# I! ' -0 4 7 

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M mutual materials co.

605 • 119TH NORTHEAST POST OFFICE BOX 2009 BELLEVUE, WASHINGTON 98009 PHONE(206)455•2869 

### March 3, 1998 Mr. Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, NC 27711
Enclosed please find three (3) Information Request forms for brick and structural clay products manufacturing facilities operated by Mutual Materials Company. 1- Newcastle Brick Plant Facility 2- Mica Brick Plant Facility 3- Columbia Brick Plant Facility We chose to use Form 2, the form developed specifically for the brick and structural clay products industry. If you have any questions or require additional information please call or write. Respectfully submitted,

George A. Beamer Mutual Materials Company (509)-924-2120



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# e+'+ mutual materials co.

605 -119TH NORTHEAST POST OFFICE BOX 2009 BELLEVUE, WASHINGTON 98009 PHONE(206)455•2869 

### March 3, 1998 Mr. Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, NC 27711 The following Information Collection Request form is submitted for the Newcastle Brick Plant Facility, operated by Mutual Materials Company, in Renton, Washington. The report contains the following items: A- Form 2, Information Collection Request (28 pages). B- Portions of the Air Operating Permit Application . including results of a kiln stack emissions test. C- Laboratory analysis of clays and brick products. D- Sample pallet tag labeling. E- MSDS for Mutual fired clay brick products. F- MSDS for raw materials used in manufacturing processes. If you have any questions or require additional information please call or write. RespectPully submitted,

George A. Beamer Mutual Materials Company (509)-924-2120

-pi

### < < 3 Enclosure 2

--- ---- NOT SUBJcCT TO TUE RE3

~ i'REMENTS OF II SECTION 3507, PAPER'iIORK RED'JCTIOt: ACT , OF 19d0. 

## INFORMATION REQUEST FOR BRICK AND STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS Instructions Please return the completed information request to: Bruce C. Jordan, Director Attn: Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at (919) 541-5435. 

## This information request should be completed for each facility that manufactures brick and structural clay products, including facilities that are not major sources. Information is requested for all processes at your plant that emit hazardous air pollutants (HAP's), including those processes that are not associated with brick and structural clay products manufacturing. Sections II through VII request information specific to brick and structural clay products manufacturing, and Section VIII requests information on emissions of HAP's from other processes located at the facility. Processes that may emit HAP's include those processes that use or handle any materials that.contain a HAP compound, all processes with elevated temperatures, and all other processes in which HAP compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this information request. Attachment 2 provides background information on the requirements of the Clean Air Act and explains how the information requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations and acronyms used in this information request. Several tables are provided throughout the information request for your convenience in answering the questions. An example response is given (shaded first column or row) in each table. If additional space is needed to respond, please make copies of applicable pages. If necessary, please make copies of this information request for additional facilities. No additional emission testing or monitoring is required to respond to this request. lI. General Facility Information A. Name of compan Name of facility

Page 1 of 28 

# .3

## Facility address: No. and street City State -&4_ Zip SS Latitude and longitude coordinates of plant: 

## ( , Ar

- '47 ° 3 2 ! /y 

## C.ENGStandard Industrial Classification (SIC) Code(s) of brick and structural clay products manufacturing operations 

## -3 Z5'1 Dun and Bradstreet No. 

# 929 Z'44'S 7 7 ± Total No. of employees for comp an 

## y -S CQ 

## for facili t y 

## 50 (If facility is a foreign subsidiary or if company has foreign subsidiaries, include number of employees not based in the U.S.). ~ 

## Please complete the following shift information for the facility: Shift No. of employees Hours per shift Days per year 

# 1 '- 

# ~ f ! 2 

# 100260 I@ 

# F- 3 i 8 3(0s B. Respondent name 

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## JiEV966 ' 6eAwC, Respondent title 

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## $ d71 Eeg:Mf?, Respondent address (if different from above) and telephone number: No. and street 

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# Z-1 L0 Name and telephone number of technical contact person (if different from above) Name 

## ~J1`~l~-~ Telephone No. (_) 

## 540C III. 

## Information on Operating Permits and Applicable Federal Emission Standards A. Please provide copies of relevant parts of all operating permits and permit applications for your facility. Relevant parts include the sections that providespecific information and data on: processes that emit HAP's; the use of HAPcontaining substances; emission levels for HAP and surrogate pollutants (i.e., VOC Page 2 of 28 

## (7-1

## for organic HAP's and PM for metal and other particulate HAP's); emission control device design and operation; monitoring and operation and maintenance (O&M) procedures for control devices; and generation and releases of other media such as wastewater and solid waste that are associated with the operation of air pollution controls for brick and structural clay products manufacturing processes. If the operating permit or application contains the same information requested in any part of this questionnaire, you may respond to the requested information by referencing the page or section of the permit/application to avoid duplication. If you reference your permit or application, you must supplement your response with all of the additional information requested in this questionnaire that is not included in the permit or permit application. If you prefer, you may submit the requested information from your permit/application on a 3- 1 /x inch diskette. B. If any source or emission unit at this facility is subject to a New Source Performance Standard or other Federal emission standard, please identify the source and applicable standard. Examples of applicable NSPS include 40 CFR 60, Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in Mineral Indtcstries.

IV. Brick and Structural Clav Products Production and Raw Material Consumption Information A. Please provide the 1996 production rates and the current production capacity for each type of brick and structural clay product manufactured (e.g., structural brick, clay sewer pipes, structural clay tile, etc.). Note that production data should be provided in units of tons per year (tons/yr).
Product 1996 production (tons) Production capacity (tons/yr) 

## P.'RrUC I 

## STPAQUA& MY4mq

. 51 372 (05 S07

Page 3 of 28



# ,~

## B. Please provide the type and amount of each raw material and body additive used in 1996 for manufacturing brick and structural clay products at your facility. Examples include clays, shale, and any additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade name. If the inforination requested is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. 

## Raw materiaVbodyadditive Amount. in 1996
.

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## C. If available, please provide a copy of the MSDS's for the raw materials and additives listed above. D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above.

Page 4 of 28



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### B. Please provide the type and amount of each raw material and body additive used in 1996 for manufacturing brick and structural clay products at your facility. Examples include clays, shale, and any additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade name. If the information requested is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. Raw materiaUbody additive 

# I Amount used in 1996 (tons/yr) 

# /, I0c 

# lbS

C. If available, please provide a copy of the MSDS's for the raw materials and additives listed above. D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above.

Page 4 of 28 

# 11

## E. Using Table 1, please provide information on the consumption and HAP composition of all glazes and colorants that contain HAP's or HAP precursors and that your facility applies to brick and structural clay products. Indicate whether the coatings are glazes or colorants. Also indicate the type of product that the coatings are applied to and the total weight of coatings used in 1996. If the glazes or colorants are formulated at your facility indicate so and provide the production capacity. List each ingredient of the glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient used in 1996. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. F. In the space below, please indicate any glazes or colorants used by your facility that do not contain HAP's and are substitutes for HAP-containing glazes or colorants used by your industry. Indicate which HAP-containing materials the non-HAP glazes or colorants replace. Describe any limitations on the use of those substitute glazes or colorants.

G. If your facility colors brick and structural clay products by flashing } please indicate the types of substances used to flash the products and the amounts of those substances used in 1996. Substance


## ~ ~ 

# tc Ge Am ount used in 1 99 6► ~ . ~ , .

, . ~ .i ?•r . 

## Units s eci



# WAC

H. If available, please provide a copy of the MSDS's for the glazes and colorants used by your facility. If your facility prepares its own glaze, please provide any available MSDS's for the glaze ingredients.

Page 5 of 28
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### TABLE 1. 

## CONSUMPTION AND HAP COMPOSTITON OF GLAZES AND COLORANTS

If additional space is required, please make copies of this page. If the information requested in the table is contained in your facility's operating permit or pernlit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. Page 6 of 28 

# i

### TABLE 1_ CnNSUMPTTON AND 1-lAP CnMPnSiTTt7N C)F r ti A7FC e nrn r , nr np n,.TTc.



### Type (e.g., glaze, colorant)

colored Type of product glazed or 

# ~~ R ✓ ~ uL ~~~ ✓ a~r ~ 1996 constimption (tons/yr)

~ 

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## Total usage (weight) of each

~ 

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If additional space is required, please make copies of this page. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable :ections of the permit (or application) rather than filling out the table.

P:i2c 6 ol' ?K 

### /~

### TABLE l. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND COLOR A ivrc

Type (e.g., glaze, colorant) 

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### If additional space is required, please make copies of this page. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table.

f';iZc 6 ol 28



## ~ /

## V. Description of Brick and Structural Clay Product Manufacturing Processes A. Please provide a simple process flow diagram for each brick and structural clay product manufacturing process line. An example process flow diagram is provided in Figure 1. A diagram of the plant layout with all processes and emission points clearly labeled is also acceptable. * eE7 ~ 

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## Assign a unique identification number (ID No.) for each process_ that has associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. Please identify all emission points, including those that do not emit HAP's. For emission points that are vented to an air pollution control device (APCD), assign an ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information request for any responses that pertain to any process or emission point.



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## B. Using Tables 2A and 2B, please provide current production rates, production capacities, and related information for each type of equipment used in brick and structural clay product manufacturing. In Table 2A, provide the requested information for only those sources that are known or expected to emit HAP's. In Table 213, provide the requested information for all thermal processing, such as drying and firing sources. For combustion sources that use different fuels, Table 2B should be completed for each type of fuel. For example, if a kiln typically is fired with gas, but periodically is fired with oil, one column in Table 2B should be completed for the kiln when fired with gas, and another column should be completed for the same kiln when fired with oil. Provide the data in the units listed for each row. 

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## ~~

## C. Using Table 3, please provide information on procedures used to monitor the process operating rate for each of the pieces of equipment and HAP emission sources listed in Tables 2A and 2B. Use the same HAP emission source types and equipment 

## ID numbers you listed in Tables 2A to 2B. Indicate whether you monitor process rate or not. Provide a summary of process rate monitoring procedures that describes how process rate is measured for the particular piece of equipment. Include where the rate is monitored (i.e., rate of material fed, rate of material discharged, or material production rate), the units used to measure process rate (e.g, lb/hr or pieces/hr), and how the process data is recorded, i.e., manually, automatically (e.g., computer - printout or stored to disk, or not at all). If you monitor process rate at both the feed and discharge ends of the equipment, indicate so. Indicate the type of monitor, equipment, or instrument used to measure process operating rate. Indicate the monitoring frequency or how often process rate measurements are made. If instruments are used to measure process throughput, indicate in the monitor accuracy column the accuracy of the instrument. The monitor accuracy could be listed in terms of a percentage of the throughput (t 1 percent), mass per unit time (±21b/hr), number of pieces per unit time (± 10 pieces/hr), or other appropriate units. Indicate the frequency that the monitor is calibrated. Provide data in the units listed for each row.

Page 12 of 28 

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Page 13 of 28 

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## VI. Identification of Brick and Structural Clay Product Manufacturing Emission Points



## A. Use the process flow diagrams developed for your facility and Table 4 to provide the following information for each HAP emission source at your facility. • Define HAP emission source type in terms of equipment, such as dryers, kilns, etc. As in the process flow diagram, you may group multiple pieces of similar equipment. • Use the same equipment ID numbers indicated on the process flow diagram(s). • If the emission source vents inside a building or to outside ambient air without first passing through a control device, place a check mark in the uncontrolled column. • If the emission source vents inside a building or to outside ambient air after passing through a fabric filter, dry injection fabric filter, or scrubber, place the APCD ID number(s) in the column corresponding to the APCD type. • If the emission source vents through a control device type not listed in Table 4, indicate the control device type in the other control column and place the APCD ID number in the appropriate cell. • In the etnission test data column, place a"yes" or "no" in the appropriate cell to indicate whether the specific source has been tested for 

## my pollutants, including any HAP's, VOC, PM, or opacity.

Page 14 of 28 

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## ~~

## B. Using Table 5, please provide information on stack parameters and emission estimates for each emission point at your facility that is known or expected to emit HAP's. Provide information for all APCD's, including those that exhaust inside the building. Include data for each inlet and outlet, if available, as indicated in the table. If you have more than one inlet to an APCD, provide data for each of the inlets. Provide data in the units listed for each row. Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal HAP's or VOC for organic HAP's. Emission estimates may consist of measurements reported in emission test reports or may be calculated using mass balances, emission factors, engineering judgement, or other estimation methods. Provide the emission estimates as emission factors in units of lb of pollutant emitted per ton of product (lb/ton). Provide complete copies of any emission test reports or other reports that document measurements of emissions. Test reports and other emission measurement documents should include the following information: process identification; location of sampling point; stack diameter, temperature, and flow rate; test method, including analytical procedures; number of test runs; emission concentration, emission rate, percent oxygen, and percent moisture for each test run; process operating rate; type of APCD; and APCD operating parameters. However, test reports with incomplete documentation may still be useful and should also be submitted. You do not need to fill out Table 5 for emission points that are covered by an emission test report that is include.d in your submittal. If emission test reports are not available, provide calculations that support your emission estimate, including the basis for all assumptions in the estimate. Note that emission estimates are needed for all HAP's that the facility emits or has the potential to emit. (Please refer to the HAP list in Attachment 1.) If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 16 of 28 

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~ Z C ~ Q ~


# ,~~3

## C. Using Tables 6A through 6D, please provide design and operating data for each APCD associated with all dryers, kilns, and any other brick and structural clay products manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of APCD's. Use Table 6D for other types of APCD's. When using Table 61), please specify the type of control device and 2 to 4 key design or operating parameters for the device. Provide data in the units listed for each row. If the information requested in Tables 6A through 6D is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the tables.



## ~ 0 Cl A'1O



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## D. Using Table 7, please provide the following information on current monitoring procedures for each of the control devices listed in Tables 6A to 61): parameters monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices used (e.g., differential pressure transducer, thermocouple), and recordkeeping practices (e.g., manually recorded in log book, continuously recorded by electronic data acquisition system). Describe briefly other operation and maintenance (O&M) procedures for each control device. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table. VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing A. Please describe all pollution prevention practices (i.e., process modifications, such as re-use of discarded or rejected materials, or any practice that prevents or reduces the amount of air emissions, or the generation and release of solid waste or wastewater associated with the operation of air pollution controls). If the information requested here is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below.

~~~~U

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### VIII. Information on Processes Other Than Brick and Structural Clav Products Manufacturiniz Processes 

### A. Using Table 8, please identify all other processes or operations at this facility that are not addressed in Items II through VII above and that are potential sources of HAP emissions. Estimate total annual emissions of each HAP emitted by these colocated processes. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 27 of 28

.3l

~ 

### :2-

### TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES

Process/emission source/SIC Code(s) HAP's emitted Estimated annual emissions, tons EXANfPT;E DTining ' ;° 

# , , SIC

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## SIC If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.
Page 28 of 28



## ~~~

# M mutual materials co. 605-119THNORTHEAST POST OFFICE BOX 2009 BELLEVUE, WASHINGTON 98009 PHONE(206)455•2869 

# February 27, 1998 This attachment consists of those portions of the Air Operating Permit Application for the Newcastle Brick Plant Facility of Mutual Materials Company, as submitted to the Puget Sound Air Pollution Control Authority, which are deemed relevant and pertinent to this ICR submission.

Ljeorge t3eamer Mutual Materials Company

# e Newrastle Plant - Au Operaa.mg Pamn Apph,:au,n Mutual Matu

- t;il; Compan.


# ~ Puget Sound Air Pollution Control Agencv


# ~ Air O eratin Permit A Iication



# p g pp
~



# ~ 

# y■ N Mutual Materials Comparry 

# y Newcastle Brick Plant Facility 

# El a■ y a June 7, 1995

# ■■ .a oP Application

D MOlD16QA ~ ll ~ VQOWO /I/I.DOC 

# 3SMtIIU:il \tJtln:ii, Corzilp m. Newcastle Plant - Air Opaatmc Per= \pplj::ui,u 

### C. Plant Operational Characteristics 

### C.1. Significant Emission Points. Controls & Stacks 

## Form C-1 is completed and attached. Emission Unit EU5.1 - Keller tunnel kiln, one exhaust stack and no emission controls. C.2. Facility Process Flow Diagram 

## Flow chart in Appendix C describes to manufactiuing flow. The flow chart in Appendix D details the emission sources, discharge points and emissions. C.3. Site Map 

## The site map is in Appendix E. It shows the facility boundaries, location of emission points, stacks, outline & elevations of buildings, access and haul roads, raw materials, fuel, waste piles, and evaporative ponds. C.4. Potential Emissions Summarv 

## Forms C-2 and C-3 are completed & attached. Appendix A& B include calculation methods, assumptions and data used in determining potential emissions. Potential emissions include: 

# ~ 1. Hydrogen fluoride from clay buming process.

2. Carbon monoxide from natural gas buming process. 

# ~ 3. Nitrogen oxides from natural gas buming process.

4. Sulfur oxides from clay burning process. 

# ~ 5. Potential VOC's from clay burning process

6. PM10 from clay burning process & grinding process. 7. Particulate from grind'mg process. 

# ~ 8. VOC's from storage tanks. ' 9. Particulate from maintenance and repairs.

The greatest emission potential are the following: 

# ~ Hydrogen fluoride (HF) generated from the natural fluorides contained in clay. The potential to emit

is approximately 58 tons per year if both kilns (Keller & Dressler) were operating the entire year. Fugitive dust from the grind'mg and material transfer processes. The potential to emit is over 1,400 

# ~ tons of dust.

4 OP A pplicattion page .i 

# I I 

# 1 I I t I

u wwanwn
~ onno
~ r_vuumc 

## '3j 

# ~ -` Vlutual MatenaL, C:,m>p:m ~ ` Newcay.le Plant - Air Operatmg Pernvt :

~ 4*pltmu n

, 

## Chapter 2 - Regulatory Requirements

A. Description of Signiflcant Emission Points 

## ' A.1. Eguiament Descriution

Emission Unit EU5.1 - Keller tunnel kiln 

# ~ Emission Point: Keller kiln stack. Located in manufacturing/firing/packaging building complex.



## Stack characteristics: Height of 35 ft. from ground level. Used a class 700 fan exhausting between 

# ~ 28,000 to 35,000 CFM.



## Rate of discharge: Based on stack test at a rate of approximately 71bs/hour for HF. About the 

# ~ same as AP-42 factor of 1 lb of HF per ton of brick manufactured.

Controls: There are no control devices on tliis ki}n for reducing air emissions. 

# ~ A.2. Emissions

Forms C-2 and C-3 are completed & attached. Appendix A& B includes calculation methods. assumptions and data used in determining potential emissions. 

# ~ Also attached are copies of the AM-Test stack test conducted in

. April of 1994 (Attachment 3),

analysis of clays done by an outside laboratory (Attachment 2) and a copy of the MSDS for fired clay 

# ~ brick (Attachment 1).

A.3. MonitorinQ/Control Ectuiament Keller stack emissions: There is no monitoring or control equipment currently used. Mutual intends to submit an NOC to install a control device to limit fluoride 

# ~ emtsstons.



## B. Applicab/e Requirements 

# ~ Form C-2 is completed & attached. It includes all applicable requirements for this facility, and

reference methods used for determining compliance. 

# ~ C. Exemptions



## Mutual Materials has not been granted any exemptions from otherwise applicable requirements. 

# ~ D. lnapplicab/e Requirements

Form C-4 is completed & attached. It includes a listing of all inapplicable requirements for this facility. 

# ~ E. Compliance P/an 

# ~ E.I. Status

Emission Unit EU5.1 - Keller tunnel kiln Based on stack tests conducted and air modeling conducted in 1994, Mutual Materials is unable to determine whether this unit is in compliance with all applicable requirements. Mutual Materials is concemed that this unit at the Newcastle facility maybe exceeding the ASIL threshold values for fluoride being emitted to the ambient air as stated in PSAPCA Regulation III, Section 2.05. AOP Application page b

A. V OIDkp,QA1FHVa W.61 _ AAQDpC 

# :57

# ~ Mtatial Matu - aL, l:ucT an\ Newcastle Plant - P.a OpQatmg Pr=t :1PpL.ati n



# ~ Form A-1: Generai Information & CertifiGation Air Operating Permit Application


# ~



# ~ 1. Company Name : ................................................ Mutual Materials Company

2. Facility Name :.................................................... Newcastle Brick Plant 

# q 3. UBI# :...........................................:....................178-001-617

4. Facility Address : ................................................ Street: 6620 Coalcreek Parkway ' City/State/Zip: Newcastle, WA 98059 County: King 5. Mailing Address :................................................ P.O. Box 2009, Bellevue, WA, 98009 

# ~ 6. Owner :
.............................................................. Mutual Materials Company

7. Owner Address :................................................. P.O. Box 2009, Bellevue, WA, 98009 

# ~ 8. Facility Person Familiar with Information:.......... Neal Bachelder, Plant Manager, 206-255-1 l01

9. Type of Operating Permit : ................................. Initial Permit Application 

# ~ 10. Reason for Application : ..................................... Exceed 10 tons of HF per year

11. Claim of Confidentiality : .................................... The records & information contained in 

# ~ the application are unique to the applicant and/or a likely to adversely affect the competitive position of the applicant if released 

# ~ to the public or a competitor

12. Document Prepared by : ..................................... Brad Cahoon, Safety & Compliance Manager, Mutual Materials Company, 455-2869 

# ~ Loren Dunn, Attomey at Law


# ~ Certification

This document and all attachments were prepared under my direct supervision. I certify that all 

# ~ information submitted is accurate to the best of my knowledge.

Printed Name: .T C

~ 

### A/O E

~ 

### CEG! 

# ~ Signec ` Title:



# ~

~

~ : IOP Application

~ D" ~ Ot1MATA4]aV1Ql5 ~ _AIffDOC 

## Date: G — 7' 

### 9S

PaSe /-' 

# slr-*-,

# ~

~ i

~ Attachment 3
Stack Test for Keller Kiln Mutual Mat nai, Nekc3sUe Plant - A.Lr Cpaatmg Nrmn ApPit.aum



# ~

~

~

~

~

~ i

~

~

~ i .40P Applrcation page 31

D~ '/
~ ORDDwUY3iVLLOJEM RtMIDOC



# . . ~ 

# I

# AIV1 r=Sr AIR QUALITY, INC. SUMMARY OF RESULTS - METH00 138 AM TEST-A1R OUALITY, INC.
FILE NAME: S705\MMATFSMB

~ CLIENT: MUTUAL MATERIALS LOCATiOM: NEHCASTLE PLANT - RENTON, 41ASHINGTON KELLER KILN STACK

RUN Ml RUN M2 RUN 93 4 • ~

AVERAGE . 

# r o! t' i+ E

~ 

# i 1~ ~i 

# 1+

~ 

# I

~ 

# 1 I~

V.

1



# ~ I ~ LAB

DATE: START T1ME: STOP TiME: SAMPLE LEMGTH (minutes): VOLLIME SAMPLED (clbic feet): VOLUME SAMPLED (dry std, cubic feet): VOLUME SAMPLED (dry std. cubit ineters): STACK GAS MOISTURE (percent): BAROMETRIC PRESSURE (inches of Hg): STATIC PRESSURE (inches of H20): STACK PRESSURE (inches of Hg): STACK TEMPERATURE (degrees F.): STACK TEMPERATURE (degrees R.): CARBOM DIOXIDE (percent): OXTGEM (percent): CARBOM MONOXIDE (ppm): CARBON MONOXIDE (lb/hr): MOLECULAR YEIGHT (dry, g/g-mole): MOLECULAR YEIGHT (wet, g/g-mole): AVERAGE VELOCITT HEAD (inches of H20): PITOT TUBE Cp: STACK GAS VELOCITT (feet/second): STACK DIAMETER (inches): STACK AREA (square feet): STACK GAS AIRFLOY (dry std. cubic feet per min.): STACK GAS AIRFLOY (actual cubic feet per min.): NOZZLE DIAMETER (inches): ISOKINETICS (percent): GASEOUS FLLKN(IDE EMISSIONS (as Hydrogen F(uoride (HF)):

------------------------------------------------------ FRONT-HALF FLUORIDE EMISSION.CONCENTRATIOM (ppm): FRONT-HALF FLUORIDE EMISSIOM RATE (lb/hr): BACK-HALF FLUORIDE EMISSION COHCENTRATIOM (ppm): BACK-HALF FLUORIDE EMISSION RATE (Lb/hr): TOTAL FLUORIDE EMISSIOM CONCENTRATION (ppm): TOTAL FLLKN2IDE EMISSIOM RATE ((b/hr); 5501 5502 5503 4/22/94 4/22/94 4/22/94 09:29 11:25 13:20 10:27 12:22 14:17 50.0 50.0 50.0
37.978 47.560 45.925 38.409 46.478 44.178 1.088 1.316 1.251 6.20 5.15 5.76
29.80 29.80 29.82 -0.54 -0.56 -0.56 29.76 29.76 29.78 447.6 432.2 434.4 907.6 892.2 894.4
2.2 1.7 2.0 17.8 18.2 18.0 55 53 51 4.05 4.94 4.43 29.06 29.00 29.04 28.38 28.43 28.40
0.851 1.31 1.16 0.84 0.84 0.84 68.7 84.6 79.4 31x35 31x35 31x35 7.54 7.54 7.54 16864.3 21359.3 19899.7 31070.4 38257.3 35938.3
0.253 0.253 0.253 98 94 96

I 1.32 1.00 0.215 0.845 0.069 0.066 0.013 0.049 118.3 96.8 116.3 110.5 6.21 6.44 7.21 6.62 119.6 97.8 116.5 111.3 6.28 6.51 7.22 6.67



# ~~ 43.821 43.022 1.218 5.70
29.81 -0.55 29.77 438.1 898.1
2.0 18.0 53 4.47 29.03 28.40 1.11
77.6

19374.4 35088.7

# I

~

~

~ Appendix A 

# I Emission Calculations Muttul \1

~ t nal. ~ l:.m ~:m~ \'eucastle Plant -.air Opcaatmg Y

~ rmit :1ppit::ui n



# I 

# I I

L'
~ 

# I I

~

~

~

~

[: 

# I 

# a .40P Application page 33

~ D ~ W OIfTDAiA ~ F]1 ~ 1lOJEY', V[MID6C

~ j

# ~ i 

# r r i i Mutual Materiais - Newcastle Plant Poteritial Air Emissions Calcuations
Keller Kiln EU5.1 Potential Air Emissions AP-42 Factor Potential (IbsRon) Capacity UOM Calculation Annual Emissions UOM HF ' 1.000 58950 tons 1.000 x 58950 29.475 ' tons NOx 0.180 58950 tons 0.18 x 58.950 5.306 tons SOx Neg Neg Neg Neg Neg Neg VOC (nonmethane) 0.003 58960 tons 0.003 x 58950 0.088 tons VOC (methane) 0.006 58960 tons 0.0D6 x 58960 0.177 tons Particulate 0.023 58950 tons 0.023 x 58650 0.678 tons PM10 0.010 58960 tons 0.01 x 58.950 0.295 tons CO 0.060 58950 tons 0.08 x 58960 1.769 tons ' Actual stack test 4/22J94 at ave. 6.67 Ibs./hr. or 29.22 tons per year



# ~ 

# i 

# i i 1 

# i i 1 i Dressler Kiln EU5.2

Potential Air Emissions HF NOx sOx VOC (nonmethane) VOC (methane) Particulate PM10 CO Grinding F3.1 - F4.1 B Potential Air Emissions Particulates HF NOx sOx VOC (nonmethane) VOC (methane) PM10 CO
ND = no data Neg = negligible AP-42 Factor Potential (IbsRon) Capacity UOM Calculatlon Annual Emissions UOM 1.000 58185 tons 1.000 x 58185 29.0925 tons 0.180 58185 tons 0.500 x 58185 5.23665 tons Neg Neg Neg Neg Neg Neg 0.003 58185 tons 0.01 x 58185 0.0872775 tons 0.008 58185 tons 0.02 x 58185 0.174565 tons 0.023 58185 tons 0.065 x 58185 0.6681275 tons 0.010 58185 tons 0.01 x 58185 0.291 tons 0.060 58185 tons 0.080 x 58185 1.74565 tons

AP-42 Factor Potential (IbsRon) Capacity UOM Calculation Annuai Emissions UOM 20 133120 tons 20 x 133120 1331 tons 

### ND ND ND ND ND ND ND ND ND ND 1.4 133120 tons 1.4 x 133120 93 tons 

### ND ND


# i i i I 1JC_cALC2JLs
4~ 0~

# i i i i 

# i 

# i i i i i i 

# i i i i i i i i Appendix B Capacity Calculations ylutual %1at

~ n: i , C:,aup:am, Newcaale Plant • Au Operauu¢ P

~ niat Apph:au,n



### AOP Application
D , W OlD.O

~~ _iIMDOC 

### page 3-J

4-5

### ~

~ 

# ~ f

~

~
~



# ~ Mutual Materials - Newcastle Plant Potential Capactty Calculatlons

Keller Kiln FUEL Daily fuel consumption 4,660 therms/day Annual operating days 365 days/yr Annual fuel consumption 1,697,250 therms 4,650 therms/day x 385 day/yr


### PRODUCT Cars per day (cpd). Kiln cars through kiln. 12.5 cpd Brick equivalents (BE) per kiln car 7,000 BE Annual operating days 366 days Annual maximum capacity 31,937,500 BE 12.5 cpd x 7,000 BE/Idln car x 365 dayslyr Annual maximum capacity (tons) 65,500 tons 31,937,500 BEryear x 4.1 pounds/BE / 2,000 poundsrton Swindel4-Dressler Kiln 

### FUEL Daily fuel consumption 4,100 therms/day Annual operating days 386 dayslyr Annual fuel consumption 1,498,500 therms 4,100 thenns/day x 365 day/yr 

### PRODUCT Cars per day (cpd). Kiln cars through Idin. 38 cpd Brick equivalents (BE) per ldin car 2,400 BE Annual operating days 3®5 days Annual maximum capacity 31,536,000 BE Annual maximum capacity (tons) 64,850 tons
Grinding Process RAW MATERIALS (Clay 8 Grog) Tons per hours ground 32 tonsihr Hours per shift 8 hours/shift Shift per day 2 shifts/day Days per week 5 day/week Weeks per year 52 weeks/yr Annual material processed 133,120 tons F-Aruding Process RAW MATERIALS (Clay Mix) Tons per hours extruded 32 tonsAv Hours per shift 8 hours/shift Shift per day 2 shifts/day Days per week 5 dayMwek Weeks per year 52 weeks/yr Annual material processed 133,124 tons BE = brick equivalent (approx 4.1 Ibs. fired weigM) 38 cpd x 2,400 BEAdIn car x 365 days/yr 31,536,000 BE/year x 4.1 poundsBE / 2,000 poundsrton

32 tonslhr x 8hr/shift x 2 shifts/day x 5 day/wk x 52 week/yr

32 tons/hr x 8hr/shift x 2 shifts/day x 5 dayAak x 52 week/yr

NC_ cwci )Ls '7" 

# ~

# i 

# i 1 i 1 

# 1 Appendix C
Process Flow Chart Mtrtual tiLitenaLs l:,upm\ Newcastle Plant - Au Operatmg Permit AQpLwu n



# i 1 1 

# r i 1

~

~ 

# i ! 1 r
~ AOPApplication page 35

WvOIAO.QwWNVRQl6M_R1?DOC 

# ~~Mutual Matenals Company - Newcastle Plant

Flow Diagram - Clay Brick Manufacturing

• Cleyon i Sb ; C+inheu ' ReJecb 

# i 

# _7 0 """T

A

i I Clay Storage Clay Prep

'\ ~~ ~ Q

I I PreCnnher

' Overalzs .._._._.. fhy Pen CrtMar

N1asb Mabrkel _....D

3teem to Atmoephere

To page 2

v Manufactured Product To Abnosphere

~ Other Materlals .D Recycled Materials► Natural Gas

- > Fugitive Dust Pa©e 1 

### 7 ~Mutual Matenals Company - Newcastle Plant

Flow Diagram - Clay Brick Manufacturing

8hippYq 1nArel

~ ow• Stonpe PreP I 6 sh4phW

Re~

To Clay Storags Nse

Page 2 

# i i i 

# i i 

# i i i i 

# i i i 

# i 1 

# i i i i 

# i From page 1 ; — ~ r --

~ ProCUCI hom ~ Setectlon
~ ~, ~~~

r 

# ~

~ CleeNnp I

I I I 1 ReSrNng Ian Cars Car GeerYrp

vacwm

M anufactured Product

— ~ Other Materials - - - - - - - - - - -- D Recycled Materials

### ► Natural Gas

_ ..... p Fugitive Dust 

# `0Mutual Matm:ils Cvmp:m ~ Neucastle Placit - Air Operazmg Pmntt :\ppltcaum



## Appendix D Process'Flow Chart by Emission Source

:IOP Application page 36

I D"y0llTDAtA1FJMLLOJEr_ V 

# ~Process #1: Brick Manufacturing 3 - Clay Prep 3.1 Batching I.10c days and grog (tlred recyded brkk usad as a fller) by tont end loader eqrlpment to obta t clay body mEt. Add cdoranb of manpansa eompoutd or dlromklrn compol/d to certah brtk. 

### 3.2

Crushing Cnnh rawday a grog ' trb snWlet pk+ces. '

i i

4-

~ 

### 4.1 Pugging Add rAtr to dayand mh~ pLig MM

### 4.2

Extruding I Under weuim s.muds ~ stR dayMaYr mbmrs ~ firutph dle. Cul brkk to proper helpht wft Nta. Soms bAck w gtwn a slury coat of csnmk mabrW at exYUdhp for color an fre subu.

6 - &tdc 

### 6.1 6.2 Sorting Packaging FFed brlck are marrady Sarted brkk are maraWly trarMerted tom Idn ar barofsned tom corveyor to artisyar and qulay to paueb and bag0ed hspected. 

# r r r r 

# r i

~
~ i 

# i i i Newcastle Plant - Brick Production Process Flow DlaQam

7 - P_I,v MnuleiHnn 

### 2.1 2.2 2.3 Mining Hauiing Stockpiiing Atie tlay uskq suaPPer Dump truek and tnler Clay b stxked at plarrt and/or em:auator harl clay to plant sRe, see uWer rool or open squpmerd. at.

OFFSnE OF PROPERTY OFFSrTE OF PROPERTY

3 - Clay Prep 

### 3.3 3.4 3.5 Grinding Screening Storing Transbr crushed day by Transkr semFRro grand Clay tnnskrted frmn corrveyor to dry pan rolbr. day by corrAyor to saeenkp b slonpe hen Clay putwrized uMer Nbrsthg scran. Slze to by corneyor. rolera. 13arlum amall mesh. Recyde ete carbonats mayM adtled larger mash slze baekto to reducs an shhs on 

## I grhdep. certakn brkk

4 - Manufacttring S - Firin 

### 4.3 4.4 5 Setting Drying Firing VYet brlck are nrrwully Set brkk ae drlsd uahtf Dry brtck are lked at a set from convsyor to eaess heat from kln max temp. of apprmc Idln ars 2.000 dppses F. 

# J i i 

# i 

# i i 6 - Brldc Handlin 6.3 Yarding Packaged brkk an trarnferred tom packalgkq lo yvd storage (oublde or kWde) by la truek 1



### 6.4 Deiivery Yarded bflektrarMemd by tUt tuek b denkwy bueks and delMred to Jobshes. 7 -Miscellaneous
• Malntenance 3 Repalrs • 8ample Board Making • vacuum System •ACi Fuding tanks (propane d diesel) • Space heaters • Alr conditloners • Palnting • Clean-up • Other

r 

# ~ (

# i 

# l i i i 

# i i i i i 

# i i i i i 

# i i i Newcastle Plant - Brick Production Process Flow DlaOram



### Process 2 (Clay Acquisition)

Sun-Proceases 2.1- Mining -7 2.2- Hauling im- 2.3- Stockpiting-------) 

## ~

~ OFFSITE OF PROPERTY --
Fuel/Raw ; I Diesel fuel I i Clay Diesel fuel Clay Materials Input I



### ~

Generation nn,rw H,Wr,p EqulPmsrrt ~ ~ r ~ Eq L lprrrnt Haul POlnt ro

~ ds

Discharge Polnt

Emisdons Output



## ~

~ ,

# i i

~ 

# i i 

# i i i 

# i i i 

# i i i i 

# i i i

~ Newcastle Plartt - Brick Production Process Flow Giaoram



### Process 3 (Ciay Prep)

3100 3.1- Batching 3.2 - Crushing -3 j

.. 3.3- Grinding ~

FuellRaw I Materials Diesel tuel 

# ~~ k Clay mix Cfay mix Input



# I F-3.3A F-3.3B i Generation ; 

# c«nsr« Point

~ 

# ,,,«« pwm I ory p«+ rai«

Discharge Point Open doaa « root openYqf

Em issions Fr ,~~ Output dr,><

....... .. .._ ...... ....................... .......... ............................. _ ....... ......................_...... .......... _._. ....... _. ....... _. ... .. .... ............ .......... _ .... ......._........._. ............. ..... ..... ........................ ................. .. ..... .. .__.



# _ 3.4- Screening 31 

# , 3.5- Storing 

# 10

Fuel/Raw I Clay mbc Clay mnc 

### Materlals Input

Generation F-3.4A F-3.4B F-3.5 Point Vlbratlnp Corrvsra CorrNy« ,a«n. trf rot« trunst« ooYib poirft .

Discharge 2 Point Opsn doon or roof operrrps

Emissions Fug*A Output dusi



# s~ In

# ~ • 

# ~ Newcastle P1ant - Brick Productlon Process Flow Dlaaram



### Process 4 (Manufacturing) 4.1- Pugging 4.2- Extruding 4.3- Setting 

# ~



# ~ Fuel/Raw

Materials 

# I

~ il Clay Mix Clay/Water Ma C1ay/Watnr i Mix 

# ~ Input 

## ~

F-4.1 

# ~ Generatlon Polnt c 

## ~~ Trarabr PoM


# ~ Discharge 2 Polnt opa,aoas 

## ~ or raot operMqs


# ~ Efn i sstons Fug*A Output nuet 

### i._._........._ _...._._......_...._........_...._...._......_._... _ _ _ _ _. . _ _ _ _ _ _ _._......_._......_._._........_.........._....._......._._........_._..........._ _._....... 4.4- Drying

- 

# ~
~
Fuel/ifaw ClayNwter Ezeess Idin 

# ~ Materials muc heat Input


# ~ EU-4.4 Generation Tunnel 

# ~ Point dryer 

# 3 ~ Dlscharge Roof



## ~ Point 

## ~ +

6n isslons ""' r 

## ~ 

# i Output Vapor



# ~ 5 ~Newcastle Plarrt - Brick Production Process Flow DlaQam



### Process 5 (Firing) Dressler Tunnel Kiln 

# ~ 

# i 1 i

~ i i

~ i 

# i i i 5.1- Firing > 1 Keller — ~ Kiln FuellRaw Naaual Ctay mix Materlals g" Input

Generatlon EU-5.1 Point KMW Tumal qn

Dlscharge 4 tw Point Ekuuat staGk

Em IpiOns Air ~u~ put EYfbro HF, CO, NOx, PM10 m 5.2- Firing )p Dressier —)p Kiln

—~ NaGUaI Clay mix i gaa

EU-5.2

Drsfabr Ttinel IOIn

5 nn E#haast 3tack

A ' r HF, CO, NOx, PM10 EmYabro ,



# d d d d 

# d d s3Newcastle Plant - Brlck Production Process Flow DlaQam



### Process 6 (Handling)

30. 6.1 Sorting _3P. 6.2 Packaging —v. 6.3 Yarding ----

~

Fuel/Raw Finished Finished Materlals briak ~~ Propane Input

Generation Handlinq Handlinp ~ b'ck PaM 8 Cump suck 

### F

- 

### 6.3
D 1 rty I Asphan



### 6 Discharge Tnuk Point Tkn

Emisslons Output


### 6.4 Delivery - —

Fuel/Raw P ro p,,,. Materials ~d~N Input

Generatlon F

- 6.4

uanno a Point dwwy

~ +,m



### 7 Discharge Pan< Truck nes

En118Slons / FupIM Output `\ dust



## . .S 

# ~ ri 

## WESTERN ANALYTICAL, INC. 

## 2417 CONSTITUTION BOULEVARD SALT LAKE CITY, UTAI-I . 84119-1225 PHONE (801) 973-9238 OR (800) 383-5924

FAX -(801) 973-7635
CERTIFICATfi OF ANALYSIS May 26, 1994 

## P94-246 ' ACCT: No. 1000 YOUR PURCHASE ORDER: 158665
MUTUAL MATERIALS t MR. BRAD CAHOON I 605 119TH NE BELLEVUE, WA 98009
Dear Mr. Cahoon: - Transmitted herewith are the analytical dalta for the nine (7) clay 

## and-two (2) brick samples delivered to our laboratory for fluoride (F-) analysis. DATE RECEIVED: May 6, 1994 DATE OF ANALYSIS: May 13, 1994 -- RECEIVED BY: Julie Lopez
SAMPLE F-
~ 

## IDENTIFICATION ( $ ) Marchesini clay 0.020 Columbia clay 0.092 Clay city state clay 

# ~ 0.028 Sec. 31 Blue clay 0.104 BucOda clay 0.068 Elk clay 0.052 

# ~ White clay 0.056 Inca green #1 0.048

, Inca fired #2 0.020

~ .

. '



## . . LLI Laboratory rector EHP/ j 1 

## cc: Ms. Mary Ainger


# ss i

## WESTERN ANALYTICAL, INC. 2417 CONSTITUTION BOULEVARD SALT LAIiE CITY, UTAH 84119-1225 

## PHONE (801) 973-9238 OR (800) 383-5924 ^ _



## FAX (801) 973-7635 CERTIFICATE' OF AIJALYSIS 

## May 26, 1994 P94-246 Page 2 of 2 

## ACCT: No. 1000 YOUR PURCHASE ORDER: 158665 MUTUAL MATERIALS MR. BRAD CAHOON - 605 119TH NE BELLEVUE, WA 98009 Dear Mr. Cahoon: Transmitted herewith are the analytical data for the two (2) brick samples delivered to our laboratory for Al 2 0 3 , BaO, CaO, CdO, CoO, Cr 2 0 3 , Fe 2 0 3 1 M901 MnO, PbO, Ti0 2 , V 2 0 5 , ZnO, Na 2 0, K Z O aild 

### Si0 2 

## aiialysis. DATE RECEIVED: May 6, 1994 DATE OF ANALYSIS: May 25, 1994 RECEIVED BY: Julie Lopez SAMPLE Inca Green #1 Ii1ca Fired #2 IDENTIFICATION ( $ ) ( $ ) Al 2 0, 19.45 19.02 

## Ba0 0.773 0.752 Ca0 2.10 1.89 Cd0 < 0.005 < 0.005 Co0 < 0.0A . ' < 0.005 

## Cr z O, 0.014 0.011 Fe Z 0, 6.62 7.14 

## Mg0 2.06 2.11 

## Mn0 0.113 0.099 Pb0 < 0.005 < 0.005 TiO Z 0.744 0.771 V Z O S < 0.005 < 0.005 

## Zn0 0.019 0.016 Na Z O 1.50 1.60 K Z O 2.34 2.35 Si0 2 64.26 64.20



# ~
~ N .

— 

# ~ orat 

## ory L irector I EHP/jl 

## cc: Ms. Mary Ainger 

## S~ l 

### k~

.



# i i i

~ i

~
~
~

# SAMPLE: PALLET WARNIIV G LABEL


# manufactured by M 

# mutual M 

# materials co.

Mutuai Materials Company, P.O. Box 2009, 605-119th Avenue N.E., Bellevue, WA 98009 

# WARNING CAUTION: IMPORTANT SAFETY INFORMATION Dry-sawing or grinding of fired clay brick is not recommended and may result in the release of respirable crystalline silica dust particles that may cause respiratory ailments (such as silicosis) and even cancer if proper protective equipment is not in place. The use of a NIOSH approved respirator, tight fitting goggles, and protecttive gloves are recommended when sawing or grinding these units. Adequate ventilation and enclosure should be provided to workers engaged in these operations. Specific MSDS information is available from the manufacturer and/or seWng agent.



# '57

# ~ MATER4AL SAFETY DATA SHEET 

# ~ aRooucr icewrrr: FIRED CLAY BRICK 

## SECTION f
Manufacturer's Nanie: 

### Mutual Materials Company
Address: 

### P. 0. Box 2009 Emergencv Phone Number: 

### (206) 455 

# - 2869 • Teleahone Number for Information: 

### (206) 455-2869 Bellevue, Washington 98009 

## Date PreDared: November 1, 1994 

# SECTION il-: Hazardous Ingredients/ldentity Information Hazardous Components: Saecific Chemical Identitv: 

### Crystalline Quartz Silica Quartz (Silicon Dioxide), Si0 2 These "Hazardous Components" are not released under normal conditions of use, but may be released from the fired clay brick as airborne respirable free crystalline silica particles when dry-sawing, dry-grinding, or otherwise materially modifying the product. 

## Common Names: Dust from sawing or grinding, Sand, Silica. OSHA PEL• 

### Exposure • to airborne crystalline silica shall not exceed an 8-hour time-weighted average limit as stated in 29 CFR 1910.1000 Table Z-3 for Mineral Dusts, specifically: Silica, Crystalline Quartz (respirable): 0.1 mg/M' ACGIH TLV: 

### Crystalline Quartz TLV-TWA m 0.1 mg/M' (Respirable Dust) See Threshold Limit Value and Biological Exposure Indices for 1991-1992, American Conference of Governmental Industrial Hygienists. Other Limits Recommended: 

### NIOSH has recommended that the permissible exposure limit be changed to 0.05 mg/M' (as respirable free silica) averaged over a work shift of up to 10 hours per day, 40 hours per week. Consult the NIOSH Criteria Document for Crystalline Silica for more information. 

# SEGT'ION IU - PhysicaUChemicat Characteristics Boliina Point 4046°F 

### Speciflc Gravity: 2.65 

### Vaaor Pressure : N/A Meltino Poinb 3050 ° F 

## Vaoor Densitv: N/A 

## Evaaoratfon Rate
: N/A 

## SolubiiitV in VMater: Not Soluble 

## ADpearance 8 Odor: Granular or Powder, 

### Odorless 

## SECTtON N- Fire and Explosion Hazard Data Flash Point Non-Combustible L_, EL; None Flammable Limits: None 

## ~ UEL: None 

### Extinauishina Media
: N/A 

### Unusual Fire and Special Fire Fiahtina Procedures : N/A ' Exalosion• Hazards: None

IV~~ ~ d II o

~ n/

~ ueTr/

~ 0//M ~o~•~~ a.00c 

# S~

### SECTION V - REACTIVITY DATA

Stabili : 

### Stable Conditions to Avoid: 

### None Incompatibility (Materials to Avoid): 

### Silica will dissolve in hydrofluoric acid and produce a corrosive gas, silicon tetrafluoride. ® Hazardous Decomnosition or Bvproducts• 

### None . Hazardous Polvmerization: wi 

### 11 not occur. . Conditions to Avoid: 

### None

_ 

## SECTION VI

- 

## Health Hazard 

## Data Route(s) of Entrv:

Inhalation?: 

### Yes Skin?: 

### No Ingestion?: 

### No Health Hazards (Acute and Chronic): 

### Dry-sawing or dry-grinding may result in the release of dust particles which may: Acute: 

### May cause minor irritation of the eye, nose, or skin. Chronic: 

### Excessive inhalation of dust particles for prolonged periods may result in lung disease (silicosis). Silicosis is a form of disabling pulmonary fibrosis which can be progressive and may lead to death. See "Carcinogenicity" section below. Carcinogenicitv: 

### NTP?: Yes . In the Sixth Annual Report on Carcinogens by The National Toxicology Program (NTP), it was concluded that respirable crystalline silica may reasonably be anticipated to be a carcinogen. The conclusion is based on sufficient evidence of carcinogenicity in laboratory animals, and limited evidence in humans. IARC Monographs?: 

### Yes . The'International Agency for Research on Cancer (IARC) Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans (Vol. 42, 1987) concludes that there is sufficient evidence for the carcinogenicity of crystalline silica to experimental animals, and that there is limited evidence of the carcinogenicity of crystalline silica to humans. IARC Class 2A. Signs and Svmptoms of Exposure: 

### Symptoms of excessive exposure are irritation of eyes, nose and/or throat, shortness of breath, sputum production. Medical Conditions Generallv Aggravated bv Exposure: 

### Pre-existing pulmonary and/or respiratory lung diseases, including, but not limited to; Emphysema, Asthma, or Bronchitis. Pulmonary function may be reduced by inhalation of respirable crystalline silica. Lung scarring produced by excessive inhalation may lead to a progressive massive fibrosis of the lung which may aggravate other pulmonary conditions and diseases, increasing susceptibility to pulmonary tuberculosis. Progressive massive fibrosis may be accompanied by heart enlargement, heart failure, and pulmonary failure. PSmoking aggravates the effects of exposure. Sensitive eye conditions may also be aggravated by excessive exposure. Emercqencv and First Aid Procedures: Eyes: 

### Flush eyes immediately and generously with water for 15 minutes. If irritation persists, seek medical attention. Inhalation: 

### For gross inhalation, remove person immediately to fresh air. Give artificial respiration as needed, and seek medical attention as needed. 

### Skin: Wash thoroughly. See physician if irritation persists. (p+ge ] o[ )) Wra,fAfETT/M96l,M90.9-9AR.00C

_i '>

### /



## SECTION.:VII Precautions 

## for Safe 

## Handiirig 

## and Use Steps to Be Taken in Case Material is Released or Spilled: Collect dust from dry-sawing or grinding operations using dustless method (vacuum or water). Wear protective equipment specified below. , 

### Waste Disposal Method: Dispose in accordance with Federal, State, and Local regulations. 

### Precautions to Be Taken in Handling and Storing: Avoid breathing of dust particles from drysawing and grinding of units. Take normal precautions against spilling of containers with waste dust particles from dry-sawing or grinding operations. 

### OtherPrecautions: Wear NIOSH approved respirator, tight fitting goggles, and gloves when sawing or grinding operations are active. Do not permit dust to collect on wall or floor surfaces, clothing, or equipment. See applicable OSHA Hazard Communication Rule 29 CFR Sections and State and Local worker or community "right to know" laws and regulations. We recommend that smoking be prohibited in all areas where respirators must be used. WARN YOUR EMPLOYEES AND (YOUR CUSTOMER-USERS IN CASE OF RESALE) BY POSTING AND OTHER MEANS OF THE HAZARD AND OSHA PRECAUTIONS TO BE USED. PROVIDE TRAINING FOR YOUR EMPLOYEES ABOUT THE OSHA PRECAUTIONS. I ' See also the ASTM E 1132-86, "Standard Practice for Health Requirements Relating.to Occupational Exposure to Quartz Dust."

„ , 

# SECTION VIII Control Measures : NOTE: THESE CONTROL MEASURES ARE TO BE USED WHEN DRY-SAWING, DRY-GRINDING, OR OTHER MATERIAL MODIFYING OPERATIONS ARE ACTIVE. NORMAL CONDITIONS OF USE ANDlOR INSTALLATIONS OF FIRED CLAY BRICK ARTICLES DO NOT REQUIRE RESPIRATORY CONTROL MEASURES. Respiratory Protection: Use NIOSH approved Particulate Respirator. Provide additional conventional respiratory protection based on considerations of airborne concentrations and duration of exposure. See most recent standards of the following: American National Standard Institute (ANSI Z.88.2) Occupational Safety and Health Administration (OSHA 29 CFR Part 1910.134) Mine Safety and Health Administration (MSHA 30 CFR Part 56) National Institute for Occupational Safety and Health (NIOSH Pocket Guide to Chemical Hazards) 

### Ventilation: Local Exhaust: Meet PEL requirements set out above in Section II.



### S ecial: N/A 

### Other: N/A 

### Mechanical(General): When cutting in confined area, meet PEL requirements. 

### Protective Gloves: Recommended. 

### Eye Protection: Tight fitting protective goggles. 

### Other Protective Clothing or Eguipment: As needed. 

### Work/Hygienic Practices: Avoid creating and breathing dust (see Other Precautions, Sec. VII. ) 

### The information, data and recommendations contained in this MSDS relates only to the specific material desrribed, and is not to be used in combination with any other material or in any other process. This information is based on data that Mutual Materials Company believes to be correct and reliable. It is intended for use by competent persons having technical skill sufficient to understand the Iimits and boundaries of application. Mutual Materials Company accepts no responsibility and disclaims all liability for any harmful health effects which may be caused by purchase, resale, use, or exposure to fired clay brick and/or dust created by sawing, grinding or other operations outside normal conditions of use which may be performed on those units. Mutual Materials Company makes no warranties, either expressed or implied, concerning the application of the information herein. Any use of this information and data must be determined by the user to be in accordance with all applicable laws, regulations and orders. ,p.ge l ot )I nATA/8AiYTr/we0s/w!D!•tI 1 a.DOt

lG/ v

# Cecrar lieiht

~ 

# ' 

# Cl ay ~

(( P. O. Box 295 • Oak Hill, OH 45656-0295 •(614) 682-7794 • fAX (614) 682-6438 

# REU 

# ~

~



### MATERIAL SAFETY DATA SHEET 

## To comply with OSHA's 29 CFR 1910.1200 and Bill No. 70 WHMIS Hazard Communication Standards.

~ 

### SECTION I- IDENTIFICATION OF MATERIAL AND MANUFACTURER



# l( MANIIFACTIIRER'S NAME AND ADDRESS:

Resco Products, Inc. Cedar Heights Clay Division P.O. Box 295 3542 State Route 93 Oak Hill, OH 45656 CHEMICAL NAME AND SYNONYMS: 

## Hydrous Alumina Silicate CHEMICAL FAMILY: Silicate EMERGENCY PHONE: (614) 682-7794



## TRADE NAME AND SYNONYMB:_ :

~ 

# Wclart

SECTION II - CHEKICAL COMPOSITION 

## INGREDIENTS: . C.A.S. NUMBER 

## Crystalline silica (quartz) 14808-60-7 

## Hydrous aluminum

- silicate 1332-58-7 

### E%POSURE LIMITS 

## Crystalline silica (quartz) 0.1 mg/m TWA (ACGIH) 

## Hydrous aluminum silicate 10 mg/m TWA (ACGIH)
SECTION III - PHYSICAL DATA 

## BOILING POINT: N/A SPECIFIC GRAVITY (H20): 2.3 VAPOR PRESSIIRE (mmHg): N/A $VOLATILE BY VOLIIME: N/A VAPOR DENSITY (Aii=1): N/A EVAPORATION RATE: N/A SOLUBILITY IN WATER: N/A APPEARANCE AND ODOR: Dark red with earthy odor.

C~ i/( ', ) PAGE 2 

### SECTION IV - FIRE AND E%PLOSION HAZARD DATA - 0



## FLASH POINT (Method Used): N/A FLAMMABLE LIMITS: N/A Lel: N/A IIel: N/A EXTINGIIISHING MEDIA: Not flammable. May actually be used as an 

## extinguisher. SPECIAL FIRE FIGHTING PROCEDURES: None UNUSIIAL FIRE AND EBPLOSION HAZARDS: None

SECTION V- HEALTH HAZARD DATA - 2 

## PERMISSIBLE ESPOSURE LIMIT: As for the product ingredients listed under, "HAZARDOUS MIXTURES, LIQUIDS, SOLIDS, OR GASES" in Section II of this form. THRESHOLD LIMIT VALUE: As for the product ingredients listed under, "HAZARDOUS MIXTURES, LIQIIIDS, SOLIDS, OR GASES" in 

## Section II of this form. EFFECTS OF OPEREBPOSURE: Dust irritates eyes and respiratory 

## tract. EMERGENCY AND FIRST AID PROCEDIIRES: Wash skin thoroughly with 

## water. Flush eyes for 15 minutes with gently running water. In case of inhalation, move to fresh air. PRIMARY ROUTE(S) OF ENTRY INTO THE BODY: Skin contact, eyes, inhalation of fine fraction. MEDICAL CONDITIONS AGGRAVATED BY E%POSURE: Any debilitating 

## condition of the iungs, eyes, or other mucous membranes. WARNING: IARC MONOGRAPH, VOLUME 42, "EVALIIATION OF THE CARCINOGENIC RISR OF CHEMICALS TO HUMANS, SILICA.'AND SOME SILICATES" PUBLISHED IN 1987 LISTS SILICA AS A CLASS 2A CARCINOGEN. THIS MEANS THAT IN THEIR OPINION THERE IS SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY OF CRYSTALLINE SILICA TO EXPERIMENTAL ANIMALS AND LIMITED EVIDENCE FOR THE CARCINOGENICITY OF CRYSTALLINE SILICA TO HUMANS.
SECTION VI - REACTIVITY DATA - 0 

## STABILITY: Stable INCOMPATIBILITY (MATERIALS TO AVOID): None known. HAZARDOUS DECOMPOSITION PRODIICTS: May release carbon monoxide and sulfur dioxide when heated above 260°C. CONDITIONS TO AVOID: Hazardous polymerization won't occur.

SECTION VII - SPILL OR LEAK PROCEDURES 

## STEPS TO BE TAREN IN CASE MATERIAL IS RELEASED OR SPILLED: Ordinary cleaning procedures taking care to avoid raising dust , clouds. Avoid breathing dust. WASTE DISPOSAL.METHOD: Bury in approved landfill. & ~ 

# ,_Z

# sco ow ` GI- 

### ~ 

## SECTION VIII - SPECIAL PROrECTION INFORMATION - E ;SPIRATORY PROTECTION (SPECIFY TYPE): NIOSH approved dust 

## spirator if working in dusty'conditions (above TLV). CAL EXHAIIST: Ventilation to keep dust/fume level below TLV. E PROTECTION: Safety glasses. HER PROTECTIVE EQUIPMENT: None

SECTION I% - SPECIAL PRECAIITIONS 

## ECAIITIONS: Avoid breathing dust. :E INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCIIR.ATE AND GIQEN IN GOOD FAITH, HOWEVER NO AARRANTY CAN BE MADE.
'T 20, 1993 

# may rials 

# ano Ition,



### ~ 

### It

~ ness 

## any any



### J' 

# 63.!~

. 

### MATERIAL SAFETY DATA SHEET RED IRON OXIDE Pfizer Inc. Form 1

~ 

### Product/Material: e9 Pf I4anufacturer 

### •

• izer Inc. 

### Address:' 235 E 42nd Street, New York, NY 10017 Emergency Tel. No.: (212) 573-2816 Section I - Product Identification Trade Name: Red Iron Oxide Synor.ym: Iron Oxide, Ferric Oxide Chemical Family: Metal Oxide Formula: Fe 2 0 C.I. 3 Pigment Red 101, C.I. No. 77491 

## CAS Number: 1309-37-1 Section II - Hazardous Ingredients Name (CAS 0) X TLV None
Section III - Phvsical Data Boiling Point ( ° F): Not Applicable Vapor Pressure (mm Hg): Not Applicable Vapor Density: Not Applicable Solubility in Water: Insoluble Specific Gravity (H 2 O-1): 4.8-5.2 Percent Volatile by Weight: 0 Evaporation Rate: 0 Appearance and Odor: Red to Reddish Brown Powder, No Odor
Section IV - Fire and Exnlosion Hazard Data Flash Point (Method Used): Non-flammable Flammable Limits: LEL - Non-flammable UEL - Non-flammable Extinguishing Media: Water Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None Section 5- Health Hazard Data Threshold Limit Values: Inert or yuisance dust - 5 mg/M 3 respirable (ACGIH 4 OSHA) 10 mg/M 3 total dust (ACGIH) 15 mg/'S 3 total dust (OSHA) Effects of Overexposure: Irritation in respiratory tract Emergencv and First Aid Procedures: Wash dust from skin with soap and Water. Flush out eyes with ger.erous amounts of water for at least 15 minutes. See a Physician.



# ~~

# /

, !&/88 NIATEF:AL SA{=ETY DATA SHEET MSDS I D # 1117 F'AGE — FRANN: D. DAV I S i= OMPANY 

## THIS INFGRMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR I MF'LI ED, EXCEPT THAT I T I S ACCUFiATE T ~ 

### THE BEST KNOWLEDGE OF DAVI S r_:OLOFS, THE DATA nN THI S SHEET RELATES ONLY TO THE SPEr_:I FI C MATERI AL DESI GNATED HEREI N. DAVI S C:riLORS ASSUMES NCi LEc;AL RESPONSI BI LI TY Fi iR USE Gk RELIANC:E UPON THESE DATA,



### SE= T I ON 1— MANUFAi= TUREF: I NFORMAT I i iN

------------------------------------- y 

### MANUF/DI ST ...; FF.ANN: D. DAVI S COM,F'ANY ADDfESS 1....: P.O. BOX =100 EIhESGENC.Y F'HCiNE: ElE E69-7311 ADDF.ESS 2.... ; 3700 E. OLYMF'IC BLVD. F'F:EF'AF;ATION/REVISION DATE: C: I TY / ST / Z I P ..; LOS ANGELES , C:AL I FO FN I A 940Z3 Lr_u_:AT ION ..; F'F'EF'AF;ER/C:GNTACT I ED E+EDSWCiRTH 

## IHON OXIDE RED I RON %iX I DE RED I NORGANI C OX I DE 

## FrZO3 1117 1 309-37-1 TRADE NAI`1E/SYNCiNYMS...: C HEM I i= AL 'NAME/ SYiVCiNYMS : Ci-IEMI C:AL FAMI LY . . . . . . . : F'KODUC:T CODE •



## ..,........ i= AS NUMBER . . . . . . . . . . . . :

~ . 

### SE.CTI ON ?- HAZARDO11S I NGREDI Er1 T S / I DEI+l T I TY I NF= CiRMATI OId


## --------------------------------------------------------- THIS F'F;ODUCT CiiNTAINS HAZARDiiUS INGF;EDIENTS (Y,N,i`J/A,N/I ): N

CHEI`1ICAL/COMMON NAI`1E C:AS-NUMBEFi 7. PEL-OSHA TLV-t=u_GIH SYNTH I t=: ~



### iN OX I DE RED 1::,09-37-1 NA NA THI S FRi

DUi_ T Ci

NTAI NS CARCI NOGENS ( NTF' , I AF:C , OF ~ ~ 

### SHA )(, N, N/ A, N/ I): N i=HEMI CAL/C OMMON NAME C:AS-NUP1E+EF: % NT1=' I ARC: Ci Sf-IA SYNTH I F:!

iN OXI DE RED 1309 Z7 1 Ni i NCi NC i

l l

(---J

# ~

88 MATEFiAL SHFETY DATA SHEET P'ISDS I D # 1117 f'AGE:
i~ / SECTI iiN 3 - HEALTH HAZAF;D DATA HEALTH EFFEi= TS ( ACl_1TE AND LHRONI i: )- 

### NONE GPSEF.VEDF'F;I MAFY ROUTES OF ENTRY

## N/A MEDI C:AL Ci iNDI TI CiNS AGGRAVATED bY EXF'iSURENCiNE

### EMERGENi_Y FIFtST AID F'Ri iCEDUF;ESSK I N C C NTAC T: WASH W I TH Si iAP AND WATER . EYE r:DNTAC T: FLUSH WI TH LARGE AiMNuUNTS i iF WATER , _ ONSULT 

### AN EYE F'HYSI CI AN.
SECTICih.l 4 - CHE1hIr_.AL DATA 

## -------------------------- Bi iILING F'OINT (F) . .. . : N/A VAFi=iF: F'RESSURE ( ihMHG ) : N/A

~ 

### IAF' I 

### R DENSI TY ( AI Fi= ! 

### ): N/A 

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### EVAPORATI EiN RATE ( B! JTYL ACETATE =1 ): NA

SEC:T I GN 5- F'HYS IC AL HA ZARD DATA 

## --------------------------------- FLASH PO I NT ("IETHOD ! SED ): N/ A

## EXTINGUISHING MEDIAPiG FI RE HAZAFD SF'EC I AL FI F:E FI GHTI NG F'F:C CEDUF;ES

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### iLYMERI Z AT I i iN676

## ~

. ~. / 

### 3/38 iv(ATCI;HL SAFETY DATA SHEET MSDS I D # 1117 SECTI ON b- SFI LL OR LEAH: F'ROCEDURES FHGE 4

STEF'S TO BE TAKEN CASE MATEF:I AL I S RELEASED OF; SF'I LLEDMATERI AL GAN BE HANDLED AS NCiF:MAL SCiLI D WASTE : SC:OOP UF' BY SOMF_ MEANS AND F'LACE I N A WASTE CONTAI NER .

WASTE DI SF'OSAL METHQDSWASTE I"IATER I AL C:AN PE BURI ED I N AN APPF;OVED LANDFI LL OR HANDLED AS I NERT WASTE IN Ai_CCiRDANi=E WITH FEDEROL, STATE AND LOCAL El`dVI RUNMENTAL F2EGi )LATI ONS.
SECTI CiN 7- EXPOSURE GONTROL I NFCiFP'tATI ~ 

### iN 

## -----------------------------------------
VENT I LAT I CiNLOr:AL EXHAi jST i REMOVE AI REQRNE D!JST MEC:HANI C:AL ( GE;uERAL ): N/A 

## SF'E!=IAL ...... : N/A OTHER ...............: N/A RESF'I RATi iF:Y F'I;C iTEC:TI ON-


### " ) I ASH AF'F'F:i

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### 8E}EF: GLOVES i iF; F LASTT I_ I_IR 

### i_Li iTH

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F'REC At 1T I ONS Ti i BE TA -:EN I N HANDLI NG ANll STOF;AGESTOFE DRY AT AMBIENT TEMF'ERATURE AWAY FROM 1=OOD AND DRINE:. MAI NTENAN=E F'REC:AUTI C NSNONE

### CiTHER F'R-EGAUTICiI`dSNi iNE

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## TECHNIGIAL DATA

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# i
~ SECTION Vlll - SPECIAL PROTECTION' INFOqM.ATiOr: ( nCSr

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### SECTION IX - SPECIAL PRECAUT!Oi%S
PAECAUT10•-c Tn RC TAKErv ri ..nr.n itiC. nr.O STJtlirvG -- ---



### ~ Do not b,- e ,th a d„St
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### PAC:E !21 Form O 7 r• :0 Pr.. -'.r 7I



# ~ 1G1

### Haterial Safety Data Sheet



# ~ `AMERICAN MINERALS PRODUCT: 901 EAST EIGHTH AVENUE, P.O.BOX 1569 .. . KJ,NG OF. PRUSSIA, PA 19406 MSDS: AMMNO2 

### Phone: Health & Safety Info 215/337-1100 Date: 12/90 Revision: 6/93

HEALTH HAZARD 2- Moderate Hazard FLAMMABILITY HAZARD 0- Minimal Hazard REACTIVITY HAZARD 1 - Slight PERSONAL PROTECTION B- Glasses & Gloves National PaiA 

### . and Coatings Association Hazardous Material Identif ication System

I SECTION I. MATERIAL IDENTIFICATION Chemical Name: Pyrolusite, #9r4a6ese'_dioxide (Mn0 2 )j 

### Description: Pyrolusite ore (manganese dioxide) is used for many ir}dustrial and chemical applications. It is the source of manganese and all its compounds; largely used in manufacture of manganese steel; oxidizer; in alkaline batteries; decolorizing glass; in ceramic bodies and glazes. CAS#: 1313-13-9 

### Manufacturer: American Minerals Phone: 215/337-1100

( 

### SECTION II. INGREDIENTS AND HAZARDS l Ingredient Name: CAS Number: Percent: Exposure Limits: Pyrolusite (MnO Z ) 1313-13-9 72-80 For Manganese Dust, as Mn, arid compounds CAS#7439-96-5 ACGIH TWA is 5mg/m 3 . OSHA Final Rule Ceiling: 5mg/m 3

. 

### FUME: OSHA PEL:TWA /Mn/ lmg/m 3 ; STEL 3mg/m 3 . Quartz (*) (Si0 2 ) 14808-60-7 1-3 OSHA PEL:TWA for respirable quartz - 0.10mg/m 3 . Uarium, Componeilt of Mn Ore 7440-39-3 1-2 ACGI11 TWAils 0.5mg/m s as /Ba/. OSHA PEL:TWA 0.5mg/m 3 . as /Ba/. Nonhazardous Ingredients (Nuisance Particulates) ---------- 15-25 Nuisance Particulates OSHA PEL: TWA, Total Dust: 15mg/3 3 ; Respirable Dust: 5mg/m . ACGIH TLV:TWA Total Dust 10mg/m 3 ; Respirable Dust: 5mg/m 3 . The product may contain a trace of lead which exists as an integral, complex mineralogical constituent of the manganese ore. The lead (0.0 - 0.2$) (Inorganic) CAS#7439-92-1 listed by IARC: Possible human carcinogen (Group 2B); human evidence is inadequate; animal evidence is sufficient. The OSHA PEL:TWA for lead is 0.05mg/m 3 . A substance specific standard applies (see 29 CFR 1910.1025). (*) A polymorph of crystalline silica. Identified by IARC as a"Probable Human Carcinogen" Group 2A. NTP lists respirable quartz amongst substances which may ("rea aonably be anticipated to be carcinogens".

Page 1--- INGREDIENTS AND HAZARDS continues on page 2 --- Page 1



# ~~Material Safety Data Sheet



## ~ AMERICAN MINERALS PRODUCT: Manganese Dioxide 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AMMNO2 Phone:.'Health & Safety Info 215/337-1100 Date: 12/90 Revision: 6/93

SECTION III. PHYSICAL DATA 

### Appearance and Odor: Black to brownish black and available in various size ranges from granular to fine powders; odorless. I Bulk Density: 125 - 132 lbs/cu.ft. (=17 lbs/gal) Melting Point: >2800°F Water Solubility ($): slight $ volatile by volume: 0 pH (10% Aqueous Slurry): 9- 10
SECTION IV. FIRE AND EXPLOSION DATA Extinguishing Media: Use dry chemical or CO 2 on fires involving Manganese dioxide. Unusual fire or explosion hazards: Although not combustible, manganese,dioxide is astrong oxidizing agent. It may increase the burning rate of combustibles with a flareburning effect. It may cause reignition after a fire is extinguished. Oxygen from the thermal decomposition of Mn0 2 facilitates combustion. 

### special Fire

- 

### Fighting Procedurea: Since fire may produce toxic fumes, wear a sel.f -contained braathing apparatue (eCBA) with full faeopiece operated in the pre§3uredeinand or positive-pressure mode. Be aware of runoff from fire control methode. Do not release to sewers or waterways.

I SECTION V. REACTIVITY DATA I 

### Stnbility: This product is a stable at room temperature in cloeed containere under normal conditions of storage and handling conditions. Hazardous polymerization will not occur. chemical incompatibilities: Manganese dioxi ; is a powerful oxidizer, hence it should not be heated or rubbed with organic mattc: or other easily oxidizable substances, e.g., sulfur, sulfides, phosphides, hypoti:osphides, etc.. Flammable by chemical reaction. Incompatible with hydrogen peroxide; sodium peroxide. Keep away from heat and flammable materials.

I SECTION VI. HEALTH HAZARD INFORMATION I Carcinogenicity: The NTP, IARC, AND OSHA do not list manganese dioxide as a carcinogen. Summary of risks: Manganese is an essential trace element for living organisms. Although found in all human tissue, acute or chronic manganese poisoning can occur from excessive intake via inhalation or ingestion. Manganese dioxide dust inhalation can irritate the respiratory tract and lead to lung damage, pleuritis, bronchitis, and 

### increased incidence of respiratory infection. Large inhaled particles may be cleared from the respiratory tract and swallowed, but small particles are eventually absorbed into the blood. Medical conditions which may be aggravated by contact: Lungs; central nervous system diseases, psychiatric disorders, eyes. Target organs: Respiratory system, central nervous system.



## ~ ~ 

### lrimary entry route: Inhalation, Ingestion
Page 2--- , HEALTH HAZARD INFORMATION continues on page 3 --- Page 2 

# Z~ LMaterial Safety Data Sheet



# ~ AMERICAN MINERALS PRODUCT: Manganese Dioxide 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF M

PRUSSIA, PA 19406 MSDS: AMNO2 

### Phone: Health & Safety Info 215/337-1100 Date: 12/90 Revision: 6/93 HEALTH HAZARD INFORMATION continued from page 2 

### Acute Effects: Exposure to high concentrations of manganese dioxide causes an influenza-like illness (metal fume fever). The 24 to 48 hour illness is characterized by chills, fever, aching muscles, dryness in the mouth and throat, and headache. ManganeeA dust and tumos are minor irritants to tho eyes and completely innocuous to the intact skin. Manganese pleuritis, bronchitis, or pneumonia may also occur. Chronic Effects: Prolonged excessive inhalation can bring manganese into the body via both the lungs.and digestive tract (swallowed mucous) to cause systemic poisoning. Chronic poisoning is usualiy in 6 to 24 month. S}m:ptoms include apathy, anorexia, headache, weakness, and easy fatigue, then clumsiness, speech problems and other central nervous system effects. Progressive and permanent disability can result from chronic untreated manganese poisoning, but it is not fatal. Signs & symptoms of overexposure: Eye contacts Physical Irritation Skin contact: Possible irritation from repeated or prolonged contact to

individuals sensitive to mineral dust. Inhalation: Throat and Upper respiratory irritation. yret aids 

### Eye contact: Flush eyes, including under the eyelids, with large amounts of

water. If irritation persists, seek medical attention. Skin contact: Wash affected area with mild soap and water to remove any dust and

manganese dioxide adhering to the skin. Inhalation: Remove exposed person to fresh air. Support breathing as needed. Ingestion: If ingested, have victim drink 2- 3 glasses of water, then



### induce vomiting, then seek medical attention.
SECTION VII. SPILL, LEAK AND DISPOSAL PROCEDURES 

### Spill / Leak procedures: The product is not readily soluble, however prevent the spill from entering water and waste water systems. Cleanup personnel need to wear approved respiratory protection, gloves, long sleeved clothing and goggles to prevent irritation from contact and inhalation. Reuse all spilled material whenever possible. Waste management / Disposal: The product is not a listed hazardous waste and does not exhibit any characteristics of a hazardous waste, including the EPA's TCLP for toxic characteristics. Follow all local, state and federal regulations for proper disposal.

SECTION VIII. SPECIAL PROTECTION INFORMATION 

### Personal protective equipment: The use of safety glasses, gloves, and long sleeve clothing is recommended. The use of OSHA approved particulate dust respirator in accordance with 29 CFR 1910.134 must be worn for dust exposure above allowabl• sxpoeure

`. 

### imits. 

### Y'

Page 3--- SPECIAL PROTECTION INFORMATION continues ori 

### page 4 --- Page 3

//~Material Safety Data Sheet



## ~ AMERICAN MINERALS PRODUCT: i Manganese Dioxide 

## ~ 901 EAST EIGHTH AVENUE, P.O.BOX 1569 f K.ZN¢ OF
. PRUSSIA, PA 19406 MSDSt AMMNO2 Phone: Health & Safety Info 215/337-1100 Date: 12/90 Revision: 6/93 SPECiAL• PROTECTION INFORMATION continued from page 3 Workplace Considerationst Ventilation: If airborne contaminants are generated during material handling, 

### provide general ventilation and local ventilation in sufficient volume and air flow patterns to control air contaminant concentration levels below allowable exposure limits.

SECTION IX. REGULATORY INFORMATION AND SPECIAL PRECAUTIONS The product contains 72-80$ Manganese dioxide (Mn0 2 ) CASf1313-13-9. Manganese dioxide ie not specilically listed on any Federal regulatory liats, howovar ManqanQse compounds, as /Mn/ CASP 7439-96-5 are listed, and manganese dioxide falls into this classification. Manganese compounds, as /Mn/ CAS# 7439-96-5 are regulated under requirements of SARA TITLE III Section 313. The product contains 1-2$ Barium. Barium compounds are listed under the EPA: EPCRA section 313; de minimis concentration is 1 percent., The product contains 0.0 - 0.2$ lead CAS17439-92-1. The lead is in the form of an inorganic lead compound. The EPA CERCLA RQ for lead is 1 pound. EPCRA section 313 de minimis concentration is 0.1%, and so it is reportable under SARA Section 313. Lead is 

## ~ listed under the following regulatory lists: Clean Water Act Sections 304 & 307, Safe Drinking Water Act Maximum Contaminant Level Substances & Statutory Contaminants, Clean Air Act Section 112, NIOSH Recommendation Substances, RCRA Hazardous Substances & Hazardous Constituents for Groundwater Monitoring, CERCLA Hazardous Substances, SARA Title III Sections 302 and 313, OSHA Air Contaminants & Specifically Regulated Substances, and the Massachusetts, New Jersey and Pennsylvania state lists. Storage Requiremeatat Store in closed containers in a cool, dry, woll-vantilatQd arQa away from sources of heat and ignition. Protect containers from physical damage. Since manganese dioxide is a strong oxidizer, store separately from organic and other oxidizable materials. TSCA INVENTORY: A11 substances contained in the product are listed in the Chemical Subetance Inventory of the Toxic Subetances Control Act. DOT Class: Not Regulated
SECTION X. REFERENCES References used in preparation of this material safety data sheet: Clansky, K.B., Suspect Chemicals Sourcebook, 1992-2 Edition, Roytech Publications, Bethesda, Maryland. Sax, N. Irving: DanQerous Properties of Industrial Materials, Seventh Edition, Van Nostrand Reinhold Co., Inc., 1989.Kirk, R. and Othmer, D., Encyclopedia of Chemical Technology, Third Edition, WileyInterscience, New York, NY 1980. Sax, N.Irving and Lewis,R.J. Hawlev's Condensed Chemical Dictionary, Eleventh Ed., Van

, Nostrand Reinhold Co.,Inc., NY 

## ~ Material SafetY Data Sheets, Genium Publiehing Corporation, Schenectady, NY

Pag e 4--- MSDS continues on page 5 --- Page 4



### :~ 

# ;KMaterial Safety Data Sheet



## ~ AMERICAN MINERALS PRODUCT:I Manganese Dioxide I 901 EAST EIGHTH AVENUE, P.O.BOX 1569 L KING OF PRUSSIA, PA 19406 MSDS: AMMNO2 

### Phone:. * Hea'lth & Safety Info 215/337-1100 Date: 12/90 Revision: 5/93 SECTfON,.XI. ACRONYMS/DEFINITIONS USED IN THIS MSDS ACGIH: American Conference of Governmental Industrial Hygienists CAS#: CAS Registration Number is an assigned number to identify a

material. CAS stands for Chemical Abstract Service. CERCLA: Comprehensive Environmental Response, Compensation, and Liability

Act (also known as superfund)(EPA). EPA: Environmental Protection Agency EPCRA: Emergency Planning and Community-Right-To-Know Act(SARA TITLE III) HMISN: Hazardous Material Identification System, National Paint & Coatings

Association. IARC: International Agency for Research on Cancer mg/m 3 : Milligrams per cubic meter NFPA: National Fire Protection Association 

### NTP: National Toxicology Program , OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit (OSHA) RCRA: Resource Conservation and Recovery Act (EPA) SARA: Superfund Amendments and Reauthorization Act Title III: Emergency Planning and Community Right to Know Act Section 302: Extremely Hazardous Substances Section 304: Emergency Release Section 313: Toxic Chemicals - Reporting - Form R TCLP: Toxicity Characteristic Leaching Procedure



## ~ ) TLV: Threshold Limit Value (ACGIH) TSCA: Toxic Substances Control Act - EPA TWA: Time Weighted Average - 8 hours

Prepared/revised by: A.G.Nighswander June 7, 1993

C~ 

## a~ Although reasonable care has been taken in the preparation of the information contained herein, American Minerals extends no warranties, makes no representation and assumes no responsibility as to the accuracy or suitability of such information for application 

### to purchaser's intended purposes or for consequences of its use. Page 5--- End of MSDs --- Page 5



## ~~2



### 1:_i 1 z/89 " -!Y!ATEF:AL Si?FETY DATA SH`ET MSDS I D # 86 ~ ~ 

### PAGE FRAP•lV D. DAVIS COMF'ANY THI S I I`dFOSMATI CiN I S FUR(VI SHED VI THOUT WAI;RANTY, EXF'RESSED C iR II"F'LIED, EXi=Er'T THAT IT IS Ai_i_URATE TCi THE BEST E:NOWLEDGE OF DAVIS

~ 

### C:CiLiiRS. THE DATA CiN THI S SHEET RELATES i NLY TCi THE SFEC I FI C MATEFI AL DES I GNATED HEFEI N. DAV I S r:OLOFS ASSUMES N ~ 

### LEGAL RESP ON 

### SI DI LI TY FOF; t1SE OR F;EI I ANi=E UF'ON THESE DATA. THI S PF;ODUCT L= ~



### :P:TAI NS TFiAGE Ah1OUNTS OF C:HEMI GALS CONSI DERED PY THE STATE OF GALI FORNI A TO BE C ARGI NOGENS On REPF;ODUC:T I VE TOX I CANTS , C1SE CAr;E WHEN HANDLI NG ANY CHEIrI CAL F'FODUCT SEi_TI C iN 1- MANUFACTURER I NFi iF;l`1ATIGN 

# -------------------------------------
# 

# 4 MANUF/DI ST. ..: FF:ANK D. DAVI S ADDFcESS 1 . . . . ; F' . O. EsOX 2Z 1 OC ) Eh1EF:GENC:Y F'HONE : 213 269 7Z 1 1 

### ADDFiESS 2....: 3700 E OLYMF'I C ESLUD F'REF'ARATI ON/F.'EVI SI ON DATE : 6 8 87 CITY/ST/ZIF'..: LOS ANGELES, CO. 9002Z LiiCATION, ,; PREF'AF:EF;/CONTAGT: ED BEDSWORTF-+

TRADE NAME/SYNC qVYMS. . 

### C:HEi`iI C:AL NAME/SYNi_iNYMS I I F:!=i`N "OX I DE i_ HEMI _ AL FAMI LY .......: i F;ON OX I DE FORNULA . . . . . . . . . . . . . . . : 0 12 F'r:GDt )C T C ODE . . . . . . . . . . : 

### 8bi ~ CAS NUMBEFi ............: 1111 86 4



### SECTION E- HAZAF;DO'•JS INGr=;EDIENTS / IDENTITY INFOF:MATICiN 

# ----------------------------=---------------------------- THIS F'RC iDUC:T C:C iNTAINS HAZARDOCIS I Nt;F;EDIENTS ( Y^N/A, N/ I) ; N

CHEMIGAL/COMt'ION NA"iE C'AS-NCIMBEF 'i. F'EL-OSHA TLV-ACGI!-' SYNTH IRON OXIDE EsLACK 1E3= 85 4 3.5MG/rr,:; 3.5mg/m: ~ 

### THIS PRODUCT GONTAINS CAF;i=INOGENS (NTP, IAF;C:, C R OSHA) (,N,N/A,N/I); n

C:HEMI C:AL/GOM^1ON NAME GAS-!=at 1MEsER % NTP I AF;C OSHA Synth 1 t'on oxi de bI3CGi 1333 86 4 no no ni i



### ~



## ~~ 

# 6. ? 

### T ERAL SAF ETY DA i A SHEF_T I`iSDS I D # 86 -)

SEC TI CiPJ S- KEALTH HhZPRD DATA



# ~ HEr+LTH EFFECTS ( ACUTE AND i_HF;CiNI i= )- fioiie G<fioWri o't.fiet' t.han pGc,s1bIe t.CiiipoY - 3r
- 'y di5cornfort d'_tC ±o 1rhaIaL1on of 

### DUST i=i iN:_ENTF;ATI Oh•1S ABC+VE THE FERMI SSI BLE EXr'OSURE LIMIT.
1='RIMAF:Y F:Oi_iTES OF ENTRYI NHALATI +!N YES SII 1'd NO I NGESTI ON YESMEDI CAL i=ONDI TI ONS AGGRAVATED BY EXF'CiSt 1RENONE F;NOWN Oi'HEFi THAN MENTI 0NED I PJ HEALTH HAZAFiDS .EMEFGENr:Y FIFST AID F'ROCED!jRESSE:I N GONTACT WASH WI TH S ~ ~ 

### AF' AND WATEFi , EYE C ~ ~ 

### NTAC T FLt 1SH W I TH L"HRi;E A! 1T , WATEF: i_ ONSULT F'HYSI C I AN . I NHALATI ON REi•1C iVE FROM DUSTY AFEA .

SE =TICtN 4 - GHEMIi:AL DATA

--------------------------


### E'OI L I NG F'i

~ 

### I PJT ( F ) . . . . : NA SPEC:I FI C GiAVI T`{ ( WA?EFi=1 : . . . . . . . . . . . . : 4.6 vqPOR F'F;ESSl1FiE ( MMHG ) ; h•lA F'ERGEN T Vi , LATI LE LjY VOLt lME ('.'"« ) , , , , . , , . : NA
1. 

### ) "O!_: DENSI TY ( AI F:=1 ): NA EVAF'OF:ATI ON FiATE ( =1 ): NA SOLUE{I LI TY I N WATEF:- 

## NILAPF'EARANCE AND ODOF I NFOf;MATI C iNAMORF'HOUS BLA+_ E; F'OWDEF: ( N ~ 

### ODC ir: ) MAY BE F'ELLETI ZED

SEi_ TI ON 5- F'HYSI C AL HAZARD DATA

FLASH F'OI NT ( METHOD l)SED ): MAY I c;NI TE FLAMMABLE LI i'9I TS : LEL= NA UEL= NAEXTI NGl1I SHI NG MEDI AC=H'=MIC:AL EXTINGUISHEFi MEDIA, WETS F'OOFiLY WITH WATEFi,SFEC I AL FI F:E F IGHTI NG PRCiC EDUnESNGRh1AL FOG ON PJOZZ LE JET AFF'LI CATI ON EXi_LUDE AI RUNUSt_1AL FI F:E AtiD EXF'LC iSI CiN HAZARDS

### r:ARBON MONC iX I DE AND CQE ARE F'RODUC TS C iF SOMB!JSTI ON USE AF'r'F;Or-'RI A T E nESFI RATOR FOR FF:i iTEi= TI ON ;=iGAI NST Pi SSI BLE EXPriSUF'E TO C G TG CO2

1"NC=OMF'ATI DI LI TY ( MATEFI ALS TO AVOI D)- C=HEMIi=AL OXIDIZING AGENTSHAZARDOUS DECOMPGSITIUN FRODUC:TSPOSSI BLY C ARBON MONC iX I DE WHEN BUF;NI NG


## ~~

### / 1 J,' S9 . r1ATERAL SArETY DATA SHEET NSDS 

### I r: ## r-'AGt - 4 SEC TI ON 6- SPI LL OR LEAK PEO!_:EDUF:ES



## ~f?EF'S TO BE TAE:EN i=ASE MATEF:I AL I S F;EL EASED OR SF'I LLEDHANDLE AS NORMAL SOL I D WASTE , SGOOF' UF' BY SOi•tE MEANS AND F'LAi_ E: N AWASTE r:ONTAI NER .

WASTE DI SF'i iSAL i IETHODS - 

### WASTER MATERI AL !_ IN BE BURI ED I N A APFF:OVEn LANDFI LL OR HANDLED ?S I NEF:T WAS T E I N Ai=i=ORDANi_E WI TH FED, STATE AND LOi_AL ENVI RONMENTAL F;ECULATIONS.


### SECTI CiN 7- EKF'OSURE C:ONTRi iL INFORMATI ON


## -----------------------------------------
VEr•JTI LATI C UVLUC AL EXHAUST : K 

### SFEC:I AL . . . . . . 2 NA MEC:HANI GAL ! GENERAL ) : NA 

## iiTHER ...............: NA F:ESF'I h:AT ~ ~ 

### nY F'RQTEC TI ONNIGSH APPROVED FOR DUST, MISTS AND FUMES, DO NiiT EXi=EED l:SE LIMITS OF THE F:ESPI FATOR.



## ~PRQTEC:TI VE CLOVES

### FUSPER ,C LCiTH OR PLAST I C: CLCiVES .

4iTHEF; F'r:0TECTIVE EQUIF'MENTP: P,OTHEF: ENGI NEEFiI 1`Jc; GONTEOLS

### N A WOF:F; PF:Ai_TI+_ES 

### DO NOT STORE NEAR FOOD AND DFiI NK , WASH Er:POSED SF:IN F+!Fi HYGIENE rUnF'OS`S.HYGI ENI C FRACTI C:ESSAME AS ABCiVE



## ~~

### ,:/' 9/B9 • .MATEF'AL Sr '1FETY DRTr? SHF_ET MSDS I D # 86C) PRGE

SECTI ON 8 - SF'EC_ AL F'hEi=:AUTI i iNS



### PREi=AUTICiNS Tii BE TAE;EN IN HAI`dDLING aND STQRAGE

### NAMAI NTENANCE F'F2Ei=:AUTI i ;NS

## NA iiTHER PRECAUTIi-iNS=j 

## NA ADDI TI GNAL C: ~



### iMh1ENTSSTOnE AT DRY AMBI ENT TEMF'ERATl1nE AWAY FROM FOOD AND DRINE:,

SEC:TI O!'d 9- HAZARDOUS PIATEFiI ALS I DENTI FI C ATI ON SYSTEM ( K

O=MI NI I`1AL HAZARD 1=SLI GHT HAZAFiD 2=1"!UDEF;ATE HAZARD 

### 3=SERI OUS HAZARD 

## P-SEVERE HAZARD

~ 1 HEALTH ....... 0 - 4 . . : 0 

### FLAMABILITY..0 - 4 ..: 1 F:EACTI VI TY . . , 0 - 4 . . : C) 

### PERSONAL PROTECTI ON . . :

SEC:TI ON 10 - 

### T ECHNI CI AL DATA
LBS/g31 s @ 25 C' 38.3 

### SF'EC I FI C GFiAVI TY 4.6 OI L ABSORPTI GN 2 1 FE203% 94-96

~ 

### loss on ignitiorl 1.5

~ ph 1 CJY. SLl!RRY

, i b

I

i

/

# Material Safety Data Sheet

Substance Identification

,__ 

## ~~ Identity: CAS #: 1308-38-9 Trade Names: CHROMOX Manufacturer: Emergency: Chemtrec One Prince Plaza 1-800-424-9300 Quincy, IL 62301

_ 

### 217-222-8854 

# Components and Contaminants Chemical Name CAS # OSHA PEL ACGIH TLV Percent 

### Chromium Cr+' 74440-47-3 0.5 mg/m 3 0.5 mg/m 3 (TWA) 30-45% Cr Silica, Crystalline Quartz respirable dust 14808-60-7 0.1 mg/m 3 0.1 mg/m 3 (TWA) 1.2% SiO Z 

# Physical Data Boiling Point: NA Specific Gravity (H Z O =1): 4.4 Vapor Pressure (mm/Hg): NA Melting Point: 3350 - 4000° F Vapor Density (Air =1): NA Evaporation Rate (Butyl Acetate =1): NA Solubility in Water: insoluble Appearance and Odor: black powder, no odor. 

# Fire and Explosion Hazard Data C Flash Point: Not combustible Flammable Limits: LEL NA UEL NA Extinguishing Media: Foam, CO 2 , or dry chemical or water. Special F'ire Fighting Procedures: In the event of fire, wear full protective clothing and NIOSH-approved self

### contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Unusual Fire and explosion hazards: Not combustible. 

## Reactivity Data Stability: Stable under ordinary conditions of use and storage. Conditions to avoid: None Known Incompatibility (materials to avoid): None Known. Hazardous Decomposition or Byproducts: None Known. Hazardous Polymerization: Will not occur. 

# Health Hazard Data Route of Entry: INHALATION: May cause delayed respiratory disease if dust is inhaled over a prolonged period of time. SKIN: No. INGESTION: Ingestion of Iron Chromite may cause abdominal pain and nausea.

Iron Chromite, Page 1 April 1991

### Health Hazards (Acute and Chronic)

Carcinogenicity: Signs and Symptoms of Exposure; Aggravation of Pre-existing Conditions: 

## Health Hazard Data (<ont.) 

### Respiratory disease may result from prolonged overexposure. Can causc eye irritation. NTP: No IARC Monographs: Yes (Silica)Excessive inhalation of dust may result in shortness of breath and reduced pulmonary function. Symptoms of silicosis include impaired pulmonary function and wheezing.Persons with impaired respiratory function may be more susceptible to the effect of this substance. Emergency and First Aid Procedures: 

### IF INHALED, remove to fresh air and seek medical attention for any breathing difficulty. 

### IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. 

### IN CASE OF EYE CONTACT, flush eyes immediately with water for at least 15 minutes. Seek medical attention if irritation persists. 

### IF INGESTED, induce vomiting immediately by giving two glasses of waterand sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

## Precautions for Safe Handling and Use Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory protection. Recover uncontaminated material for use. Vacuum or sweep remaining material, keeping dust to a minimum. Waste Disposal Method: Dispose of unreclaimable material in a RCRA-approved waste facility. Handling and Storing Precautions: Protect containers from damage and keep closed when not in use. Other Precautions: Observe good personal hygiene. Wash after handling. 

## Control Measures Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or is anticipated. OSHA standard 1910.134 or ANSI Z88.2-1980 speciGcations are recommended. Ventilation: A system of local and / or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust is generallv preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to theACGIH document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details. Protective Gloves: Yes Eye Protection: Safety goggles are recommended. Other Protective Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonged exposureto skin. Work and Hygienic Practices: Observe good personal hygiene. Wash after handling.



## SARA Title III Section 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-to Know Act of 1986 and of 40 CFR 372.45: Component CAS # % by Weieht Iron Chromite 1308-38-9 30 - 35% Cr This information must be included in all MSDS's that are copied and distributed for this material.

Iron Chromite, Page 2 April 1991 

# P(

### V 

# 1____

~ 

## ^ U. S. DEPARTMENT OF LA80R Form Approved



### ~ Occupational Safety and Health Administration 0M8 No.44-R1387



## ~ 

# MArPER.IAI. QAFETY DA'I'A SHEETI

Required under USDL Safety and Healtli Regulations for Sliip Repairing Shipbuilding, aiid Siiipbreaking (29 CFR 1915, 1916, 1917) 

## SECTION I ltanufacturer's I1ame l;nierenc Tele lio

~ :e i:o. 

### WYO-BEi
~ 

### , INC. [(40 

## e ) 

## 2 ~ 2-635 ~ ress•(
~ o, Street, C;ity St nd Zip Code) 

### 1242 N. 28th Bi 11 i n s f 

## ~IT ~~~0~ emica

~ vame and S nonyms T'ra 

### d e Nan , ~ and nony is 

## od ~ 

## u orl mori ~ 

## lonite (western Bent_onite H drogel , Bi g f ~~ 

## rn , ~ 

## nvi rooel Inor dn1C Mineral ) Empirical Formula:"R11 .,66 (A1 3.20

~ Fe .40

~ M9 .40 ) (S1 7.75' A1 75 O20 20H2 W{.e..e IIDII _('

~ }inn• IIN11 _ V nk I o 

## SECTION ll =HAZARDOUS INGRED(ENTS PAI:ITS, PRI:SERVATIVES & SOLVLrITS % TLV Units) ALLOYS A:1D METALLIC COA1'INGS `/, •rLV f(U 

### n i 

### ts Pigments N/A Base rfetal 

### Catalyst Allo s Vehicle I N A I"fetallic Coatin s N/A 

### Solvents N A Filier i`ietal 1'lus 

### Coating or Core Flux N/A Additives N A Others Otliers IIAZARDOUS i•IIXTURES OF OT'IiER LIQUIDS, SOLIDS, OR C!1SL•'S o (Units



## Low concentrations of cr stalline silica (Si0 ) in the form of quartz, cr stobalite and tridymite may be resen See in the bentonite dust. Sec.



## SE CTION 1 I l- PHYSI CAL ' DATA l3oiling Point oF. S ecific Cravitv H , )0=1 

## 2.35 Vapor Pressure (mm Hg. ) N/A erce it, voiaLile b Vo Id A / Vapor Detisit (Air=1) N/A E vaporation Rate =1 N/A Solubility in IJatcr. 

### i'pcarancc and Udor



## SECTION IV- FIRE AND EXPLOSION HAZARD DATA _ ,l5u ui[tl' PlctlluLl uscd flammablc Llnilts Lel UeI Extinguisliing 1•ledia A Specia F'ire 1 iglltlilg 

### 1'rocedures N/A
't:usuai Fire atid L:<plosion flazards N/A Copied from — Form OSHA - ZU 

### Page 1 (Continued on reverse side) Rev. May 72e

~ 

### )_

## ~ ~ TUCKY-TFNNESSEE CLAY CnMPANY
/.',AYFI::D, iCEViUCKY 4:066 PtiONE (502i 247• J 36I 

# MATERIAL SAFETY DATA SHEET

SFCTIOti 1 Mt,NUFACTURER'S NAME E 'ERGENCY TELE"rHONE r:G. ~ 

### Kentucky-Tennessee C1ay Comrany 502-247-3061 

### ~ ADDRESS ~ P. 0. Box 449, Mayfield, Kentucky 42066 CHEMICAL NAME AND SYNON'"iS TRADE hAuE AND SY':0'.YtjS

~

. ` ` N i r L J C~ 'E"' I CAL FAM I LY FORMULA 

### Hydrated Alumina Silicates , None Y 

## S£CTION I I - HAZ:'1RDOUS Iti; REDI£tiTS

Some Quartz

-

### See Section V


## S£CTIOV III - 

## PHl'SICAL DATa

. 

### SPECIFIC G;

~ 

### AVITY (H20 = 1): 

### 2.6 APPEA=,f,NCE .A'dD ODOR• 

### Cray Color - Earthy Odor When Wet



## S£CTIO\ IV - 

## FIRE A'r'D L

- XPLOSION }1AZ.ARJ D.aTA None


## S£CTIO'v 1' - HzALTH 11A=:;RD L`.a7A Tr.•ES-DLD L i"1 7 Est ir.ated to be or ra e ~ 

### r te n t


## _ O '

- o :h , EFFECTS OF C'JEREXPOSURE: Long time expos,,re to excess;ve co-cen*_ration ecy

~ e har-`;.-I to resp i r2:Ory ;ys'e"



### _ r . ~ 

### .7^.P

~ ~~IL

0



### SECTIO'v VI - RE.aCTIVITY DATA

None


## SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO B.E. TAKEN Iy CASE N,ATERlAL IS RELEASED OR SPILLED: Handle rr.aterial in such a manner to avoid excessive dusty conditions 

### wASTE DISPOSAL 4ETHOD: No special precautions except to avoid excessive dust



## SECTION VIII

- 

## SPECIAL PROTECTION INFOPMATION RtSPIRATORY PROTECTION (specify type): Dust respirators approved by OSHA 

## VENTILATIC`l - LOCAL EXHA'JST: Suggested fo r fugitive dust - 

## PROTECTIVE GLO`:ES: Not required • 

## EYE PROTECTION: Not normally required except in extremely dusty areas 

## OTHER PROTECTIVE EQUIP`1ENT: Not required


## SECTION IX - SPECIAL PRFC:lUTIO`S

PRECAUTIONS TO Bc" T,;KEN IN HANDLING AND STORING: See Section V11

~ 

# - .-.

~ 

# W

### f]RK

- 

### 2

- 

### M P1UN 14 

## :48 FAX K0, 915135857555 P. 02 GASCO INC. CORN PRODUCTS INTERNATIONAL, INC. MATERtAL SAFETY DATA 3HEE'T 401 The West Md $uiU 480 65C0 $oulh Aroher Road COlnpih! W!!t WiiMlS tiequkest ~ 

### in certiada etobwoive. ontwo WC 6P7 Sedfad Paac, iL 6oso1-1933 oBHA R"ttlroments in U8A IotdEmerg Phonm (416) 820-2300 lMOMrg Phalla: (7oe) 60,4714 Prepared nn: 2J9r98 sapetsedes: 1/6188 FAX (416) 62NM FAX- (708) SMU4 Sr: D.

— ~ - 

### Fio

~ 

### naaas lCa .r. Pariaer IUS/U -■ i . uwnri i a■■ rri 

## PftODUCT: CERELOSEV DEXTROSE 9 02001 0 CAS NO.= 50-99. 7 

# HAZARD IDENTIFICAI'10N CasodlCom Products is unaware of any 

## health ha zards for this preduct. 

# Dust ftm thfs 

# produd rnay burn explosiveJy. The conditions under whlch 

# this may occur arre not known. Avoid creating dust or exposing dust to ignitlon sources, Use antistatr'c

no odor or taint cerrea/ odor. 7' I : %• 

## l it FIRE and EXPLOSION HAZARD DATA 

# Flash Polnt (m®thod used): 

# N.A. Autoignition Temperature: N.A. Speoial Fire Fighting Procedures: 

# None Flammable Limits: 

# N.A. Extlnquishing Media: Water Unusual Fire and Explosion Elazarcls; 

# Dust clouds may be lgnited by any energy source and burn explosiv®ly. Avoid open flames, e/ectricat 

# soarks. static 

# electrrdtv and snarks 

# from weldino eauinment. Hazardous wlll not 

# Qcxur, No hazardous decompositfon products. 

# TA : No 

# IARC: No Route of Entry: ingestion:

lnhalation: 

# Skin: Eyes: Effeots of Overexposure: Acute 

# Not a hazardJ



# Not a hazard. Not a hazard. 

# Corttaot may cause 

# temporary rr7ild Irritatfon. Ingestion: Not a hazard In normal Industrfal use. 

# tnhatatlon: Not a hazard. 

# Sfdn: Not a 

# hazard. i+yes: Corltact 

## may cause 

## temporary mlld Irrltatton. 

# Chronic Ingestion: Not a 

## hazard in normal industrial use. Inhalation: 

## Not a hazard. Skln: 

# Not a hazard. Eyes: Contact may cause temporary n"lld irritatlon. 

## Emergency and First Aid Procedures:

ingestion: Get medical attentlon forindividuals who ingest large amounts, 

# inhalation: 

# Remove fo 

# fresh ar'r. Eyes, skin; Wash wlth 

# water. ot 2 S- j

## MR- 2-98 M0N 14:50 FAX K0, 915135957555 P, 03 CASCO 1NC. CORN PRODUCTS INTERNATIONAL, INC. MATERlAI. SAFETY DATA SH€ET 401 1'he Weet Maq 6utte 480 ®50Q Sot* Archer Road Compries w1tlt YVF4MI8 Repvirements in Canada ftbioobe. Mta,io ASC 5157 9edlced park, !L e0° ,Q1-1933 OStiA RmQnirernenfs in U8A UfdEnwV ?FwM: (416) a2G230o InfdEmarg taheNe: (709) s63-6714" Preparad on: Wa/se supetsedes: 1Aa199 

### FI1Xt (416) 8200W FAX (748) 56:i-66aZ Ar. D_ Nobbs (Canada) J. Patket (UBA) 

# PRODUCT:

~ 

# CERELpSEO DEXTROSE, 020010 CA$ NO.; 50-98-7 

# PRECA UTfONS F 

# OR SARE H ANDLING AND USE Precautionry $taternants: 

# Avofd creating dusf clouds, Neutraliz,ing Chemicals: 

# None ' If Materia! is Released or Spilled: 

# Folrow a# regisrative requlrerrrents for non-hazardous waste 

# dlsposaL „.

. ,



## thod R

~ 

## ; Cry sweep, dy

~ 

## sposal.



# Cleed (fly wgraft?puse, ambient condltions, 

# RW1et1bh 'R6quirertients: Loca! Exhaust Personail Prot®ctive Equipment: Eye: None Gioves: 

# None Oth®r Clothing

: 

# None Respistory Ptotedort: tlse 

# N10Shf approved respi 

# rator to limrt exposure to dust when dust f 

# rom product is present REGULATORY INFORMA 

# This product is included in the TSCA inventory of chemicai substances; in the DSL In Canada FDA has affrmed this product to be GRAS in the USA: defined as a standard food in Canada DOT; Not estricted 

# IATA lVot restricted The ettached data has been compiled from souroes whloh Casco/Com products IntemaNariat. Inc., in good faith, bClieves to be depehdable and is aoourata and relfabie to the best of our knowledge and betieL Fiowever, Ca6ee/Cem Products Int®rnational, Inc., cannot maice any werranty or representation raepaating the accur•acy of completeneas of the data and assumes ne respansibifity for atty 

### Aability or damayes relet9np ttwfeto or for adVising you regard;ng th® protection ot your employees, customers, or others. (Users should make their own temts to detemtine d+e appticabifityy of suoh informatton or the suitabMty ot any produots tor speoifb use.)

Page 2 of 2U-. y -- _ _

. -1 • . ~ ~

~ ' ~ ~ . .. • ~ .. .-t

~ t•.

~ -, •M

~ ' ✓ , ~ ,',.. r ~~,"~~ ,~ , . 1 ~r~ 

## U.S. dEPAFRTMENT OF 1.A8OR OM~ MO. M•1133i ~ 

## ONmpetionsl,Sahty and Haafth Adlnirlistrati" 

# MATERIAL SAFETY DATA SHEET Raqulftd unda+ USOt. Si1KW aeu! NRa1th Raquiniuns ror Shio Aapa:.tnp. " , Shipbuild'u g, arfd Shipbrpkinp (29 CFii 1915. 1916, 11017)

Mt#rl

~ • ~ i l.r; ~'~I:~ M'NOMi NO. ,, s ~



## 7492

, . . . .. , , • . .... ~~.

~.~ 4ti'=' ~ 'S~ ~ • , . .. w ~ ~ r. 

## :~ 

## J 07336 N~~~ TIMO[ NA1rt 4M0
~ VNANVMs 

## PP li-i.c ~i~ 

## ,;obe rikote noxgadtc ma.iieral composizj on= P ATHAU al umi.num silicate, wi t 

## h

. ~ 

## SECTiQN 1 

## 1 - HAZARDOUS iNGREQiEAITS iY11NTfr Nl ~ 

### iLQVATtVti. ~ 

### iD+LVlqTi !3 ttv A4LOVt 1WD NETAbLIC COATiWi M tt ~ 

### nlbi "i[ MtTAL M*w4V*T A1.LAVS

•4idf

~ M1S UKTw1.1.IC 60s# YeN" f`1lytiR MRwt n.us caAT+.fa ow coRt FLUX I~ OfTtvq aT uc ~ s

M

.

HAZA11tlpA MtXTNREt OP OTNi11 LIO1310l. itlLtDir OR OA;Ei x ( T 

### y~ pf



## SECTtON t I1 • PHYSICAi. DATA 11YM4 vofNf &+1 LOUC1>rlC n11AVITV lHyO-11 

## JILA `

~ H,c VpA
~ p3Rt r ~ ~! [RCENT, VOyAYikx rV voLUMf! M „ tl iONOEMS3TN tAlat

~ T1 NI ~ iV

~ AAT10N IIAtE -- 1 •1! IC}1

~ ,urfL171 ~ Nr wATtR ' - ~ ' +! t 1 tARANC ~ Ah0 OOOIt •

. , a
~■ 

## 'SECTION IV • FIRE AND EXPLOSION HA2ARD DATA

~ 

### Mrwf ru>rf+wut

~ 

### .faa

~ 

### n w uw _ 1MO~tMfi wf I+411T M

~ CtOU

~ q - -

111111. Rlllt

~I~ - r ~■ ~ .~ wrr.y...r. ~~. .. . . .. ..._.^

~ l++


## ~ / '

## IA 

## 16 

# unpag , L



## M I " 

# m ... -1

~ . Id.,



## SECTION V HEALTH HAZARD 

## DATA clay <J 11 6 

## L

091mg"cv "C P'SIRST 4610 PROCKOURES 

## Skin 

## Eofitacr 

## i WaSt ,

with sor.

~ 

## > ,tizd 

# Fltish with

~ 

## dftfac t i 

## Soul

4 

## " - ' N 

## SECTI0 1 Vi • 

## FtEACTIVITV 

## DATA IA04WIry CdftDITIONS TO AWPIO tlNftArLC 

### lTABLt x - -

12A11001JS DECO1AMSITIO04 PRooUcTs IANCKXA I MAY 0 Gun ocevot



# SECTION Vit 

# - SPILL OR LEAK! , AOCEDURES PS TO U

— TAIARN Uo CASC MATE$ 1 14AL. iS RELICASIED S ' F " t SPIL.6CO

i i n Msp

~ o"&L IMETMOC


## control r!MIstions 

## SECTION Vill • 

## SPECIAL PROTFCTION INFORMATION

Should 

## km

goylvg OLOVIS I IVE PROTECTION



## SECTION IX 

## - SPF-CIAL PRECAUTIONSYJJ% l'1L/ 5t3 1C : +-11



### 07/0111991 00:25 14U. bd.] r'Liv

~ l 

### 120ra5270373 

### 12065870373 SEATTLE POTTERY SPSP PAGE 08

... 

## ~ `" ~ '~ ..•'. 

## ~ ..0. 

## ~~ . ~ . . , 

## MATEHIAL SAFETY DATA $HEET .. ... forms to OSi3A Na

~ 

## eard Cvmmunieatiort Std. • 29CFR: ~g~~}.i~ 

## p0y Ma.x.oleM O

~ 

### a+ y • • , ~ 

### °• . ... • '1+ROD.t

~ 

### CT iQEI

~ 

### tTIi'!GA Ti



### 1 •

_ aW W+tl .1..

...... ~ti:~•~i.T

: '. ~~~.~ Zi , • . .

, . ._ - . 

# r linae

~--~ ~ 

### DATF



### . ... • Pltl STATE 21P



### . ! : pA40t1CT INGREdtEK'{'8 1D10R COMMON NAME I r



### J : S 

### ,

. --- --- - , elp

~


### b i R

— d F

•

.

w `

It • PIiY$iCAL DATA BOIL1NG PC!AYT VAPOR piiESSUE+E SPEC1PlC GRAy1TY MEITING POINY 

## N A N/A 2. 

## 56 1740 — 1T85°C SOLUBILITY IN wATER VAPOp DENSITY {AIR Pf-AC'ENT VOLAT+LE EVAPORATION RA7E 

### i liA NIA N A APPEARANCE ANO ODOFt 

## Buff coiors8 powder. odorless

--, Itt . f^iFit: AND EXPLOSIOPf OATA FuSt

~ l Palv7 j

~~ 1Gmfl9blE ft.AMMABL

~ ` LltutlTS IJ

~ MA L LIMITS L G U6L 

### A A ,ExTINCiUtSF{lNG U961A SrI!CtAL R1NERIGMTINp pROCtDLIRE$

- -- I ""--"' ur ~ w ~~~ ..i ,r 11 Illial

~ r•11Y .w. .
........ UNUSUAL FIRE OR EXPLOSION htA,?Jl1tbS 

### rit . iiEAt.TH HAZAAO tNFORMATtQN FtAZARD 8Y RORlYES OF EXfiOSURE {Indlcate chronic snd ecute) tkNALAT*N 

# ftME W,1 inhalatj.ats ot &sst ma cauge 4layecl 1. ' (sfliaosfs} tr

~ 

### CttsTta, tllt/A

_ EYE _.
~ - $KtN CONTAC7IASSOpPTIQN $1GN$ AND S1IIMPTOMS ASSOCIATED WITH EXf'OSUFtE OVER TLV 

### Vx2ft t@

~ 

### m



# ~ _Iana Lertn - tpay cause siliaosis, , a c'hrtanic disease af the lqr,gs marked by aoute fibmsis 4A£OIGSL CONmt10NS wMICw MAY AE AGGRAVA7ED

~

~ 

### ...r_ N=* knorom - - — - ~ 

### ... ~ 

### • ANY C+P PAAT / LISTED AS CARCtNCIGENS7 {N'TP.IAFIC. OS W120658?0373 

### 07/01/1991 00:25 12065870373 SEATTI.E POTTERY SPSP pACE 89

V HEALTM NA2AR0 6NFORAIIAYIQN (COS tinved) 

### `EMEFIGENCYJFIRST Aip PROCI6DURS5 , *wl 4ATION 

## _i

~ 

## c?'u ~ , 

## t0 fresh_

~ 

## ir 

## , cxmsult vhvsician aF,Q/or obtiain aar>

~ 

## tar

~ 

## t

~ 

## dical assistanae, as rneo

~ 

### ss~ INCiESTfGN

~ 

## - . ~.~•~.. ~ 

## ...,..... EYE GONTACT 

## k'lush with wa
~ 

## r; oonsult pMysician snd/vr vbtain campetant medical assist=ce, aS necessa:

Ill;' 

# ~ " , CONDlTIONS F" SAFS 1JSE (1Nhon over TLV)

~ ,o•-.._....-•,

~ .. ~ ,,•

~ ........ . . . 

## tJo symm ~ 

## MM/M_SHA

_ re!EiratAr if dust is p'resent fiY@ PROTECI'ON

_~ 

## '.

~ 

## "'` .

~ d ~7 1 ~~~...~..~•~ . .~.~--~ 

## ..,r..,,

~ 

## .__ PRQTEG" GLOVES 

## c*.icw1

~ -.. ~ ... ~ OT'rISFt RAOTECTIVfa CLOTMING&OttrPMENT

- 

# lam vg inw r. YENTtU1T1pN MiEOUIftMENTS OItlE

~ 1C9!?a

- - 

### Vll . REACTIVITY DATA 13 MATlRIAL SYASLE7 

# ~ WILL n"ZARDOt75 pOLYMER1ZATiON OCCUF? 

## Yes ` NO

~ OMPATl811,11'Y CC7ni01T JNS TO AVOlD NOI]E3 )Q1CW1Z }CnG713 MAZAFippVS DECOSwPOSI*ION PR40UCTg NDIIe VIII v SPfLL Ofl LEAK PiiOCEDURSS :TEF'S "G bE 'Ar.6•'. .- ':.: 

## If t

~ 

## tyc

~ 

## taminsted, recovex and reuse if cmM'aated e cxlllect in Suitab3e ccntainers for d' al WACf EDISPpsAL METHOD M3] ~ 

### bE, bwisd Spp=ved ZSlid disposal famlity 1T1



## acoorddr>:oe with fQdeml, tt,ate, arld Iocal rec3ulaf.iions A;qq 

### Vca X *w N1lMQER ,^.ERCLA !S:MPrtund1 AB"TABLE QUAAiTITY ;l ~ 1 f7£GULAfEb
~ OQT PROpER SHU'PI1VG NAht£ ~ Jat rt

~ r.n ~ : LASS ~ rp ~ T ~ :iNO ~~ 

### Yep X Ne 1 IX • SPEC{AL PR 

## E CAUTSOHS SPECIAL PAECAUTIpNS ft* 14ANpL1NG ANi7 STOR^GE 

## Ayoid b ~'~ 

## athirx ~ 

## dust

.

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C+TKER PRECAUT1OniS 

## NM1!

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### ~~~ NNHIQ tllp if11L1rTnt,p ~ arid e

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### PAGE 01

... ~
~ 

## SEAFILE pOt'FER MMY, It1C. 36 W MAJ,lFORo 

### WArn.E wl► 

### 96134 IQCAL 587-0574 0 (8C0) 522•1873 

### MATERIAL SAFWY t)ATP; SI•iM



### 9 C 

### . TICK I_120TIElCaTl al EtR;RGENCY 1SLEAHOrE 1ilWR 1 • ~ .v~ 1 CF
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.. .~ ... ~ .■ .... .. ~ — ! MATtIf1Ati OR Ci1rOKNT

. Of.ClPAT[tYt1LL EXP06ttAC L! 11TS I ! • G41M h A[Ciit T1tA (1986r87 ) I 1 Cebtl! lkidr 300x I t Cab.st 70-71x aa Cabalt Otidr ' Ca Wde 0,1 .q/0 s. Le 0.1 .v/6 3 ss Cv t i MlrJnl l+sa tlrn 1; se Nicicel Adde (CA5 01)13-99-1) Ni Oride

~ sr wr .r. . ~~~~r r+ 1.0 og/b3 M N! 1.0 69/43 N Ni l I r 1 ! SECTION III - Pf1YSICAL OATA
~ ( i0lL1NC /01'NT(T) I vAPOR PBE55t1RL (s, il ➢ ) N/A ! vAPCR OENSiTT (A2Aal) M/A ( N!'ae I • .: ^ I - I SatAILITY Df MATER t 9PECiFIt t;fuvlTY (rATER,lI ( = YqATItE iY VaWC !!/A I ! Imlsibli I _.. UM/J =d.1 01 ✓
~ . ~ M. .~ +r .r I I t AAPEARANCC Nd' (DOR i slseM_ AMr k • waui

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, ( FtASN MINi (Wf111A1 tlIED) I flAtMtAiLE tIKTT6 LE1. 4EL 1 I

_ r+a+alswsbls ( N/A -- - 1 1CcTIMCttllR[D1C IE11IA Osy CMoial, CO2 r Matee Speay t i SP[CIAL OIx RCMTIM6 IROROIIILS f f ok fir» hdlaN rsu wlf.eon,t:inad beaathina ~ PMrafo gw taree amtiti, ~ a!a tnvolv.d. ' ! WAllX fik MD CcPtiallpl 1Miuqs 1
i OCC+I/Ai10NN. EXPQSUIE L1K7TS 1 l ft swtlen 11 - - 1 r. 1 4'i'CCf w OVmXPQ4lIRE 1 ! Eyq - N114 ireltettae Msy erwlt frcw Cobati o.cide Aw! in the ays, I { ItqfstiAn - Cd/s1t ssid! Iw s 1ew ardst of tayicity by this louia. May osuse gsatraintastinal disordert. { 4 Skin Prolangsd as zepsatad skin contsct srey enult 4f leaal aantsrt dsrsatitla. { 1 1.IUlstton- A srsll portlan af .orkers eay dsvelap laapiratary allsrqy rith ayoptow of ssthwa an mcDesues ta cabalt ocidel (
~ Md othMr eObalt dusts. Thta praduet eantatns Niokel in escesa af 9.11 as Nicksl *clde. Accardlnq to Isazard I

~ ' f t ~ Mmunleatton 8tsndard, dospounds oantelniep in arasas af 0.12 Ntekal are te bs labslad as potsntlal I 

### I eatelneeano. Pa! dotaii. elaass wo
~ 

### , tt , ~ 

### i= . Addltim.l Inf
~ 

### aaildn. I l OIfAGCNCY IlID fYlllf Aid MtOC11KWS ! ( Cya Csntsat • Jtripste wtth wt.r at leost li stnutes. Cvuult phyaielan. (

~ licth Cantaot - Rssav
. 9 aantaninatW OleRhlnq. Ysrh sk/n tAorouahly eith soap +nd watsr. Consult physiclan. I ! 1M+alltsen . Ras,evs t0 IlM
~ + al!• M ~ y piva aeyOM• Cansult physioian. I WC486-CO-14A IEY. 30 

### 12065870373

07I01I1991 00: 25 

### 12065870373 

### SEATTLE POTTERV SPSP -•r s

1 1 u+st

~ et,t ' f
- CMIDiTtcKs ta AV4ro. t •1 iTAeIUTr t " • N/,i

~ 1 59a9lE - st.ble V%&r nen

~ .k 1 

### ( I t.•w.ratur. and pr***4f-jj 

### ~ t ( IN[WElrslltTV (MATERIALS sN tYota) f 

### I . - Mena akneelae 1 1 02410 WCO006111*4 PRmtICi9 ' ""'""i 1 ?oxlr turra and aata anidti raZ be ore ent durino decamaoitian 1 1 w

~ tMGwS 1+uY eeCtdt 1 COHpitto+s TO ar0I0 1

y. 1 rOlt+r

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.. . I \ I

MA1$R1AL 1:. ICI,[AM Qt SP1tlE0 r1et

~~~ . tt

~ 14: apsil ! ~ ae

~ ssvad oo! tas»at ror dseaoeel.

~ , , .::

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~ .. ~ . .; , , . . 000e00 ln aeeordr+ce fth t'.daeal, State aad laeal laM.

pOiECTit>lit L$PCCifiC iYOEI

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ryMat eya! ILtxsidaitla`t s . ( reer 22n1410 rhara-sra oantset w.r occur. ! 1 OTNU1 PoOiE[TIK CINSPfLN1 1
1 PAEtA1Jtt0i 19 EE t,ytpl IN 1)1NOl1bC IMD SSORMG -- ~ 

### lgm oa+tasner eleaad. Ieataet +bain.t ohysieei d.nepe, ( 1_ Avosd aOt tlsth *in, wes, etothino, ! f dlKl! IwLCAUf1bN5 1 ANld beNthidp and use an2y ritb mdequ.te wnt!lakiona I 1

_ ~ a>.- ~ hOrotlei!

_y t ltae_ArsasilnQ. 1 I ~itl~~ i'~IMP~Atl~ i` r !
~ tluonlo pY1RpnMry dltaaaa haa tman tppott.d in rorkera in the eewented tw+petan osrblde jnduetrr Oere cobalt Ia We. fhie I I arfect hts not been•tvported tn tatkora r.tsniny or wlnq echalt aetei, eobalt acide .+d athMr ea+par+de of.eab Jt. i I • 1 

### t NOiCe tht taelelty data tor 

### Cabay t Odae (C63%) CASr1X3406-1 is not rvailabla. H)+e4yar, the tollewin9 drts la Ior Cabald i ozlde (C90) CASn707J96=6 r:a the Reqistry of TN1. Lrreet or Clwical s+b•ta*eet 2982-42. 1 1 • - . - 1 t Toasnity dats - Qrai fht lDgp 202 ny/leo tDsg s tathal teaa 30, that dose o+t likaly ta eau.e desth or SOs of ! f , axaests+cl tal

~ +iMl.. I i - I
~ Are.rdsrq tu oS1M CaR 9 ne! 1910-12m (F1KSN Ca+sntent{en) Msete1 tnd sertasn Mickal ee+qo4rda ata deened ta be 1 I Pos.ible qnvee lusstdt. Thi* ta tfss+d s+ ssatsaMs `y 00 v.8 NTr (Nsttanal Tonieoloqt Roprss) thMt ther ..r ! I riasarrbly " sattClNtat to Oe 4*1tetna4tM and an saqswent U law (Internatlanal AO+ney er Ikseareh FA Caneat) whloh { I oonelided tiut there wa ltaitad wllMaa.ar "relnoyenieltr te hu.ns. fhoea hare been no st4dise denenetretinp any 1 f esoap eMCat eisir =n werkars pAoeed te Mfaltal aetal poMder, kiefeet Odde ooMdor, klokel brbonats, and Mlekoi "ro ida ~ 1, tr► Ww1e w.. Studi.a * Sedbald + Ctp1e dtd aot r.aan.trate any si=n respttabla sanear riaM ..any rorkers eXrv.ed to ( 1.'Micite1 pordec aI ztipisyble •iza. OtMe atudtaa inealvtn9 enpos4ra, to Miokal dwt r1d fWe• !n tarinlnp, ets{nleaa etee2 ~ { d"d 811aY peeA+etton have eot shoM+ eny 10dtyaaad rseh af resplralory eanear. uto. Rhera !W tfeen rao arlderve t1 at ! 1+rostieN iu/aaod to Sol4bls #fieket sslt■ i,n thstt w• haro dwronatrsted sny inersesed rirk oI rsapttetory naneer. I I UKeraneae tiill be lurniehed upon reqmst: t lnrarastta► praeantaf hrrain haa t,s.n ca.piled itoa saveCee Coneldered ta be dsDendabla 4rd ta .ee4rata at'd ealfsOlf to the be.t ar t1r lomled9e and betiar or S"ttle pQttel ~~ L^°t y"'r'nteed te tw «o. Th. Co W en y varkes no r.Arss•ntatidM 0! osrlantlsa # amprrse Q Lplted. CYS1sMre ara ovreyed te e«+duct thsir aan bsls.



# , _ ~ 

# •. J 

# • ,

~ 

# , R . , _ .. . _ . ...- •

~ ~ ~~ • ~ ~~.

## DUCT: sorilUM NEXAMETAPHOSvwATE

03i02i98 11:04 ..,' , • , A< 

### REPORT WUM6£R: 705 M&DS N0: P1427 EFFECTIVE DATE: 07/18/91 

### a NO . b?r rUbb



### PAGE: 001 

### VeRSrON : 008

ORDER NCl: 284865 F'f20C1 NC1 1 347£300 

### VAN WATERS & RCJgERb INC. MATERIAL f;AFETY 13ATA SHEET



### MUI'UAL MATERxALS CO. ~ 

### NE4iCASTLE PLAN'r 6620 COAL L;REEK PKWY S, E. RE'NTptN , WA 98055
VAN LlATEf2S & ROt3ERS INC. , 9EJH51DIARY OF UNIVAI2 6100 CARILLON POTNT , KIRKLAMD 0 . 

### ( 2OeS ) t389w-S400 , WA 98033 

### ------------------------------- EMERQENCY ASSIS1'ANCE FOR EMEPqENCY ASSxSTANCE YNVOLVI'NG t;HEMICALS CALL - CHEMTREt; ( S00 ) 424--930a



### --------------------- FQR PRODUCT AAlD SALES INFARMATIQN ------..----....--------..----

CANTACT YC1UR LpGAI. VAN WATE'RS & ROGERS DRANCH OFFICE AT ViJbt2 KENT 206-972'-5000 i(ENT , WA .---........---}-..----__.__..-_,»PROCfUCT FDENTZF'XCCATZU

~ 

### l.

~ 

### _......w......__..__.....__-_ ~ 

### ..- ~~ 

### . PRppUCT NAiiEt SOnIUM FEEXAMETAPHOSPHATE CAS Nb.: 65915-'31-1 COMMON NAMES/SYNf3NYMS: MStlS #; P1427 SHMP: GLAS9Y Si]13IUM; VITaAFCJS ( R) ; METAFOS( *). AQUASTAR (TM) 300 

### F'OtiMULA: UNDEFxHED f3ATE :CSStfED: 10/90 

## MOLECULAR WEI014t UNOEFINED Sl1PERCERES: 04/90

, 

### HA7_ARi? S2ATIA4

~



### G. tNFPA 704+ ~

y ~~y~~ 

### LA)

. .4 •. " ; •.'.t ~ ,• . + ~ ry ''. r 1 '

~ . ?.

~ d.F,

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~ ' ,ad

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### HEALTH: I ~:~s.~ iAZARO S ~ „ALE: FIRE: O 0=M2 ~ lShlAL s ~i3~?S~~ IGIUS REACTIVITY t 0 1=!3LIGH'r `• 4+aSEVERE SPECIAL s NQAt£' 2aMOnERAI'E --------------------------HAZARDhL1S :CNG12EtIxENTS ---------------------------- EXPt]SURE LIMXT6, PPM AM 

### OSNA ACGIH UTHEF?

COMPflNENT CAa NO . X PEL, TLU LIMI7 fiAZARD . DIUM HEXAMETAPHOSi'HATE 68915-31-1 >99 NONF' ~ ON£ NONE NaNF ( i2) TRADEMARK OF aTAlJFFER (:HEt1ICAL CQMPATEY; 

# ~ ~03/02/58 11:04 NO.b7' Pbbi

Iq 

### REPORT NUMBER: 703 VAN WATERS & ROGERS 1NC. PAC3E:: 002 MSClS hlO: P1427 MATERIAL SAIrETY DATA SHEE.T EF'FCCTIVE flATE:c 07/18/91 VEFtSION: qpG aiJl1CT: 5C1DIUhi HEXAMETAPHEItPHATE
~ 

### URUER NfJ: 284845 PROp AdCI : 347800
(*) 'i'RApEMARK 0F EaSEX INqUSTRxAL CHEhiICALS, xNL", ( Thi ) Tl7AOEiiARK UF MQNEAZ , ETa f)RClpERTIES-....... , ...........____------------__---- BOIL.ING Pi3INT, DEG F't N1A { VAPC}R pFtESrURE, MM HG/20 AEG C: N/A pFi : 6-8 (1X ISOLN , ) 4 

### i'fELTINfa POINT, QEG F; 1163 VAPOR QEN;3ITY (AIR=1): N/A SPCCIF'IC GRAtIITY (41ATEit=1) r a W/lI WATER SOLUBILxYY, X t 133 APPEARANCE A1VD 000R: EVAPORATICli•E RA't'r- ( BUTYL ACETATE=1) : N/A WHITE PdlJtlEl7, (3itAtJULES OR GL.ASS PLATEb'= 0!](112LESS. `v VAL.AT IL.E ( BY VOLUME ): 0 

### -....--._....,...-..-..__.. ..-_-..w......FIOST AIA IF INHALEOi REMOVE Ta FR€SH AIR. GIVE ARTIF'IL'IAL. RESPIRATI0N IF hOT EATHING. GET' IMMEt3IATE MEnICAL ATTENTION. 

### xN CASE OF EYE CONTACT: IMMEnIATELY FLU6H EYl`:S uY'rH i.OTE OF RUNHING WATi;"R F012 iS MINUT£S, LIFTING TFlE EIPPEtt AND Ll]WER EYELIDS QCCASIONAi_.LY. G£T IMMEaIATE MERxCAL ATTEAlTION. I IN CASE. OF SKIN Cf]NTACT: IMMEClIATELY LlA5H SKXN WITH LOTS i3F SOAP AND WATER. REMOVE CONTAMINAT£n L'LOTHING ANA SHOES f WASH BEFi]RE REUSE . i3ET MEOICAE. ATTENTION IF IRRI1'ATIt7N pERSxSI'S AFTER WASH7NG. :tF SWALLOUEfl; UO NOT INOUCE VE3MITING. IF CONSCYtIUS, GIVE I.OTS OF wATE:k OR MILK. GET IMME£fIATE MEOxCAL ATTENTIL7N. 00 NOT GIVE Ai•lYTHINfl 8Y MOUTH rD :4N UNCONSCIQUS pR CONVULSINI3 PERSC?N. HAZARD Ii•1F'ORMAT:C ON--------..--_......-.---_.._._....__ lJRxirEAfiY ROUTES OF EXPC}SUREa SKIN OFt EYE COMTAE:T, xNHAI.l+720N, aIGNS ANq SYMPTO('fS OF EXP05`ilJRE INi-iALATION: MONE CUt2RENTE.Y KNOWN. EYE COhTACTt RE1STS MAY I{2RxTATE THE EY1::S, SKIh CQNTACY: NL7NE CURREHTLY KNOWFl. FiWALI.OWEO: bI.IGHTLY HAZAROOtJS 

# & RONIC EF'F'ECTS OF EXPU£iURE : NC► 

### SPEECIF TC lNFORMATION AVAILABLE . 

# 1K

### SUCt ! SOi3IUM HEXAMFTApHpSPHATE N0.677 P008



### RACEe 003 VE, RS I ON : OOG

ORDER Nfl : 284565 PROD NO : 347$00 03i02i98 11:04 Li 

### R£PGRT NlJMBER: 703 MSDS NiI: P1427 EFFECTIVE 1]A1'E: 07/18/91 VAN WATERS & RpqERS ING . 

## MA7'EaxAL SAFETY DATA SHEET

MEDICAL CbNE?TTIC2NS rENERALLY AGGRAVATED DY EXPOSURE: Nt?NE RE'PnRTED. ------------------------------'f'f]XI£„ITY DA't'A

~ rrrr ~ .......,........ . ..- ....... .......rr....rr. 

### QRAL: RAT LdSO = 2.9 G/KG, DERMAi.t RABBIT LD50 > 7.94 G/KG, INHALA?xON: N0 []ATA FOUND. , 

### CARCINQL

~ 

### `ENICITY: THI9 MATC.'RIAL IS NC3T CONSIQERED Tp DE A CARCXNQ(3i:3V E3Y THE NATxqNAL 7dxICOLOGY PRqGRAM, THE INTERNATIqNAL AGENCY F39R RESEARCH QN CANCER, ©R THE OCCIJPATIt7NAL SAFETY ANQ HEALTH AC7MINISI'RATION i1THER GATA: NONE . -----------........r...«r~......----PERSONAL PROTECTI©N---....___---------------------..__... 

# 0 7ICAi'YON: GEN£RAL RQqh! VENTILAI"If]N. RESPIRATORY f'RC?TECTIL?N: IF USE COHqITIONS GENERA'T'F' qUSTfi, WEAR A NIQSHW APP6tbVEp RESPIRATt7R APPROPRIATE FtlR THOSE EMISSIpN .LE.VELS. APPRCIPRIATE RESP#RAT0N8 MAY 8E A FULL FACEPIECk OR A HALt`' MASK 'AIR^^P4iRIFYIN9 CART-. F?IEiGE RF-f3PIRATE3R WITH PARTxGULATE FIL1i'ERS, A• SELF--G43NTAINED BREA'fHxNG APPARA'CUS IN THE Pi2ESSURE DEMANR MODE, OR A SUPPLIEfl-AIR RESPxRATqR. 

## EYE PRt7TF.CTInN: CHEMICAL GdGGLES A3•!CI !"'ULI. FAL'.E SHIELD. XT !S GENERAi_LY RECCt3NIZE#7 T'HAT CONTACT LENSES SKqfJLt7 NCl'r i3E WOl2N WHEN 41ORKYNG WITH CHEMICALS BECAUSE . CONTAC1' LENfiES hfAY f,aNTf2I33UTE TO THF' SEVE1tITY C)F AN 

## EYE INJURY. V , PROTECYYVE CLUTHXN

~ 

### ' s: LONG—SLEEVED SSHIRT, TROtJSC_RS, SAFETY SH(3E.^a, RUPIBER 

## GLOVE3, AND RUBBER APRON.

~ 

### pTkSR PRE7TECTIVE "MEASURESr AN EYEWASH ANn SAFETY $HOWER SHLIULU 13E NEARSY ANCI READY FOR USE . ._....-_-.. ................--_--_F'IaE ANQ EXPLOSIflN INFQRMA1'I!]N ------------------------ 

## FLASH POINT, DEG F: N/A FLAMMABLE LIMxTS IN AYR, X MEtHA D UsE D : N/A LOLIER : N/A UPPER : N/A AIJ TOIGNITION TEhfPERATURE, DEG.F: NO'T APPL.ZCABLE 

# W XNGIJISHING MEDIA: THIS 3riATERIAL IS NOT COMBUST ~ 

### HLE, USE F..XTZNCUISHIi ~ 

### G hiEDIA APPROPRIATE FOR SURRCfUi ~ 

### p1 ~ 

### lt+ FIRE.
~~~17.
~ /b: ;'yij 11:174

- ~ 

### REPORT NUHBER t 703 i`fSDS N0: 

### fi I437 

### EFFE:CTYVE oATE a 07/18/91 

# go VAN isATERS & R(]i3ERS Xi4G. MATERIAL SAFETY DATA ;3HEET hdU. 677 PUOy



### PAGE: 004 

### VERSIOAt : 008 {7UCT a st1L3TUi•! H£xAl'1ETAPHCfSPHATE QRt3ER NO a 284865 PRCfn NO : 347800

SPECIAL F'lRE FIGt-(TINC F'ROCEDURES: USE EJATER SPRAY TC1 C;tlC)L NEAFtE3Y CdNYAINERS AND STRUCTt!l2ES ExPASFQ TO FIRE. (JNLlSUAL FIRE ANiJ EXPLOSZQN HAZARDS: NONE,

S'i'ARIl.xTY: STASLE POL.YMERIZA ~ 

### TIC7N: WILL NpT qr,CUR CUNDITIt?NS TO AVCIID: FtEAT, C3PARKS, AND OPEN FLAMES. MATERIALS TO AVOxps ClXIL1YZER:i. HAZARQOUS OECC1MPOSxTION PRE]L)Uf:TS 1 NaNE.

----------- r

------- SPILL , LEAK , AMC! C1ISPp5Al. PROGEDURES.•
~ 

### ......_. _............__.._W ACTICIN TO TAKE FOi2 SPIL,.LS QR t.EAKS: WEAR PROTECTXVE E6tU:tPNfENT INi:LIlDING BER 800TS, RUSSER CtiLOVES, RU89ER APL20N, ANp A SEL.P'—CnNTAINFI] ATHING APPARATUS YN THE PRESSURE DEMANI7 Mi713E C}R A S3Ui'PLI>':f)-•AIR RESPIRATQR. IF THE SPILL flR L.EA!( xS SMALL_, A FULL FACEPIF_CE AxR— Pl,JRIF'Y7NO CARTRZl3GE RESPIRATOR EQUYPPEEI WITt~F PARTICULATE F ILTE f!S MAY BE SATISP'ACTDFlY, IN ANY EVENT, ALLIAYS tJEAR EYE PRCITEGTION. F'OR SMALI.. SPILLS, SUEEp 1!P ANn DSSPqSE C1P IN f}OT—APPROVED WAS•TF CON7AxNERS. F'C)it I+.ARGE SPxLLS, SHC?VEL. IN7O OOT—APPROVED GtASTE C;ONTAINERS. KE'EP QUT tlF SLriJEltS, STORM DRAxNS, SURFACE WATERS, AND S©IL. COhfPtY 4iITH AL.L. APPLICABLE GOVERkMEN1'AL REGULATxtJNS ON SPILL REPARTIkG, ANG HANDtING AN1l blSppSAL OF lJASTE . qxSPaSAL riETHODS: OISPOSE OF CONTAMxNATED PRa131iCT ANtf MATERxAl.8 USED IN C!~EANYNG UP SPILLS 0l±t ~ 

### EAKS IN A MANNER APF'ROVED FCta THIS MATERIAIr , CONSULT APP1•?ClORIATE F'EnERAL, STATE AI`lI:L LCICAL REQUt.ATORY AGENCxE:f> '1'0 ASCERTAxN pNOPEL2 DISPt]SAL PROCEDUI2EF;, Nf)TE: EMPTY CONTAINERS CAN HAVE RESxt11JES, GASES Ai+kp MSs'TS AND ARE: SUSJECt' Td PROPER lJASTE DISPCfSAL , AS ABUVF: . ! .._--..—_---_--..___ .. ........—SPEC:EAL STORAGE ANiJ HANnL.YIrlt3 PREC;AUTIONS: STORE IN A CtIQL, GRY, WELL—VENTILATED Pk.ACE AWAY FROM INC0Mf'ATIBLE MA7'ERIALS. KEEP BAGS Of7 F'IBER DRUME3 DRY AT ALL TIL'fES. WAL3H THhROUGHLY AFTER HANI?L:[NO. DO NC3T SET IN EYES, ON SKIN, QR OiY CLOTNI>`tG, 

### REPAI R AND MAINTENANCE pRE:CAIJTIUNS : NONE . ER PRECAUTIONS: C01 , lTAINERS, EVEN T140:3E THA7' HA .. E ~ 

### EE' ~ 

### ! E1 ~ 

### 4P1'IF'D, NIL..L. RETAI ~ 

### J PRt7DUCT RESIDUE AND VAI P 

### ORS. Al. ~ 

### fAYS DBE:Y wA ~ 

### RfJ WAR1 , lII`li;S ANq HANDLE Ei•fPTY C0NTAINERS AS IF THEY WERE 1='UE-L . ~~

### 03,
~ 

### 02/98 11:05
1~~ 

### :Pf)R7' N11MBEA: 703 MSDS NU : P 1427 

### EF"FEL'TIVE QATEt 07/18/91 

# 6 OOUCT : SdqIl1M HEXAiiETApHOtc-tATE ' N0.677 P010 

### • i 

### PAGE t 005



### VERSIONt 009
pROER Npc 284865 PROD MO : 347800 0 

### VAN 4lATERS & ROGEERS INC. MATE.RXAL 3AFETY UATA 5h1EET

------------------ECpi.Ot3IGAL YNFt]i7MATIoN SECTION -------------------- N0 qATA FOEINA ..._-..-_---------------- 01'HER ROGULATURY INFtI(2MATION... -__-__.,....___..-....

~ 

### ....w..M,.. 

## akCTlaN 313: sEE RELaW 1 

### !'IZQPE35YT];ON e<i.5 1 ;3CE sEL©U SECTxON 313 & PR{3P. 65t SEE BEL.GW SECTI0N 313 (lJYTH CHEtiICAi.S LESTECI; NaAlC 1 3 12C1PoSI1'IG}N 65 (WITH CHEMICALS l.ISTED) t iMASSACHUSETT6: NONE
NNSYLVANIA : NGNE CALIF0RNXA SCAQMQ: NONE

C 

## TSGA: 7HE INGREtIIENTS OF THZS PROqUCT ARE ON THE TSCA INVEEMTORY.


# -- -

~ 

# ........---------------------- REVISIdt

~ 

# 5------ , ....- , .._....._....._...-__....-_-_-....__

~ 

# -_ 05/891 REVISED FIRST AID AND VENTILATION RECOMMENUATxONS. 

# - --__-....--..-....--_.._...._..-..--_...-REVx$TON.M,......,,...._..._..

~ 

# . 08/891 CHANCiEO HEAC3ING AND CC#NTAC7 INFORMATION. 3.0/ 1 3Ut ADpEI?i SYNUNYM, MOLEClJLAR WEIGHT; E(MIS RATING, 'T•RAGEMARK, A11

- tYIIGfilITTt1N TEMN'r. , PH, x VOLATILE, ECOLEIGICAL XNFORMATxCtN. f)THk".R REGtfLATORY lNFORMATION (ORINFO 1,2,3,4) 

### REVISE;O t L;AS, Nl7. , NLALTH HAZARO ( INFlALATIOiV, SKIN COAt7'ACT, rWAE.i.tlUEp) , F'IRS

- T' AXn ( IP' 8WAl.l.i1WED) , HAZARDOU$ DECC1MF'OSITION, VENTILATION, TOXICxTY 

## (ORAL)

W-771



# ~~03/02i58 11: b5 N U. b

~ 'r r~ 11

. . . _ . . tl 

### REPOFtT NUME2ER: 703 VAN WATERS & RqGE:RS INC. PAaEi 

# ae.s M5U5 NE}: P1427 MATC:RIAL SAFETY DATA SHEE'T' 

## EFFECTIVS aATE: 07/18/91 V8a5iqN: oos QOUC:T s SflOIUM NEXAMfTAPH04PWATE ORi3E.R TlO : 284e65 

### pRan NO : 347800
,_-..__--__-__- w-_-__....-r_-- FnR AnIJITIt3NAL INFaRMATION ---------------------------- CONT'ACT : MSOS Ct3QRAtNATOR VW&R KE.NT



### DURING SUSINE3ta •h10URia, PACIFIC TXME (206)889 , »3400 09/29/92 a6s28 PRODU4T: :347800 CUST NA: 100215 O17DER NO: 284865
4 

### NpT SLE

~ ~ 

### r VAN WA1'ERS & Rn6ER5 INC. ("VW&R") EXPRF.SSI.Y DISCI»AIMS ALL EXPRESS I3R ;fMPLIEA WARRANnEg ClF MERCHANTABILITY ANLf FITNESS FoR A PARTICULAR PUkf+EfgE, . -..rrrr.wrr_.w._wrw__M-MMFNw-------------.r-.rr.y..yw_-_-.ur.r--_r.r--w..-._.w_._-_-_rwyyMMM.UYwYWW.Y-_ YN

. N .- 

### WIT'H RESPECT TO THE PRODUCT UR INFORMATIQN PROVI[)ED HE:kF IN.

~ 

### * 

## ..,_._—..__wwwwww«..w—ti..._w__—....---w_—__—_—r.www+rr.rr....r____.•1_.......

~ 

## ...u..............r,.rr..r

~ 

## ._.wr.........w...w.r.__

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## ___ 

# 0 ALL YNFORNATION APPEARINE3 HEREIN IS SASF'I] Uf'!]N OAt'A OBTAINEp FRLIM T'HE ' MANUF'AGTURER AND/OR REGOGNI2ED TECHiVxCAL SflURCES. WHILE THE INFORMATYON IS BELIEVEU Tf} 8E ACCEIRATE, VW&R MAKES N4 RFPRF:bEhtTA7'IOtVg AS TQ ITS ACCURACY OR SUFFICIENCY, CONI}ITxONS flF UE3€ ARE SEYt3Nil VW&RS CC1N7RnL ANO THEREFORE USERS 

### ARE RESPC3NS2aLE YO VERIFY THIS dATA UNaFR THEIR OWN ORERATING CoNaITXONS TO CIE'1'EFtMINE WHETHER THE PRdClUL"T IS SUITASLE FOR THEYR PARTICULAR PURPOSES AND THEY ASSUi"iE ALL kISKS OF THEIFZ USE, HANDI.ING, AN-O aISPt}SAL OF TkE PRODUCT, QR FRUM '3'HE PU$LICATxtIN OR Ubrt OF, f312 ItELIANCE UPAN , INFORF4ATI0N CONTAINED HEfiEYN, 'i'HIS INFL)FtMATIQN RELATEa 0NLY TQ THE PitD13L1CT tiESIGNATEq HERE'IN, ANif E2nE8 Ndr RELATE TO ITs Uf3E IN COMBINATION WITH ANY OTHEE2 MATEhIAL OR 

## IM ANY aTHEft P ROCESS . I -k ** EN i? U f' m S D S



# ~~~• ~r• ~2; ~~ 11: ~~ rao . ~~ ~ F~~~~ 

# MATERIAL SAFETY DATA SIiEET



# ~ roENrrrr; 

# BARIVM CARBONMTG RevisedAprii, 

# 7988 TAADE NAME 9ARIUM CAfl80NATE, PRECIPtTATED AND CALCINEO (ALL FORMS ANp GRAOES) tNCLUDE8 AOUA-Fl.O®, MICRO-FLO®. TYPE FF, Pi•-lOTO CxRAOE. TYPE TV, AND TYPE CFF, TYPE S.



### ~ 

## t ~~ R ~ B CHEMIGAL PROOL CTS CORPQAA710N r

~ .ar.• : <. ,•,. :. .. . . ~ ., ~ .. ~ .. . . ' :• 

### l? 

# ~( - 

# ~ '- '8 , 449, CARTERSVlLLE, GEOFiGIA ;"`- ~ .,, :a ~~ ,. . ~ ;.•,. .,, 

### ; .. ;... ... 

### JERRY A. COOK, TECHNtCAL DtAECTOR ftEGULAR TELEPHONE KQ. Oa y 

### 4041382-2 1 44 NP g ub 4t74, gM

~ 

### RCsENCY TELEPHOiVE NO. CtiEM7REC i-8t7Q-424-9300 

# It HAZARDQUS tNGREDlENTS COMPONENT CAS NO. Yo y/

~ 

### pRp QB ~ 

### P£3. a CGiti

TLV OTHE£R l.1MIT$

RgCOMMENDED BARIUM CARBONA'1•E 513-77-9 

# 1 ca 99% TOXlC ~a ~'„' af 8t1 unf Q' "'~"''

o! Sartu

~ 

### n NtiNE 

# M PHYSlCAI. DATA 84

~ 

### UNG PO1NT * 760 MM MG Not ApptiCBble MEl.TENG POfNT D

~ 

### "' 0 QW to Barium Oxide ea 1OCO° C 

## PECIFIC GRAVITY (HsOai) 

## I 4,4 VAPOR PRfSSUftE Not Appiicable 

### VAPOR DENSf'1'1( (AIR=1) [

~ 

### ot Applicabie ~L~~~ 

### tN WATER 96 8Y WEIGHT 0.002 0 /a (WC) 

### APPEARANCg AND OOOR White powder or graraules. Odoriess 

### EVAPOitATlON RATE (EUTYl. ACETATl 1) 

### Not Applicable 

# tV FlRE A1VD EXPLOStON dA"!'A FLASH POtNT AUTOtGNiT10N 

### (TEST METHOp) NON-FLAMMABLH TEMPERATURE NON

- 

### FLAMMABLE 

### RL4MMABLE LIMiTS !EN AfR, % 9Y VOL. LOWER UPPER 

## NONE NONE NONE E%TtNGU1$H1NG MEDIA NO FfRE HAZARD 

## SPECtAL FiRE 

# ~ Avo1d corrtact wlth ac/d -- large quantities of 

### carbon dioxide wi!l 

### be evolved. 

### F1GHTING Barium carbonate 

### is toxic it ingested. 

### PROCEDUpgS I Avoid inhalation of dust. 

### t1NUSUAL FiRE AND EXPl.05tON NONE 

## HAZARDS Wltile the infonnation and recommendations contained in this pubtication are beiieved to be accur3te for this materiai when not in Combination with others, CttemiCat Products Corporatiort nnakes nowafranty or guarantee r!s to such information and 

# ~ recommendati0n5, proper use ot the informatiort Oontained herein arta of ttte product are tNe responsibiiity of the user. 

### Pag.= 1 of 3 Pages 

# ~~ p F~ +.7



### 2



# Is'13i02; g8 11 : 04 NO. 677 P004


## ' CHEMICAL PRODCJCTS , CORPORATION 

# BARIEJM CARRONATE Y REACTIYITY DATA CONDiTEONS CONTR(BUTiNG TO INSTABtLtTY

~ 

### V®h' ternperature (ca 1QQ(r C) ceuses decomposition to bariunt oxide and Carbon dioxide. iNCOlY1PAT1iBfLiTY Aekis wilt decbmpose bariurn carbonate to otlYer barium salts with liber8tion of carbort dioxide. 

## ThA mectlon may 

## 4e violent. HA7J1ROO618 QECOMPOSITION PRODUCTS 

### i8ariurn cartorlate may be decoTposed to forrn oth®r barium sa}ts. Ati water and aold 3oiuble barium saits are toxic CONOmONS CONTRIBUTiNG TO FtAXAROOiJS POLYMERZATION None 

# VI HEALTM HAZARD lNFORMAT'ION RO11M$ OF EXPO$URE I`tAZARO CLASSIFiCAT10N BASIS FtlR CLASSIFICATION SOURCI! 1NHAl.AT1ON Moderately Tpxic Irthaiation - Rat 24 Hours 

### Tel.p-11$0 /m' NIOSH Registry of 'foxic Effect 

### of Chernicat $ubstance: SKIN CONTACT Selieved to b* no hazard None None $KIN ABSORPTION Beiieved to b8 no hazard None None M CONTACT Beiieved to be irritant None None 

### INGESTION TOXtC Oral - 

### Human 1.OLo - 57 mg/kg 

### Orai - Rat LDeo - 418 rrtg/kg NlOSH Regisstry of Toxic Eifeci 

### of Chemicai SU4stance; SYMPTOMS EXCESSiVE INGESTION 1WAY CAUSE i=XCESSfVE SALEVATION, VOM1TtNCi, OF SEIJERE A8DOMINAL PAIN, V10LENT PURGING WITH WATi:RY AND SLOOOY STO 

# CR OV1=R$XPOStlRE Si.OW ANO OFTEN 3RREGUiAR PULSE, MUSCLE TWlTCHlNGS PROGRESSING TO

CONVULSIONS ANDKOR PARALYSiS, DtL.ATED PUPILS, CONFUSiON, POSStBLY DEATiMeDlCAL CONOiTiONS GE3dERALLY AGGRAVATEO BY EXPO$URP: NONE CARC3NOGgNIC1TY: 

### NTP - NO 

### IARC MONOGRAPi-IS - NO 

### OSHA R$'GULATEp - NO 

## E1YlERGENCY AlVA F1RST A1D PROCEDURES EYES: FLUSH WITH CQPfOUS AMOUNT$ OF WA7'ER: ALWAYS SEEK MEDtCAL ATTEdTION. 

### $KIN: WASH WtTH SOAi:' ANO WATER. INMALATION: FLUSH MOUTH AND NA$AL PASSAGES WiTH WAT£R AS MUCH AS POSSi8LE. INGiESTlON: ADMINSSTER ONE TABi.ESPOON OF 1:PSOM SALTS (MAGNESIUM SULFA7E) OR

GLAUSER'S SALT (SOOIUM SULl:ATE) DISSOLVED IN WATER. tF V4CTIAA IS NOT VOMITING, iNDUCE VOMITING BY GiVING SYRUP OF IP£CAC G BY STlClUNG fiNGER DOWN THROAT. NOTES ITYPOKALEMlA IS OFTEN OBSERVED: POTASSiUM SHOUID BE ADMINISTERED — TO LARGE CIOSES MAY SE Rf;OUlRED, PNYSICIAIV IN ACUTELY P0lSONED DOGS, POTASSIUM INFUSiONS CORRECTED ALL OF TH; CLINICAL SiGNS OF SARfUM POISONING EXCEPT T4-!E HYPEPTENSlON.



### ~ Page 2 of 3 Pages 

# j~~r;i G^2/90 11 : G4 hJU . 6 1 - 7 P005 

## CHEMICAL PR.ODUCTS CORPC)R.ATION 

# BARiUM CARBONATE V11 PRECAUTtONS FOR SAFE HANDLING AND USE



# ~ STEPS TO BE 7AKEN iF MATERIiAL IS REl.EASiEO Ofl SPlLLEO Try to keep materiai dry arid away frorn acid. Sweep or scoop up spilied rnaterial. pisposa of in an approved hazardous waste iandfili or mix with excess suifate to make materiat norr-ha2ardous. NSUTRALlZINta CHSMiCALS 

### Can be etlAde ttion



### - toxic by forming insolubie barium suifate. 

### Fleact with eulfurlC aCid (cairtion - 

### reaction can be violent). WASTE DISPOSAL METHOO Waste Cotltllirlirig mo+'e than 0.24b soiuble barivm is hazardous. Can be rendered nort-ttazardous by reaction with excess sufifate to form inaoluble bariurr+ suifate. 

### Obsqrve alt federal, state, and loca,l taws. PRECAUTIONARY STATEMENTS 1. Reaction with acid cnn reiease large quarttities of carbor. dioxide which Could }ead to suffocation in a confin®d area. 

## Use adequata ventiiation. 2. A smali arndunt Qf toxle hydrogen sulfide gas may be liberated on acitlification (as an impurity). Use adequate ventiiation. OTH£R HANDl..tNG ANO STORAQIa REQUTA@1MENTS 

### $tQre awa from acids. 

# V111 CONTROL MEASURES { VENTUJ1T10N REQUIREI4EENTS 

# I PiOyid@ Suffictent ventilation to remove dust. 

# ~ SPE{;SFiC PArtRSONAI. PROTECTiVE EQUIPO+[ENT 

### RESPlRATORY 

# ~ Use NtOSH approved dust mask if excessi v 

## e dust is presen 

## t. 

## EYE Safety glasses GLC?V1a8 General purpose 

### I OTHER CLOTHING AAiC EOWPMEIYT Cover exposed skin areas. F'rovide epsom salts as part of the first aid suppiies. 

# •

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### SECTION V 1

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### SECTION VIII 

### • SPECIAL 

## PRO"IFECTION INFOR."VIAT iON

oacTic"rovt



### SEC71CN iX 

### - 

## SPECIALPREICAUTIONS
046N.1L.N: A.-D =7t- 

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11

# M mutual materials co. 605•119THNORTHEAST POST OFFICE BOX 2009 BELLEVUE, WASHINGTON 98009 PHONE (206) 455-2869 

## March 3, 1998 Mr. Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, NC 27711 The following Information Collection Request form is submitted for the Columbia Brick Plant Facility, operated by Mutual Materials Company, in Gresham, Oregon. The report contains the following items: A- Form 2, Information Coltection Request (28 pages). B- Laboratory analysis of clays and brick products. C- Sample pallet tag labeling. D- MSDS for Mutual fired clay brick products. E- MSDS for raw materials used in manufacturing processes. If you have any questions or require additional information please call or write. Respectfully submitted,

George A. Beamer Mutual Materials Company (509)-924-2120



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### Enclosure 2

-- -- NOT SUBJcCT TO i[!: RE9J•:REM,NTS Of I; S£CTION 3507, PAPERi70RK RE7UCT!Ot2 ACT OF 1980. ;

~ 

## INFORMATION REQUEST FOR BRICK AND STRUCTURAi, CLAY PRODUCTS MANUFACTURING OPERATIONS I. Instructions 

## Please return the completed information request to: Bruce C. Jordan, Director Attn: Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at (919) 541-5435. 

## This information request should be completed for each facility that manufactures brick and structural clay products, including facilities that are not major sources. Information is requested for all processes at your plant that emit hazardous air pollutants (HAP's), including those processes that are not associated with brick and structural clay products manufacturing. Sections II through VII request information specific to brick and structural clay products manufacturing, and Section VIII requests information on emissions of HAP's from other processes located at the facility. Processes that may emit HAP's include those processes that use or handle any materials that contain a HAP compound, all processes with elevated temperatures, and all other processes in which HAP compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this information request. Attachment 2 provides background information on the requirements of the Clean Air Act and explains how the information requested in this questionnaire will be used by'EPA. Attachment 3 is a list of abbreviations and acronyms used in this information request. Several tables are provided throughout the information request for your convenience in answering the questions. An example response is given (shaded first column or row) in each table. If additional space is needed to respond, please make copies of applicable pages. If necessary, please make copies of this information request for additional facilities. No additional emission testing or monitoring is required to respond to this request. Q. General Facility Information 

## A. Name of company 

# 1 1

4uruW ~ 

# IvNra&lk S aoPavz Name of facility 

## l.0

2 141Y1311i llC,(~

Page 1 of 28 

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## Facility address: No. and street 

## Z300 'SAE ff

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## A-N 

## 217 City 

## 6E I iEsl

- EPrAl State 

## O'J? , Zip 

## 97080 Latitude and longitude coordinates of plant: 

## lVRpX; T~ - 

## 30

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## N

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## F3", 

## IZZ ° 2 o' C.t~lC~ 

## Standard Industrial Classificat 

# ~~ i ) Code(s) of brick and structural clay products manufacturing operations Dun and Bradstreet No. 

## Q0 9 Z c {' 4,3 7 7 Total No. of employees for company 

## +5b - S)Q for facility 

# 2~ ± (If facility is a foreign subsidiary or if company has foreign subsidiaries, include number of employees not based in the U.S.). Please complete the following shift information for the facility: Shift No. of employees Hours per shift Days per year 1 t 3



# s S



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## B. Respondent name Respondent title Respondent address (if different from above) and telephone number: No. and street 

## Ra 'a O'x H 7o ~ City ~ Jl~ 

## g State )kA_ Zip Telephone No. ( ~ 

## ~SD~ ~—~ 

## Z4 - Z 1 Z0 Name and telephone number of technical contact person (if different from above) Name 

## _5t ~ 

## mE Telephone No. (_) 

## 5f} A'1 C' 111 

## Information on ORerating Permits and Applicable Federal Emission Standards A. Please provide copies of relevant parts of all operating permits and permit applications for your facility. Relevant parts include the sections that providespecific information and data on: processes that emit HAP's; the use of HAPcontaining substances; emission levels for HAP and surrogate pollutants (i.e., VOC Page 2 of'28 

# /~ )% (6

## for organic HAP's and PM for metal and other particulate HAP's); emission control device design and operation; monitoring and operation and maintenance (O&M) procedures for control devices; and generation and releases of other media such as wastewater and solid waste that are associated with the operation of air pollution controls for brick and structural clay products manufacturing processes. If the operating permit or application contains the same information requested in any part of this questionnaire, you may respond to the requested information by referencing the page or section of the permit/application to avoid duplication. If you reference your permit or application, you must supplement your response with all of the additional information requested in this questionnaire that is not included in the permit or permit application. If you prefer, you may submit the requested information from your permit/application on a 3- 1 /z inch diskette. B. If any source or emission unit at this facility is subject to a New Source Performance Standard or other Federal emission standard, please identify the source and applicable standard. Examples of applicable NSPS include 40 CFR 60, Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in Mineral Industries.

1 

# 4

IV. Brick and Structural Clay Products Production and Raw Material Consumption Information A. Please provide the 1996 production rates and the current production capacity for each type of brick and structural clay product manufactured (e.g., structural brick, clay sewer pipes, structural clay tile, etc.). Note that production data should be provided in units of tons per year (tons/yr). Product 1996 production (tons) Production capacity (tons/yr) S-ti2ucTUr44-c, c~ 

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Page 3 of 28



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### B. Please provide the type and amount of each raw material and body additive used in 1996 for manufacturing brick and structural clay products at your facility. Examples include clays, shale, and any additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade name. If the information requested is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. Raw materiaVbody additive Amount used in 1996 (tons/yr) 

## C 1, OOc7 

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C. If available, please provide a copy of the MSDS's for the raw materials and additives

listed above. D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above.

Page 4 of 28 

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## E. Using Table 1, please provide information on the consumption and HAP composition of all glazes and colorants that contain HAP's or HAP precursors and that your facility applies to brick and structural clay products. Indicate whether the coatings are glazes or colorants. Also indicate the type of product that the coatings are applied to and the total weight of coatings used in 1996. If the glazes or colorants are formulated at your facility indicate so and provide the production capacity. List each ingredient of the glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient used in 1996. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than f lling out the table. F. In the space below, please indicate any glazes or colorants used by your facility that do not contain HAP's and are substitutes for HAP-containing glazes or colorants used by your industry. Indicate which HAP-containing materials the non-HAP glazes or colorants replace. Describe any limitations on the use of those substitute glazes or colorants.

G. If your facility colors brick and structural clay products by flashing, please indicate the types of substances used to flash the products and the amounts of those substances used in 1996. Substance Amount used in 1996 Units s ci NA374 (ML 

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H. If available, please provide a copy of the MSDS's for the glazes and colorants used by your facility. If your facility prepares its own glaze, please provide any available MSDS's for the glaze ingredients.

Page 5 of 28 

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### TABLE 1. CONSUMPTION AND HAP COMPOSTITON OF GLAZES AND COLORANTS

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## V. Description of Brick and Structural Clay Product Manufacturing Processes 

## A. Please provide a simple process flow diagram for each brick and structural clay product manufacturing process line. An example process flow diagram is provided in Figure 1. A diagram of the plant layout with all processes and emission points clearly labeled is also acceptable. Assign a unique identification number (ID No.) for each process that has associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. Please identify all emission points, including those that do not emit HAP's. For emission points that are vented to an air pollution control device (APCD), assign an ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information request for any responses that pertain to any process or emission point. 

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## B. Using Tables 2A and 2B, please provide current production rates, production capacities, and related information for each type of equipment used in brick and structural clay product manufacturing. In Table 2A, provide the requested information for only those sources that are known or expected to emit HAP's. In Table 2B, provide the requested information for all thermal processing, such as drying and firing sources. For combustion sources that use different fuels, Table 2B should be completed for each type of fuel. For example, if a kiln typically is fired with gas, but periodically is fired with oil, one column in Table 2B should be completed for the kiln when fired with ga.s, and another column should be completed for the same kiln when fired with oil. Provide the data in the units listed for each row.

Page 9 of 28 

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## C. Using Table 3, please provide information on procedures used to monitor the process operating rate for each of the pieces of equipment and HAP emission sources listed in Tables 2A and 2B. Use the same HAP emission source types and equipment ID numbers you listed in Tables 2A to 2B. Indicate whether you monitor process rate or not. Provide a summary of process rate monitoring procedures that describes how process rate is measured for the particular piece of equipment. Include where the rate is monitored (i.e., rate of material fed, rate of material discharged, or material production rate), the units used to measure process rate (e.g, lb/hr or pieces/hr), and how the process data is recorded, i.e., manually, automatically (e.g., computer - printout or stored to disk, or not at all). If you monitor process rate at both the feed and discharge ends of the equipment, indicate so. Indicate the type of monitor, equipment, or instrument used to measure process operating rate. Indicate the monitoring frequency or how often process rate measurements are made. If instruments are used to measure process throughput, indicate in the monitor accuracy column the accuracy of the instrument. The monitor accuracy could be listed in terms of a percentage of the throughput (± 1 percent), mass per unit time (t21b/hr), number of pieces per unit time (± 10 pieces/hr), or other appropriate units. Indicate the frequency that the monitor is calibrated. Provide data in the units listed for each row.

Page 12 of 28



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## VI. Identification of Brick and Structtiral Clay Product Manufacturing Emission Points



## A. Use the process flow diagrams developed for your facility and Table 4 to provide the following information for each HAP emission source at your facility. • Define HAP emission source type in terms of equipment, such as dryers, kilns, etc. As in the process flow diagram, you may group multiple pieces of similar equipment. • Use the same equipment ID numbers indicated on the process flow diagram(s). • If the emission source vents inside a building or to outside ambient air without first passing through a control device, place a check mark in the uncontrolled column. • If the emission source vents inside a building or to outside ambient air after passing through a fabric filter, dry injection fabric filter, or scrubber, place the APCD ID number(s) in the column corresponding to the APCD type. • If the emission source vents through a control device type not listed in Table 4, indicate the control device type in the other control column and place the APCD ID number in the appropriate cell. • In the emission test data column, place a"yes" or "no" in the appropriate cell to indicate whether the specific source has been tested for My pollutants, including any HAP's, VOC, PM, or opacity.

Page 14 of 28 

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## B. Using Table 5, please provide information on stack parameters and emission estimates for each emission point at your facility that is known or expected to emit HAP's. Provide information for all APCD's, including those that exhaust inside the building. Include data for each inlet and outlet, if available, as indicated in the tabfe. If you have more than one inlet to an APCD, provide data for each of the inlets. Provide data in the units listed for each row. Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal HAP's or VOC for organic HAP's. Emission estimates may consist of measurements reported in emission test reports or may be calculated using mass balances, emission factors, engineering judgement, or other estimation methods. Provide the emission estimates as emission factors in units of lb of pollutant emitted per ton of product (lb/ton). Provide complete copies of any emission test reports or other reports that document measurements of emissions. Test reports and other emission measurement documents should include the following information: process identification; location of sampling point; stack diameter, temperature, and flow rate; test method, including analytical procedures; number of test runs; emission concentration, emission rate, percent oxygen, and percent moisture for each test run; process operating rate; type of APCD; and APCD operating parameters. However, test reports with incomplete documentation may still be useful and should also be submitted. You do not need to fill out Table 5 for emission points that are covered by an emission test report that is included in your submittal. If emission test reports are not available, provide calculations that support your emission estimate, including the basis for all assumptions in the estimate. Note that emission estimates are needed for all HAP's that the facility emits or has the potential to emit. (Please refer to the HAP list in Attachment 1.) If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 16 of 28 

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### Page 18 of 28 

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### C. Using Tables 6A through 61), please provide design and operating data for each APCD associated with all dryers, kilns, and any other brick and structural clay products manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of APCD's. Use Table 6D for other types of APCD's. When using Table 6D, please specify the type of control device and 2 to 4 key design or operating parameters for the device. Provide data in the units listed for each row. If the information requested in Tables 6A through 6D is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the tables.

Page 19 of 28 

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## D. Using Table 7, please provide the following information on current monitoring procedures for each of the control devices listed in Tables 6A to 6D: parameters monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices used (e.g., differential pressure transducer, thermocouple), and recordkeeping practices (e.g., manually recorded in log book, continuously recorded by electronic data acquisition system). Describe briefly other operation and maintenance (O&M) procedures for each control device. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table. VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing A. Please describe all pollution prevention practices (i.e., process modifications, such as re-use of discarded or rejected materials, or any practice that prevents or reduces the amount of air emissions, or the generation and release of solid waste or wastewater associated with the operation of air pollution controls). If the information requested here is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below.



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### VIII. Information on Processes Other Than Brick and Structural Clay Products Manufacturing



## Processes A. Using Table 8, please identify all other processes or operations at this facility that are not addressed in Items II through VII above and that are potential sources of HAP emissions. Estimate total annual emissions of each HAP emitted by these colocated processes. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 27 of 28



# ~~~

## TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES Estimated annual Process/emission source/SIC Code(s) HAP's emitted 

# I emissions, tons EXAMPLE:° lYfning;- _ ~~ 

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SIC If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.
Page 28 of 28 

# 135:-t 1 rri r9u I UHL_UULUMB I q 5034920667 P. 02

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## Analytical nata M

- uri.Eal Material Job Nuinber: 970102AQ Page Number: 3 of 3 Lab Sample ID: 970102AQ-2 Field ID: Raw Spice Date/Time: None Provided Matrix: Solid s:PA Category: Conventional Parameters Detection Analytical Parat

- c!eler Method Limit Result Uuits Twall F
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### luoride SM 413-AB 2. 88. mg/Kg



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## r.MAR-02-98 MON.04:42 PM MLITUAL—COLUMBIA 5034920667 FP.03

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## M:.wai. Material Job Number: 970102AQ Page Number: 2 of 3
Lab 

## Sainple ID: 

## 970102AQ-1 Field ID: 

## Fired Spice Date/Time: None Provided Matrix: Solid t;PA Category: Conventional Parameters Dc,tection Analytical Pararcieter Metliod Limit _ Result Units Tcr.al Fluoride SM 413-AB 2. 49. mg/Kg



# 1 3> --

_ Coffev Laboratories, '4n:.

# SAMPLE: PALLET WARN/NG LABEL
manufactured by 

# M 

# mutual M 

# materi"als co.

Mutual Materials Company, P.O. Box 2009, 605-119th Avenue N.E., Believue, WA 98009 

# WARNING CAUTION: IMPORTANT SAFETY INFORMATION Dry-sawing or grinding of fired clay brick is not recommended and may result in the release of respirable crystalline silica dust particles that may cause respiratory ailments (such as silicosis) and even cancer if proper protective equipment is not in place. The use of a NIOSH approved respirator, tight fitting goggles, and protective gloves are recommended when sawing or grinding these units. Adequate ventilation and enclosure should be provided to workers engaged in these operations. Specific MSDS information is available from the manufacturer and/or selling agent.



# 136

# 1

.. MATERJAL SAFETY DATA SHEET 

# ~ a+zoouccrioerrrrrY: F1RED CLAY BRICK 

## SECTI ON I '

~ Manufacturer's Name: Emergency Phone Number: 

### Mutual Materials Company (206) 455-2869 • 

# ~ Telephone Number for Information: Address: (206) 455-2869 

### P. 0. Box 2009 

# ~ Bellevue, Washington 98009 

### Date Prepared: November 1, 1994 

## SEC?`!ON II -: Hazardous Ingredients/ldentity lnformation

~ Hazardous Components: Specific Chemical Identitv: 

### Crystalline Quar.tz Silica Quartz (Silicon Dioxide), SiO Z 

# ~ These "Hazardous Components" are not released under normal conditions of use, but may be released from the fired clay brick as airborne respirable free crystalline silica particles when dry-sawing, dry-grinding, or otherwise materially modifying the product. 

# ~ Common Names: Dust from sawing or grinding, Sand, Silica. 

# ~ OSHA PEL• 

### Exposure . to airborne crystalline silica shall not exceed an 8-hour time-weighted average limit as stated in 29 CFR 1910.1000 Table Z-3 for Mineral Dusts, specifically: 

# ~ Silica, Crystalline Quartz (respirable): 0.1 mg/M' ACGIH TLV• 

### Crystalline Quartz 

# ~ TLV-TWA - 0.1 mg/M' (Respirable Dust) See Threshold Limit Value and Biological Exposure Indices for 1991-1992, American Conference of Governmental Industrial Hygienists. Other Limits Recommended: NIOSH has recommended that the permissible exposure limit be changed to 0.05 mg/M' (as respirable free silica) averaged over a work shift of up to 10 hours per day, 40 hours per week. Consult the NIOSH Criteria Document for Crystalline Silica for more information. 

## SECT(ON IU :: PhysicaUChemical Characteristics Boilina Point 4046°F 

### Specific Gravitv: 2.65 

### Vapor Pressure: N/A 

### Meltina Point 3050 ° F 

### Vapor Densitv: N/A 

### Evaporation Rate: N/A 

### SolubilitV In V4tier: Not Soluble 

### Appearance 8 Odor: Granular or Powder, 

### Odorless 

## SECTION 11/.- Fire and Explosion Hazard Data Flash Polnt Non-Combustible 

### LEL: None 

### Flammable Limits
: 

### None 

### UEL
: 

### None 

### ExtinQuishing Media: N/A Unusual Fire and Special Fire Fighting Procedures: N/A ' Explosiort Hazards: None



## ~~ 

# %

# f

SECTION V - REACTIVITY DATA Stabili : Stable Conditions to Avoid: None Incompatibility (Materials to Avoid): 

### Silica will dissolve in hydrofluoric acid and produce a corrosive gas, silicon tetrafluoride. Hazardous Decomposition or Byproducts: None . 

### Hazardous Polymerization: will not occur. 

### Conditions to Avoid: None 

## SECTION;VI - Health.Hazard Data Route(s) of Entrv:

Inhalation ?: Yes Skin ?: No Ingestion ?: No Health Hazards (Acute and Chronic): 

### Dry-sawing or dry-grinding may result in the release of dust particles which may: 

### Acute: May cause minor irritation of the eye, nose, or skin. 

### Chronic: Excessive inhalation of dust particles for prolonged periods may result in lung disease (silicosis). Silicosis is a form of disabling pulmonary fibrosis which can be progressive and may lead to death. See "Carcinogenicity" section below. Carcinoqenicity: 

### NTP?: Yes . 

### In the Sixth Annual Report on Carcinogens by The National Toxicology Program (NTP), it was concluded that respirable crystalline silica may reasonably be anticipated to be a carcinogen. The conclusion is based on sufficient evidence of carcinogenicity in laboratory animals, and limited evidence in humans. IARC Monographs?: Yes . 

### The'International Agency for Research on Cancer (IARC) Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans (Vol. 42, 1987) concludes that there is sufficient evidence for the carcinogenicity of crystalline silica to experimental animals, and that there is limited evidence of the carcinogenicity of crystalline silica to humans. IARC Class 2A. Signs and Symptoms of Exposure: 

### Symptoms of excessive exposure are irritation of eyes, nose and/or throat, shortness of breath, sputum production. Medical Conditions Generally Aggravated by Exposure: 

### Pre-existing pulmonary and/or respiratory lung diseases, including, but not limited to; Emphysema, Asthma, or Bronchitis. Pulmonary function may be reduced by inhalation of respirable crystalline silica. Lung scarring produced by excessive inhalation may lead to a progressive massive fibrosis of the lung which may aggravate other pulmonary conditions and diseases, increasing susceptibility to pulmonary tuberculosis. Progressive massive fibrosis may be accompanied by heart enlargement, heart failure, and pulmonary failure. r:Smoking aggravates the effects of exposure. Sensitive eye conditions may also be aggravated by excessive exposure. Emeraencv and First Aid Procedures: 

## Eyes : Flush eyes immediately and generously with water for 15 minutes. If irritation persists, seek medical attention. 

### Inhalation: For gross inhalation, remove person immediately to fresh air. Give artificial respiration as needed, and seek medical attention as needed. 

### Skin: Wash thoroughly. See physician if irritation persists.
' : ~ .gc ] of fl DwTA/9AISTT/h5G.9/K3J50• !F


## - ~3~

## .~
SECTION:;UII Precautions.for Safe Handling:and se s. 

### Steps to Be Taken in Case Material is Released or Spilled: Collect dust from dry-sawing or grinding 

### operations using dustless method (vacuum or water). Wear protective equipment specified below. Waste DisposalMethod: 

### Dispose in accordance with Federal, State, and Local regulations. 

### Precautions to Be Taken in Handling and Storing: Avoid breathing of dust particles from dry

### sawing and grinding of units. Take normal precautions against spilling of containers with waste dust particles from dzy-sawing or grinding operations. OtherPrecautions: 

### Wear NIOSH approved respirator, tight fitting goggles, and gloves when sawing or grinding operations are active. Do not permit dust to collect on wall or floor surfaces, clothing, or equipment. See applicable OSHA Hazard Communication Rule 29 CFR Sections and State and Local worker or community "right to know" laws and regulations. We recommend that smoking be prohibited in all areas where respirators must be used. WARN YOUR EMPLOYEES AND (YOUR CUSTOMER-USERS IN CASE OF RESALE) BY POSTING AND OTHER MEANS OF THE HAZARD AND OSHA PRECAUTIONS TO BE USED. PROVIDE TRAINING FOR YOUR EMPLOYEES ABOUT THE OSHA PRECAUTIONS. See also the ASTM E 1132-86, "Standard Practice for Health Requirements Relating.to Occupational Exposure to Quartz Dust."

, 

## SECTION VI11 C'ontrol.Measures. NOTE: THESE CONTROL MEASURES ARE TO BE USED WHEN DRY-SAWtNG, DRY-GRINDING, OR OTHER MATERIAL MODIFYING OPERATIONS ARE ACTIVE. NORMAL CONDITIONS OF USE AND/OR INSTALLATIONS OF FIRED CLAY BRICK ARTICLES DO NOT REQUIRE RESPIRATORY CONTROL MEASURES. 

### Respiratory Protection: Use NIOSH approved Particulate Respirator. Provide additional 

### conventional respiratory protection based on considerations of airborne concentrations and duration of exposure. See most recent standards of the following: American National Standard Institute (ANSI Z.88.2) Occupational Safety and Health Administration (OSHA 29 CFR Part 1910.134) Mine Safety and Health Administration (MSHA 30 CFR Part 56) National Institute for Occupational Safety and Health (NIOSH Pocket Guide to Chemical Hazards) 

### Ventilation: Local Exhaust: Meet PEL requirements set out above in Section II .



### Special: N/A 

### Other: N/A Mechanical(General): 

### When cutting in confined area, meet PEL requirements. Protective Gloyes: Recommended. Eye Protection: Tight fitting protective goggles. Other Protective Clothing or Eguipment: As needed. Work/Hyqienic Practices: Avoid creating and breathing dust (see Other Precautions, Sec. VII .) The information, data and recommendations contained in this MSDS relates only to the specific material described, and is not to be used in combination with any other material or in any other process. This information is based on data that Mutual Materials Company believes to be correct and reliable. It is intended for use by competent persons having technical skill sufficient to understand the limits and boundaries of 

### application. Mutual Materials Company accepts no responsibility and disclaims all liability for any harmful health effects which may be caused by purchase, resale, use, or exposure to fired clay brick and/or dust created by sawing, grinding or other operations outside normal conditions of use which may be performed on those units. Mutual Materials Company makes no warranties, either expressed or implied, concerning the application of the information herein. Any use of this information and data must be determined by the user to be in accordance with all applicable laws, regulations and orders. 

# 13

# Cc Ar G T

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# Cl ay ~

(( P. O. Box 295 • Oak Hill, OH 45656-0295 •(6]4) 682-7794 • FAX (674) 682-6438 

## RE ~ 

## SCO ,


# ~

~



### MATERIAL SAFETY DATA SHEET 

## To comply with OSHA's 29 CFR 1910.1200 and Bill No. 70 WEMIS 

## Hazard Communication Standards.

A 

### SECTION I- IDENTIFICATION OF MATERIAL AND MANiJFACTORER


## 2"iANUFACTIIRER'S NAME AND ADDRESS: Resco Products, Inc. 

## Cedar Heights Clay Division P.O. Box 295 3542 State Route 93 Oak Hill, OH 45656 CHEMICAL NAME AND SYNONYMS: Hydrous Alumina Silicate CHEMICAL FAKILY: Silicate EMERGENCY PHONE: (614) 682-7794



## TRADE NAME AND SYNONYHS:. '*.t..:..,

~ r... "..•'



### ~ 

# Redart

SECTION II - CHEtSICAL COMPOSITION 

## INGREDIENTS: C.A.S. NIIMBER 

## Crystalline silica (quartz) 14808-60-7 

## Hydrous aluminum silicate 1332-58-7 

### EBPOSIIRE LIMITS 

## Crystalline silica (quartz) O.1 mg/m TWA (ACGIH) 

## Hydrous aluminum silicate 10 mg/m TWA (ACGIH)
SECTION III - PHYSICAL DATA 

## BOILING POINT: N/A SPECIFIC GRAVITY (H20): 2.3 VAPOR PRESSIIRE (mmHg): N/A $VOLATILE BY VOLIIME: N/A VAPOR DENSITY (Air=1): N/A EVAPORATION RATE: N/A SOLIIBILITY IN F7ATER: N/A APPEARANCE AND ODOR: Dark red with earthy odor.



# / Ob

### , , ) PAGE 2 

### SECTION IV - FIRE AND E%PLOStON HAZARD DATA - 0

FLASH POINT (Method Used): N/A F r.AMMAR 

### LE LIMITS: N/A 

## Lel: N/A Uel: N/A EXTINGUISHING MEDIA: Not flammable. May actually be used as an 

## extinguisher. SPECIAL FIRE FIGHTING PROCEDURES: None UNIISIIAL FIRE AND EXPLOSION HAZARDS: None

SECTION V- HEALTH HAZARD DATA - 2 

## PERMISSIBLE EXPOSIIRE LIMIT: As for the product ingredients listed under, "HAZARDOUS MIXTITRES, LIQUIDS, SOLIDS, OR GASES" in Section II of this form. THRESHOLD LIMIT VALUE: As for the product ingredients listed under, "HAZARDOUS MIXTURES, LIQIIIDS, SOLIDS, OR GASES" in Section II of this form. EFFECTS OF OVERE%POSIIRE: Dust irritates eyes and respiratory 

## tract. EMERGENCY AND FIRST AID PROCEDURES: Wash skin thoroughly with 

## water. Flush eyes for 15 minutes with gently running water. In case of inhalation, move to fresh air. PRIMARY ROIITE(S) OF SNTRY INTO THE BODY: Skin contact, eyes, 

## inhalation of fine fraction. MEDICAL CONDITIONS AGGRAVATED BY E%POSIIRE: Any debilitating 

## condition of the lungs, eyes, or other mucous-membranes. WARNING: IARC MONOGRAPH, `JOLIIME 42, "EVALIIATION OF THE CARCINOGENIC RISR OF CHEMICAhS TO HUMANS, SILICA.`AND SOME SILICATES" PUBLISHED IN 1987 LISTS SILICA AS A CLASS 2A CARCINOGEN. THIS MEANS THAT IN THEIR OPINION THERE IS SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY OF CRYSTALLINE SILICA TO EXPERIMENTAL ANIMALS AND LIMITED EVIDENCE FOR THE CARCINOGENICITY OF CRYSTALLINE SILICA TO HUMANS.
SECTION VI - REACTIVITY DATA - 0 

## STABILITY: Stable INCOMPATIBILITY (MATERIALS TO AVOID): None known. HAZARDOIIS DECOMPOSITION PRODUCTS: May release carbon monoxide and sulfur dioxide when heated above 260°C. CONDITIONS TO AVOID: Hazardous polymerization won't occur.

SECTION VII - SPILL OR LEAR PROCEDURES STEPS TO BE TAREN IN CASE MATERIAL IS RELEASED OR SPILLED:

~ 

## } Ordinary cleaning procedures taking care to avoid raising dust

clouds. Avoid breathing dust. WASTE DI6POSAL METHOD: Bury in approved landfill. 

# 1 `~~.GI- i 

### SECTION VZII - SPECIAL PROrECTION INFORMATION - E 

## ;SPIRATORY PROTECTION (SPECIFY TYPE): NIOSH approved dust .spirator if working in dusty conditions (above TLV).

, 

## CAL E%HAIIST: Ventilation to keep dust/fume level below TLV. *E PROTECTION: Safety glasses. 'HER PROTECTIVE EQIIIPMENT: None 

# Co

~ ~ ~



### SECTION IT - SPECIAL PRECAOTIONS 

## .ECAIITIONS: Avoid breathing dust. :E INFORMATION CONTAINED HEREIN IS BELIEPED TO BE ACCORATE AND GIVEN IN GOOD FAITH, HOWEVER NO AARRANTY CAN BE MADE.
:T 20, 1993 

### may rials 

### ano tion,
0 

### ~ It tne« 

### any any



## ~ 

# `{

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### Material Safety Data Sheet



## ~ .~ MERICAN MINERALS PRODUCT: 901 EAST EIGHTH AVENUE, P.O.BOX 1569 ..KZNG OF,PRUSSIA, PA 19406 MSDS: AMMNO2 Phone: Health & Safety Info 21S/337-1100 Date: 12/90 Revision: 6/93


### National PaiA •and Coatings Association Hazardous Material Identification 

### System HEALTH HAZARD 2- Moderate Hazard FLAMMABILITY HAZARD 0- Minimal Hazard REACTIVITY HAZARD 1 - Slight PERSONAL PROTECTION B- Glasses & Gloves 

# L SECTION I. MATERIAI, IDENTIFICATION

~ 

### an anese° ~ 

### dioxide Mno 2 Chemical Name: Pyrolusite, g" "" ( )' 

### Description: Pyrolusite ore (manganese dioxide) is used for many ir}dustrial and chemical applications. It is the source of manganese and all its compounds; largely used in manufacture of manganese steel; oxidizer; in alkaline batteries; decolorizing glass; in ceramic bodies and glazes. CAS#: 1313-13-9 

### Manufacturer: American Minerals Phone: 215/337-1100 ` I SECTION II. INGREDIENTS AND HAZARDS Ingredient Name: CAS Number: Percent: Exposure Limits: Pyrolusite (MnO Z ) 1313-13-9 72-80 For Manganese Dust, as Mn, and compounds CAS#7439-96-5 ACGIH TWA is Smg/m 3 . OSHA Final Rule 

### Ceiling: Smg/m 3 . FUME: OSHA PEL:TWA /Mn/ lmg/m 3 ; STEL 3mg/m 3 . Quartz (*) (SiO Z ) 14808-60-7 1-3 OSHA PEL:TWA for respirable 

### quartz - 

### 0.10mg/m 3 . Ciarium, Component oi Mn Ore 7440-39-3 1-2 ACGIfI TWAiie O.Smg/m s ae /Ba/. OSHA PEL:TWA 0.5mg/m 3 . ae /Ba/. Nonhazardous Ingredients (Nuisance Particulates) ---------- 15-25 Nuisance Particulates OSHA PEL: TWA, Total Dust: 15mg/m 3 ; 

### Respirable Dust: 5mg/m 3 . ACGIH TLV:TWA Total Dust 10mg/m 3 ; Respirable Dust: 5mg/m 3 . The product may contain a trace of lead which exists as an integral, complex mineralogical constituent of the manganese ore. The lead (0.0 - 0.2$) (Inorganic) CAS#7439-92-1 listed by IARC: Possible human carcinogen (Group 2B); human evidence is inadequate; animal evidence is sufficient. The OSHA PEL:TWA for lead is 0.05mg/m 3 . A substance specific st-andard applies (see 29 CFR 1910.1025). (•) A polymorph of crystalline silica. Identified by IARC as a"Probable Human Carcinogen" Group 2A. NTP listo respirable quartz amongst substances which may ( "rea3onably be anticipated to be carcinoqeno".

Page 1--- INGREDIENTS AND fiAZARDS continues on page 2 --- Page 1 

# ~ ~3Material Safety Data Sheet



## ~ AMERICAN MINERALS PRODUCT: Manganese Dioxide 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AMMNO2 

### Phone:. Health & Safety Info 215/337-1100 Date: 12/90 Revision: 6/93
SECTION III. PHYSICAL DATA Appearance and Odor: Black to brownish black and available in various size ranges from granular to fine powders; odorless. , Bulk Density: 125 - 132 lbs/cu.ft. (=17 lbs/gal) Melting Point: >2800°F Water Solubility ($): slight 8 volatile by volume: 0 pH (10$ Aqueous Slurry): 9- 10
SECTION IV. FIRE AND EXPLOSION DATA Extinguishing Media: Use dry chemical or CO Z on fires involving Manganese dioxide. Unusual fire or explosion hazards: Although not combustible, manganese,dioxide is a

### strong oxidizing agent. It may increase the burning rate of combustibles with a flareburning effect. It may cause reignition after a fire is extinguished. Oxygen from the thermal decomposition of MnO Z facilitates combustion.Special Fire-Fighting Procedurea: Since fire may produce toxic fumes, wear a selfcontained brsathing apparatue (BCSA) with full facapioce operatod in the pree3uYedeinand or positive-pressure mode. Be aware of runoff from fire control methode. Do not release to sewers or waterways.

I SECTION V. REACTIVITY DATA I 

### Stability: This product ie a atable at room temperature in closed containers under normal conditions of storage and handling conditions. Hazardous polymerization will not occur. 

### Chemical incompatibilities: Manganese dioxide is a powerful oxidizer, hence it should not be heated or rubbed with organic matter or other easily oxidizable substances, e.g., sulfur, sulfides, phosphides, hypophosphides, etc.. Flammable by chemical reaction. Incompatible with hydrogen peroxide; sodium peroxide. Keep away from heat and flammable materials.

SECTION VI. HEALTH HAZARD INF'ORMATION Carcinogenicity: The NTP, IARC, AND OSHA do not list manganese dioxide as a carcinogen. Summary of risks: Manganese is an essential trace element for living organisms. Although found in all human tissue, acute or chronic manganese poisoning can occur from excessive intake via inhalation or ingestion. Manganese dioxide dust inhalation can irritate the respiratory tract and lead to lung damage, pleuritis, bronchitis, and 

### increased incidence of respiratory infection. Large inhaled particles may be cleared from the respiratory tract and swallowed, but small particles are eventually absorbed into the blood. Medical conditions which may be aggravated by contact: Lungs; central nervous system diseases, psychiatric disorders, eyes. Target organs: Respiratory system, central nervous system.

~

~ lrimary entry route: Inhalation, Ingestion Page 2--- HEALTH HAZARD INFORMATION continues on page 3 --- Page 2 

# 1WMaterial Safety
. Data Sheet



## ~ AMERICAN MINERALS PRODUCT: Manganese Dioxide 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AMMNO2 a Phone: Helth & Safety Info 215/337-1100 Date: 12/90 Revision: 6/93 HEALTH HAZARD INFORMATION continued from page 2 Acute Effects: Exposure to high concentrations of manganese dioxide causes an influenza-like illness (metal fume fever). The 24 to 48 hour illness is characterized by chills, fever, aching muscles, dryness in the mouth and throat, and headache. 

### Manganeaa duet and tumos are minor irritante to tho eyes and completely innocuous to the intact skin. Manganese pleuritis, bronchitis, or pneumonia may also occur. Chronic Effects: Prolonged excessive inhalation can bring manganese into the body via both the lungs.and digestive tract (swallowed mucous). to cause systemic poisoning. Chronic poisoning is usualiy in 6 to 24 month. Syc:ptoms include apathy, anorexia, headache, weakness, and easy fatigue, then clumsiness, speech problems and other central nervous system effects. Progressive and permanent disability can result from chronic untreated manganese poisoning, but it is not fatal. Signs & symptoms of overexposure: Eye contacts Physical Irritation 

### Skin contact: Possible irritation from repeated or prolonged contact to

individuals sensitive to mineral dust. Inhalation: Throat and Upper respiratory irritation. yrst aidi Eye contact: Flush eyes, including under the eyelids, with large amounts of

water. If irritation persists, seek medical attention. Skin contact: Wash affected area with mild soap and water to remove any dust and

manganese dioxide adhering to the skin. Inhalation: Remove exposed person to fresh air. Support breathing as needed. Ingestion: If ingested, have victim drink 2- 3 glasses of water, then

induce vomiting, then seek medical attention.
SECTION VII. SPILL, LEAK AND DISPOSAL PROCEDURES Spill / Leak procedures: The product is not readily soluble, however prevent the spill from entering water and waste water systems. Cleanup personnel need to wear approved respiratory protection, gloves, long sleeved clothing and goggles to prevent irritation from contact and inhalation. Reuse all spilled material whenever possible. waste management / Disposal: The product is not a listed hazardous waste and does not exhibit any characteristics of a hazardous waste, including the EPA's TCLP for toxic characteristics. Follow all local, state and federal regulations for proper disposal.

SECTION VIII. SPECIAL PROTECTION INFORMATION Personal protective equipment: The use of safety glasses, gloves, and long sleeve clothing is recommended. The use of OSHA approved particulate dust respirator in accordance with 29 CFR 1910.134 must be worn for dust exposure above allowable expoeure 

## )% imits.

Page 3--- SPECIAL PROTECTION INFORMATION conti:iues oti page a --- Page J 

## / ~~Material Safety Data Sheet

~ AMERICAN MINERALS PRODUCT: I Manganese Dioxide I 901 EAST EIGHTH AVENUE, P.O.BOX 1569 K.ZN¢ OF PRUSSIA, PA 19406 MSDSs AMMNO2 

### Phone: Health & Safety Info 215/337-1100 Date: 12/90 Revision: 6/93 SPECIAL- PROTECTION INFORMATION continued from page 3 Workplace Considerations: 

### Ventilation: If airborne contaminants are generated during material handling, provide general ventilation and local ventilation in sufficient volume and air flow patterns to control air contaminant concentration levels below allowable exposure limits.

SECTION IX. REGULATORY INFORMATION AND SPECIAL PRECAUTIONS The product contains 72-80$ Manganese dioxide (Mn0 2 ) CAS#1313-13-9. Manganese dioxide ie not epecilically listed on any Federal ragulatory liots, howcver Manganese compounds, as /Mn/ CAS# 7439-96-5 are listed, and manganese dioxide falls into this classification. Manganese compounds, as /Mn/ CAS# 7439-96-5 are regulated under requirements of SARA TITLE III Section 313. The product contains 1-2% Barium. Barium compounds are listed under the EPA: EPCRA section 313; de minimis concentration is 1 percent. The product contains 0.0 - 0.2$ lead CAS17439-92-1. The lead is in the form of an inorganic lead compound. The EPA CERCLA RQ for lead is 1 pound. EPCRA section 313 de minimis concentration is 0.1$, and so it is reportable under SARA Section 313. Lead is listed under the following regulatory lists: Clean Water Act Sections 304 & 307, Safe Drinking Water Act Maximum Contaminant Level Substances & Statutory Contaminants, Clean Air Act Section 112, NIOSH Recommendation Substances, RCRA Hazardous Substances & Hazardous Constituents for Groundwater Monitoring, CERCLA Hazardous Substances, SARA Title III Sections 302 and 313, OSHA Air Contaminants & Specifically Regulated Substances, and the Massachusetts, New Jersey and Pennsylvania state lists. storage Requirementai Store in cloeed containera in a eool, dry, woll-ventilated area away from sources of heat and ignition. Protect containers from physical damage. Since manganese dioxide is a strong oxidizer, store separately from organic and other oxidizable materials. TSCA INVENTORY: A11 substances contained in the product are listed in the Chemical Substance Inventory of the Toxic Substances Control Act.
DOT Class: Not Regulated
SECTION X. REFERENCES References used in preparation of this material safety data sheet: 

### Clansky, K.B., Suspect Chemicals Sourcebook 

### , 1992-2 Edition, Roytech Publications, Bethesda, Maryland. Sax, N. Irving:

Dangerous Properties of Industrial Materials 

### , Seventh Edition, Van Nostrand Reinhold Co., Inc., 1989. Kirk, R. and Othmer, D., Encyclopedia of Chemical TechnologY 

### , Third Edition, WileyInterscience, New York, NY 1980. Sax, N.Irving and Lewis,R.J. Hawley•s Condensed Chemical Dictionary 

### , Eleventh Ed., Van Nostrand Reinhold Co.,Inc., NY M~ xtarial Safetv Data Sheeto 

### , Genium Publiehing Corporation, Schenectady, NY

Page 4--- MSDS continues on page 5 --- Page 4 

# 10
~ 

# 2Material Safety Data Sheet

AMERICAN MINERALS PRODUCT: I Manganese Dioxide 

# ~ 901 EAST EIGHTH AVENUE, P.O.BOX 1569 l KING OF PRUSSIA, PA 19406 MSDS: AMMNO2 

### Phone:. Hea"lth & Safety Info 215/337-1100 Date: 12/90 Revision: 5/93 SECTION,.XI. ACRONYMS/DEFINITIONS USED IN THIS MSDS ACGIH: American Conference of Governmental Industrial Hygienists CAS#: CAS Registration Number is an assigned number to identify a

material. CAS stands for Chemical Abstract Service. CERCLA: Comprehensive Environmental Response, Compensation, and Liability

Act (also known es superfund)(EPA). EPA: Environmental Protection Agency EPCRA: Emergency Planning and Community-Right-To-Know Act(SARA TITLE III) HMIST': Hazardous Material Identification System, National Paint & Coatings

Association. IARC• International Agency for Research on Cancer mg/m 3 : Milligrams per cubic meter NFPA: National Fire Protection Aasociation. NTP: National Toxicology Program OSHA: occupational Safety and Health Administration PEL: Permissible Exposure Limit (OSHA) RCRA: Resource Conservation and Recovery Act (EPA) SARA: Superfund Amendments and Reauthorization Act Title III: Emergency Planning and Community Right to Know Act Section 302: Extremely Hazardous Substances Section 304: Emergency Release Section 313: Toxic Chemicals - Reporting - Form R TCLP: TLV: Toxicity Characteristic Leaching Procedure

Threshold Limit Value (ACGIH) TSCA: Toxic Substances Control Act - EPA TwA: Time Weighted Average - 8 hours

Prepared/revised by: A.G.Nighswander June 7, 1993

Cti ~ 

### Although reasonable care 

### has been taken in the preparation of the information contained herein, American Minerals extends no warranties, makes no representation and assumes no responsibility as to the accuracy or suitability of such information for application to purchaser's intended purposes or for consequences of its use. Page 5--- End of MSDs --- Page 5 

# 1(7

### t



# C r~ 

## U. S. DEPARTMENT OF LABOR oMa No 

## ~ 44vR1387 

### ~ Occupational Safety and Health Administration 

# M.~~E~.aA~ 

# . SAFETY DATA SHEET

Required under USllL Safety and Healtli Regulations for Sliip Repairing Shipbuilding, atid Sliipbreaking (29 CFR 1915, 1916, 1917) 

## SECTION I lianufacturer's liame t:ii 

### ~~ rgen2



### ~ 2-t635 

### ~ lloi:e 

### ~ !o. 

### WYO-BEiJ, IP

~ 

### C. ( b) 

### ress •

~ 

### o, treet, City St nd Zip Code) 

## 1242 N. 28th Billin s P 

## ~IT ~~f0~ iemica wame and S uonyms 1'ra e Nan

~ P and nony is 

## odiu ort mori 

## ~ lonite (Western Bent_onite H 

## ~ rogel, Big f 

## ~~ rn, 

## ~ nviroael Inorganic (Mineral) Empirical Formula:"R

~~~ •66(A13.20'Fe.40

~ M9.40) (Si ~ 75 , A1

~ S O ZO 20H Z • "N"H ( Who..o IIRII — (.atinn- "N" = Variahle 

## SECTION 11 =HAZARDOUS INGREDIENTS PAI;ITS, PRESERVATIVES & SOLVL•:NTS % 

### TEV Units) ALLOYS AidD PIETALLIC COATINC;S 

### I % 

### TLV l(Uni ts Pigments N/A Base 1•fetal 

### Catalyst Allo s Vehicle N A 1~ietallic Coatin s N/A 

### Solvents N A Filler Metal 1'lus 

### Coating or Core Flux N/A Additives N A Others 0 tliers IIAZARDOUS i•iI:CTURES OF OT1IEIt LIQUIDS, SOLIDS, OR CAS1:S o 

# v (Unics 

## Low concentrations of cr stalline silica (Si0 ) in the form of quartz, cr stobalite and trid mite may be present iSee in the bentonite dust. Sec.



# SECTION 111- PHYSI CAL DATA 13oiling Point oF. S ecific Cravitv H

~ 

### 0=1 2. 35 Vapor Pressure (mm Flg. ) N/A 

### erccnt, Volatiie bv Vo ume M N/A Vapor lleiisit (Air=1) N/A L•:vaporation Rate =1 N/A Solubility in ldatcr liPcaraiice and Uclor



## SECTION IV- FIRE A1VD EXPLOSION HAZARD DATA .l5h ulill' Mctliod. used FlU lllm:lb1(. Llni.its Lel Uel L:xtinguisliiiig 1•(edia A Special 1••ire 1••igiitinb 1'rocedures N/A

•i:usuai Fire aiid L:<piosion liazards N/A 

### V

Copied from — Form OSHA-G 

# ~ Rev. May 72 l7 

### (Continued on reverse side) Page 1

### DUCT : SOi7IUM HEXAMETAPHi7SFWATE

03/02/98 11:84

~ 

### REPDRT WUM8ER: 703 MSE3S N0 t P1427 

### EFFECTIVE t7ATE: 07/18/91 ft NU.b'('( roeb



## PACE: OOA VER510id : 008



### £1ROER N0: 284865 PFtbD N0 t 347£300 

### VAN WATERS & ROMERS IhEC. MATEFiIAL 8AFETY t3ATA SHEET



## MUTUAL MATERxALS Cn. ~ 

### hEuCASTLE PI.ANT 6620 COAL CREgK PlCWY S. E. RE:NTON , WA S'8055 , 

### VAN tJATES2S & ROt3Ef2$ IhC. , SUF35I1]IARY (?F UNIV

~ 

### iR (206)A69-3+400 6300 C14RILLOi+E POIt

~ 

### l7' , KIRKf

~ 

### Ai

~ 

### ll]

~ 

### , EJA 98033 EMERGENCY ASgISI'AhtCE 

### Fi]R EMeRt3ENCY ASSxSTANCE YNVDI.VINO CHEMICALS CALL - CHEMTREt; 

### (Q00)424-9300

, FOR PRi]f?UCT AND SALE5 INFORMATIQN ----........--....--_-__. 

### du CANTACT YGUR LQCAL VAN WATERS & ROGERr SRANCH OFFXCE AT

VU&R KENT 206-872•-5000 KENT , WA 

## ,_--....-..-_----,.--_-_........MpRODUCT IDENTIP'IGA 

## TzvN ---------------------------- PRqOUCT NAME t SOnIl1M NEXAMETAPHpSPHATE CAS Nb. : 68915-•31--1 

### COMMON NAMEE3/SYNCINYMS t MS4S #: P1427 $HMR 

### ; GLAgSY liODIUM; VITPAFCTS ( R) ; METAFtl5( * ). 

### AQtJAS7AR ( TM ) 500 FOttMULA : UNDEF INED f3ATE YSSGFD :?.0/90 

### MC3L.ECULAR WEIgH r UNQEFINED SUPE:RCEDES; 04/90 

### NAZAftD f2ATI t ~ 

### lFPA 704s u ~ 

### 3A) ~ 

### r ~ ~ R r.S..• ~. ~ 'TC~•' ~ ~ja'~, t~,'• c ~ C.C

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# ~ .HAZARD 

## T~~? #~ 8 CA L E ; FIi 

# ~ Et O 0=MINIMA; 

# ~ S0IGlU8 REACTIVITY: 0 1=31.ICHT 4ORSEVERE SPECIAE. t NON£ 2-MClDERA1•E -------------------------- HAZA 12 C1OU5 :C NG i2E D z ENTS_-_-_-._.._-_----..-w----...._-- EXPUSURE LIMITS, PpM OSNA ACGIH OTHEF2 CflMPi3NENT CAS NO. ?G PSL TLU LIMIT NAZARfJ . DIUM HEXAMETAPH(lSi'HATE 68915-31-1 >99 NtaNF' 

# ~ UNE NONE NaNE

~ 

### (R) 1'RA(3EhiARK OF STAUFFER CHFt11CAL 

### CONPANY; l 

# ~~03ie2i99 11: 04 rAU. 677 PNe'?

~ 

### SREPORT A!lJti$E12: 703 VAN WAT1=:RS & ROGERS INC


### . PAGE: : 002 riSnS NO: P1427 MATERIAL. SAFE.TY CiATA 5HEET EFFCCI'IVE 13ATE: 07118191 VERSION: 008 OOLiCT: StlDYUM HEXAMETApHVIPHATE ` ORQER NU: 284$65 PROD N0 : 347800
(*) 'f•RApEMARiC 0F ESbEX IAtE3iJSTRSAI. CHE1•iICALS, xNC. 1 Thi ) TRADEMARK OF MqNSAN7t3 PRLIPERTIES_-...............__-__----------_---- ~ 

### 801i..ING POINT. DEG Ft N/A ~ 

### VAPOR PRESrURE, MM HG/20 DEG C: N/A 

## pFi: 6-$ (I'/• SOLN, ) a MEL.TIkG POINT, QEG F t 1162 VAPOR DENSxTY (AIR=1) : N/A SPECIFIC Gl7AVYTY (WATER-1) + : N/D WATER S(]i-UDILXTY, X: 133 APFEARANCE AN[1 ObOR: EVAPORATICIN RA'1"E' (f3U'TYL ACETATE=1) s N/A WHITE PC1WnER, (3l2ANUL.ES OR GLASS PLATES; t]0012LESS. ;v VOLATIl.E (8Y VOLUME): 0 

## _..-«.........__-...---_..__-..w......F'XOST ATQ IF INHALEGt REMOVE Ta FRESH AIR. GIVE ARTYF'ICxtqL kESPIRATION IF NOT EATHING. (sET IMMEDIATE MEDICAL ATTENTION. IN CASE OF EYE CONTACT: IMMEDIATELY F'k.USH EY1`:S WITH t.ATS UF RUNNING WATkR FqR 15 MIHUTES, LIF'TING THE UPNER AND LOWER EYELIDS ACCASIONALLY. GET IMMEQIATE 1"iE(31CAL ATTENTION.
. IN CASE OF SKIN CONTACT: IMMEnIATELY WA5H SKxN WITH I.OTS i3F SOAi) ANG WATER. REMOVE CONTAMINATEI] CLOTHING AND SHEIES: WASH BEFORE REUSE. (3ET mEDYCAL. ATTEN'fION YF ZRRITATIt]N PERSXSTS AFTER WASHING. :Cf= SWAL.LOUED: 00 NOT INOUCE VOMITING. xF GONSGIOUS, GIVE: I.OTS OF WATEFt OR 

### MILK, t"sET IMME13IATE MEDYCAL ATTENTTL7N. 00 NDT GIVE ANYTFfING 8Y MOUTH T© AN llNCONSCxauS OR CONVUE.SINt3 PERSON.

.,...... w ..»......_---_..--HEAL1'W HAZARt] INF't]RirfAT:CaN ------------------------- 

### N12xMARY ROUTES OF EXPOSURE a SKIN nR EYE CONTACT , INHAI-ATIQN. aIGPlS AND SYli1'TUMS OF EXPOSlJFiE INi-tALATION: NQNE CUI2RE.N'rt-Y KNQW14. EYE CONTACT: RU5TS MAY IRRITATE THE EYE:S, SKIN CaNTACT r NL7NE CURRENTLY KN(7WN. sWALL.OWEQ: SLIGHTLY HA7.AR4(3LI5 f 

# ~ IRqNIC EF'FECTS OF EXPOSLIRE: ; N0 Sf'E:CyXF i.0 :fNFaRMATIDN AVAII.ABLE.



# ~ 

# 5_1)e3i02i98 11:04

~ l 

### EPQRT NUMgt:R: 703 5US N0: P1427 FF'ECTxVE I]ATE: 07/18/91 

### ig VAN WATERS & 1?qGt:RS INC, MA'rERxAL. SAFETY DATA SH>_'E:T N0.677 P008



### PAGE: 003 VER3ION: 008 

### lIUCT : SOpIlJM HEXAMiETAPHOSPHATE (JRDFR Nfl : 284865 PROD NO r 347$00



### iEOICAL CbNqITxONS GENERALLY AGGRAVATEi1 DY EXPOSURE: NQNE REPn1tTE[1. -_Y-............-..------.._......«........-...TOxICITY f3A rA....... _.._...-... .._.._....____......_.......... 1RAL : RAT LdSt? = 2.9 G/KG . 

### TERMAI.t RABBfT LI]50 ) 7.94 G/KG. %NHALATxt?N: Ntl t?ATA FQUN[!. , 

### :ARCXNOGENICITY o THIS MATERIAL I5 NC3T Ci]NS2l3CREEI TA DE A CARCXNC3Git

- N 3Y THE NATxCaNAL TI3XICOLOGY PRI7GRAM, THE INTEF2NATIqNAL AGENCY F19R 2ESFARCH dN CANCER, OR THE OCL"i.fPATIONAL SAFETY ANtJ HEALTH AAMINISTRATxE1N 7T1-IEfi t1ATA: NQNE . 

# IR TILATIONt GEN£RAi. 

### RQqM VFNTILAI"r0N.IESPIRATORY PRQTECTIQN: IF USE CaNDI1'If1NS GEi<lERA'T'E pUSTS, WEAR A NI©SH1i'PROVE# RESPIRATOR APPROPRIATE FtiFt THOSE EM7SSION •LE.VELS. APPRC?P=='ATE 2ESpIRA1"ORB MAY 8E A F'tJLL FACEPIECE OR A HALi`' MASK 'AIR-^PURXFYINGi RI DGE RESPIRATOR WITH PARTICULATE FILTERS, ABELF--CQNTAINED 8REATNl;4t; APPARATUS IN THE t'RESSURE E7EMAND MODE, OR A SUPPLIEti-AIR RESPXRATqR, EYE RROTECTION: CHEMICAL G[IGGLES ANCI F'ULI. FACE SNIFLD. IT IS GEPlERAi,.LY RECL1Gi+tIZED THAT COi`lTACT LENSES SktqtJLC NCl'r SE Wt3l2N llHEN iJt]RKYNG WITI-E CHEMICALS SECAUSE Cf}NTACT LENfiES MAY t.'ONTRI$UTE TO THC' SEVERITY OP' AN EYE xNJURY. ti Pf2OTECTxVE CLOTHxNG s LONG—SLF_EVED SITY RT , TROIJSC=RS , SAFETY SNf3E^a , RU£313ER Gl.OVES, ANb RU6BER APRON. i OTHER PRflTECTIVE "MEASURES: AN EYEIJASH ANEI SAF ETY 9NOWER SWL3ULU F3E PlEARSY AND REAbY FL7R USE. ---------------------FIRE ANO EXF'LOSION INFORhSATION ------------------------ 

## FLASH POINT, OEG F: N/A FLAHMAeLC LxMxTS IN ArR, X METHC2D USED: N/A LLIWER : N/A Ui'PER : N/A 1OIGNITSQi`! TEhiPERATURE, DEG.F: NO't APPLZCABLE 

# IWTXNGIJISHING tiEDIA: THIS MATERIAL IS NOT COMBUfiTjHLE, USE EXTINGUISHING MEDIA APPROPRIATE FOR SURRCfUNQl:Nt, FIRE. 

# 15~b 3/ uG/ yti 11 : 04

~ 

### REPORT NUM9Et2 t 703 MSDS N0: PI427 

### EF'FECTIVE DATE c 07/18/91 VAN WATE'RS & RCJfxERg XNC. MATEaIAE, aAFETY DATA SHEET N0.677 P009

PAGE s 004 

### VERSIOtd: 009 DtJCT: SOt3XlJh3 HEXAMETAf'H03PHATi_ ARtlER N0: 284865 !'RE7D Ho : 3478o0



### SPECIAL FxRE FIGt-tTING PRf3CE0ilRES: USE E.lATER SPRAY 7'Ct C£!OL NE'ARE3Y CdNTAINERS AND STRUCTLlRES EXPOSF.O YO FxHE, UNUSUAL F I RE AND EXPLOSION HAZARDS : N0NE . ---------------------------HAZARtIf]US 12EACTIVITY -------------------------

- 

### ---- 

## STASxLxTY; STASLE POLYMERIZA7'IUN: WILL NOT i3CCUR C0NDITIt3NS TCl AVL1ZDs HEAT, SPARKS, ANt3 aPEH FLAMES. MiRTERIALS TO AVOIGt C)XIqXZE:R:i, HAZARDOUS DECCIMPC)SITxON PRCIFJUCTS t NDNE

---------- .r ------- SPILL, LEAK, ANC1 37ISPpSAL < PROCEUURES-----------•---.--__--_--_- ACTXON TO TAKE FOR SPSL„l„$ QR i.EAKS: LJEAR PR[?T£CTIVE EiQUCE'hiENT INi:LUi3ING BER E300TS, RUp9ER GLOVES, RUBBER APROM, AMn A SEL,P'wCONTAINF:D ATNING APPARATUS IN THE PRESSURE tIEMAidD MODE OR A£3Ui'pLIC

- t3--AIR RESPIRATQR. IF THE SPILL ilR LE=AK IS SMALL, A FULL FAC:EPIECE AIR-- 

### PURIFYING CARTRIDGE EtESPIRAT0R EqUIpPEG l3ITH PARTICULATE FILTEs'RS MAY SE SAT I SFAC TO RY , I N ANY EV£NT , ALUAYS NEA R ErYE P RC3TEGT ION . FO RSMALf.. SPILL"3, SWEEp Ut' ANO 13SSPf3SE (lF IN DOT-AE'PROVE:CJ LsASTE CUNYAYNERS. F'OFt LARGE SPxLLS, SHOVEI. INTO DOT-APPROVER WAS7'E C:ONTAINERS. KEEF' OUT OF' 3FrEJE{2S, STORM CIRAINS, SURFACE WATERS, AMII rfltL. COMPLY 1.iITH ALL APPLICABLE (3t7VERkMEN1'AL REGULATIQNS ON SPIL.L RF.PORTIHt3, ANn HANQLING AND blSpCfSAL UF WASTE. RISPOSAL METHOflS: OISPOSE OF C0NTAMxNATED PR!OaUCT AN!S MATERIAI.S USED IN CL,EANZNG t!P SPxL.LS OR ErEAKS IN AMANNER APPkt)VED FOa THIS MATE±RIAL. CONSi.}LT APF'RdS RIA7'E FEi1ERAL, STATE ANE3 LOC:AL REC3UL.ATQRY Af,ENC:XEES 'f 0 ASCERTAxN PROpER DISPOSAL PROCEDUI2E;S, Nf?TE : EMPTY C0NTAIi'lERS CAN HAVE RESx DUES , GASES AND MISTS AND ARF: SU8JEC1' Td PROPER 4lASTE•. DISPOSAL , AS ABUVF_ . ~


### STORAGE ANII HANkIi.ING PRECAUTIUNS: STURE IH A CUOL , GRY, WELL-VENTILATEb P}...AC£ AWAY FROM INCOME'ATYBL£' MA7'ERIALS. KEEP BAE'sS OR FIE3ER DRUMf4 DRY AT ALL TIMES. lJASH THClRt3UGNLY AFTER HANnLiNO. 00 NOT GE1' IN EYES, ON 

### SKIN, OR ON CLOTNYHG. REPAI.R AND MAINTENANCE PRE:CAI1TiUNS: N0NF_.



# ~ ER PRECAUTZONS: CONTAINF-RS . EVE N THOSrE THA7' HA _ E3EFJ ~ E~ 

### IPTIFD , 41Il..l. RETArN I
~ 

### ROqUCT RESInUE ANO VAI ~ 

### ORS. Af.
~ 

### iAYS OBE:Y f-lA
~ 

### iRO UAi2NINGS ANU HANDLE EMPTY COS`lTAINERS AS I1= THEY WERE F'Elf_L . 

# ls03/02/98 11:05 NCi.677 P010

. .-. ~

. . 

## 17EPORI' NUMBE-A t 703 VAN 4lATERS & F2fJGERS INC . PAGE : 005 ,KSI]S N0: Pi427 MATERIAL SAP'ET'Y DATA 5HEET EF'FEi:TIVE OATE t 07/18/91 VERSIaN s 008 C3ClUCT : StlaIUM HExAMETAPHO"cr'I-#ATE
~ 

## QRDER N0 c 284$65 PROD NO : 347800



## _.—_—._._._—_____--._--.__—..ECOLOf3It;A1. xNF0i7MATTQN SEC1'I0N. ------------------ Np OATA F
- OE1ND 

## ...—.. _....---_------------OTHER RgGULA7i7RY I

~ 

## lEU(2

~ 

## SATIOt

~ 

## E_..._____..... , _....__....... , ......... Sk.CTIQN 313: SEE RELQW 

# 1 f'RQPOSITION 64 t :3EE BELOI.i SECTION 313 & PRt3P. 65: SEE 8E1.CIW SECTIUN 313 (lJYTH CHEMYCALS LISTED e NdAlE I'E2C1P09ITX0N 65 <WITH CHEMICALS LISTED> s 

## iMASSACHUSETTS: NONE '


## NNSYLVANXA: NGNE CAL.IFORNIA SCAQMD: NflNi: TSCA: T'HE INGREDIENTS OF THIS PRQDLlCT ARE ON THE TSCA INVENTORY. 

# ------_.--..—__-----__-----.-----.._--REV 05/89s REVISED FIRST AIf3 ANn VENrILATI©N RECqmMENpATZONS. 

# --_..-----.__..----_

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# __--..___--_.

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# R£VISLON

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# ,_..,--_......

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## 2iaterial safety Data Sheet

AMERICAN MINERALS PRODUCT: 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AMCHROMITE Phone: Health & Safety Info 215/337-1100 Date: 1/4/90 Revision: 12/92 HEALTH HAZARD 2 - Moderate FLAMMABILITY HAZARD 0 - Minimal REACTIVITY HAZARD 0 - Minimal PERSONAL PROTECTION B- Glasses & Gloves National Paint and Coatings Association Hazardous Material Identification System

SECTION I. MATERIAL IDENTIFICATION Chemical Name: Chromite Common Names: Chrome Ore, Chromite, Chromite Ore, Iron Chromite, Iron Chromite Ore Description: Chromite-is a mineral composed of a natural oxide of ferrous iron and chromium, with varying amounts of magnesium and aluminum substituting for the iron and chromium respectively. It has the general formula of (Fe,Mg)O•(Cr,Fe,Al) Z O 3 . CAS#: 1308-31-2 

### Distributor: American Minerals Phone: 215/337-1100 SECTION II. INGREDIENTS AND HAZARDS Ingredient Name: CAS Number: Percent: Exposure Limits: Chrome Ore 1308-31-2 100 For Chromium (III) Compounds as /Cr/ ACGIH TLV:TWA is
. 0.Smg/m 3 . This would equate to a chrome ore dust exposure of 1.62mg/m 3 for a chrome ore containing 45$ Cr Z 0 3 . OSHA Typical Chemical Analysis, Wt.$ PEL:TWA for Chromium (III) Si0 2 1-5 Compounds Final PEL 0.5mg/m 3 . Fe0 15-25 FOR ORE PROCESSING 

### • ACGIH A1 Z O 3 10-20 TLV:TWA - 0.05mg/m. For ore Mg0 10-20 processing, chrome ore is Ca0 0-1 listed as a Human Carcinogen. Cr 2 0 3 35-45 The oxides shown in the

- Typical Chemical Analysis" do not exist as free, uncombined oxides, but exist in complex mineralogical combinations.
SECTION III. PHYSICAL DATA Appearance and odor: Chrome ore is usually black, but does show some variation from iron-black to brownish black with some brown streaks. Various grades can vary from large pieces down to fine powders. Chrome ore is odorless. Apparent Density: 4.3 - 4.5 g/cc. (37 lbs/gal) Melting Point: >3400°F Water Solubility (%): 0, Insoluble in Water % volatile by volume: 0 Page 1 --- MSDS continues on page 2 --- Page 1 

# l~~

### Material Safety Data Sheet AMERICAN MINERALS PRODUCT: CHROME ORE 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AMCHROMITE 

### Phone: Health & Safety Info 215/337-1100 Date: 2/14/92 Revision: 12/92
SECTION IV. FIRE AND EXPLOSION DATA Extinguishing Media: Chrome ore is not combustible. Use extinguishing media appropriate to combustibles in the surrounding area. Unusual fire or explosion hazards: None Hazardous decomposition Products: None
SECTION V. REACTIVITY DATA stability: Chrome ore is an inert and stable mineral. Hazardous polymerization will not occur. Chemical incompatibilities: Chrome ore can react at high temperature with molten alkalies and alkali vapors forming water soluble chromium salts. storage: Chrome ore is stable under all normal conditions of storage.
SECTION VI. HEALTH HAZARD INFORMATION Summary of risks: Exposure to chrome ore presents a low order of risk. The primary health hazard is the excessive inhalation of dust generated during handling operations.
health hazards such as 

### : hexavalent chromium compounds produce a corrosive action on any skin arid mucous membranes they contact; chromite salts are human and experimental carcinogens of the lungs, nasal cavity and paranasal sinus, and are also experimental carcinogens of the stomach and larynx; the hexavalent (VI) chromium compounds are more toxic than the trivalent (III) compounds. Eczematous dermatitis has been reported for some trivalent chromium compounds. A competent industrial hygienist should be consulted for evaluation of potential health hazards associated with specific chemical processes involving the use of chrome ore. Medical conditions which may be aggravated by contact: The excessive inhalation of mineral dust may aggravate pre-existing chronic lung conditions such as, but not limited to, bronchitis, emphysema, and asthma. Target organs: Upper Respiratory System Primary entry route: Inhalation Acute Effects: The excessive inhalation of mineral dust can cause a transitory upper

respiratory irritation. Chronic Effects: The chromium in chrome ore is in the trivalent (III) form. Trivalent Chrome oxide (Cr Z 0 3 ) is reported to have a low order of toxicity. The IARC - Cancer Review: Animal - Inadequate Evidence. Chrome ore is listed as a human carcinogen in ore processing.

Page 2--- HEALTH HAZARD INFORMATION continues on page 3 --- Page 2 

# l~~

### Material Safety Data Sheet AMERICAN MINERALS PRODUCT: CHROME ORE 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AMCHROMITE Phone: Health & Safety Info 215/337-1100 Date: 2/14/92 Revision: 12/92

I HEALTH HAZARD INFORMATION continued from page 2 1 

### Signs & symptoms of overexposure: Eye contact: Physical Irritation Skin contact: Possible irritation from repeated or prolonged contact to

individuals sensitive to mineral dust. Inhalation: Upper respiratory irritation. First aid: Eye contact: Flush eyes, including under the eyelids, with large amounts of

water. If irritation persists, seek medical attention. Skin contact: Wash with mild soap and water. Inhalation: Remove to fresh air. Ingestion: No data available.

SECTION VII. SPILL, LEAK AND DISPOSAL PROCEDURES ( Spill / Leak procedures:

Chrome ore is unreactive and insoluble in water and acids. Reuse all spilled material whenever possible. Thoroughly cleanup spilled material and place into a suitable container, being careful to avoid creating dusty conditions. If conditions warrant clean-up personnel should wear approved respiratory protection, gloves, and goggles to prevent irritation from contact and/or inhalation. Waste management / Disposal: Chrome ore is not biodegradable, and does not exhibit any characteristics of a hazardous waste. It is insoluble by EPA's SW-846 TCLP methodology. It is suitable for landfill disposal. However, used debris containing chromium must be evaluated for the Characteristic of Toxicity to determine the method of disposal. Follow all local, state and federal regulations for proper disposal.
SECTION VIII. SPECIAL PROTECTION INFORMATION Personal protective equipment: The use of safety glasses, gloves, and long sleeve clothing is recommended. Workplace Considerations: Ventilation: Provide adequate general ventilation and local ventilation in both sufficient volume and air flow patterns to keep air contaminant concentration levels below allowable limits.

Page 3--- MSDS continues on page 4 --- Page 3 

# l 5-; ~

### Material Safety Data Sheet AMERICAN MINERALS PRODUCT: CHROME ORE 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AMCHROMITE Phone: Health & Safety Info 215/337-1100 Date: 2/14/92 Revision: 12/92
SECTION IX. REGULATORY INFORMATION SARA TITLE III INFORMATION: 

### The product is 100$ chrome ore CAS11308-31-2, which is composed of up to 42$ Chromium and reportable under SARA TITLE III Section 313. Chrome ore is included because of definition given in 40 CFR Ch.l Part 372.65 on chromium compounds. Chrome ore is not listed under SARA TITLE III Sections 302 and 304. TSCA INVENTORY: Chrome ore is listed on the Chemical Substance Inventory of the Toxic Substances Control Act (TSCA). DOT Class: Not Regulated I SECTION X. REFERENCES I Sax, N. Irving: Dancrerous Properties of Industrial Materials, Seventh Edition, Van 

### Nostrand Reinhold Co., Inc., 1989. Kirk, R. and Othmer, D., Encvclopedia of Chemical Technolo4y 

### , Third Edition, WileyInterscience, New York, NY 1980. Clansky, K.B., Suspect Chemicals Sourcebook 

### , 1992-2 Edition, Roytech Publications, Bethesda, Maryland. Sax, N.Irving and Lewis,R.J. Hawley's Condensed Chemical Dictionarv, Eleventh Ed., Van Nostrand Reinhold Co.,Inc., NY,

I SECTION XI. ACRONYMS/DEFINITIONS USED IN THIS MSDS I ACGIH: CAS#:IARCmg/m 3 : NFPA: 

### OSHA: PEL: S ARA : 

### Title III: Section 302: Section 304: Section 313: TC Rule: 

### TCLP: TLV : 

### TSCA: TWA: American Conference of Governmental Industrial Hygienists

CAS Registration Number is an assigned number to identify a 

### material. CAS stands for Chemical Abstract Service. International Agency for Research on Cancer Milligrams per cubic meter National Fire Protection Association occupational Safety and Health Administration Permissible Exposure Limit (OSHA) Superfund Amendments and Reauthorization Act 

### Emergency Planning and Community Right to Know Act Extremely Hazardous Substances Emergency Release Toxic Chemicals - Reporting Toxicity Characteristic Rule Toxicity Characteristic Leaching Procedure Threshold Limit Value (ACGIH) Toxic Substances Control Act 

### Time Weighted Average - 8 hours Prepared/revised by: A.G.Nighswander, December 9, 1992 Although reasonable care has been taken in the preparation of the information contained herein, American Minerals extends no warranties, makes no representation and assumes no responsibility as to the accuracy or suitability of such information for application to purchaser's intended purposes or for consequences of its use. Page 4--- End of MSDS --- Page 4 

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AND EXPLOS1ON HAZARDSi Hope.

~ 

### ~ [JIONS/PROCEDURIES

n ~ 

### WSHTNG 4GENTS RECOMMEND[D: NA nG(/lSHIN8 AGENTS TO AVOID: N j -' j 3PECI PE FIGHTI@G PREC4UFIONS: N,-

~ 

### , /ENTI': ` , A/ Loral +xha;st if dusty cn'.ditN`n prevails.

~ 

### O i -; 1 5LING/ Avoid eye contact or |'`ol,/g ~~ 

### skin co.tact. Avoid

1 du1t. When dissnlving ' a6d to later cp`^tiously anJ With s ~ ~ 

### ,n/ solutiuns c an get hvt.

ntore in a scol ' dry arpa awly fron acids. Prol:xg*d otorase mi ~ 

### co p'oduct to cake from atmvsphe'ic ncisture.

~ 

### PIL (ALUAyS WEAR PERSONAL [KY[CTTWE EAUlPMENT - S[ETION E);

dry cheoical into an enpty coo+ainer uith a cover. Flos ~ 

### ro' o`ith plwnty op watsr, CSce O+cti^o I fop disposal mathods) '

~ 

### `LCA 0 [IQN5!PRQQE0URES/LA8Ei lNSTR'CTIONE/ S1GNAL UCIU - WAkNNG A ~ 

### ..i^ultanenus pm6yu'e to so&a

~ 

### 15 lin.e dcst. In the pres ^ -or^ af `.|ure ths t4n waoerials combins t, `

~ 

### m caus
~ 

### ic s,do UQi'IPMENT '
/ ' ! /

~ 

### ' '

i ~



### / '

. ~

~

~

Y-<EPUI %H; 703 ISDE . 100100r.' 

### lRbuji TOGA Asi.; VAN WAYERS I ROGERS INC. MATEPIOI. - EAFEA( OATA SHEEf 

### P A & VERSTON

ORDER NO: 20028. PROC NO ! 5025 ~



### 0, ".) ... !:',. (AT NORMAL CUNUTYIONEO;

~ OLVD APPEA AND ODUR: White powdep, Djqpiny

~ : 1010i 

### JNQ N(.'t 

### iELTI P - :':Nv. 854 ce

~~ Dws C iPECI" 

### qAQ 1 

### 7Y C 

### H29-1 ) : 

### 2, 503' 'APOW 

### &Ty (AIR- ! ) ; N.' , , 3OLUO: •1 IN WnTLR Q hy Weight)! 17X nulyf;on at 20 Degree( E: 

### )A I:. , D 1 ,- :VAPO" 4 RATE: 

### N 'A ; VO; . : 1 OY VOLUME (At 20 Degrees O. ; Nf.: 

### 1, RC. j C 

### rY OAP"'i

A F AVOTS: None, 

### N C0 

### ::t TTY (MPTVRIALS TU 

### AVOTO) , 

### Conta7 ~ 

### with acids will C j I :~ 

### xiKe gus. 

### When mixod wit n I 

### im, dust and water , 

### coppnGiv(-.-.-- C: o:': i:odo may 5e produced, 

### PRDDUuTS: SLL ; 

### =OMF64 101LITY (MA YEN TOL I TO AVn 1 P: IAZARP POLYMERTIATAnNi WILL NOY OGCU! ~ 

### o n 

### 2 j , 

### ?'S 

### INGREP, 7PTS 

### (Mixtures On

)EBRO: VY/AQUAI f C 

### T OX I C I TY: Nl.) C C'4& 

### Pnk Q :j& 

### COEFFICIENT; E 1 , 

### P L E A 4 0 A 1 E R 

### T K I C 3 11 4 i~ 

### :.` I. YO REPBRTABLE UKONVIr! (10 CFP 116_117, 

### S

~ 

### TKKOSER "US! - 

### VMCL 4TH FE5LRAL, 

### SIAIP 

### 4 0 A CO -AT

~ 

### %T ~ 

### o 5y appll

~ avlv 

### a ; S; ~ 

### in ! 1 n 0 st or dinoviva nonvToll ,



### t er 0

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### "sh al SOL,iit

### P120 !~~ 60 

### ing na 5y zn appro voj q 

### -n 

### TF rj. - QDE Not a Wiardann 

# /0

### .43LN: 202 msom 0100() 03/12/93 200A Asl-; VAN k-TER6 1 RopFUS INC,


### - MAYERIQ KAF

~ YY DATA KHEET' 

### poov , 

### VERSION;

ORDER •o. 4012. PROD No : 5025 -

PEPK ~ luLn CONCENTRATION REFERENCEb: Nu; 

### i ` • 

### yt,, 0,0,! '

~ AqKTFICATKN: Not reguittej C49 7~ 4 173) Seneval Cnemicat Uorp

~ rwhljn Ypta, UnPublished;

This not roy use " a fOOO 

### NOT YE 

### !ERMINEo NA - NO! APPLICAOLL.: A PROPRrETARY - TRADE SLOOKI 

### MAXAL A NYORMAI LON 006 1 ;ORYLAND 5URIN6 TOSINEss HoURS, PArXK VIMP (2c6)R09-3400 11:42 P%0UC7: 5C2572 SU57 NO: 107569 CRUER NO: 20711;

CLECLAIMS ALL EXPRESO

.. .... . . ... .... ...... .. ........... ... ........... . ......... . .... .. OR , 1 1 1 p L 

### T >VANTIES Cv OCROHANTADfLITY

. .. . .. .... .... .... .... .... 1 :YKIS FOR A PARTICULAR PUppp,_

.... .... . ....... ..... ........... . . ... ... THE PRLOUCT OR INFORK07LON

~ ADVIQED HEREIN, AND SHALL UN10'':

.... .. .... .. .... ....... .... .... .... ... ... ........ ....... NO ;jNCES BE TAULF FiR lNGAUK,TAL 0 0

. . .... .... .... ... . ZONSEQUENTIAL

. . . . ......... .... ............ .... .... .... . . ... 

### ... ... .... .... .... .


### OPPEAWINO AEREI N 0 S p ,. ~p Lk 9 

### , T , MA" HEQ

~ SQ/ED AECHNICAL KV

~ nKS, WHILE THE ANFOPNOVIDN
~ 

### li:: Ll:''

- ACC49 0 TU, OWoP MAKEb PC PPYREQNTATIONS AS

~ 0 TTE APCURAG ~ suppi CONDITEDNE UF WOE AkE HP7ND OWIRS CSNTROL ?NO THEREPCgE KQKn

~ 

### l R f:

~ - tynF TU VSWL O Y TPQ DATP

~ NBVY 7- jVR OWN OPERATINj CDNUITTnNo

~ ., 0C

~ WVTHER THE ORJOiK7 • Sjl - APIV i - P THETR PARTICULAR PUxPSSES pn ~

1:0KO 2v Tnk!Q

~ VE, HANOLINC AQ ~ THE nVGPEIAL OF FRQ

~ KCT, oN i.

~ K OR PELTPN

~ E "PV
~ INFORMATION a5NTQTNFP kn

~ l PAWXG ~ jESTUNP - EN HEREIN, ANC DOES

f j 

### E R M 

### A I E P F 

### A L 

### P R 

### 1 4 A 4 ~ 

### 0 T Y C 

# 4 2V—Q

### to 

## ial Wety Data Stieet I 

## U.S. 

## Department of 

## Labor used to comply w4h 1 Occupational SifetV atid itelitli Acfinirfl , .waliorl i-lazard Corrimunicatiori St•rdard, J 

### I (Non-Maiidatory Form) FR 

### 1910.1200. Standard must 

### be F-orryi Approvad for tpecifio requirements. OMS No. 

### 1218-D072 ..N •'! Y (As Osee ort L;)bol of rd Lisi.) Mate: 814mk, , 5p&o0s at* not p.
- rmitled. 11,nny 44m) is t1of appl"dob"'.Z ' 

### intcrmatlon Is avai1a&9, the spece must 15,9 nm-rkodto 

### /ndicalr 

### ftotT I Niafno ei'mergency Telephone Number 

## Jack & 

## Sons, Inc. foi 14einphil7. (20 6) 762 - 

## 7 2 2 (Number, stmef, city, vat#, Rrid ZIP 

### Corij 

# ~ r,lWelph;ne Number for Injouro6on 

## WA 

## 98131 762 7622

Date Prepared ; I



## aign, 1, 

### Preparop toptionei) 

## 11 tiazardous Ingredienisfidentity lnfornistion 

## 0(her Limits dous (>7in[Yjn0riI4 (Spm

.ific 

### Chef nicai lderitity! Cornmom Name(s)) 

### OSliA PEL 

### ACGIH TLV 

### Reconitrendod 

## limestone 

## Lq

_



## a Iciumlcarbonate) is not a hazardous substance 

## Solid waste Dsipogal Act. (CAS 

## Registry Num6er 131706503)



## se'.11on III — Physical/Chemical 

## Cligra(teristica

.......... ....... 

### Specific Gravity (H20 

### 1) 

## 700 0 

## calcines to lime ica)). V 

### . - ;'
- eS'sure (nvn Fig,) Malting Point 4 V 

### •snVily (AIR 1) 

### EvaparatiQn 

### Role (13u-yr Acetate 

### - 1)
:i. A!'PtIce and(7dor 

## grey powder or grit 

## -e- oclorless Secdan IV — Fire and Exploslon 

### Haurd Data

(Malhod Used) ~ abla 

### Llinits Mpdia NO



## FIRJ OR EXPLOSION HAZARD 

### S : . Fig I-ifing Proefdures
•ve atid Exp;oslon FluarOs 

### NONE k.)- . 

## Rea c I lvity'D a ta 

# SW f ConditlOnS to 

### Avoid 

# I Steible 

## VERYJ SriBL Matetlafs to Avold) Strdng mineral acids

cr 

# ._ _TMay 67c7, 

# cdo (at tem to Avoid 

### ratures above 1500 0 F



### Sefif; ,, )n Vi Health Hazard Data K,Z,'rr- • 

### '
- "')T"Fn 

## 7 ,j' He;.A.1 :,:<zards 

### (Acutoo amd Clironic) 

## NONE

Z8 * 14J — P? — 

### JARC Monographs? - OSHA 

### Pegttlafad?



### exposure

GPA1 , 1 , f:.:Ty Aggravated by 

### Expesure
and First Aid 

### Procedures


## Socilo► 

## Vil

— 

## Precautlons for Safe 7 -- ~ 

### --i Go 

### Taken In COO 

### kiatedal Is AsItav 

### SWEEP IT UP



### Method 

## U e it an your lawn and garden.
to Be Takon In 

## None

Spc1

, 7~o~ 

## Vill

— 

## Control Measures Protection Type) 3

gimnlp filter mask for coinfort--i-f 

## -cltist excneds 10 

## mg. for com4ort only 

## iione needed MerhanlCal 

## 6'ra/)

- 7: ' " P 

### Eye Protection

r-I c -1 

### r-I La__ 1 

### oioclive CWhing or EquipmeAt 

### Practices 

## nothin9

. special Page 2 .6 US cl 0.0. 1 sa f I -

# M mutual materials co. 605-119THNORTHEAST POST OFFICE BOX 2009 BELLEVUE, WASHINGTON 98009 PHONE (206) 455-2869 

## March 3, 1998 Mr. Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, NC 27711 The following Information Collection Request form is submitted for the Mica Brick Plant Facility, operated by Mutual Materials Company, in Mica, Washington. The report contains the following items: A- Form 2, Information Collection Request (28 pages). B- Portions of the Air Operating Permit Application . C- Laboratory analysis of clays and brick products. D- Sample pallet tag labeling. E- MSDS for Mutual fired clay brick products. F- MSDS for raw materials used in manufacturing processes. If you have any questions or require additional information please call or write. RespectPully submitted,

George A. Beamer Mutual Materials Company (509)-924-2120



# ~ 

# & 7

### Enclosure 2 - NOT SUBJcCT TC i:1= RE7!'AEl':NTS OF I; SECTION 3507, PAPERSIORK REDUCTIOR ACT OF 1930. i I 

## INFORMATION REQUEST FOR BRICK AND STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS I. Instructions Please return the completed information request to: Bruce C. Jordan, Director Attn: Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of A-ir Quality Planning and Standards Research Triangle Park, North Carolina 27711 If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at (919) 541-5435. 

## This information request should be completed for each facility that manufactures brick and structural clay products, including facilities that are not major sources. Information is requested for all processes at your plant that emit hazardous air pollutants (HAP's), including those processes that are not associated with brick and structural clay products manufacturing. Sections II through VII request information specific to brick and structural clay products manufacturing, and Section VIII requests information on emissions of HAP's from other processes located at the facility. Processes that may emit HAP's include those processes that use or handle any materials that-contain a HAP compound, all processes with elevated temperatures, and all other processes in which HAP compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this information request. Attachment 2 provides background information on the requirements of the Clean Air Act and explains how the information requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations and acronyms used in this information request. Several tables are provided throughout the information request for your convenience in answering the questions. An example response is given (shaded first column or row) in each table. If additional space is needed to respond, please make copies of applicable pages. If necessary, please make copies of this information request for additional facilities. No additional emission testing or monitoring is required to respond to this request. U. General Facility Information A. Name of company A 

# MUUL MAfE9it4-S CoM8111Vy Name of facility 

## 9lC ~ 

## Eg/CK P
- IMT t ~ 

## / (

-/7Y

Page l of 28 

# /~~J

## Facility address: No. and street 

## _/D(o ?-7 JCUTN '51rt=CE 41 Gfl Vt/d

- ~ 2 

## ..7 City State 

## WA Zip 

# 90O2-3 Latitude and longitude coordinates of plant: 

## 1..f4T• 1 4 7 0 3 3' Al LoNG : 

## (17 ° 12" Standard Industrial Classification (SIC) Code(s) of brick and structural clay products manufacturing operations 

## .32.5/ , 3/S/ Dun and Bradstreet No. 

## 009 Z'{y 3 7T Total No. of employees for company 5

- 6w

- 500 for facility (If facility is a foreign subsidiary or if company has foreign subsidiaries, include number of employees not based in the U.S.). Please complete the following shift information for the facility: Shift No. of employees Hours per shift Days per year 1 ~S a 2b0 3~ 

### 5 2 

## 3 i 8 B. Respondent name 

## 6Eop'Ge BEtq

~ 

## MEK Respondent title 

## A
-

55r " R

- 4 17 b

~ 

## 3

-

D/IZK. ~1~ 

## >, Respondent address (if different from above) and telephone number: No. and street 

# 'R O•

-Box
- 1 < 47oS City 

## 5PCMAE State WA Zip 

## 9944 Telephone No. 

## ( &9) — 9 2q - 212.Q Name and telephone number of technical contact person (if different from above) Name 

## ME Telephone No. (_) 

## S/}ME III. 

## Information on Operating Permits and Applicable Federal Emission Standards A. Please provide copies of relevant parts of all operating permits and permit applications for your facility. Relevant parts include the sections that providespecific information and data on: processes that emit HAP's; the use of HAPcontaining substances; emission levels for HAP and surrogate pollutants (i.e., VOC Page 2 of 28 

# /° ( 1 ~ I

## 5Ola V—E %



# -5TD , ie for organic HAP's and PM for metal and other particulate HAP's); emission control device design and operation; monitoring and operation and maintenance (O&M) procedures for control devices; and generation and releases of other media such as wastewater and solid waste that are associated with the operation of air pollution controls for brick and structural clay products manufacturing processes. ' If the operating permit or application contains the same information requested in any part of this questionnaire, you may respond to the requested information by referencing the page or section of the permit/application to avoid duplication. If you reference your permit or application, you must supplement your response with all of the additional information requested in this questionnaire that is not included in the permit or permit application. If you prefer, you may submit the requested information from your permit/application on a 3-

~ 

## /x inch diskette. B. If any source or emission unit at this facility is subject to a New Source Performance Standard or other Federal emission standard, please identify the source and applicable standard. Examples of applicable NSPS include 40 CFR 60, Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in Mineral Industries.

W. Brick and Structural Clay Products Production and Raw Material Consumption Information A. Please provide the 1996 production rates and the current production capacity for each type of brick and structural clay product manufactured (e.g., structural brick, clay sewer pipes, structural clay tile, etc.). Note that production data should be provided in units of tons per year (tons/yr).
Product 1996 production (tons) Production capacity (tons/yr) 

# uurum ecM 53 1 330 79 ~ 

## g l c K MO 

# CJ& (D D ~


## Page 3 of 28 ~1~ 

## 7d

## B. Please provide the type and amount of each raw material and body additive used in 1996 for manufacturing brick and structural clay products at your facility. Examples include clays, shale, and any additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade name. If the inforination requested is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. Raw materiaUbody additive . Amount used in 1996 (tons/yr)

Of 

# 2. 5M D

~ 

# gocq Szz.g

E5C 6 D DE

7 -:7) j O 

# P,o M H
- f~ 

# E Pu


# e, • COW, RLYOW.mn ~ 

# N 2 ~ 

# I.Lod
~ 

# (Do tbs ZRrw tu pm VAA1AVttt44 CO to .) 

# loo lbS

C. If available, please provide a copy of the MSDS's for the raw materials and additives listed above. D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above.

Page 4 of 28 

# 171

## E. Using Table 1, please provide information on the consumption and HAP composition of all glazes and colorants that contain HAP's or HAP precursors and that your facility applies to brick and structural clay products. Indicate whether the coatings are glazes or colorants. Also indicate the type of product that the coatings are applied to and the total weight of coatings used in 1996. If the glazes or colorants are formulated at your facility indicate so and provide the production capacity. List each ingredient of the glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient used in 1996. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. F. In the space below, please indicate any glazes or colorants used by your facility that do not contain HAP's and are substitutes for HAP-containing glazes or colorants used by your industry. Indicate which HAP-containing materials the non-HAP glazes or colorants replace. Describe any limitations on the use of those substitute glazes or colorants. 

## i4

G. If your facility colors brick and structural clay products by flashing, please indicate the types of substances used to flash the products and the amounts of those substances used in 1996. Substance 

## JV*TGIRA{. .riAS Amount used in 1996 1/1Y15Now &oT 

### Mw-WSURr.

'a ) 

## Units (specify)



# &A

H. If available, please provide a copy of the MSDS's for the glazes and colorants used by your facility. If your facility prepares its own glaze, please provide any available MSDS's for the glaze ingredients.

Page 5 of 28 

# pz~

### TABLE 1. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND COLORANTS

If additional space is required, please make copies of this page. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. Page 6 of 28 

# 173

### TABLE l. CONSUMPTION AND HAP COMPOSITION OF GLA7FS ANn rnr .nu n u'rc

If additional space is required, please make copies of this page. If the information requested in the table is contained in your facility's operating per7nit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. Page 6 of 28 

# /7` 

# ~ -

### TABLE l. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND COLORANTS

If additional space is required, please make copies of this page. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table.

Paee 6 of 28 

# l 75 ---

## V. Description of Brick and Structural Clay Product Manufacturing Processes



## A. Please provide a simple process flow diagram for each brick and structural clay product manufacturing process line. An example process flow diagram is provided in Figure 1. A diagram of the plant layout with all processes and emission points clearly labeled is also acceptable.dF RE6ER EN CC C. 

## P a 5 p— ZXS (/d 47TAeff£

-



### t> l4! f ~ 

### 0 PE744'llillC) P&V

- 

### MIT 117

9 PU0477&

~ 

### ! # 

## Assign a unique identification number (ID No.) for each process that has associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. Please identify all emission points, including those that do not emit HAP's. For emission points that are vented to an air pollution control device (APCD), assign an ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information request for any responses that pertain to any process or emission point.



## ce Pa. ~ 

## e S SQ ~ 

## onl 

## G. I. QM r ss/ovi Fb1N1'5 , C onl

— IX4c ~ 

# hrtr ~ ~lu~s 

## tN ~R7~u~ ~4
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# 2 vP

~ 

## 72,q- ~n~~ v~~~ 

## 2vyrl 7 

# AWu C1 4 1?&'V ~



# ~

Page 7 of 28
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# o) c ~ ~ Y c ~ co O cu ~ W U)



### Page 8 of 28 . 

# /77

### B. Using Tables 2A and 2B, please provide current production rates, production capacities, and related information for each type of equipment used in brick and structural clay product manufacturing. In Table 2A, provide the requested information for only those sources that are known or expected to emit HAP's. In Table 2B, provide the requested information for all thermal processing, such as drying and firing sources. For combustion sources that use different fuels, Table 2B should be completed for each type of fuel. For example, if a kiln typically is fired with gas, but periodically is fired with oil, one column in Table 2B should be completed for the kiln when fired with gas, and another column should be completed for the same kiln when fired with oil. Provide the data in the units listed for each row. 

# ( x ~ L 

# ) ~

Page 9 of 28 

# / 7'~ 0 T C

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### Page 10 of 28 

# 17,5
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## C. Using Table 3, please provide information on procedures used to monitor the process operating rate for each of the pieces of equipment and HAP emission sources listed in Tables 2A and 2B. Use the same HAP emission source types and equipment ID numbers you listed in Tables 2A to 2B. Indicate whether you monitor process rate or not. Provide a summary of process rate monitoring procedures that describes how process rate is measured for the particular piece of equipment. Include where the rate is monitored (i.e., rate of material fed, rate of material discharged, or material production rate), the units used to measure process rate (e.g, lb/hr or pieces/hr), and how the process data is recorded, i.e., manually, automatically (e.g., computer - printout or stored to disk, or not at all). ff you monitor process rate at both the feed and discharge ends of the equipment, indicate so. Indicate the type of monitor, equipment, or instrument used to measure process operating rate. Indicate the monitoring frequency or how often process rate measurements are made. If instruments are used to measure process throughput, indicate in the monitor accuracy column the accuracy of the instrument. The monitor accuracy could be listed in terms of a percentage of the throughput (t 1 percent), mass per unit time (±2 lb/hr), number of pieces per unit time (± 10 pieces/hr), or other appropriate units. Indicate the frequency that the monitor is calibrated. Provide data in the units listed for each row.

Page 12 of 28 

# l~~

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## VI. Identification of Brick and Structural Clay Product Manufacturing Emission Points



## A. Use the process flow diagrams developed for your facility and Table 4 to provide the following information for each HAP emission source at your facility. • Define HAP emission source type in terms of equipment, such as dryers, kilns, etc. As in the process flow diagram, you may group multiple pieces of similar equipment. • Use the same equipment ID numbers indicated on the process flow diagram(s). • If the emission source vents inside a building or to outside ambient air without first passing through a control device, place a check mark in the uncontrolled column. • If the emission source vents inside a building or to outside ambient air after passing through a fabric filter, dry injection fabric filter, or scrubber, place the APCD ID number(s) in the column corresponding to the APCD type. • If the emission source vents through a control device type not listed in Table 4, indicate the control device type in the other control column and place the APCD ID number in the appropriate cell. • In the emission test data column, place a"yes" or "no" in the appropriate cell to indicate whether the specific source has been tested for Agy pollutants, including any HAP's, VOC, PM, or opacity.

Page 14 of 28 

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## B. Using Table 5, please provide information on stack parameters and emission estimates for each emission point at your facility that is known or expected to emit HAP's. Provide information for all APCD's, including those that exhaust inside the building. Include data for each inlet and outlet, if available, as indicated in the table. If you have more than one inlet to an APCD, provide data for each of the inlets. Provide data in the units listed for each row. Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal HAP's or VOC for organic HAP's. Emission estimates may consist of measurements reported in enussion test reports or may be calculated using mass balances, emission factors, engineering judgement, or other estimation methods. Provide the emission estimates as emission factors in units of lb of pollutant emitted per ton of product (lb/ton). Provide complete copies of any emission test reports or other reports that document measurements of emissions. Test reports and other emission measurement documents should include the following information: process identification; location of sampling point; stack diameter, temperature, and flow rate; test method, including analytical procedures; number of test runs; enussion concentration, emission rate, percent oxygen, and percent moisture for each test run; process operating rate; type of APCD; and APCD operating parameters. However, test reports with incomplete documentation may still be useful and should also be submitted. You do not need to fill out Table 5 for emission points that are covered by an emission test report that is included in your submittal. If emission test reports are not available, provide calculations that support your emission estimate, including the basis for all assumptions in the estimate. Note that emission estimates are needed for all HAP's that the facility emits or has the potential to emit. (Please refer to the HAP list in Attachment 1.) If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 16 of 28 

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## C. Using Tables 6A through 6D, please provide design and operating data for each APCD associated with all dryers, kilns, and any other brick and structural clay products manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of APCD's. Use Table 6D for other types of APCD's. When using Table 6D, please specify the type of control device and 2 to 4 key design or operating parameters for the device. Provide data in the units listed for each row. If the information requested in Tables 6A through 6D is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the tables. 

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## D. Using Table 7, please provide the following information on current monitoring procedures for each of the control devices listed in Tables 6A to 6D: parameters monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices used (e.g., differential pressure transducer, thermocouple), and recordkeeping practices (e.g., manually recorded in log book, continuously recorded by electronic data acquisition system). Describe briefly other operation and maintenance (O&M) procedures for each control device. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table. VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing A. Please describe all pollution prevention practices (i.e., process modifications, such as re-use of discarded or rejected materials, or any practice that prevents or reduces the amount of air emissions, or the generation and release of solid waste or wastewater associated with the operation of air pollution controls). If the information requested here is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below.

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### VIII. Information on Processes Other Than Brick and Structural Clav Products Manufacturing



## Processes A. Using Table 8, please identify all other processes or operations at this facility that are not addressed in Items II through VII above and that are potential sources of HAP emissions. Estimate total annual emissions of each HAP emitted by these colocated processes. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rath.er than filling out the table.

Page 27 of 28 

# l ~~

### TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCFS



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Page 28 of 28



# ~ ~~

# M mutual materials co. 605-119TH NORTHEAST POST OFFICE BOX 2009 BELLEVUE, WASHINGTON 98009 PHONE (206) 455-2869 

# February 27, 1998 This attachment consists of those portions of the Air Operating Permit Application for the Mica Brick Plant Facility of Mutual Materials Company, as submitted to the Spokane County Air Pollution Control Authority, which are deemed relevant and pertinent to this ICR submission.



# ~ -. .- Beame 

# r Mutual Materials Company



# ~~~Mirtual Materiats Cotnpauy Mica Plant - Air Operatmg Permit Applicuim


## Spokane County Air Pollution Control Agency 

# Air Operating Permit Application

Mutual Materials Comparry 

# 1Vlica Brick Plant Facility

Originally Submitted June 7, 1995
Revised & Resubmitted 

# September 29, 1995

.40P.1 pplrcation

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~ +vuouucw_vr.trDOC
~~ wtuvf
~ ait.un i- ~( ~Munial Metaials Company Ivtica Plant - Air Operatmg Permit Applicaticn 

## B.1.c, Raw Materials and Fuels Used The raw materials used are ciay and water. Some brick will use a mix that requires a small amount of manganese or chromium to be added to the clay mix to darken the color of the brick. A die lubricant is also used at the extruder to maintain a flow of clay through the die. This material dissipates before the drying process begins. B.l.d Facility OperatingSchedule MBP grinding schedule is generally 2 eight hour shiffts, fve days per week. MBP extruding or pressing schedule is typically 2 eight hour shifts frve days per week. The fuing schedule for the tunnel kiln is 24 hours per day 7 days per week and 52 weeks per year. The kiln has a capacity to through put 36 cars per 24 hour day. The kiln holds 42 kiln cars. There are approximately 3,100 standard brick equivalents per kiln car. The kiln is shut down for repairs on very rare occasions. The rate or speed in which cars are introduced to the kiln can be adjusted to meet fluctuating market demand. The two periodic kilns altemate usage about once every two weeks (about 2-1/2 kiln bums per month). B.2. Products, Raw Materials, Fuels, Processes Forms B-1, B-2, B-3, & B-4 are completed and attached. The main fuel in the manufacturing process is natural gas. The main materials used are various clays used in manufacturing brick. C. P/ant Operationa/ Characteristics 

## C.1. Significant Emissiou Points, Controls & Stacks Form C-1 is completed and attached. Emission Unit EU4.4 - Batch Dryers, one eachaust stack and no emission controls. Emission Unit EU5.1 - Swindell-Dressler tunnel kiln, one exhaust stack and no emission controls. Emission Unit EU5.2 - Periodic kilns, two kilns with one exhaust stack and no emission controls. Emission Unit EU7.1 - Empty kiln car vacuum to Torit baghouse C.2. Facilitv Process Flow Diagram Flow chart in Appendix C describes to manufacturing flow. The flow chart in Appendix D details the emission sources, discharge points and emissions.

.AOP Application page .i

D-ORPD.QAIENMPAKA R.ffDOCIOWtLY 101' MI 

# o~% ~Mutual Mataials C.ycopaay ' tvlica Plant - Air Operatmg Peimit Appli=cn C.3. Site Map 

## The site map is in Appendix E. C.4. Potential Emissions Summary Forws C-2 and C-3 are completed & attached. Appendix A& B include calculation methods, assumptions and data used in determining potential emissions. Potential emissions include: 1. Hydrogen fluoride from clay burning process. 2. Carbon monoxide from natural gas burning process. 3. Nitrogen oxides from natural gas burning process. 4. Sulfur oxides from clay buining process. 5. Potential VOC's from clay burning process 6. PM10 from clay burning process, grinding process & car cleaning. 7. Particulate from grinding process. 8. VOC's from storage tanks. 9. Particulate from maintenance and repairs. The greatest emission potential are the following: Hydrogen fluoride (HF) generated from the natural fluorides contained in clay. Fugitive dust from the grind'mg and material transfer processes as well as mining, hauling and yarding activities. The potential to emit is over 1;000 tons of dust annually.



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~ i Mucual Mntaials ccmTaay Mica Planc - Air Operatmg Pamit Applicacion 

## Chapter 2 - Regufatory Requirements A. Description of Significant Emission Points 

### A.1. Eguipment Description 

## Emission Unit EU4.4 - Batch dryers Emission Point: Dryer stacks. Rate of discharge: Rate of discharge is the AP-42 factor for NOx of. . 5 lbs. per ton of brick manufactured. No recent stack test has been done on this dryer. Controls: There are no control devices on this dryer for air emissions. Emission Unit EU5.1 - Swindell-Dressler tunnel kiln Emission Point: Dressler kiln stack. Located in manufacturing/firing/packaging building complex. Rate of discharge: Rate of discharge is the AP-42 factor of 1 lb. HF per ton of brrick

manufactured. No recent stack test has been done on this kiln. Controls: There are no control devices on this kiln for reducing air emissions. Emission Unit EU5.2 - Periodic kilns Emission Point: Shared exhaust stack. Rate of discharge: Rate of discharge is the AP-42 factor of 1 lb. of HF per ton of brick

manufactured. No recent stack test has been done on these kilns. Controls: There are no control devices on this exhaust stack for air emissions. Note: Periodic kilns #1, 4-7, 9& 10 are not functionaL There are no plans to use

them in the future. They are past the term of their usefizl life. Restoring them would exceed the cost of building modern, "state of the art" kilns. They are presently used for storage of materials. Emission Unit EU7.1 - Empty kiln car vacuum to Torit baghouse Emission Point: Roof vent from baghouse. Rate of discharge: 3,600 to 5,600 cfin Controls: Baghouse

.4 0P A ppl ication page 7

fY'rORPDwiALL?N0.PA9[A iMf.DOC104iYY 101: wnl) 15z lll l _3

# ~ Mutual Mataials CouVany Mica Plant - Air Opaatmg Pamit Applicatim

~ 

# ~ Form A-1: General Information & Certification Air Operating Permit Application


# ~ 

# ~ l. Company Name : ................................................ Mutual Materials Company

2. Facility Name :.................................................... Mica Brick Plant



# ~ 3. UBI#:. .......178-001-617

........................................................ 

## 4. Facility Address : ................................................ Street: 10627 South State Route 27 City/State/Zip: Mica, WA 99023


# ~ County: Spokane

5. Mailing Address :................................................ P.O. Box 14705, Opportmuty, WA 99214 

# ~ 6. Owner :
.............................................................. Mutual Materials Company

7. Owner Address :................................................. P.O. Box 2009, Bellevue, WA, 98009


# ~ 8. Facility Person Famihar with Information:.......... George Beamer, Assist. R&D Lab Dir., (509) 924-2120 Bob Cole, Manager, 924-2120

Plant (509)
. 

## 9. Type of Operating Permit : ................................. Initial Permit Application 

# ~ 10. Reason for Application : ..................................... Exceed 10 tons of HF per year

11. Claim of Confidentiality : .................................... None 

# ~ 12. Document Prepared : .......................................... Brad Cahoon, Safety & Compliance Manager, Mutual Materials Company, (206) 455-2869 

# ~ Loren Dunn, Attorney at Law (206) 624-3600



# ~ Certification

This document and all attachments were prepared under my direct supervision. I certify that all information submitted is accurate to the best of my knowledge. 

# ~ Printed Na e: James E. deregg

Signed: 

# ~ Date: 

# ~ Title: e-President of Opera '

# ■ 

# a 7- 

# 1
.-1 OP . a ppl ication

~ nrou>nn ~w~L
- uowcw vnrtoociowiv9. ioi ~ .r.n page 13



### ~ /

# ~ Mutual Vtataials Ccxnpan , . Mica Plant - Air Opaatmg Permit Applicauon

I



# ~ Appendix A
Emission Calculations



# ~ -

~

~

~ '

~ .-I UP.dpplicatioyr paKe 33

' ,1 W ~ qp,UMF].YQOMKw T(fDOCiOYlUY 101'. ~Ml ~, ~

~ ,Mutual Materials - Mica Plant Potential Alr Emissions Calculatlons

Swindell-Dressler Kiln EU5.1 Potential Air Emissions AP-42 Factor Potential (Ibsiton) Capacity UOM Calculation Annual Emissions UOM HF 1.000 71400 tons 1.000 x 71400 35.7 tons NOx 0.180 71400 tons 0.18 x 71400 6.426 tons SOx Neg Neg Neg Neg Neg Neg VOC (nonmethane) 0.003 71400 tons 0.003 x 71400 0.1071 tons VOC (methane) 0.006 71400 tons 0.006 x 71400 0.2142 tons Particulate 0.023 71400 tons 0.023 x 71400 0.8211 tons PM10 0.01 71400 tons 0.01 x 71400 0.367 tons CO 0.060 71400 tons 0.06 x 71400 2.142 tons
Periodic Kiln EU5.2 Potential Air Emissions AP-42 Factor Potential (Ibshon) Capacity UOM Calculation Annual Emissions UOM HF 1.000 2550 tons 1.000 x 2550 1.275 tons NOx 0.500 2550 tons 0.500 x 2550 0.6375 tons SOx Neg Neg Neg Neg Neg Neg VOC (nonmethane) 0.010 2550 tons 0.01 x 2550 0.01275 tons VOC (methane) 0.020 2560 tons 0.02 x 2560 0.0255 tons Particulate 0.085 2560 tons 0.065 x 2550 0.082875 tons PM10 0.034 2550 tons 0.034 x 2550 0.04335 tons CO 0.060 2550 tons 0.060 x 2550 0.0765 tons Brick Dryer (for Periodic IGlns) EU4.5 Potential Air Emissions AP-42 Factor Poterrtial (Ibsrton) Capacity UOM Calculation Annual Emissions UOM HF ND ND NOx 0.660 2550 tons 0.66 x 2550 0.8415 tons SOx Neg Neg Neg Neg Neg Neg VOC (nonmethane) ND ND VOC (methane) ND ND Particulate ND ND PM10 ND ND CO ND ND Grinding F3.1 - F4.1 B Potential Air Emissions AP-42 Factor Potential (IbsRon) Capacity UOM Calculation Annual Emissions UOM Particulates 20 87360 tons 20 x 87360 874 tons HF ND ND NOx ND ND SOx ND ND VOC (nonmethane) ND ND VOC (methane) ND ND PM10 1.4 87360 tons 1.4 x 87360 61 tons CO ND ND
ND = no data Neg = negligible

MI CALC2 XLSMutual Matazals C'onTm% Mica Plant - Air Opaatmg Permit Applicati n



## Appendix B Capacity Calculations 

# f 

# I I I I I I 

# I ol 0 t 0
~ .-IOPApplication

n Woaanwwe+vaawcw vr.trmc

~ ~ wiuo+ ~o~ .wi page 34

~ O ~Mutual Materials - Mica Plant Potential Capacity Calculations

Capacity Calculations
Swindell-Dressler Kiln 

### FUEL Daily fuel consumption 6,200 therms/day Annual operating days 365 days/yr Annual fuel consumption 2,263,000 therms 365 day/yr x 6,200 therms/day


### PRODUCT Cars per day (cpd). Kiln cars through Idln. 36 cpd Brick equivalents (BE) per ldln car 3,100 BE Annual operating days 366 days Annual maximum capacity 40,734,000 BE 36 cpd x 3,100 BE/ldln car x 365 days/yr Annual maximum capacity (tons) 84,000 tons 40,734,000 BEtyear x 4.1 poundsBE / 2,000 poundsiton
Periodic Kilns 

### FUEL Batch fuel consumption 7,500 therms/batch Batches per month 2.5 batches/month Annual fuel consumption 225,000 therms 7,500 therms/batch x 2.5 batches/month x 12 monthstyr


### PRODUCT Tons per batch 100 tons Batches per month 2.5 batches/month Annual operating days 12 days Annual maximum capacity 3,000 tons 100 tons/batch x 2.5 batches/month x 12 months/yr Annual maximum capacity (BE) 1,500,000 BE 3,000 tonstyear x 2,000 poundshon / 4.1 poundsB. E. Periodic fGln Dryers 

### FUEL Batch fuel consumption 800 therms/batch Batches per month 2.5 batches/month Annual fuel consumption 18,000 therms 800 therms/batch x 2.5 batches/month x 12 months/yr Grinding Process RAW MATERIALS (Clay 8 Grog) Tons per hours ground 21 tons/hr Hours per shift 8 hours/shift Shift per day 2 shifts/day Days per week 5 dayMreek Weeks per year 52 weeks/yr Annual material processed 87,360 tons 21 tons/hr x 8hr/shift x 2 shifts/day x 5 dayhMc x 52 week/yr Extruding Process RAW MATERIALS (Clay Mix) Tons per hours extruded 21 tons/hr Hours per shift 8 hours/shift Shift per day 2 shifts/day Days per week 5 dayJweek Weeks per year 52 weeks/yr Annual material processed 87,360 tons BE = brick equivalent (approx. 4.1 Ibs. fired weight)

Nfl CALCt XLS 

# ~

~

~ 

# i 

# i

~

~ 

# i 

# i i 

# i i i i 

# i 

# i 1 1 

# 1 21 tons/hr x 8hr/shift x 2 shifts/day x 5 dayAM< x 52 week/yr ri

# ~ 

# I

~

~

~ 

# I !

~

~

~

~ 

# 1

~ 1 ! I I 

# I
~ IOPApplicacion

n~~ 'OAADwTwEt-YIROAUCwf'M[ ~ OfiOY:v> ~i~~: y~ 

### Appendix C
Process Flow Chart Mutual Materials Company Ivfica Plant - P.ir Opaatmg Permit Applicaticn



### page 35 vm 

# I Load onto I qln Can



# I StoraQe I Blm



# ~ 

# 7 )

Holdhp Room Pup r.Al Fire Brick Mfg. Dry Press

Dry Press Holdhp BM


# ~ corneyor BeRs


# ~ Feed Belb

Color PddlP.es

Page 1 To Atrnosphere

Dry— (s) (3 Vents)

Hahtal ' "n (1) Gas

ro page 2

Manufactured Product

lo-
~ Other Materials - - - - - - - - - =y ReCycled Materials► Natural Gas

f- Fugitive Dust



### ~~ 

# 16 Mutual Matenals Company - Mica Plant Flow Diagram - Clay Brick Manufacturing

Dust


# ~ 1 Note: Fugit ~ emissions e)ast thoughout the facility.

Cnuhed i Re l Jecb I

~ 

### 0
Clay onI Clay Prep S ~ ClayStorape ~ 9

~

~
Feed
~ 32nd I I Hoppers L ~ 

### p

~ ,-- ~ —

Owsize Dry Pan

~ ._._.._.. Gdnder

Q

Vlbratlrp

._.._ O ~ eralze --- Stteen 

# i wasUe Compressbn Vacwm Materlal EXbuder Chamber

Off Load Bell RebmFq M Cars

Wte Load to CutUq "n Cars

Fkal PreparaEon Wasb e..prA Heai

106t F~ e,aust

v To Atrnosphere

## ~ Mutua! Materrals Company - Mica Plant Flow Diagram - Clay Brick Manufacturing



## ~ From page 1 i 

## r~ --------- 7 

## ~

~ J Product hom 

## ~ Selecton Shlpping I tMa f rehouse 

## ~ 

# T-- qln J 

## ~ r I~ Storage Prep 6 Shlpping



## ~ To Car I Relects Cleartlng , i I I

IOtn Cars Torll ~

Baghouse ~ i Rehmkig PorhWe Crusher i To Clay i

-~ Storage Mea j I ~ I I To Atmosphere Oust Note: Fugdi4e emissions emst thoughout the facility.

ri

Flue Liner Mfg.

From Compressbn Eutnuder

Item tom To Atmosphere Warehouse Fxwder

. . a SI+4pt+g



## ~ . ...._
Batch Dry Perbdk Cool Dowtt IIIIIIIII SNectlon 

## ~ Room Iarn (2)



### ~ M
Nattral To Cnnher ReJecU Gas /

Manufactured Product .30 Other Materials

- - - - - - - - - - - - - ~ Recycled Materials► Natural Gas

,. Fugitive Dust
Page 2Mtmial Matenals CarTany Mica Plaat - Air Operating Permit Applicaticm



### Appendix D Process Flow Chart by Emission Source

, I Op .-1 pplication 

### page 36

• Wo

~ nowrw,c,.vao..ac• rwrnoc ~ow~ue~ ioi

~~ n /2( 

# 2—Mica Plant - Brick Production Process F1ow Diaaram 2 - Clay Ac u isition 

### ' 2.1 2.2 j Mining Hauling ! Mhe day uskig scrapper I tk imp truek and traAer and/or excawtor ~ haul clay to plant slle. equlpment I ~ Process #1: Brick Manufacturing
3 - Clay Prep 

### 2.3 3.1 ! 3.2 ; Stockpiling Batching 

# ~ Crushing Clay Is stocked at plant Lmc clays and grog (Iked i I Break grog Into i stte tnder roof or open recycled brlck used as a, ! smaper pleces. i

alr. Iller) by tont end loader equlpment to obtaln clay 

### ~ body md. I i

I i I I I ®

3- Clay Prep 4- Manufacturing 

### 3.3 4.2

3.4 3.5 I 4.1 Grinding Screening Storing Pugging Extruding Transter rnohed clay by Transfer semEllne grorrtd Clay tranaferted 6om PAd water to clay and mtx I Under wcwm exlrude conveyor to dry pan roller. I day by corneyor to sceening to storage bkn In pug mil. Dry hAg may stln day/water nbmre Clay puhanzed tnder Nbratp screen. Slze b by corneyor. be added aa a colorant through dle. Cut bnck b

roAera. small mesh. Reryde the for certatn brtck. proper helght tNh wtes. larger mesh slze back b

~ 1 Some brkk are gt
~ en a

grhding. I slury coat of ceramk

~ ~ materlal at extudhg for I color on Fe nrface.

4 - Manufacttring 5 - Firin 

### 4.3 4.4 5 Setting Drying I Firing Nbt brkk are marxnity Set brkk are drled uahg Dry brkk are fked at a set trom corneyor b excess heat from kln. max. temp. of approx. kIn ara 2.000 degrees F. 6- Brick Handling 

### 6.1 6.2 Sorting Packaging Fted brlek are marktally Sorted brlck are marwally bansferred tom kAn car tnnsferred tom conveyor to corneyor and quallty to pallets. Inspected.

6 - Brick Handll 

### 6.3 Yarding Packaged brlck are trartsferred tom packalging to yard storage (outskle or Inslde) by IM tuck. I 

### 6.4

Delivery Yarded brlcktnnsferred by INt truck to del" trucla and delhrtred to Jobsttes. 7 -Miscellaneous
• Malntenance 8 Repairs i • Sample Board Making ~ i • Vacuum System •AG Fueling tanks i (propane 3 diesel) • Space heaters • Alr conditloners • Painting • Clean-up • OtherMica Plant - Brick Production Process Flow Diagram



### Process 2 (Clay Acquisition)

Sub-Processes 2.1- Mining --> 2.2- Hauling -T 2.3- Stockpiling--> m

Fuel/Raw I Dieael fuel Materials Input l

Emission i Mhtrre Point . equlpmenl 

## L 1

~ Clay Dieael tuel


# r j F-2.1 Haulh g ~

i M eqpm i
~ he ground ~ ~ ent

I
- i I Ctay



### ! F-2.2 I 

# I Haul I road



### 2 Discharge Point ne:

Em issions FuglNa output dust

") f Ll

# 1

1 Mica Plant

- Brick Production Process Flow Diagram 

## Process 

## 3 (Clay Prep)
3.1-Batching

— 3.2 - Crushing 3 j . 3.3- Grinding — 3- .1



### Fuel/Raw fu7

.1 g k 

### r 

### ~ b,, 1 Clay 

### mix I 

### Materials CI-Y 

### c Input ------



### F-3.1 A F-3.1 B Emission Dles ell oader Tlre contact to Loader 

### Point clay on bucl(et ground



### Discharge 

### 3 Point Open doors or roof oper*vs



### Emissions F 

# ~ L d ig:N,. OLitput dust

.......... . ...... . ...... .. .. .......... ... .... .. . ... .. . ... .. ....... I

.. .. ....... -.- ......... .......... —



### 3.4-Screening 3 

### , 3.5- Storing

Fuel/Raw Cla 

# y mix 

# I rlay 

### mix Materfais lnpiA

Emission F-3.4A F-3.4B 

### F-3.5 Point %Abfa*V Cormyor Conveyor transfer transfer scream poinb potft



### Discharge 

### 3 Point Open doors or roof opertings



### Emissions FugMw Output dust Clay mix



### F-3.3A F-3.36 Con,myor Dry pan r'Dilef trarmter points



### fDry Additiw' t Mi t Cl i

~ l

_

F-4.1 B Dry fhop Feeder 

# i 

# i i i i i i i i i i 

# i i i 

# i i 1 i i n

Mica Piant - Brick Production Process Flow Diagram 

### Process 4 (Manufacturing)

)0. 4.1- Pugging 4.2- Extruding 4.3- Setting

——~ --~ -- ~ ,

Fuel/Raw( 1

I ( Materials I Water I I Clay Mix Input

` `T

Em ission Point F-4.1 A ConAyor Transfer PoM

Discharge Point Op doora or roof openlnps

Enl issions tZ) Output ,

....... .................... ... . _.......... .. __...................._..................... _....... .................. ... ........_ ... ..... .. ............. . .......... ............... _ ......... _ ............ ........._...._.............. . . . _. ...

~ 4.4 

### - Drvina _ BATCH DRYER

FuellRaw ClayMwter Excess Idln Materials mix heat Input

EU-4.4 Generation Tunnel Point dryer

~ 4 Discharge Point Roof %ente

E7nissions % Water Output 1 , \ Vapor


# .2lh _ 31 ,. 4.5- Drying ~ ClaylWater Natural Mix I gas

E U-4.5 I satch dryer for perlodk kt, 

# i~ i Dryer 7i]ck ,

✓ I

y , AOer ~ ROX 1 Vapor f

# 1 i i

~ 

# i i i 

# i i i 

# i 1 i 1 

# i i 

# i i i Mica Plant - Brick Production Process Flow Diagram



### Process 5 (Firing)

—)m- 5.1- Firing —

~►

Fuel/Raw 

## ~ Natural



# i I Clay mix M aterlals gas ` Input
EU-5.1 Em ission Tunnel POiflt

, Klln

Discharge 6 wn Poi nt E,Q„ust Stack

Efnissions ,qk HF. CO , NOx, PM70 Output EmLssloro 

### PERIODIC KILN

5.2- Periodic —)1. Kiln >

Firing


# ~ Natural 

# ~ I i gaa Clay mix 1 '
I i EU-5.2 Perbdk kHn IC

7 wln Exhauet Stack

/yr \ HF. CO , NOx, PM10 Embslnna ~



## r;z ~ 

## ?Mlca Plant
- Brick Production Process Flow Diagram



### Process 

## 6 (Handling)

6.1 Sorting 

### > 6.2 Packaging 

### > 6.3 Yarding 

### [E

Fuel/Raw Finished Materials j brick [nptA

Emission Handling Point

Discharge Point

Emissions Output

.. .......... .. .......... .... . ....... .. .... . .... I..,

........ .. ....... 3P. 6.4 Delivery

Fuel/Raw Mlaterials

- Pa

L 

### Il - d.. Input 

## y Emission UR ftcks Poird

Discharge Point

Emlssions Output Finished 

### I I brick Propane



### F-6.3 H2ndling 

### Dkly L Asphalt



### 8 Truck Tirei

Fugtlhoe dusl

.. .......... ... 

### —

......... ...... ... . ..... 

### Process 

## 7 (Miscellaneous)

7.1 Car Cleaning



### EU-7.1 Car deardng 'Acuum system

10 Baghouse %ent

Fug%e dLtM Asphalt dkt

F-6.4 

### ow y Asphall



### 9 Truck Tlres

Fug" dust



### ~ 

# 1,f-

## WESTERN ANALYTICAL, INC. 

# ~ 2417 CONSTITUTION BOULEVARD SA8T LAKE CITY, UTAH 84119-1225 

## PHONE (801) 973-9238 OR (800) 383-5924

FAX (801) 973-7635


## CERTIFICATE OF ANALYSIS 

# ~ June 14, 1994

P94-295 

# ~ ACCT: No. 1000

YOUR PURCHASE ORDER: 159027

, MUTUAL MATERIALS

MR. BRAD CAHOON 605 119th NE 

# ~ BELLEVUE WA 98009

Dear Mr. Cahoon: 

# ~ Transmitted herewith are the analytical data for the fourteen (14)

samples delivered to our laboratory for flouride (F-) analysis. ! DATE RECEIVED: June 3, 1994

DATE OF ANALYSIS: June 1. 1994 RECEIVED BY: Julie Lopez 

# ~ SAMPLE F- 

# 1 IDENTIFICATION ( % )

Worley Red Clay 0.092 

## Pottratz Koral Clay 0.104

, Pottratz Yellow Clay 0.104

Mica Yellow Fire Clay 0.040 Mica Cream Fire Clay 0.044 

# 1 Mica White Fire Clay 0.048

Mica White Plastic Clay 0.056 Mica Red Clay 0.100 ' M-628 0.076

A-111 0.052 

## M

- 

## 628 Green Sample 0.048 M-628 Fired Sample < 0.001 

# ~ A-111 Green Sample 0.052

A-ill Fired Sample < 0.001

. ` 

### . •• • ~ 

### - • 

## EHP/jl cc: Mr. George Beamer 116 1

# SAMPLE: PALLET WARN/NG LABEL
manufactured by M 

# mutual M 

# materi"als co.

Mutual Materials Company, P.O. Box 2009, 605-119th Avenue N.E., Bellevue, WA 98009 

# WARNING CAUTION: tMPORTANT SAFETY INFORMATION Dry-sawing or grinding of fired clay brick is not recommended and may result in the release of respirable crystalline silica dust particles that may cause respiratory ailments (such as silicosis) and even cancer if proper protective equipment is not in place. The use of a NIOSH approved respirator, tight fitting goggles, and protective gloves are reconunended when sawing or grinding these units. Adequate ventilation and enclosure should be provided to workers engaged in these operations. Specific MSDS information is available from the manufacturer and/or selling agent.

# MATERIAL SAFETY DATA SHEET
PRODucTiDerrriTY: FIRED CLAY BRICK

_ 

# SECTION I ,
Manufacturer's Name: Emergency Phone Number: 

### Mutual Materials Company (206) 455-2869 Telephone Number for Information: Address: 

### (206) 455-2869 P. 0. Box 2009 Bellevue, Washington 98009 Date Prepared: 

### November 1, 

### 1994 

# SECTION 11- Hazardous Ingredients/ldentity:lnformation Hazardous Components: Specific Chemical Identity: 

### Crystalline Quartz Silica Quartz (Silicon Dioxide), Si0 2 These "Hazardous Components" are not released under normal conditions of use, but may be released from the fired clay brick as airborne respirable free crystalline silica particles when dry-sawing, dry-grinding, or otherwise materially modifying the product. Common Names: 

### Dust from sawing or grinding, Sand, Silica. OSHA 

### PEL: 

### Exposure to airborne crystalline silica shall not exceed an 8-hour time-weighted average limit as stated in 29 CFR 1910.1000 Table Z-3 for Mineral Dusts, specifically: Silica, Crystalline Quartz (respirable): 0.1 mg/M' ACGIH TLV: 

### Crystalline Quartz TLV-TWA = 0.1 mg/M' (Respirable Dust) See Threshold Limit Value and Biological Exposure Indices for 1991-1992, American Conference of Governmental Industrial Hygienists. Other Limits Recommended: 

### NIOSH has recommended that the permissible exposure limit be changed to 0.05 mg/M' (as respirable free silica) averaged over a work shift of up to 10 hours per day, 40 hours per week. Consult the NIOSH Criteria Document for Crystalline Silica for more information. 

## SECTION 1[I - PhysicaUChemical;Characteristics Boiling Point: 

### 4046 ° F Specific Gravity: 

### 2.65 Vapor Pressure: 

### N/A Meltinct Point: 

### 3050°F Vapor Density: 

### N/A Evaporation Rate: 

### N/A Solubilitl/ in Water: 

### Not Soluble Appearance 8B Odor: 

### Granular or Powder, Odorless 

# SECTION IV

- 

### Fire 

# and Explosion Hazard 

# Data Flash Point: 

### Non-Combustible LEL: 

### None Flammable Limits: 

### None UEL: 

### None ExtincguishinQ Media' 

### N/A Unusual Fire and Special Fire Fiphting Procedures• 

### N/A Explosion Hazards: 

### None

IpR9t I O[ JI DATA/Bl1YErY/M9D8/K9UB-BRR.DOC n1/

## SECTION V - REACTIVITY DATA

Stabili 

### : Stable Conditions to Avoid: 

### None Incompatibility (Materials to Avoid): 

### Silica will dissolve in hydrofluoric acid and produce a corrosive gas, silicon tetrafluoride. Hazardous Decomposition or Byproducts: 

### None . Hazardous Polvmerization: will 

### not occur. Conditions to Avoid: 

### None 

## SECTION VI - 

## Health Hazard Data ;.: Route(s) of Entrv:

Inhalation?: 

### Yes Skin?: 

### No Ingestion?: 

### No Health Hazards (Acute and Chronic): 

### Dry-sawing or dry-grinding may result in the release of dust particles which may: Acute: 

### May cause minor irritation of the eye, nose, or skin. Chronic: 

### Excessive inhalation of dust particles for prolonged periods may result in lung disease (silicosis). Silicosis is a form of disabling pulmonary fibrosis which can be progressive and may lead to death. See "Carcinogenicity" section below. CarcinoqenicitV: 

### NTP?: Yes . In the Sixth Annual Report on Carcinogens by The National Toxicology Program (NTP), it was concluded that respirable crystalline silica may reasonably be anticipated to be a carcinogen. The conclusion is based on sufficient evidence of carcinogenicity in laboratory animals, and limited evidence in humans. IARC Mono4raphs?: 

### Yes . The'International Agency for Research on Cancer (IAF2C) Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans (Vol. 42, 1987) concludes that there is sufficient evidence for the carcinogenicity of crystalline silica to experimental animals, and that there is limited evidence of the carcinogenicity of crystalline silica to humans. IARC Class 2A. Signs and Svmptoms of Exposure: 

### Symptoms of excessive exposure are irritation of eyes, nose and/or throat, shortness of breath, sputum production. Medical Conditions Generallv Acgaravated by Exposure: 

### Pre-existing pulmonary and/or respiratory lung diseases, including, but not limited to; Emphysema, Asthma, or Bronchitis. Pulmonary function may be reduced by inhalation of respirable crystalline silica. Lung scarring produced by excessive inhalation may lead to a progressive massive fibrosis of the lung which may aggravate other pulmonary conditions and diseases, increasing susceptibility to pulmonary tuberculosis. Progressive massive fibrosis may be accompanied by heart enlargement, heart failure, and pulmonary failure. Smoking aggravates the effects of exposure. Sensitive eye conditions may also be aggravated by excessive exposure. Emeraencv and First Aid Procedures: Eves: 

### Flush eyes immediately and generously with water for 15 minutes. If irritation persists, seek medical attention. Inhalation: 

### For gross inhalation, remove person immediately to fresh air. Give artificial respiration as needed, and seek medical attention as needed. 

### Skin: Wash thoroughly. See physician if irritation persists. (payC 1 OI ]) OATA/911FATT/K50.S/I150.9-BRR.DOC

## SECTION VII - Precautions for Safe Handling and Use >' Steps to Be Taken in Case Material is Released or Spilled: Collect dust from dry-sawing or grinding operations using dustless method (vacuum or water). Wear protective equipment specified below. 

### Waste Disposal Method: Dispose in accordance with Federal, State, and Local regulations. 

### Precautions to Be Taken in Handling and Storing: Avoid breathing of dust particles from dry

### sawing and grinding of units. Take normal precautions against spilling of containers with waste dust particles from dry-sawing or grinding operations. OtherPrecautions: 

### Wear NIOSH approved respirator, tight fitting goggles, and gloves when sawing or grinding operations are active. Do not permit dust to collect on wall or floor surfaces, clothing, or equipment. See applicable OSHA Hazard Communication Rule 29 CFR Sections and State and Local worker or community "right to know° laws and regulations. We recommend that smoking be prohibited in all areas where respirators must be used. WARN YOUR EMPLOYEES AND (YOUR CUSTOMER-USERS IN CASE OF RESALE) BY POSTING AND OTHER MEANS OF THE HAZARD AND OSHA PRECAUTIONS TO BE USED. PROVIDE TRAINING FOR YOUR EMPLOYEES ABOUT THE OSHA PRECAUTIONS. See also the ASTM E 1132-86, "Standard Practice for Health Requirements Relating.to Occupational Exposure to Quartz Dust."


# ~ SECTION Vltl - Control Measures



# ~ NOTE: THESE CONTROL MEASURES ARE TO BE USED WHEN DRY-SAIMNG, DRY-GRINDING, OR OTHER MATERIAL MODIFYING OPERATIONS ARE ACTIVE. NORMAL CONDITIONS OF USE AND/OR INSTALLATIONS OF FIRED CLAY BRICK ARTICLES DO NOT REQUIRE RESPIRATORY CONTROL MEASURES. 

### Respiratory Protection: Use NIOSH approved Particulate Respirator. Provide additional 

### conventional respiratory protection based on considerations of airborne concentrations and duration of exposure. See most recent standards of the following: American National Standard Institute (ANSI Z.88.2) Occupational Safety and Health Administration (OSHA 29 CFR Part 1910.134) Mine Safety and Health Administration (MSHA 30 CFR Part 56) National Institute for Occupational Safety and Health (NIOSH Pocket Guide to Chemical Hazards) 

### Ventilation: Local Exhaust: Meet PEL requirements set out above in Section II.



### Special: N/A 

### Other: N/A 

## Mechanical(General); When cutting in confined area, meet PEL requirements. 

### Protective Gloves: Recommended. 

### Eye Protection: Tight fitting protective goggles. 

### Other Protective Clothin4 or Eguipment: As needed. Work/Hygienic Practices: Avoid creating and breathing dust (see Other Precautions, Sec. VII. ) The information, data and recommendations contained in this MSDS relates only to the specific material described, and is not to be used in combination with any other material or in any other process. This 

### information is based on data that Mutual Materials Company believes to be correct and reliable. It is intended for use by competent persons having technical skill sufficient to understand the limits and boundaries of 

### application. Mutual Materials Company accepts no responsibility and disclaims all liability for any harmful health effects which may be caused by purchase, resale, use, or exposure to fired clay brick and/or dust created by sawing, grinding or other operations outside normal conditions of use which may be performed on those units. Mutual Materials Company makes no warranties, either expressed or implied, concerning the application of the information herein. Any use of this information and data must be determined by the user to be in accordance with all applicable laws, regulations and orders. Ip•9e ] ot ]I oATA/elltYri/Mao6/ ~e~ 9e.[. 00 c -7 -1 2r 

### :::>::>::>:::::<:>::>:>:::;;.:; ;:.;:.;:;:.;:.;::::::>:< :::::::::::.::.:.:: i n f R vis o 0 

## . e
.:. ~ :::::: :::::::::::::::::::...........................................................................

...... .................... ....... ... ................. ........ 

### > 02 03 

## / /95

....................... . ...................................................... r Cor oratio ~

.... . Fer o n ~~~ o C 1 or Divi i P
.... s on P.O.Box 6550 

# „-3210 Page 1 Of 4 Cleveland, Ohio 44101 PH:(216)641-8580 FAX:(216)641-8831 

### BLUE Emergency Phone : (216)641-5324 1. Identification of the substance/preparation and the company/undertaking
2. Composition/information on ingredients CAS NUMBER: 68186958* CHEMICAL NAME OF THE SUBSTANCE: Blue 71 CHEMICAL FORMULA: (Zr,V)SiO4 CHEMICAL NAME: Zirconium Vanadium Blue Zircon 

### CHEMICAL FAMILY: Inorganic Pigment C.I. PIGMENT: 77998 

### 3. Hazards identification EMERGENCY OVERVIEW: An inorganic powder that poses little or no immediate hazard. It will not burn in a fire. Repeated or prolonged breathing of any dust may cause lung damage. ROUTES OF ENTRY: * Inhalation: * Ingestion INHALATION: Dust from the product may cause irritation of the respiratory system, nausea, or a metallic taste in the mouth. INGESTION: The product has low solubility in body fluids. Ingesting small amounts is unlikely to cause any severe health risks. SKIN & EYE CONTACT: May irritate eyes and skin. Acts as nuisance dust. MEDICAL CONDITIONS: Some inhalation and skin disorders may be aggravated by exposure to this compound. CHRONIC EXPOSURE: Prolonged exposure to dust may lead to pulmonary problems. HMIS HAZARD CLASS: Health: 1* Fire: 0 Reactivity: 0 

### 4. First aid measures INHALATION: Move to fresh air. INGESTION: For excessive ingestion, drink water or milk. Call a physician. Never give anything by mouth to an unconscious person. EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. SKIN CONTACT: Wash off immediately with soap and plenty of water. 

### 5. Fire-fighting measures EXTINGUISHING MEDIA: * ABC Dry Chemical, or * Water SPECIAL PROCEDURES: No special firefighting procedures are required. UNUSUAL FIRE HAZARDS No unusual fire or explosion hazards exist. NFPA HAZARD CLASS: Health: 1 Fire: 0 Reactivity: 0



### ~

### 6. Accidental release measures

Avoid dusting. Uncontaminated material may be scooped up for use. If contaminated, scoop or vacuum into a receptacle for disposal. Certain spills may require National Response Center (800-424-8802) notification. 

### 7. Handling and storage Protect containers against physical damage. Store in a dry area away from feed and food products. Wash thoroughly after handling. 

### 8. Exposure controls / personal protection EXPOSURE CONTROLS: CAS #: 7440-67-7 Zirconium Compounds, (as Zr) OSHA PEL: 5.0 mg/m3 ACGIH TLV: 5.0 mg/m3 ACGIH STEL: 10.0 mg/m3 This pigment is formed by high temperature calcination. Therefore, it does not necessarily have any of the properties of its component oxides or metals. VENTILATION: Use local exhaust ventilation to keep air contaminants below their PEL's while using this product. PERSONAL PROTECTION: PROTECTIVE EQUIPMENT *Safety glasses (to protect eyes against dust) *Cotton work gloves *Protective clothing, such as, but not limited to coveralls, smocks, shoes, and/or hats RESPIRATORY: Use a NIOSH approved respirator for dust. WORK PRACTICES: Avoid making dust. Do not breath or eat dust. Use only with adequate ventilation. Wash thoroughly before eating, drinking. smoking, or applying cosmetics. 

### 9. Physical and chemical properties

Aggregation : Not Applicable Colour : Blue Odour .: Odorless pH (at conc.) : Not Available Boiling Point : Not Applicable Melting Point : Not Available Flash Point : Not Applicable Flammability : Does not Burn Autoignition : Not Applicable Explosivity : Not Applicable Oxydation : Not Applicable Vapour Pressure : Not Applicable Density : 4.5-5.0 Solubility (water) : Negligible Solubility (others) : Not Available Form : Powder.



## ~~ 5

### visi n o f ' <';:::>: R o 

## e :»:.:::;:::::::::>::>< ::::::::::.:::::::::::: «>::::::::::::::::::>::::::::::::::::::::::>::::>::>:<:::>::.:>;::::>:<:> :.::<.<..:

................................. 

## ..:. .................:...... .. ....... ;:::::::::';;;: ~ 

## ; ::` ~ 

## <::: ::::':: ~:<~~~ 

## :::: ~~~~ 

## ::;:: ~~:?~~~~ 

## ''>:`:

. 

## :`'`<::>::: ~::~~ 

## ;:<:::::::':»::::::»': ~::~~:~~~ 

## :::::::........ ... <, ~~~.~ 

## ..,. ~~~ 2 

## : 0 03 

## / 95 /

.. ........,......... .......................,,.. ,..............,,....,................,...................,,,,......... o Co

................ .... . Ferr r oration ~~~~ Col r'vi - o Di ::: ....................... . . . P
.... sion P.O.Box 6550 

# ;-3210 Page 3 of 4 Cleveland 

### , ohio 44101 PH:(216)641-8580 FAX:(216)641-8831 

### BLUE 10. Stability and reactivity STABILITY: Stable at normal conditions. POLYMERIZATION: Hazardous polymerization will not occur. 

### INCOMPATIBILITY: None expected BY-PRODUCTS: None expected 

### CONDITIONS TO AVOID: None 

### 11. Toxicological information CARCINOGENICITY NTP: NO IARC MONOGRAPH: NO OSHA REGULATED: NO LD50/oral/rat : N/A LD50/derm./rat : N/A LC50/inh/lh/rat : N/A 

### 12. Ecological information

! Ecological injuries are not known or expected under normal use. l 

### 13. Disposal considerations RCRA INFORMATION: This material does not meet RCRA's characteristic definition of ignitability, corrosivity, or reactivity. It is not listed in 40 CFR 261.33. Contact the Regulatory Specialist in the Color Division R&D Laboratory for any Toxicity Characteristic Leaching Procedure (TCLP) data.



### 14. Transport information DOT: Not regulated. IATA: Not regulated. CERCLA RQ: None 

### 15. Regulatory information SARA TITLE III: This pigment is not reportable under SARA Title III. Section 313. TSCA: This product and/or its component(s) are listed on the Toxic Substances Control Act (TSCA) Chemical Substance Inventory. This substance is not subject to Section 12(b) of TSCA (Export Notification).


### I



## ~~~ ~- - 

### R i ~ - • 

### f e s i o n o ~::~ :::;<::<:: 

## < 02 /03/95 > ....:......................................>... Ferro Co r oration ~~~~ Col or
... Divi ~ . sio

. n P P.O.Box 6550 

### C-321 O Page 4 of 4 Cleveland, ohio 44101 PH:(216)641-8580 FAX:(216)641-8831 

### BLUE 16. Other information KEY: ACGIH = American Confernece of Governmental Industrial Hygenists OSHA = Occupational Safety and Health Administration TLV = Threshold Limit Value PEL = Permissable Exposure Limit (C) = Ceiling mppcf = Millions of particles per cubic foot of air STEL = Short-Term Exposure Limit N/A = Not Available est = estimated DISCLAIMER: Judgement as to the suitability of information herein or to the purchaser's purposes are the purchaser's responsibility. Reasonable care has been taken in the preparation of this information, but FERRO EXTENDS NO WARRANTIES, MAKES NO REPRESENTATIONS AND ASSUMES NO RESPONSIBILITY OF THIS INFORMATION FOR ANY PURCHASER'S USE OR FOR ANY CONSEQUENCES OF ITS USE.

# Material Safety Data Sheet

Substance Identification

,.. 

### GJ~~~~ 

# vt rI"

~ Identity: • f 

### ~ CAS #: 1308-38-9 Trade Names: CHROMOX
Chemtrec One Prince F 

### 1-800-424-9300 Quincy, IL 

### 62301
_ 217-222-8854 

# Components and Contaminants Chemical Name CAS # OSHA PEL ACGIH TLV Percent Chromium Cr+' 7440-47-3 0.5 mg/m 3 0.5 mg/m 3 (TWA) 30-45% Cr Silica, Crystalline Quartz respirable dust 14808-60-7 0.1 mg/m 3 0.1 mg/m 3 (TWA) 1.2% SiO Z 

# Physical Data Boiling Point: NA SpeciFc Gravity (H 2 0 =1): 4.4 Vapor Pressure (mm/Hg): NA Melting Point: 3350 - 4000 ° F Vapor Density (Air=1): NA Evaporation Rate (Butyl Acetate=l): NA Solubility in Water: insoluble Appearance and Odor: black powder, no odor. 

## Fire and Explosion Hazard Data C Flash Point: Not combustible

Flammable Limits: LEL NA UEL NA Extinguishing Media: Foam, CO Z , or dry chemical or water. Special F'ire Fighting Procedures: In the event of fire, wear full protective clothing and NIOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Unusual Fire and explosion hazards: Not combustible. 

# Reactivity Data Stability: Stable under ordinary conditions of use and storage. Conditions to avoid: None Known Incompatibility (materials to avoid): None Known. Hazardous Decomposition or Byproducts: None Known. Hazardous Polymerization: Will not occur. 

# Health Hazard Data Route of Entry: INHALATION: May cause delayed respiratory disease if dust is inhaled over a prolonged period of time. SKIN: No. INGESTION: Ingestion of Iron Chromite may cause abdominal pain and nausea.

Iron Chromite, Page 1 April 1991

## Health Hazard Data (cont.)

Health Hazards (Acute and Chronic): Respiratory disease may result from prolonged overexposure. Can cause eye irritation. Carcinogenicity: NTP: No IARC Monographs: Yes (Silica) Signs and Symptoms of Exposure; Excessive inhalation of dust may result in shortness of breath and reduced pulmonary function. Symptoms of silicosis include impaired pulmonary function and wheezing. Aggravation of Pre-existing Conditions: Persons with impaired respiratory function may be more susceptible to the effect of this substance. Emergency and First Aid Procedures: IF INHALED, remove to fresh air and seek medical attention for any breathing difficulty.IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. IN CASE OF EYE CONTACT, flush eyes immediately with water for at least 15 minutes. Seek medical attention if irritation persists. IF' INGESTED, induce vomiting immediately by giving two glasses of waterand sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

## Precautions for Safe Handling and Use Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel requir.e respiratory protection. Recover uncontaminated material for use. Vacuum or sweep remaining material, keeping dust to a minimum. Waste Disposal Method: Dispose of unreclaimable material in a RCRA-approved waste facility. Handling and Stor'ing Precautions: Protect containers from damage and keep closed when not in use. Other Precautions: Observe good personal hygiene. Wash after handling. 

## Control Measures Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or is anticipated. OSHA standard 1910.134 or ANSI Z88.2-1980 specifications are recommended. Ventilation: A system of local and / or general exhaust is recommended to kecp employee exposures below the Airborne Exposure Limits. Local exhaust is generallv preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to theACGIH document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details. Protective Gloves: Yes Eye Protection: Safety goggles are recommended. Other Protective Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonged exposure to skin. Work and Hygienic Practices: Observe good personal hygiene. Wash after handling.



## SARA Title III Section 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-to Know Act of 1986 and of 40 CFR 372.45: Component CAS # °j

. ~ 

### by WeiQht 

### Iron Chromite 1308-38-9 30 - 35% Cr This information must be included in all MSDS's that are copied and distributed for this material.

Iron Chromite, Page 2 April 1991



### ~ 

# %

### `'."!ATEF:AL SnFETY DATA SHEET MSDS I D # 860 F' AGc ` Z FRANV D. DAVI S C:QC1F'ANY THI S I I`JFCi4MATI ON I S FUF;NI SHED 'W I THQUT WARRANTY , EXF'RESSED i!R I MF'LI ED, EXCEF'T THAT I T I S ACCURATE TC i THE eEST E:NOWLEDGE i!F DAVI S
~ 

### i=:CiL ORS. THE DATA CiN THI S SHEET RELATES i-iNLY TO THE SFEGI FI i= MATERI AL

DESI GNATED HEF;EI N. DAVI S COLOF;S ASSI MES NO LEGAL RESF'ONSI fiI LI TY FOFi t_1SE OFi ~ 

### 'iEI I ANCE UF'ON THESE DATA. THI S F'RODUCT i_ONTAI NS TRACE AMGUNTS GF GHEMI CALS CONSI DERED BY THE STATE OF CALI FBRNI A TO BE !=AR = I NCiGENS On F:EF'F:ODUCT I VE Ti!X I C:ANTS . USE C:ARE WHEN HANDLI NG ANY i=:HEMI CAL F'RCiDUi= T SECTI ON 1- MANUFACTIIFiEF: I NFOr;l`1ATION

-------------------------------------

~ 

### MANUF/DI ST. ..; FF:ANk D. DAVI S ADDFtESS 1. .. .; F.O. BCiX 23100 EtiERGENCY F'HCiNE; Z15 269 7Z11 ADDRESS 2....: 3700 E CiLYMF'I i= ELVD F'REF'ARATI i!N/F:EVI SI ON DATE ; 6 8 87 CITY/ST/ZIF'. . 1 LOS ANGELES, CA. 9002Z LOCATIGN.. ; PREPAF;ER/CC WTACT; ED BEDSWOFiTI

- 1

_.,.. ~ 

### .

TRADE NAME/ SYNCiNYMS ~ 

### . . . :,'

~ 

### 1a1

~~ 

### ' . •. ^ ~~1~ 

### ` .: ~ ~ 

### '-:: C:HEh'1I C:AL NAME/SYNC ~ 

### NYMS: I ~Fi~ ~Ti ~ 

### nXI DE C HEMI i_ AL FAMI LY .......: i FiON OX I DE FC 1 nM`_ 1 LA . . . . . . . . . . . . . . . : C 12 

### F'RODt h_

T +_ ODE . . . . . . . . . . : 861 ~ 

### i_AS NUMBEF: ............: 1lTZ 86 4 

# C SECTION 2- HAZARDO , ?S INGrEDIENTS / IDENTITY INFORMATIO-N

--------------------------------------------------------- 

### THIS F'F:CiDUCT i:ONTAINS HAZARDOUS INGREDIENTS (Y,N,N/A,N/I) ; N

CHEMIGAL/j=OMt'iON NAME CAS-Nl%!"iBEF % F'EL-OSHA TLV-ACt-I!-' SYNTH IF:ON OXIDE BLACV 133= 86 4 3.5MG/m3 3.5mg/mE THI S F'RODUGT C:ONTAI NS C:ARGI NGGENS ( NTF' , I AF;C: , C!F: CiSHA )(, N, N/ A, N/I ): n

C:HEMI C:AL/C: ~ ~ 

### MMON NAME CAS-NUMBER % NTP I AF:C OSHA synth iron o::::ide black 1333 86 4 no no n ~ ~

~~

### - (`1ATEF;AL SAFETY DATA SHEET hiSDS I D # 860 

## PAGE -

SECTI C iPd Z- HEALTH HAZARD DATA 

# ------------------------------- C HEALTH EFFEC TS ( ACUTE AND C HF:ONI i= )- riGrie l;nown ot.het` t.flari po551 bI e f.efiipOY
- '3rg d1 ScofiifGY't ~~ t~ t; , ` =L _ f

~ 

### ._ _ i r
~~ ~ 

### al ._ i= ~r~ r~ 

### DUST COtvi=ENTRATI+ iNS ABOVE THE PERMI SSI BLE EXPOSUFE LIMIT.
F'RI MAF:Y ROUTES OF ENTF:Y

- 

### I PJHALATI C iN YES S I N NC i I NGESTI ON YES MEDIC:AL CONDITIONS AGGEAVATED BY EXPOSt1RE— NCiNE F;NOWN O T HER THAN MENTI ONED I N HEALTH HAZARDS . EMERGENC:Y FIFST AID Pf;CiCED!1RES— SE:I NCC iNTACT WASH WI TH SOAF' AND WATEFt . EYE Ci=iNTAi_T FLUSH WI Tr LARGE A`1T . WATER i=C i;aSt 1LT F'HYSI CI AN, I NHALATI ON REMi VE FROM DUSTY AREA .

SEGTION 4 — CHEMIi_AL DATA

-------------------------- 

### BOI LI N!= POI NT ( F ) , , . . ; NA SPEC:I FI C GnAV1 TY ( WATER=1 , , , , , , , , , , , , , ; 4.6 v ;Pi iR F'F:ESSt 1RE ( MMHG ) 2 NA F'EFiC'ENT V ~ ~ 

### LAT I LE BY VOLi Ir'!E ( ;. ) , , 4 , , , , , ; N.Fi 

### E~ 'OR DENSITY (AIF:=1 ) ; NA EVAF'OF;ATION FATE ( =1 ) ; NA SC+LUBI LI TY I N WATER— 

## NIL AFF'EARANi_E AND C iDGFi I NFOFiMATI!

~ 

### N— AM ~ ~ 

### RF'HO11S BL ACE: Pi iWDEF: ( N ~ 

### ODOh ) MAY BE F'ELLETI ZED

SEi_TION 5— FHYSICAL HAZAFiD DATA

FLASH F'CiI NT ( METH ~ 

### iD USED ); MAY I c_NI TE FLA.MMABLE LI MI TS ; LEL= NA UEL= NA EX.TI NGt lI SHI NG MEDI A— C:H'=MI C:AL EXTI NGt)I SHEFi MEDI A, IJETS F'OOF;LY WI TH WATER , SPECI AL FI RE FI GHTI Nc, F'ROCEDl1r;ES— NCiRMAL FOG ON pdOZZLE JET AFJF'LI GATI ON EXCLUDE AI F; UNUSUAL FIF;E AND EXF'LCiSION HAZARDS— C:ARDON MONC iX I DE AND r02 AAE FRnDUCTS OF COMBUSTI ON USE APPROPRI ATE RESFI RATOR FOFi PF;C iTEi_ TI i

N AGAI NST POSSI BLE EXPOSURE TO C O TCi CO5

1 NC:i=iMPHTI BI LI TY (MATEFiI ALS TO AVOID )— CHEMI CAL OXI DI ZI NG AGENTS HqZAFDOUS DECOMPOSI TI ON PRODUC:TS— ~ 

### F'OSSI BLY GARE<ON MOtvOX I DE WHEN BUF;NI NG ~~ ~/1°/S9 • MATERAL SArETY DaTA SHEET NSDS Ir +- '

~ k 8cf:) 

### PyGt' 4 SECTI ON cc - SPI LL OR LEAE: PRCn=:EDUF:ES



## ~ STEF'S Ti

i BE TAVEN CASE MATEn:I AL I S F;ELEASED i=iF: SF'I LLEDHANDLE AS NORMAL SOLI D WASTE , SC OOF' UP BY SOi•tE h1EANS AND F'LAi_ E: N A I:iAS T E
r:~ ~ NTAI NER .



### WASTE DI SF'CiSAL METHCiDSWASTEE MATEF:I AL !=IN E+E BURI ED IN A AF'PROVEn LANDFI LL OF; HANDLED ?S I NEF:T WASTE I N ACC ~ ~ 

### RDANi_E WI TH FED, STATE AND LOCAL ENVI F;ONh'iENTAL F:EGULATI ONS . 

### SECTI ON 7- EXF'OSUC;E CONTC;CiL I NFOF:MATI ON


## -----------------------------------------
VENTI LATI ONLG+_AL EXHAl1ST ; X SFEC:I AL . . . . . . : NA 

### MEC:HA!`.II C AL ( GENERAL ): NA 

## iiTHER ...............2 NA F;ESF'I FtiAT ~ ~ 

### nl'" PFtOTECTI ONNIUSH AFPROVED FOF: DUST, f1ISTS AND FUMES. DO Ni!T EXi=EED USE LIMITS OF THE RESFI RATQR .

PROTEC:TI VE GLOVES

### F;t1F+BEFi, CLOTH OFt PLASTIC: CLOVES.

OTHEF: Pr;OTEC:TI VE Ei1iUI FMENTNP, OTHEF; ENGI NEEFiI NG CONTEi ~ ~ LS

### N A WGF:4; PFAi=TIi=ES 

### DO Ni iT STCiRE NEAF: FCiOD AND DF:I NV . WASH EXF'OSED SE, I N FOFi HY:=I ENE PUnF'O=ES .HYGIENIC PFiACTIC:ESSAME AS AEji iVE

~~ 09 /89 , '-MP,TERAL SAFETY DPTr? SHEET r1EDS I D # 860 PAGE

SEi=:TI ON 8 - SF•EC: AL F'nEi=:AUTI ONS



### PFEGAt 1T I ONS TO BE TAVEN I N HAI`dDLI Nc_ aND STORAc;E - 

## NAMAI NTENANCE F'RECAUTI ONS

## NA OTHER PRECAUTIr_iNS=y 

## NAADDI TI ONAL GOMMENTSSTORE AT DRY AMBI ENT TEMF'ERATt 1RE AWAY FRO!`1 FOOD AND DRI NF? ,

SEC:TI ON 9- HAZARDOUS MATERI ALS I DENTI FI i:ATI ON SYSTEM ( H^

0=14INIP1AL HAZAFiD 1=SLI GHT HAZARD E=MC DEFiATE HAZARD 

### 3=SERICiUS HAZARD ^-SEVEFE HAZAF:D 

# I HEALTH . . . . . . . 0 - 4 . . : i) 

### FLAI`1ABI LI TY .. 0 - 4..: 1 F;EAC-T I VI TY . . . 0 - 4 C) PEF;SCiNAL PRQTECTI ON . . :

SEr:TI i N 10 - 

### TECHNI CI AL DATA



# --------------- LHS/gal s @ 25 C: SF'ECI FI r GFtAVI TY OI L ABSORPTI ON FE203% 

### loss on igr,i±iori pri 1 0% SLl!RFiY 18. J 

### 4.6

? 

### 1 94-9b 1.5 

## 6

~3~.......... 

### MATERIAL SAFETY DATA SHEET RED IRON OXIDE Pfizer Inc. Form 1


### Product/Material: Red Iron Oxide Manufacturer: Pfizer Inc. Address: 235 E 42nd Street, New York, NY 10017 Emergency Tel. No.: (212) 573-2816 Section I - Product Identification Trade Name: Red Iron Oxide Synor.ym: Iron Oxide, Ferric Oxide Chemical Family: Metal Oxide Formula: Fe 2 0

C.I.Pigment Red 101, C.I. No. 77491 CAS Numb er: 1309-37-1 Section II - Hazardous Inyzredients Name (CAS 

### li ) X TLV 

### None
Section III - Phvsical Data Boiling Point ( ° F): Not Applicable Vapor Pressure (mm Hg): Not Applicable Vapor Density: Not Applicable Solubility in Water: Insoluble Specific Gravity (H 2 O=1): 4.8-5.2 Percent Volatile by Weight: 0 Evaporation Rate: 0 Appearance and Odor: Red to Reddish Brown Powder, No Odor
Section IV - Fire and Exnlosion Hazard Data Flash Point (Method Used): Non-flammable glammable Limits: LEL - Non-flammable UEL - Non-flammable Extinguishing Media: Water Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None Section 5- Health Hazard Data Threshold Limit Values: Inert or :(uisance dust - 5 mg/M 3 respirable (ACGIH b OSHA) 10 mg/M 3 total dust (ACGIH) 15 mg/M 3 total dust (OSHA) Effects of Overexposure: Irritation in respiratory tract Emergency and First Aid Procedures: Wash dust from skin with soap and water. Flush out eyes with generous amounts of water for at least 15

~ 

### minutes. See a Physician.

-;~ 

# -34

### trIATEhAL SAFETY DHTO SHEET MSD S I D # 1117 F'AGE FRAN>~: D. DAVI SCi iMFANY THIS INFORMATION IS Ft1F;NISHED WITH=iUT WAF:RANTY, EXF'RESSED OR


### ~ IMF'LIED, EXi=EPT THAT IT IS ACCl.!F;ATE TO Tf-IE PEST hNiiWLEDGE OF DAVIS C:OLOFS . THE DATA ON THI S SHEET F;ELATES ONLY TO THE SPEGI FI C MATERI AL DESI GNATED HEREI N. DAVI SCOLOFiS ASSUMES NO LEGAL RESFONSI EsI LI TY FOR USE Gh RELIANC:E UF'ON THESE DATA.

SEC T ION 1- MANI_1FAi_ TUREF: I NFi iF;P1AT ION


## -------------------------------------
MANUF/DI ST. ..: FFtANh D. DAVI S i=OMF'ANY ADDRESS 1....: P . O . Bi 

### ~ X 2000 ElMERGENC Y F'HONE : Z 1 Z 26V-7Z 1 1 ADDRESS 2.... ; 3700 E. OLYMF'IC EsLVD. F'REPAF;ATION/F;EVISIiiN DATE: CITY/ST/ZIP..: LOS ANGELES, CALIFGFNIA 9002Z L0CATIiiN..: F'REFAREF:/i=EiNTAt_T: ED SEDSWiiF:TH



# ~ TRADE NAMF/SYNCiNYMS...:

CHEM I i=:AL 'NA"IE / SYNONYMS : i_ 1-IEMI i= AL FAMI LY . . . . . . . : 

## FOFMULA..............,.: PhODUi=T GUDE..........: i= AS NUMBEF :. . . . . . . . . . . . : 

### I hON OX I DE RED I F;ON OX I DE RED I NOt=;GANI r OX I DE FeZi ±3 

## 1117 11Q9-37-1

SECTI ON Z- I-IAZAkDOUS I NGf;EDI EnlTS / I DEI`1 T I TY I N1-i iF:f1ATI i=!IV


## --------------------------------------------------------- THIS PFiODUCT i=iiNTAINS HAZAF;DOUS INCREDIENTS (Y,N,Pd/A,N/I ): N

i=:f-fEMI i: AL/i==OMMON NAME CAS-NUMBEF.' 'l. :='EL-CiSHA TLV-ACGI ,- SYNTH I Ri

iN OX I DE RED 1,=,09-,:,7-1 NA NA THI S F'Fi iDt li_ T i= i_iNTAI NS CARi= I NOGENS ( NTF' , I AF;C , i iR OSHA )(, N, N/A , N/ I): N

GHEMI CAL/C>=iMP1i iN NAiIE CAS-NVI'1BER % NTI 'I AhC OSh{A SYNTH IRCiN OXIDE FED 1309 Z7 1 NO NO NO



# -23 ~9



### i1&/8b MATERF'iL SHFETY DATA SHEET I"ISDS ID # 1117 F'Ac,E:



# ~ SEi=TION 3 - HEALTH HAZARD DATA

------------------------------- HEALTH EFFEi=TS (Ai=t1TE AND CHRONIG)- 

### NnNE OHSERVEDPRI MARY REiUTES i iF ENTRY

## N/A MEDI GAL i=ONDI TI i_iNS Ac:,GRAVATED EiY EXFiiSURENi iNE

### EMERGEN_Y FIhST AID F'hiii=EDURESSE; I N i= i iNTAi= T : WASH WI TH SOAF' AND WATER , EYE i: ONTAC T: FLUSH WI TH LARGE AMNCiUNTS OF WATER . C:ONSl1LT 

## AN EYE FHYSICIAN.
SECTI 01 , .1 4- C:HEIhI CAL DATA


## -------------------------- SOI LI NG F'OI NT ( F).,.,: N/A VAF'i iF: F'RESSt_!RE ( ihMHc; ): N/A 

### 'dAF'On DENSI TY ( AI R=1 ): N/A y l UBI LI TY I N WATEr - I NS! iLUBLF_ AF'F'EE=iRANi=E AND ODOF I NFi iRh'IATI!

~ 

### NRED , ODORLESS F'i !WDER SFE C I FI C GFiAVI TY ( WATER= i . . . . . . . . . . . . . : 5 , !7 PEFiGENT Vi

LATI LE BY Vi iLt1ME ( %) . . . . . . . . : N/ A EVA.F'i iF:ATIi iN F:ATE (B!1TYL Ai=ETATE =I ): NA

SEGTIGN 5- PHYSICAL HAZAF;D DATA


## --------------------------------- FLASH POI NT ( METHOD USED ): N/AEXTINGUISHING MEDIANG FI NE HAZA{;DSF'`C I AL FI F'E FI GHTI NG F('C1i_ EDUF:ES

## N/AUNl1Sl1AL FI RE AND EXF'LOSI ON HAZAFiDSnone INC ~ 

### iMF'A T I BI LI TY ( M('TEF;I ALS TO AV+=iI D)- r,one

~ 

### 9RDnUS DEC ~



### iMF'OS I T I i iN PSODUC TSNuNE lkiI LL HAZARDOUS PI

-JLYMERI ZATI r_IN 0f_CURWI LL Ni

~ T i ii= i=l_)Fi 

## FLAMMABLE LIMITS: LEL= N/A UEL= N/i

CGNDI TI ONS TO AVOI D FGF: P ~ ~ 

### LYMEF;I ZATI ON- p2?j
~ 

### ,S ~

~ 

### _ / 1S/38 I"IATE:F:raL SAFETY llA TA SHLET MSDS I D # 1117 F-

~ 

### HGE 4 SEC TI ON b- SPI LL CiR LEAE: F'ROC:EDUF:ES

~
STEFS "fii BE TAI-:EN CASE MATERIAL IS F2ELEASED OF SF'ILLEDMATERI AL CAN BE HANDLED AS NCiF:MAL SOLI D WASTE; SCOOF' UP E+Y SCiME MEANS AND FLAi=E I N A WASTE CONTAI NER .

WASTE DI SPi iSAL METHODSWASTE MATEF:I AL C AN BE B! 1C;I ED I N AN AF'F'FiOVED LANDFI LL OR HANDLED AS I NERT WASTE I N AC r:ORDANC E WI TH FEDEROL , STATE AND LOC AL ENVI F;ONMENTAL REGt_1LATI ONS.
SEi1TI i N 7- EXFi iS11RE GONTROL I NFORMATI CiN

-----------------------------------------


### VENTI LATI C iNLOr:AL EXHA!_%ST t REMOVE AIF'BOFNE D! 1ST MECHANICAL (GE:`wERriL) : N/A SPE!=IAL ...... : N/A OTI-iEFi • ..............: NiA F;ESF'I F:ATOFY F'hOTEC TI ON- 

### _?I OSH APPf;CiVED MASV F ~ 

### ;R D! )STS , MI STA AND FUMES ) TEC:TI'•+'E GLi

VES

### r.oBBEF: GLOVES i iR F-

~ 

### LASTT I_ C I,q i=LOTH

OTHER F'ROTEC:TI VE EQ!?I P!`1ENT

### SAFTY GLASSES ARE nE+=OMMENDEDOTHEF: ENGI NEERI NG Gi iNi"F: _iLSNONE 

### 4JORV FRA,CTI i=ES N~ iNE

### HYGI ENI C PRAC TI CESNi

~ 

### NE



## 1

~~ ~

### , . I"IATERHL SAFETY DATA SHEET I"ISDS i D # 1 1 17 F'AGc

~ SECTI i iN 8- SF'ECI AL F'REi=AUTI i iNS 

### -----=---------------------------F'REC At 1T IONS Ti iBE TAKEN I N HANDLI NG AND STi ;F;AGESTORE DRY AT AMBI ENT TEMF'ERATURE AWAY FROM Fi ii iD AND DRI NE:, MAINTENANC-:E F'REr:AUTIl
--lNS

### NCiNEOTHER F'FiEC:AUT I O1`dSNi iNE

### ADDI T!: i iNHL i=OMMENTSNONE



### SECT ION 9- HAZAF;D ~ ~ 

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### ------------ --------------- LiS/g31 @25r: 41.65 SF'Ei= I F I i1 GFFAV I TY 5.0 OIL ABSORF'TION 26 FE2037. 95-97 0.5 

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### Ziaterial Safety Data Sheet



# ~ AMERICAN MINERALS 901 EAST EIGHTH AVENUE, P.O.BOX 1569 .. . KZNG OF, PRUSSIA, PA 19406 

### Phone: Health & Safety . Info 215/337-1100 PRODUCT: MSDS: AMMNO2 Date: 12/90 Revision: 6/93
National PaiA 

### •and Coatings Association Hazardous Material Identification System HEALTH HAZARD 2- Moderate Hazard FLAMMABILITY HAZARD 0- Minimal Hazard REACTIVITY HAZARD 1 - Slight PERSONAL PROTECTION B- Glasses & Gloves

i SECTION I. MATERIAL IDENTIFICATION I Chemical Name: Pyrolusite, " ~`~'" ~ `~' 

### ganese}dioxide (Mno Z )f Description: Pyrolusite ore (manganese dioxide) is used for many ir}dustrial and chemical applications. It is the source of manganese and all its compounds; largely used in manufacture of manganese steel; oxidizer; in alkaline batteries; decolorizing glass; in ceramic bodies and glazes. CAS#: 1313-13-9 

### Manufacturer: American Minerals Phone: 215/337-1100 ( SECTION II. INGREDIENTS AND HAZARDS Ingredient Name: CAS Number: Percent: Exposure Limits: Pyrolusite (Mn0 2 ) 1313-13-9 72-80 For Manganese Dust, as Mn, and compounds CAS#7439-96-5 ACGIH TWA is 5mg/m s . OSHA Final Rule 

### Ceiling: 5mg/m 3 . FUME: OSHA PEL:TWA /Mn/ lmg/m 3 ; STEL 3mg/m 3 . Quartz (*) (SiO Z ) 14808-60-7 1-3 OSHA PEL:TWA for respirable quartz - 0.10mg/m 3 . 13arium, Component of Mn ore 7440-39-3 1-2 ACGIfI TWAiis 0.5mg/m 3 ae /Ba/. OSHA PEL:TWA 0.5mg/m 3 . as /Ba/. Nonhazardous Ingredients (Nuisance Particulates) ---------- 15-25 Nuisance Particulates OSHA PEL: TWA, Total Dust: 15mg/3 3 ; Respirable Dust: 5mg/m . ACGIH TLV:TWA Total Dust 10mg/m 3 ; Respirable Dust: 5mg/m 3 . The product may contain a trace of lead which exists as an integral, complex mineralogical constituent of the manganese ore. The lead (0.0 - 0.2$) (Inorganic) CAS#7439-92-1 listed by IARC: Possible human carcinogen (Group 2B); human evidence is inadequate; animal evidence is sufficient. The OSHA PEL:TWA for lead is 0.05mg/m 3 . A substance specific standard applies (see 29 CFR 1910.1025). (*) A polymorph of crystalline silica. Identified by IARC as a"Probable Human Carcino9en" Group 2A. NTP lists respirable quartz amonget substances which may 

### ~ "reasonably be anticipated to be carcinogens".

Page 1--- INGREDIENTS AND HAZARDS continues an page 2 --- Page 1

/ 1 r 

### ~ -- 

### ~e 1 ~
Material Safety Data Sheet 

# 7 AMERICAN MINERALS PRODUCT: Manganese Dioxide 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AMMNO2 

### Phone:.'Health & Safety Info 215/337-1100 Date: 12/90 Revision: 6/93
SECTION III. PHYSICAL DATA Appearance and Odor: Black to brownish black and available in various size ranges from granular to fine powders; odorless. Bulk Density: 125 - 132 lbs/cu.ft. (=17 lbs/gal) Melting Point: >2800°F Water Solubility (%): slight $ volatile by volume: 0 pH (10$ Aqueous Slurry): 9- 10
SECTION IV. FIRE AND EXPLOSION DATA Extinguishing Media: Use dry chemical or CO Z on fires involving Manganese dioxide. Unusual fire or explosion hazards: Although not combustible, manganese,dioxide is astrong oxidizing agent. It may increase the burning rate of combustibles with a flareburning effect. It may cause reignition after a fire is extinguished. Oxygen from the thermal decomposition of Mn0 2 facilitates combustion.

### special Fire-Fighting Procedureai Since fire may produce toxic fumes, wear a seJ.fcontained braathing apparatue (BCSA) ws th full faeopioce operated in the 

## preesura demand or positive-pressure mode. Be aware of runoff from fire control methode. Do not release to sewers or waterways. !r I SECTION V. REACTIVITY DATA Stability: This product is a stable at room temperature in cloeed containere under normal conditions of storage and handling conditions. Hazardous polymerization will not occur. Chemical incompatibilities: Manganese dioxide is a powerful oxidizer, hence it should not be heated or rubbed with organic matter or other easily oxidizable substances, e.g., sulfur, sulfides, phosphides, hypophosphides, etc.. Flammable by chemical reaction. Incompatible with hydrogen peroxide; sodium peroxide. Keep away from heat and flammable materials.
SECTION VI. HEALTH HAZARD INFORMATION Carcinogenicity: The NTP, IARC, AND OSHA do not list manganese dioxide as a carcinogen. summary of risks: Manganese is an essential trace element for living organisms. Although found in all human tissue, acute or chronic manganese poisoning can occur from excessive intake via inhalation or ingestion. Manganese dioxide dust inhalation can irritate the respiratory tract and lead to lung damage, pleuritis, bronchitis, and increased incidence of respiratory infection. Large inhaled particles may be cleared from the respiratory tract and swallowed, but small particles are eventually absorbed into the blood. Medical conditions which may be aggravated by contact: Lungs; central nervous system diseases, psychiatric disorders, eyes. Target organs: Respiratory system, central nervous system. 

# i !rimary entry route: Inhalation, Ingestion Page 2--- , HEALTH HAZARD INFORMATION continues on page 3 --- Pa9e 2



# _ 7 ~ 1bMaterial Safety Data Sheet



### ~ AMERICAN MINERALS PRODUCT: Manganese Dioxide 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AMMNO2 Phone: Health & Safety Info 215/337-1100 Date: 12/90 Revision: 6/93 HEALTH HAZARD INFORMATION continued from page 2 

### Acute Effects: Exposure to high concentrations of manganese dioxide causes an influenza-like illness (metal fume fever). The 24 to 48 hour illness is characterized by chills, fever, aching muscles, dryness in the mouth and throat, and headache. ManganesA duet and fumos are minor irritants to tho eyes and completely innocuous to the intact skin. Manganese pleuritis, bronchitis, or pneumonia may also occur. Chronic Effects: Prolonged excessive inhalation can bring manganese into the body via both the lungs.and digestive tract (swallowed mucous). to cause systemic poisoning. Chronic poisoning is usually in 6 to 24 month. Syzaptoms include apathy, anorexia, headache, weakness, and easy fatigue, then clumsiness, speech problems and other central nervous system effects. Progressive and permanent disability can result from chronic untreated manganese poisoning, but it is not fatal. signs & symptoms of overexposure: Eye contacts Phyaical Irritation Skin contact: Possible irritation from repeated or prolonged contact to

individuals sensitive to mineral dust. Inhalation: Throat and Upper respiratory irritation. )rst aids 

### Eye contact: Flush eyes, including under the eyelids, with large amounts of

water. If irritation persists, seek medical attention. Skin contact: Wash affected area with mild soap and water to remove any dust and

manganese dioxide adhering to the skin. Inhalation: Remove exposed person to fresh air. Support breathing as needed. Ingestion: If ingested, have victim drink 2- 3 glasses of water, then

induce vomiting, then seek medical attention.
SECTION VII. SPILL, LEAK AND DISPOSAL PROCEDURES Spill / Leak procedures: The product is not readily soluble, however prevent the spill from entering water and waste water systems. Cleanup personnel need to wear approved respiratory protection, gloves, long sleeved clothing and goggles to prevent irritation from contact and inhalation. Reuse all spilled material whenever possible. Waste management / Disposal: The product is not a listed hazardous waste and does not exhibit any characteristics of a hazardous waste, including the EPA's TCLP for toxic characteristics. Follow all local, state and federal regulations for proper disposal.

SECTION VIII. SPECIAL PROTECTION INFORMATION 

### Personal protective equipment: The use of safety glasses, gloves, and long sleeve ciothing is recommended. The use of OSHA approved particulate dust respirator in accordance with 29 CFR 1910.134 must be worn for dust exposure above allowabl• sxpoeure

~•~ mits.

Page 3--- SPECIAL PROTECTION INFORMATION continues on page 4 --- Page 3
~U-~~Material Safety Data Sheet

~ AMERICAN MINERALS PRODUCT: I Manganese Dioxide 901 EAST EIGHTH AVENUE, P.O.BOX 1569 K ~ N¢ OP' . PRUSSIA, PA 19406 MSDSt AMMNO2 

### Phone: Health & Safety Info 215/337-1100 Date: 12/90 Revision: 6/93 SPECfAL-PROTECTION INFORMATION continued from page 3 Workplace Considerationst Ventilation: If airborne contaminants are generated during material handling, provide general ventilation and local ventilation in sufficient volume and air flow patterns to control air contaminant concentration levels below allowable exposure limits.

SECTION IX. REGULATORY INFORMATION AND SPECIAL PRECAUTIONS The product contains 72-80$ Manganese dioxide (Mn0 2 ) CAS11313-13-9. Manganese dioxide is not epecilically listed on any Federal regulatory lists, howover ManqanQse compounds, as /Mn/ CASI 7439-96-5 are listed, and manganese dioxide falls into this classification. Manganese compounds, as /Mn/ CAS* 7439-96-5 are regulated under requirements of SARA TITLE III Section 313. The product contains 1-2$ Barium. Barium compounds are listed under the EPA: EPCRA section 313; de minimis concentration is 1 percent. The product contains 0.0 - 0.2$ lead CAS#7439-92-1. The lead is in the form of an inorganic lead compound. The EPA CERCLA RQ for lead is 1 pound. EPCRA section 313 de minimis concentration is 0.1$, and so it is reportable under SARA Section 313. Lead is listed under the following regulatory lists: Clean Water Act Sections 304 & 307, Safe Drinking Water Act Maximum Contaminant Level Substances & Statutory Contaminants, Clean Air Act Section 112, NIOSH Recommendation Substances, RCRA Hazardous Substances & Hazardous Constituents for Groundwater Monitoring, CERCLA Hazardous Substances, SARA Title III Sections 302 and 313, OSHA Air Contaminants & Specifically Regulated Substances, and the Massachusetts, New Jersey and Pennsylvania state lists. storage Requirementa: Store in eloeed containers in a cool, dry, woll-vontilatQd area away from sources of heat and ignition. Protect containers from physical damage. Since manganese dioxide is a strong oxidizer, store separately from organic and other oxidizable materials. TSCA INVENTORY: A11 substances contained in the product are listed in the Chemical Subetance Inventory of the Toxic Substancea Control Act. DOT Class: Not Regulated
SECTION X. REFERENCES References used in preparation of this material safety data sheet: Clansky, K.B., Suspect Chemicals Sourcebook, 1992-2 Edition, Roytech Publications, Bethesda, Maryland. Sax, N. Irving: Danqerous Properties of Industrial Materials, Seventh Edition, Van Nostrand Reinhold Co., Inc., 1989.Kirk, R. and Othmer, D., Encyclopedia of Chemical Technolooy, Third Edition, WileyInterscience, New York, NY 1980. Sax, N.Irving and Lewis,R.J. Hawlev's Condensed Chemical Dictionary, Eleventh Ed., Van Nostrand Reinhold Co.,Inc., NY

~ 

### M,terial SafetY_Data Sheete, Genium Publishinq Corporation, Schenectady, NY

Page 4--- MSDS continues on page 5 --- Page 4

### Material Safety Data Sheet

~ 

### AMERICAN MINERALS PRODUCT: I Manganese Dioxide 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AMMNO2 Phone:.'Hea'lth & Safety Info 215/337-1100 Date: 12/90 Revision: 5/93 SECTYON,.XI. ACRONYMS/DEFINITIONS USED IN THIS MSDS ACGIH: American Conference of Governmental Industrial Hygienists CAS#: CAS Registration Number is an assigned number to identify a

material. CAS stands for Chemical Abstract Service. CERCLA: Comprehensive Environmental Response, Compensation, and Liability

Act (also known as euperfund)(EPA). EPA: Environmental Protection Agency EPCRA: Emergency Planning and Community-Right-To-Know Act(SARA TITLE III) HMISTM: Hazardous Material Identification System, National Paint & Coatings

Association. IARC• International Agency for Research on Cancer mg/m 3 : Milligrams per cubic meter NFPA: National 

### Fire Protection Association NTP: National Toxicology Program , OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit (OSHA) RCRA: Resource Conservation and Recovery Act (EPA) SARA: Superfund Amendments and Reauthorization Act Title III: Emergency Planning and Community Right to Know Act Section 302: Extremely Hazardous Substances Section 304: Emergency Release Section 313: Toxic Chemicals - Reporting - Form R TCLP: Toxicity Characteristic Leaching Procedure TLV: Threshold Limit Value (ACGIH) TSCA: Toxic Substances Control Act - EPA TWA: Time Weighted Average - 8 hours

Prepared/revised by: A.G.Nighswander June 7, 1993

\ 

### / Although reasonable care has been taken in the preparation of the information contained herein, American Minerals extends no warranties, makes no representation and assumes no responsibility as to the accuracy or suitability of such information for application to purchaser's intended purposes or for consequences of its use. Page 5--- End of MSDS --- Page 5 

## 694/

### CUSTOMER - MUTUAL MATERIALS CO. Page: 1 MATERIAL SAFETY DATA SHEET 

## Prepared: 09/06/94



# ~~ Cerdec Corporation Drakenfeld Products P.O. Box 519 Washington PA 15301 Information Phone: 412-223-5900 EMERGENCY PHONE CHEMTREC (800) 424-9300 This number is to be used onlyin the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals Prepared By : Lucy Sten

Product Safety Specialist

SECTION I - IDENTITY INFORMATION

TRADE NAME : 41388 TAN CAS NUMBER : Mixture PRODUCT CODE : SOF138800000 FAMILY/CHEMICAL NAME: Pigment and Silica Mixture. PRODUCT TYPE:



## ~ Clayware Stains. HAZARD STATEMENT: This Material Safety Data Sheet (MSDS) has been prepared in compliance with the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous substance under that standard. The key Immediate Hazards are: - Skin, eye and respiratory irritant.

SECTION II - HAZARDOUS INGREDIENTS This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of inetal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small 

# t 

# t_

~ 

# (Jq

### Page: 02 MATERIAL SAFETY DATA SHEET 41388 TAN (50F138800000) 

# l:

SECTION II - HAZARDOUS INGREDIENTS (cont.)
HAZARD STATEMENT: percentage of the starting materials may remain in this product 

## and are considered hazardous under OSHA. The pigment and/or frit ingredient(s) do not have exposure limit values. Exposure limit values for the components are listed beneath each ingredient as a guideline for safe use of these products. Ingredients CAS NUMBER ACGIH -.TLV OSHA - PEL C.I. PIGMENT BROWN 33 68186-88-9* Carcinogenicity: This product has not been reviewed for carcinogenicity by IARC, NTP or OSHA.

~ ALUMINA Dust As Al TWA 10.0 mg/M3 10.0 mg/M3 RESP 5.0 mg/M3 ZINC OXIDE Total Dust TWA 10.0 mg/M3 10.0 mg/M3 RESP 5.0 mg/M3 Fume TWA 5.0 mg/M3 5.0 mg/M3 STEL 10.0 mg/M3 10.0 mg/M3 IRON OXIDE Fume As Fe TWA 5.0 mg/M3 Total Particulate TWA 10.0 mg/M3 CHROMIUM (III) COMPOUND Cr (+3) TWA 0.5 mg/M3 0.5 mg/M3 CRYSTALLINE SILICA 14808-60-7 

## Carcinogenicity: This product is considered to be carcinogenic by IARC (Group 2A). CRYSTALLINE SILICA Dust RESP 0.1 mg/M3 0.1 mg/M3

IL

~~ ~

## Page: 03 MATERIAL SAFETY DATA SHEET 41388 TAN (50F138800000)

SECTION II - HAZARDOUS INGREDIENTS (cont.)
HAZARD STATEMENT:

SECTION III - PHYSICAL DATA
APPEARANCE : Tan Powder WEIGHT PER GALLON : N/AV BOILING RANGE : N/AP VOC : 0 0(See Note in Section XII - Addendum) VAPOR DENSITY : Non Volatile EVAPORATION RATE : Non Volatile SOLUBILITY IN WATER : Insoluble
SECTION IV - FIRE AND EXPLOSIVE HAZARD DATA
FI"SH POINT : N/AP FL )IMABILITY CLASS : NON-COMBUSTIBLE LOWER EXPLOSION LIMIT : N/AP UPPER EXPLOSION LIMIT : N/AP EXTINGUISHING MEDIA: Water.
FIRE FIGHTING PROCEDURES-SPECIAL: Fire-Fighters should wear self-contained breathing apparatus and full protective clothing when fighting chemical fires. Use water spray to cool nearby containers and structures exposed to fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: This product will not burn. Use appropriate-techniques to fight surrounding fire.

e

~~ v

### Page: 04 MATERIAL SAFETY DATA SHEET



## ~ 41388 TAN (50F138800000)

SECTION V - REACTIVITY DATA
STABILITY 

## Stable HAZARDOUS POLYMERIZATION 

## Will not occur CONDITIONS TO AVOID: None Known.
INCOMPATIBILITY: 

## None known.
HAZARDOUS DECOMPOSITION: Will not occur.

J ; SECTION VI

- 

### HEALTH HAZARD DATA 

## This product contains either pigment(s). that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of inetal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small percentage of the starting materials may remain in this product and are considered hazardous under OSHA.
PRIMARY ROUTES OF EXPOSURE: Inhalation, dermal and ingestion.

OVEREXPOSURE EFFECTS: CONTAINS ZINC OXIDE (as reacted into the frit/pigment): If processing can produce zinc oxide fumes, its inhalation may cause nausea, vomiting, fever, chills, metallic taste

~ 

## and muscle pain.

d 

# '-~ o

### Page: 05 MATERIAL SAFETY DATA SHEET 41388 TAN (50F138800000) 

## ~ SECTION VI - HEALTH HAZARD DATA (cont.)

OVEREXPOSURE EFFECTS:

CONTAINS CRYSTALLINE SILICA: 

## Crystalline silica can cause silicosis, a lung disease characterized , ..by coughing, wheezing, impaired lung function and increased,sputum production. This damage can be progressive and may cause death. May cause cancer following repeated and prolonged inhalation of the fine dust. Smoking aggravates these effects. Skin and eye contact may cause irritation due to mechanical abrasion. This product contains mixed metal oxide pigment(s) which consist of iron oxide, trivalent chromium and zinc oxide in combination with other materials.

~ I 

## CONTAINS IRON OXIDE (as reacted into the pigment):

Long-term inhalation of iron oxide dust may lead to siderosis or iron deposition in the 1ung. This is not considered to be a hazardous condition. CONTAINS CHROMIUM (III) COMPOUNDS: Compounds of chromium, in its trivalent state, have no established toxicity. When swallowed, it is not expected to cause local or systemic effects since it is poorly absorbed. No specific effects have been observed from inhalation. Skin contact has been reported to cause skin irritation but not ulceration. Allergic skin reactions may occur in sensitive individuals, although it is believed that the hexavalent (VI) form of chromium is responsible for most of the reported cases.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: } 

## Respiratory conditions.

0-

~ .~ ~

### Page: 06 MATERIAL SAFETY DATA SHEET 

# ~ 41388 TAN (50F138800000)

SECTION VI - HEALTH HAZARD DATA (cont.)

EMERGENCY AND FIRST AID PROCEDURES:

EYES: 

## For eye contact, immediately flush eyes for at least 1S minutes with running water. Hold eyelids apart to ensure rinsing of the entire eye surface and lids with water. Get immediate medical attention. SKIN For skin contact, wipe away excess material with dry towel. Then wash affected areas with plenty of water, and soap if available, for several minutes. Get medical attention if irritation occurs. INHALATION: 

## If inhaled, remove from area to fresh air. Get medical

y 

## attention if respiratory irritation develops or if breathing becomes difficult. INGESTION: 

## If swallowed, give at least 3-4 glasses of water, but do not induce vomiting. Do not give anything by mouth to an unconscious or convulsing person. Get medical attention. PHYSICIAN'S NOTE: 

## None specified.
SECTION VII - TOXICOLOGY INFORMATION Toxicology data of some components is available upon request. Please contact the Product Safety Specialist at (412) 223-5900.

~ 

### ~`t~

### Page: 07 MATERIAL SAFETY DATA SHEET 41388 TAN (50F138800000) 

# ~
SECTION VIII - SPILL OR LEAK PROCEDURES

SPILL PROCEDURES: 

## Wear appropriate protective equipment. Avoid the generation of dust. Vacuum or shovel material and place in closable container(s) for disposal. WASTE DISPOSAL METHODS: 

## Dispose in accordance with Federal, State and Local regulations.

SECTION IX - SPECIAL PROTECTION INFORMATION

VENTILATION: 

## Adequate ventilation should be provided to keep dust and vapor concentrations below acceptable Exposure Limits. Discharge from the ventilation system should comply with the applicable air P i ollution control regulations. Eliminate ignition sources.
PROTECTIVE GLOVES: Use gloves as a standard industrial handling procedure.

EYE PROTECTION: 

## Wear safety glasses or goggles to protect against exposure.

RESPIRATORY PROTECTION: 

## Appropriate respiratory protection is required when exposure to airborne contaminant is likely to exceed acceptable limits. Respirators should be selected and used in accordance with OSHA Subpart I(29 CFR 1910.134) and manufacturer's recommendations.

~

w



## _ ~~~

### Page: 08 MATERIAL SAFETY DATA SHEET 

# ~ 41388 TAN (50F138800000)

SECTION IX - SPECIAL PROTECTION INFORMATION (cont.)
OTHER PROTECTIVE EQUIPMENT: 

## None specified.

SECTION X - SPECIAL PRECAUTIONS
LABELING INFORMATION: WARNING! 

## Skin, eye and respiratory irritant. Contains crystalline silica which can cause lung damage, including cancer. Keep away from heat and flame. Avoid contact with eyes, skin and clothing. Do not breathe dust. Keep away from food products. } Wash thoroughly after handling and before eating, drinking or using cosmetic or tobacco products or toilet facilities. Use with adequate ventilation. Keep container closed when not in use. FIRST AID: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water. Remove contaminated clothing. Get medical attention. IN CASE OF FIRE: Use water, dry chemical or carbon dioxide. IN CASE OF SPILL: Vacuum and dispose in accordance with federal, state and local regulations. For industrial use only.

SECTION XI - REGULATORY INFORMATION
SARA 313 TITLE III - TOXIC CHEMICALS LIST: 98 9 6 - Zinc Compound 35% Metal As Zn 98o Chromium (3) Compound 8% Metal As Cr

C 

### ~ ~ /

## =age: 09 MATERIAL SAFETY DATA SHEET 41388 TAN (50F138800000) 

# ~ SECTION XI - REGULATORY INFORMATION (cont.)
PENNSYLVANIA RIGHT-TO-KNOW ACT: C.I. Pigment Brown 33 68186-88-9* S Quartz 14808-60-7 H S= Pennsylvania Special Hazardous Substance H = Pennsylvania Hazardous Substance TOXIC SUBSTANCE CONTROL ACT (TSCA): All ingredients in this product are listed on the U.S. EPA TSCA Inventory of Chemical Substances.
SECTION XII - ADDENDUM
DEFINITIONS AND ABBREVIATIONS :

The V.O.C., listed in Section III, Physical Data, is an estimated/calculated value based upon the EPA Method 24 for determining V.O.C. ACGIH = American Conference of Governmental Industrial Hygienists C(Ceil) = The concentration that shall not be exceeded during any part.of

the working exposure. CAS = Chemical Abstracts Service Registry Number EPA = Environmental Protection Agency IARC = International Agency for Research on Cancer LEL = Lower Explosion Limit N/AP = Not Applicable N/AV = Not Available NIOSH = National Institute for Occupational Safety and Health NTP = National Toxicology Program OSHA = Occupational Safety and Health Administration PEL = Permissible Exposure Limits :SARA = Superfund Amendments and Reauthorization Act STEL = Short Term Exposure Limit. Usually a 15 minute time weighted

1

~

~ 

# 6-2—

### ?age : 10 

### MATERIAL SAFETY DATA SHEET 41388 TAN (50F138800000) 7 

### SECTION XII - ADDENDUM (Cont.)



## average e:cposure that should not be exceeded at any time during a work day. TLV = Threshold Limit Values TSCA = Toxic Substance Control Act TWA = Time Weighted Average. Exposure concentration for a normal

8 hour work day and a 40 hour work week. VOC = Volatile Organic Content DISCLAIMER The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kin3 expressed or implied is made with respect to the information contained herein.

~

1~

~

-~~ 

# 5-3

### MATBRIAL SAF$TY DATA SHEBT MSDS No: 012-USM

IIATIMIN SPECIALTY MIN$RALS, INC. Emergency Telephone Number Route 127, P.O. Box 33 (618) 747-2338 Elco, IL 62929 Telephone Number for Information (618) 747-2338 

### Date Prepared: July 18, 1996

SBCTION 1: IDENTIFICATION 

## v IT(S O gE PRODUCT NAME: TAMSILO, IMSILO, and CERASIL° - various grades SYNONYMS: Microcrystalline Silica, Silicon Dioxide 

# --------- ----------------------------

~ 

# _-----
SgCTION 2• COMPONENTS CAS# Component Percentaqe Exposure Limits .

\ 

### 14808-60-7 Microcrystalline Silica (Quartz) 98.5-99t PEL - See Below TLV- 0.1 mg/m 3 TWA 

### (respirable fraction) MSHA - See Below

OSHA PEL and•MSHA Exposure Limit for Crystalline Silica (Respirable): 10 m 3 t Silica + 2 National Institute for Occupational Safety and Health (NIOSH) has recommended that 

### the permissible exposure limit be changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m 3 ) as determined by a full shift sample up to 10 hour working day, 40 hours per week. The 1974 NIOSH Criteria for a recommended Standard for Occupational Exposure to Crystalline Silica should be consulted for more detailed information. PEL means OSHA Permissible Exposure Limit. - TLV means American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value. MSHA means Mine Safety and Health Administration Exposure Limit. TWA means 8 hour time weighted average. Note: The Permissible Exposure Limits (PEL) reported above are the pre-1989 limits that were reinstated by OSHA June 30, 1993 following a decision by the llth Circuit Court of Appeals. These PELs are now being enforced by Federal OSHA. Be aware that more restrictive exposure limits may be enforced by some states, agencies or other authorities.

Page 1 of 7 Pages,, I

I MSDS No: 012-USM

SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW 

### This product is a chemically inert, non-combustible mineral. A single exposure will not result in serious adverse effects. Excessive inhalation of dust may cause lung disease, silicosis, with symptoms of shortness of breath and reduced pulmonary function. See "Cancer Status" in this Section 3.
HEAI,TH HAZARDS : 

### Inhalation: Breathing silica dust may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Silicosis: Excessive inhalation of.respirable crystalline silica dust may

cause a progressive, disabling and sometimes fatal lung disease called silicosis. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. This disease is exacerbated by smoking. Individuals with silicosis are predisposed to develop tuberculosis. / Cancer Status: The International Agency for Research on Cancer has determined that there is "sufficient evidence" for carcinogenicity of crystalline silica to experimental animals and "limited evidence" with respect to humans (Group 2A - probably carcinogenic to humans). The National

- Toxicology Program classifies respirable crystalline silica.as "reasonably anticipated to be a carcinogen". IARC will be convening during October 1996 to update its evaluation of crystalline silica. The updated information, when ultimately published, will appear in IARC Monograph 68, Silica, Some Silicates and Organic Fibres and must be consulted in conjunction with the use of these materials. Other Data with Possible Relevance to Human Health:

There is some evidence that breathing respirable crystalline,_ silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Inhalation of dust may cause irritation of the nose, throat and respiratory passages. Skin Contact: No adverse effects expected. _Eye Contact: Contact may cause mechanical irritation and possible injury. y



### Page 2 of 7 Pages 

## .~ ~5

### i I '

I MSDS No: 012-USM Ingestion:

### No adverse effects expected for normal, incidental ingestion. Chronic Health Effects.: 

### See °Inhalation" subsection above with respect to silicosis, cancer status and other data with possible relevance to human health. Medical Conditions Agggravated by Exposure: 

### Individuals with respiratory disease, including but not limited to, asthma and bronchitis, or subject to eye irritation should not be exposed to respirable quartz dust. SicTns and Symptoms of Exposure: 

### There are generally no signs or symptoms of exposure to crystalline silica (quartz). See "Inhalation" subsection above for symptoms of silicosis.

SECTION 4: FIRST AID Gross Inhalation: 

### Remove victim to fresh air. If breathing has stopped, perform artificial respiration. If breathing is difficult have qualified personnel administer oxygen. Get prompt medical attention. Skin Contact: 

### No first aid should be needed since-this product does not affect the skin. Wash exposed skiri with soap and water before breaks and at the end of the shift.

) ,,

~ 

### ye Contact: 

### Flush the eyes immediately with large amounts of running water, lifting the upper and lower lids occasionally. If irritation persists or for imbedded foreign body, get immediate medical attention. Ingestion:

### If large amounts are swallowed, get immediate medical attention.

SECTION 5: FIRE AND EXPLOSION DATA Flash Point (Method Used): 

### Fully oxidized, will not burn. Autoignition Temp: 

### Will not burn. Flammable Limits: LEL: 

### Not applicable UEL: 

### Not applicable Extinguishing Media: 

### This pioduct will not burn but is compatible with all '- extinguishing media. Use any media that is appropriate for the surrounding fire. Special Fire Fighting Procedures: 

### None required with respect to this product. Firefighters should always wear self-contained breathing apparatus for fires indoors or in confined areas. Unusual Fire and Explosion Hazards: 

### None. Hazardous Combustion Products: 

### None.

Page 3 of 7 Pages"



## ~~~

### MSDS No: 012-USM

SECTION 6: ACCIDENTAL RELEASE MEASIIREs Wear appropriate protective equipment. If uncontaminated, collect using dustless method (HEPA vacuum or wet method) and place in appropriate container for use. If contaminated: a) use appropriate method for the nature of contamination, b) consider possible toxic or fire hazards associated with the contaminating substances. Collect 

### for disposal.

SECTION 7: HANDLING AND STORAGE 

### Do not breathe dust. Do not rely on your sight to determine if dust is in the air. Silica may be in the air without a visible dust cloud. Use normal precautions against bag breakage or spills of bulk material. Avoid creation of respirable dust. Use good housekeeping in storage and use areas to prevent accumulation of dust in work area. Use adequate ventilation and dust collection. Maintain and use proper, clean respiratory equipment (See Section 8). Launder clothing that has become dusty. WARN and TRAIN employees in accordance with state and federal regulations. WARN YOUR EMPLOYEES-(AND YOUR CUSTOMERS - USERS IN CASE OF RESALE). BY POSTING AND OTHER MEANS OF THE HAZARDS AND OSHA PRECAUTIONS TO BE USED. PROVIDE TRAINING FOR YOUR EMPLOYEES ABOUT OSHA PRECAUTIONS.
SECTION 8: EXPOSIIRE CONTROLS/PERSONAL PFtOTECTION .. 

### Ventilation:•Use local exhaust as required to maintain exposures below applicable occupational exposure limits. See also ACGIH "Industrial Ventilation - A Manual for Recommended Practice", (current edition). Respiratory Protection: Use appropriate respiratory protection for respirable particulates based on consideration of airborne workplace concentrations and duration of exposure. Refer to the most recent standards of ANSI (Z88.2) OSHA (29 CFR 1910.134), MSHA (30 CFR Parts 56 and 57) and NIOSH Respirator Decision Logic. Gloves: Protective gloves recommended. Eye Protection: Safety glasses or goggles recommended. Other Protective Equipment/Clothing: As appropriate for the work environment. Dusty clothing should be laundered before reuse.

9: PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odor: White crystals, odorless.



## ~ H. Not applicable Specific Gravity (water=l): 2.65 'doiling Point: 4046°F / 2230°C Vapor Pressure: Not applicable Melting Point: 2930°F / 1610°C Vapor Density: Not applicable

. , ;


# c

Page 4 of 7 Pages


### ~5 ~'} I . . _



### I MSDS No: 012-USM Solubility in Water: Negligible Evaporation Rate: Not applicable Percent Volatile: 0$

SECTION 10: STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: None 

### Incompatibility: Powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese tr.ioxide, etc. Hazardous Decomposition Products: Silica will dissolve in hydrofluoric acid producing.a corrosive gas, silicon tetrafluoride. Hazardous Polymerization: Will not occur. Conditions to Avoid: None 

# ______________________________________________________________ SECTION 11: TOXICOLOGICAL INFORMATION 

### No acute toxicity data is available for product or components. Refer to Section 3 for health hazard information.

SECTION 12: ECOLOGICAL INFORMATION 

### No ecotoxicity data

- is available. This product is not expected to present an environmental hazard.

SECTION 13: DISPOSAL 

### waste Disposal Method: If uncontaminated, dispose as an inert, non-metallic mineral. If contaminated, dispose in accordance with all applicable local, state/provincial and federal regulations.

SECTION 14: TRANSPORTATION DATA U.S. DOT HAZARD CLASSIFICATION Proper Shipping Name: Not Regulated Technical Name: N/A UN Number: N/A Hazard Class/Packing Group: N/A 

### Labels Reguired: None DOT Packaging Requirements:_ N/A Exceptions• N/A

Page 5 of 7 Pages ~ 

# x

0 ~.... .., ~ 

# r MSDS No: 012-USM

SECTION 15: OTHER REGIILATORY INFORMATION SARA 311/312: 

### Hazard Categories for SARA Section 311/312 Reporting: 

### Chronic Health SARA 313 

### This Product Contains the Following Chemicals Subject to Annual Release Reporting Requirements Under the SARA Section 313 (40 CFR 372): None CERCLA Section 103 Reportable Quantity: 

### None California Proposition 65: 

### This Product contains the following substances known to the State of California to cause cancer and/or reproductive harm: This product contains crystalline silica (respirable). Toxic Substances Control Act: 

### A11 of the components of this product are listed on the EPA TSCA Inventory or exempt from notification requirements. European Inventory of Commercial Chemical Substances: 

### A11 of the components of this product.are listed on the EINECS Inventory or exempt from notification requirements. (The EINECS number for Quartz: 231=545-4) Canadian Environmental Protection Act: 

### A11 the components of this product are listed on the Canadian Domestic Substances List or exempt from notification requirements. Japan MITI: 

### A11 of the components of this product

- are existing chemical substances as defined in the Chemical Substance Control Law. Australian Inventory of Chemical Substances: 

### A11 of the components of this product are listed on the AICS inventory or exempt-from notification requirements. Canadian WEIIMIS Classification: 

### Class D, Division 2, Subdivision A(Very Toxic Material causing other Toxic Effects)

16: OTHER INFORMATION European Community Labeling Classification: 

### Harmful (Xn) European Community Risk and Safety Phrases: 

### R40, R48, S22 NFPA Hazard Ratinq: 

### Health: 1 Fire: 0 Reactivity: 0 HMIS Hazard Ratinq: 

### Health: * Fire: 0 Reactivity: 0 * Warning - Chronic health effect possible - inhalation of silica dust may cause lung injury/disease (silicosis). Take appropriate measures to avoid breathing dust. See Section 3. 't References:



### Registry for Toxic Effects of Chemical Substances (RTECS), 1995 Patty's Industrial Hygiene and Toxicology NTP Seventh Annual Report on Carcinogens, 1994
_ IARC Monograph Volume 42, Silica and some Silica

- Ees, 1987 Page 6 of 7 Pages 

# ~~N .D S" •



## ~ MSDS No: 012-USM
Revision Summary: Revise Cancer Status (Section 3). 

### CREATION DATE: October 23, 1995 REVISION DATE: July 18, 1996 

### The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. The information set forth herein is based on technical data the Unimin Corporation believes reliable. It is intended for use by persons having technical skill and at their own discretion and risk. Since conditions of use are outside the control of Unimin Corporation, no warranties, expressed or implied, are made and no liability is assumed in connection with any use of this information. Any use of these data and information must be determined by the user to be in accordance with federal, state and local laws and regulations.

.



### Page 7 of 7 Pages c z & 

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