225 313.92 432.64 493.80 2. 34005 0.411 0.571 1423 70.000 529.670 1. 1099 0.9010 0.8018 3 2 2.37 436.95 499.51 2.35095 0.413 0.572 143 8 80.000 539.670 1.0856 0.9212 0.7823 330.73 441.27 505.24 2. 36165 0.416 0.573 1453

100. 000 559.670 1. 0405 0.9611 0.7463 347.21 449.98 516.72 2. 38254 0.422 0.575 1481 120.000 579.670 0.9994 1. 0006 0.7138 363. 39 458.76 528.26 2.40280 0.426 0.579 1509

140. 000 599.670 0.9618 1.3397 0.6843 379. 33 467.66 539.88 2. 42251 0.435 0.583 1535 160.000 619.670 0.9271 1.0786 0.6574 395.05 476. 7C 551.60 2. 44174 0.443 Q.589 1560

180. 000 639.670 0.8951 1.1172 0.6327 410.58 485.86 563.43 2.46053 0.451 0.595 1585 200.000 659.670 0.8654 1.1555 0.6099 425.93 495. 15 575.39 2.47894 0.459 0.601 1608 220.000 679.670 0.8377 1. 1937 0.5889 441. 13 504. 6C 587.49 2.49701 0.467 0.608 1631 240.000 699.670 0.8119 1.2316 0.5693 456. 19 514. 21 599.73 2.51475 0. 476 0.616 1653 280.000 7 39.67 0.7651 1.3070 0.5341 485.95 533.91 624.68 2.54942 0.494 0.S32 1696 320.000 779.670 0.7236 1. 3819 0.5033 515. 31 554.32 650.28 2.58313 0.513 3.649 1737 360.000 819.670 0.6867 1.4563 0.4760 544. 32 575.44 676.57 2.61600 0.532 0.666 1777 400.000 859.670 0.6535 1. 5303 0.4516 573. 05 597.30 703.56 2.64815 0.551 0.684 1815 440.000 399.670 0.6235 1.6039 0.4298 601.53 619.88 731.26 2.67965 0.570 0.701 1852

235
ME THANE ISOB AR AT P 400.0 PSI

T T DEN VOL DP/DT OP/CD E H S CV CP H DEG F OEG R LB/CUFT CUFT/LB °SI/R PSICUFT/LB 9TU/LP 3TU/LB 8TU/LB/R BTU/LB/R BTU/L3/R FT/S

295. 181 161.. 1,89 28. 21.5 0.0351.1 166.272 3675. 17 93. 33 95.95 1. 01295 0.496 0. 783 5185 290.000 169.670 28.006 0.03571 160.403 3518. 36 97. 21 99.85 1. 03741 0.495 0, 787 5095

280. 000 179.670 27.51.6 0.03630 149.592 3223. 26 104, 85 107.54 1. 08285 0.496 300 4910 270.000 189.670 27.077 0.03693 139.378 2935. 37 112. 72 115.46 1. 12656 0.497 0. 314 4720

260. 000 199.670 26.596 0.03760 129.705 2657. 55 120. 79 123.58 1. 16871 0.4 96 0. 326 4531 250.000 209.670 26. 100 0.03831 120.514 2391. 58 129. 01 131.85 1, 20936 0.491 0, 837 4346

21.0. 00 219.670 25.587 0.03908 111.749 2138. 38 137. 35 140.25 1. 24861 0.485 0. 848 4162 230.000 229.670 25. 05-. 0.03991 103.355 189B. 19 145. 81 148.77 1. 28660 0.479 0. 860 3975 220.000 239.670 2i*. 497 0.01.082 95.278 1670. 68 154. 41 157.44 1. 32356 0.474 0. 875 3783 210.000 21.9.670 23.912 0.04182 87.470 1455. 12 163. 19 166.29 1. 35975 0.471 0. 396 3582

200. 000 259.670 23.292 0.04293 79.880 1250. 42 172. IS 175.37 1. 39 541 0.469 921 3373 190.000 269.670 22.631 0. 04419 72.451 1055. 36 181. 46 184.74 1. 43079 0.468 0. 953 3156 180.000 279.670 21.9H. 0. 04563 65. 113 868. 60 191. 07 194.45 1. 46615 0. 464 0. 991 2930 170.000 289.670 21.123 0.04734 57.773 688. 80 201. 09 204.59 1. 50178 0.458 1 040 2693 160.000 299.670 20.221 0.04945 50.276 514. 56 211. 68 215.34 1. 53825 0.449 1 115 2434

150. 000 309.670 19.132 0.05227 42.321 344. 01 223. 24 227.11 1. 57689 0.442 1 257 2130

11.5.075 311.. 595 18. 1*7-* 0. 05413 38.026 260. 16 229. 60 233.61 1 59766 0.449 1 398 1937

11.5.075 31i».595 3.0193 0. 5312 2.8338 64. 11 332. 63 357.16 1 99043 0.466 1 266 899

11.0. 000 319.670 2.8266 0. 3538 2.5650 77. 84 336. 84 363.05 2. 00900 0.449 1 075 929 130.000 329.670 2.557-. 0.3910 2.2223 99. 50 343. 8T 372.77 2 03895 0.430 393 979 120.000 339. 670 2.3633 0.4231 1.9941 117. 44 349. 85 381.19 2 06414 .419 300 1019 110.000 31.9.670 2.2111 0.4523 1.8247 133. 23 355. 39 388.89 2 08647 0.412 743 1055 100.000 359.670 2.0859 0.4794 1.6913 147, 59 360 61 396.11 2 10684 0.407 704 1087

-90. 000 369.670 1.9799 0.5051 1.5821 160. 91 365. 5° 403.00 2. 12573 0. 404 0. 675 1117 -80.000 379.670 1.8880 0.5297 1.4902 173. 43 370 41 409.64 2 14346 0.401 654 1144 -70.000 389.670 1.8072 0.5534 1.4114 185. 32 375, 1C 416.09 2 16023 0. 399 637 1170

-6 0.000 399.670 1.7351 0.5763 1.3426 196. 69 379. 7C 422.39 2 17619 0.398 624 1194 -50.000 1.09.670 1.6702 0.5987 1.2819 207. 64 384 22 428.57 2 19147 0. 398 613 1218

-1.0.000 1.19.670 1.6113 0.3 20 6 1.2278 218. 22 388 6° 434.66 2 20614 0. 397 604 1240

-30. 000 1.29.670 1.5571. 0.6421 1.1790 228. 49 393 1C -.40.66 2 22028 0.398 597 1261 -20.000 1.39.670 1.5078 0.5632 1.1348 238 50 397 .4e 446.60 2 23395 0.398 591 1281 -10.000 it 49. 670 l.i*620 0. 5840 1.0945 248. 26 401 83 "52.49 2 24720 0. 399 ,587 1301 0.000 459.670 1.1.195 0. 7045 1.0574 257, 82 406, ie 458. 34 2 26C07 0.400 583 1320 10.000 +69.670 1.3799 0.?247 1.0233 267. 18 41C 48 464.16 2 27258 0.401 580 1338

20. 000 479.670 1.3i*28 0. 7447 0.9917 276. 38 + 14 7° +69.95 2 28479 0.403 ,578 1356

3C. 000 489.670 1.3081 0. 7645 0.9623 285. 43 419 10 i*75.72 2 29670 0.405 576 1373

1.0. 000 1.99.670 1.2753 0. 7841 0.9349 294, 34 423 40 481,48 2 30834 0.407 a 575 1389 50.000 509.670 1.2+45 0. 3036 0.9092 303. 13 427 72 487.23 2 31974 .409 575 14C6 60.000 519.670 1.2153 0. 3228 0.8851 311. 80 432 01 •92.98 2 33090 0.411 575 1421

70. 000 529.670 1. 1876 0. 3420 0-8625 320. 37 436 37 498.73 2 34186 0.414 575 1437 80.000 539.670 1. 1614 0. 3610 0.8411 328. 84 440, 71 504.49 2 35262 0.416 i 576 1451 100.000 559.670 1. 1127 0. 3987 0.8018 345. 52 449, 45 516.02 ? 37361 0.422 578 1480 120.000 579.670 1.068+ 0.9360 0.7664 361. 89 458. 26 327.61 2. 39396 0.429 581 1508

11*0. 000 599.670 1. 0278 0. 9730 0.7343 377 99 467 21 539.28 2 41375 0.436 586 1534

160. 000 619.670 0.9905 1. 3096 0.7050 393. 86 476 26 551.04 2 43304 0.443 591 1560 180.000 639.670 0.9561 1. 1460 0.6782 409. 52 485. 44 562.91 2

,

45189 0. 451 597 1584 200.000 659.670 0.921.2 1. 3821 0.6536 425. 00 4^4. 7€ 574.90 2 47 35 0.459 60! 1608

220. 000 679. 670 0.891.5 1.1180 0.6308 440. 32 504 22 587.03 2 48846 0.468 610 1631

21.0.000 699.670 0.8668 1.1537 0.6097 455. 49 513 85 599.30 2, 50625 0.476 617 1653 280.000 739.670 0.8166 1.2246 0.5717 485. 44 533, 59 624.30 2, 54099 0.495 o33 1696 320.000 779.670 0.7722 1.2950 0.538"* 514. 96 554. 02 649.94 2. 57476 0.513 0. o50 1738 360.000 819.670 0.7326 1. 3650 0.5090 544. 12 575 17 676.27 2 60768 0.532 667 1777

1.00.000 859.670 0.6971 1. 4345 0.4828 572. 97 597. 04 703.30 2. 63987 0.551 •d84 181b

1.1.0. 000 899.670 0.6650 1.5C37 0.4593 601. 57 619 65 731.03 2 67140 0.570 T 0? 1853

236
METHANE ISOBAR AT P = 1*1*0.0 PSI

T T DEN VOL OP/DT DP/DD E H S cv CP W DEG F OEG R LB/CUFT CUFT/L8 PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S

295.055 164.615 28.250 0.0351*0 166.201 3680.36 93 35 96 ,24 1 .01312 ,496 ,783 5186 290.000 169.670 26.013 0.03569 160.1*87 3527.61 97 13 100 04 1 03698 .495 7 87 5098

280. 000 179.670 27.559 0. 03629 11*9.699 3233.37 101. .77 107 .72 1 ,08240 ,496 ,800 4914

27 0.0 00 189.670 27.091 0.03691 139.507 291*6. 21 112 64 115 64 1 12608 ,497 313 4725 260.000 199.670 26.611 0.03758 129.855 2669. 02 120 69 123 75 1 16820 ,496 326 4538 250.000 209.670 26.117 0.03829 120.687 21.03.62 128 90 132 02 1 208B2 . 491 a .836 4353

240. 000 219.670 25.606 0.03905 111.91*5 2150.91. 137 2? 11.0 41 1 24802 ,485 847 4170 230.000 229.670 25.075 0.03988 103.575 1911.27 11*5 67 11*8 92 1 28596 ,479 ,359 3984

22 0.00 239.670 21*. 521 0.01*078 95.526 1681.. 30 154 25 157 57 1 32266 .474 ,374 3793 210.000 249.670 23.939 0.01*177 87.71*9 1469. 33 163 00 166 40 1 35897 471 394 3594 200.000 259.670 23.321* 0.01*287 60.191* 1265.32 171 97 175 46 1 39454 ,469 919 3387 190.000 269.670 22.668 0. 01*1*11 72.808 1071. 07 181 20 161* 80 1 42961 468 949 3172 180.000 279.670 21.960 0. 01*551* 65.526 885. 3? 190 75 19i* 47 1 ,46500 ,465 .986 2949 170.000 289.670 21. 180 0. 04721 58. 261 706. 81 200 70 201. 54 1 50040 458 1 032 2716 160.000 299.670 20.297 0.01*927 50.877 534. 31 211 17 215 18 1 ,53651 ,449 1 101 2465 150.000 309.670 19.245 0.05196 1.3.121 366. 39 222 52 226 75 1 57447 441 i 227 2173 140.032 319.638 17.852 0.05602 31*. 363 200.21 235 73 21.0 29 1 61744 .452 1 547 1782

140. 032 319.638 3.1*315 0. 291i» 3.3172 55.01. 330 9«t 351. 66 1 97536 ,478 1 483 869 140.000 319.670 3.1*296 0. 2916 3.3H*3 55. 15 330 97 354 73 1 97551 478 1 480 890 130.000 329.670 2.9962 0. 3338 2.7092 83. 02 330 69 366 88 2 01297 441. 1 .0 45 952 120.000 339.670 2.721*9 0.3670 2.3711* 103.92 31.6. 51. 376 44 2 04155 428 0. 986 999

110. 000 349.670 2.5251 0.3960 2.1386 121.59 352 57 381. 84 2 .06592 , 413 300 1038 100.000 359.670 2.3668 0.4225 1.9629 137.30 358, 12 392 55 2 08766 412 746 1073

-90. 000 369.670 2.2359 0.1*1*73 1.8230 151. 66 363. 36 399 60 2 10756 .408 709 1105

-80. 000 379.670 2. 121*1* 0.+707 1.7077 165. 02 368. 38 i* 06. 73 2 12606 404 d90 1134 -70.000 389.670 2.0276 0.4932 1.6103 177.61 373. 21. 1*13 42 2 14344 402 658 1161 -60.000 399.670 1.91*22 0. 51<*9 1.5261* 189.56 377, 97 <*19 92 2 15991 401 642 1186 -50.000 i*09. 670 1.8659 0.5359 1.1*531 201.01. 38?. 60 1*26 27 2 17560 ,400 c?9 1210

-MO. 000 1*19.670 1 . 7 97 2 0. 5561* 1.3882 212. 06 387. 16 "*32 50 2 19063 399 0. 618 1233 -30.000 1*29.670 1.731*7 0.3765 1.3302 222.76 391, 66 1+36, 63 2 20507 399 j d09 1255

-2C. 000 1*39.670 1.6775 0.5961 1.2779 233. 13 396. 12 -.44 69 2 21901 400 60? 1276

-10. 003 1*1*9.670 1.621*8 0.6155 1.2301* 21*3.23 1*00. 51. 1*50 68 2 23248 400 c 59' 1296 G.000 1*59.670 1. 5761 0. 631*5 1.1870 253. 09 1*01*. 93 -.56. 62 2. 24555 401 0. 59 2 1315 10.000 i*69.670 1.5309 0.6532 1.11*72 262.73 1*09. 30 i»62 52 2 25925 402 538 1334 20.000 i*79.670 1.1*887 0.6717 1.1105 272. 19 1*13. 66 1*68. 39 2, 27 62 404 a, 385 1352 30.000 1*89.670 1. 1*1*92 0.6900 1.0761* 281.1*8 1*18. 01 474, 23 2 28267 406 0, 383 1370 40.000 1*99.670 1.1*121 0. 7082 1. 01*1*7 290. 61 1*22. 36 i*80. 06 2. 29445 4 07 39? 1386 50.000 509.670 1.3772 0.7261 1.0152 299. 61 1*26. 71 485. 87 2 30596 410 0, 531 140 3 60. 000 519.670 1. 31*1*3 0. 7i»39 0.9875 308.1*8 1*31. 07 491 68 2, 31724 412 0. 590 1419

70. 000 529.670 1.3131 0.7615 0.9615 317.23 1*35. 1.3 *97 48 2. 32830 0, 414 0, ?90 1434

80. 000 539.670 1. 2836 0. T 791 0.9370 325. 67 1*39. 81 503. 28 2, 33916 417 0. 580 1450

100. 000 559.670 1.2289 0.8137 0.8921 31.2. 87 448. 61 514. 91 2. 36C31 423 a, 592 1479 120.000 579.670 1.1793 0. 91*80 0.8518 359.53 i*57. 1*9 526. 58 2, 38079 429 0. 385 1507

140. 000 599.670 1.1339 0. 1819 0.8151* 375.89 1*66. i»e 538. 32 2. 40070 436 0, 589 1533

16 0. 000 619.670 1.0923 0. 9155 0.7823 392. 00 1*75. 55 550. 14 2. 42010 444 a. 594 1559

180. 000 639.670 1.0539 0. 91*88 0.7521 1.07.88 <*6i*. 77 562. 07 2. 43905 451 0, 599 1584 200.000 659.670 1. 0181* 0. 3819 0.721*3 1.23. 56 i*9i*. 12 574. 1? 2. 45760 460 B, 606 1606 220.000 679.670 0.9851* 1.011*8 0.6986 1.39.06 503. 62 586. 30 2. 47 57 8 468 a. 512 1631

2<*0. 000 699. 670 0.951*7 1.01*75 0.6 71*9 1.51.. 1.0 513. 27 598. 61 2, 49364 u 477 a. 519 165 4 280. 000 739.670 0.6990 1.1123 0.6323 1.81*. 66 533. 07 623. 69 2. 52849 495 0. 6 35 1697

320. 000 779.670 0.81*99 1.1766 0.5951 511.. i*i* 553. 51. 649. 41 2. 56235 , 514 , o51 1738 360.000 819.670 0.8062 1.21*05 0.5622 51.3. 83 571.. 73 675. 80 2. 59535 0, 533 0. 666 1778 400.000 859.670 0.7 66 9 1. 3039 0.5330 572.88 5 96. 61. 702. 88 2. 62761 0. 552 0. 686 1817 440.000 899.670 0.7315 1. 3670 0.5069 601.65 619. 28 730. 66 2. 65 92 0, 570 a. '03 1854

237
ME THANE ISO BAR AT P = <*80.0 PSI

T T DEN VOL DP/OT DP/DO F H S CV CP H DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/L3/R FT/S

291..928 16i».7i*2 28.255 0.03539 166.130 3685.51. 93.38 96.52 1.01329 0.1*97 783 5168

290. 000 169.670 28.029 0.03568 160.570 3536. 82 97.06 100.23 1.03656 0.1*95 0. 787 51C2

28 0.000 179.670 27.571 0.03627 11.9.806 321.3. Ui> 101.. 69 107.91 1. 08195 0.1*96 o. 799 i*919 270. 000 189.670 27.101. 0.03689 139.635 2957.01 112.55 115.83 1.12561 0.1*98 0, 813 1*731 26 0.000 199.670 26.626 0.03756 130.005 2680.1.6 120.59 123.93 1. 16769 0.1*96 0. 825 1*51*1* 250.000 209.670 26.133 0.03827 120.859 2i.15.61 128.7° 132.19 1.20627 0.1*92 0. 936 1*361 21.0.000 219.670 25.621* 0.03903 112.139 2163. i»6 137. 10 11.0.57 1. 21*71*3 0.1*86 0. 8i*6 1*178 230.000 229.670 25.096 0.03985 103.791. 1921*. 30 11.5.53 11.9.07 1.28533 0.479 857 3991* 220. 00J 239.670 2i». 5i*i* 0. J-.071* 95.771 1697. 86 151.. 09 157.71 1.32217 0.1*71* 672 3801* 210.000 249.670 23.966 0.01*173 88.021* 11.63.1.6 162.81 166.52 1.35820 0.1*71 892 36C6 200.000 259.670 23.356 0.0+282 80.501* 1280. 12 171.75 175.56 1. 39368 0.1.70 916 3<*01 190.0 00 269.670 22.705 0.01*1.01. 73.161 1086.66 180.95 181.. 66 1.1.2883 0.1.68 0. 91*5 3188

160. 000 279.670 22.005 0. 0i*5i* k 65.932 901.87 190.1.5 191.. 1*9 1.1.6387 0.1.65 0. 981 2968 170.000 289.670 21.236 0.01*709 58.738 721.. 56 200.32 201.. 50 1.1.9906 0.1.58 1, 025 271.0 160.000 299.670 20.371 0. 01*909 51.1*59 553.71 210.68 215. 01. 1.531*82 0.1.1.9 1 088 21.91. 150.000 309.670 19.351 0.05168 1.3.878 388. 12 221.83 226.1.2 1.57217 0.1*1.1 1 200 2213

11*0. 000 319.670 18.035 0.0551*5 35.1.92 225.72 231.. 62 239.55 1.61382 0.1*50 1 i*65 181.6 135. 318 321*. 352 17. 197 0.05815 30.861 H.8.69 21.1.83 21.7.00 1.63696 0.1*57 1 758 1628

135. 318 321*. 352 3.8905 0. 2570 3.8781 1.5.72 326.80 351.65 1.95961. 0.1*93 1 798 879

130. 000 329.670 3.5i*10 0.2821* 3.3600 61.. 10 331.. 61 359.72 1.981.32 0.1*63 1 321 920 120.000 339.670 3.1392 0. 3186 2.8266 89.36 31*2.78 371.10 2. 01835 0.1*38 1 09 976 110.000 31*9.670 2.8716 0. 31.82 2.1.998 109.1.2 31*9. 1*9 380.1.1. 2. 01.51.7 0.i*25 0. 971. 1020

100. 000 359.670 2.6699 0. 371.5 2.2668 126.72 355.1*7 388.76 2.06891. 0.1*17 796 1058 -90.000 369.670 2.5081 0. 3987 2.0878 11.2. 25 361.01 396.1.5 2. 09003 0.1*12 7<»5 1092 -80.000 379.670 2. 3733 0. 1*211. 1.91*37 156.53 366.26 1*03.71 2. 1091.2 0.1*08 709 1123

-7 0.0 00 389.670 2.2579 0. 1.1.29 1.821.(1 169.87 371. 30 1*10.66 2.1271.9 0. 1*05 0. 682 1151 -60.0 00 399.670 2.1573 0.1.636 1.7223 182.1.8 376.18 1*17.38 2. 11*1.51 0.1*03 662 1178 -50.000 "09.670 2.0682 0.1.835 1 .63**<* 19i*. 1*8 380.91- 423.91 2.16065 0.1*02 61.5 1203

-t.0.000 i*19.670 1.9886 0.5029 1.5572 206. CO 385. 6C 1*30.30 2.17605 0.1*01 633 1227 -30.000 1*29.670 1. 9166 0.5218 1.1*887 217. 09 390. 19 1*36.57 2.19082 0. 1*01 622 121.9 -20.000 1*39.670 1.8510 0.51.02 1.1*271. 227. 81. 391.. 73 1.1.2.75 2. 20503 0.1*01 611. 1271 -10.000 i* i*9. 670 1.7910 0.5581. 1.37 2 238. 27 399.22 1.1.8.85 2.21875 0.1*02 o07 1291 0.000 1*59.670 1.7356 0. 5762 1.3217 21.8.1.1. 1*03.66 •51.. 89 2.23203 0.1*02 601 1311 10.000 1*69.670 1.681*1* 0.5937 1.2756 258. 37 1*08. 11 1.60. 97 2. 21.1.92 .1*01* >;9 7 1330 20.000 1*79.670 1.6367 0.6110 1.2333 268.08 1*12.5? 1.66.82 2.2571.5 0.1.05 0. 593 131.9 30.000 i*89.670 1.5923 0.5280 1.191.1 277.61 1.16.92 i*72.7i* 2.26966 0.1.07 0. 590 1367

<*0. 000 1*99.670 1.5506 0.61.1.9 1.1579 286.97 1.21.31 •78.63 2.28157 0.1.08 586 1381* 50. 000 509.670 1. 5115 0.6616 1.121*1 296. 17 1.25. 7C i.8i*. 50 2.29321 0.1.10 587 11*00 60.000 519.670 1. i»7i»6 0.5781 1.0925 305.23 1*30.09 i*90.37 2. 301.60 0.1.13 586 11.17 70.000 529.670 1.1.398 0.691*5 1.0630 311.. 17 1*31*. 1*9 1*96.22 2.31576 0.1.15 585 11.33 80.000 539.670 t. **069 0.7108 1.0352 322.96 1*38.90 502.07 2.32671 0.1*18 585 1U1.8 100. 000 559.670 1. 3i*60 0. 71,29 0.981*1* 31.0. 30 1*1*7.76 513.79 2.31.802 0.1*21. 586 11.77 120.000 579.670 1.2909 0.771*7 0.9390 357.21. 1.56.69 525.51. 2.36866 0.1*30 589 15C6

11.0.000 599.670 1.21*05 0.8061 0.8980 373.86 1*65.71 537.35 2.38869 0.1*37 592 1533 160.000 619.670 1.1946 0. 9371 0.8609 390.2(1 <*7(*. A<» 51.9.25 2. 1*0 820 0. i*i.i« 597 1559

180. 000 639. 670 1.1522 0.8679 0.8270 1.06. 30 i*8i*. 09 561.21. ?. 1.2721. 0.1*52 602 1581. 200.000 659.670 1.1130 0. 3985 0.7959 1.22. 17 1*93. i*P 573.31. 2. 1*1*587 0.1.60 608 1608 220.000 679.670 1.0767 0.9288 0.7673 1.37. 85 503.01 585.57 2. 1.61*13 0.1.69 615 1631

21*0.000 699.670 1. 01*28 0.9589 0.71*09 1.53.36 512.69 597.93 2.1.8205 0.1.77 0. 622 1651. 280. 000 739.670 0.9816 1.0187 0.6935 1.83.91 532. 5i< 623.09 2.51702 0.1.95 637 1697 320.000 779.670 0.9277 1. 3779 0.6522 513.95 553.07 61.8.88 2.55097 0.511. 0. <S53 1739 360.000 819.670 0.6 79 7 1. 1367 0.6159 51.3.56 57i». 30 675.33 2.581*05 0.533 0, o70 1779

1*00.000 859.670 0.8368 1. 1951 0.5836 572. 81 596.21. 702.1.7 2.61638 0.552 0. 687 1818

1*1.0. 000 399.670 0.7980 1.2531 0.55i*7 601.75 618.92 730.30 2.61*8 02 0.571 705 1855

238
METHANE ISOBAR AT P 520.0 PSI

T T DEN VOL CP/OT DP/DO F H S cv CP W DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 3TU/L6 8TU/LB BTU/L8/R BTU/LB/R BTU/L i/R FT/S

294,,802 164.868 28.261 0.03538 166.059 3690.71 93,. 4C 96,.81 1,, 01346 0,. 4°7 0.,783 5189

290,,000 169.67 28.040 0.03566 160.653 3546.00 96,.99 100,,42 1,,03613 .496 0,, ^86 5106

28 G,, 000 179.670 27.583 0.03625 149.911 3253.48 104,,61 108,,10 1,, 08150 ,497 0,,799 4923

27 0,,000 189.670 27.113 0. 03688 139.762 2967.77 112.,46 116,,01 1,.12513 .498 0,,312 4736

260,,000 199.670 26.641 0. 03754 130. 154 2691. 85 120,,49 124,,11 1., 16719 0,.497 0,,324 4550

25 0,,000 209.670 26.150 0.03824 121.029 2427.56 128,,67 132,,36 1,,20773 .492 0,, 335 4368

240,,000 219.670 25.643 0. 03900 112.332 2175.94 136,,97 140,,73 1,,24685 0,,4 86 0,,345 4186

230,,000 229.670 25. 116 0.03981 104. 010 1937.28 145,,38 149 ,22 1,,28469 0,.480 0,,356 4003

220,,000 239.670 24.568 0. 04070 96.014 1711. 36 153.,92 157,,84 1.,32148 .475 0,,371 3814

210,,000 249.670 23.993 0. 04168 88.296 1497.53 162,,63 166,,64 1,,35744 .472 0,,390 3618

200,,000 259.670 23.387 0.0+276 80.811 1294. 82 171,.54 175,,65 1,, 39283 .470 0,,914 3414

190,,000 269.670 22. 742 0.04397 73.508 1102. 12 180,.69 184,,93 1,,42787 .469 0,,942 3204

180, 000 279.670 22. 049 0. 04535 66. 331 918. 26 190,,15 194,.51 1,,46276 .465 0,,976 2987

170,,000 289.670 21.291 0. 04697 59.205 742. 13 199,,95 204,,47 1,,49774 ,458 1,,017 2762

160,,000 299.670 20.442 0.04692 52.022 572.76 210 , ,21 214,,92 1,,53319 , 449 1,, 76 2523

150.,000 309.670 19.451 0.05141 44.600 409.28 221,, 18 226,,13 1,,56999 , 440 1,. 177 2251

140. 000 319.670 18.203 0- 05494 36. 541 250.42 233,,57 238,,86 1,,61040 . 448 1,,+0 1905

130,,893 328.777 16.488 0. 06065 27.469 104.80 248,, 04 253,,se 1,,65663 ,465 2,,078 1472

130. 893 328.777 4.4147 0.2265 4.5459 36. 21 326,, 10 347,,91 1,,94272 ,511 2,, 293 868

130,,000 329.670 4.3103 0. 2320 4.3783 40. 43 327, 51 349.,85 1,,94860 o,.500 2,, 058 878

120.,000 339.670 3.6315 0.2754 3.3984 73.38 338,,37 364,,88 1,,99359 0,.452 1,, 203 951

110.,000 349.670 3.2602 0. 3067 2.9229 96.57 346,, 07 375,,60 2,,02471 0,.434 0,,973 1002

100. 000 359.670 3.0000 0. 3333 2.6103 1 15.78 352,,61 384,,71 2., 05039 0,,423 0,, 359 1043

-90.,000 369.670 2.7 99 2 0. 3572 2. 3804 132. 65 358.,52 392. 92 2. 07293 ,416 0,,789 1080

-80.,000 379.670 2.6361 0. 3794 2.2005 147.95 364, 04 00,.57 2., 09334 0,,411 0,,743 1112

-70.,000 389.670 2.4989 0.4002 2.0540 162. 10 369,,26 407.,82 2., 11 218 0,,408 0,,709 1142

-60.,000 399.670 2. 3808 0. 4200 1.9313 175.37 374,,33 414,,77 2,,12981 ,406 0,,633 1170

-50. 000 409. 670 2. 2774 0.4391 1.8265 187.95 379. 22 421,,50 2

,

,14644 0,, 404 0,,66 4 1196

-4 0.,000 419.670 2. 1856 0. 4575 1.7353 199.95 384, OC + 28.,06 2., 16226 0,, 403 0, 648 1220

-30. 000 429.670 2. 1032 0.4755 1.6551 211.48 388,,7C 434,,48 2. 17 73 7 0,,403 0,,o36 124 + -20. 000 439. 670 2.0287 0.+929 1.5836 222. 61 393,, 32 440,,78 2,,191 87 0,,403 0. 326 1266

-10. 000 449.670 1. 9606 0. 5100 1.5195 233.39 397,,86 446,,99 2,,20584 0,,403 0.,617 1287

0. 000 459.670 1.8982 0. 5 26 8 1.4614 243. 87 402,,40 + 53,,13 2. 21934 0,,404 0, oil 1307

10. 000 469.670 1. 8405 0. 5433 1.4086 254. 06 406,,89 + 59,,21 2,,23243 0,, 405 0, 305 132 7 20.,000 479.670 1.7871 0. 5596 1.3601 264.06 411,,36 465.,2*. 2. 24513 0., 406 0. 601 1346

30. 000 489.670 1.7374 0. 5756 1.3155 273.82 415,, 81 471,,23 2.,25749 0,,408 0.,597 1364

40. 000 "99.670 1.6909 0.5914 1.2743 283.40 420,,24 477. 19 2. 26954 , ,409 0,,595 1381

50. 000 509.670 1. 6*7 5 0.6070 1.2 36 292. 82 424. 68 483. 13 2, 28131 0,,411 0. 593 1398

60.,000 519.670 1.6064 0.6225 1.2004 302.07 429. 11 + 89. 05 2. 29281 o,.414 0. 591 1 + 15 70. 000 529.670 1.5678 0.6379 1.1670 311. 19 433,,54 494. 96 y 30408 0,,416 0. 591 1431

80. 000 539.670 1.5313 0.5530 1.1353 320. 17 437,,96 500,,66 2,,31512 , ,419 0. •>9 1446

100. 000 559.670 1.4640 0.5831 1.0787 337.80 4 46. 90 512. 67 2. 33660 , ,424 n,,591 147 6 120. 000 579.670 1.4032 0.7127 1.0278 355. 03 455. 88 52*.. 51 2. 35738 0,,431 3. 393 15C5

140. 000 599.670 1.3479 0. 7419 0.9821 371.90 464,,96 536, 39 2, 37754 0,,437 0. 596 1532

16 0. 000 619.670 1. 2973 0. 7708 0.9407 388. 47 474. 13 548. 35 2. 39715 0,,445 0. 600 1558

18G. 000 639.670 1. 2508 0. 7995 0.9031 404. 77 483,, 42 560.,40 2.,41629 , ,45 3 0.,605 1563

200. 000 659.670 1.2079 0. 3279 0.8686 420. 84 492. 84 572. 56 2. 43501 0. 461 0. oil 1608

220.,000 679.670 1. 1681 0. 3561 0.8369 436. 70 502. 41 584, 84 2. 45334 , ,469 0. 617 1631

240. 000 699.670 1. 1312 0.3e41 0.8076 1*52. 37 512. 12 597. 24 2. 47133 0,,473 0. 624 1654

280.,000 739.670 1. 064J 0. 9395 0.7553 483.21 532., 02 622.,49 2.,50641 0,,496 0. 639 1698

320. 000 779.670 1. 0055 0. 9945 0.7099 513.50 552. 59 648. 35 2. 54046 0,,514 0. 655 1740

360. 000 919.670 0.9533 1. 0490 .6699 543. 33 573. 86 674. 66 2. 57362 0,, 533 0. 571 1730

400. 000 859.670 0.9066 1. 1030 0.6345 572.77 595. 84 7C2. 05 2. 60601 0,, 552 0. 588 1819

44 0. 000 899.670 0.8645 1.1568 .6028 601.86 618. 55 729. 94 2. 63770 . ,571 a. "06 1856

239
METHANE ISOBAR AT P 560.0 PSI

T T DEN VOL DP/OT DP/OD E H S CV CP H DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/ie 8TU/LB BTU/LB/R BTU/LB/R BfU/LB/R FT/S

294.675 164.995 28.266 0.03538 165.988 3695. 86 93. 42 97.09 1.01364 0.497 0. 782 5190 290.000 169.670 28.051 0.03565 160.735 3555. 14 96. 9? 100.62 1. 03570 0.496 0. 786 5110

260. 000 179.670 27.596 0.03624 150.016 3263.48 104. 53 108.29 1. 03105 0.497 0. 798 4928 270.000 189.670 27.131 0.03636 139.889 2 978.50 112. 37 116.19 1. 12466 0.498 0. 81? 4741 260.000 199.670 26.656 0.0J752 130.301 2703.20 120. 40 124.29 1. 16668 0.497 0. 3?4 4556 250.000 209.670 26.166 0.03822 121. 198 2439.48 128 56 132.53 1.20719 0.493 0. 334 4375 240.000 219.670 25.661 0.0 5897 112.524 2188.36 136. 85 140.89 1.24627 0.486 0. 344 4194

230. 000 229.670 25.137 0.03978 104.225 1950. 20 145 ?4 149.37 1.28407 0.480 0. 855 4012 220.000 239.670 24.591 0.04067 96.255 1724. 80 153 76 157.98 1.32079 0.475 369 3824 210.000 249.670 24.023 0. 0*163 88.566 1511.52 16?. 44 166.76 1. 35663 0. 472 0. 388 3629 200.000 259.670 23.417 0.04270 81.114 1309.45 171 32 175.75 1. 39199 0.470 911 3427 190.000 269.670 22.773 0. 0*390 73.851 1117.47 180. 45 185.00 1.42692 0.469 1. 939 3219 180.000 279.670 22.092 0.04527 66.722 934.50 189. 85 194.54 1.46167 0.466 0. 971 3005 170.000 289.670 21.344 0.04685 59.661 759.46 199. 59 204.44 1.49645 0.459 1 Oil 2784 160.000 299.670 20.510 0.04876 52.569 591.50 209. 75 214.80 1.53160 0.449 1. 065 2550 150.000 309.670 19.546 0.05116 45.289 429.93 220. 56 225.86 1.56790 0. 440 1 156 2287 140.000 319.670 18.356 0.05448 37.505 274.03 232, 6? 238.27 1.60727 0.447 1 348 195 8 130. 000 329.670 16.622 0. 06016 28.238 120.90 247. 67 253.91 1.65541 0.461 1 919 1526 126.723 332.947 15.696 0.05371 24.128 67.97 254. 53 261.13 1.67 72 0.479 2. 3?2 1313 126.723 332.947 5.0354 0. 1986 5.3703 26.62 322 62 343.21 1.92377 0.535 3 .169 855 120.000 339.670 4.2551 0.2350 4.1698 55. 31 332. 86 357.23 1.96549 0.473 1 565 921 110.000 349.670 3.7065 0.2698 3.4309 82.91 342. 19 370.17 2.00307 0.444 1 113 961

100. 000 359.670 3.3635 0. 2973 3.0030 104.43 349. 50 J 8 . 3 3 2.03173 0.430 938 1028

-90. 000 369.670 3. 1125 0. 3213 2.7058 122. 82 355. 87 389.19 2.05604 0.421 842 1067 -80.000 379.670 2. 9147 0. 3431 2.4810 139.24 361 71 397.29 2.07766 0.415 a 781 1102 -70.000 389.670 2.7518 0. 3634 2.3020 154.27 367 1° -»04.87 2.09738 0.411 738 1133 -60.000 399.670 2.6137 0. 3826 2.1547 168.26 372. 4? 412.10 2.11568 0.408 707 1162 -50.000 409.670 2.4940 0.4010 2.0302 181.43 377 47 419.04 2.13285 0.406 ,683 1189 -40.000 419.670 2.3888 0.4186 1.9231 193. 95 382. 37 425.78 2.14910 0.405 565 1214 -30.000 429.670 2.2949 0.4357 1.8296 205.92 387 17 432.35 2. 16457 0.404 650 1238

-2 0.00 439.670 2.2105 0.4524 1.7469 217.44 391. 88 438.79 2.17939 .404 638 1261

-10. 000 449.670 2. 1338 0.4686 1.6730 228.57 396 5? *45.1? 2.19362 0.404 528 1283 0.000 459.670 2. 0637 0. 4846 1.6066 239. 37 401 12 451.36 2.20736 0.405 520 1304 10.000 469.670 1.9993 0.5002 1.5463 249. 87 405 67 457.53 2.22064 0.406 614 1323 20.000 479.670 1.9397 0.5155 1.4912 260. 11 410 19 463.65 2.23352 0.407 609 1343

30. 000 489.670 1.8844 0.5307 1.4407 270.12 414 69 469.72 2. 2460* 0.409 605 1361

40. 000 499.670 1. 8329 0.5456 1.3942 279.92 419 17 475.75 2.25 82 3 0.410 a 602 1379 50.000 509.670 1.7847 0.5603 1.3510 239.54 423 65 481.75 2.27013 0.412 599 1396 60.000 519.670 1.7395 0.5749 1.3110 298.99 428. 12 487.73 2.28175 0.414 597 1413 70.000 529.670 1.6969 0.5893 1.2736 308.29 432 59 493.70 2.29312 0.417 596 1429

80. 000 539.670 1.6568 0.6036 1.2386 317.44 437 06 499.65 2.30426 0.419 595 1445

100. 000 559.670 1.5823 0.5318 1.1750 335. 38 446. 04 511.56 2.32592 0.425 595 1475 120.000 579.670 1.5162 0.5595 1.1184 352.88 455 oe 523.47 2. 34684 0.431 .597 1504 140.000 599.670 1.4557 0.6869 1.0676 370. 01 464 20 535.43 2.3671? 0.438 399 1532

160. 000 619.670 1.4005 0.7140 1.0218 386.60 473 42 547.46 2.38685 0.445 603 1558

180. 000 639.670 1.3498 0.7408 0.9802 403.31 482 75 559.57 2.40608 0.453 608 1583 200.000 659.670 1.3031 0.7674 0.9422 419.57 492. 20 571.78 2.42488 0.461 613 1608 220.000 679.670 1.2599 0.7937 0.9073 435.60 501 8C 584.11 2.44329 0.470 619 1632 240.000 699.670 1.2197 0. 5199 0.8752 451.42 511 54 596.56 2.46134 0.478 626 1655 280.000 739.670 1.1472 0.3717 0.8178 482.56 531 49 621.89 2.49654 0.4 96 641 1699 320.000 779.670 1.0835 0. 9230 0.7680 513. 09 55? 11 647.82 2.53068 0.515 656 1741 360.000 819.670 1. 0270 0. 9737 0.7244 543. 13 573. 42 674.40 2.5639? 0.534 673 1781 400.000 859.670 0.9764 1.1241 0.6857 572.76 595 44 701.64 ?. 59637 0.553 690 1820 440.000 899.670 0.9309 1.1742 0.6512 602.04 618 ie 729.57 2.62813 0.571 707 1858

240
ME THANE ISOBAR AT P = 500.0 PSI

T T OEM VOL DP/DT OP/OD F H S CM CP W OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB 3TU/Le PTU/LB/R BTU/IB/R eTU/L9/R FT/S

29 *. 5*9 165.121 28.272 0.03537 165.917 3700.99 93 1*5 97.38 1.01361 0.1.98 0.782 5192

290. 000 169.670 28.063 0.03563 160.817 3561*. 21* 96 85 100.81 1.03528 0.1.96 0.786 5113 280.000 179.670 2 7.603 0.03622 150.121 3273.1*1* 101* i*E 108.1*8 1. 08060 0. 1*97 3.796 1*932 270. 000 189.670 27.11*5 0.03681* 11*0.011* 2989. 18 112 26 116.38 I.IZhIS 0.499 0.811 i*7h7 260.000 199.670 26.670 0.0371*9 130. 1*1.8 2711*. 52 120 30 121*. 1*6 1.16618 0.1.97 0.823 1*563 250.000 209.670 26.183 0.03819 121.366 2U51.35 128 1*5 132.70 1.20666 0.1*93 0.333 1*382 21*0.000 219.670 25.679 0.03891. 112.71"* 2200.75 136. 72 1*1.05 1.21*569 0.1*87 0.31*3 *2C2 230.000 229.670 25.158 0.03975 101*. 439 1963.08 1*5 10 1h9.52 1.2831*1* 0.1*80 0. 851* 1.021 220.0 00 239.670 2i*. 61i» 0.01*063 96.1*91* 1738. 17 153, 60 158.12 1.32011 0.1*75 0. 868 383* 210.000 21*9.670 21*. 01*6 0.01*159 88.833 1525.1.3 162 26 166.88 1.35591. 0.1*72 0.886 36*1 200.000 259.670 23.1*1*3 0.0*265 81. i*li* 1323.97 171. 11 175.85 1. 39116 0.1.71 0.909 3**1 190.000 269.670 22.811* 0.01*383 71*. 189 1132.71 180 20 185.07 1.1*2599 0.1*69 0.936 323*

160. 000 279.670 22.131* 0.0*518 67.108 950.59 189. 56 19h. 58 1.1.6060 0.1*66 0.967 3023 170.000 289.670 21.396 0. 01*671* 60.107 776.60 199 23 201*. 1*2 1.1*9518 0.1*59 1. 001* 2806 160.000 299.670 20.577 0. 01*860 53. 100 609.95 209 30 21i*. 70 1. 53006 0.<*l*9 1.055 2577 150.000 309.670 19.637 0.05092 1*5.950 i*50. 11 219 96 225.62 1.56590 0.1*1*0 1. 137 2322

1*0. 000 319.670 18.1*96 0.051*07 36.1*00 296.77 231. 7* 237.71* 1.60437 0.1*1*6 1. 305 2007 130.000 329.670 16.920 0.05910 25.775 1<*8. 85 21*5. 91 252.1*8 1. 6..971. 0.1.56 1.726 1615 122.783 336. 887 11*. 760 0.06775 20.750 37.73 261 6? 269.15 1.69969 0.503 3.771 11*5 122.783 336.887 5.8136 0.1720 6.1*1*67 17. 11* 317 95 337.06 1.90132 0.572 5.0*7 837 120.000 339.670 5. 161*1 0.1936 5.3851 33.61* 325 OC 31*6.51 1.92927 0.510 2.51*3 882 110.000 31*9.670 I*. 2367 0.2360 *.0632 68. 26 337. 66 363.88 1.97973 0.1.57 1. 330 959 100.000 359.670 3.7693 0.2653 3.1*587 92.62 31.6 oe 375.53 2.01261 0.1*38 1 . 1* 3 1011

-90. 000 369.670 3.1*522 0.2897 3.0701* 112.77 353 03 385.21 2.03917 0.1*27 0.907 105* -80.000 379.670 3.2111* 0.3111* 2.7887 130.1*2 359. 25 393.85 2.06222 0.1*19 0.326 1091

-70. 000 389.670 3.0179 0. 3311* 2.5703 11*6. 39 365. 01 401.8? 2. 08295 0.1*11* 0.772 112* -60.000 399.670 2.8566 0.3501 2.3936 161. 13 370 1*5 1*09.31* 2.10200 0.1*11 0.731. 115* -50.000 1*09.670 2.7186 0. 3678 2.21*65 171*. 93 375 66 1*16.53 2.11976 0.1*09 0.705 1162

-1*0. 000 1*19.670 2.5982 0. 381*9 2.1212 187.98 380 7 1*23.1*6 2. 1361.3 0.1*07 0.683 1208 -30.000 i*29.67C 2.1*913 0.1*013 2.0127 200. 1.1 385. 61 1*30.19 2.15231. 0.1*06 0.665 1233 -20.000 1*39.670 2.3966 0.1*173 1.9175 212. 31* 390 1*1 1.36.77 2.1671*8 0. 1*06 0.o51 1257 -10.000 1*1*9.670 2. 3106 0.t328 1.8330 223. 82 395. 1* Hl.3.23 2.18200 0.i*06 0.6i*0 1279 0.000 1*59.670 2.2321* 0.1*1*79 1.7572 23".. 91* 399. 81 1*1*9.58 2.19597 0.hC6 0.631 13(10 10. 000 i*69.670 2. 1607 0. 1*628 1.6888 21*5.73 i»0h 1*3 55.85 2.2091.6 0.1*07 0.523 1320 20.000 1*79.670 2.091*7 0.1*771* 1.6266 256.21. 1*09 01 1.62.05 2.22253 .1.09 0.517 13*0 30.000 1*89.670 2. 0335 0.-*918 1.5698 266. 1*9 1*13 56 "+66.20 2.23521 .1* 1 0.612 1359

1*0. 000 1*99.670 1.9767 0.5059 1.5175 276.52 i»l« 09 1*71*. 30 2.21*755 0.1*11 0.608 1377 50.000 509.670 1.9236 0.5199 1.1*692 286. 31* 1*22. 61 1*60.37 2.25957 0.1*13 0.605 139* 60.000 519.670 1.8739 0.5336 l.i«2i*i* 295.99 1*27. 12 1*86.1.1 2.27131 0.1*15 0.603 1*11

70. 000 529.670 1.8273 0.51*73 1.3828 305.1*6 1*31 63 1*92.1*3 2.?6?79 0.1*18 0.601 1*28 80.000 539.670 1.7833 0.5608 1.31*39 31i*. 79 1*36. 11. <*98.itl. 2. 291*03 0.1*20 0.600 1*** 100.000 559.670 1.7025 0.5871. 1.2732 333. 01. i»i*5 16 510.HH 2. 31586 0.1*26 0.600 1*7* 120.000 579.670 1.6299 0. 5135 1.2106 350.81 i*5h 27 522.1*1* 2.33693 0.1*32 O.oOl 150*

11*0. 000 599.670 1.561*1 0.6393 1.15U6 368.18 i*63. 1*1* 531*. 1*7 2.35731* .1*39 0.603 1531

160. 000 619.670 1.501*1 0.661*8 1.101*? 385. 20 1*7?. 70 51*6.57 2.37717 0.1*1.6 0.606 1558 180.000 639.670 1. 1.1*92 0.5900 1.0585 1.01.91 1*82. 07 558.71. 2. 39650 0. i»5i« 0.611 1581* 200.000 659.670 1.3986 0.7150 1.0169 1.18.35 i*91 56 571.00 2.1.1538 0.1*62 0.616 1608

22 0. 000 679.670 1.3513 0.7398 0.9787 1.31*. 55 501 19 583.38 2.1*3387 0.1.70 0.62? 1632

21*0. 000 699.670 1.3081* 0. 761*3 0.91*35 1.50.51. 510 96 595.86 2.1*5199 0.1.79 0.o2P 1655 280.000 739.670 1.2301 0. 3129 0. 8809 1.81.95 530 97 621.29 2.1.6731 .1.97 0.61*2 1699 320.000 779.670 1.1615 0. 3610 0.8267 512.72 551 63 61.7.29 2.5215m 0.515 0.658 171.2 360.000 819.670 1. 1006 0. 9086 0.7793 5*2.98 57?. 99 573.93 2.551.86 0.53* 0.571. 1782

1.00.000 859.670 1.01*63 0. 3558 0.7373 572.79 595, 01. 701.23 2.58737 0.553 0.691 1821

1*1*0. CO 899.670 0.9973 1. 1027 0.6999 602.23 617. 81 7?9.?1 2.61918 0.572 0. 706 1859

241
METHANE ISOBAR AT P = 650.0 PSI

T T OEM VOL OP/OT OP/DD E H S CV CP H DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 9TU/LP QTU/LB BTU/LB/R BTU/LB/R BTU/L3/R FT/S

294. 392 165. 278 28.278 0.03536 165.829 3707. 39 93. 48 97.74 1. 01402 0.498 0. 782 5193

290. 000 169. 670 28.077 0.03562 160.918 3575.56 96. 76 101.05 1.03475 0.497 0.785 5118

280. 000 179. 670 27.623 0.03620 150.250 3285. 84 104. 35 108.71 1.08005 0.498 0.797 4938

270. 000 189. 670 27.161 0.03682 140.170 3002.49 112. 17 116.60 1.12360 0.499 0.311 4753

260. 000 199. 670 26.689 0. 03747 130.630 2728. 61 120. 18 124.69 1. 16556 0. 498 0.822 4570

25 0. 000 209. 670 26.203 0.03816 121.575 2466. 15 128. 32 132.91 1.20599 Q.493 0.332 4390

21*0. 000 219. 670 25.702 0.03891 112.949 2216.16 136. 57 141.25 1.24498 0.4 87 1.342 4212

230. 000 229. 670 25.183 0.03971 104.703 1979.10 144, 93 149.71 1.28267 0.481 0.852 4032

220. 000 239. 670 24.643 0.0*058 96.789 1754. 81 153. 41 158.29 1. 31926 0.476 0.366 3847

210. 000 249. 670 24.078 0.04153 89.164 1542.73 162. 04 167.03 1.35501 0.473 3. 384 3655

200. 000 259. 670 23.485 0.04258 81.783 1342.01 170. 85 175.98 1.39013 0.471 0.906 3457

190. 000 269. 670 22.857 0.04375 74.605 1151. 6C 179. 9C 185.16 1.42483 0.470 0.932 3253

180. 000 279. 670 22. 186 0.04507 67.580 970.50 189 20 194.63 1.45927 . 466 0.961 3045

170. 000 289. 670 21.460 0.04660 60.653 797.75 196. 80 204.41 1.49364 0.459 3. 996 2832

160. 000 299. 670 20.657 0.04841 53.744 632.63 208. 76 214.59 1.52819 0. 449 1.043 2609

150. 000 309. 670 19.745 0.05064 46.741 474.76 219 26 225.35 1.56351 0.440 1.116 2363

1A0. 003 319. 670 18.657 0.05360 39.441 324. 15 230 71 237.17 1.60101 0.444 1.261 2064

130. 000 329. 670 17.223 0. 05806 31.394 180.92 244 09 251.08 1.64383 0.452 1.573 1708

120. 000 339. 670 14.573 0.06862 20.469 40.82 264. 04 272.30 1.70713 0.499 3.538 1158

118. 163 31*1. 507 13.052 0. 0*662 16.013 8.41 273. 17 282. 39 1.73674 0.585 11. 907 890

118. 163 341. 507 7.3075 0. 1368 8.5906 5.28 308 ki 324.91 1.86128 0.682 17. 234 786

110. 000 31*9. 670 5. 1007 0. 1961 5.1507 48.30 330 46 354.06 1.94593 0.480 1. 347 928

100. 000 359. 670 4.3597 0. 3294 4.1491 77.25 341 16 3 6 8.77 1.98746 0.449 1.230 990

-90. 000 369. 670 3. 9229 0. 2549 3.5947 99. 69 349. 15 379.83 2. 01781 0.434 1. no 1037

-8 0. 000 379. 670 3.6122 0.2768 3.2184 IIP. 23 355 98 389.30 2.04307 0.425 3.393 1077

-7 0. 000 389. 67 3. 3716 0. 3966 2.9378 136.47 362. 14 397.84 2.06528 0.419 3.820 1113

-60. 000 399. 670 3. 1758 3. 3149 2.7168 152.21 367 88 •05.78 2. 08540 0.415 0. 7 70 1145

-50. 000 "09. 670 3. 0112 0. 3321 2.5361 166. 82 373. 32 •13.29 2. 10397 0.412 3.734 1174

-1.0. 000 419. 670 2.8696 0. 5485 2.3845 180.56 378. 55 4 2 0.49 2. 12133 0.410 3. 737 1201

-30. 000 29. 670 2.7457 0. 3642 2.2546 193.59 383 61 4 27.45 2.13771 0.408 0.636 1227

-20. 000 "39. 670 2.6357 0. 3794 2.1417 206. C3 388 55 434.21 2. 15329 0.4C8 0.669 1251

-10. coo 449. 670 2. 5370 3. 3942 2.0422 217.97 393 39 440.83 2.16817 0.408 3. i55 1274

0. 000 459. 670 2.4477 0. *085 1.9536 229.50 398 15 447.33 2. 18245 0.403 8.644 1296

10. 000 469. 670 2. 3663 3. *226 1.8741 240.66 402 8f 453.72 2. 19622 0.409 0.335 1317

20. 000 479. 670 2.2916 3.4364 1.8022 251.50 407 51 460.04 2.20952 0.410 3.628 1337

30. 000 489. 67 2. 2227 0.4499 1.7366 262.06 412 14 466.29 2. 22242 0.411 3.622 1356

40. 000 499. 670 2. 1589 0.4632 1.6766 272. 37 416 73 472.48 2.23494 3.412 3.617 1374

50. 000 509. 670 2. 099* 0.*763 1.6214 282.45 421 3C -»78.64 2.24714 0.414 0.314 1392

60. 000 519. 670 2.0*39 0.*893 1.5703 292. 34 425 87 484.76 2. 25903 0.416 3.311 14C9

70 000 529. 670 1.9919 0.5020 1.5229 302. 04 430 42 490.85 2.27064 0.419 3. 308 1426

80 000 539 670 1.9430 0.5147 1.4783 311.58 434 98 496.92 2.282C1 .421 0.607 1442

100 000 559 670 1.8533 0.5396 1.3989 330.20 444 10 509.04 2. 30405 0.426 0.605' 1474

120. 000 579 670 1.7729 0. 5640 1.3283 348. 32 453 26 521.15 2. 32531 0.433 O.3O6 1503

140 000 599 670 1.7003 0.5881 1.2655 365. °9 462 49 533.28 2.34588 0.439 0.507 1531

160. 000 619 670 1.6343 3.5119 1.2090 383.29 471 8C 545.45 2.36585 0.447 0.510 1558

180 000 639 670 1.5739 3.6354 1.1580 400.25 481 22 557.70 2.38530 0.454 0.61*1 1584

200. 000 659 670 1. 5183 3. 5586 1.1115 416. 92 490 7t 570.04 2. 40429 0.462 0.619 1609

220 000 679 670 1.4670 0.6817 1.0691 433.33 500 43 582.48 2.42287 0.471 3.625 1633

240. 000 699 67 1. 4195 3. '045 1.0300 449.50 510 24 595.03 2.44108 0.479 3.331 1656

280, 000 739 670 1.3339 0. 7497 0.9607 481.26 530 32 620.55 2.47653 .497 0.645 17C3

320. 000 779 670 1. 2590 3. 7943 0.9008 512. 33 551 04 646.64 2.51083 0.516 0.660 1743

360 000 819 670 1. 1927 0.8384 0.8485 542.84 572 44 573.35 2.544 30 0.535 9.576 1783

"•00 000 859 67 1. 1335 3. 3822 0.8023 572. 87 594 54 700.73 2.57689 0.553 0.693 1823

MtO. 000 899 670 1. 0803 3.9256 0.7612 602.51 617 35 728.76 2.60877 0.572 0.709 1860

242
METHANE ISOBAR AT P 700.0 PSI

T T DEN VOL DP/OT DP/DO E H S CV CP W DEG F OEG R LB/CUFT CUFT/L8 PSI/R PSICUFT/LB BTU/LB 3TU/LB 9TU/LR/R BTU/LB/R BTU/L3/R FT/S

29*. 231* 165. *36 28.285 0.03535 165.7*1 3713.76 93.51 98.09 1.01*2* 0.*98 0. 782 5195

290. 000 169.670 28.091 0.03560 161.018 3586. 82 96.67 101.29 1. 03*22 0. 1*97 0. 785 5122

280. 000 179.670 27.638 0.03618 150.378 3298.16 10*. 26 108.95 1.079*9 0.1*98 797 1*944 270, 000 189.670 27.178 0.03679 li»0. 325 3015.75 112.07 116.63 1.12301 0.500 3 810 1*760 260, 000 199.670 26.707 0. 0371*1* 130.811 27*2. 61* 120.06 12*. 91 1.16*9* 0.*98 322 *578

250. 000 209.670 26.223 0.03813 121.781 21*80. 67 128. 16 133.13 1. 20533 0. *9* 0. 331 *399

21*0. 000 219.670 25.721* 0.03887 113.183 2231.51 136.1*2 1*1.*6 1.2**27 0.*87 343 1*222 230. 000 229.670 25.208 0.03967 IOh. 965 1995. 05 1**.76 1*9.90 1.28190 0.*81 851 1*0*3 220. 000 239.670 2*. 671 0.01*053 97.082 1771.36 153.21 158.47 1.31643 0.*76 864 3859

210. 000 2*9.670 2*. Ill 0.01*11*8 89.1*90 1559.92 161.81 167.19 1.35*09 0.1.73 991 3669

200. 000 259.670 23.522 0.01*251 82.11*8 1359.91 170.60 176.11 1.38911 0.*72 933 3*73

190. 000 269.670 22.900 0. 0*367 75.01* 1170.33 179.60 185.26 l.*2369 .1*70 928 3272

180. 000 279.670 22.237 0.01*1*97 68.01*1* 990.20 188. 85 19*. 68 l.*5798 0.*66 956 3066

170. 000 289.670 21.521 0. 0i*6i*7 61.1B5 618.61 198. 38 20*. *0 l.*9213 0.*59 989 2857

160. 000 299.670 20.735 0.01*823 51*. 368 65*. 92 208. 21. 21*. *9 1.52637 0.**9 1. 332 26*0

150. 000 309.670 19.81*3 0.03038 1*7.1*96 1.98. 83 218.58 225.11 1.56122 0.1**0 1 J 9 6 2*03

1A0. 000 319.670 18.805 0.05318 1*0.1*11 350.55 229.77 236.66 1.59769 0.*** 1 22 3 2116

130. 000 329. 670 17.1*79 0. 05721 32.793 210.81* 2*2.53 2*9.95 1.63879 0.4*9 1 <*68 1788

12 0. 000 339.670 15.1*13 0.06h86 23.659 80.22 259. 3C 267.71 1.69181 0.*73 2 "519 1350

110. 000 3*9.670 6.481 0.151*30 6.988 25.91* 319.*9 339. *9 1. 89962 0.522 3 23 868

100. 000 359.670 5.06'* 0.19669 5.037 61.33 335.31 360. 8C 1. 95962 0.*6* 1 529 968

-90. 000 369.670 ".1*59 0.22H21* it. 217 86.79 3**. 81 373.88 1.99571 0. **3 1 148 1021

-80. 000 379.670 *.053 0.21*675 3.708 107.95 352.*3 38*. *1 2.02383 0.*31 376 106*

-70. 000 389.670 3.752 0.26652 3.3h7 126. 52 359.09 393.6* 2.0*783 0.1*23 977 1102

-60. 000 399.670 3.51* 0.29H55 3.070 1*3. 30 365. 16 *02.07 2.06918 0. *18 312 1136

-50. 000 UQ9.670 3.318 0. 33135 2.81*9 158.76 370.89 *09.95 2.08867 0.*15 767 1166

-i*0. 000 i»19.670 3.152 0.31722 2.666 173. 20 376.33 *17.*5 2.1067* 0.1*12 73 3 1195

-30. 000 1*29.670 3. 009 0.33238 2.512 186. 81. 381.56 *2*.6* 2.12370 0.*11 3 737 1221

-20. 000 1*39.670 2.882 0.31*697 2.379 199. 81 386.6* 1*31.61 2.13973 o.*io n 667 12*6

-10. 000 i*i*9.670 2.769 0.36108 2.262 212. 22 391.60 *38.*0 2.15500 0.1*09 3 671 1270

0. 000 59.670 2.668 0.37H79 2.159 ??<*. 16 396.1.7 **5.05 2.1696? 0.*10 0. 658 1292

10. 000 i*69.670 2.576 0. 39816 2.068 235. f

9

*01.26 *51.58 2.18367 .* 10 c*P 1313

20. 000 1*79.670 2.1*92 0. i*312i* 1.985 2h6. 67 *06. 00 *58.01 2. 19722 0.*11 3 639 1334

30. 000 1*89.670 2.1*15 0.1*11*06 1.910 257.7* *10.69 *6*.36 2.21033 0.*12 632 1353

*0. 000 1*99.670 2.31*1* 0.1*2665 1 .8*1 268. 33 *15.35 *70.66 2.22305 .*1* 626 1372

50. 000 509.670 2.278 0.1*3905 1.779 278.67 *19.9? *76.90 2.235*2 0.*15 0. 622 1390

60. 000 519.670 2.216 0.V5127 1.721 288. 80 1*21*. 6C *63.10 2.2*7*7 0.417 3. 618 1*08

70. 000 529.670 2.158 0.46332 1.667 298.73 *29.21 *89.26 2. 25922 0.*20 615 1*25

80. 000 539.670 2.101* 0.1*7523 1.617 308. *7 *33.81 *95.*1 2.27071 0.1.22 0. 613 1**1

100. 000 559.670 2.005 0.1*1867 1.528 32''. *8 **3.01 507.65 2.29298 0.*27 0. 611 1*73

120. 000 579.670 1.917 0.52166 1.1*1*9 3*5.93 *52.2* 519.86 2.31**2 0.*33 3. 611 1503

1*0. 000 599.670 1.837 0.51*1*27 1.379 363.91 *61.53 532.08 2.33515 0.4*0 612 1531

160. 000 619.670 1.765 0.56656 1.316 381. *7 1*70.91 5**. 3* 2. 35526 0.**7 3. 61* 1558

180. 000 639.670 1.699 0.59857 1.259 398.68 *8C.3P 556.67 2. 37*e* 0.1*55 0. ol8 1561. 200. 000 659.670 1.638 0.61031* 1.208 *15.57 469.96 569.07 2.39393 0.*63 0. 623 1609

220. 000 679.670 1.583 0.63189 1.161 1*32. 19 1*99.67 581.58 2.*1260 0.* 7 1 0. 628 1633

2*0, 000 699.670 1.531 0.65321* 1.118 **8. 55 509.52 59*. IS 2. *3090 0.1.60 0. 63* 1657

280. 000 739.670 1 . i* 3 8 0.6951*5 I.OhI 1*80. 6* 529.66 619.81 2.*6650 0.498 3. 6*7 1702

32 0. 000 779.670 1.357 0.73711 0.976 512. CO 550.** 6*5.99 2.50096 0.516 o62 17*1* 36 0. 000 919.670 1.285 0.77831 0.918 5*2.76 571. 9C 672.78 2.53**7 0.535 0. 678 1785

*00. 000 859.670 1.221 0.81912 0.868 573. 01 59*. 0* 700.22 2.56715 0.554 3 o9* 1821*

i.<<0. 000 899.670 1.163 0.85961 0. 823 602. 8* 616.90 728.32 2.59910 0.573 3. 711 1862

243
METHANE ISOBAR AT P = 750.0 PSI

T T OEN VOL OP/OT OP/OD F H S CM CP W DEG F OE& R LB/CUFT CUFT/L8 PSI/R PSICUFT/LB BTU/LB 9TU/L8 BTU/LB/R BTU/LB/R BTU/L3/R FT/S

294. 077 165.593 28.292 0. 03535 165.653 3720. 11 93.54 98.45 1.01446 0.499 0. 781 5196

290. 000 169.670 28.105 0. 03558 161.117 3598.03 96.59 101.53 1.03369 0.498 0. 785 5127

280. 000 179.670 27. 65"+ 0. 03616 150.505 3310.47 104. 16 109.18 1.07894 0.499 0. ^96 4949

27 0. 000 189.670 27. 195 0. 03677 140.479 3026.94 111.96 117.07 1.12243 0.500 0, 809 4766

26 0. 000 199.670 26.725 0. 03742 130.990 2756.62 119.94 125.13 1. 16432 0. 499 821 4585

250. 000 209.670 26. 2^3 0. 03810 121.986 2495.53 128.05 133.34 1.20467 0.494 330 4408

240. 000 219.670 25. 7i+7 0. 03884 113.414 2246.79 136.27 141.66 1.24356 0.488 839 4231

230. 000 229.670 25.233 0, 03963 105.224 2010.92 144.59 150.09 1.28113 0.482 849 4054

220. 000 239.670 2 V. 699 0> + 049 97. 371 1787. 83 153. 02 158.64 1. 31760 0.477 3 862 3871

210. 000 249.670 24.143 0. 04142 69.812 1577. 01 161.5° 167.35 1.35318 0.474 679 3683

200. 000 259,670 23.559 0. 0-.245 82.508 1377.69 17C. 35 176.24 1.38811 0.472 a 90 3489

190. 000 269.670 22.943 0. 04359 75.417 1188.90 179.31 185.36 1.42257 0.470 3 924 3290

180. 000 279.670 22.287 o. 04487 68.499 1009.69 186.51 194.74 1.45670 0.467 951 3088

170. 000 289.670 21.582 0. 04634 61.704 839.21 197.97 204.40 1.49065 0.460 982 2882

160. 000 299.670 20.810 0. 3 + 605 5 4.973 676.84 207.74 214.41 1.52461 0.449 1 321 2670

150. coo 309.670 19. 946 0. 05013 48.221 522.38 217.93 224.90 1.55903 0.439 1 081 2440

140. 000 319. 670 16.943 0. 05279 41.320 376. 13 228.89 236.2? 1.59496 0.443 1 192 2165

130. 000 329.670 17.701 0. 05649 34.042 239. 18 241.lt 249.01 1.63434 0.446 1 390 1858

120. 000 339.670 15.938 0. 05275 25.826 113.44 256. 30 265.01 1.68213 0.462 1 918 1477

110. 003 349.670 10.557 0. 01472 12.540 8.87 291.96 305.11 1.79794 0.56? 10 867 891

100. 000 359.670 6.029 0. 16585 6.245 45. 29 327.94 350.97 1.92783 0.48? 2 059 947

-90. 000 369.670 5. 084 0. 19670 4.969 73.72 339.88 367.20 1.97238 0.452 1 340 1006

-80. 000 379.670 4.542 22017 4.272 96.72 348.56 379.14 2. 00426 0.437 1 380 1052

-70. 000 389.670 4. 164 0. 24018 3.804 116.63 355.85 389.20 2.03043 0.428 945 1092

-60. 000 399. 670 3.875 o. 25810 3.458 134. 46 362.36 398.20 2. 05323 0.422 3 361 1127

-5 0. 000 409.670 3.642 0. 27460 3.188 150. 77 368. 37 •06.50 2.07375 0.416 903 1159

-1*0. 000 419.670 3.44 7 29008 2.969 165.94 374.04 414.32 2.09 261 0.415 762 1188

-30. 000 <«29.670 3.281 0. 33476 2.785 160. 18 379.46 421.78 2. line 0.413 3 731 1216

-20. 000 "39.670 3. 136 o. 31885 2.629 193.68 384.69 4?8.97 2.12672 0.412 707 1241

-10. 000 '+'9.670 3.003 33241 2.494 206.56 389. 7e 435.94 2. 14240 0.411 688 1266

0. 000 •59.670 2.894 0. 34556 2.375 218.92 394.76 •42.75 2.15736 0.411 t73 1289

10. o o a "69.670 2.791 3 5 834 2.269 230.83 399.6? 449.41 2. 17171 0.412 661 1310

20. 000 479.670 2.697 0. 37082 2.175 242.34 404.47 455.97 2. 18552 0.412 651 1331

30. 000 '89.670 2.611 38303 2.090 253.52 409.24 462.43 2.1988b 0.413 34 2 1351

1*0 000 '99.670 2.532 39502 2.012 264.40 413.96 468.62 2.21178 0.415 636 1370

50. 000 509.670 2.458 0. 43679 1.941 275.00 418.66 475.15 2. 22432 0. 416 630 1389

60. 000 519.670 2.390 41838 1.876 285. 37 423.33 481.43 2.23653 0.418 6?6 1407

70. 003 529.670 2.327 42981 1.816 295.52 427.99 487.68 2. 2+843 .420 o23 142h

80. 000 539.670 2.267 44109 1.760 305.48 432.63 493.89 2. 26005 0.423 .620 1441

100. 000 559.670 2.159 45325 1.660 324. 86 441.9? 506. ?5 2. 28254 0.428 Dl7 1472

120 000 579.670 2.062 43497 1.572 343.65 451.22 518.58 2.30417 0.4 34 3 616 1503

11*0 000 599.670 1.975 53630 1.494 361.92 460.58 530.89 2.32506 0.441 iie 1531

160, 000 619.670 1.896 52731 1.425 379.76 470.01 543.24 2.34532 0.448 6ie 1559

180 000 639.670 1. 825 54804 1.362 397. 21 479.53 555.64 2. 36501 0. 456 622 1585

200 000 659.670 1.759 .56852 1.305 414. 22 489. 16 568.11 2. 38421 0.463 626 1610

220. 000 679.670 1.698 53879 1.254 431. 14 498.91 580.68 2.40298 0.472 3 o31 1634

240 000 699.670 1.642 63866 1.207 447.69 508.80 593.35 2.42136 0.480 637 1658

260. 000 739.670 1.542 6-f851 1. 123 480. 10 529. 01 619.07 2.45710 .498 650 1703

320 000 779.670 1.454 .63760 1.051 511.74 549.85 645.34 2.49168 0.517 564 1746

360 000 819.670 1.377 72624 0.989 542.74 571.35 672.21 2.52529 0.535 660 1787

if 00 .000 859.670 1. 309 76449 0.934 573.21 593.55 699.72 2.55805 0.554 696 1826

44 000 899. 670 1.246 83242 0.885 603.22 616.44 727.88 2.59006 0.573 712 1864

244
METHANE ISOBAR AT P 300.0 PSI

T T OEN VOL OP/OT DP/DO F H S cv CP W OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LP 9TU/LB PTU/LP/R BTU/L8/R eTU/L'3/R FT/S

293.,919 165.751 28.299 0.03534 165.566 3726.43 93. 57 98.,81 1,, 01467 0.,499 3. 781 5198

290,.000 169.670 28.118 0.03556 161.216 3609. 18 96.,50 101,,77 1,,03317 0.,498 3,,784 5131

280.,000 179.670 27.669 0.03614 150.631 3322.70 104,, 06 109,,42 1,,07839 0,.499 3,,796 4954

270,,000 189.670 27.211 0.03675 140.631 3042.08 111.,85 117,,30 1,,12185 0,,500 0.,809 4773

260.,000 199.670 26.743 0. 03739 131.168 2770. 53 119. 82 125.,36 1,,16371 0,,499 0,,820 4593

250.,000 209.670 26.263 0.03808 122.189 2510. 12 127,,91 133,,56 1,,20401 0,,495 3, J29 4416

240,,000 219.670 25.769 0.03681 113.643 2262. 00 136., 12 141,,87 1,, 24285 0,,488 0,. 338 4241

230.,000 229.670 25.258 0.03959 105.481 2026.72 144,,42 150,,26 1,,28038 0,,482 0., 8*8 4064

220. 000 239.670 24. 727 0.04044 97.657 1804. 20 152. 83 158. 82 1,,31677 0,,477 3,,861 3884

210., 000 249.670 24.174 0.34137 90.131 1594.00 161,,36 167,,50 1,,35228 0,,474 0. J77 3 69 7 200,,000 259.670 23.595 0. 0*238 82.862 1395. 34 170., 10 176,,38 1,,38711 0,,472 0, 897 3504

190., 000 269.670 22.985 0.0*351 75.814 1207.31 179,,0? 185,,47 1,,42146 0,.471 0,,921 3308

180. 003 279.670 22.336 0.04477 68.946 1028. 99 188.,17 194,,80 1,,45545 0,, 467 0, 947 3108

170.,000 289.670 21.641 0.04621 62.212 659.55 197.,57 204, 41 1,,48920 0,,460 0,, 376 2906

160, 000 299.670 20.883 0.04789 55.560 698.42 207,,25 214,,34 1,,52290 0,, 450 1, 012 2699

150.,000 309.670 20.040 0.04990 48.917 545.44 217,,32 224,,71 1,,55692 0,, 439 1. 366 2476

14 0. 000 319.670 19.072 0. 03243 42. 180 400.99 228,,06 235,,82 1.,59220 , ,442 1,, 165 2211

130, 000 329.670 17.899 0.05587 35.176 266. 30 239.,93 248,,21 1,,63034 0,,445 1,, 330 1921

120. 000 339.670 16. 328 0.06125 27.561 143.71 254. OC 263,,07 1,,67472 0,,456 1., 703 1577

110..000 349.670 13.471 0.07423 18. 144 37.45 275.,16 286. 16 1.,7*159 0,, 497 3. 634 1126

100. 000 359.670 7. 385 0.13541 8.039 29.73 317,,96 3 38,,02 1,, 88793 0,,506 3., 161 928

-90. 000 369.670 5.828 0.17157 5.901 61. 11 334. ie 359,,60 1,,947 20 0,,46<t 1,,612 992

-80. 000 379.670 5.091 0. 19644 4.926 85.79 344,,32 373,,4? 1,, 98411 0,, 445 1

,

,212 1041

-70.,000 389.670 4.611 0.21686 4.317 106. °5 352. 38 364. 50 2

,

, 01?94 a,, 433 1. J25 ioe2

-60. 000 399.670 4.259 0.23480 3.885 125.79 359., 38 394,,16 2,,03742 , ,426 0.,916 1119

-50. 000 409.670 3.982 0.25112 3.556 142.93 365,,74 402, 94 2

,

, 05911 0,,421 3,,344 115?

-t*0, 000 •19.670 3.755 0.26629 3.293 158. 80 371. 67 411, 12 2

,

,07884 0,,418 , , '94 1183

-30. 000 429.670 3.564 0.28060 3. 077 173. 64 377. 29 418. 86 2,, 09708 0,,415 0. 757 1211

-2 0.,000 439.670 3.399 0.29424 2.894 187.67 382,,6° 426,,28 2,, 11415 0,,414 0.,726 1237

-10. 000 449.670 3.254 0. 30734 2.73 7 201. 02 387, 9? 433. 45 2,,13027 0,,413 3.,7 06 1262

0. 000 459.670 3.125 0.32000 2.601 213.79 393. 0? 440,,42 2,,14561 0,,*13 0,, S89 1285

10. 000 469.670 3. 010 0. 33228 2.480 226. 07 398. CI 447. 23 2. 16027 0,,413 0,,674 1306

20.,000 479.670 2.905 0.34424 2.373 237. °3 402. 92 453, 91 2,,17 4 34 0.,414 0. 553 1329

30. 000 489.670 2.810 0.35593 2.276 249. 41 407. 77 460. 49 2

,

,18792 0,,415 0. ^5 3 1349

40..000 499.670 2.722 0. 36737 2.183 260.57 41?.,56 466.,98 2,.201C4- a,,416 0,,d45 1369

50. 000 509.670 2. 641 0. 3^860 2.109 271. 44 417. 32 473. 41 2,,21377 3,,418 3, 639 1388

60..000 519.670 2.566 0.38965 2.036 282. 05 422,, 05 479. 77 2

,

,22613 , , 419 0, d34 1406

70.,000 529.670 2.497 0.40053 1.969 292.42 426. 76 4d6,.09 2,,23818 0,, 421 0, 63G 142 3 80. 000 539.670 2.432 0.41125 1.906 302.58 431. 45 492.,37 2,,24993 0,, 424 n t 627 1*40

100. 000 559.670 2.313 0.43231 1.795 322. 35 4-140 , 8? 504, 86 2,,27265 0,, 429 0. d23 1472

12 0..000 579.670 2.208 0.45291 1.698 341. 46 450. 2C 517. 29 2,,29448 , ,435 0. 621 150 3 140. 000 599.670 2.114 0.47312 1.61? 36 0. 3 459. 6? 529. 71 7 1, 31553 , , 1.41 3, S?l 1532

160. 000 619.670 2.028 0.49301 1.535 378. 1

3

•69. 1C 542. 14 2. 335"2 0. 449 0. o22 1559

180. 000 639.670 1.951 0.51262 1.467 395.62 478. 68 554. 61 2,,35574 0., 456 0. 625 1566

200, 000 659.670 1.883 0.53197 1.405 413. IE 488. 35 567. 16 2,,37505 0,,464 . 5 2 9 1611

220..000 679.670 1.815 0.55111 1.348 430. 17 496. 15 579. 79 p

,

39391 , ,472 0, o34 163 5 240.,000 699.670 1.754 0.57006 1.297 446. 9C soe. 07 592. 52 2. 41237 0. 461 3. 639 1659

280. 000 739.670 1.646 0.63746 1.206 479.64 528. 35 618, 34 2

,

,44825 0,,499 3. o5 2 1704

320. 000 779.670 1.552 0.64431 1.126 511.55 549. 25 644. 70 2. 48295 , ,517 3. 666 1747

360.,000 819.670 1.469 0.b3C70 1.060 542. 79 570. «1 671 . 65 2 t,51666 0,,536 3. 681 178e

400.,000 859.670 1.395 0.71671 1.000 ^73. 46 593. 05 699. 22 ? , 54950 0. 555 0. 697 1828

44 0.,000 399.670 1.329 0.75240 0.948 603.66 615,.98 727, 1*4 2 ,55158 0.,573 0. 714 1866

245
METHANE' IS08 AR I T P = 950.0 PSI

T T DEN VOL CP/OT DP/DD F H S CV CP W DEG DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/L8 8TU/l_e 3TU/LB 8TU/t_e/R BTU/LB/R BTU/LB/R FT/S

293. 762 165. 908 28. 305 03533 165.479 3732.74 93. 60 99.16 1.01489 0.499 0.781 5200

290. 000 169. 670 28. 132 0. 03555 161.313 3620.27 96. 41 102.01 1.03265 0.498 0.784 5136

280. 000 179. 670 27. 68-. 0. 03612 150.756 3334. 88 103. 97 1C9.65 1.07785 0.500 0.?95 4960

270. 000 189. 670 27. 227 0. 03673 140.782 3055. 17 111. 75 117.53 1.12128 0.501 0.808 4779

260. OOU 199. 670 26. 761 0. 5737 131. 344 2784.39 119. 70 125.58 1.16309 0.499 0. 319 4600

250. 000 209. 670 26. 283 0. 5805 122.391 2524.66 127, 76 133.77 1.20336 0.495 0.328 4425

240. 000 219. 670 25. 791 0. 03877 113.871 2277. 15 135 97 142.07 1.24216 0.489 0.837 4250

230. 000 229. 670 25. 282 0. 03955 105.736 2042. 44 144. 25 150.48 1. 27962 0.482 0. 947 4075

220. 000 239, 670 24 755 0. 04040 97.941 1820.50 15? 64 159.00 1.31596 0.477 0. 359 3896

210. 000 249. 670 24. 205 0. 04131 9C.446 1610.88 161. 16 167.66 1.35139 0.47«, 0.375 3710

200. 000 259 670 23 630 0. 04232 83.213 141?. 87 169 85 176.51 1.38613 0.473 0.395 3520

190. 269. 670 23. 026 0. 04343 76.205 1225. 58 178. 74 165.57 1.42036 0.471 0.916 3325

ISO. 000 279. 670 22 384 0. 04467 69.384 1048. 11 187. 84 194.67 1.45421 0.468 0.942 3128

170. 000 289. 670 21. 698 0. 04609 62.709 879.65 197, 16 204.43 1.48778 0.460 0.970 2930

160. 000 299 670 20, 953 0. 04773 56.132 719.66 206 77 214.26 1.52123 0.450 1.003 2727

150. 000 309. 670 20 130 0. 04968 49.589 568. 06 216 72 224.54 1.55489 0.439 1.052 2510

I<t0. 000 319. 670 19. 193 05210 42.995 425.22 227 27 235.47 1.58960 0.442 1. 141 2255

130. 000 329. 670 18 078 0. 05531 3F.222 292.41 238 81 247.52 1.62668 0. 443 1.282 1979

120. 000 339. 670 16 645 0, 06008 29.043 172. 10 252 1C 261.55 1.66861 0.452 1.564 1662

11C. 000 349. 670 14. 437 0. 06927 20.923 68.69 269 67 280.57 1.72371 0.476 2.456 1281

100. 000 359. 670 9 451 10581 10.926 22. 63 304 OF 320.71 1.83673 0.523 4. -.56 945

-90. 000 369. 670 6 738 14841 7.080 49.45 327 4e 350.64 1.91950 0.475 2.004 983

-80. 000 379. 670 5. 712 0. 17507 5.693 75.48 339, 63 367.18 1.96 3 16 0.452 1. 377 1032

-70. 000 389. 670 5. 100 0. 19606 4.896 97.69 346 66 379.52 1.99524 0.439 1. 119 1075

-60. 000 399. 670 4 673 21411 4.356 117.41 356 24 389.94 2.02167 0.4 30 0.978 1112

-50. 00 409 67 4, 342 0. 23032 3.955 135. 32 363. OC 399.25 2.C4468 0. 424 0. 989 1146

-40. 000 -.19. 670 4. 077 0. 24526 3.641 151.84 369 22 -.07. 63 2. 06536 0.420 0. 328 1178

-30. 000 i*29. 670 3 857 25926 3.387 167. 27 375 07 415.88 2.08432 0. 418 0. 784 1206

-20. 000 439. 670 3 669 27254 3.174 181.81 38C 65 423.55 2. 10197 0.416 0.'51 1233

-10. 000 449. 670 3 506 28524 2.994 195.61 386 03 430.92 2. 11856 .415 0.725 1259

0. 000 459. 670 3 362 c. 29747 2.837 208.79 391 25 438.07 2.13428 0.414 0.705 1283

10. 000 469 670 3 233 3 9 31 2.700 221.44 396 35 445.03 2. 14926 0.414 9.586 1305

20. 000 479. 670 3 117 32082 2.578 233.63 401 35 451.85 2. 16362 0.415 9.575 1327

30. 000 489 670 3 012 33204 2.469 245. 42 406 26 458.54 2.17743 0.416 0.564 1348

4G. 000 499, 670 2, 915 0. 34302 2. 371 256. 65 411. IE 465.14 2. 19077 0. 417 0.655 1367

50. 000 509 670 2 827 35377 2.282 267.98 415 97 471.65 2. 20368 0.419 0.o48 1386

60. 000 519. 670 2 745 36434 2.200 278.83 420 76 478.10 2.21622 0.420 0.o42 14C5

70. 000 529 670 2 669 37473 ?. 126 289.42 425 5? h84.50 2.22841 0.4?2 0.637 1422

80. 000 539 670 2 598 39497 2. 057 299. 79 430 26 490.86 2. 24029 0.425 0.3 34 1440

100 000 559 670 2 469 4 504 1.93 3 319.93 439 72 503.47 2.26325 0.430 0.o29 1472

120. 000 579 670 2 355 42466 1.826 339. 37 449 17 516.01 2.?9527 0.4 36 0.626 1503

140. 000 599 670 2 253 44388 1.732 358.23 *58 ,66 528.53 2.30649 0.442 0.625 1532

160. 000 619 670 2 161 0. 46278 1. 648 37^.60 468 20 541.04 2.32702 0.449 0.527 1560

180. 000 639 670 2 077 43139 1.573 394.52 477 83 553.60 2.34696 0.457 0.o2S 1567

20C. 000 659 670 2 001 0. •9976 1.506 412. 07 487 55 566.21 2.36637 0.4F5 0.533 1612

220, 000 679 670 1 931 0, 51790 1.444 429.28 497 .39 578.90 2. 38533 0.4?3 0.637 1637

240. 000 699. 670 1. 866 0. 53586 1.388 446. 19 507 3

C '1.69 2.40387 0.482 9.54? 1660

280. 000 739 670 1 750 57127 1.289 479.24 527 7C 617.61 2.43990 0.4<=9 0.654 1706

320. 000 779. 670 1 650 0. 61613 1.205 511.43 548 66 644.06 2.47472 0.518 0.668 1749

360. 000 819 670 1 .561 64054 1.132 542. c.o 570 ?7 671.08 2.50651 0.5 36 0.683 179C

1.00. 000 859. 670 1 482 c. 67456 1.067 573.77 592 55 698.73 2.54144 0.555 0.699 1830

440. 000 899 670 1 412 0. 7 8 2 7 1.011 604. 15 615 52 727.01 2.5735° 0.574 1. '15 1868

246
METHANE ISOBAR AT P = 900.0 PSI

T T DEN VOL OP/DT DP/DD r H S cv CP W DF.G F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 3TU/LB ITU/LB BTU/LB/R BTU/LB/R 8TU/L3/R FT/S 293.605 166. 065 28.312 0,,03532 165.392 3739. 01 93.63 99.52 1.01511 0,,500 0,,780 5201

290. 000 169.670 28.11*6 0.,03553 161.*09 3631.31 96. 33 102.25 1. 03213 0,,+99 0..783 51 + 260.000 179.670 27.699 0.,03610 150.880 33*6.99 103. 87 109.89 1. 07730 o.,500 o. 795 + 965

270. 000 189.670 27. 21*1* 0.,03671 1*0.932 3068.19 111.61* 117.76 1.12070 0,,501 0,,808 + 786

26 0. 00 199.670 26.779 0. 03731* 131.519 2798.20 119.58 125.80 1. 162*9 0.,500 0, 319 + 608 250.000 209.670 26.303 0,, 03802 122.591 2539. 11* 127.65 133.99 1.20271 0,,+95 0,,328 + 1*33 2+0. 000 219.670 25.813 0,,03871. 11*. 096 2292.2* 135.82 1+2.28 1.2*1*6 0,, + 89 0,, 836 + 26 230.000 229.670 25. 307 0. 03952 105.988 2058. 09 1 + 1*. 09 150.67 1.27888 0,,+83 0.,8*5 + 066 220.000 239.670 21*. 782 0. 01*035 98.221 1836.71 152. +5 159.18 1.31515 , ,1*78 0,,357 3907 210.000 2i*9.670 21*. 236 0.,01*126 90.757 1627.67 160.95 167.63 1.35051 0,,1*75 0,,373 372 + 200.000 259.670 23.666 0,,01*226 83.559 1*30.29 169.61 176.65 1.38516 0,,+73 0., 392 3535

190. 000 269.670 23. 066 0. Qi*335 76.590 12*3.71 178.1*6 185.66 1.41929 0,,+72 0,,91* 33+2

ieo. ooo 279.670 22.1*32 0.,0*1.58 69.815 1067. 0* 187.52 191*. 95 1.1*5300 0,,+68 0,,938 31 + 8 170. OOO 289.670 21. 75* 0.,0*597 63. 196 899.52 196.79 20+. 1*5 1.486*0 0.,+61 0., 96* 2953

160. 000 299.670 21.022 0,,0+757 56.688 7+0.6* 206.31 211*. 2 + 1.51961 , , +50 0. 995 275 + 150.000 309.670 20.216 0. 0*9*7 50.238 590.26 216.15 22*. 39 1.55293 0,,1*39 1,, U39 25 + 3

li*0. 000 319.670 19.307 0.,05179 +3.773 *i*8. 88 226.53 235.16 1.58711 0,,+ + 2 1,, 120 2296

130.000 329.670 18.21*2 0, 05*82 37.196 317.69 237.78 2*6.91 1.62330 0,,+ + 2 1,, 2*1 2032 120.000 339.670 16.915 0.,05912 3C.353 199. 12 250.*f 260.32 1.6633+ 0., 1*1*8 1,,+66 1-736 110.000 31*9.670 15.01*1* 0,,066*7 22.967 97. 27 266.15 277.23 1.71237 0,,+65 2,,017 1398

100. 000 359.670 11.1*67 0, 03721 1+.252 28.1*5 291.77 306.30 1.79+20 0,.501 *,,117 101*1 -90.000 369.670 7.87 2 0., 1270* 8.611 39.6* 319.53 3*0.70 1. P3863 0,,*86 2,,553 982 -80.000 379.670 6.1*20 0.,15576 6.597 66. 12 33*.+'* 360.*0 1. 9+126 o., *59 1.,582 1027 -70.000 389.670 5.637 0.,177*1 5.552 89. 08 3++. 66 37*. 23 1.9772+ 0,,i*i* + 1,,230 1069 -60.000 399.670 5.111 0. 1956* + .875 109.1*9 352.9+ 385.5* 2.00591 0,, + 3+ 1,, 0*9 1107 -50.000 1*09.670 l*.722 0.,21179 1*. 389 128. 05 360.15 395.** 2.03039 0,,+?'8 0,,939 11 + 2 -1*0.0 00 419.670 + .+1 + o. 22655 + . 015 1*5. 16 366.69 *0*.+5 2. 05211 o., +23 0. 366 1173 -30.000 1*29.670 i*.162 0,,2*029 3.717 161.12 372.79 *12.83 2.07186 0..+20 0,,31 + 1203

-2 0.00 1*39.670 3.91*9 0. 25325 3.*71 176. 13 378.56 +20.77 2.09012 0,, + 18 0,, 775 1230

-10. 000 1*1*9.670 3.765 0,,26561 3.263 190. 36 36+. 1C +28.36 2.10720 , , + 17 0,, 7 + 5 1256 0.000 1*59.670 3.601* 0. 2

T 7*7 3.085 203. 93 389. +5 1*35.69 2. 12332 0,,+16 a,,722 1260

10. coo 1*69.670 3.1*61 0.,23892 2.929 216.9+ 391*. 66 ++2. 81 2.13865 0,, + 16 0,,703 1303 20.000 1*79.670 3.333 0.,31003 2.792 229.*5 3 99.76 ++9.77 2.15 33 0,, + 16 0,,688 1325 30.000 1*89.670 3.217 0.. 3108* 2.670 2*1.5* +0+.76 +56.58 2.16735 0,, + 17 c,,676 131*6 + 0. 000 i*99. 670 3.111 o. 321*0 2.560 253. 25 +09.72 1*63.29 2.18091 0,. + 18 0,,666 1366 50.000 509.670 3. Oil* 0.,3317* 2.*61 26*. 63 +1+. 61 +69.90 2.19+02 0,,+20 0,, 657 1386 60.000 519.670 2.925 0.,3*187 2. 370 275.71 *19.*6 +76.++ 2.20672 , , i*21 o,, 651 1+C + 70. 000 529.670 2.81*2 0,,3518* 2.287 286.52 *2*. 26 +82.91 2.21906 0,.*23 0,, 6 + 5 1 + 22 SO. 000 539.670 2.765 0., 3516* 2.211 297.09 *29.07 +89.3+ 2.23109 .+26 0,,5*1 1 + 39 100. 000 559.670 2.626 0,,33085 2.075 317.60 *38.62 502.09 2.25+28 0,.*31 0,,63 + 1 + 72 120.000 579.670 2.503 Oi, 39958 1.958 337.37 **8. 15 51+. 7+ 2.276+9 0,, +36 0,,531 1503

1<*0. 000 599.670 2.393 0,,+1793 1.855 356.52 *57.7C 527.35 2.29767 o..+ + 3 0,, 530 153 3 160. 000 619.670 2.291* 0. + 359 + 1.763 375. 1* *67.30 539.95 2. 31855 0,.+50 0,, 531 1561

180. 000 639.670 2.201* 0,,+5367 1.681 393. 30 1*76.96 552.58 2. 33861 0,,1*57 0,,533 1588 200.000 659.670 2.122 G,,*7H5 1.608 1*11. 06 1*86.75 565.27 2. 35813 0.. +65 0,,536 1613

220. 000 679.670 2.01*7 0.,+88+1 1.5*1 +28. +7 *96. 63 578. 02 ?. 37718 0,, +7 + 0,.5+0 1638

2*0. 000 699. 670 1.978 0.,505*8 l.*81 1**5.55 506.63 590.87 2.39581 0,.1*82 0,,6 + 5 1662

280. 000 739.670 1.855 0., 53913 1.37* +78.92 527.05 616.89 2. +3198 .500 0,,657 1707

320. 000 779.670 1.71*8 0,,57222 1.283 511. 37 5*8.06 6 + 3.1.3 2. +6691 0,,518 0,,670 1751 360.000 819.670 1.653 0,,60*86 1.20* 5*3. 07 569.72 670.53 2.50060 o,,537 0.,685 1792

1*00. 000 359.670 1.57 0,,63712 1.135 57*. 1* 592.05 698.2* 2.53361 0,,556 3,,701 1831

1*1*0. 000 899.670 1.1*95 0.,66907 1.07* 60*. 69 615.07 726.57 2.56 60 2 0,,57 + 0,,716 1870

247
METHANE IS08AR AT P = 1000.0 PSI

T T OEN VOL CP/DT DP/OO F H S CV CP H OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 3TU/LB BTU/LB BTU/LB/R RTU/IB/R 8TU/L3/R FT/S

293. 291 166.379 28.325 0.03530 165.219 3751.50 93. 70 100.23 1.01554 0.501 0. 780 5204

290. 000 169.670 28.174 0.03549 161.599 3653.20 96. ie 102.73 1. 03109 0.500 0, 783 5149

280, 000 179.670 27.723 0.03606 151.125 3371. 07 103. 69 110.36 1. 076 22 0.501 o. 794 4976

270. 000 189.670 27.276 0.03666 141.228 3094.09 Ill 43 118.22 1. 11956 0.502 0, 806 4798

260. 000 199.670 26.815 0.03729 131.865 2825.63 119. 35 126.25 1.16128 0.501 0, 817 4622

250. 000 209.670 26.342 0.03796 122.986 2567.91 127 39 134.42 1.20143 0.496 0, 326 4449

240. 000 219.670 25.856 0.03868 114.541 2322. 21 135. 53 142.69 1.24009 0.490 0. 334 4279

230. 000 229.670 25.355 0. 03944 106.485 2089.18 143 76 151.06 1.27740 .484 343 41C7

220. 000 239.670 24.836 0. 04026 98.774 1868. 86 152 OQ 159.54 1. 31355 0.479 854 3931

210. 000 249.670 24.297 0.04116 91.370 1660.97 160. 53 168.15 1.34876 0.476 a. 369 3750

200. 000 259.670 23.735 0.0+213 84.237 1464. 79 169. 14 176.94 1. 38325 0. 474 388 3565

190. 000 269.670 23.145 0.04321 77.343 1279.54 177, 91 185.92 1.41717 0.472 908 3376

180. 000 279.670 22.524 0.04440 70.655 1104.40 186. 88 195.11 1.45063 0.469 930 3187

170. 000 289.670 21.863 0. 04574 64. 140 938.62 196 05 204.52 1.48370 0.461 953 2998

160. 000 299.670 21.153 0.0+727 57.760 781.73 205 43 214.18 1. 51643 0.450 380 2807

150. 000 309. 670 20.379 0.04907 51.474 633.62 215 06 224.15 1.54920 0.440 1 17 2606

140. 000 319.670 19.519 0.05123 45.232 494.72 225, IE 234.63 1.58248 0.441 1 084 2373

130. 000 329.670 18.535 0.05395 38.973 366.19 235. 92 245.91 1.61720 0.441 1 178 2129

120. 000 339.670 17. 361 0.05760 32.623 250. 13 247 72 258.39 1.65448 0.444 1 332 1864

110. 000 349.670 15.863 0.05304 26.098 149.92 261 31 272.99 1.69682 0.454 1 623 1576

100. 000 359.670 13.707 0.07296 19.276 70.95 278 64 292.15 1.75080 0.472 2 328 1274

-90. 000 369.670 10.484 0.09539 12.607 41.46 302, 66 320.32 1.82 80 2 0.485 2 37 3 1066

-80. 000 379.670 8.139 0.12286 8.936 52.38 322 51 345.26 1.89462 0.472 2 089 1037

-70. 000 389.670 6.867 0.14563 7.135 74.67 335 84 362.80 1.94027 0.454 1 497 1068

-60. 000 399.670 6.090 0.16420 6. 083 95.69 345 8C 376.21 1.97426 0.442 1 214 1103

-50. 000 409.670 5.547 0.13029 5.372 115.02 354 09 387.47 2. 00210 0.434 1 353 1137

-40. 000 419. 670 5.134 0.19476 4.849 132.96 361 39 397.45 2.02617 0.428 3 950 1169

-30. 000 429.670 4.806 0.23808 4.443 149.74 36e 04 406.57 2.04765 0.424 0. 379 1198

-20. coo 439.670 4.535 0.22053 4.115 165.54 374 25 415.09 2.06724 0.422 327 1226

-10. 000 449.670 + .305 0.23231 3.8+4 1B0.52 380 13 +23.15 2. 08538 0.420 a 788 1253

0. 000 459.670 4.106 0.24355 3.615 194. 78 385 78 430.88 2.10237 0.419 758 1277

10. 000 469.670 3.932 0.25435 3.417 20e.43 391 23 38.33 2. 11841 0.419 734 1301

20. 000 479.670 3.777 0.26479 3.245 221. 55 396 54 445.57 2.13367 0.419 a '15 1323

30. 000 489.670 3.638 0.27491 3.092 234. 19 401. 7? 452.64 2. 14825 0.419 a. 599 1345

40. 000 499.670 3.512 0.23476 2.957 246. 42 406 84 459.57 2.16225 0.420 587 1365

50. 000 509.670 3.397 0.29438 2.835 258.28 411 87 466.38 2.17576 0.422 S76 1385

60. 000 519.670 3.292 0. 30379 2.724 269.81 416 84 473.10 2. 18881 0.423 568 1404

70. 000 529.670 3.195 0.31302 2.624 281. 05 421. 77 +79.74 2.20147 0.425 0. 661 1422

80. 000 539.670 3.105 0.32209 2.532 292. 01 426 67 486.31 2.21377 0.427 3. 555 1440

100. 000 559.670 2.94 3 0. 33981 2.369 313.24 436 40 499.32 2.23744 0.432 0. 647 1473

120, 000 579.670 2.801 0.35705 2.229 333.64 446 oe 512.20 2.26005 0.438 542 1505

140. 000 599.670 2.675 0.37390 2.107 357. 36 455 77 525.01 2.28177 0. 444 639 1535

160. 000 619.670 2.561 0.39041 1.999 372.49 465 49 537.79 2.30273 0.451 639 1563

180, 000 639.670 2.459 0.40663 1.903 391. 11 475 27 550.57 2. 32304 0.459 640 1590

200 000 659.670 2. 366 0.42260 1.817 409.28 485 14 563.39 2.34278 0.466 -3+2 1616

220 000 679.670 2. 281 0.43836 1.740 427. 06 495 10 576.28 2.36202 0.475 546 1641

240 000 699.670 2.203 0.45392 1.669 444.50 505 19 589.24 2.38081 0.463 ]. 650 1665

280 000 739.670 2.064 0.+3455 1.546 478. 47 525. 74 615.47 2.41726 0. 501 0. 661 1711

320 000 779.670 1. 943 0.51463 1.441 511.44 546 ,68 642.17 2.45242 0.519 0. 574 1754

360. 000 819.670 1.837 0.54427 1.350 543.59 568 64 669.43 2.48651 0.538 0. 589 1796

400 000 859.670 1.744 0.57353 1.272 575. 04 591 07 697.27 2.51967 0.556 704 1836

440. 000 899.670 1.660 0.60248 1.202 605.93 614 16 725.72 2.55202 0.575 a. 719 1874

248
METHANE ISOBAR AT P = 1100.0 PS I

T T DEN VOL OP/DT DP/OD E H S CV CP H DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LP 9TU/L8 BTU/LB/R BTU/LB/R BTU/L3/R FT/S 292.978 166.692 28.339 0.03529 165.047 3763.90 93.76 100.95 1.01597 0.501 0.779 5207 290.000 169.670 28.201 0.03546 161.786 3674. 87 95.99 103.21 1.03006 0.501 0.782 5157 280.000 179.670 27.758 0.03603 151. 366 3394.92 103.50 110.84 1. 07514 0.502 0.793 4987

27 0.0 00 189.670 27.308 0.03662 141.520 3119.76 111.23 118.68 1.11843 0.503 0.305 4811 260.000 199.670 26.850 0.03724 132.205 2852.84 119. 12 126.71 1.160C8 0.502 0.816 4637 250.000 209.670 26.381 0.03791 123.374 2596.45 127.14 134.86 1.20016 0.497 0.824 4466 240.000 219.670 25.899 0.03861 114.979 2351.94 135.25 143.11 1.23873 0.491 0.332 4297 230.000 229.670 25.402 0.03937 106.973 2120. 00 143.44 151.46 1.27594 0.465 0.340 4127 220.000 239.670 24.889 0.04016 99.316 1900.75 151.72 159.91 1.31197 0.480 0.351 3954 210.000 249.670 24.357 0.04106 91.969 1693.90 160.13 168.49 1.34705 0.477 0.366 3776

200. 000 259.670 23.802 0.04201 84.899 1498. 86 168.67 177.23 1.38138 0.475 0.883 3593 190.000 269.670 23.222 0.04306 78.076 1314.87 177.39 186.16 1.41511 0.473 0.902 3409 160.000 279.670 22.613 0.04422 71.469 1141.11 186.28 195.28 1.44B33 0.469 0.923 3224 170.000 289.670 21.968 0.04552 65.048 976.92 195.34 204.61 1.48110 0.462 0.943 3041

160. 000 299.670 21.278 0. 04700 58.783 821.81 204.56 214.16 1.51349 0.451 0.966 2857 150.000 309.670 20.532 0.04870 52.640 675.66 214.04 223.96 1.54568 0.440 0.998 2665 mo. ooo 319.670 19.713 0.05073 46.583 538.87 223.88 234.21 1.57820 0.441 1.355 2443 130.000 329.670 16.792 0.05321 40.573 412.43 234.27 245.11 1.61176 0. 440 1.130 2216 120.000 339. 670 17.727 0.05641 34.574 298.17 245.44 256.93 1.64709 0.442 1.244 1973 110.000 349.670 16.440 0.06063 28.564 198.78 257.83 270.23 1.68564 0.447 1.431 1716 100.000 359.670 14.787 0.06763 22.550 117.82 272. 28 266. 05 1.73025 0.458 1.773 1453 -90.000 369.670 12.512 0.07993 16.600 63. 07 290.41 306.69 1.78680 0.472 2. 382 1215

-80. 000 379.670 10.027 0.09973 11.864 56.41 310.29 330.60 1.85 063 0.473 2.218 1107 -70.000 389.670 8.302 0.12046 9.139 66.47 326. 08 350.62 1.90271 0.461 1.776 1090 -60.000 3 99.67 7.199 0.13890 7.546 85.52 338.05 366.34 1.94257 0.449 1.399 1112 -50.000 409.670 6.459 0.15481 6.526 104.74 347.60 379.14 1.97420 0. 440 1.179 1141 -40.0 00 419.670 5.918 0.16898 5.805 122.91 355.77 390.19 2.00087 0.433 1.042 1170 -30.000 429.670 5.497 0.18192 5.262 140. 07 363. C6 400.12 2.02425 0.429 0.949 1199 -20.000 439.670 5.157 0.19393 4.834 156. 35 369.76 409.26 2.04529 0.426 0.383 1226 -10.000 449.670 4.87 3 0.23523 4.485 171. 83 376.03 417.84 2. 06457 0.423 0.834 1252 0.000 459.670 4.631 0.21595 4.194 186.61 381.99 425.98 2.08249 0.422 0.796 1277 10.000 469.670 4.421 0.22622 3.946 200.77 387.71 433.79 2.09929 0.421 0.767 1301 20.000 479.670 4.236 0.23609 3.733 214.39 393.24 441.34 2.11519 0.421 0.743 1324 30.000 489.670 4. 071 0.24565 3.546 227.51 398.63 446.67 2. 13032 0.422 0.724 1345 40.000 499.670 3.923 0.25492 3.380 240.19 403.90 455.83 2. 14480 0.423 0.709 1366 50.000 509.670 3.789 0.26395 3.232 252.48 409.09 462.85 2.15871 0.424 0.696 1386 60.000 519.670 3.666 0.27276 3.099 264.42 414.19 469.75 2.17213 0.425 0.685 1405

70. 000 529.670 3.554 0.28139 2.979 276. 04 419.24 476.56 2.18510 0.427 0.577 1424 80.000 539.670 3.450 0.23986 2.869 287.37 424.25 483.29 2.19769 0.429 0.670 1441 100.000 559.670 3.264 0.30636 2.676 309.27 434.17 496.57 2.22185 0.434 0.659 1475

120. 000 579.670 3.102 0.32238 2.511 330.28 444.02 509.68 2.24487 0.439 0.652 1507

140. 000 599.670 2.959 0.33799 2.368 350.54 453.84 522.69 2.26692 0.446 0.649 1537

160. 000 619.670 2.831 0.35327 2.243 370. 16 463.68 535.64 2.28817 0.453 0.647 1566 180.000 639.670 2.716 0.35825 2.132 389.22 473.57 548.58 2. 30873 0.460 0.647 1593 200.000 659.670 2.611 0.33298 2.032 407.79 483.53 561.54 2.32868 0.468 0.549 1619

220. 000 679.670 2.516 0.39750 1.943 425.94 493.59 574.55 2.34811 0.476 0.652 1645 240.000 699.670 2.423 0.41183 1.862 443.71 503.75 587.63 2.367 8 0.484 0.656 1669 280.000 739.670 2.273 0.43998 1.721 478.27 524.44 614.06 2.40 3 61 0.502 0.666 1715 320.000 779.670 2.139 0.46759 1.602 511.75 545.70 640.94 2.43920 0.520 0.678 1759

360. 000 819.670 2.021 0.49476 1.499 544.32 567.57 668.34 2.47347 0.539 0.592 1600 400.000 859.670 1.917 0.52156 1.410 576.16 590.06 696.32 2.50678 0.557 0.707 1840 440.0 00 899.670 1.825 0.54805 1. 332 607. 36 613.26 724.69 2.53927 0.576 0.722 187 8

249
METHANE ISOBAR AT P = 1200.0 PSI

T T DEN VOL DP/OT OP/OD E H S CV CP W DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 3TU/LB BTU/LB 8TU/LB/R BTU/LB/R BTU/LB/R FT/S

292.665 167. 005 28.352 0. 03527 164.877 3776. 20 93 83 101.66 1. 01641 0.502 0.779 5210 290.000 169.670 28.228 0. 03543 161.969 3696. 30 95. 83 103.70 1. 02904 0.501 0. 781 5166

280. 000 179.670 27.787 0. 03599 151.603 3418.56 103. 32 111.31 1. 07407 0.502 0.792 4997 270.000 189.670 27.340 0. 03658 141.807 3145.21 111. 02 119.15 1. 11731 0.504 0.304 4823 260.000 199.670 26.885 c 03720 132.540 2879. 84 118. 89 127.16 1. 15890 0.502 0.814 4651 250.000 209.670 26.419 0. 03785 123.757 2624.76 126. 88 135.30 1. 19890 0. 498 0.823 4482

240. 000 219.670 25.941 0. 03855 115.409 2381.42 134, 97 143.53 1. 23739 0.492 0.830 4315 230.000 229.670 25.449 0. 03929 107.453 2150.54 143 12 151.86 1 27450 0.485 0. 838 4147 220.000 239.670 24.941 0. 04009 99.847 1932.31 151. 37 160.28 1. 31042 0.480 0.348 3976 210.000 249.670 24.415 0. 04096 92.556 1726. 48 159. 73 168.83 1. 34537 0. 477 0.362 3801 200.000 259.670 23.868 0. 04190 85.546 1532.52 168 22 177.53 1 37955 0.4 76 0.879 3622 190.000 269.670 23.298 0. 04292 78.789 1349.69 176 87 166.41 1. 41309 .474 0.397 3441 180.000 279.670 22.699 0. 04405 72.257 1177.23 185 .69 195.47 1 44609 0.470 0.916 3260 170.000 289.670 22.068 0. 04531 65.924 1014.49 194 66 204.73 1 47859 0.462 0.934 3082 160.000 299.670 21.397 0. 04674 59.762 860.97 203 7P 214.16 1 51062 0.451 0.954 2904 150.000 309.670 20.676 0. 04837 53.744 716.56 213, 06 223.83 1 54234 0.440 0.981 2720

140. 000 319.670 19.891 0. 05027 47.845 581.56 222 7r 233.67 1 57422 0.441 1.330 2508

130. 000 329.670 19. 022 0. 05257 42. 037 456. 85 232 78 244.46 1 60684 0.439 1. J92 2294

120. 000 339.670 18.033 0. 05544 36.305 343.96 243 48 255.80 1 *4070 0.440 1. 181 2068 110.000 349.670 16.892 0. 05920 30.648 245. 06 255 oe 268.22 1 67 67 3 0.443 1. 313 1834 100.000 359.670 15.505 0. 06449 25.103 162. 81 267 98 282.31 1. 71646 0.450 1.523 1597 -90.000 369.670 13. 762 c 07266 19.748 100.64 282 96 299.11 1 76250 0.460 1.861 1373 -80.000 379.670 11.642 0. 03590 14.876 69.49 300 34 319.42 1 81670 0.467 2.119 1209 -70.000 389.670 9.769 0. 13237 11.446 71.81 316 61 339.35 1 86853 0.462 1.841 1152 -60.000 399.670 6.-+09 0, 11892 9.278 81.30 329, 94 356.37 1. 91165 0.453 1.561 1140

-50. 000 409. 670 7.45 3 0. 13423 7.864 97.93 340 81 370.64 1 94693 0.444 1.307 1156

-40. 000 419.670 6.758 0. 14796 6.894 115.56 349 92 382.80 1 97627 0.437 1.137 1180 -30.000 429.670 6.232 0. 15047 6. 180 132.61 357 9C 393.56 2 00 162 0.432 1.323 1205 -20.000 439.670 5.812 0. 1'204 5.629 148.97 365 13 403.36 2. 02417 0.429 0.942 1231 -10.000 449.670 5.468 0, 19289 5.188 164.66 371 82 412.46 2. 04464 0.426 3. )82 1256

0. 000 459.670 5.177 0. 19316 4.824 179.72 378 12 21.04 2 06352 0.425 3.836 1280 10.000 469.670 4.927 0. 23296 4.519 194.21 384 12 429.22 2. 08112 0.424 3.301 13C3 20.000 479.670 4.709 0. 21235 4.257 208. 17 389 89 •37.08 2 09768 0. 424 0.772 1326 30.000 489.670 4.515 0. 22142 4.030 221.65 395 49 444.69 2 11337 0. 424 0.750 1348

40. 000 499.670 4.344 0. 23020 3.831 234.70 400 94 452.09 2, 12834 0.425 0.731 1368 50.000 509.670 4.189 0, 25873 3.654 247. 34 406 27 459.32 2 14267 0.426 0.'16 1388 60.000 519.670 4.048 0. 24704 3.495 259.63 411. 52 466.42 2. 15646 0.427 0.703 1408 70.000 529.670 3.919 0. 25517 3.353 271.58 416 70 473.40 2 16976 0.429 0.693 1426

80. 000 539.670 3.801 0. 25312 3.223 283.24 421 82 480.28 2 18264 0.431 0.684 1444

100. 000 559.670 3.589 0. 27860 2.997 305.74 431 93 493.84 2 20730 0.435 0.672 1478

120. 000 579.670 3.406 0. 29359 2.805 327. 30 441 94 507. 18 2. 23073 .441 0.663 1510 140.000 599.670 3.245 0. 33817 2.639 348. C7 451 91 520.39 2 25 313 0.447 3.658 1541 160.000 619.670 3.102 0. 32241 2.495 368. 15 461 87 533.52 2 27466 0.454 3.655 1570

180. 000 539.670 2.973 0. 33636 2.367 387.63 471 87 546.61 2. 29547 0.461 0.655 1597

200. 000 659.670 2. 857 0. 35006 2.254 406.59 481 93 559.72 2 31564 0.469 0.656 1623 220.000 679.670 2.751 35354 2.152 425.09 492 07 572.85 2 33526 0.477 0.658 1649

240. 000 699.670 2.65 4 0. 3 7 6 8 3 2.060 44 3.18 502 31 586.05 ?, 35439 0.485 0.561 1673 280.000 739.670 2.482 0, 43292 1.900 478. 32 523 1? 612.68 2 39140 0.5C3 0.671 1719

320. 000 779.670 2. 334 0. 42846 1.766 512.28 544 52 639.73 2 42702 0.521 3.o82 1763 360.000 819.670 2.205 0, 45357 1.651 545. 27 566 49 667.28 2 46147 0.539 0.595 1805 400.000 859.670 2.091 47831 1.551 577.46 589 10 695.38 2, 49494 0.558 3. 710 1845 440.000 899.670 1.989 0. 53274 1.464 608.98 612 36 724.07 2. 52756 0.577 0. 725 1883

250
METHANE ISOBAR AT P = 1300.0 PSI

T T DEN VOL DP/DT OP/OO E H S cv CP H DEG F DEG R LB/CUFT CUFT/L8 PSI/R PSICUFT/LB BTU/LP 3TU/LG BTU/LB/R BTU/LB/R BTU/L9/R FT/S

292. 353 167.317 28.365 0. 03525 164.707 3788. 41 93 ,89 102.38 1 01685 .503 779 5213

290. 000 169.670 28.255 0. 03539 162. 148 3717. 51 95 66 104.18 1 02803 502 780 5174

2ao. 000 179.670 27.816 03595 151.836 3441 96 103 13 111.79 1 07301 .503 791 5007

270. 000 189.670 27.372 03653 142.089 3170. 45 110 82 119.61 1 11620 505 803 4835

260. 000 199.670 26.919 03715 132.870 2906, 61 118 67 127.61 1 15772 .503 0. 813 4665

250. 000 209.670 26.457 0. 03780 124.133 2652. 65 126- 64 135.73 1 19765 ,499 321 4498

?i*0, 000 219.670 25.983 0. 03849 115.833 2410. 66 134 .69 143.95 1 23606 ,492 128 433 3 230. 000 229.670 25.495 0, 03922 107.924 2180. 83 142 81 152.26 1 27308 486 0, t!36 4167

220, 000 239.670 2 4.99 3 04001 100.369 1963 58 151 ,0? 160.66 1 30 890 .481 846 3999

210. 000 249.670 24.472 04086 93.130 1758. 74 159 ,34 169.17 1 34372 .478 159 3626

200. 000 259.670 23.933 417 8 86. 178 1565 76 167 ,7e 177.84 1 37775 476 875 3649

190 000 269.670 2 3. 371 04279 79.484 1384 05 176 37 186.67 1 41112 ,475 n J92 3471

160. 000 279.670 22.783 04389 73.023 1212 80 185 11 195.68 1 44392 471 909 3295

170. 000 289.670 22.165 0. 04512 66.770 1051 37 194 .00 204.86 1 ,47616 ,463 926 3121

160. 000 299.670 21.510 0. 04649 60.701 899. 31 203 01 214.20 1 50787 ,452 943 2949

150. 000 309.670 20.812 0, 04805 54.796 756 44 212 17 223.74 1 53917 440 o }66 2773

140. 000 319.670 20.057 04986 49.032 623 01 221 ,60 233.61 1 57049 441 l 09 25C9

130. 000 329.670 19.231 05200 43.393 499. 75 231 42 243.94 1 60231 ,439 l. 061 2366

120. 000 339.670 18.312 0. 05461 37.871 387. 95 241 74 254.ee 1 63501 ,439 l 132 2154

110. 000 349.670 17.266 0. 05792 32.477 289. 39 252 73 266.68 1 66922 441 l 232 1936

100. 000 359.670 16.049 0, 06231 27.249 206. 13 264 68 279.68 1 70587 445 l. 377 1718

-90. 000 369.670 14.600 0. 06849 22.263 140, 32 277 95 294.43 1 74632 452 i 587 1510

-80. 000 379.670 12.876 0. 0/767 17.643 95. 96 292 se 311.57 1, 79205 459 l. 834 1333

-70. 000 389.670 11.071 0. 09033 13.811 82. 66 308 47 330.21 1 64051 ,461 l 819 1230

-60. 000 399.670 9.604 0. 10412 11. 178 87. 50 322. 22 347.29 1. 88380 0. 453 i. 599 1196

-50. 000 409.670 8.485 11786 9.377 96. 59 33"? 94 362.31 1 92093 ,44 7 l 406 1187

-40. 000 419.670 7.64 2 0. 13085 8.114 111. 40 343 94 375.44 1, 95260 440 i 227 1199

-30. 000 429.670 7.002 0. 14283 7.199 127. 66 352 63 387.01 1 97 98 5 .436 l D94 1219

-20. 000 439.670 6. 497 0. 15392 6.503 143. 70 360 40 397.45 2 0038d 432 l 000 1241

-10. 000 449.670 6.086 0. 16432 5.954 159. 29 367 53 407.08 2 02554 429 0, 930 1264

0. 000 459.670 5.742 0. 17415 5.507 174. 37 374 ie 416.10 2 04538 427 676 1267

10. 000 469.670 5.449 0. 18350 5.134 168, °7 380 47 424.65 2 C637e 42o 835 1309

20. 000 479.670 5-196 o. 19247 4.818 203. 11 386. 50 432.83 2 08101 .4 26 302 1331

30. 000 489.670 4.973 0. 20110 4.546 216. 60 392, 30 440.71 2, 09728 426 0. 776 1352

1*0. 000 499.670 4.775 0. 20944 4.308 230. 09 397 94 448.36 2 11273 427 0, 754 1373

50. 000 509.670 4.597 0, 21754 4.099 242, 99 403 44 455.80 2. 12749 ,428 0, 736 1392

60. 000 519.670 4.436 0. 22542 3.913 255. 54 408 83 463.09 2 14165 429 0, ^22 1412

70. 000 529.670 4.290 0. 23310 3.745 267. 76 414 13 470.25 2. 15529 430 0, 710 1430

80. 000 539.670 4. 156 0. 24062 3.594 279. 66 419 37 477.29 2 16847 432 0. 700 1448

100. 000 559.670 3.918 0. 25522 3.331 302. 69 429, 68 491.12 2 19363 437 0. 634 1482

120. 000 579.670 3.713 0. 26933 3.110 324. 75 439 86 504.70 2 21747 442 0, o74 1514

140. 000 599.670 3.533 0. 28303 2.920 345. 97 449 97 516.11 2 240 21 448 0, 567 1545

160. oco 619.670 3.374 0. 29639 2.755 366. 48 460 07 531.41 2. 26204 455 0, 5 64 1574

180. 000 639.670 3.231 0. 33946 2.610 386. 35 470. IP 544.67 2. 28309 4 62 0. 662 1601

200. 000 659.670 3.103 0. 32228 2.481 405. 67 480. 33 557.91 2, 30348 470 3, 662 1628

220. 000 679.670 2.986 0. 33488 2.366 424. 51 490. 56 571.18 2

,

32329 478 0. o64 1653

240. 000 699.670 2.879 0. 34729 2.263 442. 91 500 86 584.48 2

,

34258 486 0, 667 1676

280. 000 739.670 2.691 0. 3M62 2.083 478. 59 521. se 611.32 2. 37988 0. 504 0. 675 1724

320. 000 779.670 2.529 0. 39541 1.933 513. 02 543. 35 638.54 2

,

41572 522 0. 686 176e

360. 000 819.670 2.388 0. 41877 1.804 546. 42 565. 43 666.24 2

,

45036 0, 540 0. 599 1810

400. 000 8 59.670 2.264 0. 44176 1.693 576. 96 588. 12 694.47 2. 48398 559 0. 713 1850

440. 000 899.670 2.151 0. 46445 1.597 61C. 78 611. 46 723.27 2. 51672 0. 577 0. 727 1888

251
METHANE ISOBAR AT P = 1*00.0 PSI

T T OEN VOL DP/OT OP/OO E H S CV CP W DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LP 3TU/LP BTU/L8/R BTU/LB/R BTU/L6VR FT/S

292.042 167.628 28.37S 0. 03524 164.539 3800. 53 93. 96 103.09 1. 01723 0.504 0. 778 5216

290. 000 169.670 28.282 0. 03536 162.324 3738.48 95 50 104.67 1.02702 0.503 0. 780 5182 280.000 179.670 27.61*5 0. 03591 152.065 3465. 15 102, 96 112.27 1.07196 0.504 0. '90 5017

27 0.0 00 189.670 27.1*03 0. 03649 142.367 3195.47 110 62 120.08 1.11509 0.505 0. 802 4847 260.000 199.670 26.954 0. 03710 133.195 2933.17 118. 45 128.07 1. 15656 0.504 0. 312 4679 250.000 209.670 26.1*95 03774 124.504 2680.72 126 3° 136.18 1.19642 0.500 319 4513

2i«0.000 219.670 26.024 0. 03843 116.249 2439.66 134 42 144.38 1.23475 0.493 0, 826 4350 230.000 229.670 25.541 0. 03915 108.388 2210. 86 142. 51 152.66 1.27168 0.487 0. 833 4187 220.000 239-670 25. 043 0. 03993 100.881 1994.57 150. 68 161. 04 1. 30739 0.462 943 4020 210.000 249.670 24.529 0. 04077 93.694 1790.67 158 96 169.52 1.34.210 0.479 0. 356 3850 200.000 259.670 23.996 0. 0*167 86.796 1598.68 167, 35 178.15 1.37599 0.477 0. 371 3676 190.000 269.670 23.442 0. 04266 80. 162 1417.98 175 ,89 186.94 1.40920 0.475 0. 887 3502

ISO. 000 279.670 22. 86"* o. 0*374 73.767 1247. 84 184. 56 195.90 1.44179 0.471 0, 903 3329 170.000 289.670 22.258 0, 04493 67.588 1087.64 193 36 205.01 1.47380 0.464 0. 918 3159

16 0. 000 299.670 21.619 0. 04625 61.606 936. 89 202 28 214.27 1.50521 0.452 0. 933 2993

150. 000 309.670 20.941 0. 04775 55.800 795.40 211 31 223.69 1.53614 0.441 953 2822

140. 000 319.670 20.213 o. 0*947 50.155 663. 35 220 ,57 233.40 1.56696 0.441 0. 991 2627 130.000 329.670 19.424 0. 05148 44.659 541. 34 230 17 243.52 1.59812 0.438 1 035 2433 120.000 339.670 18.556 0. 05389 39.310 430.44 240 17 254.14 1.62987 0.438 1. 093 2232 110.000 31*9.670 17.589 0, 05686 34.119 332. 13 250 71 265.45 1.66268 0.439 1. 173 2027

100. 000 359.670 16.491 o. 06064 29.126 248.06 261 97 277.69 1.69717 0.442 1 260 1824

-90. 000 369.670 15.223 0. 05567 24.392 179.78 274 15 291.17 1.73414 0.447 1. 424 1629 -80.000 379.670 13.77 3 0. 07261 20.003 129. 15 287 46 306.28 1.77447 0.453 1. 601 1455 -70.000 389.670 12.175 0. 08214 16.128 100.80 301. 70 322.99 1. 81790 0. 456 1. 712 1324

-60. 000 399. 670 10.687 0. 09357 13.117 97.76 315 41 339.67 1.86017 0.452 1 592 1264

-50. 000 1*09.670 9.490 0. 10537 10.991 103.40 327 45 354.76 1.89747 0.447 1. *31 1238 -40.000 1*19.670 8.541 0, 11708 9.45? 112. 19 338 01 368.37 1.93029 0.442 1 290 1232 -30.000 "29.670 7.793 0. 12832 8.314 125. 64 347 33 380.59 1.95908 0.438 1. 158 1241

-20. 000 1*39.670 7.201 13887 7.454 140. 72 355 63 391.63 1.99449 0.434 1 054 1258 -10.000 i*i*9.670 6.721 0. 14879 6.762 155.86 363 19 401.76 2.00727 0.432 0. 976 1278 0.000 i*59.670 6. 322 0. 15817 6.241 170.72 370. 2C 411.20 2.02804 0.430 915 1298 10.000 469.670 5.96* 0. 16710 5.793 185. 22 376 79 420.11 2. 04722 0.429 969 1319 20.000 479.670 5.693 0. 17566 5.416 199.35 383 07 428.61 2. 06 511 0.428 a. 631 1339 30.000 1*89.670 5.438 13389 5.094 213.10 389 09 436.76 2.08195 0.426 a. 301 1360

1*0.000 499.670 5.213 0. 19183 4.614 226.50 394. 9? 444.65 2.09789 0.428 0. 777 1379 50.000 509.670 5. 012 0. 19954 4.568 239. 54 400 59 452. 31 2. 11309 0.429 '0 757 1399 60.000 519.670 4.830 0, 21703 4. 351 252.26 406 12 459.80 2.12761 0.430 0. 71.0 1417 70.000 529.670 4.666 0. 21433 4.157 264.67 411 5 6 467.12 2.14158 0.432 0. 726 1436 80.000 539.670 4.515 0. 22147 3.982 276.78 4ie 91 474.33 2.155C5 0.434 0. "15 1453

100. 000 559.670 4.250 0. 23530 3.679 300. 21 427 43 488.43 2.18072 0.438 0. 697 1487 120.000 579.670 4.022 0. 24864 3.426 322.67 437 78 502.24 2.20497 0.444 665 1519

1^*0.000 599.670 3.823 0. 2ol58 3.210 344.29 448 04 515.85 2.22805 0.450 0. 677 1550 160.000 619.670 3.647 0. 27418 3.023 365. 17 458 26 529.34 2.25017 0.456 0. 672 1579

180. 000 639.670 3.491 0. 29646 2.859 385.40 468 ,48 542.75 2.27147 0.463 a o70 160a

200. 000 659.670 3. 350 0. 29854 2.714 405.05 478 74 556.13 2.29 2 08 0.471 0, 669 1633 220.000 679.670 3.222 0. 31038 2.585 424. 20 489 06 569.52 2.31207 0.479 0. 37 C 1658

2<*0.000 699.670 3.105 32204 2.470 41*2.89 499 46 582.94 2. 33153 0. 487 0. 672 1683 280.000 739.670 2.900 0, 3*486 2.269 479. 09 520 57 609.98 2.36910 0.505 o. 680 1729

320. 000 779.670 2.724 0. 3o714 2.102 513.97 54? 19 637.37 2.40517 0.523 0. 690 1773 360.000 819.670 2.571 0. 33899 1.960 547.76 564. 37 665.21 2.43999 0.541 a. 702 1815

1*00.000 859.670 2.436 0. 41049 1.838 580.63 587 15 693.57 2.47377 0.560 0. 716 1855

44C. 000 899.670 2.317 0, *H68 1.731 612. 74 610 57 722.48 2.50664 0.578 o. 730 1893

252
METHANE ISOBAR AT P = 1500.0 PSI

T T DEN VOL DP/OT OP/DO E H S CV CP W DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 8TU/l_e BTU/LB BTU/LB/R BTU/LB/R BTU/L3/R FT/S 291.730 167.940 28.392 0.03522 164.371 3812.55 94 02 103. 81 1. 01772 0.504 778 5219

290. 000 169.670 28.308 0.03533 162.496 3759.23 95 34 105.15 1.02602 0.504 779 5190

280. 000 179.670 27.874 0.03588 152.290 3488.12 102 78 112.74 1.07092 0.505 790 5027 270.000 189.670 27.435 0.03645 142.641 3220.28 110 43 120.55 1.11400 0.506 301 4859 260.000 199.670 26.988 0.03705 133.515 2959.51 118 23 128.52 1.15541 0.505 311 4692 250.000 209.670 26.532 0.03769 124.869 2708.36 126 .15 136.62 1.19520 0.500 318 4529 240.000 219.670 26.065 0.03837 116.659 2468.44 134 15 144.80 1.23346 0.494 324 4368

230.000 229.670 25.586 0.03908 108.843 2240. 64 142 .21 153.07 1.27 30 .468 831 4206 220.000 239.670 25. 093 0.03985 101. 383 2025.29 150 35 161.42 1.30591 0. 463 840 4042 210.000 249.670 24.584 0.04068 94.246 1822. 29 158 58 169.88 1.34050 0.480 853 3874 200.000 259.670 24.058 0.04157 87.401 1631.22 166 93 178.48 1.37426 0.478 367 3703 190.000 269.670 23.512 0.04253 80.824 1451.49 175 .41 187.22 1.40731 0.476 383 3531 180.000 279.670 22.943 0.04359 74.491 1282.40 184 02 196.13 1.43973 0.472 898 3361 170.000 289.670 22.349 0.04475 66.382 1123. 31 192 75 205.18 1.47 151 0.464 a 911 3196 160.000 299.670 21.724 0.04603 62.478 973.77 201 57 214.35 1.50265 0.453 924 3034 150.000 309.670 21.063 0.04748 56.763 833.53 210 46 223.67 1.53324 0.441 941 2 87 140. 000 319.670 20. 359 0. 04912 51. 223 702.70 219 60 233.25 1.56363 0.441 975 2681 130.000 329.670 19.602 0.05102 45.850 581.76 229 00 243.17 1.59420 .438 1 012 2495 120.000 339.670 18.778 0.05325 40.645 471.66 238 74 253.53 1.62516 0.437 1 62 2304 110.000 349.670 17.872 0.05595 35.620 373.56 248 92 264.46 1.65686 0.438 1 126 2110

100. 000 359.670 16. 864 0.05930 3C.808 288.82 259 .65 276.1? 1.68973 0.440 1 209 1918

-90. 000 369.670 15.732 0.06357 26.262 218.63 271 07 268.73 1.72429 0.443 1 316 1734 -80.000 379.670 14.458 0.06916 22.047 164. 08 283 30 302.51 1.76109 0.448 1 444 1566 -70.000 389.670 13.060 0.07657 18.251 127.14 296. 31 317.58 1. 80024 0. 451 1 360 1427

-60. 000 399.670 11.648 0.03565 15.054 111.57 309 46 333.31 1.84010 0.449 1 557 1339 -50.000 409.670 10.415 0. 09602 12.633 113.42 321. 60 348.27 1.87709 .446 1 430 1298 -40.000 419.670 9.408 0. 10630 10.854 119.46 332 42 361.95 1.91007 .442 1 308 1279 -30.000 429.670 8.584 0.11649 9.509 128. 03 342 14 374.49 1.93962 0.439 1 202 1274 -20.000 439.670 7.914 0.12636 8.476 140.43 350 90 385.99 1.96609 0.436 1 101 1282

-10. 000 449.670 7.366 0.13576 7.670 154. 50 356 86 3 9 6.57 1.98988 0.433 1 018 1297 0.000 459.670 6.912 0.14468 7.024 168.84 366. 22 406.41 2.01151 0.431 352 1314 10.000 469.670 6.528 0.15319 6.494 183. 04 373 11 415.66 2. 03143 0.430 0. 900 1332 20.000 479.670 6.193 0.15135 6.050 197.00 379. 63 424.45 2. 04995 0.430 359 1351

30. 000 489.670 5.910 0.15919 5.672 210.66 385. 86 +32.87 2.067 33 0.430 626 1370 40.000 499.670 5.657 0.17677 5.346 224. 04 391 85 440.99 2. 08375 0.430 799 1389 50.000 509.670 5.431 0.13412 5. 061 237. 11 397. 73 448.87 2. 09 9 35 0.431 777 1407 60.000 519.670 5.229 0.19126 4.810 249. 90 403 41 456.54 2. 11425 0.432 758 1425 70.000 529.670 5.045 0.19821 4.587 262.40 408. 98 464.04 2.12855 .434 742 1443 80.000 539.670 4.878 0.20500 4.386 274.63 414. 45 471.39 2.14 231 0.435 0. 7?g 1460

100. 000 559.670 4.584 0.21814 4.041 298. 34 425. 16 485.77 2.16847 0.440 710 1494

120. 000 579.670 4,333 0.23081 3.753 321. 11 435. 71 499.82 2. 19313 0.445 t96 1525 140.000 599.670 4.114 0.2*307 3.509 343. 05 446. 11 513.63 2. 21656 0.451 0. 686 1556 160.000 619.670 3.922 0.25500 3.299 364.25 456. 46 527.29 2.23897 0.457 0. 680 1584

180. 000 639.670 3.750 0.26665 3.115 384.80 466. 79 540.86 2.26051 0.464 3 677 1612 200.000 659.670 3.597 0.27804 2.954 404.75 477 15 554.38 2.28133 0.472 . b76 1638 220.000 679.670 3.458 0.28922 2.810 424. 18 487. 56 567.89 2.30151 0.480 0. 676 1664 240.000 699.670 3.331 0.33021 2.681 443. 14 496. 04 581.43 2. 32114 0.488 0. 678 16e8

280. 000 739.670 3.108 0. 32172 2.459 479.82 519 30 608.66 2. 35898 0.506 0. 684 1735 320.000 779.670 2.913 0.34269 2.275 515. 12 541 03 636.22 2.39527 0.5 24 3. 694 1778

360. 000 819.670 2.753 0.36323 2. 119 549. 28 563. 31 664.20 2.43027 0.542 3. ?06 1820 400.000 859.670 2.603 0.38342 1.984 562.48 586. 19 692.69 2.46 420 0.561 719 I860

440. 000 899.670 2.479 0.41331 1.867 614.87 609. 69 721.71 2.49720 0.579 733 1899

253
METHANE ISOBAR AT P = 1500.0 PSI

T T DEN VOL DP/OT OP/DD F H S CV CP W OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 8TU/LF 3TU/LB BTU/LB/R BTU/L8/R ETU/L^/R FT/S

291. 1.20 168. 250 28.1.05 0. 03521 16*. 205 382*. *e 94. 09 10*. 52 1. 01816 0.505 0. 777 5222

290. 000 169.670 28.335 0. 03529 162.665 3779.7* 95. ie 105. 63 1. 02502 0.505 0. ^79 5198

280. 000 179.670 27.903 0. 03581. 152.512 3510. 87 102. 60 113. 22 1. 06988 0.506 0. 789 5037

270. 0G0 189.670 27.1.65 0. 0361.1 1*2.911 32<*4.87 110. 23 121. 02 1. 11291 0.507 0. 300 1*871 26 0. 000 199.670 27. 021 0. 03701 133.831 2985.61. 118. 02 1?8. 98 1. 15*27 0.506 0. 809 *706

250. 000 209.670 26.563 0. 03761. 125.229 2735.80 125. 91 137. 06 1. 19*00 0.501 0. 316 *51.4 2*0. 000 219.670 26. 105 0, 03831 117.063 2*97.01 133. 88 1*5. 23 1. 23218 0.*95 0. 322 1*386 230. 000 229.670 25.630 0. 03902 109.291 2270. 18 1*1. 9? 153. <*8 1. 26893 0.1.89 0. 829 *225

220. 000 239.670 25. 1*2 0. 03977 101.877 2055.7* 150, 02 161. 81 1. 30*1.5 0.*8* 0. 338 *063

210. 000 21.9.670 2i». 639 0. + 059 9*. 788 1853.61 158, 21 170. 2* 1. 33893 .*80 0. 350 3897

200. 00G 259.670 21.. 119 0. 01.11*6 87.99* 1663.1.3 166. 52 178. 80 1, 37256 0.*79 0. 363 3728

190. 000 269.670 23.580 0. 01*21.1 81.1*71 1*84.60 17*. 95 187. 51 1. 4051.6 0.*77 0. 378 3560

180. 000 279.670 23.020 0, 0*31* l* 75. 197 1316.49 183. 50 196. 37 1, 1*3 771 0.473 3. 392 3393

170. 000 289.670 22.1.36 0, 01*1*57 69.152 1158.44 192, 15 205. 36 1 1.6928 .*65 905 3232

160. 000 299.670 21.825 0, 0*582 63. 321 1010. 00 200. 89 21*. 1.6 1. 50013 0.1*53 0, 316 3071. 150. 000 309.670 21. 181 0, 0*721 57.688 870.90 209. 70 223. 68 1 53045 0.**2 330 2915

1*0. 000 319.670 2 0.1.93 0. 0*879 52.2*2 71.1. 17 218. 68 233. 14 1 56 01.5 0.**2 961 2733

130. 000 329.670 19.768 0. 35059 *6.977 621.22 227. 91 21*2, 9C 1 59051 0.1.38 993 25^4

120. 000 339.670 18.982 0, 05268 *1 .89* 511.77 237. *2 253, 03 1, 62080 0.* 37 1 035 2371

110. coo 31.9.670 18.126 0, 05517 37.006 1.13. 8* 2*7. 30 263. 6« 1. 65158 0.1*37 1. 389 2186

100 000 359.670 17.183 03818 32.3*1 323.54 257. 62 274 86 1 68319 0.1*38 1 156 2004

-90. 000 369.670 16.153 0, 06191 27.9*3 256. 83 268. *7 286, 81 1 71597 0.441 1 238 1828

-80 000 379.670 15.010 05662 23. 861 199.1.1 279 93 299, 67 1 75C29 . 1.1.4 1 335 1667

-70. 000 389.670 13.767 07261. 2C 156 157. 18 292. OC 313 52 1 73628 0.1.1.7 1 *31 1526

-60, 000 399.670 12.1.75 03016 16.917 13?. 07 30* 38 328 13 1 82330 0.4*6 1 *76 1*2*

-50, 003 1.09.670 11.251. 03885 1*.281 125.44 316. 36 31.2, 69 1 85929 .*** 1 *18 136?

-hO 000 1*19.670 10.213 9792 12.276 129. 37 327 31 356 32 1 89218 0.*l»2 1 310 1333

-30. 000 1*29.670 9.31.5 0, 10701 10. 7*9 135.65 337 23 368 9* 1 92188 0.1*39 1 ?15 1319

-20 000 1.39.670 8.613 c, 11603 9.555 144. 05 3h6 29 380 67 1 9*3b7 0.1.37 1 131 1315

-10 000 1.1.9.670 8.01? 0, 12*81 8.610 155.63 354 6C 391 58 1 97 31.2 0.1.35 1 352 1321

000 1.59.670 7.505 0, 13325 7.853 168. 8* 36? ?P *01 75 1 99580 0.*33 985 133*

10 000 1.69.670 7. 075 1*133 7.233 182.1.7 369 *4 *11 3? 2 01639 0.1.32 33 13*9

20 000 1.79.670 6.707 1*910 6.717 196. 08 376 22 *20 3° 2 03550 0.1.31 386 1366

30 000 89.670 6.387 15658 6.280 209.52 382 67 *?9 06 2 05339 0.1.31 350 1383

1*0 000 1.99.670 6.105 16381 5.90* 222.75 388 87 *37 *0 2 07026 3 .* 3 2 3 320 11.00 50 000 509.670 5.851. 0. 17081 5.577 235.75 394 87 **5 *8 2 08626 3.432 796 1*18

60 000 519.670 5.630 17762 5.290 248.50 400 71 *53 33 2 1015? 0.433 7 75 1*35

70 000 529. 67C 5.1.27 13*25 5.035 261. 02 *06 *1 *61 00 2 1161 3 0.1.35 3 758 1*52

80 000 539.670 5.21.3 19072 *.807 273.29 *12 OC *68. 51 2 13018 0.1.37 7** 1*69

100. 000 559.670 *.920 20325 4.416 297. 11* *22 93 *83 15 2 15683 0.4*1 a 722 1501

120 000 579.670 i. .61.5 21531 *. 092 320. 13 *33 63 *97 *2 2 18168 0.**6 706 1532

l«t0 000 599.670 *.*06 22697 3.818 31.2. 31 *** 19 51 1 *3 2 ?0565 0.452 3 696 1562

160 000 619.670 4.196 23831 3.583 363.77 *5* 66 525, 27 2 22834 0. i*58 688 1591

180 ,Cu0 639.670 it. 010 2*936 3.378 384.57 *65 n 538 99 2 25013 0.*66 3 68* 1618

200 000 659.670 3. 3i«4 25017 3.199 1.0*. 78 *75 57 552, 65 ? 27116 .473 532 16**

220 000 679.670 3.693 27076 3.039 4 2 4 .

i* 6 *86 07 566 29 2 29153 0.1.81 63? 1670

2*0 000 699.670 3.557 23117 2. 897 1*1*3. 65 *96 63 579 93 2 31132 0. 489 3 633 169*

28 000 739.670 3.317 33152 2.653 1.80.79 518 03 607 36 2 31*91*3 0.507 c89 171.0 320, 000 779.670 3.112 c 3213* 2.1*50 516.1*8 539 88 635 08 2 38593 0.525 3 698 1784

360 000 819.670 2.935 3*073 2.279 550.99 562 26 663 22 -> 1*2112 0.543 3 709 1826

1*00 000 859. 670 2. 779 o, 35978 2. 132 581.. ug 585. 2? 691. 82 2 *5519 0.561 3 722 1866

1*1*0 000 399.670 2.61.2 37853 2.005 617. 15 608 81 720 96 ? *d832 0.580 3 f35 1904

254
METHANE ISOBAR AT P = 1700.0 PS I

T T OEN VOL DP/DT OP/OO E H S cv CP W OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB 8TU/LB BTU/LB/R BTU/LB/R BTU/L3/R FT/S

291.109 168.561 28.1*18 0.03519 164.039 3836. 32 94 16 105.24 1. 01860 .506 777 5225 290.000 169.670 28.361 0.03526 162.831 3800. 03 95 02 106.12 1.02403 .505 778 5206 280.000 179.670 27.931 0.03580 152.730 3533.40 102 .43 113.70 1.06885 .507 0, 788 5047

270.0 00 189.670 27.1*96 0.03637 143.177 3269.26 110 04 121.49 1. 11184 508 799 4882 260.000 199.670 27.055 0.03696 134.141 3011.57 117 80 129.44 1.15313 ,506 308 4719 250.000 209.670 26.605 0.03759 125.583 2763. 01 125 66 137.51 1. 19260 ,502 815 4559

240. 000 219.670 26.11*5 0.03825 117.461 2525.33 133 62 145.66 1.23091 ,496 0. 321 4402 230.000 229.670 25.671* 0.03895 109.732 2299.46 141 63 153.89 1.26758 .489 827 4244 220.0 00 239.670 25.190 0.03970 102.363 2085.93 149 70 162.20 1.30 301 ,464 636 4064 210.000 21*9.670 21*. 692 0.04050 95.319 1884.65 157 86 170.60 1.33738 .461 347 3920 200.000 259.670 21*. 178 0.04136 86.574 1695.30 166 12 179.11. 1.37069 .479 860 3754 190.000 269.670 23.6i*7 0. 04229 82. 103 1517. 34 174 50 187.81 1.40 365 .478 374 3588 160.000 279.670 23.095 0.04330 75.884 1350.14 182 99 196.62 1.43573 ,473 388 3424 170.000 289.670 22.521 0.04440 69.901 1193. 06 191 56 205.55 1.46711 ,466 399 3266

160.000 299.670 21.922 0. 0*562 64.137 1045.64 200 23 214.59 1.49778 454 908 3113

150. 000 309. 670 21. 293 0. 04696 56.579 907.56 208 ,94 223.73 1.52777 ,442 320 2959

140. 000 319.670 20.629 0. 04847 53.218 778.83 217 80 233.06 1.55741 ,442 3 948 2782 130.000 329.670 19.921* 0.05019 46.048 659.74 226 88 242.68 1.58702 ,438 977 2609 120.000 339.670 19.170 0.05217 43.071 550.89 236 20 252.62 1.61673 437 1 913 2434

110. 000 31*9.670 18.357 0.05447 38.299 453.11 245 82 262.97 1.64675 .436 1 058 2257

100. 000 359.670 17.1*76 0.05722 33.756 367. 34 255 80 273.82 1.67733 4 37 1 113 2083 -90.000 369.670 16.516 0.06055 29.477 294.36 266. 21 285.27 1.70874 439 1 179 1915 -80.000 379.670 15.1*72 0.06463 25.502 234.68 277 0° 297.44 1.74121 441 1 255 17?8

-70. 000 389.670 li+. 31*7 0.06970 21.876 186.71 288 44 310. 38 1.77486 444 1 333 1620 -60.000 399.670 13.169 0.07594 18.650 157. 31 300 11 324.02 1. 60941 443 1 3 86 1511 -50.000 •09.670 12.006 0.08329 15.904 141. 75 311 70 337.92 1.84376 .442 1 381 1432 -40.000 1.19.670 10.954 0.09129 13.705 140. 67 322 66 351.39 1. 87626 441 1. i06 1389

-3 0.000 1*29.670 10.057 0.09943 12.002 145.51 332. 7C 364.00 1.90596 .439 1 218 1368 -20.000 1*39.670 9.296 0.10758 10.664 151.96 341 93 375.79 1.93308 ,4 37 1 142 1356 -10.000 1*1*9.670 8.61*7 0.11565 9.592 160. 21 350 47 386.87 1.95801 . 435 1 975 1354 0.000 "59.670 8.091* 0.12355 8.722 171. 14 358. 41 397.30 1.98095 434 1 312 1359

10.000 1*69.670 7.622 0.13120 6.009 183.63 365 63 407.13 2.00213 433 956 1370 20.000 1*79.670 7.217 0.13857 7.416 196.62 372 83 416.45 2. 02174 433 910 1384 30.000 1*89.670 6.861* 0.11+569 6.916 209.69 379. 49 425.35 2. 04011 433 372 1399

<»0.000 499. 670 6.351* 0.15258 6.487 222. 66 385 87 33.90 2.05740 433 340 1415

50. 000 5P9.670 6.279 0.15926 6.115 235.48 392 03 442.17 2.07378 ,434 814 1431 60.000 519.670 6.033 0.15576 5.789 248. 12 398, 01 450.19 2.08937 435 792 1447 70.000 529.670 5.811 0.17209 5.500 260.56 403 85 458.02 2.10428 4 36 0. 7 73 146 3 80.000 539.670 5.610 0.17827 5.243 272.80 409 56 465.67 2. 11860 438 0. 758 1479

100. 000 559.670 5.257 0.19023 4.804 296.67 420 70 480.58 2.14572 44? 734 1510 120.000 579.670 i*.957 0.20173 4.441 319.76 431 57 495.07 2.17117 447 0. 717 1541

It; 0, 000 599.670 4.698 0.21285 4.135 342. 10 442. 27 509.26 2.19526 .453 705 1570 160.000 619.670 i». 1*71 0.22365 3.874 363. 74 452. 86 523.28 2. 21823 460 0. 696 1598 180.000 639.670 4.270 0.23418 3.648 384.74 463. 43 537.15 2.24027 467 a. 691 1625 200.000 659.670 i*. 091 0.24446 3.449 405. 17 473, 99 550.95 2.26150 474 0. 689 1651

220. 000 679.670 3.92 9 0.25454 3.274 425. 06 484. 56 564.71 2.28205 482 0. 088 1676

21*0.000 699.670 3.782 0.26443 3. 117 444. 46 495. 22 578.46 2. 30200 490 0. 688 1700 280.00 739.670 3.524 0.23375 2.849 461.99 516. 76 606.08 2.34039 508 0. 693 1747

320. 00 779.670 3.305 0.31254 2.628 518. 05 538. 73 633.97 2.37710 525 0. 702 1790 360.000 819.670 3.116 0.32092 2.442 552.88 561. 22 662.25 2.41246 544 0. 712 1832

1*00.000 859.670 2.95 0. 33895 2.282 536.67 584. 28 690.98 2. 44669 562 0. 725 1872

1*1*0. 00 899.670 2.804 0.35670 2.144 619.59 607. 94 720.22 2.47993 580 a. 738 1910

255
METHANE ISOBAR AT P = 1800.0 PSI

T T OEN VOL CP/OT op/no E H 3 CV CP W OEG F OEG R L8/CUFT CUFT/LB PSI/R FSICUFT/LB BTU/LE 3TU/IB BTU/LB/R RTU/L8/R BTU/L^/R FT/S

290. 800 168.870 28 "31 03517 163.875 38*8. 07 9* 23 105, 95 1 01903 0.507 0, 777 5228

290. 000 169.670 28 388 0. 03523 162.993 3820. C9 9*. 86 106. 61 1. 023C5 0.506 0. 777 5213

280. 000 179.670 27 95 9 0. 5577 152.9** 3555. 72 102 26 1 1* 18 1 06763 0.507 0. '87 5056

270. 000 189.670 27. 527 0. 03633 1*3. *38 3293. *3 109. 85 121. 96 1. 11077 0.509 0. 798 *89*

260, 000 199.670 27 088 0. 3692 13*.**7 3037, 28 117 6C 129 90 1 15201 0.507 0. 307 *732

250. 000 209.670 26 6*1 0. 0375* 125.932 2790. 02 125, *5 137 96 1 19162 0.503 31* *57*

2*0, oco 219.670 26 18* 0, 03819 117.852 2553. ** 133. 37 1*6, 09 1 22966 0.*96 0. 819 **18

230. 000 229.670 25 717 0. 03888 110. 166 2328. 56 1*1. 3* 15*. 3C 1 26625 O.*90 825 *262

220. 000 239.670 25 238 03962 102.8*0 2115. 88 1*9 36 162 59 1 30153 0.*85 0. 333 *10*

210. 000 2*9.670 ZU 7*5 p, 0*0*1 95. 8*1 191^. *1 157. 5C 170. 97 1 33586 0.*82 3** 39*2

200. 000 259.670 2* 237 0, 0*126 89.1*3 1726. 67 165. 72 179 *8 1 36925 0.*80 0. 357 3779

190. 000 269.670 23 712 o. 0*217 82.721 15*9. 72 17* 06 188 11 1 *0 188 0.*78 370 3615

160. 000 279.670 23 168 0. 0*316 76.556 1383. 37 182 *° 196 88 1 *3380 0.*7* 383 3*55

170. 000 289.670 22 60* 0. 0**2* 70.629 1227. 20 191. 02 205. 76 1 *6500 .*66 393 3300

160. 000 299.670 22 016 0. 0*5*2 6*. 928 1080. 71 199 59 21*. 73 1 *95*5 0.*55 0. •901 3151

150. 000 309.670 21 "01 0. 0*673 59.*39 9*3 59 208 22 223 79 1 52516 0.**3 9 911 3000

1*0. 000 319.670 20 755 0. 0*818 5*. 155 615. 76 216 97 233 03 1 55**9 0.**2 936 2828

130. 000 329.670 20 072 0*982 *9.070 697, ** 225. 91 2*2. 51 1 58371 0.*39 0. 962 2662

120. 000 339.670 19 3*5 0, 05169 **.186 589. 12 235. 05 252. 28 1 61290 0.*36 993 2*93

110. 000 3*9. 670 18 569 05385 39.51* *91. *9 2** *6 262, *1 1 6*227 0.*36 1 932 2323

100. 000 359.670 17 735 0, 05639 35.07* *05. 32 25* 16 272 95 1 67 201 0.*36 1 379 2156

-90. 000 369.670 16 836 0. 059*0 30.893 331. 27 26*. 21 28*. 00 1 70231 .*37 1 133 199*

-80. 000 379.670 15 869 0. 06301 27.008 269. 72 27* 63 295. 6* 1 73335 0.*39 1 19* 18*3

-70, 000 389.670 1* 836 057*0 23.**9 220. 87 285. *3 307 90 1 76522 0.**2 1 258 17C7

-60. 000 399.670 13 755 0. 07270 20.252 185. 00 296. 51 320. 7* 1 79777 O.**0 1 307 1596

-50. 000 *09.670 12 666 07895 17.*63 162 78 307 63 333 9* 1 83039 O.**0 1 326 15C7

-<t0. 000 "19.670 11 63* 0, 08596 15. 127 15*. *5 316. *? 3*7. 07 1 36205 0.*39 1 290 1**9

-30 000 "29.670 10 720 09328 13.262 156 *6 328 52 359 61 1 89159 0.*38 1 217 1*18

-20. 000 "39.670 9 93"+ 0, 19067 11.785 161. 79 337 6f 371 *1 1 91875 0.*37 1 1*5 1*02

-10. 000 * "9.670 q 256 19803 10.595 16* 36 3*6 5* 362 55 1 9*380 0.*36 1 9 8* 1393

0. 000 •59.670 6 670 1153* 9.621 176. *6 35* 67 393 11 1 96702 0."«35 1 329 1391

10 000 "69.670 8 163 12251 8.816 166 89 362 30 *03 13 1 98659 0.*3* 9 977 1396

20 000 "79.670 7 723 129*9 8.1** 198. 76 369. 5C *12. 6f 2 00863 0.*3* 931 1*06

30. 000 "89.670 7 339 13625 7.577 211. 19 376 35 *21 77 2 027*5 0.*3* 391 1*18

*0 000 "99.670 7 002 0. 1*281 7. 092 223. 76 382 91 *30 51 2 0*51* 0.*3* 3 358 1*32

50. 000 509.670 6 703 1*919 6.673 236. 31 389 23 *38 95 2 06ieb 0.*35 J 331 1**6

bO 00 519.670 6 "36 15539 6.306 2*8, 75 395 3* **7 1* 2 07777 . * 36 307 1*6 1 70 000 529.670 6 195 0. 151*3 5.982 261. 0* *C1 3C *55 11 2 09297 0.*37 0. 788 1*76

80. 000 539.670 c 976 0. 1573* 5.695 273 16 *07 13 *62 90 2 1075* 0.*39 771 1*91

100. GOO 559.670 c 59* a. 17877 5.20* 296. 96 *18 *7 *78 06 2 13512 0. **3 3. '*5 1521

120. 000 579.670 5 270 13976 *.80C 320. 0* *29 51 *92, 76 2 1609* 0.**8 0. 727 1550

1I»0. 00 599.670 * 990 0. 29039 *.*62 3*2. ** **0 36 507. 16 2. 18535 0. *5* 9. 713 1579

160. 000 619.670 * 7*6 0, 21070 "..173 36* 20 *51 10 521 33 2 20859 0.*61 0. 70* 1605

180. 000 639.670 * 530 0. 22075 3.92* 385. 35 *61 77 5 3 5. 3

= 2. 23086 0.*68 598 1633

200, 000 659.670 "» 337 2 3056 3.706 *05. 93 *72 *2 5*9. 27 2, 25230 0.*75 3 695 1658

220. 000 679.670 it ,16-t 0, 2*017 3.513 *25. 99 *83. 1C 563. 15 2. 27303 0.*83 9. 693 1683

21*0. 000 699.670 * 006 0. 2*960 3.3*2 **5. 57 *93 83 577 02 2 29 31* 0.*91 3. r>9* 1707

260. 000 739.670 3 731 0. 26799 3.050 *83 ** 515 5C 50*, 83 2 33 179 0.508 598 1753

320. 000 779.670 3 *98 0. 28588 2.809 519. 83 537. 59 632. 66 2 36872 0.526 9, 705 1797

360 000 619.670 3 297 0. 30335 2.607 55*. 95 560. 16 661. 29 2 *0*26 0. 5*5 0. 716 1838

•00 000 859.670 3 120 0. 320*7 2.*3* 589. 02 583 33 690 15 2 *3862 0.563 3. '27 1878

**0. 000 899.670 2 965 0. 33732 2.285 622. 17 607. 07 719. 50 2, *7199 0.581 0. 7*0 1916

256
ME THANE ISOBAR AT P = 1900.0 PSI

T T DEN VOL DP/DT OP/DD r H S CM CP H DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/L8 BTU/LB 9TU/LB BTU/LP/R BTU/LB/R 8TU/L3/R FT/S

290.,490 169.180 28. 1*1*1* 0,,03516 163.712 3859.73 94,,30 106.67 1.01947 .507 0,,776 5231

290,iOOO 169.670 28.414 0,,01519 163.152 3839.92 94,,71 107.09 1.02207 0,.507 0,,777 5221

280.,000 179.670 27.987 0,,0 357 3 153.155 3577.82 102,,09 114.66 1. 06681 0,.508 0,, 787 5066

270. 000 189.670 27.557 0,,03629 143.696 3317.40 109,,66 122.43 1.10971 .509 0,,797 4905

260.,000 199.670 27.120 0,,03687 134.749 3062. 80 117,,39 130.36 1.15090 0,.508 0,, 306 4745

250.,000 209.670 26.676 0,,03749 126.276 2816.82 125,,22 136.41 1. 19045 .50 3 0,, 112 4569

21*0,,000 219.670 26.223 0,,03813 118.237 2581. 34 133., 11 146.53 1. 22842 0,, 497 0. 318 4435

230,,000 229.670 25.760 0,,03882 110.593 2357.41 141,,06 154.72 1.26493 .491 0,, 123 4260

220.,000 239.670 25.285 0.,03955 103.309 2145.58 149,,07 162.99 1.30018 0,.486 0,,331 4124

210,,000 249.670 24. 797 0.,04033 96.354 1945.90 157., 16 171.35 1.33435 0..483 0,, 341 396-

200.,000 259.670 24. 29* 0. 04116 89.700 1758. 13 165. 34 179.82 1. 36763 0,,481 0. 354 3803

190,,000 269.670 23.776 0,,04206 83.326 1581.76 173,,63 188.42 1.40014 0,.479 0,,367 3642

180. 000 279.670 23.240 0., 04303 77.211 1416.22 182,,01 197.15 1.43191 0,,475 0,,378 3484

170. 000 289.670 22. 684 0,,04408 71.339 1260.89 190,,47 2G5.98 1.46294 0,,467 0,,388 3333

160. 000 299.670 22.107 0. 04523 65.696 1115. 26 198. 98 214.90 1.49319 .455 0.,335 3167

150..000 309.670 21.505 0.,04650 60.271 979. 01 207,,52 223.88 1.52267 0,, 443 0,,903 3041 mo. 000 319.670 20.875 0.,04790 55.057 852. 01 216,, 17 233.02 1.55169 .443 3,,926 2673

130.,000 329.670 20.211 0., 04948 50.048 734.39 224,,96 242.39 1.58055 0,.439 0,,949 2712

120. 000 339. 670 19.510 o. 05126 45. 247 626. 55 233. 96 252.01 1.60929 0., 436 0., 376 2548

11C.,000 349.670 18.765 0,, 05329 40.662 529. 06 243,, 1° 261.94 1.63809 .435 1,, 010 2365

100. 000 359.670 17.971 0.,05565 36. 310 442.55 252.,65 272.23 1.66711 , ,435 1,, J50 2224

-90. 000 369.670 17.123 c,,05840 32.214 367.58 262,,40 282.95 1.69650 0,.436 1,,095 2068

-80. 000 379. 670 16-218 o. 05166 28.403 304.46 272,,46 294.15 1.72640 0,,438 1,, 146 1922

-70., 000 389.670 15.25 9 0.,05554 2"-. 902 253. 24 282,,82 305.87 1.75667 a .440 1,,196 1789

-60. 000 399.670 14.257 0.,07014 21.735 213.98 293,,41 318.09 1.78782 0,, 438 1,,242 1677

-50. 000 409.670 13.239 c,,07553 18.930 186. 65 304.,08 330.66 1. 81888 , , 438 1. 268 1583

-40. 000 "19.670 12.248 o. 03164 16.517 172. 11 314,,60 343.33 1.64944 .438 1,,259 1514

-30. 000 429.670 11.336 0. 03822 14.520 168.89 324..66 355.70 1.87858 , ,4 37 1. 210 1472

-20. 000 "39.670 10.532 0,,09495 12.910 172.54 334,, 06 3 6 7.48 1.90568 0,,437 1., 146 1448

-10. 000 ""9.670 9.834 0.,10169 11.608 178.17 342. 86 378.63 l."3077 0,,436 1. J87 1435

0. 000 "59.670 9.224 0., 13841 10.537 184. 83 351,, 10 389.24 1.95411 0,,435 1,,3 36 1428

10. 000 '69.670 8.690 0.,11508 9.645 192. 85 358. 86 399.37 1.97590 0,,435 3., 990 1427

20. 000 "79.670 6.221 0. 12164 8. 895 202. 83 366. 26 409.05 1.99631 0,,434 3., 9-7 1431

30. 000 "89.670 7.310 0.,12804 6.261 214. 16 373. 26 418.33 2. 01544 0,, 435 a.,9 08 1440

40. 000 "99.670 7.447 0.,13428 7.718 226.09 379.,99 427.24 2. 03345 0,,435 3. 875 1451

50. 000 509.670 7.125 0. 14036 7.249 238.22 386..45 435.84 2. 05049 , ,43b 3.,346 1464

60. 000 519.670 6.836 0., 14628 6.840 25C. 37 392. 71 -44.17 2.06669 0,,437 0,, 322 1477

70. 000 529.670 6.577 0. 15205 6.480 262.46 398. 79 452.28 2. 03216 0,, 438 0. 901 1451

80. 000 539.670 6.341 c.,15770 6.160 274.43 404.,73 460.21 2.09697 0,,440 0,,784 1505

100. 000 559.670 5.930 0. 1S863 5.616 298.00 416. 26 75.59 2.12497 0,,444 3,, 7 56 1533

120. 000 579.670 5.582 0.,17915 5.169 320. 98 427.,46 490.51 2.15116 0,,449 0,,736 1561 HC, 000 599.670 5.282 0. 13932 4.796 343. 37 439. 47 505. oe 2. 17587 0,,455 0,,722 1568

160. 000 619.670 5.020 0. 19919 4.479 365. 17 449. 33 519.41 2. 19938 0,,462 3, 712 1615

180.,000 639.670 4.789 0. 20880 4.206 386.40 460. 11 533.57 2.22188 0,,469 n. 705 1641

200. 000 659.670 4.583 0. 21819 3.967 407. 1C 470.,87 5-7.63 2.24352 0,,-76 3,,701 1666

220. 000 679.670 4. 398 0. 22737 3.757 427. 28 481. 63 561.63 2.26442 0,,484 0.,699 1691

240. 000 699.670 4.231 0..23638 3.571 447. OG 492. 44 575.60 2.28469 0,,492 0..699 1715

280. 000 739.670 3.933 0. 25394 3.253 485. 16 514..25 6C3.60 2.32359 0,,509 3. 732 1760

32 0. 000 779.670 3.690 0..27100 2.992 521.63 536.,46 631.81 2.36074 0,,527 0. 709 18C3

360. 000 819.670 3.476 0. 28765 2.774 557.22 559,,15 660.36 2. 39644 0,,545 3.,719 1845

<»00. 000 859.670 3.290 0. 33397 2.588 591.53 582.,39 689.33 2.43096 0,,564 3.,730 1884

1*1*0. 000 899.670 3.125 0. 3 2 2.427 624.91 606..20 718.79 2.46445 0,,582 3. 743 1922

257
METHANE ISOBAR AT P = 2300.0 PSI

T T DEN VOL DP/OT DP/DO E H S cv CP H DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LP 3TU/LB BTU/LB/R BTU/LB/R BTU/L3/R FT/S

290. 182 169. 488 28.457 03514 163.549 3871.29 94.37 107.38 1. 01991 5C8 3 776 5234

390. 000 169. 670 28.440 0. 03516 163.308 3859.51 94.56 107.58 1.02110 3 .509 0. 776 5228

280. 000 179. 670 28. 015 0. 03569 153. 362 3599.71 101.92 115.14 1.06580 509 786 5075

27 0, 000 189. 670 27.587 0. 03625 143.950 3341. 16 109. 4e 122.90 1. 10865 510 3 796 4916

260. 000 199. 670 27.153 0. 03683 135.046 3088. 10 117.18 130.82 1. 14980 509 305 4758

250. 000 209. 670 26.712 0, 03744 126.615 2843.42 124.99 138.86 1. 19929 504 811 46C3

240. 000 219. 670 26. 262 0. 05808 118.617 2609.02 132.86 146.97 1.22719 498 916 4451

23C. 000 229. 670 25.802 0. 03876 111.014 2386. 03 140.79 155.14 1.26363 .492 822 4298

220. 000 239. 670 25.331 0. 03948 103.771 2175. 04 149.77 163.39 1.29880 487 J 929 4144

210. 000 2 49. 670 2 4. 84 8 0. 0*025 96.858 1976.14 156.82 171.72 1. 33287 483 3 939 39e6

200. 000 259. 670 24.353 04107 90.248 1789.10 164.96 180.17 1.36605 .482 951 3827

190. 000 269. 670 23.833 0. 04195 83.919 1613.48 173.20 188.74 1. 39 84 3 480 0. 563 3668

180. 000 279, 670 23.310 0*290 77.852 1448.69 181. 54 197.43 1.43006 .475 374 3513

170. 00 J 289. 670 22.763 0, 04393 72. 031 1294. 15 189. 9* 206.22 1.46093 467 0. 382 3364

160. 000 299. 670 22.196 0. 04505 66.443 1149. 33 19P. 39 215.07 1.49098 . 456 888 3222

150. 000 309. 670 21.606 0. 04628 61.077 1C13. 87 206. 84 223.99 1. 52025 .443 3 895 3080

1*0. 000 319. 670 20.990 0. 04764 55.927 887.62 215. 4C 233.05 1.54900 ,443 317 2917

130. 000 329. 670 20 . 34* 0. 04915 5C987 770.65 224. 10 242.31 1.57753 439 937 2760

120. 000 339. 670 19.665 0. 05085 46.259 663.25 2 32.96 251.79 1.60587 436 3 361 2601

110. 000 349. 670 18.94 9 05278 41 .751 5b5.89 242. 00 261.55 1.63417 ,435 991 2443

100. 000 359. 670 18.183 0. 05498 37.476 479. 09 251.26 271.62 1.66258 435 1 325 2288

-90. 000 369. 670 17.382 0, 05753 33.454 403. 33 260.76 282.06 1.69120 435 1 ]64 2137

-80. 000 379. 67 16.529 0. 06050 29.706 338. 84 270.51 292.91 1.72016 ,436 1 107 1995

-70. 000 389. 670 15.631 05398 26.255 285.65 280.50 304.20 1. 7 4950 438 1 151 1865

-60. 000 399. 670 14.695 0. 0o805 23.118 243.63 290.70 515.90 1.77915 436 1 188 1754

-50. 000 409. 670 13.741 07278 20. 312 212.73 300.98 327.93 1. 90889 436 1 215 1657

-40. 000 419. 670 12.797 0. 07814 17.855 192.98 311.19 340.13 1.83830 436 1 220 15P1

-30. 000 429. 670 11.903 0. 03401 15.765 184. 10 321.12 352.23 1.86679 436 1 194 1526

-20. 000 439. 670 11.093 0. 09014 14.036 184.28 330.55 363.93 1. 89372 436 1 143 1496

-10. 000 449. 670 10.37 9 0. 09635 12.624 188.79 339.40 375.08 1.91880 4 36 1 "99 1478

0. 000 459. 670 9.752 0. 13255 11.460 194.64 347.73 385.71 1.94218 435 1 J39 1467

10. OOJ 469. 670 9. 193 0. 10872 10.487 201. 37 355.62 395.89 1.96407 435 996 1462

2C. 000 *79. 670 8.707 11485 9.664 209. 29 363.12 405.65 1. 98466 435 958 1461

30. 000 489. 670 8.272 0. 12089 8.964 218. 92 370. 28 415.05 2. 00404 435 922 1h65

40. 000 499. 670 7.886 0, 12681 8.363 229.79 377. 13 424.10 2.02234 436 889 147 3 50. 000 509. 670 7.542 0. 1 5259 7.843 241.28 383.73 432.84 2.03965 437 c 860 1483

60, 000 519. 670 7.234 13824 7.390 253. 00 390. 11 4 41.31 2.05611 438 935 1495

70. 000 529. 670 6.956 0. l-»376 6.992 264. 79 396. 31 449.55 2. 07182 439 914 1507

80. 000 539 670 6.704 14916 6.638 276.54 402.35 457.59 2. 08686 441 '95 1520

100. 000 559. 670 6.265 0. 15962 6.038 299. 80 414. 08 473.20 2.11526 445 '67 1546

120. 000 579 670 5.893 16970 5.548 322. 60 425.45 488.30 2.14179 450 '•.5 1573

140. 000 599 670 5.573 0. 17945 5.139 344. 90 436.59 503.05 2. 16680 456 3 730 1599

160. 000 619 670 5.294 18891 4.792 366.67 447.57 517.54 2. 19056 463 3 719 1625

180. 000 639 670 5.047 19812 4.494 387.93 458.47 531.84 2.21328 470 3 712 1650

200, 000 659 670 4. 828 20711 4.234 409.68 469.32 546.02 2.23511 477 3 707 1675

220. 003 679. 670 4.632 0. 21590 4.006 428. 95 480. 17 560. 13 2.25618 .485 3 f 04 1699

240. 000 699. 670 4.454 22453 3.803 448.77 491. Of 574.21 2.27660 493 0, 704 1722

28 0. 000 7 39 670 4.144 0, 24133 3.460 487. 15 513.01 602.39 2.31576 510 3, 706 1767

320, 000 779. 670 3.981 0, 25765 3.178 524.06 535.34 630.76 2.35311 528 0. 713 1810

360 000 819. 670 3.655 27356 2.943 559.69 558.13 659.44 2.38899 546 3 722 1851

400. 000 859. 670 3.458 0. 23915 2.743 594.22 581.45 688.54 2.42364 565 733 1891

440. 000 899. 670 3.285 33445 2.570 627.80 605. 35 718.10 2.45725 583 0. 745 1929

258
METHANE ISOBAR AT P = 2200.0 PSI

T T DEN VOL DP/DT DP/DO E H S cv CP W DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LE 9TU/LB BTU/LB/R BTU/LB/R BTU/L3/R FT/S

289.,565 170.105 28.<+83 0.,03511 163.228 3894. 16 94.,51 108.,81 1,,02080 0,,510 0.,775 5239

280.iOOO 179.670 26.070 0,,03562 153.766 3642.84 101,,59 116,,10 1,,06381 0,,510 0,,784 5093

270. 000 189.670 27.646 0., 03617 11+4.446 3388. 07 109. 11 123,,85 1,.10657 0.,512 0,,795 4938

26 0,,000 199.670 27.217 0,,03674 135.628 3138.12 116,,78 131.,75 1,,14762 0,,510 0,,803 4783

250,,000 209.670 26.782 0,,03734 127.279 2896. 01 124,,55 139,,76 1,, 18700 0,,506 3,, 309 4632

ZkO,iCOO 219.670 26.338 0,,03797 119.360 2663.78 132.,38 147,,84 1,,22477 0., 499 0., 313 4482

230. 000 229.670 25. 885 0.,03863 111.836 2442.64 140,,25 155,,99 1,.26107 0,, 493 0,,318 4333

220,,000 239.670 25.422 0,,03934 104.672 2233.27 148,,17 164,,19 1,,29608 , .488 0,,325 4182

210.,000 249.670 24.947 0., 04008 97.839 2035.85 156., ie 172,,49 1,,32997 0,,485 0,, 334 4028

200,,000 259.670 24.460 0,, 04088 91.312 1850.22 164., 23 180.,88 1,,36294 0,,483 0.. 845 3873

190. 003 269.670 2 3.96 0,,04174 85.069 1675.97 172,,39 189,,39 1,,39510 0,,481 a,,857 3719

180,,000 279.670 23.445 0.,0+265 79.092 1512.57 180,,63 198,,01 1,,42647 0,,477 0,,366 3569

170. 000 289.670 22.914 0,,04364 73.366 1359.46 188,,93 206,,71 1,, 45704 0,,469 0,,373 3426

160.,000 299.670 22.365 0, 0-+471 67.878 1216.09 197. 25 215.,46 1,.48675 0., 457 0.,3 77 3289

150. 000 309.670 21.795 0,,04588 62.619 1082.07 205,,56 224,,25 1,,51561 0.,445 0,, 382 3154

140. 000 319.670 21.207 0,,04716 57.582 957. 15 213,,95 233,,16 1,,54388 , ,444 n,,933 2998

130.,000 329.670 20.592 0,,04856 52.763 841. 31 222,,46 242,,24 1,,57184 0,.440 0,, 916 2850

120.,000 339.670 19.951 0. 05012 48. 162 734.68 231. 08 251. 50 1.,59949 0.,437 0., 936 2700

110.,000 349.670 19.280 0,,05187 4 3.78 3 637.57 2 39,,84 260,,97 1,,62696 0.,435 0,,959 2552

100. 000 359.670 18.577 0.,05383 39.636 550. 32 248,,75 270.,68 1,,65436 0,,434 3,, 985 2405

-90. 000 369.670 17.839 0,,05606 35.734 473.25 257.,84 280,,68 1,,68177 0,,434 1,,3 14 2264

-80. 000 379.670 17.067 o. 05859 32. 092 406. 53 267. 11 290. 9e 1. 70926 0.,435 1,, J46 2129

-7 0.,000 389.670 16.262 0.,05149 28. 723 350. 13 276, 55 301,,60 1,,73667 0,,436 1,, 078 2004

-60. 000 399.670 15.429 0.,06481 25.639 303. 82 286., 12 312,,53 1.,76457 0,,433 1,, 136 1896

-50. 000 409.670 14.573 0. 06860 22.846 267. 3« 295. 77 323,,71 1,,79221 0,,433 1.,133 1797

-k0. 000 •+19.670 13.726 0. 07285 20.349 240. 42 305. 42 335,,10 1,,81965 0., 434 1,, 144 1714

-30.,000 429.670 12.893 0,,07756 18. 154 222. 78 314, 9T 346,,54 1,,84661 0,,434 1,, 142 1646

-20..000 439.670 12. 104 0,,03262 16.260 213.93 324.,22 357, 88 1,,87 268 0,, 434 1,, 121 1599

-10. 000 449.670 11.379 0,, 03788 14.656 212.72 333,,11 368.,91 I,,89751 , ,435 1. 3 84 1568

0. 000 459.670 10. 727 0. 09322 17. 313 216. 33 341,,5£ 379.,54 1,,92088 0,, 435 1,,341 1549

10. 000 469.670 1C. 145 0,, 9857 1?. 185 221.65 349,,59 389,,74 1,,94264 0.,435 1,,331 1537

20. 000 479.670 9.624 0,, 13390 11.226 227.79 357. 25 399. 58 1,,96356 0,, <+36 0,,966 1530

30. 000 489.670 9.157 0,,10921 10.404 234.60 364., 59 409.,08 1.,98317 0., 4 36 0.,935 1526

40. 000 499. 670 8.736 o. 11447 9.692 242. 37 371,,66 418,,29 2,,00179 0.,437 0,, 337 1526

50. 000 509.670 8.356 0,,11968 9.073 251. 44 378,,47 + 27,,23 ? ( .01950 0,,•38 3,, 881 1530

60, 000 519.670 8.012 0,,12481 8.530 261.56 385,,07 . 435,,91 2,,03638 0,, 440 3,,357 1537

70. 000 529.670 7.702 0.,12984 8.053 272.29 391. 47 + 44. 37 2., 05249 0., 441 0. 335 1545

80. 000 539.670 7.420 0,, 13478 7.630 283. 31 397,,71 452.,62 2,,06793 0.,443 0,, 316 1555

100. 000 559.670 6.926 0., 1+438 6.914 305.61 409, 80 468, 62 2,,09704 0,, 447 0,, 785 1577

120. 000 579.670 6. 508 0,, 15366 6.331 327.82 421, 48 484.,06 2,, 12419 , ,452 3,,762 1600

140..000 599.670 6.149 0.,16263 5.847 349. 73 432. 89 4^9. 14 2,, 14974 0. i+58 0. 7 45 1624

160.,000 619.670 5.836 0,,17135 5.438 371.28 444. 11 513,,92 2,,17398 0,,465 0,,733 1647

180. 000 639.670 5.560 0. 17985 5.087 392.41 455. 22 528. 48 2,,19711 0.,472 a., 724 lb71

200. 000 659.670 5.315 0,,13 813 4.783 413. 13 466. 26 542,,90 2 , ,21931 0,,479 3,, *18 1694

?20. 000 679.670 5.096 0. 19624 4. 516 433. 44 477. 29 557. 2 3 2..24 071 0. 487 3. 715 1717

24 0..000 699.670 4.897 0..20419 4.281 453. 34 488., 33 571,,51 2

,

,26141 0,,-95 3., 713 1740

280. 000 739.670 4.552 0,,21967 3.882 492. CO 510,,5( oOO.,05 2,,30107 , ,512 3,, 714 1783

320. 000 779.670 4.261 0.,23468 3.557 529.24 533,,11 628,,72 2,,33882 0,,530 3,,''20 1825

360. 000 819.670 4. Oil 0. 24931 3.2 87 565. 24 556. 1C 657. 67 2. 3750 3 0,,548 0,, 728 1866

1*00, 000 859.670 3.793 0,,26361 3.058 600. 13 579. 6C 686,,9° 2,,40996 0.,566 0,,738 1904

l*l*0, 000 899.670 3.602 0.,27765 2.861 634. 05 603. 65 716,,76 2,,44380 , ,584 3,, 750 1942

259
ME thane ISO*!AR I T P = 2400.0 PS I

T T DEN VOL CP/DT OP/OD F H S rv CP H DEG F DEG R L6/CUFT CUFT/LB PSI/R PSICUFT/LB 9TU/LF 9TU/LB BTl'/LB/R BTU/LB/R BTU/L9/R FT/S

286. 951 170. 719 28. 508 0. 03508 162.910 3916.65 94. 66 110. 25 1. 02168 0. 511 1. 775 5245

280. 000 179. 670 28 125 0. 03556 154.158 3685. 11 101. 26 1 17 06 1, 06164 512 3. "83 5111

270. 000 189. 670 27. 705 0. 5609 144. 928 3434. 15 108. 76 124. 80 1 10452 513 0. 793 4959

260. 000 199. 670 27 280 0. 03666 136.194 3187.33 116. 3° 132 68 1 14548 512 3. 301 4807

250. 000 209. 670 26 850 0. 03724 127.924 2947. 81 124 12 143 67 1 18475 507 0, 306 4659

240. 000 219. 670 26, 412 0. 03786 120.082 2717.73 131. 90 1 + 6 73 1. 22243 501 3. 410 4513

230. 000 229. 670 25. 966 0. 03851 112.634 2498. 43 139. 72 156. 84 1 25857 ,495 0. 315 436 7 220. 000 239. 670 25, 510 0. 03920 105.545 2290.63 147. 5Q 165. 01 1 29342 489 3. 321 4219

210. 00 249. 670 25 044 0, 03993 98.789 2094.61 155 52 173, 26 1 32715 486 3 3 30 4069

200. 000 259. 670 24 567 0. 04071 92.340 1910.29 163 52 181 61 1 35993 .4 94 0, 340 3918

190. 000 269. 670 24. 077 0- 04153 86. 177 1737. 30 171 61 190 06 1 39168 482 3. 351 3767

180. 00] 279. 670 2Z 574 0, 04242 80.282 1575. 16 179 77 198 62 1 42301 + 78 3 859 3622

170. 000 289. 670 23 057 0. 0+337 74.641 14 2 3.30 187 97 207 24 1 45331 470 3, 365 3484

160. O0Q 299. 670 22 525 0, 04440 69.243 1261.20 196 17 215 90 1 48271 458 367 3353

150. 000 309. 670 21, 976 0. 04550 64.078 1148.42 204, 36 224 59 1 51121 446 370 3223

1«»0. 000 319. 670 21 408 0, 04671 59. 138 1024. 64 212 61 233 37 1 53907 445 3, 386 3074

130. 000 329. 670 20 821 0, 04803 54.421 909.76 220 94 242 2 Q 1 c 6655 440 0. 899 2933

120. 000 339. 670 20 211 0. + 948 49.925 803.81 229. 36 251. 35 1 59363 437 3. 315 2791

110. 000 349. 670 19 578 0, 05108 45.653 706. °2 237 89 260 59 1 62043 435 0, 933 2650

100. 000 359. 670 16 919 0, 05286 41.609 619. 33 246 53 270 02 1 64703 434 3. 954 2512

-90. 000 369. 670 16 234 0, 05464 37.803 541. 25 255. 3f 279 68 1 67351 .433 377 2378

-80. 000 379. 670 17 52 5 0. 05707 34.244 47?. 76 264. 2C 289- 57 1 6999J 433 1. J01 2250

-70. 000 389. 670 16 786 05957 30.941 413.86 273 23 299 71 1 72626 434 1. 326 2129

-60. 000 399. 670 16 029 0, 06239 27.901 364.26 ?82 3? 310 08 1 75255 431 1, J47 2024

-50. 000 409. 670 15 257 0, 06554 25.126 323.70 291 52 320 65 1 77867 431 1, )67 1926

-1*0, 000 419. 670 14 481 0. 06906 22.616 291. 76 300 70 331 39 1 80453 432 1. 331 1840

-30 000 429. 670 13 712 07293 20.370 266.09 309 8? 342 25 1 83013 432 1 387 176e

-20. 000 439. 670 12 966 0, 07712 16.385 252. 25 318 33 353 10 1 85511 433 1, 382 1709

-10. 000 449 670 12 259 08157 16.653 2 4 3.71 327 59 363 84 1 87926 434 1 3 64 1665

0. 000 + 59. 670 11 603 0. 31618 15. 161 241.61 336. 04 374 35 1 90237 474 1 336 1634

10 000 469 670 11 005 09087 13.867 244. ?5 34k If 384 54 1 92 4 30 3 435 1 3 02 1614

20 000 479. 67 10 464 0, 39556 12.798 249. 09 351 92 394 39 1 9+ 5 06 436 3 •J69 1602

30 000 489 670 9 975 0, 10025 11.861 254.82 359 36 + 03 93 1 96476 3 .437 9+0 159 + 40. 000 499. 670 9 531 0. 10492 11. 048 261. 12 366 57 413 20 1 98349 3 433 3 U4 1589

50 000 509. 670 9 127 13"56 10. 336 267.98 373 53 422 22 2 00137 439 391 1587

6C 000 519. 670 8 759 0, 11417 9.709 275.61 36C 28 + 31 02 2 0181.7 441 3 37C 1587

70. 000 529 670 8 422 0, 11874 9.154 284. 28 386 85 + 39 6? 2 03 4 86 44? 3. 350 1591

80. 000 539. 670 8 114 0. 12325 8.661 293.82 393 26 448 03 2 05059 444 3 332 1596

100 000 559 670 7 572 0. 13207 7.825 314. 36 405 65 464 35 ? 08028 + 49 0. 301 1612

120, coo 579 670 7 111 0, 14062 7.145 335. 59 417 62 + 80 11 7 10796 454 3, 777 1631

140. 000 599. 670 6 715 0, 1 + 892 6.582 356.88 429 26 + 95, 46 2 13 399 460 3. '59 1652

160 000 619. 670 6 370 15699 f .107 377.99 440 73 510 49 2 15865 466 3, '45 1673

180, 000 639. 670 6 066 0, 16485 5.701 398.82 452 03 525 30 2 18216 473 0. "36 1695

200 000 659. 670 5 796 0, 17253 5.350 4 19.34 463 26 539 ot 2 20470 3 481 3 72g 1716

220. 000 679, 670 5 .554 13005 5.043 439. 53 + 74 45 554. 47 2, 22640 488 0. 725 1738

240. 000 699 670 c 336 0. 18742 4.772 459. 37 485 64 568 93 2 24738 4°7 0. 722 1759

280 000 739 670 4 956 0, 23176 4.316 498. 05 508 14 5°7 80 2 28750 514 0, 7 ?2 1801

320. 000 7 79 670 4 637 0, 21566 3.946 535. 44 530, 92 626. 76 2 32563 531 0, "27 1842

36 GOO 819 670 4 363 0, 22920 3.639 571.65 5*4 11 655 97 2 36216 549 3. 734 1881

400 000 859 670 4 125 24243 3.379 606.78 577 76 685 52 2 39735 568 0. 744 1919

44 000 899 670 3 ,915 25540 3.158 640.96 601 96 715 48 2 43142 586 3. 755 1956

260
METHANE ISOBAR AT P = 2600.0 PSI

T T DEN VOL DP/DT DP/DO F H S CV CP W DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 3TU/LB iTu/ie BTU/LB/R BTU/LB/R RTU/L1/R FT/S

288.339 171.331 28.534 0.03505 162.596 3938.77 94 81 111.68 1.02257 0.513 774 5250 280.000 179.670 28.179 0.03549 154.536 3726. 52 100 94 118.03 1.05989 0.513 782 5128 270.000 189.670 27.763 0.03602 145.396 3479.44 108 41 125.75 1. 10250 0.515 791 4979 260.000 199.670 27.343 0.03657 136.744 3235.76 116 01 133.62 1.14337 0.513 799 4831

25 0.0 00 209.670 26.917 0.03715 126.551 2998. 84 123 7r 141.58 1.18254 0. 509 3 304 4686 240.000 219.670 26.485 0.03776 120.784 2770.90 131 44 149.62 1.22008 0.502 3 408 4543 230.000 229.670 26.045 0.0 1839 113.408 2553. 40 139 21 157.70 1.25612 0.496 812 4400 220.000 239.670 25.596 0.03907 106.393 2347.14 147 03 165.84 1.29063 0.491 818 4256 210.000 249.670 25.133 0.03978 99=709 2152.48 154 90 174*05 1.32 44 0.488 326 4109 200.000 259.670 24.670 0.04054 93.333 1969.38 162 84 182.35 1.35701 0.486 335 3961 190.000 269.670 24.190 0.04134 87.244 1797.55 170 85 190.76 1.38876 0.484 845 3814 180.000 279.670 23.699 0.04220 81.426 1636.54 178 93 199.25 1.41968 0.479 0. 853 3673 170.000 289.670 23.195 0.04311 75.863 1485.80 187 05 207.81 1.44973 0.471 357 3539 160.000 299.670 22.677 0.04410 70.546 1344.81 195 16 216.39 1.47885 0.459 358 3413 150.000 309.670 22.145 0.04516 65.464 1213.11 2C3 23 224.97 1.50704 .447 360 3289 140.000 319-670 21.598 0.04630 60.610 1090. 33 211 35 233.64 1.53454 0.446 373 3146 130.000 329.670 21.033 0.04754 55.981 976.28 219 53 242.42 1.56160 0.441 384 3011 120.000 339.670 2O.<*50 0.04890 51.574 870.90 227 78 251.33 1.58820 0. 438 397 2876 110.000 349.670 19.848 0.05038 47.390 774.23 236 12 260.37 1.61445 0.435 912 2741

100. 000 359.670 19.226 0.05201 43.432 686. 39 244. 54 269.58 1.64 40 0. 434 329 2609 -90.000 369.670 18.583 0.05381 39.704 607.51 253 05 278.96 1.66613 0.433 947 2481 -80.000 379.670 17.919 0.05581 36.213 537.63 261. 66 288.53 1.69167 0.433 3 967 2359 -70.000 389.670 17.236 0.05802 32.965 476.69 270 37 298.30 1.71707 0.433 987 2243

-60. 000 399.670 16.537 0. 06047 29.962 424.48 279. 14 308.2^ 1.74229 0.430 1 302 2141 -50.000 409.670 15.826 0.06319 27.205 380.68 287. 94 318.36 1.76726 0.430 1 318 2045 -40.00 419.670 15.110 0.06618 24.691 344.90 296. 75 328.61 1.79199 0.430 1 332 1958 -30.000 429.670 14.398 0.05946 22.418 316.73 305, 53 338.97 1. 81639 0.431 1. 340 1882 -20.000 439.670 13.698 0.07300 20.379 295.75 314 24 349.38 1.84034 0.432 1 341 1818 -10.000 449.670 13.023 0.07679 18.566 281.47 322. 79 359.76 1. 86368 0.433 1 3 34 1765 0.000 459.670 12.382 0.08076 16.971 273. 36 331. 15 370.03 1. 88627 0. 434 1 018 1725 10.000 469.670 11.784 0.08486 15.578 270.74 339. 25 380.11 1.90796 0. 435 996 1695

20. 000 479.670 11.232 0.09903 14.370 272.49 347. 07 389.94 1.92866 0.436 969 1676 30.000 489.670 10.728 0.09321 13.322 276.82 354, 62 399.49 1.94838 0.437 942 1663 40.000 499.670 10.26 8 0.09739 12.411 282. 20 361. 90 408.79 1.96717 0.438 917 1654 50.000 509.670 9.847 0.10155 11.611 288. 16 368. 96 417.85 1.98513 0.440 0. 395 1648 60.000 519.670 9.461 0.10570 10.905 294.58 375. 81 426.70 2.00233 0.442 376 1645 70.000 529.670 9.106 0.13982 10.27 8 301.46 382, 49 435.37 2. 01885 0.443 0. 358 1644 80.000 539.670 8.778 0.11392 9.718 308.97 389. 02 443.87 2.03474 0.446 842 1645 100.000 559.670 8.197 0.12200 8.763 326. 40 401. 67 460.41 2. 06484 0.450 0. 313 1653 120.000 579.670 7.699 0.12989 7.985 345.94 413. 89 476.42 2. 09296 0.455 0. 789 1667 140.000 599.670 7.269 0.13758 7.340 366. 24 425. 77 492.01 2.11940 0.461 0. 771 1683 160.000 619.670 6.893 0.14507 6.797 386.71 437. 43 507.27 2. 14444 0.468 0. 756 1702 180.000 639.670 6.563 0.15238 6.334 407.08 448. 93 522.29 2.16829 0.475 0. 746 1721 200.000 659.670 6.269 0.15952 5.934 427.26 460. 33 537.13 2.19114 0.482 738 1741 220.000 679.670 6.005 0.16652 5.585 447.20 471. 66 551.85 2.21311 0.490 734 1761 240.000 699.670 5.768 0.17338 5.277 466.86 483. 01 566.48 2.23434 0.498 3. 731 1781

280. 000 739.670 5.355 0. 18674 4.761 505. 35 505. 76 595.67 2.27490 0.515 a 729 1821 320.000 779.670 5.008 0.19968 4.343 542.70 528. 7£ 624.90 2.31339 0.533 0. 733 1860

36 . 819.670 4.711 0.21228 3.997 578.97 552. 14 654.34 2. 35022 0.551 0. 7 40 1898

40 0.0 00 859.670 4.453 0.22459 3.707 614.22 575. 9e 684.11 2.33567 0.569 3. 749 1935

440. 000 899.670 4.226 0.23665 3.459 648.55 600. 33 714.26 2.41995 0.587 0. 759 1971

261
ME THANE ISOB AR AT P = 2800.0 PSI

T T OEM VOL DP/OT OP/DD F H S cv CP W DEG F OEG R L8/CUFT CUFT/LB PSI/R PSICUFT/LB 9TU/LP 3TU/L9 BTU/L9/R BTU/LB/R BTU/L3/R FT/S

287.728 171.942 28.559 0. 03501 162.287 3960. 54 94. 96 113.11 1.02346 0. 514 0.774 5255

280. 000 179.670 28.232 0.03542 154.901 3767. 06 100. 63 119.00 1.05797 0. 515 0.791 5145 270.000 189.670 27.820 0.03595 145.850 3523. 90 108. 07 126.70 1.10051 0. 516 0.790 4999 260.000 199.670 27.404 0.03649 137.278 3283, 41 115. 63 134.55 1. 14129 0. 515 0.797 4855

250. 000 209.670 26. 983 0.03706 129.161 3C49. 10 123. 29 142.50 1. 18036 510 0.302 4712 240.000 219.670 26.557 0.03766 121.467 2823. 31 130. 99 150.51 1.21780 504 0.305 4572 230.000 229.670 26.123 0.03828 114.162 2607. 59 138. 7? 158.57 1.25 37 2 497 0.909 4433 220.000 239.670 25.681 0.03894 107.215 2402. 84 146. 49 166.68 1.28830 4q2 0.814 4291

210. 000 249.670 25.230 0.03964 100.601 2209. 48 154. 30 174.85 1. 32172 489 0.822 4147 200.000 259.670 24.770 0.04037 94.294 2027. 55 162. ie 183.11 1.35416 487 0. 331 4003

19 0.00 269.670 24.300 0. 0-*ll5 88.275 1856. 80 170. 13 191.47 1. 38573 485 0. 340 3860 180.000 279.670 23.819 0.04198 82.527 1696. 82 178. 14 199.91 1.41645 481 3. 947 3722

170. 000 289.670 23. 327 0. 04287 77.037 1547. 08 186. 17 208.40 1.44628 472 0.d50 3593 160.000 299.670 22.823 0.04382 71.793 1407. 08 194. 19 216.90 1.47515 460 0.350 3471 150.000 309.670 22.306 0.04483 66.785 1276. 31 20?. 16 225.41 1.50305 448 0.850 3352 140.000 319.670 21.776 0.04592 62.008 1154. 40 210. 16 233.97 1.53023 447 0. 362 3214

130. 000 329.670 21.231 0.04710 57.456 1041. 07 218. 22 242.64 1.55693 442 0.871 3084 120.000 339. 670 20.672 0.04838 53. 126 936. 19 226 32 251.40 1.58313 438 0. 382 2954 110.000 349.670 20.096 0.04976 49.017 839. 73 234. 49 260.29 1.60890 436 0.395 ?8?6 100.000 359.670 19.504 0.05127 45.131 751. 71 242. 72 269.30 1.63432 434 0.909 2700

-90. 000 369.670 18.896 0.05292 41.469 672. 19 251 0? 278.46 1.65943 433 0. 924 2577

-80. 000 379.670 18.271 0. 05473 38.035 601. 16 259. 40 287.78 1.68429 433 0.939 2459 -70.0 00 389.670 17.631 0.05672 34.832 538, 56 267. 84 297.25 1.7089? ,432 0.955 2348 -60.000 399.670 16.978 0. 05890 31.861 484. 18 276. 33 306.87 1.73330 429 0.967 2249 -50.000 409.670 16.316 0.06129 29. 121 437. 74 284 93 316.61 1.75738 .429 0. 981 2154

-40. 000 419.670 15.649 0.06390 26.608 398. 85 293. 35 326.48 1.78117 .429 0.992 2067

-30. 000 429.670 14.964 0.06674 24.319 367. 13 301 84 336.45 1.8046* .430 1.000 1990 -20.000 439.670 14.327 0. 06980 22.245 342. 13 310 29 346.47 1.82771 .431 1.004 1923 -10.000 449.670 13.686 0.07307 20.379 323. 41 318. 63 356.51 1. 35029 432 1.003 1865 0.000 459.670 13.069 0.07652 18.711 310. 49 326 83 366.51 1.87227 433 0.995 1818 10.000 469.670 12.483 0.09011 17.231 302, 87 334 86 376.39 1.89354 .434 0.931 1761

20. 000 479.670 11.933 0.08380 IF. 926 299. 97 342. 67 386.12 1.91403 436 0.963 1753 30.000 489.670 11.422 0.0S755 14.779 301. 01 350 25 395.64 1.93369 437 0.941 1733 40.000 499.670 10.950 0.09132 13.774 304, 76 357 59 404.94 1.95249 439 0.919 1720 50.000 509.670 10.517 0.09509 12.889 309. 82 364 7? •14.03 1.97049 ,440 0. 998 1711

60. 000 519.670 10.117 0. 09884 12.106 315. 51 371 66 422.91 1.98775 442 0.379 1704 70.000 529.670 9.748 0.10258 11.410 321 62 378 42 431.61 2. 00434 444 0.362 1700 80.000 539.670 9.407 0.10631 10.786 328. 11 385 04 440. 15 ?. 02032 446 0.847 1698 100.000 559.670 8.796 0.11369 9.720 342 39 397 ,88 456.83 2.05065 451 0. 321 1699

120. 000 579.670 8. 267 0. 12097 8.844 359 20 410 , 30 473.02 2.07908 .457 0.799 1706 140.000 599.670 7.806 0.12810 8.117 377. 89 422 39 488.80 2.10586 ,463 0.780 1718 160.000 619.670 7.404 0.13507 7.504 397 38 434 23 504.26 2. 13122 .469 0.766 1733 180.000 639.670 7.048 0.14188 6.982 417. 11 445 91 519.47 2. 15537 476 0.755 1750

200. 000 659.670 6.732 0.14855 6.532 436 82 457 47 534.49 2.17P49 .484 0.747 1768 220.000 679.670 6.443 0.15508 6.139 456, 39 468 96 549.37 2.20072 .492 0.74? 1786 240.000 699.670 6. 192 0.16149 5.794 475 78 480 44 564.17 2.22217 .500 0.738 1804 280.000 739.670 5.748 0.17398 5.215 513 69 503 43 593.64 2.26313 517 0. 736 1842 320.000 779.670 5.374 0.18609 4.748 551. 04 526 64 623.13 2.30196 ,534 0.739 1879 360.000 819.670 5.054 0.19787 4.363 587 22 550 21 652.80 2.33908 ,552 0.'45 1916 400.000 859.670 4.776 0.20938 4.040 622 47 574 .21 682.77 2.37477 ,571 0. 7 54 195 2 440.000 899.670 4.532 0.22065 3.765 656 65 598 70 713.10 2.40926 589 0.764 1987

262
METHANE ISOBAR AT P = 3000.0 PSI

T T DEN VOL OP/DT DP/OO E H S CV CP H DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LP 8TU/LB BTU/LB/R BTU/L3/R 6TU/L9/R FT/S

287.119 172.551 28.584 0.03498 161.981 3981. 95 95. 11 114.54 1.02435 0.515 0.773 5260

280. 000 179.670 28.285 0.03535 155.255 3806.75 100.33 119.97 1.05607 0.516 0.780 5161 270.000 189.670 27.876 0.03587 146.290 3567.55 107.73 127.66 1.09854 0.517 0.789 5019 260.000 199.67 27.465 0.03641 137.798 3330.29 115.27 135.50 1.13924 0.516 0.795 4877 250.000 209.670 27.048 0.03697 129.755 3098.61 122.89 143.43 1.17823 0.511 0. 800 4738 240.000 219.670 26.627 0.03756 122.131 2874.97 130.55 151.41 1.21556 0.505 0.803 4601 230.000 229.670 26.199 0.03817 114.894 2661. 03 138.24 159.44 1.25137 0.499 0.806 4464 220.000 239.670 25.763 0.03882 108.015 2457.77 145.96 167.52 1.28582 0.4 94 0.811 4326 210.000 249.670 25.319 0.03950 101.466 2265. 67 153.72 175.66 1.31910 0.490 0.818 4185 200.000 259.670 24.867 0.04021 95.225 2084.85 161.56 183.89 1.35139 0.488 0.827 4043 190.000 269.670 24.406 0.04097 89.272 1915. 10 169.43 192.20 1.38279 0.486 0.835 3904

160.00!) 279.670 23.935 0.04178 83.590 1756.06 177.37 200.58 1.41332 0.482 0.842 3770

170. 000 289.670 23.453 0.04264 78.167 1607.24 185.33 209.02 1.44295 0.473 0.844 3644 160.000 299.670 2 2.96 2 0.04355 72.989 1468. 10 193.26 217.46 1.47159 0.461 0.843 3526

150.000 309.670 22.459 0.04453 68.050 1338. 16 201.14 225.88 1.49924 0.449 0.842 3411

11*0 . 00 319.670 21.945 0.04557 63.341 1217.01 209.04 234.35 1.52614 0.448 0.35 3 3278

130. 000 329.670 21.418 0. 04669 58.856 1104.32 216.98 242.92 1.55252 0.443 0.860 3153 120.000 339.670 20.878 0.04790 54.594 999.89 2 24.96 251.56 1.57835 0.439 0.869 3028 110.000 349.670 20.326 0.04920 50.550 903.61 232.98 260.31 1.60372 0.436 0. 380 2905

100.000 359.670 19.760 0.05061 46.725 815.46 241.05 269.16 1.62868 0.435 0. 891 2784

-90. 000 369.670 19. 180 0.05214 43.120 735.41 2 49. 17 278.14 1.65329 0.433 0.904 2666 -80.000 379.670 18.587 0.05380 39.735 663.44 257.35 287.24 1.67759 0.433 0.917 2553 -70.000 389.670 17.982 0.05561 36.570 599.45 265. 5e 296.47 1.70159 0. 432 0.930 2445 -60.000 399.670 17.368 0.05758 33.627 543.25 273. 84 305.83 1.72529 0.429 0.939 2349

-50. 000 409.670 16.746 0.05972 30.903 494.59 282.10 315.28 1.74865 0.428 0.950 2256 -40.000 419.670 16.119 0.05204 28.393 453.12 290. 37 324.83 1.77169 0.428 0.960 2170 -30.000 429.670 15.494 0.06454 26. 093 418.44 298.62 334.47 1.79440 0.429 0.968 2092 -20.000 439.670 14.874 0.06723 23.995 390. 17 306. 83 344.18 1.81673 0.430 0.973 2023 -10.000 449.670 14.266 0.07010 22.090 367.85 314.98 353.92 1.83863 0.431 0.974 1962 0.000 459.670 13.675 0.07313 20.371 351.06 323.02 363.64 1.86 02 0.432 0.970 1911 10.000 469.670 13.107 0.07629 18.827 339.33 330.93 373.31 1.88063 0.434 0.963 186 8 20.000 479.670 12.567 0.07958 17.448 332. 21 338. 6e 382.88 1.90099 0.435 0.951 1833 30.000 489.670 12.058 0.08294 16.220 329.20 346. 24 392.32 1.92045 0.437 0.935 1807 40.000 499.670 11.582 0.08634 15.130 329.72 353.62 401.58 1.93919 0.439 0.918 1787 50.000 509.670 11.140 0.08977 14.165 332.89 360.80 410.67 1.95719 0.441 0.899 1774 60.000 519.670 10.730 0.09320 13. 307 337.61 367. 60 419.57 1.97449 0.443 0.381 1764 70.000 529.670 10.350 0.09661 12.543 343.05 374.63 428.30 1.99112 0.445 0. 365 1758 80.000 539.670 9.998 0.10002 11.859 348.94 381.31 436.87 2.00716 0.447 0.850 1753 100.000 559.670 9.364 0.10679 10.685 361.68 394.2? •53.62 2.03763 0.452 0.325 1749

120. 000 579.670 8.811 0.11349 9.717 375. 85 406.87 *69. 92 2.06625 0.458 0.805 1750 140.000 599.670 8.326 0.12010 8.908 392.13 419.13 485.85 2.09327 0.464 0.788 1757 160.000 619.670 7.899 0.12659 8.226 410.09 431.14 501.47 2. 11889 0.471 0.774 1768

180. 000 639.670 7.521 0.13296 7.644 428.87 442.97 516.83 2.14330 0.478 0.763 1781

200. 000 659.670 7. 184 0.13920 7.142 447.94 454.68 532.01 2.16667 0.485 0. 755 1797

220. 000 679.670 6.881 0.14532 6.705 467.04 466.32 547.05 2. 18912 0.493 0.749 1813 240.000 699.670 6.608 0.15133 6.321 486.06 477.92 561.99 2.21078 0.501 0. 745 1830 280.000 739.670 6.133 0.16305 5.678 523.63 501.15 591.72 2.25211 0.518 0.743 1864

320. 000 779.670 5.734 0.17441 5.161 560.44 524.56 621.45 2.29126 0.5 36 0.745 1899

360. 000 819.670 5.392 0.18547 4.735 596.41 548. 31 651.34 2.32864 0.554 0.750 1935 400.000 859.670 5.095 0.19627 4.378 631.55 572.46 681.50 2.36456 0.572 0.758 1969 440.000 899.670 4.835 0.20685 4.075 665.88 597.10 712.01 2.39925 0.590 0.768 2004

2 63
ME THANE ISO BAR AT P = 3*00.0 PSI

T T OEN VOL DP/OT OP/OO E H S CM CP W OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 8TU/LB 3TU/LB BTU/L8/R BTU/L9/R BTU/L9/R FT/S

285. 908 173.762 28.635 0.03492 161.380 4023.68 95.42 117.41 1.02613 0.518 0.772 5270 280.000 179.670 28.389 0.03522 155.927 3883.54 99.73 121.91 1.05234 0. 519 0.777 5192 270.000 189.670 27.987 0.03573 147.134 3652.46 107.08 129.58 1.09468 0.520 0.786 5056 260.000 199.670 27.583 0.03625 138.797 3421.77 114.56 137.39 1.13524 0.519 0.792 4921 250.000 209.670 27.176 0.03680 130.897 3195.42 122.11 145.28 1.17405 0.514 0.796 4788 240.000 219.670 26.763 0.03736 123.408 2976. 13 129. 7C 153.23 1.21120 0.508 0.798 4656 230.000 229.670 26.346 0.03796 116.302 2765.73 137.32 161.21 1.24679 0.501 0. 801 4525 220.000 239.670 25.922 0.03858 109.549 2565.40 144.95 169.24 1.28101 0.496 0.805 4392 210.000 249.670 25.492 0.03923 103.124 2375. 74 152.62 177.32 1.31405 0.493 0.811 4257 200.000 259.670 25. 05* 0.03991 97.005 2197. 00 160. 34 165.47 1.34605 0.491 0.819 4121 190.000 269.670 24.609 0.04064 91.173 2029. 10 168.11 193.70 1.37715 0.489 0.827 3967 180.000 279.670 24.155 0.04140 85.612 1871.74 175.93 201.99 1.40735 .484 0.832 3860 170.000 289.670 23.694 0.04221 80.308 1724.48 183.75 210.32 1.43660 0.476 0.833 3740 160.000 299.670 23.224 0.04306 75.250 1586.83 191.53 218.64 1.46485 0.464 0.831 3630 150.000 309.670 22.745 0.04397 70.429 1458.28 199. 25 226.93 1.49206 0.451 0.828 3522

140. 000 319.670 22.258 0.04493 65.837 1338.37 206.97 235.25 1.51847 0.450 0.837 3397 130.000 329.670 21.761 0.04595 61.469 1226.73 214.71 243.64 1.54431 0.444 0.842 3280

120. 000 339. 670 21.256 0. 04705 57.318 1123. 05 222.47 252.09 1.56955 0.441 0.848 3164 110.000 349.670 20.740 0.04821 53.383 1027.11 230.25 260.61 1.59425 0.438 0.855 3049 100.000 359.670 20.216 0.04947 49.659 938.78 238.06 269.20 1.61849 0.436 0. 464 2937 -90.000 369.670 19.683 0.05081 46.144 857.95 245.89 277.88 1.64229 0. 434 0.872 2827

-80. 000 379.670 19.141 0. 05224 42.838 784.51 253.76 286.65 1.66570 0.433 0.882 2721 -70.000 389.670 18.591 0.05379 39.737 718. 35 261.65 295.51 1.68874 0.432 0.891 2619 -60.000 399.670 18.035 0.05545 36.840 659.29 269.55 304.46 1.71142 0.428 0.897 2529 -50.000 409.670 17.474 0.05723 34.144 607. 11 277.44 313.47 1.73367 0.428 0.905 2440

-«»0. 000 419.670 16.911 0.05913 31.642 561.52 285. 32 322.55 1.75558 0.427 0.912 2356

-30. 000 429.670 16.348 0.06117 29.330 522.19 293.19 331.70 1.77713 0.428 0.918 2279 -20.000 439.670 15.789 0.06334 27.200 488.76 301. 04 340.91 1.79632 0.429 0.923 2208 -10.000 449.670 15.236 0.06563 25.245 460. 84 308.84 350.16 1.81912 0.430 0.926 2144

0. 000 459.670 14.694 0.06805 23.456 438.07 316.58 359.43 1.83950 0.432 0.927 2088 10.000 469.670 14.166 0.07059 21.824 420.03 324.25 368.69 1.85943 0.433 0.925 2038 20.000 479.670 13.656 0.07323 20.341 406. 34 331.81 377.91 1.87886 0.435 0.920 1995 30.000 489.670 13.166 0.07595 18.996 396.61 339.26 387.08 1. 89776 0.437 0.913 1959 40.000 499.670 12.699 0.07875 17.780 390.45 346.59 396.17 1.91615 0.439 0.904 1929 50.000 509.670 12.256 0.08159 16.683 387.51 353.78 405.15 1.93395 0.441 0.393 1906 60.000 519.670 11.838 0.08447 15.695 387. 39 360.83 414.01 1.95117 0.444 0.880 1887 70.000 529.670 11.445 0.08737 14. 804 389.61 367.74 422.75 1.96782 0.446 0.867 1873 80.000 539.670 11.078 0.09027 14.002 393.56 374.52 431.36 1.98392 0.449 0. 354 1863 100.000 559.670 10.411 0.09605 12.619 404. 01 387.73 448.20 2.01457 0.454 0. 831 1851 120.000 579.670 9.824 0.10180 11.475 415.93 400.53 464.62 2.04340 0.460 0.812 1845

140. 000 599.670 9.303 0.10749 10.515 428. 80 413.04 480.71 2.07069 0.466 0.797 1843 160.000 619.670 8.840 0.11313 9.699 442.73 425.31 496.53 2.09664 0.473 0.785 1845 180.000 639.670 8.425 0.11870 8.999 458.18 437.40 512.13 2.12142 0. 480 0.775 1851 200.000 659.670 8.052 0.12419 8.393 474.98 449.37 527.56 2.14517 0.488 0.767 1860

220. 000 679.670 7.716 0.12960 7.866 492.54 461.25 542.85 2.16800 0.496 0.762 1872 240.000 699.670 7.412 0.13492 7.402 510.46 473.09 558.03 2.19002 0.504 0.757 1885 280.000 739.670 6.881 0.14532 6.627 546.51 496.74 568.23 2.23200 0.521 0.754 1913 320.000 779.670 6.434 0.15542 6.005 582.30 520.54 618.39 2.27170 0.539 0.755 1944

360. 000 819.670 6. 051 0.16526 5.495 617.55 544.62 648.66 2.30956 0.557 0.759 1976 400.000 859.670 5.719 0.17487 5.069 652.18 569.08 679.17 2.34591 0.575 0.767 2007 440.000 899.670 5.426 0.18428 4.708 686. 17 593.98 710.01 2.38096 0.593 0.775 2039

264
METHANE ISOBAR AT P = 3800.0 PSI

T T DEN VOL DP/DT DP/DO t H S CV CP H DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB 8TU/LB BTU/L8/R BTU/LB/R BTU/L3/R FT/S

284.703 174.967 28.684 0.03486 160.794 4063.98 95.75 120.28 1.02793 0.521 0.772 5280 260.000 179.670 28.491 0.03510 156.553 3956.85 99.16 123.86 1.04869 0.522 0.776 5220

270. 000 189.670 28.096 0.03559 147.929 3734.17 106.46 131.51 1.09092 0.523 0.784 5092 260.000 199.670 27.698 0.03610 139.743 3510.25 113.88 139.29 1.13134 0.521 0.789 4963 250.000 209.670 27.299 0.03663 131.981 3289.34 121.38 147.15 1.17001 0.517 0.793 4835 240.000 219.670 26.896 0.03718 124.622 3074.46 128.90 155.06 1.20698 0.510 0.794 4709

230.000 229.670 26.488 0.03775 117.638 2867.64 136.44 163.00 1.24239 0.504 0.796 4582 220.000 239.670 26.075 0.03835 111.003 2670.20 143.99 170.98 1.27640 0.499 0. 300 4455 210.000 249.670 25.656 0.03898 104.694 2482.93 151.58 179.00 1.30920 0.495 0.805 4325 200.000 259.670 25.232 0.03963 98.687 2306.15 159.20 187.09 1.34096 0.493 0.812 4194

190. 000 269.670 24.800 0.04032 92.964 2139.92 166.88 195.25 1.37179 0.491 0.919 4066 180.000 279.670 24.363 0.04105 87.511 1984.03 174. 5e 203.46 1.40169 0.487 0.323 3944 170.000 289.670 23.918 0.04181 82.312 183e.09 182.28 211.70 1.43064 0.478 0.824 3831

16 0.0 00 299.670 23.467 0.04261 77.358 1701.64 189.94 219.92 1.45854 0.466 0.820 3726 150.000 309.670 23.009 0.04346 72.638 1574.19 197.52 228.10 1.148538 0.453 0.816 3625 140.000 319.670 22.544 0.04436 68.145 1455.27 205.08 236.30 1.51139 0.451 0.823 3506 130.000 329.670 22.073 0.04531 63.871 1344.44 212.66 244.54 1.53679 0.446 0. 826 3396 120.000 339.670 21.594 0.04631 59.813 1241. 34 220.214 252.83 1.56155 0.442 0. 831 3287 110.000 349.670 21.109 0.04737 55.963 1145.69 227.83 261.17 1.58574 0.4 39 0.336 3180 100.000 359.670 20.617 0.04850 52.319 1057.26 235.43 269.56 1.60940 0.437 0.942 3074

-9 0.000 369.670 20.119 0.04970 48.876 975.88 243.04 278.02 1.63259 0.435 0.949 2971 -80.000 379.670 19.616 0.05098 45.631 901.38 250.67 286.54 1.65534 0.434 0.356 2871 -70.000 389.670 19.107 0.05234 42.580 833.62 258.30 295.13 1.67768 0.433 0.363 2775 -60.000 399.670 18.595 0.05378 39.720 772.42 265.94 303.78 1.69959 0.429 0.966 2689 -50.000 409.670 18.079 0.05531 37.046 717.59 273.54 312.47 1.72106 0.428 0.372 2603

-1*0. 000 419.670 17.563 0.05694 34.554 668. 86 281.14 321.21 1.74214 0.427 0.977 2522 -30.000 429.670 17.047 0.05866 32.236 625.97 288.73 330.01 1.76286 0.428 0.982 2446 -20.000 439.670 16.533 0.06048 30.087 588.60 296.29 338.85 1.78321 0.429 0.387 2375 -10.000 449.670 16.025 0.06240 28.099 556.43 303.82 347.73 1.80319 0.430 0.390 2310 0.000 459.670 15.524 0. 06442 26.264 529.12 311.32 356.64 1.82278 0.431 0.892 2251 10.000 469.670 15.033 0.06652 24.574 506.32 318.76 365.56 1.84198 0.433 0.392 2198 20.000 479.670 14.554 0.06871 23.022 487.68 326. 13 374.48 1.86077 0.435 0.391 2151 30.000 489.670 14.090 0.07097 21.598 472.88 333.43 383.37 1. 87912 0.437 0.888 2109

40. 000 499.670 13.641 0.07331 20.295 461.57 340.65 392.23 1.8970 2 0.439 0.983 2073 50.000 509.670 13.211 0.07570 19.104 453.43 347.77 401.03 1.91446 . 442 0.977 2042 60.000 519.670 12.799 0.07813 18.017 448.15 354.79 409.77 1.93143 0.444 0.970 2016 70.000 529.670 12.407 0.09060 17.026 445.45 361.71 418.42 1.94793 0.447 0.862 1995

80. 000 539.670 12.035 0.09309 16.123 445.06 368.53 426.99 1.96397 0.450 0.353 1977 100.000 559.670 11.349 0.09811 14.548 449.89 381.86 443.86 1.99465 0.455 0.334 1954 120.000 579.670 10.739 0.09312 13.234 459.41 394.84 460.36 2.02362 0.462 0.317 1940 140.000 599.670 10.194 0.09810 12.128 470.71 407.51 476.54 2.05107 0.468 0.302 1933 160.000 619.670 9.705 0.10304 11.185 482.88 419.97 492.47 2.07720 0.475 0.791 1929 180.000 639.670 9.265 0. 10794 10.374 495.76 432.25 508.20 2.10218 0.483 0.782 1929 200.000 659.670 8.866 0.11279 9.669 509.43 444.41 523.78 2.12616 0.491 0.776 1932

220. 000 679.670 8.504 0.11759 9.052 524.24 456.49 539.24 2.14925 0.499 0.771 1938 240.000 699.670 8.174 0.12234 8.509 540.12 468.53 554.61 2.171514 0.507 0.767 1946 280.000 739.670 7.596 0.13164 7.600 573.64 492.55 585.19 2.21404 0.524 0.763 1967 320.000 779.670 7.107 0.14071 6.871 607.92 516.69 615.70 2.25422 0.542 0.763 1993

360. 000 819.670 6.687 0.14955 6.273 642.12 541.08 646.31 2.29250 0.559 0.767 2020 400.000 859.670 6.321 0.15820 5.775 675.96 565.81 677.13 2.32921 0.577 0.774 2049

440.000 899.670 6.000 0.15667 5.354 709.33 590.98 708.25 2.36460 0.595 0.782 2078

265
ME THANE ISO 3AR AT P = 4200.0 PSI

T T DEN VOL OP/DT OP/DO E H S CV CP H DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

283.505 176.165 28.733 0.0)480 160.223 4102. 85 96.0 6 123.15 1.02973 0.524 0.771 5289

280. 000 179.670 28.591 0.03498 157.137 4026.63 98.61 125.81 1.04511 0.524 0.774 5247

270. 000 189.670 28.201 0. 03546 148.679 3812.65 105.86 133.44 1.08724 0.525 0.782 5126 260.000 199.670 27.811 0.03596 140.640 3595.71 113.24 141.20 1.12755 0.524 0.787 5002 250.000 209.670 27.419 0.03647 133.012 3380.43 120.67 149.04 1.166C7 0.519 0.790 4880

21*0.000 219.670 27.024 0.03700 125.777 3170.07 128. 13 156.91 1.20289 0.513 0. 791 4759

230. 000 229.670 26.625 0.03756 118.910 2966.87 135.61 164.82 1.23813 0.506 0.792 4638 220.000 239.670 26.222 0.03814 112.386 2772.34 143.09 172.75 1.27195 0.501 0.795 4515 210.000 249.670 25.814 0.03874 106.183 2587.40 150.59 180.72 1.30455 0.498 Q. 10 4390 200.000 259.670 25.401 0.03937 100.280 2412.53 158. 13 188.75 1.33609 0.496 0.806 4264

190. 000 269.670 24.983 0.04003 94.658 2247.86 165.72 196.85 1.36667 0.493 0.812 4141 160.000 279.670 24.559 0.04072 89.301 2093.28 173.32 204.99 1.39633 0.489 0.816 4024 170.000 289.670 24.130 0. 04144 84.197 1948.48 180.92 213.15 1.42499 0.460 0.815 3915 160.000 299.670 23.695 0.04220 79.334 1813. 04 188.46 221.29 1.45260 0.468 0. 811 3816 150.000 309.670 23.254 0.04300 74.703 1686.48 195.92 229.37 1.47912 0.455 0.806 3721 140.000 319.670 22.809 0.04384 70.294 1568.33 203.36 237.45 1.50479 0.453 0.812 3607 130.000 329.670 22.358 0.04473 66.102 1458.14 210.80 245.58 1.52983 0.448 0.814 3503

120. 000 339.670 21. 902 0.04566 62. 120 1355. 50 218.23 253.74 1.55420 0.444 0.817 3400 110.000 349.670 21.442 0.04664 58.341 1260. 07 225.66 261.93 1.57796 0.441 0.321 3298

100. 000 359.670 20.976 0.04767 54.762 1171.58 233.08 270.16 1.60117 0.438 0. 325 3198 -90.000 369.670 20.507 0.04876 51.377 1089.79 240.51 278.44 1.62387 0.436 0.330 3101

-80. 000 379.670 20.034 0.04992 48.181 1014.50 247.95 286.77 1.64611 0.435 0.835 3006

-7 0. 00 389.670 19.557 0.05113 45.171 945.52 255.36 295.15 1.66789 0.434 0.841 2914

-60. 000 399.670 19.078 0.05242 42. 342 882.69 262.80 303.57 1.68923 0.429 0.342 2833 -50.000 409.670 18.598 0.05377 39.688 825.79 270.20 312.01 1.71010 0.428 0.846 2750 -'0.000 419.670 18.118 0.05519 37.204 774.61 277.57 320.50 1.73056 0.428 0.351 2672 -30.000 429.670 17.633 0.05670 34.884 728.91 284.93 329.03 1.75065 0.428 0.855 2597 -20.000 439.670 17.161 0.05827 32.721 688.42 292.28 337.60 1.77036 0.429 0.859 2528 -10.0 00 449.670 16.688 0.05992 30.710 652. 86 299.59 346.20 1.78971 0.430 0.362 2462 0.000 459.670 16.221 0.06165 28.842 621.92 306.86 354.63 1.80669 0.431 0.364 24C2 10.000 469.670 15.761 0.06345 27.111 595.32 314. 13 363.48 1.82730 0. 433 0. 365 2347 20.000 479.670 15.311 0.06531 25.508 572.74 321.34 372.13 1.84554 0.435 0. 366 2297 30.000 489.670 14.871 0.06725 24.027 553.88 328.49 380.79 1.86339 0.437 0.365 2252 40.000 499.670 14.443 0.06924 22.659 538.45 335.58 389.43 1.88086 0.440 0. 863 2212 50.000 509.670 14.030 0.07128 21.399 526.16 342.60 398.04 1.89792 0.442 0. 360 2177

60. 000 519.670 13.630 0.07337 20.238 516.72 349.56 406.62 1.91459 0.445 0.356 2145 70.000 529.670 13.247 0.07549 19.169 509.87 356.44 415.15 1.93085 0.448 0.351 2118 80.000 539.670 1 2 . 87 9 0.07765 18.187 505.37 363.24 423.63 1.94671 0.451 0. 345 2095

100. 000 559.670 12.191 0.08203 16.452 502.53 376.61 440.40 1.97723 0.457 0.832 2060 120.000 579.670 11.568 0.08644 14.984 506.44 389.66 456.91 2.00622 0.463 0.319 2037 140.000 599.670 11.006 0.09086 13.737 514.97 402.49 473.16 2.03377 0.470 0.306 2023 160.000 619.670 10.499 0.09525 12.672 525.70 415. 09 489.16 2.06003 0.477 0. 795 2014

180. 000 639.670 10.040 0.09960 11.752 537.36 427.52 504.98 2.08516 0.485 0. 787 2010 200.000 659.670 9.622 0.10392 10.95 2 549.63 439.83 520.66 2.10928 0.493 0. 781 2009 220.000 679.670 9.241 0.10821 10.251 562.42 452.06 536.22 2. 13253 0.501 0.776 2010 240.000 699.670 8.892 0.11246 9.631 575.83 464. 25 551.71 2.15499 0.509 0.773 2013 280.000 739.670 8.275 0.12084 8.590 605.24 488.59 582.57 2.19788 0.526 0.770 2026 320.000 779.670 7.750 0.12904 7.752 637.11 513.03 613.38 2.23845 0.544 0.771 2045 360.000 819.670 7.297 0.13705 7.066 669.83 537.69 644.28 2.27709 0.562 0.774 2068

400.0 00 859.670 6.902 0.14489 6.494 702.62 562.69 675.37 2.31413 0.580 0.781 2093 440.000 899.670 6.554 0.15258 6.011 735. 16 588.06 706.75 2.34980 0.598 0.738 2119

266
METHANE ISOBAR AT P = 4600.0 PSI

T T DEN VOL DP/DT DP/DD E H S CM CP M DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB 8TU/LB/R BTU/LB/R BTU/L3/R FT/S

282.31<« 177.356 28.781 0.03474 159.665 4140.30 96.42 126.01 1.03153 0.527 0.771 5298 2S0.000 179.670 28.690 0.03486 157.680 4092.83 98.06 127.77 1.04161 0.5 27 0.773 5272

27 0.0 00 189.670 26.305 0.03533 149.385 3887.91 105.29 135.38 1.08365 0.528 0.780 5157

26 0.000 199.670 27.921 0.03582 141.490 3678.20 112.61 143.12 1.12385 0.526 0.785 5040 250.000 209.670 27.536 0. 03632 133.993 3468.72 120. 00 150.93 1.16225 0.522 0.787 4923

21*0.0 00 219.670 27.148 0.03683 126.877 3263. 00 127.40 158.78 1.19893 0.515 0.788 4807 230.000 229.670 26.758 0.03737 120.121 3063.51 134.81 166.64 1.23401 0.509 0.789 4690 220.000 239.670 26.364 0.03793 113.704 2871.93 142.23 174.53 1.26766 0.503 0.791 4572

210.000 249.670 25.966 0.03851 107.601 2689. 34 149.66 162.46 1.30007 0.500 0.795 4451 200.000 259.670 25.563 0.03912 101.794 2516.34 157.12 190.44 1.33141 0.498 0.301 4330 190.000 269.670 25.157 0.03975 96.265 2353. 16 164.62 198.48 1.36178 0.496 0.806 4212 180.000 279.670 24.745 0.04041 90.997 2199.80 172.14 206.56 1.39121 0.491 0.809 4099

170.000 289.670 24.329 0.04110 85.979 2056. 00 179.64 214.66 1.41963 0.482 0.308 3995 160.000 299.670 23.909 0.04183 81.197 1921.41 187.09 222.71 1.44698 0.470 0.303 3900 150.000 309.670 23.484 0.04258 76.644 1795.58 194.44 230.71 1.47323 0.457 0.797 3810 140.000 319.670 23.055 0.04337 72.310 1678.05 201.76 238.71 1.49860 0.455 0. 302 3702

130. 000 329.670 22.622 0.04420 68.188 1568.35 209.08 246.73 1.52333 0.450 0.803 3603 120.000 339.670 22.186 0.04507 64.271 1466.07 216.38 254.78 1.54737 0.446 0.806 3505 110.000 349.670 21.746 0.04599 60.553 1370.81 223.68 262.85 1.57078 0.442 0.808 3408 100.000 359.670 21.303 0.04694 57.028 1282.27 230.96 270.95 1.59362 0.439 0.812 3313 -90.000 369.670 20.856 0.04795 53.691 1200.16 238.24 279.08 1.61593 0.437 0.815 3220 -80.000 379.670 20.403 0.04900 50.537 1124.25 245.52 287.25 1.63774 0.436 0.819 3129

-70.0 00 389.670 19.958 0.05011 47.561 1054.33 252.79 295.47 1.65909 0.435 0.323 3042 -60.000 399.670 19.506 0.05127 44.756 990.21 260. 04 303.71 1.67997 0.430 0. 824 2964

-50. 000 409.670 19.054 0.05248 42.119 931.68 267.25 311.96 1.70036 0.429 0.327 2885 -40.000 419.670 18.602 0.05376 39.643 678.55 274.45 320.24 1.72034 0.428 0.330 2809 -30.000 429.670 18.152 0.05509 37.322 830.59 281.63 328.56 1.73993 0.428 0.833 2736

-2 0.0 00 439.670 17.704 0.05649 35.151 787.56 288. 8C 336.91 1.75914 0.429 0.837 2667 -10.000 449.670 17.259 0.05794 33.122 749.23 295.94 345.29 1.77799 0.430 0.340 2603 0.000 459.670 16.820 0.05945 31.229 715.32 3 3.06 353.70 1.79648 0.432 0.842 2542 10.000 469.670 16.387 0.0S102 29.466 685.58 310.15 362.13 1.81463 0.434 0.344 2486 20.000 479.670 15.961 0.06265 27.825 659.74 317.21 370.57 1.83241 0.436 0.845 2435 30.000 489.670 15.544 0.06433 26.299 637.52 324.22 379.02 1.84985 0.438 0.345 2387

1*0.000 499.670 15.136 0.06607 24.882 618.66 331.20 387.47 1.86693 0.440 0.845 2345 50.000 509.670 14.740 0.06784 23.567 602.91 338.12 395.91 1.88365 0.443 0.343 2306 60.000 519.670 14.355 0.05966 22.348 590. 00 344.99 404.33 1.90001 0.4i<6 0.341 2271 70.000 529.670 13.982 0.07152 21.219 579.69 351.81 412.73 1.91602 0.449 0.838 2240 80.000 539.670 13.623 0.07341 2 0.173 571.76 358.57 421.10 1.93167 0.452 0.835 2213 100.000 559.670 12.944 0.07725 18.307 562.17 371.91 437.71 1.96190 0.458 0.827 2168

120. 000 579.670 12.320 0.08117 16.708 559.71 385.02 454.16 1.99 77 0.465 0.817 2136

140.000 599.670 11.750 0.08511 15.335 563.01 397.91 470.41 2.01833 0.472 0.308 2113 160.000 619.670 11.230 0.08905 14.152 570.63 410.61 486.47 2.04468 0.479 0.798 2099 180.000 639.670 10.756 0.09297 13.128 580.75 423.16 502.35 2.06991 0.4 67 0.791 2090

200. 0Q0 659.670 10.324 0.09687 12.235 591.96 435.59 518.10 2.09416 0.495 0.785 2085 220.000 679.670 9.928 0.10073 11.451 603.77 447.95 533.75 2.11753 0.503 0.780 2083 240.000 699.670 9.564 0.10456 10.757 616. 03 460.26 549.33 2.14011 0.511 0.778 2083 280.000 739.670 8.918 0.11214 9.588 641.84 484. 86 580.38 2. 18327 0.529 0.776 2088

320. 000 779.670 8.362 0.11959 8.644 670.16 509.55 611.41 2.22413 0.547 0.777 2101 360.000 819.670 7.881 0.12689 7.869 700.61 534.46 642.55 2.26307 0.565 0.780 2118 400.000 859.670 7.460 0.13405 7.223 731.94 559.69 673.88 2.30039 0.562 0.786 2140 440.000 899.670 7.088 0.14108 6.678 763.45 585.31 705.48 2.33632 0.600 0.794 2163

267
METHANE ISOBAR AT P = 5000.0 PSI

T T OEN VOL CP/OT DP/ OO E H S CV CP H DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/L8 9TU/Le BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

281. 130 178.540 28.829 0.03469 159.121 4176. 34 96.77 128.88 1.03334 0.529 0.770 5307

280. 000 179.670 28.787 0.03474 158.183 4155.39 97.57 129.73 1.03818 .529 0.771 5295

270. 000 189.670 28.407 0.03520 150.051 3959.90 104.74 137.33 1.08014 0.530 0.778 5187 260.000 199.67 28.029 0.03568 142.298 3757.70 112.01 145.05 1.12023 0.529 0.782 5075 250.000 209.670 27.650 0.03617 134.927 3554. 23 119. 35 152.83 1.15852 0.524 0.784 4964 240.000 219.670 27.269 0.03667 127.927 3353.30 126.70 160.65 1.19508 0.518 0.785 4853

230. 000 229.670 26.886 0.03719 121.278 3157.63 134.05 168.49 1.23001 0.511 0.785 4741 220.000 239.670 26.501 0.03773 114.961 2969.07 141.40 176.34 1.26351 0.506 0.787 4627 210.000 249.670 26. 112 0.03830 108.953 2788. 86 148.77 184.23 1.29575 0.502 0.791 4511 200.000 259.670 25.719 0.03888 103.237 2617.72 156. 17 192.16 1.32691 0.500 0.796 4394

190. 000 269.670 25.323 0.03949 97.794 2456.02 163.59 200.15 1.35 709 0.498 0.801 4279 180.000 279.670 24.923 0.04012 92.608 2303.79 171.03 208.18 1.38631 0.493 0.803 4171

17 0.0 00 289.670 24.519 0.04078 87.668 2160.92 178.45 216.21 1.41452 0.484 0.302 4071 160.000 299.670 24.112 0.04147 82.961 2027. 07 185.80 224.20 1.44164 0.472 0.796 3980 150.000 309.670 23.701 0.04219 78.478 1901.85 193.05 232.12 1.46765 0.459 0.789 3894

li»0. 000 319.670 23.286 0.04294 74.211 1784.82 200.28 240.04 1.149276 0.457 0.794 3790

130. 000 329.670 22.869 0. 04373 70. 150 1675.51 207.49 247.98 1.51722 0.451 0.794 3696 120.000 339.670 22.449 0.04455 66.290 1573.49 214.68 255.93 1.54098 0.447 0.796 3602 110.000 349.670 22.027 0.04540 62.625 1478.35 221.86 263.89 1.56409 0.444 0.798 3509 100.000 359.670 21.602 0.04629 59.147 1389.75 229.02 271.88 1.58662 0.441 0. 800 3418

-90. 000 369.670 21. 176 0. 04722 55.851 1307.39 236.17 279.90 1.60860 0.439 0.803 3330

-80. 000 379.670 20.748 0.04820 52.732 1230.98 243.32 287.94 1.63007 0.437 0.906 3243 -70.000 389.670 20.319 0.04921 49.784 1160. 31 2 50.45 296.01 1.65106 0.436 0.809 3159 -60.000 399.670 19.890 0.05028 47.001 1095.15 257.56 304.11 1.67157 0.431 0.809 3085

-50. 000 409. 670 19.461 0.05139 44.378 1035. 31 264.63 312.20 1.69158 0.430 0.911 3008

-i*0. 000 419.670 19.033 0.05254 41.909 980.59 271.68 320.32 1.71116 0.429 0.813 2935 -30.000 429.670 18.606 0.05375 39.589 930.78 278.71 328.47 1.73035 0.429 0.916 2864 -20.000 439.670 18.182 0.05500 37.411 885.66 285.73 336.65 1.74916 0.430 0. 319 2796 -10.000 449.670 17.762 0.05630 35.369 845.03 292.7? 344.85 1.76760 0.431 0.822 2732

0. 000 459.670 17.346 0.05765 33.456 808.64 299.70 353.08 1.78570 0.432 0.824 2672 10.000 469.670 16.935 0.05905 31.667 776.27 306.66 361.33 1.80346 0.434 0.926 2616 20.000 479.670 16.530 0.06050 29.995 747.67 313.59 369.60 1. 82087 0.436 0. 827 2563 30.000 489.670 16.133 0.06199 28.433 722.60 320.49 377.88 1.83796 0.439 0.828 2515

WO. 000 499.670 15.743 0.06352 26.977 700. 83 327.35 386.16 1.85471 0.441 0. 329 2470 50.000 509.670 15.363 0.06509 25.618 682.12 334.18 394.45 1.87113 0.444 0.828 2429 60.000 519.670 14.993 0.06670 24.352 666. 24 340.97 402.73 1.88722 0.447 0.828 2392 70.000 529.670 14.632 0.06834 23.173 652.96 347.72 411.00 1.90298 0.450 0.926 2358

80. 000 539.670 14.283 0.07001 22.075 642.08 354.43 419.25 1.91841 0.453 0.824 2328 100.000 559.670 13.618 0.07343 20.101 626.68 367.70 435.69 1.94 83 3 0.459 0. 819 2276

120. 000 579.670 13.000 0. 07692 18. 391 618.59 380.80 452.02 1.97699 0.466 0.813 2236 140.000 599.670 12.429 0.08046 16.908 616.55 393.72 468.22 2.00447 0.473 0.307 2206 160.000 619.670 11.903 0.03402 15.619 619.48 406.49 484.28 2.03082 0.481 0.300 2185

180. 000 639.670 11.419 0.08757 14.496 626.33 419.13 500.21 2.05612 0.489 0.793 2171

200. 000 659.670 10.976 0.09111 13.512 635.80 431.67 516.02 2.08046 0.497 0.798 2162 220.000 679.670 10.568 0.09463 12.647 646.57 444.13 531.74 2. 10393 0.505 0.784 2156 240.0 00 699.670 10. 192 0.09812 11.881 657.99 456.55 547.39 2.12662 0.514 0. 781 2153 280.000 739.670 9.522 0.10502 10.588 682.02 481.36 578.59 2. 16999 0.531 0.779 2153

320. 000 779.670 8.943 0.11181 9.541 707.40 506.26 509.79 2.21107 0.549 0.781 2160 360.0 00 819.670 8.438 0.11851 8.679 734.76 531.39 641.11 2.25025 0.567 0.785 2172

WOO. 000 859.670 7.995 0.12508 7.959 763.96 556. 83 672.64 2.28780 0.585 0.791 2188

i. 40. 000 899.670 7.602 0.13155 7.350 794.05 582.65 704.44 2.32396 0.603 0. 799 2208

268
METHANE ISOBAR AT P = 5500.0 PSI

T T OEN VOL DP/DT DP/OD E H S CV CP H DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LP BTU/LB BTU/LB/R BTU/LB/R eTU/LB/R FT/S

279.659 180.011 28.889 0.03462 158.459 4219.40 97.21 132.47 1.03560 0.532 0.770 5317 270.000 189.670 28.532 0.03505 150.829 4045.23 104.07 139.77 1.07584 0.533 0.776 5222 260.000 199.670 28.160 0.03551 143.250 3852.84 111.30 147.46 1.11583 0.532 0.780 5117

25 0.000 209.670 27.788 0.03599 136.033 3657.20 118.57 155.22 1.15400 0.527 0.781 5012

21*0.000 219.670 27.416 0.03648 129.173 3462.53 125.86 163. 01 1.19040 0.520 0.781 4907 230.000 229.670 27.042 0.03698 122.653 3271.82 133.15 170.81 1.22518 0.514 0.781 4801 220.000 239.670 26.666 0.03750 116.455 3087.17 140.43 178.63 1.25850 0.509 0.783 4692 210.000 249.670 26.287 0.03804 110.560 2910.01 147.72 186.47 1.29056 0.505 0.786 4581 200.000 259.670 25.906 0.03860 104.949 2741.24 155.04 194.35 1.32151 0.503 0.791 4469

190.000 269.670 25.522 0.03918 99.606 2581.36 162.37 202.28 1.35148 0.500 0.795 4359 180.000 279.670 25.134 0.03979 94.516 2430.55 169.72 210.24 1.38047 0.496 0.797 4255 170.000 289.670 24.744 0.04041 89.665 2288.73 177.04 218.20 1.40843 0.4 87 0.795 4160 160.000 299.670 24.351 0.04107 85.043 2155.72 184.30 226.12 1.43530 0.474 0.788 4074 150.000 309.670 23.955 0.04175 80.639 2031.14 191.45 233.96 1.46105 0.461 0.781 3993 140.000 319.670 23.557 0.04245 76.445 1914.60 198.56 241.79 1.48589 0.459 0.785 3894 130.000 329.670 23.157 0.04318 72.454 1805.66 205.66 249.64 1.51006 0.454 0.785 3804

120. 000 339.670 22.754 0. 04395 68.656 1703. 85 212.73 257.49 1.53351 0.449 0.785 3715 110.000 349.670 22.351 0.04474 65.047 1608.60 219.78 265.34 1.55631 0.446 0.786 3627 100.000 359.670 21.946 0.04557 61.620 1520.12 226.81 273.22 1.57851 0.443 0.788 3541 -90.000 369.670 21.540 0.04643 58.368 1437.48 233.83 281.11 1.60015 0.440 0.790 3457

-80. 000 379.670 21.134 0.04732 55.286 1360.57 240.83 289.02 1.62126 0.439 0.792 3374 -70.000 389.670 20.728 0.04825 52.368 1289.13 247.82 296.95 1.64189 0.437 0. 794 3295 -60.000 399.670 20.322 0.04921 49.608 1222.95 254.78 304.89 1.66202 0.433 0.793 3223 -50.000 409.670 19.916 0.05021 47.001 1161.79 261.70 312.83 1.68164 0.431 0.795 3150 -40.000 419.670 19.513 0.05125 44.540 1105.47 268.59 320.79 1.70082 0.430 0.797 3079 -30.000 429.670 19.111 0.05233 42.221 1053.79 275.47 328.77 1.71961 0.430 0.799 3011 -20.000 439.670 18.712 0.05344 40.036 1006.55 282.34 336.77 1.73801 0.431 0.801 2945 -10.000 449.670 18.316 0.05460 37.981 963.55 289. 18 344.79 1.75 60 6 0.432 0.803 2882

0. 000 459.670 17.923 0.05579 36.049 924.60 296.01 352.84 1.77375 0.433 0.806 2822

10. 000 469.670 17.536 0.05703 34.234 889.48 302.82 360.90 1.79111 0.435 0.808 2766 20.000 479.670 17.154 0.05830 32.531 857.98 309.62 368.99 1.80815 0.437 0.809 2713 30.000 489.670 16.778 0.05960 30.934 829.91 316. 39 377.09 1.82487 0.439 0.811 2664 40.000 499.670 16.409 0.06094 29.436 805.04 323.14 385.21 1.84127 0.442 0.812 2617 50.000 509.670 16.047 0.05232 28.033 783. 17 329.86 393.33 1.85737 0.445 0.813 2575 60.000 519.670 15.693 0.06372 26.719 764.10 336.56 401.45 1.87316 0.448 0.813 2535 70.000 529.670 15.348 0.06516 25.489 747.62 343.22 409.58 1.88865 0.451 0. 813 2499

80. 000 539.670 15.011 0.06662 24.337 733.54 349.86 417.70 1.90384 0.454 0.312 2466

100. 000 559.670 14.367 0.05961 22.251 711.85 363.03 433.92 1.93335 0.461 0.810 2408 120.000 579.670 13.761 0.07267 20.425 697.65 376.08 450.09 1.96173 0.468 0.807 2361 140.000 599.670 13.196 0.07578 18.825 689.73 389. 0C 466.18 1.98902 0.475 0. 803 2324 160.000 619.670 12.669 0.07893 17.421 687.06 401.81 482.20 2.01529 0.483 0.799 2295 180.000 639.670 12.181 0.08210 16.186 688.77 414.52 498.13 2.04060 0.491 0.795 2273 200.000 659.670 11.729 0.08526 15.098 694. 09 427.14 513.98 2.06500 0.499 0.791 2257 220.000 679.670 11.310 0.08842 14.136 702.19 439.71 529.76 2.08857 0.508 0.788 2247

240. 000 699.670 10.922 0.09156 13.281 712.09 452.24 545.49 2.11137 0.516 0.785 2240 280.000 739.670 10.229 0.09776 11.835 734.22 477.28 576.85 2.15496 0.534 0.784 2235 320.000 779.670 9.626 0.10388 10.663 757.77 502.42 608.21 2.19626 0.552 0.785 2236 360.000 819.670 9.098 0.10991 9.694 782. 31 527.78 639.72 2.23566 0.570 0.790 2242 400.000 859.670 8.631 0.11586 8.884 808.20 553.44 671.44 2.27345 0.588 0.796 2253 440.000 899.670 6.216 0.12172 8.198 835.71 579.48 703.44 2.30983 0.606 0.804 2267

269
M£ THANE ISOB AR t T P = 6300.0 PSI

T T DEN VOL CP/DT OP/DO F H S CV CP W DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 3TU/LB 3TU/LB BTU/LP/R 9TU/L8/R eTU/L^/R FT/S

278. 198 181. 472 28. 947 0. 03455 157.818 4260. 27 97. 67 136.05 1. 33787 5 36 0. 770 5327

27 0. 000 189, 670 28. 655 0. 03490 151.548 4125.23 103. 44 142.21 1. 07165 536 3. 775 5253

260. 000 199. 670 28. 288 0. 03535 144.14? 3943.24 110. 61 149.89 1. 11155 535 0. '78 5156

250. 000 209. 670 27. 923 0. 03581 137.076 3755.84 117. 84 157.63 1. 14960 530 3, 779 5058

21.0. 000 219. 670 27. 558 0. 03629 130.351 3567.74 125. 07 165.39 1. 185e6 523 3. '76 4959

230. 000 229. 670 27 . 192 0, 03678 123.954 3382.23 132. 30 173.15 1. 22051 517 3. 773 4356

22 0. 000 239. 670 26. 825 0. 03728 117.870 3201.67 139. 51 180.93 1. 25368 511 0. '79 4754

210. 000 2 49. 670 26. 456 0. 03780 112.081 3027.70 146. 73 188.73 1 28556 508 0. 782 4648

200. 000 259. 670 26. 084 0. 03834 106.570 2861. 38 153, 97 196.57 1. 31634 505 3. 786 4540

190. coo 269. 670 25. 711 0. 03889 101.320 2703.36 161. 23 204.45 1. 34611 3 5C3 0. '90 4435

180. 000 279. 670 25. 335 c. 03947 96. 318 2553.94 168. 50 212.35 1. 37490 498 0. 791 4336

170. 000 289. 670 24. 95 7 0, 04007 91.549 2413. 17 175. 7k 220.26 1 40265 489 3. 788 4245

160. 000 299. 670 24. 576 0. 04069 87.004 2280.92 18? 9C 228.11 1 42930 476 0. 781 4163

150. 000 309. 670 24. 194 0. 04133 82.672 2156.90 189 95 235.88 1 45462 463 0. 774 4086

140. 000 319. 670 23. 810 0. 04200 78.545 2040.75 196 97 243.63 1 47942 461 777 3990

130. 000 329. 670 23 424 0, 04269 74.614 1932. 05 203 97 251.40 1 50334 456 0. 7 76 3905

120. 000 339. 670 23 037 0. 0*341 70.872 1830.40 210. 93 259.16 1 52654 451 776 3820

110. 000 349. 670 22. 650 0. 04415 67.312 1735.37 217 67 266.93 1. 549C7 .447 0. 777 373c

100. 000 359. 670 22. 262 0. 04492 63.928 1646.58 224. 79 274. 70 1 57100 ,444 778 3654

-90. 000 369. 670 21. 873 0. 04572 60.715 1563.68 231 70 282.49 1 59235 442 0. 779 3574

-80 000 379 67 21 485 0. 0*654 57.664 1486.35 238 58 290.29 1 61317 . 440 731 3495

-70. 000 389. 670 21 091 0. 04740 54.772 1414.29 245 45 298.11 1 63349 ,439 0. 783 3*19

-60. 003 399. 670 20 711 o. 04828 52.032 1347.27 252 ?e 305.93 1 65332 ,434 781 3351

-50. 000 409 670 20 325 0. 04920 49.438 1285.07 259 06 313.74 1 67262 3 432 3 ?32 3281

-'0. 000 •+19. 670 19 942 0. 05015 46.984 1227.47 265. 85 321.56 1 69143 3 4 32 7 83 3212

-30. 000 429, 670 19 560 0. 05112 44.666 1174.28 272. 60 329. 4C 1 70994 431 785 3146

-20. 000 439. 670 19. 181 0. 05213 42.477 1125.32 ?79 34 337.26 1 72602 432 787 3082

-10. 000 449. 670 18 305 0. 05318 40.411 1080.40 266 06 345.14 1 7457* 433 789 3020

0. 000 -»59 670 18 433 0. 05425 38.464 1P39.34 292. 76 3 5 3.04 I 76312 4 34 791 2961

10. 000 •69. 67 18 065 0. 35535 36.628 1001.95 299. 46 363.96 1 78016 436 3 793 2905

20. 000 479. 670 17 702 05649 34.903 968.05 3 06 13 368.90 1 79669 ,438 3 795 2852

30. 000 *89. 670 17 34* 05766 3 3.27 3 937.45 312 er 376.85 1 81330 441 3 797 2802

40. 000 •99 670 16 992 05885 31.742 909.97 319 44 384.83 1 8294? ,443 798 2755

50. 000 509 670 16 647 0. 05007 30.303 885. 41 326. 07 392.81 1 64524 3 446 3 799 2711

60 coo 519 670 16 303 0. 06132 28.949 863.61 332 68 400.81 1 86 78 ,449 300 2670

70 000 529 670 15 977 06259 27.677 844. 37 339. 27 408.81 1 876 3 ,452 3 800 2632

80 00 539 670 15 653 0. 05389 26.481 827. 53 345 84 416.82 1 89101 ,1.55 3 301 2597

100. 000 559. 670 15 029 06654 24. 302 800. 36 358 90 432.83 1 92015 3 462 301 2535

120 000 579 670 14 439 05926 22.377 780.82 371 86 448.83 1 94824 3 4F9 3 799 2463

140 000 599 670 13 883 0*203 20.677 767.74 384 77 *64.80 I 975 33 477 n 798 2439

160 000 619 670 13 361 07484 19. 174 760.13 397 .58 480.74 2 ,00146 ,485 3 '96 2404

180 000 639 670 12 87 3 07768 17.843 757. 13 410 32 496.63 2 02670 ,493 793 2376

200 000 659 670 12 .418 3 5 3 16.661 758. 01 423 01 512.48 2 05110 501 3 791 2355

22 000 679 670 11 994 8 3 3 8 15.609 762. 14 435 65 528.29 2 07471 .510 790 2333

2<»0 000 699 670 11 59 3 03622 14.671 768.96 448 27 544.06 2 09758 3 .519 3 738 2327

280 000 739 670 10 386 09186 13. 077 787.91 473 50 575.56 2 14136 ,536 3 787 2315

320 000 779 670 10 26 5 09742 11.781 809.86 498 84 607.08 2 18286 3 554 0. 789 2311

36 000 819 670 9 718 13291 10.709 83?. 94 524 39 638.73 2 22244 .572 0. 794 2313

400 000 859 670 9 .232 10832 9.811 656.79 550 26 670.60 2 76041 .550 0. 300 2319

1*1*0 000 399 670 8 799 0. 11365 9. 048 881.53 576 49 702.77 2 29698 3 608 0. 303 2329

270
METHANE ISOBAR AT P = 7000. PSI

T T DEN VOL OP/DT DP/DD E H S C\l CP W DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LP 9TU/LB BTU/LB/R BTU/LB/R BTU/L'3/R FT/S

275. 306 184. 364 29.062 03441 156. 591 4335. 44 98 62 143. 22 1. 04242 541 770 5345

270 000 189 670 28.893 0. 03461 152 825 4268. 77 102 24 147 11 1 06355 ,542 772 5306

260. 000 199 67 28.537 0. 03504 145, 759 4109. 40 109 33 154, 76 1, 10329 540 775 5226

?50. 000 209 670 28.183 03548 138 987 3939. 94 116 46 162 46 1 14116 .535 775 5141

240. 000 219. 67 27.831 0. 03593 132. 523 3766. 07 123. 60 170. 17 1. 17723 528 0, 77 3 5053

230 000 229 670 27.479 03639 126 361 3591 85 130 71 177 89 1 21162 522 772 4963

220, 000 239. 670 27.127 0. 03686 120. 491 3420, 16 137 82 165. 60 1 24452 516 772 4869

210, 000 249. 670 26.774 03735 114 900 3253. 09 144 92 193 33 1 27612 512 ^74 4772

200. 000 259 670 26.420 o. 03785 109 572 3092. 06 152 03 201 09 1 30658 ,510 778 4673

190. 000 269, 670 26.065 03837 104 492 2938. 03 159 15 208 88 1 33603 507 731 4576

180 000 279 670 25.709 3890 99 649 2791 55 166 27 216 69 1 36447 .503 761 4484

170 000 289. 670 25.352 0, 03945 95 028 2652. 90 173 36 224 49 1 39187 4 94 3 778 4401

160. 000 299. 670 24.993 o, 04001 90 .620 2522 13 180 37 232 23 1 .41815 .481 770 4326

150. 000 309 670 24.633 0, 04060 86 415 2399 11 187 27 239 89 1 44328 ,467 761 *25o

lf»0, o o a 319. 670 24.272 04120 8? 403 2 283, 58 194 12 2 47 52 1 46749 465 764 4168

130. 000 329, 670 23.911 0, 0*182 78 577 2175 23 200 94 255 15 1, 49100 460 763 4089

120. 000 339. 670 23.550 04246 74 930 2073. 70 207 74 262 78 1 51378 455 762 4011

110. 000 349, 670 23.189 0, 04312 71 454 197e 57 214 5C 270, 40 1 5356° ,451 762 3934

100. GOO 359, 670 22.828 04381 68 144 1889. 49 221. 23 278 02 1 55738 ,448 a 762 3859

-90. 000 369. 67 22.468 0, 04451 64 993 1806. 08 227 95 285 64 1 57828 445 763 3765

-80. 000 379. 670 22.103 04523 61 996 1728, 01 234 64 293 27 1 59865 443 763 3712

-70. 000 389. 670 21.750 0, 0*598 59 146 1654. 96 241. 31 300 91 1 61851 442 '64 3642

-60. 000 399. 670 21.394 0, 04674 56. 438 1586. 67 247 95 306 54 1 63765 ,437 762 3579

-50. 000 409. 670 21.039 0. 04753 53 866 1522. 87 254. c;c, 316. 16 1 65667 435 7 62 3514

-4 0. 000 419. 670 20.686 0. 04834 51 424 1463 36 261 12 323 76 1 67505 .434 762 3450

-30. 000 429. 670 20 .336 0, 04917 49 109 1407. 93 267 67 331 41 1 69302 434 764 3387

-20, 000 439 670 19.989 0, 0500 3 46 913 1356. 36 274 21 339 05 1 71061 .435 765 3326

-10. 000 *49. 670 19.645 0. 05090 44. 832 130 8. 55 280. 73 346. 71 1, 72783 a 435 767 3268

0. 000 459 670 19. 304 05180 42 860 1264 28 287 24 354 39 1 74472 .437 769 3211

10. 000 469, 670 16.96 7 0, 05272 40. 993 1223. 40 293 75 362. 09 1. 76129 439 771 3156

20. 000 479, 670 18.634 0, 05367 39 226 1185 76 30C. 24 369. 80 1 77754 ,441 '73 3104

30. 000 •+89. 67 18.305 0. 05463 37. 554 1151. 20 306. 73 377 54 1 79350 .443 0, 774 3054

40. 000 499. 670 17.981 05561 35 971 1119. 57 313. 21 385 29 1 80 9ie 446 776 3006

50. 000 509. 670 17.66 3 0. 05662 34. 475 1090. 73 319 68 393, 06 1. 82457 448 0, 778 2961

60. 000 519. 670 17.34-) 05764 33 059 1C64, 52 326 14 400 85 1 83971 ,451 3 780 2919

70. 000 529. 670 17. 042 0. 05868 31. 721 1040 8C 332 59 408 65 1 85458 .454 781 2879

80. ooo 539. 670 16.740 0. 05974 30 455 1019, 42 339 04 416. 47 1, 86920 458 782 2841

100. 000 559. 670 16.155 0, 05190 28 127 983, 13 351 9C 432. 14 1 69771 465 '84 2772

120. 000 579. 670 15.596 0. 06412 26. 046 954, 57 364, 73 * h7 . 84 1, 92523 472 7 36 2713

140. 000 599. 670 15.064 0. 05638 24 185 932. 74 377 53 463 5e 1 95 196 460 787 2661

160. 000 619. 670 14.559 0. 06869 22. 519 916. 70 39G, 2° 479 33 1, 97779 488 738 2618

180. 000 639. 670 14.081 0, 07102 21 026 905. 63 403 03 495, 09 2 C0283 497 '68 2580

200. 000 659. 670 13.630 0. 07337 19 686 898. 82 415. 76 510. 86 2. 02711 505 o. 789 2550

220. 000 679. 670 13.205 0, 07573 18 482 895 64 428 48 526. 64 2 05068 514 769 2524

240. 000 699. 670 12.804 0, 07810 17. 398 895. 56 441. 20 542. 44 2 07358 523 3. 790 250*

280. 000 739 670 12.072 0, 08283 IE. 533 903. CI 466. 71 574. OP 2, 11756 ,541 792 2473

320. 000 779. 670 11.424 0. 08753 14, 000 918. 12 492. 37 605. 83 7, 15936 559 0. 795 2460

360. 000 819. 670 10.849 0, 09218 12 726 937, 79 518 26 637. 74 2. 19927 578 300 2454

400. 000 859. 670 10.335 0. 3676 11 , 656 959. 22 544 46 669. 87 2. 23755 5 96 0. 507 2453

440, 000 899. 670 9.874 0. 10128 10. 745 961 . 3 8 571, 02 702. 29 2, 27441 613 0. 314 2457

271
ME THANE ISO!JAR AT P = 8000.0 PSI

T T DEM VOL CP/OT DP/CD E H S cv CP H DEC F Dc & R LB/CUFT CUFT/LB PSI/R PSICUFT/L8 3TU/LG 9TU/LB BTU/LB/R BTU/LB/R 9TU/L3/R FT/S

272. 452 187. 218 29 17 3 0. 03428 155. 437 4401. 89 99. 60 150.38 1. 04696 3. 546 0. 770 5 361

270, 000 189. 670 29, 124 0. 03434 153. 900 4388. 93 101. 15 152.01 1. 05575 3 547 0. 771 5352

260. 000 199, 670 28 776 0. 03475 147. 172 4255.21 108. 16 159.64 1. 09540 545 0. 772 5285

250. 000 209. 670 28 431 0. 03517 140. 689 4105.95 115 21 167.31 1 13313 540 0. 7 72 5213

240. 000 219. 670 28. 090 0. 03560 134. 476 3948.08 122. 26 174.99 1, 16903 3 533 0. '69 5137

230. 000 229. 670 27 750 0. 03604 128. 537 3786.52 129. 28 182.66 1. 20323 526 0. 767 5057

220 000 239. 670 27 411 0. 03648 122 868 3624.83 136. 28 190.33 1. 23592 521 3. 767 4973

210. 000 249. 670 27 072 0, 03694 117. 459 3465.56 143. 28 198. OC 1. 26728 517 3. 768 4884

200. 000 259 670 26 733 03741 112 299 3310.54 150. 2e 205.69 1 29750 ,515 3. 771 4794

190. 000 269. 670 26. 393 0. 03789 137. 374 3161. 04 157. 29 213.42 1. 32668 512 0. 773 4704

180 000 279. 670 26 053 03838 102. 673 3017.91 164 29 221.15 1 35484 3 507 0. 773 4619

170, 000 289. 670 25 71? 0. 03889 98. 183 2881.6 5 171. 26 228.87 1, 38195 498 0. ^69 4542

160. 000 299. 670 25 372 0, 03941 93 895 2752.51 178 14 236.52 1, 40793 ,4 85 3. 761 •474

150. 000 309. 670 25 031 0. 33995 89. 800 2630. 53 184. 9C 244.09 1 43276 ,471 0. 752 4409

140. 000 319. 670 24 689 0. 04050 85. 888 2515.61 191 62 251.62 1. 45665 469 3. 754 4327

130, 000 329. 670 24 348 04107 82 152 2407.52 198 3C 259.15 1 47984 ,463 3. 752 4255

120. 000 339. 670 24 007 0, 34165 78. 585 2305.98 204. 95 266.66 1. 50233 3 459 3. '51 4182

110. 000 349. 670 23 667 0. + 225 75. 181 2210. 66 211 57 274.17 1 52408 ,455 0. 750 4111

100. 000 359. 670 23 32 7 0. 04287 71. 932 2121.21 218 16 281.67 1 54523 451 0. 750 4041

-90. 000 369. 670 22. 988 0. 04350 68. 834 2037.28 224. 73 289.17 1. 56579 449 3. 750 3972

-80. 000 379, 670 22 651 0. 0+415 65 879 1958.53 231 27 296.67 1 58582 447 0. 750 39C4

-7C. 000 389. 670 22 316 o. 04481 63. 064 1884.66 237 79 304.17 1 60533 445 3. 751 3838

-60, 000 399. 670 21 982 0, 0+549 60 382 1815. 36 244 28 311.67 1 62432 440 71,8 3780

-50. 000 409, 670 21 651 34619 57 828 1750.38 250 72 319.14 1 64279 438 3. 747 3719

-40. 000 -19 670 21 321 0, 04693 55 397 1689.46 257. 14 326.62 1 66 82 437 3. 748 3659

-30. 000 429. 670 20 995 04763 53 084 1632.41 263 5<* 334.10 1 67843 ,437 3 748 3600

-2 0. 000 439. 670 20 671 0. 34838 50. 884 1579.03 269 92 341.59 1 69567 437 n. 75 3542

-10, 003 449 670 20 350 0+914 48 791 1529. 13 276 3C 349.09 1 71254 .438 751 3485

0. 000 459. 670 20 033 04992 46, 802 1482.56 282 66 356.61 1 72908 ,439 75 3 3430

10. 000 469. 670 19 719 0. 05071 44, 912 1439. 17 289 02 364.15 1 745 3 .441 755 3377

20. 000 479. 670 19 409 05152 43 115 1398. 80 295. 38 371.70 1 76122 3 ,443 3 756 3326

30, 000 489, 670 19 103 05235 41 409 1361. 34 301 73 379.28 1 77685 .445 758 3277

40, 000 499, 670 18 801 0, 05319 39 787 1326.63 3C8 OP 386.87 I ,79220 . 448 76 3230

50. 003 509. 670 18 503 35405 38. 248 1294. 56 314 42 394.49 1 83729 3 . 451 762 3185

60 000 519 670 18 210 05492 36 785 1265.00 320 77 402.12 1 82212 3 .454 3 764 3141

70 000 529. 670 17 921 c 35580 35, 396 1237.83 327 1 1 4C9.77 1 83671 .457 3 766 31C0

80, 000 539 670 17 ,638 0, 05670 34 077 1212.92 333 46 +17.45 1 85105 461 3 768 3061

100. 000 559. 670 17 066 0. 05853 31. 635 1169.41 3 46 .14 +32.84 1 87907 ,468 3 772 2989

120. 000 579. 670 16 556 06040 29 432 1133.57 358 83 448.31 1 90621 ,475 3 '75 2925

140. 000 599 670 16 048 0. 05231 27 444 1104. 52 371 52 463.83 1 93254 ,463 3 777 2869

160. 000 619, 670 15 562 0, 06426 25 649 1081. 44 384 21 + 79.40 1 95809 492 0. 780 2819

180. 000 639- 670 15 099 06623 24 026 1063.59 396 92 495.03 1 98293 3 .530 3 782 2776

200, 000 o59. 670 14 65 9 0, 36822 22 558 1050.27 409 b>> 510. 7C 2 007C2 3 5C9 0. 785 2738

220. 000 679 670 14 240 07022 21, 228 1040. 89 422 36 526.41 2 03049 ,518 3

T 87 2706

21*0. 000 699. 670 13 843 0. T 224 20, 021 1034.91 435. 15 542.17 2. C5334 3 527 3. 789 2679

280. 000 739. 670 13 .109 07628 17 926 1031. 36 460 82 573.82 2 09734 ,545 794 2637

320. 000 779. 670 12 45 0. 09032 16 182 1036.68 486 69 605.68 2 13928 564 3 799 26C9

360. 003 819. 670 11 857 09434 14 719 1048.68 512. 84 637.77 2 17941 .582 3 90S 2592

400. 000 859. 670 11 32* 0. 08831 13. 483 1065.48 539. 3C 670.12 2 21794 600 3. 112 2584

44 0, 000 899 670 10 843 09223 12 428 1085. 10 566 13 702.76 2 25506 .618 3. 120 25e2

27 2
METHANE ISOBAR AT P = 9000.0 PSI

T T OEN VOL CP/DT OP/OD E H S cv CP H DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 3TU/I_e 9TU/LB BTU/LB/R BTU/LB/R BTU/L'1/R FT/S

269. 635 190. 035 29.283 3 1415 154. 351 4459.64 100 62 157.54 1 05149 .551 770 5375

26 000 199.670 29.007 03447 148.400 4379.20 107 08 164.54 1 08780 .550 771 5333

250, 000 209.670 28.671 c 03488 142.204 4252.91 114 oe 172.19 1 12544 .545 769 5275

240 000 219.670 28.338 0, 03529 136.236 4113. 19 121 03 179.84 1 16122 .538 766 5211

230 000 229.670 28.008 03570 130.512 3965.97 127 97 187.48 1 19527 .531 0. 764 5142

220 000 239.670 27.680 03613 125.034 3815.63 134 89 195.10 1 ,22778 .525 762 5066

210. 000 249.670 27.352 0, 03656 119.797 3665.27 141 80 202.73 1 25896 .521 0. 763 4986

200, 000 259.670 27.026 0, 03700 114.793 3517. 17 148 7C 210.37 1 28897 519 765 4903

190 000 269.670 26.699 03745 110.011 3372.94 155 62 218.03 1 31793 .516 767 4821

180. 000 279.670 26.373 0, 03792 105.440 3233.75 162. 52 225.71 1 34587 .511 0, 767 4742

170. 000 289.670 26.047 03839 101.070 3100.33 169 36 233.36 1 ,37274 ,502 '62 4671

160. 000 299.670 25.721 o. 03888 96.891 2973. 16 176. 15 240.94 1 39847 .489 0. 754 4609

150 000 309.670 25.396 0. 03938 92.894 2852.46 182 80 248.42 1 42305 .475 744 4550

140 000 319.670 25.070 0. 03989 89.072 2738.28 189, 40 255.67 1 44669 .473 746 4473

130. 000 329.670 24.745 0, 04041 85.416 2630.52 195 97 263.32 1 .46962 .467 0. '43 4405

120. 000 339.670 24.421 c. 04095 81.920 2529. 00 202 50 270.75 1 49181 .462 742 4338

110. 000 349.670 24.097 0. 04150 78.577 2433.47 209 00 278.16 1 51332 ,458 741 4271

100. 000 359.670 23.775 0, 04206 75.383 2343.63 215 47 285.57 1 53421 .455 740 4205

-90. 000 369.670 23.454 0. 04264 72.329 2259.17 221. 91 292.97 1 55451 452 0. 740 4140

-80. 000 379.670 23. 135 o. 04322 69.413 2179.78 228 33 300.37 1 ,57426 .450 740 4077

-70. 000 389.670 22.817 0. 04383 66.627 2105. 15 234 73 307.77 1 59350 448 0. 740 4015

-60. 000 399.670 22.502 0. 04444 6 3.96 8 2034.98 241 1C 315.16 1 61223 .443 0. 737 3 96 -50. 000 409.670 22.189 0. 0*507 61.430 1969.01 247 42 322.52 1 63043 441 o. 736 390 3 -1*0. 000 419.670 21.878 0, 04571 59.008 1906.98 253 71 329.89 1 64 819 ,440 0. 736 3846

-30. 000 429.670 21.570 0. 04636 56.698 1846.68 259. 99 337.25 1 66553 440 '37 3789

-20, 000 439.670 21.265 0, 04703 54.495 1793. 89 266. 26 344.63 1 68250 440 738 3734

-10. 000 •49.670 2 0.96 2 0. 04770 52.39* 1742. 44 272. 51 352.01 1 69911 441 0. 739 3660

0. 000 •+59.670 20.663 0. 04839 50.391 1694. 16 278. 76 359.41 1 71539 442 741 3627

10. 000 469.670 20.368 0. 04910 48.482 1648.90 285 01 366.83 1 73135 .444 '43 3576

20. 000 479.670 20.075 0, 04981 46.663 1606.49 291 2E 374.27 1 74701 ,446 744 3526

30. 000 -.89.670 19.787 G. 05054 44. 929 1566. 84 297. 49 381.72 1 76239 448 0. 746 3478

40. 000 499.670 19.502 05128 43.277 1529.81 303 74 389.20 1 77750 .451 749 3431

50. 000 509.670 19.221 0, 05203 41.703 1495. 27 309 99 396.69 1 79236 ,454 3 751 3 386

60. 000 519.670 18.944 0, 05279 4T.203 1463.13 316 24 404.21 1 80696 ,457 0. '53 3343

70. 000 529.670 18.671 0. 05356 38.773 1433. 26 322. 49 411.75 1 82133 460 755 3302

80. 000 539.670 18.403 0. 05434 37.412 1405.57 328. 75 419.31 1, 83547 463 '57 3262

100. 000 559.670 17.880 0, 05593 34.877 1356. 31 341 2e 434.49 1 86310 471 0, 761 3ie9

120. 000 579.670 17.375 0, 05755 32.576 1314.53 353. 84 449.76 1. 88990 ,478 0. 765 3122

140. 000 599.670 16.889 0. 05921 30.485 1279. 49 366. 43 465.11 1 91593 .487 0. 769 3062

160 000 619.670 16.422 0. 5 8 9 28.583 1250.47 379 05 480.53 1 94123 495 0. 773 3008

180. 000 639.670 15. 97* 0. 06260 26.853 1226.79 391. 70 496.03 1. 96584 504 0. 777 2960

200. 000 659.670 15.546 0. 06432 25.278 1207.83 404 40 511.60 1. 98961 ,513 0. 780 2918

220. 000 679.670 15.137 o. 06606 23.841 1193.03 417 13 527.23 2 01316 522 0. 784 2881

240. 000 699.670 14.747 0. 06781 22.530 1181.86 429 92 542.94 2. C3593 531 0. 787 2849

280. 000 739.670 14.020 c, 07133 20.235 1168.67 455. 68 574.55 2 07967 550 0. 794 2796

320. 000 779.670 13.360 0. 07485 18.306 1165.21 481. 69 606.44 2, 12185 568 0. 301 2758

360. 000 819.670 12.761 0. 07837 16.674 1169.20 508. 02 638.62 2, 16210 587 0. 308 2732

400. 000 859.670 12.217 0. 03186 15.284 1178.94 534 70 571.11 2. 20081 6C5 0. 316 2715

440. 000 899.670 11.722 0. 08531 14.092 1193. 10 561. 75 703.93 2. 23812 623 0. 325 2705

273
METHANE ISOBAR «! P = 110 0.0 PSI

T T DEN VOL DP/OT OP/CD E H S cv CP H DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 3TU/Le BTU/LB 9TU/LB/R 8TU/LB/R BTU/L 3/R FT/S

266. 853 192. 817 29. 389 0. 03403 153.327 4508. 70 101. 67 164. 67 1. 05599 0,,555 0. 770 5386

260. 000 199. 670 29.,233 0. 03421 149.456 4479. 41 106.,08 169.,43 1. 08046 0,,554 0. '70 5370

250. 000 209. 670 28. 902 o. 031.60 142.547 4 379. 48 113.,00 177. 07 1.,11805 0.,549 0. 768 5327

240. 000 219. 670 28.,57 7 0. 33499 137.823 4260. 43 119. 91 184. 70 1.,15374 . ,542 0, 7 64 5275

230. 000 229. 670 28. 255 0. 03539 132.309 4129. 59 126. 7e 192. 3? 1. 18767 0.,535 0. 761 5216

220. 000 239. 670 27,,936 0. 03580 127.016 3992. 21 133. 62 1 99. 91 1. 22005 0., 529 3. 759 5151

210. 000 249. 670 27,,618 0. 03621 121.943 3852. 08 140. 45 207. 50 1.,25108 0.,525 0, 759 5079

200. 000 259. 670 27,, 302 0. 5663 117.087 3711. 97 147. 27 215. 10 1,,2809? 0.,523 0, '61 50C4

19C. 000 269. 670 26,,987 0. 03705 112.438 3573. 03 154,, 10 222, 71 1, 30970 0.,5?0 0,,762 4928

160. 000 279. 670 26.,673 0. 03749 107.989 3439. 42 160. 91 230. 34 1. 33745 o.,515 :. '61 4856

170.,000 289.,670 26,,359 0.,03794 103.729 3309. 47 167,,6? 237,,93 1.,36412 0,,505 0. 756 4790

160. 003 299. 67 26,,046 0. 03839 9°. 651 3184. 76 174, 35 245. 45 1. 38965 , ,492 0. ^47 4733

150. 000 309. 670 25,,734 0. 03886 95.745 3065. 71 180,,91 ?52,,87 1,,41401 0,,479 0.,'37 4679

140.,000 319. 670 25.,42? 0. 03931. 92.004 2952. 54 187. 41 260. 25 1. 43744 0,, 476 0. 739 46C7

130.,000 329.,670 25,, 110 0.,03982 88.421 2845. 31 193,,88 267,,63 1,,46 016 0,.470 0,,'36 4543

120, 000 339, 670 24,,803 0. 04032 84.990 2743. 95 200,,31 274. 98 1,,48213 0,,465 0, '35 4480

110. 000 349. 670 21.,,491 0. 0*083 81.704 2648.,28 206,,71 282.,32 1,,50342 0,,4F1 1,, '33 4417

100. 000 3 59. 670 24., 183 0. 04135 76.558 2558. 10 213.,oe 289. 65 1,,52409 ,458 0,,733 4355

-90. 000 369, 670 23,,877 0. 04188 75.546 2473. 15 219. 42 296. 97 1, 54417 0,,455 3. 732 4294

-8 0,,000 379. 670 23,,572 0. 04242 72.663 2393. 14 225,,74 304.,29 1 , ,56371 ,453 0,, 732 4234

-70. 000 389. 670 23, 270 0. 04297 69.905 2317. 79 232,,03 311,,61 1,,58273 0,.451 0,,732 4175

-60. 000 399. 670 22. 969 o. 04354 67.266 2246. 82 238. 29 318,,91 1,,60124 o,,446 0,, 728 4124

-5 0.,000 409. 670 22.,671 0. 04411 64.743 2179. 97 244, 51 326, 19 1,,61923 0,, 444 0. 728 4069

-1*0, OuO i»19. 670 22,, 375 0. 04469 62.330 2116, 99 25T, 71 333, 47 1,,63678 0,, 443 0,, '28 4015

-30. 000 429. 670 22,,082 0.,04529 6 P . 2 3 2057. 65 256,, 8° 340,,74 1,,65391 . 442 0. 72e 3961

-20. 000 439. 670 21,,792 0. 04589 57.818 2001,,73 263,,05 348,,03 1,,67067 0,, 443 3,, 729 3908

-10,, 000 449. 670 21,,505 0. 04650 55.711 194°,,04 269.,21 355,,32 1,,6870e 3,, 443 0, 730 3856

0, 000 "59. 670 21,, 220 0. 04712 53.697 1899, 41 275, 37 362, 63 1,,70315 0,, 445 0. 732 3805

10,,000 469.,670 20,,939 0.,0*776 51.773 185?.,69 281,,52 369,,95 1.,71891 o,, 446 0. 733 3755 2C 000 479. 670 20. 661 o. + 840 49.935 1808,, 72 287.,67 377,,30 1 , ,73438 0,, 448 0,, 735 3707

3C. 000 489, 670 20,, 387 0.,0*905 48. 179 1767, 38 293. 83 384,,66 1.,7495 7 3,,451 n, '37 3660

40. 000 499. 670 20,,116 0.,04971 46.501 1728. 53 299,,9 C 392,,04 1 , ,7644° 0,,453 0,, '39 3 614

50. oco 509.,670 19,,84 9 0.,05038 44. 899 1692. 08 306. 15 399.,44 1. 77917 3,.456 o. 742 357C 6C 000 519. 670 19,,586 0.,05106 43.367 1657,,92 312,, 33 406,,87 1,,79363 0,,459 3,, 744 3527

70. 000 529. 670 19., 326 0. 05174 41.905 1625. 94 318,,50 -.14,,32 1.,80779 0,,462 :,,'46 3486

80.. o o a 539,,670 19.,07 0,, 05244 40.507 1596. 05 324,,6 C 421,,79 1,,82177 3 .466 a,,748 3*4t

100,, 000 559,,670 18.,571 0.,05385 37.897 154?. 15 337. 10 *36. 81 1., 84909 o,. 47 J 0. 753 3372

120.,000 579.,670 18,,087 0,,05529 35.513 1495,,53 349.,54 451,,92 1.,87562 .481 3,, 758 3 30 3 140,,000 599,,670 17,,621 0,,05675 33.335 1455. 52 362., 04 *67,,13 1.,90141 0,.490 3,, '63 3241

160,,000 619,,670 17,, 171 0,, 05824 31. 344 1421, 47 374,,58 482,,42 1.,92650 .498 c,,'67 3165

180,,000 639,,670 16,.739 0. 05974 20.522 1392. 79 387,, 19 497. 61 1.,95094 o,. 507 a. 772 3134

200,,coo o59,,670 16,. 323 0,,06126 27.855 1368,,92 399,,8? 513,,29 1.,97476 ,516 3.,776 30e8

220., 000 679,,670 15 ,925 0,,06279 2f .327 1349, 34 412,,57 528,,85 1,,99800 0,.525 0,,780 3047

240,,000 699,,670 15,,543 0,, 06434 24.926 1333,,55 425,,3f 544,,50 2..02069 .535 3,,785 3011

280,,000 739. 670 14,, 827 0., 05744 22.455 1311. 69 451.. 16 576. 05 2, 06454 ,553 0,,793 2951

320,,000 779..670 14,,172 0,,07056 20. 362 1300., 33 477,,27 607,,93 2,, 10652 ,572 3,,801 2905

360,,000 819,,670 13,,573 0,,C368 18.578 129',, 12 503,,73 640.,16 2,, 14683 0,,591 0,, il 2870

1.0 0.,000 859,,670 13,,024 0,,07678 17.048 1300,,24 530,,57 672,, 74 2,,1856* 0,.609 0.,819 2846

440., 000 899. 670 12,,522 0. 07986 15.729 1308. 34 557,,81 705,,68 2,,22309 .627 3,, 128 2829

274
NBS-114A (REV. 7-73)

U.S. DEPT. OF COMM.

BIBLIOGRAPHIC DATA

SHEET

1. PUBLICATION OR REPORT NO.

NBS TN 653

2. Gov't Accession

No.

3. Recipient's Accession No.

4. TITLE AND SUBTITLE

The Thermophysical Properties of Methane, From 90 to

500 K at Pressures to 700 Bar

5. Publication Date April 1974

6. Performing Organization Code

7. AUTHOR(S)

R. D. Goodwin

8. Performing Organ. Report No.

9. PERFORMING ORGANIZATION NAME AND ADDRESS

national bureau of standards, Boulder Labs

DEPARTMENT OF COMMERCE

Boulder, Colorado 80302

10. Project/Task/Work Unit No. ?,750364

11. Contract/Grant No.

1.2. Sponsoring Organization Name and Complete Address (Street, City, State, ZIP)

The American Gas Association

1515 Wilson Boulevard

Arlington, Virginia 22209

13. Type of Report & Period Covered 1970 to

pre sent- -Final

14. Sponsoring Agency Code

5. SUPPLEMENTARY NOTES

6. ABSTRACT (A 200-word or less (actual summary of most significant information. If document includes a significant

bibliography or literature survey, mention it here.)

Thermophysical properties of methane are tabulated at uniform temperatures

from 90.68 to 500 K along isobars to 700 bar. A novel equation of state is employed

for the first time, having origin on the vapor -liquid coexistence boundary. Computations are based almost entirely on ideal gas specific heats and experimental P-P-T

data via the equation of state, without weighting to data for derived properties. Good

agreement with such data confirms validity of the equation and method. New P-P-T

data are reported at 0.3 to 1.7 times the critical density.

7. KEY WORDS (six to twelve entries; alphabetical order; capitalize only the first letter of the first key word unless a proper name; separated by semicolons) Densities; enthalpies; entropies; equation of state; internal

mergies; isobars; isochores; isotherms; Joule-Thomson inversion; latent heats of

vaporization; melting line; orthobaric densities; PVT data; specific heats; speeds of

sound; vapor pressures.

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21. NO. OF PAGES

280

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