I .Airy

X

THE THERMOPHYSICAL PROPERTIES OF METHANE,

FROM 90 to 500 K AT PRESSURES TO 700 BAR

R. D. Goodwin

Cryogenics Division

Institute for Basic Standards

National Bureau of Standards

Boulder, Colorado 80302

October 1973

Final Report

Prepared for: The American Gas Association

1515 Wilson Boulevard

Arlington, Virginia 22209

NBSIR 73-342

THE THERMOPHYSICAL PROPERTIES OF METHANE,

FROM 90 to 500 K AT PRESSURES Tl II Ml

R. D. Goodwin

Cryogenics Division

Institute for Basic Standards

National Bureau of Standards

Boulder, Colorado 80302

October 1973

Final Report

Prepared for: The American Gas Association

1515 Wilson Boulevard

Arlington, Virginia 22209

U.S. DEPARTMENT OF COMMERCE, Frederick B. D*nt, S®cr®4ary

NATIONAL BUREAU OF STANDARDS. Richard W Roberts. Director
Firat Printing 30 October, 1973.

Second Printing 12 November, 1973.

li
Contents

Page

1 . Introduction 1

2. Physical Properties and Their Representation 3

2. 1 Fixed-Point Constants . . 3

2. 2 Melting Line and Vapor Pressures 3 2.3 The Orthobaric Densities 4

2.4 The Virial Equation 6

2. 5 The Equation of State 6

2.6 Representation of CV(T) at 18.5 mol/'t. 8

3. Computational Methods 9

3.1 The Homogeneous Domain 9

3.2 The Vapor-Liquid Transition 10

3. 3 Representation of E (T) and S (T) 11 o a 3.4 Circumventing the Critical Domain 12

4. Comparison of Derived and Experimental Properties 12

4. 1 Heats of Vaporization 12

4.2 Specific Heats C^(T), C

v

(p,T), C^(p,T) 13

4.3 Speeds of Sound W (T), W(p , T) . 13 a

5. Tables of Physical and Thermodynamic Properties 13

5.1 Calculated P-p-T Isochores and Isotherms 13

5.2 The Joule -Thomson Inversion Locus 14

5.3 Thermophysical Properties of the Saturated Liquid ........ 14

5.4 Thermophysical Properties Along Selected Isobars . 14

6. Tables in British Engineering Units 14

7. Comments on Uncertainties 14

8. Acknowledgments 15

9.

References 16
Contents (Continued)

Appendix A. Symbols and Units 21

Appendix B. Fixed-Point Values 22

Appendix C. Conversion of Units 23

Appendix D. List of new Data 24

Appendix E. Computer Programs 25

List of Figures

Figure 1. Density-temperature phase diagram 42

List of Tables

Table 1-A. The saturated vapor densities 43

Table 1-B. The saturated liquid densities 45

Table 1-C. The vapor-liquid saturation temperatures 46

Table 2-A. The second virial coefficient 49

Table 2-B. The third virial coefficient 50

Table 3. Summary of P-P-T data 51

Table 4. Comparison of experimental and calculated P-p-T values .... 52

Table 5. Comparison of specific heats for saturated liquid 79

Table 6. Comparison of specific heats, C^fp.T) 80

Table 7. Comparison of specific heats, Cp(P,T) . 85

Table 8. Comparison of speeds of sound for saturated liquid 87

Table 9. Comparison of speeds of sound, W(p,T) * 88

Table 10. Calculated P(T) isochores 90

Table 11. Calculated P(p) isotherms 117

Table 12. The Joule-Thomson inversion locus 134

Table 13. Thermophysical properties of the saturated liquid 135

Table 14. Thermophysical properties along isobars 137

Table 15.* The Joule-Thomson inversion locus 205

Table 16.* Thermophysical properties of the saturated liquid 206

Table 17.* Thermophysical propertie s along isobars 209

* Tables in British engineering units.

iv
The Thermophysical Properties of Methane from 90 to 500 K

at Pressures to 700 Bar*

R . D . Goodwin

Thermophysical properties of methane are tabulated at uniform temperatures from 90.68 to 500 K along isobars to 700 bar. A novel equation of state is employed for the first time, having origin on the vapor-liquid coexistence boundary.

Computations are based almost entirely on ideal gas specific heats and experimental P- p-T data via the equation of state, without weighting to data for derived

properties . Good agreement with such data confirms validity of the equation and

method . New P- P-T data are reported at 0.3 to 1.7 times the critical density

.

Key words: densities; enthalpies; entropies; equation of state; internal energies;

isobars; isochores; isotherms; Joule -Thomson inversion; latent heats of vaporization; melting line; orthobaric densities; PVT data; specific heats; speeds of sound;

vapor pressures

.

1 . Introduction

< i Methane is the major component of natural gas, and hence of great economic

importance. For the processes of liquefaction , separation, storage, pumping, transport

and custodial transfer there is required a knowledge of physical and thermodynamic properties. For mixtures, some properties can be approximated by those of pure methane.

For computations on the properties of LNG mixtures, the dominant thermodynamic data

required again are those of methane . In the following work it is possible to test the thermodynamic computations against experimental data for specific heats, heats of vaporization,

and speeds of sound available over wider ranges than for other components of LNG . Some

of the experimental data obtained here on methane , for example the saturated liquid densities

,

also have been useful to others for calibrating experimental apparatus

.

Extreme accuracy is needed in physical and thermodynamic properties data for

engineering plant design, as demonstrated recently by Zudkevitch [73] . Two monographs

on methane [61, 72] show, however, that low temperature data necessary for thermal

computations either are non-existent or are inaccurate. In view of the importance of the lowtemperature, liquid states of methane and natural gas, our objective has been to supply the

needed properties data directly by experiment, and then to produce a set of self-consistent

tables of thermodynamic functions over the entire range of fluid states

.

* This work was carried out at the National Bureau of Standards under sponsorship of The

American Gas Association.
This report culminates three years of work in acquiring available physical properties data, in performing experimental measurements, and in formulating these data for

use in thermal computations. Nearly all of these formulations are new: designed to be

consistent with critical-point behavior . Where appropriate , they are constrained both at

the triple point and at the critical point for consistency in the derived thermodynamic

network . New physical properties data which we have measured or derived are listed in

Appendix D

.

Our new equation of state is a contribution to the present task . An outstanding

feature is that it originates on the vapor-liquid coexistence boundary, thus eliminating

the long-standing problem of consistency between equations of state and this independentlyderived locus. The equation also is consistent with the nonanalytic behavior of C

v

( P ,T)

about the critical point. It has only nine coefficients to be found by least squares from

experimental P- p -T data, and these will be similar for most simple substances [30] . As

compared with equations which employ a much greater number of arbitrary coefficients , we

believe the present form to be advantageous for thermal computations because the derivatives

,

SP/9T, d ^P/dT^, and SP/9p are more likely to be simple, monotonic functions of the independent variables, as demonstrated below by computed tabulations. We believe that a

proper behavior of these derivatives is more important than the mere "representation" of

experimental P-q-T data. In particular, experimental data from different laboratories often

must be used which are not accurate, as proven by their lack of consistency. An equation

of state with excess freedom then is most likely to give serious irregularities in the derivatives . As a reward for minimizing the number of arbitrary coefficients, we find in the present

work that derived properties such as specific heats and speeds of sound, calculated "a priori"

via the equation of state , do agree with experimental data within combined uncertainties

,

without any weighting of the equation of state to such data. This accomplishment, we believe,

never before has been realized. It suggests that where such data do not exist experimentally,

they might be estimated with some reliability via the present type of equation of state.

Symbols and units of this report are given in Appendix A. Temperatures are on the

kelvin scale of IPTS-1968 [l] . Pressures are related to the International System by use

of the bar, 1 bar = 10^ Newton/square meter [ 3] . For the engineer we have computed

2
tables in British engineering units at integral pressures in psi and integral temperatures

on the Fahrenheit scale. The conversion of units is given in Appendix C. Deviations in

this report are expressed uniformly as the departure of an experimental value, Y, from

in percent, 100 * (Y-Y

caj c )/Y

2 . Physical Properties and Their Representation

2.1 Fixed-Point Constants

Selected values for the triple- and critical -point constants are listed in Appendix B

The triple-point temperature and pressure are from our vapor-pressure equation [ 52 ]. The

liquid density is an extrapolation of our accurate, saturated liquid densities [ 30] to the

triple-point temperature. The vapor density is given by eq (4-c) of this report.

The critical -point temperature is from an analysis of dielectric constants by Verbeke [68] . The pressure is given by the vapor-pressure equation (3) below. The density is selected within

the uncertainty in [ 68 ] to minimize the mean of relative pressure deviations via the present

equation of state

with constants e = 1.85, A = 16,259.1. The precision is better than 0.1 percent in pressure [ 52 ]

Densities of the freezing liquid were obtained at three points to a maximum pressure of 220 bar at intersections of our experimental isochores with the melting line, as reported in [23] . They are represented within the precision of 0.02% in density by our simple

expression

2.2 Melting Line and Vapor Pressures

These pressures P(T) are reported in [ 52] , where they are compared with other

data. Melting pressures are formulated by the Simon equation

P/P

t = 1 + A • [(T/Tt ) 6 -

1] , ( 1 )

(d/d

t ) = (T/Tt

) 1/4

( 2 )

3
Our recent vapor pressure measurements are compared with other data in [52] . Our

vapor pressure equation (3) is adjusted for the value of T

£

in the present report. Define

the argument x(T) - (1-T^/T)/(1-T^/T

c

) , when the equation is

XnfP/P^) = a- x + b* x^ + c* x" + d- x* (1 -x)^^ (3)

a = 4.7774 8580, c = -0 . 5678 8894,

b = 1.7606 5363, d = 1.3278 6231.

The rms deviation for 103 points is 0.014%.

2.3 The Orthobaric Densities

The data were reviewed in [26]. We now have omitted data near the critical point in

finding coefficients for the fitting functions, equations 4-a, 4-b, 4-c , because these data are

least accurate, and the fitting functions in the critical region are influenced only slightly by

these data. We include all data, however, in the comparison tables 1-A, 1-B, 1-C. Identifications in these tables are: ID = 1 for vapor densities obtained from the virial and vapor pressure

equations [ 23]; ID = 1 for liquid densities obtained from our isochore intersections with the

vapor pressure equation [30]; ID = 2 for vapor densities via the virial equation of this report;

ID = 5 for data of Jansoone et al . [ 39]; ID = 6 for data derived via Ricci et al. [ 53]; and ID = 7

for privately-communicated data of O . B. Verbeke [68]. Some of the latter data are assigned

two temperatures, differing by 0.02 K, due to uncertainties between different laboratories.

Identifications given by three or four digits are for densities via our dielectric constant measurements [29].

a) For the saturated vapor, define the variables —

x(T) = (T -T)/(T -T ) , u(T) = (T /T-1)/(T /T.-l) . c c t c c l

The function now is

€ 4/3 5/3 £n(p/p ) = a* x + b- x + c* x + d* x 4- e* x- u, (4-a)

c

e = 0.46, c = -8.657 3409,

a = -2.703 6003, d= 5.264 0362,

b = 3.1661552, e = -3.526 9034.

The comparisons are given in table 1-A

.

4
b) For the saturated liquid we use x(T) as defined above, and also,

W(x) a.(l-x

2/:>

) + b. (l-x

4/ 3

) + c. (l~x

2

),

in a function which is constrained both at the triple- and at the critical-points --

(p-p

c )/(p

fc -p ) = x

e -exp[W(x)] , (4-b)

« = 0. 36, b = 0.0483 8475,

a = -0. 1788 6 OI 65 , c = -0.01848987.

The comparisons are given in table 1-B.

c) The single -valued function T^(P), given by eq (4-c), is used for the equation

of state. Densities are obtained by iteration, using eqs (4-a) and (4-b) only to find the

initial density. Define the variables.

Y (T ) = (T /T - 1 ) /( T /T -1), a cO' c t

U(o) = expj^e • a- (o-o

t )/|o-l

[] ,

10

1 /3 , 2/3- * i-4

W(p)s A +A2 *tn(p) + A

3

'p + A

4

/(l+E-p ) + )/.'P

i=5

where a = d /d is a constant, e

t t c

= 1/ 2, and E = 8 . The function now has the simple form,

Y(T

o

) = U(a) •

’ [1 + (P -1) * W(p)]

Aj = 0.8432 0686, A, = 10.88693606,

A

2

= 0.1597 2304, A7

= -32. 4204 8700

A

3

= 0. 9783 7869 Ag

= 63. 1616 6459,

A4

= 0. 2865 4081 A

9

= -62. 7209 0242,

A5 =-1.7150 5402, A 10 = 25. 9249 8181

The comparisons are given in table 1-C,

The exponential form, U(o), used for T (p) in eq (4-c) was developed to give a O

well-behaved critical isotherm (non-negative slopes, SP/dp) for all reasonable assignments

(within the experimental uncertainties) of the critical point (p , T ) in the equation of state ( 6 ) c c Whereas the thermal computations circumvent this near-critical region, the equation of state is tied to the saturation boundary described as a function of density by eqs

(4-c) and (3). This may be the reason that we find the greatest deviations from experimental P-p-T data along isochores near the critical density, table 4.

5
2.4 Th® Virial Equation

For the virial equation of state,

Pv/RT = 1 + B(T)- a + C(T )-a

Z + . . .

the second and third coefficients, B(T) and C(T), here are dimensionless via reduced density, a = d/d We reduce the temperature, x s T/T , at the triple point. Sources of c t selected data in Tables 2-A, 2-B are: ID1 = Douslin [17], ID2 = Hoover [37], ID3 = Byrne [8], ID4 = Pope [51], and ID5 = Sengers [56], The virial coefficients are formulated

by completely new functions as follows,

B(T) = [b

i + B

2

/x 1/2 + B

3 /x + B

4

/k2 + B

s /x

3 ]

• f(x)

whe re

f(x) = 1 - (T /T)

o

B

505. 0 K,

16. 974 318,

-80.055 038,

1/4

B,

B £

123. 540 958,

-92.601 354,

42. 974 121.

The third virial coefficient is represented by

1/2 , 2

C(T) = [

C

1 /x 7 + c

2 /x + C

3 /x4 + C

4

/x

j

• f(x) >

whe re

f(x) = 1 - T /T,

o

C

1 = 0.36 212,

C 2

= 0.83 584,

139.922 K,

18. 69 531,

9. 15 517.

(5-a)

(5-b)

In the above equations we have defined the arguments, (l/x) n

, such that they have a maximum value of unity at the triple point. We therefore may keep the same number of

decimal digits in all of the least-squares coefficients. In this way one may ascertain that

the constants given here contain more than a sufficient number of digits for the precision

of data in tables 2-A and 2-B.

2. 5 The Equation of State

Experimental compressibility (P-p-T) data are given in various ranges by several

publications [9, 17, 30, 32, 39, 41 , 44, 49, 54, 65, 66, 72] . Michels ' data [ 49] are reviewed by

Douslin [17]. Compressed liquid data of van Itterbeek [65], as well as those found in the

monograph by Zagoruchenko [72], appear to be of lower accuracy than needed for thermal

computations

.

6
Data reproduced in the present report are summarized by table 3. For adjusting our equation of state we have used only three sets of data: 1) as computed by our virial

equation; 2) our published data [30] and our new data given in this report; and 3) the data

of Douslin et al. [17].

The present equation of state is novel in that it originates on the vapor-liquid

coexistence boundary. The melting line, however, is not a part of this equation of state.

It must be introduced independently.

By means of our function T^(p), eqn (4-c), we obtain the vapor-liquid coexistence

temperature for any density (isochore). Placing this in the vapor-pressure equation gives

the coexistence pressure P^[T^(p)]. This defines the equation of state as a function of

density on the vapor-liquid coexistence boundary. By subtraction we shift the origin to

this boundary.

This novel equation of state may be written in concise form by use of the variables,

x(T) H t/T , X (p) = T (p)/T , c GO c

Y(P, p , T) = (Z-D-x/p, Y (P) = (Z -l)-x /p , G GO

as follows

(Y-Y ) = B(p )

• X (p,T) + C(p) • X (p , T) + D(p) • X (p,T), (6 > c b c d

where B(p), C(p), D(p) are polynomial coefficients to be found by least squares, and the

X.(p, T) are functions both of density and temperature as a consequence of subtracting the

values at coexistence,

X

fe (p , T) = x.[l-exp(-p/k)] - xCT -|'l-exp(-$/xa )J

,

X (p , T) = 1/x - 1/x , c a

X ,(P , T) = F 1 -a) • “tn( 1+1 /<d )"|/ u - 1 -tw • tn( 1+1 /<jj )l/u . d L JLcj aJa

The last of these functions gives nonanalytic behavior for C^Cp, T) about the

critical point by use of the variables,

u(p , T) = T/6(p) , uu(P, T) - 6- (u-1) ,

u (p) =t (P) / 6 ( p ) , a) (P) = ^ ’ (u - 1 ) , G G G G

where 6 is an arbitrary constant, 9(p) is our locus of temperatures [18] inside the "dome"

of figure 1

,

7
0(p) s T

a

(p) • exp

[

- a .

| a - 1 ! 3

]

,

and T^(p) is given by eq (4-c) above. As described also in [26, 30], this is an empirical

equation which is qualitatively consistent with the experimental behavior of c

v

(P. T)

about the critical point.

The coefficients of (6) result from tedious investigations of various combinations

of polynomials,

B(p ) = B

q + B1

• p,

2 3

C(P) = C + C • p

4- C_ • p + c, • p , o 1 c 3 D(p) = (CT-1) . (D

o + Dj • p + D

2

• P 2

).

For application of the least squares technique, each of the above polynomials is multiplied

throughout by its temperature -dependent factor, X^(p,T) from eqn (6), to give nine leastsquares coefficients.

The constants for eq (6) are

a = 0.2, 6 = 7,

B = 1. 5991 01971,

o B = 2.4837 86733,

C = -1.0760 88156,

o C = 10.4821 92754,

6 = 1 .

C

2

= -22. 5567 15826,

C

3

= 12. 2896 65719,

D = 0. 9937 50233,

o D = -1. 2430 35021,

D

2

= 0. 3185 23715.

Table 4 gives a comparison of the experimental and calculated densities and

pressures. The reader should note that dp/BT and dp/dP become infinite at the critical

point. Density deviations therefore should be ignored in the critical region 0. 95 < T/T^ <1.1.

For compressed liquid at low temperatures the derivative dP/dp becomes extremely large,

such that small experimental errors in density will yield (via the equation of state) deviations of calculated pressures greatly exceeding the accuracy of pressure measurements.

In this domain the equation of state should be used only to find p(P, T).

2. 6 Representation of C^fT) at 18. 5 mol/jf

For use below in 3. 4 we have adjusted experimental specific heats of several runs

by Younglove [71] to the density of 18. 5 mol/j&, and then have represented these data by use of the argument, x(T) ® T/0(p), 9 = 164. 1171 K:

8
C /C° = 1 + a/x + b/x^ + c/x^/(x-l)°* ( 7 ) v v

a = 0. 472 950, b = -0. 502 717, c = 0. 214 2134

where C^fT) is the ideal gas specific heat as tabulated in [21], and as calculated by our SUBROUTINE IDEAL reproduced in Appendix E.

3. Computational methods

The numerical values for E and H in this report are on the same absolute basis

as those of Tester [61], obtained by use of E° = (4. 1868)* (2191. 3) J/mol. This not only

permits a direct comparison of results; it also precludes negative values for these functions

in compressed liquid states.

3. 1 The Homogeneous Domain

With reference to figure 1, we start our computations with ideal gas values described in T21] as a function of temperature at zero density, and then integrate along isotherms by use of the equation of state in the following relations,

AE = fp - T-(dP/ST)] .dp/p

2

, (8)

AC‘v

= -Ty'(B

2p/5T 2 ).dp/p

2

, (9)

ln[p°/(pRT )]+f[R-(Sp/5T)/p] • dp /p . (10)

Equation (10) is for use with initial entropies in hypothetical ideal gas states at P° = 1 atm.

In the compressed liquid at T< T we use

c

AS = -J(d P/9T)-dp/p

2

In each (p, T) state, reached by above integrations, we compute

H = E + P/p ,

2 2 C =C + T* (dP/d T) /(9P/dp)/p , P vW = C • (dP/dp ) /C

P

v

( 1 0 -a)

( 11 )

( 12 )

(13)

9
I

3.2 The Vapor-Liquid Transition

At T< T of figure 1 we traverse the vapor -to -liquid "dome" by use of the Clapeyron cL ®quations and Av s (v^-v^),

AH = T. (dP/dT). Av , (14)

AE = AH - P- Av , (15)

AS = AH/T (16)

where (dP/dT) is slope of the vapor pressure curve. We then obtain the specific heat of

liquid along the coexistence path via

C (T) = T- (dSa /dT) . (17)

The single -phase specific heats C (p , T) may be estimated on the s from the following difference [55] ,

aturated liquid boundary

C (p.T) = C (T) + T.(9P/BT).(dp ,/dT)/p

2

V O i, \> (18)

where (dp^/dT) is the (negative) slope of saturated liquid density vs T. Each term on

the right of (18) approaches infinity at the critical point, where the accuracy of computation

vanishes. For this and other reasons we have computed around the critical point, by use of

experimental C data at 18.5 mol/'t, as discussed below for the cross-hatched region

of figure 1

.

10
3.3 Representation of E (T) and S (T) a a Having computed these functions for saturated liquid, we give them analytical

representations to avoid repetitive integrations. The following representations are accurate

within 0,001% at any point, and each gives an rms deviation less than 0.0005% for 52 points at

T^_ S T . For consistency in the thermal network we compute C^T) by eq (17), above.

For internal energy, use these variables

x(T) = (T - T)/ ( T -T ) , c c t

Y(E) = (E-EJ/(E -E ) , t c t

W(x) =

when the function is

B = 0. 10,

e 0.19,

E

t = 3471.853,

E = 10819.568,

c

For the entropy,

V • x - -tn(l + B/x) + A *x

£ +

1 ^

Y(E) = ( 1 -x)* exp[W(x]

A

t = -0.0294 0994,

A2

= -01915 4778,

A 3

= -0.6745 4649,

A4

= 3.1 155 4755,

define x(T) as above, and c

Y(S) = (S-S

t )/(S

c -S

t

),

i=3

A5 = -9. 7180 4579,

A6

= 17. 1576 6593,

A?

= -16. 5038 8861

Ag

= 7. 7926 2156,

A9

= -1. 3662 1087.

so

(19)

8

e 1/2 V' i -2

W(x) = A • x • -tn( 1 + 1 /x) + A^x 4- A^-x + / j A . • x , i=4

1

when the function is

Y (S) = ( 1 -x)- exp[W(x)] , (20)

e = 0. 19, A3 = 0.0687 0234,

st = 67. 87 832, A4

= 1. 6874 3215,

S c = 120.46 263, A5

= -5. 3312 1801,

Aj = -0. 1566 0939, A6

= 9.0640 7137,

II <CM -0. 1727 1532, A 7

= -7. 5434 7331,

A8

= 2.43529834.

11
3.4 Circumventing the Critical Domain

The computations of section 3 become inaccurate along isotherms near T . As

c T-T" the heats of vaporization become increasingly uncertain, and the accuracy obtained + from eq (18) vanishes. As T- the slopes and curvatures of isochores are insufficiently

well known to give reliable results. We therefore have used the following procedure to com

pute around the critical point into the cross-hatched region of figure 1: We select the isochore of experimental specific heats at p'~ 18.5 mol/i, which

intersects the liquid-vapor boundary at T = 174.516 K. We then select T = 220 K, oba b taining --

E(p'. T ) = 9874.3 J/mol, S(p', T. ) = 1 1 3. 9 1 2 J/mol/K

.

b b By use of (7) for CMP*, T) we then integrate down to any T^< T<

AE C -dT,

v L

AS = / C -dT/T

We finally integrate along isotherm T as described among eqs (8) through (13). For the

cross-hatched region of figure 1 we thus obtain all of the thermofunctions without crossing

the "dome" near T , and without passing close to the critical point at T>T

c>

In the above computation around the critical point (on isotherm and then along

isochore p

' of figure 1) we wish, for consistency, to obtain values of functions for the saturated liquid at T which agree with values obtained by computing across the vapora

liquid "dome" on isotherm T . To obtain agreement for the internal energy, E, and for

the entropy, S, it is necessary to multiply the specific heats along isochore p eq (7), by

the factor 0. 9737. This adjustment of about 2. 6% is larger than the estimated uncertainty

in experimental, single-phase specific heats (71]. One must remember, however, that

until recently it was considered by many that specific heats computed via the second de2 2 rivative 3 P/?T from an equation of state were considered "good" if they were within

10% of the experimental measurements.

4. Comparison of Derived and Experimental Properties

4. 1 Heats of Vaporization

This property is notoriously difficult to measure accurately, and results from

two laboratories are not in good agreement ( 36, 70] . Their data have been tabulated in [21].

Present results agree best with those of Hestermans and White [36], namely within about

12
two percent at worst (high temperature). At 100 K our heat of vaporization of 8512 J/mol

is in excellent agreement with the experimental value, 8514 ± 21 J/mol, obtained by

Cutler and Morrison [11].

4. 2 Specific Heats, C (T), C (o, T), C (p, T)

<7 V p

Specific heats C^(T) on the coexistence path have been derived from heat capacity

measurements on the two-phase, liquid-vapor system by use of existing vapor pressure

and saturated liquid density data [71]. Results therefore are not directly experimental,

and may have greater uncertainty than the observations [31]. These recent data of

Younglove are compared with our derived results in table 5. The maximum deviations

between calculated and measured C^(T) are about two percent. Cutler and Morrison [11]

give specific heats of the saturated liquid from 93. 95 to 106. 96 K. Our calculated value

of 53. 31 J/mol/K at 95. 85 K may be compared with 54. 13 from [71], and with 53. 43 at

95. 77 K from [11].

Experimental specific heats C^(p, T) for compressed fluid methane [71] are compared with our derived results in table 6. The maximum deviations between calculated and

measured C^(p, T) are about four percent.

Specific heats at constant pressure C (p, T) have been measured with a flowP

calorimeter over a wide range of conditions. These data are smoothed and interpolated [40].

Table 7 gives these data on the first row of each isotherm. The second row was computed by

present methods. Except near the critical point the maximum deviations between calculated

and measured C (p, T) are about two percent, which we consider to be excellent.

P

4. 3 Speeds of Sound, W^T), W(p. T)

Tables 8 and 9 compare experimental speeds of sound for saturated [63] and compressed liquid [64] methane with our calculated results. In eqn (13) of section 3, above,

we have seen that this calculation is complicated. It is based on all previous calculations

via the derived specific heats. In view of this complexity, we consider that the agreement

within two percent between calculated and measured speeds of sound is good, and supports our use of the present, simple form of equation of state.

5. Tables of Physical and Thermodynamic Properties

5. 1 Calculated P-p-T Isochores and Isotherms

A selection of calculated isochores and isotherms is given by tables 10 and 11.

They are useful to examine behavior of the surface generated by the equation of state, and

to supplement the isobars of table 14 in obtaining P-p-T values and their derivatives.

Table 11 includes derivatives with respect to density of functions composing the equation

of state, to verify that the analytical expressions used for these derivatives are correct.

13
5. 2 The Joule-Thomson Inversion Locus

Tables 12 and 15 give oar calculated P-p-T locus for the J. T. Inversion,

(9T/9P) = 0. These results are obtained from the equation of state under the condition, n

T* (dP/dT) = p • (dP/dp). They are in good agreement with earlier results [24, 61],

considering sensitivity of the computation and engineering requirements.

5. 3 Thermophysical Properties of the Saturated Liquid

Tables 13 and 16 give physical and thermodynamic properties for the saturated

liquid. Column headings are interpreted on the first pages of these tables. Results are

similar to our earlier tabulation [24] except at T > 160 K where the effect of our recently

measured vapor densities is evident. Saturated vapor volumes and heats of vaporization are smaller than in [24] by up to 1.5 percent as T -+ T . At temperatures above T = C SL 174. 516 K, however, we have computed around the critical point as described in section

3. 4.

5. 4 Thermophysical Properties Along Selected Isobars

Tables 14 and 17 give physical and thermodynamic properties on isobars, as computed by methods of section 3. Explanations for the tables are given on the first pages.

These tables are extrapolated beyond the range of P-p-T data used for adjusting the equation

of state (T ~ 400 K, P ~ 350 bar).

6.

Tables in British Engineering Units

Thermophysical properties in engineering units are given in tables 15, 16, and

17 at integral temperatures on the Fahrenheit scale and at integral pressures in psi. The

conversions of unit% given in Appendix C, are taken from [3, 48]. Explanations for the

tables are given on the first page of each table.

7.

Comments on Uncertainties

For the important saturated liquid densities, the precision of about 0. 01% in

representation by eq (4-b) greatly exceeds the estimated absolute accuracy of about 0. 1%

in the data.

For other P-p-T data, the differences between calculated and experimental values are detailed by table 4. Greatest experimental uncertainties of about 0. 1% occur in the

determination of density. Deviations of table 4 are no greater than 0. 1% over most of

the P-p-T surface. Approaching the critical point, however, they become much greater

(up to about 1. 0%) over the critical region: 0. 9 S T/T < 1. 2, 0. 3 < p/p Si. 7. The

c c equation of state (6), however, is qualitatively correct in the behavior of its derivatives

about the critical point. We may generalize by the statement that the densities of table 14

(isobars) are accurate to 0. 1% except in the critical region.

14
The absolute accuracy of thermodynamic functions, computed by equations of section 3, necessarily is less than that of P-p-T data, due to the use of derivatives of

the P-p-T surface, and especially to taking differences, eq (8). This fact, mentioned

in [22], places extreme demands on the equation of state. The accuracy of enthalpy

differences is estimated by comparing our specific heats at constant pressure with

experimental data in table 7. Except very close to the critical point (190. 5 K, 46. 0 bar),

the differences mostly are no greater than 2%. With this exception, therefore, we

estimate the accuracy of enthalpy differences in table 14 (isobars) to be about 2%,

The experimental specific heats from [71] were estimated to be accurate to

0. 5%, except approaching the critical point. For the saturated liquid, however, we

mentioned above that other data used to derive C (T) could produce higher uncertainty.

GF Table 5 shows maximum deviations of about 2% near 145 K. We estimate the accuracy

of our calculated C^(T) to be 1%. Excepting the critical region, we estimate the accuracy

of our calculated C (p , T) to be about 3%, and of C (p,T) to be about 2%. v p

The experimental speeds of sound were estimated to be accurate to a few tenths

of one percent [63, 64], As our results in tables 8, 9 differ by a maximum of about 2%, we conclude that calculated values in table 14 (isobars) have an accuracy of 2%.

8. Acknowledgments

We are indebted to The American Gas Association for generous support of this

work, to Robert D McCarty for the essential least-squares program [38, 47], and to Dwain

E. Diller and Lloyd A. Weber for discussions and valuable suggestions.

15
9. References

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16
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18
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19
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\

20
Appendix A. Symbols and Units

Subscripts c and t refer to critical and liquid triple points.

Subscripts g and l refer to saturated vapor and liquid.

Subscripts a or s refer to liquid-vapor coexistence (usually the liquid)

or, 0, 6 non-linear constants in the equation of state

B, C, D. density-dependent coefficients in the equation of state

CV

(P,T),

C

p

(P * T),

Cc

(T),

d,

molal heat capacity at constant volume, J/(mol*K)

molal heat capacity at constant pressure, J/(mol*K)

molal heat capacity for saturated liquid, J/(mol*K)

density, mol/'t

E(p.T), the internal energy, J/mol

H(p.T). the enthalpy, J/mol

J, the joule, 1 N-m,

l, the liter, 10“^m^,

mol, 16.043 grams of methane ( C* ^ = 12 scale)

P,

C O pressure in bars, 1 bar = 10 N/m

Q , vap

R,

AH , the heat of vaporization, J/mol

vap

the gas constant, 8.31434 J/(mol*K),

0.0831434 bar-£/(mol* K),

P, d /d

f density reduced at the liquid triple point

, *

<J, d/d

c , density reduced at the critical point

S(P.T), the entropy, J/(mol*K)

T, temperature, K, on the IPTS-1968, [1]

v, 1/d, molal volume, t /mol

W(p, T), the speed of sound, meters /second

x, T/T , temperature reduced at the critical point

_c z, Pv/RT, the "compressibility factor"

21
Appendix B. Fixed-Point Values*

Triple Point

d^ = 0.01567865 mol/£, vapor

d^ = 28. 1470 mol/t, liquid

P = 0.11590 atm

= 0.117435675 bar

T = 90. 680 K (IPTS-1968)

Critical Point

d = 10.0 mol/t

c P = 45.98825 bar

c T = 190.555 K (IPTS-1968)

c

* These values were used for the thermodynamic computations

exactly as given.

22
Appendix C. Conversion of Units

Reference [3]

Temperature

1. 8 Rankine (R) = 1 Kelvin, (K)

Pressure, 14, 69595 psi = 1 atm = 1. 01325 bar

Volume, 1 cu ft = 28. 31685 liter, (l)

Mol. Wt. , CH , 4

1 mol , 12

= 16.043 gram, (g), (C scale)

Mass, 1 lb (avoir .

)

= 453. 5924 g

Density, CH^, 1 Ib/cu ft = 0. 998 470 mol /l

Isochore slope, 1 PSI/R = 0. 1241 056 bar/K

Isotherm slope, CH^, 1 PSI- cu ft/lb = 0.0690 5319 bar. -t/rnol

Energy 1 BTU = 1054. 350 joule, (J)

Specific energy for methane, 1 BTU/lb = 37. 291 055 J/mol

Specific entropy and heat

capacity for methane, 1 (BTU/lb) /R = 67. 123 912 ( J/mol) /K

Speed of sound, 1 ft/s = 0.30480 m/s

23
Appendix D. List of New Data

1. The melting pressures, [52],

2. The vapor pressures. [52]

3. Freezing liquid densities, [23].

4. Saturated liquid densities, [30],

5. Saturated vapor densities, [29].

6. P-P-T compressibility data [30].

7. P-p-T compressibility data [this report].

8. Dielectric constants on isotherms [29].

9. Dielectric constants for saturated liquid [29].

10. Dielectric constants for saturated vapor [29].

11. Specific heats (MT) for saturated liquid [71].

12. Specific heats CMP , T) over a wide range [71].

24
ooooo

ooo

Appendix E. Computer Programs

05/14/73

PROGRAM METHERM5

C COMPUTE METHANE THERM0FUN3TI0NS, JANUARY, 1973.

COMMON 81,82, C 1 , C2 , C 3 ,

4 , E1,£2,E3

COMMON/ 1/ AG, AL , BE ,0E, GK, DCRT , PCRT , TCRT , OTRP, PIRP , T TRP

C0MM0N/3/0P0T,02PDT2, OPSO T , DPMO T , DPDO , OPOR , OTS DR , OT HDR

CQMMON/8/ P, T, OEN, E,H,S, CY,CP,N, WK

COMMON/ 9/ CS AT

C0MM0N/99/TIf£ZZ, E Z, SZ , C V Z , HZ ,CPZ

DIMENSION PP(99) ,CF (99> ,CY (99)

1 FORMAT ( 17 , F9.3, 55X F8.3)

2 FORMAT ( 1H1 17X ’COMPARISON OF METHANE CSAT, J/MOL/K * //

1

1 8 X 2HID 7X3HT , K 6X4HCS AT 6X4HCALC bX4HPCNT)

3 FORMAT i 15X 15, 3F10.3, F10.2)

4 FORMAT ( 2X 13F6.0)

5 FORMAT ( IX)

6 FORMAT ( 15, F8. 0 , 15X F9.0, Fd.O, F9.Q)

7 FORMAT ( 1H1 17X ’COMPARISON OF METHANE CV, J/MOL/K //

1 18X 2HI0 7X 3HT , K 5X5HP,3AR 5X5HM0L/L 4X6HC,XPTL 4X6HC,CALC

2 6X4HPCNT)

8 FORMAT ( 15X 15, 5F10.3, FIG. 2)

9 F ORMAT ( 1H1 44X ’COMPARISONS OF CP(J/MOL/KJ FOR METHANE* //

1 13X 7HP, BAR = 13F8.2/ 1JX 4HT , K ) 10 FORMAT ( 1H0 9X FIG. 3, 13F3.2)

11 FORMAT ( 20 X 13F0.2)

12 FORMAT ( 1H1 16X *COMPARISON, SPEEOS OF SOUNC, SATURATED LIQUID METH

1ANE*//17X3HT ,K 5X5HP,BAR 5X5HM0L/L 5 X5HM/SEC 5X5HCALC0 6X4HPCNT

)

13 FORMAT ( 1H1 15X ’COMPARISON, SPEEDS OF SOUND, COMPRESSED LIQUID MET

1HANE*//17X3HT,K 5X5HP,9AR 5 X5HM0L/L 5X5HM/SEC 5X5HCALC0 oX4HPCNT)

14 FORMAT ( 1GX F10.2, 2F1Q.3, 2F10.1, F10-2)

15 FORMAT < 8F10. G)

16 FORMAK//////// 1H1 18X ’METHANE ISOBAR AT P =*F6.1, 4H BAR / /

1 19X 1HT 6X3HDEN 6X3HV0L 5X5HDP/DT 5X5HQP/DQ 8 X 1 HE 8 X 1 HH 8X1HS

2 oX2HCV 6X2HCP 5X1HW /

3 15X 5HDEG K 4X5HM0L/L 4<5HL/M0L 5X5HBAR/K 1 X9HB AR- L/ MOL 4X5HJ/MQL

4 4X5HJ/MOL 2X7HJ/MOL/K 1 X7HJ/MOL/K 1X7HJ/M0L/K 1X5HM/SEC ) 17 FORMAT ( 10 X F10.3, F9.3, F9.5, F1C.4, F10.3, 2F 9 . 1 , F 9 . 3 , 2F 8 . 2 ,Fo . 0

)

itt FORMAT C1GX F10.3, F9.5, F9.3, F1C.6, FIG. 3, ?F 9 . 1 , F9 • 3 , 2F 8. 2 , Fo . 0

)

CONSTANTS OF EQNSTATE-8, 5/11/73, AT 10.46, NF = 9

NOTE ARBITRARY CONSTANT, OE, IN PSI, XEF ( T , D)

20 TTRP=90.b8Q i DTRP=23.147 i P TRP - G . 1 17 4 356 75

21 TCRT=190.555 % DCRT=10.0) S PCRT= PSA TF ( TCRT

)

22 AGsAL-Q. 2 t t3E = 7 $ OI = i t GKK= 0. 18 31*34 t GK=D TRP’GKK

23 61 * 1.599101971 t b2 = 2.*8378b733 I Cl = -1.0 760 86153

24 C2 = 10.48219275* % C3 = -22 - 556 7 15826 t C4 = 12.286fcb57l9

25 El = 0.993750233 i E2 = -1.2*3035021 $ E 3 = 0.3 135237 15

28 UP = 1 . 01325 I EZZ = 4. 1363*2191. 3 4 WK = 1 0 0 0 GO /

1 . 0 4

29 QPP = 14. 69595/ QP 4 T A = 174.516 4 TB = 220

DERIVE THE J-T INVERSION 3URVE.

99 CALL JTLOCUS

TABULATE THE SATURATED LIQUID FUNCTIONS.

100 CALL TABLIQ

COMPUTE THEKMOFUNCTIONS ON ISOBARS -

25
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METHERM5 05/14/73

EVERT ISOBAR STARTS OS THE MELTING LINE AT T UNDER TORT.

ISOBARS AT P UNDER PORT TRAVERSE THE DOME.

SPECIAL CASES FOR REGION X AT TA=T=TB, DEN ABOVE DCRT

LET THE FIRST ISOBAR 3E AT P = PTRP.

149 NI = 67 $ PPtl) = PTRP

150 RE AO 15, (PP(I) ,1 = 2, SI)

151 DO 300 1=1, NI $ P = PP(I) S PRINT lb, P 152 CALL MELTHERM $ V = 1/QEN

153 PRINT 17, T , OEN , V , DPDT,OPOO, E,H,S, CV,CP,W

154 IT = T/5 J IF (P.LT. PCRT) 155,200

CASES FOR P LESS THAN PCRT.

155 TS = FINDTSF(P) % TX = TS+5

156 DO 199 J= 1 » 99 t T = JT = 5*

157 IF(T.LT.TA) 158,175

NORMAL CASES FOR P UNDER PCRT,

158 IF(T.LT.TS) 159,161

CASE FOR COMPRESSED LIQUIO AT

159 CALL THRMOLIQ $ V = 1/TEN

160 PRINT 17, T , OEN , V , DPDT , OPDD

,

161 IF(T.LT.TX) 162,183

CASE FOR SATURATED LIJUIO AND

162 IF(I.Ea.l) 163, lo4

163 PRINT 5 S GO TO 166

164 CALL SATLQTRM l V = 1/OEN

165 PRINT 17, T , DE N , V , DPOT,OPOO,

166 CALL SATGSTRM t V = 1/0EN

167 IFtP.LT. 20.0 ) 168,169

168 PRINT 18, T , DEN , V , DPDT , OPDD

,

169 PRINT 17, T , DEN , V , DPDT.JPDO,

170 T = JT * GO TO 183

CASES FOR P UNOER PCRT, T OVER

175 IF(T.LT.TS) 176,176

CASE FOR COMPR. LIQ. AT TA = T 176 CALL THERMOX t V = 1/OEN

177 PRINT 17, T , DE N , V , OPDT,9PDO,

178 IF(T.LT.TX) 179,183

CASE FOR SAT. LIU. IN REGION X,

179 CALL THERMXL l V = 1/DEN

180 PRINT 17, T , DE N , V , 0° DT , )PDD , 161 CALL SATGSTRM $ V = 1/OEN

182 PRINT 17, T , DEN , V , DPDT, OPDD,

CASES FOR HOMOGENEOUS DOMAIN,

183 IF (JT-300) 188,188,164

184 K = K*1 $ T = JT = JT f 5*K

185 IF ( JT-^00 ) 188,188,136

186 L = L+l $ T = JT = JT 10*

187 IF ( JT-5 00 ) 188,188,30 0 188 CALL THRMOGAS t V = 1/ OEN

169 IF (P.cT.20.0) 190,191

190 PRINT 18, T , DE N , V , DPDT, OPDD,

191 PRINT 17, T , DE N , V , D^OT.JPDO,

199 CONTINUE

S K = L = 0 (IT+J)

T UNDER TA.

T UNDER TA.

£ , H , S , CV,CP,W J GO TO 199

VAPOR.

E , H , 5 , CV,CP,W * PRINT 5

E,H,S, CV,CP,W J GO TO 170

E,H,S, CV,CP,W

TA, IN REGION X.

= TSAT IN REGION X.

E , H, S , CV,CP,W $ GO TO 199

AND SAT. VAPOR.

E,H,S, CV,CP,W I PRINT 5

E , H , S , CV , CP » W * T = JT

D UNDER DG, OR T OVER TC.

E,H,S, CV,CP,W f GO TO 199

E,H,S, CV,CP,W

CASES FOR P GRtATER THAN PCRT.

26
METWERM5 05/1 4/73

200 K = L = 0 S DO 230 J=l,99 $ T = JT=5* ( IT+ J) $ IF(T.LT.TB) 201,220

201 IF(T.LT.TA) 202,205

202 CALL THRMOLIQ $ V = 1/OEN

2 U 3 PRINT 17, T , DE N , V , OPDT,OPOD, E,H,S, CV,CP,W J GO TO 230

205 IF<T.LT.TCRT> 211, ZOo

206 PX = PVTF (T ,OCRT) $ IF(P.GT.PX) 211,225

C CASE FOR REGION X AT TA = T = TB, P ABOVE CRITICAL ISOCHORE.

211 CALL THERMOX $ V = 1/OEN

212 PRINT 17, T , DE N , V , DPDT , DPDD , £,H,S, CV,CP,W $ GO TO 230

C CASES FOR HOMOGENEOUS DOMAIN , D UNDER DG , OR T OVER TC.

220 IF (JT-300) 225,225,221

221 K - K*1 J T=JT : JT * 5*K

222 IF ( J T~4 0 0 ) 225,225,223

223 L = L*1 $ T = JT = JT f 10*L

22 A IF ( JT-5 00 ) 225,225,300

225 CALL THRMOGAS $ V = 1/OEN

226 PRINT 17, T,OEN,V, OPDT,OFOO, E,H,S, CV,CP,W

230 CONTINUE

300 CONTINUE

999 STOP $ END

SUBROUTINE JTLOCUS

C DERIVE THE J-T INVERSION CURVE. USE ROUTINE DE L T AF ( T , DI )

DIMENSION TT(99> ,PP(J9> ,DN<99)

DATA (OCRT=10.0 ) , (TCRT=1 00. 555)

1 FORMAT ( 1H1 lbX * THE JOULE- THOMSON INVERSION LOCUS FOR METHANE*//

1 1 7X 3HT , K 5X5HP , BAR 5X5H10L/L 7X3HT,K 5X5HP,BAR 5X5HM0L/L)

2 FORMAT ( 1GX F10.0, 2F10.2, F10.0, 2F10.2)

9

PRINT 1 $ DO 25 1=1,68 S T = 155 5*1 % DX = 1.6

10 DI = DCRT* (2.70816 - 0 . 7 0 26 3* T /TCR T ) $ IF(T-TCRT) 11,12,12

11 DL = OENLIQF(T) S IF(OI-OL) 25,12,1?

12 SS = DEL T A F ( T , D I > 13 DO 20 I T = 1 , 1

14 D= DI"DX $ SL=OELTAF (T ,D) * D = DI«-DX * SP = OEL T AF ( T , D

)

15 IF(SS-SL) 16, lb,

d

lb IF(SP-SL) 19,17,17

17 SS = SL J DI = DI - DX i GO TO 20

18 IF(SS-SP) 2 0,20,19

19 SS = SP t DI = DI * DX

20 DX = OX/2 t D = DI * P = PVTF(T,D)

21 IF ( T-TCRT) 22,23,23

22 PS = PSATF(T) $ IF(P-PS) 25,23,23

23 TT ( I ) = T i PP(I)=P 5 ON(I>=D

25 CONTINUE

26 DO 29 J = 1 , 3 4

29 PRINT 2, T T ( J) , PP ( J ) , ON ( J) , TT ( J + 34) , PP ( J+ 34 ) , ON ( J* 34

)

30 RETURN $ END

FUNCTION OEL TAF ( T , D

)

C GET ( T*OP/DT - D*DP/JJ) FOR THE J-T INVERSION CURVE.

COMMON/3/DPOT, U2PDT2, OPS JT , DPMDT , DP DO , DP OR , D TS DR , O T HO*

DATA (DCRT=10.G) ,(TCRT=190.555)

1 IF ( T-TCRT) 2,4,4

2 DL = DENLIQF(T) $ IF(D-DL) 3,4,4

3 OtLTAF = 1.0E4U10 « RETURN

4 P = PV TF ( T , 0 ) S PX = OPDRF ( T , D

)

5 DEL T AF = A 3SF ( T OP DT“ D* DPDD ) S RETURN S END

27
05/14/73

SUBROUTINE TABLIQ

C TABULATE THE SATURATED LI1UID FUNCTIONS.

COMMON/ l/AGfALtBEfDEf&K, DCRT , PCRT , TCRT , DTRP, PTRP , TTRP

C0MM0N/3/DP0T,D2P0T2, DPSOT , DPMDT , DPDO, DP DR , DTSDR , DTHDR

COMMON/8/ P,T,OEN, E,H,S, CV,CP,W, WK

C0HH0N/9/ CS AT

1 FORMAT ( 1H1 13X ’PROPERTIES OF SATURATED LIQUID METHANE’ / ) 2 FORMAT ( 14X1HT 7X1HP 5 X3HOEN 4X5HV, GAS 4X5HV,LIQ 3X5HDP/DT

1 3X6HODL/DT 3X5HQ,VAP 7 X 1HE 7X1HH 7X1HS 6X2HCV oX2HCS 6X 2HCP6X1 H W/

2 1QX5H0EG K 5X3HBAR 3X5HMOL/L 4X5HL/M0L 4X5HL/M0L 3 X5HBAR/K

3 2X7 HMOL/L/K 3X5HJ/M0L 3X5HJ/MOL 3X5HJ/MOL 1 X7 HJ/MOL/K

5 1X7HJ/MOL/K 1X7HJ/MOL/K 1 X 7 H J/MOL / K 2X5HM/SEC ) 3 FORMAT ( 7X 3F8.3, F9.4, F).5, F8.4, F9.4, 3F8.1, F8.3, 3F8.2, F7.0)

9 T A = 174.516 Z PRINT 1 Z PRINT 2 10 DO 30 U = 1 , 52 Z IF(J.EQ.l) 11,12

11 TT = TTRP S GO TO 15

12 IF ( J • Ed • 52 ) 13,14

13 TT = TCRT I DG = DL = DCRT Z V G=VL=l/OG S GO TO 17

14 TT = 88 + 2*

J

15 OG = FINDSATF ( TT , 0 ) Z VG = 1/DG

16 OL = FINDSATF ( TT , 1 ) I VL = 1/DL

17 PS = PSATF(TT) Z Q = 130’TT’DPSDT’ ( VG- VL > 18 IF (TT.LT.TA) 19,21

19 S = SSATF(TT) i E = ESATF(TT) Z H = E + IGO’PS’VL

20 GO TO 23

21 P = PS $ CALL THER'I XL Z IFU.EQ.52) 22,23

22 UDLDT=CSAT=CV=CP=W=0 Z GO TO 30

23 PX=PVTF (TT ,DL) Z PX =DPORF ( TT , DL ) Z OQLDT = DTRP/DTSDR

24 C V = CS AT 10G’TT’DPDT’ODLOT/DL”2

25 CP = CV + lQO’TT/DPID’ (DP0T/0L)”2

26 W = SQRTF (WK*CP’QPOD/CV)

30 PRINT 3, T T , PS , DL , V G , VL , DPSDT , DDL DT , Q,E,H,S, CV,CSAT,CP,R

99 RETURN Z ENO

FUNCTION FINDTHF(P)

C GIVEN MELTING PRESSURE P, ITERATE T TO MINIMIZE (P-PC).

COMMON/ 3/DPOT, 0 2PDT2, OPS 3 T , DPMOT , DPO D , DP DR , DTS DR , DT HD

R

1 FORMAT ( 1H0 9 X ’FINOTMF = 0, FAILS TO CONVERGE) ’ / ) 2 T = 100 Z DO b J = 1 , 5 0 Z OP = P-PMELTF ( T ) f ADP = ABSF(DP)

3 IF (AOP/ P-1 . OE-6 ) 7,7,4

4 I F ( A OP/ OPMOT/T-l.OE-o) 7,7,5

5 T = T OP/DPMUT

6 CONTINUE Z FINOTMF = 0 Z PRINT 1 Z RETURN

7 FINOTMF = T Z RETURN $ END

FUNCTION FINOTSF (P)

C GIVEN VAPOR PRESSURE P, ITERATE T TO MINIMIZE (P-PC).

COMMON/ 1/AG, AL , BE , OE , G<, DCRT , PCRT , TCRT , D TRP, PTRP , TTRP

COMMON/ 3/D POT, D2PDT2, DPS )T, DPMOT , OPDO , DP DR , DTSDR ,DTHOR

1 FORMAT (1H0 9X ’FINOTSF = 0, FAILS TO CONVERGE. ’ / ) 2 FORMAT ( 1H0 9X ’FINOTSF =0, P EXCEEDS PCRT. / ) 3 IF ( P-PCRT ) >4,11,12

4 T = 150 Z DO 9 J = 1 , 50 Z OP = P - PSATF(T) Z ADP = ABSF(OP)

5 IF (AOP/P-1. OL-b) 10,10,6

6 IF (AOP/OPSDT/T-1. 0E-3) 13,10,7

7 T = T ’ OP/OPSDT Z IF(T-TCRT) 9,9,8

8 T = TCRT

9 CONTINUE Z FINOTSF =0 Z PRINT 1 Z RETURN

1 0 FINOTSF = T $ RETURN

1 1 FINOTSF = TCRT S RETURN

12 FINDTSF = 0 Z PRINT 2 Z RETURN Z END

28
05/14/73

FUNCTION FINOENF (T , P)

C ON ISOTHERM T, FIND DEN, NQL/L, TO MINIMIZE (P-PC) VI ft EQNSTATE.

COMMON/l/AG,AL,B£,Q£,GK, OCR! , PCRT , TCRT , DTRP, PTRP, TTRP

CQMM0N/3/DP0T,02PDT2»DPS0T,0PM0T ,DPDO, OPDR, OTSOR ,OTHOR

41 FORMAT ( 1H0 9X *FlWO£NF s 0, FAILS TO CONVERGE. * / > 42 FORMAT ( 1H0 9X * FINOENF = DCRT , DP/OR ZERO OR NEG. * / ) 43 FORMAT C 1H0 gx *FXNQENF = 0, DOUBLE- VALUED AT P = PSAT. * / ) 1 OM « DTRP* (T/TTRP) **0 .25 S IF (T-TCRT) 2,5,8

2 OG=FINDSATF ( T» 0 ) Z DL=FINDSATF C T , 1 S Z PS=PSATF(T)$ IF(P-PS) 3,32,4

3 0 * 05/2 S GO TO 11

4 0 * (0L*DM)/2 $ GO TO 11

5 OGsQLsQGRT S PS=PCRT I IF(P-PS) 0,33,7 60* DCRT/2 $ GO TO 11 70= 2*0CRT $ GO TO 11

8 IF (T.LT. 300.0) 9,10

9 PC = PVTF C T» OCRT ) * IF (P-PC) 6,33,7

10 Q = DCRT

11 00 30 J=l, 50 $ DPsp-OPDRF (T,D) $ IF(ABSF (DP/P)-1.0E-6) 31,31,1

12 IFCDPDOS 34,34,13

13 00 = OP/OPOD Z IF (4BSF (00/0) -l.OE-6) 31,31,14

14 0 = 0 DO S IFCO.GT.O. 001) 16,15

15 0 = o.OOl % GO TO 30

16 IF (Q.GT.DM ) 17,18

17 Q * OTRP Z GO TO 3Q

18 IF (T-TCRT ) 19,24,30

19 XFCP.LT.PS) 20,22

20 IF(D.GT.OG) 21,30

21 0 = DG S GO TO 30

22 IFCD.LT.DL) 23,30

23 0 = DL Z GO TO 30

24 IF (P.LT.PCRT) 25,27

25 IF (O.LT .DCRT ) 30,26

26 D s DCRT - 0.02 Z GO TO 30

27 IF (O.GT.OCRT) 30,28

26 D = OCRT 0.02

30 CONTINUE Z FINOENF = 0 S PRINT 41 Z RETURN

31 FINOENF =0 Z RETURN

32 FINOENF * 0 t PRINT 43 % RETURN

33 FINOENF = DCRT S RETURN

34 FINOENF s DCRT Z PRINT 42 $ RETURN * END

FUNCTION DENGASF (I

)

C DENSITIES OF SATURATED METHANE VAPOR, MOL/L.

C L N ( O/DC) = A1 *W**E A2*W A3*Q**4 A4*Q**5 A5*U*H.

C Us CTC/T-1) / (TC/TT-1) , W = ( TC-T) / ( TC-TT )

DIMENSION A ( 5

DATA ( T TRP = 9 0 .68) , ( TCRT= l 90 . 555 ) ,

( DCRT = 10.0) ,(£ = 0.465

DATA (A * -2a 70 3600 3 , 3. 1561552, -8.6573409, 5. 2640362, -3.5269034)

1 FORMAT ( 1H0 9X *DENGASF =0, I EXCEEDS TCRT.*/)

2 IF ( T -TCRT I 3,7,8

3 U= ( TCRT/T- 1) / (TCRT /TTRP- i ) * W=(TCRT-T)/ (TCRT- TTRP) Z Q=CU3ERTF(W)

5 F = A < 1 1 * W** E « A ( 2

) * W * A(3S*Q**4 A(4)*Q**5 A(5)*U*W

6 OENGASF = OGRT*EXPFCFS Z RETURN

7 OENGASF = DCRT Z RETURN

8 OENGASF = 0 £ PRINT 1 $ RETURN $ END

29
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05/14/73

FUNCTION F XNOSA TF ( 7 , M

)

ITERATE PEN TO HINIHIZE (T-TS) VIA TSATF(OEN).

M * 0 FOR VAPOR, M * 1 FOR LIQUIO.

COMMON/ 1/ A G, AL » BE , OE, GK, OCRT , PCRT , TCRT , OTRP, PTRP , TTRP

CO MM ON/ 3/0 POT , 02PDT2, OPSOT , DPMOT , OPOO, OPDR , OTSOR, DTHDR

1 FORMAT ( 1H0 9X *FINDSATF * 0, FAILS TO CONVERGE. * / ) 2 FORMAT C 1HQ 9X *FINDSATF = 0 , T EXCEEDS TCRT.* / ) 3 IF ( T-TCRT) 4,22,23

4 IF(M.EQ.O) 5,b 50= DENGASF(T) S GO TO 7 60= DENLIQF ( T

)

7 00 20 J=1 , 50 S DT=T-T3ATF (0) S IF ( A BSF ( DT/ T

) -1. 0 E-6 > 21,21,6

6 OTOO * DTSOR/OTRP l IF ( DTDO. EQ. 0 . 0 ) 22,9

9 00 s OT/OTOO % IF (A BSF (00/D)-1.0E-6) 21,21,10

10 0 = D DO $ IF(M.tQ.O) 11,15

11 IF (O.GT. 0.001) 13,12

12 0 * 0.001 S GO TO 20

13 IF (O.LT.OCRT) 20,14

14 D - OCRT - 0.02 S GO TO 20

15 IF (O.GT. 30.0) 16,17

16 0 = 30.0 S GO TO 20

17 IF (O.GT. OCRT) 20,16

18 0 = OCRT 0.02

20 CONTINUE S FINOSATF = 0 $ PRINT 1 % RETURN

21 FINOSATF =0 $ RETURN

22 FINOSATF = OCRT $ RETURN

23 FINOSATF = 01 PRINT 2 S RETURN « END

05/14/73

FUNCTION OENLIQF(T)

DENSITIES OF SATURATED LIIUID METHANE, MOl/L.

( 0- DC ) / ( OT- DC ) = (H**£)*EXP(A* (1-02) BM1-Q4) + C*(l-W2)).

W = (TC-T)/ (TC-TT) , Q = CUBERTF (W)

.

OAT A (TTRP=90.b6) , ( TORT* 190 . 555) , (DCRT=10.0) , ( DTRP=28. 147)

OAT A (E=0. 3b) , (A=-0. 178660 165) , (8=0 . 04838475) , ( C=- Q . 0 1 84898 7

)

1 FORMAT ( 1H0 9X * DENL IQF = 0, T EXCEEDS TCRT.*/)

2 IF ( T-TCRT ) 3,7,8

3 W = (TCRT-T) /(TCRT -TTRP) % Q * COPE RTF ( N)

5

F = A*(l-Q**2) 8* (l-Q*R) C*(l-H**2)

b DENLIQF = OCRT ( OTRP-OCRT ) *EXPF (F) *W**E * RETURN

7 DENLIQF = OCRT f RETURN

8 OENLIQF =01 PRINT 1 1 RETURN t ENO

05/14/73

FUNCTION PMELTF(T)

C METHANE SOLIO-LIQUIO MELTING PRESSURE, BAR.

C0MM0N/1/AG,AL,8E,0E,GK, OCRT , PCRT , TCRT , OTRP, PTRP, TTRP

COMMON/3/OPOT,02POT2, DPS OT,OPMOT, OPOO, OP OR, OTSOR, OTHOR

OATA (QP*1. 01325) , ( E= 1 . 85 ) , ( A*1884 . 43)

1 X = T/TTRP $ XE * X**E S AQ = A*QP

2 PMELTF * PTRP AQMXE-i)

3 DPMOT * AQ*E*XE/ X/TTRP $ RETURN * END

30
05/14/73

FUNCTION PSATF(T>

C METHANE VAPOR PRESSURE VIA PRYDZ/ GQQDHIN DATA, NOV., 1970.

C NOTE, PRESSURE IN BARS, 1.01325 SAR/ATM.

GQMM0N/3/OPOT,D2PDT2,OPSDT,DPMDT,QPDD,DPOR,DTSDR,DTHOR

0ATA(TTRP*9Q.68J , C TCRT s l 90 • 555 1 , (PTRP=0 . 11/435675)

DATA «P1*4. 7774358 0) , <P2*1. 760o5363> , (P3=- 0 . 567 8 8894 ) DATA (P4=l. 327862311

1 FORMAT < 1H0 9X »PSA?F 3 0, I EXCEEDS TCKT.*/J

2 XK= 1 -TTRP/TGRT $ X s (1 -TTRP/T i / XK % Q = i“X % IF(Q) 3,4,5

3 PSATF - DPSDT =0 $ PRINT 1 $ RETURN

4 H = Ml = 0 & GO TO 6

5 UaSQRTF(Q) S W-Q*U % Hl=-3»U/2

6 OXOTs?TRP/XK/T**2 S Z * X*H S 11 - X*W1 W

7 F s P1*X 4 P 2 *X **2 4 P3*X**3 P4*Z

8 FI = PI 4- 2»P2»X + 3*P3*X**2 + P4*Z1

9 PSATFsPTRP^'EXPF (F) S DPS 9 l 3 Fl*PSATF*OXDT S RETURN * END

05/14/73

FUNCTION TSATF (DEN)

C L IQUID-VAPQR SATURATION TEMPERATURES OF METHANE.

C NOTE EXPONENTIAL U(S>. EQN • , (TC/T-i)/ (TC/TT-l) = U(S)*Z(R).

C UCSi 3 EXPCFS/25, FS = S* C S-ST ) /APS (S-l ) , Z<R> = 1» C R- 1

) • W (R)

,

C H = A 1 4 A2*LN<R1 4 A3*Q 4 A4/(l4£*Q2) 4 A5*R 4 . . 4 A1G*R6.

COMMON/3/DPOT, 02 P0T2, DPSDT ,OPMDT ,OPDO,DPOR,OTSDR,DTHOR

DIMENSION A C 10 J DATA (£ - 3. 01 OAT A (TTRP390. 6 81 , C TCRT= 190.555) , (OCRTslO. 0) , ( DTRP= 20 . 14 71 DATA (A = 0.84320686, 0.15972304, 0.97837869, 0.28654081,

1 -1.7 1506402 , 10.88653606, -32.42048700, 63. 16166459,

2 -62.72090242, 25.924981311

1 Rs OEN/DTRP $ S = DEN/DCRT ? QS = S-l $ IF C QS . E Q , 0 . 0 1 30,2

2 AS = A8SF ( QS 1 $ STsOSOR=DTRP/DCRT $ YN s TCRT/TTRP - 1 3 X 3 S*«S-ST! $ XI - 2«S - ST $ V = 1/AS $ VI = -V/QS

4 FS s X*W % FSl 3 (X*V1 4 X 1* VI *DSDR

5 U = EXPF ( F S/21 l U1 = J*FSl/2 % Q = CUBERTF < R) t C2 = Q*«2 6Xs l/U4E*Q2> % XI = -2*£/3/Q*X**2

7 H s Ad) 4 A (2 1 *LOGF C R) 4 AC3)*Q 4 A«4)*X

8 Ml s AC21/R 4 A ( 3 ) /3/Q2 4 A(4>*X1

9 DO 10 < 35,10 S W s W 4 A(K) *R**<<-4)

10 Hi 3 HI 4 «K-4)*ACK)*R*« JK-5)

11 Z 3 1 + W» <R»1) % Z1 3 W 4 (R-1)*W1

12 F 3 u*Z S FI = U*Z1 4 U1*Z $ X = 1 4 Y N* F 13 TSATF 3 TGRT/X * OT SDR = -YN*F 1* TSATF/X % RETURN

30 TSATF 3 TCRT % DTSDR =0 % RETURN % END

05/14/73

FUNCTION CVGFCTi

C METHANE GV , J/MOL/K, ALONG THE 18.5 MOt/L ISOCHORE.

C CV/CVZ 314 A/X 4 8/X2 4 G/X3/ CX-1 1 **E, X = T/TH.

COMMON/ 99/ T I ,EZZ,EZ, SZ , GV Z , HZ , GPZ

DATA CE s 0 © 1 1 , CTH3lo4. 117 1 ) , < G = 0 . 97 37

)

DATA { As 0.472949961 v ( 0*- 0 • 5 027 1717 1 ,(Cs 0.214 21 338)

1 TI = T S CALL IDEAL $ X = T/TH % X3 = X**3

2 F s A/X B/X**2 4 C/ X3/ C X- 1 5 * *E

3 CVGF s G*C VZ*( 14F) % RETURN % END

31
05/14/73

FUNCTION PVTF(T»DEN)

C VIA EQNSTATE, FIELDS P,BAR, ALSO DP/OT, D2P/DT2.

COMMON 81*62, C 1 * C2 » 03 , G4 , E1,E2»E3

COMMON/ 1/AG, AL , BE , D£ , GK, OCRT , PCRT , TCRT , OTRP, PTRP, TTRP

C0MN0N/3/0P0T 9 02PDT2,DPS JT, OPMOT ,DPDD,DPDR, DTS OR, OTHOR

C0MN0N/4/XBl»XB2»XCl» XC2tX01 v X02* XElf XE2

C0MMQN/5/TSAT, DXBOR, OXCOR, 0XDOR,DXEDR

1 S= OEN/OCRT $ R-OEN/DTRP % R2=R**2 S R3=R**3

2 TS * TSAT * TSATF(OEN) t PS = PSATF (TS)

3 XB - XBF(T,OEN) % XC a XCF(T,DEN) f XE = XEF <T , DEN)

5 B - B1 82* R $ C * Cl C2*R C3*R2 C4*R3

6 E * <S-1) * (El E2*R E3*R2>

9 F = 8*XB «• C*XC * E*XE t FI a B*XB1 C*XC1 E*XE1

11 F2 * B* X82 C*XC2 E*XE2 1 YS s (PS/R/GK/TS - 1)*TS/TCRT/R

15 PVTF * (T + R* <F»YS) *TCRT) *R*GK S DPDT = < 1+R*F1 ) *R*GK

17 02PDT2 * R2*GK*F2/TCRT t RETURN * END

05/14/73

FUNCTION DPDRF ( T , DEN)

C VIA EQNSTATE, DPDRF = P,BAR. YIELDS ALSO DP/DR, DP/DD.

COMMON 01 j 82 g C1,C2,C3,C*, E1,E2,E3

COMMON/ 1/ AG* At , BE » DE» GK, DCRT , PCRT , TCRT , DTRP, PTRP, T TRP

COMMON/ 3/OPOT* 02PD T2, DPSOT , DPMOT ,DPOD,DPDR*OTSOR,DTHDR

COMMON/5/TSAT , DXBOR,DXCDR,OXDOR,DXEOR

1 X = T/ TCRT S S=DEN/OCRT $ OSOR = DTRP/OCRT

2 R = DEN/OTRP S R2=R**2 S R3=R**3

3 TSaTSATaTSATF(DEN) $ XS=TS/TCRT t PSaPSATF(TS)

4 X8 a XBF ( T , DEN) $ XC = XCF < T , DEN) t XE a XEF (T, DEN)

5 0 * Bi B2*R S 90 a 82

b C = Cl C2*R C3*R2 04*R3 S CD = C2 2*C3*R 3*C4*R2

fl U = S-l $ V a El E2*R E3*R2 t VI = E2 2*£3*R

9 £ * $ ED = U*V1 V*OSDR % F a Q*XB C*XC E*XE

11 Fl a 8*0XB0R BD*XB C*OXCDR CD*XC E*DXEOR EO*XE

15 YS = (PS/R/GK/TS-1) *XS/R

16 YS1 a (TS - R*DTSDR (DPSOT*DTSDR - 2*PS/R) /GK) /TCRT

17 Q a R*(F*YS)/X J OP DR a GK*T*<1 + 2*Q«-(R2*F1+YS1)/X)

20 OPOO a OPOR/DTRP t DPDRF a R*GK*T* ( 1+Q) f RETURN t END

05/14/73

FUNCTION THETAF (DEN)

C LOCUS OF TEMPS., INSIOE THE DOME, FOR THE EQNSTATE.

C THETA a TSAT*£XP (U(S) )

.

C IF S < 1, U * AG*(S-1)**J. IF S > 1, U = - AL* ( S-l ) ** 3

.

C YIELOS ALSO THE FIRST DERIVATIVE RSP. TO RHO=OEN/OTRP.

COMMON/ 1/ AG, AL , BE, OE , GK , DCRT , PCRT , TCRT , DTRP, PTRP, TTRP

COMMON/ 3/0PDT,D2PDT2, 0PS9T , DPMDT , OPOO , DPDR , DTSDR, DTHDR

COMMON/5/TSAT , OXBOR, OXCOR, OXOOR,OXE OR IS* DEN/DCRT $ DSOR = JTRP/DCRT

2 QaS-1 t Q2*Q**2 S Q3*Q**3 % IF(Q) 3,8,4

3 U a AG*Q3 t U1 = 3* AG* 12* DSDR t GO TO 5

4 U * -AL*Q3 1 U1 * -3*AL*Q2*0SDR

5 XP a EXPF(U) t THETAF TSAT*XP

7 OTHOR a <TSAT*U1 DTS0R)*XP $ RETURN

8 THETAF a TCRT $ OTHOR « 0 i RETURN * END

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05/14/73

FUNCTION X BF (T » 0)

FOR THE EQUATION OF STATE - XB = X*< i-EXP (-BE/XM - X3* ( 1-EXP (-BE/XS) )

C0MM0N/1/AG,AL,B£,0E,GK, DCRT,PCRT,TCRT, OTRP, PTRP,TTRP

C0MM0N/3/DP0T,D2P0T2, DPSOT, OPMOT , OPOO, DPDR, OTSOR , DTHDR

C0MNQN/4/X8l,XB2,XCl, XC2 , XOi , X02 » XE 1 , XE

C0MM0N/5/TSAT, OXBOR, OXCOR , DXODR , DXEOR

1 XsT/TCRT £ XSs 1 SAT /TORT * DXSQR=DTSOR/TCRT

2 U s 0£/ X I U1 - -U/X S U2 = -2*U1/X

3 US * BE/XS £ US1 = -US/XS

4 XP-EXPF(-U) £ Z = 1-XP £ Z1=U1*XP £ Z2= ( U2 -Ul* * 2

) *X

5 PHI = X*Z l X B 1 - Z+X*Z1 * XB2 = X*Z2 2*Z1

6 XPS-EXPF (-US ) $ ZS * 1-XPS £ ZS1 = USl’XPS

7 PHS s XS*ZS S 0X3DR = - <XS*ZSl*ZS) DXSDR

8 XB F s PHI - PHS S RETURN $ END

05/14/73

FUNCTION XCF (T ,D)

FOR THE EQUATION OF STATE - XCF * 1/X - 1/XS, X = T/TC.

COMMON/l/AG, AL»BE,Q£,GK, OGRT , PCRT , TCRT , DTRP, PTRP, T TRP

COMMON/ 3/DP0T,D2PDT2,0PS3T,DPMDT,DP0D, DPOR, OTS DR, DTHOR

C0MM0N/4/ X81,XB2,XC1,XC2 ,X01,XD2 ,XE1,XE2

COMMON/ 5/T SAT, OXBOR, OXCOR, OXDOR ,OXEOR

1 X = T/TCRT £ XSs TSAT/TCRT

2 XCF = 1/X-l/XS £ XC1 = -1/X**2 £ XC2 = - 2* XC 1/X

3 DXCOR = OTSDR/TCRT/X3**2 £ RETURN $ END

05/14/73

FUNCTION XEF (T , 0

)

NOTE CONSTANT IN PSI, W * OEMU-l), Z - OEMV-1).

PSI = <1-W*LN<1+1/W> )/U, XEF = (PSI-PSISAT) = PW/U - PZ/V,

U = T/TH, W = DEMU-t), V = TS/TH, Z = OEMV-1).

COMMON/l/AG, AL» BE, OE,GK, DCRT , PCRT , TCRT , 0 TRP , PT RP , T TRP

COMMON/ 3/DPDT, D2PD T 2, DPS JT, DPMDT ,OPDD, DPOR, OTSOR, DTHOR

C0MM0 N/h/XB1,XB2,XC1,XC2,XD1,X02,XE1,XE2

C0MM0N/5/TSAT, OXBOR, OXC OR, DXODR , OXEOR

1 TS - TSAT S TH = THETAF(D)

2 U * T/TH £ U2 = U**2 £ U3 = U**3

3 U1X = TCRT/TH S UlR - -U*DTHDR/TH

4 W s OEMU-l) i W1X s 0£*U1X % W1R = OE’UIR

5 V = TS/TH £ V 2 = tf**2 £ Ml = ( OTSOR- M* DTHDR )/ T

b Z - Q£MV-1> £ 7.1- 0E*V1 £ IF C W > 9,9,10

9

RsGMsGNlsGW2 = t( £ GO TO 11

10 G = LOGF ( 1 + 1/M) £ GW = W* G £ GW 1 = G- 1 / ( !W ) £ GW2=-1/W/ ( 1«-W) **2

11 PW=1-GW £ PW1X=-GW 1M1X £ PW1R = -GW1*W1R £ PW2X = -GW2 * W 1 X

* * 2 12 IF ( Z > 13,13,14

13 Z = GZ'~GZ1~0 £ GO TO 15

14 G a LOGFU + l/Z) £ GZ - Z*G £ GZ1 * G - l/U + ZJ 15 PZ - i-GZ £ PZt " -GZ1* Z1

20 XEF s pw/u - PZ/M £ XE1 = PW1X/U - PW*U1X/U2

22 XE2 s PW2X/U - 2*PW 1X*U1 X/U2 2*PH*U1X**2/U3

23 DXEOR s PW1R/U - PNM1R/J2 - PZl/V PZM1/V2

30 RETURN I ENO

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SUBROUTINE IDEAL

C METHANE IDEAL GAS THERMOF JNGTIONS CTIK AT ONE ATMOS®

C0MM0M/99/ TIf E22j £Z f SZ 9 GVZ,HZ,CPZ

DATA $R®8» 31431 9 CE*5.02288J , (AZ= 18. 852484) , C Ai* 2 . 5998981 )

1

CA2 3 1,4449418) » ( A3*- 1 * 8 472216 ) »

C A4 3 0 . 82 11 21 8) , C A§*4. 720 790 7

)

1 X3TI/4O0 I a*eUBERTFIX) I Q2*Q**2 % U®£/X $ XP 3 EXPFCU>

2 1 s U/<XP-1> f EZ 3 Al A2*Q A3*Q2 A4*X A5*Z

3 GVZ * HI 4*A2*Q/3 5* A3*Q2/3 2*A4*X A5*XP*Z**2

4 FU 3 Z - LOGF C l-l/XP)

5 SZ 3 AZ LOGF CTI/601 A1*LQGF<X)

fe SZ * SZ 4*A2*Q 5*A3*Q2/2 4 2*A4*X * A5*FU

C CONVERT TO DIMENSIONED RESULTS IN - JOULES » MOLES » KELVINS®

7 HZ 3 R*TI*(H-EZ) $ CPZ 3 R*U4-CVZ)

8 EZ - R*TI*EZ $ CVZ = R*CVZ S SZ 3 R*S2

9 RETURN t END

FUNCTION ESATF(T)

C INTERNAL ENERGY, SATO.LIO. METHANE, J/MOL.

C EQN®, Y (E) - (1-X) *EXP(W«X) ) , WHERE -

C YCEI 3 C £**£ TS / C EG-ET ) » XCT) ~ C TC-T) / i TC-TT ) , AND - Q W(X> * Al*X*LN(l+8/X) A2*X**C A3*X . . A9*X7.

DIMENSION A ( 9)

DATA (TTRP 3 9Q.68> , < TC RT 3 1 90 . 555) , (6=0.1) , (C=0.19)

DATA (ETRP -3471*053) , CECRT-10819 .568)

OATACA - -0.02940994, -0.19154778, -0.67454649, 3.11554755,

1

-9.71804579, 17.157o659 3, -16.50388*61, 7.79262156, -1.36621087)

1 FORMAT ( 1H0 9X *£SATF 3 0,, T EXCEEDS TCRT. * / ) 2 XN = TCRT-TTRP t YN 3 ECRT-ETRP IX* (TCRT-T)/XN

3 U 3 1 - X $ IF ( X ) 4,5,6

4 ESATF =0 S PRINT 1 % RETURN

5 W 3 Z 3 0 S GO TO 7 6 W - X*LQGF (1*B/X) I Z 3 X**C

7 F s A ( 1 ) *W A(2)*Z I DO 8 J=3 ,

9

8 F 3 F A< J) *X** (J-2)

9 ESATF 3 ETRP « YN*U*£XPF(F) $ RETURN S END

FUNCTION SSATF(T)

ENTROPY AND CSAT, SATO. LID. METHANE, J/MOL/K. DEFINE -

X (T)= (TC-T)/(TC-TT) , Y (S) = < S-ST ) / (SC-ST ) , Q=X**(l/2>.

EQN • , Y ( S) = (1-X)*£XP(4) , WHERE - W(X) = A 1*X*L N ( 1 1/X ) < A2*QQ A3*Q + H*X2 . . A8*X6.

COMMON/9/ CSAT

DIMENSION A ( 6)

OATA ( T T RP = 9 C • bfl) , ( TCRT 3 1 90 . 555) , <E=0.19)

DATA C S TRP = 6 7 • 8 7832 ) , (SCRT= 12 0 . 46263

)

OATAU = -0.15660939, -0.17271532, 0.06870234, 1.68743215,

1 -5.33121801, 9.06407137, -7.54347331, 2.43529834)

1 FORMAT ( 1H0 9X *SSATF =0, T EXCEEOS TCRT. * / ) 2 XN = TCRT-TTRP X YN = SCRT-STRP $ X 3 (TCRT-T)/XN

3 U = 1-X % OX DT = -1 /XN S IF (X) 4,5,6

4 SSATF = CSAT 3 G t PRINT 1 t RETURN

5 XG = Q = QQ = 0 $ GO TO 8

b G * LOGF ( 1 +1 /X ) I XG = X*G t XGl 3 G-l/(l+X)

7 U 3 SORTF(X) t 01=0.5/1 * QQ 3 X**£ f QQ1 * E*QG/X

8 F = A ( 1

) *XG A ( 2 ) *00 «• A<3)*Q % DO 9 K*4,

8

9 F 3 F A ( K) *X** (K-2) t XP = EXPF(F)

10 SSATF 3 STRP « YN*U*XP S IF(X.EQ.O.O) 15,11

11 FI * A ( 1) *XG1 A(2)*QQ1 A(3)*Q1 J DO 12 K*4,8

12 FI 3 FI 4 tK-2)*A(K)*X** (K-3)

14 CSAT 3 T* YN* CU*F1- i> * XP* DXOT $ RETURN

15 CSAT 3 0 $ RETURN $ END

34
05/14/73

SUBROUTINE MELTHERM

C GIVEN P, GET T, DEN, ETC., FOR FREEZING LIQUID AT T L.T. TCRT

COMMON/l/AG, AL , BE, DE, GK, DCRT , PCRT , TCRT , OTRP, P TRP , T TRP

COMMON/3/DPOT,D2PDT2,DPSDT,DPMDT,DPOO,OPDR,OTSDR,DTHOR

C0MH0N/8/ P, T, OEM, £,H,S, CV»CP,W, WK

COMMON/ 9/ CS AT

1 T = FI NDTMF (PS t DL ~ FINDSATF ( T , 1

)

2 E = ESATF(T) t S~SSATF<T> $ PX=PVTF ( T , DL ) $ DOL DT = DTRP/ DTSDR

3 CV = CS AT 1GG*T*DP:)T*D0LDT/DL**2

C NOW INTEGRATE FROM SAT. LX Q® UP TO THE FREEZING LIQUID.

4 OEN = OM = OTRP* (T/ TTRP ) * * 0 .25 * N = 4 + 5M0M-DL)

5 E = E ESUMF ( N , T , OL , DM) % H = E + 100*P/DM

6 S = S SSUMF(0 , N , T , 3L * 0 1 ) J CV = CV CSUMF ( N , T , OL , DP

)

7 PX = P VTF < T , DM) l PX = DPDRF ( T , OM)

8 CP = CV «• 1JO*T/OPOQ* (DPOT/DM) **2

9 W = SQRTF ( WK*CP*OPDD/CV) $ RETURN $ END

05/14/73

SUBROUTINE SAT GSTRM

C GIVEN P, GET T, DEN, ETC., FOR THE SATURATED VAPOR.

COMMON/ 1/ AG, AL , BE, DE, GK, DCRT , PCRT , TCRT , DTRP, PTRP, TTRP

COMMON/ 3/OPOT, D2PD T2, DPS JT,DPMOT,DPDD, DPDR, DTSDR, DTHDR

COMMQN/8/ P, T , OEN, E,H,S, CV,CP,W, WK

COMMON/ 99/ TI,EZZ, E Z , SZ , C VZ , HZ , CPZ

DATA (DA = Q . 0 ) , ( QPs 1 . J 1325 > , ( GC = 0 . Ob 31434)

1 T = T I = FINDTSF (P) $ CALL IDEAL

2 DEN s og = FINDSATF <T ,0) S N = 5 * 2*QG

3 E = EZZ EZ ESUMF(N,T,DA,DG) * H = E * 10C*P/DG

4 S = SZ • 100*GC*LOGF(GC*T*DG/QP) SSUMF ( 1 , N , T , D A , DG

)

5 X = 0.02*(T“TCRT) **2 l IF(X.LT.3.0) 6,7

6 N = N 30 *£XPF ( -X)

7 CV = CVZ CSUMF CN, T, DA, DG)

8 PX = P V TF ( T , OG ) % PX = DPDRF (T ,DG)

9 CP = CV + 100*T/DPDD* (OPDT/DG) **2

10

W = SQRTF (WK*CP*OPDO/CV) $ RETURN J END

05/14/73

SUBROUTINE SATLQTRM

C GIVEN P, GET T, DEN, ETC., FOR THE SATURATED LIQUID.

C0MM0N/1/AG,AL,8E,DE,GK, DCRT , PCRT , TCRT , O TRP, PTRP , T TRP

COMMON/ 3/ D PD T, D2PDT2,DPS DT , DPMDT , DPOO , DP OR , D TSDR , OTHDk

COMMON/8/ P, T,DEN, E,H,S, CV,CP,W, WK

COMMON/9/ CSAT

1 T = FINOTSFCP) * OEN = OL - FINDSATF ( T , 1 > 2 E = ESATF(T) i S = SSATF(T) % H - E * 100*P/DL

3 PX s P V TF ( T , OL ) % PX “ DPDRF (T ,DL) $ DDLDT = OTRP/ DT SDR

4 CV = CSAT + lCiO*T*DPOT*'JJLOT/DL**2

6 CP s CV 100*T/DPOD* (OPOT/DL) ** 2

9 W = SQRTF < WK*CP*UPOD/CV) % RETURN S END

35
05/14/73

SUBROUTINE THRMOGAS

GIVEN P» T» GET DEN AND FUNCTIONS FOR HOMOGENEOUS DOMAIN.

COMMON/ I/&G, AL ,8E, BE, GK, OORT , PORT » TCRT , DTRP, PTRP, TTRP

G0HM0N/3/DP0T»D2P0T2,0PSDT,DPN0T,0PO0,DFOR,OTSDR,DTHDR

COMMON/®/ P,T »OEN® E,H,S, CV,CP»H, HK

COMMON/ 99/ II » £22 » EZ, SZ ,G VZ » HZ ,CPZ

DATA CDA*0. 0) , (QP*1. 01325) , CGC-0. 0831434)

1 TI * T S CALL IDEAL

2 OEM * 08 * FINOENF«T,P) $ N ® 5 2*08

3 E * EZZ EZ * ESUMF(N,T,DA, 08) $ H * E 10©*P/OB

4 S * SZ - 1O0*GG*LQGP C GC* T*D8/QP) SSUMF (1 , N ,T , DA, 08)

§ Q * (OB/DCRT-l) **3 S QQ * ABSF (Q) - Q

6 X s 6.02* C T-TCRT 1**2 3*Q0 t IFCX.LT.3.0) 7,®

7 M a N 3®*£XPF l“X)

® GV * CVZ CSUMF CN,T,OA,BB) S PX a PVTPCT,08>

9

PX s OPDRF C T ,08 ) S CP * CV 1QO*T/DPOD* (OPOT/DB) **2

19 H * SQRTFCWK*CP*OPO0/CV) % RETURN S END

SUBROUTINE THRMOLIQ

GIVEN P, T, GET DEN AND FUNCTIONS FOR COMPR.LIQ. AT T L.T. TORT.

COMMON/ 1/AG , AL,BE»OE»GK, OCRT , PORT , TORT , DTRP, PTRP , TTRP

COMMON/ 3/DPDT , 02P0T2, DPSDT , DPMOT , DPOO, DPDR » OTS DR » DTHDR

COMMON/®/ P,T,DEN, £,H,S, CV,CP,N, HK

COMMON/9/ CS AT

1 01 s FINDS AT F ( T , i) % DEN = DB * FINOENF (T ,P)

3

E=£SATF CT) S S*S3ATF(T) $ PX=PVTF (T , DL ) S DDL DT* DTRP/ DTSOR

5 CV * CSAT 1UG*T*DP0T*D0LDT/DL**2

NOW INTERGATE FROM SAT.LIQ. INTO THE COMPR. LIQUID.

6 N * 5 5* ( QS-DL

)

7 E = E ESUMF (N, T , DL, DBS t H = E 100*P/DB

® S * S SSUMF(0,N,T,DL,D3)

9 CV * CV CSUMF (N,T , DL ,0 3)

10 PX * PVTF (T ,DB) S PX = DPDRF (T ,03)

11 CP * CV 1CO*T/DPOO* (0PDT/D8)**2

12 N * SQRTF ( HK*CP*OPDD/CV) S RETURN t END

SUBROUTINE THERMOX

REGION X FOR DEN ABOVE DCRT , AND TSAT(1®.5) = T = 220 K.

GIVEN P,T, GET OEN ANO THERMOFUNCTIONS.

E = EA, S = SA AT 220 K ANO 18.5 MOL/L.

FIRST INTEGRATE ALONG ISOCHORE 10.5, THEN ALONG ISOTHERM T.

COMMON/ 3/DPDT, 02PDT2, DPSDT, OPMDT , DPDD , DPOR , DTS DR, DTHOR

COMMON/®/ P, T, DEN, E,H,S, CV,CP,W, HK

DATA CTTRP-90.68) , CTCRT=190 .555) , ( DCRT*10. 0 ) , C 0TRP*28. 147)

DATA CDA*18.5) , CEA*9374. 3) , (SA=113.912)

1 E-EA S S sSA S TR=220-T S N*5+TR/2 t OT*-TR/N

2 DO 4 J*1,N S TJ * 220 * CJ-0.5)*OT t CX = CVGF(TJ)

3 E * £ CX*DT S S * S CX*DT/TJ

4 CONTINUE S DEN = D3 = FINDENF (T,P)

NOH INTEGRATE ALONG ISOTHERM T.

5 N * 5 3* ABSF ( DB-OA) S S * S SSUMF ( 0 , N, T, OA , OB

)

6 E a E ESUMF (N,T,DA,OB) S H = E 100*P/DB

7 X s 0.02* CT-TCRT)**2 3* CDB/DCRT- 1) **2 S IFCX.LT.3.0) 0,9

6 N * N «• 30*EXPF C-X)

9 CV * CVGFCT) CSUMF C N, T , DA , DB)

IS PX * PVTF CT, DB) S PX * DPDRF (T , DB)

11 CP * CV 100*T/0PDD* C0P3T/0B)**2

12 H * SQRTF <MK*CP*DPOO/CV) % RETURN t END
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05 / 14/73

SUBROUTINE THERMXL

GIVEN P» GET T,0EM, ETC., FOR SAT.LIQ. IN REGION X.

INTEGRATE ALONG ISOCHORE 18.5, THEN ALONG ISOTHERH T DOWN TO OL.

COHHON/ 1/AG,AL,@£,QE,GK, OCRT , PCRT , TCRT , OTRP, PTRP , TTRP

COMMON/3/DPDT , D2P0T2, OPSOT , OP MOT ,DPOO,DPDR, OTSOR,OTHOR

COHHON/ A/ P, T, DEN, E,H,S, CV,CP,W» WK

C0HH0N/9/ CSAT

DATA C0A*1A®5) , (EA 3 9874 9 3) , <SA 3 113.912)

1 T 3 FINDTSF CP) l E = £ A $ 3 ~ SA S TR 3 220-T

2 N * 5 TR/2 £ OT - -TR/N

3 DO 5 J3 1 ,N 8 TJ * 220 (J-Q.5)*DT * CX * CVGFCTJ)

4 E 3 E CX’DT % S = S CX’DT/TJ

5 CONTINUE S DEN * QL * FINOSATF (T , 1

)

NOW INTEGRATE ALONG ISOTHERH T FROM OA DOWN TO OL

6 N 5*3*ABSF COL-DA) S E * E + ESUMF (N,T,QA,OL) * H = F + 100*P/DL

7 S * S SSUHF(0,N,T,DA,OL) S IF C T . EQ. TCRTi 8,9

8 CSAT * CV * CP 3 W 3 0 $ RETURN

9 X * 0.02MT-TCRT)”2 £ IFCX.LT.3.0) 10,11

10 N « N 30*EXPF ( -X

)

11 CV 3 CVGFCT) CSUHF(N,T ,DA,OL)

12 PX * PVTF ( T, OL ) $ PX 3 DPDRF (T ,OL ) f DDL OT = DTRP/OTSDR

13 CSAT * CV - 100*T*DPOT*ODLDT/DL**2

14 CP * CV 100*T/DPDD* (OPOT/DL) ”2

15 W * SQRTF C WK’CP’OPDD/CV) $ RETURN f END

05 / 14/73

FUNCTION CSUHF (N,T ,DA ,08)

DELTA CV * -T ’INTEGRAL ( ( D2P/OT2 ) /D”2 ) ’ DO.

COHHON/ 3/ DPDT , D2PDT2, DPSOT , DPMDT , DPDO, DPOR , DTSDR , DTHDR

2 OX 3 <OB-DA)/N £ CSUHF =0 £ DO 5 J-1,N

3 ON * OA (J-0.5)’DX £ P 3 PVTF(T,QN>

5 CSUHF * CSUHF - D2PDT2’DX/DN”2

9 CSUHF 3 1 0 O’T’CSUMF £ RETURN S END

05/14/73

FUNCTION ESUHF CN,T,DA,DB)

GET DELTA E OVER DENSITY RANGE FROM DA TO OB,

DELTA E - INTEGRALCP-T’ C DP/DT) ) *DX/DN”2.

COMMON/ 3/DP0T,D2PDT2, DPSOT, DPMDT ,OPOD» OPDR , OTSOR , DT HDR

2 OX * (DB-DA) /N $ ESUHF = 0.0

3 OO 5 J3 1 , N $ DN 3 DA (J-0.5)*DX S P = PVTF (T, ON)

5 ESUHF 3 ESUHF CP-T’DPDT) ’DX/DN”2

9 ESUHF * 100’ESUMF 8 RETURN $ END

FUNCTION SSUMFCL,N,T e OA»QB)

DENSITY- DEPENDENT CHANGE OF S FROM OA TO DB.

DELTA S * INTEGRAL CGK-COP/DT) /ON)*DX/DN.

COMMON/ 1/AGfAL ,0E,OE»GK» OCRT , PCRT , TCRT , OTRP, PTRP, TTRP

COMMON/ 3/DPDT,D2PDT 2, OPSOT, DPMOT,DPDD, OPDR, DTSDR, DTHDR

1 SSUMF 3 0 S OX ® CO0-D A) /N * IF(L.EQ.O) 4,2

2 GC*GK/DTRP $ DO 3 J*1,N $ ON*OA«- ( J-0 • 5 1 *DX S P=PVTF(T,ON)

3 SSUHF * SSUMF CGC-OPDT/ON ) ’OX/DN I GO TO 9

4 OO 5 J*1,N £ ON 3 OA (J-0.5)*DX S P 3 PVTF(T,ON)

5 SSUMF * SSUHF - QPOT’DX/QN**2

9 SSUMF 3 100’SSUHP $ RETURN S END

37
«o

05/14/73

PROGRAM MI THERM

4

C COMPUTE METHANE THERMOFUNCTIONS IN ENGINEERING UNITS.

C NOTE. DCRT*i@® @1532 LB/CUFT, TCRT-342.999 R, PCRT*667.0C3 RSI.

C NOTE® 0TRP*28. 19012 LB/GUFT, TTRP*1§3.224 R, PTRP*1. 70324 PSI.

GOMTOI8 01,82, G1,C2,C3,C4# E1,E2,E3

COMMON/ l/AG, AL , S£, BE, GK , 0CRT»PCRT ,TCRT , OTRP, PTRP', TTRP

COMMON/ 3/QPDT,D2P0T 2, DPSOT , OPHOT ,OPOO,OPOR,OTSOR,OTHOR

conmon/7/ tr,tf, gn,vs

COMM@N/e/ P,T 9 ©EN, E,H,S, CV,CP,W» NX

COMMON/ 9/ GSAT

C0NN0N/99/TI ,£22 , E2,SZ,CV2,H2,CP2

02MINSION PSI C 991

1% FORNA? f 1X1

IS FORMAT « SF10. 61

14 FORMAT (1H1 13X * METHANE ISOBAR AT P ** F0.1, • PSI* //

1 14X1HT SX1HT 6X3H0EN 6X3HVOL 4X5HDP/0T 6X5H0P/D0

2 7X1HE 7X1HH ® MIMS 7X2HGV 7X2HCP 5X1HM /

1 1OX5M0EG F 4X5H0EG R 2X7HLB/CUFT 2X7HCUFT/LB 4X5HPSI/R

4 1 X10HPSICUFT/LB 2X6H8TU/LB 2X6HBTU/L6 1XSHBTU/LB/R

5 1X8HBTU/L8/R 1X8HBTU/L8/R 2X4HFT/S ) 17 FORMAT (4X 2F9.3, F9.3, F9.5, F9.3, F11.2, 2F8.2, F9.5, 2F9.3,F6.0)

18 FORMAT (6X 2F9.3, F9.4, F9.4, F9.4, F11.2, 2F8.2, F9.5, 2F9.3,F6.0)

19 FORMAT ?4X 2F9.3, F9.5, F9.3, F9.5, F11.2, 2F8.2, F9.5, 2F9.3,F6.0)

C CONSTANTS OF EONSTATE-8, 5/11/73, AT 10.46, NF * 9.

C NOTE CONSTANT, BE, IN PSI, XEFCT,D>.

20 TTRP*90 .68 % PTRP*0. 117435675 I 0TRP*28.147 t QP*1. 01325

21 ?CRT*i9®.55§ S OCRT*10.O S PCRT*PSATF<TCRT

I

22 AG«AL«0.2 S BE*7 S DE*i t GKK*0. 0831434 $ GK*DTRP*GKK

23 @1 * 1.599101971 % B2 * 2.483786733 % Cl * -1.076088156

24 C2 * 10.482192754 t C3 « -22.556715826 t C4 * 12.289665719

25 El * 0.993750233 S E2 * -1.243035021 t E3 * 0.318523715

27 EZZ * 4.1868*2191.3 t WK * 100000/16.043

28 OPP * 14.69595/QP t TA * 174.516 f TB * 220

C DERIVE THE J-T INVERSION CURVE.

99 CALL JT LOCUS

C TABULATE THE SATURATEO LIQUID FUNCTIONS.

100 CALL TA3LIQ

C

C COMPUTE THERMOFUNCTIONS ON ISOBARS -

C EVERT ISOBAR STARTS ON THE MELTING LINE AT T UNOER TCRT

C LET THE FIRST ISOBAR BE AT P * PTRP.

C ISOBARS AT P UNOER PCRT TRAVERSE THE DOME.

C SPECIAL CASES FOR REGION X AT TA*T*TB» DEN ABOVE DCRT

140 NI « 65 S PSI(l) * PTRP*QPP

141 READ 15, CPSICI) ,1*2, NI)

142 DO 300 1*1, NI S PRINT 16, PSICI) t P * PSICD/QPP

143 CALL MELTHERM S CALL CONVERT S V * 1/DEN

145 PRINT 17, TF ,TR,DEN,V, DPDT,OPDO, E,H,S, CV,CP,M

146 IT * TF/10 - 1 t IFCP.LT.PCRT) 154,200

CASES FOR P LESS THAN PCRT.

154 K*L*0 $ TS*FINDTSF(P> S TX * TS 10/1.8

155 00 199 J*1 ,99 S JT*10*(IT*J> S T*TT*273. 15* ( JT-32J /1.8

157 IFCT.LT.TA) 158,175

C NORMAL CASES FOR P UNOER PCRT, T UNOER TA.

38
oo

METHERM6 35/16/73

158 IFST.ifr.TS 8 159 9 161

C CASE FOR GQMPR6SSE® LIQUID AT T UNDER TA.

159 CALL THRM0LIQ 8 CALL CONVERT $ V * i/OCN

160 PRINT 17, ?F,TR,0gM,V, DPDT »0PD0, E,H,S, CV,CP»M

161 IF (T.LT.TK) 162, 1§3

C CASE FOR SATURATED LIQUID AND VAPOR.

163 IFd.EQ.il 163,164

163 PRINT 14 S 80 TO 166

164 CALL SATLQTRM 8 CALL CONVERT f

165 PRINT 17, TF,?R,0EN,V, DPDT ,0PD0,

166 CALL SATGSTRM S CALL CONVERT %

167 IPCP 9 8?.i@.@8 1689169

16® PRINT 16* TF ,?R, DEN ,V , 0PO?,OP0O,

169 PRINT 19® ?F,TR»OEN»V, 0P0T,DP009

170 T « T! $ 80 TO 183

C CASES FOR P UNDER PORT , T OVER TA,

175 IFCT.LT.TS1 1 76,17®

C CASE FOR COMPR. LIQ. SI T4 * T s TSAT IN REGION X 176 CALL THEftMOM f CALL CONVERT % V * 1/DEN

177 PRINT 1?, TF 9 TR 9 OEN 9 V 9 0PDT,DPDD9 £ »K,S » CV,CP»W

17® IF ST .Lf .TAJ 17

9 1 8 3

C CASE FOR SAT. LIQ, IN REGION X, AND SAT. VAPOR.

179 CALL THERMXL S CALL CONVERT S V * 1/OEN

180 PRINT 17, TF ,TR, DEN, V , OPOT 9 DPOD 9 E»H,S» GV,CP,W

101 CALL SATGSTRM 8 CALL CONVERT S V * 1/OEN

162 PRINT 18, ?F,TR,0£N,V» DPDT 9 OPOO 9 E, H,S, CV»CP»H

V i/OEN

E,H,S, CV,CP®W

V * i/DEN

E,H,S, CV 9 CP 9 W

E e H,S, CV 9 CP 9 W

IN REGION X.

% GO TO 199

$ PRINT 14

S GO TO 170

S GO TO 199

S PRINT 14

T s TT

CASES FOR HOMOGENEOUS DOMAIN, 0 UNDER 06, OR T OVER TC.

183 IFCJT.GT.8QJ 184,108

1®4 K * S JT * JT *I0*K

185 IFSJT*GT.240) 188,18®

186 l * L+l $ JT * J?*20*l

18? IFSJT.GT.448) 303, IS®

188 CALL THRMOGAS S CALL CONVERT f

189 IF CP.6T • 10® 0 J 193,191

190 PRINT 18, TF,TR,OEN,V, OPOT,DPDD,

191 PRINT 19, TF,TR,0EN,V, DP0T»DP0D,

199 CONTINUE

ST* 273.15 <JT-32>/1.6

ST* 273.15 SJT-32J/1.®

1/DEN

E,H,S,

E, H,S,

CV,CP,W

CV,CP,H

GO TO 199

CASES FOR P GREATER THAN ®CRT.

200 K*L*0 S DO 230 J*l,99 S JT*10MIT*J> S T=2?3. 15* (JT«*32>/i. 8

201 IffT.LT.T0S 202,220

2®2 IF (T.LT.TAI 203,205

233 CALL- THRNOLIQ S CALL CONVERT $ V * i/OEN

204 PRINT 17, TF,TR,DEN,V, 0PDT,DP0D, E,H,S, CV»CP,H S GO TO 23®

209 XFST.LT.TCRTl 211,208

206 PM * PVTF<T,DCRT> S IFCP.GT.PX) 211,225

C CASE FOR REGION X ST TS * T * T8, P ABOVE CRITICAL ISOCHORE.

211 CALL THERMOS S CALL CONVERT % V * 1/OEN

212 PRINT 17, TF,TR,OEN,V , DPDT , 0POD, E,H,S, CV,CP,N S GO TO 230

C CASES FOR HOMOGENEOUS DOMAIN, 0 UNDER DC, OR T OVER TC.

228 IF CJT.GT. ®®$ 221,225

221 K * K*1 S JT * JT«>10*K ST* 273.19 (JT-321/1.8

222 IF CJ?©6?.24®I 223,229

223 L * Id 8 JT * J?*2®«L ST* 273.19 SJT-32J/1.8

224 IFSJT.GT.4485 3i@,22f

225 CALL THRMOGAS $ CALL CONVERT S V * i/DEN

226 PRINT 17, ?F,TR,DEN,V, DPDT,QPOD, E,H,S, CV,CP,^

230 CONTINUE

300 CONTINUE

999 STOP 8 END

39
05/16/73

2

6

9

10

11

12

13

14

15

16

17

16

19

20

21

22

23

25

26

29

30

SUBROUTINE JTLOCUS

DERIVE THE J" T INVERSION CURVE. USE ROUTINE DEL TAF ( T, 01 > . DIMENSION TTC99) »TF(99> * RPC 99) ,DN<99>

DATA CDCRTslO.OJ , i TCRW90 . 555 > FORMAT ( 1H1 16X *TH£ JOULE-THOMSON INVERSION

1 12X 3HT,F 5X3HT » R 2X5HP,PSI 2XFHLB/CUFT

2 9X 3HT,F 5X3HT,R 2X5HP,PSI 2X7HLB/CUFT ) FORMAT ( 3X 2CF12.2, F8.2, F7.0, F9.2))

PRINT 1 * 00 25 1*1,62 t TF € I ) * -180 10*1

TTCI) » 459.67 TF(I) t T * TT(I)/1.8 f OX s 1.6

LOCUS FOR METHANE*//

DsOH-DX t SP*DELTAF(T,D>

GO TO 20

01 * DCRT* (2.70816 - 0.70263*T/TCRT> t

OL * OENLIQF(T) f IF(DI-OL) 25,12,12

SS * DELTAF (T, 01)

DO 20 11*1,15

DaQI-DX S SL=DEL TAF (T ,0)

IF ( SS-SL) 18,16,16

IF(SP-SL) 19,17,17

SS * SL S 01 * 01 - OX

IFCSS-SP) 20,20,19

SS * SP % 01 * DI OX

OX * DX/2 % 0 * 01 % P = PVTF (T, D)

IF ( T-TCRT) 22,23,23

PS * PSATF(T) % IF(P-PS) 25,23,23

PP(X) = 14«503774*P S ON(I) = 1. 00 1532*D

CONTINUE

00 29 J*1 , 31

PRINT 2, TF(J) ,TT(J> ,PP(J) , ON ( J)

,

1 TF( J*31> ,TT (J+31) ,PP(J+31> ,DN(J+31>

RETURN % END

IF(T-TCRT) 11,12,12

05/16/73

FUNCTION DELTAF (T, 0)

C GET ( T*DP/DT - 0*0P/00) FOR THE J-T INVERSION CURVE.

COMMON/ 3/DPOT,02POT2,DPSOT, OPMOT , OPOO, OP DR , DTSOR , DTHDR

OATA (DCRT *10.0) , (TCRT=190.555)

1 IF ( T-TCRT) 2,4,4

2 OL = OENLIQF (T) % IF(D-DL) 3,4,4

3 DELTAF = l.QE+010 S RETURN

4 P * PVTF (T ,0) S PX = DPDRF (T ,0)

5 DELTAF * A BSF ( T *OPOT- D*D<>DD ) % RETURN t END

SUBROUTINE CONSAT

C CONVERT SAT .L IQ. PROPERTIES TO BRITISH UNITS.

C0MM0N/3/0PDT, 02P0T2, OPSOT, OPMOT, OPDD, DPOR, OTSOR , OTHOR

C0MM0N/6/TT,PS,0L,D0L0T, VG, VL,Q

COMMON/ 7/ TR , TF , CN,VS

COMMON/ 8/ P, T, OEN, E,H,S, CV,CP,W, WK

COMMON/9/ CSAT

DATA (EK=37. 291 055) , (SK*67 . 1 23912 ) , (DK=1 . 00 1532

>

1 TR a 1 , 8*TT S TF a 32 1 . 8* (TT-273. 15

)

2 PS = 14 .50 3775*PS t D°SDT * 8 . 0576524*DPSDT

3 OL * OK*DL * DOLOT = 0. 55640657*OOLOT

4 VG * VG/DK t VL * VL/DK S Q*Q/EK S E*E/EK * H*H/EK

5 S=S/SK * CSAT*CSAT/SK « CV*CV/SK * CP*CP/SK

6 M * 3. 28084* W S CN = 0.0578176*CN « VS * 0.067197*VS

9 RETURN t END

40
SUBROUTINE CONVERT

C CONVERT FROM SI TO BRITISH UNITS®

COMHON/S/OP0T,O2FD?2,OPSOT s BPMD?,DPOQ,OPDR» DTSOR,DTHOR

COMMON/?/ TR» f

f CN»VS

COMMON/8/ P 9 T, OEM* E,H,S, CV,GP,H, WK

DATA «EK s 3?®29i®95) g «§K * 67*1239121

1 TR a 1.8*T S IF * 32 t®0* CT-273.19)

2 OEM * 1®O01532’DEN % E * E/EK % H * M/EK

3 S * S/SK * CV * CV/SK % CP a CP/SK

4 W * 3.2®084*W $ CN » 0 • 0978t?6’CN f VS * 0.067197’VS

5 OPD? » @«05?6§24’0POT S DPOO • 14® 401591’DPOD

9

RETURN $ END

SUBROUTINE TABIXQ

C TABULATE THE SATURATED LIQUID FUNCTIONS®

COMMON/ 1/ AG# AL , BE, 0E, GK , DCRT , PORT , TCRT $ DTRP, PTRP, TTRP

COMMON/ 3/0POT, 02P0T 2, 0PSOT , OPMOT ,OPDD,OP0Rf OTSOR»0THOR

C0MHON/6/TT* PSj OL , DDL D? , VG , VL , Q

COMMON/?/ ' ?R,TF 9 GN»VS

COMMON/8/ P® T® DEN, £,H,S, CV,CP®W® MK

C0MM0M/9/ CSAT

1 FORMAT ( 1H1 13X ’PROPERTIES OF SATURATED LIQUID METHANE’ / > 2 FORMAT C14X1HT 8X1HT SX1HP 5X3H0EN 4X9HV,6AS 4X9HV,LIQ 3X5HQP/OT

1 4X6HD0L/DT 3X9MQ,VAP / 10X9H0EG f 4X9HQEG R 6X3HPSX 1 X7HLB/CUFT

2 2X7HCUFT/LB 2X7HCUFT/LB 3X9HPSX/R i X9HL8/GUFT /R 2X6H0TU/LB ) 3 FORMAT CSX 3F9.3, F8.3, F9®4, F9®5, F8.4, F10.5, . F8.2)

4 FORMAT ( I4X 1HT 8X1MP 7X1HE 7X1HH 8X1HS 7X2HCV 7X2HCS 7X2HCP 6X1HW /

1 18X9MDEG F 6X3HPSI 2X6H9TU/LB 2X6HBTU/LB 1X6H8TU/L B/R

2 i XSHiTU/L 8/R 1X8H0TU/L8/R 1X8H8TU/L0/R 3X4HFT/S ) 9 FORMAT C6X 2F9*3, 2F8.2, F9.9, 3F9®3, F7.0)

C FOR PAGE 1 OF TA0LIQ®

9 TA * 174.916 % PRINT 1 % PRINT 2

10 DO 29 Jsl s 37 % IF C J®£Q* 15 11,12

11 TT 2 TTRP % GO TO 19

12 IF ( J ® IQ* 3? I 13,14

13 TT = TORT % OG=QL s QCRT % VG=VLsl/DG S GO TO 17

14 FT 2 -300 * TT 2 273.19 (FT- 32) /l.

19 DG s f INOSATFITT,0) % VG * 1/DG

16 OL s FINOSATFJTT ,1) S VL = 1/DL

1? PS s PSATF(TT) S Q * 1 0 0’ TT ’DPSDT’ « VG*» VL i 10 IF ( J®EQ®37 1 19,20

19 DDLDT s 0 % GO TO 24

20 TS s TSATF(DL) % OOLDT * OTRP/DTSDR

24 CALL CONSAT

29 PRINT 3, IF, TR, PS, 0L,VG,VL» DPSDT , OOLDT ,Q

C FOR PAGE 2 OF TA8LIQ®

30 PRINT 1 S PRINT 4 % 00 90 J=l,37 $ IF(J.E0®1) 31,32

31 TTsTTRP S PSsPTRP t OL-OTRP * GO TO 30

32 IF ( J.EQ©37) 33,39

33 TTsfCRT S PS-PCRT S CV-CS ATsCP-MsO

34 SaSSATFCTT) t E s ESATF (TT) % H = E iOQ’PS/OCRT f GO TO 49

35 FT * -300 5® J % TT s 273.19 CFT-32>/1.8

36 PS = PSATFCTTI S DL s FINOSATF CTT , 1

)

37 IF ( TT.GT® TAI 49,38

30 S * SSATFCTT) % E s ESATF(TT) $ H * E 100’PS/DL

39 PX s PVTF (TT »0L) t DOLOT * OTRP/DTSDR

40 CV s CSAT * iOO’TT ’DPDT’ODL DT/0L”2 ? PX s OPORF(TT,OL)

41 CP * CM 10O’TT/DPOO’(DPOT/DL)”2

42 H s SQRTF ( MSC’CP’OPOO/CV) S GO TO 49

49 P * PS S CALL THERM XL

49 CALL CONSAT

90 PRINT 9, IF, PS, E ® H , S , CV,GS&?»CP» M

99 RETURN t END

41
DENSITY

<

TEMPERATURE —

Figure 1. Density-temperature phase diagram.

i

42

*0
Table 1-A. The saturated vapor densities

10 f »K HOl/L CAICD pcm

2 90.680 3.0157 0.0157 -0.03

i 91.000 3.9163 0.0163 0.G9

a 92.000 3.9193 3.0133 -0.02

2 9%. 000 3.3229 0.0229 0.01

i 95.000 J ® 9255 0.0255 0.15

2 96.010 3.3283 0.0233 -0.00

2 98.000 3.0347 3.0347 0.02

2 100 .000 3.0422 0.0421 0.03

2 102.000 3.0538 0. C508 8.02

i 103.000 3.0557 0.0556 0.17

2 104.060 3.0608 0.0608 0.02

2 106.000 0.0722 0.0721 0.02

1 107.000 3.3736 0.0784 0.23

2 103.006 3.0851 0.0851 C.01

2 110. 006 3.0997 0.0997 © e 00

1 ill. ooo 3.1081 0 ® 1078 0.32

2 112. OuO 0.1132 0.1162 -0.00

2 114.000 0.134? 0. 04? -0.C1

1 115.006 0.1452 0.1447 0.33

2 116.060 3.1553 0.1553 -0.01

2 118.000 3.1731 0.1782 - 0 . Cl

1 119.600 J . 1912 0.1905 0. 36

2 120.606 3.2035 0.2035 -C.01

2 122.000 0.2314 0.2314 -0.01

1 123.006 3.2473 0.2464 0. 35

2 124.000 3.2621 0.2622 -0.C1

2 126.066 3.2958 0.2959 - 0 . Cl

1 127.000 3.3151 0.3139 0.38

2 123.060 3.3327 0.3327 -0.01

2 130. 0 C 0 3. 3730 0.3730 -0.CO

1 131.000 3.3961 0.3945 0.41

2 132.000 0.4169 0.4169 -0.00

2 134.066 3

4646 0.4646 0.00

1 135.000 3.4920 0.4899 0.42

2 136.000 3.5154 0.5164 0.00

2 138.000 3.5725 0.5725 0.01

t 139. OCC 3*6049 0.6023 0.43

2 140.000 3.6334 0.6333 0.G1

2 142. OUO 0.6992 0 . 6991 0.00

1 143.000 0.7370 0.7340 0.41

2 144.000 3.7733 0.7703 G • GO

2 146.0 06 0.8471 0.8471 -0.00

1 1 **7 ® 0 0 0 9.8911 0. 8878 0. 37

2 148.000 3.9331 0.9301 -0.01

2 150. COG 1.3196 1. C 198 -0.01

1 151.000 1.3734 1.C672 0.30

2 192.0 CG 1.1154 1. 1165 -0. 02

2 154.000 1.2239 1.2211 -0.02

1 155.000 1.27 30 1. 2765 0.20

2 156.000 1.3338 1.3340 -0. 02

2 158.000 1*4550 1.4562 -C.01

1 153.006 1.5221 1.5210 0.07

2 160. OCC 1.5884 1.5804 0.CC

2 162.006 1.7322 1.7317 0.C3

1 163.000 1 . S'1 S3 1. 3079 -0. 09

2 164.000 1.8586 1.8874 , 6.07

2 166. u u 0 2.3593 2. 0567 C . 13

1 167 . C C 0 2.1438 2. 1471 -0.29

2 168.300 2.2455 2. 2416 0.22

1613 169. 067 2.3438 2. 3472 G.37

161% 169.276 2.3687 2. 3679 C.03

912 169.417 2.3858 2.3830 C.12

43
Table 1-A. The saturated vapor densities (continued)

id T,K MQl/L CALCD PCNT

1612 169s468 2.3331 2.3883 -0.01

910 169.601 2.4054 2.4021 0.14

90S 169.794 2.4236 2.4223 0.C6

1 171.000 2.5388 2.5526 -0.54

1716 173.088 2.7972 2.7974 -0.01

1714 173.290 2.8203 2.8225 -0.08

1712 173.489 2.8457 2.8475 -0.06

1012 173.473 2.8430 2. 8455 0.09

1010 173.675 2.8700 2.8711 -0.04

10 08 173.857 2.8935 2. 8944 -0.03

1 175.000 3.0199 3.0462 -0.87

1816 177.094 3.3501 3. 3514 -0.04

1814 177.292 3.3801 3.3823 -0.C6

1114 177.328 3.3863 3.3879 -0.05

1812 177.485 3.4108 3.4126 -0.06

1112 177.509 3.4209 3.4166 0.13

1110 177.700 3.4612 3.4472 0.38

1916 181.105 *•0663 4.0659 0.01

1914 181.304 *.1077 4.1072 0.01

1213 181.389 4.1269 4.1250 G • 05

1912 181.506 4.1496 4.1498 -0.01

1211 181.589 4.1656 4.1675 -0.05

1209 181.768 4.2042 4.2062 -0.05

1516 183.117 4.5212 4.5188 0.05

1514 183.522 *.5714 4.5700 0.01

1512 183.514 4.6139 4.6189 0.00

1316 184.125 4.7822 4.7814 0.02

2108 184.087 4.7825 4.7710 0.24

2107 184.285 4.8263 4.8258 0.01

1314 184.370 4.8462 4.8498 -0.07

2106 184.471 4.8797 4. 8786 0.02

1312 184.510 4.8876 4.8898 -0.04

6 185.030 5.0380 5.C445 -0.13

6 186.030 5.38*0 5.3748 0.17

2208 186.103 5.4077 5. 4007 0.13

1416 186.129 5.4096 5.4101 -0.01

1*14 186.319 5.4795 5.4798 -0.01

2207 186. 304 5.4827 5.4742 0.15

2206 186. 5C1 5.5571 5. 5487 0.15

1412 186.518 5.5591 5.5552 0.07

6 187.031 5.7850 5.7628 0.40

6 188.031 6.2750 6.2394 0.57

2308 188.140 6.2930 6.2988 -0.09

2307 188.343 6.4067 6.4150 -0.13

2306 188.545 6.5278 6.5382 -0.16

6 189.032 6.9190 6.6756 0.61

5 189.765 7.5510 7. 5664 -0.20

5 189.785 7.5510 7.5906 -0.52

5 190.046 7.9350 7.9525 -C.22

5 190.066 7

• 935 0 7.9850 -0.63

6 190.032 7.960C 7.9303 0.37

7 190.070 8.0010 7.9916 0.11

7 190.170 9. 1700 8.1692 0.01

7 190.270 8.3600 8. 3799 -0.24

5 190.279 8.3920 8.4011 -0.11

5 190.299 3.3920 8.4497 -0.69

7 190.370 3.6210 8.6449 -0.29

7 190.470 9.0130 9.0246 -0.28

5 190.480 9.1610 9. 0758 C • 93

5 190.500 9.1610 9.1917 -0.34

5 190 .524 9.6860 9.3706 3.25

NP = 123, RMSPCT = 0.376

44
Table 1 -B. The saturated liquid densities

10 T,K MGL/L CALCD PONT

5 190,530 1C. 059 10.790 "7.27

5 190.515 10.796 10.936 -1.30

5 190.442 11.357 11.362 B.04

5 190.462 11.357 11.270 0,®6

7 190 .470 11.410 11,229 1.59

7 190.370 11.790 11.62® 1.37

5 190.316 11,824 11.786 0.32

5 , 190.336 11.824 11.730 0.79

7 190.270 12.070 11.904 1,3®

7 190.170 12.270 12.123 1.20

5 190.04® 12.397 12.346 0,41

5 190.06® 12.397 12.312 0,68

7 190.070 12.440 12.309 1,05

6 190.032 12.474 12.373 0.81

5 1 09.707 12.879 12.830 0.3®

5 109.311 13.300 13.255 0.34

5 109.331 13.330 13.236 S.48

6 109.032 13.578 13.506 0.53

114 180.000 14.284 14.242 0.29

6 188.031 14.285 14.223 0.44

5 107.469 14.582 14.549 0.22

5 187.489 14.532 ' 14.538 0.30

6 187.031 14.8 J6 14.779 0 . 38

113 186. CCO 15.286 15.260 0,18

6 106.030 15.332 15.246 0.36

6 185. 03C 15.710 15.655 0.35

112 184.000 16.034 16.031 0.14

aG* 184. 000 16.060 16.031 C.18

lit 180.000 17.249 17.230 0.11

603 180.000 17.254 17.230 0.14

1 175.053 18.390 18.389 o.co

110 175.000 18.417 18.400 C.C9

602 175.000 16.420 18.400 0.11

109 170.000 19.397 19.372 0.0@

1 169.326 19.432 19.492 -0.00

10® 165.000 20.2 14 20.219 0.07

1 163.659 20.42® 20.431 -C.C1

107 160.000 20.991 20.981 0.05

1 157.199 21.379 21.378 0.00

1U6 155.000 21.696 21,670 0.04

1 151.553 22.130 22.129 0.30

105 150.000 22, 329 22.325 0.02

601 150.000 22.332 22.325 0. 03

1 145.448 22. 880 22.880 0 » GO

lot* 1 45 .0 C 0 22.932 22.933 -0.00

103 1 40 o u 0 0 23.500 23.50® -0,03

1 139.352 23.576 23.580 -0.01

102 135.000 24.041 24.055 -0.C5

1 133.878 24.176 24.174 0.C1

1 133.773 24.186 24.185 0.00

101 130.000 24.556 24.578 -0.08

1 129.657 24.611 24.613 -0.01

1 125.825 24.999 24.999 -0.00

1 121,893 25.38® 25.384 0.01

1 117.746 25.782 25.779 0.01

1 113.772 26.146 26.149 -0.01

1 109,611 26.527 26.526 0.30

1 105.165 26.916 26.920 -0.02

I 1Q1.434 27.243 27.244 -0.00

1 97.173 27,635 27.60? -0.01

1 93.512 27.910 27.913 ”0.01

NP * 61 $ RMSPCT s 1.Q55

45
Table 1-C. The vapor -liquid saturation temperatures

ID T» K CALG PONT MOl/l CALC PCNT OTS/DO

2 90.660 90.681 -0.00 @® 0157 0 ® 0 157 0.01 539.6170

1 91.008 91.018 ~0e 01 0. 0163 0.0163 0.12 523.2873

2 92.000 92.003 0. 00 0.0183 0. 0183 -0.00 477.9297

2 94.000 94.803 -0.00 0.0229 0. 0229 0.00 400.7747

1 99.000 95.013 -0.01 0.0255 0. 0255 0.14 367. 8597

2 96.000 95. 993 0.00 0.0263 0.0283 -0.02 339. 1716

2 98.000 98.800 0. 00 0.0347 0. 0 347 -0.00 289.3527

2 160.060 108.301 -0.00 0.0422 0.0422 0.01 248.7637

2 182.000 102.803 -0.00 0.0508 0.0506 0.00 215. 4135

1 103. COO 103.017 -0.02 0.0557 0. 0556 0.15 200.7235

2 10 4. COO 104.801 -0. 00 0.0608 0. 0608 0.01 187.7496

2 106.00 0 106.001 -0.00 0.0722 0. 0722 0.01 164.6375

1 107. GOO 107.027 -0.03 9. 0796 0. 0784 0.22 154. 2492

2 108.000 108.001 -0.00 0.0851 0.0851 0.01 145.1854

2 118.000 110.303 0.00 0.0997 0.0998 -0.00 128.7044

1 111. GOO 111.042 -0.04 0.1081 0. 1076 0. 32 121.1022

2 112. GOO 112.003 0. 00 0. 1162 0. 1162 -0. 00 114.6394

2 114.000 113.999 0.00 0.1347 0.1347 -0.01 102.5721

i 115. 008 115. 347 -0.04 0.1452 G. 1447 0.34 96.9191

2 116. Q00 115. 999 0. 00 0.1553 0. 1553 -0.01 92.1464

2 118. COO 117. 999 0. 00 0. 1781 0. 1782 -0. 01 83. 0959

1 119.000 119.055 -0.05 0.1912 0. 1905 0.37 78.7909

2 120.00 0 119.999 0.00 0.2G35 G. 2035 -0.01 75. 1942

2 122.000 121.998 0.00 0.2314 0.2314 -0.01 68.2622

1 123.000 123. 058 -0. 05 0. 247 3 9. 2464 0.36 64.9313

2 124.000 123.939 0.00 0.2621 0. 2621 -0.01 62.1479

2 126.000 125. 999 0.00 0.2958 0.2956 -0.00 56.7308

1 127. COO 127.367 -0.05 0.3151 0. 3139 0.39 54.0902

2 12 8. COO 128.003 -0. 00 0. 3327 0. 3327 0.00 51.9089

2 130 .000 130. 801 -C. 00 0. 3730 0. 3730 0.01 47.5991

i 131.000 131.075 -0.06 0. 3961 0.3944 0.42 45.4697

2 132.000 132. 802 -0.00 0.4169 0.4168 0.01 43.7308

2 134.000 134.802 -0. 00 0.4646 0.4645 0.01 40.2444

1 135.000 135.082 -0.06 0.4920 G. 4899 0.43 38.5C38

2 136.008 136.003 -0.00 0.5164 C. 5163 0.02 37.0898

2 136.000 138.804 -0.00 0.5725 C. 5724 0. 02 34. 2 259

1 139.000 139.087 -0.06 0.6049 0.6022 0.44 32. 7830

2 148.000 148.004 -0.00 0.6334 0. 6333 0.02 31.6170

2 14 2.00 0 142.803 -0.00 0.6992 0. 6991 0.02 29.2325

1 143.000 143.086 -0.06 0. 7370 0.7339 0.42 28. 0250

2 144.000 144.802 -0.00 0.77C 3 0. 7702 0.01 27. 0461

2 146.000 146.801 -0.00 0.8471 0.8471 0.00 25.0355

1 147.000 147.383 -0.05 0.8911 C. 8878 0.37 24.0165

2 148.000 147.999 0.Q0 0. 9301 0. 9301 -0. 00 23. 1816

2 150.000 149.997 0.00 1.0196 1. 0198 -0.02 21.4675

1 151.C0Q 151. 364 -0.04 1.0704 1. 0673 0.29 20.6035

2 152.00 0 151.994 0.00 1.1164 1. 1166 -0.03 19.8781

2 154.000 153. 992 0. Cl 1. 2209 1. 2213 -0.03 18.4009

1 155.000 155. 841 — 0 . C 3 1.279U 1.2767 0.16 17.6668

2 156.00 0 155.991 0.01 1.3338 1. 3343 -0.04 17. 3241

2 158.000 157. 991 0.01 1.4560 1.4566 -0.04 15.7372

1 159. COO 159.313 -c. 01 1. 5221 1. 5214 0.04 15.1133

2 160.000 159. 993 0.00 1.5884 1.5889 -0.03 14.5308

2 162. COO 161.998 0.00 1.7322 1.7323 -0.01 13.3960

1 163. COO 162.971 0.02 1.6063 1. 8065 -0.12 12.8693

2 164.000 164. 80S -0.00 1.8686 1.8880 0.03 12. 3245

2 166.000 166.32* -0.01 2.0593 2. 0573 0.10 11. 3C85

1 167. COO 166.927 0.04 2.1408 2. 1476 -0. 32 10. 8703

2 16 8. COO 168.047 -0.03 2.2465 2.2419 0.20 10. 3399

tfolb 169.067 169.083 -0.01 2. 3488 2. 3475 0.06 9.8630

1614 169.270 169.276 -C. 00 2.3687 2.3681 0.02 9.7740

912 169.417 169. 442 -0.01 2. 3858 2. 3832 0.11 9.6985

46
Table 1-C . The vapor-liquid saturation temperatures (continued)

10 T»K CALC PONT MOl/L CALC PC NT OTS/OO

1612 169.468 169.464 0 . 00 2. 3681 2. 3885 - 0.02 9.6884

9

Cl 169.601 169.631 • 0.02 2.4054 2.4022 0.13 9.6130

9 J 8 169.794 169.306 - 0.01 2. 4236 2. 4224 0.05 9.5345

1 171.000 170. 876 0 . 07 2.5368 2 . 5525 - 0 . 54 9 . 05 86

1716 173.088 173. 091 - 0.00 2.7972 2. 7969 0.01 6 . 1 C 34

1714 173.290 173.277 0.01 2.8203 2. 8219 - 0.06 8.0246

1712 173.489 173.483 0.01 2.8457 2.8469 - 0*04 7. 9391

1012 173.473 173.498 - 0 . 01 2. 8480 2. 8449 0.11 7.9314

1010 173.675 173.672 o. au 2.8700 2. 8704 - 0.02 7. 8584

1u 8 173.857 173.855 0.00 2. 8935 2. 8937 - 0.01 7,7813

1 175.000 174.813 0.11 3.0199 3 . 0453 - 0.84 7.3825

1816 177.094 177. 393 0 . oo 3. 3501 3.3502 - 0.00 6.4505

1814 177.292 177.285 0.00 3.3801 3. 3811 - 0.03 6 . 37 28

111 -* 177.328 177.325 0.00 3.3863 3 . 3868 - 0.01 6. 3568

1812 177.485 177.483 0.00 3.4103 3.4116 - 0.02 6. 2942

1112 177.509 177.543 - 0 . G 2 3.4209 3.4154 0.16 6.2686

1110 177.700 177.788 - 0 . 05 3.4602 3.4460 0.41 6. 1701

1916 181.105 181.108 - 0.00 4.0663 4. 0657 0.02 4. 8413

191 h 181.304 181.307 - 0 . 00 4. 1077 4. 1071 0.01 4. 7619

1213 181.389 181.398 - 0.03 4. 1269 4. 1250 0.05 4.7256

1912 181.506 181.505 0.00 4,1496 4. 1499 - 0.01 4. 6829

1211 181.589 181.579 0.01 4.1656 4. 1677 - 0.05 4.6531

1209 181.768 181. 758 Q . 01 4.2042 4.2065 - 0.05 4.5819

1516 183.117 183.122 - O ’. 00 4.5212 4. 5200 0.03 4.0358

1514 183.322 183.318 0.00 4.5704 4. 5713 - 0.02 3. 9569

1512 183,514 183.508 0.00 4.6189 4.6204 - 0 . 03 3. 8805

1316 184.125 184.122 0.00 4.7822 4.7831 - 0.02 3.6335

2108 184.087 184.123 - 0.02 4.7825 4.7727 0.21 3.6331

2107 184.285 164.263 0.00 4. 8263 4. 8276 - 0 . G 3 3.5694

1314 184.370 189. 351 0.01 4 . 8462 4. 8515 - 0.11 3.5408

21 C 6 184.471 164.469 0.00 4.8797 4.6803 - 0.01 3.4931

1312 194.510 18<+.*97 0.01 4.8876 4 . 8915 - 0.08 3.4820

6 185 . C 3 J 185.305 0.01 5.0380 5.0458 - 0.15 3.2759

o 186.030 186.062 - 0 . 02 5.3840 5. 3731 0.20 2. 8434

22 o 8 186.103 186.129 - 0.01 5.4077 5.3986 0.17 2. 8158

1416 186.129 186.134 - 0.00 5.4096 5.4078 0.03 2.8136

1 4

* 186.319 186. 323 - 0.00 5.4795 5.4762 0.06 2.7334

2207 186 . 30 ** 186 . 3 37 - 0 . 02 5.4827 5 . 47 C 7 0.22 2. 7298

220 o 18 o . 501 186. 537 - 0.02 5.5571 5 . 5436 0.24 2. 6467

1412 186.518 186.542 - 0.01 5. 5591 5. 5500 0.16 2.6445

t> 187.031 187.114 - 0.04 5.7660 5.7515 0.60 2.40 42

6 188.031 188 . 17^

- 0 . 08 6. 2750 6. 2026 1.15 1.9420

2 3 u 0 188.140 188.209 - 0.04 6. 2930 6. 2574 0.57 1.9262

2 3 L 7 188.343 188.423 - 0 . 04 6 . ‘067 6. 3636 0.67 1. 8276

2 3 0 6 188.545 188.633 - 0.05 6.5278 6.4748 0.81 1.7257

o 189 . C 32 189. 249 - o . 11 6. 9180 6.7702 2.14 1.4101

5 189.765 189. 984 - 0.12 7.5510 7. 3317 2.90 G .9129

5 189.785 189 . 98-* - 0.10 7.5510 7 . 35 C 2 2.66 0. 9129

5 193 . C 46 190.277 - G .12 7.9350 7 . 62 C 9 3.96 0.6103

5 193.066 190. 277 - 0 . 11 7.9350 7.6444 3.66 0.6103

6 193.032 190.292 - C . 14 7.9600 7.6047 4.46 0.5909

**

1 190.170 190.315 - 0.13 8. 000 C 7 . 6492 4 . 38 0.5599

7 193 .170 190. 399 - 0.12 8 . 1700 7.7766 4 . 82 0. 4313

7 190.270 190.463 - 0 . 10 8 . 360 C 7. 9244 5.21 0.2978

5 190.279 190. 477 - 0. 10 8.3920 7.9391 5.40 0.2769

5 190.299 190.477 - 0.09 8.3920 7.9728 5.00 0. 2769

/ 190.370 190.524 - 0 . G 8 6.6200 8. 1066 5 . 96 0. 1461

7 190.47193.553 - 0.04 9 . 0000 6® 3676 7. 03 0.0226

5 190.430 190.555 - 0.04 9.1610 8. 4032 0.27 0.0056

5 190.50 0 190.555 - 0.03 9.1610 6. 4851 7.38 0 . 0 0 56

6 193.524 190 * 5 35 - 0 . 02 9.6860 8 . 6164 11 . 04 0 . 00 00

5 190.530 190.555 - 0.01 10,0590 11 . 463®

- 13.97 - u . 0000

5 193 .515 193.555 - 0 . 02 10,7960 11.5780 - 7.24 - 0 . 0 C 16

47
Table 1-C. The vapor-liquid saturation temperatures (continued)

10 T, K CALC PONT MQL/L CALC PONT DTS/OD

5 193 .442 190.539 -0. 05 11. 3670 11. 9013 -4. 70 -0. 0800

5 190.462 190.539 -0. 04 11,3670 11. 8315 -4.09 -0.0800

7 110.470 199.535 -0.03 11.4100 11. @009 -3.43 -0.0930

7 190 e 37 0 190.473 -0.05 11.7900 12.1022 -2.65 -0.2480

5 190 . 316 190. 464 “0.0® 11. 8240 12. 222® -3. 37 -0.2648

5 190.336 190.464 -0. 07 11. 8240 12. 1801 -3. 01 -0.2648

7 190.270 190.383 -0.06 12.0700 12. 3127 -2.01 -0. 3960

7 190.170 190.292 -0.06 12.2700 12.4827 -1.73 -0.5116

5 190.048 190.223 »0. 89 12. 3970 12.6587 -2.11 -0.5876

5 190.068 190 . 223 “0.08 12.3970 12.6316 -1. 89 -0.5876

7 190 .070 199.197 -0.07 12.4400 12.6289 -1.52 -0.6136

b 190. C32 190.176 ”0.08 12.4740 12.6799 -1.65 -0. 6342

5 189.707 189. 368 “0.09 12.8790 13.0514 -1.34 -0.8635

5 189.311 189.442 -0.07 13. 3000 13. 4109 -0.83 -1. 1436

5 189.331 189. *42 “0.06 13.3000 13. 3943 -0.71 -1. 1436

6 189.032 189.133 “0.04 13.5783 13.6292 -0. 38 -1. 3149

114 188.000 183.018 -0.01 14.2837 14.2942 -0.07 -1.7510

6 188.031 188. 016 0. 01 14.2850 14. 2763 0.06 -1.7518

5 187.469 187. 468 0.00 14.5820 14. 5816 0.00 -1. 9381

5 187.489 187.463 0.01 14.5820 14.5713 0. 07 -1. 9381

b 187.031 186.955 0.04 14.8360 14.7999 0.24 -2. 0998

113 186. COO 185.944 0.03 15.2864 15. 2629 0.15 -2. 3934

6 186.030 185.906 0.07 15.3020 15. 25G0 0.34 -2.4038

b 185.030 184. 873 0. 09 15. 7100 15. 6498 0. 38 -2.6790

112 134.000 183.903 0.05 16.0539 16. 0221 0.20 -2.9185

604 184. COO 183.893 0.06 16.0599 16. 0221 0.24 -2.9227

111 180.000 179. 893 0. 06 17.2491 17.2222 0.16 -3.8051

6 G 3 18 0.000 179. 873 0. 07 17.2540 17. 2222 0.18 -3.8089

1 175.053 175.343 0.01 18. 3900 18. 3872 0.02 -4.7202

llu 175. COO 174.914 0.05 18.4167 18. 3985 0.10 -4.7422

6 y 2 175.000 174.896 0.06 18.4204 18.3985 C • 12 -4.7452

1 u 9 170.000 169. 921 0. 05 19. 3869 19. 3726 0.07 -5.5531

1 169.326 169. 333 -0.00 19.4920 19. 4932 -0.01 -5. 6417

10 8 165.C0 0 164.917 0.05 20.2335 20.2203 0.07 -6.2671

1 163.659 163.682 -0.01 20.4280 20.4316 -0.02 -6.4305

1 w 7 16J.0G0 159. 932 0. 04 20.9906 20.9808 0.05 -6.9001

1 157.199 157.193 0.01 21.3790 21.3777 0.01 -7.2206

It b 155.000 154. 9 36 0. 04 21. 6858 21. 6772 0. 04 -7.4714

1 151.553 151.537 0.01 22. 1300 22. 1280 0.01 -7. 8305

1 c p 150.000 149.962 0.03 22.3292 22. 3244 0.02 -7.9901

feel 150 .000 149.942 0.04 22.3316 22. 3244 0.03 -7. 9920

1 145.448 145. 443 0. 01 22. 8800 22.8791 0.00 -8.4268

104 145 .C00 145. 001 -0. 00 22. 9320 22. 9321 -0. 0J -8.4677

103 140 .000 140.065 -0.05 23. < 99

9

23. 5073 -0.03 -8. 9116

1 139.352 139.367 -0.01 23.5780 23.5797 -c. 01 -8. 9723

1 u 2 135. COO 135.126 -0.09 24.0414 24. 0549 -0.06 -9. 3310

1 133.878 133.864 0.01 24. 1760 24. 1745 0.01 -9.4347

1 133.773 133.769 0. 00 24.1860 24. 1856 0. CO -9. 4424

It 1 130. COO 130.202 -C.16 24.5581 24. 5789 -0.08 -9. 7282

1 129.657 129.687 -0.02 24.6110 24.6140 -0.01 -9. 7688

1 125.825 125.839 -0. 01 24.9990 25. 0C 04 -0.01 -10.0648

1 121.893 121.866 0. 02 25.3880 25. 3854 0.01 -10.3589

1 117.746 117.727 0.02 25.7820 25. 7802 0.01 -10.6521

1 113.772 113.801 -0.03 26. 1460 26. 1487 -0.01 -10.9166

1 109.611 109*591 0. 02 26.5270 26.5252 0.01 -11. 1833

1 105.165 105. 193 -0.02 26.9160 26. 9182 -0.01 -11.4404

1 101.434 101. 416 0. 02 27. 2430 27. 2414 o. 01 -11.6403

1 97.173 97.165 0.01 27.6050 27.6043 0.00 -11.8390

1 93.512 93. 532 -0.02 27.9100 27.9116 -0.01 -11.9836

NP * 18h, TSRMSPCT * 0.045, DNRMSPCT * 2.185

48
Table 2-A. The second virial coefficient

5*05000 00 00 +002 1.697431768+0 01 -8.005503820+001

1.235409580+002 -9.260135405+001 4.297412052+001

ID T » K 1/11 0+ CALC PC NT

3 110.830 lo 22221 -3.3010 -3. 3143 -0.40

3 112.430 1.23985 -3. 1990 -3. 2 037 -0.15

3 114.440 1.26202 -3.0780 -3. 0750 0.10

3 116.780 1.28783 -2.9550 -2. 9379 0.58

3 121.240 1.33701 -2.7450 -2. 7 085 1. 35

4 126.571 1. 39580 -2.4227 -2. 4780 -2. 23

3 128.830 1.42071 -2.4430 -2. 3918 2. 14

2 131.920 1,45479 -2.2400 -2. 2831 -1. 89

* 1 35.984 1.49960 -2.1520 -2. 1540 -0. 09

4 147.581 1.62749 -1.8500 -1. 8505 -0. Q3

4 158.916 1.75249 -1.6151 -1. 6 184 -0.21

5 168 .0 00 1.85267 -1.4750 -1. 4636 0.78

4 173.507 1.91340 -1. 3763 -1. 3800 -0. 27

5 176.000 1.94089 -1.3490 -1. 3443 0. 35

3 179.440 1.96780 -1. 3220 -1. 3106 0. 87

5 184.000 2.02911 -1.2380 -1. 2 380 C. 00

2 191.090 2. 10730 -1. 1631 -1. 1527 0. 90

4 191.129 2.10773 -1.1429 -1. 1523 -0.81

5 192. COO 2.11734 -1.1390 -1. 1423 -0,29

5 200.000 2.20556 -1.0510 -1. 0558 -C.46

2 203.030 2.20599 -1.0668 -1. 0555 1. 07

3 202.520 2.23335 -1.0340 -1. 0 302 C. 37

5 210.000 2.31584 -0.9530 -0. 9586 -0.59

5 22Q .000 2.42611 -0.8660 -0. 8719 -0.67

3 221.130 2.43850 -0. 8580 -0. 8626 -0.54

5 230 .0 00 2.53639 -0.7890 -0. 7941 -0.64

5 240.000 2.64667 -0.7200 -0. 7240 -0.56

2 240 .020 2.64689 -0. 7272 -0. 7 239 0.46

3 243.820 2.68880 -0. 70 30 -0. 6991 0. 56

5 260. 0C0 2.86723 -0.6020 -0. 6 0 35 -0. 25

1 273.150 3.01224 -0.5335 -0. 5361 -0,48

2 273.150 3.01224 -0.5328 -0. 5361 -0.61

3 273.170 3.01246 -0.5370 -0. 5360 0.19

5 280.0 00 3.08778 - 0.5050 -0. 5041 0.17

1 298,142 3.28785 -0. 4282 - 0. 4204 -0.04

5 3 0 0 .0 0 0 3.30834 -0.4230 -0. 4213 0.41

1 303.141 3.34298 -0.4091 -0. 4095 -0. 1C

5 320 .0 0 0 3.52889 -0, 3540 -0. 3515 0.72

1 323.140 3.56352 -0. 3423 -0. 3415 0. 24

5 340.000 3.74945 -0.2940 -0. 2920 0. 70

1 346 .143 3.83925 -0.2706 -0. 2702 C. 15

5 360.0 CO 3.97000 - 0. 2420 -0. 2407 0.55

1 373.150 4.11502 -0.2100 -0. 2106 -0. 29

5 3 30 .0 0 0 4.19056 -0, 1970 -0. 1959 0. 55

1 398.160 4.39082 -0.1587 -0. 1598 -C.71

5 400.000 4.41112 -C. 1570 -0. 1564 0.40

1 423.170 4. 66663 -0.1140 -0. 1 157 -1. 45

1 448.182 4.94246 - 0. 0756 -0. P 765 -1. 18

5 450 .000 4.96251 - 0.0740 -0, 0 730 0.25

1 473.193 5.21827 -0.0416 -0. 0411 1.25

3 136.740 1.50794 -2.1890 -2. 1315 2.70

3 148.280 1.63520 -1.8770 -1. 8347 2.31

5 160.000 1.76445 -1.6190 -1. 5987 1.27

3 162 .300 1.78981 -1.5840 -1. 5580 1 . 67

2 2 15 .0 30 2.37131 -0.9259 -0. 9138 1. 33

1 498.203 5.494C8 -0. 0116 -0. 0 085 36.85

NP = 50 ? < MSP C T = 0.786
Table 2-B. The third virial coefficient

139. 92200 0. 36212 0. 83584 18 .69531 9. 15517

ID T,K T/TT C* CALC PC NT

4 135.984 1.49960 -0.1497 -0. 1497 0. 00

4 147 .581 1.62749 0.1950 0. 1950 0.02

4 191.129 2.10773 0.3990 0. 3990 -0.00

1 273.150 3.01224 0. 2620 0. 2634 -0.54

1 298.142 3.28785 0.2370 0. 2358 0.52

1 303.141 3.34298 0.2320 , 0.2310 0.42

1 323.140 3.56352 0.2150 0. 2144 0.30

1 348.143 3.83925 0.1975 0.1976 -0.06

1 373.150 4.11502 0. 1834 0. 1844 -0.52

1 398.160 4.39082 0.1727 0. 1737 -0.55

1 423.170 4.66663 0. 1640 0. 1649 -0.53

1 448.182 4.94246 0.1585 0. 1575 0.60

1 473.193 5.21827 0.1514 0. 1513 0.04

1 498 .203 5.49408 0.1465 0. 1460 0. 33

4 126.571 1.39580 -2. 0500 -0. 7277 181.70

4 158.916 1.75249 0.3580 0. 3 399 5. 33

4 173.507 1.91340 0.4381 0. 4010 9. 26

2 191.090 2.10730 0.4741 0. 3990 18. 81

2 2 00.0 30 2.20589 0. 4351 0. 3860 12. 71

2 215.0 30 2.37131 0.4169 0. 3586 16.27

2 240 .020 2.64689 0.3508 0. 3125 12.25

2 273.150 3.01224 0.2670 0. 2634 1.34

NP = 14* RMSPCT = 0.393

SO
Range

of

the

Variables

Deviations,

(U co o CO

m in «—

cu< o in vO if) o 00 o o © o vO o o CM

O' r- r- CO CO o •""I 1 CO o O' CO • 1 • • • • <3 o o 1 o o o o

vO O' CO f—

00 vO

if) t" vo r~- in vO

if) CM f—H o o o o o o <—

o o LO if) CM o o c-H CO X) CO f“H

X.

1 1 1 1 1 1 i o CO if) MD i—

o CM 1—=

fM

(M o O CO 00 00 CO O' # h- o 00 O' r- o CO

CM rO CM co CO

PQ i l i J 1 i 1 2 o fM co in co CO f-4 ’V

in O' r^- o f—t

a

f—«) CM CM r-H (3
Table 4. Comparison of experimental and calculated P-p-T values

The following pages compare experimental P-P-T (compressibility) data with

densities and pressures computed by the equation of state (6). The first column identifies sources of the data (as in table 3) --

ID = 2, Via Virial and Vapor-Pressure equations;

ID = 3, Vennix [66];

ID = 4, van Itterbeek [65];

ID = 6, Douslin [17];

ID = 8, Kvalnes [41];

ID = 10, Cheng [9];

ID = xxx, xxxx, this laboratory [30].

The equation of state was adjusted only to data of ID = 2, 6 and this laboratory.

Remaining data validate our extrapolation to higher pressures. Density deviations should

be ignored near the critical point, and pressure deviations should be ignored for compressed liquid at low temperatures for reasons given in the text. A few of Vennix' data near the critical point have spurious, extreme density deviations because our computer

search assigns the opposite phase via eq (6), (i.e. vapor vs. liquid).

52
METHANE EQUATION OF STATE

ID T»K MOL/L CALCO 0 , PCT P , BAR CALCD P , PC T 2 150.000 1.0000 1.0007 - 0.07 10.260 10.255 0.05

2 155.000 1. 0000 1.0038 - 0.08 10.744 10.738 0.06

2 160.000 1.0000 1.0007 - 0.07 11 . 222 11.216 0.06

2 165. 000 1.0000 1.0006 - 0.06 11.696 11.690 0 . 05

2 170.000 1.0000 1.0004 - 0.04 12.165 12. 161 0.04

2 175.000 1.0000 1.0003 - 0.03 12.632 12.629 0.02

2 160.000 1.0000 1.0031 - 0.01 13.096 13.095 0.0 1 2 185.000 1.0000 1.0030 - 0.00 13.559 13.559 0.0 0 2 1 * 0.000 1 . 000 0 0.9999 0.01 14. 020 14. 021 - 0 . 0 1 2 195.000 1. 0000 0.9998 0.02 14.479 14.461 - 0 . 0 1 2 200.000 1. 0000 0.9998 0.02 14.937 14.940 - 0.0 2 2 205.000 1.0000 0.99 38 0 • C 2 15.394 15.398 - o . C 2 2 210 . 000 1.0000 0.9997 0.03 15.851 15.854 - 0.02

2 215.000 1. 0000 0.9998 0.02 16.306 1

• 3 1 C - 0.0 2 2 220.000 1.0000 0.9938 0.02 16. 761 16. 764 - 0.02

2 225.000 1.0000 3.9938 0.02 17 .215 17. 216 - 0 . 02

2 230. 000 1.0000 0.9998 0.02 17.668 17.671 - 0.02

2 235 .000 1.0000 0.9999 0.01 18.120 16. 123 - 0.0 1 2 2 h 0 .

00 1.0000 0.3939 0.01 18.572 18.574 - 0.0 1 2 245.000 1 . 0000 3.9999 0.01 19.023 19. 025 - 0 . 0 1 2 250 .000 1.0000 1.0030 0.00 19.474 19.475 - 0.0 0 2 255.000 1.0000 1.3000 0.00 19.924 19.924 — u . 0 0 2 260.000 1.0000 1.0030 - 0.00 20.373 20.373 0.0 0 2 265 .000 1. 0000 1 . 0 3 0 0 - 0.00 2

-0.822 20.822 0.0 0 2 270.000 1.0000 1.0031 - 0.01 21.271 21 . 27 C 0.0 1 2 170 . 000 2.0000 1.9336 0.02 20.616 20.618 - 0 . C 1 2 175 . 000 2.0000 1.3993 0.04 2

• 6 o 3 21.666 - 0.0 3 2 18 U . 000 2. 0000 1.9390 0.05 22.697 22.705 -0. Oh

2 165.000 2.0000 1.9938 0.06 23.721 23.732 - 0.04

2 190.000 2 . 000 C 1 . 9*86 0.07 24.737 24 . 73 C -0. 05

2 195.000 2 . 0

u 0

* 1.9986 0.07 25 .745 25.760 - 0 . C 6

2 200 . UQO 2 . 0000 1.9985 0.07 26. 746 26.763 - 0 . 0 6

2 205.000 2.0000 1.3936 0.07 27.746 27. 761 - 0 . C 6

2 210.000 2 . 00 0 0 1.9987 0.07 28.739 28.754 - 0 . C 5 2 215.000 2.0000 1.9988 0.06 29.729 29. 743 -J.C5

2 220.000 2. 000 0 1.3990 0.05 30 . 715 30 . 72 e -0. 04

2 225.000 2. 0000 1.9992 0.04 31.698 31. 709 - 0 . C 3 2 230.000 2 . 0000 1.9934 0.03 32.677 32.686 -0.03

2 255.000 2.0000 1.3995 0.02 33.654 33.661 - 0 . C 2 2 240 .000 2.0000 1.9997 0.01 34.629 34.633 - 0.0 1 2 245.000 2. 0000 1.9939 0.01 35.601 35.602 - 0.0 1 2 250.000 2.0000 2.0030 - 0.00 36.570 36.^70 0.00

2 255.000 2.0000 2.0332 - 0.01 37.537 37. 534 0.0 1 2 2 o 0 • 0 0 0 2.0000 2.0 0 33 - 0.01 38.502 38.497 J . C 1 2 265. 000 2.0000 2 . 0)34 - 0.02 39.465 39.456 0.02

2 2 7 j . cro a 2 . u 0 0 0 2 .

3 3 4 - 0.02 40.426 40.416 0 . 02

NP = 46 , DNRMSPCT = 0 .(134 , PMEANPCT = 0.025

53
METHANE EQUATION OF STATE

10 T»K NOL/l C&L30 0» PCT P f BAR CALCC Pf PCT

3 171.527 2.5593 2.5643 -0.19 24.660 24.634 0.11

3 174,691 2® 5593 2.5649 -0.22 25.283 25.251 0.13

3 177,203 2.5586 2.56*8 -0.24 25.994 25.956 0. 14

3 1S3®176 2. 5560 2.5651 -0.28 27.666 27.617 0.18

3 190*532 2.5577 2.5o35 -0.23 29.676 29.631 0. 15

3 191.849 2.5568 2.5639 -0.28 30.038 29.981 0.19

3 203.064 2.5555 2.5621 -0.2© 33.048 32.986 0.19

3 213.341 2. 5543 2.56 J3 -0.24 35.672 35.608 0.16

3 217.864 2.5537 2.55 34 -0.22 36.931 36. 867 0.17

3 223.831 2. 5530 2.5565 -0.22 38.481 38.415 0.17

3 233.546 2. 5518 2.5573 -0.22 40.990 40. 918 0.18

3 239.797 2.5512 2.5553 -0.20 42.590 *2.520 0.16

3 252.333 2.6499 2.5538 -0.15 45.897 45.838 0.13

3 263.399 2. 5487 2.5519 -0.13 48.559 48.506 0.11

3 273.360 2.5474 2.5532 -0.11 51.058 51.006 0. 1 0 3 190 .<+29 6.4670 5.3216 2.25 44.720 *4 . 893 -0.39

3 190.532 6.4686 3.3256 2.21 44.814 44.987 -0.39

3 208.574 6.4614 5.4450 0.24 60.270 60 • 334 -0.11

3 223.234 6.4571 6.4550 0.02 72.346 72.3 53 -0.0 1 3 23*. 440 6.4539 5.4566 -0.05 81.433 81.409 0 * 0 3 3 243.733 6.4508 5.4570 -0.10 88.913 88.851 0. 0 7 3 243.773 6.4506 5.4555 -0.09 88.939 88.883 0.06

3 251.376 6.4483 5.4556 -0.11 95.018 94.937 0.08

3 262.190 6. 4452 3.4527 -0.12 103.601 103. 505 0.09

3 272.155 6.4421 5.4506 -0.13 111.478 111.352 0.11

3 272.185 6.4421 3.4503 -0.13 111.494 111.376 0.11

3 150.052 7.2329 5.9’74 3.53 44.989 45.132 -0. 32

3 190.532 7.2348 7.0178 3.00 45.493 45.631 -0.3 0 3 190.750 7.2329 7.0191 2.96 45.710 45.855 -0.32

3 191.032 7.2341 7.3347 2.76 46 • u 0

1

46.145 -0.31

3 193.325 7.2316 '.1136 1.59 48.336 48.462 -0.2b

3 197.737 7.2304 7.17 3? 0.79 52.722 52. 826 -0.20

3 202.753 7.2285 7.2331 0.39 57.627 57.702 -0.13

3 206.22* 7.2266 7.2134 0.18 62.9C9 62.956 -0.07

3 212.165 7.2264 7.2231 0.07 t>6. 689 66.712 -0. C 3 3 217.136 7.2235 7.2237 -0.00 71.421 7 1. 42C 0.00

3 222.926 7. 2217 7.2273 -0.08 76. 909 76. 875 o. 04

3 230 .050 7.2192 7.2263 -0.13 83.614 83.548 0. C 8 3 237.336 7.2167 7.2276 -0.15 90.432 90.338 0. 10

3 242. 709 7.2148 7.2253 -0.15 95.434 95. 325 0. 1 1 3 246 • 444 7. 2129 7.22*7 -0.16 100.757 100.633 0.12

3 250.194 7. 2123 7.2241 -G.16 102. 376 102. 249 0.12

3 253.445 7.2111 7.2227 -0.16 105.378 105. 247 0.12

3 253.642 7.2092 7. 22 09 -0.16 110.172 110.029 0.13

3 2o3. 050 7.2079 7.21 34 -0.16 114.229 114. 08C 0.13

3 266.301 7.2061 7.2175 -0.16 119.0*9 118.891 0.13

3 273.171 7.2042 7.2153 -0.15 123.504 123.340 0.13

3 191.032 9. 8404 6.5146 13.47 46.579 46 • © 7 3 -0.20

3 191.551 9.8370 3.1094 7.40 47.318 47.416 -0.21

3 192.938 9. 8364 9.5031 3.39 49.2 82 *9 • 4 0 C -0.24

3 195 .243 9.8351 3.6630 1.78 52.563 52.696 -0.25

3 197.562 9. 8345 3.7151 1.21 55.870 56.010 -0.25

54
methane equation of state

10 T,K MOl/l CALCO

3 200.411 9.8333 9.7715

3 202.629 9.8320 9.7753

3 206. 370 9. @301 9.7939

3 213.503 9.8270 9.8151

3 223.647 9.8220 9.8260

3 236.396 9.8158 9.8285

3 246.147 9. 8108 9.8255

3 255.163 9.8071 9.8224

3 273.167 9.7990 9.8115

3 191.032 10.2157 8.3057

3 190.639 10. 2128 8.5593

3 191® 040 10.2128 3.8045

3 191.229 10.2128 9.2097

3 191.426 10.2128 9.3856

3 191.820 10.2126 9.6095

3 192.076 10.2128 9.6636

3 193.522 10.2115 9.8983

3 195.156 10.2109 13.0050

3 197.926 10.2096 10.0779

3 200.575 10.2084 13.1137

3 204.037 10.2065 13.1425

3 207.855 10. 2047 13. 1577

3 207.655 10.2047 13.1631

3 213.044 10.2022 13.1786

3 233.386 10.1922 10.1934

3 252. 887 10. 1829 13.1934

3 273.016 10. 1729 13.1825

3 273.058 10.1729 13.1324

3 190.532 11.1588 7.7126

3 191.032 11.1582 9.32 31

3 191.646 11. 1543 13 .6174

3 191.873 11.1543 13.54p8

3 193.2*6 11. 1537 10 .7939

3 195.110 11.1531 13.9238

3 197.300 11.1518 13.9776

3 199.216 11.1506 11.3123

3 200.901 11.1500 11.0356

3 233.064 11.1487 11.0557

3 207 . 5b* 11.1452 11.0857

3 213.197 11.1431 11.1054

3 213.204 11.1431 11. 1J73

3 213.212 11. 1431 11. 1057

3 223.184 11.1375 11.12 37

3 233. 161 11.1325 11.1300

3 2*3. 137 11. 1269 11.1297

3 2p3. 153 11.1219 11.12*6

3 263. 124 11. 1163 11.1188

3 273.092 11. 1113 11.1139

3 273.150 11.1113 11.1054

3 1 91. 032 11.7666 10 . 3152

3 192. *98 11.7625 11.51*0

3 195. 8*0 11.7e07 11.6275

3 196.182 11.7594 11 .6592

PCT P 9 BAR CALCO P » PC T .63 59.977 60.083 -0.18

.58 63.417 63.541 -0.20

.37 68.503 68.607 -0.15

.12 78.771 78.823 -0.07

. 04 93.389 93.363 0.03

.13 111.767 111.649 0.11

. 15 128.674 128.499 0.14

.16 138.749 138.543 0. 15

.13 164.504 164.284 0.13

.79 *6.607 46 • o 95 -0. 19

.19 46.342 46.408 -0.14

.79 46.618 46.707 -0.19

.82 46.900 46.986 -0.19

.09 *7.108 47.284 -0.20

.91 47. 762 47.867 -0.22

.33 48.131 48.245 -0.24

.07 50 . 263 50.407 -0.29

.01 52. 700 52. 854 -0.29

.29 56.836 57.004 — U . 3 0 .93 60.014 60.985 -0.28

.63 66.036 6 b • 1 9f -0.24

.46 71.799 71.954 -0.22

.36 71. 833 71.954 -0. 17

.23 79.o91 79.795 -0.13

.06 110.688 110.633 0. C 5

. 10 140. 387 140.245 J. 1 0 .09 170.925 170. 75G 0.10

.09 170 . 987 170.814 0. 1 G .88 *5.83* *5.953 - 0 • 2

.39 46.643 4c. 755 -0.24

.81 47.983 48.091 -0.22

.45 48.009 48.13? - 0 . 2 to .18 50.248 5 0 • * 1 0 -0.32

.01 53. 340 53.525 -0. 35

.56 56.99? 5 7 . 2 lfc -0.39

.24 60.228 60.462 -0.39

.03 63. 092 63.329 -0. 36

.83 66.782 67.021 -0.36

.54 7*. 518 74.737 -0.29

. 33 84.266 84.44b -0.22

. 32 8*. 282 8 4 . 4b G -0. 21

.33 64.293 84.474 -0. ?1

.12 101 • ouO 1J 1 .763 -0.10

.02 119.122 119.14b -0.02

.03 136.601 1 36. 566 0 . C 3 .02 154.123 154. 063 0.03

.02 171.554 171.510 0. C 3 .02 180.977 188.924 o. C 3 .04 188.927 189. 02b -0.05

. 3 <3 46.7C1 46. 82fc -0.27

.11 49.295 49. 4U2 -0.22

.13 55.256 55.412 -0.28

.85 59.511 59.683 -0 .29

0,

0

0

0

0 -0

-0

-0

-0

-0

13

16

13

9

855

3

2

1

0

000

0 -G

-0

-G

-0

30

lb

4

5

32

1

11

0

0

u0

0

0

0 -o

-o

-0

- 0 . 0 12

2

1G

55
METHANE EQUATION OF STATE

ID t»k NQl/L CAL CD D,PCT P» BAR CALCO P,PCT

3 203.434 11.7563 11.6968 0.51 69.192 69.370 -0.26

3 212*034 11*7513 11.7267 0.21 85.306 85.435 -0.15

3 212*035 11.7513 11.7268 0.21 85.310 85.437 -0.15

3 222*632 11.7451 11.7489 0.04 105.407 105.441 -0.03

3 233*402 11*7395 11.7432 -0.03 125.956 125.916 0.03

3 233*403 11.7395 11.7446 -0.04 125.973 125.918 0.04

3 232*033 11.7370 11.7446 -0.06 132.922 132.832 0.07

3 232*034 11.7370 11.7443 -0.06 132.920 132.833 0.07

3 243.328 11*7332 11.7416 -0.07 145.053 144.937 0. 08

3 243.381 11.7332 11.7410 -0.07 145.050 144.943 0.07

3 253*284 11.7283 11.7352 -0.06 163.987 163.875 0.07

3 263.449 11.7220 11.7278 -0.05 183.402 183.291 0.06

3 268*300 11.7195 11.7254 -0.05 192.683 192.562 0. 06

3 268.300 11.7195 11.7251 -0.05 192.678 192.562 0.06

3 272.694 11.7170 11.7216 -0.04 201.050 200.949 0.05

3 272.695 11.7170 11.7215 -0.04 201.049 200.951 0.05

3 272.698 11.7170 11.7211 -0.03 201.046 200.957 0.04

3 190.032 12.8681 7.5715 41.16 45.236 45.328 -0.20

3 191.932 12.8675 12.7901 0.60 47.247 47.308 -0.13

3 190.532 12*8681 12.7514 0.91 46.239 46.312 -0.16

3 190.703 12.8636 12.7931 0.55 46.599 46.646 -C.ll

3 191.454 12.8636 12.8027 0.47 48.097 48.153 -0. 12

3 192.397 12.8630 12.7809 0.64 49.969 50.065 -0.19

3 196.505 12.8605 12.8326 0.22 58.521 56.567 -0.11

3 203.573 12. 8562 12.8560 0.00 73.642 73.643 -0.00

3 209.295 12.8524 12.8619 -0.09 86.110 86.039 0.08

3 218.622 12.8468 12.8679 -0.16 106.682 106.492 0.18

3 228.103 12.6406 12.8641 -0.18 127.755 127.474 0.22

3 238.550 12.8343 12.8578 -0.18 151.093 150.735 0.24

3 245.920 12.8294 12.8499 -0.16 167.546 167.186 0.21

3 252.972 12.8250 12.8450 -0.16 183.347 182.951 0.22

3 260.108 12*6206 12.8383 -0.14 199.300 198.910 0. 20

3 267.312 12*8163 12.8388 -0.11 215.373 215.019 0. 16

3 274.151 12.8119 12.8226 -0.08 230.576 230.292 0.12

3 188.969 13.7516 13.7460 0.04 43.856 43.864 -0.02

3 189.258 13.7510 13.7489 0.02 44.502 44.505 -0. 01

3 189.767 13.7510 13.7474 0.03 45.639 45.644 -0.01

3 190.032 13.7545 11.7498 0.03 46.240 46.248 -0.02

3 190.172 13. 7504 13.7455 0.04 46.549 46.557 -0.02

3 191.032 13.7539 13 . 75*4 -0.00 48.523 48.522 0.00

3 190.447 13.7504 13.7483 0.01 47.177 47.181 -0.01

3 190.532 13. 7545 13.7530 0.01 47 . 379 47.381 -0.01

3 190.738 13.7504 13.7487 0.01 47 • 8*.0 47.843 -0.C1

3 191.075 13. 7497 13.7513 -0.01 48.615 48.611 0.01

3 192.892 13.7485 13.7528 -0.03 52.817 52.805 0.02

3 195.048 13.7473 13.7573 -0.07 57.893 57.859 0.06

3 195.065 13.7473 13.7556 -0.06 57.928 57.899 0.C5

3 197.100 13.7460 13.7637 -0.11 62.787 62.727 0.10

3 200.010 13.7441 13.7651 -b.15 69.812 69.704 0.15

3 203.322 13.741b 13.7639 -0.21 77.904 77.72b 0.23

3 207.197 13.7392 13.7733 -0.23 87.439 87.202 0.27

3 213.323 13.7348 13.7743 -0.29 102.706 102. 320 0.38

3 222.792 13. 728b 13.7o69 -0.28 126.432 125.931 0.40

56
METHANE EQUATION OF STATE

10 T,K M0L/L CALCO

3 227.846 13.7254 13.7630

3 2 33.272 13.7217 13.7591

3 233 .

§

0 ® 13.7130 13.7518

3 242.935 13.7148 13.7466

3 243.766 13.7111 13.7388

3 253.111 13.7086 13.7335

3 258.314 13.7049 13.7273

3 262.932 13.7018 13.7222

3 267.319 13.6996 13.7160

3 267.886 13.6986 13.7160

3 273.153 13.6949 13.7100

3 187.649 14.9705 14.9416

3 183.927 14.9699 14.9507

3 190.532 14.9732 14.9599

3 191.453 14.9630 14.9620

3 194.804 14.9655 14.9707

3 199.611 14.9618 14.9815

3 203.054 14.9593 1*. 9852

3 207.627 14.9562 I *. 9880

3 212.935 14.9524 14.9872

3 221.360 14.9462 1 *98 16

3 223.637 14.9406 1 * • 97*3

3 236.599 14.9350 14.9652

3 245.086 14.9287 14.9542

3 253.068 14,9225 14.9444

3 260.336 14.9169 14.9326

3 268.824 14.9113 14.9213

3 275.154 14.9063 1* • 9137

3 183.351 16.5234 16.4653

3 185.267 16. 5215 16.4689

3 189.259 16.5184 16.4836

3 190 .532 16.5223 16.4839

3 194. *19 16 . 51*0 16.4931

3 198.420 16. 5109 16.4947

3 201.944 16,5084 16.5030

3 207.770 16.5028 15.4993

3 213.668 16. *978 16.4987

3 222.893 16.4903 lo . 49 ll

3 232.812 16.4622 15.4616

3 241.295 16.4754 16.4735

3 25*. 531 16.4648 16.4572

3 261.826 16.4586 16.4477

3 267.883 16.4536 16 • *40

3 272.981 16.4492 16.4329

3 179.140 17. 5640 17 . 53*3

3 179.830 17.5634 17,5336

3 181.008 17.5622 17.5324

3 184.441 17.5590 17.5311

3 190.532 17. 5595 17.5279

3 196.384 17.5485 17.5232

3 200.537 17.5447 17 .5261

3 203.822 17.5379 17 . 52*3

3 217.044 17.5304 17.5173

PCT P » BAR CALCO P»PCT

.27 139.174 138.615 0.40

.27 152.884 152.272 0.40

.25 166.109 165.479 0.38

.23 177.429 176.786 0 . 3 b

.20 192.026 191.409 0.32

.18 203.005 202.412 0.29

.16 216.145 215.573 0.26

.15 227.811 227.255 0.24

.13 240.117 239.614 0.21

.13 240.288 239.784 0.21

.11 253.551 253. 065 0.18

.19 43.274 43.375 - 0.23

.13 46.771 46.849 ” 0.17

.10 51.216 51.285 ” 0.14

. 04 53.786 53.818 - 0.06

.03 63.256 63.221 0.06

.13 77.104 76.930 0.23

.17 87.135 86.368 0.31

.21 100.574 100.183 0.39

.23 116.265 115. 759 0.44

.24 141.310 140.670 0.45

.23 163.016 162. 304 0.44

.20 186.801 186.064 0. 39

.17 212.140 211.429 0.34

.15 235.968 235.284 0.29

. 11 259. 036 258.498 0.21

.07 282.716 282.341 0.13

.05 301.472 301.178 0.10

.35 38.252 38.709 - i .19

. 32 44.884 45.360 “ 1.06

.23 58.970 59.402 - 0.73

.23 63.513 63.981 - 0.74

• 13 77.509 77.810 - 0.39

.10 91.963 92.232 - 0.29

.03 101.638 101.736 - 0.10

.02 126.173 126.246 - 0.06

.01 147.882 147. 859 0 . 02

.01 181.824 181.799 0.0 1 .00 218.350 218.371 - 0.0 1 .01 249.578 249.653 - 0.03

. 05 298.027 298. 372 - 0.12

.07 324.594 325.124 - 0. 16

• 08 346.584 347.284 - 0.20

.10 364.997 365.878 - 0 . 2 * .17 33.044 33.416 - 1.13

.17 35.849 36.237 - 1.08

.17 40.651 41.064 - 1.02

.16 54.773 55.227 - 0 . ®3

.18 80.090 80.733 - 0.60

.14 104.601 105.209 - 0.58

.11 122.244 122.740 - 0.41

.08 157 . 42b 157.856 - 0.27

.07 192.276 192.756 - 0.25

0 , -0

-Q

-0

“0

”0

-0

”0

-0

-0

“0-o

0

0

00 “Q

-0

-0

-0

-Q

"0

-0

-0

-0

“0-o

-0

-0

0

0

0

0

0

0

0

0 “0

-0

00

0

0

0

00

0

e

o

o . 0

0

- 0 , 0

s ?
METHANE EQUATION OF STATE

10 T*K HOL/L CALGB D, PCI P » BAR GALGD P,PCT

i 225*622 17.5235 17.5074 0,09 225.974 226.639 “0.29

3 233.079 17.516® 17.49S® 0.10 259.963 260.790 -0.32

3 240,996 17.5092 17,487® 0.12 293.223 294.297 "0.37

1 250.735 17.5005 17.4747 0.15 333.924 335.357 "0.43

3 25®. §46 17,4936 17.4604 0.19 366.59® 36®. 580 "0*54

3 2S6.7S® 17.466® 17.4494 0.21 400.092 402.489 "0.60

3 27%. 383 17.4799 17.4392 0.23 431.136 433,901 -8.64

3 162.33% 18.468© 18.4293 0.32 65.518 66.974 -2.22

3 162,63% 18.4688 18.4282 0.33 65.491 66.974 -2.26

3 175.629 18.4956 18.4331 0.34 31.3 76 32.556 -3.76

3 176,061 i@e 4931 18.4311 0.34 42.935 44. 226 -3.01

3 166,292 18,483® 18.4287 0.30 91.646 93.222 -1.72

3 198.532 1 @® 4®7i 18.4281 0.32 102.401 104. 183 -1.74

3 193.639 18,4788 18.4274 0.28 117.303 116.966 -1.42

3 198.667 18.473® 18,425® 0.26 141.558 143.283 -1.22

3 203,156 18.4695 18.4217 0.25 163.181 164.966 -1.09

3 206*21% 16.4651 18.4234 0.24 187.511 189.407 -1.01

3 212, %2% IS. 4607 18.4162 0.24 207,694 209.701 -0.97

3 216.75® 18.4551 18.4107 0.24 238.049 240.234 -0.92

3 223, 7%2 18,4501 18,4060 0.24 261.867 264.179 -0.83

3 229.135 18. 4452 18.3991 0.25 287.485 290. 057 -0.89

3 233.395 18.4414 18.3940 0.26 307.683 310.455 -0.90

3 237.607 18.4377 18.3888 0.27 327.596 330.581 -0.91

3 243.055 18.4321 18.3817 0.27 353.252 356.490 -0.92

3 246.039 18.4277 18.3745 0.29 376.587 380.163 -0.95

3 253.126 18,4227 18.3677 0.30 400.346 404.213 -0.97

3 263.263 18.4134 18.3542 0. 32 447.525 452.030 -1.01

3 272.927 18.4047 18.3400 0.35 491.840 497.120 -1.07

3 172.566 19, 9962 19.9196 0.38 55.009 57.865 -5.19

3 178.460 19.9899 19.9112 0.39 90.082 93.425 -3.71

3 136.650 19.9612 19.9039 0.39 139.761 143.593 -2.74

3 190.532 19.9838 19.9006 0.42 161.544 165.926 -2.71

3 196.069 19.9719 19.8952 0.38 194.310 198.683 -2.25

3 204.161 19.9631 19.8872 0.38 241 .785 246.590 -1.99

3 211.525 19.9557 19.8801 0.38 284.629 289.837 -1.83

3 219.063 19.9476 19.8715 0.38 328.253 333.915 -1.72

3 227.105 19.9395 19.8636 0.40 374.341 380.662 -1.69

3 235.300 19.9314 19.8532 0.41 421.001 427.972 -1.66

3 244.17% 19.9220 19.8365 0.43 470.891 478.751 -1.67

3 253.626 19.9120 19.8236 0.44 524.859 533.539 -1.65

3 259.343 19.9064 19.8164 0.45 555.441 564.625 -1.65

3 267.733 19.8977 19.7396 0.49 601.053 611.585 -1.75

3 274.489 19. 8909 19.7922 0.50 638. 125 649. 145 -1.73

3 172.766 21.2132 21.1234 0.44 113.831 119.516 -4.99

3 176.889 21.208® 21.1149 0.44 142.805 148.924 -4. 28

3 161.669 21. 203

2

21.11 34 0.44 176.336 182.788 -3. 66

3 189.783 21.1939 21.0930 0.45 232.523 239.806 -3. 13

3 190.532 2 1.2000 21.0332 0.48 237.772 245.586 -3.29

3 197.315 21.1858 21.0913 0.45 284.387 292.251 -2.77

3 204.169 21.1783 21.0853 0.44 331.269 339.541 -2.50

3 212.644 21.1689 21.0763 0.44 388.576 397.459 -2.29

3 228.430 21. 1509 21.0560 0.45 493.464 503.735 -2.08

3 235.77© 21. 1426 21.0460 0.46 541 .550 552.567 -2.03

3 247.380 21. 1303 21.0294 0.48 616.528 628.871 -2.00

3 252.992 21.1241 21.0205 0.49 652.311 665.402 -2.01

3 168.753 22.4109 22.3149 0.43 169.422 177. 799 -4.94

3 ISO. 116 22. 3972 22.3038 0.42 262.685 271.877 -3.50

3 138.528 22.3872 22.29-*6 0.41 330.450 340.295 -2.98

3 190.532 22.3918 22.2923 U.44 346.440 357. 215 -3. 11

3 196.791 22.3772 22.2831 0.40 396.392 406.540 -2.56

3 204.366 22.3679 22.2803 0.39 455.919 466.487 -2.32

3 211.255 22.3598 22.2725 0.39 509.403 520.447 -2.17

3 218.293 22.3517 22.2047 0.39 563. 516 575.038 -2.04

3 226.285 22.3417 22.2541 0.39 624.075 636.262 -1.95

3 234.420 22.3324 22.2433 0.40 685.032 698.015 -1.90

NP * 27 6 » ONRMSPCT = 3.971, P1EANPCT = 0.626

58
METHANE EQUATION OF STATE

10 T,K MOL/t CAL CD 0 » PCI P » BAR CALCD Pf PCT

A 114.524 26.1378 26.1262 0.04 0.945 10 . 84 © - 21.28

4 114.524 26. 3609 26.3509 0.04 47.517 49.285 - 3.72

4 114.524 26.5104 26 . 5040 0.02 75.421 76.465 - 1 . 38

4 114.524 26.6581 26.6549 0.01 103.824 104.451 - 0.60

4 114.524 26.6046 26 . 30*2 0.00 133.256 133.335 - 0.06

4 114.524 26® 9535 26.9515 0.01 163*436 163.841 - 0.25

4 11*. 524 27. 1032 27.1075 - 0.02 196.656 195.721 0.48

4 114.524 27.2643 27.2692 - 0.02 232.450 231.342 0.43

4 114.524 27.4311 27.4391 - 0.03 271.554 269.669 0.69

4 114.524 27.6091 27.6123 - 0.01 312.987 312.186 0 . 26

4 119 . 42 ® 25.6812 25 .6650 0.06 0.328 10.640 - 27. 76

4 119.420 25. 8345 25.8091 0.10 30.274 34.267 - 13.19

4 119.420 26.0308 26.0065 0.09 62.146 66.202 - 6.53

4 119.420 26.2681 26.2495 0.07 104.007 107. 328 - 3 . 19

4 119.420 26.5034 26.4939 0.04 149.093 150.912 - 1.22

4 119.420 26.7480 26.7439 0.02 198.372 199.213 - 0.42

4 119.420 27. 0051 27.0070 - 0.01 253 . 74 ® 253.336 0.16

4 119.420 27.2546 27.2303 - 0.12 316.910 309.143 2.45

4 124.917 25. 2010 25 . 14*2 0.23 9.796 17.426 - 77.89

4 124.917 25.4421 25.3976 0.17 44.960 51.433 - 14.40

4 124.917 25.6911 25.6563 0.13 84.186 89.350 - 6.13

4 124.917 25.9383 25 . 91)6 0.11 125.190 129.872 - 3.74

4 124.917 26.1725 20.1637 0.05 168.829 170.976 - 1 . 27

4 124.917 26. *264 26.4233 0.01 217.985 218.572 - 0.27

4 12*. 917 26.6966 26.7007 - 0.02 273.636 272. 787 0.31

4 130.987 24.5924 24.5737 0.08 15.025 17.214 - 14.57

4 130.987 24.8361 2*. 8290 0.03 46.246 47.150 - 1,95

4 130.987 25. 1307 25.0702 0,21 79.344 06.654 - 9.21

4 130.987 25. 3524 25. 3279 0.18 115.200 118.863 - 3 . 18

4 130.987 25.5826 25.6019 - 0.08 157.736 154.633 1.97

4 130.987 25.8251 25.8506 - 0.13 200.714 194. 930 2.68

4 130.987 26. 0879 20.1298 - 0.16 249.306 2 * 1.722 3.04

4 130.987 26. 3657 26.4062 - 0.15 302.874 294. 827 2.66

4 134.328 24. 1949 24.1473 0.20 6.891 11.923 - 73 . 02

4 13*. 328 24.3807 2*. 33 40 0.19 27.123 32.403 - 19.47

4 134.328 24.6433 2* .5962 0.19 57.831 63.641 - 10.05

4 134 . 32 ® 24. 9029 2*. 0583 0.18 91.296 97 . 26b - 6.54

4 134.328 25. 1534 25.1219 0.13 127.826 132. 397 - 3.56

4 134.328 25.4059 25.3704 0.11 166.255 170.539 - 2 . 58

4 13 *. 32 ® 25.6634 25 . 6*60 0.07 209.466 212 . 38 ® - 1.39

4 134.328 25.9323 25.9231 0.04 257.678 259.330 - 0.64

4 134.328 26.2171 2o . 2 0 * 3 0.05 310.290 312.791 - 0.81

4 139.061 23.7344 23.6011 0.22 12.524 17.506 - 40.42

4 139.061 23 . 995 ® 23 . 9*18 0.22 38.254 43.881 - 14.71

4 139.061 24 . 261

24.2118 0.21 67.490 73 . 206 - 0.47

4 139.061 24.5236 2* .4760 0.19 98.761 104.689 - 6 . 0 0 4 139.061 24.7801 2 * « 7366 0 . 1 ® 132,300 136.154 -*.4 3 4 139.061 25. 0332 25. 0038 0.13 169.001 173. 822 - 2.85

4 139.061 25.2934 25.2730 0.09 209.662 213, 327 - 1.75

4 139.361 25.5571 25.5488 0.03 254.969 256.388 - 0.56

4 139.061 2 9 ® 0469 25.0397 0 ® 0 3 306.000 307.237 - 0.40

4 1 * 5.556 22 . 984 ® 22.9253 0.26 12.996 17.661 - 35.90

5 9
HETHANE EQUATION OF STATE

10 T pK HQL/L CALCD D,PCT P 9 BAR CALCO P» PC T 4 145.556 23. 2623 23.1979 0.28 35.276 40.885 -15.90

4 145.556 23.5355 23.4750 0.26 60.366 66.181 -9.63

k 145.556 23.6146 23.7458 0.29 87.361 94.632 -8.32

4 145.556 24. 0336 24.0188 0.27 117.186 124.655 -6.37

4 145.556 24.3522 24.2671 0.27 149.131 157.295 -5.47

4 145. 5i6 24.6202 24.5569 0.26 184.018 192.616 -4.67

4 145.556 24.8961 2*. 8323 0.26 222.583 231.956 -4.21

4 145.556 25.1794 25.1130 0.24 265.891 275.643 -3.67

4 145.556 25.4706 25.4150 0.22 314.581 324. 117 -3. 03

4 150.750 22.6157 22.5234 0.39 31.021 37.422 -20.63

4 150.75® 22.8932 22.8029 0.39 51.885 59.239 -14.17

4 150.75® 23. 1664 23.0737 0.33 75.115 82.993 -10.49

4 150.75® 23.4373 23.3511 0.37 100.392 108.897 -8.47

4 150.750 23.6995 23.6232 0.32 128.071 136.284 -6.41

4 150.750 23.9630 23.3831 0.31 157.454 166.210 -5.56

4 150.75® 24.2248 24.1533 0.27 190.000 198.424 -4.43

4 150.75® 24.4972 24.4350 0.25 226. 137 234.670 -3.77

4 150.750 24.7733 2*. 7136 0.22 266.405 274. 367 -2.99

4 150.75® 25.0576 25.0038 0.21 309.862 318. 466 -2.78

4 153.236 21.5316 21.3950 0.64 22.895 30.151 -31.69

4 158.233 21.8341 21.6931 0.62 39.627 47.768 -20.55

4 159.233 22.1371 22.0032 0.58 58.951 67.730 -14.89

4 156.236 22.4371 22.3107 0.56 60.251 89.692 -12.01

4 153.236 22. 7293 22.6111 0.52 103.696 113.907 -9.63

4 156.236 23.0171 22.9029 0.50 129.358 140.019 -8.24

4 156.236 23.3006 23.1958 0.45 157.625 168.279 -6. 7b

4 156.236 23.5636 23.49-46 0.38 189.060 199.076 -5.29

4 156.233 23.8720 23.7933 0.33 223.624 233.244 -4.30

4 153.236 24.1692 2-4.0953 0.31 261.723 271.556 -3.76

4 156.236 24.4706 24.4071 0.26 304.591 313.800 -3.02

4 165.616 20.4637 20.3847 0.39 30.556 33.649 -10. 12

4 165.616 20.7641 20.6630 0.46 42.201 46.506 -10.21

4 165.616 21.0624 20.9630 0.45 56.269 61.084 -8.56

4 165.616 21. 3570 21.2541 0.46 71.461 77.373 -8.27

4 165.616 21.6506 21.5237 0.56 87.639 95.592 -8. 83

4 165.616 21.9356 21.8039 0.58 106.276 115.284 -8.48

4 165.616 22.2193 22.0725 0.66 125.484 136.964 -9.15

4 165.816 22. 5012 22.3333 0.72 146.706 160.681 -9.52

4 165.816 22.7790 22.6035 0.77 169. 835 186. 266 -9.68

4 165.616 23. 0595 22.3676 0.83 194.903 214.443 -10. G3

4 145.816 23.3427 23.1326 0.90 222.178 245.385 -10. 45

4 165.616 23.6300 23.4040 0.96 252.431 279.481 -10.72

4 165.816 2 3 • 91h3 23.7052 0.87 288.859 315.989 -9. 39

4 171.020 19.4606 19.4322 0.15 30.512 31.299 -2.58

4 171.020 19. 7576 19.7375 0.10 39.620 40.274 -1.65

4 171.020 20. 0678 2U.0337 0.17 49.881 51.157 -2.56

4 171.020 20.3741 20.3346 0.19 61.656 63.549 -2.74

4 171.020 20.6778 20.6314 0.22 75.316 77.579 -3.00

4 171.020 20. 9602 20.9216 0.28 90.173 93. 386 -3.56

4 171.020 21.2743 21.2031 0.33 106.293 110.649 -4. 1 0 4 171.020 21. 5629 21.4829 0.37 124. 080 129. 50C -4. 37

4 171.020 21.8484 21.7539 0.45 142.859 150.132 -5. 09

4 171.020 22.1273 22.0216 0.48 163.662 172.301 -5.28

60
METHANE EQUATION OF STATE

ID T,K MOL/L CAL CD D, PGT P , BAR CALCD P , PC T 4 171.020 22.4120 22.2913 0.54 106.301 197.078 -5.78

4 171.020 22.6901 22.5597 0.57 210.832 223.499 -6.0 1 4 171.020 22.9769 22.8351 0.62 230. 166 253.135 -6.28

4 171.020 23.2672 23.1122 0.67 260.002 285.736 -6.62

4 171.020 23.5605 23.3938 0.71 300.800 321.453 -6. 86

4 172.012 18.9036 18.8931 0.03 26.918 27.038 -0.45

4 172.812 19.2171 19.2037 0.07 34.175 34.523 -1.02

4 172.012 19.5431 19.5216 0.11 43.111 43.769 -1.53

4 172.012 19.0601 19.8411 0.14 53.641 54.607 -1. 80

4 172.012 20. 1073 20.1525 0.17 65.532 66.968 -2.19

4 172.812 20.5019 20.4593 0.21 78.943 80.944 -2.54

4 172.812 20.0125 20.7622 0.24 93.958 96.631 -2.84

4 172.812 21.1153 21.0550 0.20 110. 311 113. 852 -3.21

4 172.012 21.4142 21.3556 0.27 128.956 132.844 -3.01

4 172.012 21.7122 21.6420 0.32 148.729 153.877 -3.46

4 172.012 22.0066 21.9151 0.42 169.456 176.823 -4.35

4 172.812 22.3015 22.2030 0.44 193.398 202. 108 -4.50

4 172.012 22.5999 22.4855 0.51 219.091 230.142 -5. 04

4 172.012 22.0995 22.7721 0.56 247.494 260.914 -5.42

4 172.812 23.2035 23.0657 0.59 279.157 294.940 -5.65

4 172.012 23.5106 23.3585 0.65 313.431 332.346 -6.0 3 4 179.526 17.0514 17.7993 0.29 38.288 39.085 -2.08

4 179.526 10. 1041 18.13;>5 0.26 43.914 44.801 -2.02

4 179.526 18.5160 13.4577 0.32 50.375 51.689 -2.61

4 179.526 18.0423 18.7921 0.27 58.367 59.689 -2.26

4 179.526 19. 1674 19.1120 0.29 67.352 69. 048 -2.52

4 179.526 19.4852 19.4275 0.30 77.613 79.651 -2.63

4 179.526 19.0016 19.7362 0.33 89.123 91.759 -2. 96

4 179.526 20.1110 20.3454 0.33 102.227 105.225 -2.93

4 179.526 20.4102 20.3451 0.36 116.557 120.303 -3.21

4 179.526 20.7228 20.6332 0.41 132.223 137.067 -3.66

4 179.526 21.0225 20.9307 0.44 149-605 155. 437 -3.90

4 179.526 21.3201 21.2190 0.47 168.544 175.639 -4.21

4 179.526 21.6179 21.5079 0.51 189.445 197.925 -4.48

4 179.526 21.9164 21.7932 0.54 212.479 222.472 -4.7 0 4 179.526 22.2163 22.0872 0.58 237.559 249.486 -5.02

4 179.526 22.5175 22.3779 0.62 265.059 279.105 -5.30

4 179.526 22.8227 22.6708 0.67 295.185 311.615 -5.63

4 100.221 16.3228 16.2771 0.28 53.258 53.696 -0.83

4 180.221 16.6622 16.6343 0.17 57.034 57.363 -0.58

4 100.221 17.0016 16.9728 0.17 61.386 61.794 -0.67

4 188.221 17. 3388 17.3135 0.15 66.632 67. OfeC -0.64

4 100.221 17.6720 17.6437 0.14 72.749 73.229 -0. 66

4 100.221 10.0034 17.9718 0.10 79.651 80.383 -0.92

4 100.221 10.3300 18.2961 0.19 87.679 S8.61C -1.06

4 108.221 18.3604 13.3245 0.20 88.439 89.414 -1.10

4 108.221 18.6839 13.6366 0.25 97.425 96.895 -1.5 1 4 100.221 19. 0009 13.9571 0.23 107.955 109.504 -1.43

4 100.221 19. 3151 19.2673 0.25 119.512 121.421 -1.60

4 100.221 I9.b290 19.5536 0.40 131. 3*3 134.879 -2.69

4 100. 221 19. 9390 19.8457 G.47 145.061 149.706 -3.20

4 180.221 20.2511 20.1621 0.44 161.461 166.409 -3.06

4 100.221 20.5427 20 .4532 0.41 178,513 183. 700 -2.91

4 108.221 20.8460 20.7525 0.45 197. 208 20 3.580 -3.23

* 100.221 21.1497 21.0h74 0.40 217.789 225.383 -3.49

4 100.221 21.4551 21.3413 0.53 240.259 249.508 -3.85

4 108.221 21. 7581 21.6373 0.55 264.984 275.693 -4.04

4 100.221 22. 0546 21.9315 0.56 291.7*4 303.015 -4. 0 7

NP = 163, ONRMSPCT = 0.3o6, PiEANPCT = 6.545

61
«

METHANE EQUATION OF STATE

£0 TeK HQL/L CAICD Of PCT P t BAR CALCD P,PCT

6 273.160 0.7500 0.7531 - 0.01 16.376 16.374 0.01

6 298.142 0.7500 0.7500 - 0.00 18.020 18.019 0.00

6 303.143 0.7500 0.7500 0.00 18.347 18.347 0.00

6 323.140 0. 7560 0.7499 0.02 19.656 19.659 - 0.02

h 348.143 0.7500 0.7499 0.01 21.292 21.295 - 0.01

6 373.169 0.7500 0.7499 0.01 22.925 22.928 - 0.0 1 6 398.160 0.7500 0.7500 0.00 24.557 24.558 - o . 00

6 273.160 1.0000 1.0003 - 0.03 21.558 21.552 0 . 03

6 298.142 1.0000 1.0001 - 0.01 23.786 23.783 0.01

6 303.143 1.0000 1.0002 - 0.02 24.232 24.226 0.02

& 323.140 1.0000 1.0000 0.00 26. 006 26. 006 - 0.00

6 348.143 1.0000 1.0000 0.00 28.221 26.222 - 0.00

6 373.160 1.0600 1.6000 0.00 30.431 30.432 - 0.00

6 398.160 1.0000 1.0030 - 0.00 32.637 32.636 0.00

6 273.150 1.5000 1.5010 - 0.06 31.539 31.520 0 . 06

6 298.142 1.5000 1.5006 - 0.04 34.993 34.981 0.03

6 303.143 1.5000 1.5006 - 0.04 35.685 35.671 0.04

6 323.140 1.5000 1.5031 - 0.01 38.427 36.424 0 . 01

6 348.143 1.5000 1.5001 - 0.00 41.852 41.851 0.00

6 373.150 1.5000 1.5001 - 0.01 45.267 45.264 0.01

6 398.160 1.5000 1.5003 - 0.02 48.676 48.665 0 . C 2 6 273.150 2 . 0000 2.0017 - 0.09 41.053 41.021 0 . 06

6 298.142 2.0000 2.0008 - 0.04 45.804 45.787 0.04

6 303.143 2.0000 2.0008 - 0.04 46.753 46.736 0.04

6 323.140 2. 0000 2.0034 - 0.02 50.530 50.521 0.02

6 348. 143 2.0000 1.9998 0.01 55.222 55.226 - 0.01

& 373.150 2. 0000 2.0003 - 0.02 59.920 59.911 0.0 1 6 398.160 2.0000 2.0003 - 0.01 64.562 64.573 0.0 1 6 273.150 2.5000 2.5018 - 0.07 50.139 50.106 0.06

6 298.142 2. 5000 2.5035 - 0.02 56.263 56.252 0.02

6 303.143 2.5000 2.5035 - 0.02 57.485 57.476 0.02

6 323.140 2.5000 2.4997 0.01 62.343 62.349 - 0 . 0 1 6 348.143 2.5000 2.4994 0.02 68.390 68.406 - 0 . 02

6 373.150 2.5000 2.4999 0.00 74.424 74.427 - 0.00

6 398.160 2.5000 2.4999 0.01 80.411 80.415 - 0.0 1 6 273.150 3.0000 3.0010 - 0.03 58.642 58.825 0.0 3 6 298.142 3.0000 2.9997 0.01 66. 415 66.421 - 0 . 0 1 & 303.143 3. 0000 3.0304 - 0.01 67.940 67.932 0.0 1 6 323.140 3.0000 2 ,9939 0.04 73.926 73.952 - 0.04

6 348.143 3.0000 2.9936 0.05 81.391 81.429 - 0.05

6 373.150 3. 0000 2.9992 0.03 88.835 66. 856 - 0.02

6 398.160 3.0000 2.9997 0.01 96.229 96.239 - 0 . C 1 6 273.150 3.5000 3.5007 - 0.02 67.222 67 . 21 C 0.02

6 298.14

2

3.5000 3.4938 0.03 76.307 76.331 - 0 . 03. 6 303.143 3.5000 3.5330 - 0.00 78.146 78.146 0.0 0 6 323.140 3.5000 3.4930 0.06 85.324 85.370 - 0.05

6 348.143 3.5000 3.4977 0.07 94.279 94.338 - 0.06

6 373.150 3.5000 3.4936 0.04 103.203 103.243 - 0 . 0 *. 6 398.160 3 . 5000 3.4995 0.01 112.073 112. 086 - 0.0 1 6 273.150 4.0000 4.0333 - 0.01 75.307 75.303 0.0 1 6 298.142 4.0000 3.9934 0 . 04 85.992 86.023 - 0.0 4 6 303.143 4.0000 3.9993 0.02 88.142 88. 155 - o . 0 1

62
METHANE EQUATION OF STATE

10 T*K H10L/L GALCO Q,PCT Ps,®AR GAIGD P » PC T 6 323.140 4 . 0000 3.9974 0.06 96.585 96.642 - 0.06

6 346.143 4.0006 3.9960 0 » 08 107.094 107.176 - 0.08

6 373.150 4 . 0000 3.9991 0*05 117.577 117.630 - 0 . 05

6 398.163 4.0600 3.9994 0.01 127.993 128.011 - 0.0 1 6 27

. 15 ® 4.5000 *.5086 “ 0.01 83.156 83.147 0.0 1 6 298.142 4.5000 4.4985 0.03 95.511 95.539 “ 0 . O 3 6 333.143 4.5000 4.4999 0.80 98.002 98.004 - 0 . 00

6 323.149 4.5000 4.4984 0.04 107.779 107.815 - 0.03

6 348.143 4.5000 *.4973 0.06 119.920 119.990 - 0.06

6 373.150 4 . 506 ® *.4988 0.04 132.013 132.070 - 0.04

6 398.163 4.5000 *.5007 - 0 . Q 2 144.083 144.060 0 . 02

6 273.153 5® 0000 5.8018 - 0.02 90.802 90.786 0.02

& 298.142 5.0000 *.9991 0.02 104.911 104.926 - 0.02

6 303 • 143 5.0000 5.0032 - 0.00 107.745 107.742 0.00

6 323. 140 5 . 000 ® *. 998 ® 0.02 118.912 118.940 - 0.02

6 348.143 5*0000 4.9980 0.04 132.781 132.834 - 0 , 04

6 373.150 5.0000 4.9988 0.02 146.983 146.610 - 0.02

6 3 98 . 160 5 ® 400 0 5.0015 - 0.03 160.346 160.296 0.63

6 273.150 5.5000 5.5029 - 0.05 98.315 98.272 0.04

6 298.142 5 . 508 ® 5.5010 -0 e 02 114.261 114.243 0,02

6 333 . 143 5 . 500 ® 5. 5815 - 0. 03 117.449 117.421 0.02

6 323 . 14 ® 5.5000 5.4982 0.03 130. 030 130.071 — 0.03

& 348.143 5.5000 5.4992 0.01 145.748 145.767 - 0.0 1 6 373.150 5.5000 5.4994 0.01 161. 321 161.338 - 0 . 0 1 6 398.160 5.5000 5.5031 - 0.06 176.887 176.785 0.06

6 273 . 15® 6. 0000 6.0017 - 0.03 109.680 105,655 0.0 2 6 29®. 142 6. 0000 6.0029 - 0.04 123.585 123.538 0.04

6 303.143 6.0000 6.0032 - 0.05 127.160 127.097 0.05

& 323 » 14® 6.0080 5.9997 0.01 141 .261 141.268 - 0.01

6 348.143 6, 8000 6.0016 - 0.03 158.896 158. 854 0.0 3 & 373 . 15 ® 6 * 0000 6.0033 - 0.01 176. 308 176.298 0.0 1 6 398 . 16® 6.0000 6.0030 - 0*05 193.701 193.600 0.05

6 273 . 15 ® 6.5800 6.5049 - 0,08 113.057 112. 986 0.06

6 298.142 6.5000 6 . 503 ® - 0.06 132.941 132. 870 0.05

6 303.143 6.5000 o . 50*6 - 0.07 136.921 136 , 82 ® 0.07

& 323.148 6.5000 5.5043 - 0.07 152.692 152.593 0,06

& 348 • 143 6.5000 o . 50 13 - 0.02 172.195 172. 160 0.0 2 6 373. 156 6 « 50 0 0 6.5035 - 0.01 191.585 191.570 0.01

6 393.166 6.5000 6.5057 - 0.09 211.015 210.818 0.09

6 273.150 7.0000 7.0121 = 0.17 120.494 120.316 0.15

b 298.142 7.0000 7.0052 - 0,09 142.411 142. 294 a . oa

& 303.143 7. 0800 7 .

0 ©9 - O.iO 146.809 146.671 0.09

6 323.140 7.0000 7 . 00*4 — 0,06 1 64 .208 164.107 0.06

6 348 . 1*3 7.0000 7 . 00*1 — 0 * 0 6 185.865 185.753 0 . 06

6 373 . 15 ® 7.0000 7.0039 — 0.06 207. 347 207.225 0. 06

& 398 . 16 ® 7 .

0 0 0 7.0053 — 0 . 0 ® 228.706 228.516 0.08

6 273.158 7 . 5000 7.5137 - 0.14 127.854 127.695 0.12

6 298.142 7. 5080 7.5089 - 0.12 152.040 151.868 0.11

6 303. 143 7.5800 7 . 50*9 - 0.06 156.783 156.685 0 • 0 6

6 323.140 7.5000 7.5038 - 0,09 175 . 9 b 6 175.875 0.05

6 348.143 7.5000 7.5037 - 0.05 199.607 199.703 0 . 05

& 373 . 15 ® 7.5088 7.5030 - 0.04 223.440 223. 342 0.04

6 398.160 7.5000 7.5074 - 0,10 247.053 246.778 0.11

S 3
METHANE EQUATION OF STATE

I© T,K MOL/L CALCO 0»PCT P , BAR CALCO P,PCT

6 273,150 8.8000 8.0151 -0.19 135.410 135.162 0.17

6 290.142 ©•@000 8.0108 -0.14 161.873 161.658 0.13

6 303.143 6.0300 8.0095 -0.12 167.135 166.936 0*12

§ 323.140 8.0000 8.0071 “0.09 188.14? 187.968 0. 09

6 348.143 8. 0900 8.0044 -0.05 214.218 214. 091 0.06

6 373.15® 8.0000 8.0022 -0.03 240.076 240.005 0.03

6 398.160 3. 0009 8.0095 -0.11 266. 023 265.694 0.12

6 273.150 8.5000 8.5156 -0.18 143.090 142.847 0.17

6 298.142 8. 5000 3.5114 -0.13 171.979 171. 745 0.14

6 303. 143 8.5000 9.5106 -0.12 177.736 177.508 0. 13

6 323.140 8.5000 8.5076 -0.09 200.673 200.478 0.10

6 348.143 8.5000 9.5059 -0.07 229.193 229.013 0.08

6 373.150 8.5000 8.5030 -0.04 257.427 257.320 0.04

6 398.160 8.5006 3.5095 -0.11 285.758 285.37b 0.13

6 273.150 9. 0000 9.0190 -0.21 151.095 150.787 0.20

6 298.142 9.0000 9.0111 -0.12 182.470 182.232 0.13

6 303.143 9. 0000 9.0101 -0.11 188.733 188.506 0.12

6 323.140 9. 0000 9.0091 -0.10 213.759 213.516 0.11

6 348.143 9. 0000 9.0056 -0.06 244.766 244.589 0.07

6 373.150 9.3000 9.0006 -0.01 275.434 275.413 0.01

6 398.168 9.0000 9.0059 -0.07 306.209 305.959 0.08

6 273.150 9.5000 9.5127 -0.13 159.307 159.092 0.14

6 298.142 9.5000 9.5039 -0.09 193.423 193.223 0.10

6 303.143 9.5000 9r5034 -0.04 200.116 200. 035 0. 04

6 323.140 9.5000 9.5062 -0.06 227.366 227.193 0.08

6 348.143 9.5000 3.5025 -0.03 261.024 260.939 0.03

6 373.150 9.5000 9.5017 -0.02 294.478 294.413 0.02

6 398.160 9. 5000 9.5065 -0.07 327.865 327.577 0. 09

6 273.150 10.0000 10.0086 -0.09 167.979 167.825 0.09

6 298.142 10.0000 10.0015 -0.01 204.825 204. 790 0.02

6 303.143 10.0000 3.9972 0.03 212.100 212.169 -0.03

6 323.140 10. 0000 9.9930 0.02 241.534 241.593 -0.02

6 348.143 10. 0000 9.9970 0.03 278. 048 278.155 -0.04

b 373.150 10.0000 9.9959 0.04 314.250 314. 417 -0.05

6 398.160 10.0000 10.0034 -0.03 350.494 350. 336 0. 05

b 273.150 10.5000 10.4931 0.02 177.002 177.037 -0.02

6 298.142 10.5000 10.4978 C.02 216.938 216. 992 -0.03

6 303.143 10.5000 10.4937 0.06 224.805 224. 97C -0.07

6 323.140 10.5000 10.4932 0.06 256. 572 256.783 -0. 08

6 348.143 10.5000 10.4920 0.08 296.014 296.313 -0.10

b 373.150 10.5000 10.4905 0.09 335.101 335.512 -0.12

b 398.160 10. 5000 10.4335 0.01 374.301 374.326 -0.0 1 b 273.150 11.0000 11.0001 -0.00 186.780 186.779 0. 00

6 298.142 11.0000 10.9922 0.07 229.688 229.893 -0.09

b 303.143 11.0000 10.9924 0.07 238.292 238.503 -0.09

b 323.140 11.0000 10.9910 0.08 272.539 272.836 -0.11

b 348.143 11. 0000 10.9882 0.11 315.031 315.494 -0.15

b 373.150 11. 0000 10.9394 0.10 357.297 357.785 -0. 14

b 398.160 11.0000 10.9976 0.02 399.523 399.648 -0.0 3 b 273.150 11.5000 11.4967 0.03 197.051 197.122 -0. 04

b 298. 142 11. 5000 11.4956 0.04 243.451 243.575 -0.05

b 303.143 11.5000 11.4334 G.10 252.507 252.851 -0.14

b 323.140 11.5000 11.4914 0.07 289.542 289.844 -0.10

b 348.143 11.5000 11.4834 0.14 335.104 335.798 -0.21

b 373.150 11.5000 11. *902 0.09 380.866 381.343 -0. 13

b 273.150 12.0000 12.0014 -0.01 208.211 208.179 0.02

6 298.142 12. 0000 11.9931 0* 06 257.950 258.160 -0.08

b 303.143 12. 0000 11.9918 0.07 267.883 268.141 -0.10

b 323.140 12.0000 11.98 37 0.09 307.555 307.940 -0.1 3 b 348.143 12.0000 11.9839 0.13 356.651 357. 369 -0. 20

b 373.150 12,0000 11.9921 0.0 7 405.932 406. 34C -0.10

b 273.150 12.5000 12.5072 -0.06 220.275 220.097 0.08

b 298.142 12.5000 12.43 33 0.01 273.788 273. 81C -0.01

b 303.143 12. 5000 12.4917 0.07 284.252 284.536 -0.10

b 323.140 12.5000 12.4920 0.06 326.974 327.296 -0.10

b 348.143 12.5000 12.4917 G . 0 7 379.993 380. 387 -0.10

NP « 171, DNRMSPCT = 0.065, P iEANPCT = 0.054

64
METHANE EQUATION OF STATE

10 T,K HOL/L CALCO 0,PCT P BAR CALCD P,PCT

8 203.084 0. 0604 3.0604 »0.04 1.013 1.013 0.04

8 223.249 0.0549 3.0548 0.06 1.013 1.014 -0.06

8 248.175 0. 0493 3.0493 0.02 1.013 1.013 -0.02

8 273.150 0.0447 3.0*47 -0.01 1.013 1.013 0.01

8 298.142 0.0409 3.0409 -0.01 1.013 1.013 0.01

8 323.140 0.0378 0.0378 -0.02 1.013 1.013 0.02

8 373.150 0.0327 3.0327 -0.02 1.013 1.013 0.02

8 423.170 0.0288 0.0288 -0.01 1.013 1. 013 0. 01

8 473.193 0.0258 3.0258 -0.00 1.013 1.013 0.00

8 203.034 1. 3818 1.3870 -0.38 20.265 20.200 0.32

8 223.249 1.2084 1.2092 -0.07 20.265 20.252 0.06

8 298.142 0.8479 0 .8*68 0.13 20.265 20.290 -0.12

8 203.084 2.2701 2.2896 -0.86 30.397 30.201 0.65

8 223.249 1.9191 1.9265 -0.38 30.397 30.300 0.32

8 248.175 1.6396 1 .6411 -0.09 30.397 30.372 0.08

8 273.150 1.4422 1.4425 -0.02 30.397 30.392 0.02

8 323.140 1.1757 1.1752 0.04 30.397 30.409 -0.04

8 373.150 1. 0004 3.9989 0.16 30 . 397 30.444 -0.15

8 423.170 0.8729 0.8717 0.14 30.397 30. 441 -0.14

8 473.193 0.7750 0.77*7 0.04 30. 397 30.409 -0. 04

8 203.084 3.4113 3.4516 -1.18 40.530 40.227 0.75

8 223.249 2.7324 2.7470 -0.53 40.530 40.362 0.41

8 248.175 2.2722 2.2767 -0.20 40.530 40.460 0.17

8 273.150 1.9734 1.9736 -0.01 40.530 40.526 0.0 1 8 298.142 1.7541 1.75*7 -0.03 40.530 40.519 0.03

8 323.140 1.5853 1.5862 -0.05 40.530 40.509 0.05

8 203.084 5. 0533 5.15*4 -2.00 50.662 50.187 0.94

8 223.249 3.6845 3.7050 -0.56 50.662 5 0. 46 2 0.40

8 273.150 2.5315 2.5312 0.01 50.662 50.668 -0.0 1 8 373.150 1.6853 1.68 37 0.10 50.662 50.712 -0.10

8 423.170 1.4597 1.4595 0.01 50.662 50.668 -0.0 1 8 473.193 1.2919 1.2923 -0.04 50.662 50.645 0.04

8 203.084 7.9718 3.3932 -5.25 60.795 59.864 1.53

8 223.249 4.8339 4.8515 -0.36 60.795 60.654 0.23

8 248.175 3.7047 3.7135 -0.24 60.795 60.681 0.19

8 273.150 3. 1161 3.1158 0.01 60.795 60.801 -o. 01

8 298.142 2.7184 2.7217 -0.12 60.795 60.728 0.11

8 323.140 2.4350 2. *337 0.05 60.795 60.824 -0.05

8 423.170 1.7532 1.7546 -0.08 60.795 60.748 0.08

8 473.193 1.5505 1.5509 -0.02 60.795 60 .78C 0.0 2 8 203.084 9.982b 13.6716 -6.90 65.861 64.246 2.45

8 203.084 11.8896 12. *3*5 -*.58 70. 927 69.119 2.55

8 223.249 6. 1880 6.2332 -0.83 70.927 70.585 0.48

8 203. 084 13.9975 14.30*4 -2.19 81.060 78.810 2.78

8 223.249 7.7710 7.8712 -1.29 81.060 80. *70 0.73

8 2*8 . 175 5.3793 5.4037 -0.45 81.060 80. 787 0. 3*

8 273.150 4. 3636 4.3656 -0.04 81 . ObO 81. 03C 3.04

8 298.142 3.7389 3.7427 -0.10 81.060 80.987 0.09

8 323.140 3.3109 3.3134 0.01 61.060 81.071 -0. C 1 8 223.249 9. 4350 9.5737 -1.44 91.192 90.345 0.93

8 203.084 15.9266 16.0629 -0.86 101. 325 99. 184 2. 1 1 8 223.249 10.9398 11.0632 — 1 e 1 3 101. 325 100.422 3.89

i 65
METHANE EQUATION OF STATE

10 T*K M0L/L , GAICO 0» PCT P s> BAR CALCD P » PC T

a 248* 175 7.2518 7.3035 -0.71 101.325 100.788 0.53

8 273.150 5.6949 5.7061 -0.20 101.325 101.159 0.16

a 298 ® 142 4.7990 4.8075 -0.18 101.325 101.166 0.16

8 323.140 4. 2048 4.2091 -0.10 101.325 101.227 0.10

a 203.084 16.9023 17.0852 -1.08 121.590 117.368 3.47

a 223.249 13.1053 13.2862 -1.38 121.590 119.528 1.70

6 248.175 9.1316 9.2105 -0.86 121.590 120.705 0.73

§ 273.15® 7. 0576 7.0857 -0.41 121.590 121.163 0.35

a 2 98.142 5. @806 5.8953 -0.25 121.590 121.317 0.22

8 323.14® 5. 1121 5.1192 -0.14 121.590 121.431 0.13

8 203.084 17.6717 17.8222 -0.85 141.855 137.264 3.24

8 223.249 14. 5471 14.7005 -1.05 141.855 139.237 1.85

8 248.175 10.7931 10.8655 -0.67 141.855 140.890 0.68

a 273.150 8.3962 8.4361 -0.48 141.855 141.237 0. 44

8 298.142 6.9544 6.9769 -0.32 141.855 141.429 0.30

6 323.140 6. 0156 6.0261 -0.17 141.855 141.620 0.17

8 203.084 18.2772 18.4052 -0.70 162.120 157.312 2.97

8 223.249 15.5521 15.6979 -0.94 162.120 158.769 2.07

8 248.171 12.1465 12.2425 -0.79 162.120 160.563 0. 96

8 273.150 9.6370 9.6763 -0.41 162. 120 161.441 0.42

8 298.142 7.9959 8.0233 -0.34 162.120 161.576 0.34

8 323.140 6. 9022 6 • 91<* 4 -0.18 162.120 161.837 0.17

8 203.084 18.7732 18.8913 -0.63 182.385 177.157 2. 87

8 223.249 16.3484 16.4655 -0.72 182.385 178.985 1.86

8 248.175 13.2422 13 , 3?54 -0.85 182.385 180.111 1.25

6 273.150 10.7591 10.7780 -0.18 182.385 182.015 0.20

8 298.142 8.9743 3.0071 -0.37 182.385 181. 682 0.39

8 323.140 7.7605 7.7711 -0.14 182.385 182.129 0.14

8 373.150 6. 1946 5.2006 -0.10 182.385 182.202 0.10

8 203.084 19.2104 19.3104 -0.52 202.650 197.568 2.51

S 223.249 16.9755 17.0903 -0.68 202.650 198.642 1.98

8 248.175 14.1547 14.2564 -0.72 202.650 200.152 1.23

8 273.150 11.7211 11.7544 -0.28 202.650 201.915 0.36

8 298.142 9.8655 9.9095 -0.24 202.650 202. 087 0.28

8 323. 140 8.5699 8.5849 -0.17 202.650 202.266 0.19

8 373.150 6. 8403 5.8553 -0.22 202.650 202.178 0.23

3 423 . 170 5.7691 5.7841 -0.26 202.650 202.089 0.28

3 473.193 5.0363 5 • 0* 54 -0.18 202.650 202. 259 0.19

e 203.064 20.0835 20.1569 -0.42 253.313 247.781 2.18

3 223.249 16.2033 18.2847 -0.45 253.313 249.288 1.59

8 246.175 15.6229 15.9211 -0.62 253.313 249. 731 1.41

8 273.150 13.6614 13.7025 -0.30 253.313 252. 050 0.50

8 298.142 11. 8075 11.8376 -0.25 253.313 252.426 0.35

8 323.140 10. 3754 10 .3382 -0.12 253.313 252.918 0.16

8 373.150 8.3661 8.3861 -0.24 253.313 252.613 0.28

8 473.193 6. 1747 6.1908 -0.26 253.313 252. 574 0.29

a 203.084 20.7751 20.8501 -0.36 303. 975 297.925 1.99

8 223.249 19.0983 19.1771 -0.41 303.975 298.989 1.64

8 248.175 17.0283 17.1046 -0.45 303.975 300.250 1.23

8 273.150 15.0966 15.1254 -0 .18 303.975 302.837 0.37

8 296.142 13. 3339 13. 3652 -0.24 303.975 302. 773 0.40

8 323.140 11.6678 11.89 32 -0.05 303.975 303.776 0.07

8 373.150 9.7327 9.7423 -0.10 303.975 303.594 0.13

66
methane equation of state

10 T,K MOL /l calqd 0, PCT P , BAR CALCD P, PCI

6 <23.170 8.2645 8.2940 “0.36 303.975 302.674 0.43

8 <73.193 7.2389 7.2615 -0.31 303.975 302.865 0.37

i 203. 084 21.0555 21,9229 -0.31 405.300 398.076 1.7®

0 223.249 20.4443 23.5031 -0.29 405.300 400.047 1.30

8 248.175 18.7101 19.7744 -0.34 405.300 400.609 1.1b

8 273.150 17.0890 17.1149 -0.15 405.300 403.685 0.40

8 298.142 15.5568 15.5774 -0.13 405.300 404.149 0.28

8 323.140 14. 1884 14.2021 -0.10 405.300 404.536 0.1®

8 373.150 11.9826 11.9798 0.02 405.300 405.442 -0.04

8 423.17® 10.3595 10.3644 -0.05 405.300 405.033 0.07

8 473.193 9.1334 9.1562 -0.36 405.300 403.406 0.47

8 203.084 22.6624 22.7661 -0.46 506,625 493.032 2.68

8 223.249 21.4329 21.4990 -0.31 506.625 499. 136 1.48

S 248.175 19.927® 19.9710 -0.22 506.625 502.467 0.82

8 273.156 18.5015 18.5062 -0.C3 506.625 506.229 0.0®

8 298.142 17.1165 17.1324 -0.09 506.625 505.421 0.24

8 323.140 15.8521 15.8717 -0.12 506.625 505.255 0.27

8 373.150 13.7378 13.7283 0.07 506.625 507. 24e -0.12

8 423.170 12.0596 12.0610 -0.01 506.625 506.537 0.02

8 473.193 10.7489 10.7735 -0.23 506.625 504.941 0.33

8 203.084 23.3596 23,4699 -0.47 607.950 590.986 2.79

8 223.249 22.2294 22.3031 -0.35 607.950 597. 281 1.75

8 2*8. 175 20.8623 20.91*4 -0.25 607.950 601.007 1. 01

8 273.150 19.5734 19.5010 -0.04 607.950 607.149 0. 1 3 8 298.142 18.3049 10.32*8 -0.11 607.950 606. 061 0.31

8 323.140 17. 1425 17.1584 -0.09 607.950 606.545 0.23

8 373.150 15.1352 15.1212 0.09 607. 950 609. 079 -0. 19

8 423.170 13.4603 13.46)2 -0.07 607.950 607.249 0.12

8 473.193 12. 1247 12.1452 -0.17 607.950 606.313 0.27

6 203.084 23.9594 24.0792 -0.50 709.275 680.301 2.96

8 223.249 22.9159 22.9958 -0.35 709.275 696.725 1. 77

S 248.175 21.6406 21.7300 -0.27 709.275 701.031 1.16

8 203.084 24.4532 24.6195 -0.68 310.600 778.233 3.99

8 223.249 23.4668 23.5970 -0.56 810.600 7 87.505 2.85

8 2*8.175 22. 2969 22.3776 -0.36 810.600 797.808 1.58

8 273.150 21.1777 21.2125 -0.16 810.600 805.568 0.62

8 298.142 20. 0986 20.1116 -0.06 810.600 808.873 0.21

8 323.140 19.0499 13.07 99 -0.16 810.600 806.862 0.46

8 373.150 17.2472 17.2324 0.09 810.600 812.271 -0.21

8 423.17® 15.6727 15.6657 0.04 810.600 811.239 -0.08

8 473.193 I*. 3403 14.3541 -0.10 810. 600 809. 144 0.18

8 203.084 24.9163 25.1070 -0.77 911.925 871. 132 4.47

8 223.249 23. 9®39 2*. 1335 -0.63 911.925 882.279 3,25

8 248.175 22.8601 22.9752 -0.51 911.925 891.365 2.25

8 203.084 25. 3296 25.5529 -0.68 1013.250 96 1 • 450 5.11

8 223.249 24. *55b 24.6232 -0.69 1013.250 977. 377 3.54

8 2*8.175 23.4024 23.51*3 -0.48 1013.250 991. 336 2.16

8 273.150 22.3610 22.4553 -0.42 1013.250 996.203 1.6 0 8 298.142 21.4062 21.45 30 -0.22 1013.250 1005.343 0.78

8 323.140 20.4724 23.51)3 -0.19 1013.250 1007.20* 0.60

8 373.150 18.8247 18.8049 0.11 1013.250 1016. 155 -0.29

8 *23.170 17.3361 17.32 96 0.04 1013.250 1014. 142 -0. C9

8 473.193 16.0518 15.0626 -0.07 1013.250 1011.809 0. 14

IMP * 158, ONRMSPCT * 0.927, P.1E&NPCT = 0.811

67
METHANE EQUATION OF STATE

10 T,K NOL/L CALCD D, PCT P » B AR CALCD P , PC T I® 111.230 27.9096 27.7368 0.62 287,000 330.430 -15.13

19 111.230 20. 3046 26.1820 0.43 402.000 435.402 -8.31

10 111.230 20.7274 28.6033 0.44 519.000 555.859 -7.10

16 111.230 29*3600 29.2876 0.25 726.000 748.629 -3. 12

19 121.19® 26.7237 25.7059 0.07 218.000 221.629 -1.66

li 121.190 27.2628 27.2437 0.07 335.000 339.443 -1. 33

19 121.190 20.6779 28.7714 -0.33 746.000 717. 882 3.77

10 121.190 29.2141 29.3993 -0.63 942.000 883.158 6.25

10 121.190 29.7000 30.0281 -1.10 1144.000 1038.585 9.21

10 131.790 27.151® 27.0972 0.20 465.000 *77.929 -2.78

10 131.790 27.7003 27.6663 0.12 607.000 616.142 -1.51

&6 131.79® 28.1770 28.1778 -0.00 748.000 747.769 0. 03

10 131.790 20.6041 28.6618 -0.20 892.000 874.345 1.98

10 131.790 29.0360 29.1574 -0.42 1048.000 1009.132 3. 71

18 143.029 26.4131 26.40 98 0.01 483.000 483.706 -0.15

10 143.020 27.2926 27.3457 -0.19 705.000 691.261 1.95

10 143.020 28. 1373 2d. 2791 -0.50 968.000 925.546 4.39

10 156.960 25.5297 25.6325 -0.40 495.000 475.425 3.95

10 156.960 26.1575 25.22*0 -0.25 617.000 602.479 2.35

10 156.969 26.7451 26.8704 -0.47 769.000 737.990 4. 03

10 156.960 27.3748 27.5527 -0.65 951.000 901.418 5.21

10 167.610 24.4616 24.46 97 -0.03 415.000 413.773 0.30

10 167.610 25.2653 25.3086 -0.17 560.000 551.797 1.46

10 167.610 26. 1370 26.2171 -0.31 751.000 732.646 2. 44

10 167.610 26.8384 26.9625 -0.46 936.000 903. 389 3.48

10 179.290 24.1604 24,1597 0.00 488.000 488.111 -0.02

10 179.290 25.5493 25.6163 -0.26 758.000 7*3.645 1.89

18 179.290 26.5111 26.6420 -0.49 1003.000 969.062 3.38

18 192.870 22.0604 21.9938 0.30 334.000 340.782 -2.03

10 192.870 23.5849 23.5665 0.08 529.000 531.754 -0.52

10 192.070 24.6427 24.6619 -0.08 714.000 710.368 0.51

10 192.070 25.7998 25.8934 -0.36 979.000 956.566 2.29

10 212.000 21.2404 21.25 09 -0.05 401.000 399.974 0.26

10 212.000 22.7739 22.8011 -0.12 586.000 582.144 0.66

10 212.000 23.7417 23.8103 -0.29 746. 000 734. 020 1.61

10 212.000 24.7463 24.8535 -0.43 950.000 927.097 2.41

10 225.070 20.O101 20.6239 -0.07 428.000 426.697 0.30

10 225.070 22.2519 22.3289 -0.35 625.000 614.392 1.70

10 225.070 23. <*797 23.5764 “0.41 823.000 805.795 2. 09

10 225.070 24. 7219 24.8723 -0.61 1087.000 1053.005 3. 13

10 237.570 17.9437 17.9453 -0.01 302.000 301.912 0.03

16 237.570 21.4638 21 • 4d 5

1

-0.10 606.000 603.343 0.44

10 237.570 23. 5793 23.6427 -0.27 946.000 933. 846 1.28

10 249.430 18. 8076 13.7664 0.22 411.000 414.071 -0.75

10 2*9. 430 20.6016 20.6115 -0.05 581.000 579. 893 0.19

10 249.430 21.8579 21.8803 -0.10 7** • 0 00 7*0.749 0. *4

10 249.430 23. 0256 23.0853 -0.2b 942.000 931.074 1.16

10 261.550 17.9147 17.8937 0.09 407.000 408. 084 -0.27

10 261.550 19.4666 19.4627 0.02 533.000 533.376 -0.07

10 261.550 20.7512 20.8011 -0.24 b80 . 0 00 673. 754 0. 92

10 261.550 21.7628 21.8467 -0.39 826.000 813. 157 1.55

10 261.550 22. 7583 22.8751 -0.51 1001.000 979.421 2.1o

10 278.710 15.7754 15.70 97 0.42 348.000 351.227 -0.93

10 278.710 18. 1752 18.1102 0.36 500. 000 505.265 -1.05

10 278.710 19.51&0 19.4*33 0.35 624. 000 631.214 -1.1b

10 278.710 20.7211 20.6978 0.11 774.000 777.158 -0-41

10 270.710 22. 1288 22.1471 -0.08 999.000 995. 763 0. 32

10 293.410 16. 7983 15.3116 -0.08 *65 .000 464.088 0.20

10 293. <*10 18.8466 18.8768 -U . 16 6*0 .000 b36. 895 0.49

10 293 .<*10 20. 1776 20 . 1681 0.05 791. 000 792.250 -a. lb

10 293.410 21.2089 21.2392 -0.14 947. 000 942. 168 0.51

10 309.290 1<*. 2227 1* • 22 63 -0.03 369.000 368.829 0.06

10 309.290 16.6694 16 .6826 -0.08 516.000 515. 02C 0. 1 9 10 309.290 18. <*570 18.4J 05 0.31 667.000 672.843 -0.88

10 309.290 19.9283 19.9174 0.05 847.000 8*8.477 -0.17

10 309.290 21.2721 21.2901 -0.08 1058.000 1054.885 0.29

NP = 6b, ONRMSPCT = J. 329, P9EANPCT = 2.037

68
METHANE EQUATION OF STATE

10 T »K MOL/L CALCD 0 »PCT P f BAR CALCD P j PC T 4101 176.000 2.9954 3.0047 - 0.31 27.962 27.919 0.15

4102 180.000 2.9936 3.0035 - 0.33 29.335 29. 283 0.18

4103 164.000 2. 9918 3.0020 - 0.34 30.663 30.624 0.19

4104 188.000 2.9901 2.9997 - 0.32 32.008 31.946 0.19

4105 192.000 2.9883 2.9974 - 0.30 33.316 33.253 0.19

4106 196.000 2.9865 2.9951 - 0.29 34.610 34.546 0.19

4107 200.000 2.9846 2.9926 - 0.26 35.890 35.827 0.17

4106 204.000 2.9631 2.9901 - 0.24 37.158 37.098 0.16

4109 208.000 2.9813 2.9877 - 0.21 38.417 38.359 0.15

4110 212.000 2.9796 2.9851 - 0.19 39.665 39.612 0.13

4111 216.000 2.9779 2.9328 - 0.17 40.907 40.857 0.12

4112 220.000 2.9761 2.9806 - 0.15 42.142 42.094 0.11

4113 225.000 2.9739 2.9776 - 0.12 43.673 43.631 0.10

4114 230.000 2. 9717 2.9749 - 0.10 45. 196 45.159 0.08

4115 240.000 2.9675 2.9698 - 0.08 48.219 48.109 0.06

4116 250.000 2.9630 2.9643 - 0.04 51.203 51.185 0.04

4117 260.000 2.9585 2.9591 - 0.02 54.160 54.152 0.0 1 4118 270. 000 2. 9540 2.9538 0.01 57.089 57.092 - 0.01

4119 280.000 2.9495 2.9438 0.02 59.996 60.008 - 0.02

4120 290.000 2.9450 2.9434 0.05 62.872 62.902 - 0.05

4121 300.000 2.9402 2.9392 0.03 65.748 65. 768 - 0.0 3 4001 184.000 3.9782 3.9524 0.65 35.156 35.250 - 0.27

40 02 188.000 3.9756 3.9602 0.39 37.096 37.162 CO O • 1 40 03 192.000 3.9730 3.9627 0.26 38.989 39. 039 - 0.13

40 04 196.000 3.9705 3.9724 - 0.05 40.900 40.889 0.03

40 05 200.000 3. 9683 3.9734 - 0.13 42.750 42.719 0.07

40 06 204.000 3.9654 3.9700 - 0.11 44.556 44.526 0.07

40 07 208.000 3.9629 3.9672 - 0.11 46.349 46.318 0 . 07

40 06 212.000 3.9604 3.9641 - 0.10 48.124 48.095 0.06

40 09 216.000 3.9579 3.9611 - 0.08 49.885 49. 859 0.05

4010 220.000 3.9554 3.9578 - 0.06 51.632 51.610 0.04

4011 225.000 3.9522 3.9539 - 0.04 53.800 53. 784 0.0 3 4012 230.000 3.9490 3.9497 - 0.02 55,949 55.942 0 . 01

4013 240.000 3.9427 3.9417 0.03 60.204 60.216 - 0 . C 2 4014 250.000 3.9363 3.9339 0.06 64.407 64.439 - 0.05

4015 260.000 3 . 9300 3.9265 0.09 68 . §68 68.617 - 0.07

4016 270. 000 3.9235 3.9138 0.12 72.682 72.754 - 0 . 10

4017 280.000 3.9170 3.9114 0.14 76.758 76.853 - 0.12

4018 290.000 3.9104 3.9044 U • 15 80.805 80.915 - 0.14

4019 300. 000 3. 9038 3.8975 0.16 84.819 84.942 - 0.15

3901 188.000 4. 9304 4.8971 0.68 40.276 40.361 - 0.2 1 3902 192.000 4. 9269 4.9018 0.51 42.770 42.851 - 0.19

3903 196.000 4.9236 4.9053 0.37 45.221 45.292 -

0 . 1 b

39 04 200.000 4.9202 4.9032 0.24 47.641 47,695 - 0 . 11

39 05 204.000 4.9169 4.9105 0.13 50.036 50.068 - 0 . C 6 39 06 206.000 4.9135 4.9122 0.03 52.409 52.416 - 0.0 1 39 07 212.000 4. 9102 4.9103 - 0.00 54.744 54.743 0.00

39 08 216.000 4.9069 4.9071 - 0.00 57.052 57.051 0.0 0 3909 220.000 4. 9035 4.9020 0.03 59. 330 59. 341 - 0 . 02

3910 225.000 4. 8994 4.8938 C .01 62.178 62.163 - 0.0 1 3911 230.000 4. 8952 4.8943 0.02 64.995 65.003 - 0.0 1 3912 240. 000 4. 6868 4 • 6846 0.04 70.563 70.586 - 0.03

69
METHANE EQUATION OF STATE

ID ? 9 «C MOL/L CAICB

3913 250 . Q 0 @ 4. 878 % 4.8750

391% 260.000 4.6699 4.8651

3915 270.000 4 . 861 % 4.8554

3916 286.000 4.8527 ‘.8459

39 17 290.060 4.6440 4.8367

3916 300.000 4.8353 4.8274

33 01 192.006 5.9478 5.9190

3802 196. 000 5.9435 5.925 9

33 03 200.000 5 ® 9392 5.9273

36 0 % 204.000 5.9350 5.9281

38 05 206.000 5.9307 5.9287

33 06 212.000 5.9264 5.9265

36 07 216.000 5.9222 5.9232

36 08 220.000 5.9179 5.9136

3309 225.000 5.9126 5.9137

3610 230.000 5.9072 5.9031

3611 240.000 5.6965 5.8958

3312 250.000 5.8857 5.8835

3813 260.000 5.8749 5.8712

331% 270.000 5.8640 5.8531

3315 260.000 5.8531 5.8488

3816 290.000 5.8422 5.8352

361 7 300.000 5.8312 5.8236

37 01 192.000 6.9618 8.9278

37 02 196.000 6.9765 8.9454

3703 200.000 6.9712 6.9532

37 0 % 204.000 6.9659 6.9571

37 05 208.000 6.9607 6.9577

37 06 212.000 6.9555 6.9571

37 07 216.000 6.9502 6.9539

37 06 220.000 6.9450 6.9498

3709 225.000 6.9384 6.9438

3710 230.000 6.9317 6.9367

3711 240.000 6.9186 6.9212

3712 250.000 6.9053 6.9055

3713 260.000 6.8920 5.8939

371 % 270.000 6.8786 6.8758

3715 280.000 6.8653 5.8622

3716 290.000 6. 8521 5.8462

3717 300.000 6. 8389 5 • 8346

3601 192.000 7.9789 7 • 8*50

36 02 196.000 7.9726 7.9151

36 03 200.000 7.9664 7.9312

36 04 204.000 7.9601 7.9334

36 05 208.000 7.9539 7 . 9*26

3606 212.000 7.9476 7.9458

3607 21 o .000 7.9413 7.9438

3608 220.000 7.9350 7.9402

36 09 225.000 7 . 9271 7.9335

3610 230.000 7.9192 7.9259

3© 11 240.000 7.9034 7.9101

3612 250.000 7.8876 7.8928

3613 260. 000 7.8718 7.8755

D,PCT P t BAR CALCO P,PCT

0.07 76. 060 76. 101 - 0.05

0.10 81.491 81.555 - 0.08

0.12 86.867 86.954 - 0.10

0.14 92.190 92.301 - 0. 12

0.15 97.469 97.599 - 0.13

0.16 102.699 102.850 - 0.15

0.49 45.371 45.427 - 0.12

0.30 48.493 48.539 - 0.09

0.20 51.555 51.594 - 0 . 08

0.12 54.580 54.607 - 0.05

0.03 57.577 57.586 - 0.02

- 0.00 60.538 60.537 0.00

- 0.02 63.471 63.465 0.01

- 0.01 66.376 66.371 0.01

- 0.02 69.986 69 . 978 0 . 01

- 0.02 73.565 73.558 0.01

0.01 80.641 80.646 - 0.01

0.04 87.631 87.656 - 0.03

0.06 94.542 94.589 - 0 . 05

0.08 101.384 101.454 - 0.07

0.11 106.156 108.255 - 0.09

0.12 114.873 114.994 - 0.11

0.13 121.534 121.673 - 0.11

0.77 46 . 845 46.900 - 0.12

0.45 50.661 50.714 - 0.10

0.26 54.408 54 . 45 C - 0.08

0.13 58.110 58.137 - 0.05

0.04 61.774 61.785 - 0.0 2 - 0.02 65.410 65.403 0.01

- 0.05 69.013 68.995 0 . 03

- 0.07 72.591 72.563 0.04

- 0.08 77.032 76.996 0.05

- 0.07 81.437 81.401 0.04

- 0.04 90.158 90. 134 0.03

- 0.02 98.789 98.776 0 . 01

0.02 107.322 107.336 - 0.0 1 0.03 115.791 115.817 - 0.02

0.04 124.174 124.222 - 0.04

0.06 132.489 132.556 - 0.05

0.06 140.737 140.820 - 0.06

1.68 47.528 * 7.590 - 0 . 13

0.72 52.011 52.075 - 0.12

0.44 56.416 56.479 - 0.11

0.27 60.781 60.834 - 0.09

0.14 65. 120 65. 156 - 0.05

0.02 69.442 69.449 - 0 . 0 1 - 0.03 73.730 73.719 0.02

- 0.07 77.995 77.966 0.04

- 0.08 83.292 83.252 0.05

- 0.10 88.565 88.510 0.06

- 0.08 99.012 98.953 0.06

- 0.07 1 09 . 3 o 0 109.304 0.05

- 0.05 119.614 119.567 0.04

70
METHANE EQUATION OF STATE

ID T*K NOL/L calcd

3614 270.000 7.8961 7.8532

3615 280. 000 7 . 8405 7.8412

3616 290.000 7.8251 7.8245

3617 300.000 7.8100 7.8083

3501 192.000 9 . 0©90 9.0165

35 02 196. 900 9. 0817 9.0404

35 03 200.000 9. 0743 9.0456

3504 204.000 9.0669 9.0445

35 05 203.000 9.0595 9.0504

35 06 212.000 9.0520 9.0491

35 07 216.900 9.0445 9.0454

3508 220.000 9.0369 9.0420

35 09 225. 000 9. 0275 9.0343

3510 230.000 9.0180 9.0265

3511 240.000 8.9990 9.0072

3512 250.000 8.9801 8.9865

3513 260.000 8.9614 8.9636

3514 270.000 3.9429 8.9456

3515 230.060 8.9249 8.9258

3516 290 . 00 ® 8.9072 8.9067

3517 300.000 8.8900 8.8838

3401 192.600 10.2380 13.0595

3402 196.000 10.2296 10.1056

3403 200.000 10.2210 10.1274

3404 204.000 10.2123 10.1412

34 05 208,000 10.2035 13.1497

34 06 212.000 10.1947 10.1539

3407 216.000 10.1658 10.1547

3408 220 . 00 ® 10.1769 10.1539

34 09 225.000 10.1657 10.1433

3410 230.000 10.1545 10.1417

3411 240.000 10.1320 13.1230

3412 250.000 16 . 1100 13.1018

3413 260. 300 10.0882 IQ . 0805

3414 270. 060 10.0671 13.0583

3415 280.088 10.0466 13.0374

3416 290.000 10.0270 13.0170

3417 306.000 10.0081 9.9976

3301 192.006 11.1113 11.0749

3302 1 96 .

0 0 11.1019 10 . 98*8

3303 206.000 11.0923 13.9993

33 04 204. 060 11 . 0825 11.0134

33 05 208.600 11.0725 11.0189

3306 212.000 11.0625 11.0130

3307 216.606 11.0523 11.0139

33 08 220.060 11. 0422 11.0153

3309 225.600 11.0294 11.0076

3310 230.000 11.0167 13.9935

3311 240.000 10. 9914 10.9792

3312 256.000 10.9667 10.9539

3313 266.006 10,9428 10.9299

3314 270.000 10.9198 13.9064

3315 280. 600 10. 8978 10.8830

PCT P , BAR CALCO P*PCT

.03 129.779 129 . 74 ® 0,02

.01 139.858 139.846 0.01

.01 149.853 149.864 - 0.0 1 .02 159.769 159.803 - 0.0 2 .80 47.891 47.906 — 0 • 03

.45 93.082 53 . 11 ® - 0.07

.31 58.237 58.281 - 0.07

.25 63.364 63,416 “ 0.06

.10 68.502 6®. 530 - 0.04

.03 73.619 73.626 » 0.02

.01 78.711 78.707 0.01

.06 83.800 83.773 0.03

.08 90.129 90.085 0.05

.09 96.439 96.376 0 . 06

.09 108.970 108.894 0.07

.07 121 . 39® 121.325 0.06

.09 133.727 133.670 0.04

.03 145.970 145.927 0.03

.01 158.114 158.098 0 . 0 1 .01 170. 170 170. 180 - 0.0 1 .01 182.149 182. 174 “ 0.01

.74 48.104 48.141 - 0.08

.21 54.020 54.133 - 0.21

.92 59.983 60. 141 - 0 . 26

.70 65.977 66. 155 - 0.27

.53 71.990 72. 170 - 0.25

.40 78.012 78.183 - 0.22

.31 84.035 84.193 - 0.19

.23 90 . 060 9 C . 196 - 0.15

.17 97.568 97.690 - 0 . 12

.13 105.066 105.170 - 0.10

.09 119. 985 120. 079 - 0 , 08

.03 134.809 134.913 -0.0 8

. 0 ® 149.544 149 . 66 C - 0.08

.09 164. 165 164.317 • 0.09

.09 178.700 178,881 “ J . 1 0 .10 193. 133 193.354 “0.11

.11 207.474 207.729 - 0.12

.33 48.322 48.331 “0. 02

.03 54.855 54 . 97 C -0.21

.84 61.513 61.686 - 0.28

.62 68.249 68.439 - 0.26

.48 75.017 75.214 - 0.26

.49 81.773 82.002 - 0.26

.30 © 8.609 08.795 - 0 . 2 1 .24 95.415 95.591 “ 0.18

.20 103,913 104 . 08 ?

- 0.16

.17 112.402 112.565 - 0.15

.12 129.341 129.493 - 0.12

.12 146.170 146.349 - 0 . 12

.12 162.909 163 . 12 ?

- 0.13

.12 179.548 179. 804 - 0.14

.14 196.070 196 . 38 ® - 0 . 1 b

D , -0

-0

0

00

D

0

00

0 -0

-0

“0

-0

-0

-0

-0

-0

-0

0

01

10

0

00

0

00

0

0

00

00

0

00

1

0

0

0

00

0

0

00

0

0

0

0

71
METHANE EQUATION OF STATE

10 T,K NOL/L calcd D,PCT P v BAR CALCD P,PCT

3316 290.000 10.9769 10.8612 0.16 212.697 212.875 - 0.18

3317 300.000 10.9570 10.8608 0.15 228.826 229.259 - 0.19

3291 192. OOi 12.0697 12.1368 ” 0.56 68.685 66.652 0.07

3202 196.000 12.0591 12.0128 0.38 56.033 56. 096 - 0.12

32 @3 200.000 12.0691 12.0017 0.39 63.576 63.685 - 0.17

3204 206.000 12.0370 11.9996 0.31 71.216 71 . 366 - 0 . 18

3205 200.000 12.0256 11.9956 0.25 78.913 79.067 - 0.17

3206 212.900 12.0162 11.9916 0.19 86.656 86.779 - 0.16

32 07 216.000 12.0026 11.9873 0.13 94.628 96.529 - 0.11

32 OS 229.000 11.9912 11.9797 0.10 102.201 102.289 - 0.09

3209 225.009 11.9767 11.9678 0.07 111.912 111.993 - 0.07

3219 230.009 11.9626 11.9569 0.06 121.617 121.696 - 0.06

3211 260.009 11.9362 11.9277 0.06 160.965 161.072 - 0.06

3212 250.000 11.9069 11.8990 0.07 160.255 160.361 - 0.08

3213 260.000 11.9308 11.8710 0.08 179.625 179.606 - 0.10

3216 270.000 11.9562 11.9666 0.10 196.690 196.766 - 0.13

3215 260.000 11.9330 11.8192 0.12 217.642 217.777 - 0 . 15

3216 290.000 11.3112 11.7958 0.13 236.293 236.710 - 0.18

3217 300.000 11.7906 11.7739 0.16 255.031 255.528 - 0.20

3101 192.000 12.9815 13.0293 - 0.37 69.655 69. 395 0.12

3102 196.090 12.9695 12.97 52 - 0.06 57.790 57. 776 0.02

3103 200.000 12.9570 12.9575 - 0.00 66.328 66.326 0 . 00

3196 206.000 12.9662 12.9690 - 0.06 76.993 76.971 0.03

311$ 209.000 12.9313 12.9399 - 0.07 63.726 63.675 0.06

3106 212.008 12.9186 12.92 96 - 0.09 92.699 92.619 0.09

3107 216.000 12.9053 12.9193 - 0.11 101.306 101.187 0.12

3106 220.000 12.9923 12.9075 - 0.12 110.116 109.971 0.13

3109 225.000 12.8761 12.8902 - 0.11 121.115 120. 959 0.13

3110 230.000 12.9600 12.8733 - 0.10 132.115 131.967 0.13

3111 260 . 00 ® 12.9286 12.8399 - 0.08 156.057 153.695 0.11

3112 250.000 12.7988 12.8053 - 0.05 175.900 175.779 0.07

3113 260.000 12.7708 12.7736 - 0.02 197.638 197.577 0.03

3116 270.000 12.7668 12.7661 0.01 219.261 219.280 - 0.0 1 3115 290.000 12.7205 12.7152 0.03 260.753 260.875 - 0.05

3116 290.000 12.6980 12.6906 0.06 262.130 262.358 - 0.09

3117 300.000 12.6767 12.6670 0 . 08 283.387 283.714 - 0.12

3001 192.000 16.2336 16.2136 0.16 52. 052 52.119 - 0.13

30 02 196.000 16.2158 1^.2366 - 0.11 62.209 62 . 133 0.12

30 03 200.000 16.2038 14.2278 - 0.17 72.651 72. 298 0.21

30 06 206. 000 16. 1686 16.2175 - 0.20 82.785 82.559 0.27

30 05 209.000 16.1733 16.2053 - 0.23 93.177 92.880 0.32

30 06 212.000 16. 1580 14.1923 - 0.26 103.608 103.260 0.36

30 07 216.000 16. 1627 16.1769 - 0.26 116.040 113.623 0.37

30 00 220.000 16 . 1275 14.1612 - 0.26 126.678 126.019 0.37

30 09 225. 000 16. 1088 16.1639 - 0.23 137.516 137.02

2

0.36

30 10 230.000 16.0906 14.1205 - 0.21 150.536 150.020 0.36

3011 260. 000 16. 0557 16.0811 - 0.18 176.506 175.976 0.30

JO 12 250.000 16. 0233 14.0636 - 0.16 202.352 201. 861 0.26

3013 260.000 13.9939 14.0036 - 0.10 228.06

2

227.655 0.16

3016 270.000 13.9669 13.9756 - 0.07 253.635 253.338 0.12

3015 290.000 13.9621 13.9669 - 0.03 279.069 278.901 0.06

3016 290.000 13.9190 1J.9191 - 0.00 306.333 306.328 0.00

3017 300.000 13.8972 13.8945 0.02 329.683 329.597 - 0.03

72
METHANE EQUATION OF STATE

ID T »K HOL/l CALCD 0 » PCI P v BAR CALCD P 5 PC T 2901 190.000 15.3796 15.3591 0.13 51.866 51.991 -0.24

2902 194.00® 15.3621 15.3622 “0.00 63.787 63.786 0.00

2903 198.000 15.3444 15.3537 “0.10 75.861 75.711 0.20

2904 202.003 15.3267 15.3521 "0.17 88.012 87.719 0.33

29 OS 206.000 15.3088 15.3408 "0.21 100.201 99.775 0,42

2906 210.000 15.2911 15.3255 -0.23 112.37® 111.862 0.46

2907 215.000 15.2692 15.3047 -0.23 127.596 126. 989 0. 4®

2908 220.000 15.2478 15.2826 "0.23 142.792 142.120 0.47

2909 230.000 15.2071 15.2401 -0.22 173.125 172.356 0.44

2910 240.000 15.1701 15.1981 -0.18 203.287 202.521 0.38

2911 250.000 15. 1369 15.1597 -0.15 233.313 232.595 0.31

2912 260.000 15. 1069 15.1245 -0.12 263.178 262.553 0.24

2913 270.000 15.0797 15.0920 -0.08 292.861 292.370 0.16

2914 280.000 15.0546 15.0627 "0.05 322.396 322.046 0.11

2915 290.000 15.0313 15.0342 -0.02 351.677 351.539 0.04

28 01 186.000 16.2733 16.2612 0.07 45.617 45.715 -0.22

28 02 190.000 16.2543 16.2533 0.01 59.078 59.089 -0.02

2803 19*. 000 16.2348 16.2*29 "0.05 72.680 72.579 0.14

28 04 198.900 16.2151 16.2305 -0.09 86.363 86.140 0.26

2805 202.000 16. 1953 16.21*0 "0.12 100.048 99.739 0.31

28 06 206.006 16. 1755 16.1970 -0.13 113.751 113.354 0.35

2807 210. 009 16. 1562 16.1796 -0.14 127.454 126.977 0.37

28 08 215.000 16. 1328 16.1515 -0.11 144.404 144.003 0.28

28 09 220.000 16. 1098 io.1340 -0.15 161.607 161.002 0.37

2810 230.000 16.0677 16.0906 -0.14 195.626 194.946 0.35

2811 240.000 16. 0302 16.0493 -0.12 229.43® 228.785 0.28

2812 250.000 15.9971 16.0128 -0.10 263.114 262.507 0.23

2813 260.000 15.9676 15.9781 -0.07 296.539 296. 090 0.15

2814 270.O0® 15.9403 15.9462 -0.03 329.757 329.503 0.08

2701 182.000 17.2858 17.2732 0.04 41.322 41.416 "0.23

2702 186.0@@ 17.2636 17.2635 0.00 56,948 56.949 -0.00

27 03 190.000 17.2416 17.2489 -0.04 72.675 72.549 0.17

27 04 194. 000 17.2194 17.2282 -0.05 88.346 88. 173 0.20

27 05 193.000 17. 1973 17.2100 -0.07 104.060 103.801 0.27

2706 202.000 17. 1754 17.1913 -0.09 119.774 119.412 0.30

2707 206.000 17.1539 17.1713 -0.10 135.462 135.001 0.3*

270® 210.000 17. 1331 17.1511 -0.10 151.080 150.569 0.34

27 09 215.000 17. 1084 17.1279 -0.11 170.602 169.994 0.3b

2710 220,006 17.0848 17.1044 -0.11 190.033 189. 371 0,35

2711 230.000 17.0424 17.0614 -0.11 228.723 228. 023 0.31

2712 2*0.000 17. 0056 17.0237 -0.09 267 .186 266.524 0.25

2713 250.000 16.9731 16.9853 -0.07 305.442 304.850 0.19

2714 260.000 16.9441 16.9513 -0.04 343. 357 342.973 0.11

2601 176.000 18. 3840 18.3815 0.01 32. 172 32. 217 -0.14

26 02 180.000 18.3570 18.3563 0.00 50.437 50. *53 -0.0 3 2603 184.300 18.3320 18.3311 0,00 68.691 68.711 -0.0 3 26 04 188.000 18.3070 18.3061 0.00 86.906 86.929 -0.0 3 2605 192.000 18.2310 13.2821 -0.01 105.089 105.057 0. C 3 26 06 196.000 18.256Q 19.2589 -0.02 123.227 123. 136 0.07

2607 200.000 18.2320 18.2364 -0.02 141.311 141.163 0.11

26 08 205.000 18.2030 18.2099 -0.04 163.860 163.604 0.1b

26 09 210.000 18.1750 18.1844 -0.05 186.312 185.937 0.20

2610 215.000 18. 1500 18.1633 -0.06 208,687 208.243 0.21

73
METHANE EQUATION OF STATE

10 T,K MOL/l CALCO

2611 220. 000 18. 1270 13.1380

2612 225.000 18. 1060 13 . 11S9

2613 230.000 18.0860 18.0970

2614 235.000 18.0680 18.0732

2616 240.000 16.0520 18.0604

26 16 245.000 18.0360 18.0433

2561 170 * 00 ® 19.5060 19.4878

2512 174.000 19.4750 19.4553

2503 178.009 19.4460 19.4240

2504 162.000 19.4170 19.3929

2S®5 166 * 009 19. 3880 19.3635

25 06 190.009 19.3590 19.3362

2507 194.000 19.3320 19.3107

2506 196.000 19.3070 19.2863

25 09 202.000 19.2830 19.2635

2S10 205.000 19.2660 19.2477

2511 210.000 19.2400 19.2232

2512 215.000 19.2160 19.2004

2513 220.000 19.1950 19.1796

2516 225.000 19. 1750 19.1601

2515 230.000 19.1570 19.1414

2401 164.000 20.4250 20.4229

24 02 168.000 20.3890 20.3669

2403 172.000 20.3570 20.3511

2404 176.000 20.3240 20.3157

2405 180.060 20. 2920 20.2820

2406 184.000 20.2600 20.2511

2407 188.000 20.2310 20.2224

2406 192.000 20.2060 20.1960

2409 196.000 20.1780 20.1723

2410 200.000 20.1550 20.1507

2411 204.000 20.1340 20.1308

2412 208.000 20.1150 23.1125

2413 212 . Q00 20.0970 20.0955

2414 216.000 20.0800 20.0794

2415 220.000 20.0650 20 • 3 o 43

2301 158.000 21. 3710 21.3700

23Q2 162.000 21.3320 21.3297

2303 166.000 21.2940 21.2392

2304 170.000 21.2580 21.2478

23 05 174. 000 21.2230 21.2111

23 06 178.000 21.1690 21.1775

2307 182.000 21.1580 21.1472

2308 186. 000 21.1290 21.1233

2309 190.000 21.1030 21.0961

2310 194.000 21.0800 21.0746

2311 198.000 21.0590 21.0546

2312 202.000 21.0400 21.0365

2313 20o. 000 21. 0220 21.0196

2201 152.000 22.1250 22.1227

22 0 2 156.000 22. 0800 22.0775

22 03 160.000 22.0400 22.0311

2204 164.000 22.0010 21.9873

PCT P,BAR CALCO P,PCT

.06 231. 002 230.496 0.22

.06 253.237 252.704 0.21

.06 275. 393 274. 828 0.21

.06 297.479 296. 925 0.19

.05 319.486 319.006 0.15

.04 341.402 340.966 0.13

.09 26.367 26.867 - 1.90

.10 47.743 48.348 - 1.27

• 11 69.007 69.748 - 1.07

• 12 90.117 90.999 - 0.98

.13 111.128 112.093 - 0.87

.12 132.061 133.021 - 0.73

.11 152.913 153.871 - 0.63

.11 173.668 174.653 - 0.57

.10 194.349 195.331 - 0.51

.09 209.838 210 . 79 ?

- 0.45

.09 235.576 236.507 - 0.40

.08 261.206 262.122 - 0.35

.08 286.762 287.716 - 0.33

.08 312.214 313.185 - 0.31

.08 337.542 338.603 - 0.31

.01 20.288 20.365 - 0.38

.01 44.689 44.775 - 0.19

.03 68.823 69. 083 - 0.38

.04 92.700 93.091 - 0.42

• 05 116.390 116.890 - 0.43

.04 139.966 140.436 - 0.34

.04 163.418 163.898 - 0.29

.05 186.776 187 . 36 ? - 0.31

.03 210.084 210 . 43 ?

- 0.17

.02 233.321 233. bOO - 0.12

.02 256.494 256.708 - 0.08

.01 279.599 279. 772 - 0 . Ob

.01 302.629 302.739 - 0.04

.00 325.569 325.617 - 0.0 1 .00 346.434 348.492 - 0.02

.00 19.836 19.886 - 0.25

.01 47.537 47.661 - 0 . 26

.03 74.747 75. 077 - 0.44

.05 101.595 102.215 - 0.61

.06 128.267 129. 041 - 0.59

.05 154.807 155.574 - 0.50

.05 181.216 181.971 - 0.42

. 04 207.556 208.194 - 0.31

.03 233.818 234. 344 - 0.23

.03 260.026 260.455 - 0 . 1 7 .02 286.118 286.478 - 0 . 1 3 .02 312.140 '312.433 - 0.09

.01 338.043 338.256 - 0.06

• 01 14.593 14.736 - 0.98

.01 45.086 45.250 - 0 . 3b

.04 74.923 75.542 - 0 . 8 3 .06 104.403 105 . 39 ?

- 0.95

0 , -o

-o-0

-0-o

-0

0

0

00

0

0

0

0

00

0

0

0

0

00

0

00

00

0

0

00

c0

0

00

00

0

0

000

00

o , 0

00 , 0 , o.

o , 0 ,

74
METHANE EQUATION OF STATE

10 T#K HOL/L CALCD

22 05 166.000 21.9620 21.9479

22 06 172.000 21.9290 21.9119

22 07 176.000 21.8920 21.8800

22 oa 160. 009 21.8620 21.8517

22 09 164.000 21.8360 21.8273

2210 168.000 21.8120 21.8055

2211 192.000 21.7910 21.7850

2212 196.000 21.7720 21.7678

2101 146.000 22.8730 22.8726

20 01 140.000 23.5700 23.5719

2102 150.900 22.8240 22 , 82*7

2103 154.000 22.7820 22.7757

2104 158.000 22.7390 22.7290

2105 162.000 22.6980 22.6873

2106 166.000 22.6600 22.6500

2107 170. 000 22.6260 22.6176

2106 174.000 22.5960 22.5895

2109 176.000 22.5700 22.5656

2110 182.000 22.5460 22.5442

2111 186.000 22.5250 22.5248

2002 144.000 23.5180 23.5214

20 03 148.000 23.4720 23.4691

20 04 152.000 23.4260 23.4195

20 05 156.000 23.3830 23.3754

20 06 160.000 23.3430 23.3369

20 07 164.000 23. 3080 23.3040

20 06 168.000 23 . 2780 23.2759

20 09 172.000 23.2520 23.2515

2010 176.000 23.2280 23.2305

1901 134.000 24. 1830 24.1826

19 02 138.000 24. 1250 24.1291

1903 142.009 24. 0760 24.0736

1904 146.000 24. 0270 24.0211

1905 150.000 23.9810 23.9748

1906 154.000 23.9400 23.9351

1801 134.000 24.1740 24.1729

1602 136. 000 24. 1410 24.1456

18 03 138.000 24. 1150 24.1188

16 04 140.000 24.0900 24.0912

1805 142.000 24.0660 24.0621

16 06 144.000 24. 0420 24.0343

1607 146.000 24.0170 24.0098

1608 148 .000 23.9940 23.9663

1609 150.000 23.9710 23.9639

1610 152.000 23.9500 23.9433

1811 154.000 23.9310 23.9244

1812 156.000 23.9120 23.9068

1813 158.000 23. 8930 23.8890

1614 160.009 23.8770 23.8747

1815 162.000 23.3620 23.8611

1616 164.000 23.6490 23.8484

1817 166.009 23. @360 23.8375

1816 168.000 23.8240 23.8273

PCT P » 0AR CALCD P.PCT

.06 133.692 134.753 » 0.79

.08 162.772 164.117 * 0.83

.05 191.756 192.736 “ 0.51

.05 220.648 221. 523 - 0.40

.04 249.520 25 0 ® 292 - 0.31

.03 278.308 278.907 “ 0.22

• 82 307.015 307.491 - 0,16

.02 335.575 335.984 “ 0.12

.00 13.127 13.157 - 0.23

.01 12.262 12. 091 1.39

.00 46.703 46.644 0 . 13

.03 79,462 79.988 - 0.66

.04 111.736 112.601 - 0.77

.05 143.810 144. 773 - 0.67

.04 175.712 176.642 - 0.53

.04 207.555 208.358 - 0.39

.03 239.330 239 . 98C - 0.27

.02 271. 112 271.565 - 0.17

.01 302.767 302.958 - 0.06

.00 334.282 334.300 “ 0.01

.01 48.910 48.585 0.66

.01 84.500 @ 4.782 “ 0 . 3 3 .03 119.526 120.182 - 0.55

.03 154.350 155.139 - 0.51

.03 189.067 189.720 - 0.35

.02 223.762 224.208 - 0.20

• 01 258.440 258.680 - 0 . 09

.00 293.040 293. 094 - 0.02

.01 327. 578 327.271 0.09

• 00 6,861 6.908 “ 0.69

.02 46.383 45.935 0.96

.01 84.630 84.901 - 0.32

.02 122.240 122.915 “ 0*55

.03 159.656 160.388 - 0.46

.02 197 .040 197.638 - 0 . 30

.00 5.841 5.957 - 1.99

.02 25.770 25.168 2.34

.02 45.258 44.850 0.90

.00 64.512 64.384 0.20

.02 83.348 83.784 - 0.52

.03 102.134 102.947 - 0.80

.03 120.944 121.767 - 0.66

.03 139.702 140. 595 - 0.64

• 03 158.374 159.209 - 0.53

.03 177.053 177.856 “ 0.45

.03 195.747 196. 549 - 0.41

.02 214.417 215.059 - 0.30

. 02 232.888 233. 390 - 0.22

.01 251.636 251.926 “ 0 . 1 1 .00 270.317 270.426 - 0 . C4

.00 288.962 289.034 - 0.02

.01 307.694 307.499 0.06

.01 326.391 325.958 0.13

D »0

0

0

6

00

00

0 -0-o

0

0

0

00

0

0

00 -o

0

0

00

00

0 -0

0 -0

00

0

00 -o

-0

-o

0

0

0

0

0

Q0

00

0

00 -0

-0

7 §
METHANE EQUATION OF STATE

10 T,K NOL/L CALCO Of PCT P » 8 AR CALCO Pf PCT

1819 170.000 23. 6120 23.8172 - 0.02 344.986 344.286 0.20

17 @1 130*000 24.6050 24.6098 - 0.02 7.286 6.724 7.71

17 02 132.000 24.5720 24.5822 - 0.04 28.230 27.024 4.27

1703 134.000 24.5460 24.5538 - 0.03 48.781 47.847 1.92

17 @% 136.000 24.5190 2*.5242 - 0.02 68.894 68.262 0.92

1705 138.000 24.4940 24.4940 0.00 88.639 88.644 - 0 . 01

17 06 140.000 24.4690 24.4663 0.01 108.425 108.761 - 0.31

1707 142*900 24.4430 24.4405 0.01 128.176 128.496 - 0 . 25

17 0 ® 144.000 24.4190 24.4160 0.01 147.856 148.236 - 0.26

1709 146.000 24.3960 24.3933 0.01 167.516 167.866 - 0.21

1710 148.000 24.3740 24.3726 0.01 187.222 187.399 - 0.09

1711 150*000 24.3540 24.3536 0.00 206.921 206. 978 - 0 . 03

1712 152.000 24.3350 24.3362 - 0.00 226.644 226.484 0.07

1713 154.000 24.3170 24.3134 - 0.01 246.119 245.929 0.08

1714 156.000 24.3010 24.3043 - 0.01 265.906 265.459 0.17

1715 158.000 24.2860 24.2912 - 0.02 285.671 284.951 0.25

1716 160.000 24.2730 24.27 94 - 0.03 305.459 304.555 0.30

1717 162.000 24.2600 24.2681 - 0.03 325.155 324.002 0 . 35

1718 164.000 24.2480 24.2583 - 0.04 344.921 343.438 0.43

1601 126.000 24.9960 24.9980 - 0.01 4.795 4.537 5.38

16 02 123.000 24.9600 24.9694 - 0.04 26.740 25.527 4.54

1603 130.000 24.9330 24.9432 - 0.03 48.275 47.339 1.94

16 04 132.000 24.9050 24.9106 - 0.02 69.442 68.700 1 . 07

1605 134.000 24.8790 24.8804 - 0.01 90.206 90.018 0.21

1606 136.000 24.6520 24.3520 0.00 110.901 110.907 - 0.01

16 07 138.000 24.8260 24.8248 0.00 131.487 131.645 - 0.12

1608 140.000 24.8010 24.7995 0.01 152.046 152.247 - 0.13

1609 142.000 24.7770 24.7762 0.00 172.619 172.724 - 0.06

1610 144 .

0

00 24.7540 24.7549 - 0.00 193.223 193. 090 0 . 07

1611 146.000 24.7340 24.7355 - 0.01 213.859 213.641 0.10

1612 148.000 24.7150 24.7184 - 0.01 234.593 234.110 0.21

1613 148.000 24. 7140 24.7182 - 0.02 234.564 233.966 0.25

1614 150.000 24.6970 24.7024 - 0.02 255.294 254.508 0.31

1615 152.000 24.6810 24.6330 - 0.03 276.024 274.994 0.37

1616 154.000 24.6660 24.6744 - 0.03 296.684 295.436 0.42

1617 156.000 24.6520 24.6620 - 0.04 317.346 315.842 0 . *7

1618 158.000 24.6390 24.6509 - 0.05 338. 030 336.224 0.53

1501 122.000 25. 3860 25.3842 0.01 3.482 3.731 - 7 . 14

1502 124.000 25.3480 25.3526 - 0.02 26.168 25.522 2.47

1503 126.000 25.3200 25.3233 - 0.01 48.814 * 8.346 0 . 96

1504 128. 000 25.2930 25.2888 0.02 70.363 70.960 - 0.85

15 05 130.000 25.2660 25.2590 0.03 92.218 93.236 - 1.10

15 06 132.000 25.2390 25.2312 0.03 114.039 115.186 - 1 . 0 1 1507 134.000 25.2120 25.2050 0.03 135.786 136. 823 - 0 . 76

15 08 134.000 25.2110 25.2052 0.02 135.814 136.675 - 0.63

1509 136.009 25. 1840 25.1784 0.02 157.173 158.007 - 0.53

1510 138.000 25.1600 25.1554 0.02 178.801 179.497 - 0.39

1511 140.000 25. 1370 25.1342 0.01 200.430 2 00.862 - 0.22

1512 142.000 25.1160 25.1152 0.00 222.144 222.271 - 0.06

1513 144.000 25.0970 25.0978 - 0.00 243.865 243.739 0.05

1514 146.000 25.0800 25.0823 - 0.01 265.643 265.283 0.14

1515 148.000 25. 0640 25.0684 - 0.02 287.462 286.764 0.24

1516 150.000 25. 0490 25.0558 - 0.03 309.282 308.192 0.35

76
METHANE EQUATION OF STATE

10 7pK MQL/L CALCD D,PCT P»BAR CALCD Pt 1517 152.000 25. 0350 25.0437 “ 0.03 330.987 329.578 0 1518 154.000 25.0220 25.0330 “ 0.04 352.726 350.934 0 1401 118.000 25.7770 25.7765 0.00 4.740 4.815 -1

1402 120.000 25.7390 25.7441 - 0.02 28.487 27.705 2 1403 122.000 25.7100 25.7116 - 0.01 51.614 51.564 0 1404 124.000 25.6820 25.6763 0.02 74.303 75.189 -1

1405 126.000 25.6540 25.6461 0.03 97.196 98.440 -1

1406 128.000 25.6250 25.6177 0.03 120.010 121.173 -o 1407 130.000 25.5980 25.5916 0.03 142.846 143.876 -0

1408 132.000 25.5740 25.5667 0.03 165 o 554 166.735 -0

1409 134.000 25.5500 25 . 5*41 0.02 188.320 189.280 -0

1410 136.000 25.5240 25.5232 0.00 211.062 211.196 -a 1411 138.000 25.5030 25.5043 • 0.01 233.855 233.643 0 1412 138.000 25.5030 25.5018 0.00 233.445 233.643 -0

1* 13 140.000 25.4640 25.4851 •0.00 256. 331 256. 151 0 1414 142.000 25.4660 25.4705 • 0.02 279.330 278.569 0 1415 144.000 25.4500 25.4566 - 0.03 302.209 301.081 0 1416 146.000 25.4350 25.4449 - 0.04 325.227 323.532 0 1417 148. 000 25.4220 25.4336 - 0 . 05 348.148 346. 107 0 1301 114.000 26.1420 26.1452 - 0.01 4.106 3.581 12

1302 116.000 26.1030 26.1118 - 0.03 28.896 27.421 5 1303 118.000 26.0720 26.0770 - 0.02 52.968 52.137 1 1304 120. 000 26. 0440 26.0406 0.01 76.358 76.926 -0

1305 122.000 26. 0140 26.0093 0.02 100.162 100.965 -0

1306 124.000 25.9650 25.9800 0.02 123.929 124 . 77 e -0

13 07 126.000 25.9560 25.9528 0.01 147 « 655 148. 211 -0

1303 128.000 25.9290 25.9273 0.01 171.338 171.625 -0

1309 130.000 25.9040 25.90 45 - 0.00 195.123 195.039 0 1310 132.000 25.8810 25.8837 - 0.01 218.955 218.474 0 1311 132.000 25.8800 25.8813 “ 0.01 218.534 218. 298 0 1312 134.000 25.8590 25.8626 - 0.01 242.441 241.772 0 1313 136.000 25. 8400 25 . 8*64 - 0.02 266.440 265. 306 0 1314 138.000 25.8220 25.3316 • 0.04 290.474 288.737 0 1315 mo. 000 25. 8070 25.8187 - 0.05 314.577 312.445 0 1316 142.000 25. 7920 25.3056 - 0.06 338.590 335.902 0 1201 110.000 26.5190 26.5185 0.00 5.935 6.027 -1

120 2 112.000 26.4800 26 . 48*5 - 0.02 31.839 31.022 2 12 03 114.000 26.4490 25.4451 0.01 56.444 56.963 -0

1204 116.000 26.4190 26 .*1

5 0.03 81.054 82.612 -1

12 05 113.000 26.3880 26.3734 0.04 105.870 107.625 -1

12 06 120.000 26. 3570 26 . 3*36 0.03 130. ©59 132.203 -1

1207 122.000 26.3270 26.3208 0.02 155.400 156.548 -0

1208 12* • 000 26.2990 25.2952 0.01 180 . 154 180 . 866 -0

12 09 126.000 26.2740 25.2719 0.01 204.975 205.366 -0

1210 128.000 26.2510 26.2511 - 0.00 229.892 229. 883 0 1211 130.000 26.2300 25.2325 - 0.01 254.906 254.436 0 1212 132.000 26.2110 25.2151 - 0.02 28 Q .025 279. 052 0 1213 134.000 26.1930 26.20 16 - 0.03 305.214 303.551 G 1214 13*. 000 26.1920 26.2003 - 0.03 304.967 303. 358 0 1215 136.000 26.1760 25.1875 " 0.04 330.135 327.952 0 1101 106.000 26.9010 25.9036 - 0.01 12.02

11.503 4

1102 103.000 26.8640 26 .8636 - 0.02 38.986 38.088 2 1103 113.000 26.8330 26. 8294 0.01 64.591 65 • 305 -l

PCI

.43

.51

.58

® 7 5 .48

.19

.28

. 97

.72

.71

.51

. 06

.09

.08

.07

.27

. 37

.52

.59

.79

.10

.57

.74

.80

.69

. 38

.17

.04

.22

. 11

.28

.43

.60

.68

.79

. 55

.57

.92

.92

, 66

. 1 8 .74

.40

.19

. 0 0

. 18

.35

• b 4 .53

.68

.32

.30

. 1 G

77
methane equation of state

10 T ,« MOl/L CAL 30 O.PCT P , BAR CALCC P»PCT

11 C4 112.000 26.8010 26.7934 0.03 90.300 91.804 - 1.67

1109 116.000 26.7680 26.7605 0.03 116.122 117.606 - 1 . 26

1186 116.000 26.7360 26.7297 0.02 141.871 143.133 - 0.69

14 07 118.000 26.7060 26.7013 0.02 167.653 168.602 - 0.57

ii ee 120.000 26.6790 26.6755 0.01 193.539 194.239 - 0.36

1109 112.000 26.6530 26.6524 0.00 219.542 219.665 - 0.06

1110 126.000 26.6300 26.6325 - 0.01 245.620 245.307 0.21 mi 126.000 26.6310 26.6318 - 0.00 245.678 245.510 0.07

1112 126.000 26.6106 26.6142 - 0.02 272.049 271.189 0.32

1113 128.000 26.5920 26.5987 - 0.03 298.510 297.133 0.46

111 A 130.000 26.5740 26.5850 - 0.04 325.020 322.744 0.70

1119 132.000 26.5590 26.5722 - 0.05 351.423 348.661 0.79

10 01 102.000 27.2320 27.2314 0.00 8.474 8.610 - 1.60

10 02 106.000 27.1920 27.1952 - 0.01 36.489 35.826 1.82

10 03 106.000 27. 1600 27.1546 0.02 63.034 64. 119 - 1.72

10 06 108.000 27.1270 27.1170 0.04 89.515 91.633 - 2.37

1009 110.000 27.0930 27.0827 0.04 116. 218 118.391 - 1.87

10 06 112.000 27.0600 27.0510 0.03 142.937 144.639 - 1 . 33

1007 116.000 27.0290 27.0214 0.03 169.612 171.216 - 0.95

1000 116.000 27.0010 26.9950 0.02 196.480 197.757 - 0.65

10 09 116.000 27.0010 26.9950 0.02 196.471 197.757 - 0.65

1010 118.000 26.9760 26.9717 0.02 223.568 224.491 - 0.41

1011 120.000 26.9520 26.9513 0.00 250.862 251.014 - 0.06

1012 122.000 26.9310 26.9333 - 0.01 278.278 277.779 0.18

1013 126. 000 26.9120 26.9180 - 0.02 305.898 304.595 0.43

1016 126.000 26.8950 26.9039 - 0.03 333.424 331.484 0.58

901 98.000 27.5880 27.5887 - 0.00 12.437 12.281 1.25

902 100.000 27.5480 27 . 55 0 8

- 0.01 41.407 40.777 1.52

903 102.000 27.5160 27.5084 0.03 68.696 70.418 - 2.51

906 106. 000 27.4810 27.4700 0.04 96.270 98.759 - 2.59

909 106.000 27.4470 27.4349 0.04 124.002 126.731 - 2.20

906 108.000 27.4130 27.4025 0 . 04 151.755 154.136 - 1.57

907 110.000 27.3820 27.3730 0.03 179.649 161.681 - 1.13

908 112.000 27.3530 27.3470 0.02 207.794 209.167 - 0.66

909 116.000 27.3280 27.32 39 0.01 236.148 237.075 - 0.39

910 116.000 27.3050 27.3040 0.00 264.752 264.979 - 0.09

911 116.000 27.3050 27.3046 0.00 264.894 264.979 - 0.03

912 118.000 27.2850 27.2871 - 0.01 293.612 293.133 0.16

913 120.000 27.2660 27.2716 - 0.02 322.446 321. 104 0 . 42

801 96.000 27.9000 27.9017 - 0.01 7.513 7.112 5.34

802 96.000 27.8580 27.8623 - 0.02 37.517 36.483 2.76

803 98.000 27.8250 27.8176 0.03 65.517 67.284 - 2.70

806 100.000 27.7890 27.7780 0.04 94.061 96.685 - 2.79

805 102.000 27.7530 27.7416 0.04 122.725 125.437 - 2.21

806 106.000 27.7190 27.7078 0.04 151.383 154.048 - 1.76

807 106.000 27.6860 27.6773 0.03 180.222 182.310 - 1 . 16 608 108.000 27.6570 27.6502 0.02 209.351 210.970 - 0.77

809 110.000 27.6300 27.6265 0.01 238.728 239.577 - 0.36

810 112.000 27.6070 27.6060 0.00 268.394 268.642 - 0.09

811 116.000 27.5860 27.5893 - 0.01 298.261 297. 711 0.18

812 116.000 27.5670 27 .5733 - 0.02 328.347 326.813 0.47

601 92.000 28.2090 29.2134 - 0.02 44.123 42.993 2.56

602 96.000 28. 1750 23.1666 0.03 72.852 74.997 - 2.94

603 96.000 28.1370 29.1264 0.04 102.543 105.236 - 2.63

606 98.000 28. 1010 26.0835 0.04 132.353 135.280 - 2.21

605 100.000 28. 0660 28. 0553 0.04 162.160 164.904 - 1.68

6 06 100.000 28.0660 28.0553 0.04 162.190 164.904 - 1.67

607 102.000 28.0340 28 . 02+5 0.03 192.243 19 + . o 52 - 1.25

608 106.000 28.0040 27.9977 0.02 222. 687 224.300 - 0.72

609 106.000 27. 9780 27.9747 0.01 253.551 254 . 38 e - 0 . 33 610 108.000 27.9560 27.9548 0.00 264 . 6<«1 284.693 - 0.02

611 110.000 27.9350 27.9330 - 0.01 316.018 315.247 0.24

612 112.000 27.9160 27.92 36 - 0.03 347.527 345.568 0.56

701 96.000 28. 3910 28.3734 0.04 126.133 131.226 - 2.41

7 02 96.000 28.3540 28.3437 0.04 158.893 lo 1 . 640 - 1.73

703 98.000 28.3210 29.3115 0.03 189. 866 192.421 - 1.33

706 100.000 28.2900 29.2 835 0.02 221. 336 223. 072 - 0.78

7 05 102.000 28.2660 29.2595 0.02 253.222 254.422 - 0.47

706 106.000 28.2400 29.2390 0.00 285.440 285.706 - 0.09

707 106.000 28.2190 29.2221 - 0.01 318.049 317. 229 0 . 26

7 08 108.000 28.2000 29.2069 - 0.02 350 .566 348 . 7 5 G 0.52

516 96.500 28.5520 29.5508 0.00 224.938 225.257 - 0.1 + 515 97.000 28.5450 23 . 5++3 u . 0 0 233. 128 233.308 - 0.08

516 98.000 28.5310 29.5323 - 0.00 249.643 249. 285 0.14

517 100.000 28.5070 28.5136 - 0.01 262.843 281.861 0.35

518 100.000 28. 5070 29.5109 - C .01 282.935 281.861 0 . 38 519 102.000 28.4860 28.4924 - 0.02 316.433 314. 651 0. 56

520 106.000 28.4660 29 .4767 - 0.04 350.093 347.134 0.85

NP = 554 , ONKMSPCT = 0 . 194 , P 9 EANPCT = 0.497

78
Table 5. Comparison of specific heats for saturated liquid, J /(mol • K)

10 T,K CS 4 T CfeLC PCNT

201 95 ©4 0 2 54.240 53,240 1.64

401 95.346 54.131 53.307 1.52

202 99.021 54.647 53.833 1.49

302 101.651 54.877 54.300 1.05

402 101.961 54.790 54.396 0.79

203 102.574 54.896 54,469 0.79

204 106.891 . 55.602 55.204 0.72

303 108.219 55.583 55.417 0.30

403 108.600 95.315 55.507 - 0.35

2 09 112.604 § 6.075 56.066 @.02

304 115.165 56.434 56.410 0.04

206 119.117 56.810 56.922 - 0.20

305 122.474 57.237 57.365 - 0.14

405 123.367 56.996 § 7.486 - 0.86

207 125.766 57.645 57.839 - 0.33

406 130.765 58.245 58.673 - 0.73

20 ® 132.274 58.774 58.964 - 0. 32

10 01 132.751 58.879 59.860 - 0.31

902 135.455 58.930 59.643 - 1.21

1002 137.805 59.729 60.206 - 0.80

903 139.970 59 . 69 ® 60.770 - 1.80

@01 144.305 60.560 62.029 - 2.43

904 144.401 60.929 62.059 - 1.85

802 148.500 62.033 63.402 - 2.21

905 148.831 62.005 63.534 - 2.47

1003 150.824 64.014 64.224 - 6. 33

@03 152.809 63.898 64.962 - 1.67

906 153.157 64.

48 65.096 - 1.64

1004 155.542 65.246 66.840 = 1.22

804 157.043 65.435 66.668 - 1.88

90 r 157.355 65.569 66.802 - 1.88

1005 159.127 66.905 67.593 - 1.03

805 161.181 67.733 6 ® •

83 - 1.25

908 161.483 67.898 68.737 - 1.24

13 06 163.136 68.379 69.622 - 1.82

402 163.782 69.936 69,992 - 0.08

407 165.128 70.865 70,813 0.07

806 165.249 70.534 70.891 - 0.51

909 165.548 70.745 71.985 - 0.48

1007 166.549 71.756 71.768 - 0.02

807 169.253 73.960 73.918 0.06

910 169.565 74.411 74.201 0.28

220 170.157 74.696 74.762 - 0,09

100 ® 170.197 75.369 74.801 0.75

40 ® 170.251 75.575 74. 854 0.95

403 171.097 76.320 75.721 0.79

@08 173.180 78.540 78.212 0.42

911 173.480 79.194 78.619 0.73

701 173.505 78.678 78.654 0 . 03

216 174.032 79.623 79.406 0.27

1009 174.429 81.334 80.094 1.64

409 175.228 @ 2.128 81.734 0.48

404 176.295 64. 253 83.641 0.73

8 09 177.029 85.466 @ 5.096 0.43

221 177.420 @ 7.382 85.925 1 o 67

702 177.902 @ 6.730 @ 7.003 - 0.25

UIQ 178.557 @ 8.641 88.579 0.07

200 180.613 95.067 94.560 8.53

217 181.034 36.349 96*028 0.33

703 181.645 98.844 98.346 0,50

1011 182.572 103.442 102.372 1.03

222 184.222 113.330 111.643 1.49

704 185.271 121.769 119.693 1.71

201 186.127 132.153 128.276 2.93

1012 187.577 141. 359 150.568 = 6.51

2 16 187.633 156.489 151.752 3.03

79
10

2209

2203

2210

2204

2211

2212

2205

2206

2213

220 7 2214

2208

2216

2 218

1505

1506

1502

1507

1503

1504

1508

1509

1510

1511

1512

1513

1514

1515

1517

1518

1519

219

223

2 24

2 25

205

226

206

227

207

2 28

208

229

209

210

211

212

214

301

302

303

Table 6. Comparison of specific heats C (P, T), J/(mol • K)

v

T,K P,BAR MOL/L C, XPTL C > CALC PCNT

200.342 56.917 7.991 35.351 34.277 3. 04

201.339 58.027 7.991 35.004 33.907 3. 13

207.854 65.217 7.988 33.153 32.179 2.94

208.168 65.562 7.988 33.141 32.116 3.09

215.402 73.451 7.984 31.732 30.992 2.33

222.937 81.598 7.980 31.046 30.243 2. 59

22 2.993 81.658 7.980 31.059 30.239 2.64

230.373 89.583 7.977 30.698 29.757 3. 07

230.454 89.670 7.977 30.381 29.753 2.07

237.534 97.229 7.973 30.419 29.448 3. 19

238.128 97.862 7.973 30.198 29.428 2. 55

244.733 104.881 7.970 30.045 29.252 2. 64

252.790 113.406 7.966 28.913 29.136 -0.78

266.349 127.671 7.959 29.785 29.135 2.16

195.780 53.853 10.176 39.325 36.351 7. 56

202.601 54.048 10.171 ' 34.818 33.263 4.41

203.142 64.857 10.171 34.032 33.142 2.61

209.526 74.426 10.166 32.879 31.911 2.94

209.853 74.915 10.166 33.020 31.864 3. 50

216.813 85.365 10.161 32.185 31.052 3.52

216.467 84.845 10.161 31.750 31.085 2.09

223.396 95. 256 10.157 31.318 30.266 3. 36

230.790 106.373 10.151 30.432 29.784 2. 13

237.756 116.844 10.147 29.996 29.492 1.69

244.636 127.181 10.142 29.857 29.316 1. 81

251.488 137.466 10.137 29.650 29.226 1.43

259.403 149.331 10.131 29.632 29.207 1. 44

266.154 159.433 10.126 29.560 29.249 1. 05

282.516 183.843 10.114 29.922 29.528 1. 32

289.146 193.696 10.110 29.964 29.699 0.89

295.822 203.596 10.105 30.170 29.899 0.90

195.627 55. 318 11.838 37.165 34.952 5. 95

196.581 57.055 11. 839 36.177 34.474 4. 71

203.924 70.601 11.832 33.223 32.299 2. 78

211.370 84.550 11.826 31.908 31.207 2.20

215.626 92.584 11.822 31.148 30.790 1. 15

218.787 98.572 11.819 30.922 30.540 1. 24

223.653 137.819 11.815 30.609 29.963 2. 11

226.191 112.653 11.813 30.347 29. 800 1. 80

231.675 123.117 11.808 30 .155 29.527 2.08

233.566 126.729 11.806 30. 130 29.454 2. 24

239.625 138.319 11.801 30.043 29.279 2. 54

240.923 1*0.803 11.800 29.653 29.252 1. 35

248.734 155.751 11.792 29.604 29.153 1.52

257.453 172.459 11.784 29.534 29.151 1. 30

266.957 190.643 11.775 29.632 29.25C 1.29

276.534 208.934 11.766 29.702 29.436 0. 90

296.364 246.647 11.748 30 .0 98 30.032 0.22

204.751 77. 746 13.088 32.393 31. 334 3.27

212.016 93.924 13.080 31.485 30.569 2.84

219.265 110.2*2 13.073 30.868 30.106 2.47

80
10

304

305

306

3or

309

310

313

314

311

312

501

526

502

5 20

503

521

504

5 22

505

523

506

524

507

508

525

509

510

511

514

512

515

513

516

517

1601

1602

1603

1604

1618

1605

1606

1607

1608

1619

1620

1609

1611

1610

1622

1612

1623

Table 6. Comparison of specific heats Cv (p,T), J/(mol • K) (continued)

T »K P f BAR MOL/L C, XPTL G»CALC PC NT

226.524 126.697 13.065 30.478 29.,480 3.2®

234.072 143.881 13.057 30.165 29,,211 3. 16

241.245 160.256 13.050 29.985 29,,077 3, 03

248.387 176.580 13.042 29.965 29,> 0 34 3. 11

262.566 208.937 13.026 29.91® 29,,148 2. 58

276.780 241.398 13.011 30.309 29,,458 2.81

276.944 241.772 13.010 30 .114 29., 463 2. 16

283.783 257.318 13.003 30.147 29.,668 1. 59

290.591 272.756 12.995 30.375 29.,901 1. 56

297.427 238.216 12.987 30.687 30,, 161 1.71

191.539 52.228 14.388 34.042 32,,384 4.87

195.039 61.226 14.383 32.765 31.,654 3. 39

198.638 70.602 14.379 32.000 31.,120 2.75

200.323 75.028 14.377 31 . 860 30,,919 2.95

205.816 89.577 14.371 31.171 30,,405 2.46

208.733 97.366 14.366 30.940 30., 196 2.41

212.954 108.696 14.362 30.585 29,,949 2. 08

217.103 119.884 14.356 30.292 29.,757 1.77

220.066 127.901 14.353 30.152 29,,434 2. 38

225.394 142.360 14.346 30.0 32 29,,195 2.79

227.167 147.180 14.344 30.067 29.,135 3. 10

234.287 166.574 14.334 29.826 28,,969 2. 87

234.417 166.928 14.335 29.805 28.,967 2. 81

241.372 185.902 14.326 29.647 28,,903 2. 51

242.493 186.962 14. 324 29.585 28.,900 2. 32

248.293 204.731 14.317 29.485 28,,913 1.94

255.197 223.622 14.308 29.500 28.,983 1.75

262.143 242.543 14.299 29.656 29.,103 1. 86

265.537 251.779 14.294 29.681 29,,178 1.70

269.538 262.650 14.289 29.689 29,,278 1. 38

273.495 273.386 14.284 29.885 29,,390 1. 66

277.494 284.223 14.278 29.877 29.,514 1.22

281.439 294. 892 14.273 30.064 29.,646 1. 38

289.349 316.229 14.262 30.557 29,, 940 2.02

185.501 42.477 16.036 32.608 31,,345 3.8?

187.587 *9.323 16.035 32.198 30.,994 3. 74

189.591 55.934 16.032 31.832 30,,727 3.47

191.595 62.532 16.029 31.732 30.,506 3.86

192.871 66.824 16.024 31.410 30,,384 3. 27

193.605 69.272 16.026 31.163 30., 319 2.71

195.615 75.989 16.023 31.041 30,,158 2.85

197.622 32.719 16.020 31.157 30.,018 3.66

199.628 39.464 16.017 30.831 29,,895 3. 03

200.331 90.821 16.011 30.746 29., 872 2. 84

209.230 121.946 15.996 30.246 29,,476 2.54

217.884 151.399 15.986 29.793 29. 255 1. 81

223.224 169.616 15.977 29.830 28,,908 3. 09

223.903 171.930 15.976 29. 834 28. 890 3. 16

229.421 190.764 15.964 29.842 28,,7 87 3. 53

229.453 190.871 15.967 29.795 28. 787 3. 38

239.424 224.878 15.948 29.681 28,,745 3. 15

81
ID

1613

1614

1615

1616

1617

1625

701

707

721

702

708

720

703

709

704

710

711

705

711

706

713

714

715

716

717

718

719

1309

1301

1310

1302

1311

1303

1323

1312

1304

1324

1305

1313

1325

1306

1314

1326

1327

1317

1318

1319

1320

1321

1322

411

Table 6. Comparison of specific heats C v (p,T), J/(mol • K) (continued)

T *K P» BAR MOL/L C, XPTl C » CALC PC NT

241.503 231.959 15.948 29.748 28.756 3. 34

247.521 252.433 15.939 29.715 28.816 3. 03

253.443 272.535 15.929 29.742 26.914 2.79

259.333 292. 473 15.919 29.669 29.044 2. 76

265.198 312.270 15.910 29.856 29.203 2. 19

269.447 326.572 15.901 29.942 29. 335 2. 03

187.947 51.079 16.103 32.040 30.863 3. 67

188.669 53.489 16.102 31.992 30.768 3.63

191.577 63.234 16.097 31.546 30.447 3.46

195.118 75.175 16.092 31.068 30.147 2.96

195.637 76.929 16.091 31.042 30.109 3. 00

199.140 88.817 16.086 30.673 29.865 2.57

202.277 99.538 16.081 30.672 29.722 3. 10

202.632 110. 720 16.080 30.443 29.706 2. 42

209.408 123.921 16.070 30.206 29.447 2. 51

209.569 124.473 16.070 30.260 29.442 2. 70

216.494 148.281 16.059 29.913 29.266 2.16

216.509 148. 334 16.059 29.877 29.266 2. 05

223.352 171. 908 16.048 29.807 28.892 3. 07

223.900 173.795 16.047 29.782 28.878 3. 03

230.437 196. 326 16.037 29.642 26.767 2. 95

237.251 219. 796 16.026 29.731 28.736 3. 35

244.048 243. 173 16.015 29.596 28.773 2. 78

250.777 266.259 16.004 29.629 26.865 2. 58

257.424 288.998 15.993 29.692 29.000 2.33

264.035 311.538 15.982 29.946 29.173 2.58

270.623 333.917 15.971 29.851 29.379 1.56

184.764 45.449 16.723 31.721 30.621 3. 47

187.826 56.698 16.717 31.357 30.298 3. 36

190.103 65.099 16.714 31.150 30.108 3. 34

194.733 82. 255 16.706 30.685 29.808 2. 86

195.445 84.904 16.706 30.679 29.769 2.97

201.094 135. 956 16.696 30.196 29.518 2. 25

202.937 112.841 16.693 30 .239 29.452 2.60

206.062 124.532 16.688 30.204 29.357 2.81

206.122 124. 756 16.689 30.023 29.355 2. 22

208.580 134.336 16.683 30 .164 29.289 2. 96

210.401 140.788 16.681 29.682 29.250 2. 11

211.348 144.339 16.679 29.987 29.230 2.52

214.143 154. 818 16.674 29.847 29.179 2. 24

215.024 158. 123 16.673 29.840 29.164 2.26

216.658 164.252 16.670 29.924 29. 140 2.62

219.582 175.218 16.665 29.727 29. 103 2. 10

225.003 195.545 16.655 29.749 28.775 3.27

232.337 223. 039 16.643 29.585 28.703 2.98

237.557 242.891 16.633 29.651 28. 707 3. 18

243.097 263.174 16.624 29.802 28.752 3.52

248.519 283. 339 16.614 29.686 28.832 2. 88

253.921 333. 370 16.604 29.831 28.940 2.99

259.304 323. 264 16.595 29.913 29.075 2. 80

187.325 58.459 17.007 31. 221 30.119 3.53

82
10

*01

406

413

414

*15

416

4ir

416

419

1601

16 02

1603

1604

1805

1606

1807

1808

1809

1810

1811

1812

1709

1710

1701

1711

1702

1712

1703

1713

1704

1714

1705

1715

1706

1716

1707

1717

1708

807

801

808

802

809

810

803

811

804

812

805

813

806

Table 6. Comparison of specific heats C v (P,T), J/(mol • K) (continued)

T,K P,3AR MOL/L C, XPTL C » CALC PC NT

193 .924 83.993 16.997 30.513 29.705 2. 65

196 .587 94. 337 16.992 30.399 29.583 2.68

203 .953 123. 025 16.978 30 .119 29.332 2.61

211 .986 154. 390 16.964 30 . 0 33 29. 160 2. 91

219 .901 185.282 16.950 29.782 29. 063 2.41

227 .768 215.952 16.936 29.698 28.715 3. 31

235 .598 2*6.397 16.922 29.743 28.693 3.53

2 45 .293 283.931 16.904 29.635 28.786 2.87

252 .926 313.338 16.890 29. 667 28. 932 2.48

176 .581 37.972 18.086 31.280 30.072 3. 86

181 .649 51.836 18.080 30.991 29. 854 3.67 186 .224 72. 545 18.068 30.598 29.610 3. 23

192 .299 13 0. 083 18.056 30 • 377 29. 382 3. 28

198 .354 127.540 18.044 30.090 29.225 2.87

204 .379 154.828 18.032 29.958 29.119 2. 80

210 .370 131.915 18.019 29.803 29.050 2.53

216 • 641 210.187 18.006 29.741 29.010 2. 46

222 .620 237.053 17.994 29. 812 28.747 3.57

228 .488 263. 318 17.982 29.742 28. 698 3.51

234 • 30* 289.242 17.970 29.683 28.708 3. 28

240 .990 318.901 17.955 29.841 28.778 3.56

172 .603 *0.332 19.500 30.6 37 29.495 3.73

178 .550 73.*39 19.486 30 . 586 29. 587 3. 27

181 • 613 90.419 19.479 30 .306 29.476 2.74

164 .637 137.182 19.472 30.262 29.386 2.89

187 .628 123.725 19.465 30.094 29. 317 2. 58

190 .660 1*0.564 19.457 30 .082 29.257 2.74

193 • 6*~0 156. 857 19.450 30.021 29.210 2. 70

196 .653 173.622 19.443 29.980 29.171 2.70

199 .616 189.630 19.435 29.918 29. 141 2. 60

202 .661 236. 260 19.428 29.976 29.117 2.87

205 .563 222.086 19.421 29.798 29. 100 2. 34

208 .615 238.633 19.413 29.854 29.089 2, 56

211 .46 0 254.140 19.406 29.844 29.0 84 2.55

214 .522 270. 555 19.398 29.783 29.084 2. 35

217 .573 286.970 19.391 29.752 29. 089 2. 23

220 .387 302.058 19.384 29.837 28.882 3. 20

223 .411 318.216 19.376 29.789 28.850 3. 15

161 .140 39. 3 94 21.312 30.545 30.771 -0.74

165 .189 6 8.455 21.298 30.567 30.409 0. 52

166 .828 8C.175 21.295 30.509 30.231 0.91

171 .921 116. 3^4 21.278 30.496 29.683 2.67

172 .486 120.333 21.278 30.337 29.633 2.32

178 • 091 159. 8*5 21.261 30.308 29.803 1.67

178 .582 163. 284 21.257 30 . 276 29.788 1.61

183 .6*0 198.575 21.244 30.225 29.661 1. 87

185 .182 239.280 21.237 30.195 29.631 1. 87

189 . 1 5 3 236.719 21.227 30.237 29.566 2. 21

191 .734 254.462 21.217 30 .176 29.536 2. 12

194 .626 274.250 21.210 30.230 29.507 2. 39

198 .229 298.774 21.197 30 .140 29.480 2. 19

83
ID 814

2109

2101

2102

2103

2104

2105

2103

2107

2108

1406

1407

1402

1401

1408

1403

1409

1404

1410

1405

2001

2002

2 J 03

200 * 20 05

2 J 05

2007

901

909

9 04

902

910

903

911

9 06 912

907

913

908

1201

1202

1203

1204

1101

1103

1106

1102

1107

1104

1108

1109

1105

1304

1301

1305

1002

13 06

1 J 03

1 J 07 1912

1901

19 07 13 02 1913

1 308

1903

1909

1904

1913

1305

1911

19 06

Table 6. Comparison of specific heats C (p,T), J/(mol • K) (continued)

T»K P 9 BAR MOL/L C» XPTL C,CALC PC NT 200.378 311.300 21.192 30 . 110 29.469 2. 13

153.984 30.846 22.126 31.040 31.271 -0.75

157.876 62. 103 22.113 30. 931 31.219 -0. 93

162.200 96.526 22.098 30.800 30.966 -0.54

166.497 130.432 22.083 30 .832 30.544 0,93

170 .767 163.847 22,069 30.716 30.070 2.10

175.011 196.789 22. 054 30-567 30.193 1 . 22

179.314 229.914 22.040 30.615 30.038 1.88

183.514 2o 1. 982 22.025 30.432 29.933 1.64

187.701 293.689 22.011 30.468 29.856 2.01

148.828 44. 459 22.933 31.314 31. 549 -0.75

155.536 104. 131 22.907 31.098 31.680 -1.87

155.969 107.942 22.906 31. ICO 31.674 -1.84

156.936 116.449 22.900 31.042 31.653 -1.97

162.130 161.805 22.883 30.958 31.364 -1.31

162.555 165.498 22.081 30-925 31. 328 -1. 30

168.648 217.963 22.858 30.923 30.678 0.79

169.076 221.618 22.856 30.826 30.628 0.64

175.122 272.935 22.834 30.798 30.550 0 . 61

175.530 276.347 22.832 30 . 898 30.531 1. 19

139.073 45. 399 24.008 31.796 31. 731 0. 20

143.270 88.569 23.990 31.655 31. 988 -1. 05

147.448 130.924 23.972 31.612 32.213 -1.90

151.599 172.491 23.954 31. 437 32. 352 -2. 91

155.908 215.104 23.935 31.550 32.348 -2. 53

160.011 255.209 23.917 31.258 32.165 -2. 90

164.072 294. 445 23.900 31 . 267 31. 81C -1.74

130.508 34.766 24.785 32.662 31.993 2. 05

131.693 48. 379 24.772 32.454 32. 041 1.27

132.694 59.842 24.767 32.479 32. 083 1.22

1 34.136 76.278 24.761 32.166 32.148 0 . 06

137.159 110.410 24.746 32.080 32.294 -0.67

139.337 134.756 24.735 31.949 32.408 -1. 44

142.547 170.300 24.720 31.911 32.580 - 2 . 10

143.713 183.112 24.715 31.964 32.641 - 2 . 12

147.886 226.554 24.695 31.785 32. 830 -3.29

149.124 241.915 24.689 31.732 32.871 -3.59

153.185 285.371 24.670 31.728 32.933 -3. 80

154.473 299. 029 24.664 31.839 32.924 -3.41

121.160 64.484 25.872 33.145 32.926 0.66

124.223 134.694 25.855 32.958 33.003 -0. 14

127.262 144.001 25.838 32.757 33.065 -0.94

130.274 182.414 25.822 32.691 33. 13C -1. 34

110.867 44. 963 26.655 33.910 33.413 1. 47

111.855 59.603 26.649 33.724 33.496 0.68

111.917 60.514 26.649 33.789 33.501 0.85

116.030 120.523 26.624 33.557 33.746 -0.56

117.051 135.131 26.618 33.478 33.786 -0.92

122.089 206. 386 26.588 33.415 33.898 -1.45

122.094 236.453 26.588 33. 311 33. 898 -1.76

127 .100 275.451 26.559 33.180 33. 942 -2. 30

127.123 2'' 5. 769 26.558 33.210 33. 942 -2. 20

102.424 48.414 27.388 34.428 33.505 2.68

105.029 90.948 27.371 34.267 33. 8 8

C

1.13

107.466 129.912 27.355 34.129 34.170 -0. 12

110.058 170.735 27.338 34.049 34.411 -1. 06

112.446 207.806 27.322 34.035 34.573 -1.58

115.1*2 249. 0 13 27.305 33 . 999 34.694 -2. 04

117.361 282. 491 27.290 33.879 34.751 -2. 58

92.592 40. 274 28.164 35- 326 33. 339 5.63

92.609 40.540 28.164 35.415 33. 34C 5. 86

93.793 52.334 28.155 35.186 33.492 4. 81

95.465 92.859 28.143 35.003 33.731 3.63

95.634 95.385 28.141 35. 020 33.756 3. 61

96.675 114.525 28.134 34.898 33.913 2. 82

98.301 143. 313 28.122 34.913 34.161 2. 15

99.5C5 134.435 28.114 34. 830 34.344 1 . 40

101-123 132.506 28.102 34.839 34.580 0 . 74

102.319 213. 035 28.C93 34.710 34.746 -G. 10 103.902 2 + C. 3 32 28.082 34. 793 34. 946 -0 . 45

105.104 250. 314 28.074 34.630 35. C 87 -1. 41 10b. 655 236.252 28.063 34.644 35.247 -1.74
Table 7. Comparison of specific heats C (P,T), J/(mol • K)

P

P, BAR * T, K 10.36 20.68 26.13 31.03 37.92 61.37 63.09 66. 88 55.16 68.95 82. 7* 103.42 137.90

11b . 483 55.62

56.56

55.36 56.36 55.36

56.27 55.2956.13 55.22

55.99

55.16

55.93 55.0955.89

55.09

55. 82 55.0255.67

5*. 15 55.63

56.69

55.21 54.5554.90 54.01

54. 44 122.039 56. 57 57.35

56.30 57.0856.63 56.9956. 30 56.81 56.16

56.65 56.0356.57

55.96

56.53

55.96

5 0.66 55.63

56.26 55.5955. 97 55.62

55.70 54.6955.32 54.35

54.77

127.591* 57.91

58.26 57.51 57.93 57.66

57.82

57.37

57. 61 57. 06 57.60 56.97 57.30

56.90 57.25

56.77 57.1556.50 56.92

56.37

56.57

56.03 56.2655. 36 55.60 54.75 55.15

133.150 59.39

59.69 58.78

59.06

58.58

56.90

58.38

58.63 58.06

58.37

57.91 58.2557.78 58.1957.71 58.0557.31 57.78

57.10

57. 35 56.7056.95 55.96

56.h2 55.16

55.64

1 39 • 706 61.16

61.07 60.13

60.69

59.93

60.31

59.66

59. 96 59.6659.63 59.19

59.67 58.99

59.39

58.85

59.23

58.52

58.88 57.8658.35

57. 37 57.67

5o.57

57. 22 55.5660. 31

l"** .261 63. <*2 63.11 61.76

62.33

61.61 62.08

61. 00 61.62

60.53

61.20 60.6060.99

60. 19 60 .896 0.06

6 0.68 59.72 60.26

58.85

53.58

58.11

58. 38 57. 37 58.20 56.10

57.11 149.817 63.76

0 4.50 63.6966.27

62. 88 63.66 62.16

o3. 07 61.61 62.79

61.67

62.66

61.27

62. 38 60.93

61.81

53.79

60- 36 59.1260. 21 58.25

59.25 56.70

57. 94 155.372 62.12

62. 90

6 6.58

67. .*7 66.3866.97

65.23

66.07

66. 16 65.26 63.89

66.88 63.6266. 70 63.08

66. 32 62.61 63.55

61.20 62.63

60.26

61.47 59.32 60.26 57.51 58.68

160.928 60.51

61.26

71.35

71.37

69. 87 70.57

68. 59 69.16

67. 05 67.9666.91 67.39

69 > 38 67.13

65.50 66.58 66.63

65.50 63.38 63.37

bl.76

62.71

6 0.53 01.17 66.45

59.23

166. <*83 39. 37 60.07

76.05

76. 19

73. 77 73.70

71.62 71.68 70.96

70.80

70 .68

70. 39 63.2069. 56 68.32 67.93

65.'7 65.76

6 3.62 66.06

62.01 62.04 59.52 59.63

172. 039 38. 56 39.16 55.69

56.61 82.83 81.89

78.96

77.96

77.66

76.35 77.1975.62

75.71

76. 17 73.09

71.56

63.67 68.26

66.44

65.83

63 . 62 63.15 60.73

60.11 177.596 38. 02 38.66 50.65

69.85 58.1857.71

106. 08 102.60 93.72 91.3289.08 87.6287 .96

86 . 06 86.58

83.07

80.21 78.1776. 37 72.75

69.73 69.13

65.43 65.43 62.01

61.52 183.150 37.62

37. 90 67.36

66.82 52.76

52.06

75.06

73.65 132.66

133. 18 116.61115.88

109.37 110.17102.92

101.07 89.75

89.28 81.09

73.06

74.30

73.28 67.79

67. 36 63.49

62.87 168.706 37.29

37.65 66.9666. 70 69.2668.53

62.01

61.26

100.26 97.16166.66

170.71

352.17 382.68186.68

175.33 115.62116.30

90 . 30 83. *2 8O.48

79.24 70.81 71.28 65.0364.52 196.261 37. 02 37. 09 63.26

63.15 66.6966.11

56.95

56.83

73.30 72.02 91.50 89.26101.18

103.10 193.21 168.97

260.85

263.30 107.09108.31

88.58

88.15 75.18 75.59 66.85

66.50

35
Table 7. Comparison of specific heats C

p(o,T), J/(mol - K) (continued) p,a*« * T, K

10. 34 20. o8 24. 13 31. 03 37. 92 41.37 43. 09 46.88 55.16 68.95 82.74 103.42 137.90

199.817 36. 75 36. 79 41.12

41. 16 44.6844. 35 50.79

50.83

62.01 61.5271.82

70.01 77.3375.62

9-* . 46 93. 36 231.4*. 212.17

148. J 7 156.29

102.25

102.21

81.76 81.18 68.86 68.79 205.372 36.55

36.55 40.55 41.03

43.13

43.01

47.90 48.09

55.76 55.5961.94

60.87 65.64

64.07

75.38 72.99111.05

108.18

194.33

192.83

123.01 124.8990.49

88. 33 70.9471.41 210.928 36.41 36.36 40.04 40.29

41.79

41.96

45.82

46. 09 51.60 51.75 55.6355 . 44 58.2557.57

64.96 63.1484.31

81.34 139.00140.24

138.46

142.21 97.8896.93 73.5674.27

216. <83 36.28

36.20

39.37 39.69 40.85 41.13

44.27 44.5848.77

49. 05 51.6051.82

53.28

53.37

57. 98 57.2769. 94 68.78103.26

100.30

127.71

123. 58 103.12 104.69

76. 18 77.23

222. 039 36.08 36.08

38.90

39.21

40.11 40.46

43. 13

4 3 1> 4 0 46.69

47.05

48.91 49.24

50 . 18 50 . 43 53.28

53. 36 61.74

61 .46

85. 32 81..7 105.34

10.4. 75 103.66104. 49 79.0179.72 227.594 36.01

36.00

38.5 0 38.81 39.57 39.92

42. 19 42.47

45.08

45.53 46.8947.31

47.77

48.27

5 0. 32 50.57

56.50 56.6674.10 70.668 7.94 87.75

97.68 96.00 81.22

81.58 233.150 35. 94 35.94 38.23

38.49 39.10 39.49

41. 38 41.7244. 00 44.3345.48 45.8246.29

46.61

48. 03 48. 49 53.07 53.29

65. 77 63.74

76. 52 76.3288.21

87. 83 80.89

81.91 238. 706 35.94

35.90 37.16

38.24

38.76

39.13

40.78

41. 11 43.0643. 38 44.27 44.65

45.08 45.3246.42

46.89 50.79

50.80 59.6658.97

68.3b

68.04

79. 48 80.65

78.87 80.17 244.261 35.88

35. 89 37.76

38.03

38.50 38.84 40.24

40.61

42.26

42.61 43.4043.71

43. 74 4*. 29 45.41

45.62

48.44

48 . 39 55.5655.50

0 3 . 22 63.20

72. 35 73. 90 76.32 76.74

2*9. 817 35. 94 35.90

37.62 37.88 38.29

38.61

39. 84 40.21 41.59

41.99 42.7342.95

43. 13 43.4644.34

4<» . 62 46.96

47.40 52.74

52.89

59.05 59.19bo . 78 68. 30 73.36

73.03 255.372 35. 94 35.93

37.55

37.76 38.16

38.43

39.57

39. 89 41. 12 41.48 42.0642. 34 42.3942. 78 43.4743. 80 45.08 46.22

50 .65 50.97

55.83 56.13 62.34

63.91 70.14 69.75 260.928 36.01

35.98 37.493 7.58 38.0238.30

39. 37 39.6340.78 41.07 41.59

41 . 84

41 . 79 42.23 42.79

43.14 44.94

45.26 43.1143.27

53. 34 53.74

58.92 60.44 67.05 66.88

266.483 36. 08 36.0537. <.2 37.53

37.96

38.20

39. 17 39.424 0.44 40.74 41.05

41.43

41 . 38 41.79

42.19

42.60 44.27 44.48 47.83

47 . 98 51.3951.85

56.43

57.68 64.0964.29 272.039 36. 14 36. 13 37.42

37.61 37.8938.14

39.03

39.27

4 0.24

4 0.47 40.7841.10 41.0541.43

41.85

42.16

44.00

43.84 46.89

46. 94 49.98

50.32

54.55 55.45 61.54

61.86 277.594 36.21, 36.23 37.^2

37. b2 37.89

38.11

38.97

39. 16 40 . 17 40.26 40.64

40.84

40.85

41.14

41.59

41.80 43.60

43.32 46.02

46.0 9 48.91 49.08

53. 14 53.o3 59.46 59.65 283.150 36.28

36.34 37.35

37. j5 37.8238.11

38.90 39.0840.11

40.10 40.51

40. 6*

40. 78 40.91 41.52

41.52

42. 33 42.90 45.48 45.39

48.03

48.06

52.07

52. 13 57.78 57.72

86
Table 8. Comparison of speeds of sound for saturated liquid

T»K P 9 BAR MOL/L M/SEC C&LCD PONT

94.05 0.178 27.867 1509.0 1543.3 -2. 27

9%. 36 0.185 27.841 1507.0 1540.1 -2.20

96.17 0.228 27.689 1489.® 1521.2 -2. 11

98-. 5® 0.294 27.492 1466.6 1496.4 -2.03

101.79 0.414 27.211 1433.9 1460.7 -1. @7

105.45 @.590 26.893 1400.0 1421.0 -1.50

109.89 0.818 26.572 1363.® 1381.7 -1.31

112.79 1.113 26.23® 1326.® 1342.3 -1.17

116.07 1.439 25.937 1293.3 1307.7 -1. 11

119.78 1.889 25.598 1256.0 1268.6 -1.01

123.81 2.491 25.199 1214.5 1226.1 -0,96

127.96 3.250 24.787 1170.3 1181.7 -0.9®

131.97 4.135 24.375 1127.

1138.0 -0.95

136.17 5.248 23.929 1001.0 1090,9 -0,91

140.23 6.499 23.481 1035,3 1044,0 -0.84

144.49 8.043 22.992 986.7 993.6 -0.70

149. 01 9.955 22.448 933.3 938.9 -0.60

153.78 12.306 21. 839 875.7 @80.0 -0.49

158. Q2 14.7G9 21.263 822.2 826.8 ”0.56

162.81 17.810 20.562 759.1 765.2 — 0.80

167.5® 21.275 19.809 694.3 702,2 -1.14

172.02 25.051 1®. 997 628.2 636,® -1,37

176.44 29.195 18.085 558.1 562.® ”0 . ®4

179.47 32.313 17.360 < 506.569° 6 -0.70

182.51 35.686 16.538 449,0 451.6 -0.58

185.93 39. 80S 15.292 374.3 378.6 -1.14

137.55 41.87® 14.540 331.5 339.0 -2.27

189.60 44.640 13. 156 273. 0 276.5 -1.27

§7
Table 9. Comparison of speeds of sound, W(p,T)

T,K P,BAR MOL/L

111.33 1.125 26.372

111.33 5.046 26.394

111.33 9.608 26.421

111.33 19.728 26.477

111.33 29.374 26.530

111.33 39.324 26.584

111.33 49.132 26.636

111.33 58.839 26.687

111. 33 66.151 26.736

111.33 75.690 26.775

123.09 2.807 25.074

123.09 5.299 25.093

129. 09 10.102 25.129

123.09 19.910 25.202

125.09 29.577 25.273

125.09 39.172 25.341

125.09 48.636 25.407

125.09 59.235 25.479

125.09 66.465 25.541

125.09 77.959 25.603

125.09 87.747 25.666

125.09 97 . B 80 25.730

140.02 6.475 23.596

140.02 11.115 23.557

140.02 19.880 23.652

140.02 29.810 23.755

140. 02 39.344 23.851

140.02 49.305 23.947

140.02 56.991 24.036

140.02 68.354 24.124

140.02 78.932 24.216

140.02 88.355 24.299

140.02 97.880 24.378

140.02 106.067 24.446

140. 02 110.343 24.480

155.44 13.679 21.627

155.44 21.451 21.767

155.44 29.151 21.898

155.44 39.611 22.068

155.44 49.528 22.213

155.44 59.295 22.352

155.44 67.371 22.461

155. 44 78.426 22.603

155.44 88.761 22.730

155.44 97.779 22.836

155.44 106.416 22.957

155.44 118.145 23.063

155.44 127.771 23.164

155. 44 137.701 23.265

155.44 147.732 23 . 364

155.44 155.939 23.443

M/SEC CAL 00 PC NT

1340.9 1357.9 - 1.27

1345.0 1360.8 - 1.18

1349.6 1364.3 - 1.09

1358.7 1371.5 - 0.94

1367.0 1378.3 - 0 . 83

1376.6 1385.3 - 0.63

1364.8 1391.9 - 0.51

1393.1 1398.4 - 0.38

1402.1 1404.5 - 0.17

1408.5 1409.3 - 0.06

1200.6 1212.6 - 1.00

1202.9 1215.2 - 1.02

1209.

0

1220.1 - 0.92

1220.8 1229.9 - 0.75

1232.1 1239.4 - 0.59

1242.7 1248.5 - 0.47

1253.6 1257.3 - 0.28

1265.1 1266.9 - 0.14

1275.0 1275.0 0.00

1285.0 1283.2 0.14

1295.0 1291.4 0.27

1305.2 1299.8 0.41

1036.5 1046.6 - 0.78

1045.0 1053.5 - 0.81

1059.5 1066.2 - 0.63

1075.0 1060.1 - 0.47

1069.1 1092.8 - 0.34

1104.0 1105.7 - 0.15

1117.9 1117.8 0.01

1130.6 1129.1 0.14

1145.3 1141.4 0.34

1157.0 1152.0 0.43

1169.5 1162.5 0.60

1178.7 1171.3 0.63

1183.9 1175.7 0.69

854.0 860.4 - 0.75

872.9 878.6 - 0.66

891.3 895.6 - 0.48

915.1 917.6 - 0.27

935.5 936.3 - 0.08

954.5 954.0 0.05

970.5 968.0 0.26

990.5 986.1 0.44

1007.7 1002.3 0.54

1022.5 1015.8 0.66

1036.6 1031.0 0.73

1053.6 1044.4 0. 87

1068.6 1057.2 1.06

1080.9 1070.0 1.01

1094.9 1062.4 1.14

1105.5 1092.3 1.20

88
Table 9. Comparison of speeds of sound, W(p,T) (continued)

T »K P,BAR MOL/L M/SEC CALCO PCNT

170.75 24.024 19.239 646. 8 656.2 -1.45

170.75 30.012 19.468 672.2 683.2 -1.64

170.75 39.567 19.735 710.2 720.4 -1.44

170. 75 49.153 20.058 743.7 752.7 -1.22

170.75 62.001 20. 378 782.7 790.5 -1. 00

170.75 78.426 20.732 826.0 832.4 -0.77

170.75 88.761 20.930 849.9 856.0 -0.71

170.75 98.285 21.100 871.1 876.2 -0.58

170.75 106.898 21.245 890.3 893.4 -0.35

170.75 116.726 21.402 909.0 912.0 -0.33

173.75 126.960 21.556 927.0 930.4 -0.36

170.75 135.775 21.682 944.1 945.4 -0.14

170.75 146.111 21.823 961.4 962.2 -0. 09

17 0.75 156.142 21.954 977.9 977.8 0.01

170.75 168.706 22.110 995. 3 996*5 -0. 12

170.75 182.392 22.278 1015.6 1016.4 -0.08

185.91 45.211 16.248 450.0 456.4 -1.41

185.91 50 .034 16.756 494.8 499.8 -1.00

185.91 59.336 17.440 556.2 561.2 -0.90

185.91 68.860 17.950 603.0 609.3 -1.05

185.91 78.932 18.

T 9 646.6 651.2 -0.72

185.91 89.267 18.747 685.6 688.1 -0.37

185.91 98.083 19.021 707.4 716.0 -1.22

135.91 108.114 19.298 733.7 744.8 -1.52

185.91 118.246 19.551 766.8 771.4 -0.60

185.91 132.533 19.870 800.6 805.3 -0.59

185. 91 148.137 20.180 836. 3 838.8 -0.30

185.91 158.878 20. 376 856.1 860.1 -0.46

185.91 173.570 20.624 884.2 887.2 -0.34

185.91 183.398 20.778 901.8 904.3 -0.28

190. 03 45.525 13. 167 264.2 285.9 -8.20

190.03 47.754 14.410 340.2 357.2 -5.00

190.03 52.942 15.514 415.6 430.2 -3.51

190.03 59.528 16.286 482.3 488.1 -1.20

19Q.nQ3 68.405 16.980 539.8 544.9 -0.95

190.03 77.919 17.524 590.9 592.6 -0.29

190.03 88.558 18.035 634.5 636.7 -0.35

190.03 101.021 18.463 677.7 680.5 -0.42

190.03 113.484 18.846 715.7 718.4 -0.38

190.03 125.744 19.177 7 48.8 751.6 -0.38

190.03 137.903 19.468 776.2 781.4 -0.41

190.03 150 .366 19.737 807.2 809.4 -0. 27

190.03 163.336 19.992 833. 3 836.2 -0.35

190.03 175.090 20.205 855.1 858.9 -0.45

190.03 187.350 20.413 878.5 881.2 -0.3C

190.03 199.712 20.609 900.5 902.3 -0.2C

89
Table 10. Calculated P(T) isochores

The following pages give P(T) along isochores, as computed by the equation of state (6). The third column DP/DD is the isotherm slope (3p/3p) in units of the bar and

2 2 mol/t. The last two columns give the isochore slopes and curvatures 3 P /3 T , 3 P/3

T

, in units of the bar and K.

These tables show that the isochore curvatures are qualitatively consistent with

a maximum in the specific heat C (P, T) near the critical point.

90
methane isochore 1.0 MOl/L

T ®K P ®0AR DP/OD OP/OT 02P/0T2

154.0 10.642 0.511 0.0962 -0. 00019

162.0 11.406 9.394 0.0949 =0. 0001 4 170.0 12.161 10.2 35 0. 0939 -0.00011

178.0 12.909 11.069 0. 0931 -0.00009

1 @6 . © 13.651 11. 890 0. 0925 -0. 00007

194.0 14.369 12.792 0.0920 -0. 00006

202.0 15.123 13.505 0.0916 -0.00005

210.0 15.654 14.302 0.0912 -0,00004

218.3 16.583 15.033 0. 0909 -0. 00004

226.0 17.308 15.879 0. 0906 -0. 00003

234.0 18.032 16.651 0.0904 -0.00003

242.0 18.754 17.439 0.0901 -0.00003

290.0 19.475 18.215 0.0900 -0.00002

258.0 20.194 18.997 0,0898 -0.00002

266.0 28.911 19.757 0.0896 -0, 00002

274.0 21.628 20.524 0.0895 -0.00002

282.0 22.343 21.289 0.0893 -0.00002

290.0 23.057 22.052 0.0892 -0.00002

298.0 23.770 22.813 0.0891 -0® 00001

306.0 24.483 23.573 0. 0390 -0. 00001

314.0 25.194 24.330 0.0889 -0.00001

322.0 25.905 25.097 0.0888 -0. 00001

330.0 26.615 25.841 0.0887 -0. 00001

338.0 27.324 26.5 35 0 . 0886 -0. 00001

346.0 28.832 27.347 0. 0885 -0,00001

354.0 28.740 28.0 37 0.0684 -0.00001

362.0 29.447 28.846 0. 0884 -0.00001

370.0 30.154 29.535 0. 0883 -9. 00001

378.0 30.860 30.341 0.0832 -0. 00001

3 86.0 31.565 31.037 0.0881 -0.00001

394.0 32.270 31.832 0.0881 “0.00001

methane: ISOCHORE 2.0 MOL/L

T»K P 98AR DP/3D DP/QT D2P/0T2

170.® 20.618 6.764 0,2115 -0. 00065

178.0 22.292 7.785 0.2072 -0. 00045

186.0 23.936 8.758 0.2040 -0. 00034

194.0 25.558 9.724 0.2016 -0. 00027

202.0 27.163 10.652 0. 1997 -0. 00022

210.0 28.754 11.584 0.1981 -0.00018

218.0 30.334 12.434 0,1968 -0.00015

226.0 31.904 13.395 0.1957 -0. 00013

234.0 33.466 14.258 0. 1948 -0. 00011

242.0 35.021 15.174 0.1939 -0.00010

250.0 36.570 16.054 0.1932 -0.00009

2 58.0 38.112 16. 928 0. 1925 -0,00008

266*0 39.650 17. 738 0. 1919 -0. 00007

274.0 41.184 18. i 34 0.1914 -0. 00007

282.0 42.713 19,526 0.1909 -0. 00006

290.0 44.238 20.335 0.1904 -0. 0000b

298.0 45.760 21. 2*0 0.1900 -0. 00005

306.0 47.278 22. 0 33 0.1896 -0. 00005

314,0 48,793 22.942 0.1892 -0.00005

322.0 50.305 23.789 0.1888 -0.00004

3 30.0 51.815 24. 633 0. 1885 ”0® 00004

333.0 53.321 25.475 0.1802 -0, 00004

346.0 54.825 26.314 0.1878 ”0.00004

354.0 56.327 27.152 0,1875 -0,00004

362.0 57,026 27.936 0. 1872 »0. 00004

370.® 59.322 28. 819 0. 1869 ”0. 00004

378.0 60.817 29.650 0.1867 -0, 00003

3 86,0 62.309 3 0 . < 7 8 0.1664 -0.00003

3 94 ® 0 63.799 31. 3 J5 0. 1861 -0. 00003

91
METHANE ISOGHORE 3.0 MOL/L

T»K PpBAR OP/ JO OP/OT

178.8 28.631 4.960 0.3440

186.0 31.343 6.114 0.3345

194.0 33.992 7.210 0.3281

202. 0 36.597 8. 271 0. 3234

210.0 39.169 9.338 0.3197

218.0 41.715 10.327 0.3168

228.0 44.239 11.333 0.3144

234.0 46.745 12.328 0.3123

242.0 49.236 13.314 0.3105

250.0 51.715 14.232 0.3090

258.0 54.181 15.264 0.3077

266.0 56.637 16.230 0.3064

274.0 59.085 17.191 0.3053

282.0 61.523 18. 148 0.3043

290. 0 63.954 19. 101 0.3034

298.0 66.376 20.0^9 0.3025

306.0 68.795 20. 334 0.3017

314.0 71.205 21.936 0. 3009

322.0 73.610 22.874 U. 3002

330.0 76.009 23,839 0.2995

338.0 78.402 24.741 0.2988

346.0 80.790 25.670 0. 2982

354.0 83.173 26.536 0.2975

362.0 85.551 27.520 0.2969

370.0 87.923 28.440 0.2963

378.0 90.292 29.358 0. 2957

386.0 92.655 30.273 0.2952

3 94.0 95.014 31.135 0.2946

methane ISOCHORE 4.0 MOL/L

T »K P,BAR OP/OD DP/OT

186.0 36.30 0 3.872 0.4041

194.0 40.112 5.099 0.4700

202.0 43.834 6.268 0.4609

210.0 47.493 7.4)3 0.4543

218.0 51.107 8.517 0.4493

226.0 54.684 9.616 0. 4452

234.0 58.232 10. 7J3 0.4419

242.0 61.756 11.732 0.4391

250.0 65.260 12. 053 U . 4367

258.0 68.745 13.910 0.4346

266.0 72.215 14.970 0.4320

274.0 75.670 16.033 0.4311

282.0 79.112 17. 004 0.4295

290.0 82.543 10.131 0.4201

298.0 85.962 19.174 0.4260

306.0 89.371 20.214 0 • *>255

314.0 92.770 21.250 0.4243

322.0 96.160 22.203 0.4231

330.0 99.541 23. 312 0.4220

338.0 102.913 24.330 0.4210

346.0 106.27b 25.361 0.4199

354.0 109.631 26.301 0.4109

362.0 112.978 27.390 0.4179

370.0 116.318 20.411 0.4169

378.0 119.649 29.421 U.416G

386.0 122.973 30.420 0.4150

3 94.0 126.209 31.432 0 . <»141

02P/DT2

-0.00149

-0. 00095

-0. 00060

-0. 00052

-0.00041

-0. 00033

-0. 00028

-0. 00024

- 0.00020

-0.00016

-0.00016

-0. 00014

-0.00013

- 0.00012

- 0. 00011

- 0.00011

- 0.00010

-0. 00009

-0. 00009

-0.00009

- 0 . 0 000 8

-0. 00008

-0.00008

-0.00008

-0.00007

-0. 00007

-0. 00007

-0.00007

D2P/DT 2 -0. 00227

-0. 00137

-0.00095

-0. 00071

-0.00056

-0. 00045

-0. 00038

-0.00032

-0. 00028

-0. 0U 025

-0.00022

-0. 00020

-0. 00019

-0.00017

-0.00016

-0.00015

-0. 00015

-0.00014

-0. 00014

-0. 00013

-0. 00013

-0. 0001 3 -0. 00C12

-0. C0012

- 0. 00 012

-0.00012

-0. 0u012

92
MET HAWE ISOCHORE 5.0 HOL/L

T.K P f BkR

186.0 39.236

190.8 41.815

194.0 44.337

198.0 46.319

202.0 49.271

206.0 51.699

210.0 54.107

214.0 56.498

218.0 58.875

222.0 61.240

226.0 63.593

230.0 65.937

234.0 6 @.272

238.0 70.599

242.0 72.919

246.0 75.232

250.0 77.939

254.0 79.840

258.0 82.135

262.0 84.426

266.0 86.712

270.0 88.993

27 4.0 91.270

278.0 93.542

282.0 95.811

286.0 98.076

290 . S 100.337

294.0 102.594

298*0 104.848

302.0 197.099

306.0 109.346

310.0 111.590

314 . 0 113.831

318.0 116.069

322.0 118.303

326.0 120.539

3 30.6 122.763

334.0 124.989

338.0 127*211

342.0 129.431

346.0 131.647

350.0 133.861

354.0 136.072

358.0 138.280

362.0 140.486

3 66.0 142 * 68 ® 370.0 144 * 88 ® 374.0 147.085

378.0 149.279

382.0 151.470

386.0 153.699

390.0 155.845

3 94.0 158*028

398.0 160 . 20 ®

OP/OD DP/DT

2. 076 0.6545

2.772 0.6366

3. h26 0.6250

4.05® 0.6164

4.6 77 0.6098

5.28© 0.6043

5*8 91 0.599®

6.490 0.5960

7.035 0.5926

7.6 77 0*5897

B.2S7 0.5871

8.8 54 0.5848

9.439 0.5827

10*023 0.5808

10.606 0.5791

11.187 0.5775

11.768 0.5760

12.347 0.5746

12.925 0.5733

13.533 0.5720

14.079 0.9709

14.655 0.5697

15.230 0.5687

15*805 0.5677

16* 378 0.5667

16.951 0.5657

17.524 0 • 5648

18.095 0.5639

18.356 0.5631

19.236 0.5622

19.805 0.5614

20.374 0.5606

20.942 0.5598

21.509 0.5590

22. 075 0.5582

22.641 0. 5575

23.205 0.5567

23.759 0.5560

24. 333 0.5553

24.899 0.5545

25.457 0.5538

26.017 0.5531

26.5 77 0.5524

27.136 0.5517

27.695 0.5510

28.252 0.5503

28. 809 0. 5496

29. 364 0.5489

29.919 0*5482

30.473 0.5475

31. 026 0.5468

31.57® Q • 9461

32.129 0*5455

32® s SO 0.5448

D2P/DT2

- 0 • 00589

-0.00348

-0. 00245

-0. 00187

-0. 0Q149

-0. 00123

-0. 00104

-0.00089

-0. 00078

-0. 00069

- 0 . 00061

-0. 00055

-0.00050

-0. 00046

-0. 00042

-0*00039

-0.00036

-0. 00034

-0.00032

-0* 00030

-0. 00028

-0. 00027

-0. 00026

-0. 00029

-0. 00024

-0. 00023

-0. 00023

- 0. 00022

- 0. 00021

- 0 • 00021

- 0. 00020

- 0 . 00 020

- 0.00020

-0*00019

-0. 00019

-0. 00G19

-0. 00019

-0.00018

- 0. 00010

-0. 00018

-0.00018

-0.00018

- 0 . 0001 ® -0.00018

-0. 00018

-'0 . 00017

-0* 0001 7 -0. 00017

-0.00017

-0.00017

-0.00017

-0.00017

-0.00017

-0. C0017

93
METHANE ISOCHORE 6.0 MOL/L

T»K P»BAR

190.0 *3.917

194.0 47.112

198.0 50.241

202.0 53.327

206.0 56.380

210.0 59.408

214. 0 62.416

218.0 65.406

222.0 68.382

226.0 71.345

230.0 74.296

234.0 77.238

238.0 80.171

242.0 83.096

246. 0 86.013

250.0 88.924

254.0 91.828

258.0 94.726

262.0 97.619

266.0 100.506

270.0 103.388

274.0 106.266

278.0 109.138

282.0 112.007

286.0 114.871

290.0 117.730

294.0 120.586

298.0 123.437

302.0 126.285

306.0 129.128

310.0 131.967

314.0 134.803

318.0 137.635

322.0 140.463

326.0 143.287

330.

0

1*6.108

334.0 148.925

338.0 151.738

3*2.0 154.5*7

346. 0 157.353

350.0 160.155

3 54.0 162.953

358.0 165.7*7

362.0 168.536

366.0 171.325

370.0 174.109

374. 0 176.889

378.0 179.665

382.0 182.437

386.0 185.206

390.0 187.971

394.0 190.733

398.0 193.490

DP/OD DP/OT

1.534 0.6104

2.194 0.7892

2. 853 0. 7763

3.500 0.7670

4.139 0.7600

4. 774 0.7543

5.437 0.7496

6.038 0.7456

6.o68 0.7422

7.2 97 0.7393

7.926 0.7366

8.554 0.73*3

9.132 0.7322

9.610 0.7302

10.438 0.7285

11. 056 0.7268

11.694 0.7253

12. 322 0.7238

12. 949 0.7225

13.576 0.7212

14.204 0.7200

1*. 8 31 0.7188

15.457 0.7176

16.034 0.7165

16.710 0.7154

17.335 0.7144

17.961 0.7134

18.536 0.7123

19.210 0. 7113

19.834 0.7104

20. 458 0. 7094

21.081 0.7084

21.703 0.7075

22. 325 0.7065

22. 9*6 0.7056

23.556 0.7047

24.136 0.7037

24.805 0.7028

25. *23 0.7019

26.0*0 0.7009

26.656 0.7000

27.272 0.6991

27.837 0.6982

28.301 0.6973

29.114 0 • t963

29.726 0.6954

30. 337 0 • 6945

30.947 0.6936

31.556 0.6927

32. 165 0.6917

32. 772 0.6906

33.378 0.6899

33.933 0.6890

02P/DT2

-0. 00727

-0.00396

-0. 00268

- 0 . 00200

-0. 00157

-0. 00128

-0. 00107

-0. 00091

-0. 00079

-0. 00070

-0. 00062

-0. 00056

-0. 00051

-0. 00046

-0. 00043

-0.00040

-0.00037

-0. 00035

-0.00033

-0.00032

-0.00030

-0. 00029

-0. 00028

-0. 00027

-0.00027

-0. 00026

-0. 00026

-0.00025

-0. 00025

-0.00024

-0. 00024

-0. 00024

-0.00024

-0.00024

-0. 00023

-0. 00023

-0. U0 023

-0.00 023

-0. 00023

-0. 00 023

- 0. 00 023

- 0. 00 02 3 -0. 00023

-0. 00023

-0. 00023

-0. 00023

-0. 00 02 3 - 0. 00 02 3 -0.00023

-0. 00023

-0. 00 023

-0.00023

- 0. 00 02 3

94
METHAME ISOCHORE 7.0 MOL/L

T»& P*8AR OP/OD DP/DT D2P/0T2

190 . a 44.952 0.623 0.9975 =0.01927

194.0 48.S47 1.329 0.9580 -0. 00568

198.0 52.642 1.396 0.9410 -0. 00 326

202.0 56.383 2.661 0.9302 -0.00223

206.0 60.08® 3. 324 0.9225 -0. 00167

210.0 63.765 3.988 0.9166 -0. 00131

214.0 67.422 4. 654 0.9119 -0. 00106

218.0 71.061 5. 322 0 o 90 80 -0. 00089

222.0 74.687 5.993 0. 9047 -0. 00076

226.9 78.300 6.665 0.9019 -0. 00066

23®.

81.903 7.339 0.8994 = 0. 00058

234.0 85.496 8.0 15 0.6973 -0.00052

238.0 89.081 8*693 0. 8953 -0. 00047

242.0 92.659 9.372 0.8935 -0. 00043

246.0 96.229 10.052 0.8919 -0.00039

250.9 99.794 10.733 0.8904 -0.00037

254.0 103.352 11.415 0.8889 -0.00035

258.0 106.905 12. 0 98 0.8876 - 0. 00 033

262.9 110.453 12.732 0.8863 -0.00032

266.0 113.995 1 3 . *. 67 0.8850 -0.00031

270.

117.533 14.152 0.8838 -0.00030

274.0 121.066 14.838 0.8827 -0. 00029

278.0 124.595 15.523 0.8015 -0.00020

282.® 128.118 16.209 0. 8804 -0. 00028

206.0 131.638 16.896 0.8793 -0. 00028

290.0 135.153 17.592 0.8782 -0.00027

294.0 138.663 18.268 0.6771 - 0. 00 027

298.0 142.169 18. 954 0. 8760 -0. 00027

302.0 145.671 19.640 0.8749 -0. 00027

306.0 149.169 20.326 0. 8739 -0. 00027

310.0 152.662 21.011 0.8728 -0.00027

314.0 156.151 21. 696 0. 8717 -0. 00027

318.0 159.636 22.331 0.8706 - 0. 00 027

322.0 163.116 23. 0 d4 0.8695 -0. 00027

326*0 166.592 23. 7*8 0. 8684 -0. 00027

330.0 170.063 24.431 0.8673 -0. 00028

334.0 173.530 25. 113 0.8662 - 0. 00 028

338.0 176.993 25.7 94 0.8651 -0. 00028

342.0 180.451 2 6. *75 0. 8640 -0.00028

346.9 183.904 27.155 0.8628 -0. 00028

350.0 187.354 27.8 *4 0.8617 -0. 00 028

354.0 190.798 28.512 0.8606 -0. 00029

358.0 194.238 29.189 0.8594 - 0. 00 029

362.0 197.673 29.856 0. 8583 -0.00029

366.9 201.104 30. 541 0.8571 -0.00029

370.0 204. 530 31.215 0.8559 -0. 00 02 9 374.0 207.952 31.898 0.8548 ”0. 00029

37®. 0 211.36® 32. 5al 0. 8536 - 0. 00 030

382.0 214.780 33.232 0.8524 -0. 00030

386.0 218.188 33.902 0.8512 -0.00030

390.0 221.590 3%. 57 0 0.8500 -0.00030

394.0 224.988 35. 238 0. @483 “0. 00030

398.0 228.331 35.934 0.8476 -0. 00030

9 5
METHANE ISOCHORE 8.0 MOL/L

?»K DP/ 90 OP/OT 02 P / DT 2 ISko ® 49.865 0.755 1. 1253 -0. 00635

198.0 54.327 la *21 1. 1080 »0. 00302

202.0 58.739 2. 100 1.0984 “0.00190

206.0 63.119 2.7 90 1. 0921 “0. 00134

210.0 67.478 3.490 1. 0874 -0.00101

216.0 71.620 4.197 1.0839 -0.00079

218.0 76.158 4.911 1.0810 -0.00064

222.0 60 ® 46 9 5.631 1. 0787 -0. 00054

226.0 84.780 6.355 1. 0767 -0.00046

230.0 @9.083 7.085 1. 0750 -0.00040

2 36.0 93.380 7.810 1.0735 -0. 00036

238.0 97.671 8. 554 1. 0721 -0. 00033

242.0 101.957 9.294 1. 0708 -0. 00030

246.6 106.237 10.036 1. 0697 -0. 00028

250.0 110.514 10.781 1. 0686 -0. 00027

254.0 114.786 11.528 1. 0675 -0. 00026

258.0 119.054 12.276 1. 0665 -0.00026

262.0 123.318 13.026 1.0654 -0. 00025

266.0 127.577 13.776 1.0644 -0. 00025

270.0 131.833 14.531 1. 0634 -0. 00025

274.0 136.085 15.284 1. 0624 -0.00025

278.0 140.332 16.039 1. 0614 -0.00025

282.0 144.576 16.794 1.0604 -0.00026

286.0 148.815 17.550 1.0593 -0.00026

290.0 153.051 18.306 1. 0583 -0. 00027

29*.

0

157.282 19.062 1.0572 -0.00027

298.0 161.508 19.819 1.0561 -0. 00028

302.0 165.730 20.575 1.0550 -0.00028

306.0 169.946 21.332 1. C 539 -0. 00029

310.0 174.161 22.088 1. 0527 -0. 00029

3 1*. 0 178.370 22.8*4 1.0515 -0.00030

318.0 182.574 23.599 1.0503 -0.00030

322.0 186.773 24.354 1. 0491 -0. 00031

326.0 190.967 25.109 1.0479 -0.00031

330.0 195.156 25.363 1. C 466 -0.00032

334. 0 199.340 26.616 1.0453 -0. 00032

338.0 203.518 27.369 1 . 04*0 -0. 00 033

3*2.0 207.692 28.120 1. 0427 -0. 00033

3*6.0 211. 86 C 28. 871 1. 0414 -0. 00034

350.0 216.023 29.621 1. 0400 -0.00034

35*.

0

220. 160 30.369 1.0386 -0. 00035

358.0 224.332 31.117 1.0372 -0.00035

362.0 228.478 31.864 1.0358 -0. 00036

366.

0

232.618 32.609 1.0344 -0.00036

370.0 236.753 33. 354 1.0330 -0. 00036

374.0 240.662 34. 0 97 1.0315 -0. 00037

378.0 245.005 34.8 39 1. 0300 - 0. 00037

382.0 249.122 35.530 1.0285 -0. 00037

3 86.0 253.233 36.319 1.0270 -0.00038

390.0 257.338 37. 057 1. 0255 -0. 00038

3 9*. 0 261.438 37.7 33 1. 0240 -0. 00038

398.0 265.531 38.526 1. 0225 -0.00038

96
METHANE ISOCHORE 9.0 MOL/l

T »K P»@&R DP/ )D DP/DT 02P/DT 2

1 9* • 0 90.476 0.532 1.2689 -0. 00 395

198.0 59.609 1.214 1.2790 -0.00158

202.0 60.715 1.929 1.2744 »0.0G086

206.0 69.806 2.666 1.2717 “0. 00053

210.0 70.889 3. *19 1.2699 -0. 00G35

214.0 75.966 4.136 1.2687 -0. 00024

218.0 @1.039 4.963 1.2679 "0. 00018

222.0 86.110 5.748 1.2673 “0. 0001*

226.0 91-178 6. 542 1. 2668 ” 0. 0001 1 230.0 96.244 7.342 1.2664 - 0. 0 0 01 0 234.0 101.309 8.148 1.2660 -0.00009

238.0 106.372 8.958 1.2656 -0.00009

242.0 111.434 9.773 1. 2652 -0. 00010

2 46.0 116.494 10.592 1.2648 “0. 00010

298.0 121.552 11. *14 1.2644 -0. 00011

294.0 126.609 12.239 1.2639 -0. 00012

298.0 131.664 13.067 1.2634 ”0.00014

262.0 136.716 13. 8 36 1.2b28 - 0. 0 0 01 5 2 66.0 141.766 14.728 1.2622 -0. 00016

270.0 146.814 15.531 1.2615 - 0. 0 0 01 8 274.0 151.858 16.395 1.2608 -0.00019

278.0 156.900 17.231 1.2600 -0. 00020

282.0 161.938 16.068 1.2591 -0. 00C22

286.0 166.973 18.935 1.2582 -0. 00023

290.0 172.004 19. 742 1.2573 -0. 00025

294.0 177.031 20.580 1. 2563 -0. C 0 0 2

298.0 182.054 21.419 1.2552 -0.00027

302. 0 187.073 22.257 1.2541 -0. 00029

306.0 192.087 23. 095 1.2529 -0. C0030

310.0 197.096 23.933 1.2517 -0. 00031

314.0 202.100 24.771 1.2504 -0. 00032

318.0 207.100 25.608 1.2491 -0.00033

322.0 212.093 26. 444 1.2478 -0.00034

326.0 217.082 27.230 1.2464 -0. 00036

330.0 222.0b* 28.115 1. 2449 - 0. 00037

334.0 227.041 28.949 1.2434 -0. 00038

338.0 232. 012 29.733 1.2419 -0.00038

342.0 236.976 30.615 1.2404 “0. 00039

346.0 241.935 31. **6 1. 2388 - 0. 00 040

330.0 246.887 32.277 1. 2372 -0. 00041

394.0 251.832 33.135 1.2355 -0. 00042

358.0 256.771 33.933 1.2338 -0. 00 G43

362.0 261.702 34.759 1. 2321 - 0. 00 043

366 s 0 266.627 35.564 1.2303 -0. 00044

370.0 271.545 - 36. *38 1.2286 -0.00045

374.0 276.456 37.2 30 1.2268 -0. 00045

378.0 281.359 38.050 1. 2249 -0. 00046

382.0 266.255 38.869 1.2231 - 0. 00 046

386.0 291.1*4 39.686 1.2212 -0. 00047

390.0 296.025 40.502 1.2193 -0.00047

3 9*. 0 300.899 *1. 316 1. 2174 - 0. 00 040

398.0 305. 7b5 42.128 1.2155 -0. 00048

97
METHANE ISOCHORE 10.0 MOL/L

T »K P,BAR DP/ ID OP/DT D2P/DT2

194.0 51.007 0.5*0 1.4582 0.00085

198.0 56.846 1.275 1.4614 0. 00077

202.0 62.698 2. 056 1.4644 0.00070

206.0 68.561 2.835 1.4670 0. 00 063

210.0 74.434 3.6 9b 1.4695 0. 00 057

214. G 80.316 4.543 1.4716 0. 00051

218.0 86.206 5.404 1.4735 0.00045

222.0 92.104 6.276 1.4752 0. 00040

226.0 98.008 7. 157 1. 4767 0. 00035

230.0 103.917 8.047 1.4780 0.00030

234.0 109.631 8.9*3 1.4791 0.00025

238.0 115.750 9.8*5 1.4800 0. 00020

242.0 121.671 10. 752 1. 4807 0. 00016

246.0 127.595 11.654 1.4813 0. 00 01 2 290.0 133.521 12.579 1.4817 0.00008

254.0 139.448 13.4 98 1.4819 0.00004

258.0 145.376 1*. 420 1. 4820 0.00001

262.0 151.305 15.344 1.4820 - 0. 0 0 00 3 266.0 157.232 16.270 1.4818 -0. 00006

270.0 163.159 17. 1 97 1. 4815 - 0. 00 00 9

27*. 0 169.084 18.127 1.4811 -0. 00012

278.0 175.008 19. 0 57 1.4806 -0.00015

282.0 180.929 19. 988 1.4799 -0.00018

286.0 186.847 20.920 1 . *792 -0 . 0 0 02 0 290. 0 192. 762 21. 852 1. 4783 - 0. 00 023

294.0 198.673 22. 78 4 1.4773 -0. 00025

298.0 204.580 23.717 1.4763 -0.00028

302.0 210.483 24.6*9 1.4751 -0. 00030

306. 0 216-381 25.531 1. 4739 -0. 00032

310.0 222.27* 26.512 1.472o -0. 00034

314.0 228.162 27.4*3 1.4712 -0. 0 0 C 3

b

318.0 234.0*3 28. 373 1.4697 -0.00038

322.0 239.919 29.333 1.4682 -0.00039

326.0 245.789 30.2 31 1.4666 -0. 00C41

330.0 251.652 31.158 1. 46 49 -0. 00043

3 3* • 0 257.508 32. 0 34 1.4631 -0. 00044

3 38.0 263.357 33.009 1.4613 -0. 00046

342 .0 269.196 33. 933 1.4595 -0. 00047

346.0 275.033 34.855 1.4576 -0. 00048

350.0 280.859 35. 776 1. 4556 -0. 0005C

354.0 286.677 36.o 95 1.4536 -0. 0005

1

358 .

0

292.488 37.612 1.4515 -0. C 0 0 5 2 362.0 298.290 36.528 1.4494 -0. 00053

366.0 304.083 39. **2 1. 4473 -0. 00 054

370.0 309. 8b8 40. 354 1 . 445

1

-0. 00055

374.0 315.644 *1.254 1.4429 -C. 00056

378.0 321.41

1

*2. 173 1.4406 -0. 00057

382.0 327.169 *3. 079 1. 4383 - 0. 00 05 8 386.0 332.918 43. 983 1.4360 -0. 00058

390.0 338.657 *4. 3 36 1.4337 -0 . 0 0 05 9 39*. 0 344.387 *5.736 1.4313 -0. 0006C

3 98.0 350. 1J7 + 6. o 34 1. 4289 -0 . 0 0 06 0

98
METHANE ISOCHORE 11.0 MOl/l

T,K P f BAR DP/QD DP/OT 02 P / 0 T 2 194.0 51.571 0.601 1.6420 0 . 0 0 707

19 S .0 58.183 1.417 1 . 6620 0 . 00376

202.0 64.858 2.287 1.6746 0, 00266

206.0 71.576 3 . 1 32 1.6840 0. 00207

210.0 78.327 4.122 1.6915 0. 00169

21*.® 85.106 5 . 071 1.6976 0 . 0 0141

216.0 91.907 6,036 1 . 7029 0. 00120

222.® 98 . 72 ® 7.0 13 1.7073 0.00102

226.0 105.565 6.001 1.7111 0.00088

230 . 0 112.415 8 . 398 1. 7143 0 . 00075

234.0 119.278 10.002 1.7171 0. 00064

238.0 126.152 11.0 13 1.7194 0. 00054

242.0 133.033 12.029 1.7214 0.00045

246 . 0 139.922 13. 050 1.7230 0. 00036

250.0 146.817 14.075 1.7243 0. 00029

254.0 153.716 15.103 1.7253 0.00022

2 58.0 160.619 16.134 1.7261 0.00016

262.0 167.525 17. 167 1.7266 0. 00010

266.3 174.432 1 8.202 1.7269 0.00004

270.0 181.339 19.239 1.7269 - 0.00001

274.0 188.247 20.277 1.7268 - 0.00006

278 . © 195.153 21. 315 1.7265 - 0. 00010

282.0 202.058 22.355 1.7260 - 0. 00015

286.8 208.961 23 . 394 1.7253 - 0 . 0001 9

2 90.0 215.861 24.434 1.7245 - o . 00022

294.0 222.757 25.473 1.7235 - 0. 00026

298.0 229.649 26.512 1.7224 - 0.00030

302.0 236.536 27.551 1. 7212 - 0. 00033

306.0 243.418 28.589 1.7190 - 0. 00036

310.0 250.294 29.626 1.7183 - 0.00039

314.0 257.164 30.662 1.7167 - 0. 00042

318.0 264.027 31.697 1. 7150 - 0. 00044

322.0 270.884 32 . 730 1.7131 - 0 . 00047

326.0 277.733 33.762 1.7112 - 0.00049

330.0 284.573 34.793 1.7092 - 0.00051

334.0 291.406 35.822 1.7071 - 0. 00053

338 . 0 298.230 36.649 1.7049 - 0 . 00056

342.0 305.046 37 . 875 1.7027 - 0. 00057

3 h 6.

311.852 38.898 1.7004 - 0.00059

350.0 318.646 39.920 1.6979 - 0. 00061

354 . 0 325.435 40. 939 1.6955 - 0 . 00 06 3 358.0 332.212 41.957 1.6929 - 0 . 00064

362.0 336.979 42. 372 1.6903 - 0. 00066

366.0 345.735 43.935 1.6877 - 0. 00067

370.0 352.480 44.9 35 1.6850 - 0 . 0006 8 374.

359.215 46.004 1.6822 “ 0 . 0007 0 378.0 365.938 47. 009 1.6794 - 0.00071

382.

372.650 48. 013 1.6766 - 0 . 00072

3 86.0 379.351 49.013 1.6737 - 0.00073

390.0 386.039 50.012 1.6708 - 0.00074

394.0 392.716 51.

J 7 1.6678 - 0. 00075

398 . 0 399.382 52. 000 1 . 6648 - 0 . 0007 b

99
METHANE ISOCHORE I2.Q MOL/l

T,K P.SAR DP/ DO OP/DT 02 P / 0 T 2 194.0 52.289 0.913 1.8516 0 . 01322

198.0 59.779 1.865 1. 8892 0. 00699

202.0 67.384 2.867 1.9123 0. 00481

206.0 75.068 3.902 1.9290 0 . 0 0 365

210.0 82.811 4.962 1.9420 0. 00292

214.0 90.601 6 . 042 1.9526 0. 00239

218.0 98.430 7.137 1.9614 0.00200

222.0 106.290 8.245 1.9687 0. 00169

226.0 114.178 9.363 1.9749 0.00143

230.0 122.009 10.490 1. 9802 0 . 00121

234.0 130.019 11.624 1.9847 0 . 00103

238.0 137.965 12. 764 1.9885 0.00087

2 42.0 145.926 13.909 1.9917 0. 00073

246.0 153.898 15. 058 1.9943 0 .

0

0 06 0 260.0 161.880 16. 211 1.9965 0.00049

254.0 169.869 17.366 1.9982 0. 00038

258.0 177.865 18.524 1.9995 0. 00029

262.0 185.865 19.683 2.0005 0. 00020

266.0 193.666 20.844 2.0012 0. 00012

270.0 201.874 22.006 2.0015 0.00005

274.0 209.860 23.168 2. 0015 - 0 . 00002

278.0 217.686 24.330 2.0013 - 0.00009

282.0 225.890 25.493 2.0009 - 0. 00014

286.0 233.892 26.655 2. 0002 - 0.00020

290.0 241.891 27.816 1.9993 - 0. 00025

294.0 249.686 28.977 1.9982 - 0.00030

298.0 257.876 30.137 1.9969 - 0.00035

302.0 265.861 31.2 J 5 1.9954 - 0.00039

306.0 273.839 32.452 1.9937 - 0 . 00043

310.0 281.610 33.608 1.9919 - 0. 00047

314.0 289.774 34 . 7 61 1.9900 - 0.00051

318.0 297.730 35.913 1.9879 - 0. 00054

322.0 305.677 37.063 1. 9856 - 0 . 00057

326.0 313.614 38.211 1.9033 - 0 . 00061

330.0 321.543 39. 357 1.9808 - 0. 00063

334.0 329.461 - 0.531 1.9702 - 0.00066

338.0 337.368 41. 642 1.9755 - 0 . 00069

342.0 345.264 42. 731 1. 9727 - 0. 00071

34 o . 0 353.149 3.917 1. 9698 - 0. 00074

350.0 361.022 45.050 1.9668 - 0.00076

354 . 0 368.684 6. 181 1. 9637 - 0 . 00078

358.0 376.732 47. 3 39 1.9606 - 0.00080

362.0 384.568 8.434 1.9573 - 0. 00082

366.0 392.351 49.556 1.9540 - 0. 00083

370.0 400.200 50 . b 75 1.9507 - 0. 00085

374.0 407.996 51 . 792 1.9472 - 0. 00087

378.0 415.778 52. 935 1.9437 - 0. 00088

382.

0

423 . 54 b 54.315 1.9402 - 0. 00089

386 . 0 431.299 55. 122 1. 9366 - 0.00091

390.0 439.036 56.225 1.9329 - 0.00092

3 94.0 446. 763 57.326 1.9292 - 0 . 00093

398.0 454.472 58 . ^23 1.9255 - 0.00094

100
METHANE ISOCHORE 13.0 MOL/L

T,K P f 8AR OP/QD OP/DT 02P/DT2

190.0 45.342 0.642 1.9949 0. 06151

194.0 53.601 1.830 2.1098 0.01596

196.6 62.145 3. 031 2.1581 0. 00936

282.0 7 0 o @44 4.196 2.1894 0. 00659

206.0 79.650 5.413 2.2124 0. 00503

210.0 86.937 6.648 2.2303 0. 0040 0 214.0 97.488 7.89? 2. 2448 0. 00327

216.0 106.492 9. 159 2.2567 0 . 0 0 27 1 222.6 115.539 10.430 2.2666 0.00227

226.0 124.623 11.710 2.2750 0. 00191

230.0 133.737 12. 995 2.2820 0. 0 0161

234.0 142.877 14.286 2.2879 0. 00136

238.0 152.039 15.581 2.2929 0.00114

242.0 161.219 16.880 2.2970 0. 00094

246.0 170.414 18.181 2.3005 0. 00077

250.0 179.622 19.483 2. 3032 0. 00062

254.0 188.839 20.788 2.3054 0. 00048

258.0 198.064 22.093 2.3071 0. 00036

262.0 207.295 23.398 2.3083 0. 00025

266.0 216.530 24.734 2.3091 0.00014

270.0 225.768 26.009 2.3095 0.00005

274.0 235.006 27.314 2.3095 -0. 00004

278.0 244.243 28.617 2.3091 -0. 0001 2 282.0 253.478 29.919 2. 3085 -0.00020

2 86.0 262.710 31.220 2.3076 -0. 00027

290.0 271.938 32.520 2.3064 -0. 00033

294.0 281.161 33.817 2. 3049 -0. 00040

298.0 290.377 35.112 2.3032 -0.00045

302.0 299.566 36.405 2.3013 -0.00051

306.0 308.787 37.696 2. 2991 -0. 00056

310.0 317.979 38.934 2.2968 -0. 00061

314.0 327. Ibl •+0. 27 0 2.2943 -0. 00065

316.0 336.333 41.353 2.2916 -0.00069

322.0 345.494 •2. 832 2.2888 -0. 0007 3 326.0 354.643 44.109 2.2858 -0. 00077

330.0 363.780 45.383 2.2826 -0. C0080

3 3h • 0 372.904 46.654 2.2793 -0.00084

338.0 382.015 47.921 2.2759 -0. 00 08 7 342.0 391.111 49. 185 2.2724 -0. 00090

346.0 400.193 50.445 2.2687 -0. 00053

350.0 409.261 51. 732 2. 2650 -0. 00095

354.0 418.313 52. 956 2.2611 -0. 00098

358.0 427.350 54.236 2.2571 -0.00100

362.0 436.370 55.452 2.2531 -0. 00 1C 2 366.0 445.374 56.6 34 2.2490 -0. 00104

370.0 454. 3b2 57.933 2. 2447 -0.00106

374.0 463.332 59. 158 2.2405 -0. 00108

378.0 472.285 50.399 2.2361 -0.00110

382.0 461.221 6 1 *o26 2.2317 -0. 0U112

386.0 490.139 52. 849 2. 2272 -0. 00113

390.0 499.038 54.058 2.2226 -0.00 114

394.0 907.919 65.233 2. 2180 -0. 00116

396.0 616.782 66. 4 34 2. 2134 -0. 00117
METHANE ISOCHORE 14.0 MOL/L

T »K

190.0

194.9

190.0

202.0

2 06.0

210.9

214.0

213.0

222.0

226.0

230.0

234.0

238.0

242.0

246.0

250.0

254.0

258.0

262.0

266.0

270.0

274.0

278.0

282.0

286.0

290.0

294.0

298.0

302.0

306.0

310.0

314.0

318.0

322.0

326.0

330.0

334.0

338. 0 342.0

346.0

350.0

354. 0 358.0

362.0

366.0

370.0

374.0

378.0

382.0

386. 0 390.0

3 9* • 0 398.0

P»BAR DP/OD OP/DT

46.636 2.106 2.3515

56.229 3.590 2.4357

66.078 5. 035 2.4853

76.092 6. 478 2.5200

86.227 7.927 2.5463

96.455 9.382 2.5671

106.758 10. 843 2.5839

117.123 12.309 2.5978

127.537 13.778 2.6093

137.994 15.251 2.6189

148.486 16. 726 2.6269

159.008 18.202 2.6336

169.553 19.679 2.6391

180.119 21.157 2.6437

190.702 22.634 2. 6473

201.297 24. 110 2.6502

211.902 25.586 2.6524

222.515 27.060 2.6540

233.133 28.532 2.6550

243.755 30.002 2.6555

254.377 31.470 2.6555

264.998 32.935 2.6551

275.617 34.398 2.6543

286.232 35.858 2.6531

296.842 37.315 2.6516

307.445 38.768 2.6498

318.040 40.218 2.6477

328.626 41.665 2.6452

339.201 *3.108 2.6426

349.766 *4.5*7 2. 6397

360.318 45.982 2.6365

370.858 *7.413 2.6332

381.384 *8.841 2. 6297

391.895 50. 264 2.6259

402.391 51.633 2.6220

412.871 53.097 2.6179

423.334 54.538 2.6137

433.780 55. 914 2.6093

444.209 57.315 2.6048

454.619 58.712 2.6002

465.010 60.104 2.5954

475.382 61.492 2.5905

485.734 52.875 2.5855

496.065 64.253 2.5804

506.377 65.627 2.5752

516.667 56. 396 2.5699

526.936 58.350 2.5646

537.183 59.719 2.5591

5*7,409 71.073 2.5536

557.612 72.423 2.5480

567.793 73. 757 2.5423

577.951 75.107 2.5366

588.085 76. **2 2.5308

02P/0T2

0.03018

0.01528

0. 01014

0. 00747

0.00580

0.00465

0. 00380

0. 00315 J

0 . 0 0 26 2

0. 00219

0. 00183

0. 00152

0.00125

0.00102

0.00082

0. 00063

0. 00047

0.00032

0.00019

0. 00006

-0.00005

-0.00015

-0.00025

-0.00034

-0. 00042

-0. 00050

-0.00057

-0. 00063

-0. 00070

-0. 00076

-0.00081

-0. 00086

-0.00091

-0. 00096

- 0. 00100

-0.00104

-0.00108

- 0. 00111

-0.00115

-0. 00118

- 0 . 00 121

-0. 00124

-0. 00126

-0. 00129

-0.00131

-0.00133

-0. 00135

-0. 00137

-0.00139

-0. 00141

-0. 00142

-0. 00144

-0.00145

102

Ml
METHANE ISOCHORE 15.0 MOL/L

T»K P S ®AR DP/OO BP/DT 02P/DI2

190.0 49.939 4,729 2.7734 0.01990

194.0 61.170 6,524 2® 8376 0.01307

198.0 72.615 8.273 2. @822 0. 00952

202.0 @4.213 10.003 2.9155 0. 00731

206.0 95.929 11.722 2.9416 0.00580

210.0 107.739 13.435 2,9624 0. 80469

214.0 119.624 15.142 2.9794 0. 00304

218.0 131.570 16.646 2.9934 0. 00 316

222.0 143.567 18.546 3.0049 0. 00261

226.0 155.606 20.242 3.0144 0. 00215

2 30*0 167. 660 21.934 3, 0222 0.00176

234.0 179.782 23,623 3. 0285 0. 00143

238.0 191.906 25.308 3.0337 0.00114

242.0 204.050 26.989 3.0377 0® 00089

246.0 216.207 28.666 3,0408 0® 00067

250.

228.375 30.338

‘ 3.0431 0. 00047

254.0 240.550 32.007 3.0446 0. 00029

258.0 252.731 33.670 3,0454 0. 00012

262. 0 264.913 35.329 3.0456 -0. 0000 2 266.0 277.094 36.983 3, 0452 -0.00016

270.0 289.274 38,632 3. 0443 -0. 00028

274.0 301.449 *0.277 3.0430 -0. 00039

278.0 313.617 41.916 3,0412 -0. 00050

282.

325.778 *3.550 3. 0390 -0. 00059

286.0 337.929 45.179 3.0365 -0. 00068

290.0 350.069 * 6 • 8 0 3 3. 0336 -0. 00077

294.0 362.197 48.421 3.0303 -0. 00084

298.0 374.311 50. 034 3.0263 -0. 00092

302.0 386.411 51.641 3. 0230 -0.00098

306*0 398.495 53.2*3 3. 0189 -0.00105

319.0 410.562 54 0 839 3.0146 -0. 00111

314.0 422.612 56. * 30 3,0101 -0. 00116

318.0 434.643 58,015 3.0053 -0, 00122

322.0 446.654 59.595 3. 0004 -0. 00126

326.0 458.645 61.168 2.9952 -0.00131

3 30.0 470.616 62.736 2.9899 -0.00135

33*.482.564 64.299 2.9844 -0.00139

338.0 494.491 35.855 2.9787 -0. 00 143

342.0 506.394 67.406 2.9729 -0.00147

346. 0 518.274 68.951 2,9670 -0. 00150

359.0 530.130 70.489 2.9609 -0. 0 015 3 354.0 541.961 72.022 2,9547 -0. G0156

358.0 553.767 ,•73.530 2.9484 -0. 00159

362.0 565,548 75.071 2. 9420 -0. 00162

366.0 577.303 76.586 2.9354 -0. 00 164

370.0 589.031 73. 0 06 2.9283 -0. 00167

37*. 0 600.733 79.599 2. 9221 -0. 00169

378.0 612.408 31.097 2.9153 -0. 00171

382.0 624.056 92.588 2® 90 35 - 0. 0017 3 386.S 635.676 34.074 2,9015 -0.00174

399.0 647.268 85. 553 2, 8945 -0.00176

394.0 658.8 32 87.027 2.8874 -0.00178

398.0 670.367 88.4 95 ' 2. 6803 -0. 00179
METHANE ISOCHORE 16.0 MQL/L

T »K P»6AR DP/OO OP/DT 02P/DT2

166.0 43.674 6.770 3.2038 0.02046

190.0 56.632 8.971 3.2713 0.01397

194.0 69.818 11.087 3.3193 0.01031

193.0 83.171 13.155 3.3554 0. 00793

202. 0 96.651 15.191 3.3836 0.00626

206.0 110.232 17.205 3.4061 0. 00502

210.0 123.894 19.200 3.4241 0.00406

214.0 137.621 21.179 3.4388 0. 00330

213.0 151.401 23.146 3.4507 0. 00267

222.0 165.224 25.101 3.4603 0. 00216

226.0 179.081 27.044 3.4680 0.00172

230.0 192.966 28.977 3.4742 0. 00134

234.0 206.872 30.901 3.4789 0. 00102

238.0 220.795 32.815 3.4824 0.00074

242.0 234.730 34.720 3.4848 0.00049

246.0 248.672 36.617 3.4863 0. 00027

250.0 262.619 38.505 3.4870 0. 00 00 7 254.0 276. 5b7 *0. 354 3.4869 -0. 00011

258.0 290.513 42.255 3.4861 -0. 00027

262.0 304.455 *4. 118 3.4847 •0.00042

266.0 318.390 *5.973 3.4827 -0.00056

270.0 332.316 *7. 820 3.4803 -0. 00068

274.0 346.231 49.659 3.4773 -0. 00079

278.0 360.134 51.490 3.4739 -0.00090

282.0 374.022 53.313 3.4701 -0. 00100

286. 0 387.894 55. 129 3.4659 -0.00109

290.0 401.749 56.937 3.4614 -0. 00117

294.0 415.585 58.737 3.4566 -0.00125

298.0 429.401 60.530 3.4514 -0. 00132

302.0 443.196 62. 315 3.4460 -0.00139

306.0 456.969 64.092 3.4*03 -0. 00146

310.0 470.719 65.862 3.4344 -0. 0 015 2 314.0 484.444 67.625 3.4282 -0.00157

318.0 498.1*4 69.380 3.4218 -0. 00162

322.0 511.818 71.127 3.4152 -0. 00167

326.0 525.465 72.867 3.4084 -0.00172

330.0 539.085 7*. 600 3.401* -0. 00176

334. 0 552.67b 76.325 3. 3943 -0.00181

338.0 566.239 78. 0*3 3. 3870 -0.00184

342.0 579.772 79. 753 3.3795 -0.00188

3*6.0 593.275 81.* 57 3.3720 -0. 00191

350.0 606.748 33.152 3. 3642 -0.00195

354.0 620.189 84. 8*1 3.3564 -0. 00198

358.0 633.598 86.522 3.3484 - 0.00200

362.0 646.976 88.196 3.3404 -0. 0020 3

3 66.0 660.321 89.863 3.3322 -0.00205

370.0 673.633 91.522 3.3239 -0. 00208

374.0 686.912 93.175 3. 3156 - 0.00210

104
METHANE ISOCHORE 17.0 MOL/l

T,K P,BAR DP/DD DP/OT D2P/DT2

182.0 38.182 10.252 3.7459 0. 01746

186.0 53.291 12.872 3. 8051 0.01255

190.0 68.603 15.390 3. 8487 0. 00943

194.0 84.067 17. 819 3. 8819 0. 00729

198.0 99.648 20.207 3.9077 0. 00571

202.0 115.321 22.556 3.9281 0. 00452

206.0 131.067 24. 873 3.9442 0. 0 0 358

210.0 146.870 27.162 3.9569 0. 00 262

214.0 162.719 29.426 3.9670 0.00220

218.0 178.603 31.669 3. 9747 0. 0 016 8 222.0 194.514 33.893 3.9805 0.00124

226.0 210.445 36.098 3.9847 0. 00087

2 JO • 0 226.390 38.297 3.9875 0. 00054

234.0 242.343 40. *59 3. 9891 0. 00026

238.0 258.301 42.617 3.989 7 0. 00001

242.0 274.260 44.750 3.9892 -0.00021

246.0 290.214 *6.890 3.9860 -0. '00041

250.0 306.162 49. 007 3.9860 -0. 00059

254.0 322.101 51.111 3.9833 -0.00075

258.0 338.028 53.202 3.9800 -0. 00090

262.0 353.940 55.292 3.9761 -0.00104

266.0 369.836 57. 350 3.9717 -0. 00116

270.0 385.713 59.406 3.9668 -0. 00127

274.0 401.570 51.452 3.9615 -0. 00138

278.0 417.404 o3.*97 3.9558 -0.00148

282. 0 433.215 65*511 3. 9497 -0. 00157

286.0 449.001 57.524 3.9433 -0. 00165

290.0 464.761 69.526 3. 9365 -0. 00173

294.0 480.493 71.521 3.9295 -0. 00180

2 98.0 496.196 7 3. 5 04 3.9221 -0. 00167

302.0 511.870 75.477 3.9145 -0.00193

306.0 527.512 77.440 3.9067 -0.00199

310.0 543.123 79.394 3.8986 -0.00205

314.0 558.700 31.338 3.8903 -0. 00210

318.0 574.2*5 83.272 3.8818 -0.0021

322.0 589.754 85. 197 3.8731 -0.00220

326.0 605.229 97.113 3.8642 -0. 0 0 224

330.0 620.667 99.020 3.6551 -0. 0 0 22 8 33*.

636.070 90.917 3.8459 -0. 00232

338.0 651.435 92.805 3. 6366 -0. 00236

342.0 666.762 94.694 3.8271 -0. C0239

346.0 682.051 96.555 3.8175 -0. 00242

350.0 697.302 98.416 3.8077 -0. 00245

105
METHANE ISOCHORE 18.0 MOL/L

T,K P »8AR DP/DD DP/OT 02P/0T2

178.0 34.766 15.826 4.4043 0. 01270

182.0 52.475 18.828 4.4480 0. 00938

186.0 70.335 21.725 4.4806 0.00706

190.0 88.310 24.540 4.5053 0.00537

194.0 106.370 27.293 4.5242 0.00409

198. 0 124.497 29.992 4.5384 0. 00308

202.0 142.673 32.647 4.5491 0. 00228

206.0 160.885 35.262 4.5568 0.00162

210.0 179.124 37.843 4.5622 0.00108

214.0 197.380 40.392 4.5656 0. 00063

218.0 215.647 42.914 4.5673 0. 00025

222.0 233.917 45.408 4.5676 -0. 00009

226.0 252.18b 47.879 4.5667 -0. 00037

230.0 270.450 50.327 4.5647 -0. 00062

234.0 288.703 52.753 4.5618 -0.00084

238.0 306.943 55.159 4.558C -0.00104

242.0 325.166 57.546 4.5535 -0. 00121

246.0 343.370 59.915 4.5483 -0.00137

250.0 361.552 62.267 4.5425 -0. 00152

2 54.0 379.710 64.601 4.5362 -0. 00165

258.0 397.841 66.920 4.5294 -0. 00176

262.0 415.944 59.222 4.5221 -0.00187

266.0 434.017 71.510 4.5144 -0.00197

270.0 452.059 73.733 4.5063 -0.00207

274.0 470.068 76. 042 4.4979 -0. 00215

278.0 488.042 78.287 4.4891 -0. 00223

282.0 505.980 30.518 4.4800 -0. 00231

286.0 523.882 32.7 06 4.4707 -0. 00238

290.0 541.745 84.941 4.4610 -0.00244

294.0 559.570 37.133 4.4511 -0. 00250

298.0 577.354 89.313 4.4410 -0.00256

302.0 595.097 91.431 4.4306 -0. 00262

306.0 612.799 93.636 4. 4201 -0. G02b7

310.0 630.458 95.730 4.4093 -0. 00271

31*.. 0 648.073 47.912 4. 3984 -0. 00276

318.0 665.644 100.032 4.3872 -0. 00280

322.0 683.171 102.141 4. 3759 -0. 00284

106
METHANE ISOCHORE 19.0 MOL/L

T »K P»8AR DP/OD DP/OT D2P/0T2

174.0 35.346 24.083 5.1773 0.00717

178.0 56.106 27.453 5.2016 0.00508

182.0 76.949 30.719 5.2187 0. 0 0 354

186.0 97.848 33.899 5.2304 0.00237

190.0 118.786 37.006 5.2380 0.00146

194.0 139.748 40.052 5.2423 0. 0 0 07 4 198.0 160.722 43. 042 5.2441 0.00016

202.0 181.698 45,985 5.2438 -0. 00031

206.0 202.169 * 8. 8 33 5.2417 “0.0 0 07 1 210.0 223.630 51.742 5.2382 -0.00104

214.0 244.573 54.565 5.2335 -0. 00132

218.0 265.496 57.354 5.2277 -0. 00156

222.0 286.39* 60.111 5.2211 -0. 00176

226.0 307.263 52.840 5.2136 -0. 00194

230.0 328.102 55.541 5,2055 -0.00210

234.0 348.907 58.216 5.1968 -0. 00224

238.0 369.676 70. 857 5.1876 -0. 00237

242.0 390.407 73.494 5,1779 -0. 00248

246.0 411.099 76,099 5.1678 -0. 00259

250.0 431.749 78.683 5,1572 -0. 0026 8 254.0 452.356 81. 247 5. 1463 -0. 00276

258.0 472.919 33. 791 5.1351 -0. 00284

262.0 493.43? 36. 316 5. 1236 -0.00292

266.0 513.907 38.823 5.1116 -0. 00299

270.0 534.331 91. 313 5, 0997 -0. 00 305

274.0 554.705 93.785 5.0874 -0. 0031

273.0 575.029 96. 240 5. 0748 -0.00316

282.0 595.303 98.630 5.0621 “0. 00322

286.0 615.526 101. 133 5. 0491 - 0.0 0 327

290.0 635.696 103.512 5.0360 -0. 00331

294.0 655.813 105.935 5.0226 -0. 00336

298.0 675.877 108.283 5.0091 -0.00340

302.0 695.666 110.647 4.9954 -0. 00344

METHANE ISOCHORE 20.0 MOL/L

T,K P»8AR DP/3D DP/OT D2P/DT2

170.0 42.455 35. 602 8 » 06 0 8 0. 00112

174.0 66.7G4 39. 310 6.0629 -0. 00001

178.0 90.953 42.915 6,0611 -0.00066

182.0 115.188 46,432 6.0563 -0. 00150

186.0 139.400 49, 871 6. 0492 - 0. 0 020 0 190.0 163.580 53.242 6.0404 -0.00239

194.0 187,722 56.551 to. 0302 -0. Cu27 0 198.0 211.820 59.835 6.0189 -0. 00294

202.0 235.872 63. 038 6 • 0068 - 0. 00 31 3 206.0 259.874 66 • 135 5.9939 -0. 00329

210.0 283.623 58.279 5.9805 -0. 0u 34 2 214.0 307.717 72. 353 5.9665 -0. G0353

218.0 331.554 75. 3 91 5. 9522 - 0. 0 G 3b 2 222.0 355,334 78.393 5.9376 -0.00370

226.0 379.055 31. 36 3 5.9226 -0. 00377

230.0 402.715 34. 333 5.9075 -0. 00383

234.0 426.314 37.213 p. 8920 - 0. 0 0 38 8 233.0 449.851 90.095 5 « 87o4 -0. 00 392

2 42.0 473.325 92.951 5. 8607 -0. 00397

2 46.0 496.736 95,732 5. 8447 - G . 00401

250.0 520.083 98. 589 5. 8286 - 0. G 0 4 0 4 254.0 543.365 101. 373 5.8124 -0. 00408

253.0 5b6. 582 104.135 5,7960 -0. 00411

262.0 589.733 10b. 875 5,7795 -0 . 0 0 41 4

2 6o . 0 612.816 109. 5 94 5.7629 -0. 0G417

270.0 635.836 11-2.2 94 5.7462 -0. 00419

274.0 ,658.787 114.974 5.7294 -0. GO-22

273.0 681,671 117. to 35 5.7124 -0.00425
METHANE ISOCHORE 21*0 M0L/L

T P » BAR OP/OD OP/DT D 2 P / 0 T 2 160,0 16.794 44.644 7 . 07 S 5

“ 0 . 00454

162,0 36.941 46.753 7 . 0691 » 0. 00489

164.0 45.070 48.829 7.0590 - 0.00518

166.0 59.177 50.875 7.0484 - 0. 00541

168,6 73.263 52.891 7. 0374 - 0.00560

170,0 87.327 54.881 7. 0261 - 0 . 00575

172.0 101.367 56.845 7.0144 - 0. 00587

174.0 115.384 § 8.735 7.0026 - 0.00597

176.0 129.377 60.703 6.9906 “ 0 . 00604

17 ®. 0 143.346 62.600 6 . 9784 - 0 . 00610

180.0 157.291 64.477 6.9662 - 0.00614

182.0 171.211 66.335 6.9539 - 0.00617

184.0 185.106 68.175 6.9415 - 0.00618

186.0 198.977 69.998 6.9291 - 0. 00619

188.0 212.823 71.834 6.9167 - 0. 00619

190.0 226.644 73.595 6.9044 - 0. 00619

192.0 240.440 75.370 6.6920 - 0.00617

194.0 254.212 77. 132 6.8797 - 0.00616

196.0 267.959 78.879 6.8674 - 0. 00614

198.0 281.681 30.613 6.8551 - 0.00612

200.0 295.379 82.335 6.8429 - 0.00609

202.0 309.053 34. 044 6.8307 - 0. 00607

204.0 322.702 85.741 6. 8186 - 0. 00604

206.0 336.327 87.427 6.8066 - 0 . 00602

208.0 349.929 39.102 6 . 79+6 - 0.00599

210.0 363.506 30.766 6.7826 - 0.00596

212.0 377.059 92.420 6.7707 - 0. 00593

214.0 390.589 94.064 6.7589 - 0 . G 0591

216.0 404.094 95.698 6.7471 - 0.00588

218.0 417.577 97.323 6.7353 - 0. 00585

220.0 431.036 98.939 6.7237 - 0 . 00583

222.0 444.472 100.546 6.7120 - 0.00580

224.0 457 . 88 h 102 . 1+4 6.7005 - 0. 00578

226 . 0 471.273 103.734 6.6889 - 0. 00576

228.0 484.640 105.316 6.6774 - 0.00573

230.0 497.983 106.890 6.6660 - 0.00571

232.0 511.304 138.456 6 . € 546 - 0 . 00569

234.0 524.602 110.014 6.6432 - 0. 00567

236.0 537.877 111.566 6.6319 - 0. 00565

238.0 551.129 113.110 6 . 620 b - 0.00563

240.0 564.359 114 - 6+6 6.6094 - 0 . 00562

242.0 577.567 116.176 6.5981 - 0. 00560

244.0 590.752 117.700 6.6870 - 0 . 0 0559

2 46.0 603.915 119.216 6.5758 - 0.00557

248.0 617.055 120 - 726 6.5647 - 0 . 00556

250.0 630.173 122.230 6.5536 - 0. 00555

252.0 643.269 123.728 6.5425 - 0.00554

254.0 656.343 125.219 6.5314 - 0 . 00553

256.0 669.395 126 . 704 6.5204 - 0 . 00552

258.0 682.425 128.134 6.5094 - 0. 00551

260.0 695.432 129.656 6.4983 - 0.00550

108
METHANE I50GHORE 22,0 HOL/L

T#K Pj BAR

154.0 23.629

156.0 40 o @69

153.0 56.457

160.6 72.795

162.0 89.082

164.0 105.319

166.0 121.50?

1 6 © o 0 137.647

176.0 153.740

172.0 169.736

174.0 185.786

176.0 201.741

170.® 217.652

160.0 233.519

182.0 249.343

104.0 265,125

186.0 280.865

188.0 296.565

190.0 312.225

192.® 327.845

194.® 343.426

196.0 358.970

193 . § 374.475

203.0 309.943

282.0 405.375

204.0 420.771

206.® 436.131

200.0 451.456

210.® 466.747

212.0 432.003

214.0 497,226

216.0 512.415

218.0 527.571

220.0 542.695

222.0 557.786

224.0 572.846

226.0 587.874

223.0 602.871

2 30.0 617.836

232.0 632.772

234.0 647.676

236. 0 662,551

233.0 677.395

2*0.0 692.210

DP/OO D 61,470 a. 63,711 8,

65.950 6,

68.154 3 , 70,321 S.

72,461 8®

74.574 0

76.663 0. 78.729 8.

00.772 , 8.

82.794 7.

@4.795 7.

86.770 7

S8. 742 7.

90.698 7. 92.610 7. 94.531 7. 96.429 7.

98.312 7.

100.180 7.

102.035 7. 103.876 7.

105.704 7.

107.520 7.

139.324 7.

111.116 7. 112.897 7.

114. 667 7

116.427 7.

118.176 7.

119.915 7. 121.6*5 7.

123.365 7.

125. 076 7. 126.770 7.

128.47 1 7.

130.156 7.

131. 833 7. 133.531 7. 135.162 7.

136.815 7.

138.460 7. 140.098 7.

1*1.729 7.

P/DT D2P/OT2

2331 -0. 01305

2071 -0. 01292

1614 -0.01277

1561 -0. 01261

1310 -0. 01243

1063 -0.01224

0820 -0.01205

0581 -0. 01186

0346 -Q. 01167

0115 -0.01147

9887 -0.01128

9663 -0. 01109

9443 -0. 01090

9227 -0.01072

9015 -0.01054

@806 ”0. 01036

6600 -0. 01019

8398 -0.01003

8199 -0. 00987

8003 -0. 0097 1 7311 -0. 00956

7621 -0. 00941

7434 -0. 00927

7250 -0. 0091 4

7068 -0.00901

6889 -0. 00889

6713 -0.00677

6539 -0.00865

6367 -0.00854

6197 -0. 00844

6029 -0.00834

5864 -0. C0824

5700 -0.00815

5538 -0. 00806

5377 -0. 00797

5219 -0.00789

5062 -0.00782

4906 -0. 00774

4752 -0. 00767

4599 -0. 00761

4448 -0.00754

4297 - 0. 00748

4148 -0. 00742

4000 -0. 00737

1 0 9
METHANE ISOCHORE 23.0 MOL/L

T,K P » BAR DP/OD OP/OT 02P/0T2

146.0 23.115 80.355 9.5564 -0. 02359

148.0 42.181 82. 766 9.5099 -0. 02293

150.0 61.156 85.143 9.4647 -0.02228

152.0 60.041 87.438 9.4208 -0. 02165

154.0 96.839 39.802 9.3781 -0. 02105

156.0 117.554 92.086 9.3366 -0.02046

158.0 136.186 94.343 9.2962 -0. 01989

160.0 154.739 96.574 9. 2570 -0. 01935

162.0 173.215 98. 730 9.2188 -0. 01882

164.0 191.615 100.963 9.1817 -0.01831

166.0 209.942 103.122 9. 1455 -0. 01783

168.0 228.198 105.261 9.1104 -0.01736

170.0 246.384 107.378 9.0761 -0. 01691

172.0 264.503 109.476 9. 0427 -0. 01648

174.0 282.556 111.555 9.0101 -0.01607

176.0 300.544 113.615 8.9784 -0. 01568

178. 0 318.470 115. 659 8.9474 -0.01530

180.0 336.334 117.636 8.9172 -0.01494

182.0 354.139 119.696 8.8877 -0. 01459

184.0 371.685 121.691 8.8588 -0. 01426

166.0 389.575 123.671 8.8306 -0. 01394

168.0 407.208 125.037 8. 6031 -0. 01363

190.0 424.768 127.539 8.7761 -0.01334

192.0 442.313 129.528 8.7497 -0.01307

19*.

0

459.787 131.454 8.7238 -0. 01280

196.0 477.209 133.367 8.6985 -0.01255

196.0 494.561 1 J5.268 8.6736 -0. 01230

200.0 511.904 137. 157 8.6493 -0. 01207

202.0 529.178 139.036 8.6253 -0. 01185

204.0 546.405 1*0.903 8.6018 -0.01164

206.0 563.586 1*2.759 8.5788 -0. 01144

208.0 580-721 1*4.605 8.5561 -0. 01124

210.0 597.810 146.441 8.5338 -0. 01106

212.0 614.856 1*8.267 8.5118 -0.01088

214.0 631.658 150.0 33 8.4902 -0. 01072

216. 0 648.817 151. 890 8.4690 -0.01056

218.0 665.734 153. b39 8.4480 -0. 01040

220.0 682.609 155. *7 8 8.4273 -0. 01026

222.0 699. 44* 157.259 8.4070 -0.01012

110
METHANE ISOCHORE 24-0 HOL/l

T,K P»8AR OP/QO OP/OT D2P/0T2

136* 3 10.481 10 1® 5 SO 11.1141 -0. 03823

136.0 32*634 104.112 11.0391 -0.03681

1A0.@ 54.639 106.627 10.966® -0.03547

142.0 76.503 109. 108 10,8972 -0. 03419

144.0 9®. 229 111. 556 10.8300 -0.03296

146.0 119*824 113.973 10.7653 -0.03180

146.0 141.292 116. 350 10.7028 -0. 03070

150.0 162.637 118.719 10.6424 -0. 02964

152.0 183.863 121.052 10.5842 -0.02864

154.0 204.975 123.359 10.5278 -0. 02769

156.0 225.976 125.642 10.4734 -0. 02678

156.0 246.870 127.903 10.4207 -0. 02591

160.0 267.660 130.141 10.3697 -0.02509

162.0 288.35® 132.358 10.3203 -Q. 02430

164.0 3fi8. 942 134,555 10.2725 -0. 02355

166.0 329.440 136.733 10.2261 -0. 02284

166.0 349.847 138.892 10® 1811 -0.02216

179.0 370.166 1*1.034 10.1374 - 0 ® 0 2152

172.0 390.39® 143.156 10.0950 -0. 02090

174.® 410.547 1*5. 266 10. 0538 -0. 02032

176.

430.614 147. 358 10.0137 -0,01976

17®.® 450.662 1*9. *35 9. 9747 -0. 01923

160 .

470.514 151.498 9.9366 -0. 01872

132.0 490.350 15 3. 5*6 9. 6999 -0. 01823

184.0 510.114 155.581 9.8639 -0.01777

186.0 529.806 157.632 9. 8287 -0.01733

188.0 549.429 159.611 9.7945 -0. 01691

190.0 56®. 985 151.697 9.7611 -0.01652

192.0 588.474 163.592 9.7284 -0. 0161

194.0 607.899 lo5. 565 9.6965 -0. 01577

196.0 627.261 167.527 9.6653 -0. 01543

198.0 646.561 169.478 9.6348 -0. 01510

200.0 665.800 171.418 9.6049 -0. 01*78

202.0 684.981 173.348 9,5757 -0.01448

METHANE ISOCHOR E 25.0 MOL/L

T,K P,8AR OP/ 30 DP/OT D2P/DT2

126.® 5.050 128.311 12.8973 -0. 05794

128.0 30.730 130.935 12.7840 -0.05544

130.0 56.189 133.522 12.6755 -0. 05308

132.0 81.435 136.073 12.5715 -0. 05086

134.0 106.478 138.592 12.*719 -0. 0*876

136.0 131.326 141.079 12. 3764 -0. 04b7 8 138.® 155.986 1*3.537 12. 284b -0.0*490

140.0 180.467 1*5. 966 12.1967 -0. 04313

142.0 204.776 1*8. 369 12. 1122 -0. 04145

144.0 228.91® 150.746 12.0309 -0. 03987

146.0 252.901 153. 099 11.9526 -0. C3837

148.0 276.731 155. *29 11.8773 -0. 03695

150.6 300.412 157. 737 11. 8048 -0. 03560

152.0 323.952 160.024 11.7349 -0. 03432

154.0 347.354 162.2 31 11.6675 -0.0331

156.0 370.623 164.538 11.6024 -0. 03196

158.0 393.765 166.768 11.5396 -0. 03087

160.0 41to. 763 168.979 11.4789 -U. C 2 98 4 162.0 439.682 17 1. 174 11. 4202 - 0. 02866

164.0 462.4t>5 173.352 11.3634 -0. 02793

166.0 485.137 175.515 11.3085 -0. 02704

163.0 507.700 177. 6o3 11.2552 -0. G2b20

170.0 530. 159 179. 796 11. 20 36 -0. 02540

172.0 552.515 181.916 11. 1536 -0. 02464

17*. 0 57*. 774 134.022 11. 1050 -0. G 2 39

1 7© • 0 596.937 136.115 11.0579 -0. 02323

178.0 619.006 188.196 11. 0121 -0. 02257

130.0 640.986 130.264 10. 9676 -0. 02195

182.0 662.878 132. 321 10. 9243 -0.02136

184.0 684.664 134.367 10.8821 -0. 0 2 08 C

111
METHANE ISOCHORE 26.0 MOL/L

T,K P>SAR OP/DD OP/DT 02P/0T2

116.0 10.520 161.524 14.9191 -0.08420

117.0 25.39® 162. 820 14.8360 -0. 08213

116.0 40.193 164.108 14.7549 -0. 08012

119.0 54.90® 165.397 1%. 6757 -0. 07818

120.0 69.545 1 6 6 . 6 5 8 14.5985 -0.07630

121.0 84.106 167.921 14.5231 -0. 0744®

122.0 96.592 169.177 14.4495 -0. 07272

123.0 113.005 170.425 14.3776 -0.07102

12%.

0

127.34® 171.665 14.3075 -0.06936

125.0 141.621 172.899 14. 2389 -0. 06776

126.0 155.826 174.125 14.1719 -0. 06621

127.0 169.965 175.345 14. 1064 -0. 06471

123.0 184.039 176.55® 14.0425 -0. 06326

129.0 198.050 177.765 13.9799 -0.06184

130.0 212.000 178.966 13.9168 -0.06047

131.0 225. 88® 180.161 13.8590 -0. 05915

132.0 239.718 181.350 13. 8005 -0. 05786

133.0 253.490 182.533 13.7432 -0. 05661

134.0 267.205 133.710 13.6872 -0. 05539

135.0 280.865 134.333 13.6324 -0.05422

136.0 294.470 186. 049 13.5788 -0. 05307

137.0 308.023 137.211 13.5263 -0. 05196

133.0 321.523 138.366 13.4748 -0. 05089

139.0 334.973 139.520 13.4245 -0.04984

140.0 348.372 190.667 13. 3752 -0. 04882

141.0 361.723 191.809 13. 3268 -0. 04784

142.0 375.026 192.947 13.2795 -0.04688

143.0 338.283 194.030 13.2331 -0.04594

144.0 401.493 195-209 13. 1876 -0.04504

145.0 414.658 196. 334 13.1430 -0.04416

146.0 427.779 197.454 13.0993 -0. 0%330

147.0 440.857 198.571 13.0564 -0. 0%247

148.0 453.892 199. 683 13.0143 -0.04166

149.0 466.886 200.792 12.9731 -0. 04087

150.0 479.838 201.397 12.9326 -0. 04010

151.0 492.751 232. 998 12.8928 -0. 03936

152.0 505.624 204.095 12.8539 -0. 03863

153.0 513.459 235.199 12.8156 -0. 03793

154.0 531.256 206.230 12.7780 -0.03724

155.0 5%4.0 15 207.367 12.7411 -0. 03657

156.0 556.733 238.450 12.7048 -0. 03592

157.0 569.425 239.531 12.6692 -0. 03^29

153.0 532.077 210.638 12.6343 -0.03467

159.0 594.694 f 211.632 12. 5999 -0. 03407

160.0 607.277 212.753 12.5661 -0. 03349

161.0 619.826 213.821 12.5329 -0.03292

162.0 632. 3%3 214.335 12.5003 -0. 03236

163.0 644.827 215. 947 12.4682 -0. 03182

164.0 657.279 217. 307 12.4366 -0. 03130

165.0 669.701 218.053 12.4056 -0. 03078

166.0 632.091 219.116 12.3751 -0. 03029

167.0 694.451 220.15

7

12. 3450 -0. C2980

112
METHANE ISOCHORE 27.0 MOL/L

TfK P»8AR OR/OD OP/DT 02P/0T2

105. © 13.940 23Q.2S6 17. 3004 -0.12219

106,0 31.180 201.475 17.1799 -0.11881

107.0 48,301 232.657 17.0628 -0.11556

108.0 65.307 203. @34 16. 9488 -0. 11242

109.0 @2.200 235. 005 16.8379 -0.10940

110.0 98.983 206.170 16.7299 -0. 10648

111.0 115.661 207.329 16.6249 -0. 10367

112.0 132.234 208.494 16.5226 -0.10096

113.0 148.707 209.633 16.4229 -0. 09834

114.0 165.081 210.777 16.3259 -0. 09581

115.0 181.359 211.916 16. 2313 -Q. 09337

116.0 197.544 213.050 16.1391 -0. 0910

117.0 213.638 214. 190 lb. 0492 -0. 08873

118.0 229.643 215.336 15.9616 -0. 08653

119.0 245.562 216.427 15.8762 -0. 08440

120.0 261.396 217.544 15.7928 -0.08234

121.0 277.14® 218.657 15.7115 -0. 08035

122.0 292.820 219.767 15.6321 -0. 07842

123.0 308.413 220.872 15.5546 -0. 07655

124.0 323.930 221. 974 15.4790 -0.07475

125.0 339.372 223.072 15.4051 -0. 07300

126.0 354. 741 224. 156 15. 3329 -0.07131

127.0 370.03® 225.257 15.2625 -0. 06967

128.0 385.266 226.3 45 15. 1936 -0.06808

129.0 400.426 227.^29 15.1263 -0. 06654

130.0 415.519 228.511 15. 0605 -0. 06505

131.0 430.547 229.599 14.9962 - 0 . 06 360

132.0 445.512 230. 655 14.9333 -0. 06220

133.0 460.414 231. 737 14.8718 -0. 06084

134.3 475.256 232.807 14. 6116 -0. 05952

135.0 490.03® 233.873 14.7527 -0. 05824

136.0 504.762 254.938 14.6951 -0. 05700

137® i 519.429 235. 199 14.6367 -0. 05579

138.534.040 237.056 14.6835 -0. 05462

139.0 548.596 238. 114 14. 5294 -0. 05349

140.3 563.099 ' 239.168 14.4765 -0. 05239

141.0 577.549 2^0.220 14.4247 -0.05132

142.0 591.94® 2*1. 2o9 14.3739 -0. 05028

143.0 606.297 242. 316 14. 3241 -0. 04927

144.0 620.59? 243. 351 14.2753 -0. 04829

145.0 6 34 . @4 8 244.403 14.2275 -0.04733

146.0 649.052 245. 444 14.1306 -0. 04641

147.0 663.210 246. 492 14. 1347 -0. 04550

148.0 677.322 247.516 14. C896 -0. 0 4h6 3 149.0 691.389 2 + 8. 552 14.0454 -0.04376

1 1 3
METHANE ISOCHORE 27.5 MOL/L

T»K P * BAR OP/DD OP/OT 02P/0T2

99.0 11.423 221.454 18.6804 -0. 14843

100.0 30.030 222.533 18.5342 -0.14406

101.8 48.493 223.639 18.3922 -0.13986

102.0 66.816 224.680 18.2544 -0. 13582

103.0 85.003 225.7*8 18.1205 -0. 13194

104.0 103.058 226.813 17.9904 -0. 12821

105.0 120.985 227.875 17. 8640 -0. 12461

106.0 138.787 228.933 17.7412 -0.12115

107.0 156.469 229.988 17.6217 -0. 11782

108.0 174.032 231.041 17.5055 -0. 11461

109.0 191.481 232. 090 17. 3924 -0. 11151

110.0 208.818 233.137 17.2824 -0. 10853

111.0 226.046 234. 181 17. 1754 -0. 10565

112.0 243.169 235.223 17.0711 -0. 10287

113.0 260.190 236.262 16.9696 -0. 10019

114.0 277.110 237.298 16.8707 -0.09760

115.0 293.932 238.333 16.7744 -0.09511

116.0 310.659 239.365 16.6805 -0. 09269

117.0 327.294 2*0.395 16.5889 -0. 09036

118.0 343.838 2*1. *23 16.4997 -0.08811

119.0 360.294 242. 449 16.4127 -0.08593

120.0 376.664 2*3.473 16.3278 -0. 08383

121.0 392.950 244. *95 16.2450 -0. 08179

122.0 409.154 245.515 16.1642 -0. 07982

123.0 425.279 2*6.534 16.0853 -0. 07792

124.0 441.326 2*7.551 16. 0083 -0.07608

125.0 457.296 2*8.566 15.9332 -0. 07*29

126.0 473.193 249.579 15. 8597 -0. 07256

127.0 489.016 250.5 91 15.7880 -0. 07089

128.0 504.769 251. 601 15. 7180 -0. 06927

129.0 520.453 252. 610 15. 6495 -0. 06770

130.0 536.069 25 3. 6 1

7

15.5825 -0.06618

131.0 551.618 ?54.623 15.5171 -0. 06470

132.0 567 • lu 3 255.628 15.4531 -0. 06327

133.0 582.525 256.631 15.3906 -0. 06188

1 3* . 0 597.885 257.632 15.3293 -0.06054

135.0 613.164 258. b33 15.2695 -0. 05923

136.0 628.424 259.032 15. 2109 -0. 05797

137.0 643.607 250.6 30 15.1535 -0. 05674

138.0 658.732 261.627 15.0974 -0. 05555

139.0 673.802 262.623 15.0424 -0.05439

1*0.0 688.817 263. 618 14. 9886 -0. 05327

114
METHANE ISOCHORE 28.0 MOl/L

T,K P » BAR DP/OD DP/DT D2P/DT2

93.0 11.234 2^3.870 20.1629 -0.17994

94. i 31.308 244. 778 19. 9858 -0. 17429

95.0 51.207 245.637 19.8142 -0. 16886

96.0 70.938 246.595 19.6479 -0. 16369

97.0 90.505 247.504 19.4868 -0. 15871

98.0 109.913 248.413 19. 3305 -0. 15393

99.0 129.167 249. 323 19.1788 -0.14934

100.0 148.272 250.233 19. 0317 -0.14493

101.0 167.232 251.143 18. 0889 -0. 14069

102.0 186.051 25 2. 054 18.7503 -0. 13662

103.0 204.734 252.965 18.6156 -0. 13270

104.0 223.284 253.876 18.4848 -0. 12893

105.0 241.705 254.738 18. 3577 -0. 12531

106.0 260.000 255. 700 18.2342 -0. 12182

107.0 278.174 256.613 18.1140 -0. 11846

108.0 296.230 257.526 17.9972 -0. 11522

109.0 314.170 25 8. 44 0 17.8836 -0.11210

110.0 331.998 259. 354 17.7730 -0. 10909

111.0 349.717 260.288 17.6654 -0. 10619

112.0 367.329 261.133 17.5606 -0. 10339

113.0 384.639 262.098 17.4586 -0. 10069

114.0 402.247 253. 014 17.3592 -0. 09808

115.0 419.556 263.930 17.2624 -0. 09556

116.0 436.773 264. 847 17.1680 -0.09314

117.0 453.895 265.764 17.0761 -0.09079

118.0 470.926 266.631 16.9864 -0. 08852

119.0 487.668 257.599 lb. 8990 -0. 08633

120.0 504.725 268.517 16.8137 -0. 08421

121.0 521.497 269.435 16.7306 -0. 08216

122.0 538.186 270. 354 16.6494 -0. 00018

123.0 554.796 271.274 16.5702 “0. 07826

124.0 571.327 272. 1 34 16. 4928 -0. 07641

125.0 587.782 273.114 16.4173 -0. 074b 1 126.0 604.163 274. 035 16.3436 -0. 07287

127.0 620.470 274.956 16.2716 -0.07119

128.0 636.70b 275.877 16. 2012 - 0 . 0 b95

129.0 652.873 276.799 16. 1325 -0. 06798

130.0 668.972 277.721 16.0652 -0. 06645

131.0 685.004 276.643 15.9995 - 0 • 0 6496

1 1 5
METHANE ISOCHORE 28.5 MOL/L

T*K Pf BAR DP/3D OP/OT 02P/DT2

96*0 200.967 273.049 20. 0519 -0.16 227

97.8 220.939 273.756 19.8921 -0.15732

98.0 240.753 274.457 19.7372 -0. 15258

99.0 260.415 275. 184 19.5869 -0. 14802

100.0 279.929 275.905 19.4411 -0. 14364

101.0 299.299 276.632 19.2996 -0. 13943

102.0 316.529 277.363 19.1622 -0. 13539

103.0 337.624 278. 099 19. 0288 -0. 13150

104.0 356.568 278. 839 18. 8991 -0.12776

105.0 375.^24 279.584 18.7732 -0. 12416

106.0 394.135 280.332 18.6508 -0. 12069

107.0 412.726 281.035 18.5318 -0. 11735

108.0 431.200 231.642 18.4160 -0. 11414

109.0 449.560 232.633 18. 3035 -0. 11104

110.0 467.606 233.368 18.1939 -0. 10806

111.0 485.948 284. 137 18. 0873 -0.10518

112.0 503.964 284.909 17.9835 -0. 10240

113.0 521.916 235.685 17.8825 -0. 09972

114.0 539.749 236.464 17.7840 -0. 09714

115.0 557.485 237.246 17.6882 -0.09464

116.0 575.126 288. 032 17.5947 -0. 09223

117.0 592.675 288.821 17.5037 -0. 08991

118.0 610.135 239.613 17.4149 -0. 08766

119.0 627.506 290.409 17.3283 -0. 08549

120.0 644.792 291.237 17.2439 -0. 08338

121.0 661.994 292. JOtt 17. 1615 -0.08135

122.0 679.116 292. 812 17.0812 -0. 07939

123.0 696.157 293.619 17. 0027 -0.07749

METHANE ISOCHORE 29.0 MOL/L

T »K P »BAR OP/0O DP/DT D2P/DT2

103.0 482.144 299.070 19. 3503 - 0. 12817

104.0 501.430 / 299.619 19.2239 -0.12452

105.0 520.593 300.177 19.1012 -0. 12101

106. 0 539.634 300. 7+2 18.9819 -0. 11763

107.0 558.558 301. 317 18. 8659 -0. 11437

108.0 577.367 30 1.8 99 18.7531 -0. 11124

109.0 596.065 302. +38 18.643+ -0. 10 822

110.0 614.655 303. 056 18. 5366 -0. 10530

111.0 633.139 3J3.6 90 18.4327 -0. 10 250

112.0 651.521 304.302 18.3316 -0. 09979

113.0 669.803 304.921 18.2331 -0. 09718

114.0 687.988 3J5.546 18.1372 -0. 09466

116
Table 11. Calculated P(p) isotherms

The following pages give P(p,) isotherms, as computed by the equation of state (6). The third column DP/DD is the isotherm slope (dP/dp ) in units of the bar and mol At . The

fourth column DP/DT is the isochore slope (dP/dT) in unite of the bar and kelvins . Remaining columns validate the analytical expressions used to compute derivatives of functions composing the equation of state.

These tables show that dP/dp is non-negative, and that it increases monotonically

with density to pressures about twice those used for adjusting the equation of state.

117
METHANE ISOTHERM 95.0 DEG. K

MOIL /L P,BAR DP/ DO DP/DT XB OXB/DD XC OXC/DO XD DXO/OD

27.0 3.195 236.390 19.6266 0.001 0.063 *0.003 -0.253 -0.000 -0.016

27.9 26.919 260.069 19.7214 0.007 0. 063 -0.029 -0.260 -0.002 -0.014

28.0 51.207 245.687 19.6142 0.013 0.063 -0.055 -0.268 -0.003 -0.013

20.1 76.05% 251.229 19.9030 0.020 0.063 -0.082 -0.276 -0.006 -0.012

28.2 101. 450 256.662 19.9878 0.026 0.063 -0.111 -0.284 -0.005 •0.010

28.3 127.386 262.030 20.0684 0.032 0.064 -0.139 -0.293 -0.006 -0.019

28 .4 153.852 267.258 20.1447 0.039 0. 064 -0.169 -0.302 -0.007 -0.008

METHANE ISOTHERM 100.0 DEG. K MOL/L P,8AR DP/DD OP/DT XB OX8/D0 XC DXC/DD XD OXO/OO

27.4 8.059 216. 886 16.4249 0.002 0.062 -0.008 -0.225 -0.001 -0.017

27.5 30.030 222.533 18.5342 0.006 0.062 -0.031 -0.232 -0.002 -0.016

27.6 52.565 226.159 16.6403 0.015 0.062 -0.054 -0.239 -0.004 -0.014

27.7 75.661 233.753 18.7432 0.021 0.062 -0.079 -0.246 -0.005 -0.013

27.8 99.314 239.304 18.6428 0.027 0.063 -0.104 -0.253 -0.006 -0.012

27.9 123.520 244.601 16.9390 0.033 0.063 -0.129 -0.260 -0.007 -0.010

28.0 146.272 250.233 19.0317 0.040 0.063 -0.156 -0.266 -0.006 -0.009

28.1 173.564 255.585 19.1210 0.046 0.063 -0.183 -0.276 -0.009 -0.008

28.2 199.366 260.645 19.2066 0.052 0.063 -0.211 -0.284 -0.010 -0.007

28.3 225.729 265.995 19.2886 0.059 0.064 -0.240 -0.293 -0.011 -0.006

28.4 252.581 271.022 19.3667 0.065 0. 064 -0.269 -0.302 -0.011 -0.005

26.5 279.929 275.905 19.4411 0.071 0.064 -0.300 -0.311 -0.012 -0.004

28.6 307.757 280.626 19.5115 0.078 0.064 -0.332 -0.321 -0.012 -0.004

28.7 336.048 265.169 19.5779 0.064 0.064 -0.364 -0.331 -0.012 -0.003

26.8 364.784 269.506 19.6403 0.091 0.064 -0.398 -0.341 -0.013 -0.002

METHAME ISOTHERM 105.0 DEG. K

MOL/L P,BAR OP/DO DP/DT XB OXB/OD XC DXC/DD XD DXO/OO

27.0 13.940 200. 286 17.3004 0.004 0.060 -0.013 -0.20 2 -0.001 -0.019

27.1 34. 245 205. 605 17.4164 0.010 0.061 -0.034 -0.20 7 -0.003 -0.017

27.2 55.101 211. 331 17.5338 0.016 0.061 -0.055 -0.213 -0.005 -0.015

27.3 76.511 216. 857 17.6466 0.022 0.061 -0.077 -0.219 -0.006 -0.014

27.4 98.472 222. 374 17.7567 0.028 0.062 -0.099 -0.225 -0.007 -0.013

27.5 120.965 227.875 17.8640 0.035 0.062 -0.122 -0.232 -0.009 -0.011

27.6 144.047 233. 350 17.9666 0.041 0.062 -0.145 -0.239 -0.010 -0.010

27.7 167.654 238.790 18. 0703 0.047 0. 062 -0.169 -0.246 -0.011 -0.009

27.8 191. 80 3 244. 184 18.1691 0.053 0. 063 -0.194 -0.253 -0.012 -0.006

27.9 216. 489 249. 521 18.2650 0.060 0.063 -0.220 -0.260 -0.012 -0.007

28.0 241. 705 254. 788 16.3577 0.066 0. 063 -0.246 -0.268 -0.013 -0.006

26.

1

267.444 259.973 18.4474 0.072 * 0.063 -0.274 -0.276 -0.013 -0.005

28.2 293.696 265. 061 18.5336 0.079 0.063 -0. 302 -0.284 -0.014 -0.004

28.3 323.452 270.036 18.6170 0.085 0.064 -0. 330 -0.293 -0.014 -0.003

28.4 347.699 274.883 18.6968 0.091 0.064 -0.360 -0.302 -0.015 -0.003

28 . 5 375. 424 279.584 18.7732 0.098 0.064 -0.391 -0.311 -0.015 -0.002

28.6 403.610 284.119 16.8461 0.104 0.064 -0.422 -0.321 -0.015 -0.001

28.

7

432.241 288.468 18.9155 0.110 0.064 -0.455 -0.331 -0.015 -0.001

28.8 461.297 292.610 18.9811 0.117 0.064 -0. 489 -0.341 -0.015 -0.000

26.9 490.756 296.521 19. 0431 0.123 0.064 -0.523 -0.352 -0.015 0.000

29.0 520.593 300.177 19.1012 0.130 0.064 -0.559 -0. 363 -0.015 0.001

29.

1

55J. 781 303.550 19. 1554 0.136 0. 064 -0.596 -0.374 -0.015 0.001

11 8
METHANE ISOTHERM 110.0 OEG K

MOL/L P.BAR OP/DD DP/DT XB OX 0 /DD xc DXC/OD XD DXD/OD

26.5 2.608 179.430 16.1222 0.001 0.059 - 0. 002 - 0.176 — 0.009 - 0.022

26.6 20.016 184.725 16.2479 0.006 0.059 - 0.020 - 0.101 “ 0.002 - 0.020

26.7 39.554 190. 052 16. 3716 0.012 0.059 - 0.038 - 0,106 - 0.004 - 0.018

26.8 58.827 195.405 16.4931 0,010 0.060 - 0.057 - 0.191 - 0.006 - 0.017

26.9 78.636 200.779 16.6126 0 o 024 0.060 - 0.076 - 0.196 - 0.007 - 0.015

27.0 98.983 206.170 16,7299 0.030 0.060 - 0.096 - 0.202 - 0.009 - Q .014

27.1 119.070 211.571 16.8451 0,036 0 . 061 - 0.116 - 0.207 - 0.010 - 0.012

27.2 141.296 216.975 16.9579 0.042 0 . 061 - 0.137 - 0.213 - 0.011 - 0.011

27.3 163.265 222.376 17 . 06 S 5 0.049 0.061 - 0. 159 “ 0.219 - 0.012 - 0.010

27.4 185.772 227.766 17.1767 0.055 0.062 - 0. 101 - 0.225 - 0.013 - 0.009

27.5 208.818 233.137 17.2824 0.061 0.062 - 0.204 - 0.232 “ 0.014 - 0.008

27.6 232.399 233.479 17.3857 0.067 0.062 - 0.220 - 0.239 - 0.915 - 0.007

27.7 256.512 243.783 17.4865 0.073 0.062 - 0.252 - 0.246 - 0 . C 15 - 0.006

27.8 281.154 249.030 17.5047 0 . 0 ®i 0.063 - 0.277 - 0,253 - 0.016 - 0.005

27.9 306.318 254.232 17.6802 0.006 0. 063 - 0. 302 - 0.260 - 0.016 - 0.004

28.0 331.998 259.354 17.7730 0.092 0.063 - 0.329 - 0.260 - 0.017 - 0.00 3 28.1 358.186 264.369 17.8630 0.093 0.063 - 0. 356 - 0.276 - 0.017 - 0.002

28.2 384.872 269.325 17.9502 0.105 0.063 - 0.384 - 0.284 - 0.017 - 0.002

28.3 412. 047 274.144 18.0344 0.111 0.064 - 0. 413 - 0.293 - 0.017 - 0.001

28.4 439.697 278.831 10.1157 0.117 0.064 - 0.443 - 0.302 - 0.018 - 0.001

28.5 467.808 283.368 18.1939 0.124 0 . 064 - 0.473 - 0.311 - 0,018 - 0,000

28.6 496.365 287.736 18.2690 0.130 0.064 - 0.505 “ 0.321 - 0.018 0.09 0 28.7 525.349 291.914 13.3409 0.137 0.064 - 3.537 “ 0. 331 - 3.017 0.001

2 8.8 554.741 295.861 18.4095 0.143 0.064 - 0.571 “ 0.341 - 0.017 0.00 1 28.9 584.517 299.613 16.4748 0.150 0.064 - 0.606 - 0.35 2 - 0.017 0.002

29.0 614.655 303.066 18.5366 0.156 0.064 - 0. 641 - 0.363 - 0.017 0.002

29.1 645.125 306.272 18.5950 0.162 0.064 - 0.678 - 0.374 - 0.017 0.002

29.2 675 . 09 ® 309.143 18.6497 0.169 0.064 - 0. 716 • 0 o 3 ® & - 0.017 0.003

METHANE ISOTHERM 115.0 DEG . K

MOL/L P.BAR DP/DD DP/DT XB DXB/OD XC DXC/DO XD DXD/DO

0.1 0.929 9.007 0.0085 0.026 - 0.674 - 0.075 2.022 - 0.058 1.415

26.1 11.830 165.222 15.1346 0.004 0.057 - 0.010 - 0.159 - 0.001 - 0.023

26.2 28.605 170.271 15.2633 0.009 0.057 - 0. 026 - 0.163 - 0.004 - 0.021

26.3 45.886 175.363 15.3904 0.015 0.058 - 0.043 - 0.167 - 0.006 - 0.019

26.4 63.679 160.496 15.5158 0.021 0.058 - 0.060 - 0.172 - 0.000 - 0.018

26 . 5 81.986 165.665 15.6395 0.027 0.059 - 0.077 - 0.176 - 0.009 - 0.016

26.6 100.613 190.667 15.7615 0.033 0.059 - 0.095 - 0 . 181 - 0.011 - 0.015

26.7 120.161 196 . 09 ® 15. 6817 0.039 0.059 - 0.113 - 0.186 - 0.012 - 0.013

26.8 140.033 201.353 16.0001 0.045 0.060 - 0.132 - 0.191 - 0.013 - 0.012

26.9 160.432 206.628 16.1166 0.051 0.060 - 0. 151 - 0.196 - 0.014 - 0.011

27.0 181.359 211.916 16.2313 0.057 0.060 - 0.171 - 0.202 - 0.015 - 0.009

27.1 202.815 217.212 16.3440 0.063 0.061 - 0.192 - 0.207 - 0.016 - 0.008

27.2 224.602 222.509 16.4547 0.069 0.061 - 0.213 - 0.213 - 0.017 - 0.007

27.3 247.317 227.800 16.5634 0.075 0.061 - 0.234 - 0.219 - 0.018 - 0.006

27.4 270.361 233.078 16.6699 0 . 0 S 1 0.062 - 0.257 - 0.225 - 0.018 - 0.005

27.5 293.932 238 . 333 16.7744 0.087 0.062 - 0.279 - 0.232 - 0.019 - 0.004

27.6 318. 027 243.557 16.3766 0.093 0.062 - 0.303 - 0.239 - 0.019 - 0.004

27.7 342.642 248.740 16.9765 0.100 0 . 062 - 0. 327 - 0.246 - 0.020 - 0.003

27.8 367.773 253.871 17.0742 0.106 0.063 - 0. 352 - 0.253 - 0.020 - 0.002

27 . 9 393.414 258.938 17.1695 0.112 0.063 - 0. 378 - 0.260 - 0.020 - 0.001

28.0 419.558 263.930 17.2624 0.118 0.063 - 0.404 - 0.268 - 0.020 - 0.001

28.1 446.197 268.833 17.3527 0.125 0.063 - 0.431 - 0.276 - 0.020 - 0.000

28.2 473.321 273.632 17.4406 0.131 0 . 063 - 0.459 - 0.284 - 0.020 0.000

28.3 500.919 278.311 17.5258 0.137 0.064 - 0.488 - 0 . 29 3 - 0.020 0.00 1 28.4 528.979 262.856 17.6083 0.144 0.064 - 0.518 - 0.302 - 0.020 0.001

28.5 557.485 287.246 17.6882 0.150 0.064 - 0.549 - 0.311 - 0.020 0.002

28.6 586.422 291.464 17.7652 0.157 0 . 064 - 0.580 - 0.321 -0 .020 0.002

28.7 615.772 295.489 17.0393 0.163 0.064 - 0.613 - 0.331 - 0.019 0.002

28.8 645.513 299.299 17,9105 0.169 0.064 - 0.646 - 0.341 - 0.019 0.00 3 28.9 675.624 302.871 17.9787 0.176 0.064 - 0.681 - 0.352 - 0.019 0.00 3
METHANE ISOTHERM 120.0 DEG * K MOL/L P , 0 AR DP/ 00 OSVDT xe 0 X 0/00 xc OXC/DO XD DXO/OU

0 . 1 0.971 9,442 0.0065 0 . 052 — 0.674 - 0.144 2.022 - 0.107 1.219

0.2 1.006 9. 696 0.0174 o , om - 0.400 - 0.003 1 . 012 - 0.003 0.921

29.6 6.756 147.421 14.0813 0.002 0.055 - 0.005 - 0.140 - 0.001 - 0.025

25.7 21.734 152.153 14.2125 0.007 0 . 056 - 0.019 - 0.143 - 0.003 - 0.024

25.0 37.109 156.930 14.3424 0.013 0.036 - 0.033 - 0.147 - 0.006 - 0.022

25.9 53.124 161.774 14.4711 0.019 0.056 - 0.040 - 0.151 - 0.000 - 0.020

26.0 69.545 166.658 14.5985 0.024 0.057 - 0, 063 - 0.155 - 0.010 - 0.016

26 . 1 66.457 171.569 14.7245 0.030 0.057 - 0.079 - 0.159 • 0.011 - 0.017

26.2 103.064 176.564 14.8492 0.036 0.057 - 0.095 - 0.163 - 0.013 - 0.015

26 . 3 121.771 181.561 14.9724 0.041 0.058 - 0.112 - 0.167 - 0.014 - 0.014

26.4 140.162 166.635 15.0943 0.047 0.058 - 0.129 - 0.172 - 0.016 - 0.013

26.5 159.099 191.724 15.2146 0.053 0 . 059 - 0.146 - 0.176 - 0.017 = 0.011

26.6 173.526 196.644 15.3334 0.059 0.059 - 0.164 - 0.181 - 0.018 - 0.010

26 . 7 190.469 201.991 15.4507 0.065 0.059 - 0.182 - 0.186 - 0.019 - 0.009

26.0 216.927 207.161 15.5664 0,071 0.060 - 0.201 - 0.191 - 0.020 - 0.008

26.9 239.902 212.347 15.6804 0.077 0 . 060 - 0.220 - 0.196 - 0.021 - 0.007

27.0 261.396 217.544 15.7928 0.083 0.060 - 0.240 - 0.202 - 0.021 - 0.006

27.

1

263.411 222.747 15.9034 0.089 0 . 061 - 0.261 - 0.207 - 0.022 - 0.005

27.2 305.946 227.949 16. 0123 0.095 0 . 061 - 0.282 - 0.213 - 0.022 - 0.004

27.3 329.001 233.143 16.1194 0.101 0.061 - 0.303 - 0.219 - 0.023 - 0.003

27.4 352.574 238. 320 16.2245 0.107 0 . 062 - 0.326 - 0.225 - 0.023 - 0.002

27.5 376.664 243.473 16. 3278 0.113 0.062 -0.348 - 0.232 - 0.023 - 0.002

27.6 401.267 246.592 16.4291 0.120 0.062 -0.372 - 0.239 - 0.023 - 0.001

27.7 426.361 253.667 16.5284 0.126 0 . 062 - 0.396 - 0.246 - 0.023 - 0.000

27.0 451.999 258.687 16.6257 0.132 0.063 - 0.421 - 0.253 - 0.023 0.000

27.9 478.116 263.641 16.7208 0.138 0.063 - 0.447 - 0.260 - 0.023 0.001

20.0 504. 725 268.517 16.8137 0.145 0.063 - 0.473 - 0.268 - 0.023 0.001

26.1 531.616 273. 300 16.9044 0.151 0.063 - 0.500 - 0.276 - 0.023 0.002

20.2 559.361 277.977 16.9929 0.157 0.063 - 0.528 - 0.284 - 0.023 0.002

23.3 587.408 282.532 17.0790 0 . 164 0 . 064 - 0.557 - 0.293 - 0.023 0.003

26.4 615.883 286.948 17.1627 0.170 0.064 - 0.567 - 0.302 - 0.022 0.003

28.5 644.792 291 . 2 C 7 17.2439 0.176 0.064 - 0.618 - 0.311 - 0.022 0.003

20.6 674.118 295.290 17. 3226 0.183 0.064 - 0.649 - 0.321 - 0.022 0.004

METHANE ISOTHERM 130.0 OEG . K

MOL/L P .BAR DP/ DO DP/DT X8 OXB/DO XC OXC/OD XD OXD/OO

0.1 1.056 10 . 3 C 7 0.0065 0.105 - 0.674 - 0.266 2.022 - 0.162 0.937

0.2 2.061 9.800 0.0173 0.054 - 0.400 - 0.126 1.012 - 0.104 0.678

0.3 3.016 9.294 0.0264 0.020 - 0.294 - 0.044 0.671 - 0.042 0.587

24.6 6.139 116.881 12. 1560 0.001 0.051 - 0.002 - 0.110 - 0.001 - 0.031

24.

7

18.031 120.954 12.2869 0.006 0 . 052 - 0.013 - 0.113 - 0.004 - 0.029

24.

8

30.332 125. 066 12.4171 0.011 0.052 - 0.025 - 0.116 - 0.006 - 0.027

24.9 43.050 129.275 12.5466 0.017 0 . 052 - 0.037 - 0 . 118 - 0.009 - 0.025

25.0 56.189 133.522 12.6755 0.022 0 . 053 - 0.049 - 0.121 - 0.011 - 0.023

25.1 69.756 137.625 12 . 8035 0.027 0.053 - 0. 061 - 0. 124 - 0.014 - 0.021

25.2 83.756 142.185 12.9308 0.033 0.054 - 0.073 - 0.127 - 0.016 - 0.020

25 . 3 98.195 146.600 13.0574 0.038 0.054 - 0.086 - 0.130 - 0.017 - 0.016

25.4 113.078 151.070 13.1831 0.043 0.054 - 0.099 - 0.133 - 0.019 - 0.016

25.5 128.410 155.593 13.3079 0.049 0.055 - 0.113 - 0.137 - 0.021 - 0.015

25.6 144. 198 160.169 13.4319 0.054 0.055 - 0.127 - 0.140 - 0.022 - 0.014

25.7 160. 446 164.796 13.5551 0.060 0.056 - 0.141 - 0.143 - 0.024 - 0.012

25.8 177.159 169.472 13.6772 0.065 0 . 056 - 0.155 - 0.147 - 0.025 - 0.011

25.9 194.342 174. 196 13.7985 0.071 0 . 056 - 0.170 - 0.151 - 0.026 - 0.010

26.0 212.000 178.966 13.9188 0.077 0.057 - 0. 186 - 0.155 - 0.027 - 0.009

26.1 230.137 183.779 14.0380 0.082 0.057 - 0.201 - 0.159 - 0.027 - 0.008

26.2 248.757 186.633 14. 1563 0.088 0.057 - 0.217 - 0.163 - 0.028 - 0.007

26.3 267.864 193.524 14.2734 0.094 0.058 - 0.234 - 0.167 - 0.029 - 0.006

26.4 287.463 198. 450 14. 3894 0.100 0.056 - 0.251 - 0.172 - 0.029 - 0.005

26.5 307.555 203.408 14.5043 0 . 105 0.059 - 0.268 - 0.176 - 0.030 - 0.004

26.6 328.145 208 . 39

2

14.6181 0.111 0.059 - 0.286 - 0.181 - 0.030 - 0.003

26.7 349.235 213.400 14.7306 0.117 0.059 - 0.304 - 0.186 - 0.030 - 0.002

26.0 370.826 216. 426 14.8419 0.123 0.060 - 0. 323 - 0.191 - 0.030 - 0.001

26.9 392.920 223.465 14.9518 0.129 0.060 - 0. 343 - 0.196 - 0.031 - 0.001

27.0 415.519 228.511 15.0605 0.135 0.060 - 0. 362 - 0.202 - 0.031 0.000

27.1 438.62 3 233.558 15.1678 0.141 0.061 - 0.383 - 0.207 - 0.031 0.001

27.2 462.231 238.600 15.2737 0.147 0.061 - 0.404 - 0.213 - 0.030 0.001

27.3 466.342 243.630 15.3781 0.153 0.061 -0.426 - 0.219 - 0.030 0.002

27.4 510.956 248.636 15.4811 0.160 0.062 - 0.446 - 0.225 - 0.030 0.002

27.5 536.069 253.617 15.5825 0.166 0.062 - 0.471 - 0.232 - 0.030 0.003

27.6 561.678 258.556 15.6824 0.172 0.062 - 0.494 - 0.239 - 0.030 0.003

27.7 587.779 263.450 15.7807 0.178 0.062 - 0.518 - 0.246 - 0.029 0.004

27.8 614.366 268.282 15.6772 0.184 0.063 - 0.543 - 0.253 - 0.029 0.004

27.9 641. 433 273.043 15.9721 0 . 191 0.063 - 0.569 - 0.260 - 0.028 0.004

28.0 668.972 277.721 16. 0652 0.197 0 . 063 - 0.595 - 0.268 - 0.028 0.005

26.1 696.974 282.301 16.1566 0.203 0 . 063 - 0.623 - 0.276 - 0.027 0.005

120
H£ THANE ISOTHERM 140.0 DEG . K

HOE /L 0P/DD op/m X 8 DXB/DD XC DXC/OD XD DXO/DO

9.1 1.448 11.167 0.0084 0.157 - 0.674 - 0.371 2.022 - 0.238 0.743

0.2 2.233 10.693 0.0172 0.106 - 0.400 -0.230 1.012 - 0.177 0.522

0.3 3.279 10.221 0.0262 0.072 “ 0.294 - 0.146 0.671 - 0.129 0.440

0 .4 4. 27 i 9.749 0.0356 0.046 - 0.237 - 0.091 0.499 - 0.086 0.398

0.5 5.229 9.275 0.0453 0.024 - 0.199 - 0.046 0.395 - 0.049 0.376

0.6 6.132 8.799 0.0554 0.006 - 0.173 - 0,011 0.326 - 0.012 0.364

23.6 14.059 92.469 10 • 4649 0.004 0.047 - 0.008 - 0.088 - 0.003 - 0.035

23.7 24.269 95.925 10.5908 0.009 0.048 - 0.017 - 0.090 - 0.007 - 0.033

23.0 34.037 99.436 10.7164 0.014 0.048 - 0.026 - 0.092 - 0.010 - 0.031

23.9 44.&5S 103® 004 10.0418 0.019 0.048 - 0.036 - 0.094 - 0.013 - 0.029

24.0 54.639 106.627 10.9660 0.024 0.049 - 0. 045 - 0.096 - 0.016 - 0.027

24.1 65.465 110 . 30 © 11.0915 0.028 0.049 - 0.055 - 0.099 - 0.018 - 0.025

24.2 76.703 114. 044 11.2159 0.033 0 . 050 - 0.065 - 0. 101 - 0.021 - 0.023

24.3 66.296 117.037 11.3399 0.038 0.050 - 0.075 - 0.10 3 - 0.023 - 0.021

24.4 100.272 121.687 11,4636 0.043 0.050 - 0.085 - 0.105 - 0.025 - 0.020

24.5 112.635 125.593 11.5869 0.048 0.051 - 0.096 - 0.108 - 0.027 - 0.018

24.6 125.392 129.556 11.7097 0.054 0.051 - 0.107 - 0.110 - 0.028 - 0.017

24.7 130.549 133.575 11.8322 0.059 0 • 0 5 < - 0. 118 - 0.113 - 0.030 - 0.015

24.6 152.109 137.650 11.9542 0.064 0.052 - 0. 130 - 0.116 - 0 . 03 ?

- 0.014

24.9 166.000 141.780 12.0757 0.069 0.052 - 0.141 - 0.118 - 0.033 - 0.013

25.0 100. 467 145.966 12.1967 0.074 0.053 - 0.153 - 0.121 - 0.034 - 0.011

25.1 195.275 150 . 2 C 7 12.3173 0.080 0.053 - 0.166 - 0.124 - 0.035 - 0.010

25.2 210.510 154.501 12.4373 0.085 0.054 - 0. 178 - 0.127 - 0.036 - 0.009

25.3 226.177 158.848 12.5567 0.090 0.054 - 0. 191 - 0.130 - 0.037 - 0.008

25.4 242.262 163.248 12.6756 0.096 0.054 - 0.204 - 0.133 - 0.038 - 0.007

25.5 256.829 167.698 12.7938 0.101 0.055 - 0.218 “ 0.137 - 0.038 - 0.006

25.6 275.823 172. 199 12.9115 0.107 0.055 - 0.231 - 0.140 - 0.039 - 0.005

25.7 293.270 176. 748 13.0284 0.112 0.056 - 0.246 - 0 . 143 - 0.039 - 0.004

25.6 311.174 181. 343 13.1447 0.118 0.056 “ 0. 260 - 0.147 - 0,040 - 0.00 3 25.9 329.540 185.984 13.2603 0.123 0.056 “ 0.275 - 0.151 - 0.040 - 0.002

26. 0 348. 372 190.667 13.3752 0.129 0.057 - 0.290 - 0.155 - 0.040 - 0.001

26.1 367. 675 195. 390 13 . 409 .'? 0.135 0.057 - 0.306 - 0.159 - 0.040 - 0.000

26.2 307.452 200.151 13.60 25 0.141 0. 057 - 0.322 - 0.163 - 0.040 0.000

26 . 3 407. 706 204.947 13.7150 0.146 0.058 - 0. 339 - 0.167 - 0.040 0.00 1 26.4 420.442 209.774 13 . 826-6 0.152 0.058 - 0.356 - 0 . 17 ?

- 0.040 0.00 2 26 . 5 449.662 214.629 13.9373 0.158 0.059 - 0. 373 - 0.176 - 0.040 0.00 2 26.6 471.369 219 . 5 C 8 14 . 047a 0.164 0.059 - 0.391 - 0.181 - 0.039 0.00 3 26.7 493.564 224.406 14 . 15(60 0.170 0.059 - 0. 409 - 0.186 - 0.039 0.00 3 26.8 516.250 229.319 14.26 38 0.176 0.060 - 0. 428 - 0 . 191 - 0.039 0.00 4 26.9 539.426 234.242 14.3707 0.182 0.060 - 0.447 - 0.196 - 0.038 0.004

27.0 563. 099 239.168 14.4765 0.188 0.060 - 0.467 - 0 . 20 ? - 0.038 0.005

27.1 567.262 244.092 14 . 58H 2 0.194 0.061 - 0.480 - 0.207 - 0.037 0.005

27.2 611.917 249. 007 14 . fec’146 0.200 0.061 - 0.509 - 0.213 - 0.037 0.005

27.3 637.063 253 . 9 C 5 14.7073 0.206 0.061 - 0.530 - 0.219 - 0.036 0.00 6 27.4 662.697 258. 778 14 . 80 86 0.212 0.062 - 0.552 - 0.225 - 0.036 0 . C 06

27.5 688.817 263.618 14.9086 0.218 0.062 - 0.575 - 0.232 - 0 . C 35 0.006

121
METHANE ISOTHERM 150.0 DFG . K

MOt /L P.SAft DP/OO OP/DT XS 0 X 8/00 XC DKC/DO XD OXD/DD

0,2 2,405 11.577 0.0171 0.159 • 0,400 - 0.321 1.012 - 0.231 0.413

0.4 4.632 10.693 0.0353 0.096 - 0.237 - 0.181 0.499 - 0.162 0.302

0.6 6.68 2 9 . 810 0.0546 0.058 - 0.173 - 0.101 0.326 - 0.106 0.265

0.8 8.556 6.931 0.0752 0.027 - 0.130 - 6.046 0.238 - 0.055 0.251

1.0 10.255 8.062 0.0971 0.002 - 0.114 - 0.004 0.186 - 0.005 0.248

22.4 15.442 67.547 8.7568 0.003 0.842 - 0. 005 - 0.069 - 0.003 - 0.041

22.6 29.514 73.205 8.9927 0.012 0.043 - 0.019 - 0.072 - 0.011 - 0.037

22.8 44.738 79.070 9.2287 0. 020 0.044 - 0.834 - 0.075 - 0.018 - 0.033

23.0 61.156 65.143 9.4647 0.029 0.045 - 0. 049 - 0.078 - 0.024 - 0.029

23.2 78.809 91.428 9.7007 0.038 0.045 - 0.065 - 0.081 - 0.029 - 0.025

23.4 97.741 97.927 9.9366 0.047 0.046 - 0.062 - 0.085 - 0.034 - 0.022

23.6 117.994 104.640 10.1723 0.057 0,047 - 0.099 - 0 . C 88 - 0.038 - 0.019

23.8 139.612 111.571 10.4076 0.066 0.048 - 0.117 - 0.092 - 0.042 - 0.016

24.0 162.637 118.719 10.6424 0.076 0.049 - 0.136 - 0.096 - 0.045 - 0.013

24.2 187. 114 126.067 10.8767 0.086 0.050 - 0.156 - 0.101 - 0.047 - 0.011

24.4 213. 086 133.673 11.1192 0.096 0.050 - 0.176 - 0 . 105 - 0.049 - 0.006

24.6 240.598 141.479 11. 3428 0.106 0.051 - 0.198 - 0.110 - 0.050 - 0.006

24.8 269.692 149.501 11.5744 0.116 0.052 - 0.220 - 0.116 - 0.051 - 0.004

25.0 300.412 157.737 11.8048 0.127 0.053 - 0.244 - 0.121 - 0.052 - 0.002

25.2 332.801 166.183 12.0338 0.137 0.054 - 0.269 - 0.127 - 0.052 - 0.001

25.4 366.899 174.832 12.2613 0.148 0.054 - 0.295 - 0.133 - 0.052 0.001

25.6 402.747 183.675 12.4870 0.159 0.055 - 0. 322 - 0.140 - 0.052 0.002

25.8 440.361 192.702 12.7109 0.170 0.056 - 0.351 - 0.147 - 0.051 0.004

26.0 479.838 201.897 12.9326 0.182 0.057 - 0.381 - 0.155 - 0.050 0.005

26.2 521.150 211.242 13.1520 0.193 0.057 -0.413 - 0.163 - 0.049 0.006

26.4 564. 344 220. 714 13.3688 0.205 0.058 - 0.446 - 0.172 - 0.046 0.006

26.6 609.442 230 . 2 e 6 13.5830 0.216 0.059 - 0.481 - 0.181 - 0.047 0.007

26.8 656.462 239.923 13.7941 0.228 0.060 - 0.519 - 0.191 - 0.045 0 . 008

METHANE ISOTHERM 160.0 DEG . K

MOL/L P ,BAR DP/DD OP/DT X 8 DXB/OO XC DXC/DD XD OXO/OD

0.2 2.576 12.456 0.0171 0.211 - 0.400 - 0.400 1.012 - 0.274 0.332

0.4 4.984 11.623 0.0351 0.151 - 0.237 - 0.261 0.499 - 0.219 0.235

0.6 7 . 225 10. 794 0.0541 0.110 - 0.173 - 0.181 0.326 - 0.176 0.200

0.8 9.302 9.974 0.0741 0.060 - 0.138 - 0. 125 0.236 - 0.138 0.163

1 . 0 11.216 9.160 0.0952 0.055 - 0. 114 - 0. 083 0.166 - 0.102 0.175

1.2 12.970 8.380 0.1174 0.033 - 0.098 - 0.050 0.151 - 0.067 0.172

1.4 14. 569 7.611 0.1409 0.015 - 0.085 - 0.022 0.126 - 0.033 0.173

21.0 16.794 44.644 7.0785 0.001 0.036 - 0.001 - 0.052 > 0.001 - 0.046

21.2 26.152 48.966 7.2916 0.008 0.037 - 0.012 - 0.054 - 0.010 - 0.044

21.4 36.393 53.476 7.5062 0.016 0.036 - 0.022 - 0.056 - 0.016 - 0.040

21.6 47.555 50.176 7.7218 0.023 0.039 -0.034 - 0.058 - 0.026 - 0.036

21.8 59.676 63.068 7.9384 0.031 0.040 -0.046 - 0.061 - 0.033 - 0.032

22.0 72. 795 68.154 8.1561 0.039 0.040 - 0.058 - 0.063 - 0.039 - 0.029

22.2 86.951 73.437 8.3747 0.047 0.041 - 0.071 - 0.066 - 0.044 - 0.025

22.4 102.183 78.919 8.5942 0.056 0.042 - 0.085 - 0.069 - 0.049 - 0.022

22.6 118.532 84.601 0.8144 0.064 0.043 - 0.099 - 0.072 - 0.053 - 0.019

22.8 136.037 90.465 9.0354 0.073 0.044 - 0.113 - 0.075 - 0.057 - 0.016

23.0 154.739 96.574 9.2570 0.082 0.045 - 0. 126 - 0.078 - 0.060 - 0.014

23.2 174.680 102.869 9.4790 0.091 0 . 045 - 0.144 - 0.081 - 0.062 - 0.011

23.4 195.901 109. 372 9.7015 0.100 0.046 - 0.161 - 0.085 - 0.064 - 0.009

23.6 218.443 116.084 9.9241 0.109 0.047 - 0.178 - 0.086 - 0.066 - 0.007

23.8 242.349 123. 007 10.1469 0.119 0.040 - 0.196 - 0.092 - 0.067 - 0.005

24.0 267.660 130. 141 10.3697 0 . 128 ' 0.049 - 0.215 - 0.096 - 0.068 - 0.003

24.2 294. 419 137.487 10.5924 0.138 0 . 050 - 0.235 - 0.101 - 0.068 - 0.001

24.4 322.669 145. 046 10.8148 0.148 0.050 - 0.256 - 0.105 - 0.068 0.001

24.6 352.451 152.816 11.0368 0.158 0 . 051 - 0.277 - 0.110 - 0.068 0 . 00 ? 24.8 383.809 160.794 11.2582 0.169 0.052 - 0.300 - 0 . 116 - 0.067 0 . 004

25.0 416.783 168.979 11.4789 0.179 0.053 - 0.323 - 0.121 - 0.066 0.005

25.2 451.414 177. 365 11.6987 0.190 0.054 - 0.348 - 0.127 - 0*065 0.006

25.4 487.742 185.946 11.9175 0.201 0.054 - 0.374 - 0.133 - 0.064 0.007

25.6 525.805 194.713 12. 1352 0.212 0.055 - 0.402 - Q . 14 0 - 0.062 0.008

25.8 565.639 203.653 12.3514 0.223 0.056 - 0.430 - 0.147 - 0.061 0.009

26.0 607.277 212.753 12.5661 0.234 0 . 057 - 0.460 - 0.155 - 0.059 0.009

26.2 650.749 221.992 12.7791 0.245 0.057 - 0.492 - 0.163 - 0.057 0.010

26.4 696.082 231.349 12.9902 0.257 0.058 - 0.526 - 0.172 - 0.055 0.010

122
METHANE ISOTHERM 170.0 OEG . K MOC/L P »BAR OP/DD DP/DT XB DXB/DD XC DXC/DD XD OXO/OO

0.2 2.746 13.330 0.0170 0.263 - 0.400 - 0.471 1.012 - 0.307 0.270

0.4 5.333 12.543 0.0349 0.203 - 0.237 - 0.331 0.499 - 0.264 0.184

0.6 7.764 11.762 0.0537 0.163 - 0.173 - 0.251 0. 326 - 0.230 0,153

O.S 10.039 10.990 0.0733 0.132 - 0.138 - 0.195 0.238 - 0.201 0.137

1.0 12.161 10.235 0.0939 0.107 - 0.114 - 0.153 0.186 - 0.175 0.127

1.2 14.134 9.499 0.1154 0.086 - 0.098 - 0. 120 0.151 - 0.150 0.122

1.4 15.962 8.785 0.1379 0.068 - 0. 085 - 0. 092 0.126 - 0.126 0.120

1.6 17.649 6.092 0.1614 0.051 - 0.076 - 0.069 0.107 - 0.102 0.119

1.0 19.200 7.419 0.1859 0.037 - 0.068 - 0.049 0.09 3 - 0.079 0.119

2.0 20.618 6.764 0.2115 0.024 - 0.061 - 0.032 0.081 - 0.055 0.120

2.2 21.907 6.124 0.2383 0.013 - 0.055 - 0.016 0.072 - 0.030 0.123

2.4 23.069 5.499 0.2664 0.002 - 0.050 - 0.003 0.064 - 0.006 0.126

19.4 24.017 26 . 1 C 5 5.5047 0.001 0.029 - 0.001 - 0.037 - 0.001 - 0.052

19.6 29.536 29.105 5.6661 0.007 0.030 - 0. 009 - 0.038 - 0.011 - 0.048

19.8 35.670 32.270 5.8735 0.013 0.031 - 0.016 - 0.040 - 0.021 - 0.044

20.0 42.455 35.602 6. 0608 0.019 0.032 - 0.025 - 0.042 - 0.029 - 0.041

20.2 49.923 39.106 6.2500 0.025 0.033 - 0.033 - 0.044 - 0.037 - 0.038

20.4 58.109 42.782 6.4412 0.032 0.034 - 0.042 - 0.045 - 0.044 - 0.035

20.6 67.047 46.636 6.6343 0.039 0.034 - 0. 051 - 0.047 - 0.051 - 0.031

20.8 76.775 50.668 6.8293 0.046 0.035 - 0.061 - 0.049 - 0.057 - 0.026

21.0 87.327 54.681 7.0261 0.053 0.036 - 0. 071 - 0.052 - 0.062 - 0.026

21.2 98.739 59.277 7.2246 0 . 060 0.037 - 0. 082 - 0.054 - 0.067 - 0.023

21.4 111.050 63. 858 7.4248 0.068 0.038 - 0. 093 - 0.056 - 0.071 - 0.020

21.6 124.295 68.625 7.6266 0.076 0.039 - 0.104 - 0.056 - 0.075 - 0.017

21.8 138.512 73.582 7.8299 0.083 0.040 - 0. 116 - 0.061 - 0.078 - 0.015

22.0 153.740 78.729 8.0346 0.091 0.040 - 0. 128 - 0. 063 - 0.081 - 0.013

22.2 170.017 64.068 8.2406 0.100 0.041 - 0.141 - 0.066 - 0.083 - 0.010

22.4 187.380 89.600 8.4479 0.108 0.042 - 0. 155 - 0.069 - 0.085 - 0.008

22.6 205.870 95.328 8.6563 0.116 0.043 - 0.169 - 0.072 - 0.087 - 0.006

22.8 225.525 101.254 8.8657 0.125 0.044 - 0.183 - 0.075 - 0.087 - 0.004

23 . 0 246. 384 107. 378 9.0761 0. 134 0.045 - 0.199 - 0.078 - 0.088 - 0.002

23.2 268.489 113.703 9.2872 0.143 0.045 - 0.214 - 0.081 - 0.088 - 0.000

23.4 291.879 120.229 9.4990 0.152 0.046 - 0. 231 - 0.085 - 0.088 0.001

23.6 316.594 126.959 9.7114 0.161 0.047 - 0.248 - 0.088 - 0.088 0.00 3 23.8 342. 676 133.894 9.9243 0.171 0.048 - 0.266 - 0.092 - 0.087 0.004

24.0 370.166 141 . 034 10.1374 0.181 0. 049 - 0 . 2 C 5

- 0.096 - 0.086 0.006

24.2 399.104 148. 379 10.3508 0.191 0.050 - 0.305 - 0.101 - 0.085 0.007

24.4 429.531 155.929 10.5642 0.201 0.050 - 0.326 - 0 . 105 - 0.083 0.008

24.6 461.489 163 . 684 10.7776 , 0.211 0.051 - 0.347 - 0.110 - 0.082 0.009

24.8 495.018 171.641 10.9908 0.221 0.052 - 0.370 - 0.116 - 0.080 0.010

25.0 530.159 179.796 11.2036 0.231 0.053 - 0. 393 - 0.121 - 0.078 0.011

25.2 566.950 188. 146 11.4160 0.242 0 . 054 - 0.418 - 0. 127 - 0.076 0.011

25.4 605.429 196.682 11.6277 0.253 0.054 - 0.444 - 0.133 - 0.073 0.012

25.6 645.634 205. 355 11.8387 0.264 0.055 - 0.472 - 0.140 - 0.071 0 . 01 ? 25.8 687.598 214.275 12. 0488 0.275 0.056 - 0.500 - 0.147 - 0.068 0.013

123
METHANE ISOTHERM 160.0 DEG. K

HOI /l P,8AR DP/DD DP/DT XB OXB/DO XC OXC/DO XD OXO/DD

0.5 7.009 13.065 0.0440 0.234 -0.199 -0.349 0.395 -0.285 0.129

1.0 13.095 11.275 0. 0930 0.159 -0. 114 -0.215 0.166 -0.232 0.093

1.5 16.305 9.568 0.1470 0.112 -0. 060 -0.142 0.116 -0.169 0.082

2.0 22.705 6.034 0.2063 0.077 -0.061 -0.094 0.061 -0.149 0.079

2.5 26.356 6.594 0.2709 0.050 -C. 046 -0.059 0. 060 -0.109 0.078

3.0 29.316 5.256 0.3412 0.028 -0. 039 -0.032 0.046 -0.070 0.060

3.5 31.630 4.014 0. 4176 0.010 -0.032 -0. 012 0.037 -0.029 0.063

17.5 36.109 12.746 4.0606 0.006 0.021 -0.006 -0.024 -0.014 -0.046

16.0 43.599 17.343 4.4278 0.017 0.023 -0.019 -0.027 -0.036 -0.041

16.5 53.591 22.770 4.6110 0.029 0.025 -0.033 -0.030 -0.055 -0.036

19.0 66.519 29.096 5.2109 0.042 0.027 -0.049 -0.034 -0.072 -0.030

19.5 62.649 36.385 5.6271 0.056 0.030 -0.067 -0.038 -0.065 -0.025

20.0 103.073 44.664 6.0590 0.071 0.032 -0.087 -0.042 -0.096 -0.019

20.5 127.706 54.036 6.5058 0.088 0.034 -0.109 -0.046 -0.105 -0.014

21 .

0

157.291 64. 477 6.9662 0.105 0.036 -0.133 -0.052 -0.111 -0.009

21.5 192.372 76.037 7.4390 0.124 0.038 -0. 160 -0.057 -0.114 -0.004

22.0 233.519 88.742 7.9227 0.144 0. 040 -0.191 -0.063 -0.115 -0.000

22.5 261.309 102.616 8.4160 0.164 0.043 -0.224 -0. 070 -0.114 0.004

23.

0

336.334 117.666 6.9172 0.166 0.045 -0.261 -0.078 -0.111 0.007

23.5 399.198 133.973 9.4247 0.209 0.047 -0. 302 -0.087 -0.107 0.010

24.0 470.514 151.496 9.9363 0.233 0.049 -0.348 -0.096 -0.101 0.012

24.5 550.903 170.268 10.4517 0.256 0.051 -0.399 -0.108 -0.095 0.014

25.0 640.966 190.264 10.9676 0.284 0.053 -0.456 -0.121 -0.087 0.015

METHANE ISOTHERM 190.0 DEG. K

MOL/L P » BAR OP/DD DP/DT XB 0X8/00 XC DXC/DD XO OXD/DO

0.5 7.448 14. 0 10 0.0436 0.286 -0.199 -0.405 0.395 -0.317 0.100

1.0 14.021 12.297 0.0922 0.211 -0.114 -0.271 0.186 -0.277 0.067

1.5 19.766 10.7C7 0.1452 0.164 -0. 080 -0.198 0.116 -0.247 0.056

2.0 24. 750 9.249 0.2026 0.129 -0.061 -0.150 0.061 -0.221 0.051

2.5 29.034 7. 907 0.2647 0.102 -0.046 -0.115 0.06 0 -0.196 0.046

3.0 32.674 6.666 0.3311 0.060 -0.039 -0. 088 0.046 -0.172 0.046

3.5 35.716 5.529 0.4016 0.062 -0.032 -0. 067 0.037 -0.150 0.045

4.0 38.220 4.496 0.4762 0.046 -0.026 -0.051 0.029 -0.128 0.043

4.5 40.233 3.575 0.5546 0.036 -0.021 -0. 036 0.023 -0.107 0.041

5.0 41.815 2. 772 0.6366 0.027 -0.017 -0.028 0.019 -0.087 0.039

5.5 43.024 2.064 0.7219 0.019 -0.014 -0.019 0.015 -0.066 0.037

6.0 43.917 1.504 0.6104 0.012 -0.011 -0.013 0.012 -0.050 0.035

6. 5 44.544 1. 021 0.9021 0.007 -0.009 -0.006 0.009 -0.033 0.033

7.0 44.952 0.623 0.9975 0.003 -0.007 -0.003 0.007 -0.017 0.031

7.5 45.160 0. 301 1.0996 0.000 -0. 005 -0. 000 0.005 -0.002 0.026

13.0 45.342 0.642 1.9949 0.001 0.005 -0.001 -0.005 -0.007 -0.024

13-5 45.606 1.254 2.1663 0.004 0.007 -0.004 -0.007 -0.019 -0.026

14. 0 46.636 2.106 2.3515 0.006 0.006 -0.008 -0.008 -0.032 -0.027

14.5 47.961 3. 247 2.5534 0.012 0.010 -0. 013 -0.010 -0.046 -0.027

15.0 49.939 4.729 2.7734 0.016 0.012 -0.016 -0.012 -0.059 -0.027

15.5 52.757 6.615 3.0126 0.024 0.013 -0.025 -0.014 -0.073 -0.027

16.0 56.632 8.971 3.2713 0.031 0.015 -0.032 -0.016 -0.086 -0.025

16.5 61.616 11.868 3.5500 0.039 0.017 -0.041 -0.019 -0.098 -0.024

17.

0

68.60 3 15. 380 3. 8467 0.046 0.019 -0. 051 -0.021 -0.110 -0.022

17.5 77.313 19.580 4.1672 0.058 0.021 -0.062 -0.024 -0.120 -0.019

16.0 88.310 24.540 4.5053 0.069' 0.023 -0.075 -0.027 -0.129 -0.017

16 .

5

101.991 30.329 4.8625 0.061 0.025 -0.069 -0.030 -0.137 -0.014

19.0 118.786 37. 0 C 6 5.2360 0.094 0.027 -0. 105 -0.034 -0.143 -0.010

19.5 139. 155 44.626 5.6310 0.106 0.030 -0. 123 -0.036 -0.147 -0.007

20.0 163.560 53.242 6.0404 0.123 0.032 -0. 143 -0.042 -0.150 -0.003

20.5 192.566 62.666 6.4653 0.140 0.034 -0.165 -0. 046 -0.150 0.000

21.0 226. 644 73.595 6.9044 0.157 0.036 -0.189 -0.052 -0.149 0.004

21.5 266.345 85.395 7.3563 0.176 0.036 -0.216 -0.057 -0.147 0.007

22.0 312.225 96. 312 7. 6199 0.196 0. 040 -0.246 -0.063 -0.143 0.010

22.5 364.847 112.369 8.2936 0.217 0.043 -0.260 -0.070 -0.137 0.012

23.0 424. 788 127.589 8.7761 0.230 0.045 -0.316 -0.076 -0.130 0.015

23.5 492.634 143.996 9.2658 0.261 0.047 -0.355 -0.087 -0.122 0.016

24.0 568.965 161.607 9.7611 0.285 0.049 -0.403 -0.096 -0.114 0.016

24.5 654.443 180.429 10.2604 0.310 0.051 -0.454 -0.106 -0.105 0.019

124
HE THAME ISOTHERM 200.0 DEG . K

MQL/L P,BAR DP/DD OP/DT X 8 OMB /DO XC QXC/QD XD OXO/QD

0.5 7.865 14.930 0.0437 0.338 - 0.199 - 0.455 0.395 - 0.344 0.077

1.0 14.940 13.305 0.0917 0.263 - 0.114 - 0. 321 0.186 - 0.315 0.047

1.5 21.211 11.001 0.1438 0.216 - 0.080 - 0.248 0.116 - 0.294 0.036

2.0 26.763 10.429 0.2001 0.181 - 0.061 - 0. 200 0.081 - 0.278 0.031

2.5 31.659 9.169 0.2604 0.154 - 0.048 - 0. 165 0.060 - 0.263 0.027

3.0 35.949 8.009 0.3245 0.132 - 0.039 - 0.138 0.046 - 0.250 0.025

3.5 39.663 6.944 0.3921 0.114 - 0.032 - 0.118 0.037 - 0.238 0.022

4.0 42.910 5.979 0.4629 0.100 - 0.026 - 0.101 0.029 - 0 .228 0.020

4.5 45.680 5.120 0 o 5366 0.066 - 0.021 - 0.088 0.023 - 0.219 0.017

5.0 46.046 4.369 0.6129 0.079 - 0.017 - 0. 078 0.019 - 0.211 0.015

5.5 50.067 3.724 0.6913 0.071 - 0.014 - 0. 070 0.015 - 0.204 0.012

6.0 51.789 3. 176 0.7713 0.065 - 0.011 - 0.063 0.012 - 0.198 0.010

6.5 53.259 2.717 0.8527 0.059 - 0.009 - 0.058 0.009 - 0.194 0.008

7.0 54 . 51 ® 2.330 0.9351 0.055 - 0.007 - 0.054 0.007 - 0.190 0.005

7.5 55.600 2.006 1.0184 0.052 - 0.005 - 0.050 0.005 - 0.188 0.003

e.o 56.538 1 . 759 1.1027 0.050 - 0.003 - 0.048 0.003 - 0.188 - 0.000

6.5 57.375 1.606 1.1664 0,049 - 0.001 - 0.047 0.001 - 0.189 - 0.003

9.0 56.164 1.569 1.2764 0.049 - 0.000 - 0.047 0 . Q 00 - 0.190 - 0.003

9.5 56.955 1.602 1.3676 0.049 - 0.000 - 0. 047 0.000 - 0.191 - 0.001

10.0 59.770 1.661 1.4629 0.049 0 . 000 - 0.047 0.000 - 0.191 0.000

10.5 60.619 1.739 1.5631 0.049 0.000 - 0.047 - 0.000 - 0.191 0.001

11.0 61.514 1.847 1.6689 0.049 0 . 000 - 0.047 - 0.000 - 0.190 0.00 3 11.5 62.479 2.031 1.7813 0.049 0.001 - 0.047 - 0. 00 1 - 0.188 0.004

12.0 63.570 2.361 1.9018 0.050 0.002 - 0.048 - 0.002 - 0.186 0.00 3 12.5 64.871 2.875 2.0324 0.051 0.003 - 0.049 - 0.003 - 0.185 0.00 2 13.0 66.479 3.595 2.1751 0.053 0.005 - 0.051 - 0.005 - 0.185 - 0.000

13.5 68.504 4.544 2.3318 0.056 0.007 - 0.054 - 0.007 - 0.185 - 0.002

14.0 71.067 5.756 2.5040 0.060 0.008 - 0. 058 - 0.008 - 0.187 - 0.003

14.5 74.310 7.271 2.6930 0.064 0.010 - 0. 063 - 0.010 - 0.189 - 0.004

15.0 70.397 9.140 2.8999 0.070 0.012 - 0.068 - 0.012 - 0.191 - 0.005

15.5 63.519 11. 421 3.1256 0.076 0.013 - 0.075 - 0.014 - 0.193 - 0.005

16.0 89.097 14.177 3. 3704 0.083 0.015 - 0.082 - 0.016 - 0.195 - 0.005

16.5 97.786 17.475 3.6346 0.091 0.017 - 0.091 - 0.019 - 0.198 - 0.004

17.0 107.474 21. 386 3.9185 0.100 0.019 - 0.101 - 0.021 - 0.199 - 0.003

17.5 119.266 25.980 4.2218 0.110 0.021 - 0.112 - 0.024 - 0.201 - 0.002

16.133.579 31. 325 4.5441 0.121 0.023 - 0.125 - 0.027 - 0.201 - 0.000

16.5 153.746 37.485 4.8852 0.133 0.025 - 0.139 - 0.030 - 0.201 0 . 00 ? 19.0 171.210 44.519 5.2442 0.146 0.027 - 0.155 - 0.034 - 0.199 0.004

19.5 195.420 52.400 5.6204 0.160 0.030 - 0.173 - 0.038 - 0.196 0.006

20.0 223.852 61.413 6.0130 0.176 0.032 - 0.193 - 0.042 - 0.193 0.009

20.5 257.001 71. 354 6.4208 0 . 192 0.034 - 0.215 - 0.046 -0 .188 0.011

21.0 295.379 82.335 6.8429 0.209 0.036 - 0.239 - 0.052 - 0.101 0.014

21.5 339.514 94.382 7.2780 0.228 0.038 - 0.266 - 0.057 - 0.174 0.016

22.0 389.943 107.520 7.7250 0.248 0.040 - 0.296 - 0.063 - 0.166 0.016

22.447.219 121. 771 8.1825 0 . 269 0.043 - 0.330 - 0.070 - 0.156 0.019

23.0 511.904 137.157 8.6493 0.290 0.045 - 0. 367 - 0.078 - 0.146 0.021

23.5 584.570 153. 701 9.1239 0.313 0 . C 47 - 0.408 - 0.087 - 0.135 0.022

24.0 665.600 171.418 9.6049 0.337 0 . 049 - 0. 453 - 0.096 - 0.124 0 . 02 ?

125
METHANE ISOTHERM 210.0 0E 6 . K MOl/L P i BAR DP/DO DP/OT XB 0X 8/00 XC OXC/DO XO oxo/oo

0.5 8.322 15.844 0.0436 0.390 - 0.199 - 0.500 0.395 - 0.366 0.058

1.0 15.854 14.302 0.0912 0.315 - 0.114 - 0. 367 0.186 - 0.345 0.031

1.5 22.644 12.879 0.1428 0.268 - 0. 080 - 0.294 0.116 - 0.333 0.020

2.0 28.754 11.584 0.1961 0.233 - 0.061 - 0.245 0.081 - 0.324 0.015

2.5 34.246 10.399 0.2572 0.206 - 0.048 - 0.210 0.060 - 0.317 0.012

3.0 39.169 9.306 0.3197 0.184 - 0.039 - 0.184 0.046 - 0.312 0.009

3.5 43.569 6.309 0.3855 0.166 - 0.032 - 0.163 0.037 - 0.308 0.007

4.0 47.493 7.403 0.4543 0.152 - 0.026 - 0.147 0.029 - 0.305 0.005

4.5 50.989 6.596 0.5258 0.140 - 0. 021 • 0.134 0.023 - 0.303 0.003

5.0 54.107 5.691 0.5998 0.131 - 0. 017 - 0.123 0.019 - 0.302 0.001

5.5 56.897 5.286 0.6760 0.123 - 0.014 - 0.115 0.015 - 0.302 - 0.000

6.0 59.408 4.7 74 0.7543 0.116 - 0.011 - 0.108 0.012 - 0.302 - 0.001

6.5 61.685 4.345 0.8345 0.111 - 0.009 - 0.103 0.009 - 0.303 - 0.002

7.0 63.765 3.986 0.9166 0.107 - 0.007 - 0.099 0.007 - 0.304 - 0.003

7.5 65.684 3.699 1.0008 0.104 - 0.005 - 0.096 0.005 - 0.305 - 0.003

a.o 67.478 3.490 1.0874 0.102 - 0.003 - 0.094 0.003 - 0.307 - 0.004

8.5 69.192 3.389 1.1769 0.101 - 0. 001 • 0.093 0.001 - 0.309 - 0.005

9.0 70.889 3.419 1.2699 0.101 - 0.000 - 0.093 0.000 - 0.311 - 0.004

9.5 72.626 3.538 1.3672 0.101 - 0.000 - 0.093 0.000 - 0.313 - 0.001

10.0 74.434 3.696 1.4695 0.101 0.000 - 0.093 0.000 - 0.313 0.000

10.5 76.328 3 . 866 1.5773 0.101 0.000 - 0.093 - 0.000 - 0.313 0.001

11.0 78.327 4.122 1.6915 0.101 0.000 - 0.093 - 0 . 000 - 0.311 0.004

11.5 80.466 4.455 1.8127 0.101 0.001 - 0.093 - 0.001 - 0.309 0.006

12.0 82.811 4.962 1.9420 0.102 0.002 - 0.093 - 0.002 - 0.306 0.006

12.5 85.464 5.686 2.0808 0.103 0 . 003 - 0.095 - 0.003 - 0.303 0.006

13.0 88.537 6.646 2. 2303 0.105 0.005 - 0.097 - 0.005 - 0.300 0.007

13.5 92.155 7.870 2.3920 0.108 0.007 - 0.100 - 0.007 - 0.296 0.00 7 14.0 96.455 9.382 2.5671 0.112 0.008 - 0.104 - 0.006 - 0.293 0.007

14.

5

101.591 11.221 2.7569 0.116 0.010 - 0.108 - 0.010 - 0.290 0.007

15.0 107.739 13.435 2.9624 0.122 0.012 - 0.114 - 0.012 - 0.286 0.007

15.5 115.097 16.074 3.1846 0.128 0.013 - 0. 120 - 0.014 - 0.282 0.006

16.0 123.894 19. 200 3.4241 0.135 0.015 - 0. 128 - 0.016 - 0.278 0.008

16.5 134.368 22.874 3.6815 0.143 0.017 - 0.137 - 0.019 - 0.274 0.009

17.0 146. 870 27. 162 3.9569 0.152 0.019 - 0.146 - 0.021 - 0.269 0.010

17 . 5 161.663 32.130 4.2506 0.162 0.021 - 0. 158 - 0.024 - 0.264 0.011

16.0 179. 124 37. 843 4.5622 0.173 0 . 023 - 0. 170 - 0.027 - 0.258 0.012

18.5 199.641 44.362 4.8916 0.185 0 . C 25 - 0.165 - 0.030 - 0.252 0.014

19.0 223.630 51.742 5.2382 0.198 0.027 - 0. 200 - 0.034 - 0.245 0.015

19.5 251.535 60. 034 5.6014 0.212 0.030 - 0.218 - 0.038 - 0.237 0.017

20 .

0

283.823 69. 279 5.9805 0.227 0 . 032 - 0.238 - 0.042 -0 .228 0.018

20.5 320.979 79.513 6.3745 0.244 0.034 - 0.260 - 0.046 - 0.218 0.020

21 .

0

363.506 90. 766 6.7826 0.261 0.036 - 0.285 - 0.052 - 0.208 0.022

21.5 411.919 103.063 7.2037 0.280 0.038 - 0.312 - 0.057 - 0.197 0.023

22.0 466. 747 116.427 7.6367 0.300 0.040 - 0. 342 - 0.063 - 0.165 0.024

22.5 528.527 130.879 8.0804 0.320 0.043 - 0. 375 - 0.070 - 0.172 0.025

23.0 597.810 146.441 8.5338 0.342 0 . 045 - 0.412 - 0.078 - 0.160 0.026

23.5 675.156 163.133 8.9955 0.365 0.047 - 0.453 - 0.087 - 0.147 0.026

126
METHANE ISOTHERM 220,0 DEG. K HOL/L P.BAR OP/ DO QP/DY X@ OXB/OO XC DXC/DD xo GXQ/DO

8.5 0.757 16.754 0.0435 0.441 - 0.199 - 0.541 0.395 - 0.385 0.043

1.0 16.764 15.290 0.0908 0.367 - 0. 114 - 0.408 (9.186 - 0.371 0 . 01 ? 1.5 24.067 13.942 0.1419 0.319 - 0. 080 - 0. 335 0. 116 - 0.365 0.006

2.0 30.720 12.720 0.1965 0.264 - 0.061 - 0.286 0.081 - 0.362 0.003

2.5 36.005 11.605 0.2547 0.257 - 0.048 - 0.251 0.060 - 0.362 - 0.008

3.0 42.347 10.500 0.3161 0.236 - 0 o 039 - 0.225 0.946 - 0.362 -0.002

3.5 47.399 9.642 ®. 3 ® 0 ? 0.210 - 0.032 - 0.204 0 . 03 ? - 0.364 -0.004

4.0 52.004 8.793 0.4402 0.204 - 0.026 - 0.188 0.029 - 0.366 -0.006

4.5 56.200 6.030 0.5104 0,192 - 0.021 - 0.175 0.023 - 0.370 - 0.007

5.0 60.059 7.381 0.5911 0.182 - 0.017 - 0.165 0.019 - 0.373 - 0.008

5.5 63.606 6.021 0.6663 0.174 - 0.014 -0.156 0.015 - 0.377 - 0.006

6.0 66.096 6.353 0.7439 0.168 - 0.011 - 0.150 0.012 - 0.381 - 0.008

6.5 69.973 5.960 0.0238 0.163 - 0.009 - 0.144 0.009 - 0.386 - 0.008

7.0 72.076 5.657 0.9063 0.159 - 0.007 - 0.140 0.007 - 0.389 - 0.007

7.5 75.642 5.420 0.9915 0.156 - 0.005 - 0.137 0.005 - 0.393 - 0.007 e.o 70.311 5.270 1.0790 0.154 - 0.003 - 0.135 0.003 - 0.396 -a. 006

0.5 00.932 5.240 1.1716 0.153 - 0.001 - 0.134 0.001 - 0.399 - 0.006

9.0 03.575 5.354 1.2676 0.153 - 0.000 - 0.134 0.000 - 0.401 - 0. 084

9.5 06.304 5.571 1.3603 0.153 - 0.000 - 0.134 0.000 - 0.403 - 0.001

10.0 09.154 5.039 1.4744 0.153 0.000 - 0.134 0.000 - 0.40 3 0.000

10.5 92.150 6.151 1.5865 0.153 0.000 - 0. 134 - 0.000 - 0,403 0.001

11.0 95.315 6.523 1,7052 0.153 0.000 - 0.134 - 0.000 “ 0.401 0.004

11.5 90.691 7.009 1.0311 0.153 O.OQi - 0.134 - 0.001 - 0.399 0.006

12.0 102.356 7.609 1.9652 0.154 0.002 - 0.135 - 0.002 - 0.395 0.00 8 12.5 106.421 0.610 2.1084 0.155 0.003 - 0.136 - 0.003 - 0.391 0.009

13.0 111.010 9.794 2.2619 0.157 0.005 - 0.138 - 0.005 - 0.386 0.011

13.5 116.262 11.262 2.4266 0.160 0.007 -0.141 - 0.007 - 0.380 0.012

14.0 122.324 13.043 2.6038 0.164 0.008 - 0.145 - 0.008 - 0.374 0.013

14.5 129.363 15.173 2.7944 0.168 0.010 - 0.149 - 0.010 - 0.367 0.014

15.0 137.563 17.696 2.9994 0.173 0.012 - 0.155 - 0.012 - 0.360 0.015

15.5 147.133 29.662 3.2196 0.160 9.013 - 0.162 - 0.014 - 0.352 0.016

16.0 150.307 24.125 3.4556 0,. i 87 0 . 015 ' - 0.169 - 0.016 - 0.344 0.017

16.5 171.350 28.145 3.7084 0.195 0.017 - 0.176 - 0.019 - 0.335 0.016

17 . 0 186.555 32.784 3.9778 0.204 0.019 - 0.188 - 0.021 - 0.326 0.019

17.5 204.247 38.103 4.2643 0.213 0,021 - 0.199 - 0.02 4

- 0.316 0.020

18.0 224.782 44.164 4.5677 0.224 0.023 - 0.212 - 0.027 - 0.305 0.021

10.5 240.545 51. 024 4.8879 0.236 0.025 - 0.226 - 0.030 - 0.294 0.023

19.0 275.940 58. 736 5.2245 0.250 0.027 - 0.242 - 0.034 - 0.283 0.024

19.5 307.431 67.347 5.5771 0.264 0.030 - 0.259 - 0.036 - 0.271 0.025

20.0 343.452 76.096 5.9449 0.279 0.032 - 0.279 - 0.042 - 0.258 0.026

20.5 304.489 07.418 6. 3274 0.296 0.034 - 0.301 - 0.046 - 0.244 0.027

21.0 431.036 98.939 6.7237 0.313 0.036 - 0.326 - 0.052 - 0.230 0.028

21.5 403.599 111.485 7.1328 0.332 0.036 - 0. 353 - 0.05 7 - 0.216 0.029

22.0 542.695 125.076 7.5538 0.351 0.040 - 0.383 - 0.063 -0.201 0 . 03 C 22.5 609 * 052 139. 733 7.9056 0.372 0.043 - 0.416 - 0.070 - 0.186 0.030

23.0 602.609 155.478 8.4273 0.394 0.045 - 0.453 - 0.078 - 0.171 0.030

127
METHANE ISOTHERM 240.0 OEG . K MOL/L P » BA R OP/DO DP/OT XB 0 X 8/00 XC DXC/DD XO DXD/OO

0.5 9.625 18.564 0.0433 0.544 - 0.199 - 0.613 0.395 - 0.414 0.013

1 .0 18.574 17.245 0.0902 0.470 - 0.114 - 0.480 0.186 - 0.412 - 0.003

1.5 26.890 16.039 0.1405 0.422 - 0.080 - 0.407 0.116 - 0.415 - 0.011

2.0 34.633 14.953 0.1941 0.387 - 0.061 -0.359 0.061 - 0.422 - 0.015

2.5 41.859 13.968 0.2510 0.360 - 0.048 - 0.324 0.060 - 0.430 - 0.017

3.0 48.615 13.068 0.3110 0.338 - 0.039 - 0.297 0.046 - 0.439 - 0.019

3.5 54.941 12.249 0. 3739 0.321 - 0. 032 - 0.276 0.037 - 0.449 - 0.020

4.0 60.877 11.513 0.4396 0.306 - 0. 026 - 0.260 0.029 - 0.459 - 0.020

4.5 66.469 10.867 0.5065 0.295 - 0.021 -0.247 0.023 - 0.469 - 0.020

5.0 71.760 10.315 0.5799 0.265 - 0.017 - 0.237 0.019 - 0.479 - 0.020

5.5 76.799 9.859 0.6541 0.277 - 0.014 - 0.226 0.015 - 0.468 - 0.019

6.0 81.634 9.496 0.7312 0.271 - 0.011 - 0.222 0.012 - 0.497 - 0.017

6.5 86.310 9.222 0.6112 0.266 - 0.009 - 0.216 0.009 - 0.505 - 0.015

7.0 90.871 9.032 0.6944 0.262 - 0.007 - 0.212 0.007 - 0.512 - 0.013

7.5 95.357 8.927 0.9810 0.259 - 0.005 - 0.209 0.005 - 0.516 - 0.011

8.0 99.814 6.924 1.0715 0.257 - 0.003 - 0.207 0.003 - 0.523 - 0.009

8.5 104.303 9.060 1.1661 0.256 - 0.001 - 0.206 0.001 - 0.527 - 0.007

9.0 108.903 9.365 1.2654 0.256 - 0.000 - 0.206 0.000 - 0.530 - 0.004

9.5 113.690 9.795 1.3700 0.256 - 0.000 - 0.206 0.000 - 0.531 - 0.001

10 . 0 118.710 10.298 1.4804 0.256 0.000 - 0.206 0.000 - 0.531 0.000

10.5 123.998 10.868 1.5970 0.256 0.000 - 0.206 - 0.000 - 0.531 0.001

11.0 129.591 11.520 1.7204 0.256 0.000 - 0.206 - 0.000 - 0.530 0.004

11.5 135.542 12.314 1.8513 0.256 0.001 - 0.206 - 0.001 - 0.527 0.007

12.0 141.944 13.336 1.9901 0.256 0.002 - 0.207 - 0.002 - 0.523 0.010

12.5 148.924 14.633 2.1378 0.256 0.003 - 0.208 - 0.003 - 0.517 0.013

13.0 156.627 16.230 2.2951 0.260 0.005 - 0.210 - 0.005 - 0.510 0.015

13.5 165.208 18.149 2.4627 0.263 0 . 007 - 0.213 - 0.007 - 0.501 0.018

14.0 174.834 20.418 2.6415 0.266 0.008 - 0.217 - 0.006 - 0.492 0.021

14.5 185.690 23.071 2 . f323 0.271 0.010 - 0.222 - 0.010 - 0.481 0.023

15.0 197.976 26.149 3. 0358 0.276 0.012 - 0.227 - 0.012 - 0.469 0.025

15.5 211.917 29.698 3.2526 0.282 0.013 - 0.234 - 0.014 -0 .456 0.027

16.0 227.761 33. 769 3.4837 0.269 0.015 - 0.241 - 0.016 - 0.442 0.029

16.5 245.782 38.414 3.7292 0.297 0.017 - 0.250 - 0.019 - 0.427 0.031

17.0 266.281 43.690 3.9896 0.306 0.019 - 0.260 - 0.021 - 0.411 0.032

17.5 289.587 49.653 4.2651 0.316 0. 021 -0.271 - 0.024 - 0.394 0.034

18.0 316.057 56.355 4.5558 0.327 0.023 - 0.264 - 0.027 - 0.377 0.035

18.5 346. 074 63.850 4.6618 0.339 0.025 - 0.298 - 0.030 - 0.360 0 . 036

19.0 380.046 72.183 5.1626 0.352 0.027 - 0.314 - 0.034 - 0.342 0.037

19.5 418.404 81.397 5.5185 0.367 0.030 - 0.332 - 0.038 - 0.323 0.037

20.0 461.596 91.527 5.8666 0.362 0.032 - 0.351 - 0.042 - 0.304 0.038

20.5 510.088 102.601 6. 2324 0.396 0 . 034 - 0.374 • 0.046 - 0.285 0.038

21.0 564.359 114.646 6.6094 0.416 0.036 - 0. 396 - 0.052 - 0.266 0.039

21.5 624.900 127.682 6.9968 0.434 0.038 - 0.425 - 0.057 -0.246 0.039

22.0 692.210 141.729 7.4000 0.454 0.040 - 0.455 - 0.063 - 0.227 0.038

128
METHANE ISOTHERM 260.0 0E6. K MOL/L DP/DD OP/ DT KB OXB/OC XC OXC/DD XD DXD/OO

0.6 10.491 20.364 0.9432 0.646 - 0.199 - 0,675 0.395 - 0.437 0.001

1.0 20.373 19.160 0.0897 0.572 - 0.114 “ 0.541 0.186 - 0.442 - 0.017

1.5 29.669 18.105 0.1395 0.524 - 0. 080 - 0.468 0.116 - 0.452 - 0.024

2.0 33.497 17.146 0.1924 0.489 “ 0. 061 - 0. 420 0.081 - 0.465 - 0.027

2.5 46.652 16.285 0.2464 0.462 - 0.048 ” 0.385 0.060 - 0.480 - 0.029

3.0 54.796 15.906 0,3073 0.440 - 0.039 - 0.358 0.046 - 0.494 - 0.030

3.5 62.370 14. 604 0.3693 8.423 - 0.032 - 0.337 0.037 - 0.509 - 0.030

4.0 69.614 14. 184 0.4342 0.400 - 0.026 - 0. 321 0.029 - 0.524 - 0.030

A.76.569 13.651 0.5019 0.396 ” 0.021 - 0.388 0.02 3 - 0.539 - 0.029

5.0 63.261 13.214 0.5726 0.387 - 0.017 - 8.298 0.019 - 0.553 - 0.027

5.5 89.799 12.675 0.6463 0.379 - 0.014 - 0.289 0.015 - 0.566 - 0.025

6.0 96.173 12.635 0.7232 0.373 - 0.011 - 0.283 0.012 - 0.576 - 0.022

6.5 102.451 12.491 0.8033 0.368 - 0.009 - 0.278 0.009 - 0.566 - 0.020

7.0 106.660 12.446 0.6669 0.363 “ 0.007 - 0.273 0.007 - 0.597 - 0.016

7.5 114.907 12.467 0.9744 0.360 - 0.005 - 0.270 0.005 - 0.605 - 0.013

8.0 121.166 12.651 1,0659 0.359 - 0.003 - 0.268 0.003 - 0.611 - 0.010

6.5 127.565 12.972 1. 1620 0.356 " 0.001 - 0.267 0.001 - 0.615 - 0.007

9.0 134.190 13.481 1.2631 0.357 “ 0. 000 - 0,267 0.000 - 0.618 - 0.004

9.5 141.090 14.135 1.3696 0.357 “ 0. 000 - 0.267 0.000 - 0.619 “ 0.001

10.0 146.340 14.061 1.4820 0.357 0.000 - 0.267 0.000 - 0.620 0.000

10.5 155.966 15.714 1.6003 0.357 0.000 - 0.267 - 0.000 - 0.619 0.001

11.0 164.072 16.650 1.7264 0.357 0.000 - 0.267 - 0.000 - 0.618 0.004

11.5 172.663 17.750 1. 8593 0.357 0 . 001 - 0.267 - 0.001 - 0.615 0.008

12.0 161.664 19.104 2.0001 0.358 0.002 “ 0.268 - 0.002 - 0.610 0.011

12.5 191.617 20.760 2. 1494 0.359 0.003 - 0.269 - 0.003 - 0.604 0.015

13 . 0 202.679 22.746 2.3078 0.361 0.005 “ 0.271 - 0.005 - 0.595 0.018

13.5 214.621 25.062 2.4760 0.364 0.007 - 0.274 - 0.007 - 0.585 0.022

1

. 0 227.624 27. 796 2.6546 0.368 0.000 - 0.278 - 0.008 - 0.574 0.025

14.5 242.486 30.922 2.8442 0.373 0.010 - 0.283 - 0.010 - 0.560 0.023

15.0 253.622 34.500 3.0456 0.378 0 . 012 ' - 0.288 - 0.012 - 0.545 0.032

15.5 277.063 36.573 3.2591 0.384 0.013 - 0.295 - 0.014 - 0.529 0.034

16 . 0 297.485 43.187 3.4855 0.391 0.015 - 0. 302 - 0.016 - 0.511 0.037

16.5 320.354 48.394 3.7250 0.399 0.017 - 0.311 - 0.019 - 0.492 0.039

17.0 345.986 54.243 3.9781 0.408 0.019 - 0.321 “ 0.021 - 0.472 0.041

17.5 374.713 60.787 4.2450 0.418 0.021 - 0. 332 - 0.024 “ 0.451 0.042

16.0 406.396 68.073 4.5258 0.429 0.023 - 0. 345 - 0.027 - 0.429 0.044

16.5 442.918 76.149 4. 8207 0.441 0.025 - 0.359 - 0.030 - 0.407 0.045

19.0 433.164 65.056 5.1294 0.454 0.027 - 0.375 - 0.034 - 0.385 0.046

19.5 526.119 94.832 5.4519 0.468 0.030 “ 0.393 - 0.036 - 0.362 0.046

20.0 576.165 105.507 5.7870 0.484 0.032 - 0.413 - 0.042 - 0.339 0.046

20.5 633.760 117.109 6.1368 0.500 0.034 - 0.435 - 0.046 - 0.315 0.046

21.0 695.432 129.656 6.4983 0.518 0.036 - 0. 459 - 0.052 - 0.292 0.046

METHANE ISOTHERM 260.0 DEG. K

MOL/L P.BAR OP/DD OP/DT XB DXB/DO XC OXC/DD XD OXD/OO

0.5 11.354 22.155 0.0431 0.746 - 0.199 - 0.727 0.395 - 0.454 - 0.013

1.0 22. 164 21.096 0.0894 0.672 - 0. 114 - 0.593 0.186 - 0.465 - 0.028

1.5 32.471 20.148 0.1387 0.624 - 0.080 - 0.520 0.116 - 0.481 - 0.034

2.0 42.331 19.311 0.1910 0.589 - 0.061 - 0.472 0.081 - 0.498 - 0.037

2.5 51.790 18.570 0.2463 0.562 “ 0. 048 - 0.437 0.060 - 0.517 - 0.038

3.0 60.914 17.909 0.3046 0.541 - 0.039 - 0.410 0.046 - 0.536 - 0.038

3.5 69.720 17.325 0.3658 0,523 - 0.032 - 0. 390 0.037 - 0.555 - 0.037

4.0 78.253 16. 822 0.4299 0.509 “ 0.026 - 0.374 0.029 - 0.573 - 0.036

4.5 86.556 16.408 0.4970 0.497 - 0.021 - 0. 361 0.023 - 0.591 - 0.034

5.0 94.677 16.092 0.5672 0.487 - 0.017 - 0. 350 0.019 - 0.606 - 0.032

5.5 102.665 15.879 0.6405 0.480 - 0.014 “ 0. 342 0.015 - 0.623 - 0.029

6.0 110.573 15.770 0.7171 0.473 - 0. Oil - 0.335 0.012 - 0.637 - 0.026

6.5 110.453 15.767 0.7971 0.468 - 0.009 - 0. 330 0.009 - 0.649 - 0.022

7.0 126.357 15.066 0.9010 0.464 - 0.007 - 0.326 0.007 - 0.659 - 0.019

7.5 134.330 16. 076 0.9688 0.461 - 0.005 - 0.323 0.005 - 0.668 - 0. 015 8.0 142.455 16.417 1.0609 0.459 - 0.003 - 0.321 0.003 - 0.674 - 0.011

8.5 150.703 16,930 1.1577 0.458 - 0.001 - 0.320 0.001 - 0.679 - 0.008

9.0 159.420 17.649 1.2596 0.458 - 0. 000 - 0.319 0.000 - 0.682 - 0.005

9.5 168.459 10.531 1.3670 0.458 - 0.000 - 0. 319 0 . 000 - 0.684 - 0.001

10.0 177.968 19.522 1.4803 0 . 4?S 0.000 - 0.319 0.000 - 0.684 0.000

10.5 187.999 20.618 1.5999 0.458 0.000 - 0.319 - 0.000 - 0.684 0.001

11.0 198.606 21. 835 1. 7263 0.458 0.000 - 0. 319 - 0.000 - 0.682 0.005

11.5 209.864 23.236 1.0598 0.458 0.001 - 0.320 - 0.001 - 0.679 0.008

12.0 221.880 24.912 2.0011 0.459 0.002 - 0.320 - 0.002 - 0.674 0.012

12.5 234.030 26.914 2.1506 0.460 0.003 - 0.322 - 0.003 - 0.667 0.016

13.0 240.861 29.268 2.3069 0.462 0.005 - 0.324 - 0.005 - 0.658 0.020

13.5 264.161 31.997 2.4764 0.465 0.007 - 0.327 - 0.007 - 0.647 0.024

14.0 280.925 35.128 2.6538 0.469 0.008 - 0.330 - 0.008 - 0.634 0.028

14.5 299.362 30.694 2.3415 0.473 0.010 - 0.335 - 0.010 - 0.618 0.032

15.0 319.699 42.734 3.0402 0 . 47S 0.012 - 0.341 - 0.012 - 0.601 0.036

15.5 342.182 47.288 3.2502 0.485 0.013 - 0.347 - 0.014 - 0.583 0.039

16.0 367.080 52.402 3.4721 0.492 0 . 015 - 0.355 - 0.016 - 0.562 0,042

16.5 394.685 58.124 3.7062 0.500 0.017 - 0. 363 - 0.019 - 0.541 0.045

17.0 425.313 64.500 3.9528 0.509 0.019 - 0. 373 - 0. 021 - 0.518 0.047

17.5 459.302 71.578 4.2122 0.516 0.021 - 0. 384 - 0.024 - 0.494 0.049

18.0 497.016 79.404 4.4846 0.529 0.023 - 0.397 - 0.027 - 0 . 469 0.050

18.5 530.838 68.019 4.7701 0.541 0.025 - 0,411 - 0.030 - 0.443 0.051

19.0 585.173 97.462 5.0685 0.555 0 . 027 - 0.427 - 0.034 - 0.417 0.052

19.5 636.443 107.766 5.3798 0.569 0 . 030 - 0.445 - 0.038 - 0.391 0.053

20.0 693.087 118.958 5.7039 0.584 0.032 - 0.465 - 0.042 - 0.365 0.053

129
METHANE ISOTHERM 300.0 DEG. K

MOL /L f* j SAR DP/DD OP/DT X 0 DXB/DD XC OXC/OD XD OXO/OO

0.5 12.216 23.940 0.0431 0.845 • 0.199 - 0.772 0.395 - 0.468 - 0.023

1.0 23.949 23.003 0.0891 0.771 • 0.114 - 0.639 0.186 - 0.483 - 0.037

1.5 35.237 22.172 0.1300 0.723 - 0.060 - 0.566 0.116 - 0.503 - 0.041

2.0 46 o 14 0 21.454 0.1099 0.688 • 0. 061 - 0.517 0.081 - 0,524 - 0.043

2.5 56.707 20.830 0.2447 0.661 - 0.048 - 0. 482 0 . 060 - 0.546 - 0.044

3.0 66.983 20.266 0.3023 0.640 - 0.039 - 0.456 0.046 - 0.568 - 0.044

3.5 77.006 19.019 0.3629 0.622 - 0.032 - 0.435 0.037 - 0.590 - 0.043

A . 0 86. 815 19.434 0.4264 0.608 - 0. 026 = 0.419 0.029 - 0.611 - 0.041

A .

5

96.455 19.142 0.4930 8.596 - 0.021 - 0.406 0.023 - 0.631 - 0.039

5.0 105.974 10.951 0.5627 0.586 - 0.017 - 0.396 0.019 - 0.649 - 0.036

5.5 115.424 10.868 0.6355 0.579 - 0.014 - 0.387 0.015 - 0.667 - 0.033

6.0 124.861 18.893 0.7118 0.572 - 0.011 - 0.381 0.012 - 0.682 - 0.029

6.5 134.341 19.041 0.7917 0.567 - 0.009 - 0. 375 0.009 -0 .695 - 0.025

7.0 143.921 19.297 0.0755 0.563 - 0.007 - 0.371 0.007 - 0.707 - 0.020

7.5 153.659 19.675 0.9633 0,560 - 0,005 - 0. 368 0.005 - 0.716 - 0.016

8.0 163.620 20.197 1.0556 0.558 - 0.003 - 0.366 0.003 - 0.723 - 0.012

8.5 173. 887 20.907 1.1526 0.557 - 0.001 - 0.365 0.001 - 0.728 - 0.008

9.0 184.564 21.638 1.2547 0.557 - 0.000 - 0.365 0.000 - 0.731 - 0.005

9.5 195.755 22.947 1.3622 0.557 - 0.000 - 0.365 0.000 - 0.732 - 0.001

10.0 207.532 24.183 1.4757 0.557 0.000 - 0.365 0.000 - 0.733 0.000 10.5 219.957 25.538 1.5954 0.557 0.000 - 0.365 - 0.000 - 0.732 0.001 11.0 233.093 27.032 1.7218 0.557 0.000 - 0.365 - 0.000 - 0.731 0 . 005

11 .5 247.022 28.727 1.8552 0.557 0.001 - 0.365 - 0.001 - 0.728 0.009

12.0 261.869 30. 716 1.9961 0.558 0.002 - 0.366 - 0.002 - 0.722 0.013

12.5 277.796 33.051 2.1450 0.559 0.003 - 0.367 - 0.003 - 0.715 0.017

13.0 294.983 35.759 2.3023 0.561 0.005 - 0.369 - 0.005 - 0.705 0.022

13.5 313.621 38. 862 2.4684 0.564 0.007 - 0. 372 - 0.007 - 0.693 0.026

14.0 333.915 42.387 2.6439 0.568 0.008 - 0.376 - 0.008 - 0.679 0.031

14.5 356.083 46.366 2.8293 0.572 0.010 - 0.380 - 0.010 - 0.663 0.035

15 . 0 380.363 50.838 3.0249 0.577 0.012 - 0. 386 - 0.012 - 0.644 0.039

15.5 407.010 55.843 3.2313 0.584 0.013 - 0.393 - 0.014 - 0.624 0.043

16.0 436.302 61.423 3.4488 0.591 0.015 - 0.400 - 0.016 - 0.602 0.046

16.5 468.537 67.624 3.6777 0.599 0.017 - 0.409 - 0.019 - 0.578 0.049

17.0 504.037 74.491 3.9183 0.608 0.019 - 0.419 - 0.021 - 0.553 0.051

17.5 543.146 82.069 4. 1710 0.618 0.021 - 0.430 - 0.024 - 0.526 0.054

18.0 586.231 90. 398 4. 4358 0.628 0 . 023 - 0.443 - 0.027 - 0 .499 0.055

16.5 633.677 99.519 4.7129 0.641 0.025 - 0.457 - 0.030 - 0.471 0.056

19.0 685.688 109.467 5.0023 0.654 0.027 - 0.473 - 0.034 - 0.443 0.057 METHANE ISOTHERM 320.0 DEG . K

MOL /L P , 8 AR DP/DD DP/DT XB OXB/OO XC DXC/DO XD DXD/DO

0.5 13.076 25.719 0.0430 0.943 - 0. 199 - 0.812 0.395 - 0.478 - 0.032

1 . 0 25.727 24.898 0.0886 0.868 - 0.114 - 0.679 0.186 - 0.498 - 0.043

1.5 37.992 24.161 0.1375 0.821 - 0.080 - 0.605 0.116 - 0.521 - 0.047

2.0 49.928 23.578 0.1889 0.786 - 0.061 - 0.557 0.081 - 0.545 - 0.049

2.5 61.586 23.068 0.2432 0.759 - 0.048 - 0.522 0.060 - 0.569 - 0.049

3.0 73.009 22.640 0.3004 0.737 - 0. 039 - 0.495 0.046 - 0.594 - 0.048

3.5 84.239 22.290 0.3604 0.720 - 0.032 - 0.475 0.037 - 0.617 - 0.047

4.0 95.313 22.025 0.4234 0.705 - 0.026 - 0.459 0.029 - 0.640 - 0.045

4.5 106.279 21.855 0.4895 0.693 - 0.021 - 0.446 0.023 - 0.662 - 0.042

5 . 0 117. 186 21. 792 0.5586 0.684 - 0.017 - 0.435 0.019 - 0.682 - 0.039

5.5 128.090 21. 843 0.6311 0.676 - 0.014 - 0. 427 0.015 - 0.701 - 0.035

6.0 139.049 22.014 0.7070 0.670 - 0.011 - 0.420 0.012 - 0.717 - 0.031

6.5 150.124 22.306 0.7866 0.664 - 0.009 - 0. 415 0.009 - 0.731 - 0.026

7.0 161.376 22.723 0.8701 0.660 - 0.007 - 0.411 0.007 - 0.743 - 0.022

7.5 172. 869 23.272 0.9577 0.657 - 0.005 - 0.408 0.005 - 0.753 - 0.017

8.0 184.674 23.977 1.0497 0.655 - 0.003 - 0.406 0.003 - 0.760 - 0.013

8.5 196.879 24.864 1.1465 0.654 - 0.001 - 0.405 0.001 - 0.766 - 0.009

9.0 209.597 26. 026 1.2485 0.654 - 0.000 - 0.405 0.000 - 0.769 - 0.005

9.5 222.938 27. 362 1.3558 0.654 - 0. 000 - 0.405 0.000 -0 .770 - 0.002

10.0 236.982 28. 838 1.4690 0. 65 A 0.000 - 0.405 0.000 - 0.771 0.000 10.5 251.798 30.449 1.5883 0.654 0.000 - 0.405 - 0 . 000 - 0.770 0.002

11 . 0 267. 457 32.214 1.7141 0.654 0.000 - 0.405 - 0.000 - 0.769 0.005

11 .

5

284.048 34. 196 1.8468 0.654 0.001 - 0.405 - 0.001 - 0.765 0.009

12.0 301.704 36.489 1.9866 0.655 0.002 - 0.405 - 0 . 002 - 0.760 0.013

12.5 320.597 39.146 2.1344 0.656 0 . 003 - 0.407 - 0.003 - 0.752 0.018

13.0 340.915 42.193 2.2902 0.658 0.005 - 0.409 - 0.005 - 0.742 0.023

13.5 362.859 45.653 2.4545 0.661 0 . 007 - 0.412 - 0.007 - 0.730 0.027

14.0 386.641 49.553 2.6276 0.665 0.008 - 0.415 - 0.008 - 0.715 0.032

14.5 412.490 53. 925 2.8105 0.669 0.010 - 0.420 - 0.010 - 0.697 0.037

15.0 440.651 50.806 3.0029 0.675 0.012 - 0.426 - 0.012 - 0.678 0.041

15.5 471.387 64.235 3.2054 0.681 0.013 - 0.432 - 0.014 - 0.656 0.045

16.0 504.984 70.254 3.4105 0.688 0.015 - 0.440 - 0.016 - 0.633 0.049

16 . 5 541.747 76.907 3.6424 0.696 0.017 - 0.448 - 0.019 - 0.607 0.052

17.0 582.004 84.236 3.0774 0.705 0.019 - 0.458 - 0.021 - 0.580 0.055

17.5 626.103 92.283 4.1236 0.715 0.021 - 0.470 - 0.024 - 0.552 0.057

18.0 674.413 101.088 4.3816 0.726 0.023 - 0.482 - 0.027 - 0.523 0.059

130
METHANE ISOTHERM 31*0.0 DEG. K MOL/L P.BAR DP/DD OP/DT xe DXB/OO XC DXC/DD xn oxn/oo

0.5 13.936 27. 493 0.0429 1.039 “ 0.199 - 0.847 0.395 - 0.487 - 0.038

1.0 27.501 26.783 0.0386 0.964 “ 0.114 - 0.714 0.186 - 0.510 - 0.049

1.5 40.736 26.177 0.1370 0.916 - 0.080 - 0. 640 0.116 - 0.535 - 0.052

2.0 53.696 25.605 0.1881 0.882 - 0.061 - 0.592 0 . 081 - 0.561 - 0.053

2.5 66.437 25.268 0.2420 0.854 - 0.048 - 0.557 0.060 - 0.588 - 0.053

3.0 79.000 24.974 0.2987 0.633 - 0.039 - 0.531 0.046 - 0.614 - 0.052

3.5 91.425 24. 740 0.3582 0.815 “ 0.032 - 0.510 0.037 - 0.640 - 0.050

<*.0 103.754 24.594 0.4207 0.601 “ 0,026 - 0.494 0.029 - 0.664 - 0.048

4.5 116.036 24.548 0.4862 0.789 - 0.021 - 0.481 0.023 - 0.687 - 0.045

5.0 126.321 24.614 0.5549 0. 779 “ 0.017 - 0.470 0.019 - 0.709 - 0.041

5.5 140.670 24,800 0.6269 0.772 “ 0. 014 - 0.462 0.015 - 0.728 - 0.037

6.0 153.143 25.114 0.7023 0.765 “ 0.011 - 0.455 0.012 - 0.745 - 0.032

6.5 165.805 25.557 0.7815 0.760 “ 0.009 - 0.450 0.009 - 0.760 - 0.027

7.0 178.722 26.135 0.8645 0.756 - 0.007 - 0.446 0.007 - 0.773 - 0.022

7.5 191.964 26.855 0.9517 0.753 - 0.005 “ 0. 443 0.005 - 0.783 - 0.018

e. o 205.606 27. 744 1.0434 0.751 - 0.003 “ 0,441 0 . 003 - 0.790 - 0.013

8.5 219.744 28.847 1.1397 0.750 - 0.001 -0.440 0.001 - 0.796 - 0.009

9 . 0 234.495 30.199 1.2412 0.750 - 0.000 - 0.440 0.000 - 0.799 - 0.005

9.5 249.977 31.758 1.3479 0.750 - 0,000 - 0.440 0.000 - 0.801 - 0.002

10.0 266.279 33,471 1.4604 0.750 0.000 “ 0.440 0.000 - 0.801 0.000

10.5 283.473 35.333 1.5789 0.750 0.000 - 0.440 - 0.000 - 0.801 0.002

11.0 301.639 37. 362 1.7038 0.750 0.000 - 0.440 - 0.000 - 0.799 0.035

11.5 320.874 39.624 1.8354 0 . 750 0.001 - 0.440 - 0.001 - 0.796 0.009

12.0 341.318 42.212 1.9741 0.751 0.002 - 0.440 - 0.002 - 0.790 0.013

12.5 363.149 45.179 2.1202 0.752 0.003 - 0.442 - 0.003 - 0.782 0.016

13.0 386.565 48.553 2.2742 0.754 0.005 - 0.444 - 0.005 - 0.772 0.023

13.5 411. 774 52.356 2,4363 0.757 0.007 - 0.447 - 0.007 - 0.759 0.028

14.0 438.997 56.615 2.6071 0.761 0.006 - 0.450 - 0.008 - 0.743 0.034

14.5 468.470 61. 361 2 . 786 e 0. 765 0.010 - 0.455 - 0.010 - 0.725 0.038

15.0 500. 445 66.631 2.9758 0.770 0.012 - 0.461 - 0.012 - 0.705 0.043

15.5 535.195 72.464 3.1746 0.777 0.013 - 0.467 - 0.014 - 0.682 C . 047 16.0 573.009 78.899 3.3833 0.784 0.015 - 0.475 - 0.016 - 0.657 0.051 16.5 614.201 65.979 3.6023 0.792 0.017 - 0. 483 - 0.019 - 0.631 0.055

17.0 659.103 93.746 3.6318 0.801 0.019 - 0.493 - 0.021 - 0.603 0.058

METHANE ISOTHERM 360.0 DEG. K

MOL/L P.BAR OP/DO OP/DT xe OXB/DO XC oxr/oD XD DXO/OD

0.5 14.794 29.262 0.0429 1.132 - 0.199 - 0.878 0.39 5 - 0.495 - 0.044

1.0 29.271 28.659 0.0834 1.058 - 0.114 “ 0. 745 0.186 - 0.519 - 0.053

1.5 43.471 28.162 0.1365 1.010 - 0.080 - 0.672 0.116 - 0.547 - 0.056

2.0 57.451 27. 778 0. 1873 0.975 - 0.061 - 0.623 0.081 - 0.575 - 0.057

2.5 71.265 27.491 0.2408 0.948 - 0. 048 - 0.588 0.060 - 0.603 - 0.056

3.0 84.957 27 . 2 C 9 0.2971 0.927 - 0.039 - 0.562 0.046 - 0.631 - 0.055

3 .5 98.568 27.171 0.3561 0.909 - 0.032 - 0.541 0.037 - 0.658 - 0.053

4.0 112.142 27. 144 0.4181 0.695 - 0.026 - 0.525 0.029 - 0.683 - 0.050

4.5 125.729 27. 221 0.4832 0.883 - 0.021 - 0.512 0.023 - 0.708 - 0.047

5.0 139. 383 27.416 0.5513 0.873 - 0.017 “ 0.501 0.019 - 0.730 - 0.043

5.5 153.166 27. 738 0.6228 0.865 - 0.014 - 0.493 0.015 - 0.750 - 0.038

6.0 167.143 28. 194 0.6977 0.859 - 0.011 - 0.486 0.012 - 0,768 - 0.033

6.5 181.383 28.769 0.7763 0.854 - 0.009 - 0.481 0.009 - 0.784 - 0.028

7.0 195.956 29.528 0.8588 0.850 - 0.007 - 0.477 0.007 - 0.796 - 0.023

7.5 210.936 30.419 0.9455 0.847 - 0.005 - 0.474 0.005 - 0.807 - 0.018

8 . 0 226.406 31.491 1.0365 0.845 - 0.003 - 0.472 0.003 - 0.815 - 0.013

8.5 242.465 32.788 1.1323 0.844 - 0.001 - 0.471 0 . 001 - 0.820 -0.009

9.0 259.237 34.346 1.2330 0.044 - 0.000 - 0.471 0.000 - 0.624 - 0.005

9 . 5 276.848 36.125 1.3389 0.844 - 0.000 - 0.471 0.000 - 0.825 -0.002

10.0 295.390 38.070 1.4505 0 o 844 0.000 - 0.471 0.000 - 0.825 0.000

10.5 314.945 40.177 1.5680 0.844 0.000 - 0.471 - 0.000 - 0.825 0.002

11.0 335.597 42.465 1.6917 0.844 0.000 - 0.471 - 0.000 - 0.824 0.005

11.

357.450 44.998 1.8219 0.844 0.001 - 0.471 - 0.001 -0 .020 0.009

12.0 380.652 47.872 1.9590 0.844 0.002 - 0. 471 - 0.002 - 0.814 0.014

12.5 405.368 51. 140 2.1033 0.846 0.003 - 0.473 - 0.003 - 0.806 0.019

13.0 431. 662 54.829 2.2551 0.848 0.005 - 0.475 - 0.005 - 0.796 0.024

13,5 460.291 56.962 2.4149 0.851 0.007 ” 0 . 47 ® - 0.007 - 0.782 0.029

14.0 490.902 63.565 2.5830 0.854 0.008 - 0.482 - 0.008 - 0.766 0.035

14.5 523.939 68.669 2.7596 0.859 0.010 - 0.486 - 0.010 - 0.748 0.040

15.0 559.661 74.311 2.9452 0.864 0.012 - 0.492 - 0.012 - 0.727 0.045

15.5 598.346 80.528 3.1400 0.870 0.013 - 0.498 - 0.014 - 0.703 0.049

16.640.291 87.360 3.3444 0.878 0 . 015 - 0.506 - 0.016 - 0.678 0.053

16.5 685.815 94.848 3.5586 0.885 0.017 - 0.515 - 0.019 - 0.650 0.057
METHANE ISOTHERM 380.0 DEG. K HOL/L P * BAR DP/OD OP/OT XB OXB/DD XC DXC/DD XO DXO/DO

0.5 15.651 31.027 0.0428 1.224 -0.199 -0.906 0.395 -0.501 -0.046

1.0 31.036 30.528 0.0882 1.150 -0.114 -0.773 0.186 -0.527 -0.056

1 .5 46.197 30.135 0.1361 1.102 -0.080 -0.699 0.116 -0.556 -0.059

2.0 61.190 29.857 0. 1666 1.067 -0.061 -0.651 0.061 -0.586 -0.059

2.5 76.070 29.678 0.2397 1.040 -0. 048 -0.616 0.06 0 -0.616 -0.059

3.0 90.863 29.587 0.2956 1.018 -0.039 -0.590 0.046 -0.645 -0.057

3 . 5 105.671 29.582 0.3542 1.001 -0.032 -0.569 0.037 -0.673 -0.055

4.0 120.481 29.673 0.4157 0.986 -0.026 -0.553 0.029 -0.699 -0.052

4.5 135. 363 29. 873 0.4802 0.975 -0.021 -0.540 0.023 -0.724 -0.046

5 .

0

150.375 30.196 0.5478 0.965 -0.017 -0.529 0.019 -0.748 -0.044

5.5 165.581 30.653 0.6188 0.957 -0.014 -0.521 0.015 -0.766 -0.039

6.0 181.052 31.252 0.6931 0.951 -0.011 -0.514 0.012 -0.787 -0.034

6.5 196. 858 31. 998 0.7711 0.946 -0.009 -0.509 0.009 -0.803 -0.029

7.0 213.075 32. 696 0.8530 0.942 -0.007 -0.505 0.007 -0.616 -0.024

7.5 229.781 33.958 0.9390 0.939 -0. 005 -0.502 0.005 -0.827 -0.019

8.

0

247.064 35.209 1.0293 0.937 -0.003 -0.500 0.003 -0.835 -0.014

8.5 265. C30 36.698 1.1242 0.936 -0.001 -0.499 0.001 -0.640 -0.009

9.0 283.808 38.460 1.2240 0.935 -0.000 -0.499 0.000 -0.844 -0.005

9.5 303.529 40.454 1.3290 0.935 -0.000 -0.499 0.000 -0.845 -0.002

10.0 324.291 42.626 1.4395 0.935 0.000 -0.499 0.000 -0.646 0.000

10.5 346.183 44.972 1.5557 0.935 0.000 -0.499 -0.000 -0.845 0.002

11 .

0

369.295 47.511 1.6780 0.935 0.000 -0.499 -0.000 -0.844 0.005

11.5 393.738 50.309 1.8067 0.936 0.001 -0.499 -0.001 • -0.840 0.009

12.0 419.664 53.460 1.9420 0.936 0.002 -0.499 -0.002 -0.634 0.014

12.5 447 .266 57.019 2.0843 0.938 0.003 -0.501 -0.003 -0.626 0.019

13.0 476.755 61.013 2.2339 0.940 0.005 -0.503 -0.005 -0.815 0.024

13.5 508.355 65.463 2. 3911 0.943 0.007 -0.506 -0.007 -0.602 0.030

14.0 542.299 70.397 2.5564 0.946 0.008 -0.509 -o.ooe -0.785 0.035

14.5 578.837 75.845 2.7298 0.951 0.010 -0.514 -0.010 -0.766 0.041

15.0 618.235 61.843 2.9119 0.956 0.012 -0.520 -0.012 -0.745 0.046

15.5 660 .778 88.428 3.1028 0.962 0.013 -0.526 -0.014 -0.721 0.050

METHANE ISOTHERM 400.0 DEG. K

f

MOl/L P,BAR OP/DO DP/DT XB OXB/DC XC DXC/OD XD DXO/OO

0 . 5 16.507 32.789 0.0428 1.314 -0. 199 -0.931 0.395 -0.506 -0.052

1 . 0 32. 798 32. 390 0.0880 1. 240 -0. 114 -0. 798 0.186 -0.534 -0.059

1 .

5

48.915 32.098 0.1357 1.192 -0.080 -0. 725 0.116 -0.565 -0.062

2.0 64.915 31.923 0.1859 1.157 -0.061 -0.676 0.061 -0.596 -0.062

2. 5 80.855 31. 850 0.2367 1.130 -0.048 -0.641 0.060 -0.626 -0.061

3.0 96.780 31. 867 0.2942 1.108 -0.039 -0.615 0.046 -0.656 -0.059

3.5 112.737 31.975 0.3524 1.091 -0.032 -0.594 0. 037 -0.685 -0.057

4.0 128.772 32.183 0.4134 1.076 -0.026 -0.578 0.029 -0.713 -0.053

4.5 144. 939 32.5C4 0.4774 1.064 -0.021 -0.565 0.023 -0.739 -0.050

5.0 161.298 32.954 0 . 5444 1. 055 -0.017 -0.554 0.019 -0.762 -0.045

5 . 5 177.916 33.545 0.6148 1.047 -0.014 -0.546 0.015 -0.764 -0.040

6 . 0 194. 866 34.285 0.6885 1.041 -0.011 -0.539 0.012 -0.803 -0.035

6.5 212.228 35.161 0.7659 1.036 -0.009 -0. 534 0. 009 -0.819 -0.030

7.0 230 .075 36.237 0.8470 1.031 -0.007 -0.530 0.007 -0.632 -0.024

7.5 248.493 37.466 0.9322 1.028 -0.005 -0.527 0.005 -0.643 -0.019

8. 0 267. 575 36. 895 1.0217 1.027- -0.003 -0.525 0. 003 -0.851 -0.014

8.5 267.430 40.572 1.1157 1.026 -0.001 -0.524 0.001 -0.857 -0.009

9.0 308.195 42.533 1.2146 1.025 -0.000 -0.524 0.000 -0.861 -0.005

9.5 330.004 44. 736 1.3184 1.025 -0.000 -0.524 0.000 -0.662 -0.002

10 . 0 352.964 47.132 1.4277 1.025 0.000 -0.524 0.000 -0.862 0.000

10 .

5

377. 167 49. 712 1.5425 1.025 0.000 -0.524 -0.000 -0.662 0.002

11.0 402.710 52.496 1.6633 1.025 0.000 -0.524 -0.000 -0.861 0.005

11.5 429.708 55.550 1.7902 1.025 0.001 -0.524 -0.001 -0.857 0.009

12. 0 458.321 58.970 1.9236 1.026 0.002 -0.524 -0.002 -0.851 0.014

12.5 488.748 62.811 2.0638 1.027 0.003 -0. 526 -0.003 -0.843 0.019

13.0 521.207 67.098 2.2110 1.029 0.005 -0.528 -0.005 -0.832 0.025

13.5 555.925 71.855 2.3656 1.032 0.007 -0.531 -0.007 -0.618 0.031

14.0 593.144 77. 1 C 7 2.5279 1.036 0.008 -0.535 -0.008 -0.801 0.036

14.5 633.120 62.886 2.6982 1.041 0.010 -0.539 -0.010 -0.782 0.042

15.0 676.124 89.226 2.6767 1.046 0.012 -0.545 -0.012 -0.760 0.047

132
METHANE SS0TOEW8 420.0 0£6. K

MOL/E E8P/0D OP/BT KB OX6/DO xc DXC/DD XO DXD/OD

0.5 17.362 34.547 0. 0427 1.402 “ 0.199 - 0.954 0.395 - 0,510 - 0.055

1.0 34 . SS 6 34.244 0 . S 878 1 . 32 ? “ 0.114 » 0 .@ 2 S 0.186 " 0.540 “ 0.062

1.9 51.625 34.051 @.1353 1.200 - 0,000 - 8.747 0.116 - 0.572 -0 . 0{>4 2.0 6®. 627 33.977 0.1053 1.249 - 0.061 “ 0,699 0,001 - 0.604 - 0.064 2.5 09.619 34. @68 0 , 237 ® I .210 “ 8,040 - 0.664 0.060 “ 0.635 - 0.063

3.0 102.690 34.131 0 . 292 ® 1.196 - 0.039 1 “0 a 63 ? 0.046 “ 0 . 666 - 0.061 3.9 119. 766 34.349 0,3806 1.178 - 0,032 - 8 , 61 ? 0.037 - 0.696 - 0.058 4.0 137.017 34,672 0.4111 1. 164 - 0.026 “ 0.600 0.029 - 0.724 - 0.055 4.5 154.450 35.114 0.4746 1.152 - 0.021 - 0,587 0.023 - 0.750 - 0.051 5.0 172.153 35.690 0.5411 1.143 “ 0 . 01 ? - 0.577 0.019 - 0.775 - 0.046 5.5 196.172 38,413 0.6190 1.135 - 0.014 - 0.569 0.015 ” 0.797 - 0.041 6.0 208.592 37.292 6.6839 1.128 - 0,011 - 0.562 0.012 * - 0.816 - 0.036 6.5 227.492 38.335 0.7605 1.123 “ 0.009 - 0.557 0.009 - 0.032 - 0.030

7.0 246.995 39.947 0.8409 1.119 - 0.007 - 0.553 0.007 - 0.646 - 0.025

7.5 267.069 40,942 0.9253 1.116 “ 8.005 - 0.550 0.005 - 0.857 - 0.019

0.0 287.931 42.545 1.0139 1.114 - 0.003 - 0.543 0.003 - 0.865 - 0.014

8.5 309.657 44.406 1.1069 1.113 - 0.001 - 0.547 0.001 - 0.871 - 0.009 9.0 332.387 46.563 1,2047 1.113 - 0 . 00 ® - 0.546 0.000 - 0,875 - 0.005 9.5 356.263 4®. 973 1.3073 1.113 - 0 . 000 - 0.546 0.000 - 0.876 - 0.002

10.0 301.394 51,584 1.4152 1.113 8 . 000 “ 0. 546 0.000 - 0.877 0.000 10.5 407.879 54,391 1.5286 1.113 0.003 - 0.546 - 0.000 - 0.876 0.002

11.0 435. 821 57.413 1 . 647 ? 1.113 0,000 - 0.546 “ 0.000 - 0.875 0.005

11.5 465.339 60.717 1.7729 1.113 0.001 - 0.546 - 0.001 - 0.871 0.009

12.0 496.601 S'1! .398 1.9042 1.114 0.002 - 0.547 - 0.082 - 0.865 0.014

12.5 529.809 66.511 2.0422 1.115 0 . 003 , - 0 . S 48 - 0.003 - 0.857 0.020 13.0 565 . 18 ® 73.083 2.1870 1.117 0 . 005, “ 0.551 - 0.005 - 0.846 0.025 13.5 602,972 78.135 2 . 33 S 9 1.120 0 . 00 ?; - 0.553 - 0.007 - 0.832 0.031

14.0 643.408 83. 695 2.4903 1.124 0.006 - 0.557 - 0.008 - 0.815 0.037

14.5 606 . 75 ? 89.792 2.6653 1.128 0.010 - 0.562 “ 0.010 - 0.795 0.042

METHANE ISOTHERM 450,0 DEG . K

MOL/L P , 0 AR OP/DO DP/O? X 8 OXB /00 xc OXC/DD XD DXD/OD

0.5 IS . 643 37.178 0.0427 1.529 - 0.199 - 0.984 0.395 - 0.516 - 0.059

1 . 0 37.180 37.015 0.0876 1.455 - 0.114 - 0.851 0.186 = 0 . 54 ? - 0.065 1.5 55 . 67 ? 36.964 0.1368 1 . 40 ? - 0. 080 - 0 . 777 0.116 - 0.580 - 0.066

2.0 74.172 37.036 0.1844 1.372 - 0.061 - 0.729 0.081 - 0.614 - 0.066 2.5 92.731 37.217 0.2364 1.345 - 0 . 04 ® - 0.694 0.060 - 0.646 - 0.065

3.0 111.406 37.497 0.2909 1.323 - 0.039 - 0.668 0.046 - 0.678 - 0.063

3.5 130.245 37. 877 0,3400 1.306 - 0.032 “ 0.647 0.037 - 0.709 - 0.060 4.0 149.302 38.368 0. 4079 1.292 - 0.026 “ 0.631 0.029 - 0.738 - 0.056 4.5 160,635 38.986 0.4705 1.280 - 0.021 - 0.618 0.023 - S .765 - 0.052

5.0 138.312 39.748 0.5362 1,270 - 0,017 - 0.607 0.019 - 0.790 - 0.047 5.5 208.408 40.666 0.6050 1.262 - 0.014 - 0.599 0.015 - 0.812 - 0.042

6.0 229.005 41. 750 0.6770 1.256 - 0.011 - 0.592 0.012 - 0.832 - 0.037 6.5 250.188 43.010 0.7525 1.251 - 0.009 - 0.587 0.009 - 0.849 - 0.031 7.0 272.045 44.451 0.8317 1,247 - 0.007 - 0.503 0.007 - 0.863 - 0.025 7.5 294.671 46.087 0.9148 1,244 - 0.005 - 0.580 0.005 - 0.874 - 0.020 8.0 318. 170 47.946 1.0019 1.242 “ 0.003 - 0.570 0.003 - 0.883 - 0.014 8.5 342 . 66 3 56,077 1.0934 1.241 “ 0.001 - 3.577 0.001 - 0.889 - 0.009

9 . 0 368.299 52.518 1.1893 1,241 “ 0. 000 - 0,577 o.ooo - 0.892 - 0.005 9.5 395.226 55.228 1.2911 1,241 - 0.000 - 0.577 0.000 - 0.894 - 0.002

10.0 423.562 58.153 1.3959 1.241 0.000 - 0.577 0.000 - 0,894 0.000 10.5 453.414 61.289 1,5069 1.241 0.000 - 0.577 - 0.000 - 0.894 0.002 11.0 484.890 64.657 1.6234 1.241 0.000 - 0.577 “ 0.000 - 0.892 0.005 11.5 518.120 68. 321 1 . 745 ? 1.241 0.001 - 0.577 - 0.001 - 0.809 0.009

12.0 553.277 72.379 1.8740 1.241 0.002 - 0.577 - 0.002 - 0.883 0.014

12.5 590.573 76.885 2.0085 1.243 0.003 - 0.579 - 0.003 - 0.874 0.020 13.0 630.241 81.865 2.1496 1.245 0.005 - 0.581 - 0.005 - 0,863 0.026

13.5 672.522 87.343 2,2975 1 . 24 © 0.007 - 0.584 - 0.007 - 0.848 0.032

METHANE ISOTHERM 500.0 DEG . K MOL/L P 9 BAR DP/OO QP/ 0 T XB OXB/DO XC QXC/OO XO DXD/OD

0.5 20.775 41.548 0.0426 1.731 - 0. 199 - 1. 026 0.395 - 0.523 - 0.065

1.0 41.559 41,603 0.0672 1.657 - 0.114 - 0.893 0.186 - 0.557 - 0.069 1.5 62.398 41.777 0.1340 1.609 - 0.080 - 0.820 0.116 - 0.591 - 0.070 2.0 83,357 42.081 0.1830 1 . 574 - 0. 061 - 0.771 0.081 - 0.626 - 0.069 2.5 104.498 42.501 0.2343 1 . 54,7 - 0. 048 - 0. 736 0.060 - 0.660 - 0.068

3.0 125.876 43.029 0.2879 1.526 - 0.039 “ 0 . 71 ® 0.046 - 0.694 - 0.065 3.5 147.545 43.668 0,3440 1 , 50 ® “ 0.032 - 0.689 0.037 - 0.725 - 0.062

4.0 169.564 44.430 0,4027 1,494 - 0.026 - 0.673 0.029 - 0,756 - 0.058 4.5 191 . 99 ® 45.331 0.4641 1.402 - 0. 021 ” 8. 660 0 . 023 - 0.784 - 0.054 5.0 214.922 46.390 0.5283 1.472 - 0.017 - 0.650 0.019 - 0.809 - 0.049

5.5 238.417 47.621 0.5955 1.464 “ 0.014 - 0.641 0.015 - 0.032 - 0.043 6.0 262.573 49.035 0.6658 1.458 - 0.011 - 0.635 0.012 - 0.853 - 0.038 6.5 207.485 50.642 0.7394 1.453 - 0.009 “ 0.629 0.009 - 0.670 - 0.032

7.0 313.249 52.450 0.8164 1.449 - 0.007 - 0,625 0.007 - 0.864 - 0.026

7.5 339.970 54.472 0.8972 1.446 “ fi , 005 - 0.622 0.005 - 0.896 - 0.020 8.0 367.762 56.738 0.9818 1,444 - 0.003 - 0.620 0.003 - 0.904 - 0.014 8.5 396 . 75 ? 59.296 1.0704 1.443 - 0.001 -0.619 0.001 - 0.910 - 0.009 9.0 427.116 62.190 1.1633 1.443 - 0.000 “ 0.619 0.000 - 0.914 “ 0.005 9.5 458.996 65.374 1.2607 1.443 - 0.000 - 0.619 0.000 - 0.916 “ 0.002

10.0 492,529 68.796 1.3628 1.443 0.000 - 0.619 0.000 - 0.916 0.000 10.5 527.831 72.452 1.4697 1.443 0.000 - 0.619 - 0.000 - 0.916 0.002

11.0 565.023 76.362 1 , 5 ® 1 ® 1.443 0.000 “ 0.619 - 0.000 - 0.914 0.005 11.5 604.247 80.593 1.6993 1,443 0.001 - 0.619 - 0.001 - 0.910 0.009

12.0 645.687 85.241 1.0223 1.443 0.002 - 0.620 - 0.002 - 8.904 0.015 12.5 689.567 90.362 1,9511 1.445 0.003 - 0.621 - 0.003 - 0.096 0.020

133
Table 12. The Joule -Thomaon inveraion locua

T,K P,MR HOL/L T» K P.BAR MOL/l

164 44.51 21.55 330 499.31 15.44

16$ 69.92 21.33 335 504.06 15.26

176 94.12 21.12 340 506.44 15.12

175 117.19 20.91 345 512.45 14.96

160 139.22 20.71 350 516.06 14.60

165 160.26 20.50 355 519.37 14.64

190 160.40 20.10 360 522.30 14.46

195 199.69 20.10 365 524.87 14.32

200 216.17 19.91 370 527.11 14.15

205 235.90 19.71 375 529.01 13.99

210 252.91 19.52 360 530.57 13.63

215 269.23 19.33 365 531.61 13.67

220 264.91 19.15 390 532.72 13.51

225 299.96 18.97 395 533.30 13.34

230 314.41 16.79 400 533.56 13.16

235 326.26 16.61 405 533.50 13.02

240 341.59 16.<*3 410 533.11 12.85

245 354.36 16.25 415 532.40 12.69

250 366.60 16.06 420 531.36 12.52

255 376.33 17.91 425 529.99 12.36

260 369.56 17.74/ 430 526.26 12.19

265 400.29 17.57 435 526.22 12.02

270 410.55 17.40 440 523.61 11.65

275 420.34 17.23 445 521.04 11.67

260 429.67 17,07 450 517.93 11.50

265 436. 54 16.90 455 514.51 11.32

296 446.96 16.74 460 510.61 11.14

295 454.97 16.57 465 506.93 10.97

366 462.53 16.41 470 502.96 10.79

305 469.66 16.29 475 496.95 10.62

310 476.41 16.09 486 494.94 10.45

315 462*73 15.92 465 490.96 10.26

320 460.65 15.76 490 467.01 10.12

325 494.16 15.60 495 463.10 9.96

134
Table 13. Thermophysical properties of the saturated liquid

For the following table we have used the Clapeyron equation to make the vapor

liquid transition at temperatures T £ T = 174.516 K. For higher temperatures we have computed around the critical point as described in section 3.4 of the text);with aid from figure 1

Column headings have the following interpretations--

DP/DT * dP/dT, vapor pressure,

DDL/DT * dp^/dT, saturated liquid,

Q, VAP * AHvap,heat of vaporization,

CV * CV

(P,T),

CS * C (T), a CP * C (P, T).

135
V

Table 13. Thermophysical properties of the saturated liquid

T P OEN v.&as O.LXQ OP/OT ODL/OT Q, VAP E H S C ) cs CP N OEG K 8 AR MOL/L L/NOL L/NOL 8AR/K HOL/L/K J/NOL- J/HOL J/HOL J/MOL/K J/HOL/K J/NOL/K J/HOL/K H/SEC 90.630 0.117 28.167 63.7807 0.03553 0. 0151 - 0. 0828 8720 . 1 3471.9 3472.

3

67.878 33 . 10 52.74 52.75 1576 92.000 0.139 28.038 54.7012 0.03567 0.0173 - 0.0831 8692 . 1 3537.0 3536.3 68.641 33.02 52.63 52.85 1564 96.000 0.127 27.871 43.7 449 0.03568 0.0211 - 0.0836 6648.9 3638.9 3639.5 69.779 32.96 53.05 53.07 1544 96.000 0.223 27.703 35.3419 0.03610 0.0254 - 0.0841 8604.5 3741.2 3742.0 70.699 32.96 53.33 53 . 36 1523

93. 0 Q 0 0.279 27.534 28.8252 0. 03632 0 . 0303 - 0.0847 8556.9 3644.9 3645.9 72.002 32.99 53.66 53.69 1502

160. 000 0.365 27.364 23.7210 0.03654 0.0359 - 0.0854 8511.7 3949.6 3951.1 73.090 33.04 54.01 54.05 1680

102. 000 0.423 27.193 19.6618 0.03677 0.0422 - 0.0861 8463.

0

4059.9 4057.4 74.163 33.06 54.36 54.41 1456 104.060 0.515 27.020 16 .4565 0.03701 0.0493 - 0.0869 8412.6 4163.1 4165.

0

75.222 33 . 11 54.72 54.78 1437

106. 006 0.621 26.665 13.8591 0.03725 0.0571 - 0.0878 6360.4 4271.3 4273.6 76.267 33 . 12 55 . 0 o 55.13 1415

108. 060 0.743 26.669 11.7502 0.03750 0.0657 - 0.0887 8306.

5

4360.4 4383.2 77 . 2)9 33.10 55.38 55.47 1393 110.000 0.886 26.690 10.0250 0.03775 0.0751 - 0.0696 8250.

7

4490.4 4493.6 76.316 33.06 55.69 55.60 1372 112.000 1.044 26.310 8.6036 0.03801 0.0654 - 0. 0906 6193. 0 4601.2 4605.2 79.324 32.96 55.98 56.11 1351 114.000 1.226 26. 128 7.4244 0.03827 0.0966 - 0.0917 6133.5 4712.7 4717.4 60.318 32.69 56.26 56.40 1329 116.000 1.431 25.943 6.4399 0.03855 0.1087 - 0.0920 8071 . 9 4624.9 4630.4 81.298 32.76 56.52 56.69 1306

118. 000 1.662 25.756 5.6131 0.03863 0.1216 - 0.0940 6008.4 4937.7 4944.2 62.267 32.63 56.78 56.96 1267 120.000 1.919 25.567 4.9146 0.03911 0 . 1358 - 0. 0953 7942 . 7 5051.1 5056.6 63.223 32.46 57.04 57.26 1266 122.000 2.206 25.375 4.3213 0.03941 0. 1507 - 0.0966 7874.8 5165.1 5173.8 64.166 32.32 57.30 57.56 1245 126.000 2.523 25. 160 3.8148 0.03971 0.1667 - 0.0980 7604.

7

5279.7 5289.7 65.102 32.17 57.58 57.90 1224 126.000 2.873 24.983 3. 3832 0.04003 0.1837 - 0.0995 7732.1 5394.9 9406.4 66.026 32.02 57.87 56.24 1203 126.000 3.258 24.783 3.0056 0.04035 0.2017 -0.1010 7657.0 5510.6 5523.9 86.940 31.66 58.19 56.62 1161 130.009 3.681 24.579 2.6612 0.04069 0.2208 - 0.1026 7579.2 5627.3 5642.2 67.644 31.75 58.53 59.03 1160 132.000 4.142 24.372 2 . 39)1 0.04103 0.2409 - 0.1043 7498 . 5 5744.5 5761.5 66.741 31.64 58.91 59.46 1136 134.000 4.665 24.162 2.1526 0.04139 0.2621 - 0. 1061 7414.6 5662.6 5661.6 69.630 31.55 59.32 59.97 1115

136. 000 5.191 23.947 1.9369 0.04176 0.2843 - 0.1080 7327.6 9961.4 6003.1 90.512 31.47 59.77 60.52 1093 136.000 5.763 23.729 1 • 7469 0.04214 0.3076 -0.1100 7237.4 6101.2 6125.6 91.366 31.42 60.25 61.11 1070 140.000 6.422 23.507 1.5791 0. 04254 0. 3321 -0.1121 7143. 4 6222.0 6249.3 92.259 31.38 60.78 61.75 1047 142.000 7.112 23.281 1.4335 0.04295 0.3576 - 0.1144 7045.5 6343.6 6374.4 93.125 31.35 61.34 62.45 1023 146.000 7.853 23. 050 1.2984 0.04336 0.3842 - 0.1168 6943.6 6466.0 6500.9 93.987 31.33 61.94 63.20 999 146.000 6.649 22. 813 1.1605 0.04383 0.4120 - 0.1194 6637.3 6590.9 6626.6 94.645 31.31 62.57 64 . 01 975

148. 000 9.502 22. 572 1.0751 0. 04430 0.4409 -0.1222 6726.5 6716.3 6756.4 95.701 31.29 63.23 64.88 951 160.000 10.416 22.324 0.9806 0.04479 0.4710 - 0.1252 6610.

6

6643.0 6669.6 96.554 31.26 63.93 65.80 927

162. 000 11.367 22.071 0.6955 0.04531 0.5022 - 0.1265 6490.

1

6971.0 7022.6 97.406 31.22 64.66 66.00 902

154. 000 12.423 21.810 0.8186 0.04565 0.5346 - 0.1321 6363.9 7100.5 7157.4 98.256 31.15 65.42 67 . 87 877 156.000 13.526 21.542 0.7494 0.04642 0.5663 - 0.1360 6232.1 7231.4 7294.2 99.105 31.09 66.23 69.03 652

156. 000 14.697 21.266 0.6865 0.04702 0.6031 • 0. 1403 6094.2 7363.8 7433.0 99.954 30.93 67.06 70.30 827 160.000 15.939 20.981 0.6296 0.04766 0.6393 - 0.1451 5949. 6 7497.9 7573.9 100.604 30.78 66.00 71.71 802 162.000 17.255 20.685 0.5773 0. 04634 0.6767 - 0.1505 5796 . 5 7633.8 7717.2 101.655 30.60 69.01 73.29 776 166.000 16.647 20.376 0.5237 0.04907 0.7155 - 0.1565 5639.5 7771.6 7863.1 102.506 30.40 70.12 75.10 749 166.000 20.118 20.059 0 .4861 0.04965 0.7557 - 0.1634 5472.1 7911.6 8011.9 103.366 30.19 71.39 77.20 723 168. 000 21.671 19.724 3 . 4460 0. 05070 0.7973 - 0.1713 5295.4 6054.0 6163.9 104.229 29.99 72.86 79.70 695

120. 000 23.308 19.373 0.4092 0.05162 0.8404 - 0.1605 5108 . 1 6199.3 6319.7 105.101 29.61 74.61 82.72 667

122. 000 25.036 19.001 0.3750 0.05263 0.8851 - 0.1913 4908. 6 6346.2 8479.9 105.966 29.69 76.73 86.47 637

126. 000 26.850 18.606 0.3434 0. 05375 0.9316 - 0.2041 4694 . 6 6501.2 6645.

5

106.666 29.67 79.36 91.19 606

126. 000 26.761 16.183 0.3139 0.05500 0.9796 - 0.2196 4463.9 6660.4 6616.6 107.614 30.19 83.09 97.72 570

126. 000 30.771 17.725 0.2851 0.05642 1.0301 - 0.2393 4212.0 8826.3 0999.9 106.776 30.36 87.23 105.74 536

180. 000 32.883 17.222 0.2599 0.05806 1.0626 - 0.2643 3933.5 9000.7 9191.6 109.779 30.64 92.59 116.71 500 182.000 35.103 16.662 0.2349 0. 06002 1.1377 - 0.2977 3620 . 4 9186.0 9396.7 110.639 31.06 99.01 132.60 462 164.000 37.435 16.022 0.2106 0.06241 1.1956 - 0.3453 3259.9 9366.6 9620.3 111.963 31.72 110.19 157.71 421 166.000 39.688 15.263 0.1665 0.06552 1.2579 - 0.4205 2630.

1

9610.2 9671.5 113.256 32.77 126.65 203.50 377 188. 000 42.471 16.294 0.1616 0.06996 1.3257 - 0.5690 2264.7 9674.3 10171.4 114.766 3 -.. 7 S 160.47 315.41 327 190. 000 45.199 12.721 0.1321 0.07661 1.4064 - 1.2723 1430.1 10256.3 16613.6 116.996 41.07 325.27 1130.96 259 190.555 45.966 10.000 0.1000 0.10000 1.4451 0.0 10641.2 11301.1 120.574 0

13#
Table 14. Thermophysical properties along isobars

The following pages give physical and thermodynamic properties along selected

isobars, as computed by methods of section 3 of the text.

The first table is for the triple-point pressure, P^ = 0. 1 17 436 bar (1. 70326 psi).

The first line of each table refers to freezing liquid on the P(T) melting line.

Each table at T < T c contains a blank line for the transition from saturated liquid

to vapor, as seen by the abrupt decrease of density.

Table headings for partial derivatives have the following interpretations--

DP/DT s dP/dT,

DP/DD s dp/dp.

The specific heat interpretations are--

CV s CV(P,T),

CP = C (P, T). P

* These tables are extrapolated beyond the range of P-p-T data used for adjusting the equation of state (T ~ 400 K, P~ 350 bar).

131
METHANE ISOBAR AT P « 0.1 17 436 BAR

T DEN VOL DP/DT OP/DO E H S CV CP M DEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/NOl J/MOL/K J/HOL/K J/MOL/K M/SEC

90.660 28. 147 0. 03553 20.7249 250-154 3471.9 3472.3 67. 878 33.10 52.75 1576

90.660 0.01566 63.781 0.001310 7.434 11429.1 1217 8oi 164.042 25.05 33.57 249

95.000 0.01495 66. 876 0.001249 7.601 11538.5 12323.8 165.603 25.03 33.53 255

109.000 0.01419 70.452 0.001165 8.224 11664.9 12492.2 167. 322 25. 02 33.49 262

105.000 0. 01351 74.025 0.001127 8.647 11791.1 12660.5 168.955 25.01 33.46 269

110.000 0.01269 77.593 0.001074 9.068 11917.3 12828.5 170.510 25.00 33.43 275

115.000 0.01232 81. 159 0.001027 9.489 12043.4 12996.5 171.996 25.00 33.42 281

120.000 0. 01100 84. 722 0.000963 9.909 12169.4 13164.4 173.418 24.99 33.40 287

125.000 0. 01133 86.283 0.000944 10.329 12295.4 13332.2 174.781 24.99 33. 39 293

130.000 0.01069 91. 843 0.000907 10.748 12421.4 13499.9 176.091 24.99 33.38 299

135.000 0.01048 95.401 0.000873 11.167 12547.3 13667.6 177.350 24. 99 33. 37 305

140. 000 Q. 01011 98. 957 0.000841 11.585 12673.

1

13835.2 178.564 24.99 33.37 311

145.000 0.00975 102.513 0.000812 12.004 12799.0 14002.9 179.735 24.99 33.37 316

150.000 0.00943 106. 066 0.000785 12.422 12924.8 14170.5 180.866 25.00 33.37 321

155.000 0.00912 109.621 0.000759 12.839 13050.7 14338.1 161.960 25.01 33.37 327

160.000 0.00664 113. 174 0.000735 13.257 13176.6 14505.7 183. 020 25.02 33. 38 332

165.000 0.00657 116.727 0.000713 13.675 13302.5 14673.3 184.047 25.03 33. 39 337

170.000 0.00631 120.279 0.000692 14.092 13428.5 143*1.0 165.044 25.04 33.40 342

175.000 0.00606 123. 630 0.000672 14.509 13554.5 15008.7 186.012 25.06 33.41 347

160.000 0. 00785 127. 381 0.000653 14.927 13680.6 15176.5 186.954 25.08 33.43 352

165.000 0.00764 130. 931 0.000636 15.344 13806.8 15344.4 187.87 0 25. 11 33. 45 357

190.000 0 .00744 134. 461 0.000619 15.761 13933.2 15512.5 188.762 25.13 33.48 362

195.000 0. 00724 136. 031 0. 000603 16.178 14059.7 15680.6 169.633 25.17 33.51 366

200.000 0. 00706 141. 580 0.000588 16.594 14186.3 15849.0 190.481 25.21 33.55 371

205.000 0.00669 145. 129 0.000573 17.011 14313.2 16017.5 191. 310 25.25 33.59 37o

210.000 0.00673 148.678 0.000560 17.428 14440.2 16186.3 192. 121 25.30 33.64 380

215.000 0. 00657 152.227 0.000547 17.845 14567.6 16355.3 192.913 25.36 33.70 384

220. 000 0. 00642 155. 775 0.000534 18.261 14695.2 16524.6 193.688 25.42 33.76 389

225.000 0.00626 159. 323 0. 000522 18.678 14823.2 16694.2 194.448 25.49 33.83 393

230.000 0.00614 162. 871 0.000511 19.094 14951.

5

1686 4.2 195. 192 25.57 33. 91 397

235.000 0.00601 166.419 0.000500 19.511 15080.2 17034.6 195.922 25.66 33.99 401

2*0 .000 0.00566 169. 967 0.000489 19.927 15209.3 17205.4 196.639 25.75 34.08 405

245.000 0.00576 173. 514 0.000479 20.344 15339.0 17376.6 197.343 25.85 34.18 409

250.000 0.00565 177. 061 0.000470 20.760 15469.

1

17548.4 198.034 25.96 34.29 413

255.000 0.00554 180. 608 0.000461 21.177 15599.8 17720.8 198.714 26.07 34.40 417

260.000 0.00543 184. 155 0.000452 21.593 15731.0 17893.7 199.364 26.20 34.53 421

265.000 0.00533 187. 702 0.000443 22.009 15862.9 18067.2 200.042 26.33 34.66 425

270.000 0. 00523 191. 249 0. 000435 22.426 15995.5 18241.4 200.692 26.47 34.79 429

275.000 0.00513 194. 796 0.000427 22.842 16128.8 18416.4 201.331 26.61 34.94 432

260.000 0.00504 196. 342 0.000419 23.258 16262.8 18592.0 201.962 26.77 35.10 43b

265.000 0.00495 201.666 0.000*12 23.674 16397.6 18768.5 202.585 26.93 35.26 440

290 .000 0. 00467 205. 435 0.000405 24.091 16533.2 18945.8 203. 200 27.10 35.43 443

295.000 0. 00479 208.981 0.000398 24.507 16669.7 19123.9 203.807 27.26 35. 60 447

300.000 0. 00471 212. 527 0 .000391 24.923 16807.1 19302.9 204.406 27.46 35. 79 450

310.000 0.00*55 219.619 0.000379 25.756 17084.7 19663.8 205.566 27. 85 36. 18 457

320.000 0.00441 226.711 0.000367 26.588 17366.4 20028.7 206.741 28.27 36.59 463

330. 000 0 . 00426 233.602 0.000356 27.420 17652.2 20397.9 207.874 28.71 37.03 470

340 .000 0.00415 240.694 0.000345 28.252 17942.6 20771.6 208.986 29.17 37.49 *7o

350.000 0.0040 3 247.985 0.000335 29. 085 18237.

7

21149.9 210.060 29.65 37.97 482

360 .000 0. 00392 255.075 0.000326 29.917 18537.7 21533.2 211.157 30.15 38.48 488

370.000 0.00381 262. 166 0.000317 30.749 18842.8 21921.5 212.218 3 0.-67 38.99 49*

360.000 0.00371 269. 256 0.000309 31.581 19153.1 22315.1 213.265 31.20 39.52 499

390 .000 0. 00362 276. 346 0.000301 32.413 19468.8 22714.1 214.298 31.75 *0.07 5 0 5 *00.000 0.00353 263. *36 0.000293 33.245 19789.9 23118.5 215. 320 32. 30 *0.62 510

420.000 0. 00336 297.616 0.000279 34.909 20449.0 23944.1 217.329 33.43 41.75 521

440 .000 0. 00321 311.795 0. 000267 36.574 21130.9 24792.5 219.298 34.58 42.90 532

460.000 0.00307 325.973 0.000255 36.238 21835.9 25664.0 221.230 35.74 *4. 06 542

460 . 000 0. 00294 340. 151 0. 000244 39.901 22564.1 26558.6 223. 130 36.90 45.22 552

500. 000 0. 00282 354. 328 0 .000235 41.565 23315.3 27476.4 224.999 38.05 46. 37 562

138
METHANE ISOBAR AT P * 0.5 BAR

T OEN VOL DP/DT DP/OO E H S CV CP w DEG K MOL/L L/HOL BAR/K BAR-L/MOL J/HOL J/MOL. J/MOL/K J/MOL/K J/MOL/K M/SEC

90.&90 26.1*0 0. 03553 20.7236 250.205 3*72.0 3*73.7 67.880 33.10 52.75 1576

95.000 27.709 0.03599 19.6133 233.73* 3689.6 3691.* 70.338 32.96 53.20 1534

100.000 27.365 0.0365* 18.3859 21*. 90* 39*9.6 3951.* 73.088 33.0* 5*. 05 1480

103.701 27.0*6 0.03697 17.5167 201.267 *1*7.0 *1*8.6 75.06* 33.11 5*. 72 14*0

103.701 0.05919 16.095 0.005001 0.269 11719.2 12563.9 156.261 25.23 3*. 19 26*

105.000 0.050*2 17.119 0.00*932 8.366 11752.* 12608.* 156.686 25.22 3*. 1* 266

110.000 0.05562 17.976 0.0 0*686 8.831 11880.1 12779.0 158. 271 25.17 3*. 01 273

115.000 0.05309 10. 03* 0.00**65 9.271 12007.3 129*9.0 159.781 25.13 33.90 279

120.000 0.05000 19.607 0.00*266 9.709 1213*.

13118.6 161.222 25.10 33. 82 296

125.000 0.0*669 20.537 0.00*005 10.1** 12260.9 13287.® 162,601 25.08 33. 76 292

130.000 0.0*676 21. 305 0.003919 10.577 12387.* 13*56.7 163.92* 25.07 33.70 298

135.000 0. 0**90 22.232 0.003767 11.008 12513.7 13625.3 165.195 25.06 33.66 304

1*0.000 0.0*333 23. 077 0.003627 11. *37 12639.9 13793.8 166. *18 25.05 33.63 309

1 <*5.0 00 0.0*101 23.920 0.003*97 11.065 12766.1 13962.1 167.598 25.05 33.60 315

150.000 0. 0*030 2*. 763 0.003376 12.292 12892.1 1 1*130.3 168.736 25.05 33.58 320

155.000 0. 03906 25. 605 0. 00326* 12.71® 1301®.

1*298.* 169.837 25.05 33.56 326

160.000 0.03701 26. **6 0.003159 13.1** 131**.1**66.* 170.902 25.05 33.55 331

165.000 0.03665 27.206 0.003061 13.568 13270.1 1*63*.* 171.935 25.06 33.5* 336

170.000 0.03556 28. 125 0.002968 13.992 13396.1 1*802.3 172.936 25.07 33.5* 3*2

175.000 0. 03*53 20. 96* 0.002882 1*.*15 13522.1 1*970.3 173.908 25.09 33.5* 3*7

100.000 0.03355 29.802 0.002800 1*.837 136*8.2 15138.3 17*. 853 25.10 33.55 352

105.000 0. 0326* 30.6*0 0.002723 15.259 1377*.15306.3 175.773 25.13 33.57 356

190.000 0.03177 31. *77 0.002650 15.681 13909.6 15*7*.* 176.666 25.16 33.59 361

195.000 0. 03095 32.31* 0.002581 16.102 1*027.0 156*2.7 177.5*1 25.19 33. 61 366

200.000 0.03016 33. 151 0.002515 16.523 1*153.5 15811.1 178. 392 25.23 33.6* 371

205.000 0.029*2 33.987 0.002*53 16.9** 1*280.2 15979.6 179.223 25.27 33.68 375

210.000 0.02072 3*. 823 0.00239* 17.36* 1**07.

161*®.* 180.035 25.32 33.72 380

215.000 0.0200* 35.659 0.002336 17.78* 1*53*.* 16317.* 180.830 25.37 33.77 384

220.000 0. 027*0 36. *95 0.06228* 18.20* 1*661.9 16*86.6 181.607 25.** 33.83 308

225.000 0.02679 37. 330 0.002232 18.623 1*789.7 16656.2 182.368 25.51 33.90 393

230.000 0.02620 38. 165 0.002183 19.0*3 1*917.8 16826.1 183.11* 25.58 33.97 397

235.000 0.0256* 39.000 0.002136 19. *62 150*6.* 16996.* 183.8*5 25.67 3*. 05 401

2*0.000 0. 02510 39.835 0.002092 19.881 15175.3 17167.1 18*. 563 25.76 3*. 1* 405

2*5.000 0.02*59 *0.670 0.0020*8 20.299 1530*.

17338.3 185.268 25.86 3*. 2* 409

250.000 0.02*09 *1.50* 0.002007 20.718 15*3*.

17509.9 185.960 25.97 34. 3* 413

255. 000 0. 02362 *2. 339 0. 001967 21.137 15565.2 17682.2 186.6*1 26.0® 3*. *5 417

260.000 0.02316 *3. 173 0.001929 21.555 15696.3 17855.0 187.312 26.20 3*. 57 421

265.000 0.02272 **. 007 0.001893 21.973 15628.0 18028.* 187.971 26.33 34.70 425

270.000 0.02230 **. 8*1 0.001657 22.391 15960.* 18202.* 188.621 26. *7 34.8* 429

275.000 0.02109 *5.675 0.001823 22.809 16093.5 18377.2 189.262 26.62 34.98 432

200.000 0.02150 *6.509 0. 001791 23.227 16227.3 18552.7 189.893 26.77 35.13 *36

205.000 0.02112 *7.3*2 0.001759 23.6*5 16361.9 18729.0 190.517 26.9* 35.29 *39

290.000 0.02076 *8. 176 0.001728 2*. 062 16*97.* 18906.1 191.132 27.11 35.46 4*3

295.000 0.020*0 *9. 009 0.001699 2*. *80 16633.6 1908*.

191.7*0 27.28 35.64 **6

300.000 0.02006 *9.8*3 0.001670 2*. 898 16770.8 19263.0 192.3*0 27. *7 35.62 45 0 310.000 0.019*1 51.509 0.001616 25.732 170*8.1 19623.5 193.521 27.86 36.21 457

320.000 0.01801 53. 176 0.001566 26.567 17329.3 19988.1 19*». 677 28.27 36-62 463

330.000 0. 01023 5*. 8*2 0.001518 27.*?1 1761*.® 20356.9 195.810 28.71 37.06 470

3*0.000 0.01770 56.508 0.001*73 28.235 1790*.® 20730,2 196.923 29.17 37.52 476

350.000 0.01719 58. 17* 0.001*31 29.069 18199.5 21108.2 198.018 29.66 38.00 ,6 2 360.000 0.01671 59. 839 0.001391 29.903 18*99.1 21*91.0 199. 095 30.16 38.50 488

370.000 0.01626 61.505 0.001353 30.736 10903.8 21879.0 200. 157 30.67 39.01 494

300.000 0.01503 63. 170 0.001317 31.570 19113.7 22272.2 201.20 * 31.21 39.5* 499

390.000 0.015*2 6*. 835 0.00126* 32. *03 19*29.0 2267 0.8 202.238 31.75 40.09 505

*00.000 0.0150* 66.500 0.001251 33.236 197*9.8 2307*.

203.260 32.30 40.64 511

*20.000 0.01*32 69.830 0.001192 3*. 902 20*08.1 23899.6 205.270 3 3.** 41.77 521

**0.000 0. 01367 73. 160 0.001137 36.568 21089.3 2*7*7.

207.2*0 3*. 59 42.92 532

*60.000 0.01307 76. *89 0.001088 30.233 21793.6 25618.0 209. 173 35.75 44.08 54 2 *00.000 0.01253 79. 817 0.0010*2 39.098 22521.0 26511.9 211. 073 36.91 45.23 552

500.000 0.01203 83.1*6 6.001001 *1.563 23271.6 27*28.9 212.9*3 38.06 46- 38 562

139
METHANE I SOSA* AT P a 1.0 BAR

T DEN VOL DP/DT DP/OD E H S CV CP * DEG K NOL/l l/MQL BAR/K iAR-L/MOL J/NOL J/HOL . J/MOL/K J/MOL/K j/hol/k M/SEC

90.703 26.149 0.03553 20.7220 250.272 3472.1 3475.7 67.682 33.11 52.75 1577

95.004 27.791 0.03596 19.6154 233.656 3689.0 3692.6 70.333 32.96 53.20 153*

100.000 27.367 0.03654 18.3885 215.036 3949.0 3952.7 73.062 33.04 54.04 1481

105.000 26.935 0.03713 17.2222 196.694 4216.5 4220.2 75.741 33.12 54.95 1426

110.000 26.491 0.03775 16.1109 178.956 4490.3 4494.0 76.317 33.06 55.79 1372

111**72 26.356 0.03794 15.7932 173.861 4571.9 4575.7 79.060 33.01 56.03 1356

111.472 0.11170 8.953 0.009546 6.631 11686.4 12781.6 152.697 25.42 34.65 272

115.000 0.10794 9.265 0.009198 8.962 11977.9 12904.3 153.780 25.35 34.67 276

120.000 0.10306 9.70 3 0.008753 9.425 12106.9 13077.2 155.251 25.26 34.47 283

125.000 0.09663 10. 139 0.008356 9.882 12235.3 13249.3 156.654 25.23 34.31 289

130.000 0.09456 10.573 0.007996 10.334 12363.3 13420.6 157.997 25.19 34.18 296

135.000 0.09067 11.00* 0. 007670 10.762 12490.9 13591.4 159.265 25.16 34.08 302

140.000 0.06746 11.434 0.007371 11.227 12618.2 13761.7 160.523 25.14 34.00 308

145.000 0. 06430 11. 663 0. 007096 11.668 12745.3 13931.6 161.715 2 5.12 33.93 313

150.000 0.06137 12.290 0.006842 12.108 12872.2 14101.2 162.665 25.11 33.87 319

155.000 0.07664 12.717 0.006607 12.545 12999.0 14270.6 163.975 25.11 33.63 325

160.000 0.07609 13.142 0.006388 12.969 13125.6 14439.8 165.046 25.11 33.79 330

165.000 0. 07371 13. 567 0.006184 13.414 13252.1 14608.8 166.067 25.11 33.77 335

170.000 0.07146 13.990 0.005993 13.846 13376.6 14777.7 167.095 25.11 33.75 341

175.000 0.06938 14.414 0.005814 14.277 13505.1 149*6.5 168.073 25.12 33.73 346

160.000 0.06740 14. 837 0.005646 14.707 13631.6 15115.3 169.023 25.14 33.73 351

165.000 0.06554 15.259 0.005487 15.136 13758.1 15284.0 169.947 25.16 33.73 356

190.000 0. 06377 15.681 0.005337 15.564 13664.7 15452.8 170.847 25.16 33.74 360

195.000 0.06210 16. 102 0.005196 15.991 14011.4 15621.6 171.723 25.21 33.75 365

200.000 0.06052 16.523 0.005062 16.416 14138.2 15790.5 172.578 25.25 33.77 370

205.000 0. 05902 16. 944 0. 004935 16.844 14265.2 15999.6 173.412 25.29 33.80 375

210.000 0.05759 17.364 0.004814 17.269 14392.4 16128.8 174.227 25.34 33.84 379

215.000 0.05623 17.784 0.00*699 17.693 14519.8 16298.2 175.024 25.39 33.86 384

220.000 0.05493 16.204 0.004590 18.118 14647.5 16467.9 175.603 25.46 33.93 389

225.000 0. 05369 16.624 0.004485 18.541 14775.4 16637.8 176.567 25.52 33.99 392

230.000 0.05251 19. 043 0.004386 18.964 14903.8 16806.1 177.314 25.60 34.06 397

235.000 0.05138 19. 463 0.004291 19.387 15032.4 16978.7 176.046 25.66 34.14 401

2*0.000 0.05030 19.682 0.004199 19.810 15161.5 17149.7 178.767 25.77 34.22 405

245.000 0.04926 20. 300 0.004112 20.232 15291.1 17321.1 179.474 25.87 34. 31 409

250.000 0.04626 20.719 0.004028 20.654 15421.2 17493.1 160.168 25.96 34.41 413

255.000 0.04731 21.136 0.003946 21.075 15551.8 17665.5 180.650 26.09 34.52 417

260.000 0. 04639 21.556 0.003871 21.496 15682.9 17636.5 161.522 26.21 34.64 421

265.000 0.04551 21.975 0.003797 21.917 15814.7 18012.2 182.163 26.35 34.76 *25

270.000 0.04466 22. 393 0.003726 22.338 15947.2 16186.4 162.834 26.48 34.90 *28

275.000 0.04384 22.611 0.003657 22.759 16080.3 18361.4 183.475 26.63 35.0* 432

260.000 0. 04305 23. 229 0.003591 23.179 16214.2 16537.1 164.106 26.76 35.19 *36

265.000 0.04229 23.6*7 0.003527 23.599 16348.9 18713.5 184.732 26.95 35.35 439

290.000 0.04155 24.065 0.003465 24.019 16464.3 18690.8 165.346 27.11 35.51 443

295.000 0.04065 24.462 0.003406 24.439 16620.7 19066.9 165.957 27.29 35.68 446

300.000 0. 04016 24.900 0.003349 24.856 16757.9 19247.9 166.556 27.47 35.66 450

310.000 0.03666 25. 7 35 0.003239 25.697 17035.2 19608.7 167.740 27.86 16.25 456

320.000 0.03764 26.570 0.003137 26.535 17316.5 19973.4 106.697 28.26 36.66 463

330.000 0.03649 27. 404 0. 003041 27. 373 17602.

0

20342.4 190.032 26.72 37.09 469

3*0.000 0.03541 26. 236 0.002951 26.210 17892.0 20715.9 191.146 29.18 37.55 476

350.000 0.03440 29. 073 0.002866 29.046 16186.7 21094.0 192.241 29.66 36.03 482

360.000 0. 03344 29.906 0. 002766 29.863 16466.3 21477.0 193.320 30.16 36.53 489

370.000 0.03253 30.740 0.002710 30.719 16791.0 21665.1 194.362 30.66 39.0* 494

360.000 0.03167 31.574 0.002638 31.554 19101.0 22256.3 195.430 31.21 39.57 499

390.000 0.03066 32.407 0.002570 32.390 19416.2 22657.0 196.465 31.76 *0.11 505

400.000 0. 03006 33. 241 0.002506 33.225 19737.0 23061.0 197.488 32.31 40.66 511

420.000 0.02665 34.907 0.002386 34.894 20395.3 23866.0 199.496 33.44 *1.79 521

4*0.000 0.02734 36.573 0.002277 36.563 21076.4 24733.7 201.469 34.59 *2.93 532

460.000 0. 02615 36.238 0.002177 38.231 21760.6 25604.4 203.403 35.75 *4.09 542

460.000 0.02506 39. 904 0. 002006 39.699 22507.9 26496.3 205.304 36.91 45.25 552

500.000 0.02406 41.569 0.002002 41.565 23256.4 27415.2 207.174 36.06 *6.40 562

140
METHANE ISOBAR AT P * 1.5 BAR

T BEN VOL DP/OT OP7 DO E H S CW CP H DEG K MQL/L L/MOL 0AR/K 8AR-L/M0L J/MOL J/MOL J/MOL/

J/MOL/K J/MOL/K M/SEC

90.715 20.150 0.03552 20.7203 250.339 3472.3 * 3477.6 67.884 33.11 52.74 1577

95.000 27.793 0.03596 19.6175 233.978 3688.5 3693.9 70.327 32.96 53. 19 153*

100.000 27.370 0.03654 18.3911 215.168 3948.5 3954.0 73.076 33.05 54.03 1481 105.000 26. 937 0.03712 17.2252 196.833 4215.9 4221.4 75.735 33.13 54.9* l*2o

110.000 26.494 0.03774 16. 1144 179.104 4489.5 4495.2 78.310 33. 06 55.78 1372

115.000 26.037 0.03641 15.0526 162.057 4768.5 4774.2 80.807 32.83 56.55 1319

116.621 25.886 0. 03863 14. 7180 156.687 4859.8 4865.6 81.600 32.72 56.78 1302 116.621 0. 16213 6.168 0.013994 8.800 11991.4 12916.6 150.648 25.57 35.45 276 120-000 0. 15695 6.372 0.013498 9.131 12080.

13036.0 151.657 25.49 35.21 280 125. 000 0.14992 6.670 0.012838 9.613 12210.9 13211.4 153.089 25.40 34.93 287 130.000 0.14355 6. 966 0.012250 10.086 12340.7 13385.6 154.454 25.33 34.72 29*

135.000 0.13775 7.260 0.011722 10.552 12469.

13558.® 155. 761 25.28 34.54 300 140.000 0. 13242 7.552 0.011243 11.012 12598.4 13731.2 157.015 25.24 34.40 306 149.000 0. 12752 7. 842 0.010806 11.468 12726.7 13903.0 158.220 25.21 34.29 312 150.000 0. 12296 8. 131 0.010405 11.920 12854.5 14074.2 159.381 25.19 34.19 318 155.000 0. 11878 8.419 0.010035 12.369 12982.2 142*5.0 160.501 25.17 34. 12 323 160.000 0.11486 8. 706 0.009692 12.814 13109.6 14415.5 161.583 25.16 34.05 329 165.000 0.11120 6.992 0.009374 13.258 13236.8 14585.7 162.630 25.16 34.00 33*

170. 000 0. 10778 9. 278 0.009077 13.699 13364.0 14755.7 163.644 25.16 33.96 339 175.000 0.10457 9.563 0.008799 14.138 13491.0 14925.5 164.628 25.16 33.93 3*6 ioo.ooo 0.10155 9. 847 0.008539 14.575 13618.0 15095.1 165.584 25.18 33.91 350 105.000 0.09671 10. 131 0.008294 15.011 13745.0 15264.7 166.512 25. 19 33.89 355 190.000 0. 09b02 10.414 0.008064 15.445 13872.1 15434.2 167.416 25.21 33.89 360 195.000 0.09348 10. 697 0.007846 15.878 13999.2 15603.7 168.297 25.24 33.89 365 200.000 0.09108 10.980 0.007641 16.310 14126.3 15773.3 169. 155 25.28 33.91 369 205.000 0.08879 11.262 0.007446 16.741 14253.7 15943.0 169.992 25.32 33.93 37* 210.000 0.06663 11.544 0.007261 17.171 14381.1 16112.7 170.810 25.36 33.95 379 215.000 0. 08456 11. 826 0.007086 17.601 14506.8 16282.7 171.610 25.41 33.99 383 220 .000 0.08260 12. 107 0.006919 18.029 14636.8 16452.8 172.391 25.47 34.0* 387 225.000 0.08072 12.388 0.006760 18.457 14765.

16623.2 173. 157 25.54 34. 09 392 230.000 0. 07893 12.669 0.006608 18.884 14893.5 16793.9 173.907 25.62 34.15 396 235. OOO 0.07722 12.950 0.006463 19.310 15022.4 16964.9 174.642 25.70 34.22 400 240.000 0.07556 13.230 0.006324 19.736 15151.7 17136.2 175.363 25.79 34.30 405 245.000 0.07*02 13. 511 0.006191 20.162 15281.5 17308.0 176. 071 25. 89 34.39 409

250.000 0. 07251 13. 791 0.006064 20.587 15411.7 17480.3 176.767 25.99 34.48 *13 255.000 0.07107 14.071 0.005942 21.011 15542.4 17653.1 177.451 26.10 34.59 *17

2b0 .000 0. 06968 14. 351 0.005825 21.435 15673.8 17826.4 178.124 26.23 34.70 *20 265.000 0. 06835 14. 630 0.005713 21.859 15805.7 18000.3 178.786 26.36 34.83 424 270.000 0.06707 14.910 0 . 0 Q5b05 22.282 15938.3 18174.8 179.438 26.49 34.96 428

275.000 0.06583 15.190 0.005501 22.705 16071.6 18350.0 180.081 26.64 35. 10 432 260.000 0.06465 15.469 0.005401 23.128 16205.6 18525.9 180.715 26.79 35.2* 4 35 285. 000 0. 06350 15. 748 0.005304 23.550 16340.4 1870 2.6 181.340 26.95 35.40 439 290.000 0.06239 16. 028 0.005211 23.972 16475.9 18880.1 181.957 27.12 35.56 443 295.000 0. 06132 16. 307 0.005121 2*.394 16612.4 19058.4 182.566 27. 30 35.73 44o

300.000 0.06029 16.586 0.005034 24.816 16749.7 19237.6 183.168 27. *8 35.91 *50 310.300 0. 05833 17. 144 0.004869 25.658 17027.2 19598.8 184.352 27.87 36.29 46o 320.000 0.05649 17.701 0.004715 26.500 17308.6 19963.8 185.510 28.29 36.70 463 330.000 0.05477 18. 259 0.004570 27.340, 17594.3 20333.1 186. 646 26.72 37.13 469

3 *0 . 0 00 0.05315 18. 816 0 .004434 28.180 17884.4 20706.8 187.761 29. 19 37. 68 476

350. 000 0. 05162 19. 373 0.004306 29.020 18179.3 21085.2 188.857 29.67 38.06 482

360.000 0.05016 19.930 0.004185 29.859 18479.0 21468.4 189.937 30.17 38.56 488

370.000 0.04881 20.486 0.004071 30.697 18783.8 21856.7 191.000 30.69 39.07 494 380.000 0.04752 21.0*3 0.003962 31.535 19093.8 22250.2 192. 049 31.22 39.59 499

390.000 0.04630 21.599 0.003860 32.373 19409.1 22649.0 193.084 31.76 40.13 505 400.000 0.04514 22. 155 0.003763 33.210 19730.0 23053.2 194. 107 32.31 *0.68 511 420 .000 0.04298 23. 267 0.003582 34.883 20388.4 23878.5 196.119 33.45 *1.81 521 *40.000 0.04102 24. 379 0.003418 36.555 21069.6 24726.4 198. 091 34.60 *2.95 532 460.000 0. 03923 25.490 0.003268 38.226 21773.8 25597.3 200. 025 35.76 4*. 11 542 480.000 0 •'0 3 7 5 9 26.601 0.003131 39.896 22501.2 26491.4 201.927 36.92 *5. 2b 552 500.000 0. 03b09 27.712 0.003006 41.565 23251.7 27408.5 203.798 36.07 *6.41 5o2

141
METHANE ISOSAft AT P 2.0 BAR

T DEN VfOL DP/OT OP/DD E H S CV CP w OEG K HOL/L L/HOL 8AR/K BAR-L/MOL J/HOL J/MCH. J/MOL/K J/MOL/K J/MOL/K 1/SEC

90.728 20.151 0.03552 20.7187 250.406 3472.4 3479.5 67.886 33.12 52.74 1577

95.000 27.795 0.03590 19.6196 234.100 3688.0 3695.2 70.322 32.97 53. 19 153*

100.000 27.372 0.03653 18. 3937 215.299 3947.

9

3955.2 7 3.07 1 33.05 54.03 1481

105.000 26.940 0.03712 17.2283 196.973 4215.2 4222.6 75.729 33.13 54.93 1*27

110.000 26.497 0.03774 16.1179 179.251 4488.8 4496.4 70.304 33.07 55.78 137 3 115. 000 26.040 0.03840 15.0566 162.212 4767.7 4775.3 60.800 32.83 5b. 54 1313

120.009 25.568 0.03911 14.0385 145.897 5051.0 5056.8 83.222 32.48 57.27 1266

128.588 25.511 0.03920 13.9214 144.028 5084.5 5092.4 83.502 32.43 57.36 1263

120*580 0.21140 4.730 0.016414 8.807 12068.5 13014.5 149.205 25.72 36.0 1 279

125.000 0. 20270 4. 933 0.017557 9.3 36 12185.9 13172.6 150.492 25.59 35.63 285

130.000 0.19376 5. 161 0.016699 9.832 12317.7 133*9.9 151.883 25.48 35.30 291

135.000 0.18566 5. 386 0.015937 10.317 12448.6 13525.8 153.210 25.40 35.05 298

140 .000 0. 17028 5.609 0.015253 10.795 12578.7 13700.5 154.481 25.35 34. 84 30*

145.000 0.17151 5. 631 0. 014634 11.266 12708.1 13874.3 155.700 25.30 34.67 310

150.000 0.16527 6. 051 0.014069 11.731 12837.1 140*7.3 156.873 25.26 34.53 316

155.000 0.15949 6. 270 0.013551 12.192 12965.7 14219.7 150. 004 25.24 34.42 322

160.000 0.15413 6.480 0.013074 12.648 13094.0 14391.6 159.095 25.22 34. 32 328

165.000 0.14914 6.705 0*012632 13.101 13222.0 14563.0 160. 150 25.21 34.25 333

170.000 0.14440 921 0. 012222 13.551 13349.9 14734.1 161.171 25.21 34.18 338

175.000 0.14011 7. 137 0.011839 13.998 13477.5 14904.9 162.161 25.21 34.13 3**

180.000 0.13601 7.352 0.011461 14.443 13605.1 15075.5 163. 122 25.21 34.09 3*9

105.000 0.13216 7.567 0.011145 14.886 13732.6 15246.0 164.056 25.23 34.07 35*

190.000 0.12852 7.701 0. 010830 15.326 13060.1 15416.3 164.964 25.25 34.05 359

195.000 0.12500 7. 995 0.010533 15.765 13987.6 15506.6 165.649 25.27 34.0* 36*

200.000 0.12183 a. 206 0.010252 16.203 14115.

2

15756.8 166.710 25.30 34.04 369

205.000 0. 11875 8.421 0.009987 16.639 14242.9 15927.1 167.551 25.34 34.05 373

210.000 0.11583 8.63* 0.009736 17.074 14370.7 16097.5 168.372 25.38 34.07 378

215.000 0. 11305 3. 8*6 0.009497 17.508 1*498.7 16267.9 169. 174 25.43 34. 1 0 383

220.000 0.11040 9. 058 0.009271 17.941 14627.0 16438.6 169.958 25.49 34.14 387

225.000 0.10788 9.270 0.009055 18.372 14755.5 16609.5 170.726 25.56 34. 19 391 230.000 0. 10547 9.482 0.008849 18.803 14884.3 16780.6 171.47 8 25.63 34.24 396

235.000 0. 10317 9.693 0.000653 19-233 15013.4 16952.0 172.215 25.71 34.31 400

240.000 0. 10097 9.904 0.008466 19.663 15142.9 17123.0 172.938 25.80 34.38 40*

245.000 0.09886 10.115 0.008287 20.091 15272.9 17296.0 173.640 25.90 34.47 408

250.000 0.09684 10.326 0.008115 20.519 15403.3 17466.6 174.345 26.00 3*. 56 412

255.000 0.09490 10.537 0.007950 20.947 15534.3 17641.7 175.031 26.12 34.66 416

260.000 0. 09304 10.748 0.007793 21.374 15665.8 17815.3 175.705 26.24 34.77 420

265.000 0.09126 10.958 0.007641 21.800 15797.9 17989.5 176.366 26.37 34.89 42*

270.000 0.08954 11. 169 0.007495 22.226 15930.6 18164.3 177.022 26.50 35.02 4 28 275.000 0.08788 11. 379 0.007355 22.651 16064.0 10339.8 177.665 26.65 35.13 432

200.000 0.08629 11.589 0.007220 23.076 16198.2 18516.0 178.300 26.80 35. 30 *35

285.000 0.08475 11.799 0.007090 23.501 16333.

1

18692.9 178.926 26.96 35.45 439

290.000 0.08327 12. 009 0.006965 23.925 16468.8 10870.6 179.544 27.13 35.61 442

295.000 0.08104 12.219 0.006844 24.349 16605.4 19049.2 160.154 27.31 35.78 44b

300.000 0.08046 12.429 0.006728 24.772 16742.8 19228.6 180.757 27.49 35. 96 449

310. 000 0. 07783 12.848 0.006506 25.610 17020.5 19590.1 181.942 27.00 36.33 456

320.000 0.07537 13.267 0.006299 26.463 17302.1 19955.6 163.102 28.29 36.74 463

330.000 0.07307 13.686 0.006104 27.3,07 17568.0 20325.2 184.239 28.73 37.17 469

340.000 0. 07090 14. 105 0.005922 28.150 17870.3 20699.2 185.355 29.19 37.62 476

350.000 0.06886 14.523 0.005750 28.993 18173.3 21077.9 166.453 29.68 30. 09 482

360.000 0.06693 14.9*1 0.005588 29.834 18473.

1

21461.4 187.533 30.18 38.59 488

370.000 0.06511 15.359 0.005435 30.675 18778.

1

21649.9 186.597 30.69 39.10 *9*

300.000 0.06338 15.777 0.005290 31.515 19088.2 22243.6 189.646 31.22 39.62 499

390.000 0.06175 16. 195 0.005152 32.355 19403.7 22642.7 190.663 31.77 *0.16 505

400.000 0.06020 16.613 0.005022 33.194 19724.6 23047.1 191.706 32.32 *0.71 510

420.000 0. 05732 17. 447 0.004781 34.871 20363.2 23672.7 193. 719 33.45 41.83 521

440.000 0.05470 18.282 0.004561 36.546 21064.5 24720.9 195.692 34.60 42.97 532

460.000 0.05231 19. 116 0.004361 38.219 21766.9 25592.2 197.627 35.76 *4.13 542

400.000 0.05013 19.950 0.00*178 39.892 22*96.5 26406.5 199. 530 36.92 *5. 28 552

500.000 0.04012 20.783 0.004010 41.563 23247.1 27403.6 201.401 38.07 *6.42 562

1 42
METHANE ISOBAR ATP® 3.0 BAR

T DEN VOL DP/OT DP/DO e H S cv CP W OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/HOL J/MOL- J/MOL/K J/MOL/K J/MOL/K M/SEC

90.754 26.153 0.03552 20.7154 250.539 3472.7 3463.4 67.690 33.12 52.73 1577

95.000 27.799 0.03597 19.6236 234.344 3667.0 3697.8 70.311 32.98 53. 18 1535

100.000 27.377 0.03653 16.3988 215.562 3946.6 3957.7 73.059 33.06 54.02 1482

105.000 26.945 0.03711 17.2344 197.253 4214.0 4225.1 75.717 33.14 54.92 1427

110.000 26.502 0. 03773 16. 1250 179.545 4487.4 4498.8 78.291 33.08 55.76 1374

115.000 26.046 0.03839 15.0647 162.520 4766.1 4777.6 80.767 32.84 56.51 1320

120.000 25.574 0.03910 14.0476 146.216 5049.2 5060.9 63.207 32.49 57.25 1267

125.000 25. 064 0.03987 13.0680 130.649 5336.6 5346.6 85.960 32.09 58.06 1214

126.661 24.915 0. 04014 12.7462 125.577 5434.3 5446.3 66.339 31.97 58.37 1196

126.661 0. 30803 3.246 0.027276 8.940 12178.8 13152.6 147.174 25.98 37.09 282

130.000 0.29629 3. 352 0.026263 9.302 12269.4 13275.2 146.128 25.35 36.68 287

135.000 0. 26492 3. 510 0.024913 9.833 12404.4 13457.3 149.562 25.70 36.19 294

140.000 0.27287 3.665 0.023728 10.349 12537.9 13637.3 150.912 25.58 35.81 300

145.000 0.26193 3. 616 0.022674 10.653 12670.2 13615.6 152.063 25.59 35.51 307

150.000 0.25193 3.969 0.021727 11.347 12601.7 13992.5 153.263 25.44 35.27 313

155.000 0. 24274 4. 120 0.020868 11.833 12932.5 14168.4 154.416 25.39 35.07 319

160.000 0.23426 4. 269 0.020085 12.313 13062.7 14343.3 155.526 25.39 34.90 325

165.000 0.22640 4. 417 0.019366 12.786 13192.4 14517.4 156.598 25.32 34.76 331

170.000 0.21909 4. 564 0. 010703 13.254 13321.7 14691.0 157.634 25.30 34.65 336

175.000 0.21227 4. 711 0.018089 13.719 13450.7 14664.0 158.637 25.29 34.56 342

lao.ooo 0.20589 4. 857 0.017518 14.179 13579.5 15036.6 159.618 25.29 34.48 347

165.000 0. 19991 5.002 0.016964 14.636 13708.2 15206.9 160.554 25.30 34.42 352

190.000 0.19426 5. 147 0.016466 15.090 13636.7 15380.9 161.471 25.31 34.38 357

195.000 0.16897 5. 292 0.016017 15.541 13965.1 15552.7 162.363 25.33 34. 34 362

200.000 0.16396 5. 436 0.015577 15.990 14093.6 15724.4 163.233 25.36 34.32 367

205.000 0. 17922 5. 580 0.015162 16.437 14222.1 15696.0 164.060 25.39 34.31 372

210.000 0.17473 5.723 0.014769 16.861 14350.6 16067.6 164.907 25.43 34.32 377

215.000 0.17047 5. 666 0.014398 17.324 14479.3 16239.2 165.715 25.48 34.33 381

220.000 0.16641 6. 009 0.014046 17.766 14608.2 16410.9 166.504 25.53 34.35 386

225.000 0.16255 6. 152 0.013711 18.206 14737.3 16582.8 167.277 25.60 34.39 390

230.000 0.15666 6.294 0.013393 18.644 14666.6 16754.9 168.033 25.67 34.43 395

235.000 0.15537 6. 436 0.013090 19.081 14996.3 16927.2 168.774 25.75 34.49 399

240.000 0. 15201 6. 578 0.012801 19.518 15126.3 17099.8 169.501 25.83 34.55 403

245.000 0. 14660 6.720 0.012525 19.953 15256.7 17272.8 170.214 25.93 34.63 408

250.000 0.14573 6. 662 0.012260 20.387 15387.6 17446.1 170.914 26.03 34.71 412

255.000 0. 14279 7. 003 0.012006 20.620 15518.9 17619.9 171.602 26.14 34.80 416

260.000 0.13996 7. 145 0.011765 21.252 15650.8 17794.2 172.279 26.26 34.91 420

265.000 0.13725 7.286 0.011533 21.664 15783.3 17969.1 172.945 26.39 35.02 424

270.000 0.13464 7.427 0.011310 22.115 15916.4 18144.5 173.601 26.53 35.14 427

275.000 0.13213 7.568 0.011096 22.545 16050.1 18320.6 174.247 26.67 35.27 431

260.000 0.12972 7.709 0.010690 22.975 16184 .

18497.3 174.884 26.82 35.41 435

265.000 0. 12739 7. 850 0.010691 23.404 16319.8 18674.7 175.512 26.96 35.56 438

290.000 0. 12516 7. 990 0.010500 23.632 16455.8 18853.0 176.132 27.15 35.72 442

295. 000 0.12296 8. 131 0.010316 24.260 16592.7 19032.0 176.743 27.33 35.88 446

300.000 0.12090 8. 272 0.010138 24.667 16730.4 19211.8 177.348 27.51 36.05 4h 9 310.000 0.11693 6.552 0.009800 25.541 17008.5 19574.3 178.536 27.89 36.42 45o

320.000 0.11321 8.633 0.009485 26.392 17290.6 19940.5 179.699 28.31 36.82 463

330.000 0. 10973 9. 113 0.009190 27.242 17576.9 20310.6 160.638 28.75 37. 24 469

340.000 0.10646 9.393 0.008912 28.091 17867.6 20685.5 161.956 2 9.21 37.69 475

350.000 0. 10336 9.673 0.008652 28.939 18162.9 21064.6 183.056 29.69 38.16 482

360.000 0.10047 9. 953 0.008406 29.765 18463.

21448.9 184. 137 30.19 38.65 463

370.000 0.09773 10.232 0.006174 30.631 18768.3 21838.0 185.203 30.70 39.15 493

380.000 0.09513 10.512 0.007955 31.475 19078.7 22232.2 186.254 31.23 39.68 499

390.000 0.09267 10.791 0.007747 32.319 19394.5 22631.7 187.292 31.78 40.21 505

400.000 0.09034 11. 070 0.007550 33.162 19715.6 23036.6 188.317 32.33 40.76 510

420.000 0.06600 11.628 0.007185 34.845 20374.7 23863.0 190.332 33.46 41. 87 521

*40 • 0 00 0. 08207 12. 165 0.006854 36.526 21056.5 24711.9 192.306 34.61 43.01 532

‘.60.0 00 0.07846 12. 742 0.006552 38.206 21761.2 25583.8 194.243 35.77 44.16 542

*.80.000 0.07620 13. 299 0.006276 39.883 22489.1 26478.6 196. 147 36.93 45.31 552

600.000 0.07216 13. 855 0.006022 41.559 23240.0 27396.5 198. 020 38. 08 46.45 562

H3
I

METHANE ISOBAR AT P * 4.0 BAR

T DEN VOL OP/OT OP/DD E H S CV CP H OEG K HOL/L L/HOL BAR/K BAR-L/HOL J/HOL J/HOL J/NOL/K J/MOL/K J/HOL /K M/SEC

90.786 26.155 0 .03552 20.7121 250.673 3473.0 3487.2 67.894 33.13 52.73 1577

95. 0 SO 27.803 0 .03597 19.6260 234.567 3666.0 3700.3 70.300 32.99 53.17 1535

100.000 27.381 C» .03652 18.4040 215.624 3945.6 3960.2 73.048 33.07 54.00 1482

105.000 26.950 0 .03711 17.2405 197.532 4212.7 4227.5 75.705 33.15 54.90 1428

110.000 26.508 0 .03772 16.1321 179.839 4466.0 4501.1 78.278 33.09 55.74 1374

115.000 26. 052 0 . 03636 15. 0727 162.827 4764.5 4779.9 80.773 32.85 56.49 1321

120.000 25.581 0 .03909 14.0566 146.539 5047.5 5063.1 63.193 32.50 57.22 1266

125.000 25.092 0 .03985 13.0761 130.963 5334.6 5350.6 65.544 32.10 58.03 1215

130.000 24.582 0 .04066 12.1319 116.139 5626.6 5642.8 87.839 31.75 59- 02 1160

131.403 24.434 0 . 04093 11.6714 112.098 5709.4 5725.8 88.474 31.67 59. 34 114*

131.403 0.40334 2.479 0.036256 6.903 12256.6 13266.5 145.724 26.21 38.14 284

135.000 0.38933 2.569 0.034737 9.322 12357.3 13364.7 146.746 26.04 37.57 290

140.000 0. 37172 2.690 0.032692 9.683 12494.9 13570.9 148.101 25.86 36.95 297

145.000 0.35592 2. 810 0.031266 10.424 12630.6 13754.4 149.369 25.73 36.47 30*

150.000 0.34162 2.927 0.029866 10.951 12764.9 13935.6 150.619 25.63 36.09 310

155.000 0.32858 3. 043 0.028597 11.465 12696.

2

14115.5 151.797 25.55 35.79 316

lbO.OOO 0.31663 3.158 0.027451 11.970 13030.5 14293.6 152.929 25.49 35.5*. 323

165.000 0.30561 3. 272 0.026409 12.465 13162.1 14470.9 154.020 25.44 35.33 328

170.000 0.29541 3.365 0.025455 12.954 13293.1 14647.1 155.072 25.41 35. 16 33*

175.000 0.28593 3.497 0.024576 13.436 13423.6 14622.5 156.068 25.39 35.01 340

100.000 0.27709 3.609 0.023766 13.913 13553.7 14997.3 157.073 25.38 34.69 345

105.000 0.26662 3.720 0.023013 14.365 13663.6 15171.5 158.026 25.37 34.80 351 190. 000 0. 26107 3.630 0.022311 14.652 13613.2 15345.3 158.955 25.36 34.72 35o

195.000 0.25379 3.940 0.021655 15.316 13942.6 15516.6 159.856 25.39 34.66 3o 1 200.000 0.24692 4. 050 0.021040 15.777 14072.0 15692.0 160.733 25.41 34.62 366

205.000 0.24044 4.159 0.020462 16.234 14201.3 15665.0 161.587 25.44 34. 59 371

210.000 0.23431 4.268 0.019918 16.689 14330.7 16037.6 162.420 25.46 34.57 376

215.000 0.22649 4. 376 0.019403 17.142 14460.1 16210.7 163.234 25.52 34. 56 380 220.000 0.22296 4.485 0.018917 17.592 14569.6 16383.5 164.026 25.57 34.57 365

225. 000 0.21773 4.593 0.016456 18.040 14719.3 16556.4 164.806 25.63 34.59 390

230.000 0.21274 4.701 0.018018 18.466 14649.3 16729.5 165.566 25.70 34.63 39*

235.000 0.20798 4. 806 0.017602 18.931 14979.5 16902.7 166.311 25.76 34.67 398

240.000 0.20344 4. 915 0. 017205 19.374 15110.0 17076.2 167.042 25.86 34.72 403

245.000 0. 19910 5. 023 0.016827 19.616 15240.9 17250.0 167.756 25.96 34.79 407

250.000 0.19494 5. 130 0.016466 20.256 15372.2 17424.1 168.462 26.06 34.86 411

255.000 0. 19096 5. 237 0.016121 20.695 15504.

0

17596.7 169.153 26.17 34.95 415

260.000 0.18715 5. 343 0.015790 21.133 15636.3 17773.7 169.633 26.29 35.0* 419

265.000 0.18349 5.450 0.015474 21.570 15769.2 17949.2 170.501 26.41 35.15 423

270.000 0.17997 5.556 0.015170 22.006 15902.6 16125.2 171.159 26.55 35.27 427

275.000 0. 17659 5.663 0.014879 22.441 16036.6 16301.9 171.606 26.69 35.39 431

280.000 0. 17334 5.769 0.014599 22.675 16171.6 18479.2 172.446 26.84 35.53 43*

285.000 0.17021 5. 875 0.014329 23.309 16307.1 18657.2 173.076 27.00 35.67 438

290.000 0.16719 5. 981 0.014070 23.741 16443.4 18635.9 173.698 27.17 35.82 442

295.000 0.16428 6.087 0.013820 24.173 16580.5 19015.4 174.312 27.34 35.98 445

300.000 0.16147 6. 193 0.013579 24.604 16718.5 19195.7 174.916 27.53 36.15 449

310.000 0. 15614 6. 405 0.013122 25.465 16997.2 19559.0 176.109 27.91 36.51 456

320.000 0. 15115 6.616 0.012696 26.323 17279.8 19926.1 177.274 28.32 36.90 462

330.000 0. 14646 6. 627 0.012297 27.179 17566.5 20297.2 178.416 26.76 37.32 469

340.000 0. 14209 7. 038 0.011923 28.034 17857.6 20672.6 179.537 29.22 37.76 *75

350.000 0.13797 7. 246 0.011572 28.606 18153.3 21052.5 160.636 29.70 38.22 481

360.000 0.13408 7.458 0. 011241 29.736 18453.6 21437.2 161.721 30.20 38.71 487

370.000 0.13040 7. 669 0.010928 30.588 18759.4 21826.9 162.769 30.72 39.21 493

380.000 0.12692 7. 679 0.010633 31.436 19070.

1

22221.6 163.641 31.25 39.73 499

390.000 0. 12363 8.089 0.010354 32.284 19366.1 22621.6 164.860 31.79 40.26 505

400.000 0.12051 6. 298 0.010069 33.130 19707.6 23026.9 165.906 32.34 40.80 510

420.000 0.11471 8.718 0.009596 34.621 20367.2 23654.2 187.924 33.47 -.1.91 521

440. 000 0.10945 9. 136 0.009154 36.508 21049.4 24703.9 169.900 34.62 43.05 532

460.000 0.10466 9.555 0.008749 36.192 21754.5 25576.4 191.639 35.76 *4.20 542

480.000 0.10027 9.973 0.006379 39.674 22462.6 26471.9 193.744 36.94 45. 34 552

500.000 0.09624 10.391 0.006039 41.554 23234.0 27390.2 195.616 36.09 46.48 562

144
METHANE ISOBAR ATP® 5.0 BAR

T OEN VOL DP/DT DP/DD E H S CV CP R DEG K MQL/l L/MOL BAR/K BAR-L/MOl J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

90.405 20. 157 0.03552 20.7008 250.006 3473.3 3491.1 67.899 33.14 52.72 1577

95.000 27.006 0.03596 19.6322 234.030 3684.9 3702.9 70.289 33.00 53.16 153o

100. 000 27. 3flb 0.03652 18.4092 -216.086 3944.5 3962.8 73.037 33.08 53.99 1483

105.000 26.955 0.03710 17.2466 197.810 4211.4 4230.0 75.693 33.16 54.89 1429

110.000 26.513 0. 03772 16.1391 160.132 4484.6 4503.5 78.266 33.10 55.72 1375

115.000 26.056 0.03030 15. 0806 163.134 4763.0 4782.2 80.759 32.86 56.47 1322

120.000 25.500 0.03900 14.0656 146.859 5045.7 5065.2 83.178 32.50 57.19 1269

125.000 25. 100 0.0390*. 13.0882 131.316 5332.7 5352.6 85.529 32.11 57. 99 1216

130.000 24.590 0.0.067 12.1432 116.406 5624.

5644.7 87.822 31.76 58. 98 1161

135.000 24.056 0.04157 11.2249 102.327 5921.7 5942.4 90.070 31.51 60.23 1104

135.319 24.021 0.0.163 11.1072 101.446 5940.0 5961.6 90.212 31.50 60.33 1101

135.319 0.49010 2. 007 0. 045412 8.817 12315.8 13319.4 144. 585 26.44 39.19 285

140.000 0.47549 2.103 0.042872 9.391 12449.

13500.7 145.902 26.18 38.30 293

145.000 0.45396 2.203 0.040557 9.976 12508.9 13690.3 147.233 25.98 37.58 300

150.000 0.43469 2. 301 0.030549 10.540 12726.5 13876.8 148.498 25.84 37.03 307

155.000 0.41727 2.397 0.036702 11.086 12862.5 14060.8 149.705 25.72 36.59 314

160.000 0.40142 2.491 0.035205 11.617 12997.2 14242.8 150.861 25.64 36.23 320

165.000 0.30690 2.565 0.033786 12.137 13130.9 14423.2 151.971 25.57 35.9. 326

170.000 0. 37353 2. 677 0.032498 12.647 13263.7 14602.3 153.040 25.52 35.70 332

175.000 0.36116 2.769 0.031321 13.148 13395.9 14780.3 154.072 25.49 35.53 338

100.000 0.34967 2. 060 0.030240 13.643 13527.4 14957.3 155.070 25.46 35.33 343

105.000 0.33096 2. 950 0.029241 14. 130 13658.6 15133.7 156. 036 25.45 35.19 349

190.000 0.32695 3. 040 0.028315 14.612 13789.4 15309.3 156.973 25.45 35 . oe 354

195.000 0.31956 3. 129 0.027453 15.089 13919.9 15484.5 157.883 25.45 34.99 360

200.000 0.31074 3.210 0.026647 15.562 14050.

15659.3 158. 768 25.47 34.92 36s

205.000 0. 30242 3. 307 0.025893 16.031 14180.4 15833.7 159.629 25.49 34.87 370

210.000 0.29457 3. 395 0.025184 16.496 14310.6 16008.0 160.469 25.52 34.83 375

215.000 0.20715 3.403 0.024517 16.959 14440.0 16182.0 161.288 25.56 34.81 379

220.000 0.20011 3.570 0.023886 17.418 14571.0 16356.1 162.088 25.61 34.60 384

225.000 0.27342 3.657 0.023291 17.875 14701.4 16530.1 162.871 25.67 34.80 389

230.000 0.26707 3.744 0.022726 18.329 14831.9 16704.1 163.636 25.74 34.82 393

235.000 0. 26102 3.031 0.022190 18.781 14962.7 16878.3 164.385 25.81 34.85 395

240.000 0.25524 3. 916 0.021680 19.231 15093.8 17052.7 165. 119 25.89 34.90 402

245.000 0.24974 4. 004 0.021195 19.680 15225.2 17227.3 165.839 25.99 34.95 4 0 0 250.000 0.24447 4. 090 0.02073

20.126 15357.0 17402.2 166.546 26.09 35.02 410

255.000 0. 23943 4. 177 0.020290 20.571 15489.2 17577.5 167.240 26.19 35. 10 414

260.000 0.23460 4.263 0.019868 21.015 15622.0 17753.2 167.923 26.31 35. is 41'9 2o5 . 0 00 0.22997 4. 3.0 0.019464 21.457 15755.2 17929.4 168. 594 26. 44 35. 26 4 22 270.000 0.22553 4. 434 0.019076 21.898 16889.

18106.1 169.254 26.57 35. 39 42b

275.000 0.22126 4.520 0.010704 22.338 16023.5 18283.4 169.905 26.71 35.51 430

200. 000 0.21715 4.605 0.018348 22.777 16158.7 18461.2 170.546 26.86 35.b. 434

205.000 0.21320 4. 690 0. 018U05 23.215 16294.5 18639.8 171.178 27.02 35.78 438

290.000 0.20939 4. 776 0.017675 23.651 16431.2 18819.0 171. 80

27.19 35.92 441

295.000 0.20572 4.861 0.017357 24.087 16568.6 18999.1 172.417 27.36 36. C6 443

300.000 0.20210 4. 946 0.017052 24.522 16706.9 19179.9 173. 024 27.54 36. 24 4 4 8 310.000 0.19547 5.116 0.016472 25.390 16986.

19544.1 174.219 27.93 36.60 455

320.000 0. 10919 5. 286 0.015932 26.255 17269.1 19912.0 175. 386 28.34 36.96 4 0 2 330.000 0.10332 5.455 0.015427 27.117 17556.3 20233.8 176.531 28.77 37.39 469

340.000 0.17700 5.624 0.014954 27.977 17847.8 20659.9 177.653 29.23 37.83 475

350.000 0. 17262 5.793 0.014509 28.835 18143.9 21040.5 178.757 29.71 38.29 481

360.000 0.16773 5. 962 0.014091 29.691 18444.9 21425.9 179.842 30.21 36.77 487

370. 000 0. 16312 6. 131 0.013697 30.546 18750.8 21816.1 180.911 30.73 39.27 493

300.000 0.15675 6. 299 0.013325 31.399 19061.8 22211.3 181.965 31.26 39.78 499

390.000 0.15462 6. 467 0.012973 32.250 19378.1 22611.8 183.005 31.80 40.31 5 0 3 400.000 0.15070 6. 636 0.012639 33.101 19699.9 23017.7 184. 033 32.35 40.85 510

420.000 0. 14344 6.972 0.012021 34.798 20360.0 23845.8 186. 052 33.48 41.96 521

440.000 0.13605 7.307 0.011462 36.491 21042.6 24696.2 188.030 34.63 43.09 532

460.000 0.13005 7.642 0.010953 30. 130 21748.2 25569.5 189.971 35.79 44. 23 5h2

400.000 0. 12535 7.977 0.010488 39.867 22476.9 26465.6 191.877 36.95 45.37 552

500.000 0.12031 8. 312 0.010061 41.551 23228.4 27384.5 193.753 38.09 46.51 562

t

145
METHANE ISOBAR ATP* 6.0 BAR

T DEN VOL 0P/DT OP/BO E H S CV CP OEC K MOL/L L/MOl 8AR/K 8AR-1/M0L J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K

96.831 28.159 0.03551 20.7055 250.940 3473.6 3494.9 67.903 33.14 52.71

95.000 27.812 0.03596 19.6364 235.072 3663.9 3705.5 70.279 33.00 53. 15 100.006 27.390 0.03651 18.4143 216.346 3943.4 3965.3 73.025 33.09 53.98

9 105.000 26. 960 0.03709 17.2527 198.088 4210.2 4232.4 75.681 33.17 54.88

c 110.090 26. 519 0.03771 16.1461 180.426 4483.2 4505.9 7 8 . 25 3 33.10 55.70

K 115.000 26.065 0.03837 15.0686 163.441 4761.4 4784.4 80.746 32.87 56.45

11 120.000 25.595 0.03907 14.0745 147.179 5044.

0

5067.4 83. 163 32.51 57. 17

1 125.000 25. 107 0.03983 13.0983 131.649 5330.7 5354.6 85.513 32.12 57.96

i 130.000 24.599 0.0*065 12.1544 116.833 5622.1 5646.5 87.804 31.77 58.94

1 135.000 24.066 0.04155 11.2375 192.689 5919.1 5944 .0 90.051 31.52 60- 18

1 138.696 23. 653 0. 04228 10.5737 92.628 6143.2 6168.5 91.692 31.40 61.33

1 138.696 0.59307 1.686 0.054764 8.698 12362.0 13373.6 143.640 26.65 40.26

1 140.000 0.58501 1.709 0.053835 8.870 12400.3 13425.9 14*. 015 26.56 39.92

1 145.000 0.55661 1.797 0.050596 9.507 12544.8 13622.8 145.397 26.26 38.88

; 150.600 0. 53153 1. 881 0. 047653 10.112 12686.

3

13815.1 146.701 26.07 38.09

155.000 0.50911 1. 964 0.045477 10.693 12825.5 140Q4.0 147.940 25.92 37.49

160.000 0.43886 2. 046 0 • 043386 11.254 12962.9 14190.2 149.122 25.60 37.00

165.000 0.47045 2. 126 0.041526 11.600 13098.8 14374.2 150.254 25.71 36.61

170.000 0.45359 2. 205 0.039654 12.333 13233.6 14556.4 151.342 25.64 36.29

175.000 0.43807 2. 283 0.038337 12.855 13367.5 14737.1 152.390 25.59 36.02

180.000 0.42372 2. 360 0.036952 13.368 13500.6 14916.6 153.402 25.56 35.80

185.000 0. 41039 2.437 0.035679 13.872 13633.1 15095.2 154.380 25.53 35.61

190.000 0.39796 2.513 0.034505 14.369 13765.1 15272.8 155.326 25.52 3 5.46

195.000 0.38634 2.588 0.033417 14.860 13896.8 15449.8 156.247 25.52 35.34

200.000 0.37545 2.663 0.032404 15.346 14028.

1

15626.2 157. 141 25.53 35.24

205.000 0.36520 2.738 0.031458 15.826 14159.3 15802.2 158.010 25.55 35.16

210.000 0.35555 2. 813 0.030573 16.302 14290.3 15977.8 158. 856 25.57 35.10

215.000 0.34643 2. 887 0.029741 16.775 14421.3 16153.2 159.681 25.61 35.06

220.000 0.33781 2. 960 0.028957 17.243 14552.3 16328.4 160.487 25.66 35.03

225.000 0.32963 3. 034 0.028218 17.709 14683.3 16503.6 161.274 25.71 35. 02 230.000 0. 32186 3.107 0.027519 18.171 14814.5 16678.7 162.044 25.77 35. 03 235.000 0.31447 3. 180 0.026856 18.631 14945.9 16653.8 162.797 25.84 35.0*

240.000 0. 30744 3.253 0. 026227 19.088 15077.5 17029.1 163.536 25.93 35.08

245.000 0. 30073 3. 325 0.025629 19.544 15209.4 17204.6 164.259 26.02 35. 12 250.000 0.29432 3. 398 0.025060 19.997 15341.7 17380.3 164.969 26.11 35.18

255.000 0.28819 3.470 0.024517 20.448 15474.4 17556.4 165.667 26.22 35.25

260.000 0.28232 3.542 0.023996 20.697 15607.6 17732.8 166.352 26.34 35.33

265.000 0. 27670 3. 614 0.023503 21.345 15741.2 17909.7 167.025 26.46 35.42

270.000 0.27130 3.686 0.023028 21.791 15875.5 18087.0 167.688 26.59 35.52

275.000 0.26613 3.758 0.022573 22.236 16010.3 18264.9 168. 341 26.73 35.63

280.000 0. 26115 3.829 0.022137 22.679 16145.8 18443.4 168.984 26.88 35.76

285.000 0.25636 3.901 0.021716 23.121 16262.0 18622.5 169.618 27.04 35.69

290.000 0.25175 3.972 0.021316 23.562 16419.0 18802.3 170.244 27.21 36.03

295.000 0.24731 4. 043 0.020928 24.002 16556.7 18962.8 170.861 27.36 36.18

300.000 0. 24303 4. 115 0.020555 24.441 16695.3 19164.1 171.470 27.56 36.3*

310.000 0.23491 4.257 0.019850 25.316 16975.0 19529.2 172.668 27.94 36.69

320.000 0.22733 4.399 0.019192 26.188 17258.6 19898.0 173.838 28.35 37.06

330.000 0.22023 4.541 0.018579 27.056 17546.2 20270.6 174. 985 28.79 37.47

340.000 0.21358 4.682 0.018004 27.922 17838.2 20647.4 176. 110 29.25 37.90

350.000 0.20733 4. 823 0.017465 28.785 18134.7 21028.7 177.215 29.73 38.36

360.000 0.20143 4. 964 0.016958 29.646 18436.0 21*14.6 178.302 30.23 38.83

370.000 0. 19588 5. 105 0.016461 30.505 18742.3 21805.4 179.373 30.74 39.33

380.000 0.19062 5.246 0.016030 31.362 19053.

7

22201.3 180.428 31.27 39.84

390.000 0.18565 5. 387 0.015604 32.218 19370.3 22602.3 161.470 31.81 *0.36

400.006 0.18093 5.527 0.015200 33.072 19692.3 23008.6 182.498 32.36 *0.90

420.000 0.17219 5. 806 0.014453 34.775 20353.0 23637.6 184.520 33.49 42.00

440.000 0.16426 6. 086 0.013778 36.474 21036.1 24688.6 186.500 34.64 *3.13

460.000 0.15704 6. 368 0.013164 38.169 21742.1 25562.8 168.442 35.80 *4.26

480.000 0.15044 6.647 0.012602 39.860 22471.2 26459.5 190. 350 36.95 45. 4 j 500.000 0. 14437 6.926 0.012088 41.548 23223.1 27379.0 192.227 38.10 46.54

w M/SEC

15 77 1536

1483

1429

1376

1323

1270

1217

1162

1106

1062

286

288

296

303

310

317

324

330

336

342

347

353

35S

363

368

373

378

383

388

392

397

401

406

410

* 1 * 418

422

426

430

434

437

4*1

446

448

*56

462

469

475

481

*87

493

499

505

510

521

532

542

553

562

t 46
methane isobar at p » r.u bar

T OEN VOL DP/DT OP/DO E H S C V CP M OEG K HOL/L L/MOl BAR/K BAR-L/MOL 3/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

9J.857 28.161 0.03551 20.7022 251.073 3473.9 3498.8 67.907 33.15 52.71 1577

93.000 27. 816 0. 03595 19.6406 235.315 3682.9 3708.1 70. 268 33.01 53.14 1537

100.000 27.395 0.03650 18.4194 216.609 3942.2 3967.8 73. 014 33.10 53.97 148*

105.000 26.965 0.03708 17.2588 198.366 4208.9 4234.9 75.669 33.18 54.86 1430

110.000 26.524 0.03770 16.1531 180.718 4481.

4508.2 78.240 33.11 55.69 1376

115.000 26. 071 0. 03836 15.0966 163.747 4759.9 4786.7 80.732 32.88 56.43 1324

120.000 25.602 0.03906 14.0835 147.498 5042.2 5069.6 63.149 32.52 57.1* 1271

125.000 25. 115 0.03982 13.1083 131.981 5328.7 5356.6 85.497 32.13 57.93 1213

130.000 24.607 0 • 0406-4 12.1656 117.179 5619.9 56*8.3 87.787 31.78 58. 90 1163

135.000 24. 075 0. 04154 11.2501 103.049 5916.6 5945.6 90.032 31.53 60.13 1107

140.000 23.514 0.04253 10. 3561 69.533 6220.3 6250.1 92.246 31.38 61.72 1048

IhI.685 23. 317 0.0*289 10.0585 85.102 6324.

6354.6 92.989 31.35 62. 34 1027

1 <41. 685 0.68836 1.453 0.064398 8.557 12398.9 13415.8 142. 825 26*86 *1. 35 287

145.000 0.66461 1.505 0.061546 9.013 12498.0 13551.3 143.770 26.61 40.41 292

150.000 0.63266 1.581 0.057869 9.666 12644.

13750.4 145. 121 26.33 39.32 3 0 u 155.000 0.60 *444 1.654 0.054749 10.286 12786.8 13944.9 146.396 26.13 38.49 307

160.000 0.57922 1. 726 0.052046 10.680 12927.2 14135.7 147. 608 25.98 37.85 314

165.000 0.55645 1. 797 0.049668 11.455 13065.6 14323.6 148.764 25. 86 37.34 321

170.000 0.53574 1. 867 0.047550 12.012 13202.6 14509.2 149.873 25.77 36.92 328

175.000 0.51678 1.935 0.045645 12.556 13338.4 14692.9 150.936 25.70 36.58 33*

180.000 0.49932 2. 003 0.043917 13.088 13473.2 14875.1 151.964 25.65 36.29 340

185.000 0.48316 2. 070 0.042340 13.609 13607.2 15056.0 152.955 25.62 36.06 346

190.000 C . 4 6 8 12.136 0.040892 14.122 13740.5 15235.7 153.914 25.60 35.86 351

195.000 0.45*17 2.202 0.039556 14.628 13873.4 15414.6 15*. 8*3 25.59 35.70 357

200.000 0.44108 2. 267 0.038317 15.126 14005.8 15592.8 155.746 25.59 35.57 362

205.000 0. 42881 2. 332 0.037164 15.619 14137.9 15770.3 156.623 25.60 35.46 367

210.000 0.41726 2. 397 0.036088 16.106 14269.8 15947.4 157.476 25.63 35.38 372

215.000 0.40638 2. 461 0.035079 16.589 14401.6 16124.2 158. 308 25.66 35.31 377

220. 000 0. 39610 2. 525 0. 03*132 17.067 14533.4 16300.6 159. 119 25.70 35.27 382

225.000 0. 38637 2.588 0. 033240 17.542 14665.1 16476.9 159.911 25.75 35.24 387

230.000 0.37713 2. 652 0.032398 18.012 14797.0 16653.1 160.686 25.81 35.23 391

235.000 0.36837 2.715 0.031602 18.480 14928.9 16829.2 161.444 25.88 35.24 39o

240.300 0.36002 2. 77a 0 . 030848 18.945 15061.1 17005.5 162.186 25.96 35.26 400

245.000 0. 35207 2. 840 0. 030131 19.407 15193.6 17181.8 162.913 26.05 35.29 405

250.000 0.34449 2. 903 0.029450 19.867 15326.4 17358.4 163.626 26.14 35.34 *09

255 .000 0.33724 2. 965 0.028802 20.324 15459.6 17535.2 164.327 26.25 35.40 *13

260 .000 0. 33031 3. 027 0.028183 20.779 15593.2 17712.4 165 .015 26.36 35.47 41 7 265.000 0. 32367 3. 090 0.027592 21.232 15727.3 17890.0 165.691 26. *8 35.55 422

270. 000 0. 31731 3. 152 0.027027 21.684 15861.9 18068.0 166. 357 26.o2 35.65 425

275.000 0.31120 3.213 0.026486 22.134 15997.1 18246.5 167.012 26.76 35.76 42*

280.000 0.30534 3. 275 0.025967 22.582 16133.0 18425.5 167.657 26.90 35.87 433

285.000 0. 29970 3. 337 0.025470 23.028 16269.5 18605.2 168.293 27.06 36.00 437

290.000 0.294 27 3. 398 0.024992 23.474 16406.8 18785.5 168.920 27.23 36.1* 4*1

295.000 0.28905 3. 460 0.024533 23.918 16544.8 1896 6.6 169.539 27. *0 36.28 4*4

300.000 0.28401 3.521 0.024091 24.361 16683.7 191*8.4 170. 150 27.58 36.44 448

310.000 0.27447 3.643 0.023265 25.243 16964.0 19514.4 171.351 27.96 36.78 455

320. 000 0.26556 3. 766 0. 022478 26.121 17248.1 19884.0 172.524 26.37 37.15 462

330.000 0.25724 3. 887 0.021753 26.996 17536.2 20257.5 173.673 28.80 37.55 468

3*40.000 0.24943 4. 009 0.021075 27.867 17828.6 20635.

174.800 29.26 37.97 4 75 350.000 0.24210 4. 131 0.020439 28.736 18125.6 21017.0 175.907 29.74 38.42 481

360 . 000 0.23519 4. 252 0.019642 29.602 18427.2 21403.5 176.996 30.24 36.89 487

370.000 0.22868 4. 373 0.019279 30.465 18733.8 21794.9 178.069 30.75 39.38 493

380.000 0. 22252 4. 494 0.018749 31.327 19045.6 22191.3 179. 126 31.28 39.89 499

390.000 0. 21670 4.615 0.018247 32.186 19362.5 2?592.8 180.169 31.82 *0.41 505

400.000 0.21118 4. 735 0.017772 33.044 19684.9 22999.6 181. 196 32.37 *0.95 510

420.000 0.20095 4.976 0.016895 34.754 20346.

23829.5 183.223 33.50 42.04 521

4*0.000 0.19168 5. 217 0.016102 36. *59 21029.7 24681.5 185.204 34.65 *3.16 532

*60.000 0.18325 5. 457 0.015381 38.159 21736.2 25556.2 187.148 35.81 *4.30 5*2

480.000 0. 17553 5. 697 0.014723 39.854 22465.6 26453.5 189. 057 36.96 45.44 553

500.000 0.16844 5. 937 0.014119 41.547 23217.9 27373.6 190.935 38.11 *6.57 563

147
23

333

33

34

4

4<4141S<

NE THAME ISOBAR ATP® 8.0 BAR

T OfM WOL DP/DT QP/OO E H S CV CP M 0E6 K MOL/L L/NOL ® AR/K BAR-L/MOL J/HOl J/MOL J/MOL/K J/MOl/K J/MOL/K M/SEC

§0.a®2 26. 163 0. 03551 20.6990 251.206 3474.2 3502.6 67.911 33.16 52.70 1578

95.000 27.629 0.03396 19.6447 iS5«S§7 3661.9 3710.6 70.257 33.02 53.13 1537

100.000 27.400 0.03650 18.4246 216.870 3941.1 3970.3 73.003 33.11 53.96 146h

105.000 26.970 0. 0370® 17.264® 198.644 4207.7 4237.3 75.657 33.19 54.05 1431

110.090 26.530 0.03769 16.1600 181.011 6480.5 4510.6 78.226 33.12 55.67 1377

115.009 26.077 0.03835 15.1045 164.053 4758.3 4789.0 80.719 32.89 56.41 1324

120.009 25.608 0 ® 03905 14.0924 147.817 5040.5 5071.7 03. 134 32.53 57.12 1272

125.000 25.122 0. 03981 13.1183 132.313 5326.8 5358.6 85.481 32.14 57.90 1219

130.000 26.616 0.04062 12.1768 117.524 5617.6 5650.1 87. *70 31.79 58.86 1165

135.000 26.085 0.04152 11.2626 103.409 5914.0 5947.3 90.013 31.54 60.08 1108

140.000 23.525 9.04251 10.3701 89.910 6217.4 6251.4 92.226 31.39 61.65 1049

144. 379 23. 005 0.04347 9.6015 78.535 6490.2 6525.0 94.150 31.33 63.35 995

144. 379 0.78630 1.275 0.074277 8.399 12428.8 13448.8 142.105 27.06 42.48 287

145.000 0. 77387 1.284 0.073596 8.491 12448.0 13475.1 142.266 27.00 <2.25 288

150.000 0. 73867 1. 354 0. 066714 9.200 12599.3 13682.3 143.692 26.63 40.74 296

155.000 0. 70370 1.421 0.064673 9.864 12746.

3

13883.2 145.009 26.36 39.64 30*

160.000 0.67279 1.686 0.061232 10.494 12890.1 14079.2 146.254 26.17 38.80 311

165.000 0.66513 1.550 0.058245 11.099 13031.4 14271.4 147.437 26.02 38. 14 318

170. 000 0.62015 1.613 0.055613 11.683 13170.7 14460.8 148.567 25.91 37.61 325

175. 000 0. 59741 1.674 0.053266 12.250 13306.6 14647.7 149.651 25.82 37.18 332

180.000 0.57657 1.734 0.051153 12.802 13445.1 14832.6 150.693 25.76 36.82 338

185.000 0.55737 1.794 0.049236 13.342 13580.7 15016.0 151.698 25.71 36.53 344

190. 000 0. 53960 1.853 0.047486 13.872 13715.4 15198.0 152.669 25.66 36.28 350

195.000 0.52309 1.912 0.045877 14.392 13049.5 15378.9 153.609 25.66 36.08 355

200.000 0.50760 1.970 0.044392 14.904 13963.1 15558.9 154.520 25.65 35.91 361

205.098 0.49327 2.027 0.043015 15.409 14116.3 15738.1 155.405 25.66 35.78 366

210.000 0.47974 2.084 0.061733 15.908 14249.1 15916.7 156.266 25.68 35.67 371

215.000 0.46700 2. 141 0.060536 16.401 14381.8 16094.8 157.104 25.70 35.58 376

220.000 0.45500 2. 196 0.039414 16.890 14514.3 16272.5 157.921 25.74 35.52 381

225.000 0.44365 2. 254 0.038360 17.373 14646.8 16450.0 158.719 2 5.79 35.47 386

230.000 0.43290 2.310 0.037367 17.853 14779.3 16627.3 159.498 25.85 35.45 391

235.000 0.42270 2. 366 0.036630 18.328 14911.9 16804.5 160.260 25.91 35.44 395

240.000 0.41301 2. 421 0.035543 16.801 15044.7 16961.7 161.007 25.99 35.44 400

245. 000 0. 40378 2.477 0.036703 19.270 15177.7 17156.9 161.736 26.06 35.47 404

250.000 0.39499 2.532 0.033904 19.736 15311.0 17336.4 162.455 26.17 35.50 409

255.000 0.38659 2.587 0.033145 20.200 15444.6 17514.0 163.156 26.27 35.55 413

260.000 0.37857 2.642 0.032422 20.661 15578.7 17691.9 163.849 26.39 35.62 417

265.000 0.37089 2.69o 0.031732 21.120 15713.2 17870.2 164.526 26.51 35.69 421

270.000 0. 36354 2.751 0.031073 21.576 15648.3 16046.9 165.196 26.64 35.78 425

275.000 0.35649 2. 805 0.030442 22.031 15963.9 18228.0 165.854 26.76 35.88 429

280.000 0.34972 2. 859 0.029839 22.484 16120.1 16407.7 166.501 26.93 35-99 433

285.000 0.34321 2.914 0.029260 22.935 16257.0 18587.9 167.139 27.00 36.11 437

290.000 0.33695 2. 968 0.028704 23.385 16394.6 18766.8 167.768 27.25 36. 24 440

295.000 0.33093 3.022 0.028171 23.833 16533.0 18950.4 168. 389 27.42 36. 39 44*

300.000 0. 32513 3. 076 0.027658 24.280 16672.1 19132.7 169.002 27.60 36.54 448

310.000 0.31414 3.183 0.026669 25.170 16953.0 19499.7 170.205 27.96 36.87 455

320.000 0.30389 3.291 0.025789 26.055 17237.6 19870.1 171.361 26.38 37.23 462

330.000 0. 29432 3. 398 0. 026950 26.936 17526.2 20244.6 172.533 28.62 37.62 468

360.000 0.28535 3.584 0.024165 27.813 17619.1 20622.7 173.662 29.28 38. 04 475

350.000 0.27692 3.611 0.023431 28.687 18116.4 21005.3 174.771 29.75 38.49 481

360.009 0.26900 3. 718 0. 022741 29.558 18418.5 21392.5 175.862 30.25 38.96 *87

370.000 0.26152 3.624 0.022092 30.426 18725.5 21764.5 176.936 30.76 39.44 493

380.000 0.25466 3. 930 0.021480 31.292 19037.5 22181.4 177.995 31.29 39.95 499

390.000 0.24778 4.036 0.020902 32.155 19354.8 22563.4 179. 039 31.83 40.46 505

400.000 0.24145 4. 142 0.020356 33.016 19677.4 22990.7 180.070 32.36 40.99 510

420.000 0.22973 4.353 0.019346 34.733 20339.2 23821.5 182.096 33.51 42.09 521

440.000 0.21912 4.564 0.018433 36.444 21023.3 24674.3 10H.OSS 34.66 43.20 532

460.000 0.20966 4. 774 0. 017606 38.149 21730.2 25549.6 186.025 35.61 44.33 543

480.000 0.20062 4.985 0.016848 39.849 22460.0 26447.7 187.936 36.97 45.47 553

500.000 0.19251 5.194 0.016156 41.545 23212.7 27368.3 169.815 38.12 46.59 563

148
METHANE ISOBAR AT P « 9.0 BAR

T DEN VOL DP/OT QP/OD E H S CV CP w OEG K HOL/L L/MOL BAR/K 8AR-L/N0L J/MOL J/MQL J/HOL/K J/MOL/K J/MOL/K M/SEC

90.908 28.169 0.03991 20.6997 291.339 3474.9 3506.5 67.915 33.16 52.69 1578

99.000 27.629 0.03994 19.6469 239.798 3660.8 3713.2 70.246 33.03 53.12 1537

100.000 27.404 0.03649 18.4297 217.131 3940.0 3972.8 72.991 33.12 53. 94 1465

109.000 26.979 0.03707 17.2706 196.921 4206.4 4239.8 75.645 33.20 54.83 1431

110.000 26.939 0.03769 16.1670 161.303 4479.4913.0 78.215 33.13 55.65 1378

119.000 26.063 0.03834 19.1124 164.399 4796.8 4791.3 80.705 32.90 56.38 1325

120.000 29.619 0. 03904 14. 1013 146.136 9038.7 9073.9 83.120 32.54 57.09 1273

129.000 29. 130 0.03979 13.1263 132.644 9324.6 9360.6 85.466 32.15 57.87 1220

130.000 24.624 0.04061 12.1679 117.868 9619.4 5652.0 87.753 31.80 58.82 1166

139.000 24.099 0.04190 11.2791 103.769 9911.9 5948.9 89.995 31.55 60.03 1109

140.000 23.936 0.04249 10. 3841 90.286 6214.9 6252.8 92.205 31.40 61.59 1051

149.000 22.942 0.04 399 9.9090 77.348 6926.2 6565.4 94. 3-99 31.33 63.53 989

146.839 22.713 0 . 04403 9.1898 72.710 6643.3 6683.0 95.204 31.31 64.37 9b5

146.639 0.86112 1. 139 0.084441 8.230 12492.9 13474.3 141.455 27.26 43.64 267

190.000 0.89034 1. 176 0.080940 8.711 12991.9 13610.3 142.371 26.97 42.41 292

199.000 0.80739 1.239 0.079344 9.429 12703.8 13616.5 143.736 26.62 4 0.94 3Q1

1&0. 000 0. 76992 1.299 0.071010 10.097 12891.4 14020.4 145.018 26.38 39.66 308

169.000 0.73673 1.397 0.067304 10.739 12999.9 14217.5 146. 231 26.19 39.02 3 lo 170.000 0.70699 1.414 0.064076 11.347 13137.9 14410.9 147.386 26.05 38.36 323

179.000 0.68009 1.470 0.061229 11.936 13277.9 14601.3 148.490 25.94 37.82 329

160.000 0.69998 1.929 0.096676 12.912 13416.4 14789.3 149.549 25.86 37.39 336

169.000 0.63309 1.960 0.096362 13.071 13993.7 14975.3 150.566 25.80 37.03 342

190.000 0.61236 1.633 0.094297 13.618 13689.9 15159.6 151.552 25.76 36.73 348

199.000 0. 99319 1. 686 0.092390 14.193 13829.3 15342.6 152.502 25.73 36.48 354

200.000 0.97929 1.738 0.090637 14.680 13960.1 15524.5 153.423 25.72 36.27 359

209.000 0.99661 1.790 0.049017 19.198 14094.3 15705.4 154.317 25.72 36.11 365

210.000 0.94299 1. 842 0.047914 19.706 14228.1 15685.6 155.185 25.73 35. 97 370

219.000 0.92633 1.893 0.046119 16.212 14361.6 16065.1 156. 030 25.75 35.86 375

220.000 0.91492 1.944 0.044806 16.711 14499.0 16244.2 156.854 25.79 35. 77 380

229.000 0.90149 1.994 0.043960 17*204 14626.2 16422.9 157.657 25.63 35.71 385

230. 000 0. 46917 2.044 0.042427 17.692 14761.9 16601.3 158.441 25.89 35.67 390

239.000 0.47749 2. 094 0.041341 16.176 14694.7 16779.6 159.208 25.95 35.64 394

240.000 0.46641 2. 144 0.040319 18.699 19028.1 16957.8 159.958 26.02 35.64 399

249.000 0.49966 2. 194 0.039344 19.132 19161.7 17135.9 160.693 26.11 35.65 404

290.000 0.44963 2.243 0.038423 19.609 19299.9 17314.2 161.413 26.20 35.67 408

299.000 0.43629 2.292 0.037949 20.079 19429.7 17492.7 162. 120 26.30 35.71 412

260.000 0.42711 2.341 0.036716 20.942 19964.2 17671.4 162.814 26.41 35. 77 416

269.000 0.41837 2. 390 0.039923 21.006 19699.1 17850.3 163.496 26.53 35.83 421

270.000 0.41000 2.439 0.039167 21.469 19634.6 18029.7 164. 166 26.66 35.91 425

279.000 0.40196 2. 486 0.034443 21.929 19970.6 18209.5 164.626 26.60 36.01 429

260.000 0. 39429 2. 936 0. 033792 22.386 16107.2 18389.8 165.476 26.95 36.11 432

289.000 0.38690 2.989 0.033089 22.842 16244.4 18570.6 166.116 27.10 36.23 436

290.000 0.37980 2.633 0.032493 23.296 16382.4 18752.1 166 .747 27.26 36.35 440

299.000 0. 37296 2.681 0.031643 23.749 16921.1 18934.2 167.370 27.44 36.49 444

300.000 0* 36 63 6 2. 729 0.031297 24.200 16660.9 19117.0 167.984 27.61 36.64 44 7 310. J00 0.39393 2. 829 0.030191 29.097 16942.0 19484.9 169. 191 27.99 36.96 45 . 320.000 0.34232 2.921 0.029124 29.989 17227.1 19856.2 170.370 28.40 37.31 461

330.000 0.33149 3.017 0.026169 26.676 17916.2 20231.3 171.524 28. 83 37.70 468

340. 000 0. 32134 3.112 0.027276 27.^99 17809.5 20610.3 172.655 29.29 38.11 475

390.000 0.31161 3.207 0.026441 28.638 18107.

20993.6 173.766 29.77 38.55 481

3a0.000 0. 30289 3.302 0.029697 . 29.914 18409.7 21381.5 174. 859 30.26 39.02 487

370.000 0.29h41 3.397 0 . 02*920 30.387 18717.1 21774.0 175.934 30.76 39.50 493

360.000 0.26644 3.491 0.024226 31.297 19029.5 22171.5 176.994 31.30 40.00 499

390.000 0.27890 3.986 0.023970 32.124 19347.1 22574.1 178.040 31.84 40.51 505

400.000 0.27179 3. 680 0.022990 32.989 19670.0 22961.9 179.072 32.39 41.04 510

420.000 0.29893 3. 868 0.021609 34.713 20332.

23813.5 181. 101 33.52 42.13 521

440.000 0.24696 4.096 0.020772 36.429 21017.0 24667.1 163.086 34.67 43. 24 532

460.000 0.23967 4. 243 0.019839 38.139 21724.3 25543.2 185.033 35.82 44.37 543

480.000 0.22972 4 * 430 0.018980 39.844 22454.6 26441.6 186.945 36.98 45.50 553

900.000 0.21698 4.617 0.016197 41.944 23207.6 27363.1 188.825 38.13 46.62 5o3

149
METMAWE ISOBAR ft? P a 10.0 BAR

T DEN VOL DP/OT DP/DD E H S CV CP M DEG K M0L/L L/MOL BAR/K 0AR-L/HQL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

90.933 26.167 0.03550 20.6929 251.971 3979.9 3510.9 67.919 33.17 52.69 1578

99.000 27.629 0.03593 19.6530 236.939 3679.6 3715.6 70.236 33.99 53. 11 1538

100.300 27.909 0. 03696 18.9398 217.391 3936.9 3975.3 72.960 33.12 53.93 1965

109.003 26.960 0.03706 17.2769 199.196 9205.2 9292.3 75.633 33.26 59.62 1932

110.000 26.591 0.03766 16.1739 161.599 9977.7 9515.9 76.202 33.19 55.63 1379

119.000 26.069 0.03633 15.1203 169.669 9755.2 9793.5 80.692 32.91 56.36 1326

120.060 25.622 0.03903 19.1102 196.959 5037.0 5076.0 63.105 32.55 57.06 1279

129.000 25. 136 0.03978 13.1362 132.975 5322.9 5362.7 85.950 32.16 57.83 1221 130.000 29. 633 0. 09060 12. 1990 116.212 5613.2 5653.8 67.736 31.61 56.78 1167

139.000 29.109 0.09199 11.2875 109.127 5909.0 5950.5 69.976 31. SB 59.98 1111 190.000 23.597 0.09297 10.3961 90.662 6211.6 6259.1 92.189 31.91 61.52 1052

199.000 22.955 0.09356 9.5296 77.793 6522.9 6566.9 99.375 31.39 63.95 991

1<49. 100 22.939 0. 09957 8.6192 67.979 6706.3 6630.9 96.179 31.26 65.36 93d

199.100 0.9769o 1. 021 0.099906 6.052 12972.9 13993.9 190.659 27.95 99.86 266

190.000 0.96663 1. 032 0.093595 8.198 12501.3 13533.6 191.125 27.35 •»9.92 268

199.000 0.91612 1. 092 0.066862 8.970 12659.0 13750.6 192.596 26.91 92.95 297 160.000 0.67102 1. 198 0.061957 9.686 12611.1 13959.1 193.672 26.60 91.05 305 169.000 0.63199 1.203 0.076896 10.361 12959.1 19161.6 195.119 26.37 39.99 313 170.006 0.79696 1.256 0.072975 11.003 13109.

0

19359.5 196.300 26.20 39.17 320 179.000 0.76999 1. 307 0.069596 11.621 13296.9 19553.7 197.926 26.07 36.52 327 160.000 0.73699 1. 358 0.066511 12.217 13367.0 19799.9 196.503 25.97 37.99 334

169.000 0.71091 1. 908 0.063793 12.796 13526.1 19933.7 199.536 25.90 37.56 3h0 190.000 0.66699 1.957 0.061336 13. 361 13663.9 15120.6 150.535 25.09 37.20 396 199.000 0.66991 1.505 0.059109 13.912 13600.7 15305.6 151.997 25.01 36.90 352 200.000 0.69399 1.553 0.057059 19.953 13936.7 15969.6 152.928 25.79 36.65 356 209.000 0.62966 1.600 0.055177 19.989 19072.0 15672.9 153.330 25.70 36.95 363 210.000 0. 60707 1. 697 0. 053936 15.507 19206.9 15659.1 159.206 25.79 36.26 369 219.000 0.99037 1.699 0.051619 16.022 19391.3 16035.2 155.056 25.00 36.19 3/4

220.000 0.97969 1.790 0.050312 16.530 19975.5 16215.6 155.688 25.63 36.03 379

223.000 0.99991 1.786 0.098903 17.033 19609.

5

16395.5 156.697 25.67 35.95 364

230. 000 0.99999 1.832 0.097561 17.530 19793.5 16575.1 157.966 25.92 35.89 389 239.000 0.93279 1.877 0.096337 18.022 19877.9 16759.5 156.256 25.96 35.85 399 290.000 0.52022 1.922 0.095165 18.510 15011.9 16933.7 159.012 26.06 35.63 398 299.000 0.50632 1. 967 0.099057 18.993 15195.5 17112.6 159.751 26.19 35.63 903 290.000 0.99701 2. 012 0.093008 19.973 15279.9 17292.0 160.975 26.23 35.64 907 299.000 0.96622 2.057 0.092013 19.999 15919.6 17971.3 161.105 26.33 35.67 912

260.000 0.97593 2. 101 0.091067 20.923 15599.6 17650.7 161.882 26.99 35.92 916 269.000 0. 96610 2. 195 0.090167 20.893 15685.

0

17830.9 162.566 26.56 35.96 920 270.000 0.95670 2. 190 0.039309 21.361 15620.9 16010.5 163.290 26.69 36.05 929 279.000 0.99769 2.239 0.038990 21.826 15957.3 18191.0 163.902 26.82 36.19 928 260.000 0.93906 2.278 0.037707 22.288 16099.3 18371.9 169.559 26.97 36.23 932

269.000 0. 93077 2. 321 0.036957 22.799 16231.9 16553.3 165.196 27.12 36.39 936 290.000 0.92260 2. 365 0.036239 23.208 16370.1 18735.3 165.029 27.28 36.96 490 299.000 0.91515 2.909 0.035550 23.669 16509.2 18917.9 166.959 27.95 36.60 993 300.000 0.90777 2.952 0.039669 29.119 16696.

9

19101.3 167. 070 27.63 36. 79 997 310.000 0.39363 2.539 0.033692 25.029 16931.0 19970.2 168.279 26.01 37.05 959

320.000 0.36065 2. 626 0.032965 25.923 17216.7 19892.9 169.961 26.92 37.90 961 330.000 0. 36879 2. 712 0. 031910 26.816 17506.2 20216.2 170.616 2 6.85 37.78 968 390.000 0.35790 2.798 0.030907 27.705 17800.0 20598.0 171.751 29.30 30. 19 979 390.000 0.39676 2. 889 0.029969 28*590 16090.2 20982.0 172.669 29.76 38.62 981 360.000 0.33676 2.969 0.026569 29.970 16901.0 21370.5 173.959 30.26 39. 08 987 370.000 0.32739 3.055 0.027763 30.398 16708.7 21763.6 175.036 30.79 39.56 993 360.000 0. 31695 3. 190 0.026969 31.222 19021.5 22161.7 176.096 31.32 90.05 999

390.000 0.31009 3. 225 0.026250 32.093 19339.9 22569.8 177.195 31.65 90.57 505 900.000 0.30208 3.310 0.025655 32.962 19662.6 22973.0 176. 176 32.91 91. 09 510 920.000 0.26735 3.980 0.029275 39.692 20325.5 23605.6 160.209 33.53 92. 17 522 990.000 0. 27902 3.699 0.023119 36.915 21010.6 29660.0 162.196 39.66 93.26 532 960.000 0.26190 3.618 0.022072 38.130 21718.5 25536.6 169.195 35.83 49.90 593 960.000 0.25082 3. 967 0. 021117 39.690 22999.1 26936.1 166. 050 36.99 45.53 553

500.000 0.29065 9.155 0.020293 91.599 23202.5 27357.9 107.990 36.13 46.65 563

110
METHANE ISOBAR AT P * 12.0 BAR

T OEM VOL DP/DT OP/ 00 E H S CV CP H OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K 1/SEC

90 • 90S 26.121 0.03550 20.6859 251.736 3475.5 3518.1 67.928 33. 19 52.67 1578

95.000 22.632 0.03592 19.6613 236.521 3677.8 3720.9 7 0.214 33.06 53.09 1539

100.000 22.416 0.03647 18.4449 217.911 3936.6 3980.4 72.957 33.14 53.91 14 8 b 109.000 26.990 0.03705 17.2889 199.751 4202.7 42 * 7.2 75.609 33.22 54.79 1433

110.000 26.552 0. 03766 16. 1878 182.176 4474.9 4520.1 78.177 33. 16 55.60 1380

11 S.OOO 26. 101 0.03831 15. 1360 165.273 4752.

4798.1 80.665 32.92 56.32 1 328

120.000 25.635 0.03901 14.1279 149.088 5033.6 5080.4 83. 076 32.57 57.01 1275

125.000 25.153 0.03976 13.1580 133.635 5319.0 5366.7 85.419 32.17 57. 77 1223

130.000 24.650 0 . 0*057 12. 2211 118.899 5608.9 5657.5 87.702 31.82 58.70 1169

135.000 24.123 0 . 0*145 11.3122 104.842 5904.0 5953.8 89.939 31.57 59.69 1113

140.000 23.569 0 . 0*243 10.4258 91.410 6205.9 6256.8 92.143 31.43 61.40 10 55 145.000 22.960 0 . 0*352 9.5562 78.530 6516.1 656 8.4 9*. 329 31.35 63.28 99*

150.000 22.349 0 . 0*475 8.6961 66.123 6836.7 6890.4 96.512 31.27 65.62 930

153. 198 21.916 0 . 0*563 8.1468 58.393 7048.4 7103.1 97.915 31.18 67.43 887

153.196 1. 12636 0.849 0.116626 7.678 12499.9 13518.3 139.790 27.84 * 7.45 2 8 o 155.000 1.15192 0 . 869 0. 113207 7.997 12561.

13602.140. 338 27.61 * 6.33 289

160.000 1. 06219 0 . 920 0.104745 8.822 12724.3 13828.1 141.769 27.13 43.96 299

165.000 1. 03215 0 . 969 0.097934 9.582 12880.9 14043.5 143.095 26.79 42.29 307

120.000 0.96433 1 . 016 0. 092256 10.293 13032.6 14251.7 144. 338 26 . 54 * 1.05 315

125.000 0.94209 1.061 0.067406 10.968 13180.7 14454.4 145.514 26.35 * 0 . 09 322

160.000 0.90432 1 . 106 0.083192 11.613 13326.0 14652.9 1 * 6.632 26.21 39.33 330 165.000 0. 62022 1 . 149 0. 079475 12.235 13469.

14848.0 147.701 26.10 38.71 33 b 190.000 0.63919 1 . 192 0.076159 12.837 13610.3 15040.2 148.726 26 , 02 38.21 343

195.000 0.61076 1.233 0.073174 13.422 13750.1 15230.2 149.713 25.96 37.80 349

200.000 0.26456 1.275 0.070466 13.993 13888.8 15418.4 150.666 25.93 37.46 355

205.000 0.76031 1 . 315 0. 067992 14.551 14026.6 15604.9 151.587 25.90 37.17 361

210.000 0.73776 1 . 355 0.065720 15.099 14163.6 15790.1 152.480 25.90 36.93 3 DO 215.000 0.71673 1 . 395 0.063623 15.637 14300.0 15974.3 153.347 25.91 36.74 372

220.000 0.69703 1.435 0.061678 16.167 14436.0 16157.6 154. 189 25.93 36.59 377

225.000 0.67853 1 . 47 * 0.059869 16.688 14571.6 163* 0.2 155.010 25.96 36.45 382

230.000 0.66112 1.513 0.058178 17.204 14707.1 16522.2 155.810 26.00 36 . 3 o 38 7 235.000 0.64466 1.551 0.056594 17.713 14842.4 16703.8 156.591 26.06 36.28 392

240.000 0.62914 1.569 0.055106 18.216 14977.7 16885.0 157.355 26.12 36.23 397 245.000 0.61441 1.629 0.053704 18.714 15113.0 17066.1 158.101 26.20 36.20 401

250.000 0 . 60042 1 . 66 b 0.052361 19.206 15248.5 17247.1 158. 833 26.29 36 . 19 40 o 255.000 0.58712 1.703 0.051129 19.697 15384.2 17428.1 159.549 26.38 36.20 *10

260.000 0. 57444 1 . 741 0.049942 20.183 15520.2 17609.1 160.253 26.49 36.23 415

265.000 0.56236 1.778 0.048815 20.665 15656.5 17790.4 160.943 26.61 36.27 419

220.000 0.55061 1 . 616 0.047742 21.143 15793.2 17971.8 161.621 26.73 36.33 423

225.000 0.53976 1 . 653 0.046720 21.619 15930.4 18153.6 162.289 26.87 36.40 427

260.000 0.52919 1.890 0.045745 22.092 16068.2 18335.8 162 . 9*5 27.01 36.48 431

265. 000 0.51905 1 . 927 0.044814 22.562 16206.5 18518.5 163.592 27.16 36.58 435

290.000 0.50932 1.963 0.043923 23.029 16345.5 18701.6 164.229 27.32 36.69 439

295.000 0.49997 2 . 000 0.043069 23.494 16485.2 18885.4 164.857 27.49 3 b . 61 443

300.000 0.49098 2.037 0.042250 23.957 16625.6 19069.8 165.477 27.67 36 . 9 * 447

310. 000 0.47399 2.110 0.040710 24.877 16908.9 19440.6 166.693 28.04 37.23 454

320.000 0.45620 2 . 182 0.039284 25.790 17195.6 19814.6 167.880 28.45 37.57 461

330.000 0.44346 2.255 0.037962 26 . 696 t 17486.2 20192.0 169.042 28.88 37.93 468

3 * 0.000 0.42973 2 . 327 0.036730 27.597 17780.9 20573.3 170.180 29.33 36.33 4 7 4 350.000 0.41664 2.399 0.035580 28.492 18079.9 20958.7 171.297 29.81 38.76 48 1 360.000 0.40473 2.471 0.034503 29.383 18383.6 21348.5 172.395 30.30 39.20 487

320.000 0. 39333 2.542 0.033492 30.270 18692.0 21742.9 173.476 30.81 39.67 493

360.000 0.38256 2 . 61 * 0.032541 31.153 19005.5 22142.1 174. 540 31 . 34 40 . 16 499

390.000 0.37242 2.685 0.031645 32.032 19324.0 22546.2 175.590 31.88 40.67 505

400.000 0.36260 2.756 0.030799 32.908 19647.9 22955.5 176.626 32.43 * 1.19 5 1 J 420.000 0.34503 2.696 0.029240 34.652 20311.9 23789.8 178.661 33.55 * 2.26 522

440.000 0. 32896 3 . 040 0. 027837 36.387 20998.0 24645.9 180.652 34.70 43. 35 532

460.000 0. 31436 3 . 181 0.026565 38.112 21706.8 25524.1 182.604 35.85 44.4 7 543

460.000 0.30102 3.322 0.025407 39.631 22438.3 26424.7 184.520 37.00 * 5 . 59 553

500.000 0.26860 3.463 0.024349 41.544 23192.4 27347.6 186.404 38.15 * 6.71 563

151
HETHANE ISOBAR AT P a 14.0 BAR

T DEN VOL QP/DT DP/OO E H S CV CP M OEG « NOL/L L/MOL BAR/K 8AR-L/M0L D/MOL J/MOL J/NOL/K J/MOL/K J/iOL/K •0/SEC

91.036 28.175 0.03549 20.6793 252.001 3476.

1

3525.8 67.936 33.20 $2.66 1578

95.000 27. 84 6 0.03591 19.6695 237.001 3675.8 3726.1 70. 193 33.07 53.07 1540

100. 080 27.427 0.03646 18.4550 218.429 3934.4 3985.4 72.935 33.16 $3.89 1487

105.000 27. 000 0.03704 17.3008 200.302 4200.2 4252.1 75.585 33.24 $4.76 143*

110.000 26.563 0.03765 16.2015 182.757 4472.2 452 4.9 78.152 33.18 55.57 1381

115.000 26.113 0.03629 15.1516 165.861 4749.

1

4802.7 80.638 32.94 56. 28 1329

120.900 25.649 0.03699 14. 1454 149.721 5030.1 5084.7 83.040 32.59 56.96 1277

125.000 25.167 0.03973 13. 1776 134.293 5315.2 5370.8 85.308 32.19 57.71 1225

130.000 24.666 0 • 0*054 12.2431 119.583 5604.5 5661.3 87.666 31.84 58.62 1171

135.000 24. 142 0.04142 11.3367 105.555 5899.1 5957.1 69.902 31.59 59.79 lllo

1 *0.000 23.591 0.0*239 10.4533 92.155 6200.2 6259.6 92. 102 31.44 61.27 1058

145.000 23.006 0.04347 9.5072 79.313 6509.6 6570.4 94.283 31.37 63.12 997

150.000 22.379 0.0*469 8.7316 66.953 6829.0 6891.5 96.460 31.29 65.40 934

155.000 21.696 0.0*609 7.8774 54.986 7160.9 7225.4 98.649 31.11 68.27 867

156.024 21.430 0.04666 7.5638 50.699 7285.7 7351.1 99.455 31.01 69.54 042

156.024 1.36353 0.723 0 . 140174 7.288 12515.1 13527.0 138.837 26.23 50.32 205

160.000 1. 32656 0.754 0.132146 7.891 12627.5 13682.8 139.820 27.78 47.90 291

165.000 1.25032 0 o 80 0 0.121993 8.757 12795.5 13915.2 141.251 27.20 45. 21 301

170. 000 1.16594 0.843 0.113870 9.550 12955.8 14136.3 142.571 26.92 43.33 310

175.000 1.13027 0. 665 0.107131 10.291 13110.7 143*9.4 143.606 26.67 41.9* 310

ISO. 000 1.08129 0. 925 0. 101399 10.991 13261.6 14556.3 144.972 26.47 40.87 325

105.000 1. 03764 0. 964 0.096431 11.660 13409.3 14758.5 146.080 26.32 40.03 332

190.000 0.99631 1. 002 0.092061 12.303 13554.5 14956.9 147.138 26.21 39.3$ 339

195.000 0. 96260 1. 039 0.088172 12.923 13697.8 15152.2 148.153 26.13 38.79 34b

200.000 0.92992 1.075 0.084678 13.526 13839.4 15344.9 149. 129 26.07 30.33 352

205.000 0.69986 1. Ill 0.081514 14.113 13979.8 15535.6 150.071 26.03 37.95 358

210.000 0.67206 1. 1*7 0.078628 14.687 14119.2 15724.6 150.961 26.02 37-64 36*

215.000 0.84624 1. 192 0.075981 15.248 14257.7 15912.1 151.864 26.01 37.38 370

220.000 0. 62216 1. 216 0.073541 15.800 14395.6 16090.4 152.721 26.02 37. 16 37$

225.000 0.79964 1.251 0.071280 16.341 14533.0 16203.8 153.554 26.05 36. 99 380

230.000 0.77849 1. 285 0.069178 16.875 14670.0 16468.4 154.365 26.08 36.85 385

235.000 0.75860 1.318 0.067217 17.401 14806.6 16652.3 155.156 26.13 36.73 390

240.000 0.73983 1. 352 0.065380 17.921 14943.4 16035.8 155.929 26.19 36.65 395

245.000 0.72208 1.385 0.063656 18.434 15080.0 17018.9 156.664 26. 26 36.59 400

250.000 0.70527 1.418 0.062033 18.942 15216.7 17201.7 157.423 26.35 36.56 40$

255.000 0.68931 1.451 0.060501 19.444 15353.5 17384.5 158.147 26.44 36.54 409

260.000 0.67413 1. 483 0.059053 19.942 15490.5 17567.2 158.856 26.54 36.55 41*

2o5 . 0 00 0.65968 1.516 0.057681 20.436 15627.7 17750.0 159.553 26.66 36.57 410

270.000 0.64589 1.548 0.056376 20.926 15765.4 179J2.9 160.236 26.76 36.61 422

275.000 0.63272 1.580 0.055139 21.412 15903.4 10116.1 160.909 26.91 36.67 42b

200.000 0.62013 1. 613 0.053959 21.894 16042.0 18299.6 161.570 27.05 36.7* 430

285.000 0.60806 1. 645 0.052833 22.374 16181.1 18403.5 162. 221 27.20 36.82 434

290.000 0.59650 1.676 0.051758 22.050 16320.8 18667.8 162.862 27.36 36.92 438

295.000 0. 58540 1.708 0.050729 23.324 16461.1 18852.7 163.494 27.53 37.03 442

300.000 0.57474 1.740 0.049745 23.795 16602.2 19038.1 16*. 117 27.70 37.15 446

310.000 0. 55*62 1- 803 Q. 047894 24.731 16866.7 19410.9 165.340 28.08 37.42 453

320.000 0.53695 1. 866 0.046187 25.657 17174.5 19786.7 166.533 28.46 37.74 460

330.000 0.51857 1.928 0.044605 26.577 17466.1 20165.0 167.700 28.91 38.09 467

340.000 0.50234 1.991 0.043135 27.489 17761.7 20548.6 168.8*2 29.36 38.48 474

350.000 0.48715 2.053 0.041764 28.395 18061.6 20935.5 169.964 29.83 38.89 480

360.000 0.47289 2. 115 0.040483 29.296 16366.

1

21326.6 171.065 30.33 39. 33 487

370.000 0.45949 2. 176 0.039281 30.192 16675.3 21722.2 172.149 30.64 39.79 493

380.000 0.44665 2.238 0.038153 31.064 16969.4 22122.5 173.217 31.36 40. 27 499

390.000 0.43492 2.299 0.037090 31.971 19308.7 22527.7 174.269 31.90 40.77 505

400.000 0.42363 2.361 0.036088 32.855 19633.2 22937.9 175.308 32.45 41.20 510

420.000 0.40278 2.483 0.034243 34.613 20298.3 23774.1 177.346 33.57 42 . 3* 522

440.000 0.36395 2.60$ 0 • 032585 36.359 20985.5 24631.6 179.342 34.71 *3. 43 532

460.000 0.36665 2.726 0.031084 38.095 21695.1 25511.4 161.297 35.87 44.54 543

400.000 0.35124 2.847 0.029720 39.823 22427.5 26413.3 183.216 37.02 45.6$ 553

500.000 0.33694 2. 968 0.028474 41.544 23182.4 27337.5 185.102 36.17 46.76 563

152
METHANE ISOBAR AT P * 16.0 BAR

T OEN VOL DP/DT OP/ DO E H S CV CP M DEG K MOL/L L/MOL BAR/K BAR-l/MOL J/MOL J/MOL J/MOL/K J/HOL/K J/MOL/K M/SEC

91.08? 28.179 0.03549 20.6726 252.265 3476.7 3533.5 67.945 33.21 52.65 1579

95 o 000 27.854 0.03590 19.6776 237.480 3673.® 3731.2 70.171 33.09 53. 06 1541

100.000 27.436 0.03645 18.4651 218.946 3932.2 3990.5 72.912 33.18 53.66 1489

105.000 27.010 0.03702 17.3127 200.852 4197.8 4257.0 75,562 33.26 54.73 1435

110.000 26.574 0. 03763 16.2152 183.336 4469.4 4529.6 .78.127 33.19 55.53 1383

115.000 26. 125 0. 03828 15. 1671 166.487 4746.

4807.3 80.611 32.96 56.24 1331

120.000 25.662 0.03697 14.1629 150.353 5026.7 5089.1 83.019 32.60 56.91 1279

125.000 25.182 0.03971 13.1972 134.949 5311.3 5374.9 85.357 32,21 57.65 1227

130.000 24.683 0.04051 12.2649 120.265 5600.2 5665.0 87.63S 31.86 58.55 1174

135.000 24. 161 0. 04139 11.3610 106.264 §894.2 5960.4 89. 665 31.61 59.70 1110

1*0.000 23.612 0.04235 10.4805 92.896 6194.6 6262.4 92. 0631.46 61.15 1061

145.000 23.031 0.04342 9.6179 8 0 o 0 9i 6503.0 6572.5 94,238 31.39 62.96 1001

150.000 22.408 0.04463 8. 7o66 67.776 6821.3 6892.7 96.408 31.30 65.16 933

155. 000 21. 732 0.04601 7.9180 55=867 7151.6 7225.3 98.569 31.12 67.95 872

160.000 20.982 0.04766 7.0595 44.267 7497.6 7573.9 190.882 30.7® 71.70 802

160.095 20.967 0.04769 7.0431 44.050 7504,3 7580.6 190.844 30.77 71.78 800

160.095 1.59544 0.627 0.165104 6.887 12520.5 13523.4 137.964 28.62 53.52 283

165.000 1.49068 0.671 0.150025 7.876 12700.9 13774.1 139.507 27.88 49.09 294

170. 000 1. 40433 0.712 0.138385 8.770 12872.5 14011.9 140.927 27.37 *6.20 304

175.000 1.33152 0.751 0.129084 9.588 13035.9 14237.5 142.236 27.02 44.17 313

180.000 1.26874 0. 786 0.121381 10.351 13193.4 14454.5 143.458 26.76 42.68 321

185.000 1.21363 0.824 0.114837 11.072 13346.5 14664.9 144.611 26.57 41.53 323

190.000 1. 16456 0. 659 0.109172 11.758 13496.3 14870.2 145.706 26.42 *0.62 336

195.000 1.12046 0.892 0.104195 12.417 13643.4 15071.4 146.751 26.31 39.89 343

200.000 1. 08042 0. 926 0.099771 13.054 13788.4 15269.3 147.754 26.23 39.29 349

205.000 1.04384 0.958 0.095799 13.671 13931.7 15464.5 148.718 26.17 38.80 355

210.000 1.01020 0. 990 0.092205 14.271 14073.6 15657.5 149.648 26.14 38.40 361

215.000 0. 97911 1.021 0.088930 14.857 14214.4 15848.6 150.547 26.12 38.06 367

220. 000 0. 95025 1. 052 0.085928 15.431 14354.4 16038.1 151.419 26.12 37.78 373

225.000 0.92 335 1. 083 0.083161 15.993 14493.6 16226.4 152.265 26. 14 37. 55 378

230.000 0.89818 1. 113 0.080600 16.546 14632 .3 16413.7 153.088 26.17 37.36 384

235.000 0.87458 1.143 0.078220 17.089 14770.6 16600.1 153.890 26.21 37.21 389

240.000 0. 85236 1. 173 0.076000 17.625 14908.7 16785.8 154.672 26.26 37.09 394

245.000 0.83141 1. 203 0.073923 18.153 15046.6 16971.0 155.436 26.33 37.00 349

250.000 0.61161 1.232 0.071973 18.675 15184.5 17155.9 156.183 26.41 36. 94 404

255.000 0.79284 1.261 0.070138 19.191 15322.4 17340.4 156.914 26.50 36. 93 408

260. 000 0. 77503 1.290 0.068407 19.702 15460.4 17524.9 157.630 26.60 36.88 413

2b5. 000 0.75810 1.319 0.066771 20.207 15598.7 17709.3 158.332 26.71 36.88 417

270.000 0. 74197 1. 348 0.065220 20.708 15737.3 17893.7 159.022 26.83 36.90 421

275.000 0.72656 1. 376 0.063749 21.205 15876.2 16078.3 159.699 26.96 36.94 426

280.000 0.71189 1.405 0.062350 21.697 16015.6 18263.1 160.365 27.10 37. 00 430

285.000 0.69783 1.433 0.061016 22.186 16155.5 18448.3 161.021 27.24 37.07 434

290.000 0.68437 1.461 0.059748 22.672 16295.9 18633.8 161.666 27.40 37.15 438

295.000 0.67146 1.489 0.058534 23.154 16436.9 16819.8 162. 302 27.57 3 7.25 442

300.000 0.65908 1.517 0.057374 23.634 16578.7 19006.3 162.929 27.74 37.36 445

310.000 0.63573 1.57 3 0.055198 24. 58* 16864.4 19361.1 164.158 28.11 37.62 453

320.000 0.61410 1.628 0.053194 25.525 17153.3 19756.8 165.357 28.51 37.92 460

330.000 0.59399 1. 684 0.051342 26.457 17445.9 20139.6 166.529 28.94 38.25 467

340.000 0.57524 1. 738 0. 049623 27.381' 17742.5 20523.9 167.676 29.39 38.63 474

350.000 0.55770 1.793 0.048023 28.299 18043.3 20912.2 168.802 29.86 39.03 480

360.000 0.54126 1.848 0.046529 29.210 163*8.5 21304.6 169.907 30.35 39.46 48 7 370. 000 0.52581 1. 902 0. 045131 30.115 18658.5 21701.4 170.994 30.86 39.91 493

380.000 0.51126 1.956 0.043818 31.015 18973.4 22102.9 172. 065 31.38 *0.38 499

390.000 0.49753 2. 010 0.042584 31.911 19293.3 22509.2 173. 120 31.92 40.88 5 0 5 400.000 0.46455 2.064 S. 041421 32.802 19618.4 22920.5 174.161 32.47 4 1.38 510

420.000 0.46060 2. 171 0.039283 34.573 20284.7 23758.5 176.205 33.59 42.43 522

440.000 0.43898 2.278 0.037364 36.332 20972.9 24617.8 178.204 34.73 43.51 533

460.000 0.41936 2. 385 0.035630 38.079 21683.5 25498.9 180. 162 35.89 44.61 543

480.000 0.40147 2.491 0 .034055 39.816 22416.7 26402.

182.084 37. 04 45. 71 553

500.000 0. 36506 2.597 0.032618 41.545 23172.4 27327.4 183.973 38.18 46. 62 563

1 S3
METHANE IS68&R AT P * 18.0 BAR

T DEN VOL DP/DT QP/DD E H S CV CP

DEG < MOL/L L/HOL 8AR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K i/SEC

91.136 26.162 0. 035*8 20.6663 252.528 3*77.3 35*1.2 67.953 33.23 52.64 1579

95. O0S 27. 663 0. 03569 19.6857 237.957 3671.8 3736.4 70. 150 33. 11 53. 04 1541

ISO .006 27. **6 0.036*4 18.4750 219.461 3929.9 3995.5 72.890 33.19 5 3 . 8h 1490

105. 000 27.020 0.03701 17.32*5 201.401 *195.3 *261.9 75.538 33.27 54.71 1437

110.000 26.565 0.03762 16.2266 163.91* 4*66.7 *53*.* 78.102 33.21 55.50 1384

115.000 26. 137 0. 03626 15.1826 167.091 *7*3.0 *811.9 80.585 32.98 56.20 1332

120.000 25. 675 0.03695 14.1603 150.982 5023.3 5093.* 82.990 32.62 56. 86 1281

125.000 25.197 0.03969 13.2166 135.603 5307.5 5379.0 85.326 32.23 57.59 1229

130.000 2*. 700 0.0*049 12.2866 120.9*4 5595.9 5668.8 67.601 31.88 58.47 1176

135. 000 2*. 160 0. 0-»136 11.3652 106.971 5669.3 5963.7 89.826 31.62 59.60 1121

1<*Q.0Q0 23.63* 0.0*231 10.5076 93.633 6169.0 6265.2 92.021 31.46 61.03 1 06h

1*5.000 23.056 0.0*337 9.6*83 80.665 6*96.6 6574.6 94.193 31.40 62.80 1 0 0 H 150 .000 22. *38 0.04*57 8.6011 68.595 6813.7 6893.9 96.357 31.32 64. 96 942

155.000 21. 766 0. 0*59* 7.9580 56.7*0 71*2.5 7225.2 98.529 31.13 67.65 8 77 160. 000 21.027 0.0*756 7.1071 *5.213 7*86.3 7571.9 100.730 30.79 71.22 807 163.06* 20.521 0.0*873 6.5703 38.220 7708.3 7796.0 102.117 30.49 7 4.24 7 o 2 163.06* 1.61506 0.551 0.191786 6.479 12517.3 13509.

0

137.1*9 29.03 57.13 282

165.000 1.76139 0.566 0.18358* 6.917 1259*.

0

13616.0 137.801 28.6* 54.55 28 7 170.000 1.6*372 0.606 0.166627 7.944 12781.1 13876.2 139.35* 27.91 49.90 298

175.000 1.5*6** 0.6*6 0.153760 8.656 12955.3 1*117.7 1*0.755 27.43 46.91 307

160.000 1* *6836 0.681 0.1*3*55 9.691 13120.9 143*6.7 142.0*6 27.08 44.81 316

165.000 1.39935 0.715 0.13*909 10.469 13260.4 1*566.7 1*3.251 26.83 43.25 32h

190.000 1.33660 0.7*7 0.12764* 11.204 13*35.4 1*779.9 1*4.366 26.6* *2.0 5 332

195.000 1. 26*93 0. 778 0.121353 11.905 13566.9 1*967.7 1*5.468 26.50 41.11 339

200.000 1.23650 0. 809 0.115625 12.577 13735.6 15191.3 1*6.499 26.39 40. 34 34o

205.000 1.19257 0. 839 0.110910 13.225 13682.1 15391.4 1*7.487 26. 32 39.72 353

210.000 1.152*3 0.668 0.106*99 13.854 1*026.6 15568.7 1*8.438 26. 26 39.21 359

215.000 1. 11553 0. 696 0.102507 14.465 1*170.

1

15783.7 1*9. 355 26.23 38.78 365 220.000 1. 081*4 0.925 0.098670 15.061 1*312.2 15976.7 150.2*3 26.22 33.43 371 225.000 1.0*976 0.953 0.095537 15.645 1*453.5 16166.1 151.103 26.23 38.14 377

230.000 1.02026 0.960 0.092*65 16.216 1*594.0 16356.2 151.939 26.25 37.90 382

235.000 0.99269 1. 007 0.069622 16.778 1*733.9 165*7.2 152.752 26.29 37.70 387

2*0.000 0.96660 1.03* 0.066960 17.330 1*873.5 16735.3 153.54* 26. 3* 37.54 392

2*5.000 0.9*2** 1.061 0.06*516 17.873 15012.7 16922.7 154.316 26.40 37.42 397 250.000 0.919*7 1. 066 0.062211 18.410 15151.9 17109.5 155.072 26.47 37.33 402

255.000 0.69775 1. 11* 0.0600*7 16.939 15291.

0

17296.0 155. 810 26-56 37. 26 407

260.000 0.87717 1.1*0 0.078011 19.462 15*30.1 17*82.2 156.533 26.65 37.22 412

265.000 0.65763 1.166 0.076091 19.979 15569.4 17668.2 157.2*2 26.76 37.20 416

270.000 0.83906 1. 192 0.07*276 2 0.491* 15708.9 17854.2 157.937 26.88 37.20 420

275.000 0.62136 1. 217 0.072556 20.999 158*6.8 160*0.2 158.620 27.00 37-22 425

260.000 0.804*8 1.2*3 0.07092* 21.501 15969.0 18226.4 159.291 27.1* 37.26 429

265.000 0.78836 1.268 0.069373 22.000 16129.6 16*12.9 159.951 27.29 37. 32 433

290. 000 0. 77293 1. 29* 0.067695 22.49* 16270.8 18599.6 160.60 0 27.4* 37.39 437

295.000 0.75816 1.319 0.066*86 22.985 16*12.6 18786.8 161.2*0 27.60 37.47 441 300.000 0.7*399 1.3*4 0.0651*1 23.473 16555.0 1897*.* 161.871 27.78 37.57 445

310.000 0.71733 1. 39* 0.062622 2*. *39 166*1.9 19351.3 163. 107 26.1* 37. 31 452

320.000 0.69266 1.*** 0.060308 25.393 17132.1 19730.7 L64.311 28.5* 38.09 460

330.000 0.66976 1.493 0.056173 26.336 17*25.7 20113.3 165.489 26.96 38.42 467

340. 000 0. 6*643 1. 5*2 0.056195 27. £7* 17723.2 20*99.2 166.6*1 29.41 38.78 473

350.000 0.62650 1.591 0.05*356 28.202 16024.9 20838.9 167.770 29.89 39.17 480

360.000 0.6096* 1.6*0 0.0526*3 29.123 18331.0 21282.6 168.879 30.38 39. 59 486

370.000 0.59231 1. 688 0.0510*1 30.036 166*1.6 21680.7 169.970 30.86 4 0.03 493

360.000 0. 57562 1. 737 0.0*9539 30.9*7 16957.3 22063.3 171.0** 31.41 40.50 499

390.000 0.56027 1. 785 0.0*6128 31.851 19277.9 22*90.7 172.102 31.9* 40.98 505

*00.000 0.5*557 1. 833 0.0*6799 32.750 19603.7 22902.9 173.1*6 32.49 41.48 51J

*20.000 0. 516*8 1. 929 0.0**361 34.53* 20271.

1

237*2.8 175.19* 33.61 42.51 522

*40.000 0.49*05 2. 02* 0.0*2175 36.305 20960.4 2*603.6 177.197 34.75 43.58 533

*60.000 0.47189 2.119 0.0*0202 36.062 21671.9 25*86.3 179. 158 35.90 44.68 543

*60.000 0.45170 2.21* 0.036413 39.809 22*05.

9

26390.6 161.063 37. 06 *5. 78 55*

5U0.000 0.43322 2.308 0.036761 *1.5*6 23162.4 27317.3 182.97* 38.20 46.87 564

154
METHANE ISOBAR ATP* 20.0 BAR

T DEN VOL OP/DT QP/OD E H S CV CP W DEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

91.199 20. 106 0.03549 20.6599 252.791 3478.0 3548.9 67.961 33.24 52.62 1579

95.000 22.921 0.03590 19.6938 238.433 3669.8 3741.5 70.129 33.13 53.02 1542

100.000 22.455 0.03642 18.4850 219.975 3927.7 4000.6 72.868 33.21 53. 82 1491

109.000 22. 030 0. 03200 17. 3362 201.948 4192.9 4266.9 75.515 33.29 54.68 1438

110.000 26.596 0.03760 16.2424 184.491 4464.0 4539.2 78.077 33.23 55.47 1386

115.000 26.149 0.03824 15.1990 167.694 4740.0 4816.4 80.558 32.99 56.16 133*

120.000 25.699 0.03993 14.1976 151.610 5020.0 5097.® 82.962 32.64 56. 82 i2e3

125.000 25. 212 0.03966 13.2359 136.256 5303.7 5383.1 85.295 32.25 57.53 1231

130.000 24.216 0.04046 12.3081 121.621 5591.6 5672.5 87.568 31.90 58.40 1178

135.000 24.199 0. 04132 11.4092 107.675 5884.5 5967.1 89.792 31.64 59.51 1124

140.000 23.655 0. 0*227 10.5344 94.368 6183.5 6268.0 91.981 31.50 60.92 1067

145.000 23.090 0.04333 9.6784 81.635 6490.2 6576.8 94.148 31.42 62.65 1007

150.000 22.462 0. 04451 8.8353 69.407 6606.2 6895.2 96.306 31.33 64.76 94o

155.000 21.603 0.04587 7.9974 57.606 7133.5 7225.3 98.470 31.15 67.35 881

160.000 21.021 0.04746 7. 1537 46.149 7475.2 7570-1 100.659 30.79 70. 76 813

165.000 20.239 0. 04941 6.2861 34.935 7836.8 7935.7 102.909 30.30 75. 86 736

165.943 20. 094 0.04979 6.1353 33.058 7900.5 8000.1 103.298 30.21 77.02 725

165.943 2.043 0.40936 0.2204 6.064 12506.7 13485.5 136.374 29.45 61.27 280

120.000 1.911 0.52342 0.1999 7.055 12678.9 13725.8 137.806 28.57 54. 95 291

125.000 1.295 0.5O035 0.1818 8.086 12867.5 13988.2 139.327 27.90 50.37 302

190.000 1.692 0.59441 0.1680 9.007 13043.3 14232.1 140.702 27.44 47.38 311

195.000 1.596 0.62649 0.1569 9.851 13210.5 14463.5 141.970 27.12 45- 27 320

190.000 1.522 0.65706 0.1477 10.640 13371.6 14685.7 143.155 26.88 43.69 328

195.000 1.452 0.68648 0.1399 11.385 13528.0 14901.0 144.273 26.70 42.47 336

200.000 1.399 0.71498 0.1329 12.095 13680.9 15110.8 145.336 26.56 41.50 343

205.000 1.346 0.74271 0. 1269 12.777 13830.9 15316.3 146.351 26.47 40.72 350

210.000 1.299 0.76981 0. 1216 13.435 13978.7 15518.3 147.324 26.40 40.09 357

215.000 1.256 0.79636 0.1168 14.072 14124.6 15717.4 148.261 26.35 39.56 363

220.000 1.216 0.82245 0.1124 14.692 14269.2 15914.0 149.166 26.33 39.13 369

225. 000 1. 129 0. 84813 0. 1084 15.297 14412.5 16108.7 150.041 26.32 38.76 375

230.000 1.145 0.97345 0.1048 15.888 14554.9 16301.8 150.889 26.34 38.47 380

235.000 1. 113 0.89846 0.1014 16.467 14696.6 16493.5 151.714 26.37 38. 22 386

240.000 1.093 0.92319 0.0983 17.036 14837.7 16684.1 152.516 26.41 38.02 391

245. 000 1. 055 0 . 9*767 0.0954 17.595 14978.4 16873.7 153.299 26.46 37.86 396

250.000 1.029 0.97192 0.0928 18.145 15118.9 17062.7 154.062 26.53 37.73 401

255.000 1. 004 0.99596 0.0902 18.688 15259.2 17251.1 154.808 26.61 37.63 406

260.000 0.901 1.01982 0.0879 19.224 15399.5 17439.1 155.538 26.71 37. 57 411

265.000 0.959 1.04350 0.0656 19.753 15539.8 17626.8 156.253 26.81 37.53 415

220.000 0.932 1.06704 0.0835 20.276 15680.3 17814.4 156.955 26.92 37.51 420

225.000 0.912 1.09042 0.0816 20.794 15821.1 18001.9 157.643 27.05 37.51 42*

290.000 0.999 1.11368 0.0797 21.306 15962.2 18189.5 158.319 27. 18 37.53 428

295.000 0.000 1. 13661 0.0779 21.814 16103.7 18377.3 158.984 27.33 37.57 432

290.000 0.062 1.15983 0.0762 22.318 16245.6 18565.3 159.638 27.48 37.63 436

295.000 0.945 1.18274 0.0746 22.817 16388.1 18753.6 160.281 27.64 37.70 440

300.000 0.929 1.20556 0. 0730 23.313 16531.2 18942.3 160.916 27.81 37.79 444

310.000 0.299 1.25092 0.0702 24.294 16819.4 19321.3 162.158 28.18 38.01 452

320.000 0.222 1.29597 0 . Qo75 25.263

26.220

17110.7 19702.7 163.369 28.57 38.27 459

330.000 0.246 1.34073 0.0651 17405.4 20086.9 164.551 26.99 38.58 466

340. 000 0. 222 1. 38523 0.0629 27.168 17703.9 20474.4 165.708 29.44 36.93 473

350.000 0.200 1.42952 0.0608 28.107 18006.5 20865.6 166.842 29.91 39.31 480

360.000 0.629 1.47360 0.0588 29.038 18313.5 21260.7 167.955 30.40 39.72 46b

320.000 0.659 1.51750 0.0570 29.962 18625.0 21660.0 169.049 30.91 •0.15 493

390.000 0.641 1.56124 0. 0553 30.879 16941.3 22063.7 170.126 31.43 40.61 499

390.000 0.623 1.60483 0. 0537 31.791 19262.5 22472.2 171.187 31.97 41.08 505

400.000 0.602 1.64929 0.0522 32.697 19588.9 22885.5 172.233 32.51 41.58 511

420.000 0.526 1.73464 0.0495 34.496 20257.5 23727.2 17*. 286 33.63 42.60 522

440. 000 0.549 1. 82097 0.0470 36.278 20947.8 24589.7 176.293 34.77 43.66 533

460.000 0.524 1.90676 0.0448 38.046 21660.3 25473.8 178.257 35.92 44.74 544

490.000 0.502 1.99224 0.0428 39.802 22395.1 26379.6 180.185 37.07 4 5.84 554

500.000 0.h91 2.07746 0.0410 41.547 23152.4 27307.3 182. 076 38.22 46.93 564

155
METHANE ISOBAR AT P a 22,0 BAR

»• T OEN VOL OP/DT DP/DO E H S CV CP w

DEIS K MOL/L L/MOL BAR/K 8AR-L/M0L J/MOL J/MOL J/MOL/K J/MOL/K J/iOL/K 1/ SEC 91.240 28.190 0.035+7 20.6534 253.053 3478.6 3556.6 67.970 33.26 52.61 1580 93.000 27. 879 0.03567 19. 7018 238.906 3667.6 37+6.7 70.107 33.14 53.00 15*3 100.000 27.464 0.03641 18,4949 220.438 3925.5 4005.6 72.846 33.23 53.80 1492

109.000 27. 040 0.03696 17.3+79 202. +93 4190 .

4271.8 75.491 33.31 54. b5 1 + 33 110.009 2 6.60 6 0.03756 16.2559 185. 0b6 4461.3 45+4.0 76.052 33.25 55.43 1387 113.009 26. 161 0. 03622 15.2133 166.296 4737.0 4821.1 80.531 33.01 56.12 1335

120.000 25. 702 0.05891 14.2148 152.236 5016.6 5102.2 82. 934 32.66 56.77 128 + 125.000 25.226 0.0595* 13,2551 136.906 5300.0 5387.2 85.265 32.26 57.47 1233

130.000 24. 733 0.0*043 12.3295 122.296 5587.4 567 6.3 87.535 31.91 58.33 1180 135.000 24.217 0.0*129 11.4330 108.377 5879.

7

5970.5 89.756 31.66 59.42 1126 140.000 23.676 0.04224 10. 5o C 9 95.099 6178.0 6270.9 91.9+1 31.51 o 0 . 8 J 1069

1 + 5. 000 23. 105 0.0*328 9. 7082 82. +01 6463.9 6579.1 9 + . 104 31.44 62.50 1011 150.000 22.496 0.0*445 6.8691 70.215 6798.8 6896.6 96.256 31.35 64. 56 9 + 9 155. 000 21. 837 0. 0+579 8. 0363 58.466 7124.7 7225.5 98.412 31.16 67.06 886 lbO.000 21. 114 C. 0+736 7.1995 47.075 746+.

3

7568.5 100.590 30.80 70.32 613

1 o5 .000 20.295 0. 0+927 6. 3422 35.952 7822.8 7931.2 102.822 30.29 75.11 745 lod • +1

1

19.653 0.05088 5.7307 28.455 8063.6 8195.5 10+.407 29.95 80.27 689

1 b8 • + 1

1

2.282 0.43822 0.2513 5 .o42 12489.1 13453.1 135.627 29.89 66.07 273 170.000 2.215 0.45141 0.2404 6.076 12562.0 13555.1 13o.230 29.43 62.38 283 125.000 2.045 0 . 43695 0.2144 7.268 12770.8 138+6.5 137.919 28.47 54.92 29o lao.ooo 1.91* 0.52257 0. 1957 8.294 12959.6 1+109.3 139. 400 27.86 50.55 306 165. 000 1.606 0 . 55369 0.1812 9.215 13136,3 14354.4 140.743 27.44 + 7.65 316 190.000 1.715 0.53303 0. lo94 10.064 1330+ •

5

14587.2 141.985 27.1 + *5.56 3 23 195.000 1.63 7 0.61104 0.1596 10.656 13466.6 1+810.9 143.147 26.91 + 4.03 333 200 . 000 1.567 0.63799 0. 1512 11.609 13624.

1

15027.7 144.245 26.75 42.78 340 205.000 1.506 0 . .>5411 0.1439 12.326 13778.1 15239.1 145.289 26.62 + 1.81 347 210.000 1.45 0 0.63953 0.1375 13.01+ 13929.2 1 54+6.

1

146.287 26.53 + 1.03 35 + 215.000 1.400 0.71436 0.1317 13.679 14078.0 156+9.6 147.245 26. +7 + 0.39 361 220.000 1.354 0.75869 0.1266 14.323 14225.1 15850.2 146.167 26.44 39.86 367 225.000 1. 311 C. 75259 0. 1219 1+.949 14370.7 i oO+e .

4

149.058 26.42 39. + 2 373 230. 000 1.272 0.78611 0.1176 15.561 14515.1 162+4.6 149.920 26.43 39.06 379 256.000 1.236 0.80951 0.1137 16.158 14658.6 16+39.1 150.757 26.45 38. 76 38+ 290. 000 1. 202 0. 83221 0. 1101 16.744 14801.4 16632.3 151.570 26.48 38.51 390 295. 000 1.170 0.85465 0.1067 17.318 14943.6 16824.3 152. 362 26.53 38.31 395 250.000 1. 14C 0 .87725 0.1036 17.883 15085.5 17015.4 153. 134 26.60 38.15 40 J 255.000 1.112 0.859*5 0.1007 18. +39 15227.0 17205.

8

153. 889 26.67 38. 02 405

2b0. 000 1. 085 C .921*5 0.0980 18.988 15368.5 17395.7 154.626 26.76 3 7 ."9l 410 2o5. 000 1. 060 0.9+327 0. 0954 19.529 15509.9 17586.1 155.348 26.86 37.86 41 + 270 .000 1.056 0.96494 0.0930 20.063 15651.5 17774.3 156.055 26.97 37.82 41* 275.0 00 1.014 0 .936*0 0.0908 20.591 15793.2 17963.

156.749 27. 09 37.83 423 260.000 0.992 1. 03764 0 . 0686 21.114 15935.2 18152.4 157.430 27.23 37.81 427 265 .000 0.972 1.02910 0 . 0866 21.631 lbO 77 •

5

183+1.5 158.099 27.37 37.83 432 290.000 0.952 1 . 05024 0 • 0647 22.143 16220.2 16530.8 158.758 27.52 37.88 43o 296.000 0. 93 3 1 ,0 T 128 0. 0828 22.651 16363.5 18720.3 159.406 27.68 37.9 + 440 500.000 0.916 1 . 09222 0.0611 23.155 16507.3 18910.2 160. 044 27.85 38.01 44* 510.000 0.882 1.15382 0.0778 2+.151 16796.8 19291.2 161.293 28.21 38.21 + 52 320. 000 0.651 1. 17509 0. 0749 25.133 17089.3 1967+.5 162.510 28. oO 38.46 459

330.000 0.622 1 . 21608 0. 0721 2b. 10+ 17385.1 20060.5 163.698 29. 02 38. 75 46o 340.000 0.796 1 . 25682 0.0696 27.063 17684.6 20++9.6 16+.859 29.47 39.08 473 350.000 0.771 1.23733 0 . 0673 28.013 17988.1 208+2.2 165.997 29.94 39.45 48 U 3o 0 . 0 00 0.746 1.5376* 0.0651 28.953 16295.

8

21238.7 167.114 30*43 39. 85 486 370.000 0. 72b 1. 37777 3.0630 29 • d 87 18608.1 21639.2 166.212 30.93 + 0.27 492

380.000 0.703 1 . 4 1 7 7 3 0.0611 30.813 18925.2 22044.2 169.292 31.45 40.72 49 9 390 .000 0. 666 1 . +575+ 0.0594 31.732 19247.1 22453.7 170.356 31.99 + 1.19 506 400.000 0 . b6 8 1 . +9722 0. 0577 32.646 19574.1 22868.0 171.404 32-53 *l.b3 511 420.000 0.634 1.57621 0.0546 34.458 20243.9 23711.6 17 J. 462 33.65 + 2.6 3 522

+ + 0 . 0 0 0 0.604 1.65479 0.0519 36.252 20935.2 2+575.8 175.472 34.79 + 3.7 + 533 460.000 0.577 1.75301 0. 0+94 38.030 21646.7 254ol.3 177.440 35.94 + + . 81 5 + + 460. 000 0. 552 1.8109+ 0. 0472 39.795 2238+.

3

263b8> 4 179.370 37.09 45.90 554 500.000 0.529 1 . 53860 0.0452 41.549 23142.4 27297.3 181.266 38.23 + 6.99 5b +

156
METHANE ISOBAR AT P

T OEM vol

29.0 ®AR

0P70T OP/OO E H S CP M 0E6 st H0L/L L/MOL ®AR/K SAR-L/MOL J/M0L J/N0L- J/NOL/K J/MOL/K M/SEC

91.291 28.199 0.03597 20.6969 253.315 3979.2 3569.3 67»f7® 33.27 52.60 1580

95.069 27.888 0.03586 19.709® 239.381 3665 37S I.® 70® 006 33. ii 52.9® 159*

100.066 27.973 0.03690 18.5067 221.00® 3923.3 9010.7 72.823 33.25 §3.77 1993

105.000 27.05Q* 0.03697 17.3596 203.03® 9188.0 9276.7 75.96© 33.33 59.63 1990

110.000 26.617 0.03797 16.2693 185.639 995®.

9598.® 78.027 33.26 5§« 90 1388

115.000 26.173 @.03821 15.2285 16®. @96 9739.0 9825.7 @6.505 33.03 56.03 1337

120.000 25.715 0.03839 19.2319 152.861 5013.3 5106.6 82.909 32.67 56.72 1286

125.000 25.291 0.03962 13.2792 137.559 5296.2 5391.3 85.239 32.28 57.91 1235

130.006 29.799 0.09091 12.350? 112.969 5583.2 5680.1 ®7 = 502 31.93 5®. 26 1183

135.000 29.236 0.09126 11.9566 199.076 S879.9 5973.® ©9.720 31.6® 59. 33 1128

190.000 23.697 0.09220 10.5873 95.82® 6172.6 6273.® 91.902 31.53 60.69 1072

195.000 23.129 1.09329 9.737® 83.169 6977.6 6581.3 99.060 31.95 62.36 1019

150.006 22.529 .0.09990 8.9025 71.01® 6791.5 6898.0 96.206 31.36 69.36 953

155.000 21.871 0.09572 8.0796 59.31® 7116.® 7225 .7 98.355 31.17 66.79 890

160.000 21.156 0.09727 7.2999 97.991 7953.7 7567.1 100.522 30. 81 69.91 829

165.000 20.350 0.09919 6.3969 36.959 7009.1 7927.1 102.737 30.29 79.92 752

170.006 19.399 0. 05155 5.5S91 26.195 0192.9 0316.6 105.062 29.01 82.25 670

170.819 19.229 0.05202 5.350® 29.33® 825® « ® 8382.® 105.999 30.13 89.53 652

170.819 2.532 0.39995 0.2896 5.219 12969.7 13912.6 139.897 30.35 71.73 277

175.000 2.338 0.92765 0.2530 6.382 12662.0 13688.9 136.993 29.17 61.26 289

180.000 2.166 0.96163 0.2272 7.593 12868.6 13976.5 138.116 28.39 59.5® 301

185.000 2.031 0.99233 0.2082 8.557 13056.9 19230.5 139.553 27. @0 50.51 311

190.000 &.920 0.52085 0.1932 9.979 13233.7 19983.7 190.861 27.92 97.79 321

195.000 1.825 0.59731 0.1810 10.322 13902.9 19717.1 192.073 27.15 95.72 329

200.006 1.793 0.57358 11. 11® 13565.2 19991.® 193.211 26.99 99.20 33 7 205.000 1.671 0. 59891 0.1619 11.072 13723.5 15159.7 199.287 26.79 93.00 395

210.000 1.606 0.62297 0.1592 12.593 13078.3 15372.2 195.311 26.68 92.05 352

215.000 1.598 0. 69591 0.1979 13.206 19030.3 15580.5 196.291 26.66 91.27 358

220.000 1.995 0 . 66880 0.1919 13.955 19180.1 15785.2 197.233 26.55 90.69 365

225.000 1.987 0.69129 0.1359 19.609 19328.1 15987.1 198.190 26.52 90.12 371

230.000 1.902 0.71328 0.1309 15.235 19979.6 16186.5 199.017 26.52 39.68 377

235.000 1.361 0.73997 0.1269 15.851 19620.1 16389.0 199.866 26.53 39.32 383

290.000 1.322 0.75636 0.1222 16.959 19769.6 16579.8 150.691 26.56 39-82 3®#

295.000 1.286 0.77798 0. 1189 17.099 19908.9 16779.3 151.993 26.6® 30.78 399

250.000 1.253 0.79835 0.1198 17.623 15051.6 16967.7 152.279 26.66 38.58 399

255.000 1.221 0.81901 0. 111S 18.193 15199.5 17160.2 153.037 26.73 38.92 909

260.000 1.191 0.83996 0.1069 18.759 15337.2 17351.9 153.781 26. ©2 38.29 909

265.000 1. 163 0. 85979 0.1055 19.307 15979.8 17593.2 159.510 26.91 38.20 913

270.000 1.137 0.87985 0.1028 19.852 15622.9 17739.0 155.223 27.02 38.19 918

275.000 1. ill 0.89982 0.1092 20.391 15769.1 17929.6 155.923 27.19 38.10 922

280.000 1.087 0.91969 0.097® 20.923 15908.0 18115.1 156.609 27.27 3®. 09 927

285.000 1.065 0.93939 0.0955 21.950 16051.1 18305.6 157.283 27.91 38.10 931

290.001 1.093 0.95892 0.0933 21.971 16199.7 18996.1 157.996 27.56 38.13 935

295.000 1.022 0.97890 0.0912 22.98® 16338.7 18696.9 158.59® 27.72 38.17 939

300.000 1.002 0.99777 0.0893 22.999 16983.2 18877.9 159.29® 27.89 38.29 993

310.000 0.965 i. 03629 0.0856 29.010 16779.1 19261.1 160.997 28.29 36.91 951

320.000 0.931 1.07937 0. 0023 25.006 1 7 067 o a 19696.3 161.720 28.69 38.69 959

330.000 0.899 1. 11222 0.0792 25.989 17369.7 20039.0 162.913 29.05 38.92 966

3*0.006 0.870 1.1*982 0.0769 26.95,9 17665.2 20929.7 169.879 29.50 39.23 973

350.000 0.892 1.19718 0.0738 27.92® 17969.6 20818.8 165.222 29.96 39.59 980

360.000 0.817 1.22935 0.0719 28.870 1S278.2 21246.6 166.392 30.95 39.98 986

370.000 0.793 1.26133 0.0691 29.813 18591.3 21618.5 167.993 30.96 90.39 992

380.000 0.770 1.29819 0. 0670 30.797 16909.

22029.6 168.526 31.9® 90.83 999

390.000 0.799 1. 33981 0.0651 31.675 19231.7 22935.2 169.593 32.01 91.30 505

900.000 0.729 1.37139 0.0632 32.596 19559.9 2285®.

170.695 32.56 91.77 511

920.000 0.693 1 . 9990 3 8 • 059® 39.921 20230.3 23696.1 172.707 33.67 92.7® 522

990.000 0.659 1.51631 9. 0560 36.226 20922.7 29561.8 179.721 39.il 93.82 533

960.000 0.630 1.53823 0.0591 38.015 21637.0 25998.® 176.692 35.96 99.8® 59*

980.000 0.602 1.65936 0.0516 39.789 22373.6 26357.3 178.625 37.11 95.96 559

500.009 0.578 1.73122 0.0999 91.551 23132.9 27287.3 130.523 38.25 97.0* 56*

157
METHANE ISOBA* AT P 26.0 BAR

T DEN VOL OP/OT SP7D0 E H S CV CP W OEG K MOL^L L/N0L BAR/K S&R-l/MOL J/MOL J/NOL J/NOL/K J/HQl/K J/NOl/K M/SEC

91 . 3*2 28 . 19 ® 0.03546 20 . 6 * 0 * 253.576 3479.

8

3572 . 1

- 67.986 33.29 52.59 1580

99.939 27.696 0.03535 19.7177 239.853 3663.8 3757.0 70.065 33.18 52.97 1545

199.999 27.*®

2

0.03639 18 . 51*5 221.510 3921.1 * 015.6 72.801 33.26 53.75 1494

195.099 27.060 0.03696 17.3712 203.581 *185.6 * 281.7 75.444 33.34 54.60 1441

110.000 26.626 0 • 03755 16.2827 186.211 * 455.9 *553.6 78.002 33.28 55.37 1390

113.900 26.185 0. 03 @19 15 . 2*37 169. 49* * 731.0 * 830.3 80.479 33.05 56 . 04 1339

129.000 25 . 72 ® 0.03837 14 . 2*89 153 . 48 * 5009.9 5111.0 82.877 32.69 56.67 1268

125.000 25.256 0.03960 13.2932 136.201 5292.5 5395.5 85.204 32.30 57.36 1237

133.000 2*. 765 0 . 0*038 12.3718 123 . 6*0 5579.0 5684.0 87.469 31.95 58.19 1165

135.000 2 *. 25 * 0 . 0*123 11.4601 109.772 5870.2 5977.4 89.685 31.69 59.25 1131

1 * 0.000 23.718 0 . 0*216 10 . 613* 96.553 6167.2 6276.8 91,862 31.55 60 . 56 1075

1 *5.000 23.153 0 . 0*319 9.7670 83.922 6 *71 .* 6563.7 94.016 31.47 62.22 1017

150.000 22.552 0 . 0 **3 * 8. 9355 71.815 678*.

2

6899.5 96.157 31.38 64.17 957

155.000 21.905 0 . 0*565 8.1123 60 . 16 * 7107 .* 7226.1 93.298 31.19 66.52 894

1 (30.000 21 . 19 ? 0 . 0*718 7.2885 * e . 8 @a 7 ** 3.

2

7565.8 100.455 30.82 69.51 829

165 .000 20. *03 0 . 0*901 6.4502 37 . 9*2 7799.8 7923.3 102.655 30.29 73.76 759

170.006 19 .7 * 0.05135 5.5727 27.202 817*.

7

8306.2 104.952 29.79 80.96 679

173.077 18.792 0. 05321 *.9912 20.625 8 *29.5 8567.8 106.463 30.09 69.29 618

173.077 2 . 79 b 0.35772 0.3208 *.777 12 *33.5 13363.6 134.175 30.85 78.55 275

175.000 2 . 67 ® 0.37339 0.3006 5.398 12536.0 13506.9 134.999 30.11 70.95 282

ISO . 000 2.**6 0.40877 0.2637 6 . 7 ** 12767.8 13830.7 136 . 82 * 28.92 59.94 295

105.000 2.275 0.43961 0.2385 7.871 12971 .* 1 * 114.4 138 . 379 26.21 54.04 307

190.000 2.136 0.46771 0 . 219* 8.868 13158.6 1 *374.7 139.767 27.73 50.30 317

195.000 2 . 02 * 0.49395 0 . 20*3 9.776 13335.0 1 *619.3 1 * 1.038 27.39 47.70 326

200.000 1.927 0.51682 0.1917 10.621 13503.8 1 *852.8 1 * 2.220 27.15 45.76 334

205.000 1 . 9*3 0 . 5*263 0.1611 11. *15 13667.0 15077.8 143.332 26.96 44 . 31 342

210.000 1.769 0.56560 0.1720 12.170 13825.9 15296.4 144.385 26.83 * 3.15 349

215.000 1.701 0.58788 0 . 16*0 12.892 13981.3 15509.8 145.390 26.73 42.23 356

220.000 1 . 6*0 0.60959 0.1569 13.587 1 * 13*.

1

15719.0 146.351 26.66 41.47 363

225.000 1.565 0.63061 0.1505 1*.259 1 * 28*.

6

15924.7 147.276 26.62 40.85 369

239.000 1.535 0.65161 0 • 1**6 1*. 912 1 **33.

5

16127.7 148.168 26.61 40.33 375

235.000 1**68 0.67205 0.1396 15 . 5*6 1 * 580.9 16328.2 149.031 26.61 39.91 361

2 * 0.000 1 • **5 0.69216 0 . 13*8 16.166 1 * 727.2 16526.8 149.867 26.63 39.55 367

2 *5.000 l .*0 * 0.71200 0 . 130* 16.772 1 * 872.6 16723.8 150.680 26.67 39.26 392

250.000 1.367 0.73158 0.1263 17.366 15017 .* 16919.5 151.470 26.73 39.02 398

255.000 1.332 0 . 7509* 0.1226 17.950 15161.7 17114.1 152 . 2*1 26.79 38.63 403

230.000 1.299 0.77009 0. 1191 18.523 15305.6 17307.9 152.993 26.67 38.67 406

265.000 1.267 0.78906 0.1158 19.086 154*9.4 17500.9 153.729 26.97 38.55 412

270.000 1.236 0.60787 0.1127 19 . 6 ** 15593.0 17693.5 154 . 4*9 27.07 38.47 417

275.000 1.210 0.82652 0.1098 20.193 15736.7 17885.7 155 . 15 * 27.19 38.41 422

200.000 1 . 183 0 . 8*502 0.1071 20.735 15680.6 18077.6 155 . 8*6 27.31 38.38 426

205.000 1.156 0 • 8o 3*0 0 . 10*5 21.271 16024.6 18269.5 156.525 27.45 38.37 430

290.000 1 . 13 * 0.89166 0.1021 21.801 16169.0 18*61.3 157.192 27.60 38.38 *35

295.000 1.111 0.89982 0.0996 22.326 16313.8 18653.3 157 . 8*9 27.76 38.41 439

300.000 1 . 069 0.91786 0.0976 22 . 8*6 16 *59.1 188*5.5 158.495 27.92 38.46 443

310.000 1 . 0*9 0.95368 0.0936 23.872 16751.3 19230.8 159.758 26.28 38.61 451

320.000 1.011 0.98916 0.0896 2*. 881 170* 6.2 19618.0 160.987 28.67 38.8 2 458

330.000 , 0.976 1 . 02*35 0.0665 25.876 173*4.2 20007.5 162. 186 29.08 39 . 09 466

3 * 0.000 0 . 9** 1.05929 0.0633 26.856 176* 5.7 20399.8 163.357 29.53 39.39 473

350.000 0 . 91 * 1.09399 0.0805 27.628 17951.0 20795.4 164.504 29.99 39.73 479

360.000 0 . 866 1. 12850 0.0778 28.789 18260.5 21194.6 165.628 30.46 40.11 486

370.000 0.660 1. 16261 0.0753 29 . 7*0 1857*.* 21597.7 166.733 30.98 40.52 492

300.000 0.835 1.19696 0.0730 30.683 18892.9 22005.0 167.819 31.50 40.95 499

390.000 0.812 1.23097 0.0708 31.618 19216.3 22416.8 168.888 32.03 41.40 505

* 00. 000 0.791 1 . 26*63 0. 0686 32 . 5*6 195*4.6 22833.1 169.943 32.58 41.87 511

* 20.000 0.751 1. 33220 0.0650 3*. 385 20216.7 23680.4 172.009 33.69 * 2.86 522

**0.000 0.715 1 . 3991* 0.0617 36.202 20910.2 24547.9 174.027 34.83 43 . 89 533

*60 o 0 00 0.682 1 . 4657 * 0.0588 38.001 21625.5 25436.4 176.002 35.98 44.95 544

* 60.000 0.653 1.53203 0.0561 39 . 76 * 22362.9 263* 6.1 177.937 37.12 46.03 554

500.000 0.626 1.59606 0.0536 * 1 . 55 * 23122.4 27277.4 179.838 38.26 47.10 565

158 /
I

METHANE ISOBAR AT P « 2®.® BAR

T OEN VOL DP/DT OP/ 00 E H S CV CP H OEG K NOL/l L/MOL BAR/K BAR-L/MOL J/HOl J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

91.393 28.202 0.03546 20.6340 253.617 3480.5 3579.8 - 67.995 33.30 52.57 1581

95.000 27.905 0.03584 19.7256 240.324 3661.8 3762.2 70.044 33.20 52.95 1546

100.000 27.491 0.03638 16.5243 222.018 3919.0 4020.8 72.779 33.28 53.73 1495

105.000 27.070 0.03694 17.3627 204.123 4183.2 4286.6 75.421 33.36 54.57 1443

110.000 26.639 0.03754 16.2960 186.782 4453.3 4558.4 77.978 33.30 55.34 1391

115.000 26.196 0.03817 15.2586 170.092 4728.0 4834.9 80.453 33.06 56.00 1340

120.000 25.741 0.03685 14.2656 154.105 5006.6 5115.4 82.849 32.71 56.63 1290

125.000 25.270 0.03957 13.3121 138.846 5288.8 5399.6 85.174 32.32 57.30 1239

130.000 24.781 0.04035 12. 3928 124.309 5574.8 5687.8 87.437 31.97 58.12 1187

135.000 24.272 0.04120 11.5034 110.466 5865.5 5980.8 @9.649 31.71 59.16 1133

140.000 23.739 0.04213 10.6394 97.275 6161.8 6279.8 91.623 31.56 60.47 1078

145.000 23.176 0.04315 9.7960 84.676 6465.2 6586.0 93.973 31.49 62.08 1020

150. 000 22.579 0. 04429 3.9682 72.608 6777.1 6901.1 96.109 31.39 63.99 96 0 155.000 21.938 0.04558 8.1496 61.004 7098.9 7226.6 98.243 31.20 66.26 899

160.000 21.237 0.04709 7.3319 49.796 7432.9 7564.7 100.389 30.83 o9. 13 834

165.000 20.455 0.04669 6.5023 38.917 7762.8 7919.7 102.574 30.30 73. 14 765

170.000 19.546 0. 05116 5.63S9 28.287 8157.1 8306.4 164.846 29.77 79.79 687

175.000 18.410 0.05432 4.6926 17.750 8577.3 8729.4 107.330 30.13 94. 18 588

175.216 16.353 0.05449 4.6483 17.293 8597.2 8749.8 107.446 30.15 95.15 583

175.216 3.075 0.32520 0. 3603 4.332 12395.4 13305.9 133.452 31.38 86.92 273

100.000 2.763 0.36167 0.3072 5.877 12654.3 13667.5 135.490 29.64 67.49 289

105.000 2.541 0.39352 0.2729 7.149 12878.4 13980.2 137.204 28.68 58.53 302

190.000 2.372 0.42160 0.2484 8.241 13078.5 14259.0 138.691 28.08 53.37 312

195.000 2.235 0.44740 0.2296 9.218 13264.

14516.9 140. 031 27.66 •9.96 322

200.000 2.120 0.47161 0.2143 10.116 13439.9 14760.4 141.264 27.36 47.56 331

205.000 2.022 0.49463 0.2016 10.954 13608.6 14993.5 142.415 27.14 45.75 339

210.000 1.935 0. 51671 0.1908 11.745 13771.8 15218.6 143.500 26.98 44.36 347

215.000 1.659 0.53605 0.1614 12.49® 13931.0 15437.5 144.530 26.86 43.25 354

220.000 1.790 0.55676 0.1731 13.220 14086.9 15651.5 145.514 26.78 42. 35 361

225.000 1.727 0.57896 0.1658 13.916 14240.3 15861.3 146.457 26.73 41.62 368

230.000 1.670 0.59671 0.1592 14.590 14391.5 16067.9 147.365 26.70 41.02 374

235.000 1.616 0.61808 0.15 32 15.244 14541.1 16271.7 148.242 26.70 40.52 380

240.000 1.570 0.63712 0.1478 15.881 14689.3 16473.3 149. 091 26.71 40.11 386

245.000 1.525 0.65566 0.1428 16.503 14836.5 16672.9 149.914 26.74 39*76 391

250.000 1.483 0.67434 0.1382 17.112 14982.8 16871.0 150.714 26.79 39.48 396

255.000 1.444 0.69260 0.1340 17.709 15128.5 17067.8 151.494 26.85 39.25 402

260.000 1.407 0.71064 0.1300 18.295 15273.7 17263.5 152.254 26.93 39.06 407

265.000 1.373 0.72649 0.1263 10.871 15418.7 17458.4" 152.997 27.02 38*91 412

270.000 1.340 0.74617 0.1229 19.439 15563.4 17652.7 153.723 27.12 38. 80 416

275.000 1.309 0.76369 0.1197 19.998 15708.2 17846.5 154.434 27.23 38.72 421

200.000 1.280 0.76108 0.1166 20.550 15853.0 18040.0 155. 131 27.36 38.67 425

205.000 1. 253 0.79833 0.1138 21.096 15997.9 16233.3 155.815 27.49 38.64 430

290.000 1.226 0.81546 0.1111 21.634 16143.2 16426.5 156.487 27.64 38.64 434

295.000 1.201 0.63247 0.1085 22.167 16288.

18619.7 157.148 27.79 3 8 # b 6 438

300.000 1.177 0.64 938 0.1061 22.695 16434.8 16813.0 157.798 27.96 38.69 442

310.000 1.133 0.68293 0. 1016 23.735 16728.4 19200.6 159.069 28.31 38.82 450

320.000 1. 092 0.91614 0.0975 24.758 17024.5 19569.7 160.304 28.70 39.01 458

330.000 1.054 0.94905 0.0938 25.765 17323.6 19981.0 161.508 29.11 39.26 465

340.000 1.019 0.98171 0.0903 26.758 17626.2 20375.0 162*684 29.55 39.55 472

350.000 0.966 1.01413 0.0872 27.739' 17932.5 20772.0 163.835 30.02 39.88 479

360.000 0.956 1.04635 0.0342 28.709 18242.8 21172.6 164.964 30.50 0 • 2* <•86 370.000 0.927 1.07836 0.0815 29.669 18557.5 21577.0 166.072 31.00 h0.64 492

380.000 0.901 1. 11025 0. 0790 30.620 16876.

21985.5 167. 161 31.52 <1.06 499

390.000 0.676 1.14197 0.0766 31.563 19200.8 22398.3 168.233 32.06 41.51 505

400.000 0.652 1.17355 0.0744 32.498 19529.8 22815.7 169.290 32.60 41.97 511

420.000 0.609 1.23635 0.0703 34.350 20203.1 23664.9 171.361 33.71 42.95 522

440.000 0.770 1. 29672 0.0667 36.178 20897.6 24534.0 173. 383 34.85 43.97 533

460.000 0.735 1.36075 0.0635 37.907 21613.9 25423.9 175.361 35.99 h5. 02 544

460.000 0.703 1.42247 0.0605 39.779 22352.1 26335.0 177.299 37.14 <6.09 555

500.000 0.674 1.46392 0.0579 41.557 23112.5 27267.5 179.202 3 8.2® 47.16 565

159
METHANE ISOBAR AT P * 30.0 BAR

T DEN VOL OP/OT DP/DD E H S CV CP W DEG K NQL/L L/MOL BAR/K bar-l/mol J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

91. 444 28.206 0 . 03545 20.6276 254.097 3481.1 3587.5 68.003 33.31 52.56 1581

95.000 27.913 0.03583 19.7335 240.793 3659.8 3767.3 70.023 33.21 52.93 1547

100.000 27.500 0.03636 18.5340 222.526 3916,8 4025.9 72.757 33.30 53-71 1496

105.000 27.079 0 . 03693 17. 3942 204.663 4180.8 4291.6 75.398 33.38 54.55 144*

110.000 26. o49 0.03752 16.3092 187.351 4450.6 4563.2 77.953 33.31 55.30 1392

115.000 26.208 0.03816 15.2738 170.687 4725.1 4839.5 80.426 33.08 55. 96 1342

120. 000 25. 754 0.03883 14.2827 154.724 5003.

3

5119.8 82.821 32.73 56.58 1291

125.000 25.284 0.03955 13.3309 139.489 5235.1 5403.8 85.144 32.33 57.24 1241

130.000 24. 797 0. 0*033 12.4137 124.975 5570.7 5691.7 87.404 31.98 58.05 1189

135.000 24.290 0.0*117 11.5265 111.158 5860.

8

5984.3 89.614 31.73 59. 08 1 1 3o 150.000 23.759 0.04209 10.6651 97.994 6156.5 6282.8 91.785 31.58 60.37 1081

145.000 23.200 0. 0*310 9. 8247 85.427 6459.1 6588.4 93.930 31.50 61.94 1023

150.000 22.007 0. 04423 9.0005 73.396 6770.0 6902.7 96.060 31.41 63.81 96*

155.000 21.970 0.04552 8.1864 61.837 7090.6 7227.1 98.187 31.21 66.01 903

160.000 21.277 0. 04700 7.3745 50.685 7422.8 7563.8 100.325 30.84 68.76 839

165.000 20.506 0. 0*877 6.5532 39.880 7770.2 7916.5 102.495 30.30 72.55 772

120.000 19.616 0 . 05098 5.7028 29.351 8140.2 8293.1 10*. 744 29.76 78.71 696

125.000 18.519 0 . 05400 4. 7819 18. 982 8551.7 8713.7 107. 178 30.07 91.54 600

122.245 17.902 0.05586 4.3190 14.298 8762.8 8930.4 108.408 30.29 102.43 549

122.245 3.374 0.29641 0.4039 3.878 12349.5 13238.8 132.719 31.98 97.48 271 180.000 3.134 0 . 3190* 0.3611 4.913 12521.9 13479.0 13*. 064 30.59 79. 22 282

165.000 2.837 0. 35250 0.3128 6.382 12775.6 13833.1 136.006 29.24 64.43 296

190.000 2.625 0.33100 0.2809 7.589 12992.5 14135.5 137.619 28.47 57 . 14 308

195.000 2.459 0 • 40666 0.2573 8.645 13189.2 14409.1 139. 041 27.96 52.64 319

200.000 2. 323 0.43043 0.2387 9.603 13373.

0

14664.

3

140.333 27.60 *9. 58 328

205.000 2. 208 0.45284 0.2235 10.488 13547.9 14906.4 141.528 27.34 47.35 337

210. 000 2.109 0.47421 0. 2107 11.317 13716.1 15138.8 142.648 27. 14 45.67 34*

215.000 2. 021 0 • *9476 0 . 1997 12.103 13879.4 15363.7 143.707 27.00 44. 35 352

220.000 1.943 0 .51464 0.1901 12. 854 14038.7 15582.6 144. 714 26.90 43.29 359

225.000 1.873 0.53397 0.1817 13.574 14195.0 15796.9 145.677 26.84 42.44 36o

230.000 1.809 0. 55283 0.1742 14.270 14348.8 16007.3 146.602 26.80 41.74 372

235.000 1.750 0.57129 0.1674 14.944 14500.6 16214.5 147.493 26.78 *1.16 378

2*0 .000 1.697 0.589*0 0.1612 15.598 14650.9 16419.1 148. 354 26.79 40.68 38*

245.000 1.647 0.60720 0. 1556 16.237 14799.8 16621.5 149.189 26.81 40.28 390

250.000 1.601 0 .62474 0. 1504 16.860 14947.8 16822.0 149.999 26.86 39.95 39?

255.000 1. 558 0.6*203 0.1457 17.471 15095.0 17021.1 150.788 26.91 39.68 401

2o 0 . 0 00 1.517 0.65911 0. 1*13 18.070 15241.6 17218.9 151.556 26.99 39.46 406

265.000 1.479 0.67600 0.1372 18.658 15387 .7 17415.7 152.306 27.07 39.28 411

270.000 1. 444 0.69271 0.1333 19.237 15533.6 17611.8 153.039 27.17 39.14 416

275. 000 1.410 0 . 7092b 0.1297 19.807 15679.* 17807.2 153.756 27.28 39.04 420

280.000 1. 378 0. 72567 0. 1264 20.368 15825.2 18002.2 154.459 27.40 38.97 426

285.000 1.348 0 . 7*194 0. 1232 20.923 15971.1 18196.9 155. 148 27.54 38.52 429

290.000 1.319 0.75809 0. 1202 21.470 16117.2 18391.5 155.825 27.68 38.90 434

295.000 1.292 0. 77412 0.1174 22.011 16263.6 18586.0 156.490 27.83 38.90 433

300.000 1.26b 0.79005 0.1147 22.547 16410.4 18780.5 157.144 27.99 38.93 442

310.000 1.217 0.82163 0.1098 23.601 16705.4 19170.2 158.421 28. 35 39. 03 450

320.000 1. 173 0. 85286 0.1053 24.637 17002.8 19561.3 159.663 28.73 39.20 458

330.000 1.131 0. 33380 0. 1012 25.656 17303.0 19954.4 160.873 29.14 39.43 46?

3*0.000 1.094 0 . 91448 0.0974 26.661 17606.6 20350.1 162.054 29.58 39.70 472

350.000 1.058 0.9*493 0.0940 27.652 17913.

9

20748.6 163. 209 30.04 40.02 479

360.000 1.025 0 .97517 0.0908 28.631 18225.1 21150.6 16 4. 341 30.53 40 . 38 486

373.000 0.995 1. 00522 0.0878 29.600 18540.6 21556.3 165.453 31.03 40.75 492

380.000 0.966 1.03511 0. 0850 30.559 18860.6 21965.9 166. 545 31.55 *1.19 49 i 390.000 0. 93 9 1 • 0o48? 0.0824 31.509 19185.3 22379.9 167.621 32.08 *1.62 5 0? 400.000 0.914 1.09445 0.0800 32.452 19515.0 22798.3 168.680 32.62 42.07 511

420.000 0.867 1.15329 0.0756 34.31b 20189.5 236*9.3 170.756 33.73 *3.0* 522

440.000 0.825 1.21170 0.0717 36.156 20885.1 24520.2 172.781 34.87 **•05 53*

460.000 0.788 1. 2d976 0. 0682 37.975 21602.

3

25411.5 174.762 36.01 *5. 09 5**

460.000 0. 753 1.32752 0. 0b50 39.776 22341.4 26323.9 176.704 37.16 *6. 15 555

500.000 0. 722 1.38502 0. 0622 41.561 23102.5 27257.6 178.609 38.30 *7.21 56 ?

160
METHANE ISOBAR AT P « 32o0 BAR

T OEN VOL OP/DT DP/OD E H S GV CP W OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/HOL J/HOL J/MOL/K J/MOL/K J/MOL/K M/ SEC

91.495 26. 210 0. 03545 20.6211 254.357 3401.8 3595.2 68.011 33.33 52.55 1581

95.000 27.921 0.03582 19.7413 241.261 3657.9 3772.5 70.002 33.23 52.91 1547

100.000 27.509 0.03635 18.5437 223.032 3914.6 4031.0 72.735 33.31 53.69 1497

105.000 27.069 0.03692 17.4056 205.202 4178.4 4296.5 75,375 33.40 54.52 1445

110.000 26.660 0.03751 16.3224 187.919 4448.0 4568.0 77.929 33,33 55.27 1394

115.000 26.220 0.03614 15.2667 171.201 4722.1 4044.2 80.400 33.10 55.93 1343

120.000 25.767 0.03881 14.2994 155.342 5000.1 5124.3 82.794 32.74 56.53 1293

125.000 25.299 0.03953 13.3495 140.130 5281.5 5408.0 85. 114 32.35 57.19 1243

130.000 24.613 0.04030 12.4344 125.640 5566.6 5695.5 87.372 32. 00 57.98 1191

135.000 24.306 0.04114 11.5495 111.847 5856.1 5987.8 89.579 31.75 56.99 1138

1 AO . 000 23.779 0.04205 10.6906 98.710 6151.2 6285.8 91.746 31.60 6 0*26 1083

145.000 23.223 0.04306 9.6532 86*174 6453.

6590.9 93.887 31.52 61.81 1026

150.000 22.634 0.04418 9.0325 74.180 6763.0 6904.4 96.013 31.43 63.63 963

155.000 22.002 0 • O-s-545 8.2227 62.664 7062.3 7227.8 98.133 31.23 65.77 907

160.000 21.316 0.04691 7.4164 51.567 7412.9 7563.0 100.261 30.85 66.41 844

165.000 20.555 0.04665 6.6030 40.831 7757.8 7913.4 102. 417 30.30 72.00 778

170.000 19.683 0.05081 5.7647 30.396 8123,6 8286.4 104.644 29.74 77.72 704

175.000 18. 621 0.05370 4.8663 20.175 0527.7 8699.5 107.035 30.02 89.25 612

179.176 17.435 0. 05736 4.0006 11.614 0927.7 9111.2 109.360 30.51 111.74 515

179.176 3. o96 0.27056 0.4523 3.415 12295.2 13161.0 131.965 32.65 111.24 269

100.000 3.595 0.27618 0.4332 3.790 12356.0 13248.2 132.450 32.01 100.90 273

105.000 3.172 0.31524 0.3601 5.554 12659.9 13666.6 134.756 29.93 72.04 290

190.000 2.901 0. 34474 0.3176 6.906 12899,1 14002.3 136.536 28.91 ol.09 304

195.000 2.699 0.37056 0.2876 6.055 13109.6 14295.3 138.059 28.28 55.01 315

200.000 2.537 0.33410 0.2651 9.079 13302.9 14564.0 139.419 27.85 51.09 325

205.000 2.403 0.41607 0.2469 10.015 13484.

14616.2 140.665 27.54 49. 14 334

210.000 2.289 0.43686 0.2316 10.887 13658.6 15056.6 141.824 27.31 47.10 342

215.000 2.169 0.45679 0.2191 11.707 13826.3 15206.0 142.913 27.15 45.53 350

220.000 2.101 0. 47597 0.2080 12.487 13989.4 15512.5 143,945 27.03 44.30 357

225.000 2.022 0.49457 0.1963 13.233 14146.15731.4 144.929 26.95 43.30 364

230.000 1.951 0.51266 0.1897 13.951 14305.3 15945.8 145.872 26.90 42.49 371

235.000 1.686 0.53033 0.1820 14.645 14459.5 16156.6 146.778 26.87 41.03 377

240.000 1. 626 0.54764 0.1751 15.318 14611.9 16364.3 147.653 26.87 41.23 383

245.000 1.771 0 . 56463 0.1668 15.973 14762.7 16569.5 148.499 26.89 40.82 389

250.000 1.720 0.58134 0.1630 16.612 14912.4 16772.6 149.320 26.92 40 . 44 394

255.000 1.673 0.59780 0.1577 17.236 15061.1 16974.0 150.117 26.98 40.12 400

260.000 1.629 0.61404 0. 1528 17.848 15209.1 17174.0 150.894 27.04 39.87 405

265.000 1.587 0.63008 0.1482 18.446 15356.5 17372.8 151.651 27.13 39.66 410

270.000 1.548 0.64595 0.1440 19.036 15503.6 1757 0.6 152. 391 27.22 39.49 415

275.000 1.511 0.66165 0.1400 19.618 15650.5 17767.8 153.114 27.33 39. 36 420

260.000 1.47 7 0.6/720 0.1363 20.189 15797.3 17964.3 153.823 27.45 39.27 424

265.000 1. 444 0.69262 0.1328 20.753 15944.1 18160.5 154.517 27.58 39.20 429

290.000 1.413 0.70791 0. 1295 21.309 16091.1 18356.4 155. 198 27.72 39. 16 433

295.000 1.363 0.72308 0.1264 21.858 16238.3 18552.2 155. 068 27.87 39.15 437

300.000 1.355 0.73615 0. 1235 22.401 16385.8 18747.9 156.526 28.03 39.16 442

310.000 1.302 0.76601 0.1181 23,470 16602.3 19139.9 157.811 28.38 39.24 450

320.000 1.254 0.79752 0.1132 24.519 16980.9 19533.0 159. 059 28. 76 39.39 458

330.000 1.210 0.62673 0.1067 25.550 17282.4 19927.9 160.274 29.17 39.60 4 65 340.000 1. 169 0. 65568 0. 1046 26.565 17587.0 20325.2 161.460 29.61 39.86 472

350.000 1. 131 0.96439 0.1008 27.566 17895.2 20725.3 162.620 30.07 40.17 479

360.000 1.095 0.91290 0.0974 28.555 18207.3 21128.6 163.756 30.55 4 0.51 48o

370.000 1.062 0.94122 0.0941 29.532 18523.6 21535.5 164.871 31. 05 40.89 492

360.000 1. 032 0 . 9o938 0.0911 30.500 18844.4 21946.4 165.967 31.57 41.29 499

390.000 1.003 0.33738 0.0883 31.457 19169.22361.5 167.045 32.10 41.72 5 0 5 400.000 0.975 1.02525 0 .0857 32.407 19500.1 22730.9 168.107 32.64 42. 17 511

420.000 0. 925 1. 08062 0.0810 34.284 20175.9 23633.8 170.187 33.75 43.13 523

440.000 0.881 1.13556 0.0767 36.134 20872.5 24506.3 172.217 34.88 44.13 53-. <.60.000 0.840 1.19016 0.0729 37.963 21590.7 25399.2 174. 20 1 36.03 45.16 545

460.000 0.804 1.24445 0.0695 39.773 22330.6 26312.9 176. 145 37. 17 46-21 555

500.000 0.770 1.29648 0.0665 41.566 23092.6 27247.7 178. 053 38.31 47.27 565

161
METHANE ISOBAR ATP* 34. 0 BAR

T OEN VOl. OP/OT DP/OD £ H S CV CP H DEG K MOL/L L/MOL BkR/K 8AR-L/M0L J/MOL J/MOL J/MOL/K J/MOL/K J/MOl/K 4/SEC

91.546 26.214 0.03544 20.6147 254.616 3462.4 3602.9 68.020 33.34 52.54 1581

95.000 27.929 0.03590 19.7491 241.726 3655.9 3777.7 69.981 33.25 52.90 1549

190.000 27. 516 0. 03634 18.5533 223.537 3912.5 4036.0 72.71

3

33.33 53.67 1498

105.000 27.099 0.03690 17.4170 205.740 4176.0 4301.5 75. 352 33.41 54.50 1446

110. 000 26.671 0.03749 16.3355 186.466 4445.3 4572.8 77.904 33. 35 55.24 1395

115.000 26.232 0.03612 15.3036 171.674 4719.2 4846.8 80. 375 33. 12 55. 89 1345

120. 000 25.760 0. 03679 14.3161 155.959 4996.6 5128.7 82.766 32.76 56.49 1295

125.000 25. 313 0.03951 13.3681 140.769 5277.8 5*12.2 85.085 32.37 57.13 1245

130.000 24. 929 0.04026 12.4550 126.302 5562.5 5699.4 87.340 32.02 57.92 1193

135.000 24.326 0. 04111 11.5724 112.534 5851.5 5991.3 99.544 31.76 58.91 1141

140.000 23.900 0. 04202 10.7160 99.423 6146.0 6288.9 91.708 31.62 6 0.16 108o

145. 000 23.246 0. 04302 9. 6914 66.918 6447.1 6593.4 93.845 31.53 61.69 1024

150.000 22.661 0.04413 9.0641 74.959 6756.1 6906.1 95.965 31. *4 6 3.46 971

155.000 22.034 0.04538 8.2565 63.486 7074.2 7228.5 98.079 31.24 65.54 911

160.000 21.355 0. 04663 7.4577 52.441 7403.1 7562.3 100.198 30. 86 68.07 849

165.000 20. 604 0. 04653 6. 6517 41.770 7745.6 7910.7 102. 342 30.31 71.49 734

170.000 19.746 0.05064 5. 8247 31.424 6109.0 8260.2 10*. 546 29.74 76.80 711

175.000 19.719 0. 05 343 4.9464 21.336 8504.8 8686.5 106.900 29.97 87.25 622

lao.ooo 17.325 0.05772 3.9353 11.315 8977.7 9174.0 109.645 30.53 112.61 510

101.019 16.945 0. 05901 3.6907 9.217 9093.5 9294.2 110. 311 30.83 124.00 481

191.019 4.049 0.24704 0.5066 2.943 12230.9 13070.8 131. 177 33.43 129.84 267

195.000 3.565 0.26052 0.4162 4.644 12525.3 13479.1 133.410 30.82 85.66 28*

190.000 3.206 0.31167 0.3597 6.165 12796.6 13857.0 135.426 29.43 68.09 299

195.000 2.957 0.33921 0.3217 7.444 13024.4 14174.3 137. 075 28.64 59.64 311

200.000 2.764 0.36174 0.2936 8.544 13229.0 14458.9 138.516 28. 12 54.57 321 205.000 2.609 0. 39343 0.2721 9.536 13419.0 14722.7 139.819 27.76 51.15 331 210.000 2.476 0.40391 0.2543 10.452 13599.

0

14972.0 141.021 27.49 48.66 34 0 215.000 2.363 0.42319 0.2395 11.310 13771.7 15210.5 142.1*4 27.30 46. 82 348

220.000 2.264 0.44179 0.2266 12.120 13938.8 15440.9 143. 20 3 27.16 45.37 355

225. 000 2. 175 0.45975 0.2157 12.693 14101.6 15664.8 144.209 27.06 *4.22 362

230.000 2. 096 0.47719 0.2060 13.634 14261.1 15883.5 145. 171 27.00 43.29 36)

235.000 2. 024 0.49417 0.1973 14.349 14417.6 16098.0 146.093 26.96 *2.53 3 7o 240.000 1.959 0.51079 0.1895 15.040 14572.3 16309.0 146.982 26.95 41.90 382

2*5.000 1.997 0.52706 0.1624 15.712 14725.1 16517.1 147.840 26.96 *1.37 388

250.000 1.941 0.54304 0.1760 16.366 14676.5 16722.9 148.671 26.99 40.94 393

255.000 1.790 0.55679 0.1701 17.004 15026.8 16926.7 149.478 27.04 40.58 399

260.000 1.741 0.57429 0.1646 17.629 15176.3 17128.8 150.263 27.10 *0.28 40*

265.000 1 . 69o 0.59956 0.1596 16.241 15325.

0

17329.6 151. 028 27. 18 40. 0* 409

270.000 1.654 0.60470 0.1549 19.841 15473.3 17529.3 151.775 27.27 39.85 41*

275.000 1.614 0.61965 0.1505 19.432 15621.3 17726.1 152.505 27.38 39.69 419

200. 000 1. 576 0.63445 0.1465 20.013 15769.2 17926.3 153.219 27.49 39.57 424

205.000 1.541 0.64911 0.1426 20.566 15917.0 18123.9 153.918 27.62 39.49 *28

290.000 1.507 0.66 365 0.1390 21.151 16064.8 18321.2 154. 605 27.76 39. 43 433

295.000 1.475 0.67607 0.1356 21.706 16212.9 18518.3 155.278 27.91 39. 40 437

300.000 1. 44 4 0.63236 0.1324 22.259 16361.2 18715.3 155.941 28.07 39.43 441

310.000 1.369 0.72071 0.1265 23.342 16659.1 19109.5 157. 233 28.41 39.45 44 ) 320.000 1.336 0.74870 0.1212 24.404 16959.0 19504.6 158.488 28.79 39.56 457

330.000 1.266 0.77638 0.1163 25.447 17261.6 19901.3 159.708 29.20 39.77 465

340.000 1.244 0. 60380 0.1119 26.472 17567.3 20300.3 160.899 29.64 40.02 472

350.000 1.203 0.93099 0.1078 27.484 17676.5 20701.9 162.06 3 30.10 40.31 47 4 360.000 1.166 0.85797 0.1040 29.481 18169.5 21106.6 163.204 30. 58 *C . 6* 4 8o 370.000 1.130 0.99476 0.1005 29.467 16506.7 21514.9 164. 322 31.08 41.01 *92

390.000 1.097 0.91139 0.0973 30.442 18628.2 21926.9 165.421 31.59 41.41 499

390.000 1.066 0.93766 0.0943 31.407 19154.4 22343.1 166.502 32.12 41.83 505

400.000 1.037 0.96420 0.0915 32.364 19485.3 22763.6 167.567 32.66 *2.27 511

420.000 0.994 1.01651 0. 0863 34.253 20162.2 23616.4 169.652 33. 77 43.21 523

440.000 0.936 1.06839 0.0818 36.114 20859.9 24492.5 171.685 34.90 44.21 53*

460.000 0.993 1.11993 0.0777 37.953 21579.1 25366.8 173.672 36.05 *5.23 545

490.000 0.954 1. 17116 0.0741 39.771 22319.9 26301.9 175.619 37.19 *6.27 555

500.000 0. 916 1.22213 0. 0708 41.572 23062.6 27237.9 177.530 38.33 47.33 56o

162
METHANE IS09AR AT P * 36,0 BAR

T OEN VOL DP/DT DP/OD £ H S CV CP W DEG K HOL/L L/MOL BAR/K 8AR-L/N0L J/HOL J/MOL J/MOL/K J/ HOC/

J/HOL/K H/SEC

91.597 26.218 0.0354* 20.6083 254.874 3483.1 3610.6 68. 028 33.36 52.53 1582

95.000 27.938 0.03579 19.7568 242.193 3654.0 3782.8 69,960 33.26 52.88 15*9

loo. ooo 27.527 0. 03633 13.5620 224.040 3910.3 4041.1 72.691 33.35 53.65 1*99

105.000 27.109 0.03689 17.4203 206.276 4173.6 4306.4 75.329 33. *3 5*. 4 7 1**7

110.000 26.681 0 . 03748 16.3485 189.051 4442.7 4577.6 77.880 33.37 55.21 139c

115.000 26.243 0.03811 15.3184 172.465 4716.3 *853.5 8 0. 3*9 33.13 55.85 13*6

120.000 25. 792 0.03877 14.3326 156.574 4993.6 5133.1 82.738 32.78 56.4* 1296

125.000 25. 327 0.03948 13.3865 141.407 5274.2 5416.4 05 . 055 32.39 57.08 12*6

130.000 24.845 0.0*025 12.4755 126.963 5550.4 5703.3 07.300 32.03 57.05 1 195

135.000 24.3*4 0.0*108 11.5950 113.218 5847.5994.8 89.509 31.78 58.83 11*3

1*0.000 23.820 0.04196 10.7411 100.134 6140.8 6291.9 91.670 31.63 60.06 1089

1*5.000 23.269 0.04298 9.9094 87.658 6441.2 6595.9 93.80 3 31.55 61.55 1032

150.000 22.687 0.0*408 9. 0954 75.734 6749.2 6907.9 95.910 31. *6 63. 29 975

155.000 22.065 0.04532 8.2939 64. 302 7066.2 7229.3 98,026 31.25 65.31 915

160.000 21.393 0.0*675 7.4983 53.307 7393.5 7561.7 100.136 30.87 47.7* 85*

165.000 20. o51 0.04842 6. 6994 42.6?9 7733.8 7908.1 102.267 30.31 70.98 789

170.000 19. 810 0.05046 5. 8830 32.436 8092.6 8274.3 104. 454 29.73 75.95 719

175.000 18.809 0.05317 5.0228 22.468 8403.8674.5 106.771 29.93 35.49 632

160.000 17.491 0.05717 4.0544 12.673 8940.1 91*5.9 109.425 30.37 106.68 527

162.761 16.423 0.06089 3.3868 7.089 9262.3 9*81.5 111.274 31.28 1*0.93 44 6

162. 781 4.438 0.22532 0.5691 2.465 12154.4 12965.6 130.339 34.35 156.24 264

165.000 4. 051 0.2*688 0. 4946 3.609 12360.3 132*9.0 131.881 32.11 108.56 2 7c 190.000 3.551 0.28158 0.4091 5.418 12681.9 13695.6 13*. 265 30.05 76.59 293

195.000 3.238 0.30888 0.3597 6.810 12932.5 140**.

136. 078 29.04 64. 39 307

200.000 3.006 0. 33263 0.3253 7.995 13150.9 14348.4 137.617 28.41 57.70 318

205.000 2.823 0. 35420 0.2992 9.050 13350.4 1*625.5 138.986 27.98 53.42 3 2 d 210.000 2.0 72 0. 37*27 0.2783 10.014 13537.4 14884.7 1*0.235 27.68 50. *3 337

215.000 2.543 0.39323 0.2611 10.910 13715.5 15131.1 1*1. 395 27.45 *8. 22 3*6

220.000 2.431 0.4113* 0.2465 11.753 13887.0 15367.6 1*2.483 27.29 *6.53 353

225.000 2.332 0.42876 0.2339 12.553 14053.5 15597.0 143.513 27.17 *5.20 361

230.000 2.24* 0 . **563 0.2229 13.319 14216.0 15820.2 14*. *95 27.10 *4.13 368

235.000 2. 164 0.46202 0. 2131 14.054 14375.4 16038.6 1*5. *34 27.05 *3.26 37*

240.000 2.092 0.47801 0.2044 14.765 14532.3 16253.1 146.337 27.03 *2.5* 381

2*5. 000 2.026 0.49366 0. 1965 15.453 14687.1 16464.3 147.208 27.03 *1.95 387 250.000 1.965 0.50901 0.1893 16.123 14840.3 16672.7 148.050 27.06 *1.46 392

255.000 1.908 0.52410 0. 1828 16.775 14992.16879.148.067 27.10 *1.05 393

260.000 1.855 0.53895 0.1768 17.412 15143.2 17083.4 149.661 27.16 40.71 *03

265.000 1.806 0.55359 0.1712 18.036 15293.3 17286.2 150.434 27.23 *0.43 *0 9 270.000 1.760 0. 56805 0.1661 18.648 15442.8 17487.8 151.187 27.32 *0.21 * 1* 275.000 1.71

0.58233 0. 1613 19.249 15592.0 17688.4 151.923 27.42 *0.03 *18

280.000 1.677 0.59647 0.1568 19.840 15740.9 17888.1 152.643 27.54 39.88 *23

285.000 1.638 0.61046 0.1526 20.422 15889.6 18087.3 153. 348 27.66 39.73 *28

290.000 1.602 0.62432 0.1487 20.995 16038.4 18286.0 15*. 039 27.80 39.70 *32

295.000 1.567 0.63807 0. 1450 21.561 16187.3 18484.4 154.718 27.95 39.66 *37

300.000 1.534 0.65171 0. 1415 22.119 16336.5 18682.6 155.384 28. 10 39.6* **1

310.000 1.473 0.67869 0. 1351 23.217 16635.8 19079.1 156.684 28.45 39.6 7 4*9

320.000 1.418 0.70532 0.1293 24.291 16937.

19476.2 157. 9*5 28.82 39.77 *57

330.000 1.367 0.73165 0.1240 25.345 17240.9 19874.8 159. 171 29.23 39.95 *6 5 3*0.000 1.320 0.75771 0.1192 26.382 17547.6 20275.4 160.367 29.66 *0.18 *72

350 .000 1.276 0.7335* 0.1148 27.403 17857.8 20678.5 161.536 30.12 *0.46 *79

360.000 1.236 0.80916 0.1107 28.410 18171.7 21084.7 162.600 30.60 *0.78 436

370. 000 1.196 0.03459 0.1070 29.404 18489.7 21494.2 163. 002 31.10 *1.13 *92

380.000 1. 163 0 . 85986 0.1035 30.387 10812.0 21907.5 164.904 31.61 *1.52 *9*

390.000 1.130 0.38497 0.1003 31.359 19138.8 22324.7 165. 988 32. 14 *1.94 505

*00.000 1.099 0.90994 0.0972 32.322 19470.5 22746.3 167. 055 32.68 *2.37 511

*20.000 1.042 0.95953 0.0917 34.223 20148.6 23602.9 169. 1*5 33.79 *3.30 523

*40.000 0.991 1 . 00870 0.0869 36.096 20847.4 24478.7 171.181 34.92 **.28 53*

*60.000 0. 946 1. 05751 0.0825 37.943 21567.5 25374.5 173.172 36. 06 *5.30 5*5

480.000 0.904 1. 13602 0. 0786 39.770 22309.2 26290.8 175. 122 37.21 *6.3* 5 5o 500.000 0.866 1. 15427 0.0751 41.579 23072.7 27228.0 177.035 38.34 *7.38 566

163
METHANE ISOBAR AT P * 38.0 BAR

T DEN VOL DP/DT DP/DD E H S CV CP W DEG K MOL/L L/HOL BAR/K BAR-L/MOL J/HOL J/MOL J/NOL/K J/MOL/K J/MOL/K M/SEC

91.6*8 28. 222 Q. 035*3 20.6020 255.132 3*83.7 3618.* 68.037 33.37 52.51 1582

95.000 22o 9*6 0.03578 19.76*5 2*2.657 3652.0 3788.0 69.939 33.2® 52.86 1550

100.000 22.536 0.03632 18.572* 224.5*2 3908.2 *0*6.2 72.669 33.37 53.63 1500

105.000 22.110 0.03683 17.4396 206.811 *171.3 *311. 4 75.306 33.45 5* . ** 1449

110.000 26.692 0. 037*6 16.3615 189.615 ***0.1 *582.* 77.856 33.38 55.18 1398

115.000 26.255 0.03809 15. 3331 173.05* *713.* *858.1 8Q.323 33.15 55.81 1 348

120.000 25. 605 0.03875 14.3*91 157.187 *990.3 5137.6 82.711 32.80 56.40 1293

125.000 25.3*1 0.039*6 13.40*9 1*2.043 5270.6 5*20.6 85. 026 32.40 57.03 1248

130.000 2*. 861 0.0*022 12.4958 127.621 555*.* 5707.3 87.277 32.05 57.79 1198

135.000 2*. 361 0.0*105 11.6176 113.900 58*2.* 5998.* 89.475 31.80 58.75 1145

1*0.000 23.8*0 0.0*195 10.7661 100.8*2 6135.7 6295.1 91.633 31.65 5 9.96 1091

1*5.000 23. 292 0. 0*293 9.9372 88.395 6*35.3 6598.* 93.762 31.57 61.42 1035

150.000 22.213 0.04*03 9.126* 76.50* 67*2.* 6909.7 95.872 31.47 6 3.13 978

155.000 22. 096 0.0*526 8.3289 65.112 7056.2 7230.2 97.973 31.27 65.09 919

160.000 21. *30 0.0*666 7.5383 54.166 736*.

0

7561.3 10 0. 07 5 30.88 67.43 859

165.000 20.698 0. 0*831 6.7*62 *3.618 7722.1 7905.7 102.195 30.32 70.50 795

If 0.000 19. 871 0.05032 5.9397 33. *32 8077.7 8268.9 104.363 29.72 75. 15 72o

125.000 18.896 0.05292 5.0959 23.573 8*62.* 8663.5 106.6*7 29.90 83.89 642

180.000 17.6*2 0.05668 4.1631 13.968 8905.

9

9121.3 109. 225 30.2* 102.00 542

18*. *69 15.857 0 • 06306 3. 0861 5.216 9*36.6 9676.3 112.268 31.92 165.87 411

18*. *69 *.880 0.20*93 0.6*17 1.985 12062.6 128*1.3 129.428 35.50 196. 20 262

185.000 *. 726 0.21158 0.6102 2.3** 12132.7 12936.7 129.9*5 3*. *5 166.01 265

190.000 3.952 0.25307 0.4688 *.591 12550.2 13511.9 133.017 30.83 89.07 286

195.000 3.5*6 0.20198 0.4029 6.1*8 12632.* 13903.9 135.05* 29.50 70.4* 302

200.000 3.266 0.30621 0. 3600 7. *31 13067.8 1*231.* 136.713 28.73 o 1 . * 3 315

205.000 3.051 0.32781 0.3285 6.55* 13278.* 1*524.1 138.159 28.23 56.02 325

210.000 2.826 0. 3*769 0. 3039 9.570 13*73.3 1*794.5 139.462 27.87 52.37 335

215.000 2.730 0.36633 0.2839 10.507 13657.5 150*9.5 1*0.662 27.61 *9.75 344

220.000 2.60* 0.33*03 0.2672 11.38* 13833.6 15293.1 1*1.782 27.43 47.77 352

225. 000 2. *9* 0. *0099 0.2529 12.21* 1*00*.

2

15528.0 1*2.838 27.29 *6.2* 359

230.000 2.396 0.41736 0.2*05 13.00* 1*170.0 15756.0 143.8*0 27.20 45.01 36o

235.000 2.308 0.43323 0.2295 13.761 1*332.2 15978.5 1*4.798 27.1* 44.02 373

2*0.000 2.229 0. **869 0.2198 1*.*91 1**91.

6

16196.6 1*5.716 27.11 *3.21 379

2*5.000 2. 156 0. *6378 0.2110 15.197 1*6*8.

6

16*10.9 1*6.600 27.11 42.55 3 8o 250.000 2.090 0.47856 0. 2031 15.862 1*803.7 16622.2 1*7.453 27.13 41.99 391 255.000 2. 028 0.49308 0.1958 16.5*8 1*957.3 16831.0 1*8.280 27.16 41.53 397

260.000 1.971 0.50735 0.1892 17.199 15109.8 17037.7 1*9. 083 27.22 41.15 403

265.000 1.918 0.521*0 0.1831 17.835 15261.3 172*2.6 1*9.86* 27.29 40.84 408

220.000 1.866 0.53527 0.1775 16. *56 15*12.1 17*46.1 150.625 27.37 40.58 41 3 225.000 1.822 0.5*896 0.1723 19.069 15562.* 176*8.5 151.367 27.47 40.37 413

280.000 1.778 0.56250 0.167* 19.670 15712.* 178*9.9 152.093 27.58 40.20 423

285.000 1.736 0.57589 0.1628 20.261 15862.2 18050.6 152.803 27.71 40.07 427

290.000 1.697 0.58916 0.1585 20.8*3 16011.9 18250.7 153.499 27.8* 39.98 432

295.000 1.660 0.60230 0.15*5 21. *16 16161.7 18*50.* 154.182 27.99 39.92 4 3o 300.000 1.625 0.61533 0.1507 21.982 16311.7 186*9.9 15*. 853 28. 1* 39.88 441 310.000 1.560 0.6*110 0.1*38 23.09* 16612.5 190*8.7 156. 160 28.48 39.83 449

320.000 1.500 0 • 66652 0.1375 2*. 161 16915.1 19*47.9 157.428 28. 85 39.97 457

330.000 1 . *46 0.6916* 0.1318 25.2*7 17220.1 198*8.3 158.660 29.26 •0.12 •65

3*0.000 1.396 0.716*8 0. 1266 26.29* 17527.9 20250.5 159. 861 29.69 •0.34 472

350.000 1.3*9 0.7*110 0.1219 27.32* 17839.0 20655.2 161.03* 30.15 40.60 479

360.000 1.306 0.76550 0.1175 28.3*0 18153.9 21062.7 162.182 30.63 40.91 48o

320.000 1.26b 0 . 73971 0.1135 29.3*3 18*72.7 21*73.6 163.307 31.12 41.26 •92

380.000 1. 229 0.81376 0.1098 30.333 18795.7 21888.0 164.413 31.6* 41.6* *99

390.000 1. 19* 0.83766 0.1063 31.313 19123.3 22306.4 165.499 32.17 * 2. Oh 505

*00.000 1.161 0.861*1 0.1031 32.282 19*55.6 22729.0 166.569 32.70 *2.47 511

*20.000 1.101 0.90856 0.0972 3*. 196 20135.0 23587.5 168.663 33.81 *3.39 523

**0.000 1. 0*7 0.95529 0.0920 36.078 20834.8 24*64.9 170.70* 34.9* *4.36 53*

*60.000 0.998 1. 03167 0.087* 37.936 21555.9 25362.2 172.698 36.0 8 •5.37 5*5

*80.000 0.95* 1.0*77* 0.0832 39.771 22298.5 26279.9 174.651 37.23 46. 40 55o

500.000 0.91* 1.09356 0.0795 *1.567 23062.7 27218.

3

176. 566 38. 36 47. 44 566
METHANE. ISOBAR ATP* 40.0 BAR

T OEN tfOL DP/OT OP/DO E H S CV CP W EG K MOL/L L/HOL BAR/K BAR“L/MOL J/MOL J/MOL J/ MOL/

J/HOL/K J/HOL/K H/SEC

91.699 28.226 0.03543 20.5956 255.389 3484.4 3626.1 68.045 33.39 52.50 1582

99.000 27.954 0.03577 19.7721 243.119 3650.1 3793.2 69.918 33.30 52. 85 1551

100. 000 27.545 0.03630 18.5618 225.043 3906.

4051.3 72.647 33.38 53.61 1501

105.000 27. 126 0.03696 17. 4506 207.345 4168.9 4316.4 75.283 33.46 54.42 145 J 110.000 26.702 0.03745 16. 3744 190.177 4437.5 4587.3 77. 832 33.40 55. 15 1399

115.000 2 6. 26b 0.03607 15.3477 173.642 4710.5 4 86 2 .

80. 297 33.17 55.78 13*4 9 120. 000 25.816 0. 03673 14. 3655 157.798 4987.1 5142.1 82.684 32.81 56.36 1300

125.000 25.355 0 . 03944 13.4231 142.677 5267.0 5424.8 84.996 32.42 56. 92 1250

130.000 24. 876 0. 04020 12.5160 128.276 5550.4 5711.2 87.245 32.07 57.72 1200

135.000 24.379 0.04102 11.O40Q 114.580 5837.9 6002.0 69.440 31.81 50.6? 1148

14U.000 23. 859 0. 04191 10.7908 101.547 6130.6 6298.2 91.595 31.67 59.87 1094

145.000 23.315 0.04289 9.9647 89.128 6429.5 6601.0 93.720 31.58 61.30 1038

150.000 22. 739 0.04398 9. 1571 77.271 6735.7 6911.6 95. 826 31. 49 62.9 7 981

155.000 22.127 0.04519 8.3635 65.917 7050.4 7231.2 97.921 31.28 04.87 923

160.000 21.467 0.04658 7.5778 55.017 7374.7 7561.0 100.015 30.89 67.13 863

165.000 20.743 0.04821 6.7922 44.52? 7710.7 790 3.6 102.123 3 0.32 70.05 801

170.000 19.930 0.05018 5.9949 34.415 8063.2 8263.9 104. 274 29.72 74.41 733

175.000 16.979 0. 05269 5.1661 24.656 8442.5 865 3 .

10b. 528 29.87 32.46 651

ISO. 000 17. 779 0 • 05625 4.2634 15.211 8874.4 9099.4 109. 041 30.14 98 . 19 556

165.000 15.920 0.06281 3, 1361 5.815 9440 .

9691.3 112.281 31.67 155.12 421

186.089 15.225 0 . 0 o 560 2.7846 3.586 9620.8 9883.5 113.317 32.84 206 . *»3 375

18o. 089 5.393 0.18541 0. 7287 1.507 11950.12691.7 128.411 37.00 2o2. 46 258

190.000 4.436 0.22544 0,5443 3.687 12393.0 13294.7 131. 622 31.86 109.46 281

195.000 3.891 0 . 25698 0.4527 5.455 12721.7 13749.7 133.987 30.0 3 78.40 298

200.000 3. 546 0.23202 0.3984 6.851 12979.0 i^lO? .0 135.797 29. 09 65.94 311

2 05 . 000 3.292 0. 30381 0 . 3603 8.050 13202.

14418.0 137.333 28.49 59.0 1 322

210.000 3.090 0. 32360 0.3314 9.121 13406.8 14701.2 138.698 28. 07 5 4.55 332

215.000 2.924 0. 34201 0.30 82 10.102 13597.6 14965.7 139.943 27.78 51.42 341 220.000 2. 783 0 . 35 938 0.2890 11.015 13779.2 15216,8 141.098 27.57 49. 11 350

225. 000 2. 660 0.37596 0. 2728 11.874 13953.9 15457.7 142.181 27.41 *7 .34 350

230.000 2.552 0.39190 0. 2588 12.690 14123.2 15690.8 143.205 27.30 •5.95 3 6 5 235. 000 2.455 0.43731 Q. 2465 13.470 14288.4 15917.6 144. 181 27. 23 4.83 372

240.000 2.368 0.42229 0.2357 14.219 14450 .

16139.4 145. 115 27.20 43.92 378

245.000 2.289 0 .43689 0.2260 14.942 14609.5 16357.1 146.012 27.18 3.1? 385

250.000 2.216 0.45117 0.2172 15.643 14766.7 1657 1.3 146.878 27.19 *2. &- 391

255. 000 2. 15 0 0.45517 0.2093 16.324 14922.1 16732.

147.715 27.23 2.0 3 39o

2o0 .000 2. 088 0.47892 0. 2020 16.988 15076.

16991.6 148.527 27.27 1.60 4 02 265.000 2.031 0.49245 0.1953 17.636 15229.

17198.9 149.316 27.34 1.25 4 u 7 270.000 1.977 0.50579 0.1892 18.271 15381.2 17404.3 150.084 27.4? 0.95 12 275.000 1. 927 0.51894 0. 1835 18.892 15532.7 17608.5 150.833 27.52 40.71 417

260.000 1.680 0.53195 0.1782 19.503 15683.6 17811.6 151.565 27.63 0.52 4 22 265.000 1.836 0 « 54480 0.1732 20.103 15834.6 18013.8 152.281 27.75 40.37 427

290.000 1.794 0.55752 0.1666 20.693 15985.3 18215.4 152.982 27.88 0-26 432

295.000 1.754 0.57013 0. 1642 21.275 16135.9 18416.4 153.670 28. 02 40.10 4 3 o 300.000 1. 716 0 .53262 0. loQi 21.848 16286.7 18617.2 154. 345 28.18 0.13 4^0

310.000 1.647 0.60730 0.1526 22.974 16589.

19018.

155. 660 28.51 0 . 1 J 44 4 320.000 1.583 0.65162 0.1458 24.074 16893.0 19419.5 15o. 934 28. 89 0.16 457

330.000 1. 52 5 0 . 65565 0.1397 25.151 17199.2 19821.8 158. 171 29.29 40.30 464

340.000 1.4 72 0.67940 0.1342 26.206 17508.1 20225.7 159.377 29.72 0.50 72 350.000 1.423 0.70291 0.1291 27 . 248‘ 17820.3 20631.9 160 • 555 30.17 0 . 75 47 9 360.000 1.377 0.72622 0.1244 28.273 18136.

21040.9 161. 707 30.65 1.05 400

370.000 1.335 0.74934 0.1201 29.284 18455.6 21453.0 162.836 31.15 41.38 492

360.000 1.295 0. 77229 0.1161 30.281 18779.5 2 186 8.6 163.944 31.66 1.75 499

390.000 1.256 0.79509 0. 1124 31.268 19107.8 22288.1 165.034 32.19 2.15 505

400.000 1.223 0. 81775 0. 1090 32.244 19440.8 22711.7 166-106 32. 73 42. 57 511

420.000 1.159 0 . So 27 0 0.1027 34.169 20121.3 23572.1 168.205 33.83 3.48 523

440.000 1. 102 0.90724 0 .0972 35.063 20822.

24451.2 170.250 34.96 4 .44 53?

4o 0 .0 00 1. 051 0.95142 0,09 22 37.929 21544.

25350.0 172. 247 36- 10 5.44 54o

460.000 1.005 0. 33630 0.0878 39.772 22287.7 26268.9 174.203 37.24 4 6.46 5 5o 500.000 U. 963 1.03892 0.0838 41,596 23052.8 272J8.5 176.120 38.38 7.49 5 6 o

163
METHANE ISOBAR AT P » 44.0 BAR

T OEM VOL DP/OT OP/DO E H S CV CP M 0EG K HOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

BiefiOl 28.234 0.03542 20.5829 255.902 3485.7 3641.5 68.062 33.42 52.46 1583

95.060 27.971 0.03575 19.7873 244.040 3646.2 3803.5 69.677 33.33 52.61 1553

100.000 27.562 0.03626 18.6006 226.041 3901.6 4061.4 72.604 33.42 53.56 1503

105.000 27.147 0.03684 17.4731 208.408 4164.2 4326.3 75.237 33.50 54.37 1452

110. 900 26. 723 0.03742 16.4001 191.296 4432.3 4597.0 77.763 33.43 55.09 1402

115.000 26.289 0.03804 15.3768 174.614 4704.6 4672.1 80.246 33.20 55.71 1352

120.000 25.843 0.03670 14.3981 159.017 4960.6 5151.0 62.629 32.85 56.27 1303

125.000 25.383 0.03940 13.4593 143.940 5259.9 5433.3 84.936 32.45 56.67 1254

130. 000 24. 907 0. 04015 12. 5561 129.585 5542.4 5719.1 87.162 32.10 57.60 1204

135.000 24.413 0.04096 11.6843 115.933 5829.0 6009.2 89.372 31.95 58.52 1152

140.000 23.898 0.0^184 10.8398 102.949 6120.5 6304.6 91.521 31.70 59.68 1099

145.000 23.359 0.04281 10.0190 90.586 6416.0 6606.3 93.639 31.61 61. 06 1044

150. 000 22.791 0. 04388 9.2176 78.791 6722.5 6915.6 95.735 31.52 62.66 988

155.000 22.167 0.04507 8.4314 67.512 7035.0 7233.3 97.616 31.31 64.46 931

160.000 21. 538 0.04643 7.6550 56.701 7356.5 7560.7 99.897 30.91 66.56 072

165.000 20.831 0.04001 6.8815 46.319 7668.6 7899.8 101. 964 30.33 69.21 812

170.000 20.043 0.04989 6.1013 36.340 6035.2 8254.8 104.103 29.71 73.06 746

175.000 19. 134 0.05226 5.2969 26.756 8405.0 8635.0 106.304 29.63 79.98 669

160.000 18.023 0.05548 4.4451 17.574 8817.9 9062.0 108.709 29.98 92.26 581

185.000 16.474 0.06070 3.4627 6.752 9320.2 9567.3 111.566 30.87 124.25 469

189.136 13.551 0.07 380 2.1436 1.006 10062.4 10367.1 115.652 37.03 507.54 293

189.136 6.839 0.14621 0.9641 0.566 11612.8 12256.1 125.737 42.92 734. 23 246

190.000 6. 056 0. 16511 0.8206 1.445 11884.3 1261(1.6 127.606 36.62 278.05 261

195.000 4.745 0.21073 0.5624 3.966 12453.6 133ro.8 131.616 31.44 105.50 286

200.000 4. 188 0.23890 0.4902 5.644 12778.7 13629.5 133.890 29.91 78.48 304

205.000 3.823 0.26156 0.4332 7.016 13038.1 14189.0 135.666 29.06 66.58 317

210.000 3.552 0.28152 0.3926 6.210 13264.8 14503.5 137.162 28.51 59.75 327

215.000 3.337 0.29969 0.3613 9.265 13471.7 14790.4 138.532 28.13 55.29 337 220.000 3.159 0.31661 0.3363 10.273 13665.5 15058.5 139.765 27.86 52.13 346

225. OQO 3.007 0. 33256 0.3155 11.195 13649.7 15313.1 140.909 27.66 49. 79 354

230.000 2.675 0.34783 0.2978 12.064 14026.6 15557.3 141.963 27.52 *7.98 362

235.000 2.759 0 . 3o 249 0.2826 12.390 14198.5 15793.5 142.999 27.42 46.55 369

240.000 2.655 0. 37667 0.2692 13.660 14366.0 16023.3 143.967 27.36 45.41 376

245.000 2. 561 0. 39044 0.2574 14.440 14530.0 16248.0 144.693 27.34 44.4 7 383

250.000 2.476 0.40386 0.2468 15.173 14691.3 16468.3 145.783 27.33 43.70 389

255.000 2.398 0.41698 0.2373 15.864 14650.5 16665.2 146.642 27.35 43.07 395

260.000 2.326 0.42984 0.2286 16.574 15007.9 16699.2 147.473 27.39 42.54 401

265.000 2.260 0.44247 0.2206 17.247 15163.6 17110.7 148.279 27.45 42.09 406

270.000 2.198 0.45490 0.2134 17.904 15316.7 17320.2 149.062 27.52 41.73 411

275.000 2.141 0.46714 0.2066 18.547 15472.7 17528.1 149.625 27.61 41.43 41b

280.000 2.067 0.4’922 0.2004 19.176 15626.1 17734.6 150.570 27.72 41.18 421

285.000 2.036 0.49114 0.1946 19.795 15779.0 17940.0 151.297 27.83 40.98 426

290.000 1.968 0 . 5 J 293 0.1892 20.402 15931.6 18144.5 152.006 27.96 40.83 431

295.000 1.943 0.51460 0.1841 21.000 16064.1 183*8.

4

152.705 28.10 *0.71 435

300.000 1.901 0.52616 0. 1793 21.589 16236.6 18551.7 153. 386 28.25 40.62 440

310.000 1.622 0.54895 0.1706 22.742 16542.0 18957.4 154.719 28.58 40.54 448

320.000 1.750 0.57140 0.1629 23.666 16648.7 19362.9 156.006 28.95 40.56 457

330.000 1.685 0.59353 0.1558 24.966 17157.4 19768.9 157.255 29.35 40.65 464

340.000 1.625 0.61539 0.1495 26.044 17468.5 20176.2 158.471 29.77 40.82 472

350.000 1.570 0.63701 0.1437 27.183 17782.6 20585.5 159.658 30.23 41.04 479

360.000 1.519 0.65642 0.1364 28.145 18100.2 20997.2 160.816 30.70 *1.32 48b

370.000 1. 471 0.67964 0.1335 29.172 18421.5 21411.9 161.954 31.20 *1.63 493

380.000 1.42 7 0.70069 0.1269 30.165 18747.0 21630.0 163.069 31.71 41.98 499

390.000 1.386 0.72159 0.1248 31.165 19076.7 22251.7 164. 164 32.23 42. 37 505

400.000 1.347 0.74235 0.1208 32.174 19411.0 22677.4 165.242 32.77 *2.77 512

420.000 1. 276 0. 78352 0. 1136 34.122 20094.1 23541.5 167.350 33.87 43.65 524

440.000 1.213 0.82426 0. 1076 36.036 20797.2 24423.9 169.402 35.00 44.59 535

460.000 1.157 0.66465 0.1020 37.920 21521.1 25325.6 171.40 6 36.14 45.58 546

480.000 1.105 0.90474 0.0971 39.779 22266.3 26247.2 173.367 37.28 *6.59 557 500.000 1. 059 0.94456 0.0926 41.617 23032.9 27189.1 175.289 38.41 47.61 567

166
METHANE ISOBAR AT P « 46.0 BAR

T DE.N VOL OP/OT DP/ DO E H S CV CP w OEG K MOL/L L/MOL 8AR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/NOL/K M/SEC

91.902 26.241 0.03541 20.5702 256.413 3487,0 3656.9 68.079 33.44 52.46 1583

99.000 27.987 0.03573 19. 3023 244.956 3642.4 3813.9 69. 835 33. 36 52.78 1554

100.000 27.580 0.03626 18.6193 227.033 3897.6 4071.6 72.561 33.45 53.52 1505

105.000 27.166 0.03661 17.4951 209.466 4159.6 4336.3 75. 192 33.53 54. 32 145,

110.000 26.744 0.03739 16.4255 192.413 4427.2 4606.7 77.736 33.47 55.0 3 14 0,

115.000 26. 312 0. 03801 15.4055 175.980 4699.1 4881.5 80.196 33. 23 55.64 1355

120.000 25.668 0.03866 14.4303 160.230 4974.5 5160.0 82.575 32.88 56.19 1306

125.000 25.411 0.03935 13.4952 145.196 5252.9 5441,8 84.880 32.49 56.77 1258

130.000 24.936 0.04010 12.5958 130,684 5534.6 5727.1 87.120 32.14 57.47 1208

135.000 24.446 0. 04090 11.7280 117.277 5820.2 6016.5 89.305 31.88 58.37 1157

140.000 23. 937 0.04178 10.8881 104.340 6110.5 6311.0 91.448 31.73 59.49 110,

145.000 23.403 0.04273 10.0724 92.030 6406.7 6611.8 93.558 31.65 60.83 1050

150.000 22.641 0.04 378 9.2770 80.296 6709.6 6919.7 95.646 31.55 62.36 995

155.000 22.245 0.04495 8.4978 69.063 7020.0 7235.8 97.718 31.33 64.07 938

160.000 21.606 0.04628 7.7300 58.359 7338.8 7560.9 99.782 30.93 66.02 881

165.000 20.916 0. 04781 6.9677 48.076 766?o3 7896.8 101.849 30. 35 68.44 822

170.000 20. 150 0. 04963 6.2028 36.219 8008.7 8246.9 103.939 29.71 71.86 759

175.000 19. 278 0.05187 5.4230 28.788 8370.2 8619.2 106.095 29.79 77.89 685

160.000 18.237 0. 05483 4.6075 19.809 8767.8 9031.0 108.414 29.86 87.86 603

165.000 16.873 0.05927 3.7110 11.326 9231.4 9515.9 111. 070 30.44 109.44 504

190.000 14.512 0.06891 2.5584 3.278 9897.3 10228.1 114.863 33.01 213. 16 363

195.000 6.043 0.15548 0. 7927 2.317 12063.4 12857.7 128.548 33.82 178.64 276

200.000 4.989 0 . 20044 0.6112 4.384 12535.6 13497.7 131.792 30.97 99.44 29o

205.000 4.441 0.22517 0.5220 5.956 12850.9 13931.7 133.936 29.74 77.29 311

210.000 4.069 0.24576 0.4640 7.286 13108.9 14288.5 135.657 29.00 66.49 323

215.000 3.788 0.26400 0.4216 8.462 13336.4 14603.6 137.140 28.51 60.01 333

220.000 3.563 0.26069 0. 3690 9.531 13544.9 14892.2 138.467 28.17 55.69 3,3

225.000 3.375 0.29627 0.3625 10.518 13740.4 15162.5 139.682 27.92 52.59 351

230.000 3.215 0.31101 0. 3403 11.443 13926.5 15419.3 140.811 27.74 5 0.26 359

235.000 3.076 0. 32509 0.3215 12.317 14105.6 15666.0 141. 872 27.62 48.46 367

240.000 2.953 0.33863 0. 3052 13.149 14279.2 15904.6 142.877 27.54 47.03 37,

245.000 2. 843 0. 35173 0. 2909 13.946 14448.5 16136.8 143. 834 27.49 45.88 381

250.000 2.744 0. 36445 0.2782 14.712 14614.4 16363.7 144.751 27.47 44. 94 387

255.000 2 . b54 0 . 37686 0.2668 15.452 14777.5 lt>586.4 145.633 27.48 44. 16 393

260.000 2.571 0. 38899 0.2565 16.170 14938.5 16805.6 146.484 27.51 *3.52 399

265.000 2.495 0.40087 0. 2472 16.868 15097.6 17021.8 147.308 27.56 42.98 405

270.000 2.424 0.41255 0.2366 17.547 15255.3 17235.6 148.107 27.62 42.54 410

275.000 2.356 0.42403 0.2308 18.211 15412.0 17447.3 148. 684 27.71 42.17 416

260.000 2.297 0.43534 0.2235 16.861 15567.7 17657.3 149.641 27.80 ,1.86 421

265.000 2. 240 0.44649 0.2166 19-497 15722.8 17866.0 150.380 27.92 41.61 426

290.000 2. 166 0.45751 0.2105 20.1 22 15877.5 18073.6 151.102 28.04 41.41 430

295.000 2. 135 0.46840 0.2047 20.735 16031.9 18280.2 151.808 28.18 41.25 435

300.000 2.087 0.47917 0.1992 21.339 16186.1 18486.1 152. 501 28. 32 41.13 440

310.000 1. 998 0. 50040 0.1852 22.520 16494.7 18896.6 153.847 28.65 40.99 448

320.000 1.918 0.52127 0.1803 23.669 16804.2 19306.3 155. 147 29.01 40.96 456

330.000 1.646 0.54182 0.1724 24.791 17115.3 19716.1 156.408 29.40 41.0 1 46,

340.000 1.779 0 . 5o 21

0.1651 25.890 17428.7 20126.8 157.634 29.83 41.14 472

350.000 1.718 0.58214 0.1586 26.967 17744.9 20539.2 158.830 30.28 41.34 479

360.000 1.661 0.60197 0.1526 26.026 18064.4 20953.8 159.998 30.75 ,1.59 486

370.000 1.609 0.62161 0.1471 29.066 18387.4 21371.1 161.141 31.24 41.88 493

360.000 1.560 0.64106 0. 1420 30.096 18714.4 21791.6 162.262 31.75 42.21 499

390.000 1.514 0. j6039 0.1373 31.109 19045.6 22215.5 163. 363 32.27 42.58 5 Oo 400.000 1.472 0.67957 0.1329 32.111 19381.3 22643.3 164.446 32.81 42.97 512

420.000 1.394 0.71757 0.1250 34.082 20066. a 23511.1 166. 563 33.91 43.83 52,

440.000 1.324 0.75515 0.1161 36.015 20772.1 24396.8 168.623 35.03 44.75 535

460.000 1.262 0.79238 0.1119 37.917 21496.0 25301.4 170.634 36.17 45.71 547

460.000 1.206 0.82931 0.1064 39,791 22244.9 26225.6 172.600 37.31 46.71 557

500.000 1.155 0. 86598 0. 1015 41.643 23013.

27169.8 174. 527 38.44 47.72 56 6

167
HE THANE ISOBAR ATP* 52.0 BAR

? DEN VOL OP/DT 0P/OD E H S CV CP H DEG & NOL/L L/MOL 0AR/K BAR- L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

92.0 011 28.2*9 0.035*0 20.5576 256.922 3*88.3 3672.* 68.095 33. *7 52.4* 1584

95.000 28.003 0.03521 19.8171 2*5.867 3638.6 382*.

3

69.79* 33. *0 52.75 1556

100.000 22.598 0.0362* 18.6377 226.020 3893.* *081.8 72.518 33. *8 53. *8 1507

105. 800 22.185 0.03628 17.5170 210.519 *155.0 *3*6.3 75.1*7 33.56 54.27 1*57

110.000 26.265 0.03236 16. *507 193.523 **22.1 *616.* 77.688 33.50 54.97 1*07

115.000 26.335 0.03792 15. *3*1 177.1*0 *693.* *890.9 80.1*5 33.27 55-57 1358

120.000 25.893 0. 03662 1*.*622 161.636 *968.2 5169.0 82.521 32.91 56.10 1310

125.000 25. *36 0.03931 13.5306 1*6. **6 52*5.9 5*50.* 8*. 823 32.52 56.67 1261

130.090 2*. 968 0.0*005 12.63*9 132.176 5526.8 5735.1 87.058 32.17 57.36 1212

135.000 2*. *82 0 . 0*085 11.7712 118.612 5811.* 6023.9 89.239 31.91 58.23 1161

1*0.009 23.925 0.0*121 10.9358 105.722 6100.7 6317.6 91.375 31.76 59.31 1109

1*5.000 23. **6 0.0*265 10.1250 93. *63 6395.5 6617.3 93. *79 31.68 60.61 1056

150.000 22.890 0.0*369 9.3352 61.766 6696.9 692*.

0

95.558 31.58 62.08 1001

155.000 22.303 0 • 0**8* 8.5627 70.6** 7005.3 7238.5 97.619 31.36 63.70 946

160.000 21.625 0.0*61* 7.8031 59.99* 7321.5 7561.* 99.670 30.96 65.52 890

165.000 20.992 0.0*762 7.0512 *9.802 76*6.7 789*.

3

101.718 30.36 67.72 832

120.000 20.252 0.0*938 6.3000 *0.05* 7983.3 82*0.1 103.703 29.71 70.78 771

125.000 19. *13 0. 05151 5.5399 30.755 6337.6 8605.* 105.898 29.77 76.10 700

ISO. 000 18.429 0.05*26 *.7555 21.9*5 8722.6 900*.

8

108.1*7 29.77 84.39 623

185.000 12.19* 0.05816 3. 9182 13.697 9159.1 9*61.5 110.6*9 30.17 100.31 533

190.000 15.381 0.06501 2.9539 6.126 9713.* 10051.5 113.793 31.50 145.88 *21

195.000 9. 3*1 0.10706 1. 3*33 0.697 1118$. 1 117*1.8 122.5*0 38.78 617.65 263

200.000 6.062 0.16*82 0.7822 3.111 12221.7 13078.8 129.333 32.38 139.23 289

205.000 5. 181 0. 19302 0.6332 *.896 12633.0 13636.7 132.090 30.53 93.05 305

210.000 *.656 0.21*78 0.5*87 6.365 12935.6 1*052.* 134.09* 29.5* 75.35 318

215. 000 *. 285 0. 23337 0 * *911 7.6** 13189.9 1**03.* 135.7*7 28.92 65.85 329

220.000 *. 000 0.25003 0. **81 8.79* 13*16.6 1*716.7 137.188 28. *9 59.89 339

225.000 3.268 0 . 2o537 0 . *1*3 9.8*8 13625.5 15005.* 138. *85 28.19 55.80 3*9

230.000 3.525 0.27975 0.3867 10.629 13822.0 15276.6 139.678 27.97 52.82 357

235.000 3. *09 0.29338 0. 3636 11.752 1*009.3 1553*.

8

1*0^788 27.81 50.57 365

2*0.000 3.26* 0.306*2 0.3*38 12.626 1*169.7 15783.1 1*1.83* 27.71 *8.80 372

2*5.000 3. 135 0. 31897 0. 3266 13. *60 1*36*.

6

16023.5 1*2.825 27.6* 47.40 379

250.000 3.020 0.33113 0.3115 1*.260 1*535.7 16257.5 1*3.771 27.61 *6.26 386

255.000 2.916 0.3.29* 0.2980 15.031 1*703.1 16*86.* 1*4.677 27.61 45.32 392

260.000 2.821 0. 35**6 0.2859 15.776 1*867.9 16711.0 1*5.550 27.62 *4.55 399

265.000 2.23* 0. 36572 0.2750 16. *98 15030.* 16932.2 1*6.392 27.66 43.91 *04

220.000 * 2.65* 0. 37676 0.2650 17.201 15191.2 17150.3 1*7.208 27.72 *3.38 *10

225.000 2.580 0.38760 0.2559 17.866 15350.6 17366.1 1*7.999 27.80 42.93 *15

280.000 2.511 0.39826 0.2*76 18.555 15508.8 17579.8 1*8.769 27.89 42.56 *20

265.000 2 • **6 0 • *0877 0. 2398 19.210 15666.2 17791.8 1*9.520 28.00 *2.26 *25

290.000 2.386 0 . *1 91

3

0.2326 19.651 15823.0 18002.* 150.253 28.12 *2.01 *30

295.000 2.329 0 . *2936 0.2260 20. *81 15979.3 18212.0 150.969 28.25 41.81 *35

300.000 2.225 0 • *39*7 0.2197 21.100 16135.3 18*20.6 151.670 28.39 *1.65 *39

310.000 2. 122 0 .*5938 0.208* 22.308 16**7.

2

18835.9 153.032 28.71 *1.4* *48

320.000 2. 086 0 . *7891 0.1983 23. *62 16759.6 192*9.9 154.3*6 29.07 41.36 *5o

330.000 2.008 0 . *381 3 0.1893 2*. 626 17073.2 19663.5 155.619 29. *6 41.37 *64

3*0.000 1.93* 0.51707 0.1812 25.7** 17368.9 20077.6 156.856 29.88 41.47 472

350.000 1.866 0.53577 0.1738 26.8*0 17707.2 20*93.1 158.060 30.33 *1.64 479

360.000 1.60* 0.55*25 0. 1671 27.916 18028.5 20910.6 159.236 30.80 41.86 *86

320.000 1.2*2 0.57255 0.1609 28.973 18353.3 21330.5 160.386 31.29 42.13 *93

380.000 1.693 0.59068 0.1553 30.015 18681.9 21753.* 161.51* 31.80 *2.45 500

390.000 1.6*3 0.60865 0.1500 31.0*2 1901*.

6

22179.6 162.621 32.32 42.79 506

*00.000 1.596 0.626*9 0.1*52 32.055 19351.6 22609.* 163.709 32.85 43.17 512

*20.000 1.511 0.66181 0.136* 3*. 0*8 20039.6 23*81.0 165.835 33.95 44.00 524

**0.000 1* *35 0.69670 0. 1287 36.001 207*7.0 2*369.9 167.903 35.07 44.90 536

*60.000 1.368 0.73125 0. 1219 37.919 21*7*.

9

25277.* 169.?20 36.21 *5 • 85 5*7

*80.000 1.306 0.76550 0.1159 39.809 22223.5 2620*.

2

171.892 37.3* *6.83 558

500.000 1.251 0.79950 0. 110* *1.67* 22993.3 27150.7 173.82* 38. *7 *7.83 568

168
METHANE ISOBAR AT P = 56.0 BAR

T DEN VOL OP/QT DP/DD E H S CV CP M DEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

92.105 23.257 0.03539 20.545Q 257.429 3489.7 3687.8 68. 112 33-50 52.42 158*

95.000 28.019 0.03569 19.8316 246.772 3634.8 3834.7 69.75 3 33.43 • 52.72 1557

100.000 27.615 0.03621 18.6559 229.002 3889.2 4092.0 72.475 33.52 53.45 1509

105.000 27.204 0.01676 17.5386 211.566 4150.4 4356.3 75.102 33.60 54.23 1*59

110.000 26.786 0.03733 16.4757 194.627 4417.

4626.1 77.641 33.53 54.92 1410

115.000 26.357 0.03794 15.4623 178.295 4687.9 4900.3 80.095 33.30 55.50 1361

120.000 25.913 0.03858 14.4938 162.637 4962.0 5178.1 82.468 32.95 56.02 1313

125.000 25.465 0.01927 13.5656 147.689 5239.1 5459.0 84.766 32.55 56.57 1265

130.000 24.999 0. 0*000 12.6736 133.461 5519.1 5743.2 86.997 32.20 57.24 1216

135.000 24.515 0.04079 11.8139 119.939 5802.9 603 1.3 89.173 31.95 53.09 1166

1*0.000 24.013 0 . 04164 10.9827 107.093 6091.0 6324.2 91.304 31.80 59.14 1114

145.000 23.469 0.04257 10.1767 94.883 6384.6 6623.0 93.400 31.71 6 0.40 1061

150.000 22. 939 0. 04359 9. 3924 83.262 6604 .6928.5 95.471 31.61 61.81 1007

155.000 22.359 0. 04473 8.6263 72.183 6990.9 7241.4 97.523 31.39 63.35 953

160.000 21.741 0.0*600 7.8744 61.605 7304.8 7562.4 99.561 30.98 65.05 890

165.000 21. 076 0.04745 7.1321 51.499 7626.8 7892.5 101.592 30.38 67.07 8*2

170.000 20.350 0. 0491* 6. 3934 41.850 7959.

3234.2 103.632 29.72 69.81 783

175.000 19.539 0.05113 5.6506 32.669 8306.8 0593.4 105.712 29.75 7 4.55 71*

ISO. 000 18.603 0.05 37 5 4.8921 23.999 8681.2 8982.2 10 7.902 29.71 81.58 6*1

135.000 17.464 0.05726 4. 0989 15.925 9097.2 9417.8 110.288 29.90 93.97 553

190.000 15.928 0. 0©278 3. 2328 8.600 9594.4 9946.0 113.103 30.83 121.84 460

195.000 13. 127 0.07618 2.1622 2.301 10354.3 10780.9 117.434 33.61 263.49 335

200.000 7.705 0. 12978 1.0528 1.896 11776,1 12502.9 126. 158 34.18 231. 11 283

205.000 6.097 0.16402 0.7770 3.887 12372.9 13291.4 130. 058 31.44 117.10 300

210.000 5. 333 0.13750 0.6504 5.477 12740.8 13790.8 132.466 30.13 07.15 314

215.000 4.333 0.20670 0.5711 6.849 13030.3 14187.9 13*. 335 29.35 73.09 326

220.000 4.474 0.22350 0.5147 8.075 13279.6 14531.2 135.914 28.83 64.88 337

225. 000 4.189 0. 23874 0.4717 9.193 13504.4 14841.3 137.309 28.46 59.50 346

230.000 3.955 0. 25286 0.4374 10.229 13712.8 15128.8 138.572 28.20 55.70 3 5 5 235.000 3.757 0.2)615 0.4091 11.199 13909.5 15400.0 139. 739 28.0 1 52.89 363

2*0.000 3.537 0.27879 0.3852 12.115 14097.6 15658.8 140.829 27. 88 50.73 371

245.000 3. 433 0.29090 0. 3646 12.986 14279.0 15908.0 141.857 27.80 49.03 370

250.000 3.305 0.30258 0.3467 13.819 14455.2 16149.7 142. 833 27.75 47.66 385

255.000 3.136 0.31389 0.3309 14.619 14627.3 16385.1 143. 765 27.73 *6.55 391

260.000 3.078 0.32489 0.3168 15.391 14796.1 16615.5 144.660 27-74 *5.64 397

265.000 2.979 0. 31563 0.3041 16.139 14962.2 16841.7 145.522 27.77 44.88 403

270.000 2.839 0.3*613 0.2926 16.864 15126.2 17064.5 146.355 27.82 44.25 409

275.000 2.806 0.35643 0.2822 17.571 15288.4 17284.4 147.162 27.89 *3.72 41*

230.000 2.728 0 * 36654 0.2725 18.259 15449.17501.9 147. 946 27.98 43-28 *20

235.000 2.656 0.37649 0.2637 16.932 15609.1 17717.4 148.708 28,08 42.92 *25

290.000 2.589 0 . 33629 0.2555 19.590 15768.0 17931.2 149.452 28.20 42.62 430

295.000 2.526 0.33595 0.2479 20.236 15926.3 18143.7 150.179 28.32 *2.37 4 3 * 300.000 2 • 46 6 0 . 40550 0.2409 20.870 16084.

18355.0 150.889 28.47 *2.18 439

310.000 2.357 0.42427 0.2280 22.105 16399.4 18775.3 152.267 28.78 *1.91 4*8

320.000 2.259 0 • .*266 0.2167 23.303 16714.7 19193.6 153.595 29.13 *1. 77 4 5 o 330.000 2.170 0 . 46 0 73 0.2066 24.469 17031.0 19611.1 154.880 29.52 *1.7* *0*

340.000 2. 090 0.47852 0.1975 25.607 17349.0 20028.7 156.127 29.94 41.80 4 72 350.000 2. 016 0.43607 0.1893 26.721 17669.4 20447.3 157.340 30.38 41.94 473

360.000 1. 948 0.51340 0.1819 27.813 17992.6 20867.6 150. 524 30.85 *2.13 487

370.000 1.885 0.53055 0.1750 28.686 18319.1 21290.2 159.682 31. 34 *2.38 493

330.000 1.826 0.5*752 0.1688 29.941 18649.3 21715.4 160.816 31.84 *2.68 503

390.000 1.772 0.56435 0.1630 30.981 18983.5 22143.8 161.929 32.36 *3.0 1 507

400.000 1.721 0.58103 0.1576 32.007 19321.9 22575.7 163.022 32.89 *3.37 513

420.000 1.629 0.6140* 0.1479 34.021 20012.4 23451.0 165. 157 33.99 **•17 525

440.000 1.546 0 • 64664 0.1395 35.993 20722.0 24343.2 167.232 35.11 *5.06 537

460. 000 1.473 0 . 67 8S9 0.1321 37.92® 21451.8 25253.6 169.255 36.24 *5.99 548

430.000 1.40 7 0.71084 0.1254 39.832 22202.2 26182.9 171.233 37.38 *6.95 558

500.000 1.34 7 0.7*254 0. 1195 41.709 22973.6 27131.8 173. 170 38. 50 *7.9* 569

169
METHANE IS08AR ATP* 60.0 SAR

T OEN VOL DP/OT OP/DO E H S CV CP

DEG K MOL/L L/MOl BAR/K SAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

92.206 28.265 0.03538 20.5325 257.933 3491.0 3703.3 68.129 33.53 52.40 1585

95.000 28.036 0.03567 19.8463 247.671 3631.0 3845.1 69.712 33.46 52.69 1559

100.000 27. 632 0. 03619 18.6740 229.979 3685.1 4102.3 72.432 33.55 53.41 1511

105.000 27. 223 0.03673 17.5601 212.609 4145.9 4366.3 75.057 33.63 54.18 1461

110.000 26.806 0.03731 16.5004 195.726 4412.0 4635.9 77.594 33.57 54.86 1412

115.000 26.380 0.03791 15.4903 179.444 4682.3 4909.8 80.045 33.33 55.43 1364

120.000 25- 942 0.03855 14.5251 163.631 4955.9 5167.2 82.415 32.98 55.94 1316

125.000 25.492 0.03923 13.6003 146.926 5232.2 5467.6 84.710 32.59 56.48 1268

1 JO. 000 25. 028 0.03995 12.7119 134.738 5511.6 5751.3 86.937 32.24 57.13 1220

135.000 24.548 0.0*074 11.8560 121.257 5794.4 6036.6 39. 106 31.96 57.95 1170

140. 000 24. 050 0.04158 11.0290 106.455 6081.5 6331.0 91.233 31.83 58.98 1119

145.000 23.530 0.0*250 10.2277 96.292 6373.9 6628.8 93.323 31.74 60.19 1067

150.000 22.986 0.0*350 9.4486 64.724 6672.1 6933.2 95.386 31.64 61.55 1014

155.000 22.413 0.0*462 8.6886 73.705 6976.9 7244.6 97.428 31.42 63.02 96 0 160.000 21.805 0.04586 7.9440 63.196 7268.5 7563.6 99.454 31.00 64.61 906

165.000 21. 153 0.04727 7.2106 53.169 7607.5 7891.1 101.469 30.40 66.46 851

170.000 20.444 0.0*891 6.4833 43.611 7935.7 8229.2 103.467 29.72 68.93 794

175.000 19.658 0.05087 5.7559 34.535 8277.6 8562.9 105.535 29.73 73.18 728

ISO. 000 18.763 0.05330 5.0194 25.964 8643.0 8962.7 107.675 29.66 79.23 658

195.000 17.700 0.05650 4.2609 16.048 9042.6 9381.6 109.969 29.64 39.24 580

190.000 16* 340 0. 06120 3.4567 10.878 9503.

0

9870.2 112.574 30.43 106.68 492

195.000 14.30 7 0. 06990 2.5646 4.731 10102.9 10522.3 115.959 31.93 164.38 390

200.000 10.137 0.09864 1.4900 1.661 11183.9 11775.7 122.296 34.12 291.19 299

205.000 7.272 0. 13751 ' 0. 9696 2.982 12055.3 12880.3 127.759 32.39 154.61 298

210.000 6. 125 0. 16325 0.7742 4.659 12520.3 13499.9 130.747 30.76 102.76 312

215.000 5.457 0.18326 0.6641 6.103 12656.0 13955.6 132. 893 29.80 81.98 323

220. 000 4.992 0.20032 0.5900 7.391 13133.0 14335.0 134.638 29.17 70.75 33*

22 5.000 4.639 0.21554 0.5353 8.565 13376.7 14669.9 136.143 28.74 63.72 34*

230.000 4. 357 0.22950 0.4928 9.650 13598.6 14975.6 137.488 28.43 58.92 353

235.000 4. 123 0.24252 0.4583 10.664 13606.2 15261.3 138.716 26.21 55.4* 361

240.000 3. 924 0. 23483 0.4296 11.619 14002.6 15531.6 139.855 28.06 52.62 369

245.000 3.751 0.26658 0.4052 12.525 14191.0 15790.4 140.922 27.95 50.78 377

250.000 3.599 0. 27785 0. 3841 13.390 14373.0 16040.2 141.931 27.89 49.16 384

255.000 3. 463 0.28874 0.3657 14.220 14550.1 16282.5 142.691 27.86 47.85 390

260.000 3.341 0. 29931 0.3493 15.019 14723.2 16519.0 143.809 27.66 *6.78 396

265.000 3. 230 0. 30959 0.3346 15.791 14693.

1

16750.6 144.692 27.88 45.89 403

270.000 3.129 0.31963 0.3214 16.539 15060.4 16976.2 145.543 27.92 45.15 408

275.000 3. 035 0. 32 946 0.3094 17.265 15225.7 17202.4 146.365 27.99 44.5* 414

200.000 2.949 0. 33909 0.2985 17.973 15369.2 17423.8 147.163 28.07 44.03 419

295 • 000 2. 869 0.3*856 0.2885 16.664 15551.4 17642.8 147.938 28.16 43.60 424

290.000 2. 794 0.35788 0.2792 19.339 15712.6 17659.9 148.694 26.27 43.25 429

295.000 2.724 0.36706 0.2706 20.000 15673.0 16075.4 149.430 28.40 42.95 434

300.000 2.659 0.37611 0.2627 20.649 16032.9 16269.5 150. 150 26.54 42.71 439

310.000 2.539 0. 39389 0.2483 21.911 16351.5 18714.8 151.545 28.84 42.37 448

320.000 2.431 0.41129 0.2356 23.133 16669.7 19137.5 152.887 29.19 42.18 45b

330.000 2.334 0.42837 0.2244 24.321 16988.7 19558.9 154. 183 29.57 42.11 465

3*0. 000 2.246 0 **516 0.2143 25.479 17309.

0

19960.0 155.440 29.99 42.13 472

350.000 2.166 0.46171 0.2052 26.610 17631.5 20401.8 156.663 30.43 42.24 430

360.000 2.092 0.47805 0.1969 27.718 17956.6 20624.9 157.855 30.90 *2.41 487

370.000 2.024 0.43419 0.1894 28.806 16264.9 21250.1 159.020 31.36 42.63 49*

390.000 1.960 0.51016 0.1825 29.875 16616.7 21677.7 160. 160 31.86 42.91 501

390.000 1.901 0.52599 0.1761 30.928 16952.4 22108.3 161.279 32.40 43.22 507

400.000 1.846 0.54167 0.1702 31.965 19292.2 22542.3 162.377 32.93 *3.57 513

420.000 1. 746 0.57269 0.1596 34.001 19965.2 23421.3 164.522 34.03 *4.35 526

440.000 1.658 0.60328 0. 1504 35.990 20697.0 24316.7 166.604 35.14 *5.21 537

460.000 1.578 0.63354 0.1423 37.942 21428.7 25230.0 166.634 36.26 46.12 548

480.000 1.507 0.66350 0.1350 39.660 22160.9 26161.9 170.617 37.41 47.07 559

500.000 1.443 0.63320 0.1266 41.750 22953.9 27113.1 172.558 36.54 48.05 570

170
METHANE ISOBAR ST P = 65.0 BAR

T DEN VOL DP/OT DP/DD E H S C V CP w OtG K MOL/l L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

9 2.333 28.274 0.03537 20.5169 258.560 3492.7 3722.6 68. 150 33.57 52.37 1586

95.000 28.056 0.03564 19.8643 248.788 3626.4 3858.1 69.661 33.51 52.65 1561

100. 000 27.654 0.03616 18.6964 231.192 3880.0 4115.0 72.379 33.59 53.36 1513

105.000 27.247 0.03670 17.5866 213.904 4140.2 4378.8 75.001 33.67 54.12 1 46 * 110.000 26.831 0.03727 16.5310 197.093 4405.8 46*8.1 77.535 33.61 54.79 1415

115.000 26.407 0.03787 15.5249 180. 873 4675.5 4921.6 79. 983 33.38 55.35 1367

120.000 25.973 0.03850 14.5637 165.316 4943.3 5198.6 82. 350 33.02 55.8* 1320

125.000 25.526 0.03918 13.6432 150.463 5223.8 5478.5 84.640 32.63 56.36 1273

130.000 25.065 0.03990 12.7592 136.325 5502.2 5761.5 86.862 32.20 56.99 1225

135.000 24.589 0. 04067 11. 9079 122.894 5783.

6048.2 89.027 32.02 57.79 1176

1 AO . 000 24.096 0.04150 11.0860 110.144 6069.8 6339.5 91.146 31.87 58.77 1125

145.000 23.582 0.04241 10.2903 98.038 6360.6 6636.3 93.228 31.78 59.94 107*

150.000 23.045 0.04339 9.5175 86.532 6657.2 6939.2 95.282 31.67 61.2* 1021

155.000 22. 480 0.0*448 8. 7648 75.585 6959.7 7248.9 97.312 31.45 62.62 969

160.000 21.883 0.04570 8.0287 65.156 7268.6 7565.6 99.323 31.03 64.09 91b

165.000 21.245 0.04707 7.3056 55.220 7584.2 7890.1 101.320 30.42 65.75 863

170.000 20.556 0 • 0*865 6.5914 45.767 7907.8 8224.0 10 3. 313 2 9.73 67. 93 8 07 175.000 19. 798 0. 05051 5.8809 36.807 0243.2 8571.5 105.325 29.73 71.68 744

100.000 18.947 0.05278 5. 1678 20.385 8598.0 89*1.8 10 7.411 29.61 76.78 677

105.000 17.959 0.05568 4. 4437 20.584 8982.1 93*4.0 109.615 29. 71 84.74 605

190.000 16.751 0.05970 3.6972 13.547 9410.4 9798.5 112.038 30.10 98.43 525

195.000 15. 136 0.06607 2.9108 7.490 9922.8 10352.2 114.913 31.00 127.27 430

200.000 12.545 0.07972 2.0446 2.931 10645.5 11163.7 119.017 32.69 213.99 346

205.000 9.187 0. 10805 1.3072 2.503 11574.9 12202.4 12*. 543 33.14 198.97 306

210.000 7.317 0.13666 0.9698 3.797 12203.1 13091.4 128. 446 31.49 126.65 311

215.000 6.339 0 . 15 776 0.8025 5.280 12615.4 13640.8 131. 033 30.35 95.63 322

220.000 5.708 0.17521 0.6982 6.616 12935.5 14074.4 133.027 29.61 79.37 333

225.000 5.250 0.19048 0.6249 7.840 13207.2 14445.3 13*. 695 29.09 o 9 . 7 5 342

230.000 4. 895 0.20430 0.5695 8.973 13449.3 14777.2 136.154 28.73 6 3.42 351

235.000 4 . bO 7 0.21707 0.5256 10.033 13671.7 15082.6 137.468 26.46 50.96 360

240. 000 4.366 0.22905 0.4896 11.031 13879.9 15368.7 138.673 28.23 5 5.6b 368 245.000 4. 160 0.2*041 0.4597 11.977 14077.8 15640.5 139.793 28. 15 53.13 375

250.000 3. 980 0. 25127 0. 4340 12.879 14267.7 15901.0 140.846 28.06 51.15 383

255.000 3. 821 0 • 26 17

0.4118 13.742 14451.5 16152.6 141.843 28.01 *9.56 389

260.000 3.679 0.27181 0.3922 14.572 14630.4 16397.1 142.792 26.00 48. 27 39o

265.000 3.551 0.28161 0.3748 15.373 14805.3 16635.8 143.701 28. 01 *7.21 402

270. 000 3. 435 0.23116 0.3592 16.148 14977.0 16869.5 144.575 28.04 46.33 409

275.000 3.328 0.30043 0. 3451 16.900 15146.2 17099.3 145.419 28.10 *5.60 413

2SO.OOO 3.230 0.30960 0. 332^ 17.631 15313.3 17325.8 146.235 28.17 44.90 419

205.000 3.139 0.31855 0.3207 18. 344 15478.8 175*9.4 147. 026 28.26 44.48 4 24 290.000 3.055 0.32735 0.3099 19.039 15642.9 17770.7 147.796 26.37 44 . 05 429

295.000 2.976 0. 33600 0.3000 19.720 15806.0 17990.0 148.5*6 28.49 4 3.69 * 3 * 300.000 2.903 0.34453 0.2909 20.366 15968.3 18207.7 149.278 28.62 43.40 439

310.000 2.768 0. 36125 0.2744 21.681 16291.3 18639.4 150.693 28.92 42.97 448

320.000 2.648 0. 37758 0.2599 22.933 16613.4 19067 .6 152.053 29.27 42. 70 457

330.000 2.541 0.33350 0.2471 2*. 147 16935.6 19493.9 153.364 29.64 42.57 465

340.000 2.443 0. 40930 0.2357 25.329 17259.0 19919.4 154.635 30.05 42. 55 473

350.000 2.354 0.42477 0.2254 26.482 17584.

20345.

155. 869 30.49 *2.6 1 40 0 3 o 0 . 0 0 0 2.273 0 • *4 0 0 3 0.2161 27.611 17911.7 20771.9 157.071 30.95 *2.75 409

370.000 2. 197 0.45509 0.2077 28.717 18242.2 21200.3 158.245 31. *4 *2.95 * 9* 380. 000 2. 128 0.46999 0. 1999 29.603 18576.1 21631.0 159. 393 31.94 43.20 501

390.000 2. 063 0.43473 0.1928 30.871 18913.6 22064.4 160.519 32.46 43.49 508

400.000 2.003 0.43934 0.1862 31.923 19255.2 22500.9 161.624 32.99 *3.82 51*

420.000 1.893 0.52819 0.1744 33.984 19951.2 23384.163.780 34.07 44.56 526

440.000 1.797 0.55663 0.1642 35.996 20665.8 24284.0 165.872 35.19 45.40 53d

460.000 1.710 0.58473 0.1552 37.967 21400.

25200.8 167.909 36.32 46.29 5*0

480.000 1.633 0.61254 0.1472 39.902 22154.4 26135.9 169.899 37.45 4 7.22 56 0 500.000 1.562 0.64010 0.1400 41.808 22929.

27089-9 171.8*6 38.57 *8.18 571

171
J

HETHANE I SO iJ Art AT P = 70.0 BAR

T OEN VOL DP/OT DP/DD E H S CV CP W OEG K MOL/t L/MOL BAR/K BAR-L/MOL J/NOL J/MOL J/MOL/K J/ M OL / K J/MOL/K 8/SEC

92.rt59 28.28* 0.03536 20.5014 259.184 3494.4 37*1.9 6 8. 17 1 33.60 52.35 1 5 8'j 95.000 28.076 0. 03562 19.8819 249.897 3621.7 3 671.1 69.611 33.55 52.61 1563

100. 0 00 27. 676 0. 03613 18.7185 232.398 3674.9 4127.8 72.327 33.63 53.31 1515

105.000 27.270 0 . 03667 17.6129 215.192 4134.6 4391.3 74.946 33.71 54.07 1467

110.000 26. 857 0. 03723 16.5612 198.452 4399.7 4660.3 77.477 33.65 54.73 1418

115.000 26.435 0.03783 15.5591 182.294 4668.7 4933.5 79.922 33.42 55.27 1371

120. 000 26. 003 0 . 03846 14.6019 166.792 4940.8 5210.0 82.285 33.06 55. 75 1 324

125.000 25.559 0 . 03913 13.6855 151.990 5215.5 5489.4 84.570 32.67 56.25 1277

130.000 25.102 0. 03984 12.8058 137.902 5492.9 5771.8 86.788 32. 32 56.65 1230

135.000 24.630 0.0*060 11.9591 124.519 5773.6 6057.8 88.947 32.06 57. b2 1181

140.000 24. 141 0 . 0*142 11.1421 111.820 6058.

3

6348.2 91.060 31.91 58.58 1131

145. 000 23. 632 0. 0*231 10. 3517 99.768 6347.7 6643.9 93.134 31.82 59.70 1030

150.000 23. 102 0 . 0*329 9. 5850 88.322 6642.5 69*5.5 95.179 31.71 60.95 10 29 155.000 22. 546 0.0*435 8. 8391 77.440 6943. 0 7253.5 97.199 31.48 62.25 977 160.000 21.959 0.04554 8.1110 67.087 7249.3 7566.1 99. 196 31.06 63.60 9 2 5 165.000 21.334 0 . 04687 7.3975 57.236 7561.7 7889.8 101.176 30.44 65.10 873

170.000 20.662 0. 0*8*0 6.6950 47. 876 7881.1 8219.8 103.146 29.75 67.03 3 20 175.000 19.930 0.05018 5.9996 39.020 8210.7 8561.9 105. 127 29.72 7 0.36 759

130.000 19.116 0.05231 5. 3063 30.707 8557.8 8924.0 107.166 29. 57 74.7* 695

135.000 18.188 0. 05498 4.6098 23.017 8928.0 9312.9 109.297 29.61 31.25 627

190.000 17.089 0. 05852 3. 9038 16.074 9333.1 9742.7 111.589 29.88 91.57 554

195 .000 15.710 0. 0?366 3.1818 10.060 9796.0 102*1.6 114. 180 30.48 109.99 476

200.000 13.806 0.07243 2.4352 5.252 10370.2 10877.2 117.396 31.54 150.02 395

205.000 11.036 0.09061 1.6901 2.978 11144.4 11778.6 121.845 32.47 193.91 333

210. 000 8.739 0. 11443 1. 2208 3.368 11646.1 12647.1 126.032 31.95 152. 93 313 215. OuO 7.353 0. 13600 0.9704 4.627 12349.7 13301.6 129.115 30.83 111.77 32 3 220. 000 6.505 0. 1?374 0 . 8246 5.964 12722.2 13798.4 131.399 30.0 1 89.28 333

225.000 5.916 0.1690* 0.7267 7.209 13027.0 14210.

3

133. 251 29.42 7b. 53 3*2

230. 000 5.472 0. 1827* 0 • 6552 8.370 13292.0 14571.2 134.838 29.01 68.40 351

235. 000 5. 120 0. 19530 0.5999 9.460 13531.4 14898.5 136.246 28.71 62.80 359

240 .000 4.831 0.20700 0.5554 10.491 13752.8 15201.8 137. 523 28. 49 58.73 367

245.000 *.586 0. 2180* 0.5187 11.469 13961.2 15487.4 138. 701 28.33 55.66 375

250.000 4.376 0 . 22854 0.4877 12.401 14159.7 15759.5 139.801 28.23 53.27 382

255.000 4.191 0.23861 0.4610 13.294 14350.7 16021.0 140 . 836 28.17 51.38 3 8 3 260.000 4. 027 0 . 24831 0.4378 14.152 14535.8 16273.9 141.819 28.14 *9.65 39? 265.000 3. 881 0.25770 0.4173 14.979 14716.

0

16519.9 142.756 28.14 48.59 40?

27Q.000 3.748 0 . 26682 0 . 3990 15.779 14892.5 16760.2 143.654 28.16 * 7 . 5 o * 0 8 275.000 3.627 0.27571 0.3826 16.554 15065.8 16995.8 144.519 28.21 *6.70 *13

230.000 3.516 0 .28440 0.3678 17.307 15236.7 17227.5 145.354 28.28 *5.98 *19

235.000 3.414 0.29291 0.3543 18.041 15405.4 17455.8 146. 162 28.36 45.38 424

290.000 3. 319 0.30125 0. 3420 18.756 15572.6 17681.4 146.947 28.46 *4.67 429

295.000 3.231 0 . 3094b 0. 3306 19. *55 15738.4 1790 4.7 147.710 28.58 *4.45 4 34 300.000 3.149 0. 31753 0.3201 20.138 15903.3 18126.0 148.454 28.71 *4.10 439

310.000 3.000 0. 53334 0. 3013 21.466 16230.8 18564.2 149.891 29.00 43.57 448

320.000 2. 667 0 . 3*875 0.2849 22.746 16556.8 18998.0 151.268 29. 34 *3.2 3 45 7 330.000 2. 749 0 . 36383 0.2705 23.986 16882.5 19429.3 152.595 29.71 *3.0* * 6 5 340.000 2.641 0 . 37 862 0.2577 25.191 17208.9 19859.

2

153. 879 30.12 *2.97 4 7 3 350. 000 2.543 0 .39317 0.2462 26.366 17536.8 20288.9 155.125 30.55 42.99 481

360.000 2.454 0 . 40750 0.2358 27.514 17866.

8

20719.3 156.337 31.0 1 *3.09 * 8 a 370.000 2.372 0.42163 0.2263 28.638 18199.5 21151.0 157.520 31.49 43.26 495

330.000 2.296 0.*3560 0.2177 29.740 18535.4 21584.7 158.676 31.99 *3.48 502

390.000 2.225 0.44942 0.2098 30.824 18874.9 22020.8 159.809 32.51 43. 75 5 J? 400.000 2. 159 0 • 46 3 1

0

0.2025 31.890 19218.2 22459.9 160.921 33.04 *4.0 6 51?

420.000 2. 040 0.49010 0 . 1894 33.976 19917.4 23348.1 163.087 34.12 *4.78 527

*40.000 1.935 0.51669 0.1761 36.010 20634.

7

24251.6 165.189 35.23 45.59 5 3? 460 . 000 1.842 0 . 54294 0 . 1682 38.000 21371.3 25171.9 167.234 36. 36 *6 . 46 55 0 480.000 1.758 0 . 5o 890 0 . 1594 39.953 22127.9 26110.2 169. 231 37.49 47.37 561

500.000 1.682 0.59461 0.1516 41.873 22904.6 27067.1 17 1. 183 38. bl *8.32 571

172
METHANE ISOBAR AT P * 75.0 BAR

T Q£N VOL DP/DT OP/DO E H S CV CP w OEG K MOL/L L/MOL BAR/K iAR«l/MQL J/MOL J/MOL J/MOL/K J/HOL/K J/MOL/K M/SEC

92.595 28.294 0 . 03534 29.4859 259.805 3496.1 3761.2 68.193 33.64 52.32 1507

95.000 28.096 0.03559 19.8994 250.998 3617.1 3884.1 69.560 33.59 52.57 1565

100. 000 27.697 0. 03610 18. 7403 233.595 3069.9 4140.7 72.274 33.67 53.27 1518

105.000 27. 293 0 . 03664 17.6380 216.472 4129.1 4403.9 74.891 33.75 54.0 1 1469

110.000 26.982 0.03720 16.5911 199.802 4393.6 4672.6 77.419 33.69 54. 66 1422

115.000 26.462 0.03779 15.5929 183.706 4662.0 49*5.4 79.061 33.46 55.19 1374

120.000 26. 033 0. 03841 14.6397 166.260 4933.4 5221.5 82.220 33.10 55.66 1328

125.000 25.592 0.03908 13.7273 153.508 5207.3 5500.4 84.502 32.71 56.1* 1281

130.000 25. 138 0.03978 12.8518 139.467 5483,8 5782.2 86.714 32.36 56.72 1234

135.000 24.670 0.04054 12.9095 126.132 5763.5 6067.5 88. 869 32. 10 57.47 1186

140. 000 24.185 0.04135 11.1973 113.481 6046.9 6357.0 90.975 31.95 58.39 1137

145.000 23.682 0. 04223 10.4121 101.481 6334.9 6651.6 93.042 31.86 59.48 1087

150.000 23. 156 0.04318 9.6512 90.092 6628.1 6952.0 95.076 31.75 6 0.66 1 0 3o 155.000 22.610 0.04423 8. 9110 79.274 6926.7 7258.4 97.083 31. 52 61.90 985

160.000 22.032 0.04539 8. 1911 68.991 7230.6 7571.1 99.072 31.09 63.15 935

165.000 21.420 0.04669 7.4865 59.217 7540.0 7890.1 101.036 30.47 o 4 . 5 0 88*

170.000 20.765 0.04816 6.7948 49.943 7855.5 8216.7 102.985 29.76 66.21 832

175.000 20.055 0. 04986 6. 1126 41.179 8179.9 8553.9 104.938 29.72 o9. 20 773

180 .000 19.274 0.05188 5.4366 32.962 8519,7 8908.8 106.937 29.55 73.00 712

185.000 18.395 0.05436 4.7628 25.363 8878.9 9286.6 109.007 29.55 78.44 648

190.000 17.378 0.05754 4.0880 18.492 9266.1 9697.7 111.199 29.72 86.58 579

195. 000 16.154 0.06190 3. 4102 12.502 9696.2 10160.5 113.603 30.14 99.65 508

200.000 14.593 0.06653 2.7300 7.589 10197.2 10711.1 116.390 30.87 123.10 43*

205.000 12.475 0.08016 2.0535 4.225 10821.8 11423.0 119.903 31.74 163.22 368

210.000 10.152 0.03850 1.5017 3.750 11508.5 12247.3 123.876 31.85 154.37 337

215.000 8. 484 0. 11787 1. 1709 4.308 12066.

12950.0 127.185 31.13 126.20 330

220.000 7.362 0.13546 0.9711 5.469 12495.1 13511.1 129.765 30.34 99.95 335

225.000 6.636 0.15069 0.8422 6,695 12837.0 13967.2 131 . 8129.72 33.84 343

230.000 6.089 0.16423 0.7507 7.860 13127.7 14359.** 133.541 29.27 73.7* 351

235.000 5. 664 0. 17657 0.6615 8.964 13385.7 14710.0 135.049 28.93 56.90 355

240.000 5.319 0. 18801 0.6269 10.013 13621.5 15031.5 136.403 28.69 ol.99 367

245.000 5. 031 0.19875 0.5824 11.012 13841.3 15331.9 137.642 28.51 58.32 3 7o 250.000 4.766 0.20894 0.5452 11.968 14049.1 15616.2 138.790 28. 39 55.50 382 255.000 4.573 0.21867 0.5135 12.884 14247.9 15887.9 139.867 28.31 53.27 389

260.000 4.386 0.22802 0.4862 13.765 14439.5 16149.6 140.883 28.27 51.48 395

265.000 4.219 0.23705 0.4622 14.615 14625.4 16403.3 141.850 28.26 50-03 402

270.000 4. 066 0.24581 0.4409 15.436 14806.8 16650.3 142.773 28.28 48.83 408

275. 000 3.932 0.25432 0.4220 16.232 14984.5 16891.9 143.660 28.32 *7.83 413

280.000 3.808 0.26263 0.4049 17.005 15159.2 17128.9 144. 514 28.38 *7.00 413

285.000 3.693 0.27075 0.3894 17.757 15331.5 17362.1 145.339 28.46 46. 30 424

290.000 3.586 0.27871 0. 3753 18.491 15501.8 17592.1 146.139 28.55 45.71 43 0 295.000 3.490 0.28652 0. 3624 19.207 15670.5 17819.4 146.916 28.67 *5.22 435

300.000 3.399 0.29420 0.3504 19.907 15837.9 18044.4 147.673 28.79 44.81 4 3 9 310.000 3.234 0.30921 0. 3292 21.265 16170.1 18489.2 149.131 29.08 44.18 449

320.000 3. 088 0. 32383 0.3107 22.573 16500 .1 18926.8 150.527 29.41 *3.77 458

330.000 2. 958 0. 33811 0.2946 23.638 16829.3 19365.1 151.869 29.78 *3.51 46o

340.000 2.840 0.35210 0.2802 25.666 17158.7 19799.5 153.166 30.18 43.33 4 7* 350.000 2.733 0.36584 0.2674 26.261 17489.4 20233.2 154.423 30.61 43.37 482

360.000 2.636 0.37936 0.2556 27.428 17621.9 20667.1 155.646 31.07 *3.43 *8 9 370.000 2.547 0. 39269 0.2454 28.569 18156.9 21102.1 156.836 31.55 *3.57 496

380.000 2.464 0.40585 0.2358 29.688 16494.9 21538.8 158. 002 32. 05 *3.77 503

390.000 2.387 0.41886 0.2271 30.786 18836.2 21977.7 159. 142 32.56 *4.02 509

400.000 2.316 0.43174 0.2190 31.866 19181.3 22419.3 160.260 33.09 *4.31 5 lo 420.000 2. 186 0.45713 0.2047 33.977 19883.6 23312.1 162.438 34.17 *4.99 523

440.000 2.074 0.48211 0. 1923 36.033 20603.8 24219.6 164. 549 35.28 *5.77 540

460.000 1.973 0.50676 0.1814 38.041 21342.8 25143.5 166.602 36.40 *6.62 551

480.000 1.683 0.53111 0.1718 40.010 22101.5 26084.9 168.605 37.53 *7.52 562

500.000 1.801 0.55523 0.1633 41.945 22080.3 270*4.5 170.564 38.65 *8.45 572
METHANE ISOBAR ATP® 66.0 BAR

T DEN VOL DP/OT DP/ 00 £ H S CV CP W DEG K MOL/L L/MOL i&R/K iAR-L/MOL J/NQL J/ MOL J/MOL/K J/N04/K J/HOL/K M/SEC

92.711 26. 303 0.03533 20.4705 260.422 3497.9 3760.5 68.214 33.68 52.30 1588

95.000 26. 116 0.03557 19.9166 252.090 3612.6 3®97»i 69.510 33.63 52.54 1567

100.000 27.719 0.03608 18.7619 234.F84 3664.9 4153.5 72.222 33.71 53.23 1520

105. 000 27.316 0.03661 17.6644 217.743 4123.6 4416.5 74.837 33.79 53.96 1472

110.090 26.907 0.03717 16.6207 201.145 4367.5 4684.9 77.362 33.73 54.60 1425

115.000 26.469 0.03775 15.6263 165.110 4655.3 4957.3 79.801 33.50 55.12 1376

120.000 26.062 0.03837 14.6770 169.718 4926.0 5233.0 82.156 33.14 55.57 1332

125.000 25.624 0.03903 13.7636 155.016 5199.2 5511.4 84.434 32.75 56.03 1286

i JO .000 25. 173 0.03972 12.8971 141.923 5474.6 5792.6 86.642 32.40 56.59 1239

135.000 24.709 0.0*047 12.0592 127.734 5753.5 6077.2 88.791 32.14 57.31 1192

140.000 24.229 0.04127 11.2516 115.130 6035.6 6365.9 90.891 31.99 56.21 1143

145.000 23.731 0.0*214 10.4715 103.179 6322.5 6659.6 92.991 31.89 59.26 1093

150.000 23.213 0.04308 9. 7161 91.845 6614.1 6958.7 94.979 31.70 60.39 1043

155.000 22.672 0.04411 6. 9628 81.085 6910.8 7263.6 96.979 31.55 61.56 993

160.009 22.104 0.04524 6.2692 70.666 7212.4 7574.4 98.952 31.13 62.72 944

165.000 21.503 0. 04651 7.5728 61.167 7519.0 7891.0 100.900 30.49 63.95 894

170.000 20.663 0. 04793 6. 6909 51.972 7330.9 6214.3 102.830 29.76 65.47 644

175.000 20.173 0.0*957 6.2206 43.291 8150.6 8547.2 104.757 29.7 3 68.17 787

160.000 19.420 0.05149 5.5597 35.158 6483.9 8895.9 106.722 29.53 71.49 7 28 165.000 16.564 0.05381 4.9051 27.637 8633.6 9264.3 108.740 29.49 76.13 667

190.000 17.633 0.05671 4.2553 20.623 9206.7 9660.4 110.853 29.61 82.75 602

195.000 16.520 0. 06053 3.6105 14.647 9612.9 10097.1 113.121 29.91 92.64 535

200.000 15.169 0.06592 2.9740 9.661 10069.1 10596.5 115.648 30.43 106. 39 468

205.000 13.456 0.07430 2.3529 6.097 10603.4 11197.6 118.617 31.11 133.66 404

210.000 11.394 0.06776 1.7665 4.372 11222.8 11924.9 122.120 31.53 149.59 360

215.000 9.617 0. 19396 1.3917 4.592 11792.8 12624.6 125.414 31.19 129.24 344

220.000 6.322 9. 12016 1.1365 5.234 12260.0 13221.3 128.158 30.55 109.21 342

225.000 7.406 0.13502 0.9719 6.323 12639.7 13719.8 130.400 29.96 91.24 346

230.000 6.743 0.14631 0.6565 7.460 12957.5 14143.9 132.265 29.49 79.23 353

235.000 6.235 0.16039 0.7710 8.556 13235.5 14516.6 133.876 29.14 71.12 361

240.000 5.629 0.17156 0.7045 9.610 13466.6 14659.1 135.310 26.87 65.35 368

245.000 5.494 0. 18202 0.6510 10.619 13716.5 15174.6 136.612 28.66 61.06 375

250.000 5.211 0.19191 0.6066 11.586 13936.2 15471.5 137.611 2 8.54 57.80 382

255.000 4.967 0.20133 0.5694 12.519 14143.1 15753.8 138.929 26.45 55.23 389

260.000 4.754 0.21037 0.5374 13.417 14341.7 16024.6 139.981 26.40 53.17 396

265.000 4.565 0.21908 0.5095 14.285 14533.5 16266.1 140.978 26.36 51.50 402

270.000 4.396 0.22750 0.4850 15.124 14720.1 16540.1 141.927 28.39 50.13 408

275.000 4.243 0.23569 0.4632 15.938 14902.3 16767.6 142.836 28.42 48.99 414

260.000 4. 104 0.24366 0 • 4436 16.726 15061.0 17030.3 143.710 26.48 46.04 419

265.000 3.977 0.25144 0.4260 17.497 15256.9 17266.4 144.553 26.55 47.2* 425

299.000 3. 660 0.25905 0.4100 16.246 15430.5 17502.9 145.369 26.64 46.57 430

295.000 3.752 0.26652 0.3953 16.978 15602.1 17734.3 146.160 26.75 46.01 435

JOO.OOO 3.652 0.27385 0.3619 19.693 15772.3 17963.1 146.929 26.67 45.53 440

310.000 3.470 0.26817 0.3560 21.079 16109.2 18414.5 148.409 29.15 44.60 449

320.000 3.310 0.30206 0.3373 22.413 16443.2 16659.9 149.823 29.48 44.30 459

330.000 3.166 0.31566 0.3193 23.702 16776.0 19301.2 151.161 29.85 43.99 467

3*0.000 3.040 0.32694 0.3033 24.952 17108.6 19740.1 152.491 30.25 43.81 475

350.000 2.924 0.34197 0.2691 26.168 17442.0 20177.6 153.760 30.67 43.75 482

360.000 2.619 0.35479 0.2763 27.353 17777.1 20615.4 154.993 31.13 43.78 490

370.000 2.722 0.36741 0.2648 28.511 18114.3 21053.7 156.194 31.61 *3.89 497

360.000 2.632 0.37987 0.2543 29.646 18454.4 21493.3 157.366 32. 10 44. 06 504

390.000 2.550 0.39217 0.2447 30.756 18797.6 21935.0 158.513 32.61 44.28 510

400.000 2.473 0.40434 0.2356 31.652 19144.4 22379.2 159.636 33.14 44.55 517

420.000 2.335 0.42632 0.2201 33.987 19650.0 23276.5 161.627 34.22 *5.20 529

4*0.000 2.213 0.45 169 0.2066 36. 063 20572.6 24166.0 163.947 35. 32 45.96 541

460.000 2. 105 0.47513 0.1946 36.090 21314.3 25115.4 166.006 36.45 46.79 552

460.000 2.006 0.49806 0.1643 40.075 22075.2 26059.9 168.016 37.57 47.67 563

500.000 1.920 0.52079 0.1751 42.024 22656.0 27022.3 169.982 36.69 48.58 573

174
METHANE ISOBAR AT P = ©5.0 BAR

T OEM VOL DP/OT OP/ DO E H S Ctf CP W QEG K MOL/L L/MOL 8AR/K BAR-L/HOL J/MOL J/HOL J/MOL/K J/HOL/K J/40L/K H/SEC

92.83 7 28.313 0.03532 20.4552 261.036 3499.6 3799.9 68.235 33.71 52.28 1588

95.000 28. 135 0 e 03554 19.9336 253.174 3608.0 3910.2 69.461 33.67 5 2 . 5 Q 1569

100.000 27.740 0.03605 18.7832 235.967 3859.9 4166.

7 2.17 0 33.75 53.18 1522

105.000 27.339 0.03658 17.6898 219.007 4118.2 4429.1 74.783 33.83 53.91 1475

110.000 26.932 0.03713 16.6499 202.479 4381.6 4697.2 77.305 33.77 54.53 1428

115.000 26.516 0. 03771 15.6593 186.506 4648.8 4969.3 79.741 33.54 55.04 1381

120.000 26.092 0.03833 14.7139 171. 170 4918.8 5244.

82. 093 33.18 55.48 13 36 125.000 25.656 0.03898 13.8093 156.516 5191.2 5522.5 84.367 32.79 55.93 1290

130.000 25.209 0.03967 12.9419 142.568 5466.0 5803.1 86.570 32.44 56.47 1244

135.000 24. 748 0.04041 12.1082 129.324 5743.6 6087.1 88.714 32.18 57.17 1197

l-tO.QOO 24. 272 0 . 0* 120 11. 3051 116.766 6024.8 6375.0 90.800 32. 02 58.04 1148

145.000 23.779 0.04205 10.5298 104.863 6310.2 6667.7 92.862 31.93 59.05 1099

150.000 23.26? 0 * 0*298 9.7797 93.579 6600.3 6965.6 94.882 31.82 60.14 1050

155.000 22. 733 0.04399 9. 0523 82.876 6895.2 7269.1 96.872 31.59 61.24 1001

160.000 22. 173 0. 04510 8.3454 72.721 7194.

7578.1 98.833 31.16 62.32 952

165.000 21.584 0.04633 7.6567 63.088 7498.6 7892.4 100.768 30.52 63.43 904

170.000 20.957 0.04772 6. 9838 53.965 7807.2 8212.8 102.681 29.80 64.78 855

175.000 20.286 0. 0*929 6. 3246 45. 360 8122.6 8541.6 104.584 29.74 67.24 800

180.000 19.558 0. 05113 5.6767 37.302 8450.2 8884.8 106.518 29.52 70.18 743

185.000 18.758 0.05331 5.0386 29.847 8792.0 9245.1 108.492 29.45 74.13 684

190.000 17.861 0.05599 4.4094 23.081 9153.1 9629.0 110.539 29.52 79.69 623

195. 000 16. 834 0. 05940 3.7903 17.113 9540.9 10045.9 112.704 29.74 87.51 560

200.000 15.626 0 . 0640 0 3.1855 12.069 9966.2 10510.2 115. 055 30.12 98.99 497

205.000 14.168 0 . 07058 2.6023 8.093 10445.3 11045.3 117.696 30.65 116.10 437

210.000 12.417 0.03053 2.0572 5.550 10991.6 11676.2 120.736 31.11 134.95 387

215.300 10.653 0. 09387 1.6173 5. 094 11549.6 12347.5 123.896 31.15 128.44 362

223.000 9.264 0.10795 1.3200 5.461 12031.5 12949.1 126.662 30.62 112.42 35-. 225.000 8.210 0.12180 1.1157 6.160 12439.1 13474.3 129.024 30.12 97.56 353

230.000 7.427 0.13465 0.9727 7.185 12783.5 13928.0 131.019 29.67 84.50 357

235. 000 6.830 0. 14640 0. 8683 8.251 13082.0 14326.5 132.733 29.31 75.33 364

240.003 6.356 0. 15727 0.7862 9.291 13349.0 14685.8 134.246 29.04 3 8.74 370 245.000 5.972 0 • 1574h 0,7246 10.297 13593.

15016 .

135.611 28.83 63.85 377

250.000 5.649 0. 17704 0.6724 11.269 13821.4 15326.2 136.862 28.69 60-13 384

255.000 5. 371 0. 18617 0.6288 12.208 14036.8 15619.3 138.022 20.59 57.21 390

260.000 5.131 0.10491 0.5916 13.116 14242.5 15899.

139. 110 20.52 54.88 397 265.000 4.918 0.20332 0.5594 13.995 14440.6 16168.8 140.137 20.50 52.99 403

270.000 4.729 0.21145 0.5312 14.847 14632.5 16**2 9. 6 141.112 28.50 51.44 409

275.000 4.559 0. 21933 0.5063 15.675 14819.4 16683.7 142.044 28.53 50.16 415

280.000 4.405 0.22700 0.4841 16.479 15002.3 16931.8 142.938 28.57 49.09 420

285.000 4.265 0.21447 0.4641 17.262 15181.9 17174.9 143.799 28.64 48.19 425

290.000 4. 136 0. 24178 0.4460 18.026 15358.8 17413.9 144.630 20.73 4 7.44 431

295.000 4. 017 0 . 24894 0.4295 18.771 15533.5 17649.5 145.436 28.03 46.80 436

330.000 3.907 0.25597 0.4144 19.499 15706.3 17882.1 146.217 20.95 46.26 441

310.000 3.706 0.26966 0 . 367 6 20.911 16048.1 18340.2 147.720 29.23 45.42 450

320. 000 3. 534 0. 28295 0. 3646 22.269 16386.3 18791.4 149.152 29.55 44.85 459

330.000 3.380 0.29590 0. 3446 23.580 16722.7 19237.8 150.526 29.91 44.46 467

340.000 3.241 0. 30856 0. 3270 24.851 17058.4 19681.2 151.050 30.31 -*4.23 475

350.000 3.116 0-32097 0.3113 26.086 17394.7 20122.9 153.130 30.73 44.13 483

360.000 3. 002 0. 33316 0.2972 27.289 17732.3 20564.1 154.373 31.19 44.12 491

370.000 2. 89? 0. 34515 0.2846 28.463 18071.8 21005.7 155.583 31.66 44.20 49d

380.000 2.801 0.35698 0.2731 29.613 18414.0 2144 8.

156.763 32.15 *4.35 505

390.000 2.713 0 . 36 866 0. 2625 30.740 18759.1 21892.8 157.918 32.66 44.55 511

400.000 2. b30 0. 38020 0.2629 31.846 19107.7 22339.5 159. 049 33.19 44.8 0 518

423.000 2.482 0.40294 0.2358 34.005 19816.4 23241.

161.249 34.26 4 5.41 530

440.300 2.351 0.42526 0.2211 36.102 20542.0 24136.8 163. 378 35.37 4b. 1 4 542

4oO. 000 2. 236 0. -*4726 0.2083 38.146 21285.9 25087.6 165.446 36.49 46.95 553

480.000 2. 132 0 . 4o896 0.1970 40.147 22049.0 26035.2 167.453 37.61 47.81 56 500.000 2. 039 0.40043 Q • 1869 42.109 22831.8 27000.4 169.433 38.73 -*8.71 575

175
METHANE ISOBAR ATP* 90.0 BAR

T OEM VOL 0P/DT OP/ DO E H S cv CP H QEG K MQL/L L/HOL BAR/K 8AR-L/H0L J/MOL J/MOL J/ MOL/

K

J/MOL/K J/MOL/K M/SEC

92.963 26.323 0 . 03531 20.4600 261.647 3501.4 3819.2 60.256 33.75 52.26 1589

95.000 2®. 155 0.03552 19.9503 254.250 3603.5 3923.2 69.411 33.71 52.47 1571

100.000 27.761 0.03602 18.8942 237.140 3855.0 4179.2 72. 119 33.79 53- 14 1525

105.000 27.362 0.03655 17.7148 220.263 4112.8 4441.7 74.729 33.87 53.85 1477

110.000 26.956 0.03710 16.6786 203.806 4375.6 4709.5 77.249 33.81 54.47 1431

115.000 26.543 0.03767 15.6920 187.893 4642,2 *981.3 79.682 33.53 54-97 1385

120. 000 26. 121 0. 0382® 14.7503 172.611 4911.6 5256.2 82.030 33.22 55.39 1339

125.000 25o 606 0. 03893 13.8496 158.006 5183.3 5533.6 84.300 32.83 55. 82 129*

130.000 25.246 0.03961 12.9861 144.104 5457.2 5813.7 86.499 32.48 56.35 1248

135.000 26. 786 0. 0*034 12.1565 130.904 5733.9 6097.0 @8.638 32.22 57.03 1202

140. 000 26.316 0.04113 11. 3578 118.389 6014.0 6334.1 90.726 32.06 57.87 1154

145.000 23.626 0.04197 10.5671 106.532 6298.1 6675.9 92.774 31.97 5 8.8* IlOo

150.000 23.326 0. 04288 9.6421 95.298 6586.8 6972.7 94.786 31.85 59.89 1057

155.000 22.793 0. 04387 9. 1204 86.648 6880,0 7274.9 96.767 31.62 6 0.94 1008

160.000 22.261 0.0*496 6.4196 74.551 7177.5 7582.

1

98.710 31.19 61.95 961

165.000 21.662 0.0*616 7.7383 64.980 7478.9 7894.3 100.639 30.55 62- 95 91*

170.000 21. 066 0. 04751 7.0738 55.924 7784.3 8211.9 102.536 29.82 64. 15 86b

175. 000 20.396 0.04903 6.4246 47.388 8095.8 8537.1 104.418 29.75 66.39 812

ISO. 000 19.669 0.05079 5.7884 39.398 6418.2 8875.3 106.323 29.52 o9. 0 1 758

105.000 16.920 0.05286 5.1645 32.002 8753.0 9228.7 108.260 29.43 72-50 701

190. 000 16. 068 0.05535 4.5527 25.276 9104.2 9602.3 110.252 29.45 77.18 643

195.000 17.109 0.05845 3.9545 19.315 9477.2 1000 3.3 112.335 29.61 83.55 583

200.000 16. 007 0.06247 3.3741 14.220 9879.7 10441.9 114.555 29.90 92.39 523

205.000 16.720 0.06793 2.6182 10.100 10321.6 10933.0 116. 980 30-31 104- 71 46b

210.000 13.212 0.07569 2.2975 7.134 10812.9 11494.1 119.683 30.72 119.73 416

215.000 11.577 0.08638 1.8427 5.798 11337.2 12114.6 '122.603 30.92 124.87 382

220.000 10.166 0.09658 1.5060 5.924 11623.1 12710.3 125.343 30.57 112.43 369

225.000 9.016 0.11094 1.2697 6.349 12243.4 13241.9 127.732 30. 16 100-49 363

230.000 6.129 0. 12301 1.098® 7.083 12608.7 13715.8 129.616 29.79 89.11 363

235.000 7.665 0.13433 0 . 97 34 8.055 12926.9 14135.8 131.623 29.45 79. 33 368

240.000 6.906 0.14485 0. 8781 9.062 13209.6 14513.3 133.213 29.18 72.03 373

265.000 6. *66 0. 15470 0.6031 10.053 13466.9 14859.2 134.639 26.97 66.59 380

250.000 6.097 0. 16400 0.7422 11.016 13705.3 15181.3 135.9*1 28.62 62.43 38b

255.000 5.765 0.17285 0.6916 11.956 13929.4 15485.0 137.144 28.71 59.18 392

260.000 5.516 0.18130 0.6467 12.667 14142.5 15774.2 138.267 28.64 56.59 398

265. 000 5.279 0. 16964 0-6118 13.751 14346.

8

16051.7 139.325 28.60 54.49 404

270.000 5.069 0.19726 0.5797 14.611 14544.2 16319.7 140.327 28.60 52.77 410

275.000 6.661 0.20489 0.5514 15.448 14735.9 16579.9 141.281 28.62 51.34 416

260.000 6. 711 0.21226 0.5262 16.262 14923.0 16833.5 142. 195 28.67 50-15 421

265. 000 6. 556 0.21946 0.5037 17.056 15106.4 17081.7 143.074 28.73 49.15 426

290.000 6.415 0.22651 0.4833 17.831 15286.7 17325.3 143.921 28.81 *8.31 *32

295.000 4.265 0.23339 0.4649 18.588 15464.5 17565.0 14*. 741 20.91 47.59 437

300.000 4. 164 0.2*014 0.4460 19.328 15640.2 17801.4 145.535 29.03 46.99 442

310.000 3.948 0.25327 0.4182 20.762 15986.9 18266.4 147.060 29.30 *6.05 451

320.000 3.759 0.26600 U • 3927 22.141 16329.3 18723.4 148.511 29.62 45.39 460

330. QQO 3.592 0.27639 0.3706 23.473 16669.3 19174.9 149.900 29.97 *4. 94 468

360. 000 3.442 0.29049 0.3512 24.763 17008.3 19622.7 151.237 30.37 44.66 476

350.000 3. 308 0.30234 0.3340 26.01/5 17347.4 20066.5 152.530 30.79 44.51 48*

360.000 3.185 0.31397 0.3186 27.235 17667.5 20513.3 153.783 31.24 44.47 492

370.000 3.073 0.325*1 0.3047 28.426 16029.4 20956.1 155.001 31.71 44.51 499

360.000 2.970 0.33668 0.29 22 29.590 18373.6 21403.8 156.190 32.21 *4.63 506

390.000 2.875 0.34760 0.2807 30.730 18720.7 21851.0 157.351 32.71 *4.81 512

600. 000 2.787 0.35879 0.2702 31.849 19071.1 22300.2 158.489 33.23 45.04 519

620.000 2.629 0.38041 0.2517 34.031 19782.9 23206.6 160.700 34. 31 *5.62 531

660.000 2.490 0.40162 0.2358 36.147 20511.3 24125.9 162.838 35.41 46.33 543

660.000 2.367 0.42251 0.2219 38.209 21257.6 25060.2 164.915 36.53 *7.11 55*

660.000 2.257 0.44311 0.2097 40.225 22022.9 26010.9 166.937 37.65 *7.96 565

500.000 2.15® 0. 46347 0.1989 42.201 22807.6 26978.8 168.913 38.77 *6.84 57b

176
METHANE ISOBAR AT P * 95.0 BAR

T DEN VOL DP/DT DP/OD E H S CV CP w DEG K MOL/L L/MOl BAR/K BAR-L/HOL J/MOl J/MOL J/NOL/K J/MOL/K J/MOL/K N/ SEC 93.069 2ft. 332 0.03530 20.4248 262.254 3503.2 3838.5 68.277 33.79 52.23 1590

95.000 28.175 0.03549 19.9668 255.317 3599.1 3936.3 69. 362 33.75 52.43 1572

100.000 27. 782 0.03599 18.8250 230.305 3050.1 4192.1 72.067 33.83 53.10 1527

105.000 27 . 304 0.03652 17.7396 221.512 4107.5 4454.4 74.675 33.91 53. 8 J 1480

110.000 26.991 0.03706 16.7074 205.125 4369.0 4721.9 77.193 33. 85 54.41 1434

115.000 26.569 0.03764 15.7243 189.273 4635.8 4993.4 79.622 33.62 54.90 1388

120.000 26. 149 0.0382* 14.7863 174.044 4904.5 5267.0 81.968 33.26 55.31 1 343

125.000 25. 719 0.03888 13.8894 159.487 5175.4 5544.0 8*. 234 32.87 55.72 1298

130.000 25.278 0.03956 13. 0290 145.630 5448.

5824.4 06.429 32.52 56.23 1253

135.000 24.824 0.04028 12.2042 132.472 5724.3 6107.0 08.563 32.26 56.89 1207

140.000 24.356 0. 84106 11.4097 120.001 6003.4 6393.4 90.646 32.10 57.70 1160

145.000 23. 873 0.04109 10.6436 108.188 6286.3 6604.2 92.687 32.01 5 8.65 1112

150.000 23. 372 0.0*279 9.9034 97.000 6573.5 6900.0 94.692 31.89 59.66 1064

155.000 22.851 0.04376 9. 1871 86.401 6065.1 7200.8 96.665 31.66 60.65 1016

160.000 22.307 0 • 0*48 3 8.4925 76.358 7160.6 7586.5 98.605 31.22 61.59 969

165.000 21.737 0.04600 7.8178 66.847 7459.7 7896.7 100.514 30.57 62.50 923

170.000 21.136 0. 0*731 7. 1610 57.853 7762.3 6211.7 102.395 29.84 63.57 87b

175.000 20.497 0. 0*879 6.5206 49.380 8070.1 8533.6 104.258 29.76 o 5 . 6 2 82*

ISO. 000 19.812 0.05047 5. 8952 41.451 8387.8 0067.3 106.138 29.52 67.97 771

1S5.000 19.071 0.0524* 5.2640 34.100 8716.3 9214.5 100. 040 29.41 71.05 717

190.000 1ft. 25ft 0.05477 4.6071 27.416 9059.0 9579.3 109.986 29.40 75.00 661

195.000 17. 354 0. 05762 4. 1062 21.459 9419.9 9967.3 112.002 29.51 00.39 60*

200.000 16.335 0.06122 3.5453 16.323 98Q4.5 10306.1 11*. 122 29.73 07.45 547

205.000 15.172 0.06591 3.0105 12.091 10219-5 100*5.7 116. 391 30.05 96.61 493

210.000 13.040 0.07225 2.5097 8.866 10671.5 11357.9 118.859 30.40 106.29 444

215.000 12.371 0.08084 2.0507 6.901 11156.6 11924.5 121.525 30.65 116.9* 4 0 5 220.000 10.952 0.09131 1.6934 6.403 11635.0 12502.4 124.103 30. *5 111.57 395

225.000 9.777 0.10228 1.4277 6.765 12061.4 13033.1 126.560 30. 17 100.89 376

230.000 0.830 0.1132b 1.2324 7.254 12438.0 13513.9 128.682 29.85 91.62 373

235.000 8.068 0.12394 1.0057 8.005 12772.1 13949.5 130.556 29.55 02.71 374

2*0.000 7.460 0. 13405 0.9740 8.932 13069.6 14343.3 132.214 29.29 75.09 378

2*5.000 6. 966 0. 14356 0. 0065 9.890 13339.6 14703.4 133.699 29.08 69.21 303

250.000 6.555 0. 15255 0.8160 10.838 13588.4 15037.6 135. 050 28.93 6* . 6 7 389

255.000 6. 207 0. lollO 0.7577 11.766 13821.2 15351.7 136.294 28.82 61.11 39-

2o0 . 000 5.907 0. 16928 0.7087 12.673 14041.7 15649.9 137.452 28.74 58.27 400

265.000 5.645 0. 17714 0.6667 13.557 14252.4 15935.3 130.540 28.70 55.97 406

270.000 5. *13 0. 18473 0.6303 14.419 14455.4 16210.3 139.568 28.70 54.0 0 412

275.000 5.206 0.19207 0.6983 15.260 14652.0 16476.6 140.5*5 28.71 52.51 417

280.000 5.020 0.19920 0.5701 16.081 14843.4 16735.8 141.479 28.75 51.20 423

285.000 4.851 0.20614 0.5448 16.882 15030.7 16909.0 142.376 28.81 50.10 420

290.000 4.697 0.21292 0. 5220 17.665 15214.4 17237.2 143.239 28.89 49.18 433

295.000 4.555 0.21955 0.5014 18.431 15395.4 17481.0 144.073 28.99 40.39 438

300.000 4.424 9.22604 0.4827 19.100 15573.9 17721.3 144.880 29.10 47.72 443

310.000 4. 190 0.23867 0.4497 20.633 15925.6 18193.0 146.427 29.37 46.68 452

320.000 3.986 0.25089 0.4216 22.031 16272.3 18655.8 147.896 29.68 *5.93 461

330.000 3.805 0.26278 0. 3973 23.361 16616.

19112.4 149. 301 30. 04 45. 42 469

340.000 3.645 0.27437 0.3760 24.688 16958.2 19564.8 153.652 30.43 *5.08 473

350.000 3.500 0.20572 0. 3572 25.950 17300.2 20014.5 151.956 30.85 4* . 89 485

360.000 3.369 0.29685 0.3404 27.193 17642.

20462.9 153. 219 31.30 44.81 493

370.000 3.249 0.30778 0. 3253 20.399 17987.1 20911.0 154.447 31.77 44.82 500

380.000 3.139 0. 31855 0.3116 29.576 16333.4 21359.7 155.643 32.26 *4.92 507

390.000 3.038 0.32917 0.2992 30.730 16682.4 21809.6 156.812 32.76 *5.07 513

400.000 2. 944 0. 33966 0.2870 31.861 19034.6 22261.3 157.955 33.26 45.28 520

420.000 2. 776 0. 36028 0.2678 34.064 19749.6 23172.2 160. 177 34.36 *5.83 532

**0.000 2.628 0.38050 0.2506 36.200 20480.

24035.5 162.325 35.46 46.51 5**

460.000 2.490 0. 40039 0.2357 30.279 21229.5 25033.2 164.409 36.57 *7.28 555

480.000 2.381 0.42000 0. 2226 40.310 21996.9 25986.9 166.438 37.69 * 8.10 56o

500.000 2.276 0. 43937 0.2110 42.299 22783.5 26957.6 168.419 36.81 *8.97 577

177
METHANE ISOBAR ATP* 100.0 BAR

T DEN VOL DP/DT DP/ 00 E M S GV CP w DEG K MOL /l L/MOL 3AR/K BAR-L/HQL J/MOL J/MOL J/MOl/K J/MOL/K J/MOL/K M/SEC

93 . 214 26. 342 0.03526 20.4097 262.656 3505.0 3857.8 68.299 33.82 52.21 1590

95.809 26. 194 0. 03547 19.9631 256.376 3594.7 3949.3 69,312 33.79 52.40 1574

180.000 27.603 0.03597 16.8456 239.463 3845.3 4204.9 72.016 33.67 53.06 1529

IQS. 009 27.407 0.03649 17.7641 222.752 4102.2 4467.0 74.622 33.95 53.75 1463

110.060 27.005 0. 03703 16.7357 206.436 4364.

0

4734.3 77.137 33.89 54.35 1437

115.000 26.596 9.03760 15.7563 190.645 4629.4 5605.4 79.564 33.65 94.63 1391

120.000 26. 170 0.03320 14.8219 175.469 4897.5 5279.5 61.906 33.30 55.22 1347

125.000 25. 751 0.03683 13.9267 160.960 5167.7 5556.6 64.168 32.91 55.63 1302

ISO. 093 25. 312 0.03951 13. 0726 147.146 5440.0 5835.1 86.359 32.55 56.12 1257

135.000 24.662 0.04022 12.2512 134.031 5714.9 6117.1 88.488 32.29 56.75 1212

140 . ces 24.396 0.04099 11.4606 121.600 5992.9 6402.6 90.566 32.14 57.54 1165

145.000 23. 919 0. 04161 10.6991 109.830 6274.6 6692.7 92.601 32.04 56.46 1118

150.000 23.423 0.04269 9.9637 98.667 6560.5 6987.5 94.599 31.93 59.43 1070

155. 000 22.906 0* 0*365 9.2525 86.137 6650.5 7287.0 96.564 31.69 60.38 1023

160.008 22.372 0.04470 8.5636 78.145 7144.2 7591.2 98.494 31.25 61.25 977

165.000 21.611 0.04585 7.8952 68.669 7441.0 7899.5 100*392 30.60 62.08 932

170.008 21. 221 0.04712 7.2457 59.753 7740.9 8212.1 102.258 29.86 63.03 667

175.000 20.597 0. 04655 6.6136 51.339 8045.4 8530.9 104.104 29.77 64.92 635

160.000 19.930 0.05017 5.9979 43.464 6358.6 886 0 .5 105.961 29.52 67.03 764

165.000 19. 213 0.05205 5.3976 36.169 8681.7 9202.2 107.833 29.39 69.76 732

190.000 16.433 0.05425 4.8139 29.506 9017.0 95 5 9.4 109.738 29.36 / 3.28 676

195.008 17. 576 0. 05689 4.2477 23.554 9367.7 9936.6 111.697 29.43 77.79 623

200.000 16.624 0 • 06016 3.7029 18.382 9737.9 10339.5 113.737 29.60 83.59 569

205.000 15.555 0.06429 3.1649 14.056 10132.3 10775.2 115.888 29.65 90.99 517

210.000 14. 354 0 . 06966 2.7001 10.650 10555.3 11252.0 116.186 30.15 99.92 469

215.000 13. 032 0. 07673 2.2561 8.290 11006.4 11773.7 120.641 30.40 108.26 429

220.000 11.684 0.03559 1. 8794 7.233 11466.3 12322.1 123.162 30.28 106.96 403

225.000 10.466 0.03535 1.5670 7.302 11694.2 12847.6 125.525 30.11 100.67 390

230. 000 9.501 0. 10525 1. 3696 7.664 12276.9 13329.4 127.643 29.66 92.22 364

235.000 8.666 0.11510 1.2036 8.172 12620.8 13771.6 129.546 29.60 64.61 362

240.000 6. 021 0 . 12468 1.0753 8.926 12931.1 14177.8 131.256 29.37 77.70 364

245.000 7.474 0.13360 0.9745 9.614 13212.6 14550.6 132.793 29.16 71.62 386

250.000 7. 019 0.14247 0.8936 10.730 13471.5 14696.1 134.169 29.02 66.79 392

255.000 6.635 0. 15072 0.6272 11.641 13712.9 15220.1 135.473 28.91 52.96 396

260.000 6.304 0. 15863 0.7715 12.536 13940.7 15527.0 136.665 26.64 59.90 403

265.000 6. 016 0. 16622 0.7240 13.415 14157.9 15620.1 137.781 28.80 57.41 408

2/0.000 5.762 0.17355 0.6630 14.274 14366.3 16101.6 138.635 26.78 55.36 414

275.000 5.536 0.16064 0.6472 15.115 14567.6 16374.3 139.834 26.60 53.67 419

260.000 5.332 0.18753 0.6155 15.936 14763.6 16639.0 140.786 26.64 52.24 424

285.000 5.146 0.19423 0.5874 16.743 14954.6 16897.1 141.702 26.69 51.05 429

298.000 4.981 0.20077 0.5621 17.531 15142.0 17149.7 142.581 26.97 50.04 434

295.000 4.827 0. 20716 0.5392 18.303 15326.1 17397.7 143.429 29.06 *9.16 439

3J0. 000 4.666 0.21342 0.5165 19.059 15507.5 17641.7 144.249 29.17 48.45 444

310.000 4.433 0.22559 0.4821 20.526 15664.3 16120.2 145.816 29.44 47.30 453

320.000 4.213 0.23735 0.4512 21.940 16215.3 16568.8 147.306 29.75 46.47 462

330.000 4. 020 0.24 677 0.4246 23.306 16562.7 19050.5 148.726 30.10 45. 69 471

340.000 3.847 0.25991 0.4013 24.629 16908.2 19507.3 150.090 30.49 45.50 479

350.000 3.693 0.27060 0.3606 25.913 17253.1 19961.1 151.406 30.90 45.27 466

360.000 3.553 0.29147 0. 3625 27.163 17598.3 20413.1 152.679 31.35 45.15 49*

370.000 3.425 0.29196 0.3462 26.362 17944.6 20864.4 153.916 31.62 45.14 501

360.000 3.306 0.30227 0.3314 29.573 16293.

3

21316.1 155.120 32.31 45.20 508

390.000 3.201 0. 31244 0.3180 30.739 16644.3 21768.7 156.296 32.61 45.33 515

400.000 3.101 0. 32246 0.3057 31.662 16996.

2

22222.9 157.446 33.33 45.52 521

420.000 2.922 0.34219 0.2641 34.106 19716.4 23138.3 159.679 34.40 46.04 533

440.000 2.766 0.36152 0.2656 36.260 20450.2 24065.4 161.835 35.50 46.69 545

4o0 .000 2.62 6 0.36051 0.2496 36.356 21201.4 25006.5 163.927 36.61 47.43 55/

460.000 2. 505 0. 39923 0.2356 40.401 21971.0 25963.3 165.962 37.73 46.25 56/

500.000 2.394 0.41770 0.2232 42.403 22759.6 26936.6 167.949 36.85 49.10 576

178
METHANE ISOBAR AT P = 110.0 BAR

T DEN VOL DP/DT OP/QO E H S C V CP m OEG K MOL/ L L/HOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/HOL/K J/NOl/K M/SEC

93. *65 26.361 0.03526 20.3797 264.055 3506.7 3896.5 68.341 33.90 52.17 1592

95.000 28.233 0.03542 20.0150 258.469 3585.9 3975.5 69.215 33.86 52.3* 1578

100.000 27. 844 0. 03591 18.8859 241.754 3835.7 4230.8 71.915 33.95 52.98 1533

105.000 27.452 0.03643 17.8123 225.210 4091.7 4492.4 74.516 34.03 53.66 1*88

110.000 27.053 0.03696 16.7913 ‘209.035 4352.5 4759.1 77.026 33.96 54. 24 1**2

115.000 26.646 0. 03753 15.8192 193.365 4616.9 5029.6 79.448 33.73 54.69 1398

120.000 26.235 0.03612 14.8920 178.295 4883.7 5303.0 81.783 33.38 55.06 135*

125.000 25.812 0.03874 14.0059 163.880 5152.5 5578.7 84.039 32.98 55.44 1310

130.000 25. 360 0.03940 13.1574 150.152 5423 o 3 5856.7 86.222 32.63 55.90 1266

135.000 24. 936 0.04010 12.3434 137.117 5696.4 6137.5 88.342 32.37 56.50 1221

140.000 24.479 0.04085 11.5609 124.766 5972.4 6421.8 90.410 32.21 5 7.24 1176

145.000 24.008 0.04165 10. 8076 113.076 6251.9 6710.1 92.433 32. 12 58.10 1129

150.000 23.523 0.04251 10.0811 102.018 6535.2 7002.9 94.418 32.00 59. 00 1083

155.000 23.020 0. 04344 9.3796 91.556 6822.3 7300.1 96. 367 31.76 59.86 1037

160.000 22.497 0 . 04445 8.7013 81.660 7112.5 7601.4 98.280 31.31 6 0.62 993

165.000 21.953 0.04555 8.0446 72.304 7405.2 7906.2 100.156 30.66 61.30 949

170.000 21.384 0 . 04676 7.4082 63.473 7700.1 8214.5 101.996 29.91 62.06 906

175.000 20.784 0. 04811 6.7909 55.163 7998.5 8527.7 103.810 29.81 63.67 857

160.000 20. 150 0. 04963 6.1920 47.386 6304.4 8850.3 105.627 29.54 65.40 809

165.000 19.475 0. 05135 5.6110 40.172 8617.6 9182.6 107. 447 29.38 67.60 759

190.000 18. 751 0. 05 333 5.0486 33.564 8940.6 9527.2 109.285 29.31 70.35 709

195.000 17.968 0. 05566 4.5063 27.616 9274.9 9887.1 111.155 29.32 73.74 658

200.000 17.115 0 • 05843 3.9868 22.384 9623.2 10265.9 113.073 29.42 77.90 608

205.000 16. 163 0 • 0ol79 3.4942 17.916 9987.8 10667.5 115.056 29.58 82.92 56 J 210.000 15. le>3 0.06595 3. 0332 14.248 10371 .

11096.4 117.123 29.78 88. 7o 51*

215.000 14. 056 0.07113 2.6090 11.421 10773.

11555.6 119.283 29.98 9*. 82 47*

220.000 12. 895 0.07755 2. 2289 9.523 11188.8 12041.9 121.519 29.92 98.93 443

225.000 11.752 0.08509 1. 9050 8.672 11601.0 12537.1 123.745 29. 88 98.06 421

230.000 10.727 0. 09322 1.6471 8.708 11987.9 13013.4 125.839 29.77 92.0* 410

235.000 9.856 0.10146 1.4472 9.034 12341.2 13457.3 127.748 29.61 85.69 * 0* 240.000 9. 117 0.10969 1.2893 9.457 12665.1 13871.7 129.494 29.44 80.20 401

245.000 8.487 0.11783 1.1625 10.025 12963.9 14260.0 131.095 29.29 75.14 400

250.000 7. 952 0. 12575 1.0597 10.768 13240.4 14623.6 132.564 29.16 70.39 402

255.000 7.497 0. 13338 0. 9754 11.593 13497.8 14965.0 133.917 29.06 06. 29 406

260.000 7. 106 0. 14072 0. 9051 12.442 13739.8 15287.7 135.170 28.99 62.90 *10

265.000 6. 766 0.14780 0.8457 13.290 13969.2 15595.0 136.341 28.95 60.10 415

270.000 6.467 0.15463 0.7947 14.130 14188.6 15889.6 137.442 28. 94 57.79 419

275.000 6.201 0.16125 0.7503 14.959 14399.8 16173.6 138.484 28.95 55.86 424

280.000 5.964 0. 16768 0.7114 15.775 14604.2 164*8.7 139.476 28.96 54.2* 429

285.000 5. 749 0. 17394 0.6769 16.577 14803.16716.4 140.423 29.04 52.

7 * 3 * 290.000 5.554 0. 18004 0. 6461 17.366 14997.3 16977.8 141. 333 29. 11 51.71 *38

295.000 5.376 0 . 18600 0.6183 18.141 15187.7 17233.8 142. 208 29.20 50.71 ** 3 300.000 5.213 0 . 19184 0.5933 18.902 15374.9 17485.2 143.053 29.31 *9.87 4*8

310.000 4.922 0.20317 0.5496 20.386 15741.9 17976.7 144.665 29.56 *8.52 *57

320.000 4. 670 0. 21412 0.5127 21.821 16101.5 18456.8 146.189 29.87 47.54 465

330.000 4.450 0. 22473 0.4811 23.210 16456.4 18928.* 147.640 30.22 *6.83 47*

340.000 4.254 0.23506 0.4536 24.558 16808.4 19394.1 149.031 30.60 *6.3* 481

350.000 4.079 0.2 + 515 0.4295 25.867 17159.

19855.8 150. 369 31.01 *6- 02 *89

360.000 3.921 0. 25503 0.4082 27.142 17509.5 20314.9 151.662 31.46 *5.83 *96

370.000 3.778 0.26472 0. 3891 28.384 17860.7 20772.7 152.917 31.92 *5.75 50*

360.000 3. 646 0.27425 0.3719 29.598 18213.4 21230.2 15*. 137 32.41 *5.76 510

390.000 3.526 0. 28363 0. 3564 30.786 18568.3 21688.2 155.326 32.91 *5.85 517

400.000 3.414 0.292SS 0.3422 31.950 18925.7 22147.4 156.489 33.42 *6.00 52*

420.000 3.215 0.31103 0. 3173 34.213 19650.3 23071.6 156. 7*3 34.49 *6.45 5 3o

* * 0 .000 3.041 0.32880 0.2962 36.402 20389.

24006.4 160.918 35.59 *7.05 5*8

460.000 2. 888 0.34624 0.2779 38.529 21145.7 24954.3 163. 024 36.70 *7.75 559

480.000 2.752 0.36340 0.2620 40.601 21919.5 25916.9 165.073 37.81 *8.53 570

500.000 2.629 0. 38033 0.2479 42.627 22712.0 26895.7 167.070 38.92 *9.35 580
METHANE ISOBAR AT P * 120.0 BAR

T OEN VOL DP/DT OP/ DO E H S CV CP

0£G K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

93.71<* 26.360 0.03524 20.3499 265.239 3512.4 3935.2 68.384 33.97 52.14 1593

99.000 26.272 0.03537 20.0460 260.530 3577.3 4001.7 69. 116 33.94 52.27 1581

100.000 27.666 0.03566 18.9253 244.013 3626.3 4256.6 71.815 34.02 52.90 1538

109.000 27.496 0.03637 17.8595 227.637 4081.4 4517.8 7*. 412 34.11 53.57 1493

110.000 27. 101 0.03690 16.6456 211.604 4341.3 4784.1 76.917 34.04 54.13 1446

119.000 26.699 0.03745 15.6807 196.055 4604.5 5054.0 79.333 33.81 54.56 1404

120.000 26.290 0.03834 14.9605 161.069 4670.2 5326.6 81.663 33.45 54.91 1361

129.000 25.873 0.03665 14.0614 166.767 5137.6 5601.5 83.912 33.06 55.26 1318

130.000 25. *46 0.03930 13.2400 153.122 5406.9 5876.5 86.087 32.70 55.69 1275

135.000 25.006 0.03999 12.4332 140.165 5676.4 6158.2 88.199 32.44 56.25 1231

140.000 24.556 0.04072 11.6563 127.869 5952.5 64*1.1 90.257 32.29 56.96 1186

145.000 24.096 0.04150 10. 9129 116.275 6229.9 6727.9 92.269 32.19 57.77 11*1

150.000 23.619 0. 0*234 10.1948 105.293 6510.6 7016.9 94.242 32.07 56.61 1095

155.000 23.127 0.04324 9.5022 54.913 6795.1 7314.0 96. 177 31.82 59.39 1051

160.000 22.617 0.0*421 6.8335 65.102 7062.1 7612.7 98.073 31.37 60.05 1008

165.000 22. 066 0. 0*527 6. 1674 75.836 7371.

1

7914.4 99.930 30.71 60.61 966

170.000 21.537 0.04643 7.5625 67.096 7661.6 6216.8 101.747 29.96 61.20 924

175.000 20.960 0.0*771 6.9581 58.877 7954.7 8527.2 103.533 29.84 62.60 877

160.000 20.353 0.0*913 6.3733 51.184 6254.1 6843.7 105.316 29.56 64.04 831

165.000 19.713 0.05073 5.8082 44.039 8559.5 9166.2 107.094 29.38 65.85 764

190.000 19.033 0.05254 5.2631 37.474 8672.3 9502.8 108.876 29.28 66.05 737

195.000 18.306 0. 05463 4.7392 31.531 9194.0 9849.5 110.679 29.26 70.71 669

200.000 17.527 0.05705 4.2389 26.252 9526.0 10210.7 112.508 29.30 73.86 642

205.000 16.690 0.05992 3.7650 21.675 9669.9 10586.9 114.376 29.40 77.53 597

210.000 15.790 0. 06333 3. 3212 17.621 10226.6 10966.6 116.293 29.54 81.67 554

215.000 14.626 0.0674* 2. 9108 14.706 10596.7 11406.0 118.266 29.69 86.03 515

220.000 13.817 0. 07238 2.5374 12.352 10977.6 11846.3 120.290 29.62 89.69 483

225.000 12. 766 0.07620 2.2062 10.008 11362.3 12300.6 122.332 29.63 91.59 456

230.000 11.797 0.08477 1.9236 10.114 11739.1 12756.3 124.335 29.60 90.06 436

235. 000 10.902 0. 09172 1.6932 10.133 12095.2 13195.9 126.226 29.52 85.46 428

240.000 10.124 0.09677 1.5066 10.433 12425.3 13610.6 127.972 29.42 60.51 422

2*5.000 9.450 0.10562 1. 3594 10.820 12732.2 14002.0 129.567 29.32 76.18 419

250.000 6.863 0. 11263 1.2364 11.266 13019.3 14373.2 131. 066 29.23 72. 34 417

255.000 6.352 0.11974 1.1341 11.866 13268.9 14725.7 132.463 29.16 68.71 418

2oO. 000 7.906 0.12646 1.0464 12.610 13542.9 15060.7 133.764 29.10 65.36 420

265.000 7.517 0.1330* 0.9759 13.367 13783.6 15360.0 135. 001 29.07 62.44 423

270.000 7.174 0.13939 0.9139 14.184 14013.2 15665.8 136. 144 29.06 59.95 427

275.000 6. 670 0 . 14556 0. 8602 14.983 14233.5 15980.2 137.224 29.06 57. 85 431

260.000 6.596 0.15156 0.8133 15.776 14446.2 16264.9 138.250 29.11 56.07 435

265.000 6. 353 0. 15740 0.7719 16.565 14652.5 16541.4 139.229 29.17 54.56 439

290.000 6. 131 0. 16311 0.7350 17.343 14653.6 16610.9 140.166 29.24 53.27 44*

295.000 5.928 0.16668 0. 7019 16.111 15050.2 17074.4 141.067 29.33 52.16 448

300.000 5.743 0. 17414 0.6721 16.869 15243.

1

17332.8 141. 936 29.43 51.21 452

310.000 5.413 0.18474 0.6204 20.352 15620.1 17836.9 143.569 29.66 49.69 461

320.000 5. 129 0. 19497 0.5770 21.794 15986.3 18327.9 145.146 29.98 48.57 469

330.000 4. 861 0.23468 0.5400 23.195 16350.7 18809.2 146.629 30.33 47.74 477

340.000 4.661 0.21452 0.5060 24.557 16709.2 19283.5 148. 045 30.71 , 47.15 465

350.000 4. *66 0.22393 0.4801 25.66* 17065.7 19752.9 149.406 31.12 1 46.75 492

360.000 4.269 0.23314 0.4554 27.175 17421.3 20219.0 150.719 31.56 46.49 500

370.000 4. 130 0.2*216 0.4334 26.436 17777.2 20633.1 151.990 32.02 46.35 507

360.000 3.964 0.25102 0.4137 29.669 16134.

1

21146.3 153.226 32.50 *6.31 513

390.000 3.650 0.25973 0.3959 30.675 18492.8 21609.6 154.429 33.00 46. 36 520

400.000 3.727 0.26632 0.3797 32.056 18653.6 22073.7 155.604 33.52 46.47 526

420.000 3.507 0.23516 0.3514 34.353 19564.7 23006.6 157.680 34.50 46. 65 539

440.000 3.315 0. 33162 0. 3274 36.573 20329.5 23946.9 160.072 35.67 47.40 550

460.000 3. 147 0.31775 0.3066 38.727 21090.4 2490 3.4 162.193 36.76 46.06 562

460.000 2.997 0.33362 0.2666 40.625 21668.5 25672.0 164.254 37.89 *6.60 573

500.000 2.663 0. 3*926 0.2730 42.674 22664.

6

26055.9 166. 262 39. 00 49.60 583

180
HET MANE ISOBAR AT P = 130.0 BAR

T OEN VOL OP/DT DP/DD E H S CV CP 4 DEG K MOL/L L/HOL BAR/K 8 AR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

93.964 28.398 0 . 03521 20.3205 266.410 3516.

3973.9 68.427 34.04 52.10 159*

95.000 28.310 0. 03532 20.0762 262.557 3568.

4028.

69.022 34.02 52.21 1585

100.000 27.926 0.03581 18.9638 246.242 3817.0 4232.5 71.715 34.10 52.83 1542

105.000 27. 539 0.03631 17.9056 230.034 4071.3 4543.3 74.309 34.16 53.48 1498

110.000 27.148 0.03684 16.6991 214.142 4330.2 4809.1 76.610 34. 12 54. 02 1454

115.000 26.750 0. 03738 15.9409 198.715 4592.4 5078.4 79.221 33.88 54.43 1411

120 .000 26.345 0.03796 15.0275 183.853 4856.9 5350.4 81.544 33.53 54.76 1368

125.000 25.932 0.03856 14. 1552 169.621 5123.1 5624.4 83.786 3 3.13 55.09 1326

130.000 25.510 0. 03920 13. 3206 156.057 5391.0 5900.6 85.955 32.78 55.49 1283

135.000 25. 078 0.03988 12.5208 143.175 5660.8 6179.2 88.058 32.52 56. 02 1240

140. 000 24.635 0 . 0*059 11.7531 130.971 5933.2 6460.9 90.107 32.36 56. 69 1196

145.000 24. 181 0.04136 11.0151 119.427 6208.6 6746.2 92.110 32.26 57.45 1151

150.000 23. 713 0. 0*217 10.3049 108,517 6487.2 7035.5 94. 071 32. 13 58.24 1107

155.000 23.230 0.04305 9.6206 98.211 6768.9 7328.5 95.992 31.89 58.96 106*

160.000 22.733 0.0*399 8.9608 88.478 7053.0 7624.9 97.874 31.44 59.53 1022

165.000 22.217 0.0*501 8. 3242 79.292 7338.6 7923.7 99.713 30. 77 59. 98 982

170.000 21.682 0 . 0*612 7.7097 70.633 7625.1 8224.7 101.510 30.01 60.44 942

175.000 21. 125 0 • 0*734 7.1165 62.493 7913.5 8528.9 103. 27 1 29. 86 61.67 897

ISO. 000 20.542 0.04868 6 • 5440 54.873 8207.3 8840.1 105.024 29.59 62.88 853

185.000 19.931 0.05017 5.9921 47.787 8505.9 9158.2 106.767 29.39 64. 38 808

190 .000 19.287 0. 05185 5.4613 41.259 8810.4 9484.5 108.507 29.27 66.19 763

195.000 18.606 0. 05375 4.9524 35.321 9121.9 9820.6 110.254 29.22 68.33 718

200.000 17.883 0. 05592 4.4672 30.006 9441.4 10168.3 112. 014 29.22 70.81 673

205.000 17. 116 0.05843 4.0079 25.342 9769.8 10529.3 113.797 29.27 73.63 630

210.000 16.301 0.06134 3.5771 21.345 10107.7 10905.1 115.608 29. 37 76. 74 590

215.000 15. 441 0.06476 3.1774 18.020 10455.1 11297.0 117.452 29.46 80.01 552

22Q. 000 14.542 0.06877 2.8109 15.368 10810.9 11704.9 119.327 29.39 82.88 520

225.000 13.619 0.07343 2.4801 13.399 11170.8 12125.3 121.217 29.41 85.05 492

230.000 12.702 0 . 07873 2. 1880 12.130 11529.7 12553.1 123. 097 29.42 85.67 *69

235.000 11.829 0.03454 1.9376 11.559 11379.2 12978.1 124.925 29.40 83.94 454

240. 000 11.035 0.09062 1.7295 11.571 12211.2 13389.2 126.656 29.36 80.30 44*

245.000 10. 334 0.03677 1.5588 11.851 12522.7 13780.7 128.271 29.30 76.3* 439

250.000 9. 71b 0. 10292 1.4176 12.215 12815.3 14153.4 129.777 29. 25 72.81 435

255.000 9. 170 0.10906 1.2992 12.637 13091.8 14509.5 131.187 29.20 69. 71 43*

260.000 8.685 0. 11514 1.1989 13.139 13354.1 14850.9 132.513 29.17 66.87 433

2o5 • 0 00 8.255 0. 1211* 1.1132 13.755 13603.7 15176.5 133. 761 29. 15 64. 19 43*

270.000 7.874 0.12701 1.0397 14.453 13842.0 15493.2 134. 938 29.16 61.73 437

275.000 7.534 0. 13274 0.9762 15.193 14070.7 15796.3 136.050 29.18 59.57 440

280.000 7.229 0.13833 0.9207 15.948 14291.0 16089.3 137.106 29.22 57.69 4*3

285.000 6. 955 0. 14379 0.8718 16.707 14504.4 16373.6 138.113 29.27 56.08 447

290.000 6. 706 0.14912 0.8284 17.464 14711.9 16650.5 139.076 29.35 5 4.69 450

295 .000 6.479 0.15434 0.7897 18.216 14914.4 16920.8 140. 000 29.44 53.49 4 5* 300.000 6.271 0.15945 0.7548 18.961 15112.8 17185.6 140. 890 29.54 52 . 46 458

310.000 5.90 4 0. 16938 0.6945 20.429 15499.5 17701.5 142.582 29.79 50.79 4 6o 320.000 5.587 0 . 17897 0.6441 21.864 15876.1 18202.8 144.174 3 0.09 49.54 474

330.000 5. 312 0.18827 0.6013 23.265 16245.8 18693.3 145.683 30. *3 *8.61 481

340.000 5. 068 0. 19731 0.5645 24.632 16610.9 19175.9 147.124 30.81 47.93 489

350. 000 4. 851 0.20612 0.5324 25.966 16973.0 19652.7 148.506 31.22 *7.45 496

360.000 4.657 0.21474 0. 5042 27.269 17333.8 20125.5 149.838 31.66 *7.13 503

370.000 4.481 0.22318 0.4791 28.542 17694.

20595.7 151.126 32. 12 *6.9* 510

380.000 4.320 0.23147 0.4567 29.788 18055.5 21064.6 152.376 32.60 46.85 517

390.000 4. 173 0.23962 0.4365 31.008 18418.0 21533.0 153.593 33.09 46. 85 523

400.000 4. 038 0.2*764 0.4182 32.203 18782.6 22001.9 154.780 33.61 46.93 529

420.000 3. 797 0. 2o335 0. 3862 3*. 528 19519.7 22943.3 157. 077 34.66 47.25 542

440.000 3.588 0.27869 0. 3593 36.774 20270.0 23893.0 159. 286 35.75 47.75 553

460.000 3.405 0. 29372 0.3361 38.953 21035.6 24854.0 161.421 36.86 *8.37 5 6* 480.000 3.242 0.30849 0.3161 41.073 21818.

25828.163.495 37.97 *9.08 575

500.000 3.096 0.32303 0.2985 43.143 22618.0 26817.4 165.513 39.07 *9.8* 5 8o

181
HETHftNE ISOBAR ft T P s 140.0 BAR

f OEM VOL 0P/OT OP/DO E H S CV CP M DEG K MOL/L L/MQL B&R/K SftR-L/MOL J/HGL J/HOL J/HOL/K J/MOL/K J/MOL/K fl/SEC

94.213 20.417 0.03519 20.2913 267.568 3519.9 4012.6 68.470 34.12 52.07 1595

99.000 20.346 0.03526 20.1055 264.551 3560.4 4054.2 68.927 34.09 52.16 1588

100.000 27.967 0.03576 19.0013 248.439 3807.9 4308.5 71.617 34.18 52.76 1546

105.000 27.663 0.0 3625 17.9507 232.401 4061.3 4568.9 74.207 34.26 53.39 1503

110.000 27.194 0.03677 16 o 9512 216.652 4319.4 4834.2 76.703 34.19 53.92 1459

115.000 26.600 0.03731 15.9999 201.345 4580.6 5103.0 79.109 33.96 54.31 1417

120.000 26.399 0.03788 15.0931 186.566 4343.9 5374.3 81.427 33.60 54.62 1375

123 » 000 25.991 0. 03648 14.2274 172.445 5108.9 5647.5 83.663 33.21 54.93 1333

130.000 25.574 0.03910 13.3994 158.960 5375.4 5922.® 85.825 32.85 55.30 1292

135.000 25. 147 0. 03977 12.6063 146.151 5643.7 6200.4 87.921 32.59 55.80 1249

140.000 24.711 0. 04047 11.9454 134.014 5914.4 6480.9 89.961 32.43 56.43 1206

145.000 24.263 0.04121 11. 1145 122.537 6187.9 6764.9 91.954 32.33 57.16 1162

190.000 23. 803 0.04201 10.4117 111.693 6464.4 7052.6 93.904 32.20 57.90 1119

153.000 23.331 0. 0-*2®6 9.7352 101.455 6743.7 7343.8 95.614 31.95 58.55 1077

160. 000 22. 643 0. 04378 9.0835 91.792 7025.0 7637 .9 97.681 31.50 59.06 1036

165.000 22.341 0.0^476 8.4556 82.678 7307.5 7934.1 99.504 30.83 59.42 997

120.009 21.620 0.04583 7.8504 74.092 7590.4 8232.0 101.283 30.06 59.76 958

175.000 21.280 0.04699 7.2672 66.021 7874.6 8532.5 103.022 29.93 60.84 915

190.009 20.719 0.04827 6.7054 58.465 8163.4 8839.1 104.790 29.62 61.87 872

105.000 20. 132 0.04967 6.1650 51.430 8456.2 9151.6 106.462 29.41 63.14 830

190.000 19.519 0. 05123 5.6461 44.935 8753.7 9470.9 108.165 29.27 64.65 787

195.000 16.675 0. 05298 5.1496 39.003 9056.

8

9798.5 109.866 29.19 66.41 744

200.000 10.196 0.05495 4.6768 33.659 9366.1 10135.4 111.572 29.17 68.41 701

205.000 17.405 0.05719 4.2292 26.925 9682.

3

10483.0 113.289 29.19 70.66 661

210.000 16.735 0.05975 3.8090 24.813 10005.8 10842.3 115.020 29.25 73.09 622

215.000 15.951 0.06269 3.4178 21.323 10336.4 11214.1 116.770 29.34 75.63 585

220.000 15.135 0.06607 3.0573 18.450 10673.5 11598.5 118.537 29.22 77.87 554

225.000 14.298 0.06994 2.7287 16.187 11013.9 11993.1 120.311 29.23 79.86 5 25 230.000 13.456 0.07432 2.4334 14.531 11355.3 12395.7 122.060 29.25 81.02 501

235.000 12.632 0.07917 2.1729 13.476 11692.7 12801.0 123.824 29.26 80.86 482

240.000 11.852 0. 03437 1.9483 13.007 12020.4 13201.6 125.510 29.26 79.12 468

245.000 11.140 0.08977 1.7586 13.018 12333.3 13590.1 127.113 29.25 76. 15 460

290.000 10.501 0.09523 1.5999 13.282 12629.5 13962.7 128.618 29.23 72.91 454

255.000 9.932 0.10068 1 * <*664 13.630 12910.2 14319.8 130.033 29.21 69.99 451

260.000 9.423 0. 10613 1. 3528 14.027 13177.3 14663.1 131.366 29.20 67.40 449

265.900 8.965 0. 11154 1.2551 14.475 13432.7 14994.2 132.628 29.20 65.09 448

270.000 8.554 0. 11691 1.1706 15.004 13677.5 15314.2 133.624 29.22 62.92 449

275.000 0.184 0.12220 1.0971 15.621 13912.9 15623.7 134.960 29.25 60.89 450

200.000 7.85 0 0.12739 1.0328 16.298 14140.0 15923.4 136.040 29.30 59.03 452

205.000 7.548 0.13248 0.9761 17.006 14359.7 16214.4 137.070 29.36 57.39 455

290.000 7.275 0.13746 0. 9259 17.728 14573.1 16497.6 138. 055 29.44 55.94 458

295.000 7.025 0.14235 0.8811 18.453 14781.2 16774.1 139.000 29.53 54.68 461

300.000 6.796 0.14714 0.8409 19.179 14984.7 17044,7 139.910 29.64 53.58 465

310.000 6.391 0. 15646 0.7715 20.618 15380.7 17571.2 141.637 29.89 51.80 472

320.000 6. 043 0. 16548 0.7137 22.034 15765.4 16082.1 143.25 9 30.19 50.45 479

330.000 5.740 0.17422 0.6649 23.425 16142.2 18581.2 144.795 30.53 49.43 486

340.000 5.473 0.18272 0.6229 24.787 16513.5 19071.6 146.259 30.91 48.67 493

350.000 5.236 0.13100 0.5865 26.121 16861.4 19555.4 147.661 31.31 •*8.13 500

360.000 5. 022 0. 19910 0.5545 27.427 17247.2 20034.6 149.011 31.75 47.75 507

370.000 4.830 0.20704 0.5261 28.707 17612.2 20510.8 150.316 32.21 47.50 514

360.000 4 . b5 5 0.21482 0.5008 29.960 17977.5 20985.1 151.581 32.69 47.37 520

390.000 4.495 0.22247 0 • *761 31.188 18343.9 21458.5 152. 810 33.18 47.33 527

400. 000 4.348 0.23000 0.4576 32.393 18711.9 21931.9 154.009 33.69 47.37 533

420.000 4. 086 0.24474 0.4218 34.739 19455.3 22881.7 156.326 34.75 47.64 545

440.000 3.059 0.25912 0. 3917 37.007 20211.0 23838.6 158.552 35.83 48.09 556

460.000 3.660 0.27319 0. 3660 39.206 20981.

3

24805.9 160.701 36.94 48.67 567

460.000 3.484 0.28700 0.3438 41.346 21767.9 25785.9 162.787 38.04 49.34 578

500.000 3.327 0.30059 0.3243 43.433 22571.7 26780.1 164.816 39. 14 50.08 589

182

t
METHANE ISOBAR AT P * 150.0 BAR

T DEN WOL OP/DT DP/DD E H S CM CP w OEG K MOL/L L/MOL 8AR/K 8AR-L/M0L J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

94. 461 26.436 0.03517 20.2623 266.712 3523.8 4051.3 68.513 34.19 52.04 1597

95.000 26.386 0.03523 20.1340 266.512 3552.1 4080.5 68.833 34.17 52.10 1592

100.000 28.007 0.03571 19. 0380 250.605 3798.9 4334.5 71.520 34.25 52.63 1550

105.000 27.625 0.03620 17.994® 234.737 4051.6 4594.5 74. 106 34. 33 53. 31 1507

110.000 27.240 0. 03671 17.0023 219.131 4308.7 4859.3 76.598 34.26 53.82 1465

115.000 26.849 0. 03725 16.0576 203.945 4566.9 5127.6 78.999 34.03 54.20 1423

120.000 26.452 0.03780 15.1573 189.290 4831.2 5398.3 81.312 33.67 54.49 1382

125.000 26.046 0.03839 14.2980 175.237 5095.0 5670.8 83-542 33.26 54.77 1341

130.000 25.636 0.03901 13.4764 161.830 5360.

5945.2 85.697 32.92 55.12 1303

135.000 25.215 0.03966 12.689® 149.091 5627.0 6221.9 87.786 32.66 55.59 1258

1 AO . 0 00 24. 785 0.04035 11.9355 137.020 5896.1 6501.3 89.81® 32.50 56.19 1215

145.000 24.344 0. 04108 11.2113 125.605 6167.8 6783.9 91.802 32.40 56.88 1172

150.000 23.892 0.04186 10.5154 114.824 6442.3 7070.1 93.742 32.27 57.57 1130

155.000 23.428 0.04268 9.8461 104.648 6719.3 7359.6 95. 6**0 32.02 58.18 1089

160.000 22.951 0 • 0>* 357 9.2021 95.049 6998.1 7651.7 97.494 31.56 58. 62 1049

165.000 22. 459 0. 04453 8.5822 86.000 7277.7 7945.6 99.303 30.88 58.90 1011

lro.ooo 21.952 0.04555 7.9855 77.479 7557.3 8240.6 101. 064 30.11 59. 1** 974

175.000 21.428 0.04667 7.4111 69.471 7837.7 8537.7 102.784 29.97 60.11 932

100.000 20.885 0.04788 6.8588 61.971 8122.1 6840.4 104. 489 29.66 60.98 891

105.000 20.320 0.04921 6.3283 54.982 8409.7 9147.9 106. 174 29.43 62. 07 850

190.000 19.733 0.05068 5.8190 48.516 8701.2 9461.4 107. 846 29.28 63.3*+ 809

195.000 19. 120 0.05230 5. 3337 42.589 8997.2 9781.7 109. 510 29.19 64.82 768

200.000 18.460 0.05411 4. 8712 37.222 9298.

10109.8 11 £..,17 2 29. 14 66.47 728

205.000 17.811 0.05614 4.4334 32.430 9604.5 10446.7 lltW35 29.14 68.30 688

210.000 17. 113 0.05843 4.0217 28.223 9916.5 10793.1 11-*. 505 29.17 70.27 651

215.000 16.387 0.06102 3.6376 24.600 10234.1 11149.5 116. 182 29.23 72.30 fc Id 220.000 15.636 0. 06396 3. 2822 21.551 10556.6 11516.0 117.867 29.09 74.07 585

225.000 14.867 0.06726 2.9561 19.064 10881.7 11890.7 119.551 29.09 75.76 55 a 230.000 14.089 0.07098 2.6601 17.127 11208.1 12272.8 121.230 29.11 76.98 531

235. 000 13.319 0. 07508 2.3946 15.726 11533.0 12659.2 122.892 29.14 77. hh 510

240.000 12. 573 0.07954 2. 1601 14.847 11852.4 13045.5 124.519 29.16 76.88 494

245.000 11. 670 0.08425 1.9565 14.456 12162.4 13426.1 126.089 29.18 75.22 482

250.000 11.223 0.08910 1.7823 14.473 12459.8 13796.3 127. 585 29.19 72.75 4 7 1* 255.000 10.638 0.09400 1.6342 1«*.723 12743.3 14153.3 128. 999 29.20 70-07 469

260.000 10.111 0.09890 1.5078 15.058 13013.8 14497.4 130.335 29.21 67.61 466

265.000 9.635 0. 10379 1.3989 15.439 13272.9 14829.8 131.601 29.23 65.42 46>* 270.000 9.203 0.10866 1. 3043 15.859 13522.0 15151.9 132.806 29.26 6 3 . *.6 463

275.000 8.811 0.11350 1.2214 16.329 13762.2 15464.7 133.953 29.31 61.67 463

200.000 8. 454 0.11829 1.1485 16.874 13994.4 15768.8 135.049 29.36 59.99 4o4

205.000 8.129 0. 12302 1.0841 17.487 14219.5 16064.8 136.097 29.43 5 8.42 465

290.000 7.833 0.12767 1.0269 18.144 14438.2 16353.2 137.101 29.52 56.99 467

295.000 7.562 0. 13224 0.9758 18.826 14651.3 16634.9 138. 064 29.61 55.71 470

300.000 7.313 0.13674 0.9300 19.519 14859.5 16910.6 138.990 29.72 54.58 473

310.000 6.873 0. 14550 0.8512 20.914 15264.2 17446.6 140.748 29.98 52.71 479

320 .000 6.494 0. 15398 0.7857 22.302 15656.6 17966.2 142.398 30.28 51.28 485

330.000 6.165 0. 16221 0.7304 23.673 16040.2 18473.3 143.956 30.62 50.19 492

340.000 5. 875 0. 17022 0.6331 25.0 23 16417.6 18970.9 145 .444 31.00 49.37 49a

350.000 5.617 0.17804 0.6421 26.350 16790.8 19461.4 146.866 31.40 •8.76 505

3b0. 000 5. 386 0.18568 0.6061 27.652 17161.6 19946.7 146.233 31.84 48.33 512

370.000 5.177 0.19316 0.5744 28.931 17531.1 20428.5 149. 553 32.30 46.04 518

300.000 4. 988 0.20050 0.5461 30.187 17900.5 20907.9 150.832 32.78 47. 87 524

390.000 4.814 0.20771 0.5208 31.419 18270.5 21386.2 152. 074 33.27 47.79 530

400.000 4. 655 0.21480 0.4979 32.630 16642.0 21864.1 153.284 33.78 47.60 536

420.000 4.373 0.22869 0.4582 34.989 19391.5 22821.8 155.620 34.83 48.0 1 548

440.000 4.129 0.24222 0. 4248 37.273 20152.5 23785.8 157.862 35.91 48.41 560

460.000 3.915 0.25545 0.3964 39.488 20927.5 24759.3 160.Q26 37.01 48.96 571

4SC.000 3.725 0.26843 0. 3719 41.644 21718.3 25744.8 162. 123 38.12 49. fc J 58 1 500.000 3.556 0.28120 0. 3505 43.747 22525.9 26743.9 16**. 162 39.21 50. 32 592

183
METHANE ISOBAR AT P = 160.0 BAR

T OEN VOL DP/DT OP/DD E H S C V CP ri OEG K HOL/L L/HQL 8AR/K 8AR-L/M0L J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

94.709 26. 455 0.03514 20. 2336 269.843 3527.7 4090.0 68.556 34.26 52.01 1598

95.000 23.423 0.03516 20. 1617 268.440 3544.0 4106.9 68.740 34.24 52.05 1595

100.000 23. 047 0.03565 19.0738 252.740 3790.1 4360.5 71.423 34.32 52.62 155*

105.000 27.66® 0.03614 16. 0379 237.044 4041.9 4620.2 74. 006 34.40 53.23 1512

110.000 27.265 0. 03665 17.0524 221.562 4298.2 4884.6 76.494 34.34 53.73 1470

115.090 26. 693 0.03716 16. 1142 206.517 4557.5 5152.3 78.891 34.10 54.09 1429

120.000 26.505 0. 03773 15.2202 191.964 4818.7 5422.4 81.199 33.75 54.36 1388

125.000 26.105 0.03831 14. 3671 178.000 5081.3 5694.3 83.423 33.35 54.62 1348

130.000 25.697 0.03691 13.5517 164.670 5345.2 5967.9 05.571 32.99 54.95 1307

135.000 25.282 0.03955 12.7713 151.999 5610.7 6243.6 87.653 32.73 55.40 126o

140.000 24.857 0.04023 12.0233 139.991 5878.2 6521.9 89.677 32.57 55.97 1225

145.000 24. 422 0. 04095 11.3056 128.635 6148.2 6803.4 91.65 3 32.46 56.62 1183

150.000 23. 976 0.04171 10.6163 117.912 6420.6 7088.1 93.583 32.33 57.27 Il4l

155.000 23.522 0.04251 9.9538 107.794 6695.8 7376.0 95.471 32.08 57. 63 1101

160.000 23.054 0.04338 9. 3169 98.254 6972.2 7666.2 97. 313 31.62 58. 22 1062

165. Q 00 22. 573 0. 04430 8.7044 89.264 7249.1 7957.9 99.108 30.94 58.43 1025

170.000 22.079 0.04529 6. 1153 80.801 7525.7 8250.3 100.855 30.16 58.59 989

175.000 21.563 0.04636 7.5491 72.849 7802.6 8544.4 102.557 30.02 59.45 948

100.000 21. 042 0.04752 7.0052 65.399 8083.1 8843.5 104. 242 29.69 60.20 909

105.000 20.497 0. 04879 6.4834 58.450 6366.

1

91*6.7 105.903 29.46 61. 13 869

190.000 19.932 0.05017 5.9836 52.010 8652.

3

9455.0 107.548 29.30 62.22 830

195.000 19.346 0.05169 5.5066 46.090 8942.2 9769.2 109. 180 29.19 63.47 790

200.000 18.737 0.05337 5. 0530 40.704 9236.0 10090.0 110.604 29.13 64.86 752

205.000 16. 104 0 . 05524 4.6234 35.864 9534.3 10418.0 112.424 29.10 66.38 714

210.000 17.448 0.05731 4.2191 31.577 9836.9 10754.0 114. 043 29.11 60.00 670

215.000 16.769 0.05964 3.8409 27.842 10144.0 11098.1 115.662 29. 15 69. b7 64*

220.000 16.069 0.06223 3.4898 24.648 10454.9 11450.6 117.283 2 9.00 71.09 61*

225.000 15.355 0.06513 3. 1662 21.961 10767.6 11809.7 118.897 26.98 72.51 585

230.000 14.632 0.05634 2.8703 19.824 11061.7 12175.2 120.503 29.00 73.65 560

235.000 13.911 0.07189 2.6022 18.160 11395.2 12545.4 122.096 29.03 74.32 538

240.000 13.203 0.07574 2.3619 16.970 11705.5 12917.3 123.662 29.07 74. 33 520

245.000 12.523 0.07985 2. 1491 16.231 12009.7 13287.3 125.188 29.11 73.56 506

250.000 11.683 0.08415 1.9629 15.908 12305.1 13651.6 126.659 29. 14 72.02 495

255.000 11.291 0.08856 1.8019 15.932 12589.6 14006.6 128.066 29.17 69.93 480

260.000 10.752 0.09301 1.6632 16.171 12862.5 14350.6 129. 401 29.20 67. 67 483

265.000 10. 261 0. 09745 1.5433 16.496 13124.

3

14683.6 130.670 29.24 65.53 480

270.000 9. 615 0.13189 1.4389 16.864 13376.5 15006.7 131.878 29.29 63.73 478

275.000 9.406 0. 10631 1.3473 17.266 13620.0 15320.9 133.031 29.34 62.02 477

260.000 9.033 0. 11071 1.2665 17.703 13855.9 15627.2 134. 135 29.41 60.50 47b

265.000 8.690 0. 11507 1.1946 18.192 14084.9 15926.1 135.193 29.49 59. 09 477

290.000 8.375 0.11940 1.1306 18.745 14307.9 16218.2 136.209 29.58 57.77 479

295.000 8. 066 0.12367 1.0733 19.351 14525.3 16504.0 137.186 29.68 56. 54 479

300.000 7.820 0. 12788 1. 0218 19.990 14737.7 16783.8 138. 127 29.80 55.42 481

310.000 7.347 0.13611 0.9332 21.318 15150.3 17326.

1

139.912 30.06 53.52 486

320.000 6.939 0 . 14411 0. 6597 22.665 15549.9 17855.6 141.587 30.36 52.03 492

330.000 6.584 0.15187 0.7976 24.009 15939.9 18369.9 143. 170 30.71 50.89 *98

340.000 6.272 0. 15944 0.7449 25.339 16323.

1

18874.2 144.675 31.08 50.01 504

350.000 5.994 0.16683 0.6991 26.651 16701.6 19370.9 146. 115 31.49 49.36 510

360.000 5.745 0.17405 0.6591 27 . 945f 17077.1 19861.9 147.498 31.93 48.88 51 o 370.000 5.521 0.18112 0.6238 29.218 17451.0 20349.0 148.833 32.36 *6. 55 523

360.000 5. 317 O. 18806 0.5925 30.470 17824.4 20833.4 150.124 32.86 48. 34 529

390.000 5.131 0.19488 0. 5644 31.702 18198.1 21316.2 151.379 33.35 48.24 535

400.000 4.961 0.20159 0.5390 32.914 18572.9 21798.4 152.599 33.86 48.21 540

420.000 4.65 7 0.21471 0.4952 35.280 19326.5 22763.8 15-.. 955 34.91 48. 37 552

440. 000 4. 39b 0.22749 0.4585 37.573 20094.7 23734.6 157.212 35.99 48.73 563

460.000 4. 167 0.23999 0.4273 39.801 20874.4 24714.1 159.390 37.09 *9. 24 574

460.000 3.965 0.25224 0.4004 41.969 21669.2 25705.0 161..49 8 38.19 49.86 584

500.000 3.764 0.26428 0.3770 44.064 22480.5 26708.9 163.547 39.29 50.55 595
METHANE ISOBAR ATP* 170.0 BAR

T DEN VOL OP/QT OP/DO E H S CV CP ri DEG K MOL/L L/MOL SAR/K 8AR-L/M0L J/NOL J/MOL J/MOL/K J/HOL/K J/NOL/K H/ SEC 94.956 28.473 0.03512 20.2052 270.961 3531.7 4128.7 68.599 34.33 51.98 1599

95.000 28.460 0.03514 20.1865 270.335 3535.9 4133.2 68.647 34.32 52.00 1598

100.000 28. 086 0. 03560 19. 1087 254.843 3781.3 4386.6 71.328 34.40 52.56 1553

105.000 27. 710 0.03609 18. 0802 239.322 4032.4 4645.9 73.907 34.47 53.15 1517

110.000 27.330 0.03659 17.1014 224.004 4287.9 4909.9 76.391 34.41 53.63 1475

115.000 26.946 0.03711 16.1696 209,061 4546.3 5177.1 78.784 34. 17 53. 98 1435

120.000 26. 556 0. 03766 15.2819 194.610 4806.5 5446.6 81.086 33.82 54.23 1395

125.000 26. 161 0.03823 14.4348 180.733 5068.0 5717.8 83.305 33.42 54.48 1355

130.000 25.750 0 . 03082 13.6254 167.479 5330.7 5990.7 85.447 33.06 54. 73 1315

135.000 25.347 0.03945 12.8510 154.375 5594.8 6265.5 87.523 32.80 55.21 1275

140.000 24. 928 0.04012 12.1091 142.927 5860 .8 6542.8 89.540 32.63 55.75 1234

145.000 24.499 0.0*082 11.3975 131.620 6129.2 6823.1 91.507 32.53 56.37 1192

150.000 24. 061 0.0*156 10.7145 120.959 6400.0 7106.5 93.420 32.40 56,99 1152

155.000 23.613 0.0*235 10.0584 110.895 6672.9 7392.9 95.306 32. 14 57.50 1112

160.000 23.154 0.04319 9.4281 101.409 6947.1 7681.3 97.137 31,68 57.84 107*

lo5. 000 22.683 0.0*409 8.8224 92.472 7221.5 7971.0 98.920 31.00 57.99 1038

170.000 22.200 0.0*505 8.2405 84.062 7495.3 8261.1 100.652 30.21 58.08 100*

175.000 21.703 0 « 0*608 7.6816 76.161 7769.1 8552.4 102.338 30.07 58. 35 96*

100.000 21. 191 0.04719 7.1452 68,756 8046.0 8848.2 104.005 29.73 59.50 926

105.000 20.863 0.04840 6.6312 61.844 3325.0 91*7.7 105.646 29.49 60.33 888

190.000 20.110 0.0*971 6.1395 55.427 8606.5 9451.5 107.266 29.32 61.2* 850

195. 000 19.555 0. 05114 5.6703 49.513 8091.0 9760.3 108.871 29.20 62.31 612

200.000 18.973 0. 05271 5.2241 44.112 9170.8 10074.8 110.463 29.12 63.50 77*

205.000 18.371 0. 05443 4. 8016 39.232 9470.1 10395.5 112.046 29.08 64.78 738

210.000 17.749 0.05634 4.4035 34.877 9764.9 10722.7 113.624 29.08 66.1* 703

215.000 17. 109 0. 05845 4. 0305 31.047 10063.3 11056.9 115.196 29.10 o7 . 5 3 670

220.000 16.452 0 . 06078 3.6832 27.730 10364.7 11398.0 116.765 26.93 6 8.69 641

225.000 15.782 0.06336 3.3619 2*. 913 10667.3 117*4.5 118.322 28.90 69.89 613

230.000 15. 10* 0. 06621 3.0665 22.576 10971.1 12096.6 119.869 26. 91 70.91 587

235.000 14.426 0. 06932 2.7970 20.701 11274.7 12453.1 121.403 28.95 71.62 565

240.000 13.756 0.07269 2.5529 19.266 11576.3 12812.1 122.914 28.99 71.89 546

245.000 13. 104 0.07631 2.3339 18.250 11873.8 13171.1 124.395 29.04 71.62 530

250.000 12.481 0. 08012 2. 1393 17.627 12165.

13527.2 125.834 29.09 70.76 517

255.000 11.893 0.03408 1.9679 17.360 12440.3 13877.7 127. 222 29.13 69.35 508

260.000 11.348 0.08812 1.8182 17.394 12722.1 14220.1 128.552 29.18 67.55 501

265.000 10.048 0.09210 1.6878 17.623 12985.9 14553.0 129.820 29.24 65-6* *97

270.000 10. 390 0.09625 1. 5739 17.940 13240.4 14876.6 131.030 29.30 63.84 49*

275.000 9. 969 0.10031 1.4738 18.299 13486.4 15191.7 132.186 29.37 62.21 *92

2 SO . 0 00 9.583 0.11435 1.3853 18.688 13725.0 15499.1 133.294 29.44 60.76 *90

285.000 9.227 0. 10038 1.3065 19.105 13957.0 15799.5 134.357 29.53 59.44 490

290.000 8.890 0. 11238 1.2360 19.558 14183.1 16093.7 135.381 29.63 58.24 490

295.000 8.594 0.11636 1.1727 20.060 14403.9 16302.1 136.367 29.74 57.12 490

300.000 8.313 0. 12030 1.1157 20.616 14620.0 16665.0 137.318 29.86 56.07 491

310.000 7.810 0.12803 1.0172 21.835 15039.6 17216.1 139.125 30.13 54.21 495

320.000 7.376 0.13557 0.9356 23.122 15445.7 17750.4 140.821 30.44 52.70 500

330.000 6.997 0.1*291 0. 8669 24.428 15841.

18271.3 142.424 30.79 51.52 505

340.000 6.664 0.15007 0.6082 25.731 16230.5 18761.7 143.9*8 31.16 50.60 510

350.000 6.367 0. 15706 0.7575 27.024 16614.

19284.0 145.404 31.57 49.91 516

360.000 6.101 0.15390 0.7133 28.303 16994.1 19780.4 146.80 3 32.01 *9.39 522

370.000 5.861 0. 17061 0.6744 29.566 17372.1 20272.4 148. 151 32.47 *9.0 3 528

380.000 5. 644 0.17719 0.6398 30.811 17749.3 20761.5 149.455 32.94 *8.79 533

390.000 5.445 0. 18365 0.6088 32.038 18126.6 21248.6 150.720 33.44 48.66 539

400.000 5.263 0.19001 0.5810 33.247 18504.7 21734.9 151.951 33.94 *8.61 545

420.000 4. 94 0 0. 20245 0.5329 35.612 19266.

22707.7 154. 325 34.99 *8. 72 55o

440.000 4.661 0.21456 0 . *927 37.910 20037.5 23605.

156.598 36.07 *9.0* 567

460.000 4.417 0.22639 0.4587 40.145 20821.7 24670.4 158. 788 37.16 *9.52 577

480.000 4.202 0.23799 0.4294 42.322 21620.6 25666.5 160.907 38.26 50.11 580

500.000 4.010 0.24939 0.4039 44.446 22435.5 26675.2 162.966 39.36 50.77 598

185
METHANE ISOBAR AT P = 180*0 BAR

T DEN OOL OP/DT DP/DD E H S CV CP M 0E6 K HOL/L L/HOL 8AR/K BAR-L/MQL J/MOL J/MOL. J/MOL/

K

J/WOL/K J/HOL/K H/SEC

95.202 28. 492 0. 03510 20. 1771 272.066 3535.7 4167.5 68.642 34.41 51.96 1600

100.000 28.125 0.03556 19. 1428 256.916 3772.7 4412.7 71.233 34.47 52.50 1562

105.000 27.751 0. 03603 18.1215 241.569 4023.1 4671=7 73. 809 34.54 53.08 1521

110.000 27.375 0=03653 17.1494 226.396 4277.7 4935.3 76.290 34.48 53.55 1480

115.000 26.994 0.03705 16.224® 211.576 4535.2 5202.0 78.678 34.24 53.88 1440

120.000 26. 607 0.03758 15. 3423 197.228 4794.5 5471.0 80.976 33.89 54.11 1401

125.000 26.215 0.03815 14.5011 183.438 5054.9 5741.5 83.189 33.49 54 . 34 1362

130.000 25.817 0. 03673 13.6976 170.259 5316.4 6013.6 85. 326 33. 13 54.63 1323

135.000 25. 411 0.03935 12.9290 157.720 5579.

2

6287.6 87.395 32.87 55.03 1283

140.000 24.997 0.04001 12. 1929 145,831 58*3.9 6564o0 89.405 32.70 55.54 1243

145.000 24. 574 0. 04069 11.4872 134.506 6110.7 6843.1 91.364 32.59 56.14 1202

150. 000 24. 143 0. 04 142 10.8101 123.968 6379.8 7125.

3

93.277 32.46 56.72 1162

155.000 23. 702 0.04219 10.1602 113.954 6650.8 7410.2 95. 145 32.21 57.20 1123

160.000 23.251 0.0-430 1 9.5361 104.517 6922.9 7697.1 96.966 31.74 57.49 1086

165.000 22. 790 0.04388 8.9367 95.630 7195.0 7 984.8 98.737 31.05 57.59 1051

170.000 22. 317 0. 0*481 8. 3613 87.268 7466.2 8272.8 100.457 30.27 57.61 1018

175.000 21.831 0 . 04581 7.8091 79.412 7737.1 8561.6 102.128 30.11 58.31 979

180.000 21. 333 0 . 0*688 7.2796 72.048 8010.7 0854.5 103.778 29.78 58.67 942

185.000 20 o 821 0 = 0*803 6.7726 65.168 8286.0 9150.5 105.400 29.53 59.57 905

190.000 20.293 0.04928 6.2879 58.773 8563.3 9450.3 107.000 29.35 60.38 868

195.000 19.750 0. 05063 5.8256 52.866 6843.1 9754.5 108.580 29.21 61.31 832

200.000 19.191 0 . 05211 5. 3861 47.452 9125.6 10063.6 110.145 29.12 62.32 796

205.000 18.615 0. 05372 4. 9697 42.538 9410.

9

10377.9 111.697 29.07 63.42 761

210.000 18.023 0 . 05548 4.5770 38.125 9699.1 10697.9 113.239 29.05 64.58 727

215.000 17.415 0.05742 4.2085 34.213 9990.1 11023.7 114.772 29.06 65.76 695

220 . 000 16. 794 0 . 05955 3.8646 30.791 10283.6 11355.4 116.298 28.88 66.71 666

225. 000 16. 161 0. 06188 3. 5454 27.845 10577.8 11691.6 117.808 28.84 67.73 638

230. 000 15.522 0 • 0644

2

3.2507 25.356 10872.9 12032.5 119.30 7 26.84 68.63 613

235.000 14.881 0 . 06720 2.9803 23.305 11167.9 12377.5 120.791 28.88 69.32 591

21.0.000 14.246 0.07020 2.7337 21.671 11461.6 12725.2 122. 255 28.92 69.70 571

245.000 13.622 0.07341 2.5103 20.430 11752.5 13073.9 123.693 28.90 69.70 553

250.000 13. 019 0. 07681 2.3096 19.560 12038.9 13421.5 125.097 29.04 69.26 539

255 .000 12.444 0.0303b 2.1304 19.032 12319.2 13765.7 126.460 29.10 68.37 528

260 .000 11. 902 0. 03402 1.9717 18.814 12592.1 14104.5 127. 776 29.16 67.09 519

265.000 11.397 0. 08774 1.8319 10.857 12856.7 14436.1 129. 040 29.23 65.5* 513

270.000 10.930 0.091*9 1.7069 19.080 13112.9 14759.7 130.249 29.30 63.09 509

275.000 10. 500 0 .09524 1.6005 19.389 13361.0 15075.2 131.407 29.36 62. 34 506

280.000 10.103 0. 09898 1 . 5U45 19.740 13601.7 15383.3 132.516 29.47 60.92 504

285.000 9. 737 0.10270 1.4169 20.119 13636.0 15684.7 133.584 29.57 59.65 503

290.000 9.397 0. 10641 1.3423 20.523 14064.6 15980.0 134.612 29.67 58.50 502

295.000 9.062 0.11011 1.2733 20.953 14287.9 16269.9 135.603 29.79 57.46 502

300.000 8.789 0.11378 1.2109 21.418 14506.7 16554.8 136.560 29.91 56.50 502

310.000 8.262 0.12134 1.1029 22.484 14932.2 17110.9 138.384 30.19 54.76 50*

320.000 7.804 0. 12814 1.0131 23.679 15344.3 17650.9 140.099 30.51 53.28 508

330.000 7. •0 3 0. 135D9 0.9374 24.930 15745.9 18177.5 141. 719 30.66 52. 08 512

340.000 7.049 0.14137 0.8729 26.199 16139.8 18633.4 143.259 31.24 51.14 517

350.000 6.734 0. 1*850 0.8172 27.466 16528.0 19201.0 144.731 31.65 50.42 522

360.000 6.452 0. 15499 0.7666 20.726 16912.4 19702.3 146.143 32.09 49.87 528

370.000 6. 197 0. 1613b 0.7259 29.973 17294.5 20198.9 147.504 32.54 49.48 533

380.000 5.966 0.16761 0.6880 31.207 17675.4 20692.3 148.820 33.02 49.21 538

390.000 5. 755 0.17375 0.6541 32.426 18056.1 21183.6 150.096 33.52 49.05 544

400.000 5.562 0.17979 0.6237 33.629 18437.4 21673.7 151.336 34.02 48. 98 549

420. 000 5. 219 0. 19161 0. 5712 35.987 19204.6 22653.6 153.727 35.07 49.05 560

440 .000 4.923 0.20312 0.5275 38.284 19981.0 23637.1 156. 015 36.15 49.34 571

4 o 0 . 0 00 4. 665 0.21436 0.4905 40.521 20769.

7

24628.2 158.217 37.24 49.79 531

480.000 4.437 0.22538 0.4587 42.702 21572.6 25629.3 160.348 36.33 50. 35 591

500.000 4.234 0.23619 0.4311 44.833 22391.1 26642.6 162.416 39.43 50.99 601

186
METHANE ISOBAR ATP* 190.0 BAR

T OEN VOL DP/DT OP/OO E H S CV CP H DEG K MOL/L L/MOL BAR/K BAR-L/MOL J/HOL J/MOL J/MOL/K J/MOL/K J/HOL/K M/SEC

98.446 26.510 0.03506 20.1492 273.157 3539.

4206.2 68.685 34.48 51.93 1601

100.000 26.164 0.03551 19.1761 258.957 3764.3 4438.9 71.140 34.54 52. 44 1566

105.000 27.793 0.03598 18.1620 243.787 4013.9 4697.6 73.712 34.61 53.01 1525

110.000 27.419 0.03647 17.1964 228.763 4267.8 4960.7 76.189 34.55 5 3.46 1485

115. 000 27.041 0.03698 16.2772 214.064 4524.4 5227.0 76.573 34.31 53.78 1446

120.000 26.656 0.03751 15.4015 199.819 4782.7 5495.4 80.867 33.95 54. 00 1407

125.000 26.270 0.03807 14.5661 186.116 5042.1 5765.4 83.075 33.56 54.21 1369

130.000 25.875 0.03865 13.7683 173.011 5302.4 6036.7 85.206 33.20 54. 47 1330

135.000 25.474 0.03926 13.0053 160.536 5564.

6309.9 87.26 9 32.93 54.85 1291

140.000 25. 065 0 . 03990 12.2748 148.704 5827.

6585.3 8 9 . 27 2 32.77 55.35 1251

145.000 24.648 0.04057 11.5747 137.510 6092.6 6863.5 91.224 32.66 55.91 1211

150.000 24.223 0. 04128 10.9034 126.941 6360.1 7144.5 93. 129 32.53 56.47 1172

155.000 23. 789 0.04204 10.2592 116.974 6629.4 7428.0 94.988 32.27 56.91 1134

160.000 23.346 0.04283 9.6409 107.583 6899.5 7713.3 96.800 31.80 57.16 1098

165.000 22.693 0.04368 9.0475 98.740 7169.4 7999.4 98.560 31.11 57.21 106-4 170.000 22.429 0.04458 8.4782 90.422 7438.2 8285.3 100.267 30.32 57. 18 1031

175.000 21.955 0.04555 7.9322 82.607 7706.4 8571.8 101.926 30.16 57.81 993

160.000 21.469 0.04658 7.4090 75.279 7977.0 8862.0 103.561 29.82 58.30 958

165.000 20.970 0.04769 6.9062 68.429 8248.9 9155.0 105.166 29.57 58.90 922

190.000 20.459 0.04886 6.4298 62.054 8522.5 9451.2 106.746 29.37 59.62 886

195.000 19.934 0.05017 5.9737 56.153 8798.1 9751.3 108.305 29.23 60.42 851

200.000 19.395 0. 05156 5.5400 50.729 9075.9 10055.6 109.845 29.14 61.30 816

205.000 16.642 0.05307 5.1290 45.785 9356.0 10364.4 111.371 29. 07 62. 25 782

210. 000 16.275 0. 05472 4.7411 41.324 9638.5 10678.2 112.883 29.04 63. 24 749

215.000 17.695 0.05651 4. 3766 37.340 9923.2 10996.9 114.383 29.03 54.26 718

220.000 17.103 0.05647 4. 0357 33.826 10209.9 11320.7 115. 872 28.84 65.05 690

225.000 16.503 0 • 06060 3.7184 30.768 10496.9 11648.2 117. 343 28.79 65.92 663

230.000 15.896 0.05291 3.4244 28.148 10784.6 11979.8 118.801 28.79 66.71 636

235. 000 15.286 0 • 06541 3.1535 25.947 11072.

12315.1 120.243 26.82 67.36 615

240.000 1 4. 663 0.06811 2.9051 24.144 11359.0 12653.0 121.666 28.87 67.78 59-4 245.000 14. 067 0. 07099 2.6786 22.716 11643.6 12992.4 123. 066 28.93 67. 92 577

250.000 13.505 0.07404 2.4732 21.640 11924.9 13331.7 124.436 28.99 67 . 7-4 561

255.000 12.945 0.07725 2.2882 20.892 12201.5 13669.2 125.773 29.06 67.20 549

260.000 12.412 0.03057 2.1224 20.445 12472.3 14003.1 127.070 29.14 66.32 539

265.000 11.909 0. 06397 1. 9746 20.269 12736.4 14331.9 128.323 29.22 65.16 531

270.000 11. 438 0.08743 1.8434 20.322 12993.3 14654.4 129.528 29.30 6 3.81 525

275.000 11.001 0.09090 1.7271 20.539 13242.9 14969.9 130. 686 29.39 62.39 521

260.000 10.597 0. 09437 1.6237 20.842 13485.4 15278.4 131.798 29.49 61.03 519

265.000 10.221 0.09784 1.5315 21.186 13721.6 15580.5 132.867 29.59 59.80 517

290.000 9. 873 0.10129 1.4488 21.558 13952.

15876.6 133.897 29.71 58.68 515

295.000 9.548 0. 10473 1.3743 21.951 14177.6 16167.4 134.892 29.83 57.67 514

300.000 9.246 0. 10816 1.3069 22.366 14398.5 16453.4 135. 853 29.96 56. 76 514

310.000 8.699 0. 11495 1.1897 23.282 14826.7 17012.8 137. 687 30.25 55. 15 514

320.000 8.220 0.12165 1.0918 24.349 15245.9 17557.2 139.416 30.57 53. 76 517

330.000 7.799 0. 12822 1.0092 25.521 15652.5 18088.6 141.051 30.93 52.58 520

340.000 7. 427 0. 13465 0.9387 26.740 16051.1 18609.4 142.606 31.31 51.62 524

350.000 7.095 0. 14095 0.8779 27.975 16443.8 19121.8 144.091 31.73 50.88 529

360.000 6.797 0 • 1-.712 0.8249 29.210 16832.4 19627.6 145.516 32.16 50.31 534

370.000 6.526 0.15317 0.7783 30.439 17216.2 20128.6 146.889 32.62 49.90 539

360.000 6.285 0. 15912 0.7370 31.658 17602.7 20626.0 148.215 33.10 49.61 544

390.000 6. 062 0.16497 0.7002 32.865 17986.7 21121.1 149.501 33.59 *9.43 549

400.000 5.856 0. 17072 0.6671 34.059 18371.1 21614.8 150.751 34.10 ^9.33 5 54 420.000 5.495 0. 16197 0.6101 36.405 19143.9 22601.4 153. 158 35.15 49.37 565

440.000 5. 183 0.19293 0.5627 38.695 19925.3 23591.0 155.460 36.22 49.62 575

460.000 4.911 0.20364 0.5227 40.930 20716.3 24587.5 157.675 37.31 50.04 585

460.000 4.670 0.21413 0.4883 43.112 21525.1 25593.5 159.815 38.41 50.58 595

500.000 4. 456 0. 22442 0.4585 45.246 22347.1 26611.2 161.892 39.50 51.20 605

7
METHANE ISOBAR ATP* 200.0 BAR

T DEN VOL DP/DT OP/ DO E H S CV CP W 0£G K NOL/L L/NOL BAR/K BAR-L/NOL J/NOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

95.699 26. 520 0.03505 20. 12&5 279.236 3593.9 9299.9 68. 728 39.55 51.91 1603

100.000 23.202 0.03596 19.2086 260.967 3755.9 9965.1 71.097 39.61 52.38 1569

105. @00 27. 633 0. 03593 18.2015 295.976 9009.9 9723.9 73.616 39.68 52.99 1530

110. 0S0 27.962 9.03691 17.2925 231.099 9257.9 9986.2 76.090 39.62 53.38 1990

115.000 27.067 0.03692 16. 3295 216.529 9513.7 5252.1 78.970 39.38 53.68 1952

120.000 26.796 0.03799 15.9595 202.382 9771.1 5520.0 80.759 39.02 53.89 1919

125.000 26.323 0.03799 19.6298 188.766 5029.5 5789.3 82.963 33.62 59. 08 1376

136.000 25.932 0.03656 13.8375 175.735 5286.6 6060.0 85.088 33.27 59.33 1338

135.009 25.535 0.03916 13.0800 163.322 5599.2 6332.9 87. 195 33.00 59.69 1299

190.000 25.131 0.03979 12.3599 151.595 5811.1 6607.0 89.192 32.83 55. 16 1260

145. 000 29.720 0.09095 11.6603 190.902 6075.0 6889.1 91.087 32.72 55.70 1221

150.090 29.301 0.09115 10.9999 129.879 6391.0 7169.0 92.989 32.59 56.23 1182

155.000 23. 873 0.09189 10.3557 119.956 6608.5 7996.3 99.835 32. 33 56.69 1195

166.600 23.937 0.09267 9.7929 110.607 6876.8 7730.1 96.637 31.86 56.85 1109

165.000 22.992 0.09399 9.1551 101.606 7199.6 8019.5 98.387 31.16 56.86 1076

170.600 22.538 0.09937 6.5919 93.527 7911.2 8298.6 100.089 30.37 56.78 1099

175.008 22.079 0.09530 8.0511 85.799 7676.9 8582.9 101.730 30.21 57. 36 1007

160 .008 21.599 0.09630 7.5337 78.955 7999.7 8870.7 103.351 29.86 57.77 973

105.000 21.113 0. Ot 736 7.0387 71.632 8213.6 9160.9 109.991 29.60 58.31 938

190.600 20.616 0.09851 6.5659 65.275 8983.8 9953.9 106.509 29.91 58.93 903

195.600 20.107 0. Of 973 6. 1153 59.380 8755.7 9750.3 108. 099 29.26 59.63 869

260.000 19.586 0.05106 5.6868 53.996 9029.

3

10050.9 109.563 29.15 60.90 835

205.000 19. 053 0.05299 5.2807 96.979 9309.8 10359.5 111.065 29.08 61.23 802

210.000 18.508 0.05903 9.8971 99.979 9582.2 10662.8 112.550 29.09 62. 09 770

215.009 17.952 0.05570 9.5361 90.929 9861.9 10975.9 119.022 29.02 62.97 739

220.000 17.387 0. 05752 9,1978 36.839 10192.2 11292.5 115.980 28.82 63.63 712

225.000 16.813 0.05998 3. 8622 33.676 10923.0 11612.5 116.918 28.76 69. 38 685

230.000 16.235 0.05160 3.5891 30.993 10709.3 11936.2 118.391 28.75 65.08 661

235.000 15.655 0. 06366 3.3179 28.611 10985.6 12263.2 119.797 26.78 65. b7 638

290 .000 15.077 0.06633 3.0682 26.661 11266.1 12592.7 121. 135 28.82 66.10 617

295.009 19.505 0.06699 2. 6392 25.072 11595.

0

12923.8 122.500 28.88 66.32 599

250. 000 13.996 0. 07171 2.6303 23.822 11821.3 13255.5 123.890 28.95 66. 29 583

255.000 13.903 0.07961 2.9906 22.886 12099.0 13586.2 125.150 29.03 65.98 569

260.000 12.881 0.07763 2.2692 22.292 12362.1 13919.8 126.926 29.12 65. 90 558

265.000 12. 389 0.08075 2. 1199 21.669 12629.

7

19239.8 127.669 29.21 69. 56 599

270.000 11.919 0. 08393 1.9767 21.725 12881.9 19560.0 128.861 29.30 63.51 592

275.000 11.979 0.08715 1.8532 21.786 13131.6 19879.6 130.016 29.90 62. 32 537

200.000 11.069 0.09039 1.7928 22.001 13375.9 15183.1 131.128 29.50 61.09 533

205.000 10.661 0.03362 1.6991 22.296 13613.2 15985.6 132. 199 29.62 59.90 530

290.000 10.325 0.09685 1.5555 22.636 13895.3 15782.3 133.231 29.79 58.81 528

295.000 9.993 0. 10007 1.9756 23.001 19072.6 16073.9 139.227 29.87 57.83 527

300.000 9.683 0. 10327 1.9031 23.386 19295.3 16360.7 135.192 30.00 56.99 526

310.000 9.121 0. 10969 1.2771 29.219 19729.3 16922.2 137.033 30.30 55.90 525

320.000 8.625 0. 11595 1. 1715 25.196 15150.7 17969.6 138.771 30.63 59. 11 52o

330.000 8.166 0. 12216 1.0820 26.210 15561.7 18009.9 190.918 30.99 52.99 529

390.000 7.7 97 0.12826 1.0055 27.360 15969.7 18529.9 191.986 31.38 52.05 532

350.000 7.999 0. 13925 0. 9395 28.550 16361.5 19096.5 193.983 31.80 51.30 536

360.000 7. 136 0. 19013 0.8821 29.755 ' 16753.9 19556.5 199.920 32.23 50.72 590

370.000 6.859 0.19589 0.8316 30.961 17193.5 20061.9 196.303 32.69 50.28 595

380.000 6.596 0. 15156 0.7868 32.162 17531.3 20562.6 197.690 33.17 99. 98 550

390. 000 6.369 0. 15719 0.7970 33.359 1/918.5 21061.2 198.935 33.67 99.78 559

900.000 6. 199 0. 16262 0.7112 39.536 18305.9 21558.9 150.199 39.17 99.67 559

920.000 5.768 0. 17336 0.6996 36.865 19089.1 22551.3 152.616 35.22 99.67 569

990.000 5.990 0.18382 0.5969 39.199 19870.2 23596.6 159.931 36.29 99.90 579

969.000 5.159 0.19909 0.5553 91.372 20667.5 29598.3 157.157 37.38 50.29 $89

900.000 9.901 0.20909 0.5163 93.552 21978.2 25559.0 159.308 38.98 50.80 599

500.000 9.676 0. 21387 0. 9863 95.685 22303.7 26581.0 161.399 39.56 51.90 608

188
METHANE ISOBAR ATP® 220.0 BAR

T DC N VOL OP/DT DP/OO E H S CV CP H OEG K MOL/L L/MOL 8AR/K 6AR-L/H0L J/MOL J/HOL J/MOL/K J/MOL/K J/MOL/K M/SEC

96.183 28.565 0.03501 20.0669 276.353 3552.3 4322.5 68.815 34.69 51.87 1605

100.000 28.278 0.03536 19.2712 264.694 3739.6 4517.5 70.863 34.75 52.28 1576

105.000 27.914 0.03532 18.2782 250.265 3987.2 4775.3 73.427 34.82 52.81 1538

110.000 27.548 0.03630 17.3320 235.689 4238.8 5037.4 75. 894 34.75 53.23 1500

115.000 27.178 0.03679 16.4309 221.363 4493.0 5302.4 78.266 34.51 53.50 1462

120.000 26.805 0.03731 15.5723 207.429 4748.6 5569.3 80.547 34.15 53.68 1426

125.000 26.427 0.03784 14.7536 193.985 5005.1 5837.6 82.742 33.76 53.84 1389

130.000 26.044 0.03840 13.9719 181.100 5262.

6107.0 84. 857 33.40 54. 05 1352

135.000 25.656 0.03898 13.2248 168.812 5520.4 6377.9 86.903 33.13 54. 38 1314

140.000 25.261 0.03959 12.5101 157.142 5779.9 6650.8 88.838 32.96 54.61 1276

145.000 24.860 0.04023 11.8257 146.093 6041.1 6926.1 90.820 32.85 55.31 1238

150.000 24.451 0.04090 11. 1700 135.656 6304.1 7203.9 92.703 32.71 55.79 1201

..55.000 24.036 0. 0416 0 10.5415 125.813 6568.5 7483.8 94.539 32.45 56.14 1165

160.000 23.613 0.04235 9. 9390 116.541 6833.7765.0 96. 324 31.97 56.29 1131

165.000 23. 183 0. 04313 9.3615 107.813 7097.4 8046.4 98.056 31.27 56.23 1099

170.000 22.745 0.04397 8.8081 99.604 7359.9 8327.1 99.732 30.46 56.07 1069

175.000 22.299 0.04485 8.2780 91.892 7621.1 8607.7 101.356 30.31 56.55 1034

180.000 21.844 0.04578 7.7708 84.655 7884.0 8891.2 102.953 29.95 56.86 1001

185.000 21.381 0. 0*677 7.2859 77.879 8147.5 9176.5 104.516 29.68 57. 27 968

190.000 20.908 0.04783 6.8230 71.553 8411.8 9464.0 106.050 29.47 57.75 935

195. 000 20.427 0.04895 6. 3818 65.670 8677.1 9754.1 107.557 29.31 58.30 902

200.000 19.937 0 . 05016 5.9624 60.226 8943.5 10047.0 109. 040 29.19 58.89 870

205.000 19.437 0.05145 5.5644 55.217 9211.2 10343.1 110.502 29.10 59.53 839

210.000 18.929 0.05283 5.1880 50.641 9480.2 10642.4 111. 945 29.05 60.20 809

215.000 18.413 0.05431 4.8331 46.493 9750.3 10945.1 113.369 29.01 60.87 780

220.000 17.890 0.05590 4.4994 42.764 10021.4 11251.1 114.776 28.79 61.34 754

225.000 17.361 0.05760 4.1870 39.443 10292.0 11559.2 116. 161 28.73 61.90 728

230.000 16.829 0.05942 3.8953 36.515 10562.9 11870.1 117.528 28.70 62.45 704

235.000 16.295 0.06137 3.6240 33.965 10833.6 12183.6 118.876 28.72 62.94 681

240.000 15.763 0. 06344 3.3725 31.772 11103.7 12499.4 120.206 26.76 63.34 660

245.000 15.235 0.06564 3.1401 29.917 11372.8 12816.8 121.515 28.82 63.61 642

250.000 14. 715 0.06796 2.9260 28.380 11640.1 13135.2 122.801 28.90 63.73 625

255.000 14.205 0.07040 2.7294 27.139 11905.1 13453.8 124.063 28.99 63.68 610

260.000 13.710 0.07294 2.5496 26.173 12167.0 13771.7 125.298 29.08 63. 44 597

265.000 13.232 0.07557 2.3857 25.462 12425.2 14087.9 126.502 2 9.16 63. 02 585

270.000 12.774 0.07829 2.2366 24.983 12679.3 14401.6 127.675 29.29 62.43 576

275.000 12.337 0. 03106 2.1014 24.715 12928.7 14711.9 128. 814 29.41 61.69 568

280.000 11.924 0.08387 1.9791 24.636 13173.2 15018.2 129.918 29.53 60. 84 562

285.000 11.534 0.08670 1. 86 85 24.719 13412.7 15320.1 130.986 29.65 59.91 558

290.000 11.168 0.03954 1.7685 24.927 13647.3 15617.3 132.020 29.78 56. 96 555

295.000 10.824 0.03239 1.6780 25.214 13877.3 15909.8 133.020 29.92 58.04 552

300.000 10.502 0.09522 1. 5958 25.543 14102.9 16197.8 133.988 30.07 57.19 550

310.000 9.914 0. 10087 1.4526 26.269 14543.

16762.2 135.839 30.39 55.72 548

320.000 9.392 0. 10647 1.3321 27.061 14970.8 17313.2 137.588 30.73 54.52 54 7 330.000 8. 926 0.11203 1.2296 27.917 15388.7 17853.3 139.250 31.10 53.54 54 7 340.000 8.509 0.11752 1.1415 28.869 15798.8 18384.4 140. 836 31. 50 52.70 549

350.000 8.134 0.12295 1.0652 29.918 16202.9 18907.7 142.353 31.93 51.99 551

360.000 7.795 0.12829 0.9987 31.027 16602.3 19424.6 143.809 32.37 51.41 554

370.000 7.488 0. 13354 0.9402 32.167 16998.5 19936.4 145.212 32.33 50.97 558

380.000 7.209 0. 13871 0. 8885 33.319 17392.7 20444.3 146. 566 33.31 50.64 562

390.000 6.954 0. 14380 0. 8423 34.473 17785.8 20949.5 147.878 33.81 50.41 56o

400.000 6.720 0.14882 0.8010 35.624 18178.8 21452.8 149. 153 34. 32 50. 27 570

420.000 6.303 0.15864 0.7300 37.905 18967.2 22457.3 151.603 35.36 50.22 579

440 .000 5.945 0.16822 0.6711 40.151 19762.5 23463.3 153.943 36.44 50.40 586

460.000 5.632 0.17757 0.6216 42.356 20568.0 24474.6 150.191 37.52 50.75 598

480.000 5.355 0. 18673 0.5792 44.520 21386.

25494.2 15 3.36 0 38.61 51.23 607

500.000 5. 109 0.19573 0.5427 46.644 22218.3 26524.2 160.463 39.70 51.79 6 lo

189
METHANE XS08AR AT P = 240.0 BAR

T OEN t/OL DP/DT QP/DD E H S CV CP H DEG K HOL/L L/HOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

96.670 28.601 0.03496 20.0133 278.419 3560.8 4400.0 63.902 34.83 51.63 1607

100.000 23. 353 0.03527 19. 3308 268.695 3723.7 4570.1 70.683 34.88 52.18 1583 105.000 27.993 0.03572 16.3516 254.438 3970.0 4827.4 73.241 34.95 52.69 154c no. oso 27.632 0.03619 17.4100 240.169 4220.2 5088.8 75.702 34.30 53-08 1509 115.000 27.268 0.03667 16.5286 226.095 4472.9 5353.0 7 8 . 96 8 34.64 53. 33 1473

120.000 26.900 0.03717 15.6810 212.371 4726.9 5619.0 80.341 34.28 53.40 1437 125.000 26.529 0.03769 14.8727 199.102 4981.5 5386.2 82,527 33.88 53.62 1401 130.000 26. 153 0. 03624 14. 1012 186. 361 5236.

8

6154.4 8*. 63 3 33.52 53.30 1365

135.000 25.772 0. 03880 13. 3640 174.196 5492.8 6424.0 86.668 33.25 54.09 1329

140.000 25.386 0.03939 12.6590 162,629 5750.0 6695.4 88.643 33.08 54.49 1292 145.000 24.994 0. 04001 11.9842 151.669 6008.8 6969.0 90.563 32.97 54-95 1255

150.000 24.59b 0.04066 11.3379 141.311 6269.1 7244.9 92.433 32.83 55.38 1219

155.000 24. 191 0.04134 10.7180 131.540 6530 . 6 7522.7 94.255 32.56 55.69 1184

150.000 23.781 0.04205 10.1256 122.335 6792.3 7801.5 96.025 32.08 55.79 1152

165.000 23.364 0.0<*26Q 9.5573 113.670 7053.1 8080.3 97.740 31.38 55.67 1121 170.000 22.940 0.04359 9.0129 105.521 7311.9 8358.1 99. 399 30.58 55.45 1092

175.000 22.510 0 . 04443 8.4919 97.862 7569.1 8635.3 101.004 30.40 55. 85 1059

ISO. 000 22.072 0.04531 7.9935 90.674 7827.8 8915.1 102.580 30.04 56.08 1027 105.900 21.628 0. 04624 7.5172 83.937 8086.6 9196.2 10*. 121 29.76 56.39 996 190.000 21.177 0.04722 7.0626 77.638 8345.8 9479.1 105.629 29.55 56.77 964

195.000 20.718 0.0*827 6.6295 71.766 8605.6 9764.0 107.109 29.38 57.20 933 200.000 20.253 0.04938 6.2174 66.314 8866.1 10051.2 108.563 29.24 57.67 903 205.000 19.781 0.05055 5. 8263 61.274 9127.4 10340.7 109.993 29.15 58.17 873 210.000 19. 302 0.05181 5.4556 56.643 9389.5 10632.9 111.401 29.07 58.69 844 215.000 18.818 0.05314 5. 1058 52.413 9652.3 10927.7 112.789 29.03 59.23 816 220.000 18.328 0 • 03 45o 4.7761 48.576 9915.7 11225.2 11*. 157 28.80 59-55 791 225. OOO 17.835 0.05607 4 • 4663 45.123 10178.4 11524.0 115.500 28.72 59.99 767 230.000 17.339 0.05757 4.1761 42.040 10440.9 11825.1 116.823 28.69 60.42 743

235. 000 16.842 0.05937 3.9049 39.313 10703.2 12128.2 118. 127 28.69 60.83 721 2*0.000 16.346 0 . OollS 3.6523 36.924 10965.

0

12433.2 119.411 28.73 61.18 700 2*5.000 15.854 0. 05308 3.4174 34.855 11226.0 12739.8 120.676 28.79 61.45 681 250.000 15. 367 0 . 0o5 08 3.1997 33.089 11485.8 13047.6 121.919 28.87 61.62 664

255.000 14. 888 0.06717 2.9984 31.605 11743.

8

13355.9 123.140 26.96 61.66 648

260.000 1*.419 0. 06935 2.8127 30.386 11999.7 13664.2 124. 337 29.06 61.62 634

265.000 13.963 0.07162 2.6418 29.411 12253.0 13971.9 125.509 29.17 61.42 621 270.000 13.521 0. 07396 2.4848 28.661 12503.2 14278.2 126.655 29.29 61.10 611 275. 000 13.096 0.07636 2.3410 28.117 12750.1 14582.7 127.772 29.41 60. 66 601 280.000 12.689 0. 07881 2. 2094 27. 762 12993.

3

14884.7 128.860 29.54 60.12 593 285.000 12.301 0.08130 2.0892 27.578 13232.6 15183.7 129.919 29.68 59.49 587 290.000 11.932 0.03381 1.9795 27.547 13468.0 15479.5 130.948 29.82 58.80 582 295.000 11.582 0.03634 1.87 94 27.647 13699.5 15771.7 131.947 29.97 58- 07 578

300.000 11.252 0. 03886 1.7881 27.853 13927.1 16060.2 132.916 30.13 57.33 575 310.000 10.645 0.0)394 1.6281 28.454 14371.9 16626.4 134.773 30.46 55.95 571 320 . 000 10. 104 0.09897 1.4933 29.162 14804.6 17179.9 136.531 30.82 54. 79 568 330.000 9.618 0. 10397 1.3782 29.928 15227.7 17722.9 138.202 31.21 53.85 567 340.000 9. 181 0.10892 1.2791 30.743 15643.2 18257.4 139.797 31.61 53. 08 567 350.000 8.764 0. 11384 1. 1929 31.618 16052.9 18785.0 141.327 32.04 52.46 568 360.000 8.425 0.11670 1.1175 32.575 16458.1 19306.9 142.797 32.49 51.9* 570 370.000 8. 097 0. 12350 1. 0511 33.604 16860.0 19824.1 144. 214 32-96 51.52 572 380.000 7.798 0 . 12824 0.9922 34.678 17259.7 20337.5 145.583 33.45 51.19 575 390. 000 7.524 0.13291 0.9398 35.775 17658.2 20848.2 146.910 33.94 50.95 579

400.000 7.272 0.13752 0.8928 36.882 18056.3 21356.9 146.198 34.45 50.80 582 420.000 6. 823 0. 1*656 0. 8121 39.099 16854.2 22371.6 150.673 35.50 50.72 590 440.000 6.436 0.15536 0.7453 41.296 19658.0 23387.0 153.035 36.57 50. 86 598 460.000 6. 098 0.16400 0.6892 43.468 20471.3 24407.2 155.302 37.66 51.18 607 480.000 5.799 0.1724* 0.6413 45.606 21296.4 25*34.9 157.489 38.75 51.62 615 500. 000 5.533 0. 18073 0.6000 47.709 22135.0 26472.5 159.607 39.83 52.15 624

190
methane isobar at p 260.0 BAR

T DEN VOL DP/DT OP/DD E H S CV CP M OEG K MQL/L L/HQL BAR/K 6AR-L/N0L J/MOL J/NOL J/ MOL/

J/MOL/K J/MOL/K M/SEC

97.156 20.637 0.03492 19.9607 200.432 3569.6 4477.5 60.990 34.97 51.80 1609

100.000 20.427 0.03518 19. 3874 272.371 3708.2 4622.8 70.505 35.01 52.09 1589

105.000 20. 071 0.03562 18.4219 258.494 3953.3 4879.5 73.059 35.08 52.58 1554

110.000 27.7 14 0.03608 17.5007 244.537 4202.2 5140.4 75.514 35.01 52.95 1518

115.000 27.355 0 o 03656 16.6226 230.722 4453.4 5403.9 77.873 34.77 53. 18 1483

120.000 26. 994 0.03705 15.7856 217.210 4705.9 5669.0 80.139 34.41 53.30 1448

125.000 26.620 0.03755 14.9875 204.117 4958.0 5935.2 82.317 34.01 53.41 141*. 130.000 26.259 0.03800 14.2257 191.522 5212.2 6202.4 84.415 33.65 53.57 1379

135.000 25.005 0. 03663 13.4979 179.477 5466.

6470.7 86.441 33. 38 53.83 1343

140.000 25.507 0.03920 12.8021 166.011 5721.4 6740.7 88.405 33.20 54. 19 1307

145.000 25.123 0.03900 12. 1363 157.137 5977.8 7012.7 90.314 33.09 54.62 1272

150.000 24. 735 0.04043 11.4988 146.854 6235.7 7286.9 92. 17 2 32.94 55.02 1 2 3o 155.000 24.340 0. 04108 10.8883 137.148 6494.6 7562.8 93.981 32.67 55. 29 1203

160.000 23.941 0.04177 10.3036 128.002 6753.5 7839.5 95.738 32.19 55. 35 1171

165.000 23.535 0.04249 9.7436 119.392 7011.2 8115.9 97.439 31.49 55.17 1142

170.000 23. 125 0.04324 9.2075 111.293 7266.7 8391.0 99.082 30.68 54.90 111*. 175.000 22.700 0. 04404 8. 6944 103.680 7520.4 8665.4 100.670 30.50 55.24 1082

100.000 22.206 0.04487 8.2038 96.532 7775.3 8941.9 102.228 30.13 55.40 1052

105.000 21.050 0.04575 7.7350 89.820 8030.0 9219.5 103.749 29. 85 55.64 1022

190.000 21.425 0.04667 7.2877 83.551 8284.9 9498.4 105.237 29.62 55. 93 992

195.000 20.906 0 . 04765 6. 8613 77.689 8540.0 9778.9 106.694 29.44 56.27 962

200.000 20.542 0 . 04868 6.4556 72.231 8795.5 10061.2 108. 123 29.30 56.65 933

205.000 20.092 0.04977 6.0701 67.163 9051.5 10345.5 109.527 29.19 57.05 905

210.000 19.630 0.05092 5.7046 62.492 9307.0 10631.8 110.907 29. 11 57. 47 877

215.000 19. 100 0. 05214 5.3588 58.197 9564.6 10920.2 112.264 29.06 57.90 850

220.000 10. 718 0.05343 5.0324 54.274 9821.7 11210.8 113.600 28.82 58.12 826

225.000 10.253 0.05479 4.7249 50.712 10077.8 11502.2 114.910 20.73 58.46 802

230.000 17.706 0.05622 4. 4360 47.502 10333.6 11735.4 life. 199 28.69 58.81 779

235.000 17.319 0.05774 4.1651 44.628 10589.0 12090.2 117.467 28.69 59. 14 757

240.000 16.054 0. 05933 3.9117 42.076 10844.0 12386.7 118.716 28.72 59.45 737

245.000 16.390 0. OolOl 3.6752 39.831 1 1090 .12684.7 119.944 28.78 59.70 718

250.000 15. 931 0. 06277 3.4548 37.Q75 11351.7 12983.7 121. 152 20.85 59.89 700

255.000 15.479 0 . 0o46 0 3.2499 36.191 11603.7 13283.5 12 2. 340 26.94 60.00 684

260.000 15.034 0.06652 3.0597 34.761 11854.2 13583.6 123.505 29.05 60.0 3 669

265.000 14.599 0.06850 2.8835 33.569 12102.7 13883.6 124.648 29.16 59.96 656

270.000 14. 176 0. 07054 2.7206 32.596 12348.9 14183.0 125.768 29.29 59.80 644

275.000 13.765 0. 07265 2.5701 31.626 12592.6 14431.4 126.863 29.42 59.55 6 3h 200.000 13.360 0 . 07480 2.4314 31.241 12833.5 14778.3 127.933 29.56 59. 21 625

205.000 12.907 0.07700 2.3036 30.827 13071.4 15073.4 128.977 29.71 58.79 617

290.000 12.621 0.07923 2. 1660 30.567 13306.2 15366.2 129.996 29.86 58.32 610

295.000 12.272 0.08149 2.0779 30.448 13537.8 15656.5 130.986 30.02 57.79 604

300.000 11.939 0.08376 1.9785 30.455 13766.3 15944.1 131.955 30.16 57.24 600

310.000 11.321 0.08833 1.8031 30.770 14214.1 16510.6 133.01

30.53 56. 08 594

320.000 10. 765 0.09289 1.6542 31.364 14650.7 17065.9 135.575 30.90 54.99 590

330.000 10.264 0.09743 1.5269 32.057 15078.0 17611.1 137.253 31.30 54.08 586

340.000 9.011 0.10193 1.4171 32.005 15497.8 18146.0 136.856 31.71 53.34 586

350.000 9.390 0 . 106*0 1.3215 33.593 15911.9 18678.4 140. 394 32. 15 52.75 58b

360.000 9.022 0. 11084 1.2375 34.421 16321.7 19203.5 141. 873 32.61 52. 29 587

370.000 0.670 0.11523 1. 1634 35.307 16728.3 19724.4 143. 300 33.08 51.92 588

300.000 0.362 0. 11959 1.0976 36.261 17132.8 20242.0 144.681 33.57 51.62 590

390.000 0.072 0.12389 1.0388 37.267 17536.0 20757.1 140. 019 34.07 51.40 592

400.000 7.004 0. 12814 0.9861 38.300 17938.6 21270.3 147. 318 34.58 51.25 595

420.000 7.326 0.13650 0.8955 40.435 18745.1 22294.0 149.815 35.63 51.15 602

440.000 6.913 0.14465 0.8207 42.574 19556.9 23317.9 152.197 36.71 51.27 609

460.000 6.552 0. 15264 0. 7576 44.700 20377.4 24346.0 154.482 37.79 51.56 617

400.000 6.232 0.16046 0.7043 46.803 21209.2 25301.1 156.604 38.88 51.97 625

500.000 5.947 0.16814 0.6582 48.878 22053.9 26425.6 158.616 39.96 52.48 633

191
METHANE ISOBAR AT P = 280. 0 BAR

T OEN VOL DP/DT OP/DO E H S CV CP H OEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K 9/ SEC 97.639 28.672 0.03488 19.9090 282.394 3578.5 4555.1 69.077 35.11 51.78 1611

100.000 28.500 0.03509 19.4413 275.919 3693.

1

4675.6 70.330 35.14 52.01 1599

105.000 28.148 0.03553 18.4893 262.432 3937.1 4931.9 72.879 35.21 52.48 1561

110.000 27. 795 0.03598 17.5802 248.795 4184.

7

5192.1 75.329 35.14 52.83 1527

115.000 27.441 0.03644 16.7132 235.244 4434.6 5455.0 77.682 34.90 53.03 1493

120.000 27. 085 0.03692 15.8866 221.949 4685.5 5719.3 79.942 34.53 53. 14 1459

125.000 26.725 0.03742 15.0982 209.034 4936.9 5984.6 82.112 34.13 53. 22 1425

130.000 26. 362 0. 03793 14. 3457 196.585 5138.6 6250.7 84.202 33.77 53.35 1391

135.000 25.995 0.03847 13.6270 184.661 5440.8 6517.9 86.219 33.49 53.58 1357

mo. ooo 25.624 0.03903 12.9396 173.295 5693.9 6786.6 88.174 33.32 53. 92 1322

145.000 25.249 0.03961 12.2825 162.504 5948.2 7057.2 90. 073 33.20 54. 32 1287

150.000 24.868 0. 04021 11.6533 152.290 6203.9 7329.8 91.921 33.06 54.69 1253

155.000 24.483 0.04034 11. 0506 142.645 6460.3 7603.9 93.718 32.78 54.92 1220

160.000 24.094 0.04150 10.4739 133.553 6716.6 7878.7 95.463 32.30 54. 94 1190

165.000 23.699 0. 04220 9. 9216 124.990 6971.5 8152.9 97. 151 31.59 54. 73 1162

170.000 23.300 0.04292 9.3929 116.935 7224.0 8425.7 98.780 30.78 54.40 1135

175.000 22.896 0. 04368 8.8870 109.362 7474.6 8697.5 100.353 30.59 54.70 110*

180.000 22.487 0. 04447 8. 4033 102.247 7726.1 8971.2 101.895 30.22 54.80 1075

185.000 22.074 0.04530 7.9412 95.570 7977.2 9245.7 103.399 29.93 54.98 1046

190.000 21.656 0 . 0*618 7.5001 89.313 8228.3 9521.2 1 0 * . 86 8 29.70 55.22 1017

195.000 21.234 0. 0*709 7.0796 83.459 8479.3 9797.9 106.306 29.52 55.49 989

200.000 20- 608 0.04806 6.6793 77.996 8730.5 10076.1 107.714 29.37 55.79 961

205.000 20. 378 0.04907 6.2987 72.914 8981.8 10355.9 109.096 29.25 56. 11 93*

210.000 19.944 0.05014 5.9376 68.203 9233.4 10637.3 1 1 0 . 45 2 29.16 56.45 907

215.000 19.508 0.05126 5.5953 63.854 9485.1 10920.4 111.784 29. 10 56. 80 881

220.000 19- 068 0. 05244 5. 2717 59.859 9736.9 11235.3 113.094 28.85 56.94 858

225.000 18.627 0.05368 4. 9663 50.208 9987.4 11490.6 114. 377 28.75 57.21 bZj

230.000 18. 185 0.05499 *.6786 52.891 10237.6 11777.4 115.637 28. 71 57.49 813

235.000 17.743 0.05636 4.4081 49.895 10487.4 12065.5 116. 877 28.70 57.77 791

240.000 17.302 0.05780 4. 1542 47.206 10736.7 12355.0 118.096 28.73 58.03 771 245.000 16.863 0.05930 3,. 9163 44.811 10985.4 12645.8 119.295 28.78 58.27 752

250.000 16. *29 0.06087 3.6939 42.694 11233.3 12937.7 120.474 28.85 58.46 73*

255.000 15.999 0.06251 3 . *861 40.840 11480.2 13230.3 121.633 28.95 58. 59 718

260.000 15.575 0.06420 3.2924 39.233 11725.8 13523.5 122.772 29.05 58.67 703

265.000 15. 160 0.06596 3. 1121 37.856 11969.9 13816.8 123.889 29.17 58.67 689

270.000 14. 754 0.06778 2.9444 36.694 12212.2 14110.1 12*. 985 29.30 58.61 6 7 o 275.000 14. 356 0. 06965 2.7886 35.731 12452.6 14402.8 126. 060 29. 44 58.47 665

280.000 13. 974 0.07156 2.6441 34.952 12690.9 14694.6 127. Ill 29. se 58. 27 655

285.000 13.602 0. 07352 2.5102 34.342 12926.8 14985.3 128.140 29.74 58.00 646

290.000 13.243 0. 07551 2. 3863 33.887 13160.2 15274.6 129. 146 29. 89 57.68 638

295.000 12.898 0. 07753 2.2715 33.574 13391.1 15562.1 130.129 30.06 57.31 632

300.000 12.566 0.07958 2. 1654 33.389 13619.5 15847.7 131.089 30.23 56.91 626

310.000 11.946 0.08371 1.9764 33.359 14068.5 16412.* 132.941 30.59 56.03 617

320.000 11. 381 0. 0 d 787 1. 8145 33.698 14587.8 16968.

1

134. 706 30.98 55.11 611

330.000 10.868 0.09202 1.6754 34.272 14938.4 17514.9 136. 388 31.38 54.27 608

340.000 10.401 0 .09614 1.5550 34.953 15361.9 18053.9 137.997 31.81 53.55 6 0 o 350.000 9.97b 0 .1302* 1.4501 35.684 15779.6 18586.* 139.5*1 32.25 32. 98 60*

360.000 9. 587 0. 13431 1.3579 36.451 16193.2 19113.8 141.027 32.72 52.53 604

370.000 9.230 0.13835 1. 2763 37.251 16603.6 19637.3 142.461 33.19 52.19 60*

380.000 8.901 0. 11235 1.2038 38.088 17012.0 20157.9 143.849 33.69 51.9* 605

390.000 6.597 0.11633 1.1388 38.977 17419.

2

20676.3 145. 196 34.19 5 1.75 6 Oo 400.000 6.315 0. 12026 1.0805 39.921 17825.9 21193.1 146.504 34.71 51.62 608

420.000 7.812 0 o 12801 0.9801 41.916 18640.

1

22224.3 149.020 35.76 5 1.53 61*

440 .000 7.375 0 . 13559 0.8971 43.974 19459.2 23255.7 151.419 36.83 5 1 . b * 620

460.000 6.992 0.1*301 0. 8275 46.044 20286.5 2429 0.9' 153.720 37.92 51-91 627

480.000 6.654 0. 15029 0. 7682 48.104 21124.6 25332.8 155.937 39.00 52.30 63*

500.000 6. 351 0.15744 0.7171 50.144 21975.

1

26383.6 158.082 40.08 52.79 642

192
METHANE ISOBAR ATP* 300. 0 BAR

T DEN tf OIL DP/DT OP/DD E M S CV CP w DEG K MOL/L L/MOL 8AR/K 8AR-L/M0L J/MOL J/MOL J/MOL/K J/MOL/K J/NOL/K N/SEC

90.120 20.707 0.03683 19.8582 284.303 3587.6 4632.7 69.165 35.24 51.75 1613

too. 000 20.572 0.03500 19.4924 279.337 3678.5 4728.5 70.158 35.27 51.93 1601

105.000 20.224 0.03543 18.5538 266.252 3921.4 4984.3 72.703 35.34 52.38 1568

110.000 27.875 0.03567 17.6566 252.944 4167.

5244.

Q

75.148 35.26 52.71 1535

115.000 27.525 0.03633 16.8005 239.663 4416.3 5506.2 77.496 35.02 52.90 1502

120.000 27. 174 0.03600 15.9840 226.509 4665.9 5769.9 79.749 34.65 52.98 1469

125.000 26.020 0.03729 15.2051 213.855 4915.8 6034.3 81.913 34,25 53.0* 1437

130. ooa 26.463 0.03779 14.4616 201.555 5165.8 6299.5 83.995 3 3.68 53.15 140*

135.000 26.102 0.03031 13.7514 169.751 5416.

6565.6 86.004 33.61 53. 36 1370

140.00® 25.730 0.03885 13.0726 178.484 5667.5 6833.1 87.950 33.43 53.67 1336

145.000 25. 370 0.03942 12.4232 167.774 5919.9 7102.4 89.839 33.31 5*. 0* 1302

150.000 24.997 0. 04000 11. 8018 157.620 6173.3 7373.5 91.677 33.17 54. 38 1269

155.000 24.621 0.04062 11.2069 148.040 6427.5 7646.0 93.464 32.09 54.58 1237

160.000 24.240 0. 04125 10.6373 136.996 6681.4 7919.0 95.198 32.40 54.57 1208

165.000 23.056 0.04192 10.0920 130.477 6933.0191.3 96.874 31.69 54.32 1181

170.000 23.467 0.04261 9.5700 122.459 7183.6 8462.0 98.490 30.86 53.96 1155

175.000 23. 074 0.04334 9.0707 114.919 7431.3 8731.5 100.050 30.69 54.22 1125

100.000 22.670 0.04410 8.5932 107.832 7679.8 9002.7 1 0 1 . 57 8 30.31 54.28 1097

105.000 22.277 0.04469 8.1371 101.178 7927.7 9274.4 103. 066 30.02 54.41 1069

190.000 21.073 0.04572 7.7016 94.936 8175.4 95*6.9 104.520 29.78 54.59 1042

195.000 21.466 0.04656 7.2863 89.089 8422.8 9820.4 105.940 29.59 54.81 1014

200.000 21.056 0 o 0*749 6.8907 83.623 8670.2 10095.0 107.331 29.43 55.05 987

205.000 20.642 0. 0*844 6.5144 78.525 8917.6 10370.9 108.693 29.31 55.31 961

210.000 20.226 0.04944 6.1570 73.705 9164.9 10648.1 110.030 29.22 55.59 935

215.000 19.000 0 . 05048 5.8179 69.392 9412.2 10926.8 111.341 29.15 55.87 911

220.000 19.300 0.05150 5.4967 65.338 9659.5 11206.9 112.629 28.89 55. 95 883

225.000 10.967 0- 05272 5.1931 61.612 9905.4 11487.1 113.889 28.79 56.16 866

230.000 10.545 0.05392 4.9064 58.205 10150.9 11768.5 115. 125 28.73 56.39 8**

235.000 10.124 0.05517 4.6363 55.104 10395.8 12051.1 116.341 28.72 56. 63 823

240.000 17.704 0 • 05646 4.3821 52.299 10640.3 12334.8 117.535 28.75 56.86 803

245. 000 17.207 0.05785 4.1432 49.776 10884.2 12619.6 118.710 26.79 57. 07 784

250.000 16.072 0.05927 3. 9191 47.521 11127.4 12905.5 119.865 28.87 57.25 76o

255.000 16.462 0.06074 3.7091 45.520 11369.8 13192.1 121.000 20.96 57.40 750

260.000 16.058 0 • 0o227 3.5125 43.759 11611.1 13479-3 122.116 29.07 57.49 735

265.000 15.660 0 • 06386 3.3288 42.223 11851.3 13767.0 123.211 29.19 57.54 720

270.000 15. 270 0.06549 3.1572 40.897 12090.0 14054.7 124.287 29.32 57.5* 707

275.000 14.000 0.06717 2.9971 39.767 12327.3 14342.3 125.342 29.46 57.48 695

200.000 14.516 0. 06889 2.8479 30.820 12562.0 14629.4 126. 377 29.61 57.37 685

205.000 14.155 0.07065 2.7089 38.040 12796.5 14915.9 127.391 29.77 57.21 675

290.000 13.005 0.07 244 2.5796 37.415 13028.2 1520 1.4 128.384 29.93 57.00 66b

295.000 13.466 0.07426 2.4593 36.932 13257.9 15485.8 129.357 30.10 56.75 659

300. 000 13. 139 0.07611 2.3475 36.579 13485.5 15768.8 130.300 30.28 56. 46 652

310.000 12.521 0.07936 2.1468 36.221 13934.3 16330.2 132. 149 30.65 55.81 641

320.000 11.953 0.08366 1.9733 36.259 14375.0 16884.8 133.910 31.05 55. 10 633

330.000 11.432 0.09747 1.0231 3®. 6 1

14608.0 17432.2 135.594 31.46 54.38 628

340.000 10. 956 0.09127 1.6926 37.176 15234,4 17972.6 137.207 31.90 53.72 625

350.000 10.520 0.09506 1.5785 37.844 15655.3 18507.0 138.756 32.35 53.17 623

360.000 10.120 0. 09881 1.4782 30.562 16072.1 19036.4 140.248 32.82 52.73 621

370.000 9.752 0. 10254 1.3894 39.313 16485.

19562.0 141.688 33.30 52.40 621

300.000 9.412 0. 10624 1.3102 40.091 16897.5 20086.8 143.082 33.80 52.16 621

390.000 9.090 0. 10992 1.2393 4 0 .896 17308.0 20605.6 14*. 435 34.31 52.00 622

400 . 000 0.00 5 0. 11357 1.1755 41.737 17718.1 21125.1 145.750 34.82 51.90 623

420.000 0.200 0. 12077 1. 0655 43.554 18539.3 22162.3 148. 281 35.88 51.85 626

440.000 7.023 0. 12784 0.9744 45.498 19365.

23200.1 150.694 36.96 51. 96 631

460.000 7.420 0.13477 0.8978 47.495 20198.6 24241.7 153.009 38.04 52.22 637

400.000 7. 064 0. 14157 0.8327 49.503 21042.5 25289.7 155.239 39.12 52.60 6 h*

500.000 6.745 0. 14826 0. 7767 51.503 21898.6 26346.

157.396 40.20 53.07 651
METHANE ISOBAR AT P = 3>0. (J LIAR

T DEN VOL OP/DT DP/DD E H S CV CP H QE6 K HOL/L L/MOL 8AR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

96.599 28. 792 0.03979 19.6083 286.162 3596.9 9710.2 69.253 35.37 51.73 1615

100.000 28.693 0.03991 19. 5909 282.625 3669.2 9781.9 69. 988 35.39 51.86 1607

105.000 28.298 0.03539 18.6156 269.959 3906.0 5036.8 72.529 35.96 52.29 1575

110.000 27. 959 0.03577 17.7302 256.983 9151.3 5296.1 79.970 35.38 52.60 1543

115.000 27.606 0.03622 16. 6898 293.979 9398.6 5557.7 77.312 35.19 52.77 1511

120.000 27. 261 0. 03668 16. 0781 231.131 9696.

8

5820.7 79.560 39.77 52.83 1480

125.000 26.912 0.03716 15. 3083 218.582 9895.3 6089.3 81.717 39.37 52.87 1449

130.000 26.561 0.03765 19.5736 206.932 5193.8 6398o6 83.792 39.00 52.96 1416

135.000 26.206 0.03816 13.8717 199.751 5392.6 6613.7 85.799 33.72 53.15 1383

190.000 25.896 0. 03663 13.2007 183.583 5692.1 6880.1 87.732 33.59 53.43 1350

195.000 25. 987 0 . 03929 12.5590 172.959 5892.6 7198.1 89.613 33.92 53.78 1317

150.000 25. 122 0.03981 11.9999 162.873 6199.

1

7917.9 91.941 33.27 54.09 1285

155.000 29.759 0.09090 11.3571 153.339 6396.2 7686.9 93. 21

8

33. 00 54. 27 1254

160.000 29. 382 0.09101 10.7993 199.390 6697.8 7960.3 99.992 32.51 54.23 1225

165.000 29. 006 0 . 09166 10.2555 135.859 6897.9 8230.9 96.60 7 31.79 53.96 1199

iro.ooo 23 . b27 0 . 09232 9.7398 127.879 7195.2 8999.6 98.212 30.97 53.56 1174

175.000 23.299 0. 09302 9.2965 120.363 7390 .

3

8767.

0

99. 759 30.78 53.79 1145

160 . 000 22.859 0 . 09375 6.7797 113.300 7636.1 9036.0 101.279 30.90 53.81 1119

165.000 22.970 0 . 09950 8.3239 106.665 7881.1 9305.2 102.750 30.10 53.90 1091

190.000 22. 078 0.09523 7.8939 100.936 8125.7 9575.1 104. 189 29.86 54.0* 106*

195.000 21.669 0 . 09612 7. *827 99.599 8369.9 9895.7 105.595 29. 66 54.21 1038

200. 000 21.287 0.09698 7.0919 89.125 8619.0 10117.2 106.970 29.50 54.43 1012

205.000 20 . 866 0 . 09737 6.7188 89.0 19 8857.8 10389.3 108. 316 29.37 54.62 987

210.000 20.966 0.09881 6. 3696 79.299 9101.5 10663.9 109.635 29.27 54.85 962

215.000 20.085 0 . 09979 6.0283 79.819 9395.0 10938.2 110.928 29.20 55.08 938

220.000 19.682 0.05081 5. 7093 70.719 3588.4 11219.2 112. 197 28.93 5 5.11 916

225. 000 19.278 0. 05167 5.9073 66.925 9830.3 11990.2 113.937 26.83 55.27 894

230.000 18.879 0.C5298 5. 1216 63.991 10071.6 11767.0 119. 659 28.77 55.46 873

235 .000 16.971 0 . 05919 9.8518 60.252 10312.9 12099.9 115.899 28.75 55. 66 853

290 .000 18.069 0. 05539 9.5979 57.397 10552.7 12323.7 117.023 28.77 55.86 633

295.000 17.670 0.05659 9.3577 59.712 10792.5 12603.5 118. 177 28. 82 56- 05 819

250.000 17.273 0. 05789 9.1322 52.338 11031.6 12889.2 1 19. 311 28.89 56.23 797

255.000 16.661 0.05929 3.9203 50.209 11270.0 13165.7 120.426 28.96 56.37 780

260 .000 16. 993 0.06063 3. 7219 98.313 11507.6 139*7.9 21.522 29.09 56.49 765

265.000 16. Ill 0.06207 3.5398 96.637 11799.2 13730.5 122.599 29.21 56.56 750

270.000 15. 735 0.06355 3.3599 95.168 11979.8 19013.9 123.656 29.34 56.60 737

275.000 15.367 0.06507 3.1962 93.891 12219.0 19296.9 124.695 29.49 56.59 725

260.000 15. 007 0. 06669 3. 0931 92.799 12996.9 19579.3 125.719 29.64 56 . 54 713

265.000 19.656 0 . 06623 2.8998 91.669 12678.9 19861.8 126.719 29.80 56.45 703

290. 000 19. 315 0 . 06986 2.7660 91.089 12908.2 15193.7 127.695 29.97 56.32 694

295.000 13.963 0.07152 2.6909 90.957 13136.9 15929.9 128.656 30.15 56.16 685

300.000 13. 662 0.07320 2. 5292 39.955 13362.9 15705.2 129.599 30.33 55.96 678

310.000 1 3. 052 0.07662 2. 3135 39.309 13810.7 16262.5 131.926 30.71 55.49 665

320.000 12.985 0.08010 2. 1298 39.059 19251.7 16819.8 1 33. 179 31.11 5*. 96 656

330.000 11.961 0.03361 1. 9696 39.152 19686.

1

17361.6 139. 862 31.54 54.33 649

390.000 11.976 0.03712 1.8295 39.517 15119.7 17902.7 136. 977 31. 98 53.8* 644

350.000 11.039 0 . 09063 1.7066 90.073 15538.3 18938.5 138.030 32.44 53.33 641

360 .000 10.625 0. 09912 1.5983 90.731 15957.8 18969.6 139.527 32.91 52.91 639

370 .000 10.298 0.09758 1.5023 91.936 16379.9 19997.0 190.972 33.40 52.59 638

360.000 9. 899 0. 10102 1.9167 92.172 16789.0 20021.7 192.371 33.90 52.36 637

390.000 9.575 0. 10999 1.3399 92.933 17202.9 20599.5 193.729 34.41 52.20 637

900.000 9. 279 0. 10783 1. 2708 93.716 17615.5 21066.0 195. 050 34.94 52. 12 638

920.000 8. 730 0 . 11959 1. 1519 95.369 18992.6 22107.9 197.591 36.00 52.10 640

990 . 000 8.259 0. 12115 1.0522 97.158 19279.3 23151.0 150.017 37.07 52.2* 64*

960.000 7. 835 0. 12769 0. 9686 99.055 20113.7 29198.2 152.395 38.16 52.50 649

960.000 7.962 0.13902 0.8978 50.996 20963.1 25251.7 159.587 39.24 52.87 654

500.000 7.128 0. 19029 0.8368 52.997 21829.

3

26313.6 156.759 40.32 53.33 661

194
METHANE ISOBAR AT P 340.0 BAR

T OEN VOL DP/DT OP/DD E H S CV CP M OEG K MOL/L L/HOL BAR/K BAR-L/NOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

99.076 26.777 0.03475 19.7593 267.969 3606.3 4787.6 69.341 35.50 51.72 161/

100.000 26.714 0.03483 19.5668 285.762 3650.3 4834.4 69.621 35.52 51.80 1612

106.000 26.372 0.03525 16.6747 273.537 3691.1 5089.5 72.356 35.56 52.21 1582

110.000 26. 031 0.03568 17.6010 260.914 4135.3 5348.2 74.795 35.50 52.50 1551

115.000 27.669 0.03611 16.9660 248.191 4381.4 5609.4 77.132 35.26 52.65 1520

120.000 27.347 0.03657 16.1690 235.575 4628.4 5871.7 79.374 34.89 52.69 1489

125.000 27. 003 0.03703 15.4062 223.216 4675.5 6134.6 61.526 34.48 52.71 1458

130.000 26.657 0.03751 14.6816 211.219 5122.6 6398.0 83.594 34.11 52.78 1427

135.000 26.306 0.03801 13.9879 199.662 5369.8 6662.2 85.589 33.83 52.95 1396

140.000 25.956 0.03853 13.3246 188.594 5617.7 6927.6 87.519 33.65 53.22 1363

145.000 25.601 0. 03906 12.6901 178.045 5866.4 7194.5 89.392 33.53 53.54 1331

150.000 25.243 0.03961 12.0630 168.030 6116.0 7462.9 91.212 33.38 53.83 1300

155.000 24.662 0.04019 11.5013 158.547 6366.2 7732.6 92.980 33.10 53.99 1270

160.000 24.516 0.04079 10.9454 149.591 6615.8 6002.5 94.694 32.60 53.92 1242

165.000 24.150 0.04141 10.4126 141.145 6663.6 8271.5 96.349 31.89 53.62 1216

170.000 23.760 0.04205 9.9029 133.190 7108.7 8538.5 97.944 31.06 53.20 1192

175.000 23.407 0.0t272 9.4151 125.703 7351.4 8604.0 99.460 30.67 53.39 1164

ISO. 000 23.031 0.04342 8.9465 118.660 7594.6 9070.9 100.984 30.48 53.38 1138

165.000 22.653 0 . 04414 8.5026 112.040 7837.0 9337.9 102.448 30.16 53.44 1112

190.000 22.272 0.04490 8. 0766 105.822 8078.8 9605.4 103.674 29.94 53.55 1086

195.000 21. 690 0. 04566 7.6702 99.984 8320.

9873.5 105.267 29.74 53.68 1061

200.000 21.505 0.04650 7.2826 94.512 8561.3 10142.3 106.628 29.57 53.84 1036

205.000 21.119 0.04735 6.9134 69.389 8802.0 10411.9 107.959 29.44 54. 01 1011

210.000 20.732 0.04823 6.5621 84.603 9042.4 10662.4 109.263 29.33 54.20 967

215.000 20.344 0.04916 6.2281 80.142 9282.6 10953.9 110.541 29.25 54.40 96*. 220.000 19.955 0. 05011 5.9111 75-994 9522.5 11226.4 111.794 28.96 54.39 943

225.000 19.566 0.05111 5.6105 72.151 9760.9 11496.6 113.017 28.67 54.51 921

230.000 19.177 0. 05214 5.3257 68.601 9998.6 11771.6 114.217 28.61 54.67 901

235.000 18.790 0.05322 5.0563 65.336 10235.8 12045.3 115.395 26.79 54. 84 881

240.000 16. 404 0.05434 4.6017 62.343 10472.5 12320.0 116.551 28.81 55.01 861

245.000 18.020 0.05549 4.5614 59.612 10708.7 12595.5 117.687 28.85 55.19 843

250.000 17.639 0.05669 4. 3348 57.133 10944.2 12871.8 116.804 28.92 55.35 82b

255.000 17.261 0. 05793 4. 1213 54.892 11179.2 13148.9 119.901 29.01 55.49 809

260.000 16.866 0. 05921 3.9203 52.678 11413.4 13426.7 120.980 29.11 55.61 793

265.000 16.520 0.06053 3.7313 51.078 11646.9 13705.0 122.040 29.24 55.70 779

270.000 16. 15s 0.06169 3.5537 49.480 11879.4 13963.7 123.082 29.37 55-76 765

275. 000 15. 802 0.06328 3.3868 48.073 12111.0 14262.6 124.105 29.52 55.79 753

260.000 15.454 0.06471 3.2302 46.843 12341.4 14541.5 125. Ill 29.67 55. 79 741

265.000 15.113 0.06617 3. 0633 45.779 12570.7 14820.4 126.098 29.84 55.75 730

290.000 14.780 0.06766 2.9^56 44.869 12798.6 15099.0 127.067 30. 01 55.68 720

295.000 14.456 0.06917 2.8165 44.102 13025.3 15377.2 128.018 30.19 55.58 711

300.000 14. 142 0. 07071 2.6955 43.467 13250.5 15654.7 128.951 30.38 55.45 703

310.000 13.541 0.07385 2.4760 42.553 13696.7 16207.7 130.764 30.77 55.12 689

320.000 12. 978 0. 07705 2.2633 42.052 14137.2 16757.0 132.508 31.18 54.73 678

330.000 12.455 0.03029 2.1141 41.899 14572.2 17302.2 134.185 31.61 54.30 670

340.000 11.969 0.03355 1.9652 42.039 15002.2 17843.0 135.800 32.06 53.86 664

350.000 11.519 0.03681 1.8340 42.415 15427.8 18379.5 137.355 32.52 53. 44 659

360.000 11. 103 0. 09007 1.7180 42.963 15849.8 18912.0 138.855 33.00 53.07 656

370.000 10.718 0.09330 1.6149 43.610 16268.9 19441.0 140.305 33.50 52.76 65-. 360.000 10. 361 0.09651 1.5229 44.304 16686.0 19967.4 141.709 34.00 52.53 653

390.000 10.030 0.09970 1.4404 45.028 17102.1 20491.9 143. 071 34.52 52- 38 653

400.000 9.721 0.10287 1.3660 45.773 17517.7 21015.3 144.396 35.04 52.30 653

420.000 9.162 0. 10914 1.2374 47.321 18350.0 22060.9 146.947 36.11 52.30 65*. 440 .000 6.671 0. 11533 1.1304 48.965 19187.1 23106.3 149.383 37.19 52.46 656

460.000 6. 236 0.12142 1. 0402 50.733 20031.7 24160.2 151.721 38.28 52.74 660

460.000 7.648 0.12742 0.9634 52.585 20886.2 25218.6 153.973 39.36 53.11 665

500.000 7.501 0. 13332 0.0973 54.474 21752.3 26265.3 156.150 40.44 53.57 671

195
METHANE ISOBAR AT P * 360.0 BAR

T OEN VOL DP/OT DP/DO E H S CV CP H DEG K WOL/L 8. /MOL BAR/K BAR-L/HOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

99.551 28.812 0.03471 19.7111 269.725 3615.9 4865.4 69.429 35.62 51.71 1619

100.000 28.783 0 o 03474 19.6302 288.804 3636.7 4887.4 69.656 35.64 51.74 1617

105.008 28.465 0.03516 18.7313 276.998 3876.6 5142.2 72. 190 35.70 52. 14 1583

110.000 28.107 0.03558 17. 8691 264.731 4119.7 5400.6 74.622 35.62 52.41 1558

115.000 27.769 0.03601 17.0445 252.301 4364.8 5661.1 76.956 35.37 52.54 1528

130.000 27.431 0. 03646 16.2568 239.924 4610.5 5922.9 79.192 35.00 52.57 1499

125.000 27.092 0.03691 15.5048 227.758 4856.3 6165.1 61.336 34.59 52.57 1469

130.000 26.750 0.03738 14.7865 215.919 5102.0 6447,8 63.401 34.22 52.62 1439

135.000 26.407 0. 03787 14.1003 204.488 5347.6 6711.1 85.389 33.94 52.76 1408

140. 000 26.061 0. 03837 13.4443 193.521 5594.1 6975.5 87.312 33.76 53.01 1376

145.000 25.712 0.03869 12.8168 163.053 5641.2 7241.3 89.177 33.63 53.32 1345

150.000 25.360 0.03943 12.2163 173.101 6089.1 7508.6 90.990 33.48 53.59 1314

155.000 25.006 0.03999 11.6415 163.670 6337.4 777 7.0 92.750 33.20 53.72 1285

160.000 24.649 0.04057 11.0912 154.754 6565.0 8045.5 94.454 32.70 53.63 1258

165.000 24.289 0. 04117 10.5642 146.341 6830.9 8313.0 96. 100 31.98 53.31 1233

170.000 23.927 0.04179 10.0598 138.412 7073.8 8578.4 97.685 31.16 52.87 1210

175.000 23.563 0.04244 9.5771 130.947 7314.3 8842.2 99.212 30.96 53. 04 1183

100.000 23. 196 0.04311 9.1154 123.921 7555.2 9107.2 100.705 30.57 53.00 1157

185.000 22. 627 0. 04381 8.6740 117.314 7795.2 9372.3 102.158 30.26 53. 03 1132

190.000 22.457 0.04453 8.2522 111.103 8034.5 9637.6 103.573 30.02 53.11 1107

195.000 22.084 0.04528 7.8495 105.269 8273.3 9903.4 104.954 29.81 53. 21 1082

200.000 21.711 0.04606 7.4653 99.793 8511.7 10169.8 106.303 29.64 53. 34 1058

205.000 21.337 0.04687 7.0992 94.661 8749.6 10436.6 107.621 29.50 53.48 1034

210.000 20.961 0.04771 6.7504 69.856 8967.1 10704.6 108.912 29.39 53.63 1011

215.000 20.585 0.04858 6.4187 85.367 9224.4 10973.2 110.176 29.31 53.80 988

220.000 20.209 0.04948 6. 1034 61.183 9461.2 11242.5 111.415 29. 04 53.75 968

225.000 19.834 0.05042 5.8040 77.292 9696.5 11511.5 112.624 28.92 53. 65 947

230.000 19.459 0.05139 5.5201 73.686 9931.0 11781.1 113.608 28.86 53.98 927

235.000 19.085 0.05240 5.2511 70.354 10165.0 12051.3 114.971 26.63 54.12 907

240.000 18.712 0. 05344 4. 9964 67.265 10396.5 12322.3 116.112 26.85 54.28 888

245.000 16.342 0.05452 4. 7555 64.471 10631.4 12594.1 117.233 26.69 54.43 870

250.000 17.975 0.05563 4.5279 61.698 10663.9 12666.7 118.334 28.95 54.58 853

255.000 17.611 0.05678 4.3131 59.556 11095.6 13139.9 119.416 29.04 54. 72 836

260. 000 17. 251 0. 05797 4. 1103 57.439 11327.0 13413.9 120.480 29.15 54.85 821

265.000 16.896 0.05919 3.9192 55.529 11557.6 13686.4 121.526 29.27 54.95 806

270.000 16.545 0.06044 3.7392 53.817 11787.5 13963.3 122.553 29.40 55.03 792

275.000 16.201 0.06172 3.5696 52.292 12016.5 14238.6 123.564 29.55 55-08 779

280.000 15.863 0.06304 3.4101 50.942 12244.7 14514.1 124.556 29.71 55.11 7o7

285.000 15.532 0.06438 3.2600 49.757 12471.8 14789.6 125.532 29.88 55.11 756

290.000 15.208 0.06576 3.1188 48.726 12698.0 15065.1 126.490 30.05 55.08 746

295.000 14. 692 0. 06715 2.9861 47.837 12923.0 15340.4 127.431 30.23 55.03 737

300.000 14.584 0. 06857 2.8614 47.081 13146.9 15615.4 128. 356 30.42 54.95 728

310.000 13.993 0.07146 2.6341 45.928 13591.2 16163.9 130.154 30.82 54.74 713

320.000 13.437 0.07442 2.4334 45.194 14030.8 16710.0 131.888 31.24 54. 46 701

330. 000 12.916 0.07742 2.2561 44.816 14465.8 17253.0 133.559 31.68 54.15 691

340.000 12.430 0. 08045 2.0993 44.740 14896.6 17792.6 135. 170 32.14 53.81 683

350.000 11.977 0.08349 1.9604 44.918 15323.6 18329.3 136.725 32.61 53. 48 678

360.000 11.556 0.08653 1.8370 45.304 15747.4 16662.5 138.228 33.09 53.17 67*

370.000 11.166 0.08956 1.7271 45.845 16168.7 19392.9 139.681 33.59 52.90 671

380.000 10. 802 0. 09257 1.6289 46.481 16588.

1

19920.6 141. 089 34.10 52.69 669

390.000 10.464 0.09557 1.5407 47.165 17006.5 20446.9 142.455 34.62 52.55 669

400.000 10.148 0.09854 1.4611 47.877 17424.5 20971.9 143. 784 35.15 52.47 667

420.000 9.576 0.10443 1. 3234 49.358 16261.5 22020-9 146. 344 36.22 52.47 668

440.000 9.071 0. 11024 1.2087 50.904 19103.3 23071.6 148.788 37.30 52.65 669

460.000 8.623 0.11597 1.1118 52.538 19952.7 24127.6 151.134 38.39 52.95 672

680.000 8.222 0. 12162 1.0292 54.278 20811.9 25190.2 153.396 39.47 53.33 6 76 500. 000 7.662 0. 12719 0. 9581 56.086 21662.5 26261.3 155.582 40.55 53.79 681

196
HETHANE ISOBAR AT P = 360.6 BAR

T OEM VOL DP/D7 DP/DD E H S CV CP H OEG K MOL/l L/MOL SAR/K BAR-L/MOl J/MOL J/HOL J/MOL/K J/MOL/K J/fiOL/K fl/SEC

100.0 25 28.846 0.03467 19.6636 291.429 3 625 06 4943.0 69.517 35.75 51.69 1621

10S.000 28.516 0. 03507 18.7854 260.337 3862.4 5195.0 72. 024 35.81 52.07 1594

110.000 28.182 0.03548 17.9346 268.439 4104.6 5453.0 74.453 35.73 52.33 1565

115.000 27.648 0.03591 17.1202 256.308 4348.5 5713.1 76.782 35.48 52.44 1537

120.000 27.514 0.03635 16.3418 244.177 4593.1 5974.3 79.014 35.11 52.45 1508

125.000 27. 178 0.03679 15.5983 232.209 4637.7 6235.9 81.155 34.70 52.43 1479

130.000 26.642 0.03726 14.8860 220.531 5082.1 6497.8 83.211 34.33 52.46 1449

135.000 26.503 0.03773 14.2092 209.230 5326.5 6760.3 85.193 34.05 52.59 1419

140.000 26.163 0.03822 13.5603 198.366 5571.3 7023.8 87. 110 33.86 52. @2 1389

145.000 25. 820 0. 03873 12.9394 187 .980 5816.8 7288.6 88.968 33.74 53.11 1358

150.000 25.474 0.03926 12.3453 178.093 6063.1 7554.8 90.773 33.58 53.36 1328

155.000 25. 126 0.03980 11.7765 168.712 6309.7 7822.0 92.52 5 33.29 53.40 1300

160.000 24.77© 0.0->036 11.2319 159.836 6555.5 8089.3 94. 222 32.80 53.37 1273

165.000 24.424 0.0*094 10.7104 151.453 6799.5 8355.4 95.860 32.08 53.03 1249

170.000 24. 069 0.0* 155 10.2111 143.549 7040.5 8619.3 97.436 31.25 52.56 1227

175.000 23.712 0.04217 9.7332 136.102 7278.9 8881.5 98.953 31.05 52.71 1200

ISO. 000 23.354 0.0*282 9.2760 129.091 7517.7 9144.8 100.437 30.65 52.65 1176

1S5.000 22.994 0.04349 8.8387 122.494 7755.5 9408.1 101.880 30.34 52.66 1151

190.000 22.633 0.04418 8.4207 116.289 7992.5 9671.5 103.285 30.09 52.71 1127

195.000 22.270 0.04490 8.0215 110.457 8228.9 9935.3 104.655 29.88 52.79 1103

200.000 21.906 0.0*565 7.6405 104.977 8464.10199.4 105.992 29.71 52.89 1079

205.000 21.542 0.04642 7.2771 99.834 8700.2 10464.2 107.300 29.57 53. 00 1 0 5 0 210.000 21.178 0.0*722 6.9307 95.013 8935.2 10729.5 108.578 29.46 53.13 1034

215.000 20.613 0.04805 6.6010 90.500 9169.7 10995.5 109.830 29.37 53.27 1011

220. 000 20.448 0. 04690 6. 2872 86.264 9403.8 11262.1 111.056 29.09 53.20 992

225.000 20.084 0.04979 5.9890 82.353 9636.3 11528.3 112.253 28.97 53.27 971

230.000 19.721 0.05071 5.7059 78.598 9868.0 11794.9 113. 424 28.90 53.37 952

235.000 19.359 0.05165 5.4371 75.307 10099.2 12062.0 114.573 28.88 53.49 932

240.000 1 6o 999 0. 05263 5. 1824 72.172 10329.8 12329.8 115.701 28.89 53.63 914

245.000 18.642 0.05364 4.9411 69.283 10559.9 12598.3 116.806 28.93 53.77 8 9o 250.000 18.286 0.05469 4.7127 66.629 10789.5 12867.6 117.896 28.99 53.91 879

255.000 17.934 0.05576 4. *966 6*. 201 11018.6 13137.5 118.965 29. 08 54.05 862

260. 000 17.586 0.05686 4.2923 61.987 11247.2 13408.0 120.016 29.18 54.17 847

265.000 17.242 0 . 05800 4.0994 59.979 11475.3 13679.2 121.049 29.31 54.23 832

270.000 16.903 0.05916 3.9172 58.164 11702.7 13950.8 122.064 29.44 54. 37 818

275.000 16.569 0.0o035 3.7453 56.533 11929.4 14222.9 123. 063 29.59 5*. 45 803

260.000 16.240 0.06157 3.5831 55.076 12155.4 14495.3 124.044 29.75 54.50 793

265.000 15.916 0.06262 3.4302 53.780 12380.6 14767.8 125.009 29.92 54.52 782

290.000 15.603 0.06409 3.2860 52.636 12605.0 15040.5 125.957 30.10 54.53 771

295.000 15.294 0. 06538 3. 1501 51.636 12628.5 15313.1 126.690 30. 28 54.52 761

300.000 14.993 0.06670 3.0221 50.770 13051.1 15585.6 127.806 30.47 54.48 752

310.000 14.413 0. 06938 2.7878 49.398 13493.3 16129.9 129.590 30.68 54.36 7 3o 320.000 13.664 0. 07213 2.5799 48.450 13931.7 16672.5 131.313 31.30 54.17 723

330. 000 13. 348 0. 07492 2.3954 47.866 14366.3 17213.2 132.977 31.75 53.95 712

340.000 12.863 0.07774 2. 2313 47.590 14797.4 17751.5 134.584 32.21 53.71 703

350.000 12.410 0.03053 2. 0853 47.576 15225.3 18287.3 136.137 32.69 53. 46 696

360.000 11.986 0.03343 1.9551 47.788 15650.5 18820.7 137.640 33.18 53.22 691

370.000 11.591 0. 03627 1.8388 48.183 16073.5 19351.8 139.095 33.68 53.01 687

380. 000 11.223 0.03911 1.7344 48.718 16494.9 19881.0 140.506 34.20 52.83 685

390.000 10. 878 0.09193 1.6406 49.344 16915.4 20408.5 141.876 34.72 52.69 683

400.000 10.557 0.09473 1.5559 50.017 17335.5 20935.

143.209 35. 25 52-62 682

420.000 9.973 0.10027 1.4093 51.438 16176.9 21987.2 145.776 36.32 52.63 682

440.000 9.457 0. 10574 1.2869 52.922 19023.0 23041.3 148.228 37.41 52.81 682

460.000 8.997 0. 11115 1.1836 54.462 19876.7 24100.3 150.582 38.50 53. 12 68*

480.000 6.585 0. 11648 1.0953 56.083 20740.1 25166.5 152.850 39.58 53.52 687

500.000 8.214 0. 12175 1.0191 57.793 21615.0 26241.4 155.044 4 0 • 6 6 53.98 692

197
HETHAME ISOBAR AT P * 400.0 86R

T DEN VOL DP/OT OP/D0 E H S CV CP H OEG K HOt/ L L/MQL BAR/K BAR-l/MOL J/MOL J/NOL J/NOL/K J/MOL/K J/HOL/K M/SEC

100.496 26.880 0.03463 19.6174 293.083 3635.5 5020.5 69.606 35.86 51.69 1623

103.000 28.567 0.03496 18.6370 263.552 3846.6 5247.9 71.660 35.93 52.00 1600

US. 00© 28.256 0.03539 17.9976 272.034 4089.8 5505.5 74.286 35.84 52.25 1572

115. 000 27.925 0.03581 17.1933 260.213 4332.3 5765.2 76.611 35.59 52. 34 1544

120.000 27.595 0.03624 16.4240 248.332 4576.3 6025.6 78.639 35.22 52.34 1517

125.000 27.264 0.03668 15.6888 236.570 4819.7 6286.8 80.974 34.60 52.30 1489

130.000 26.932 0. 03713 14.9863 225.057 5062.8 6546.1 83.026 34.43 52. 32 1460

135.000 26.598 0.03760 14.3148 213.889 5305.9 6809.8 85.002 34.15 52.43 1431

140.000 26.262 0.03608 13.6726 203.132 5549.3 7072.4 86.912 33.96 52. 6* 1401

145.000 25.925 0.03857 13.0582 192.829- 5793.4 7336.3 88.764 33.83 52.91 1371

150.900 25.585 0.03909 12.4702 163.006 6038.

1

7601.5 90.562 33.66 53.15 1342

155.000 25.243 0.03961 11.9072 173.676 6283.0 7867.6 92.307 33.39 53.25 1314

160.000 24. 699 0.04016 11.3680 164.839 6527.2 8133.7 93.996 32.69 53. 12 1288

165.000 24.554 0.04 07 3 10.3517 156.487 6769.4 3398.5 95.626 32.17 52.76 1265

170.000 24. 206 0. 04131 10.3572 146.604 7008.6 6661.1 97.194 31.34 52.28 1243

175.000 23.857 0.04192 9. 8839 141.174 7245.1 6921.6 98.703 31.13 52.41 1217

ISO. 000 23.506 0. 0-+254 9.4308 134.176 7461.9 9183.6 100.176 30.74 52.33 1193

105.000 23.154 0.04319 8. 9974 127.567 7717.6 9445.2 101.612 30.42 52. 32 1169

190.000 22.601 0.04386 8.5830 121.366 7952.6 9706.9 103.007 30.17 52.35 1146

195.000 22.447 0.04455 8. 1870 115.554 8186.

6

9968.8 104.368 29.96 52.41 1123

200.000 22.092 0.04526 7.8088 110.070 8420.4 10231.0 105.695 29.78 52.48 1100

205.000 21.738 0.04600 7.4479 104.918 8653.5 10493.6 106.992 29.64 52.58 1077

210. 000 21. 363 0.04677 7.1038 100.082 8866.1 10756.7 108.261 29.52 52.68 1055

215.000 21.028 0.04756 6.7758 95.546 9118.2 11020.4 109.502 29.43 52.79 1034

220.000 20.674 0.04837 6.4635 91.303 9349.6 11284.7 110.717 29.15 52.70 101-t 225. 000 20.320 0.04921 6.1663 67.336 9579.6 11546.3 1 1 1 . 90 1 29.03 52.75 995

230.000 19.968 0.05008 5.8638 83.637 9809.0 11612.2 113.062 26.96 52.83 975

235.000 19.617 0.05098 5.6155 60.196 10037.6 12076.7 114.199 28.93 52.94 956

240.000 19.268 0. 05190 5.3607 77.002 10265.6 12341.7 115.315 26.93 53.06 938

245.000 16.921 0.05285 5.1190 74.047 10493.2 12607.3 116.410 28.97 53. 19 921

250.000 18.576 0.05383 4.6898 71.321 10720.3 12873.6 117.466 29.04 53.32 904

255.000 16.235 0.05484 4.6727 68.614 10947.0 13140.5 118.543 29.12 53.45 887

260.000 17.896 0. 05587 4.4671 66.517 11173.2 13406.1 119.563 29.23 53.58 872

265. 000 17.564 0.05694 4.2725 64.419 11396.9 13676.3 120.604 29.35 53.69 657

270.000 17.234 0.05602 4.0665 62.512 11624.1 13945.0 121.609 29.46 53. 79 843

275.000 16.910 0.05914 3.9144 60.765 11646.7 14214.2 122.597 29.63 53.67 830

200.000 16.591 0.06028 3.7499 59.229 12072.7 14463.7 123.568 29.79 53. 94 618

205.000 16. 277 0.06144 3.5944 57.834 12296.

1

14753.6 124.523 29.96 53.99 80b

290.000 15.969 0.06262 3.4476 56.590 12516.8 15023.6 125. 463 30.14 54. 03 795

295.000 15.666 0. 06 363 3. 3086 55.487 12740.6 15293.6 126.366 30.33 54. 04 785

300.000 15. 373 0.06505 3. 1778 54.516 12962.0 15564.0 127.294 30.52 54.0 4 776

310.000 14. 604 0.06755 2. 9373 52.943 13402.2 16104.2 129.066 30.93 53. 98 759

320.000 14. 264 0. 07011 2.7229 51.797 13839.2 16643.5 130.276 31.36 53.88 745

330.000 13. 753 0. 07271 2.5317 51.021 14273.1 17181.6 132.434 31.82 53.73 733

340.000 13.271 0. 07535 2.3611 50.561 14704.1 17718.2 134.036 32.26 53.57 723

350.000 12. 819 0.07801 2.2066 50.371 15132.5 16253.0 135.586 32.77 53.39 715

360.000 12.394 0.08068 2.0720 50.412 15558.6 16786.0 137.086 33.26 53.22 709

370.000 11.996 0.06336 1.9496 50.650 15963.0 19317.5 138.544 33.77 53.06 7 04 380.000 11.624 0.08603 1.8395 51.052 16406.1 19847.4 139.957 34.29 52.93 701

390.000 11.275 0. 08869 1.7402 51.561 16826.4 20376.1 141.330 34.81 52.82 698

400.000 10.948 0. 09134 1.6505 52.197 17250.4 20904.0 142.667 35.34 52.76 697

420.000 10. 354 0.09656 1.4949 53.550 18095.6 21959.0 145.240 36.42 52. 77 695

440.000 9.827 0.10176 1.3651 54.962 16945.8 23016.1 142.699 37.51 52. 95 696

460. 000 9.358 0. 10686 1. 2553 56.463 19803.5 24078.1 150.059 38.61 53.27 697

480.000 8.936 0.11191 1.1614 57.993 20670.9 25147.4 152.335 39.69 53.67 699

500.000 8.555 0. 11690 1 . 0803 59.597 21549.6 26225.5 154.535 40.77 54.15 702

198
METHANE ISOBAR AT P = 450.0 BAR

T DEN VOL DP/DT OP/OO E H S CV CP H DEG K MOL/L L/MOL BAR/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

101.667 20.963 0.03453 19.5048 296.994 3660.7 5214.4 69.827 36.15 51.67 1627

105.000 20.761 0.03477 18.9561 291.033 3815.6 5380.2 71.460 36.20 51.87 1612

110. 000 28.437 0.03517 18. 1449 280.522 4054.6 5637.1 73.879 36.11 52.08 1588

115.000 20.114 0.03557 17.3653 269.517 4295.2 5695.8 76. 196 35.85 52.13 1563

120.000 27.792 0.03590 16.6182 258.301 4536.2 6155.3 78.414 35.48 52.09 1537

125.000 27.471 0.03640 15.9032 247.079 4776.9 6415.0 80.538 35. 06 52.02 1512

130.000 27. 140 0.03603 15.2193 236.003 5017.2 6674.7 82.578 34.68 51.99 1485

135.000 26.026 0.03720 14.5650 225.185 5257.2 6934.7 84.541 34.40 52.07 1458

140 .000 26.502 0. 03773 13. 9390 214.706 5497.5 7195.5 86.438 34.21 52.25 1430

145.000 26. 176 0.03020 13.3398 204.621 5738.2 7457.3 88.275 34.07 52.48 1*02

150.000 25. 050 0.03069 12.7661 194.966 5979.4 7720.2 90.058 33.91 52.68 1374

155.000 25.522 0.03910 12.2165 185.767 6220.6 7983.9 91.786 33.62 52.74 1348

160.000 25.192 0.03970 11.6900 177.027 6461.0 8247.3 93.459 33.11 52.58 1324

165.000 24.061 0. 04022 11.1855 168.746 6699.2 8509.2 95.071 32.38 52. 18 1302

170.000 24.529 0.04077 10.7021 160.916 6934.3 8768.8 96.621 31.55 51.66 1282

175.000 24. 196 0. 04133 10.2390 153.523 7166.5 9026.3 98.111 31.34 51.75 1257

160.000 23.062 0.04191 9.7955 146.549 7399.

9284.8 99.567 30.94 51.63 1235

185.000 23.528 0.0*250 9. 3708 139.974 7630.2 9542.8 100.981 30.62 51.58 1212

190.000 23.193 0.04312 8.9643 133.779 7860.4 9800.7 102.357 30.36 51.57 1190

195.000 22.050 0.0*375 8.5754 127.943 8089.9 10058.6 103.697 30. 14 51.59 1168

200.000 22. 523 0 . 0*4*0 8. 2036 122.447 8318.6 10316.6 105.003 29.96 51.63 1147

205.000 22. 180 0.0*507 7.8482 117.272 8546.7 10574.9 106.279 29.80 51.68 1126

210.000 21.854 0.0*576 7.5088 112.403 8774.

10833.4 107.524 29.68 51. 74 1105

215.000 21.520 0.04647 7.1847 107.823 9001.2 11092.3 108.743 29.58 51.81 1085

220.000 21.187 0.0*720 6.8755 103.519 9227.5 11351.4 109.935 29.30 51.68 1067

225.000 20.056 0.0*795 6.5807 99.479 9452.2 11609.8 111.096 29. 17 51.68 10*8

230. 000 20.526 0. 0*872 6. 2997 95.691 9676.0 11868.4 112.232 29.09 51.73 1030

235.000 20. 190 0.0*951 6.0320 92.145 9899.2 12127.2 113.346 29.06 51.80 1012

240.000 19.071 0.05032 5.7772 68.832 10121.9 12386.4 114.437 29.06 51.89 99*

245.000 19.547 0.05116 5.5347 85.742 10344. 1 12646.2 115.508 29. 09 52.00 977

250.000 19.226 0.05201 5.3041 82.867 10565.9 12906.5 116.560 29.15 52.11 961

255.000 10.907 0. 05289 5.0848 80.197 10787.3 13167.3 117.593 29.23 52.23 945

260.000 10.592 0.05 379 4.8765 77.725 11008.4 13428.8 118.609 29.34 52. 35 930

265.000 10.200 0.05470 4.6785 75.442 11229.2 13690.8 119.607 29.46 52.47 915

270.000 17.972 0. 05564 4. 4905 73.339 11449.6 13953.5 120.589 29.59 52.58 901

275.000 17.660 0.05660 4.3120 71.409 11669.6 14216.6 121.554 29.74 52.68 888

200.000 17.360 0.05758 4.1426 69.642 11889.3 14480.3 122. 504 29.91 52.73 875

205.000 17.073 0.05857 3.9818 68.032 12108.7 14744.4 123.439 30.08 52. 86 863

290.000 16.703 0.05958 3.8293 66.569 12327.6 15008.9 124.359 30.26 5 2. 94 052

295.000 16.490 0.06061 3.6846 65.245 12546.2 15273.8 125.265 30.45 53.01 841

300.000 16.210 0.06 16b 3.5473 64.052 12764.3 15538.9 126. 156 30.65 5 3 • 0 o 831

310.000 15.676 0.06 37 9 3.2936 62.032 13199.3 16069.9 127. 897 31.07 53.13 813

320.000 15.157 0.06598 3.0653 60.447 13632.5 16601.5 129.585 31.52 53.17 797

330.000 14.662 0.05820 2.8598 59.244 14064.0 17133.2 131.221 31.98 53.17 78*

340.000 14. 191 0.07047 2.6748 58.372 14493.9 17664.8 132.808 32.46 53.15 772

350.000 13.745 0. 07275 2. 5080 57.787 14922.3 18196.2 134. 348 32.95 53.12 762

360.000 13.323 0.07506 2.3575 57. *48 15349.6 18727.2 135.844 33.46 53.08 754

370.000 12.924 0.07737 2.2214 57.323 15776.0 19257.8 137.298 33.98 53.05 747

300. 000 12.540 0.07970 2.0983 57.382 16201.9 19788.2 138.713 34.50 53.02 741 390.000 12. 193 0.03202 1.9865 57.600 16627.6 20318.3 140.090 35.04 53.01 737

400.000 11.050 0.08433 1.8849 57.956 17053.4 20848.4 141.432 35.58 53.02 73*

420.000 11.244 0.0889* 1.7079 58.982 17907.2 21909.4 144.020 36.67 53.10 730

440. 000 10.696 0.09349 1.5596 60.254 18766.0 22973.1 146.494 37.76 53. 29 728

460 .000 10.205 0.09799 1,4339 61.617 19632.3 2*041.8 148.869 38.86 53.60 728

400.000 9.763 0.10243 1.3263 63.026 20508.4 25117.7 151.159 39.95 54.01 729

500.000 9.361 0. 10682 1.2332 64.467 21395.6 26202.6 15 3.37 3 41. 03 54.49 731

199
METHANE ISOBAR ATP® § 00.0 BAR

T DEN VOL QP/OT DP/OD E •H S CV CP M DEG K NOL/L L/MGL BAR/K 8AR-1/M0L J/MQL J/ MOL J/NOL/K J/MOL/K J/MOL/K N/SEC

102.026 29.046 0. 03443 19.3970 300.533 3686.

8

9408.2 70.048 36.42 51.67 1631

105.008 28.931 0.03456 19.0616 297.687 3784.6 5512,8 71,072 36.46 51.77 1623

110.000 28.613 0.03495 18.2783 268,274 4021.6 5769,1 73.485 36.37 51.94 1602

115.000 28. 297 0.03534 17.5230 276.159 4260.1 6027.1 75.795 36.11 51.96 1580

120.000 27.982 0.03574 16.7975 267.664 4498.8 6285.6 78. 005 35,72 51.88 155/

125.000 27.669 0.03614 16. 1019 257.027 4737.1 6544.2 80.121 35.30 51.77 1533

130.000 27.356 0.03656 15.4357 246,425 4974,

6802,6 82.150 34.92 51.72 1508

135.000 27. 042 0.03698 14.7978 235,967 5212.2 7061.1 84,192 34.63 51.76 1483

160.090 26.729 0.03741 14.1869 225.610 5449.6 7320,2 85.987 34.44 51.90 145/

145.000 26.414 0.03786 13.6018 215.963 5687.3 7580,2 87.812 34.30 52.10 1430

150.000 26.099 0.03632 13.0412 208.493 5925.4 7841.2 ®9,§Si 34.13 52. 27 1404

155.000 25.763 0.03879 12.5039 197.431 6163.5 8102.® 91.296 33.64 52.30 13/9

160.000 25.465 0.03927 11.9839 168.794 6400.5 8363.9 92,954 33.33 52.11 1356

165.900 25.168 0.0397/ 11.4951 160.567 6635.2 8623.5 94.552 32.59 51.68 1336

170.000 24. 829 0.0*026 11.0216 172.608 6666.8 8880.5 96. 096 31.75 51.14 131/

1/5.000 24.510 0.04080 10.5677 165. 448 7095.4 9135.4 97.561 31.54 51.20 1294

180. 000 24. 190 0.04134 10.1325 158.494 7324.

0

9391.0 99.001 31.13 51.06 12/3

185.000 23.871 0.04189 9.7155 151.928 7551.4 9646.0 100.399 30.81 50.98 1252

190.000 23.551 0.04246 9.3159 145.732 7777.8 9900.8 101. 758 30.54 50.94 1231

195. 000 23.231 0. 04305 8.9332 139.868 8003.2 10155.5 103.061 30.31 50.93 1210

200.000 22.912 0. 04 364 8.5668 134.376 8227.9 10410.1 104.370 30.13 50.93 1190

205.000 22.594 0.0*426 8.2161 129.179 8451.9 10664.8 105.628 29.97 50.95 11/0

210.000 22.276 0.0*469 7.8807 124.279 8679.2 10919.7 106.656 29. 84 50. 99 1151

215.000 21.960 0. 04554 7.560Q 119.660 8897.8 11174.7 108.057 29.73 51.03 1131

220.000 21.645 0.04620 7.2534 115.308 9119.9 11429.9 109.230 29.44 50.87 1114

225.000 21.331 0 . 046 66 6.9605 111.210 9340.2 11684.2 110. 373 29.31 50. 65 109/

230.000 21. 019 0. 04758 6.6808 107.353 9559.7 11938.5 111.491 29.23 50.87 10/9

235.000 20.709 0.04629 6.4138 103.727 9770.6 12193.0 112.586 29.19 50.92 1062

240.000 20.401 0. 04902 6.1590 100.323 9996.9 12447.8 113.659 29.19 50.99 1045

245.000 20.095 0.0*976 5.9159 97.129 10214.0 12703.0 114.711 29.22 51.08 1029

250.000 19.792 0.05053 5.6841 94.139 10432.3 12958.7 115.744 29.26 51.18 1013

255.000 19.691 0.05131 5.4632 91.344 10649.6 13214.8 116.750 29.36 51.29 99/

260.000 19.194 0.05210 5.2526 88.735 10666.5 13471.6 117.756 29.46 51.40 982

265.000 18.699 0. 05291 5. 0520 86.306 11063.

3

13728.9 118.736 29.56 51.52 968

2/0.000 18.606 0.05374 4.8609 84.049 11299.6 13906.8 119.700 29.71 51.63 954

2/5.000 16.321 0.05456 4.6789 81.957 11516.1 14245.2 120.648 29.66 51.75 941

260.000 16.037 0.05544 4.5056 80.021 11732.2 14504.2 121.582 30.03 51.86 928

285.000 17.758 0.05631 4.3405 78.236 11948.2 14763.0 122.501 30.20 51.9/ 916

290.000 17.463 0.05720 4.1634 76.593 12163.9 15023.9 123.405 30.39 52.0/ 90*

295. 000 17.212 0. 05610 4.0339 75.087 12379.5 15284.5 124.296 30.58 52.16 893

300.000 16.966 0.05901 3.6915 73.709 12594.9 15545.5 125.173 30.78 52. 25 883

310.000 16.427 0.0608/ 3.6271 71.315 13025.1 16068.8 126.889 31.21 52.40 86*

320.000 15.929 0.062/6 3.3674 69.357 13454.5 16593.5 126.555 31.66 52. 53 84/

330.000 15.451 0.064/2 3. 1702 67.786 13683.2 17119.3 130. 173 32.14 52.63 832

360.000 14.993 0.06670 2.9733 66.557 14311.3 17646.1 131.746 32.63 52. Z2 819

350.000 14.557 0.068/0 2.7945 65.627 14738.6 16173.6 133.275 33.13 52. Z9 80/

360.000 14. 142 0. 0/0/1 2.6321 64.956 15166.1 18701.6 134.763 33.65 52.85 79/

3/0.000 13.746 0. 0/2/5 2.4844 64.516 15593.3 19230.6 136.211 34.17 52.91 Z89

380.000 13.371 0.0/479 2.3499 64.271 16020.6 19759.9 137.623 34.71 52.9/ /82

390.000 13.015 0.0/683 2.2272 64.199 16448.2 20290.0 139.000 35.25 53.04 776

600.000 12.677 0. 0/666 2. 1151 64.277 16876.6 20820.7 140.344 35.80 53.12 77 1 420.000 12. 053 0.08297 1.9164 64.810 17736.5 21865.0 142.940 36.90 53.31 / 6* 440.000 11.491 0.06703 1.7525 65.736 18602.4 22953.7 145.426 36.00 53.5/ Z60

460.000 10.966 0.09104 1.6113 66.916 19476.

1

24028.3 147.614 39.10 53.90 /58

480.000 10.525 0.09501 1.4902 68.216 20359.6 25110.1 150.116 40.20 54.30 Z58

500.000 10.106 0.09693 1.3654 69.566 21254.2 26200.8 152.342 41.27 54.// Z59

200
METHANE ISOBAR ATP* 550.0 BAR

T DEN tfOL OP/DT OP/OO E H S Ctf CP H OEG K HOL/L l/HOL BAR/K 8AR-L/M0L J/WOL J/MOL J/HOL/K J/HOU/K J/MOL/K M/SEC

103.974 29.126 0.03433 19.2938 303.366 3713.5 5601.8 70.269 36.66 51.67 1634

105.000 29.097 0.03437 19.1540 303.467 3755.3 5645.5 70.695 36.71 51.71 1632

110.000 26.784 0.03474 18.3987 295.260 3990.6 590 1.4 73.104 36.61 51.84 1614

115.000 26.474 0.03512 17.6676 286.116 4227.1 6158.7 75.408 36.35 51. 82 1595

120.000 26.166 0.03550 16.9632 276.407 4463.8 6416.5 77.611 35. 96 51.71 1574

125.000 27.660 0.03569 16.2865 266.408 4699.9 6674.1 79.719 35.53 51.57 1552

130.000 27.555 0.03629 15.6373 256.322 4935.4 6931.4 81.740 35.15 51.43 1530

135.000 27.250 0.03670 15.0149 246.300 5170.3 7188.7 83.683 34.85 51.49 1506

140.000 26.945 0.03711 14.4184 236.455 5405.2 7446.4 85.557 34.66 51.61 1482

145.000 26.640 0.03754 13.8465 226.869 5648.3 7704.9 87.371 34.51 51.78 1457

150.000 26.335 0.03797 13.2982 217.602 5875.7 7964.2 89. 129 34.34 51. 92 1432

155.000 26.029 0.03642 12.7723 208.694 6110.8 8223.9 90.832 34.04 51.93 1409

160.000 25.723 0.03688 12.2678 200.171 6344.9 8483.1 92.478 33.53 51.71 1387

165.000 25.416 0.03935 11.7838 192. Q46 6576.6 8740.6 94.063 32.79 51.26 1366

170.000 25.109 0.03983 11.3194 184.323 6805.8995.5 95. 585 31.94 50-69 1350

175.000 24.602 0.04032 10.6738 176.998 7030.4 9248.0 97.046 31.72 50.73 1328

180.000 24.495 0.0*083 10.4463 170.062 7255.8 9501.2 98.473 31.31 50.56 1308

185.000 24.188 0.04134 10.0361 163.503 7479.9 9753.8 99.857 30.99 50.47 1288

190. 000 23.681 0. 04187 9.6427 157.304 7702.8 10095.9 101.202 30.71 50.41 1269

195.000 23.575 0.04242 9.2655 151.449 7924.9 10257.9 102.511 30.46 50. 37 1249

200.000 23.269 0.04296 6.9039 145.920 8146.1 10509,7 103.786 30.29 50.36 1230

205.000 22.965 0.04355 8.5574 140.699 8366.5 10761.5 105.029 30.13 50.36 1211

210.000 22.661 0. 04413 8.2255 135.770 8586.3 11013.3 106.243 30.00 50.37 1192

215.000 22.359 0.04473 7.9076 131.116 8805.4 11265.3 107.428 29.89 50.40 117*

220.000 22.056 0.04533 7.6034 126.722 9023.8 11517.3 108.587 29.59 50.22 1158

225.000 21.759 0.0*596 7.3122 122.575 9240.5 11768.3 109.715 29.45 50.18 11*1

230.000 21.462 0.04659 7.0336 118.662 9456.4 12019.2 110.818 29.37 50. 19 112*

235.000 21.166 0.04725 6.7671 114.972 9671.7 12270.2 111.898 29.33 50.22 1106

240.000 20.673 0.04791 6.5124 111.494 9886.* 12521.4 112.956 29.32 50.26 1092

245.000 20.562 0. 0*659 6.2689 106.219 10100.8 12773.0 113.993 29. 35 50. 35 107o

250.000 20.294 0.04928 6.0362 105.138 10314.8 13025.0 115.011 29.40 50.44 1060

255.000 20.006 0.04998 5.6139 102.244 10528.5 13277.4 116.011 29.48 50.54 10*5

260.000 19.725 0.05070 5.6015 99.527 10742.1 13530.4 116.994 29.58 50.65 1031

265.000 19.445 0. 05143 5.3967 96.982 10955.5 13784.0 117.960 29.70 50.76 1016

270.000 19.169 0.05217 5.2050 94.601 11168.8 14038.1 118.910 29.84 50.86 1003

275.000 16.695 0. 05292 5.0201 92.377 11382.0 14292.8 119.844 29.99 51.00 990

280.000 18.625 0.05369 4.8436 90.305 11595.1 14548.1 120.764 30.15 51.12 977

285.000 18. 359 0.05447 4.6750 88.376 11808.2 14804.0 121.670 30.33 51.24 965

290.000 16.096 0.05526 4.5142 66.566 12021.2 15060.5 122.562 30.51 51.36 953

295.000 17.636 0.05606 4.3606 84.928 12234.2 15317.6 123.441 30.71 51.47 942

300.000 17.563 0.05667 4.2140 63.396 12447.2 15575.2 124. 307 30.92 51.58 931

310.000 17.086 0.05853 3.9406 80.685 12873.0 16092.1 126.002 31.35 51.79 911

320.000 16.606 0.06022 3.6914 78.407 13298.9 16610.9 127.649 31.81 51.98 894

330.000 16.144 0.06194 3.4643 76.517 13724.8 17131.5 129.251 32.29 52.15 878

3*0.000 15.701 0.06369 3.2572 74.974 14150.8 17653.8 130.811 32.79 52.31 863

350.000 15.276 0.06546 3.0682 73.739 14577.1 18177.6 132.329 33.30 52.45 851

360.000 14.869 0.06726 2.8956 72.775 15003.8 18702.8 133.808 33.83 52.59 640

370.000 14.460 0.06906 2.7377 72.050 15430.9 19229.* 135.251 34.36 52.72 830

380.000 14. 109 0. 07036 2.5933 71.534 15658.

19757.2 136.659 34.90 52.65 822

390.000 13. 754 0. 07270 2.4609 71.203 16287.7 20266.4 138.033 35.45 52.98 814

400.000 13.417 0.07453 2.3395 71.033 16717.6 20816.9 139.376 36.00 53. 12 608

420.000 12.769 0.07619 2.1251 71.099 17581.8 21882.3 141.975 37.11 53.42 799

440.000 12.220 0.03184 1.9430 71.606 18453.1 22954.1 144.468 38.23 53.76 792

460. 000 11.702 0. 09546 1.7672 72.452 19333.0 24033.0 146.866 39.33 54.14 788

480.000 11.231 0.03904 1.6530 73.543 20222.9 25120.0 149.179 40.43 54. 57 787

500.000 10.801 0.09253 1.5366 74.775 21124.0 26216.0 151.416 41.51 55.04 786

201
METHANE ISOBAR AT P s 600.0 BAR

T OEN WOL DP/DT OP/DO E H S CV CP W 0£6 K NOL/L L/MOL 8&R/K BAR-L/MOL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

105.111 29.206 0.03424 19.1951 306.628 3740.9 5795.3 70.490 36.66 51.66 1637

110.000 29.952 0.03454 16.5071 301.436 3961.3 6033.7 72.733 36.65 51.76 1625

115.060 29. 64 6 0.03491 17.7999 293.358 4196.1 6290.6 75. 033 36.56 51.71 1608

120.600 29.344 0.63526 17.1164 264.511 4431.0 6547.6 77.231 36.16 51.57 1590

125.006 29.045 0.03566 16.4562 275.211 4665.1 6804.6 79.332 35.75 51.40 1570

ISO. 000 27.746 0.03604 15. 8255 265.690 4898.5 7061.0 81.346 35.36 51.28 1550

135.000 27.449 0.03643 15.2161 256.125 5131.3 7317.2 83.280 35.06 51.27 1528

140.000 27.152 0.03663 14.6352 246.645 5363.9 7573.7 35.146 34.86 51.35 1505

145.000 26.695 0.03724 14. 0759 237.349 5596.6 7630.6 86.951 34.72 51.50 1481

150.060 26.559 0.03765 13.5391 226.309 5829.5 6086.7 66.699 34.54 51.62 1458

155. 006 26.262 0.03608 13.0240 219.574 6062.2 8346.8 90.392 34.24 51.60 1436

160.000 25.966 0.03851 12.5294 211.180 6293.6 8604.4 92.027 33.72 51.36 1416

165.000 25.669 0.03696 12.0545 203.148 6522.6 8860.1 93.601 32.96 50.69 1398

170.666 25.372 0.03941 11.5985 195.489 6748.3 9113.0 95.111 32.13 50.30 1381

175.000 25.076 0.03968 11. 1605 186.205 6970.8 9363.6 96.561 31.90 50.32 1360

100.000 24.779 0.04036 10.7400 181.292 7193.3 9614.7 97.976 31.49 50.14 1341

105.000 24.493 0.04084 10.3361 174.741 7414.5 9865.1 99.348 31.16 50.03 1322

190.000 24.199 0.04134 9.9484 168.539 7634.5 10115.1 100.681 30.83 49.95 1304

195.000 23.993 0.04165 9.5761 162.673 7853.5 10364.7 101.978 30.65 49.90 1285

200.000 23.599 0.04237 9. 2189 157.125 8071.7 10614.1 103.241 30.45 49.67 1267

205.000 23.307 0.04291 8.8762 151.661 8289.1 10663.5 104.472 30.29 49. 86 1248

210.000 23.015 0.04345 8.5475 146.923 8505.8 11112.8 105.674 30.15 49.66 1231

215.000 22.725 0.04400 8.2322 142.235 8721.8 11362.1 106.847 30.03 49.87 1213

220.000 22.436 0.04457 7.9300 137.803 8937.2 11611.4 107.994 29.74 49.68 1196

225.000 22. 149 0.04515 7.6403 133.613 9150.6 11859.7 109.110 29.59 49.63 1182

230.000 21. 964 0.04574 7.3628 129.652 9363.6 12107.8 110.201 29.51 49.62 1166

235.000 21.592 0.04634 7.0969 125.906 9575.8 12356.0 111.268 29.46 49. 65 1150

240.000 21.301 0.04695 6.8422 122.370 9787.5 12604.3 112.314 29.46 49.69 1134

245.000 21.022 0.04757 6.5984 119.026 9998.9 12853.0 113.339 29.46 49.76 1119

250.000 20.747 0.04620 6.3649 115.874 10209.9 13102.0 114.345 29.53 49.64 1 1 Oh 255.000 20.473 0.04664 6. 1*15 112.698 10420.7 13351.4 115. 333 29.61 49.94 1089

260.000 20.203 0.04950 5.9276 110.095 10631.4 13601.3 116.304 29.71 50.04 1075

265.000 19.935 0.05016 5.7229 107.456 10842.0 13651.6 117.256 29.83 50.15 1061

270.000 19.670 0.05064 5.5271 104.974 11052.6 14102.9 116.196 29.96 50.27 1048

275.000 19.409 0.05152 5.3397 102.644 11263.1 14354.6 119.120 30.11 50.39 1035

200.000 19.150 0.05222 5.1605 100.458 11473.7 14606.9 120.029 30.28 50.52 1022

295.000 19.995 0. 05292 4.9889 98.412 11664.

3

14659.8 120.924 30.46 50.65 1010

290.000 19.643 0.05 364 4.8249 96.499 11895.0 15113.3 121.606 30.64 50.77 998

295.000 19.395 0.05436 4.6679 94.715 12105.7 15367.5 122.675 30.64 50.90 987

300.000 19. 150 0. 05510 4.5177 93.052 12316.6 15622.3 123.532 31.05 51.02 976

310.000 17.672 0.05659 4.2366 90.073 12738.6 16133.6 125.209 31.49 51.27 956

320.000 17.210 0.05611 3.9793 67.519 13161.2 16647.7 126.840 31.95 51.50 938

330.000 16.763 0. 05966 3.7436 85.352 13584.5 17163.8 128.426 32.44 51. 72 921

340.000 16.332 0. 06123 3.5277 63.532 14006.4 17662.1 129.976 32.95 51.94 906

350.000 15.916 0.06262 3.3296 62.025 14433.2 16202.5 131.464 33.47 52.14 892

360.000 15.521 0.06443 3.1482 80.796 14859.0 18724.8 132.956 34.00 52.33 880

370.000 15.139 0.06605 2.9815 79.815 15285.

6

19249.1 134.392 34.54 52. 52 870

390.000 14. 773 0.06769 2. 8263 79.053 15713.6 19775.2 135.795 35.09 52.70 660

390.000 14.423 0.06933 2.6673 76.465 16143.2 20303.2 137. 166 35.64 52. 69 652

400.000 14.066 0.07098 2.5574 78.069 16574.2 20833.0 138.508 36.20 53.08 845

420.000 13.462 0. 07428 2. 3271 77.732 17441.4 21096.4 141. 107 37.32 53.46 833

440.000 1 2. '669 0.07758 2.1301 77.849 16316.7 22971.6 143.603 36.44 53.88 825

460.000 12.366 0.08067 1.9607 78.338 19201.5 24053.6 146.006 39.55 54.31 619

400.000 11. 667 0.08413 1.6141 79.121 20096.6 25144.5 148.329 40.65 54.78 815

500. 000 11.447 0.06736 1.6666 60.128 21003.6 26245.0 150.575 41.73 55.28 813

202
METHANE ISOBAR AT P * 650.0 BAR

T OEN VOL DP/DT DP/OD E H S CV CP H OEG K MOL/L L/MOL 8AR/K BAR-L/MOL J/MOL J/MOL J/HOL/

J/HOL/K J/MOL/K M/SEC

106.238 29.284 0.03415 19. 1005 309.474 3768.8 5988.5 70.710 37.09 51.69 1640

110.000 29. 116 0.03435 13.6039 306.750 3933.7 6166.1 72.371 37.07 51.71 1633

115.000 28.815 0.03470 17.9209 299.850 4166.9 6422.7 7*. 668 36.80 51.63 1619

120.000 28.518 0.03507 17.2581 291.950 4400.1 6679.4 76.86 2 36.40 51.45 1604

125.000 28.224 0.03543 16.6180 283.417 4632.5 6935.6 78.958 35.96 51.26 1587

130.000 27.931 0.03580 16.0015 274.517 4864.0 7191.2 80.966 35.57 51.11 1568

135.000 27.640 0.03618 15.4085 265.454 5094.9 7446.5 82.894 35.27 51,07 1548

140. 000 27. 351 0.03656 14.8388 256.379 5325.4 7701.9 84.752 35.06 51.13 1527

145.000 27.062 0.03695 14. 2915 247.406 5556.0 7957.9 86.548 34.91 51.26 1505

150.000 26. 773 0.03735 13. 7658 238.620 5786.7 8214.5 88.288 34.73 51.3 = 1483

155.000 26.485 0.03776 13.2608 230.081 6017.0 8471.3 89.971 34.43 51.31 1462

160.000 26. 197 0.03817 12.7755 221.835 6246.

8727.3 91.597 33.90 51.06 14*3

165 .000 25.909 0.03860 12.3092 213.912 6472.7 8981.5 93. 161 33.16 50.57 1426

170.000 25.621 0. 03903 11.8610 206.329 6695.8 9232.8 94.662 32. 30 *9.96 1410

175.000 25.334 0.03947 11.4303 199.095 6915.9 9481.6 96. 102 32. 08 49- 97 1390

180.000 25.047 0.03992 11.0162 192.211 7135.8 9730.9 97.507 31.66 *9. 77 1372

105.000 24.761 0. 0*039 10.6182 185.672 7354.9979.4 98. 869 31. 32 49. 64 135*

190.000 24.475 0.04086 10.2357 179.471 7571.7 10227.4 100. 191 31.04 49.56 1336

195.000 24.191 0.0*134 9. 8681 173.595 7788.1 10475.1 101.478 30.81 49.50 1319

200. 000 23. 907 0. 04183 9.5149 168.030 8003.6 10722.5 102.730 30.60 49.46 1301

205.000 23.624 0. 0*233 9. 1757 162.762 8218.3 10969.7 103.951 30.44 *9.44 1284

210.000 23. 343 0.0428* 8. 8499 157.776 8432.3 11216.9 105. 142 30.29 *9. 43 1267

215.000 23. 064 0.0*336 8.5370 153.056 8645.7 11464.0 106.305 30.18 *9.43 1250

220. 000 22. 785 0. 04389 8.2367 148.589 8858.4 11711.0 107.442 29.88 49. 22 1235

225.000 22.509 0 • 0*443 7.9485 144.359 9069.3 11957.0 108.547 29.73 *9.17 1220

230.000 22.235 0. 0*497 7.6719 140.354 9 279.5 12202.8 109.628 29.64 49.15 1204

235.000 21. 963 0.0*553 7.4066 136.563 9489.0 12448.6 110.685 29.60 *9. 17 1189

240.000 21.693 0.04610 7.1521 132.973 9698.1 12694.5 111.720 29.59 *9.21 1174

245.000 21. 425 0.04667 6.9079 129.575 9906.9 12940.7 112.736 29.61 49.27 1159

250.000 21.160 0.0*726 6.6739 126.359 10115.3 13187.2 113.732 29.66 49.3* 11*?

255.000 20.897 0. 0*785 6. 4494 123.317 10323.7 13434.2 114.710 29.74 *9.44 1130

260.000 20.637 0.04846 6.2343 120.442 10531.9 13681.6 115.671 29.84 *9.5* 1116

265.000 20. 379 0.04907 6.0280 117.725 10740.1 13929.6 116.615 29.95 49.65 1103

270.000 20.125 0. 0*969 5. 8303 115.160 10948.3 14178.2 117.545 30.09 *9.77 1090

275.000 19.873 0.05032 5.6*08 112.742 11156.5 14427.3 118.459 30.24 *9.89 1077

280.000 19.624 0 . 05 Q9o 5.4592 110.464 11364.9 14677.1 119.359 30.41 50.02 1064

285.000 19.379 0.05160 5.2851 108.319 11573.4 14927.6 120.246 30.58 50.15 1052

290.000 19. 136 0. 05226 5. 1183 106.304 11782.0 15178.7 121.119 30.77 50.29 10*1

295.000 18.897 0. 05292 4. 9583 104.413 11990.8 15430.4 121. 980 30. 97 50.42 1029

300.000 18.662 0.05359 4.8050 102.641 12199.8 15682.9 122.826 31.18 50.56 1019

310.000 18.200 0.05494 4.5173 99.432 12618.5 16189.9 124. 491 31.62 50.63 998

320.000 17.753 0.05633 4. 2528 96. 642 13038.1 16699.5 126.109 32. 09 51.10 979

330.000 17. 320 0.05774 4. 0097 94.232 13458.9 1721 1.7 127.685 32.59 5 1.35 962

340.000 16. 902 0. 05916 3.7860 92.169 13880.9 17726.6 129.222 33.10 51.61 94 o 350.000 16.499 0.06061 3.5802 90.419 14304.2 182*3.9 130.721 33.62 51.85 932

360.000 16.110 0. 06207 3.3907 88.952 14728.9 18763.6 132.185 34. 16 52.09 919

370 .000 15.736 0.06355 3.2161 87.738 15155.1 19285.6 133.616 34.71 52.32 908

380.000 15.377 0.06503 3.0550 86.751 15582.9 19810.0 135.014 35.26 52.55 899

390.000 15. 032 0.06653 2. 9063 85.966 16012.6 20336.

13(9. 382 35.82 52.78 889

400.000 14.701 0.06802 2.7688 85.361 16444.

20865.7 137.721 36. 39 53.01 880

420.000 14. 078 0. 07103 2.5239 84.614 17313.4 21930.4 140.319 37.52 53.47 867

440.000 13. 506 0.07404 2. 3133 84.371 18191.

23004.5 142.817 38.64 53.94 857 460.000 12.980 0.07704 2.1313 84.529 19080.6 24088.2 145. 225 39.76 54.43 9*9

480.000 12.496 0.08002 1.9731 85.005 19980.4 25181.9 147.553 40.86 54.94 844

500.000 12.050 0.08298 1.8350 85.736 20892.0 26286.0 149. 806 41. 94 55.47 841

203
METHANE ISOBAR AT P 8 700.0 BAR

T OEM VOL OP/DT DP/DD E H S CV CP M 0E6 K HOL/L L/HOL 3AR/K SAR-L/MQL J/MOL J/MOL J/MOL/K J/MOL/K J/MOL/K M/SEC

107.355 29.360 0.03406 19. 0100 311.804 3797.3 6181.5 70.928 37.27 51.70 1642

110.000 29.278 0.03416 18.6897 311.137 3907.6 6298.5 72.017 37.29 51.70 1640

115.000 28.989 0.03451 18.8311 305.543 4139.4 6554.8 74.313 37.01 51.56 1629

120.000 28.687 0.03486 17.3891 298.669 4371.1 6611.2 76.504 36.61 51.37 1616

125. 000 28.398 0.03521 16.7669 291.000 4601.9 7066.9 78.596 36.17 51.14 1602

130.000 2So 111 0.03557 16.1663 262.786 4631.7 7321.8 80.598 35.77 50.97 1565

135.000 27.626 0.03594 15.5875 274.277 5060.7 7576.4 62.520 35.46 50.91 1567

14*0. 009 27.542 0.03631 15.0305 265.651 5289.4 7830.9 84.372 35.25 50.95 1547

145 • 000 27.260 0. 03666 14.4946 257.037 5518.0 8085.9 66.161 35.10 51.05 1527

150.000 26.978 0.03707 13.9796 248.535 5746.7 8341.4 87.893 34.92 51. 12 1506

155.000 26.697 0.03746 13.4663 240.220 5975.0 8597.0 89.569 34.60 51.06 1486

160.066 26.417 0.03785 13.0079 232.145 6201.9 6851.7 91. 187 34.08 50.79 1469

165. 000 26.137 0. 03626 12.5497 224.349 6426.3 9104.5 92.742 33.33 50.29 1453

170.000 25.858 0.03667 12. 1090 216.658 6647.2 9354.4 94.234 32.47 49.66 1438

175.000 25.579 0.03910 11.6850 209.685 6665.0 9601.6 95.666 32.24 49.66 1419

180.000 25.300 0. 03953 11.2770 202.840 7082.6 9849.4 97.061 31.62 49.45 1402

105.000 25.023 0.03996 10.8846 196.322 7298.8 10096.3 98.414 31.48 49.31 138*

190.000 24.746 0.04041 10.5070 190.125 7513.8 103*2.6 99.726 31.20 49.21 1367

195.000 24.470 0.04087 10.1437 184.242 7 727.8 10588.4 101.005 30.96 49.1* 1350

209.000 24. 195 0. 04133 9.7944 178.662 7940.9 10834.0 102.249 30.75 49.10 1333

205.000 23.922 0. 04180 9.4584 173.373 6153.3 11079.5 1 0 3 . 46

1

30.56 49.07 1317

210.000 23.650 0.04228 9.1353 168.360 6364.9 11324.7 104.643 30.44 49. 05 1300

215.000 23.379 0. 0*277 6.8248 163.610 6575.9 11570.0 105.797 30. 32 49. 04 1284

22 0. 000 23. Ill 0. 04327 8.5262 159.106 6786.2 11815.1 106.924 30.02 40.84 1270

225.000 22. 844 0.04376 6.2394 154.641 8994.8 12059.1 106.021 29.87 48.77 1255

230.000 22.578 0.0*429 7.9637 150.797 9202.6 12302.9 109. 093 29.78 48.75 1241

235.000 22.315 0.04481 7.6969 146.962 9409.

6

12546.7 110. 141 29.73 40.76 1226

240. 000 22.055 0.04534 7 . 4446 143.326 9616.6 12790.6 111.168 29.72 48.80 1211

245.000 21.796 0.04586 7.2003 139.879 9623.1 13034.7 112.175 29.74 48.85 1197

250.000 21.540 0 . 04643 6.9657 136.610 10029.4 13279.1 113.163 29.79 48.93 1183

255.000 21.286 0.04696 6.7405 133.512 10235.5 13524.0 114.132 29.87 49. 02 1169

260.000 21.035 0.04754 6.5242 130.575 10441.6 13769.3 115. 085 29.96 49. 12 1155

265.000 20.767 0. 04811 6.3166 127.793 10647.7 14015.2 116.022 30.06 49.23 1142

270.000 20.541 0.04668 6.1172 125.159 10853.8 14261.7 116.943 30.22 49.35 1129

275.000 20.296 0.04927 5.9259 122.667 11060.1 14508.7 117.850 30.37 49.47 1116

200.000 20.056 0.04966 5.7422 120.310 11266.5 14756.4 118.742 30.53 49.61 1104

205.000 19. 821 0.05045 5.5658 118.064 11473.1 15004.8 119.622 30.71 49. 74 1092

290.000 19.586 0.05106 5.3965 115.963 11679.9 15253.8 120.486 30.90 49- 88 1080

295.000 19.355 0. 05167 5.2340 114.002 11887.0 15503.6 121.342 31.10 50.02 1069

300.000 19.127 0.05228 5.0780 112.137 12094.4 15754.1 122.184 31.31 50.17 1058

310.000 18.661 0. 05353 4.7643 106.733 12510.1 16257.2 123.833 31.76 50.46 1038

320.000 18.247 0.05480 4.5135 105.738 12927.1 16763.2 125.440 32.23 50. 75 1019

330.000 17.827 0.05609 4.2637 103.117 13345.6 17272.2 127.006 32.73 51.03 1001

340.000 17.421 0.05740 4.0332 100.639 13765.7 17783.9 128.534 33.25 51.32 985

350.000 17.027 0.05673 3.8204 98.873 14167.5 18296.5 130.025 33.78 51.60 970

3o0.000 16.646 0.06007 3.6238 97.191 14611.1 18815.9 131.483 34.32 51.87 957

370.000 16.262 0.06142 3.4420 95.767 15036.6 19335.9 132.906 34.87 52.14 945

360.000 15.929 0.06276 3.2739 94.573 15464.1 19658.7 134.302 35.43 52.41 934

390.000 15.569 0.06415 3.1161 93.589 15893.7 20384.0 135.666 36.00 52.67 924

400. 000 15.262 0.06552 2.9738 92.791 16325.6 20912.0 137.003 36.56 52.93 915

420.000 14.646 0. 06826 2.7155 91.678 17196.4 21975.8 139.598 37.70 53.45 900

440.000 14.076 0.07104 2.4923 91.101 18077.3 23050.1 142.097 38.04 53.98 888

460.000 13.55Q 0.07360 2.2986 90.950 18969.2 24135.1 14*. 508 39.96 54. 51 879

480. 000 13. 064 0. 07654 2. 1296 91.141 19872.7 25230.8 146.840 41.07 55.06 873

500.000 12.615 0.07927 1.9615 91.606 20786.5 26337.5 149.096 42.15 55.62 868

204
Table 15. The Joule - Thomson inversion locus

T»F T »R P,PSI IB/CUFT T*F T »

P.PSI IB/CUFT

>17®. 00 289.67 715 21.54 140.00 599.67 7286 15. 36

160.00 299.67 1120 21.30 150. 00 609.67 7358 15. 18

150.00 309.67 1503 21.07 160.00 649.67 7424 15. 00

140.00 319.67 1867 20.84 170.00 629.67 7483 14. 83

130.00 329.67 2213 20.61 180.00 639.67 7536 14.65

120.00 339.67 2542 20. 38 190. 00 649.67 7583 14. 47

110.00 349.67 2856 20.16 200.00 659.67 7623 14. 29

100.00 359.67 3155 19.94 210.00 669.67 7657 14. 11 -90.00 369.67 3440 19.73 220.00 679.67 7685 13.93

-00.00 379.67 3713 19.52 230.00 689.67 7707 13.75

-70.00 389.67 397 3 19.31 240.00 699.67 7723 13. 57

-60.00 399.67 4222 19.10 250.00 709.67 7734 13. 39

-50.00 409.67 4460 18.90 260.00 719.67 7739 13.21

-40.00 419. 67 4688 16.70 270.00 729.67 7738 13. 03

-30.00 429.67 4905 18.50 200.00 739.67 7731 12. 84

-20.00 439.67 5113 18.31 290.00 749.67 7718 12. 66

-10.00 449.67 5311 18.11 300.00 759.67 7699 12.47

0. oo 459.67 5560 17.92 310.00 769.67 7675 12. 29

10.00 469.67 5679 17.73 320.00 779.67 7644 12. 10

20.00 479.67 5851 17.55 330.00 789.67 7607 11. 91

30.00 489.67 6013 17.36 340.00 799.67 7563 11. 72

40.00 499.67 6168 17.17 350.00 809.67 7514 11.52

50.00 509.67 6314 16.99 360.00 819.67 745 8 11.33

60.00 519.67 6452 16.81 370.00 829.67 7398 11. 13

70.00 529.67 6582 16.62 380.00 839.67 7335 10. 93

60.00 539.67 6705 16.44 390.00 049.67 7271 10. 74

90.00 549.67 6820 16.26 400.00 859.67 7206 10.55

100.00 559.67 6927 16.08 410.00 869.67 7142 10. 36

110.00 569.67 70 27 15.90 420.80 879.67 7078 10. 18

120.08 579.67 7121 15.72 430.00 889.67 7015 10. 00

130.00 589.67 72®? 15.94 440. 00 899.67 6953 9. 03

205
Table 16. Thermophysical properties of the saturated liquid

For the following table we have used heats of vaporization to make the vaporliquid transition at temperatures T « T

&

= 174.516 K. For higher temperatures we have computed around the critical point as described in section 3.4 of the text with aid

from figure 1

.

Column headings have the following interpretations -- DP/DT s dP/dT, vapor pressure,

DDL/DT - dp^/dT, saturated liquid

Q, VAP £ Af*vap’keat of vaporization,

CV = Cv(p,T),

CS = Ca(T),

CP = C

p

(P , T).

206
Table 16. Thermophysical properties of the saturated liquid

T T P OEN V,GAS V. LIQ DP/DT DDL/DT Q, VAP

DEG F OEG R PS I L8/CUFT CUFT/LB CUFT/LB PSI/R LB/CUFT/R BTU/LB

-296. 41*6 163.224 1.703 28.190 63.6831 0.03547 0.1216 -0.04606 233.84

-290.000 169.670 2.648 27. 992 42.4544 0.03585 0.1739 -0.04654 231.78

- 265. 0 0 0 174.670 3.641 27.658 31.7071 0.03616 0.2246 -0.04698 230.11

-260.000 179.670 4.911 27.422 24. 1032 0.03647 0.2852 -0.04748 228.37

-275.000 164.670 6.511 27.183 18.6191 0.03679 0.3565 -0.04805 226.55

-270.000 169.670 6.495 26.941 14.5936 0.03712 0.4394 -0.04868 224.64

-265.000 194.670 10.925 26.696 11.5909 0.03746 0.5346 -0.04937 222.64

-260. 000 199.670 13.863 26.447 9. 3177 0 . 03781 0.6428 -0.05012 220.54

-255. 000 204.670 17.375 26.195 7.5731 0.03818 0.7646 -0.05094 218.35

-250.000 209.670 21.532 25. 938 6. 2174 0.03655 0.9006 -0.05182 216.05

-245.000 214.670 26.406 25.677 5.1514 0.03895 1.0513 -0.05276 213.65

-240. 000 219.670 32.070 25.410 4.3041 0.03935 1.2171 -0.05378 211.14

-235.000 224.670 36.603 25.139 3.6238 0.03978 1.3984 -0.05486 208.50

-230.000 229.670 46.080 24. 861 3. 0725 0.04022 1.5954 -0. 05603 205.74

-225.000 234.670 54.584 24.578 2.6217 0.04069 1.8086 -0.05727 202.85

-220. 000 239.670 64.194 24.289 2.2500 0.04117 2.0381 -0.05861 199.80

-215.000 244.670 74.993 23.992 1.9412 0.04168 2.2843 -0.06006 196 .59

-210. 000 249.670 67.065 23. 668 1.6828 0.04222 2.5473 -0.06162 193.20

-205.000 254.670 100.494 23. 375 1.4650 0.04278 2.8273 -0.06332 189.62

-200.000 259.670 115.366 23. 054 1.2803 0.04338 3.1246 -0.06518 185.83

- 195. 000 264.670 131.769 22.723 1.1226 0.04401 3.4395 -0.06723 181.82

-190. 000 269.670 149.791 22.382 0. 9873 0.04468 3.7722 -0.06951 1 77.57

-165.000 274.670 169.522 22. 028 0.8706 0.04540 4.1231 -0.07206 173.05

-180.000 279.670 191.053 21.660 0.7693 0.04617 4.4927 -0.07495 168.25

-175.000 264.670 214.480 21.278 0.6810 0.04700 4.8813 -0.07825 163.14

- 170. 000 289. 670 239.900 20.877 0.6037 0.04790 5.2897 -0.08208 157.69

-165.000 294.670 267.411 20.456 0.5356 0.04889 5.7185 -0.08657 151.87

-160.000 299.670 297.121 20.010 0.4754 0.04998 6.1689 -0.09192 145.62

-155.000 304.670 329.138 19.535 0.4218 0.05119 6.6419 -0. 09844 138.87

- 150. 000 309.670 363.580 19.023 0. 37 38 0.05257 7.1393 -0.10654 1 31 .52

-145.000 314.670 400.575 18.465 0.3306 0.05416 7.6631 -0.11692 123.43

-140.000 319.670 440.261 17.348 0.2912 0.05603 8.2165 -0. 13071 114.37

-135.000 324.670 462.797 17.149 0.2548 0. 05631 6.8040 -0.15007 104.00

-130.000 329.670 528. 369 16.331 0.2205 0.06123 9.4328 -0.17958 91.71

- 125. 000 334.670 577.215 15.317 0.1871 0.06529 10.1167 -0.23204 76.35

-120.000 339.670 629.664 13. 381 0.1520 0.07204 10.8928 -0.37388 54.80

-116.671 342.999 667.003 10. 015 0. 0998 0. 09985 11.6443 0.0 0

207
Table 16. Thermophysical properties of the saturated liquid (continued)

T P E H S CV CS CP h OEG F PS I BTU/LB 9TU/LB 8TU/LB/R BTU/LB/R BTU/LB/R BTU/LB/R FT/S

-296. 446 1. 703 93.10 93.11 1.01124 0.493 0.786 0. 786 5172

-290.000 2.648 97.94 97. 95 1. 04175 0.491 0.791 0. 791 5056

-285.000 3.641 101.76 101.79 1.06481 0.491 0.797 0. 797 4961

-280. 000 4.911 105.66 105.69 1.08740 0.492 0.804 0. 805 4863

-275. 000 6.511 109.61 109.66 1. 10957 0.493 0.811 0. 812 4764

- 27 0 . 0 0 0 8. 495 113.63 113.68 1. 13135 0.493 0.819 0. 820 4665

-265. 000 10.925 117.69 117. 76 1.15274 0.493 0.8 25 0. 827 4566

-260. 000 13.863 121.79 121.89 1.17375 0.492 0.832 0. 833 4469

-255.000 17.375 125.94 126.06 1.19439 0.490 0.837 0.840 437?

-250. 000 21.532 130.11 130.27 1. 21467 0.488 0.843 0.846 4276

-245.000 26.406 134.33 134.52 1.23460 0.485 0.848 0. 852 4180

-240.000 32.070 138.57 138. 80 1.25419 0.481 0.854 0. 858 4084

-235.000 38.603 142.84 143.12 1.27347 0.478 0.860 0. 865 3968

-230.000 46. 080 147.15 147.49 1. 29246 0.475 0.866 0.872 3890

-225.000 54.584 151.49 151.90 1.31118 0.473 0.873 0. 881 3791

-220.000 64.194 155.86 156.35 1.32967 0.471 0.881 0. 890 3690

-215.000 74.993 160.28 160.86 1.34796 0.469 0.890 0.901 3588

-210. 000 87. 065 164.75 165.43 1.36606 0.468 0.900 0.914 3483

-205.000 100.494 169.27 170.07 1.38403 0.467 0.912 0. 928 3377

-200.000 115. 366 173.85 174.77 1.40187 0.467 0.924 0. 943 3269

-195.000 131.769 178.49 179.56 1.41961 0.466 0.937 0. 960 3159

- 190. 000 149. 791 183.19 184.43 1.43728 0.466 0.951 0.979 3048

-185.000 169.522 187.96 189. 39 1.45490 0.465 0.967 1. 000 2936

-180.000 191.053 192.81 194. 44 1.47248 0.463 0.983 l. 023 2 822

-175.000 214.480 197.74 199.60 1.49005 0.461 1.000 1. 049 2707

-170.000 239.900 202.75 204.88 1.50764 0.457 1.020 1. 079 2591

-165.000 267.411 207.86 210.28 1.52527 0.453 1.042 1. 115 2472

- 160. 000 297. 121 213.07 215.82 1.54302 0.449 1.068 1. 159 2350

-155.000 329.138 218.42 221.54 1.56096 0.445 1.101 1. 215 2223

-150.000 363.580 223.94 227.48 1.57922 0.442 1.144 1. 289 2088

-145.000 400.575 "229.69 233.71 1.59795 0.449 1.208 1. 399 1935

- 140.000 440.261 235.77 240. 34 1.61757 0.452 1.286 1.548 1781

-135. 000 482. 797 242.26 247. 48 1.63833 0.457 1.397 1. 776 1617

-130.000 528. 369 249.37 255.36 1.66088 0.468 1.568 2. 167 1439

-125.000 577.215 257.48 264.45 1.68654 0.488 1.878 2. 997 1242

-120.000 629.684 267.78 276.18 1.71933 0.536 2.745 6. 085 1007

-116.671 667. 003 290.14 302. 47 1.79463 0

208
Table 17. Thermophysical properties along isobars

The following pages give physical and thermodynamic properties along selected

isobars, as computed by methods of section 3 of the text.

The first table is for the triple-point pressure, = 0.117 436 bar (1. 70326 psi).

The first line of each table refers to the freezing liquid on the P(T) melting line.

Each table at P < P contains a blank line for the transition from saturated liquid

c to vapor, as seen by the abrupt decrease of density.

Table headings for partial derivatives have the following interpretations-

DP/DT = 6P./3T,

DP/DD = 3p/6p.

The specific heat interpretations are-- CV s c (P, T), v CP = C (P, T).

P

These tables are extrapolated beyond the range of P-P-T data used for adjusting the

equation of state (T ~ 400 K, P~ 350 bar).

209
METHANE ISOBAR AT P = 1.703 26 PSI

T T DEN VOL OP/DT OP/DD E H S CV CP W DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 8TU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S

-296.646 163. 224 26.190 0.03547 166.994 3622.62 93.10 93.11 1.01124 0.493 0.786 5172

-296. 446 163.224 0.01570 63.683 0.01056 107.65 306.48 326.57 2.44386 0.373 0.500 816 -290.000 169.670 0.01510 66.245 0. 01014 112.06 308.91 329.81 2.46322 0.373 0.500 634 -280.000 179.670 0.01424 70.214 0. 00956 118. 88 312.66 334.83 2.49181 0.373 0.499 859 -270.000 189.670 0.01343 74.177 0.00905 125.67 316.44 339.84 2.51882 0.373 0.498 663 -260.000 199.670 0.01280 78.135 0.00858 132.45 320.20 344.85 2.54442 0.372 0.498 906

-250. 000 209. 670 0.01218 82.090 0.00317 139. 22 323.96 349.85 2.56 875 0.372 0.496 929 -240. 00Q 219.670 0.01162 86. 043 0. 00779 145. 98 327.71 354.85 2.59193 0.372 0.498 951 -230.000 229.670 0.01111 89.992 0.00745 152.73 331.47 359.85 2.61408 0.372 0.497 972

-220. @00 239.670 0.01065 93.940 0.00713 159.47 335.22 364.85 2.63527 0.372 0.497 993 -210. 000 249.670 0.01022 97.687 0.00684 166. 20 338.97 369.84 2.65560 0.372 0.497 1014

-200. 000 259. 670 0. 00982 101. 831 0. 00658 172.93 342.72 374.84 2.67512 0.372 0.497 1034

-190.000 269.670 0.00945 105.775 0.00633 179. 66 346.47 379.83 2.69390 0.372 0.497 1054

-160.000 279.670 0.00911 109.718 0.00610 186. 39 350.22 384.83 2.71201 0.373 0.497 1073

-170.000 289.670 o.ooaeo 113.659 0.00589 193. 11 353.97 369.82 2.72947 0.373 0.497 1093

- 160. 000 299.670 0. 00850 117.600 0.00569 199.82 357.72 394.81 2.74635 0.373 0.497 1111 -150.000 309.670 0.00823 121.541 0.00551 206.54 361.48 399.61 2.76266 0.373 0.498 1130

- 140. 000 319.670 0.00797 125.480 0.00534 213.25 365.23 404.81 2.77850 0.373 0.498 1148

-130.000 329.670 0. 00773 129.419 0.00517 219.97 368.99 409. 81 2.79364 0.374 0.498 1165

-120. 000 339.670 0.00750 133.358 0.00502 226.68 372.76 414.82 2.80674 0 . 374 0.499 1183

-110.000 349.670 0.00728 137.296 0.00488 233. 38 376.52 419.83 2.82322 0.375 0.499 1200 -100.000 359.670 0.00708 141.234 0.00474 240. 09 360.30 424.84 2.83730 0.376 0.500 1217

-90. 000 369.670 0.00689 145. 171 0.00461 246. 80 384. 08 429.86 2. 65102 0. 376 0.501 1233

-80.000 379.670 0.00671 149. 108 0.00449 253.50 387.86 434.89 2.86439 0.377 0.501 1250 -70.000 389.670 0.00653 153.045 0.00437 260. 21 391.66 439.93 2.67743 0.378 0.502 1266

-60.000 399.670 0.00637 156.982 0.00426 266. 91 395.47 444.98 2.89018 0.379 0.503 1261 -50.000 409.670 0. 00621 160. 918 0. 00416 273. 61 399. 28 450. 04 2.90263 0. 380 0.505 1297

-40. 000 419.670 0.00607 164. 854 0.00406 280.32 403. 11 455.11 2.91481 0. 362 0.506 1312

-30. 000 429.670 0.00592 168.790 0.00396 287.02 406.96 460.19 2.92675 0.363 0.507 1327

-20.000 439.670 0.00579 172.725 0.00387 293.72 410.62 465.29 2.93844 0.365 0.509 1342

-10. 000 449. 670 0. 00566 176.660 0. 00379 300. 42 414. 69 470.41 2.94990 0.387 0.511 1356 0.000 459.670 0.00554 180.596 0.00371 307. 12 418.59 475.55 2.96116 0.389 0.513 1370 10.000 469.670 0.00542 184.531 0.00363 313. 82 422.50 480.70 2.97221 0.391 0.515 1384

20.000 479. 670 0.00531 188.466 0.00355 320.52 426.43 465.86 2.98308 0.393 0.517 1398

30.000 489. 670 0. 00520 192.400 0. 00348 327.22 430.39 491.07 2.99377 0. 395 0.519 1411 40.000 499.670 0.00509 196.335 0.00341 333. 92 434.37 496.30 3. 00429 0.398 0.522 1425

50.000 509.670 0.00499 200.269 0.00334 340.61 438.38 501.54 3.01466 0.400 0.524 1438 60.000 519.670 0.00490 204.204 0. 00328 347. 31 442.41 506.82 3.02487 0.403 0.527 1451 70.000 529. 670 0.00480 208. 138 0.00321 354.01 446.47 512.12 3.03494 0.406 0.530 1463

80.000 539.670 0.00472 212.072 0.00316 360. 71 450.57 517.45 3.04489 0.409 0.533 1476

100. 000 559.670 0.00455 219.940 0.00304 374. 10 458.84 528.21 3. 06440 0.415 0.5 39 1500 120.000 579.670 0.00439 227.808 0.00294 387.49 467.25 539. 10 3. 06346 0.422 0.546 1524

140. 000 599. 670 0.00424 235.675 0.00284 400.88 475.80 550.13 3. 10212 0.430 0.554 1547

160.000 619.670 0. 00411 243.542 0. 00275 414. 28 484.51 561.32 3.12041 0.438 0.562 1569

160. 000 639.670 0.00398 251.409 0.00266 427.67 493.37 572.66 3.13838 0.446 0.570 1591

200. 000 659.670 0.00386 259.275 0.00258 441. 06 502. 40 564.17 3. 15605 0.454 0.578 1613

220.000 679.670 0. 00 374 267.141 0.00250 454.45 511.60 595.85 3. 17344 0.463 0.587 1634 240.000 699.670 0. 00364 275.007 0. 00243 467. 84 520.97 607.71 3. 19059 0.472 0.596 1654

280.000 739.670 0. 00344 290.739 0.00230 494.61 540.27 631.97 3.22423 0.490 0.614 1694

320. 000 779.670 0.00326 306. 469 0. 00218 521. 39 560. 32 656.98 3. 25707 0.509 0.633 173 3 360.000 819.670 0. 00 310 322.199 0.00208 548. 16 581.12 662.74 3.26923 0.529 0.652 1771 400.000 859.670 0.00296 337.928 0.00198 574.94 602.70 709.28 3.32077 0.548 0.672 1807

440.000 899. 670 0.80283 353.657 0.00189 601.71 625.04 736.58 3.35175 0.567 0.691 1843

21 0
METHAWE ISOBAR IT f » 5.0 PSI

T T DEN VOL DP/DT DP/OD E H S CV CP M OEG F OEG R LB/CUFT CUFT/L0 PSI/R PSICUFT/L8 0TU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S

296. <*35 163.235 20. 191 0.03547 166.936 3623. 06 93. 10 93.14 1.01 125 0.493 0.786 5172

290. 000 169.670 27.092 0.03585 159.537 3425.01 97,93 97.96 1.04173 0.491 0.791 5056

2B0. 000 179.670 27.422 0. 03647 148.494 3121.46 105.66 105.69 1.08740 0.492 0.805 4863

279.690 179. 960 27.407 0.03649 148.161 3112. 16 105.90 105.94 1.00079 0.492 0.305 4857

229.690 179.960 0.04210 23.709 0.02856 116.68 312.06 334.01 2.35702 0.375 0.506 854 270.000 189.670 0.03994 25. 040 0. 02698 123. 51 315.73 338.91 2. 38350 0.374 0.504 870

260.000 199.670 0.03707 26.407 0.02555 130.50 319.51 343.96 2.40936 0.374 0.503 902

250.000 209.670 0.03601 27.770 0.02427 137.45 323.28 348.99 2.43391 0.373 0.502 925

240.000 219.670 0.03433 29.130 0.02311 144.36 327.04 354.01 2.45726 0 . 373 0.501 947

230.000 229.670 0. 03200 30.487 0. 02207 151. 25 330.80 359.03 2.47955 0.373 0.500 969

220.000 239.670 0.03140 31.642 0.02111 158.11 334.56 364.04 2. 50086 0.373 0.500 991

210.000 249.670 0.03012 33.195 0.02024 164.95 338.31 369,05 2.52128 0.373 0.499 1012

200.000 259.670 0.02095 34.547 0.01944 171.78 342.06 374.05 2.54089 0.373 0.499 1032

190. 000 269.670 0.02706 35. 697 0. 01870 178. 59 345.82 379.05 2.55974 0.373 0.499 1052

ISO. 000 279.670 0.02665 37.246 0.01802 185. 39 349.56 384.05 2.57791 0.373 0.499 1072

170.000 209.670 0.02591 38.594 0.01739 192.10 353.31 389.05 2.59543 0.373 0 . 499 1091

160.000 299.670 0.02504 39.941 0.01680 198.96 357.06 394.05 2.61235 0.373 0.499 1110

150. 000 309.670 0.02422 41.208 0. 01625 205.73 360.82 399.04 2.62872 0.373 0.499 1128

140.000 319.670 0.02346 42.634 0.01573 212.49 364.57 404. 04 2.64458 0.374 0. *99 1147

130.000 329.670 0.02274 43.979 0.01525 219. 25 368. 33 409.04 2.65995 0.374 0.499 1164

120. 000 339.670 0.02206 45.324 0.01479 226.01 372.08 414.05 2.67488 0.375 0.500 1182

110. 000 349.670 0. 02143 46.668 0.01436 232.76 375.85 419.06 2.68938 0.375 0.500 1199

100.000 359.670 0. 02093 48.012 0.01396 239.50 379.62 424.07 2.70349 0 . 376 0.501 1216

-90.000 369.670 0.02026 49.355 0.01358 246.24 383. 39 429.09 2.71723 0 . 376 0.501 1233

-SO. 000 379.670 0.01972 50.690 0.01322 252. 98 387.18 434. 12 2.73062 0.377 0.502 1249

-70. 000 309.670 0.01922 52.041 0.01268 259.72 390.97 439. 15 2.74368 0 . 378 0.503 1265

-60. 000 399.670 0.01073 53. 304 0.01255 266.45 394.77 444.19 2.75644 0. 379 0.504 1201

-50.000 409.670 0. 01327 54.726 0.01224 273. 18 398.58 449.25 2.76891 0.381 0.505 1296

-40.000 419.670 0.01704 56.068 0.01195 279. 90 402.41 454.32 2.78110 0. 302 0.506 1311

-30.000 429.670 0.01742 57.410 0.01167 286.63 406.24 459.40 2.79305 0. 383 0.508 1326

-20.000 439.670 0.01702 50.752 0.01140 293. 35 410.10 464.49 2. 80475 0. 385 0.509 1341

-10.000 449.670 0.01664 60.093 0.01115 300. 07 413.97 469.61 2.81623 0.387 0.511 1356

0.000 459.670 0.01628 61.434 0.01090 306.79 417. 86 474.74 2.62749 0. 389 0.513 1370

10.000 469.670 0.01593 62.776 0.01067 313.50 421.77 479.69 2.83856 0. 391 0.515 1384

20.000 479.670 0.01560 64.117 0.01045 320.22 425.70 465.06 2.84943 0.393 0.517 1 398

30.000 489.670 0.01523 65.457 0.01023 326.93 429.65 490.25 2.86013 0.395 0.520 1411 40.000 499. 670 0. 01497 66.79® 0. 01003 333.65 433.62 495.47 2.87066 0.398 0.522 1424

50.000 509.670 0.01463 68.139 0.00983 340. 36 437.62 500.71 2.08103 0.400 0.525 1438

60.000 519.670 0.01439 69.479 0.00964 347.07 441.65 505.98 2.09125 0.403 0.527 1450

70.000 529.670 0.01412 70.820 0.00945 353.78 445.71 511.28 2.90133 0.406 0.530 146 3 SO. 000 539.670 0.01336 72.160 0. 00928 360. 49 449.80 516.61 2.91127 0.409 0.533 1476

100.000 559.670 0.01336 74,841 0.00395 373.90 450.06 527.35 2.93080 0.416 0.540 1500

120.000 579.670 0.01290 77.521 0.00864 387. 31 466. 46 538.23 2.94987 0.422 0.547 1524

140. 000 599.670 0.01247 30.201 0.00835 400.72 475.00 549.26 2.96853 0 .430 5.554 1547

160. 000 619.670 0.01207 82. 880 0.00608 414. 12 483.70 560.43 2.98684 0.438 0.562 1569

100.000 639.670 0.01169 85.560 0.00782 427.53 492.55 571.77 3.00481 0.446 0.570 1591

200.000 659.670 0.01133 88.239 0.00759 440.93 501.57 583.26 3.02248 0.454 0.578 161 3 220.000 679.670 0.01100 90.918 0.00736 454.33 510.76 594.93 3. 03969 0.463 0.587 1634

240. 000 699.670 0.0106$ 93.597 0.00715 467.73 520. 12 606.78 3.05704 0.472 0.596 1654

260. 000 739.670 0.01011 98.954 0.00676 494.52 539.40 631.02 3. 09068 0.490 0.614 1694

320.000 779.670 0.00959 104. 311 0.00642 521. 31 559.43 656.01 3. 12354 0.509 0.633 1733

360.000 019. 670 0.00912 109.667 0.00610 548. 09 580. 22 601.76 3.15570 0.529 0.653 1771 400.000 359.670 0.00069 115.023 0.00582 574.87 601.78 708.27 3.18725 0.548 0.672 1807

440. 000 099. 670 0.00031 120.379 9.00556 601.65 624.10 735.55 3.21823 0.567 0.691 1043

211
METHANE isobar AT ? = 10.0 PSI

T T DEN VOL DP/OT DP/DO E H S C V CP w OEG P OEG R LB/CUFT CUPT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

-296.420 163.250 28.191 0. 03547 166.979 3623. 73 93. 11 93.17 1. 01127 0. 493 0.786 5172

-290.000 169.670 27.694 0.03585 159.548 3426.22 97.92 97.99 1.04167 0.491 0.791 5057

-260.000 179.670 27.423 0. 0 3647 148.508 3122.77 105.65 105.72 1.08734 0.492 0.305 4863

-270.000 189.670 26.942 0.03712 138.073 2627.73 113.62 113.69 1.13133 0.493 0. 320 4665

-266.790 192. 660 26. 764 0. 03734 134. 642 2735. 26 116.23 116.30 1.14512 0.493 0.824 4601

-266. 790 192. 880 0.07956 12.569 0. 05433 122. 29 316. 28 339.56 2. 30317 0.377 0.513 878 -260. 000 199.670 0.07666 13.045 0.05223 1 27. 27 318.88 343.04 2.32088 0 . 376 0.511 895 -250.000 209.670 0.07278 13.741 0.04945 134.52 322.70 348. 14 2. 34579 0. 375 0.509 919

-240. 000 219. 670 0.06929 14.433 0.04698 141.69 326.50 353.22 2. 36944 0.375 0.507 942

-230.000 229.670 0.06613 15. 122 0.04476 148. 79 330.29 358.29 2.39197 0 . 374 0.505 965

-220.000 239.670 0.06326 15.809 0.04276 155. 65 334.07 363.34 2.41348 0.374 0.504 987

-210.000 249.670 0.06063 16.494 0.04094 162. 86 337.84 368.38 2.43406 0. 374 0.503 1006

-200.000 259.670 0.05822 17.177 0.03927 169.83 341.61 373.42 2. 45381 0.374 0.502 1029

-190.000 269.670 0. 05600 17.858 0.03775 176.78 345.37 378.44 2.47278 0. 374 0.502 1049

-180.000 279.670 0.05394 18.539 0. 03634 183.70 349.13 383.46 2.49105 0.373 0.501 1069

-170.000 269.670 0.05203 19. 218 0. 03503 190. 60 352.89 368.46 2.50866 0. 374 0.501 1066

-160.000 299.670 0.05026 19.897 0.03382 197.49 356.65 393.50 2.52566 0.374 0.501 1106

-150. 000 309.670 0.04860 20.574 0.03269 204. 35 360.41 398.51 2 . 54 2 1 0 0 . 374 0.501 1126

-140.000 319.670 0. 04706 21.251 0.03164 211.20 364. 17 403.52 2.55802 0.374 0.501 1145

-130.000 329. 670 0. 04561 21.927 0. 03066 216. 04 367.93 408.54 2.57344 0.374 0.501 1163

-120.000 339. 670 0. 04424 22.603 0.02973 224. 87 371.70 413.55 2.56842 0.375 0.501 1180

-110. 000 349.670 0.04296 23.278 0.02686 231.68 375.47 418.57 2.60296 0.375 0.501 1198

-100.000 359.670 0.04175 23.953 0.02604 238.49 379.24 423.59 2.61711 0.376 0.502 1215

-90. 000 369. 670 0. 04061 24.627 0. 02727 245. 29 363.02 428.62 2.63066 0.377 0.502 1231

-60.000 379. 670 0.03952 25.301 0.02653 252. 08 386.80 433.65 2.64430 0. 377 0.503 1246

-70.000 369.670 0.03850 25.975 0.02554 258. 87 390.60 438.70 2.65739 0 . 378 0.504 1264

-60. 000 399.670 0.03753 26.649 0.02516 265. 64 394.40 443.75 2.67017 0.379 0.505 1280

-50.000 409. 670 0. 03660 27.322 0. 02456 272.42 398.21 446.81 2.68267 0.381 0.506 1295

-40.000 419.670 0.03572 27.995 0. 02397 279. 19 402.04 453.88 2.69488 0.382 0.507 1311 -30.000 429.670 0.03463 28.667 0.02340 285.95 405.88 458.96 2.70685 0.383 0.509 1326

-20.000 439.670 0.03403 29. 340 0.02286 292.71 409.74 464. 06 2. 71657 0. 3 85 0.510 1340

-10.000 449. 670 0.03332 30.012 0.02235 299. 47 413.61 469.18 2.73006 0.387 0.512 1355

0.000 459.670 0.03259 30.664 0.02186 306.22 417. 50 474.31 2. 74134 0 . 389 0.514 1369

10.000 469.670 0.03189 31.356 0. 02139 312. 97 421.40 479.47 2.75242 0.391 0.516 1383

20.000 479.670 0.03122 32.026 0.02094 319. 71 425. 33 484.64 2. 76331 0.393 0.518 1397

30.000 469.670 0. 03058 32.699 0. 02050 326. 45 429.29 489.84 2. 77402 0.395 0.520 1411 40.000 499.670 0.02997 33.371 0.02009 333. 19 433. 26 495.06 2.78456 0.398 0.523 1424

50.000 509.670 0.02938 34.042 0.01969 339.93 437. 26 500.30 2. 79494 0.400 0.525 1437

60.000 519.670 0.02881 34.713 0.01931 346. 67 441. 29 505.57 2. 60517 0.403 0.528 1450 70.000 529.670 0. 02826 35.385 0.01694 353.40 445.36 510.87 2. 81526 0.406 0.531 1463

60.000 539. 670 0.02773 36.056 0.01659 360. 13 449.43 516.20 2. 82521 0.409 0.534 1475

100.000 559.670 0.02674 37. 398 0.01792 373.59 457.70 526.95 2.84475 0.416 0.540 1500

120.000 579.670 0.02581 36.739 0. 01730 387. 03 466. 09 537.83 2. 86364 0.423 0.547 1524

140. 000 599.670 0.02495 40.080 0.01672 400.48 474.63 548.85 2.88251 0.430 0.554 1547

160.000 619.670 0.0241* 41.421 0.01617 413. 92 483.32 560.03 2.90063 0.438 0.562 1569

180. 000 639.670 0.02339 42.762 0.01567 427. 35 492.17 571.36 2.91881 0.446 0.570 1591

200. 000 659. 670 0. 02267 44.103 0. 01519 440. 78 501.19 562.86 2.93649 0.454 0.579 1613

220. 000 679.670 0. 0220 1 45.443 0.01474 454. 20 510.38 594.53 2.95390 0.463 0.587 1634

240.000 699.670 0.02138 46.783 0.01432 467.62 519.74 606.37 2.97107 0.472 0.596 1654

280. 000 739. 670 0.02022 49.463 0.01354 494. 45 539.02 630.61 3.00472 0.490 0.615 1694

320.000 779. 670 0. 01918 52. 142 0. 01284 521.28 559.04 655.59 3.03756 0.509 0.634 1733

360. 000 819. 670 0. 01824 54.821 0. 01221 546.09 579.82 681. 34 3. 06976 0.529 0.653 1771 400.000 859.670 0.01739 57.500 0. 01164 574.90 601.37 707.85 3.10131 0.548 0.672 1807

440.000 699. 670 0.01662 60.176 0.01112 601.69 623.69 735.1? 3. 13230 0.567 0.691 1843

212
METHANE ISOBAR AT P * 15.0 PSI

T T DEN VOL DP/DT DP/DD E H S CV CP M OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

-296. «»0 <• 163. 266 26.192 0.03547 166.970 3624. 40 93. 11 93.21 1. 01 130 0.493 0.786 5172

-290.000 169.670 27.695 0. 03585 159.560 3427. 42 97.91 98. 01 1. 04162 0.491 0.791 5057

-260.000 179.670 27.425 0.03646 148.523 3124. 08 105.64 105.74 1. 08728 0.492 0.805 4864

-270.000 169.670 26.944 0.03711 136.091 2829. 13 113.61 113.71 1. 13127 0.493 0.820 4666

-260.000 199.670 26.448 0.03761 128.201 2545.13 121.79 121.89 1.17373 0.492 0.833 4469

-256. 264 201. 366 26. 361 0. 03793 126.554 2497. 60 123.21 123.31 1.18088 0.491 0.836 4435

-256. 284 201.386 0. 11537 8.667 0. 07938 125. 21 318.97 343. 05 2.27230 0 . 379 0.520 892 -250.000 209.670 0. 11037 9.060 0.07566 131. 48 322. 16 347.34 2. 29318 0. 378 0.516 913

-240.000 219.670 0.10492 9.531 0.07167 138.92 326.02 352.49 2. 31716 0.376 0.513 937

-230. 000 229.670 0. 10 0 G 2 9.998 0.06814 146. 26 329.84 357.61 2.33995 0.376 0.511 960

-220. 000 239.670 0.09556 10.462 0. 06498 153.51 333.65 362.71 2.36167 0.375 0.509 982 -210.000 249.670 0.09154 10.925 0.06212 160.70 337.45 367.80 2. 38243 0.375 0.507 1004

-200.000 259.670 0.06763 11. 385 0.05952 167. 83 341. 24 372.86 2.40233 0. 374 0. 506 1025

-190.000 269.670 0.06443 11.844 0.05715 174.92 345.02 377.92 2.42143 0 . 374 0.505 1046

-180.000 279.670 0.08129 12.302 0.05496 181.97 348. 80 382.97 2.43980 0.374 0.504 1066

-170.000 289.670 0.07638 12.759 0.05295 168. 98 352.58 388.01 2.45751 0.374 0.504 1086

-160.000 299.670 0.07568 13.214 0. 05109 195. 96 356.35 393.05 2. 47459 0. 374 0.503 1105

-150.000 309.670 0.07316 13.669 0.04935 202.92 360.12 398.09 2.49110 0.374 0.503 1124

-140.000 319.670 0.07081 14. 123 0.04774 209, 86 363.89 403.12 2.50708 0.374 0.503 1 142 -130.000 329. 670 0.06860 14.576 0.04623 216.77 367.66 408.15 2.52256 0.375 0.503 1161

-120.000 339. 670 0. 06654 15. 029 0. 04482 223.67 371.43 413. 18 2.53758 0. 375 0.503 1178

-110.000 349.670 0.06459 15.462 0.04349 230.55 375. 21 418.21 2.55217 0 . 376 0.503 1196

-100.000 359.670 0.06276 15.934 0.04224 237.42 378.98 423.24 2.56636 0.376 0.503 1213

-90.000 369.670 0. 06103 16.385 0.04106 244. 28 382.77 428.26 2.58016 0.377 0.504 1230

-60. 000 379. 670 0.05940 16. 636 0.03995 251. 13 386. 56 433.32 2.59362 0. 378 0.504 1246

-70.000 389.670 0.05765 17.287 0. 03890 257.96 390.36 438.37 2.60674 0 . 379 0.505 1263

-60.000 399.670 0.05636 17.737 0.03790 264.79 394.17 443.43 2.61955 0 .380 0.506 1279

-50.000 409. 670 0.05498 18.188 0.03695 271.61 397.96 448.50 2.63206 0.381 0.507 129*. -40. 000 419.670 0.05365 16.636 0. 03605 278.42 401.81 453.56 2.64430 0.382 0.508 1310

-30.000 429.670 0.05239 19.087 0. 03520 285.22 405.66 458.67 2.65629 0 .384 0.510 1325

-20.000 439.670 0.05119 19.537 0.03438 292. 02 409.51 463.78 2.66803 0. 385 0.511 1340

-10.000 449.670 0.05003 19.986 0.03360 298. 81 413.39 468.90 2.67954 0. 3 87 0.513 1354

0. 000 459. 670 0.04694 20.435 0.03286 305.59 417.28 474. 04 2.69083 0.389 0.514 1369

10.000 469.670 0.04768 20.684 0.03215 312. 37 421. 19 479. 20 2.70192 0.391 0.516 1383

20.000 479.670 0.04666 21.333 0.03147 319. 15 425.12 484.36 2.71283 0 .393 0.519 1397

30.000 469.670 0.04591 21.782 0.03062 325.92 429.08 489.58 2.72355 0.395 0.521 1410

40. 000 499.670 0.04496 22.230 0.03019 332.69 433.05 494.80 2.73410 0 . 398 0.523 1424

50.000 509.670 0.04409 22.679 0.02959 339.45 437.06 500.05 2.74449 0.401 0.526 1437

60.000 519.670 0.04324 23.127 0.02901 346.21 441.09 505.32 2.75473 0.403 0.528 1450

70.000 529.670 0.04242 23.575 0.02846 352. 97 445. 14 510.62 2. 76483 0. 406 0.531 146 3 80.000 539.670 0.04163 24.023 0.02793 359.72 449.23 515.96 2. 77480 0.409 0.534 1475

100.000 559.670 0.04013 24.919 0.02692 373. 22 457.50 526.71 2.79435 0.416 0.541 1500

120. 000 579.670 0.03874 25.615 0.02598 386.71 465. 90 537.60 2.81345 0.423 0.547 1523

140.000 599.670 0.03744 26.710 0. 02511 400. 19 474.44 548.63 2.83214 0.430 0.555 1547

160. 000 619.670 0.03623 27.605 0.02429 413.66 483.13 559.80 2.85047 0.438 0.562 1569

160.000 639.670 0.03509 28.499 0. 02352 427. 12 491.98 571.14 2.86846 0.446 0.571 1591

200. 000 659. 670 0. 03402 29. 394 0. 02280 440.58 501.00 582.64 2.88615 0.454 0.579 1613

220.000 679.670 0.03302 30. 286 0. 02213 454. 03 510.18 594. 31 2. 90357 0.463 0.588 1634

240.000 699.670 0.03207 31.182 0.02149 467.47 519.55 606. 16 2. 92074 0.472 0.597 1654

260.000 739.670 0. 03033 32.970 0.02032 494. 35 538.82 630.40 2.95441 0.491 0.615 1664

320. 000 779.670 0.02677 34.756 0.01928 521.21 558.85 655.39 2.98728 0.509 0.634 1733

360. 000 619.670 0.02736 36.545 0. 01833 548. 05 579.63 681.14 3.01946 0.529 0.653 1771 400.000 859.670 0.02609 38,331 0.01747 574.89 601. 18 707.65 3.05103 0.548 0.672 1808

440.000 899.670 0.02493 40.117 0.01669 601.71 623.50 734.93 3. 08202 0.567 0.691 1843

213
METHANE ISOBAR AT P = 20.0 PSI

T T DEN VOL OP/OT OP/OD E H S CV CP M DEG F OEG R LB/CUFT CUFT/L8 PSI/R PSICUFT/LB 8YU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S

296.383 163.282 28.193 0.03547 166.960 3625. 07 93.11 93.24 1.01132 0.493 0.786 5173

290.000 169.670 27.897 0.03585 159.971 3428.63 97.90 98.04 1.04156 0.491 0.791 5056

280.000 179.670 27.427 0.03646 148.537 3125.39 105.63 105.76 1.08722 0.492 0. 805 4865

270.000 189.670 26.945 0.03711 138.106 2830.54 113.60 113.74 1.13120 0.494 0.820 4666

260.000 199.670 26.450 0.03781 128.221 2546.61 121.77 121.91 1.17367 0.492 0.833 4470

251.750 207. 920 26.028 0.03842 120.426 2321.65 128.65 128.79 1.20762 0.489 0.844 4310

251.750 207. 920 0. 15028 6.654 0.10412 126. 98 320.97 345.61 2. 25064 0.380 0.526 902

250.000 209.670 0.14886 6.718 0.19302 128.36 321.65 346.53 2.25504 0.380 0.525 906

240.000 219.670 0.14128 7.073 0.09729 136. 10 325.55 351.76 2.27938 0.378 0.520 931 230.000 229.670 0.13451 7.434 0.09227 143.69 329.41 356.94 2.30245 0.377 0.516 955

220. 000 239.670 0.12840 7.780 0. 08781 151. 15 333.25 362.10 2.32440 0.376 0.514 978

210.000 249.670 0. 12286 8.139 0.08381 158.52 337.08 367.22 2.34535 0.376 0.511 1000

200.000 259.670 0.11780 8.489 0.08020 165. 82 340. 69 372.33 2.36540 0.375 0.510 1021

190. 000 269.670 0.11317 8.836 0.07692 173.04 344.70 377.42 2. 38464 0.375 0.508 1042

180. 000 279.670 0. 10890 9.183 0.07391 180.22 348.49 382.50 2.40312 0.375 0.507 1063

170.000 289.670 0.10495 9.528 0.07115 187. 34 352.28 387.57 2.42092 0. 375 0.506 1083

160.000 299.670 0.10129 9.872 0.06859 194. 43 356. 07 392.63 2.43809 0.375 0.505 1103

150.000 309.670 0.09789 10.216 0.06623 201.48 359.85 397.68 2.45468 0. 375 0.505 1122

140. 000 319. 670 0. 09471 10.559 0.06403 208.50 363.63 402.73 2.47072 0.375 0.505 1140

130.000 329.670 0.09174 10.901 0.06198 215.49 367.41 407.76 2.48626 0.375 0.504 1159

120. 000 339. 670 0.08895 11.242 0.06006 222.47 371.19 412.83 2.50133 0.375 0.504 1177 110.000 349.670 0.08633 11.583 0.05826 229.42 374. 98 417.87 2.51596 0. 376 0.504 1194

100. 000 359.670 0.08387 11.924 0.05657 236.35 378.76 422.92 2.53019 0.376 0.505 1212

-90.000 369.670 0.08154 12.264 0.05497 243.26 382.55 427.97 2.54403 0.377 0.505 1229

•80.000 379.670 0.07934 12.603 0.05347 250. 16 386.35 433.03 2.55752 0.378 0.506 1245

•70.000 389.670 0.07726 12.943 0.05205 257. 05 390. 15 438.09 2.57067 0. 379 0.506 1262

•60.000 399.670 0.07529 13.282 0.05070 263.92 393.97 443.16 2.56350 0.380 0.507 1278

-50.000 409.670 0.07342 13.620 0.04943 270.78 397.79 448.23 2.59604 0.381 0.506 1293

-40.000 419.670 0.07164 13.959 0.04821 277.63 401.62 453.32 2.60631 0.382 0.509 1309

-30.000 429.670 0. 06994 14.297 0.04706 284. 48 405.47 456.42 2.62031 0.364 0.510 1324

-20.000 439.670 0.06833 14.635 0.04596 291.31 409.33 463.53 2.63207 0.385 0.512 1339

-10.000 449.670 0.06679 14.973 0.04492 298. 14 413.21 468.66 2.64360 0.367 0.513 1354

0.000 459.670 0.06531 15. 311 0.04392 304.96 417. 11 473.81 2.65491 0.389 0.515 1368

10. 000 469.670 0.06391 15.648 0.04296 311.77 421. 02 478.97 2.66602 0.391 0.517 1362

20.000 479.670 0.06256 15.986 0.04205 318.57 424.95 484.16 2.67693 0.393 0.519 1396

30.000 489.670 0.06126 16.323 0.04117 325.37 428.91 489.36 2.66767 0.396 0.521 1410

40.000 499.670 0.06002 16.660 0. 04033 332. 17 432.89 494.59 2.69823 0.396 0.524 1423

50.000 509.670 0.05883 16.997 0.03953 338.96 436.90 499.84 2.70664 0.401 0.526 1436

60. 000 519.670 0. 05769 17.334 0.03875 345.74 440.93 505.12 2.71689 0.403 0.529 1449

70.000 529.670 0.05659 17.670 0.03801 352.52 444.99 510.43 2.72900 0.406 0.532 1462

80.000 539.670 0.05553 18.007 0.03729 359. 30 449.07 515.76 2.73897 0.409 0.535 1475

100.000 559.670 0.05353 18.680 0.03594 372. 84 457.34 526.53 2.75854 0.416 0.541 1499

120. 000 579.670 0. 05167 19.352 0.03468 386.36 465.75 537.42 2.77765 0.423 0.548 1523

140.000 599.670 0.04994 20.025 0.03351 399.88 474.29 548.45 2.79636 0.430 0.555 1546

160. 000 619.670 0.04832 20.697 0.03242 413. 38 482.99 559.64 2.81469 0.438 0.563 1569

180.000 639.670 0.04680 21.368 0.03140 426. 87 491.84 570.98 2. 83270 0.446 0.571 1591

200.000 659.670 0.04537 22.040 0. 03043 440. 36 500.66 562.48 2.85040 0.454 0.579 1613

220.000 679.670 0.04403 22.711 0.02953 453. 83 510.05 594.16 2.66783 0.463 0.588 1634

240.000 699.670 0.04277 23.383 0.02868 467.30 519.41 606.01 2.88501 0.472 0.597 1654

280.000 739.670 0.04045 24.724 0. 02712 494.22 536.69 630.26 2.91869 0.491 0.615 1694

320.000 779.670 0.03836 26.066 0.02572 521.12 558.72 655.25 2.95157 0.509 0.634 1733

360.000 819.670 0.03649 27.407 0.02445 548. 00 579.50 661.00 2.98376 0.529 0.653 1771 400.000 859.670 0.03479 28.747 0.02331 574.86 601.05 707.52 3.01533 0.548 0.672 1808

440.000 899. 670 0.03324 30.087 0.02227 601.71 623. 37 734.80 3. 04633 0.567 0.691 1644

214
HETHANE ISOBAR AT P = 25.0 PSI

T T DEN VOL OP/OT OP/ DO F H S CV CP w DEO F OEG R LB/CUFT CUFT/L8 PSI/R PSICUFT/LB BTU/LP 9TU/LB btu/lb/r BTU/LB/R eTU/L 9/R FT/S

296. 372 163. 298 28.193 0.03597 166.951 3625. 74 93.11 93. 28 1. 01134 0.493 0. 786 5173

290. 000 169.670 27.898 0.03589 159.583 3429.83 97.89 98.06 1.04151 0 .491 0.791 5058

280.000 179.670 27.928 0.03696 198.552 3126.70 105.62 105.79 1.08716 0.492 0.604 4865

270.000 189.670 26.997 0.03711 138.125 2831.94 113.59 113.76 1.13114 0 .494 0.819 4667

260.000 1 99. 670 26.952 0.03780 128. 291 2548. 09 121. 76 121. 94 1.17360 0.492 0.633 4471

250.000 209.670 25.939 0.03855 118.835 2276.63 130.10 130.28 1.21462 o. 4 es 0.646 4277

296 . 365 213. 305 25. 798 0.03839 115.521 2181.19 133. 17 1 33. 35 1.22919 0.486 0.050 4206

296. 365 213. 305 0. 18957 5.918 0.12870 128. 11 322.56 347.64 2.23393 0. 382 0.532 909

290. 000 219. 670 0. 17891 5.605 0. 12390 133.22 3 25 . 06. 351.01 2.24951 0. 381 0.528 925

? 3 0 . 0 0 0 229.670 0. 16963 5.895 0. 11718 141. 07 328.97 356.26 2.27289 0 . 379 0.523 950

220. 000 239.670 0.16175 6.183 0.11129 148,76 332.85 361.47 2.29508 0 . 378 0.519 973

210.000 299.670 0. 15962 6.967 0.10605 156.33 336.71 366.65 2. 31623 0. 377 0.516 996

200. 000 259. 670 0. 19819 5.750 0.10139 163. 79 340.55 371.80 2. 33645 0. 376 0.514 1018

190.000 269.670 0.19222 7.031 0.09708 171. 16 344.37 376.92 2. 35582 0. 376 0.512 1039

190.000 279.670 0.13678 7.311 0. 09319 178. 46 348.19 382.03 2. 37442 0 . 375 0.510 1 060 170.000 289.670 0.13176 7.590 0.08963 185. 70 352. 0C 387.13 ?. 39232 0. 375 0.309 1080

160. 000 299.670 0.12711 7.867 0.08636 192. 89 355.80 392.22 2.40958 0 . 375 0.508 1100

150.000 309.670 0.12279 8. 199 0.08333 200. 04 359.59 397.29 2.42623 0 . 375 0.507 1119

190.000 319.670 0.11877 8.920 0.08051 207.15 363.38 402.36. 2.44234 0 . 375 0.507 1138

130.000 329. 670 0.11501 8.695 0.07790 214. 22 367.18 407.43 2. 45794 0. 375 0.506 1157

120.000 339.670 0.11199 8.970 0.07595 221.26 370.97 412.49 2.47306 0.376 0.506 1175

110. 000 399.670 0.10818 9.299 0. 07316 228. 28 374.76 417.55 2.48774 0 . 376 0. ->06 1193

100.000 359.670 0. 10507 9. 517 0. 07102 235. 27 370.55 422.61 2.50201 0 . 377 0.506 1210

-90.000 369.670 0. 10219 9.791 0. 06900 242. 24 382.35 427.68 2.51589 0. 377 0.506 1227

-80.000 379.670 0.09937 10.063 0. 06709 249.20 386. 16 432.74 2.52941 0 . 378 0.507 1244 -70.000 389.670 0.09675 10.336 0.06529 256.13 389.97 437.81 2.54259 0 . 379 0.507 1260 -60.000 399. 670 0. 09927 10.608 0.06359 263. 05 393.78 942. 89 2.55545 0.380 0.508 1276

-50. 000 909. 670 0.09191 10. 880 0. 06198 269. 96 397.61 447.98 2.56802 0.381 0.509 1292

-90.000 919.670 0.08967 11.152 0. 06095 276. 85 401.45 453. oe 2.58030 0 . 382 0.510 1308

-30.000 929.670 0. 08759 11.923 0.05899 283.73 405. 3C 458.18 2. 59233 0.384 0.511 1323

-20. 000 939. 670 0.08551 1 1 .699 0.05760 290.60 409.17 463.30 2.60411 0. 3 06 0.513 1338

-10. 000 999. 670 0. 08358 11.965 0. 05628 297.46 413.05 468.44 2.61565 0 . 387 0.514 1353

0.000 959. 670 0.08173 12.236 0.05502 304. 32 416.95 473.59 2.62668 0.389 0.516 1367

10.000 969.670 0.07996 12.507 0.05382 311. 16 420.87 478. 76 2.63810 0. 391 0.518 1381 20.000 979.670 0.07827 12.777 0. 05267 317.99 424.80 483.95 2. 64903 0. 393 0.520 1395

30.000 989. 670 0.07669 13.097 0.05157 324. 82 428.76 489. 16 2.65978 0. 396 0.522 1409

90.000 999.670 0.07509 13.317 0.05051 331.64 932.75 494. 4 0 2.67036 0 . 398 0.324 1423

50.000 509.670 0.07360 13.588 0.09950 338. 46 436.75 499.66 2.68077 0.401 3.527 1436

60. 000 519.670 0.07216 13.857 0.09852 345. 26 440.79 504. 94 2.69103 0.403 0.529 1449

70.000 529. 670 0.07078 19.127 0.09759 352. 07 444.85 510.25 2.70115 0.406 0.532 1462

80.000 539.670 0.06996 19.397 0.09669 358. 86 448.94 515.59 2.71114 0.409 0.5 ?5 1474

too . 000 559.670 0.06695 19.936 0.09999 372. 45 457. 22 526.36 2.7307? 0.416 3.541 1499

120.000 579.670 0. 06962 15.975 0. 04391 386. 01 465.62 537.26 2. 74985 0.423 0. 548 1523

190.000 599.670 0.06295 16.019 0.09199 399. 56 474. 17 548.30 2.76857 0.430 0.555 1546

160. 000 619. 670 0.06092 16.552 0.04057 413.09 482.87 559.49 2.78692 0. 4 38 0.56 3 1569

180. 000 639. 670 0.05851 17.090 0. 03928 426.62 491.7? 570.84 2.80493 0.446 0.571 1591

200.000 659. 670 0.05673 17.628 0.03808 440. 13 500.74 582.35 2. 82264 0.454 0.580 1613

220.000 679.670 0.05505 18.165 0.03695 453.63 509.94 594.03 2.84008 0.463 0.588 1634

290. 000 699.670 0.05397 18.702 0.03588 467. 12 519.30 605.89 2. 85726 0.47? 0.597 1654

280. 000 739. 670 0.05056 19.777 0. 03392 494.08 538.59 630.14 2.09096 0.491 0.615 1694

320. 000 779. 670 0. 09796 20.851 0.03216 521. 02 558.61 655. 14 2.92366 0. 510 0.634 1733

360. 000 819.670 0. 09561 21.929 0.03058 547.93 579.40 680,89 2.95606 0.529 0.653 1771 900.000 859.670 0. 09398 22.997 0.02915 574. 82 600.96 707.42 2.98764 0.548 0.672 1808

990. 000 899. 670 0.09155 29.070 0.02785 601.70 623.27 734.70 3.01864 0.567 0.691 1844

215
MET MfiME ISO® SR A? P b 36.® PSI

T T OEM WGL OP/0T DP/00 E H S ev CP M DEG F DEG R LB/CUFT CUFT / L ® PSI/R PSEGUFT/LB 8TU/LB 8 TU/L 8 0 TU/LB/R BTU/ LB/R 0TU/LB/R FT/S

-296. 356 163. 319 26=159 0.03557 166.992 3626=41 93.12 93,31 1=01136 0.493 0 . 70 S 5173

-29®. 000 169.670 27.900 9.03 S ®5 159.599 3931.03 97=8© 90.08 1=04149 0.891 0.791 5059

-200. 000 179.670 27.93® 0= 63 S 66 140=566 3128.01 105.61 105.81 1.08711 0.992 0.804 4866

-220.000 109.67® 26.959 0=03711 138=142 2833.39 113.57 113=78 1,13100 0.894 0.819 4668

-260.000 199.670 26=959 0=03700 128.262 2599.58 121=75 121.96 1.17353 0.492 0.833 4471

-250.000 20®. 670 21.592 0=03855 116=850 2278= 19 130. 09 130=3® 1=21459 6=888 0= 845 4278

-261.796 217.926 25.509 0.03921 111=400 2063=97 137=0® 137.3® 1.24740 0.983 0 = 856 4118

-261.799 217.926 0=21692 5 = 570 G . 15324 120= 82 323=87 349.31 2.22032 0.383 0.538 915

-290. 000 219.670 0=21637 9.622 0= 15159 130 o 2? 324.57 350=24 2.22460 0.3 83 0.536 919

-230. 000 229.670 0= 20591 9.066 0.19296 130.91 328.53 355.57 2.29831 0 = 301 0.530 944

-220.000 239.670 0.19563 5 = 112 0.13596 196.39 332=44 360.84 2.27077 0,379 0.525 969

-210.000 299.670 0= 16669 5.352 0. 12685 154.11 336.33 366.0? 2.29213 0.378 0.521 992

-200. 000 259.670 0= 17606 5.591 0.12295 161.74 340.2® 371.26 2.31252 0.377 0.518 1014

-190.000 265.670 0.17160 5.628 0.11764 169.26 344.05 376.92 2.33204 0. 377 0.515 1036

-160. 000 279.670 0= 16659 6. 063 0.11202 176,70 397.09 381=57 2.35076 0.376 0.513 1057

-170.000 289.670 0.15600 6.297 0.10042 189. 66 351.71 38§ o 69 2.36876 0.376 0.512 1077

-160.00® 299=670 0.15319 6.530 0=10938 191.36 355=53 391,80 2=30619 0. 376 0.510 1098

-150. 000 305.670 0.19786 6.762 0.10065 198.60 359=34 396=90 2.80209 0.376 0.509 1117

-190.000 319.670 0. 19299 6.995 0.09720 205.79 363= 14 401.99 2.41902 0.376 0.509 1136

-130.000 329=67® 0.13892 7.225 0.09900 212.95 366.94 907.08 2.43467 0.376 0.508 1155

-120.000 33®. 67® 0.13515 7.555 0.09101 220= 06 370.75 412=16 2.44985 0. 376 0.508 1173

-110.000 399=670 0= 13015 7.635 0.08821 227.15 374,55 417.23 2.46457 0.376 0.507 1191

-100.000 355.670 0=12637 7.913 0.08559 234.20 370.35 422.31 2.97880 0.377 0.507 1209

-90.000 369.670 0. 12282 0.152 0.08313 241.23 382= 16 427.38 2.49280 0.378 0.508 1226

-80.000 379.670 0.11997 8.370 9=08082 248. 24 305=97 432.96 2.50635 0. 378 0.508 1243

-70.000 309.670 0.11631 8.590 0.07863 255.22 389.78 437.55 2.51956 0.379 0.506 1259

“60.000 399.670 0.11331 8.826 0.07656 262.19 393.61 442.64 2.53245 0.380 0.509 1275

-50.000 909.670 0. 11696 9.053 0.07461 269.14 397.44 447=73 2.54504 0.381 0.510 1291

-90. 000 919.670 0. 10776 9.230 0=07275 276. 07 401.29 452.84 2.55735 6.363 0.511 1307

-30.000 929.670 0.10519 9.507 0.07099 282.99 905.14 457.95 2.56940 0.364 0.512 1322

-20.000 939.670 0. 10279 9.733 0.06931 289,90 909.01 463.08 2.50120 0.386 0.513 1337

-10.000 999.670 0. 10090 9.960 0.06771 296,79 412=90 468.23 2.59276 0.387 0.515 1352

0.000 959.673 0 o 09317 10. 186 0. 06618 303=68 916.00 473.39 2.60411 0.369 0.517 1367

10. 000 969.670 0.09609 10.912 0.06973 310.55 420.72 470.56 2.61524 0.391 0.518 1381

20.000 979. 670 0.09900 10.630 0. Q 6339 317.41 424.66 983.76 2.62619 0.393 0.520 1395

30.000 989.670 0=09205 10.869 0.06200 324.2? 428.63 4 08.98 2.63695 0.396 0.523 1409

90. 000 999. 670 0.09013 11= 039 0.06073 331.12 432.61 494.22 2.64754 0.398 0.525 1422

50.000 509.670 0.08333 11.315 0.05950 337.96 436.62 499.40 2.65796 0.401 0.527 1435

60.000 519.670 0.03669 11.590 0.05833 344.79 440.66 504.77 2.66824 0.404 0.530 1446

70.000 529.670 0.08500 11.765 0.05720 351.61 444.72 510.00 2=67036 0.406 0 = 533 1461

00. 000 539. 67® 0.03390 11.990 0.05612 350.43 448.32 515.43 2.68836 0.409 0.536 1474

100.000 559.670 0.08033 12.950 0.05407 372.06 457.10 526.21 2.70796 0.416 0.542 1499

120.000 579.670 0=07750 12.090 0.05216 385.66 465.51 537.11 2.72711 0.423 0.549 1523

190.000 599.670 0.07597 13.339 0.05039 399. 24 474. @6 546.16 2.74584 0.430 0.556 1546

160. 000 619.670 0.07252 13.78® 0=04879 412.81 482.76 559.36 2.76420 0.438 0.563 1569

100.000 639.670 0=07029 14.237 0.04719 426.36 491.62 570.71 2.78222 0.446 0.571 1591

200.000 659.670 0.06009 19.686 0.04574 439.90 500.69 582.23 2.79994 0.455 0.580 1612

220.000 579.670 0=06608 15. 134 0. 04437 453=42 909.89 593.91 2.01739 0.463 0.568 1634

290.000 699.670 0.06517 15.502 0=04309 966.94 919.21 605.77 2.83458 0.472 0.597 1654

260. 000 739.670 0.06969 16,478 0.04073 493.94 530.49 630.03 2.06829 0.491 0.616 1694

320. 000 779=670 0.05756 17.374 0=03862 520.91 553.92 695.09 2.90120 0.510 0.634 1733

360.000 819.670 0.05979 18.269 0=03672 547= ®6 979.32 680.80 2.93341 0.529 0.653 1771

909. 00® 859=670 0.05218 19.163 0.03500 574.70 690.37 707=33 2.96499 0.548 0.673 1808

990.000 099.670 0.09936 20.050 0=03343 601.68 623.19 734.62 2.99601 0.567 0.691 1844

216
HE THANE ISOBAR AT P * 40.0 PSI

T T OEM VOL OP/DT DP/OO F H S CV CP H OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 0TU/LB 8TU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

296. 324 163.366 28.195 0.03567 166.926 3627.76 93.12 93.39 1.01 160 0.493 0.786 5173

290.000 169.670 27.903 0.03586 159.616 3633. 63 97. 87 98.13 1.06136 0 . 491 0, 791 5060

200.000 179.670 27.633 0.03665 168.596 3130.63 105. 58 105.65 1. 08699 0.692 0.304 4867

270. 000 189.670 26.952 0.03710 138.177 2836. 16 113.55 113.83 1.13095 0.694 0.819 4669

260.000 199.670 26.658 0.03780 128.302 2552. 56 121.72 122.00 1.17360 0.492 0.833 4473

250.000 209.670 25.966 0.03856 118.906 2281.31 130.06 130.36 1.21661 0 .488 0.945 4279

260.000 219.670 25.616 0.03935 109.919 2023. 12 138.56 138.83 1.25607 0. 482 0. 858 40 86 236.016 225.656 25.086 0.0 3987 106.713 1876.80 163.69 163.98 1.27726 0.478 0.866 396®

236.016 225.656 0.28526 3.506 0.20263 129. 63 325.97 351.96 2.19886 0.386 0.549 923

230.000 229.670 0.27912 3.583 0.19735 132.91 327.60 356.16 2.20850 0.385 0.545 934

220. 000 239.670 0.26516 3.772 0. 18605 161. 37 331.61 359.56 2.23156 0.382 0.537 959

210.000 269.670 0.25269 3.95 7 0.17628 169.58 335.57 366.88 2.25336 0.381 0.531 983

200.000 259.670 0.26150 6.161 0. 16768 157.58 339.50 370.17 2.27612 0.379 0.526 1007

190.000 269.670 0.23135 6.322 0.16003 165.63 363.60 375.61 2.29396 0.378 0.523 1029

100.000 279.670 0.22210 6.502 0. 15315 173.16 367.28 380.62 2.31292 0 . 378 0.520 1051 170.000 289.670 0. 21363 6.681 0.16691 180. 75 351.16 385.81 2.33116 0.377 0.517 1072

160.000 299.670 0. 20582 6.859 0.16122 188.27 356.99 390.98 2.36867 0.377 0.516 1092 150.000 309.670 0.19860 5.035 0.13600 195.71 358.83 396.12 2.36556 0.377 0.514 1112 160.000 319.670 0.19190 5.211 0.13119 203. 09 362.66 601.26 2.38188 0.377 0.513 1132

130.000 329.670 0.18566 5. 386 0. 12676 210.60 366. 69 606. 38 2.39766 0.377 0.512 1151

120.000 339.670 0.17986 5.561 0.12260 217.67 370.31 611.69 2.61296 0.377 0.511 1170 110.000 369.670 0.17638 5.736 0.11875 226. 89 376. 13 616.60 2.62776 0.377 0.511 1188

100.000 359. 670 0.16927 5.908 0.11516 232. 07 377.95 621.71 2.66215 0.378 0.510 1206

-90.000 369. 670 0. 16665 6. 081 0. 11176 239.21 381.77 626.81 2.65615 0.378 0.510 1223

-00.000 379.670 0. 15991 6.253 0.10859 266. 33 385.60 631.92 2.66977 0.379 0.510 1240

-70.000 389.670 0. 15563 6.626 0.10560 253.61 369.63 637.02 2.68306 0. 380 0.511 1257

-60.000 399.670 0.15157 6.597 0.10277 260.67 393.26 662.13 2.69599 0.381 0.511 127 3 -50. 000 609. 670 0. 16773 6.769 0. 10010 267.51 397.11 667.25 2.50863 0.382 0.512 1289

-60. 000 619.670 0.16608 6.960 0.09758 276.53 600.96 652.37 2.52098 0.383 0.513 1305

-30.000 629.670 0.16062 7.112 0.09518 281. 52 606.83 657.51 2.53307 0. 384 0.514 1320 -20.000 639.670 0. 13732 7.282 0.09290 288. 50 608.71 *62.65 2. 56691 0. 386 0.515 1 336

-10. 000 669.670 0. 13617 7.653 0. 09073 295.67 612.61 667.81 2.55651 0.388 0.517 1351 0.000 659.670 0.13117 7.626 0.08866 302. 61 616.52 672.98 2.56789 0.390 0.518 1365

10.000 669.670 0.12831 7.796 0.08669 309. 35 620.65 678. 17 2.57906 0.392 0.520 1300

20.000 679.670 0. 12557 7.966 0. 08681 316. 27 626.60 683. 38 2.59003 0. 394 0. 522 1394

30.000 689.670 0. 12296 8.136 0.08301 323. 18 628.36 688.61 2.60081 0. 396 0.524 1407

60.000 699.670 0. 12063 8.306 0.08128 330.08 632.36 693.86 2.61163 0 . 398 0.526 1421 50.000 509.670 0. 11801 8.676 0.07963 336. 97 636.37 699.16 2.62188 0.401 0.529 1434

60.000 519.670 0.11570 8.663 0. 07806 363. 65 660.62 506.66 2.63217 0. 404 0.531 1448

70.000 529.670 0. 11367 8.813 0.07652 350.72 666.69 509.76 2.66232 0.407 0.534 1461 60.000 539.670 0.11133 8.982 0. 07506 357. 58 668.59 515.12 2.65233 0.410 0.537 1473

100.000 559. 670 0. 10729 9. 321 0.07230 371. 28 656.87 525.91 2.67197 0.416 0.543 1498

120.000 579.670 0. 10353 9.659 0. 06976 386. 96 665.29 536.86 2.69116 0.423 0.549 1522 160.000 599.670 0.10003 9.997 0.06735 398.61 673.85 567.90 2.70990 0.430 0.557 1546

160.000 619.670 0.09677 10. 336 0. 06513 612. 23 682.56 559.11 2.72 828 0 . 438 0.564 1568

160. 000 639. 670 0.09371 10.672 0.06305 625. 86 691.63 570.67 2.76633 0.446 0.572 1591

200. 000 659. 670 0. 09066 11.009 0. 06110 639. 66 500.66 582.00 2.76607 0.455 0.580 1612

220.000 679.670 0.08816 11.366 0.05927 653. 01 509.66 593.70 2.78153 0.463 0.589 1633

260.000 699.670 0.08560 11.682 0.05755 666.57 519.06 605.57 2.79876 0.472 0.598 1654

260.000 739.670 0.08096 12.355 0.05639 693.66 538.33 629.85 2.83268 0.491 0.616 1694

320. 000 779.670 0. 07676 13. 028 0. 05156 520.70 558.37 656.67 2.86561 0.510 0.635 1733

360. 000 819.670 0.07299 13.700 0.06901 567.71 579. 17 680.66 2.89766 0.529 0.654 1771 600.000 859.670 0.06958 16. 371 0.06671 576.68 600.73 707.18 2.92926 0.568 0.673 1808

660.000 899.670 0.06663 15.063 0.06661 601.63 623. 06 736.68 2.96027 0.567 0.692 1844

217
NETHfiWE ISOBAR AT P = 50,0 PSI

T T DEN VOL DP/DT DP/DD E H S CV CP w DEG F OEG R L8/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

-296. 292 163. 378 28.197 0.03547 166.906 3629. 08 93.13 93.46 1.01145 0.493 0.786 5174

-290.000 169.670 27.906 0. 03584 159.639 3435. 63 97. 85 98. 18 1. 04123 0.491 0.791 5061

-200.000 179.670 27.436 0.03645 148.623 3133. 24 105.56 105.90 1.08687 0.493 0.804 4668

-270. 000 189.670 26.956 0.03710 13e. 211 2830. 94 113.53 113.87 1.13083 0.494 0.819 4671

-260.000 199.670 26.462 0.03779 128.342 2555.50 121.70 122.04 1. 17327 0.492 0.833 4475

-250. 000 209.670 25.950 0. 03353 118.950 2284. 42 130.03 130.39 1.21426 0.488 0.845 4261

-240.000 219.670 25.419 0.03934 109.972 2026. 37 138.51 138.87 1.25391 0.482 0.857 4086

-230.000 229.670 24.864 0. 04022 101.345 1781. 32 147.13 147.50 1.29239 0.475 0.872 3891

-227.617 232. 053 24.727 0.04044 99.335 1724.78 149.21 149.58 1.30141 0.474 0. 876 3843

-227. 617 232.053 0. 35130 2.847 0.25200 129. 34 327.60 353.96 2.18216 0 . 389 0.56 0 929

-220.000 239.670 0.33719 2.966 0.24000 136. 21 330.73 358.19 2.20009 0 . 386 0.551 949

-210.000 249.670 0.32061 3.119 0.22638 144. 91 334.77 363.65 2.22243 0.383 0.542 975

-200.000 259.670 0.30503 3.270 0.21459 153. 32 338.77 369.04 2. 24360 0. 382 0. 536 999

-190.000 269.670 0.29253 3.418 0.20422 161.52 342. 73 374.38 2.26376 0.380 0.531 1022

-180. 000 279.670 0.28047 3.565 0.19499 169.53 346.65 379.66 2.28301 0.379 0.527 1045

-170.000 269.679 0.26947 3.711 0. 18669 177. 40 350.56 384.92 2.30146 0.378 0.524 1066

-160.000 299.670 0.25938 3.655 0.17918 185. 16 354.44 390.14 2.31919 0. 378 0.521 1087

-150.000 309.670 0.25003 3.999 0.17232 192.80 358.31 395.34 2.33625 0.378 0.519 1108

-140.000 319.670 0.24147 4. 141 0.16603 200.36 362. 17 400.52 2.35271 0 . 377 0.517 1128

-130. 000 329.670 0.23348 4.203 0.16023 207.85 366.02 405.68 2.36861 0.377 0.516 1147

-120. 000 339.670 0.22603 4. 424 0.15486 215. 27 369. 67 410.83 2.38401 0.377 0.515 1166

-110.000 349.670 0.21908 4.565 0.14987 222.63 373.71 415.97 2.39893 0.378 0.514 1185

-100.000 359.670 0.21256 4.705 0.14522 229. 94 377.55 421.11 2.41341 0.378 0.513 1203

-90. 000 369.670 0.20643 4.044 0.14086 237. 20 381.39 426.24 2.42748 0.379 0.513 1220

-80.000 379. 670 0.20067 4.903 0. 13679 244.43 385.23 431.37 2.44117 0.379 0.513 1238

-70.000 389.670 0. 19523 5.122 0.13295 251.62 389. 07 436.50 2.45450 0.380 0.513 1254

-60.000 399.670 0.19009 5.261 0. 12934 258.77 392.93 441.63 2.46751 0.381 0.513 1271 -50.000 409.670 0.18523 5.399 0.12593 265. 90 396.78 446.77 2.48020 0.382 0.514 1287

-40. 000 419. 670 0. 18061 5.537 0.12270 272.99 400.65 451.91 2.49261 0.383 0.515 1303

-30. 000 429.670 0. 17623 5.674 0.11964 280.07 404.53 457. 06 2.50474 0.385 0.516 1319

-20.000 439.670 0.17206 5.012 0. 11674 287. 12 408.42 462.23 2.51661 0. 386 0.517 1334

-10.000 449.670 0. 16809 5.949 0.11398 294. 15 412. 32 467.40 2.52825 0. 388 0.516 1349

0. 000 459. 670 0.16431 6.006 0.11135 301.17 416.24 472.59 2.53966 0.390 0.520 1364

10.000 469.670 0. 16069 6.223 0.10885 308. 16 420.18 477.79 2.55086 0.392 0.521 1378

20.000 479.670 0.15724 6.360 0.10646 315. 14 424. 13 403.02 2.56186 0.394 0.523 1392

30.000 409.670 0. 15393 6.496 0. 10418 322. 11 428. 11 488.26 2.57267 0. 396 0.525 1406

40.000 499.670 0. 15077 6.633 0.10199 329. 06 432.11 493.52 2.58331 0.399 0.527 1420

50.000 509.670 0. 14773 6.769 0.09990 336. 00 436. 13 498.61 2.59378 0.401 0.530 1434

60.000 519.670 0.14482 6.905 0,09789 342.92 440.18 504.12 2.60410 0.404 0.532 1447

70.000 529.670 0.14202 7.041 0. 09597 349. 84 444. 26 509.45 2.61427 0.407 0. 535 1460

00.000 539.670 0.13933 7.177 0.09412 356. 74 448.36 514.81 2.62430 0.410 0.538 1473

100.000 559.670 0.13425 7.449 0. 09063 370.52 456.66 525.63 2.64397 0.416 0.544 1497

120. 000 579.670 0. 12953 7.720 0.08740 384.27 465.09 536.57 2.66317 0.423 0.550 1522

140.000 599. 670 0. 12514 7. 991 0. 08440 397.99 473. 66 547.65 2.68196 0.430 0.557 1545

16 0 . 0 0 0 619.670 0. 12104 6.262 0. 08159 411.68 462. 36 558.87 2.70037 0.438 0.565 1568

160. 000 639.670 0. 11720 8.532 0.07898 425. 34 491.25 570.25 2.71843 0.446 0.573 1590

200.000 659. 670 0. 11361 8.802 0.07652 438.98 500.29 561.79 2.73619 0.455 0.581 1612

220. 000 679. 670 0. 11022 9. 072 0. 07422 452. 61 509. 50 593.49 2.75367 0.463 0.590 1633

240.000 699.670 0.10704 9.342 0.07205 466. 21 516.88 605.37 2.77090 0.472 0.598 1654

200. 000 739.670 0.10120 9. 881 0.06808 493. 38 538.18 629.67 2.80466 0 . 491 0.617 1694

320.000 779.670 0.09597 10.420 0.06453 520.49 558.23 654.71 2.83762 0.510 0.635 1733

360. 000 019. 670 0.09125 10. 958 0. 06133 547.56 579.04 680.50 2.86987 0.529 0.554 1771 400.000 059.670 0.08698 11.496 0.05844 574.59 600.61 707.05 2.90148 0.540 0.673 1806

440.000 099.670 0.08310 12.034 0.05581 601.58 622.94 734.36 2.93253 0.567 0.692 1844

21 8

-*1
METHANE isobar at p 60.0 PSI

T T DEN VOL OP/DT DP/DD E H S CV CP w DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LP 9TU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S

-296. 260 163. 410 28.198 0. 0 3546 166.887 3630. 41 93.13 93.53 1.01149 0 . 494 0.786 5174

-290.000 169.670 27.908 0. 0 3583 159.662 3438. 23 97.83 98.23 1.04112 0.491 0.791 5062

-200.000 179.670 27.439 0. 0 3644 148.652 3135. 85 105.54 105.95 1. 06676 0.493 0.004 4869

-270.000 189.670 26.959 0.03709 138.245 2841. 73 113.50 113.92 1.13071 0.4 94 0.319 4672

-260.000 199.670 26.466 0.03778 128. 382 2558.46 121.67 122.09 1. 17 314 0.49? 0.933 4476

-250.000 209. 670 25.955 0.03853 118.996 2287.53 130.00 130.43 1.21412 0.408 0. 845 4283

-240.000 219.670 25.424 0. 0 3933 110. 024 2029. 63 138.47 138.91 1.25376 0.482 0.957 4090

-230.000 229.670 24.869 0.04021 101.405 1784.72 147.09 147.54 1.29222 0.475 0.972 3894

-222. 109 237.561 24.412 0.04096 94.812 1600.25 154.01 154.47 1.32190 0.471 0.986 3733

-222. 109 237.561 0.41697 2.398 0. 30214 128. 80 328.92 355.57 2. 16843 0. 391 0.570 93 3 -220. 000 239. 670 0. 41209 2.427 0.29782 130.01 329.81 356.77 2. 17345 0.390 0.567 939

-210.000 249.670 0. 39079 2.559 0.27947 140.07 333. 95 362.30 2. 19639 0. 387 0.555 966

-200. 000 259.670 0.37200 2.688 0.26389 148.93 338.02 367.88 2.2180? 0.384 0.547 991

-190. 000 269.670 0.35522 2.815 0.25037 157.51 342. 04 373.31 2. 23854 0. 362 0.540 1015

-180. 000 279.670 0.34010 2.940 0.23847 165. 85 346.02 378.68 2.25809 0 . 381 0.534 1038

-170.000 289.670 0. 32638 3.064 0.22786 174.00 349,96 384.00 2.27679 0 . 380 0.530 1061

-160.000 299.670 0.31385 3.186 0.21831 182.00 353.89 389.29 2.29472 0.379 0.527 1082

-150.000 309.670 0.30234 3.307 0. 20965 189. 86 357. 79 394.54 2. 31196 0. 379 0.524 1 1 P 3 -140. 000 319.670 0. 29173 3.428 0.20175 197.62 361.68 399.77 2.32857 0 . 378 0.522 1124

- 130.000 329.670 0.28189 3.547 0.19449 205. 28 365.56 404.97 2.34461 0. 378 0.520 1143

- 120. 000 339. 670 0.27275 3.666 0. 18780 212. 86 369.43 410.16 2. 36011 0.378 0.518 1163

-110.000 349.670 0.2642? 3.785 0. 18160 220. 36 373. 29 415.34 2.37514 0. 378 0.517 1181

-100.000 359.670 0.25625 3.902 0. 17583 227. 80 377. 15 420.51 2.38971 0.379 0.516 1200

-90. 000 369.670 0.24877 4.020 0.17045 235.19 381.01 425.67 2.40386 0 . 379 0.516 1218

-80.000 379.670 0.24174 4.137 0.1654? 242.53 384.86 430.82 2.41762 0.380 0.515 1235

-70.000 389.670 0. 23512 4. 253 0. 16070 249. 82 388.72 435.98 2.43102 0.300 0.515 1252

-60.000 399.670 0. 22886 4. 369 0.15626 257. 07 392.59 441.13 2. 44408 0. 381 0.516 1269

-50.000 409.670 0.22295 4.485 0. 15207 264. 29 396.46 446.29 2.45683 0. 382 0.516 1285

-40.000 419.670 0. 21735 4.601 0.14812 271.47 400.34 451.45 2.46928 0.384 0.517 1301

-30. 000 429. 670 0. 21203 4.716 0. 14438 278. 62 404.2? 456.62 2.48146 0.385 0.517 1317

-20.000 439.670 0.20697 4.832 0.14083 285. 75 40e. 12 461.80 2.49337 0. 387 0.518 1333

-10.000 449.670 0.20217 4.946 0.13746 292.85 412.04 467.00 2.50504 0.388 0.520 1348

0.000 459.670 0.19758 5.061 0.13426 299.93 415.97 472.20 2.51649 0.390 0.521 1 363

10. 000 469. 670 0. 19321 5. 176 0.13121 306.99 419.91 477.42 2.52772 0 . 392 0.523 1377

20.000 479.670 0. 1890 3 5.290 0.12830 314. 02 423.88 482.65 2.53875 0 . 394 0.524 1391

30.000 489.670 0. 18503 5.404 0.12552 321.04 427. 86 487.91 2.54959 0 . 396 0.526 1405

40. 000 499.670 0.18121 5.519 0.12286 328.05 431. 87 493.18 2.56025 0. 399 0.529 1419

50.000 509. 670 0.17754 5.633 0. 12032 335.03 435.90 498.48 2.57075 0.401 0.531 1433

60.000 519.670 0.17402 5.746 0.11788 342. 01 439.95 503.80 2.58108 0.404 0.5 33 1446

70.000 529.670 0.17064 5.660 0.11554 348.97 444.04 509.15 2. 59127 0.407 0.536 1459

80.000 539.670 0.16740 5.974 0.11330 355. 91 448. 15 514.52 2.60132 0.410 0.539 1472

100.000 559.670 0. 16127 6.201 0.10908 369.78 456.46 525.35 2.62103 0.4 16 0.545 1497

120.000 579.670 0. 15558 6.426 0.10516 383.59 464.89 536.31 2.64026 0.423 0.551 1521 140.000 599.670 0.15029 6.654 0.10152 397. 38 473.47 547.40 2.65907 0.431 0.558 1545

160.000 619.670 0. 14535 6.880 0. 09813 411.13 482. 20 558.64 2.67751 0. 438 0.566 1568

180. 000 639.670 0. 14073 7.106 0. 09497 424. 85 491.08 570.03 2.69559 0.446 0.573 1590

200.000 659.670 0.13640 7.332 0.09200 438. 54 500.12 581.58 2.71337 0.455 0.582 1612

220. 000 679. 670 0.13233 7.557 0.08922 452. 22 509.34 593.30 2.73087 0.464 0.590 1633

240.000 699.670 0. 12850 7. 782 0. 08660 465. 87 518.73 605.19 2.74811 0.473 0.599 1654

280.000 739.670 0.12147 8.232 0.08181 493.11 538. 04 629.51 2.78190 0.491 0.617 1694

320.000 779.670 0.11518 6.682 0.07753 520.29 558.10 654.56 2.81488 0.510 0.636 1733

360.000 819.670 0. 1095? 9.131 0.07368 547. 42 578.92 680.36 2.84715 0.529 0.655 1771

400. 000 859. 670 0.10439 9.579 0. 07019 574. 50 600.50 706.93 2.87878 0.548 0.67% 1808

440.000 899.670 0.09972 10.028 0.06703 601.54 622.04 734.25 2.90984 0.567 0.692 1844

21 9
METHAWE ISOBAR ATP* 70.0 PS I

T T OEM VOL OP/OT DP/OO e H S CV CP w OEC F DEO R LB/CUFT CUFT/L9 PSI/R PSXCUFT/LB BTU/LB BTU/LB 8TU/LB/R BTU/LB/R BTU/LB/R FT/S

296.229 163.441 20.200 0.03546 166.669 3631.74 93. 14 93.60 1.01153 0.494 0.705 5174

290.000 169.670 27.911 0.03563 159.684 3440.63 97.81 96.27 1.04101 0.492 0.790 5063

200.000 179.670 27.443 0.03644 146.660 3136.46 105.52 105.99 1.08664 0.493 0.604 4871

270.000 169.670 26.963 0.03709 138.280 2644.53 113.48 113.96 1.13056 0.494 0.819 4674

260. 000 199.670 26.469 0.03776 126.422 2561.42 121.64 122.13 1.17300 0.493 0.632 4478

250.000 209.670 25.959 0.03652 119.042 2290.63 129.97 130.47 1.21396 0.408 0.645 4285

240.000 219.670 25.429 0.03933 110.077 2032.68 136.44 138.95 1.25360 0.482 0.857 4092

230.000 229.670 24.875 0.04020 101.464 1788.12 147.05 147.57 1.29205 0.476 0.871 3 896

220. 000 239. 670 24.292 0.04117 93.145 1555. 75 155.84 156.37 1.32956 0.471 0.890 3692

217.241 242.429 24.126 0. 0*145 90.893 1493.69 158.30 156.83 1.33978 0.470 0.896 3634

217. 241 242.429 0.48245 2.073 0.35299 127.94 330.01 356.66 2.15671 0.393 0.581 936

210.000 249.670 0.46349 2.156 0. 33596 135.04 333. 08 361.05 2.17364 0.390 0.570 956

200.000 259.670 0.44018 2.272 0.31564 144.41 337.24 366.68 2.19579 0. 367 0.558 983

190.000 269.670 0.41955 2.384 0.29665 153. 39 341.32 372.22 2.21671 0. 384 0.549 1008

190.000 279.670 0.40109 2.493 0.26369 162.08 345.36 377.66 2.23658 0.383 0.543 1032

170.000 269.670 0.36443 2.601 0.27046 170.53 349. 36 363.07 2.25554 0. 381 0.537 1055

160.000 299.670 0.36929 2.706 0.25668 178.79 353.32 366.42 2.27369 0.380 0.533 1077

isp. 000 309.670 0.35543 2.613 0.24805 186. 88 357.26 393.73 2.29112 0. 380 0.529 1098

140.000 319.670 0.34269 2.916 0.23636 194.84 361.16 399.01 2.30789 0.379 0.526 1119

130.000 329.670 0.33092 3.022 0. 22956 202.68 365.09 404.26 2. 32407 0.379 0.524 1139

120.000 339.670 0.32000 3.125 0.22144 210.42 368.96 409.49 2.33969 0.379 0.522 1159

110.000 349.670 0.30964 3.227 0.21395 218.08 372.67 414.70 2.35402 0.379 0.521 1178

100.000 359.670 0.30035 3. 329 0.20700 225.66 376.75 419.90 2.36946 0.379 0.519 1197

-90. 000 369.670 0.29147 3. 431 0.20054 233. 17 380.62 425.09 2.36372 0.380 0.519 1215

-80. 000 379.670 0.26313 3.532 0.19450 240.62 364.49 430.20 2.39755 0.360 0.518 1233

-70.000 369.670 0.27529 3.633 0.16065 248.02 386.37 435.46 2.41102 0.381 0.518 1250

-60.000 399. 670 0.26769 3.733 0.18355 255. 37 392.25 440.63 2.42414 0.382 0.518 1267

-50. 000 409.670 0. 26090 3.633 0.17655 262.68 396.13 445.61 2.43694 0.363 0.518 1283

-40.000 419.670 0.25429 3.933 0.17364 269.95 400.02 451.00 2.44944 0. 3 84 0.519 1300

-30.000 429.670 0.24601 4.032 0.16939 277.18 403.92 456.19 2.46166 0.385 0.519 1315

-20.000 439.670 0.24205 4.131 0. 16516 284. 38 407.03 461.36 2.47362 0.387 0.520 1331

-10.000 449.670 0.23639 4.230 0.16118 291.55 411.76 466.59 2.46533 0.368 0.521 1346

0.000 459.670 0.23099 4.329 0. 15738 298.70 415.69 471.61 2.49661 0.390 0.523 1361

10.000 469.670 0.22564 4.426 0.15376 305.82 419.65 477.04 2.50607 0.392 0.524 1376

20. 000 479.670 0.22093 4.526 0.15031 312.91 423.62 462.29 2.51913 0.394 0.526 1390

30.000 499.670 0.21623 4.625 0.14703 319.99 427.61 487.56 2.52999 0.397 0.528 1404

40.000 499.670 0.21174 4.723 0.14389 327.04 431.63 492.65 2.54068 0.399 0.530 1418

50. 000 509.670 0.20743 4.621 0.14088 334.06 435.66 496.15 2.55120 0.402 0.532 1432

60. 000 519.670 0. 20330 4. 919 0. 13801 341.10 439.73 503.49 2.56156 0.404 0.534 1445

70.000 529.670 0. 19933 5.017 0.13525 346. 11 443.61 500.64 2.57177 0.407 0.537 1458

80.000 539.670 0. 19552 5.114 0.13260 355.10 447.93 514.22 2.58103 0.410 0.540 1471 100.000 559.670 0.16634 5.310 0.12762 369.04 456.25 525.06 2.60158 0.417 0.546 1496

120. 000 579.670 0. 16167 5.504 0.12301 362.93 464.70 536.05 2.62084 0.423 0.552 1521

140.000 599.670 0.17547 5.699 0.11673 396.78 473.29 547.16 2.63966 0.431 0.559 1544

160.000 619.670 0.16969 5.693 0.11474 410.59 462.02 558.41 2.65613 0.430 0.566 1567

160.000 639.670 0.16426 6.067 0.11102 424.37 490.91 569.81 2.67624 0.447 0.574 1590

200. 000 659. 670 0.15921 6.261 0.10754 438. 11 499.96 561.36 2.69404 0.455 0.582 1612

220.000 679.670 0.15445 6.475 0.10427 451.63 509.10 593.11 2.71156 0.464 0.591 1633

240.000 699.670 0.14997 6.666 0.10120 465.53 516.56 605.01 2.72881 0.473 0.599 1654

260.000 739.670 0.14176 7.054 0.09556 492. 85 537.91 629.34 2.76263 0.491 0. 617 1694

320.000 779.670 0.13441 7.440 0.09056 520.10 557.97 654.41 2.79563 0.510 0.636 1734

360. 000 819.670 0.12779 7.625 0.06609 547.29 578.80 600.23 2.82792 0.529 0.655 1772

400.000 859.670 0.12160 6.210 0.06197 574.42 600.39 706.61 2.85957 0.548 0.674 1008

440.000 899.670 0.11635 6.595 0.07626 601. 51 622.73 734.14 2.89064 0.567 0.693 1845

220
METHANE ISOBAR AT P = 80.0 PSI

T T OEM VOL OP/OT OP/OO E H S CV CP W DEG F OEG R L0/CUFT CUFT/LB PSI/R PSXCUFT/LB 8TU/LP BTU/L8 BTU/LB/R BTU/LB/R BTU/LB/R FT/S

296.197 163.473 28.201 0.03546 166.851 3633. 07 93. 15 93.67 1. 01157 0,494 0. 785 5175

290. 000 169.670 27.914 0. 03582 159.706 3443. 02 97.79 98.32 1.04090 0.492 0.790 5064

280.000 179. 670 27.446 0.03644 146.708 3141. 07 105.50 106.04 1.08652 0.493 0.804 4872

270.000 189.670 26.966 0.03708 138. 314 2847.32 113.46 114.01 1.13046 0.494 0.819 4675

260.000 199.670 26.473 0.03777 128.462 2564. 37 121.62 122. 18 1. 17287 0, 493 0.032 4480

250.000 209.670 25.964 0.03852 119.088 2293. 74 129.94 130.51 1.21384 0.488 0.844 4287

290.000 219.670 25.434 0.03932 110.129 2036. 12 130.40 138.99 1.25345 0.482 0.056 4095

230.000 229.670 24.880 0. 04019 101.524 1791.51 147.01 147.61 1.29188 0.476 0.871 3898

220.000 239.670 24.299 0. 04115 93.212 1559. 30 155.79 156.40 1. 32937 0.471 3.890 3695

212.660 246. 810 23. 863 0.04191 87.423 1400.51 162. 19 162.81 1.35573 0,468 0.906 3543

212. 860 246. 810 0.54793 1.825 0.40464 126. 84 330.94 357.97 2. 14645 0.396 0.592 938

210.000 249.670 0.53901 1.855 0.39633 129.00 332, 17 359.66 2. 15324 0. 394 0.587 946

200. 000 259. 670 0.51056 1.959 0.37074 139.73 336.43 365.44 2.17596 0.390 0.571 974

190.000 269.670 0.48565 2.059 0,34927 149. 16 340.59 371.09 2. 19732 0.387 0.560 1000

180.000 279.670 0.4635 3 2.157 0.33081 158.23 344.69 376.65 2.21755 0.305 0.551 1025

170.000 289. 670 0.44369 2.254 0.31467 166. 99 348.74 382.12 2. 23679 0. 383 0. 545 1049

160. COO 299. 670 0.42573 2.349 0.30037 175.52 352.75 387.54 2.25518 0. 302 0.539 1072

150.000 309.670 0.40938 2.44 3 0.28756 183. 86 356.72 392.91 2.27280 0.381 0.535 1094

140.000 119.670 0.39439 2.536 0.27599 192. 03 360.66 398.24 2. 28974 0.360 0.531 1115

130.000 329.670 0.38058 2.628 0.26546 200. 06 364.61 403.54 2. 30606 0. 300 0.528 1135

120.000 339.670 0. 36780 2.719 0.25582 207.97 368.53 408.81 2.32161 0.380 0.526 1155

110.000 349.670 0.35594 2.809 0.24695 215.78 372.44 414.06 2.33704 0.360 0.524 1175

100.000 359. 670 0.34488 2.900 0.23875 223. 50 376.34 419.29 2.35180 0.380 0.523 1 1°4 -90.000 369.670 0.33455 2.989 0. 23114 231. 14 380.23 424.51 2.36612 0. 380 0, 522 1212

-80.000 379.670 0.32486 3.078 0. 22404 238,71 384.12 429.73 2. 38003 0 . 381 0.521 1230

-70.000 389. 670 0.31576 3.16 7 0.21742 246. 21 388.01 434.93 2.39357 0.381 0.520 1248

-60. 000 399.670 0.30718 3.255 0.21121 253.67 391.91 440.13 2.40675 0.382 3.520 1265

-50.000 409.670 0. 29909 3. 343 0. 20537 261. 07 395. 80 445. 33 2.41960 0.383 0.520 1281

-40.000 419.670 0. 29144 3.431 0. 19987 268.42 399.71 450.54 2.43215 0. 384 0.521 1296

-30.000 429.670 0.28418 3.519 0.19469 275.74 403.62 455.75 2.44442 0.386 0.521 1314

-20.000 439.670 0.27730 3.606 0.18978 283.01 407.54 460.96 2.45641 0.307 0.522 1329

-10.000 449. 670 0.27076 3.693 0.18513 290. 25 411.47 466.18 2.46816 0. 389 0.523 1 345 0.000 459. 670 0.26454 3.780 0.18071 297.47 415.42 471.42 2.47967 0.391 0.524 1360

10.000 469.670 0.25861 3.867 0.17652 304.65 419.38 476.67 2.49097 0.393 0.526 1375

20.000 479. 670 0.25294 3.953 0.17252 311. 00 423.36 481.93 2.50206 0.395 0. 527 1389

30. 000 489. 670 0. 24753 4. 040 0. 16871 318.94 427.36 487.21 2.51295 0.397 0.529 1403

40.000 499. 670 0.24236 4.126 0.16507 326. 04 431.39 492.51 2.52366 0 . 399 0.531 1417

50.000 509.670 0.23740 4.212 0.16160 333. 13 435.43 497.83 2.53421 0.402 0.533 1431 60.000 519.670 0.23265 4.298 0.15827 340.20 439.50 503. 17 2.54459 0.405 0.535 1444

70.000 529. 670 0.22810 4. 384 0.15508 347. 25 443.59 508.54 2.55482 0.407 0.538 1458

80.000 539,670 0.22372 4.470 C . 1 5 c 0 3 354.26 447.72 513.93 2.56490 0.410 0.541 1471 100.000 559.670 0.21546 ‘.64 1 0.14627 368. 31 456.05 524, 80 2.58468 0.417 0.546 1496

120.000 579.670 0.20781 4.812 0.14095 382. 27 464.51 535.79 2.60397 0*424 0.553 1520

140. 000 599.670 0.20069 4.983 0.13602 396. 19 473.10 546.92 2.62284 0.4 31 0.560 1544

160.000 619. 670 0.19406 5.153 0.13143 410.06 461.85 558.18 2.64132 0.439 0.567 1567

180.000 639.670 0. 18786 5. 323 0. 12714 423. 89 490.74 569.60 2.65945 0.447 0.575 1590

200.000 659.670 0. 18205 5.493 0.12314 437.69 499. 80 501. 18 2.67727 0.455 0. 583 1611

220. 000 679.670 0. 1 7659 5.663 0.11 938 451 . 46 509.03 592.92 2.69400 0.464 0.591 1633

240.000 699.670 0. 17146 5.832 0. 11565 465.19 518.43 604. 83 2.71207 0.473 0.600 1654

280. 000 739.670 0. 16205 6.171 0. 10939 492.60 537.77 629.18 2.74592 0.491 0.618 1694

320. 000 779.670 0. 15364 6.509 0- 10363 519. 91 557. 85 654.27 2. 77894 0.510 0.636 1734

360. 000 819.670 0.14606 6.846 0.C9845 547.16 578.68 680. 10 2.81125 0.529 0.655 1772

400. 000 859.670 0.13921 7.184 0. C9377 574. 35 600.28 706.69 2.84291 0.548 0.674 18C9

440.000 899.670 0. 1 3297 7. 520 0. 08Q5? 601.48 622.63 734. 04 2.87400 0.567 0.693 1 845

221
<

METHANE ISOBAR AT P = 90.0 PSI

T T DEN VOL OP/OT DP/OO E H S CV CP M OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/L8 BTU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S

-296.165 163.505 28.202 0.03546 166.832 3634.40 93.15 93.74 1.01162 0.494 0.785 5175

-290.060 169.670 27.917 0.03582 159.729 3445.41 97.77 98.37 1. 04079 0.492 0.790 5065

-200. 000 179. 670 27.449 0.03643 148.737 3143.67 105.48 106.09 1.08641 0.493 0.004 4873

-270.000 189.670 26.970 0.03700 138.348 2850.11 113.43 114.05 1.13034 0.494 0.818 4676

-260.000 199.670 26.477 0.03777 128.502 2567.32 121.59 122.22 1.17274 0.493 0.832 4481

-250.000 209.670 25.968 0.03851 119.134 2296. 84 129.91 130.55 1.21369 0.488 0. 844 4289

-240.000 2 IB. 670 25.439 0.03931 110.181 2039.37 138.37 139.03 1.25329 0.482 0.856 4097

-230.000 229.670 24.886 0.04018 101.583 1794.90 146.97 147.64 1.29171 0.476 0.870 3901 -220.000 239.670 24.305 0.04114 93.279 1562.85 155.75 156.43 1.32919 0.471 0.889 3698

-210.000 249.670 23.690 0.04221 85.209 1342. 17 164.74 165.44 1.36600 0.468 0.913 3484

-206.861 250.809 23.617 0.04234 84.302 1317. 70 165.77 166.48 1.37017 0.468 0.917 3459

-208.061 250.609 0.61353 1.630 0.45717 125.56 331.72 358.88 2.13729 0.398 0.603 939

-200.000 259.670 0.58339 1.714 0.42897 134.88 335.58 364.15 2.15792 0.393 0.586 965

-190.000 269.670 0.55368 1. 806 0.40245 144.81 339.83 369.93 2.17977 0.389 0.571 992 -ISO. 000 279.670 0.52753 1.896 0.37998 154.28 344.00 375.59 2.20038 0.387 0.561 1018

-170.000 269.670 0.50422 1.983 0.36053 163.38 348. 18 381.15 2.21993 0.385 0.552 1043

-160.000 299.670 0.48325 2.069 0.34345 172.20 352. 16 386.64 2.23856 0.383 0.546 1066

-150. 000 309.670 0.46422 2.154 0.32825 180.79 356.18 392.08 2.25639 0.382 0.541 1089

-140. 000 319.670 0.44685 2.238 0.31459 189.18 360.16 397.46 2.27351 0.381 0.536 1110 -130.000 329.670 0.43090 2.321 0.30223 197.40 364. 13 402.81 2.28997 0.381 0.533 1131 -120.000 339.670 0.41617 2.403 0.29095 205.49 368. 08 408.12 2.30586 0.380 0.530 1152

•110. 000 349.670 0.40253 2.484 0.28061 213.46 372.01 413.41 2.32120 0.380 0.528 1171

-100. 000 359.670 0.38984 2.565 0.27108 221. 32 375.93 418.68 2.33606 0.381 0.526 1191 -90.000 369.670 0.37800 2.645 0.26225 229.09 379.84 423.93 2.35046 0.381 0.525 1209

-60.000 379.670 0.36692 2.725 0.25405 236.78 383.75 429.17 2. 36445 0. 381 0.524 1227 -70.000 369.670 0.35652 2.805 0.24640 244.40 387.66 434.40 2.37005 0.382 0.523 1245

-60.000 399.670 0.34674 2.884 0.23925 251.95 391.57 439.63 2.39130 0.383 0.522 1263

-50.000 409.670 0.33751 2.963 0.23253 259.45 395.48 444.85 2.40421 0.384 0.522 1279

-40.000 419.670 0.32880 3.041 0.22622 266.89 399.39 450.08 2.41681 0. 385 0.523 1296

-30.000 429.670 0.32055 3.120 0.22026 274.29 403.31 455.31 2.42912 0. 386 0.523 1312

-20.000 439.670 0.31272 3.198 0.21464 281.64 407.25 460.54 2.44116 0.387 0.524 1328

-10.000 449.670 0. 30529 3.276 0.20932 288.96 411.19 465.78 2.45294 0.389 0.525 1343

0.000 459.670 0.29823 3. 353 0.20427 296. 24 415.15 471.03 2.46449 0.391 0.526 1359

10.000 469.670 0.29149 3.431 0.19947 303.48 419.12 476.29 2.47582 0.393 0.527 1373

20.000 479.670 0.28507 3.508 0.19491 310.70 423.11 481.57 2.48694 0.395 0.528 1388

30.000 469.670 0.27894 3.585 0.19056 317.89 427.12 486.86 2.49786 0.397 0.530 1402

40.000 499.670 0.27306 3.662 0. 18642 325.05 431. 15 492.17 2.50860 0.399 0.532 1416

50.000 509.670 0.26746 3.739 0.18246 332. 19 435.20 497.51 2.51916 0.402 0.534 1430 60.000 519.670 0.26209 3.816 0.17867 339. 30 439.27 502.86 2.52956 0.405 0.537 1444

70.000 529.670 0.25693 3.892 0.17504 346.40 443.37 508.24 2.53981 0.408 0.539 1457

80. 000 539.670 0.25198 3.969 0.17157 353.48 447.50 513.64 2.54992 0.411 0.542 1470

100.000 559.670 0. 24264 4.121 0. 16503 367.58 455.84 524.53 2.56973 0.417 0.547 1495

120.000 579.670 0.23399 4.274 0.15899 381.62 464.31 535.54 2.58906 0.424 0.554 1520 140.000 599.670 0.22595 4.426 0.15339 395.60 472.92 546.68 2.60795 0.431 0. 560 1544

160.000 619.670 0.21846 4.577 0.14819 409.53 481.67 557.96 2.62645 0.439 0.568 1567

180. 000 639. 670 0. 21146 4.729 0.14333 423.42 490.58 569.39 2.64460 0.447 0.575 1589

200. 000 659.670 0.20491 4.880 0.13879 437.27 499.64 580.98 2.66244 0.455 0.583 1611 220.000 679.670 0.19675 5.031 0.13454 451.09 508.88 592.73 2.67999 0.464 0.592 1633

240.000 699.670 0.19296 5.182 0.13054 464. 87 518.29 604.65 2.69728 0.473 0.600 1654

280. 000 739.670 0. 18236 5.484 0.12324 492.35 537.64 629.03 2.73115 0.491 0.518 1694

320. OOU 779.670 0. 17288 5.785 0.11673 519.73 557.73 654.13 2.76420 0.510 0.637 1734

360. 000 819.670 0.16434 6.085 0.11087 547.04 578.57 679.98 2.79652 0.529 0.656 1772 400.000 859.670 0.15662 6.385 0.10559 574.28 600.17 706.58 2.82821 0.548 0.674 1809

44 0 . 0 0 0 899.670 0.14960 6.685 0.10079 601.46 622.54 733.94 2.85931 0.568 0.693 1845

222
METHANE ISOBAR AT P * 100.0 PSI

T T OEN VOL DP/DT DP/OO E H S CV CP M OEG F DEG R LB/CUFT CUFT/LB PSI/R PSXCUFT/L8 8TU/L0 8TU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S

-296.133 163. 537 28.204 0.03546 166.814 3635.73 93. 16 93.81 1.01166 0.494 0.785 5175

-290.000 169.670 27.920 0.03582 159.751 3447. 80 97.75 98.42 1.04068 0.492 0.790 5066

-280. 000 179.670 27.452 0.03643 148.765 3146. 28 105.46 106.13 1. 08629 0.493 0.804 4874

-270.000 189.670 26.973 0.03707 136.382 2852. 89 113.41 114. 10 1.13021 0.494 0. 018 4678

-260. 000 199.670 26.481 0.03776 128.542 2570.27 121.56 122.26 1. 17261 0.493 0.132 4483

-250.000 209.670 25.972 0.03850 119. 180 2299.94 129.68 130.59 1.21355 0.480 0.344 4291

-240.000 219.670 25.444 0.03930 110.233 2042.61 138.34 139.06 1.25314 0.482 0.156 4099

-230.000 229.670 24.892 0.04017 101.642 1798. 29 146. 94 147.68 1.29154 0.476 0. 870 3903

-220.000 239.670 24.312 0. 04113 93.346 1566.40 155.70 156.46 1.32900 0.471 0.189 3701

-210.000 249.670 23.697 0.04220 85,285 1345.90 164.68 165.46 1.36579 0.468 0.913 3486 -205. 175 254.495 23.387 0.04276 81.460 1243. 16 169.11 169.90 1.38340 0.467 0.927 3381

-205. 175 254. 495 0.67934 1.472 0. 51064 124. 14 332.40 359.65 2.12899 0.400 0.614 94 0 -200. 000 259.670 0.65894 1.518 0.49095 129. 86 334.70 362.80 2. 14123 0.397 0.602 956

-190.000 269.670 0.62382 1.603 0.45846 140.33 339.04 366.73 2. 16363 0. 392 0.584 964 -180.000 279.670 0.59321 1.686 0.43137 150.23 343.28 374.50 2.18465 0. 3 89 0.571 1011

- 170. 000 289. 670 0.5661

1.766 0.40819 159.70 347.45 380.16 2.20453 0 • 366 0.561 1036

-160.000 299.670 0.54190 1.845 0.38801 168. 82 351.56 385.73 2.22343 0.385 0.551 1061 -150.000 309.670 0.52002 1.923 0.37018 177.67 355.62 391.23 2.24148 0.363 0.547 1084 •140.000 319.670 0.50012 2.000 0.35425 186.29 359.64 396.67 2. 25878 0. 382 0.542 1106

-130.000 329.670 0.48190 2.075 0.33990 194.72 363,64 402.06 2.27540 0.382 0.538 1127

-120. 000 339.670 0.46514 2.150 0.32687 202. 99 367.61 407.42 2.29142 0.361 0.534 1148

-110.000 349.670 0.44964 2.224 0.31496 211. 12 371,57 412.75 2.30688 0.381 0.532 1168 -100.000 359.670 0.43525 2.293 0.30402 219. 13 375.51 418.06 2. 32184 0. 381 0.529 1188

-90. 000 369.670 0.42185 2.371 0.29391 227,03 379.45 423.34 2.33633 0.381 0.528 1206

-80. 000 379.670 0.40933 2.443 0.28454 234. 84 383.37 428.61 2.35040 0 .382 0.526 1225 -70,000 389.670 0.39759 2.515 0.27561 242.57 387.30 433.87 2.36407 0.382 0.525 1243 -60.000 399.670 0.38656 2.587 0.26767 250. 23 391. 22 439.12 2. 37738 0.383 0.525 1260

-50.000 409.670 0.37618 2.658 0.26004 257. 82 395.15 444.37 2. 39035 0.384 0.525 1277 -40.000 419.670 0. 36637 2.729 0.25288 265. 36 399.07 449,62 2.40300 0.365 0.525 1291. -30.000 429. 670 0.35710 2.800 0.24613 272. 84 403.01 454.86 2.41536 0. 3 86 0.525 1310 -20.000 439.670 0.34832 2.871 0.23976 280. 27 406. 95 460.11 2.42744 0. 388 0.525 1326

-10.000 449.670 0.33993 2.941 0.23375 287.66 410.91 465.37 2.43926 0.389 0.526 134?

0.000 459.670 0. 33205 3.012 0, 22804 295.00 414.87 470.64 2.45085 0.391 0.527 1357

ir. ooo 469.670 0. 32451 3.082 0.22263 302. 31 418.65 475.92 2.46221 0.393 0.528 137?

20. 000 479. 670 0.31732 3.151 0. 21749 309. 59 422. 85 481.21 2.47335 0.395 0.530 1387

30.000 489.670 0. 31045 3.221 0.21259 316. 84 426.87 486.52 2.48430 a. 397 0.532 1401 40.000 499.670 0.30389 3.291 0.20793 324.05 430. 90 491.84 2.49507 0.400 0.533 1415

50.000 509. 670 0.29761 3.36 0 0.20347 331.24 434,96 497.18 2.50566 0.402 0.535 1429

60. 000 519. 670 0. 29160 3.429 0. 19921 338.41 439.05 502.55 2.51608 0.405 0.538 1443 70.000 529. 670 0.28583 3.499 0.19514 345.55 443.15 507.94 2.52635 0.408 0.540 1456

80.000 539.670 0. 28030 3.568 0. 19123 352.67 447.29 513.35 2.53648 0.411 0.543 1469

100.000 559.670 0.26987 3.705 0.18389 366.65 455,64 524.26 2.55632 0.417 0. 548 1495

120.000 579. 670 0. 26022 3.843 0.17712 380.96 464.12 535.28 2.57568 0.424 0.554 1519

140.000 599.670 0. 25125 3.980 0. 17085 395.01 472.74 546.44 2.59460 0.431 0.561 1543

160.000 619.670 0. 24289 4.117 0.16502 409.01 481.50 557.73 2.61312 0.439 0.568 1567

180.000 639.670 0.23509 4.254 0. 15958 422.95 490.41 569.18 2. 63 130 0.447 0.576 1589

200.000 659. 670 0.22779 4.390 0.15451 436. 86 499.49 580.76 2.64916 0.455 0.584 1611

220. 000 679.670 0. 22093 4.526 0.14975 450.72 508.73 592.54 2.66672 0.464 0.592 1633

240. 000 699.670 0.21443 4.662 0.14529 464. 55 518.14 604.48 2.6S403 0.473 O.bOl 1654

280.000 739.670 0.20267 4. 934 0.13713 492. 11 537.50 626.87 2.71792 0.491 0.619 1694

320.000 779.670 0. 19212 5.205 0.12985 519.56 557.60 653.99 2.75099 0.510 0.637 1734

36 0. 0 00 819.670 0. 18262 5.476 0.12333 546. 92 578.46 679.85 2.78334 0.5 29 0.656 1772 400.000 859. 670 0.17403 5.746 0. 11743 574.21 600.07 706.47 2.81504 0.549 0.675 1809

440.000 899.670 0.16622 6.016 0.11209 601. 44 622. 44 733.84 2. 84615 0.968 0.694 1845

223
he thane isobar at p

T T DEN

* 120.0

VOL

PSIOP/OT OP/OO E H S CV CP w DEC r DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

>9 -296.069 163.601 26.206 0.03545 166.778 3636. 39 93.17 93.96 1. 01174 0.494 0. 765 5176

>9 -290. 000 169.670 27.926 0.03561 159.796 3452.57 97.72 96.51 1.04046 0.492 0.790 5068

?6 -280. 000 179.670 27.459 0.03642 146.622 3151.47 105.42 106.23 1.08606 0.493 0.803 4877

27 -270.000 189.670 26.960 0.03706 138.450 2658.46 113.36 114.19 1.12996 0.494 0.816 4661

>6 -260.000 199.670 26.469 0.03775 128.621 2576. 16 121.51 122.35 1.17234 0.493 0.831 4466

?5 -250.000 209.670 25.961 0.03649 119.271 2306. 12 129.62 130.66 1.21327 0.489 0.843 4295

?4 -240.000 219.670 25.453 0.03929 110.337 2049. 06 138.27 139.14 1.25283 0.462 0.655 4103

23 -230.000 229.670 24.903 0.04016 101.760 1605. 05 146.86 147.75 1.29121 0.476 0.869 3908

22 -220.000 239.670 24.324 0.04111 93.479 1573.47 155.61 156.53 1. 32663 0. 471 0.866 3706

21 -210.000 249.670 23.712 0.04217 65.437 1353. 33 164.56 165.52 1.36536 0.466 0.912 3494

20 -200.000 259.670 23.056 0.04337 77.566 1143.23 173.82 174.76 1.40176 0.467 0.943 3271

2020

-198. 538 261.132 22.959 0.04356 76.425 1113.26 175.20 176.16 1.40707 0.467 0.946 3237

- 198. 538 261. 132 0.61195 1.232 0.62066 120.96 333.46 360.65 2.11431 0.404 0.637 941

19 -190.000 269.670 0.77126 1.297 0.56032 130.95 337.36 366.19 2.13442 0.396 0.614 967

18 -160.000 279.670 0.73017 1.370 0.54165 141.64 341.79 372.22 2. 15641 0. 394 0.594 996

17 -170.000 269.670 0.69442 1.440 0.50944 152.09 346.09 376.09 2. 17703 0.390 0.560 1023

16 - 160. 000 299.670 0.66266 1.509 0.46194 161.66 350.31 363.64 2.19652 0.366 0.569 1049

15 -150.000 309.670 0.63465 1.576 0.45603 171.29 354.47 369.46 2.21505 0.366 0.560 1073

16 -140.000 319.670 0.60921 1.641 0.43693 160. 39 356.57 395.05 2.23274 0.365 0.553 1097

13 -130.000 329.670 0.56606 1.706 0.41612 189. 25 362.64 400.55 2.24970 0.364 0.546 1119

12 -120.000 339.670 0.56492 1.770 0.40116 197.90 366.67 406.01 2.26600 0.363 0. 543 1140

11 -110.000 349.670 0.54545 1.633 0.36581 206.36 370.66 411.42 2.28171 0.363 0.540 1161

10 -100.000 359.670 0.52746 1.696 0.37177 214.66 374. 67 416.60 2.29668 0.382 0.537 1161

-9 -90.000 369.670 0.51076 1.956 0. 35666 222. 66 378.65 422.15 2. 31156 0. 363 0.534 1201

-a — 80. 0 0 0 379.670 0.49521 2.019 0.34699 230.93 362.61 427.49 2.32579 0.363 0.532 1220

-7 -70.000 389.670 0.46067 2.060 0.33596 236. 69 386.57 432.60 2.33961 0.363 0.531 1238

-6 -60. 000 399.670 0.46705 2.141 0.32571 246.76 390.53 436.10 2.35305 0. 384 0.530 1256

-5 -50.000 409.670 0.45425 2. 201 0.31613 254.55 394.46 443.40 2.36613 0.365 0.529 1273

-4 -40.000 419.670 0.44219 2.261 0.30716 262.26 396.43 446.69 2.37889 0. 3 66 0.529 1290

-3 -30.000 429.670 0.43060 2. 321 0.29674 269.91 402.39 453.97 2.39134 0.367 0.529 1307

-2 -20.000 439. 670 0.42003 2. 381 0.29062 277.51 406.36 459.26 2.40351 0.366 0.529 1323

-1 -10. 000 449. 670 0. 40962 2.440 0.26334 265. 04 410.34 464.56 2.41541 0.390 0.530 1339

0.000 459.670 0.40014 2.499 0.27627 292.53 414.32 469.66 2.42707 0.392 0.530 1355

1 10.000 469.670 0.39092 2.556 0.26956 299.97 416.32 475.16 2.43649 0.394 0.531 1370

2 20.000 479.670 0.36215 2.617 0.26322 307.37 422.34 460.46 2.44970 0. 396 0.533 1365

3 30. 000 469. 670 0. 37379 2.675 0. 25716 314.73 426.37 465.62 2.46071 0.396 0.534 1399

4 40.000 499.670 0.36580 2.734 0.25143 322. 06 430.42 491.17 2.47152 0.400 0.536 1414

5 50.000 509.670 0.35816 2.792 0.24595 329. 35 434.50 496.54 2.46216 0.403 0.538 1428

6 60.000 519.670 0.35066 2.650 0.24072 336.62 436.59 501.92 2.49263 0.405 0.540 1441

7 70.000 529. 670 0. 34365 2.908 0.23571 343.65 442.71 507.33 2.50294 0.406 0.542 1455

a 80.000 539.670 0. 33714 2.966 0.23093 351. 06 446. 66 512.77 2.51310 0.411 0.545 1468

10 100.000 559.670 0.32450 3.082 0.22194 365.41 455.24 523.71 2.53302 0.417 0.550 1494

12 120.000 579.670 0. 31261 3.197 0.21366 379. 67 463.74 534.76 2.55244 0.424 0.556 1519

14 140. 000 599.670 0.30195 3.312 0.20600 393.85 472.37 545.96 2.57141 0.431 0.56 3 1543

16 160. 000 619.670 0. 29166 3.426 0. 19690 407. 97 461.15 557.29 2.58999 0.4 39 0.570 1566

ia 180.000 639.670 0. 26243 3.541 0.19226 422. 03 490.06 566.76 2.60621 0.447 0.577 1589

20 200.000 659.670 0.27361 3.655 0.16611 436. 04 499. 17 560.38 2.62610 0.456 0.565 1611

22 220. 000 679.670 0.26534 3.769 0.16033 450.00 506.43 592.17 2.64370 0.464 0.593 1632

24 240. 000 699.670 0.25757 3.663 0.17491 463.91 517.85 604.13 2.66104 0.473 0 • oO 2 1654

26 260.000 739.670 0.24334 4.110 0.16501 491.63 537.24 626.56 2.69499 0.492 0.620 1695

32 320.000 779.670 0. 23063 4. 336 0.15620 519.22 557. 36 653.71 2.72611 0.510 0.636 1734

36 360. 000 619.670 0.21920 4.562 0.14631 546.71 576.23 679.61 2.76049 0.530 0.657 1772

40 400.000 659.670 0.20667 4.766 0.14116 574.10 599.66 706.25 2.79222 0.549 0.675 1609

44 640. 000 699.670 0.19946 5.013 0.13473 601.41 622.25 733.64 2.62336 0.566 0.694 1646

224
METHANE ISOBAR AT P = 140.0 PSI

T T DEN VOL OP/DT DP/DD E H S CV CP w 0E6 F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/L 3/R FT/S

-296. 006 163.664 28.209 0. 0 3545 166.741 3641. 04 93.16 94.10 1.01183 0.494 0. 785 5177

-290. 000 169.670 27.932 0.03580 159.840 3457.33 97.68 98.61 1. 04024 0.492 0. 790 5070

-260. 000 179. 670 27.465 0.03641 146.878 3156.66 105.38 106.32 1.08583 0.493 0.30 3 4879

-2/0.000 189.670 26.987 0.03705 138.518 2864. 02 113. 32 114.28 1. 12972 0 . 495 0.818 4 68 4 -260.000 199.670 26.497 0. 0 3774 128,700 2582. 04 121.46 122. 44 1. 17208 0.493 0.331 4490

-250.000 209.670 25.990 0.03848 119. 362 2312.30 129. 76 130-76 1. 21298 0. 489 0.343 4298

-240. 000 219.670 25.463 0.03927 110.441 2055.54 138. 2C 139.22 1.25252 0.482 3. 355 4107

-230. 000 229.670 24.914 0.04014 101.877 1811.80 146.78 147.82 1.29087 0.476 0.369 3913

-220. 000 239.670 24.337 0.04109 93.612 1580.53 155.53 156.59 1. 32826 0.471 0. 387 3712

-210.000 249.670 23.727 0.04215 85.587 1360. 75 164.48 165.57 1. 36496 0 . 468 0.910 3501 -200.000 259.670 23.076 0.04334 77.738 1151.07 173.70 174.82 1.40129 0.467 0.941 3278 -192.659 267.011 22.565 0.04432 72.043 1002. 65 180.66 181.83 1.42790 0 • 466 0.969 3107 -192.659 267.011 0.94630 1.057 0.73516 117.52 334,29 361.69 2. 10 149 0.408 0.662 940

- 190. 000 269. 670 0. 9300 9 1.075 0. 71818 120.93 335.56 363.43 2.10800 0.406 0.552 949 -180.000 279.670 0.87572 1.142 0.66364 133.00 340.19 369.80 2. 13117 0 . 399 0.623 98 1 -170.000 289.670 0.82945 1.206 0.61970 144.17 344.66 375.92 2. 15267 0 . 394 0.602 1010 -160.000 299.670 0.78922 1.267 0.58304 154. 69 349.01 381.86 2. 17284 0.391 0.587 1037

-150. 000 309. 670 0. 75370 1. 327 0.55172 164.72 353.27 387.67 2.19191 0.389 0.575 106 3 -140. 000 319.670 0. 72197 1.385 0.52447 174. 35 357.46 393.37 2.21005 0. 387 0 .566 1087 -130.000 329. 670 0.69335 1.442 0.50043 183.66 361.61 399.00 2. 22737 0 . 3e6 0.559 1 11C -120.000 339.670 0.66733 1.499 0.47899 192.71 365.71 404.55 2. 24398 0. 385 0.553 1133

- 110. 000 349. 670 0.64352 1.554 0.45969 201.53 369.77 410.06 2. 25995 0. 384 0.548 1154

-100.000 359. 670 C. 62161 1.609 0. 44217 210.16 373.81 415.52 2.27534 0.384 0.644 1175

-90. 000 369. 670 0.60137 1.663 0.42618 218.63 377.83 420.94 2. 29022 0.384 0.541 1195 -80.000 379.670 0.58257 1.717 0.41 150 226.96 381.84 426.34 2. 30463 0.384 0.538 1214 -70.000 389.670 0.56505 1.770 0.39794 235.16 385.83 431.71 2. 31 860 0 . 384 0.536 1233

-60. 000 399. 670 0. 54868 1.823 0.38538 243. 25 369.82 437.07 2.33217 0. 385 0.535 125 2 -50.000 409.670 0.53333 1.875 0.37369 251.24 393.81 442.41 2. 34538 0 . 386 0.534 1269

-40. 000 419.670 0.51890 1.927 0. 36278 259.15 397. 79 447. 75 2. 35824 0.367 0.533 i2e7

-30.000 429.670 0.50530 1.979 0.35257 266.97 401.77 453. 08 2. 37079 0.388 0.533 1 3C4

-20. 000 439. 670 0.49246 2.031 0.34297 274. 72 405.76 458.41 2. 38 305 0.389 0.533 1320 -10.000 449.670 0.48032 2.082 0.33394 282.41 409. 7f 463.73 2.39504 0.391 0.533 1336 0.000 459.670 0.46880 2.133 0.32542 290. 04 413.77 469.07 2.40677 0.392 0.534 1 357 10.000 469.670 0.45786 2.184 0.31736 297.61 417.7° 474.41 2.41826 0. 394 0.534 1 36 3 20.000 479.670 0.44746 2.235 0. 30973 305.14 421.82 479.76 2.42953 0 . 396 0.536 1 38 3 30.000 489. 670 0.43755 2.285 0.30248 312.62 425.87 485. 12 2.44059 0 . 398 0.537 1 397 40.000 499. 670 0.42809 2. 336 0.29560 320. 06 429.94 490.50 2.45146 0.401 0.538 14 1? 50.000 509. 670 0.41906 2. 386 0. 28904 327. 46 434.03 495. 89 2. 46215 0.403 0.540 1426 60.000 519.670 0.41043 2.436 0.28279 334.82 438.14 501.30 2.47266 0.406 0.342 1440 70.000 529. 670 0.40216 2.487 0.27682 342. 15 442.27 506.73 2.48302 0.409 0 .644 145 3 80.000 539.670 0. 39424 2.537 0.27111 349.45 446.43 512.19 2.49322 0.411 0.547 1467 100.000 559. 670 0. 37934 2.636 0. 26042 363. 96 454.83 523. 17 2.51321 0.418 0.552 14 9 3 120.000 579.670 0. 36557 2.735 0.25058 378. 37 463.35 534.27 2.53269 0.425 0.558 1518 140.000 599.670 0. 35281 2.834 0.24149 392.69 472.01 545.49 2.55172 0.432 0.564 1542

160. 000 619.670 0.34094 2.933 0.23307 406. 94 480 . 81 556.84 2.57034 0.439 0.571 1565 180.000 639. 670 0. 32987 3.031 0.22524 421. 11 489. 75 568.34 2.58860 0.448 0.579 1588

200.000 659. 670 0.31952 3.130 0.21794 435.23 498.86 579.99 2.60654 0.456 0.586 1611

220. 000 679.670 0.30982 3.228 0.21112 449. 28 508.13 591.80 2.62417 0 . 465 0. 595 1632 240.000 699. 670 0.30071 3.326 0.20472 463. 29 517.57 603.78 2.64154 0.473 0.60 3 165 3 280. 000 739. 670 0. 28404 3.521 0. 19305 491.17 536.98 628.25 2.67555 0 .492 0.o21 1695

320.000 779.670 0.26916 3.715 0.16268 518. 89 557. 12 653.44 2.70871 0.511 0.639 1734

360.000 819.670 0.25579 3.909 0.17339 546.50 576.01 679. 36 2.74113 0. 530 0.657 1773 400.000 859.670 0.24371 4. 103 0.16502 573.99 599.66 706.03 2.77290 0.549 0.676 1810

440. 000 899. 670 0. 23273 4.297 0. 15744 601.40 622. 06 733.45 2.80407 0.568 0.595 1846

225
me thane isobar at p * 160.0 psx

T T OEM VOL DP/DT OP/DO E H S CV CP M OEG F OEG R LB/CUFT CUFT/L0 PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R 0TU/L8/R BTU/L8/R FT/S

-295.942 163.726 28.212 0.03545 166.705 3643. 69 93.19 94.24 1. 01192 0.494 0.785 5177

-290.000 169.670 27.937 0.03579 159.685 3462.08 97.64 98.70 1. 04002 0.492 0.790 5072

-280. 000 179.670 27.471 0.03640 148.934 3161.84 105.34 106.41 1.08560 0.494 0.603 4881

-270.000 189.670 26.994 0.03704 138.585 2669.56 113.27 114.37 1.12947 0.495 0. 817 4686

-260.000 19*. 670 26.504 0. 03773 128.779 2567. 91 121.41 122.52 1.17162 0.493 0.831 4493

-250.000 209.670 25.998 0.03846 119.452 2318.46 129.70 130.84 1.21270 0.489 0.842 4302

-240.000 219.670 25.473 0.03926 110,544 2061.99 138. 14 139.30 1.25222 0.483 0.854 4112

-230.000 229. 670 24. 925 0.04012 101,993 1818.53 146.71 147.89 1.29054 0.476 0.868 3918

-220.000 23*. 670 24. 350 0. 04107 93.744 1587.57 155.44 156.65 1.32789 0.471 0. S86 3718

-210. 000 249.670 23.742 0. 04212 85.737 1368. 13 164.37 165.62 1. 36455 0.468 0.909 3507

-200.000 259.670 23.093 0.04330 77.910 1158. 68 173.58 174.86 1.40082 0.467 0.939 3286

- 190.000 269.670 22.392 0.04466 70.185 958.22 183.12 184.44 1.43701 0.466 0.97 8 3053 -187.357 272. 313 22. 196 0. 04505 68.149 906.41 185.70 187.04 1.44660 0.465 0.990 2989

-187. 357 272. 313 1.0828 0.9235 0.8545 113. 66 334.89 362.25 2.09002 0.412 0.688 938 -180.000 279.670 1.0316 0.9694 0.6001 123.66 338.47 367.19 2.10793 0.405 0.657 964 -170.000 269.670 0.9723 1. 0285 0.7406 135. 90 343. 14 373.61 2.13048 0.399 0.628 995

-160.000 299.670 0.9217 1.0850 .0.6924 147. 26 347.64 379.78 2. 15144 0.395 0.608 1024

- 150. 000 309.670 0.8777 1.1394 0.6520 157.96 352.02 385.78 2. 17112 0.392 0.592 1052 -140.000 319. 670 0.8388 1. 1922 0.617*4 168.16 356.32 391.64 2.18974 0. 390 0.560 1077

-130.000 329.670 0.8040 1. 2438 0.5872 177.96 360.54 397.39 2. 20747 0.388 0.571 1102

-120.000 339.670 0.7726 1.2944 0.5606 187.43 364.71 403.06 2.22441 0. 367 0.563 1125

-110.000 349.670 0.7440 1.3441 0.5368 196.62 368.84 408.66 2.24066 0. 3 86 0.557 1147

-100. 000 359. 670 0.7178 1. 3931 0.5154 205.59 372.94 414.21 2.25630 0.385 0.552 1169

-90. 000 369. 670 0.6937 1. 4414 0.4959 214. 35 377. 00 419.71 2.27139 0.385 0.548 1189

-80.000 379.670 0.6715 1.4693 0.4762 222. 95 361.05 425.18 2.28598 0.3 85 0.545 1209 -70.000 369.670 0.6508 1.5366 0.4616 231.40 385.09 430.61 2.30011 0.385 0.542 1228 -60.000 399.670 0.6315 1.5635 0.4468 239.71 369.11 436.02 2.31382 0.3 86 0.540 1247 -50.000 409. 670 0. 6135 1.6301 0.4326 247.91 393.12 441.42 2.32715 0. 386 0.539 1265

-40.000 419.670 0.5965 1.6763 0.4196 256.01 397.14 446.80 2 . 34 0 1

3

0.387 0.536 1283 -30.000 429.670 0.5806 1.7222 0 .4076 26 4. 01 401. 15 452.17 2. 35279 0.388 0.537 1300 -20.000 439.670 0.5656 1.7679 0.3963 271.92 405.16 457.54 2. 36513 0.390 0.537 1317

-10.000 449. 670 0.5515 1.8133 0.3856 279.77 409.18 462.91 2.37720 0.391 0.537 1334

0.000 459. 670 0.5361 1.8566 0.3755 287.54 413.21 468.27 2.38901 0.393 0.537 1350 10.000 469.670 0.5253 1.9036 0.3660 295.25 417.25 473.65 2.40057 0.395 0.538 1365

20.000 479.670 0.5132 1.9484 0.3570 302. 90 421.30 479. 03 2.41191 0. 397 0.538 1380

30. 000 489.670 0.5017 1.9931 0.3465 310.50 425.37 484.42 2.42303 0 . 399 0.540 1395 40.000 499. 670 0.4908 2.0376 0.3404 318. 05 429.45 489.82 2.43395 0.401 0.541 1410 50.000 509.670 0.4803 2. 0620 0.3326 325.55 433.55 495.24 2.44469 0.404 0.543 1424 60.000 519.670 0.4703 2. 1262 0.3254 333. 02 437.68 500.67 2. 45525 0.406 0.544 1438 70.000 529.670 0.4608 2.1703 0.3165 340.44 441.83 506.13 2.46564 0.409 0.547 1452 80.000 539.670 0.4516 2.2143 0.3118 347. 63 446.00 511.60 2.47589 0.412 0.549 1465 100.000 559.670 0.4344 2.3020 0.2993 362. 51 454.43 522.63 2.49595 0.416 0.554 1492 120.000 579.670 0.4185 2. 3894 0.2879 377.08 462.97 533.76 2.51549 0.425 0.560 1517

140.000 599.670 0.4038 2.4764 0.2773 391.54 471.64 545.01 2.53457 0.432 0.566 1541

160.000 619.670 0.3902 2.5631 0.2675 405.91 480.46 556.40 2.55325 0.440 0.573 1565

180.000 639.670 0.3774 2. 6496 0.2565 420.20 469.4? 567.92 2.57155 0.448 0.560 1588

200.000 659.670 0.3655 2.7359 0.2500 434. 42 498.54 579.60 2.58953 0.456 0.588 1610

220. 000 679.670 0.3544 2.3219 0.2421 448. 57 507.83 591.43 2.60720 0.465 0.596 1632

240.000 699.670 0.3439 2.9076 0.2347 462.67 517.28 603.43 2.62460 0.474 0. 604 1653

280. 000 739.670 0.3248 3.0791 0.2212 490.71 536.72 627.94 2.65866 0.492 0.622 1695

320. 000 779.670 0.3077 3. 2496 0.2093 518.57 556.68 653.17 2.69167 0.511 0.640 1734

360.000 819.670 0.2924 3.4201 0.1986 546.29 577.79 679.12 2.72433 0.530 0.658 1773

400.000 859.670 0.2786 3.5900 0.1689 573.90 599.46 705.82 2.75613 0.549 0.677 1810 440.000 899.670 0.2660 3.7595 0.1802 601.39 621.67 733.26 2.78732 0.566 0. 695 1647

226
METHANE ISOBAR AT P = 100.0 RSI

T T 0EN VOL CP/DT OP/DO E M S CV CP w OEG F OEG R LB/CUFT CUfT/LB PSI/R PSICUFT/LB 8TU/LB 8TU/L0 8TU/IB/3 STU/L B/R 8TU/L8/R FT/S

-295.879 163.791 28.215 0.03599 166.669 3696.33 93.2® 99.30 1.0120® 0.494 0.785 5178

-290.000 169.670 27.993 0.03579 159.929 3966. 82 97.61 98.00 1. 0390® 0.493 0. 709 5074

-200.000 179.670 27.978 0.03639 198.990 3167.01 105.29 106.51 1.08536 0.494 0.803 4884

-270. 000 189.670 27.001 0.03709 136.652 2875. 10 113.22 119.96 1.12923 0.495 0.817 4689

-260.000 199.670 26.512 0.03772 128.858 2593.77 121.35 122.61 1.17155 0.494 0. 830 4496

-250.000 209.670 26.007 0.03895 119.593 2329.61 129.69 130.93 1.21292 0.489 0.842 4306

-290.000 219.679 25.983 0.03929 110.696 2068.92 138.07 139.3® 1.25191 6.483 0.854 4116

-230.000 229.670 29.936 0.09010 102.109 1825.29 196.63 197.97 1.29020 0.477 0.967 3923

-220.000 239.670 29.362 0.09105 93.875 1399.59 155.35 156.72 1.32752 0.472 0.985 3723

-210. 000 299.670 23.756 0. 09209 85.886 1375.50 169.27 165.60 1.36919 0.469 0.906 3514

-200.000 259.670 23.116 0.09327 78.080 1166.66 173.96 179.90 1.90035 0.467 0.938 3293

-190.000 269.670 22.913 0.09962 70.383 966.52 102.97 109.96 1.93697 8.966 0.975 3062

-182.513 277. 157 21.897 0.09577 69.632 821.31 190.36 191.09 1.96365 0.464 1.011 2879

-102. 513 277. 157 1.2218 0.8189 0.9790 110.05 335.31 362.59 2.07953 0.416 0.715 936

-100.000 279.670 1.2001 0.8332 0.9590 113.71 336.59 369.37 2.00592 0.413 0.701 946 -170.000 209.670 1.1293 0.8899 0.8793 127.29 391.51 371.16 2.10978 0.405 0.660 980 -160.000 299.670 1.0612 0.9929 0.8112 139.56 396.19 377.60 2. 13167 0. 399 0.632 1011 -150.000 309.679 1.0071 0.9929 0.7596 151.01 350.72 3®3.®i 2.15205 0.395 0.611 1040

• 190.000 319.670 0.9600 1.0917 0.7162 161.83 355.12 389.09 2.17122 0.392 0.596 1067

-130.000 329.678 0.9182 1.0891 0.6789 172.15 359.99 395.79 2.18939 0.390 0.584 1093

-120.000 339.670 0.8808 1. 1353 0.6963 182. 06 363.69 901.53 2.20669 0.389 0.575 1117

-110. 000 399.670 0.8970 1.1806 0.6179 191.65 367.09 907.29 2.22325 0. 307 0.567 1 140 -100.000 359.670 0.6162 1.2252 0.5916 200.96 372.09 912.03 2.23914 0.307 0.561 1162 -90,000 369.670 0.7880 1.269® 0.5683 210.03 376.16 910.96 2.25995 0.3 06 0.556 1183

-ao. ooo 379.670 0.7620 1. 1123 0.5971 218.91 380.25 923.99 2.26923 0.386 0.552 1204

-70.000 369.670 0.7379 1.3551 0.5277 227.60 389. 33 929.99 2. 20353 0. 306 0.548 1224 -60.000 399.67® 0.7156 1.3975 0.5099 236. 15 388.30 939.97 2.29739 0. 307 0.546 1243

-50.000 909.670 0.6997 1.9395 0.9935 299.56 392.93 990.91 2.31086 a. 3®7 0.544 1261

-90. 000 919.670 0.6752 1.9811 0.9782 252. 65 396.97 995.89 2.32395 0.308 0.542 1279

-30.000 929.670 0.6568 1.5225 0 .9690 261. 03 900.51 951.26 2.33671 0.309 0.541 1297 -20.000 939.670 0.6396 1.5635 0.9507 269.11 909.55 956.67 2.39915 0.390 0.541 1314

-10.000 999.670 0.6233 1.6099 0.9382 277.11 900.60 962.07 2.36131 0. 392 0.540 1331

0.000 959. 670 0.6079 1.6950 0,9266 285.03 912.65 967.90 2.37319 0.393 0.540 1347

10.000 969.670 0.5933 1.6859 0.9155 292.87 916.71 972.08 2.36982 0. 395 0.541 136 3 20.000 979.670 0.5795 1.7256 0.9051 300.65 920.70 978.29 2.39622 0.397 0.541 1378

30.000 989.670 0.5669 1.7656 0.3953 300.37 929.86 903.71 2.90741 0. 399 0.542 1393

90.000 999. 670 0.5539 1.8055 0.3860 316.03 928.96 989.19 2.91838 9.401 0.544 1408

50.000 509.670 0.5919 1.8952 0.3771 323.65 933.00 999.50 2.92917 0.404 0.545 1423

60.000 519.670 0.5305 1.8099 0.3687 331. 21 937.22 500.09 2.93978 0.407 0.547 1437

70.000 529.67® 0.5197 1.9293 0.3607 330.73 991. 38 505.52 2.95022 0.409 0. 549 1451

ao. ooo 539.670 0.5092 1.9637 0.3530 396.21 995.57 511.02 2.96050 0.412 0.551 1464

100. 000 559.670 0.9897 2.0921 0.3387 361.06 959.02 522.09 2.98063 9.410 0.556 1491 120.000 579.670 0.9717 2. 1202 0.3256 375.7® 962.50 533.25 2.50029 0.425 0.561 1516

190.000 599.670 0.9550 2.1979 0.3135 390. 38 971. 2® 599.59 2.51938 0.432 0.567 1541 160.000 619.670 0.9395 2.2759 0.3023 909.86 900.11 555.95 2.53010 0.440 0.574 156 4 lao. ooo 639.670 0.9251 2. 1526 0.2920 919.26 909.09 567.51 2.55695 0.448 0.581 1588

200. 000 659.670 0.9116 2.9296 0.2823 933.61 990*23 579.21 2.57997 0.456 0.589 1610 220.000 679.670 0. 3990 2.5063 0.2733 997. 06 507.53 591.07 2.59218 0. 465 0.597 1632 290.000 699.670 0.3872 2.5829 0.2699 962,05 517. 0® 603.09 2.60961 0.474 0.605 1653

280. 000 739.670 0.3656 2.7356 0.2996 990.25 536.96 627.69 2.69372 0.492 0.622 1695

320.000 779.670 0. 3963 2. 8677 0.236® 518.25 556.69 652.90 2.67698 0.511 0.640 1735

360. 0 00 819.67® 0. 3290 3. 9399 0.2239 596. 10 577.57 670.88 2.70948 0.530 0.659 1773

900.000 859.670 0.3139 3. 1907 0.2130 573.00 599.25 705.61 2.74130 0.549 0.677 1811 990.000 899.670 0.2992 3.3917 0.2031 601.39 621.69 733.07 2.77253 0.568 0.696 1847

227
ME THAME ISOBAR AT P * 200.0 PSI

T T DEN WOL DP/DT QP/DD E H S CV CP M DEG F DEG R LB/CUPT CUFT/LB PSI/R PSICUFT/LB BTU/L® 8TU/LB 8TU/LB/R BTU/ LB/R BTU / LB/R FT/S

- 295.815 163. 833 28.217 8.03544 166.633 3640.97 93.21 94.53 1.01209 0.495 0.785 9179

- 290.000 169.670 27.949 0 . 93 S 78 159.973 3471.55 97.57 98.89 1.03958 0.493 0.709 9876

- 200.000 179.670 27.484 0.03638 149.046 3172.17 105. 25 106.60 1.06513 0.494 0.892

- 270. 000 1 89. 670 27.000 0 . OS 783 138.719 2880.62 113.18 114.55 1.12898 0.495 0.817 4*92

- 260.000 199.670 26.520 0.03771 128.936 2599.62 121.30 122.70 1.17129 0.494 0.930 4499

- 250.000 209.670 26.015 0.03844 119.633 2330.76 129.59 131.01 1. 21214 0.489 0.642 4310

- 240.000 219.670 25.492 @o 9 392 3 110.749 2074.84 139.00 139.46 1.25161 0.483 0.853 4120

- 230.000 229.670 24.947 0.04009 102.225 1831.95 146.55 148.04 1.28967 0.477 0.867 3928

- 220 . 060 239.670 24.375 0. 04103 94.006 1601.59 155.26 156.78 1.32715 0.472 0.884 3729

- 210.000 249.670 23.771 0.04207 86.034 1362.34 164.17 165.73 1.36373 0.469 0.907 3520

- 200.000 259.670 23.127 0.04324 78.249 1174.41 173.34 174.94 1,39989 0.467 0.936 3301

- 190.000 269.670 22.434 0.04458 70.578 974.78 182.83 184.49 1.43593 0.466 0 . 973 3071

- 180. 000 279.670 21.672 0. 04614 62.924 792.21 192.73 196.44 1.47220 0.463 1.021 2627

- 178. 041 281.629 21.512 0.04646 61.415 745.15 194.73 196.45 1.47937 0.462 1.033 2777

- 178.041 282. 629 i • 3637 0.7333 1.1091 106. 14 335.58 362.73 2.06979 0.420 0.745 934

- 170.000 289.670 1.2873 0.7768 1.0236 118. 14 339.76 368.52 2. 09007 0.411 3.698 964

- 160.000 299.670 1.2087 0.8273 0.9412 131.57 344.66 375.30 2.11307 0.404 0.66 0 998

- 150.000 309. 670 1.1428 0.8750 0.8757 143. 87 349.35 381.76 2.13426 0.399 0.633 1020

- 140.000 319.670 1.0861 0.9207 0.6217 155.36 353.80 387.98 2.15405 0.395 0.613 1057

- 130.000 32®. 670 1. 0334 0.9648 0.7759 166. 23 358.30 394.04 2 . 17270 0.393 0.598 1083

- 120.000 339.670 8.9923 1.0077 0.7363 176.62 362.64 399.96 2.19040 0.391 0.587 1109

- 110.000 349.670 0.9528 1.0496 0.7017 186.61 366.91 405.70 2.20729 0.389 0.577 1133

- 100.000 359.670 0 o 9169 1. 0906 0.6709 196. 28 371.12 411.51 2.22346 0.388 0.570 1155

- 90.000 369.670 0.8842 1. 1309 0.6433 205.67 375.30 417.18 2.23900 0.388 0.564 1177

- 80.000 379.670 0.6542 1.1706 0.6184 214.83 379.44 422.79 2.25398 0.387 0.559 1198

- 70.000 389.670 0.8266 1.2096 0.5957 223.79 383.55 426.36 2.26845 0.

3

87 0.555 1219

-60.000 399.670 0.8009 1.2466 0.5749 232.57 387.65 433.89 2.28247 0.388 0.552 1238

- 50. 000 409.670 0.7770 1.2869 0.5558 241. 19 391.73 439.39 2.29607 0.368 0.549 1257

- 40.000 419.670 0.7548 1. 3249 0.5381 249.68 395.61 444.87 2 . 30929 0.389 0.547 1276

- 30.000 429.670 0.7339 1.3626 0.5216 258. 04 399.87 450.34 2.32215 0.390 0.546 1294

- 20.000 439.670 0.7143 1.4000 0.5063 266.29 403.94 455.79 2.33469 0.391 0.545 1311

- 10. 000 449. 670 0.6958 1.4372 0.4920 274.45 408.01 461.23 2.34694 0 . 392 0.544 1328

0.000 459.670 0.6784 1. 4741 0.4766 282.51 412.08 466.67 2.35890 0.394 0.544 1344

10. 000 469.670 0.6619 1.5108 0.4660 290. 49 416. 16 472.11 2.37061 0.396 0.544 1360 20.000 479.670 0.6463 1.5473 0.4541 296.40 420.25 477.55 2.38207 0 . 398 0.545 1376

30. 000 489. 670 0.6315 1.5836 0.4428 306.24 424.35 463.00 2.39331 0.400 0.545 1391

40.000 499.670 0.6173 1.6198 0.4322 314. 02 428.47 488.46 2.40435 0.402 0.546 1406

50.000 509.670 0.6039 1.6559 0.4221 321.74 432.60 493.93 2.41519 0.404 0.540 1421 60.000 519.670 0.5911 1.6918 0.4125 329.40 436.76 499.41 2.42584 0.407 0.549 1435

70.000 529.670 0.5769 1.7276 0.4034 337.02 440.93 504.91 2.43633 0.410 0.551 1449

80.000 539.670 0.5671 1.7632 0.3947 344.59 445.13 510.43 2.44665 0.413 0.553 1463

100.000 559.670 0.5452 1. 8342 0.3785 359.61 453.61 521.54 2.46686 0.419 0.550 1490 120.000 579.670 0.5250 1.9049 0.3636 374.48 462.20 532.74 2.48653 0.425 0.563 1515

140.000 599.670 0.5063 1.9752 0.3500 369.22 470.91 544.06 2.50573 0.433 0.569 1540

160.000 619.670 0.4689 2. 0452 0.3374 403.85 479.77 555.51 2.52450 0.440 0.576 1564

180.000 639. 670 0.4728 2. 1150 0.3257 418. 37 488.76 567.09 2.54289 0.448 0.583 1587

200.000 659.670 0.4578 2.1845 0.3149 432. 80 497.92 578.82 2.56095 0.457 0.590 1610 220.000 679.670 0.4437 2.2539 0.3047 447.15 507. 23 590.70 2.57869 0.465 0.598 1632

240.000 699.670 0.4305 2.3230 0.2953 461.43 516.71 602.74 2.59615 0.474 0.606 1653

280. 000 739.670 0.4064 2.4608 0.2761 489.79 536.20 627.33 2.63033 0.492 0.623 1695

320. 000 779.670 0.3849 2.5981 0.2629 517.94 556.41 652.63 2.66362 0.511 0.641 1735

360.000 819.670 0.3656 2.7349 0.2493 545.90 577.35 678.64 2.69616 0.530 0.660 1774

400.000 859.670 0.3483 2.6714 0.2371 573.71 599.05 705.39 2.72802 0.549 0.678 1811

440.000 899.670 0.3325 3.0075 0.2260 601.48 621.50 732.89 2.75928 0.568 0.696 1648

228
HE THAME ISOBAR AT P = 225.0 PSI

T T DEN VOL DP/DT OP/OD E H S CV CP H OEG F OEG R L8/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB 8TU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

295. 736 163.934 26.221 0.03543 166.587 3652. 27 93.23 94.70 1. 01219 0.495 0.784 5179

290.000 169.670 27.956 0.03577 160.027 3477. 46 97.52 99.01 1.03931 0.493 0 . 789 5078

260. 000 179.670 27.492 0.03637 149.115 3178.61 105.20 106.72 1.00485 0.494 0.802 4889

270.000 169.670 27.017 0.03701 138.803 2887.52 113. 12 114.66 1.12868 0.495 0. 816 4695

260.000 199.670 26.529 0.03769 129.033 2606.91 121.24 122.81 1.17097 0.494 0.829 4504

250.000 200.670 26.026 0.03842 119.745 2338.42 129.51 131.11 1.21179 0.490 0.841 4314

260.000 219.670 25.504 0.03921 110.876 2062.85 137.92 139.55 1.25123 0.483 0.852 4126

230. 000 229.670 24.960 0.04006 102.369 1840.30 146.46 148.13 1.28946 0.477 0.866 3934

220.000 239.670 24.390 0.04100 94.168 1610. 32 155.15 156.86 1.32670 0.472 0.883 3736

210.000 249.670 23.769 0. 04204 @ 6.218 1391.99 164. 05 165.80 1. 36322 0.469 0.905 3529 200.000 259.670 23.149 0.04320 78.459 1184.06 173. 19 174.99 1.39932 9.468 0.934 3310

190.000 269.670 22.459 0.04453 70.821 985.05 182.65 184.51 1.43527 0.466 0.970 3082

160.000 279.670 21.704 0. 0460 8 63.210 793.20 192.51 194.43 1.47141 0.463 1.017 2 84 0 172. 682 286.766 21. 110 0. 04737 57.733 660. 15 199.85 201.82 1.49750 0.459 1 . 061 2658

172.662 266.766 1.5456 0.6470 1.2802 101. 16 335.74 362.70 2.05844 0.425 0.785 931 170.000 269.670 1.5105 0.6620 1.2388 105.96 337.34 364.92 2. 06617 0.421 0.761 942

160.000 299.670 1.4067 0.7109 1.1227 121.10 342.60 372.22 2. 09094 0 . 411 0.703 9 ®Q

150. 000 309.670 1.3224 0.7562 1.0346 134.63 347.53 379.04 2. 11334 0.404 0.665 1013

140. 000 319.670 1.2515 0.7991 0.9640 147. 06 352.26 385.55 2 . 13402 0.399 0.638 1044

130.000 329.670 1.1903 0. 8401 0.9055 158.69 356.82 391.63 2.15336 0.396 0.618 1072

120.000 339.670 1.1367 0.8797 0.8557 169. 72 361.28 397.93 2. 17161 0.393 6.603 1098

110.000 349.670 1.0691 0.9162 0.8126 180. 25 365.65 403.90 2.18893 0.391 0.591 1123

100.000 359.670 1.0462 0.9558 0.7748 190. 38 369.95 409.77 2.20547 0.390 0.582 1147

-90. 000 369.670 1.0074 0.9926 0.7412 200.19 374.19 415.55 2.22133 0.389 0.574 1170

- 60.000 379.670 0.9720 1. 0288 0*7110 209. 71 378.40 421.26 2.23658 0.389 0.568 1192

- 70.000 369.670 0.9395 1.0644 0.6837 219.00 382.57 426.92 2.25128 0.389 0.563 1212

- 60. 000 399.670 0.9095 1. 0996 0.6588 228.07 366 . 7 ? 432.53 2.26550 0.389 0.559 1233

- 50.000 409. 670 0.0616 1. 1343 0.6360 236.97 390. 85 438.11 2.27928 0.369 0.556 1252

- 40.000 419.670 0.8557 1. 1686 0.6150 245.70 394. 96 443.65 2.29265 0.390 0.553 1271

- 30.000 429.670 0.8315 1.2027 0.5956 254. 30 399.07 449.17 2. 30566 9.391 0.551 1289

- 20.000 439.670 0.8086 1.2364 0.5776 262.76 403. 17 454.68 2.31832 0.392 0.550 1307

- 10.000 449.670 0.7875 1.2699 0.5608 271.11 407.26 460.17 2.33068 0.393 0.549 1324

0 . 000 459. 670 0.7674 1. 1031 0.5450 279.36 4 1 1 . 36 465.66 2.34274 0.395 0.548 1341 10.000 469.670 0.7464 1. 3362 0.5303 267.52 415.47 471.14 2.35454 0.396 0.548 1357 20.000 479.670 0.7305 1. 3690 0.5164 295.59 419.59 476.62 2. 36609 0. 390 0.548 1373

30.000 469.670 0.7134 1.4016 0.5033 303.58 423.71 482.11 2.37741 0.400 0.549 1389

40. 000 499.670 0.6973 1.4341 0.4909 311.50 427.85 487.60 2.38852 0.402 0.550 1404

50.000 509.670 0.6819 1.4665 0.4792 319. 35 432.01 493.11 2. 39942 0.405 0.551 1419

60.000 519.670 0.6673 1.4987 0.4681 327. 15 436. 18 498.62 2.41014 0.407 0.552 143 3 70.000 529.670 0.6533 1.5308 0.4576 334.88 440.37 504.15 2. 42068 0 . 410 0.554 1447 60.000 539.670 0.6399 1.5627 0.4476 342.57 444.59 509.70 2.43106 0.413 0.556 1461

100. 000 559.670 0.6149 1.6263 0.4289 357.80 453.10 520.86 2.45136 8.419 0.560 1488

120.000 579.670 0.5919 1.6896 0.4118 372.86 461.71 532.11 2.47111 0.426 0.565 1514

140.000 599.670 0.5706 1.7524 0.3961 387.78 470.45 543.47 2.49038 0.433 0.571 1539

160.000 619.670 0.5509 1.8150 0.3817 402.56 479.33 554.95 2.50922 0.441 0.577 1563

160.000 639.670 0.5327 1.6774 0.3683 417.23 488.35 566.57 2.52767 0.449 0.584 1587

200.000 659.670 0.5156 1.9395 0.3559 431. 79 497.52 578.33 2.54577 0.457 0.592 1610 220.000 679.670 0.4996 2. 0014 0.3443 446. 27 506.85 590.24 2.56356 0.466 0.690 1632

240. 000 699.670 0.4647 2.0631 0.3335 460.66 516.35 602.31 2.58106 0.474 0.608 1653

260.000 739.670 0.4574 2.1661 0.3139 469. 23 535. 87 626.95 2.61530 0.493 0.625 1695

320. 000 779.670 0.4332 2. 3085 0.2966 517.55 556.11 652.29 2.64866 0.512 0.642 1735

360.000 819.670 0. 4114 2-4305 0.2812 545.66 577. 08 678. 34 2.68124 0.531 0.660 1774

400.000 859.670 0.3916 2.5520 0.2673 573.61 598.80 705.13 2.71315 0.550 0.679 1812

640.000 899.670 0.3741 2.6733 0.2548 601.40 621.27 732.65 2.74443 0.569 0.697 1 848

229
METHANE ISOBAR AT P = 250.0 PSI

T T DEN VOL OP/DT DP/DD F N S CV CP w 0E 6 F DEO R L0/CUFT CUFT/LB PSI/R PSXCUFT/LB BTU/LB BTU/LB BTU/L8/R BTU/ LB/R BTU / LB/R FT/S

295.657 166.013 28.226 0.03563 166.562 3655.56 93.24 94.-68 1.01230 0.495 0.784 5180

290. 000 169.670 27.963 0.03576 160.082 3663.36 97.48 99.13 1.03904 0.493 0.789 5080

280.000 179.670 27.500 0.03636 169.166 3165.03 105.15 106.63 1. 06456 0.494 0 . 802 4892

27®. 000 169.670 27.026 0.03700 136.666 2896.60 113.06 116.76 1 . 12 S 37 0.496 0.816 4699

260.000 199.670 26.539 0.03768 129.131 2616. 19 121.17 122.92 1.17064 0.494 0.829 4508

250.000 209.670 26.037 0.03661 119.656 2366. 06 129.44 131.22 1.21144 0.490 0.840 4319

240.000 219.670 25.516 0.03919 111.002 2090. 86 137.84 139.65 1. 25005 0.483 0 . 852 4131

230. 000 229.670 26.976 0.06006 102 . 51 ? 1868.64 146.37 140.22 1.28904 0.477 0.865 3940

220.000 239.670 26.606 0.06097 96.330 1619.02 155.05 156.94 1.32624 0.472 0.882 3742

210.000 269.670 23.807 0.06201 66.691 1401. 11 163.92 165.87 1.36272 0.469 0.904 3536

200.000 259.670 23.170 0.06316 78.667 1193. 66 173. 06 175.04 1. 39675 0.466 0.932 3319

190.000 269.670 22.666 0.06668 71.060 995.26 102.48 184.54 1.43461 0.467 0.966 3093

160.000 279.670 21.735 0.06601 63.692 804.26 192.30 194.43 1.47063 0.463 1.013 2854

170.000 269.670 20.893 0.06766 55.826 618.89 202.66 204.85 1.50725 0.457 1.076 2597

166.119 292. 551 20.721 0.06626 56.355 584.46 204.66 206.69 1.51426 0.456 1.092 2546

168.119 291.561 1.7329 0.5771 1.6616 96.09 335.72 362.64 2.04777 0.430 0.830 927

160.000 299.670 1.6231 0.6161 1.3311 109.98 340.34 366.86 2.06950 0.419 0.758 960 150.000 309.670 1.5150 0.6601 1.2116 125.00 345.59 376.15 2.09342 0.410 0.703 997

1,60 . 0 00 319.670 1.6266 0.7010 1.1199 138.51 350.53 362.98 2.11516 0.404 0.667 1030 130.000 329.670 1.3516 0.7396 1.0655 150.99 355.27 389.52 2.13529 0.399 0.641 1060

120.000 339.670 1.2672 0.7769 0.9836 162.70 359.86 395.63 2.15415 0 . 396 0.622 1088

110.000 369.670 1.2303 0. 6126 0.9306 173. 80 364. 36 401.97 2. 17197 0.394 0.607 1114

100. 000 359.670 1.1796 0.8677 0.8666 164.43 368.74 407.98 2.18692 0.392 0.595 1139

- 90.000 369.670 1.1361 0.8616 0.8636 194.66 373.06 413.88 2.20511 0.391 0.586 1162

- 80.000 379.670 1.0927 0.9152 0.8077 20 4.57 377.34 419.70 2.22064 0.390 0.570 1185

- 70.000 369.670 1.0569 0.9660 0.7753 214.19 381.57 425.45 2.23559 0 . 390 0.572 1206

-60.000 399.670 1.0202 0.9602 0.7659 223.57 385.77 431.15 2.25002 0.390 0.567 1227

- 50.000 609.670 0.9661 1.0121 0.7190 232. 74 389.95 436.80 2.26398 0.390 0.563 1247

- 60.000 619.670 0.9581 1.0635 0.6965 241.73 394.10 442.41 2.27752 0.391 0.560 1266

- 30.000 629.670 0. 9305 1.0767 0.6716 250. 56 398.25 446.00 2. 29067 0.392 0.557 1265

- 20.000 639.670 0.9066 1.1055 0.6506 259. 24 402.36 453.56 2.30347 0.393 0.555 1303

- 10. 000 669.670 0.6303 1.1360 0.6313 267.79 406.51 459.10 2.31594 0.394 0.554 1321 0.000 659.670 0.6576 1.1663 0.6131 276. 22 410.66 464.64 2.32611 0.

3

95 0.553 1330

10.000 669.670 0. 6353 1. 1966 0*5960 284.55 414.76 470.16 2. 34001 0.397 0.552 1354

20.000 679.670 0.6156 1.2263 0.5601 292.78 418.92 475.69 2.35164 0.399 0.552 1371

30.000 669.670 9.7962 1.2560 0.5650 300.92 423.07 481.21 2.36304 0.401 0.553 1386

60. 000 699. 670 0.7779 1.2856 0.5508 308.99 427.23 466.74 2.37422 0.403 0.553 1402

50. 000 509. 670 0.7605 1. 3150 0.5376 316. 98 431.40 492.28 2.38519 0.405 0.554 1417 60.000 519.670 0.7639 1.3662 0.5267 324.90 435.60 497.83 2.39597 0.408 0.555 1431 70.000 529.670 0.7232 1. 3733 0.5127 332.75 439.61 503.39 2.40657 0.411 0.557 1446

80. 000 539.670 0.7131 1.6023 0.5012 340.55 444.06 508.96 2.41700 0.413 0.556 1460

100 . Q 00 559.670 0. 6869 1. 6600 0.6799 356.00 452.58 520.17 2.43739 0.420 0.563 1487

120.000 579.670 0.6591 1.5173 0.6605 371.25 461.23 531.47 2.45723 0.426 0.567 1513

160.000 599.670 0.6352 1.5763 0.6626 366. 36 469.99 542.87 2.47657 0. 433 0.573 1538

160.000 619.670 0.6132 1.6309 0.6266 401.26 478.89 554.39 2.49547 0.441 0.579 1563

180. 000 639. 670 0.5927 1.6673 0.6113 416. 09 467.94 566.05 2.51397 0.449 0.586 1586

200.000 659.670 0.5736 1.7635 0.3973 430.79 497. 13 577.04 2.53213 0.457 0.593 1609

220.000 679.670 0.5557 1.7995 0.3662 445. 39 506.68 569.70 2.54996 0.466 0.601 1632

260.000 699.670 0.5390 1.8552 0.3721 459.90 516.00 601.86 2.56750 0.475 0.609 1653

280.000 739.670 0.5066 1.9663 0.3500 490.66 535. 54 626.57 2.60102 0.493 0.626 1695

320. 000 779.670 0.6615 2.0766 0.3306 517.16 555.61 651.95 2.63523 0.512 0.643 1736

360.000 619.670 0.6573 2.1669 0.3132 545.43 576. 61 678.05 2.66787 0.531 0.661 1774 600.006 859.670 0.6356 2.2966 0.2977 573.50 596.55 704.67 2.69961 0.550 0.68 0 1812

660.000 699.670 0.6156 2.6059 0.2637 601. 42 621.04 732.42 2.73113 0.569 0.698 1849

230
METHANE ISOBAR ATP* 275.0 PSI

T T DEN VOL OP/DT OP/ CD E H S C V CP M OEG F DEG R L8/CUFT CUFT/LB PSX/R PSICUFT/LB B YU/LB 3TU/LB BTU/LB/R BTU/LB/R 9TU/L0/R FT/S

-295.577 164.093 28.228 0.03543 166.497 3658. 84 93.26 95. 06 1. 01241 0.495 0.794 5161

-290. 000 169.670 27.971 0.03575 160.136 3489.22 97.43 99.25 1.03877 0.493 0.789 5083

-290.000 179.670 27.507 0.03635 149.253 3191.44 105.10 106.95 1.08427 0.495 0.901 4895

-270.000 199.670 27.034 0.03699 138.969 2901. 27 113.01 114.69 1.12807 0.496 0.916 4702

-260.000 199.670 26.549 0.03767 129.227 2621. 46 121. 11 123. 03 1.17032 0. 494 0. 929 4512

-250.000 209.670 26.047 0.03839 119.967 2353.69 129.37 131.32 1.21109 0.490 0.940 4323

-240.000 219.670 25.528 0.03917 111.128 2098.81 137.76 139.75 1.25047 0.464 0.951 4136

-230.000 229.670 24. 987 0.04002 102.654 1856.95 146.27 148.31 1.28063 0.477 0.364 3946

-220.000 239.670 24.421 0. 04095 94.490 1627. 70 154.94 157.02 1. 32579 0. 472 0.881 3749

-210.000 249.670 23.824 0.04197 86.582 1410.19 163.80 165.93 1. 36221 0.470 0.903 3544

-200.000 259.670 23.190 0. 04312 78.873 1203. 23 172.90 175.09 1.39618 0 . 468 0.930 3329

- 190.000 269.670 22.509 0. 04443 71.298 1005.41 162.30 184.57 1.43396 0.467 0.965 3103

-190.000 279.670 21.766 0. 04594 63.771 815. 19 192.09 194.43 1.46986 0.464 1.009 2867

-170.000 299.670 20.933 0.04777 56.164 630.82 202. 37 204.60 1.50630 0.457 1. J7 0 2614

•163.696 295.964 20.341 0. 04916 51.224 . 516.49 209. 22 211.72 1.52992 0.452 1.125 2440

-163.666 295.964 1.9265 0.5191 1.6541 90.95 335.55 361.96 2. 03761 0. 435 0.880 923

•160. 000 299.670 1.8636 0.5366 1.5755 97.99 337.81 365.14 2. 04820 0.429 0.834 939

•150.000 309.670 1.7235 0.5802 1.4118 114. 88 343.48 373.03 2.07410 0.416 0.75 1 980 -140.000 319.670 1.6130 0.5200 1.2916 129.67 348.70 360.27 2. 09713 0.409 0.701 1015

-130.000 329.670 1.5218 0.6571 1.1974 143. 10 353. 64 387.11 2.11818 0.403 0.667 1048

-120.000 339.670 1.4443 0.5924 1.1204 155.56 358.39 393.65 2.13773 0.399 0.643 1077

-110.000 349.670 1.3769 0.7263 1.0556 167.28 362.99 399.98 2.15610 0. 396 0.624 1104

-100.000 359.670 1.3174 0.7590 1.0001 178. 43 367.49 406.14 2. 17348 0.39*. 0.610 1130 -90.000 369.670 1.2644 0.7909 0.9516 189. 11 371.90 412.18 2.19004 0. 393 0.598 1155

-90.000 379.670 1.2165 0.3220 0.9088 199.41 376. 25 418.11 2.20587 0.392 0.389 1178

-70.000 399.670 1.1730 0.8525 0,8706 209.38 380.55 423.96 2.22108 0. 392 0.581 1200

-60.000 399. 670 1. 1331 0.8825 0.8362 219.07 384.80 29.74 2.23574 0.391 0.575 1221 -50.000 409.670 1. 0965 0.9120 0.6049 228. 52 369. 03 435.47 2. 24969 0.392 0.570 1242 -40.000 419.670 1.0625 0.9411 0.7764 237. 77 393.23 441. 16 2.26360 0.392 0.566 1262

-30.000 29.670 1.0310 0.9699 0.7502 246.83 397.42 446. 31 2.27690 0.393 0.563 1281 -20.000 439. 670 1.0017 0.9983 0.7260 255.72 401.59 452.43 2.28983 0. 394 0.561 1299

-10. 000 449. 670 0.9742 1. 0265 0.7036 264. 47 405.75 458.02 2.30243 0.395 0.559 1317 0.000 459.670 0.9494 1. 0544 0.6828 273.09 409.91 463.61 2.31471 0.396 0.558 1335 10.000 469.670 0.9241 1. 0821 0.6633 281.59 414.08 469.18 2.32670 0.398 0.557 1352 20.000 479.670 0.9012 1. 1096 0.6451 289.99 418.24 474.75 2.33842 0.400 0.556 1368

30.000 499. 670 0.8796 1.1369 0.6280 ~ 298.26 422.42 480.31 2.34990 0.401 0.556 1384

40.000 499.670 0.8591 1. 1640 0.6119 306.49 426.60 485.88 2. 36116 0.4 04 0.557 1400 50.000 509.670 0.8396 1. 1910 0,5967 314.61 430.80 491.45 2.37220 0.406 0.557 1415 60.000 519.670 0.8211 1.2178 0.5823 322.66 435.01 497.03 2. 38304 0.408 0.558 1430 70.000 529. 670 0.8035 1. 2445 0.5687 330.64 439.24 502.62 2.39369 0.411 0.560 1444

80. 000 539.670 0.7867 1.2711 0.5558 338.55 443.49 508.22 2.40418 0.414 0.561 1458 100.000 559.670 0.7553 1.3239 0.5317 354,20 452. 06 519.48 2.42467 0 . 420 0.565 1486 120.000 579.670 0.7266 1.3764 0.5099 369. 64 460.74 530. 83 2.44458 0.427 0.570 1512

140. 000 599. 670 0.7001 1.4285 0.4900 384.90 469.53 542.28 2.46400 0.434 0.575 1538

160.000 619.670 0.6756 1.4803 0.4716 400.01 478.46 553.84 2.48296 0.441 0.581 1562

i ec . o o o 639.670 0.6528 1.5318 0.4547 414. 96 487.52 565.53 2.50153 0 .449 0.588 1586

200. 000 659.670 0.6317 1.5831 0.4390 429. 80 496.73 577. 35 2.51973 0.458 0.595 160 9 220.000 679.670 0.6119 1.6342 0.4245 444.52 506. 10 589.32 2.53761 0.466 0. o02 1631 240.000 699.670 0.5934 1.6851 0.4109 459. 14 515.64 601.45 2.55519 0.475 0.610 1653 280.000 739. 670 0.5598 1.7865 0.3864 488.11 535.22 626.19 2.58958 0.493 0.627 1695

320.000 779.670 0.5299 1. 8 87 3 0.3647 516.78 555.51 651.62 2.62305 0.512 0.644 1736

360.000 819.670 0.5031 1.9676 0.3455 545. 19 576.53 677.75 2.65573 0.531 0.662 1775

400.000 959.670 0.4790 2.0876 0.3282 573.40 598.30 704.60 2.68772 0.550 0.680 1813 440.000 899. 670 0.4572 2.1872 0.3127 601.43 620.81 732.18 2.71907 0.569 0.699 1850

231
HE THANE ISOBAR AT P a 300.0 RSI

T T DEN VOL OP /OT . DP/OO E H S CV CP w DEG F OEG R LS/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

295 . 698 166. 172 28.231 0.03562 166.652 3662. 12 93.27 95.26 1.01252 0.695 0.784 5182

290.000 169.670 27.978 0.03576 160.190 3695.08 97.39 99.37 1 . 03869 0.696 0.788 5085

280. 000 179. 670 27.515 0.03636 169.321 3197.83 105.05 107.07 1.08399 0.695 0.801 4898

278.000 189.670 27.063 0.03698 139.051 2908. 12 112.95 115.00 1.12777 0.696 0.815 4706

260.000 199.670 26.553 0.03765 129.323 2628.71 121.05 123.16 1.16999 0.695 0.828 4516

250.000 209.679 26.058 0.03838 120.077 2361. 30 129. 30 131.63 1. 21076 0.690 0 . 839 4328

260. 000 219.670 25.560 0.03915 111.256 2106.76 137.67 139.85 1.25010 0.686 0.850 4141

230.000 229.670 25.001 0.06000 102.796 1865.26 166.18 168.60 1.28822 0.678 0.863 3952

220. 000 239.678 26.636 0.06092 96.650 1636. 36 156.63 157.11 1.32536 0.673 0.380 3756

210.000 269.670 23.862 0.06196 36.762 1619. 26 163.67 166. 00 1.36171 0.670 0.901 3552

200.000 259.670 23.211 0.06308 79.078 1212.75 172.75 175.15 1.39762 0.668 0.929 3338

190.000 269.670 22.536 0.06633 71.533 1015.51 182.13 186.60 1.63332 0.667 0.962 3114

ISO . 000 279.670 21.796 0.06588 66.066 826. 02 191.88 196.63 1.66910 0.666 1.005 2800

170.000 289.670 20.973 0.06768 56.697 662. 66 202. 10 206.75 1.50537 0.656 1.063 2630

160.000 299.670 20.016 0.06996 66.673 663 . 37 213.03 215.81 1.56288 0.669 1.157 2352

159.535 300.135 19.967 0.05006 66.296 655.06 213.57 216.35 1.56668 0.669 1.163 2338

159. 535 300.135 2.1271 0.6701 1.8590 85.76 335.26 361.36 2.02783 0.661 0.936 918 150.000 309. 670 1. 9513 0. 5123 1.6610 106. 15 361.17 369.63 2.05698 0.626 0.814 962 160.000 319.670 1.8129 0.5516 1.6826 120.68 366.76 377.38 2.07962 0.616 0.743 1001 130.000 329.670 1.7017 0.5877 1.3630 135.00 351.92 386.57 2. 10176 0.607 0.697 1035

120.000 339. 679 1.6088 0.6216 1.2677 166.29 356.85 391.38 2. 12211 0.603 0.666 1066

110. 000 369.670 1.5296 0.6539 1.1890 160.66 361.59 397.92 2.16109 0.399 0.643 1095

100.000 359.670 1.6600 0.6869 1.1226 172. 38 366.20 606.25 2.15895 0.397 0.625 1122

” 90 .000 369.670 1.3985 0.7150 1.0669 163.53 370.71 610.63 2.17590 0.395 0.611 1147

> 00.000 379.670 1.3635 0.7663 1.0166 196. 23 375. 16 616.69 2.19206 0. 396 0.600 1171

- 70.000 389.670 1.2938 0.7729 0.9699 206.56 379.50 622.66 2.20756 0.393 0.591 1194

-60.000 399.670 1.2686 0.8010 0.9299 216.57 383.62 628.32 2.22263 0.393 0.584 1216

-50.000 609. 670 1.2069 0.8286 0.8938 226. 31 388.10 636.13 2.23679 0.393 0.578 1237

-60.000 619.670 1.1686 0. 8557 0. 8610 233.82 392.35 639.89 2.25068 0 . 393 0.573 1257

- 30. 000 629.670 1.1331 0.9825 0.8310 263.11 396.58 665.60 2.26616 0.396 0.570 1277

- 20.000 639.670 1.1001 0.9090 0.8036 252. 23 600.79 651.28 2.27721 0.396 0.567 1296

- 10.000 669. 670 1.0693 0.9352 0.7779 261.18 606.99 656.96 2.28992 0.396 0.564 1314

0.000 659.670 1.0605 0.9611 0.7562 269.98 609. 18 662.57 2. 30231 0.397 0.563 1332

10.000 669.670 1.0136 0.9866 0.7321 276.66 613.37 668.19 2.31661 0.398 0.561 1349

20.000 679.670 0.9879 1.0123 0.7115 267.21 617.56 673.80 2.32622 0.600 0.561 1365

30. 000 689.670 0.9638 1.0376 0.6922 295.66 621.76 679.60 2.33779 0.602 0.560 1382

60. 000 699. 670 0. 9610 1. 0627 0.6761 306. 01 625.97 685.00 2.36911 0.606 0.560 1397

50.000 509.670 0.9196 1. 0877 0.6570 312.26 630. 19 690.61 2.36022 0.607 0.561 1413

60.000 519.670 0.6989 1.1125 0.6609 320.66 636.62 696.22 2. 37113 0.609 0.562 1428

70.000 529.670 0.8796 1.1372 0.6256 328.56 638.67 501.86 2.38186 0.612 0 . 563 1442

80 . 000 539.670 0.6608 1.1617 0.6111 336.56 662.96 507.68 2.39238 0.614 0.564 1457

100.000 559.670 0.8261 1.2105 0.5863 352.62 651.55 518.79 2.61296 0.420 0.568 1485

120.000 579.670 0.7963 1.2589 0.5599 368.05 660. 25 530.19 2.63297 0.427 0.572 1511 160.000 599.670 0.7651 1.3070 0.5377 363.69 669.07 561.68 2.65266 0.434 0.577 1537

160. 000 619.670 0.7381 1.3567 0.5173 398.76 678.02 553.28 2.67169 0.442 0.583 1562

180.000 639.670 0.7131 1.6022 0.6985 613. 85 687.11 565.00 2.69011 0.450 0.590 1586

200.000 659.670 0.6699 1.6695 0.6812 628.61 696. 36 576.86 2.50836 0.458 0.596 1609

220. 000 679.670 0.6662 1.6965 0.6651 663.65 505.73 508.87 2.52629 0.466 0.604 1631 260.000 699.670 0.6679 1.5636 0.6501 658.38 515.28 601.02 2.56391 0.475 0.612 165 3 200. 000 739.670 0.6110 1.6367 0.6229 667.56 536.89 625.81 2.57837 0.494 0.628 1696

320.000 779.670 0.5783 1.7293 0.3990 516. 60 555.21 651.28 2.61190 0.512 0.645 1736

360.000 819.670 8.5690 1.8216 0.3778 566. 97 576.26 677.65 2.66663 0.531 0.663 1775

600.000 859.670 0.5226 1.9136 0.3589 573. 30 598.05 706.36 2.67665 0.550 0.681 1813

660.000 899.670 0 . 698 e 2.0069 0.3618 601.65 620.58 731.95 2.70606 0.569 0.699 1850

232
METHANE ISOBAR AT S» a 325.0 PSI

T T DEN WOL DP/DT DP/ OD E H S ev CP M DEG F DEG R LB/CUFT cuft/lb PSI/R PSICUFT/IB 8TU/LB BTU/LB BTU/LB/R 8TU/L3/R 0TU/LB/R FT/S

295. 419 164.251 20.234 0.03542 166.407 3665.39 93.29 95.42 1.01262 3.496 0.784 5183

290.000 169.670 27.985 0,91573 160.243 3500.92 97.34 99.49 1.03822 0.494 0.708 5088

200.000 179.670 27.523 9.03633 149.389 3204.21 105. 00 107.18 t° 08370 0.495 0. 801 4901

270. 000 109. 670 27.052 0.03697 139.133 2914.95 112.89 115.12 1.12746 0.496 0.815 4709

260.000 199.670 26.568 0.03764 129.419 2635.94 120.96 123.25 1.16967 0.495 0.828 4520

250.000 209.670 26.069 0.03036 120.10? 2368.90 129.22 131.53 1.21040 0.490 0.839 4333

240.000 219.670 25.952 9.03914 111.379 2114. 69 137.59 139.95 1.24972 0 . 404 0.850 6146

230.000 229.670 25.014 0.03993 102.937 1873.51 146.09 148.49 1.28782 0.478 0.862 3958

220.000 239.670 24.452 0.04090 94.800 1644.97 154.73 157.19 1.32489 0.473 0.879 3763

210.000 249.670 23.060 9.04191 06.941 1426,25 163.55 166.07 1.36122 0.470 0.900 3559

200.000 259.670 23.232 0.04304 79.281 1222. 23 172.61 175.20 1.39706 0.469 0.927 334?

190.000 269.670 32.559 0.04633 71.766 1025.55 161. 96 104.63 1.43266 0.467 0.960 3125

100.000 279.670 21.026 0.04502 64.318 336.77 191.67 194.43 1.46835 0.464 1.001 2893

170.000 209.670 21.011 0.04759 56.824 654.34 201.04 204.71 1.50445 0.458 1.057 2646

160.000 299.670 20.069 0. 04903 49° 088 476.43 212.68 215.68 1.54168 0.449 1.146 2373

155.626 304. 064 19.596 0. 05103 45.537 399. 36 217.75 220.82 1.55870 8.446 1,207 2239

155.626 304. 064 2.3355 0.4202 2.0776 80.45 334.79 360.56 2.01831 0.447 1.000 914

150.000 309.670 2. 2060 0.4533 1.9094 92.58 338.59 365.87 2.03564 0.434 0. S98 942

160.000 319.670 2. 0291 0.492® 1.6971 110.86 344,62 374.28 2.06238 0.421 0.794 965 130.000 329.670 1.0920 0.5283 1.5447 126.65 350.10 361.89 2.08583 0.412 0.733 1022

120.000 339.670 1.7018 0.5612 1.4269 140.87 355.24 389.01 2. 10709 0.406 0.693 1055

110.000 369.670 1.6003 0.5923 1.3315 153.99 360.14 395.79 2. 12675 0. 402 0.664 1005

100.000 359.670 1.6076 0.6220 1.2520 166.28 364, 87 402.31 2.14515 0.399 0,642 1113

-90.000 369.670 1.5369 0.6507 1.1842 177.92 369.49 406.64 2.16252 0.397 0.625 1140

-00.000 379.670 1.4740 0.6784 1.1252 109. 05 374.00 414.83 2. 17903 0.396 0.612 1164

-70.000 309.670 1.4174 0.7055 1.0734 199.75 378.44 420.90 2. 19481 0.395 0.602 1186

-60.000 399.670 1.3662 0.7320 1.0273 210. 09 382. 82 426.07 2.20994 0.394 0.593 1211 -50.000 409.670 1.3194 0. 7579 0.9050 220.12 367.15 432.77 2.22452 0.394 0,586 1232

-40.000 419.670 1.2764 0.7834 0.9403 229,69 391.45 438.60 2.23859 0.394 0.581 1253

-30.000 429.670 1.2367 0.8006 0.9142 239.42 395.72 444.39 2.25221 0.395 0.576 1273

-20.000 439.670 1.1999 0.8334 0.8829 240.76 399=97 450.13 2. 26542 0.395 0.573 1292

-10. 000 449.670 1.1656 0.0579 0.0540 257.91 404.21 455.84 2.27026 0.396 0.570 1310

0.000 659.670 1.1336 0.8021 0.8273 266.9® 408.44 461.52 2.29077 0.398 0.567 1328

10.000 469.670 1.1036 0.9061 0.8025 275.75 412.66 467.19 2.30296 0.399 0.566 1346

20.000 479.670 1.0753 0.9299 0.7794 284. 46 416. 88 472.84 2. 31487 0.401 0.565 1363

30.000 409.670 1.0487 0.9535 0.7576 293.06 421.10 478.49 2.32652 0.403 0.564 1379

40.000 499.670 1.0236 8.9770 0.7375 301.55 425. 33 484.13 2.33792 0.405 0.564 1395

50. 000 509.670 6.9998 1. 0002 0.7184 309.94 429.50 489.77 2.34910 0.407 0.564 1411 60.000 519.670 0. 9772 1. 0233 0.7004 318. 24 433. 83 495.42 2. 36007 0.410 0.565 1426

70.000 529.670 0.9597 1.0463 0.6834 326.46 438,10 501.07 2.37085 0.412 0.566 1441 00.000 539.670 0.9353 1. 0692 0.6673 334.59 442.39 506.73 2.38144 0.415 0.567 1455

100.000 559.670 0.0972 1.1146 0.6375 350.66 451.03 510.10 2.40212 0.421 0.570 1463

120.000 579.670 6. 0624 1. 1596 0.6106 366.46 459.76 529.54 2.42221 0.427 0.574 1510

140.000 599.670 0.0394 1. 2042 0.586® 302. 08 468.61 541.00 2.44177 0.435 0.579 1536

160.000 619.670 0.0009 1.2405 0.5635 397.50 477.58 952.72 2.46007 0.442 0.585 1561 100.000 639.670 0.7736 1.292® 0.5428 412.74 406.69 564.40 2.47955 0.450 0.591 1585

200. 000 659.670 0.7483 1. 3364 0.5237 427. 84 495.94 576.37 2.49765 0.458 0.598 1608

220.000 679.670 0.7246 i. 3801 0.5060 442.80 505.35 980.41 2.51583 0.467 0.605 1631 260.000 699.670 0.7025 1.4235 0.4895 457,64 514,92 690.59 2.53349 0.476 0.613 1653

200. 000 739.670 0.6623 1.5099 0.4598 407.01 534.57 625.43 2.56002 0.494 0.629 1696

320. 000 779.67® 0. 6267 1.5957 0.4336 516.03 554.92 650.95 2.60161 0.513 0.646 1737

360. 000 019.670 8.5949 1.6811 0.4104 544,74 575.99 677.16 2.63438 0.532 0.664 1776

400.000 059.670 8.5662 1.7660 0.3896 57 3.21 597. 80 704.00 2.66645 0.551 0.682 1614

440.000 099.670 0.5403 1.8507 0.3710 601.47 620.34 731.72 2.69788 0.569 0.700 1851

233
HETHANE ISOBAR AT P = 350.0 PSI

T T OEN VOL OP/OT DP/DD E H S CV CP W OEC F OEG R LB/CUFT CUE T /LB PSI/R PSICUFT/LB 8TU/Le BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

295. 340 164. 330 26.236 0.03541 166. 362 3668.66 93.30 95.60 1.01273 0.496 0.784 5164

290.000 169.670 27.992 0. 03572 160.297 3506. 75 97. 30 99.61 1.03795 0* 494 0.766 5090

280.000 179.670 27.531 0.03632 149.457 3210.58 104.95 107.30 1.08342 0.495 0.801 4904

270.000 189.670 27.060 0.03695 139.215 2921.77 112.64 115.23 1.12716 0.497 0.815 4713

260.000 199.670 26.577 0.03763 129.515 2643.16 120.92 123.36 1.16935 0.495 0.827 4524

250.000 209.670 26.079 0.03834 120.297 2376. 47 129.15 131.64 1.21005 0.491 0.638 4337

240.000 219.670 25.564 0.03912 111.503 2122.61 137.51 140.05 1.24935 0.464 0.849 4152

230.000 229.670 25.027 0.03996 103.077 1681.76 146.00 146.59 1.28741 0.478 0.661 3963

220. 000 239.670 24.467 0.04087 94.966 1653.56 154.62 157.27 1.32445 0.473 0.877 3769

210. 000 249. 670 23.877 0. 04168 87.119 1437. 24 163.43 166.15 1.36072 0.470 0.898 3567

200.000 259.670 23.252 0.04301 79.462 1231.66 172.47 175.26 1.39650 0.469 0.925 3356

190.000 269.670 22.563 0.04426 71.996 1035.54 181.79 164.66 1.43205 0.467 0.957 3135

160. 000 279.670 21.856 0.04575 64.566 847.45 191.47 194.43 1.46761 0.464 0. 998 2905

170.000 289.670 21.049 0. 04751 57.145 665.93 201.59 204.67 1.50354 0.458 1.051 2662

160.000 299.670 20.121 0.04970 49.494 489.31 212.34 215.56 1.54051 0.449 1.135 2394

151.929 307.741 19.225 0.05202 42.920 346.63 221.79 225.16 1.57213 0.443 1.258 2141 151.929 307.741 2.5526 0. 3917 2.3115 75. 09 334. 20 359.59 2. 00696 0.453 1.075 909

150.000 309.670 2.4962 0.4006 2.2343 79.81 335.65 361.61 2.01551 0.447 1.023 920

140.000 319.670 2.2655 0.4414 1.9415 100.68 342.31 370.92 2.04510 0.426 0.860 96 8 130.000 329.670 2.0972 0.4766 1.7455 116. 01 346.16 379.06 2.07018 0.417 0.776 1008

120.000 339.670 1.9642 0.5091 1.5995 133. 28 353.54 366.53 2. 09252 0.410 0.723 1043

110. 000 349.670 1.6543 0.5393 1.4641 147. 20 356.62 393.58 2. 11295 0.405 0.687 1075

100.000 359.670 1.7608 0.5679 1.3695 160.12 363.50 400.31 2.13193 0.402 0.661 1105

•90.000 369.670 1.6797 0.5954 1.3097 172.29 368.22 406.81 2.14977 0.399 0.641 1132

-60.000 379.670 1.6081 0.6219 1.2412 163. 66 372.63 413.14 2.16665 0.397 0.625 1158

-70.000 369.670 1.5441 0.6476 1.1613 194.94 377.35 419.32 2.18274 0.396 0.613 1182

-60.000 399.670 1.4665 0.6727 1.1264 205.61 381. 60 425.40 2. 19614 0.395 0.603 1205

-50.000 409.670 1.4341 0.6973 1.0611 215.94 366.19 431.39 2.21293 0.395 0.595 1227

-40. 000 419.670 1.3861 0.7215 1.0365 225.96 390.54 437.30 2.22720 0. 395 0.586 1246

-30.000 429.670 1.3420 0.7452 0.9998 235.75 394.06 443.16 2.24098 0.396 0.563 1269

-20.000 439.670 1.3011 0.7686 0.9645 245.31 399. 15 446.96 2.25435 0.396 0.579 1268

-10.000 449.670 1.2632 0.7916 0.9321 254.66 403.43 454.73 2.26732 0.397 0.575 1307

0. 000 459. 670 1. 2278 0.8145 0.9022 263.64 407.69 460.47 2.27994 0.396 0.573 1325

10.000 469.670 1.1947 0.6370 0.8745 272.86 411.94 466.19 2.29224 0.400 0.571 1343

20.000 479.670 1.1636 0. 8594 0.8487 261.74 416. 19 471.68 2.30425 0.401 0.569 1360

30.000 469.670 1.1344 0.8615 0.6246 290.49 420.44 477.57 2.31598 0.403 0.566 1377

40.000 499. 670 1. 1066 0.9035 0.6020 299.12 424.70 463.25 2.32746 0.405 0.568 1393

50. 000 509.670 1.0607 0.9253 0.7609 307.64 426.96 468.93 2.33871 0.408 0.566 1409

60.000 519.670 1.0560 0.9470 0.7610 316. 07 433.24 494.61 2.34975 0.410 0.566 1424

70.000 529.670 1.0325 0.9665 0.7421 324.40 437.52 500.29 2. 36058 0.413 0.569 1439

60.000 539.670 1.0102 0.9699 0.7244 332.65 441.63 505.99 2.37123 0.415 0.570 1454

100.000 559.670 0.9667 1. 0323 0.6915 346.92 450.50 517.41 2.39202 0.421 0.573 1482

120.000 579.670 0.9308 1.0744 0.6619 364.93 459.27 526.90 2.41219 0.428 0.577 1509

140.000 599.670 0.6960 1.1161 0.6349 380.70 468. 14 540.46 2.43183 0.435 0.561 1535

160.000 619.670 0.6639 1.1575 0.6102 396.26 477.14 552.16 2.45099 0.442 0.587 1561

160.000 639.670 0.6343 1. 1966 0.5675 411.65 466.27 563.96 2.46972 0.450 0.593 1585

200.000 659. 670 0.6068 1.2395 0.5666 426. 68 495.55 575.66 2.48606 0.459 0.600 1608

220.000 679.670 0. 7811 1. 2602 0.5472 441.96 504.96 567.95 2.50610 0.467 0.607 1631 240.000 699.670 0.7572 1.3207 0.5293 456.91 514.56 600.16 2.52301 0.476 0.614 1653

260. 000 739.670 0.7137 1.4012 0.4966 486.46 534.24 625.05 2.55640 0.494 0.630 1696

320. 000 779.670 0.6752 1.4611 0.4663 515.66 554.62 650.61 2.59205 0.513 0.647 1737

360. 000 619.670 0.6408 1.5606 0.4431 544.53 575.71 676.86 2.62468 0.532 0.665 1776

400.000 659.670 0.6099 1.6397 0.4206 573.13 597.55 703.62 2.65699 0.551 0.683 1814

440.000 699.670 0.5619 1.7165 0.4003 601.50 620.11 731.49 2.66645 0.570 0.701 1851

234

'ii mi
HE T HANE ISOBAR AT P * 575.0 PSI

T T DEN VOL OP/OT DP/DO F H S CV CP H DEG F DEG R LB/CUFT CUFT/LB PSX/R PSICUFT/Le BTU/L8 BTU/L 8 BTU/L 8 /R BTU / L 8 /R 0 TU / L 9 /R FT/S

- 795.260 164.410 28.241 0.03541 166.317 3671.92 93.31 95.77 1.01264 0.496 0.783 5184

- 290.000 169.670 27.999 0.03572 160.350 3512. 56 97.25 99.73 1.03768 0.494 0.786 5092

- 280.000 179.670 27.539 0.03631 149.525 3216.93 104. 90 107.42 1. 08313 0.495 0.800 4907

- 270. 000 189.670 27.069 0.03694 139.296 2928.58 112.78 115.35 1.12686 0.497 0.814 4716

- 260.000 199.670 26.587 0.03761 129.610 2650. 37 120.86 123.47 1 . 16903 0.495 0.827 4528

- 250.000 209.670 26.090 0.03833 120.406 2384. 03 129.06 131.74 1. 20971 0.491 0.838 4342

- 240.000 219. 670 25.575 0.03910 111.626 2130.50 137.43 140.15 1.24898 0.485 0 . 848 4157

- 230.000 229.670 25.041 0.03993 103.216 1889.98 145.90 146.68 1.28701 0.478 0.861 3969

• 220.000 239.670 24.482 0.04035 95.122 1662. 13 154.52 157.35 1.32401 0.473 0.876 3776

- 210.000 249.670 23.894 0. 04185 87.295 1446. 19 163.31 166.22 1.36023 0.470 0.897 3575

- 200.000 259.670 23.272 0.04297 79.602 1241. 06 172. 33 175.31 1.39595 0.469 0.923 3364

- 190.000 269.670 22.607 0.04423 72.224 1045.48 181.63 184.70 1.43142 0.468 0.955 3146

- 180.000 279.670 21.885 0.04569 64.351 858. 06 191.27 194.44 1.46687 0.464 0.994 2916

• 170.000 289.670 21.086 0.04742 57.462 677.41 201,33 204.63 1.50265 0.458 1.046 2678

- 160.000 299.670 20. 172 0. 04957 49.389 502. 02 212. 00 215.45 1.53937 0.449 1.125 2414

- 150.000 309.670 19.058 0.05247 41.796 329.64 223.72 227.36 1.57847 0 . 442 1.279 2102

• 148.418 311.252 18.852 0. 05304 40.422 302.37 225.72 229.40 1.58499 0.448 1 . J 25 2035

- 148.418 311.252 2.7802 0. 3597 2.5627 69.65 333.49 358.46 1.99970 0.459 1.162 904

- 140. 000 319. 670 2.5282 0.3955 2.2254 69.77 339.75 367.22 2.02746 0.437 0.948 950

- 130.000 329.670 2.3175 0.4315 1.9694 106.98 346.07 376.03 2.05462 0.423 0.828 994

• 120.000 339.670 2.1574 0.4635 1.7877 125.49 351.75 383.94 2. 07825 0.414 0.759 1032

- 110.000 349.670 2.0283 0.4930 1.6480 140. 26 357. 04 391.28 2. 09956 0.406 0 . 713 1065

- 100.000 359.670 1.9201 0.5208 1.5356 153.89 362.08 398.24 2.11920 0.404 0.681 1096

-90.000 369.670 1.8272 0.5473 1.4422 166.62 366.93 404.93 2.13754 0.401 0.657 1124

- 80. 000 379.670 1.7460 0.5727 1.3627 178. 65 371,64 411.41 2.15483 0.399 0.639 1151

-70.000 389.670 1.6740 0. 5974 1.2939 190.13 376.24 417.72 2 . 17124 0 . 398 0.624 1176

-60.000 399.670 1.6094 0.6214 1.2334 201.15 380.76 423.91 2.18692 0.397 0.613 1200

- 50.000 409.670 1.5510 0.6448 1.1797 211.78 385.22 429.99 2.20195 0 . 396 0.604 1222

- 40.000 419.670 1.4977 0.6677 1.1316 222.09 389.62 435.99 2.21641 0. 396 0.596 1244

- 30. 000 429.670 1.4488 0.6902 1.0881 232.11 393.99 441.91 2. 23037 0.397 0.590 1265

- 20.000 439.670 1.4038 0.7124 1.0485 241.89 398.32 447.79 2.24336 0. 397 0.585 1285

- 10.000 449.670 1.3620 0.7342 1.0122 251.45 402.63 453.62 2.25699 0.396 0.581 1304

0.000 459.670 1.3231 0.7558 0.9789 260.61 406.93 459.41 2.26974 0.399 0.578 1323

10.000 469. 670 1. 2868 0. 7771 0.9481 270. 01 411.21 465.18 2.28214 0.401 0.575 1341

20. 000 479.670 1.2528 0.7982 0.9194 279. 05 415.49 470.92 2.29425 0.402 0.574 1358

30. 000 489.670 1.2208 0.8191 0.8928 287. 94 419.77 476.65 2.30607 0.404 0.572 1375

40. 000 499.670 1.1907 0.8398 0.8678 296.72 424.05 482.37 2.31763 0.406 0.572 1391

50. 000 509.670 1.1623 0. 8604 0.8445 305.37 423.34 486.08 2. 32895 0.408 0.571 1407 60.000 519.670 1.1354 0.8808 0.8225 313.92 432.64 493.80 2. 34005 0.411 0.571 1423 70.000 529.670 1.1099 0.9010 0.8018 322. 37 436.95 499.51 2.35095 0.413 0.572 1438

80.000 539.670 1.0856 0.9212 0.7823 33 P .73 441.27 505.24 2 . 36165 0.416 0.573 1453

100. 000 559.670 1.0405 0.9611 0.7463 347.21 449.98 516.72 2. 38254 0.422 0.575 1481 120.000 579.670 0.9994 1. 0006 0.7138 363. 39 456.78 528.26 2.40280 0.428 0.579 1509

140.000 599.670 0.9618 1.0397 0.6843 379. 33 467.68 539.68 2.42251 0.435 0.583 1935

160.000 619.670 0.9271 1.0786 0.6574 395.05 476.70 551.60 2 . 44174 0.443 0.589 1560

180. 000 639.670 0.8951 1.1172 0.6327 410.58 485.86 563.43 2.46053 0.451 0.595 1585

200. 000 659.670 0.8654 1.1555 0.6099 425.93 495.15 575.39 2.47894 0.459 0.601 1606

220.000 679.670 0.8377 1.1937 0.5869 441.13 504.60 587.49 2.49701 0.467 0.608 1631 240.000 699.670 0.8119 1.2316 0.5693 456. 19 514.21 599.73 2. 51475 0.476 0 . 616 1653

280.000 739.670 0.7651 1.3070 8.5341 485.95 533.91 624.68 2.54942 0.494 0.632 1696

320.000 779.670 0.7236 1. 3819 0.5033 515. 31 554.32 650.28 2.58313 0.513 0.649 1737

360. 000 819.670 0.6867 1.4563 0.4760 544. 32 575.44 676.57 2.61600 0.532 0.666 1777 400.000 859.670 0.6535 1.5303 9.4516 573. 05 597.30 703.56 2.64815 0.551 0.684 1815

440.000 899.670 0.6235 1.6039 0.4298 601.53 619.88 731.26 2.67965 0.570 0.701 1852

235
METHANE ISOBAR AT P S 400.0 PSI

T T OEN VOL OP/DT DP/00 E H S CV CP M DEG F OEG R LB/CUf

T

CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

295.161 164. 469 20.245 0.03541 166.272 3675.17 93.33 95.95 1.01295 0.496 0.763 5165

290.000 169.670 26.006 0.03571 160.403 3518. 36 97.21 99.65 1.03741 0.495 0.787 5095

260.000 179.670 27.546 0.03630 149.592 3223.26 104.65 107.54 1.06285 0.496 0.800 4910

270.000 169.670 27.077 0.03693 139.378 2935. 37 112.72 115.46 1.12656 0.497 0.814 4720

260. 000 199.670 26.596 0.03760 129.705 2657.55 120.79 123.56 1. 16671 0.496 0.826 4531

250.000 209.670 26. 100 0.03631 120.514 2391.56 129.01 131.65 1.20936 0.491 0.837 4346

240.000 219.670 25.567 0.03908 111.749 2138. 36 137.35 140.25 1.24861 0.485 0.846 4162

230.000 229.670 25.054 0.03991 103.355 1896. 19 145. 61 146.77 1. 28660 0.479 0.660 3975

220.000 239.670 24.497 0.04062 95.276 1670.66 154.41 157.44 1.32356 0.474 0.875 3703

210.000 249.670 23.912 0.04162 87.470 1455. 12 163. 19 166.29 1.35975 0.471 0.396 3562

200.000 259.670 23.292 0.04293 79.660 1250.42 172.19 175.37 1.39541 0.469 0.921 3373

190.000 269.670 22.631 0. 04419 72.451 1055. 36 161.46 164.74 1.43079 0.466 0.953 3156

160.000 279.670 21.914 0. 04563 65. 113 660.60 191. 07 194.45 1.46615 0.464 0.991 2930

170.000 269.670 21.123 0.04734 57.773 688.60 201.09 204.59 1.50176 0.456 1.040 2693

160.000 299.670 20.221 0.04945 50.276 514.56 211.68 215.34 1.53625 0.449 1.115 2434

150.000 309.670 19.132 0.05227 42.321 344.01 223.24 227.11 1.57689 0.442 1.257 2130

145. 075 314.595 16.474 0.05413 36.026 260. 16 229.60 233.61 1.59766 0.449 1.398 1937

145. 075 314.595 3.0193 0.3312 2.6336 64.11 332.63 357.16 1.99043 0.466 1.266 899

140.000 319.670 2.6266 0.3536 2.5650 77. 64 336.64 363.05 2.00900 0.449 1.075 929

130.000 329.670 2.5574 0.3910 2.2223 99.50 343.60 372.77 2.03895 0.430 0. 893 979

120.000 339.670 2.3633 0.4231 1.9941 117.44 349.85 361.19 2.06414 0.419 0.300 1019

110.000 349.670 2.2111 0.4523 1.6247 133.23 355.39 366.69 2.06647 0.412 0.743 1055

100.000 359.670 2.0659 0.4794 1.6913 147.59 360.61 396.11 2.10684 0.407 0.704 1067

-90.000 369.670 1.9799 0.5051 1.5621 160.91 365.59 403.00 2.12573 0.404 0.675 1117

-60.000 379.670 1.6660 0.5297 1.4902 173.43 370.41 409.64 2.14346 0.401 0.654 1144 -70.000 309.670 1.6072 0.5534 1.4114 165. 32 375.10 416.09 2.16023 0.399 0.637 1170

-60. 000 399.670 1.7351 0.5763 1.3426 196.69 379.70 422.39 2.17619 0.396 0.624 1194

-50.000 409.670 1.6702 0.5987 1.2619 207. 64 364. 22 426.57 2. 19147 0.396 0.613 1218 -40.000 419.670 1.6113 0.5206 1.2278 216.22 366.69 434.66 2.20614 0.397 0.604 1240

-30.000 429.670 1.5574 0.6421 1.1790 226.49 393.10 440.66 2.22028 0.396 0.597 1261 -20.000 439.670 1.5076 0.6632 1.1346 236.50 397.46 446.60 2.23395 0.398 0.591 1281 -10.000 449.670 1.4620 0.6640 1.0945 246. 26 401.63 452.49 2.24720 0.399 0.567 1301 0.000 459.670 1.4195 0.7045 1.0574 257.62 406. 16 456.34 2.26007 0.400 0.583 1320

10.000 469.670 1.3799 0.7247 1.0233 267.18 410.46 464.16 2.27258 0.401 0.560 1338

20.000 479.670 1.3426 0.7447 0.9917 276. 36 414.79 469.95 2.26479 0.403 0.578 1356

30. 000 469.670 1.3001 0.7645 0.9623 285.43 419. 10 475.72 2.29670 0.405 0.576 1373

40.000 499.670 1.2753 0. 7841 0.9349 294. 34 423.40 461.46 2.30834 0.407 0.575 1369

50.000 509.670 1.2445 0.6036 0.9092 303. 13 427.72 467.23 2. 31974 0.409 0.575 1406

60.000 519.670 1.2153 0.8226 0.6051 311.80 432.04 492.96 2.33090 0.411 0.575 1421

70. 000 529.670 1. 1676 0. 6420 0.6625 320.37 436.37 496.73 2.34186 0.414 0.575 1437

60.000 539.670 1. 1614 0.8610 0.6411 326.64 440.71 504.49 2.35262 0.416 0.576 1451

100.000 559.676 1. 1127 0. 8967 0.8016 345.52 449.45 516.02 2.37361 0.422 0.576 1460 120.000 579.670 1.0664 0.9360 0.7664 361.69 456.26 527.61 2. 39396 0.429 0.561 1506

140. 000 599.670 1. 0276 0. 9730 0.7343 377.99 467.21 539.28 2.41375 0.436 0.586 1534

160. 000 619.670 0.9905 1.0096 0.7050 393. 66 476.26 551.04 2.43304 0.443 0.591 1560

160.000 639.670 0.9561 1.0460 0.6762 409.52 465. 44 562.91 2.45189 0.451 0.597 1564

200.000 659.670 0.9242 1.0821 0.6536 425.00 494.76 574.90 2.47035 0.459 0.603 1606

220. 000 679.670 0.6945 1.1160 0.6306 440. 32 504.22 567.03 2.46646 0.466 0.610 1631

240.000 699.670 0.6666 1.1537 0.6097 455.49 513.05 999.30 2.50625 0.476 0.617 1653

260.000 739.670 0.6166 1.2246 0.5717 465.44 533.59 624.30 2.54099 0.495 0.633 1696

320.000 779.670 0.7722 1.2950 0.5364 514. 96 554. 02 649.94 2.57476 0.513 0.650 1736

360.000 619.670 0.7326 1.3650 0.5090 544. 12 575.17 676.27 2.60768 0.532 0.667 1777 400.000 659.670 0.6971 1.4345 0.4628 572.97 597.04 703.30 2.63967 0.551 0.664 1616

440. 000 699.670 0.6650 1.5037 0.4593 601.57 619.65 731.03 2.67140 0.570 0.702 1653

236
ME T HANE ISOBAR AT P = <*40.0 PSI

T T DEN VOL OP/OT OP/OD E H S CV CP H OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/L8 8TU/LB BTU/LB 8TU/LB/R BTU/LB/R BTU/LB/R FT/S

295.055 164.615 28.250 0.03540 166.201 3680.36 93.35 96.24 1.01312 0.496 0.783 5186

290.000 169.670 28.018 0.03569 160.487 3527.61 97.13 100.04 1. 03698 0.495 0.787 5098

200. 000 179.670 27.559 0. 03629 149.699 3233.37 104.77 107.72 1. 08240 0.496 0.800 4914

270.000 189.670 27.091 0.03691 139.507 2946. 21 112.64 115.64 1.12608 0.497 0.313 4725

260.000 199.670 26.611 0.01758 129.855 2669.02 120.69 123.75 1.16820 0.496 0. 326 4538

250.000 209.670 26.117 0.03829 120.687 2403.62 128. 90 132. 02 1.20882 0.491 0.836 4353

240.000 219.670 25.606 0.03905 111.945 2150.94 137.22 140.41 1.24802 0.485 0.847 4170

230. 000 229.670 25.075 0.03988 103.575 1911.27 145.67 148.92 1.28596 0.479 0.859 3984

220.000 239.670 24.521 0. 04078 95.526 1684. 30 154.25 157.57 1.32286 0.474 0.874 3793

210.000 249.670 23.939 0.04177 07.749 1469. 33 163. 00 166.40 1. 35897 0.471 0. 394 3594

200.000 259.670 23.324 0.04287 80.194 1265. 32 171.97 175.46 1. 39454 0.469 0.919 3387

190. 000 269.670 22.668 0.04411 72.808 1071. 07 181.20 184.80 1.42961 0.468 0.949 3172

ISO. 000 279.670 21.960 0.04554 65.526 885. 32 190.75 194.47 1.46500 0.465 0.986 2949

170.000 289.670 21.180 0. 04721 58.261 706. 81 200.70 204.54 1.50040 0.458 1.032 2716

160.000 299.670 20.297 0.04927 50.877 534. 31 211.17 215.18 1.53651 0.449 1.101 2465

150.000 309.670 19.245 0.05196 43.121 366. 39 222.52 226.75 1.57447 0.441 1.227 2173

140.0 32 319.638 17.852 0.05602 34. 363 200.21 235.73 240.29 1.61744 0.452 1.547 1782

140. 032 319. 638 3.4315 0. 2914 3.3172 55.04 330.94 354.68 1.97536 0.478 1.483 889

140.000 319.670 3.4296 0.2916 3.3143 55. 15 330.97 354.73 1.97551 0.478 1.480 890 130.000 329.670 2.9962 0.3338 2.7092 83. 02 339.69 366.86 2.01297 0.444 1.045 952 120.000 339.670 2.7249 0. 3670 2.3714 103.92 346.54 376.44 2. 04155 0.426 0. 886 999

110. 100 349. 670 2.5251 0.3960 2.1386 121.59 352.57 384.84 2.06592 0.418 0.800 1038

100.000 359.670 2.3668 0.4225 1.9629 137. 30 358.12 392.55 2.08766 0.412 0.746 1073

-90. 000 369.670 2.2359 0.4473 1.8230 151. 66 363.36 399.80 2. 10 756 0.406 0.708 1105

-80.000 379.670 2.1244 0.4707 1.7077 165. 02 368. 38 406.73 2. 12606 0.404 0.680 1134

-70.000 389.670 2.0276 0.4932 1.6103 177.61 373. 24 413.42 2.14344 0.402 0.658 1161 -60.000 399.670 1.9422 0.5149 1.5264 189.58 377.97 419.92 2.15991 0.401 0.642 1186

-50.000 409.670 1.8659 0.5359 1.4531 201. 04 382.60 426.27 2.17560 0.400 0.629 1210 -40.000 419.670 1.7972 0.5564 1.3882 212. 08 387. 16 432.50 2. 19063 0. 399 0. 618 1233

-30.000 429.670 1.7347 0 0.5765 1.3302 222.76 391.66 436.63 2.20507 0.399 0.609 1255 -20.000 439.670 1.6775 0.5961 1.2779 233. 13 396.12 444.69 2.21901 0.400 0.602 1276

-10.000 449.670 1.6248 0.6155 1.2304 243.23 400.54 450.68 2.23248 0.400 0.597 1296 0.000 459. 670 1.5761 0. 6345 1.1870 253. 09 404.93 456.62 2. 24555 0.401 0.592 1315 10.000 469.670 1.5309 0.6532 1.1472 262.73 409. 30 462.52 2.25825 0.402 0.588 1334 20.000 479.670 1.4887 0.6717 1.1105 272. 19 413.66 468.39 2.27062 0.404 0.585 1352

30.000 489. 670 1.4492 0.6900 1.0764 281.48 418.01 474.23 2.28267 0.406 0.583 1370 40.000 499.670 1.4121 0.7082 1.0447 290. 61 422.36 480. 06 2.29445 0.407 0.582 1386

50.000 509.670 1.3772 0.7261 1.0152 299.61 426.71 485.87 2.30596 0.410 0.581 1403

60. 000 519.670 1.3443 0. 7439 0.9875. 308.48 431.07 491.68 2. 31724 0.412 0.580 1419

70. 000 529.670 1.3131 0.7615 0.9615 317.23 435.43 497.48 2.32830 0.414 0.580 1434

00. 000 539.670 1.2836 0. 7791 0.9370 325. 67 439.81 503.26 2.33916 0.417 0.580 1450 100.000 559.670 1.2289 0.8137 0.8921 342.87 448.61 514.91 2. 36031 0.423 0.582 1479

120.000 579.670 1.1793 0.8480 0.6518 359.53 457.49 526.58 2.36079 0.429 0.565 1507

160.000 599.670 1.1339 0.8819 0.8154 375. 69 466.46 538.32 2.40070 0.4 36 0.589 1533

160. 000 619. 670 1.0923 0. 9155 0.7823 392.00 475.55 550.14 2.42010 0 . 444 0.594 1559

180.000 639.670 1.0539 0.9488 0.7521 407.88 484.77 562.07 2.43905 0.451 0.599 1584

200.000 659.670 1.0184 0.9819 0.7243 423. 56 494. 12 574.12 2.45760 0.460 0.606 1608

220.000 679.670 0.9854 1.0148 0.6986 439. 06 503. 62 586. 30 2.47578 0.468 0.612 1631

240. 000 699. 670 0.9547 1.0475 0.6749 454.40 513.27 598.61 2.49364 0.477 0.619 1654

280.000 739.670 0.8990 1.1123 0.6323 484.66 533. 07 623.69 2.52849 0.495 0.635 1697

320.000 779.670 0.8499 1.1766 0.5951 514. 44 553.54 649.41 2.56235 0.514 0 .651 1730 360.000 819.670 0.8062 1.2405 0.5622 543. 83 574.73 675.80 2. 59535 0. 533 0.668 1778

400.000 859.670 0.7669 1. 3039 0.5330 572.88 596.64 702.88 2.62761 0.552 0.686 1817

440. 000 899.670 0.7315 1.3670 0.5069 601. 65 619.28 730.66 2.65920 0.570 0.703 1854

237
METHANE ISOBAR AT P a 460.0 PSI

T T DEN VOL DP/DT OP/DO F H S cv CP w -25 DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 8TU/LB 8TU/L6 BTU/LB/R BTU/LB/R BTU/L9/R FT/S

-25 - 294. 928 164.742 28.255 0.03539 166.130 3685.54 93.38 96.52 1.01329 0.497 0.763 5186

-2< -290. 000 169.670 28.029 0.03568 160.570 3536. 82 97.06 100.23 1.03656 0.495 0.787 5102

-27 -260.000 179.670 27.571 0.03627 149.006 3243.44 104.69 107.91 1. 08195 0.496 0. 799 4919

- 28 -270. 000 189. 670 27.104 0.03689 139.635 2957.01 112.55 115.83 1.12561 0.498 0.813 4731

- 25 -260. 000 199. 670 26.626 0.03756 130.005 2680.46 120.59 123.93 1.16769 0.496 0. 825 4544

-24 -250.000 209.670 26.133 0.03827 120.859 2415.61 128.79 132.19 1.20827 0.492 0.836 4361

-23 -240.000 219.670 25.624 0.03903 112.139 2163. 46 137. 10 140.57 1.24743 0.486 0. 846 4178

-22 -230.000 229.670 25.096 0.03985 103.794 1924. 30 145.53 149.07 1.28533 0.479 0.857 3994

-21 -220. 000 239.670 24.544 0. 04074 95.771 1697.86 154.09 157.71 1.32217 0.474 0.872 3804

-2d -210.000 249.670 23.966 0. 04173 88.024 1483.46 162.81 166.52 1.35820 0.471 0.892 3606

-IS -200.000 251.670 23.356 0. 04282 80.504 1280. 12 171.75 175.56 1. 39368 0.470 0.916 3401

-la -190. 000 269.670 22.705 0.04404 73,161 1086.66 180.95 184.86 1.42883 0.468 0.945 3188

-17 -180. 000 279.670 22.005 0.04544 65.932 901.87 190.45 194.49 1.46387 0.465 0.981 2968

-16 -170.000 289.670 21.236 0.04709 58.738 724.58 200.32 204.50 1.49906 0.458 1.025 2740 -15 -160.000 294.670 20.371 0. 04909 51.459 553. 71 210.68 215. 04 1.53482 0.449 1.088 2494

- 14 -150. OOO 309.670 19.351 0.05168 43.878 388. 12 221.83 226.42 1.57217 0.441 1.200 2213

-140.000 319.670 18.035 0.05545 35.492 225.72 234.62 239.55 1.61 382 0.450 1.465 1846

-14 - 135. 318 324. 352 17.197 0.05815 30.361 148.69 241. 83 247.00 1.63696 0.457 1.758 1628

- 14 -13 - 135. 318 324. 352 3. 8905 0.2570 3.8781 45.72 328.80 351.65 1.95964 0.493 1.798 879 -12 -130. 000 329.670 3.5410 0.2824 3.3600 64. 10 334.61 359.72 1.96432 0.463 1.321 920 -11 -120.000 339.670 3.1392 0.3186 2.8266 89. 36 342.78 371.10 2.01835 0.438 1.009 976 -10 -110.000 344.670 2. 8716 0. 3482 2.4998 109. 42 349.49 300.44 2. 04547 0.425 0.874 1020

-9 -100. 000 359.670 2.6699 0.3745 2.2668 126.72 355.47 388.76 2.06894 0.417 0.796 1058

-a -90.000 369.670 2.5081 0. 3987 2.0878 142.25 361.01 396.45 2. 09003 0.412 0.745 1092

-7 -80.000 379.670 2.3733 0.4214 1.9437 156. 53 366.26 403.71 2. 10942 0.408 0.709 1123

-6 -70.000 369.670 2.2579 0.4429 1.0240 169. 87 371. 30 410.66 2.12749 0.405 0. 682 1151

-5 -60.000 399.670 2.1573 0.4636 1.7223 182. 48 376.18 417.38 2.14451 0.403 0.662 1178

-4 -50.000 409.670 2.0682 0.4835 1.6344 194.48 360.94 423.91 2.16065 0.402 0.645 1203

-3 -40. 000 419. 670 1.9886 0.5029 1.5572 206.00 385.60 430.30 2.17605 0.401 0.633 1227

-2 -30.000 429.670 1.9166 0. 5218 1.4887 217. 09 390.19 436.57 2.19062 0.401 0.622 1249

-1 -20.000 439.670 1.8510 0.5402 1.4274 227.84 394.73 442.75 2.20503 0.401 0.614 1271

-10. 000 449.670 1.7910 0.5584 1.3720 238. 27 399.22 448.85 2. 21875 0.402 0.607 1291

1 0.000 459. 670 1.7356 0.5762 1.3217 248.44 403.68 454.89 2.23203 0.402 0.601 1311

2 10.000 469.670 1.6844 0.5937 1.2756 258. 37 408.11 460.87 2. 24492 0.404 0.597 1330

3 20.000 479.670 1.6367 0.6110 1.2333 268. 08 412.52 466.82 2.25745 0.405 0.593 1349

4 30.000 489.670 1.5923 0.6280 1.1941 277.61 416.92 472.74 2.26966 0.407 0.590 1367

5 40.000 499. 670 1.5506 0.6449 1.1579 286.97 421.31 478.63 2.28157 0.408 0.588 1384

6 50. 000 509. 670 1.5115 0.6616 1.1241 296. 17 425.70 484.50 2.29321 0.410 0.587 1400

7 60.000 519.670 1.4746 0.6781 1.0925 305.23 430.09 490.37 2. 30460 0.413 0.586 1417

a 70.000 529.670 1.4398 0.6945 1.0630 314. 17 434.49 496.22 2. 31576 0.415 0.585 1433

10 80.000 539.670 1.4069 0.7108 1.0352 322.98 430.90 502.07 2.32671 0.418 0. 585 1448

12 100.000 559.670 1. 3460 0. 7429 0.9844 340. 30 447.76 513.79 2.34802 0.424 0.586 1477

14 120. 000 579. 670 1.2909 0.7747 0.9390 357.24 456.69 525.54 2.36666 0.430 0.589 1506

16 140.000 599.670 1.2406 0.8061 0.8980 373.86 465.71 537.35 2.38869 0.437 0. 592 1533

10 160.000 619.670 t . 1 946 0.8371 0.8609 390.20 474. 84 549.25 2.40620 0.444 0.597 1559

20 180. 000 639. 670 1.1522 0.8679 0.8270 406. 30 484. 09 561.24 2.42724 0.452 0.602 1584

22 200. 000 659.670 1.1130 0.8985 0.7959 422. 17 493.48 573.34 2.44567 0.460 0.608 1608

24 220. 000 679.670 1.0767 0.9288 0.7673 437. 85 503.01 585.57 2.46413 0.469 0.615 1631

20 240.000 694.670 1.0428 0.9589 0.7409 453. 36 512.69 597.93 2.48205 0.477 0. 622 1654

32 280. 000 739.670 0.9816 1. 0187 0.6935 483.91 532.54 623.09 2.51702 0.495 0.637 1697

36 320.000 779.670 0.9277 1. 0779 0.6522 513.95 553.07 648.88 2.55097 0.514 0.653 1739

40 360.000 819.670 0.8797 1.1367 0.6159 543.56 574.30 675.33 2.56405 0.533 0.670 1779

44 400. 000 859.670 0.0368 1.1951 0.5836 572. 81 596.24 702.47 2.61638 0.552 0.667 1818

440. 000 899.670 0.7900 1.2531 0.5547 601.75 618.92 730.30 2.64802 0.571 0.705 1855

238
METHAWE ISOBAR AT P * 520.0 PSI

T T OEN wot OP/DT DP/OO E H S CV CP W OEG F D£6 R LS/CUF? CUP? /LB PSI/R PSJCUFT/LB BTU/te 8TU/L8 BTU/L8/R 0TU/L0/R 0TU/L3/R PT/S

- 294.802 164.368 28.261 0 . 0353 ® 166.059 3690.71 93.40 96.81 1.01346 0.497 0.783 5189

- 290.000 169 . 67 ® 28 . 04 ® led 3566 160.653 3546.00 96.99 100.42 1 . 03613 0.496 0. 786 5186

- 200. 000 179.670 27.583 O « 0 3625 149.911 3253.48 104.61 108.10 1.08150 0.497 0.799 4923

- 270.000 189.670 27. 118 0.03688 139.762 2967.77 112.46 116.01 1.12513 0.498 0.812 4736

- 260.000 198.670 26.641 0. 03754 130. 154 2691. 85 120. 49 124.11 1. 16719 0.497 0.824 4550

- 250.000 209.670 26. 150 0.03824 121.029 2427.56 128.67 132.36 1.20773 0.492 0 . @35 436®

- 240.000 219.670 25.643 0.03900 112. 332 2175. 94 136.97 140.73 1.24685 0.4 86 0.843 4186

- 230.000 229.670 25.116 0.03981 104.010 1937.28 145 . 3 ® 149.22 1.28469 0.480 0.056 4003

- 220.000 239.670 24. 560 0.04070 96. 014 1711. 36 153.92 157.84 1.32148 0.475 0.871 3814

- 210.000 249.670 23.993 0.94168 88.296 1497.53 162.63 166.64 1.35744 0.472 0.890 361 ® - 200.000 259.670 23.387 0.04276 80.611 1294. 82 171.54 175.65 1.39283 0.470 0.914 3414

- 190.000 269.670 22.742 0.04397 73.508 1102.12 180.69 184.93 1.42787 0.469 0.942 3204

- 180. 000 279.670 22. 049 ®o 04535 66. 331 918.26 110.15 194.51 1.46276 0.465 0.976 2987

- 170.000 289.670 21.291 0.04697 59.205 742. 13 199.95 204.47 1.49774 0 . 45 ® 1.017 2762

- 160.000 299.670 20.442 0.04892 52.022 572.76 210.21 214.92 1.53319 0.449 1.076 2523

- 150.000 309.670 19.451 0.05141 44.600 409.20 221.18 226.13 1.56999 0.440 1.177 2291

- 140. 000 319.670 18.203 0. 09694 36.541 250.42 233.57 238.86 1.61040 0.446 1.400 1905

- 130.893 328.777 16.488 0.06065 27.469 104. 80 249.04 253.88 1.65668 0.465 2 . 07 $ 1472

- 130.893 328.777 4.4147 0.2265 4.5459 36 . 21 326 . 10 347.91 1.94272 0.511 2.293 86 0

- 130.000 329.670 4.3103 0. 2320 4.3783 40.43 327.91 349.85 1.94860 0.500 2 . 056 87 8 - 120.000 339.670 3.6315 0.2754 3.3964 73.36 338.37 364.88 1.99359 0.452 1.203 951

- 110.000 349.670 3.2602 0.3067 2.9229 96.57 346.07 375.60 2.02471 0.434 0.973 1002

- 100.000 359.670 3.0000 0.3333 2.6103 115.70 352.61 384.71 2.05039 0.423 0.859 1043

-90.000 369.670 2.7992 0. 3572 2.3604 132. 65 358.52 392.92 2. 07293 0.416 0.789 10®®

- 80.000 379.670 2.6361 0. 3794 2.2005 147.95 364. 04 400.57 2.09334 0.411 0.743 1112

- 70.000 389.670 2.4989 0.4002 2.0540 162. 10 369.28 407.82 2 . 11218 0.408 0.709 1162

- 60.000 399.670 2.3808 0.4200 1.9313 175.37 374.33 414.77 2.12901 0.406 0.683 1170

- 50. 000 400.670 2. 2774 0. 4391 1.6265 187.95 379.22 421.50 2.14644 0.404 0.664 1196

-40.000 419.670 3.1856 0.4575 1.7353 199.95 384. 00 428.06 2.16226 0.403 0. 648 1220

- 30.000 429.670 2.1032 0.4755 1.6551 211.40 386.70 434.48 2 . 17737 0.403 0.636 1244

- 20.000 439.670 2.0287 0.4929 1.5036 222.61 393.32 440.78 2.19187 0.403 0.626 1266

- 10. 000 449.670 1.9606 0. 9100 1.5195 233.39 397.88 446.99 2.20584 0.403 0.617 1237

0 . 000 459.670 1.3982 0.9260 1.4614 243. 67 402.40 453.13 2.21934 0.404 0.611 1307

10.000 469.670 1.8405 0. 5433 1.4066 254.08 406. 89 459.21 2.23243 0.405 0.603 1327

20.000 479.670 1.7871 (8. 3596 1.3601 264.06 411.36 465.24 2.24513 0 . 4 OS 0.681 1346

30. 000 439. 67 ® 1. 7374 S. 5796 1.3155 273.82 415.81 471.23 2.25749 0 . 40 ® 0. 597 1364

40.000 499.670 1.6909 0.5914 1.2743 283.40 420.24 477.19 2. 26954 0.409 0.599 1331

50.000 509.670 1.6473 0.6070 1.2360 292.82 424.68 483.13 2.28131 0.411 0.593 1398

60.000 919.670 1.6064 0.6225 1.2004 302.07 429. 11 489.05 2.29281 0.414 0.591 1415

70. 000 529.670 1 . 567 ® 0.6379 1.1670 311. 19 433.54 494.96 2.30408 0.416 0.591 1431

80.000 539.670 1.5313 0.6530 1.1356 320.17 437.90 500.86 2.31512 0.419 0.590 1446

100.000 559.670 1.4640 0.6831 1.0787 337.80 446 . 9 ® 512.67 2.33360 0.424 0.591 1476

120.000 579.670 1.4032 0. 7127 1.0278 355. 03 455. ®e 524.51 2 . 35738 0. 431 0.593 1595

140.000 599.670 1.3479 0.7419 0.9021 371.90 464.96 536.39 2.37754 0.437 0.596 1532

160. 000 619.670 1.2973 0.7708 0.9407 388.47 474. 13 548.35 2.39715 0.445 0.600 1550

180. 000 639.670 1.2508 0.7995 0.9031 404.77 483.42 560.40 2.41629 0.453 0.605 1503

200.000 659.670 1.2079 0.8279 0.6686 420. 04 492.84 572.56 2.43501 0 . 461 0.611 1698

220. 000 679.670 1.1681 0. 8561 0.8369 436.78 502.41 584.84 2.45334 0.469 0.617 1631

240. 000 699.670 1. 1312 0.8841 0.0076 452. 37 512.12 597.24 2.47133 0.478 0.624 1654

200.000 739.670 1.0643 0. 9395 0 .7553 483.21 532. ®2 622.49 2.50641 0.496 0.639 169 ® 320.000 779.670 1.0056 0.9945 0.7099 513.90 552.59 § 48.35 2 • §4046 0.514 0.655 1740

360.000 819.670 0.9533 1.0690 0.6699 543.33 573.36 674.86 2.57362 0,533 0.671 1760

400.000 859.670 0.9066 1.1030 0.6345 572.77 595.84 702.05 2.60601 0.552 0 . 68 ® 1819

440. 000 899.670 0.8645 1 . 156 ® 0 . 602 ® 601 . 0 ® 618.55 729.94 2.63770 0.571 0.706 imo,

23 $
METHANE ISOBAR AT P * 560.0 PSI

-29 T T GEN VOL OP/DT DP/OD E H S CV CP H -29 OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB 8TU/LB/R BTU/LB/R BTU/LB/R FT/S

-20 -294.675 164.995 28.266 0.03538 165.988 3695. 86 93.42 97.09 1.01364 0.497 0.782 5190

«27 -290.000 169.670 28.051 0.03565 160.735 3555. 14 96.92 160.62 1. 03570 0.496 0.706 5110

-26 -280. 000 179.670 27.596 0.03624 150.016 3263.48 104.53 108.29 1.08105 0.497 0.790 4928

-25 -270.000 189.670 27.131 0.03686 139.889 2978.50 112.37 116.19 1.12466 0.498 0.612 4741 -24 -260.000 199.670 26.656 0.01752 130.301 2703. 2® 120.4® 124.29 1.16663 0.497 0.824 4556

-23 -250.000 209.670 26.166 0.03822 121.198 2439.68 128.56 132.53 1.20719 0 o 493 0. 834 4375

-22 -240.000 219.670 25.661 0.01897 112.524 2188.36 136.85 140.89 1.24627 0.486 0.344 4194

-21 -230.000 229.670 25.137 0.03978 104.225 1950. 20 145.24 149.37 1.28407 0.400 0.855 401?

-20 -220. 000 239.670 24.591 0.04067 96.255 1724. 80 153.76 157.98 1.32079 0.475 0.869 3024

-19 -210.000 249.670 24.020 0. 04163 88.566 1511.52 162. 44 166.76 1.36668 0. 472 0.608 3629

-10 -200.000 259.670 23.417 0.04270 81.114 1309.45 171.32 175.76 1.39199 0.470 0.911 3427

-17 -190.000 269.670 22.778 0.04390 73.851 1117.47 180.45 185.00 1.42692 0.469 0.939 3219

-16 -180.000 279.670 22.092 0.04527 66.722 934.50 189.85 194.54 1.46167 0.466 0.971 3005

-15 -170.000 289. 670 21.344 0. 04685 59.661 759.46 199.59 204.44 1.49645 0.459 1.011 2704

- 14 -160.000 299.670 20.510 0.04876 52.569 591.50 209.75 214.80 1.53160 0.449 1. 065 2550

-150.000 309.670 19.546 0.05116 45.289 429.93 220.56 225.86 1.56790 0.440 1.156 2207

-14 - 140. 000 319.670 18.356 0.05448 37.505 274.03 232.62 238.27 1.60727 0.447 1. 348 1950

-14 -130.000 329.670 16.622 0. 06016 28.238 120.90 247.67 253.91 1.65541 0.461 1.919 1526

-13 -126.723 332.947 15.696 0.06371 24.128 67.97 254.53 261.13 1.67720 0.479 2.622 1313

-12

-11 -126.723 332.947 5.0354 0.1986 5.3703 26.62 322.62 343.21 1.92377 0.535 3.169 055

-10 -120.000 339.670 4.2551 0.2350 4.1698 55. 31 332. 86 357.23 1.96549 0. 473 1.565 921

-9 -110. 000 349.670 3.7065 0.2698 3.4309 82.91 342.19 370.17 2.00307 0.444 1.113 901

-a -100.000 359. 670 3.3635 0.2973 3.0030 104.43 349.50 380.33 2.03173 0.430 . 0.938 1028

-7 -90. 000 369.670 3. 1125 0. 3213 2.7058 122.82 355.87 389.19 2.05604 0.421 0.84? 1067

-6 -80.000 379.670 2. 9147 0. 3431 2.4810 139. 24 361.71 397.29 2.07766 0.415 0.781 1102

-5 -70.000 389.670 2.7518 0. 3634 2.3020 154.27 367.19 604.87 2.09738 0.411 0.738 1133

-A -60.000 399.670 2.6137 0.3826 2.1547 168.26 372.42 412.10 2.11568 0.408 0.707 1162

-3 -50.000 409.670 2.4940 0.4010 2.0302 181.43 377.47 419.04 2.13285 0.406 0.663 1189

-2 -40.000 419. 670 2. 3888 0.4186 1.9231 193.95 382. 37 425.78 2.14910 0.405 0.665 1214

-1 -30.000 429.670 2.2949 0.4357 1.8296 205.92 387. 17 432.35 2.16457 0.404 0.650 1238

-20.000 439.670 2.2105 0.4524 1.7469 217.44 391.88 438.79 2.17939 0.404 0.630 1261

1 -10.000 449. 670 2.1338 0.4666 1.6730 228.57 396.52 445.12 2.19362 0.404 0.620 1203

i 0. 000 459. 670 2. 0637 0. 4646 1.6066 239. 37 401.12 451.36 2.20736 0.405 0.620 1304

3 10.000 469.670 1.9993 0.5002 1.5463 249.87 405.67 457.53 2.22064 0.406 0.614 1323

t 20.000 479.670 1.9397 0.5155 1.4912 260.11 410.19 463.65 2.23352 0.407 0.609 1343

S 30.000 489.670 1.8844 0.5307 1.4407 270.12 414.69 469.72 2.24604 0.409 0.605 1361

( 40. 000 499.670 1. 8329 0.5456 1.3942 279.92 419. 17 475.75 2.25823 0.410 0.602 1379

3 50.000 509.670 1.7847 0.5603 1.3510 289.54 423,65 401.75 2.27013 0.412 0.599 1396

< 60.000 519.670 1.7395 0.5749 1.3110 298.99 428. 12 407.73 2.28175 0.414 0.597 1413

11 70.000 529.670 1.6969 0.5893 1.2736 308.29 432.59 493.70 2.29312 0.417 0.596 1429

i; 80. 000 539. 670 1.6568 0.6036 1.2386 317.44 437.06 499.65 2.30426 0.419 0.595 1445

i‘ 100.000 559.670 1.5828 0.6316 1.1750 335. 38 446. 04 511.56 2.32592 0.425 0.595 1475

li 120.000 579.670 1.5162 0.6595 1.1184 352. 88 455.00 523.47 2.34684 0.431 0.597 1504

it 140.000 599.670 1.4557 0 . 6 86 9 1.0676 370. 01 664.20 535. %3 2. 36712 0.438 0.599 1532

21 160. 000 619.670 1.4005 0.7140 1.0218 386.80 473.42 547.46 2.38685 0.445 0.603 1550

2J ieo. ooo 639.670 1.3496 0.7408 0.9802 403. 31 482.75 559.57 2.40608 0.453 0.600 1583

2* 200. 000 659.670 1.3031 0. 7674 0.9622 419.57 492.20 571.78 2.42488 0.461 0.613 1600

21 220.000 679.670 1.2599 0.7937 0.9073 435.60 501.80 584.11 2.44329 0. 470 0.619 1632

33 240.000 699.670 1.2197 0.8199 0.8752 451.42 511.5% 596.56 2.46134 0.478 0.626 1655

31 280.000 739.670 1.1472 0.8717 0.8178 482.56 531.49 621.89 2.49654 0.496 0.641 1699

41 320.000 779.670 1.0835 0.9230 0.7630 513. 09 552.11 647.82 2.53068 0.515 0.656 1741

4< 360.000 819.670 1. 0270 0. 9737 0.7244 543. 13 573.42 674.40 2.56392 0.5 34 0.673 1701

400.000 859.670 0.9764 1.0241 0.6857 572.76 595.4% 701.64 2.59637 0.553 0.690 1820 440.000 899.670 0.9309 1.0742 0.6512 602.04 616.18 729.57 2.62813 0.571 0.707 1858

240
METHANE ISOBAR 6! P » 600.0 PSI

T T OEM VOL DP/OT OP/OO F H S CV CP M OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BIO/LB BTU/IB BT0/18/R BTU/L B/R BTU/L0/R FT/S

294.549 165. 121 28.272 0.01537 165.917 3700.99 93,45 97.38 1.01381 0.498 0.782 5192

290.000 169.670 28.063 0.03563 160.817 3564. 24 96.85 100.81 1.03528 0,696 0.786 5113

280.000 179.670 27 . 60 ® 0.03622 150.121 3273.44 104.45 108.48 t o 08060 0.497 S. 79® 6932

270. 000 189 . 67 ® 27. 145 0.03684 140.014 2909.18 112.20 116 . 3 ® 1. 12419 0.499 0.811 4747

260.000 199.670 26.670 0.03749 130.448 2714.52 120.30 124.46 1.16618 0.497 0.823 4563

250.000 289.670 26.183 0.01619 121.366 2451.35 128.45 132,70 1.20666 0.493 0.833 4362

240.000 219.670 25.679 0.03894 112.714 2200.75 136.72 141.05 1.24569 0.487 0.843 4202

230.000 229.670 25.158 0.03975 104.439 1963.08 145.10 149.52 1.28344 0.460 0.854 4021

220.000 239 . 67 ® 24.614 0 . 04063 96.494 1738. 17 153.60 158.12 1.32011 0.475 0.868 3034

210.000 249.670 24.046 0.04159 88.833 1525.43 162.26 166.68 1.35594 0.472 0.886 3641 200.000 259.670 23.448 0.04265 61.414 1323.97 171. 11 175.05 1. 39116 0.471 0.909 3441

190.000 269.670 22.814 0.04383 74.189 1132,71 180.20 185.07 1.42599 0.469 0.936 3234

180.000 279.670 22.134 0.04518 67. 108 950.59 189.56 194.58 1.46060 0 • 466 0.967 3023

170.000 289.670 21.396 0.04674 60.107 776.60 199.23 204.42 1.49518 0.459 1.004 2806

160.000 299.670 20.577 0 . 0466 ® 53.100 609.95 209. 30 214.70 1.53006 0.449 1.055 2577

150.000 309.670 19.637 0.05092 45.950 450,11 219.96 225.62 1.56590 0.440 1.137 2322

140.000 319.670 18.496 0.05407 38.400 296.77 231.74 237.74 1.60437 0.446 1.305 2007

130.000 329.670 16.920 0.05910 29.775 148.35 245.91 252 . 4 ® 1.64974 0.456 1.726 1615

122.783 336. 887 14 . 76 ® 0.06775 20.750 37,7 3 261.62 269.15 1.69969 0.503 3.771 1145

122.783 336. 887 5.8136 0.1720 6.4467 17 , 14 317.95 337.06 1.90132 0.572 5.047 037 120.000 339.670 5.1641 0.1936 5.3851 33.64 325.00 346.51 1.92927 0.510 2.543 082 110.000 349.670 4.2367 0.2360 4.0632 68 . 26 337.66 363 .ee 1.97975 0.457 1.330 959 100.000 359.670 3.7698 0.2653 3.4587 92.62 346. 06 375.53 2.01261 0.438 1.043 1011

- 90.000 369.670 3.4522 0.2697 3.0704 112.77 353.03 385,21 2.03917 0.427 0.907 1054

• 80.000 379.670 3.2114 0. 3114 2.7887 130.42 359.25 393.85 2.06222 0.419 0.826 1091

- 70.000 389.670 3.0179 0. 3314 2.5703 146. 39 365. 01 401.82 2 . 08295 0.414 0.772 1124

-60.000 399.670 2. 8566 0.3501 2.3936 161. 13 370.45 409.34 2 . 10200 0.411 0.734 1154

- 50.000 409.670 2.7186 0.3678 2.2465 174.93 375.66 416.53 2. 11976 0.409 0.705 1102

- 40.000 419.670 2.5982 0. 1849 2.1212 187.98 380.70 423.46 2 . 1364 ® 0.407 0.683 1200

- 30. 000 429.670 2.4918 0. 4013 2.0127 200. 41 385.61 430.19 2 . 15234 0.406 0.665 1233

-20.000 439 . 67 ® 2.3966 0.4173 1.9175 212.34 390.41 436.77 2.16748 0.406 Q . to 51 1257

- 10.000 449.670 2.3106 0.4328 1.8330 223. 82 395. 14 443.23 2.18200 0.406 0.640 1279

0.000 459.670 2.2324 0.4479 1.7572 234.94 399.81 449. 5 ® 2.19597 0.406 0.631 1300

10. 000 469.670 2. 1607 0. 4628 1.6888 245.73 404.43 455.85 2.20946 0.407 0.623 1320 20.000 479.670 2.0947 0.4774 1.6266 256.24 409.01 462.05 2.22253 0.408 0.617 1340 30.000 489.670 2.0335 0.4918 1.5698 266.49 413.56 468.20 2.23521 0.410 0.612 1359

40. 000 499.670 1.9767 0.5059 1.5179 276.52 410.09 474 , 3 ® 2.24755 0.411 0.606 1377

50.000 509.670 1.9236 0.5199 1.4692 286.34 422.61 480.37 2.25957 0 . 413 0.605 1394

60. 000 519.670 1.8739 0.5336 1.4244 295.99 427.12 486.41 2.27131 0.415 0.603 1411

70. 000 529.670 1.8273 0.5473 1.3826 305.46 431.63 492.43 2.20279 0.418 0.601 1428

80.000 539.670 1.7833 0.5608 1.3439 314.79 436.14 498.44 2.29403 0.420 0.600 1444

100. 000 559.670 1.7025 0.5674 1.2732 333. 04 445 . 1 ® 510.44 2. 31506 0.426 0.600 1474

120. 000 579.670 1.6299 0.5135 1.2106 350.81 454.27 522.44 2. 33693 0.432 0.601 1504

140.000 599.670 1.5641 0.6393 1.1596 368. 18 463.44 534.47 2.35734 0,439 0.603 1531 160.000 619.670 1.5041 0.6666 1.1042 305.20 472 . 7 ® 546.57 2.37717 i .446 0.606 1558

180.000 639.670 1.4492 0.6900 1.0585 401.91 462. 07 558.74 2.39650 0.454 0.611 1584

200. 000 659.670 1.3986 0.7150 1.0169 418. 35 491.56 571 . 0 ® 2.41538 0.462 0.616 1606

220. 000 679.670 1.3518 0.7398 0.9787 434.55 501.19 503.30 2.43387 0.470 0.622 1632

240. 000 699.670 1.3084 0. 7643 0.9435 450.54 510.96 595.80 2.45199 0.479 0.628 1655

280.000 739.670 1.2301 0.8129 0.8809 481.95 530.97 621.29 2.48731 0.497 0.642 1699

320.000 779.670 1.1615 0.8610 0.8267 512.72 551.63 647.29 2.52154 0.515 0.658 1762

360.000 819.670 1.1006 0.9086 0.7793 542.98 572.99 673.93 2.59406 0.5 34 0.674 1702

400.000 859.670 1.0463 0.9556 0.7373 572.79 595.04 701.23 2.50737 0.553 0.691 1821

440. 000 899.670 9.9973 1. 0027 0.6999 602.23 817.81 729.21 2.61918 0.572 0.708 1859

241
ME THANE ISOBAR AT P * 650.0 PSI

T T OEM VOL OP/DT DP/OD E H S CV CP w DEG F DEG R L8/CUFT CUFT/LB PSI/R PSICUFT/LB 0TU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

294o392 165.278 28.278 0.03536 165.829 3707. 39 93.4® 97.74 1. 01402 0. 498 0. 782 5193

290.000 169.670 28.077 0.03562 160.916 3575.56 96.76 101.05 1.03475 0.497 0.785 5118

280. 000 179.670 27.623 0.03620 150.250 3285. 84 104.35 108.71 1.08005 0.496 0.797 4938

270. 000 189.670 27.161 0.03682 140.170 3002.49 112.17 116.60 1.12360 0.499 0.511 4753

260. 000 199.670 26.689 0. 03747 130.630 2728. 61 120.18 124.69 1.16556 0.498 0.822 4570

250.000 209.670 26.203 0.03816 121.575 2466. 15 128.32 132.91 1.20599 0.493 0.832 4390

240.000 219.670 25.702 0.03891 112.949 2216.16 136.57 141.25 1.24498 0.487 0.642 4212

230.000 229.670 25. 163 0.03971 104.703 1979.10 144.93 149.71 1.28267 0.481 0.852 4032

220. 000 239.670 24.643 0.04058 96.789 1754. 81 153.41 158.29 1.31926 0.476 0.866 3847

210.000 249.670 24.078 0.04153 89.164 1542.73 162.04 167.03 1.35501 0.473 0. 884 3655

200.000 259.670 23.405 0.04258 81.783 1342.01 170.85 175.98 1.39013 0.471 0.906 3457

190.000 269.670 22.857 0.04375 74.605 1151.60 179.90 185.16 1.42463 0.470 0.932 3253

180. 000 279.670 22. 166 0.04507 67.530 970.50 189.20 194.63 1.45927 0.466 0.961 3045

170.000 289.670 21.460 0.04660 60.653 797.75 198.60 204.41 1.49364 0.459 0.996 2832

160.000 299.670 20.657 0.04841 53.744 632.63 208.76 214.59 1.52819 0.449 1.043 2609

150.000 309.670 19.745 0.05064 46.741 474.76 219.26 225.35 1.56351 0.440 1. 116 2363

140. 000 319. 670 18.657 0.05360 39.441 324. 15 230.71 237.17 1.60101 0.444 1.261 2064

130.000 329.670 17.223 0.05806 31.394 180.92 244.09 251.08 1.64363 0.452 1.573 1708

120.000 339.670 14.573 0.06862 20.469 40.82 264. 04 272.30 1.70713 0.499 3.538 1158

118. 163 341.507 13.052 0.07662 16.013 8.41 273. 17 282.39 1.73674 0.585 11.907 890 118.163 341.507 7.3075 0.1368 8.5906 5.28 308.44 324.91 1.66126 0.662 17.234 786 110.000 349.670 5.1007 0.1961 5.1507 48.30 330.46 354.06 1.94593 0.480 1.847 928

100.000 359.670 4.3597 0.2294 4.1491 77.25 341.16 368.77 1.98746 0.449 1.230 990 -90.000 369. 670 3.9229 0. 2549 3.5947 99. 69 349.15 379.83 2. 01781 0.434 1.010 1037

-80.000 379.670 3.6122 0.2768 3.2184 119. 23 355.98 389.30 2.04307 0.425 0.893 1077

-70.000 309.670 3.3716 0.2966 2.9378 136.47 362.14 397.84 2.06528 0.419 0.820 1113

-60.000 399.670 3. 1758 0.3149 2.7168 152.21 367.88 405. 78 2.08540 0.415 0.770 1145

-50. 000 409. 670 3. 0112 0. 3321 2.5361 166. 82 373. 32 413.29 2.10397 0.412 0. 734 1174 -40.000 419.670 2. 8696 0.3485 2.3845 180.56 378.55 420.49 2.12133 0.410 0.707 1201 -30.000 429.670 2.7457 0.3642 2.2546 193.59 383.61 427.45 2.13771 0.408 0.686 1227 -20.000 439.670 2.6357 0. 3794 2.1417 206.03 388.55 434.21 2.15329 0.408 0.669 1251 -10.000 449.670 2.5370 0. 3942 2.0422 217.97 393.39 440.83 2.16817 0.408 0.655 1274

0.000 459.670 2.4477 0.4085 1.9536 229.50 390.15 447.33 2. 16245 0.408 0.644 1296

10.000 469.670 2.3663 0.4226 1.8741 240.66 402.86 453.72 2.19622 0.409 0.635 1317

20.000 479.670 2.2916 0.4364 1.8022 251.50 407.51 460.04 2.20952 0.410 0. 628 1337

30. 000 489. 670 2. 2227 0.4499 1.7366 262.06 412.14 466.29 2.22242 0.411 0.622 1356

40.000 499. 670 2.1589 0.4632 1.6766 272.37 416.73 472.48 2.23494 0.412 0.617 1374

50.000 509.670 2.0994 0.4763 1.6214 282.45 421.30 478.64 2.24714 0.414 0.614 1392

60.000 519.670 2.0439 0.4893 1.5703 292. 34 425.87 484.76 2.25903 0.416 0.611 1409

70. 000 529.670 1.9919 0.5020 1.5229 302.04 430.42 490.85 2.27064 0.419 0.608 1426

80.000 539.670 1.9430 0. 5147 1.4788 311.58 434.98 496.92 2.28201 0.421 0.607 1442 100.000 559.670 1.8533 0.5396 1.3989 330. 20 444.10 509.04 2.30405 0.426 0.605 1474 120.000 579.670 1.7729 0.5640 1.3283 346. 32 453. 26 521.15 2. 32531 0.433 0. 606 1503

140.000 599.670 1.7003 0.5881 1.2655 365.99 462.49 533.23 2.34588 0.439 0.607 1531

160. 000 619.670 1.6343 0.6119 1.2090 383.29 471.80 545.45 2.36585 0.447 0.610 1558

180.000 639. 670 1.5739 0.6354 1.1580 400.25 481.22 557.70 2.38530 0.454 0.614 1584

200.000 659.670 1.5183 0.6586 1.1115 416.92 490.76 570.04 2.40429 0.462 0.619 1609

220.000 679.670 1.4670 0.6817 1.0691 433.33 500.43 582.48 2.42287 0.471 0.625 1633

240.000 699.670 1.4195 0.7045 1.0300 449.50 510.24 595.03 2.44108 0.479 0.631 1656

280. 000 739.670 1.3339 0.7497 0.9607 481.26 530.32 620.55 2.47653 0.497 0.645 1700

320.000 779.670 1. 2590 0. 7943 0.9008 512. 33 551.04 646.64 2.51086 0.516 0.660 1743

360.000 819.670 1.1927 0.8384 0.8485 542.84 572.44 673.35 2.54430 0.535 0.676 1783

400.000 859.670 1.1335 0.8822 0.8023 572.87 594.54 700.73 2.57689 0.553 0.693 1823

440.000 899.670 1.0803 0.9256 0.7612 602.51 617.35 728.76 2.60877 0.572 0.709 I860

Till

242
METHANE ISOBAR AT P * 700.0 PSI

T T DEN VOL DP/DT DP/DD E H S CV CP H OEC F OEG R L8/CUFT CUFT/LB PSI/R PSICUFT/L8 BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

294.234 165.436 26.281 0.03535 165.741 3713.76 93.51 98.09 1.01424 0.498 0.782 5195

290. 000 169.670 20.091 0.03560 161.018 3586. 82 96.67 101.29 1. 03422 0.497 0. 785 5122

260. 000 179.670 27.638 0.03618 150.378 3298.16 104.26 106.95 1.07949 0.498 0.797 4944

270.000 189.670 27.178 0.03679 140.325 3015.75 112.07 116.83 1.12301 0.500 0.810 4760

260.000 199.670 26.707 0.03744 130.811 2742.64 120.06 124.91 1.16494 0.498 0.822 4573

290.000 209.670 26.223 0.03813 121.781 2480. 87 128. 1@ 133.13 1.20533 0.494 0. 831 4399

240.000 219.670 25.724 0.03087 113.183 2231.51 136.42 141.46 1.24427 0.487 0. 640 4222

230.000 229.670 25.206 0.03967 104.965 1995. 05 144.76 149.90 1.28190 0.481 0.851 4043

220.000 239.670 24.671 0.04053 97.082 1771.36 153.21 158.47 1.31043 0.476 0.364 3859

210.000 249.670 24.111 0. 04148 89.490 1559.92 161.81 167.19 1.35409 0.473 0. 861 3669

200.000 259.670 23.522 0.04251 82.148 1359.91 170.60 176.11 1.30911 0.472 0.903 3473

190.000 269.670 22.900 0.04367 75.014 1170.33 179.60 135.26 1.42369 0.470 0.928 3272

100.000 279.670 22.237 0.04497 68.044 990.20 188.85 194.68 1.45798 0.466 0.956 3066

170. 000 289.670 21.521 0. 04647 61.185 818.61 198. 38 204.40 1.49213 0.459 0.989 2857

160.000 299.670 20.735 0.04623 54.368 654.92 208.24 214.49 1.52637 0.449 1. 332 2640

150.000 309.670 19.646 0.05038 47.496 498. 83 218.58 225.11 1.56122 0.440 1.096 2403

140.000 319.670 18.805 0.05318 40.411 350.55 229.77 236.66 1.59788 0.444 1. 223 2116

130. 000 329.670 17.479 0.05721 32.793 210.64 242,53 249.95 1.63879 0.449 1.468 1788

120. 000 339.670 15.418 0.06486 23.659 80.22 259.30 267.71 1.69181 0.473 2. 319 1350

110.000 349.670 6.461 0.15430 6.988 25.94 319.49 339.49 1.09962 0.522 3.423 888 100.000 359.670 5.084 0.19669 5.037 61.33 335.31 360.80 1. 95982 0. 464 1. 529 968

-90. 000 369.670 4.459 0.22424 4.217 86.79 344.31 373.80 1.99571 0.443 1.148 1021

-80. 000 379.670 4.053 0.24675 3.708 107.95 352.43 384.41 2.02383 0.431 0.976 1064

-70.000 369.670 3.752 0.26652 3.347 126.52 359.09 393.64 2. 04783 0.423 0.877 1102

-60.000 399.670 3.514 0.29455 3.070 143. 30 365. 18 402.07 2.06918 0.418 0.812 1136

-50. 000 409.670 3.316 0.30135 2.849 158.76 370.89 409.95 2.08867 0.415 0.767 1166

-40. 000 419.670 3.152 0.31722 2.666 173. 20 376.33 417.45 2.10674 0.412 0.733 1195

-30.000 429.670 3.009 0.33238 2.512 186.84 381.56 424.64 2.12370 0.411 0.707 1221 -20.000 439.670 2.662 0.34697 2.379 199. 81 386.64 431.61 2. 13973 0.410 0.687 1246

-10.000 449.670 2.769 0.36108 2.262 212.22 391.60 438.40 2.15500 0.409 0.671 1270 0.000 459.670 2.668 0.37479 2.159 224. 16 396.47 445.05 2. 16962 0.410 0.658 1292

10.000 469.670 2.576 0.38616 2.068 235.69 401.26 451.58 2.18367 0.410 0.648 1313

20.000 479.670 2.492 0.40124 1.985 246. 8? 406. 00 458.01 2. 19722 0.411 0.639 1334

30.000 409.670 2.415 0.41406 1.910 257.74 410.69 464.36 2.21033 0.412 0.632 1353

40.000 499.670 2.344 0.42665 1.341 266. 33 415.35 470.66 2.22305 0.414 0.626 1372

50. 000 509. 670 2.278 0.43905 1.779 278.67 419.99 476.90 2.23542 0.415 0.622 1390

60. 000 519.670 2.216 0.45127 1.721 288. SO 424.60 483.10 2.24747 0.417 0.618 1408

70.000 529.670 2.158 0.46332 1.667 298.73 429. 21 489.26 2. 25922 0.420 0.615 1425

60.000 539.670 2.104 0.47523 1.617 308.47 433.81 495.41 2.27071 0.422 0.613 1441 100.000 559.670 2.005 0.43867 1.528 327.48 443.01 507.65 2.29298 0.427 0.611 1473

120. 000 579.670 1.917 0.52166 1.449 345.93 452.24 519.86 2.31442 0.433 0.611 1503

140.000 599.670 1.837 0.54427 1.379 363. 91 461.53 532.08 2.33515 0.440 0.612 1531

160. 000 619.670 1.765 0.56656 1.316 381.47 470.91 544.34 2. 35526 0.447 0.614 1558

180.000 639.670 1.699 0.56857 1.259 398.68 480.38 556.67 2.37484 0.455 0.618 1584

200. 000 659. 670 1.638 0.61034 1.208 415.57 469.96 569.07 2.39393 0.463 0.623 1609

220.000 679.670 1.583 0.63189 1.161 432. 19 499.67 581.58 2.41260 0.471 0.628 1633

240.000 699.670 1.531 0.65324 1.118 448.55 509.52 594. 19 2. 43090 0.480 0.634 1657

260.000 739.670 1.436 0.69545 1.041 430.64 529.66 619.81 2.46650 0.498 0. 647 1702

320.000 779.670 1.357 0.73711 0.976 512.00 550.44 645.99 2.50096 0.516 0.662 1744 360.000 619.670 1.265 0.77631 0.918 542.76 571.90 672.78 2.53447 0.535 0.678 1785

400. 000 659.670 1.221 0.81912 0.868 573. 01 594.04 700.22 2.56715 0.554 0.694 1324

440.000 899.670 1.163 0.85961 0.823 602. 84 616. 90 728.32 2.59910 O'. 573 0.711 1862

243
METHANE ISOBAR AT P a 750.0 PSI

T T DEN VOL OP/OT OP/OD E H S CV CP H DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 8TU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

294.077 165.593 20.292 0.03535 165.653 3720. 11 93.54 93.45 1.01446 0.499 0.781 5196

290.000 169.670 28.105 0.03550 161.117 3598.03 96.59 101.53 1.03369 0.493 0.705 5127

200.000 179.670 27.654 0.03616 150.505 331C.47 104. 16 109.18 1.07694 0.499 0.796 4949

270. 000 109.670 27.195 0.03677 140.479 3026.94 111.96 117.07 1.12243 0.500 0.009 4766

260.000 198.670 26.725 0.03742 130.590 2756.62 119.94 125.13 1.16432 0.499 0.821 4505

250.000 209.670 26.243 0.03010 121.906 2495.53 128.05 133.34 1.20467 0.494 0.830 4408

240. 000 219.670 25.747 0.03004 113.414 2246.79 136.27 141.66 1.24356 0.488 0.039 4231

230.000 229.670 25.233 0.03963 105.224 2010.92 144.59 150.09 1.20113 0.482 0.049 4054

220. 900 239. 670 24.699 0. 04049 97. 371 1787. 83 153. 02 158.64 1. 31760 0.477 0.062 3871

210.000 249.670 24.143 0.04142 09.012 1577.01 161.59 167.35 1.35310 0.474 0.879 3683

200. 000 259.670 >3.559 0.04245 02.500 1377.69 170.35 176.24 1.30811 0.472 0.900 3489

190.000 269.670 22.943 0.04359 75.417 1186.90 179.31 105.36 1.42257 0.470 0.924 3290

100. 000 279.670 22.287 0. 04407 68.499 1009.69 188.51 194.74 1.45670 0.467 0.951 3080

170.000 209.670 21.502 0.04634 61.704 839.21 197.97 204.40 1.49065 0.460 0.982 2002

160.000 299.670 20.010 0.04805 54.973 676.64 207.74 214.41 1.52461 0.449 1.021 2670

150.000 309.670 19.946 0.05013 40.221 522.30 217.93 224.90 1.55903 0.439 1.081 244 0 140. 000 319.670 10.943 0. 05279 41.320 376.13 228.69 236.22 1.59496 0.443 1.192 2165

130. 000 329.670 17.701 0.05649 34.042 239. 18 241.16 249.01 1.63434 0.446 1.390 1858

120. 000 339.670 15.930 0.06275 25.026 113.44 256.30 265.01 1.60213 0.462 1.910 1477

110.000 349.670 10.557 0.09472 12.540 0.67 291.96 305.11 1.79794 0.562 10.067 091 100.000 359.670 6.029 0. 16505 6.245 45. 29 327.94 350.97 1. 92703 0.402 2.059 947

-90.000 369.670 5.004 0.19670 4.969 73.72 339.88 367.20 1.97230 0.452 1. 340 1006

-00.000 379.670 4.542 0.22017 4.272 96.72 348.56 379.14 2.00426 0.437 1.000 1052

-70.000 309.670 4. 164 0.24018 3.004 116.63 355.05 389.20 2.03043 0.420 0.945 1092

-60. 000 399. 670 3.075 0. 25010 3.456 134. 46 362.36 390.20 2.05323 0.422 0.861 1127 -50.000 409.670 3.642 0.27460 3.108 150.77 368.37 406.50 2.07375 0.410 0.803 1159

-40.000 419.670 3.447 0.29008 2.969 165. 94 374.04 414.32 2.09 261 0.415 0. 762 1100

-30.000 429.670 3.201 0.30470 2.705 160.10 379.46 421.70 2.11018 0.413 0.731 1216

-20. 000 439.670 3. 136 0. 31005 2.629 193.68 364.69 428.97 2.12672 0.412 0.707 1241 -10.000 449.670 3.000 0.33241 2.494 206.56 389.78 435.94 2.14240 0.411 0.608 1266

0.000 •59.670 2.094 0. 34556 2.375 218.92 394.76 442.75 2.15736 0.411 0.673 1289

10.000 469.670 2.791 0.35034 2.269 230.03 399.65 449.41 2.17171 0.412 0.661 1310

20. 000 479.670 2.697 0.37002 2.175 242.34 404.47 455.97 2.18552 0.412 0.651 1331 30.000 409.670 2.611 0.30303 2.090 253.52 409.24 462.43 2.19006 0.413 0.642 1351 40.000 499.670 2.532 0.39502 2.012 264.40 413.96 466.02 2.21178 0.415 0.636 1370

50. 000 509.670 2.450 0.40679 1.941 275.00 410.66 475.15 2. 22432 0.416 0.630 1389

60. 000 519. 670 2.390 0.41030 1.076 285. 37 423.33 401.43 2.23653 0.418 0.626 1407

70.000 529.670 2.327 0.42901 1.016 295.52 427.99 407.68 2.24043 0.420 0.623 1424

00.000 539.670 2.267 0.44109 1.760 305.48 432.63 493.09 2.26005 0.423 0.620 1441 100.000 559.670 2.159 0.46325 1.660 324. 66 441.92 506.25 2.28254 0.428 0.617 1472

120.000 579.670 2.062 0.40497 1.572 343.65 451.22 510.58 2.30417 0.4 34 0.616 1503

140.000 599.670 1.975 0.50630 1.494 361.92 460.58 530.89 2.32506 0.441 0.616 1531 160.000 619.670 1.096 0.52731 1.425 379.76 470.01 543.24 2.34532 0.440 0.618 1559

100.000 639.670 1.025 0.54004 1.362 397. 21 479.53 555.64 2. 36501 0.456 0.622 1585

200.000 659.670 1.759 0.56052 1.305 414.32 489.16 568.11 2.30421 0.463 0.626 1610

220. 000 679.670 1 .690 0.58079 1.254 431. 14 498.91 500.68 2.40290 0.472 9.631 1634

240. 000 699.670 1.642 0.60006 1.207 447.69 508.00 593.35 2.42136 0.460 0.637 1658

200.000 739.670 1.542 0.64051 1. 123 400. 10 529.01 619.07 2.45710 0.496 0.650 1703

320.000 779.670 1.454 0.60760 1.051 511.74 549.85 645.34 2.49160 0.517 0.664 1746

360. 000 019.670 1.377 0.72624 0.909 542.74 571.35 672.21 2.52529 0.535 0.680 1787

400.000 059.670 1.308 0.76449 0.934 573.21 593.55 699.72 2.55605 0.554 0.696 1026

440.000 099. 670 1.246 0.00242 0.005 603.22 616.44 727.00 2.59006 0.573 0.712 1064

244
METHANE ISOBAR AT P * 900.0 PSI

T T OEN VOL DP/OT DP/OO E H S C V CP M OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 8TU/18 9TU/LB BTU/LB/R BTU/LB/R 6TU/L8/R FT/S

293.919 165.751 20.299 0.0353* 165.566 3726. 43 93.57 98.81 1. 01467 0.499 0 • 705198

290.000 169.670 20.110 0.03556 161.216 3609. 16 96.50 101.77 1.03317 0.498 0.78* 5131

200.000 179.670 27.669 0.0361* 150.631 3322.70 104.06 109. *2 1.07839 0.499 0.796 *95*

270.000 109.670 27.211 0.03675 140.631 3042.08 111.85 117.30 1.12185 0.500 0.809 * 773

260 .000 199.670 26.7*3 0. 03739 131.168 2770.53 119.82 125.36 1.16371 0.499 0.820 *593

290.000 209.670 26.263 0.03000 122.109 2510.12 127.91 133.56 1.20401 0.495 0. 829 **16

2*0.000 219.670 25.769 0.03801 113.643 2262. SO 136.12 1*1.87 1.24285 0.488 0.838 *2*1 230.000 229.670 25.250 0.03959 105.481 2026.72 144.42 150.28 1.28038 0.462 0.8*8 *06*

220.000 239.670 2*. 727 0. 0*0** 97.657 1804.20 152.83 158.82 1.31677 0.477 0.861 386*

210. 000 2*9.670 24.17* 0.0*137 90.131 1594.00 161.38 167.50 1.35228 0.47* 0. 877 3697

200.000 259.670 23.595 0.0*238 82.862 1395.34 170.10 176.38 1.38711 0.472 0.897 350*

190. 000 269.670 22.905 0.0*351 75.814 1207.31 179.02 185. *7 1.42146 0.471 0.921 3308

ISO. 000 279.670 22.336 0. 0**77 68.9*6 1028.99 188.17 19*. 80 1.45545 0.467 0.9*7 3108

170.000 209.670 21.6*1 0. 0*621 62.212 659.55 197.57 20*. *1 1.48920 0.460 0.976 2906

160.000 299.670 20.083 0.0*709 55.560 698. 42 207.25 214.3* 1.52290 0.450 1.012 2699

150.000 309.670 20.0*0 0.0*990 *8.917 545.44 217.32 22*. 71 1.55692 0 . *39 1.366 2*76

1*0. 000 319.670 19*072 0. 052*3 *2. 180 400.99 228.06 235.82 1.59220 0.4*2 1.165 2211 130.000 329.670 17.099 0.05507 35.176 266. 30 239.93 2*6.21 1.6303* 0.4*5 1.330 1921 120.000 339.670 16.320 0.06125 27.561 143. 71 254.00 263.07 1.67*72 0.456 1.703 1577

110.000 3*9.670 13. *71 0.07*23 16.1** 37.45 275.16 286.16 1.7*159 0.497 3.63* 1126

100. 000 359.670 7.305 0.135*1 6.039 29.73 317.96 338.02 1.88793 0.506 3. 161 928

-90.000 369.670 5.020 0.17157 5.901 61. 11 334. 18 359.60 1.9*720 0.46* 1.612 992 -00.000 379.670 5.091 0. 196** *.926 85.79 344.32 373. *2 1.98*11 0.4*5 1.212 10*1

-70.000 309.670 *.611 0.21606 4.317 106. 95 352. 38 38*. 50 2. 0129* 0. *33 1.025 1082

-60. 000 399.670 *.259 0.23*80 3.885 125.79 359.38 39*. 16 2.037*2 0.426 0.916 1119

-50. 000 *09.670 3.902 0.25112 3.556 142.93 365.7* *02.9* 2.05911 0.421 0.8*4 1152

-*0.000 419.670 3.755 0.26629 3.293 158. 80 371,67 *11.12 2.0788* 0.418 0.79* 1183

-30.000 *29.670 3.56* 0.28060 3. 077 173. 64 377. 29 *18.86 2.09708 0.415 0. 757 1211 -20.000 *39.670 3.399 0.29*2* 2.89* 187.67 382,69 *26.28 2.11*15 0.41* 0.728 1237

-10.000 **9.670 3.25* 0.3073* 2.73? 201.02 387.92 *33. *5 2. 13027 0.413 0.706 1262

0. 000 *59.670 3.125 0.32000 2.601 213.79 393.0? **0.*2 2. 1*561 0.413 0.589 1285

10.000 *69.670 3. 010 0. 33228 2.480 226. 07 398. 01 **7.23 2.16027 0.413 0.67* 1308

20.000 *79.670 2.905 0. 3**2* 2.373 237.93 402.92 *53.91 2. 17*3* 0.41* 0.663 1329

30.000 *09.670 2.010 0.35593 2.276 249.41 *07,77 *60. *9 2.18792 0,415 0.653 13*9

*0.000 *99.670 2. 722 0.36737 2.188 260.57 412.56 466.98 2.2010 * 0.416 0.6*5 1369

50.000 509.670 2.6*1 0.37860 2.109 271.44 417.32 473.41 2.21377 0.418 0.639 1388

60.000 519.670 2.566 0.38965 2.036 282. 05 422.05 479.77 2.22613 0.419 0.63* 1*06

70.000 529.670 2. *97 0.40G53 1.969 292.42 *26.76 486.09 2.23818 0.421 0.630 1*23

80. 000 539.670 2. *32 0.41125 1.906 302.58 *31. *5 492.37 2.2*993 0.42* 0.627 1**0

100. 000 559. 670 2.313 0.43231 1.795 322.35 **0.8? 504.86 2.27265 0.429 0.623 1*72

120. 000 579.670 2.200 0.45291 1.698 341. 46 *50.20 517.29 2.294*8 0.4 35 0.621 1503

1*0.000 599.670 2.11* 0.47312 1.612 360.03 *59.62 529.71 2. 31553 0.4*1 0.621 1532

160.000 619.670 2.020 0.49301 1.535 378, 13 *69.10 542. 14 2. 33592 0.4*9 0. 622 1559

100. 000 639.670 1.951 0.51262 1.467 395.82 *78.60 554.61 2.3557* 0.456 0.625 1586

200.000 659.670 1.000 0.53197 1.405 413. 15 *88.35 967.16 2.37505 0.46* 0.629 1611 220.000 679.670 1.015 0.55111 1.348 430. 17 *98.15 579.79 2.39391 0.472 0.63* 1635

240.000 699.670 1.75* 0.57006 1.297 446. 90 508. 07 592.52 2.41237 0.431 0.639 1659

200. 000 739.670 1.6*6 0.60746 1.206 479.64 528. 35 618.34 2.4*825 0.499 0.652 170*

320. 000 779.670 1.552 0.64431 1.128 511.55 5*9.25 644.70 2.48295 0.517 0.666 17*7 360.000 019.670 1 . *69 0.63070 1.068 542.79 570.81 671.65 2.51666 0.536 0.681 1788

*00.000 059.670 1.395 0.71671 1. 000 573.46 593.05 699.22 2.5*950 0.555 0.697 1828

**0.000 099.670 1.329 0.75240 0.948 603.66 615.98 727.44 2.58150 0.573 0.71* 1066

241
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ru

METHANE ISOBAR AT P » 850.0 PSI

T T DEN VOL OP/OT OP/OD E H S CV CP M DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/L8 BTU/LB 8TU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

293. 26

2

165. 908 28.305 0.03533 165.479 3732.74 93.60 99.16 1.01489 0.499 0.781 5200

290. 000 169.670 28.132 0.03555 161.313 3620. 27 96.41 102.01 1.03265 0.498 0.784 5136

280. 000 179.670 27.684 0.03612 150.756 3334.88 103.97 109.65 1.07785 0.500 0.795 4960

270.000 1 OS. 670 27.227 0.03673 140.782 3055.17 111.75 117.53 1.12128 0.501 0.808 4779

260. 000 199.670 26.761 0.03737 131.344 2784.39 119.70 125.58 1.16309 0.499 0.819 4600

250.000 209.670 26.283 0.03805 122.391 2524.66 127.78 133.77 1.20336 0.495 0.828 4425

240.000 219.670 25. 791 0.03677 113.871 2277.15 135.97 142.07 1.24216 0.489 0.837 4250

230.000 22S.670 25.282 0.03955 135.736 2042. 44 144. 25 150.48 1.27962 0.482 0. 847 4075

220.000 239.670 24.755 0.04040 97.941 1820.50 152.64 159.00 1.31596 0.477 0.859 3896

210.000 249.670 24.205 0.04131 90.446 1610.88 161.16 167.66 1.35139 0.474 0.875 3710

200.000 259.670 23.630 0.04232 63.213 1412.87 169.85 176.51 1.38613 0.473 0.895 3520

190.000 26S. 670 23.026 0. 04343 76.205 1225.58 178.74 185.57 1.42036 0.471 0.918 3325

180.000 279.670 22.384 0.04467 69.384 1048.11 187.84 194.87 1.45421 0.468 0.942 3128

170.000 289.670 21.698 0.04609 62.709 879.65 197.18 204.43 1.48778 0.460 0.970 2930

160.000 299.670 20.953 0.04773 56.132 719.68 206.77 214.28 1.52123 0.450 1.003 2727 150.000 309.670 20.130 0. 04968 49.589 568. 06 216.72 224.54 1.55489 0.439 1.052 2510

140.000 319.670 19.193 0.05210 42.995 425.22 227.27 235.47 1.58960 0.442 1. 141 2255

130.000 329.670 18.078 0.05531 36.222 292.41 238.81 247.52 1.62668 0.443 1.282 1979

120. 000 339.670 16.645 0.06008 29.043 172. 10 252.10 261.55 1.66861 0.452 1.564 1662

110. 000 349.670 14.437 0. 06927 20.923 68.69 269.67 280.57 1.72371 0.476 2.456 1281 100.000 359.670 9.451 0.10581 10.926 22.63 304.06 320.71 1.83673 0.523 4.456 945

•90.000 369.670 6.738 0.14841 7.080 49.45 327.48 350.84 1.91950 0.475 2.004 983

-80.000 379.670 5.712 0.17507 5.693 75.46 339.63 367.18 1.96316 0.452 1. 377 1032

-70.000 389.670 5.100 0.19606 4.896 97.69 348.66 379.52 1.99524 0.4 39 1.119 1075

-60.000 399.670 4.670 0.21411 4.356 117.41 356.24 389.94 2.02167 0.430 0.978 1112 -50.000 409.670 4.342 0.23032 3.955 135.32 363. 00 399.25 2.04468 0.424 0.889 1146

-40.000 419.670 4.077 0.24526 3.641 151.84 369.22 407.83 2. 06536 0.420 0.828 1178

-30. 000 429. 670 3.857 0.25926 3.387 167.27 375.07 415.88 2.08432 0.418 0.784 1206

-20.000 439.670 3.669 0.27254 3.174 181.61 380.65 423.55 2.10197 0.416 0.751 1233

-10. 000 449.670 3.506 0. 28524 2.994 195.61 386.03 430.92 2.11856 0.415 0.725 1259

0.000 459.670 3.362 0.29747 2.837 208.79 391.25 438.07 2.13428 0.414 0.705 1263

10.000 469.670 3.233 0.30931 2.700 221.44 396.35 445.03 2.14926 0.414 0.688 1305

20.000 479.670 3. 117 0.32082 2.578 233.63 401.35 451.85 2.16362 0.415 0.675 1327

30.000 489. 670 3.012 0.33204 2.469 245.42 406.28 458.54 2.17743 0.416 0.664 1348

40.000 499.670 2.915 0.34302 2.371 256.85 411. 15 465.14 2.19077 0.417 0.655 1367

50.000 509.670 2.827 0.35377 2.202 267.98 415.97 471.65 2.20368 0.419 0.648 1386

60.000 519.670 2.745 0.36434 2.200 278.83 420.76 478.10 2.21622 0.420 0.642 1405

70.000 529.670 2.669 0.37473 2.126 269.42 425.52 484.50 2.22841 0.422 0.637 1422 80.000 539.670 2.598 0.38497 2. 057 299. 79 430.26 490.86 2.24029 0.425 0.634 1440 100.000 559.670 2.469 0.40504 1.933 319.93 439.72 503.47 2.26325 0.430 0.629 1472 120.000 579.670 2.355 0.42466 1.826 339. 37 449. 17 516.01 2.28527 0.436 0.626 150 3 140.000 599.670 2.253 0.44388 1.732 358.23 458.66 528.53 2.30649 0.442 0.625 1532

160. 000 619.670 2.161 0.46278 1.648 376.60 468. 20 541.04 2.32702 0.449 0.627 1560 180.000 639.670 2.077 0.48139 1.573 394.52 477.83 553.60 2.34696 0.457 0.629 1587

200. 000 659.670 2.001 0.49976 1.506 412.07 487.55 566.21 2.36637 0.465 0.633 1612

220. 000 679. 670 1.931 0.51790 1.444 429.28 497.39 578.90 2.38533 0.473 0.637 1637

240. 000 699.670 1. 866 0.53586 1.388 446.19 507.35 591.69 2.40387 0.482 0.642 1660 280.000 739.670 1.75 0 0.57127 1.289 479.24 527.70 617.61 2.43990 0.499 0.654 1706

320.000 779.670 1.650 0.60613 1.205 511.43 548.66 644. 06 2.47472 0.518 0.668 1749

360.000 819.670 1.561 0.64054 1.132 542.90 570.27 671.08 2.50851 0.536 0.683 1790

400. 000 859.670 1.482 0.67456 1.067 573.77 592.55 698.73 2.54144 0.555 0.699 1830

440.000 899.670 1.412 0.70027 1.011 604. 15 615.52 727.01 2.57359 0.574 0.715 1868

246
METHANE ISOBAR AT P * 900.0 PSI

T T DEN VOL OP/DT DP/DD F H S CW CP M DEC F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 6TU/LB 9TU/LB BTU/LB/R BTU/LB/R 8TU/LB/R FT/S

-293.605 166. 065 20.312 0.03532 165.392 3739. 01 93.63 99.52 1.01511 0.500 0.780 5201

-290.000 169.670 20.166 0.03553 161.409 3631. 31 96. 33 102.25 1.03213 0.499 0.783 5140

-200.000 179.670 27.699 0.03610 150.030 3346.99 103.07 109.89 1. 07730 0.500 0. 795 4965

-270. 000 109.670 27.266 0.03671 140.932 3068. 19 111.64 117.76 1.12070 0.501 0.808 4786

-260.000 199.670 26.779 0.03736 131.519 2790.2® 119.5© 125.80 1. 16249 0.500 0.819 4608

-250.000 209.670 26.303 0.03302 122.591 2539. 14 127.65 133.99 1.20271 0.495 0.828 443 3 -260.000 219.670 25.013 0.03674 114.096 2292.24 135.82 142.28 1.2414© 0.409 0,836 4260

-230.000 229.670 25. 307 0.03952 105.966 2058. 09 144.09 150.67 1.2786® 0.483 0.845 4066

-220.000 239.670 26.702 0.04035 98.221 1836.71 152.45 159.18 1.31515 0,478 0. 857 39S7

-210.000 269.670 26.236 0.04126 90.757 1627.67 160.95 167.03 1.39051 0.475 0.873 3724

-200.000 259.670 23.666 0.04226 03.559 1430.29 169.61 176.65 1.30516 0.473 0. 892 3535

-190. 000 269.670 23.066 0. 04335 76.590 1243. 71 178.46 185.68 1.41929 0.472 0.914 3342

-100.000 279.670 22.432 0.04450 69.015 1067.04 107.52 194.95 1.45360 0,468 0.930 314$

-170. 000 209.670 21.756 0.04597 63.196 099.52 196.79 204.45 1.40640 0.461 0.964 2953

-160.000 299.670 21.022 0,04757 56.608 740.64 206.31 214.24 1.51961 0.450 0. 995 2754

-150. 000 309.670 20.216 0. 04947 50.238 590.28 216.15 224.39 1.55293 0.439 1.039 2543

-160. 000 319.670 19.307 0.05179 43.773 448. 80 226.53 235.16 1.58711 0.442 1.120 2296

-130.000 329.670 10.262 0.05602 37.196 317.69 237. 78 246.91 1.62330 0.442 1. 241 2032

-120.000 339.670 16.915 0.05912 30.353 199. 12 250.46 260.32 1.66334 0.448 1.466 1736

-110. 000 369.670 15.046 0.06647 22.967 97.27 266.15 277.23 1.71237 0.465 2.017 1398

-100.000 359.670 11.667 0.00721 14.252 28.45 291.77 306.30 1.79420 0.501 4.117 1041 -90.000 369.670 7.872 0.12704 0.611 39. 64 319.53 340.70 1.88863 0.486 2.553 982

-00.000 379.670 6.620 0.15576 6.597 66. 12 334.44 360.40 1.94126 0.459 1.582 1027

-70. 000 309.670 5.637 0.17741 5.552 89.08 344.66 374.23 1.97724 0.444 1.230 1069

-60.000 399.670 5.111 0.19564 4.875 109.49 352.94 385.54 2.00591 0.4 34 1. 049 1107

-50.000 609.670 4.722 0.21179 4.309 128.05 360.15 395.44 2.03039 0.428 0.939 1142 -60.000 619.670 4.414 0.22655 6. 015 145. 16 366.69 404.45 2. 05211 0.423 0. 866 1173

-30.000 629.670 4.162 0.24029 3.717 161.12 372.79 412.83 2.07186 0.420 0.814 1203

-20.000 639.670 3.949 0.25325 3.471 176.13 378.56 420.77 2.09012 0.418 0.775 1230

-10. 000 669.670 3.765 0.26561 3.263 190. 36 304-10 428.36 2.10720 0.417 0.745 1256

0.000 659.670 3.606 0.27747 3.085 203.93 309.45 435.69 2. 12332 0.416 0.722 1280 10.000 669.670 3.461 0.20092 2.929 216.94 394.66 442.81 2.13865 0.416 0.703 1303

20.000 679.670 3.333 0.39003 2.792 229.45 399.76 449.77 2. 15330 0.416 0.688 1325

30.000 609.670 3.217 0.31034 2.670 241.54 404.7® 456.50 2. 16736 0.417 0.676 1346

60. 000 699.670 3.111 0. 32140 2.560 253. 25 409.72 463.29 2.18091 0.418 0.666 1366

50.000 509.670 3.014 0.33176 2.661 264.63 414.61 469.90 2.19402 0.420 0.657 1386

60.000 519.670 2.925 0.34107 2.370 275.71 419.46 476.44 2.20672 0.421 0.651 1404

70.000 529.670 2.042 0.35104 2.287 286.52 424.20 402.91 2.21906 0.423 0. 645 1422

00. 000 539.670 2.765 0. 36166 2.211 297.09 429.07 489.34 2.23109 0.426 0.641 1439

100.000 559.670 2.626 0.38005 2.075 317.60 438.62 502.09 2.25428 0.431 0.634 1472 120.000 579.670 2.503 0.39950 1. 956 337.37 44S.15 514.74 2.27649 0.4 36 0.631 150 3 160.000 599.670 2.393 0.41793 1.055 356.52 457.70 527.35 2.29707 0.443 0.630 1533

160. 000 619.670 2.294 0.43594 1.763 375.14 467.3® 539.95 2. 31855 0.450 0.631 1561 100.000 639.670 2.204 0.49367 1.681 393.30 476.90 552.58 2.33861 0,457 a. 633 1588

200.000 659.670 2. 122 0.47115 1.608 411. 06 486.75 565.27 2.35013 0.465 0.636 1613

220.000 679.670 2.047 0.40041 1.541 420.47 496.63 570. 02 2. 37710 0.474 0.640 1638

260. 000 699.670 1.970 0.50540 1.401 445.55 506.63 590.37 2.39581 0.482 0.645 1662

200.000 739.670 1.055 0.53913 1.374 478.92 527.05 616.09 2.43198 0.500 0.657 1707

320.000 779.670 1.760 0.57222 1.203 511.37 548.06 643.43 2.46691 0.518 0.670 1751 360.000 019.670 1.653 0.69406 1.204 543. 07 569.72 670.53 2.50080 0.537 0.685 1792

600. 000 059.670 1.570 0.63712 1.135 574.14 592.05 698.24 2.53301 0.556 0.701 1031 460.000 099.670 1.495 0.66907 1.074 604.69 615,07 726.57 2.56602 0.574 0.716 1070

247
METHANE ISOBAR ATP* 1000.0 PSI

T T OEM VOL DP/OT DP/OO E H S CV CP w OEO F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

-293.291 166. 379 26.325 0.03530 165.219 3751.50 93.70 100.23 1.01554 0.501 0.780 5204

-290.000 169.670 28.174 0.03549 161.599 3653. 20 96. 16 102.73 1.03109 0.500 0. 783 5149

-200.000 179.670 27.728 0.03606 151.125 3371. 07 103.69 110.36 1. 07622 0.501 0. 794 4976

-270. 000 169. 670 27.276 0.03666 141.228 3094.09 111.43 110.22 1.11956 0.502 0.806 4796

-260.000 199.670 26.615 0.03729 131.665 2825.63 119.35 126.25 1.16128 0.501 0.817 4622

-250.000 209.670 26.342 0.03796 122.986 2567.91 127.39 134.42 1.20143 0.496 0.826 4449

-240.000 219.670 25.656 0.03666 114.541 2322.21 135.53 142.69 1.24009 0.490 0. 834 4279

-230.000 229.670 25.355 0.03944 106.485 2069.18 143.76 151.06 1.27740 0.484 0.843 4107

-220.000 239.670 24.636 0.04026 98.774 1868.88 152.09 159.54 1.31355 0.479 0.854 3931

-210.000 249.670 24.297 0.04116 91.370 1660.97 160.53 168.15 1.34876 0.476 0.869 3750 -200.000 259.670 23.735 0. 04213 84. 237 1464. 79 169. 14 176.94 1. 38325 0.474 0.886 3565

-190.000 269.670 23. 145 0.04321 77.343 1279.54 177.91 185.92 1.41717 0.472 0.906 3376

•100.000 279.670 22.524 0.04440 70.655 1104.40 186.86 195.11 1.45063 0.469 0.930 3187

-170.000 269.670 21.863 0.04574 64.140 938. 62 196.05 204.52 1.48370 0.461 0.953 2996

-160.000 299.670 21.153 0. 04727 57.760 781.73 205.43 214.18 1.51648 0.450 0.960 2807

-150.000 309.670 20.379 0.04907 51.474 633.62 215.06 224.15 1.54920 0.440 1.017 2606

-140.000 319.670 19.519 0. 05123 45.232 494.72 225. 15 234.63 1.58248 0.441 1.084 2373

-130. 000 329.670 16.535 0. 05395 38.973 366. 19 235.92 245.91 1.61720 0.441 1.176 2129

-120. 000 339. 670 17.361 0. 05760 32.623 250. 13 247.72 258.39 1.65448 0.444 1.332 1664

-110.000 349. 670 15.663 0.06304 26. 098 149.92 261.31 272.99 1.69682 0.454 1.623 1576

-100.000 359.670 13.707 0.07296 19.276 70.95 278.64 292.15 1.75080 0.472 2. 326 1274

-90.000 369.670 10.484 0.03539 12.607 41.46 302.66 320.32 1.62602 0.465 2. 873 1066

-ao. ooo 379. 670 8. 139 0.12266 8.936 52.38 322.51 345.26 1.89462 0.472 2.089 1037

-70.000 369.670 6.667 0. 14563 7.135 74.67 335.04 362.60 1.94027 0.454 1.497 1068

-60.000 399.670 6.090 0.16420 6.063 95.69 345. 80 376.21 1.97426 0.442 1.214 1103

-50.000 409.670 5.547 0.18029 5.37 2 115.02 354.09 367.47 2. 00210 0.434 1. 053 1137

-40. 000 419. 670 5.134 0. 19476 4.849 132.96 361.39 397.45 2.02617 Q.426 0.950 1169

-30.000 429.670 4.806 0.20608 4.443 149.74 366.04 406.57 2.04765 0.424 0.879 1198

-20.000 439.670 4.535 0.22053 4.115 165.54 374. 25 415.09 2.06724 0.422 0.827 1226

-10.000 449.670 4.305 0.23231 3.644 180.52 360. 13 423.15 2.06536 0.420 0.768 1253

0. 000 459.670 4.106 0.24355 3.615 194.78 385.78 430.86 2.10237 0.419 0.756 1277

10. 000 469.670 3.932 0.25435 3.417 208.43 391.23 438.33 2.11841 0.419 0.734 1301 20.000 479.670 3.777 0.26479 3.245 221.55 396.54 445.57 2. 13367 0.419 0.715 1323

30.000 469.670 3.636 0.27491 3.092 234.19 401.73 452.64 2. 14825 0.419 0.699 1345

40.000 499.670 3.512 0.28476 2.957 246.42 406.84 459.57 2.16226 0.420 0.687 1365

50.000 509.670 3.397 0.29438 2.835 258. 28 411.87 466.38 2.17576 0.422 0.676 1385 60.000 519.670 3.292 0.30379 2.724 269.81 416.84 473.10 2.18881 0.423 0.668 1404

70.000 529.670 3.195 0.31302 2.624 261. 05 421.77 479.74 2.20147 0.425 0.661 1422 60.000 539.670 3. 105 0.32209 2.532 292. 01 426.67 486.31 2.21377 0.427 0.655 1440 100.000 559.670 2.943 0.33961 2.369 313.24 436.40 499.32 2.23744 0.432 0.647 1473

120. 000 579.670 2.801 0.35705 2.229 333.64 446.08 512.20 2.26005 0.438 0.642 1505

140.000 599.670 2.675 0.37390 2. 107 353. 36 455.77 525.01 2.28177 0.444 0.639 1535

160.000 619.670 2.561 0.39041 1.999 372.49 465.49 537.79 2. 30273 0.451 0.639 1563

160. 000 639.670 2.459 0.40663 1.903 391. 11 475.27 550.57 2.32304 0.459 0.640 1590

200.000 659.670 2.366 0.42260 1.617 409.28 485.14 563.39 2.34276 0.466 0.642 1616

220.000 679.670 2. 261 0.43636 1.740 427. 06 495.10 576.28 2.36202 0.475 0.646 1641 240.000 699.670 2.203 0.45392 1.669 444.50 505.19 589.24 2.36081 0.483 0.650 1665

260.000 739.670 2.064 0.48455 1.546 478.47 525.74 615.47 2.41726 0.501 0.661 1711 320.000 779.670 1.943 0.51463 1.441 511.44 546.66 642.17 2.45242 0.519 0.674 1754

360. 000 619.670 1.637 0.54427 1. 350 543.59 566.64 669.43 2.46651 0.5 38 0.689 1796

400.000 659.670 1.744 0.57353 1.272 575. 04 591.07 697.27 2.51967 0.556 0.704 1636

440.000 899.670 1.660 0.60248 1.202 605.93 614. 16 725.72 2.55202 0.575 0.719 1874

243
methane isobar «t p i 1100. o psi

T T DEN VOL DP/0T OP/OD E H S CV CP M DEC F OEG R LB/CUFT CUFT7LB PSI/R PSICUFT/LB BTU/LB 0TU/LB BTU/L0/R BTU/L8/R 8TU/L0/R FT/S

-292.978 166.692 28.339 0.03529 165.047 3763.90 93.76 100.95 1.01597 0.501 0.779 5207

-290.000 169.670 28.201 0.03546 161.786 3674. 87 95.99 103.21 1.03006 0.501 0.702 5157

-280.000 179.670 27.758 0. 03603 151. 366 3394.92 103.50 110.84 1. 07514 0.502 0. 793 4967

-270.000 189.670 27.30® 0.03662 141.520 3119.76 111.23 118.60 1.11043 0.503 0. 805 4011

-260.000 199.670 26.850 0.03724 132.205 2852.84 119. 12 126.71 1.1600® 0.502 0.816 4637

-250.000 209. 670 26.381 0.03791 123.374 2596.45 127. 14 134.86 1.20016 0.497 0.824 4466

-240.000 219.670 25.099 0.03061 114.979 2351. 94 135.25 143.11 1.23073 0.491 0.832 4297

-230.000 229.670 25.402 0.03937 106.973 2120. 00 143.44 151.46 1.27594 0.405 0.840 4127

-220.000 239.670 24.889 0.04018 99.316 1900.75 151.72 159.91 1.31197 0 . 4 SO 0.851 3954

-210.000 249.676 24.357 0.04106 91.969 1693.90 160.13 168.49 1.34705 0.477 0.866 3776

-200. 000 259.670 23.802 0. 04201 84.899 1496. 86 168.67 177.23 1.38138 0.475 0.883 3593

-190.000 269.670 23.222 0.04306 78.076 1314. 87 177.39 186.16 1.41511 0.473 0.902 3409

-180.000 279.676 22.613 0.04422 71.469 1141.11 186.28 195.28 1.44833 0.469 0.923 3224

-170.000 289.670 21.968 0.04552 65.048 976.92 195.34 204.61 1.40110 0.462 0. 943 3041

-160. 000 299.670 21.278 0. 04700 58.783 821.81 204.58 214.16 1.51349 0.451 0.966 2 05 7 -150.000 309.670 20.532 0.04870 52.640 675.66 214.04 223.96 1.54568 0.440 0.990 2665

-140.000 319.670 19.713 0.05073 46.583 538. 87 223.88 234.21 1.57820 0.441 1.055 2443

-130.000 329.670 18.792 0.05321 40.573 412.43 234.27 245.11 1.61176 0.440 1.130 2216

-120.000 339. 670 17.727 0.05641 34.574 298. 17 245.44 256.93 1.64709 0.442 1.244 1973

-110.000 349.670 16.440 0.06083 28.564 196.78 257.83 270.23 1.60564 0.447 1.431 1716

-100.000 359.670 14.787 0.06763 22.550 117.82 272.28 286.05 1.73025 0.458 1.773 1453

-90.000 369.670 12.512 0.07993 16.600 63. 07 290.41 306.69 1.70680 0.472 2. 382 1215

-80. 000 379.670 10.027 0.09973 11.864 56.41 310.29 330.60 1.05063 0.473 2. 210 1107

-70. 000 389.670 8.302 0.12046 9.139 66.47 326. 08 350.62 1.90271 0.461 1.776 1090 -60.000 399.670 7.199 0.13890 7.546 85. 52 338.05 366.34 1.94257 0.449 1.399 1112

-50. 000 409.670 6.459 0.15481 6.526 104.74 347.60 379.14 1. 97420 0.440 1.179 1141 -40.000 419.670 5.918 0.16898 5.805 122.91 355.77 390.19 2.00007 0.433 1. 042 1170

-30. 000 429.670 5.497 0.18192 5.262 140. 07 363.06 400.12 2.02425 0.429 0.949 1199

-20.000 439.670 5.157 0.19393 4.834 156. 35 369.76 409.26 2.04529 0.426 0.863 1226

-10.000 449.670 4.87 3 0.20523 4.485 171. 03 376.03 417.04 2. 06457 0.423 0.834 1252

0. 000 459.670 4.631 0.21595 4.194 186.61 381.99 425.9® 2.08249 0.422 0.796 1277 10.000 469.670 4.421 0.22622 3.946 200.77 387.71 433.79 2.09929 0.421 0.767 1301 20.000 479.670 4.236 0.23609 3.733 214.39 393.24 441.34 2. 11519 0.421 0.743 1324

30.000 489.670 4. 071 0.24565 3.546 227.51 398.63 448.67 2. 13032 0.422 0. 724 1345

40.000 499.670 3.923 0.25492 3.380 240. 19 403.90 455.03 2. 14400 0.423 0.709 1366

50.000 509.670 3.789 0.26395 3.232 252.40 409.09 462.05 2.15071 0 .424 0. 696 1386

60.000 519.670 3.666 0.27276 3.099 264.42 414.19 469.75 2. 17213 0.425 0.685 1405

70. 000 529.670 3.554 0.28139 2.979 276. 04 419.24 476.56 2.10510 0.427 0.677 1424 00.000 539.670 3.450 0.28906 2.869 287. 37 424.25 403.29 2.19769 0.429 0.670 1441 100.000 559.670 3.264 0.30636 2.676 309.27 434.17 496.57 2.22105 0. 434 0.659 1475

120.000 579.670 3.102 0. 32238 2.511 330c 28 444.02 509.68 2.24407 0.439 0.652 1507

140. 000 599.670 2.959 0. 33799 2.368 350.54 453.84 522.69 2.26692 0.446 0.649 1537

160. 000 619.670 2.831 0. 35327 2.243 370. 16 463.68 535.64 2.20017 0.453 0.647 1566

180.000 639.670 2.716 0.36825 2.132 389.22 473.57 540.50 2.30073 0.460 0.647 1593

200.000 659.670 2.611 0.38298 2.032 407.79 983. 53 561.54 2.3206® 0.46® 0.649 1619

220. 000 679.670 2.516 0.39750 1.943 425.94 493.59 574.55 2.34011 0.476 0.652 1645

240.000 699.670 2.42© 0.41183 1.862 443.71 503.75 507.63 2.36700 0.464 0.656 1669

280.000 739.670 2.273 0.43998 1.721 478. 27 524.44 614.06 2.40301 0.502 0.666 1715

320.000 779.670 2.139 0.46759 1.602 511. 75 545.70 690.94 2.43920 0.520 0.676 1759

360. 000 819.670 2.021 0.49476 1.499 544.32 567.57 668.34 2.47347 0.539 0.692 1800

400. 000 859.670 1.917 0.52156 1.410 576. 16 590.08 696.32 2.50678 0.557 0.707 1040

440.000 899.670 1.825 0.54805 1. 332 607. 36 613.26 724.09 2.53927 0.576 0.722 1078

249
METHANE ISOBAR AT P = 1203.0 PSI

T T DEN VOL DP/DT OP/ OD E H S CV CP M DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 8TU/LB BTU/L8 BTU/LB/R BTU/LB/R BTU/LB/R FT/S

292.665 167.005 28.352 0.03527 164.877 3776.20 93.83 101.66 1.01641 0.502 0.779 5210

290.000 169.670 28.228 0.03543 161.969 3696.30 95.83 103.70 1. 02904 0.501 0. 781 5166

280. 000 179. 670 27. 787 0.03599 151.603 3418.56 103.32 111.31 1.07407 0.502 0.792 4997

220.000 189.670 27.340 0.03658 141.807 3145. 21 111. 02 119.15 1.11731 0.504 0.804 4823

260.000 199.670 26.385 0.0 3720 132.540 2879. 64 118.89 127.16 1.15890 0.502 0.814 4651

250.000 209.670 26.419 0.03785 123.757 2624. 76 126. 60 135.30 1.19890 0.498 0. 823 4482

240. 000 219.670 25.941 0.03855 115.409 2381.42 134.97 143.53 1.23739 0.492 0.830 4315

230.000 229.670 25.449 0.03929 107.453 2150.54 143.12 151.86 1.27450 0.485 0.838 4147 220.000 239.670 24.941 0.04009 99.847 1932. 31 151.37 160.20 1.31042 0.480 0.848 3976

210.000 249.670 24.415 0. 04096 92.556 1726. 40 159.73 168.83 1.34537 0.477 0. 862 3801

200.000 259.670 23.868 0.04190 05.546 1532.52 168.22 177.53 1.37955 0.476 0.879 3622

190. 000 269.670 23.298 0.04292 78.789 1349.69 176.87 186.41 1.41309 0.474 0.897 3441

180.000 279.670 22.699 0.04405 72.257 1177.23 185.69 195.47 1.44609 0.470 0.916 3260

170.000 289.670 22.068 0. 04531 65.924 1014.49 194.66 204.73 1.47859 0.462 0.934 3082

160.000 299.670 21.397 0.04674 59.762 860.97 203.78 214.16 1.51062 0.451 0.954 2904

150.000 309.670 20.676 0.04837 53.744 716.56 213. 08 223.83 1.54234 0.440 0.981 2720

140. 000 319. 670 19.891 0.05027 47.845 581.56 222.70 233.07 1.57422 0.441 1.030 2508

130.000 329. 670 19.022 0. 05257 42.037 456.85 232.78 244.46 1.60684 0.439 1.092 2294

120. 000 339.670 18.038 0. 05544 36. 305 343.96 243.48 255.80 1.64070 0.440 1.181 2068

110.000 349.670 16.892 0.05920 30.648 245. 06 255.06 266.22 1.67673 0.443 1.313 1834

100.000 359.670 15.505 0.06449 25.103 162.81 267.98 282.31 1.71646 0.450 1.523 1597

-90.000 369.670 13.762 0.07266 19.748 100.64 202.96 299.11 1.76250 0.460 1.861 1373

-80.000 379.670 11.642 0.08590 14.876 69.49 300.34 319.42 1.81670 0.467 2.119 1209

-70.000 389.670 9.769 0.10237 11.446 71.81 316.61 339.35 1.86853 0.462 1.841 1152 -60.000 399.670 8.409 0.11892 9.278 81. 30 329.94 356.37 1.91165 0.453 1.561 1140

-50. 000 409. 670 7.450 0. 13423 7.864 97.93 340.81 370.64 1.94693 0.444 1.307 1156

-40.000 419.670 6.758 0.14796 6.894 115.56 349.92 382.80 1.97627 0.437 1.137 1160 -30.000 429.670 6.232 0.16047 6. 180 132. 61 357.90 393.56 2.00162 0.432 1.023 1205

-20.000 439.670 5.812 0.17204 5.629 148. 97 365. 13 403.36 2. 02417 0.429 0.942 1231 -10.000 449. 670 5.468 0.18289 5.188 164.66 371.82 412.46 2.04464 0.426 0.882 1256 0.000 459.670 5.177 0.19316 4.824 179.72 376.12 421.04 2.06352 0.425 0.836 1260 10.000 469.670 4.927 0.20296 4.519 194.21 384.12 429.22 2.08112 0.424 0.801 1303

20.000 479.670 4.709 0.21235 4.257 208. 17 389. 69 437.08 2. 09768 0.424 0.772 1326

30.000 489.670 4.516 0.22142 4.030 221.65 395.49 444.69 2.11337 0.424 0.750 1348

40.000 499. 670 4.344 0.23020 3.831 234.70 400.94 452.09 2. 12834 0.425 0.731 1368

50.000 509.670 4.189 0.23873 3.654 247. 34 406.27 459.32 2.14267 0.4 26 0.716 1386

60.000 519.670 4.048 0.24704 3.495 259.63 411.52 466.42 2.15646 0.427 0.703 1408

70.000 529.670 3.919 0.25517 3. 353 271.58 416.70 473.40 2.16976 0.429 0.693 1426

60.000 539.670 3.801 0.26312 3.223 283.24 421.82 480.20 2.18264 0.431 0.684 1444 100.000 559. 670 3.589 0.27860 2.997 305. 74 431.93 493.84 2.20730 0.435 0.672 1478

120.000 579.670 3.406 0. 29359 2. 805 327. 30 441.94 507. 18 2.23073 0.441 0.663 1510 140.000 599.670 3.245 0. 30817 2.639 348.07 451. 91 520.39 2.25313 0.447 0.658 1541 160.000 619.670 3. 102 0.32241 2.495 368. 15 461.87 533.52 2.27466 0.454 0.655 1570

180. 000 639.670 2.973 0. 33636 2.367 387.63 471.87 546.61 2.29547 0.461 0.655 1597

200. 000 659.670 2.857 0. 35006 2.254 406. 59 481.93 559.72 2.31564 0.469 0.656 1623

220.000 679.670 2.751 0.36354 2.152 425.09 492. 07 572.65 2.33526 0.477 0.658 1649

240.000 699.670 2.654 0.37683 2.060 443.18 502.31 586.05 2.35439 0.485 0.661 1673

260.000 739.670 2.482 0.40292 1.900 478. 32 523.15 612.68 2.39140 0.503 0.671 1719

320. 000 779.670 2.334 0.42846 1.766 512. 28 544.52 639.73 2.42702 0.521 0.682 176 3 360.000 819.670 2.205 0.45357 1.651 545. 27 566.49 667.28 2.46147 0.539 0.695 1805

400.000 859.670 2.091 0.47831 1.551 577.46 589.10 695.38 2.49494 0.558 0.710 1845

440.000 899.670 1.989 0.50274 1.464 608.90 612.36 724.07 2.52756 0.577 0.725 1883

250
METHANE ISOBAR AT P * 1100.0 PSI

T T OEN VOL OP/DT DP/OD E H S CV CP M OEG F OEG R L0/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB 8TU/L8 BTU/LB/R BTU/LB/R 8TU/L9/R FT/S

292.353 167. 317 28.365 0.03525 166.707 3788. 61 93.89 102.38 1.01685 0.503 0.779 5213

290.000 169.670 28.255 0.03539 162.168 3717.51 95.66 106.18 1. 02803 0.502 0.780 5176

200.000 179.670 27.816 0.03595 151.836 3661.96 103.13 111.79 1. 07301 0.503 0.791 5007

270.000 189.670 27.372 0.01653 162.089 3170.65 110.82 119.61 1.11620 0.505 0.803 6835

260. 000 199.670 26.919 0.03715 132.870 2906.61 110.67 127.61 1.15772 0.503 0. 813 6665

250. 000 209.670 26.657 0. 03780 126.133 2652.85 126.66 135.73 1.19765 0.699 0.821 6698

260.000 219.670 25.983 0.03869 115.833 2610.66 136.69 163.95 1.23606 0.692 0. 328 6333

230.000 229.670 25.695 0.01922 107.926 2180.83 162.81 152.26 1.27308 0.686 0.036 6167

220.000 239.670 26.993 0.06001 100.369 1963.58 151.02 160.66 1.30690 9.681 0. 866 3999

210.000 269.670 26.672 0. 06086 93.130 1758. 76 159.36 169.17 1.36372 0.678 0.359 3826

200.000 259.670 23.933 0.06178 86.178 1565.78 167,78 177.86 1.37775 0.676 0.875 3669

190.000 269.670 23.371 0.06279 79.686 1386. 05 176,37 186.67 1.61112 0.675 0. 392 3671

180.000 279.670 22.783 0.06389 73.023 1212.80 185.11 195.68 1.66392 0.671 0. 909 3295

170.000 289.670 22. 165 0. 06512 66.770 1051.37 196.00 206.86 1.67616 0.663 0.926 3121

160. 000 299.670 21.510 0.06669 60.701 899.31 203.01 216.20 1.50767 0.652 0.963 2969

150.000 309.670 20.812 0.06805 56.796 756.66 212. 17 223.76 1.53917 0.660 0.966 2773

160.000 319.670 20.057 0.06986 69.032 623.01 221.60 233.61 1.57069 0.661 1. 009 2569

130. 000 329.670 19.231 0.05200 63. 393 699.75 231.62 263.96 1.60231 0.639 1.061 2366

120.000 339.670 18.312 0.05661 37.871 387. 95 261.76 256.88 1.63501 0.639 1.132 2156

110.000 369.670 17.266 0.05792 32.677 289. 39 252.73 266.68 1.66922 0.661 1.232 1936

100.000 359.670 16.069 0.06231 27.269 206.13 266.68 279.68 1.70587 0.665 1. 177 1718

-90. 000 369.670 16.600 0.06869 22.263 160.32 277.95 296.63 1.76632 0.652 1.587 1510

-80. 000 379.670 12.876 0.07767 17.663 95.98 292.88 311.57 1.79205 0.659 1.836 1333

-70.000 389.670 11.071 0.09033 13.811 82.66 308.67 330.21 1.66051 0.661 1.819 1230 -60.000 399.670 9.606 0.10612 11. 178 87.50 322.22 367.29 1.88380 0. 653 1.599 1196

-50.000 609.670 8.685 0.11786 9.377 96.59 333.96 362.31 1.92093 0.667 1.606 1187

-60.000 619.670 7.662 0.13085 8.116 111.60 363.96 375.66 1.95260 0.660 1.227 1199

-30.000 629.670 7.002 0.16283 7. 199 127. 66 352.63 387.01 1.97985 0.636 1. 096 1219

-20.000 639.670 6.697 0.15392 6.503 163. 70 360.60 397.65 2. 00388 0.632 1.000 1261 -10.000 669.670 6.086 0.16632 5.956 159.29 367.53 607.08 2.02556 0.629 0.930 1266

0.000 659.670 5.762 0.17615 5.507 176.37 376. 18 616.10 2.06538 0.6 27 0.876 1287

10. 000 669.670 5.669 0.18350 5.136 108.97 380.67 626.65 2.06376 0.626 0.835 1309

20.000 679.670 5.196 0. 19267 6.818 203. 11 386.50 632.03 2.08101 0.6 26 0.802 1331 30.000 689.670 6.97 3 0.20110 6.566 216. 80 392. 30 660.71 2. 09728 0.626 0.776 1352

60.000 699.670 6.775 0. 20966 6.308 230. 09 397.96 668.36 2.11273 0.627 0.756 1373

50. 000 509.670 6.597 0.21756 6.099 262.99 603.66 655.80 2.12769 0.628 0.736 1392

60. 000 519.670 6.636 0.22562 3.913 255. 56 608.63 663.09 2.16165 0.629 3. 722 1612

70.000 529.670 6.290 0.21310 3.765 267.76 616.13 670.25 2.15529 0.630 0.710 1630 80.000 539.670 6.156 0.26062 3.596 279.68 619. 37 677.29 2.16867 0.632 0.700 1668

100.000 559.670 3.918 0.25522 3.331 302.69 629.68 691.12 2.19363 0.6 37 0.686 1682

120. 000 579.670 3.713 0.26933 3.110 326.75 639.86 506.70 2.21767 0.662 0.676 1516

160. 000 599.670 3.533 0.28303 2.920 365.97 669.97 518.11 2.26021 0.668 0.667 1565

160.000 619.670 3. 376 0.29639 2.755 366.68 660.07 531.61 2.26206 0.655 0.666 1576

180.000 639.670 3.231 0.30966 2.610 386. 35 670.18 566.67 2.28309 0.662 0. 662 1601

200. 000 659.670 3.103 0.32226 2.681 605.67 680. 33 557.91 2.30368 0.670 0.662 1628

220. 000 679.670 2.986 0.33688 2.366 626.51 690.56 571.18 2.32329 0.678 0.666 1653

260.000 699.670 2.879 0.36729 2.263 662.91 500.88 586.68 2.36258 0.686 0.667 1678

280.000 739.670 2.691 0.37162 2.083 678.59 521.86 611.32 2. 37968 0. 506 0.675 1726

320. 000 779.670 2.529 0.39561 1.933 513. 02 563.35 638.56 2.61572 0.522 0.686 1768 360.000 819.670 2.388 0.61877 1.806 566.62 565.63 666.26 2.65036 0.560 0.699 1810 600.000 859.670 2.266 0.66176 1.693 578.96 588. 12 696.67 2.68398 0.559 0.713 1850 660.000 899.670 2.153 0.66665 1.597 610.78 611.66 723.27 2.51672 0.577 0.727 1888

251
METHANE ISOBAR AT P n 1400.0 PSX

T T OEM VOL DP/OT OP/DD E H S CV CP M DEG F OEG R L8/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/L8 BTU/LB BTU/L8/R BTU/L8/R 6TU/LB/R FT/S

-292. 042 167.628 26.376 0.03524 164.539 3800. S3 93.96 103.09 1.01728 0.509 0.776 5216

-290. 000 169.670 26.282 0.03536 162.329 3738.48 95.50 104.67 1.02702 0.503 0.760 5182

-209.000 179.670 27.845 0.03591 152.065 3465.15 102.96 112.27 1.07196 0.509 0.790 5817

-270.000 169.670 27.403 0.03649 142.367 3195.4? 110.62 120.00 1.11509 0.505 0.602 4847

-260.000 199.670 86 . 954 0.03710 133.195 2933.17 118.45 128.07 1.15656 0.509 0.812 4679

-250.000 209.670 26.495 0.03774 124.509 2680.72 126.39 136.18 1.19692 0.500 0.819 4513

-240.000 219.670 26.024 0.03843 116.249 2439.66 134.42 144.38 1.23975 0.993 0.826 4350

-230.000 229.670 25.541 0.03915 108. 388 2210.66 142.51 152.66 1.27168 0.987 0.833 4187

-220.000 239.670 25.043 0. 03993 100.881 1994.57 150.68 161.04 1.30739 0-462 0.893 4020

-210.000 249.670 24.529 0.04077 93.694 1790.67 158.96 169.52 1.39210 0.979 0.856 3850

-200.000 259.670 23.996 0.04167 86.796 1598.66 167.35 176.15 1.37599 0.977 0.871 3676

-190.000 269.670 23.442 0.04266 80.162 1417.98 175.69 186.94 1.90920 0.975 0.887 3502

-100.000 279.670 22. 864 0.04374 73.767 1247. 84 184.56 195.90 1.99179 0.971 0.903 3329

-170.000 289.670 22.258 0. 04493 67.568 1087.64 193.36 205.01 1.97380 0.969 0.916 3159

-160. 800 299.670 21.619 0.04625 61.606 936.89 202.28 214.27 1.50521 0.952 0.933 2993

-150.000 309.670 20.941 0.04775 55.800 795.40 211.31 223.69 1.53619 8.991 0.953 2622

-140. 000 319. 670 20.213 0.04947 50.155 663.35 220.57 233.40 1.56696 0.991 0.991 2627

-130.000 329.670 19.424 0. 05148 44.659 541. 34 230.17 243.52 1.59012 0.938 1.035 2433

-120.000 339.670 18.556 0.05389 39.310 430.44 240.17 259.14 1.62987 0.936 1.093 2232

-110.000 349.670 17.589 0.05686 34.119 332. 13 250.71 265.45 1.66268 0.939 1. 173 2027

- 100. 000 359.670 16.491 0.06064 29.126 248.06 261.97 277.69 1.69717 0.992 1.280 1824

-90.000 369.670 15.228 0.06567 24.392 179.78 274.15 291.17 1.73919 0.997 1.929 1629

-80.000 379.670 13.773 0.07261 20.003 129. 15 287.46 306.28 1.77997 0.953 1.601 1455

-70.000 389.670 12.175 0.08214 16.128 100.80 301.70 322.99 1.61790 0.956 1.712 1324

-60. 000 399.679 10.687 0.09357 13.117 97.76 315.41 339.67 1.86017 0.952 1.592 1264

-50. 000 409.670 9.490 0.10537 10.991 103.40 327.45 354.76 1.69797 0.997 1.431 1238

-40.000 419.670 8.541 0.11708 9.452 112. 19 338.01 368.37 1.93029 0.992 1.290 1232

-30.000 429.670 7.793 0.12832 8.314 125.64 347.33 380.59 1.95900 0.930 1.150 1241

-20. 000 439.670 7.201 0.13887 7.454 140.72 355.63 391.63 1.98999 0.939 1.054 1258

-10.000 449.670 6.721 0.14879 6.782 155.86 363. 19 401.76 2.00727 0.932 0.976 1278

0.000 459.670 6.322 0.15817 6.241 170.72 370.20 411.20 2.02809 0.930 0.915 1298

10.000 469.670 5.984 0. 16710 5.793 185. 22 376.79 420.11 2.09722 0.929 0.869 1319

20.000 479.670 5.693 0.17566 5.416 199.35 383.07 428.61 2.06511 0.920 0.831 1339

30.000 489.670 5.438 0.18389 5.094 213.10 389.09 436.76 2.00195 0.928 0.801 1360

40.000 499. 670 5.213 0.19183 4.614 226.50 394.92 444.65 2.09769 0.928 0.777 1379

50.000 509.670 5.012 0. 19954 4.568 239.54 400.59 452.31 2.11308 0.929 0.757 1399

60.000 519.670 4.830 0.20703 4.351 252.26 406.12 459.86 2.12761 0.930 0.740 1417 70.000 529.670 4.666 0.21433 4.157 264.67 411.56 467.12 2.19158 0.932 0.726 1436

80.000 539.670 4.515 0.22147 3.982 276.78 416.91 474.33 2.15505 0.939 0.715 1453

100.000 559.670 4.250 0.23530 3.679 300. 21 427.43 468.43 2.18072 0.938 0.697 1487

120.000 579.670 4.022 0.24864 3.426 322.67 437.78 502.29 2.20997 0.999 0.605 1519

140.000 599.670 3.823 0.26156 3.210 344. 29 448.04 515.05 2.22005 0.950 0.677 1550

160.000 619.670 3.647 0.27418 3.023 365.17 458.26 529.39 2.25017 0.956 0.672 1579

180. 000 639. 670 3.491 0.28648 2.659 385.90 468.46 592.75 2.27197 0.963 0.670 1606

200. 000 659.670 3.350 0.29854 2.714 405.05 478.74 556.13 2.29200 0.971 0.669 1633

220.000 679.670 3.222 0.31036 2.565 424.20 489.06 569.52 2.31207 0.979 0.670 1650

240.000 699.670 3.105 0.32204 2.470 442.89 499.46 502.99 2.33153 0.987 0.672 1663

280.000 739.671 2.900 0.34466 2.269 479.09 520.97 609.90 2.36910 0.905 0.680 1729

320. 000 779.670 2.724 0.36714 2.102 513.97 542.19 637.37 2.90517 0.923 0.690 1773

360.000 819.670 2.571 0.38699 1.960 547.76 564.37 665.21 2.93999 0.591 0.702 1815

400.000 859.679 2.436 0.41049 1.838 580.63 587.15 693.57 2.97377 0.560 0.716 1855

440.000 899.670 2.317 0.43168 1.731 612.74 610.57 722.98 2.50669 0.576 0.730 1893

252
METHANE ISOBAR AT P = 1500.0 PSI

T T DEN VOL OP/OT OP/OO E H S C V CP M DEG F DEG R LB/CUFT CUFT/L8 PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

251.730 167.960 29.392 0.01522 164.371 3612.55 94. 02 103.81 1. 01772 0.504 0.778 5219

290. 000 169.670 29.309 0.03533 162.496 3759.23 95.34 105.15 1.02602 0.504 0.779 5190

290.000 179.670 27.974 0.03596 152.290 3466.12 102.78 112.74 1.07092 0.505 0.790 5027

270.000 199.670 27.435 0.01645 142.641 3220.26 110.43 120.55 1.11400 0.506 0.801 4659

200.000 199.670 26.999 0.03705 133.515 2959.51 116.23 126.52 1.15541 0.505 0. 811 4692

250.000 209.670 26.532 0.03769 124.969 2708.36 126.15 136.62 1.19520 0.500 0.818 4529

240.000 219.670 26. 065 0.03937 116.659 2468.44 134.15 144.80 1.23346 0.494 0.824 4368

230.000 229.670 25.596 0.03909 109.943 2240.64 142.21 153.07 1.27030 0.488 0.631 4206

220.000 239.670 25. 093 0.03995 101. 393 2025.29 150.35 161.42 1.30591 0.483 0.840 4042

210.000 249.670 24.594 0.04069 94.246 1822.29 156.58 169.69 1.34050 0.480 0.853 3874

200.000 259.670 24.059 0.04157 97.401 1631.22 166.93 178.46 1.37426 0.478 0.867 3703

190.000 269.670 23.512 0.04253 90.924 1451.49 175.41 187.22 1.40731 0.476 0. 863 3531

190.000 279.670 22.943 0.04359 74.491 1282.40 184. 02 196.13 1.43973 0.472 0.899 3361 170.000 299.670 22.349 0.04475 69.392 1123. 31 192.75 205.19 1.47151 0.464 0.911 3196

160.000 299.670 21.724 0.04603 62.478 973.77 201.57 214.35 1.50265 0.453 0. 924 3034

150.000 309.670 21.063 0.04746 56.763 633.53 210.46 223.67 1.53324 0.441 0. 941 2 67 0 160. 000 319.670 20.359 0. 04912 51.223 702.70 219.60 233.25 1.56363 0.441 0.975 2681

130.000 329.670 19.602 0.05102 45.950 561.78 229.00 243.17 1.59420 0.438 1.012 2495

120.000 339.670 16.779 0.03325 40.645 471.66 238.74 253.53 1.62516 0.437 1.062 2304

110.000 349.670 17.972 0.05595 35.620 373.56 246.92 264.46 1.65686 0.436 1. 126 2110

100. 000 359.670 16.964 0. 05930 30.606 268.62 259.65 276.12 1.68973 0.440 1.209 1918

-90. 000 369.670 15.732 0. 06357 26.262 216.63 271.07 288.73 1.72429 0.443 1.316 1734

-90.000 379.670 14.459 0.06916 22.047 164. 06 283.30 302.51 1.76109 0.446 1.444 1566

-70.000 399.670 13.060 0.07657 18.251 127.14 296. 31 317.56 1. 80024 0.451 1.560 1427

-60. 000 399.670 11.649 0.09595 15.054 111.57 309.46 333.31 1.84010 0.449 1.557 1339

-50.000 409.670 10.415 0.09602 12.633 113. 42 321. 60 348.27 1. 87709 0.446 1.430 1298

-40. 000 419.670 9.409 0.10630 10.854 119.46 332.42 361.95 1.91007 0.442 1.308 1279

-30.000 429.670 9.594 0.11649 9.509 128. 03 342. 14 374.49 1.93962 0. 439 1. 202 1274 -20.000 439.670 7.914 0.12636 9.476 140.43 350.90 385.99 1.96609 0.436 1.101 1282

-10.000 449.670 7.366 0.13576 7.670 154.50 356.86 396.57 1.98989 0.433 1.018 1297

0.000 459.670 6.912 0.14469 7.024 166.84 366.22 406.41 2.01151 0.431 0.952 1314

10. 000 469.670 6.529 0.13319 6.494 183. 04 373.11 415.66 2. 03143 0.430 0.900 1332

20.000 479.670 6.199 0. 16135 6.050 197.00 379.63 424.45 2.04995 0.430 0.859 1351 30.000 499.670 5.910 0.16919 5.672 210.66 385.68 432.67 2. 06733 0.430 0.826 1370

60.000 499.670 5.657 0.17677 5.346 224. 04 391.69 440.99 2.08375 0.430 0.799 1389

50.000 509.670 5.431 0.18412 5. 061 237.11 397.73 446.87 2. 09935 0.431 0.777 1407

60.000 519.670 5.229 0.19126 4.910 249.90 403.41 456.54 2.11425 0.432 0.758 1425

70.000 529.670 5.045 0.19921 4.597 262.40 408.96 464.04 2.12855 0.434 0.742 1443

90.000 539.670 4.979 0.20500 4.396 274.63 414.45 471.39 2.14231 0.435 0.729 1460

100. 000 559.670 4.594 0. 21914 4. 041 298. 34 425.16 485.77 2.16847 0.440 0.710 1494

120. 000 579.670 4.333 0.23091 3.753 321. 11 435.71 499.82 2. 19313 0.445 0.696 1525

140.000 599.670 4.114 0.24307 3.509 343. 05 446. 11 513.63 2.21656 0.451 0.666 1556

160.000 619.670 3.922 0.25500 3.299 364.25 456.46 527.29 2.23697 0.457 0.660 1564

190. 000 639. 670 3. 750 0. 26665 3.115 384.80 466.79 540.86 2.26051 0.464 0.677 1612

200.000 659.670 3.597 0.27904 2.954 404.75 477.15 554.38 2.26133 0.472 0.676 1638

220.000 679.670 3.459 0.29922 2.910 424. 18 487.56 567.89 2.30151 0.460 0.676 1664

260. 000 699.670 3.331 0.30021 2.661 443.14 496.04 561.43 2.32114 0.488 0.678 1688

290. 000 739.670 3. 109 0. 32172 2.459 479.92 519.30 608.66 2.35898 0.506 0.684 1735

320. 000 779.670 2.919 0.34269 2.275 515.12 541.03 636.22 2.39527 0.524 0.694 1778 360.000 919.670 2.753 0.36323 2.119 549.26 563.31 664.20 2.43027 0.542 0.^06 1820 600.000 959.670 2.60 9 0.39342 1.984 562.46 586.19 692.69 2.46420 0.561 0.719 1660

440. 000 999.670 2.479 0.40331 1.967 614. 87 609.69 721.71 2.49720 0.579 0.733 1699

253
METHANE ISOBAR AT P = 1600.0 PSI

T T DEN VOL DP/OT DP/DD E H S C V CP w OEG f OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/L6 BTU/LB BTU/LB/R 8TU/L8/R BTU/LB/R FT/S

-291. 420 166. 250 28.405 0. 03521 164. 205 3824. 48 94. 09 104.52 1.01816 0.505 0.777 5222

-290. 000 169. 670 28.335 0.03529 162.665 3779.74 95.18 105.63 1.02502 0.505 0.779 5198

-260.000 179.670 27.903 0.03584 152.512 3510.87 102.60 113.22 1.06968 0 . 506 0.789 5037

-270.000 189.670 27.465 0.03641 142.911 3244.07 110.23 121,02 1.11291 0.507 0. 800 4671

-260. 000 199. 670 27.021 0. 03701 133. 831 2985.64 118.02 128.98 1.15427 0.506 0.809 4706

-250. 000 209.670 26.568 0.03764 125.229 2735.00 125.91 137.06 1.19400 0.501 0.816 4544

-240.000 219.670 26.105 0.03831 117.063 2497.01 133. 68 145.23 1.23210 0.495 0.822 4385

-230.000 229.670 25.630 0.03902 109.291 2270. 18 141.92 153.48 1.26893 0.489 0.829 4225

-220. 000 239. 670 25. 142 0. 03977 101.877 2055.74 150.02 161.81 1.30445 0.464 0.338 4063

-210.000 249.670 24.639 0.04059 94.788 1653.61 158.21 170.24 1. 33893 0.480 0.850 3897

•200.000 259, 670 24. 119 0.04146 87.994 1663.43 166. 52 178.80 1.37256 0.479 0.863 3728

-190.000 269.670 23.580 0.04241 81.471 1484.60 174. 95 187,51 1.40546 0.477 0.878 3560

-180. 000 279. 670 23.020 0.04344 75.197 1316.49 163.50 196.37 1.43771 0.473 0 . d92 3393

-170.000 289.670 22.436 0.04457 69.152 1158. 44 192.15 205.36 1.46928 0.465 0.905 3232

-160.000 299.670 21.625 0.04582 63. 321 1010.00 200.89 214.46 1.50018 0.453 0.916 3074

-150.000 309.670 21.161 0.04721 57.688 870. 90 209.70 223.68 1.53045 0.442 0.930 2915

- 140.000 319.670 20.498 0.04879 52.242 741.17 218.68 233.14 1.56045 0.442 0.961 2733 -130.000 329.670 19.768 0. 05059 46.977 621.22 227.91 242.90 1.59051 0.438 0.993 2554

-120.000 339.670 18.962 0.05268 41.894 511.77 237.42 253.03 1.62080 0.437 1.035 2371

-110.000 349.670 16.126 0.05517 37. 006 413. 84 247. 30 263.64 1. 65158 0. 437 1. 069 2186

-100.000 359.670 17.168 0.05818 32.341 328.54 257.62 274.86 1.68319 0.436 1.156 2004

-90. 000 369.670 16.153 0.06191 27.943 256. 83 268.47 266.81 1.71597 0.441 1.238 1828

-60. 000 379. 670 15.010 0.06662 23. 861 199.41 279.93 299.67 1.75029 0.444 1.335 1667

-70.000 389. 670 13.767 0.07264 20. 156 157. 18 292. 00 313.52 1.78628 0.447 1.431 1526

-60.000 399.670 12.475 0.08016 16.917 132. 07 304. 38 328.13 1.82330 0.446 1.476 1424 -50.000 409.670 11.254 0.08885 14.281 125.44 316.36 342.69 1.85929 0.444 1.416 1362 -40.000 419.670 10.213 0.09792 12.276 129. 37 327.31 356.32 1.09218 0.442 1. 310 1333

-30. 000 429. 670 9. 345 0. 10701 10.749 135.65 337. 23 368.94 1.92188 0.439 1.215 1319

-20. 000 439.670 8.619 0.11603 9.555 144. 05 346.29 380.67 1.94887 0.437 1.131 1315 -10.000 449.670 6.012 0.12481 8.610 155.63 354.60 391.58 1.97342 0.435 1.052 1321 0.000 459. 670 7.505 0.13325 7.853 168. 84 362.28 401.75 1.99580 0.433 0.985 1334

10.000 469. 670 7.075 0. 14133 7.233 182.47 369.44 411.32 2.01639 0.432 0.930 1349

20.000 479.670 6.707 0.14910 6.717 196.08 376.22 420.39 2. 03550 0.431 0.886 1366

30.000 489. 670 6.367 0.15658 6.280 209.52 382.67 429.06 2.05339 0.431 0.850 1383

40.000 499.670 6.105 0.16381 5.904 222.75 386.87 437.40 2.07026 0.432 0.620 1400

50.000 509. 670 5. 854 0. 17081 5.577 235.75 394.07 445.48 2. 08626 0.432 0.796 1418

60.000 519.670 5.630 0. 17762 5.290 248.50 400.71 453.33 2. 10152 0.433 0.775 1435

70. 000 529. 670 5.427 0.16425 5.035 261. 02 406.41 461.00 2. 11613 0. 435 0.758 1452

60.000 539.670 5.243 0.19072 4.807 273.29 412. 00 468.51 2. 13018 0.437 0.744 1469

100. 000 559.670 4.920 0.20325 4.416 297. 14 422.93 483.15 2.15683 0.441 0.722 1501

120. 000 579.670 4.645 0.21531 4.092 320. 13 433.63 497.42 2.18188 0.446 0.706 1532

140.000 599.670 4.406 0.22697 3.818 342. 31 444. 19 511.43 2.20565 0.452 0.696 1562

160.000 619.670 4.196 0.23631 3.583 363.77 454.66 525.27 2.22834 0.458 0.686 1591

100. 000 639.670 4.010 0.24936 3.378 384.57 465.11 538.99 2.25013 0.466 0.604 1618 200.000 659.670 3.844 0.26017 3.199 404.78 475.57 552.65 2.27116 0.473 0.682 1644

220. 000 679.670 3.693 0.27076 3.039 424. 46 486.07 566.29 2.29153 0.481 0.682 1670 240.000 699.670 3.557 0. 28117 2.897 443. 65 496.63 579.93 2. 31132 0.469 0.663 1694

280.000 739.670 3. 317 0.30152 2.653 480.79 518. 03 607.36 2.34943 0.507 0.689 1740

320. 000 779.670 3.112 0.32134 2.450 516.48 539.08 635.08 2.38593 0.525 0.698 1784

360.000 819. 670 2.935 0.34073 2.279 550.99 562.26 663.22 2.42112 0.543 0.709 1826

400. 000 659. 670 2.779 0. 35978 2. 132 584. 49 585.23 691.62 2.45519 0.561 0.722 1866

440.000 899.670 2.642 0.37853 2.005 617. 15 606.81 720.96 2.46832 0.580 0.735 1904

254
METHANE ISOBAR ATP* 1700.0 PSI

T T OEM VOL OP/OT OP/OD E H S CV CP M DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 0TU/LB 9TU/LB BTU/L 8/R BTU/LB/R BTU/L3/R FT/S

-291.109 166.561 26.410 0.03519 164.039 3036. 32 94.16 105.24 1.01860 0.506 0.777 5225

-290.000 169.670 26.361 0.03526 162.031 3000.03 95.02 106.12 1.02403 0.505 0.778 5206

-200.000 179.670 27.931 0.03500 152.730 3533.40 102.43 113.70 1.06865 0.507 0.768 5047

-220.000 16B.670 27.496 0.03637 143.177 3269. 26 110. 04 121.49 1. 11184 0.508 0.799 4002

-260.000 199.670 27.055 0.03696 134.141 3011.57 117.00 129.44 1. 15313 0.506 0. 908 4719

-250.000 209.670 26.605 0.03759 125.583 2763. 01 125.60 137.51 1.19280 0.502 0.815 4559

-240.000 219.670 26. 145 0.03025 117.461 2525.33 133.62 145.66 1.23091 0.496 0.821 4402

-230.000 229.670 25.674 0.03095 109.732 2299.46 141.63 153.09 1.26758 0.489 0.827 4244

-220.000 239.670 25.190 0.03970 102.363 2005.93 149.70 162.20 1.30301 0.404 0.836 4004

-210.000 249.670 24.692 0.04050 95.319 1004.65 157.06 170.60 1.33738 0.401 0.847 3920 -200.000 259.670 24.170 0.04136 06.574 1695.30 166.12 179.14 1.37089 0.479 0.960 3754

-190.000 269.670 23.647 0. 04229 62. 103 1517. 34 174,50 107.01 1.40 365 0.470 0.874 3588

-160.000 279.670 23.095 0.04330 75.604 1350. 14 102.99 196.62 1.43573 0.473 0.908 3424

•170.000 209.670 22.521 0.04440 69.901 1193. 06 191.58 205.55 1.46711 0.466 0. 899 3266

-160.000 299.670 21.922 0.04562 64.137 1045.64 200.23 214.59 1.49770 0.454 0.906 3113

-150. 000 309. 670 21.293 0. 04696 50.579 907.56 200.94 223.73 1.52777 0.442 0.920 2959

-140.000 319.670 20.629 0. 04047 53.210 770.03 217.00 233.06 1.55741 0.442 0.948 2702

-130.000 329.670 19.924 0.05019 40.040 659.74 226.00 242.60 1.58702 0.43S 0.977 2609

-120.000 339.670 19. 170 0.05217 43.071 550.09 236.20 252.62 1.61673 0. 437 1. 013 2434

-110. 000 349. 670 10.357 0.05447 30.299 453.11 245.02 262.97 1.64675 0.436 1.050 2257

-100.000 359.670 17.476 0.05722 33.756 367. 34 255.00 273.02 1.67733 0.437 1.113 2063

-90.000 369.670 16.516 0.06055 29.477 294. 36 266. 21 205.27 1.70874 0.439 1.179 1915

-60.000 379.670 15.472 0.06463 25.502 234.66 277. 09 297.44 1.74121 0.441 1.255 1758

-70.000 369.670 14.347 0.06970 21.076 108.71 280.44 310.36 1.77406 0.444 1. 333 1620 -60.000 399.670 13. 169 0.07594 10.650 157.31 300.11 324.02 1.00941 0.443 1.306 1511 -50.000 409.670 12.006 0.00329 15.904 141.75 311.70 337.92 1.04376 0.442 1. 381 1432

-40.000 419.670 10.954 0.09129 13.705 140.67 322.66 351.39 1. 07626 0.441 1. 306 1389

-30.000 429.670 10.057 0.09943 12.002 145.51 332.70 364.00 1.90596 0.4 39 1.218 1368

-20.000 439.670 9.296 0.10756 10.664 151.96 341.93 375.79 1.93300 0.437 1.142 1356

-10.000 449.670 0.647 0.11565 9.592 160. 21 350.47 386.67 1.95801 0.435 1.375 1354

0. 000 459.670 0.094 0.12355 0.722 171. 14 350.41 397.30 1.90095 0. 434 1.012 1359

10.000 469.670 7.622 0.11120 6.009 103.63 365.63 407. 13 2. 00210 0.433 0.956 1370 20.000 479.670 7.217 0.13057 7.416 196.62 372.03 416.45 2.02174 0.433 0.910 1384

30. 000 409.670 6.064 0.14569 6.916 209.69 379.49 425.35 2.04011 0.433 0.872 1399

40.000 499.670 6.554 0.15256 6.467 222.66 305.07 433.90 2.05740 0.433 0. 840 1415

50.000 509.670 6.279 0. 15926 6.115 235.40 392.03 442.17 2.07378 0.4 34 0.814 1431 60.000 519.679 6.033 0.16576 5.709 240. 12 390.01 450.19 2.00937 0.435 0.792 1447 70.000 529.670 5.611 0.17209 5.500 260.56 403.05 450.02 2.10428 0.436 0.773 146 3 60.000 539.670 5.610 0.17027 5.243 272. SO 409.56 465.67 2.11860 0. 436 0.758 1479

100. 000 559.670 5.257 0. 19023 4.604 296.67 420.70 400.58 2.14572 0.442 0.734 1510 120.000 579.670 4.957 0.29173 4.441 319.76 431.57 495.07 2. 17117 0.447 0.717 1541 140.000 599.670 4.696 0.21205 4.135 342. 10 442.27 509.20 2. 19526 0.453 0.705 1570 160.000 619.670 4.471 0.22365 3.074 363. 74 452. 60 523.28 2. 21823 0.460 0.696 1598

100.000 639.670 4.270 0.23410 3.640 304.74 463.43 537.15 2.24027 0.467 0.691 1625

200.000 659.670 4.091 0.24446 3.449 405.17 473.99 550.95 2.26150 0.474 0.689 1651

220.000 679.670 3.929 0.25454 3.274 425. 06 404.56 564.71 2.20205 0.482 0.668 1676

240.000 699.670 3.702 0.26443 3.117 444.46 495. 22 570.46 2.30200 0.490 0. 680 1700

200.000 739.670 3.524 0.20375 2.049 401.99 516.76 606.00 2.34039 0.500 0.693 1747 320.000 779.670 3.305 0. 30254 2.626 510. 05 530.73 633.97 2.37710 0.525 0.702 1790

360.000 019.670 3.116 0.32092 2.442 552.00 561.22 662.25 2.41246 0.544 0.712 1032

400.000 059.670 2.950 0.33695 2.282 506.67 504.28 690.90 2.44669 0.562 0.725 1872

440.000 099.670 2.604 0.35670 2.144 619.59 607.94 720.22 2.47993 0.580 0.738 1910

25 S
METHANE ISOBAR AT P = 1800.0 PSI

T T OEN VOL DP/OT DP/DD E H S CV CP w DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

-290.800 168. 870 28.431 0.03517 163.875 3848,07 94.23 105.95 1.01903 0.507 0.777 5228

-290.000 169.670 28.388 0.03523 162.993 3820. 09 94.66 106.61 1.02305 0.506 0.777 5213

-280.000 179.670 27.959 0. 0 3577 152.944 3555.72 102.26 114.18 1.06783 0.507 0

.

7 87 5056

-270.000 189.670 27.527 0. 03633 143.438 3293. 43 109.85 121.96 1.11077 0.509 0.798 4894

-260.000 199.670 27.088 0.03692 134.447 3037.28 117.60 129.90 1. 15201 0.507 0.807 4732

-250.000 209.670 26.641 0.03754 125.932 2790.02 125.45 137.96 1. 19162 0.503 0.814 4574

- 290. 000 219. 670 26. 164 0.03819 117.852 2553.44 133.37 146.09 1.22966 0.496 0.819 4418

-230.000 229. 670 25. 717 0. 0 3888 110. 166 2328. 56 141.34 154.30 1.26625 0.490 0.825 4262

-220.000 239.670 25.238 0.03962 102.840 2115.68 149.38 162.59 1.30158 0.485 0.833 4104

-210.000 249.670 24.745 0. 04(141 95.841 1915.41 157,50 170.97 1.33586 0.462 0.844 3942

-200.000 259. 670 24.237 0.04126 89.143 1726. 87 165.72 179.48 1.36925 0.460 0. 857 3779

-190. 000 269. 670 23. 712 0. 04217 82.721 1549.72 174.06 186.11 1.40188 0.478 0.370 3615

-180.000 279.670 23.168 0.04316 76.556 1363. 37 182.49 196.86 1.43380 0.474 0.883 3455

-170.000 289.670 22.604 0.04424 70.629 1227.20 191. 02 205.76 1.46500 0 . 466 0.893 3300

-160.000 299.670 22.016 0.04542 64.928 1080.71 199.59 214.73 1.49545 0.455 0. 901 3151

-150.000 309. 670 21.401 0. 04673 59.439 943.59 208.22 223.79 1.52518 0.443 0.911 3000

- 140. 000 319.670 20.755 0.04818 54. 155 615.76 216.97 233.03 1.55449 0.442 0.936 2828

-130.000 329. 670 20.072 0.04982 49.070 697.44 225.91 242.51 1.58371 0.439 0.962 2662

-120.000 339.670 19.345 0.05169 44.186 589. 12 235. 05 252.28 1.61290 0. 436 0.993 2493

-110. 000 349. 670 18.569 0.05385 39.514 491.49 244.46 262.41 1.64227 0. 436 1.032 2323

-100. 000 359.670 17.735 0.05639 35. 074 405.32 254.16 272.95 1.67201 0.4 36 1.079 2156

-90. 000 369.670 16.836 0.05940 30.893 331. 27 264.21 284.00 1.70231 0.437 1.133 1994

-80.000 379.670 15.869 0.06301 27.008 269.72 274.63 295.64 1.73335 0.439 1.194 1643

-70.000 389.670 14.836 0.06740 23.449 220.87 265.43 307.90 1.76522 0.442 1.258 1707

-60.000 399.670 13.755 0.07270 20.252 185.00 296.51 320.74 1.79777 0.440 1.307 1596

-50.000 409. 670 12.666 0.07895 17.460 162.78 307.63 333.94 1.83039 0.440 1.326 1507

-40. 000 419.670 11.634 0. 08596 15.127 154.45 318.42 347.07 1. 86205 0. 439 1.290 1449

-30.000 429.670 10.720 0.09328 13.262 156.46 328.52 359.61 1.89159 0.436 1.217 1418

-20. 000 439.670 9.934 0.10067 11.785 161.79 337.66 371.41 1.91875 0.437 1.145 1402

-10.000 449.670 9.256 0. 10803 10.595 168.36 346.54 382.55 1.94380 0.436 1.064 1393

0.000 459. 670 8.670 0. 11534 9.621 176. 46 354.67 393.11 1.96702 0.435 1.029 1391 10.000 469.670 8.163 0.12251 8.816 186.89 362.30 403.13 1.98859 0.434 0.977 1396

20.000 479.670 7.723 0.12949 8. 144 198.76 369.50 412.66 2.00868 0.434 0.931 1406

30.000 489. 670 7.339 0.13625 7.577 211.19 376.35 421.77 2.02746 0.434 0.891 1416

40. 000 499. 670 7.002 0. 14281 7. 092 223. 76 382.91 430.51 2. 04514 0.434 0.358 1432

50.000 509.670 6.703 0.14919 6.673 236. 31 389. 23 438.95 2.06186 0.435 0.831 1446

60.000 519.670 6.436 0.15539 6.306 248.75 395.34 447.14 2. 07777 0.436 0.807 1461 70.000 529.670 6.195 0.16143 5.982 261.04 401.30 455.11 2.09297 0. 437 0.768 1476

80.000 539. 670 5. 976 0. 16734 5.695 273. 16 407.13 462.90 2, 10754 0.439 0.771 1491 100.000 559. 670 5.594 0.17877 5.204 296.96 418.47 478.06 2. 13512 0.443 0.745 1521

120. 000 579.670 5.27 0 0.18976 4.800 320.04 429.51 492.76 2. 16094 0.448 0.727 1550 140.000 599.670 4.990 0.20039 4.462 342.44 440.36 507.16 2. 18535 0.454 0.713 1579

160. 000 619. 670 4. 746 0.21070 4.173 364.20 451.10 521.33 2.20859 0.461 0.704 1606 180.000 639.670 4.530 0. 22075 3.924 365. 35 461.77 535.35 2.23086 0.468 0.698 1633

200. 000 659.670 4.337 0.2 3056 3.706 405. 93 472. 42 549.27 2.25230 0.475 0.695 1658

220. 000 679.670 4.164 0.24017 3.513 425. 99 463. 10 563.15 2.27303 0.483 0.693 1683

240. 000 699.670 4.006 0.24960 3.342 445.57 493.83 577.02 2.29314 0.491 0.694 1707

280. 000 739.670 3.731 0.26799 3.050 483.44 515.50 604.83 2.33179 0.508 0.696 1753

320.000 779.670 3.498 0.28588 2.809 519. 83 537.59 632.86 2.36872 0.526 0.705 1797

360.000 819.670 3.297 0.30335 2.607 554. 95 560.16 661.29 2.40426 0.545 0.716 1638

400.000 859.670 3.120 0. 32047 2.434 589.02 563.33 690.15 2.43862 0.563 0. 727 1878

440.000 899. 670 2.965 0.33732 2.285 622. 17 607.07 719.50 2.47199 0.581 0.740 1916

2 56
METHANE ISOBAR ATP* 1900.0 PSI

T T OEN VOL DP/DT DP/DO r H S CV CP DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 3TU/LB 8TU/LB BTU/LB/R BTU/LB/R 0TU/L8/R FT/S

• 290 . **90 169. 180 28.444 0.03516 163.712 3859.73 94. 30 106.67 1.01947 0.507 0.776 5231

-290.000 169.670 26.414 0.03519 163.152 3839.92 94.71 107.09 1.02207 0.507 0.777 5221

-2S0.000 179.670 27.987 0.03573 153.155 3577.82 102. 09 114.66 1. 06681 0.508 0. 787 5066

-270.000 189.670 27.557 0.03629 143.696 3317.40 109.66 122.43 1.10971 0.509 0.797 4905

-260.000 199.670 27.120 0.03687 134.749 3062. 80 117.39 130.36 1. 15090 0.506 0.806 4745

-250.000 209.670 26.676 0.03749 126.276 2816.82 125.22 138.41 1.19045 0.503 0.812 4589

-240.000 21B.670 26.223 0.03813 118.237 2581. 34 133.11 146.53 1.22842 0. 497 0.818 4435

-230.000 229.670 25.760 0.03882 110.593 2357.41 141.06 154.72 1.26493 0.491 0.823 4260

-220. 000 239.670 25.285 0.03955 103.309 2145.58 149.07 162.99 1.30018 0.486 0.831 4124

-210.000 249.670 24.797 0.04033 96.354 1945.90 157. 16 171.35 1.33435 0.483 0.841 3964

-200.000 259.670 24.294 0.04116 89.700 1758. 13 165.34 179.82 1. 36763 0. 481 0. 354 3803

-190.000 269.670 23. 776 0.04206 83.326 1581.76 173.63 188.42 1.40014 0.479 0.867 3642

-180. 000 279.670 23.240 0.04303 77.211 1416.22 182.01 197.15 1.43191 0.475 0.878 3484

-170.000 289.670 22.684 0.04408 71.339 1260.89 190.47 205.98 1.46294 0.467 0.888 3333

-160.000 299.670 22.107 0. 04523 65.696 1115. 26 198.98 214.90 1. 49319 0.455 0.895 3187

-150.000 309.670 21.505 0.04650 60.271 979.01 207.52 223.88 1.52267 0.443 0.903 3041

-140.000 319.670 20.875 0.04790 55.057 852.01 216. 17 233.02 1.55169 0.443 0.926 2873

-130.000 329.670 20.211 0.04943 50.048 734.39 224.98 242.39 1.58055 0.439 0.949 2712

-120. 000 339.670 19.510 0. 05126 45.247 626. 55 233.98 252.01 1.60929 0. 436 0.976 2548

-110.800 349.670 18.765 0. 05329 40.662 529. 06 243. 19 261.94 1.63809 0.435 1.010 2385

-100.000 359.670 17.971 0.05565 36.310 442.55 252.65 272.23 1.66711 0.435 1. 050 2224

-90.000 369. 670 17.123 0.05840 32.214 367.58 262.40 282.95 1.69650 0.4 36 1.095 2068

-80.000 379.670 16.218 0. 06166 28.403 304.46 272.46 294.15 1.72640 0.438 1.146 1922

-70.000 389.670 15.259 0.06554 24.902 253. 24 282. 82 305.67 1.75687 0.440 1.198 1789

-60.000 399.670 14.257 0.07014 21.735 213.98 293.41 318.09 1.78782 0.438 1.242 1677

-50.800 409.670 13.239 0.07553 18.930 186. 85 304.08 330.66 1. 81888 0.438 1. 268 1583

-40. 000 419.670 12.248 0. 08164 16.517 172. 11 314.60 343. 33 1.84944 0.438 1.259 1514

-30.000 429.670 11.336 0.08822 14.520 168. 89 324.66 355.70 1.87858 0.437 1.210 1472 -20.000 439.670 10.532 0.09495 12.910 172. 54 334. 08 367.46 1.90568 0.437 1.146 1448

-10.000 449.670 9.834 0. 10169 11.608 178.17 342.86 378.63 1.93077 0. 4 36 1. 087 1435

0. 000 459. 670 9.224 0. 10841 10.537 184.83 351.10 389.24 1.95411 0.4 35 1.036 1428

10.000 469.670 8.690 0. 11508 9.645 192.85 358. 88 399.37 1.97590 0.435 0.990 1427 20.000 479.670 6.221 0.12164 8.895 202.83 366.26 409.05 1.99631 0.434 0.947 1431 30.000 489.670 7.810 0.12804 8.261 214.16 373.28 418.33 2. 01544 0.435 0.908 1440

40.000 499.670 7.447 0.13428 7.718 226.09 379.99 427.24 2.03345 0.435 0.875 1451 50.000 509.670 7.125 0. 14036 7.249 238.22 386.45 435.84 2. 05049 0.436 0.846 1464

60.000 519.670 6.636 0.14628 6.840 250. 37 392.71 444.17 2.06669 0.437 0.822 1477 70.000 529.670 6.577 0. 15205 6.480 262.46 398. 79 452.28 2.08216 9. 438 0.801 1491 80.000 539.670 6. 341 0.15770 6.160 274.43 404.73 460.21 2.09697 0.440 0.784 1505

100.000 559.670 5.930 0.16863 5.616 298. 00 416.26 475.59 2.12497 0 . 444 0.756 1533 120.000 579.670 5.582 0.17915 5.169 320.98 427.48 490.51 2.15116 0.449 0.736 1561 140.000 599.670 5.282 0. 18932 4.796 343. 37 438.47 505. 08 2. 17587 0.455 0.722 1588 160.000 619.670 5.020 0. 19919 4.479 365. 17 449. 33 519.41 2. 19938 0.462 3.712 1615 180.000 639.670 4.789 0.20880 4.206 386.40 460.11 533.57 2.22188 0.469 0.705 1641 200.000 659.670 4.563 0.21819 3.967 407. 10 470.87 547.63 2.24352 0.476 0.701 1666

220. 000 679.670 4. 398 0. 22737 3.757 427. 28 481.63 561.63 2.26442 0.484 0.699 1691 240.000 699.670 4.231 0.23638 3.571 447.00 492.44 575.60 2.28468 0.492 0.699 1715

280. 000 739.670 3.93 8 0.25394 3.253 485. 16 514.25 603.60 2.32359 0.509 0.702 1760

320. 000 779.670 3.690 0.27100 2.992 521.83 536.46 631.81 2.36074 0.527 0.709 1803

360. 000 819.670 3.476 0.28765 2.774 557.22 559.15 660.36 2.39644 0.545 0.719 1845

400.000 859.670 3.290 0.30397 2.588 591.53 582.39 689.33 2.43096 0.564 0.730 1884

440.000 899.670 3.125 0.32000 2.427 624.91 606.20 718.79 2.46445 0.582 0.743 1922

257
METHANE ISOBAR AT P = 2000.0 PSI

T T DEN VOL DP/DT OP/OD E H S CV CP H DEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LP BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

-290. 18? 169.488 28.457 0.03514 163.549 3871.29 94.37 107.38 1. 01991 0.508 0.776 5234

-290.000 169. 670 28.440 0.03516 163.308 3859.51 94.56 107.58 1.02110 0.508 0.776 5228

-280. 000 179. 670 28. 015 0. 03569 153. 362 3599.71 101.92 115.14 1. 06580 0.509 0.786 5075

-270.000 189.670 27.587 0.03625 143.950 3341.16 109.48 122.90 1. 10865 0.510 0.796 4916

-260.000 199.670 27.153 0.03683 135.046 3088.10 117. 18 130.82 1.14980 0.509 0.305 4758

-250.000 209.670 26.712 0.03744 126.615 2843.42 124.99 136.66 1.18929 0.504 0. 611 4603

-240. 000 219. 670 26. 262 0. 03806 118.617 2609.02 132.86 146.97 1.22719 0.498 0.816 4451

-230.000 229.670 25.802 0.03876 111. 014 2386.03 140.79 155.14 1.26363 0.492 0.822 4298

-220.000 239.670 25.331 0.03948 103.771 2175. 04 148.77 163.39 1.29880 0.487 0.829 4144

-210.000 249.670 24. 843 0.04025 96.858 1976.14 156.62 171.72 1. 33287 0. 483 0. 839 3986

-200. 000 259. 670 24.350 0.04107 90.248 1789.10 164.96 180.17 1.36605 0.482 0.651 3827

- 190. 000 269.670 23.838 0.04195 83.919 1613.48 173.20 166.74 1.39843 0.480 0.863 3666

-180. 000 279.670 23.310 0.04290 77. 852 1448.69 181.54 197.43 1.43006 0.475 0.874 3513

-170.000 289.670 22.763 0.04393 72.031 1294. 15 189. 95 206.22 1.46093 0.467 0.862 3364

-160.000 299.670 22.196 0.04505 66.443 1149. 33 198.39 215.07 1.49098 0.456 0.866 3222

-150.000 309.670 21.606 0.04628 61.077 1013.87 206.64 223.99 1.52025 0.443 0.895 3060

- 140. 000 319.670 20.990 0.04764 55.927 887.62 215.40 233.05 1.54900 0.443 0.917 2917

-130.000 329.670 20.344 0. 04915 50.987 770. 65 224. 10 242.31 1.57753 0.439 0.937 2760

-120.000 339.670 19.665 0.05085 46.259 663.25 232.96 251.79 1.60587 0.436 0.961 2601

-110.000 349.670 18.948 0.05278 41.751 565.89 242.00 261.55 1.63417 0.435 0.991 2443

-100. 000 359.670 18.183 0.05498 37.476 479.09 251.26 271.62 1.66258 0.4 35 1.025 2286

-90.000 369. 670 17.382 0.05753 33.454 403.33 260.76 262.06 1.69120 0.435 1.064 2137

-80. 000 379.670 16.529 0.06050 29.706 338. 84 270.51 292.91 1.72016 0.436 1.107 1995

-70. 000 389.670 15.631 0.06398 26.255 285.65 280.50 304.20 1.74950 0.438 1. 151 1665

-60.000 399.670 14.695 0.06805 23.118 243.63 290.70 315.90 1.77915 0.436 1. 186 1754

-50. 000 409. 670 13.741 0.07278 20.312 212.73 300.96 327.93 1. 80888 0.436 1.215 1657

-40.000 419. 670 12.797 0. 07814 17.855 192.98 311.19 340.13 1.83630 0.436 1.220 1561 -30.000 429.670 11.903 0.08401 15.765 184.10 321.12 352.23 1.86679 0.436 1.194 1526

-20.000 439.670 11.093 0.09014 14.036 184.28 330.55 363.93 1.89372 0.436 1.143 1496

-10.000 449.670 10.379 0.09635 12.624 188.79 339.40 375.08 1.91660 0.436 1.068 1476

0. 000 459. 670 9.752 0.10255 11.460 194.64 347.73 365.71 1.94218 0.435 1.039 1467

10.000 469.670 9.198 0.10672 10.487 201. 37 355.62 395.89 1.96407 0.435 0.996 1462

20.000 479.670 8.707 0.11485 9.664 209. 29 363.12 405.65 1.96466 0.435 0.958 1461

30.000 489.670 6.272 0.12089 8.964 218. 92 370.28 415.05 2.00404 0. 435 0.922 1465

40. 000 499.670 7.886 0.12681 8. 363 229.79 377.13 424.10 2.02234 0.436 0.889 1473

50.000 509.670 7.542 0.13259 7.843 241.28 383.73 432.84 2.03965 0.437 0.860 1483

60.000 519.670 7.234 0.13824 7.390 253.00 390.11 441.31 2.05611 0.438 0.835 1495

70.000 529.670 6.956 0.14376 6.992 264.79 396. 31 449.55 2. 07182 0. 439 0.814 1507

SO. 000 539.670 6.704 0.14916 6.638 276.54 402.35 457.59 2.08686 0.441 0.795 1520 100.000 559.670 6.265 0.15962 6.038 299. 60 414.08 473.20 2.11526 0.445 0.767 1546

120. 000 579.670 5.893 0. 16970 5.548 322. 60 425.45 466.30 2.14179 0.450 0.745 1573

140.000 599.670 5.573 0.17945 5.139 344. 90 436.59 503.05 2. 16680 0.456 0.730 1599

160.000 619.670 5.294 0.18891 4.792 366.67 447.57 517.54 2. 19056 0.463 0.719 1625

180. 000 639.670 5.047 0.19812 4.494 367.93 458.47 531.84 2.21328 0.470 0.712 1650 200.000 659. 670 4.828 0.20711 4.234 408.68 469.32 546.02 2.23511 0.477 0.707 1675

. 220.000 679-670 4.632 0. 21590 4.006 428. 95 480. 17 560.13 2.25616 0.465 0.704 1699

240.000 699.670 4.454 0.22453 3.803 448.77 491. 06 574.21 2.27660 0.493 0.704 1722 280.000 739.670 4.144 0.24133 3.460 487. 15 513.01 602.39 2.31576 0.510 0.706 1767

320.000 779. 670 3.881 0.25765 3. 178 524. 06 535.34 630.76 2.35311 0.528 0.713 1810

360. 000 819.670 3-655 0. 27356 2.943 559.69 558.13 659.44 2.36699 0.546 0. 722 1851

400. 000 859.670 3.458 0. 28915 2.743 594.22 561.45 688.54 2.42364 0.565 0.733 1891 440.000 899.670 3.285 0.30445 2.570 627. 80 605.35 716.10 2.45725 0.583 0.745 1929

258
METHANE ISOBAR ATP* 2200,0 PSI

T T OEN VOL DP/OT DP/DD E H S CV CP M OEG F DEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB BTU/LB 8TU/LB/R BTU/LB/R 8TU/LQ/R FT/S

289.565 170. 105 28.683 0.03511 163.228 3896.16 96.51 108.81 1.02080 0.510 0.775 5239

280. 000 179.670 20.070 0.03562 153.766 3662.86 101.59 116.10 1.06381 0.510 0.766 5093

270. 000 189. 670 27.666 0. 03617 166.666 3388. 07 109. 11 123.85 1.10657 0.512 0.795 6938

260.000 199.670 27.217 0.03676 135.628 3138.12 116.78 131.75 1. 16762 0.510 0.803 6783

250.000 209.670 26.782 0.03736 127.279 2896. 01 126.55 139.76 1. 18700 0.506 0.809 6632

260.000 219.670 26.338 0.03797 119.360 2663.78 132.38 167.86 1.22677 0.699 0.813 6682

230. 000 229.670 25.885 0. 03863 111.836 2662.66 160.25 155.99 1 . 26 1 0 7 0.693 0.818 6333

220.000 239.670 25.622 0.03936 106.672 2233.27 168.17 166.19 1.29608 0.688 0.825 6182

210.000 269.670 26.967 0.06008 97.839 2035. 65 156.16 172.69 1.32997 0.685 0.836 6028

200.000 259.670 26.660 0.06088 91.312 1850.22 166.23 180.88 1. 36296 0.683 0. 665 3873

190. 000 269.670 23.960 0.06176 85.069 1675.97 172.39 189.39 1. 39510 0.681 0.857 3719

180.000 279.670 23.665 0.06265 79.092 1512.57 180.63 198.01 1.62667 0.677 0.866 3569

170.000 289.670 22.916 0.06366 73.366 1359.66 188.93 206.71 1. 65706 0.669 0.873 3626

160.000 299.670 22.365 0.06671 67.878 1216.09 197.25 215.66 1.68675 0.657 0. 877 3289

150. 000 309.670 21.796 0.06588 62.619 1082.07 205.56 226.25 1.51561 0.665 0.862 3156

160. 000 319.670 21.207 0.06716 57.582 957. 15 213.95 233.16 1.56388 0.666 0.900 2998

130.000 329.670 20.592 0.06856 52.763 861.31 222. 66 262.26 1.57186 0.660 0.916 2850

120.000 339.670 19.951 0. 05012 68.162 736. 68 231.08 251.50 1.59969 0. 637 0.936 2700

110.000 369.670 19.280 0.05187 63.783 637.57 239.86 260.97 1.62696 0.635 0.959 2552

100. 000 359.670 18.577 0.05383 39.636 550.32 268.75 270.68 1.65636 0.636 0.985 2605

•90.000 369.670 17.839 0.05606 35.736 673.25 257.86 280.68 1.68177 0.636 1.016 2266

•80.000 379.670 17.067 0.05859 32.092 606. 53 267. 11 290.98 l. 70926 0.635 1.066 2129

-70.000 389.670 16.262 0.06169 28.723 350. 13 276.55 301.60 1.73687 0.636 1.078 2006

-60.000 399.670 15.629 0.06681 25.639 303. 82 286.12 312.53 1.76657 0.633 1.106 1896

-50.000 609. 670 16.578 0.06860 22.866 267.36 295.77 323.71 1.79221 0.633 1.130 1797

-60. 000 619.670 13.726 0. 07285 20.369 260. 62 305.62 335.10 1.81965 0.6 36 1.166 1716

-30.000 629.670 12.893 0.07756 18.156 222.76 316.95 366.56 1.86661 0.636 1. 162 1668

-20.000 639.670 12. 106 0.08262 16.260 213.93 326.22 357.88 1.87268 0.636 1.121 1599

-10.000 669.670 11.379 0.08788 16.656 212.72 333.11 368.91 l. 89751 0.6 35 1.086 1568

0. 000 659.670 10.727 0. 09322 13. 313 216. 33 361.56 379.56 1.92088 0.635 1.061 1569

10. 000 669.670 10.165 0.09857 12.185 221.65 369.59 389.76 1.96266 0. 635 1.001 1537

20.000 679.670 9.626 0.10390 11.226 227.79 357.25 399.58 1.96356 0. 636 0.966 1530 30.000 689.678 9.157 0.10921 10.606 236.60 366.59 609.08 1.98317 0.6 36 0. 935 1526

60. 000 699.670 8.736 0. 11667 9.692 262. 37 371.66 618.29 2. 00179 0.637 0.907 1526

50.000 509.670 8.356 0.11968 9.073 251.66 378.67 627.23 2.01950 0.638 0.881 1530

60.000 519.670 8.012 0.12681 8.530 261.56 385.07 635.91 2.03638 0.660 0.857 1537

70.000 529.670 7.702 0.12986 8.053 272.29 391.67 666.37 2. 05269 0.661 0. 835 1565

80. 000 539.670 7.620 0.13678 7.630 283.31 397.71 652.62 2.06793 0.663 0.816 1555

100. 000 559.670 6.926 0.16638 6.916 305.61 609.80 668.62 2.09706 0.667 0.785 1577

120.000 579.670 6.508 0. 15366 6.331 327. 82 621.68 686.08 2. 12619 0.652 0.762 1600

160. 000 599.670 6.169 0.16263 5.867 369.73 632.89 699.16 2. 16976 0.658 0.765 1626

160.000 619.670 5.836 0.17135 5.638 371.28 666. 11 513.92 2.17398 0.665 0.733 1667

180. 000 639.670 5.560 0.17985 5.087 392.61 655.22 528.68 2.19711 0.672 0.726 1671 200.000 659.670 5.315 0.18813 6.783 613. 13 666.26 562.90 2.21931 0.679 0.718 1696

220. 000 679.670 5.096 0. 19626 6.516 633.66 677. 29 557.23 2.26071 0.687 0. 715 1717 260.000 699.670 6.897 0.20619 6.281 653. 36 688.33 571.51 2.26161 0.695 0.713 1760 280.000 739.670 6.552 0.21967 3.882 692.00 510.56 600.05 2.30107 0.512 0.716 1783

320.000 779. 670 6.261 0.23668 3.557 529.26 533.11 628.72 2.33882 0.530 0.720 1825

360.000 819.670 6. Oil 0.26931 3.287 565. 26 556. 10 657.67 2. 37503 0.568 0.728 1866

600.000 859.670 3.793 0.26361 3.058 600.13 579.60 686.99 2.60996 0.566 0.730 1906

660.000 899.670 3.602 0.27765 2.861 636. 05 603.65 716.76 2.66380 0.586 0. 750 1962

259
METHANE ISOBAR AT P = 2400.0 PSI

T T OEN VOL DP/DT OP/OD e H S CV CP w DEG F OEG R LB/CUFT CUFT/L a PSI/R PSICUFT/LB 8TU/LP BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

- 288. 951 170.719 26.508 0.03508 162.910 3916.65 94.66 110.25 1.02168 0.511 0.775 5245

-280. 000 179.670 28. 125 0.03556 154. 158 3685. 11 101.26 117.06 1.06184 0.512 0.783 5111

-270.000 169.670 27.705 0. 03609 144. 928 3434. 15 108.76 124.80 1.10452 0-513 0. 793 4959

-260.000 199.670 27.280 0.03666 136.194 3187.33 116.39 132.68 1. 14548 0.512 0.801 4807

-250. 000 209.670 26.850 0.03724 127.924 2947. 81 124. 12 140.67 1.18475 0.507 0.806 4659

-240.000 219.670 26.412 0.03736 120.082 2717.73 131.90 148.73 1.22240 0.501 0.810 4513

-230.000 229.670 25. 966 0. 03851 112.634 2498. 43 139.72 156.84 1.25857 0.495 0.815 4367

-220.000 239.670 25.510 0.03920 105.545 2290.63 147.59 165.01 1.29342 0.489 0.821 4219

-210.000 249.670 25.044 0.03993 98.789 2094.61 155.52 173.26 1.32715 0.486 0.830 4069

-200.000 259.670 24.567 0.04071 92.340 1910.29 163.52 181.61 1. 35993 0.4 64 0.840 3918

-190. 000 269.670 24.077 0. 04153 86.177 1737. 30 171.61 190.06 1.39188 0.462 0.851 3767

-180.000 279.670 23.574 0.04242 80.282 1575. 16 179.77 198.62 1.42301 0.478 0.859 3622

-170.000 289.670 23.057 0.04337 74.641 1423.30 187.97 207.24 1.45331 0.470 0.865 3484

-160.000 299.670 22.525 0.04440 69.243 1281.20 196.17 215.90 1.48271 0.458 0. 867 3353 -150. 000 309. 670 21.976 0. 04550 64.078 1148.42 204.36 224.59 1.51121 0.446 0.870 3223

-140.000 319.670 21.408 0.04671 59.138 1024.64 212.61 233.37 1.53907 0.445 0.886 3074

-130.000 329.670 20.821 0.04803 54.421 909.76 220.94 242.29 1.56655 0.440 0.899 2933

-120.000 339.670 20.211 0.04948 49.925 603. 81 229. 36 251.35 1.59363 0.437 0.915 2791

-110.000 349. 670 19.578 0. 05108 45.653 706.92 237.89 260.59 1.62043 0. 435 0.933 2650

- 100. 000 359.670 18.919 0.05266 41.609 619. 33 246.53 270.02 1.64703 0.434 0.954 2512

-90.000 369.670 18.234 0.05464 37. 803 541. 25 255.30 279.68 1.67351 0.433 0.977 2378

-80.000 379.670 17.523 0.05707 34.244 472.78 264.20 289.57 1. 69990 0.433 1.001 2250 -70.000 389.670 16. 766 0.05957 30.941 413. 66 273.23 299.71 1.72626 0.434 1.026 2129

-60.000 399.670 16.029 0. 06239 27.901 364.28 282.35 310.08 1.75255 0.431 1.047 2024

-50. 000 409. 670 15.257 0.06554 25.126 323.70 291.52 320.65 1.77867 0.431 1.067 1926 -40.000 419.670 14.481 0. 06906 22.616 291.76 300.70 331.39 1.80458 0.432 1. 061 1840 -30.000 429.670 13.712 0.07293 20.370 268.09 309.63 342.25 1.83013 0.432 1.087 1768

-20.000 439.670 12.966 0.07712 16.385 252.25 316.83 353.10 1.85511 0.433 1.082 1709

-10. 000 449.670 12.259 0.08157 16.653 243.71 327.59 363.84 1.87926 0.434 1.064 1665

0.000 459.670 11.603 0. 03618 15. 161 241. 61 336. 04 374. 35 1.90237 0.434 1.036 1634

10.000 469.670 11.005 0.09087 13.887 244. 25 344.15 384.54 1.92430 0.435 1.002 1614 20.000 479.670 10.464 0.09556 12.798 249. 09 351.92 394.39 1.94506 0.4 36 0.969 1602 30.000 469.670 9.975 0.10025 11.861 254.82 359.36 403.93 1.96476 0.437 0.940 1594

40. 000 499.670 9.531 0. 10492 11.046 261. 12 366.57 413.20 1.96349 0.436 0.914 1589

50.000 509.670 9.127 0.10956 10.336 267.98 373.53 422.22 2.00137 0.439 0.891 1587 60.000 519.670 8.759 0. 11417 9.709 275.61 380.26 431.02 2.01847 0.441 0.870 1587

70.000 529.670 8.422 0. 11874 9.154 284.28 366.85 439.62 2.03486 0.442 0. 850 1591

80. 000 539.670 8.114 0. 12325 8.661 293.82 393.26 448.03 2.05059 0.444 0.832 1596

100.000 559.670 7.572 0.13207 7.625 314. 36 405.65 464.35 2.08028 0.449 0.801 1612

120.000 579.670 7.111 0. 14062 7.145 335. 59 417.62 480.11 2. 10796 0.454 0.777 1631 140.000 599.670 6.715 0.14892 6.562 356. 88 429.28 495.46 2. 13399 0.460 0. 759 1652

160. 000 619.670 6. 370 0.15699 6.107 377.99 440.73 510.49 2.15865 0.466 0.745 1673

180.000 639.670 6.066 0. 16485 5.701 398. 82 452.03 525.30 2. 18216 0.473 0.736 1695

200.000 659.670 5.796 0. 17253 5.350 419. 34 463.26 539.94 2.20470 0.461 0.729 1716

220.000 679.670 5.554 0.18005 5.043 439. 53 474.45 554.47 2.22640 0.468 0. 725 1738

240. 000 699.670 5.336 0.16742 4.772 459.37 485.64 568.93 2.24738 0.497 0.722 1759

260. 000 739.670 4.956 0.20176 4.316 498. 05 508.14 597.80 2.28750 0.514 0.722 1801 320.000 779.670 4.637 0.21566 3.946 535. 44 530.92 626.76 2.32563 0.531 0.727 1842

360.000 619.670 4.363 0.22920 3.639 571.65 554. 11 655.97 2.36216 0.549 0.734 1881 400.000 859.670 4.125 0.24243 3.379 606.78 577.76 665.52 2.39735 0.568 0.744 1919

440.000 699.670 3.915 0.25540 3.158 640.96 601.98 715.46 2.43142 0.586 0.755 1956

260
METHANE ISOBAR ATP* 2600.0 PSI

T T DEN VOL DP/DT OP/DD F H S CV CP W DEG F OEG R L8/CUFT CUFT/IB PSI/R PSICUFT/LB 0TU/LB BTU/LB 0TU/L0/R 8TU/18/R 0TU/L9/R FT/S

288. 339 171.331 28.534 0.03505 162.596 3938.77 94.81 111.68 1.02257 0.513 0.774 5250

280.000 179.670 28.179 0.03549 154.536 3726. 52 100.94 118.03 1.05989 0.513 0.782 5128

270.000 189.670 27.763 0.03602 145.396 3479.44 108.41 125.75 1. 10250 0.515 0. 791 4979

260. 000 199.670 27.343 0.03657 136.744 3235.76 116.01 133.62 1.14337 0.513 0.799 4831

250. 000 209.670 26.917 0.03715 128.551 2998. 84 123.70 141.58 1.18254 0.509 0.304 4686

240.000 219.670 26.485 0.03776 120.784 2770.90 131.44 149.62 1.22008 0.502 0.808 4543

230.000 229.670 26.045 0.0 3839 113.408 2553. 40 139. 21 157.70 1.25612 0.496 0. 812 4400

220.000 239.670 25.596 0.03907 106.393 2347.14 147.03 165.84 1.29083 0.491 0.818 4256

210.000 249.670 25. 138 0.03978 99.709 2152.48 154.90 174.05 1.32440 0.483 0.326 4109

200.000 259.670 24.670 0.04054 93.333 1969. 38 162. 84 182.35 1.35701 0.486 0.835 3961 190.000 269.670 24. 190 0.04134 87.244 1797.55 170.85 190.76 1.38876 0.484 0. 345 3814

lao.ooo 279.670 23.699 0.04220 81.426 1636. 54 178.93 199.25 1.41968 0.479 0.853 3673

170.000 289.670 23.195 0.04311 75.863 1485.80 187.05 207.81 1.44973 0.471 0.857 3539

160.000 299.670 22.677 0.04410 70.546 1344.81 195.16 216.39 1.47885 0.459 0.856 3413

150.000 309.670 22.145 0.04516 65.464 1213.11 203.23 224.97 1.50704 0.447 0.360 3289

140. 000 319.670 21.598 0.04630 60.610 1090. 33 211.35 233.64 1.53454 0.446 0.873 3146

130.000 329.670 21.033 0.04754 55.981 976.26 219.53 242.42 1.56160 0.441 0.884 3011 120.000 339.670 20.450 0.04890 51.574 870. 90 227.78 251.33 1.58820 0.438 0.997 2876

110.000 349.670 19.848 0.05038 47.390 774.23 236.12 260.37 1.61445 0.435 0.912 2741 100.000 359.670 19.226 0.05201 43.432 686. 39 244. 54 269.58 1.64040 0.434 0.929 2609

-90.000 369.670 18.583 0.05381 39.704 607. 51 253.05 278.96 1.66613 0.433 0.947 2481

-80.000 379.670 17.919 0.05581 36.213 537.63 261.66 288.53 1.69167 0.433 0.967 2359

-70. 000 389.670 17.236 0.05802 32.965 476.69 270.37 298.30 1.71707 0.433 0.987 2243

-60. 000 399.670 16.537 0. 06047 29.962 424.48 279.14 308.25 1.74229 0.430 1.002 2141 -50.000 409.670 15.826 0.06319 27.205 380.68 287.94 318.36 1.76726 0.430 1.018 2045

-40.000 419.670 15. 110 0.06618 24.691 344.90 296. 75 328.61 1.79199 0.430 1.032 1958

-30.000 429.670 14.398 0.06946 22.418 316.73 305.53 338.97 1. 81639 0.431 1. 040 1882

-20. 000 439. 670 13.698 0.07300 20.379 295.75 314.24 349.38 1.84034 0.432 1.041 1818

-10.000 449.670 13.023 0.07679 18.566 281.47 322.79 359.76 1.86368 0.433 1.034 1765

o . a o o 459.670 12.382 0.08076 16.971 273. 36 331.15 370.03 1.88627 0. 434 1.018 1725

10.000 469.670 11.784 0.08486 15.578 270.74 339.25 380. 11 1.90796 0.435 0. 996 1695

20. 000 479. 670 11.232 0.08903 14.370 272.49 347.07 389.94 1.92866 0.436 0.969 1676 30.000 489.670 10.728 0.09321 13.322 276. 62 354.62 399.49 1.94836 0.437 0. 942 1663

40.000 499.670 10.268 0.09739 12.411 282. 20 361.90 408.79 1.96717 0.438 0.917 1654

50.000 509.670 9.847 0.10155 11.611 288. 16 368.96 417.85 1.98513 0.440 0.395 1648

60.000 519.670 9.461 0. 10570 10.905 294.58 375. 81 426.70 2.00233 0.442 0.376 1645

70.000 529.670 9.106 0.10982 10.278 301. 46 382.49 435,37 2.01885 0.443 0.856 1644

80.000 539.670 8.778 0. 11392 9.718 308. 97 389. 02 443.87 2. 03474 0.446 0.842 1645

100.000 559.670 8.197 0. 12200 6.763 326. 40 401.67 460.41 2. 06484 0.450 0. 313 165 3 120.000 579.670 7.699 0.12989 7.985 345.94 413.89 476.42 2.09296 0.455 0. 789 1667

140.000 599.670 7.269 0.13758 7.340 366.24 425.77 492.01 2. 11940 0.461 0.771 1683

lbO. 000 619.670 6.893 0.14507 6.797 386.71 437.43 507.27 2. 14444 0.468 0.756 1 7P 2 180.000 639.670 6.563 0. 15238 6. 334 407.06 448.93 522.29 2. 16829 0.475 0.746 1721 200.000 659.670 6.269 0.15952 5.934 427.26 460. 33 537.13 2.19114 0.482 0.738 1741 220.000 679.670 6.005 0. 16652 5.585 447.20 471.66 551.85 2.21311 0.490 0.734 1761 240.000 699.670 5.768 0. 17338 5.277 466.86 483.01 566.48 2.23434 0.498 0.731 1781

280. 000 739.670 5.355 0. 18674 4.761 505. 35 505.76 595.67 2.27490 0.515 0. 729 1821 320.000 779.670 5.008 0.19968 4. 343 542.70 528.76 624.90 2.31339 0.533 0.733 1860 360.000 819.670 4.711 0.21228 3.997 578. 97 552.14 654.34 2.35022 0.551 0. 740 1898 400.000 859.670 4.453 0.22459 3.707 614.22 575.98 684.11 2.38567 0.569 0.749 1935

440. 000 899. 670 4.226 0.23665 3.459 648.55 600.33 714.26 2.41995 0.587 0.759 1971

261
METHANE ISOBAR AT P = 2800.0 PSI

T I DEN VOL DP/DT DP/DD E H S CV CP W DEG F DEG R LB/CUFT CUFT/L9 PSI/R PSICUFT/LB BTU/LB BTU/L

8

BTU/L B/R 8TU/LB/R BTU/L B/R FT/S

-287.728 171.942 20.559 0. 03501 162.287 3960. 54 94.96 113.11 1.02346 0.514 0.774 5255

-280. 000 179.670 28.232 0.03542 154.901 3767. 06 100.63 119.00 1.05797 0.515 0.781 5145

-270.000 189.670 27.820 0.03595 145.850 3523.90 108,07 126.70 1.10051 0.516 0.790 4999

-260.000 199. 670 27.404 0.03649 137.278 3283.41 115.63 134.55 1.14129 0.515 0.797 4855

-250.000 209. 670 26. 983 0. 03706 129.161 3049. 10 123.29 142.50 1. 18036 0.510 0.802 4712

-240.000 219.670 26.557 0.03766 121.467 2823.31 130.99 150.51 1.21780 0.504 0.905 4572

-230.000 229.670 26. 123 0.03828 114.162 2607.59 138.7? 158.57 1.25 372 0.497 0.809 4433

-220.000 239.670 25.681 0.03894 107.215 2402.84 146.49 166.6® 1.28830 0.492 0.814 4291

-210. 000 249. 670 25. 230 0. 03964 100.601 2209. 48 154.30 174.85 1.32172 0.489 0.822 4147

-200.000 259.670 24.770 0.04037 94.294 2027.55 162. 18 183.11 1.35416 0.487 0.831 4003

-190.000 269.670 24.300 0.04115 88.275 1656. 80 170.13 191.47 1.39573 0 . 465 0. 840 3860

- 180.000 279.670 23.819 0.04198 82.527 1696. 82 178.14 199.91 1.41645 0.481 0. 847 3722

-170. 000 289. 670 23. 327 0. 04287 77.037 1547.08 186.17 208.40 1.44628 0.472 0.850 3593

-160.000 299. 670 22.823 0.04382 71.793 1407.08 194.19 216.90 1.47515 0.460 0.850 3471 -150.000 309.670 22.306 0. 04483 66.785 1276. 31 202.16 225.41 1. 50305 0.448 0.850 3352

-140.000 319.670 21.776 0.04592 62.008 1154.40 210.16 233.97 1.53023 0.447 0.862 3214 -130. 000 329.670 21. 231 0.04710 57.456 1041. 07 218. 22 242.64 1.55693 0.442 0.871 3064

-120.000 339. 670 20.672 0.04838 53. 126 936.19 226.32 251.40 1.58313 0.438 0.882 2954

-110.000 349.670 20.096 0. 04976 49.017 839. 73 234.49 260.29 1.60890 0.436 0.895 2826

-100.000 359.670 19.504 0.05127 45.131 751.71 242.72 269.30 1.63432 0.434 0.909 2700

-90. 000 369.670 18.896 0.05292 41.469 672. 19 251.02 278.46 1.65943 0.433 0.924 2577

-80.000 379. 670 18.271 0. 05473 38.035 601.16 259.40 287.78 1.68429 0.433 0. 939 2459

-70. 000 389.670 1 7 . 63

1

0.05672 34.832 538. 56 267.84 297.25 1.70892 0.432 0.955 2340

-60.000 399.670 16.978 0. 05690 31.861 484. 18 276.33 306.67 1.73330 0.429 0.967 2249

-50.000 409.670 16.316 0.05129 29.121 437.74 284.83 316.61 1.75738 0.429 0.981 2154

-40.000 419.670 15.649 0.06390 26.608 398. 85 293. 35 326.48 1.78117 0.429 0.992 2067

-30.000 429.670 14. 964 0.06674 24.319 367.13 301.84 336.45 1.80464 0.430 1.000 1990 -20.000 439. 670 14. 327 0. 06980 22. 245 342. 13 310.29 346.47 1.82771 0.431 1.004 1923

-10.000 449.670 13.686 0.07307 20.379 323.41 318.63 356.51 1. 85029 0.432 1.003 1865

0.000 459.670 13.069 0.07652 18.711 310.49 326.83 366.51 1.87227 0.433 0.995 1818

10.000 469.670 12.483 0.09011 17.231 302.87 334.86 376.39 1.89354 0.434 0.981 1781 20.000 479. 670 11.933 0. 08380 15.926 299. 97 342. 67 386.12 1.91403 0.436 0.963 1753

30.000 489.670 11.422 0.08755 14.779 301. 01 350. 25 395.64 1.93369 0.437 0.941 1733 40.000 499.670 10.950 0.09132 13.774 304.76 357.59 404.94 1.95249 0.439 0.919 1720

50. 000 509. 670 10.517 0.09509 12.889 309.82 364.72 414.03 1.97049 0.440 0.898 1711

60. 000 519. 670 10.117 0. 09884 12. 106 315.51 371.66 422.91 1.98775 0,442 0.879 1704

70. 000 529.670 9.748 0. 10258 11.410 321.62 378.42 431.61 2.00434 0.444 0.862 1700 80.000 539.670 9.407 0.10631 10.786 328. 11 385. 04 440.15 2. 02032 0 . 446 0.847 1698

100.000 559.670 8.796 0.11369 9.720 342.39 397.88 456.83 2.05065 0.451 0. 821 1699

120. 000 579. 670 8.267 0.12097 6.844 359.20 410.30 473.02 2.07908 0.457 0.799 1706

140.000 599.670 7.806 0.12810 8.117 377. 89 422.39 488.60 2.10586 0.463 0.780 1718

160.000 619.670 7.404 0.13507 7.504 397. 38 434. 23 504.26 2.13122 0 . 469 0.766 1733 180.000 639. 670 7.048 0.14188 6.982 417. 11 445. 91 519.47 2. 15537 0. 476 0.755 1750

200. 000 659.670 6.732 0.14855 6.532 436. 82 457.47 534.49 2.17849 0.484 0.747 1768 220.000 679.670 6.448 0.15508 6.139 456. 39 466.96 549.37 2.20072 0.492 0.742 1786

240.000 699.670 6. 192 0. 16149 5.794 475.78 480.44 564.17 2.22217 0.500 0.738 1604

200.000 739.670 5.748 0. 17398 5.215 513. 89 503.43 593.64 2.26313 0.517 0.736 1842 320.000 779.670 5.374 0.18609 4.748 551. 04 526.64 623.13 2.30196 0.5 34 0.739 1879

360.000 819.670 5.054 0.19787 4.363 567.22 550.21 652.80 2.33908 0.552 0.745 1916

400. 000 859.670 4.776 0,20938 4.040 622.47 574.21 682.77 2.37477 0.571 0.754 1952

440.000 899.670 4.532 0.22065 3.765 656.85 598.70 713.10 2.40926 0.569 0.764 1987

262
METHANE ISOBAR AT P * 3000.0 PSI

T T DEN VOL OP/DT OP/OO E H S CV CP H DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LP 9TU/LB BTU/LB/R BTU/LB/R BTU/L9/R FT/S

287.119 172.551 28.584 0.03498 161.981 3981. 95 95. 11 114.54 1.02435 0.515 0.773 5260

280. 000 179.670 28.285 0.03535 155.255 3806. 75 100.33 119.97 1.05607 0.516 0.780 5161

270.000 189.670 27.876 0.03587 146.290 3567.55 107.73 127.66 1.09854 0.517 0.789 5019

260.000 199.670 27.465 0.03641 137.798 3330.29 115.27 135.50 1.13924 0.516 0.795 4877

250.000 209.670 27.048 0. 03697 129.755 3098.61 122.89 143.43 1.17823 0.511 0. 300 4738

240.000 219.670 26.627 0.03756 122.131 2874.97 130.55 151.41 1.21556 0.505 0.803 4601

230.000 229.670 26.199 0.03817 114.894 2661. 03 138.24 159.44 1.25137 0.499 0.306 4464

220.000 239.670 25.763 0.03882 106.015 2457.77 145.96 167.52 1.28582 0.4 94 0.811 4326

210.000 249.670 25.319 0.03950 101.466 2265. 67 153.72 175.66 1.31910 0.490 0.818 4185

200.000 259.670 24.867 0.04021 95.225 2084.65 161.55 183.89 1.35139 0.468 0.827 4043

190.000 269.670 24.406 0.04097 89.272 1915.10 169.43 192.20 1.38279 0.486 0.835 3904

180.000 279.670 23.935 0.04178 83.590 1756.06 177.37 200.58 1.41332 0.482 0. 842 3770

170. 000 289.670 23.453 0.04264 78. 167 1607. 24 185. 33 209.02 1.44295 0.473 0.844 3644

160.000 299.670 22.962 0.04355 72.989 1468. 10 193.26 217.46 1.47159 0.461 0. 843 3526

150. 000 309.670 22.459 0.04453 68.050 1338. 16 201.14 225.88 1.49924 0.449 0.842 3411

140.000 319.670 21.945 0.04557 63.341 1217.01 209.04 234.35 1.52614 0.448 0. 353 3278

130.000 329.670 21.418 0. 04669 58.856 1104. 32 216.98 242.92 1.55252 0.443 0.860 3153 120.000 339.670 20.878 0.04790 54.594 999. 89 224.96 251.56 1.57835 0.439 0.869 3028

110.000 349.670 20.326 0.04920 50.550 903.61 232.98 260.31 1.60372 0.436 0.380 2905

100.000 359.670 19.760 0.05061 46.725 815.46 241.05 269.16 1.62868 0.435 0.891 2784

-90.000 369.670 19. 180 0. 05214 43.120 735.41 249. 17 278.14 1.65329 0.433 0.904 2666

-80. 000 379.670 18.587 0.05380 39.735 663.44 257.35 287.24 1.67759 0.433 0.917 2553

-70.000 389.670 17.982 0.05561 36.570 599.45 265. 58 296.47 1.70159 0.432 0.930 2445

-60.000 399.670 17.368 0.05758 33.627 543.25 273. 84 305.83 1.72529 0.429 0.939 2349

-50. 000 409.670 16.746 0.05972 30.903 494.59 282.10 315.28 1.74865 0.428 0. 95 0 2256

-40.000 419.670 16. 119 0.06204 28.393 453.12 290.37 324.83 1.77169 0.428 0.960 2170

-30.000 429.670 15.494 0.06454 26.093 418.44 298.62 334.47 1.79440 0.429 0.068 2092

-20.000 439.670 14. 874 0.06723 23.995 390. 17 306. 83 344.18 1.81673 0.430 0. 973 2023

-10.000 449.670 14.266 0.07010 22.090 367.85 314.98 353.92 1.83863 0.431 0.974 1962

0.000 459.670 13.675 0.07313 20.371 351. 06 323.02 363.64 1.86002 0.432 0.970 1911 10.000 469.670 13.107 0.07629 18.827 339. 33 330.93 373.31 1.88083 0.434 0.963 1868

20.000 479.670 12.567 0. 07958 17.448 332. 21 338. 68 382.88 1.90099 0.435 0.951 1833

30.000 489.670 12.058 0.08294 16.220 329.20 346. 24 392.32 1.92045 0.437 0.935 1607

40.000 499.670 11.582 0.08634 15.130 329. 72 353.62 401.58 1.93919 0.439 0.918 1787 50.000 509.670 11.140 0.08977 14. 165 332.69 360.80 410.67 1.95719 0.441 0.899 1774 60.000 519.670 10.730 0. 09320 13. 307 337.61 367. 80 419.57 1.97449 0.443 0.881 1764

70.000 529.670 10.350 0.09661 12.543 343. 05 374. 63 428.30 1.99112 0.445 0.365 1758

80.000 539.670 9.998 0.10002 11.859 348. 94 381.31 436.87 2.00716 0.447 0.850 1753

100.000 559.670 9.364 0.10679 10.685 361.68 394.29 453.62 2.03763 0.452 0.825 1749

120. 000 579. 670 8.811 0.11349 9.717 375. 85 406.87 469.92 2.06625 0.458 0.805 1750 140.000 599.670 8.326 0.12010 8.908 392.13 419.13 485.85 2.09327 0.464 0.788 1757

160.000 619.670 7.899 0. 12659 8.226 410.09 431. 14 501.47 2.11889 0.471 0.774 1768 180.000 639.670 7.521 0.13296 7.644 428. 87 442.97 516.83 2.14330 0.478 0.763 1781

200. 000 659.670 7. 184 0. 13920 7.142 447.94 454.68 532.01 2.16667 0.485 0. 755 1797

220. 000 679.670 6.881 0.14532 6.705 467.04 466.32 547.05 2. 18912 0.493 0.749 1813

240.000 699.670 6.608 0.15133 6.321 486. 06 477.92 561.99 2.21078 0.501 0. 745 1830 280.000 739.670 6.133 0.16305 5.678 523.63 501.15 591.72 2.25211 0.518 0.743 1864

320. 000 779.670 5.734 0.17441 5.161 560.44 524.56 621.45 2.29126 0.536 0.745 1899

360. 000 819.670 5.392 0.18547 4.735 596.41 548. 31 651.34 2. 32864 0.554 0.750 1935

400. 000 859.670 5.095 0. 19627 4.378 631.55 572.46 681.50 2.36456 0.572 0.758 1969

440.000 899.670 4.835 0.20685 4.075 665. 88 597.10 712.01 2. 39925 0.590 0. 768 2004

263
NE YUftME i$0B6R ft V P = 3400.0 PSI

T V OEM HOL OP/OT OP/ DO E H S CM CP ti DEG F DEG 8 LB/CUFT CUFT/LB PSI/R PSICUFT/LB 0TU/LB 0TU/LB BTU/LG/R BTU/L9/R BTU/LB/P F .VS

• 205. >308 IV'3.762 28.635 0.03492 161.380 4023.68 95.42 117.41 i, 02613 0.518 0.772 5270

280,000 ivs.ero 20.389 0,03522 155.927 3883.54 99.73 121.91 lo 05234 0.519 0. 77V 5192

270o 000 189. 670 2 7 ,98 7 0. 0357 3 147.134 3652.46 107.00 129.58 1.09468 0.520 0,766 5056

-260.000 199 . 670 27,533 0,03625 138.797 3421.77 114.56 137.39 1.13524 0.519 0.792 4921

250o 0 0

0

209,670 27.176 0.0 1680 130,897 3195.42 122,11 145.28 1.17405 0.514 0,796 4768

240 . (J Cl 0 219 670 26,763 0.03736 123.408 2976.13 129. 70 153.23 1.21120 0.508 0. 798 4656

230,000 229,670 26.366 0.03796 116.302 2765.73 137, 32 161.21 1. 24679 0,501 0 n 8 0 1 4525

"22 0o 0 0

0

239.670 25,922 0.03658 109.549 2565,40 144.95 169.24 1.28101 0 ,496 0.805 4392

210,000 249,670 25,692 0.03923 103.124 2375. 74 152.62 177.32 1.31405 0.493 0,811 4257

200. 000 259.670 25.054 0. 03991 97.005 2197. 00 160. 34 185.47 1.34605 0.491 0,819 4121

190,000 269,670 24,609 0.04064 91.173 2029. 10 168.11 193.70 1.37715 0.489 0. 827 3987

-100.000 279,670 24, 155 0.04140 85.612 1871.74 175.93 201.99 1.40735 0 0 4 84 0,832 3860 -ifo.ooo 289,670 23.694 0, 04221 80.308 1724.48 183.75 210,32 1.43660 0.476 0.033 3740 -160,000 299.670 23. 224 0. 04306 75.250 1586. 03 191.53 218.64 1. 46485 0.464 0 3 31 3630 -150.000 309,670 22,745 0.04397 70.429 1458.28 199. 25 226.93 1.49206 0.451 0. 828 3522

-140. 000 319,670 22,258 0.04493 65.837 1338.37 206.97 235.25 1.51847 0 , 450 0,837 3397

-130.000 329. 670 21.761 0.04595 61.469 1226.73 214.71 243.64 1.54431 0.444 0,842 3280 =120, 000 339. 670 21.256 0. 04705 57. 318 1123. 05 222.47 252,09 1.56955 0.441 0,648 3164 -110.000 349,670 20,740 0. 04821 53. 303 1027.11 230.25 260.61 1.59425 0.438 0.855 3049

“100,000 359,670 20.216 0.04947 49.659 938.76 238.06 269.20 1.61849 0 0 4 36 0, 366 2937

-90. 000 369,670 19,663 0.05081 46, *44 857. 95 245.89 277,88 1.64229 0.436 0. 872 2827

30 000 379. 670 19. 141 0. 05224 42. 838 784.51 253.76 286,65 1.66570 0.433 0,382 2721 =70.000 389,670 10 591 0.05379 39.737 718, 35 261.65 295.51 1.66874 0.432 0,991 2619

“60o 000 399,670 13,035 0.05545 36.840 659.29 269.55 304.46 1.71142 0 , 428 0, 997 2529

-50,000 409o 6 /

0

17.474 0.05723 34.144 607.11 277,44 313.47 1.73367 0.426 0. 905 2440 -GO , 000 419. 670 16.911 0. 05913 31.642 561.52 205. 32 322.55 1.75558 0.427 0.912 2356

“30,000 429.670 16.348 0.06117 29. 330 522. 19 293.19 331.70 1.77713 0.428 0,918 2279

-20,000 639.670 15.789 0.06334 27.200 488. 76 301.04 340.91 1.79832 0.429 0,923 2208

• 10,000 449,670 15,236 0.06563 25.245 460. 84 308.04 350.16 1.81912 0.430 0 926 2144 0.000 659,670 14,694 0.06805 23.456 438. 07 316.56 359.43 1.83950 Q . 632 0,927 2088

1U, 000 669. 670 14.166 0.07059 21.824 420. 03 324,25 368.69 1.85943 0.633 0, 925 2038

20,000 679,670 13,656 0.07323 20.341 406. 34 331.01 377,91 1.07066 0.635 0,920 1995

30,000 689,570 13,166 0,07595 18.996 396. 61 339. 26 367.08 1.89778 0. 637 0,913 1959

40.000 699,670 12,699 0.07875 17.780 390.45 346.59 396.17 1,91615 0,439 0,906 1929

50.000 509.670 12,256 0.08159 16.683 387.51 353.78 4 0 5o 15 1.93395 0 0 441 0 893 1906

60.000 519.670 11.838 0.08447 15.695 387. 39 360.83 414.01 1.95117 0.464 0. 080 1 887 >0.000 529, 670 11.445 0. 08737 14. 804 389.61 367.74 422. 75 1,96702 0 . 446 0.867 137 3 30.000 539.670 11.078 0,09027 14.002 393.56 374.52 431,36 1.90 392 0,449 0, 956 1863 100.000 559,670 10.411 0.09605 12.619 404. 01 387.73 448,20 2.01457 0 0 4 5 4 0,831 1851 120.000 579.670 9, 824 0.10180 11.475 415.93 400 0 53 464o 62 2. 04340 0.460 0,312 1345

140. 000 59®, 670 9. 303 0. 10749 10.515 428. 80 413. 04 480.71 2.07069 0.666 0 7 97 1843

160.000 619.670 8,840 0.11313 9.699 442.73 425.31 496,53 2.09666 0.473 0.785 1045

130.000 639. 67U 8,425 0.11870 8.999 458,18 437.40 512,13 2.12142 0, 480 0c 775 1351 200.000 659 670 8, 052 0.12419 8.393 474,98 449.37 527,56 2, 16517 0.4 88 0, 767 1060

220. 000 679, 670 716 0. 12960 7. 866 492. 54 461.25 542.85 2.16800 0,496 0,762 1072 240.000 699,670 7.412 0. 13492 7.402 510, 46 473.09 558.03 2.19002 0,5 06 0 757 1885

280. 000 739.670 6.881 0.14532 6.627 546,51 496.74 588.23 2.23200 0,521 0.756 1913 320.000 779,670 6.434 0, 15542 6.005 502,30 520.54 610.39 2.27170 0.539 0, 755 1944

360. 000 819.670 6. 051 0. 16526 5.495 617.55 544,62 640o6S 2.30956 0.557 0.759 1976

400. 000 859.670 5.719 0.17487 5.069 652. 18 569.08 679,17 2,34591 0,575 0,767 2007

440.000 899.670 5.426 0.18428 4.708 686. 17 593.96 710,01 2.38096 0,593 0.775 2039

264
HETHANE IS08AR »T P = 3800.0 PSI

T T OEN VOL OP/OT DP/DO E H S cv CP M DEG F BEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 8TU/LE 0TU/LB 8TU/LB/R BTU/18/R 8TU/L3/R FT/S

• 284.7 0 3 174.967 28.684 0.03486 160.794 4063.98 95.75 120.28 1.02793 0.521 0. 772 5260

-280.000 179.670 28.491 0.03510 156.553 3956. 85 99. 16 123.86 1.04869 0.522 0. 776 5220

-270. 000 189.670 26.096 0. 03559 147.929 3734.17 106.46 131.51 1.09092 0.523 0.784 5092

-260.000 199.670 27.698 0.03610 139.743 3510. 25 ii3.ee 139.29 1.13134 0.5 21 0.789 4963

-250.000 209.670 27.299 0.03663 131.981 3289. 34 121.38 147.15 1.17001 0.517 0.793 4835

-240.000 219.670 26.896 0.03716 124.622 3074.46 128.90 155.06 1.20698 0.510 0.794 4709

-230. 000 229.670 26.488 0. 03775 117.638 2867.64 136.44 163.00 1.24239 0.504 0. 796 4582

-220. 000 239.670 26.075 0.03635 111.003 2670.20 143.99 170.98 1.27640 0.499 0.800 4455

-210.000 249.670 25.656 0.03698 104.694 2482.93 151.58 179.00 1. 30920 0. 495 0.805 4325

-200.000 259.670 25.232 0.03963 98.667 2306.15 159.20 187. 09 1.34096 0.493 0.812 4194

-190. 000 269. 670 24.800 0. 04032 92.964 2139.92 166.88 195.25 1.37179 0 . 491 0. 819 4066

-180.000 279.670 24.363 0.04105 87.511 1964.03 174.58 203.46 1.40 169 0.487 0.823 3944

-170.000 289.670 23.918 0. 04181 82. 312 1838.09 182.28 211.70 1.43064 0.478 0.824 3831 -160.000 299.670 23.467 0.04261 77.358 1701. 64 189. 94 219.92 1.45854 0.466 0. 820 3726

-150.000 309.670 23.009 0.04346 72.638 1574.19 197.52 228.10 1.48538 0.453 0.816 3625

-140.000 319.670 22.544 0.04436 66.145 1455. 27 205.08 236.30 1.51139 0.451 0.323 3506 -130.000 329. 670 22.073 0.04531 63.871 1344.44 212.66 244.54 1.53679 0.446 0.826 3396

-120.000 339.670 21.594 0.04631 59.813 1241. 34 220.24 252.83 1.56155 0.442 0.831 3287

-110.000 349.670 21.109 0. 04737 55.963 1145.69 227.83 261.17 1.58574 0.439 0.836 3180 -100.000 359.670 20.617 0.04850 52. 319 1057.26 235.43 269.56 1.60940 0.437 0. 842 3074

-90.000 369.670 20.119 0.04970 48. 876 975.88 243.04 278.02 1.63259 0.435 0.849 2 971 -80.000 379.670 19.616 0. 05098 45.631 901. 38 250.67 286.54 1.65534 0.434 0.356 2071

-70.000 389.670 19.107 0.05234 42.580 833.62 258.30 295.13 1.67768 0.433 0. 363 2775

-60.000 399.670 16.595 0.05378 39.720 772.42 265.94 303.78 1.69959 0.4 29 0.366 2609

-50.000 409. 670 18.079 0.05531 37.046 717.59 273.54 312.47 1.72106 0.428 0.372 2603

-40. 000 419.670 17.563 0. 05694 34.554 668. 86 281.14 321.21 1.74214 0.427 0.377 2522

-30. 000 429.670 17.047 0.05866 32.236 625.97 288.73 330.01 1.76286 0.428 0.882 2446

-20.000 439.670 16.533 0. 06048 30.087 588.60 296. 29 338.85 1.78321 0.429 0.887 2375

-10.000 449.670 16.025 0.06240 26.099 556.43 303.82 347.73 1. 80 319 0.430 0. 890 2310

0. 000 459.670 15.524 0. 06442 26.264 529.12 311.32 356.64 1.82278 0.431 0.392 2251 10.000 469. 670 15.033 0.06652 24,574 506. 32 318.76 365.56 1.84198 0.433 0.892 2198

20.000 479.670 14.554 0.06871 23,022 487.68 326. 13 374.48 1.86077 0.435 0.891 2151

30. 000 489.670 14.090 0.07097 21.598 472.88 333.43 383.37 1. 87912 0.437 0.888 2109

40.000 499. 670 13.641 0.07331 20.295 461.57 340.65 392.23 1.89702 0.439 0.883 2073

50.000 509.670 13.211 0.07570 19.104 453.43 347.77 401.03 1.91446 0 .442 0.377 2042

60.000 519.670 12.799 0.07813 16.017 448.15 354.79 409.77 1.93143 0 . 444 0.370 2016

70.000 529.670 12.407 0.09060 17.026 445, 45 361.71 418. 42 1.94793 0.447 0.862 1995

30.000 539.670 12.035 0.08309 16. 123 445. 06 368.53 426.99 1.96397 0.450 0.853 1977

100. 000 559.670 11.349 0.03611 14.548 449.89 381.86 443.86 1.99465 0.455 0. 334 1954

120.000 579.670 10.739 0. 09312 13.234 459.41 394.84 460.36 2.02362 0.462 0.317 1940

140. 000 599.670 10.194 0. 09610 12. 128 470.71 407.51 476.54 2.05107 0.468 0.802 1933

160.000 619.670 9.705 0.10304 11.185 482. 88 419.97 492.47 2. 07720 0.475 0.791 1929

180.000 639.670 9.265 0. 10794 10.374 495.76 432. 25 508.20 2.10218 0.483 0.782 1929

200.000 659.670 8.666 0.11279 9.669 589.43 444.41 523.78 2. 12616 0.491 0.776 1932

220. 000 679. 670 8. 504 0. 11759 9.052 524.24 456.49 539.24 2. 14925 0.499 0.771 193 8 240. 000 699.670 8.174 0.12234 8.509 540. 12 468.53 554.61 2. 17154 0.507 0.767 1946 280.000 739.670 7.596 0.13164 7.600 573. 64 492.55 585.19 2.21404 0.524 0. 763 1967

320.000 779.670 7.107 0.14071 6.871 607.92 516.69 615.70 2. 25422 0.542 0.763 1993

360. 000 819.670 6.667 0.14955 6.273 642. 12 541.08 646.31 2.29250 0.559 0. 762020

400.000 859.670 6.321 0. 15620 5.775 675.96 565.81 677.13 2.32921 0.577 0 . 7 74 2049

440.000 899.670 6.000 0. 16667 5.354 709.33 590.98 708.25 2.36460 0.595 0.782 2078

265
METHANE ISOBAR AT P = 4200.0 PSI

T T OEM VOL OP/DT DP/DD E H S CV CP w DEG F OEG R L8/CUFT CUFT/LB PSI/R PSICUFT/LR BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

-283. 505 176. 165 28.733 0.0 1480 160.223 4102. 85 96.0 6 123.15 1.02973 0.524 0.771 5289

-280. 000 179.670 28.591 0.03498 157.137 4026.63 98.61 125.81 1.04511 0.524 0. ’74 5247

-270. 000 189. 670 28.201 0. 03546 148.679 3812.65 105.86 133.44 1.08724 0.5 25 0.782 5126

-260.000 199.670 27.811 0.03596 140.640 3595. 71 113.24 141.20 1.12755 0.5 24 0.787 5002

-250.000 209.670 27.419 0.03647 133.012 3380.43 120.67 149.04 1. 166C7 0.519 0. 790 4880 -240.000 219.670 27.024 0.03700 125.777 3170.07 128. 13 156.91 1.20289 0.513 0. 791 4759

-230.000 229. 670 26.625 0.03756 118.910 2966.87 135.61 164.82 1.23813 0.506 0.792 4638

-220.000 239. 670 26.222 0.03814 112. 386 2772.34 143.09 172.75 1.27195 0.501 0.795 4515

-210. 000 249.670 25.814 0.01874 106.183 2587. 40 150.59 180.72 1. 30455 0.498 0.100 4390

-200.000 259.670 25.401 0.03937 100.280 2412.53 158. 13 188.75 1.33609 0.496 0. 806 4264

- 190. 000 269.670 24.983 0.04003 94.658 2247.86 165.72 196.85 1. 36667 0.493 0.812 4141 -180.000 279.670 24.559 0. 04072 89.301 2093. 28 173.32 204.99 1.39633 0.489 0.316 4024

-170.000 289.670 24.130 0.04144 84.197 1948.48 180.92 213. 15 1.42499 0.480 0.815 3915

-160.000 299.670 23.695 0.04220 79.334 1813. 04 188. 46 221.29 1.45260 0.468 0.311 3816

-150.000 309.670 23.254 0.04300 74.703 1686.48 195.92 229.37 1.47912 0.455 0.806 3721 -140.000 319.670 22.809 0.04384 70.294 1568. 33 203.36 237.45 1.50479 0.453 0.812 360 7 -130.000 329. 670 22.358 0.04473 66. 102 1458. 14 210.60 245.58 1.52983 0.448 0.814 3503 -120. 000 339. 670 21. 902 0. 04566 62. 120 1355. 50 218.23 253.74 1.55420 0 . 444 0.817 3400 -110.000 349.670 21.442 0.04664 58.341 1260. 07 225.66 261.93 1.57796 0.441 0.821 3296 -100.000 359. 670 20.976 0.04767 54.762 1171.58 233.08 270.16 1.60117 0.438 0. 325 3198

-90.000 369.670 20.507 0. 04876 51.377 1089.79 240.51 278.44 1.62387 0.436 0.830 3101 -80.000 379.670 20.034 0.04992 48.181 1014.50 247.95 286.77 1.64611 0. 4 35 0.835 3006

-70.000 389.670 19.557 0.05113 45.171 945.52 255.38 295.15 1.66789 0.4 34 0.341 2914

-60. 000 399.670 19.078 0. 05242 42. 342 882.69 262.80 303.57 1.68923 0.429 0.342 2833

-50.000 409.670 18.598 0.05377 39.688 825. 79 270.20 312. 01 1.71010 0.428 0. 346 2750 -40.000 419.670 18.118 0.05519 37.204 774.61 277.57 320.50 1.73056 0.428 0.351 2672

-30.000 429. 670 17.638 0. 05670 34.864 728. 91 284.93 329.03 1.75065 0.428 0.855 2597

-20.000 439.670 17.161 0.05827 32.721 688.42 292.28 337.60 1.77036 0.429 0.859 2528

-10.000 449. 670 16. 688 0. 05992 30.710 652. 86 299. 59 346.20 1.78971 0.430 0.362 2462

0.000 459.670 16.221 0.06165 28.842 621.92 306.88 354.83 1.80869 0.431 0.364 24C2

10.000 469.670 15.761 0.06345 27.111 595. 32 314. 13 363.48 1.82730 0.433 0. 365 2347

20.000 479.670 15.311 0. 06531 25.508 572.74 321.34 372.13 1. 84554 0.4 35 0.366 2297

30.000 489. 670 14. 871 0.06725 24.027 553. 88 328.49 380.79 1.86339 0.437 0. 365 2252

40.000 499.670 14.443 0.06924 22.659 538.45 335.58 389.43 1.88086 0.440 0.863 2212 50.000 509. 670 14.030 0.07128 21.399 526. 16 342. 60 398.04 1.89792 0.442 0.360 2177 60.000 519.670 13.630 0.07337 20.238 516. 72 349.56 406.62 1.91459 0 . 445 0.356 2145

70.000 529.670 13.247 0. 07549 19.169 509.87 356. 44 415.15 1.93085 0 . 448 0.351 2118

80.000 539.670 12. 879 0.07765 18.187 505.37 363. 24 423.63 1.94671 0. 451 0. 145 2095

100. 000 559.670 12.191 0.08203 16.452 502.53 376.61 440.40 1.97723 0.457 0.832 2060

120. 000 579.670 11.568 0.08644 14.984 506.44 389.68 456.91 2.00622 0.463 0.319 2037

140 .000 599.670 11.006 0.09086 13.737 514. 97 402.49 473. 16 2.03377 0.470 0.806 2023

160.000 619.670 10.499 0. 09525 12.672 525. 70 415.09 489.16 2 . 06 0 0 3 0.477 0. 795 2014

18 0. 000 639. 670 10.040 0.09960 11.752 537.36 427.52 504.98 2. 08516 0.485 0. 787 2010 200.000 659.670 9.622 0.10392 10. 952 549.63 439.83 520.66 2.10928 0 .493 0. 781 2009

220.000 679.670 9.241 0.10821 10.251 562.42 452.06 536.22 2. 13253 0.501 0.776 2010 240.000 699.670 8.892 0. 11246 9.631 575. 83 464. 25 551.71 2.15499 0.509 0.773 2013

280.000 739.670 8.275 0. 12084 8. 590 605. 24 488.59 582.57 2. 19788 0.526 0.770 2026

320.000 779.670 7.750 0.12904 7.752 637.11 513.03 613.38 2.23845 0.544 0.771 2045

360. 000 819.670 7.297 0.13705 7.066 669. 83 537.69 644.28 2.27709 0.562 0.774 2068

400.000 859. 670 6.902 0.14489 6.494 702.62 562.69 675.37 2.31413 0.580 0.781 2093

440.000 899. 670 6. 554 0. 15258 6.011 735. 16 588.08 706.75 2. 34980 0.598 0.788 2119

266
METHANE ISOBAR AT P * 4600.0 PSI

T T OEM VOL OP/DT DP/DD E H S CV CP W DEG F OEG R LB/CUFT CUFT/L0 PSI/R PSICUFT/LB BTU/LB BTU/LB BTU/LB/R e?U/L@/R 0TU/L9/R FT/S

282.314 177.356 28.781 0.03474 159.665 4140. 30 96.42 126.01 1. 03153 0.527 0. 771 5298

280.000 179.670 28.690 0.03486 157.680 4092.83 98.08 127.77 1.04161 6.527 0. 773 5272

270.000 189.670 28.305 0.03533 149.385 3887.91 105.29 135.38 1.08365 0.528 0. 780 5157

260.000 199.670 27.921 0.03582 141.490 3678. 20 112.61 143.12 1.12385 0.526 0.785 5040

250.000 209.670 27.536 0. 03632 133.993 3468. 72 120.00 150.93 1. 16225 0.522 0.787 4923

240.000 219.670 27.148 0. 03633 126.877 3263. DO 127.40 158.78 1.19893 0.515 0.788 4807

230. 000 229.670 26.758 0.03737 120.121 3063.51 134.81 166.64 1.23401 0.509 0.789 4690

220.000 239.670 26.364 0.03793 113.704 2071.93 142.23 174.53 1.26766 0.503 0.791 4572

210.000 249.670 25.966 0. 03851 107.601 2669. 34 149.66 182.46 1.30007 0.500 0.795 4451

200.000 259.670 25.563 0.03912 101.794 2516.34 157. 12 190.44 1.33141 0.498 0.801 4330

190. 000 269.670 25.157 0.03975 96.265 2353. 16 164.62 198.48 1.36178 0.496 0.806 4212

180.000 279.670 24. 745 0.04041 90.997 2199. 80 172.14 206.56 1.39121 0.491 0. 809 4099

170. 000 289.670 24. 329 0.04110 85.979 2056. 69 179.64 214.66 1.41963 0.482 0.808 3995

160.000 299.670 23.909 0.04183 01.197 1921.41 187.09 222.71 1.44698 0.470 0.803 3900

150.000 309.67® 23.484 0.04258 76.644 1795.58 194.44 230.71 1.47323 0.457 0.797 3810

140.000 319.670 23.055 0.04337 72.310 1678.05 201.76 238.71 1.49860 0.455 0. 802 3702

130.000 329.670 22.622 0.04420 68.180 1568.35 209.08 246.73 1.52333 0.450 0.803 3603

120.000 339.670 22.186 0.04507 64.271 1466.07 216.30 254.78 1.54737 0.446 0.806 3505 110.000 349.670 21.746 0.04599 60.553 1370.81 223.68 262.85 1.57078 0.442 0.808 3408

100.000 359.678 21.303 0.04694 57.028 1202.27 230.96 270.95 1.59362 0.439 0. 812 3313

-90.000 369. 670 20.856 0.04795 53.691 1200. 16 238.24 279.08 1.61593 0.437 0.815 3220 -80.000 379.670 20.408 0.04900 50.537 1124.25 245.52 287.25 1.63774 0.4 36 0.819 3129

-70.000 389.670 19.958 0.05011 47.561 1054*33 252.79 295.47 1.65909 0.435 0.823 3042

-60. 000 399.670 19.506 0.05127 44.756 990.21 260. 04 303.71 1.67997 0.430 0. 824 2964

-50. 000 409.670 19.054 0.05248 42.119 931.68 267.25 311.96 1.70036 0.429 0.827 2885

-40.000 419.670 18.602 0.05376 39.643 878.55 274.45 320.24 1.72034 0.428 0.830 2009

-30.000 429.670 18.152 0.05509 37.322 830.59 281.63 328.56 1.73993 0.428 0.833 2736

-20.000 439.670 17.704 0.05649 35. 151 787.56 288.80 336.91 1.75914 0. 429 0.837 2667

-10.000 449.670 17.259 0.05794 33.122 749.23 295.94 345.29 1.77799 0.430 0. 840 2603

0.000 459.670 16.820 0.05945 31.229 715. 32 303.06 353.70 1.79648 0 .432 0.842 2542

10.000 469.670 16. 387 0.06102 29.466 685.58 310.15 362.13 1.81463 0.434 0.844 2486

20.000 479.670 15. 961 0.06265 27.825 659. 74 317.21 370.57 1.83241 0. 4 36 0.845 2435

30.000 489.670 15.544 0.06433 26.299 637.52 324.22 379.02 1.84985 3.438 0.845 2367

40. 000 499.670 15.136 0.06607 24.882 613.66 331.20 387.47 1.86693 0.440 0.845 2345

50.000 509.670 14.740 0.06784 23.567 602.91 338.12 395.91 1.88365 0.443 0. 043 2306

60.000 519.670 14.355 0.06966 22. 348 590. 00 344.99 404.33 1.90001 0.446 0.841 2271 70.000 529.670 13.982 0.07152 21.219 579.69 351.81 412.73 1.91602 0 . 449 0.838 2240

80.000 539.670 13.623 0.07341 20.173 571.76 358.57 421.10 1.93167 0.452 0.835 2213

100. 000 559.670 12.944 0.07725 18.307 562.17 371.91 437.71 1.96190 0.458 0.827 2168

120. 000 579.670 12. 320 0. 08117 16.708 559.71 385.02 454.16 1.99077 0.465 0.817 2136

140.000 599.670 11.750 0.08511 15.335 563. 61 397.91 470.41 2.01833 0.472 0.808 2113

160.000 619.670 11.230 0.08905 14.152 570.63 410.61 486.47 2.04468 0.479 0.798 2099

180.000 639.670 10.756 0.09297 13.128 580.75 423.16 502.35 2. 06991 0. 487 0. 791 2090

200. 000 659. 670 10. 324 0. 09687 12.235 591.96 435.59 518.10 2.09416 0.495 0.785 2085

220.000 679.670 9.928 0.10073 11.451 603.77 447.95 533.75 2.11753 0.503 0.780 2083

240.000 699. 670 9.564 0.10456 10.757 616.03 460.26 549.33 2.14011 0.511 0. 778 2083

280. 000 739.670 8.918 0.11214 9.588 641. 84 484.86 580. 38 2. 18327 0.529 0.776 2088

320. 000 779. 670 8.362 0.11959 8.644 670. 16 509.55 611.41 2.22413 0.547 0.777 2101

360.000 819.670 7.881 0. 12689 7.869 700.61 534.46 642.55 2.26307 0.565 0.780 2118

400.000 859.670 7.460 0.13405 7.223 731.94 559.69 673.88 2.30039 0.582 0.786 2140

440.000 899.670 7.088 0.14108 6.678 763. 45 585. 31 705.48 2. 33632 0.600 0. 794 2163

267
methane isobar at p = 5900.0 PSI

T T OEN VOL CP/OT OP/DO E H S C V CP W DEO F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/L8 BTU/L8 BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

-281.130 178.540 28. 829 0.03469 159.121 4176. 34 96.77 128.88 1. 03334 0.529 0. 770 5307

-280. 000 179.670 28.787 0.03474 158.183 4155. 39 97.57 129.73 1.03818 0.529 0. 771 5295

-270. 000 189.670 28.407 0.03520 150. 051 3959.90 104.74 137.33 1.08014 0.530 0.778 5187

-260.000 199. 670 26.029 0.03563 142.298 3757.70 112.01 145.05 1.12023 0.529 0.782 5075

-250.000 209.670 27.650 0.03617 134.927 3554. 23 119. 35 152.83 1. 15852 0.524 0. 784 4964

-240.000 219.670 27.269 0.03667 127.927 3353.30 126.70 160.65 1. 19508 0.518 0.785 4853

-230.000 229.670 26.836 0.03719 121.273 3157.63 134.05 168.49 1.23001 0.511 0.785 4741 -220.000 239.670 26.501 0. 03773 114.961 2969.07 141.40 176.34 1.26351 0.506 0.787 4627

-210.000 249. 670 26. 112 0. 03830 108.953 2788. 86 148.77 184.23 1.29575 0.502 0.791 4511 -200.000 259.670 25.719 0.03886 103.237 2617.72 156. 17 192.16 1.32691 0.500 0.796 4394

-190. 000 269.670 25. 323 0.03949 97.794 2456.02 163.59 200.15 1.35709 0.498 0.801 4279

-180.000 279.670 24.923 0. 04012 92.608 2303.79 171.03 208.18 1.38631 0.493 0.803 4171 -170.000 289.670 24.519 0. 04078 67.668 2160. 92 178.45 216. 21 1.41452 0. 484 0.302 4071

-160.000 299.670 24.112 0.04147 82.961 2027. 07 185.80 224.20 1.44164 0.472 0.796 3980 -150.000 309.670 23.701 0.04219 78.478 1901.65 193.05 232.12 1.46765 0.459 0.789 3894

-140.000 319. 670 23.286 0.04294 74.211 1784.82 200.28 240.04 1.49276 0.457 0.794 3790

-130.000 329. 670 22.869 0. 04373 70. 150 1675.51 207.49 247.98 1.51722 0.451 0.794 3696 -120.000 339.670 22.449 0.04455 66.290 1573.49 214.68 255.93 1.54098 0.447 0.796 3602 -no. ooo 349.670 22.027 0.04540 62.625 1478.35 221.86 263.89 1.56409 0.444 0. 798 3509

-100.000 359. 670 21.602 0.04629 59.147 1389.75 229.02 271.88 1.58662 0.441 0.800 3418

-90. 000 369. 670 21. 176 0. 04722 55.851 1307. 39 236. 17 279.90 1.60660 0.439 0.803 3330

-80. 000 379.670 20.748 0.04820 52.732 1230.98 243.32 287.94 1.63007 0.437 0.806 3243 -70.000 389. 670 20.319 0.04921 49.784 1160. 31 250. 45 296.01 1.65106 0.436 0.809 3159

-60.000 399.670 19.890 0.05028 47.001 1095. 15 257.56 304.11 1.67157 0.431 0.809 3085

-50. 000 409. 670 19.461 0.05139 44.378 1035.31 264.63 312.20 1.69158 0.430 0.311 3008

-40.000 419.670 19.033 0.05254 41.909 980.59 271,68 320.32 1.71116 0.429 0.813 2935

-30.000 429.670 16.606 0.05375 39.589 930.78 278.71 328.47 1.73035 0.429 0.316 2864

-20.000 439.670 18.182 0.05500 37.411 885. 66 285.73 336.65 1. 74916 0.430 0. 319 2796

-10.000 449.670 17.762 0.05630 35.369 845.03 292.72 344.85 1.76760 0.431 0.822 2732 0.000 459.670 17.346 0.05765 33.456 808.64 299.70 353.08 1.78570 0.432 0.824 2672

10.000 469. 670 16.935 0.05905 31.667 776. 27 306.66 361.33 1.60346 0.434 0.826 2616

20.000 479.670 16.530 0.06050 29.995 747. 67 313.59 369.60 1.82087 0. 4 36 0. 827 2563

30.000 489.670 16.133 0.06199 28.433 722.60 320.49 377.88 1.83796 0.439 0.328 2515

40.000 499.670 15.743 0.06352 26.977 700. 83 327.35 366. 16 1.85471 0 .441 O’. 329 2470

50.000 509.670 15.363 0.06509 25.618 682.12 334.18 394.45 1.87113 0.444 0.828 2429

60.000 519. 670 14.993 0. 06670 24. 352 666. 24 340.97 402.73 1.88722 0.447 0.828 2392

70.000 529.670 14.632 0.06834 23.173 652.96 347.72 411.00 1.90298 0.450 0.326 2358

80.000 539.670 14.283 0.07001 22.075 642.08 354.43 419.25 1.91841 0.453 0.824 2328

100.000 559. 670 13.618 0.07343 20.101 626.68 367.70 435.69 1.94833 0.459 0.819 2276

120. 000 579.670 13.000 0. 07692 18. 391 618.59 380. 80 452.02 1.97699 0.466 0.813 2236

140. 000 599.670 12.429 0.08046 16.908 616.55 393.72 468.22 2.00447 0. 473 0.307 2206

160.000 619.670 11.903 0. 08402 15.619 619. 48 406.49 484.28 2.03082 0 .481 0.300 2185

180. 000 639. 670 11.419 0.08757 14.496 626. 33 419.13 500.21 2.05612 0 .489 0.793 2171

200. 000 659. 670 10.976 0. 09111 13.512 635.80 431.67 516.02 2.08046 0.497 0.738 2162

220. 000 679. 670 10.568 0.09463 12.647 646.57 444.13 531.74 2. 10393 0.505 0.784 2156

240.000 699.670 10.192 0.09812 11.881 657.99 456.55 547.39 2.12662 0.514 0.781 2153

280. 000 739.670 9.522 0. 10502 10.588 682. 02 481.36 578.59 2. 16999 0.531 0.779 2153

320. 000 779. 670 8.94 3 0.11181 9.541 707.40 506.26 609.79 2.21107 0 .549 0.781 2160

360. 000 819.670 6.438 0. 11851 8.679 734.76 531.39 641.11 2.25025 0.567 0.785 2172

400. 000 859.670 7.995 0.12508 7.959 763.96 556. 83 672.64 2.28780 0 .585 0.791 2188

440.000 899.670 7.602 0.13155 7.350 794.05 582.65 704.44 2.32396 0.603 0.799 2208

268
METHANE ISOBAR AT P * 5500.0 PSI

T T OEM VOL DP/DT OP/OO E H S CM CP W DEG F DEG R L0/COFT CUFT/L0 PSI/R PSICUFT/LB BTU/LP BTU/18 BTU/L8/R 8TU/LB/R eui/ta/R FT/S

-279.659 160.011 26.669 0.01462 158.459 4219. 40 97.21 132.47 1.03560 0.532 0. 770 5317

-270. 000 109.670 26.532 0.03505 150.629 4045.23 104. 07 139.77 1.07584 0.533 0. 776 5222

-260.000 199.670 26.160 0. 03551 143.250 3852.84 111.30 147.46 1.11583 0.532 0.780 5117

-250. 000 209.670 27.768 0.03599 136.033 3657.20 118.57 155.22 1.15400 0.527 0.781 5012

-260.000 219.670 27.416 0.01646 129.173 3462. S3 125.86 163. 01 1. 19040 0.520 0. 781 4907

-230.000 229.670 27.042 0.03690 122.653 3271. 82 133.15 170.81 1.22518 0.514 0.781 4001

-220.000 239.670 X6.666 0.03750 116.455 3087. 17 140.43 178.63 1.25850 0.509 0.763 4692

-210. 000 269.670 26.267 0.03804 110.560 2910.01 147.72 186.47 1.29056 0.505 0.786 4581

-200.000 259.670 25.906 0. 01660 104.949 2741. 24 155.04 194.35 1.32151 0.503 0. 791 4469

-190.000 269.670 25.522 0.03918 99.606 2581.36 162.37 202.28 1.35148 0.500 0.795 4359

-100.000 279.670 25.134 0.01979 94.516 2430.55 169.72 210.24 1.38047 0.496 0.797 4255

-170.000 269.670 24.744 0. 04041 89.665 2288.73 177.04 218.20 1.40843 0.4 87 0.795 4160

-160. 000 299. 670 24. 351 0.04107 85.043 2155.72 164. 30 226.12 1.43530 0.474 0.788 4074

-150.000 309.670 23.955 0.04175 80.639 2031. 14 191.45 233.96 1.46105 0.461 0.781 3993

-160.000 319.670 23.557 0.04245 76.445 1914.60 198.56 241.79 1.48589 0.459 0.785 3894

-130. 000 329.670 23.157 0.04318 72.454 1805.66 205.66 249.64 1.51006 0.454 0.785 3604

-120. 000 339. 670 22.754 0.04395 68.656 1703. 85 212.73 257.49 1.53351 0.449 0.785 3715

-110.000 369.670 22.351 0.04474 65.047 1608. 80 219.78 265.34 1.55631 0.446 0.786 3627

-100.000 359.670 31.946 0.04557 61.620 1520.12 226.81 273.22 1.57851 0.443 0.788 3541

-90.000 369.670 21.540 0.04643 58.368 1437.48 233.03 261.11 1.60015 0.440 0.790 3457

-60. 000 379.670 21. 134 0. 04732 55.286 1360.57 240.83 269.02 1.62126 0.4 39 0.792 3374

-70.000 369.670 20.728 0.04825 52.368 1289. 13 247.82 296.95 1.64189 0.437 0.794 3295

-60.000 399.670 20.322 0.04921 49.608 1222.95 254.78 304.89 1.66202 0.433 0.793 3223

-50.000 609.670 19.916 0.05021 47.001 1161.79 261.70 312.83 1.68164 0. 431 0.795 3150

-60. 000 619.670 19.513 0.05125 44.540 1105.47 268.59 320.79 1.70082 0.430 0.797 3079

-30. 000 629.670 19.111 0.05233 42.221 1053.79 275.47 328.77 1.71961 0.430 0.799 3011 -20.000 639.670 18.712 0.05344 40.036 1006.55 282.34 336.77 1.73801 0.431 0.801 2945

-10.000 649.670 18.316 0.05460 37.981 963. 55 289. 18 344.79 1.75606 0.432 0.803 2882

0. 000 459.670 17.923 0.05579 36.049 924.60 296.01 352.64 1.77375 0.433 0.806 2822

10.000 469.670 17.536 0.05703 34.234 689.48 302.82 360.90 1.79111 0.435 0.308 2766

20.000 479.670 17.154 0.05830 32.531 857.96 309.62 366.99 1.80815 0.437 0.809 2713

30.000 469.670 16.776 0.05960 30.934 029.91 316. 39 377.09 1. 82487 0. 4 39 0.811 2664

60.000 499.670 16.409 0.06094 29.436 805.04 323.14 385.21 1.84127 0.442 0.812 2617

50.000 509.670 16.047 0.06232 28.033 763. 17 329.66 393.33 1.85737 0.445 0.813 2575

60.000 519.670 15.693 0.06372 26.719 764.10 336.56 401.45 1.87316 0.448 0.813 2535

70.000 529.670 15.348 0.06516 25.489 747.62 343.22 409.58 1.88865 0.451 0.813 2499

60. 000 539.670 15.011 0. 06662 24.337 733.54 349.86 417.70 1.90384 0.454 0.812 2466

100. 000 559.670 14.367 0.06961 22.251 711.85 363.03 433.92 1.93335 0.461 0.810 2408

120.000 579.670 13.761 0.07267 20.425 697.65 376.0® 450.09 1.96173 0.468 0.807 2361 160.000 599.670 13.196 0.07578 18.825 689.73 389.00 466.18 1.98902 0.475 0.803 2324

160.000 619.670 12. 669 0.07693 17.421 687.06 401.81 482.20 2.01529 0.483 0.799 2295

160.000 639.670 12.101 0.06210 16.186 688.77 414.52 498.13 2.04060 0.491 0.795 2273

200.000 659.670 11.729 0.08526 15.096 694. 09 427. 14 513.98 2.06500 0.499 0.791 2257

220. 000 679.670 11.310 0.03842 14.136 702.19 439.71 529.76 2. 08857 0.508 0.738 2247

260. 000 699. 670 10.922 0.09156 13.281 712.09 452.24 545.49 2.11137 0.516 0. 785 2240

260.000 739.670 10.229 0.09776 11.635 734.22 477.28 576.85 2.15496 0.534 0.784 2235

320.000 779.670 9.626 0.10368 10.663 757.77 502.42 608.21 2.19626 0.552 0.785 2236

360.000 619.670 9.096 0.10991 9.694 782. 31 527.7® 639.72 2.23566 0.570 0.790 2242 600.000 659.670 8.631 0.11586 6.864 806.20 553.44 671.44 2.27345 0.588 0.796 2253

660. 000 699.670 6.216 0.12172 8.198 835.71 579.48 703.44 2.30983 0.6 06 0.304 2267

269
METHANE ISOBAR AT P = 6000.0 PSI

T T OEN VOL OP/DT DP/OD E H S C V CP W DEG F OEG R LB/CUFT CUFT/L8 PSI/R PSICUFT/L8 BTU/LB BTU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

*278.1 98 181 . *72 28.9*7 0.03*55 157.818 *260. 27 97.67 136.05 1.03787 0 .536 0.770 5327

-270.000 189. 670 28.655 0.03*90 151.5*8 *125.23 103. ** 1*2.21 1.07165 0.536 0.775 5253

-260.000 199.670 28.288 0.03535 1** .1*2 39*3.2* 110.61 1*9.89 1. 11155 0.535 0. 778 5156

-250. 000 209. 670 27.923 0.03581 137.076 3755. 8* 117.8* 157.63 1.1*960 0.530 0.779 5058

-2*0.000 219.670 27.558 0.03629 130.351 3567.7* 125. 07 165.39 1.18588 0.523 0.778 *959

-230.000 229.670 27.192 0.03678 123.95* 3382.23 132.30 173. 15 1.22051 0.517 0.778 *858

-220. 000 238.670 26.825 0.03728 117.870 3201.67 139. 51 180.93 1.25368 0.511 0. 779 *75*

-210.000 2*9.670 26. *56 0.03780 112.081 3027.70 1*6.73 188.73 1.28556 0.508 0.782 *6*8

-200.000 259.670 26.08* 0.0383* 106.570 2861.38 153.97 196.57 1. 3163* 0.505 0.786 *5*0

-190.000 269.670 25.711 0.03889 101.320 2703. 36 161.23 20*. *5 1.3*611 0.503 0.790 *435

-180.000 279.670 25.335 0.039*7 96. 318 2553. 9* 168.50 212.35 1. 37*90 0.498 0. 791 *336

-170.000 289.670 2*. 957 0.0*007 91.5*9 2*13. 17 175.7* 220.26 1. *0 265 0.469 0.788 *2*5

-160.000 299.670 2*. 576 0.0*069 87.00* 2280.92 182.90 228.11 1.42930 0.476 0.781 *163

-150.000 309. 670 2*. 19* 0.0*133 82.672 2156.90 189.95 235.88 1.45*82 0.463 0.77* *086

-1*0.000 319.670 23.810 0. 0*200 78.5*5 20*0.75 196.97 2*3.63 1.479*2 0.461 0.777 3990

-130.000 329.670 23. *2* 0.0*269 7*. 61* 1932. 05 203.97 251. *0 1.5033* 0.456 0.776 3905

-120.000 339.670 23.037 0. 0*3*1 70. 872 1830. *0 210.93 259.16 1.5265* 0.451 0.776 3820 -110.000 3*9. 670 22.650 0.0*415 67.312 1735. 37 217.87 266.93 1.5*907 0.4*7 0.777 3736

-100. 000 359. 670 22. 262 0. 0**92 63. 928 16*6. 58 22*. 79 27*. 70 1.57100 0 .*** 0.778 365*

-90.000 369.670 21.873 0.0*572 60.715 1563. 68 231.70 282. *9 1.59235 0.4*2 0.779 357*

-80.000 379.670 21. *85 0.0*65* 57.66* 1*86. 35 238.58 290.29 1.61317 0 . 4*0 0.781 3*95

-70.000 389.670 21.098 0.0*740 5*. 772 1*1*. 29 2*5. *5 298.11 1.633*9 0.439 0.783 3*19

-60. 000 399. 670 20.711 0. 0*828 52. 032 13*7.27 252.28 305.93 1.65332 0.43* 0.781 3 351 -50.000 *09.670 20.325 0.0*920 *9. *38 1285. 07 259.08 313.7* 1.67262 0.432 0.782 3281 -*0.000 *19.670 19.9*2 0.05015 *6.98* 1227. *7 265. 85 321.56 1.691*8 0.432 0.783 3212

-30.000 *29.670 19.560 0.05112 **.666 117*. 28 272.60 329. *0 1. 7099* 0.431 0.785 31*6

•20. 000 *39.670 19. 181 0. 05213 *2. *77 1125.32 279.3* 337.26 1.72802 0.432 0.787 3082

-10.000 **9.670 18.805 0.05316 *0.*11 1080. *0 286. 06 3*5.1* 1.7*57* 0 .433 0.789 3020 0.000 *59.670 18. *33 0.05*25 38. *6* 1039. 3* 292.76 353.0* 1.76312 0 .*3* ' 0.791 2961 10.000 *69.670 18.065 0.05535 36.628 1001.95 299. *6 360.96 1.78016 0.436 0. 793 2905

20. 000 *79. 670 17.702 0.056*9 3*. 900 968.05 306. 13 368.90 1.79689 0.438 0.795 2852

30.000 *89.670 17. 3** 0.05766 33.273 937. *5 312.80 376.85 1.81330 0.4*1 0.797 2802

*0.000 *99.670 16.992 0.05885 31.7*2 909.97 319. ** 38*. 83 1.829*2 0.4*3 0.798 2755

50.000 509.670 16.6*7 0.06007 30.303 885. *1 326. 07 392.81 1.8*52* 0. 4*6 0.799 2711 60.000 519.670 16.308 0.06132 28.9*9 863.61 332.68 *00.81 1.86078 0.4*9 0.300 2670

70.000 529.670 15.977 0.06259 27.677 8**. 37 339. 27 *08.81 1. 87603 0.452 0.800 2632

80.000 539.670 15.653 0.06369 26. *81 827. 53 3*5.8* *16.82 1.89101 0.455 0.801 2597

100.000 559.670 15.029 0. 0665* 2*. 302 800. 36 358.90 *32. 83 1.92015 0.462 0.801 2535

120.000 579.670 1 * . *39 0.06926 22. 377 780.82 371.88 **8.83 1.9*82* 0.469 0.799 2*83

1*0. 000 599.670 13.883 0.07203 20.677 767.7* 38*. 77 *6*. 80 1.97533 0.477 0.798 2*35

160. 000 619.670 13.361 0.07*8* 19.17* 760.13 397.58 *80.7* 2.001*6 0.485 0.796 2*0*

180.000 639. 670 12. 873 0. 07768 17.8*3 757. 13 *10. 32 *96.63 2. 02670 0.493 0.793 2376

200. 000 659.670 12. *18 0.08053 16.661 758.01 *23.01 512. *8 2.05110 0.501 0.791 2355

220.000 679.670 11.99* 0.08338 15.609 762. 1* *35.65 528.29 2. 07*71 0.510 0.790 2338

2*0.000 699.670 11.598 0.08622 1*. 671 768.96 **8.27 5**. 06 2.09758 0.519 0.788 2327

280. 000 739. 670 10.886 0.09186 13. 077 787.91 *73.50 575.56 2.1*136 0.5 36 0.787 2315

320.000 779.670 10.265 0.097*2 11.781 809. 86 *98. 8* 607.08 2.18286 0.55* 0.789 2311

360.000 819.670 9.718 0.10291 10.709 632. 9* 52*. 39 638.73 2.222** 0.572 0.79* 2313

*00. 000 859.670 9.232 0. 10832 9.811 856.79 550.26 670.60 2.260*1 0.590 0.800 2319

**0. 000 899. 670 8. 799 0. 11365 9. 0*8 881.53 576. *9 702.77 2.29698 0.608 0.308 2329

270
methane isobar AT P X 7000.0 PSI

T T DEN VOL OP/DT DP/DD E H S CV CP W OEG F OEG R L8/CUFT CUFT/LB PSI/R PSICUFT/LB 0TU/LB 8TU/LB 8TU/L0/R BTU/LB/R BTU/L8/R FT/S

-276. 306 164.364 29-062 0. 03441 156.591 4335. 44 98.62 143.22 1. 04242 0.541 0.770 5345

-270.000 189.670 26.893 0.03461 152.825 4268. 77 102.24 147.11 1.06355 0.542 0.772 5308

-260.000 199.670 28.537 0.03504 145.759 4109.40 109. 33 154.76 1.10329 0.540 0.775 5226

-250.000 209.670 28.183 0.03548 138.987 3939.94 116.46 162.46 1.14116 0.535 0.775 5141

-240.000 219. 670 27. 631 0. 03593 132.523 3766. 07 123.60 170.17 1. 17723 0.528 0.773 5053

-230.000 229.670 27.479 0.03639 126.361 3591.85 130.71 177.89 1.21162 0.522 0.772 4963

-220.000 239.670 27.127 0.03686 120.491 3420.16 137.82 185.60 1.24452 0.516 0.772 4869

-210.000 249. 670 26.774 0.03735 114.900 3253. 09 144.92 193.33 1.27612 0.512 0.774 4772

-200.000 259. 670 26.420 0. 03785 109.572 3092. 06 152.03 201.09 1.30658 0.510 0.778 4673

-190.000 269.670 26.065 0.03837 104.492 2938.03 159.15 208.88 1. 33603 0.507 0.78 1 4576

-100.000 279.670 25.709 0.03690 99.649 2791.55 166.27 216.69 1.36447 0.503 0. 781 4484

-170.000 269. 670 25.352 0.03945 95.026 2652.90 173.36 224.49 1.39187 0 . 4 94 0.778 4401

- 160. 000 299. 670 24.993 0. 04001 90.620 2522. 13 180.37 232.23 1.41815 0.481 0.770 4326

- 150. 000 309.670 24.633 0. 04060 86.415 2399.11 187.27 239.89 1.44328 0.467 0.761 4256

-140. 000 319. 670 24.272 0.04120 62.403 2283. 58 194. 12 247.52 1.46749 0.465 0. 764 4168

-130.000 329.670 23.911 0. 04162 78.577 2175.23 200. 94 255.15 1. 49100 0.460 0.763 4089

- 120. 000 339. 670 23.550 0.04246 74.930 2073. 70 207.74 262.78 1.51378 0.455 0.762 4011

-110.000 349.670 23.189 0. 04312 71.454 1976.57 214.50 270.40 1.53589 0.451 0.762 3934 -100.000 359.670 22.626 0.04381 68. 144 1889. 49 221.23 278.02 1.55738 0.448 0.762 3859

-90.000 369.670 22.468 0.04451 64.993 1806. 08 227. 95 285.64 1.57828 0.445 0.763 3785 -60.000 379.670 22.108 0.04523 61.996 1728.01 234.64 293.27 1.59865 0.443 0.763 3712

-70.000 369.670 21.750 0.04598 59.146 1654.96 241.31 300.91 1.61851 0 . 442 0. 764 3642 -60.000 399.670 21.394 0.04674 56.438 1586.67 247.95 308.54 1.63785 0.437 0.762 3579

-50.000 409.670 21.039 0. 04753 53.866 1522. 87 254. 55 316. 16 1.65667 0.435 0. 762 3514

-40.000 419.670 20.686 0.04834 51.424 1463.36 261.12 323. 78 1.67505 0.434 0.762 3450

-30. 000 429.670 20.336 0.04917 49.109 1407. 93 267.67 331.41 1.69302 0.434 0.764 3387 -20.000 439.670 19.989 0. 05003 46.913 1356. 38 274.21 339.05 1.71061 0.435 0.765 3326 -10.000 449-670 19.645 0. 05090 44.832 1308. 55 280.73 346.71 1. 72783 0.435 0.767 3268

0.000 459.670 19.304 0.05180 42.860 1264.28 287.24 354.39 1.74472 0.437 0. 769 3211 10.000 469.670 18.967 0.05272 40.993 1223.40 293.75 362.09 1.76129 0.439 0.771 3156

20.000 479. 670 16.634 0.05367 39.226 1185.76 300.24 369.80 1.77754 0.441 0.77 3 3104 30.000 489. 670 16.305 0. 05463 37.554 1151. 20 306.73 377.54 1.79350 0.443 0. 774 3054

40.000 499.670 17.981 0.05561 35.971 1119.57 313. 21 385.29 1.80918 0 . 446 0.776 3006

50.000 509.670 17.663 0.05662 34.475 1090.73 319.68 393.06 1.82457 0 . 448 0. 778 2961

60. 000 519. 670 17.349 0.05764 33.059 1064.52 326.14 400.85 1.83971 0.451 0.780 2919

70.000 529. 670 17.042 0.05868 31.721 1040.80 332.59 408.65 1.85458 0.454 0.781 2879

60. 000 539.670 16.740 0.05974 30.455 1019.42 339.04 416.47 1.86920 0.458 0.782 2841 100.000 559.670 16.155 0.06190 28.127 983.13 351.90 432.14 1.89771 0.465 0.784 2772 120.000 579.670 15.596 0.06412 26.046 954.57 364.73 447.84 1.92528 0.472 0.786 2713

140. 000 599. 670 15.064 0. 0663® 24.185 932.74 377.53 463.58 1.95196 0.480 0.787 2661

160.000 619.670 14.559 0. 06869 22.519 916.70 390. 29 479.33 1.97779 0 .488 0.788 2618

160.000 639.670 14.061 0.07102 21.026 905. 63 403.03 495.09 2. 00283 0.497 0.788 2560

200.000 659.670 13.630 0.07337 19.686 898. 82 415. 76 510.86 2. 02711 0.505 0. 789 2550

220. 000 679. 670 13.205 0.07573 18.482 895.64 428.48 526.64 2. 05068 0.514 0.789 2524

240.000 699.670 12.604 0.07810 17.398 895.56 441.20 542.44 2.07358 0.523 0. 790 2504

260.000 739.670 12.072 0. 08283 15.533 903.01 466. 71 574.08 2. 11756 0.541 0.792 2475

320.000 779.670 11.424 0.08753 14.000 918. 12 492. 37 605.83 2. 15936 0.559 0.795 2460

360.000 819.670 10.849 0.09218 12.726 937.79 518.26 637.74 2.19927 0.578 0.800 2454

400. 000 859.670 10.335 0.09676 11.656 959. 22 544.46 669.87 2.23755 0.596 0.807 2453

440.000 899.670 9. 874 0.10128 10.745 981. 38 571.02 702.29 2.27441 0.613 0.814 2457

27
>

HETHANE ISOBAR AT P = 8000.0 PSI

T T DEN VOL OP/DT OP/DO E H S cv CP H OEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB 8TU/LB 9TU/LB BTU/LB/R 8TU/L8/R 9TU/LB/R FT/S

-272.453 187. 218 29.173 0.03428 155.437 4401. 89 99.60 150.38 1.04696 0.546 0.770 5 361 -270. 000 189.670 29. 124 0.03434 153.900 4388. 93 101.15 152.01 1. 05575 0.547 0.771 5352

-260. 000 199.670 28.776 0.03475 147.172 4255.21 106.16 159.64 1.09540 0.545 0.772 5285

-250.000 209.670 28.431 0.03517 160.689 4105. 95 115.21 167.31 1.13313 0.540 0.772 5213

-240.000 219.670 28.090 0.03560 134.476 3948. 08 122.26 174.99 1. 16903 0.533 0.769 5137

-230.000 229.670 27.750 0.03604 128. 537 3786. 52 129. 28 182.66 1. 20 323 0.526 0. 767 5057

-220.000 239.670 27.411 0.03648 122.868 3624.83 136. 28 190.33 1.23592 0.521 0. 767 4973

-210.000 249.670 27.072 0.03694 117.459 3465.56 143. 28 198.00 1.26728 0.517 0.768 4884

-200. 000 259.670 26. 733 0.03741 112.299 3310. 54 150.28 205.69 1.29750 0.515 0.771 4794

-190.000 269. 670 26.393 0. 03789 107. 374 3161. 04 157. 29 213.42 1. 32668 0.512 0.773 4704

-180.000 279.670 26.053 0.03838 102.673 3017.91 164.29 221.15 1. 35484 0.507 0.773 4619

-170.000 289.670 25.71

3

0.03889 98. 183 2881.65 171.26 228.87 1.38195 0.498 0.769 4542

-160. 000 299. 670 25. 372 0.0 3941 93.895 2752.51 178.14 236.52 1.40793 0.4 85 0.761 4474

-150. 000 309. 670 25. 031 0. 03995 89.800 2630. 53 184. 90 244.09 1.43276 0.471 0.752 4409

-140. 000 319.670 24.689 0.04050 85.888 2515.61 191.62 251.62 1. 45665 0.469 0.754 4327

-130.000 329.670 24. 368 0.04107 82.152 2407.52 198.30 259.15 1.47984 0.463 0. 752 4255

-120.000 339.670 24.007 0.04165 78.585 2305.98 204.95 266.66 1.50230 0.459 0. 751 4182

-110.000 349. 670 23.667 0. 04225 75. 181 2210. 66 211.57 274.17 1.52408 0 . 455 0.750 4111 -100.000 359. 670 23. 327 0.04287 71.932 2121.21 218.16 281.67 1.54523 0.451 0. 75.0 404 1 -90.000 369.670 22.988 0.04350 68. 834 2037.28 224.73 289.17 1.56579 0 . 449 0. 750 3972

-80. 000 379.670 22.651 0.04415 65.879 1958.53 231.27 296.67 1.58582 0 . 447 0.750 3904

-70. 000 389. 670 22.316 0. 04681 63.064 1884.66 237.79 304.17 1.60533 0.445 0.751 3638 -60.000 399.670 21.982 0.04549 60.382 1815. 36 244.28 311.67 1.62432 0.440 0.748 3780 -50.000 409.670 21.651 0.04619 57.828 1750.38 250.72 3 19. 14 1.64279 0 . 438 0.747 3719 -40.000 419.670 21.321 0.04690 55.397 1689.46 257. 14 326.62 1.66082 0. 437 0.748 3659

-30. 000 429. 670 20.995 0.04763 53.084 1632.41 263.54 334.10 1.67843 0.437 0. 748 3600 -20.000 439. 670 20.671 0.04838 50.884 1579.03 269.92 341.59 1.69567 0. 437 0. 750 3542 -10.000 449.670 20.350 0. 04914 48.791 1529. 13 276. 30 349.09 1.71254 0.438 0.751 3485 0.000 459.670 20.033 0.04992 46.802 1482.56 282.66 356.61 1.72908 0.439 0.753 3430 10.000 469.670 19.719 0. 05071 44.912 1439. 17 289. 02 364.15 1.74530 0.441 0.755 3377 20.000 479.670 19.409 0. 05152 43.115 1398. 80 295. 38 371.70 1.76122 0.44 3 0.756 3326

30.000 489.670 19.103 0.05235 41.409 1361. 34 301.73 379.28 1.77685 0.445 0.758 3277

40.000 499. 670 16.801 0.05319 39.787 1326.63 308.08 386.87 1.79220 0.448 0.760 3230 50.000 509. 670 18. 503 0. 05405 36. 248 1294. 56 314.42 394.49 1.80729 0.451 0.762 3185 60.000 519.670 18.210 0.05492 36.785 1265. 00 320.77 402. 12 1.82212 0 .454 0.764 3141 70.000 529. 670 17.921 0.05580 35.396 1237.83 327.11 409.77 1.83671 0.457 0.766 3100 80.000 539.670 17.638 0.05670 34.077 1212.92 333.46 417.45 1.85105 0.461 0.768 306 1 100. 000 559. 670 17.086 0. 05853 31. 635 1169.41 346. 14 432.84 1.87907 0.468 0.772 2989

120. 000 579.670 16.556 0.06040 29.432 1133.57 358.83 448.31 1.90621 0 . 475 0.775 2925

140. 000 599.670 16.048 0.06231 27.444 1104. 52 371.52 463.83 1.93254 0.483 0.777 2869

160.000 619.670 15.562 0.06426 25.649 1081.44 384.21 479.40 1.95809 0.492 0.780 2819

160. 000 639.670 15. 099 0.06623 24.026 1063.59 396.92 495.03 1.98290 0.500 0. 782 2 776 200.000 659.670 14.659 0.06822 22.558 1050. 27 409.64 510.70 2.00702 0.509 0.785 2738

220.000 679.670 16.240 0.07022 21.228 1040. 89 422.38 526.41 2.03049 0.518 0.787 2706

240.000 699.670 13.843 0.07224 20.021 1034.91 435. 15 542.17 2. 05334 0.527 0.789 2679

280. 000 739. 670 13.109 0.07628 17.926 1031. 36 460.82 573.82 2.09734 0.545 0.794 2637

320. 000 779.670 12.450 0.08032 16.182 1036.68 486.69 605.68 2.13928 0 . 564 0.799 2609

360.000 819.670 11.857 0.08434 14.719 1046.68 512. 84 637. 77 2.17941 0.582 0.305 2592

400.000 859.670 11.324 0.08831 13. 483 1065. 48 539. 30 670.12 2.21794 0. 600 0. 812 2584

440.000 899.670 10.843 0.09223 12.428 1085.10 566.13 702.76 2.25506 0.618 0.820 2582

272
.c

METHANE ISOBAR AT P = 9Q00.0 PSI

T T OEN VOL CP/OT OP/OD E H S CV CP w OEG F OEG R LB/CUFT CUFT/IB PSI/R PSICUFT/IB BTU/LB BTU/LB BTU/L8/R BTU/LB/R BTU/LB/R FT/S

-269. 635 190. 035 29.203 0.01415 154.351 4459.64 100.62 157.54 1.05149 0.551 0.770 5375

-260. 000 199.670 29.007 0.03447 148.400 4379.20 107.08 164.54 1.06760 0.550 0.771 5333

-250.000 209.670 20.671 0.03460 142.204 4252.91 114.06 172.19 1.12544 0 .545 0.769 5275

-240.000 219.670 20.330 0.03529 136.236 4113. 19 121.03 179.84 1. 16122 0.538 0.766 5211

-230.000 229.670 20.000 0.03570 130.512 3965.97 127.97 107.48 1.19527 0.531 0. 7 64 5142

-220. 000 239.670 27.600 0.03613 125.034 3615.63 134.89 195.10 1.22778 0.525 0.762 5066

-210.000 249.670 27.352 0.03656 119.797 3665.27 141. 60 202.73 1.25696 0.521 0.763 4966

-200.000 259.670 27.026 0. 01700 114.793 3517. 17 148.70 210.37 1.28897 0.519 0.765 4903

-190.000 269.670 26.699 0.03745 110.011 3372.94 155.62 218.03 1.31793 0.516 0.767 4021

-100.000 279.670 26.373 0.01792 105.440 3233.75 162.52 225.71 1.34587 0.511 0.767 4742

-170.000 209.670 26. 047 0.01839 101.070 3100.33 169.38 233.36 1.37274 0.502 0.762 4671

-160.000 299. 670 25.721 0. 03088 96.091 2973. 16 176. 15 240.94 1.39647 0.489 0.754 4609

-150.000 309.670 25.396 0.03938 92.094 2652.46 102.60 246.42 1.42305 0.475 0.744 4550

-140.000 319.670 25.070 0.03909 89.072 2738.28 189.40 255.87 1.44669 0.473 0.746 4473

-130.000 329.670 24.745 0.04041 85.416 2630.52 195.97 263.32 1.46962 0.467 0.743 4405

-120.000 339. 670 24.421 0. 04095 01.920 2529. 00 202.50 270.75 1.49181 0.462 0.742 4338

-110.000 349.670 24.097 0.04150 78.577 2433.47 209.00 270.16 1.51332 0.458 0.741 4271

-100.000 359. 670 23.775 0.04206 75.383 2343.63 215.47 285.57 1.53421 0.455 0.740 4205

-90.000 369.670 23.454 0.04264 72.329 2259. 17 221.91 292.97 1.55451 0.452 0. 740 4140

-00. 000 379.670 23. 135 0. 04322 69.413 2179.78 228.33 300.37 1.57426 0.450 0.740 4077

-70.000 309.670 22.017 0. 04303 66.627 2105. 15 234.73 307.77 1.59350 0.448 0.740 4015

-60.000 399.670 22.502 0.04444 63.968 2034.98 241.10 315.16 1. 61223 0.443 0. 737 3960 -50.000 409.670 22.109 0.04507 61.430 1969.01 247.42 322.52 1.63043 0.441 0. 736 3903

-40.000 419. 670 21.870 0.04571 59.008 1906.90 253.71 329.89 1.64819 0.440 0.736 3846

-30.000 429.670 21.570 0.04636 56.698 1848.68 259.99 337.25 1.66553 0.440 0.737 3789

-20.000 439.670 21.265 0.04703 54.495 1793. 09 266. 26 344.63 1.68250 0.440 0.738 3734

-10.000 449.670 20.962 0.04770 52.394 1742.44 272. 51 352. 01 1.69911 0.441 0.739 3680 0.000 *59.670 20.663 0.04639 50.391 1694. 16 270.76 359.41 1.71539 0.442 0.741 3627

10.000 469.670 20.360 0.04910 48.482 1648.90 285.01 366.83 1.73135 0.444 0.743 3576

20.000 479.670 20.075 0.04901 46.663 1606.49 291.25 374.27 1.74701 0.446 0.744 3526

30.000 409.670 19.707 0. 05054 44. 929 1566. 64 297.49 381.72 1.76239 0.448 0.746 3478

40.000 499.670 19.502 0.05128 43.277 1529. 01 303.74 389.20 1.77750 0.451 0.749 3431 50.000 509.670 19.221 0.05203 41.703 1495.27 309.99 396.69 1.79236 0.454 0.751 3386

60.000 519.670 10.944 0.05279 40.203 1463. 13 316.24 404.21 1.80696 0.457 0.753 3343

70.000 529.670 10.671 0. 05356 36.773 1433. 26 322.49 411.75 1. 82133 0.460 0.755 3302

00.000 539.670 16.403 0.05434 37.412 1405.57 320.75 419.31 1. 83547 0.463 0.757 3262

100.000 559.670 17.360 0.05593 34.077 1356. 31 341.26 434.49 1. 86310 0.471 0.761 3189

120. 000 579.670 17.375 0. 05755 32.576 1314.53 353.04 449.76 1.88990 0.478 0.765 3122

140.000 599.670 16. 009 0. 05921 30.405 1279. 49 366.43 465.11 1.91593 0.487 0.769 3062

160.000 619.670 16.422 0.06089 26.503 1250.47 379.05 480.53 1.94123 0.495 0.773 3008

100.000 639.670 15.974 0.06260 26.653 1226.79 391.70 496.03 1.96584 0.504 0.777 2960

200.000 659.670 15.546 0.06432 25.278 1207.03 404.40 511.60 1.98901 0.513 0.780 2918

220. 000 679.670 15.137 0. 06606 23. 041 1193.03 417.13 527.23 2.01316 0.522 0.784 2881

240.000 699.670 14.747 0. 06701 22.530 1161.86 429.92 542.94 2. 03593 0.531 0.787 2849

200.000 739.670 14.020 0.07133 20.235 1168.67 455.68 574.55 2.07987 0.550 0.794 2796

320.000 779.670 13.360 0.07465 16.306 1165.21 401.69 606.44 2.12185 0.566 0. 801 2756

360. 000 019.670 12.761 0. 07037 16.674 1169. 20 500.02 630.62 2. 16210 0.587 0.808 2732

400.000 059.670 12.217 0.08106 15.264 1178.94 534.70 671.11 2.20001 0.605 0.816 2715

440.000 899.670 11.722 0.00531 14.092 1193. 10 561.75 703.93 2.23012 0.623 0.825 2 70 5

273
METHANE ISOBAR AT P * 10000.0 PSI

T T OEM VOL OP/DT OP/OD E H S CV CP u DEG F OEG R LB/CUFT CUFT/LB PSI/R PSICUFT/LB BTU/LB 8TU/LB BTU/LB/R BTU/LB/R BTU/LB/R FT/S

-266. 853 192. 817 29.389 0.03403 153.327 4508.70 101.67 164.67 1.05599 0.555 0.770 5386

-260.000 199.670 29.233 0.03421 149.456 4479.41 106.08 169.43 1. 08046 0.554 0. 770 5370

-250.000 209.670 28.902 0. 03460 143.547 4379.48 113.00 177.07 1.11805 0.549 0.768 5327

-240.000 219.670 28.577 0.03499 137.823 4260.43 119.91 184.70 1. 15374 0.542 0.764 5275

-230.000 229.670 28.255 0.03539 132.309 4129. 59 126.78 192.32 1.18767 0.535 0.761 5216

-220. 000 239.670 27.936 0.03580 127.016 3992.21 133.62 199.91 1. 22005 0.529 0.759 5151

-210. 000 249. 670 27.618 0.03621 121.943 3852.08 140.45 207.50 1.25108 0.525 0.759 5879

-200.000 259.670 27.302 0.03663 117.087 3711.97 147. 27 215.10 1.26092 0.523 0.761 5004

-190.000 269.670 26.987 0.03705 112.438 3573. 93 154.10 222.71 1.30970 0.520 0.762 4926

-180.000 279.670 26.673 0.03749 107.989 3439.42 160.91 230.34 1. 33745 0.515 0.761 4656

-170.000 289.670 26.359 0.03794 103.729 3309. 47 167.68 237.93 1. 36412 0.505 0.756 4790

-160.000 299.670 26.046 0.03839 99.651 3164.76 174.35 245.45 1.36965 0.492 0.747 4733

-150.000 309.670 25.734 0.03886 95.745 3065.71 180.91 252.67 1.41401 0.479 0.737 4679

-140.000 319.670 25.422 0.03934 92.004 2952. 54 187.41 260.25 1.43744 0.476 0. 739 4607

-130.000 329.670 25. 110 0.03982 88.421 2845. 31 193.88 267.63 1.46016 0.470 0. 736 4543

-120.000 339.670 24.800 0.04032 84.990 2743.95 200.31 274.96 1.48213 0.465 0.735 4480

-110.000 349. 670 24.491 0. 04083 81.704 2648.28 206.71 282.32 1.50342 0.461 0.733 4417

-100.000 359.670 24. 183 0. 04135 78.558 2558. 10 213. 08 289.65 1.52409 0.458 0.733 4355

-90.000 369.670 23.877 0.04168 75.546 2473. 15 219.42 296.97 1.54417 0.455 0.732 4294

-80.000 379.670 23.572 0. 04242 72.663 2393. 14 225.74 304.29 1.56371 0.453 0.732 4234

-70.000 389.670 23.270 0.04297 69.905 2317.79 232.03 311.61 1.58273 0.451 0.732 4175

-60. 000 399. 670 22.969 0. 04354 67.266 2246. 82 236. 29 318.91 1.60124 0.446 0.728 4124

-50.000 409.670 22.671 0. 04411 64.743 2179.97 244.51 326.19 1.61923 0.444 0.728 4069

-40.000 419.670 22. 375 0.04469 62.330 2116. 99 250.71 333.47 1.63678 0.443 0.728 4015

-30.000 429.670 22.082 0.04529 60.023 2057.65 256.89 340.74 1.65391 0.442 0.728 3961

-20. 000 439. 670 21.792 0. 04589 57.818 2001.73 263.05 348.03 1.67067 0.443 0.729 3906

-10.000 449.670 21.505 0.04650 55.711 1949.04 269.21 355.32 1.68708 0.443 0.730 3856

0.000 459.670 21.220 0. 04712 53.697 1899.41 275. 37 362.63 1.70315 0 . 445 0. 732 3605

10.000 469.670 20.939 0.04776 51.773 1852.69 281.52 369.95 1.71891 0.446 0.733 3755

20.000 479. 670 20.661 0. 04840 49.935 1808.72 287.67 377.30 1.73438 0.446 0.735 3707

30.000 489.670 20.387 0.04905 48. 179 1767. 38 293.83 384.66 1.74957 0.451 0.737 3660

40.000 499. 670 20.116 0.04971 46.501 1728. 53 299.99 392.04 1.76449 0.453 0.739 3614

50.000 509.670 19.849 0.05038 44.899 1692.06 306. 15 399.44 1.77917 0.456 0. 742 3570

60. 000 519. 670 19.586 0.05106 43.367 1657.92 312. 33 406.87 1.79360 0.459 0.744 3527

70.000 529.670 19. 326 0. 05174 41.905 1625.94 318.50 414.32 1.80779 0.462 0.746 3486

80.000 539.670 19.070 0.05244 40.507 1596. 05 324.69 421.79 1.62177 0.466 0.748 3446

100.000 559.670 18.571 0.05385 37.897 1542. 15 337. 10 436.81 1. 64909 0.473 0.753 3372

120.000 579.670 18.087 0.05529 35.513 1495.53 349.54 451.92 1.67562 0.481 0.756 3383

140. 000 599.670 17.621 0.05675 33.335 1455.52 362.04 467.13 1.90141 0.490 0.763 3 241

160. 000 619. 670 17.171 0.05824 31.344 1421.47 374.58 482.42 1.92650 0.498 0.767 3185

180.000 639.670 16.739 0. 05974 29.522 1392.79 387.19 497.81 1.95094 0.507 0.772 3134

200.000 659.670 16. 323 0.06126 27.855 1368.92 399.85 513.29 1.97476 0.516 0.776 3088

220. 000 679.670 15.925 0.06279 26.327 1349. 34 412.57 528.85 1.99800 0.525 0.760 3047

240.000 699.670 15.543 0.06434 24.926 1333.55 425.36 544.50 2.02069 0.5 35 0.765 3011

280.000 739.670 14.827 0. 06744 22.455 1311. 69 451. 16 576.05 2. 06454 0.553 0.793 2951

320.000 779.670 14. 172 0.07056 20.362 1300. 33 477.27 607.93 2.10652 0.572 0.601 2905

360.000 819.670 13.573 0.07368 18.578 1297.12 503.73 640.16 2.14683 0.591 0.810 2870

400.000 859.670 13.024 0.07678 17.048 1300.24 530.57 672.74 2.16564 0.609 0.619 2846

440. 000 899.670 12.522 0. 07986 15.729 1308. 34 557.81 705.68 2.22309 0.627 0.828 2629

274
V

t

FORM NBS-IKA (t-71! U.S. DEPT. OF COMM. 1. PUBLICATION OR REPORT NO. T. Csoir't Acc«*«loa~

BIBLIOGRAPHIC DATA NBSIR 73-342

3. Recipient's Accession No.

4. TITLE AND SUBTITLE

The Thermophysical Properties of Methane, From 90 to 500 K at Pressures to 700 Bar

5. Publication Date October 1973

6. Parfoming OrgBniceeion Code

7. AUTHOR(S)

R. D. Goodwin

3. Performing Organization

9. PERFORMING ORGANIZATION NAME AND ADDRESS

NATIONAL BUREAU OF STANDARDS, Boulder Labs.

DEPARTMENT OF COMMERCE

Boulder, Colorado 80302

10. Project/Task/ Work Unit No. 2750364

11. Contract/Grant No.

12. Sponsoring Organization Name and Address The American Gas Association

1515 Wilson Boulevard

Arlington, Virginia 22209

13. Type of Report & Period Covered 1970-present

Final

14. Sponsoring Agency Code

15. SUPPLEMENTARY NOTES

16. ABSTRACT (A 200-word or less (actual summary of most significant information. If document includes a significant

bibliography or literature survey, mention it here.) Thermophysical properties of methane are tabulated at uniform temperatures

from 90.68 to 500 K along isobars to 700 bar. A novel equation of state is employed

for the first time, having origin on the vapor-liquid coexistence boundary. Computations are based almost entirely on ideal gas specific heats and experimental P-p-T

data'via the equation of state, without weighting to data for derived properties. Good

agreement with such data confirms validity of the equation and method. New P-p-T

data are reported at 0.3 to 1.7 times the critical density.

17. key words (Alphabetical order, separated by semicolons) Densities? enthalpies; entropies, equation or

state; internal energies; isobars; isochores; isotherms; Joule- Thomson inversion;

latent heats of vaporization; melting line; orthobaric densities; PVT data; specific

heats: speeds of sound: vapor pressures

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