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# OAR Box 1384 Prepped by Charmelle Mathews



### Document

Number: 

# 92 ) ll-E-5 2 Docket Number: 

# A-94-5 2

Printed 7/2/2008 8:42:06

AM Sheet 92 of 264DEC - 9-9 6 HON 13:5 8 CAHE O MARBLE FA XNO , 1 80 0 94 4 523 6 

### 770T P. 2 

# t 12/08/9 6 10:0 1 01918941023 4 PB S RT P N C 12002/00 2

ContactReport 

## ll-E-52

From : Date : Contact : Company ; Melanie Procter , Pacific Environmen

l Octobe r30,199 6 Mr . Marvi n Shor t Came o Marbl e Telephon e Number : (812 ) 944-505 5
Contac tSummaiy : _»d00Bd^A^ : ^dd^A;d ;

:V.

. EPAAIRDOCKg T v

Mr. Shor twas contacte

d t o verif y theconten

to f hazardou s ai rpollutant

s (HAP) i n th e resins use d b y Came

o Marble . Mr . Shor texplaine d tha tCame o Marbl e use s onl y one resin , whic h contains 2 9 percen

tstyren e by *»eigh

tan d no othe rHA Pmonomer

. Afterreceivin g th

e resi n from th

esuppUer , Came o Marbl e doe s no tad d an y additiona

l HA Pt o theresin . Th e 1993 industr

y surve y indicate d dia tCame o Marbl e use s ha twax in -thei

rpolyme r castin g process . Mr

. Shor texplaine d tha tthis wa xdoes notserv

e as avaporsuppressant

, bu ti ti s use d as amol d release agen t Whe n auke d abou tCameo' s mixin g process , Mr . Shor tindicate d tha tmixin g fo rth e polyme rcastin g proces s i s don e i nope n containers . INFORMATIO

N I S ACCURAT

E



# - 

# See gA/cLtseD



# I

### DEC - 9-9 6 HON

13:5 9

• 

### i CAME O HARBL E FA X NO

. 1 80 0 94 4 b^3 6 T7 W P. 3

W E DO INDEE D US E ONL Y ON E RESI N A

T ATIM E FO R OU R PRODUCTIO N PROCESS

. I N 199 3 WHE N W E COMPLETE D TH E SURVE Y W E USE D 32113-00-0 0 RESIN

. W E HA D PRODUCTIO N PROBLEM S WIT H THI S RESIN

. W E HAV E REMAINE D WIT H TH E SAM E MANUFACTURE R O F RESIN , BU T W E HAV E SWITCHE D SEVERA L TIME S TRYIN G T O CORRECT VARIOU S PRODUCTIO N PROBLEMS

. W E HAV E USE D 32144-2 5 AN D 32-130-3 7 RESI N SINC E 1993

. W E PRESENTL Y US E 32144-28

. A S YO U CA N SE E TH E PRESEN T STYREN E CONTEN T I S 30%

. I DON T HAV E TH E MSD S O N TH E 199 3 RESI N AS W E HAV E REPLACE D I T WIT H ANEWE R MSD S EAC H TIM E W E SWITCH
ENCLOSE D AR E THRE E MSD S FO R TH E OTHE R RESINS , INCLUDIN G TH E ON E W E PRESENTL Y US E 32144-28

. MARVI N



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### DEC - 9-9 6 HO

N 13:5 9 CAHEO HARBL E FA XNO . 1 80 0 94 4 523 B OS " P. 4

MATERIAL SAFET YDAT A SHEE T Informatio nTelephon e No . (800 ) 275-635 3 Reichhol d Chemicals , Inc . P.O . Bo x1358 2 AL L CHEMICAL EMERGENCIE S Researc hTriangl e Park , N C 2770 9 1-800-424-930 0 Issu e Date t 03-28-9 6 [ ! Pag e T ••sssaus:aaaesMai(tssa»t:saMi83BBnM3MHHlNmiuMSSSsi»«sssaaBsssssa i SECTIO N I - PRODUC T IDENTIFICATION MSD S Number : S002227 6 Trad e Name : POLYLITE(R ) 32144-2 5 Produc t Class xUnsaturate d Polyeste r C.A.S . Number : Mixtur e HKI S Rating : Healt h• 2 * Fir e * 3 Reactivit y * 1 s:saaBSSsaDSS&aiBSSaaBBSBSSa«::saBiBSsaaBBSsaaBeS!3aassssaBDBS=saaBSSsaacss:ss a SECTIO N I I - INGREDIENT S

^ - a -«BBBBBBBBBBBMv>«-^BBBBBBBBBBBBnM_^K^^BBBBBBBBBBBBB^__^^«^^nBBBBB. v _^^^^^^BBBBBB_^naBBBBBBBa«BBBBBaM^^BBBBaBBBBBBBBBBh_ IBBBBBBBB* - I—^BBaBB«BBBBBBBBh_ v B l Maximu m Exposur e Ingredient s CA S # Conten t Limit s Polyeste r resi nProprietary 70. 0 % Non e assigne d Styren e Monome r 100-42- 5 28. 5 % 50. 0 pp m alpha-Methy l styren e 98-63- 5 1. 5 % 50. 0 pp m assssaBesssaESSBSBesBBaaasssssaBSSSaBBBBSaaflBSBaaaBSSSSaaBSSSaBaBBSBsaaBSSS : SECTIO N II I - PHYSICAL DAT A Boilin g Point : 29 5 Deg . F . - Vapo r Density : Heavie r tha nAir . Volatil e % : 2 8 - 3 2 Specifi c Grav : 1.1 2 - 1.1 8 Evap . Rate : Slowe r tha nn-Buty l Acetate . Appearance : Clear , blu e liquid . Pungen t odor .

SECTION I V - FIR E AN D EXPLOSION HAZAR D DAT A

^BBBBBBBBB*..—•^^^BBBBBBBBB^—^^^BBBBBBBB^—.—^^BBBBBBBBBBBBBBBB^—^^^^^^BBBBBBBa^*TM^^^BBBBBBBBBBBB»^.»^^BBBBBBBBB«BBBB^^BBBBB B Flammabilit y

Class : I C Flas hPoint : 8 9 Deg . F . LE L : 1. 1 -EXTINGUISHIN

GMEDIA : Wate r spray , foam , dr y chemical , carbo ndioxid e o r an y Clas s B extinguishin g agent . -SPECIA L FIREFIGHTINGPROCEDURES : Firefighter s an d other s expose d t o vapor s o r product s o f combustio nshoul d wea r self-containe d breathin g apparatus . Equipmen t shoul d b e thoroughl y decontaminate d afte r use . -UNUSUA L FIR E 6 EXPLOSIO N

HAZARDS : A t elevate d temperatures , suc ha s i na fire , polymerizatio n ma y tak e place . I f polymerizatio ntake s plac e i na close d container , ther e i s the possibilit y o f violen t ruptur e o f th e container . Produc t vapor s na y fonna nexplosiv e mixtur e i nair .

sectio n2 o f 6 pag e 1



# 3a
J DEC
- 9-9 6 HO

N 14:0 0

• > - 

### REICHHOL D CAMEO MARBL E FA X NO

. 1 80 0 94 4 523 6 P

. 0 6 

# MATERIA L SAFET

Y DAT A SHEE T
REICHHOLD CHEMICALS. INC . P.O . Bo x 13138 2 AL L CHEMICA L EMERGENCIE S Raaearch Triangle Park

, N C 27709-358 2 . on n ^o < qon n
Issu e Date : 08/23/9 3 Page 1 8ECTI0 N I — PRODUC T IDENTIFICATIO N Produc t Code : Trade.Name » Produc t Class : C.A.S . Number : Hni 3 Rating : 

### 32-130-3 7

POLYLITE(R ) 32-130-3 7 Unsaturate d Polyeste r Mixtur e Healt h- 2 « Fir e • 3 Reactivity • 1

- INGREDIENT S SECTIO N I I Ingredient s CA8 « Maximu m Conten t Exposur e Liait s Polyeste r resi n 8tyren e Monome r Proprietar y 74. 0 X Non e assigned 100-42- 5 32. 0 X 50. 0 pp m 6ECTI0 N II I - PHYSICA

L DAT A Boilin g Point : 29 5 Deg . F . Volatil e X

i Evap . Rate : Appearance : Vapor Density : Heavie r tha nAi r 26-3 0 Specifi c Cr*v* 1.1 0 - 1.2 0 Slowe r tha

nn-Butyl Acetate . < • Purpl e clear liquid . Pungent odor . SECTIO N X V - FIR E AN D EXPLOSIO

N HAZAR D DAT A Flas hPoint : 8 9 Deg . F . 

### LE L 1. 1 Flammabilit

y Class : ic -EXTINGUISHIN

G MEDIA : Wate r spray , foam

* dr y chemical , carbo

ndioxide o

r an y Clas s B extinguishin g agent . -SPECIA L FIREFIGHTIN

G PROCEDURES : Firefighter s an

d other s expose

d t o vapor s or product s of combustio

nshoul d wear self-containe d breathin

g apparatus . Equipmen t shoul d be thoroughl y decontaminated after use . -UNUSUA L FIR E 4 EXPLOSIO

N HAZARDS : A t elevated temperatures , suc ha s i n a fire , polymerization ma y take place . I f polymerizatio n take s plac e i

n a closed container , ther e l s th e possibilit

y of violent ruptur e o f th e container . Produc t vapor s ma y fora a n explosiv

e mixtur e l nair . SECTIO N V - HEALTH HAZAR

D DAT A -PERMISSIBL E EXPOSUR E LEVEL : OSH A PE L an

d ACGI H TL

V fo r styren

e ar e bot hSO pp

a fo r a n 8-hou r Tim e Weighted Averag e (TWA) . Th e OSH A an d ACGI H Shor t Ter

m (cont. )

H-ii i informatio n i t furnishe d withou t Warranty , representation inducement , o r licem s ot an y kind . eacep t tha i i t j * accurat e t o th e best o l Aoich'iol d Chemicals . Inc * knowledge , o r obtaine d fro m source s believe d b y fleielihold Chemicals . Inc . t a b a accurate , an d Reichhol d Chemicals . Inc . doe e no t assum e an y lega l r«*ponsibilii y lo r us e o r relianc e upo n same . Customer s ar e encourage d u

> conduc t thei r ow n lasts . Before usin g an y product , ree d it s labol . 

# V

# iHwrm—ess TM mwrrnrnTM^. ^ 7

MATERIA

L 

### SAran^DAn^sffiE T P. 6

Informatio

n Telephone MO . (800 ) 275-635 3 Reichhol d Chemicals , Inc . . P.O . Bo x1358 2 AL L CHEMICA L EMERGENCIE S ResearchTriangl e Park , N C 2770 9 1-800-424-930 0 issu e Date s 05-30-9 6 - Pag e I
• ••»•»«• • wwBiai«»BiBr«r«ai«aiaiaiBi««B»BiaiBi«iaiBiBi«Biw«»«»««a,«»«iar«Bi«»»Bi«Bi«Bi«WBi»ww»«Biai«m« . aeaaas a SECTIO N X- PRODUC T IDENTIFICATIO N MSD S Number i S002299 6 Trad e Kama i POLYLITE(R ) 32144-2 8 •••*' . j Produc t Class t Unsaturate d Polyeste r • C.A.S . Numbe n Mixtur e

. HKI S Rating : Healt h- 2 * Fir e • 3 Reactivit y • 1 araiBiBiaiB i «•».••»**•.( •WB< H era —var a •• •BJ* Wsa wVS M « •MM BaaaaaaBBa a •••*«••••• •a t • « ••(••< « apa* . SECTIO N I X . • INGREDIENT S ——»—BBBB—B— -——m — — I . —^>^——»^——w—B —

. Maxiau a. Exposur e . • Ingredient s . CA S #Conten tLiait s Polyeste rresi n Proprietar y 70. 0 % Non e assigne d Styren e Monoae-t

f 100-42- 5 30. 0 % 50. 0 pp a

SECTION . IZ X - PHYSICA

L DAT A

•SaBBBBBBBBBBBBBeeeeeaejBBBBBBBBBBBBBBBiBBBBBlBBBBBBBBBBBB a. , •^BBBBBB < BBBBB»aBBBBWBBBBBBBBB»BBB,^^MBB»BBBBBBBBBBBBBB > W ^,,,,B^,,,, M ^,^^^.^ M i^^^ M ^ M i ^ M , , . —, «____.. —,_.•••• • —______ Boilin g Point : 29 5 Deg . P . Vapo r Density » Heavie r than Air . Volatil e %».. . 2 8 - 3 2 by weight . . Specifi c Qcav i 1.1 2 - 1.1 8 Evap . Rata : , Slowe r than n-Buty l Acetate . .. . Appearance : Blue , dea r liquid . Pungen t odor . SECTIO N X V - FIR E AN

D EXPLOSIO

N HAZARD DATA Plaamability

Class t I C Plas hPoint i 8 9 Deg . 7 . , LE L t 1. 1 rEESIXfODXSHZM

B MEDIA :

. Mate r spray , foam , dr y chemical , carbo

n dioxid e o r an

y Clas s B extinguishing agent . -SPECIA L PIREPIGHTTN

G PROCEDURES : Firefighter s and other s expose d t o vapors , o r product s o f coabustion shoul d wea r self-contained breathin g apparatus . Equipmen t shoul d b e thoroughl y decontaminated afte r use . -ONOSUA L PIR E 6 EXPLOSIO

N HAZARD S * A t elevate d temperatures , suc ha s l n a fire , polymerization aa y tak e place . I f polymerization take s pise s i n a close d container , ther e i s th e possibilit y o f violen t ruptur e o f the container . Produc t vapor s aa y for m a n explosiv

e mixtur e i n Sir . SECTIO N V - HEALT H HAZARD DATA -PERMISSIBLE EXPOSUR E LEVEL : Ther e i s n o OSH

A PE L o r ACGI H TL

V established for th e polyeste r resi n i n thi s product . OSH A PE L and ACGI H TL

V for styren e ar e bot h5 0 pp a for . a n 8-hou r (cont. )



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