U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards

The First Spectrum

of Hafnium (Hfi)
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The First Spectrum of Hafnium (Hf i)

William F. Meggers and

Charlotte E. Moore

Office of the Associate Director

for Information Programs

National Bureau of Standards

Washington, D.C. 20234

U.S. DEPARTMENT OF COMMERCE, Rogers C. B. Morton, Secretary

Dr. Betsy Ancker-Johnson, Assisfani Secrefary for Science and Technology

NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Acfing Direcfor

Issued July 1976
Library of Congress Cataloging in Publication Data

Meggers, William Frederick, 1888-1966. The first spectrum of hafnium (Hf I)

(NBS monograph; 153)

Supt. of Docs. No.: C 13.44:153

1. Hafnium—Spectra. I. Moore, Charlotte Emma, 1898- joint author. II. Title. III. Series: United States. National Bureau of .Standards. Monograph; 153. QC100.U556 No. 153 [QC462.H5J 602'.ls [546'.514] 76-872

National Bureau of Standards Monograph 153

Nat. Bur. Stand. (U.S.), Monogr. 153, 117 pages (July 1976)

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The First Spectrum of Hafnium (Hf I)

William F. Meggers and Charlotte E. Moore

Thepresent publication terminates the work on the analysis of Hf I which was started by the

late W. F. Meggers in 1928 and left unfinished in 1966. His final line list contains some 4700 lines of which about 67 percent have been classified. Observed g-values are known for 198 levels. The

reliability of the Zeeman observations is indicated in tables containing sums of Observed and

Lande g-values for selected groups of "even" and "odd" terms. An attempt has been made to continue Meggers' analysis in LS-coupling as far as possible.

This coupling is not rigorous in Hf I, and many intervals are irregular. Consequently, the levels are given also in numerical order with the even and odd levels presented in separate tables. An ionization limit of 54700 ±600 cm"', giving an ionization potential of 6.78 ±0.07 eV has

been derived from a two-member series. The long line lists are given in two Appendices: Appendix A contains the observed Zeeman

data for the individual lines, 531 in all; Appendix B consists of the complete line list of observed

and classified lines. By far the greater part of the analysis is that of Meggers. Detailed notes explain changes that

have been introduced and additions to his work.

Key words: Spectrum, Hfi; Analysis, Hfi Spectrum; Hafnium, Analysis of first spectrum;

Zeeman effect, Hf I.

1. Introduction

The first description of the Hf i and Hf ii spectra

was reported by W. F. Meggers in 1928[1].^ This

paper contains a history of the element hafnium,

wavelength measurements of some 1500 lines in the

arc and spark spectra of hafnium between 2155 A

and 9250 A, and a list of 12 persistent lines in each

spectrum.

He and B. F. Scribner discovered the first regularities in Hfi in 1930[2]. This was achieved with the

aid of the temperature classification of the lines

obtained by A. S. King[3] from a study of the electric

furnace spectrum of hafnium, and by analogy with

the known regularities in the similar spectra Ti i[4]

and Zr i[5]. At this time the complexities in Hf i were evident; the search for significant wave-number

intervals of low terms had to be made with differences

greater than 2000 cm~^ Thus the two leading intervals in the ground term a ^F, 2356.6 cm~^ and

2211.0 cm~\ were detected. It was recognized that

extension and confirmation of these first regtdarities

would require further improvements in the basic

descriptions of hafnium spectra and, also, observation

of the Zeeman effect. Both requirements were partially met in 1932 when hafnium spectra were

reobserved with purified oxide donated by G. von

Hevesey, and the first Zeeman-effect spectrograms were made with a small rod of hafnium metal con- densed on a tungsten filament, presented for this

purpose by G. Hoist of Eindhoven. The arc and

spark spectra were remeasured, and extended from

1990 A to 10637 A. This list included nearly 1400

lines of Hfi. Magnetic splitting was also observed

for 70 Hfi lines. The earlier regularities were fully

confirmed. At this point, Meggers and Scribner

' Figures in brackets indicate the literature references at the end of this paper.

turned their attention to Hf ii and published their

analysis of this spectrum in 1934[6] with the state- ment that "Further data and analysis of the Hfi

spectrum will be published after they have been

supplemented by additional observations of Zeeman

effects, since the data at present available have

proven insufiicient for the complete identification of

Hfi spectral terms."

Attempts to improve the description of the Hfi

spectrum presented serious difficulties because of

the presence of many metallic impurity lines as well as strong background HfO spectra. Finally, in

1958, C. H. Corliss and Meggers [7] succeeded in

overcoming these complications by using "electrodeless metal-halide lamps excited at relatively

low pressure and temperature, by microwaves."

This light source was fully described in 1953 by

C. H. Corliss, W. R. Bozman, and F. O. Westfall

[8], "who showed that a bright emission spectrum of

any metal could be obtained from outgassed quartz

tubes inclosing a minute amount of any volatile

compound of that metal when excited by

microwaves."

"Lamps of hafnium iodide, hafnium bromide, and

hafnium chloride were compared" to detect atomic

hafnium lines common to the different lamps. This

"Improved Description of Hafnium Specta" ex- tends from 1284 A to 12043 A and includes some 6200

lines in all as compared with the total of 2400 lines

observed earlier.

When the present writer (CEM) requested data

on Hfi for inclusion in Volume III of "Atomic

Energy Levels," [9] about 1957, Meggers generously

provided all of his results to date, but he did not

yet have the complete 1958 line list available. In

August 1949, greatly improved Zeeman spectrograms were obtained, by courtesy of G. R. Harrison, with the Bitter Magnet at the Massachusetts

Institute of Technology. These spectrograms were supplemented from 5000 A to 9000 A by later

1
ones taken by C. H. Corliss at the National Bureau

of Standards, with a hafnium-iodide lamp as source. The beautiful standard patterns in Hf I and Hf ii, reproduced in the 1958 paper on page 270, are from

these Bureau spectrograms.

With the help from the Zeeman data. Meggers

had classified approximately 2000 lines from his

unpublished line list having the short-wave limit

1917 A. His unpublished analysis at that time

included 7 low even terms, 90 miscellaneous even

levels, 16 odd terms, 58 miscellaneous odd levels

and 132 g-values. These are recorded in reference

[9]. All subsequent work on the analysis is based

almost entirely on the description published in 1958.

He continued his study of Hf i with the aid of

electronic computers until his death in 1966. At

this time the material was turned over to C. E.

Moore, with the request that she complete the

unfinished work on which he had toiled for so many

years. This assignment was accepted very reluctantly, with the feeling that it was an obligation

she owed to her colleague, but, also, with the full realization that it would be a difficult task.

A square array had been prepared by electronic

computer by W. R. Bozman, and a printout of the

line list made by J. Sugar contained the classified

lines as entered by Meggers, assisted by Isabel D.

Murray. The line list totaled some 4700 lines of which

about 2800 or 60 percent were classified.

From the regularities already known, it was

obvious that Meggers intended to carry the analysis

much further on the basis of LS-coupling, by analogy

with Til and Zri and with the help from Zeeman data.

Consequently, the work has been carried forward

with the terms arranged by configurations exactly

according to his plan. A serious problem was to

determine how completely the Zeeman observations

had been utilized in obtaining final g-values. Many

resolved patterns had been used to derive the g- values recorded in the 1966 list of levels. The writer

was, however, unable to locate a complete summary

of g-values similar to the meticulously prepared list Meggers left for Yb ii, for example. With the idea

that more g-values could be obtained from the

original observations, she examined the observing

books of Zeeman data, recorded all observed patterns in a duplicate ledger of the line list, and

derived as complete a set of g-values as possible.

There are now 198 levels for which g-values are known as compared with about 137 listed in 1966.

The details of the reduction are described below.

2. The Analysis

Throughout the work on extending the analysis, a great effort has been made to differentiate between

the assignments by Meggers and those added later

by the writer. When a complete square array by

terms had been prepared, and the combining properties of the levels with regard to intensity, limit terms

and g-values were studied, it was evident that some

of the earlier tentative designations needed revision.

The term and configuration assignments finally

adopted are given in tables 1 and 2, for even and odd

terms, respectively. The tables are arranged similarly, with the terms grouped by configuration. The

successive columns give the configuration, term

designation, /-value, level, interval, observed g- value, Lande g-value, number of combinations, and

notes described at the end of table 1. Every user is requested to give serious attention to these notes.

They have been devised to show as explicitly as possible how far the analysis had been carried by

Meggers in 1966 in contrast to additions and re- visions made by the writer in order to present a less fragmentary interpretation. The same notes apply to

tables 2, 4, and 5. All levels having note "a" were found by Meggers

so far as can be ascertained, and those noted as "6"

by the writer. Note "c" is particularly important; it signifies that the configuration and term assignments were by Meggeis. Notes "e, /, g" indicate changes

made in Meggers' lists. To summarize, notes "a, c"

represent Meggers' work, "6, rf" indicate interpretation by the writer, and other notes are intermediate

in type.

In general, many intervals are irregular, which

is not surprising for this complex spectrum in which

both sets of levels, odd and even, overlap in position. The I/S-coupling does not hold for the more

complex configm-ations. The present terms have

been assembled on the basis of their combining

properties, intensities of the combinations, and gvalues. Many designations are subject to question

and may well need revision. For example, the level

25678.61 cm~' is very low for the 'F term in the

configuration 5d^(b ^F)6s, but the combinations are good. Similarly, the level 42061.60 cm~^ ascribed

to ^Ds in the configuration 5d 6s^(a ^D)7s has a g-value of 0.832? based on one observation. This

g-value, if correct, fits ^Gs and the line in question

may be masked. Further search for this ^Ds level

has been fruitless. There is, also, no check on the

level 28586.39 cm"^ designated as y ^Pf, which is based on only two combinations. The levels y ^G?

and y ^Gg, also need further confirmation. Colons

following the level values in tables 1 and 2 indicate

dubious entries. The number of combinations listed

in column 8 also provide a check on the reliability

of the level.

A number of gaps still exist in completing the

various groups of terms. This is regrettable, but at

present further searching by hand is not rewarding.

An array of observed and predicted terms of Hf i

is presented in table 3. This table is condensed in

form, but it is designed for use by comparison with

tables 1 and 2. Predicted terms are entered only

for those configurations having some observed

terms. Many predicted terms could be added, as shown, for example, in the array given on page xxii

of reference [9]. The line list is not exhausted (see

table 8), but most of the leading lines have been

classified (see sec. 6).

Because of the complications that arise when an

attempt is made to carry the LS-coupling scheme

2
as far as was evidently planned by Meggers, the

writer has repeated the term lists (tables 1 and 2),

by level, in the general format that Meggers was

using in the course of his work on the analysis. All

levels are tabulated in numerical order in tables 4

and 5. Table 4 contains the even levels, 164 in all. Table 5 gives the odd levels, which total 159.

In each table the respective columns list the Jvalue, the level value (cm~'), the notes described at

the end of table 1, and the number of combinations. A

single note, "a" or "6" in column 4 indicates the

miscellaneous levels, i.e., those not yet assigned a term designation. The number of levels totals 323

of which all but 26 were found by Meggers.

3. The Ionization Limit

No good series are known as yet in Hf i. By using

the term 5(/^6s^a and the center of gravity of the

terms ascribed to S<P{a ^F4)6s 7s as series terms, J. Sugar as calculated an ionization limit of 54700 ± 600

cm~^ by methods described in reference[10]. With the

conversion factor 0.000123981, the ionization potential is 6.78 ±0.07 eV.

An experimental value of the ionization potential

of Hf I, 6.65 it 0.1 eV, obtained by an electron impact

method, has been reported by E. G. Rauh and R. J. Ackerman[ll]. This value agrees well with the spectroscopic value derived above.

4. Observed g-Values

A test of the correctness of the interpretation and

of the accuracy of the Zeeman data is to be found if the g-sum rule of Pauli is applied. As Meggers stated

in the paper on Hf ii[6], this rule "is expected to be

valid for all spectra no matter what the nature of the

vector coupling may be." It should be applied to

complete groups.

A comparison of observed and Lande g-values for

LS-coupling is given for the leading even terms in

table 6, and similarly, for the odd terms in table 7. The Lande values are taken from the detailed

"Tables of Theoretical Zeeman Effect8"[12] published by C. C. Kiess and W. F. Meggers in 1928.

The terms are arranged by configuration and the

g-sums are given for each /-value in the separate

groups. The agreement is excellent for the low groups

in each table. The remaining configurations show

larger deviations, as is to be expected, since the

groups are not so complete, some designations are open to question, and there is a departure from LScoupling. These factors are inherent in such a complex spectrum.

In general, these results are a real tribute to

Meggers, whose splendid observations and measure- ments are revealed. In these tables only a few dubious

g-values are entered and these are marked with a

colon.

5. The Zeeman Observations:

The history of the Zeeman observations has been

described above briefly, and need not be repeated

here. In averaging the final g-values from the individual Zeeman observations triple weight was given

to the best fully-resolved patterns, double weight to

many other resolved patterns and less weight to

those that were not resolved. With the final averages

thus obtained for as many levels as possible, the

remaining blended patterns were carefully examined.

For classified lines having an observed g-value for one level, this value was used to derive the g-value

for the other level, on the assumption that the

strongest component had been observed in the unresolved pattern.

The final observed Zeeman data are given in

appendix A where the separate columns contain:

(1) Wavelength, (2) Intensity (Tube), (3) Intensity

(Spark), (4) Classification, (5) Type of Pattern,

(6) Ag, (7) 1st g, (8) 2nd g, (9) the strong p-component, and (10) the strong n-component. The

Zeeman type is quoted mostly from reference

[7], but some have been taken directly from the

observing books. The observed g-values used as described above for blended or unresolved patterns

are entered in parentheses. The "1st g" refers to

the first entry in column 4, i.e., the lower level

of the transition. The "2nd g" refers to the higher

level involved. The respective /-values are given

as subscripts in column 4. The Zeeman effect has

been observed for 531 lines.

6. The Classified Lines

Appendix B contains the final list of observed

and classified lines. Meggers' line list of 1966 contained more than 4700 lines in which 3217 classifications are entered. There are 88 lines which are blends having 2 classifications. The number of

classified lines is, therefore, 3129 or roughly 67

percent of the total.

The successive columns contain: (1) Wavelength,

(2) Intensity (Arc or Tube), (3) Intensity (Spark),

(4) Wave number (cm~^), (5) Wave number o-c (cm~^), (6) Classification. The levels involved in the

transition are entered in whole numbers, with the

respective /-values as subscripts. The "odd" level

of the transition is in italics. The observed data are mostly from reference [7]. In column 2 "Z" has been added for the lines having an observed Zeeman effect. For these lines, the

Zeeman data are given in appendix A.

The leading unclassified lines are listed in table 8. Lines of intensity 30 or greater are included, and the

total number is 31. They are taken from appendix B.

The wavelengths and intensities are entered in this

table with "Z" added in column 2 for those lines

having an observed Zeeman effect (app. A).

3
7. Acknowledgments 8. References

Throughout the years since W. F. Meggers en- visaged a Monograph on Hf i, a number of colleagues

have generously supported the effort. W. R. Bozman

and J. Sugar assisted with the computer preparation

of the square array and line list which have been

used in bringing the work to its present conclusion.

The late Ruth Peterson furnished the latest revised

computer list of the energy levels. Much of the careful editing of the final list of classified lines was

ably handled by the late Isabel D. Murray. The

generous contributions of all who have participated

in the work and helped to make this publication a tribute to W. F. Meggers are gratefully acknowledged. The writer is especially indebted to her husband, B. W. Sitterly, for his cordial cooperation

throughout the years.

Special thanks are due to K. G. Kessler and D. R.

Lide for their support and encouragement during

the preparation of this Monograph, and to J. L. Tech

for his valuable suggestions.

Washington, D.C.

December 9, 1975

[1] Meggers, W. F., Bur. Std. J. Res. 1, 151-187, RP8

(1928).

[2] Meggers, W. F., Bur. Std. J. Res. 4, 169-175 RP139

(1930).

[3] King, A. S., Astroph. J. 70, 105-113 (1929).

[4] Russell, H. N., Astroph. J. 66, 347-438 (1927).

[5] Kiess, C. C, and Kiess, H. K., J. Res. Natl. Bur. Std.

6, 621-672, RP296 (1931).

[6] Meggers, W. ¥., and Scribner, B. F., J. Res. Natl. Bur.

Std. 13, 625-657, RP732 (1934).

[7] Corliss, C. H., and Meggers, W. F., J. Res. Natl. Bur.

Std. 61, No. 4, 269-324, RP2904 (1958).

[8] Corliss, C. H., Bozman, W. R., and Westfall, F. O., J. Opt. Soc. Am. 43, No. 5, 398-400 (1953).

[9] Moore, C. E., "Atomic Energy Levels" Circ. Natl. Bur.

Std. 467, III, 143-146 (1958).

[10] Sugar, J., J. Chem. Phys. 59, 788-791 (1973).

[11] Rauh, E. G., and Ackermann, R. J., J. Chem. Phys.

60, 1396-1400 (1974).

[12] Kiess, C. C, and Meggers, W. F., Bur. Std. J. Res. 1, 641-684, RP23 (1928).

4
Table 1. Even Terms of Hf i

Configuration Desig. J Level Interval Obs. g Lande g No.

Comb.

Notes

a 'F 2 0. 00

2356. 68

2210. 96

0. 696 0. 667 67 a, c o ooc^ Aft 1 nQ9 i. Uoo 7ni\j a, c

1 9/1 n 1. ZDU Z1^9 a, c

a 3P 0 5521. 77

1050. 77

O/l 1 1 OA z41i. ZO

0. 000 % 28 a, c

1 6572. 54 1.496 1. 500 56 a, c 2 8983. 74 1. 300 1. 500 86 a, c

a iG 4 10532. 55 1.007 1. 000 59 a, c

OO* OS* 9 OOOo. Ol 11. nnn a, c

5d2 6s' a 'S 0 25444. 37 % 9 a, c

5d3(6 *F)6s a 5F 12

3

4

5

14092. 26

14740. 67

15673. 32

16766. 60

17901. 28

648. 41

932. 65

1093. 28

1134. 68

0. 010

1. 007

1.248

1. 341

1.383

0. 000

1.000

1. 250

1.350

1. 400

46

60

63

47

24

a, c

a, c

a, c

a, c

a, c

it 2

3

4

23327. 71

25281 82

27074. 50

1954. 11 1792. 68

0. 902

1.144

0. 667

1. 083

1.250

38

37

22

a, c

C

a, c

5«i3(6 <P)6s a 1 20784. 87 123. 56 2.40 2. 500 27 a, c

o

991 OQ Oft 1290. 65

1. lo'i 1. 00 i

41

ZD 0, C

b 3P 0 %

1 9OC97 QO ZODZ /. Vo

-327.44

1 900 X. ^ZZ 1. ouu 1 ft Q, C Z ZoZUU. o4! 1. oVo 1. DuU Z494. 0, C

5d3(a 2H)6s a 3H 4 26922. 72:

96. 03

0.800 4 b, d

5 27018. 75 1. 033 17 a, c 6 26943. 95 -74.80 1. 167 7 a, c

ITT Cd

11, nnn vUU

a 3G 3 22880. 24

372. 57

0. 802: 0. 750 44 a, c 4 23252. 81 1.028 1.050 32 a, c 5 24085. 14 832. 33

1. 142 1.200 23 a, c

IP 11. nnn uuu

5<P(62 F)6s c 3F 2 31119. 20

-64. 56

0. 889 0. 667 15 a, c 3 31054. 64 1.085 1.083 17 a, c 4 31575. 68 521. 04

1. 150 1.250 11 a, c

a T 3 25678. 61 1.000 29 a, d

5<P(c 2D)6s a 3D 1 26918. 13

-1833. 97

1631. 22

0. 500 21 a, c 2

3

25084 16

26715. 38 1.223

1. 167

1.333

37

25

fl, c

a, c

At

fc ID 2 31619. 97 1.007 1.000 16 a, e

5
Table 1. Even Terms of Hf i—Continued

Configuration Desig. J Level Interval Obs. g Lande g No.

Comb.

Notes

b<P{b 2P)6s C V

1 OUilO. 4U 1. o71

%

1.500

1 C AA 1. 500 22 a, c

a >P 1 32091. 60 1. 167 1. 000 11 a, e

12 35115. 29

oOozo. o4

123. 65

1408. 55

U. out) 1.110

1 OAC 1. ZOD

A C AA U. 500

1.167

1. oo6

15

19

11

a, e

a, e

(« c 'D 2 38289. 39 1.085 1.000 16 a,f

c»F 12

o

4

5

39790. 69

40636. 28

AiAne OA

42670. 82

845. 59

839. 56

1194. 98

0. 591

1.065

1. 237

0. 000

1.000

1 OCA 1. Z50

1. 350

1.400

1220

23

14

a, c

a, c

a, c

a, c

31? c "r oJ,3

4

4D000. iO

45994. 61

45387. 51

328. 45

-607. 10

0. 631: 1.021:

0. 007

1.083

1.250

1 A

10

14

14

a, c

a, c

a, c

6p2('P)5rf(^D)6s b »D 0

1Oz

34

42782. 54

43013. 02: 43838. 33

233. 92

-3.44

825. 31

1.530

1.295

%

1.500

1. DUO

1.500

1.500

11

OlZl

3

13

a, c

a, c

b, d

a, c

«4 12

3

/I 91 1 1 '71

42719. 58

42360. 88

607. 87

-358. 70

0. /bo

1.182

1. 143

A C AA 0. 500

1.167

1.333

1 o la

17

15

a, c

a, c

a, c

0 ^P 12

3

45254. 92

45364. 84

-845. 86

109. 92

Z. 117

1. 038:

O C AA Z. 500

1.833

1.667

1 A

10

18

18

a, e

a, c

a, c

/ u

12

45474. 61

46437. 73 963. 12

1.420

%

1. 500

1. 500

10

24

a, c

a, c

/

oZ

3

/« 4

45649. 36 —406. 93

633. 00

0. 696

1. 178

1. Z35

0. DO / 1.083

1 OCA 1. ZoU

15

22

a, c

a, c

a, c

46 6 IF 3 45083. 30 1.000 18 a, c

c •'JJ 12

Qo

o lOOO. ZU

37038. 84

oyiZY. 64

-297. 36

2088. 80

A A on

u. 487

1. 084

1. 316

A CAA 0. 500

1. 167

1 O 0 o

1. ODO

A

y

16

1 ^10

a. c

a, c

a, c

64 d ID 2 40130. 23 1.211 1.000 21 a, d

/^»^2 /3D^ {2X>\fxr. Op^ {^r )D(l\fr

)

OS a 0

12

43561. 77

44375. 44 813. 67

1.467

1.335

%

1. 500

1.500

15

24

a, c

a, c

44 b 'P 1 46782. 78 1. 000 11 a, d

6
Table 1. Even Terms o/Hf I—Continued

Configuration Desig. J Level Interval Obs. g Lande g No.

Comb.

Notes

6p2(iD)5d(2G)6s b 3G 3

4

5

47345. 93

46992. 38

47768. 65

-353. 55

776. 27

1.142

0. 750

1.050

1.200

26

18

6

a, c

a, c

a, c

6 >G 4 47606. 23 0. 97: 1. 000 15 a, c

6j)2(iD)5d(2F)6s g 3F 23

4

46961. 96

46280. 29

46678. 15

-681.67

397. 86

0. 667

1. 083

1.250

23

19

14

a, c

a, c

a, c

c 'F 3 46966. 62 1.000 22 a, c

6i>20D)5d(2D)6s 12

3

47874. 42

47304. 99

47112. 37

-569.43 — 192. 62

1. 478

0. 500

1. 167

1.333

15

27

14

a, c

a, c

a, c

2 47702. 42 1.000 15 a, c

6pH'D)5d(2P)6s g

0

12

47751. 22

47309. 20

47867. 65

-441. 92

558. 35

1.529

%

1.500

1.500

6

14

10

b, d

a, c

a, d

c IP 1 48129. 58 1.000 11 a, c

6p'('D)5d(2S)6s 3S 1 2. 000

'S 0 %

6p'(»S)5(i(2D)6s g 3D 12

3

48309. 88

47955. 19

47896. 90

-354. 69

-58. 29

0. 500

1.167

1. 333

8

24

15

a, d

a, c

ct, c

g ID 2 48407. 25 1.000 23 a, c

5d 6sHa 2D)7s d 3D 12

3

39546. 34

40513. 53

42061. 60:

967. 19

1548 07

0. 815

1. 091

0. 832:

0. 500

1. 167

1.333

12

23

14

«,/

«,/

e »D 2 46183. 08 0.942 1.000 22 a,/

5d2(3F)6s(a *F)7s 6 T 12

3

4

5

39286. 18

39788. 90

40882. 08

42283. 54

44132. 02

502. 72

1093. 18

1401. 46

1848. 48

0.216

1.009

1.230

1.353

1.400

0. 000

1.000

1.250

1. 300

1.400

18

18

17

16

9

a, c

a, c

a, c

a, c

a, c

it d 3F 2

3

4

41298. 36

43489. 29

44777. 53

2190. 93

1288. 24

0.826

1. 196: 1.248

0. 667

1.083

1.250

27

23

19

a, c

a, c

a, c

5d2('P)6s(a <P)7s c 12

3

46937. 92

46860. 74

47938. 44

-77. 18

1077. 70

1. 285:

1.33:

2.500

1.833

1.667

9

15

19

a, d

a, e

a, d

7
Table 1. Even Terms o/Hf i—Continued

Configuration Desig. J Level Interval Obs. g Lande g No.

Comb.

Notes

5(i2(3P)6s(a«P)7s e 3P 0

12

44940. 00: 45270. 13

45728. 61

330. 13

458. 48

1.376

%

1.500

1. 500

4

15

16

b, d

a, e

a, d

5d2('F)6s(a2F)7s i 3F 2

34

48459. 08

48746. 51

49005. 36

287. 43

258. 85

0. 667

1.083

1.250

14

16

20

a, d

a, d

a, d

d IF 3 48049. 44 1.000 16 a, d

5tZ2('D)6s(6'D)7s 1230. 500

1. 167

1. 333

tt 2 1.000

5<i2(3P)6s(a2P)7s 3p 0

12

%

1.500

1.500

tt •P 1 1.000

5d2 0G)6s(a2G)7s 3

4

5

0. 750

1.050

1.200

tt >G 4 1.000

a 6D 0

12

34

39843. 86

40618. 63

41211. 02

41739. 39

42175. 62

774. 77

592. 39

528. 37

436. 23

1.511

1.444

1.338

1. 281

0/0

1.500

1.500

1.500

1.500

4

1118

21

14

a, c

a, c

a, c

a, c

a, c

6 3H 4

56

48022. 20

49180. 66

50888. 76:

1158. 46

1708. 10

0. 800

1. 033

1. 167

15

9

3

a, c

a, c

b, d

c 3G 3

4

5

48598. 99

48356. 92

49540. 65

-242. 07

1183. 73

0. 505: 0. 750

1.050

1.200

18

14

11

a, d

a, c

a, c

A 'F 23

4

48991. 42

48869. 45

48220. 74

-121. 97

-648. 71

0. 667

1.083

1.250

26

23

17

a, c

a, c

a, c

5d* /l 3D 123

48982. 17: 48906. 42

48809. 77

-24. 25

-96. 65

0. 500

1. 167

1. 333

9

13

14

a, d

a, g

a, c

5d* 3p 0

12

0/0

1.500

1. 500

8
Table 1. Even Terms of Hfi—Continued

Configuration Desig. / Level Interval Obs. g Lande g No. Notes

Comb.

Miscellaneous Levels

3 46181. 42 12 a

2 48179. 12 14 a

3 48319. 12 23 a

2 48552. 34 13 a

2 48594. 81 21 a

5p? 2 48708. 44 1.857 24 a, e 5 49178. 34: 4 b 3 49347. 30 1.304 20 a, e 2 49403. 97 14 a

2 49438. 81 10 a

1 49446. 83 8 a 4 49623. 42 18 a

3 49660. 56 26 a

3 49791. 86 24 a

3 49999. 13 1.398 11 a

2 50193. 24 17 a

5 50279. 54 9 a

4 50393. 21 14 a

3 50680. 42 1. 146: 10 a

1 50828. 57: 8 a

2 50891. 34 9 a

1 51091. 22 7 a

4 51201. 45 11 a

5F 4 51390. 77 10 b 3 51395. 73 20 a

5 51408. 67 16 a

2 51508. 36 10 a

3 51556. 21 12 b

4 51640. 33 12 a

2 51771. 56 10 a

2 51782. 92 8 a

3 51847. 43 11 a

5 51929. 94 10 a

Notes to Tables 1 to 4 a Level found by W. F. Meggers.

b Level new; added by C. E. Moore.

c Configuration and term .designation assigned by W. F. Meggers.

d Configuration and term designation assigned by C. E. Moore.

e Configuration and term designation by W. F. Meggers changed in present work.

/ Configuration by W. F. Meggers changed in present work.

g Term designation by W. F. Meggers changed in present work.

9
Table 2. Odd Terms of Hf i

Configuration Desig. / Level Interval Obs. g Lande g No.

Comb.

Notes

5a OS'' (a 'iJ)bp z 'r 14400. IZ

106. 54

3683. 31

0. Oo7 72 a, c

3 14541. 66 1. 085 1. 083 68 a, c 4 18224. 97 1. 246 1.250 30 a, c

z 'U 1 14U1 1. Ol

2145. 54

2218. 15

A C AA 0. 500 57 a, c 2 16163. 35 1. 172 1. 167 77 a, c

3 18381. 50 1. 287 1. 333 68 a, c

u

1

7 007n 7 9 loZ/U. Iz

18143. 39 -126.73

1647. 90

A AAA

1.428

%

1. 500

1146a, c

a, c

1 AT 4

1. 414 1 C AA 1. 500 56 a, c

z 'J?

•> o Zoo44. l4 1. U /4 1 AAA 1. 000 56 a, c

z iD° 2 10508. 88 0. 805 1.000 70 a, c

z iP° 1 26463. 93 0.996 1. 000 35 a, c

5d2(a 'r)6s(o ^F)6/> Z 5G° 2

3

18011. 04

19292. 68

1281. 64

1667. 42

1941. 26

2560. 73

0. 394

0. 952

0. 333

0. 917

48

69

a, c

a, c 4

7/1 1. 157 1 1 CA

1. 150 iZ a, c

5 22901. 36 1.276 1.267 19 a, c 6 25462. 09 1.38: 1.333 4 a, c

Z 5F° 1 21738. 70

711. 84

998. 06

1336. 64

1417. 29

0. 030 0. 000 40 a, c 2 22450. 54 1.011 1. 000 58 a, c 6 Zo44o. uU 1. 204 1 OCA 1. z50 C A59 a, c 4 24785. 24 1.330 1.350 35 a, c 5 26202. 53 1. 357 1.400 22 a, c

Z 5D° 0 24966. 78

227. 70

439. 72

671. 58

1210. 62

0. 000 % 10 a, c

1 25194. 48 1. 447 1.500 31 a, c z Z00o4. ZU 1 y1 1 O 1 r AA 1. 500 CO5z a, c 3 26305. 78 1.396 1.500 57 a, c 4 27516. 40 1.474 1.500 42 a, c

"IJ"' O 3 OOCOO /TO 662. 96

1730. 35

A A/1 A 0. 94u 0. 750 Cl51 a, c 4 29246. 65 1.071 1.050 35 a, c

5 30977. 00 1.213 1.200 22 a, r.

Z Zll4y. 04

504. 69

3078. 90

A AAQ 0. OO / CA50 a, c 3 27654. 33 1. 157 1. 083 49 a, c 4 30733. 23 1.277 1.250 32 a, c

12

28790. 24

28267. 40

COO QA

1729. 42

0. 966

1. 139

0. 500

1. 167

24

45

a, c

a, c 3 29996. 82 1. 232 1. 333 49 a, c

5d2(a 3P)6s(a <P)6p y 0

1

27231. 74

27533. 74

302. 00

991Q 11

1589. 65

600. 81

1.264

%

1.500

10

31

a, c

a. g

2 29752. 85 1.498 1. 500 40 a, c 3 31342. 50 1. 387 1. 500 35 a, c 4 31943. 31 1. 401 1. 500 35 a, c

10
Table 2. Odd Terms of Hf i—Continued

Configuration Desig. J Level Interval Obs. g Lande g No.

Comb.

Notes

5d2(a3P)6s(a *P)6p 2 5P° 12

31952. 25

33121. 48

1169. 23

17. 65

2. 080

1. 342

2. 500

1.833

20

27

a, c

a, c 3 33139. 13 1. 441 1. 667 42 a, c

Z 5S° 2 31943. 82 1. 594 2. 000 31 a, c

1 33137. 89

1810. 06

1661. 91

0. 772 0. 500 22 a, c

2 34947. 95 1. 164 1. 167 24 a, c 3 36609. 86 1. 256 1. 333 24 a, c

0 28526. 20

60. 19

815. 06

0. 000 % 6 a, c

1 28586. 39: 1.500 2 b, d

2 29401. 45 1. 748 1. 500 41 a, c

2 3S° 1 28047. 91 I. 930 2.000 26 a, c

5d2(a'r)6s(o2F)6p j3G° 34

32533. 32

33994. 71 1461. 39

1999. 02

0. 951

1.031

0. 750

1. 050

40

23

a, c

a, c

5 35993. 73 1. 130 1. 200 17 a, c

« 'F° 2 33538. 14

411. 14

2125. 76

0. 821 0. 667 26 a, c

3 33949. 38 1.088 1. 083 28 a, c 4 36075. 04 1. 063 1.250 22 a, c

1 34596. 47

2176. 38

1634. 95

0. 970 0. 500 16 a, c 2 36772. 85 1. 153 1. 167 18 a, c 3 38407. 80 1. 296 1. 333 14 a, c

2 'G° 4 38987. 85 1. 142 1. 000 19 a, e

3 34877. 04 0. 955 1.000 31 a, c

2 31610. 80 1. 004 1.000 35 a, c

5d\b 'D)6s(6 ^T))6p 23

40194. 45

43104. 70

2910. 25

2216. 79

0. 511

1. 078

0. 667

1.083

14

12 a, d

4 45321. 49 1. 250 9 b, d

1 36949. 27

1376. 19

868. 46

0. 531 0. 500 9 a,f

2 38325. 46 1. 153 1. 167 14 a, c 3 39193. 92 1.283 1.333 19 a, c

X

AU o i o^o. /

1

0u. onn uuu /o O h ,1u

1 38151. 72 1.433 1.500 8 a, c

2 39435. 19

308. 01

1. 355 1. 500 10 a, c

3 36237. 34

1283. 47

1. 047 1. 000 20 a, c

X 'D° 2 41768. 67 0. 926 1.000 12 a, d

1 35284. 32 1. 061 1.000 15 g

11
Table 2. Odd Terms of Hf i—Continued

Configuration Desig. / Level Interval Obs. g Lande g No.

Comb.

Notes

5d2(a 3P)6s(a 'P)6p 12

39704. 40

40267. 32

562. 92

500. 11

0.618

1.082

0. 500

1. 167

10

15

a, d

GE, C 3 40767. 43 1. 215 1. 333 11 C

0 41133. 80

60. 14

881. 87

0. 000 % 2 b, d

1 41193. 94 1.319 1. 500 11 a, d

2 42075. 81 1. 232 1. 500 10 a, d

ago 1 2. 000

2 43517.82 0. 997 1.000 13 a, d

1 40704. 12 1. 153 1.000 8 0^ d

Igo 0 %

5d^(a 10)65(0 2G)6p z 3H° 4

5

34805. 90

36419. 26 1613. 36

882. 33

0. 992

1. 118

0. 800

1. 033

19

14

a, e

ct, c 6 37301. 59 1.15: 1. 167 6 a, d

3 0. 750

4

5

36850. 04

38845. 45 1995. 41

1.062

1. 208

1.050

1. 200

20

12

a, e

a, c

2

3

33994. 86

35453. 82

1458. 96

1816. 02

0. 934

1. 002

0. 667

1. 083

24

32

a,f

a,f

4 37269. 84 1. 165 1. 250 21 a, g

5 42166. 60: 1. 000 2 b, d

4 42453. 70 1. 034 1. 000 7 Ctf c

3 42395. 66 1. 062 1. 000 14 a, c

5d'(6 <F)6p y 5G° 2

3

40957. 53: 41422. 44

464. 91

448. 56

1666. 49

586. 90

0. 78: 0.9340. 333

0. 917

8

11

a, c

a, c 4 42871. 00 1. 144 1. 150 9 a, c 5 44537. 49 1. 247 1.267 6 a, c 6 45124. 39: 1.326 1.333 1 a, c

y 6F° 1 43786. 59

717. 13

608. 50

1177. 46

1077. 18

0. 170 0. 000 9 a, c 2 44503. 72 1.014 1.000 6 a, c 3 45112. 22 1.250 12 a, c 4 46289. 68 1. 269 1.350 8 a, c

5 47366. 86 1. 310 1.400 7 b, d

0 45533. 45

266. 04

370. 62

900. 56

977. 23

/o 3 b, d

1 45799. 49 1. 426 1.500 8 a, d

2 46170. 11 1. 500 9 a, d

3 47070. 67 1. 500 9 a, d

4 48047. 90 1.500 10 a, d

12
Table 2. Odd Terms of Hfi—Continued

Configuration Desig. J Level Interval Obs. g Lande g No.

Comb.

Notes

w 3G° 3

4

5

4,6775. 95

48236. 17

49389. 44

1460. 22

1153. 27

0. 750

1.050

1.200

710

6

a, d

a, d

a, d

t 'r° 2

3

4

50084. 58

50354. 52

52581. 23:

269. 94

226. 71

0. 667

1.083

1.250

8

9

8

a, d

a, d

a, d

12

3

49204. 11 50879. 35: 51739. 26:

1675. 22

859. 91

0. 500

1.167

1.333

74

4

a, d

b, d

b,d

w 5D° 0

12

3

4

48985. 40

48259. 17: 50364. 65

50857. 91 51968. 59

-726. 23

2105. 48

493. 26

1110. 68

%

1.500

1. 500

1. 500

1.500

4

9

8

78

a, d

a, d

b, d

a, d

a, d

J 5P° 12

3

47876. 61

48951. 98

48647. 51

75.37

-304. 47

2. 500

1.833

1.667

714

8

b, d

a, d

a, d

2. 000

t 'D° 12

3

42485. 49

44463. 51

0. 859

1. 292

0. 500

1. 333

9

9

a, d

a, d

0

12

42036. 40 1.229

%

1. 500

1.500

11 a, d

ago 1 2. 000

4

56

49268. 25

51641. 85 1. 084:

0. 800

1. 033

1.167

10

4

a, d

b, d

3

4

5

47931. 85 0. 828 0. 750

1. 050

1. 200

4 b, d

u W° 2

3

4

42302. 11 41824. 58

41175. 36

-477. 53

-649. 22

0. 861

1. 131:

1. 203

0. 667

1.083

1. 250

16

19

13

a, d

a, d

a, d

'H° 5 1. 000

X 'G° 4 43794. 60 1.038 1.000 8 a, d

t; 1F° 3 44049. 25 1. 024: 1.000 9 a, d

13
Table 2. Odd Terms of Hf i—Continued

Configuration Desig. Level Interval Obs. g Lande' g No.

Comb.

Notes

Miscellaneous Levels

1 43844. 62 1. 363 12 a

1 44257. 57 1. 216: 9 a

2 45138. 88 11 a

3 45455. 14 10 a

3 45522. 34 7 a

2 45848. 38 10 a

3 46218. 21 8 a

1 46460. 74 8 b

2 46981. 19 7 a

1 47092. 01 8 a

2 47345. 10 12 a

3 47590. 11 1. 346 10 a

1 47640. 24 7 b

3 47884. 71 11 a

2 47937. 90 8 b

3 48081. 48 13 a

3 50583. 62 7 a

4 53063. 82 5 a

0 53853. 61 3 a

2 57622. 92 6 b

2 58115. 27 8 b

14
Table 3. Observed and Predicted Terms of Hf I

Config.

5d*

5<P 6s

5d' 6s2

5d2 6s 7s

5d 6s2 7s

5d 6s 6p2

Even Terms

IS

3S

IS

a

3p

3p

6 3p

C 3P a iP

a 3P

C 6P

C 'P

3p

>P

d 3P

6 >P g

3p

C iP

a 5D

ID IF ID

a 3D

6 ID

b 3D

c 'D

ID

3D

»D

c 3D

c 3D

d ID

f 3D

/ 'D

g 3D

g ID

a 6r

6 3F

c 3F a 'F

a 3F

b 5F

d 3F

i 3F

(Z IF

d 3D

e 'D

fc «P 6 5D c 6F

e 3F

/

6 'F g 3F

c IF

c 3G 6 3H

a 3G

iG

3G

»D

3G

iG

a m

Config.

5^3 6p

5d^ 6s 6p

5d 6s^ 6p

Odd Terms

X 5D° y 5F° y 6G°

S 3D° t W° w 3G°

«S° y

spo ^ 5D°

3S° i; 3P° t 3D° « 3F° t, 3G° y m°

V 'F° X 'G° iH°

Z 5D° 2 6F° 2 5G°

J 3D° y 3F° 2 3G°

2 5S° 2 5P° y 5D°

2 3S° y

3po ^ 3D°

w 3D° a; 3F° y 3G°

Jy iD° u y 1 ^

apo

J, 3D° V 3F°

y >P° X iD° iF°

M 3D°

X 'P" m; 'D°

y 'F° 2 iG°

iF°

3S° W 3P° M 3£)0 Igo

m; 3F° 3G° 2 3H°

M) 1F° y 1G° z 1H°

2 3P° 2 3D° 2 3F°

z >P° 2 'D° z iF°

15
Table 4. Even Levels of Hf I

/ Level Obs. g Notes No. Comb. J Level Obs.g Notes No. Comb.

2 0. 00 0. 696 a, c 67 2 41298. 36 0. 826 a, c 27

3 2356. 68 1. 082 a, c 70 3 41475. 84 1.277 a, c 23

4 4567. 64 1. 240 a, c 52 3 41739. 39 1.338 a, c 21

0 5521. 77 0. 000 a, c 28 3 42061. 60 0. 832: 14

2 5638. 61 1. 164 a, c 85 1 42111. 71 0. 756 a, c 13

1 6572. 54 1.496 a, c 56 4 42175. 62 1. 281 a, c 14

2 8983. 74 1. 300 a, c 86 4 42283. 54 1. 353 a, c 16

4 10532. 55 1. 007 a, c 59 3 42360. 88 1. 143 a, c 15

1 14092. 26 0. 010 a, c 46 4 42670. 82 1.237 a, c 14

2 14740. 67 1. 007 a, c 60 2 42719. 58 1. 182 a, c 17

3 15673. 32 1. 248 a, c 63 1 42782. 54 1. 530 a, c 11 4 16766. 60 1. 341 a, c 47 3 43013. 02: 6, d 3

5 17901. 28 1. 383 a, c 24 2 43016. 46 a, c 21

1 20784. 87 2. 40 a, c 27 3 43489. 29 1, 196: a, c 23

2 20908. 43 1. 734 a, c 41 1 43561. 77 1.467 a, c 15

3 22199. 08 a, c 25 4 43838. 33 1. 295 a, c 13

3 22880. 24 0. 802: a, c 44 5 44132. 02 1. 400 a, c 9

4 23252. 81 1.028 a, c 32 2 44375. 44 1. 335 a, c 24

2 23327. 71 0. 902 a, c 38 4 44777. 53 1.248 a, c 19

5 24085. 14 1. 142 a, c 23 0 44940. 00: b, d 4

2 25084. 16 a, c 37 3 45083. 30 a, c 18

3 25281. 82 1. 144 a, c 37 2 45254. 92 1. 038: a, c 18

0 25444. 37 a, c 9 1 45270. 13 1. 376 a, e 15

3 25678. 61 a, d 29 3 45364. 84 a, c 18

3 26715. 38 1. 223 a, c 25 4 45387. 51 1. 021 a, c 14

1 26918. 13 a, c 21 1 45474. 61 1. 420 a, c 10

4 26922. 72: b, d 4 3 45649. 36 1. 178 a, c 22

6 26943. 95 a, c 7 2 45666. 16 a, c 10

5 27018. 75 a, c 17 2 45728. 61 a, d 16

4 27074. 50 a, c 22 3 45994. 61 0. 631: a, c 14

2 28200. 54 1. 393 a, c 24 2 46056. 19 0. 696 a, c 15

1 28527. 98 1. 222 a, c 18 1 46100. 78 2. 117 a, e 10

2 30146. 40 1. 371 a, c 22 3 46181. 42 a 12

3 31054. 64 1. 085 a, c 17 2 46183. 08 0. 942 a,f 22

2 31119. 20 0. 889 a, c 15 3 46280. 29 a, c 19

4 31575. 68 1. 150 a, c 11 4 46282. 36 1.235 a, c 21

2 31619. 97 1. 007 a, e 16 2 46437. 73 a, c 24

1 32091. 60 1. 167 a, e 11 4 46678. 15 a, c 14

1 34991. 64 0. 505 a, e 15 1 46782. 78 a, d 11 2 35115. 29 1. 110 a,g 19 2 46860. 74 a, e 15

3 36523. 84 1. 265 a, e 11 1 46937. 92 1. 285: a, d 9

2 37038. 84 1. 084 a, c 16 2 46961. 96 a, c 23

1 37336. 20 0. 487 a, c 9 3 46966. 62 a, c 22

2 38289. 39 1. 085 a,f 16 4 46992. 38 a, c 18

3 39127. 64 1. 316 a, c 16 3 47112. 37 1. 478 a, c 14

1 39286. 18 0.216 a, c 18 2 47304. 99 a, c 27

1 39546. 34 0. 815 a,f 12 1 47309. 30 1. 529 a, c 14

2 39788. 90 1. 009 a, c 18 3 47345. 93 a, c 26

1 39790. 69 0. 591 a, c 12 4 47606. 23 0. 97: a, c 15

0 39843. 86 a, c 4 2 47702. 42 a, c 15

2 40130. 23 1. 211 a, d 21 0 47751. 22 b, d 6

2 40513. 53 1. 091 a,f 23 5 47768. 65 1. 142 a, c 6

1 40618. 63 1. 511 a, c 11 2 47867. 65 a, a 10

2 40636. 28 1. 065 a, c 20 1 47874. 42 a, c 15

3 40882. 08 1. 230 a, c 17 3 47896. 90 a, c 15

2 41211. 02 1.444 a, c 18 3 47938. 44 1.33: a, d 19

16
Table 4. Even Levels of Hf i—Continued

J Level Obs. g Notes No. Comb. J Level Obs. g Notes No. Comb.

z ct, c Z4 9 4y400. ol a 10

A4 a, c

1 c 10 11 4y440. 00 a

00

QO

110fk cD 4y04\i. DO a, c

1

1

11

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1

1

AQM^ 4yDZ0. d.9 4Z a

1 0

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A G, c 1 i 0 4.0701 4y Rf, i yi. 00 a Z4

i 4oouy. c)o nct, aA Q0

0 AOQOQ 1

4yyyy. 10 a 11

Q 4ooiy. iz d ZO 9 ouiyo. Z4 a

1 7

A4

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1 /I 14 ^0970 t^/l ouz jy. 04 a 9

^iyhv I, ZD CE, c Zo 4; ouoyo. Cfi^Q^ zi91 a

1 A

Z ^o'toy. Uo u, ct 14 0

OUDoV/. CfiARft 4.9 4Z 1. 140: a 1 A

Z

/IQCCO Q/l 4oOOZ. O'i GE 10 11 ouozo. 0 J

:

a

00

z 'looy'i!. oi 01Zl £. CflQQO 7A.

0, a

00

6 woyo. yy V. ouo: 1ioft 9 ouoyi. 04 a y

Z i. OO 1 a, e Z49/1 11 oiuyi. ClAQl 99zz a

7

oO 40 i40. Di n fl 110 A ci 9m AC OlZvl. 40 a

1

1

11

oo

/I QftAQ 77 4o(>vy. i / ct, c 114A oloyv. ciOQn 771 i L01 AlU

oo

A QQAQ /I 4oo0y. 40 (Z, c

9^* ZO 00 CIQQC 70 oloyo. to a OAZU

A QOAA /I 0 4c)yU0. 4Z g

110^ cD AHQ A7 Ol4Uo. 0 i a

1 Alo

i

/I QOQO 17. 4oyoz. 1 i

:

r, rl CL^ a

0y

0Z

CI t-AO 0/; OloUo. 00 a

1 AlU

Z

/iQOOl /10 4oyyi. 4z a, c zo9^; OlOOO. CI cc/; Zl91 L01 0IZ

A4 4yuuo. OO zu9fl 0104U. ci f,Af\ 00 a.

1 0IZ

5 49178. 34: b 4 2 51771. 56 a 10

5 49180. 66 a, c 9 2 51782. 92 a 8

3 49347. 30 1.304 a, e 20 3 51847. 43 a 11

2 49403. 97 a 14 5 51929. 94 a 10

Table 5. Odd Levels of Hf i

/ Level Obs. g Notes No. Comb. / Level Obs. g Notes No. Comb.

2 10508. 88 0. 805 a, c 70 6 25462. 09 L 38: a, c 4

1 14017. 81 0. 542 a, c 57 2 25634. 20 L 418 a, c 52

2 14435. 12 0. 903 a, c 72 5 26202. 53 1.357 a, c 22

3 14541. 66 1.085 a, c 68 3 26305. 78 1.396 a, c 57

2 16163. 35 1.172 a, c 77 1 26463. 93 0. 996 a, c 35

2 18011. 04 0. 394 a, c 48 2 27149. 64 0. 993 a, c 50

1 18143. 39 1. 428 a, c 46 0 27231. 74 a, c 10

4 18224. 97 L 246 a, c 30 4 27516. 40 1.474 a, c 42

0 18270. 12 0. 000 a, c 11 1 27533. 74 1.264 a,g 31

3 18381. 50 1.287 a, c 68 3 27654. 33 1. 157 a, c 49

3 19292. 68 0. 952 a, c 69 1 28047. 91 1.930 a, c 26

2 19791. 29 1.414 a, c 56 2 28267. 40 1. 139 a, c 45

4 20960. 10 \. 157 a, c 32 0 28526. 20 0. 000 a, c 6

1 21738. 70 0. 030 a, c 40 3 28583. 69 0.940 a, c 51

2 22450. 54 1.011 a, c 58 1 28586. 39: b, d 2

5 22901. 36 1.276 a, c 19 1 28790. 24 0. 966 a, c 24

3 23448. 60 1.204 a, c 59 4 29246. 65 1.071 a, c 35

3 23644. 74 1.074 a, c 56 2 29401. 45 1.748 a, c 41

4 24785. 24 L 330 a, c 35 2 29752. 85 1.498 a, c 40

0 24966. 78 0. 000 a, c 10 3 29996. 82 1.232 a, c 49

1 25194. 48 1.447 a, c 31 4 30733. 23 1.277 a, c 32

5 30977. 00 1.213 a, c 22

17
Table 5. Odd Levels of Hf i—Continued

TJ JLiCVCl yjDb. g

i. 'I O ICo rJ UDS. g

i 1 oxes

3 31342. 50 1.387 a, c 35 2 43517. 82 0. 997 a, d 13

2 31610. 80 1.004 a, c 35 1 43786. 59 0.170 a, c 9

4 31943. 31 1.401 a, c 35 4 43794. 60 1.038 a, d 8

2 31943. 82 1.594 a, c 31 1 43844. 62 1.363 a 12

1 31952. 25 2. 080 a, c 20 3 44049. 25 1. 024 a, d 9

3 32533. 32 0. 951 a, c 40 1 44257. 57 1.216: a 9

2 33121. 48 1.342 a, c 27 3 44463. 51 1.292 a, d 9

1 33137. 89 0. 772 a, c 22 2 44503. 72 1.014 a, c 6

3 33139. 13 1.441 a, c 42 5 44537. 49 1. 247 a, c 6

2 33538. 14 0.821 a, c 26 3 45112. 22 a, c 12

3 33949. 28 1.088 a, c 28 6 45124. 39: 1.326 a, c 1 4 33994. 71 1.031 a, c 23 2 45138. 88 a 11

2 33994. 86 0. 934 a,f 24 4 45321. 49 b, d 9

1 34596. 47 0. 970 a, c 16 3 45455. 14 a 10

4 34805. 90 0. 992 a, e 19 3 45522. 34 a 7 3 34877. 04 0. 955 a, c 31 0 45533. 45 b, d 3 2 34947. 95 1.164 a, c 24 1 45799. 49 1. 426 a, d 8

1 35284. 32 1.061 a,g 15 2 45848. 38 a 10

3 35453. 82 1.002 a,f 32 2 46170. 11 a, d 9

5 35993. 73 1.130 a, c 17 3 46218. 21 a 8

4 36075. 04 1.063 a, c 22 4 46289. 68 1. 269 a, c 8

3 36237. 34 1.047 a, c 20 1 46460. 74 b 8

5 36419. 26 1.118 a, c 14 3 46775. 95 a, d 7 3 36609. 86 1.256 a, c 24 2 46981. 19 a 7 2 36772. 85 1.153 a, c 18 3 47070. 67 a, d 9

4 36850. 04 1.062 a, e 20 1 47092. 01 a 8

1 36949. 27 0. 531 9 2 47345. 10 a 12 4 37269. 84 1.165 21 5 47366. 86 1.310 b,d 7 6 37301. 59 1.15: a, d 6 3 47590. 11 1. 346 a 10

0 37843. 71 0. 000 b,d 2 1 47640. 24 b 7

1 38151. 72 1.433 a, c 8 1 47876. 61 b, d 7

2 38325. 46 1.153 a, c 14 3 47884. 71 a 11 3 38407. 80 1. 296 a, c 14 3 47931. 85 0. 828 b, d 4

5 38845. 45 1.208 a, c 12 2 47937. 90 b 8

4 38987. 85 1.142 a, e 19 4 48047. 90 a, d 10

3 39193. 92 1. 283 a, c 19 3 48081. 48 a

2 39435. 19 1.355 a, c 10 4 48236. 17 a, d 10

1 39704. 40 0. 618 a, d 10 1 48259. 17: a, d 9

2 40194. 45 0. 511 a,f 14 3 48647. 51 a, d 8

2 40267. 32 1.082 a, c 15 2 48951. 98 a, d 14

1 40704. 12 1.153 a, d 8 0 48985. 40 a, d 4

3 40767. 43 1.215 a, c 11 1 49204. 11 a, d 7 2 40957. 53: 0. 78: a, c 8 4 49268. 25 a, d 10

0 41133. 80 0. 000 b, d 2 5 49389. 44 a, d 6

4 41175. 36 1.203 a, d 13 2 50084. 58 a, d 7

1 41193. 94 1.319 a, d 11 3 50354. 52 a, d 9

3 41422. 44 0. 934 a, c 11 50364. 65 b, d 8

2 41768. 67 0. 926 a, d 12 3 50583. 62 a 7

a 41824. 58 1.131: a, d 19 3 50857. 91 a, d 7

1 42036. 40 1.229 a,f 11 2 50879. 35: b, d 4

2 42075. 81 1. 232 a, d 10 6 51641. 85 1. 084: b, d 4

5 42166. 60: b, d 2 3 51739. 26: b, d 4

2 42302. 11 0. 861 a, d 16 4 51968. 59 a, d 8

3 42395. 66 1. 062 a, c 14 4 52581. 23: a, d 8

4 42453. 70 1.034 a, c 7 4 53063. 82 a 5

1 42485. 49 0. 859 a, d 9 0 53853. 61 a 3

4 42871. 00 1.144 a, c 9 2 57622. 92 b 6

3 43104. 70 1. 078 a, d 12 2 58115.27 b 8

18
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Table 8. The Strongest Unclassified Lines of Hf I

Wavelength A

Air

Intensity

Wavelength A

Air

Intensity

X UJ3G 1 uhe C 1. Spark

60 7 OOQC f^AA 30

7612. 60 50 8 3276. 431 30 1 4708. 053 30 4Z 3239. 393 80 8Z

4U'*i. /DO 40 2 oZoU. Uoo 100 lOZ

DQAO OQ7 90 8Z OiOD. oOz 30 2

oj^io. yo * 50 2 ouo i . lyo 60 6

3528. 217 30 3076. 885 30 1 3522. 223 30 3067. 614 60 10

O'lyi. DO / 60 1 oUo /. Zo 30 0

a40o. IzU 30 1 Z / lo. 44d 30 4

50 2 zoyy. ooz 70 lOZ

044o. Zo4 100 8Z 0A71 791 ZO/1. /Zl 40 1 3392. 450 30 1 2630. 907 100 3 3303 871 30 2 2611 340 30 1 3299. 662 40 2458. 653 30

2456. 061 30

Appendix A. Zeeman Data, Hf I

1 2 3 4 5 6 7 8 9 10

Wavelength

A

Air

Intensity

Classification Zee- man

Type

1st g 2ndg

Zeeman Components

Tube Spark Strong p Strong n

8711. 20 600 100 156733-27J495 2 0. 25 1.25 1.00 0 1.75

8640. 04 2500 500 6512i- 181431 3 0. 07 1.50 1.43 0.07 (1.43, 1. 50)

8546. 43 2500 500 6572i-J82705 7 1.50 1. 50 0. 00 0 1.50

8460. 00 500 120 167664 -285835 2 0. 395 1.355 0. 960 0 2. 539

8344. 25 400 80 156733-276541 3 0. 09 1.25 1. 16 0. 28 (1.16,1.25)

8276. 94 1000 200 23563-144355 2 0. 19 1. 08 0.89 0 1.46

8204. 57 2000 500 23563-145411 7 0. 00 (1.08) 1. 08 0 1.08

8173. 90 300 70 209082 -331391 1 0. 298 1. 739 1.441 0 0. 845

8080. 26 500 100 56382-180115 3 0. 774 1. 164 0. 390 1.545 (0. 388,1.165)

7994. 76 5000 800 56382-18143! 1 0. 261 1.167 1.428 0 0. 906

7938. 06 500 100 156733-282675 2 0. 100 1.258 1.158 0 1.458

7920. 75 2000 400 5521o-18143? 7 1.43 (0. 000) 1.43 0 1.43

7845. 37 4000 800 56382-183815 2 0. 112 1. 182 1.294 0 1.518

7814. 57 400 80 147402-27533? 1 0. 264 1.005 1.269 0 0. 741

7790. 90 500 100 179015-307331 2 0. 110 1.405 1.295 0 1.845

7743. 57 150 20 156733-285831 3 0. 30 (1.25) 0. 95 0. 909 ? 7740. 17 2000 400 105324-234481 1 0. 190 1.012 1.202 0 0.442

7645. 655 400 80 179015-30977! 3 0. 175 1.388 (1.213) 0. 877 9

7624. 387 5000 1000 105324-236441 1 0. 06 (1.007) 1.07 0. 27m; 0. 81 +

7592. 977 150 30 232524-364195 2? 0. 094 (1.027) 1. 121? 0 ?

22
Appendix A. Zeeman Data, Hf I—Continued

1 2 3 4 5 6 7 8 9 10

Wavelength

A

Air

Intensity

Classification Zee- man

Type

Istg 2ndg

Zeeman Components

lube spark Strong p Strong n

7577. 02 300 40 18381§-315754 1 0. 137 (1.287) 1. 150 0 ? 7564. 24 200 40 240855-373011 7 0. 01 (1.14) 1.15 0 1. 20

7562. 93 1500 300 6572i-1979l2 1 0. 091 1.504 1.413 0 1.322

7556. 37 200 40 167664-299965 2 0.116 1.348 (1.232) 0

7463. 905 200 40 236441-370382 7 0. 003 (1.074) 1.077 0 1. 065

7437. 600 500 100 14092 1-27533! 3 1.244 0. 000 1.244 1. 244 1. 244

7423. 628 120 20 89832-224501 3 0. 30 (1.300) 1.00 0. 59 ? 7390. 729 400 60 147402 —282671 3 0. 136 1. 008 1. 144 0. 272 1. 008, 1. 144

7321. 79 150 30 56382-192921 1 0.211 (1. 164) 0. 953 0 ? 7320. 06 1000 200 45674- 18224S 7 0. 00 (1.240) 1.24 0 1. 24

7262. 587 80 10 144351-282002 3 0.49 (0. 903) 1.39 0. 97 y 7240. 87 5000 600 23563-161631 1 0. 08 (1.082) 1.16 Qw 0. 92 +

7237. 101 8000 1000 45674- 1&381I 1 0. 04 (1.240) 1.28 w 1.12

7131. 82 7000 1000 02-14017! 2 q. 145 0.696 0. 551 0 0. 841

7119. 520 700 100 179013-319431 1 0.01 1. 39 (1.401) w 1. 33

7094. 412 100 15 25194!- 39286i 3? 1.23 (1.447) 0. 22 1. 23

7063. 852 3000 400 56382-197911 3 0. 244 1. 166 1.410 0. 486 1. 165, 1. 411

6979. 61 100 20 156733 — 29996.§ 0. 02 1. 25 (1.23') 0. 06 1. 24ft 6926. 21 70 10 14092i- 285265 0 0. 00 - 0.00 Unaffected Unaffected

6911. 40 300 80 89832-234481 1 0. 100 1.291 1. 191 0 0. 991

6874. 89 40 5 O2- 145415 2 0. 384 (0. 696) 1.080 0 9

6858. 76 200 40 167664 - 313425 1 0. 035 1.352 (1.387) w 1.245

6857. 03 20 3 249665-39546, 7 0. 83 (0. 00) 0. 83 0 0. 83

6850. 06 60 8 25194! -397882 1 0. 441 1.457 1. 016 0 0. 575

6826. 55 100 10 236441-382892 7 0.01 (1.074) 1.08 0 1. 06

6818. 95 2000 300 89832-236441 1 0. 222 1. 304 1.082 0 0. 638

6789. 28 1000 100 45674-192921 2 0. 288 1.249 0. 961 0 2. 114

6773. 06 30 3 240855—388451 3 0. 12 (1. 14) 1. 26 0. 94 1. 200

6769. 924 40 5 27516S-422834 3 0. 132 (1.474) 1.342 0. 542 ? 6744. 00 7 249665- 3979O1 7 0. 58 0. 00 0. 58 0 0. 58

6716. 014 30 3 224501- 373361 2 0. 528 1.009 0. 481 0 1. 536

6713. 48 200 20 161631-310543 1 0. 083 (1. 173) 1.090 IV 0. 925

6708. 33 20 3 240855-389871 7 0. 00 1.14 (1.137) 0 1. 17

6693. 491 15 1 25194!-401303 1 0. 227 1.431 1.204 0 0. 977

6684. 50 30 2 161631-311192 3 0. 286 1. 170 0. 884 0. 578 0. 886, 1. 168

6671. 28 20 2 252813-402671 2 0. 065 1.147 (1.082) w 1. 276

6669. 34 15 2 28527i-43517l 1 0. 225 1. 222 0. 997 0 0. 772

6659. 42 40 4 147402—297521 3 0. 499 1. 002 1. 501 0. 999 1. 002, 1. 501

6587. 23 150 15 167664-31943S 3 0. 06 1.34 1.40 0. 244 1.37

6556. 48 70 6 256341-408823 1 0. 180 1.403 1.223 0 0. 862

6552. 91 20 2 147402-299961 2 0.218 1.021 1.239 0 1.673

6536. 56 15 28267l-43561i 1 0. 322 1. 133 1. 455 0 0. 811

6523. 92 30 2 197911-351152 3 0. 291 1.417 1. 126 0. 583 1. 126, 1.417

6456. 956 50 6 236445-391273 3 0. 239 1.069 1.308 0.717 1. 069, 1. 308

6429. 44 10 307333-462824 3 0. 03 1.28 1.25 0. 12 1.26

23
1

I Appendix A. Zeeman Data, Hf i—Continued [

1 2 3 4 5 6 7 8 9 10

Wavelength

A

Air

Intensity

Classification Zee- man

Type

1st g 2nd g

Zeeman Components

Tube Spark Strong p Strong n

6418. 02 10 2 56342 -412112 3 0. 024 1. 43 1.45 0. 047 1. 433

6409. 50 70 7 21738;—37336i Unaffected Unafifected 6388. 914 20 2 264631-42111, 3 0. 240 0. 996 0. 756 0. 240 0. 756, 0. 996

6386 229 300 40 23563— I8OII2 2 0. 689 1. 078 0. 389 0 2. 456

6380. 196 80 7 156733-31342? 3 0. 136 1.244 1. 380 0.408 1. 244, 1. 380

6376. 19 20 2 234483-391273 3 0. 12 1. 22 1.34 0. 35 1. 28

6338. 096 80 9 105324-260353 1 0. 392 0. 983 1.375 0 -0. 193

6318. 313 30 3 192923-351152 1 0. 164 0. 938 1. 102 0 0. 610

6311. 844 50 7 224501-382892 3 . 0. 08 1. 02 1. 10 0. 16 1.06

6299. 52 50 6 263053-421754 1 0. 17 (1.396) 1.23 0. 41m; 0. 60

6277. 197 10 1 7 0 1.108

6271. 355 15 2 232524-391933 7 0. 323 0. 960 (1.283) 0. 968 ? 6258. 79 40 4 262021-421754 2 0. 062 (1. 357) 1.295 Om; 1. 604

6256. 97 70 9 263053—422834 1 0. 041 (1. 396) 1. 355 Ow 1. 232

6241. 81 10 1 25194f-4121l2 7 0. 018 (1.449) 1.431 0 1. 415

6238. 59 100 10 23563-183811 3 0. 201 1.089 1.290 0. 605 1. 089, 1. 290

6216. 800 80 10 262021-422834 7 0. 019 (1.357) 1.338 0 1.432

6212. 00 20 2 17901 5 -339941 2 0. 360 1.378 1.018 0 2.818

6210. 680 150 20 247851-408823 2 0. 098 1. 328 (1.230) 0. 263u; 1. 620

6209. 43 40 4 56382-21738! 2 1. 134 1. 157 0. 023 0 2. 291

6198. 460 20 2 140171-301462 2 0. 817 0. 545 1. 362 0 2.179

6192. 475 50 5 236443-397882 2 0. 05 (1.074) 1.02 Ou; 1. 18

6185. 128 400 40 02-161631 3 0. 475 0. 692 1. 167 0. 949 0. 692, 1. 167

6168 66 20 2 105085—26175^ 2 0. 449 0. 774 1. 223 0 2. 122

6152. 952 10 1 294011-456493 1 0.575 1. 725 1. 150 0 0. 575

6144. 392 30 2 156733-319431 1 0. 354 1. 236 1.590 0 0. 528

6118. 16 40 6 234483-397882 2 0. 192 1. 193 1.001 0 1.577

6104. 58 20 3 233272-39074! 2 0. 283 0. 902 0. 619 0 1. 185

6098. 68 200 30 4567i-20960| 3 0. 070 1. 239 1. 169 0.278 1.204

6091. 37 20 2 27149l-43561i 1 0. 474 0. 992 1.466 0 0.518

6054. 166 80 6 145413-310543 7 0. 00 1.08 1.08 0 1.08

6040. 37 15 1 21738!-382892 2 1. 056 0. 035 1. 091 0 2. 147

6021. 77 20 2 147402-313423 2 0. 376 1.041 1.417 0 2.169

6016 78 100 20 275163—441325 1 0. 074 (1. 474) 1. 400 Om; 1. 105

6004. 18 30 2 89831-256341 3 0. 12 1.30 1.42 0. 24 1. 36±

5994. 58 10 224501-391273 2 0. 292 1.063 1.355 0 1.937

5992. 97 50 6 234483-401302 7 0. 009 (1.204) 1.213 0 1.186

5986. 62 20 2 294011-46100i 1 0. 368 1.749 2. 117 0 1.381

5978. 67 150 20 182705- 34991

1

7 0. 50 0. 00 0. 50 0 0. 50

5974. 728 80 8 197911-365233 1 0. 140 1.392 1.252 Om; 0. 972

5974. 294 200 30 183813-351152 2 0. 171 1.277 1.106 0 1.618

5938. 142 15 2 224501- 392861 2 0. 790 1.019 0. 229 0 1.809

5933. 70 150 20 18143!-34991i 3 0. 927 1.436 0. 509 0. 927 0. 509, 1. 436

5926. 48 40 5 236443-405132 7 0. 008 (1.074) 1.082 0 1.057

5902. 95 500 70 23563-192923 3 0. 135 1. 073 0. 938 0. 408 0. 938, 1. 073

5896. 63 50 4 247855-417393 7 0. 005 (1.330) 1.335 0 1.315

24
Appendix A. Zeeman Data, Hf i—Continued

1 2 3 4 5 6 7 8 9 10

Wavelength

A

Air

Intensity

Classification Zee- man

Type

c? 1st & 2nd a Zeeman Components

Tube Spark Strong p Strong n

5890. 4o 200 30 1 Ql /IQo Qttll^ ioi40i —00ii02 11 U. olZ 1 /IOC 1. 4Z5 1 113 1. llo 0 0. 800

5oo7. 45 20 2 ioUii2 —o'lyyii 1i A AQt^ /A 30/f \ (u. oV4

;

A A '7A u. 4 /y 0 0. 309

§5886. 31 30 2 iUbOZ4 —Z /0ID4 0 1.386 ? COOO /CCA 70 10 ZOD4'l3 —4UOOD2 nI 0 01 0 U. UIZ ( 1 AT/I \

( 1. U /4 j

1 AAO 1. uoz 0 1.098

5860. 42 4 io4i —0 io40o n

i 0 /I A Z. 4U 0 /I A Z. 4U A AA u. uu 0 2. 40

5858. 349 30 3 Z044O3—4UDl02 z A 11/1 W. 1X4 / 1 OA/1 \ 1. ZU4 )

1 AAA 1. uyu 0 1. 433

5849. 688 60 8 Z4U0D5 —41i (04 11 A ACO 1 1/1/1 1. 144 f 1 OA3

\

(1. ZUo

)

Oit) 0. 906

5847. 768 80 8 224505-39546i 2 0. 193 1.018 0. 825 0 1. 211

5845. 866 100 10 14017?-311192 2 0. 332 0. 559 0. 891 0 1. 223

5838. 896 40 4

lACOO OT^C/lo IU50Z4

L /0D43 11 A 1 CA 1 AO 1 1. Ool 1 1 01

1. 181 0 0. 581

5817. 475 80 6 1440D2 —0101^2 0 A 11 U, 90 1 Al 1. Ui 0. 22 0. 96

COAO OO 5802, 88 40 3 lo ioo4 —ooyy44 6

A 3A1 U. OUl 1. 000 1 ACC 1. U55 1. 247 1. 055, 1. 356

nAA n£.f\ 5799. 760 50 5 ZDO443 —4U00Z3 0 A 1 C

U. lo 1. 15 1 3 A 1. oU 0. 49 1.23

c^nc\£, ooA 5796. oz9 30 2lO'TOlo Q'TOQQ ly /yi2 —0 <U0)O2 0.' A 3Q

C

i. 42o.^ 1 AA33 1. Uyo.' 0. 641 1. 428?, 1. 093?

cn£.c A/C 5765. 96 30 4 ZZ40U2 —OV <002 '7 A AO U. UZ / 1 Al 1 \ (1. oil) 1 A3 1. Uo 0 1. 02

5765. o7 40 4

00,1 c^Ao QO^OA z A /I 1 0 U. 41Z 1 Al 3 1. Ulo A ^A1 U. OUl 0 1. 425

5758. 96 10 297522 —4/IIZ3 7 A AO U. UZ / 1 /I AO N (1. 49o; 1 AO

1. 48 0 1. 44

5756. 83 10 313421-487082 7 0. 470 (1.387) 1.857 0 1. 447

5734. 514 50 6 234481-408823 3 0. 03 1. 17? 1. 20? 0. 08 1. 18

nOA ^OD 5729. 683 20 2 156733— 03I2I2 1 U. U7 ( 1, 248

)

1 30

1. oZ Ow 1. 12

5719. 175 600 100 8980 2 —zo40oi Z A 3 A7 1. oU4 A AAT 0. 99 / 0 1. 611

5713. 2o7 100 10 Z4 <OD4 —4ZZ004 7 A AA / 1 00 A\

\ 1. ooO )

1 33 1. 00 0 1. 33

5702. 10 20 2 263051-438384 1 0. 096 (1. 396) 1.300 Oif 1. 012

5697. 25 15 2 21738f-39286i 3 0. 176 0. 008 0. 184 0. 175 0. 008, 0. 184

5683. 738 6

0COO1 /< OOTI 0 Z5Z813— 4Z8/14 7 A AA 1 1 A 1. 14 f 1 1 A A\

( 1. 144

)

0 1.14

5679. 553 30 14017i — oioly2 Z U. 4/0 A C 3 A U. 5oU 1 AA/C 1. UUo 0 1. 482

5668. 716 20 2 ZOZUZ5 4OOOO4 z A AT> u. u /z / 1 3 CT\ (.1. o5 /)

1 OQC 1. Zoo 0 1. 643

5662. 982 20 2 23644^-412982 2 0. 247 (1.074) 0.827 0 1. 62?

5662. 078 40 4 144351- 32091

1

1 0.271 0. 896 1. 167 0 0. 624

5654. 645 80 9 ZZ45O2 4UI0U2 A 0A^ U. ZUo 1 AA/C 1. UUo 1 010 1. ziz 0. 410 1. 006, 1. 212

5650. 811 50 6

1 ACAOo OOOAA 105081- 28ZUU2 6A col

U. 581 A 01 0U. olZ 1 3 A31. o9d 1. 162 0. 810, 1. 396

5644. 67 30 3

OA/IAlo /I '71 1 0 Z94U11 —4 /iiZs 1 A 0 0 C U. Z85 1. /do 1 A HQ 1. 4 /o 0 0. 908

56oJ. 450 20 2 19Z9Z3 — 3 /U302 1 A 1/1 U. 14 f f\ ACO \ (,u. ybz

)

1 AO 1. uy Om; 0. 68

5628. 29o 40 4

OO/I/IO0 /11011 234485 —41Zil2 1 A OCA U. Z50 1 OAA 1. ZUU 1 /I C A 1. 4oU 0 0. 703

§5614. 004 80 10 Z17o8i —o9o40i A nn£. A A3A U. UoV /A Ql C \ (,U. 815

)

0. 776 1. 722?

5613. 259 400 70 c/::oo oO/1/lOo 56382 — 234403 7 A AO

(1. 164) 1 1 A 1. 19 0 1. 23

C £.10 5606. 613 20 2 Z36443— 4147D3 3A 0 1 /I U. Z14 / 1 f\n A \

( i. U74

)

1 000 1. Z88 0. 643

5600. 762 60 6 23448°,- 412982 2 0. 368 1. 198 0. 830 0 1. 934

5578. 008 15 2 232524-411751 3 0.210 0. 993 (1.203) 0. 839 f

5575. 857 200 30 Z6ZUZ5— 44I3Z5 3

A AO 0. Oa 1. a5 1 30

1. 08 0. 12 1.37

CCCO TOO 5552. 128 1000 100 56382 —Z36443 11 A AO 0. 08 (1. 164) 1 AO 1. U8 Om; 0. 91

5550. 61 1000 100 O2— I8OII2 3

A OAA

0. 290 A AA0. 690 A A AA 0. 4UU 0. 586 0. 400, 0. 690

15 2 10 / DD4 — 040U04 6 U. o4d 1. o22 A OTC u. y /5 1.368 0. 975, 1. 322

5534. 638 8 1 224501-405132 3 0. 08 1.02 1. 10 0. 16 1.06

5530. 268 30 2 228803-409571 7 0. 02 (0. 802?) 0. 78 0 0. 84

25
Appendix A. Zeeman Data, Hf I—Continued

1 2 3 4 5 6 7 8 9 10

Wavelength

A

Air

Intensity

Classification Zee- man

Type

Istg 2ndg

Zeeman Components

Tube Spark Strong p Strong n

5522. 554 20 2 7 0 1. 07

5520. 01 10 1 1 Ow 0. 90 +

5510. 436 40 7 183811-365233 7 0. 026 (1. 287) 1.261 0 1. 274

5510. 116 60 6 O2— 18143! 1 0. 749 (0. 696) 1. 445 0 0

§5497. 301 50 5 224501-406362? 1 0. 18 0 1. 03

5467. 32 10 1 209082-391935 1 0.446 1. 732 1.286 0 0. 394

5465. 73 20 2 234485-417393 3 0. 13 1. 19 1.32 0. 40 1. 25 ±

5463. 31 150 20 18224S-365233 7 0. 03 1.25 (1.266) 0 1.21

5452. 92 300 30 45674 -22901! 7 0. 015 (1.240) 1.255 0 1.317

5438. 75 100 10 02-183811 2 0. 582 0. 714 1.296 0 2. 460

5435. 781 30 4 217385-401302 7 0 1. 48?

5423. 981 60 9 224501-408823 2 0. 227 1.010 1.237 0 1. 691

5404. 457 50 7 197911-382892 3 0. 325 1. 407 1. 082 0. 645 1. 081, 1. 407

5398. 655 10 1 179015—36419! 3 0. 269 (1. 383) 1. 114 1. 346 ? 5394. 896 20 3 23644§-421754 2 0. 220 1.064 1. 284 0 1. 944

5389. 336 100 20 89832-27533! 7 0.01 (1. 300) 1. 29 0 1. 31

5383. 04 40 4 232524-418241 1 0. 092 1. 039? (1.131) Ow 0. 754

5376. 302 10 1 24966s- 43561

1

7 1.480 (0. 000) 1.480 0 1.480

5373. 863 300 50 23563 - 209601 2 0. 071 (1.082) 1. 153 Ow 1.367

§5371. 80 2 4 1? 0. 55 0 1. 10, 1. 65

5368. 52 20 2 6572i-25194! 7 0. 06 (1.496) 1.44 0 1. 47

5358. 338 40 6 183811-370382 2 0. 200 1.279 1. 079 0 1. 679

5354. 724 200 40 254621-441325 1 0.02 1.38? (1.400) 0 1. 04+

5315. 928 15 1 26463!— 45270i 3 0. 390 0. 986 1. 376 0. 391 0. 986, 1. 376

5309. 681 100 15 161631- 34991

1

2 0. 663 1.180 0.517 0 1. 843

5307. 812 60 8 234483-422834 2 0. 142 1. 256 1.398 0 1. 824

5304. 178 40 4 224505-412982 3 0. 185 0. 968 0. 783 0. 375 0. 783, 0. 965

5294. 870 300 30 45674 -234481 7 0. 092 (1.240) 1. 332 0 1.293

5292. 783 30 3 228803 -417681 1 0. 124 0.802 (0. 926) 0 0. 555

5290. 812 20 2 18143!-370382 1 0. 303 1.372 1.069 0 0. 766

5286. 098 70 7 234483- 4236O3 3 0. 050 1. 195 1.145 0. 149 1. 170

5275. 04 150 20 161631-351152 3 0. 058 1. 169 1. Ill 0. 117 1. 140

5258. 736 40 5 26463!-45474i 3 0. 414 1.006 1.420 0. 414 1. 006, 1. 420

5255. 464 15 285833—476064 7 0. 03 (0. 940) 0. 97 0 1. Olh

5254. 48 20 3 236441-426704 2 0. 16 (1. 074) 1.23 Ow 1. 69—

5247. 031 40 3 247851-438384 7 0. 06 (1. 330) 1.27 0 1. 30

5244. 67 50 4 6572 1-256345 7 0. 057 (1.496) 1.439 0 1.381

5243. 984 250 30 89832-28047! 1 0. 640 1.278 1.918 0 0. 638

5222. 43 10 1 232524-423953 7 0.034 1.028 (1.062) 0 0. 924

5200. 866 20 2 234483-426704 1 0. 028 (1.204) 1.232 0 1.315

5199. 545 10 1 167664- 35993! 1 0. 222 (1.341) 1. 119 0 0. 230

5186. 825 50 10 2290l!-421754 7 0. 015 (1.275) 1.260 0 1. 236

5184. 295 20 2 89832-282671 3 0. 15 1.34 1. 19 0. 30 1.26

5181. 87 300 60 O2- 192923 2 0. 251 0. 719 0. 970 0 1.472

5173. 162 15 2 180111-37336i 7 0. 070 (0. 394) 0. 464? 0 0. 324

26
Appendix A. Zeeman Data, Hf i—Continued

1 2 3 4 5 6 7 8 9 10

Wavelength

A

Air

IntensityClassification Zee- man

Type

Istg 2ndg

Zeeman Components

Tube Spark Strong p Strong n

5170. 173 100 20 197912-391273 1 0. 088 (1.414) 1.326 1. 150

5167. 376 30 4 247853-441325 2 0. 06 1.34 (1.400) Qw 1. 62

5166. 390 20 2 299963-493473 3 0. 053 1.251 1.304 0. 158 1.278

5157. 95 200 20 229011—422834 1 0. 06 1. 29 (1. 353) Ow 1.02

§5153. 122 40 4 1790l5-37301g 1 0. 205 1.320 1. 115 0 0. 090

5136. 20 30 2 105324-29996§ 1 0.232 (1.007) 1. 239 0 0. 310

5112. 130 100 10 56382-25194; 1 0. 280 1. 165 1.445 0 0. 885

5101. 668 40 4 275161-471123 1 0. 002 (1.474) 1.476 0 1. 468

5100. 64 60 4 89832—285833 1 0. 345 1. 272 0. 927 0 0. 237

5090. 876 15 2 105081-301462 3 0. 55 0. 82 1.38 1. 09 0. 82, 1. 38

5069. 810 20 1 264631-461832 1 0. 054 (0. 996) 0. 942 0 0. 887

5051. 319 50 3 O2-I979I2 3 0. 712 0. 706 1.418 1. 42 0. 706, 1. 418

5047. 440 300 30 89832-28790! 2 0. 335 1.309 0. 974 0 1. 644

5037. 74 9 236441-434893 7 0. 122? (1.074) 1. 196? 0 1. 135

5034. 92 30 3 147402-34596! 7 0. 003 (1.007) 1.004 0 1. 010

5025. 91 15 1 6572i-264635 3 0. 506 1.510 1. 004 0. 504 1. 004, 1. 510

5023. 09 70 5 14092 1-339941 2 0.923 0. 009 0. 932 0 1. 855

5021. 745 40 5 183811-382892 2 0. 198 1.288 1.090 0 1. 684

5021. 13 40 5 224501—423603 2 0. 13 (1.011) 1. 14 Ow 1. 39

5018. 20 200 20 209603-408823 1 0. 070 1. 160 (1. 230) 0. 102 0. 952

5000. 54 20 2 247851-447774 3 0. 080 (1.330) 1. 250 0. 322 ? 4975. 26 400 50 23563-224501 7 0. 056 (1.082) 1.026 0 1. 195

4962. 381 50 6 18143!-382892 1 0. 335 1.408 1.073 0 0. 738

4948. 951 100 15 105324-307331 3 0. 266 1.007 1.273 1.062 1. 007, 1. 273

4947. 336 15 2 147402-349471 3 0. 152 1.000 1. 152 0. 303 1. 076

4943. 42 15 2 7 0 1. 455

§4932. 260 7 224501-427192 2 0. 184? 0. 368 1. 264

4915. 32 40 6 I979II-4OI3O2 3 0. 205 1. 425 1.220 0. 410 1. 220, 1. 425

4910. 10 30 2 161631—365233 2 0. 097 (1. 172) 1. 269 0 1. 464

4903. 06 20 2 234481-438384 2 0. 088 (1. 204) 1. 292 Otv 1. 555

4896. 34 40 4 89832-294011 3 0. 460 1.296 1. 756 0. 962 1. 296, 1. 756

4889. 932 20 2 105324 -30977g 2 0. 19 (1. 007) 1. 20 Ow 1. 98

4878. 166 20 4 7 0 1.383

4877. 587 150 20 192925-397882 7 0.024 (0. 952) 0. 976 0 0. 905

4872. 949 50 5 209601-414753 1 0. 120 1. 146 1.266 0. 360m; 0. 786

4863. 282 150 20 144351- 34991

1

2 0. 400 0. 904 0. 504 0 1. 304

4859. 24 200 30 145415-351152 7 0.02 1.09 (1.110) 0 1. 06

4858. 42 70 7 6572 1-271491 1 0. 496 1.482 0. 986 0 0. 490

4837. 238 150 20 56382—263055 2 0. 228 1. 176 1. 404 0 1. 860

4834. 20 80 10 144351-351152 3 0.216 0. 903 1. 121 0. 427 0. 903, 1. 121

4818. 84 100 15 183811-391273 7 0. 000 1.299 1.299 0 1. 299

4811. 146 40 5 209603-417393 1 0. 201 (1. 157) 1. 358 0? 0. 565?

4800. 50 500 100 56382-26463! 2 0. 168 1. 167 0. 999 0 1.335

4795. 98 15 2 197911-406362 3 0. 346 1.413 1.068 0. 697 1. 068, 1. 413

4782. 737 200 50 182243-391273 1 0. 050 1.246 1.296 0. 15m; 1. 096

27
Appendix A. Zeeman Data, Hf I—Continued

1 2 3 4 5 6 7 8 9 10

Wavelength

A

Air

Intensity Zee- man

Type

Art ist g zna 9Tlrl rt g

Zeeman Components

Strong p Strong 71

4777. 216 20 2 234481—443752 1 0. 140 1. 176 1. 316 0. 280 0. 896

4774. 904 30 4 229011—438384 7 0. 018 1.277 (1. 295) 0 1. 205

4773. 72 150 20 5521o-26463l 7 1.000 0. 000 1. 000 0 1. 000

4769. 372 20 2 6572,-27533! 3 0. 233 (1.496) 1.263 0. 233 1. 233?, 1. 523?

4766. 507 100 10 14017!— 34991

1

7 0. 04 (0. 542) 0. 50 Ow 0. 52

4757. 611 50 5 89832-299961 7 0. 060 (1. 300) 1. 240 0 1. 120

4739. 83 40 4 23563—234485 3 0. 091 1. 091 1. 182 0. 272 1. 136?

4738. 574 80 10 14017!— 351152 2 0. 564 0. 532 1. 096 0 1.660

4721. 71 50 5 16163°2— 37336i 2 0. 695 1. 184 0. 489 0 1. 879

4717. 43 30 2 14092i — 35284! 3 1. 078 0. 000 1. 078 1. 095 1. 061

4708. 85 40 5 22901S— 441325 3 0. 140 1. 281 1. 421 0. 699 1. 351

4708. 053 30 4 7 0 1. 182

4699. 008 150 30 1801ls-39286i 2 0. 174 (0. 394) 0. 220 0 0. 568

4673. 176 20 2 0 Unaffected Uunaffected

4670. 94 20 2 18143!— 39546i 3 0. 624 1. 428 0. 819 0. 640 0. 819, 1. 428

4669. 245 50 7 105324—319431 3 0. 401 0. 997 1. 398 1. 600 0. 997, 1. 398

4655. 198 300 50 6572i— 28047! 3 0. 443 1. 490 1. 933 0. 440 1. 490, 1. 933

4650. 59 20 2 147402—362375 7 0. 02 (1. 007) 1. 03 0 1. 08

4648. 35 10 197915—412982 3 0. 569 1. 407 0. 838 1.140 0. 838, 1. 407

4642. 25 30 4 18011°2-39546i 1 0. 396 0. 396 0. 792 0 0

4630. 608 40 192925—408823 3 0. 282 0. 946 1. 227 0. 858 0. 946, 1. 227

4620. 862 300 30 45674 —262021 2 0. 124 1. 239 1. 363 0 1. 859

4619. 52 20 2 167664-384071 7 0. 04 (1.352) 1.31 0 1. 48

4608. 093 100 10 6572i -282671 1 0. 351 1. 478 1. 127 0 0. 776

4598. 801 300 30 02—21738! 2 0. 649 0. 699 0. 050 0 1.348

4597. 945 60 6 236441—453874 7 0. 053 (1. 074) 1. 021 0 0. 861

4565. 95 300 50 56382—27533! 1 0. 100 1. 166 1. 266 0 1. 066

4562. 638 15 1 7 0 1. 520

4559. 76 20 2 224501-443752 3 0. 338 1.013 1.347 0. 701 1. 013, 1. 347

4553. 776 80 8 6572i— 285265 7 1. 495 1. 495 0. 000 0 1.495

4550. 16 40 V 249665- 46937i 7 1.285? 0 1. 285? 0 1. 285?

4547. 87 30 2 145411—365233 3 0. 195 (1. 085) 1. 280 0. 584

4546. 90 10 1 18143!-401302 7 0.214 (1. 428) 1.214 0 1. 00

4544. 02 100 10 105324-325331 7 0. 029 (1. 007) 0. 978 0 1. 094

4540. 934 200 20 56382-276541 7 0. 013 (1. 164) 1. 151 0 1. 126

4520. 587 30 4 25194!— 47309i 7 0. 082 (1. 447) 1. 529 0 1. 488

4518. 305 50 5 161631-382892 3 0. 085 1. 176 1. 091 0. 171 1. 134

4503. 095 15 234485-456493 7 0. 030 (1. 204) 1. 174 0

1 1 QO

4499. 662 50 5 6572i— 28790! 3 0. 540 1. 511 0. 971 0. 540 0. 971,1.511

4492. 16 30 2 183815—406362 2 0. 186 1. 349? 1. 163? 0 1. 721

4473. 042 20 3 236445-459943 7 0. 418? (1.074) 0. 656? 0 0. 865

4461. 181 200 30 56382—28047! 1 0. 777 1. 159 1. 936 0 0. 382

4457. 347 300 40 23563—247851 2 0. 244 1. 083 1. 327 0 2.059

4452. 98 80 8 02—224501 3 0. 312 0. 663 0. 972 0. 632 0. 663, 0. 972

4448. 086 15 18143:-40618i 7 0. 114? (1.428) 1. 542? 0 1.485

28
Appendix A. Zeeman Data, Hf I—Continued

1 2 3 4 5 6 7 8 9 10

Wavelength

A

Air

Intensity

Classification Zee- man

Type

Istg 2ndg

Zeeman Components

Tube Sp3.rk Stron^y T> Strong n

4438. 038 200 30 5521o- 28047! 7 1.92 0 1.92 0 1.92

4418. 247 70 9 89832-316101 3 0. 306 1.316 1.010 0. 611 1. 010, 1. 316

4417. 91 150 20 56382-282675 7 0. 14 (1. 164) 1. 02 0 1. 09

4416. 19 40 3 23644§-462824 2 0. 146 (1.074) 1.220 0 1.658

§4379. 064 40 3 183811-412112 1 0. 163 1.277 1.440 0 0. 951

4365. 377 60 6 14435§-37336i 2 0.416 0. 920 0. 504 0 1.336

4357. 000 60 7 56382-285831 1 0.214 1. 135 0.921 0 0. 493

4356. 306 300 40 45674 —275161 3 0. 235 1. 238 1 A no

1. 473 0. 940 1. 238, 1. 473

4353. 36 30 5 161631-39127., 7 0. 133 (1. 172) 1.305 Ow 1. 572

4352. 567 60 7 88932-31952! 1 0. 779 1.302 2.081 0 0. 523

4330. 282 150 20 45674-276541 2 0. 086 1.228 1. 142 0 1.486

4318. 138 100 10 56382-28790! 2 0. 194 1. 166 0. 972 0 1.360

4296. 45 50 5 5521o-28790! 7 0.961 0. 000 0. 961 0

A A^ 1 0. 961

4294. 78 300 30 23563-256341 1 0. 337 1.080 1.417 0 0. 406

4263. 45 150 15 02-234481 2 0. 498 0.698 1. 196 0 2. 192

4260. 98 80 8 105324-339941 3 0.018 1.035 1.017 0. 071 1.026

4245. 168 40 4 89832-325331 1 0. 354 1.304 0. 950 0 0. 242

4zzo. 074 100 10 O2 —236443 2 0. 377 0. 697 1 nn A 1. 074 0 1.828

4209. 743 100 10 145411-382892 7 0. 001 (1.085) 1.086 0 1.082

4201. 55 80 10 183811-421754 7 0. 002 (1.287) 1.289 Oh 1.296

4190. 95 50 5 144351-382892 3 0. 178 0. 903 1.081 0. 356 0. 903, 1. 081

4174. 348 1500 150 23563-263051 3 0. 316 1.081 1.397 0. 948 1. 081, 1. 397

4145. 759 150 15 56382-297521 3 0. 334 1. 169 1.503 0. 669 1. 169, 1. 503

4118. 583 100 8 105324-348051 7 0. 006 (1. 007) 1. 001 0 1.004

4115. 88 50 4 183811-426704 1 0. 038 (1.287) 1.249 0 1. 135

4106. 553 200 15 105324-348771 2 0. 045 (1.007) 0. 962 0. 115 1.142

4104. 234 150 8 56382-299961 2 0. 044? 1. 180 1. 224 0. 087 1.312

408 /. 942 50 5 161631- 406-1O1 1 0. 327 1. 169 1. 496 0 0. 841

4083. 36 300 30 105081- 34991

1

2 0. 303 0. 811 0. 508 0 1. 115

4067. 830 100 10 18143!-427192 1 0. 239 1.424 1. 185 0 0. 945

4066. 21 200 30 145411-391273 3 0. 226 1.085 1. 311 0. 680 1. 085, 1. 311

4062. 84 400 60 105081-351152 3 0. 308 0. 805 1. 113 0. 614 0. 805, 1. 113

4057. 439 80 6 18143! -42782

1

3 0. 108 1.422 1.530 0. 108 1. 476

4044. 370 80 8 161631-408823 2 0. 061? 1. 177 1.238 0. 122 1. 360

4032. 266 300 15 23563-271491 2 0. 086 1. 086 1.000 0 1. 254

4011. 503 100 4 105324-354531 7 0. 003 (1.007) 1.004 0 1. 017

3973. 477 600 20 23563-275161 2 0. 391 1.086 1.477 0 2. 650

oVoi. oZZ 1000 100 23563 —276541 3

A A^O

0. 072 1. 084 i. 156 0.217 1. 120

3939. 042 100 5 6572i-31952! 3 0.579 1. 500 2.079 0. 581 1. 500, 2. 079

3931. 38 700 70 45674-299961 7 0. 009 (1.240) 1.231 0 1.266

3927. 585 100 15 147402-401941 3 0. 487 0. 998 0.511 0. 970 0. 511, 0. 998

3926. 434 100 8 105324-359931 2 0. 123 1.017 1. 140 0 1. 632

3906. 888 80 5 145411-401302 1 0. 116 1.078 1. 194 0 0. 846

3902. 937 90 8 7 wh 1.089

3899. 937 1000 80 02-256341 3 0. 720 0. 697 1. 417 1.440 0. 697, 1. 417

29
Appendix A. Zeeman Data, Hf i—Continued

1 2 3 4 5 6 7 8 9 10

Wavelength

A

Air

Intensity

Classification Zee- man

Type

Istg 2ndg

Zeeman Components

Tube Spark StrATiff n kj irong n

3889. 362 200 30 00002 —OiO'^'Zs 2 0.218 1.166 1.384 0 1.819

3889. 228 150 20 —OOZO *

3

1 0. 029 (1.007) 1.036 0. 067 0.920

OQQO CO'7 100 10 loo 103 U. Ol4 ^1. z4o; A AO A 0. 934 0. 941 9 3860. 910 200 20 0VOO2 Q/1 Q77« 1 0. 343 1.299 0. 956 0 0. 270

3858. 31 800 80 ZOOO3 1 0. 064 1.082 1. 146 0. 127 0. 955

3849. 19 1000 70 56382 -316105 3 0.170 1. 166 0. 996 0. 340 0. 996, 1. 166

3833. 667 60 5 —OOOUy3 1 0. 245 1.008 1.253 0 0.273

3830. 018 200 50 —/ini QA 0 ^Uiy'*2 2 0.493 0. 018 0.511 0 1.003

3829. 686 100 20 110f\lf\f\ * U04 —^ZO 1 I4 3 0. 195 1.336 1.141 0. 783 1. 141, 1. 336

3820. 728 1000 100 ^DO ( 4 —OU /OO4 3 0. 036 1.237 1.273 0. 135 1.255

3811. 781 400 40 ^0003 ZOOOO3 3 0. 137 1.081 0. 944 0.405 0. 944, 1. 081

3800. 452 300 50 00002 3 0. 435? (1. 164) 1. 599? 0. 870?

aoUU. oo 1000 100 U2 Z00UO3 z u. <uz 1 OAA I. o99 0 2. 804

3787. 375 50 4 X00013 /1/1777 1 0. 034 (1.287) 1.253 Om; 1.152

3785. 46 3000 250 ^DO / 4 —oVy / /

5

1 0. 027 1.235 1.208 0. 108 1. 100

3777. 658 2000 200 O2 -26463! 1 0. 300 0. 691 0. 991 0 0. 391

3768. 254 200 10 11/OU02 —0 i 0002 3 0. 280 0. 812 1.092 0. 564 0. 812, 1. 092

3765. 558 100 10 00 i z 1 _Q31 — 91 0 OOIZI2 1 0.150 1.498 1.348 0 1.190

3765. 046 100 9 lOZZ4:'4 — yl/1777 i i I 4 7 0. 004 (1.246) 1.242 0 1. 244

3764. 528 90 8 101002 — 4.971 "iZ / 01^2 7 0. 004 (1.172) 1. 176 0 1.174

3753. 225 100 20 1 7001 — d.J.^57° ^4?00 15 3 0. 129 1.384 1.256 0. 647 1. 256, 1. 384

3746. 810 400 60 l"* i '*U2 —'±1'*ZZ3 1 0. 072 1.006 0. 934 0. 144 0. 790

Q7QO AQn o toy. UoU 150 10 II/OOZ4 —0579AQ° 1 zoy4 0 u. loo 1. uu / 1. loo A £C\ A 0. 624 1. 007, 1. 163

3733. 786 1000 100 lOO / 4 —010^Z3 1 0. 147 1.244 1.391 0 0. 805

3729. 093 150 15 zuyou4 9nQ^^n« — A4? 77AP i / 0C>5 7 0.015 (1.157) 1. 142 0 1.084

3726. 485 150 15 105085--37336i 2 0. 330 0. 804 0. 474 0 1. 134

3717. 802 1000 100 ZOOO3 7 0.011 (1.082) 1.071 0 1.037

3707. 374 70 7 Do — OOOOO2 1 0. 672 1.487 0. 815 0 0. 143

3696. 524 400 40 ZOOO3 1 0. 668 1.078 1.746 0 -0. 258

3682. 247 3000 200 A

"2 971 /IO0 3 0. 301 0. 691 0. 992 0. 602 0. 691, 0. 992

3675. 742 400 150 loo /O3 — 4Zo / 14 1 0. 103 1.249 1. 146 0.310 0. 837

3672. 304 300 30 1 /yuis — loizie 7 0. 057 (1.383) 1.326 0 1.039

oOO(>. ly 100 10 0^00 2 — oOZo 13 1 U. ZOl 1 3AQ 1. dUo 1 f\A 9 1. U4Z A A C9A U. OZU

3651. 838 400 40 400 < 4 — Ql f\4 Do 0 1V404 3 0. 164 1.242 1.406 0. 656 1. 242, 1. 406

3649. 106 700 60 Z0OO3 — zy /0Z2 1 0.416 1.075 1.491 0. 0. 243

3637. 594 90 7 56382 -331212 3 0. 170 1. 162 1.332 0. 340 1.162,1,332

3635. 425 150 10 56382 -33137! 2 0. 385 1. 158 0. 773 0 1.543

3630. 872 700 100 O2 -27533! 1 0. 569 0.692 1.261 0 0. 123

3627. 850 70 10 240855 -51641g 1 0. 068 (1. 142) 1.084 Ow 0. 791

3620. 041 100 10 552I0 -33137! 7 0. 778 0. 000 0. 778 0 0. 778

3616. 892 2000 200 23563 -299961 3 0. 142 1.082 1.224 0. 423 1. 082, 1. 224

3615. 034 300 30 O2 -276543 2 0. 458 0. 696 1.154 0 2. 070

3599. 867 200 60 167664 -445375 1 0. 078 1.308 1.230 0.310 0. 920

3597. 501 60 10 89832 -36772? 3 0. 142 1.298 1. 156 0. 284 1. 156, 1. 298

3583, 267 100 10 56382 -335385 3 0. 342 1. 163 0. 821 0. 684 0. 821, 1, 163

30
Appendix A. Zeeman Data, Hf I—Continued

1 2 3 4 5 6 7 8 9 10

Wavelength

0A

Air

Intensity

Classification Zee- man

Type

Istg 2nd g

Zeeniari Components

Tube Spark strong p Strong re

3567. 360 600 50 6572 1-34596! 3 0. 528 1.501 0. 973 0. 528 0 973 1 501

3564. 307 200 30 02-28047! 7 1.250 (0. 696) 1.946 0 -0. 554

3536. 630 400 50 02-282671 3 0. 448 0. 695 1. 143 0. 896 0. 695, 1. 143

3531. 224 200 15 56382-33949! 1 0. 074 (1. 164) 1. 090 0. 134 0. 941

3523. 025 1000 100 23563-307331 2 0. 191 1.083 1.274 0 1. 847

3513. 271 300 30 105324-389871 3 0. 141 1.008 1. 149 0. 560 1. 008, 1. 149

3498. 988 100 10 45674-33139! 1 0. 201 1.247 1. 448 0 0. 644

3497. 498 1500 150 02—28583! 2 0. 251 0. 697 0. 948 0 1. 448

3472. 410 800 100 02-28790! 1 0. 268 0. 690 0. 958 0 0. 422

3467. 569 150 15 156733-445031 2 0. 229 1.250 1.021 0 1. 709

3452. 304 70 10 56382-34596! 2 0. 193 1. 164 0. 971 0 1. 357

3448. 284 100 8 7 0 1.491

3441. 835 150 8 147402-43786! 2 0. 834 1.003 0. 169 0 1.837

3438. 428 300 30 5521 0-34596! 2 0. 969 0. 000 0. 969 0 0. 969

3427. 430 150 20 89832-38151! 1 0. 134 1. 304 1. 438 0. 134 1. 170

3419. 171 500 90 56382-34877! 1 0. 205 1. 156 0. 951 0 0. 540

3417. 34 300 30 23563-316101 2 0. 077 1.088 1. Oil 0. 154 1. 242

3412. 374 100 10 14541!— 438384 2 0. 208 1. 118 1. 326 0 1. 950

3407. 140 50 10 89832-383251 3 0. 150 1.302 1. 152 0. 301 1 152 1 302

3402. 512 200 20 45674 -33949! 2 0. 150 1. 239 1.089 0 1. 689

3397. 602 100 20 89832-38407! 7 0. 013 (1.300) 1.287 0 1. 262

3397. 257 200 20 45674 - 339955 3 0. 206 1.238 1. 032 0. 827 1. 032, 1. 238

3392. 815 150 40 I79OI5-473665 3 0. 065 1. 362 1.297 0. 326 1.329

3386. 214 150 20 167664-462891 3 0. 060 1.33 1. 27 0. 239 1. 24?

3372. 201 60 5 56382-35284! 2 0. 112 1. 173 1. 061 0 1. 285

3366. 681 100 20 14092 1-43786! 3 0. 142 0. 030 0. 172 0. 142 0 000 0 172

3360. 060 200 30 O2-297521 3 0. 806 0. 690 1. 496 1. 612 0 690 1 496

3358. 965 100 20 552I0— 35284! 7 1. 055 0. 000 1. 055 0 1.055

3332. 737 600 100 O2-29996! 2 0. 524 0. 697 1.221 0 2.270

3312. 869 600 100 23563 -32533! 3 0. 133 1.080 0. 947 0. 399 0 947 1 080

3310. 274 300 70 6572 1-367721 1 0. 339 1.491 1. 152 0 0. 813

3309. 193 100 10 89832-39193! 7 0. 004 (1.300) 1.296 0 1. 288

3306. 110 300 30 45674 —348051 3 0. 237 1. 232 0. 995 0. 949 0. 995, 1. 232

3293. 116 60 4 14017!-443752 2? 0. 805 0. 537 1. 342 0 2. 147

3291. 043 150 100 6572 1-36949! 3 0. 955 1.498 0. 543 0. 955 0 543 1 498

3287. 286 70 10 14092 1-445031 2 0. 992 0. 009 1.001 0 1. 993

3282. 977 100 40 89832-394251 ?0. 04 (1.300) 1.34 0 1. 32

3267. 165 80 10 56382-36237! 1 0. 123 1. 173 1. 050 0 0. 804

3267. 000 70 10 167664-47366! 1 0. 019 (1.341) 1.322 Om; 1.245

3265. 281 80 10 156733-462891 2 0.020 (1. 248) 1.268 Om; 1.330

3262. 469 100 15 105324-411753 3 0.215 0. 988 1.203 0. 860 0. 988, 1. 203

3249. 529 200 20 23563-331211 1 0. 263 1.086 1.349 0 0. 559

3247. 67 400 80 23563-33139! 3 0. 356 1.082 1. 438 1.067 1. 082, 1. 438

3243. 343 100 10 I67664- 47590! 7 0. 005 (1.341) 1.346 0 1.326

3239. 393 80 8 7 0 1.428

31
Appendix A. Zeeman Data, Hf i—Continued

1 2 3 4 5 6 7 8 9 10

Wavelength

A

Air

Intensity

Classification Zee- man

Type

Ag Istg 2ndg

Zeeman Components

Tube Spark Strong p Strong n

3236. 76 100 10 45674- 354531 2 0. 238 1. 240 1. 002 i. yoo

3230. 058 10 7 nV 1 09/1 3218. 770 70 5 147402-47599; 1 0. 419 (1.007) 1.426 0 U. 000

3213. 708 70 5 145411—456493 3 0. 094 1. 093 1. 187 1 1 An 3210 965 100 10 56382- 36772S 7 0. 010 (1. 164) 1. 154 1 TKQ

3206. 108 150 30 23563-335381 2 0. 263 1. 079 0. 816 1. OUO

3196. 916 60 10 6572 1 -378435 7 1.496 1. 496 0 0 1.496

3189. 632 100 20 02-313421 2 0. 688 0. 692 1. 380 0 2.756

3181. 148 70 10 45674-359931 1 0. 108 (1.240) 1. 132 0 7A1 3181. 008 RO 10 5521o- 369491 7 0. 530 0. 000 0. 530 0

3178. 436 40 5 145411-459943 9 0. 480? (1. 085) 0. 605? 0 flAK"? U. O'rO. §3174. 882 o\j ^0 179015-493891 3 0. 334 1.383 ? 1 1 ^4 A i. lyo, i. 041

3172. 949 300 70 45674— 36075S 3 0. 177 1.237 1. 060 0 700 1. uou, 1. I §3168. 390 100 40 10508S-420613? 7 0. 027 (0. 805) 0. 832? 0 0 RRA

3165. 730 10 6572i-38151; 7 0. 070 (1. 496) 1.426 0 1 AAl 1. ^\jL

3164. 385 100 20 23563—339491 7 0. 000 1. 082 1. 082 0 1 Oft9 §3162. 575 300 30 02-31610? 3 0. 304 (0. 696) 1. 000 0. 608 9

3161. 536 20 3 144351—460562 3 0. 200 0. 896 0. 696? 0. 410 0. 698, 0. 892

§3159. 84 300 40 23563 - 339941 2 0. 150 1. 078 0. 928 11. 0^7ft1 0 3156. 688 200 100 45674- 362371 2 0. 198 1. 250 1. 052 0 1. 0^0

3151. 640 80 20 89832-40704; 2 0. 153 1. 302 1. 149 0

3148. 415 100 40 6572i-38325l 1 0. 346 1. 500 1. 154 0 0u. ftOft owo

3137. 520 70 30 105324-423951 1 0. 043 (1. 007) 1.050 V. ±00lA/ 0 ft7Q

3131. 812 400 200 105324-42453S 7 0. 000 1. 034 1. 034 0

3119. 980 100 40 45674- 366091 7 0. 008 (1.240) 1.248 0 1 91 ^

3096. 764 150 40 45674 -368503 3 0. 169 1.216 1.047 0 677 v. UU J X. t 3080. 842 200 50 23563-348053 1 0. 090 (1.082) 0. 992 0. 196 0. 720

§3074. 789 100 40 56382-38151; 1? 0.277 1. 159 1. 436? 0 1.436

3074. 104 60 20 23563 -348771 3 0. 125 1.070 0. 945 0 374. 0 78=; 1 990

3072. 881 400 100 02-325331 2 0.263 0. 687 0. 950 0 1 4.77 3069. 213 80 15 105324—431041 1 0. 065 0. 990 1. 055 0. 194m; 0 706

3067. 426 200 40 23563-349471 1 0. 088 1.095 1. 183

3063. 778 80 10 5521o-3815l; 7 1.436 0. 000 1.436 0 1 4^6

3057. 010 400 100 45674 —372691 3 0. 077 1.242 1. 165 0w. o\jy HOQ 1 904. 3050. 760 300 80 56382—384071 2 0. 130 1. 155 1. 285 0 261 1 =^46

3049. 300 60 15 89832—417681 3 0. 374 1. 300 0. 926 0. 748 0 026 1 300

3042. 085 30 4 6572 1—394351 1 0. 155 1. 518 1.363 0. 155 1. 208

3020. 530 300 100 23563—354531 3 0. 083 1. 084 1.001 0. 247 0. 842-1.243

3018. 30 250 70 O2— 331211 3 0. 647 0. 688 1. 335 1.299 0. 688, 1. 335

3016. 80 200 50 O2—33137; 1 0. 066 (0. 696) 0. 762 Ow 0. 630

3016. 69 150 40 02—331391 2 0. 742 0. 698 1.440 0 2. 924

3005. 556 300 100 105324—437945 3 0.025 1. 013 1.038 0. 100 1.026

2984. 058 50 10 89832-42485! 2 0. 442 1.296 0. 854 0 1.738

2982. 727 150 40 105324-440491 7 0. 017 (1.007) 1.024 0 0. 955

2980. 815 500 100 02-335381 3 0. 133 0. 697 0.830 0. 266 0. 536-0. 990

32
Appendix A. Zeeman Data, Hf I-—Continued

1 2 3 4 5 6 7 8 9 10

Wavelength

A

Air

Intensity

Classification Zee- man

Type

Istg 2ndg

Zeeman Components

Tube Spark Strong p Strong n

2979. 288 100 30 56382-39193? 2 0. 125 1. 153 1.278 0 1. 527

2973. 390 100 30 6572 1-401942 1 0. 992 1.503 0. 511 0 —0. 481

2966. 953 150 30 6572i-40267| 1 0.418 1.500 1. 082 0 0. 664

2964. 885 400 80 23563-360751 7 0.012 (1.082) 1.070 0 1. 035

2958. 01 300 40 56382-394351 3 0. 200 1. 157 1.357 0. 400 1, 157, 1. 357

2954. 201 500 100 45674 -384071 1 0. 048 1.264 1.312 0. 144 1. 120

2950. 67 600 100 23563-36237J 3 0. 035 1.080 1.045 0. 104 1.062

2944. 71 200 40 02-339491 2 0. 390 0. 698 1. 088 0 1.867

2940. 762 800 100 O2- 339945 3 0. 243 0. 696 0. 939 0. 486 0. 696, 0. 939

2935. 365 40 2 145415-485983 7 0. 580? (1.085) 0. 505? 0 0. 795

2929. 895 200 50 89832-431041 1 0.214 1.296 1.082 0 0. 654

2924. 613 1 50 20 5521o-39704! 7 0.612 0. 000 0. 612 0 0. 612

2918. 591 300 40 23563-366091 3 0. 175 1.087 1. 262 0. 525 1. 087, 1. 262

2916. 48 800 100 45674-388451 1 0. 062 1. 270 1.208 0. 248 0. 960

2904. 760 300 60 23563-367721 1 0. 071 1.078 1. 149 0. 142 0. 936

2904. 412 400 70 45674-389875 3 0. 095 1. 232 1. 137 0. 368 1. 137, 1. 232

2898. 256 500 50 23563-368501 7 0. 006 (1.082) 1.076 0 1.060

2896. 260 10 16163s- 5O68O3 7 0. 062? (1. 172) 1. 110? Oiv 1.094

2892. 565 60 7 6572i-411335 7 1.493 1.493 0. 000 0 1. 493

2889. 62 300 50 O2— 34596! 1 0. 276 0.694 0. 970 0 0. 418

§2887. 542 100 30 6572i-41193f 3? 0. 171 1.490 1.319 0. 171 1. 404

2887. 132 200 60 45674 -391931 1 0.040 1.228 1.268 0. 122 1. 106

2877. 18 80 7 105082-452542 3 0. 106 0. 932? 1. 038? 0.213 0. 984

2867. 70 60 7 89832 -43844! 7 0. 055 (1.300) 1.355 0 1. 245

2866. 373 500 100 02-34877§ 2 0. 263 0. 697 0. 960 0 1. 487

2863. 41 60 4 23563-372691 2 0. 066 1. 103 1. 169 0. 198 1.367

2860. 558 100 15 O2-349471 3 0. 454 0. 705 1. 159 9 0. 705, 1. 159

2850. 967 100 20 56382 -40704! 7 0.011 (1. 164) 1. 153 0 1. 175

2845. 832 200- 20 56382-40767? 2 0. 045 1. 160 1.205 0. 091 1.296

2841. 493 70 7 552I0— 40704! 7 1. 158 0. 000 1. 158 0 1. 158

2834. 130 60 10 89832-44257! 2 0. 084 (1.300) 1.216 0 1.384

2833. 285 150 20 02—35284! 1 0. 353 0.698 1.051 0 0. 345

2819. 746 100 15 O2— 35453§ 2 0. 303 (0. 696) 0. 999 0. 605

2818. 942 60 5 6572,— 42036! 3 0. 270 (1. 496) 1.226 0. 266 1. 124, 1. 398

2817. 685 100 10 89832—444631 2 0. 000 (1.300) 1. 300? Ow 1. 299

2783. 698 60 10 6572 1 —42485! 3 0. 636 1.500 0. 864 0. 634 0. 864, 1. 500

2779. 370 150 30 23563-383251 1 0. 076 (1.082) 1. 158 Ow 0. 930

2766. 966 80 10 56382-417681 3 0. 237 1. 163 0. 926 0. 472 0. 926, 1. 163

2762. 688 60 10 56382—418241 1 0. 033 (1. 164) 1. 131 Ow 1.064

2761. 634 200 20 45674—407671 7 0. 014 (1. 240) 1. 226 0 1. 282

2758. 771 80 10 02—362371 2 0. 344 0. 700 1. 044 0 1. 732

2743. 637 100 20 56382-420751 3 0. 068 (1. 164) 1.232 d 1. 198

2737. 816 50 3 5521o-42036! 7 1.232 0. 000 1.232 0 1.232

2730. 700 50 5 02-366091 2 0. 554 0. 702 1.256 0 2.364

2729. 098 40 5 23563-389871 2 0. 058 (1. 082) 1. 140 On; 1.312

33
Appendix A. Zeeman Data, Hf i—Continued

1 2 3 4 5 6 7 8 9 10

Wavelength

A

Air

Intensity

Classification Zee- man

Type

Isrg 2ndg

Zeeman Components

Tube Spark Strong p Strong n

2726. 70 60 7 56382-423025 3 0. 294 1. 155 0. 861 0. 588 0 861 1 155

2718. 593 50 10 02-36772! 3 0. 460 0.695 1. 155 0. 957 0 6Q5 1 155

2713. 837 50 5 23563-391931 3 0. 206 1. 076 1.282 0. 618

2705. 612 100 20 02-36949! 2 0. 185 (0. 696) 0. 511 0

2699. 632 70 10 7 0 X» '±7^

2696. 180 80 10 23563-39435! 1 0.268 1. 076 1. 344 0

2668. 290 90 6 56382-431041 1 0. 070 (1. 164) 1.094 Ou) 0. 954

§2652. 781 50 1 6572i-44257! 7 0 1. 006?

2642. 751 80 6 45674-42395? 2 0. 165 (1.240) 1.075 Ow 1. 736

2642. 076 60 2 23563-401945 2 0. 573 1.084 0. 511 0 2. 230?

2636. 997 50 5 23563-40267! 7 0. 000 (1.082) 1.082 0 1.083

2616. 606 80 8 56382-438445 1 0. 207 1. 163 1. 370 0 0. 956

2612. 585 40 1 5521o-43786! 7 0. 170 0. 000 0.170 0 0. 170

2608. 450 60 5 02-38325! 3 0. 457 0. 694 1. 151 0. 915 0. 694, 1. 151

§2574. 896 50 2 56382-444635 ? 0. 120? (1. 164) 1. 284? 0. 120 1.205

2517. 858 30 02-39704! 7 0. 052 (0. 696) 0. 644 0 0. 748

§ Notes on discordant Zeeman patterns:

X Remarks

5886.31 Classification appears correct. for observed levels = 0.467. Observed pattern gives Ag=0A62 by assuming J=3.

5614.004 Pattern recorded for Hf n appears to belong to Hf i. 5497.301 Resolved pattern Ti, A^=0.18, J=2 g=1.21; 7=1 g=1.39. This does not fit present classification. 5371.80 Line classified as Hf ii. Observed pattern appears to fit Hf i. Ti? A7=0.55, /=3 g=1.10; J=2 g = 1.65. 5153.122 Well-resolved pattern; not used in deriving mean g-values. Discordance unexplained, 4932.260 Observed pattern does not fit classification. If Ts is assumed, A7=0.184 as compared with Af7=0.171 from other observations. 4379.064 Observed pattern recorded by W.F.M. for X4379.175 appears to belong with X4379.064. 3174.882 Well-resolved pattern does not fit classification except for type. 3168.390 Classification seems reasonable. Further confirmation needed for g-value of higher level. 3162.575 Blend with Hf 11. 3159.84 Observed pattern fits classification 23563 —339942, o-c=—17cm~'; Classification 23563—339943 gives o-c=—2 cm"'. 3074.789 Resolved pattern recorded as T2. Ti has been assumed, giving g= 1.436 for higher level. 2887.542 Resolved pattern recorded as T2. Ts has been assumed.

2652.781 Classification appears correct. Discordance in observed pattern not explained. 2574,896 Published type is T3. Observed p-component assumed to be Aff; n-component unexplained.

34
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CSI CN) (N Cn) CNI CN| CN] a V. S. GOVERNMENT PRINTING OFFICE : 1976—210-801/353

114
NBS-114A (REV. 7-73)

U.S. DEPT. OF COMM. I. PUBLICATION OR REPORT NO. 2. Gov't Accession

BIBLIOGRAPHIC DATA No. SHEET NBS MN-153

3. Recipient's Ac ce s sion No

4. TITLE AND SUBTITLE

The First Spectrum of Hafnium ( Hf I )

5. Publication Date July 1976

6. Performing Organization Code

7. AUTHOR(S)

William F. Meggers and Charlotte E« Moore

8. Performing Organ. Report No.

9. PERFORMING ORGANIZATION NAME AND ADDRESS

NATIONAL BUREAU OF STANDARDS

DEPARTMENT OF COMMERCE

WASHINGTON, D.C. 20234

10. Project/Task/Work Unit No.

11. Contract/Grant No.

12. Sponsoring Organization Name and Complete Address (Street, City, State, ZIP)

Same as 9.

13. Type of Report & Period

Covered

Final

14. Sponsoring Agency Code

15. SUPPLEMENTARY NOTES

Library of Congress Catalog Card Number: 76-872

16. ABSTRACT (A 200-wof(i or less factual stiminary of most significant infoTmatit^. If docutnent includes a significant

bibliography or literature survey, mention it here.)

The present publication terminates the work on the analysis of Hf I which was

started by the late W. F. Meggers in 1928 and left unfinished in 1966. His final

line list contains some 4700 lines of which about 67 percent have been classified.

V-'uocxvcu g""veti.u.co dx^c i\.xnjwiji lOi X70 icvcis. xne reiiaDii-ii.y 01 ine Zjeemian ODser — vations is indicated in tables containing sums of Observed and Lande' g- values for

selected groups of "even" and "odd" terms.

An attempt has been made to continue Meggers' analysis in LS-coupling as far

as possible. This coupling is not rigorous in Hf I, and many intervals are irregalar.

Consequently, the levels are given also in numerical order with the even and odd

levels presented in separate tables.

j An ionization limit of 54700 ± 600 cm~ , giving an ionization potential of 6. 78±0. 07

eV has been derived from a two-member series.

The long line lists are given in two Appendices: Appendix A contains the observed

Zeeman data for the individual lines, 531 in all; Appendix B consists of the complete

line list of observed and classified lines.

By far the greater part of the analysis is that Meggers. Detailed notes explain

changes that have been introduced and additions to this work.

17. KEY WORDS (six to twelve entries; alphabetical order; capitalize only the first letter of the first key word unless a proper name; separated by semicolons)

Analysis, Hf I spectrum; hafnium, cinalysis of first spectrum; spectrum, Hf I; Zeeman effect, Hf I.

18. AVAILABILITY fl? Unlimited

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Special Publications—Include proceedings of confer- ences sponsored by NBS, NBS annual reports, and other

special publications appropriate to this grouping such

as wall charts, pocket cards, and bibliographies.

Applied Mathematics Series—Mathematical tables,

manuals, and studies of special interest to physicists,

engineers, chemists, biologists, mathematicians, computer programmers, and others engaged in scientific and technical work.

National Standard Reference Data Series—Provides

quantitative data on the physical and chemical properties of materials, compiled from the world's literature

and critically evaluated. Developed under a world-wide

program coordinated by NBS. Program under authority

of National Stavidard Data Act (Public Law 90-396).

NOTE: At present the principal publication outlet for

these data is the Journal of Physical and Chemical

Reference Data (JPCRD) published quarterly for NBS

by the American Chemical Society (ACS) and the American Institute of Physics (AIP). Subscriptions, reprints,

and supplements available from ACS, 1155 Sixteenth

St. N. W., Wash. D. C. 20056.

Building Science Series—Disseminates technical information developed at the Bureau on building materials,

components, systems, and whole structures. The series presents research results, test methods, and performance criteria related to the structural and environmental functions and the durability and safety characteristics of building elements and systems.

Technical Notes—Studies or reports which are complete

in themselves but restrictive in their treatment of a

subject. Analogous to monographs but not so comprehensive in scope or definitive in treatment of the subject area. Often serve as a vehicle for final reports of work performed at NBS under the sponsorship of other'

government agencies.

Voluntary Product Standards—Developed under pro- cedures published by the Department of Commerce in Part 10, Title 15, of the Code of Federal Regulations.

The purpose of the standards is to establish nationally

recognized requirements for products, and to provide

all concerned interests with a basis for common understanding of the characteristics of the products. NBS

administers this program as a supplement to the activities of the private sector standardizing organizations.

Federal Information Processing Standards Publications

(FIPS PUBS)—Publications in this series collectively

constitute the Federal Information Processing Standards Register. Register serves as the official source of

information in the Federal Government regarding standards issued by NBS pursuant to the Federal Property

and Administrative Services Act of 1949 as amended,

Public Law 89-306 (79 Stat. 1127), and as implemented

by Executive Order 11717 (38 FR 12315, dated May 11, 1973) and Part 6 of Title 15 CFR (Code of Federal

Regulations).

Consumer Information Series—Practical information,

based on NBS research and experience, covering areas

of interest to the consumer. Easily understandable

language and illustrations provide useful background

knowledge for shopping in today's technological

marketplace.

NBS Interagency Reports (NBSIR)—A special series of interim or final reports on work performed by NBS for

outside sponsors (both government and non-government). In general, initial distribution is handled by the

sponsor; public distribution is by the National Technical

Information Service (Springfield, Va. 22161) in paper

copy or microfiche form.

Order NBS publications (except NBSIR's and Biblio- graphic Subscription Services) from: Superintendent of

Documents, Government Printing Office, Washington,

D.C. 20402.

BIBLIOGRAPHIC SUBSCRIPTION SERVICES

The following current-awareness and literature-survey

bibliographies are issued periodically by the Bureau:

Cryogenic Data Center Current Awareness Service

A literature survey issued biweekly. Annual subscription: Domestic, $20.00; foreign, $25.00.

Liquefied Natural Gas. A literature survey issued quarterly. Annual subscription : $20.00.

Superconducting Devices and Materials. A literature

survey issued quarterly. Annual subscription : $20.00.

Send subscription orders and remittances for the

preceding bibliographic services to National Bureau of Standards, Cryogenic Data Center (275.02)

Boulder, Colorado 80302.

Electromagnetic Metrology Current Awareness Service

Issued monthly. Annual subscription: $24.00. Send

subscription order and remittance to Electromagnetics

Division, National Bureau of Standards, Boulder,

Colo. 80302.
U.S. DEPARTMENT OF COMMERCE

National Bureau of Standards

Washington. D.C. 20234

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BOOK

1

'•^^6-191^

YEARS

1901-1376 NBS