### 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 

# Order Summary Report Analytical Laboratory

Order Number: J10120118

Lab Contact: Jason C Perkins 

## Date: 12/20/2010 Customer Address: 253 Plant Allen Road Customer Name(s): Don Scruggs, Robbin Jolly, Ray Lidke, Bill Kennedy

Belmont, NC 28012
Phone: 980-875-5348 Report Authorized By: (Signature) 

### Program Comments: Allen Test Burn #2 - 12/3 Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with an "X" or "1" indicate a deviation from the method quality system or quality control requirement. All results are reported on a dry weight basis unless otherwise noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.

# Sample ID's & Descriptions:

Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2010013060 ALLEN 03-Dec-10 8:26 AM Jeff Womack FGD Purge Eff 2010013061 ALLEN 03-Dec-10 9:04 AM Jeff Womack EQ Tank Eff 2010013062 ALLEN 03-Dec-10 8:59 AM Jeff Womack BioReactor 1 Inf 2010013063 ALLEN 03-Dec-10 8:30 AM Jeff Womack BioReactor 2 Inf 2010013064 ALLEN 03-Dec-10 9:08 AM Jeff Womack BioReactor 2 Eff 2010013065 ALLEN 03-Dec-10 Jeff Womack TRIP BLANK 2010013066 ALLEN 22-Nov-10 1:45 PM L. Davis Filter Blk 7 Total Samples

### COC and .pdf report are in agreement with sample totals

and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. The Vendor Laboratories have been qualified by the Analytical Laboratory Yes No



# Technical Validation Review Checklist:

Yes No Yes No



# Report Sections Included:

Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Test Case Narratives Analytical Laboratory QC Report Chain of Custody

Reviewed By:

### DataBase Administrator Date:

### 12/20/2010Yes

Electronic Data Deliverable (EDD) Sent Separately

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J10120118

2010013060 Collection Date: 03-Dec-10 8:26 AM 

## Site:FGD Purge Eff Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 36.6 ug/L EPA 245.1 10-Dec-10 10:50 2.5 TLINN TOTAL RECOVERABLE METALS BY ICP Boron (B) 137 mg/L EPA 200.7 08-Dec-10 11:45 0.5 DJSULL1 DISSOLVED METALS BY ICP-MS Selenium (Se) 159 ug/L EPA 200.8 16-Dec-10 12:40 10 KRICHAR TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 240 ug/L EPA 200.8 14-Dec-10 15:09 10 KRICHAR Chromium (Cr) 168 ug/L EPA 200.8 14-Dec-10 15:09 10 KRICHAR Copper (Cu) 214 ug/L EPA 200.8 14-Dec-10 15:09 10 KRICHAR Nickel (Ni) 291 ug/L EPA 200.8 14-Dec-10 15:09 10 KRICHAR Selenium (Se) 1640ug/L EPA 200.8 14-Dec-10 15:09 10 KRICHAR Silver (Ag) < 10ug/L EPA 200.8 14-Dec-10 15:09 10 KRICHAR Zinc (Zn) 399 ug/L EPA 200.8 14-Dec-10 15:09 20 KRICHAR TOTAL DISSOLVED SOLIDS Vendor Parameter Complete V_PRISM 

## 2010013061 Collection Date: 03-Dec-10 9:04 AM 

## Site:EQ Tank Eff Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 34.3 ug/L EPA 245.1 10-Dec-10 10:52 2.5 TLINN TOTAL RECOVERABLE METALS BY ICP Boron (B) 100 mg/L EPA 200.7 08-Dec-10 11:49 0.5 DJSULL1 DISSOLVED METALS BY ICP-MS Selenium (Se) 98.2 ug/L EPA 200.8 16-Dec-10 12:43 10 KRICHAR TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 162 ug/L EPA 200.8 14-Dec-10 15:04 10 KRICHAR Chromium (Cr) 113 ug/L EPA 200.8 14-Dec-10 15:04 10 KRICHAR Copper (Cu) 150 ug/L EPA 200.8 14-Dec-10 15:04 10 KRICHAR Nickel (Ni) 206 ug/L EPA 200.8 14-Dec-10 15:04 10 KRICHAR Selenium (Se) 1070ug/L EPA 200.8 14-Dec-10 15:04 10 KRICHAR Silver (Ag) < 10ug/L EPA 200.8 14-Dec-10 15:04 10 KRICHAR Zinc (Zn) 266 ug/L EPA 200.8 14-Dec-10 15:04 20 KRICHAR

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J10120118

2010013062 Collection Date: 03-Dec-10 8:59 AM 

## Site:BioReactor 1 Inf Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst TOTAL RECOVERABLE METALS BY ICP Boron (B) 76.1 mg/L EPA 200.7 08-Dec-10 11:53 0.5 DJSULL1 DISSOLVED METALS BY ICP-MS Selenium (Se) 80.8 ug/L EPA 200.8 16-Dec-10 12:47 10 KRICHAR TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 10ug/L EPA 200.8 14-Dec-10 15:00 10 KRICHAR Chromium (Cr) < 10ug/L EPA 200.8 14-Dec-10 15:00 10 KRICHAR Copper (Cu) 12.3 ug/L EPA 200.8 14-Dec-10 15:00 10 KRICHAR Nickel (Ni) 29.3 ug/L EPA 200.8 14-Dec-10 15:00 10 KRICHAR Selenium (Se) 78.0 ug/L EPA 200.8 14-Dec-10 15:00 10 KRICHAR Silver (Ag) < 10ug/L EPA 200.8 14-Dec-10 15:00 10 KRICHAR Zinc (Zn) < 20ug/L EPA 200.8 14-Dec-10 15:00 20 KRICHAR 

## 2010013063 Collection Date: 03-Dec-10 8:30 AM 

## Site:BioReactor 2 Inf Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst TOTAL RECOVERABLE METALS BY ICP Boron (B) 70.3 mg/L EPA 200.7 08-Dec-10 11:57 0.5 DJSULL1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 10ug/L EPA 200.8 14-Dec-10 14:55 10 KRICHAR Chromium (Cr) < 10ug/L EPA 200.8 14-Dec-10 14:55 10 KRICHAR Copper (Cu) < 10ug/L EPA 200.8 14-Dec-10 14:55 10 KRICHAR Nickel (Ni) 33.7 ug/L EPA 200.8 14-Dec-10 14:55 10 KRICHAR Selenium (Se) < 10ug/L EPA 200.8 14-Dec-10 14:55 10 KRICHAR Silver (Ag) < 10ug/L EPA 200.8 14-Dec-10 14:55 10 KRICHAR Zinc (Zn) < 20ug/L EPA 200.8 14-Dec-10 14:55 20 KRICHAR 

## 2010013064 Collection Date: 03-Dec-10 9:08 AM 

## Site:BioReactor 2 Eff Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 1 ug/L EPA 245.1 10-Dec-10 10:55 1 TLINN TOTAL RECOVERABLE METALS BY ICP Boron (B) 74.4 mg/L EPA 200.7 08-Dec-10 12:01 0.5 DJSULL1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 2.02 ug/L EPA 200.8 14-Dec-10 16:07 2 KRICHAR

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J10120118

2010013064 Collection Date: 03-Dec-10 9:08 AM 

## Site:BioReactor 2 Eff Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst TOTAL RECOVERABLE METALS BY ICP-MS Chromium (Cr) < 2 ug/L EPA 200.8 14-Dec-10 16:07 2 KRICHAR Copper (Cu) < 2 ug/L EPA 200.8 14-Dec-10 16:07 2 KRICHAR Nickel (Ni) < 2 ug/L EPA 200.8 14-Dec-10 16:07 2 KRICHAR Selenium (Se) 4.70 ug/L EPA 200.8 14-Dec-10 16:07 2 KRICHAR Silver (Ag) < 2 ug/L EPA 200.8 14-Dec-10 16:07 2 KRICHAR Zinc (Zn) < 4 ug/L EPA 200.8 14-Dec-10 16:07 4 KRICHAR 

## 2010013065 Collection Date: 03-Dec-10 

## Site:TRIP BLANK Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst TOTAL RECOVERABLE METALS BY ICP Boron (B) < 0.05mg/L EPA 200.7 08-Dec-10 11:18 0.05 DJSULL1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 1 ug/L EPA 200.8 14-Dec-10 14:45 1 KRICHAR Chromium (Cr) < 1 ug/L EPA 200.8 14-Dec-10 14:45 1 KRICHAR Copper (Cu) < 1 ug/L EPA 200.8 14-Dec-10 14:45 1 KRICHAR Nickel (Ni) < 1 ug/L EPA 200.8 14-Dec-10 14:45 1 KRICHAR Selenium (Se) < 1 ug/L EPA 200.8 14-Dec-10 14:45 1 KRICHAR Silver (Ag) < 1 ug/L EPA 200.8 14-Dec-10 14:45 1 KRICHAR Zinc (Zn) < 2 ug/L EPA 200.8 14-Dec-10 14:45 2 KRICHAR 

## 2010013066 Collection Date: 22-Nov-10 1:45 PM 

## Site:Filter Blk Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DISSOLVED METALS BY ICP-MS Selenium (Se) < 2 ug/L EPA 200.8 16-Dec-10 12:51 2 KRICHAR

### This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 

# Case Narrative 12/20/2010

Duke Energy Corporation Jay Perkins 13339 Hagers Ferry Road Huntersville, NC 28078 Project: Allen - FGD Alternative Fuels Test Burn #2 Daily Project No.: J10120118 Lab Submittal Date: 12/07/2010 Prism Work Order: 0120253

Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC.



### VP Laboratory Services Reviewed By

Data Qualifiers Key Reference:



### Method Detection Limit MDLBelow Reporting Limit BRLRelative Percent Difference RPD 

## *Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 1 of 5

# Sample Receipt Summary 12/20/2010 

## Prism Work Order: 0120253 Client Sample ID Matrix Lab Sample ID Date SampledDate Received 

### 0120253-01 12/03/10 2010013060/FGD Purge EFF 12/07/10 Water Samples received in good condition at 1.1 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 2 of 5

# Laboratory Report 12/20/2010

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: J10120118 Project: Allen - FGD Alternative Fuels Test Burn #2 Daily Duke Energy Corporation Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: 2010013060/FGD Purge E Prism Sample ID: 0120253-01 Prism Work Order: 0120253 Time Collected: 12/03/10 08:26 Time Submitted: 12/07/10 15:25

General Chemistry Parameters 10000 *SM2540 C P0L0227 1 50 12/10/10 13:30JAB mg/L 8.7 Total Dissolved Solids

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 3 of 5

### 12/20/10 

## Level II QC Report

13339 Hagers Ferry Road Project No: J10120118 Project: Allen - FGD Alternative Fuels Test Burn #2 Daily Duke Energy Corporation Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 0120253 Time Submitted: 12/7/10 3:25:00PM

Result Limit

ReportingUnitsLevel SpikeResult

Source%REC%REC LimitsRPDRPD LimitNotes Analyte General Chemistry Parameters - Quality Control



### Batch P0L0227 - NO PREP Blank (P0L0227-BLK1) 

### Prepared & Analyzed: 12/10/10 Total Dissolved Solids mg/L BRL 50 LCS (P0L0227-BS1) 

### Prepared & Analyzed: 12/10/10 Total Dissolved Solids mg/L 1000 50 1000 90-110 100 Duplicate (P0L0227-DUP1) 

### Prepared & Analyzed: 12/10/10 Source: 0120253-01 Total Dissolved Solids mg/L 10400 50 10400 20 0.3 

### Sample Extraction Data NO PREP Lab Number Batch Date Initial Final P0L0227 0120253-01 12/10/10 50 50 mL mL

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 4 of 5Page 5 of 5