# Quarterly Groundwater Monitoring Report – Outside (Non-Tunnel) Wells Red Hill Fuel Storage Facility Pearl Harbor, Oahu, Hawaii Latitude: 21 o 

# 22’15” N Longitude: 157 o 

# 53’33” W
HDOH Facility ID No. 9-102271 HDOH Release ID No. 99051, 010011, 020028
August 2010

Prepared by:

TEC Inc. 1003 Bishop St. Suite 1550 Pauahi Tower Honolulu, Hawaii 96813

Prepared for:

Commander Navy Region Hawaii Environmental Department, Code N45 850 Ticonderoga Street, Suite 110 Pearl Harbor, Hawaii 96860-5101

## 1 

# Table of Contents
Table of Contents ............................................................................................................................ 1 Executive Summary ......................................................................................................................... 2 1.0 Introduction .......................................................................................................................... 3 1.1 Project Objective ............................................................................................................. . 3 1.2 Previous Reports .............................................................................................................. 3 1.3 Background .................................................................................................................... .. 4 1.3.1 Site Description ......................................................................................................... 4 1.3.2 Facility Information .................................................................................................. 5 1.3.3 UST Information ....................................................................................................... 6 1.4 Regulatory Updates .......................................................................................................... 6 2.0 Sample Collection and Analyses .......................................................................................... 6 2.1 Monitoring Well Purging ................................................................................................. 6 2.2 Groundwater Sample Collection ...................................................................................... 7 2.3 Groundwater Sample Analyses ........................................................................................ 7 3.0 Groundwater Sample Analytical Results ............................................................................ 6 3.1 July 2010 Sample Analytical Results ............................................................................... 7 4.0 Summary and Conclusions ............................................................................................... 9 5.0 References .......................................................................................................................... 12
List of Tables Table 1 Monitoring Well Information ........................................................................................6 Table 2 Analytical Results for Quarte rly Groundwater Sampling (July 8, 2010) ......................8 List of Figures Figure 1 Groundwater Monitoring Well Locations ....................................................................10 Figure 2 TPH Detected in Groundwater .....................................................................................11 List of Appendices Appendix A – Laboratory Analytical Reports

## 2 

# Executive Summary There are 18 active and 2 inactive, 12.5 million gallon, field-constructed underground storage tanks (USTs) located at the Red Hill Fuel Storage F acility (the Facility). Previous environmental site investigations i ndicated a release had o ccurred and contaminated the groundwater underlying the Facility. The United States (US) Navy implemented a gr oundwater monitoring program, which includes collecting groundwater samples quarterly from US Navy Well 2254-01 (RHMW2254-01) and four wells installed in the Facility lower access tunnel (RHMW01, RHMW02, RHMW03, and RHMW05). The US Navy Well 2254-01 is located approximately 3,000 feet downgradient from the Facility and provides approx imately 24 percent of the potable water to the Pearl Harbor Water System (PHWS). The groundwater samples are analyzed for petroleum constituents and compared against State of Hawaii Depart ment of Health (HDOH) Drinking Water Environmental Action Levels (EALs) (HDOH, 2008). In response to increasing concentr ations of contaminants of poten tial concern in the groundwater monitoring wells within the faci lity (specifically RHMW02) dur ing 2008, plans were made to conduct four rounds of quarterly sampling at th e following outside monitoring well locations:

 RHMW04;

 Oily Waste Disposal Facility monitoring well 01 (OWDFMW01); and

 Halawa Deep Well 2253-03 (referred to as HDMW2253-03 in this report). Since four quarterly sampling events at RHMW04 and OWDFMW01 have already been completed (during August 2009 through April 2010), this groundwater monitoring report presents the analytical results for sample s collected on July 8, 2010 at HDMW2253-03. Laboratory analytical results indi cate that only naphthalene wa s detected above the laboratory method detection limit (MDL) via United Stated Environmental Protection Agency (USEPA) Method 8279C SIM at 0.0596F μg/L [F indicate s that the compound was identified, with the concentration above the laboratory MDL, but be low the reporting limit (RL), therefore it is considered an estimate] in HDMW2253-03. No other compounds were detected above the MDL during July 2010.

## 3 

# 1.0 Introduction This report presents the results of the f ourth groundwater sampling event at HDMW2253-03, conducted in July 2010. The first, second, and third sampling events at HDMW2253-03 were conducted in October 2009, January 2010, and Ap ril 2010, respectively. Four quarterly sampling events at two other monitoring we lls (RHMW04 and OWDFMW01) were completed during August 2009, October 2009, January 2010, and April 2010. An August 2009 sampling event for HDMW2253-03 was not conducted due to access issues.
These three wells surround the Red Hill Fuel Stor age Facility, Oahu, Hawaii (hereafter referred to as “the Facility”). This groundwater sampling and analysis is considered supplemental to the quarterly groundwater monitoring program conducte d within the Facility. This supplemental sampling was conducted in response to increasing concentrations of cont aminants of potential concern in a groundwater monitoring well with in the Facility, specif ically RHMW02 during 2008. 

# 1.1 Project Objective This groundwater sampling project was performed to evaluate the presence of chemicals of potential concern in gr oundwater surrounding the Facility. The projec t was conducted to ensure the Navy remains in compliance with Hawaii De partment of Health (HDOH) UST release response requirements. The groundwater sampli ng program followed the procedures described in Red Hill Bulk Fuel Storage Fa cility Groundwater Protection Plan [TEC Inc. (TEC), 2008 updated in 2009], also refe rred to as “the Plan”. This groundwater sampling event was condu cted by TEC under United States (US) Navy Contract Number N47408-04-D-8514, Task Order No. 54, Modification No. 01. 

# 1.2 Previous Reports As indicated earlier, this outside well sa mpling supplements the quarterly groundwater monitoring of wells within the Facility, which began in 2005. The following groundwater monitoring reports were previously submitted to the HDOH, for groundwater monitoring wells within the Facility:
1. Groundwater Sampling Report, First Quarter 2005 (submitted April 2005); 2. Groundwater Sampling Report, Second Quarter 2005 (submitted August 2005); 3. Groundwater Sampling Report, Third Quarter 2005 (submitted November 2005); 4. Groundwater Sampling Report, Fourth Quarter 2005 (submitted February 2006); 5. Groundwater Monitoring Results, July 2006 (submitted September 2006); 6. Groundwater Monitoring Results, December 2006 (submitted January 2007); 7. Groundwater Monitoring Results, March 2007 (submitted May 2007); 8. Groundwater Monitoring Results, June 2007 (submitted August 2007); 9. Groundwater Monitoring Results, September 2007 (submitted October 2007);

## 4 10. Groundwater Monitoring Results, January 2008 (submitted March 2008); 11. Groundwater Monitoring Results, April 2008 (submitted May 2008); 12. Groundwater Monitoring Results, July 2008 (submitted October 2008); 13. Groundwater Monitoring Results, October and December 2008 (submitted February 2009); 14. Groundwater Monitoring Results, February 2009 (submitted May 2009); 15. Groundwater Monitoring Results, May 2009 (submitted July 2009); 16. Groundwater Monitoring Results, July 2009 (submitted September 2009); 17. Groundwater Monitoring Results, Oc tober 2009 (submitted December 2009); 18. Groundwater Monitoring Results, January, February, and March 2010 (submitted April 2010); 19. Groundwater Monitoring Results, April 2010 (submitted May 2010); and 20. Groundwater Monitoring Results, July 2010 (submitted August 2010).
The following groundwater monitoring reports we re previously submitted to the HDOH for groundwater monitoring wells outside the Facility:
1. Groundwater Monitoring Results, August 2009 (submitted September 2009); 2. Groundwater Monitoring Results, Oc tober 2009 (submitted December 2009); 3. Groundwater Monitoring Results, January 2010 (submitted April 2010); and 4. Groundwater Monitoring Results, April 2010 (submitted May 2010). 

# 1.3 Background The following sections provide a description of th e site and information on the Facility and USTs.
1.3.1 Site Description The Facility is located in Red Hill, Oahu, Hawaii. Land adjacent to the north of the Facility is occupied by the Halawa Correctional Facility and private businesses. Land to the south and west of the Facility includes the Coas t Guard Reservation. Moanalua Valley is located east of the Facility (Dawson, 2006). The Navy Public Works Department operates a pot able water infiltratio n tunnel approximately 1,550 feet from the Facility (Dawson, 2006) . The US Navy Well 2254-01 is located approximately 3,000 feet west of the Facility and provides approximatel y 24% of the potable water to the Pearl Harbor Water System, whic h serves approximately 52,200 military consumers (TEC, 2008).

## 5 1.3.2 Facility Information The Facility consists of 18 ac tive and two inactive USTs operat ed by Navy Fleet and Industrial Supply Center (FISC) Pearl Harbor. Each UST has a capacity of 12.5 million gallons. The Facility is located approximately 100 feet above the basal aquifer (Dawson, 2006). In 2002, the US Navy installed a groundwater monitoring well (cur rently named RHMW01) into the basal aquifer, directly down-gradient from the Facility, within th e lower access tunnel. Groundwater samples from this well indicated that petroleum from the Facility has migrated to the basal aquifer (AMEC, 2002). In 2005, the US Navy began quarterly monitoring of the aquifer to protect their down-grad ient drinking water resource a ssociated with the US Navy Well 2254-01. By September 2005, the US Navy had installe d two more groundwater monitoring wells (RHMW02 and RHMW03) within the Facility UST system, a groundwater monitoring well (RHMW04) north of the Facility adjacent to the US Navy Firing Range, and a groundwater monitoring well within the US Navy Well 2254-01 infiltration ga llery (RHMW2254-01). Since 2005, RHMW01, RHMW02, RHMW03, and RHMW2254-01 ha ve been sampled quarterly for TPH-DRO, TPH-GRO, VOCs, PAHs, and dissolved lead. Due to increasing concentrations of contamin ants of potential con cern at the groundwater monitoring wells within the Fa cility (specifically RHMW02) during 2008, response measures were warranted. In April 2009, another groundwa ter monitoring well (RHMW05) was installed within the lower access tunne l between RHMW01 and RHMW2254- 01. It was installed to identify the extent of contaminant migration be fore it reaches the infiltration gallery at RHMW2254-01. Additionally, plans were made to sample three monitoring wells surrounding and outside of the Facility, RHMW04, OWDFMW01, and HDMW2253- 03. RHMW04 was installed to provide contaminant chemistry data for water moving through the basal aquifer beneath the Facility. OWDFMW01 (originally known as MW08) was inst alled into the basal aquifer in 1998 for a Phase II Remedial Investigation/ Feasibility St udy for the Red Hill Oily Waste Disposal Facility (Earth Tech Inc., 2000). It is located geographi cally down-gradient of the USTs and US Navy Well 2254-01. HDMW2253-03 is controlled by the State of Hawaii Commission on Water Resource Management. It is located between the Facility and the mu nicipal drinking water supply well run by the City and County of H onolulu Board of Water Supply (Halawa Shaft pumping station 2354-01). Table 1 summarizes basic gr oundwater monitoring well information, Figure 1 shows groundwater monitoring well locations and Appendix A provides the laboratory data.

## 6 Table 1. Monitoring Well Information

Groundwater Well TOC Elevation (ft msl) DTW (ft) TD (ft)

RHMW04 313.03 293 320 OWDFMW01 138.94 120 142.8 HDMW2253-03 225 210 1,575 Notes: DTW - Distance to water TD - Total depth of well TOC - Top of casing ft – Feet ft msl - Feet from mean sea level



## 1.3.3 UST Information The USTs were constructed in th e early 1940s. The tanks were c onstructed of steel and currently contain Jet Propulsion (JP)–5 fuel, JP-8, and F-76 (diesel marine fuel). Previously, several tanks stored Navy Special Fuel Oil, Navy Distillate, av iation gasoline, and motor gasoline. Each tank measures approximately 245 feet in height and 100 feet in diameter. The upper domes of the tanks lie at depths varying between approxima tely 100 feet and 200 feet below the existing ground surface (TEC, 2006). 

# 1.4 Regulatory Updates During the summer and fall of 2008, HDOH updated their EALs, which resulted in significant changes to the action levels associated with me thylnaphthalenes. The drinking water toxicity EAL for these compounds was 240  g/L. This concentration pres umed that methylnaphthalenes were non-carcinogenic. Evidence th at they are human carcinogens has now been accepted by the US Environmental Protection Agency (USEPA). As a result, HDOH adopted more rigorous EALs of 4.7  g/L for 1-methylnaphthalene and 24  g/L for 2-methylnaphthalene, corresponding to a residential tap water scenario, and a 1 in a million cancer risk (HDOH, 2008). Also, the drinking water EAL for na phthalene was increased from 6.2  g/L to 17  g/L (HDOH, 2008). Finally, the HDOH Drinking Water EA L for TPH-DRO was increased from 100  g/L to 210  g/L, although the HDOH Groundw ater Gross Contamination EAL for TPH-DRO remains 100  g/L. 

# 2.0 Sample Collection and Analyses Field activities relating to groundwater samp le collection were conducted on July 8, 2010. Groundwater samples were collected from one monitoring well, HDMW2253-03. Sampling and analysis were conducted according to Red Hill Bulk Fuel Storage Facility Groundwater Protection Plan (TEC, 2008). 

# 2.1 Monitoring Well Purging Due to the well construction characteristics of HDMW2253-03, the well was not purged prior to sampling, but field parameters were recorded. Ra ther than purging, a grab sample was collected at a depth below the solid casing (which extends about 50 feet be low the water table) and within the open-holed portion of the well. Field pa rameters included pH, temperature, specific conductivity, dissolved oxygen, and turbidity.

## 7 

# 2.2 Groundwater Sample Collection HDMW2253-03 was sampled using a disposable bail er designed to collect samples at desired depths. Samples were placed into sampling cont ainers with appropriate preservatives [i.e., hydrochloric acid (HCl) for volatile or ganic analysis, nitric acid (HNO 3 

## ) for dissolved lead]. The dissolved lead sample was filtered in the fiel d and placed in a preserved bottle. Sample containers were labeled with the date, sample identification number, type of analysis, and sampler’s name. The containers were placed on ice in a sample cooler and transported under chain-of-custody procedures to the certified laboratory for analysis. 

# 2.3 Groundwater Sample Analyses Groundwater samples were analyzed by SGS Environm ental Service, Inc. in Anchorage, Alaska for TPH-DRO and TPH-GRO by EPA Method 8015B, VOCs by EPA Method 8260B, PAHs by EPA Method 8270C SIM, and dissolved lead by EPA Method 6020. 

# 3.0 Groundwater Sample Analytical Results This section provides a summary of analytical results for groundwater samples collected from HDMW2253-03. A summary of gr oundwater analytical results for TPH-DRO and TPH-GRO, VOCs, PAHs, and dissolved lead is included in Ta ble 2. Complete analytical laboratory reports are provided in Appendix A. 

# 3.1 July 2010 Sample Analytical Results Groundwater samples were analyzed for TPH- DRO, TPH-GRO, VOCs, PAHs, and dissolved lead. The results are discussed below.
HDMW2253-03 Naphthalene was analyzed by USEPA Method 8270C SIM and USEPA Method 8260B. Trace concentrations of naphthalene was detected at 0.0596F μg/L [F indicates that the compound was identified, with the concentra tion above the laborato ry method detection limit (MDL), but below the reporting limit (RL), theref ore it is considered an es timate] in HDMW2253-03, via USEPA Method 8270C SIM. This concentration is significantly below th e HDOH Drinking Water EAL for this constituent (i.e., 17 μg/L). No other po tential chemical of concern was detected above the laboratory MDL in HDMW2253-03 (Table 2).Page  Table 

. Analytical Results for Quarterly Groundwater Monitoring Release Response Report (July 8, 2010) Red Hill Fuel Storage Facility, Pearl Harbor, Hawaii

Result Q MDL RL TPH as DIESEL RANGE ORGANICS 210 100 ND U 160 426 TPH as GASOLINE RANGE ORGANICS 100 100 ND U 30 100 1-METHYLNAPHTHALENE 4.7 10 ND U 0.0174 0.0581 2-METHYLNAPHTHALENE 24 10 ND U 0.0174 0.0581 ACENAPHTHENE 370 20 ND U 0.0174 0.0581 ACENAPHTHYLENE 240 2000 ND U 0.0174 0.0581 ANTHRACENE 1800 22 ND U 0.0174 0.0581 BENZO(a)ANTHRACENE 0.092 4.7 ND U 0.0174 0.0581 BENZO(a)PYRENE 0.2 0.81 ND U 0.0174 0.0581 BENZO(b)FLUORANTHENE 0.092 0.75 ND U 0.0174 0.0581 BENZO(g,h,i)PERYLENE 1500 0.13 ND U 0.0174 0.0581 BENZO(k)FLUORANTHENE 0.92 0.4 ND U 0.0174 0.0581 CHRYSENE 9.2 1 ND U 0.0174 0.0581 DIBENZ(a,h)ANTHRACENE 0.0092 0.52 ND U 0.0174 0.0581 FLUORANTHENE 1500 130 ND U 0.0174 0.0581 FLUORENE 240 950 ND U 0.0174 0.0581 INDENO(1,2,3-c,d)PYRENE 0.092 0.095 ND U 0.0174 0.0581 NAPHTHALENE 17 21 0.0596 F 0.036 0.116 PHENANTHRENE 240 410 ND U 0.0174 0.0581 PYRENE 180 68 ND U 0.0174 0.0581 1,1,1,2-TETRACHLOROETHANE 0.52 50000 ND U 0.15 0.5 1,1,1-TRICHLOROETHANE 200 970 ND U 0.31 1 1,1,2,2-TETRACHLOROETHANE 0.067 500 ND U 0.15 0.5 1,1,2-TRICHLOROETHANE 5 50000 ND U 0.31 1 1,1-DICHLOROETHANE 2.4 50000 ND U 0.31 1 1,2,3-TRICHLOROPROPANE (TCP) 0.6 50000 ND U 0.31 1 1,2,4-TRICHLOROBENZENE 70 3000 ND U 0.31 1 1,2-DIBROMO-3-CHLOROPROPANE (DBCP) 0.04 10 ND U 0.62 2 1,2-DIBROMOETHANE (EDB) 0.0065 50000 ND U 0.31 1 1,2-DICHLOROBENZENE 600 10 ND U 0.31 1 1,2-DICHLOROETHANE 0.15 7000 ND U 0.15 0.5 1,2-DICHLOROPROPANE 5 10 ND U 0.31 1 1,3-DICHLOROBENZENE 180 50000 ND U 0.31 1 1,4-DICHLOROBENZENE 75 5 ND U 0.15 0.5 ACETONE 22000 20000 ND U 3.1 10 BENZENE 5 170 ND U 0.12 0.4 BROMODICHLOROMETHANE 0.22 50000 ND U 0.15 0.5 BROMOFORM 100 510 ND U 0.31 1 BROMOMETHANE 8.7 50000 ND U 0.94 3 CARBON TETRACHLORIDE 5 520 ND U 0.31 1 CHLOROBENZENE 100 50 ND U 0.15 0.5 CHLOROETHANE 8600 16 ND U 0.31 1 CHLOROFORM 70 2400 ND U 0.3 1 CHLOROMETHANE 1.8 50000 ND U 0.31 1 cis-1,2-DICHLOROETHYLENE 70 50000 ND U 0.31 1 cis-1,3-DICHLOROPROPENE 0.43 50000 ND U 0.15 0.5 DIBROMOCHLOROMETHANE 0.16 50000 ND U 0.15 0.5 ETHYLBENZENE 700 30 ND U 0.31 1 HEXACHLOROBUTADIENE 0.86 6 ND U 0.31 1 M,P-XYLENE (SUM OF ISOMERS) 10000 20 ND U 0.62 2 METHYL ETHYL KETONE (2-BUTANONE) 7100 8400 ND U 3.1 10 METHYL ISOBUTYL KETONE (4-METHYL-2-PENTANONE) 2000 1300 ND U 3.1 10 METHYLENE CHLORIDE 4.8 9100 ND U 1 5 NAPHTHALENE 17 21 ND U 0.62 2 STYRENE 100 10 ND U 0.31 1 TETRACHLOROETHYLENE(PCE) 5 170 ND U 0.31 1 TOLUENE 1000 40 ND U 0.31 1 trans-1,2-DICHLOROETHENE 100 260 ND U 0.31 1 TRICHLOROETHYLENE (TCE) 5 310 ND U 0.31 1 VINYL CHLORIDE 2 3400 ND U 0.31 1 XYLENES, TOTAL 10000 20 ND U 0.94 3 6020 LEAD 15 50000 ND U 0.31 1 PAHs - Polynuclear aromatic hydrocarbons VOCs - Volatile organic compounds UG/L - Micrograms per Liter Q - Data qualifier U - Indicates that the compound was analyzed for but not detected at or above the stated limit MDL - Method detection limit

RL - Reporting limit TPH - Total petroleum hydrocarbons

ND - Indicates that the compound was not detected above the stated method detection limit

F - Indicates that the compound was identified but the concentration was above the MDL and below the RL

- Result exceeds one or both HDOH EALs 1

2 HDMW2253-03 UG/L

8015B (Petroleum)

8270C SIM

(PAHs)

8260B (VOCs)

Final Drinking Water Action Levels for Human Toxicity, Table D-3a, Screening for Environmental Concerns at Sites with Contaminated Soil and Groundwater , HDOH, 2009 Groundwater Gross Contamination Action Levels, Table G-1, Screening for Environmental Concerns at Sites with Contaminated Soil and Groundwater , HDOH, 2009 July 8, 2010 Method HDOH Drinking Water EALs 1 for Human Toxicity UG/L HDOH Groundwater Gross Contamination EALs 2 UG/L Chemical

200

## 9 

# 4.0 Summary and Conclusions Summary In HDMW2253-03, trace naphthalene was detected at 0.0596F μg/L. This concentration is below the HDOH Drinking Water EAL, and the HDOH Gross Contamination EAL. No other potential chemicals of concern were detect ed above the laboratory MDLs in HDMW2253-03 during the July 2010 sampling event. This is the first time naphthalene was dete cted at HDMW2253-03 during the four quarterly sampling events. Previously, only TPH-DR O has been detected at HDMW2253-03 and OWDFMW01. TPH-DRO has not been detected above the laboratory MDL in HDMW2253-03 since January 2010. Figure 2 summarizes TPH resu lts for three wells outsi de of the Facility during all four quarter ly sampling events.
Conclusions/Recommendations No compounds were detected above the MDLs during the August 2009 sampling event at OWDFMW01 and RHMW04 (HDMW2253-03 was not sampled in August 2009 due to access issues); or during the October 2009 sa mpling event at OWDFMW01, RHMW04, or HDMW2253-03. Despite the detection of TPH-DRO at HDMW2 253-03 during January 2010, TPH-DRO was not detected above the laboratory MDL during the April 2010 and July 2010 sampling events. Since two or more consecutive sampling events of incr easing (or decreasing) concentrations of TPHDRO at HDMW2253-03 have not occurred, no trend for TPH-DRO has been established at this location.
TPH-DRO detected at OWDFMW 01 during January 2010 significantly decreased in April 2010 (i.e., from 1,490 μg/L in January 2010 to 288F μg/L in April 2010). TPH-DRO (detected at both HDMW2253-03 and OWDFMW01 in January 2010 and only at OWDFMW01 in April 2010) has been the only parameter detected above HDOH Drinking Water EALs during all four outside well samp ling rounds. For the th ree wells surrounding the Facility (i.e., RHMW04, OWDFMW01, and HD MW2253-03), no more sampling event remains tasked under Contract Number N47408-04-D-8514, Task Order No. 54, Modification No. 01. Consequently, consideration should be given to conducting follow-on, periodic (perhaps semiannually), targeted monitoring of thes e outside wells for TPH-DRO.Figure1GroundwaterMonitoringWellLocationsdilll SiliReHFuetorageFactyOahu,HawaiiRHMW04 (ug/L)CompoundAugust 4, 2009 October 13, 2009 January 26, 2010 April 26, 2010Result Q MDL RL Result Q MDL RL Result Q MDL RL Result Q MDL RLTPH-DRO ND U 157 419 ND U 169 452 ND U 167 444 ND U 174 465TPH-GRONDU30100NDU30100NDU30100NDU30100HDMW2253-03 (ug/L)CompoundOctober 13, 2009 January 26, 2010 April 26, 2010 July 8, 2010Result Q MDL RL Result Q MDL RL Result Q MDL RL Result Q MDL RLTPH-DRO ND U 185 494322F 172 460 ND U 176 471 ND U 160 426TPH-GRONDU30100NDU30100NDU30100NDU30100TPH-GRONDU30100NDU30100NDU30100NDU30100RHMW04D (ug/L)CompoundAugust 4, 2009 October 13, 2009 January 26, 2010 April 26, 2010Result Q MDL RL Result Q MDL RL Result Q MDL RL Result Q MDL RLTPH-DRO ND U 161 430 ND U 174 465 ND U 165 440 ND U 176 471OWDFMW01 (ug/L)TPH-GRONDU30100NDU30100NDU30100NDU30100TPH-GRO ND U 30 100 ND U 30 100 ND U 30 100 ND U 30 100CompoundAugust 4, 2009 October 13, 2009 January 26, 2010 April 26, 2010Result Q MDL RL Result Q MDL RL Result Q MDL RL Result Q MDL RLTPH-DRO ND U 171 457 ND U 167 4441490165 440288F 176 471TPH-GRO ND U 30 100 ND U 30 100 ND U 30 100 ND U 30 100Notes:F - Estimated result between the RL and MDLDRO - Diesel Range OrganicsGRO - Gasoline Range OrganicsMDL - Method Detection LimitND - Not DetectedQ - Data QualifierFigure2TPHDetectedInGroundwaterOutside(Non‐Tunnel)WellsRL - Reporting LimitTPH - Total Petroleum HydrocarbonsU - Result not detectedug/L - Micrograms per liter200 - Result exceeded one orboth HDOH EALs200Outside(NonTunnel)WellsRedHillFuelStorageFacilityOahu,Hawaii•TPH-DRO Residential Tap Water EAL is 210 ug/L; and•TPH-GRO Residential Tap Water EAL is 100 ug/L;(HDOH, 2008).

## 12 

# 5.0 References AMEC. Red Hill Bulk Fuel Storage Facility Investigation Report , Prepared for NAVFAC Pacific, August 2002. Dawson Group, Inc. Fourth Quarter 2005 Groundwater Sam pling Report, Red Hill Fuel Storage Facility, Hawaii. February 2006. Earth Tech, Inc. Remedial Investigation Phase II, Volume I, Technical Report, Red Hill Oily Waste Disposal Facility, Halawa, Oahu, Hawaii . September 2000. Hawaii Administrative Rules, Titl e 11, Chapter 281, Subchapter 7.
HDOH. Screening for Environmental Concerns at Sites with Contaminated Soil and Groundwater, Summary Lookup Tables. March 2009.
HDOH. Use of May 2005 Environmental Action Levels (“EALs”) at Leaking Underground Storage Tank Sites . Memo. July 2005.
HDOH. Evaluation of Environmental Hazards at Sites with Contaminated Soil and Groundwater . Summer 2008 (updated October 2008).
TEC, Inc. Red Hill Bulk Fuel Storage Facility, Fi nal – Addendum Planning Documents, Pearl Harbor, Hawaii. May 2006.
TEC, Inc. Red Hill Bulk Fuel Storage Facility, Final Groundwater Protection Plan, Pearl Harbor, Hawaii. January 2008 revised in December 2009.

# Appendix A Laboratory Analytical Reports

## SGS Work Order:

Contents: Cover Page Case Narrative Final Report Pages Quality Control Summary Forms Chain of Custody/Sample Receipt Forms 

## Project: Client: 

# SGS North America Inc. Alaska Division Level II Laboratory Data Report

Released by:

Note: Unless otherwise noted, all quality assurance/quality control criteria is in compliance with the standards set forth by the proper regulatory authority, the SGS Quality Assurance Program Plan, and the National Environmental Accreditation Conference. 

## 3354-003 Red Hill BFSF The Environmental Company, Inc. (TEC) 1103364

## CASE NARRATIVE Print Date: 7/30/2010

Workorder No.: 1103364 Project Name: 3354-003 Red Hill BFSF Client Name: The Environmental Company, Inc. (TEC)

Lab Sample ID 

## Sample Comments

Sample Type Client Sample ID Refer to the sample receipt form for information on sample condition.

1103364001 8270D SIM – The corrected CCV recovery for naphthalene does not meet QC criteria (biased high). The results for this

analyte may be estimated in the associated samples. 8270D SIM Corrected Report - Results for this analysis are being resubmitted based on a correction to the initial calibration. PS HDMW2253-03-WG-05

972723 8270D SIM - LCSD recovery for napthalene is outside of QC criteria (biased high). The results for this analyte may be

estimated in the associated samples. 8270D SIM - LCS/LCSD RPD for napthalene is outside of QC criteria (biased high). The results for this analyte may be estimated in the associated samples. LCSD LCSD for HBN 515780 [XXX/23016 

### *

973529 8260B - LCS recovery for acetone does not meet QC criteria (biased high). This analyte was not detected above the LOQ in

the associated samples. LCS LCS for HBN 533980 [VXX/20930] 

### *

973530 8260B - LCSD recovery for acetone and 2-hexanone does not meet QC criteria (biased high). These analytes were not

detected above the LOQ in the associated samples. 8260B - LCS/LCSD RPD for acetone does not meet QC criteria. This analyte was not detected above the LOQ in the associated samples. LCSD LCSD for HBN 533980 [VXX/20930 

### *

973543 8260B - CCV recovery for several analytes does not meet QC criteria (biased high). These analytes were not detected

above the LOQ in the associated samples. CCV CCV for HBN 534280 [VMS/11383] 

### *

976463 8270D SIM – The corrected CCV recovery for naphthalene does not meet QC criteria (biased high). The results for this

analyte may be estimated in the associated samples. CCV CCV for HBN 599080 [XMS/5543] 

### *

* QC comments may be associated with the field samples found in this report. When applicable, comments will be applied to associated field samples.

SG S N o rth A m eric a Inc . En vir onm enta l D ivision 200 W e st Potter D rive A nc hora ge A K 99518 t (907 )562.2343 f ( 907)561 .5301 w w w .us.sgs.com M em ber of SG S GroupPrint Date: 7/30/2010 4:34 pm 

### Report of Manual Integrations
Laboratory ID Client Sample ID Analytical Batch Method Analyte Reason 972722 LCS for HBN 515780 [XXX/23016] XMS5511 8270D SIMS Benzo[k]fluoranthene RP 972723 LCSD for HBN 515780 [XXX/23016 XMS5511 8270D SIMS Benzo[k]fluoranthene RP 

### Manual Integration Reason Code Descriptions Code Description O Original Chromatogram M Modified Chromatogram SS Skimmed surrogate BLG Closed baseline gap RP Reassign peak name PIR Pattern integration required IT Included tail SP Split peak RSP Removed split peak FPS Forced peak start/stop BLC Baseline correction PNF Peak not found by software All DRO/RRO analysis are integrated per SOP.

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S Group

### 3354-003 Red Hill BFSF

Project Manager jennifer.serna@sgs.com Jennifer Serna T: (808)528-1445 F:(808)528-0768 Attn: Rick Adkisson 1003 Bishop Street, Pauahi Tower Suite 1550 Honolulu, HI 96813

Certification: This data package is in compliance with the terms and conditions of the contract, both technically and for completeness, unless otherwise noted on the sample data sheet(s) and/or case narrative. This certification applies only to the tested parameters and the specific sample(s) received at the laboratory. If you have any questions regarding this report, or if we can be of further assistance, please contact your SGS Project Manager. 

### 1103364 The Environmental Company, Inc. (TEC)

Workorder No.:

Client:

Project: 

# Laboratory Analytical Report

Contents (Bookmarked in PDF): Cover Page Glossary Sample Summary Forms Case Narrative Sample Results Forms Batch Summary Forms (by method) Quality Control Summary Forms (by method) Chain of Custody/Sample Receipt Forms Attachments (if applicable)

SGS No rth Americ a Inc . En vir onmenta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com Member of SG S Group

### Enclosed are the analytical results associated with the above work order. All results are intended to be used in their entirety and SGS is not responsible for use of less than the complete report. If you have any questions regarding this report, or if we can be of any other assistance, please contact your SGS Project Manager at 907-562-2343. All work is provided under SGS general terms and conditions (<http://www.sgs.com/terms_and_conditions.htm>), unless other written agreements have been accepted by both parties.
SGS maintains a formal Quality Assurance/Quality Control (QA/QC) program. A copy of our Quality Assurance Plan (QAP), which outlines this program, is available at your request. The laboratory certification numbers are AK00971 (DW Chemistry & Microbiology) & UST-005 (CS) for ADEC and AK100001 for NELAP (RCRA methods: 1020A, 1311, 3010A, 3050B, 3520C, 3550C, 5030B, 5035B, 6010B, 6020, 7470A, 7471B, 8021B, 8081B, 8082A, 8260B, 8270D, 8270D-SIM, 9040B, 9045C, 9056A, 9060A, AK101 and AK102/103). Except as specifically noted, all statements and data in this report are in conformance to the provisions set forth by the SGS QAP and, when applicable, the National Environmental Laboratory Accreditation Program and other regulatory authorities. The following descriptors or qualifiers may be found in your report:

* The analyte has exceeded allowable regulatory or control limits. ! Surrogate out of control limits. B Indicates the analyte is found in a blank associated with the sample. CCV Continuing Calibration Verification CL Control Limit D The analyte concentration is the result of a dilution. DF Dilution Factor DL Detection Limit (i.e., maximum method detection limit) E The analyte result is above the calibrated range. F Indicates value that is greater than or equal to the DL GT Greater Than ICV Initial Calibration Verification J The quantitation is an estimation. JL The analyte was positively identified, but the quantitation is a low estimation. LCS(D) Laboratory Control Spike (Duplicate) LOD Limit of Detection (i.e., 2xDL) LOQ Limit of Quantitation (i.e., reporting or practical quantitation limit) LT Less Than M A matrix effect was present. MB Method Blank MS(D) Matrix Spike (Duplicate) ND Indicates the analyte is not detected. Q QC parameter out of acceptance range. R Rejected RL Reporting Limit RPD Relative Percent Difference U Indicates the analyte was analyzed for but not detected.
Note: Sample summaries which include a result for "Total Solids" have already been adjusted for moisture content.

All DRO/RRO analyses are integrated per SOP. Print Date: 7/30/2010

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S Group

## SAMPLE SUMMARY Client Name: The Environmental Company, Inc. (TEC) Project Name: 3354-003 Red Hill BFSF Workorder No.: 1103364 

## Analytical Methods
Method Description Analytical Method 8270 PAH SIM Semi-Vol GC/MS Liq/Liq ext. 8270D SIMS AFCEE 3.1 8260 (W) SW8260B Dissolved Metals by ICP-MS SW6020 DRO by 8015C (W) SW8015C GRO (W) SW8015C Print Date: 7/30/2010 4:34 pm



## Sample ID Cross Reference
Client Sample ID Lab Sample ID 1103364001 HDMW2253-03-WG-05 1103364002 TB01-WG-05

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S Group

### The Environmental Company, Inc. (TEC) Print Date: 7/30/2010 4:34 pm

Client Sample ID: 

### HDMW2253-03-WG-05 SGS Ref. #: 1103364001 Collection Date/Time: 07/08/10 10:05 Receipt Date/Time: 07/09/10 11:30 Project ID: 3354-003 Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch LOQ/CL Units Qualifiers Parameter Result 

### Dissolved Metals by ICP/MS

DL DF

Lead 0.620 U 1.00 ug/L MMS6543 MXX23243 0.310 5
Batch Information Initial Prep Wt./Vol.: 50 mL Prep Extract Vol.: 50 mL Analytical Batch: MMS6543 Analytical Method: SW6020 Analysis Date/Time: 07/21/10 19:48 Prep Batch: MXX23243 Prep Method: SW3010A Prep Date/Time: 07/16/10 18:10 Container ID:1103364001-G Dilution Factor: 5 Analyst: KDC

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S Group

### The Environmental Company, Inc. (TEC) Print Date: 7/30/2010 4:34 pm

Client Sample ID: 

### HDMW2253-03-WG-05 SGS Ref. #: 1103364001 Collection Date/Time: 07/08/10 10:05 Receipt Date/Time: 07/09/10 11:30 Project ID: 3354-003 Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch LOQ/CL Units Qualifiers Parameter Result 

### Volatile Fuels Department

DL DF
Gasoline Range Organics 60.0 U 100 ug/L VFC10031 VXX20961 30.0 1 4-Bromofluorobenzene <surr> 105 50-150 % VFC10031 VXX20961 1
Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VFC10031 Analytical Method: SW8015C Analysis Date/Time: 07/20/10 15:09 Prep Batch: VXX20961 Prep Method: SW5030B Prep Date/Time: 07/20/10 12:00 Container ID:1103364001-B Dilution Factor: 1 Analyst: EAB

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S Group

### The Environmental Company, Inc. (TEC) Print Date: 7/30/2010 4:34 pm

Client Sample ID: 

### HDMW2253-03-WG-05 SGS Ref. #: 1103364001 Collection Date/Time: 07/08/10 10:05 Receipt Date/Time: 07/09/10 11:30 Project ID: 3354-003 Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch LOQ/CL Units Qualifiers Parameter Result 

### Semivolatile Organic Fuels Department

DL DF
Diesel Range Organics 0.320 U 0.426 mg/L XFC9357 XXX23023 0.160 1 5a Androstane <surr> 83.7 50-150 % XFC9357 XXX23023 1
Batch Information Initial Prep Wt./Vol.: 940 mL Prep Extract Vol.: 1 mL Analytical Batch: XFC9357 Analytical Method: SW8015C Analysis Date/Time: 07/20/10 05:12 Prep Batch: XXX23023 Prep Method: SW3520C Prep Date/Time: 07/13/10 10:10 Container ID:1103364001-K Dilution Factor: 1 Analyst: LCE

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S Group

### The Environmental Company, Inc. (TEC) Print Date: 7/30/2010 4:34 pm

Client Sample ID: 

### HDMW2253-03-WG-05 SGS Ref. #: 1103364001 Collection Date/Time: 07/08/10 10:05 Receipt Date/Time: 07/09/10 11:30 Project ID: 3354-003 Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch LOQ/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

DL DF

1,1,1,2-Tetrachloroethane 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 1,1,1-Trichloroethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,1,2,2-Tetrachloroethane 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 1,1,2-Trichloroethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,1-Dichloroethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,1-Dichloroethene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,1-Dichloropropene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2,3-Trichlorobenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2,3-Trichloropropane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2,4-Trichlorobenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2,4-Trimethylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2-Dibromo-3-chloropropane 1.24 U 2.00 ug/L VMS11383 VXX20930 0.620 1 1,2-Dibromoethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2-Dichlorobenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2-Dichloroethane 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 1,2-Dichloropropane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,3,5-Trimethylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,3-Dichlorobenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,3-Dichloropropane 0.240 U 0.400 ug/L VMS11383 VXX20930 0.120 1 1,4-Dichlorobenzene 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 1-Chlorohexane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 2,2-Dichloropropane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 2-Butanone (MEK) 6.20 U 10.0 ug/L VMS11383 VXX20930 3.10 1 2-Chlorotoluene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 4-Chlorotoluene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 4-Isopropyltoluene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 4-Methyl-2-pentanone (MIBK) 6.20 U 10.0 ug/L VMS11383 VXX20930 3.10 1 Acetone 6.20 U 10.0 ug/L VMS11383 VXX20930 3.10 1 Benzene 0.240 U 0.400 ug/L VMS11383 VXX20930 0.120 1 Bromobenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Bromochloromethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Bromodichloromethane 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 Bromoform 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Bromomethane 1.88 U 3.00 ug/L VMS11383 VXX20930 0.940 1 Carbon tetrachloride 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Chlorobenzene 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S Group

### The Environmental Company, Inc. (TEC) Print Date: 7/30/2010 4:34 pm

Client Sample ID: 

### HDMW2253-03-WG-05 SGS Ref. #: 1103364001 Collection Date/Time: 07/08/10 10:05 Receipt Date/Time: 07/09/10 11:30 Project ID: 3354-003 Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch LOQ/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

DL DF Chloroethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Chloroform 0.600 U 1.00 ug/L VMS11383 VXX20930 0.300 1 Chloromethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 cis-1,2-Dichloroethene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 cis-1,3-Dichloropropene 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 Dibromochloromethane 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 Dibromomethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Dichlorodifluoromethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Ethylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Hexachlorobutadiene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Isopropylbenzene (Cumene) 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Methylene chloride 2.00 U 5.00 ug/L VMS11383 VXX20930 1.00 1 Methyl-t-butyl ether 3.00 U 5.00 ug/L VMS11383 VXX20930 1.50 1 Naphthalene 1.24 U 2.00 ug/L VMS11383 VXX20930 0.620 1 n-Butylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 n-Propylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 o-Xylene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 P & M -Xylene 1.24 U 2.00 ug/L VMS11383 VXX20930 0.620 1 sec-Butylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Styrene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 tert-Butylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Tetrachloroethene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Toluene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 trans-1,2-Dichloroethene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 trans-1,3-Dichloropropene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Trichloroethene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Trichlorofluoromethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Vinyl chloride 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Xylenes (total) 1.88 U 3.00 ug/L VMS11383 VXX20930 0.940 1 1,2-Dichloroethane-D4 <surr> 104 73-120 % VMS11383 VXX20930 1 4-Bromofluorobenzene <surr> 109 76-120 % VMS11383 VXX20930 1 Toluene-d8 <surr> 97 80-120 % VMS11383 VXX20930 1

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S Group

### The Environmental Company, Inc. (TEC) Print Date: 7/30/2010 4:34 pm

Client Sample ID: 

### HDMW2253-03-WG-05 SGS Ref. #: 1103364001 Collection Date/Time: 07/08/10 10:05 Receipt Date/Time: 07/09/10 11:30 Project ID: 3354-003 Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch LOQ/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

DL DF Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VMS11383 Analytical Method: SW8260B Analysis Date/Time: 07/14/10 14:40 Prep Batch: VXX20930 Prep Method: SW5030B Prep Date/Time: 07/13/10 11:31 Container ID:1103364001-A Dilution Factor: 1 Analyst: SCL

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S Group

### The Environmental Company, Inc. (TEC) Print Date: 7/30/2010 4:34 pm

Client Sample ID: 

### HDMW2253-03-WG-05 SGS Ref. #: 1103364001 Collection Date/Time: 07/08/10 10:05 Receipt Date/Time: 07/09/10 11:30 Project ID: 3354-003 Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch LOQ/CL Units Qualifiers Parameter Result 

### Polynuclear Aromatics GC/MS

DL DF
1-Methylnaphthalene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 2-Methylnaphthalene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Acenaphthene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Acenaphthylene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Anthracene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Benzo(a)Anthracene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Benzo[a]pyrene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Benzo[b]Fluoranthene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Benzo[g,h,i]perylene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Benzo[k]fluoranthene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Chrysene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Dibenzo[a,h]anthracene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Fluoranthene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Fluorene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Indeno[1,2,3-c,d] pyrene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Naphthalene 0.0596J 0.116 ug/L XMS5543 XXX23016 0.0360 1 Phenanthrene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Pyrene 0.0348 U 0.0581 ug/L XMS5543 XXX23016 0.0174 1 Terphenyl-d14 <surr> 118 50-135 % XMS5543 XXX23016 1
Batch Information Initial Prep Wt./Vol.: 860 mL Prep Extract Vol.: 1 mL Analytical Batch: XMS5543 Analytical Method: 8270D SIMS Analysis Date/Time: 07/13/10 15:37 Prep Batch: XXX23016 Prep Method: SW3520C Prep Date/Time: 07/12/10 11:00 Container ID:1103364001-H Dilution Factor: 1 Analyst: CDE

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S Group

### The Environmental Company, Inc. (TEC) Print Date: 7/30/2010 4:34 pm

Client Sample ID: 

### TB01-WG-05 SGS Ref. #: 1103364002 Collection Date/Time: 07/08/10 08:05 Receipt Date/Time: 07/09/10 11:30 Project ID: 3354-003 Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch LOQ/CL Units Qualifiers Parameter Result 

### Volatile Fuels Department

DL DF
Gasoline Range Organics 60.0 U 100 ug/L VFC10031 VXX20961 30.0 1 4-Bromofluorobenzene <surr> 103 50-150 % VFC10031 VXX20961 1
Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VFC10031 Analytical Method: SW8015C Analysis Date/Time: 07/20/10 15:48 Prep Batch: VXX20961 Prep Method: SW5030B Prep Date/Time: 07/20/10 12:00 Container ID:1103364002-B Dilution Factor: 1 Analyst: EAB

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S Group

### The Environmental Company, Inc. (TEC) Print Date: 7/30/2010 4:34 pm

Client Sample ID: 

### TB01-WG-05 SGS Ref. #: 1103364002 Collection Date/Time: 07/08/10 08:05 Receipt Date/Time: 07/09/10 11:30 Project ID: 3354-003 Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch LOQ/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

DL DF

1,1,1,2-Tetrachloroethane 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 1,1,1-Trichloroethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,1,2,2-Tetrachloroethane 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 1,1,2-Trichloroethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,1-Dichloroethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,1-Dichloroethene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,1-Dichloropropene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2,3-Trichlorobenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2,3-Trichloropropane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2,4-Trichlorobenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2,4-Trimethylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2-Dibromo-3-chloropropane 1.24 U 2.00 ug/L VMS11383 VXX20930 0.620 1 1,2-Dibromoethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2-Dichlorobenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,2-Dichloroethane 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 1,2-Dichloropropane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,3,5-Trimethylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,3-Dichlorobenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 1,3-Dichloropropane 0.240 U 0.400 ug/L VMS11383 VXX20930 0.120 1 1,4-Dichlorobenzene 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 1-Chlorohexane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 2,2-Dichloropropane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 2-Butanone (MEK) 6.20 U 10.0 ug/L VMS11383 VXX20930 3.10 1 2-Chlorotoluene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 4-Chlorotoluene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 4-Isopropyltoluene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 4-Methyl-2-pentanone (MIBK) 6.20 U 10.0 ug/L VMS11383 VXX20930 3.10 1 Acetone 3.43J 10.0 ug/L VMS11383 VXX20930 3.10 1 Benzene 0.240 U 0.400 ug/L VMS11383 VXX20930 0.120 1 Bromobenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Bromochloromethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Bromodichloromethane 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 Bromoform 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Bromomethane 1.88 U 3.00 ug/L VMS11383 VXX20930 0.940 1 Carbon tetrachloride 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Chlorobenzene 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S Group

### The Environmental Company, Inc. (TEC) Print Date: 7/30/2010 4:34 pm

Client Sample ID: 

### TB01-WG-05 SGS Ref. #: 1103364002 Collection Date/Time: 07/08/10 08:05 Receipt Date/Time: 07/09/10 11:30 Project ID: 3354-003 Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch LOQ/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

DL DF Chloroethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Chloroform 0.600 U 1.00 ug/L VMS11383 VXX20930 0.300 1 Chloromethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 cis-1,2-Dichloroethene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 cis-1,3-Dichloropropene 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 Dibromochloromethane 0.300 U 0.500 ug/L VMS11383 VXX20930 0.150 1 Dibromomethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Dichlorodifluoromethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Ethylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Hexachlorobutadiene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Isopropylbenzene (Cumene) 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Methylene chloride 2.00 U 5.00 ug/L VMS11383 VXX20930 1.00 1 Methyl-t-butyl ether 3.00 U 5.00 ug/L VMS11383 VXX20930 1.50 1 Naphthalene 1.24 U 2.00 ug/L VMS11383 VXX20930 0.620 1 n-Butylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 n-Propylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 o-Xylene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 P & M -Xylene 1.24 U 2.00 ug/L VMS11383 VXX20930 0.620 1 sec-Butylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Styrene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 tert-Butylbenzene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Tetrachloroethene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Toluene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 trans-1,2-Dichloroethene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 trans-1,3-Dichloropropene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Trichloroethene 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Trichlorofluoromethane 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Vinyl chloride 0.620 U 1.00 ug/L VMS11383 VXX20930 0.310 1 Xylenes (total) 1.88 U 3.00 ug/L VMS11383 VXX20930 0.940 1 1,2-Dichloroethane-D4 <surr> 101 73-120 % VMS11383 VXX20930 1 4-Bromofluorobenzene <surr> 107 76-120 % VMS11383 VXX20930 1 Toluene-d8 <surr> 98.6 80-120 % VMS11383 VXX20930 1

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S Group

### The Environmental Company, Inc. (TEC) Print Date: 7/30/2010 4:34 pm

Client Sample ID: 

### TB01-WG-05 SGS Ref. #: 1103364002 Collection Date/Time: 07/08/10 08:05 Receipt Date/Time: 07/09/10 11:30 Project ID: 3354-003 Red Hill BFSF Matrix: Water (Surface, Eff., Ground)

Analytical Batch Prep

Batch LOQ/CL Units Qualifiers Parameter Result 

### Volatile Gas Chromatography/Mass Spectroscopy

DL DF Batch Information Initial Prep Wt./Vol.: 5 mL Prep Extract Vol.: 5 mL Analytical Batch: VMS11383 Analytical Method: SW8260B Analysis Date/Time: 07/14/10 13:47 Prep Batch: VXX20930 Prep Method: SW5030B Prep Date/Time: 07/13/10 11:31 Container ID:1103364002-A Dilution Factor: 1 Analyst: SCL

SGS No rth Am eric a Inc . En vir onm enta l Division 200 W e st Potter D rive Anc hora ge AK 99518 t (907 )562.2343 f ( 907)561 .5301 w ww.us.sgs.com M ember of SG S GroupMatrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 972721 Method Blank The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) XXX23016 SW3520C 07/12/2010 QC results affect the following production samples: 

### 1103364001

Parameter Results LOQ/CL Units Analysis Date DL


### Polynuclear Aromatics GC/MS 

### 1-Methylnaphthalene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 1-Methylnaphthalene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 2-Methylnaphthalene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 2-Methylnaphthalene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Acenaphthene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Acenaphthene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Acenaphthylene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Acenaphthylene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Anthracene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Anthracene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Benzo(a)Anthracene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Benzo(a)Anthracene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Benzo[a]pyrene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Benzo[a]pyrene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Benzo[b]Fluoranthene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Benzo[b]Fluoranthene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Benzo[g,h,i]perylene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Benzo[g,h,i]perylene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Benzo[k]fluoranthene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Benzo[k]fluoranthene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Chrysene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Chrysene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Dibenzo[a,h]anthracene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Dibenzo[a,h]anthracene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Fluoranthene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Fluoranthene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Fluorene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Fluorene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Indeno[1,2,3-c,d] pyrene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Indeno[1,2,3-c,d] pyrene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Naphthalene 0.0620 U 0.100 ug/L 07/13/10 

### 0.0310 Naphthalene 0.0620 U 0.100 ug/L 07/13/10 

### 0.0310 Phenanthrene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Phenanthrene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Pyrene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150 Pyrene 0.0300 U 0.0500 ug/L 07/13/10 

### 0.0150Matrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 972721 Method Blank The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) XXX23016 SW3520C 07/12/2010

Parameter Results LOQ/CL Units Analysis Date DL


### Polynuclear Aromatics GC/MS

Surrogates 

### Terphenyl-d14 <surr> 120 50-135 % 07/13/10 

### Terphenyl-d14 <surr> 114 50-135 % 07/13/10

Instrument Method Batch XMS5543

8270D SIMS HP 6890/5973 MS SVQAMatrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 972948 Method Blank The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) XXX23023 SW3520C 07/13/2010 QC results affect the following production samples: 

### 1103364001

Parameter Results LOQ/CL Units Analysis Date DL


### Semivolatile Organic Fuels Department 

### Diesel Range Organics 0.300 U 0.400 mg/L 07/20/10 

### 0.150 Surrogates


### 5a Androstane <surr> 83.6 60-120 % 07/20/10

Instrument Method Batch XFC9357

SW8015C HP 7890A FID SV E RMatrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 973528 Method Blank The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) VXX20930 SW5030B 07/13/2010 QC results affect the following production samples: 

### 1103364001, 1103364002

Parameter Results LOQ/CL Units Analysis Date DL


### Volatile Gas Chromatography/Mass SpectroscopyMatrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 973528 Method Blank The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) VXX20930 SW5030B 07/13/2010

Parameter Results LOQ/CL Units Analysis Date DL


### Volatile Gas Chromatography/Mass Spectroscopy


### 1,1,1,2-Tetrachloroethane 0.300 U 0.500 ug/L 07/14/10 

### 0.150 1,1,1-Trichloroethane 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,1,2,2-Tetrachloroethane 0.300 U 0.500 ug/L 07/14/10 

### 0.150 1,1,2-Trichloroethane 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,1-Dichloroethane 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,1-Dichloroethene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,1-Dichloropropene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,2,3-Trichlorobenzene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,2,3-Trichloropropane 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,2,4-Trichlorobenzene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,2,4-Trimethylbenzene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,2-Dibromo-3-chloropropane 1.24 U 2.00 ug/L 07/14/10 

### 0.620 1,2-Dibromoethane 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,2-Dichlorobenzene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,2-Dichloroethane 0.300 U 0.500 ug/L 07/14/10 

### 0.150 1,2-Dichloropropane 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,3,5-Trimethylbenzene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,3-Dichlorobenzene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 1,3-Dichloropropane 0.240 U 0.400 ug/L 07/14/10 

### 0.120 1,4-Dichlorobenzene 0.300 U 0.500 ug/L 07/14/10 

### 0.150 1-Chlorohexane 0.620 U 1.00 ug/L 07/14/10 

### 0.310 2,2-Dichloropropane 0.620 U 1.00 ug/L 07/14/10 

### 0.310 2-Butanone (MEK) 6.20 U 10.0 ug/L 07/14/10 

### 3.10 2-Chlorotoluene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 4-Chlorotoluene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 4-Isopropyltoluene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 4-Methyl-2-pentanone (MIBK) 6.20 U 10.0 ug/L 07/14/10 

### 3.10 Acetone 6.20 U 10.0 ug/L 07/14/10 

### 3.10 Benzene 0.240 U 0.400 ug/L 07/14/10 

### 0.120 Bromobenzene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Bromochloromethane 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Bromodichloromethane 0.300 U 0.500 ug/L 07/14/10 

### 0.150 Bromoform 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Bromomethane 1.88 U 3.00 ug/L 07/14/10 

### 0.940 Carbon tetrachloride 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Chlorobenzene 0.300 U 0.500 ug/L 07/14/10 

### 0.150 Chloroethane 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Chloroform 0.600 U 1.00 ug/L 07/14/10 

### 0.300 Chloromethane 0.620 U 1.00 ug/L 07/14/10 

### 0.310Matrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 973528 Method Blank The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) VXX20930 SW5030B 07/13/2010

Parameter Results LOQ/CL Units Analysis Date DL


### Volatile Gas Chromatography/Mass Spectroscopy


### cis-1,2-Dichloroethene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 cis-1,3-Dichloropropene 0.300 U 0.500 ug/L 07/14/10 

### 0.150 Dibromochloromethane 0.300 U 0.500 ug/L 07/14/10 

### 0.150 Dibromomethane 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Dichlorodifluoromethane 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Ethylbenzene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Hexachlorobutadiene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Isopropylbenzene (Cumene) 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Methylene chloride 2.00 U 5.00 ug/L 07/14/10 

### 1.00 Methyl-t-butyl ether 3.00 U 5.00 ug/L 07/14/10 

### 1.50 Naphthalene 1.24 U 2.00 ug/L 07/14/10 

### 0.620 n-Butylbenzene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 n-Propylbenzene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 o-Xylene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 P & M -Xylene 1.24 U 2.00 ug/L 07/14/10 

### 0.620 sec-Butylbenzene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Styrene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 tert-Butylbenzene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Tetrachloroethene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Toluene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 trans-1,2-Dichloroethene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 trans-1,3-Dichloropropene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Trichloroethene 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Trichlorofluoromethane 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Vinyl chloride 0.620 U 1.00 ug/L 07/14/10 

### 0.310 Xylenes (total) 1.88 U 3.00 ug/L 07/14/10 

### 0.940 Surrogates 

### 1,2-Dichloroethane-D4 <surr> 101 73-120 % 07/14/10 

### 4-Bromofluorobenzene <surr> 109 76-120 % 07/14/10 

### Toluene-d8 <surr> 99.7 80-120 % 07/14/10

Instrument Method Batch VMS11383

SW8260B HP 5890 Series II MS1 VJAMatrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 974420 Method Blank The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) MXX23243 SW3010A 07/16/2010 QC results affect the following production samples: 

### 1103364001

Parameter Results LOQ/CL Units Analysis Date DL


### Metals by ICP/MS



### Lead 0.620 U 1.00 ug/L 07/21/10 

### 0.310

Instrument Method Batch MMS6543

SW6020 Perkin Elmer Sciex ICP-MS P3Matrix SGS Ref.# Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 975014 Method Blank The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) VXX20961 SW5030B 07/20/2010 QC results affect the following production samples: 

### 1103364001, 1103364002

Parameter Results LOQ/CL Units Analysis Date DL


### Volatile Fuels Department 

### Gasoline Range Organics 60.0 U 100 ug/L 07/20/10 

### 30.0 Surrogates


### 4-Bromofluorobenzene <surr> 106 50-150 % 07/20/10

Instrument Method Batch VFC10031

SW8015C HP 5890 Series II PID+FID VCAMatrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 972722 Lab Control Sample 972723 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) XXX23016 SW3520C 07/12/2010

QC results affect the following production samples: 

### 1103364001

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Polynuclear Aromatics GC/MS 

### 1-Methylnaphthalene LCS 0.372 74 ( 58-114 ) 0.5 ug/L 07/13/2010 LCSD 0.475 95 24 (< 30 ) 0.5 ug/L 07/13/2010
1-Methylnaphthalene LCS 0.433 87 ( 58-114 ) 0.5 ug/L 07/13/2010 LCSD
2-Methylnaphthalene LCS 0.348 70 ( 54-105 ) 0.5 ug/L 07/13/2010 LCSD 0.408 82 16 (< 30 ) 0.5 ug/L 07/13/2010
2-Methylnaphthalene LCS 0.395 79 ( 54-105 ) 0.5 ug/L 07/13/2010 LCSD
Acenaphthene LCS 0.373 75 ( 57-110 ) 0.5 ug/L 07/13/2010 LCSD
Acenaphthene LCS 0.373 75 ( 57-110 ) 0.5 ug/L 07/13/2010 LCSD 0.395 79 6 (< 30 ) 0.5 ug/L 07/13/2010
Acenaphthylene LCS 0.398 80 ( 58-105 ) 0.5 ug/L 07/13/2010 LCSD
Acenaphthylene LCS 0.385 77 ( 58-105 ) 0.5 ug/L 07/13/2010 LCSD 0.411 82 6 (< 30 ) 0.5 ug/L 07/13/2010

Anthracene LCS 0.375 75 ( 63-120 ) 0.5 ug/L 07/13/2010 LCSD

Anthracene LCS 0.369 74 ( 63-120 ) 0.5 ug/L 07/13/2010 LCSD 0.399 80 8 (< 30 ) 0.5 ug/L 07/13/2010
Benzo(a)Anthracene LCS 0.405 81 ( 61-120 ) 0.5 ug/L 07/13/2010 LCSD 0.455 91 12 (< 30 ) 0.5 ug/L 07/13/2010
Benzo(a)Anthracene LCS 0.456 91 ( 61-120 ) 0.5 ug/L 07/13/2010 LCSD
Benzo[a]pyrene LCS 0.350 70 ( 57-120 ) 0.5 ug/L 07/13/2010 LCSD 0.380 76 8 (< 30 ) 0.5 ug/L 07/13/2010Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 972722 Lab Control Sample 972723 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) XXX23016 SW3520C 07/12/2010

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Polynuclear Aromatics GC/MS 

### Benzo[a]pyrene LCS 0.378 76 ( 57-120 ) 0.5 ug/L 07/13/2010 LCSD
Benzo[b]Fluoranthene LCS 0.404 81 ( 66-130 ) 0.5 ug/L 07/13/2010 LCSD 0.454 91 12 (< 30 ) 0.5 ug/L 07/13/2010
Benzo[b]Fluoranthene LCS 0.447 89 ( 66-130 ) 0.5 ug/L 07/13/2010 LCSD
Benzo[g,h,i]perylene LCS 0.393 79 ( 60-125 ) 0.5 ug/L 07/13/2010 LCSD 0.442 89 12 (< 30 ) 0.5 ug/L 07/13/2010
Benzo[g,h,i]perylene LCS 0.443 89 ( 60-125 ) 0.5 ug/L 07/13/2010 LCSD
Benzo[k]fluoranthene LCS 0.404 81 ( 67-125 ) 0.5 ug/L 07/13/2010 LCSD
Benzo[k]fluoranthene LCS 0.396 79 ( 67-125 ) 0.5 ug/L 07/13/2010 LCSD 0.380 76 4 (< 30 ) 0.5 ug/L 07/13/2010
Chrysene LCS 0.397 79 ( 71-120 ) 0.5 ug/L 07/13/2010 LCSD 0.414 83 4 (< 30 ) 0.5 ug/L 07/13/2010
Chrysene LCS 0.415 83 ( 71-120 ) 0.5 ug/L 07/13/2010 LCSD
Dibenzo[a,h]anthracene LCS 0.387 78 ( 56-125 ) 0.5 ug/L 07/13/2010 LCSD 0.419 84 8 (< 30 ) 0.5 ug/L 07/13/2010
Dibenzo[a,h]anthracene LCS 0.424 85 ( 56-125 ) 0.5 ug/L 07/13/2010 LCSD

Fluoranthene LCS 0.416 83 ( 63-125 ) 0.5 ug/L 07/13/2010 LCSD 0.465 93 11 (< 30 ) 0.5 ug/L 07/13/2010

Fluoranthene LCS 0.454 91 ( 63-125 ) 0.5 ug/L 07/13/2010 LCSD

Fluorene LCS 0.415 83 ( 59-120 ) 0.5 ug/L 07/13/2010 LCSDMatrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 972722 Lab Control Sample 972723 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) XXX23016 SW3520C 07/12/2010

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Polynuclear Aromatics GC/MS



### Fluorene LCS 0.408 82 ( 59-120 ) 0.5 ug/L 07/13/2010 LCSD 0.422 84 4 (< 30 ) 0.5 ug/L 07/13/2010
Indeno[1,2,3-c,d] pyrene LCS 0.393 79 ( 59-125 ) 0.5 ug/L 07/13/2010 LCSD 0.435 87 10 (< 30 ) 0.5 ug/L 07/13/2010
Indeno[1,2,3-c,d] pyrene LCS 0.431 86 ( 59-125 ) 0.5 ug/L 07/13/2010 LCSD
Naphthalene LCS 0.376 75 ( 56-108 ) 0.5 ug/L 07/13/2010

* LCSD 0.546 109 * 37 (< 30 ) 0.5 ug/L 07/13/2010
Naphthalene LCS 0.502 100 ( 56-108 ) 0.5 ug/L 07/13/2010 LCSD

Phenanthrene LCS 0.412 83 ( 60-115 ) 0.5 ug/L 07/13/2010 LCSD 0.457 91 10 (< 30 ) 0.5 ug/L 07/13/2010

Phenanthrene LCS 0.427 85 ( 60-115 ) 0.5 ug/L 07/13/2010 LCSD
Pyrene LCS 0.380 76 ( 62-130 ) 0.5 ug/L 07/13/2010 LCSD 0.400 80 5 (< 30 ) 0.5 ug/L 07/13/2010
Pyrene LCS 0.391 78 ( 62-130 ) 0.5 ug/L 07/13/2010 LCSD

Surrogates 

### Terphenyl-d14 <surr> LCS 115 ( 50-135 ) 07/13/2010 LCSD 105 9 07/13/2010
Terphenyl-d14 <surr> LCS 109 ( 50-135 ) 07/13/2010 LCSD

Batch Method Instrument 

### XMS5543

8270D SIMS HP 6890/5973 MS SVQAMatrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 972950 Lab Control Sample 972952 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) XXX23023 SW3520C 07/13/2010

QC results affect the following production samples: 

### 1103364001

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Semivolatile Organic Fuels Department 

### Diesel Range Organics LCS 4.60 92 ( 75-125 ) 5 mg/L 07/20/2010 LCSD 4.80 96 4 (< 20 ) 5 mg/L 07/20/2010

Surrogates 

### 5a Androstane <surr> LCS 86 ( 60-120 ) 07/20/2010 LCSD 88 3 07/20/2010

Batch Method Instrument 

### XFC9357

SW8015C HP 7890A FID SV E RMatrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 973529 Lab Control Sample 973530 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) VXX20930 SW5030B 07/13/2010

QC results affect the following production samples: 

### 1103364001, 1103364002

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass SpectroscopyMatrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 973529 Lab Control Sample 973530 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) VXX20930 SW5030B 07/13/2010

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass Spectroscopy 

### 1,1,1,2-Tetrachloroethane LCS 30.1 100 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 29.2 97 3 (< 20 ) 30 ug/L 07/14/2010
1,1,1-Trichloroethane LCS 30.7 102 ( 80-122 ) 30 ug/L 07/14/2010 LCSD 31.3 104 2 (< 20 ) 30 ug/L 07/14/2010
1,1,2,2-Tetrachloroethane LCS 31.7 106 ( 76-123 ) 30 ug/L 07/14/2010 LCSD 31.3 104 1 (< 20 ) 30 ug/L 07/14/2010
1,1,2-Trichloroethane LCS 33.5 112 ( 77-120 ) 30 ug/L 07/14/2010 LCSD 31.2 104 7 (< 20 ) 30 ug/L 07/14/2010
1,1-Dichloroethane LCS 29.6 99 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 30.5 102 3 (< 20 ) 30 ug/L 07/14/2010
1,1-Dichloroethene LCS 27.8 93 ( 76-130 ) 30 ug/L 07/14/2010 LCSD 28.6 96 3 (< 20 ) 30 ug/L 07/14/2010
1,1-Dichloropropene LCS 30.4 101 ( 80-122 ) 30 ug/L 07/14/2010 LCSD 30.5 102 0 (< 20 ) 30 ug/L 07/14/2010
1,2,3-Trichlorobenzene LCS 30.9 103 ( 77-120 ) 30 ug/L 07/14/2010 LCSD 31.1 104 1 (< 20 ) 30 ug/L 07/14/2010
1,2,3-Trichloropropane LCS 31.9 106 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 32.1 107 1 (< 20 ) 30 ug/L 07/14/2010
1,2,4-Trichlorobenzene LCS 33.6 112 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 34.0 113 1 (< 20 ) 30 ug/L 07/14/2010
1,2,4-Trimethylbenzene LCS 31.6 105 ( 80-125 ) 30 ug/L 07/14/2010 LCSD 31.5 105 0 (< 20 ) 30 ug/L 07/14/2010
1,2-Dibromo-3-chloropropane LCS 32.9 110 ( 73-130 ) 30 ug/L 07/14/2010 LCSD 34.0 113 3 (< 20 ) 30 ug/L 07/14/2010
1,2-Dibromoethane LCS 32.3 108 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 31.6 105 2 (< 20 ) 30 ug/L 07/14/2010
1,2-Dichlorobenzene LCS 30.8 103 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 30.4 101 1 (< 20 ) 30 ug/L 07/14/2010Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 973529 Lab Control Sample 973530 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) VXX20930 SW5030B 07/13/2010

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass Spectroscopy



### 1,2-Dichloroethane LCS 29.8 99 ( 80-129 ) 30 ug/L 07/14/2010 LCSD 30.6 102 3 (< 20 ) 30 ug/L 07/14/2010
1,2-Dichloropropane LCS 30.7 102 ( 80-121 ) 30 ug/L 07/14/2010 LCSD 31.7 106 3 (< 20 ) 30 ug/L 07/14/2010
1,3,5-Trimethylbenzene LCS 31.7 106 ( 80-128 ) 30 ug/L 07/14/2010 LCSD 31.1 104 2 (< 20 ) 30 ug/L 07/14/2010
1,3-Dichlorobenzene LCS 30.7 102 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 30.2 101 2 (< 20 ) 30 ug/L 07/14/2010
1,3-Dichloropropane LCS 32.4 108 ( 80-121 ) 30 ug/L 07/14/2010 LCSD 31.1 104 4 (< 20 ) 30 ug/L 07/14/2010
1,4-Dichlorobenzene LCS 31.0 103 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 31.0 103 0 (< 20 ) 30 ug/L 07/14/2010

1-Chlorohexane LCS 50.4 112 ( 70-125 ) 45 ug/L 07/14/2010 LCSD 47.0 104 7 (< 20 ) 45 ug/L 07/14/2010
2,2-Dichloropropane LCS 34.0 113 ( 80-132 ) 30 ug/L 07/14/2010 LCSD 34.5 115 1 (< 20 ) 30 ug/L 07/14/2010
2-Butanone (MEK) LCS 108 120 ( 66-136 ) 90 ug/L 07/14/2010 LCSD 121 135 12 (< 20 ) 90 ug/L 07/14/2010

2-Chlorotoluene LCS 30.6 102 ( 80-125 ) 30 ug/L 07/14/2010 LCSD 30.5 102 0 (< 20 ) 30 ug/L 07/14/2010

4-Chlorotoluene LCS 31.2 104 ( 79-128 ) 30 ug/L 07/14/2010 LCSD 30.9 103 1 (< 20 ) 30 ug/L 07/14/2010
4-Isopropyltoluene LCS 31.5 105 ( 80-125 ) 30 ug/L 07/14/2010 LCSD 31.3 104 1 (< 20 ) 30 ug/L 07/14/2010
4-Methyl-2-pentanone (MIBK) LCS 92.1 102 ( 69-134 ) 90 ug/L 07/14/2010 LCSD 95.8 106 4 (< 20 ) 90 ug/L 07/14/2010

Acetone LCS 136 151 ( 50-135 ) * 90 ug/L 07/14/2010Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 973529 Lab Control Sample 973530 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) VXX20930 SW5030B 07/13/2010

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass Spectroscopy



### * LCSD 167 186 * 21 (< 20 ) 90 ug/L 07/14/2010

Benzene LCS 29.3 98 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 29.7 99 1 (< 20 ) 30 ug/L 07/14/2010

Bromobenzene LCS 30.7 102 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 29.6 99 4 (< 20 ) 30 ug/L 07/14/2010

Bromochloromethane LCS 28.7 96 ( 77-129 ) 30 ug/L 07/14/2010 LCSD 30.2 101 5 (< 20 ) 30 ug/L 07/14/2010

Bromodichloromethane LCS 29.7 99 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 30.6 102 3 (< 20 ) 30 ug/L 07/14/2010

Bromoform LCS 30.9 103 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 29.8 99 4 (< 20 ) 30 ug/L 07/14/2010

Bromomethane LCS 27.1 90 ( 30-140 ) 30 ug/L 07/14/2010 LCSD 29.7 99 9 (< 20 ) 30 ug/L 07/14/2010

Carbon tetrachloride LCS 30.1 100 ( 80-126 ) 30 ug/L 07/14/2010 LCSD 30.2 101 0 (< 20 ) 30 ug/L 07/14/2010

Chlorobenzene LCS 31.0 103 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 29.5 98 5 (< 20 ) 30 ug/L 07/14/2010

Chloroethane LCS 33.3 111 ( 67-133 ) 30 ug/L 07/14/2010 LCSD 32.0 107 4 (< 20 ) 30 ug/L 07/14/2010

Chloroform LCS 29.0 97 ( 80-124 ) 30 ug/L 07/14/2010 LCSD 29.7 99 2 (< 20 ) 30 ug/L 07/14/2010

Chloromethane LCS 30.6 102 ( 67-125 ) 30 ug/L 07/14/2010 LCSD 32.4 108 6 (< 20 ) 30 ug/L 07/14/2010
cis-1,2-Dichloroethene LCS 28.2 94 ( 80-125 ) 30 ug/L 07/14/2010 LCSD 29.4 98 4 (< 20 ) 30 ug/L 07/14/2010
cis-1,3-Dichloropropene LCS 31.2 104 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 32.2 107 3 (< 20 ) 30 ug/L 07/14/2010Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 973529 Lab Control Sample 973530 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) VXX20930 SW5030B 07/13/2010

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass Spectroscopy


### Dibromochloromethane LCS 31.0 103 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 30.2 101 3 (< 20 ) 30 ug/L 07/14/2010

Dibromomethane LCS 28.7 96 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 29.8 99 4 (< 20 ) 30 ug/L 07/14/2010

Dichlorodifluoromethane LCS 30.4 101 ( 62-153 ) 30 ug/L 07/14/2010 LCSD 30.9 103 2 (< 20 ) 30 ug/L 07/14/2010
Ethylbenzene LCS 31.8 106 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 30.0 100 6 (< 20 ) 30 ug/L 07/14/2010

Hexachlorobutadiene LCS 32.2 107 ( 77-125 ) 30 ug/L 07/14/2010 LCSD 31.9 106 1 (< 20 ) 30 ug/L 07/14/2010
Isopropylbenzene (Cumene) LCS 32.1 107 ( 80-121 ) 30 ug/L 07/14/2010 LCSD 30.5 102 5 (< 20 ) 30 ug/L 07/14/2010
Methylene chloride LCS 29.2 97 ( 63-131 ) 30 ug/L 07/14/2010 LCSD 30.6 102 5 (< 20 ) 30 ug/L 07/14/2010
Methyl-t-butyl ether LCS 45.0 100 ( 80-120 ) 45 ug/L 07/14/2010 LCSD 46.9 104 4 (< 20 ) 45 ug/L 07/14/2010
Naphthalene LCS 31.5 105 ( 75-120 ) 30 ug/L 07/14/2010 LCSD 31.2 104 1 (< 20 ) 30 ug/L 07/14/2010
n-Butylbenzene LCS 33.1 110 ( 80-124 ) 30 ug/L 07/14/2010 LCSD 32.7 109 1 (< 20 ) 30 ug/L 07/14/2010
n-Propylbenzene LCS 31.6 105 ( 80-129 ) 30 ug/L 07/14/2010 LCSD 31.2 104 1 (< 20 ) 30 ug/L 07/14/2010
o-Xylene LCS 31.6 105 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 30.1 100 5 (< 20 ) 30 ug/L 07/14/2010
P & M -Xylene LCS 62.9 105 ( 80-120 ) 60 ug/L 07/14/2010 LCSD 60.1 100 5 (< 20 ) 60 ug/L 07/14/2010
sec-Butylbenzene LCS 31.7 106 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 31.3 104 1 (< 20 ) 30 ug/L 07/14/2010Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 973529 Lab Control Sample 973530 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) VXX20930 SW5030B 07/13/2010

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass Spectroscopy



### Styrene LCS 32.7 109 ( 80-120 ) 30 ug/L 07/14/2010 LCSD 30.9 103 6 (< 20 ) 30 ug/L 07/14/2010
tert-Butylbenzene LCS 31.3 104 ( 80-122 ) 30 ug/L 07/14/2010 LCSD 30.7 102 2 (< 20 ) 30 ug/L 07/14/2010

Tetrachloroethene LCS 30.8 103 ( 79-122 ) 30 ug/L 07/14/2010 LCSD 29.2 98 5 (< 20 ) 30 ug/L 07/14/2010

Toluene LCS 30.4 101 ( 77-120 ) 30 ug/L 07/14/2010 LCSD 29.2 97 4 (< 20 ) 30 ug/L 07/14/2010
trans-1,2-Dichloroethene LCS 28.1 94 ( 79-132 ) 30 ug/L 07/14/2010 LCSD 28.6 95 2 (< 20 ) 30 ug/L 07/14/2010
trans-1,3-Dichloropropene LCS 33.8 113 ( 80-124 ) 30 ug/L 07/14/2010 LCSD 33.2 111 2 (< 20 ) 30 ug/L 07/14/2010

Trichloroethene LCS 30.2 101 ( 80-125 ) 30 ug/L 07/14/2010 LCSD 30.8 103 2 (< 20 ) 30 ug/L 07/14/2010

Trichlorofluoromethane LCS 30.1 100 ( 68-145 ) 30 ug/L 07/14/2010 LCSD 30.9 103 3 (< 20 ) 30 ug/L 07/14/2010
Vinyl chloride LCS 28.5 95 ( 72-145 ) 30 ug/L 07/14/2010 LCSD 30.5 102 7 (< 20 ) 30 ug/L 07/14/2010
Xylenes (total) LCS 94.5 105 ( 80-120 ) 90 ug/L 07/14/2010 LCSD 90.1 100 5 (< 20 ) 90 ug/L 07/14/2010

Surrogates 

### 1,2-Dichloroethane-D4 <surr> LCS 98 ( 73-120 ) 07/14/2010 LCSD 102 3 07/14/2010

4-Bromofluorobenzene <surr> LCS 101 ( 76-120 ) 07/14/2010 LCSD 102 0 07/14/2010

Toluene-d8 <surr> LCS 101 ( 80-120 ) 07/14/2010 LCSD 98 3 07/14/2010Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 973529 Lab Control Sample 973530 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) VXX20930 SW5030B 07/13/2010

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Gas Chromatography/Mass Spectroscopy

Batch Method Instrument 

### VMS11383

SW8260B HP 5890 Series II MS1 VJAMatrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 974421 Lab Control Sample
The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) MXX23243 SW3010A 07/16/2010

QC results affect the following production samples: 

### 1103364001

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Metals by ICP/MS


### Lead LCS 1030 103 ( 80-120 ) 1000 ug/L 07/21/2010

Batch Method Instrument 

### MMS6543

SW6020 Perkin Elmer Sciex ICP-MS P3Matrix SGS Ref.#

Client Name Project Name/# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Prep 

### 975015 Lab Control Sample 975016 Lab Control Sample Duplicate The Environmental Company, Inc. (TEC) 3354-003 Red Hill BFSF Water (Surface, Eff., Ground) VXX20961 SW5030B 07/20/2010

QC results affect the following production samples: 

### 1103364001, 1103364002

Parameter QC Results Pct

Recov Spiked Amount Analysis

Date RPD LCS/LCSD Limits RPD Limits


### Volatile Fuels Department 

### Gasoline Range Organics LCS 200 100 ( 80-116 ) 200 ug/L 07/20/2010 LCSD 193 96 4 (< 20 ) 200 ug/L 07/20/2010

Surrogates 

### 4-Bromofluorobenzene <surr> LCS 110 ( 50-150 ) 07/20/2010 LCSD 105 5 07/20/2010

Batch Method Instrument 

### VFC10031

SW8015C HP 5890 Series II PID+FID VCAMatrix SGS Ref.# Printed Date/Time 

### 07/30/2010 16:34 Batch Method Date Original Prep



### 974422 Matrix Spike 974423 Matrix Spike Duplicate

1103478004 Water (Surface, Eff., Ground) MXX23243 3010 H20 Digest for Metals ICP-MS 07/16/2010

QC results affect the following production samples: 

### 1103364001

Parameter QC Result Pct

Recov Spiked Amount Analysis

Date MS/MSD Limits RPD RPD Limits Original Result Qualifiers


### Metals by ICP/MS


### Lead MS (0.620) U 1040 104 ( 80-120 ) 1000 ug/L 07/21/2010 MSD 1020 102 1 (< 15 ) 1000 ug/L 07/21/2010
Batch Method Instrument 

### MMS6543

SW6020 Perkin Elmer Sciex ICP-MS P3