Baselines and Complaints

Toxic Compounds Baselines

Place of concern Frenchtown Badminton Saddlebrook Furst Compressor Blessing Unit

Sample date 3/16/2010 6/18/2010 2/3/2010 6/2/2010

ACL number (all ppb) ACL 100202 ACL 100625

Sample location 165 ft N/NE 6 ft NW

Detect ND Detect ND Detect ND Detect ND Detect ND

Number of detects/ND 7 78 10 74 10 74 36 48 23 62

Methane 2.3 2.6 2.7

ethane 0 0 0 130 100

ethylene 0 0 0 0.93 0

acetylene 0 0 0 0.79 0

propane 0 0 0 9.2 5.7

propylene 0 0 0 0 0

dichlorodifluoromethane 0 0.491 0.33 0.57 0.51

methyl chloride 0.62 0.714 0.65 0.58 0.65

isobutane 6.22 0 0 1.1 0.57

vinyl chloride 0 0 0 0 0

1-butene 0 0 0 0.15 0.39

1,3-butadiene 0 0 0 0 0

n-butane 0 0 0 1.7 0.81

t-2-butene 0 0 0 0 0

bromomethane 0 0 0 0.02 0

c-2-butene 0 0 0 0 0

3-methyl-1-butene 0 0 0 0 0

isopentane 0 0 0 0.58 0.57

trichlorofluoromethane 0 0 0 0.25 0.25

1-pentene 0 0 0 0 0

n-pentane 0 0 0 0.38 0.36

isoprene 0 0 0 0 0

t-2-pentene 0 0 0 0 2

1,1-dichloroethylene 0 0 0 0 0

c-2-pentene 0 0 0 0 0

methylene chloride 0 0 0 0.09 0.1
Baselines and Complaints

2-methyl-2-butene 0 0 0 0 0

2,2-dimethylebutane 0 0 0 0 0

cyclopentene 0 0 0 0 0

4-methyl-1-pentene 0 0 0 0 0

1,1-dichloroethane 0 0 0 0 0

cyclopentane 0 0 0 0 0

2,3-dimethylbutane 0 0 0 0 0

2-methylpentane 0 0 0 0.11 0.09

3-methylpentane 0 0 0 0.07 0.06

2-methyl-1-pentene+1-hexene 0 0 0 0 0

n-hexane 0 0 0 0.15 0

chloroform 0 0 0 0.01 0.02

t-2-hexene 0 0 0 0 0

c-2-hexene 0 0 0 0 0

1,2-dichloroethane 0 0 0 0 0

methylcyclopentane 0 0 0 0.06 0

2,4-dimethylpentane 0 0 0 0 0

1,1,1-tricholorethane 0 0 0 0 0

benzene 0.65 1 2.27 0.27 0.16

carbon tetrachloride 0 0 0 0.13 0.1

cyclohexane 0 0 0 0.24 0

2-methylhexane 0 0 0 0.27 0

2,3 dimethylpentane 0 0 0 0.26 0

3-methylhexane 0 0 0 0.06 0.04

1,2-dichloropropane 0 0 0 0 0

trichloroethylene 0 0 0 0 0

2,2,4-trimethylpentane 0 0 0 0.05 0.03

2-chloropentane 0 0 0 0 0

n-heptane 0 0 0 0.04 0.05

c-1,3-dichloropropylene 0 0 0 0 0

methylcyclohexane 0 0 0 0.03 0

t-1,3-dichloropropylene 0 0 0 0 0

1,1,2-trichloroethane 0 0 0 0 0

2,3,4-trimethylpentane 0 0 0 0.02 0
Baselines and Complaints

toluene 1.16 5.3 10.8 0.23 0.22

2-methylheptane 0 0 0 0.01 0

3-methylheptane 0 0 0 0 0

1,2-dibromoethane 0 0 0 0 0

n-octane 0 0 0 0 0

tetrachloroethylene 0 0 0 0.02 0

chlorobenzene 0 0 0 0 0

ethylbenzene 0 1.84 3.93 0.02 0

m & p-xylene 1.17 8.52 21.7 0.05 0.17

styrene 0 2.98 4.96 0 0

1,1,2,2-tetrachloroethane 0 0 0 0 0

o-xylene 0 3.12 6.13 0.02 0

n-nonane 0 0 0 0 0

isopropylbenzene 0 0 0 0 0

n-propylbenzene 0 0 0 0 0

m-ethyltoluene 0 0 0 0 0

p-ethyltoluene 0 0 0 0 0

1,3,5-trimethylbenzene 1.03 2.54 5.3 0 0

o-ethyltoluene 0 0 0 0 0

1,2,4-trimethylbenzene 0 1.09 2.3 0 0

n-decane 0 0 0 0 0

1,2,3-trimethylbenzene 0 0 0 0 0

m-diethylbenzene 0 0 0 0 0

p-diethylbenzene 0 0 0 0 0

n-undecane 0 0 0 0.04 0.24 0

1,2,4-trichlorobenzene 0.83

Crude total (ppb) 11.68 27.595 58.37 148.5 113.09

ND

TICs ND

C8 hydrocarbon ND 3.7 ND

C3 hydrocarbon 24.5 ND ND

carbon disulfide 6.3 ND 19
Baselines and Complaints

dimethyl disulfide 21.7 14.4 6.66

diethyl disulfide 2.95 ND 8.82

methyl ethyl disulfide ND 4.1 ND

methylene disulfide 13 ND ND

dimethyl trisulfide 16.6 26.4 ND

diethyl disulfide 2.95 ND ND

unidentified sulfur group 23.4 32 ND

diethyl trisulfide 4.24 3.3 ND

limonene ND 8.1 ND

C10 hydrocarbon ND 13.1 ND

C11 hydrocarbon ND 6.9 67.1

c12 hydrocarbon 32.6 15.2 13

55.2

148.24 127.2 17.7

169.78
Baselines and Complaints

Complaints

Marsden 1 WellWalling Compressor Blessing Unit Fuller Family Unit Blessing Unit Argyle Central Argyle Central

7/30/2010 8/13/2010 8/19/2010 8/20/2010 9/15/2010 10/4/2010 10/7/2010

ACL 100812 ACL 100912 ACL 100827 ACL 100833 ACL 100942 ACL 101017 ACL 101031

33.5 NE wellhead Knoll's home 1096 ft. N 50 ft. downwind Sizelove House Sizelove's house Wolfe's House

Detect ND Detect ND Detect ND Detect ND Detect ND Detect ND Detect

29 55 37 47 32 52 32 58 28 56 32 0 46

12 1.7 32 57 4.2 1.5 19

0.76 0.45 0.55 0.66 0.53 0.39 2

0 0 0.25 0 0.33 0.24 0.79

2.8 0.56 14 2.9 2.1 0.63 0.61

0 0 0 0 0

0.59 0.49 0.6 0.54 0.53 0.53 0.55

0.93 1.1 0.69 1.3 0.78 0.71 0.42

0.87 0.14 0.33 0.28 0.17 0.41 1.3

0 0 0 0 0

0.41 0.27 0.27 0.24 0.19 0.27 0.2

0 0 0 0 0

1.3 0.2 0.49 0.62 0.19 0.31 1.2

0 0 0 0 0

0 0 0.02 0 0.01

0 0 0 0 0

0 0 0 0 0

0.47 0.16 0.37 0.22 0.17 0.26 1.7

0.35 0.29 0.29 0.27 0.26 0.24 0.28

0 0 0 0 0

0.44 0 0.25 0 0 0.16 0.56

1.7 2.2 0.15 3.1 1.8 0.09

0 0 0 0 0 0.12

0.05 0.02 0 0.02 0 0.02

0 0 0 0 0

0.09 0 0.06 0.07 0.05 0.09 0.12
Baselines and Complaints

0 0 0 0 0 0.2

0 0 0 0 0

0 0 0 0 0 0.08

0 0 0 0 0

0 0 0 0 0

0 0 0 0 0

0 0 0 0 0 0.17

0.12 0.04 0.14 0.06 0 0.05 0.57

0 0 0.1 0.05 0.02 0.04 0.49

0 0 0 0 0 0.06

0.15 0 0 0 0 0.05 0.54

0.02 0.02 0.04 0.14 0.02 0.02 0.05

0 0 0 0.01 0

0 0 0 0 0

0 0 0 0 0

0.03 0 0 0 0 0.02 0.35

0 0 0 0 0 0.11

0 0 0 0 0

0.12 0.12 0.14 0.11 0.14 0.1 0.43

0.07 0.11 0.09 0.09 0.11 0.05 0.12

0 0 0 0 0 0.18

0 0 0.04 0 0.03 0.39

0 0 0 0 0 0.01 0.2

0.05 0 0.05 0.04 0 0 0.03 0.4

0 0 0 0 0

0 0 0 0 0

0 0 0.12 0.05 0 0.05 0.04 1.1

0 0 0 0 0

0.08 0 0.07 0.13 0 0 0.02 0.31

0 0 0 0 0

0 0 0 0 0 0.24

0 0 0 0 0

0 0 0 0 0

0.01 0.03 0.05 0.04 0 0.02 0.49
Baselines and Complaints

0.29 0.2 0.33 0.14 0 0.16 0.2 0.9

0 0 0.02 0 0.02 0.1

0.02 0.02 0 0.07 0 0 0.1

0 0 0 0 0

0.05 0.08 0 0.14 0 0.01 0.12

0 0.02 0 0 0 0.01 0.06

0 0 0 0 0

0.05 0.09 0.05 0 0.05 0.03 0.19

0.13 0.16 0.11 0.1 0.1 0.06 0.44

0 0 0 0 0

0 0 0 0 0

0.04 0.05 0.03 0.02 0.03 0.02 0.12

0 0.14 0 0.32 0

0 0.07 0 0 0.04

0 0.13 0 0.14 0

0 0.09 0 0 0 0.08

0 0.07 0.01 0 0.01 0.02

0 0.06 0.01 0 0 0.02

0 0.08 0 0 0

0 0.13 0 0 0 0.13

0 0.22 0 0.36 0

0 0.11 0 0 0

0 0.2 0 0 0

0 0.18 0 0 0

0 0.49 0 0.07 0

23.99 10.49 51.72 69.3 12.11 6.61 37.61
Baselines and Complaints
Baselines and Complaints

mplaints

Argyle Central Hillwood Jenkins 1H Hillwood Jenkins 1H Hillwood Jenkins 1H Hillwood Jenkins 1H Ginger Hackel

10/7/2010 10/9/2010 10/13/2010 10/7/2010 10/18/2010 10/15/2010

ACL 101031 ACL 101032 ACL 101034 ACL 101035 ACL 101052 ACL 101047

Wolfe's House At facility 500 ft. SE 3396 ft. SE (H.S. parking lot) Old Justin Road

ND Detect ND Detect ND Detect ND Detect ND Detect

38 37 47 36 48 65 19 33 51 35

3.7 20 55 4.8 21

1.7 0.48 3.7 1.4 2.7

0 0 1.7 0.53

2.5 19 13 1.6 6.2

0 0 0 1 0.31 0.71

0.53 0.67 0.7 0.5 0.55

0.49 0.71 0.88 0.53 0.47

9.6 3.3 2.9 0.23 0.71

0 0 0 0.06 0

0.25 0.22 0.62 0.23 0.39

0 0 0 0 0.04

1.8 7.9 4.5 0.42 2.1

0 0 0 0 0

0 0 0 0 0

0 0 0 0.08 0

0 0 0 0.03 0

1.5 1.8 3 0.25 0.86

0.26 0.3 0.32 0.25 0.27

0 0 0 0 0

0.37 1.7 1.8 0 0.3

0 0 0.02 0.09 0.1

0 0 0.08 0

0 0 0.03 0.03 0

0 0 0 0.05 0

0.06 0.06 0.19 0.04 0.04
Baselines and Complaints

0 0 0.09 0

0 0 0.02 0.06 0

0 0.1 0.09 0

0 0 0 0 0

0 0 0 0 0

0 0 0 0 0

0 0.05 0.18 0

0.17 0.34 0.52 0.07 0.14

0.14 0.22 0.37 0.06 0.13

0.02 0 0.04 0.02 0.03

0 0.48 0.42 0

0.02 0.02 0.07 0.02 0.02

0 0 0 0 0

0 0 0 0 0

0 0 0 0.08 0

0.08 0.19 0.18 0 0.08

0 0 0.09 0

0 0 0 0 0

0.22 0.18 0.54 0.18 0.25

0.12 0.1 0.11 0.12 0.12

0 0.15 0.11 0

0.11 0 0 0.05 0.08

0 0.04 0.14 0 0.04

0.09 0.14 0.28 0.05 0.09

0 0 0 0 0

0 0 0 0.04 0

0.21 0 0.66 0.08 0.17

0 0 0 0 0

0.1 0.21 0.22 0.08 0.11

0 0 0 0 0

0.07 0 0 0

0 0 0 0 0

0 0 0 0.02 0

0.14 0 0.19 0.03 0.14
Baselines and Complaints

0.32 0.18 1.3 0.28 0.46

0.03 0.06 0.1 0.02 0.04

0 0.03 0.07 0

0 0 0 0 0

0 0.09 0.12 0

0.04 0 0.07 0

0 0 0 0 0

0.07 0.03 0.16 0.05 0.09

0.16 0.08 0.45 0.11 0.22

0 0 0 0.08 0

0 0 0 0 0

0.05 0.02 0.15 0.03 0.05

0 0 0.04 0.16 0.03

0 0 0 0.02 0

0 0 0 0.05 0

0.07 0 0.14 0

0.02 0 0.06 0.02 0.05

0.02 0 0.07 0 0.01

0 0 0 0.06 0

0.13 0 0.22 0 0.05

0 0.1 0 0.24 0

0 0 0 0.06 0 0.01

0 0 0 0.01 0

0 0 0 0.08 0

0 0.16 0 0.12 0

25.42 58.96 98.02 12.53 38.68
Baselines and Complaints
Baselines and Complaints

Ginger Hackel Argyle Central Hillwood Jenkins 1HHillwood Jenkins 1HHillwood Jenkins 1H

10/15/2010 10/15/2010 10/29/2010 10/29/2010 11/10/2010

ACL 101047 ACL 101046 ACL 101110 ACL 101111 ACL 101052

Old Justin Rd (Up)Old Justin Rd (Down) Old Justin Road

ND Detect ND Detect ND Detect ND Detect ND

49 39 45 32 52 37 47 44 40

Sum of Individual compounds

46 2.9 16 4.4 531.2

1.4 0.5 0.69 0.73 19.57

0 0.46 0.38 0.34 0.32 6.13

9.5 1.7 5.2 1.7 98.9

0.38 0 0 0 2.4

0.5 0.56 0.56 0.51 10.811

0.44 0.62 0.64 0.64 14.564

0.75 0.33 1.1 0.45 30.76

0 0 0 0 0 0.06

0.32 0.17 0.14 0.21 4.94

0 0 0 0 0 0.04

1.8 0.9 1.3 0.95 28.49

0 0 0 0 0 0

0 0 0 0 0 0.05

0 0 0 0 0 0.08

0 0 0 0 0 0.03

0.85 0.34 0.63 0.41 14.14

0.25 0.29 0.27 0.28 4.97

0 0 0 0 0 0

0.33 0 0.44 0 7.09

0 0 0.1 0.15 0.06 9.56

0 0 0 0 0 2.2

0 0 0.03 0 0.03 0.23

0 0 0 0 0 0.05

0.05 0.07 0.06 0.08 1.32
Baselines and Complaints

0 0 0 0 0 0.29

0 0 0.01 0.02 0 0.11

0 0 0 0 0 0.27

0 0 0 0 0 0

0 0 0 0 0 0

0 0 0 0.04 0 0.04

0 0 0 0.04 0.03 0.47

0.17 0.08 0.16 0.1 2.93

0.15 0.05 0.11 0.08 2.14

0.03 0 0 0 0.2

0 0 0.1 0.21 0.11 2.21

0.02 0.02 0.02 0.01 0.56

0 0 0 0 0 0.01

0 0 0 0 0 0

0 0 0 0 0 0.08

0.09 0.04 0.08 0.07 1.27

0 0 0 0 0 0.2

0 0 0 0 0 0

0.3 0.14 0.16 0.16 7.64

0.12 0.08 0.1 0.11 1.85

0 0 0 0 0 0.68

0.13 0 0 0 1.1

0.04 0 0.03 0.02 0.78

0.13 0.05 0.07 0.07 1.64

0 0 0 0 0 0

0 0 0 0.01 0 0.05

0.23 0.05 0.06 0.07 2.97

0 0 0 0 0 0

0.15 0.04 0.09 0.06 1.76

0 0 0 0 0 0

0 0.14 0 0 0 0.48

0 0 0 0 0 0

0 0 0 0 0 0.02

0.15 0.02 0.02 0.03 1.38
Baselines and Complaints

0.9 0.21 0.24 0.29 24.11

0.05 0 0 0 0.45

0 0 0 0.01 0.02 0.34

0 0 0 0 0 0

0 0 0.03 0.05 0.07 0.76

0 0 0.02 0.02 0.02 0.28

0 0 0 0 0 0

0.12 0.04 0.05 0.12 6.98

0.3 0.1 0.11 0.3 34.54

0 0 0 0 0 8.02

0 0 0 0 0 0

0.08 0.03 0.03 0.11 10.13

0 0.11 0 0 0.27 1.07

0 0 0 0 0 0.13

0 0 0 0 0.07 0.39

0 0.06 0 0 0.21 0.65

0.02 0 0 0.07 0.35

0.02 0 0 0.1 9.18

0 0 0 0 0.09 0.23

0.1 0 0 0.49 4.64

0 0 0 0 0.76 1.68

0 0 0 0.19 0.37

0 0 0 0 0 0.21

0 0 0 0 0 0.26

0 0.08 0 0 1.2 2.4

0

0.83

0

66.72 10 29.25 16.07 926.715

0

0

3.7

24.5

25.3
Baselines and Complaints

42.76

11.77

4.1

13

43

2.95

55.4

7.54

8.1

13.1

74

60.8

55.2

293.14

169.78