### TS-EMLA40 

### Attachment #1 Material Safety Data Sheets

# MATERIAL SAFETY DATA SHEET

Date Issued: 02/11/2008 MSDS No: Date Revised: 11/22/2010 Revision No: 8

1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: GENERAL USE: Liquid anti-strip PRODUCT DESCRIPTION: Modified Fatty Amidoamine PRODUCT CODE: CHEMICAL FAMILY: Amines MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
Emergency Contact: Product Stewardship: Alternate Emergency Phone: CANUTEC (Canadian Transportation) : (613) 996-6666 CHEMTREC (US Transportation) : (800) 424-9300

2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW PHYSICAL APPEARANCE: Dark liquid IMMEDIATE CONCERNS: This product can cause severe burns to the eyes, skin, mouth and throat. Developmental hazards/birth defects and negative reproductive effects have been noted in laboratory animal tests using pure aminoethylethanolamine (AEEA). Avoid oral and dermal contact. Exposure to AEEA should be minimized, especially for female employees. A No Effect Level (NOEL) has not been determined for AEEA. All components of this product are considered hazardous as defined by OSHA 29 CFR 1910.1200. See Section 8 for Exposure Guidelines and Section 16 for Other Information. POTENTIAL HEALTH EFFECTS EYES: Substance causes severe eye irritation. Injury may be permanent. SKIN: Prolonged or repeated contact may cause skin irritation. SKIN ABSORPTION: May be absorbed through the skin in harmful amounts. INGESTION: Harmful when swallowed. May cause burns to the digestive system. INHALATION: Irritation of the respiratory system may occur. SIGNS AND SYMPTOMS OF OVEREXPOSURE EYES: Causes eye irritation. SKIN: Prolonged contact may cause irritation. INHALATION: Prolonged or excessive inhalation will cause respiratory tract irritation. CHRONIC EFFECTS: Avoid contact with eyes; may cause redness, irritation and conjunctivitis. CARCINOGENICITY: No evidence of potential carcinogenicity. MUTAGENICITY: Not determined. REPRODUCTIVE TOXICITY REPRODUCTIVE EFFECTS: Not determined. Page 1 of 7TERATOGENIC EFFECTS: Refer to Section 11 for specific information.

ROUTES OF ENTRY: Eyes, skin, lungs or gastrointestinal. SENSITIZATION: May cause allergic skin reaction. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Wt.% CAS EINECS Classification Modified Fatty Amidoamine > 90 Proprietary Proprietary Aminoethylethanolamine (AEEA)* > 1 111-41-1 203-867-5 Xi, N; R20/21/22, R41, R43, R61 ( Full text of R-Phrases can be found under heading 16 ) 4. FIRST AID MEASURES EYES: Flush eyes with water for 15 minutes. Get medical attention. SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if rash developes. Wash contaminated clothing before reuse. INGESTION: Get medical attention immediately. Do not induce vomiting. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: > (300°F) Pensky-Martens CC EXTINGUISHING MEDIA: CO2, foam, or dry chemical. HAZARDOUS COMBUSTION PRODUCTS: CO, CO2, NOx, and other thermal decomposition byproducts. EXPLOSION HAZARDS: None. FIRE FIGHTING PROCEDURES: As in any fire, wear self-contained breathing apparatus pressuredemand, (MSHA/NIOSH approved or equivalent) and full protective gear. HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO 2 , NO x , and other thermal decomposition byproducts. 6. ACCIDENTAL RELEASE MEASURES GENERAL PROCEDURES: IN CASE OF SPILLS: No action shall be taken involving personal risk without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering spill area. Do not touch or walk through material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate Personal Protective Equipment (PPE). Dike area to contain spill. Take precautions as necessary to prevent contamination of ground and surface waters. Absorb with materials such as: Clay. Dirt. Milsorb. Sand. Do NOT use absorbent materials such as: Cellulose. Sawdust. After all visible traces, including ignitible vapors, have been removed thoroughly wet vacuum the area. Do not flush to sewer. If area of spill is porous, remove as much contaminated earth and gravel, etc. as necessary and place in closed containers for disposal. Collect any wash water for disposal. Dispose of according to local, state and federal regulations. Advise authorities if material has entered or may enter waterways or sewer drains. COMMENTS: Waste disposal: Incinerate or bury in certified landfill according to federal, state and local regulations. Page 2 of 77. HANDLING AND STORAGE

HANDLING: Avoid eye and skin contact. Avoid breathing vapors or mists of this material. Use only with adequate ventilation. Keep away from heat, sparks or open flame. After emptied, drum may retain solid, liquid and/or vapor residues. Wash thoroughly after handling. STORAGE: Avoid extreme heat conditions. If the additive becomes frozen, apply heat gradually to avoid localized overheating near heat transfer surfaces. Apply heat until desired temperature and/or viscosity is achieved. Gentle agitation or stirring is recommended to ensure additive homogeneity. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Use chemical splash goggles and face shield (ANSI Z87.1 or approved equivalent). SKIN: Impervious rubber or plastic. RESPIRATORY: A respiratory protection program that meets 29 CFR & OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. PROTECTIVE CLOTHING: Work clothing sufficient to prevent all skin contact should be worn, such as coveralls and long sleeves. Ensure compliance with OSHA's personal protective equipment (PPE) standard, 29 CFR 1910.132 (general) and 138 (hand protection). OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Liquid ODOR: Mild. APPEARANCE: Dark brown liquid. COLOR: Dark brown. VAPOR PRESSURE: < 1 mmHg at 25°C VAPOR DENSITY: > 1 (Air=1) BOILING POINT: > 260°C FLASHPOINT AND METHOD: > (300°F) Pensky-Martens CC SOLUBILITY IN WATER: Slight SPECIFIC GRAVITY: 1.06 - 1.10 @ 77 ° F VISCOSITY: Not determined 10. STABILITY AND REACTIVITY STABILITY: Stable. POLYMERIZATION: None CONDITIONS TO AVOID: Oxidizing materials. POSSIBILITY OF HAZARDOUS REACTIONS: None HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2, NOx and other thermal decomposition byproducts. INCOMPATIBLE MATERIALS: Strong oxidizers and materials that will react with amine products. 11. TOXICOLOGICAL INFORMATION ACUTE Page 3 of 7Chemical Name ORAL LD 50 (rat) INHALATION

LC 50 (rat) Aminoethylethanolamine (AEEA)* 2000 to 4000 mg/kg (rat) 3266 mg/kg

(rabbit) INHALATION LC 50 : Not Established EYE EFFECTS: Risk of serious damage to eyes. SKIN EFFECTS: Prolonged contact may cause irritation. CHRONIC: Not Established IRRITATION: Prolonged contact may cause irritation. CORROSIVITY: Not Established NEUROTOXICITY: Not Established REPRODUCTIVE EFFECTS: Not Established TARGET ORGANS: Not Established TERATOGENIC EFFECTS: Studies have shown teratogenetic effects for rats specific to Aminoethylethanolamine (AEEA) only. MUTAGENICITY: Not Established COMMENTS:



### THE FOLLOWING IS SPECIFIC FOR AEEA ONLY: Sensitization Skin Skin contact may cause an allergic skin reaction. Individuals who have had an allergic skin reaction to similar materials may have an allergic reaction to this product. The similar materials(s) is/are: Triethylenetetramine (TETA). Has caused allergic skin reactions when tested in mice. Has caused allergic reactions when tested in guinea pigs. Repeated Dose Toxicity Avoid all oral and dermal contact. In animals, effects have been reported on the following organs: gastrointestinal tract, kidney and fetal development. Repeated skin application to laboratory animals did not produce systemic toxicity. Developmental Toxicity Avoid all oral and dermal contact. Has caused birth defects in laboratory animals. Reproductive Toxicity Avoid all oral and dermal contact. Has been toxic to the fetus in laboratory animal tests. Genetic Toxicity In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative. Oral LD50 (rat) - 2000 to 4000 mg/kg Dermal LD50 (rabbit) - 3266 mg/kg 12. ECOLOGICAL INFORMATION ENVIRONMENTAL DATA: Do not flush to sewer or to allow entry into any waterways. BIOACCUMULATION/ACCUMULATION: Not determined Page 4 of 7AQUATIC TOXICITY (ACUTE): 96h LC50 (fatheads minnows) - 1 mg/L < LC50 < 10 mg/L

COMMENTS:



### THE FOLLOWING IS SPECIFIC FOR AEEA ONLY: CHEMICAL FATE Movement & Partitioning Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for mobility in soil is very high (Koc between 0 and 50). Given its very low Henry's constant, volitilzation from natural bodies of water or moist soil is not expected to be an important fate process. Henry's Law Constant (H): 8.8E-10 atm*m3/mole; 25°C Estimated. Partition coefficient, n-octanol/water (log Pow) ; -1.346 Measured. Partition coefficient, soil organic carbon/water (Koc) ; 3.5 Estimated. Persistence and Degradability Material is readily biodegradable. Passes OECD test(s) for biodegradablity. Indirect Photodegradation with OH Radicals Rate Constant: 1.20E-10 cm3/s Atmospheric Half-life: 1.1 h Method: Estimated OECD Biodegradation Tests: Biodegradation: >97% Exposure Time: 28d Method: OECD 301F Test Biological oxygen demand (BOD) BOD 5: 2% BOD 10: 64% BOD 20: 90% Theoretical Oxygen Demand: 2.77 mg/mg ECOTOXICITY Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 mg/L in the most sensitive species tested). Fish acute & Prolonged Toxicity LC50, fathead minnow (Pimephales promelas), 96 h: 520 - 628 mg/L Aquatic Invertebrate Acute Toxicity EC50, water flea (Daphnia magna), 48 h, immobilization: 65 mg/L Aquatic Plant Toxicity EC50, alga Scenedesmus sp., biomass growth inhibition, 72 h: 210 mg/L Toxicity to micro-organisms EC50, bacteria, Growth inhibition, 16 h: >5,000 mg/L 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characteristics and compliance with applicable laws Page 5 of 7are the responsibility solely of the waste generator. HAS NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted, recycler. Incinerator or other thermal destruction device. EMPTY CONTAINER: Empty container may contain product residue and should not be reused. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Amines, Liquid, Corrosive, N.O.S. TECHNICAL NAME: Fatty Amidoamine PRIMARY HAZARD CLASS/DIVISION: 8 UN/NA NUMBER: UN2735 PACKING GROUP: III NAERG: 153 PLACARDS: Corrosive LABEL: Class 8 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: Immediate and delayed health FIRE: No PRESSURE GENERATING: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes 313 REPORTABLE INGREDIENTS: Contains no SARA 313 (40 CFR 372.65) reportable ingredients. TSCA (TOXIC SUBSTANCE CONTROL ACT) Chemical Name CAS Aminoethylethanolamine (AEEA)* 111-41-1 TSCA REGULATORY: This substance is not listed on the Toxic Substances Control Act (TSCA) Chemical Substance Inventory. This substance may only be used for experimental purposes under the TSCA R&D Exemption in accordance with 40 CFR 720.36. Commercial use is prohibited. 16. OTHER INFORMATION RELEVANT R-PHRASES: R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. R41: Risk of serious damage to eyes. R43: May cause sensitization by skin contact. R61: May cause harm to the unborn child. REASON FOR ISSUE: New APPROVED BY: TITLE: Product Manager PREPARED BY: REVISION SUMMARY: Revision #: 8. This MSDS replaces the November 22, 2010 MSDS. Any changes in information are as follows: In Section 16: HMIS Health, NFPA Health Page 6 of 7HMIS RATING

HEALTH: 

### 2 FLAMMABILITY: 

### 1 PHYSICAL HAZARD: 

### 0 PERSONAL PROTECTION: 

### X NFPA CODES 

### 1 2 0

MANUFACTURER DISCLAIMER: This safety data sheet and the information it contains are offered to you in good faith as accurate. We have reviewed any information contained in this data sheet that we received from sources outside our company. We believe that this information to be correct but cannot guarantee its accuracy or completeness. Health and safety precautions in this data sheet may not be adequate for all individuals and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. No statement made in this data sheet shall be construed as permission or recommendation for the use of any product in a manner that might infringe existing patents. No warranty is made, either expressed or implied. Page 7 of 7Recommended Use Asphalt Emulsifier

Company Emergency Phone Number

OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) Product Code(s)

Chemical Emergency Phone Number

Potential Health Effects CANUTEC (Canadian Transportation) : (613) 996-6666 CHEMTREC (US Transportation) : (800) 424-9300

Principle Routes of Exposure Eye Contact. Skin Contact. Inhalation. Ingestion. Product Name

Acute toxicity 

### 2. HAZARDS IDENTIFICATION

Eyes Avoid contact with eyes. Risk of serious damage to eyes. Skin Avoid contact with skin. Contact causes severe skin irritation and possible burns. May cause sensitization by skin contact. Inhalation Avoid breathing vapors or mists. Aspiration into lungs can produce severe lung damage. Irritating to respiratory system. Corrosive by inhalation. UN/ID No

Ingestion Ingestion may cause serious damage to mouth, throat, and stomach. May be harmful if swallowed. May cause uptake in target organs with no visable symptoms. May cause lung damage if swallowed. Aspiration may cause pulmonary edema and pneumonitis. UN2735

Emergency Contact 

### 1. PRODUCT AND COMPANY IDENTIFICATION

E-mail Manufacturer



### Emergency Overview Corrosive. Vapors may be irritating to eyes, nose, throat, and lungs. May cause sensitization by skin contact. May cause allergic respiratory reaction. May be harmful if swallowed, inhaled, or absorbed through skin. Contains components that may cause target organ damage, based on laboratory animal data. Do not mix with nitrites; product may form suspected cancer-causing nitrosamines.

_____________________________________________________________________________________________ Appearance: Amber viscous liquid Revision Date: 11-Apr-2012

Odor: Ammoniacal



### Page 1 / 8 Issuing Date: 11-Apr-2012 

# Material Safety Data Sheet

Physical State: Not Applicable Version: 1

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012 Prolonged exposure may cause chronic effects. Repeated or prolonged skin contact may cause skin irritation and/or dermatitis and sensitization of susceptible persons. Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen.



### 5. FIRE-FIGHTING MEASURES Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Do not rub affected area. Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.

Flammable Properties Not flammable Environmental hazard

Flash Point > 300 °F / > 149 °C Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Remove and wash contaminated clothing before re-use. Consult a physician. Allergic symptoms may develop within 12 hours after exposure. In the case of skin irritation or allergic reactions see a physician.

Method closed cup See Section 12 for additional Ecological Information. Aggravated Medical Conditions

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Carbon dioxide (CO 2 ). Alcohol-resistant foam. Dry chemical. Chemical Name

Inhalation Move to fresh air in case of accidental inhalation of vapors or decomposition products. Get medical attention immediately if symptoms occur. CAS-No

Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire. Weight % Respiratory disorders. Skin disorders. Call a doctor immediately if allergic signs, particularly in the respiratory tract, are observed.

Hazardous Combustion Products Carbon monoxide (CO). Carbon dioxide (CO 2 ). Nitrogen oxides (NOx). Sulfur oxides. Hydrocarbons. Decomposes in a fire giving off toxic fumes and dense clouds of smoke. Ingestion Do NOT induce vomiting. Call a physician or Poison Control Center immediately. Rinse mouth. Never give anything by mouth to an unconscious person. Risk of product entering the lungs on vomiting after ingestion. Smallest quantities reaching the lungs through swallowing or subsequent vomiting may result in lung edema or pneumonia. Fatty Amidoamine Mixture Proprietary

Explosion Data 100

Sensitivity to Mechanical Impact None. Chronic Effects

Notes to Physician

Sensitivity to Static Discharge None. Treat symptomatically. 

### 4. FIRST AID MEASURES

_____________________________________________________________________________________________ 

### 3. COMPOSITION/INFORMATION ON INGREDIENTS

Protection of First-aiders



### Page 2 / 8 Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012

Methods for Containment Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13). Prevent material from entering surface waters, drains or sewers, and soil. Spills of material which could reach surface waters must be reported to the United States Coast Guard National Response Center's toll free phone number (800) 424-8802. Methods for Cleaning Up Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly. May cause sensitization by inhalation and skin contact. Heating of containers may cause pressure rise, with risk of bursting. Avoid prolonged contact with rags or other porous materials - may spontaneously combust. Always store rags used for wiping purposes that may have contacted this product in an appropriate metal container.



### 7. HANDLING AND STORAGE 6. ACCIDENTAL RELEASE MEASURES Protective Equipment and Precautions for Firefighters

Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Do not breathe vapors or spray mist. In case of insufficient ventilation, wear suitable respiratory equipment. Wear personal protective equipment. Refer to Section 8. Remove contaminated clothing and shoes. Do not puncture or incinerate. If spilled, take caution, as material can cause surfaces to become very slippery. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. There is a hazard associated with rags, paper or any other material used to remove spills which become soaked with product. Avoid accumulation of these: they are to be disposed off safely after use. Never pierce, drill, grind, cut, saw or weld any empty container. Personal Precautions

Technical Measures/Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from direct sunlight. Keep away from heat and sources of ignition. Store in accordance with local regulations. Store away from incompatible materials (see section 10). Store in original container. Do not re-use empty containers. Keep away from food, drink and animal feedingstuffs. No action shall be taken involving any personal risk or without suitable training. Evacuate non-essential personnel. Do not touch or walk through spilled material. Avoid breathing vapors or mists. Ensure adequate ventilation. For personal protection see section 8. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

Environmental Precautions Do not allow material to contaminate ground water system. Try to prevent the material from entering drains or water courses. Prevent entry into waterways, sewers, basements or confined areas. Local authorities should be advised if significant spillages cannot be contained. Specific hazards arising from the chemical

Flammability 1 Personal protection X HMIS



### _____________________________________________________________________________________________ Flammability 1 Physical and chemical hazards
- Stability 1



### Page 3 / 8 Health Hazard 2 Physical Hazard 1 NFPA Health Hazard 2

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012

Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.

9.2 Other information Density VALUE 7.90 lbs/gal @ 25 C / 77 F; 7.84 lbs/gal @ 49 C / 120 F Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.



### 10. STABILITY AND REACTIVITY Engineering Measures Showers Eyewash stations Ventilation systems

Stability Stable under recommended storage conditions. Hygiene Measures

Incompatible Products Oxidizing or reducing agents. Metals. Acids. Combustible materials. May react with nitrites to form suspected cancer causing nitrosamines. Avoid prolonged contact with rags or other porous materials - may spontaneously combust. Always store rags used for wiping purposes that may have contacted this product in an appropriate metal container. Handle in accordance with good industrial hygiene and safety practice.

Conditions to Avoid Extremes of temperature and direct sunlight. Excessive heat. Keep away from open flames, hot surfaces and sources of ignition. Exposure to air. Storage near to reactive materials. 

### 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Other Exposure Guidelines

Personal Protective Equipment

Hazardous Decomposition Products None known based on information supplied. 

### 9. PHYSICAL AND CHEMICAL PROPERTIES

Hazardous Polymerization Hazardous polymerization does not occur. If user operations generate mist, use ventilation to keep exposure to airborne contaminants below the applicable exposure limits. Refer to the current exposure limits for oil mist, diethylenetriamine, triethylenetetramine, and tetraethylenepentamine. Exposure Guidelines



### 11. TOXICOLOGICAL INFORMATION 9.1 Information on Basic Physical and Chemical Properties Eye/Face Protection Tightly fitting safety goggles. If splashes are likely to occur, wear: Goggles, Face-shield. Avoid contact with eyes. Skin and Body Protection

Appearance:

Specific Gravity 0.95 Amber viscous liquid pH Flash Point > 149 °C / > 300 °F 25 C / 77 F Not applicable Odor: Ammoniacal



### _____________________________________________________________________________________________ Remarks • Methods
Viscosity, dynamic 825 cps closed cup



### Page 4 / 8 Property No information available Values

25 C / 77 F

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012

No information available. Inhalation Corrosive to nose, throat and respiratory tract. Avoid breathing vapors or mists. May be harmful if inhaled. Aspiration into lungs can produce severe lung damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. There is no data available for this product.

Developmental Toxicity No information available. Skin Contact Avoid contact with skin. Contact causes severe skin irritation and possible burns. May be absorbed through the skin in harmful amounts. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons.

Chronic Effects Prolonged exposure may cause chronic effects. Repeated or prolonged skin contact may cause skin irritation and/or dermatitis and sensitization of susceptible persons. Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen.



### Teratogenicity No information available. This material should only be handled by, or under the close supervision of, those properly qualified in the handling and use of potentially hazardous chemicals. It should be borne in mind that the toxocological and physiological properties of this compound is not well defined. May be harmful by inhalation, ingestion, or skin absorption.

Target Organ Effects Kidney. Respiratory system. Liver. Skin. Eyes. Carcinogenicity Contains no ingredient listed as a carcinogen. Acute toxicity



### 12. ECOLOGICAL INFORMATION Ingestion May be harmful if swallowed. Can burn mouth, throat, and stomach. May cause uptake in target organs with no visable symptoms. May cause lung damage if swallowed.

Ecotoxicity The environmental impact of this product has not been fully investigated. When spilled, this product may act as an oil, causing a film, sheen, emulsion, or sludge at or beneath the surface of a body of water. This product contains a chemical which is listed as a marine pollutant according to DOT. This product itself is not currently regulated as a marine pollutant per US DOT regulation. Eye Contact

Sensitization May cause sensitization of susceptible persons.



### 13. DISPOSAL CONSIDERATIONS Avoid contact with eyes. Vapor may cause irritation. May cause irreversible damage to eyes.



### _____________________________________________________________________________________________ Germ Cell Mutagenicity No information available. Product Information



### Page 5 / 8 Chronic Effects

Reproductive toxicity

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012

TSCA - Not listed on the TSCA Inventory. R&D Exemption use only. Commercial use is prohibited.

- Waste Disposal Methods

DSL DOT

NDSL EINECS - This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.


### 14. TRANSPORT INFORMATION

ELINCS - IATA

ENCS - Proper shipping name

IECSC - Proper shipping name

KECL - UN2735; Amines, Liquid, Corrosive, N.O.S. (Polyethylene Polyamines, n-Alkyl Polypropylene Polyamines); 8; PG III UN2735; Amines, Liquid, Corrosive, N.O.S. (Polyethylene Polyamines, n-Alkyl Polypropylene Polyamines); 8; PG III

PICCS - Contaminated packaging

AICS - Do not re-use empty containers.

IMDG Hazard class

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory 8

DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List Proper shipping name UN2735; Amines, Liquid, Corrosive, N.O.S. (Polyethylene Polyamines, n-Alkyl Polypropylene Polyamines); 8; PG III

EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances UN/ID No

KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances UN2735

AICS - Australian Inventory of Chemical Substances 

### U.S. Federal Regulations Packing Group III



### 15. REGULATORY INFORMATION

_____________________________________________________________________________________________ International Inventories

Page 6 / 8 Emergency Response Guide Number 153

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012

Fire Hazard No

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.



### U.S. State Regulations

WHMIS Hazard Class D2B Toxic materials E Corrosive material Sudden Release of Pressure Hazard No Acute Health Hazard

California Proposition 65 This product does not contain any Proposition 65 chemicals. Yes

Reactive Hazard No



### 16. OTHER INFORMATION U.S. State Right-to-Know Regulations SARA 311/312 Hazard Categories

This product does not contain any substances regulated by state right-to-know regulations

Prepared By
Issuing Date: 11-Apr-2012 Chronic Health Hazard

Revision Date: 11-Apr-2012 Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).



### International Regulations

Revision Note No information available. Yes



### _____________________________________________________________________________________________ Canada



### Page 7 / 8 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material.

### _____________________________________________________________________________________________ Revision Date: 11-Apr-2012 Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.



### Page 8 / 8 _____________________________________________________________________________________________ End of Material Safety Data Sheet