### 1 Test item GK10051-0370 fllüssig

CAS No.

Inventory name

Batch identification

Date of production (test item)

Origin of test item

Sponsor

Date of receipt of order 17.02.2014 14:51:07

Date of receipt of test item 03.03.2014

Testing facility

Study director

Storage conditions of test item Room temperature

Test period 1 day

Storage of records Archives, GKC

Storage of sample of test item Room temperature 

## TS-MF06Y4_

### 2 

### Number average Mn n.a.g/mol Weight average Mw n.a.g/mol Mw/Mn n.a.- **Molar mass < 500 g/mol** 

### n.a.**Area % Molar mass < 1000 g/mol**  

### n.a.**Area %**

SEC RI Overlay curve see page 4 Slice printout see page 5 and following

Type of analysis: 

### Molar mass distribution by Size Exclusion, Chromatography (SEC), formerly called GPC

Aim of the measurement Determination of the molar mass distribution. Result should include distribution curve of the molar mass distribution, Mw, Mn and Slice Printout.



### Remarks: Polymer is totally insoluble. At a tenfold (40 mg/mL) of the usual concentration still no signal could be detected. Note however that the injection volume of the sample needed to be strongly reduced. At standard injection volume, the column upper pressure limits was exceeded due to sample's viscosity. It is therefore that no molar mass distribution of the polymer could be determined. This polymer is stronlgy crosslinked and therefore no longer soluble enough to preform SEC measurements at ordinary concentrations. A raw curve is depicted. In the used calibration range from 300 up to 1.6 Mio. equivalents no polymer peak could be detected.



### Date of test 03.03.2014



### Head of laboratory

Study director ( Date03.03.2014

### 3 SEC-equipment : App_F Solvent :

Column temperatur : 85°C Flow. : 1mL/min Injection volume : 5μL Concentration : 40mg/mL Sample preparation

Column combination :

Column material Nr. i.D.Length

mm cm

1494 8 5 Polyester copo GRAM Vorsäule 1501 8 30 Polyester copo GRAM 30A 1496 8 30 Polyester copo GRAM 1000A 1497 8 30 Polyester copo GRAM 1000A

Plate height at given flow: 20000

calibration curve: F_628_normal_PMMA_Gram_S1494_S1501_S1496_S1497.CAL

Detector:



### Calibration:

Integration limits: DRI Agilent 1100 DMAC + 0.5% LiBr

Colums Column type



### The callibration was obtained with narrow molar mass standards (PMMA, molar mass range 800

-1820000 g/mol, PSS). Extrapolation was used to estimate the molecular weight distribution outside the range of these calibration standards with respect to the exclusion and permeation limits.

The lowest possible integration limit was set at 32,37mL (M(300) ca. ) No lower molar masses could be obtained due to possible polymer additives or impurities.

### 4 

### SECcurve

0 0.0002 0.0004 0.0006 0.0008

0.001 0.0012 0.0014 0.0016 0.0018

0.002

100 1,000 10,000100,0001,000,000dM/dLogM



### Relative Molar mass (g/mol) 

## GMC-Nr 14Y08133

System Int. limit 300 g/mol

Non applicable



### 14161820222426283032343638404244 0 0.05

0.1 0.15

0.2 0.25

0.3 0.35

Vol. (mL)Int. (mV) 

## GMC-Nr 14Y08133

System Int. limit 300 g/mol

GK10051-0370 fllüssig DRI

### 5 

### Calibration curve:

### 6 

### Slice table:

M (g/mol) mL WlogM by AreaIntergral distribution 300 32.37 1.687E-03 0.001 303 32.36 1.665E-03 0.003 306 32.34 1.643E-03 0.004 309 32.32 1.639E-03 0.006 312 32.31 1.631E-03 0.007 316 32.29 1.628E-03 0.009 319 32.28 1.617E-03 0.011 322 32.26 1.619E-03 0.012 326 32.25 1.621E-03 0.014 329 32.23 1.622E-03 0.016 332 32.22 1.629E-03 0.017 336 32.20 1.626E-03 0.019 339 32.19 1.637E-03 0.020 343 32.17 1.624E-03 0.022 346 32.16 1.621E-03 0.024 350 32.14 1.626E-03 0.025 353 32.13 1.635E-03 0.027 357 32.11 1.617E-03 0.029 360 32.09 1.619E-03 0.030 364 32.08 1.630E-03 0.032 368 32.06 1.629E-03 0.033 372 32.05 1.624E-03 0.035 375 32.03 1.624E-03 0.037 379 32.02 1.632E-03 0.038 383 32.00 1.636E-03 0.040 387 31.99 1.623E-03 0.042 391 31.97 1.634E-03 0.043 395 31.96 1.635E-03 0.045 399 31.94 1.649E-03 0.046 403 31.93 1.645E-03 0.048 407 31.91 1.642E-03 0.050 412 31.90 1.651E-03 0.051 416 31.88 1.645E-03 0.053 420 31.86 1.633E-03 0.055

### 7 465 31.71 1.570E-03 0.071 470 31.70 1.570E-03 0.072 475 31.68 1.553E-03 0.074 480 31.67 1.550E-03 0.075 485 31.65 1.557E-03 0.077 490 31.64 1.560E-03 0.078 495 31.62 1.565E-03 0.080 500 31.60 1.565E-03 0.082 505 31.59 1.565E-03 0.083 510 31.57 1.571E-03 0.085 515 31.56 1.571E-03 0.086 520 31.54 1.553E-03 0.088 526 31.53 1.544E-03 0.089 531 31.51 1.543E-03 0.091 537 31.50 1.542E-03 0.093 542 31.48 1.528E-03 0.094 548 31.47 1.516E-03 0.096 553 31.45 1.519E-03 0.097 559 31.44 1.513E-03 0.099 565 31.42 1.504E-03 0.100 570 31.41 1.496E-03 0.102 576 31.39 1.494E-03 0.103 582 31.37 1.473E-03 0.105 588 31.36 1.473E-03 0.106 594 31.34 1.473E-03 0.108 600 31.33 1.473E-03 0.109 606 31.31 1.463E-03 0.110 613 31.30 1.459E-03 0.112 619 31.28 1.466E-03 0.113 625 31.27 1.476E-03 0.115 632 31.25 1.479E-03 0.116 638 31.24 1.484E-03 0.118 645 31.22 1.484E-03 0.119 651 31.21 1.463E-03 0.121 658 31.19 1.470E-03 0.122 665 31.18 1.467E-03 0.124 672 31.16 1.459E-03 0.125 678 31.15 1.455E-03 0.127 685 31.13 1.451E-03 0.128 692 31.11 1.424E-03 0.129 700 31.10 1.411E-03 0.131 707 31.08 1.416E-03 0.132 714 31.07 1.425E-03 0.134

### 8 791 30.92 1.397E-03 0.148 799 30.90 1.391E-03 0.149 807 30.88 1.387E-03 0.151 815 30.87 1.383E-03 0.152 824 30.85 1.384E-03 0.153 832 30.84 1.398E-03 0.155 841 30.82 1.403E-03 0.156 849 30.81 1.416E-03 0.158 858 30.79 1.409E-03 0.159 867 30.78 1.411E-03 0.160 876 30.76 1.409E-03 0.162 885 30.74 1.413E-03 0.163 894 30.73 1.411E-03 0.165 903 30.71 1.409E-03 0.166 912 30.70 1.412E-03 0.167 921 30.68 1.422E-03 0.169 931 30.67 1.419E-03 0.170 940 30.65 1.410E-03 0.172 950 30.64 1.411E-03 0.173 960 30.62 1.415E-03 0.175 970 30.60 1.423E-03 0.176 980 30.59 1.431E-03 0.177 990 30.57 1.433E-03 0.179 1000 30.56 1.428E-03 0.180 1010 30.54 1.427E-03 0.182 1020 30.52 1.422E-03 0.183 1031 30.51 1.401E-03 0.185 1041 30.49 1.412E-03 0.186 1052 30.48 1.415E-03 0.187 1063 30.46 1.435E-03 0.189 1074 30.45 1.449E-03 0.190 1085 30.43 1.447E-03 0.192 1096 30.41 1.438E-03 0.193 1107 30.40 1.454E-03 0.195 1118 30.38 1.452E-03 0.196 1130 30.37 1.444E-03 0.197 1141 30.35 1.442E-03 0.199 1153 30.33 1.436E-03 0.200 1165 30.32 1.434E-03 0.202 1177 30.30 1.445E-03 0.203 1189 30.28 1.449E-03 0.205 1201 30.27 1.436E-03 0.206 1214 30.25 1.437E-03 0.208

### 9 1344 30.09 1.490E-03 0.222 1358 30.07 1.498E-03 0.224 1372 30.06 1.498E-03 0.225 1386 30.04 1.479E-03 0.227 1400 30.02 1.466E-03 0.228 1414 30.01 1.470E-03 0.230 1429 29.99 1.468E-03 0.231 1443 29.97 1.478E-03 0.233 1458 29.96 1.485E-03 0.234 1473 29.94 1.479E-03 0.235 1488 29.92 1.484E-03 0.237 1503 29.91 1.506E-03 0.238 1519 29.89 1.504E-03 0.240 1534 29.87 1.511E-03 0.241 1550 29.86 1.524E-03 0.243 1566 29.84 1.521E-03 0.245 1582 29.82 1.507E-03 0.246 1598 29.81 1.502E-03 0.248 1615 29.79 1.502E-03 0.249 1631 29.77 1.503E-03 0.251 1648 29.76 1.516E-03 0.252 1665 29.74 1.518E-03 0.254 1682 29.72 1.545E-03 0.255 1699 29.71 1.539E-03 0.257 1717 29.69 1.545E-03 0.258 1734 29.67 1.549E-03 0.260 1752 29.66 1.540E-03 0.261 1770 29.64 1.538E-03 0.263 1788 29.62 1.544E-03 0.264 1806 29.61 1.534E-03 0.266 1825 29.59 1.527E-03 0.267 1844 29.57 1.549E-03 0.269 1863 29.55 1.555E-03 0.271 1882 29.54 1.549E-03 0.272 1901 29.52 1.527E-03 0.274 1920 29.50 1.512E-03 0.275 1940 29.49 1.513E-03 0.277 1960 29.47 1.519E-03 0.278 1980 29.45 1.528E-03 0.280 2000 29.44 1.535E-03 0.281 2021 29.42 1.541E-03 0.283 2042 29.40 1.543E-03 0.284 2063 29.38 1.544E-03 0.286

### 10 2284 29.21 1.558E-03 0.301 2307 29.19 1.567E-03 0.303 2331 29.18 1.567E-03 0.305 2355 29.16 1.568E-03 0.306 2379 29.14 1.569E-03 0.308 2404 29.12 1.569E-03 0.309 2428 29.11 1.570E-03 0.311 2453 29.09 1.566E-03 0.312 2478 29.07 1.554E-03 0.314 2504 29.05 1.545E-03 0.315 2529 29.04 1.538E-03 0.317 2555 29.02 1.561E-03 0.319 2581 29.00 1.565E-03 0.320 2608 28.98 1.567E-03 0.322 2635 28.97 1.578E-03 0.323 2662 28.95 1.584E-03 0.325 2689 28.93 1.601E-03 0.326 2717 28.91 1.611E-03 0.328 2744 28.89 1.596E-03 0.330 2773 28.88 1.581E-03 0.331 2801 28.86 1.567E-03 0.333 2830 28.84 1.577E-03 0.334 2859 28.82 1.585E-03 0.336 2888 28.81 1.582E-03 0.338 2918 28.79 1.565E-03 0.339 2948 28.77 1.557E-03 0.341 2978 28.75 1.556E-03 0.342 3008 28.73 1.560E-03 0.344 3039 28.72 1.562E-03 0.345 3070 28.70 1.572E-03 0.347 3102 28.68 1.568E-03 0.348 3134 28.66 1.585E-03 0.350 3166 28.64 1.594E-03 0.352 3198 28.63 1.586E-03 0.353 3231 28.61 1.610E-03 0.355 3264 28.59 1.614E-03 0.356 3298 28.57 1.609E-03 0.358 3331 28.55 1.624E-03 0.360 3366 28.54 1.623E-03 0.361 3400 28.52 1.615E-03 0.363 3435 28.50 1.605E-03 0.365 3470 28.48 1.600E-03 0.366 3506 28.46 1.604E-03 0.368

### 11 3882 28.28 1.630E-03 0.384 3922 28.26 1.613E-03 0.386 3962 28.24 1.615E-03 0.387 4003 28.22 1.633E-03 0.389 4044 28.21 1.650E-03 0.390 4085 28.19 1.653E-03 0.392 4127 28.17 1.642E-03 0.394 4169 28.15 1.647E-03 0.395 4212 28.13 1.671E-03 0.397 4255 28.11 1.673E-03 0.399 4299 28.10 1.684E-03 0.400 4343 28.08 1.684E-03 0.402 4388 28.06 1.670E-03 0.404 4433 28.04 1.672E-03 0.405 4478 28.02 1.667E-03 0.407 4524 28.00 1.670E-03 0.409 4570 27.98 1.650E-03 0.410 4617 27.96 1.644E-03 0.412 4665 27.95 1.635E-03 0.414 4712 27.93 1.623E-03 0.415 4761 27.91 1.647E-03 0.417 4810 27.89 1.657E-03 0.419 4859 27.87 1.665E-03 0.420 4909 27.85 1.675E-03 0.422 4959 27.83 1.677E-03 0.424 5010 27.82 1.685E-03 0.425 5061 27.80 1.694E-03 0.427 5113 27.78 1.677E-03 0.429 5166 27.76 1.662E-03 0.430 5218 27.74 1.664E-03 0.432 5272 27.72 1.667E-03 0.434 5326 27.70 1.653E-03 0.435 5381 27.68 1.649E-03 0.437 5436 27.66 1.631E-03 0.439 5492 27.65 1.645E-03 0.440 5548 27.63 1.652E-03 0.442 5605 27.61 1.641E-03 0.444 5662 27.59 1.641E-03 0.445 5720 27.57 1.652E-03 0.447 5779 27.55 1.669E-03 0.449 5838 27.53 1.658E-03 0.450 5898 27.51 1.653E-03 0.452 5958 27.49 1.631E-03 0.453

### 12 6598 27.30 1.607E-03 0.470 6666 27.28 1.623E-03 0.471 6734 27.26 1.644E-03 0.473 6803 27.24 1.650E-03 0.475 6873 27.23 1.639E-03 0.476 6944 27.21 1.639E-03 0.478 7015 27.19 1.648E-03 0.480 7087 27.17 1.631E-03 0.481 7159 27.15 1.632E-03 0.483 7233 27.13 1.634E-03 0.484 7307 27.11 1.639E-03 0.486 7382 27.09 1.658E-03 0.488 7458 27.07 1.649E-03 0.489 7534 27.05 1.628E-03 0.491 7611 27.03 1.609E-03 0.493 7689 27.01 1.611E-03 0.494 7768 26.99 1.588E-03 0.496 7848 26.97 1.582E-03 0.497 7928 26.95 1.597E-03 0.499 8010 26.94 1.611E-03 0.501 8092 26.92 1.613E-03 0.502 8175 26.90 1.622E-03 0.504 8258 26.88 1.638E-03 0.505 8343 26.86 1.620E-03 0.507 8429 26.84 1.617E-03 0.509 8515 26.82 1.622E-03 0.510 8602 26.80 1.615E-03 0.512 8691 26.78 1.600E-03 0.514 8780 26.76 1.600E-03 0.515 8870 26.74 1.619E-03 0.517 8961 26.72 1.625E-03 0.518 9052 26.70 1.633E-03 0.520 9145 26.68 1.633E-03 0.522 9239 26.66 1.631E-03 0.523 9334 26.64 1.631E-03 0.525 9429 26.62 1.617E-03 0.527 9526 26.60 1.610E-03 0.528 9624 26.58 1.608E-03 0.530 9723 26.56 1.615E-03 0.531 9822 26.54 1.607E-03 0.533 9923 26.53 1.615E-03 0.535 10025 26.51 1.638E-03 0.536 10127 26.49 1.644E-03 0.538

### 13 11215 26.29 1.646E-03 0.554 11330 26.27 1.643E-03 0.556 11446 26.25 1.653E-03 0.558 11564 26.23 1.641E-03 0.559 11682 26.21 1.647E-03 0.561 11802 26.19 1.636E-03 0.563 11923 26.17 1.621E-03 0.564 12045 26.15 1.629E-03 0.566 12169 26.13 1.625E-03 0.567 12293 26.11 1.635E-03 0.569 12419 26.09 1.620E-03 0.571 12547 26.07 1.599E-03 0.572 12675 26.05 1.626E-03 0.574 12805 26.03 1.621E-03 0.576 12937 26.01 1.617E-03 0.577 13069 25.99 1.625E-03 0.579 13203 25.97 1.610E-03 0.580 13339 25.95 1.626E-03 0.582 13475 25.93 1.639E-03 0.584 13614 25.91 1.626E-03 0.585 13753 25.89 1.640E-03 0.587 13894 25.87 1.650E-03 0.589 14037 25.85 1.647E-03 0.590 14181 25.83 1.642E-03 0.592 14326 25.81 1.625E-03 0.594 14473 25.79 1.636E-03 0.595 14621 25.77 1.639E-03 0.597 14771 25.75 1.634E-03 0.598 14923 25.73 1.626E-03 0.600 15076 25.71 1.644E-03 0.602 15230 25.69 1.620E-03 0.603 15386 25.67 1.644E-03 0.605 1554425.65 1.649E-03 0.607 15703 25.63 1.612E-03 0.608 15864 25.61 1.618E-03 0.610 16027 25.59 1.620E-03 0.611 16191 25.57 1.615E-03 0.613 16357 25.55 1.611E-03 0.615 16525 25.53 1.618E-03 0.616 16694 25.51 1.625E-03 0.618 16866 25.49 1.611E-03 0.620 17039 25.47 1.620E-03 0.621 17213 25.45 1.615E-03 0.623

### 14 19062 25.26 1.599E-03 0.639 19257 25.24 1.612E-03 0.640 19455 25.22 1.667E-03 0.642 19654 25.20 1.688E-03 0.644 19856 25.18 1.674E-03 0.645 20059 25.16 1.679E-03 0.647 20265 25.14 1.667E-03 0.649 20473 25.12 1.655E-03 0.651 20683 25.10 1.638E-03 0.652 20895 25.08 1.666E-03 0.654 21109 25.06 1.661E-03 0.655 21325 25.04 1.659E-03 0.657 21544 25.02 1.679E-03 0.659 21765 25.00 1.712E-03 0.661 21988 24.98 1.691E-03 0.662 22213 24.96 1.689E-03 0.664 22441 24.94 1.694E-03 0.666 22671 24.92 1.701E-03 0.667 22904 24.90 1.683E-03 0.669 23139 24.88 1.672E-03 0.671 23376 24.86 1.674E-03 0.672 23615 24.84 1.646E-03 0.674 23858 24.82 1.657E-03 0.676 24102 24.80 1.677E-03 0.677 24349 24.78 1.669E-03 0.679 24599 24.76 1.689E-03 0.681 24851 24.74 1.653E-03 0.682 25106 24.72 1.651E-03 0.684 25363 24.70 1.640E-03 0.686 25623 24.68 1.635E-03 0.687 25886 24.66 1.641E-03 0.689 26151 24.64 1.651E-03 0.691 26420 24.62 1.627E-03 0.692 26690 24.60 1.649E-03 0.694 26964 24.58 1.664E-03 0.695 27241 24.56 1.661E-03 0.697 27520 24.54 1.651E-03 0.699 27802 24.52 1.649E-03 0.700 28087 24.50 1.656E-03 0.702 28375 24.48 1.655E-03 0.704 28666 24.46 1.670E-03 0.705 28960 24.44 1.677E-03 0.707 29257 24.42 1.682E-03 0.709

### 15 32399 24.22 1.746E-03 0.726 32731 24.20 1.730E-03 0.727 33067 24.18 1.734E-03 0.729 33406 24.16 1.701E-03 0.731 33748 24.14 1.703E-03 0.733 34094 24.12 1.698E-03 0.734 34444 24.10 1.686E-03 0.736 34797 24.08 1.692E-03 0.738 35154 24.06 1.688E-03 0.739 35514 24.05 1.712E-03 0.741 35878 24.03 1.703E-03 0.743 36246 24.01 1.686E-03 0.744 36618 23.99 1.660E-03 0.746 36993 23.97 1.639E-03 0.748 37372 23.95 1.650E-03 0.749 37755 23.93 1.654E-03 0.751 38143 23.91 1.646E-03 0.753 38534 23.89 1.659E-03 0.754 38929 23.87 1.669E-03 0.756 39328 23.85 1.657E-03 0.758 39731 23.83 1.659E-03 0.759 40138 23.81 1.658E-03 0.761 40550 23.79 1.633E-03 0.763 40966 23.77 1.636E-03 0.764 41386 23.75 1.634E-03 0.766 41810 23.73 1.619E-03 0.768 42239 23.71 1.613E-03 0.769 42672 23.69 1.612E-03 0.771 43109 23.67 1.595E-03 0.772 43551 23.65 1.601E-03 0.774 43998 23.63 1.591E-03 0.776 44449 23.61 1.612E-03 0.777 44905 23.60 1.608E-03 0.779 45365 23.58 1.594E-03 0.780 45830 23.56 1.608E-03 0.782 46300 23.54 1.639E-03 0.784 46775 23.52 1.599E-03 0.785 47254 23.50 1.609E-03 0.787 47739 23.48 1.620E-03 0.788 48228 23.46 1.617E-03 0.790 48723 23.44 1.601E-03 0.792 49222 23.42 1.586E-03 0.793 49727 23.40 1.585E-03 0.795

### 16 55067 23.21 1.610E-03 0.811 55632 23.19 1.583E-03 0.812 56202 23.17 1.587E-03 0.814 56778 23.15 1.594E-03 0.816 57360 23.13 1.565E-03 0.817 57949 23.11 1.585E-03 0.819 58543 23.09 1.571E-03 0.820 59143 23.07 1.587E-03 0.822 59749 23.06 1.586E-03 0.824 60362 23.04 1.612E-03 0.825 60981 23.02 1.571E-03 0.827 61606 23.00 1.596E-03 0.828 62238 22.98 1.580E-03 0.830 62876 22.96 1.557E-03 0.831 63520 22.94 1.572E-03 0.833 64172 22.92 1.547E-03 0.835 64830 22.90 1.552E-03 0.836 65494 22.88 1.520E-03 0.838 66166 22.87 1.530E-03 0.839 66844 22.85 1.552E-03 0.841 67530 22.83 1.558E-03 0.842 68222 22.81 1.541E-03 0.844 68921 22.79 1.539E-03 0.845 69628 22.77 1.567E-03 0.847 70342 22.75 1.554E-03 0.849 71063 22.73 1.543E-03 0.850 71792 22.71 1.544E-03 0.852 72528 22.70 1.497E-03 0.853 73271 22.68 1.481E-03 0.855 74023 22.66 1.461E-03 0.856 74782 22.64 1.455E-03 0.857 75548 22.62 1.452E-03 0.859 76323 22.60 1.430E-03 0.860 77105 22.58 1.465E-03 0.862 77896 22.56 1.443E-03 0.863 78695 22.55 1.449E-03 0.865 79501 22.53 1.449E-03 0.866 80317 22.51 1.433E-03 0.868 81140 22.49 1.434E-03 0.869 81972 22.47 1.412E-03 0.870 82812 22.45 1.409E-03 0.872 83661 22.43 1.386E-03 0.873 84519 22.42 1.374E-03 0.875

### 17 93596 22.23 1.269E-03 0.888 94555 22.21 1.248E-03 0.889 95525 22.19 1.231E-03 0.890 96504 22.18 1.254E-03 0.892 97494 22.16 1.247E-03 0.893 98493 22.14 1.243E-03 0.894 99503 22.12 1.231E-03 0.895 100523 22.10 1.229E-03 0.897 101554 22.08 1.245E-03 0.898 102595 22.07 1.227E-03 0.899 103647 22.05 1.218E-03 0.900 104710 22.03 1.228E-03 0.901 105783 22.01 1.215E-03 0.903 106868 21.99 1.204E-03 0.904 107964 21.97 1.201E-03 0.905 109071 21.96 1.199E-03 0.906 110189 21.94 1.159E-03 0.907 111319 21.92 1.173E-03 0.909 112460 21.90 1.153E-03 0.910 113613 21.88 1.168E-03 0.911 114778 21.87 1.157E-03 0.912 115955 21.85 1.158E-03 0.913 117144 21.83 1.157E-03 0.914 118345 21.81 1.117E-03 0.916 119558 21.79 1.104E-03 0.917 120784 21.78 1.083E-03 0.918 122022 21.76 1.097E-03 0.919 123273 21.74 1.065E-03 0.920 124537 21.72 1.075E-03 0.921 125814 21.70 1.094E-03 0.922 127104 21.69 1.074E-03 0.923 128407 21.67 1.061E-03 0.924 129724 21.65 1.059E-03 0.925 131054 21.63 1.057E-03 0.926 132397 21.62 1.052E-03 0.927 133755 21.60 1.042E-03 0.928 135126 21.58 1.044E-03 0.929 136512 21.56 1.047E-03 0.930 137911 21.54 1.042E-03 0.932 139325 21.53 1.015E-03 0.933 140754 21.51 9.931E-04 0.934 142197 21.49 9.969E-04 0.935 143655 21.47 9.631E-04 0.935

### 18 159082 21.30 8.911E-04 0.945 160713 21.28 8.761E-04 0.946 162361 21.26 8.694E-04 0.946 164025 21.25 8.574E-04 0.947 165707 21.23 8.437E-04 0.948 167406 21.21 8.437E-04 0.949 169122 21.19 8.358E-04 0.950 170856 21.18 8.109E-04 0.951 172608 21.16 8.029E-04 0.951 174378 21.14 8.010E-04 0.952 176166 21.13 7.796E-04 0.953 177972 21.11 7.438E-04 0.954 179797 21.09 7.677E-04 0.955 181640 21.07 7.732E-04 0.955 183502 21.06 7.642E-04 0.956 185384 21.04 7.273E-04 0.957 187285 21.02 7.195E-04 0.958 189205 21.01 7.097E-04 0.958 191145 20.99 7.389E-04 0.959 193104 20.97 7.183E-04 0.960 195084 20.95 7.290E-04 0.960 197084 20.94 7.290E-04 0.961 199105 20.92 7.042E-04 0.962 201147 20.90 7.139E-04 0.963 203209 20.89 7.132E-04 0.963 205292 20.87 6.854E-04 0.964 207397 20.85 6.737E-04 0.965 209524 20.84 6.696E-04 0.965 211672 20.82 6.604E-04 0.966 213842 20.80 6.576E-04 0.967 216034 20.79 6.560E-04 0.967 218249 20.77 6.531E-04 0.968 220487 20.75 6.420E-04 0.969 222748 20.73 6.328E-04 0.969 225032 20.72 6.322E-04 0.970 227339 20.70 6.335E-04 0.970 229670 20.68 6.219E-04 0.971 232024 20.67 6.225E-04 0.972 234403 20.65 6.150E-04 0.972 236807 20.63 6.107E-04 0.973 239235 20.62 5.980E-04 0.974 241687 20.60 5.795E-04 0.974 244165 20.58 5.731E-04 0.975

### 19 270386 20.42 5.098E-04 0.980 273159 20.40 5.010E-04 0.981 275959 20.39 5.153E-04 0.981 278789 20.37 4.893E-04 0.982 281647 20.35 4.843E-04 0.982 284535 20.34 5.013E-04 0.983 287452 20.32 4.525E-04 0.983 290399 20.31 4.336E-04 0.983 293377 20.29 4.306E-04 0.984 296385 20.27 4.292E-04 0.984 299423 20.26 4.279E-04 0.985 302493 20.24 4.409E-04 0.985 305595 20.22 4.151E-04 0.986 308728 20.21 4.057E-04 0.986 311893 20.19 4.042E-04 0.986 315091 20.18 3.962E-04 0.987 318322 20.16 3.926E-04 0.987 321585 20.14 3.846E-04 0.988 324882 20.13 3.809E-04 0.988 328213 20.11 3.669E-04 0.988 331579 20.10 3.771E-04 0.989 334978 20.08 3.636E-04 0.989 338413 20.06 3.556E-04 0.989 341882 20.05 3.193E-04 0.990 345388 20.03 3.131E-04 0.990 348929 20.02 3.224E-04 0.990 352506 20.00 3.124E-04 0.991 356121 19.98 2.984E-04 0.991 359772 19.97 2.952E-04 0.991 363460 19.95 2.955E-04 0.992 367187 19.94 3.024E-04 0.992 370952 19.92 3.052E-04 0.992 374755 19.90 2.879E-04 0.993 378597 19.89 2.873E-04 0.993 382479 19.87 2.882E-04 0.993 386400 19.86 2.868E-04 0.993 390362 19.84 2.672E-04 0.994 394364 19.83 2.258E-04 0.994 398408 19.81 2.499E-04 0.994 402493 19.79 2.402E-04 0.994 406619 19.78 2.351E-04 0.995 410788 19.76 2.310E-04 0.995 415000 19.75 2.174E-04 0.995

### 20 459567 19.59 1.642E-04 0.997 464279 19.58 1.699E-04 0.997 469039 19.56 1.613E-04 0.997 473848 19.55 1.389E-04 0.997 478707 19.53 1.259E-04 0.998 483615 19.52 1.233E-04 0.998 488573 19.50 1.202E-04 0.998 493582 19.49 1.138E-04 0.998 498643 19.47 1.128E-04 0.998 503755 19.46 1.169E-04 0.998 508920 19.44 1.120E-04 0.998 514138 19.42 1.088E-04 0.998 519410 19.41 1.138E-04 0.998 524735 19.39 1.106E-04 0.999 530115 19.38 9.821E-05 0.999 535550 19.36 8.435E-05 0.999 541041 19.35 8.335E-05 0.999 546588 19.33 8.083E-05 0.999 552192 19.32 7.101E-05 0.999 557854 19.30 6.868E-05 0.999 563574 19.29 7.217E-05 0.999 569352 19.27 6.255E-05 0.999 575189 19.26 6.832E-05 0.999 581087 19.24 3.569E-05 0.999 587044 19.23 1.403E-05 0.999 593063 19.21 2.676E-05 0.999 599144 19.20 4.166E-05 0.999 605287 19.18 3.289E-05 0.999 611493 19.17 1.019E-05 0.999 617762 19.15 6.356E-06 0.999 624096 19.14 8.606E-06 0.999 630495 19.12 1.890E-05 0.999 636959 19.11 2.851E-05 1.000 643490 19.10 3.058E-05 1.000 650087 19.08 1.692E-05 1.000 656753 19.07 1.407E-05 1.000 663486 19.05 1.288E-05 1.000 670289 19.04 5.690E-06 1.000 677161 19.02 1.664E-06 1.000 684104 19.01 9.913E-07 1.000 691118 18.99 2.621E-07 1.000 698204 18.98 1.538E-05 1.000 705363 18.96 9.342E-06 1.000

### 21 781112 18.82 5.908E-06 1.000 789120 18.80 8.830E-06 1.000 797211 18.79 1.254E-05 1.000 805385 18.77 1.393E-05 1.000 813642 18.76 8.194E-06 1.000 821984 18.75 4.543E-06 1.000 830412 18.73 3.554E-06 1.000 838926 18.72 2.158E-06 1.000 847528 18.70 5.204E-07 1.000 856217 18.690.000E+00 1.000 864996 18.670.000E+00 1.000 873864 18.660.000E+00 1.000 882824 18.650.000E+00 1.000 891876 18.630.000E+00 1.000 901020 18.620.000E+00 1.000 910258 18.600.000E+00 1.000 919590 18.590.000E+00 1.000 929019 18.580.000E+00 1.000 938544 18.560.000E+00 1.000 948167 18.55 9.640E-07 1.000 957888 18.53 1.360E-06 1.000 967709 18.52 1.136E-06 1.000 977631 18.50 4.032E-07 1.000 987654 18.49 1.854E-07 1.000 997781 18.48 3.670E-06 1.000 1008011 18.46 1.009E-05 1.000 1018346 18.45 8.656E-06 1.000 1028787 18.43 8.355E-06 1.000 1039335 18.42 8.534E-06 1.000 1049991 18.41 5.602E-06 1.000 1060756 18.39 2.380E-06 1.000 1071632 18.38 6.137E-06 1.000 1082619 18.37 4.787E-06 1.000 1093719 18.35 1.393E-06 1.000 1104933 18.340.000E+00 1.000 1116262 18.320.000E+00 1.000 1127706 18.310.000E+00 1.000 1139269 18.30 2.831E-06 1.000 1150949 18.28 2.536E-06 1.000 1162750 18.27 9.028E-07 1.000 1174671 18.260.000E+00 1.000 1186715 18.240.000E+00 1.000 1198882 18.230.000E+00 1.000

### 22 1327631 18.090.000E+00 1.000 1341243 18.080.000E+00 1.000 1354994 18.060.000E+00 1.000 1368887 18.050.000E+00 1.000 1382922 18.040.000E+00 1.000 1397101 18.020.000E+00 1.000 1411425 18.010.000E+00 1.000 1425896 18.000.000E+00 1.000 1440516 17.980.000E+00 1.000 1455285 17.97 2.478E-06 1.000 1470206 17.96 7.230E-06 1.000 1485280 17.94 7.390E-06 1.000 1500508 17.93 2.487E-06 1.000 1515893 17.92 3.113E-07 1.000 1531435 17.900.000E+00 1.000 1547136 17.890.000E+00 1.000 1562999 17.880.000E+00 1.000 1579024 17.860.000E+00 1.000 1595213 17.850.000E+00 1.000 1611569 17.840.000E+00 1.000 1628092 17.820.000E+00 1.000 1644785 17.810.000E+00 1.000 1661648 17.800.000E+00 1.000 1678685 17.780.000E+00 1.000 1695896 17.770.000E+00 1.000 1713284 17.760.000E+00 1.000 1730850 17.740.000E+00 1.000 1748596 17.730.000E+00 1.000 1766524 17.720.000E+00 1.000 1784636 17.700.000E+00 1.000 1802934 17.690.000E+00 1.000 1821419 17.68 2.098E-08 1.000 1840094 17.66 6.687E-06 1.000 1858960 17.65 6.586E-06 1.000 1878020 17.64 3.167E-06 1.000 1897275 17.620.000E+00 1.000 1916727 17.610.000E+00 1.000 1936379 17.600.000E+00 1.000 1956232 17.580.000E+00 1.000 1976289 17.570.000E+00 1.000 1996552 17.560.000E+00 1.000 2017022 17.540.000E+00 1.000 2037702 17.530.000E+00 1.000

### 23 2256532 17.400.000E+00 1.000 2279668 17.380.000E+00 1.000 2303041 17.370.000E+00 1.000 2326654 17.360.000E+00 1.000 2350509 17.340.000E+00 1.000 2374608 17.330.000E+00 1.000 2398955 17.320.000E+00 1.000 2423551 17.300.000E+00 1.000 2448399 17.290.000E+00 1.000 2473502 17.280.000E+00 1.000 2498862 17.260.000E+00 1.000 2524483 17.250.000E+00 1.000 2550366 17.240.000E+00 1.000 2576514 17.220.000E+00 1.000 2602931 17.210.000E+00 1.000 2629619 17.200.000E+00 1.000 2656580 17.180.000E+00 1.000 2683817 17.170.000E+00 1.000 2711334 17.160.000E+00 1.000 2739133 17.140.000E+00 1.000 2767217 17.130.000E+00 1.000 2795588 17.120.000E+00 1.000 2824251 17.100.000E+00 1.000 2853208 17.090.000E+00 1.000 2882461 17.080.000E+00 1.000 2912015 17.060.000E+00 1.000 2941871 17.050.000E+00 1.000 2972034 17.040.000E+00 1.000 3002505 17.020.000E+00 1.000 3033290 17.010.000E+00 1.000 3064389 17.000.000E+00 1.000 3095808 16.980.000E+00 1.000 3127549 16.970.000E+00 1.000 3159615 16.960.000E+00 1.000 3192010 16.940.000E+00 1.000 3224737 16.930.000E+00 1.000 3257800 16.920.000E+00 1.000 3291202 16.900.000E+00 1.000 3324946 16.890.000E+00 1.000 3359036 16.880.000E+00 1.000 3393476 16.860.000E+00 1.000 3428269 16.850.000E+00 1.000 3463418 16.840.000E+00 1.000

### 24 3835356 16.700.000E+00 1.000 3874680 16.690.000E+00 1.000 3914406 16.680.000E+00 1.000 3954540 16.660.000E+00 1.000 3995085 16.650.000E+00 1.000 4036046 16.640.000E+00 1.000 4077427 16.620.000E+00 1.000 4119232 16.610.000E+00 1.000 4161466 16.600.000E+00 1.000 4204133 16.580.000E+00 1.000 4247237 16.570.000E+00 1.000 4290784 16.560.000E+00 1.000 4334776 16.540.000E+00 1.000 4379220 16.530.000E+00 1.000 4424119 16.520.000E+00 1.000 4469479 16.500.000E+00 1.000 4515304 16.490.000E+00 1.000 4561599 16.480.000E+00 1.000 4608368 16.460.000E+00 1.000 4655617 16.450.000E+00 1.000 4703350 16.440.000E+00 1.000 4751573 16.420.000E+00 1.000 4800290 16.410.000E+00 1.000 4849507 16.400.000E+00 1.000 4899228 16.380.000E+00 1.000 4949459 16.370.000E+00 1.000 5000205 16.360.000E+00 1.000 5051471 16.340.000E+00 1.000 5103263 16.330.000E+00 1.000 5155586 16.320.000E+00 1.000 5208446 16.300.000E+00 1.000 5261847 16.290.000E+00 1.000 5315796 16.280.000E+00 1.000 5370298 16.260.000E+00 1.000 5425359 16.250.000E+00 1.000 5480984 16.240.000E+00 1.000 5537180 16.220.000E+00 1.000 5593951 16.210.000E+00 1.000 5651305 16.200.000E+00 1.000 5709247 16.180.000E+00 1.000 5767783 16.170.000E+00 1.000 5826919 16.160.000E+00 1.000 5886662 16.140.000E+00 1.000

### 25 6518834 16.010.000E+00 1.000 6585670 16.000.000E+00 1.000 6653192 15.980.000E+00 1.000 6721406 15.970.000E+00 1.000 6790320 15.960.000E+00 1.000 6859940 15.940.000E+00 1.000 6930274 15.930.000E+00 1.000 7001329 15.920.000E+00 1.000 7073112 15.900.000E+00 1.000 7145632 15.890.000E+00 1.000 7218895 15.880.000E+00 1.000 7292909 15.860.000E+00 1.000 7367682 15.850.000E+00 1.000 7443222 15.840.000E+00 1.000 7519536 15.820.000E+00 1.000 7596632 15.810.000E+00 1.000 7674519 15.800.000E+00 1.000 7753205 15.780.000E+00 1.000 7832697 15.770.000E+00 1.000 7913005 15.760.000E+00 1.000 7994136 15.740.000E+00 1.000 8076098 15.730.000E+00 1.000 8158901 15.720.000E+00 1.000 8242553 15.70 2.167E-06 1.000 8327063 15.69 5.880E-06 1.000 8412439 15.68 8.994E-06 1.000 8498690 15.66 1.214E-05 1.000

### 29

### 26