# Patent

## Title
Substituted imidazole derivatives and their use as anti-thrombosis agents

## Abstract

An improved method for manufacturing a composite metal wire including a core metal wire having extruded therearound a coating metal layer which is different in material from the core metal wire, includes feeding the coating metal into a narrow passageway which is defined between a circumferential groove formed on the outer edge of a rotary wheel and a close fitting surface of a fixed shoe block, carrying the coating metal towards an outlet end of the passageway by frictional drag with the surface of the passageway in accordance with the rotation of the wheel, and passing a core metal wire harder in material than the coating metal through a covering chamber of a larger cross sectional area which is provided with a die and a nipple at the front and rear portions, respectively, whereby the core metal wire is covered with the coating metal in the covering chamber so that a predetermined construction of a composite metal wire is extruded through the die. 20

## Background
This invention relates to a method for the manufacture of a composite metal wire including a core metal wire having extruded therearound a coating metal layer which is different in material from the core metal wire.

Conventionally, a composite metal wire has been manufactured according to methods well known to those skilled in the art and put into a practical use for many purposes. In one of the typical methods, a composite metal wire is manufactured with use of composite billets. Such a billet has a construction of an inner core metal and an outer coating metal which are concentrically positioned. In another method, a composite metal wire is manufactured with the extrusion of a coating metal around a running core wire. In the former method wherein the composite billet is used, an extruder or a rolling apparatus has been adopted.

In such a method of manufacturing a composite metal wire, it is desirable that a composite metal wire be continuously manufactured in an infinite length and that a uniform quality is obtained along the entire length thereof.

In a method of using a composite billet, however, such a billet proves itself a limitation with regard to the volume thereof so that it is definitely impossible to manufacture a composite metal wire of an infinite length. For this reason, a predetermined number of the composite billets must be connected one after another in every stroke of the extrusion operation to provide a desired length of the composite metal wire. However, such a connection of composite billets is extremely difficult during the manufacture thereof. Accordingly, the manufacturing operation is interrupted by this connection of composite billets. This results in a lower productivity in the manufacture of a composite metal wire. Further, even if a composite metal wire of an infinite length can be manufactured in the method as set forth above, it has been considered extremely difficult to provide a composite metal wire with a uniform quality along the entire length thereof.

On the other hand, the coating metal also proves itself a limitation with regard to the volume thereof even in a method of extruding a coating metal layer on a core wire although the core wire is easily available in an infinite length. Accordingly, it is absolutely required that the coating metal be recharged into an extruder during every stroke of the extrusion operation to provide a composite metal wire with such a length. However, a lower productivity also results from the interruption of the manufacturing operation in accordance with the recharging process thereof. In this method, especially, the so-called "stop-mark" is often observed on the products as an indication of why it is difficult to uniformly control the condition of extruding a coating metal layer by different extrusion strokes.

As explained above, the disadvantages in the methods of using a composite billet and of extruding a coating metal layer are that it is impossible to continuously manufacture a composite metal wire and irregularities on the material used are found longitudinally on the products. Especially, it has been regarded as a great problem that such irregularities are produced due to the above mentioned reason during the manufacture of an electrical conducting wire such as an aluminium-clad steel wire (aluminium coated steel wire)

Accordingly, it is an object of the present invention to provide a method for the manufacture of a composite metal wire wherein there is no limitation on the length and volume of materials to be used for the core metal and the coating metal.

It is another object of the present invention to provide a method for the manufacture of a composite metal wire wherein the extrusion of a coating metal layer can be continuously made without any limitation along the entire length thereof.

It is a further object of the present invention to provide a method for the manufacture of a composite metal wire wherein the productivity thereof is remarkable improved as a result of the continuous manufacturing operation.

It is a still further object of the present invention to provide a method for the manufacture of a composite metal wire whereby there is obtained a composite metal wire having an uniform quality along the entire length thereof.

According to one aspect of the present invention, there is provided an improved method of manufacturing a composite metal wire including a core metal wire having extruded therearound a coating metal layer which is different in material from the core metal wire. The improved method comprises feeding the coating metal into a narrow passageway, the narrow passageway being defined between a rotary wheel and a fixed shoe block, the rotary wheel having a circumferential groove around the outer edge thereof and the fixed shoe block making a close fit to the circumferential groove of the wheel, carrying the coating metal toward an outlet end of the passageway therealong by frictional drag with the surface of the passageway as a part or the whole of the pressure of extrusion, passing the core metal wire of a material harder than the coating metal through a covering chamber positioned at the outlet end of the narrow passageway, the covering chamber having a die and a nipple at the front and rear portions thereof respectively, and covering the core metal wire with the coating metal in the covering chamber to establish a bonding between the two metals, whereby a predetermined construction of a composite metal wire is extruded through the die.

An apparatus for manufacturing a composite metal wire according to the above method comprises a rotary wheel having a circumferential groove on the outer edge thereof, a fixed shoe block making a close fit to the rotary wheel, the rotary wheel and the fixed shoe block cooperatively defining a narrow passageway between the circumferential groove of a former and the fitting surface of the latter for feeding a coating metal thereinto, and a covering chamber having a wider cross sectional area positioned at the back or outlet end of the narrow passageway, the covering chamber being provided with a die and a nipple at the front and rear portions thereof, respectively, whereby the extrusion of a composite metal wire is effected by frictional drag of the coating metal with the surface of the circumferential groove as a part or the whole of the pressure of extrusion.

According to the present invention, the core metal wire is of harder material than the coating metal in the construction of a composite metal wire. For instance, metals such as steel, copper, aluminium or alloys thereof may be used as materials of the core metal wire.

On the other hand, the coating metal must have less deformation resistance than the core metal wire. For instance, metals such as zinc, lead, tin or alloys thereof, other than the above mentioned metals, may be used as materials of the coating metal in the combination of two metals as set forth above. In addition, a coating metal may be fed in the form of a wire member, powdery metal or liquid metal in accordance with a specified manufacturing condition of the composite metal wire.

According further to the present invention, the following composite metal wires can be effectively manufactured, that is, for instance, aluminium-clad steel wire (aluminium coated steel wire), aluminium-clad copper wire (aluminium coated copper wire), copper-clad steel wire (copper coated steel wire), lead-clad steel wire (lead coated steel wire), lead-clad aluminium wire (lead coated aluminium wire) etc.

Other objects and aspects of the invention will become apparent from the following description of preferred embodiments with reference to the accompanying drawings in which:

FIG. 1 is a sectional view illustrating apparatus for manufacturing a composite metal wire embodying the present invention,

FIG. 2 is a sectional view taken along the line II--II of FIG. 1,

FIG. 3 is a sectional view illustrating apparatus for manufacturing a composite metal wire in another manner embodying the present invention,

FIG. 4 is a sectional view taken along the line IV--IV of FIG. 3, and

FIG. 5 is a sectional view taken along the line V--V of FIG. 3.

With reference to FIGS. 1 and 2, there is shown apparatus for manufacturing a composite metal wire according to the present invention. A rotary wheel 10 is provided on the outer edge thereof with a circumferential groove 12 having an approximately U shaped cross section. The rotary wheel 10 is mounted on a drive shaft 11 to allow the rotation thereof in a predetermined direction. A shoe block 13 is fixed to a base (not shown) so as to maintain a close fit to the rotary wheel 10. A narrow passageway 15 for feeding an aluminium bar 14 thereinto is defined between the circumferential groove 12 of the rotary wheel 10 and a cooperating fitting surface of the fixed shoe block 13. This passageway 15 is considered to have a container-like function for the aluminium bar 14 and is shaped as having a cross sectional area which decreases for the first half length and which then increases therefrom to the back or outlet end thereof as illustrated by d.sub.1 and d.sub.2, respectively designating large and small portions of the cross sectional area, in FIG. 1.

A covering room or chamber 18 is provided in block 13 at a position orthogonal to the outlet end of the passageway 15 and is provided with a die 16 and a nipple 17 at the front and rear portions respectively. A steel wire 19 is introduced as a core metal wire through the nipple 17, the chamber 18 and the die 16. A stopper 22 is positioned at the end of the passageway 15 to close the same, and a portion 20 having a decreased cross sectional area is installed right above the stopper 22 to connect passageway 15 and chamber 18. .Iadd.As shown in the drawings, the cross sectional area of portion 20 is less than the cross sectional areas of chamber 18 and passageway 15. .Iaddend.

The cross sectional area of the covering chamber 18 is designed to be larger than that of the passageway 15 and that of the decreased area portion 20. The presence of the chamber 18 having a larger area and the portion 20 allows the pressure of extrusion necessary for the manufacture of a composite metal wire to remain stable during the manufacturing operation as set forth in detail hereinafter.

The stopper 22 is adapted to close the end of the passageway 15 by the tight combination thereof with the groove 12.

In operation, the extrusion of a composite metal wire is effected with the rotation of the wheel 10 in the direction of the arrow and the feeding of the aluminium bar 14 into the passageway 15. The aluminium bar 14 is subjected to contacting frictional resistance against the groove 12 as the rotary wheel 10 rotates so that the aluminium bar 14 is carried by frictional drag towards the back of the passageway 15. The bar 14 is thus plastically deformed and passes toward chamber 18 as fluid aluminium. The fluid aluminium 21 surrounds the steel wire 19 in the chamber 18 so that an aluminium-clad steel wire 22 is extruded through the die 16 of the extruder.

With reference next to FIGS. 3 to 5, there is shown apparatus entitled a "two wheel system" for manufacturing a composite metal wire according to another embodiment of the present invention.

Two rotary wheels 10 and 10a are symmetrically mounted on drive shafts 11 and 11a, respectively. The rotary wheels 10 and 10a are provided on the outer edges thereof with circumferential grooves 12 and 12a having U shaped cross sections, respectively. A common shoe block 13 is fixed to a base (not shown) so as to maintain a close fit to the rotary wheels 10 and 10a. Narrow passageways 15 and 15a are defined for feeding aluminium bars 14 and 14a thereinto between the circumferential grooves 12 and 12a of the rotary wheels 10 and 10a and the fitting surfaces of the fixed shoe block 13, respectively.

Each of the passageways 15 and 15a is shaped as having a cross sectional area which decreases for a first half length portion and which increases therefrom to the outlet end thereof, as fully explained in the former embodiment.

A covering room or chamber 18 is installed in block 13 at a position orthogonal to the respective outlet ends of the passageways 15 and 15a and is provided with a die 16 and a nipple 17 at the front and rear portions thereof, respectively. A steel wire 19 is introduced into the covering chamber 18. Stoppers 22 and 22a are positioned to close the respective ends of the passageways 15 and 15a.

In the two wheel system of this embodiment according to the present invention, each of the aluminium bars 14 and 14a is 8 mm in diameter and the steel wire 19 is 2.6 mm in diameter.

The driving force of each of the rotary wheels 10 and 10a is 30 HP, and the speed of revolution thereof is 10 r.p.m. The configuration of the circumferential grooves 12 and 12a is 8 mm square, so that the cross sectional area thereof is 64 mm.sup.2. Further, the cross sectional area of the covering chamber 18 is 200 mm.sup.2, while that of decreased area portions 20 and 20a is 50 mm.sup.2.

The aluminium bars 14 and 14a are fed into the passageways 15 and 15a respectively after being subjected to a preliminary heating up to 300.degree.-450.degree. C. The extrusion of a composite metal wire is effected by the pressure of extrusion of 15-40 kg/mm.sup.2 in the covering chamber 18. The steel wire 19 is preliminarily heated up to 250.degree.-350.degree. C. and is subjected to a forward traction force of 150-300 kg for the extrusion of the composite metal wire.

In the case of manufacturing an aluminium-clad steel wire 23, the speed of extrusion is 150 m/min. The outer diameter of the aluminium-clad steel wire 23 is 3.2 mm while the thickness of the coating aluminium is 0.3 mm. As set forth above, the cross sectional area of the covering chamber 18 is larger than that of the passageways 15 and 15a.

This allows a sufficient quantity of the fluid aluminium contained in the covering chamber 18 to accomodate a minute fluctuation of the pressure of extrusion by the viscosity thereof even if such a fluctuation occurs for the aluminium bars 14 and 14a in the passageways 15 and 15a. Accordingly, the pressure of extrusion is always kept stable when the coating aluminium 21 is metallurgically bonded to the steel wire 19. The decreased area portions 20 and 20a are positioned between the covering chamber 18 and the passageways 15 and 15a, respectively. This prevents the fluid aluminium 21 from reversely flowing into the passageways 15 and 15a when the pressure of extrusion is extremely decreased due to any fluctuation of the contacting frictional resistance (frictional drag) in the passageways 15 and 15a. Accordingly, both the covering chamber 18 of a larger cross sectional area and the decreased area portions 20 and 20a serve the purpose of stabilizing the pressure of extrusion. The block 13 is provided with a fitting step portion 25, while the rotary wheel 10 is provided with two fitting step portions 25a at opposite sides of the groove 12 as shown in FIG. 5. Accordingly, the rotatory wheel 10 faces the fixed shoe block 13 with more than two fitting surfaces. Further, the wheels 10 and 10a are each provided with a pair of shallow grooves 26 between the two fitting surfaces so that splinters of a coating metal 14 are easily set free even if they are produced.

Although the occurrence of such splinters can be decreased to some extent by the close fit of the step portions 25 and 25a, it is very difficult to perfectly prevent the occurrence of splinters. The shallow grooves 26 serve the purpose of suppressing the growth of such splinters due to the fact that the increase of pressure is avoided with the release thereof into the shallow grooves 26. Especially, it is ascertained that the occurence of splinters is remarkable near the areas of the stoppers 22 and 22a. However, splinters of a material to be carried can be easily set free because the stoppers 22 and 22a are designed to have side surfaces fitting into the grooves 12 and 12a which are provided with freeing surfaces.

As set forth above, the various means are adapted to suppress the disadvantage of splinters so that no difficulty will result even in the event of the occurrence of splinters in this embodiment according to the present invention. Further, such means for coping with the problem of splinters results in less overall consumption of power. Accordingly, this makes a big contribution to the practical use of the present invention.

The change of cross sectional area of the passageways 15 and 15a serves the purpose of not only producing the frictional drag necessary for the pressure of extrusion but also of decreasing the frictional drag which is the cause of the consumption of power.

There is expected the following advantages in the above mentioned embodiment of the two wheel system with regard to the manufacture of a composite metal wire as compared to the former embodiment of a single wheel system.

One advantage is that less power is necessary to drive the rotary wheels 10 and 10a, and the ratio of extrusion can be larger so that the thickness of an extruded coating metal can be freely changed within a broader range.

Another advantage is that the flows of extruded coating metal are well balanced dynamically at the opposite entrances to the covering chamber 18 so that uniformity is surely obtained in the bonding between a core metal wire and a coating metal, and uneven thickness of the coating metal layer hardly occurs. Further, the apparatus of the two wheel system is stable mechanically and dynamically, thus providing less possibility of breakdown an excellent durability.

It goes without saying that it is possible to increase the number of rotary wheels other than the two wheel system in the present invention. For instance, it is considered a practical use that three wheels may be installed at angles of 120 degrees and four wheels may be installed at angles of 90 degrees.

As fully explained in the above mentioned embodiments, there is no limitation on the length and volume for materials of the core metal and a coating metal, and the manufacture of a composite metal wire can be continuously performed in an infinite length thereof so that the productivity thereof is remarkably improved and an excellent product can be obtained without any irregularity of materials.

Further, the apparatus of the present invention may be extremely small as compared to the volume of a conventional apparatus of a press-extruding system having a larger container.

Although the invention has been described in preferred embodiments with a certain degree of particularity, it is understood that the present disclosure of the preferred embodiments may be changed with regard to the details of construction and the combination and arrangement of parts without departing from the spirit and the scope of the invention as hereinafter claimed.

## Claims

1. A method of manufacturing a composite metal wire including a metal core wire surrounded by a coating metal of a material different from said metal core wire, said method comprising: circumferential portion of said groove to define therewith a narrow passageway having an inlet end and an outlet end, a fixed stopper portion fitting in said groove to entirely close said passageway and to define said outlet end thereof, and a covering chamber communicating with said outlet end of said passageway and having a nipple for guiding a metal core wire and a die for defining the outer cross-section of a composite metal wire; rotating said rotary wheel in a direction toward said outlet end of said passageway; due to oppositely directed frictional forces including a greater friction force from the surfaces of said wheel defining said groove and a lesser friction force from said fitting surface of said fixed shoe block; greater friction force and causing said coating metal to collide with said fixed stopper portion, thereby imparting an extrusion pressure to said coating metal; chamber; .[.and.]. chamber, thus filling said chamber with said coating metal, covering said metal core wire with said coating metal to form a bond therebetween, and extruding through said die said metal core wire covered with said coating metal as a composite metal wire.[...]..Iadd.; and providing the cross sectional area of said chamber greater than the cross sectional area of said passageway to ensure that said extruding pressure remains stable in said chamber..Iaddend.

2. A method as claimed in claim 1, wherein said step of feeding comprises feeding coating metal in wire form into said inlet end of said passageway.

3. A method as claimed in claim 1, wherein said step of feeding comprises feeding coating metal in powder form into said inlet end of said passageway.

4. A method as claimed in claim 1, wherein said step of feeding comprises feeding coating metal in liquid form into said inlet end of said passageway.

5. A method as claimed in claim 1, wherein said metal core wire is of a metal selected from the group consisting of steel, copper, aluminium or alloys thereof and said coating metal is a metal selected from the group consisting of zinc, lead, tin or alloys thereof.

6. A method as claimed in claim 1, wherein said metal core wire comprises steel and said coating metal comprises a bar of aluminium, and further comprising preliminarily heating said steel wire to 250.degree.-350.degree. C., and preliminarily heating said aluminium bar to 300.degree.-450.degree. C.

7. A method as claimed in claim 1, further comprising applying a forward traction force of 150-300 kg to said metal core wire during extrusion.

8. A method as claimed in claim 1, wherein coating metal is passed into said chamber from two said passageways. .Iadd.9. A method as claimed in claim 1, further comprising preventing said coating metal from flowing from said chamber to said passageway by providing between said chamber and said passageway a decreased area portion having a cross sectional area smaller than said cross sectional area of said passageway..Iaddend. .Iadd.10. A method as claimed in claim 1, further comprising preventing said coating metal from flowing from said chamber to said passageway by providing between said chamber and said passageway a decreased area portion having a cross sectional area smaller than said cross sectional area of said chamber..Iaddend. .Iadd.11. A method as claimed in claim 1, further comprising feeding a coating metal into said chamber from said passageway by providing a plurality of said rotary wheels positioned symmetrically in a dynamically balanced condition..Iaddend.