# pennsyLvania DEPARTMENT OF ENVIRONMENTAL PROTECTION

SECRETARY 

### April 24, 2014



### Mr. 

### Shawn Garvin Regional Administrator U.S. Environmental Protection Agency, Region III 1650 Arch Street (Mail Code: 3RAOO) Philadelphia, PA 19103-2029 Dear Mr. Garvin: As required under 40 Code of Federal Regulations (CFR), Part 58.15, I hereby certify that, to the best of my knowledge, the Pennsylvania 2013 ambient concentration data and the quality assurance data collected and analyzed by the Pennsylvania Department of Enviromnental Protection (DEP) are completely submitted to the Air Quality System (AQS) database, and the ambient data are accurate taking into consideration the quality assurance findings. In addition, I certify that the data collection procedures conform to the applicable quality assurance, air monitoring methodology, probe siting criteria and reporting requirements in Part 58 of the CFR, Appendices A, C, and E. Please note that the certification letter for the 2013 lead and S02 data was previously sent to the Enviromnental Protection Agency on March 31,2014. I am enclosing copies of the AMP 450NC and AMP 600 reports to identify the data that are being certified. The AMP 450NC reports apply to non-criteria NO and NO x 

### data, as reported by DEP, and speciated PM 

### z . 5 

### data which was collected by DEP but analyzed and reported by Research Triangle Institute. Should you have any questions or need additional information, please contact Joyce E. Epps, Director, Bureau of Air Quality, bye-mail atjeepps@pa.govorbytelephone at 717.787.9702. Sincerely, 

# 9" /' () 0 

# a /' '---**~' ~'''-**  E. Christopher Abruzzo " '('\'"' Secretary Enclosures

Rachel Carson State Office Building 

### I P.O. Box 2063 

### I Harrisburg, PA 17105-2063 717.787.2814 W Printed on Recycled Paper 

### \tJ1fj www.depweb.state.pa.usUNITED STATES ENVIRONMENTAL PROTECTION AGENCY DESIGN VALUE REPORT Jul. 23, 2014 Report Request ID: 1235731 Report Code: AMP480

Selection Criteria Page 1 User ID: AES

State County City Site Parameter POC AQCR UAR CBSA CSA EPA Region 42 GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS Parameter Classification Parameter Method Duration DESIGN VALUE 88101

SELECTED OPTIONS

SINGLE EVENT PROCESSING WORKFILE DELIMITER USER SITE METADATA MERGE PDF FILES QUARTERLY DATA IN WORKFILE

AGENCY ROLE Option Type Option Value EXCLUDE REGIONALLY CONCURRED EVENTS

, STREET ADDRESS YES NO PQAO DATE CRITERIA

2012 Start Date End Date 2013 Tribal Code

APPLICABLE STANDARDS Standard Description PM25 24-hour 2013 PM25 Annual 2013UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM PRELIMINARY DESIGN VALUE REPORT Report Date: Jul. 23, 2014

Notes: 1. Computed design values are a snapshot of the data at the time the report was run (may not be all data for year). 2. Some PM2.5 24-hour DVs for incomplete data that are marked invalid here may be marked valid in the Official report due to additional analysis. 3. Annual Values not meeting completeness criteria are marked with an asterisk ('*'). Page 1 of 10UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM PRELIMINARY DESIGN VALUE REPORT Report Date: Jul. 23, 2014

Notes: 1. Computed design values are a snapshot of the data at the time the report was run (may not be all data for year). 2. Some PM2.5 24-hour DVs for incomplete data that are marked invalid here may be marked valid in the Official report due to additional analysis. 3. Annual Values not meeting completeness criteria are marked with an asterisk ('*'). Page 2 of 10 

### Pollutant: Standard Units: NAAQS Standard: Statistic: Statistic: Site-LevelPM2.5 - Local Conditions(88101) Micrograms/cubic meter (LC)(105) PM25 24-hour 2013 / PM25 Annual 2013 Annual Weighted Mean Annual 98th Percentile Level: Level: Design Value Year: 2012

REPORT EXCLUDES MEASUREMENTS WITH REGIONALLY CONCURRED EVENT FLAGS. 12 35 State Name: Pennsylvania Site_ID / STREET ADDRESS | | | Cred. Days Comp. Qrtrs Wtd.

Mean 98th Perctil Cert&

Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert& Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert&

Eval | | | Design Value Valid

Ind. | | | Design Value Valid

Ind. 24-Hour Annual 2012 2011 2010

42-001-0001 42-003-0002 42-003-0008 42-003-0064 42-003-0067 42-003-0093 42-003-0095 42-003-1008 42-003-1301 42-003-3007 42-005-0001 NARSTO SITE - ARENDTSVILLE 520 ORCHARD AVE, AVALON 301 39TH ST, BLDG #7, LAWRENCEVILLE 2743 WASHINGTON BLVD, LIBERTY 3640 OLD OAKDALE RD, SOUTH FAYETTE KUMMER RD, GOLF CLUBHOUSE, NORTH PARK 1000 BEAVER GRADE RD CORAOPOLIS PA PACIFIC & IDAHO AVE, HARRISON 600 ANDERSON ST, NORTH BRADDOCK 501 WADDELL AVE, CLAIRTON GLADE DR. & NOLTE RD. KITTANNING 335 111 343 344 108 54 0 110 100 54 347 4

4 4 4 4 4 0 4 3 4 4 27.7 20.9 20.4 42.5 18.1 16.4

20.7 26.8 19.2 20.9 *

* 11.0 10.9 10.1 14.3 9.2 8.6

10.5 11.5 9.4 9.7 * S

S S S S

S S S 336 205 346 339 107 50 0 104 100 49 312 4

4 4 4 4 3 0 3 3 3 3 30.2 29.8 27.3 38.0 30.6 25.6

29.8 33.7 30.3 28.2 *

*

*

*

*

* 12.2 13.1 11.1 14.0 10.6 9.0

11.6 12.3 10.7 12.1 *

*

*

* 348

358 342 340 111 52 53 111 106 55 348 4

4 4 4 4 3 3 4 4 4 4 31.0 37.7 29.7 48.8 28.5 26.5 26.4 34.0 37.2 28.2 31.9 *

* 11.7 16.3 12.2 16.0 11.7 10.5 11.5 13.0 13.7 12.5 13.2 *

* 30

29 26 43 26 23 26 28 33 26 27 Y Y Y Y Y Y N Y Y N Y 11.6 13.4 11.1 14.8 10.5 9.4 11.5 11.7 12.5 10.9 11.7 Y

Y Y Y Y Y N N Y N YUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM PRELIMINARY DESIGN VALUE REPORT Report Date: Jul. 23, 2014

Notes: 1. Computed design values are a snapshot of the data at the time the report was run (may not be all data for year). 2. Some PM2.5 24-hour DVs for incomplete data that are marked invalid here may be marked valid in the Official report due to additional analysis. 3. Annual Values not meeting completeness criteria are marked with an asterisk ('*'). Page 3 of 10 

### Pollutant: Standard Units: NAAQS Standard: Statistic: Statistic: Site-LevelPM2.5 - Local Conditions(88101) Micrograms/cubic meter (LC)(105) PM25 24-hour 2013 / PM25 Annual 2013 Annual Weighted Mean Annual 98th Percentile Level: Level: Design Value Year: 2012

REPORT EXCLUDES MEASUREMENTS WITH REGIONALLY CONCURRED EVENT FLAGS. 12 35 State Name: Pennsylvania Site_ID / STREET ADDRESS | | | Cred. Days Comp. Qrtrs Wtd.

Mean 98th Perctil Cert&

Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert& Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert&

Eval | | | Design Value Valid

Ind. | | | Design Value Valid

Ind. 24-Hour Annual 2012 2011 2010

42-007-0014 42-011-0011 42-013-0801 42-017-0012 42-021-0011 42-027-0100 42-029-0100 42-041-0101 42-043-0401 42-045-0002 42-049-0003 EIGHT STREET AND RIVER ALLEY 1059 Arnold Road 2ND AVE & 7TH ST ROCKVIEW LANE MILLER AUTO SHOP 1 MESSENGER ST PENN STATE UNIVERSITY - ARBORETUM SITE NEW GARDEN AIRPORT - TOUGHKENAMON IMPERIAL COURT 651 Gibson Blvd., Harrisburg, PA 17104 FRONT ST & NORRIS ST 10TH AND MARNE STREETS 358 364 346 361 342 361 330 365 351 288 346 4

4 4 4 4 4 4 4 4 3 4 22.6 26.3 26.4 28.2 28.0 22.5 24.1 29.2 28.1 31.1 25.3 * 11.9

11.3 11.7 10.7 11.6 9.8 9.8 10.9 11.6 12.8 11.2 364

362 345 364 332 355 293 362 352 336 346 4

4 4 4 4 4 3 4 4 4 4 29.8 26.4 30.1 29.7 32.5 28.5 33.8 30.4 31.2 28.6 26.7 * 11.7

11.3 11.8 11.5 13.4 9.5 13.2 11.5 12.1 12.9 11.4 319

328 197 354 364 359 341 365 360 346 320 4

4 2 4 4 4 4 4 4 4 3 29.4 26.7 26.8 28.3 30.2 25.5 35.1 31.4 32.9 32.8 30.2 *

* 12.5 10.0 5.9 10.5 11.9 9.1 13.8 10.6 12.0 13.5 11.1 *

* 27

26 28 29 30 26 31 30 31 31 27 Y Y N Y Y Y Y Y Y N Y 12.0 10.9 9.8 10.9 12.3 9.5 12.3 11.0 11.9 13.1 11.2 Y

Y N Y Y Y Y Y Y Y NUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM PRELIMINARY DESIGN VALUE REPORT Report Date: Jul. 23, 2014

Notes: 1. Computed design values are a snapshot of the data at the time the report was run (may not be all data for year). 2. Some PM2.5 24-hour DVs for incomplete data that are marked invalid here may be marked valid in the Official report due to additional analysis. 3. Annual Values not meeting completeness criteria are marked with an asterisk ('*'). Page 4 of 10 

### Pollutant: Standard Units: NAAQS Standard: Statistic: Statistic: Site-LevelPM2.5 - Local Conditions(88101) Micrograms/cubic meter (LC)(105) PM25 24-hour 2013 / PM25 Annual 2013 Annual Weighted Mean Annual 98th Percentile Level: Level: Design Value Year: 2012

REPORT EXCLUDES MEASUREMENTS WITH REGIONALLY CONCURRED EVENT FLAGS. 12 35 State Name: Pennsylvania Site_ID / STREET ADDRESS | | | Cred. Days Comp. Qrtrs Wtd.

Mean 98th Perctil Cert&

Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert& Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert&

Eval | | | Design Value Valid

Ind. | | | Design Value Valid

Ind. 24-Hour Annual 2012 2011 2010

42-069-2006 42-071-0007 42-075-0100 42-085-0100 42-089-0002 42-091-0013 42-095-0025 42-095-0027 42-101-0004 42-101-0024 42-101-0047 GEORGE ST TROOP AND CITY OF SCRANTON ABRAHAM LINCOLN JR HIGH GROFFTOWN RD 125 Birch Road PA518 (NEW CASTLE ROAD) & PA418 HC 1, BOX 95-B NEAR RT 611 & BROOKDALE ROAD STATE ARMORY - 1046 BELVOIR RD WASHINGTON & CAMBRIA STS. FREEMANSBURG 2604 Schoenersville Road 1501 E. LYCOMING AVE. GRANT-ASHTON ROADS PHILA NE AIRPORT 500 SOUTH BROAD STREET-PARKING LOT (CHS) 344 366 338 359 348 362 351 321 47 0 337 4

4 4 4 4 4 4 3 3 0 4 19.7 28.9 33.3 22.5 19.3 21.8 27.6 26.0 21.1

21.8 *

*

* 8.3 12.6 14.2 10.9 7.9 9.7 11.5 10.9 9.7

10.2 *

*

* 354

364 260 361 331 365 340 348 57 0 308 4

4 3 4 4 4 4 4 4 0 4 23.4 29.9 29.3 25.7 20.3 27.6 35.2 29.8 23.7

27.9 *

* 9.3 12.0 11.4 10.1 6.4 10.3 14.5 11.2 8.9

11.4 * 347

343 0 316 190 330 335 346 329 352 316 4

4 0 3 2 4 4 4 4 4 4 27.7 34.1

27.4 25.8 25.9 33.3 27.6 27.6 25.2 28.3 *

*

* 9.7 11.7

10.9 9.7 9.5 13.7 9.8 10.7 9.6 11.0 *

*

* 24

31 31 25 22 25 32 28 24 25 26 Y Y N Y N Y Y Y Y N Y 9.1 12.1 12.8 10.6 8.0 9.8 13.2 10.6 9.8 9.6 10.9 Y

Y N Y N Y Y Y Y N YUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM PRELIMINARY DESIGN VALUE REPORT Report Date: Jul. 23, 2014

Notes: 1. Computed design values are a snapshot of the data at the time the report was run (may not be all data for year). 2. Some PM2.5 24-hour DVs for incomplete data that are marked invalid here may be marked valid in the Official report due to additional analysis. 3. Annual Values not meeting completeness criteria are marked with an asterisk ('*'). Page 5 of 10 

### Pollutant: Standard Units: NAAQS Standard: Statistic: Statistic: Site-LevelPM2.5 - Local Conditions(88101) Micrograms/cubic meter (LC)(105) PM25 24-hour 2013 / PM25 Annual 2013 Annual Weighted Mean Annual 98th Percentile Level: Level: Design Value Year: 2012

REPORT EXCLUDES MEASUREMENTS WITH REGIONALLY CONCURRED EVENT FLAGS. 12 35 State Name: Pennsylvania Site_ID / STREET ADDRESS | | | Cred. Days Comp. Qrtrs Wtd.

Mean 98th Perctil Cert&

Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert& Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert&

Eval | | | Design Value Valid

Ind. | | | Design Value Valid

Ind. 24-Hour Annual 2012 2011 2010

42-101-0055 42-101-0057 42-101-1002 42-125-0005 42-125-0200 42-125-5001 42-125-5200 42-129-0008 42-133-0008 24TH & RITNER STREETS 240 Spring Garden Street 5200 PENNYPACK PARK PHILADELPHIA, PA. 19136 CHARLER01 WASTE TREATMENT PLANT MCCARRELL AND FAYETTE STS HILLMAN STATE PARK - KINGS CREEK ROAD 220 Meddings Road DONOHOE ROAD - PENN DOT MAINT DIST BLDG HILL ST. 325 328 311 351 366 348 145 363 365 4

4 4 4 4 4 1 4 4 24.8 23.3 23.5 23.4 20.6 15.8 18.4 22.8 28.4 * 10.3

10.1 10.3 10.4 10.5 6.9 9.0 10.1 12.0 * 335

345 302 317 364 343 0 309 349 4

4 4 3 4 4 0 3 4 30.6 30.5 19.3 28.6 27.4 12.3

32.8 28.0 *

*

* 11.4 11.4 8.9 12.0 10.8 5.9

13.7 11.6 *

* 336

323 0 352 351 347 0 345 352 4

4 0 4 4 4 0 4 4 28.9 27.9

27.0 27.0 22.2

32.4 29.7 *

* 11.3 10.9

13.2 12.1 8.9

14.0 11.3 *

* 28

27 21 26 25 17 18 29 29 Y Y N Y Y Y N N Y 11.0 10.8 9.6 11.9 11.1 7.2 9.0 12.6 11.7 Y

Y N N Y Y N Y YUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM PRELIMINARY DESIGN VALUE REPORT Report Date: Jul. 23, 2014

Notes: 1. Computed design values are a snapshot of the data at the time the report was run (may not be all data for year). 2. Some PM2.5 24-hour DVs for incomplete data that are marked invalid here may be marked valid in the Official report due to additional analysis. 3. Annual Values not meeting completeness criteria are marked with an asterisk ('*'). Page 6 of 10 

### Pollutant: Standard Units: NAAQS Standard: Statistic: Statistic: Site-LevelPM2.5 - Local Conditions(88101) Micrograms/cubic meter (LC)(105) PM25 24-hour 2013 / PM25 Annual 2013 Annual Weighted Mean Annual 98th Percentile Level: Level: Design Value Year: 2013

REPORT EXCLUDES MEASUREMENTS WITH REGIONALLY CONCURRED EVENT FLAGS. 12 35 State Name: Pennsylvania Site_ID / STREET ADDRESS | | | Cred. Days Comp. Qrtrs Wtd.

Mean 98th Perctil Cert&

Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert& Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert&

Eval | | | Design Value Valid

Ind. | | | Design Value Valid

Ind. 24-Hour Annual 2013 2012 2011

42-001-0001 42-003-0002 42-003-0008 42-003-0064 42-003-0067 42-003-0093 42-003-1008 42-003-1301 42-003-3007 42-005-0001 42-007-0014 NARSTO SITE - ARENDTSVILLE 520 ORCHARD AVE, AVALON 301 39TH ST, BLDG #7, LAWRENCEVILLE 2743 WASHINGTON BLVD, LIBERTY 3640 OLD OAKDALE RD, SOUTH FAYETTE KUMMER RD, GOLF CLUBHOUSE, NORTH PARK PACIFIC & IDAHO AVE, HARRISON 600 ANDERSON ST, NORTH BRADDOCK 501 WADDELL AVE, CLAIRTON GLADE DR. & NOLTE RD. KITTANNING EIGHT STREET AND RIVER ALLEY 339 112 360 357 112 57 117 111 58 342 363 4

4 4 4 4 4 4 4 4 4 4 25.3 23.2 20.8 31.1 23.5 16.0 24.2 26.1 17.1 23.3 24.8 10.4

10.2 9.8 12.0 8.9 8.7 9.6 11.2 9.4 10.7 11.1 S

S S S S S S S 335 111 343 344 108 54 110 100 54 347 358 4

4 4 4 4 4 4 3 4 4 4 27.7 20.9 20.4 42.5 18.1 16.4 20.7 26.8 19.2 20.9 22.6 * 11.0

10.9 10.1 14.3 9.2 8.6 10.5 11.5 9.4 9.7 11.9 * S

S S S S S S S 336 205 346 339 107 50 104 100 49 312 364 4

4 4 4 4 3 3 3 3 3 4 30.2 29.8 27.3 38.0 30.6 25.6 29.8 33.7 30.3 28.2 29.8 *

*

*

*

* 12.2 13.1 11.1 14.0 10.6 9.0 11.6 12.3 10.7 12.1 11.7 *

*

* 28

25 23 37 24 19 25 29 22 24 26 Y Y Y Y Y Y Y Y N Y Y 11.2 11.4 10.3 13.4 9.6 8.8 10.6 11.7 9.8 10.8 11.6 Y

Y Y Y Y Y Y N N Y YUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM PRELIMINARY DESIGN VALUE REPORT Report Date: Jul. 23, 2014

Notes: 1. Computed design values are a snapshot of the data at the time the report was run (may not be all data for year). 2. Some PM2.5 24-hour DVs for incomplete data that are marked invalid here may be marked valid in the Official report due to additional analysis. 3. Annual Values not meeting completeness criteria are marked with an asterisk ('*'). Page 7 of 10 

### Pollutant: Standard Units: NAAQS Standard: Statistic: Statistic: Site-LevelPM2.5 - Local Conditions(88101) Micrograms/cubic meter (LC)(105) PM25 24-hour 2013 / PM25 Annual 2013 Annual Weighted Mean Annual 98th Percentile Level: Level: Design Value Year: 2013

REPORT EXCLUDES MEASUREMENTS WITH REGIONALLY CONCURRED EVENT FLAGS. 12 35 State Name: Pennsylvania Site_ID / STREET ADDRESS | | | Cred. Days Comp. Qrtrs Wtd.

Mean 98th Perctil Cert&

Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert& Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert&

Eval | | | Design Value Valid

Ind. | | | Design Value Valid

Ind. 24-Hour Annual 2013 2012 2011

42-011-0011 42-013-0801 42-017-0012 42-021-0011 42-027-0100 42-029-0100 42-041-0101 42-043-0401 42-045-0002 42-049-0003 42-069-2006 1059 Arnold Road 2ND AVE & 7TH ST ROCKVIEW LANE MILLER AUTO SHOP 1 MESSENGER ST PENN STATE UNIVERSITY - ARBORETUM SITE NEW GARDEN AIRPORT - TOUGHKENAMON IMPERIAL COURT 651 Gibson Blvd., Harrisburg, PA 17104 FRONT ST & NORRIS ST 10TH AND MARNE STREETS GEORGE ST TROOP AND CITY OF SCRANTON 363 346 364 345 363 351 364 343 336 348 334 4

4 4 4 4 4 4 4 4 4 4 32.7 32.9 31.3 29.6 21.1 27.2 36.5 35.0 30.5 25.6 24.0 10.6

12.2 10.3 11.9 8.6 10.2 10.6 12.0 11.5 12.2 9.2 364

346 361 342 361 330 365 351 288 346 344 4

4 4 4 4 4 4 4 3 4 4 26.3 26.4 28.2 28.0 22.5 24.1 29.2 28.1 31.1 25.3 19.7 * 11.3

11.7 10.7 11.6 9.8 9.8 10.9 11.6 12.8 11.2 8.3 362

345 364 332 355 293 362 352 336 346 354 4

4 4 4 4 3 4 4 4 4 4 26.4 30.1 29.7 32.5 28.5 33.8 30.4 31.2 28.6 26.7 23.4 * 11.3

11.8 11.5 13.4 9.5 13.2 11.5 12.1 12.9 11.4 9.3 28

30 30 30 24 28 32 31 30 26 22 Y Y Y Y Y Y Y Y N Y Y 11.0 11.9 10.8 12.3 9.3 11.1 11.0 11.9 12.4 11.6 9.0 Y Y Y Y Y Y Y Y Y Y YUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM PRELIMINARY DESIGN VALUE REPORT Report Date: Jul. 23, 2014

Notes: 1. Computed design values are a snapshot of the data at the time the report was run (may not be all data for year). 2. Some PM2.5 24-hour DVs for incomplete data that are marked invalid here may be marked valid in the Official report due to additional analysis. 3. Annual Values not meeting completeness criteria are marked with an asterisk ('*'). Page 8 of 10 

### Pollutant: Standard Units: NAAQS Standard: Statistic: Statistic: Site-LevelPM2.5 - Local Conditions(88101) Micrograms/cubic meter (LC)(105) PM25 24-hour 2013 / PM25 Annual 2013 Annual Weighted Mean Annual 98th Percentile Level: Level: Design Value Year: 2013

REPORT EXCLUDES MEASUREMENTS WITH REGIONALLY CONCURRED EVENT FLAGS. 12 35 State Name: Pennsylvania Site_ID / STREET ADDRESS | | | Cred. Days Comp. Qrtrs Wtd.

Mean 98th Perctil Cert&

Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert& Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert&

Eval | | | Design Value Valid

Ind. | | | Design Value Valid

Ind. 24-Hour Annual 2013 2012 2011

42-071-0007 42-075-0100 42-085-0100 42-089-0002 42-091-0013 42-095-0025 42-095-0027 42-101-0004 42-101-0047 42-101-0048 42-101-0055 ABRAHAM LINCOLN JR HIGH GROFFTOWN RD 125 Birch Road PA518 (NEW CASTLE ROAD) & PA418 HC 1, BOX 95-B NEAR RT 611 & BROOKDALE ROAD STATE ARMORY - 1046 BELVOIR RD WASHINGTON & CAMBRIA STS. FREEMANSBURG 2604 Schoenersville Road 1501 E. LYCOMING AVE. 500 SOUTH BROAD STREET-PARKING LOT (CHS) 3000 LEWIS ST. (NEAR BATH ST.) Philadelphia, PA. 19137 24TH & RITNER STREETS 365 342 358 342 364 365 349 54 349 73 323 4

4 4 4 4 4 4 3 4 1 4 33.6 35.6 22.9 21.7 27.2 31.7 33.5 35.1 26.3 35.3 29.8 *

* 11.3 11.2 9.8 9.4 9.3 10.5 9.9 9.2 9.8 10.9 11.5 * 366

338 359 348 362 351 321 47 337 0 325 4

4 4 4 4 4 3 3 4 0 4 28.9 33.3 22.5 19.3 21.8 27.6 26.0 21.1 21.8

24.8 *

*

* 12.6 14.2 10.9 7.9 9.7 11.5 10.9 9.7 10.2

10.3 *

* 364

260 361 331 365 340 348 57 308 0 335 4

3 4 4 4 4 4 4 4 0 4 29.9 29.3 25.7 20.3 27.6 35.2 29.8 23.7 27.9

30.6 *

* 12.0 11.4 10.1 6.4 10.3 14.5 11.2 8.9 11.4

11.4 * 31 33 24 20 26 32 30 27 25 35 28 Y N Y Y Y Y Y Y Y N Y 12.0 12.3 10.3 7.9 9.8 12.2 10.6 9.3 10.5 10.9 11.1 Y

Y Y Y Y Y Y Y Y N YUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM PRELIMINARY DESIGN VALUE REPORT Report Date: Jul. 23, 2014

Notes: 1. Computed design values are a snapshot of the data at the time the report was run (may not be all data for year). 2. Some PM2.5 24-hour DVs for incomplete data that are marked invalid here may be marked valid in the Official report due to additional analysis. 3. Annual Values not meeting completeness criteria are marked with an asterisk ('*'). Page 9 of 10 

### Pollutant: Standard Units: NAAQS Standard: Statistic: Statistic: Site-LevelPM2.5 - Local Conditions(88101) Micrograms/cubic meter (LC)(105) PM25 24-hour 2013 / PM25 Annual 2013 Annual Weighted Mean Annual 98th Percentile Level: Level: Design Value Year: 2013

REPORT EXCLUDES MEASUREMENTS WITH REGIONALLY CONCURRED EVENT FLAGS. 12 35 State Name: Pennsylvania Site_ID / STREET ADDRESS | | | Cred. Days Comp. Qrtrs Wtd.

Mean 98th Perctil Cert&

Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert& Eval | | | Cred. Days Comp. Qrtrs 98th Perctil Wtd.

Mean Cert&

Eval | | | Design Value Valid

Ind. | | | Design Value Valid

Ind. 24-Hour Annual 2013 2012 2011

42-101-0057 42-101-1002 42-125-0005 42-125-0200 42-125-5001 42-125-5200 42-129-0008 42-133-0008 240 Spring Garden Street 5200 PENNYPACK PARK PHILADELPHIA, PA. 19136 CHARLER01 WASTE TREATMENT PLANT MCCARRELL AND FAYETTE STS HILLMAN STATE PARK - KINGS CREEK ROAD 220 Meddings Road DONOHOE ROAD - PENN DOT MAINT DIST BLDG HILL ST. 344 258 346 365 349 333 362 365 4

3 4 4 4 3 4 4 25.5 23.7 22.2 21.2 20.6 17.9 21.6 30.6 *

* 10.5 9.4 10.6 9.7 8.7 8.4 9.7 10.2 *

* 328

311 351 366 348 145 363 365 4

4 4 4 4 1 4 4 23.3 23.5 23.4 20.6 15.8 18.4 22.8 28.4 * 10.1

10.3 10.4 10.5 6.9 9.0 10.1 12.0 * 345

302 317 364 343 0 309 349 4

4 3 4 4 0 3 4 30.5 19.3 28.6 27.4 12.3

32.8 28.0 *

*

* 11.4 8.9 12.0 10.8 5.9

13.7 11.6 *

* 26

22 25 23 16 18 26 29 Y N Y Y Y N N Y 10.7

9.5 11.0 10.3 7.2 8.7 11.1 11.3 Y

N Y Y Y N Y YUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM PRELIMINARY DESIGN VALUE REPORT Report Date: Jul. 23, 2014

Notes: 1. Computed design values are a snapshot of the data at the time the report was run (may not be all data for year). 2. Some PM2.5 24-hour DVs for incomplete data that are marked invalid here may be marked valid in the Official report due to additional analysis. 3. Annual Values not meeting completeness criteria are marked with an asterisk ('*'). Page 10 of 10 M N

S

U

X Y The monitoring organization has revised data from this monitor since the

most recent certification letter received from the state. The certifying agency has submitted the certification letter and required summary reports, but the certifying agency and/or EPA has determined that issues regarding the quality of the ambient concentration data cannot be resolved due to data completeness, the lack of performed quality assurance checks or the results of uncertainty statistics shown in the AMP255 report or the certification and quality assurance report. The certifying agency has submitted the certification letter and required summary reports. A value of "S" conveys no Regional assessment regarding data quality per se. This flag will remain until the Region provides an "N" or "Y" concurrence flag. Uncertified. The certifying agency did not submit a required certification letter and summary reports for this monitor even though the due date has passed, or the state's certification letter specifically did not apply the certification to this monitor. Certification is not required by 40 CFR 58.15 and no conditions apply to be the basis for assigning another flag value The certifying agency has submitted a certification letter, and EPA has no unresolved reservations about data quality (after reviewing the letter, the attached summary reports, the amount of quality assurance data submitted to AQS, the quality statistics, and the highest reported concentrations). MEANING CERTIFICATION EVALUATION AND CONCURRENCE FLAG MEANINGS

FLAG