P. I


# OAR Box 1490 Prepped by Charmelle Mathews



### Document

Number: 

# 18 ) IV-B-1 8 Docket Number: 

# A-94-5 2

Printed 8/4/200811:51:46

AM Sheet 18of 273P. 2 

# PE S
A MACTEC

COMPANY 

### TaEKTORSOTJOK T 

## A-^52 . Pacifi c Environmenta l Serv i 5001 Sout h Miam i Boulevard , Suit e 30 0 P.O

. BO X 1207 7 Researc h Triangl e Park , N C 2770 9 Office : 919/941-033 3 Fax : 919/941-023 4 Hom e Page : www.mactec.co m
TO : Docke t

A-94-5 2 FROM : Kenneth R
. Meardo n

Pacifi c Environmenta l Services , Inc
. DATE : Octobe r

31,200 2 SUBJECT : NonCorrosio n Resistan t Centrifugal Castin g Emissio n Factor s an d Operatio n Characteristic s Th e purpos e ofthi s mem o i s t o summariz e informatio n o n (1 ) th e emissio n factor s availabl e fo r

noncorrosio n resistan t

centrifugal castin g operation s an d (2 ) th e characteristic s o f

thes e operation s at

eac h ofth e si x know n facilities
. Tabl e 1 present s th e HA P content , emissio n factors , an demissio n rat e fo r th e si x know n facilities
. Tabl e 2 present s informatio n o n ai r movemen t

an d temperatur e associate d wit h th e centrifuga l castin g machine s an dcuring
. Followin g thes e table s ar e telephon e conversatio n report s (Attachmen t

1 ) fo r thes e si x facilitie s an d tes t report s (Attachment s 2 an d 3 ) fo r tw o facilities
. Emissio n Factor s Thre e ofth e si x facilitie s reporte d emissio n factor s for thei r centrifuga l castin g operations
. Thes e facilitie s an dthei r emissio n factor s ar e presente d below
. Th e actua l emissio n facto r

reporte db y Alte c i s considere d b y the mt o b e confidential
. Henderson , Black , an dGreen : 0.3 % o f availabl e HA P Newmar k

(formerl y Sherman Poles) : 2.6 % o f availabl e HA P Altec : >2.6 % o f availabl e HA P Th e HB& G emissio n facto r i s base d o n ates t

at th e facility
. Th e Newmar k emissio n facto r

i s base do n asimilar

facility tha t

wa s teste d i n Germany
. Thi s tes t i s attached
. Th e emissio n facto r reporte d b y Alte c i s based o n numerou s materia l balance s conducte da t

th e facility
. Henderson
. Black , an dGree n Th e HB& G emissio n factor s wa s calculate d a s follow s (page s refe r t o repor t foun di n Attachmen t

2) : Emissions : 0.57 6 lbs/hrP. 3

NonCorrosio n Resistan t

Centrifugal Castin g Octobe r 31 , 200 2 page 2 Fro mAppendi x C , page s C- 3 an d C- 4

Ru n 1 : (20 8 scf

mx 104 M W x 6 0 min/h r x 191. 9 ppmw ) / 385.3E0 6

E0 6 0.64 6 lbs/h r

Ru n 2 : (20 2 scf

mx 104 M W x 6 0 min/h r x 154. 7 ppmw ) /

385. 3 0.50 6 lbs/h r Averag e = 0.57 6 lbs/h r Availabl e styren e (pag e 2-3) : 20 6 lbs/h r Emissio n factor : 0.28 % ( = 0.576/206 ) Newmar k Th e Newmar k

emissio n facto r

was calculate d a s follow s (page s refe r t o repor t foun d i n Attachmen t

3) : Emission s (pag e 10) : 77 0 gram s pe r hou r (average ) 1,21 0 gram s pe r

hou r (worst-case ) Resi n Usag e (pag e 8) : 23 5 k g ove r 2.7 5 hour s = 85.4 5 kg/h r = 85,45 5 grams/h r Styren e conten t

(pag e 9) : 35 % Availabl e styrene : 29,90 9 grams/h r ( = 85,45 5 x 0.35 ) Emissio n factors : 2.57 % ( = 770/29,909 ) averag e

4.05 % ( = 1,210/29,909 ) worst-cas e
Base do n th e mos t

frequen t se t o f operatin g characteristic s (i.e. , passiv e ventin g a t ambien t temperature ) ofth e know n facilities , a s show n i n Tabl e 1 , a2.6 % emissio n facto r i s judge dt o b e areasonabl e estimat e o f emission s fro mothe r

non-corrosio n resistan t centrifugal castin g facilities
.NonCorrosio n Resistan t Centrifugal Castin g Octobe r 31 , 200 2 page 3 TABL E 1 . NONCORROSIO N RESISTAN T CENTRIFUGA L CASTIN G HA P CONTENT , EMISSIO N FACTORS , AN D EMISSIO N RATE S

FACILIT Y
Alte c Desig n Tank s (formerl y Raven ) Dixie-Pacifi c Henderson , Black , and Gree n Newmar k (formerl y Sherma n Poles ) Pentai r Water Treatmen t (formerl y Structural NA ) HA P

CONTEN T 44. 5
4 9
<3 5
<4 5
37. 5
4 3 EMISSIO N

FACTO R >2.6 %
2.6 %
2.6 %
0.3 %
2.6 %
>2.6 % EMISSIO N

RAT E (lbs/ton ) >25. 5
25. 5
<1 8
<2. 7
19. 5
>25. 5 COMMENT S

Activ e venting , ambien t

temperature . Emissio n facto r i s base do n numerou s materia l balances
. Passiv e venting , ambien t

temperature . Emissio n facto r assume d sam e a s Newmark
. Passiv e venting , ambien t

temperature . Emissio n facto r assume d sam e a s Newmark. Activ e venting
. Emissio n facto r base do n 199 7 emissio n tes t at facility
. Passiv e venting , ambien t

temperature . Emissio n facto r base do n emissio n tes t

a t similar facilit y in Germany
. Activ e venting , elevate d temperature . Emissio n facto r assume d sam e a s Altec
.NonCorrosio n Resistan t Centrifuga l Castin g Octobe r 31 , 200 2 page 4
TABL E 2 . NONCORROSIO N RESISTAN T CENTRIFUGA L CASTIN G OPERATION S Facilit y Alte c

Desig n Tank s (formerl y Raven )

Dixie-Pacifi c Henderson , Black , and Gree n

Newmar k (formerl y Sherman Poles )
Pentai r Wate r Treatmen t (formerl y Structural NA ) Produc t

boom s

smal l diamete r tank s architectura l column s architectura l column s
pole s

base s fo r wate r softenin g tank s Ai r Movemen tan d Temperatur e

Ai r move d throug h molds
. Centrifugal castin g machine s hav e en dcap s wit h hole s tha t provid e a

n openin g fo

r ai r t o b e move d throug h th e spinnin g mol ddurin g curing
. Fans/ai r flow use dfor

cooling , no t

curing
. The y hav e hood s an d ductwor k at th e ope n en dofth e mold s tha t

pul l ai r downward
. Ai r i s "drawn " fromope n end o f mold s usin g afa n locate di n th e outsid e wall
. N o heatin g o f air
. Passiv e ventin g at

ambien t conditions
. Ai r frommold s i s vente d throug h suctio n line s (n o blowers ) and , alon g wit h ai r in th e roo min whic h the y ar e located , vente d throug h aroo f

stack
. Ai r i s no t blow n throug h molds
.

Machin e i s close d a

t on e en d an dope n at

th e other
. Heate dai r

i s blow n throug h th e machin e t o remov e heat

an di s the n vente dt o th e atmosphere
. Curin g Produc t i s remove d after th e ge l stage , whil e stil l a semi-soli d an d cur e i t

in ambien t air
.

Mos t part s ar e fully cure d i n th e mold
. T o mee t

FD A requirements , som e ar e steam-cure dafte

r removal
.

Produc t i s move d t o separat e roo mt o complet e curing
. Produc t i s cure d completel y in th e mold , allowe d t o cool , an d the n removed
. Appear s tha t

part i s cure d in th e mold
. Comment s Resi n i s no t

heated
. The y hav e no t change d thei r

resin s sinc e submitta l ofth e origina l information
.

Mol d i s no t

heated
. Resi n i s heate d t o 9 0 t o 10 0 de g F
.

N o heatin g ofresin , mold , o r air
.

Mold s ar e heate d durin g winte r months ; targe t

tem p for reactio n i s 15 0 de g F
. Mol d heate d t o 280 de g F
. Currently , onl y operatin g on e machine , whic h i s operate d sporadically
.

•* • O lP. 6



### ATTACHMEN

T 1 Telephon e Conversation Report s



# SP. 7

MAK~//"3 0 TR I t-U O HY i riEL U OEAUU C 03/2T/8 S 10:1 1 ©1918641023 4 PE S RI P N C y002/00 2 

## A 

## UJ?
ContactRepor

t

' V Melanie Proctor

, Pacific Environmenta

l Services , Inc . (PES ) Date : Marc h 26,199 8 Mr . Colb y Edward s Company : Alte c Industries , Inc . Telephon e Number : (816)364-224 4 Fa x Numbe n (816 ) 236-135 2 

# ?H



# <\\<\ W 

# oz^

Contac tSummary : MS . Proctor explaine

d tha i PE S i s workin

g wit h th e U.S . EP A o n th e developmen tof a nationa l emissio n standar

d fo r th e reinforce

d plastic composites industiy . Ms . Procto r adde d tha t Alte c Industries , Inc . wa s contacte d to verif y infonnatio

n provide d i n the 199 3 EP

A screenin g surve y submitted for thei

r facility . ^ ^ Ms . Proctor aske

d Mr . Edward s i f Alte c Industri e Inc . i s using an y pollutio n preventio n measures fo r thei r ccntrifiiga l casting process . Ms . Procto r furthe r explained tha

tsuc h pollutio n preventio n measures ma

y include managemen

toreliminatio

n o f air flo w throug

h th e centrifuga

l castin g machines , no theatin g th e ai ran d th c r«i n <farir

^ applicatio

n an d curing , orth e redustkm i f hazardou s ai r pollutant s (HAP ) i n th e resi a $dfr

. Edward s indicate d tha tAlte c Industries , Inc . i s ^ 'no tusin g any specia

l pollution preventio

n measmg^for.thfl

tprocess . H e explaine d thatth e EntnZuga l actin g machines have en d cap s whic

h haveJOMnn the

m tha tprovid e a

n openin g fo r air t o b e move d throug

h th e spinnin g mol d durin

g curing. Mr

. Edward s indicated tha

th e di d no t kno w ih e exac tai

r flow rat e throug h th e mol d a tth e tim e (Coul d yo u pleas e find ou twha tth e ai r flow rat e throug h th e mold I s an d Ifth e resi n o r tb e ai r i s heate d i a th e process ? Ifth e ai r o r tiie resi n i s heated , eoul d yo u provid e th e temperature?) . Accordm g t o Mr. Edward

s th e facility sti U use s th e sam e resins tha twer e repotte d i n the 199

3 screenin g surve y whic h ar

e polyeste r fle x resi n a ta HA P conten

to f 3 0 percen tan d unsaturate

d polyeste r resi n ata HAP contento f

4 5 percent .

INFORMATION I S ACCURAT E 

# H &st* ts //*rkt*leJ

/ A 4t*. pmc*s

^Kr/A j . /-klpS tool /A0l#£

CLffer^fO'tf&'M'*—P. 8



### From : Date : Contact : Contac tRepor t Kennet h R
. Meardon , Pacific Environmenta l Services , Inc
. (PES ) Jun e 2 8 an dJul y 9,200 2 Mr
. Colb y Edward s Company : Alte c Industries ) Telephone Number : (816 ) 364-224 4 Fa x Number : Contac tSummary : Dr
. Meardon contactedMr
. Edward s t o confir mcertain aspect s of

centrifuga l castin g conducteda

t their facility
. Mr
. Edward s indicatedtha t the y remov e their

produc t afte r th e gel stage , whil e stil l asemi-soli dan dcur e i t i n ambien t air
. The y hav e hood s an

dductwor k a t th e ope n en dofth e mold s tha

t pull ai r downward
. The y hav e developeda

n emission facto

r fo r their centrifuga l castin g proces s base don numerou s materia

l balances
. H

e notedtha t the y hav e not changedtheir

resi n sinc e submitta

l of the origina l information
. Mr
. Edward s indicate dtha

t 200 0 hour s pe

r yea r o f operatio n i s typical
.



# 7Contac tRepor t From : Kennet h R
. Meardon , Pacifi c Environmenta l Services , Inc
. (PES ) Date : June 25 , 2002 Contact : Mr
. Marcu s Weeldrye r Company : Desig n Tanks (formerl y Rave n Industries ) Telephon e Number : (605)965-160 0 Fa x Number : (605 ) 965-163 0
Contac tSummary : P. 9

Dr
. Meardo n contacte dMr
. Weeldrye r t o confirmcertai n aspect s o f centrifuga l castin g conducte dat

th e Siou x Falls , SD , facility
. Dr
. Meardo n rea d aportio n ofth e Apri l 8,1998 , teleco n betwee n Melani e Proctor , PES , an d Mr
. Kurt Doeden , Rave n Industries , describin g th e operatio n ofth e centrifugal castin g operation s a t th e Siou x Falls , SD , facility
. Mr
. Weeldrye r indicate dtha t

th e descriptio n was accurat e wit h th e exceptio n tha t the y hea t thei r resi n t o betwee n 9 0 an d 10 0 de g F withi n a n in-lin e heate r

fo r applicatio n i n th e molds
. Mr
. Weeldrye r confirme dtha t

the y d o no t

blo w ai r throug h th e molds , bu t

b y usin g afan locate d i n th e outsid e wal l ai r fro mth e ope n en dofth e mold s i s draw n downwar d throug h grate s i n th e floor , travel s throug h trenches , an d i s emitte dt o th e outside air
. Th e part s ar e full y cure d i n th e molds , althoug h o n occasio n t o mee t FD A requirement s th e part s ar e steam-cure d after remova l fro mth e mold
. Th e facilit

y i s stil l makin g smal l diamete r tanks , thoug h th e uppe r

rang e i s no w 14-fee t interna l diameter
. Dr
. Meardo n aske di f

the y ha d don e an y testin g o f emissions
. Mr
. Weeldrye r state d tha t the y wer e i n th e proces s o f settin g u p t o conduc t

ful l da y testin g tomorrow , Jun e 26
. Dr
. Meardo n aske di f

an y ofth e informatio n the y discusse d wa s considere d b y Desig n Tank s t o b e confidentia l busines s information
. Mr
. Weeldrye r state d tha t

non e ofth e informatio n discusse di s confidential
.P.1 0

'a^7o»>»«*** w ioVos f

**~Tari»"iJ»V4i.o"asa

V ""re s *r r n w ifljoojc/oo a vi/ w a r

w

Contac tRepor t From ; Melani e Proctor , Pacifi c Enviromnenta l Services , Inc . (PES) Date : Apri l 8,199 8 Contact : Mr . Kur tDoede n Company : Rave n Industries , Inc . Telephon e Number : (60S ) 336-275 0 Fa x Number : (605)335-026 8
Contac tSummary : Ms . Procto r explaine d tha tPE S i s workin g with th e U.S . EP A o n th e developmen tof a national emissio n standar d fo r th e reinforce d plasti c composite s industry . Sh e adde d thatRave n Industries wa s contacted t o verif y information provided i n the 199 3 EP A screenin g surve y fo r thei r centrifuga

l castin g process . Ms . Procto r pointe d outtha tth e EP A i a i n th e proces s o f

establishin g emissio n standards fo r al l majo r source s o f

hazardous air pollutant

s (HAP ) tha

treflec tmaximum achievabl e contro l technolog y (MACT) . Sh e explaine d tha tth e EP A i s currentl y reviewin g an y pollutio n preventio n o r reduction measure s tha tar e bein g use d i n centrifuga l castin g operations , i n orde r t o determin e th e MAC T floo r fo r thi s process . Ms . Procto r aske d Mr . Doede n i f Rave n Industries i s usin g any pollutio n preventio n measure s fo r thei r centrifuga l castin g process . Sh e explaine d tha tsuc h pollutio n preventio n measure s ma y includ e managemento r eliminatio n o f air flo w throug

h th e centrifuga

l castin g machines , no theatin g th c air , the resin , o r th e mol d durin g application an

d £unn&)an

d th e reductio n o f HA P i n th e resin . Se t*Jo|e
_ Mr . Doede n indicate d tiiatRave n Industries doe s no theatth e air , th e resin , o r th e mol d i n thei r centrifuga l castin g operation . H e als o pointe d ou ttha ton e en d o f

eac h o f th e 1 2 molds i s close d with a

n en d cap . Mr

. Doede n explaine d tha

tai r i s draw n fro m th e ope n en d o f

th e 1 2 molds . Mr . Doede n wa s no tsur

e abou tth e exac tai

r flo w draw

n fro m each ofth e mold s buth e indicate d tha t onl y on e fa n wa s use d t o dra w air from th e 1 2 mold s an d tha tthi s fa n ha s a desig n air flo w rat e o f 12,00 0 cubi c fee tpe r minut e (cfm) . H e adde

d tha tth e air flo w from eac h mol d woul d likel y no t excee d 1,00 0 cf

m and coul d possibl y b e lower . (Contactrepor

tcontinue d o n secon d page ) INFORMATIO N I S ACCURAT E 

### 1
C**~cJi f o w\ee~[ " ^"IbA r a.ff-rev<K.\ .p.1 1

04/OV/M" ~ lV : 5 V ' "BiVlMVlOZ M " PE S RT P N C m «a/ooa

Coul d yo u pleas e verif

y tha tal l th e product s produce d b y you r facilit y usin g centrifuga l castin g ar e product s tha tar e use d fo r corrosion-resistan tapplications ? UgA00ff Mr . Procto r explaine d tha tth e average weighte d HAP conten to f Rave n Industries ' resin s wa s calculate d t o b e 4 9 percen tbase d o n information tha tMr. Doede n submitte d t o PE S i n Novembe r 1996 . Ms . Procto r added tha tthi s average weighte d HA P conten twa s calculate d base d o n th e entire resi n us e atth e plan tincludin g th e resi n us e for filamen twinding , cho p spra y lay-up , an d centrifuga l casting . Ms . Procto r asked i f distribution o f

resi n usag e i s simila r fo r al l o f thei r processe s o r i f

on e proces s use s highe r resi n HAP content s tiian others . Mr . Doede n replie d tiiatth e averag e weighte d resi n HA P conten to f 4 9 percen

twa s representative o f

al l thei r processes . INFORMATIO N I S ACCURAT E 

# tt ©

( 0P.1 2

07/30/» « u:

o o 

## A 

## 9 4 5 2 

# II- F m Contac tRepor t From : Melanie Procto r an d Shaw n McKee , Pacific Environmenta l Service * Inc . (PES ) Date ; Jul y 29,199 8 Contact : Mr. Stephe n Scharfenber

g Company : Dude-Pacific Manufacturin g Conpany , Inc . Telephon e Number : (226)442-451 3 Fa x Nunber : (256)442*479 4
Contac tSummary : Ms . Procto r state d tha

tDixie-Pacifi c Manufacturing Company , Inc . wa s contacte d t o giv e infonnatio n abou tth e cost s tha tthei r facilit

y ma y hav e incurre

d du e t o changin g th e ream use d i n Ihei r manufacturin g proces s fro m a resi n wit h a hazardous ai r pollutan t(HAP ) conten to f 39.8 % t o 35% . Mr . Scharfenber g confirme d th e chang e i n resi n bein g use d b y Dixie-Pacifi c Manufacturin g Company , In c li e state d tiiatn o cost s wer e associate d wit h th e chang e mtr « typ e o f res m bdn g use d du e t o an y processin g problems , an d thatany increas e i n scrap o r reworkin g o f product s becaus e o f th e chang e wa s negligible . Dixie-Pacifi c Manulacturin g Company , Inc . di d no texperienc e an y difficultie s i n processin g o r pefermanc e problem s rcsulb^ i n a n ioal^t y to mai ^ products , an d thu s di d no texperienc e any los s i n busines s du e t o thes e factors . Mr . Scharfenber g state d tha tth e cos to f th e ne w resi n wa s comparabl e t o th c ol d resin . H e als o stated thstther e wa s n n increas e In th e cos to f training , an d n o produc tcertificatio n test s wer e necessai y du e t o tiie chang e m resins . Dixie-Pacifi c Manufacturing Company , Inc . di d incu r a cos tof a fe w hundre d dollar s becaus e o f performin g drop-testin g o n finished architectura l columns . Accordin g t o Mr . Scharfenberg , tins oos t include s th e labo r cos tt o mak e and tes ttiie samples . Accordin g t o Mr

. Scharfenberg , th e facility' s vendor , McWhorter Technologies , Inc. . wa s vei y belp M Inth e tnmsitionfo m th e highe r HA P i^ ^ McWhorte r Technologies , Inc . performe d th e testm g o f propertie s and an

y othe r necessary testin g fre e o f charge , wit h th e exceptio n o f

th e drop-testin g performed b y Dixie-Pacifi c Manufecturin g Company , Inc . Mr . Scharfenber g als o pointe d ou tthatMcWhorte r Technologies , Inc . conducte d test s t o ensur e tha ttile ne w formulatio n provide s th e sam e loa d bearin g productpropertie s a s th e ol d formulation . Mr . Scharfenber g state d thati twa s possibl e tha tcompetitio n betwee n supplier s adde d a n additiona l incentiv e fo r McWhorte r Technologies , Inc . x o ai d Dixie-Pacifi c Manufacturin g Company; , Inc . m th e transition .

INFORMATIO N I S ACCURAT E 

# A£A



# wP.1 3 JU L I G 200 2 10:52H M HB G 07/18/0 2 08:4 6 'B'1919941023 4 334807866 5 PE S RT P N C p . 2 ©002/00 2

From : Date : Contact : ContactRepor t Kennet h R
. Meardon , Pacifi c Environmenta l Services , Inc
. (PES ) Jun e 25 , 200 2 Mr
. Geof f McDuffie Company : Henderson , Black , an d Green Telephon e Number : (334 ) 566-5000 , ext . 651 4 Fax Number : (334 ) 807-866 5
Contac tSummary : Dr
. Meardo n contacte dMr
. McDuffie t o discus s certai n aspect s o f centrifuga

l castin g conducte datth e Troy , Alabama , facility
. Mr
. McDuffie indicate d tha t [infonnatio n claime d t

o b e confidential ha s bee

n deleted]
. Th e ai T fromth e mold s i s vente d throug h suctio n line s and , alon g with th e ai r in th e roo m L n whic h the y ar e localed , vente dthroug h aroo f stack
. Th e facilit

y als o vent s th c mixin g roo m throug h aseparat e roo f

stac k t o th e atmosphere
. Th e volum e of air fro mth e spinner s i s muc h lowe r than that fro mthe mixin g room , whil e th c styren e concentratio n in th e ai r fromth e spinner s i s muc h higher

tha n that fro mth e mixin g room . Base d on testin g i n 1997 , th e facilit y ha s calculate da

n emissio n factor

fo r thei r facility , whic h they ar e usin g fo r al l resins
. (Informatio n claime dto b e confidentia l ha s been deleted. ] Mr
. McDuffi e indicate dtha t the y ha d buil t anew plant

designe d specificall y t o b e "friendly " for

th e potentia

l installatio n o f

aiherma l oxidizer
. INFORMATIO N I S ACCURATEP. M

From : Date : Contact : Company : Contac tRepor t

Kenneth R
. Meardon , Pacifi c Environmenta l Services , Inc
. (PES ) Jun e 20,200 2 Mr
. Clarenc e Faire r Alabam aDepartmen t

o f Environmenta l Managemen t Telephon e Number : (334)271-789 2 Fa x Number :
Contac tSummary : Dr
. Meardo n contacte dMr
. Faire r t o discus s certai n aspect s o f centrifugal castin g conducte d at th e Henderson , Black , an dGree n facilit y locate d i n Troy , Alabama
. Accordin g t o Mr
. Fairer , th e facilit y doe s not

hea t th e resin , mold , o r

air
. Resi n i s poure d int o ope n molds , whic h ar e the n close d for abou t 1 5 t o 2 0 minutes
. The y mold s start gettin g war man d bega n offgasing
. Ther e ar e duct s at th e en dofth e mold s t o ge t

th e emission s away fromth e workers
. The y d o not us e blower s o n th e mold , althoug h the y ma y hav e fan s tha t "suck " th e ai r

out . Whil e the y ar e stil l curing , th e column s ar e remove dfromth e mold s an dar e cure d i n aseparat e room .



# \ 3P.1 5



### From : Date : Contact : Company : Contac tRepor t Kennet h R
. Meardon , Pacific Environmenta l Services , Inc
. (PES ) July 12,200 2 Mr
. Geof f McDuffi e Henderson , Black , an

dGree n Telephone Number : (334 ) 566-5000 , ext . 651 4 Fa x Number : (334)807-866 5
Contac tSummary : Mr
. McDuffi

e indicate dtha

t their facilit y i s currentl

y operatin g a

t approximately 10

0 hour s pe r week
.



# ( HP.1 6



### From : Date : Contact : Contac tRepor t Kennet h R
. Meardon , Pacific Environmenta l Services , Inc
. (PES ) Jul y 15,200 2 Mr
. Geof f McDuffi e Company : Henderson , Black , an dGree n Telephone Number : (334 ) 566-5000 , ext . 651 4 Fa x Number : (334 ) 807-866 5
Contac tSummary : In respons e t

o aJun e 25,2002 , fax , Mr
. McDuffi e indicate dtha

t (1 ) th e prope

r unit s fo r Tabl e 2- 3 shoul db e "lb s styrene pe r hour " no t "lb s styrene pe

r shift " an d(2 ) th e 1,60

9 wa s equa

l to lb s of slurry
.



## l bP.1 7

Contac tRepor t From : Kenneth R
. Meardon , Pacifi c Environmenta l Services , Inc
. (PES ) Date : Jun e 20,200 2 Contact : Mr
. Bil l Ros s Company : Newmark (formerl y Sherma n Poles ) Telephon e Number : (803)625-313 1 Fa x Number :
Contac tSummary : Dr
. Meardo n contacte dMr
. Ros s abou t certai n aspect s o f

thei r centrifuga l castin g operations
. Mr
. Ros s indicate dtha t the y hav e 7 centrifuga l castin g machines , 6 ofwhic h ar e use dan dth e 7 t

hi s currentl y use da s aspare . Reinforcemen t i s place d o n ainsertio n ro d whic h i s inserte dint o th e mold , wher e i t i s spu n s o tha t

th e reinforcemen t

i s o n th e insid e ofth e mold
. Th e insertio n ro di s removed
. Resi n wit h catalys t i s injecte d int o th e smalle r en d ofth e tapere d mol dvi aan automati c pump . The y d o no t blo w an y ai r

int o th e mold
. Th e produc t i s cure d completel y i n th e mold , allowe dt o cool , an d the n i s removed
. Durin g winte r months , fo r example , the y wil l us e infrare dheater s o n th e exterio r ofth e mold s t o war mthe m(pre-hea t th e mold ) unti l th e catalys t

"get s going. " The y hav e atarge t temperatur e o f

15 0 de g F fo r

th e reactio n t o tak e place
. Mr
. Ros s indicate dtha t

thei r paren t compan y ha s teste d thre e simila r machine s i n German y for

emissions
. H e i s forwardin g acop y ofth e tes t report t o PES
. H e note d tha t

i n German y the y collec t

th e emission s fromth e machine s an d ven t the mt o th e outsid e an d tha t the y wer e plannin g t o insta

U asimilar

emissio n collectio n syste ma t th e facility i n South Carolin ai n th e near future
. Lastly , Mr
. Ros s indicate dtha t an averag e HA P conten t

o f 37.5 % i s stil l accurat e fo r thei r facility
.



## I WP.1 8

07/08/0 2 15:5 3 -©1919941023 4 PE S RT P N C ®002/00 2



### Contac t Report From : Kennet h R
. Meardon , Pacific Environmenta l Services , Inc
. (PES ) Date : Jul

y 8. , 200 2 Contact : Mr
. Steve n Ose r Company : Pentai r Wate r Treatmen t (fonnerl y Structura

l Nort h America) Telephon e Number : (440 ) 821-414 6 Fa x Number : (440 ) 286-714 5
Contac t Summary : Dr
. Meardon contactedMr
. Ose r to discus s certain aspect s o f centrifuga l castin g conducteda

t th e Chardon , Ohio , facility
. Dr
. Meardon inquiredabou t th e movemen

t o f air throug h th e centrifuga

l castin g macliin

e an dwhethe r o r no t it wa s heated
. Mr
. Ose

r first describedth e macliine an

dthen it s operation
. He indicatedtha t th e machin e resemble s aclothe s dryer
. Fiberglas s mat s (abou t 4 ) ar e place dint

o th e machine , which the n spin s forcing th e mat s to th e inside par

t of th e walls
. Resin ( amixtur

e of viny l este r andpolyester

resin ) i s poure d int

o th e machine
. Th e mol

di s heate dandth e par

t i s cured
. Th

e machine i s close da

t one endand ope n a t tli e other
. Heate dair

i s blown through th e machin e t o remov e hea

t andi s the n vente d to the outside
. Mr
. Ose

r indicate dtha

t they hav e teste dthe ven

t fo r emission s andsuggeste d tha t I contac t Mr
. Ke n Ziemick

i fo r additiona l information o

n emissions , /J^ J ;k'.e.ivicJfc c cj>r**jubz&. M

e . KM*. &4 w»* t l*i*»»«

. c*-*W

^ •f-e.ct.-W s 

### Mr
. Ose r indicate dtha

t the y hav e greatl

y reducedth e us e of

thei r centrifuga l castin g <.,*•

» c*-*-,,;^ ^ machine s ove

r th e las t thre e year s b

y using adifferen

t proces s (injectio n molding ) t o produc e tM 

### ^ liU 

### , ' ) their bases
. They currently only hav e on e centrifuga l castin g machine , an di t

i s operate d " ^ / sporadically
. $° *-W-<*

- Dr
. Meardon askedi f

an y ofth e information the

y discusse dwa s considere dby Pentair Wate r Treatmen t t o b e confidentia

l busines s infonnation
. Mr
. Ose r state dtiiat

non e ofth e infonnatio n discusse di s confidential
. INFORMATIO

N I S ACCURAT

E



# 1 1
I ' d SPZ'OK J 9W 3 'H"k l "IHM n I T\_A I c ; I.UKCI- C 7nci*3'*Lj*3-in rP.1 9

- 0*jr-i,°i

—20:.5-^*-'J1915i^:y ^ H M PE

S RT P N C NU . r ^ r . • 4^2/00 3 

### A 945 7
Contac tRepor t From : Melani e Proctor, Pacifi c Environmenta l Services , Inc . (PES ) Date : Marc h 27,199 8 Contact : Mr . Kennet h Ziernick

i Company : Structura l Nort h America Telephon e Number : (440 ) 286-411 6 Fa x Number : (440 ) 286-650 4
Contac tSummary : Ma . Procto r explaine d tha tPE S i s workin g witi i th e U.S . EP A o n th e developmen to f a nationa l emissio n standar

d for th e reinforce

d plasti c composite s industry . Sh e adde d thatStructura

l Nort h Americ a wa s contacted t o verif y infonnatio n provided i n th e 199 3 EF A screenin g surve y fo r thei r centrifugal castin g process . Ms . Procto r pointe d ou ttha tth e EPA i s i n th e proces s o f establishin g emissio n standard s fo r al l majo

r source s o f

HAP tha trefiec tmaximu m achievabl e contro l technolog y (MACT) . Sh e explaine d tha tth e EP A i s currentl

y reviewin g an y pollutio n preventio n o r reductio n measure s tha tar e bein g use d i n centrifuga l castin g operations , i n order t o detennin e th e MAC T floo r fo r thi s process . Ms . Procto r aske d Mr. Ziernick i i f Structura

l Nort h Americ a i s usin g an y pollutio n preventio n measure s fo r thei r centrifuga l castm g process . Sh e explaine d thatsuc h pollutio n preventio n measure s ma y includ e managemen to r eliminatio n o f

ai r flo w tiirough th e centrifugal castin g machines , no theatin g tiie ai r an d th e resi n durin

g applicatio n an

d curing , an

d th e reductio n o f hazardou s ai r pollutants (HAP ) i n tiie resin . Mr . Ziernick i indicate d tha tStructura

l Nort h Americ a doe s no tmov e an y ai r through th e centrifuga l castin g machine s durin

g tiie entir e process . H e als o indicate d tha tth e centrifuga

l castin g machine s (drums ) ar

e electricall y heated t o 280 ° F t o hel p cur e th e par tMr. Ziernicki explaine d tha t th e centrifuga

l castin g machine s ar

c open^tboti i end^an d tha tth e opening s are 1 2 o r 1 6 inche s i n "diamete r dependin g o n th e par tThe part s produced ar

e base s fo r wate r softenin g tanks . Mr . Ziernicki indicate d tha

tthes e base s ar

e no tproduced fo r corrosion-resistan tapplications . (Contac trepor

tcontinue d o n secon d page ) INFORMATIO N I S ACCURAT E


# nOBP?.-. , 8.1998 0 :.?

- SlPl^isiSIRyCTURflL Nf l PE S RT p N c P.2 0 NO

. 72 3 P

. 2/3)3/00 3



### Coul d yo n pleas e verif

y thatyo u sti

U us e I S tons o f

polyeste r resi n pe r yea r i n centrifugal castin g operations wit h a HA P contento f

37. 5 percent ? I n addition , coul d yo u verif y tha tyo u stil l ad d I. S tons o f styren e monome r t o thatresin a tyou r facility ? Whe n Ms
. Procto r

aske di f Structura l Nort h America' s resi n mixin g vessel s ar e ope n o r covered , Mr
. Ziernick

i replie dtha

t mos t o f their mixing vessel s ar

e open during mixing
. Mr
. Ziemiek i adde dthat

acove r i s placedo

n th e mixing vessel s afte

r th e mixin g proces s i s completed
. 

# see get*"/ INFORMATIO N I S ACCURAT E 

# Vt/f0

3S r 

# ^^ s 

# e^sTyfc^

MCSJC^CZ:



# \°\P.2 1



### ATTACHMEN

T 2
No
. 4 Permacasting Lin

e Tota l Hydrocarbon an

d Stryren e Emissio n Tes t

Repor t
a t Henderson , Black , an

dGree n Troy , Alabam

a



# xoP.2 2 

# ADE M

JAME S W

. WAR R DIRECTO R 

### ALABAM A DEPARTMEN T O F ENVIRONMENTA L MANAGEMEN T s 

## %rj^' :
POS T OFFIC E Box 30146 3 • 175 1 CONG . W . L.DICKINSO N DRIV E 36109-260 8 MONTGOMERY , ALABAM A 36130-146 3 (334 ) 271-770 0 

### Ma y 29 , 199 8
Madelein e Stru

m USEP A MD-1 3 Researc h Triangl e Park , NC 2771 1 FO B JAMES , JR

. GOVERNO R Facsimiles : (334 ) Administration : 271-795 0

Air : 279-304 4 Land : 279-305 0 Wate r 279-305 1 Groundwate r 270-563 1 Fiel d Operation** : 272413 1 Laboratory : 277-671 8 Education/Outreach : 213-439 9


### Dea r Ms
. Strum : Enclosed , pleas e fin

d th e styren e emission s tes t repor t conducte d a

t Henderson , Blac k an d Greene i n Troy , Alabam ao n Februar y 4 , 1997
. If

yo u need additiona

l information , pleas e contac t m e a t (334 ) 271-786 1 i

n Montgomery
. Sincerely ,

este r Meredit h Engineerin g Service s Branch Ai r Divisio n

11 0 Vulca n Roa d Birmingham . Alabam a 35209-470 2 (205)942-616 8 (205 ) 941-160 3 [Fax ] 40 0 Wel l Street . N E . • P. O Bo x 95 3 Decatur . Alabam a 35602-095 3 (205)353-171 3 (205 ) 340-935 9 (Fax ) 220 4 Perimete r Roa d Mobile . Alabam a 36615-113 1 (334 ) 450-340 0 (334 ) 479-259 3 (Fax ] Printe d o n Recycle d Pape r -JC / 

# x\P.2 3



# Henderson, Black, and

Greene, Inc. Troy, Alabama 36081



# No
. 4 Permacastin g Lin e Tota l Hydrocarbo n an d Styren e Emissio n Tes t

Repor t

February 1997

Work OrderNo. 11665-002-001

Prepare d by : Roy F . Weston , Inc . 163 5 Pumphre y Avenu e Auburn , Alabam a 3683 0 

# r^P.2 4



## Wor k Orde r No . 11665-002-00 1

No . 4 Permacastin g Lin e Total Hydrocarbo n an d Styren e Enlissio n Tes tRepor t Henderson , Black , an d Greene , Inc. Februar y 199 7

Prepare dFo r 

## HENDERSON , BLACK , AN D GREENE , INC . 101 5 Brundidg e Blvd
. Troy , Alabam a3608 1

Prepare d B y 

## RO Y F.WESTON

, INC . 163 5 Pumphre y Ave
. Auburn , Alabam a36832-430 3

7 Marc h 199 7

K M 1665\aH\00l\REPORT.DO C 7 Marc h 199 7 8:0 0 A

M Versio n 

## i- >P.2 5



## TABL E O F CONTENT S

SECTIO N 1 INTRODUCTIO N . 1- 1 SECTIO N 2 RESULT S AN D DISCUSSIO N 2- 1 SECTIO N 3 SOURC E TESTIN G METHODOLOG Y 3- 1
APPEND KA SAMPL E CALCULATION S APPENDT

X B TES T METHODOLOG Y APPENDI

X C FTEL

D DAT A - SPINNIN G MACHINES , COMBINED COOLIN G VEN T APPENDI

X D FTEL

D DATA-MIXIN G ROO M VEN T APPENDI

X E LABORATOR

Y DAT A APPENDT

X F QUALITY CONTRO L DAT A APPENDI

X G PROCES S DAT

A
LIS T O F TABLE S Tabl e 2- 1 Summar

y o f Emissio n Tes t

Result s 2- 1 Tabl e 2- 2 Emissio n Dat a- Spinnin g Machines , Combine dCoolin g Vent 2- 3 Tabl e 2- 3 Emissio n Dat a- Mixin g Roo mVen t 2- 4 Tabl e 2- 4 Analytica

l Data- Aromati c Hydrocarbon s 2- 5 Tabl e 3- 1 Sourc e Testin g Methodolog y 3- 1

K:\ l 1665\002\001\REPORT.DO C 7 Marc h 199 7 8:0 0 A M Versio n ^P.2 6



## SECTIO N 1 INTRODUCTIO N

Ro y F
. Weston , Inc
. (WESTON®) wa s retained b y Henderson , Black , an dGreene , Inc
. (HBG) to conduc t tota l hydrocarbo n (THC ) andstyren e emissio n testin g on th e Spinnin g Machines , Combined Coolin g Ven t

an dMixin g Roo mVent

a t th e facilit

y i n Troy , Alabama
. Testin g was conducte dt

o quantif y total styren e emission s ffo mth e No
. 4 Permacastin g Line
. WESTO N performe dth e emissio n testin g o n 4 Februar y 1997 wit

h aprojec t

tea mcomprise dof

the followin g individuals
. Nam e

Davi d Ela m Gre g Sim s Gar y Lloy d Bil l Groebe

r | Wayn e Robert s Jo n Howar

d Sherri e Walker Projec tRol e Projec t Directo r Projec t Manage r Technica l Directo r Proces s Enginee

r Tes t Tea mLeader Tes t Tea mMember Dat aReductio n andReportin g Mr
. Geof f McDuffie of

HB G coordinate dth e testin g wit h mill operation s an dserve da s WESTON' s technica l contac t throughou t

th e effort
. Mr
. Lester Meredit h o f Alabam aDepartment

o f Environmenta

l Management

(ADEM ) wa s present

durin g aportio n ofth e testing
. Thi s repor t i s organize dint o thre e section s andsupportin g appendices
. Sectio n 2 summarize s th e tes t progra mresults
. Sectio n 3 reference s th e samplin g an danalytica

l procedure s use dt o perfor m the tes t program . Supportin g dat aar e provide din th e appendices
.

K:\ ) 1665\002\001\REPORT.DO C 7 Marc h 199 7 8:0 0 A M Versio n 1- 1 

# 1 5P.2 7



## SECTIO N 2 RESULT S AN

D DISCUSSIO N

Tabl e 2- 1 summarize s th e results of th e emissio n testing
. Table s 2- 2 and2- 3 present th e detaile d tes t result s fo r eac h ofth e selecte demissio n points
. Some difference s betwee n th e calculate d results show n i n th e appendice s an dth e reporte dresult s i n th e summar y table s are du e to roundin g th e result s fo r presentation
. TABL E 2- 1

SUMMAR Y O F EMISSIO N TES T RESULT S 

### Spinnin g Machines , Combined Coolin g Ven t Tota l Hydrocarbons , a s Styrene Concentration , pp m Emissio n Rate , lb/h

r 3 1 0.1 0 Mixin g Room Ven t Total Hydrocarbons , a s Styrene Concentration , pp m Emissio n Rate , lb/h

r 3 1 7. 6 Total Styren e Emissio n Rate , lb/h r 7. 7 

### Emissio n Factors l b Styrene/lb Prepare dPolyme r Input l b Styrene/l

b Styren e Input 0.00 5 0.03 7 I n additio n to testin g th e selecte demissio n point s fo r TH C emissions , tw o sample s wer e collecte d fro meac h source , withi n th e tim e fram e o f th e TH C testing , an

danalyze dfo

r selecte d aromati c hydrocarbons
. Th e aromati c hydrocarbo n analysi s indicate dtha t styren e comprise dan averag e concentratio n equivalent

to 9 6 percen

t o f th e tota l aromati c hydrocarbon s present i n th e sourc e ga s streams . Th e result s ofth e aromati c hydrocarbon s testin g ar e presente di

n Tabl e 2-4
. A revie w o f

th e proces s operatin g dat aindicate s that durin g th e testing , asolvent (containin g primarily toluen e andxylenes ) wa s use dt o clean equipment
. A revie w o f th e dat apresente di n Tabl e 2- 4 show s thes e compound s compris e th e majorit y ofth e non-styren e aromati c hydrocarbons
. A THC respons e factor

fo r styrene wa s detennined , afte r th e testin g ha

dbeen completed , usin g th e sam e analyze r andpropan e calibratio n ga s mixtures
. A certifie dstyren e ga s mixtur e wa s presente d t o th e calibrate dTHC analyze r an dth e TH C (a s carbon ) respons e wa s recorded
. Styren e emissio n

K:\l I665\002\OOI\REPORT.DO C 7 Marc h 199 7 8:0 0 A M Versio n 

# U* 2- 1P.2 8

RESULT S AN

D DISCUSSIO N


### rate s wer e then calculate dfromth e TH C a s carbo n emissions , b y assuming th e total emission s were styren e and applyin g th e measure dstyren e respons e factor
. Testin g wa s performeddurin g operatio n o f th e proces s under

norma l operatin g conditions
. Testin g wa s interrupte ddu e to aschedule doutag e (lunc h break)
. Testin g was resume dafte r th e brea k and th e result s fro

meac h tes t

perio dwer

e average dt o represent acomplet e cycl e (time weighted)
. A proces s descriptio n wit

h th e tota l productio n rate an dmateria l input , usedto calculate th e emissio n factors , ha s been include din Appendi x G
.



## • ^ K>t " W { 

## ^ 0



## [ J 

## ^y- A


## - A


## - c 

## ^'¥*\

K M 1665\OH\001\REPORT.DO C 7 March 199 7 8:0 0 A M Versio n 2- 2P.2 9

RESULT S AND DISCUSSIO N
TABL E 2- 2 EMISSIO N DAT A - SPINNIN G MACHINES , COMBINE D COOLIN G VEN T


### Dat e Tim e Bega n Time Ended Stac k Ga s Dat a Temperature , ° F Velocity , ft/sec Moisture , % CO 2 Concentration , % O 2 Concentration , % VFR , dscf m Proces s Inpu t l b PreparedPolymer/h

r lb Styrene/h

r Tota l Hydrocarbons , a s carbo n Concentration , pp m Emissio n Rate , lb/h

r Tota l Hydrocarbons , a s styren e Concentration , pp m Emissio n Rate , lb/h

r Run l 2/4/9 7 065 7 113 0 6 6 2. 0 1. 9 0. 0 20. 8 20 8 1,60 9 20 6 21 5 0.0 8 3 0 0.1 0 

### Ru

n 2 2/4/9 7 1200 ,153 0 6 6 2. 0 1.9 0. 0 20. 8 20 2 1,60 9 20 6 22 9 0.0 9 3 2 0.1 1 Mea n

""*•



### 6 6 2. 0 1.9 0. 0 20. 8 20 5 1,60 9 20 6 221 a 

### 0.08 a 

### 31 a 

### 0.10 a Tim e weighte d average .

K M I665\002\001\REPORT.DO C 7 Marc h 199 7 8:0 0 A M Versio n 

# V( 2-3P.3 0

RESULT S AN

D DISCUSSIO N
TABL E 2- 3 EMISSIO N DAT A - MDON G ROO M VEN T


### Dat e Tim e Bega

n Tim e Ende d 2/4/9 7 065 7 113 0 2/4/9 7

1200 153 0 Mea n

Stack Gas Dat

a Temperature , ° F Velocity , ft/sec Moisture , % VFR , dscf m 6 2 4 1 1. 7 15,10 0 7 0

4 1 2. 2 14,700 6 7

4 1 2. 0 14,90 0 Proces s Inpu t l b Prepare dPolymer/h

r lb Styrene/Shif

t 1,60 9 20 6 1,60

9 20 6 1,60

9 20 6 Tota l Hydrocarbons , as carbon Concentration , pp m Emissio n Rate , lb/h

r 21 4 6. 0 23 0

6. 3 222 a



### 6.2 a 

### Tota l Hydrocarbons , a s styrene Concentration , ppm Emissio n Rate , lb/h

r Tim e weighte d average . 3 0 7. 4 3

3 7. 8 

### 31 a



### 7.6 a

K:\l 1665\002\001\REPORT.DO C 7 Marc h 199 7 8:0 0 A

M Versio n 

# 1^ 2- 4P.3 1

RESULT S AN D DISCUSSIO N
TABL E 2- 4 ANALYTICA L DAT A - AROMATI C HYDROCARBON S



### Aromati c Hydrocarbons 8 

### Styrene , pp m Toluene , pp m Ethy l Benzene , pp m Xylenes , pp m Su mo f Aromati c Hydrocarbons , pp m Styren e Concentration , % Spinnin g Machines , Combine d Cooling Vent Run l 19 2 1. 2 1. 0 3. 0 19 7 | 97 Ru

n 2 15 5 0. 9 0. 6 2. 1 15 9 9 7 Mixin g Roo m Ven t1

Run l 2 5 0. 7 b 

### 0. 3 2 6 9 6 

## Ru

n 2 [ 1 8 | 

## 1. 5 I b 1 0. 2 2 0 | 9 0 "Cumene , benzene , a-methyl styrene , butyl-toluene , vinyl-toluen e an d naphthalen

e wer e no tdetected . ''Ethy l benzen e wa s no tdetecte d o n th e mixin g roo m ven t

K:\ l 1665\002V001\REPORT.DO C 7 Marc h 199 7 8:0 0 A M Versio n 

# 3 o 2-5P.3 2



## SECTIO N 3 SOURC E TESTIN G METHODOLOG Y

Th e emissio n testin g progra mwa s conducte di n accordanc e wit h th e method s indicate d i n Tabl e 3-1
. Detaile dmetho ddescription s andqualit y assuranc e dataar

e provide din th e reference d appendix
. TABL E 3- 1 SOURC E TESTIN G METHODOLOG Y

Paramete r Volumetri c Flow Rat

e Tota l Hydrocarbon s an

dStyrene | Aromati c Hydrocarbon s Metho d Numbe r EP A 1,2,3, 4 EP A 25 A NIOS H 150 1 Appendi x Referenc e

Metho d Descriptio n B. 1 B. 2 B.3 Qualit

y Contro l Data F F F |

Comments Note i Modified , Note 2 [ 

### Notes : 1
. Styren e emission s wer

e calculatedusin g arespons e facto r fo r th e TH C analysis
. A known concentration o

f styren e wa s introducedto a n analyzer andthe respons e recorde din unit s o f propane concentration
. Th e calculatedrespons e facto r i s arati o o f

the know n styrene concentratio n to th e resulting carbon equivalen

t value (propane respons e x 3 = carbon equivalent)
. 2
. A moistur

e knockout

impinge r wa s place din serie s wit

h the charcoa

l tub e fo r th e collectio n o f

th e aromatic hydrocarbons
. Th e impinge r an dprob e were quantitativel

y rinse dwit

h methylene chloride afte r eac h tes t run . Th e methylen

e chloride rins e fraction wa s analyzedin additio n to th e charcoa l tub e (afte r extraction wit

h methylen

e chloride ) andth e mas s of targe t compound foun

dfo r eac h fraction wer e adde dt o giv e th e tota

l mas s fo r th e sample
. A desorption efficien-;" / stud y fo r NIOS H 150 1 compound s i s o

n file wit h th e WESTO

N laborator

y performing the analyse
.

K: U I665\002\OOI\REPORT.DO C 7 Marc h 1997 8:0 0 A

M Versio n 

# 3 1 3- 1

### *

. Apjiendlx.A; ; i^i'.P.3 4



## APPENDI X A SAMPL E CALCULATION S

K;\ l 1665\002\001\REPORT.DO C 7 Mirc h 199 7 8*0 0 A M Versio n ^
__ ^



# 3 3P.3 5

APPENDI X A 

### SAMPL E CALCULATION S Mixin g Tank Roo m Ven t Run No . 1 I . Absolut

e Stac k Gas Pressur e (Ps) , in . H g

Pg Ps = Pb + 13.6

in. H 2 0 / in. Hg where , Pb = barometri c pressure , in
. H g Pg = Stati c Pressure , in
. H 2 0 Ps = 30.00in.Hg + -° J( >in.H 2 0 = 2999ituH 13.6 in. H 2 0 / iru Hg I L Molecula

r Weigh t(DRY ) (Md) , lb/lb-mol e Md - (0.44x%CO 2

) + (0.32 x%0 2

) + (0.28(100 - %C0 2 - %0 2 )) Md = (0.44x0.0) + (0.32x20.8) + (0.28(100 -20.8 - 0.0)) = 28.83 lb / lb • mole in . Molecula

r Weigh t(WET ) (Ms) , lb/lb-mol e M i = M d (7 - Bws ) + 7 8 (Bws) where , M d = molecula

r weigh t (DRY) , lb/lb-mol e Bw s = moistur

e fraction , dimensionles s Ms = 28.83 lb /lb -mole (1 - 0.0148) + 18(0.0148) = 28.67 lb /lb - mole IV . Averag

e Velocit y (Vs) , ft/se c V s = 85.4 9 -i - J - —x Cp x -J Delta P avg. x .1 sec V (°R)(in.H 2 0) \Psx_ Ms where , C p = pito t

tub e coefficien

t Delt aP = velocit

y hea d o f stack gas , in
. H 2 0 T s = absolut

e stack temperature , °

R P s = absolut

e stack ga s pressure , in
. H

g M s = molecula

r weigh t o f stac k gas , lb/lb-mol e

Vs m 85A9 JL UWtlb-nmOUHim

sec V (°R)(in.HJ Vs = 41.34

ft /sec in. Hg)

O) x 0.84

x 0.7332 in. H

2 Oxj 521 °R 29.99 in. Hg x 28.67

lb/lb- mole

KM 1665\002\00l\REPORT.DO C 7 Marc h 199 7 8:0 0 A M Versio n 

# -y\ A- lP.3 6

mwi—^^ /

ammmm rnmi w APPENDI X A
V . Average Stac

k Ga s Flo w a tStac

k Condition s (Qa) , acf/min Qa = 60 sec/

min x Vs x As where, V s = stac k ga s velocity , ft/sec A s = cross-sectiona

l are a o f stack , ft 2 Qa = 60sec/min x41.34ft/sec x 6.21ft 2 = 1.54E + 04

acf/min VI . Averag

e Stac k Ga s Flo w a tStandar

d Condition s (Qs) , dscf/min Qs = 17.647

— —x Qa x (1 - Bws) x — . in. Hg Ts where, Q

a = averag e stac k ga s flow a tstac k condidons , ftVmin Bw s = moistur

e conten t(dimensionless ) Ps = absolut

e stac k ga s pressure, in . H

g T s = absolut

e stac k temperature

, ° R Qs = 77.64 7 — —xl.54E + 04,^- x (1 - 0.0748 ) x 29
- 99lTlH S = 1.52E + 04

dscf/min iruHg -min 521 °R VTI . TH C Concentratio n dry as Propane (P) , pp m OiL/L ) THC dry as P = —— —= 721
_ 71.4ppm(uL/L) (1 - Bws) (1 - 0.0148) yy

wher e Bw s = moistur

e fraction , dimensionles s VUl . THC Concentratio n dr y as Carbon (C) , ppm (jiL/L ) THCdryasC

= THCdryasPppm x 3 = 71.4ppm x 3 = 274. 7 IX . THC Emission Rat

e (TH C EMR) , lb/h r a s Carbo n THCdryasC

x MW x Qs x 60 — x 28.32 -p THC EMR = • —•*

24.04 - x l.OxlO 6

^ x 454

•$- g - mole L lb

where , TH C dr y a s C = TH C conc . dr

y a s Carbon , pp m (nL/L ) M W = molecula

r weigh to f carbon , 12.0 1 g/g-mol

e Qs = stac k ga s flo w a tstd . cond. , dscf/mi

n 27 4 & x 12.01 —I

—x 1.51E + 04^x60^x 28.32 ±j THC EMR = £ £12 £ : E J £ tL. = 6.03 lb/hr

24.04 x l.OxlO 6

=- x 454

-^ - g - mole L lb

KA I 166S\002\001\REPORT.DO C 7 Marc h 199 7 8:0 0 A M Versio n """ 2 C A- 2



# 3 5P.3 7

APPENDIX A
X . TH C Concentration a s Styrene (St) , pp

m (nL/L ) THC as St, ppm = THC

as Cppm x Response Factor= 214.1 ppm x 0.742

= 30.40ppm where, Response Facto r i s fro m th e styren e conversio

n CEM S dat a (0.14 2 pp

m styrene/ 1 pp m carbon ) XI . TH C Emissio

n Rat e (TH C EMR) , lb/h r a s Styren e THC dry as St x MW x Qs x 60 —x 28.32 ^ THC EMR = r - ^ —£—

24.04 - x LOx l(f

Z=- x 454

±- g - mole L lb

where, TH

C dr y a s S t= TH C conc . dr

y a s Styrene, pp

m (nL/L ) M W = molecula

r weigh to f styrene , 104.1 4 g/g-mol e Q s = stac k ga s flo w a tstd . cond. , dscf/mi

n 30.4 0 ^ x 104.14

^ x 1.5IE + 04

^ - x 60 — x 28.32 -^rL g-mole min hrft* THC EMR = -— 7 -rJ

— = 7.43 lb/hr 24.04 x 7.0 x l& =- x 454 -£ - g - mole L lb XII . TH C Emissio

n Rat e as Styrene (St) , I

b styrene/l b prepare d polymer

„, „ „ THC as St. lb/hr7.43 lb / hr^ „
_n j lb stvrene THC as St = • • —— = •— • -4.62E-03- Process Input, lb prepared polymer/

hr1608.8

S lb prepared

polymer/

hrlb prepared polymer XIII . TH C Emissio

n Rat e a s Styrene (St

) tim e weighte d average , Ib/h r Run 1 THC

as St, —x Run 1 time, hr+ Run 2 THC as St. —x Run 2 time, hr THC average = ^ =—7 = 7 ~ — Total Time, hr 7.43 — x 4.5hr+ 7.78 — x 3.5hr., THC average = ^ ^ = 7.58 — 8hrhr

K:\11665\002\00l\REPORT.DOC7Marc h 199 7 8:0 0 A M Versio n A- 3

# mymyymmymmymmammymy *•"*••*••.•.* • ••?;..• : ,:*'» • ;*..v.^=^xi>;:t*-i-••,*:.w?-t:*s*fe^:****!^*K*?ia*-*^*K***-:; - 

# 3 1P.3 9



## APPENDI X B TES T METHODOLOGY

B. 1 VOLUMETRI C FLO W RAT E B. 2 TOTA L HYDROCARBON S B. 3 AROMATI C HYDROCARBON S

KW 1665\002\001\REPORT.DO C 7 Marc h 199 7 8*0

0 A M Versio nP.4 0

APPENDIX B 

### B. l VOLUMETRI C FLO W RAT E Mas s emissio n rate s ar

e calculate db y multiplyin g measuredtarge t analyte concentration s b y calculate d volumetri c flo

w rates . Volumetri c flo w rate s ar e calculate dusin g measuremen t dat a obtaine d b y EP

A Referenc e Mediod s 1-4
. Th e ductwor

k i s measure da

t the sampl e locatio n t o th e neares t 0.2 5 inch usin g astee l tap e measure . Travers e point s ar

e selecte di

n accordanc e wit

h EP A Referenc e Metho d1 o n th e basi s o f ductwor k dimensions , geometry , an

dupstrea man ddownstrea

mdisturbances
. Whe n asampl e locatio n doe s no t meet EP A Referenc e Metho d1 criteria , th e maximu mrecommendednumber of travers e point s ar e used
. Ga s Velocit

y Th e velocit

y o f th e ga s strea

mi s measure di n accordanc e wit h EP A Referenc e Metho d2 b y readin g th e instantaneou s velocit

y pressur e wit h a n incline dmanomete

r a t each travers e point

usin g either

a standar d"P " typ e o r

a n "S " typ e pito t

tube
. Th e stac k

pressur e i s calculate dfro

mth e measure d stati c pressur

e o f th e stac k an dth e ambient

barometri c pressure . Th

e stati c pressure i s measure d b y usin g th e stati c side of

th e pito t tube , an dth e barometri c pressur e i s measure dusin g acalibrate d aneroi d barometer
. Magnahelic ® gauge s wit h scale s of

0 t o 5 an d0 t o 2 5 inche s o

f wate r o r a n incline dmanomete

r wit h ascal e o

f 0 t o 1 0 inche s o

f wate r ar e use dfo r velocit y pressur e measurements . Manomete r selectio n i s determine db y th e velocit y pressure of

th e ga s stream . A manomete r wit h a0 t o 0.2 5 inch scal e ma y b e use dwhen th e velocit y pressure of

th e ga s strea

mi s les s tha n 0.0 2 inche s o

f water . B y convention , an y measuredvelocit

y pressure s o f

les s tha n 0.00 5 inche s o

f wate r ar e recorde dan dreporte da s les s tha n 0.00 5 inche s o

f water . Th e stac k temperatur

e i s measure dwit

h acalibrate dthermocoupl e andpyrometer . For lo w velocit

y pressur e measurement s (les s tha

n 0.00 5 inche s o

f water ) aho t wir e anemomete

r ma y b e usedt o measur e th e velocit

y o f th e ga s stream . Th e indicatedvelocit y i s use dwithout

correctio n whe n the gas strea

mi s ambien

t ai r wit h amoistur

e content o f les s tha n 65%
. Th e indicate d velocit y i s corrected i n accordanc e wit

h procedure s specifie db y the manufacture r whe n th e moistur

e conten t exceed s 65 % o

r whe n th e dr y gas fraction i s somethin g othe r tha n ambien t air
. Ga s Compositio n an dMoistur e Conten t Th e compositio n of

th e ga s strea

mi s measure di n accordanc e wit h EP A Referenc e Metho d 3 usin g a n Orsa t or Fyrit e Combustio n Ga s Analyzer
. Ga s compositio n determination s ar e conducte d usin g eithe r integrate do

r gra b sampling techniques
. Gra b sample s ar

e analyze dusing aFyrite analyzer b y withdrawin g agas sampl e fro mth e sourc e and introducin g th e sampl e directly t o azeroe doxyge n o r carbo n dioxide combustio n ga s analyzer
. Afte r introductio n o

f th e ga s sample , th e analyzer i s inverte dthe prescribe dnumber o f time s and th e

KA I 1665\002\001\REPORT.DO C 7 Marc h 199 7 8:0 0 A M Versio n , - /- \ B- l



### 51P.4 1



### APPENDD C B analyzer flui dleve l i s recorde dgivin g apercen t b y volum e determinatio n o f th e oxygen o r

carbo n dioxid e concentrations
. Integrate d sample s ar

e collecte db y withdrawin g asampl e fro mth e sourc e throug h amoisture condenser into aTedlar

® sampl e bag
. Th e ba g i s then analyze dusin g a n Orsa t analyzer
. Th e moisture content

ofth e ga s strea

mi s determine dusin g one ofth e followin g procedures :

• For source s requiring testin g b y EPA Referenc e or Tes t Method s 5 , 8 , 12,13,17 , 23 , 26A , 29,0010 , o

r 0011 , moistur

e i s detennine db y EP

A Referenc e Metho d4
. A

t th e conclusio n o f each ru n th e volum

e o f condense dmoistur

e i n th e impinger s of

th e samplin g trai n i s measuredan

duse dto calculat

e th e moistur

e content ofth e gas stream .

• For source s wit

h temperature s greate

r tha n 21 2 °F , th

e approximatio n techniqu e describe d in EP A Referenc e Metho d 4 ma y b e use dwit

h midge t impinger s t o condens e moistur e befor e dr y gas volum

e measurement .

• For source s wit

h atemperatur

e of les s tha n 21 2 °F , we

t bulb/dr y bul b temperatur

e measurement s ma

y b e made , andth e moistur e conten t calculate dusin g vapo r

pressure tables
. Whe n multipl e method s ar e use dfo r moisture determinations , th e lowes t moisture valu e i s use d fo

r volumetri c flow calculations
. Th e molecula

r weigh t o f th e ga s strea

mi s calculate dusin g th e measure dmoisture , oxygen , and carbo n dioxid e concentrations
. Th e balanc e of th e ga s strea

mi s assume dt o b e nitrogen
. Th e volumetri c flow i s then calculate da t stac k andstandardcondition s usin g th e calculate dmolecula r weight , th e measure dstac k temperature , andmeasure dvelocity , stack andbarometri c pressures . Standar d condition s ar

e 6 8 ° F and29.9 2 inche s of mercur y and0 % moisture
. Dat aAcquisitio n an dReportin g Dataar e recorde da

t the time o

f collectio n o n preprinte ddat asheets
. Calculation s ar e performe d (wher e possible ) wit

h preprogramme dcalculator s o r spreadsheet

software
. Oualit v Contro l Qualit y contro l procedure s fo

r volumetri c flo w measurement s involv e lea k check s of

pito t tubes , pito t tub e line s an

dmanometers ; periodi c analysi s o f ambien t air andduplicate analysi s of

sourc e ga s sample s wit

h the Fyrit

e analyzer ; triplicat e analysi s wit h th e Orsa

t analyzer ; and periodi c calibratio n check s of

thermocouple s an dpyrometers .

K:\11665V102\001\REPORT.DOC7March 199 7 8:0 0 A M Versio n (_£- » B- 2



# f oP.4 2



### APPENDDC

B Dat atransfer s ar

e minimized
. Dat asheet s ar e checke dfo

r completenes s andaccuracy . Calculation s are verifie dby asecon dperson . 

### B. 2 TOTA L HYDROCARBON CONCENTRATION Total hydrocarbo

n (THC ) concentration s ar

e sample dusin g EP

A Referenc e Metho d2 5 A and analyzed b y WESTO

N o n sit e wit

h aflam e ionizatio n detecto r

(FID ) analyzer
. I t

shoul db e note dtha

t Metho d 25 A determine s tota

l organics , including methane , whic h i s no t aregulated volatil e organi c compound (VOC)
. Samplin g Equipmen t

an dProcedure s Figur e B- l i s aschemati c of

th e EP A Referenc e Metho d25 A sampling system . A n extractiv e syste

m i s use da t th e samplin g location s t o obtai n vent ga s samples
. Sample s ar

e withdraw n continuously a t a singl e poin

t an dtransporte dt

o th e FT D through aheate dprob e Teflon ® filter, an

dheate d Teflon

® sampl e line
. All hydrocarbo n measurement s ar e made o n a"hot , wet " basis
. Sampl e Anaivsi s A TEC O Mode

l 5 1 total hydrocarbon analyze r i s use dt o measur e th e tota l hydrocarbo n concentratio n i n th e sourc e gas . Thi s analyze r utilize s aFID a s describe db y EP A Referenc e Metho d 25A
. Th e technique i s no

t selectiv e between species , an dth e results ar

e reporte da s carbo n volum e equivalent s o

f th e calibration gas (propane in nitroge n or propan e i n air)
. Prio r to eac h test , th e samplin g andanalytica l syste mare calibrate dusing tw o calibratio n gase s (zer o an d8 0 t o 9 0 percen

t o f span)
. Thi s ste

p i s followe db y acalibratio n erro r chec k utilizin g tw o additiona l cahbration gase s a

t approximatel

y 2 5 an d4 5 percen

t o f th e spa n value
. The acceptanc e criterio n fo r th e cahbratio n error

check i s les s tha n 5 % th e certifie dgas value
. Dat aAcquisitio n an dReductio n Datai s acquire

delectronically using a

n IB M compatibl e compute r andsoftwar

e designe d b y WESTO N fo r EP A Referenc e Metho d25 A analysis
. Oualit v Contro l Th e calibratio

n an dcheck gase s ar e propane , i n either

nitrogen o

r air , certifie daccording t

o EP A Protocol-1
. Followin

g eac h sampl e run , th e calibratio n drif t o f th e syste mi s checkedb y introducing th e zer o an don e upscal e gas t o th e syste man drecording th e response . Thi s differenc e in concentratio

n must b e withi n five percen

t o f the ful l scal e spa n value
.

K:\tl665\002\001\REPORT.DO C 7 Marc h 199 7 8:0 0 A M Versio n B- 3



# 4 \?*

:

< 8 . 

# 1°

£ ^ ^ STAC K £ WALL HEATE D SAMPL E UN E
HEATE D RLTE R

HEATE D UN E DAT A ACQUISITIO N SYSTE M

TOTA L HYDROCARBO N R D ANALYZE R DAT A OUTPU T



## r HEATE D TEFLO N PUM P CAUBRATIO N GA S UN E GA S MANIFOL D 

# W U r l r l r I *

CAUBRATIO N GASE S



### Figur e B- l EP A Reference Metho d 2S A Samplin g Syste m 

# W

•* * c oP.4 4



### APPENDD C B 

### B. 3 AROMATI C HYDROCARBON S Samplin g an

d analysi s ar

e performe d usin g th e guideline s describe din NIOS H Metho d 1501
. Aromati c hydrocarbon s include : benzene , p-tert-buty l toluene , cumene , ethy l benzene , amethylstyrene , naphthalene , styrene , toluene , vinyl-toluene , andxylenes
. Samplin g Equipmen t

an dProcedure s Sample s ar

e withdraw n fro

mth e sourc e a

t aflo w rate betwee n 0. 2 and1.0 L/min through aTeflon ® prob e andUn

e to acoconut

shel l charcoa

l sorben t tube
. Th e tub e contain s 10 0 m g of charcoa l i n th e fron t sectio n an

d5 0 m g i n th e bac k

section
. Th e tw o section s o f th e tub e ar

e separate db y a2-m

m urethan e foa

mplug
. A silylate dglas s woo l plu g precede s th e front sectio n and3-m

murethan e foa

m plu g follow s th e bac k

section
. Th e outle t

o f th e sorbent

tub e i s connecte d t o alea k free vacuu m pum p an d calibrate drotometer . Followin g asuccessfu

l lea k check , th e initial rotometer readin g andsamphn g syste mbarometri c pressur e ar e recorde da

t th e star t o f ga s strea mcollection
. Th e temperature a t th e rotometer

i s recorde d periodically
. Afte r completio n o

f th e samplin g procedure , th e final rotomete r readin g i s recorded
. A post-tes t

lea k check i s performe dan dth e sorbent tube s are seale dan

dplace d o n ic e prio r t o shipmen

t to th e laborator

y fo r analysis
. Sampl e Anaivsi s Th e fron t an d back section s o f th e sorbent

tub e ar e extracte dseparately
. Th e fraction adsorbe d fro m th e ga s strea

mi s extracted , separated , andmeasure db y GC/FLD
. Dat aAcquisitio n an dReductio n Dataar e recordeda

t th e time o

f collectio n o n preprinte ddat asheets
. Wher e possible , calculation s ar e performedwit

h preprogramme dcalculator s or spreadshee t

software
. Oualit v Contro l A n unusedsorben

t tub e i s retaine dandanalyze da s ablank
. Te n percent o f all sample s ar

e analyze d in duplicat e to demonstrat

e repeatabilit

y of laborator y results
. Prio r t o andfollowing eac h ru

n th e samplin g trai n i s lea k checked
. A leakag e rat

e no t i n exces s o f 2 % o f th e averag e samplin g rat

e i s acceptabl e fo

r th e pre-ru n check
. I

f alea k i s detecte din th e pos t run check , th

e tes t ru n i s voided , or

acceptabl e procedure s ar

e made t o adjus t

sampl e volum

e fo r th e leakage
. Initial , post-tes t

an dcontinuin g calibratio n ar e performed
. Th e rotomete r calibratio n i s include d i n th e final report. Sampl e volume s ar e correcte dt o standardtemperatur e andpressur

e to obtai n th e dr

y standar dsampl e volume
.

K:V11665\002\001\REPORT.DO C 7 Marc h 199 7 8:0 0 A M Versio n _B- 5P.4 5



### APPENDD C B Datatransfer s are minimized
. Fiel dandlaborator y dat asheet s are checke dfo r completenes s an d accuracy . Calculation s are verifiedb y asecon dperson .

KA I 1665\002\001\REPORT.DO C 7 March 199 7 8:0 0 A M Versio n (J'L C B- 6



# wv - , '"-••• ^ Mfiy$P.4 7



## APPENDI X C FIEL D DAT A - SPINNIN G MACHINES ,

COMBINE D COOLIN G VEN T

K M 1665\002\001\REPORT.DO C 7 Marc h 199 7 8:0 0 A M Versio n 

# ^ b

### TH C a s Styren e Emission s P.4 8

Proces s Input , l

b prepare d polymer/h

r 

## eg) Proces s Input , I

b styrene/hr) _^'_ r ^__mZ^i£g_____*_i_?_^m_^x?-T_7*' Vr '

~ SpmningMachin e Combined Coolin g Vent Mixing Roo m Ven t

Ave
. Emission Rate , lb/h

r a s styrene * Ave
. Emission Rate , l

b styrene/l b prepared polyme

r input * Ave
. Emission Rate , l

b styrene/lb styrene input * 'Tim e weighte d average . ^
. -0.1 0 ' W -v •- • 7.5 8 .5* . •?i|iv.' * ;Tiota l V1S08.8 5 ..,•306.22 . ns%
4&8&0 3

K:\11665\002\O01\MRVO2.XL S 

# M~ 7 C- 1 Pfinte o on : 3/7/9 7 3:4 7 A MP.4 9

TH C EMISSIO

N CALCULATION S Client : Location : Westo n W.O
. No. : HB& G

Troy , A L 11665-002-00 1 Sourc e Cod

e : Spinnin g Machine Combined Coolin g Ven t

Ru n Numbe r Dat e Tim e Bega n Tim e Ended Volumetri c Flow Rate , dscfm* Moistur e (Bws ) Respons e Factor , (Styrene/Carbon ) Tota l Hydrocarbo n Concentration , pp

mwe t a s propan e Concentration , pp

mdr y a s propan e Molecula r Weign t o f C , ug/ug-mol e Concentration , ppmdr

y a s C Emission Rate , lb/h

r as C b Styren e Molecula r Weigh t o f styrene , ug/ug-mol e

b. c 1

2/4/9 7 065 7 113 0 2.08E+0 2 0.01 9 0.14 2 2

2/4/9 7 120 0 153 0 2.02E+0 2 0.01 9 0.14 2 Averag e

2.05E+0 2 0.01 3 0.14 2 70. 3 71. 7 12.0 1 215. 0 0.08 4 104.1 4 30.5 3 0.10 3 75. 0

76. 5 12.0 1 229. 4 0.08 7 104.1 4 32.5 7 0.107 72. 7

74. 1 12.0 1 22 1 0.08 5 104.1 4 31. 4 0.10 5 Concentration , ppmdr

y a s styren e Emission Rate , lb/h

r a s styreneb

' Ru n 1 an d2 VM F fromaverag e of

Run s 1 and 2 of

velocit y travers e data
. b Tim e weighte d average . c Styrene concentratio n calculate d usin g th e measure d THC respons e facto r o f 1 pp mC - 0.14 2 pp

mstyrene .

K:\1-66S\002\001\SMCH01.XL S % C- 2 Printe d on : 3/7/9 7 3:S S A MP.5 0

EMISSIO N CALCULATION S Clien t Locatio n Westo n W.O . No .

Sourc e

Ru n Numbe r Dat e Tim e Bega n Tim e Ende d Styren e Molecula r Weight , ug/ug-mol e Correcte d Sampl e Volume , L Mas s o f Sample , ja

g Concentration , ppm Toluen e Molecula r Weight , ng/|ig-mol e Correcte d Sampl e Volume , L Mas s o f Sample , ji g Concentration , ppm Ethy l benzen e Molecula r Weight , |ig/|ig-rnol e Corrected Sampl e Volume , L Mas s o f Sample , n g Concentration , pp

m Xylene s Molecula r Weight , jig/|ig-mol e Corrected Sampl e Volume , L Mas s o f Sample , n g Concentration , pp

m HB& G

Troy , A L 11665-002-00 1 Spinnin g Machin e Combine d Coolin g Ven t

1 2/4/9 7 084 6 094 6

104.1 4 12.0 3 1000 0 191. 9
92.1 0 12.0 3 56. 0 1 2
106.2 0 12.0 3 52. 0 1. 0
106.2 0 12.0 3 160. 0 3. 0 2

2/4/9 7 125 0 135 0

104.1 4 11.9 4 800 0 154. 7
92.1 0 11.9 4 42. 0 0. 9
106.2 0 11.9 4 32. 0 0. 6
106.2 0 11.9 4 110. 0 2. 1 Sampl e volum e equivalen to f styrene , % 9 7 98

K:\1166S\O02\00l\SMCHO1.XL S ^ C- 3 Pflnwe * on : 3/7/9 7 3:1 2 A MP.5 1

VELOCIT Y CALCULATION S
Client : H

B & G Location : Troy , A

L WESTO N Project No. : 11665-002-00 1 Source : SMCCV
Ru n Number Dat e Time Bega

n Time Ende d 1 2 2/3/9 7
_2/3/9 7 130 0 140 0 Averag e

Volumetri c Flo w Data Velocity , ft/min Point 1 Point 2 Poin t 3 Point 4 Point 5 Poin t 6 Point 7 Poin t 8 Poin t 9 Point 1 0 Point 1 1 Point 1 2 Poin t 1 3 Poin t 1 4 Point 1 5 * Point 1 6 Point 1 7 Poin t 1 8 Point 1 9 Point 2 0 Poin t 2 1 Point 2 2 Poin t 2 3 Poin t 24 Averag e Velocity , ft/min Barometri c Pressure , (Pb).in
. H g Stati c Pressure
. (Pg ) in
. H 2 0 Stack Pressur e (Ps)
. in
. H

g Stac k Diamete r (l.D.) , in
. Stac k Cros s Sectiona

l Area , ft 2 MFR
. std
. temp , fo

r anemometer . °R Stac k Ga s Temperature (ts) , °

F Moisture
. (BWS ) C0 2 Concentratio n (C0 2 )
. % 0 2 Concentratio n (0 2 ) , % Molecula r Weigh t (Ms) , lb/lb-mole Velocit y (Vs) , ft/sec Volumetri c Flo w Rate , A t Stac k Condition s (Qa) , ACF

M A t Standar dCondition s (Qs) , DSCF

M k'. l I665W2\OOI\SMHOVEL.XL S 100 75 75 7 5 7 5 10 0 12 5 15 0 25 0 25 0 25 0 20 0 7 5 75 7 5 7 5 75 100 10 0 10 0 15 0 15 0 15 0 10 0 12 3 30.0 0 0. 0 30.0 0 17.7 5 1.7 2 53 0
6 0 0.014 9 0. 0 20. 8 28.6 7 2. 0
20 7 20 8 7

5 7 5 10 0 100 100 10 0 15 0 15 0 25 0 20 0 20 0 20 0 7 5 7 5 10 0 20 0 10 0 10 0 10 0 7 5 100 75 100 100 12 1 30.0 0 0. 0 30.0 0 17.7 5 1.7 2 53 0
7 1 0.023 9 0. 0 20. 8 28.5 7 • 2. 0
20 8 20 2 12

2 30.0 0 0. 0 30.0 0 17.7 5 1.7 2 530
66 0.01 9 0. 0 20. 8 28.6 2 2. 0
20 8 20 5 

## So c-n Prime d On : 3/7/9 7co i rem ^CH o

wni r Ttni B m M

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• • Calculate d Dat a Sampl e Volum e ( L ) Corr . Sampl e Volum e ( L ) Calculatio n Vst d

Note s .*. . 

### e.\ 3

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# 5 V C- 8P.5 6 R U M SUMMAR Y Run s 1 an d 2 

### Clien t Henderson,Black, & Greene . Sourc e SMCHO " Z< MRVO Dat e Fe b 4 , 139 7 Projec t No . 116G5-002-00 1 Analys t Robert s
TH C pp m TH

C pp m
BIA S DAT

A Post-run bia s a

t 9:0 6 Zer o Spa n Spa n Ga s

AVERAGE DAT A Ru n 1 Ra w average s

•*•**••-. ' A Q A 

### Correcte d usin

g post-ru

n bia s N/ A N/ A
Ru n 2 Ra w average s JrnCtt O _*nrvrig.V_

_ 494 ^ 82.2^ - Correcte d usin g post-ru n bia s

N/ A N/

A

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# 9 S 

# -^Pffi Q C- 9FIEL D

Clien t Henderson,Black, & Green e Sourc e SMCH O & MRV O Dat e Fe b 4 , 199 7

Dat e Fe b 4 , 199 7

Startin g tim e 

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Projec i

TH C m v b No . Analys t

pp m 

## nrrii / l-minu t 24 5 24 4 24 6 24 8 24 3 25 4 26 5 27 6 28 5 36 2 41 4 40 5 41 8 42 4 42 9 42 9 44 5 51 2 50 4 50 0 49 8 50 3 50 8 51 1 52 1 54 9 61 0 70 1 70 6 68 8 72 3 99 9 76 0 57 6 61 5 61 5 57 1 51 9 49 4 50 1 50 1 39 4 11665-002-00 1

Robert s
TH C m v ppm 3rn<L^ O e dat a averaqin q perio d 2 4 / 2 4 2 4 2 5 2 4 2 5 2 6 2 8 2 9 3 8 4 4 4 3 4 4 4 5 4 5 4 5 4 7 5 5 5 4 5 4 5 4 5 4 5 5 5 5 5 6 5 9 6 6 7 7 7 7 7 6 7 9 11 2 8 4 6 2 6 7 6 7 62 y 5 6 5 3 5 4 5 4 4 1 *"?*T , 7 27 7 31 7 34 8 35 8 36 0 36 7 38 7 40 1 38 7 38 4 38 1 38 4 37 7 38 3 38 4 38 8 39 1 38 6 33 4 38 4 38 8 62 4 94 4 103 3 111 2 123 3 150 9 161 6 167 5 188 5 295 0 727 7 785 7 785 6 785 6 785 6 785 8 785 9 786 0 785 7 2. 9

* 5 =• . 4. 1 4. 2 4. 4 4. 6 4. 6 4. 7 4. 9 5. 1 4. 9 4.9/ ' 4. 9 4. 9 4. 8 4. 9 4. 9 5. 0 5. 0 4. 9 4. 9 4. 9 4. 9 7. 9 12. 0 13. 2 14. 2 15. 8 19. 2 20 . 6 21. 4 24 . 0 37. 6 92.8 ' 10 0 1 0 0 1 0 0 10 0 10 0 1 0 0 10 0 1 0 0 

# WisftinJ * H.- D

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### FIEL D DAT A Ru n 1 Clien t Henderson,Black, & Green e Projec t No . 11665-002-00 1 Sourc e SMCH O & MRVO Analys t Robert s Dat e Fe b 4 , 199 7 THC THC Tim e m v pp m m v pp m
Ru n Averages : -?:S 7 t o 8+39 -

48 1 5 2 221 7 28. 3



# *1 

# •v^am c 

# -FIEL D DAT A Ru n 2 P.5 9

Clien t Henderso n % Black, ! Sourc e SMCH O & MRV O Dat e Fe b 4 , 199 7 l a reen e Projec t No . Analys t 11665-002-00 1

Robert s

Tim e 7". HZ. TH C

mv pp m TH C

m v pp m Startin g time S-H^ 7 1-minut e dat a

8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 9 9 9 9 9 4 3 4 4 4 5 4 6 4 7 4 8 4 9 5 0 5 1
5 4 5 5 5 6 5 7 5 8 5 9 0 0 0 1 0 2 0 3 0 4 0 5 =.,364 522 9 491 4 459 2 4451 " 467 9 503 2 489 9 569 3 574 7 581 1 554 2 512 4 477 3 443 4 432 8 396 7 331 0 280 8 242 3 2345* / 192 4 170 9 616 / 380 2 60 0 376 6 56 4 52 7 51 1 53 7 57 7 56 2 65 4 66 0 66 8 63 6 58 8 54 8 50 9 49 6 45 4 37 9 32 0 27 6 26 7 21 8 19 4 426 3 540 3 573 8 576 2 559 8 600 7 599 4 621 6 619 9 644 1 669 0 677 8 702 2 785 7 785 8 735 8 735 8 785 9 779 3 757 0 785 4 averagin g 48. 5 48 . 0 54. 4 68. 9 73. 2 73. 5 71.4 / 76. 6 76. 4 79. 3 79. 1 82. 1 

### S er * } 86. 4 89. 6 10 0 10 0 1 0 0 10 0 10 0 99 . 4 96. 6 10 0 perio d

SMCH O MTR V

49 4 Ru n Averages :

430 9 t o 9T©5 -

644 3 82. 2 Pro s

C-1 2 

## S? !P.6 0 

### CALIBRATIO N DRIF T DAT A

Numbe r 1 Starting Tim

e 9:0 6 Clien t Henderson,Black, & Green e Projec t No . 11665-002-00 1 Sourc e SMCH O S

< MRV O Analys t Robert s Dat e Fe b 4 , 199 7 Analyze r TH C TH C Metho d 25 A• 25 A Spa n Conc . tOO

O pp m10 0 pp

m
RESULT S Zer o m v 6 2 8 2 Conc . 3 pp

m 1. 0 pp

m Cal . Zer o 0 pp

m 0. 0 pp

m Spa n m v 384 4 345 1 Conc . 44 0 pp

m44. 0 pp

m Spa n Ga s 44 9 pp

m44. 2 pp

m

CALIBRATIO

N DRIF T
Zer o Drif t 0.3/ / 1.0*/ / Sinc e Ca l 1 Ca l 1 a t _17:0 8 17:0 8 Spa n Drif t -0.9"/ / -0.27 / Sinc e Ca l 1 Ca l 1 a t 17:0 8 17:0 8

^P.6 1



### CALIBRATIO M DAT A Numbe r 1 Startin g Tim e 17:0 8 Clien t Henderson,Black,S < Green e Sourc e SMCH O & MRVO Dat e Fe b 3 , 193 7 Projec t No . 11665-002-00 1 Analys t Robert s Analyze r Metho d Spa n Con c TH C TH C

25 A 25A 100 0 pp m10 0 pp

m
Zer o Result , m

v 3 5 Span tti Conc

. 25 9 pp m 25. 3 pp m Cyl

. I D C£AO«\fr\< A e/Lvoo-V H Result , m

v 224 9 201 0 

### Span tt2 Conc . 45 4 pp

m43. 5 pp

m 

## Cyl . I D <HU\*.0* Uces'vrs s Result , m

v 392 2 346 3

. Spa n # 3 Conc

. 93 3 pp m 92. 6 pp m Cyl

. I D Ctjcflul ^ (LC-»UT2> \ Result , m v810 7 726 0


### Calibration Curv e Coefficient s Slop e 8.652 ^ 78.39 / 

### Intercep t 35. 0 ^ 1.0 / Cor r Coef f N/ A

N/ A

Recalculated Concentration s an d Calibration Error Erro r Use s Valu e Valu e
Zer o Spa n # 1 Spa n # 2 Spa n # 3 pp

m '/.errpp

m '/.err N/ A N/

A 25 $ -1.2 ' 25. 6 1.2 ' 44 9 -1.1 ' 44. 2 1. 6 ' N/ A N/

A

C - H 

## 6&P.6 2


### HARDWAR E IMFORMATIO M Clien t Henderson,Blac k ,S < Green e "Sourc e SMCH O S

< MRV O Dat e Fe b 3 , r.**9 7 - Projec t No . 11665-002-00 1 Analys t Robert s
Analo g inpu t device : ACj r Analo g Car d CStrawberr yTree )

ANALYZER S Channe l 2 : Metho d Analyze r Mak e S

< Mode l Ful l Scal e Output , m v Spa n Concentration , pp m Channe l 3 : Metho d Analyze r Mak e & Mode l Ful l Scal e Output , m v Spa n Concentration , pp m - TH C

25 A Teco5 1 1000 0 100 0 TH C 25 A TecoS l 1000 0 10 0

C-1 5 

# < HP.6 3
R U M SUMMAR Y Run s 1 an d 2 

### Clien t Henderson,Black,S < Green e Sourc e SMCH O S

< MRV O Dat e Fe b 4 , 139 7 Projec t No . 11665-002-00 1 Analys t Robert s
TH C pp m TH C

pp m
BIA S DAT

A Post-run bia s a

t 11:3 0 Zer o - - Spa n —

- Spa n Ga s - -

/••-—C v •

= 

### AVERAG E DAT A Ru n 1 Ra w average s 2 5 I y 

### 5 4 y 

### Correcte d using post-ru n bia s N/ A N/ A
Ru n 2 Ra w average s 44 5 ' 9 3 Correcte d usin g post-ru n bia s

N/ A N/

A

UL\L \



### e>2+ C-1 6

### RU M SUMMAR Y Ru n 3 Client ' Henderson,Black, & Green e Projec t No . 11665-002-00 1 Sourc e SMCH O ?

< MRV O Analys t Robert s Dat e Fe b 4 , 199 7 TH C TH C pp m pp

m
BIA S DAT

A Pre-ru n bia s at 11:3 0 Zer o - - Spa n - - Spa n Ga s - - Post-ru n bia s a t 15:3 0 Zer o - - Spa n - - Spa n Ga s - -

AVERAG E DAT A Ra w average s 44 4 ^ 7 5 Correcte d usin

g averag e o f pre-ru n an d post-ru

n bia s N/ A N/ A

C-1 7



# —w$§m-±

### FIEL D DAT A Ru n 1 P.6 5



### Clien t Henderson,Black,? < Green e Sourc e SMCH O 2

< MRVO Dat e Fe b 4 , 199 7 Projec t No . Analys t 11665-002-00 1

Robert s

Startin g Tim e

V-T* SM C 8:3 0 9:3 1 9:3 2 9:3 3 9:3 4 9:3 5 9:3 6 9:3 7 9:3 8 9:3 9 9:4 0 9:4 1 9:4 2 9:4 3 9:4 4 9:4 5 9:4 6 9:4 7 9:4 8 9:4 9 9:5 0 9:5 1 9:5 2 9:5 3 9:5 4 9:5 5 9:5 6 9:5 7 9:5 8 9:5 9 1 0 :0 0 10:0 1 10:0 2 10:0 3 10:0 4 10:0 5 10:0 6 10:0 7 10:0 8 10:0 9 10:1 0 10:1 1 10 : 1 2 10 : 1 3 10 : 1 4 TH C

m v ;H 0 pp m

MTRV , 

### 1-minut e da i 327 1 343 2 O O O "7 * 270 3 214 6 174 6 146 0 125 4 116 2 107 8 100 3 92 4 86 5 81 1 76 9 72 8 69 0 65 8 £3 0 60 6 57 9 56 0 54 0 52 3 51 1 51 0 50 5 50 8 50 4 49 9 55 4 57 7 53 9 51 3 49 7 49 3 52 4 80 5 92 7 106 7 164 1 263 8 334 4 367 0 409 7 37 4 36 8 30 8 24 4 19 8 16 5 14 1 13 0 12 0 11 2 10 3 9 6 ' 9 0 8 5 8 0 7 6 7 2 6 9 6 6 6 3 6 1 5 8 5 7 5 5 5 5 5 4 5 5 5 4 5 4 6 0 6 3 5 8 5 5 5 3 ' 5 3 5 7 8 9 10 3 11 9 18 6 30 1 38 3 42 0 47 0 TH C m v pp m
> 

### ; a averaqin g per i 53 1 56 0 54 7 53 7 52 6 51 2 46 4 44 5 45 7 47 2 45 4 44 0 42 3 41 6 40 6 39 7 38 9 JU- J 37 8 36 6 *J%J *** * 35 1 34 7 34 1 34 2 39 5 42 5 45 1 41 7 40 3 41 5 39 8 39 9 40 9 40 7 42 2 44 1 44 9 44 5 44 5 46 3 48 8 50 5 53 0 53 7 6 1 6 5 6 3 6 2 6 0 5 9 5 2 5 0 5 1 5 3 5 1 4 9 4 8 4 6 4 5 4 4 4 3 4 2 4 1 4 0 3 9 3 8 3 7 3 7 3 7 4 3 4 7 5 1 4 6 ' 4 5 4 6 4 4 4 4 4 5 4 5 4 7 4 9 5 0 5 0 5 0 5 2 5 5 5 7 6 1 6 2 o d

C-1 8 

# yjiforMN l

### IEL D DAT A Ru n 1 Clien t Henderson,Black,S < Green e Sourc e SMCH O & MRVO Dat e Fe b 4. , 199 7 Projec t No . 11665-002-00 1 Analys t Robert s

<T.Z< \ 1

10 : 10 : 10 : 10 : 10 : 10 : 10 : 10 : IO
I O 1 0 1 0 1 0 1 0 UX 

### 'im e 1 5 1 6 1 7 1 8 1 9 2 0 2 1 2 2 .2 3 2 4 .2 5 :2 6 :2 7 :2 8 

### *-se

TH C



### m v 422 4 442 9 544 2 637 1 694 5 565 5 459 2 428 9 415 6 393 5 380 6 457 6 519 2 627 3 635 2 

### pp

m 48 4 50 8 62 5 73 2 79 9 650 y 52 7 / 49 2 47 6 45 1 43 6 52 5 59 6 72 1 73 0 TH C 

### m v 56 6 54 9 53 6 53 2 53 8 55 1 53 6 56 4 60 3 58 6 59 0 59 5 63 4 66 0 68 8 pp m 6 5 6 3 6 1 6 1 6 2 6 3 6 1 6 5 7 0 6 8 6 8 6 9 7 4 7 7 8 1 •s 

### Ru n Averages : 9:2 9 t o 10:2 9

220 9 25 1 47 4 5 4



### toS C-1 90 1 •rt
0 > ct * **-• • 3 l£l
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J i D U J k D 

### • - • - ,_ * | 1
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### t o t o c o t o t o to r o c nj i t o ro i - o U J C O 

### v i tnc

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### v i c nL

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### s j cnL

nj i O J

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### j i Lntnc nc nc nc nt nc no i L nt nt nt nt nt nL

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nt o s 4 to t o oo o nt o s i t o oo o i **•

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### •s i L nj i t o t o t o t o t o j i j i L nL n* • t o t o t o t o t o r o r o r o r o t o t o L nt ns i v i L nc nc ns j v j L n c o c o s j j i o t o c no o -

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n o i r o -D r o wo i r o t o j i t n r o to to r o jn-o m o t n L

n L n L H c n c o to o •- * v i j i L n c o r o r o r o L n c o r o U J L n •- » U J t n J i to c

n j i u > j i •-* • o o »- * c n j i U['CDCDOOODOOOOs4v|-J*v|vJv|s4vjajv|vimoOsJCDCOCOOO"J)'aiUJOu:'UjOOOOmCO m 

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o s i I D L n u > ro u i • - j i t o s i iDUjui'OooooomsivivivioiroLnffiuirororoLnLnL n to j i P J i j i j i r

o o o o o L n L n UJ U I to t

o ro p »- p L

n u i » - 3

I D DOll ,

O i o *- rt-C •*• I D tI D n 3 I D rt3 < T J T J 3 X O

3 < T J T J 3 X O 3 

### a ^IU J x I D 3 I D CTO I Ji O I D

• • •*•** ; « ° u l "
—o UJ 3 3 UJ73 * v j < 0 0 O •* - tu l~ l 7 7
U. "

- < I D I D 3 I D

T l t O <~ . J > I D 3 n 0 i rt- i — ** < z i n o rt- • T J - 0 • - c rro I D ro -_ L n < + 1 i n p p r o i p p T J C 3 O J H 

## in 

# r c i 

# o ] > 

## H

BP.7 5


### CAI

_I BRA T I O M DRIF T DAT A

Numbe r 1 Startin g Tim

e 11:3 0 Clien t Henderson,Black,S < Green e Projec t No . 11665-002-00 1 Sourc e SMCH O & MRV O Analys t Robert s Dat e Fe b 4 , 199 7 Analyze r TH C TH C Metho d 25A

25

A Spa n Conc . 1-00

0 pp m100 0 pp

m
RESULT S Zer o m v 2 0 6 6 Conc . - 2 pp

m1 pp

m Cal . Zer o 0 pp

m0 pp

m Span m v 388 6 349 5 Conc . 44 5 pp

m44 0 pp

m Span Ga s 44 9 pp m44 6 pp

m

CALIBRATIO

N DRIF T
Zer o Drif t -0.27. y 

### 0.V// Sinc e Ca l 1 Ca l 1 at _9:0 9 9:0 9 Span Drif t -0.47 . -0.67 . / 

### Sinc e Ca l 1 Ca l 1 at 9:0 9 9:0 9

C-2 8 

# T fP.7 6 

### CALIBRATIO N DRIF T DAT A Numbe r 2 Startin g Tim e 15:3 0 Clien t Henderson,Black, & Green e Sourc e SMCH O S

< MRV O Dat e Fe b 4 , 199 7 Projec t No . 11665-002-00 1 Analys t Robert s Analyze r TH C TH C Metho d 25 A 25 A Spa n Conc . 400 0 pp m100 0 pp

m
RESULT S Zer o m v Conc . Cal . Zer o Spa n m v Conc . Spa n Ga s -?*"7

-

- 1 pp m 0 pp m 400 0 45 8 pp m 44 9 pp m 7 3

2 pp m 0 pp m 358 1 45 0 pp m 44 6 pp m



### CALIBRATIO NDRIF T
Zer o Drif t Sinc e a t -0.1*/ /

Ca l 1 9:0 9 0.27 . '

Ca l 1 9:0 9 Spa n Drif t 0.97. ' 0.47 . ' Sinc e Ca l 1 Ca l 1 a t 9:0 9 9:0 9



# IS C-2 9



# -MpffiQ -P.7 7



### CALIBRATIO M DAT A Numbe r 1 Starting Tim

e 9:0 9 Clien t Henderson,Black,S < Green e - Projec t No . 11665-002-00 1 Sourc e SMCH O & MRV O Analys t Robert s Dat e Fe b 4 , 199 7 Analyze r TH C TH C Metho d 25 A25 A Spa n Cbnc . 100 0 pp m100 0 pp m

Zero Res u 11 , m

v 3 5 5 5 Spa n # 1 Conc . 25 9 pp m25 9 pp m 

### Cyl . I D ccio-m- 4 ce.\o«\cq q Result , m

v 224 9 206 2 Spa n # 2 Conc
. 45 4 pp m45 4 pp m Cyl
. I D CJUl2.oju > teuton * Result , m

v 392 2 354 8 Spa n # 3 Conc . 93 3 pp m93 3 pp m Cyl . I D CCVO^U"!* ^ CC_10*^6.7« ? Result , mv 810 7 735 8

Calibratio n Curv e Coefficient s Slop e 8.652 ' 7.827 y Intercep t 35. Q ' 55.0- ^ Cor r Coef f N/ AN/ A

Recalculate d Concentration s an d Calibratio n Erro r

Erro r Use s Valu e Valu e

pp m '/.err ppm '/.err Zer o N/ AN/ A Spa n # 1 25 6 -1.2 / 25 6 -1.2 ^ Spa n # 2 44 9 -1. 1 ' 44 6 -1.8 ' Spa n # 3 N/ AN/ A

C-3 0



### ICoP.7 8


### HARDWAR E INFORMATION Clien t Henderson,Black,2 < Green e Sourc e SMCH O ?

< MRVO Dat e Fe b 4 , 199 7 Projec t No . 11665-002-00 1 Analys t Robert s

Analo g inpu t device : ACj r Analo g Card (Strawberr y Tree )

ANALYZER S Channe l 2 : Metho d Analyze r Mak e 8

< Mode l Ful l Scal e Output , m v Spa n Concentration , pp m Channe l 3 : Metho d Analyze r Mak e 8

< Mode l Ful l Scal e Output , m v Spa n Concentration , pp m - TH C

25 A Teco5 1 1000 0 100 0 TH C 25 A Teco5 1 1000 0 100 0

C-3 1


# 7 7 

# —\sspnfl
-rcun i Clien tHenderson , Blac k -i t Green e Projec tNo . i i 665-002-0 0 i Sourc e Styren e Conversio n Analys tRobert s Dat e Feb 20 , i99 7 TH C Tim e m vpp m Startin g tim e i3:i2 ; i-minut e dat a averagin g perio d zer o ai r i 3 : i 3 -i 6 0. 0 i 3 : i 4 -i 6 0. 0 Styren e Convers i

• •••.•I t .•'!.• • .•**.• • 1 i W i >^ V - ^ i * - ^.^.a i i 3 : 2 i 2i 2 22. i 1 3 : 2 2 2i 2 22. i 

# £iiE^ n 

# -i^—

t M ^ MAk- (

Ru n Averages : i3:i 2 t o ij:2 4 i3 5 i4. 7

9^»vo . a.*

i f*op&>ne . ~ <3-S>-. ) o p m A. S <LcLt\>ct\

~<PS«

\ >^>3
—L_olff,2>



### o.m a ^ ^- ^ n- c J te c boo

> -ret^o*=<e

. 4odro r

^ tf 

### y T.«v j o ,',•"• * /"-J"

—"Z-T- . . 

### • 4*2- ^ ^ ^ f 

### ^f~^f , oti* i r ")(~~f Pf~(*r

C-32

"7C > WHUJ "P.8 0

CHLIBRHTIO N 

### DAT A Numbe r i Startin g Tim e 12:5 2 Clien t Henderson , Blac k i t Green e Projec t No . i i 655-002-0 0 i Sourc e Styren e Conversio n Analys t Robert s Dat e Feb 20 , iS3 7 Analyze r TH C netho d 25 A Spa n Conc . iO O pp m

*.er o Kesuit , m

v -i b Spa n # i Conc . 25 9 pp m L«y i • i u c c iOli'-j'-T'- f Resuit , m

v 265 4 Spa n # 2 Conc . 45 4 pp m Cyl . I D ccii205 6 Result , m

v 472 6 spa n -ff

j L>onc
. *3ta»%j

s pp m Cyl
. I D cci0967 9 Result , m

v 363 i

Calibratio n i_urv e coefficient s Slop e i0.3 4 Intercep t

-i6. 0 Cor r Coef f N/ A

Recalculate d Concentration s an d Calibratio n trro r

Erro r use s valu e

pp m '/.err Zer o M/ H Spa n -S i 23 5 -0. 3 Spa n 7.2 45 9 i. O Spa n # 3 M/ H



# "> 1 C-3 3P.8 1



## HARDWAR E xMrDRMATxO M Clien t Henderson , Blac k i* * Green e Projec t No . i iSS5-002-00 i Sourc e Styren e Conversio n Analys t Robert s Dat e Feb

20 , i99 7 Analo g inpu t aevice : HCj r Hnaio g car o » . at r a w o err y iree ;

HNHL.Tl.fcK a unanne i i : m c rietho d 25 A Analyze rHak e i_ riode i TEC O 5 i Ful i Scai e Output , m v iOOO

O Spa n Concentration , pp m iO O

C-3 4
Y W i «jTA

» mMM ST I %Q wwKWi "P.8 3



## APPENDI X D FIEL D DAT A - MIXIN G ROO M VEN T

K M 1665\MZ\001\REPORT.DO C 7 Muc h 199 7 8:0 0 A M Versio n 

### %~L~

### TH C a s Styren e Emission s P.8 4

Combine d Coolin g Ven t Proces s Input , l

b prepare dpolymer/h

r Proces s Input , I

b styFene/h

r Ave
. Emission Rate , lb/h

r a s styrene * Ave
. Emissio

n Rate , l b styrene/lb prepare d polyme r input ' Ave
. Emissior

i Rate , l b styrene/lb styrene input 1 0.1 0 Vent
I'r-te'- 1 Mi i uriir ; *

- V.tf • , -*;i- i „ t . i j___l,i_i

"<*i • • :j*^V**.';-,. i • • v*.

. - . ••*!'* , , ' , TM , *(i,]'*T."i'H'*T*

. Spinnin g Machin e 'If^in^Roiiin 1 ' '"^f;y ^

r,!-.-*>,.;': . . •?••• . .•:•:*«*,• ! :s«v**.i'*> v

: **1SS73^'' : : ; *;^;^,;.n-*;;***,»S:t: : . ffi**i^ r «~ii'*% ,v

- „,STbtal.'" . £' . ^%*i-'«:* , :r . "v«08i8 5 

### •.-po6a2 v

: -*'*i,*S.r:* : "^ii.;' ^ •:.:^69*" ' 3.73E-0 2 "Tim e weightedaverage .

K:\1 1665UXH\001\MRV02.XL S 

# r

> D- 1 Prima d on : 3/7/9 7 3:4 7 A MP.8 5

TH C EMISSION CALCULATION S

Client : Location : Westo n W.O
. No. : Sourc e Code :

1 2/4/9 7 065 7 113 0 1.5 1 E+04 0.01 5 HB&

G Troy , A L 11665-002-00 1 Mixing Roo

mVen t

2 2/4/9 7 120 0 153 0 1.47E+0 4 0.02 2 Averag e

1.49E+0 4 0.01 2 0.14 2 0.14 2 0.14 2 Ru n Numbe r Dat e Tim e Bega n Tim e Ende d Volumetri c Flo w Rate , dscfm*' b Moistur e (Bws ) Respons e Factor , (Styrene/Carbon ) Tota l Hydrocarbo n Concentration , pp mwet

a s propane Concentration , ppmdr

y a s propan e Molecula r Weigh t o f C , ug/ug-mol e Concentration , pp mdr

y a s C c Emissio n Rate , lb/h

r a s C c Styren e Molecula r Weigh t o f styrene , ug/ug-mol e Concentration , ppmdr

y a s styrenec- d Emissio n Rate , lb/h

r a s styrene 0

' Ru n 1 VF Rfromaverag e o f

Run s 1 an

d 2 o f velocit y travers e data
. b Ru n 2 VF RfromRu

n 3 o f velocit y travers e data
. 'Tim e weighted average . dStyren e concentratio n calculate d using th e measure d THC respons e factor o f lpp mC=0.14 2 pp

mstyrene . 70. 3 71. 4 12.0 1 214. 1 6.03 4 104.1 4 30.4 0 7.43 0 75. 0

76. 7 12.0 1 230. 1 6.31 5 104.1 4 32.6 7 7.77 6 72. 7

74. 0 12.0 1 221. 1 6.15 7 104.1 4 31.3 9 7.58 1

K:\l l 665\O02\OO 1 \MRV02 . XL S 

# ?* ? Printe d on : Hni&l 3 : 3 0 A MP.8 6
EMISSIO N CALCULATION S

Ru n Numbe r Date Tim e Bega n Tim e Ende d Styren e Molecula r Weight , jig/ng-mol e Correcte d Sampl e Volume , L Mas s o f Sample , |i g Concentration , ppm Toluen e Molecula r Weight , |ig/ng-mol e Correcte d Sampl e Volume , L Mas s o f Sample , n g Concentration , pp

m

. Xylene s Molecula r Weight , ng/jig-mol e Corrected Sampl e Volume , L Mas s o f Sample , n g Concentration , pp

m Client :

Location : Westo n W.O . No. :

Source :

1 2/4/9 7 084 6 094 6

104.1 4 12.0 3 130 0 24. 9
92.1 0 12.0 3 34. 0 0. 7
106.2 0 12.0 3 16. 0 0.30 1 HB& G

Troy , A L 11665-002-00 1 Mbcin g Room Ven t

2 2/4/9 7 125 0 135 0

104.1 4 12.0 6 96 0 18. 4
92.1 0 12.0 6 71. 0 1. 5
106.2 0 12.0 6 13. 0 0.24 4 Sampl e volum e equivalen to f styrene , % 9 6 9 1

K--.1166S\0O2\0Ol\MRVO2.XL S 

# tt D- 3 Printe d on : 3/7/9 7 3:3 4 A MP.8 7 

## VELOCITY TRAVERS E DA' A
CUEN T H(*^r^ > SOURC E t&*rj*2>**iEJ

frtngt / PITO T TUB E I D NO . PbH STAC KDIAM . (to ) WOR

KORDE RHO . WIPLPS-OOZ-OO N ^.7 5 STAC K ARE A ((rt PTTO T TUBE COEFHCEf

r ».r± THERMO/LO ) P NOS , J&2L&L SKETC H

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### Pag e o

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# w D-H

### MOISTUR E I N STAC K GA S B Y WE T BUL B - DRY BUL B MEASUREMEN T PLAN T l^fo^ o STAC K rvrr-gA / OPERATO RTutt LOCATIO N Tro-^A L RU N I . Z , S DAT E Zr^-^.1

Barometri c Pressur e (Hg ) Static Pressur

e (i n HjO ) Absolut e Pressur e o f Stac k 13. 6 We tBul b Temperatur

e (°F) Dr y Bul b Temperatur

e (T ) Tem p Differenc

e (T d -T w) Vapo r Pressur e o f H2 O a tT w Partia l Pressur e of H, 0 • P P
PP = ( VP) - (P, - KP ) (At ) 280 0 - (1.3 ) <JJ
P P = ( ) ( ) ( )

280 0 - (U ) (T. ) Moisture by volume = M M {PP 

### C

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-inHg 

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# IB R tXlENEKAOAElMNPOftl*XAft-*.rft M * W WKMWiCIXfcj H 

# * 1 D- 5P.8 9 

### PRELIMINAR

Y VELOCITY DAT A •TMEN T Ufe

. o-r o SOURCE ^

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# & r D- 6P.9 0
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" * * /



### SAMPL E FLO W FIEL D DAT A Clien t HB*Gi Locatio n /V/>/ ^

TAVK 

### fitf* \Jc<_l W.O. # Sourc e Cod e Tes t Personne l -

J v v/ u R
Dat e Tim e Bega n Tim e En d Sampl e Tim e (min. ) Barometri c Pressur e (i n H g ) Ambien t Temp. ( F ) Initia l Flo w Rat e ( mL/min. ) Fina l Flo w Rat e (mL/min. ) Mea n Ro w Rat e (mL/min. ) Adsorptio n Tub e l.D .
• Calculate d Dat a Sampl e Volum e ( L ) Corr . Sampl e Volum e ( L ) Calculatio n Vst d

Note s Ru n 1 Ru n 2 Ru n 3

P b T a 

### ft\2>
"«f\ / , , 2/y/7 7 

### 6Wb 0?</f e 0>O 30.0 0 C?2 ao o zoo sao 

# shhi

I2SO 0 5i> 

### CO 30.06 

### 72 SOO QO</ 30Q. c-fisaa' t K * ^77 - • i :\\\9

• \ Dup .

• • "

. . » -• *

- ••''••.£* . -.. ,• ' ;<»p. 3 CG155S

4 ctk ft/7S r CQSV7-

V

V a Vst d /2.0O 

## /a.oi' /D./Q

/

' /3.c(t y V a x P b x 528 R 29.9 2 x (46 0 + Ta )

^ D- 7P.9 2



## APPENDI X E LABORATOR

Y DAT A

KA I 1665V002\001\R£FORT.OO C 7 Mmf a 199 7 8:0 0 A M Versio n %P.9 3 

# Inter-Office Memorandum

MANAGER S "V^^ X DESIGNERS •CONSULTANTS 

## Auburn Operations

FROM : Bria

n Benson TO : Gre g Sim s * * 

### DATE : 1 1 Februar y 199 7 cc : fil e PROJECT : Henderson , Blac k & Green W.O
. NO. : 11665-002-00 1 SUBJECT : NIOS H 150 1 Sampl e Analysi s Result s ACTION : Analysi s of

Sample s Receive do n 0 5 Februar y 1997
. RESULT S AN

D DISCUSSION : Thi s lette r wit h attachment s constitute s ou r repor t ofth e air sample s submitte dto the laborator y fo r aromati c hydrocarbon s analysis
. Th e sample s were receive di n goodconditio n an

din accordanc e wit h the chain-of-custody
. Th

e analysi s wa s performe dfollowing NIOS H Referenc e Metho d 1501
. Th e charcoa

l tub e sample s wer

e prepare db y separatin g th e fron t an dbac k portion s o f eac h charcoa l tub e int o afive millilite

r via l an ddesorbin g eac h wit

h fou r milliliter s o f

carbon disulfide
. Th e sample s wer

e allowe dt

o desor b ove r night i n afreezer
. A on

e millilite r aliquo t fromeach sampl e wa s the n placedinto atw o millilite r autosample

r via l andanalyzedusing ga s chromatograph y (GC ) wit h aFlam e Ionizatio n Detecto

r (FID)
. Th e impinge

r sample s wer

e prepare dby first

measuring the methylene chloride fractio n by pourin g th e entire content s int o afift y millilite r graduate d cylinde r an drecordin g th

e methylen

e chloride volume
. A on

e millilite r aliquo t fromeach sampl e wa s the n placedint

o atw o millilite

r autosample

r via l andanalyzedb

y G C widi aFID
. QUALIT Y ASSURANC

E AN D QUALIT

Y CONTROL : Qualit y contro l procedure s conforme dt o th e referenc e metho dan

dou r laborator y qualit y assuranc e plan
. Calibratio n Curv e Verification(CCV ) Standard s wer e analyzedbefor

e andafte r th e analytica

l sequenc e an

dwer e within the Percen

t Differenc e Acceptanc e Criterion o f ± 1 5 percent . Replicat e analyse s wa s performe

don on e sample
. Th e Percen t Difference Acceptanc e Criterio n i s ± 1 0 percent . Al

l ofth e targe

t compound s detecte dha

dpercentag e difference s les s tha n on e percent . Substantiating datai s on file an davailabl e upo n request . r r

K '.CHE M LABV'WORDVCHE

M LABXG

C LTRS\HBG2_ 7 DO C 

# VE- 1P.9 4

Clien t WESTO N W.O . # Dat e Received Analys t Detection Limi

t(ng/mL ) Henderson , Bloc k & Gree n 11665-002-00 1 5 Februar y 199 7 B . Benso n 1. 5 Aubur n Ai r Qualit

y & Industria

l Hygien e Laborator

y 

### Analysi s Repor t fo r Aromati c Hydrocarbon s b y NIOS H 1501 .

Sourc e I D Vol . (mL ) Sampl

e I D Styren

e Oig/rnL ) Styren

e (Hg/Section

) Styren

e (|ig/Sample )
SMCH O RUN1

SMCH O RU N2

MTR V RUN1

MTR V RU N2

FIEL D BLANK 1 0 4 4 1 2 4 4 6 4 4 8 4
' 4 1 4 4 4 CQ5558. I

CQ5558 F CQ5558 B CQ5554 I CQ555 4 F CQ555 4 B CQ5556 I CQ5556 F CQ555 6 B CQ547 7 I CQ547 7 F CQ547 7 B CQ555 7 I CQ555 7 F CQ555 7 B 15.

5 2561. 8 0. 0 19. 3 1932. 4 15.0 16.0 310. 8 0. 0 6. 5 226. 1 0. 0 0. 0 0. 0 0. 0 154.7

10247. 3 <1. 0 232. 1 7729. 8 59. 9 95. 7 1243.3 <1. 0 51. 7 904. 3 <1. 0 <2 1 <1. 0 <1. 0 10000

800 0

1300

96 0

<2 1

k:.che mlab\i-cWoc\air\HBG2_7.XL S Ai r Report Pa B e I 

### on<c 

# l3 E- 2 Printed on : 2/11/9 7P.9 5

Clien t WESTO N W.O . # Date Receive d Analys t Detectio n Limit(jig/mL ) Aubur n Ai r Qualit

y & Industria

l Hygien e Laborator

y 

### Analysi s Report fo r Aromati c Hydrocaibon s b y NIOS H I S O I . Henderson , Bloc k & Gr

e 11665-002-00 1 5 Februar y 199 7 B . Benso n 1.5

Sourc e ID Vo L (mL ) Samplel D Toluen e (ug/mL ) Toluen e

(Hg/Section ) Toluen e

(Hg/Sample )
SMCH O RUN 1

SMCH O RU

N 2

MTR V RU N 1

MTR V RUN 2

FIEL D BLAN K 1 0 4 4 1 2 4 4 6 4 4 8 4 4 1 4 4 4 CQ555 8 I

CQ555 8 F CQ555 8 B CQ555 4 I CQ555 4 F CQ555 4 B CQ555 6 I CQ555 6 F CQ555 6 B CQ547 7 I CQ547 7 F CQ547 7 B CQ555 7 I CQ555 7 F CQ555 7 B 0. 0 14. 0 0. 0 0. 0 10. 4 0. 0 0. 0 8. 6 0. 0 0. 0 17. 8 0. 0 0. 0 0. 0 0. 0 <1 5

56. 2 <1. 0 <1 8 41. 8 <1. 0
< 9 34. 3 <1. 0 <1 2 71. 2 <1. 0 <1. 0 <1. 0 <1. 0 5

6

4 2

3 4

7 1

<1. 0

k:\chei n JabNgc\voc\airiHBG2_7.XL S Ai r Repo n Pag e 2 o f 1 0 E- 3 Printe d on : 2/11/9 7P.9 6

Aubum Ai r Quality & Industria l Hygien e Laborator

y 

### Analysi s Repor t fo r Aromati c Hydrocaibon s b y NIOS H ISOl . Clien t WESTO N W.O . # Dat e Receive d Analys t Detectio n Limi t(ng/mL )

, ~ Vo1
- Sourc e ID .. . •: . (mL )
SMCH O RUN l 1 0

• 1

•I • 1 X SMCH O RUN 2 1 2

MTR V RU N 1

MTR V RU N 2

FIEL D BLAN K 4 4 6 4 4 8 4 4 4 4 4 Henderson , Bloc k & Gr e 11665-002-00 1 5 Februar

y 199 7 B . Benso n 1. 5
Samplel D
CQ555 8 I CQ555 8 F CQ555 8 B CQ555 4 I CQ555 4 F CQ555 4 B CQ555 6 I CQ555 6 F CQ555 6 B CQ547 7 I CQ547 7 F CQ547 7 B CQ555 7 I CQ555 7 F

- CQ5557 B Ethylbenzen e (Ug/mL ) 0. 0 13. 1 0. 0 0. 0 8.0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 Ethylbenzen e

(Hg/Section ) <1 5 52. 4 <1. 0 <1 8 32. 1 <1. 0
< 9 <1. 0 <1. 0 <1 2 <1. 0 <1. 0 <2 1 <1. 0 <1. 0 Ethylbenzen e

(fig/Sample ) 52

3 2

< 9

<1 2

<2 1

k : chein_laW|jc\voc'air\HBG2_7.XL S Ai r Repo n Pag e 3 o f 1 0



# K E- 4 Printe d on : 2/11/9 7P.9 7

Aubur n Ai r Qualit

y & Industria

l Hygien e Laborator

y 

### Analysi s Repor t fo r Aromati c Hydrocaibon s b y NIOS H ISOl . Clien t WESTO N W.O . # Dat e Receive d Analys t Detectio n Limi t(ng/mL )
Vol . Sourc e ID , . . (mL ) SMCH O RUN 1 I

- .
SMCH O RU N 2 1

MTR V RU N 1

MTR V RU N 2

FIEL D BLAN K 0 4 4 2 4 4 6 4 4 8 4 4 1 4 4 4 Henderson , Bloc k & Gr e 11665-002-00 1 5 Februar y 199 7 B . Benso n 1. 5
Sampl e I D
CQ555 8 I CQ555 8 F CQ555 8 B CQ555 4 I CQ555 4 F CQ555 4 B

. * CQ5556 1 CQ555 6 F CQ555 6 B CQ547 7 I CQ547 7 F CQ547 7 B CQ555 7 1 CQ555 7 F CQ555 7 B Xylene s

(}ig/mL ) 0. 0 38. 8 0. 0 0. 0 28. 7 0. 0 0. 0 4. 0 0. 0 0. 0 3. 2 0. 0 0. 0 0. 0 0. 0 Xylene s

(Hg/Section ) <1 5 155. 3 <1. 0 <1 8 114. 9 <1. 0
< 9 15. 8 <1. 0 <1 2 12. 8 <1. 0 <2 1 <1. 0 <1. 0 Xylene s

(Hg/Sample ) 16 0

11 0

1 6

1 3

<2 1

k:,cliernJab\gcwoc\air\HBG2_7.XL S Ai r Repo n Pag e 4 o f 1 0 E- 5 Printed on : 2/11/9 7P.9 8

Aubur n Ai r Qualit

y & Industria

l Hygien e Laborator

y 

### Analysi s Repor t fo r Aromati c Hydrocarbon s b y NIOS H I S O I . Clien t WESTO N W.O . # Dat e Receive d Analys t Detectio n Limi t(jig/mL )
Vol. . Sourc e I D .. . (mL ) SMCH O RU N 1 1 0 4 4 SMCH O RU N 2 1

MTR V RU N 1

MTR V RU N 2

FIEL D BLAN K 2

4 4 6 4 4 8 4 4 1 4 4 4 Henderson

, Block & Gr

e 11665-002-00 1 5 Februar y 199 7 B . Benso n 1. 5
Sampl e I D CQ555 8 I CQ555 8 F CQ555 8 B CQ5554 1 CQ5554 F CQ555 4 B CQ555 6 1 CQ555 6 F CQ555 6 B CQ547 7 I CQ547 7 F CQ547 7 B CQ555 7 I CQ555 7 F CQ555 7 B Cumen

e (Ug/mL ) 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 Cumen

e (|ig/Section ) <1 5 <1. 0 <1. 0 <1 8 <1. 0 <1. 0
< 9 <1. 0 <1. 0 <1 2 <1. 0 <1. 0 <2 1 <1. 0 <1. 0 Cumen

e (ug/Sample ) <1 5

<1 8

< 9

<1 2

<2 1

k:'.cliem_labvgcwoc\air\HBG2_7.XL S Ai r Repo n Pag e 5 o f 1 0 

# 91 E- 6 Printed on : 2/1U9 7P.9 9

Aubur n Ai r Qualit

y &. Industria

l Hygien e Laborator

y 

### Analysi s Repor t fo r Aromati c Hydrocarbon s by NIOS H ISOl . Clien t WESTO N W.O . # Dat e Receive d Analys t Detectio n Limi t(ng/mL )
Vol . Sourc e ID * ; , . (mL ) SMCH O RU N 1 1 0 4 4 SMCH O RU N 2 1

MTR V RUN 1

MTR V RU N 2

FIELD BLAN K 2 4 4 6 4 4 8 4 4 1 4 4 4 Henderson , Bloc k & Gr e 11665-002-00 1 5 Februar

y 199 7 B . Benso n 1.5
Samplel D
CQ555 8 1 CQ555 8 F CQ555 8 B CQ555 4 I CQ5554 F CQ555 4 B CQ555 6 I CQ5556 F CQ555 6 B CQ547 7 I CQ547 7 F CQ547 7 B CQ555 7 I CQ555 7 F CQ555 7 B Benzen e

(Ug/mL )
0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 Benzen e

(jig/Section )
<1 5 <I. O <1. 0 <1 8 <1. 0 <1. 0
< 9 <1. 0 <1. 0 <1 2 <1. 0 <1. 0 <2 1 <1. 0 <1. 0 Benzen e

(Hg/Sample ) <1 5

<1 8

< 9

<1 2

<2 1

k : chein_lab\|!cwoc\air\HBG2_7.XL S Ai r Repo n Pag e 6 o f 1 0 E- 7 Prime d on : 2/11/° 7P.10 0

Aubur n Ai r Qualit

y & Industria

l Hygien e Laborator

y 

### Analysi s Report fo r Aromati c Hydrocarbon s by NIOS H ISOl . Clien t WESTO N W.O . # Dat e Receive d Analys t Detectio n Limi t(ng/mL )
Vo l SourceI D fnr ^ \ut SMCH O RU N 1 1 0 "

SMCH O RU N 2 1

MTR V RU N 1

MTR V RU N 2

FIELD BLAN K 4 4 2 4 4 6 4 4 8 4 4 1 4 4 4 Henderson , Bloc k & Gr e 11665-002-00 1 5 Februar

y 199 7 B . Benso n 1. 5
Sampl e I D
CQ555 8 I CQ5558 F CQ555 8 B CQ555 4 I CQ555 4 F CQ555 4 B CQ555 6 I CQ555 6 F CQ555 6 B CQ547 7 I CQ547 7 F CQ547 7 B CQ555 7 I CQ555 7 F CQ5557 B a-methyl

Styrene (Ug/mL ) 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 a-methy l

Styren e (Hg/Section ) <1 5 <1. 0 <1. 0 <1 8 <1. 0 <1. 0
< 9 <1. 0 <1. 0 <1 2 <1. 0 <1. 0 <2 1 <1. 0 < 1. 0 a-methy l

Styren e (Hg/Sample ) <1 5

<1 8

< 9

<1 2

<2 1

k : chemJab\gcwoc\air\HBG2_7.XL S Ai r Repo n Pag e 7 o f 1 0 

## ?9 E- 8 Printed on : 2/11/9 7p. 1

Aubu m Ai r Qualit

y 4 Industria

l Hygien e Laborator

y 

### Analysi s Repor t fo r Aromati c Hydrocarbon s b y NIOS H 1301 . Clien t WESTO N W.O . # Dat e Receive d Analys t Detectio n Limi t(|ig/mL )
Vol . Sourc e I D , , . (mL ) SMCHO RU N 1 1

SMCHO RU N 2

MTR V RU N 1

MTR V RUN 2

FIEL D BLAN K 0 4 4 2 4 4 6 4 4 S 4 4 1 4 4 4 Henderson , Bloc k & Gr e 11665-002-00 1 5 Februar

y 199 7 B . Benso n 1.5
Sampl e I

D
CQ555 8 1 CQ555 8 F CQ555 8 B CQ555 4 I CQ555 4 F CQ555 4 B CQ555 6 I CQ555 6 F CQ555 6 B CQ547 7 I CQ547 7 F CQ547 7 B CQ555 7 I CQ555 7 F CQ555 7 B butyl-Toluen e

:(Hg/mL )
0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 butyl-Toluen e (ug/Section )
<1 5 <1. 0 <1. 0 <1 8 <L 0 <1. 0
< 9 <1. 0 <1. 0 <1 2 <1. 0 <1. 0 <2 1 <1. 0 <1. 0 butyl-Toluen e

(fig/Sample )
<1 5

<1 8

< 9

<1 2

<2 1

k:*.chemJab\| , c'.voc\air'iHBG2_7.XL S Ai r Repo n Pag e 8 o f 1 0 

### (00 E- 9 Printed on : 2/11/0 7P. 2

Aubur n Ai r Qualit

y & Industria

l Hygien e Laboratoiy 

### Analysi s Report fo r Aromati c Hydrocarbon s b y NIOS H 1501 . Clien t WESTO N W.O . # Date Receive d Analys t Detectio n Limit(fig/mL ) Henderson , Bloc k & Gr e 11665-002-00 1 5 Februar

y 199 7 B . Benso n 1. 5
*-*v- - ..•vol:* ' Sourc e I D •-••/•,* , (mL ) Sampl e I D
SMCH O RU

N 1 1 0 CQ5558 I

•
SMCH O RU

N 2 1

MTR V RU N 1

MTR V RU N 2

FIEL D BLAN K \ CQ555 8 F 4 CQ555 8 B 2 CQ5554 1 4 CQ555 4 F 4 CQ555 4 B 6 J CQ5556 1 4 CQ555 6 F 4 CQ555 6 B 8 CQ5477 1 4 CQ547 7 F 4 CQ547 7 B 1 4 - CQ5557 I 4 CQ555 7 F 4 CQ555 7 B vinyl-Toluen e (Ug/mL ) 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 vinyl-Toluen e

(ug/Section ) <1 5 <1. 0 <1. 0 <1 8 <1. 0 <1. 0
< 9 <1. 0 <1. 0 <1 2 <1. 0 <1. 0 <2 1 <1. 0 <1. 0 vinyl-Toluen e

(Ug/Sample ) <1 5

<1 8

< 9

<1 2

<2 1

k:*«hemJab\uc\vocvair\HBG2_7.XL S Ai r Repo n Pag e 9 o f 1 0 

## /oi E-1 0 Printe d on : 2/11/9 7P. 3

Aubu m Ai r Qualir

y & Industria

l Hygien e Laboraior

y 

### Analysi s Repor t fo r Aromati c Hydrocaitwn s b y NIOS H 1301 . Clien t WESTO N W.O . # Date Receive d Analys t Detectio n Limit(|ig/mL ) Henderson , Bloc k & Gr e 11665-002-00 1 5 Februar

y 199 7 B . Benso n 1. 5
Vol . Sourc e ID , , - , (mL ) Sampl e I D
SMCH O RUN 1 1 0 CQ5558 1

SMCH O RU N 2 1

• MTR V RU N 1

MTR V RUN 2

FIELD BLAN K X CQ555 8 F 4 CQ555 8 B

* 2 CQ5554 1 4 CQ555 4 F 4 CQ555 4 B 6 CQ5556 1 4 CQ555 6 F 4 CQ555 6 B 8 CQ5477 1 4 CQ547 7 F 4 CQ547 7 B 1 4 CQ5557 1 4 CQ555 7 F 4 CQ555 7 B Naphthalen e (jig/mL )

' 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0. 0 0.0 0.0 0.0 0. 0 0. 0 0. 0 0. 0 0.0 Naphthalen e

(ug/Section ) <1 5 <1. 0 <1. 0 <1 8 <1. 0 <1. 0
< 9 <1. 0 <1. 0 <1 2 <1. 0 <1. 0 <2 I <1. 0 <1. 0 Naphthalen e

((ig/Sample ) <1 5

<1 8

< 9

<1 2

<2 1

k:\chemJab\i-c\vocuir\HBG2_7.XL S Ai r Repor t Pag e 1 0 o f 1 0 E-l l Printe d on : 2/11/9 7

## Custod y Transfe r Recor d / La b Servic e Reques t PagcJLof t Client : Hcvderson^Bhck

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## APPENDI X F QUALIT Y CONTRO L DAT A

KA I I665\002VOOI\REPORT.DO C 7 Marc h 199 7 8:0 0 A M Venio nNATIONAL SPECIALT Y CASE S 63 0 UNITE

D DRIV E DURHAM , NC 2771 3 (919)544-377 2 CERTIFICAT E OFANALYSI S * EP A PROTOCO L MIXTURE S REFERENC

E H: EXP . DATE : 88-4844 3 7/18/9 9 . J CYLINDER# :

LAS T ANALYSI S DATE : |C C 10091 4 7/18/9 6 CYL . PRESSURE :

CUSTOMER : 200 0 PSIO P.O . 0 : SOUTHEAS T AIRGAS • 2718 1 METHOD : I993G- I THI S STANDAR D SHOUL D NO T B E USE D WHE N IT S GA S PRESSURE I S BELO W I.O MEGAPASCAL S (IS O PSIG) .

ANALYZE D ACCORDIN G T O EP A TRACEABILIT Y PROTOCO L FO RASSA Y AN D CERTIFICATIO N O F GASEOU S CALIBRATIO N STANDARDS-SEPTEMBE R COMPONENT : STANDAR D SRMS : CYL

. # : CONC : INSTRUMENT : MODEL* : SERIA L #
. LAS T CAL. : MEA N CONC : REPLICAT E CONC

. PROPAN E

I668 B ' , CL M 643 9 : 95. 5 PP M ROSEMOUN T TH C 400 A 200033 5 7/6/9 6 25. 3 PP M +/ - DATE : 7/18/9 6

25. 3 25. 2 25. 3 PP M

PP M PP M i

0.2 0 PP M l

•

., .

1

,

BALANC E GAS : AI

R | REPLICAT E DAT A

T l I REPLICAT E DAT A

DATE : 7/18/9 6 Z 0 | REPLICAT E DAT A

R Z DAT E Z R Z 86. 7 0 R

Z c
R Z C 86. 7 0 23. 0 

### c

c R C C R 23. 0 22. 9 86. 8



# rsz.<&^rtnc,t<iANALYST : TIU S RETOR

T STATE D ACCURATEL

Y TH E RESULT S O f

TH E INVESTIGATIO N CONNECTION WIT

H TIP S RETORT . NATIONAL SPECIALT Y CASE S SHALL

lATKJNMACC U kLLIIAVEJlOL I Z=ZER O C=CANDIDAT E R=REFERENC E APPROVE D BY : UTONTHEMATEMALSUBMITTEOTOTHEANALVTCALlAeaKATtXir . EVER Y EFFOR T HA S UABUTYMEXCESSOrirSESTAIILISIIEOniAKCEfCHIlllESEIIVICE . ASSAYE D AT . NATIONA L BEE N MADOT O DETERMINE OOIECTu/EL ' •.TONA L SJ-ECtALT

Y GASES . * W UNITE D V

Y TI E MFORMAIH N REQUESTED : HOWEVER . I N DRIVE . DURHAM . N T ITTI 1 ftm*u-ll» lNATIONA L SPECIALTY CASE S 63 0 UNITE

D DRIV E DURHAM, N C 2771 3 (919)544-377 2 CERTIFICAT

E O F ANALYSI

S * EP A PROTOCOL MIXTURES REFERENCE* : EXP
. DATE : 88-48442 CYLINDER* : CC5985 5 CYL
. PRESSURE : 7/18/9 9 LAS T ANALYSI S DATE : 7/18/9 6 CUSTOMER : 200 0 PSI G P.O.» : SOUTHEAS T AIRGA

S 2718 1 METHOD : ANALYZE D ACCORDIN

G T O EP A TRACEABILIT

Y PROTOCO

L FO RASSA Y AND CERTIFICATION O F GASEOU S CALIBRATION STANDARDS-SEPTEMBE R I993:G- I THI S STANDAR D SHOUL D NO T B E USE

D WHE N IT S OA S PRESSUR

E I S BELO

W I. O MEGAPASCALS (15 0 PSIG)
. COMPONENT : STANDAR

D SRM# : CYL.* : CONC : INSTRUMENT : MODE L # : SERIAL* : LAS T CAL. : PROPAN E I668 B CL M 643 9 95. 5 PP M ROSEMOUN

T TH C 400 A 200033 5 7/6/9 6 MEA N CONC : REPLICAT

E CONC
. DATE : 7/18/9 6

43. 5 PP M 43. 4 PP

M 43. 5 PP M 43. 5 PP M +/

- 0.3 5 PP M

BALANC E GAS : AI

R REPLICAT E DAT A DATE : 7/18/9 6 Z 0 R R 86. 7 Z REPLICAT E DAT A | REPLICAT E DAT A 86. 7 0 39. 5 C

C

C C 39. 5 39. 4 86. 8

• n I ANALYS T 

# „^S^ % Z=ZER O C=CANDIDAT E R=REFERENCE APPROVE

D BY : THI S RETORT STATE D ACCURATEL Y TH E RESULT S O F TH E INVESTIGATIO N MAD E UPO N CONNECTIO N WIT H THI S RETORT . NATIONA L SPECIALT Y GASE S SHAU . H A V E N O U i I ATERIA L SUBMITTE D T O TH E ANALYTICA L LABORATORY . EVER Y EFFOR T HA S BEE N I N EXCES S O F rT S ESTABLISHE D CHARG E FO RTH E SERVICE . ASSAYE D AT : NATIONA L 

# Q 

# Sm
DETERMIN E OBfecT I IALTY OASES . « 0 UNITE D TH E INFORMATIO N REQUESTED : HOWEVER . I N UVB . DURHAM . N C 1T7II . (tll)S4«-377 1

*" • 0 0NATIONA L SPECIALT Y GASE S 63 0 UNITE D DRIV E DURHAM , N C 2771 3 (919)544-377 2 CERTIFICAT E OFANALYSI S ' EP A PROTOCO L MIXTURE S REFERENCE* : EXP. DAT E 88-4844 1 CYLINDER* : C C 1673 1 CYL . PRESSURE : 7/18/9 9 LAS T ANALYSIS DATE : 7/18/ % CUSTOMER : 200 0 PSIO P.O.* : SOUTHEAS T A1RGA S 2718 1

O

• n METHOD : ANALYZE D ACCORDIN G T O EP A TRACEABILITY PROTOCOL FO RASSA Y AN D CERTIFICATIO N O F GASEOU S CALIBRATIO N STANDARDS-SEPTEMBE R 1993:G- 1 THI S STANDAR D SHOUL D NO T B E USE D WHE N IT S GA S PRESSUR

E IS BELO

W 1. 0 MEGAPASCAL S (15 0 PSIG) . COMPONENT : STANDAR D SRM# : CYL . # : CONC : INSTRUMENT : MODEL* : SERIAL* : LAS T CAL. : MEA N CONC : REPLICAT

E CON C PROPANE

I668 B CLM 643 9 95. 5 PP M
ROSEMOUN T TH C 400 A 200033 5 7/6/9 6 92. 6 PP

M +/ - 0.7 4 PP M
DATE : 7/18/9 6

92. 6 92. 7 92. 6 PP

M PP M PP M 1 i 1 ! 

# 1
1
t 1 a

BALANC E GAS : AI

R REPLICAT E DAT A DATE : Z 1 R Z DAT E Z R Z 7/18/9 6 0 86. 7 0 R

Z 

### c R Z C 86. 7 0 84. 2 C

C R C C R 84. 1 84. 2 86. 8 | REPLICAT E DAT A

• 1 

# i | REPLICAT E DAT A

1CCURATEL

Y TH E RESULT

S O F TH E MVESTIGATION

M Z=ZER O ^CANDIDAT E R-REFERENC E : APPROVE D BY : ANALYST : THI S RETOR T HATE D ACCURATEL

Y TKERESULl

i C #TH E MVESTIGATKI N MADEJUFO N TH E MATERIA

L SUBMITTE

D T D TK E ANALYTICA

L LABORATORY

. EVER Y EFFOR T HA S BEE N MAD E TODtTtRMlK

E OBJECTIVEL

Y lll E D*ORMAHO

N REQUESTED: HOW

E VER. W coxwrno N WIT H na s RETORT , NATIOHA L SFECIUT Y GASE S SHAL L HAV E NtpjABaiTY M EXCES S O F mESTABUSHEOouR a FO RHI E SERVIC E ASSAYE D A T NATIONA L SFECMLT Y GASES . MIMIEDDRA'E.DURHAM.N C mil . mnm-nn 

## AWxs Q>Sm

C ONATIONA L SPECIALT Y GASE S 63 0 UNITE D DRIV E DURHAM , N C 2771 3 (919)544-377 2 CERTIFICAT E O F ANALYSI S * EP A PROTOCO L MIXTURE S REFERENCE* : EXP. DATE : 88-4844 4 7/18/9 9 CYLINDER* :

LAS T ANALYSI S DATE : C C 10984 4 7/18/9 6 CYL . PRESSURE :

CUSTOMER : 200 0 PSIG P.O.« : SOUTHEAS T AIRGA S 2718 1

^

- ^ METHOD : ANALYZE D ACCORDIN G T O EPA TRACEABILIT Y PROTOCO L FORASSA Y AN D CERTIFICATIO N O F GASEOU S CAUBRATIO N STANDARDS-SEPTEMBE R

I993:G- 1 THI S STANDAR D SHOUL D NO T B E USE D WHE N IT S GA S PRESSUR E I S BELOW 1. 0 MEGAPASCAL S (15 0 PSIO) . COMPONENT : STANDAR D SRM# : CYL.« : CONC : INSTRUMENT : MODEL* : SERIAL* : LAS T CAL. : MEA N CONC : REPUCATECON C PROPAN E 1 | 1669 B CLM 78 9 J 46 4 PP M i
ROSEMOUN T TH C 400 A 200033 5 7/6/9 6 ..... . j 25 9 PP M +/ - 2.0 7 PP M
DATE : 7/18/9 6

25 9 25 9 25 8 PP

M PP M PP M BALANC E GAS : AI R



### • n I REPLICAT

E DAT A DATE : 7/18/96 | REPLICAT E DAT A | REPLICATE DAT A
Z R Z DAT E Z R Z 0 42. 3 0 R

Z c
R Z c 42. 3 0 23. 6 

### c

c R C C R 23. 6 23. 6 42. 4 l

"^ '*< — Z-ZER O C*=CANDIDAT E R-REFERENC E APPROVE D BY : 

# ytem. 0- Sfofat TH U RETOR T STATO ZSifeC'rcEYTiEReuL ^ Bva»£FiwTiusbwMAD^nnw»qi«oa i CONNECTIO N WII H TW S REPCRT . NATIONA L SFEOALT Y GASE S SHAL L HAV E NO/IABIUT Y M 4 EXCES S O T R S ESTABLISHE D CHARG E FO RTH E SEKVKZ . ASSAYE D AT : NATIONA L .T V OASES . < M " TH E INFORMATIO N REQUESTED : HOWEVER . W DRIVE . DURHAM . N C mil . (imSM-IT ONATIONA L SPECIALT

Y GASE S 63 0 UNITE

D DRIV E DURHAM, N C 2771 3 (919)544-3772 CERTIFICAT E O F ANALYSI S * EPA PROTOCO L MIXTURE S REFERENCE* : EXP . DATE : 88-4844 5 CYLINDER* : C C 11208 6 CYL . PRESSURE :

7/18/9 9 US T ANALYSIS DATE : 7/18/9 6 CUSTOMER : 200 0 PSIO P.O.* : SOUTHEAS T AIRGA S 2718 1

o ••-• • METHOD : ANALYZE D ACCORDIN G T O EP A TRACEABILIT Y PROTOCO L FO RASSA Y AN D CERTIFICATIO N O F GASEOU S CALIBRATIO N STANDARDS-SEPTEMBE R 1993:0- 1 THI S STANDAR D SHOUL D NO T B E USE D WHE N IT S GA S PRESSUR

E I S BELOW 1. 0 MEGAPASCAL S (IS O PSIG) .

BALANC E GAS : AI R | REPLICAT E DAT A | REPLICAT E DAT A

I u i REPLICAT E DAT A

DATE : 7/18/9 6 Z R Z DATE Z R Z 0 42. 3 0 R

Z c 42. 3 0 41. 5 C

C R 41. 4 41. 5 42. 4

ANALYST : THI S REFOR

T STATE D ACCURATEL Y TK E RESULT S O F TH E 1 1 CONNECTION WII H TH B REFORT . NATIOHA L SFEOALT Y GASE S SHAL L HAV E H O L Z-ZER O OCANDIDAT E R-REFERENC E APPROVE D BY : THE MATERIA L SUBMITTE D T O *H E ANALYTICA L LABORATORY . EVER Y EFFOR T HA S BEE H MAD E D l EXCES S o r n s OTABt__D CHARG E FO RTH E SERVK X ASSAYE D AT : NATIONA L 

### ' / S(UJL TY OASE S (M l t

TH E DCORMATW N REQUESTED : HOWEVER . D « rDRJVt . DURHAM , H C 277I L <Hf04MT nNATIONA L SPECIALT Y GASE S 63 0 UNITE D DRIV E DURHAM , N C 2771 3 (919)544-3772 CERTIFICAT E O F ANALYSIS > EP A PROTOCO L MIXTURE S REFERENCE* : EXP
. DATE : 88-4844 6 CYLINDER* : C C 109679 ' CYL
. PRESSURE : 7/18/9 9 LAST ANALYSI S DATE : 7/18/9 6 CUSTOMER : 2000PSI Q < P.O.* : SOUTHEAS T AIRGA

S 2718 1 METHOD : ANALYZE D ACCORDIN

G T O EP A TRACEABILIT

Y PROTOCO

L FO RASSA Y AN D CERTIFICATION O F GASEOU S CAUBRATIO N STANDARDS-SEPTEMBE R I993:G- 1 THI S STANDAR D SHOUL D NO T B E USE

D WHE N IT S GA S PRESSUR

E I S BELO

W 1.0 MEGAPASCALS (15 0 PSIG)
. COMPONENT : STANDAR

D SRM# : CYL
. * : CONC : INSTRUMENT : MODEL* : SERIAL* : LAS T CAL. : MEA N CONC : REPLICAT

E CON C PROPAN

E I669 B CL M 78 9 464 PP M ROSEMOUN

T TH C 400 A 200033 5 7/6/9 6 93 3 PP

M +/

- DATE : 7/18/9 6

93 3 93 2 93 3 PP

M PP M PP M i

7.4 6 PP M i I

• ' | i i

1

:

BALANC E GAS : AI R

• n I Ot . REPLICAT E DAT A DATE : 7/18/9 6 Z 0 | REPLICAT E DAT A | REPLICAT E DAT A

R Z DAT E Z R Z 42. 3 0 R

Z c 42. 3 0 85. 3 C

C R 85. 1 85. 0 42. 4

ANALYST : THI S REFOR

T STATE D ACCURATEL Y TH E RESULT S O F 1 CONNECTIO N WIT H THI S REFORT . NATIONA L SPECIALT Y CASE S SHAL L HAV E N O LIABILIT Y H Z=ZER O ^CANDIDAT E R-REFERENC E APPROVE D BY : _ _ IA L SUBMITTE D T O TH B ANALYTICA L LABORATORY . EVER Y EFFOR T HA S BEE N MAD B KES S O F n S ESTABUSHE D CHARG E FO RTH E SERVICE . ASSAYE D AT : NATIONA L ECTIVEL/TH E INFORMATIO N REQUESTED . HOWEVER . I N s , DURHAM , M C mn . 0irtu*-im

y i- oP.1 3



# Scott Specialty Gase s 614 1 EASTO NROA D PLUMSTEAOVILL E Phone : 215-766-886 1 P A 18949-031 0 CERTIFICAT E O F P O BO X 31 0 Fax : 215-766-207 0 ANALYSI S 

### RO Y F WESTON , IN C BOBB Y BETT S 163 5 PUMPHRE Y AV E AUBUR N A L 3683 0 PROJEC T # : 01-87056-00 1 PO# : CREDI T CAR D ITE M # : 010425 5 4 DATE : 2/01/9 7

SCOT T LOT# : 70300 6

COMPONEN T STYREN E MONOME R NITROGE N ANALYTICA L ACCURACY : PRODUC T EXPIRATION : REQUESTE D GA S CQN C + -5 % 6/01/199 7 ANALYSI S (MOLES ) 10 . PP M

BALANC E 9.4 3 PP M BALANC E

MANUFACTURE D DATE : 1/30/9 7
ANALYST : SCOTT Y SIZE : 4

•CJ-_\
. s \£<r.- > v o *^_

5 

### A L ROJA S

FREMONT . C

A SA N BERNAROINO . C A LONGMONT . C O CHICAGO . I L WAKEFIELD . M A TROY . M l BREDA . TH E NETHERLAND S p_ 7 DURHAM . N C SOUT H PLAINFIELD . N J SARNIA . ONTARI O PLUMSTEAOVILLE . P A PASADENA . TX SHEFFORD . UNITE D KINGDO M 

### i fP. M



# POST-TES T EQUIPMEN T CALIBRATION S

Clien t MfW o Tes t Tea mLeade r Wor

k Order No.))i*l.$-c?d2-Jo,> Tes t Date s Du e Dat

e Z~)G-7~7 

### 2.-*W 7

Prob e No.
_ Prob e No.
. Prob e No.
. Prob e No
. Pito t Tub e No.
_ Pito t Tub e No.
_ Pito t Tub e No.
_ Pito t Tub e No
. Meter Bo x No.
. Meter Bo x No.
_ Meter Box No.
. Mete r Bo x No
. 

# i m Avg . Stac k Temp. . Avg . Stac k Temp. . Avg . Stac k Temp. . Avg . Stac k Temp. ,

Highes tVacuum . Highes tVacuum . Highes tVacuum . Highes tVacuum . Avg . AH
_ Avg . AH
_ Avg . AH . Avg . AH

_ Singe r DG M No.
_ Singer DG M No.
_ Singe r DG M No.
_ Sinaer DG M No
. Flo w Rat e Flo w Rate
_ Flo w Rat e Flo w Rat e VOS T Box No.
. VOS T Box No
. VOS T Box No.
. VOS T Bo x No
. H H Thennocoupl e No
. )cT?%y H H Thermocouple No
. H H Thennocoupl e No
. H H Thermocouple No
. Flo w Rat e Flo w Rat e Flo w Rate . Flo w Rat e Avg . Temp. . Avg
. Temp. . Avg
. Temp.
. Avg
. Temp.
. 

### 7" Q

Rotamete r No.
. Rotamete r No.
_ Rotamete r No.
. Rotamete r No
.

'.: CE.NERAL , ADMNFORM , TAR-73.FR M TAR-7 3 119 3 

# 11 3

## PITO T TUB E CALIBRATIO N

DAT E 3- i X„ . 9 7 PITO T TUB E I D NO . P&4 PROB E I D NO . ~ PITO T TUB E ASSEMBLY LEVEL ? ^ye s n o PITO T TUB E OPENING S DAMAGED ? ye s •***** - n o PITO T TUB E COEFFICIEN T 0.84 ? ^ye s n o CHECKE D BY / i •AI \ q

lim a 

# -.J£&--®@L.-.

I - T

l« M ••« — H- t 

# '-- E "^ T x : 

# '^^.J^--'

. ^^

_.^fcTl^M*» - fc"*****- - l a 

# c o,- a • (<icn.a , - <g

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### (<sn . P , 

### - _i_ #

### (<s p 7 - J . *

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( (In.) ; <0.03 1 P * 0-3/ 7 (In. ) P

» o-ll! (In.) D,-_4 i 2££_(ln. )



### _ L

" " »«• «

Pao e o

f ).|.MAASMNFO«l«TAIlOaFM « TAXO 0 3V9 1 

# n H » . 80TTW V.Oi . SWMN C HINIIU I PIT0T-WI2 U »«»TI0N . /gw f

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t cv w .i w o

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# S3 C 2 p . £ 

# S D

I I I I HIHIHI-MIIIIII I »«4lM«Ma>|-VllMJ<1*» i
X - . Z - . Y - (ln.);>0.75 0

(In.) ; >2. 0

. (In.) ; >3. 0
POSTTEST CHEC K 

### cnantJOJJ L Wor k Orda r No . u&S&L&QZtZDJDd.

Ffi* S pat . y pr e g? > Damag e Found ?

____

_ya a Chacka d b y _« £ Commant

s tf #• > V f n

o

F- 9P.1 6



### STAC K TEMPERATUR E SENSO R CALIBRATIO NDAT AFORM Reference : Digita l Thermomete r - Wah i Mode l C-6 5 NIS T Thermocoupl e Number : 10788 A

Date : 2 3 MARC H 9 5 Ambien t Temperature , |F : 8 1

Calibrator : LO F Referenc e Poin t Numbe r 1 A B C 2 A B C 3 A B C
Tem p Dif f (% ) Referenc e

Temperature ,

35. 0 35. 0 35. 0 160. 0 159. 0 159. 0 478. 0 478. 0 477. 0

* 

### (Re f Temp , 

## I F

I F Thermocoupl e

Potentiomete r Temperature ,

35. 0 35. 0 35. 0 160. 0 159. 0 159. 0 478. 0 478. 0 478. 0 + 460 ) - (Ther

mPo t Re f Temp , | F + 46 0 F

Temp , Temperatur e

Difference ,

0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.1 1 | F + 460 ) X 1 < Ar e al l temperatur e difference s les s tha n 1. 5 % ? Ye s

Av g Stac k Temp , | F POSTTES T STAC K TEMPERATUR E SENSO R CALIBRATIO NDAT A 

### Client : UBfe6 ~ Wor k Orde r Number : \\c~£.k ~on%.- ftp f Date : 7 FEB3*1 Referenc e Temperatur e

Calibrator : 

### I F Th e rm o c oup1 e

Temperature , | F Temperatur e Difference , 

# 22. 74 

# n Wa s apretes t

temperatur e correctio n used ? T s temperatur e differenc e withi n 1: 5 % ? !fe s 

### X N o 

### No I f no , calculation s don e onc e wit h recorde d value s an d onc e wit h correcte d values .

F-1 0 

# US'P.1 7



### I JL*"". 1 ! T 

# G # 

# ;GILMON T M.* ' INSTRUMENTS . INC . 

### ®

•MEASURE D AN D FLOWIN G A T 1 ATM . AN D 7 0 DEG . F . » . • •



# Correlate d Flow

, Tabl e Flowmete r Cat. No . SIZE : I 

# Seria l Nb . 1030 1 - 1040 0 

# Floa tTyp e GLAS

S $-/ J 

# Flui d Nam e AI

R

SCAL E DIVISIO N 1 2 3 4 5

. !

1 1 1 2 1 3 1 4 1 5

2 1 2 2 2 3 2 4 2 5 FLOW

RAT E ML/MI N 0.78 0 1.0 9 1.4 7 1.9 1 2.4 3
6 ' . 7 8 5* ~ '" •

- 0 3.0 3

3.7 0 4.4 6
" ~ • ; j ~5.30 ' 6.2 3
7.2 6 8.3 7 9.5 9 10. 9 12. 3
1 6 1 7 1 8 1 9 

### IU 13. 8 15. 5 17. 2 .-iy.'- l
• 2i'.' l
23. 3 25. 5 27. 8 30. 0 32. 4 SCAL E

DIVISION 2 6 2 7 2 8 2 9 3 0
3 1 3 2 3 3
3 5
3 6 3 7 3 8 3 9 4 0
4 1 ,4 2 ,-44 2 44 ' 4 5 

# ll

4 6

At . 4 9 5 0 FLOW

RATE ) ML/MI N 34. 8 37. 4 40. 0 42. 6 45. 3
48. 0 50. 8 53. 6

" ~ oc. 5 59. 4

- 62. 3 65. 3 68. 4 71. 5 74. 6
77. 8 81. 0 84. 2 87. 5 90. 8
94. 2 97. 6 10 1 10 4 

### \ 10 8 SCAL E

DIVISIO N 5 1 5 2 5 3 5 4 5 5
5 6 5 7 5 8 "S9 ~ 6 0
61 . 6 2 6 3 6 4 6 5
6 6 6 7 68 . 6 9 7 0
7 1 7 2 7 3 7 4 7 5 FLO W

RAT E ML/MI N 11 1 11 5 11 8 12 2 12 6
12 9 13 3 13 7 14 0 14 4
14 8 15 1 15 5 15 9 16 3
16 7 17 0 _1 7 4 1 7 8 18 2
18 6 19 0 19 3 19 7 20 1 SCAL E DIVISIO N '7 6 7 7 7 8 7 9 8 0
81 8 2 8 3 "8 4 8 5
8 6 8 7 8 8 8 9 9 0
9 1 9 2 9 3 9 4 9 5
9 6 9 7 9 8 9 9 10 0 

# \\L> FLO W RATE I ML/MI N ' 20 5 20 9 21 3 21 7 22 1
22 5 22 9 23 3 23 7 24 1
24 5 "24 9 25 3 25 7 26 1
26 5 26 9 27 4 27 8 28 2
28 6 29 0 29 4 29 8 30 3 F-1 1P.1 8

ATTACHMEN T 3 Report - Emissio n Measurement s GFK-Wer k Meumarkt Firm aPfleidere r

Infrastrukturtechni k



# i nP.1 9



### Dr
. Rietzle

r Laborator y fo r Environmenta

l Analysi s Schnorrstrass e 5 a 9047 1 Nurember

g Telephon e 0911/8 6 8 8 2 0 Fa x 0 9 11/8 6 8 8 22 2

Projec t site :

Client : Responsibl e authority : Contrac t date : Dat e o f measurement : REPOR T Emissio n Measurement s GFK-Wer k Neumark t Firm aPfleidere r Infrastrukturtechni

k
Firm aPfleidere r Infrastrukturtechni

k Sulzbuerge

r Str
. 8 9231 8 Neumark

t Firm aPfleidere r Infrastrukturtechni

k Ingolstaedte

r Str
. 5 1 9231 8 Neumark

t Offic e o f th e Chief Administrativ e Office

r March 200 1 3/14/0 1 Projec t manager : M
. Humme l (Environmenta

l engineer ) Ou r symbol/Projec t

code : PFI.NEU2 1 3/14/0 1 Location , date : Nuremberg , 5/4/0 1 Tota l 3 copie s issue d 1 0 page s o f

report 2 appendice s Tes t laborator y accredite dby th e Germa n Testin g Accreditatio n Syste m(DAP) by th

e Bavaria n Stat e Trad e Institut e (LGA)
. Accreditatio n applie s t

o th e tes t procedure s listed i

n the documen

t (Registratio n no . DAP-P-02 02 9 00-91-04 ) Announced as ameasuremen t offic e pursuan t t o 3 26,28 , Federa

l Immission Protection La

w an d 31 2 Paragrap

h 7 of the 2n dFedera l Immissio n Protection Ac

t Certified b y AQ S Regiona l Headquarters Bavaria/Approved pursuan t t o 3 3 Sewerag e Ac

t an d 3 1 9 Drinking Wate

r Act


# U *P.2 0



### 1 . Measuremen ttas k 1. 1 Client FirmaPfleidere

r Infrastrukturtechni

k Gmb H & Co
. KG , Ingolstaedte

r Str
. 5 1 in 9231 8 Neumarkt
. 1.2 Operato r See item2.1
. 1. 3 Locatio n Th e syste mi s locate din aproductio n she da t th e sit e namedunde

r item2. 3 1. 4 Syste

m Syste mfo r processin g o

f liqui dU P resin s wit

h addedstyrene . 1.5 Dat

e o f samplin g Sample s wer

e taken o n 3/14/01
. It

i s afirs t measurement . 1. 6 Cause Measuremen

t o f emission s withi n the framewor k o f a n registratio n proces s pursuan t to B 6 7 Paragrap h 2 o

f th e Federa

l Immissio n Protectio n Law
. 1. 7 Formulatio n of

th e tas k Determinatio n o

f mas s concentration s an

dmas s flow s o

f th e organi c substance s contained in the exhaus t

ai r o f th e centrifug e bank s (No
. 3.1. 7 Technical Air Pollutio n Abatemen

t Instruction s [TAPAI] ) an

ddeterminatio n of

th e emission s forme dwhe n storag e tank s B l - B 4 ar

e bein g filled
. 1.8 Measuremen

tcomponent

s Th e following component s wer e detecte din th e GC-M S screening :



# 2 

# llfP.2 1



### Tabl e 4
. Measuremen

t component s Measurement

componen

t Benzen e Toluen e Ethy l benzen e p-/m-/o-xylen e Styren e Cumen e Trimethy l benzene s 2-Ethy l toluen e 3-/4-Ethy l toluen e Aceti c aci disobuty l este

r n-Butylacetate Substanc e clas s a s pe r TAPA I 2.3.III 3.1.7.II 3.1.7.II 3.1.7.I I 3.1.7.II 3.1.7.I I 3.1.7.II 3.1.7.I I 3.1.7.II 3.1.7.II I 3.1.7.III

1. 9 Coordinatio n o

f th e measuremen t

schedul e Th e measuremen

t schedule wa s coordinate dwit h Mr
. Klaue

r (Fa
. Pfleiderer)
. 1.1 0 Participant s i n samplin g Sample s an

dmeasurement s wer

e take n o n site b

y Mr
. M
. Hummel (environmenta

l engineer)
. 1.1 1 Participatio n o

f othe r institution s Al l measurement s wer

e take n an dstudie s wer

e carrie dout

b y the laborator

y o f Dr
. Rietzler
. 1.1 2 Technica l manage r Dr
. Rietzler , Schnorrstr
. 5a , 90471 , Nuremberg i s recorde da s technically responsibl e (Tel
. 0911/868820)
. 2
. Descriptio n of

th e system , substance s handle d 2. 1 Descriptio n of

th e syste m Th e syste mi s use dt

o produc e mast s fro

mglas s fiber-reinforce dplastic
. Th e importan t systemcomponent s ar

e th e following :

- storag e tank s (B l - B4 )

- daily storag e tan

k (B5 )

- mixin g statio n 

# \V0P.2 2



### - centrifug e bank s (S l - S3 ) Th e U P resi n i s pumpedint o th e dail y storag e tan

k B 5 fro mstorag e tank s B l - B 4 andi s heate dt

o roughl y 30°C
. A stipulate damoun t o f resin fro mtan k B 5 i s weighe d into areceivin g container
. A t th e mixin g statio n th e weighe dan d homogenize dload s ar

e adde dt o th e resin according t

o the formulation
. Actual productio n o

f mast s take s plac e o

n th e centrifug e bank s (S1-S3 ) i n mold s whic h ru n cylindrically o

r conically , which ar

e composed-of

severa l lengths , an

d whic h ar e closedon th

e en dwit h aclosur e plate
. Th

e mas t mold s ar e supporte d wit h flange s o

n the driv e roller s o

f the centrifug e banks
. Th e reinforcin g materia

l i s adde dt o the slowl

y rotatin g moldan

dth e rpmar

e increase dt

o 900-1100
. Applicatio n device s consis t o f apum p an dcontro l unit , the feedstock an d auxiliar y substanc e containers , an

don e injection gu

n each
. When th e injectio n gun i s activated , resin an

dcurin g agen

t ar e delivere dt

o th e mixin g batter

y o f the injectio n gu

n i n aformulation-specifi c rati o an dthe y ar e thoroughly mixe dthere
. Th e reactio n mixtur

e i s injectedwit

h the injection gu

n int o th e rotatin g mas t

mold i n whic h i t i s uniforml

y distribute don th

e inside o f the mas t mol db y centrifuga

l forc e an dimpregnate s th

e reinforcin g material
. The injectedamoun

t o f resin i s recorde db

y the contro l uni t

andindicated ; when th e set preselecte damoun

t i s reache dthi s i s moreove

r opticall y indicate do n th e injection gun . To accelerat

e th e curin g o f the masts , electrica

l heatin g element s ar e mountedon th e tw o side s o f th e centrifug e banks
. Th e injection proces s last s 5-1 0 minutes , th e curin g proces s roughly 20-3 0 minutes , th

e entir e proces s o

f producin g amas t

blan k i s roughl y 30-6 0 minutes
. 2. 2 Typ e o f

syste m Syste mfo r producin g molding s an

dfinishe dproduct s fromglass-fiber reinforce d plastic s (GFK

) usin g unsaturate dpolyester resin s (U P resins ) wit

h adde dstyrene . The syste mshoul db e classifie dpursuant t o th e 4t h Federa l Immissio n Protectio n Ac t unde r 5. 7 i n colum n 2
. 2. 3 Location o

f th e system 2.3. 1 Location

Sulzbuerge

r Str
. 8 9231 8 Neumark

t (Corrido r no . 2131 ) 2.3. 2 Emission source s 

# 4 mP.2 3



### 2.3.2. 1 Emissio n sourc e 1

The volum

e o f gas displace dwhe n the storag e tank s B1-B 4 ar e bein g filledwit h U P resi n i s discharge dt o the atmospher e vi aavent

pipe
. Tabl e 1
. Emissio n sourc e 1 Lega l valu e High valu e Absolut e geod
. valu e (m

) Heigh t above ground(m

) 446058 6

545804 6 42 7 7. 0
2.3.2. 2 Emissio n sourc e 2

The emission s forme

don th e centrifug e bank s ar e collecte dvi afum

e hoods , exhaustedan

demitte dvi ath e chimney , an di t ca n b e assumedtha

t due t o thi s exhaus t

n o noteworthy diffus e emission s occur . Tabl e 2
. Emissio n sourc e 2 Lega l valu e Hig h valu e Absolut e geod
. valu e (m

) Exi t are a(m2 

### ) Heigh t abov e ground(m) 446057 0 545804 1 42 7 0.03 5 11. 5
2. 4 Feedstock Tabl e 3
. Feedstock Th e indicate damount s ar

e referencedto on e batch i n th e receivin g container
. Feedstoc k U P resi n Dye past e Accelerato r Paraffi n solutio n U V absorbe r solutio n Curin g agen

t TOTA L SIRESTE RF S 413 1 OLDOPAL , or VETROPHE

N PERGAQUIC K

C 125 % Paraffin an

d95 % Styren e 10 % TINUVI

N 32 0 and 90 % Styren e PEROXA N A 4 0 L 180.00 k g

9.00 k g 2.3 0 kg 2.7 0 kg 9.0 0 kg 3.1 5 kg 206.1 5 k g 

## v ^ 

## vi - $h> l/tjL^-«

_



# IW -P.2 4



### 2. 5 Operatin g times 2.5. 1 Tota

l operatin g tim

e Th e syste mi s operatedi

n two-shifts , Monday-Friday , fro m060 0 t o 220 0 hours
. 2.5. 2 Emissio n time s 2.5.2. 1 Emissio n sourc e 1

Twic e monthl

y fo r 1 hou r a t atime
. I n th e perio dfro

mMonday-Frida

y betwee n 060 0 an

d220 0 hours
. 2.5.2. 2 Emissio n sourc e 2

Workday s 1 6 hours , Monday-Frida y fro m060 0 t o 220 0 hours
. 2. 6 Device for collectin g an d reducin g emission 2.6. 1 Collectio n o

f emissio n Onl y th e emission s which for

min actua l mas t productio n are collecte d (emissio n sourc e 2)
. The volum

e o f ai r displace dwhe

n th e storag e tank s (B1-B4 ) ar

e bein g filledi s discharge dt

o the atmospher

e vi athe vent

lin e o f th e tanks
. 2.6.1. 1 Emissio n collectio n syste m Emission s ar

e intaken by asuctio n draf

t fan
. 2.6.1. 2 Collectio n element s

Collectio n take s plac e vi aexhaus t hood s on the centrifug e bank s S1-S 3 on the intak e side t o the fan
. 2.6. 2 Emissio n reductio n system s

Emissio n reductio n system s ar e no t installed
. Installin g aga s displacement lin e between the daily storag e tan k B 5 an dth e U P resi n storag e resulte di n no emission s int

o the atmospher

e bein g forme

dwhen tank

B 5 i s bein g filled
. 3 Descriptio n of

samplin g site s 

# inP.2 5



### 3. 1 Locatio n o f

th e measuremen

tcros s section s 3.1. 1 Emissio n sourc e 1

Th e sample s wer

e take n fro mthe gaseou s phas e o

f th e dail y storag e tan k B5
. 3.1. 2 Emissio n sourc e 2

The measuremen

t cros s sectio n fo

r emissio n measurement s on th e exhaus t ai r side i s roughly 1. 5 mbehin dth e fan
. Tabl e 5
. Measuremen

t cros s section Measuremen

t cros s sectio n Geometr y Diamete r Cros s sectio n roun d 21 0 m m 0.03 5 m

A



### 3.1.2. 1 Measuremen

t axe s The gaseou s component s to b e measure dca n b e measureda

t on e measuremen

t poin t a s aresul t o f optimumswirlin g i n th e fan
. 4 . Measurementan

d analysi s processes , Equipment 4. 1 Determinatio n of

exhaustgas boundar

y condition s Tabl e 6
. Measuremen

t instrument s fo

r measurin g the boundar

y condition s No
. 4.1. 1 4.1. 2
4.1. 3

4.1. 4 Paramete r Flo w velocit

y Stati c pressur

e i n th e exhaus t ga s chimne

y Air pressur e a t th e heigh t o f th e measuremen

t point Exhaus t ga s temperatur e Meas
. principl e Prandt l pressur e tub e Piezoresistiv e differentia l pressure gaug e Piezoresistiv e absolut e pressur e transduce r Pt10 0 * 1 Typ e

DP S
AP S

Z A 9030-FS 1 Mak

e 1 Ahlbor n Co
. Ahlbor n Co
. Ahlbor n Co
.

Ahlbor n Co
.



### 7 

# iv HP.2 6



### 4. 2 Gaseous emission s 4.2. 1 Discontinuou s measuremen t processe s 4.2.1. 1 Samplin g

Adsorptio n o

f organi c component s o

n activatedcharcoa

l tube s typ e G fro mFa
. Draeger
. 4.2.1. 2 Analysi s

See Tabl e 4 in 2. 8 an

dAppendi x 2
. 4.2. 2 Continuou s measuremen t processe s Measuremen

t of tota l C emission s by mean s o

f flam e ionizatio n detector V E 7 fro mFa
. J.U.M
. (Qualificatio n tes t available ) Calibratio n wa s done wit

h methane a s the tes t

ga s (tes t certificat e ca n b e inspected)
. 5 . Operating stat

e o f th e syste mdurin g measurement s Durin g the samplin g interva l o f 2.7 5 hour s 9 mast s wer

e produced ; resi n consumptio n wa s 23 5 kg
. Al l thre e centrifug e bank s S l - S 3 wer e i n operatio n Extrapolate d shif

t output : Maximu mshif t output : Utilizatio n o

f th e system : 68 4 k g resin 90 0 k g resin 76 % 6 Measuremen

tresult s and discussio n 6. 1 Boundar

y condition s The physica

l boundar y condition s wer

e recordeddurin g measurements . 6.1. 1 Ambien

t condition s Tabl e 7
. Ambien

t boundar y condition s Temperatur

e Ai r pressur e Relativ e humidit

y 6- 8 degree s C 95 7 hPa 52-56 %


# /LiP.2 7



### 6.1. 2 Exhaus t

ga s boundar

y condition s Th e followin g dat

awer e establishe di

n th e measuremen

t cros s sectio n o

f th e emissio n sourc e 2
. Tabl e 8
. Exhaus t

ga s boundar

y condition s Measuremen

t quantit y Temperatur

e Abs
. humidit

y Stati c pressur

e Volumetri c flow , averag e Volumetri c flow , tr . averag e Volumetri c flow , norma

l stat e Uni t degree s C g/cubi c mete

r HP a cubi c meters/

h cubi c meters/

h cubi c Nm/ h 24

roughly 7 roughly 1 252 0 250 0 233 0 6. 2 Measurement

s of gases 6.2. 1 Emissio n sourc e 1 6.2.1. 1 Discontinuou s measuremen t Tabl e 9
. Result s fo

r emissio n sourc e 1 Substanc e clas s TAPA I 2.3.III 3.1.7.II mg/N

m
0.6 1 2949 3 Boundar

y valu e TAPA I mg/m3 

### g/ h 5 10 0 Emissio n g/ h roughly 0.01 2 roughly 59 0 Boundar y valu e TAPA I g/ h 2 5 200 0 For assessmen

t purpose s the average s fro

mtw o measurement s wer

e used , the component s 2-ethyl toluen e an d3/4-ethy l toluen e wer

e assigne dt

o clas s 3.1. 7 III

. Th e result s o f individua l measurement s ca

n b e take n fro m the tes t repor t (Appendix)
. Th e tota l emissio n wa s compute dunde r th e assumptio n tha

t th e storag e tank s ar e completel

y emptie dandthe fillin g proces s last s 1 hour
. 6.2. 2 6.2.2. 1 Discontinuou s measurement s 

# J . ,j * ° " Emissio n sourc e 2 

## o*o ^ Tw o half-hou

r average s wer

e taken
. I t become s apparent

fromth e stud

y ^ ^ I* * result tha t th e compositio n o

f th e exhaus t

ai r change s wit

h respec t t o the ^^./o^ concentratio n o

f individua l component s dependin g o n th e operatin g stat e 

## |7 >P.2 8



### of th e system . Thi s i s in conformit y wit h the continuou s tota

l carbo n measuremen

t whic h likewis e show s fluctuation s o f emissio n dependin g o n th e operatin g state . Measurement s yieldedth e followin g result s relativ e t o standar d conditions : Tabl e 10
. Result s o

f emissio n sourc e 2 Substanc e clas s TAPAI 3.1.7.II 3.1.7.II I mg/Nm J


### 54.3 5 0.4 0 Boundar

y valu e TAPA I mg/m3 

### g/ h 10 0 15 0 Emissio n g/ h roughl y 12 6 roughl y 0. 9 Boundar

y valu e TAPA I g/ h 200 0 300 0

For assessmen

t purpose s th e average s fro

mtw o measurement s wer

e used , th e componen

t aceti c acidisobuty l este

r wa s assigne d to clas s 3.1. 7 III. The result s o

f individua l measurement s ca

n b e take n fro

mth e tes t repor t (Appendix)
. 6.2.2. 2 Continuou s measuremen t I n th e establishe dcompositio n o f pollutant s wit

h 96 % styren e portio n th e continuou s measuremen

t yield s apictur

e o f the styren e emission s or

clas s 3.1. 7 II emission s which take s int o accoun t the changin g emissio n conditions
. The tota

l C emission s wer

e therefor e converte dt

o styrene . Half-hou r averag e 1 2 3 4 Measuremen t time interva l 11.15-11.4 5 11.45-12.1 5 12.15-12.4 5 12.45-13.4 5 Measure d valu e i n

g/m 3 

### styrene 0.4 2 0.5 2 0.1 5 0.4 2 Emissio n i n g/ h styren e (extrap. ) 98 0 121 0 35 0 98 0
Tabl e 11
. Half-hou

r average s The averag e i s 0.3 3 g/m 3 

### or 77 0 g/ h styrene fo

r th e entire measuremen

t interval
. The exac t progressio n o

f th e measuremen

t ca n b e take n fro

mth e graphi c evaluatio n (appendix)
. 6. 3 Predictio n of

emission s for th e syste m a tful l load

1 0 

# 111P.2 9



### Predictio n i s possibl e her

e onl y fo r the maximu

mshif t outpu t sinc e auniform , representativ e operatin g stat e o f the systemcanno t

b e establishe ddu e to th e variou s operatin g state s o

n th e individua

l centrifug e banks
. Extrapolatio n o

f the averag e ove

r th e entir e measuremen

t interva l o f 77 0 g/ h fo r syste mutilizatio n o

f 76 % yield s roughl

y 101 0 g/ h styrene a s the ful

l loa d emissio n value
. I f th e half-hou r averag e 2 (worst-case ) o

f 121 0 g/ h i s usedfo

r extrapolation , thi s yield s aful

l loa demissio n valu e o

f roughly 159 0 g/

h styrene . 6. 4 Evaluatio n 6.4. 1 Emissio n sourc e 1

Measurement s show tha

t the emitte dsubstance s ca

n b e assigne dt

o substanc e grou

p 3.1. 7 I I o

f th e Technica

l Ai r Pollutio n Abatemen

t Instructions
. The mai

n componen

t wit h aproportio n o

f mor e tha n 96 % i s styrene , othe

r compound s ar

e present in par t onl y in trac e concentrations
. Furthermore , it

ca n b e statedtha

t the time-reference dboundar y valu e o f 200 0 g/ h fo r substance s o

f clas s 3.1.7
. I I wit

h roughl y 59 0 g/ h i s certainly maintained , th

e boundar y valu e referencedt

o th e volumetri c flow o

f exhaus t ai r o f 0. 1 g/m

3 

### i s howeve

r exceede dwit

h roughly 29. 5 g/m3



### . Th e boundar

y valu e referencedt

o the volumetri c flow o

f exhaus t ai r i s howeve r no t relevan t a s aresul t of th e lo w tota

l emissio n amount . Thi s emissio n couldunde

r certai n circumstance s b e prevente db y aga s displacemen

t lin e between th e tanke

r truck an dthe storag e tank s B1-B 4 durin g the fillin g process . Thi s emissio n reductio n systemi s no t necessar y accordin g t

o the Technica

l Air Pollutio n Abatemen

t Instructions
. 6.4. 2 Emission sourc e 2

Measurement s sho w tha

t th e emitte dsubstance s ca

n b e assigne dt

o substanc e grou

p 3.1. 7 I I o

f th e Technica

l Air Pollutio n Abatemen

t Instructions
. The main componen t wit h aproportio n o

f mor e tha n 96 % i s styrene , othe

r compound s ar

e present i n par t onl y in trac e concentrations
. Furthermor

e i t ca n b e state dtha

t the time-reference dboundar y valu e o f 200 0 g/ h fo r substance s o

f clas s 3.1.7
. II of

the Technica

l Air Pollutio n Abatemen t Instruction s i s certainl y maintained , but th e boundar

y valu e referenced t

o th e volumetri c flo w o

f exhaus t ai r o f 0. 1 g/m3 

### i s t

o som e

1 1 

# \tHP.3 0



### extent greatly exceededdurin g productio n hours , a s continuou s measurement s show (see 6.2.2.2 ) Th e boundar

y valu e referencedt

o th e volumetri c flow o

f exhaus t ai r i s howeve r not relevan t her e eithe r a s aresul t o f the lo w tota

l emissio n amount . A n emissio n reductio n systemi s therefor e no t necessary . 6.4. 3 Diffus e emission s

Whe n the receivin g containe

r i s being filledfro

mth e daily storag e tan

k an dwhe n the auxiliar

y agent s an

dth e charg e ar

e bein g mixed , diffus e emission s occu

r repeatedl y in the areao

f th e hall on adaily basis
. Thes e emission s ar

e howeve r largely collecte dby the exhaus t syste mon the centrifug e bank s an

dar e thu s containedi

n th e exhaus t ai r o f the emissio n sourc e 2 an

dthe correspondin g measuremen t results
. Diffus e emission s ar

e not aproblemwit

h respec t t o th e emissio n situation
. Question s o

f industria l safet y an dworkplac e concentration s wer e no t th e subject o f study
. Nuremberg , 5/9/0 1 Author : fo r [Signature ] [Signature ] Dr
. Rietzle

r Martin Hummel (Environmenta

l engineer) Appendix : 1
. Descriptio n o f the measuremen

t proces s 2
. Laborator

y tes t repor t

1 2 

## /*- ?

### Appendi x 1. 1 Emissio n measuremen

ta tth e GFK-Wer

k Neumarkto f

Firm a Pfleidere r Infrastrukturtechni k on 3/14/0 1

x axi s - emission s in g/

m discontinuou s measuremen

t 1 discontinuou s

measuremen

t 2



# o

1 3 y axi s - tim e

### Appendi x 1. 2

Half-hou r average s o f

emissio n measurementatth e GFK-Wer k Neumarkto f

Firm a Pfleidere r Infrastrukturtechni k o n 3/14/0 1

x axi s - emission s in g/Nm 3 

### styren e

v O

y axi s - half-hou r averag e

1 4P.3 3



### Dr
. Rietzler Schnorrstrass e 5 a 9047 1 Nurember

g Laborator

y fo r Environmenta

l Analysi s

Pfleidere r Verkehrstechnik

Gmb H Mr
. Klaasse n Ingolstaedter

Str
. 5 1 9231 8 Neumark

t

22 2 

### Schnorrstrass e 5 a 9047 1 Nurember

g Telephone 0 9 11/8 6 8 8 2 0 Fa x 0 9 11/8 6 8 8

Dat e 4/23/0 1 TES T REPOR

T 010938/PFLNEU21-u

r Client : Client address : Samplin g site : Sampler : Samplin g date : Sampl e arriva

l date : Tes t interval : Page : Pfleidere r Verkehrstechnik

Gmb H Ingolstaedte

r Str
. 51 , 9231 8 Neumark

t Neumark t Humme l 3/14/0 1 3/14/0 1 3/14/0 1 - 4/20/0 1 Io f 4

Tes t laborator y accreditedby the Germa

n Testin g Acaeditatio n Syste m(DAP) by th

e Bavaria n Stat e Trade Institut

e (LGA)
. Accreditatio n applie s t

o the tes t procedure s listedi

n the documen

t (Registratio n no . DAP-P-0 2 02 9 00-91-04 ) Announce da s ameasuremen

t offic e pursuan t t o 3 26,28 , Federa

l Immission Protection La

w an d 3 1 2 Paragrap

h 7 o f the 2n d Federa l Immissio n Protection Ac

t Certifie d b y AQ S Regiona l Headquarter s Bavaria/Approved pursuan t t o 3 3 Sewerag e Ac

t an d 3 1 9 Drinkin g Wate

r Act Tes t result s appl

y exclusivel

y to the aforementionedsamples
. The tes t repor t ma y no t b e reproducedi

n extract for mwithou t the writte n permission o

f th e tes t laboratory
. Posta l Ban k Nurember g Accoun t no . 41118-855 5 BL

Z 76 0 1008 5 Cit y Saving s Ban

k Nurember g Accoun t no . 117 9 24 6 BL

Z 76 0 60 1 0 1



### 1 5P.3 4



### Pag e 2 o f 4 STUD Y RESULT S GC/M S SCREENIN G Sample : Emissio n 1 Method : Laborator v numbe r 10402 0

The activate dcharcoa

l wa s extracte dwit

h carbon disulfide
. A

n aliquo t o f th e extrac t wa s then analyze dunde

r the following conditions :

- Techniqu e Ga s chromatograph y

- Detector Mas s selectiv e detecto r io n tra p MAGNU

M Finniga n MAT

- Temperatur

e rang e 40° C t

o 230° C

- Mas s rang e 4

- - 24 0 am u

- Colum n DB-VR X capillar y colum n

- Automati c injectio n 2 microlite r splitles s

- Carrie r ga s Heliu m5. 0 Identificatio n wa s done usin g the retentio n tim e an dby computer-aide d compariso n o

f th e sampl e spectrawit

h librar y spectra . Th e followin g librarie s wer

e availabl e fo

r comparison :

- NIS T Mas s SpectraLibrar y (roughly 6200 0 compounds )

- Genera l Purpos e Librar

y (roughly 500 0 compounds )

- Toxicology Librar

y (roughly 300 0 compounds )

- Terpene Librar

y (roughly 70 0 compounds ) Result : Emissio n 1 -10402 0 The followin g substanc e group s were detected
. Highl y volatil e aromati c hydrocarbons : Benzene Toluene Ethy l benzen e p-/m-xylene 0-Xylene Styrene Cumen e Trimethy l benzene s 2-Ethyl toluen e 3-/4-Ethyl toluen e 0.00 8 mg/m 3 

### 1. 3 mg/m3 

### 0.06 6 mg/m3 

### 0.1 2 mg/m

3 

### 0.02 0 mg/m

3 

### 6 3 mg/m3 

### 0.01 0 mg/m3 

### 0.01 7 mg/m3 

### 0.00 4 mg/m3 

### 0.01 0 mg/m3

» mP.3 5



### Ester s Aceti c aci disobuty l ester s 0.1 8 mg/m3 

### n-Buty l acetate 0.1 7 mg/m 3 

### Tes t result s apply exclusivel

y t o th e aforementionedsamples
. The tes t repor t ma y no t b e reproduce

di n extrac t for mwithout the writte n permissio n o

f th e tes t laboratory
.

1 7P.3 6



### Pag e 3 o f 4 Result : Emissio n 2 -10402 1 Th e followin g substanc e group s wer e detected : Highly volatil e aromati c hydrocarbons : Benzene 0.00 9 mg/m 3 

### Toluen e 0.6 3 mg/m 3 

### Ethy l benzene 0.06 1 mg/m 3 

### p-/m-xylen e 0.1 2 mg/m 3 

### o-Xylene 0.02 6 mg/m 3 

### Styrene 3 3 mg/m 3 

### Cumene 0.01 1 mg/m 3 

### Trimethy l benzene s 0.02 3 mg/m3 

### 2-Ethyltoluen e 0.00 5 mg/m 3 

### 3-/4-Ethy l toluen e 0.05 0 mg/m3 

### Ester s Aceti c acidisobuty l ester s 0.2 1 mg/m 3 

### n-Buty l acetat

e 0.2 0 mg/m 3 

### Result : Storag e tan k 1 -10402 2 Th e following substanc e group s were detected : Highl y volatil e aromati c hydrocarbons : Benzene Toluene Ethyl benzene p-/m-Xylene 0.6 6 1.00 0 3 2 1 6 o-Xylen e eclipse dby styren e Styrene Cumen e Trimethyl benzene s 2-Ethyl toluene 3-/4-Ethyl toluen e mg/m 3 

### mg/m3 

### mg/m 3 

### mg/m 3 

### mg/m 3 

### 33.00 0 mg/m 3 

### 6. 9 6. 4 0.3 4 1.4 mg/

m mg/m 3 

### mg/m 3 

### mg/m 3 

### Tes t result s appl

y exclusively to th e aforementione dsamples
. The tes t repor t ma y no t b e reproduce di n extrac t

for mwithou t th e writte n permissio n of th e tes t laboratory
. 

# /3 S 1 8P.3 7



### Pag e 4 o f 4 Result : Storag e tan k 2 -10402 3 Th e followin g substanc e group s wer e detected : Highly volatil e aromati c hydrocarbons : Benzen e Toluen e Ethy l benzene p-/m-Xylen e 0.4 8 87 0 1 8 9. 3 o-Xylen e eclipse dby styrene Styren e Cumene Trimethy l benzene s 2-Ethy l toluene 3-/4-Ethy l toluene Nuremberg , 4/23/0 1 [Signature ] Dr
. Rietzle

r mg/m 3 

### mg/m 3 

### mg/m 3 

### mg/m 3 

### mg/m 3 

### 20,00 0 mg/m

J 

### 3. 3 7. 8 0.1 6 0.2 7 mg/

m mg/m 3 

### mg/m 3 

### mg/m 3



### Tes t result s appl

y exclusively t

o th e aforementione dsamples
. Th e tes t repor t ma y not b e reproducedin extrac t

for mthe writte n permissio n o f th e tes t laboratory
.

&(* 

### 1 9P.3 8



### Appendi x to Stud

y Repor t (PFLNEU21/010938 ) Sample : Laborator v number : Emission l 104020 Chromatogra

mPlo t C:\MAGNUM\DATA\18402 8 Date : 4/12/0 1 23:08:3 1 Comment : PFLNEUZ 1 Emission l 3/14/0 1 A k Type G GC/G

M Screenin g Sca n no : 69 5 Retentio n time : 11:3 5 RIC:388974 1 Mas s Range : 4 8 - 23 7 Plotted : 69 5 to 1920 Rang e 1 t o 192 0 100 % = 6074865 1 1.56%

Tes t result s appl

y exclusively t

o the aforementionedsamples
. The tes t repor t ma y not b e reproduce di

n extrac t for mwithout th e writte n permissio n o

f the tes t laboratory
.

2 0P.3 9



### Appendi x to Stud

y Repor t (PFLNEU21/010938 ) Sample : Laborator y number : Emissio n 2 10402 1 Chromatogra

mPlot C:\MAGNUM\DATA\18402 1 Date : 4/12/0 1 23:51:0 3 Comment : PFLNEUZ 1 Emission 2 3/14/0 1 A k Type G GC/G

M Screenin g Sca n no : 69 5 Retentio n time : 11:3 5 RIC:2374580 8 Mas s Range : 4 0 - 2863 7 Plotted : 69 5 t

o 1920 Rang e 1 t

o 192 0 100 % = 6429875 1 1.56 %

Tes t result s appl

y exclusively t

o the aforementione dsamples
. Th e tes t repor t ma y no t b e reproducedin extrac t

for mwithout the writte n permissio n o

f th e tes t laboratory
.



# tV ? 2 1P.4 0



### Appendi x to Stud

y Repor t (PFLNEU21/010938 ) Sample : Laborator v number : Storag e tank l 104022 Chromatogra

mPlo t C:\MAGNUM\DATA\18482 8 Date : 4/13/0 1 00:33:3 1 Comment : PFLNEUZ 1 Storag e tank l 3/14/0 1 A k Type G GC/G

M Screenin g Sca n no : 69 8 Retentio n time : 11:3 1 RIC:1766038 2 Mas s Range : 4 0 - 26 5 Plotted : 69 0 to 191 9 Range 1 t o 191 9 100 % = 32327258 0 1.56 %

Tes t result s appl

y exclusively t

o the aforementionedsamples
. Th e tes t repor t ma y no t b e reproduce din extrac t

for mwithou t the writte n permissio n o

f th e tes t laboratory
.

2 2P.4 1



### Appendi x t

o Stud y Repor t (PFLNEU21/010938 ) Sample : Laborator y number : Storag e tan

k 2 10402 3 Chromatogra

mPlo t C:\MAGNUM\DATA\10402 3 Date : 4/13/0 1 01:16:0 0 Comment : PFLNEU2 1 Storag e tank 2 3/14/0 1 A

k Type G GC/G

M Screenin g Sca n no : 69 8 Retentio n time : 11:3 1 RIC:2056477 0 Mas s Range : 4 0 - 22 4 Plotted : 69 0 t

o 191 8 Range 1 t

o 191 8 100 % = 28166889 2 0.78 %

Tes t result s appl

y exclusively t

o the aforementione dsamples
. Th e tes t repor t ma y not b e reproducedi

n extract s withou

t the writte n permissio n o

f th e tes t laboratory
.



## Iif 0 23P.4 2 

# a PFlflDERE R

AKTltNOeSIUJCHAF T 

### ZentraleAnalytikHTF A ProJeW-Nr. : 179-0 0 

### Laborberich t Betreff : NM-lnfrasV\iMurtedinlk;GFK-Mastenprodukiio n

Emissio n a n orflapjgc h oebundenom'Kohlenstof f *- : er*tf*n*\ &•*/• * or^eLnictJliA MesaungvprfTl6/112000.•' S Matu re 

### *->v + ^ Wn i carbo*-

J Kamlndurchmesse r- ^

m 0,2 1 Abtufttemperatu rB 

### C 24,1 —exk*us + a". ' ^«»"r fttwf t 

### relativ e Feucht © % 28, 7 - rc 

### i 0 

### (.; ^ dampwes- J 

### bar.Luftdruc

k hP

a 96 4 - to•+1***o

iA - o. v 1 

### v S 

### r/u-' e Druc k i n de rAbluf t hP a 964'ft, l 

### > 0 

### „ ,- > f U eyj-ieuff 4



### - o i r Wesserantel l g/m» N 

### >« ' 7.- T V b v 6 

### io^* « H Q3Btrieb5>olume n r^wa * 240 0 KvnU**- * v»i»-*«»

j Normvolumen , feuch t TiVfiwh t 210 0 4«.rr, p 

### Normvolumen , trocke n rn' N 

### ,treei» n 210 0

r o idorc l y.S>/u«-» * flf''*W"»< 

### pp m mgC/m* N 

### mgStyrol/m V » bM.»u1?rop» n V * 

### 10.49.2 5 139, 5 224, 3 243, 4 (Hal^std.M W 11.19.2 5 76, 6 123, 2 133, 7 Halbetd.M W 11.49.2 6 92, 4 148, 8 181, 1 Halbetd.M W 12.19.2 5 86, 8 139, 6 181, 4 Helbstd.M W 12.49.2 5 102, 6 165, 0 179, 0 Halb»td.M W

99J 6 160, 1 173, 7 Gesamt-M W

| 384, 8 a Styrol/Stontff l t n \r>Vel v

-

*K 

## K \ 

# X

M (

E O B LLi»« 3 >M«IIN» N V9XSO T QO-^IOH Qeo' d 22/. * 92 9 eQ 8 

# (M V l \

LL!-'*'5 3 *>1-«BuuM*a N \/9i:O I OO-VT-OO Q