### Instructions for completing the Fuel Material Analysis Information

This Information Collection Request (ICR) spreadsheet is intended to collect information about chemical analyses of fuels used fossil fuel burning power plants. Constituents of concern are: mercury, chlorine, fluorine, and metals, such as antimony, beryllium, cadmium, chromium, cobalt, lead, manganese, nickel, and selenium. This spreadsheet is intended to be used for one boiler of one facility but is designed to allow multiple (up to 4) fuel analyses at that specific boiler. Th number of analyses would coincide with one boiler where emissions testing for all 4 HAP surrogates were being tested. Data for multiple boilers should be handled by using separate spreadsheets. Fields that are highlighted in yellow are required fields. Green highlighted cells should be filled using the drop

- down boxes, included. Gray fields are automatically filled from other fields.

Please name each resulting spreadsheet with the following naming convention: [FacilityID]_Unit_[BoilerID]_Fuels_Testing.xls (example: 8100_Unit_2_Fuels_Testing.xls).

Please refer to the following steps when using these spreadsheets.

1. Please enter the EIA Facility Code, Facility Name and Boiler ID of your boiler on the Boiler Information worksheet. 2. Please enter the test date on the Boiler Information worksheet. 3. Please choose the type of fuel being sampled using the drop

- down in the fuel column of the Boiler Information worksheet. If you choose "other", please provide a description of the fuel in the Other Fuel Description column. 4. Please provide the analysis method for each constituent in the Analysis Methods worksheet. For example: "ASTM D5865 04". 5. Please check the Units of Measure tables for HHV, Metals, and Cl/Fl in the Picklist worksheet (orange tab). If the units

measure that you plan to report are not found in the Units of measure table, please fill them in the blank, orange highlighted, cell in each table. This allows you to choose the units of measure in the Fuels Sample Results worksheet. 6. Select the HAPs Test Group (i.e., HAP surrogate) for which the tab's data reflects (o range highlighted cell) 7. Provide the Sample Number and Sample Date on the Fuels Sample Results worksheet. You must provide a minimum of 3 composite samples consisting of 3 combined grab samples each, but you are not limited to that number if you have collected

more. 8. Provide the results of the analyses for each constituent requested. Use the drop

- down boxes to fill in the units of

measure.

### Information

This Information Collection Request (ICR) spreadsheet is intended to collect information about chemical analyses of fuels used fossil fuel burning power plants. Constituents of concern are: mercury, chlorine, fluorine, and metals, such as antimony, beryllium, cadmium, chromium, cobalt, lead, manganese, nickel, and selenium. This spreadsheet is intended to be used for one boiler of one facility but is designed to allow multiple (up to 4) fuel analyses at that specific boiler. Th is number of analyses would coincide with one boiler where emissions testing for all 4 HAP surrogates were being tested. Fields that are highlighted in yellow are down boxes, included. Gray fields are automatically

1. Please enter the EIA Facility Code, Facility Name and Boiler ID of your boiler on the Boiler Information worksheet.

down in the fuel column of the Boiler Information worksheet. If you choose "other", please provide a description of the fuel in the Other Fuel Description column. 4. Please provide the analysis method for each constituent in the Analysis Methods worksheet. For example: "ASTM D5865

- 5. Please check the Units of Measure tables for HHV, Metals, and Cl/Fl in the Picklist worksheet (orange tab). If the units of

measure that you plan to report are not found in the Units of measure table, please fill them in the blank, orange highlighted, cell in each table. This allows you to choose the units of measure in the Fuels Sample Results worksheet. range highlighted cell)

. 7. Provide the Sample Number and Sample Date on the Fuels Sample Results worksheet. You must provide a minimum of 3 composite samples consisting of 3 combined grab samples each, but you are not limited to that number if you have collected

down boxes to fill in the units ofEIA

Facility Code Facility Name Boiler ID Fuel Type 1

68029 AES Puerto Rico Unit 1 

### bituminousFuel Type 2 Fuel Type 3 Other Fuel DescriptionEIA

Facility Code Facility Name Boiler ID Basis An alyte



### 68029 AES Puerto Rico Unit 1 As Received Higher Heating Value 

### 68029 AES Puerto Rico Unit 1 As Received % Moisture 

### 68029 AES Puerto Rico Unit 1 As Received % Ash 

### 68029 AES Puerto Rico Unit 1 As Received % Sulfur 

### 68029 AES Puerto Rico Unit 1 Dry basis Higher Heating Value 

### 68029 AES Puerto Rico Unit 1 Dry basis % Ash 

### 68029 AES Puerto Rico Unit 1 Dry basis % Sulfur 

### 68029 AES Puerto Rico Unit 1 Dry basis Antim ony 

### 68029 AES Puerto Rico Unit 1 Dry basis Arsenic 

### 68029 AES Puerto Rico Unit 1 Dry basis Bery llium 

### 68029 AES Puerto Rico Unit 1 Dry basis Cadmium 

### 68029 AES Puerto Rico Unit 1 Dry basis Chlorine 

### 68029 AES Puerto Rico Unit 1 Dry basis Chromium 

### 68029 AES Puerto Rico Unit 1 Dry basis Cobalt 

### 68029 AES Puerto Rico Unit 1 Dry basis Fluorine 

### 68029 AES Puerto Rico Unit 1 Dry basis Lead 

### 68029 AES Puerto Rico Unit 1 Dry basis Manganese 

### 68029 AES Puerto Rico Unit 1 Dry basis Mercury 

### 68029 AES Puerto Rico Unit 1 Dry basis Nickel 

### 68029 AES Puerto Rico Unit 1 Dry basis SeleniumAn alysis M ethod for each Analyte

(example: ASTM D5865-04) 

### D4809 D3173 D482 D1552 / D4239 D5865 D3174 D4239 6010B 6010B 6010B 6010B 9056 6010B 6010B 9056 6010B 6010B 7471A 6010B 6010BEIA

Facility Code Facility

Name Boiler ID HAPs Test Group 

### 68029 AES Puerto Rico Unit 1 Acid gas HAPs

Sample Number (minimum of 3 composite samples) Test Start Date

(MM/DD/YYYY) Test Stop Date

(MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units Unit 1 Run 1 HCl and HCN



### 3/3/2010 3/3/2010 11014.00 Btu/lb Unit 1 Run 2 HCl and HCN



### 3/4/2010 3/4/2010 10850.00 Btu/lb Unit 1 Run 3 HCl and HCN



### 3/4/2010 3/4/2010 10736.00 Btu/lb Fuel Testing Results% Moisture

(as received) % A

sh (as received) % Sulfur

(as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % A sh (Dry Basis) % Sulfur

(Dry Basis) 

### 12 8.21 12516 Btu/lb 9.33 1.298 14 8.82 12329 Btu/lb 10.02 0.967 13 7.85 12200 Btu/lb 8.92 0.805Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units An timony

(Dry Basis) An timony

Units Arsenic (Dry

Basis) Arsenic

Units Beryllium

(Dry Basis) 

### 42 ppm 42 ppm 49 ppmBeryllium

Units Cadmium

(Dry Basis) Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

UnitsNickel (Dry

Basis) Nickel Units Selenium (Dry Basis) Selenium

Units Fluorine

(Dry Basis) Fluorine

Units Cobalt (Dry

Basis) Cobalt Units Total Moisture 

### 32 ppm 12 33 ppm 12 41 ppm 12 Proximate Analy

ses, % by

wtNote the Proximate/Ultimate data below should be recorded on a dry basis (including ash).

Volatiles As h Fixed Carbon Carbon Hydrogen Nitrogen Total Sulfur 

### 38.65 9.33 52.03 69.24 4.49 1.47 1.298 38.91 10.02 51.07 69.41 4.49 1.46 0.967 38.28 8.92 52.79 70.06 4.55 1.63 0.805 Proximate Analy

ses, % by

wt Ultimate Analy ses, % by

wtOxygen



### 12.49 12.35 12.62EIA

Facility Code Facility

Name Boiler ID HAPs Test Group 

### 68029 AES Puerto Rico Unit 1 Mercury and non-mercury metalic HAPs

Sample Number (minimum of 3 composite samples) Test Start Date

(MM/DD/YYYY) Test Stop Date

(MM/DD/YYYY) Higher Heating

Value (HHV) (as received) HHV Units R1 PM/Met 

### 7/29/2010 7/29/2010 11150.00 Btu/lb R2 PM/Met 7/29/2010 7/29/2010 11083.00 Btu/lb R3 PM/Met 7/31/2010 7/31/2010 11236.00 Btu/lb Fuel Testing Results% Moisture

(as received) % A

sh (as received) % Sulfur

(as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % A sh (Dry Basis) % Sulfur

(Dry Basis) 

### 12.8 5.65 12787 Btu/lb 5.65 0.935 13 6.42 12739 Btu/lb 6.42 0.91 14.1 4.73 13081 Btu/lb 4.73 0.793Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units An timony

(Dry Basis) An timony

Units Arsenic (Dry

Basis) Arsenic

Units Beryllium

(Dry Basis) 

### [<7.5] ppm 0.0707 mg/Kg 1.9 mg/Kg 4.4 mg/Kg [<0.11] [<7.5] ppm 0.0758 mg/Kg 2.5 mg/Kg 5.4 mg/Kg 0.65 [<7.5] ppm 0.0515 mg/Kg 1.5 mg/Kg 20 mg/Kg [<0.11]Beryllium

Units Cadmium

(Dry Basis) Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units 

### mg/Kg [<0.15] mg/Kg 4.8 mg/Kg 2.1 mg/Kg 21 mg/Kg mg/Kg [<0.15] mg/Kg 5.3 mg/Kg 2.8 mg/Kg 22 mg/Kg mg/Kg [<0.15] mg/Kg 3.6 mg/Kg 1.8 mg/Kg 29 mg/KgNickel (Dry

Basis) Nickel Units Selenium (Dry Basis) Selenium

Units Fluorine

(Dry Basis) Fluorine

Units Cobalt (Dry

Basis) Cobalt Units 

### 8.5 mg/Kg 4.6 mg/Kg 2.4 mg/Kg 9.8 mg/Kg 4.8 mg/Kg 3.2 mg/Kg 6.9 mg/Kg 4.3 mg/Kg [<0.08] mg/KgNote the Proximate/Ultimate data below should be recorded on a dry basis (including ash).

Total Moisture Volatiles As h Fixed Carbon Carbon Hydrogen Nitrogen Total Sulfur



### 12.8 38.7 6.47 54.81 71.95 4.4 1.5 0.935 13 40.84 7.38 51.78 71.86 4.55 1.52 0.91 14.1 40.81 5.51 63.69 72.94 4.47 1.48 0.793 Proximate Analy

ses, % by

wt Ultimate Analy ses, % by

wtNote the Proximate/Ultimate data below should be recorded on a dry basis (including ash).

Oxygen 

### 12.99 13.14 11.88EIA

Facility Code Facility

Name Boiler ID HAPs Test Group 

### 68029 AES Puerto Rico Unit 1 Non-dioxin/furan organic HAPs

Sample Number (minimum of 3 composite samples) Test Start Date

(MM/DD/YYYY) Test Stop Date (MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units U1 R1 THC HCHO 

### 3/7/2010 3/7/2010 10388.00 Btu/lb U1 R2 THC HCHO 3/7/2010 3/7/2010 10452.00 Btu/lb U1 R3 THC HCHO 3/7/2010 3/7/2010 10373.00 Btu/lb Fuel Testing Results% Moisture

(as received) % A

sh (as received) % Sulfur

(as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % A sh (Dry Basis) % Sulfur

(Dry Basis) 

### 12 9.62 11804 Btu/lb 10.93 0.889 11 8.21 11744 Btu/lb 9.22 1.154 11 10.44 11655 Btu/lb 11.73 1.111Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units An timony

(Dry Basis) An timony

Units Arsenic (Dry

Basis) Arsenic

Units Beryllium

(Dry Basis)Beryllium

Units Cadmium

(Dry Basis) Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

UnitsNickel (Dry

Basis) Nickel Units Selenium (Dry Basis) Selenium

Units Fluorine

(Dry Basis) Fluorine

Units Cobalt (Dry

Basis) Cobalt Units Total Moisture 

### 12 11 11 Proximate Analy

ses, % by

wtNote the Proximate/Ultimate data below should be recorded on a dry basis (including ash).

Volatiles As h Fixed Carbon Carbon Hydrogen Nitrogen Total Sulfur Oxygen 

### 37.49 10.93 51.58 69.6 4.26 1.57 0.889 10.15 38.41 9.22 52.37 70.81 4.37 1.42 1.154 9.98 38.64 11.73 49.64 68.24 3.95 1.39 1.111 12.2 Proximate Analy

ses, % by

wt Ultimate Analy ses, % by

wtEIA

Facility Code Facility

Name Boiler ID HAPs Test Group 

### 68029 AES Puerto Rico Unit 1 Mercury and non-mercury metalic HAPs

Sample Number (minimum of 3 composite samples) Test Start Date

(MM/DD/YYYY) Test Stop Date

(MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units U1 R1 Hg 

### 3/8/2010 3/8/2010 10699.00 Btu/lb U1 R2 Hg 3/8/2010 3/8/2010 10601.00 Btu/lb U1 R3 Hg 3/8/2010 3/8/2010 10460.00 Btu/lb Fuel Testing Results

### Mercury and non-mercury metalic HAPs

% Moisture (as received) % A

sh (as received) % Sulfur

(as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % A sh (Dry Basis) % Sulfur

(Dry Basis) 

### 12 10.13 12158 Btu/lb 11.51 1.039 12 7.13 12047 Btu/lb 8.12 1.104 12 9.69 11886 Btu/lb 11.01 0.958Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units An timony

(Dry Basis) An timony

Units Arsenic (Dry

Basis) Arsenic

Units Beryllium

(Dry Basis) 

### 51 ppm 0.105 mg/Kg 1.8 mg/Kg 5.1 mg/Kg 0.59 44 ppm 0.0496 mg/Kg 2.2 mg/Kg 8.2 mg/Kg 0.62 49 ppm 0.0667 mg/Kg 2 mg/Kg 6.1 mg/Kg 0.59Beryllium

Units Cadmium

(Dry Basis) Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units 

### mg/Kg 0.59 mg/Kg 4.4 mg/Kg 2.6 mg/Kg 25 mg/Kg mg/Kg 0.74 mg/Kg 4.7 mg/Kg 2.5 mg/Kg 25 mg/Kg mg/Kg 0.54 mg/Kg 4.4 mg/Kg 2.2 mg/Kg 27 mg/KgNickel (Dry

Basis) Nickel Units Selenium (Dry Basis) Selenium

Units Fluorine

(Dry Basis) Fluorine

Units Cobalt (Dry

Basis) Cobalt Units Total Moisture 

### 7.3 mg/Kg 3.8 mg/Kg 32 ppm 2.3 mg/Kg 12 8.6 mg/Kg 4.8 mg/Kg 33 ppm 2.8 mg/Kg 12 7.8 mg/Kg 3.8 mg/Kg 41 ppm 2.5 mg/Kg 12 Proximate Analy ses, % by

wtNote the Proximate/Ultimate data below should be recorded on a dry basis (including ash).

Volatiles As h Fixed Carbon Carbon Hydrogen Nitrogen Total Sulfur Oxygen 

### 38.67 11.51 49.83 69.1 3.87 1.37 1.039 10.58 40.08 8.12 51.8 68.83 4.07 1.42 1.104 10.87 38.34 11.01 50.56 69.9 3.85 1.86 0.958 12.06 Proximate Analy

ses, % by

wt Ultimate Analy ses, % by

wtUnits of Measure Tables: Please do not modify these tables, except to add your own unit of measure to the

Fuel Units of Measure - HHV anthracite Btu/lb bitum inous Btu/gallon subbituminous lignite coal refuse (culm or gob) No.2 Fuel Oil (distillate) No.6 Fuel Oil (residual or bunker C) Units of Measure - Metals sy nfuel mg /g petroleum coke μg/g other mg /KgUnits of Measure Tables: Please do not modify these tables, except to add your own unit of measure to the orangehightlighted cell, if necessary

.

Units of Measure - Cl, Fl % ppm