## SAMPLE SUMMARY

HOD2704.79

SAMPLED SAMP NO 

### # 

### SAMPLE'" CLIENT SAMPLE ID DATE TIME
LOKON 001 MOO31 UNIT 2 RUN 1 SET 1 TENAX 04/23/10 LOKIC 002 MOO3l UNIT 2 RUN 1 SET 1 TEN/CHAR 04/23/10 LOKID 003 MOO3! UNIT 2 RUN 1 SET 2 TENAX 04/23/10 LOKIF 00. MOO31 UNIT 2 RUN 1 SET 2 TEN/CHAR 04/23/10 LOKIJ 005 MOO31 UNIT 2 RUN 1 SET 3 TENAX 04/23/10 LOKIP 006 MOO3! UNIT 2 RUN 1 SET 3 TEN/CHAR 04/23/10 LOKIO 009 MOO31 UNIT 2 RUN 1 CONO 04/23/10 LOKll 010 MOO3! UNIT 2 RUN 2 SET 1 TENAX 04/23/10 LOK13 011 MOO3! UNIT 2 RUN 2 SET 1 TEN/CHAR 04/23(10 LOK16 012 MOO31 UNIT 2 RUN 2 SET 2 TENAX 04/23/10 LOK19 013 MOO31 UNIT 2 RUN 2 SET 2 TEN/CHAR 04/23/10 LOK2C 014 MOO31 UNIT 2 RUN 2 SET 3 TENAX 04/23/10 LOK2E 015 MOO3! UNIT 2 RUN 2 SET 3 TEN/CHAR 04/23/10 LOK2J 018 MOO3! UNIT 2 RUN 2 COND 04/23/10 LOK2M 019 MOO31 UNIT 2 RUN 3 SET 1 TENAX 04/23/10 LOK2T 020 MOO31 UNIT 2 RUN 3 SET 1 TEN/CHAR 04/23/10 LOK2V 021 

### MOO3! UNIT 2 RUN 3 SET 2 TBNAX 04/23/10 LOK2W 022 MOO31 UNIT 2 RUN 3 SET 2 TEN/CHAR 04/23/10 LOK20 023 MOO31 UNIT 2 RUN 3 SET 3 TENAX 04/23/10 LOK21 024 MOO31 UNIT 2 RUN 3 SET 3 TEN/CHAR 04/23/10 LOK22 025 MOO31 UNIT 2 RUN 3 SET 4 TENAX 04/23/10 LOK24 026 M0031 UNIT 2 RUN 3 SET

# • TEN/CHAR 04/23/10 LOK25 027 M0031 UNIT 2 RUN 3 COND 04/23/10 LOK28 028 M0031 UNIT 2 RUN FB TENAX 04/23/10 LOK29 029 M0031 UNIT 2 RUN FB TEN/CHAR 04/23/10 LOK3A 030 MOO31 UNIT 2 RUN FB COND 04/23/10

NOTE (S) :

- The analytical results ofthe sample! listed above arepresented on the following pages.

- All calculalions are performed before rounding tD**a~oid** round·offerrors in calculated results.
•Result!; noted as ·'ND·· were not dQleCled at orabove the stated limit.

· This**re~orl** must not be reproduced. except in full. without the written approval ofthe laboratory.
•R.sults for the follOWing parameters ere never reported on adry weight basis: color.**corrosi~ity.** density. fiashpoint. ignilability. layers. odor. paint filter test pH. porosity pressure. reaClivity. redox polenlial, specific gravity. spot lesls, solids. solubilily. lemperature. viscosity. and weight.

### AirNova, Inc.
Client Sample 1D: M0031 UNIT 2 RUN 1 SET 1 TENAX

Lot-Sample 

### #

... : HOD270479-001 Date Sampled

... : 04/23(10 Prep Date

...... : 04(30/10 Prep Batch 

### #

... : 0119073 Dilution Factor: 1

PARAMETER 

### Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane cis-l,2-Dichloroethene trans-1,2-Dichloroethene 1,1-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane cis-l,3-Dichloropropene trans-l,3-Dichloropropene l,l-Dichloropropene GC/MS volatiles
Work Order 

### #

... : LOKONlAA Date Received

.. : 04/27(10 Analysis Date

.. : 04/30/10
Method........• : SW846 VOST
REPORTING RESULT 

### LIMIT 0.27 B 0.10 0.044 0.010 NO 

### 0.010 NO 

### 0.025 NO 

### 0.010 NO 

### 0.025 0.0085 J 

### 0.050 NO 

### 0.10 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 0.21 0.010 0.0019 J 

### 0.010 NO 

### 0.010 NO 

### 0.025 NO 

### 0.050 NO 

### 0.010 0.019 J,B 

### 0.050 NO 

### 0.010 NO 

### 0.010 NO 

### 0.050
NO 

### 0.025 NO 

### 0.025 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.025 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 (Continued 

### on next page) Matrix

.........: AIR

UNITS MOL U9 

### 0.030 u9 

### 0.0035 u9 

### 0.0020 u9 

### 0.0028 U9 

### 0.0013 U9 

### 0.010 U9 

### 0.0059 u9 

### 0.10 u9 

### 0.0010 U9 

### 0.0010 U9 

### 0.0011 u9 

### 0.0019 u9 

### 0.0012 u9 

### 0.0010 U9 

### 0.0020 u9 

### 0.0062 u9 

### 0.0011 u9 

### 0.0025 U9 

### 0.0012 U9 

### 0.0014 U9 

### 0.013
u9 

### 0.0014 u9 

### 0.0021 U9 

### 0.0018 U9 

### 0.0014 U9 

### 0.0015 u9 

### 0.0024 u9 

### 0.0010 u9 

### 0.0017 U9 

### 0.0010 U9 0 

### .0020 u9 0 

### .0015 u9 0 

### .0017 u9 0 

### .0014 U9 

### 0.0010 U9 

### 0.0017 U9 

### 0.0012 u9 

### 0.0010AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN I SET I TENAX
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-001 Work Order 

### #

... : LOKONlAA
REPORTING PARAMETER RESULT LIMIT Ethylbenzene 0.0010 J 0.010 Hexachlorobutadiene NO 0.025 2-Hexanone NO 0.10 Isopropylbenzene NO 0.010 p-Isopropyltoluene NO 0.010 Methylene chloride 0.021 J,B 0.025 4-Methyl-2-pentanone NO 0.10 Naphthalene NO 0.025 n-Propylbenzene NO 0.010 Styrene NO 0.010 1,1,1,2-Tetrachloroethane NO 0.010 1,1,2,2-Tetrachloroethane NO 0.025 Tetrachloroethene 0.0028 J 0.010 Toluene 0.0071 J 0.010 1,2,3-Trichlorobenzene NO 0.025 1,2,4-Trichloro- NO 0.025 benzene 1,1,1-Trichloroethane NO 0.025 1,1,2-Trichloroethane NO 0.025 Trichloroethene NO 0.010 Trichlorofluoromethane 0.026 J 0.050 1,2,3-Trichloropropane NO 0.025 1,2,4-Trimethylbenzene NO 0.010 1,3,5-Trimethylbenzene NO 0.010 Vinyl chloride NO 0.010 m-xylene 

### & p-Xylene 0.0028 J 0.020 a-xylene NO 0.010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 90 (50 123) 1,2-Dichloroethane-d4 78 (50 128) Toluene-d8 91 (50 120) Bromofluorobenzene 76 (50 120) NOTE(S) : B Method blankcontamination. The essociated method blankcontains the**t~rsel**en"lyte at areportable level. J EstimalCd relull. Result il leIS than RL. Matrix

......... : AIR

UNITS MOL ug 0.0010 ug 0.0025 ug 0.0068 ug 0.0010 ug 0.0010 ug 0.0022 ug 0.10 ug 0.010 ug 0.0010 ug 0.0013 ug 0.0011 ug 0.0029 ug 0.0011 ug 0.0010 ug 0.0010 ug 0.0016

ug 0.0010 ug 0.010 ug 0.0022 ug 0.0017 ug 0.025 ug 0.0015 ug 0.0018 ug 0.0021 ug 0.0020 ug 0.0010AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 1 SET 1 TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... , HOD270479-002 Work Order 

### #

... , LOK1C1AA Matrix

......... : AIR Date Sampled

... : 04/23/10 Date Received

.. : 04/27/10 Prep Date

...... : 04/30/10 Analysis Date

.. : 04/30/10 Prep Batch fL

.. : 0119073 Dilution Factor: 1 Method

......... : SW846 VOST
REPORTING PARAMETER RESULT LIMIT UNITS MDL Acetone 0.15 B 0.10 

### u9 0.030 Benzene NO 0.010 

### u9 0.0035 Bromobenzene NO 0.010 

### u9 0.0020 Bromochloromethane NO 0.025 

### U9 0.0028 Bromodichloromethane NO 0.010 

### u9 0.0013 Bromoform ND 0.025 

### u9 0.010 Bromomethane 0.023 J 0.050 

### u9 0.0059 2-Butanone ND 

### o. 10 u9 0.10 n-Butylbenzene ND 

### o. 010 U9 0.0010 sec-Butylbenzene ND 

### 0 .010 

### U9 0.0010 tert-Butylbenzene ND 

### 0 .010 

### u9 0.0011 Carbon disulfide ND 0.010 

### u9 0.0019 Carbon tetrachloride ND 0.010 

### u9 0.0012 Chlorobenzene ND 0.010 

### U9 0.0010 Chlorodibromomethane ND 0.025 

### u9 0.0020 Chloroethane ND 0.050 

### u9 0.0062 Chloroform NO 0.010 

### u9 0.0011 Chloromethane 0.054 B 0.050 

### U9 0.0025 2-Chlorotoluene NO 0.010 

### U9 0.0012 4-Chlorotoluene ND 

### 0 .010 

### u9 0.0014 1,2-Dibromo-3-chloro- ND 0.050 

### u9 0.013 propane 1,2-Dibromoethane ND 0.025 

### u9 0.0014 Dibromomethane ND 0.025 

### U9 0.0021 1,2-Dichlorobenzene ND 0.010 

### u9 0.0018 1,3-Dichlorobenzene ND 0.010 

### u9 0.0014 1,4-Dichlorobenzene NO 0.010 

### u9 0.0015 Dichlorodifluoromethane 0.0056 J 0.025 

### u9 0.0024 1,1-Dichloroethane ND 0.010 

### u9 0.0010 1,2-Dichloroethane NO 0.010 

### U9 0.0017 cis-1,2-Dichloroethene NO 0.010 

### U9 0.0010 trans-1,2-Dichloroethene ND 0.010 

### u9 0.0020 1,1-Dichloroethene ND 0.010 

### u9 0.0015 1,2-Dichloropropane ND 0.010 

### u9 0.0017 l,3-Dichloropropane ND 0.010 

### U9 0.0014 2,2-Dichloropropane NO 0.010 

### U9 0.0010 cis-1,3-Dichloropropene NO 0.010 

### U9 0.0017 trans-1,3-Dichloropropene ND 0.010 

### u9 0.0012 1,1-Dichloropropene ND 0.010 

### u9 0.0010 (Continued on next page)AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 1 SET 1 TEN/CHAR
GC/MS volatiles Lot-Sample 

### #

... : HOD270479-002 Work Order 

### #

... : LOK1C1AA
REPORTING PARAMETER RESULT LIMIT Ethylbenzene ND 0.010 Hexachlorobutadiene ND 0.025 2-Hexanone ND 0.10 Isopropylbenzene ND 0.010 p-Isapropyltoluene ND 0.010 Methylene chloride 0.041 B 0.025 4-Methyl-2-pentanone ND 0.10 Naphthalene ND 0.025 n-Propylbenzene ND 0.010 Styrene ND 0.010 1,1,1,2-Tetrachloroethane ND 0.010 1,1,2,2-Tetrachloroethane ND 0.025 Tetrachlaroethene 0.0018 J 0.010 Toluene 0.0096 J 0.010 1,2,3-Trichlorobenzene ND 0.025 1,2,4-Trichloro- ND 0.025 benzene l,l,l-Trichloroethane ND 0.025 1, 1, 2-Trichloroethane ND 0.025 Trichloroethene ND 0.010 Trichlorofluoromethane 0.0025 J 0.050 1,2,3-Trichloropropane ND 0.025 1,2,4-Trimethylbenzene ND 0.010 1, 3, 5-Trimethylbenzene ND 0.010 Vinyl chloride ND 0.010 m-Xylene 

### & p-xylene ND 

### o. 020 a-Xylene ND 0.010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibramofluoromethane 90 {50 l23} 1,2-Dichloroethane-d4 7, {50 128} Toluene-d8 87 (50 120) Bromofluorobenzene 75 (50 120) NOTE(S) : B Melhoo blankcontamination The associated method blank**conlain~**the IIIrgetanalyt. al areportBble level. J ESlimaled resull. Result is le'ls than RL. Matrix

.....__ .. : AIR

tmITS MDL 

### ug 0.0010 

### ug 0.0025 

### ug 0.0068 

### ug 0.0010 

### ug 0.0010 

### ug 0.0022 

### ug 0.10 

### ug 0.010 

### ug 0.0010 

### ug 0.0013 

### ug 0.0011 

### ug 0.0029 

### ug 0.0011 

### ug 0.0010 

### ug 0.0010 

### ug 0.0016



### ug 0.0010 

### ug 0.010 

### ug 0.0022 

### ug 0.0017 

### ug 0.025 

### ug 

## a.0015 

### ug 0.0018 

### ug 0.0021 

### ug 0.0020 

### ug 0.0010AirNova. Inc.
Client Sample ID: M003l UNIT 2 RUN 1 SET 2 TENAX

Lot-Sample 

### #

... : HOD270479-003 Date Sampled

... : 04/23/10 Prep Date

...... : 04/30/10 Prep Batch 

### #

... : 0119073 Dilution Factor: 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluenel,2-Dibromo-3-chloropropane l,2-Dibromoethane Dibromomethane l,2-Dichlorobenzene l,3-Dichlorobenzene l,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane l,2-Dichloroethane cis-1,2-Dichloroethene trans-1,2-Dichloroethene l,l-Dichloroethene l,2-Dichloropropane l,3-Dichloropropane 2,2-Dichloropropane ciS-l,3-Dichloropropene trans-l,3-Dichloropropene 1,1-Dichloropropene GC/MS Volatiles
Work Order #

... : LOK1D1AA Date Received

.. : 04/27/10 Analysis Date

.. : 04/30/10
Method

......... : SW846 VOST
REPORTING RESULT LIMIT 0.69 B 0.10 0.065 0.010 ND 0.010 ND 0.025 ND 0.010 ND 0.025 0.0096 

### J 0.050 ND 0.10 ND 0.010 ND 0.010 ND 0.010 0.19 0.010 ND 0.010 ND 0.010 ND 0.025 ND 0.050 ND 0.010 0.014 

### J,B 0.050 ND 0.010 ND 0.010 ND 0.050
ND 0.025 ND 0.025 ND 0.010 ND 0.010 ND 0.010 ND 0.025 ND 0.010 ND 0.010 ND 0.010 ND 0.010 ND 0.010 ND O. 010 ND 0.010 ND 0.010 ND 0.010 ND 0.010 ND 0.010 (Continued on next page) Matrix...•..... : AIR

UNITS MDL ug 0.030 ug 0.0035 ug 0.0020 ug 0.0028 ug 0.0013 ug 0.010 ug 0.0059 ug 0.10 ug 0.0010 ug 0.0010 ug 0.0011 ug 0.0019 ug 0.0012 ug 0.0010 ug 0.0020 ug 0.0062 ug 0.0011 ug 0.0025 ug 0.0012 ug 0.0014 ug 0.013

ug 0.00l4 ug 0.0021 ug 0.0018 ug 0.0014 ug 0.0015 ug 0.0024 ug 0.0010 ug 0.0017 ug 0.0010 ug 0.0020 ug 0.0015 ug 0.0017 ug 0.0014 ug 0.0010 ug 0.0017 ug 0.0012 ug 0.0010AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 1 SET 2 TENAX
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-003 Work Order 

### #

... : LOKlDlAA
REPORTING PARAMETER RESULT LIMIT Ethylbenzene ND 0.010 Hexachlorobutadiene ND 0.025 2-Hexanone ND 0.10 Isopropylbenzene ND 0.010 p-Isopropyltoluene ND 0.010 Methylene chloride 0.10 B 0.025 4-Methyl-2-pentanone ND 0.10 Naphthalene ND 0.025 n-Propylbenzene ND 0.010 Styrene ND 0.010 1,1,1,2-Tetrachloroethane ND 0.010 1,1,2,2-Tetrachloroethane ND 0.025 Tetrachloroethene ND 0.010 Toluene 0.0050 J 0.010 1,2,3-Trichlorobenzene ND 0.025 1,2,4-Trichloro- ND 0.025 benzene l,l,l-Trichloroethane ND 0.025 1,1,2-Trichloroethane ND 0.025 Trichloroethene ND 0.010 Trichlorofluoromethane 0.012 J 0.050 1,2,3-Trichloropropane ND 0.025 1,2,4-Trimethylbenzene ND 0.010 1,3,5-Trimethylbenzene ND 0.010 vinyl chloride ND 0.010 m-Xylene & p-Xylene ND O. 020 o-Xylene ND 0.010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 91 (50 123) 1,2-Dichloroethane-d4 77 (50 l2B) Toluene-dB 91 (50 120) Bromofluorobenzene 73 (50 120) NOTE(S) : B**Mel~o~** blankcontamination. The a,seciated method blankeontaiM the target anBlyt! at a reponabl! level. J Estimated result. Result is less than RL. Matrix

......... : AIR

UNITS MDL ug 0.0010 ug 0.0025 ug 0.0068 ug 0.0010 ug 0.0010 ug 0.0022 ug 0.10 ug 0.010 ug 0.0010 ug 0.0013 ug 0.0011 ug o .0029 ug 0.0011 ug 0.0010 ug 0.0010 ug 0.0016

ug 0.0010 ug 0.010 ug 0.0022 ug 0.0017 ug 0.025 ug 0.0015 ug 0.0018 ug 0.0021 ug 0.0020 ug 0.0010AirNova. Inc.
Client Sample ID: M0031 UNIT 2 RUN 1 SET 2 TEN/CHAR

Lot-Sample 

### #

... : HOD270479-004 Date Sampled

... : 04/23/10 Prep Date

...... : 04/30/10 Prep Batch 

### #

... : 0119073 Dilution Factor: 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromadichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane 1.2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenz.ene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,1-Dichloroethene l,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane cis-1,3-Dichloropropene trans-l,3-Dichloropropene 1,1-Dichloropropene GC/MS Volatiles
Work Order 

### #

... : LOK1F1AA Date Received

.. : 04/27/10 Analysis Date

.. : 04/30/10
Method

......... : SW846 vaST
REPORTING RESULT LIMIT 0.52 B 0.10 

### NO 0.010 

### NO 0.010 

### NO 0.025 

### NO 0.010 

### NO 0.025 0.030 J 0.050 

### NO 0.10 

### NO 0.010 

### No 0.010 

### NO 0.010 0.0052 J 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.025 

### NO 0.050 

### NO 0.010 0.046 J,B 0.050 

### NO 0.010 

### No 0.010 

### NO 0.050


### NO 0.025 

### NO 0.025 

### NO 0.010 

### NO 0.010 

### NO 0.010 0.0031 J 0.025 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 (Continued 

### on next page) Matrix

......... : AIR

UNITS**MDJ~** 

### u9 0.030 

### U9 0.0035 

### U9 0.0020 

### U9 0.0028 

### u9 0.0013 

### u9 0.010 

### U9 0.0059 

### U9 0.10 

### u9 0.0010 

### u9 0.0010 

### u9 0.0011 

### U9 0.0019 

### U9 0.0012 

### U9 0.0010 

### u9 0.0020 

### U9 0.0062 

### U9 0.0011 

### U9 0.0025 

### u9 0.0012 

### u9 0.0014 

### u9 0.013


### U9 0.0014 

### U9 0.0021 

### u9 0.0018 

### u9 0.0014 

### u9 0.0015 

### U9 0.0024 

### U9 0.0010 

### u9 0.0017 

### u9 0.0010 

### u9 0.0020 

### U9 0.0015 

### U9 0.0017 

### U9 0.0014 

### u9 0.0010 

### u9 0.0017 

### u9 0.0012 

### u9 0.0010AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 1 SET 2 TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-004 Work Order 

### #

... : LOK1F1AA
REPORTING PARAMETER RESULT LIMIT Ethylbenzene NO 0.010 Hexachlorobutadiene NO 0.025 2-Hexanone NO 0.10 Isopropylbenzene NO 0.010 p-Isopropyltoluene NO 0.010 Methylene chloride 0.020 

### J,B 0.025 4-Methyl-2-pentanone NO 0.10 Naphthalene NO 0.025 n-Propylbenzene NO 0.010 Styrene NO 0.010 1,1,1,2-Tetrachloroethane ND 0.010 1,1,2,2-Tetrachloroethane ND 0.025 Tetrachloroethene NO 0.010 Toluene 0.0071 

### J 0.010 1,2,3-Trichlorobenzene ND 0.025 1,2,4-Trichloro- ND 0.025 benzene l,l,l-Trichloroethane ND 0.025 1,1,2-Trichloroethane ND 0.025 Trichloroethene ND 0.010 Trichlorofluoromethane ND 0.050 1,2,3-Trichloropropane ND 0.025 1,2,4-Trimethylbenzene ND 0.010 1,3,5-Trimethylbenzene ND 0.010 Vinyl chloride ND 0.010 m-Xylene 

### & p-Xylene ND 0.020 o-Xylene ND 0.010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 

### 97 (50 123) 1,2-Dichloroethane-d4 81 (50 128) Toluene-d8 101 (50 120) Bromofluorobenzene 81 (50 120) NOTE(Sj: B Method blankCOIllaminatlon. The asso-cialed ml!lhod blankconlains Ihe largel analyte al a rllporlable level. J ESlimaled result. Resuilis less than RL. Matrix

........_: AIR

UNITS MOL 

### U9 0.0010 

### u9 0.0025 

### u9 0.0068 

### u9 0.0010 

### U9 0.0010 

### U9 0.0022 

### U9 0.10 

### u9 0.010 

### u9 0.0010 

### u9 0.0013 

### U9 0.0011 

### U9 0.0029 

### u9 0.0011 

### u9 0.0010 

### U9 0.0010 

### U9 0.0016


### u9 0.0010 

### u9 0.010 

### U9 0.0022 

### U9 0.0017 

### u9 0.025 

### u9 0.0015 

### u9 0.0018 

### U9 0.0021 

### U9 0.0020 

### U9 0.0010AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 1 SET 3 TENAX

Lot-Sample 

### #

... : HOD270479-005 Date Sampled

... : 04/23/10 Prep Date

...... : 04/30/10 Prep Batch 

### #

... : 0119073 Dilution Factor: 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluenel,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane l,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane l,l-Dichloroethane 1,2-Dichloroethane cis-l,2-Dichloroethene trans-1,2-Dichloroethene 1,1-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane ciS-1,3-Dichloropropene trans-1,)-Dichloropropene l,l-Dichloropropene CC/MS Volatiles
Work Order 

### #

... : LOK1JlAA Date Received

.. : 04/27/10 Analysis Date

.. : 04/30/10
Method

......... : SW846 vaST
REPORTING RESULT LIMIT 0.096 J,B 0.10 0.052 0.010 

### NO 0.010 

### NO 0.025 

### NO 0.010 

### NO 0.025 0.0090 J 0.050 

### NO 0.10 

### NO 0.010 

### NO 0.010 

### NO 0.010 0.14 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.025 

### NO 0.050 

### NO 0.010 0.0098 J,B 0.050 

### NO 0.010 

### NO 0.010 

### NO 0.050


### NO 0.025 

### NO 0.025 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.025 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 

### NO 0.010 (Continued on next page) Matrix

......... ; AIR

UNITS 

### MOL u9 0.030 

### u9 0.0035 

### u9 0.0020 

### U9 0.0028 

### U9 0.0013 

### u9 0.010 

### u9 0.0059 

### u9 0.10 

### U9 0.0010 

### U9 0.0010 

### u9 0.0011 

### u9 0.0019 

### u9 0.0012 

### U9 0.0010 

### u9 0.0020 

### u9 0.0062 

### u9 0.0011 

### u9 0.0025 

### U9 0.0012 

### U9 0.0014 

### u9 0.013


### u9 0.0014 

### u9 0.0021 

### U9 0.0018 

### u9 0.0014 

### u9 0.0015 

### u9 0.0024 

### u9 0.0010 

### U9 0.0017 

### U9 0.0010 

### u9 0.0020 

### u9 0.0015 

### u9 0.0017 

### U9 0.0014 

### U9 0.0010 

### U9 0.0017 

### u9 0.0012 

### u9 0.0010AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 1 SET 3 TENAX
GC/MS volatiles Lot-Sample 

### #

... : HOD270479-005 Work Order 

### #.

__ : LOKIJlAA Mat.rix

......... : AIR
REPORTING PARAMETER RESULT LIMIT UNITS MOL Et.hylbenzene NO 0.010 u9 0.0010 Hexachlorobut.adiene NO 0.025 u9 0.0025 2-Hexanone NO 0.10 u9 0.0068 Isopropylbenzene NO 0.010 U9 0.0010 p-Isopropyltoluene NO 0.010 U9 0.0010 Methylene chloride 0.025 B 0.025 u9 0.0022 4-Methyl-2-pentanone NO 0.10 u9 0.10 Naphthalene NO 0.025 u9 0.010 n-Propylbenzene NO 0.010 U9 0.0010 Styrene NO 0.010 U9 0.0013 1,1,1,2-Tetrachloroethane NO 0.010 u9 0.0011 1,1,2,2-Tetrachloroethane NO 0.025 u9 0.0029 Tetrachloroethene NO 0.010 u9 0.0011 Toluene 0.027 0.010 U9 0.0010 l,2,3-Trichlorobenzene NO 0.025 U9 0.0010 1,2,4-Trichloro- NO 0.025 u9 0.0016 benzene 1,1,1-Trichloroethane NO 0.025 u9 0.0010 1,1,2-Trichloroethane NO 0.025 U9 0.010 Trichloroethene NO 0.010 u9 0.0022 Trichlorofluoromethane 0.019 J 0.050 u9 0.0017 1,2,3-Trichloropropane NO 0.025 u9 0.025 1,2,4-Trimethylbenzene NO 0.010 u9 0.0015 l,3,S-Trimethylbenzene NO 0.010 U9 0.0018 Vinyl chloride NO 0.010 U9 0.0021 m-Xylene & p-Xylene NO 0.020 u9 0.0020 a-Xylene NO 0.010 u9 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 98 (50 123) l,2-Dichloroethane-d4 92 (50 128) Toluene-d8 90 (50 120) Bromofluorobenzene 78 (50 120) NOTE(S) : 

# , Estimated result. Result is less than RL. B Method blank eontaminalion. The associated metl10d blank contains the larget an.lyle atareportable level.AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 1 SET 3 TEN/CHAR

Lot-Sample 

### #

... : HOD270479-006 Date Sampled

... : 04/23/10 Prep Date

...... ; 04/30/10 Prep Batch 

### #

... ; 0119073 Dilution Factor; 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane cis-l,2-Dichloroethene trans-1,2-Dichloroethene 1,1-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane cis-l,3-Dichloropropene trans-1,3-Dichloropropene 1,1-Dichloropropene GC/MS Volatiles
Work Order 

### #

... : LOK1P1AA Date Received

.. : 04/27/10 Analysis Date

.. ; 04/30/10
Method

......_•. ; SW846 VOST
REPORTING RESULT LIMIT 0.088 J,B 0.10 NO 0.010 NO 0.010 NO 0.025 NO 0.010 NO 0.025 0.037 J 0.050 NO 0.10 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.025 NO 0.050 NO 0.010 0.036 J,B 0.050 NO 0.010 NO 0.010 NO 0.050
NO 0.025 NO 0.025 NO 0.010 NO 0.010 NO 0.010 0.0028 J 0.025 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 (Continued 

### on next page) Matrix

......... ; AIR

UNITS MOL ug 0.030 ug 0.0035 ug 0.0020 ug 0.0028 ug 0.0013 ug 0.010 ug 0.0059 ug 0.10 ug 0.0010 ug 0.0010 ug O. 0011 ug 0.0019 ug 0.0012 ug 0.0010 ug 0.0020 ug 0.0062 ug 0.0011 ug 0.0025 ug 0.0012 ug O. 0014 ug O. 013

ug 0.0014 ug 0.0021 ug 0.0018 ug 0.0014 ug 0.0015 ug 0.0024 ug 0.0010 ug 0.0017 ug 0.0010 ug 0.0020 ug 0.0015 ug 0.0017 ug 0.0014 ug 0.0010 ug 0.0017 ug 0.0012 ug 0.0010AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 1 SET 3 TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... ; HOD270479-006 Work Order #

... : LOKIPlAA Matrix

......... ; AIR
REPORTING PARAMETER RESULT LIMIT UNITS 

### MOL Ethylbenzene 

### NO 0.010 ug 0.0010 Hexachlorobutadiene 

### NO 0.025 ug 0.0025 2-Hexanone 

### NO 0.10 ug 0.0068 Isopropylbenzene 

### NO 0.010 ug 0.0010 p-Isopropyltoluene 

### NO 0.010 ug 0.0010 Methylene chloride 0.0078 J,B 0.025 ug 0.0022 4-Methyl-2-pentanone 

### NO 0.10 ug 0.10 Naphthalene 

### NO 0.025 ug 0.010 n-Propylbenzene 

### NO 0.010 ug 0.0010 Styrene 

### NO 0.010 ug 0.0013 l,l,1,2-Tetrachloroethane 

### NO 0.010 ug 0.0011 l,l,2,2-Tetrachloroethane 

### ND 0.025 ug 0.0029 Tetrachloroethene 

### NO 0.010 ug 0.0011 Toluene 0.0029 J 0.010 ug 0.0010 1,2,3-Trichlorobenzene 

### NO 0.025 ug 0.0010 1,2,4-Trichloro- 

### NO 0.025 ug 0.0016 benzene l,l,l-Trichloroethane 

### NO 0.025 ug 0.0010 1,1,2-Trichloroethane 

### NO 0.025 ug 0.010 Trichloroethene 

### NO 0.010 ug 0.0022 Trichlorofluoromethane 

### NO 0.050 ug 0.0017 1,2,3-Trichloropropane 

### NO 0.025 ug 0.025 1,2,4-Trimethylbenzene 

### NO 0.010 ug 0.0015 1,3,5-Trimethylbenzene 

### NO 0.010 ug 0.0018 vinyl chloride 

### NO 0.010 ug 0.0021 m-Xylene 

### & p-Xylene 

### NO 0.020 ug 0.0020 o-Xylene 

### NO 0.010 ug 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 94 (50 123) 1,2-Dichloroethane-d4 83 (50 128) Toluene-d8 99 (50 120) Bromofluorobenzene 

### 82 (50 120) NOTE(S) ; J ESlimaled ,.,ull. Resull**i~** 1",1 th.n RL. B Melncd blank contamination. Th. ",sociated method bl.nk conLains the tarSjetlnalyte at a '!portable level.AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 1 COND

Lot-Sample 

### #

... : HOD270479-009 Date Sampled

... : 04/23/10 Prep Date

...... : 05/01/10 Prep Batch 

### #

... : 0119312 Dilution Factor: 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibrornomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluorornethane l,l-Dichloroethane 1,2-Dichloroethane cis-l,2-Dichloroethene trans-l,2-Dichloroethene l,l-Dichloroethene 1,2-Dichloropropane l,3-Dichloropropane 2,2-Dichloropropane cis-l,3-Dichloropropene trans-l,3-Dichloropropene 1,1-Dichloropropene GC/MS volatiles
Work Order 

### #

... : LOKI0lAA Date Received

.. : 04/27/10 Analysis Date

.. : 05/01/10 Matrix

......... : WATER

Method

......._.: SW846 8260B
REPORTING RESULT LIMIT UNITS MOL 63. E 

# ,. ug/L 2 .• 0.088 J 1.. ug/L 0.025 NO 1.0 ug/L 0.051 1.7 1.. ug/L 0.097 NO 1.0 ug/L 0.065 NO 1.0 ug/L 0.50 NO 2.0 ug/L 0.14 13 5.0 ug/L 1.3 NO 1.0 ug/L 0.038 NO 1.0 ug/L 0.034 NO 1.0 ug/L 0.035 NO 1.0 ug/L 0.039 NO 1.0 ug/L 0.054 NO 1.0 ug/L 0.041 NO 1.0 ug/L 0.11 NO 2.0 ug/L 0.13 0.23 J 

# 1.. ug/L 0.036 0.099 J 2.0 ug/L 0.064 NO 1.0 ug/L 0.050 NO 1.0 ug/L 0.050 NO 2.0 ug/L 0.33
NO 1.0 ug/L 0.094 NO 1.0 ug/L 0.097 NO 1.0 ug/L 0.035 NO 1.0 ug/L 0.043 NO 1.0 ug/L 0.049 NO 2.0 ug/L 0.48 NO 1.0 ug/L 0.034 NO 1.0 ug/L 0.046 NO 1.0 ug/L 0.054 NO 1.0 ug/L 0.036 NO 1.0 ug/L 0.066 NO 1.0 ug/L 0.048 NO 1.0 ug/L 0.036 NO 1.0 ug/L 0.053 NO 1.0 ug/L 0.059 NO 1.0 ug/L 0.056 NO 1.0 ug/L 0.042 (Continued 

### on next page)AirNova, 

### Inc.
Client Sample ID: MOO]1 UNIT 2 RUN 1 COND
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-009 Work Order #

... : 

### LOK101AA Matrix..•...... : WATER
REPORTING PARAMETER RESULT LIMIT UNITS MOL 

### Ethylbenzene NO 1.0 

### ug/L 0.040 Hexachlorobutadiene NO 2.0 

### ug/L 0.19 2-Hexanone 1.8 J 5.0 

### ug/L 0.25 Isopropylbenzene NO 1.0 

### ug/L 0.036 p-Isopropyltoluene NO 1.0 

### ug/L 0.034 Methylene chloride NO 2.0 

### ug/L 0.070 4-Methyl-2-pentanone NO 5.0 

### ug/L 1.3 

### Naphthalene NO 1.0 

### ug/L 0.12 n-Propylbenzene NO 1.0 

### ug/L 0.017 Styrene NO 1.0 

### ug/L 0.041 1,1,1,2-Tetrachloroethane NO 1.0 

### ug/L 0.054 1,1,2,2-Tetrachloroethane NO 1.0 

### ug/L 0.082 Tetrachloroethene NO 1.0 

### ug/L 0.051 Toluene 0.57 J 1.0 

### ug/L 0.04.7 1,2,3-Trichlorobenzene NO 1.0 

### ug/L 0.14 1,2,4-Trichloro- NO 1.0 

### ug/L 0.10 benzene l,l,l-Trichloroethane NO 1.0 

### ug/L 0.070 1,1,2-Trichloroethane NO 1.0 

### ug/L 0.079 Trichloroethene NO 1.0 

### ug/L 0.054 Trichlorofluoromethane NO 2.0 

### ug/L 0.038 1,2,3-Trichloropropane NO 1.0 

### ug/L 0.18 1,2,4-Trimethylbenzene NO 1.0 

### ug/L 0.031 1,3,S-Trimethylbenzene NO 1.0 

### ug/L 0.017 Vinyl chloride NO 2.0 

### ug/L 0.088 m-Xylene & p-Xylene NO 2.0 

### ug/L 0.036 o-Xylene NO 1.0 

### ug/L 0.046
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 97 (79 

### 120) 1,2-Dichloroethane-d4 96 (71 

### 127) Toluene-d8 97 (80 

### 120) Bromofluorobenzene 94 (69 

### 126) NOTE(S) : E Estimated re,ult. Result concentration e.cecdsthe calibration range. J Estimated resull. Result is tess than RL.AirNova, Inc.
Client Sample ID; M0031 UNIT 2 RUN 2 SET 1 TENAX

Lot-Sample 

### #

... ; HOD270479-010 Date Sampled

... ; 04/23/10 Prep Date

...... ; 04/30/10 Prep Batch #

... ; 0119073 Dilution Factor; 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluenel,2-Dihromo-3-chloropropane l,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane l,l-Dichloroethane l,2-Dichloroethane cis-l,2-Dichloroethene trans-l,2-Dichloroethene 1,1-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane cis-l,3-Dichloropropene tranS-l,3-Dichloropropene 1,1-Dichloropropene GC/MS Volatiles
work Order 

### #

... ; LOKlllAA Date Received•. ; 04/27/10 Analysis Date•. ; 04/30/10
Method

......... ; SW846 VOST
REPORTING RESULT LIMIT 0.095 J,B 0.10 0.093 0.010 ND 0.010 ND 0.025 ND 0.010 ND 0.025 0.015 J 0.050 ND 0.10 ND 0.010 ND 0.010 ND 0.010 0.25 0.010 0.0026 J 0.010 ND 0.010 ND 0.025 ND 0.050 ND 0.010 0.029 J,B 0.050 ND 0.010 ND 0.010 ND 0.050
ND 0.025 ND 0.025 ND 0.010 ND 0.010 ND 0.010 ND 0.025 ND 0.010 ND 0.010 ND 0.010 ND 0.010 ND 0.010 ND 0.010 0.0018 J 0.010 ND 0.010 ND 0.010 ND 0.010 ND 0.010 (Continued 

### on next page) Matrix.......•. ; AIR

UNITS MDL 

### U9 0.030 

### U9 0.0035 

### U9 0.0020 

### u9 0.0028 

### u9 0.0013 

### u9 0.010 

### U9 0.0059 

### U9 0.10 

### u9 0.0010 

### u9 0.0010 

### U9 0.0011 

### U9 0.0019 

### U9 0.0012 

### u9 0.0010 

### u9 0.0020 

### U9 0.0062 

### U9 0.0011 

### u9 0.0025 

### u9 0.0012 

### u9 0.0014 

### U9 0.013


### U9 0.0014 

### u9 0.0021 

### u9 0.0018 

### U9 0.0014 

### u9 0.0015 

### U9 0.0024 

### u9 0.0010 

### u9 0.0017 

### u9 0.0010 

### u9 0.0020 

### U9 0.0015 

### U9 0.0017 

### u9 0.0014 

### u9 0.0010 

### u9 0.0017 

### u9 0.0012 

### U9 0.0010AirNova, Inc.
client Sample ID: M0031 UNIT 2 RUN 2 SET 1 TENAX
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-010 Work Order 

### #

... : LOKlllAA Matrix.....•... : AIR
REPORTING PARAMETER RESULT LIMIT UNITS MOL Ethylbenzene NO 0.010 u9 0.0010 Hexachlorobutadiene ND 0.025 u9 0.0025 2-Hexanone NO 0.10 U9 0.0068 Isopropylbenzene NO 0.010 U9 0.0010 p-Isopropyltoluene NO 0.010 u9 0.0010 Methylene chloride 0.023 J,B 0.025 u9 0.0022 4-Methyl-2-pentanone NO 0.10 u9 0.10 Naphthalene NO 0.025 u9 0.010 n-Propylbenzene NO 0.010 U9 0.0010 Styrene NO 0.010 U9 0.0013 1, 1,l,2-Tetrachloroethane NO 0.010 u9 0.0011 l,l,2,2-Tetrachloroethane NO 0.025 u9 0.0029 Tetrachloroethene NO 0.010 U9 0.0011 Toluene 0.018 0.010 U9 0.0010 1,2,3-Trichlorobenzene NO 0.025 u9 0.0010 1,2,4-Trichloro- NO 0.025 u9 0.0016 benzene l,l,l-Trichloroethane ND 0.025 u9 0.0010 l,l,2-Trichloroethane NO 0.025 U9 0.010 Trichloroethene NO 0.010 u9 0.0022 Trichlorofluoromethane 0.036 J 0.050 u9 0.0017 1,2,3-Trichloropropane NO 0.025 u9 0.025 1,2,4-Trirnethylbenzene NO 0.010 U9 0.0015 1,3,5-Trirnethylbenzene NO 0.010 U9 0.0018 Vinyl chloride NO 0.010 U9 0.0021 m-Xylene & p-Xylene NO 0.020 u9 0.0020 o-Xylene NO 0.010 u9 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 96 (50 123) 1,2-Dichloroethane-d4 84 (50 128) Toluene-d8 91 (50 120) Bromofluorobenzene 78 (50 120)
NOTE (S) :

Estimated result. Result is less ltwn RL. B Method blank contamination. The associated me1hod blank containsthe target analyte at areportable level.AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 2 SET 1 TEN/CHAR

Lot-Sample 

### #

... : HOD270479-011 Date Sampled

... : 04/23/10 Prep Date

...... : 04/30/10 Prep Batch 

### #

... : 0119073 Dilution Factor: 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene l,3-Dichlorobenzene l,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane cis-1,2-Dichloroethene trans-l,2-Dichloroethene l,l-Dichloroethene l,2-Dichloropropane l,3-Dichloropropane 2,2-Dichloropropane ciS-1,3-Dichloropropene trans-l,3-Dichloropropene 1,1-Dichloropropene GC/MS Volatiles
Work Order 

### #

... : LOK131AA Date Received

.. : 04/27/10 Analysis Date

.. ; 04/30/10
Method

......... : SW846 VOST
REPORTING RESULT LIMIT 0.086 J," 0.10 NO 0.010 NO 0.010 NO 0.025 NO 0.010 NO 0.025 0.039 J 0.050 NO 0.10 NO 0.010 NO 0.010 NO 0.010 0.011 0.010 NO 0.010 NO 0 010 NO 0.025 NO 0.050 NO 0.010 0.094 

# " 0.050 NO 0.010 NO 0.010 NO 0.050
NO 0.025 NO 0.025 NO 0.010 NO 0.010 NO 0.010 0.011 J 0.025 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 (Continued on next page) Matrix

.........: AIR

UNITS MOL ug 0.030 ug 0.0035 ug 0 .0020 ug 0.0028 ug 0.0013 ug 0.010 ug 0.0059 ug 0.10 ug 0.0010 ug 0.0010 ug 0.0011 ug 0.0019 ug 0.0012 ug 0.0010 ug 0.0020 ug 0.0062 ug 0.0011 ug 0.0025 ug 0.0012 ug 0.0014 ug 0.013
u9 0.0014 ug 0.0021 ug 0.0018 ug 0.0014 u9 0.0015 ug 0.0024 ug 0.0010 ug 0.0017 ug 0.0010 ug 0.0020 ug 0.0015 ug 0 0017 ug 0.0014 ug 0.0010 ug 0.0017 ug 0.0012 ug 0.0010AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 2 SET 1 TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-011 Work Order #

... : LOK131AA Matrix

......... : AIR
REPORTING PARAMETER RESULT LIMIT UNITS MDL Ethylbenzene ND 0.010 

### u9 0.0010 Hexachlorobutadiene ND 0.025 

### U9 0.0025 2-Hexanone ND 0.10 

### U9 0.0068 Isopropylbenzene ND 0.010 

### u9 0.0010 p-Isopropyltoluene ND 0.010 

### u9 0 0010 Methylene chloride 0.36 B 0.025 

### U9 0.0022 4-Methyl-2-pentanone ND 0.10 

### U9 0.10 Naphthalene ND 0.025 

### U9 0.010 n-Propylbenzene ND 0.010 

### u9 0.0010 Styrene ND 0.010 

### u9 0.0013 1,1,1,2-Tetrachloroethane ND 0.010 

### u9 0.0011 1,1,2, 2-Tetrachloroethane ND 0.025 

### U9 0.0029 Tetrachloroethene ND 0.010 

### U9 0.0011 Toluene 0.0046 J 0.010 

### u9 0.0010 1,2,3-Trichlorobenzene ND 0.025 

### u9 0.0010 1,2,4-Trichloro- ND 0.025 

### U9 0.0016 benzene l,I,I-Trichloroethane ND 0.025 

### U9 0.0010 1,1,Z-Trichloroethane ND 0.025 

### u9 0.010 Trichloroethene ND 0.010 

### U9 0.0022 Trichlorofluoromethane 0.0071 J 0.050 

### u9 0.0017 l,2,3-Trichloropropane ND 0.025 

### U9 0.025 l,2,4-Trimethylbenzene ND 0.010 

### u9 0.0015 1,3,5-Trimethylbenzene ND 0.010 

### u9 0.0018 vinyl chloride ND 0.010 

### u9 0.0021 m-xylene 

### & p-Xylene ND 0.020 

### U9 0.0020 o-xylene ND 0.010 

### U9 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 93 (50 123) 1,2-Dichloroethane-d4 81 (50 128) Toluene-d8 93 (50 120) Bromofluorobenzene 

### 82 (50 120)
NOTE (5) :

Estilllilted result. Resutt is leS$lhan RL. B Methgd blankCOlIlamination. TMe associated method blank contains the targetanatyle at arepgrtabl. level.AirNova. Inc.
Client Sample ID: M0031 UNIT 2 RUN 2 SET 2 TENAX

Lot-Sample 

### #

... ; HOD270479-012 Date Sampled

... ; 04/23(10 Prep Date

...... : 04(30(10 Prep Batch 

### #

... : 0119073 Dilution Factor: 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane l,2-Dichlorobenzene l,3-Dichlorobenzene l,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,1-Dichloroethene 1,2-Dichloropropane 1.3-Dichloropropane 2,2-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene 1,1-Dichloropropene GC/MS Volatiles
Work Order 

### #._.: LOK16lAA Date Received

.. : 04/27/10 Analysis Date

.. : 04(30(10
Method

......... : SW846 VOST
REPORTING RESULT LIMIT 0.086 J,B 0.10 0.072 0.010 NO 0.010 NO 0.025 NO 0.010 NO 0.025 0.016 J 0.050 NO 0.10 NO 0.010 NO 0.010 NO 0.010 0.095 0.010 NO 0.010 NO 0.010 NO 0.025 NO 0.050 NO 0.010 0.053 B 0.050 NO 0.010 NO 0.010 NO 0 .050
NO O. 025 NO 0.025 NO 0.010 NO 0.010 NO 0.010 NO 0.025 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 0.0016 J 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 (Continued on next page) Matrix_

........ : AIR

UNITS MDT" U9 0.030 U9 0.0035 U9 0.0020 u9 0.0028 U9 0.0013 u9 0.010 U9 0.0059 u9 0.10 u9 0.0010 u9 0.0010 U9 0.0011 U9 0.0019 u9 0.0012 u9 0.0010 U9 0.0020 U9 0.0062 U9 0.0011 u9 0.0025 u9 0.0012 u9 0.0014 U9 0.013
U9 0.0014 u9 0.0021 u9 0.0018 U9 0.0014 U9 0.0015 U9 0.0024 u9 0.0010 u9 0.0017 u9 0.0010 U9 0.0020 U9 0.0015 U9 0.0017 u9 0.0014 u9 0.0010 u9 0.0017 u9 0.0012 U9 0.0010AirNova. Inc.
Client sample ID: M0031 UNIT 2 RUN 2 SBT 2 TENAX
GC/MS Volatiles**Lot~Sample** 

### #

... : HOD270479-012 Work Order #

... : LOK161AA Matrix......•.. : AIR
REPORTING PARAMETER RESULT LIMIT UNITS MDL Ethylbenzene ND 0.010 

### u9 0.0010 Hexachlorobutadiene ND 0.025 

### u9 0.0025**2~Hexanone** ND 0.10 

### U9 0.0068 Isopropylbenzene ND 0.010 

### U9 0.0010**p~Isopropyltoluene** ND 0.010 

### u9 0.0010 Methylene chloride 0.019 J,B 0.025 

### u9 0.0022 4-Methyl-2-pentanone ND 0.10 

### u9 0.10 Naphthalene ND 0.025 

### u9 

## a.010 n-Propylbenzene ND 0.010 

### U9 0.0010 Styrene ND 0.010 

### U9 0.0013 1,1,1,2-Tetrachloroethane ND 0.010 

### u9 0.0011 1,1,2,2-Tetrachloroethane ND 0.025 

### u9 0.0029 Tetrachloroethene ND 0.010 

### U9 0.0011 Toluene 0.0024 J 0.010 

### U9 0.0010 1,2,3-Trichlorobenzene ND 0.025 

### u9 0.0010 1,2,4-Trichloro- ND 0.025 

### u9 0.0016 benzene 1,1, I-Trichloroethane ND 0.025 

### U9 0.0010 1,1,2-Trichloroethane ND 0.025 

### U9 0.010 Trichloroethene ND 0.010 

### u9 0.0022 Trichlorofluoromethane 0.018 J 0.050 

### u9 0.0017 1,2,3-Trichloropropane ND 0.025 

### u9 0.025 1,2,4-Trimethylbenzene ND 0.010 

### U9 0.0015 1,3,5-Trimethylbenzene ND 0.010 

### U9 0.0018 Vinyl chloride ND 0.010 

### u9 0.0021 m-xylene & p-Xylene ND 0.020 

### u9 0.0020 a-Xylene ND 0.010 

### u9 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibramofluaromethane 105 {50 123} 1,2-Dichloroethane-d4 

### 89 (50 128) Toluene-d8 99 {50 l20} Bromofluorobenzene 83 (50 120)
NOTE (S) : 

# , ESlimated result. Result is**le~** Ihan RL. B Melhod blank conlamination. The associated melhod blank conlainsthe tar"el anDlyle ata reportable level.

### AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 2 SET 2 TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... , HOD270479-013 Work Order fL

.. : 

### LOK191AA Matrix

......... : AIR 

### Date Sampled

... : 04/23/10 Date Received

.. : 04/27/10 Prep Date

...... : 04/30/10 Analysis Date

.. : 04/30/10 Prep Batch 

### #

... , 0119073 Dilution Factor: 1 

### Method

......... : SW846 VOST
REPORTING PARAMETER RESULT LIMIT UNITS MOL 

### Acetone 0.099 J,B 

### 0.10 U9 

### 0.030 Benzene NO 

### 0.010 U9 

### 0.0035 Bromobenzene NO 

### 0.010 U9 

### 0.0020 Bromochloromethane NO 

### 0.025 u9 

### 0.0028 Bromodichloromethane NO 

### 0.010 u9 

### 0.0013 Bromoform NO 

### 0.025 u9 

### 0.010 Bromomethane 0.044 J 

### 0.050 U9 

### 0.0059 2-Butanone NO 

### 0.10 U9 

### 0.10 n-Butylbenzene NO 

### 0.010 u9 

### 0.0010 sec-Butylbenzene NO 

### 0.010 u9 

### 0.0010 tert-Butylbenzene NO 

### 0.010 U9 

### 0.0011 Carbon disulfide 0.0030 J 

### 0.010 U9 

### 0.0019 Carbon tetrachloride NO 

### 0.010 u9 

### 0.0012 Chlorobenzene NO 

### 0.010 u9 

### 0.0010 Chlorodibromomethane NO 

### 0.025 u9 

### 0.0020 Chloroethane NO 

### 0.050 U9 

### 0.0062 Chloroform NO 

### 0.010 U9 

### 0.0011 Chloromethane 0.38 B 

### 0.050 u9 

### 0.0025 2-Chlorotoluene NO 

### 0.010 u9 

### 0.0012 4-Chlorotoluene NO 

### 0.010 u9 

### 0.0014 1,2-Dibromo-3-chloro- NO 

### 0.050 U9 

### 0.013 propane 1,2-Dibromoethane NO 

### 0.025 U9 

### 0.0014 Dibromomethane NO 

### 0.025 u9 0 

### 0021 1,2-Dichlorobenzene NO 

### 0.010 u9 

### 0.0018 1,3-Dichlorobenzene NO 

### 0.010 U9 

### 0.0014 1,4-Dichlorobenzene NO 

### 0.010 u9 

### 0.0015 Dichlorodifluoromethane 0.0031 J 

### 0.025 U9 

### 0.0024 1,1-Dichloroethane NO 

### 0.010 u9 

### 0.0010 1,2-Dichloroethane NO 

### 0.010 u9 

### 0.0017 cis-1,2-Dichloroethene NO 

### 0.010 u9 

### 0.0010 trans-l,2-Dichloroethene NO 

### 0.010 u9 

### 0.0020 1,1-Dichloroethene NO 

### 0.010 U9 

### 0.0015 1,2-Dichloropropane NO 

### 0.010 U9 

### 0.0017 1,3-Dichloropropane NO 

### 0.010 u9 

### 0.0014 2,2-Dichloropropane NO 

### 0.010 u9 

### 0.0010 ciS-l,3-Dichloropropene NO 

### 0.010 u9 

### 0.0017 trans-l,3-Dichloropropene NO 

### 0.010 u9 

### 0.0012 1,1-Dichloropropene NO 

### 0.010 U9 

### 0.0010 (Continued 

### on next page)AirNova, Inc.
Client sample ID: MOO]1 UNIT 2 RUN 2 SET 2 TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-013 Work Order 

### #

... : LOK191AA Matrix

......... : AIR
REPORTING PARAMETER RESULT LIMIT UNITS 

### MOL Ethylbenzene 

### NO 0.010 ug 0.0010 Hexachlorobutadiene 

### NO 0.025 ug 0.0025 2-Hexanone 

### NO 0.10 ug 0.0068 !sopropylbenzene 

### NO 0.010 ug 0.0010 p-Isopropyltoluene 

### NO 0.010 ug 0.0010 Methylene chloride 0.021 

### J,B 0.025 ug 0.0022 4-Methyl-2-pentanone 

### NO 0.10 ug 0.10 Naphthalene 

### NO 0.025 ug 0.010 n-Propylbenzene 

### NO 0.010 ug 0.0010 Styrene 

### NO 0.010 ug 0.0013 1,1,1,2-Tetrachloroethane 

### NO 0.010 ug 0.0011 1,1,2,2-Tetrachloroethane 

### NO 0.025 ug 0.0029 Tetrachloroethene 

### NO 0.010 ug 0.0011 Toluene 0.011 0.010 ug 0.0010 1,2,3-Trichlorobenzene 

### NO 0.025 ug 0.0010 1,2,4-Trichloro- 

### NO 0.025 ug 0.0016 benzene l,l,l-Trichloroethane 

### NO 0.025 ug 0.0010 1,1,2-Trichloroethane 

### NO 0.025 ug 0.010 Trichloroethene 

### NO 0.010 ug 0.0022 Trichlorofluoromethane 0.0042 

### J 0.050 ug 0.0017 l,2,3-Trichloropropane 

### No 0.025 ug 0.025 1,2,4-Trimethylbenzene 

### NO 0.010 ug 0.0015 1,3,5-Trimethylbenzene 

### NO 0.010 ug 0.0018 vinyl chloride 

### NO 0.010 ug 0.0021 m-xylene &. p-Xylene 

### NO 0.020 ug 0.0020 o-xylene 

### NO 0.010 ug 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 107 (50 123) 1,2-Dichloroethane-d4 93 (50 l28) Toluene-d8 102 (50 120) Bromofluorobenzene 

### 88 (50 120)
NOTE (S) :

Estimated ,.sult. Resull i. less lhan RL. B Method blank cDI1laminnion. The assoclaled melhod blank conlains**Ih~** largel analyte at areportable level.AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 2 SET 3 TENAX

Lot-Sample #

... : HOD270479-014 Date Sampled

... : 04/23/10 Prep Date

.. _... : 04/30/10 Prep Batch**~'** ... : 0119073 Dilution Factor: 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane cis-l,2-Dichloroethene trans-1,2-Dichloroethene 1,1-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane ciS-1,3-Dichloropropene trans-l,3-Dichloropropene 1,1-Dichloropropene GC/MS Volatiles
Work Order 

### #

__ .; LOK2C1AA Date Received

.. : 04/27/10 Analysis Date

.. : 04/30/10
Method

......... : SW846 VOST
REPORTING RESULT LIMIT 0.070 

### J,B 0.10 0.068 0.010 NO 0.010 NO 0.025 NO 0.010 NO 0.025 0.013 

### J 0.050 NO 0.10 NO 0.010 NO 0.010 NO 0.010 0.13 0.010 NO 0.010 NO 0.010 NO 0.025 NO 0.050 NO 0.010 0.035 

### J,B 0.050 NO 0.010 NO 0.010 NO 0.050
NO 0.025 ND 0.025 NO 0.010 NO 0.010 NO 0.010 ND 0.025 ND 0.010 ND 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 0.0016 

### J 0.010 NO 0.010 ND 0.010 ND 0.010 ND 0.010 (Continued 

### on next page) Matrix

......... ; AIR

UNITS MOL 

### U9 0.030 

### u9 0.0035 

### u9 0.0020 

### u9 0.0028 

### U9 0.0013 

### U9 0.010 

### U9 0.0059 

### u9 0.10 

### u9 0.0010 

### U9 0.0010 

### U9 0.0011 

### u9 0.0019 

### u9 0.0012 

### u9 0.0010 

### U9 0.0020 

### U9 0.0062 

### U9 0.0011 

### u9 0.0025 

### u9 0.0012 

### u9 0.0014 

### U9 0.013


### u9 0.0014 

### u9 0.0021 

### U9 

### O. 0018 

### U9 0.0014 

### U9 0.0015 

### U9 0.0024 

### u9 0.0010 

### u9 0.0017 

### u9 0.0010 

### U9 0.0020 

### U9 0.0015 

### u9 0.0017 

### u9 0.0014 

### u9 0.0010 

### u9 0.0017 

### U9 0.0012 

### U9 0.0010AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 2 SET 3 THNAX
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-014 Work Order 

### #

... : LOK2C1AA Matrix

......... : AIR
REPORTING PARAMETER RESULT LIMIT UNITS MOL Ethylbenzene NO 0.010 ug 0.0010 Hexachlorobutadiene NO 0.025 ug 0.0025 2-Hexanone NO 0.10 ug 0.0068 Isopropylbenzene NO 0.010 ug 0.0010 p-Isopropyltoluene NO 0.010 ug 0.0010 Methylene chloride 0.012 J,B 0.025 ug 0.0022 4-Methyl-2-pentanone NO 0.10 ug 0.10 Naphthalene NO 0.025 ug 0.010 n-propylbenzene NO 0.010 ug 0.0010 Styrene NO 0.010 ug 0.0013 1,1,1,2-Tetrachloroethane NO 0.010 ug 0.0011 1,1,2, 2-Tetrachloroethane NO 0.025 ug o .0029 Tetrachloroethene NO 0.010 ug 0.0011 Toluene 0.004.0 J 0.010 ug 0.0010 1,2,3-Trichlorobenzene NO 0.025 ug 0.0010 1,2,4-Trichloro- NO 0.025 ug 0.0016 benzene 1,1,I-Trichloroethane NO 0.025 ug 0.0010 1,1,2-Trichloroethane NO 0.025 ug 0.010 Trichloroethene NO 0.010 ug 0.0022 Trichlorofluoromethane 0.030 J 0.050 ug 0.0017 1,2,3-Trichloropropane NO 0.025 ug 0.025 1,2,4-Trimethylbenzene NO 0.010 ug 0.0015 1,3,5-Trimethylbenzene NO 0.010 ug 0.0018 Vinyl chloride NO 0.010 ug 0.0021 m-xylene & p-Xylene NO 0.020 ug 0.0020 o-xylene NO 0.010 ug 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS DibromoEluoromethane 105 (50 123) 1,2-Dichloroethane-d4 91 (50 128) Toluene-dB 96 (50 120) Bromofluorobenzene 83 (50 120)
NOTE (S) :

ESlimaled result. Result**i~** leiS than RL B Method blank**~Qntamination.** The a"oeioted method blankcontains the target**~nalyte** at a reponable level.AirNova. Inc.
Client sample ID: M0031 UNIT 2 RUN 2 SET 3 TEN/CHAR

Lot-Sample 

### #

... : HOD270479-015 Date Sampled

... : 04/23/10 Prep Date

...... : 04/30/10 Prep Batch #

... : 0119073 Dilution Factor: 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromornethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane cis-l,2-Dichloroethene trans-1,2-Dichloroethene 1,1-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane ciS-1,3-Dichloropropene trans-1,3-Dichloropropene 1,1-Dichloropropene GC/MS Volatiles
Work Order 

### #

... : LOK2ElAA Date Received

.. : 04/27/10 Analysis Date

.. : 04/30/10
Method

.........: SW846 VOST
REPORTING RESULT LIMIT 0.068 J,' 0.10 0.0043 J 0.010 NO 0.010 No 0.025 NO 0.010 NO 0.025 0.065 0.050 NO 0.10 NO 0.010 NO 0.010 NO 0.010 0.0064 J 0.010 NO 0.010 No 0.010 NO 0.025 NO 0.050 NO 0.010 0.57 B 0.050 NO 0.010 NO 0.010 NO 0.050
NO 0.025 NO 0.025 NO 0.010 NO 0.010 NO 0.010 0.0057 J 0.025 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 (Continued on next page) Matrix

......... : AIR

UNITS MOL U9 0.030 U9 0.0035 U9 0.0020 u9 0.0028 u9 0.0013 u9 0.010 U9 0.0059 u9 0.10 u9 0.0010 u9 0.0010 U9 0.0011 U9 0.0019 U9 0.0012 u9 0.0010 U9 0.0020 U9 0.0062 U9 0.0011 u9 0.0025 u9 0.0012 u9 0 .0014 U9 0.013
U9 0.0014 u9 0.0021 u9 0.0018 U9 0.0014 U9 0.0015 U9 0.0024 u9 0.0010 u9 0.0017 u9 0.0010 U9 0.0020 U9 0.0015 U9 0.0017 u9 0.0014 u9 0.0010 u9 0.0017 u9 0.0012 U9 0.0010AirNova, Inc.
Client sample ID: M0031 UNIT 2 RUN 2 SET 3 TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-015 Work Order 

### #

... : LOK2ElAA Matrix

......... : AIR
REPORTING PARAMETER RESULT LIMIT UNITS MDL Ethylbenzene ND 0.010 

### u9 0.0010 Hexachlorobutadiene ND 0.025 

### u9 0.0025 2-Hexanone ND 0.10 

### u9 0.0068 Isopropylbenzene ND 0.010 

### U9 0.0010 p-Isopropyltoluene ND 0.010 

### u9 0.0010 Methylene chloride 0.019 J.B 0.025 

### u9 0.0022 4-Methyl-2-pentanone ND 0.10 

### u9 0.10 Naphthalene ND 0.025 

### u9 0.010 n-Propylbenzene ND 0.010 

### U9 0.0010 Styrene ND 0.010 

### U9 0.0013 1,1,1,2-Tetrachloroethane ND 0.010 

### u9 0.0011 l,l,2,2-Tetrachloroethane ND 0.025 

### u9 0.0029 Tetrachloroethene ND 0.010 

### u9 0.001l Toluene 0.0032 J 0.010 

### U9 0.0010 1,2,3-Trichlorobenzene ND 0.025 

### U9 0.0010 l,2,4-Trichloro- ND 0.025 

### u9 0.0016 benzene l,l,l-Trichloroethane ND 0.025 

### u9 0.0010 1,1,2-Trichloroethane ND 0.025 

### U9 0.010 Trichloroethene ND 0.010 

### u9 0.0022 Trichlorofluoromethane 0.0075 J 0.050 

### u9 0.0017 1,2,3-Trichloropropane ND 0.025 

### u9 0.025 1,2,4-Trimethylbenzene ND 0.010 

### u9 0.0015 l,3,5-Trimethylbenzene ND 0.010 

### U9 0.0018 Vinyl chloride ND 0.010 

### U9 0.0021 m-xylene 

### & p-xylene ND 0.020 

### u9 0.0020 o-Xylene ND 0.010 

### u9 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 102 (50 123) 1,2-Dichloroethane-d4 95 (50 128) Toluene-d8 103 (50 120) Bromofluorobenzene 93 (50 120)

NOTE (8) :

Estimaled result. Result is less Ihan RL. B Method blank contamination The associated method blank contains the target !nalyte at areporuoble**I~vel.**AirNova, Inc.
Client Sample 10: M003l UNIT 2 RUN 2 COND
GC/MS Volatiles Lot-Sample 

### #

... , HOD270479-0l8 Work Order 

### #

... , LOK2J1AA Matrix

......... : WATER Date Sampled

... : 04/23/10 Date Received

.. ; 04/27/10 Prep Date

...... : 05/01/10 Analysis Date

.. : 05/01/10 Prep Batch ft

... : 0119312 Dilution Factor: 1 Method.

......... : SW846 8260B
REPORTING PARAMETER RESULT LIMIT UNITS MOL Acetone 710 E 10 ug/L 2.0 Benzene 0.14 J 1.0 ug/L 0.025 Bromobenzene NO 1.0 ug/L 0.051 Bromochloromethane 1.0 1.0 ug/L 0.097 Bromodichloromethane NO 1.0 ug/L 0.065 Bromoform ND 1.0 ug/L 0.50 Bromomethane NO 2.0 ug/L 0.14 2-Butanone 17 5.0 ug/L 1.3 n-Butylbenzene ND 1.0 ug/L 0.038 sec-Butylbenzene ND 1.0 ug/L 0.034 tert-Butylbenzene ND 1.0 ug/L 0.035 Carbon disulfide ND 1 

## a ug/L 0.039 Carbon tetrachloride ND 1.0 ug/L 0.054 Chlorobenzene ND 1.0 ug/L 0.041 Chlorodibromomethane ND 1.0 ug/L 0.11 Chloroethane NO 2.0 ug/L 0.13 Chloroform 0.19 J 1.0 ug/L 0.036 Chloromethane 0.088 J 2 .• ug/L 0.064 2-Chlorotoluene ND 

# I..
ug/L 0.050 4-Chlorotoluene ND I .• ug/L 0.050 l,2-Dibromo-3-chloro- ND 2 .• ug/L 0.33 propane 1,2-Dibromoethane ND 1.0 ug/L 0.094 Dibromomethane ND 1.0 ug/L 0.097 l,2-Dichlorobenzene NO 

# I.. ug/L 0.035 l,3-Dichlorobenzene ND 

# I.. ug/L 0.043 l,4-Dichlorobenzene ND 

# I.. ug/L 0.049 Dichlorodifluoromethane ND 2 .• ug/L 0.48 l,l-Dichloroethane ND 1.0 ug/L 0.034 l,2-Dichloroethane ND 1.0 ug/L 0.046 cis-l,2-Dichloroethene ND 

# I.. ug/L 0.054 trans-l,2-Dichloroethene ND 1.0 ug/L 0.036 l,l-Dichloroethene ND 1.0 ug/L 0.066 1,2-Dichloropropane ND 1.0 ug/L 0.048 l,3-Dichloropropane NO 1.0 ugjr, 0.036 2,2-Dichloropropane ND 

# I.. ugjL 0.053 CiS-l,3-Dichloropropene ND 

# I.. ugjL 0.059 trans-l,3-Dichloropropene ND 

# I.. ug/L 0.056 1,1-Dichloropropene ND I .• ug/L 0.042 (Continued 

### on next page)AirNova, Inc.
Client Sample ID; M0031 UNIT 2 RUN 2 COND
GC/MS Volatiles Lot-Sample 

### #

... ; HOD270479-018 Work Order 

### #

... ; LOK2JlAA
REPORTING PARAMETER RESULT LIMIT Ethylbenzene 

### NO 1.0 Hexachlorobutadiene 

### NO 2.0 2-Hexanone 2.3 J 5.0 Isopropylbenzene 

### NO 1.0 p-Isopropyltoluene 

### NO 1.0 Methylene chloride 1100 B,E,S 2.0 4-Methyl-2-pentanone 

### NO 5.0 Naphthalene 

### NO 1.0 n-Propylbenzene 

### NO 1.0 Styrene 

### NO 1.0 l,l,1,2-Tetrachloroethane 

### NO 1.0 1,1,2,2-Tetrachloroethane 

### NO 1.0 Tetrachloroethene 

### NO 1.0 Toluene 0.082 J 1.0 1,2,3-Trichlorobenzene 

### NO 1.0 1,2,4-Trichloro- 

### NO 1.0 benzene 1,1,1-Trichloroethane 

### ND 1.0 1,1,2-Trichloroethane 

### NO 1.0 Trichloroethene 

### NO 1.0 Trichlorofluoromethane 

### NO 2.0 1,2,3-Trichloropropane 

### NO 1.0 1,2,4-Trimethylbenzene 

### NO 1.0 1,3,5-Trimethylbenzene 

### NO 1.0 vinyl chloride 

### NO 2.0 m-xylene 

### & p-Xylene 

### NO 2.0 o-xylene 

### NO 1.0
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 99 (79 120) 1,2-Dichloroethane-d4 102 (71 127) Toluene-dB 

### 9< (80 120) Bromofluorobenzene 93 (69 126)
NOTE (S) ; E Estimated result. Result**~onccntnllion** exceeds thecalibration**r~nge.** J Estimated result. Result is lessthan RL. B Me1hod blank contamination. The associated method blank contains the target analyte atareportable level. S Mass spectrometer5aruralion. Matrix

.....__ ._: WATER

UNITS 

### MOL ug/L 0.040 ug/L 0.19 ug/L 0.25 ug/L 0.036 ug/L 0.034 ug/L 0.070 ug/L 1.3 ug/L 0.12 ug/L 0.017 ug/L 0.04.1 ug/L 0.054 ug/L 0.OB2 ug/L 0.051 ug/L 0.047 ug/L 0.14 ug/L 0.10 ug/L 0.070 ug/L 0.079 ug/L 0.054 ug/L 0.038 ug/L 0.18 ug/L 0.031 ug/L 0.017 ug/L 0.08B ug/L 0.036 ug/L 0.046

### AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 SET 1 TENAX

Lot-Sample 

### #

... : HOD270479-019 Date Sampled

... : 04/23/10 Prep Date

...... : 04/30/10 Prep Batch 

### #

... : 0119073 Dilution Factor: 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluenel,2-Dibromo-3-chloropropane l,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene l,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane l,l-Dichloroethane l,2-Dichloroethane cis-1,2-Dichloroethene trans-1,2-Dichloroethene l,l-Dichloroethene l,2-Dichloropropane l,3-Dichloropropane 2,2-Dichloropropane cis-l,3-Dichloropropene trans-1,3-Dichloropropene l,l-Dichloropropene GC/MS Volatiles
Work Order 

### #

... : LOK2M1AA Date Received

.. : 04/27/10 Analysis Date

.. : 04/30/10
Method

......... : SW846 VaST
REPORTING RESULT LIMIT 0.073 J,B 

### 0.10 0.041 0.010 NO 

### 0.010 NO 

### 0.025 NO 

### 0.010 NO 

### 0.025 0.018 J 

### 0.050 NO 

### 0.10 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 0.11 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.025 NO 

### 0.050 NO 

### 0.010 0.066 B 

### 0.050 NO 

### 0.010 NO 

### 0.010 NO 

### 0.050
NO 

### 0.025 NO 0 

### 025 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.025 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 (Continued on 

### next page) Matrix

......... : AIR

UNITS MOL u9 

### 0.030 U9 

### 0.0035 U9 

### 0.0020 U9 

### 0.0028 u9 

### 0.0013 u9 

### 0.010 u9 

### 0.0059 U9 

### 0.10 U9 

### 0.0010 u9 

### 0.0010 u9 

### 0.0011 u9 

### 0.0019 u9 

### 0.0012 U9 

### 0.0010 u9 

### 0.0020 u9 

### 0.0062 u9 

### 0.001l U9 

### 0.0025 U9 

### 0.0012 u9 

### 0.0014 u9 

### 0.013
u9 

### 0.0014 U9 

### 0.0021 u9 

### 0.0018 u9 

### 0.0014 u9 

### 0.0015 u9 

### 0.0024 u9 

### 0.0010 U9 

### 0.0017 U9 

### 0.0010 u9 

### 0.0020 u9 

### 0.0015 u9 

### 0.0017 U9 

### 0.0014 U9 

### 0.0010 U9 

### 0.0017 U9 

### 0.0012 u9 

### 0.0010AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 SET 1 TENAX
GC/MS volatiles Lot-Sample ft •.. : HOD270479-0l9 Work Order 

### #

... : LOK2MlAA Matrix

......... : AIR
REPORTING PARAMETER RESULT LIMIT UNITS MDL Ethylbenzene ND 0.010 

### u9 0.0010 Hexachlorobutadiene ND 0.025 

### u9 0.0025 2-Hexanone ND 0.10 

### U9 0.0068 Isopropylbenzene ND 0.010 

### U9 0.0010 p-Isopropyltoluene ND 0.010 

### u9 0.0010 Methylene chloride 0.012 J,B 0.025 

### u9 0.0022 4-Methyl-2-pentanone ND 0.10 

### u9 0.10 Naphthalene ND 0.025 

### u9 0.010 n-Propylbenzene ND 0.010 

### U9 0.0010 Styrene ND 0.010 

### U9 0.0013 1,1,1,2-Tetrachloroethane ND 0.010 

### u9 0.0011 1,1,2,2-Tetrachloroethane ND 0.025 

### u9 0.0029 Tetrachloroethene ND 0.010 

### U9 0.0011 Toluene 0.0028 J 0.010 

### U9 0.0010 1,2,3-Trichlorobenzene ND 0.025 

### u9 0.0010 1,2,4-Trichloro- ND 0.025 

### u9 0.0016 benzene 1,1,1-Trichloroethane ND 0.025 

### U9 0.0010 1,1,2-Trichloroethane ND 0.025 

### U9 0.010 Trichloroethene ND 0.010 

### u9 0.0022 Trichlorofluoromethane 0.054 0.050 

### u9 0.0017 1,2,3-Trichloropropane ND 0.025 

### u9 0.025 1,2,4-Trimethylbenzene ND 0.010 

### U9 0.0015 1,3 , S-Trimethylbenzene ND 0.010 

### U9 0.0018 Vinyl chloride ND 0.010 

### u9 0.0021 rn-Xylene 

### & p-Xylene ND 0.020 

### u9 0.0020 o-Xylene ND 0.010 

### u9 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 

### 88 (50 123) 1,2-Dichloroethane-d4 70 (50 128) Toluene-d8 96 (50 120) Bromofluorobenzene 

### 86 (50 120) NOTE(S) : 

# , Estimated result. Result Is less than RL. B Method blank contamination. The associated method blankcontains the larget analyro ala reportable level.AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 SET 1 TEN/CHAR
GC/MS volatiles Lot-Sample 

### #

... , HOD270479-020 Work Order 

### #

... , LOK2T1AA Matrix......•.. : AIR Date Sampled

... : 04/23/10 Date Received

.. : 04/27/10 Prep Date

...... : 04/30/10 Analysis Date

.. : 04/30/10 Prep Batch 

### #

... : 0119073 Dilution Factor: 1 Method

......... : SW846 VOST
REPORTING PARAMETER RESULT LIMIT UNITS MOL Acetone 0.069 J,B 0.10 u9 0.030 Benzene NO 0.010 ug 0.0035 Bromobenzene NO 0.010 ug 0.0020 Bromochloromethane NO 0.025 ug 0.0028 Bromodichloromethane NO 0.010 ug 0.0013 Bromoform NO 0.025 ug 0.010 Bromomethane 0.051 0.050 u9 0.0059 2-Butanone NO 0.10 ug 0.10 n-Butylbenzene NO 0.010 ug 0.0010 sec-Butylbenzene NO 0.010 ug 0.0010 tert-Butylbenzene NO 0.010 ug 0.0011 Carbon disulfide NO 0.010 u9 0.0019 Carbon tetrachloride NO 0.010 u9 0.0012 Chlorobenzene NO 0.010 u9 0.0010 Chlorodibromomethane NO 0.025 U9 0.0020 Chloroethane NO 0.050 u9 0.0062 Chloroform NO 0.010 u9 0.0011 Chloromethane 0.36 B 0.050 u9 0.0025 2-Chlorotoluene NO 0.010 U9 0.0012 4-Chlorotoluene NO 0.010 U9 0.0014 1,2-Dibromo-3-chloro- NO 0.050 u9 0 .013 propane 1,2-Dibromoethane NO 0.025 u9 0 .0014 Dibromomethane NO 0.025 u9 0.0021 1,2-Dichlorobenzene NO 0.010 U9 0.0018 1,3-Dichlorobenzene NO 0.010 u9 0.0014 1,4-Dichlorobenzene NO 0.010 U9 0.0015 Dichlorodifluoromethane 0.0041 J 0.025 u9 0.0024 l,l-Dichloroethane NO 0.010 u9 0.0010 1,2-Dichloroethane NO 0.010 u9 0.0017 cis-1,2-Dichloroethene NO 0.010 U9 0.0010 trans-1,2-Dichloroethene NO 0.010 U9 0.0020 1,1-Dichloroethene NO 0.010 u9 0.0015 1,2-Dichloropropane NO 0.010 u9 0.0017 l,3-Dichloropropane NO 0.010 u9 0.0014 2,2-Dichloropropane NO 0.010 U9 0.0010 cis-1,3-Dichloropropene NO 0.010 u9 0.0017 trans-1,3-Dichloropropene NO 0.010 U9 0.0012 1,1-Dichloropropene NO 0.010 u9 0.0010 (Continued on next page)AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 SET 1 TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-020 Work Order 

### #

... : LOK2T1AA Matrix...••...• : AIR
REPORTING PARAMETER RESULT LIMIT UNITS MDL Ethylbenzene ND 0.010 ug 0.0010 Hexachlorobutadiene ND 0.025 ug 0.0025 2-Hexanone ND 0.10 ug 0.0068 Isopropylbenzene ND 0.010 ug 0.0010 p-Isopropyltoluene ND 0.010 ug 0.0010 Methylene chloride 0.013 J,B 0.025 ug 0.0022 4-Methyl-2-pentanone ND 0.10 ug 0.10 Naphthalene ND 0.025 ug 0.010 n-Propylbenzene ND 0.010 ug 0.0010 Styrene ND 0.010 ug 0.0013 1,1,1,2-Tetrachloroethane ND 0.010 ug 0.0011 1,1,2,2-Tetrachloroethane NO 0.025 ug 0.0029 Tetrachloroethene ND 0.010 ug 0.0011 Toluene 0.0027 J 0.010 ug 0.0010 1,2,3-Trichlorobenzene ND 0.025 ug 0.0010 1,2,4-Trichloro- ND 0.025 ug 0.0016 benzene l,l,l-Trichloroethane ND 0.025 ug 0.0010 1,1,2-Trichloroethane ND 0.025 ug 0.010 Trichloroethene ND 0.010 ug 0.0022 Trichlorofluoromethane 0.0062 J 0.050 ug 0.0017 1,2,3-Trichloropropane ND 0.025 ug 0.025 1,2,4-Trimethylbenzene ND 0.010 ug 0.0015 1,3,5-Trimethylbenzene ND 0.010 ug 0.0018 vinyl chloride ND 0.010 ug 0.0021 m-Xylene 

### & p-Xylene NO 0.020 ug 0.0020 o-Xylene NO 0.010 ug 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 101 (50 123) 1,2-Dichloroethane-d4 87 (50 128) Toluene-d8 102 (50 120) Bromofluorobenzene 85 (50 120)
NOTE (8) :

Estimated resull. Result**i~** less 1han RL. B Method blank contamination. TMe associated melhod blank conlainsthe Illrgel**~naly1e** al a reportable level.

### AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 SET 2 TENAX

Lot-Sample 

### #

... : HOD270479-021 Date Sampled

... : 04/23/10 Prep Date

...... ; 04/30/10 Prep Batch 

### #

... ; 0119073 Dilution Factor: 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-chlorotoluene1,2-Dihromo-3-chloropropane 1,2-Dihromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene l,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,1-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane cis-1,3-Dichloropropene trans-l,3-Dichloropropene 1,1-Dichloropropene GC/MS Volatiles
Work Order 

### #

... : LOK2V1AA Date Received

.. : 04/27/10 Analysis Date

.. : 04/30/10
Method

......... : SW846 VaST
REPORTING RESULT LIMIT 0.044 J,B 

### 0.10 0.048 0.010 NO 

### 0.010 NO 

### 0.025 NO 

### 0.010 NO 

### 0.025 0.021 J 

### 0.050 NO 

### 0.10 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 0.11 0.010 0.0015 J 

### 0.010 NO 

### 0.010 NO 

### 0.025 NO 

### 0.050 NO 

### 0.010 0.088 B 

### 0.050 NO 

### 0.010 ND 

### 0.010 NO 

### 0.050
NO 

### 0.025 NO 

### 0.025 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.025 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 NO 

### 0.010 (Continued on 

### next page) Matrix......•..; AIR

UNITS MOL 

### u9 0.030 u9 0.0035 ug 0.0020 ug 0.0028 U9 0.0013 U9 0.010 u9 0.0059 u9 0.10 ug 0.0010 ug 0.0010 ug 0.0011 u9 0.0019 u9 0.0012 ug 0.0010 U9 0.0020 u9 0.0062 u9 0.0011 u9 0.0025 U9 0.0012 U9 0.0014 u9 0.013
u9 0.0014 ug 0.0021 ug 0.0018 ug 0.0014 U9 0.0015 u9 0.0024 u9 0.0010 u9 0.0017 U9 0.0010 U9 0.0020 u9 0.0015 ug 0.0017 ug 0.0014 ug 0.0010 ug 0.0017 U9 0.0012 u9 0.0010AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 SET 2 TENAX
OC/MS Volatiles Lot-sample 

### #

... : HOD270479-021 Work Order 

### #

... : LOK2V1AA Matrix

......... : AIR
REPORTING PARAMETER RESULT LIMIT UNITS 

### MOL Ethylbenzene 

### NO 0.010 

### u9 0.0010 Hexachlorobutadiene 

### NO 0.025 

### U9 0.0025 2-Hexanone 

### NO 0.10 

### U9 0.0068 Isopropylbenzene 

### NO 0.010 

### u9 0.0010 p-Isopropyltoluene 

### NO 0.010 

### u9 0.0010 Methylene chloride 0.022 J,B 0.025 

### U9 0.0022 4-Methyl-2-pentanone 

### NO 0.10 

### U9 0.10 Naphthalene 

### NO 0.025 

### U9 0.010 n-Propylbenzene 

### NO 0.010 

### u9 0.0010 Styrene 

### NO 0.010 

### u9 0.0013 1,1,1,2-Tetrachloroethane 

### NO 0.010 

### u9 0.0011 1,1,2,2-Tetrachloroethane 

### NO 0.025 

### U9 0.0029 Tetrachloroethene 

### NO 0.010 

### U9 0.0011 Toluene 0.018 0.010 

### u9 0.0010 1,2,3-Trichlorobenzene 

### NO 0.025 

### u9 0.0010 1,2,4-Trichloro- 

### NO 0.025 

### u9 0.0016 benzene l,l,l-Trichloroethane 

### NO 0.025 

### U9 0.0010 1, 1, 2-Trichloroethane 

### NO 0.025 

### u9 0.010 Trichloroethene 

### NO 0.010 

### u9 0.0022 Trichlorofluoromethane 0.070 0.050 

### u9 0.0017 1,2,3-Trichloropropane 

### NO 0.025 

### U9 0.025 1,2,4-Trirnethylbenzene 

### NO 0.010 

### U9 0.0015 1,3,5-Trirnethylbenzene 

### NO 0.010 

### u9 0.0018 Vinyl chloride 

### NO 0.010 

### u9 0.0021 rn-Xylene & p-Xylene 

### NO 0.020 

### u9 0.0020 o-Xylene 

### NO 0.010 

### u9 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibrornofluoromethane 104 (50 123) 1,2-Dichloroethane-d4 93 (50 128) Toluene-da 97 (50 120) Brornofluorobenzene 01 (50 120) NOTE{S):

Estimated resull. Result is less than RL. B Method blank**cont~mination.** The associated method blank contains \he t.&rget analyte at areportable level.AirNova. Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 SET 2 TEN/CHAR

Lot-Sample 

### #

... : HOD270479-022 Date Sampled

... : 04/23/10 Prep Date

...... : 04/30/10 Prep Batch**~,** ... : 0119073 Dilution Factor: 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane l,2-Dichlorobenzene l,3-Dichlorobenzene l,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane cis-1,2-Dichloroethene trans-l,2-Dichloroethene l,l-Dichloroethene l,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane ciS-l,3-Dichloropropene trans-1,3-Dichloropropene l,l-Dichloropropene GC/MS Volatiles
Work Order 

### #

... : LOK2WlAA Date Received

.. : 04/27/10 Analysis Date

.. : 04/30/10
Method

......... : SW846 VaST
REPORTING RESULT LIMIT 0.11 B 0.10 NO 0.010 NO 0.010 NO 

### o. 025 NO 0.010 NO 0.025 0.054 0.050 NO 0.10 NO 0.010 NO 0.010 NO 0.010 0.0024 J 0.010 NO 0.010 NO 0.010 NO 0.025 NO 0.050 NO 0.010 0.49 B 0.050 NO 0.010 NO 0.010 NO 0.050
NO 0.025 NO 0.025 NO 0.010 NO 0.010 NO 0.010 0.0051 J 0.025 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 NO 0.010 (Continued on next page) Matrix

......... : AIR

UNITS MOL u9 0.030 u9 0.0035 u9 0.0020 u9 0.0028 U9 0.0013 U9 0.010 u9 0.0059 u9 0.10 U9 0.0010 U9 0.0010 U9 0.0011 u9 0.0019 u9 0.0012 u9 0.0010 U9 0.0020 u9 0.0062 u9 0.0011 u9 0.0025 U9 0.0012 U9 0.0014 U9 0.013
u9 0.0014 u9 0.0021 U9 0.0018 U9 0.0014 U9 0.0015 u9 0.0024 u9 0.0010 u9 0.0017 U9 0.0010 U9 0.0020 u9 0.0015 u9 0.0017 u9 0.0014 u9 0.0010 u9 0.0017 U9 0.0012 u9 0.0010AirNova, Inc.
Client Sample ID; M0031 UNIT 2 RUN 3 SET 2 TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... ; HOD270479-022 Work Order 

### #

... ; LOK2WlAA
REPORTING PARAMETER RESULT LIMIT Ethylbenzene 

### NO 0.010 Hexachlorobutadiene 

### NO 0.025 2-Hexanone 

### NO 0.10 Isopropylbenzene 

### NO 0.010 p-Isopropyltoluene 

### NO 0.010 Methylene chloride 0.77 B 0.025 4-Methyl-2-pentanone 

### NO 0.10 Naphthalene 

### NO 0.025 n-Prapylbenzene 

### NO 0.010 Styrene 

### NO 0.010 1,1,1,2-Tetrachlaroethane 

### NO 0.010 1,1,2,2-Tetrachloroethane 

### NO 0.025 Tetrachloroethene 

### NO 0.010 Toluene 0.027 0.010 1,2,3-Trichlorobenzene 

### NO 0.025 1,2,4-Trichloro- 

### NO 0.025 benzene l,l,l-Trichloroethane 

### NO 0.025 1,1,2-Trichloroethane 

### NO 0.025 Trichloroethene 

### NO 0.010 Trichlorofluoromethane 0.0084 J 0.050 1,2,3-Trichloropropane 

### NO 0.025 1,2,4-Trimethylbenzene 

### NO 0.010 1,3,5-Trimethylbenzene 

### NO 0.010 Vinyl chloride 

### NO 0.010 m-Xylene & p-xylene 

### NO 0.020 a-Xylene 

### NO 0.010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibramafluaramethane 103 (50 123) 1,2-Dichloroethane-d4 99 (50 128) Toluene-dB 

### 97 (50 120) Bromofluorobenzene 

### 88 (50 120) NOTE(S) : B Method blank conlamination. The associated method blank cOI1!ains the large! analyte at arcponable level. J ESilmaltd result. Result is less than RL. Matrix

......... ; AIR

UNITS 

### MOL ug 0.0010 ug 0.0025 ug 0.0068 ug 0.0010 ug 0.0010 ug 0.0022 ug 0.10 ug 0.010 ug 0.0010 ug 0.00l3 ug O.OOll ug 0.0029 ug O.OOll ug 0.0010 ug 0.0010 ug 0.0016

ug 0.0010 ug 0.010 ug 0.0022 ug 0.0017 ug 0.025 ug 0.0015 ug 0.0018 ug 0.0021 ug 0.0020 ug 0.0010

### AirNova, Inc.
Client sample ID: M003l UNIT 2 RUN 3 SET 3 TENAX
GC/MS Volatiles Lot-Sample #

... : HOD270479-023 Work Order 

### #

... , LOK201AA Matrix

......... : AIR 

### Date Sampled

... : 04/23/10 Date Received

.. : 04/27/10 Prep Date

...... : 04/30/10 Analysis Date

.. : 04/30/10 Prep Batch 

### #

... , 0119073 Dilution Factor: 1 

### Method

......... : SW846 VOST
REPORTING PARAMETER RESULT LIMIT UNITS MOL 

### Acetone 0.054 J.B 

### 0.10 U9 

### 0.030 Benzene 0.019 0.010 U9 

### 0.0035 Bromobenzene NO 

### 0.010 U9 

### 0.0020 Bromochloromethane NO 

### 0.025 u9 

### 0.0028 Bromodichloromethane NO 

### 0.010 U9 

### 0.0013 Bromoform NO 

### 0.025 u9 

### 0.010 Bromomethane 0.011 J 

### 0.050 U9 

### 0.0059 2-Butanone NO 

### 0.10 u9 

### 0.10 n-Butylbenzene NO 

### 0.010 u9 

### 0.0010 sec-Butylbenzene NO 

### 0.010 u9 

### 0.0010 tert-Butylbenzene NO 

### 0.010 U9 

### 0.0011 Carbon disulfide 0.13 0.010 U9 

### 0.0019 Carbon tetrachloride NO 

### 0.010 U9 

### 0.0012 Chlorobenzene NO 

### 0.010 u9 

### 0.0010 Chlorodibromomethane NO 

### 0.025 u9 

### 0.0020 Chloroethane NO 

### 0.050 U9 

### 0.0062 Chloroform NO 

### 0.010 U9 

### 0.0011 Chloromethane 0.074 B 

### 0.050 u9 

### 0.0025 2-Chlorotoluene NO 

### 0.010 u9 

### 0.0012 4-Chlorotoluene NO 

### 0.010 u9 

### 0.0014 l,2-Dibromo-3-chloro- NO 

### 0.050 U9 

### 0.013 propane l,2-Dibromoethane NO 

### 0.025 U9 

### 0.0014 Dibroroomethane NO 

### 0.025 u9 

### 0.0021 l,Z-Dichlorobenzene NO 

### 0.010 u9 

### 0.0018 l,3-Dichlorobenzene NO 

### 0.010 U9 

### 0.0014 l,4-Dichlorobenzene NO 

### 0.010 u9 

### 0.0015 Dichlorodifluoromethane NO 

### 0.025 U9 

### 0.0024 1,1-Dichloroethane NO 

### 0.010 u9 

### 0.0010 1,2-Dichloroethane NO 

### 0.010 u9 

### 0.0017 cis-1,Z-Dichloroethene NO 

### 0.010 u9 

### 0.0010 trans-l,2-Dichloroethene NO 

### 0.010 u9 

### 0.0020 l,l-Dichloroethene NO 

### 0.010 U9 

### 0.0015 l,2-Dichloropropane NO 

### 0.010 U9 

### 0.0017 l,3-Dichloropropane NO 

### 0.010 u9 

### 0.0014 2,2-Dichloropropane NO 

### 0.010 u9 

### 0.0010 ciS-1,3-Dichloropropene NO 

### 0.010 u9 

### 0.0017 trans-l,3-Dichloropropene NO 

### 0.010 u9 

### 0.0012 l,l-Dichloropropene NO 

### 0.010 U9 

### 0.0010 (Continued on 

### next page)AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 SET 3 TENAX
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-023 Work Order 

### #

... : LOK201AA Matrix

......... : AIR
REPORTING PARAMETER RESULT LIMIT UNITS MDL Ethylbenzene ND 0.010 ug 0.0010 Hexachlorobutadiene ND 0.025 ug 0.0025 2-Hexanone ND 0.10 ug 0.0068 Isopropylbenzene ND 0.010 ug 0.0010 p-Isopropyltoluene ND 0.010 ug 0.0010 Methylene chloride 0.0097 J,B 0.025 ug 0.0022 4-Methyl-2-pentanone ND 0.10 ug 0.10 Naphthalene ND 0.025 ug 0.010 n-Propylbenzene ND 0.010 ug 0.0010 Styrene ND 0.010 ug 0.0013 l,l,l,2-Tetrachloroethane ND 0.010 ug 0.0011 l,l,2,2-Tetrachloroethane ND 0.025 ug 0 0029 Tetrachloroethene ND 0.010 ug 0.0011 Toluene ND 0.010 ug 0.0010 1,2,3-Trichlorobenzene ND 0.025 ug 0.0010 1,2,4-Trichloro- ND 0.025 ug 0 .0016 benzene 1,1,1-Trichloroethane ND 0.025 ug 0 .0010 1,1,2-Trichloroethane ND 0.025 ug 0.010 Trichloroethene ND 0.010 ug 0.0022 Trichlorofluoromethane 0.012 J 0.050 ug 0.0017 1,2,3-Trichloropropane ND 0.025 ug 0.025 1,2,4-Trimethylbenzene ND 0.010 u9 0.0015 1,3,5-Trimethylbenzene ND 0.010 ug 0.0018 Vinyl chloride ND 0.010 ug 0.0021 m-xylene 

### & p-xylene ND 0.020 ug 0.0020 o-Xylene ND 0.010 ug 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 63 (50 123) 1,2-Dichloroethane-d4 44 

## • (50 128) Toluene-d8 

### 86 (50 120) Bromofluorobenzene 

### 6' (50 120) NDTE(S):

Surrogate**recov~ry** is outside**~taled** controllimil5. E51imaled**'e~ult.** Resull is less than RL. B Method blank contaminalion. The**a~socia1ed** method blankconlains the (.rge( .n"lyle.t.reportable level.AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 SET 3 TEN/CHAR
GC/MS Volatiles Lot-Sample :/L •• : HOD270479-024 Work Order 

### #

... , LOK211AA Matrix......•.. : AIR Date Sampled

... : 04/23/10 Date Received

.. : 04/27/10 Prep Date

...... : 04/30/10 Analysis Date•. : 04/30/10 Prep Batch :JI: ••• : 0119073 Dilution Factor: 1 Method

......... : SW846 VOST
REPORTING PARAMETER RESULT LIMIT UNITS MDL Acetone 0.098 J.B 0.10 

### U9 0.030 Benzene ND 0.010 

### u9 0.0035 Bromobenzene ND 0.010 

### u9 0.0020 Bromochloromethane ND 0.025 

### u9 0.0028 Bromodichloromethane ND 0.010 

### U9 0.0013 Bromoform ND 0.025 

### U9 0.010 Bromomethane 0.034 J 0.050 

### u9 0.0059 2-Butanone ND 0.10 

### u9 0.10 n-Butylbenzene ND 0.010 

### u9 0.0010 sec-Butylbenzene ND 0.010 

### U9 0.0010 tert-Butylbenzene ND 0.010 

### U9 0.0011 Carbon disulfide ND 0.010 

### u9 0.00l9 Carbon tetrachloride ND 0.010 

### u9 0.0012 Chlorobenzene ND 0.010 

### u9 0.0010 Chlorodibromomethane ND 0.025 

### U9 0.0020 Chloroethane ND 0.050 

### U9 0.0062 Chloroform ND 0.010 

### u9 0.0011 Chloromethane 0.28 B 0.050 

### u9 0.0025 2-Chlorotoluene ND 0.010 

### u9 0.0012 4-Chlorotoluene ND 0.010 

### U9 0.0014 1,2-Dibromo-3-chloro- ND 0.050 

### U9 0.013 propane 1,2-Dibromoethane ND 0.025 

### u9 0.0014 Dibromomethane ND 0.025 

### u9 0.0021 1 /2-Dichlorobenzene ND 0.010 

### U9 0.0018 1,3-Dichlorobenzene ND 0.010 

### U9 0.0014 1,4-Dichlorobenzene ND 0.010 

### U9 0.0015 Dichlorodifluoromethane 0.0025 J 0.025 

### U9 0.0024 1,1-Dichloroethane ND 0.010 

### u9 0.0010 1,2-Dichloroethane ND 0.010 

### u9 0.0017 cis-1,2-Dichloroethene ND 0.010 

### u9 0.0010 trans-1,2-Dichloroethene ND 0.010 

### U9 0.0020 1,1-Dichloroethene ND 0.010 

### U9 0.0015 1,2-Dichloropropane ND 0.010 

### U9 0.0017 1,3-Dichloropropane ND 0.010 

### u9 0.0014 2,2-Dichloropropane ND 0.010 

### u9 0.0010 cis-l,3-Dichloropropene ND 0.010 

### u9 0.0017 trans-1,3-Dichloropropene ND 0.010 

### u9 0.0012 1,1-Dichloropropene ND 0.010 

### U9 0.0010 (Continued on next page)AirNova, Inc.
Client Sample ID: M003l UNIT 2 RUN 3 SET 3 TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-024 Work Order 

### #

... : LOK211AA Matrix

......... : AIR
REPORTING PARAMETER RESULT LIMIT UNITS MOL Ethylbenzene NO 0.010 U9 0.0010 Hexachlorobutadiene NO 0.025 u9 0.0025 2-Hexanone NO 0.10 u9 0.0068 Isopropylbenzene NO 0.010 U9 0.0010 p-Isopropyltoluene NO 0.010 U9 0.0010 Methylene chloride 0.012 

### J,B 0.025 u9 0.0022 4-Methyl-2-pentanone NO 0.10 u9 0.10 Naphthalene NO 0.025 u9 0.010 n-Propylbenzene NO 0.010 U9 0.0010 Styrene NO 0.010 U9 0.0013 1,1,1,2-Tetrachloroethane NO 0.010 U9 0.0011 1,1,2,2-Tetrachloroethane NO 0.025 u9 0.0029 Tetrachloroethene NO 0.010 u9 0.0011 Toluene 0.0043 

### J 0.010 u9 0.0010 1,2,3-Trichlorobenzene NO 0.025 U9 0.0010 1,2,4-Trichloro- NO 0.025 U9 0.0016 benzene l,l,l-Trichloroethane NO 0.025 u9 0.0010 1,1,2-Trichloroethane NO 0.025 U9 0.010 Trichloroethene NO 0.010 U9 0.0022 Trichlorofluoromethane NO 0.050 U9 0.0017 1,2,3-Trichloropropane NO 0.025 u9 0.025 l,2,4-Trimethylbenzene NO 0.010 u9 0.0015 1,3,5-Trimethylbenzene NO 0.010 u9 0.0018 Vinyl chloride NO 0.010 U9 0.0021 m-xylene 

### & p-xylene NO 0.020 U9 0.0020 o-xylene NO 0.010 U9 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 102 (50 123) 1,2-Dichloroethane-d4 87 (50 126) Toluene-d8 99 (50 120) Bromofluorobenzene 86 (50 120)
NOTE (S) :

Estimated reJull. Result is**teJltha~** RL. 8 Method blank contamination. The**as~ciated** method blank**~onlains** the targetanalyte at areportable lwei.

### AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 COND

Lot-Sample 

### #

... : HOD270479-027 Date Sampled

... : 04/23/10 Prep Date

...... : 05/01/10 Prep Batch 

### #

... : 0119312 Dilution Factor: 1

PARAMETER Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene1,2-Dibromo-3-chloropropane l,2-Dibromoethane Dibromomethane l,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dich1oroethane cis-l,2-Dichloroethene trans-1,2-Dichloroethene 1,1-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane cis-l,3-Dichloropropene trans-l,3-Dichloropropene l,l-Dichloropropene GC/MS Volatiles
Work Order 

### #

... : LOK251AA Date Received

.. : 04/27/10 Analysis Date

.. : 05/01/10 Matrix

....._... : WATER

Method

......... : SW846 82608
REPORTING RESULT LIMIT UNITS MDL 790 E 10 

### ug/L 2.0 

### 0.042 J 1.0 

### ug/L 0.025 ND 1.0 

### ug/L 0.051 0.72 J 1.0 

### ug/L 0.097 ND 1.0 

### ug/L 0.065 ND 1.0 

### ug/L 0.50 ND 2.0 

### ug/L 0.14 19 5.0 

### ug/L 1.3 

### ND 1.0 

### ug/L 0.038 ND 1.0 

### ug/L 0.034 ND 1.0 

### ug/L 0.035 ND 1.0 

### ug/L 0.039 ND 1.0 

### ug/L 0.054 ND 1.0 

### ug/L 0.041 ND 1.0 

### ug/L 0.11 ND 2.0 

### ug/L 0.13 0.21 J 1.0 

### ug/L 0.036 0.088 J 2.0 

### ug/L 0.064 ND 1.0 

### ug/L 0.050 ND 1.0 

### ug/L 0.050 ND 2.0 

### ug/L 0.33
ND 1.0 

### ug/L 0.094 ND 1.0 

### ug/L 0.097 ND 1.0 

### ug/L 0.035 ND 1.0 

### ug/L 0.043 ND 1.0 

### ug/L 0.049 ND 2.0 

### ug/L 0.48 ND 1.0 

### ug/L 0.034 ND 1.0 

### ug/L 0.046 ND 1.0 

### ug/L 0.054 ND 1.0 

### ug/L 0.036 ND 1.0 

### ug/L 0.066 ND 1.0 

### ug/L 0.048 ND 1.0 

### ug/L 0.036 ND 1.0 

### ug/L 0.053 ND 1.0 

### ug/L 0.059 ND 1.0 

### ug/L 0.056 ND 1.0 

### ug/L 0.042 (Continued 

### on next page)

### AirNova, Inc.
Client Sample ID; M0031 UNIT 2 RUN 3 COND
GC/MS Volatiles Lot-Sample #

... : 

### HOD270479-027 Work Order 

### #

... ; LOK251AA
REPORTING PARAMETER RESULT LIMIT Ethylbenzene 

### ND 1.0 

### Hexachlorobutadiene 

### ND 2.0 

### 2-Hexanone 2." J 5.0 

### Isopropylbenzene 

### ND 1.0 

### p-Isopropyltoluene 

### ND 1.0 

### Methylene chloride 1000 B,E,S 2." 

### 4-Methyl-2-pentanone 

### NO 5." 

### Naphthalene 

### NO 1.0 

### n-Propylbenzene 

### NO 1.0 

### Styrene 

### NO 1.0 

### l,l,l,2-Tetrachloroethane 

### NO 1.0 

### l,l,2,2-Tetrachloroethane 

### NO 1." 

### Tetrachloroethene 

### NO 1." 

### Toluene 0.14 J 

# 1." l,2,3-Trichlorobenzene 

### NO 1.0 

### l,2,4-Trichloro- 

### NO 1." 

### benzene l,l,l-Trichloroethane 

### NO 1.0 

### 1,I,2-Trichloroethane 

### NO 1.0 

### Trichloroethene 

### NO 1.0 

### Trichlorofluoromethane 

### NO 2.0 

### l,2,3-Trichloropropane 

### NO 1.0 

### l,2,4-Trimethylbenzene 

### NO 1.0 

### l,3,S-Trimethylbenzene 

### NO 

## i.o Vinyl chloride 

### NO 2.0 

### m-Xylene & 

### p-Xylene 

### NO 2.0 

### o-Xylene 

### NO 1.0


### PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 100 (79 

### 120) l,2-Dichloroethane-d4 96 (71 

### 127) Toluene-d8 94 

### (80 120) Bromofluorobenzene 92 (69 

### 126)
NOTE (5) : 

# , EslirTlllted result Resullconcentration exceeds tneealibratlon range.

ESlimated re,ult. Result is less th"n RL. B Method blank contamination. The associated method blank containsthe larget analyteat areportable level. S Mass**s~~trometer**saturation. 

### Matrix

......... ; WATER

UNITS 

### MDL ug/L 0.040 ug/L 0.19 ug/L 0.25**ug/J~** 

### 0.036 ug/L 0.034 ug/L 0.070 ug/L 1.3 

### ug/L 0.12 ug/L 0.017 ug/L 0.041 ug/L 0.054 ug/L 

# " 082 ug/L 0.051 ug/L 0.047 ug/L 0.14 ug/L 0.10 ug/L 0.070 ug/L 0.079 ug/L 0.054 ug/L 0.038 ug/L 0.18 ug/L 0.031 ug/L 0.017 ug/L 0.088 ug/L 0.036 ug/L 0.046AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 SET 4 TENAX
GC/MS volatiles Lot-Sample 

### #

... , 1-I0D270479-025 Work Order 

### #

... , LOK221AA Matrix

......... ; AIR Date Sampled

... : 04/23/10 Date Received

.. : 04/27/10 Prep Date

...... : 05/03/10 Analysis Date

.. : 05/03/10 Prep Batch 

### #

... : 0119218 Dilution Factor: 1 Method

......... : SW846 VOST
REPORTING PARAMETER RESULT LIMIT UNITS MDL Acetone 0.047 J,B 0.10 

### u9 0.030 Benzene 0.031 0.010 

### U9 0.0035 Bromobenzene NO 0.010 

### U9 0.0020 Bromochloromethane NO 0.025 

### u9 0.0028 Bromodichloromethane ND 0.010 

### u9 0.0013 Bromoform ND 0.025 

### u9 0.010 Bromomethane 0.0093 J 0.050 

### u9 0.0059 2-Butanone ND 0.10 

### U9 0.10 n-Butylbenzene ND 0.010 

### u9 0.0010 sec-Butylbenzene ND 0.010 

### u9 0.0010 tert-Butylbenzene ND 0.010 

### u9 0.0011 Carbon disulfide 0.74 0.010 

### U9 0.0019 Carbon tetrachloride 0.0013 J 0.010 

### U9 0.0012 Chlorobenzene ND 0.010 

### U9 0.0010 Chlorodibromomethane ND 0.025 

### u9 0.0020 Chloroethane ND 0.050 

### U9 0.0062 Chloroform ND 0.010 

### u9 0.0011 Chloromethane 0.026 J,B 0.050 

### U9 0.0025 2-Chlorotoluene ND 0.010 

### u9 0.0012 4-Chlorotoluene ND 0.010 

### u9 0.0014 1,2-Dibromo-3-chloro- ND O. 050 

### u9 0.013 propane 1,2-Dibromoethane ND 0 .025 

### u9 0.0014 Dibromomethane NO 0.025 

### U9 0.0021 l,2-Dichlorobenzene ND 0.010 

### u9 0.0018 l,3-Dichlorobenzene ND 0.010 

### u9 0.0014 l,4-Dichlorobenzene ND 0.010 

### u9 0.0015 Dichlorodifluoromethane NO 0.025 

### u9 0.0024 l,l-Dichloroethane ND 0.010 

### U9 0.0010 l,2-Dichloroethane ND 0.010 

### U9 0.0017 cis-1,2-Dichloroethene ND 0.010 

### U9 0.0010 trans-l,2-Dichloroethene ND 0.010 

### u9 0.0020 l,l-Dichloroethene NO 0.010 

### u9 0.0015 l,2-Dichloropropane ND 0.010 

### u9 0.0017 1,3-Dichloropropane ND 0.010 

### U9 0.0014 2,2-Dichloropropane ND 0.010 

### U9 0.0010 cis-1,3-Dichloropropene ND 0.010 

### U9 0.0017 trans-l,3-Dichloropropene ND 0.010 

### u9 0.0012 l,l-Dichloropropene ND 0.010 

### u9 0.0010 (Continued 

### on next page)AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 SET 4 TENAX
GC/MS Volatiles Lot-Sample #

... : HOD270479-025 Work Order #

... : LOK221AA Matrix

......... : AIR
REPORTING PARAMETER RESULT LIMIT UNITS MDL Ethylbenzene ND 0.010 

### u9 0.0010 Hexachlorobutadiene ND 0.025 

### u9 0.0025 2-Hexanone ND 0.10 

### U9 0.0068 Isopropylbenzene ND 0.010 

### U9 0.0010 p-Isapropyltoluene ND 0.010 

### u9 0.0010 Methylene Chloride 0.012 J,B 0.025 

### u9 0.0022 4-Methyl-2-pentanone ND 0.10 

### u9 0.10 Naphthalene ND 0.025 

### u9 0.010 n-Propylbenzene ND 0.010 

### U9 0.0010 Styrene ND 0.010 

### U9 0.0013 1,1,1,2-Tetrachloroethane ND 0.010 

### u9 0.0011 l,l,2,2-Tetrachloroethane ND 0.025 

### u9 0.0029 Tetrachloroethene ND 0.010 

### U9 0.0011 Toluene ND 0.010 

### U9 0.0010 l,2,3-Trichlorobenzene ND 0.025 

### u9 0.0010 l,2,4-Trichloro- ND 0.025 

### u9 0.0016 benzene l,l,l-Trichloroethane ND 0.025 

### u9 0.0010 l,l,2-Trichloroethane ND 0.025 

### U9 0.010 Trichloroethene ND 0.010 

### u9 0.0022 Trichlorofluoromethane 0.00a3 J 0.050 

### u9 0.0017 1,2,3-Trichloroprapane ND 0.025 

### u9 0.025 1,2,4-Trimethylbenzene ND 0.010 

### U9 0.0015 1,3,5-Trimethylbenzene ND 0.010 

### U9 0.0018 vinyl chloride ND 0.010 

### u9 0.0021 m-Xylene 

### & p-Xylene ND 0.020 

### u9 0.0020 a-Xylene ND 0.010 

### u9 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoramethane 

### 63 (50 123) 1,2-Dichloroethane-d4 50 (50 128) Toluene-d8 79 (50 120) Bromofluorobenzene 52 (50 120) NOTE(S) :**E~(imated** result. Result Is less**lh~n** RL. B Method blankcontamlnalion. The associated method blankcontain. the largel anDlyle ill. reportable level.AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 SET 4 TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... , HOD270479-026 Work Order 

### #

... , LOK241AA Matrix

......... : AIR Date Sampled

... : 04/23/10 Date Received. _: 04/27/10 Prep Date

...... : 05/03/10 Analysis Date

.. : 05/03/10 Prep Batch :It ••• : 0119218 

### Dilution Factor: 1 Method

......... : SW846 vaST
REPORTING PARAMETER RESULT LIMIT UNITS MDL Acetone 0.10 B 0.10 

### u9 0.030 Benzene ND 0.010 

### u9 0.0035 Bromobenzene ND 0.010 

### u9 0.0020 Bromochloromethane ND 0.025 

### U9 0.0028 Bromodichloromethane ND 0.010 

### U9 0.0013 Bromoform ND 0.025 

### U9 0.010 Bromomethane 0.0088 J 0.050 

### u9 0.0059 2-Butanone ND 0.10 

### u9 0.10 n-Butylbenzene ND 0.010 

### U9 0.0010 sec-Butylbenzene ND 0.010 

### U9 0.0010 tert-Butylbenzene ND 0.010 

### u9 0.0011 Carbon disulfide 0.0071 J 0.010 

### u9 0.0019 Carbon tetrachloride ND 0.010 

### u9 0.0012 Chlorobenzene ND 0.010 

### U9 0.0010 Chlorodibromomethane ND 0.025 

### u9 0.0020 Chloroethane ND 0.050 

### u9 0.0062 Chloroform ND 0.010 

### u9 0.0011 Chloromethane 0.029 J,B 0.050 

### u9 0.0025 2-Chlorotoluene ND 0.010 

### U9 0.0012 4-Chlorotoluene ND 0.010 

### U9 0.0014 1,2-Dibromo-3-chloro- ND 0.050 

### u9 0.013 propane 1,2-Dibromoethane ND 0.025 

### u9 0.0014 Dibromomethane ND 0.025 

### u9 0.0021 1,2-Dichlorobenzene ND 0.010 

### U9 0.0018 1,3-Dichlorobenzene ND 0.010 

### U9 0.0014 1,4-Dichlorobenzene ND 0.010 

### U9 0.0015 Dichlorodifluoromethane ND 0.025 

### u9 0.0024 1,1-Dichloroethane ND 0.010 

### u9 0.0010 1,2-Dichloroethane ND 0.010 

### u9 0.0017 cis-1,2-Dichloroethene ND 0.010 

### U9 0.0010 trans-l,2-Dichloroethene ND 0.010 

### U9 0.0020 l,l-Dichloroethene ND 0.010 

### u9 0.0015 1,2-Dichloropropane ND 0.010 

### u9 0.0017 1,3-Dichloropropane ND O. 010 

### u9 0.0014 2,2-Dichloropropane ND 0.010 

### U9 0.0010 cis-1,3-Dichloropropene ND 0.010 

### u9 0.0017 trans-1,3-Dichloropropene ND 0.010 

### U9 0.0012 l,l-Dichloropropene ND 0.010 

### u9 0.0010 (Continued 

### on next page)AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN 3 SET 4 TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-026 Work Order 

### #

... : LOK241AA
REPORTING PARAMETER RESULT LIMIT Ethylbenzene ND 0.010 Hexachlorobutadiene ND 0.025 2-Hexanone ND 0.10 Isopropylbenzene ND 0.010 p-Isopropyltoluene ND 0.010 Methylene chloride 0.031 B 0.025 4-Methyl-2-pentanone ND 0.10 Naphthalene ND 0.025 n-Propylbenzene ND 0.010 Styrene ND 0.010 1,1,1,2-Tetrachloroethane ND 0.010 1,1,2,2-Tetrachloroethane ND 0.025 Tetrachloroethene ND 0.010 Toluene 0.0073 J 0.010 1,2,3-Trichlorobenzene ND 0.025 1,2,4-Trichloro- ND 0.025 benzene 1,1,1-Trichloroethane ND 0.025 1,1,2-Trichloroethane ND 0.025 Trichloroethene ND 0.010 Trichlorofluoromethane ND 0.050 1,2,3-Trichloropropane ND 0.025 1,2,4-Trimethylbenzene ND 0.010 1,3,5-Trimethylbenzene ND 0.010 Vinyl chloride ND 0.010 m-Xylene 

### & p-Xylene 0.0020 J 0.020 o-Xylene ND 0.010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 90 (50 123) 1,2-Dichloroethane-d4 

# 7, (50 128) Toluene-dB 96 (50 120) BromoEluorobenzene 

# 8, (50 120)
NOTE (S) : B Method blankcontamination. The associated method blank contains the target analyte at a reporuble level. J**E~timaled** resull. ReSUlt is less than RL. Matrix.•.•....• : AIR

UNITS MDL 

### u9 0.0010 

### u9 0.0025 

### U9 0.0068 

### U9 0.0010 

### u9 0.0010 

### u9 0.0022 

### u9 0.10 

### u9 0.010 

### U9 0.0010 

### U9 0.0013 

### u9 0.0011 

### u9 0.0029 

### U9 0.0011 

### U9 0.0010 

### u9 0.0010 

### u9 0.0016


### u9 0.0010 

### U9 0.010 

### u9 0.0022 

### u9 0.0017 

### u9 0.025 

### U9 0.0015 

### U9 0.0018 

### U9 0.0021 

### u9 0.0020 

### u9 0.0010AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN FB TKNAX
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-028 Work Order 

### #

... , LOK281AA Matrix

......... : AIR Date Sampled

... : 04/23/10 Date Received

.. : 04/27/10 Prep Date

...... : 04/30/10 Analysis Date

.. : 04/30/10 Prep Batch It

... : 0119073 Dilution Factor: 1 Method

......... ; SW846 vaST
REPORTING PARAMETER RESULT LIMIT UNITS 

### MOL Acetone 0.049 J.B 0.10 ug 0.030 Benzene 

### NO 0.010 ug 0.0035 Bromobenzene 

### NO 0.010 ug 0.0020 Bromochloromethane 

### NO 0.025 ug 0.0028 Bromodichloromethane 

### NO 0.010 ug 0.0013 Bromoform 

### NO 0.025 ug 0.010 Bromomethane 

### NO 0.050 ug 0.0059 2-Butanone 

### NO 0.10 ug 0.10 n-Butylbenzene 

### NO 0.010 ug 0.0010 sec-Butylbenzene 

### NO 0.010 ug 0.0010 tert-Butylbenzene 

### NO 0.010 ug 0.0011 Carbon disulfide 

### NO 0.010 ug 0.0019 Carbon tetrachloride 

### NO 0.010 ug 0.0012 Chlorobenzene 

### NO 0.010 ug 0.0010 Chlorodibromomethane 

### NO 0.025 ug 0.0020 Chloroethane 

### NO 0.050 ug 0.0062 Chloroform 

### NO 0.010 ug 0.0011 Chloromethane 0.0030 J.B 0.050 ug 0.0025 2-Chlorotoluene 

### NO 0.010 ug 0.0012 4-Chlorotoluene 

### No 0.010 ug 0.0014 l,2-Dibromo-3-chloro- 

### NO 0.050 ug 0.013 propane 1,2-Dibrornoethane 

### NO 0.025 ug 0.0014 Dibromornethane 

### NO 0.025 ug 0.0021 l,2-Dichlorobenzene 

### NO 0.010 ug 0.0018 l,3-Dichlorobenzene 

### NO 0.010 ug 0.0014 l,4-Dichlorobenzene 

### NO 0.010 ug 0.0015 Dichlorodifluoromethane 0.0031 J 0.025 ug 0.0024 l,l-Dichloroethane 

### NO 0.010 ug 0.0010 1,2-Dichloroethane 

### NO 0.010 ug 0.0017 cis-1,2-Dichloroethene 

### NO 0.010 ug 0.0010 trans-l,2-Dichloroethene 

### NO 0.010 ug 0.0020 l,l-Dichloroethene 

### NO 0.010 ug 0.0015 l,2-Dichloropropane 

### NO 0.010 ug 0.0017 l,3-Dichloropropane 

### NO 0.010 ug 0.0014 2,2-Dichloropropane 

### NO 0.010 ug 0.0010 cis-1,3-Dichloropropene 

### NO O. 010 ug 0.0017 tranS-l,3-Dichloropropene 

### NO O. 010 ug 0.0012 l,l-Dichloropropene 

### NO O. 010 ug 0.0010 (Continued on next page)AirNova, Inc.
Client Sample ID: M003! UNIT 2 RUN FB TENAX
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-028 Work Order 

### #

... ; LOK281AA Matrix

......... : AIR
REPORTING PARAMETER RESULT LIMIT UNITS MOL Ethylbenzene NO 0.010 ug 0.0010 Hexachlorobutadiene NO 0.025 ug 0.0025 2-Hexanone NO 0.10 ug 0.0068 Isopropylbenzene NO 0.010 ug 0.0010 p-Isopropyltoluene NO 0.010 ug 0.0010 Methylene chloride 0.073 B 0.025 ug 0.0022 4-Methyl-2-pentanone NO 0.10 ug 0.10 Naphthalene NO 0.025 ug 0.010 n-propylbenzene NO 0.010 ug 0.0010 Styrene NO 0.010 ug 0.0013 1,1,1,2-Tetrachloroethane NO 0.010 ug 0.0011 1,1,2, 2-Tetrachloroethane NO 0.025 ug 0.0029 Tetrachloroethene NO 0.010 ug 0.0011 Toluene 0.0078 J 0.010 ug 0.0010 1,2,3-Trichlorobenzene NO 0.025 ug 0.0010 1,2,4-Trichloro- NO 0.025 ug 0.0016 benzene 1, 1,I-Trichloroethane NO 0.025 ug 0.0010 1,1,2-Trichloroethane NO 0.025 ug 0.010 Trichloroethene NO 0.010 ug 0.0022 Trichlorofluoromethane NO 0.050 ug 0.0017 1,2,3-Trichloropropane NO 0.025 ug 0.025 1,2,4-Trimethylbenzene NO 0.010 ug 0.0015 1,3,5-Trimethylbenzene NO 0.010 ug 0.0018 Vinyl chloride NO 0.010 ug 0.0021 m-xylene 

### & p-Xylene NO 0.020 ug 0.0020 o-xylene NO 0.010 ug 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 94 (50 123) 1,2-Dichloroethane-d4 80 (50 120) Toluene-dB 99 (50 120) Bromofluorobenzene 81 (50 120) NOTE(S):

Estimated result. Result is less Hliln RL. B Method blank contamination The associated method blank contains the target "nslyle at"reponeble level.AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN FB TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... , HOD270479-029 Work Order 

### #

... , LOK291AA Matrix.•.......: AIR Date Sampled

... : 04/23/10 Date Received

.. : 04/27/10 Prep Date

...... : 04/30/10 Analysis Date

.. : 04/30/10 Prep Batch 

### #

... : 0119073 Dilution Factor; 1 Method

......... : SW846 vaST
REPORTING PARAMETER RESULT LIMIT UNITS MDL Acetone 0.044 J,. 0.10 

### u9 0.030 Benzene ND 0.010 

### u9 0.0035 Bromobenzene ND 0.010 

### u9 0.0020 Bromochloromethane ND 0.025 

### u9 0.0028 Bromodichloromethane ND 0.010 

### U9 0.0013 Bromoform ND 0.025 

### U9 0.010 Bromomethane ND 0.050 

### u9 0.0059 2-Butanone ND 0.10 

### u9 0.10 n-Butylbenzene ND 0.010 

### U9 0.0010 sec-Butylbenzene ND 0.010 

### U9 0.0010 tert-Butylbenzene ND 0.010 

### U9 0.0011 Carbon disulfide ND 0.010 

### u9 0.0019 Carbon tetrachloride ND 0.010 

### u9 0.0012 Chlorobenzene ND 0.010 

### u9 0.0010 Chlorodibromomethane ND 0.025 

### U9 0.0020 Chloroethane ND 0.050 

### u9 0.0062 Chloroform ND 0.010 

### u9 0.0011 Chloromethane 0.0065 J,B 0.050 

### u9 0.0025 2-Chlorotoluene ND 0.010 

### U9 0.0012 4-Chlorotoluene ND 0.010 

### U9 0.0014 l,2-Dibromo-3-chloro- ND 0.050 

### U9 0.013 propane l,2-Dibromoethane ND 0.025 

### u9 0.0014 Dibromomethane ND 0.025 

### u9 0.0021 l,2-Dichlorobenzene ND 0.010 

### U9 0.0018 l,3-Dichlorobenzene ND 0.010 

### U9 0.0014 l,4-Dichlorobenzene ND 0.010 

### U9 0.0015 Dichlorodifluoromethane ND 0.025 

### u9 0.0024 1,1-Dichloroethane ND 0.010 

### u9 0.0010 1,2-Dichloroethane ND 0.010 

### u9 0.0017 cis-l,2-Dichloroethene ND 0.010 

### U9 0.0010 trans-1,2-Dichloroethene ND 0.010 

### U9 0.0020 1,1-Dichloroethene ND 0.010 

### u9 0.0015 l,2-Dichloropropane ND 0.010 

### u9 0.0017 l,3-Dichloropropane ND 0.010 

### u9 0.0014 2,2-Dichloropropane ND 0.010 

### u9 0.0010 cis-l,3-Dichloropropene ND 0.010 

### u9 0.0017 trans-l,3-Dichloropropene ND 0.010 

### U9 0.0012 l,l-Dichloropropene ND 0.010 

### U9 0.0010 {Continued on next page}AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN FB TEN/CHAR
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-029 Work Order 

### #

... : LOK29lAA Matrix

......... : AIR
REPORTING PARAMETER RESULT LIMIT UNITS 

### MOL Ethylbenzene 

### NO 0.010 

### u9 0.0010 Hexachlorobutadiene 

### NO 0.025 

### U9 0.0025 2-Hexanone 

### NO 0.10 

### U9 0.0068 Isopropylbenzene 

### NO 0.010 

### u9 0.0010 p-Isopropyltoluene 

### NO 0.010 

### u9 0.0010 Methylene chloride 0.068 B 0.025 

### U9 0.0022 4-Methyl-2-pentanone 

### NO 0.10 

### U9 0.10 Naphthalene 

### NO 0.025 

### U9 0.010 n-Propylbenzene 

### NO 0.010 

### u9 0.0010 Styrene 

### NO 0.010 

### u9 0.0013 1,1,1,2-Tetrachloroethane 

### NO 0.010 

### u9 0.0011 1,1,2,2-Tetrachloroethane 

### NO 0.025 

### U9 0.0029 Tetrachlaraethene 

### NO 0.010 

### U9 0.0011 Toluene 0.0025 J 0.010 

### u9 0.0010 1,2,3-Trichlorobenzene 

### NO 0.025 

### u9 0.0010 1,2,4-Trichloro- 

### NO 0.025 

### u9 0.0016 benzene 1,1,I-Trichloroethane 

### NO 0.025 

### U9 0.0010 l,l,2-Trichloroethane 

### NO 0.025 

### u9 0.010 Trichloroethene 

### NO 0.010 

### u9 0.0022 Trichlorofluoromethane 

### NO 0.050 

### u9 0.0017 1,2,3-Trichloroprapane 

### NO 0.025 

### U9 0.025 l,2,4-Trimethylbenzene 

### NO 0.010 

### U9 0.0015 l,3,S-Trimethylbenzene 

### No 0.010 

### U9 0.0018 Vinyl chloride 

### NO 0.010 

### u9 0.0021 m-Xylene & p-xylene 

### NO 0.020 

### u9 0.0020 a-Xylene 

### NO 0.010 

### u9 0.0010
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibramafluoromethane 87 150 123) 1,2-Dichloroethane-d4 72 150 128) Toluene-dB 93 150 120) Bromofluorobenzene 67 150 120) NOTE{S):

E!limBled result. Result is less Ihan RL. B Melhod blank contamination, The associated method blank conlains the targetan"lyle at areponable level.METHOD BLANK REPORT
GC/MS Volatiles
Client Lot If; ••• ; HOD270479 Work Order 

### #

... , LOPCC1AA Matrix
.... ..... ; AIR MB Lot-Sample 

### ff; HOD290000-073 Prep Date...... ; 04/30/10 Analysis Date.. ; 04/30/10 Prep Batch 

### #
... ; 0119073 Dilution Factor; 1
REPORTING PARAMETER RESULT LIMIT UNITS METHOD Acetone 0.049 J 0.10 

### u9 SW846 VOST Benzene ND 0.010 

### U9 SW846 VOST Bromobenzene ND 0.010 

### U9 SW846 VOST Bromochloromethane ND 0.025 

### U9 SW846 VOST Bromodichloromethane ND 0.010 

### u9 SWB46 VaST Bromoform ND 0.025 

### u9 SW846 vaST Bromomethane ND 0.050 

### u9 SW846 VOST 2-Butanone ND 0.10 

### U9 SWB46 VOST n-Butylbenzene ND 0.010 

### U9 SW846 VOST sec-Butylbenzene ND 0.010 

### U9 SW846 VOST tert-Butylbenzene ND 0.010 

### u9 SW846 VOST Carbon disulfide ND 0.010 

### u9 SWB46 VOST Carbon tetrachloride ND 0.010 

### u9 SWB46 VOST Chlorobenzene ND 0.010 

### U9 SW846 VOST Chlorodibromomethane ND 0.025 

### u9 SW846 VOST Chloroethane ND 0.050 

### u9 SW846 VOST Chloroform ND 0.010 

### u9 SW846 VOST Chloromethane 0.0066 J 0.050 

### u9 SW846 VOST 2-Chlorotoluene ND 0.010 

### U9 SW846 VOST 4-Chlorotoluene ND 0.010 

### U9 SW846 VaST l,2-Dibromo-3-chloro- ND 0.050 

### u9 SW846 VaST propane 1,2-Dibromoethane ND 0.025 

### u9 SW846 VaST Dibromomethane ND 0.025 

### u9 SW846 vaST 1,2-Dichlorobenzene ND 0.010 

### U9 SW846 vaST l,3-Dichlorobenzene ND 0.010 

### u9 SW846 vaST l,4-Dichlorobenzene ND 0.010 

### U9 SW846 vaST Dichlorodifluoromethane ND 0.025 

### u9 SW846 VaST l,l-Dichloroethane ND 0.010 

### u9 SW846 vaST 1,2-Dichloroethane ND 0.010 

### u9 SW846 vaST cis-l,2-Dichloroethene ND 0.010 

### U9 SW846 VOST trans-l,2-Dichloroethene ND 0.010 

### U9 SWB46 vaST 1,1-Dichloroethene ND 0.010 

### u9 SW846 VaST 1,2-Dichloropropane ND 0.010 

### u9 SWB46 vaST 1,3-Dichloropropane ND 0.010 

### u9 SW846 vaST 2,2-Dichloropropane ND 0.010 

### U9 SWB46 VOST cis-1,3-Dichloropropene ND 0.010 

### u9 SWB46 vaST trans-l,3-Dichloropropene ND 0.010 

### U9 SW846 VOST 1,1-Dichloropropene ND 0.010 

### u9 SWB46 vaST Ethylbenzene ND 0.010 

### u9 SWB46 VOST Hexachlorobutadiene ND 0.025 

### u9 SW846 VOST (Continued 

### on next page)

### METHOD BLANK REPORT


### GC/MS Volatiles
Client Lot #

... : 

### HOD270479 Work Order 

### ft ..• : LOPCClAA

PARAMETER 2-Hexanone Isopropylbenzene p-Isopropyltoluene Methylene chloride 4-Methyl-2-pentanone Naphthalene
n- propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene vinyl chloride m-xylene & p-Xylene o-Xylene

SURROGATE Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 Bromofluorobenzene
NOTE (8) : RESULT ND ND ND 0.0027 J 

### ND ND ND ND ND ND ND ND 0.0014 J 

### ND
ND ND ND ND ND ND ND ND ND ND
PERCENT RECOVERY 93 79 92 77

Calculations are performed before rounding to avoid round·off errors In**calculal~d** results. J EsHmated result Result is less [han RL. 

### REPORTING LIMIT UNITS 0.10 u9 0.010 U9 0.010 U9 0.025 

### u9 0.10 u9 0.025 u9 0.010 u9 0.010 U9 0.010 u9 0.025 u9 0.010 u9 0.010 u9 0.025 

### U9 0.025 U9
0.025 u9 0.025 u9 0.010 U9 0.050 u9 0.025 u9 0.010 u9 0.010 u9 0.010 U9 0.020 U9 0.010 u9
RECaVERY LIMITS (50 

### 123) (50 

### 128) (50 

### 120) (50 

### 120) Matrix

..... "

.. : AIR



### METHaD SW846 VaST SW846 VOST SW846 vaST SW846 vaST SW846 vaST SW846 VOST SW846 vaST SW846 VOST SW846 vaST SW846 vaST SW846 vaST SW846 vaST SW846 VOST SW846 vaST
SW846 vaST SW846 vaST SW846 VOST SW846 vaST SW846 vaST SW846 vaST SW846 vaST SW846 VOST SW846 vaST SW846 vaST

### LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS volatiles
Client Lot #

... : HOD270479 HOD290000-073 04/30/10 0119073 Work Order #

... : LOPCC1AC-LCS LOPCC1AD-LCSD Analysis Date

.. : 04/30/10 Matrix

......... : AIR LCS Lot-sample#; Prep Date

...... : Prep Batch #

... : Dilution Factor: 1
PERCENT PARAMETER RECOVERY Benzene 102 100 

### Chlorobenzene 

# " B4 

### 1,I-Dichloroethene 113 lOB 

### Toluene .3 B6 

### Trichloroethene 115 112



### SURROGATE Dibromofluoromethane 1,2-Dichloroethane-d4
Toluene-d8
Broroofluorobenzene

NOTE (5) : Calculationsarc performed before rounding 10**~void** round..,rr errors in calcul8tcd msults. Bold print denolei control paramelers 

### RECOVERY RPO 

### LIMITS RPD 

### LIMITS METHOD (6"7 120) SN846 VOST (67 

### 120) 

# 1.. (0-22) SN846 VOST (5. 

### 120) SN846 VOST (5. 

### 120) 7.7 

### (0-26) SN846 VOST (66 

### 121) SW846 VOST (66 

### 121) 5.1 

### (0-22) SW846 VOST (62 

### 120) SN846 VOST (62 

### 120) B.1 

### (0-22) SN846 VOST (6B 

### 128) SN846 VOST (6B 

### 120) 2.B 

### (0-32) SW846 VOST
PERCENT RECOVERY RECOVERY LIMITS 102 (50 

### 123) 

# •• (50 

### 123) 8' (50 

### 128) 85 (50 

### 128) 100 (50 

### 120) 94 (50 

### 120) B3 (50 

### 120) B1 (50 

### 120)

### LABORATORY CONTROL SAMPLE DATA REPORT
GC/MS volatiles
Client Lot 

### #

... : HOD270479 Work Order 

### #

... : LOPCCIAC-LCS Matrix

......... : AIR LCS Lot-Sample#: HOD290000-073 Prep Date

...... : 04/30/10 Analysis Date

.. : LOPCCIAD-LCSD 04/30/10 Prep Batch #

... : 

### 0119073 Dilution Factor: 1
SPIKE MEASURED PARAMETER AMOUNT AMOUNT 

### Benzene 0.250 0.255 0.250 0.250 

### Chlorobenzene 0.250 0.227 0.250 0.211 

### 1,1-Dichloroethene 0.250 0.284 0.250 0.269 

### Toluene 0.250 0.232 0.250 0.214 

### Trichloroethene 0.250 0.288 0.250 0.280



### SURROGATE Dibromofluoromethane 1,2-Dichloroethane-d4
Toluene-dS
Bromofluorobenzene

NOTE(S) ; Calculation, are perrorrned berore rounding to avoid round·orr errors in calculated results. Bold printdenotes conlrol**par~melers** 

### PERCENT UNITS RECOVERY ug 102 

### ug 100 

### ug 91 

### ug 8. 

### ug 113 

### ug 108 

### ug 93 

### ug 8. 

### ug 115 

### ug 112


### PERCENT RECOVERY RECOVERY LIMITS 102 (SO 123) 

### 99 (SO 

### 123) 8' (SO 

### US) 85 (SO 

### 12S) 100 (SO 

### 120) 

# " (SO 

### 120) 83 (SO 

### 120) 81 (SO 

### 120) RPD 

### METHOD SWS46 VOST 1.9 

### SWS46 VOST SW846 VOST 1.1 

### SWS46 VOST SW846 VOST 5.1 

### SWS46 VOST SWS46 VOST 8.1 

### SW846 VOST SW846 VOST 2.8 

### SW846 VOSTMETHOD BLANK REPORT
GC/MS Volatiles
Client Lot 

### #

... : HOD270479 Work Order 

### #

... , LOPQRlAA Matrix

......... : AIR MB Lot-sample 

### #: HOD290000-2l8 Prep Date

...... : 05/03/10 Analysis Date

.. : 05/03/10 Prep Batch 

### #

... : 0119218 Dilution Factor: 1
REPORTING PARAMETER RESULT LIMIT UNITS METHOD Acetone 0.039 J 0.10 

### u9 SWB46 VOST Benzene ND 0.010 

### u9 SW846 VaST Bromobenzene ND 0.010 

### u9 SW846 VaST Brornochloromethane ND 0.025 

### u9 SW846 VaST Bromodichloromethane ND 0.010 

### U9 SW846 VaST Bromoform ND 0.025 

### U9 SW846 VOST Bromomethane ND 0.050 

### u9 SW846 VOST 2-Butanone ND 0.10 

### u9 SW846 VOST n-Butylbenzene ND 0.010 

### U9 SW846 VOST sec-Butylbenzene ND 0.010 

### U9 SW846 VOST tert-Butylbenzene ND 0.010 

### u9 SW846 VaST Carbon disulfide ND 0.010 

### u9 SW846 VOST Carbon tetrachloride ND 0.010 

### u9 SW846 VOST Chlorobenzene ND 0.010 

### u9 SW846 VOST Chlorodibromomethane ND 0.025 

### U9 SW846 VOST Chloroethane ND 0.050 

### u9 SW846 VOST Chloroform ND 0.010 

### u9 SW846 VOST Chloromethane 0.0097 J 0.050 

### u9 8W646 VOST 2-Chlorotoluene ND 0.010 

### U9 SW846 VaST 4-Chlorotoluene ND 0.010 

### U9 SW846 VOST l,2-Dibromo-3-chloro- ND 0.050 

### u9 SW846 VaST propane 1,2-Dibromoethane ND 0.025 

### u9 SW846 VOST Dibromomethane ND 0.025 

### u9 SW846 VOST 1,2-Dichlorobenzene ND 0.010 

### U9 SW846 VaST l,3-Dichlorobenzene ND 0.010 

### U9 SW846 VaST 1 ,'I-Dichlorobenzene ND 0.010 

### U9 SW846 VaST Dichlorodifluoromethane ND 0.025 

### U9 SW846 VaST l,l-Dichloroethane ND 0.010 

### u9 SW846 VOST l,2-Dichloroethane ND 0.010 

### u9 SW846 VOST cis-l,2-Dichloroethene ND 0.010 

### u9 SW846 VaST trans-l,2-Dichloroethene ND 0.010 

### U9 8W846 VaST l,l-Dichloroethene ND 0.010 

### u9 SW846 VOST l,2-Dichloropropane ND 0.010 

### u9 SW846 VOST l,3-Dichloropropane ND 0.010 

### u9 SW846 VOST 2,2-Dichloropropane ND 0.010 

### u9 SW846 VOST cis-l,3-Dichloropropene ND 0.010 

### u9 SW846 VOST tranS-l,3-Dichloropropene ND 0.010 

### U9 SW846 VOST l,l-Dichloropropene ND 0.010 

### U9 SW846 VOST Ethylbenzene ND 0.010 

### U9 8W846 VOST Hexachlorobutadiene ND 0.025 

### u9 81'1846 VOST (Continued 

### on next page)METHOD BLANK REPORT
GC/MS Volatiles
Client Lot #

... : HOD270479 work Order 

### #

... : LOPQRlAA

PARAMETER 2-Hexanone Isopropylbenzene p-Isopropyltoluene Methylene chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene l,l,l,2-Tetrachloroethane l,l,2,2-Tetrachloroethane Tetrachloroethene Toluene l,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene l,l,l-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane l,2,3-Trichloropropane l,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene vinyl chloride m-xylene 

### & p-Xylene o-Xylene

SURROGATE Dihromofluoromethane l,2-Dichloroethane-d4 Toluene-d8 Bromofluorobenzene
NOTE(S) : RESULT 

### NO NO NO 0.0042 J 

### NO NO NO NO NO NO NO NO 0.0012 J 

### NO
NO NO NO NO NO NO NO NO NO NO
PERCENT RECOVERY 86 77 93 76

Calculations are performed Derore rounding to avoid round·orrerrors in calcuhrted results. J Estimaled re'iult. Resuli i, less than RL. REPORTING LIMIT UNITS 0.10 

### U9 0.010 

### U9 0.010 

### u9 0.025 

### u9 0.10 

### U9 0.025 

### U9 0.010 

### U9 0.010 

### u9 0.010 

### u9 0.025 

### u9 0.010 

### U9 0.010 

### U9 0.025 

### u9 0.025 

### u9
0.025 

### U9 0.025 

### U9 0.010 

### U9 0.050 

### u9 0.025 

### U9 0.010 

### U9 0.010 

### U9 0.010 

### u9 0.020 

### u9 0.010 

### u9
RECOVERY LIMITS (50 123) (50 128) (50 l20) (50 l20) Matrix

......... : AIR

METHaD SW846 VOST SWB46 VaST SWB46 vaST SWB46 vaST SW846 vaST SW846 VOST SW846 VOST SW846 vaST SW846 vaST SWB46 vaST SW846 vaST SW846 VOST SW846 VOST SWB46 vaST
SW846 VOST SW846 VOST SWB46 vaST SWB46 vaST SW846 vaST SW846 vaST SW846 VaST SW846 vaST SWB46 vaST SWB46 vaST

### LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Volatiles
Client Lot 11:.

.. : HOD270479 Work Order #

... : 

### LOPQR1AC-LCS Matrix

......... : AIR LC8 Lot-8ample#: HOD290000-218 Prep Date

...... : 05/03/10 Analysis Date

.. : LOPQRIAD-LCSD 05/03/10 Prep Batch 

### #

... : 0119218 Dilution Factor; 1
PERCENT PARAMETER RECOVERY Benzene 90 92 

### Chlorobenzene 85 81 

### l,l-Dichloroethene 100 105 

### Toluene 88 87 

### Trichloroethene 100 103



### SURROGATE Dibromofluoromethane 1,2-Dichloroethane-d4
Toluene-d8
Bromofluorobenzene

NOTE(S) : Calculaliorn; are perrormed berore rounding \0 avoid round-off errors in ealcul81ed resull'i. Bold printdenoles conlrol paramelers 

### RECOVERY RPD 

### LIMITS RPD 

### LIMITS (67 

### 120) (67 

### 120) 2.3 

### (0-22) (59 

### 120) (59 

### 120) 5.3 

### (0-26) (66 

### 121) (66 

### 121) 0.7 

### (0-22) (62 

### 120) (62 

### 120) 1.7 

### (0-22) (68 

### 128) (68 

### 128) 0.70 (0-32)
PERCENT RECOVERY RECOVERY LIMITS 85 (50 

### 123) 84 (50 

### 123) 73 (50 

### 128) 69 (50 

### 128) 90 (50 

### 120) 85 (50 

### 120) 77 (50 

### 120) 71 (50 

### 120) METHOD SW846 VOST SW846 VaST SW846 VaST SW84.6 VaST SW846 VaST 8W846 VOST 

### 8W846 VeST SW846 veST SW84.6 VaST 8W846 VOSTLABORATORY CONTROL SAMPLE DATA REPORT
GC/MS volatiles
Client Lot 

### #

... : HOD270479 Work Order 

### #

... : LOPQRIAC-LCS Matrix

......... : AIR LCS Lot-Sample#: HOD290000-218 Prep Date

...... : 05/03/10 Analysis Date

.. : LOPQRIAD-LCSD 05/03/10 Prep Batch 

### #

... : 0119218 Dilution Factor: 1
SPIKE MEASURED PARAMETER AMOUNT AMOUNT Benzene 0.250 0.225 0.250 0.230 Chlorobenzene 0.250 0.213 0.250 0.202 1,I-Dichloroethene 0.250 0.251 0.250 0.263 Toluene 0.250 0.220 0.250 0.217 Trichloroethene 0.250 0.260 0.250 0.258

SURROGATE Dibromofluoromethane 1,2-Dichloroethane-d4
Toluene-d8
Bromofluorobenzene

NOTE (S) ; Calculation, are performed before rounding to avoid roull!:l·off errors in calculated r••ults. Bold print. denotes control parameters PERCENT UNITS RECOVERY 

### ug 90 

### ug 92 

### ug 85 

### ug 81 

### ug 100 

### ug 105 

### ug 88 

### ug 87 

### ug 100 

### ug 103
PERCENT RECOVERY RECOVERY LIMITS 85 (50 123) 8. (50 123) 73 (50 128) 69 (50 128) 90 (50 120) 85 (SO 120) 77 (SO 120) 71 (SO 120)RPD METHOD SW846 VOST 2.3 SW846 VOST SW846 VOST 5.3 SW846 VOST SW846 

### VOST 4.7 SW846 VOST SW846 VOST 1.7 SW846 VOST SW846 VOST 0.70 SW846 

### VDST

### AirNova, Inc.
Client Sample ID; M0031 UNIT 2 RUN FB COND
GC/MS Volatiles Lot-Sample #

... : HOD270479-030 Work Order 

### #

... , LOK3AlAA Matrix

......... : WATER Date Sampled

... : 04/23/10 Date Received

.. : 04/27/10 Prep Date

...... : 05/01/10 Analysis Date

.. : 05/01/10 Prep Batch 

### #

... , 0119312 Dilution Factor: 1 

### Method

......... : SW846 8260B
REPORTING PARAMETER RESULT LIMIT UNITS 

### MOL Acetone 16 10 

### ug/L 2.0 

### Benzene 

### NO 1.0 

### ug/L 0.025 Bromobenzene 

### NO 1.0 

### ug/L 0.051 Bromochloromethane 

### NO 1.0 

### ug/L 0.097 Bromodichloromethane 0.084 J 1.0 

### ug/L 0.065 Bromoform 

### NO 1.0 

### ug/L 0.50 Bromomethane 

### NO 2.0 

### ug/L 0.14 2-Butanone 

### NO 5.0 

### ug/L 1.3 

### n-Butylbenzene 

### NO 1.0 

### ug/L 0.038 sec-Butylbenzene 

### NO 1.0 

### ug/L 0.034 tert-Butylbenzene 

### NO 1.0 

### ug/L 0.035 Carbon disulfide 0.17 J 1.0 

### ug/L 0.039 Carbon tetrachloride 

### NO 1.0 

### ug/L 0.054 Chlorobenzene 

### NO 1.0 

### ug/L 0.041 Chlorodibromomethane 

### NO 1.0 

### ug/L 0.11 Chloroethane 

### NO 2.0 

### ug/L 0.13 Chloroform 0.54 J 1.0 

### ug/L 0.036 Chloromethane 

### NO 2.0 

### ug/L 0.064 2-Chlorotoluene 

### NO 1.0 

### ug/L 0.050 4-Chlorotoluene 

### NO 1.0 

### ug/L 0.050 l,2-Dibromo-3-chloro- 

### NO 2.0 

### ug/L 0.33 propane l,2-Dibromoethane 

### NO 1.0 

### ug/L 0.094 Dibromomethane 

### NO 1.0 

### ug/L 0.097 1,2-Dichlorobenzene 

### NO 1.0 

### ug/L 0.035 1/3-Dichlorobenzene 

### NO 1.0 

### ug/L 0.043 l,4-Dichlorobenzene 

### NO 1.0 

### ug/L 0.049 Dichlorodifluoromethane 

### NO 2.0 

### ug/L 0.48 l,l-Dichloroethane 

### NO 1.0 

### ug/L 

## a 034 

### 1,2-Dichloroethane 

### NO 1.0 

### ug/L 0.046 cis-l,2-Dichloroethene 

### NO 1.0 

### ug/L 0.054 trans-l,2-Dichloroethene 

### NO 1.0 

### ug/L 0.036 l,l-Dichloroethene 

### NO 1.0 

### ug/L 0.066 l,2-Dichloropropane 

### NO 1.0 

### ug/L 0.048 l,3-Dichloropropane 

### NO 1.0 

### ug/L 0.036 2,2-Dichloropropane 

### NO 1.0 

### ug/L 0.053 cis-l,3-Dichloropropene 

### NO 1.0 

### ug/L 0.059 trans-l,3-Dichloropropene 

### NO 1.0 

### ug/L 0.056 l,l-Dichloropropene 

### NO 1.0 

### ug/L 0.042 (Continued 

### on next page)AirNova, Inc.
Client Sample ID: M0031 UNIT 2 RUN FB COND
GC/MS Volatiles Lot-Sample 

### #

... : HOD270479-030 Work Order**t~** 

### ... : LOK3A1AA Matrix

......... : WATER
REPORTING PARAMETER RESULT LIMIT UNITS MDL Ethylbenzene ND 1.0 ug/L 0.040**Hexachlo~obutadiene** ND 2.0 ug/L 0.19 2-Hexanone ND 5.0 ug/L 0.25**Isop~opylbenzene** ND 1.0 ug/L 0.036 p-Isopropyltoluene ND 1.0 ug/L 0.034 Methylene chloride 4.8 B 2.0 ug/L 0.070 4-Methyl-2-pentanone ND 5.0 ug/L 1.3 Naphthalene ND 1.0 ug/L 0.12 n-Propylbenzene ND 1.0 ug/L 0.017 Styrene ND 1.0 ug/L 0.041 l,l,l,2-Tetrachloroethane ND 1.0**ug/J~** 0.054 1,1,2,2-Tetrachloroethane ND 1.0 ug/L 0.082 Tetrachloroethene ND 1.0 ug/L 0.051 Toluene 0.23 J 1.0 ug/L 0.047 1,2,3-Trichlorobenzene ND 1.0 ug/L 0.14 1, 2, 4-Trichloro- ND 1.0 ug/L 0.10 benzene 1,1,1-Trichloroethane ND 1.0 ug/L 0.070 l,l,2-Trichloroethane ND 1.0 ug/L 0.079 Trichloroethene ND 1.0 ug/L 0.054 Trichlorofluoromethane ND 2.0 ug/L 0.038 l,2,3-Trichloropropane ND 1.0 ug/L 0.18 l,2,4-Trimethylbenzene ND 1.0 ug/L 0.031 l,3,5-Trimethylbenzene ND 1.0 ug/L 0.017 Vinyl chloride ND 2.0 ug/L 0.088 m-xylene & p-Xylene ND 2.0 ug/L 0.036 o-xylene ND 1.0 ug/L 0.046
PERCENT RECOVERY SURROGATE RECOVERY LIMITS Dibromofluoromethane 100 (79 120) 1,2-Dichloroethane-d4 9, (71 127) Toluene-d8 9S (80 120) Bromofluorobenzene 89 (69 126)
NOTE (8) :

Estimated reSIJl1. Result is Ie

..than RL. B Method blankcontamination. Thea",ociatcd methed blank cootainsthe**l~rget ~n&tyte**  at a reportable level.

### METHOD BLANK REPORT

GC/MS 

### Volatiles
Client Lot 

### it

... ! 

### HOD270479 Work Order #

... ! 

### LOQDMlAA Matrix

......... : WATER MB Lot-Sample #: HOD290000-312 Prep Date

...... : 05/01/10 Analysis Date

.. : 05/01/10 Prep Batch #

... : 0119312 Dilution Factor: 1


### REPORTING PARAMETER RESULT LIMIT UNITS METHOD Acetone NO 10 

### ug/L SW846 8260B Benzene NO 1.0 

### ug/L SW846 8260B Bromobenzene NO 1.0 

### ug/L SW846 8260B Bromochloromethane NO 1.0 

### ug/L SW846 8260B Bromodichloromethane NO 1.0 

### ug/L SW846 8260B Bromoform NO 1.0 

### ug/L SW846 8260B Bromomethane NO 2.0 

### ug/L SW846 8260B 2-Butanone NO 5.0 

### ug/L SW846 8260B n-Butylbenzene NO 1.0 

### ug/L SW846 8260B sec-Butylbenzene NO 1.0 

### ug/L SW846 8260B tert-Butylbenzene NO 1.0 

### ug/L SW846 8260B Carbon disulfide NO 1.0 

### ug/L SW846 8260B Carbon tetrachloride NO 1.0 

### ug/L SW846 8260B Chlorobenzene NO 1.0 

### ug/L SW846 8260B Chlorodibromomethane NO 1.0 

### ug/L SW646 8260B Chloroethane NO 2.0 

### ug/L SW846 8260B Chloroform NO 1.0 

### ug/L SW846 8260B Chloromethane NO 2.0 

### ug/L SW846 8260B 2-Chlorotoluene NO 1.0 

### ug/L SW846 8260B 4-Chlorotoluene NO 1.0 

### ug/L SW846 8260B l,2-Dibromo-3-chloro- NO 2.0 

### ug/L SW646 8260B propane l,2-Dibromoethane NO 1.0 

### ug/L SW646 8260B Dibromomethane NO 1.0 

### ug/L SW846 8260B l,2-Dichlorobenzene NO 1.0 

### ug/L SW846 8260B 1,3-Dichlorobenzene NO 1.0 

### ug/L SW846 6260B 1,4-Dichlorobenzene NO 1.0 

### ug/L SW846 6260B Dichlorodifluoromethane NO 2.0 

### ug/L SW646 8260B l,l-Dichloroethane NO 1.0 

### ug/L SW846 8260B l,2-Dichloroethane NO 1.0 

### ug/L SW846 8260B cis-l,2-Dichloroethene NO 1.0 

### ug/L SW846 8260B trans-l,2-Dichloroethene NO 1.0 

### ug/L SW846 8260B l,l-Dichloroethene NO 

### 1.0 ug/L SW846 8260B l,2-Dichloropropane NO 

### 1.0 ug/L SW846 8260B l,3-Dichloropropane NO 1.0 

### ug/L SW846 8260B 2,2-Dichloropropane NO 1.0 

### ug/L SW846 8260B cis-l,3-Dichloropropene NO 1.0 

### ug/L SW846 8260B trans-l,3-Dichloropropene NO 1.0 

### ug/L SW846 8260B l,l-Dichloropropene NO 1.0 

### ug/L SW846 8260B Ethylbenzene NO 1.0 

### ug/L SW846 8260B Hexachlorobutadiene NO 2.0 

### ug/L SW846 8260B (Continued 

### on next page)METHOD BLANK REPORT
GC/MS
Client Lot 

### #

... : HOD270479 Work Order

PARAMETER RESULT 2-Hexanone ND Isopropylbenzene ND p-Isopropyltoluene ND Methylene chloride 0.37 J 4-Methyl-2-pentanone ND Naphthalene ND n-Propylbenzene ND Styrene ND 1,1,1,2-Tetrachloroethane ND 1,I,2,2-Tetrachloroethane ND Tetrachloroethene ND Toluene ND 1,2,3-Trichlorobenzene ND 1,2,4-Trichloro- ND

benzene l,l,l-Trichloroethane ND 1,1,2-Trichloroethane ND Trichloroethene ND Trichlorofluoromethane ND 1,2,3-Trichloropropane ND 1,2,4-Trimethylbenzene ND 1,3,S-Trimethylbenzene ND vinyl chloride ND m-Xylene 

### & p-Xylene ND a-Xylene ND
PERCENT SURROGATE RECOVERY Dibromofluoromethane 94 1,2-Dichloroethane-d4 91 Toluene-d8 99 Bromofluorobenzene 93 NOTE(S) : Calculations**~re** performed before rounding to avoid round-offerrors in calculated results. J Estimated re,ult. Re,ult is lenlh.n RL. Volatiles

:If- ••• : LOQDM1AA
REPORTING LIMIT UNITS 5.0 ug/L 1.0 ug/L 1.0 ug/L 2.0 ug/L 5.0 ug/L 1.0 ug/L 1.0 ug/L 1.0 ug/L 1.0 ug/L 1.0 ug/L 1.0 ug/L 1.0 ug/L 1.0 ug/L 1.0 ug/L
1.0 ug/L 1.0 ug/L 1.0 ug/L 2.0 ug/L 1.0 ug/L 1.0 ug/L 1.0 ug/L 2.0 ug/L 2.0 ug/L 

### 1.0 ug/L
RECOVERY LIMITS (79 120) (71 127) (80 120) (69 126) Matrix

......... : WATER

METHOD SW846 82608 SW846 82608 SW846 8260B SW846 82608 SW846 82608 SW846 82608 SW846 82608 SW846 8260B SW846 82608 SW846 8260B SW846 82608 SW846 8260B SW846 82608 SW846 8260B
SW846 8260B SW846 82608 SW846 82608 SW846 8260B SW846 8260B SW846 8260B SW846 8260B SW846 8260B SW846 8260B SW846 8260B

### LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Volatiles
Client Lot #

... : HOD270479 Work Order #

... : LOQDMIAC-LCS Matrix

......... : WATER LCS Lot-Sample#: HOD290000-312 Prep Date

...... : 05/01/10 Analysis Date

.. ; LOQDMIAD-LCSD 05/01/10 Prep Batch #

... : 

### 0119312 Dilution Factor: 1
PERCENT PARAMETER RECOVERY Benzene 98 93 

### Chlorobenzene 96 93 

### 1,1-Dichloroethene 101 93 

### Toluene 9. 90 

### Trichloroethene 97 91



### SURROGATE Dibromofluoromethane 1,2-Dichloroethane-d4
Toluene-d8
Bromofluorobenzene

NOTE (S) : Calculations an! performecl before rounding to avoid round·offerrors in calculated results. Bold printdenotes control parameters 

### RECOVERY RPD 

### LIMITS RPD 

### LIMITS (80 

### 121) (80 

### 121) 5.2 

### (0-20) (80 

### 121) (80 

### 121) 3.3 

### (0-20) (70 

### 128) (70 

### 120) 8.8 

### (0-26) (77 

### 124) (77 

### 124) 4.1 

### (0-20) (80 

### 121) (88 

### 121) 6.8 

### (0-20)
PERCENT RECOVERY RECOVERY LIMITS 102 (79 

### 120) 100 (79 

### 120) 97 (71 

### 127) 92 (71 

### 127) 95 (80 

### 120) 97 (80 

### 120) 93 (69 

### 126) 9. (69 

### 126) METHOD SW846 8260B SW846 82GOB SW846 82GOB SW846 8260B SW846 8260B SW846 8260B SW846 8260B SW846 8260B SW84.6 8260B SW846 8260BLABORATORY CONTROL SAMPLE DATA REPORT
GC/MS Volatiles
Client Lot #

... : HOD270479 HOD290000-312 05/01/10 0119312 Work Order 

### ft

... : LOQDM1AC-LCS LOQDM1AD-LCSD Analysis Date

.. : 05/01/10 Matrix

......... : WATER LCS Lot-Sample#: Prep Date

...... : Prep Batch #

... : Dilution Factor: 1
SPIKE MEASURED PARAMETER AMOUNT AMOUNT Benzene 10.0 9.82 10.0 9.32 Chlorobenzene 10.0 9.63 10.0 9.31 1,1-Dichloroethene 10.0 10.1 10.0 9.25 Toluene 10.0 9.41 10.0 9.03 Trichloroethene 10.0 9.69 10.0 9.05

SURROGATE Dibromofluoromethane 1,2-Dichloroethane-d4
Toluene-d8
Bromofluorobenzene

NOTE (S) : Calculations are performed before rounding to avoid round-orrerrorS in calculated result5. Bold printdenotes conlrOl parameters PERCENT UNITS RECOVERY RPD METHOD ug/L 9B 8W846 8260B ug/L 93 5.2 8""846 8260B ug/L 96 8""846 8260B ug/L 93 3.3 8""846 8260B ug/L 101 8""846 8260B ug/L 93 B.B 8""846 8260B ug/L 9. 8""846 8260B ug/L 90 4.1 8W846 8260B ug/L 97 8W846 8260B ug/L 91 6.B SW846 8260B
PERCENT RECOVERY RECOVERY LIMIT8 102 (79 120) 100 (79 120) 97 (71 127) 92 (71 127) 95 (BO 120) 97 (80 120) 93 

### (69 126) 94 

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# II**~NALYTICAL** PERSPECTIVES

28 May 2010 

### JoeJackson AIRNOVA, Inc. 5845 ClaytonAvenue Pennsauken,NJ08109
Ph,; 856-486-1500 FaK: 856-486-9896 E-mail:**iackson@aimoj!!!-.~cQm** 

### Subject Certificate

### ofResults
DearJoe;
Attached to this narrative are the analyticalresults you requested onthe samples submitted for the detennination ofpolychlorinated dibenzo-p-dioxins and dibenzofurans andpolychlorinated bIphenyl congeners. Theinsertbelow summanzes the relevant infonnationpertainingto yourproject Inparticular,the QC annotationsbringto yOUT 

### attention specific analytical observations and assessments made during the sample handling and data interpretationphases. A briefdescriptionofthereport's componentsis providedonthe nextpage. Results reportedrelate only to the itemstested.

Project Information SUmmary When applicable, see QCAnnotationsfordetails

Client Project No. AP Project No. Analytical Protocol

No. Samples Submitted No. Samples Analyzed No. Laboratory Method Blanks No. OPRs I Batch CS3 No. Outstanding Samples

Date Received Condition Received Temperature upon Receipt (e) Extraction within Holding Time Analysiswithin HoldingTlma

Data meet QAlQC Requirements Exceptions Analytical Difficulties 3333 Unit4 P2196 Methods23 & 1668

4 4

1 

## o
29·Apr-2010 

## go"" ·9(Traps & Filten;). -2 (Solvents)**y~**

2714 ExCHANGE DRIVE WILMINGTON, NC28405 PH.: 91 0-794·1613
112**y~**

see noles below
see notes below see noles belowPERSPECTIVES



### QCAnnotations:


### I. Please see the attached appendices for alist ofdataqualifiers and lab identifiers that maybe contained in thereport.



### AnalyticalPerspeclivesremains committedto serving you inthe mosteffective manner. Should you have any questions orneed additional information and technical support, please, do not hesitate to contactus. Thank you for choosing Analytical Perspectives as part ofyour analytical supportteam. Sincerely, 

# r)../i Q

## ~~'«..:.<'::':"il..2...~ /. ',.--1-./ 

### Heather Steele, Ph.D. ProjectManager

2714 EXCHANGE DRIVE WILMINGTON, NC 28405 PH." 91Q·794·1613 212

### APPENDIX A: DATA QUALIFIERS/DATA ATTRIBUTES


# • The reportedconcentrationexceeds thecalibrationrange (upperpointofthe calibration

### cllrve)~l > Indicates highrecoveries. Shown with thenumeric value at the top ofthe range. 

### B The analyte is found in themethodblank, at a level thatis <-lOxthe sample concentration. Two ormore congenersco-elute. InEDDsC denotes the lowestIUPAC congener in a 

### C co-elution group andadditional co-eluters forthe group are shownwith thenumberofthe lowestIUPAC co-eluter. 

### E Thereported concentrationexceeds the calibration range (upperpointofthe calibration

### curve)~ Represents an Estimated MaximumPossIble Concentration. EMPC's al1se III caseswhere 

### EMPC the signal/noiseratio is notsufficientfor peakidentification (the detelTI1ined IOnabundanceratio is outsidethe allowed theoreticalrange), orwherethere is a co-elutIng interference. 

### ETH Indicates thepresence ofa diphenyl ether that appearsto interfere with the quantitationof a furan. The reportedconcentration is the maximum. 

### H/h Ifthe standardrecovery is belowthe method or SOP specified value "H"is assigned. If the obtainedvalue is lessthanhalfthe soecified value "h"is assigned.J 

### J Indicates that ananalytehas a concentration below the reportinglimit(lowestpointofthe calibrationcurve). 

### ND Indicatesa non-detect. 

### NR Indicates a value thatis notreportable. 

### PR Due to Interference, the associated congeneris poorlyresolved, 

### QI Indicates the presenceofa Quantitative interference. 

### Ra The newratio

- [Ra]

-- for 2,3,7,8-TCDD following the J/C14-2,3,7,8-TCDD correction is shownbetween squared brackets inthe DLcolumn.J 

### Denotes "Single IonMode" and is utilized for PCBs where the secondary iontrace has a 

### SI significantlyelevatednoise level dueto background PFK. Responses for suchpeaks are calculatedusing an EMPC approach based solelyonthe pnmalY IOn area(s) andmay be consideredestimates.J 

### U The analytewas not detected. The estImated detection limit (EDL) may be

### reported for this analyte. V 

### The labeled standardrecovery was found to beoutsideofthe method control limits. 

### X Indicatesresultsreportedfrom rein'ection, refractionahon, orrepeatanalyses. 

### APPENDIXB: LABID IDENTIFIERS AR Indicates use ofthe archivedportionofthe sample extract. 

### CU Indicates a samplethatrequired additional clean-uppriortoMS in'ection/processmg, 

### D Indicates a dilution ofthe sample extract. The number thatfollows the "D"Indicates the dilution factor, 

### DE Indicates a dilution perfolTI1ed withthe additionofES (extractIon standard) solution. 

### DUP Designation for a duplicate sample. 

### MS Designation for amatrix spike, 

### MSD Designation for a matrix spike duplicate,



### RJ Indicates a reinjection ofthe sample extract. 

### S Indicates a samplespliL. Thenumberthat follows the "S"indicates the splitfactor. Denotesdata quaiIfiers/attnbutes whoseusewJiI bephased outovertune

# Sample Summary Part 1

Analyte

2,3,7,8·TCDD 1,2,3,7,8-PeCDD 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2.3,7,8,9-Hx.CDD 1,2,3,4,6,7,8-HpCDD 

## oeDO

2,3,7,S-TCDF 1,2,3,7,8-PeCDF 2,3.4.7.8-PeCOF 1,2,3,4,7,8-HxCDF 1,2,3,6,7,6-HxCDF 2,3,4,6,7,8-HxCDF 1,2.3,7,6,9-HxCOF 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF oeDF

ITEF TEQ (ND=-O; EMPC"'O) ITEF TEQ (ND=O; EMPC=EMPC)

ITEFTEQ (ND=DU2; EMPC=O) ITEFTEQ (NO=DU2; EMPC:EMPC)

ITEFTEQ (ND=DL; EMPC;EMPC)

Checkcode LablD
() = DL 

# []=EMPC 

# P2196 - TEQ Project ID: 3333 Unit4 

# .11 ANALYTICAL PERSPECTIVES



### O_7753_MBOO1 Blank Run One



### P9 P9 09 

### (4.18) (3.46) (3.47) (4.25) (3.31) (3.41) (3.77) (3.32) (3.53) (4.15) (3.59) (3.84) (4.29) (3.86) (4.1) (5.01) (4.47) (4.38) (10.7) (9.2) (7.77) (2.72) (1.97) (2.47) (2.51) (2.24) (2.4) (2.51) (2.14) (2.17) (2.31) (1.98) (2.19) (2.29) (1.8) (2.3) (2.27) (2.01) (2.5) (3.04) (2.53) (3.2) (2.84) (1.82) 4.32 

### (3.89) (3 14) (3.72) (8.83) (8.16) (7.48i 0.00 0.00 0.0432 0.00 0.00 0.0432 5.15 4.26 4.49 5.15 4.26 4.49
10.3 8.51 

### 8.93


### 899-148 179-419 

### 153-946 MB1_7753 OF SDSRJ P2196 7753 001RJ P2196 7753 002RJ 

# Method 23

Run Two Run Three

po 

### P9 

### (3.41) (2.03) (4.47) (1.72) (4 17) (1.79) (446) (1.86) (4.82) (2.04) (3.94) (2.03) 42.3 16.7 

### (2.61) (1.23) (2.44) (1.07) (2.49) (1.05) [3.39] (1.03) [2.95] (0.931) [3.72] (1.11) (3.62) (1.25) 79.9 8.19 (387) (1.64) 74.3 [13.2]
0.916 

### 0.0986 1.92 0.112 5.87 2.41 

### 6.45 2.43 11.0 4.74


### 928·313 829·859 P2196_7753_003RJ P2196_7753_004RJ

# Sample Summary Part 1

Analyte

2.3,7,S-ICOO 1,2,3,7,8-PeCDD 1,2,3.4.7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD 1,2,3,4,6,7,8-HpCDD 

### oeoo

2,3,7,8·TCDF 1,2,3,7,S·PeCDF 2,3,4,7.8-PeCDF 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7.8-HxCDF 1,2,3,7,8,9-HxCDF 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,6,9-HpCDF OCDF
WHO·200S TEQ (ND=O; EMPC-=O) WHO·200STEQ (ND:::O; EMPC=EMPC)

WHO-200S TEQ(ND=DU2; EMPC=O) WHO-200S TEQ (ND:DU2; EMPC=EMPC)

WHO-200S TEQ (ND:DL; EMPC=EMPC)

Checkcode Lab 10
() = 

### DL 

### [J = EMPC 

# P2196 - WHO-200S-TEQ Project 10: 3333 Unit4 

# .11 ANALYTICAL PERSPECTIVES

OJ7S3_MBOO1 Blank Run One



### P9 PO P9 (4.18) (3.46) (3.47) (4.25) (3.31) (3.41) (3.77) (332) (3.53) (4.15) (359) (3.84) (4.29) (3.86) (4.1) (5.01) (4.47) (4.38) (10.7) (9 2) (7.77) (2.72) (1.97) (2.47) (2.51) (2.24) (2.4) (2.51) (2.14) (2.17) (2.31) (1.98) (2.19) (2.29) (1.8) (2.3) (2.27) (2.01) (2.5) (3.04) (2.53) (3.2) (2.84) (1.82) 4.32 (3.89) (3.14) (3.72) (8.83) (8.16) (7.48) 0.00 0.00 0.0432 0.00 

### 0.00 0.0432
5.93 

### 4.84 5.09 5.93 

### 4.84 5.09
11.9 

### 9.69 10.1
899·148 179-419 

### 153·946 MB1_7753_0F _SOSRJ P2196_7753_001RJ P2196_7753_002RJ 

# Method 23

Run Two Run Three



### P9 P9 (3.41) (2.03) (4.47) (1.72) (4.17) (1.79) (4.46) (1.86) (4.82) (2.04) (3.94) (2.03) 42.3 16.7 

### (2.61) (1.23) (2.44) (1.07) (2.49) (1.05) [3.39J (1.03) [2.95J (0.931) [3.72J (1.11) (3.62) (1 25) 79.9 8.19 (3.87) (1.64) 74.3 [13.2J 0.834 0.0869 1.84 0.0909 6.63 2.71 7.21 

### 2.72 

### 12.6 5.34


### 928·313 

### 829-859 P2196_7753_003RJ P2196_7753_004RJ

# P2196

- Totals Project 10: 3333 Unit4 

# Sample Summary 

# II ANALYTICAL PERSPECTIVES 

# Method 23 Part2**.IJ-~~~~**
Analyte O_7753_MB001 Blank Run One 

### Run Two Run Three**~ ~** **~ ~** **~** Totals


### TCOOs 0 0 0 0 0 PeCDDs 0 0 0 0 0 HxCDDs 0 0 0 0 0 HpCDDs 0 0 0 0 0 

### OCOO 0 0 0 42.3 16.7
TCOFs 0 0 12.4 3.08 10.1 PeCDFs 0 

# a 0 0 0 HxCDFs 0 0 0 12 0 HpCDFs 0 0 4.32 79.9 8.19 OCDF 0 0 0 74.3 13.2

Total PCDD/Fs(NO-=O; EMPC-=O) 0.00 0.00 16.7 212 35.0 Tolal PCDD/Fs (NO-=O; EMPC-=EMPC) 0.00 0.00 32.1 257 67.0
Tolal PCDDIFs (2378·X ND:DL; EMPC=EMPC) 69.5 59.0 91.0 

### 298 87.8
total,,2378s (NO=O;.EMPC=O)" '0.00

_

# O~OO --' 4.32.

# ',~~;_ 0, 

### .24,9

### T~_I'~318~'**(~D~9,5; .I;Nn',C~O)·**  

## 34.80 -:" 

# 29;50**~3.~8.1** ' _._.--

### -',2:2-1-,-: 

## r_. 37.3'**TotaJt3:78fj;,~D"'1;** E.MPC=1)}-. 69.5' 59.0

. ,- 63.2'**'-~45"** 49.6.
Total2378s(NO:O; EMPC";'1'1 '0.00 0.00 

### 8.65:

.'403 -63:0 TotaI2378sJNO=O.5;EMPC,=1) 

### 34.8 -29.5- 33.8 

### 227-- 48.5 TOlal2378s(ND=1;EMPC=1) 

### 69.5 59.0: 63:2'.

- __ 247 

### -58;8 Checkcode 899-148 179-419 153·946 928-313 829-859 LablD M61_7753_DF_SDSRJ P2196_7753_001RJ P2196_7753_002RJ P2196_7753_003RJ P2196_7753_004RJ

() = DL [] = EMPC

# Sample Summary Part 3

Analyte

Other PCDDIFs (ND:O, EMPC 0)

OtherTCDD Other PeCDD Other HxCDD Other HpCDD

OtherTCDF Other PeCDF Other HxCDF Other HpCOF

Other PCDDIFs (ND=O, EMPC_EMPC)

OlherTCDD Other PeCDD Other HxCDD Other HpCDD

OlherTCDF Other PeCDF Other HxCDF Other HpCDF

Checkcode Lab ID



### ()= DL 

### I]

# =EMPC 

# P2196

- Others Project 10: 3333 Unit4 

# .11
ANALYTICAL PERSPECTIVES



### O_7753_MBOO1 

### Blank Run One


## PO pg pg



### 0 0 0 0 0 0 0 0 0 0 0 0
0 0 12.4 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0
0 0 27.8 

### 0 0 0 0 0 0 0 0 0

899-148 179-419 153-946 MB1_7753 OF_SDSRJ P2196_7753_001RJ P2196_7753 002RJ 

# Method 23

Run Two Run Three



### pg pg



### 0 0 0 0 0 0 0 0
3.08 10.1

0 0 12 0 0 0

6.97 0

0 0 0 0 0 0
24.1 

### 25.7

0 0 197 0

0 3.24

928-313 829-859 P2196_7753_003RJ P2196_7753_004RJ

# Sample Summary Part 5

Analyte

2,3,7,8-TCDD 1.2,3,7.6-PeCDD 1,2,3,4,7,8-HxCDD 1,2,3,6,7,6-HxCDD 1,2,3,7,B,e-HxCOD 1,2,3.4.6,7,8-HpCDD 

### ocoo 2,3,7,8-TCDF 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF 1,2,3.4.7,8-HxCDF 1,2,3,6,7,6-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,6,9·HxCDF 1,2,3,4,6,7.8-HpCDF 1,2,3,4,7,8,9-HpCDF OCDF
TolalTCDD Total PeCDD Total HxCDD Total HpCDD
Total TCOF Total PeCOF Total HxCOF Total HpCOF
Checkcode Lab 10 

# P2196

- DLs Proiect 10: 3333 Unit4 

# .11 ANALYTICAL PERSPECTIVES



### 03753_MBOO1 Blank Run One



### P9 P9 P9 4.18 3.46 3.47 

### 4.25 3.31 3.41 3.77 3.32 353 4.15 3.59 

### 384 429 3.86 

### 4.1 5.01 4.47 

### 4.38 10.7 

### 9.2 7.77 2.72 1.97 2.47 

### 2.51 2.24 

### 2.4 2.51 

### 2.14 2.17 

### 2.31 

### 1.98 2.19 2.29 1.8 2.3 2.27 2.01 

### 2.5 3.04 2.53 3.2 2.84 1.82 

### 233 389 3.14 3.72 8.83 8.16 7.48 4.18 

### 3.46 3.47 4.25 3.31 3.41 

### 4.06 358 3.81 5.01 4.47 

### 4.38 2.72 1.97 2.47 2.51 2.19 2.28 2.45 2.05 2.5 3.3 2.35 2.92 899-148 179-419 153-946 MB1 7753 OF SDSRJ P2196**7753~OO1RJ** P2196**7753~OO2RJ** 

# Method 23

Run Two Run Three



### P9 P9 3.41 

### 2.03 4.47 

### 1.72 4.17 1.79 4.46 

### 186 4.82 2.04 3.94 2.03 10.2 

### 4.47 2.61 1.23 

### 2.44 1.07 

### 2.49 

### 1.05 2.95 1.03 2.71 0.931 2.96 1.11 3.62 1.25 2.71 

### 1.1 3.87 

### 1.64 8.28 3.98 

### 3.41 

### 2.03 4.47 1.72 

### 4.47 

### 1.89 3.94 2.03 261 123 2.46 1.06 3.03 1.07 3.2 1.33 928-313 829-859 P2196**7753~OO3RJ P2196~7753~004RJ** 

### pg

4-'



# " 0' 0'

## ~~" ,>" 

# '"**~'"** 

# ITEF-TEQ ProjecllD: 

## 3333 Unil4 

## P2196

oc· 

## .p**,~o ~c**  ,0 

# ,**.-.** 

## ----, Q ND=O- EMPC-O

-

# ~ ND=O; EMPC=EMPC 

### I D ND=DU2; EMPC=O 

### I 

### I • ND=DU2; EMPC=EMPC 

### I ! 6 ND=DL: EMPC=EMPC I



# "",.!' ,>oc

### 14

12-'



### 10

P9

0'

### ~,?**",~** 

# " 0' 

# ""**<iJ-'l.>~** 

# WHO-2005-TEQ Project 10: 

## 3333 Unit4 

## P2196**o~·**



# ..

,r**~.P** 

# ...**~ ,,'1,~**  

### EJND=O; EMPC=O**~**

### ND=O; EMPC=EMPC 

## o ND=DU2; EMPC=O


### • ND=Dl/2; EMPC=EMPC 

# rn ND=DL; EMPC=EMPC**-~--.,-.**

",. 

# ""



# ...**~**

### pg



# " 0'

# ""

# .'**~~"** >-**~<q~** 

# Totals Project 10: 3333 Unit4 

## P2196



# o· o ,<-",0 0Total PCDD/Fs (ND=O; EMPC=O) DTotal PCDD/Fs (ND=O; EMPC=EMPC)**~Total** PCDO/Fs (2378-X ND=DL; EMPC=EMPC)**~o ~**  

# .,,0 •• <f ,<-",0

### % 

### Rec. 

### Mean Recoveries of Extraction Standards (N=5) 

### Project 10: 3333 Unit4 

## P2196 

# L:Mean o SId.

# Dev.

, iC--,gr 

# , 

# '"**.~ ..$!J~**  

# .'

, Of' 

# ," ,1" <{Yo., 

# ," ," ," <i:P 

### 90



# , 80 ;


### 70

60

50 

## , 

# , 40

30

20··



### 10



## o 

## <:P 0<:) ,,0**<l.~** n;,(f n;,v 

# , , 

# " 

# .. / 

# ," 

# , / ;

### -,;o~- 

# -'-" Z 

# , /.



# , ;: ; 

### % 

## -, /. 

# , , /' /. ,



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### % /. 

# " /. 

### -;:

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# , / 

### /.**~**

# ~ -/. /. / 

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# 9" 

# ,," <:)<:) <:)Q**~0 ~0**  QQ 

### ij 00 -<.,O 

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## .;:s .::s V (f ,,"3 

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# "' 

# , ,'if 

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### /. 

## ;:
--;-: 

## Y.

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### /.


## 0< .0 QX QX 

# " " 

# .. ,

,

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## fi p-0 

# " 

# " 

# ..

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# c? (P fi**v~** 

## c/' .;:s ,,"j 

### 0:<:- 0' ,,"j 

## .;:s 

# '" 1/" 

# , 

# cl "

Method Specification Limits: Tetra-Hexa ES: 40-130%, Hepta-Octa ES: 25-130% (F

# = fail) 

# "**~,** 

# ,-**.~**



# ,,' .0 

# cl -('--



### /.
/.



# ,,' 0° CJ 

# "

### % 

### Rec.

00**~0** 0' 

## 4' Mean Recoveries ofSampling Standards (N=5) Project 10: 3333 Unit4



# " 0S'



# (?0 P2196



# " <§ .0 

## c;< 

# " <§ 

## p c;'"

Method Specification Limits: Tetra-Octa 

### SS: 70-130% (F = 

### fail) 121 Mean



### <§ 

# .0 c;'" 

# " DStd. Dev.**~** ,

# ,

, , 

# ,

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# Sample 10: 

# 0 7753 MBOO1 Method 23 ClientData Sample Data Laboratory Data 

### Name- AirNova, Inc. 

### Matnx: Air Lab Project 10; P2196 

### Date Received: 

### o/a Project ID: 3333 Unit4 WeighWolume: 

### 1 Lab Sample 10 MB1J753_DF _SDSRJ Date Extracted: 06 May 2010 Date Collected- 

### o/a OC Batch No: 

### 7753 DateAnalyzed: 22 May 2010 Split 

### 2 Dilulion-



## - Time Analyzed: 00:46:17 Analyte Cone. (pg) Dl (pg) EMPC (pg) Qualifiers Standard ES Recoveries Qualifiers 2378-TCDD 

### NO 4.18 ES237lHCDD 89-1 12376-PeCOD 

### NO 4.25 ES 12378·PecOD 

### 858 123478-HxCDD 

### NO 3.77 ES 123478-HxCDD 

### 87.9 123676-HxCDD 

### NO 415 ES 123678-HxCDO 

### 87 1237B9-HxCDD 

### NO 4.29 ES 123789-HxCDD 

### 86.9 1234678-HpCOD 

### NO 5.01 ES 1234678-HpCOO 

### 88 OCOD 

### NO 10] ESOCDD 

### 81.7

237S-TeOF 

### NO 2.72 ES 237!3-TCDF 

### 87.2 12378-PeCDF 

### NO 2.51 ES 12378-PeCOF 

### 84.1 23478-PeCDF 

### NO 2.51 ES 23476-PeCDF 

### 83 123476-HxCDF 

### NO 2_31 ES 123478-HxCDF 87.2 123676-HxCDF 

### NO 2.29 ES 123678-HxCDF 

### 859 234678-HxCDF 

### NO 2.27 ES 234678-HxCDF 87.6 123769-HxCDF 

### NO 3.04 ES 123789-HxCDF 

### 88 1234678-HpCDF 

### NO 2.84 ES 1234678-HpCDF 87.9 1234789-HpCDF 

### NO 3.89 ES 1234789-HpCOF 88.6 OCDF 

### NO 8.83 ESOCDF 82.2 Totals Standard 

### SS/AS Recoveries
ss37CI-2376-TCOO 95.5 Total TCDD 

### NO 4.18 

### NO SS 12347-PeCDD 95A Total PeCDD 

### NO 425 

### NO SS 12346-PeCDF 94.8 Total HxCOO 

### NO 4.06 

### NO SS 123469-HxCOF 

### 101 Total HpCOO 

### NO 5.01 

### NO SS 1234689-HpCOF 95.2 AS 1386-TCOO 88.9 Total TCDF 

### NO 2.72 

### NO AS 1368-TCDF 

### 835 Total PeCDF 

### NO 251 

### NO Total HxCOF 

### NO 245 

### NO Total HpCDF 

### NO 3.3 

### NO Total PCDD/Fs 

### NO NO ITEFTEQs TEO: ND=O 

### 0 0 

# .11 ANALYTICAL PERSPECTIVES 2714 Exchange Drive TEO: ND=DU2 5.15 5.15 Wilmin9ton. NC 26405

. USA TEO: ND=DL 10.3 10.3 info@ullralrace.com Tel: +1910794-1613 (Fax: -3919); Toll-Free 866 646-6290 WNW.ullratrace.com Checkcode: 699-146 AP OIF2010 Rev. L Report Created: 22-May-2010 11:09 Analyst: MC

# Sample 10: Blank Method 23 ClientData**Sam~le** 

### Data LabolCltory Data Name: AirNova, Inc Matrix: Air lab Project 10: 

### P2196 Date Received: 29Apr2010 Project 10 

### 3333 Unit4 WeighWolume: 

### 1 Lab Sample 10 P2196_7753_001RJ Date Extracted: 06 May 2010 Date Collected: 22 Apr2010 QC Batch No: 7753 Date Analyzed: 22 May2010 Split: 2 Dilution:



## - Time Analyzed: 

### 01 :36:51 Analyte 

### Cone. (pg) DL (pg) EMPC (P9) Qualifiers Standard ES Recoveries Qualifiers 2378-TCDD 

### NO 3.46 ES2378-TCDD 

### 84.3 12378-PeCDD 

### NO 3.31 ES 12378-PeCDD 86.1 123478-HxCDD 

### NO 3.32 ES 123478-HxCDD 85.2 123678-HxCDD 

### NO 3.59 ES 123678-HxCOD 

### 81.3 123789-HxCDD 

### NO 3.86 ES 123789-HxCDD 

### 80.8 1234678-HpCDD 

### NO 4.47 ES 1234678-HpCOO 

### 83.3 OCOD 

### NO 

### 92 ESOCDO 

### 75.3
2378-TCDF 

### NO 1.97 ES 2378-TCDF 86.2 12378-PeCDF 

### NO 2.24 ES 12378-PeCOF 83.2 23478-PeCDF 

### NO 2.14 E523478·PeCDF 85.8 123478·HxCDF 

### NO 1.98 E5 123478-HxCDF 82.6 123678·HxCDF 

### NO 1.8 E5 123678-HxCDF 84.6 234678·HxCDF 

### NO 2.01 E5234678-HxCDF 78.5 123789·H:w::CDF 

### NO 2.53 E5 1237S9-H:w::CDF 80.3 1234678·HpCDF 

### NO 1.82 E51234678-HpCDF 87.1 1234789·HpCDF 

### NO 3.14 E51234789-HpCDF 

### 75 OCDF 

### NO 8.16 E50CDF 72.1 Totals Standard SSIAS Recoveries , 5537CI-2378·TCDD 

### 99.' 

# l Total TCDD 

### NO 3.46 

### NO 5512347-PeCDD 

### 96.3 Tolal PeCDD 

### NO 3.31 

### NO 55 12346·PeCDF 

### 101 Tolal HxCDD 

### NO 3.58 

### NO 55 123469-H)(CDF 95.2 Tolal HpCDD 

### NO 4.47 

### NO 55 1234589-HpCDF 89.4 AS 1368-TCDD 89.3 Total TCDF 

### NO 1.97 

### NO AS 1368-TCDF 86.6 Tolal PeCDF 

### NO 2.19 

### NO Total HxCDF 

### NO 2.05 

### NO Total HpCDF 

### NO 2.35 

### NO Total PCDD/Fs 

### NO NO ITEF TEQs TEQ: ND=O 

### 0 0 

# IIANALYTICAL PERSPECTIVES 2714 Exchange Drive TEO: ND=DU2 4.26 4.26 Wilmington, NC28405, USA TEQ:ND=DL 8.51 8.51 

# •• info@ullratrace.com Tel: +1 910794-1613 (Fa:w::: ·3919); ToIl·Free 866 846·8290 www.ultratrace.oom Checkcode: 179419 AP DfF 2010 Rev. L Report Created: 22-May-2010 11:10 Analyst: MC

# Sample 10: Run One Method 23 Client Data SamP'le Data Laborato!)f Data 

### Name: AirNova, Inc. Matrix: Air Lab Project ID: P2196 Date Received: 29 Apr 2010 Project 10: 3333 Unit4 WeighWolume. 1 Lab Sample 10 P2196_7753_002RJ Date Extracted: 06 May2010 Date Collected" 20Apr2010 QC Batch No: 7753 DateAnalyzed. 22 May 2010 Split: 

### 2 Dilution:



## - TimeAnalyzed: 02:27:24 Analyte 

### Cone. (pg) 

### OLlpg) EMPe Ipg) Qualifiers standard ES Recoveries 

### Qualifiers 2378-TCOD 

### NO 3.47 ES 2378-TeDD 

### 84.9 12378-PeCDD 

### NO 341 ES 12378-PeCDD 

### 87.9 123478-HxCDD 

### NO 3.53 ES 12347S-HxCDD 

### 90.3 123678-HxCDD 

### NO 3.84 ES 123678-HxCDD 

### 88.1 123789--HxCDD 

### NO 4.1 ES 123789-HxCDD 85.3 1234678-HpCOD 

### NO 4.38 ES 1234678-HpCOD 

### 85.9 

### Deco NO 7,77 ESOCDD 

### 75.3

2378-TCDF 

### NO 2.47 ES 2378-TCDF 82.8 12378-PeCDF 

### NO 2. ES 12378-PeCDF 

### 82.9 23478-PeCDF 

### NO 2.17 ES 23478·PeCDF 83.2 123478'HxCDF 

### NO 2 19 ES 123478-HxCDF 

### 908 123678·HxCDF 

### NO 2.3 ES 123678-HxCDF 89.3 234678·HxCDF 

### NO 2.5 ES 234678-HxCDF 87.9 123789·HxCDF 

### NO 3.2 ES 123789-HxCDF 

### 82 1234678·HpCDF 4.32 

### J ES 1234678-HpCDF 

### 87 1234789·HpCDF 

### NO 3.72 E51234789·HpCDF 83.8 OCDF 

### NO 7.48 ESOCDF 77.9 Totals Standard SS/AS Recoveries SS**37CI·2378~TCDD** 

### 97 Total TCDD 

### NO 3.47 

### NO SS 12347·PeCDD 98.8 Tolal PeCDD 

### NO 341 

### NO 5512346·PeCDF 

### 101 Tolal HxCDD 

### NO 381 

### NO 55 123469-HxCDF 

### 101 Tolal HpCDD 

### NO 4.38 

### NO 551234689-HpCDF 98.5 AS 1368·TCDD 94.2 Total TCDF 12.4 27.8 AS 1368-TCDF 

### 89 Total PeCDF 

### NO 2.28 

### NO Total HxCDF 

### NO 2.5 

### NO Tolal HpCDF 4.32 4.32 Total PCDD/Fs 

### 16.7 32.1 ITEF TEQs TEO ND=O 0.0432 0.0432 

# .11 ANALYTICAL PERSPECTIVES 2714 Exchange Drive TEO: ND=DU2 4.49 4.49 Wilmington. NC 28405. USA TEO: ND=DL 8.93 8.93 info@ullralrace.com Tel: +1 910794-1613 (Fax: -3919); Toll-Free 866 846-8290 www.ultralrace.com Chec::J(code: 153--945 AP DfF 2010 Rev. l ReportCrealed: 22-May·2010 11.10 Analyst: MC

# Sample 10: Run Two Method 23 Client Data**Sam~le** Data Laboratory Data 

### Name: AirNova, Inc Matrix: Air Lab Project 10: 

### P2196 Date Received: 29Apr2010 Project 10: 3333 Unit4 WeightIVolume. 

### 1 lab Sample 

### ID P2196_77S3_003RJ Date Extracted: 06 May 2010 Date Collected: 21 Apr2010 QC Batch No: 

### 7753 Date Analyzed: 22 May 2010 Split: 

### 2 Dilution:



## - Time Analyzed: 03:17:59 Analyte 

### Cone. (pg) DL (pg) EMPC 

### Cpg) Qualifiers Standard ES Recoveries Qualifiers 2378-TCDD 

### NO 3.41 ES 2378-TCDD 

### 80.7 12378-PeCDD 

### NO 4.47 ES 12378-PeCDD 

### 82.2 123478-H)CCDD 

### NO 4.17 ES 123478-HxCOD 

### 83 123678-HxCDD 

### NO 4.46 ES 123678-HxCDD 79.8 123789-HxCDD
, 

### NO 4.82 ES 123789·H)(CDO 79.5 '1234678-HpCDD 

### NO 3.94 ES 1234678-HpCDD 7B.S 

## oeoc 42.3 J ESOCDD 72.9

237S-leOF 

### NO 2.61 ES 2378-TeDF 

### 81.8 12378-PeCDF 

### NO 2.44 ES 12378-PeCDF 

### 82 1 23478-PeCDF 

### NO 2.49 ES 23476-PeCDF 79.2 123478-HxCOF 

### EMPC 3_39 J ES 123476-HxCOF 

### 80.2 123678-HxCDF 

### EMPC 2.95 

### J ES 123678-HxCDF 81.2 234678-HxCDF EMPC 3.72 

### J ES 234678-HxCDF 

### 79.9 123789-HxCDF 

### NO 3.62 ES 123789-HxCDF 

### 79.5 1234678-HpCDF 

### 79_9 ES 1234678-HpCOF 

### 825 12347B9-HpCDF 

### NO 3.87 ES 1234789-HpCDF 

### 79 

## oeDF 74.3 J ESOCDF 75.6 

### Totals Standard 

### SS/AS Recoveries 55 37CI-2378-TCDD 94.5 TotalTeDD 

### NO 697 5512347-PeCDD 

### 90.5 Total PeCOD 

### NO 4.47 

### NO 55 12346-PeCDF 

### 94.6 Total HxCDD 

### NO 4.47 

### NO 58 123469-HxCDF 90.9 Total HpCDD 

### NO 3.94 

### NO 55 1234689-HpCOF 90.5 AS 1368-TCOD 

### 85.5 Total leDF 

### 3.08 24.1 AS 1368-TCDF 

### 80.5 Total PeCDF 

### NO 2.46 

### NO Total HxCDF 

### 12 29.7 Total HpCDF 

### 79.9 79.9 Total PCDD/Fs 

### 212 257 ITEFTEQs 

### TEO: ND=O 

### 0.916 1.92 

# .11 ANALYTICAL PERSPECTIVES 2714 Exchange Drive 

### TEO: ND=DU2 5_87 6.45 Wilmington, NC 28405. USA 

### TEQ:ND=DL 10.8 11 info@ullralrace.com Tel: +1 910794-1613 (Fax: -39191: Toll-Free 866 846-8290 www.ullratrace.com
Checkcode: 928-313 AP DIF 2010 Rev. L ReportCreated: 22-May-2010 11:10 Analyst MC

# Sample 10: Run Three Method 23 Client Data Sample Data Laboratory Data Name_ AirNova, Inc. Matrix: 

### A" Lab Project ID: 

### P2196 Date Received: 29 Apr2010 Project ID: 3333 Unit4 WeighWolume: 

### 1 Lab Sample ID P2196_77S3_004RJ Date Extracted: 06 May 2010 Date Collected: 22 Apr2010 QC Batch No: 7753 DateAnalyzed: 22 May2010 Split 

### 2 Dilution:



## - Time Analyzed: 

### 04:08:33 Analyte Conc. (pg) DL (pg) EMPe (pg) Qualifiers Standard ES Recoveries Qualifiers 2378-TCDD 

### NO 203 ES 2378-TCDD 

### 91.4 12376-PeCDD 

### NO 1.72 ES 12378-PeCDD 

### 975 12347B-HxCDO 

### NO 1.79 ES 12347S-HxCDD 

### 92.2 123678-HxCDD 

### NO 1.86 ES 123678-HxCDO 

### 90.7 123789-HxCDD 

### NO 2.04 ES 123789-HxCDD 

### 89.8 1234678-HpCDD 

### NO 2.03 ES 1234678·HpCDD 

### 88.6 

### aeoc 16.7 J ESOCDD 

### 76.7

2378-TCDF 

### NO 1.23 ES 2378-TCDF 

### 91.5 12378-PeCDF 

### NO 1.07 ES 12378-PeCDF 

### 89.9 23478-PeCDF 

### NO 1.05 E523478-PeCDF 

### 90.3 123478-HxCDF 

### NO 1.03 E5 12'1478-HxCDF 

### 92.2 123678-HxCDF 

### NO 0.931 ES 123678-HxCDF 

### 93 234678-HxCDF 

### NO 1.11 E5234678-HxCDF 

### 86.9 123789-HxCDF 

### NO 1.25 E5123789-HxCDF 

### 88.7 1234678-HpCDF 

### 8.19 J E5 1234678-HpCDF 

### 89.2 1234789-HpCDF 

### NO 1.64 E5 1234789-HpCDF 

### 85.9 

### oeD' EMPC 13.2 J E50CDF 

### 79.1 Totals Standard SS/AS Recoveries 5537CI-2378-TCDD 

### 94 Tolal TCDO 

### NO 2.03 

### NO 5512347-PeCDD 

### 94.5 Total PeCOD 

### NO 1.72 

### NO S512346-PeCDF 

### 95.6 Total HxCDD 

### NO 1.89 

### NO S5123469-HxCDF 

### 94.7 Total HpCDD 

### NO 2.03 

### NO 55 1234689-HpCDF 

### 95.4 AS 1368-TCDD 

### 97_3 Total TCDF 

### 10.1 25.7 AS 1368..-TCDF 

### 941 Tolal PeCDF 

### NO 1_06 

### NO Total HxCDF 

### NO 1.07 

### NO Total HpCDF 

### 8.19 11.4 Total PCDD/Fs 

### 3. 67 ITEF TEQs TEO: ND=O 

### 0.0986 0.112 

# .11 ANALYTICAL PERSPECTIVES 2714 Exchange Drive TEa· ND=DU2 

### 2.41 2.43 Wilminglon, NC28405, USA TEO NO=DL 

### 4.73 4.74 info@ullralrace.com Tel: +1 910794-1613 (Fax: -3919); Toll-Free 866 846-8290 www.ultratrace.com
Checkcode: 829--859 AP DIF 2010 Rev. L ReportCreated: 22-May-2010 11:10 Analyst Me

# Sample Summary

Analyte

PCB-77 PCB-81 PCB-i0S PCB-114 PCB-118 PCB-123 PCB-126 PCB-156/157 PCB-167 PCB-169 PCB-189

TEQs (WHO 2005 M/H) NO=O;EMPC=O NO = 0; EMPC = EMPC

NO = OU2; EMPC = 0 NO = OLl2; EMPC = EMPC
NO=OL;EMPC=O NO = OL; EMPC = EMPC

Checkoode

() = DL 0= EMPC Method Blank O_7753_MBOO1
Conc. P9



### (6.4B) (6.7B) 

### (5.25) (5.21) 23.3 (5.39) (7.95) (11.3) (B.65) (10.B) 

### (11.6)

0.000699 0000699

0.562 0.562

1.12 1.12

PW P2196 Project ID: 3333 Unit 4


# .11 ANALYTICAL PE):l:SPEC'l"VES

Blank Run One

Conc. pg Conc. P9



### (10.9) 16.2 

### (10.7) (14.9) [14.7] 64.9 (B.50) 

### (9.55) 36.2 

### 173 (B.30) 

### (9.07) (B.64) 

### (11.7) (14.6) (20.2) (10.9) (15.2) (14.9) (21.1) (13.1) (17.B)

0.00109 0.00876 0.00153 0.00876

0.659 0.913 

### 0.659 0.913



### 1.32 1 B2 

### 1.32 1 B2



# ,8 

# " HR-PCB

Run Two Run Three

Conc. P9 Conc. pg 12.8 18.2 

### (4.64) (7.67) 6B.B 

### 94.0 (4.5) (5.01) 177 242 (4.34) (4 7B) 

### (6 15) (6.29) 22.9 32.5 

### (7.54) (7.4B) 

### (9.93) (10.7) (B.21) (B.47)



### 0.00933 0.0129 0.00933 0.Q129

0.467 0.489 0.467 0.489



### 0.925 0.965 0.925 0.965



# "**u~**

# PCB Recoveries

Standard

ES 

### PCB-1 ES 

### PCB-3 ES 

### PCB-4 ES 

### PCB-15 ES 

### PCB-19 ES 

### PCB-37 ES 

### PCB-54 ES 

### PCB-77 ES 

### PCB-81 ES 

### PCB-104 ES 

### PCB-tOS ES 

### PCB-114 ES 

### PCB·118 ES 

### PCB-123 ES 

### PCB-126 ES 

### PCB-1S3 ES 

### PCB-1SS ES 

### PCB-1S6/1S7 ES 

### PCB-167 ES 

### PCB-169 ES 

### PCB-170 ES 

### PCB-180 ES 

### PCB-188 ES 

### PCB-169 ES 

### PCB-202 ES 

### PCB-20S ES 

### PCB-206 ES 

### PCB-20B ES 

### PCB-209

Che<:kcode 

### 0= DL 

### 0= EMPC P2196 Project 10: 3333Unit4 

# .11 ANA.LYTICA.L PERSPECTIVES



### Method Blank Blank O_7753_MBOO1
78.5 734 87.3 80.3 879 80.3 105 90.0 94.6 82.0 109 90.9 105 87.2 105 869 108 88.5 107 89.0 107 91.0 104 87.6 105 67.1 107 92.3 103 88.0 107 88.5 110 93.5 104 89.9 105 93.3 100 88.4 116 100 115 980 105 89.8 113 97.4 105 90.0 110 97.2 108 93.4 115 96.9 105 905

,"' 

# " HR-PCB

Run One RunTwo Run Three

73.3 65.9 67.8 79.3 79.7 80.6 80.6 80.8 82.2 91.0 90.8 97.1 83.1 82.0 85.7 92.4 91.9 94.0 89.7 84.4 

### 81.8 8a.2 86.6 88.3 88.3 87.3 90.4 96.5 95.0 99.0 90.4 86.9 91 1 88.4 87.9 88.8 90.3 89.7 90.6 92.6 91.8 92.7 67.2 85.0 65.0 92.3 91.8 96.4 97.3 97.4 102 90.6 67.5 90.4 93.0 89.4 93.6 64.8 85.9 84.1 102 102 107 103 103 104 92.6 90.3 942 100 101 101 91.2 89.2 94.6 98.0 98.1 98.1 98.3 98.7 97.7 101 101 102 95.7 93.5 94.0**~11** 

# " u;

# " ,."' ,.<**J>~** 

# +-'" "" "'**+~"** PCBTEQ Project 10: 3333 Unit4 

## P2196



# ,. <i;'b'<::' 

### o<f ",<**~o ~**  

# .-,,0 ,§> 

# ,,, .-,,<**ND**

# = 0, EMPC = 

### 0 .NO = 

### 0; EMPC = 

### EMPC DND = 

### DU2; EMPC = 

### 0 

## o NO = DU2; EMPC = EMPC • NO = DL; EMPC = 0 iiiNO = DL; EMPC 

### = EMPC



## --------

-**------~-.--------------** ..

### 250

200 /



### 150

pg 

### 100-



### 50



# o , ,p"?

0'

### ~"," -0{Jv 

# *"' 

# ,." 

# .'"**~#** PCBWHO Project 10: 

## 3333 Unit4 

## P2196**¥~-** 

## ...



# * <:iJ-'?><::' 

# ,- ,

"0 o <>co" 

# " ,**~p** 

### <>co" 

## '"**~o!'** <>co"

II!IPCB-77

### .PCB-8!E~CB-105 DPCB-114 .PCB-118

### ~PCB-123 .PCB-126

### DPC~_:~56/157**.PCB~167** .PCB-169 DPCB-1@

## in 

# " z 

# -**S~~-66 aO~-E6**  OLL-L6

88-08 Le-6.!.

# Sample 10: Blank
Client Data Sample Data Name: AirNova,lnc_ Matrix: Project 10: 3333 Unit4 WeighWolume: Dale Collected: 22-Apr-l0 Analyle Cone. pg PCB-7733'44"-TeCB NO PCB-81344'5-TeCB NO PCB-10S 233'44"-PeCB 

### EMPC PCB-1142344'S-PeCS NO PCB-lIB23'44'5-PeCB 36.2 PCB-12323'44'5'-PeCB NO peB-12633'44'S-PeCB NO PCB-156/IS7233'44'S/233'44'S'-HxCB NO PCB-16723'44'55'-H)(CB NO PCB-16933'44'5s'-HxCB NO PCB-189233'44'55'-HpCB NO
TEQs (WHO MlH)

ND"'O 0.00109 ND=O.sxDL 0.659



# "



# .11 ANALYTICAL PERSPECTIVES Laboratory Data Air Project No.: 1 Sample 10. 

## ac Balch No.: 

### DL EMPC pg pg 10.9 10.7 14.7 8.5

8.3 8.64 14.6 10.9 14.9 13.1

0.00153 0.659

2714 Exchange Drive T: 910 794-1613 Wilmington F: 910 794-3919 North Carolina 2840S Info@ultratrace.com USA www.ultratrace.com 

# Method HR-PCB

P2196 Date Received- 29-Apr-l0 P2196_7753_PCB_OOI Date Extracted: 6-May-l0 7753 Date Analyzed: 20-May-l0 Qualifier Standard Recovery % ESPCB-' 73.4 ES PCB-3 80.3 J ES PCB-4 80.3 ES PCB-1S 90 B ES PCB-19 82 ES PCB-37 90.9 ES**PCB~54** 87.2 C ES PCB-77 86.9 ES PCB-81 88.5 ES PCB-104 89 ES PCB-105 91 ES PCB-114 67.6 ES PCB-118 87.1 ES PCB-123 92.3 ES PCB-126 88 ES PCB-153 88.5 ES PCB-155 93.5 ES PCB-I56/IS7 89.9 ES PCB-167 93.3 ES PCB-169 88.4 ES PCB-HO 100 ES PCB-180 98 ES PCB-188 89.8 ES PCB-1a9 97.4 ES PCB-202 90 ES PCB-20s 97.2 ES PCB-2OO 93.4 ES PCB-208 98.9 ES PCB-209 90.5

SfSS PCB-28 92.6 SfSS PCB-11t 93.4 CS/SS PCB-H8 94.7

AP PCB 2010 Rev. A

# Sample 10: Run One
Client Data Sample Data Name: AirNova, Inc. Matrix: Project 10. 3333 Unil4 WeighWolume: Dale Collected: 20-Apr-10 Analyte Cone. pg PCB-77 33'44'-TeCB 162 PCB-81344'5-TeCB NO PCB-IDs233"44'·PeCB 

## 64.' PCB-114**2344'5~PeCB** NO PCB-lIB23'44'5-PeCB 173 PCB-12323'44'5'-PeCB NO PCB-12633'44'5-PeCS NO PCB-156/1S7 233'44'5/233'44'S'-HxCB NO PCB-16723'44'5S"-HxCB NO PCB·16933'44'55'-HxCB NO PCB-189233'44'5S'-HpC8 NO

TEQs (WHO MfH)

NO = 0 0.00876 ND=0.5xDL 0.913



# "



# .11 ANALYTICAL. PERSPECTIVES Laboratory Oata Air Project No_: 1 Sample 10: QC Balch No.: 

# 0' EMPC PO pg
14.9
9_55

9.07 11.7 20.2 15.2 21-1 17.6

0.00676 0.913

2714 Exchange Drive T: 910 794-1613 Wilmington F: 910 794-3919 North Carolina 28405 info@ultratrace.com USA www.ultrntrace.com 

# Method HR-PCB

P2196 Date Received: 29-Apr-l0 P2196_7753_PCB_002 Dale Exlrac:ed: 6_May_10 7753 Date Analyzed: 20-May-10 Qualifier Standard Recovery % J ES PCB-1 73.3 ESPCB-3 79.3 ES PCB-4 80.6 ES PCB-IS 91 

# • ES PCB-19 83.1 ES PCB-37 92.4 ES PCB-54 89.7 C ES PCB-77 88.2 ES PCB-81 88.3 ES PCB-l04 96.5 ES PCB-10S 90.' ES PC6-114 66.4 ES PCB-116 90.3 ES PCB-123 92.6 ES PCB-126 87.2 ES PCB-153 92.3 ES PCB-155 97.3 ES PCB-156/157 90.8 ES PCB-167 93 ES PCB-169 84.8 ES PCB-170 102 ES PCB-180 103 ES PCB-1BB 92.6 ES PCB-1a9 100 ES PCB-202 91.2 ES PCB-20S 

# ,. ES PCB-206 98.3 ES PCB-208 101 ES PCB-209 95.7

SISS PCB-28 97.7 CS/SS PCB-111 97.5

SISS PCB-178 95.4

AP PCB 2010 Rev. A

# Sample 10: Run Two
Client Data Sample Data Name: AirNova, Inc. Matrix: Project 10: 3333 Unit4 WeighWolume: Date Collected: 21-Apr-l0 Analyte Conc. pg PCB-77 33'44'-TeCB 12.8 PCB-81344'S-TeCB NO PCB-IDS 233'44'-PeCB 68.6 PCB-1142344'S-PeCS NO PCB-lIB 23'44'5-PeCB 177 PCB-12323'44'5'-PeCB NO PCB-12633'44'5-PeCB NO PCB-15611S7233'44'51233"44'5'-HxCB 22.9 PCB-t6723'44'55'-HxCB NO PCB-t6933'44'S5'-HxCB NO PCB-189233'44'S5'-HpCB NO

TEQs (WHO MIH)

NO =0 0.00933 ND=O.5xDL 0.467

pp



# .11 ANALYTICAL PERSPECTIVES Laboratory Data Air Project No.: 1 Sample 10: QC Batch No.: DL 

### EMPC PO pg
4.64

4.5

4.34 6.15

7.54 9.93 8.21

0.00933 0.467

2714 Exchange Drive T: 910 794-1613 Wilmington F: 910 794-3919 North Carolina 28405 info@ultratrace.com USA www.ullratrace.com 

# Method HR-PCB

P2196 Date Received: 29-Apr-l0 P21963753_PCB_003 Date Extracted: 6-May-tO 7753 DaleAnalyzed: 20-May-l0 Qualifier Standard Recovery % J ES PCB-l 65.9 ESPCB-3 79.7 ES PCB-4 808 ES PCB-IS 90.8 B ES PCB-19 82 ES peS-37 91.9 ES PCB-54 84.4 JC ES PCB-77 86.6 ES PCB-81 87.3 ES PCB-1M 95 ES PCB-lOS 88.9 ES PCB-114 87.9 ES PCB-118 89.7 ES PCB-123 91.8 ES PCB-126 85 ES PCB-153 91.8 ES PCB-155 97.4 ES PCB-156/157 87.5 ES PCB-16l 89.4 ES PCB-169 85.9 ES PCB-170 102 ES PCB-laO 103 ES PCB-18S 90.3 ES PCB-1a9 101 ES PCB-202 89.2 ES PCB-20S 98.1 ES PCB-20e 98.7 ES PCB-20B 101 ES PCB-20e 93.5

SfSS PCB-28 96.3 CS/SS PCB-111 95.2 CS/SS PCB-178 96.2

AP PCB 2010 Rev. A

# Sample 10: Run Three
Client Data Sample Data Name: AirNova, Inc_ Matrix: Project 10: 3333 Unit4 WeighWolume: Dale Collected: 22-Apr-l0 Analyte Conc.

PCB-77 33'44'-TeCB 18.2 PCB-al 344'5-TeCB NO PCB-IDS 233'44'-PeCB 94 PCB-1142344'S-PeCS NO PCB-1tB23"44'5-PeCB 242 PCB-12323"44'S'-PeCB NO peB-12633'44'S-PeCB NO PCB-156/1S7233'44'S/233'44'5'-HxCB 32_5 PCB-16l23'44'55'-HxCB NO PCB-16933'44'55'-HxCB NO**PCB~189** 233'44'55'-HpCB NO

TEQs (WHO M/H)

NO = 0 0.0129 NO=O.5xOL 0.489



# us



# .11 ANALYTICAL PERSPECTIVES Laboratory Data Air Project No_: 1 Sample 10_ QC Balch No.: 

### OL EMPC pg pg
7.67

5.01

4.78 6.29

7.48 10.7 8.47

0.0129 0.489

2714 Exchange Drive T: 910 794-1613 Wilmington F: 910 794-3919 North Carouna 28405 info@ultratrace.com USA www.ultratrace.com 

# Method HR-PCB

P2196 Date Received. 29-Apr-l0 P2196J7S3_PCB_004 Date Extracted: 6-May-l0 7753 Date Analyzed: 20-MaHO Qualifier Standard Recovery % J ES PCB-1 67.8 ES peS-3 80_6 ES PCB-4 82.2 ES PCB-IS 97_1 ES PCB-19 85.7 ES PCB-37 94 ES PCB-54 81.8 JC ES PCB-77 88_3 ES PCB-Sl 90.4 ES PCB-104 99 ES PCB-105 91.1 ES PCB-114 88.8 ES PCB-118 90.6 ES PCB-123 92.7 ES PCB-126 B5 ES PCB-153 96.4 ES PCB-155 102 ES PCB-156/157 90.4 ES PCB-167 93.6 ES PCB-169 84.1 ES PCB-170 107 ES PCB-180 104 ES PCB-188 94.2 ES PCB-189 101 ES PCB-202 94.6 ES PCB-205 98.1 ES PCB-206 97.7 ES PCB-208 102 ES PCB-209 94 CS/SS PCB-28 93.7 CSISS PCB-111 93.6 CS/SS PCB-17S 92.3

AP PCB 2010 Rev. A

### Appendix C
Emission Calculations

### Unit NO.1

## Spruance Genco, LLC Richmond, Virginia 

## Project No. 3333 April 16, 2010 Unit No.1 Run No.1 Coal Analysis for F Factor Calculation

F FACTOR CALCULATION

INPUT % 

### H= 

## 4.82 Hydrogen Content 

### (%) INPUT 

### %c= 

## 76.49 Carbon Content (%) 

### INPUT 

### %N= 

## 1.4 Nitrogen Content (%) 

### INPUT 

### %0= 

## 4.54 Oxygen Content (%) 

### INPUT 

### %s= 

## 0.69 SulfurContent (%) 

### INPUT GCV= 

## 13494 Gross Calorific Value (Btu/lb)



### Fd = 10'6'[(3.64'%H) 

### +(1.53'%C) 

### + (0.57'%S) 

### + (0.14'%N)

- 

### (0.46'%02))1 GCV 

### Fd = 

### 9862 scf/MMBtu

## Spruance Genco, LLC Richmond, Virginia 

## Project No. 3333 April 19, 2010 Unit No.3 Run No.2 Coal Analysis for F Factor Calculation

F FACTOR CALCULATION

INPUT 

### %H= 

## 5.04 Hydrogen Content 

### (%) 

### INPUT 

### %c= 

## 76.71 Carbon Content (%) 

### INPUT 

### %N= 

## 1.56 Nitrogen Content 

### (%) INPUT 

### %0= 

## 6.35 Oxygen Content 

### (%) 

### INPUT 

### %8= 

## 1.05 SulfurContent 

### (%) INPUT GCV= 

## 13696 Gross Calorific Value (Btu/lb)



### Fd = 

### 10"6'"[(3_64"%H) 

### + (1.53*%C) 

### + (0,57"'%S) 

### +(O.14*%N)

- 

### (0.46"%02)] /GCV 

### Fd

# = 9755 scf/MMBtu

## Spruance Genco, LLC Richmond, Virginia Project No, 3333 April 19, 2010 Unit No.3 Run No.3 Coal Analysisfor F Factor Calculation

F FACTOR CALCULATION

INPUT % 

### H

# = 5.12 Hydrogen Content (%) INPUT 

### %c= 

## 78.65 Carbon Content 

### (%) INPUT 

### %N= 

## 1.67 Nitrogen Content (%) 

### INPUT 

### %0= 

## 5.68 Oxygen Content (%) INPUT 

### %s= 

## 1 04 Sulfur Content (%) INPUT GCV= 

## 13902 Gross Calorific Value (Btu/lb)

Fd

# =1011

### 6'" ((3**64~O/oH)** 

### + (1.S3*%C) 

### + (O.57*%S) + 

### (O.14*%N)

- (0-46·%02)]1 GCV 

### Fd = 

### 9868 scf/MMBtuClient Project No. Test Location Test Date Spruance Genco. LLC 3333 Unit #1 04/12110

Parameter: 

### Oxygen Instrument

### Soan f% 

### 02)' 22.03

Actual Calibration 

### Gas Value (% 

### 02): Anal\:::zerCalibration 

### ResQ.onse (% 

### 021: AnalvzerCalibration Error1% Span):

Zero Sy:stem Calibration Gas A{2Q.arent Init. 

### S:iS. Init. 

### Sk:s. Final

### S\:::s. Final

### S:k:s.**~** Calib 

### Cal. Bigs. Calib. 

### Cal. Bigs. 

### Run Cone, ResDons.e (% span) ResQ.Onse f% s{2an)



### 1 4.80 0.13 0.01 0.04 0.23 2 4.96 0.04 0.23 0.06 0.32 3 4.27 0.06 0.32 0.10 0.50 

### 4 0.00 0.10 0.50 0.00 0.05 

### 5 0.00 0.00 0.05 0.00 0.05 6 0.00 0,00 0.05 0.00 0.05 

### 7 0.00 0.00 0.05 0.00 0.05 8 0.00 0.00 0.05 0.00 0.05 9 

### 0.00 0.00 0.05 0.00 0.05 10 0.00 0.00 0.05 0,00 0.05 11 0.00 000 0.05 0.00 0.05 12 0.00 0.00 0.05 0.00 0.05 

### AirNova, Inc. Page 1 EPA Method 6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

Ang/wrCalib. 

### Gases. UQ.scale
zero low mid high 

### S\:::s. Cal. Gas 

### 0.00 

### NIA 11.90 22.03 11.90 -0.01 

### NIA 11.70 21.79 11.70 -0.05 0.00 -0,91 -1.11

Ugscale Sy:stem Calibration Gas Ca/ib. Init. 

### S:I:§. Init 

### S\:::s. Final S:iS. Final

### S!!s. Calib. 

# """"'" Drift Calib. 

### Cal. Bias Calib. Cal. Bias Drift**~** (% span) 

### ReSQ.onse f% 

### span! Response f% sQ.anJ (% 

### span) Cone.



### -0.41 11.80 0.45 11.70 0.00 -0.45 4.81 0.09 11.70 0.00 11.70 0.00 0.00 5.02 0.18 11.70 0.00 11.93 1.04 1.04 4.25 -0.45 11.93 1.04 0.00 -53,11 -54.15 ·0.10 0.00 0.00 -53.11 0.00 -53.11 0.00 

### ERR 0.00 0,00 -53.11 0.00 -53.11 0.00 

### ERR 0.00 0.00 -53.11 0.00 -53.11 0.00 

### ERR 0.00 0.00 -53.11 0.00 -53.11 0.00 

### ERR 0.00 0.00 -53,11 0.00 -53.11 0.00 

### ERR 0.00 0.00 -53.11 0.00 -53,11 0.00 

### ERR 0.00 0.00 -53.11 0.00 -53.11 0.00 

### ERR 0.00 0.00 -53.11 0.00 -53.11 0.00 

### ERR

## o

Client 

### ProjectNo. Test Location Test Date 

### Spl1Jance Genco, LLC 

### 3333 Unit #1 

### 04112110



### Parameter: 

### Carbon Dioxide Instrument Span f% 

### C02): 22.28

Actual Calibration Gas Value f% C021: AnalvzerCalibration 

### Response f% 

### C02): AnalyzerCalibration Errorf% Span):

Zero Sy:§tem Calibration Gas AQQarent Init, Sys Init. Sys. Final Sys. Final $\,,8.

Stack Calib. 

### Cat Bias Calib. Cal. Bias 

### Run Cone. Response t% span) Response t% soan)



### 1 15.00 0.00 0.10 -0.12 -0.49 2 14.55 -0.12 -0.49 0.00 0.04 3 14.70 0.00 0.04 -0.12 -0.49 4 0.00 -0.12 -0.49 0.00 0.04 

### 5 0.00 0.00 004 0.00 0.04 

### 6 0.00 0.00 0.04 0.00 0.04 7 0.00 0.00 004 0.00 0.04 8 0.00 0.00 0.04 0.00 0.04 g 

### 0.00 0.00 0.04 0.00 0.04 10 0.00 0.00 0.04 0.00 0.04 11 0.00 0.00 0.04 0.00 0.04 12 0.00 0.00 0.04 0.00 

### 0.04 

### AirNova, Inc. Page2 EPA Method6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)**An~l~zer** Calib. Gases Uuscale 

### zero low mid high 

### SI:§:. Qal. 

### Gas 

### 0.00 N/A 

### 12.39 22.28 

### 12.39 -0.01 N/A 12.46 

### 21.98 12.46 -0.04 0.00 0,31 

### -1.35

U[!scale Sy:stem Calibration Gas GaliP. Init. Sys. fnit Sys Final SjI's. Final Sys, Galib. Actua/ Drift Calib. Cal. Bias Calib. Cal, 

### Bias Drift Stack t% span) Response t% span) Response t% span) t% span) Cone.



### -0.54 12.35 -0.49 12.33 -0.58 -0.09 15.05 0.54 12.33 -0.58 12.33 -0.58 0.00 14.61 -0.54 12.33 -0.58 12.45 -0.04 0.54 14.69 0.54 12.45 -0.04 0.00 -55.92 -55.88 0.12 0.00 0.00 -55.92 0.00 -55.92 0.00 

### ERR 0.00 0.00 -55.92 0.00 -55.92 0.00 

### ERR 0.00 0.00 -55.92 0.00 -55.92 0.00 

### ERR 0.00 0.00 -55.92 0.00 -55.92 0.00 

### ERR 0.00 0.00 -55.92 0.00 -55.92 0.00 

### ERR 0.00 0.00 -55.92 0.00 -55.92 0.00 

### ERR 0.00 0.00 -55.92 0.00 -55.92 0.00 

### ERR 0.00 0.00 -55.92 0.00 -55.92 0.00 

### ERR

## o

Client Project No. Test Location Test Date 

### Spruance Genco, LLC 

### 3333 Unit #1 04/12/10

Parameter: 

### Sulfur Dioxide InstrumentSpan (ppmV

### 8021: 443

Actual Calibration Gas Value (Ppm V

### S021: AnalyzerCalibration Response (ppm V

### S02): AnalyzerCalibration Error(% Soan):

Zero**S~stem** Calibration Gas A(lQarent Init. S"-S. Init. S!!:S:. FinalS'iS Final S\:,:s.

Stack Calib. Cal. Bias Calib Cal. Bias Run Conc. Response (% span) Response (% span)



### 1 32.2 -0.2 0.00 2.4 0.60 2 21.0 2.A 

### 0.60 -2.4 -0.50 3 19.6 -2.4 -0.50 -2.4 -050 4 0.0 

### -2.4 -0.50 0.0 0.05 

### 5 0.0 0.0 0.05 0.0 0.05 6 0.0 0.0 0.05 0.0 0.05 7 0.0 0.0 0.05 0.0 0.05 

### 8 0.0 0.0 0.05 0.0 0.05 9 

### 0.0 0.0 0.05 0.0 0.05 10 0.0 0.0 0.05 0.0 0.05 11 0.0 0.0 0.05 0.0 0.05 12 0.0 0.0 0.05 00 0.05 

### AirNova, Inc. Page 3 EPA Method 6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

Anal'izerCalib. Gasf:S: UQ.sca/e 

### zero low mid high S!:::,:s. e.g/. 

### Gas 

### 0.0 0.0 222.0 443.0 

### 222.0 -0.2 

### 0.0 224.6 

### 441,0 224.6 -0,05 0.00 

### 0.59 -0.46

URscale Sllstem Calibration Gas Calib. Init.**~vs.** IniI. S,,-s. Final S,,-s.**FinaIS~.** Cafib, Actual Drift Calib. Cal- Bias Calib. Cal. Bias Drift Stack (% span) Response (% 

### span) Response (% span! (% 

### span) Conc.



### 0.60 224.6 0.00 222.2 -0.55 -0.55 

### 31.1 -1.10 222.2 -0.55 222.2 -0.55 0.00 21.0 0.00 222.2 -0.55 224.6 0.00 0.55 21.6 0.55 224.6 0.00 0.0 -50.70 -50.70 2.' 0.00 0.0 -50.70 0.0 -50.70 0.00 

### ERR 0.00 0.0 -50.70 0.0 -50.70 0.00 

### ERR 000 0.0 -50.70 0.0 -50.70 0.00 

### ERR 0.00 0.0 -50.70 0.0 -50.70 0.00 

### ERR 0.00 0.0 -50.70 00 -50.70 0.00 

### ERR 0.00 0.0 -50.70 0.0 -50.70 0.00 

### ERR 0.00 0.0 -50.70 0.0 -50.70 0.00 

### ERR 0.00 0.0 -50.70 0.0 -50.70 0.00 

### ERR

## o

Client 

### ProjectNo. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit #1 04/12/10



### Parameter: 

### Nitrogen Oxides (as N02)

Run

1 2 3 4 

### 5 6 7 

## a g 

### 10 11 12 Instrument Span (ppmVNOxJ: 502.9

Actual Calibration Gas Value (opmVNOx)'- AnalvzerCalibration Response (ppm VNOx): AnalvzerCalibration Error(% Span):

Zero Sllstem Calibration Gas AgQarent !nit S'iS. Inif. S!!s. Final 

### :S:l!s. FinalS'lS,



### Stack Galib. Cal. Bias Galib. Cal. Bias 

### Cone. Response (% span) 

### Response t% span)



### 211.0 0.3 0.00 0.3 0.00 210.5 0.3 0_00 -0.3 -0.11 218.8 -0.3 -0.11 1.2 0.19

0.0 1.2 0.19 0.0 -0.05 00 0.0 -0,05 0.0 -0.05 0.0 00 -0.05 0.0 -0.05 0.0 0.0 -0.05 0.0 -0,05 0.0 0.0 -0.05 0.0 -0.05 0.0 0.0 -005 0.0 -0.05 00 0.0 -0.05 00 -0.05 0.0 0.0 -0.05 0.0 -0.05 0.0 

### 00 -0.05 0.0 -0.05 

### AirNova, Inc. Page4 EPA Method Be Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Anal'izerCalib. Gg§es UgS!;.g/e 

### zero low mid high ,s'is. Cal. Gas 

### 0.0 0.0 246.8 502.9 246.8 0.3 0.0 245.5 501.7 245.5 0.05 0.00 -0.27 

### -0.25

U(;!scale Sllstem Calibration Gas CatiP. Init· S'i5. !nit S'ls. Final S'i,'l. FinalS'iS. Galib.**~** Drift Galib. Cal. Bias Galib. Cal. Bias Drifl Stack (% span) Response (% span) Response (% span) (% span) 

### Cone.



### 0_00 245.7 0.05 246.5 0.21 0.16 211.5 -0.11 246.5 0.21 246.5 0.21 0.00 210.7 0,30 246.5 0.21 249.0 0.69 0.48 217.9 -0.24 249.0 0_69 0.0 -48.81 -49.50 -1.2 0.00 0.0 -48.81 0.0 -48.81 0.00 

### ERR 0.00 0.0 -48.81 0.0 -48.81 0.00 

### ERR 0.00 0.0 -48_81 0.0 -48.81 0.00 

### ERR 0_00 0.0 -48.81 0.0 -48.81 0_00 

### ERR 0_00 0.0 -48.81 00 -48_81 0.00 

### ERR 0.00 00 -48.81 0.0 -48.B1 0.00 

### ERR 0.00 0.0 -48.81 0.0 -48.81 0.00 

### ERR 0.00 0.0 -48.81 0.0 -48.81 0.00 

### ERR3333-HCI-HF-R1



### Client Project No. Test Location Test Run Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vic

# = Vm= Pstatic

# = Pb

# = Ps

# = Pstd

# = dP

# = dH 

### = Tm= Ts

# = Tstd= On

# = An

# = y= t= 

### Os

# = As= Cp

# = Kp

# = K1 

# = K2= K3

# = Fd 

### = CF

# = CF

# =

102] IC02]
IN2] 

## AirNova, Inc. EPA Methods 1,2,3A,4,and 26A 

### (Flows, 

### 02/C02, H20,and HCI/HF) 

### Spruance Genco, LLC 

## 3333 Unit No.1 One 04/12/10 

## 0840-1149

334.2 

### cc Emission Data

120.514 dcf -050 in. H20 30.32 in. Hg 30.28 in. Hg 

### 29.92 In 

### Hg 

# o7014 in 

### H20 1\ 

### 5

1.243 in. 

### H20 538.2 R 659.0 R 527.7 

### R 0.248 in. 

### 0.000335 sq. ft. 0.97 

### 180 min. 10.300 ft Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rtdelta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area of nozzle orifice Metercalibration factor 

### Duration ofsElmpling time Diameter ofstack 83,323 sq. 

### ft, Cross sectional area ofstack 0,84 Pitottube coefficient 85.49 ft[(lb/lbmol)"'(inHg)]".S}/[s"'R"inH20] Pitottube constant 17.637 R/in.Hg 0.047070 cu.fUml 0.0026688 in.Hg-cf/ml-R 9862 scf/MMBtu 9.461 E-08 Ib/dscf

### I ppmVd 5.192E-08 Ib/dscf

### I ppmVd



### Instrumental Data
4,81 %-dry 15,05 %-dry

80.14 %-dry constant constant constant Fuel Factor Conversion Factorfor HCI Conversion Factorfor HF

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. 

### Spruance Genco, llC 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1'Y 'Vm ' (Pb + 

### dH/13.6) 

### ITm Vmstd

# = 116.500 dsc! 330 dscm Unit No.1 One



### 2) Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std) = K2 " Vic Vw(std) = 15.731 scf
3) Decimal fraction ofmoisture by volume in stack gas, Bws.

Bws 

### =Vwstd/ (Vmstd+Vwstd) Bws= 0.119
4) Molecularweight ofthe stack gas on awet basis, Ms.

Ms = [((44'%C02) 

### +(32"%02) + 

### (2S"%N2))' (1-Bws) 

## I+ 

### (1S'Bws) Ms

# = 29.10 Ib/lbmoJe
5) Average stack gas velocity, Vs.

Vs = Kp' Cp' (dP) " (Ts/Ps"Ms)A5 Vs

# = 43.55 fps 

### 6)Average actual stack gasvolumetricflowrate, Qa.
Qa

# = 60 sec/min"Vs ., As Qa

# = 217732.6 efm 6166.2 cmm 7)Average stack gas dryvolumetric flowrate, Qstd.
Qstd =Qa" (TstdlTs)" (Ps/Pstd)' (1-Bws) Qstd 

### = 155486.4 dscfm 4403.4 dscmm Page 2

### Client Spruance Genco, LLC Project No. 3333 Test location Test Run

Calculations (cont.)
8) Hydrogen Chloride Concentration and Emissions Unit No.1 

### One

M[HCI[

# =M[CI-[(mg) • MW[HCI[(mg/mmol) 

### 1MW[CI-](mg/mmol) 

### Page 3

C[HCI]

# =(M[HCI](mg) " 2.20SE-06(lb/mg) • 21.8S(scf"inHgllbmol·R) • K1 • 10'6) 

### 1(MW[HCI](Ib/lbmol) • Vmstd(d C[HCI](@corr. 02) = 

### C[HCI](ppmV)"[(20.9-corrected 02) 

### 1(20.9-actual %02)] E[HCI]

# =M[HCI](m9)' Qstd(dscfm)' (2.20SE-06)(lb/mg)· 60(min/hr) 

### 1Vmstd(dscD E[HCI]

# = C[HCI](ppmV)' Fd" CF(HCI)' 

### (20.9/(20.9-%02))

M[HCI] 

### = C[HCI]

# = C[HCI]

# = E[HCI]

# = E[HCI]

# = S.99 mg 1.199 ppmV 1.03S ppmV 1.0S8 Ib/hr 1.4SE-03 Ib/MMBtu


### 9) Hydrogen Fluoride Concentration and Emissions
C[HF]

# =M[HF](mg) 

### 1Vmstd(dscm) 

### (@ 7.0 % 

### 02)

C[HF] 

### = (M[HF](mg)' 2.20SE-06(lb/mg)· 21.8S(scf"inHg/lbmol·R)· K1 "10'6) 

### 1(MW[HF](lb/lbmol)'Vmstd(dsc C[HF](@corr. 02)

# = C[HF](mg/dscm)' [(20.9-corrected 02) 

### 1(20 9-actual %02)] E[HF]

# = C[HF](mg/dscm) " Qstd(dscmm) " (2.20SE-06)(lb/mg) • 60(min/hr) E[HF] = 

### C[HF](ppmV)' Fd" CF(HF)' 

### (20.9/(20.9-%02))
M[HF] = 

### C[HF] = 

### C[HF] = 

### C[HF] = 

### E[HF]

# = E[HF]

# = 10) Isokinecity, 

### I. 

## O.soo mg 

### 0.152 

### mg/dscm 0.182 ppmV 0.1S7 ppmV (@ 0.088 Ib/hr 

### 1.21E-04 Ib/MMBtu 7.0

% 1

# =(100·Ts·(K3·Vlc+(Vm·YlTm)(Pb+dH/13.6)))/(60·t·Ps-Vs·An) % 

### I = 

### 103.4 % 

### 02)

### 3333-HCI-HF-R2

Client 

### Project No. Test Location 

### Test Run Test Date 

### Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vic

# = Vm= Pstatic

# = Pb

# = Ps

# = Pstd

# = dP = 

### dH 

### = Tm= Ts

# = Tstd= 

### On 

### = An = 

### y= 

### t

# = Ds

# = As= Cp= Kp= K1 

# = K2= K3= Fd 

### = CF

# = CF

# =

[02J [C02J
[N2J 

### AirNova, Inc. EPA Methods 1,2,3A,4,and 26A (Ftows, 021C02, H20,and HCIIHF) 

### Spruance Genco, LLC 

## 3333 Unit No.1 

# Two 04112110 1215-1524

354.1 

### cc 122.346 dcf

### Emission Data**~O.50** 

### in. 

### H20 30.35 in. Hg 

### 30,31 in. Hg 2992 in. Hg 

### 06887 in. 

### H20 

### ",5

1.253 in. 

### H20 561.5 R 657.8 R 527.7 R 

### 0.248 

### in. 0.000335 

### sq. 

### ft. 0.97 

### 180 min. 10.300 

### ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometnc pressure Stack pressure 

### EPA Standard pressure Average sq.rt delta P Average draft gauge readmg Average metertemperature Average stacktemperature Standard temperature 

### Nozzle diameter Area ofnozzle orifice Metercalibration factor Duration ofsampling time Diameterofstack 83.323 sq ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)*(inHg)]1\.5}/[s*R*inH20] Pitottube constant 17.637 R/in.Hg 0.047070 cu.ftlml 00026688 in.Hg-cf/ml-R 9755 scf/MMBtu 9.461 E-08 Ib/dscf

### I ppmVd 5.192E-08 Ibldscf

### I ppmVd

Instrumental Data



### 5.02 %-dry 14.61 %-dry

80.37 %-dry constant constant constant Fuel Factor Conversion Factorfor HCI Conversion Factorfor 

### HF

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. 

### Spruance Genco, LLC 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1*

### Y*

### Vm * 

### (Pb +dH/13.6) 'Tm Vmstd = 113.488 dscf 3.21 dscm Unit NO.1 Two

2) Volume ofwatervapor collected atstandard conditions, Vw(std).
Vw(std)

# =K2 'Vie Vw(std) = 

### 16667 sef
3) Decimal fraction ofmoisture by volume in stack gas, Bws.

Bws 

### =Vwstd 

### I (Vmstd+Vwstd) Bws= 0.128
4) Molecularweight ofthe stack gas on a wet basis, Ms.

Ms

# =[((44'%C02) + 

### (32'%02) + 

### (28'%N2))' (1-Bws) ) + 

### (18'Bws) Ms= 28.93 Ibllbmole
5) Average stack gas velocity, Vs.

Vs

# =Kp' Cp' (dP) , (TsIPs'Msj'.5 

### Vs

# = 42.83 fps
6) Average actual stack gas volumetric flowrate, Oa.
Qa

# = 60 sec/min * 

### Vs * 

### As Qa

# = 214130.8 cfm 6064.2 cmm 

### 7) Average stackgas dryvolumetricflowrate, Ostd.
Qstd 

### = Qa' (Tstd/Ts)' (PsIPstd)' (1-Bws) Qstd

# = 151754.6 dscfm 4297.7 dscmm 

### Page 2

### Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

Calculations (cont.)


### 8) Hydrogen Chloride Concentration and Emissions Unit No.1 Two

M[HCI]

# =M[CI-](mg) • MW[HCI](mg/mmol) 

### 1MW[CI-](mg/mmol) Page 3

C[HCI] 

### = (M[HCI](mg) • 2.205E-06(lb/mg) • 21.85(scf·inHgllbmol·R) • K1 • 10'6) 1(MW[HCI](Ib/lbmol) • Vmstd(d C[HCI](@corr 02)

### = C[HCI](ppmV)' [(20.9-corrected 02) 

### 1(20.9-actual %02)] E[HCI] = 

### M[HCI](mg) • Ostd(dscfm) • (2.205E-06)(lb/mg) • 60(min/hr) 

### 1Vmstd(dscD E[HCI] 

### = C[HCI](ppmV)' Fd' CF(HCI)' 

### (20.9/(20.9-%02))
M[HCI]

# = 5.98 

### mg C[HCI]

# = 1.228 ppmV C[HCI]

# = 1.075 ppmV (@ 7.0 % 

### 02) E[HCI]

# = 1.058 Ib/hr E[HCI]

# = 1.49E-03 Ib/MMBtu


### 9) Hydrogen Fluoride Concentration and Emissions
C[HF]

# =M[HF](mg) 1Vmstd(dscm) C[HF]

# =(M[HF](mg) • 2.205E-06(lb/mg) • 21.85(scf'inHg/lbmol·R) 'K1 • 10'6) 

### 1(MW[HF](lb/lbmol) • Vmstd(dsc C[HF](@corr. 02)

# = C[HF](mg/dscm)' [(20.9-corrected 02) 

### 1(20.9-actual %02)] E[HF] 

### = C[HF](mg/dscm)' Qstd(dscmm)' (2.205E-06)(lb/mg)' 60(min/hr) E[HF]

# = C[HF](ppmV)' Fd' CF(HF)' (20 

### 9/(20.9-%02))



### < M[HF]

# =
< C[HF] = 

### < C[HF] 

### = 

### < C[HF]

# =
< E[HF]

# = < E[HF]

# =
10) Isokinecity, I. 0.040 

### mg 

# o012 

### mg/dscm 0015 ppmV 0.013 ppmV (@ 0.007 Ib/hr 9.98E-06 Ib/MMBtu 7.0

% 1

# =(100·Ts·(K3'Vlc+(Vm'Y/Tm)(Pb+dH/13.6)))/(60't'Ps'Vs·An) 

### % I = 

### 103.2 % 

### 02)

### 3333-HCI-HF-R3

Client Project No. Test Location Test Run Test Date 

### TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vlc= Vm= Pstatic

# = Pb

# = Ps

# = Pstd

# = dP = 

### dH

# = Tm= 

### T5

# = Tstd= 

### Dn

# = An = 

### y= t= 

### Ds= As= Cp= Kp

# = K1 

# = K2= 

### K3

# = Fd

# = CF= CF=

[02] [C02]
[N2] 

### AirNova, Inc. EPA Methods 

### 1,2,3A,4,and 26A (Flows, 

### 02/C02, H20,and HCI/HF) 

### Spruance Genco, LLC 

## 3333 Unit No.1 

## Three 04/12/10 

## 1555-1904

368.9 

### cc 123.001 dcf

### Emission Data**~O.50** 

### in. H20

30.28 

### in. Hg 30.24 

### in. Hg 

### 29.92 in. Hg 

### 0.6670 In. 

### H20 11.5

1.176 in. 

### H20 

### 563.8 R 6570 R 527.7 R 

### 0.248 in. 

### 0.000335 sq. ft. 0.97 

### 180 

### min. 10.300 ft. 83.323 sq. ft. 084 Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rtdelta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature 

### Nozzle diameter Area of nozzle orifice Meter calibration factor Duration ofsampling time Diameterofstack Cross sectional area ofstack Pltottube coefficient 

### 85.49 ft[(lb/lbmol)'(inHg)]'.5)/[s'R'inH20] P,tot tube constant 17.637 Rlin.Hg 0047070 cU.fUml 0.0026688 in.Hg-cf/ml-R 9868 scf/MMBtu 9.461 E-08 Ib/dscf

### I ppmVd 

### 5.192E-08 Ib/dscf! ppmVd



### Instrumental Data

425 %-dry 14.69 %-dry

81.06 %-dry constant constant constant Fuel Factor Conversion Factorfor Hel Conversion Factorfor HF

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test location Test Run

Calculations
1) Volume 

### ofgas sampled at standard conditions, Vmstd.

Vmstd =K1"" Y**~** Vm * (Pb 

### + dH/13.6)/ Tm Vmstd

# = 113.341 dscf 

### 3.21 dscm 

### Unit No.1 Three



### 2) Volume ofwatervaporcollected at standard conditions, Vw(std). 

### Vw(std) 

### = K2 'Vie Vw(std)

# = 17.364 sef
3) Decimal fraction of moisture by volume in stack gas, Bws.



### Bws

# = Vwstd 

### I (Vmstd+Vwstd) 8ws

# = 0.133
4) Molecularweight ofthe stack gas on a wet basis, Ms.



### Ms

# =[((44'%C02) + 

### (32'%02) + 

### (28'%N2))' (1-Bws) 

## I + 

### (18'Bws) 

### Ms= 28.86 Ib/lbmole
5) Average stack gas velocity, Vs.



### Vs

# =Kp , Cp , (dP) , (Ts/Ps'Ms)'.5 Vs

# = 41.56 fps
6) Average actual stackgas volumetric flowrate, Qa.



### Oa

# = 60 sec/min""Vs '" As Oa = 

### 207786.9 cfm 

### 5884.5 cmm 

### 7) Average stack gas dry volumetric flowrate, Qstd.


### Qstd 

### = Qa' (Tstdrrs)' (Ps/Pstd)' (1-Bws) Ostd

# = 146278.1 dscfm 4142.6 dscmm Page 2

### Client Spruance Genco, LLC Project No. 

### 3333 Test Location Test Run

Calculations (cont.)
8) 

### Hydrogen Chloride Concentration and Emissions Unit No.1 

### Three

M[HCI] = M[CI-](mg) , MW[HCI](mg/mmol) 

### 1MW[CI-](mg/mmol) 

### Page 3

C[HCI] = (M[HCI](mg)'2.205E-06(lb/mg)' 21.85(scf'inHg/lbmol'R)' K1 '10'6) 

### 1(MW[HCI](lbllbmol)'Vmstd(d C[HCI](@corr. 02) = C[HCI](ppmV)' [(20.9-corrected 02) 

### 1(20.9-actual %02)] E[HCI] = M[HCI](mg)' Qstd(dscfm)' (2.205E-06)(lb/mg)"60(min/hr) 

### 1Vmstd(dscf) E[HCI] = C[HCI](ppmV) , Fd ' CF(HCI) • 

### (20.9/(20.9-%02))
M[HCI]= 10.00 

### mg C[HCI] = 2.057 

### ppmV C[HCI] = 1.717 

### ppmV (@ 7.0 

### % 

### 02) E[HCI] = 1.7071b/hr 

### E[HCI]= 2.41E-03Ib/MMBtu
9) 

### Hydrogen Fluoride Concentration and Emissions
C[HF] = M[HF](mg) 

### 1Vmstd(dscm) C[HF] = (M[HF](mg) '2.205E-06(lb/mg) • 21.85(scf·inHg/lbmol·R) • K1 • 10'6) 

### 1(MW[HF](lb/lbmol) • Vmstd(dsc C[HF](@corr. 02) = C[HF](mg/dscm)' [(20.9-corrected 02) 

### 1(20.9-actual %02)] E[HF] = C[HF](mg/dscm)' Qstd(dscmm)' (2.205E-06)(lb/mg)'60(min/hr) E[HF] = C[HF](ppmV)' Fd' CF(HF)' 

### (20.9/(20.9-%02))

< M[HF] = 

### < C[HF] = 

### < C[HF] = 

### < C[HF] = 

### < E[HF] = 

### < E[HF] = 

### 10) Isokinecity, I. 0.040 

### mg 

### 0.012 mg/dscm 0015 ppmV 0.013 ppmV ( @ 0007 Ib/hr 

### 9.B4E-OB Ib/MMBtu 7.0

% I = (100'Ts'(K3'Vlc+(Vm'YlTm)(Pb+dH/13.6)))/(60't"Ps'Vs·An) %1= 

### 106.9 % 

### 02)Client Project No. Test Location Fuel Type Test Run Test Date Time Period

INPUT INPUT INPUT INPUT Vic

# = Vm= Pstatic= Pb

# = Ps = Pstd = dP = dH

# = Tm = Ts = INPUT Tstd= INPUT Y = INPUT t

# = INPUT Dn = An 

### = INPUT Ds = As = INPUT

INPUT Cp

# = Kp = K1 

### = K2 

### = K3

# = Fd =

INPUT [02] INPUT [C02] [N2] INPUT [NOx] INPUT [S02] 

### AirNova, Inc. Page 1 of3 EPA Methods 

### 1, 2, 3A, 

### 4, 6 and 7E (Flows, 02/C02, H20, S02 and NOx)
Spruance Genco, LLC 

### 3333 Unit No. Coal One 04/12110 0840-1149 Emission Data

334.2 cc 120.514 dcf -0.50 in. H2O 30.32 in. Hg 30.28 tn. 

### Hg 2992 in. 

### Hg 0.7014 in. H20" 5 1.24 in. 

### H2O 538.2 R 659.0 

### R 527.7 

### R



### 097

180 min. 

### 0.248 in. 0.000335 sq. ft. 

### 10.300 

### ft. 83323 sq ft. Vol. ofH20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameter of stack Cross sectional area ofstack 0.84 Pitottube coeffir.ient 85.49 ft[(lb/lbmolt(inHg)]".5}f[s*R'"inH20] 17637 Rfin.Hg constant 0.047070 cu.ftlml 0.0026688 in.Hg-cf/ml-R 9862 scf/MMBtu

Instrumental Data 4.81 %-dry 

### 1505 %-dry 80.14 %-dry 

### 211.5 ppmV-dry



### 31.1 ppmV-dry constant Pitot tube constant constant From EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Nitrogen Oxides concentration Sulfur Dioxide concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations 1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1" Y "Vm ;0 

### (Pb + dH/13.6) /Tm Vmstd = 116.500 dscf 3.299 dscm Unit No.1 One



### 2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2 * 

### Vic Vw{std) = 15.731 scf 3) Decimal fraction ofmoisture byvolume in stack gas, Bws.

Bws =Vwstd / (Vmstd+Vwstd) Bws= 0.1190 4) Molecularweightofthestackgas on awet basis, Ms.

Ms = [{(44"%C02) + (32"%02) + (28;O%N2))'" (1-Bws) 1 + (18;OBws) Ms = 29101 Ib/lbmole 5) Average stack gas velocity, Vs.

Vs = Kp" Cp " (dP) " (Ts/Ps*Ms)".5 Vs = 43.552 fps 6) Average actual stack gas volumetric flowrate, Qa.
Qa = 60 sec/min ;0 

### Vs .., As Qa = 217732.6 cfm 6166.2 cmm 7) Average stackgas dry volumetric flowrate, Qstd.
Qstd = Qa**~** 

### (Tstd/Ts) 

### *(Ps/Pstd) * 

### (1-Bws) Qstd = 155486.4 dscfm 4403.4 dscmm Page 2 of3Client Project No. 8pruance Genco, LLC 

### 3333 Test Location Test Run
Calculations (cont.)Unit No. One Page 3 of3

9) Nitrogen Oxides concentrations and emissions
Carr. C[NOx] = ((20.9-02% corr. value)/(20.9-actual avg. 02% value))*Avg. raw NOx value E[NOx] =**(C[NOxl~Mol** Wt[NOx]*60(min/hr)*Qstd(dscfm»/(MolarVol. alr*10"6) E[NOx Ib/MMBtu] = Cd;O Fd * (20.9/(20.9-actual 02%)) C[NOx] = 211 

### 5 ppmVd C[NOx] = 182.7 ppmVd corrected to 7 

### % 02 Mol. Wt. [NOx]= 46.01 Ib/lb-mole Molar vol air= 

### E[NOx[

# = Cony Factor. 

### E[NOx[ = 385 scmb-mole 

### @ 235.80 Ib/hr 

### 68
1.194E-07 convert ppmV to Jb/scf NOx 0.323 Jb/MMBtu 10) Sulfur Dioxide concentrations and emissions def F

Carr. C[S02] = ((20.9-02% corr. value)/(20.9-actual avg. 02% value))*Avg. raw 802 value E(lb/MMBtu) = Cd(lb/scf)

... Fd(scf/MMBtu) * [20.9 I (20.9-% 02)] E[S02 Ib/hr]

# = (C[S02]*Mol Wt[S02]*60(mm/hr)*Qstd(dscfm»/(MolarVol. air*10"6) C[S02] 

### = 31.1 ppmV (dry) Actual Conc. C[S02] 

### = 26.9 ppmVd corrected to 7 % 02 Mol. Wt. [802]= 64.06 Ib/lb-mole Molarvol air= Cony Factor. E[S02[ 

### = E[S02[ = 385 scfllb-mole 

### @ 68 166E-07 convert ppmV to Ib/scf 802 0.066 JbfMMBtu 48.28 fb/hr def FClient Project No. Test Location Fuel Type Test Run Test Date Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT INPUT

INPUT INPUT Vic 

### = Vm= Pstatic = Pb

# = Ps = Pstd = dP 

### = dH

# = Tm= Ts = Tstd= y= t= Dn

# = An = Ds 

### = As= Cp 

### = Kp = K1 

# = K2

# = K3 = Fd 

### =

[02[ [C02J [N2J [NOxJ [S02J 

### AirNova, Inc. EPA Methods 

### 1, 2, 3A, 4, 6 and 7E (Flows, 

### 02/C02, 

### H20, S02and NOx)
Spruance Genco, LLC 3333 Unit No. Coal 

### Two 04/12/10 1215-1524 Emission Data

354.1 cc 122.346 dcf -0.50 in. H20 30.35 In. Hg 30.31 in. Hg 29.92 in. Hg 0.6887 in. H20 '\5 125 in. H20 561.5 R 

### 657.8 R 527.7 R



### 0.97 Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta 

### P Average draft gauge reading Average meter temperature Average stack temperature Standard temperature Meter calibration factor 180 min. Duration of sampling time 0.248 in. Nozzle diameter 0.000335 sq. ft. Nozzle area 10.300 ft. Diameter of stack 83.323 sq. ft Cross sectional area of stack 0.84 Pitot tube coefficient 85.49 ft[(lbflbmol)*(inHg)]".5}/[s·WinH20] 17.637 Rlin.Hg constant Page 1 of3

0.047070 cu.fUml constant Pitot tube constant 0.0026688 in.Hg-cf/ml-R constant 9755 scf/MMBtu From EPA Reference Method 19

Instrumental Data 5.02 %-dry Oxygen concentration 14.61 %-dry Carbon Dioxide concentration 80.37 %-dry Nitrogen concentration 210.7 ppmV-dry Nitrogen Oxides concentration

21.0 ppmV-dry Sulfur Dioxide concentrationClient Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1* Y * Vm * (Pb + dH/13.6) ITm Vmstd

# = 113.488 dscf 3.214 dscm Unit No. Two

2) Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std) = K2 * Vic Vw(std) = 16.667 sef
3) Decimal fraction of moisture byvolume instackgas, Bws.

Bws = Vwstd 

### J(Vmstd+Vwstd) Bws= 0.1281
4) Molecularweightofthestack gas on a wet basis, Ms.

Ms = [«44*%C02)+ (32*%02) + (28*%N2)) * (1-Bws) 

## 1 + (18*Bws) Ms = 28.933 Ibf Ibmole
5) Average stack gasvelocity, Vs.

Vs 

### =Kp * Cp * (dP) • (Ts/Ps*Ms)" 5 Vs = 42.831 fps
6) Average actual stackgasvolumetricflowrate, Qa.
Qa

# = 60 sec/min·Vs • As Qa= 214130.8cfm 6064.2 cmm 7) Average stackgas dryvolumetric flowrate, Qstd.
Qstd = Qa * (TstdlTs) * (Ps/Pstd);O (1-Bws) Qstd = 151754.6 dsefm 4297.7 dscmm Page 2 of3

### Client Project No. Spruance Genco, LLC 3333 Test Location Test Run
Calculations (cont.)Unit No. Two 

### Page 3 of3

9) Nitrogen Oxides concentrations and emissions
Corr. C[NOx] = (20.9-02% corr. value)/(20.9-actual avg. 02% value))"Avg. raw NOx value EINOx] = (C[NOx]*Mol Wt[NOx]*60(min/hr)*Qstd(dscfm»/(MolarVol. air*10"6) E[NOx Ib/MMBtu] 

### =Cd * 

### Fd 

### *(20 9/(20.9-actual 02%)) C[NOx] 

### = 210.7 ppmVd C[NOx] = 184.4 ppmVd corrected to 7 % 02 Mol. Wt. [NOx]= 46.01 Ibllb-mole Molarvol air= E[NOx] = Conv Factor. EINOx] 

### = 385 scfllb-mole @ 229.27 Ib/hr 

### 68
1.194E-07 convert ppmV to Ib/scf NOx 0.323 Ib/MMBtu 10) Sulfur Dioxide concentrations and emissions def F

Corr. C[S02]

# =«20.9-02%corr. value)/(20.9-actual avg. 02% valueWAvg. raw 802 value E(lb/MMBtu) = Cd(lb/scf) * 

### Fd(scf/MMBtu) * 

### [20.9 I 

### (20 9-% 02)] E[802 Ib/hr] = (C[802rMol Wt[802]*60(min/hr)*Qstd(dscfm))/(MolarVol. air*10"6) C[802] = 21.0 ppmV (dry) Actual Conc. C[S02]

# = 18.4 ppmVd corrected to 7 %02 Mol. Wt. [802]= 64.06 Ibllb-mole Molarvol air= Conv Factor. EIS02] 

### = EIS02] = 

### 385 scf/lb-mole @ 68 1.66E·07 convert ppmV to Ib/scf 802 0.045 Ib/MMB1u 31.82 Ib/hr def FClient Project No. Test Location Fuel Type Test Run Test Date Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT Vic = Vm= Pstatic = Pb 

### = Ps = Pstd = dP

# = dH = Tm

# = Ts = Tstd= 

### y= j= On

# = An

# = Os = As

# = Cp = Kp

# = K1 = K2

# = K3 

### = Fd =

INPUT [02] INPUT [C02] [N2] INPUT [NOx] INPUT [802] 

### AirNova, Inc. EPA Methods 

### 1, 2, 3A, 

### 4, 6 and 7E (Flows, 

### 021C02, H20, 802 and NOx)
Spruance Genco, LLC 

### 3333 Unit No. Coal Three 

### 04112/10 1555·1904 Emission Data



### 368.9 cc 123.001 dcf 

### -0.50 in. H20 

### 30.28 m. Hg 30.24 in. Hg 29.92 in. Hg 

### 0.6670 in. H20A.5 H20 1.18 in. 

### 563.8 R 657.0 R 527.7 R



### 0.97

180 min. 0.248 in. 

### 0.000335 sq. ft. 

### 10.300 ft. 83.323 sq. ft. Vol. of H20 colle:cted Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft. gauge readmg Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling tIme Nozzle diameter Nozzle area Diameter ofstack Cross sectional area ofstack 0.84 Pitotlube coefficient 

### 85.49 ft[(lb/lbmol)'(inHg)]'5}/[s'R'inH20] Page 1 of3

17.637 R/in.Hg 

### 0.047070 cu ftlml 

### 00026688 in.Hg·cf/ml-R 9868 scf/MMBtu constant constant Pitottube constant constant From EPA Reference Method 19

Instrumental Data 425 %-dry Oxygen concentration 14.69 %-dry Carbon Dioxide concentration 

### 81.06 %·dry Nitrogen concentration 217.9 ppmV-dry Nitrogen Oxides concentration

21.6 ppmV-dry Sulfur DioxJde concentrationClient Project No. Spruance Genco, 

### LLC 

### 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1* 

### Y·Vm * (Pb 

### + dH/13 6) / Tm Vmstd = 113.341 dscf 3.210 dscm Unit No, Three



### 2) Volume ofwatervapor collected atstandard conditions, Vw(std).
Vw(std) = K2 • Vic Vw(sld) = 17.364 scf
3) Decimal fraction of moisture byvolume in stack gas, Bws.

Bws

# = Vwstd / (Vmstd+Vwstd) Bws= 01328


### 4) Molecularweightofthestackgas on a wet basis, Ms.

Ms

# =[((44*%C02) + (32*%02) + (2B*%N2»**~** (1-Sws) 

## 1 +**(18~Bws)** Ms= 28.857 Ib/lbmole
5) Average stack gasvelocity, Vs.

Vs

# =Kp * Cp * (dP) 

### ***(Ts/Ps~Ms)J\.5** Vs= 41.562 fps
6) Average actualstack gas volumetric flowrate, Qa.
Qa = 60 sec/min ;0 Vs ., As Qa

# = 207786.9 cfm 5884.5 cmm 7) Average stackgas dryvolumetric flowrate, Qstd.
Qstd 

### =Qa· (Tsld/Ts)**~** (Ps/Psld)**~** (1-Bws) Qstd = 146278,1 dscfm 4142.6 dscmm Page 2 of3Client Project No. Spruance Genco, LLC 3333 Test Location Test Run
Calculations (cant.)Unit No.1 Three Page 3of3

9) Nitrogen Oxides concentrations and emissions
Carr C[NOx] = «20.9-02%carr. value)/(20.9·actual avg. 02% value))*Avg. raw NOx value E[NOx] = (C[NOx]*Mol Wt[NOx]*60(min/hr)*Qstd(dscfm»/(MolarVol. air"10Jl6) E[NOx Ib/MMBtu]

# = Cd

.. Fd

.. (20 9/(20.9-actual 02%)) C[NOx] 

### = 217.9 ppmVd C[NOx] = 181.9 ppmVd corrected to 7 % 02 Mol. 

### WI. [NOxj= 46.01 Ibllb-mole Molarvol air= 385 scf/lb-mole 

### @ 68 def

### F E[NOx] = 228.55 Ib/hr Conv Factor. E[NOx] = 1.194E-07 convert ppmV to Ib/scfNOx 0.322 Ib/MMBtu 10) Sulfur Dioxide concentrations and emissions

Carr. C[S02] = «20.9-021;'/0 corf. value)/(20.9-actual avg. 02% value»*Avg. raw S02value E(lb/MMBtu) 

### =Cd(lb/set)· Fd(scf/MMBtu)' [20.9/ (20.9-% 02)] E[S02Ib/hr] = (C[S02]·Mol Wt(S02]"60(min/hr)"Qstd(dscfm»/(MolarVol. air"10116) C(S02] = 21.6 ppmV (dry) Actual Conc. C(S02] = 18.0 ppmVd corrected to 7 % 02 Mol. WI. [S02]= 6406 Ib/lb-mole Molar vol air= Conv Factor. E[S02)

# = E[S02] = 385 scf/lb-mole 

### @ 68 1.66E-07 convert ppmV to Ib/scf S02 0044 Ib/MMBtu 31.54 Ib/hr def F

### 3333-HCN-R1

Client Project No. Test Location Test Run Test Date 

### TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vic = 

### Vm= Pstatic

# = Pb

# = Ps = Pstd

# = dP

# = dH = 

### Tm= Ts

# = Tstd= 

### On 

### = An = 

### y= 

### t

# = Os

# = As= 

### Cp= Kp

# = K1 

### = K2

# = K3 = 

### Fd

# = CF=



### [02[ [C02[
[N2[ 

### AirNova, Inc. EPA Methods 1,2,3A,4,and Modified 26 

### (Ftows, 02/C02, H20,and HCN) 

### Spruance Genco, LLC 

## 3333 Unit No.1 One 

## 04/12/10 

## 0840-0940

152 

### cc 42.521 delEmission Data



### -050 in. 

### H20 30.32 in. 

### Hg 30.28 

### m. Hg 

### 29.92 in 

### Hg 0.7021 in. 

### H20 

### ".5



### 1.660 in. 

### H20 532.1 R 

### 654.4 R 

### 527.7 R 0.244 in. 

### 0.000325 sq. ft. 

### 1.00

60 min. 

### 10.300 

### It. 83.323 sq. ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure 

### Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter 

### Area ofnozzle orifice 

### Meter calibration factor Duration ofsampling time Diameter ofstack 

### Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft{(lb/lbmol)*(inHg)1".5}/[s*R*inH20] Pitot tube constant 17.637 R/in.Hg 0.047070 cu.ft!ml 0.0026688 m.Hg-cf/ml-R 9862 scf/MMBtu 

### 7.014E-08 Ib/dsefl ppmVd

Instrumental Data



### 4.81 

### %-dry 15.05 

### %-dry

80.14 

### %-dry constant constant constant Fuel Factor Conversion Factorfor HCN

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1)

### Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1'Y 'Vm ' (Pb 

### + dH/13.6) 

### ITm Vmstd

# = 42.904 

### dscf 1.22 

### dscm Unit No.1 One

2) 

### Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std) = K2 'Vic Vw(std) = 7.155 scf
3) Decimal fraction ofmoisture by volume in stack gas, Bws.

Bws

# = Vwstd / (Vmstd+Vwstd) Bws 

### = 0,143


### 4) Molecularweightofthe stack gas on a wet basis, Ms.

Ms = [((44'%C02) 

### + (32'%02) 

### + (28'%N2))' (1-Bws) 

## I+ (18'Bws) Ms

# = 28,80 Ib/lbmole


### 5) Averagestack gasvelocity, Vs.

Vs = Kp' Cp' (dP) , (Ts/Ps'Ms)'.5 Vs= 43.68 fps
6) Average actual stack gasvolumetric flowrate, Qa.
Qa

# = 60 sec/min"Vs ,. As Qa

# = 218349.3 cfm 6183.7 cmm 7) Averagestackgas dryvolumetric flowrate, Qstd.
Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) Qstd = 152748.6 dscfm 4325,8 dscmm Page 2

### Client 

### Spruance Genco, LLC Project No. 

### 3333 Test Location Test Run

8) Hydrogen Cyanide Concentration and Emissions Unit No.1 

### One

M[HCN[ = M[CN-](mg) , MW[HCN](mg/mmol) 

### 1MW[CN-](mg/mmol) Page 3



### C[HCN] = (M[HCN](mg) , 2.205E-06(lb/mg) , 21.85(scf'inHg/lbmol'R) , K1 • 10'6) 1

### (MW[HCN](lb/lbmol) 'Vms' C[HCN](@corr 02) = C[HCN](ppmV)' [(20.9-correcled 02) 1

### (20.9-aclual %02)] E[HCN] = M[HCN](mg)' Qsld(dscfm)' (2.205E-06)(lb/mg)'60(min/hr) 

### 1Vmstd(dscf) E[HCN] =C[HCN](ppmV)' Fd' CF(HCN)' (20.9/(20.9-%02))



## < M[HCN]= 

## < C[HCN] = 

## < C[HCN] = 

### < E[HCN] = 

## < E[HCN] = 0.004 mg 0.003 ppmV 0.003 ppmV 0.002 Ib/hr 263E-06 Ib/MMBtu (@ 

### 7.0 %02)

### 3333-HCN-R2



### Client Project No. 

### Test Location Test Run Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vic = 

### Vm= 

### Pstatic 

### = Pb

# = Ps = 

### Pstd

# = dP

# = dH

# = Tm= Ts

# = Tstd= 

### On 

### = An

# = y= t = 

### Ds

# = As= Cpo Kp= K1 

# = K2= K3

# = Fd = 

### CF

# =

[02[ [C02]
[N2] 

## AirNova, Inc. EPA Methods 1,2,3A,4,and Modified 26 

### (Flows, 02/C02, 

### H20,and HeN) 

### Spruanee Genco, LLC 

## 3333 Unit 

## No.1 

# Two 04/12/10 

## 1215-1315

Emission Data



### 148.4 

### cc 43.863 def

-0.50 

### in. H2O 

### 30.35 

### m. Hg 

### 30.31 in Hg 

### 29,92 

### in, Hg 

### 0.6899 in, 

### H20 ".5

1.660 in. H2O 550.3 R 6579 R 527.7 R 0.244 

### in 0.000325 sq. ft 1.00



### 60 

## min. 10.300 

### ft. Vol. of H20 collected Dry 

### gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average meter temperature Average stack temperature Standard temperature Nozzle diameter Area ofnozzle orifice 

### Meter calJbration factor Duration ofsampling time Diameter ofstack 83,323 sq. ft, Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lb/lbmol)"(inHg)]".5}/[s'*R*inH20] Pitot tube constant 17.637 R/in.Hg constant 0.047070 cU.fUml 0.0026688 in.Hg-ef/ml-R 9755 scf/MMBtu 7.014E-08 Ib/dsef

### I ppmVd

Instrumental Data
5,02 %-dry 14.61 %-dry

80.37 %-dry constant constant Fuel Factor Conversion Factorfor HCN

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 

### Test Location Test Run
Calculations
1)

### Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd**=K1~'** 

### Y .., Vm " 

### (Pb 

### +dH/13.6) I

### Tm Vmstd

# = 42.839 dsef 1.21 dscm 

### Unit No, 1 

### Two



### 2) 

### Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std) 

### = K2 'Vic Vw(std)

# = 6.985 sef
3) 

### Decimal fraction ofmoisture by volume in stack gas, Bws.

Bws

# = Vwstd I 

### (Vmstd+Vwstd) Bws= 0.140


### 4) 

### Molecularweightofthe stack gas on awet basis, Ms.

Ms

# =[((44'%C02)

### + (32'%02) 

### + (28'%N2))' (1-Bws) 

## I+(18'Bw;) Ms= 

### 28.78 Ib/lbmole
5) 

### Average stack gas velocity, Vs.

Vs = 

### Kp'Cp' (dP)' (Ts/Ps'Ms)'.5 Vs= 43_02 fps
6)

### Average actual stack gas volumetric flowrate, Qa.

Qa

# = 60 

### see/mrn *

### Vs *

### As Qa

# = 215088.8 efm 6091.3 cmm 

### 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd

# = Oa' (TstdlTs)' (Ps/Pstd)' (1-Bws) Qstd

# = 150292.4 

### dscfm 4256.3 

### dsemm Page 2

### Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

8) Hydrogen Cyanide Concentration and Emissions Unit No.1 

## Two

M[HCN[ 

### =M[CN-[(mg) , MW[HCN[(mg/mmol) 

### 1MW[CN-[(mg/mmol) 

### Page 3

C[HCN[

# =(M[HCN[(mg) , 2.205E-06(lb/mg) , 21.85(scf'inHg/lbmol'R) , K1 ' 10'6) 

### 1(MW[HCN[(lb/lbmol) • Vmsl C[HCN[(@corr 02) = 

### C[HCN[(ppmV)' [(20.9-corrected 02) 

### 1(20.9-actual %02) [ E[HCN[

# =M[HCN[(mg) , Qstd(dscfm) , (2.205E-06)(lb/mg) '60(min/hr) 

### 1Vmstd(dscf) E[HCN[

# = C[HCN[(ppmV)' Fd' CF(HCN)' 

### (20.9/(20.9-%02))



## < M[HCN]

# = 0.004 

### mg 

## < C[HCN]

# = 0.003 ppmV 

## < C[HCN]

# = 0.003 ppmV (@ 7.0 % 

### 02) 

## < E[HCN]

# = 0.002 Ib/hr 

## < E[HCN]

# = 2.64E-06 Ib/MMBtu3333-HCN-R3



### Client Project No. Test Location Test Run Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vic

# = Vm= Pstatic

# = Pb 

### = Ps = 

### Pstd

# = dP

# = dH

# = Tm= Ts

# = Tstd= 

### Dn = 

### An

# = y= t

# = Ds= 

### As= Cp= 

### Kp = 

### K1 

### = K2= 

### K3= Fd = 

### CF 

### =

[02J [C02J
[N2J 

## Ai,Nova, Inc. EPA Methods 1,2,3A,4,and Modified 26 

### (Flows, 

### 021C02, H20,and HeN) 

### Spruance Genco, LLC 

## 3333 Unit No.1 Three 

## 04/12/10 1555-1655

147,7 

### cc 44.933 dcf

### Emission Data

-0.50 in. 

### H20 30.28 in Hg 30.24 in. Hg 29,92 

### in. Hg 

### 0,6678 in. 

### H20 

### ".5

1.660 in. H20 563.1 

### R 656.2 

### R 527.7 

### R 0.244 

### in, 0.000325 

### sq. ft 1.00



### 60 min 10.300 

### ft. Vol. of H20 collected Dry

### gas meter reading Static pressure Barometric pressure Stack pressure 

### EPA Standard pressure Average sq.rt delta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area of nozzle orifice Meter calibration factor Duration ofsampling time Diameter ofstack 83.323 sq. ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)"'(inHg)]".5}/[s*R*inH20] Pitot tube constant 17.637 R/in.Hg 0.047070 cu.fUml 0.0026688 in.Hg-cf/ml-R 9868 

### scf/MMBtu 7.014E-08 Ib/dscf

### I ppmVd



### Instrumental Data

4.25 %-dry 14.69 %-dry

81.06 %-dry constant constant constant Fuel Factor Conversion Factorfor HCN

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1} Volume ofgas sampled atstandard conditions, Vmstd.



### Vmstd =K1'Y 'Vm ' (Pb 

### + dH/13.6) I

### Tm Vmstd = 

### 42.785 dscf 1.21 dscm Unit NO.1 Three

2) Volume ofwatervaporcollected at standard conditions, Vw(std). 

### Vw(std) = K2 'Vic Vw(std) = 

### 6.952 scf
3) Decimal fraction ofmoisture by volume in stack gas, Bws.

Bws

# = Vwstd 

### I (Vmstd+Vwstd) Bws= 0.140
4) Molecularweight ofthestack gas on a wet basis, Ms.



### Ms = [((44'%C02) + 

### (32'%02) + 

### (2S'%N2))' (1-Bws) 

## I+ 

### (1S'Bws) Ms= 

### 28.77 Ib/lbmole
5) Average stack gasvelocity, Vs.



### Vs = Kp'Cp' (dP)' (Ts/Ps'Ms)A5 Vs= 41.65 fps
6) Average actual stack gas volumetric flowrate, Qa.

Qa

# = 60 sec/min'"Vs * 

### As Qa

# = 208214.1 cfm 

### 5896.6 cmm
7) Average stack gas dry volumetric flowrate, Qstd.


### Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) Qstd

# = 145592.3 dscfm 4123.2 dscmm Page 2

### Client 

### Spruance Genco, LLC Project No. 3333 Test Location Test Run

8) Hydrogen Cyanide Concentration and Emissions Unit No.1 Three



### M[HCN[ = 

### M[CN-[(mg) , MW[HCN](mg/mmol) 1

### MW[CN-](mg/mmol) Page 3



### C[HCN]

# = (M[HCN](mg) • 2.20SE-06(lb/mg) '21.8S(scf"inHg/lbmol'R) , K1 • 10'6) 1

### (MW[HCN](Ib/lbmol) 'Vmsl C[HCN](@corr. 02)

# = C[HCN](ppmV)' [(20.9-corrected 02) 1

### (20.9-actual %02)] E[HCN]

# =M[HCN](mg)' Qstd(dscfm)' (2.20SE-06)(lb/mg)·60(min/hr) 

### 1Vmstd(dscf) E[HCN]

# = C[HCN](ppmV)' Fd'CF(HCN)' (20 

### 9/(20.9-%02))

M[HCN]

# = 0.136 mg C[HCN]

# = 0.100 ppmV C[HCN]

# = 0.083 ppmV (@ 7.0 

### % 02) E[HCN]

# = 0.061 Ib/hr E[HCN]

# = 8.68E-OS Ib/MMBtuClient Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit #1 04113110

Parameter: Instrument Span (% 02): 

### Oxygen 22.03

Actual Calibration Gas Value t% 02): AnalyzerCalibration Response t% 02): AnalyzerCalibration Errort% Span):

Zero**S~stem** Calibration Gas Apparent Init. S\,:s Init. Sk':s. Final

### S!'§. FinaJS\,:s.

Stack Ga/ib. Gal. Bias Ca/ib. Cal. Bias Run Gonc. Response (% span) Response t% span)



### 1 4.24 0.04 0.01 0.01 ·0.14 0 0.00 0.01 -0.14 0.00 -0.18 0 0.00 0.00 -0.18 0.00 -0.18 0 0.00 0.00 -0.18 0.00 -0.18 0 0.00 0.00 -0.18 0.00 -0.18 0 0.00 0.00 -0.18 0.00 -0.18 0 0.00 0.00 -0.18 0.00 -0.18 0 0.00 0.00 -0.18 0.00 -0.18 0 0.00 0.00 -0.18 0.00 -0.18 0 0.00 0.00 -0.18 0.00 -0.18 0 0.00 0.00 -0.18 0.00 -0.18 0 0.00 0.00 -0.18 0.00 -0.18 

### AirNova, Inc. Page 1 EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Anal"t.zerCalib. Gases**!lQ§'Qa/~** zero low mid high Sk':s. Cal. Gas 

### 0.00 

### NIA 11.90 22.03 11.90 0.04 

### NIA 11.87 21.79 11.87 

## o18 

### 0.00 -0 14 -1.11

Uj;!scale Sy:stem Calibration Gas Calib. Init. S\,:s. Init. S\,:s. FinalSk':s. FinalS\':S Calib.**~** Drift Calib. Cal. Bias Galib. Cal. Bias Drift Stack t% span) Response t% span) Response t% soan) (% span) Conc.



### ·0.14 11.93 0.27 11.94 0.32 0.05 

### 4.21 -0.05 11.94 0.32 0.00 -53.88 -54.20 

### ·0.01 0.00 0.00 -53.88 0.00 -53.88 0.00 

### ERR 0.00 000 -53.88 0.00 -53.88 0.00 

### ERR 0.00 0.00 -53.88 0.00 -53.88 0.00 

### ERR 0.00 0.00 -53.88 0.00 -53.88 0.00 

### ERR 0.00 0.00 -53.88 0.00 -53.88 0.00 

### ERR 0.00 0.00 -53.88 0.00 -53.88 0.00 

### ERR 0.00 0.00 -53.88 0.00 -53.88 0.00 

### ERR 0.00 0.00 -53.88 0.00 -53.88 0.00 

### ERR 0.00 0.00 -53.88 0.00 -53.88 0.00 

### ERR 0.00 000 -53.88 0.00 -53.88 0.00 

### ERRClient Project No. Test Location Test Date

Parameter: Spruance Genco, LLC 

### 3333 Unit #1 04/14/10

InstrumentSpan (% 02)' 

### Oxygen 22.03

Actual Calibration Gas Value (% 02L AnalyzerCalibration Response (% 02): AnalyzerCalibration Error(% Soanl:

Zero**S~stem** Calibration Gas AQparent Init. S'!.s Init. S\:::s. Final S'!.s. Fingl S\:::s.

Stack Calib Gal. Bias 

### c..ali.!L Cal. Bias Run Gone. ReSQon§.e (% span) Response (% span)



### 2 4.34 0.10 0.01 0.10 0.50 3 4.37 0.10 0.50 0.10 0.50 0 

### 0.00 0.10 0.50 0.00 0.05 0 

### 0.00 0.00 0.05 0.00 0.05 0 

### 0.00 0.00 0.05 000 

### 0.05 0 

### 0.00 0.00 0.05 0.00 0.05 0 

### 0.00 0.00 0.05 0.00 0.05 0 

### 0.00 0.00 0.05 0.00 0.05 0 

### 0.00 0.00 0.05 0.00 0.05 0 

### 0.00 0.00 0.05 0.00 0.05 0 

### 0.00 0.00 0.05 0.00 005 0 

### 0.00 0.00 0.05 0.00 0.05 

### AirNova, Inc. Page 1 EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Ana/'!.zerGalib. Gases Upscale 

# = low mid high Svs. Gal. Gas 

### 0.00 N/A 

### 11.90 22.03 11.90 -0.01 N/A 

### 11.93 21.96 11.93 -0.05 0.00 0.14 -034

Ugscale**S~stem** Calibration Gas Calib. Init. S'!.s. Init. S'!.s. Final

### S'i..S: FinalS'!.s. Calib. Actual Drift Galib. e.g/. Bias Calib. Cal. Big§. Drift 

### 'ilidi (% span) Response (% span) Response (% span) (% span) Cone.



### 0.00 11.90 -0.14 11.90 -0.14 0.00 4.28 0.00 11.90 -0.14 11.90 -0.14 0.00 4.31 

### -0.45 11.90 -0.14 0.00 -54.15 -54.02 -0.10 

### 0.00 0.00 -54.15 0.00 -54.15 0.00 

### ERR 0.00 0.00 -54.15 0.00 -54.15 0.00 

### ERR 0.00 0.00 -54.15 0.00 -54.15 0.00 

### ERR 0.00 0.00 -54.15 0.00 -54.15 0.00 

### ERR 0.00 0.00 -54 15 0.00 -54.15 0.00 

### ERR 0.00 000 

### -54.15 0.00 -54.15 0.00 

### ERR 0.00 0.00 -54.15 0.00 -54.15 0.00 

### ERR 0.00 0.00 -54.15 0.00 -54.15 0.00 

### ERR 0.00 0.00 -54.15 0.00 -54.15 0.00 

### ERR

## o

Client Project No. Test Location Test Date 

### Spruance Genco, LLG 

### 3333 Unit #1 

### 04113110

Parameter: 

### Carbon Dioxide Instrument Span f% 

### C02): 22.28

Actual Calibration Gas Value 

### r% C021-' AnalYZerCalibration Response f% C02): 

### AnalvzerCalibration Errorr% Span):

Zero Sy:stem Calibration Gas AQJ1arent {nit. SKS. Init. Si::s. Final Sk's. Final Sk's.

Stack Calib. Cal. 

### Bias Calib. Cal. Bias 

### Run Cone. Response f% span) Response f% span)

1 

### 16.21 0.12 0.10 0.00 0.04 

### 0 0.00 0.00 0.04 0.00 0.04 

### 0 0.00 0.00 0.04 0.00 

### 0.04 0 0.00 0.00 0.04 

### 000 0.04 

### 0 0.00 0.00 

### 0.04 0.00 

### 004 0 0.00 0.00 0.04 0.00 0.04 

### 0 0.00 0.00 0.04 0.00 0.04 

### 0 0.00 0.00 0.04 0.00 

### 0.04 0 0.00 0.00 

### 0.04 0.00 0.04 

### 0 0.00 0.00 0.04 0.00 0.04 

### 0 0.00 0.00 0.04 0.00 

### 0.04 0 0.00 0.00 0.04 0.00 

### 0.04 

### AirNova, Inc. Page 2 EPA Method 6C Calculations (Cal. Error, Bias Drift and Bias Adjustment)

Anal't.zerCalib.**Gase~ IJJ2~Qfi.I~**  

# '"'" 

# """ mid high SKS. Cal. Gas 0,00 NfA 12.39 

### 2228 12.39 -0.01 NfA 12.33 

### 22.34 12.33 

### -0.04 0.00 -0.27 0.27

Urui;cale Sy:stem Calibration Gas Calib. Init. Sk's. Init. Sk'S, Final Sk'S FinalSk's. Calib. Actual Drift Calib. Cal. Bias Cafib. C!3.f.**Bifi.~** Drift Stack f% span) Response (% span) Response (% span) r% span) 

# =

-0.54 12.33 0.00 12.31 -0.09 -0.09 16.32 

### 0.00 12.31 -0.09 0.00 -55.34 -55.25 0.00 

### 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 

### -55.34 0.00 

### -55.34 0.00 

### ERR 0.00 0.00 

### -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -5534 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR

## o

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit #1 

### 04114110

Parameter: 

### Carbon Dioxide Instrument Span f% C02): 22.28

Actual Calibration Gas Value (% C02): AnalyzerCalibration Response (% 

### C021: AnalvzerCalibration Errort% Span).-

Zero System Calibration Gas 

### Armarent Init. SjI'S. Init. SJ,':S. Fina!SjI's. Final S,,-s.

Stack Calib. Cal. Bias Calib. Cal. Bias 

### Run**~** 

### Response (% span) Response (% 

### span)

2 

### 14.77 -0.12 0.10 -0.12 0.00 3 14.75 -0.12 0.00 -0.12 0.00 0 0.00 -0.12 0,00 0.00 0.54 0 0.00 0.00 0.54 0.00 0.54 0 0.00 0.00 0.54 0.00 0.54 0 0.00 0.00 0.54 0.00 0.54 0 0.00 0.00 0.54 0.00 0.54 0 0.00 0.00 0.54 0.00 0.54 0 0.00 0.00 0.54 0.00 0.54 0 0.00 0.00 0.54 0.00 0.54 0 0.00 0.00 0.54 0.00 0.54 0 0.00 0.00 0.54 0.00 0.54 

### AirNova, Inc. Page2 EPA Method 6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

Anal'izerGalib. Gases**UQ~Qg/e** zero 

### iflliL mid high S,,-s. Cal. Gas 0.00 NfA 

### 12.39 22.28 

### 12.39**~O.12** NfA 

### 12.33 22.34 12.33 -0.54 

### 0.00 -0.27 0.27

Ugscale Sllstem Calibration Gas Galib. 

### Init S"-S. Init. 81:::5. Final SI:§.**FinaIS~.** 

### !&1iJL Actual Drift Gal/b. GgL Bi;;Js Calib, Caf. Bias Drift Slack (% 

### span) Response (% span) Response (% span) (% span) 

### QQaQ.

0.00 12.33 0.00 12.33 0.00 0.00 14.82 0.00 12.33 0.00 12.33 0.00 0.00 14.80 0.54 12.33 000 0.00 -55.34 -55.34 0.12 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR 0.00 0.00 -55.34 0.00 -55.34 0.00 

### ERR

### 3333-PM2.5-R1

Client 

### Project No. Test Location Test Run Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT
INPUT INPUT INPUT
INPUT

INPUT INPUT 

### Vic = 

### Vm= Pstatic

# = Pb 

### = Ps 

### = Pstd 

### = dP

# = dH

# = Tm= Ts

# = Tstd= Dn = 

### An= 

### y= 

### tr= Os

# = As

# = Cp= 

### Kp

# = K1 

# = K2= 

### K3= C1= C2= C3= C4= C5= 

### C6

# = B1 

# = Fd 

### =

[02[ 

### [C02[ [N2[ 

### AirNova, Inc. EPA Methods 1,2,3,4, OTM 27 and 202 (Flows, 021C02, H20, PM2.S and CPM) Spruance Genco, LLC 

### 3333 UnitNO.1 One 

### 04113110 1601-2211
Emission Data

379.7 

### cc VoL of H20 collected 

### 113.235 dcf 

### Dry gas meter reading -0.50 in. 

### H20 Static pressure 

### 30.38 In, 

### Hg Barometric pressure 30.34 in. 

### Hg Stack pressure 

### 29.92 in 

### Hg EPA Standard pressure 0.6871 in. 

### H20 ".5 Average sq.rt delta P

0.310 

### in 

### H20 Average draftgauge reading 

### 528.7 R Average metertemperature 654.3 R Average stack temperature 527.7 R Standard temperature 

# a 189 in. Nozzlediameter 0.000195 sq. ft Area of nozzle orifice 

### 1.00 Meter calibration factor, gamma 357.22 min Duration of sampling time 10,300 ft. 

### Diameter ofstack

83,32 sq, 

### ft. Cross sectional area ofstack

0.84 Pitottube coefficient 8549 ft[(lbllbmol)'{inHg)]'.5}/[s·R"inH20] Pito1 tube constant 17.637 Rfin.Hg constant 0.047070 cu.fUml constant 0.0026688 in.Hg-cf/ml-R

-150.3162 upoise

13.4622 upolse/R"0.5 3861530 upoisefR"2 0.591123 upolse

91,9723 upoise 1.51761E-05 upoiseJR"2 0.15625 9862 dscf/MMBtu
Instrumental Data
4.21 

### %-dry 16,32 

### %-dry 79.47 

### %-dry constant Viscosity constant Viscosity constant Viscosity constant Viscosity constant Viscosity constant Viscosity constant Constant Fuel Factor

Oxygen concentration Carbon Dioxide concentration NItrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations 

### Unit No.1 One

1) Dry Gas Volume atstandardconditions, Vms 

### (EPA OTM27 

### Equation 27).


### Vms =K1*Y

.. Vm * 

### (Pb + 

### dH/13.6) I

### Tm Vms = 

### 114.635 dscf 3.252 dsem 2) Drygas sampling rate atstandardconditions, QsST(EPA OTM27 

### Equation 28)
QsST

# = Vms 

### I tr 

### asST= 0.321 dscfm 

### 0.009 dsem 

### I min. 3) Volume ofwatervaporcondensedatstandardconditions, Vws 

### (EPA OTM27 

### Equation 29).


### Vws 

### = 

### K2 "Vic Vws= 17.872 scf 4) Decimalfraction ofmoisture byvolume in stackgas, Bws (EPA aTM27

### Equation 30).


### Bws

# = Vwstd 

### I (Vmstd+Vwstd) Bws= 

### 0.135 5) Molecular weightofthe stackgas 

### on a 

### wetbasis, 

### Mw (EPA OTM27 

### Equations 

### 1 &2).


### Mw = [((44'%C02) 

### + (32"%02) 

### +(28"%N2))' (1-Bws) 

## I+ (18"Bws) Mw= 

### 29 

### 06 Ib/lbmole 

### 6) Gas 

### sampling rate atactual Cyclone conditions, Os 

### (EPA OTM27 

### Equation 31).



### as = (Pstd/Tstdl'asST' (1/(1-Bws))'(Ts/Ps) Os

### = 0.454 aefm 7) Average stackgas velocity, Vs (EPA OTM27 

### Equation 11).


### Vs = Kp' Cp" (ave of (dP)'O.5)· (Ts/Ps"Mw)'O.5 Vs = 

### 4251 fps 8) Average actualstackgas volumetric f/owrate, 

## Oa.
Oa

# = 60 sec/min"Vs

.. As 

### Oa

# = 212499.8 efm 6016.0 cmm 9) Average stackgas 

### drystandard volumetric f/owrate, Ostd


### astd = aa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) Ostd 

### = 150404.0 dsefm 4259.4 dscmm Page 2

### Client Project No. Spruance Genco, LLC 3333 

### Test Location Test Run

Calculations (cont.) Unit No.1 

### One Page 3

10) Analyticaldata
Cvclone andFilterFractions (EPA Method aTM27): Ml) Instack quartz microfibrefilter, <2 Sum
0.0054 9 PM <2.S filter netwt M2-4) Cyclone acetonewashes
0.0000 9 actual mass of>2.S, Containers2&3 0.0026 9 actual mass of </=2.5um, Container 4 0.0000 9 acetone blank netwt 

# omL volume 150 mLvolume 150 mL volume


# o0000 9 blank corrected mass of >2.5um, Containers 2&3 = M2&M3 00026 9 blank corrected mass of </=2.Sum, Container 4

# =M4
Condensible Parliculate Matter(CPMJ Fractions (EPA Method202): M5) Back HalfAqueous Wash
0.0107 9 actual sample mass 0.0003 9 aqueous blank mass 300 ml blankvol. 300 ml Sample volume
0.0104 9 condensIble aqueous PM M6) Back Half MeCI2 Extraction Portion
0.0000 9 extraction net

## wt 0.0000 g MeCI2 blank netwt 300 ml blank vol. 300 ml MeCI2 extraction volume


# o0000 9 condensible organic PM M[CPM]

# =blank corrected mass of Total CPM, M5 & M6 (in grams) M[CPM] = 0.0104 9 CPM 11) Parliculate Concentrations, C (EPA OTM27andEPA 202).

Equation 43 Equation 45



### EPA 202 C[totalsus] = M 1(g)+M2(g)+M3(g)+M4(g)'15.43(grains/g)Nmstd(dscf)= C[PM2.5sus] = M1 (g) + M4(g) " 15.43(grains/g) 

### 1Vmstd(dscf) = C[CPM] = M[CPM](g) "15 43(gralns/g) 

### 1Vmstd(dscf) where 15.43

# = 7000/453592*1000 C[PMtotal] = C[PMtotalsus] + C[CPM] C[PM2.5total] = C[PM2.5sus] + C[CPM] 0.0011 gr/dscf PMsus 0.0011 gr/dscf PM2 5sus 0.0014 gr/dscfCPM
0.0025 gr/dscfTo1al PM 0.0025 gr/dscfTotal PM2.5

### Client Spruance Genco, LLC Project No. 3333



### 12) Particulate Emission Rates, 

### E. Test Location Test Run

Calculations (cont.) Unit No.1 One

E[lblhr] = C[](grldscD • (1 Ibl7000 gr) • Qstd(dscfm) • 60(minlhr) E[lbIMMBtu] = C[](grldscD • (1 Ibl7000 gr) • Fd(dscfIMMBtu) • (20.9120 9-%02) 

### E[totalsusJ

# = 1.39 

### Ib/hr total sus PM E[totalsus] = 

### 0.0019 

### Ib/MMBtu total sus PM E[PM2.5sus] = 1.39 

### Ib/hr PM2.5sus

# = 43.5 % ofTotal 

### PM2.5 E[PM2.5sus] = 0.0019 

### Ib/MMBtu PM2.5sus = 

### E[CPM]= 1.80 

### Ibfhr CPM 56.5 % 

### of Total PM2.5 E[CPM] = 00025 IblMMBtu CPM E[PMtotal] = 319 

### Ibfhr total PM E[PMtotal] = 0.0044 

### Ib/MMBtu total PM E[PM2 5total] = 3.19 Iblhrtotal PM2.5 E[PM2.5total] = 0.0044 IblMMBtu total PM2 5 

### 13) Percent fsokinectic Sampling, %1 (EPA OTM

### 27Equation 40).
% 

### I = 

### [100"Ts*Vms*Pstd) 

### I(60*Vs*tr*An*Ps*(1-Bws)*Tstd) %1= 9141 

### 14) Stack Gas Viscosity, u(EPA OTM

### 27Equation 3).

u = 

### C1 + 

### C2"'(TsIIO.5) + 

### C3*(Tsll-2) + 

### C4*(%02) - (C5*Bws) + 

### C6*Bws*(TsIl2) u = 

### 194.0 micropoise Page 4

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations (cont.) 15) Test Condition Reynolds number, Nre (EPA OTM

### 27 Equation 8).


### Nre =8.64"10'5"(Ps"MwiTs),(Oslu) Nre 

### = 2726 

### Unit No.1 

### One

16) ActualParticle Cut**~iameter** 

### for Cyclone I, 050 (EPA OTM

### 27 Equation 32).


### 050= 81 "( [Ts 1 (Mw" Ps))'.2091) "( (u lOs)'.7091) 050= 10.77 um 17) Actual Cunningham Correction Factorbasedon Op

# = 2.5um, 

### C (EPA OTM

### 27 Equation 4).


### C = 1+ 0.0057193" (ul(Ps"Op))" (TsIMw)'O.5 C = 1.0694 18) Initial D50 for Cyclone IVbased

### on testcondition Reynolds numberfrom OTM

### 27 Equation 8.


### If Nre < 

### 3162, use Equation 33 which results in 050for IV

# = IfNre >= 

### 3162, use Equation 34 which results in 050 for iV 

### = Initial 050 

### 243 2.29 Equation 33 Equation 34 Equation 35 

### 050=0.0024302"(uIOs),1.1791"(1IC)'OS(Tsl(Ps"Mw)),0.6790 050 =0019723"(uIOs)'O.8058"(1IC)'0.5·(Tsl(Ps"Mw)),0.3058 Cr = 1 +0.0057193"(ul(Ps"050)),(TslMw),0.5 19) Re·establishedD50 for Cyclone 

### IV, 050-1. 

### Page 5

Re·established Cunningham, Cr 

### 1.0715 1.0757

IfNre < 

### 3162, use Equation 36 which results in 050 for IV

# = If Nre >= 

### 3162, use Equation 37 which results in 050 for iV

# = Recalculated Cut Oiam, 050-1 

### 2.42 2.29 Equation 36 Equation 37 

### 050-1 =0.0024302·(uIOs),1.1791"(1ICr)'O 5"(Tsl(Ps"Mw))'0.6790 050-1 =O.019723"(uIOs)'O.8058"(1ICr)'0.5"(TsI(Ps"Mw))'0.3058 19) Establishing "Z" value, 

### Z.
IfEquation 36 was used, then IfEquation 37 was used, then 

### Z=050-11050= Z= 050-1 1050 =
If 0.99 <

### Z < 

### 1.01, then 050-1 is best cutdiameterestimate. If0.99 > 

### Z > 

### 1.01, then repeat calcs for Crusing 050-1 

### 1.00 1.00

### 3333-PM2.5-R2

Client Project No. Test Location Test Run Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT
INPUT INPUT INPUT
INPUT

INPUT INPUT 

### Vic

# = Vm= 

### Pstatic

# = Pb

# = Ps

# = Pstd

# = dP

# = dH = 

### Tm= 

### T5 = 

### Tstd= 

### Dn

# = An= y= 

### tr

# = Ds= As= 

### Cp= Kp= K1 

# = K2= 

### K3

# = C1= C2

# = C3= C4= C5= 

### C6= 

### 81 = 

### Fd

# =

[02] [C02] [N2] AirNova, Inc. EPA Methods 1,2,3,4, 

### aTM 27 and 202 (Flows, 

### 02/C02, H20, PM2.5 

### and CPM) Spruance Genco, LLC 

### 3333 UnitNo.1 

## Two 04114110 0739-1408
Emission Data


### 390 

### cc Vol. of H20collected 121.466 def 

### Dry gas meter reading 

### -0.50 

### in. H20 Static pressure 30.57 in. 

### Hg Barometric pressure 30.53 In. Hg Stack pressure 29.92 in. 

### Hg EPA Standard pressure 0.7113 In, 

### H20 fI 

### 5 Average sq.rt delta P



### 0.310 in. 

### H20 

### Average draftgauge reading 5249 R Average metertemperature 

### 656.7 R Average stack temperature 527,7 R Standard temperature 0.189 

### in. Nozzle diameter 0000195 

### sq. 

### ft. Area ofnozzle orifice 1.00 Metercalibration factor, gamma 36566 min. Duration ofsampling time 10.300 

### ft. Diameter ofstack

83.32 sq. 

### ft. Cross sectional area ofstack

0.84 Pitottube coefficient 

### 85.49 ft[(lb/lbmol)'(inHg)]A.5)/[s'WinH20] P,tot tube constant 17.637 R/in Hg constant 0.047070 cu.ftlml constant 0.0026688 in.Hg-cf/ml-R constant

-150.3162 upoise Viscosity constant

13.4622 upoise/R"0.5 Viscosity constant 3861530 upoise/R"2 Viscosity constant 0.591123 upoise Viscosity constant

91.9723 upoise Viscosity constant 1.51761E-05 upoise/R"2 Viscosity constant 0.15625 Constant 9755 dscf/MMBtu Fuel Factor
Instrumental Data
428 %-dry 14.82 %-dry 80.90 %-dry Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations Unit 

### No.1 Two

1) DryGas Volume atstandardconditions, Vms (EPA OTM

### 27 Equation 27J
### Vms =K1'Y'Vm ' (Pb + 

### dH/13.6) ITm Vms = 

### 124.870 dscf 

### 3536 dscm 2) Drygas sampling rate atstandardconditions, QsST(EPA OTM

### 27 Equation 28).


### QsST = Vms 

### Itr QsST= 

### 0.341 dscfm 

### 0.010 dscm 

### I min. 3) Volume 

### ofwater vaporcondensedatstandardconditions, Vws (EPA OTM

### 27 Equation 29).


### Vws = 

### K2 "Vic Vws= 

### 18357 scf 4) Decimalfracllon 

### ofmOIsture by volume in stackgas, Bws (EPA OTM

### 27 Equation 30).


### Bws = Vwstd I 

### (Vmstd+Vwstd) Bws= 

### 0.128 5) Molecular weight

### ofthe 

### stackgas on 

### a wetbasIs, 

### Mw (EPA OTM

### 27 Equations 

### 1 &2).


### Mw = [((44'%C02) 

### + (32'%02) + 

### (2S'%N2))' (1-Bws) 

## I+ 

### (1S'Bws) 

### Mw

# = 28.93 Ib/lbmole 6) Gas samplmg rate 

### atactualCyclone conditions, 

### Os (EPA OTM

### 27 Equation 31).


### Qs = (PstdlTstd),QsST ' (1/(1-Bws))'(Ts/Ps) 

# as = 

### 0.478 acfm 7) Average stackgas velocIty, Vs (EPA OTM

### 27 Equation 11).


### Vs = Kp , Cp • (ave of(dP)'O.5) , (Ts/Ps'Mw)'O 5 Vs = 

### 4404 fps 8) Average actualstack

### gas volumetric fJowrate, Qa.


### Qa = 

### 60 sec/min"Vs " As Qa = 

### 220170.7 cfm 

### 6235.2 cmm 9) Average stackgas drystandard volumetric flowrate, Qstd. 

### Qstd = Qa ' (TstdlTs) , (Ps/Pstd) , (1-Bws) Qstd 

### = 157406.7 dscfm 

### 4457.8 dscmm Page 2

### Client Project No. Spruance Genco, LLC 3333 

### Test Location Test Run

Calculations (cont.) Unit No.1 

## Two Page 3

10) Analyticaldata Cyclone andFilterFractions (EPA Method aTM27): M1) Instack quartz microfibrefilter, <2 Sum
0.0083 9 PM <2.5 filter net

### wt M2-4) Cyclone acetone washes
0.0000 9 actual mass of>2.S, Containers2&3 

# o0022 9 actual mass of 

### <1=2.5um, Container4 0_0000 g acetone blank net

### wt 

# a mLvolume 100 mL volume 150 mLvolume
0.0000 g blank corrected mass of >2.5um, Containers 2&3 = 

### M2&M3 0.0022 9 blank corrected mass of 

### <I=2.5um, Container 4

# =M4


### Condensible Parliculate Matter(CPM) Fractions (EPA Method202): M5) Back HalfAqueous Wash
0.0102 9 actual sample mass 00003 9 aqueous blank mass 300 ml blank vol. 300 ml Sample volume
0.0099 9 condensible aqueous PM M6) Back Half MeCI2 ExtractIon Portion
0.0000 9 extraction netwt 0.0000 9 MeCI2 blank net

### wt 300 ml blank vol. 300 ml MeCI2 extraction volume
0.0000 9 condensible organic PM M[CPM]

# =blank corrected mass of Total CPM, M5 & M6 (in grams) M[CPM] = 0.0099 9 CPM 

### 11) Particulate Concentrations, C 

### (EPA OTM27andEPA 202).

Equation 43 Equation 45



### EPA 202 C[totalsus] = M1 (g)+M2(g)+M3(g)+M4(g)'15.43(grains/g)Nmstd(dscf)= C[PM2.5sus] = M1(g) + M4(g) '15 43(grains/g) 

### 1Vmstd(dscf) = C[CPM] = M[CPM](g) , 15.43(grains/g) 

### 1Vmstd(dscf) where 15.43 = 

### 7000/453592'1000 C[PMtotal] = C[PMtotalsus] + C[CPM] C[PM2.5total] = C[PM2.5sus] + C[CPM] 0.0013 gr/dscf PMsus 0.0013 gr/dscf PM2.5sus 0.0012 gr/dscfCPM
0.0025 gr/dscfTotal PM 0.0025 gr/dscfTolal PM2.5

### Client Project No. 

### Spruance Genco, LLC 3333



### 12) Particulate Emission Rates, 

### E. Test Location Test Run

Calculations (cont.) 

### Unit No.1 

## Two

E[lb/hr] = 

### C[](gr/dscn • (1 Ib/7000 gr) • Qsld(dscfm) • 60(min/hr) E[lb/MMBlu]

# = C[](gr/dsc0' (1 Ib/7000 gr)' Fd(dscf/MMBlu)' 

### (20.9/20.9-%02) E[lotalsus] 

### = 1.75 

### Ib/hrtotal sus PM E[totalsusJ = 

### 0.0023 

### Ib/MMBtu total sus PM E[PM2.5sus] 

### = 1 75 

### Iblhr PM2.5sus = 

### 51.5 %of Total PM2.5 E[PM2.5sus] 

### = 0.0023 

### Ib/MMBtu PM2 5sus = 

### E[CPM] 

### = 1 65 Ib/hr CPM 

### 48.5 %of Total PM2.5 E[CPM] 

### = 0.0021 Ib/MMBlu CPM E[PMlolal] 

### = 3.40 

### Ib/hrtotal PM E[PMlolal] 

### = 0.0044 

### Ib/MMBtu total PM E[PM2.5Iolal] 

### = 3.40 

### Ib/hrtotal PM2.5 E[PM2.5Iolal] 

### = 0.0044 Ib/MMBlu lolaI PM2.5 

### 13) Percentfsokinectic Sampling, %f(EPA OTM

### 27 Equation 40).


### % I= 

### [1

### OO"'Ts"'Vms*Pstd) I

### (6D*Vs*tr*An*Ps*(1-Bws)*Tstd) % I= 

### 92.78 14) Stack Gas Viscosity, u(EPA OTM

### 27 Equation 3).

u = 

### C1 + 

### C2*(Ts"O.5) + 

### C3*(Ts"-2) + 

### C4*(%02) - (C5*Bws) + 

### CS*Bws*(Ts"2) 

### u= 

### 195.2 micropoise Page 4

### Client Project 

### No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations (cont.) 15) Test Condition Reynolds number, Nre (EPA OTM

### 27Equation B).
Nre

# = 8.64*10"S*(Ps""MwlTs)*(Qs/u) 

### Nre 

### = 2844 Unit No 1 

### Two

16) ActualParticle CutDiameterfor Cyclone I, 050 (EPA OTM

### 27 Equation 32).


### DSO = 81 • ([Ts I 

### (Mw' Ps))'.2091)· ((u I 

### Qs)'.7091) D50

# = 10.44 um 

### 17) ActualCunningham Correction Factorbasedon Dp = 

### 2 5um, 

### C (EPA OTM

### 27 Equation 4).


### C = 1+ 0 00S7193'(u/(Ps'Dp))' (Ts/Mw)'O.S C= 1.0697 18) Initial 050 for Cyclone IVbasedon testcondition Reynolds numberfrom orM

### 27 Equation 8.


### If Nre 

### < 3162, use Equation 33 which results in DSO for IV

# = IfNre 

### >= 3162, use Equation 34 which results in DSO for iV

### = Initial D50 

### 2.30 2.21 Equation 33 Equation 34 Equation 35 

### DSO =0.0024302·(u/Qs)'1.1791·(1/C),0.S"(Ts/(Ps"Mw)),0 6790 DSO = 0.019723·(u/Qs)'0.8058·(1/C)'0.S·(Ts/(Ps·Mw)),0.30S8 Cr= 1 + 0.00S7193·(u/(Ps·DSO))·(Ts/Mw)'0.S 19) Re·established050 for Cyclone IV, 050-1. Page 5

Re-establlshed Cunningham, Cr 

### 1.07S6 1.0787

If Nre 

### < 3162, use Equation 36 which results in DSO for IV

# = If Nre 

### >= 3162, use Equation 37 which results in DSO for iV

### = Recalculated Cut Diam, DSO-1 

### 230 2.20 Equation 36 Equation 37 

### DSO-1 = 0 0024302·(u/Qs)'11791·(1/Cr)'0.S·(TsI(Ps·Mw)),0.6790 DSO-1 = 0.019723·(u/Qs),0.80SS·(lICr),0.S·(Ts/(Ps·Mw))'0.30S8 19) Establishing "Z" value, 

### Z.
If Equation 36 was used, then If Equation 37 was used, then 

### Z= DSO-1/DSO= Z = DSO-1/DSO =
If 0.99 < 

### Z 

### < 1.01, then DSO-1 is best cut diameterestimate. If0.99 

### > Z 

### > 1.01, then repeat cales for Cr using DSO-1 

### 1.00 1.00

### 3333-PM2.5-R3



### Client Project No. Test Location Test Run Test Date 

### TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT
INPUT INPUT INPUT
INPUT

INPUT INPUT 

### Vic

# = Vm= Pstatic

# = Pb= Ps

# = Pstd

# = dP 

### = dH 

### = Tm= Ts

# = Tstd= 

### Dn

# = An

# = y= tr

# = Os 

### = As= Cp= Kp= K1 

# = K2= 

### K3

# = C1 

# = C2 

### = C3= C4= C5= 

### C6

# = B1 

# = Fd =



### [02[ [C02] [N2] AirNova, Inc. EPA Methods 1,2,3,4, OTM 27 and 202 

### (Flows, 

### 02/C02, H20, PM2.5 and CPM) Spruance Genco, LLC 

### 3333 UnitNo 1 Three 

### 04/14/10 1451-2120
Emission Data
431 

## cc Vol. of H20 collected 139.204 dcf 

### Dry gas meter reading 

### -0.50 in 

### H20 Static pressure 

### 30.51 

### in_ Hg Barometric pressure 30.47 in. 

### Hg Stack pressure 29.92 in. 

### Hg EPA Standard pressure 0.6667 in. 

### H20 

### ".5 Average sq,rt delta P

0.340 

### in. H20 Average draft gauge reading 

### 538.7 R Average metertemperature 656.1 R Average stack temperature 527.7 R Standard temperature 0.180 in, Nozzle diameter 0.000177 sq. ft. Area of nozzle orifice 

### 0.97 Meter calibration factor, gamma 388.84 min. DUration ofsampling time 10.300 

### ft. Diameter ofstack

83.32 sq. ft. 

### Cross sectional area ofstack

o 84 Pitot tube coefficient 85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R*jnH20] Pltot tube constant 17 637 R/in.Hg constant 0.047070 cu.ftlml constant 0.0026688 in.Hg-cf/ml-R constant

-150.3162 upoise Viscosity constant

134622 upoise/R"0.5 Viscosity constant 3861530 upoise/R"2 Viscosity constant 0.591123 upoise Viscosity constant

91.9723 upoise Viscosity constant 1.51761E-05 upoise/R"2 Viscosity constant 0.15625 Constant 9868 dscf/MMBtu
Instrumental Data


### 4.31 %-dry 14.80 %-dry 8089 %-dry Fuel Factor

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run


### Calculations Unit 

### No.1 Three

1) DryGas Volume atstandardconditions, Vms (EPA OTM27Equation 27).


### Vms =K1" Y"Vm " (Pb 

### +dH/13.6) ITm Vms

# = 134.989 dscf 

### 3.823 dsem 2) Drygas sampling rate atstandardconditions, QsST(EPA OTM27 Equation 28).
QsST = 

### Vms 

### Itr 

### asST= 

### 0.347 dscfm 

### 0.010 dscm 

### I min. 3) Volume ofwater vaporcondensedatstandardconditions, Vws (EPA OTM27 Equation 29).
Vws

# =K2 ·Vlc Vws

# = 20.287 sef 4) Decimalfraction ofmoisture byvolume in stackgas, Bws (EPA OrM27 Equation 30).
Bws

# = Vwstd I 

### (Vmstd+Vwstd) Bws

# = 0.131 5) Molecularweightofthe stackgas on 

### a wetbasis, Mw (EPA OTM

### 27 Equations 

### 1 &2).


### Mw = [((44"%C02) 

### +(32"%02) 

### + (2S"%N2))" (1-Bws) 

## I+ (1S'Bws) 

### Mw

# = 28,90 Ib/lbmole 6) Gas sampling rate atactual Cyclone conditions, Os (EPA aTM27 Equation 31)



### as= (Pstd/Tstd)"asST' (11(1-Bws))'(Ts/Ps) Qs

# = 0.487 aefm 7) Average stackgas velocity, Vs (EPA arM27Equation 11).


### Vs = Kp • Cp " (ave of(dP)'O.5) • (Ts/Ps"Mw)'O.5 Vs = 41.33 Ips 8) Average actualstackgas volumetric f/owrate, 

### Qa.
Qa

# = 60 sec/min * Vs • As Qa

# = 206595.8 efm 

### 5850.8 cmm 9) Average stackgas drystandard volumetric f/owrate, Qstd.


### astd = aa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) Qstd

# = 147122.3 dsefm 

### 4166,5 dscmm 

### Page 2

### Client Project No. Spruance Genco, LLC 3333 

### Test Location Test Run

Calculations (cont.) Unit No.1 Three 

### Page 3

10) Analyticaldata Cyclone andFifterFractions (EPA Method OTM

### 27J: M1) Instack quartz microfibre filter, <2.5um
0.0085 9 PM <2.5 filter netwt M2-4) Cyclone acetone washes
0.0000 9 actual mass of >2.5, Containers 2&3 0.0014 9 actual mass of <1=2.5um, 

### Container4 0.0000 9 acetone blank netwt 

# a mL volume 100 mL volume 150 mLvolume

0.0000 9 blank corrected mass of>2.5um, Containers 2&3 = M2&M3 0.0014 9 blankcorrected mass of<1=2.Sum, Container4 = M4


### Condensible Particulate Matter(CPMJ 

### Fractions (EPA Method202): MS) Back HalfAqueous Wash
0.0105 9 actual sample mass 0.0003 9 aqueous blank mass 300 ml blank vol. 300 ml Samplevolume
0.0102 9 condensible aqueous PM M6) Back HalfMeCI2 Extraction Portion

0.0000 9 extraction netwt 0.0000 9 MeCI2 blank netwt 300 ml blank vol. 300 ml MeCI2 extraction volume
0.0000 9 condensible organic PM M[CPM] = blank corrected mass of Total CPM, MS & M6 (in grams) M[CPM[ = 0.0102 9 CPM 

### 11) Particulate Concentrations, 

### C (EPA OTM27andEPA 202).

Equation 43 Equation 45

EPA 202 C[totalsus[ = M 1(g)+M2(g)+M3(g)+M4(g)'15.43(grains/g)Nmstd(dsc0= C[PM2 5sus] = M1 (g) + M4(g) " 15.43(grains/g) 

### 1Vmstd(dscf) = C[CPM] = M[CPM](g)" 15.43(groins/g) 

### 1Vmstd(dsc0 where 15.43

# =7000/453592"1000 C[PMtotal] = C[PMtotalsus] + C[CPM] C[PM2.5total] = C[PM2.5sus] + C[CPM] 0.0011 grJdscf PMsus 0.0011 gr/dscf PM2.5sus 0.0012 grJdscfCPM
0.0023 grJdscfTotal PM 0.0023 gr/dscfTotal PM2.5

### Client Project No. Spruance Genco, LLC 

### 3333

12) Parliculate Emission Rates, 

### E Test Location Test Run

Calculations (cont.) Unit No.1 Three



### E[lblhr]

# = C[](grldscD' (1 Ibl7000 gr)'Qstd(dscfm)'60(minlhr) E[lbIMMBtu]

# = C[](grldscD' (1 Ibl7000 gr)' Fd(dscfIMMBtu)' (20.9120.9-%02) E[totalsusJ

# = 1.43 Ibfhrtotal SllS PM E[totalsus]

# = 0.0020 Ib/MMBtu total sus PM 

### E[PM2.5sus]

# = 1.43 Ib/hr PM2.Ssus

# = 493 

### % ofTotal PM2.S 

### E[PM2.5sus]

# = 0.0020 Ib/MMBtu PM2.Ssus = 

### E[CPM]

# = 1.47 IblhrCPM SO 7 % ofTotal PM2 S 

### E[CPM]

# = 0.0021 IblMMBtu CPM E[PMtotal]

# = 2.90 Ib/hr total PM 

### E[PMtotal]

# = 0.0041 Ib/MMBtu total PM 

### E[PM2.5total]

# = 2.90 Ib/hrtotal PM2.S 

### E[PM2.5total]

# = 0.0041 Ib/MMBtu total PM2.S 13) Percent Isokinectic Sampling, %1 (EPA OTM

### 27 Equation 40).


### % I

# =[100*Ts*Vms·Pstd) 

### I (60*Vs*tr*An*Ps*(1-Bws)*Tstd) %1= 111.26 14) Stack

### Gas Viscosity, u (EPA OTM

### 27 Equation 3).



### u = 

### C1 

### + C2"(Ts"0.S) 

### + C3*(Ts"-2) + 

### C4*(%02)

- (CS"Bws) 

### + C6"Bws"(TsA2) u

# = 194.9 mlcropoise 

### Page 4

### Client Project No. Spruance Genco, 

### LLC 3333 Test Location Test Run

Calculations (cont.) 15) Test Condition Reynolds number. Nre (EPA 

### orM

### 27 Equation 8).


### Nre

# =B.64""10/1-5'''(Ps·MwlTs)*(QsJu) 

### Nre

# = 2901 Unit No.1 Three

16) ActualParticle CutDiameterforCyclone 

### I. 050 (EPA 

### OrM

### 27 Equation 32).


### 050 = 81 '( [Ts 1

### (Mw' Ps)['.2091)' ((u 1

### Os)' 7091) 050 = 10.28 um 17) Actual Cunningham Correction Factorbasedon Dp

# = 2.Sum, 

### C (EPA 

### OrM

### 27 Equation 4).


### C = 1+ 00057193' (u/(Ps'Op))' (Ts/Mw)'O 5 C= 1.0697 18) Initial

### 050 for Cyclone IVbasedon testcondition Reynolds numberfrom 

### OrM

### 27 Equation 8.


### IfNre < 

### 3162, use Equation 33 which results in 050for IV

### = If Nre 

### >= 3162, use Equation 34 which results in 050 for iV

### = Initial 050 

### 2.25 2.18 Equation 33 Equation 34 Equation 35 

### 050 = 00024302'(u/Os),1 1791'(1/C)'0.5'(Ts/(Ps'Mw))'0.6790 050 = 0.019723'(u/Os)'0.8058'(l/C)'0.5'(Ts/(Ps'Mw)),0.3058 Cr = 1 + 0.0057193'(u/(Ps'050))'(Ts/Mw)'0 5 19) Re-establlshed

### 050 for Cyclone IV, D50-1. 

### Page 5

Re-established Cunningham. Cr 

### 1.0775 1.0801

If Nre < 

### 3162, use Equation 36 which results in 050for IV

### = IfNre 

### >= 3162, use Equation 37 which results in 050 for 

### IV 

### = Recalculated Cut Olam, 050-1 

### 2.24 2.17 Equation 36 Equation 37 

### 050-1 =0.0024302'(u/Os)'1 1791'(1/Cr)'0.5'(Ts/(Ps'Mw))'0.6790 050-1 = 0.019723'(u/Os)'0.8058'(l/Cr)'0.5'(Ts/(Ps'Mw))'0.3058 19) Establishing 

# "z" value, 

### Z.
If 

### Equation 36 was used, then Z

# =050-1 f

### 050

# = If Equation 37 was used, then Z

# =050-11 050

# =
If 0.99 < 

### Z < 

### 1.01, then 050-1 is best cut diameter estimate If0.99 > 

### Z > 

### 1.01, then repeat calcs for Cr using 050-1 

### 1.00 1.003333-TSP·Metals-R1

Client Project No. Test Location Test Run Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vic = Vm= Pstatic = Pb = Ps= Pstd = dP = dH 

### = Tm = Ts = Tstd= Dn = An = y= t= Ds= As= Cp= Kp = K1 = K2 = K3= Fd =

[02] [C02]
[N2] 

### AirNova, Inc. EPA Methods 1,2,3A,4,5and 29 (Flows, 02/C02, H20,TSP and Metals) 

### Spruance Genco. LLC 

### 3333 Unit No.1 One 04/13/10 

### 1601-2216

Emission Data

630.3 cc 208.204 dcf -0.50 in, H20 30.38 in, Hg 30,34 in. Hg 29.92 in. Hg 0.6873 in. H20 11,5

0,883 in. H20 532.5 R 655,5 R 527,7 R 0,230 in. 0.000289 sq. ft. 0.97 360 min. 10.30 ft. VoL ofH20collected Dry gas meter reading Staticpressure Barometric pressure Stack pressure EPA Standard pressure Average sq, rt delta P Average draftgauge reading Average meter temperature Average stack temperature Standard temperature Nozzle diameter Area ofnozzle orifice Meter calibration factor Duration ofsampling time Diameter of stack 83.3204 sq. ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbmolt{inHg)JII.5}/[s·R*inH20] Pitot tube constant 17.637 R/in.Hg 0.047070 cU.Wml 0.0026688 in.Hg-cf/ml-R 9862 scf/MMBtu

Instrumental Data

4.21 %-dry

16.32 %-dry

79.47 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. 

### Spruance Genco, 

### LLC 3333 Test Location Test Run

Calculations
1)Volume of gas sampled atstandard conditions, Vmstd.

Vmstd =K1* Y *Vm * (Pb + dH/13.6) /Tm Vmstd = 203.668 dscf 5.768 dscm Unit No.1 Ooe

2) Volume ofwatervaporcollected at standard conditions, Vw(std).
Vw(std) = K2 * Vic VW(Sld) = 29.668 scf
3) Decimalfraction ofmoisture byvolume in stack gas, Bws.

Bws = Vwstd I (Vmstd+Vwstd) Bws = 0.1271
4) Molecularweight ofthe stack gas on

### a wet basis, Ms.

Ms= 29.155 Ib/lbmole
5) Average stackgasvelocity, Vs.

Vs = Kp * Cp * (dP) • (TslPs*Ms)".5 Vs = 42.481 fps
6) Average actual stack gasvolumetric flowrate,

# aa.

Qa = 60 sec/min * Vs * As Qa = 212372.54 cfm 6014.39 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa * (TstdfTs)· (ps/Pstd) * (1-Bws) Qstd = 151351.62 dscfm 4286.28 dscmm Page2Client Spruance Genco, LLC ProjectNo. 3333 Test Location Test Run Unit No.1 One
Calculations (cont.) 8) Particulate MatterAnalytical Data INPUT 

### A 0.0290 

### 9 INPUT B 100 ml INPUT C 0.0512 

### 9 INPUT D 100 ml INPUT E 0.0000 

### 9 9) Particulate sample mass calculations

H I 

### J Front Half: Acetone blank adj. residuev Adj. Acetone wash partwt. Front halfsamplewt. 10) Front Half Particulate Matter Emission Data Filter sample net

### wt Frontacetone wash vol. Frontacetone residue

### wt. Acetone blank vol. Acetone blank residuewt.

0.0000 g 0.OS12 9 0.0802 9 E"(B/D) C-H A>I

C[PMJ = (Front HalfWt){g) * (1Nmstd) * 15.43(grainsfg) E[PMJ = C[PMJ *Vdscfm * A * (60 minfhr);O (1 Ib f7000 grains) Page 3

E[PMJ IbfMMBtu = E[PMJ Ibfhr*{Fuel HV) scffBtu*{fuel use) 1 hourfkscf*kscff1000scf'"10"6BtufMMBtu C[PMJ = 6.08E-03 grainsfdscf C[PM] = 8.68E-07 Ibfdscf E[PM] = 7.882 Ibfhr E[PM] = 1_07E-02IbfMMBtu 11)Trace metal concentrations and emission rates

Element Antimony Arsenic Beryllium Cadmium Chromium

Cobalt Lead Manganese Nickel Selenium C[MJ = M[M] tug) fVmstd (dscm) C[MJ(lb/dscf) = C[MJ{ug/dscm) * 1e-06g/ug;O2.205e-03Ib/g;O 0.02832 dscm/dscf E[MJ(lb/hr) = C[MJ (ug/dscm) * (2.205E-09) (Ib/ug) * Qstd (dscmm) * 60 (minfhr) E[MJ{lb/MMBtu) = C[M]{lbfdscf);O Fd ;0 (20.9/20.9-%02) C[M]{@ corr. 02) = C[MJ (ug/dscm) * ( (20.9-corrected %02)I (20.9-actual %02) ] Corrected 02 percentage is: 

### 70 % Sample Conc. Conc.@corr. 02 Conc. Emission Rate Mass tug) (ugfdscm) (ugfdscmj {Ib/dscf} {lbfhr}

2.771 4.80E-01 4.00E-01 3.00E-11 2.72E-04 1.802 3.12E-01 2.60E-01 1.95E-11 1.77E-04 0.777 1.35E-01 1.12E-01 8.41E-12 7.64E-05 0.308 5.34E-02 4_45E-02 3.33E-12 3.03E-05 6.56 1.14E+OO 9.47E-01 7.10E-11 6.45E-04 2.64 4.5SE-01 3.81E-01 2.86E-11 2.60E-04 5.434 9.42E-01 7.S5E-01 5.88E-11 S.34E-04 5.364 9.30E-01 7.75E-01 5.S1E-11 5.27E-04 5.762 9.99E-01 8.32E-01 6.24E-11 5.66E-04 0.915 1.59E-01 1.32E-01 9.91E-12 9.00E-05 12) Isoklneclty, I.
% I=**[100*Ts*(K3~Vlc+«(Vm~Y)fTm)*(Pb+(dH/13** 6»)))J I (60*t*Ps*Vs*An) 

### % I

### = 107.95
" < " symbol indicates values given are the quantitative detection limit. Emission Rate (lbfMMBtu) 3_70SE-07 2.409E-07 1.039E-07 4.11SE-OS S.771E-07 3.S30E-07 7.265E-07 7.172E-07 7.704E-07 1.223E-073333-TSP-Metals-R2

Client Project No. Test Location Test Run TestDate TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vlc= Vm= Pstatic = Pb= Ps = Pstd = dP= dH = Tm= Ts = Tstd= Dn = An= y= 1= Ds = As = Cp = Kp= K1 

### = K2= K3 

### = Fd 

### =

[02) [C02) [N2) AirNova, Inc. EPA Methods 1,2,3A,4,5and 29 (Flows, 02lC02, H20, TSP and Metals) 

### Spruance Genco, LLC 

### 3333 Unit No.1 

## Two 04/14/10 0739-1354

Emission Data

627.4 

### cc 188.668 dcf -0.50 in. H20 30.57 in. 30.53 in. 29.92 in. 0.6820 in.

0.880 in. 527.7 R 658.2 R 527.7 R 0.230 in. H9 H9 H9 H20 ".5 H2O

0.000289 sq. ft. 1.00 360 min, 10.30 

### ft, Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rtdelta P Average draftgauge reading Average meter temperature Average stack temperature Standard temperature Nozzle diameter Area ofnozzle orifice Metercalibration factor Duration ofsampling time Diameterofstack 83.3204 sq, 

### ft, Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49**ft[(lbllbmol)·(inHg)1",5}/[s~R·inH201** Pitottube constant 17.637 Riin,Hg 0.047070 cu.fUml 0.0026688 in.Hg·cf/ml·R 9755 scf/MMBtu

Instrumental Data

4.28 %-dry
14,82 %-dry
80,90 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 TestLocation Test Run

Calculations
1)Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1* Y'Vm * (Pb + dH/13.6) ITm Vmstd = 193.175 dscf 5.471 dscm Unit No. Two

2) Volume ofwatervapor collected atstandard conditions, Vw(std). Vw(std) = K2 •Vic Vw(std) = 29.532 scf 3) Decimalfraction ofmoisture byvolume In stack gas, Bws.

Bws =Vwstd I (Vmstd+Vwstd) Bws= 0.1326 4) Molecularweightofthe stack gas on awet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28*%N2» * (1-Bws) 

### J+ (18*Bws) Ms= 28.879 Ib/lbmole 5)Average stack gas velocity, Vs.

Vs = Kp * Cp' (dP) * (Ts/Ps*Ms)".5 Vs= 42.312 fps 6)Average actual stack gas volumetricflowrate, Qa.
Qa =60 sec/min * Vs ;0As Qa= 211525.76cfm 5990.41 cmm 7) Average stack gas dryvolumetricflowrate, Qstd.
Qstd = Oa * (TstdfTs);O (PsiPstd) • (1-Bws) Qstd = 150114.11 dscfm 4251.23 dscmm Page 2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run Unit No. 

### Two
Calculations (cont.) 8) Particulate MatterAnalytical Data INPUT A 0.0494 9 INPUT 

### 8 100 ml INPUT 

### C 0.0203 9 INPUT 

### 0 100 ml INPUT E 0.0000 g 9) Particulate sample mass calculations

H



### J Fron! Half: Acetone blank adj. residuev Adj. Acetone wash part.wt. Front halfsample wt. 10) Front Half Particulate Matter Emission Data Filter sample netwt Front acetone wash vol. Front acetone residue wt. Acetone blankvol. Acetone blank residue wt.

0.0000 

### 9 0.0203 

### 9 0.0697 

### 9 E'(8ID) C-H A+ I

C[PM] = (Front HalfWt)(g)'" (1Nmstd) w 15.43(grainslg) E[PM];:: C[PM] *Vdscfm'"A**~** (60 min/hr)**~** (11b 17000 grains) Page 3

E[PM]lb/MMBtu =**E[PMllbfhr~(Fuel** HV} scf/Btu"(fuel use) 1 hourlKscf""kscf/1000scf*10"6Btu/MMBlu C[PM] 

### = 5.57E-03 grains/dscf C[PMJ = 7.95E-07 Ib/dscf E[PM] = 7.1631b/hr E{PM] = 9.76E-03Ib/MMBtu
11)Trace metal concentrations and emission rates

Element Antimony Arsenic Beryllium Cadmium Chromium

Cobalt Lead Manganese Nickel Selenium C[M] = M[M] (ug) IVmstd (dscm) C[M](lb/dscf) = C[M](ug/dscm)**~** 1e-06gfug**~** 2.205e-03Ib/g**~** 0.02832 dscmfdscf E[M](lb/hr) = C[M] (ug/dscm)**~** (2.205E-09) (Ibfug)**~** Qstd (dscmm) '" 60 (min/hr) E(M](lb/MMBtu) = C[M](lbfdscf) • Fd**~** (20.9/20.9-%02) C[M](@ carr. 02) = C[M] (ug/dscm)**~** [(20.9-corrected %02) I (20.9-actual %02)

## 1 Corrected 02 percentage is: 

### 7.0 

### % Sample Conc. Qonc.@cQII QZ Conc. Emission Rate Mass (ugj {ugfdscmj {ugfdscmj {Ib/dscf} {lb/hrj

6.521 1.19E+00 9.97E·01 7.44E-11 6.70E-04 2.406 4.40E-01 3.68E·01 2.75E-11 2.47E-04 1.22 2.23E·01 1.87E-01 139E-11 125E-04 0.366 6.69E-02 5.60E-02 4.1BE-12 3.76E-OS 7.034 1.29E+00 1.08E+00 B.03E·11 7.23E-04 3.31 6.0SE-01 5.06E-01 3.78E-11 3.40E-04 S.549 1.01E+00 B.48E-01 6.33E-11 5.70E-04 5.23 956E·01 8.00E·01 5.97E·11 5.38E-04 6.685 1.22E+00 1.02E+OO 7.63E-11 6.B7E-04 2.37 4.33E-01 3.62E-01 2.71E·11 2.44E-04 12) Isokinecity, I.
% I=**[100~Ts*(K3~Vlc+«(Vm·Y)fTm"(Pb+(dH/13.6»»]1** (60*t·Ps·Vs*An) %1= 103.23

" <" symbol indicates values given are the quantitative detection limit. Emission Rate (lb/MMBtuj 9.131E-07 3.369E-07 1.706E-07 S.12SE-OB 9.849E-07 4.635E-07 7.770E-07 7.323E-07 9.361 E-07 3.319E-073333-TSP-Metals-R3

Client Project No. Test Location Test Run Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vlc= Vm= Pstatic = Pb = Ps= Pstd = dP = dH = Tm= Ts = Tstd= Dn = An = y= t= Ds = As= 

### Cp 

### = Kp= K1 

### = K2 

### = K3 

### = Fd 

### =

[02[ [C02)
[N2) 

### AirNova, Inc. EPA Methods 1,2,3A,4,5 and 29 (Flows, 02/C02, H20,TSP and Metals) 

### Spruance Genco, LLC 

### 3333 Unit No.1 Three 04/14/10 

### 1451·2056

633.9 cc 190.479 dcfEmission Data

-0.50 in. H20 30.51 in. Hg 30.47 in. Hg 29.92 in. Hg 0.6775 in. H20 ".5

0.882 in. H20 538.7 R 655.4 R 527.7 R 0.230 in. 0.000289 sq. 

### fl. 1.00 360 min. 10.30 

### fl. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rtdelta P Average draft gauge reading Average metertemperature Average stacktemperature Standard temperature Nozzle diameter Area of nozzle orifice Meter calibration factor Duration ofsampling time Diameter of stack 83.3204 sq. 

### fl. Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 f1[(lb/lbmolt(inHg»)".5}/[s·R*inH20] Pitot tube constant 17.637 R/in.Hg 0.047070 cu.ftIml 0.0026688 in.Hg-cf/ml-R 9868 scf/MMBtu

Instrumental Data

4.31 

### %-dry

14.80 %-dry

80.89 %-dry constant constant constant Fuel 

### Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. 

### Spruance Genco, LLC 3333 Test Location Test Run
Calculations
1)Volume ofgas sampled at standard conditions, Vmstd.
Vmstd**=K1~** Y *Vm * (Pb + dH/13.6) ITm Vmstd = 190.688 dscf 5.400 dscm Unit No. Three

2) Volume ofwater vaporcollected atstandard conditions, Vw(std), Vw(std) =

### K2 *Vic Vw(std) = 29.838 scf
3) Decimal fraction of moisture byvolume instack gas, Bws.

Bws =Vwsld I (Vmsld+Vwsld) Bws= 0.1353
4) Molecularweight ofthe stack gas on awet basis, Ms.

Ms =

## I«44*%C02) + (32*%02) + (28*%N2» * (1-Bws) 

## 1 + (18*Bws) Ms= 28.844 Ib/lbmole
5) Average stack gas velocity, Vs.
Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)".5 Vs = 42.012 fps 6) Average actual stack gas volumetric flowrate, Qa.


# aa = 60 sec/min *Vs *As Oa = 210029.36 cfm 5948.03 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd =Oa * (TstdlTs) * (Ps/Pstd) * (1-Bws) Qsld= 148937.55 dscfm 4217.91 dscmm Page 2Client Spruance Genco, LLC Project No. 3333 TestLocation Test Run Unit No.1 Three
Calculations (cont.) 8) Particulate MatterAnalytical Data
INPUT A 0.0526 

### 9 INPUT B 100 ml INPUT C 0.0326 

### 9 INPUT D 100 ml INPUT E 0.0000 

### 9 9) Particulate sample mass calculations

H



### J Front Half: Acetone blank adj. residuev Adj. Acetone wash part.wt. Front halfsample wt. 10) Front HairParticulate Matter Emission Data Filter sample netwt Front acetone wash vol. Front acetone residue wt. Acetone blankvol. Acetone blank residue wt.

0.0000 9 0.0326 9 0.0852 9 

### E'(BID) C-H A+ I

C{PM] = (Front HalfWt)(g)**~** (1Nmstd)" 15.43(grains/g) E[PM] 

### =C{PMj" Vdscfm"A**~** (60 min/hr) "(1 Ib 17000 grains) Page 3

E[PM]lb/MMBtu = E[PM]lb/hr*(Fuel HV) set/Btu"(fuel use) 1 hour/kscf*kscf/1000scr10"6Btu/MMBtu C{PM] 

### = 6.89E-03 grainsldscf C{PM] = 9.85E-07 Ib/dscf E[PM] = 8.801 Ib/hr E[PM] = 1.22E-02Ib/MMBtu
11)Trace metal concentrations and emission rates

Element Antimony Arsenic Beryllium Cadmium Chromium

Cobalt Lead Manganese Nickel Selenium C[M] = M[M] (ug) IVmstd (dscm) C[M](Jb/dscf) = C[M](ug/dscm) " 1e-06g/ug"2.205e-03Ib/g;O 0.02832 dscm/dscf E[M](lb/hr) = C[M] (ug/dscm) • (2.205E-09) (Ib/ug)" Qstd (dscmm) "60 (min/hr) E[M](lb/MMBtu) = C{M](lb/dscf) " Fd * (20.9120.9-%02) C[M](@corr. 02) 

### =C{M] (ug/dscm)'" [(20.9-corrected %02) I (20.9-actual %02) ] Corrected 02 percentage is: 7.0 % Sample Conc. Conc.@corr. 02 Conc. Emission Rate Mass (ug) (ug/dscm) (ug/dscm) (Ib/dscfl (lb/hr)

4.235 7.84E-01 6.57E-01 4_90E-11 4.38E-04 2.96 5.48E-01 4.59E-01 3.42E-11 306E-04 1.34 2.48E-01 2.08E-01 1.55E-11 138E-04 0.739 1.37E-01 1.15E-01 8.55E-12 7.64E-05 8.522 1.58E+OO 1.32E+00 9.85E-11 8.81E-04 3.59 6.65E-01 5.57E-01 4.15E-11 3.71E-04 6.088 1.13E+00 9.45E-01 7.04E-11 6.29E-04 6.503 1.20E+OO 1.01E+00 7.52E-11 6.72E-04 8.001 1.48E+00 1.24E+00 9.25E-11 8.27E-04 3.07 5.68E-01 4.76E-01 3.55E-11 3.17E-04 12) Isoklneclty, I.
% 1= [100*Ts"(K3"Vlc+«{Vm"Y)fTm)"(Pb+(dH/13.6))))] I (60*t*Ps"Vs*An) %1= 102.71

" <" symbol indicates values given are the quantitative detection limit. Emission Rate (lb/MMBtuj 6.088E-07 4.255E-07 1.926E-07 1.062E-07 1.225E-06 5.161E-07 B.752E-07 9.348E-07 1.150E-06 4.413E-073333-Hg-unspiked-R1

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT INPUT Vm= Pstatic = 

### Pb= Ps 

### = Pstd = Tm= INPUT Ts = INPUT Tstd= INPUT y= INPUT t = INPUT Ds=



### INPUT

INPUT

INPUT As= Kp 

### = K1 

### = K2= K3= 

### Fd·

[02[
[C02[
[N2] 

### AirNova, Inc. EPA Method 1, 

### 2, 3A, and 308

- UnspikedTube (Flows, 

### 021C02, and Mercury) 

### Spruance Genco, LLC 

## 3333 Unit No.1 One 04/13/10 

### 1601-2216

Emission Data

8.879 dcf -0.50 in. H2O 30.38 in. Hg 30.34 in. Hg 29.92 in Hg 524.5 R 655.5 R 527.7 R 1.000

360 min 10.30 ft. Dry gas meter reading Static presSure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stacktemperature Standard temperature Meter calibration faclor Duration of sampling time Diameter of Stack 83.32043375 sq. ft. Cross sectional area of stack 85.49 ft[(lb/lbmol)*(inHg)l".

### 5}/1s*R*1nH20] 17.637 R/in.Hg 0.047070 cU.fVml 0.0026688 in.Hg·cf/ml·R 9862 scf/MMBtu

Instrumental Data

4.21 %-dry

1632 %-dry

79.47 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations
1) 

### Volume ofgas sampled atstandard conditions.Vmstd.

Vmstd**=K1~** Y 

### *Vm " PblTm Vmstd = 9.071 dscf 0.2569 dscm
3) 

### Decimalfraction ofmoisture by volume in stack gas, Bws.

INPUT Bws = Bws = Based on the M29 sampling train 0.1271 4) Molecularweightofthe stackgas on awet basis, Ms. Unit No.1 One



### Ms = [«44"%C02) 

### +(32*%02) + 

### (28*%N2)) " (1-Bws) ] + 

### (18*Bws) Ms= 29.155 Ib/lbmole 5) Average stack gas velocity, Vs.

INPUT Vs= Vs = 

### Based on the M29 sampling train 42647 fps
6) 

### Average actual stackgas volumetric flowrate, Qa.
Oa =60 secJmin " Vs * 

### As Oa = 213201.99 cfm 6037.88 cmm 7) 

### Average stackgas dry 

### volumetric flowrate, Qstd.
Ostd 

### =Qa 

### * (TstdlTs)**~** 

### (Ps/Pstd) 

### * (1·Bws) Qstd 

### = 151939.41 dscfm 4302.92 dscmm
8) 

### Mercuryconcentrations and emission rates C[M] = M[M] (ug) 1

### Vmstd (dscm) C[M](Ib/dscf) =C[M](ug/dscm) • 

### 1e-06g/ug· 2.205e-03Ib/g • 0 02832 dscm/dscf E[M](lb/hr) 

### =C[MJ (ug/dscm) " (2 205E·09) (Ib/ug) "Qstd (dscmm)**~** 

### 60 (min/hr) E[M](Ib/MMBtu) =C[MJ(lb/dscf) • Fd " (20.9/20.9-%02)



### Element Mercury C[M](@ corr. 02) =C[M] (ug/dscm) " ( (20.9-corrected %02) 1

### (20.9-actual %02) ] Corrected 02 percentage is' 7 % Sample Mass (ug)

0.0011 Conc. (ug/dscm)



### 0.004 Conc.@corr. 02 

### (ug/dscm)



### 0.004 Conc. (lb/dscfl 

### 2.67E-13 Emission Rate (Ib/hr) 2,44E-06 Page 2

Emission Rate

(lb/MMBtu) 3.30E-093333-Hg-unspiked-R2

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT 

### INPUT Vm= Pstatic = Pb= Ps 

### = Pstd = Tm = INPUT Ts = INPUT Tstd= INPUT 

### Y = INPUT INPUT



### INPUT

INPUT

INPUT t= Ds= As = Kp 

### = K1 

### = K2= K3 = Fd =

[02[
[C02] 

### [N2] 

### AirNova, Inc. EPA Method 1, 2, 3A, and 30B

- UnspikedTube (Flows, 02/C02, and Mercury) 

### Spruance Genco, LLC 

### 3333 Unil No.1 Two 

### 04/14/10 

## 0739-1354

Emission Data

7.791 dcf -0.50 in. H2O 3057 In. Hg 30.53 in. Hg 29.92 in. Hg 520.5 R 658.2 R 527.7 R 1.000

360 min. 10.30 ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stacktemperature Standard temperature Meter calibration factor Duration ofsampling time Diameter ofStack 83.32043375 sq. ft. Cross sectional area ofstack 85.49 ft[(lbllbmol)·(inHg)]".5}I[s·R·inH20] 17.637 R/in.Hg 0.047070 cu.ftlml 0.0026688 in.Hg-cf/ml-R 9755 scf/MMBtu

Instrumental Data

4.28 %·dry



### 14.82 %-dry

80.90 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentration

### Client Spruance Genco, LLC Test Location Test Run Project No. 

### 3333
Calculations
1)

### Volume ofgassampled atstandard conditions,Vmstd.

Vmsld =K1· Y·Vm· Pb/Tm Vmsld 

### = 8.070 dscf 0.2286 dscm 3) Decimal fraction ofmoisture byvolume instackgas, Bws.

INPUT Bws 

### = Bws 

### = Based on the M29 sampling tram 0.1326 4) Molecularweightofthe stackgas on a wet basis, Ms. Unit No. 

### Two

Ms 

### =

## I**«44~%C02)** 

### +**(32~%02)** 

### +**(28~%N2»·** 

### (1-Bws)] 

### +(18*Bws) Ms= 28.879 Ib/lbmole 5) Average stack gas velocity, Vs.

INPUT Vs 

### = Vs = 

### Based on the M29 sampling tram 42.326 fps 6) Average actual stackgasvolumetricflowrate, Qa.

Oa 

### =60 sec/min" Vs " As Qa= 211597.24cfm 5992.43 cmm 7) Average stackgas dry volumetric flowrate, Qstd.
Qstd = 

### Oa • (TstdfTs) " (Ps/Pstd) * 

### (1-Bws) Ostd = 

### 150165.40 dscfm 4252.68 dscmm 8) Mercury concentrations and emission rates
C[MI • MIMI (ug) I Vmstd (dscm) 

### C[M]{Ib/dscf) = 

### C[M]{ug/dscm) 0; 

### 1e-06g/ug"2.205e-03Ib/g" 0 02832 dscm/dscf E[M](lb/hr) = 

### C[M] (ug/dscm) " (2.205E-09) (Ib/ug) " Qstd (dscmm) "60 (min/hr) E[M](lb/MMBtu) = 

### C[M](Ib/dscf) " Fd • (20.9/20.9-%02)

Element Mercury C[M](@ carr. 02) = C[M] (ug/dscm) " [ (20.9-corrected %02)/ (20 9-actual %02) 1 Corrected 02 percentage is: 7 % Sample Mass (ug)

0.0039 Conc (ug/dscm)

0.017 Cone@eorr. 02 

### (ug/dscm)

0.014 Conc. (lb/dscO 1.07E-12 Emission Rate Clb/hr) 

### 9.BOE-OB Page 2

Emission Rate

(lb/MMBtu)

1.31 E-083333-Hg-unspiked-R3

Client Project No. Test Location Test Run Test Date 

### Time Period

INPUT INPUT INPUT

INPUT INPUT INPUT 

### INPUT INPUT



### INPUT

INPUT

INPUT Vm= Pstatic = Pb = Ps = Pstd 

### = Tm 

### = Ts= Tsld= y= t= Ds 

### = As = Kp = K1 = 

### K2= K3 = Fd =

[02]
[C02]
[N2] 

### AirNova, Inc. EPA Method 1, 2, 3A, and 30B· Unspiked Tube (Flows, 

### 02/C02, and Mercury) 

### Spruance Genco, LLC 

### 3333 Unit No.1 Three 

### 04114110 1451-2056

Emission Data

6.924 dcf -0.50 in H20 30.51 in. Hg 30.47 in. Hg 29.92 In. Hg 537.1 

### R 655.4 R 527.7 R 

### 1.000

360 min. 10.30 

### ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time Diameterof Stack 83.32043375 sq. ft. Cross sectional area ofstack 85.49 fi[(Ib/lbmol)*(inHg)]"

.

### 5}1[s·R"*inH20] 17.637 R/in.Hg 0.047070 cu.fUml 0.0026688 in.Hg-cf/ml-R 9868 scf/MMBtu

Instrumental Data

4.31 %-dry

14.80 %-dry

80.89 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Spruance Genco, LLC Test Location Test Run Project No. 3333

Calculations 1) Volume ofgassampled atstandard conditions.Vmstd.

Vmstd**=K1~** 

### Y**~** Vm**~** 

### Pb/Tm Vmstd = 8.941 dscf 0.2532 dscm
3) Decimal fraction of moisture byvolume in stack gas, Bws.

INPUT Bws= Bws= Based on the M29 sampling Irain 0.1353
4) Molecularweightofthe stackgas on a wet basis, Ms. Unit No.1 Three

Ms =**[«44~%C02)** + (32·%02) 

### +**(28~%N2))"** (1·Bws)] 

### + (18"Bws) Ms= 28.844 Ib/lbmole
5) Average stack gas velocity, Vs.

INPUT Vs = Vs = Based on the M29 sampling train 42.025 fps
6) Average actual stack gasvolumetric f1owrate, Qa.
Oa =60 sec/min"Vs

.. As Oa = 210092.47 cfm 5949.82 cmm 7) Average stackgas dry volumetricflowrate, Qstd.

Ostd =Oa" (TstdfTs)" (PslPstd)· (1·Bws) Ostd = 148975.07 dscfm 4218.97 dscmm
8) Mercuryconcentrations and emission rates C[M] = M[M] (ug) / Vmstd (dsem) C[M]{lb/dscf) = C[M](ug/dscm)" 1e·06g/ug"2.205e-03Ib/g" 0.02832 dscm/dscf E(M](lb/hr) 

### =C[M} (ug/dscm)

.. (2.20SE-09) (Ib/ug)

.. Ostd (dscmm)

.. 60 (min/hr) E[MJllbIMMBtu) 

### =C[M](lbldsc0 • Fd • (20.9120 9-%02) C[M](@corr. 02) = C[M] (ug/dscm) "[(20.9·corrected %02)/ (20.9·actual %02)] Corrected 

### 02 percentage is: 

### 7 % Page 2

Sample Mass (ug)

0.0012 Cone. (ug/dscm)

0.005 Conc.@corr. 02 (ug/dscm)

0.004 Cone. (Ib/dsef) 2.96E-13 Emission Rate Emission Rate Element Mercury (Ib/hrl (lb/MMBlu) 2.65E-06 3.68E·09M7E

Client Project No. 

### TestLocation Test Date 

### Spruance Genco,LLC 

### 3333 Unit No.1 

### 04115110



### Parameter: 

### Oxygen Instrument SQ.an f% 021: 

### 22.03

Actual CalibratiQn 

### Gas Value (% 

### 021: Ang/\::zerCalibration Rfj.sQ.onse ('M! 

### 021. AnalvzerCalibration ErroL(% Span):

Zero**S~stem** Calibration Gas 

### At2Qarent Init. SI§. fnit $):,5. Final $1:::8. Final SI@.

Slack**~** Cal. Bias Calib. Cal. Bias Run Cone. Response (% span) Response (% span)



### 1 9.33 0.12 0.45 0.06 0.18 2 13.30 0.06 0.18 0.00 -0.09 3 12,91 0.00 -0.09 0.07 0.23 4 

### 0.00 007 0.23 0.00 -0.09 5 0,00 0.00 -0.09 0.00 -0.09 6 0.00 0.00 -0.09 0.00 -0.09 7 

### 0.00 0.00 -0.09 0.00 -0.09 8 0.00 0.00 -0.09 0.00 -0.09 g 

### 0.00 0.00 -0.09 0.00 -0.09 10 0.00 0.00 -0.09 0.00 -0.09 11 0.00 0.00 -0.09 0.00 -0.09 12 0.00 0.00 -0.09 0.00 -0.09 

### AirNova, Inc. Page 1 EPA Method

### 6e Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Ana/\::zfj:fCalib, Gases 

### Uascafe 

### zero low mid high $\,:5. 

### Qa!. Gas 

### 0.00 

### NIA 11.90 22.03 11,90 

### 0.02 

### NIA 12.02 21.97 

### 11.90 0.09 

### 0.00 0.54 

### -027

U[!scale Sy:stem Ci!;libration Gas Calib. 

### lait. $1::5. Init. S\,:s. Final S!!s. Fingl $\,:s. Ca/ib. Actual Drift Calib. Cal. Bias Calib. (2el. Bias Drift 

### Stack (% span) Response (% soan) Response (% span) (% span) Cone.



### -0.27 11.91 0.05 11.96 0.27 0.23 9.28 -0.27 11.96 0.27 12.00 0.45 0.18 13.21 0.32 12.00 0.45 12.00 0.45 0.00 12.81 -0.32 12.00 0.45 0.00 -54.02 -54.47 -0.07 0.00 0.00 -54.02 0.00 -54.02 0.00 

### ERR 0.00 0.00 -54.02 0.00 -54.02 0.00 

### ERR 0.00 0.00 -54.02 0.00 -54.02 0,00 

### ERR 0.00 0.00 -54.02 0.00 -5402 0.00 

### ERR 0.00 000 -54.02 0.00 -54.02 000 

### ERR 0.00 0.00 -54.02 0.00 -54.02 0.00 

### ERR 0.00 0.00 -54.02 0.00 -54.02 0.00 

### ERR 0.00 0.00 -54.02 0.00 -54.02 0.00 

### ERRM7E

Client Project No. Test Location Test Date Spruance Genco,LLC 

### 3333 UnitNo.1 04/15110

Parameter: InstrumentSpan (% 

### C02!: 

### Carbon Dioxide 22.28

ActualCalibration Gas Value (% C02)" AnalyzerCalibration Response (% 

### C021: AnalyzerCalibration EfTor

### t% Span):

Zero Sy:stem Calibration Gas Am.!8[f!nt lnit. Sys. Init. $)!S_ Final S):::s. FinfJ.1 

### S\"s.

Stack Galib. Cal. Biail Galib. Cal.**Bia~** Run Conc. Response (% span) Response (% span)



### 9.96 -0.12 -0.54 0.00 0.00 2 

### 6.37 0.00 0.00 -0_12 -0.54 3 6.85 -0.12 -0.54 -0.12 -0.54 4 

### 0.00 -0.12 -0.54 0_00 0.00 5 

### 000 

### 0.00 0.00 0.00 0.00 6 0_00 0_00 0.00 0.00 0.00 7 

### 0.00 0_00 0.00 0.00 0.00 8 0.00 0.00 0.00 0.00 0.00 

### 9 0.00 0.00 0.00 0.00 0_00 10 

### 0.00 0.00 0.00 0.00 0.00 11 

### 0.00 0.00 0.00 0.00 0.00 12 

### 0.00 0.00 0_00 0.00 0.00 

### AirNova, Inc. Page 2 EPA Method 6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

AnalyzerGalib. Gases Upscale "'-0 low mid high Sys. Cal.**Ga~** 

### 0.00 N/A 

### 12.38 22.28 

### 12.38 0.00 N/A 12.21 22.34 12.38 0.00 

### 0.00 -0]6 

### 0.27

URscale Sy:stem Calibration Gas Ga/ib. Init Sys. Init. S!!s. Final Sys. Final Sys Galib. Actual Drift Galib. 

### Cal. Bias Gal/b_ CaL Bias On'lt Stack (% span) Response (% span) Response (% span) (% span) Conc_



### 0.54 

### 12_33 -0.22 12.33 -022 0.00 10.01 -0.54 12.33 -0.22 12.45 0.31 0.54 

### 6.39 0.00 12.45 0.31 12.45 0.31 0.00 6.86 0.54 

### 12.45 0.31 0.00 -55.57 -55.88 0.12 0.00 0_00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55_57 0.00 -55.57 0.00 

### ERR 0_00 0.00 -55_57 0.00 -55.57 0_00 

### ERR 0_00 0.00 -55.57 0.00 -55.57 0_00 

### ERR 0_00 0.00 -55.57 0.00 -5557 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0_00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERRM7E

Client Project No. Test Location Test Date 

### Spruance Genco,LLC 

### 3333 Unit No.1 04/15/10

Parameter: 

### Carbon Monoxide Instrument Span (pDmVCO): 935.7

Actua! Calibration 

### Gas Value (ppmVCO): AnalyzerCalibration Response topmVCO): AnalyzerCalibration Error(% Spanl:

Zero Sy:stem Calibration Gas AQQarent Init. 

### S!!s. Init. Sys. Final SI:§:. Final

### Sys

Stack CaNb. Cal.**Bla~** Cafib. Cal. Bias Run 

# = Response (% span) Response (% span)



### 1 1362.3 -4.9 0.00 -4.9 0.00 2 583.5 -4.9 

### 0.00 -4.9 0.00 3 390.6 -4.9 

### 0.00 -4.9 0.00 4 

### 0.0 -4.9 

### 0.00 0.0 0.52 5 0.0 0.0 0.52 0.0 0.52 6 0.0 0.0 0.52 0.0 0.52 

### 7 0.0 0.0 0.52 00 0.52 8 00 0.0 0.52 0.0 0.52 9 

### 0.0 0.0 0.52 0.0 0.52 10 0.0 0.0 0.52 0.0 0.52 11 

### 0.0 0.0 0.52 0.0 052 12 0.0 0.0 0.52 0.0 052 

### AirNova, Inc. Page 3 EPA Method 6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

AnalyzerCalilJ.. 

### Gases U{2scale 

### zero low mid high Sk':S. Cal. Gas 

### 0.0 0.0 486.0 935.7 486.0 -4.9 

### 0.0 488.0 933.0 486.0 -0.52 

### 0.00 0.21 -029

URscale Sy:stem Calibration Gas CaNb. 

### Ini!. S'i.s. Init. Sys. Fingl

### Sys, Final Sys. Calib. Actual 

### On' Calib. Cal. Bi!3.§ Calib_ Cal. Bias Drift Stack (% span) Response (% span) Response (% span! (% span) Cone.



### 0.00 479.0 -0.75 479.0 -0.75 000 1373.1 0.00 479.0 -0.75 493.0 0.75 1.50 582.5 

### 0.00 493.0 0.75 474.0 -1.28 -2.03 393.6 0.52 474.0 -1.28 0.0 -51.94 -50.66 5.• 

### 0.00 00 -51.94 00 -51.94 0.00 

### ERR 0.00 0.0 -51.94 00 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 000 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 00 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERRM7E

Client Project No. Test Location Test Date Spruance GenCO,LLC 

### 3333 Unit No.1 04/15110

Parameter: 

### Total Hydrocarbons (as Instroment Span (ppm V THCJ: 20

Actual Calibration Gas Value (ppmV THCJ: AnalyzerCalibration Response fppmV THC!: AnalyzerCa1ibrafion

### Error (%

### Cal. Gas Value):

Zero**S~stem** Calibralion Gas AQQarent Init. S)(S. 

## mit. S:I:§. Final Sys. Fma/.5:\"s.

Stack Calib. 

### CaL. Bias Calib. Cal. Bias Run**~** Response (% span) Response (% span)



### 1 6.9 -0.1 0.00 0.3 2.00 2 5.0 0.3 2.00 0.0 0.50 3 3.5 0.0 0.50 0.2 1.50 4 0.0 0.2 1.50 0.0 0.50 

### 5 0.0 0.0 0.50 0.0 0.50 6 0.0 0.0 0.50 0.0 0.50 7 

### 0.0 0.0 0.50 0.0 0.50 8 0.0 0.0 0.50 0.0 0.50 9 0.0 00 0.50 00 0.50 10 0.0 0.0 0.50 0.0 0.50 11 0.0 0.0 0.50 0.0 0.50 12 0.0 0.0 0.50 0.0 0.50 

### AirNova, Inc. Page 4 EPA Method 6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)



### CH4 ) Anal\"zerCallb.**Ga~es** 

### UQ.scale zero 

### !illx mid high 

### SlI:s. Ca'- Gas 

### 0.0 4.9 

### 9.1 17.4 

### 9.1 -0.1 

### 4.9 9.1 17.3 9.1 0.41 0.11 -0.57

Ugscale Sl/stem Calibration Gas Gallb. Init· S):':S. Init. Sl!s. Final S!:,:s. Final S)@. Calib. Actual Drift Galib, Cal. BIB§. Callb. Cal. Bias Drift Stack (% span) Response (% 

### span) Response (% span) (% span) Cone.



### 2.00 4.9 -20.95 4.9 -20.95 0.00 12.9 -1.50 4.9 -20.95 5.0 -20.45 0.50 9.2 1.00 5.0 -20.45 4.9 -20.95 -0.50 6.4 -1.00 4.9 -20.95 00 -45.45 -24.50 ·0.4 0.00 0.0 -45.45 0.0 -45.45 0.00 

### ERR 0.00 0.0 -45.45 0.0 -45.45 0.00 

### ERR 0.00 0.0 -45.45 0.0 -45.45 0.00 

### ERR 0.00 0.0 -45.45 0.0 -45.45 0.00 

### ERR 0.00 0.0 -45.45 0.0 -45.45 0.00 

### ERR 0.00 0.0 -45.45 0.0 -45.45 0.00 

### ERR 0.00 00 -45.45 0.0 -45.45 0.00 

### ERR 0.00 00 -45.45 00 -45.45 0.00 

### ERR3333-Formaldehyde-R1



### Client Project No. Test Location Emission Source Test Date Test Run Time Period

Vlc= Vm= Pstatic = Pb= Ps= Pstd = 

### dP = dH = 

### Tm· Ts = Tstd= y= t= 

### Dn 

### = An = 

### Ds = As = Cp = 

### Kp = 

### K1 = K2 = 

### K3 = Fd = CF =

[02] [C02]
[N2] 

### AirNova, Inc. EPA Methods 1,2.3A,4,and RCRA Method 0011

(Flows, 

### 02/C02, H20, 

### and Formaldehyde)
Spruance Genco, LLC 3333 Richmond, Virginia Unit No.1 04/15/10 One 1130-1336


### Emission Data

317.2 cc 89.740 dcf

-0.50 in. H20 30.39 in. Hg 30.35 in. Hg 29.92 in. Hg 0.639 in. H20

### ".5

1.81 in. H20 538.8 

### R 674.4 

### R 527.7 

### R

1.00 120 min. 0.296 in. 0.000478 sq. ft. 10.30 

### ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average meiertemperature Average stack temperature Standard temperature Metercalibration factor Duration of sampling time Nozzle diameter Nozzle area Diameterofstack 83.3204 sq. 

### ft. Cross sectional area ofstack 0.84 Pilot tube coefficient 85.49 ft[(lb/lbmol)*(mHg)]".5}/[s"R*inH20] Pitot tube constant 17.637 R/in.Hg 0.047070 cu.fVml 0.0026688 in.Hg-cf/ml-R 9862 scf/MMBtu 7.793E-08 Ib/dscf 1ppmVd constant constant constant Fuel Factor Conversion FactorforCH20



### EPA Method 3A Instrumental Data 9.28 %-dry 10.01 %-dry

80.71 %-dry Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration Data from'

EPA4 EPA4 EPA 

### 2

EPA 

### 2

EPA2 EPA4 EPA4 EPA2

EPA2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

Calculations

1) Volume of gas sampled at standard conditions, Vmstd. Vmsld =K1* Y* Vm '" (Pb + 

### dH/13_6) ITm Vmsld = 89,666 dscf 2.539 dscm Richmond, Virginia One

2) Volume ofwater vapor collected at standard conditions, Vw(std). Vw(std) = K2"Vic Vw(std) = 14.931 scf

3) Decimal fraction ofmoisture by volume in stack gas, Bws. Bws =Vwstd / (Vmstd+Vwstd) Bws = 0.1427

4) Molecularweight ofthe stack gas on awet basis, Ms. Ms 

### =[((44*%C02) + (32*%02) + (2S*%N2)) * (1-Bws) 

## I+ (1S*Bws) Ms 

### = 28.264 Ib/lbmole

5) Average stack gas velocity, Vs. Vs = Kp" Cp,o (dP) " (Ts/Ps*Ms)".5 Vs 

### = 40.670 fps

6) Average actual stack gas volumetric f1owrate, Oa. Oa = 60 sec/min·Vs " As Oa= 20331981 cfm 5758,02 cmm

7) Average stack gas dry volumetric flowrate, Qsld. Qstd = Oa" (TstdfTs)" (Ps/Pstd)" (1-Bws) Qsld = 138364.38 dscfm Qstd = 3918.48 dscmm Page 2Client Spruance Genco, llC Project No. 

### 3333 Test location Test Run

Calculations (cont.)
8) Formaldehyde

- Concentrations and EmissIon Rates M[CH20] 

### =sample mass (mg) Richmond, Virginia One

C[CH20] = M[CH20] (mg) / sample volume (dscm) C[CH20 @ corr. %021 = C[CH20] (ppmV) * (20 9-Corr. %02)/(20.9-Actual %02) Corrected 02 Percentage = 

### 7 % Page 3

E[CH20] = C[CH20] (mg/dscm) * 60 (minlhr) * Qstd {dscmm);O; (1 Ib 14.536 e+05 mg) E[CH20](lb/MMBtu) = C[CH20]{ppmV) CF * Fd * (20.9/20.9-%02)
Compound Sample Mass Concentration Concentration Concentration Mass Emission 

### ll:!:!9l (mg/dscm) 

## !mmJlil pmV@Corr.%O (Ib/hr)
Formaldehyde 0.20600 0.081 

### 0065 0078 0.042

9) Isokinecity, 

### I. 

### % 1= [100,oTs*(K3*Vlc+«{Vm*Y)fTm)*(Pb+(dH/13.6))))] I (60*t*Ps·Vs*An) %1= 94.16 Mass Emission (lb/MMBtu)

8.98E-OS3333-Formaldehyde-R2

Client Project No. Test Location Emission Source Test Date Test Run Time Period

Vlc= Vm= Psratic = Pb = Ps 

### = Pstd = dP = dH 

### = Tm'" Ts= Tstd= y= t= On = An = Os = As = Cp 

### = Kp '" K1

# = K2 '" K3 '" Fd '" CF '"

[02[ [C02[
[N2[ 

### AirNova, Inc. EPA Methods 1,2,3A,4,and ReRA Method 0011

(Flows, 02/C02, H20, and Formaldehyde)
Spruance Genco, LLC 3333 Richmond, Virginia Unit No 1 04/15/10 

### Two 1440-1653

Emission Data

271.6 cc 82.242 def

-0,50 in. H2O 30.32 In, Hg 30.28 in Hg 29,92 in Hg 0.706 in H20 ".5

1.37 in H2O 555.2 R 638.5 R 527,7 R

1,00 120 min. 0.250 in. 

# o000341 sq. ft. 1030 ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta 

### P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameter of stack 83.3204 sq. ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49**ft[(lb/lbmol)*(inHg)]".5}/[s~R"lnH201** Pitot tube constant 17.637 R/in.Hg 0.047070 cu,fUml 0.0026688 in.Hg-cf/ml-R 9755 scf/MMBtu 7.793E-08 Ib/dscf

### I ppmVd constant constant constant Fuel Factor Conversion Factorfor CH20

EPA Method 3A Instrumental Data

13.21 %-dry 6.39 %-dry

80.40 %-dry Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration Data from:

EPA4 EPA4 EPA 2

EPA2

EPA2 EPA4 EPA4 EPA2

EPA2Client Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations

1) Volume ofgas sampled at standard conditions, Vmstd. Vmstd =K1* Y·Vm * (Pb + dH/13.6) ITrn Vmstd = 79.482 dscf 2.251 dscm Richmond. Virginia Two

2) Volume ofwater vaporcollected at standard conditions, Vw(std). Vw(std) = 

### K2 * Vic Vw(std) 

### = 12.784 

### scf

3) Decimal fraction of moisture by volume in stack gas, Bws. Bws 

### =Vwstd I (Vmstd+Vwstd) Bws 

### = 0.1386

4) Molecularweight ofthe stack gas on a wet basis, Ms. Ms = [«44*%C02) + (32*%02) + (28*%N2»;O (1-Bws)] + (18*Bws) Ms= 27.9501b/lbmole

5) Average stack gas velocity, Vs. Vs = Kp· Cp 

### * (dP) 

### * (Ts/Ps*Ms)" 5 Vs = 44.015 fps

6) Average actual stack gas volumetric flowrate, Qa. Qa = 60 sec/min·Vs • As Qa

# = 220041 58 cfm 6231 58 cmm

7) Average stack gas dryvolumetric f1owrate, Qstd. Qstd 

### =Qa • (TstdfTs) • (Ps/Pstd) • (1-Bws) Qstd

# = 158573.91 dscfm Qstd = 4490.81 dscmm Page 2Client Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations (cont.) Richmond, Virginia 

### Two

8) Formaldehyde· Concentrations and Emission Rates M[CH20]

### =sample mass (mg) C[CH20]

### =M[CH20] (mg) 1sample volume (dscm) C[CH20 @ corr. %02] = C[CH20] (ppmV)**~** (20_9-Corr. %02)/(20 9-Aclual %02) Corrected 02 Percentage = 

### 7 % E[CH20] = C[CH20] (mg/dscm)" 60 (min/hr) "Qstd (dscmm)" (1 Ib /4.536 e+05 mg) E[CH20]{lb/MMBtu) = C[CH201{ppmV) CF" Fd**~** (20.9/20.9-%02) Page 3

Compound Sample Mass Concentration Concentration Concentration Mass Emission Mass Emissjon {!!llll (mq/dscm) {QruJ:)Yl 'pmV@Corr.%O (Ib/hr) (lb/MMBlu)
Formaldehyde 0.05600 0.025 0.020 0_036 0.015 4 12E-05

9) Isokineclty, I % I 

### =[100*Ts*{K3*Vlc+«(Vm*Y)fTm)*(Pb+(dH/13.6))))] 1(60''l*Ps·Vs*An) % I

# = 102.103333-Formaldehyde-R3

Client Project No. Test location Emission Source Test Date Test Run Time Period

Vlc= Vm= Pstatic = Pb= Ps= Pstd = dP = dH = Tm= Ts = Tstd= 

### y= t= Dn 

### = An = Ds = As = 

### Cpo Kp= K1 = K2 = K3 = Fd = CF =



### [02] [C02]
[N2] 

### AirNova, Inc. EPA Methods 1,2,3A,4,and RCRA Method 0011

(Flows, 

### 02/C02, 

### H20, and Formaldehyde)
Spruance Genco, LLC 

### 3333 Richmond, Virginia Unit No.1 04/15/10 Three 1812-2022

Emission Data

278.2 cc 82.782 dcf

-0.50 in. H20 30.24 in. 30.20 in. 29.92 in. 0.706 in.

1.41 in. 548.4 R 641.5 R 527.7 R

1.00 

### H9 H9 H9 H20h.5 

### H2O

120 min. 0.250 in. 0.000341 sq. 

### ft. 10.30 

### ft Vol of H20collected Dry gas meter reading Slatic pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standardtemperature Metercalibration factor Duration of sampling time Nozzle diameter Nozzle area DIameter ofstack 83.3204 sq. ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)*{inHg)jh.5}/[s*R*inH20] Pitottube constant 17.637 R/in.Hg 0.047070 cu.Wml 0.0026688 in.Hg-cf/ml-R 9868 scf/MMBtu 7.793E-OB Ib/dscf

### I ppmVd constant constant constant Fuel Factor Conversion Factorfor CH20

EPA Method 3A Instrumental Data

12.B1 %-dry Oxygen concentration 6.86 %-dry Carbon Dioxide concentration

80.33 %-dry Nitrogen concentration Data from:

EPA4 EPA4 

### EPA 2

EPA 2

EPA2 EPA4 EPA4 

### EPA2

EPA2Client Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations

1) Volume ofgas sampled at standard condillons, Vmstd. Vmstd =K1" Y " Vm

.. (Pb 

### +dH/13.6)/ Tm Vmstd = 80.791 dscf 2.288 dscm

2) Volume ofwater vaporcollected at standard conditions, Vw(std) Vw(Sld) = 

### K2

.. Vic Vw(std) = 13.095scf

3) Decimal fraction of moisture by volume in stack gas, Bws. Bws =Vwstd 

### I (Vmstd+Vwstd) Bws = 0.1395

4) Molecularweight ofthe stack gas on awet basis, Ms. Richmond. Virginia Three

Ms = [«44*%C02)

### + (32·%02) 

### + (28*%N2»" (1-Bws) 

## 1 + (1S*Bws) Ms= 27.991 Ib/lbmole

5) Average stack gas velocity, Vs. Vs 

### =Kp

.. Cp" (dP) " (Ts/Ps·Ms)".5 Vs 

### = 44170 fps

6) Average actual stack gas volumetric flowrate, Qa. Oa = 60 sec/min" Vs

..As Oa = 220815.76 cfm 6253.50 cmm

7) Average stack gas dry volumetric fJowrate, Qstd. Qstd

# = Oa" (TstdfTs)" (Ps/Pstd)" (1-Bws) Qstd = 157800.68 dscfm Qstd = 4468.92 dscmm Page 2

### Client Spruance Genco, LLC 

### Project No. 3333 

### Test Location Test Run
Calculations (cont.)
8) Formaldehyde

- Concentrations and Emission Rates M[CH20] = sample mass (mg) Richmond. Virginia Three

C[CH20] = M[CH20] (mg) 1sample volume (dscm) C[CH20 @corr. %02] = qCH20] (ppmV) • (20.9-Corr. %02)1(20.9-ActuaJ %02) Corrected 02 Percentage = 7 

### % E[CH20] '" C[CH20] (mg/dscm)

.. 60 (min/hr) * Qstd (dscmm) * (1 Ib 

### 14.536e+05 mg) E[CH20](lb/MMBtu) 

### =C[CH20](ppmV) CF**~** Fd

.. (20.9/20.9-%02) 

### Page 3

Compound Sample Mass Concentration Concentration Concentration Mass Emission Mass Emission 

### irr!.9l (mq/dscm) (QQrffiQ. 'pmV@Corr.%O (Ib/hr) (lb/MMBtu)
Formaldehyde 0.02870 0.013 0.010 

### 0.017 0.007 2.00E-05

9) Isokinecity, I. 

### % I=**[100~Ts*(K3·Vlc+«(Vm·Y)fTm)"(Pb+(dH/13.6))))]1** (60*t*Ps·Vs*An) %1= 104.29Client Project No. Test Location Emission Source Test Date Test Run Time Period

INPUT 

### INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT 

### INPUT

INPUT INPUT INPUT Vic

# = Vm= Pstatlc

# = Pb 

### = Ps = Pstd

# = dP = dH 

### = Tm= Ts = Tstd= 

### y= t= On = An

# = Os

# = As = Cp

# = Kp = 

### K1 

# = K2 = K3

# = Fd

# =

[02[ [C02[ [N2] {COl {THC[ [CH4[ 

### AirNova, Inc. Page 1 of3 EPA Methods 

### 1, 2, 3A, 

### 4,10,18 and 25A

(Flows, 

### 02/C02, H20, CO and NMHC)
Spruance Genco, LLC 

### 3333 Richmond, VIrginia Unit No.1 

### 04/15/10 

### 00. 1130-1336 Emission Data
317_2 cc 89.740 dcf

-0.50 in. H20 30.39 in, Hg 3035 in. 

### Hg 29.92 in, 

### Hg 0.6388 in. H20 A 5 

### 1 81 in, 

### H2O 538.8 

### R 674.4 

### R 527.7 

### R

1,00

120 min. 0.296 in. 0.000478 sq, ft 

### 10.300 ft. Vol of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameterofstack 83.3204 sq_ ft Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49**ft.[(1bjlbmol)·(inHgW.5}/[s~R·inH201** 17.637 R/in.Hg constant 0047070 cU.ftlml 0.0026688 in.Hg-cf/ml-R 9862 scf/MMBtu

Instrumental Data 9,28 %-dry 10.01 %-dry 

### 80.71 %-dry 1373.1 ppmV-dry



### 12 9 ppmV-wet 28.9 ppmV-dry constant Pitot tube constant constant From EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentratlon Nitrogen concentration Carbon Monoxide concentration Total Hydrocarbon concentration Methane Concentration by GC-FID

### Client Project No. Spruance Genco, LLC 

### 3333 Emission Source Unit No.1 Test Run One
Calculations 1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1" Y" Vm,o (Pb +dH/13.6)/ Tm Vmstd 

### = 89.666 dscf 2.539 dscm 2) Volume ofwatervapor collected atstandard conditions, Vw(std). Vw(std) = K2" Vic Vw{std)

# = 14.931 scf 3) Decimal fraction ofmoisture byvolume in stack gas, Bws.

Bws

# = Vwstd I (Vmstd+Vwstd) Bws = 0.1427 4) Molecularweightofthe stack gas on awet basis. Ms.

Ms = [«44"%C02)+ 

### (32*%02) + (28*%N2» * (1-Bws) 

## 1 + (18*Bws) Ms = 28.264 Ib/lbmole 5) Average stackgas velocity.Vs.

Vs = Kp " Cp " (dP) * 

### (Ts/Ps*Ms)" 5 Vs

# = 40.670 fps 6) Average actual stack gasvolumetricflowrate, Qa.
Qa = 60 sec/mm " Vs • As Qa

# = 203319.8 cfm 5758.0 cmm 7) Average stack gas 

### dryvOlumetricflowrate, Qstd.
Qstd

# = Qa" (TstdlTs),o (Ps/Pstd)" (1-Bws) Qstd = 138364.4 dscfm 3918.5 dscmm Page 2 of3Client Project No. 

### Spruance Genco, LLC 3333 Test Location Test Run
Calculations (cont.)

### Unit No.1 One Page 3 of3

8) Total Hydrocarbon concentrationsand emissions



### INPUT C[THC] dry basIs = C[THC] wet/(1-Bws) C[VOC] dry basis

# = C[THC]

- C[CH4] Corr. crCH4] = ({20.9-02% corr. value)/(20.9-actual avg. 02% value»"VOC value E[VOC] = (C[VOC]*Mol Wt[VOC equivalent]*60(min/hr)*Qstd(dscfm))/(Molar Vol. air*10"6) E[VOC Ib/MMBtu]

# = Cd;O Fd" (20.9/(20.9-actual 02%)) C[THC] 

# = 12.9 ppmVw C[THC] = 15.0 

### ppmVd C[CH4] = 

### 28.9 ppmVd C[VOC] = 

### -13.9 ppmVd C[VOC]

# = -16.6 ppmVd corrected 10 

### 7 

### % 02 Mol. WI. [THCJ= 

### 44.096 Ib/lb-mole Molar vol air= 385 scf/lb·mole 

### @ Propane 

### 68 def F E[VOC] = -13.17 Ib/hr Conv Factor. E]VOC]

# = 4.134E·oa convert ppmV to Ib/scfTHC as CH4 -1.02E·02 Ib/MMBtu 9) Carbon Monoxide concentrations and emissions


### Corr. C[CO] = 

### «20.9·02%corr. value)/(20.9·actual avg. 02%value»·Avg. raw CO value E[CO Ib/hr] = (C[CO]*Mol Wt[CO]*60(min/hr)*Qstd(dscfm»/(MolarVol. air*10"6) E[CO Ib/MMBtu] = Cd" Fd**~** 

### (20.9/(20.9-aclual 02%» C[CO]

# = 1373.1 ppmVd qCO] = 

### 1642.5 ppmVd corrected to 7 % 02 Mol. 

### Wt. [CO]= 28.01 

### Ib/lb-mole Molar vol airE]CO]

# = Conv Factor. E[CO] 

### = 385 scf/lb-mole 

### @ 829.34 Ib/hr 7.235E-08 convert ppmVto Ib/scf CO 1.762 Ib/MMBtu 

### 68 def FClient Project No. Test Location Emission Source Test Date Test Run Time Period

INPUT INPUT INPUT INPUT Vic 

### = Vm= Pstatic = Pb

# = Ps = Pstd = dP 

### = dH = Tm

# = Ts = INPUT Tstd= INPUT y = INPUT t = INPUT On = An

# = INPUT

INPUT

INPUT

INPUT INPUT

INPUT INPUT INPUT Os = As = Cp

# = Kp

# = K1 

# = K2 = 

### K3 = Fd

# =

[O2[ [C02[ [N2] [COr [THC[ [CH4] 

### AirNova, Inc. EPA Methods 

### 1, 2, 3A,4, 

### 10, 18 and 25A

(Flows, 02/C02, H20, CO and NMHC)
Spruance Genco, LLC 3333 Richmond, Virginia Unit No.1 04/15/10 Two 1440-1653 Emission Data

271.6 cc 82.242 dcf

-0.50 in. H2O 30.32 in. Hg 30.28 in. Hg 29.92 in. Hg 0.7057 in. H20 ".5 1.37 in. H2O 555.2 R 

### 638.5 R 527.7 R

1.00

120 min. 0.250 in. 0.000341 sq. ft.. 10300 ft 

### 83.3204 sq. ft.. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Slack pressure EPA Standard pressure Average sq.rt delta P Average draft. gauge reading Average metertemperature Average stacktemperature Standard temperature Meter calibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameter of stack Cross sectional area of stack 0.84 Pitot tube coefficient 85.49 ft[(lb/lbmol)*(inHg)}".5}/[s*R*inH20] 17.637 R/in Hg constant Page 1 of3

0.047070 cu.ft/ml constant Pitottube constant 0.0026688 in Hg-cf/ml-R 9755 scf/MMBtu

Instrumental Data 13.21 %-dry 6.39 %-dry 80.40 %-dry 582.5 ppmV-dry

9.2 ppmV-wet 13.6 ppmV-dry constant From EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentratLon Nitrogen concentration Carbon Monoxide concentration Total Hydrocarbon concentration Methane Concentration by GC-FID

### Client Project No. Spruance Genco, LLC 

### 3333 Emission Source Unit No. 

### 1 Test Run Two

Calculations 1) Volume ofgassampled atstandard conditions, Vmstd.

Vmstd =K1*Y"Vm * (Pb + dH/13.6) ITm 

### Vmstd

# = 79.482 dscf 2.251 dscm 2) Volume ofwatervapor collected atstandard conditions, Vw(std). Vw{sld) = K2 ,. Vic Vw{std) = 12.784 scf
3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws =Vwstd I 

### (Vmstd+Vwstd) Bws= 01386 4) Molecularweightofthe stack gas on awet basis, Ms.

Ms = [({44*%C02) + (32*%02) + (28*%N2)) * 

### (1-Bws) 

## 1+ (18*Bws) Ms

# = 27.950 Ib/lbmole S) Average stackgas velocity, Vs.

Vs

# =Kp * Cp 

### *(dP) * (Ts/Ps*Ms)".5 Vs = 44.015 fps 6) Average actual stack gas volumetricflowrate, Qa.

Qa 

### = 60 sec/min * 

### Vs ,. As Qa

# = 220041.6 cfm 6231.6 cmm 7) Average stackgas dryvolumetric flowrate, Qstd.
Qstd = Qa * 

### (TstdlTs) * 

### (Ps/Pstd) * (1-Bws) Qsld = 158573.9 dscfm 4490.8 dscmm Page 2 of3Client Project No. Spruance Genco, LLC 3333 Test Location Test Run
Calculations (cont.)Unit No.1 

### Two Page 3 of3

8) Total Hydrocarbon concentrationsand emissions

INPUT C[THC] dry basis = C[THC] wet/(1-Bws) C[VOCJ dry basis = C[THC]

- C[CH4] Carr. C[CH4] = «20.9-02%carr. value)/(20.9-actual avg. 02% value))*VOC value E[VOC] = (C[VOC]*Mol Wt[VOC equivalent]*60(mm/hr)*Qstd(dscfm»/{MolarVol. air*10A6) E[VOC Ib/MMBtu] = Cd * Fd * (20.9/(20.9-actual 02%» C[THC] = 9.2 ppmVw C[THC] = 10.7 ppmVd C[CH4) 

### = 13.6 ppmVd C[VOC) 

### = -2.9 ppmVd C[VOC] = -5.3 ppmVd corrected to Mol. Wt. [THC]= 44.096 lb/lb-mole Molarvol air= 385 scf/lb-mole 

### @ E[VOG) = -3.18Iblhr 

### 7 Propane 68
Conv Factor. E[VOG) = 4.134E-08 convert ppmV to Ib/scfTHC as CH4 -3.20E-03 Ib/MMBtu %02
def F

9) Carbon Monoxide concentrations and emissions

Carr. C[CO] = «20.9-02% carr. value)/(20.9-actual avg. 02% value))*Avg. raw CO value E[CO Ib/hr] = (C[COl"Mol Wt[CO]*60(min/hr)'"Qstd(dscfm))/(Molar Vol.**ai~101\6)** E[CO Ib/MMBtu] = Cd * Fd 

### * (20.9/(20.9-actual 02%)) C[CO)

# = 582.5 ppmVd C[CO] = 1052.9 ppmVd corrected to 7 % 02 Mol. Wt [CO]= 2801 Ib/lb-mole Molarvol air= E[CO)

# = Conv Factor. E[CO) 

### = 385 scf/lb-mole 

### @ 403.21 Ib/hr 7.235E-08 convert ppmVto Ib/scf CO 1.117 Ib/MMBtu 68 def FClient Project No. Test Location Emission Source Test Date Test Run Time Period

INPUT INPUT INPUT INPUT Vlc= Vm= Pstatic = Pb 

### = Ps = Pstd = dP 

### = dH 

### = Tm= Ts

# = INPUT Tstd= INPUT 

### y = INPUT t = INPUT On = An = INPUT Os = As = INPUT

INPUT

INPUT INPUT

INPUT INPUT INPUT Cp

# = Kp

# = K1 

# = K2 = 

### K3 = Fd

# =

[O2[ [CO2] [N2] [CO] [THC] [CH4] 

### AirNova, Inc. EPA Methods 

### 1, 2, 3A, 

### 4, 10, 18 and 25A

(Flows, 

### 02/C02, H20, CO and NMHC)
Spruance Genco, LLC 

### 3333 Richmond, Virginia Unit No, 1 04/15/10 Three 1812-2022 Emission Data

278.2 cc 82.782 dcf

-0.50 in. H2O 30.24 in. Hg 30.20 in. Hg 29.92 in. Hg 0.7061 in. H20 11.5 1.41 in. H2O 548.4 

### R 641.5 

### R 527.7 

### R

1.00

120 min. 0.250 in. 0.000341 sq. ft.. 10.300 

### ft. 83,3204 sq. ft.. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft. gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration of sampling time Nozzle diameter Nozzle area Diameter ofstack Cross sectional area of stack 0.84 Pitot tube coefficient 85.49 ft.[(lb/lbmol)*(inHgW.5}/[s*R*inH201 17.637 R/in.Hg constant Page 1 of3

0,047070 cu.ft!ml 00026688 in.Hg-cf/ml-R 9868 scf/MMBtu constant Pitot tube constant

Instrumental Data 12.81 %-dry 6.86 %-dry 80.33 %-dry 3936 ppmV-dry

6.4 ppmV-wet 7.6 ppmV-dry constant From EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Carbon Monoxide concentration Total Hydrocarbon concentration Methane Concentration by GC-FID

### Client Project No. Spruance Genco, LLC 3333 Emission Source Unit No.1 Test Run Three
Calculations
1) 

### Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1·

### Y·Vm • (Pb 

### + dH/13.6) I 

### Tm Vmstd = eo 791 dscf 2.288 dscm
2) 

### Volume ofwatervapor collected atstandard conditions, Vw(std).
Vw(std) 

### =K2**~** 

### Vie Vw(std) = 13095 scf
3) 

### Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws =Vwstd 

### I (Vmstd+Vwstd) Bws= 0.1395
4) Molecularweightofthe stack gas on a wetbasis, Ms.

Ms 

### =[«44*%C02) 

### + (32*%02) + (28*%N2)" (1-Bws) 

## 1 +**(1e~Bws)** 

### Ms = 27.991 Ib/lbmole
5) 

### Average stack gasvelocity, Vs.
Vs = Kp;O Cp" (dP);O**(Ts/Ps~Ms)".5** 

### Vs 

### = 44.170 fps
6) Average actual stack gasvolumetric f1owrate, Qa.
Qa = 60 sec/min"Vs

.. As Qa = 220815.8 efm 6253.5 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd

# = Qa" (Tstd/Ts)" (Ps/Pstd)'" (1-Bws) Qstd = 157800.7 dscfm 4468.9 dscmm Page 2 of3Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations (cant.)Umt No.1 Three Page 3 of3



### 8) Total Hydrocarbon concentrations and emissions

INPUT C[THC] dry basts = C[THC] wetl(1-Bws) C[VOC] dry basis

# = C[THC]- C[CH4] Corr. C[CH4] = «20.9-02%carr. value)/(20.9-actual avg. 02% value))*VOC value E[VOC] = (C(VOC]*Mol Wt[VOC equivalent]*60(min/hr)*Qstd(dscfm»/(MolarVol. air*1 0"6) E[VOC Ib/MMBtu] = Cd * Fd * (20.9/(20.9-actual 02%» C[THC] = 6.4 ppmVW C]THC] = 7.4 ppmVd C[CH4] 

# = 7.6 ppmVd C(VOC] = -0.2 ppmVd C[VOC} = -0.3 ppmVd corrected to 

### 7 %02 Mol. WI. [THC]= 44.096 Ib/lb-mole Molarvol air= E]VOC] 

### = Conv Factor. E]VOC] = 385 scf/lb-mole 

### @ -0.18 Ib/hr Propane 

### 68 def F
4.134E·08 convert ppmV to Ib/scfTHC as CH4

-1.71E-04Ib/MMBtu 9) Carbon Monoxide concentrations and emissions

Corr. qCO] = «20.9-02%corr. value)/(20.9-actual avg. 02% valueWAvg. raw CO value E[CO Ib/hr] = (C[CO]*Mol Wt[CO]*60(min/hr)*Qsld(dscfm»/(MolarVol. air*10"6) E[CO Ib/MMBtu] = Cd 

### * Fd * (20.9/(20.9-actual 02%» C[CO] 

### = 393.6 ppmVd C[CO]

# = 676.3 ppmVd corrected to 7 

### % 02 Mol. Wt. [CO]= 28.01 Ib/lb·mole Molar vol air= E]CO]

# = Conv Faclor. E[CO]

# = 385 scf/lb-mole 

### @ 271.12 Ib/hr 7.235E-08 convert ppmVto Ib/scf CO 0.726 Ib/MMBtu 

### 68 def F3333-SSVOH-R1 

### AirNova, Inc.

Client Project No. Test Location Test Run Test Date TestTime

INPUT EPA Methods 1,2,3A,4and 0010 with SW-846 Method 82700 (Flows, 02fC02, H20. Speclated Semivolatile Organic HAPs and PAHs)

Vlc= 

### Vm" Pstatic = Pb= Ps = Pstd = dP = dH = Tm= Ts= Tstd= On = An = y= t 

### = Os = As = Cp = Kp = K1 = K2 = K3 = 

### Fd"

[02]
[C02]
[N2] Spruance Genco, LLC 3333 Unit No_ 1 One 04/15/10 1130-1342

Emission Data
296,6 cc 85.997 dcf -0.50 in, H20 30,39 in. Hg 30.35 in. Hg 29.92 in. Hg 0.5922 in H20 ",5

1.529 in, H20 538.1 

### R 668.4 R 527.7 R 0.3 in. 0000491 sq, ft. 0.97

120 min. 10.300 ft. Vol. of H20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area of nozzle orifice Meter calibration factor Duration ofsampling time Diameter ofstack 83.3204 sq. 

### ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[{lb/lbmol)*{inHg)]",5}/[s·R*inH20] Pitot tube constant 17.637 R/in.Hg 0.047070 cu.ftfml 00026688 m.Hg-cf/ml-R 9862 scf/MMBtu Instrumental Data

9.28 %-dry

10.01 %-dry

80.71 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1'" Y '" Vm '" (Pb + dH!13.6)/ Tm Vmsld = 83.395 dscf 2.36 dscm Unit No.1 One

2) Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std) '" K2

.. Vic Vw(std) '" 

### 13.961 scf
3) Decimal fraction of moisture byvolume in stackgas, 8ws.

Bws = Vwstd I (Vmstd+Vwstd) Bws'" 0.143
4) Molecularweight ofthe stackgas on awet basis, Ms.

Ms'" [«44*%C02)

### +(32*%02) 

### + (28"%N2»"(1-Bws) 

## 1 + (18"'Bws) Ms = 28.26 Ib/lbmole
5) Average stack gas velocity, Vs.

Vs = Kp '" Cp • (dP)

.. (Ts/Ps"Ms)".5 Vs '" 37.54 fps
6) Average actual stackgas volumetric flowrate, Qa.

Oa 

### =60 sec/min"Vs *As Qa = 187672.7 cfm 5314.9 cmm 7) Average stackgas dryvolumetric flowrate, Qstd.
Qstd 

### =Oa * (TstdfTs).o (Ps/Pstd)" (1-Bws) Qstd = 128764.0 dscfm 3646.6 dscmm Page 2Client Spruance Genco, LLC Test Location Unit No. Page 3 Project No. 

### 3333 Test Run 

### One

Calculations (cont.)
8) Speciated Semivolatile Organic HAPs

- Concentrations and Emissions
qSSVOH] '" M[SSVOH](ug) IVmstd(dscm) qSSVOH](Ib/dscf) '" qSSVOH](ug/dscm) * 1e-06g/ug 

### *2.205e-03Ib/g;O 0.02832 dscm/dscf E[SSVOH](lb/hr) = qSSVOH](ug/dscm)* Qstd(dscmm) * (2.205E-09)(lb/ug) ·60(min/hr) E[SSVOH](lb/MMBtu) = qS8VOH](lb/dscf) • Fd * (20.9/20.9-%02) qSSVOH](@ carr. 02) = qSSVOH] (ug/dscm) * [ (20.9-corrected %02) 1(20.9-actual %02) ] Corrected 02 percentage is: 

### 7.0 %

SSVOH SamJ;!le Conc. QQn!;;.@ggrr. 02 Conc. Emission Rate Emission Rate Analyte Mass (uql (uq/dscm) (ug/dscm) (lb/dscO (Ib/hr) (lb/MMBtu)
Acenaphthene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Acenaphthylene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO o OOE+OO Acetophenone 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO o OOE+OO Aniline 

### 0.00 0.000 

### 0.000 O.OOE+OO O.OOE+OO o OOE+OO Anthracene 0.00 0.000 

### 0.000 O.OOE+OO O.OOE+OO o OOE+OO Benzidine 

### 000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(a)anthracene 

### 000 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(b)fluoranthene 

### 0.00 0.000 0000 O.OOE+OO O.OOE+OO o OOE+OO Benzo(k)f1uoranthene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzoic Acid 

### 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(g,h,i)perylene 0.00 0.000 

### 0.000 O.OOE+OO O.OOE+OO o OOE+OO Benzo(a)pyrene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzyl Alcohol 

### 11000 46.58 55.715 2.91 E-09 2.25E-02 5.16E-05 bis (2-ChloroethyJ) ether 

### 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO bis (2-Ethylhexyl) phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Bromophenyl phenyl ether 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Butyl benzyl phthalate 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Carbazole 0.00 

### 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Chloroaniline 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Chloro-3-methylphenol 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Chloronaphthalene 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Chlorophenol 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Chlorophenyl phenyl ether 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Chrysene 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Dibenzo(a,h)anthracene 0.00 0.00 

### 0.000 o OOE+OO O.OOE+OO O.OOE+OO Dibenzofuran 0.00 

### 0.00 0.000 

# oOOE+OO O.OOE+OO O.OOE+OO Di-n-butyl phthalate 

### 0.00 0.00 0.000 

# oOOE+OO O.OOE+OO O.OOE+OO 1,2-Dichlorobenzene 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,3-Dichlorobenzene 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 1,4-Dichlorobenzene 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 3,3-Dichlorobenzidine 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 2,4-Dichlorophenol 0.00 

### 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Diethyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2,4-Dimethylphenol 

### 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Dimethyl phthalate 4.30 1.B2 2.178 1.14E-10 B.78E-04 2.02E-06 4,6-Dinitro-2-methylphenol 0.00 

### 000 0.000 O.OOE+OO O.OOE+OD O.OOE+OOClient Project No. Spruance Genco, LLC 3333

SSVOH Sample Analyte Mass (ug)
2.4-Dinitrophenol 0.00 2,4-Dimtrotoluene 0.00 2,6-Dimtrotoluene 0.00 Di-n-octyl phthalate 0 00 1.2-Diphenylhydrazine 0.00 Fluoranthene 0.00 Fluorene 0 00 Hexachlorobenzene 0.00 Hexachlorobutadiene 0.00 Hexachlorocyclopentadiene 0.00 Hexachloroethane 0.00 Indeno(1.2,3-c,d)pyrene 0.00 Isophorone 0.00 2-Methylnaphthalene 0.00 2-Methylphenol 0.00 3 & 4-Methylphenol 0.00 Naphthalene 0.00 2-Nitroaniline 0.00 3-Nilroaniline 000 4-Nilroaniline 0.00 Nitrobenzene 0.00 2-Nitrophenol 0.00 4-Nltrophenol 0.00 N-Nitrosodimethylamine 0 00 N-Nitrosodiphenylamine 0.00 N-Nitrosodi-n-propylamine 0.00 Pentachlorobenzene 0.00 Pentachloronitrobenzene 0.00 Pentachlorophenol 0.00 Phenanthrene 0.00 Phenol 0.00 2.2'-oxybis (1-Chloropropane) 0.00 pyrene 0.00 Pyridine 0.00 1,2,4-Triehlorobenzene 0.00 2,4,5-Tnehlorophenol 0.00 2,4,6-Trichlorophenol 000

Total SSVOHs 114.300 Test Location Test Run

Calculations (cont.)

Cone. (ug/dscm)

0.00 0.00 

### 0.00 0.00 0.00 

### 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 

### 0.00 0.00 0.00 0.00 0.00 0.00 0.00 

### 0.00 0.00 0.00 0.00 

### 0.00 0.00 0.00 0.00

0.620 Unit NO.1 Ooe

Conc.@corr. 02 Cone.

(ug/dscm) (Ib/dscf)

0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO

0.752 4.03E-11 Page4

Emission Rate Emission Rate (Ib/hr) (lb/MMBlu)

O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO OOOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO OOOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO OOOE+OO O.OOE+OO OOOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO

2.33E-02 5.36E-05Client Spruance Genco, LLC Test Location Unit No. Page 5 Project No. 3333 Test Run 

### 00.

Calculations (cont.)
9) PAH Concentrations and Emissions
C[PAH] = M[PAH](ug) 1Vmstd(dscm) C[PAH](lb/dscf) = C[PAH](ug/dscm) '* 1e-06g/ug" 2.20Se-03Ib/g" 0.02832 dscm/dscf E[PAH](lb/hr)

# = C[PAH](ug/dscm) '* QSld(dscmm) ,. (2.20SE-09)(lb/ug) ., 60(min/hr) E[PAH](lb/MMB1u)

# =**C[PAH](lb/dsc~** ,. Fd**~** (20.9/20.9-%02) C[PAH](@ corr. 02) = C[PAH] (ug/dscm) 

### '* [(20.9-correcled %02) I (20.9-actual %02)] Corrected 02 percentage IS: 

### 7.0 %


### PAH Sample Cone. Conc.@o;;Qrr. Q2 Conc. Emission**R~Ie:** Emission Rate Analvte Mass (ug) (ug/dscm) (ug/dsem) (Ib/dscf) (lb/hr) (lb/MMBtu)
Acenaph1hene 0.00180 

### 0.00 0001 4.76E-14 3.68E-07 8.44E-10 Acenapl11hylene 0.07300 

### 0.03 0037 1.93E-12 1.49E-05 3.42E-08 Anthracene 0.00210 

### 0.00 0001 5.5SE-14 4.29E-07 9.85E-l0 Benzo{a)an1hraeene 000280 0.001 0001 7.40E-14 5.72E-07 1.31 E-09 Benzo{b)fluoranlhene 0.00540 0.002 0003 1.43E-13 1.10E-06 2.53E-09 Benzo{k)fluoranthene 0.00270 0.001 0.001 714E-14 5.52E-07 1.27E-09 Benzo(g,h,i)perylene 0.01490 0.006 

## oOOB 3.94E-13 3.04E-06 6.99E-09 Benzo(a)pyrene 0.00510 0.002 0003 135E-13 1.04E-06 2.39E-09 Benzo(e)pyrene 0.00510 0.002 0.003 135E-13 1.04E-06 2.39E-09 Chrysene O.OOSBO 0.002 0.003 1.53E-13 1.1BE-06 2.72E-09 Dibenzo(a,h)an1hracene 

### 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Fluoranthene 0.05100 0.02 0.026 135E-12 1.04E-OS 2.39E-OB Fluorene 0.00800 0.00 0.004 212E-13 1.63E-06 3.7SE-09 Indeno(1,2,3-c,d)pyrene 0.00340 0.001 0.002 8.99E-14 6.9SE-07 1 59E-09 2-Me1hylnaphlhalene 

### 0.10300 0.04 0052 272E·12 2 10E-05 4.B3E-08 Naphthalene 1.24000 0.53 0.62B 3.28E-11 2 S3E-04 5.B2E-07 Perylene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Phenanthrene 0.11700 0.05 0.059 309E·12 239E-05 5.49E-OB Pyrene 001100 0.00 0.006 291E-13 225E-06 5.16E-09

Total PAHs 1.6521 0.037 0.044 2.30E·12 3.37E-04 7.75E-07

10) Isokinecity, I.



### % I = [100*Ts*(K3*Vlc+{«Vm"Y)fTm)*(Pb+(dH/13.6»)))] 1**(60*t~Ps*Vs*An)** % I

# = 91.613333-SSVOH-R2 

### AirNova, Inc.

Client Project No. Test Location Test Run Test Date TestTime

INPUT EPA Methods 1,2,3A,4and 0010 with SW-84S Method 82700 (Flows, 02/C02, H20, Speciated Semivolatile Organic HAPs and PAHs)

Vlc= Vm= Pstatic = Pb = Ps = Pstd = dP = dH = Tm = Ts = Tstd= On = An = y= t= Os = As = Cp = Kp = K1 = K2 = K3 = Fd

# =

[02] [C02]
[N2] Spruance Genco, LLC 3333 Unit No.1 

### Two 04/15/10 1440-1653

Emission Data

289.3 cc 80.586 dcf -0.50 in. H20 30.32 m. Hg 30.28 in. Hg 29.92 in. Hg 0.6960 in. H20 ".5

1.182 in H20 553.5 R 640.5 R 527.7 R 0.246 in 0.000330 sq. ft. 0.97

120 min. 10300 ft. 83.3204 sq. ft. 0.84 Vol. ofH20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge readmg Average meter temperature Average stack temperature Standard temperature Nozzle diameter Area ofnozzle orifice Meter calibration factor Duration of sampling lime Diameter ofstack Cross sectional area ofstack Pitot tube coefficient 85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R*inH20] Pitot tube constant 17.637 R/in Hg constant 0.047070 cu fIIml constant 0.0026688 in.Hg-cf/ml-R 9755 scf/MMBtu Instrumental Data

13.21 %·dry

6.39 %-dry

80.40 %-dry constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1)Volume ofgassampled atstandard conditions, Vmstd.

Vmsld =K1·

### Y·Vm • (Pb + dH/13.6)/ Tm Vmstd = 75.744 dscf 2.15 dscm Unit No. 

### Two

2) Volume ofwatervapor collected atstandard conditions, Vw(std).
Vw(std) = 

### K2

.. Vic Vw(std) = 13.617 sef
3) Decimal fraction of moisture byvolume in stack gas, Bws.

Bws = Vwstd / (Vmstd+Vwstd) Bws= 0.152
4) Molecularweight ofthe stack gas on a wet basis, Ms.

Ms = [«44*%C02)+ (32*%02) + (28*%N2»· (1-Bws) 

## 1 + (18*Bws) Ms = 27.79 Ib/lbmole
5) Average stack gas velocity, Vs.

Vs = Kp" Cp" (dP)

.. (Ts/Ps*Ms)".5 Vs= 43.60 fps
6) Average actual stack gas volumetric flowrate, Qa.

Oa = 60 sec/min"Vs

.. As Oa = 217980.8 cfm 6173.2 cmm 7) Average stack gas dry volumetricflowrate, Qstd.

Ostd = Oa" (TstdfTs)· (Ps/Pstd)" (1-Bws) Ostd = 154064.8 dscfm 4363.1 dsemm Page 2Client Spruance Genco, LlC Test location Unit No.1 Page 3 Project No. 3333 Test Run 

### Two

Calculations (cont.)
8) Speciated Semivolatile Organic HAPs

- Concentrations and Emissions
qSSVOH]

# = M[SSVOH](ug) IVmstd(dscm) qSSVOH)(lb/dscf) = qSSVOH)(ug/dscm);O 1e-06gfug·2.205e-03Ibfg;O 0.02832 dscmfdscf E[SSVOH](lb/hr) = qSSVOH)(ugfdscm)**~** Qstd(dscmm) * (2.205E-09)(lbfug) ·60(min/hr) E[SSVOH](lb/MMBtu) '" crSSVOH](lb/dscf) • Fd * (20 9/20.9-%02) crSSVOH)(@ corr. 02) = crSSVOH) (ug/dscm) 

### *[(20.9-corrected %02) I (20.9-actual %02) I Corrected 02 percentage is: 

### 7.0 %

SSVOH Samgle Conc. Ggn!;; @!;&!rr. Q2 Conc. Emission Rate Emission Rate Analyte Mass (ug) (ug/dscm) (ug/dscm) (lb/dscf) (lb/hr) (lb/MMBtu)
Acenaphthene 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Acenaphthylene 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Acetophenone 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Aniline 0.00 0.000 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Anthracene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzidine 

### 0.00 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(a)anthracene 0.00 0.000 

### 0000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(b)f1uoranthene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(k)f1uoranthene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzoic Acid 

### 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(g,h,i)perylene 0.00 0000 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(a)pyrene 0.00 

### 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzyl Alcohol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO bls (2-Chloroelhyl) ether 0.00 0.000 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO bis (2-Ethylhexyl) phthalate 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Bromophenyl phenyl ether 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Butyl benzyl phthalate 

### 0.00 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO Carbazole 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Chloroaniline 0.00 0.00 

### 0000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Chloro-3-melhylphenol 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Chloronaphthalene 

### 000 0.00 0.000**O.OOE~OO** O.OOE+OO 

# oOOE+OO 2-Chlorophenol 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Chlorophenyl phenyl ether 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Chrysene 0.00 0.00 0.000 O.OOE+OO o OOE

...OO o OOE+OO Dibenzo(a,h)anthracene 

### 0.00 0.00 0.000 O.OOE+OO 

# oOOE+OO O.OOE+OO Dibenzofuran 

### 0.00 0.00 0.000 O.OOE+OO 

# oOOE+OO O.OOE+OO Di-n·butyl phthalate 

### 0.00 0.00 0.000 O.OOE+OO o OOE+OO O.OOE+OO 1,2-Dichlorobenzene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,3-Dichlorobenzene 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,4-Dichlorobenzene 

### 000 0.00 0.000 O.OOE+OO o OOE+OO O.OOE+OO 3,3-Dichlorobenzidine 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2,4-Dichlorophenol 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Dielhyl phthalate 0.00 

### 0.00 0.000 O.OOE+OO O.OOE+OO o OOE+OO 2,4-Dimethylphenol 0.00 

### 0.00 0.000 O.OOE+OO O.OOE+OO o OOE+OO Dimethyl phthalate 0.00 

### 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4,6-Dinitro-2-methylphenol 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OOClient Project No. Spruance Genco, LLC 3333

SSVOH Analyte**2,4~Dmltrophenol 2,4~Dinitrotoluene** **2,6~Dinitrotoluene Di~n~oclyl**  phthalate 1**,2~Diphenylhydrazine** Fluoranthene Fluorene Hexaehlorobenzene Hexaehlorobutadiene Hexaehlorocyclopentadiene Hexachloroethane Indeno(1**,2,3~c,d)pyrene** Isophorone**2~Methylnaphthalene 2~Methylphenol**  3 

### &**4~MethylphenoJ** Naphthalene**2~Nitroaniline 3~Nitroaniline** **4~Nltroaniline** Nitrobenzene**2~NitrophenoJ 4~Nitrophenol** **N~Nitrosodimethylamine N~Nit(Qsodiphenylamine** **N~Nitrosodl·n~propylamine** Pentachlorobenzene Pentaehloronitrobenzene Pentachlorophenol Phenanthrene Phenol**2,2'~oxybis (1~Chloropropane)**  Pyrene Pyridine 1,2,4· Trichlorobenzene 2,4,5·Triehlorophenol**2,4,6~Triehlorophenol** Total SSVOHs Sample Mass (ug)



### 0.00 

### 000 0.00 0.00 0.00 0.00 0.00 0.00 

### 0.00 0.00 0.00 

### 000 0.00 0.00 0.00 

### 0.00 6.50 

### 0.00 0.00 0.00 0.00 0.00 0.00 

### 000 000 0.00 0.00 0.00 0.00 0.00 

### 0.00 0.00 0.00 0.00 0.00 0.00 

### 000

6.500 Test Location Test Run
Calculations (cont.)

Cone. (ug/dscm)



### 0.00 0.00 0.00 0.00 

### 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 

### 0.00 0.00 3.03 

### 0.00 0.00 0.00 0.00 

### 0.00 

### 0.00 0.00 0.00 0.00 0.00 0.00 0.00 

### 000 0.00 0.00 0.00 0.00 

### 0.00 0.00 0.00

0.039 Unit No.1 Two

CQnc.@corr. 02 Conc.

(ug/dsem) (Ib/dscf)



### 0.000 OOOE+OO 0.000 OOOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 5.477 1.89E·10 

### 0.000 O.OOE+OO 0000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0000 O.OOE+OO 0000 O.OOE+OO 0000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO

0.071 2.52E-12 Emission Rate {Ib/hrl



### O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 1.75E-03 

### O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO

1.75E-03 Page 4

Emission Rate

(lb/MMBtu)



### O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOHOO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 5.02E-06 

### O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO

5.02E-06Client Project No. Spruance Genco, LLC 3333

9) PAH Concentrations and Emissions Test Location Test Run

Calculations (cont.)

C[PAH] = M[PAH](ug) IVmstd{dscm) Unit No.1 Two

C[PAH](lb/dscf) = C[PAH](ug/dscm)" 1e-06g/ug"2.20Se-03Ib/g**~** 0.02832 dscm/dscf E[PAH](Ib/hr) = C[PAH]{ug/dscm)

.. Qstd(dscmm)

.. (2.20SE-09){lb/ug)" 60(min/hr) E[PAH](Ib/MMBtu) 

### =C[PAH](Ib/dscf)' Fd • (20.9120.9-%02) C[PAH](@ corr. 02) 

### =C[PAH] (ug/dscm) * [(20.9-corrected %02) I (20.9-actual %02)] Corrected 02 percentage IS: 

### 7.0 %

PAH Sample Conc. QQnc.@oorr. 02 Conc. Emission Rate Analyte Mass (ug) (ug/dscm) (ug/dscml (Ib/dscf) (Ib/hr)
Acenaphthene 0.02700 0.01 0.023 7.86E-13 727E·06 Acenaphthylene 0.03884 0.02 0.033 113E-12 1 OSE-OS Anthracene 0.00000 

### 0.00 0000 O.OOE+OO O.OOE+OO Benzo(a)anthracene 0.00000 0.000 

### 0000 O.OOE+OO O.OOE+OO Benzo(b)f1uoranthene 0.00330 0.002 0.003 9.61E-14 8 S8E-07 Benzo(k)f1uoranthene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO Benzo{g,h.i)perylene 0.00900 

### 0.004 0.008 2.62E-13 2.42E-06 Benzo{a)pyrene 000230 

### 0.001 0.002 6.70E-14 6.19E-07 Benzo(e)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO Chrysene 0.00091 0.000 0.001 2.65E-14 2.45E-07 Dibenzo(a,h)anthracene 0.00000 

### 0.000 0.000 O.OOE+OO O.OOE+OO Fluoranthene 0.02500 0.01 

### 0.021 7.28E-13 6.73E-06 Fluorene 0.01030 0.00 0.009 3.00E-13 2.77E-06 Indeno{1,2,3-c,d)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 2-Methylnaphthalene 0.97900 0.46 0.825 2.85E-11 263E-04 Naphthalene 10.17000 4.74 8.570 2.96E-10 2.74E-03 Perylene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO Phenanthrene 003400 0.02 0.029 9.90E-13 9.15E-06 Pyrene 0.00000 0.00 0.000 O.OOE+OO O.OOE+OO

Total PAHs 11.2997 0.277 0.501 1.73E-11 3.04E-03

10) Isokinecity, I.

%1= 103.43 Page 5

Emission Rate

(lb/MMBtul

2.08E-08 3.00E-08 O.OOE+OO
o OOE+OO 2.55E-09 O.OOE+OO 6.95E-09 1.78E-09
o OOE+OO 7.02E-10 O.OOE+OO 1.93E-08 7.9SE-09
o OOE+OO 7.56E-07 7.85E-06 O.OOE+OO 2.62E-08 O.OOE+OO

8.72E-063333-SSVOH-R3 

### AirNova, Inc.

Client Project No. Test Location Test Run Test Date Test Time

INPUT EPA Methods 1,2,3A,4 and 0010 with SW-B46 Method 82700 (Flows, 021C02, H20, Speciated Semivolatile Organic HAPs and PAHs)

Vlc= Vm= Pstatic = Pb= Ps = Pstd = dP = dH = Tm = Ts 

### = Tstd= On = An 

### = y= t= Os = As 

### = Cp 

### = Kp = K1 = K2= K3 

### = Fd =



### 1021
IC021
IN21 Spruance Genco, LLC 3333 Unit No.1 Three 04/15110 1812-2022

Emission Data

293.5 cc 84.794 dcf

-0.50 in. H20 30.24 in. H9 30.20 in. H9 29.92 in. H9 07058 in. H20 ".5

1.263 in. H2O 547.7 R 6425 R 527.7 R 0.246 in. 0.000330 sq. ft. 0.97

120 min. 10.300 ft. 83.3204 sq. ft. Vol. of H20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area of nozzle onfice Metercalibration factor Duration of sampling time Diameter ofstack Cross sectional area of stack 0.84 Pitottube coefficient 85.49**ft[(lb/lbmolt(inHg)]".5}/[s~R~InH201** Pitot tube constant 17.637 R/in.Hg constant 0.047070 cu.ftlml constant 0.0026688 in.Hg-c1lml-R 9868 sc1/MMBtu Instrumental Data

12.81 %-dry

6.86 %-dry

80.33 %-dry constant Fuel Factor

Oxygen concentration
Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions,Vmstd.

Vmstd =K1* 

### Y'" Vm " (Pb 

### +dH/13.6) JTm Vmstd = 80.340 dscf 2.28 dscm Unit No. Three

2) Volume ofwatervaporcollected atstandard conditions, Vw(std),
VW{Sld) = K2"Vic Vw{std) = 13.815 set
3) Decimal fraction of moisture byvolume in stackgas, Bws.

Bws = Vwstd I (Vmstd+Vwstd) Bws= 0.147
4) Molecularweight ofthe stack gason awet basis, Ms.

Ms = [«44"%C02)

### + (32*%02) + (28*%N2»"(1-Bws)] + (18*8ws) Ms= 27.91 Ib/lbmole
5) Average stackgas velocity, Vs.

Vs = Kp ." Cp'" (dP)'" (Ts/Ps*Ms)" 5 Vs = 44.25 fps
6) Average actual stackgas volumetricflowrate, Qa.
Qa = 60 sec/min"Vs

.. As Qa = 221218.1 cfm 6264.9 cmm 7) Average stackgas dryvolumetric flowrate, Ostd.
Qstd '" Qa'" (TstdfTs)· (PsJPstd)" (1-Bws) Qstd = 156492.1 dscfm 4431.9 dscmm Page 2Client Project No. Spruanee Genco, LLC 3333 Test Location Test Run

Calculations (cont.) Unit No.1 Three

8) Speciated Semivolatile Organic HAPs

- Concentrations and Emissions
qSSVOH]

# = M[SSVOH](ug)/ Vmstd{dscm) qSSVOH]{lb/dscf) = qSSVOH](ug/dscm) • 1e-06g/ug**~** 2.205e-03Ib/g ·0.02832 dsem/dscf E[SSVOH]{lbfhr) '" C[SSVOH]{ug/dscm) ;0 Qstd{dscmm);O (2.205E-09)(lb/ug) 

### *60{min/hr) E[SSVOH](lb/MMBtu) = qSSVOH](lb/dscf)· Fd * (20.9120 9-%02) qSSVOH](@ corr. 02) = qSSVOH] (ug/dsem) * [ (20 9-correcled %02)/ (20.9-actual %02)] Corrected 02 percentage is 7.0 %

SSVOH AnaMe
Acenaphthene Aeenaphthylene Acetophenone Anrline Anthracene Benzidine Benzo(a)anthracene Benzo(b)f1uoranthene Benzo(k)fluoranthene BenzOIc ACid Benzo{g,h,i)perylene Benzo(a)pyrene Benzyl Alcohol bis (2-Chloroelhyl) ether bis (2-Ethylhexyl) phthalate 4-Bromophenyl phenyl ether Butyl benzyl phthalate Carbazole 4-Chloroaniline 4-Chloro-3-methylphenol 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenyl phenyl ether Chrysene Dibenzo(a,h)anthraeene Dibenzofuran Di-n-butyl phthalate 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1A-Dichlorobenzene 3,3-Dichlorobenzidine 2,4-Dichlorophenol Diethyl phthalate 2.4-Dimethylphenol Dimethyl phthalate 4,6-Dinitro-2-methylphenol Sample Mass (ug)



### 000 0.00 

### 000 000 000 0.00 0.00 0.00 0.00 3800 0.00 0.00 0.00 0,00 0.00 0.00 0.00 0.00 0,00 

### 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0,00 

### 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 

### 0.00 Cone, (ug/dsem)

0.00 0.00 0.00 0.000 0.000 0000 0000 0000 

### 0000 16.702 0000 

### 0.00 0.00 0.000 0.00 0.00 0000 0.00 0.00 0.00 0.00 0.00 0.00 

### 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Conc.@corr. 02 Cone. (ug/dsem) (lb/dscf)

0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O,OOE+OO 28.696 1.04E-09 0.000 O,OOE+OO 0.000 O,OOE+OO 0.000 OOOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 OOOE+OO 0.000 O.OOE+OO 0.000 O,OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0,000 O.OOE+OO 0.000 O,OOE+OO 0.000 O,OOE+OO 0.000 O.OOE+OO 0,000 O.OOE+OO 0.000 OOOE+OO 0.000 OOOHOO 0.000 O.OOE+OO 0.000 O.OOE+OO Emission Rate (Iblhr)

O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.ODE+OO O.ODE+OO 979E-D3 O.ODE+OO O.OOE+OO O.OOE+OO
o OOE+OO
o ODE+DO O.OOE+OO O.OOE+OD O.OOE+OD D.DOE+OO D.OOE+OO O.ODE+OO O,OOE+OO O,OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OD
o OOE+OD O.OOE+OD O.OOE+OO D.DOE+OO D.OOE+OO O.OOE+OO O.ODE+OO O.ODE+OO**O.ODE~·OO** Page 3

Emission Rate

Clb/MMBtu)

O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 2.66E-05 O.OOE+OO O,OOE+OO O,OOE+OO O.OOHOO O.OOE+OO O.OOE+OO O.OOE+OO O,OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO
o OOE+OO
o OOE+OO O.OOE+OO O.OOE+OO O,OOE+OO O,OOE+OO O.OOE+OO O.OOE+OOClient Spruance Genco, LLC Test Location Unil No. Page 4 Project No. 3333 Test Run Three

Calculations (cont.)
SSVOH Sample Conc. Canc.@corr. 02 Conc. Emission Rate: Emission Rate Analyte Mass (ug) (uq/dscm) (uq/dscm) ([b/dscO (lb/hr) (lb/MMBlu)
2,4-0Inilrophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2,4-0InitroloJuene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2,6-0initrotoluene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Oi-n-octyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,2-Diphenylhydrazine 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Fluoranthene 

### 000 0.00 

### 0000 O.OOE+OO O.OOE+OO O.OOE+OO Fluorene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Hexachlorobenzene 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO Hexachlorobutadiene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Hexachlorocyclopentadiene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO o OOE+OO Hexachloroethane 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Indeno(1,2,3-c,d)pyrene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Jsophorone 0.00 0.00 0000 O.OOE+OO o OOE+OO O.OOE+OO 2-Methylnaphthalene 0.00 0.00 

### 0000 O.OOE+OO 

# oOOE+OO O.OOE+OO 2-Methylphenol 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 3 

### & 4-Methylphenol 0.00 

### 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Naphthalene 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Nitroaniline 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 3-Nitroaniline 

### 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Nitroaniline 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Nitrobenzene 

### 0.00 0.00 

### 0000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Nitrophenol 

### 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Nitrophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO N-Nitrosodimethylamine 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO N-Nitrosodiphenylamine 

### 0.00 000 0.000 O.OOE+OO o OOE+OO O.OOE+OO N-Nitrosodi-n-propylamine 

### 0.00 0.00 

### 0.000 O.OOE+OO o OOE+OO O.OOE+OO Pentachlorobenzene 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO Pentachloronilrobenzene 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO Pentachlorophenol 

### 0.00 0.00 

### 0000 O.OOE+OO O.OOE+OO o OOE+OO Phenanthrene 

### 0.00 0.00 0000 O.OOE+OO O.OOE+OO o OOE+OO Phenol 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO o OOE+OO 2,2'-oxybIS (1-Chloropropane) 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Pyrene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Pyridine 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,2,4-Trichlorobenzene 

### 000 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2,4,5-Trichlorophenol 

### 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO o OOE+OO 2,4,6-TrichlorophenoJ 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO

Total SSVOHs 38.000 0.214 0.373 1.39E-11 9.79E-03 2.66E-05Client Project No. Spruanee Genco, LLC 3333

9) PAH Concentrations and Emissions Test Location Test Run

Calculations (cont.)

C[PAH] = M[PAH](ug) I Vmstd(dscm) Unit No. Three

C[PAH](lb/dsef) = C[PAH](ug/dscm)· 1e-06g/ug '* 2.205e-03Ib/g**~** 0.02832 dscm/dsef E[PAH](Ib/hr) = C[PAH](ug/dscm)

.. Qstd(dscmm) " (2.205E-09)(lb/ug) * 60(min/hr) E[PAH](Ib/MMBtu) = C[PAH](lb/dscf) * Fd * (20.9/20_9-%02) C[PAH](@corr. 02) = C[PAH] (ug/dscm) * [(20.9-eorreeted %02) f(20.9-actual %02)

## 1 Corrected 02 percentage IS: 

### 7.0 %


### PAH Sample Cone. Conc.@corr Q2 Conc. Emission Rat!i! AnaMe Mass (ug) (uq/dscm) (ug/dscm) (lb/dscf) (Ib/hr)
Acenaphthene 0.00170 0.00 0.001 4.67E-14 43SE-07 Acenaphthylene 0.03548 0.02 0_027 9.74E-13 9 14E-06 Anthracene 000000 0.00 0.000 O.OOE+OO O.OOE+OO Benzo(a)anthracene 000000 

### 0.000 0.000 O.OOE+OO O.OOE+OO Benzo(b)f1uoranthene 

### 0.00000 0.000 0.000 O.OOHOO O.OOE+OO Benzo{k)f1uoranthene 0.00000 0_000 0.000 O.OOE+OO O.OOE+OO Benzo(g,h,i)perylene 0.00000 0000 0.000 O.OOE+OO O.OOE+OO 8enzo{a)pyrene 0.00660 0003 0.005 181E-13 1 70E-06 8enzo(e)pyrene 

### 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO Chrysene 0.00297 0.001 0.002 8.15E-14 7.65E-07 Dibenzo(a,h)anthracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO Fluoranthene 0_01BOO 0.Q1 0.014 494E-13 4.64E-OS Fluorene 000800 

### 0.00 0.006 2.20E-13 2.0BE-OS Indeno(1,2,3-c,d)pyrene 

### 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 2-Methylnaphthalene 0.07300 0.03 0.055 2.00E-12 1.B8E-05 Naphthalene 0.27400 0.12 0.207 7.52E·12 706E-05 Perylene 0.00000 

### 0.000 0.000 O.OOE+OO O.OOE+OO Phenanthrene 0.02400 0.01 0.Q18 6.59E-13 6.18E-06 Pyrene 0.00000 0.00 0.000 

## oOOE+OO O.OOE+OO

Total PAHs 0,4438 0.010 0018 6,41E-13 1.14E-04

10) Isokineclty, L



### % J= [100*Ts"(K3*Vlc+({(Vm"Y)fTm)*(Pb+(dH/13_S»)))] I (60*t*Ps'*Vs*An) %1= 10800 Page 5

Emission Rate

(lb/MMBtu)

1.19E-09 2,4SE-08 O_OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 4.62E-09 O.OOE+OO 2.0BE-09 O.OOE+OO 1.26E-OB 5.S0E-09 O.OOE+OO 5.11E-08 1.92E-07 O.OOE+OO 1.68E-08 O.OOE+OO

3.10E-073333-VQST-R1

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT INPUT Vm= Pstatic = Pb 

### = Ps= Pstd 

### = Tm= INPUT Ts = INPUT Tstd= INPUT Y = INPUT t = INPUT Ds = As = Kp = K1 = K2 = K3= INPUT Fd =

INPUT [02[

INPUT [C02[
[N2[ 

### AirNova, Inc. EPA Method 1, 2, 3A and 0031JSW-846 Method 82608 (Flows, 021C02, and Speciated Volatile Organic HAPs)
Spruance Genco, LLC 3333 Unit No.1 

### Ooe 04/15/10 1130-1330

Emission Data

1.016 dct -0.50 in. H2O 30.39 in. H9 30.35 in. H9 29.92 in. H9 544.6 R 668.4 R 527.7 R 1,000 90 min. 10,300 ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stacktemperature Standard temperature Meter calibration factor Duration ofsampling time DiameterofStack 83.3204 sq. ft. Cross sectional area ofslack 85.49 ft[(lb/lbmoIY"(inHg)]".5}/[s*R*inH20] 17.637 R/in.Hg constant 0.047070 CU.ft/ml constant 0.0026688 in.Hg-cf/ml-R constant 9862 scf/MMBtu Fuel Factor

Instrumental Data

9.28 %-dry Oxygen concentration

10.01 %-dry Carbon Dioxide concentration

80.71 %-dry Nitrogen concentrationClient Project No. Spruance Genco, 

### llC 3333 Test Location Test Run
Calculations 1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1'* Y '* Vm

- PbfTm Vmstd = 1.000 dsef 0.0283 dsem 3) Decimal fraction ofmoisture by volume in stack gas, Bws.

INPUT Bws = Bws = Based on the SSVOH sampling train 0.1430 4) Molecularweightofthe stack gas on awet basis, Ms. Unit No. One

Ms = [«44*%C02) + (32*%02) + (28*%N2))" (1-Bws) 

### I+(18*Bws) Ms= 28.261 Ibf Ibmole 5) Average stack gas velocity, Vs.

INPUT Vs = Vs = Based on the SSVOH sampling train 37.230 fps 6) Average actual stack gasvolumetric flowrate, Qa.
Qa = 60 sec/min *Vs .,As Qa = 186121.18 cfm 5270.95 cmm 7) Average stack gas dryvolumetric f1owrate, Qstd.
Qstd = Qa ., (TstdfTs) * (PsfPstd) • (1-Bws) Qstd = 127752.88 dscfm 3617.96 dscmm Page 2Client Spruance Genco, LLC Test Location Unit No.1 Page 3 Project No. 3333 Test Run Ooe

Calculations (cant.) 8) Speciated Volatile Organic HAPs

- Concentrations and Emission Rates C[SVOH] = M(SVOH] lug) IVmstd (dscm) C[SVOH]{lb/dscf) = C(SVOH]{ug/dscm) * 1e-06g/ug"2,205e-03Ib/g • 0.02832 dscm/dscf E(SVOH](lb/hr) = C(SVOH] (ug/dscm) • (2.20SE-09) (Ib/ug) * Qstd (dscmm) *60 (min/hr) E[SVOH](lb/MMBtu) = C(SVOH](Ib/dscf) • Fd * (20.9/20.9-%02) CjSVOH](@carr. 02) = C[SVOH[ (ug/dscm) * [ (20.9-corrected %02) I (20,S-actual %02)] Corrected 02 percentage is: 7.0 

### %
Cone. Conc.@corr. 02 Cone. Emission Rate Emission Rate Compound {ug/dseml (ug/dsem) (lb/dscfl (lb/hrl (lb/MMBtu)

Acetone 1177,924 1409.048 7.36E-08 5,64E-01 1.30SE-03 Benzene 1.377 1,647 B.60E-11 6,S9E-04 1.S2SE-06 Bromobenzene 0.177 0.211 1.10E-11 B,4SE-OS 1.956E-07 Bromochloromethane 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO Bromodichloromethane 0.000 0.000 O.OOE+OO O.OQE+OO O,OOOE+OO Bromoform 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Bromomethane 3.083 3.688 1.93E-10 1,48E-03 3,415E-06 2-Butanone 3.767 4.506 2.3SE-10 i.80E-03 4,172E-06 n-Butylbenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO sec-Butylbenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO tert-Butylbenzene 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Carbon Disulfide 0.1S2 0.182 9,48E-12 7.27E-05 1.682E-07 Carbon Tetrachloride 0.530 0.634 3.31 E-11 2.54E-04 S.867E-07 Chlorobenzene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO Chlorodibromomethane 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO Chloroethane 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO Chloroform 0,473 0.566 2.95E-11 2,26E-04 5.241 E-07 Chloromethane 9,768 11.684 6.10E-10 4.68E-03 1.082E-05 2-Chlorotoluene 0.000 0000 O.OOE+OO O,OOE+OO O.OOOE+OO 4-Chlorotoluene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 1,2-Dibromo-3-chloropropane 0000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dibromoethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Dibromomethane 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO i,3-Dichlorobenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 1A·Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Dichlorodifluoromethane 4.121 4.930 2.57E-10 1.97E-03 4.565E-06 1,1-Dichloroethane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichloroethane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO cis-1,2-Dichloroethene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO trans-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1-Dichloroethene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,3-Dichloropropane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 2,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO cis-i,3-Dichloropropene 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO trans-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OOClient Spruance Genco, LLC Test Location Unit No. Page 4 ProjectNo. 3333 Test Run 

### Doe

Calculations (cont.)

Conc. Qonc.@oorr. 02 Conc. Emission Rate Emission Rate Compound (uq/dscm) (uq/dscm) (lb/dscO (lb/hr) (lb/MMBtu)
1,1-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Ethylbenzene 0.042 0.051 2.65E-12 2.03E-05 4.694E-OB Hexachlorobutadiene 

### 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 2-Hexanone 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO Isopropylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO p-Isopropyltoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Methylene Chloride 122.560 146.607 7.65E-09 5.B7E-02 1.358E-04 4-Methyl-2-Pentanone 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO Naphthalene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO n-Propylbenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO Styrene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 1,1,1,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 1,1,2,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Tetrachloroethene 0.258 0.308 1.61E-11 1.23E-04 2.855E-07 Toluene 19.240 23.015 1.20E-09 9.21E-03 2.131E-05 1,2,3-Trichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2,4-Trichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1,1-Trichloroethane 0.049 0,059 3.09E-12 2.37E-OS 5,476E-08 1,1,2-Trichloroethane 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO Trichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Trichlorofluoromethane 85.874 102,724 5.36E-09 4.11E-02 9.512E-05 1,2,3-Trichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2,4-Trimethylbenzene 0.120 0.144 7.50E-12 5.75E-05 1.330E-07 1,3,5-Trimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Vinyl Chloride 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO m-Xylene & p-Xylene 0.088 0.106 5.51E-12 4.23E-05 9.779E-OB o-Xylene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO

Total 21.661 24.784 1.31E-09 6.B4E-01 1.5B4E-03**3333~VOST-R2**

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT INPUT

INPUT INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT Vm= Pstatic = Pb= Ps= Pstd = Tm= Ts= Tstd= y= t= Ds= As= Kp = K1 = K2= K3= Fd =

[021
[C021
[N21 

### AirNova, Inc. EPA Method 1, 2, 3A and 00311SW·846 Method 82608 (Flows, 02fC02, and Speclated Volatile Organic HAPs)
Spruance Genco, LLG 3333 Unit NO.1 

### Two 04/15f10 1450-1650

Emission Data

1.337 

### dcf -0.50 in, H20 30.31 in. Hg 30.27 in. Hg 29.92 in. Hg 553.9 R 640.5 R 527.7 R 1.000 90 min. 10.300 ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stack temperature Standard temperature Metercalibration factor Duration ofsampling time DiameterofStack 83.3204 sq. ft. Cross sectional area ofstack 85.49**ft[(lbllbmol)"(inHg)1".5}/[s~R*inH201** 17.637 Rlin.Hg constant 0.047070 cu.ftlml constant 0.0026688 in.Hg-cffml-R 9755 scffMMBtu

Instrumental Data

13.21 %-dry

6.39 %-dry


### 80AO %-dry constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 

### 3333 TestLocation Test Run
Calculations 1)Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd**t::K1~** 

### Y"Vm * Pbl Tm Vmstd = 1,290 dscf 0.0365 dscm
3) Decimal fraction ofmoisture byvolume In stack gas, Bws.

INPUT Bws= Bws= Based on the SSVOH sampling train 0,1520
4) Molecularweightofthe stackgas on awet basis, Ms. Unit No. Two

Ms =**[«44~%C02)** +**(32~%02)** +**(28~OloN2))** * (1-Bws) 

## 1 + (18*8ws) Ms= 27.795 Ib/lbmole
5) Average stack gas velocity, Vs.

INPUT Vs = Vs= Based on the SSVOH sampling train 42.970 fps G) Average actual stack gasvolumetricflowrate, Qa.
Oa =60 sec/min *Vs * As Oa = 214816.74 cfm 6083.61 cmm 7) Average stack gas dryvolumetricflowrate, Qstd.
Qstd = Oa * (TstdfTs) * (Ps/Pstd)" (1-Bws) Qstd = 151855.03 dscfm 4300.63 dscmm Page 2Client Spruance Genco, LLC Test Location Unit No.1 Page 3 Project No. 3333 TestRun 

### Two

Calculations (cont.)
8) Specialed Volatile Organic HAPs - Concentrations and Emission Rates C[SVOH] = M[SVOH] (ug) IVmstd (dscm) C[SVOH](lb/dscf) =C[SVOH](ugfdscm)**~** 1e-06g/ug·2.205e-03Ibfg * 0.02832 dscm/dscf E[SVOH](lblhr) = C[SVOH] (ugfdscm)**~** (2,205E-09) (Ib/ug) * Qstd (dscmm)· 60 (min/hr) E[SVOHj(lb/MMBtu) = C[SVOHj(lb/dscf) * Fd '" (20.9/20.9-%02) C[SVOH](@ cerro 02) = C[SVOH] (ugfdscm) * [(20.9-corrected %02) f(20.9-actual %02)] Corrected 02 percentage is: 

### 7.0 %
Conc. Conc.@corr. 02 Cone. Emission Rate Emission Rate Compound (ug/dscm) (ug/dscm) (lb/dscO (lb/hr) (lb/MMBtu)

Acetone 501.965 907.323 3.13E-08 2.86E-01 8.310E-04 Benzene 3.557 6.430 2.22E-10 2.02E-03 5.890E-06 Bromobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Bromochloromethane 0.255 0.462 1.59E-11 1.45E-04 4.228E-07 Bromodichloromethane 0.000 0.000 O.OOE+OO**O,OOE~'OO** O.OOOE+OO Bromoform 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO Bromomethane 1.792 3.240 1.12E-10 1.02E-03 2_967E-06 2-Butanone 4.652 8.409 2.90E-10 2.65E-03 7.702E-06 n-Butylbenzene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO sec-Butylbenzene 0,000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO tert-Butylbenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO Carbon Disulfide 2.619 4.734 1.64E-10 1.49E-03 4.336E-06 Carbon Tetrachloride 0.520 0.940 3.25E-11 2.96E-04 8,BOBE-07 Chlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Chlorodibromomethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Chloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Chloroform 0.354 0.640 2,21E-11 2.01E-04 5.S59E-07 Chloromethane 9.293 16.798 5.80E-10 5.29E-03 1.539E-05 2-Chlorotoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 4-Chlorotoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dibromo-3-chloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OO 1,2-Dibromoethane 0.000 

### 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO Dibromomethane 0.000 0,000 O_OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichlorobenzene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,3-Dichlorobenzene 0,000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 1.4-Dichlorobenzene 0,000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO Dichlorodifluoromethane 3.295 5,955 2.06E-10 1.87E-03 5.455E-06 1,1-Dichloroethane 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichloroethane 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO cis-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO trans-1 ,2-Dichloroethene 0.000 0_000 O.OOE+OO O,OOE+OO O.OOOE+OO 1,1-Dichloroethene 0.000 0.000 O.OOE+OO O,OOE+OO O_OOOE+OO 1,2-Dichloropropane 0.000 0,000 O.OOE+OO O.OOE+OO O_OOOE+OO 1,3-Dichloropropane 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 2,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO cis-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO trans-1 ,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OOClient Spruance Genco, LLC Test Location Unit No.1 Page 4 Project No. 3333 Test Run Two

calculations (cont.)

Conc. QonQ.@!<QIT Q2 Conc. Emission 

### Bate Emission Rate: Compound (ugfdscml (ug/dscm) (lb/dscO (lb/hr) (lb/MMBtu) 1,1-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Ethylbenzene 0.077 0.138 4.78E·12 4.36E-05 1.269E-07 Hexachlorobutadiene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 2-Hexanone 0.602 1.088 3.76E-11 3.43E-04 9.967E-07 Isopropylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO p-Isopropyltoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Methylene Chloride 118.518 214.226 7.40E-oe 6.74E-02 1.962E-04 4-Methyl-2-Pentanone 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Naphthalene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO n-Propylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Styrene 0.038 0.069 2.39E-12 2.i8E-05 6.343E-08 1,1,1,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1,2,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Tetrachloroethene 0.115 0208 7.18E-12 6.54E-05 1.e03E-07 Toluene 2.268 4.099 1.42E-10 1.29E-03 3.754E-06 1,2,3-Trichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2,4-Trichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1,i-Trichloroethane 0.030 0.054 1.88E-12 1.7iE-05 4.984E-08 1,1,2-Trichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Trichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Trichlorofluoromethane 6.825 12.336 4.26E-10 3.88E-03 1.130E-05 1,2,3-Trichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2,4-Trimethylbenzene 0.109 0.198 6.84E-12 6.23E-05 1.8i2E-07 1,3,5-Trimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO o OOOE+OO Vinyl Chloride 0.000 

### 0000 O.OOE+OO O.OOE+OO O.OOOE+OO m-Xylene 

### & p-Xylene 0.167 0.302 1.04E-11 9.50E-05 2.764E-07 o-Xylene 0.036 0.064 2.22E-12 2.02E-05 5.890E-08
Total 9.956 17.213 B.03E-10 374E-01 i.088E-033333-VOST-R3

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT INPUT Vm= Pstatic = Pb = Ps = Pstd = Tm= INPUT Ts = INPUT Tstd= INPUT Y= INPUT t= INPUT

INPUT

INPUT

INPUT Ds = As 

### = Kp = K1 = K2= K3= Fd =

[02[ [C02[
[N2[ 

### AirNova, Inc. EPA Method 1, 2, 3Aand 

### 0031/SW-846 Method 8260B (Flows, 02fC02, and Speciated Volatile Organic HAPs)
Spruance Genco, LLC 3333 Unit No.1 Three 04/15/10 1812-2012

Emission Data

0.922 def -0.50 in. H2O 30.24 in. Hg 30.20 in. Hg 29.92 in. Hg 543.0 

### R 642.5 R 527.7 R 1.000 90 min. 10.300 ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stacktemperature Standard temperature Meter calibration factor Duration ofsampling time Diameterof Stack 83.3204 sq. ft. Cross sectional area ofstack 85.49 ft[(lbflbmolt(inHg»)1I.5}/[s*WinH20] 17.637 Rfin.Hg constant 0.047070 cu fUml constant 0.0026688 in.Hg·cffml-R 9868 scf/MMBtu

Instrumental Data

12.81 %-dry

6.86 %·dry

80.33 %-dry constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 

### 3333 TestLocation Test Run

Calculations
1)Volume ofgas sampled atstandard conditions, Vmstd.

Vmsld =K1* Y*Vm * PbfTm Vmstd = 0.906 dscf 0.0256 dscm
3) Decimal fraction of moisture by volume in stack gas, Bws.

INPUT Bws = Bws = Based on the SSVOH sampling train 0.1470 4) Molecularweight ofthe stack gas on awet basis, Ms. Unit No.1 Three

Ms = [«44*%C02) + (32*%02) + (28*%N2»·(1-Bws) 

## 1 + (18*Bws) Ms = 27,903 Ib! Ibmole 5) Average stack gas velocity, Vs.

INPUT Vs= Vs= Based on the SSVOH sampling train 43.650 fps 6) Average actual stack gas volumetricflowrate, Ca.
Qa = 60 sec/min"Vs *As Qa = 218216.22 cfm 6179,88 cmm 7) Average stack gas dry volumetricflowrate, Qstd.
Qstd = Qa" (TstdfTs)" (Ps!Pstd) " (1-Bws) Qstd = 154326.99 dscfm 4370.54 dscmm Page 2Client Spruance Genco, LLC Test Location Unit NO.1 Page 3 Project No. 3333 Test Run Three

Calculations (cont.) 8) Speciated Volatile Organic HAPs

- Concentrations and Emission Rates C[SVOHj = M!SVOH] (ug) IVmstd (dscm) C[SVOH](lb/dscf) = C[SVOH](ug/dscm) * 1e-06g/ug·2.20Se-03Ib/g * 0,02832 dscm/dscf E[SVOH)(lb/hr) = C[SVOH] (ug/dscm) * (2.20SE-09) (lb/ug)**~** Qstd (dscmm) * 60 (min/hr) E[SVOH)(lb/MMBtu) = C[SVOH](lb/dscf} * Fd**~** (20.9/20.9-%02) C[SVOH](@ corr. 02) = C[SVOH] (ug/dscm) * [(20.9-corrected %02) I (20.9-actual %02)] Corrected 02 percentage is: 7.0 %
Conc. Conc.@corr. 02 Conc. Emission Rate Emission Rate Compound (ug/dscm) (ug/dscm) (lb/dscO (lb/hr) (lb/MMBtu)

Acetone 540.160 928,088 3_37E-08 3.12E-01 8,599E-04 Benzene 78.577 135.008 4_91 E-09 4.S4E-02 1.2S1E-04 Bromobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Bromochloromethane 0.247 0.424 1,S4E-11 1.43E-04 3.931E-07 Bromodichloromethane 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Bromoform 0,000 0.000 O_OOE+OO O.OOE+OO O.OOOE+OO Bromomethane 11.736 20.16S 7.33E-i0 6.79E-03 i.868E-OS 2-Butanone 9.748 16.748 6.09E-10 S,64E-03 1.SS2E-OS n-Butylbenzene 0.000 0,000 O,OOE+OO O.OOE+OO O.OOOE+OO sec-Bulylbenzene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO tert-Bulylbenzene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO Carbon Disulfide 153.638 263.976 9.S9E-09 8.88E-02 2.446E-04 Carbon Tetrachloride 

### 00409 0_703 2.S6E-11 2,37E-04 6.518E-07 Chlorobenzene 0,000 0_000 O.OOE+OO O,OOE+OO O,OOOE+OO Chlorodibromomethane 0,000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO Chloroethane 0,000 0,000 O.OOE+OO O,OOE+OO O.OOOE+OO Chloroform 0_675 1.159 4_21E-11 3.90E-04 1.074E-06 Chloromethane 39.264 67.463 24SE-09 2.27E-02 6.251 E-05 2-Chlorotoluene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 4-Chlorotoluene 0.000 0.000 O.OOE+OO O_OOE+OO O.OOOE+OO 1,2-Dibromo-3-chloropropane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dibromoethane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO Dibromomethane 0.000 0.000 o OOE+OO O_OOE+OO O.OOOE+OO 1,2-Dichlorobenzene 0.000 0.000 o OOE+OO O.OOE+OO O.OOOE+OO 1,3-Dichlorobenzene 0,000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,4-Dichlorobenzene 0,000 0,000 O,OOE+OO O.OOE+OO O.OOOE+OO Dichlorodifluoromethane 4.429 7,610 2.77E-10 2.S6E-03 7.051 E-06 1,1-Dichloroethane 0.000 0_000 O,OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO cis-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO trans-1,2-Dichloroethene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 1,1-Dichloroethene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichloropropane 0.000 0.000 O,OOE+OO O.OOE+OO O,OOOE"'OO 1,3·Dichloropropane 0,000 0,000 O.OOE+OO O.OOE+OO O.OOOE"'OO 2,2-Dichloropropane 0,000 0,000 O.OOE+OO O,OOE+OO O.OOOE"'OO cis-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO trans-1 ,3-Dichloropropene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OOClient Spruance Genco, LLC Test Location Unit No.1 Page 4 Project No. 3333 Test Run Three

Calculations (cant.)

Conc. Conc.@corr. og Cone. Emission Rate Emission Rate: Compound (ug/dseml (ug/dscml (lb/dscO (Ib/hr) (lbfMMBtu)
1,1-Dichloropropene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO Ethylbenzene 0.113 0.194 7.06E-12 6.54E-05 1.BOOE-07 Hexaehlorobutadiene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 2-Hexanone 1.131 1.943 7_06E-11 6.54E-04 1.BOOE-06 Isopropylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO p-Isopropyltoluene 0.000 0.000 O.OOE+OO O,OOE+OO O,OOOE+OO Methylene Chloride 147.647 2S3,683 9.22E-09 8.S4E-02 2.3S0E-04 4-Methyl-2-Pentanone 0.000 0,000 O.OOE+OO O,OOE+OO O,OOOE+OO Naphthalene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO n-Propyibenzene 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Styrene 0.152 0.261 9.S0E-12 8,79E-OS 2.421E-07 1,1,1,2-Tetrachloroethane 0.000 0.000 o OOE+OO O.OOE+OO O.OOOE+OO 1,1,2,2-Tetraehloroethane 0.000 0.000 O_OOE+OO O.OOE+OO O.OOOE+OO Tetraehloroethene 0.160 0.275 9.98E-12 9.24E-OS 2.S45E-07 Toluene 4.358 7.488 2.72E-10 2,52E-03 6.938E-06 1,2,3-Trichlorobenzene 0.000 0,000 O.OOE+OO O,OOE+OO O.OOOE+OO 1,2,4-Trichlorobenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 1,1,1-Trichloroethane 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1,2-Trichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Trichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Trichlorofluoromethane 3.611 6.204 225E-10 2.09E-03 5.748E-06 1,2,3-Triehloropropane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 1,2,4-Trimethylbenzene 0.000 0_000 O.OOE·OO O.OOE·OO O.OOOE+OO 1,3,5-Trimethylbenzene 0.000 0_000 O.OOE+OO O.OOE·OO O.OOOE·OO Vinyl Chloride 0_000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO m-Xylene & p-Xylene 0.285 0.489 1.78E-11 1.65E-04 4.S31E-07 a-Xylene 0.078 0.134 4,87E-12 4.S1E-OS 1.241E-07

Total 15.097 24.812 9,15E-10 5.76E-01 1.586E-03

### Unit No 2

## Spruance Genco, LLC Richmond, Virginia Project No, 3333 April 22, 2010 Unit No.2 Run No.1 Coal Analysis for F FactorCalculation

F FACTOR CALCULATION

INPUT 

### % 

### H= 

## 4.67 Hydrogen Content (%) INPUT 

### %c= 

## 70.81 Carbon Content (%) INPUT 

### % 

### N= 

## 1.39 Nitrogen Content (%) INPUT 

### %0= 

## 551 Oxygen Content (%) INPUT 

### %8= 

## 0.83 Sulfur Content (%) INPUT GCV= 

## 12563 Gross Calorific Value (Btu/lb)

Fd

# =10"6 * 

### [(3.64*%H) 

### + (1.53*%C) 

### + (0.57*%8) 

### + (O.14*%N)

- 

### (0.46·%02)]/ GCV 

### Fd = 

### 9828 scf/MMBtu

## Spruance Genco, LLC Richmond, Virginia 

## Project No. 3333 April 22, 2010 Unit No.2 Run No.2 Coal Analysis for F Factor Calculation

F FACTOR CALCULATION

INPUT 

### %H= 

## 4.99 Hydrogen Content (%) 

### INPUT 

### %c= 

## 76.57 Carbon Content (%) 

### INPUT % 

### N= 

## 1.54 Nitrogen Content (%) 

### INPUT %0= 

## 6.47 Oxygen Content 

### (%) 

### INPUT 

### %s= 

## 0.88 SulfurContent 

### (%) INPUT GCV= 

## 13751 Gross CalorificValue (Btu/lb)



### Fd = 10'6 ' [(3.64'%H) + 

### (1.53'%C) + 

### (0.57'%8) + 

### (0.14'%N)

- (0.46'%02)11 GCV Fd

# = 9676 scflMMBtu

### Spruance Genco, LLC Richmond, Virginia 

## Project No. 3333 April 23, 2010 Unit No.2 Run No.3 Coal Analysis for F FactorCalculation

F FACTOR CALCULATION

INPUT %H= 

## 4.95 Hydrogen Content (%) INPUT %C= 

## 74.35 Carbon Content (%) INPUT % 

### N= 

## 1.48 Nitrogen Content (%) INPUT %0= 

## 5.61 Oxygen Content (%) INPUT %5= 

## 0.89 Sulfur Content (%) INPUT GCV= 

## 13221 Gross CalorificValue (Btu/lb)

Fd = 10A

### 6 >[(3.64>%H) + (1.S3>%C) + (o.sr%S) + (0.14>%N)

- (0.46>%02)11 GCV Fd

# = 9826 scf/MMBtu3333·7E

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit No.2·Acid Gases 04/20/10

Parameter: 

### Oxygen Instrument Span (% 

### 02): 21.96

ActualCalibration Gas Value (% 02): AnalvzerCalibration Response (% 02): Ana/'i.zerCalibration Error(% Span):

Zero**S~stem** Calibration Gas Apparent Init. S'i.s. Init. SI@. Final S)@. Fina/,s)@.

Stack QgJjQ, Cal. Bias Calib. Cal. Bias Run Conc. Response (% span) Response (% span)



### 4.06 0.02 0.00 0.00 

### -0.09 2 4.30 0.00 -0.09 

### 001 -005 

### 0 0.00 0.01 -0.05 0.00 -0.09 

### 0 0.00 0.00 -0.09 0.00 -0.09 

### 0 0.00 0.00 -0.09 0.00 

### -0.09 0 

### 0.00 0.00 -0.09 0.00 -0.09 

### 0 0.00 0.00 -0.09 0.00 -0.09 

### 0 0.00 0.00 

### -0.09 0.00 -0.09 

### 0 0.00 0.00 -009 0.00 -0.09 

### 0 0.00 0.00 -0.09 0.00 -0.09 0 

### 0.00 0.00 -0.09 0.00 -0.09 

### 0 0.00 0.00 -0.09 

### 000 -0.09 

### AirNova, Inc. EPA Method 7E Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Anal'i.zerCali!J.. Gases UQ.scale 

### zero low mid high**,s'i.~.** Cal. Gas 

### 0.00 NIA 12.46 21.96 12.46 0.02 

### NIA 12.46 21.92 12.46 0.09 0.00 0.00 ·0.18

URscale**S~stem** Calibration Gas**~** Init. SJ,':s, Init. S'i.s. Final S'i.s. FinalSJ,':s. Calib. Actual Drift Galib. Cal. Bias Calib. Cal. Bias. Drift Stack (% span) Response (% span) Response (% span) (% span) Cone.



### -0.09 12.38 -0.36 12.37 -0.41 -0.05 4.08 

### 005 12.37 -0.41 12.33 -0.59 -0.18 4.34 -0.05 12.33 -0.59 0.00 -5674 -56 15 -0.01 0.00 0.00 -56.74 0.00 -56.74 0.00 

### ERR 0.00 

### 0.00 -56.74 0.00 -56.74 0.00 

### ERR 0.00 0.00 -56.74 0.00 -56.74 0.00 

### ERR 0.00 0.00 -56.74 0.00 -56.74 0.00 

### ERR 0.00 0.00 -56.74 0.00 -56.74 0.00 

### ERR 0.00 0.00 -56.74 0.00 -56.74 0.00 

### ERR 0.00 0.00 -56.74 0.00 -56.74 0.00 

### ERR 0.00 0.00 -56.74 0.00 -56.74 0.00 

### ERR 0.00 0.00 -56.74 0.00 -56.74 0.00 

### ERR

### 3333-7E

Client Project No. Test Location Test Date Spruance 

### Genco, llC 3333 Unit No.2

- Acid 

### Gases 04/20/10

Parameter: 

### Carbon Dioxide InstrumenfSpan (% C02): 17.83

Actual Cali!J.ration GaS Value (% C02)' AnalyzerCalibration Response (% C02): AnalyzerCalibration Error(% SQan):

Zero**S~stem** Calibr§jtion Gas Ag,Qarent Init. S"t.s. Init. S"t.,s:. Final S"t.s. Final S"t,s.

Stack Ga/ib. 

### Cal Bias Gafib. Cal. Bias 

### Run Cone. Resgonse (% s,Qan) Res,Qonse (% sPBn)



### 1 14.49 0.11 1.01 0.23 1.68 2 14.11 0.23 1.68 0.21 

### 157 0 

### 0.00 0.21 1.57 0.00 0.39 0 

### 0.00 0.00 0.39 0.00 0.39 0 

### 0.00 0.00 0.39 0.00 0.39 0 

### 0.00 0.00 0.39 0.00 0.39 0 

### 0.00 0.00 0.39 0.00 0.39 0 

### 0.00 0.00 0.39 0.00 0.39 0 

### 0.00 0.00 0.39 0.00 0.39 0 

### 0.00 0.00 0.39 0.00 0.39 0 

### 0.00 0.00 0.39 0.00 0.39 0 

### 0.00 000 

### 0.39 0.00 039 

### AirNova, Inc. EPA Method 6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

Anal"t,zerCali!J.. Gases UQscale 

### ,ero low mid high S"t.s. Cal. Gas 

### 0.00 N/A 

### 12.39 17.83 12.39 -0.07 N/A 

### 12.41 17.89 12.41 -0.39 0.00 0.11 0.34

U(:!scale**S~stem** Qalibration Gas**~** Init. S!!s. Init. S"t.s. Final S):::s. Final S!!S Galib. Actual Drift Calib. Cal. Bias Cali!J.. Cal. Bias Drift Stack f% s,QanJ Res,Qonse (% wan) Resgonse (% sgan) (% s,Qan) Cone.



### 0.67 12.38 -0.17 12.31 -0.56 -0.39 14.57 -0.11 12.31 -0.56 12.32 -0.50 0.06 14.23 -1.18 12.32 -0.50 0.00 -69.60 -69.10 -0.21 0.00 0.00 -69.60 0.00 -69.60 0.00 

### ERR 0.00 0.00 -6960 0.00 -69.60 0.00 

### ERR 0.00 0.00 -69.60 0.00 -69.60 0.00 

### ERR 0.00 0.00 -69.60 000 

### -69.60 0.00 

### ERR 0.00 0.00 -69.60 0.00 -69.60 0.00 

### ERR 0.00 0.00 -69.60 0.00 -69.60 0.00 

### ERR 0.00 0.00 -69.60 0.00 -69.60 0.00 

### ERR 0.00 0.00 -69.60 0.00 -69.60 0.00 

### ERR 000 

### 0.00 -69.60 0.00 -6960 0.00 

### ERR

### 3333·7E

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit No.2·Acid Gases 04/20110

Parameter: 

### Nitrogen Oxides (as N02) Instrument Span (ppmVNOx): 

### 232.6

Actual Calibration Gas Value (ppmVNOx): AnalvzerCalibration Response (ppmVNOx): AnalYZerCalibration Error(% Span);

Zero**S~stem** Calibr!ltion Gas APl2amn

### t Init. 5\::s. Init.**S~s.** FinalS\::s. Final**S~s.**

Stack Calib Cal. Bias Ca/ib. Cal. Bias 

### Run Conc. Response (% span) Response f% span)



### 198.7 0.0 -0.52 00 -0.52 

### 2 198.0 0.0 -0.52 0.0 -0.52 0 0.0 0.0 -0.52 0.0 -0.52 0 0.0 0.0 -0.52 0.0 -0.52 0 00 0.0 -0.52 0.0 -0.52 0 0.0 0.0 -0.52 0.0 -0.52 0 0.0 00 -0.52 0.0 -0.52 0 0.0 0.0 -0.52 0.0 -0.52 0 0.0 0.0 -0.52 0.0 -0.52 0 0.0 0.0 -0.52 0.0 -0.52 0 00 0.0 -0.52 00 -0.52 0 0.0 00 -0.52 0.0 -0.52 

### AirNova, Inc. EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Anal-aerCalib. Gases Upscale ..", low mid high S\::s. Cal. Gas 

### 0.0 0.0 122.1 232.6 122.1 1.2 

### 0.0 120.9 233.9 120.9 0.52 0.00 -0.54 0.54

Uj2scale**S~stem ~alibration**  Gas 

### 1!..a1Lt.L Init. S\::s. Init. S\:::s. Final S\:::s. Final S\::s. Calib. Actual

Drift Calib. Cal. Bias Calib. Qal. Bias Drift Stack f% span) Response f% span) Response (% span) (% span) Conc.



### 0.00 120.9 -0.02 122.1 0.52 0.54 199.7 

### 0.00 122.1 0.52 120.9 0.00 -0.52 199.0 

### 0.00 120.9 0.00 0.0 -51.98 -51.98 0.0 0.00 00 -51.98 0.0 -51.98 0.00 

### ERR 0.00 00 -51.98 0.0 -51.98 0.00 

### ERR 0.00 0.0 -51.98 0.0 -51.98 0.00 

### ERR 0.00 0.0 -51.98 0.0 -51.98 0.00 

### ERR 000 0.0 -51.98 0.0 -51.98 0.00 

### ERR 0.00 0.0 -51.98 0.0 -51.98 0.00 

### ERR 0.00 0.0 -51.98 00 -51.98 0.00 

### ERR 0.00 0.0 -51.98 0.0 -51.98 0.00 

### ERR 0.00 00 -51.98 0.0 -51.98 0.00 

### ERR

### 3333·7E

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit No.2

- Acid Gases 04/20/10

Parameter: 

### Sulfur Dioxide InstrumentSpan (ppmVS02): 89.9

Actual Calibration Gas Value (oomV S02).- AnalyzerCalibration Response (ppmV

# son AnalyzerCalibration Error(% Span):

Zero Sy:stem Calibmtion Gas Apparent Init. Sys. Init. Sys. Final Sys. FinalSy:s.

S!fg;f<, Calib. Cal. Bias Calib. k§.l. Bias 

### Run Conc. Respont!e (% span) Response (% span)


### 30,9 0.3 0.00 -0.8 -1 30 2 

### 33.3 -0.8 -1.30 1.8 1.64 

### 0 0.0 

### 18 1.64 0.0 -0.38 0 0.0 0.0 -0.38 0.0 -0.38 0 0.0 0.0 -0.38 0.0 -038 0 0.0 0.0 -0.38 0.0 -0.38 0 0.0 0.0 -0.38 0.0 -0.38 0 0.0 0.0 -0,38 0.0 -0.38 0 00 0.0 -0.38 0.0 -0.38 0 00 0.0 -0.38 00 -0.38 0 0.0 0.0 -0.38 00 -0.38 0 0.0 0.0 -0.38 0.0 -0.38 

### AirNova, Inc. EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)

AnalyzerCalib. Gases Upscale 

# ""'" low mid high Sys. Cal. Gas 

### 00 0.0 50.7 899 50.7 0.3 0.0 510 89.0 51.0 0.15 0.00 0.15 -0.38

Up'seale Sy:stem Calibration Gas Calib. Inil. Sy:s. Init. Sys. Final Sys. Final Sys. Calib.**~** Drift Calib. Cal. Biat! Calib. Cal. Bias Drift Stack (% span) Response (% span) Response f% span} r% span) Cone.



### -1.30 51,0 0.00 51.0 0.00 0.00 30.8 2.94 

### 51.0 0.00 50.6 -0.44 -0.44 33.1 

### -2.01 50.6 -0.44 0.0 -56.73 -56.28 ·1.9 

### 0,00 0.0 -56.73 0.0 -56.73 0.00 

### ERR 0.00 00 -56.73 0.0 -56.73 0.00 

### ERR 000 0.0 -5673 0.0 -56.73 0.00 

### ERR 0.00 0.0 -56.73 00 -56.73 0.00 

### ERR 0,00 0.0 -56.73 0.0 -56.73 0.00 

### ERR 0.00 0.0 -56.73 00 -5673 0.00 

### ERR 0.00 0.0 -56.73 0.0 -56.73 0.00 

### ERR 0.00 0.0 -56.73 0.0 -56.73 0.00 

### ERR 0.00 0.0 -56.73 0.0 

### -56.73 000 

### ERR3333-7E-R3

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit No.2

- Acid Gases 04/21/10

Parameter: 

### Oxygen InstrumentSpan (% 

### 02): 21.96

Actual Calibration Gas Value (% 02): AnalYZerCalibration Response (% 02!: AnalvzerCalibration Error(% Span!:

Zero S),stem Calibration Gas AQ[2arent Init. Svs. Init. S\,:s. Final**S~s.** Final**S~s.**

Stack Cafib. Cal. Bias Calib. Cal. Bias 

### Run Conc. Response (% soan! Response (% s[2an!



### 3 4.92 0.02 0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 000 -0.05 0.00 -0.05 0 0.00 000 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -005 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 

## a 0.00 0.00 -0.05 0.00 -0.05 

### AirNova, Inc. EPA Method 7E Calculations (Cal. Error, Bias Driftand Bias Adjustment)**Anal~zer** Calib. Gases U[2scg/€!. 

# """ low mid high S\,:s. Cal. Gas 

### 0.00 

### NIA 12.46 21.96 12.46 0.01 

### NIA 12.39 21.74 12.39 0.05 0.00 -0.32 -1.00

Ul2scale Sllstem Calibration Gas**~** Init. S)!s. Init.**S)!~.** FinalS)!:s. Final**S~s.** Calib. Actual Drift Calib. e.g/. Bias Calib. Cal.**Bia~** Drift Slack (% span) Response (% span! Response (% spgn! (% span) Cone.



### -0.09 12.35 -0.18 12.37 -0.09 0.09 4.95 0.00 12.37 -009 0.00 -56.42 -56.33 0.00 0.00 0.00 -56.42 0.00 -56.42 0.00 

### ERR 0.00 0.00 -56.42 0.00 -56.42 0.00 

### ERR 0.00 000 -56.42 0.00 -56.42 0.00 

### ERR 0.00 0.00 -56.42 0.00 -56.42 0.00 

### ERR 0.00 0.00 -56.42 0.00 -56.42 000 

### ERR 0.00 0.00 -56.42 0.00 -56.42 0.00 

### ERR 0.00 0.00 -56.42 0.00 -56.42 0.00 

### ERR 0.00 0.00 -56.42 0.00 -56.42 0.00 

### ERR 0.00 0.00 -56.42 0.00 -56.42 0.00 

### ERR 0.00 0.00 -56.42 0.00 -56.42 0.00 

### ERR

### 3333-7E-R3

Client Project No. Test Location Test Date Spruance Genco, LLC 3333 Unit No.2

- Acid Gases 04121/10

Parameter: 

### Carbon Dioxide Instrument Span f% C02): 17,83

ActualCalibration Gas Value (% C02): Analy.zerCalibration Rewonse f% C02): AnalvzerCalibration Error(% Span):

Zero Sy:stem Calibration Gas At2Qarent Init. 

### Sy's. Init. 

### Sy's. FinalSy.s. Final

### S\::s.

Stack Calib. Clil. Bias Calib. Cal. Bias 

### Run Cone. 

### Res{2onse f% soan) Res{2onse (% span)



### 3 13.76 0.22 0.50 0.16 0.17 

### 0 0.00 0.16 0.17 0.00 -0.73 

### 0 0.00 0.00 -0.73 0.00 -0,73 

### 0 0.00 0.00 -0.73 0.00 -0.73 

### 0 0.00 0.00 -0.73 0.00 -0.73 

### 0 0.00 0.00 -0.73 0.00 -0.73 

### 0 0.00 0.00 -0.73 0.00 -0.73 

### 0 0,00 0.00 -0.73 0.00 -0.73 

### 0 0.00 0.00 -0.73 0.00 -0.73 

### 0 0.00 

### 000 -0.73 0.00 -073 

### 0 0.00 0.00 -0.73 0.00 -0.73 

### 0 0.00 0.00 -0.73 

### 0.00 -0.73 

### AirNova, Inc. EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Analy.zerCalib. Gases U{2scale zero low mid hioh $)i's. Cal. Gas 0.00 

### NIA 12.39 17,83 12.39 0.13 

### NIA 12.38 17.75 12.38 0.73 0.00 -0.06 -0.45

Uescale Sy:stem Calibration Gas Calib. lnit. Sy's. Init. 

### S\::s Final $\:::s. Finlil

### S\::s. Calib. Actual Drift Calib. Cal. Bias Calib. Cal. Bias Drift Stack (% span) Response (% span) Response (% s{2an) (% span) Cone.

-0.34 12.32 -0.34 12.32 -0.34 0.00 13.86 -0,90 12.32 -0.34 0.00 -69.43 -69.10 -0.16 0.00 0.00 -69.43 0.00 -69.43 0.00 

### ERR 0.00 0,00 -69.43 0.00 -69.43 0.00 

### ERR 0.00 0.00 -69.43 0.00 -69.43 0.00 

### ERR 0.00 0.00 -69.43 0.00 -69.43 0.00 

### ERR 0.00 0.00 -69.43 0.00 -69.43 0.00 

### ERR 0.00 0.00 -69.43 0.00 -69.43 0.00 

### ERR 0.00 0.00 -69.43 0.00 -69.43 0.00 

### ERR 0.00 0.00 -69.43 0.00 -69.43 0.00 

### ERR 0.00 0.00 -69.43 0.00 -69.43 0.00 

### ERR 000 0.00 -69.43 0.00 -69.43 0.00 

### ERR3333-7E-R3

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit No.2

- Acid Gases 04121/10

Parameter: 

### Nitrogen Oxides (as N02) InstrumentSpan (ppmVNOx): 232.6

Actual Calibration Gas Valu!1. fppmVNOx): AnalvzerCalibration R!1.SDOnSe (opmVNOx): AnalyzerCalibration Error(% Spgn):

Zero**S~stem** Calibration Gas AE2J2arent Init. Sys. Init. S't.s. Final Sys. FinalS:'t.s.

Stack Galib. Cal. Bias Ga/ib. 

### Ca'- Bias Run Cone. Response (% span) Re§.Qonse (% span)



### 3 189.9 0.0 0.00 0.0 0.00 0 0.0 0.0 0.00 00 0.00 0 00 0.0 000 00 0.00 0 0.0 0.0 0.00 0.0 0.00 0 0.0 0.0 0.00 0.0 0.00 0 0.0 0.0 0.00 0.0 0.00 0 0.0 00 0.00 0.0 0.00 0 0.0 0.0 0.00 0.0 0.00 0 0.0 0.0 0.00 0.0 0.00 0 0.0 0.0 0.00 0.0 0.00 0 0.0 0.0 0.00 0.0 0.00 0 00 0.0 0.00 00 0.00 

### AirNova, Inc. EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Anal't.zerCalib. Gase§. UpSCal!1. zero low mid high S't.s. Cal. Gas 

### 0.0 00 122.1 232.6 122.1 0.0 0.0 120.9 232.7 120.9 000 0.00 -0.52 0.04

Uj;lscale System Calibration Gas Calib. lnit**S~·** Init. S\:::s. FinalS:'t.s. Final Sys. Ga/ib. Actual Drift 

### ka.!i!L Cal. Bias Calib. Gal. Bias Dnft Stack (% span) Response (% span) R!1.sponSe (% span) (% 

### §.ognJ Conc.



### 0.00 120.9 0.00 119.6 -0.56 -0.56 192.9 0.00 119.6 -0.56 0.0 -51.98 -51.42 0.• 0.00 0.0 -51.98 0.0 -51.98 0.00 

### ERR 0.00 0.0 -51.98 0.0 -51,98 0.00 

### ERR 0.00 0.0 -51.98 0.0 -51.98 0.00 

### ERR 0.00 0.0 -51.98 0.0 -51.98 0.00 

### ERR 0,00 0.0 -51.98 0.0 -51.98 0.00 

### ERR 0.00 00 -51.98 0.0 -51.98 0.00 

### ERR 000 0.0 -51.98 0.0 -51.98 0.00 

### ERR 0.00 0.0 -51,98 0.0 -51.98 0,00 

### ERR 0.00 0.0 -51.98 0.0 -51.98 000 

### ERR 0.00 0.0 -51.98 00 -51,98 0.00 

### ERR

### 3333-7E·R3

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit No_ 2

- Acid Gases 04/21/10

Parameter: 

### Sulfur Dioxide Instrument Span (ppmVS02): 89.9

Actual Calibration Gas Value (ppmVS021. AnalvzerCalibration Response (ppmVS02): AnaNzerCalibration Error(% Span):

Zero**S~tem** Calibration Gas**ApQar~nt** Init. S)!s. Init. S,,-s. Final S,,-s. FinalS,,-s. Stack Ca/ib. Cal. Bias Calib. Cal. Bias 

### Run Conc_ Respon,s:§: (% span) Response (% sPf1.n)



### 3 31.6 

### 0.4 0.00 

### 1.0 0,60 

### 0 0.0 1.0 0.60 

### 0.0 -0.49 0 

### 0.0 0.0 -0,49 

### 0.0 -0.49 

### 0 0.0 0.0 -0.49 

### 0.0 -0.49 

### 0 0.0 0.0 -0.49 

### 0.0 -0.49 

### 0 0.0 0.0 -0,49 

### 0.0 -0.49 

### 0 0.0 00 -0,49 

### 0.0 -0.49 

### 0 00 0.0 -0,49 

### 00 -0.49 

### 0 0.0 0.0 -0.49 

### 00 -0,49 

### 0 0.0 0.0 -0.49 

### 0.0 -0.49 

### 0 0.0 0.0 -0.49 

### 0.0 -0.49 

### 0 0.0 0.0 -0.49 

### 0.0 -0.49 

### AirNova, Inc. EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Ana/,,-zerCalib. Ga,s:§:s UQ.,s:QB.le zero low mid high S,,-s. Cal. Gas 

### 0.0 0.0 50.7 89.9 50.7 

### 0.4 0.0 50.8 89.0 50.8 0.19 0.00 0.04 -0.39

Ur;lscale Sy:stem Calibration Gas Calib. lnit. S,,-s. Init. S,,-s. Final**S~.** Final S)!s. Calib. Actual Drift Calib. Cal. Bias Calib_ Cal. Bias Drift Stack (% span) Response (% span) Response (% span) (% sQanJ Conc.

0.60 50.8 0.00 49.7 -1.22 -122 31.6 -1.09 49.7 -1.22 

### 0.0 -56.51 -55.28 -1.0 0.00 

### 0.0 -5651 

### 0.0 -56.51 0.00 

### ERR 0.00 

### 00 -56_51 

### 0.0 -56.51 0,00 

### ERR 0.00 

### 00 -56.51 

### 0.0 -56.51 0.00 

### ERR 0.00 

### 00 -56.51 

### 0.0 -56.51 0.00 

### ERR 000 0.0 -56.51 

### 0.0 -56.51 0.00 

### ERR 0.00 

### 0.0 -56.51 

### 0.0 -56.51 0.00 

### ERR 0.00 

### 0.0 -56.51 

### 0.0 -56_51 0.00 

### ERR 0.00 

### 0.0 -56.51 

### 0.0 -56_51 0_00 

### ERR 0.00 

### 0.0 -56.51 

### 0.0 -56.51 0_00 

### ERR 0.00 

### 0.0 -5651 

### 0.0 -56.51 0.00 

### ERR

### 3333-HCI-HF-R1



### Client Project No. 

### Test location Test Run 

### Test Date Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vic

# = Vm= Pstatic 

### = Pb

# = Ps

# = Pstd

# = dP= 

### dH 

### = Tm= Ts

# = Tstd= 

### On

# = An

# = y= 

### t

# = Os

# = As

# = Cp= Kp= K1 

### = K2= K3

# = Fd

# = CF= 

### CF 

### =

[02[ 

### [C02]
[N2] 

### AirNova, Inc. EPA Methods 1,2,3A,4,and 26A (Flows, 

### 02/C02, H20,and HCI/HF] 

### Spruance Genco, LLC 

## 3333 Unit No.2 One 04/20/10 

## 1107-1414

373.9 

### cc Emission Data

117.848 dcf 

### -0.47 in. 

### H20 30.04 in. Hg 30.01 In. Hg 29.92 in. Hg 

# o7286 in. 

### H20 '\5

1.468 in. 

### H20 538.4 R 649.2 R 527.7 R 

### 0.248 in 0.000335 sq. ft. 1.01 

### 180 min. 10.300 ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure 

### EPA Standard pressure 

### Average sq.rt delta P Average draft gauge reading Average meter temperature Average stack temperature Standard temperature Nozzle diameter Area of nozzle orifice Metercalibration factor 

### Duration of sampling time Diameterofstack 83.323 sq, 

### ft, Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)'(inHg)]'.5}/[s·R·onH20] Pilot lube constant 17.637 R/in.Hg 0.047070 cu.ftlml 0.0026688 in.Hg-ef/ml-R 9828 sef/MMBtu 9.461

### E-OB Ib/dscf

### I ppmVd 5.192E-08 Ib/dseff ppmVd



### Instrumental Data



### 4.0B %-dry 14.57 %-dry

81.35 %-dry constant constant constant Fuel Factor Conversion Factor for HCI Conversion Factorfor HF

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client 

### Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) Volume of gas sampled at standard conditions, Vmstd.



### Vmstd =K1'Y 'Vm ' (Pb +

### dH/13.6) 

### ITm Vmstd

# = 117.557 dscf 

### 3,33 dscm Unit No.2 One



### 2) Volume ofwatervaporcollected at standard conditions, Vw(std). 

### Vw(std) = K2 • Vie Vw(std) = 17.599 sef


### 3) Decimal fraction of moisture by volume in stack gas, Bws.

Bws

# = Vwstd / (Vmstd+Vwstd) Bws

# = 0.130
4) Molecularweight ofthe stack gas on a wet basis, Ms.



### Ms = [ ((44'%C02) + 

### (32'%02) + 

### (28'%N2)) • (1-Bws)

## J+ 

### (18'Bws) Ms= 28,87 Ib/lbmole


### 5) Average stack gas velocity, Vs.



### Vs = Kp' Cp' (dP)' (Ts/Ps'Ms)A5 Vs = 4529 fps
6) Average actual stack gas volumetric flowrate, Qa.

Qa

# = 60 sec/min 

### * Vs ., As 

### Qa = 226446.6 efm 6413,0 cmm 

### 7) Average stack gas dry volumetric flowrate, Qstd.


### Qstd = Qa' (TstdlTs)' (Ps/Pstd)' (1-Bws) Qstd

# = 160555.3 dscfm 4546.9 dscmm 

### Page 2

### Client 

### Spruance Genco, LLC Project No. 

### 3333 Test Location Test Run

Calculations (cont.)


### 8) Hydrogen Chloride Concentration and Emissions Unit No.2 

### One

M[HCI[ = 

### M[CI-lImg)' MW[HCI](mg/mmol) 1

### MW[CI-](mg/mmol) Page 3



### C[HCI]

# =(M[HCI](mg) • 2.205E-06(lb/mg) • 21.85(scf·inHg/lbmol·R) • K1 • 10'6) 1

### (MW[HCI](lb/lbmol) • Vmstd(d C[HCI](@corr 02)

# = C[HClllppmV)' [(20.9-corrected 02) 

### 1(20 9-actual %02)] E[HCI] = 

### M[HClllmg) • Qstd(dscfm) • (2.205E-06)(lb/mg) • 60(min/hr) 

### 1Vmstd(dscD E[HCI]

# = C[HCI](ppmV)' Fd'CF(HCI)' (20.9/(20.9-%02)]



## < M[HCI]

# = < C[HCI]

# = < C[HCI] = 

## < E[HCI]

# = < E[HCI]

# = 0.07 mg 0.014 ppmV 0.011 ppmV 0.013 Ib/hr 160E-05 Ib/MMBtu


### 9) Hydrogen Fluoride Concentration and Emissions


### C[HF]

# =M[HF](mg) 

### 1Vmstd(dscm) (@ 7.0 

### %02)

C[HF]

# =(M[HF](mg) • 2.205E-06(lb/mg) '21.85(scr'InHgllbmol'R) , K1 ' 10'6) 

### 1(MW[HF](Ibllbmol) 'Vmstd(dsc C[HF](@corr. 02)

# = C[HF](mg/dscm)' [(20.9-corrected 02) 1

### (20.9-actual %02)] E[HF]

# = C[HF](mg/dscm)' Qstd(dscmm)' (2.205E-06)(lb/mg)'60(min/hr) E[HF]

# = C[HFllppmV)' Fd' CF(HF)' (20.9/(20.9-%02))
M[HF] 

### = C[HF]

# = C[HF] 

### = C[HF] 

### = E[HF]

# = E[HF]

# =
10) Isokinecity, 

### I. 

### 0.670 mg 0.201 mg/dscm 

### 0.242 ppmV 0.200 ppmV ( @ 0.121 Ib/hr 

### 1.53E-04 Ib/MMBtu 7.0

% I

### = (100'Ts'(K3OVlc+(Vm·YlTm)(Pb+dH/13.6)))/(60't·Ps'Vs'An) %1= 101.0 % 

### 02)

### 3333-HCI-HF-R2



### Client Project No. Test Location Test Run Test Date 

### lestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vlc= Vm= 

### Pstatic

# = Pb 

### = Ps 

### = Pstd

# = dP

# = dH 

### = Tm= Ts= Tstd= Dn

# = An= 

### y= t= Ds

# = As= Cp

# = Kp= K1 

### = K2= 

### K3= Fd

# = CF

# = CF

# =

[02] ]C02]
]N2] 

## AirNova, Inc. EPA Methods 1,2,3A,4,and 26A (Flows, 021C02, H20,and HCIIHF) 

### Spruance Genco, LLC 

## 3333 Unit No.2 

# Two 04/20/10 1430-1738

376.3 

## cc 120.241 delEmission Data



### ,·0.45 

### in. H20 29.99 

### in, Hg 29.96 in. Hg 

### 29,92 in. 

### Hg 0.7343 in. H20 

### '\5

1 533 in. H20 5410 R 6500 R 527.7 R 0.248 in. 0.000335 sq. 

### ft. 1.01 

### 180 min. 10.300 

### ft 83.323 sq. 

### ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq rt delta P 

### Average draftgauge reading Average metertemperature Average stack temperature Standard temperature 

### Nozzle diameter Area ofnozzle onfice Metercalibration factor Duration ofsampling time Diameter ofstack Cross sectional area ofstack 

### 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R"mH20] Pitot tube constant 17.637 Rlin Hg 

### 0047070 cu.ftlml 0.0026688 in.Hg-ellml-R 9676 scf/MMBtu 9.461 E-08 Ibldsell ppmVd 5.192E-08 Ibldsell ppmVd



### Instrumental Data

4.34 %-dry 1423 %-dry

81.43 %-dry constant constant constant Fuel Factor Conversion Factorfor Hel Conversion Factor for HF

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run



### Calculations
1) 

### Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1'Y'Vm' (Pb + 

### dH/13.6) /Tm Vmstd

# = 119.174 dscf 

### 3.38 dscm Unit 

### NO.2 

### Two

2) 

### Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std) = K2 'Vic Vw(std) = 17712 

### scf
3) Decimal fraction ofmoisture byvolume in stack gas, Bws.

Bws = 

### Vwstd 

### I (Vmstd+Vwstd) Bws

# = 0.129
4) 

### Molecularweight ofthe stack gas on awet basis, Ms.

Ms = [((44'%C02) 

### +(32'%02) + 

### (28'%N2))' (1-Bws) I 

### + (18'Bws) Ms

# = 28.84 Ib/lbmole
5) Average stack gas velocity, Vs.

Vs = Kp , Cp , (dP) , (Ts/Ps'Msj'.5 Vs

# = 45.73 fps 

### 6) Average actual stack gas volumetricflowrate, Qa.

Qa

# = 60 sec/min 

### * Vs 

### *As 

### Qa = 228644 8 cfm 64752 cmm 7) Average stackgas dryvolumetric flowrate, Qstd.
Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) Qstd 

### = 161817.4 dscfm 4582.7 dscmm Page 2

### Client Spruance Genco, LLC Project No. 

### 3333 Test Location Test Run

Calculations (cont.)


### 8) Hydrogen Chloride Concentration and Emissions Unit No.2 

### Two

M[HCI] = 

### M[CI-lImg) , MW[HCllImglmmol) 1MW[CI-](mglmmol) Page 3



### C[HCI] = 

### (M[HCI](mg) , 2 205E-06(lblmg) , 21.85(scf·'nHgllbmol'R) , K1 ' 10'6) 1(MW[HCI)(Ibllbmol) 'Vmstd(d C[HCIII@corr. 02)

# = C[HCI](ppmV)' [(20.9-corrected 02) 1(20 9-actual %02)] E[HCI]

# =M[HCI](mg)' Qstd(dscfm)' (2.205E-06)(lblmg)'60(minlhr) 1Vmstd(dscn E[HCI]

# = C[HCllIppmV)' Fd'CF(HCI)' (20.91(20.9-%02))



## < M[HCI]

# = 0.08 

### mg 

## < C[HCI]

# = 0.016 ppmV 

## < C[HCI]

# = 0.013 ppmV (@ 7.0 

### %02) 

## < E[HCI]

# = 0.014 Iblhr 

## < E[HCI]

# = 1.81E-05IbIMMBtli


### 9) Hydrogen Fluoride Concentration and Emissions


### C[HF] = 

### M[HF](mg) 1Vmstd(dscm) C[HF] = 

### (M[HF](mg) , 2 205E-06(lblmg) , 21.85(scf'inHgllbmol'R) , K1 ' 10'6) 1(MW[HFlIlbllbmol) • Vmstd(dsc C[HF](@corr. 02)

# = C[HF](mgldscm)' [(20.9-corrected 02) 1(20.9-octual %02)] E[HF] 

### =C[HF](mgldscm)' Qstd(dscmm)' (2.205E-06)(lblmg)·60(minlhr) E[HF]

# = C[HF](ppmV)' Fd' CF(HF)' (20.91(20.9-%02))
M[HF]

# = C[HF] 

### = C[HF] = 

### C[HF]

### = E[HF]

# = E[HF]

# =
10) Isokinecity, I. 0.700 

### mg 0.207 

### mg/dscm 

### 0.249 ppmV 0.209 ppmV (@ 0.126 Iblhr 1.58E-04 IblMMBtu 7.0

% I

# =(1 00'Ts'(K3'Vlc+(Vm·YlTm)(Pb+dHI13.6)))1(60't'Ps'Vs·An) %1= 101.6 

### %02)

### 3333-HCI-HF-R3



### Client Project No. Test Location Test Run 

### TestDate TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vlc= 

### Vm 

# = Pstatic

# = Pb

# = Ps = 

### Pstd 

### = dp

# = dH = 

### Tm= Ts= Tstd= Dn 

### = An = 

### y= 

### t

# = Ds = 

### As

# = Cp

# = Kp= K1 

### = K2= K3= Fd 

### = CF= CF=

[02[ [C02[
[N2[ 

## AirNova, Inc. EPA Methods 1,2,3A,4,and 26A (Flows, 021C02, H20,and HCtIHF) 

### Spruance Genco, LLC 

## 3333 Unit No.2 Three 

## 04121110 0655-1000

381.8 

### cc 114.872 del

### Emission Data

-045 

### in, H20 29_87 in. 

### Hg 29.84 

### in. Hg 29.92 

### in, Hg 

### 07263 in. H20 

### ".5

1.443 in. 

### H20 514.2 R 647.6 R 527.7 R 

### 0,248 

### in. 0.000335 sq. ft. 

### 1.01 

### 180 min, 10.300 ft. Vol. of H20 collected 

### Dry gas 

### meter readfng Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature 

### Nozzle diameter Area ofnozzle orifice Meter calibration factor Duration ofsampling time Diameter of stack 83.323 sq. 

### ft. Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lbllbmol),(inHg)]'.5)/[s'R'inH20] Pitot tube constant 17.637 R/in.Hg 0.047070 cu.ftlml 0.0026688 in.Hg-cf/ml-R 9826 scf/MMBtu 9.461 E-08 Ibldscf I ppmVd 5.192E-08 Ibldscff ppmVd



### Instrumental Data

4.95 %-dry 13.86 %-dry

81.19 %-dry constant constant constant Fuel Factor Conversion Factorfor HCI Conversion Factorfor HF

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 

### Test Location Test Run
Calculations 1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1' Y'Vm' (Pb + 

### dH/13.6) ITm 

### Vmstd 

### = 119.290 dscf 

### 338 dscm Unit No 2 

### Three

2) Volume ofwatervaporcollected at standard conditions,Vw{std).
Vw(std) = K2 • Vic Vw(std) = 17.971 scf 

### 3) Decimal fraction of moisture by volume in stack gas, Bws.

Bws

# = Vwstd 

### I (Vmstd+Vwstd) Bws= 

### 0131 4) Molecularweight ofthe stack gas on awet basis, Ms.

Ms = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) [+ (1S'Bws) 

### Ms= 28.79 Ib/lbmole 

### 5) Average stack gas velocity, Vs.

Vs = Kp'Cp' (dP)' (Ts/Ps·Ms)'.5 

### Vs = 

### 45.29 fps 

### 6) Average actual stack gasvolumetric flowrate, Qa.
Qa

# = 60 sec/min '* 

### Vs '* 

### As Qa 

### = 226405.0 cfm 

### 6411.8 cmm 

### 7) Average stack gas dryvolumetric flowrate, Qstd.

Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

### Qstd

# = 159883.5 dscfm 4527.9 dscmm 

### Page 2

### Client Spruance Genco, LLC 

### Project No. 3333 Test Location Test Run

Calculations (cont.)
8) Hydrogen Chloride Concentration and Emissions Unit No 2 Three



### M[HCI]

# =M[CI-](mg) , MW[HCI](mglmmol) 1MW[CI-](mglmmol) Page 3



### C[HCI] = (M[HCI](mg) , 2 205E-06(lblmg) , 21.85(scf'lnHgllbmol'R) , K1 ' 10'6) 1(MW[HCI](Ibllbmol) 'Vmstd(d C[HCI](@corr. 02) = C[HCI](ppmV)' [(20.9-corrected 02) 1(20.9-actual %02)] E[HCI] = M[HCI](mg) , Qstd(dscfm) , (2.205E-06)(lblm9) '60(minlhr) 1Vmstd(dscf) E[HCI] = C[HCI](ppmV)' Fd' CF(HCI)' (20.91(20.9-%02)]



## < M[HCI]= 0.07 mg 

## < C[HCI] = 0.014 ppmV 

## < C[HCI] = 0.012 ppmV (@ 7.0 % 

### 02) 

## < E[HCI]= 0.012 Ibfhr 

## < E[HCI] = 1.67E-05 IblMMBtu
9) Hydrogen Fluoride Concentration and Emissions


### C[HF] = M[HF](mg) IVmstd(dscm) C[HF] = (M[HF](mg) '2.205E-06(lblm9) , 21.85(scf'lnHgllbmol'R) , K1 ' 10'6) 1(MW[HF](Ibllbmol) , Vmstd(dsc C[HF](@corr. 02) = C[HF](mgldscm)' [(20.9-corrected 02) 1(20.9-actual %02)] E[HF] = C[HF](mgldscm)' Qstd(dscmm)' (2.205E-06)(lblmg)'60(minlhr) E[HF] = C[HF](ppmV) , Fd ' CF(HF) , (20.91(20 9-%02)]
M[HF] = C[HF] = C[HF] = C[HF] = E[HF] = E[HF] = 

### 10) Isokinecity,l. 0.620 m9 

### 0,184 mgfdscm 0.221 ppmV 0.192 ppmV (@ 0.1101bfhr 

### 148E-04 IblMMBtu 7.0

% 1= (100'Ts'(K3'Vlc+(Vm"YlTm)(Pb+dHI13.6)))1(60't'Ps'Vs'An) 

### % I = 

### 103.0 

### %02)Client Project No. Test Location Fuel Type Test Run Test Date Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT INPUT

INPUT INPUT Vic 

### = Vm= Pstatic = Pb = Ps

# = Pstd = dP

### = dH = Tm= Ts= Tstd= 

### y= t= On = An

# = Os = As

# = Cp = Kp 

### = K1 = K2

# = K3 = Fd =

[02J [C02J [N2J [NOxJ [802J 

### AirNova, Inc. EPA Methods 

### 1, 2, 3A, 

### 4, 6 and 7E (Flows, 

### 02/C02, H20, 802 and NOx)
Spruance Genco, LLC 

### 3333 Unit No, 2 Coal One 04/20/10 1107-1414 Emission Data

373.9 cc 117,848 dcf -0.47 in. H20 30,04 in. Hg 30.01 in. Hg 2992 in. Hg 0.7286 in. H20 

### ".5 1.47 in. H2O 538.4 

### R 649.2 

### R 

### 5277 R

1.01

180 min. 0.248 in, 0.000335 sq. ft. 10.300 ft, 83,323 sq. ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Metercalibration factor Duration of sampling time Nozzle diameter Nozzle area Diameter ofstack Cross sectional area of stack 

## o84 Pitottube coefficient 85.49 

### ft.[(lb/lbmolt(1nHg)

## J".5}/[ s*R*inH20] 17.637 R/in.Hg constant Page 1 

### of3

0.047070 cu.fVml constant Pitot tube constant 0.0026688 in.Hg-cf/ml-R 9828 scf/MMBtu

Instrumental Data 4.08 %-dry 14.57 %-dry 81.35 %-dry 199.7 ppmV-dry 30.8 ppmV-dry constant From EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Nitrogen Oxides concentration Sulfur Dioxide concentrationClient Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations 1) Volume ofgassampled atstandard conditions, Vmstd.

Vmstd =K1*

### Y"Vm" (Pb +dH/13 

### 6) I Tm Vmstd

# = 117.557 dscf 3.329 dscm Unit No.2 One

2) Volume ofwatervaporcollected at standard conditions, Vw(std). Vw(std)

# =K2**~** Vic Vw(std) = 17.599 scf


### 3) Decimal fraction ofmoisture 

### byvolume in stack gas, Bws.

Bws =Vwstd / (Vmstd+Vwstd) Bws'" 0.1302


### 4) Molecularweight ofthe stack gas on a wet basis, Ms.

Ms

# = [«44"%C02)+ (32"%02) + (2S*%N2»" (1-Bws) 

## 1+ (1S*Bws) Ms= 28.867 tbl tbmote
5) Average stackgas velocity, Vs.

Vs

# =Kp" Cp" (dP) " (TslPs*Ms)ll.5 Vs 

### = 45.295 fps
6) Average actual stack gas volumetric flowrate, Qa.

Oa 

### =60 sec/min" Vs " As Oa = 

### 226446.6 cfm 6413.0 cmm 7) Average stackgas dryvolumetric flowrate, Qstd.

Ostd = Oa" (TstdfTs)"" (Ps/Pstd)" (1-Bws) Qstd

# = 160555.3 dscfm 

### 4546.9 dscmm Page 2 of3Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations (cant.)Umt No, 

### 2 One Page 3 of3

9) Nitrogen Oxides concentrations and emissions
Carr. C[NOx] = «20.9-02% carr. value)/(20.9-actual avg 02% value))"Avg. raw NOxvalue E[NOx] = (C[NOx]"Mol Wt[NOx]*60(min/hr)*Qstd(dscfm))/(Molar 

### Vol. air"10"6) E[NOx Ib/MMBtu] = Cd 

### * Fd • (20.9/(20.9-actual 02%)) C[NOx] = 199.7 ppmVd C[NOx] = 165.0 ppmVd corrected to 7 % 02 Mol. Wt. [NOx]= 46,01 Ib/lb-mole Molarvol air= E[NOx[

# = Cony Factor, E[NOx[

# = 385 scf/lb-mole 

### @ 229.90 Ib/hr 

### 68
1.194E-07 convert ppmV to Ib/scf NOx 0,291 lb/MMBtu 10) Sulfur Dioxide concentrationsand emissions def F

Corr. C[S02] = ({20.9-02% carr. value)/(20.9-actual avg. 02% vaJue))·Avg. raw 502 value E(lb/MMBtu) = Cd(lb/scf)**~** Fd(scf/MMBtu) " [20.9 I (20.9-% 02)] E[S02 Ib/hr] = (C[S02]*MolWt[S02]*60(min/hr)*Qstd(dscfm))/(Molar Vol. alr"10"6) C[S02] = 30.8 ppmV (dry) Actual Conc. C[S02] = 25.5 ppmVd corrected to 7 % 02 Mol. WI. [S02]= 64.06 Ib/lb-mole Molarvol air= Conv Factor, E[S02[ = E[S02[ 

### = 385 scf/lb-mole 

### @ 68 1.66E-07 convert ppmV to Ib/scf S02 0.062 Ib/MMBtu 49.37 Ib/hr def FClient Project No. Test Location Fuel Type Test Run Test Date Time Period



### INPUT INPUT INPUT INPUT

INPUT 

### INPUT INPUT 

### INPUT

INPUT

INPUT

INPUT Vlc= Vm= Pstatic = Pb = Ps 

### = Pstd = dP 

### = dH

# = Tm = Ts 

### = Tstd= 

### y= t= On 

### = An = Ds= As= Cp= Kp

# = K1 

# = K2= K3

# = Fd =



### INPUT [02] INPUT [C02] [N2] 

### INPUT [NOx] INPUT [S02] 

### AirNova, Inc. EPA Methods 

### 1, 2, 3A, 4, 6 and 7E (Flows, 

### 02/C02, H20, 502 and NOx)
Spruance Genco, LLC 

### 3333 Unit No.2 Coal 

### Two 04/20/10 

### 1430-1738

376.3 ccEmission Data



### 120.241 dcf 

### -0.45 in. H20 

### 29.99 in. Hg 

### 29.96 in. Hg 

### 29.92 in. Hg 

### 0.7343 In. H20 

### ".5 1.53 in. H20 

### 541.0 R 

### 650.0 R 527.7 R



### 1.01

180 min. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration of sampling time 

### 0.248 in Nozzle diameter 

### 0.000335 sq. 

### ft. Nozzle area 

### 10.300 ft. Diameter ofstack 

### 83 323 sq. ft. Cross sectional area ofstack 

### 0.84 Pitot tube coefficient 

### 85.49 ft[(Ib/lbmol)*(inHg)J".5}/[**s~R*inH201** 

### 17.637 R/in.Hg constant 

### 0.047070 cu.ftlml 

### 00026688 in.Hg-cf/ml-R 

### 9676 scf/MMBtu

Instrumental Data 

### 4.34 %-dry 

### 14.23 %-dry 

### 81.43 %-dry 

### 1990 ppmV-dry 

### 33.1 ppmV-dry constant Pitot tube constant constant From EPA Reference Method 

### 19

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Nitrogen Oxides concentration Sulfur Dioxide concentration Page 

### 1 of

### 3

### Client Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1* 

### Y

### *Vm 

### * (Pb 

### + dH/13 6) 

### ITm Vmstd= 119.174 dscf 3.375 dscm Unit 

### No.2 Two



### 2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2 * Vic Vw(std) = 17.712 scf 3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws = Vwstd 

### I (Vmstd+Vwstd) Bws= 0.1294 4) Molecularweightofthestack gas on awet basis, Ms.

Ms = [«44*%C02)

### + (32*%02) 

### + (28*%N2»· (1-Bws) 

## 1 + (18*Bws) Ms = 28.839 Ib/lbmole
5) Average stack gas velocity, Vs.

Vs = Kp * Cp * 

### (dP) " (TsJPs*Ms)".5 Vs = 45735 fps 6) Average actual stack gasvolumetric flowrate, Qa.

Oa = 60 sec/min * Vs • As Oa = 228644.8 cfm 6475.2 cmm 7) Average stackgas dry volumetric flowrate, Qstd.
Ostd = Oa • (Tstd/Ts) • (Ps/Pstd) * (1-Bws) Ostd = 161817.4 dscfm 4582.7 dscmm Page 2 of3Client Project No. 

### Spruance Genco, LLC 

### 3333 Test location Test Run
Calculations (cont.)

### Unit No 2 

## Two Page 3

### ot3

9) Nitrogen Oxides concentrations and emissions


### Corr. C[NOx]

# =«20.9-02%corr 

### value)/{20.9-actual avg 02% value»"Avg. raw NOx value E[NOxJ = (C[NOxtMol**WI[NOxl~60{min/hrtQstd(d$cfm))/(Molar** 

### Vol air*10116) E[NOx Ib/MMBtu] = Cd ., Fd ,. (20.9/(20.9-actual 02%» C[NOx]

# = 199.0 ppmVd C[NOx]

# = 1670 ppmVd corrected to 7 % 02 Mol. WI. [NOx]= 46.01 Ib/lb·mole 385 scf/lb-mole 

### @ 230.90 Ib/hr 

### 68 Molarvol air- E[NOx[ 

### = Conv Factor. E[NOx]

# = 1.194E-07 convert ppmV to Ib/scf NOx 0290 Ib/MMBtu
10) Sulfur Dioxide concentrations and emissions 

### defF

Corr. C[802] = ({20.9-02% corr. value)/(20.9-actual avg. 02% value»*Avg. raw 802 value E{lb/MMBtu) = Cd(lb/scf) * 

### Fd(scf/MMBtu) * 

### [20.91 (20.9-% 02)J E[802Ib/hr] = (C[S02]"Mol Wt[802]*60(min/hr)*Qstd(dscfm»/{MolarVol. air"10116) C[802] = 33.1 ppmV (dry) Actual Cone. C[S02] = 27.8 ppmVd corrected to 7 % 02 Mol. 

### WI. [802]= 64.06 Ib/lb-mole Molarvol air= Conv Factor. 

### E[S02]

# = E[S02]

# = 385 scf/lb-mole 

### @ 68 1.66E-07 convert ppmV to Ib/scf802 0.067 Ib/MMBtu 5347 Ib/hr def FClient Project No. Test Location Fuel Type Test 

### Run Test Date Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT INPUT

INPUT INPUT Vic

# = Vm= Pstatic

# = Pb

# = Ps

# = Pstd

# = dP 

### = dH = Tm 

### = Ts 

### = Tstd= 

### y= t= Dn

# = An = Ds

# = As = Cp 

### = Kp 

### = K1 = 

### K2 

### = K3 = Fd

# =

[02[ [C02[ [N2] [NOx] [S02] 

### AirNova, Inc. EPA Methods 

### 1, 2. 3A. 4. 6 and 

### 7E (Flows, 02/C02. H20, 802and NOx)
Spruance Genco, LLC 3333 Unit No.2 Coal Three 

### 04/21/10 0655-1000

381.8 ccEmission Data

114.872 dcf -0.45 in. H20 29.87 in. Hg 29.84 in. Hg 29.92 in Hg 0.7263 in. H20 '\5 1.44 in H20 514.2 R 

### 647.6 R 527.7 R



### 1.01

180 min. 0.248 in. Vol. of H20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time Nozzle diameter 0.000335 sq ft. Nozzle area 10.300 ft. Diameter ofstack 83.323 sq. ft. Cross sectional area ofstack
o 84 Pitottube coefficient 85.49 ft[(lb/lbmol)*(inHg)]".5}/(s*R*inH20] 17.637 R/in.Hg constant 0047070 CU.fl/ml 0.0026688 in.Hg-cf/ml-R 9826 scf/MMBtu

Instrumental Data 4.95 %-dry 13.86 %-dry 81.19 %-dry 192.9 ppmV-dry 31.6 ppmV-dry constant Pitot tube constant constant From EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Nitrogen Oxides concentration Sulfur Dioxide concentration Page 1

### of3

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test 

### Run
Calculations
1) 

### Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd**=K1~** Y 

### *Vm 

### * (Pb + dH/13.6) 

### ITm Vmstd = 119.290 dscf 3.378 dscm 

### Unit No.2 Three



### 2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = 

### K2 * 

### Vic Vw(std) = 17.971 scf
3) 

### Oecimal fraction ofmoisture by

### volume in stackgas, Bws.

Bws =Vwstd I 

### (Vmstd+Vwstd) Bws= 0.1309
4) 

### Molecularweightofthestackgas on awet basis, Ms.

Ms = [«44*%C02)+ (32"%02) + (28*%N2))" (1-Bws) 

## 1 + (18*Bws) Ms = 28790 Ib/lbmole
5) 

### Average stack gasvelocity, Vs.

Vs = Kp'" Cp * 

### (dP)"**(Ts/Ps~Ms)".5** 

### Vs 

### = 45 287 fps 6) Average actual stack gas volumetricflowrate. Qa.
Qa = 60 sec/min**~** 

### Vs**~** 

### As Qa = 226405.0 cfm 6411.8 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa**~** 

### (Tstd/Ts)" (Ps/Pstd);O; (1-Bws) Qstd = 159883.5 dscfm 4527.9 dscmm Page 2 of3Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations (cont.)Unit No.2 Three Page 3 of3

9) Nitrogen Oxides concentrationsand emissions
Corr. C[NOx] = {(20.9-02% carr. value)/{20.9-actual avg. 02% value»"Avg. raw NOx value E[NOx] = (C[NOx]*Mol Wt[NOx]*60{min/hr)*Qstd{dscfm))/{MolarVol. air*1 0"6) E[NOx Ib/MMBtu]

# = Cd· Fd· (20.9/{20.9-actual 02%)) C[NOx] = 192.9 ppmVd C[NOx] = 168.1 ppmVd corrected to 7 % 02 Mol. 

### wt. [NOx]= 46.01 Ib/lb-mole Molar vol air= 385 scf/lb-mole 

### @ 68 def

### F E[NOx] = 221.15 Ib/hr Conv Factor. E[NOx] = 1.194E-07 convert ppmV to Ib/scf NOx 0297 Ib/MMBtu 10) Sulfur Dioxide concentrationsand emissions
Carr. C[S02] = ({20.9-02% carr. value)/{20.9-actual avg. 02% value»*Avg. raw S02 value E{lb/MMBtu) = Cd{lb/scf) " Fd{scf/MMBtu) • [20.9 

### I (20.9-% 02)] E[S02 Ib/hr] = (C[S02]*Mol Wt[S02t60(min/hrtQstd(dscfm»/{MolarVol. air"10"6) C[S02] = 31.6 ppmV (dry) Actual Conc C[S02]

# = 27.5 ppmVd corrected to 7 % 02 Mol. 

### wt. [S02]= Molar vol air= Conv Factor. 

### E[S02]

# = E[S02]

# = 64.06 Ibllb-mole 385 scf/lb-mole @ 68 166E-07 convert ppmV to Ib/scf S02 0.068 Ib/MMBtu 50.44 Ib/hr defF

### 3333-HCN-R1



### Client Project No. Test Location Test Run Test Date 

### TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT Vic

# = Vm= Pstatic

# = Pb

# = Ps

# = Pstd 

### = dP= dH

# = Tm= 

### Ts= Tstd= 

### On

# = An 

### = y=. t= Ds 

### = As= Cp= 

### Kp

# = K1 

# = K2= 

### K3

# = Fd = 

### CF=

[02] [C02]
]N2] 

## AirNova, Inc. EPA Methods 1,2,3A,4,and Modified 26 (Flows, 

### 02/C02, H20,and HCN) 

## Spruance Genco, LLC 

## 3333 Unit No.2 One 

## 04/20/10 1107-1207

142 

### cc 44.207 dclEmission Data**~O.50** 

### in, 

### H20

30.04 

### in, Hg 

### 30.00 in. 

### Hg 29.92 

### in. Hg 

### 0.7294 

### in, 

### H20 11,5



### 1.820 in. H20 537.2 R 647.5 R 527.7 R 

### Din. 0.000000 sq. ft. 0.99



### 60 min. 10.300 ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure 

### EPA Standard pressure Average sq.rtdelta P Average draftgauge reading 

### Average metertemperature Average stacktemperature Standard temperature Nozzle diameter Area ofnozzle orifice Metercalibration factor Duration ofsampling time Diameterofstack 

### 83,323 sq. ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lbllbmol)'(inHg)]'.5)/]s·WinH20] Pitottube constant 17.637 R/in.Hg 0047070 cU.ft/ml 0.0026688 in.Hg-cflml-R 

### 9828 scf/MMBtu 7.014E-08 Ib/dscfl ppmVd

Instrumental Data

4.08 %-dry 14.57 %-dry

81.35 %-dry constant constant constant Fuel Fador Conversion Factor for HCN

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) Volume of gas sampled atstandard conditions, Vmstd.

Vmstd 

### =K1*Y* Vm 

### * (Pb + dH/13.6) I 

### Tm Vmstd = 

### 43.356 dsef 1.23 dsem Unit No.2 One



### 2} Volume ofwatervaporcollected at standard conditions, Vw(std).


### Vw(sld)

# =K2 'Vic Vw(sld)

# = 6.684 sef


### 3) Decimal fraction ofmoisture by volume in stack gas, Bws.

Bws 

### =Vwstd 

### I (Vmstd+Vwstd) Bws 

### = 0.134


### 4) Molecularweightofthe stack gas on awet basis, Ms.



### Ms 

### = [((44'%C02) 

### +(32'%02) + 

### (2S'%N2))' (1-Bws) 

### [+ (1S'Bws) 

### Ms= 28.83 Ib/lbmole


### 5) Average stack gas velocity, Vs.



### Vs 

### = Kp' Cp' (dP) , (Ts/Ps'Ms)'.5 Vs 

### = 45.32 Ips
6) Average actual stack gas volumetric flowrate, Qa.

Qa = 

### 60 sec/min**~** 

### Vs 

### *As Qa

# = 226582.1 efm 6416.8 emm 

### 7) Average stack gas dry volumetricfJowrate, Qstd.


### Qsld

# =Qa' (TsldfTs)' (Ps/Psld)' (1-Bws) Qstd

# = 160431.4 dscfm 4543.4 dscmm 

### Page 2

### Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

8) Hydrogen Cyanide Concentration and Emissions Unit No.2 One

M[HCN[

# =M[CN-[(mg) , MW[HCN](mglmmol) 1MW[CN-](mglmmol) 

### Page 3

C[HCN]

# =(M[HCN](mg) , 2.205E-06(1blmg) • 21.85(scf'inHgllbmol'R) , K1 ' 10'6) 1(MW[HCN](lbllbmol) 'Vmsl C[HCN](@corr. 02)

# = C[HCN](ppmV)' [(20.9-corrected 02) 1(20.9-actual %02)] E[HCN]

# =M[HCN](mg)'Qstd(dscfm)' (2.205E-06)(lblmg)' 60(minlhr) 1Vmstd(dscf) E[HCN]

# = C[HCN[(ppmV)' Fd' CF(HCN)' (20.91(20.9-%02))



## < M[HCN]

# = 0.004 mg 

## < C[HCN]

# = 0003 ppmV 

## < C[HCN]

# = 0.002 ppmV (@ 7.0 % 

### 02) 

## < E[HCN]

# = o002 Iblhr 

## < E[HCN]

# = 2.48E-06 IblMMBtu

### 3333-HCN-R2



### Client Project No. Test Location Test Run 

### Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT Vic

# = Vm= 

### Pstatic

# = Pb = 

### Ps

# = Pstd

# = dP

# = dH

# = Tm= 

### Ts

# = Tstd= Dn

# = An

# = y= t= Ds 

### = As= Cp= Kp= K1 

# = K2= 

### K3

# = Fd

# = CF 

### =

[02] [C02]
]N2] 

## AirNova, Inc. EPA Methods 1,2,3A,4,and Modified 26 (Flows, 

### 02/C02, H20,and HCN) 

## Spruance Genco, LLC 

## 3333 Unit No.2 Two 

## 04/20/10 

## 1430-1530

143.3 

### cc 44.725 defEmission Data



### -OA5 in. H20 29.99 in. 

### Hg 29.96 

### in. Hg 29.92 

### in. Hg 

### 07348 in. 

### H20 11.5

1.820 

### in. H20 5399 

### R 6495 

### R 527.7 R Din. 0.000000 sq. 

### ft. 0.99



### 60 min, 10.300 

### ft Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average meter temperature Average stack temperature Standard temperature Nozzle diameter Area ofnozzle onfice Meter calibration factor Duration of sampling time Diameter ofstack 83.323 

### sq. ft. Cross sectional area ofstack 0.84 Pltottube coeffiCient 85.49 ft[(lb/lbmol)*(inHg)]A.5}/[s*R*inH20] Pitottube constant 17.637 R/in.Hg constant 0.047070 cu.ftlml constant 0.0026688 in.Hg-cf/ml-R 9676 scf/MMBtu 7.014E-08 Ib/dsef 

### 1ppmVd

Instrumental Data

4.34 

### %-dry 14.23 

### %-dry

81 43 

### %-dry constant Fuel Factor Conversion Factorfor HeN

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions,Vmstd.

Vmstd =K1*Y * 

### Vm ., 

### (Pb + dH/13.6) I 

### Tm Vmstd

# = 43.575 dscf 

### 1.23 dscm 

### Unit No.2 Two

2)

### Volume ofwatervaporcollected atstandard conditions, Vw{std).
Vw(std)

# =K2 'Vie Vw(std)

# = 6.745 sef 

### 3) Decimal fraction of moisture byvolume in stack gas, Bws.

Bws

# = Vwstd / (Vmstd+Vwstd) Bws= 

### 0.134
4) Molecularweight ofthe stack gas on awet basis, Ms.

Ms

# =[((44'%C02) + 

### (32'%02) + 

### (28'%N2))' (1-Bws)] + 

### (18'Bws) 

### Ms= 

### 28.78 Ib/lbmole


### 5) Average stack gas velocity, Vs.

Vs 

### = Kp' Cp' (dP) , (TsIPs'Ms)'.5 Vs

# = 45.80 Ips
6) 

### Average actual stack gasvolumetric flowrate, Qa.
Qa 

### =60 sec/min"Vs * As Qa 

### = 228983.2 elm 

### 6484.8 cmm
7) 

### Average stack gas dryvolumetric flowrate, Qstd.
Qsld = 

### Qa' (TsldITs], (PsIPstd)' (1-Bws) Qstd

# = 161294.8 dscfm 

### 4567.9 dscmm Page 2

### Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

8) Hydrogen Cyanide Concentration and Emissions 

### Unit No, 2 

## Two

M[HCN[

# =M[CN-](mg) , MW[HCN](mg/mmol) 1

### MW[CN-](mg/mmol) Page 3



### C[HCN] = 

### (M[HCN](mg)'2.20SE-06(lb/mg)' 21.8S(scf'inHg/lbmol'R)' K1 '10"6) 

### 1(MW[HCN](lb/lbmol)' Vmsl C[HCN](@corr. 02) 

### =C[HCN](ppmV)' [(20.9-corrected 02) 1

### (20.9-actual %02)] E[HCN]

# =M[HCN](mg) , Qstd(dscfm) • (2.20SE-06)(lb/mg) • 60(min/hr) 1

### Vmstd(dscf) E[HCN]

# = C[HCN](ppmV)' Fd'CF(HCN)' (20.9/(20.9-%02))



## < M[HCN] = 0.005 

### mg 

## < C[HCN] = 0.004 ppmV 

## < C[HCN] = 0.003 ppmV (@ 70 %02) 

## < E[HCN] = 0.002 Ib/hr 

## < E[HCN] = 309E-06 Ib/MMBtu

### 3333-HCN-R3



### Client 

### Project No. Test Location Test Run 

### Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vic

# = Vm= Pstatic

### = Pb 

### = Ps

# = Pstd

# = dP

# = dH

# = Tm= 

### T5

# = Tstd= 

### On 

### = An

# = y= t

# = Os= As= Cp

# = Kp = 

### K1 

# = K2= K3

# = Fd

# = CF=



### [02[ [C02[
[N2] 

## AirNova, Inc. EPA Methods 1,2,3A,4,and Modified 26 (Flows, 

### 02/C02, H20,and HCN) 

## Spruance Genco, LLC 

## 3333 Unit No.2 Three 

## 04/21/10 0655-1000

Emission Data
159,2 

### cc 47.973 def

-0,45 in. 

### H20 29.87 in. Hg 

### 29.84 in Hg 

### 29.92 in 

### Hg 0.7266 in. 

### H20A.S



### 1.820 

### in. H20 515.9 R 647.2 R 527.7 R Din. 

### 0.000000 sq. ft. 

### 0.99



### 60 min. 

### 10.300 

### ft. Vol. of H20 collected Drygas meter reading Static pressure Barometric pressure Stack pressure 

### EPA Standard pressure Average sq.rtdelta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature 

### Nozzle diameter Area of nozzleorifice Metercalibration factor Duration ofsampling time 

### Diameter ofstack 83.323 sq. 

### ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)"(inHg)]".5}/[s*R"inH20] Pltottube constant 17.637 R/in.Hg 0.047070 cu.fUml 0.0026688 In.Hg-cf/ml-R 9826 sef/MMBtu 7.014E-08 Ib/dscf

### I ppmVd

Instrumental Data

4.95 %-dry 13.86 %-dry

81.19 %-dry constant constant constant Fuel Factor Conversion Factorfor HeN

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1)

### Volume ofgas sampled at standard conditions, Vmstd.

Vmstd =K1"Y

.. Vm

.. (Pb 

### +dH/13.6) I

### Tm Vmstd

# = 48.719 

### dscf 1.38 dscm Unit NO.2 Three

2) 

### Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std)

# =K2 'Vic Vw(std)

# = 7494 

### sct 3) Decimal fraction of moisture byvolume in stack gas, Bws.

Bws =Vwstd I 

### (Vmstd+Vwstd) Bws= 0.133


### 4) Molecularweight ofthe stackgas on a wet basis, Ms.

Ms = 

### [((44'%C02) + 

### (32'%02) + 

### (28'%N2))' (l-Bws)

## I + 

### (18'Bws) Ms

# = 28.76 Ib/lbmole


### 5) Average stack gasvelocity, Vs.

Vs

# =Kp' Cp' (dP) , (Ts/Ps'Msl' 5 Vs = 45.32 

### fps
6) 

### Average actual stack gas volumetric flowrate, Qa.
Qa

# = 60 

### sec/min"Vs 

### *As 

### Qa

# = 226554.2 efm 6416.0 emm 

### 7)Average stack gas dryvolumetric flowrate, Ostd.
Qstd 

### = Qa' (Tstd/Ts)' (Ps/Pstd)' (l-Bws) Qstd 

### = 159653.4 

### dscfm 4521.4 dscmm 

### Page 2

### Client 

### Spruance Genco, LLC Project No. 3333 Test Location Test Run

8) Hydrogen Cyanide Concentration and Emissions Umt No.2 Three



### M[HCN[

# =M[CN-[(mg) " MW[HCN](mg/mmol) 

### 1MW[CN-](mg/mmol) Page 3



### C[HCN] = 

### (M[HCN](mg) " 2 205E-06(lb/mg) " 21.85(scf"inHg/lbmol"R) " K1 " 10'6) 1

### (MW[HCN](lb/lbmol) "Vmsl C[HCN](@corr 02)

# = C[HCN](ppmV)" [(20.9-corrected 02) 1

### (20.9-actual %02)] E[HCN]

# =M[HCN](mg) " Qstd(dscfm) " (2.205E-06)(lb/mg) "60(min/hr) 

### 1Vmstd(dsc0 E[HCN]

# = C[HCN](ppmV)" Fd" CF(HCN)' 

### (20.9/(20.9-%02))



## < M[HCN] = 

## < C[HCN]

# = < C[HCN]

# = < E[HCN] 

### = 

### < E[HCN] = 

### 0.005 mg 0.003 ppmV 0.003 ppmV 0.002 Ib/hr 2 91 E-06 Ib/MMBtu 

### (@ 

### 7.0 % 

### 02)3333-7E

Client Project No. Test Location Test Date 

### Spruance Genco, llC 3333 Unit No.2

- Metallic HAPs 04/22/10

Parameter: Instrument Span f% 02): 

### Oxygen 21,96

ActualCalibralion Gas Value f% 

### 02t AnalyzerCalibration Response 

### (% 02): AnalvzerCalibration Error(% Span):

Zero**S~tem** Calibration Gas Apparent Init. Sys. Init. Sys. Final

### S\,:§. FinalSys.

Stack Calib. C{Ji. Bias Calib. Cal. Bias 

### Run Conc. Response f% span) Response (% span)

1 

### 4.86 0.02 0.09 0.01 0.05 2 

### 4.43 0.01 0.05 0.03 0.14 0 0.00 0.03 0.14 0.00 0.00 0 0.00 0.00 0.00 0.00 0.00 0 0.00 0.00 0.00 0.00 0.00 0 0,00 0.00 0.00 0.00 0.00 0 0.00 0.00 0.00 0.00 0.00 0 0.00 0.00 0.00 0.00 0.00 0 0.00 0.00 0.00 0.00 0.00 0 0.00 0.00 0.00 0.00 0.00 0 

### 0.00 0.00 0.00 0.00 0.00 0 0.00 0.00 000 000 0.00 

### AirNova, Inc. EPA Method 7E Calculations (Cal. Error, Bias Driftand Bias Adjustment)

zero 

### 0.00 0.00 0.00 AnalYZerCalib. Gases**~** mid N/A 12.46 N/A 12.33 

### 0.00 -0.59 high 

### 21.96 21.74 -1,00

Ugscale**S~stem** Calibration Gas Calib. Init. Sys. Init. Sys. Final Sys. FinalSys. Drift Calib. Cal. Bias Calib. Cal. Big§. (% span) Response (% spanl Response (% span)

-D.05 

### 12.34 0.05 12.37 0.18 0.09 12.37 0.18 12.34 0.05 -0.14 12.34 0.05 0.00 -56.15 0.00 0.00 -56.15 0.00 -56.15 0.00 0.00 -56.15 0.00 -56.15 0.00 0.00 -56.15 0.00 -56.15 000 0.00 -56.15 0.00 -56.15 0.00 0.00 -56.15 0.00 -56.15 0.00 0.00 -56.15 0.00 -56.15 0.00 0.00 -56.15 0.00 -56.15 0.00 0.00 -56.15 0,00 -56.15 0.00 0.00 -56.15 0.00 -56.15 Upscale Svs. Cal. Gas 

### 1246 12.33

Calib. DnJt f% span)



### 0.14 -0.14 -56.19

0.00 000 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Page 1

Actual Steck Conc.



### 4.89 4.45 -0.03 

### ERR ERR ERR ERR ERR ERR ERR ERR ERR

### 3333-7E

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit No_ 2 - Metallic HAPs 04/22110

Parameter: 

### Carbon Dioxide Instrument Span (% G02!: 

### 17.83

Actual Calibration Gas Value (% C02L AnalvzerCalibration Response (% G02): AnalyzerCalibration Error(% Span!:

Zero Sllstem Calibration Gas Apr1.arent Init. S\"s_ Init. S\"S. FinglS!!s. FinalS\::s_

Stack Galib. Cgf. BigS Calib. Cal. Bias 

### Run Gonc. Response (% span) Response (% span)

1 

### 13.92 0.06 0.84 0.21 1.68 2 14.19 0.21 1.68 -0.01 0.45 0 0.00 -0.01 0.45 0.00 0.50 0 0.00 0.00 0.50 0.00 0_50 0 0.00 000 0.50 0.00 050 0 0.00 0.00 0.50 0.00 050 0 

### 0.00 0.00 0.50 0.00 0.50 0 0.00 0.00 0.50 0.00 0.50 0 0.00 0.00 0.50 0_00 0.50 0 0.00 0.00 0,50 0_00 0.50 0 0.00 0.00 0.50 0.00 0.50 0 0.00 0.00 0.50 0.00 0.50 

### AirNova, Inc. Page 2 EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Anal\::zerCalib. G§:ses**W2~cale** 

### zero 

### !ill!i mid high S\::s. Cal.**Gg~** 

### 0.00 NfA 

### 12.39 17.83 12.39 -009 NfA 

### 12.26 17.74 12.26 -0.50 0.00 -0.73 -0 50**U~scale** Sy:stem Calibration Gas Calib. fnit S\::s. Init. Svs. Final Sys. Final S\::s. Cafib. Actual Drift Galib. Cal. Bias Calib. Gg/. Bias Drift !ltil2; (% span! Response (% span) Response (% span) (% span) Conc_



### 0.84 12.29 0.17 12.32 0_34 0.17 14.03 -1.23 12.32 0.34 12,32 0.34 0.00 14.29 0.06 12.32 0.34 0.00 -68.76 -69.10 0.01 000 0.00 --68,76 0.00 -68.76 0.00 

### ERR 0_00 0.00 -68.76 0.00 -68.76 0_00 

### ERR 0_00 0.00 -68.76 0.00 -68,76 0_00 

### ERR 0.00 0.00 -68.76 0.00 -6876 0.00 

### ERR 0.00 0.00 -68.76 0.00 -68_76 0.00 

### ERR 0.00 0.00 -68.76 000 -68.76 0.00 

### ERR 0.00 0_00 -68.76 0.00 -68.76 0.00 

### ERR 0.00 0_00 -68.76 0.00 -68.76 0.00 

### ERR 0.00 0.00 -68,76 0.00 -68.76 0.00 

### ERR3333-7E-R3

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit No.2

- Metallic HAPs 04/23/10

Parameter: 

### Oxygen Instrument Soan (% 

### 02): 21.96
Actugl Calibration Gas Value (% 

### 02): AnalyzerCalibration Resflonse (% 

### 02): AnalyzerCalibratIon Error(% Span):

Zero**S~stem** Calibration Gas Aflgarent Init. Sys. Init. Sys. Final**S~s.** Final Sys.

stack Ca/lb. Qa/. Bias Galib. Cal. Bias 

### Run Cone. Response r% sgan) Resflonse t% sflan)



### 3 4.95 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0,00 0.00 -0.05 000 -0.05 0 0.00 0,00 -0.05 0.00 -0.05 0 0.00 0.00 -0,05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -005 0 0.00 0.00 -0.05 0.00 -0.05 0 0,00 0.00 -0.05 0.00 -0,05 0 0,00 0.00 -0.05 0.00 -0.05 

### AirNova, Inc. Page 1 EPA Method 7E Calculations (Cal. Error, Bias Driftand Bias Adjustment)**Anal~zer** Calib.**Ga~§:s Ufl~~g/e**  zero low mid high ,svs. Cal. Gas 

### 0.00 NfA 

### 12.46 21,96 12.46 0.01 NfA 

### 12.38 21.62 12.38 0.05 0.00 -0.36 -1.55

Ugscale Sllstem Calibration Gas Cg/ib. Init. Sys. Init. Sys. Final Sys.**FinaIS~.** Calib. Actual Drift Galib. Cal. Bif!.S Galib. Gal.**Bia~** Drift Stack t% S!)gn) Resflonse f% sQf!.n) Resgonse (% span) r% span) Gonc.



### 000 12.38 0.00 12.45 0.32 032 4.97 

### 000 12.45 0.32 0.00 -56.38 -56.69 0.00 0.00 0.00 -56.38 0.00 -5638 0.00 

### ERR 0.00 0.00 -56.38 0.00 -56.38 0.00 

### ERR 0.00 0.00 -56.38 0.00 -56,38 0.00 

### ERR 0.00 0.00 -56.38 000 -56.38 0.00 

### ERR 0.00 000 -56.38 0.00 -56.38 0.00 

### ERR 000 0.00 -56.38 0.00 -56.38 0.00 

### ERR 0.00 0.00 -56.38 0.00 -56.38 0.00 

### ERR 0.00 0.00 -56.38 0.00 -56.38 0.00 

### ERR 0.00 0.00 -56.38 0.00 -56.38 000 

### ERR 0.00 0.00 -56.38 0.00 -56.38 0.00 

### ERR

### 3333-7E-R3

Client ProjectNo. TestLocation TestDate Spruance Genco, 

### LLC 3333 Unit 

### No.2

- Metallic HAPs 04/23/10

Parameter: InstrumentSoan (% C02): 

### Carbon Dioxide 17.83

Actual Calibration Gas Value (% 

### C02): Ana/,,-zerCalibration Responsft. t% C02): AnafyzerCaJibration Error(% Span):



### ZerQ**S~tem** 

### Calibration Gas AQQarent Init.**S~.** Init. Sys. Final

### S):::s.**FinaIS~.**

Stack**~** Gal. Bias Gallb. Gal Bias Run Cone. ResQonse (% span) ResQonse (% span)



### 3 13.78 0.03 -006 0.10 0.34 0 0.00 0.10 0.34 0.00 -0.22 0 0.00 0.00 -022 0.00 -0.22 0 0.00 0.00 -0.22 0.00 -0.22 0 0.00 0.00 -0.22 0.00 -0.22 0 0.00 0.00 -0.22 0.00 -0.22 0 0.00 0.00 -0.22 0.00 -0.22 0 0.00 0.00 -0.22 0.00 -0.22 0 0.00 0.00 -0.22 0.00 -0.22 0 0.00 0.00 -0.22 0.00 -0.22 0 0.00 0.00 -022 0.00 -0.22 0 0.00 0.00 -0.22 0.00 -0.22 

### AirNova, Inc. Page 2 EPA Method 6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

Anal,,-zerCaNb. Gases Uusealft.
zero low mid high S,,-s. Cal. Gas 

### 0.00 N/A 

### 7.49 1783 7.49 0.04 N/A 

### 7.52 17.83 7.52 0.22 0.00 0.17 0.00

!.!gscale Sxstem Calibration Gas CaNb. lnit**~):::s.** Init. S):::s. Final S):::s. Final S):::s. Calib. Actual Drift Calib. Gal. Bias**~** 

### Cal. Bias Drift Slack (% span) ResQonse (% spgn) Response f% span) (% soan) Cone.



### 0.39 7.52 0.00 7.61 050 0.50 13.70 -0.56 7.61 0.50 0.00 -42.18 -42.68 -0.10 0.00 0.00 -4218 0.00 -42.18 000 

### ERR 0.00 0.00 -42.18 000 -42.18 0.00 

### ERR 0.00 0.00 -42.18 0.00 -42.18 0.00 

### ERR 0.00 0.00 -42.18 0.00 -42.18 0.00 

### ERR 0.00 0.00 -42.18 0.00 -42.18 0.00 

### ERR 0.00 0.00 -42.18 0.00 -42.18 0.00 

### ERR 0.00 0.00 -42.18 0.00 -42.18 0.00 

### ERR 0.00 0.00 -42.18 0.00 -4218 0.00 

### ERR 0.00 0.00 -42.18 0.00 -42.18 000 

### ERR 0.00 0.00 -42.18 0.00 -42.18 0.00 

### ERR

### 3333-PM2.5-R1

Client Project No. Test Location Test Run Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT
INPUT INPUT INPUT
INPUT

INPUT INPUT 

### Vic

# = Vm= Pstatic = Pb**~** 

### Ps 

### = Pstd = 

### dP**~** 

### dH**~** 

### Tm= Ts

# = Tstd= Dn

# = An =**y~** 

### tr

### = Os= As=**Cp~** 

### Kp**~** 

### K1**~ K2~**  

### K3= C1 

# = C2

# = C3**~** 

### C4= C5= C6= 

### 81 

# = Fd

# =

[02J [C02J [N2J AirNova, Inc. EPA Methods 1,2,3,4, OTM 27 and 202 (Flows, 

### 02/C02, H20, PM2.S and CPM) Spruance Genco, LLC 

### 3333 Unit No.2 One 

### 04122110 0647·1318
Emission Data


### 406.3 cc Vol. of H20 collected 134.716 dcf Dry gas meter reading -0.45 in. H20 Static pressure 29 81 in Hg Barometric pressure 2978 in. Hg Stack pressure 29.92 in. Hg EPA Standard pressure 0.7715 in. H20 ".5 Average sq.rt delta P

0.390 in. H20 Average draft gauge reading 523.9 R Average metertemperature 6492 R Average stack temperature 5277 R Standard temperature 0.180 in. Nozzle diameter 0000177 sq. ft. 

### Area ofnozzle orifice 0.99 Metercalibration factor, gamma

382 min. Duration ofsampling time 10.300 

### ft. Diameter ofstack

83.32 sq. ft. 

### Cross sectional area of stack

0.84 Pitot tube coefficient 85.49 ft[(lb/lbmolninHg)J'.5)/[s'R'inH20J Pilot tube constant 

### 17.637 R/in.Hg constant 0.047070 cu.ftlml constant 0.0026688 in.Hg·cf/ml·R constant

-150.3162 upoise Viscosity constant

13.4622 upoise/R"0.5 Viscosity constant 3861530 upoise/R"2 Viscosity constant 0.591123 upoise Viscosity constant

91.9723 upoise Viscosity constant 1.51761E-05 upoise/R"2 Viscosity constant 0.15625 Constant 9828 dscflMMBtu Fuel Factor
Instrumental Data


### 4.89 %-dry 14.03 %·dry 81.08 %-dry Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project 

### No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations Unit No.2 One

1) DryGas Volume atstandardconditions, Vms (EPA aTM27 Equation 27).


### Vms =K1'Y'Vm' (Pb + 

### dHI13.6) 

### ITm Vms

# = 133.980 dscf 

### 3.794 dscm 2) Drygas sampling rate atstandardconditions, OsST (EPA aTM27 Equation 28).
OsST

### =Vms 

### Itr 

### QsST= 

### 0.351 dscfm 

### 0.010 dsem 

### I min. 3) Volume ofwater vaporcondensedatstandardconditions, Vws (EPA aTM27 Equation 29).
Vws

# =K2 *Vle Vws= 

### 19124 sef 4) Decimalfraction ofmoisture byvolume in stackgas, Bws (EPA aTM27 Equation 30).
Bws = Vwstd 

### I (Vmstd+Vwstd) 

### BW5

# = 0.125 5) Mo/ecularweightofthe stackgas on a wetbasis, Mw (EPA aTM27 Equations 

### 1 &2).


### Mw = [((44'%C02) + 

### (32'%02) + 

### (2S'%N2))' (1-Bws) 

## I+ 

### (1S'Bws) Mw = 

### 28.89 Ib/lbmole 6) Gas sampling rate atactual Cyclone conditions, Os (EPA aTM27 Equation 31).


### Qs = (PsldlTsldrQsST' (1/(1-Bws))'(Ts/Ps) Os = 

### 0495 8efm 7) Average stackgas velocity, Vs (EPA aTM27 Equation 11).


### Vs = Kp'Cp' (ave of (dPyO.5)' (Ts/Ps'Mw)'O.5 Vs = 

### 48.13 fps 8) Average actualstackgas volumetnc f/owrate, Oa.
Oa = 

### 60 sec/min"Vs * 

### As Oa

# = 240633.6 efm 

### 6814.7 cmm 9) Average stackgas drystandard volumetric f/owrate, Qstd 

### Qsld = Qa' (TsldlTs)' (Ps/Psld)' (1-Bws) Ostd = 

### 170347.2 dscfm 

### 48242 dscmm Page 2

### Client Project No. Spruance Genco, LLC 3333 

### Test Location Test Run

Calculations (cont.) Unit No 2 One 

### Page3

10) Analyticaldata
Cvclone andFilterFractions (EPA Method orM27); 

### M1) Instack quartz microfibre filter, <2.5um
0.0054 9 PM <2.5 filter netwt M2-4) Cyclone acetone washes


# o0000 9 actual mass of >2.5, Containers 2&3 0.0006 9 actual mass of 

### <1=2.5um, Container 4 0.0000 9 acetone blank netwt 

# omLvolume 100 mL volume 100 mLvolume
0.0000 9 blank corrected mass of >2.5um, Containers 2&3 = M2&M3 0.0006 9 blank corrected mass of</=2.5um, Contamer 4 = M4
Condensible Particulate Matter(CPM) Fractions (EPA Method202): 

### M5) Back HalfAqueous Wash
0.0076 9 actual sample mass 0.0003 9 aqueous blank mass 300 ml blank vol. 300 ml Sample volume
0.0073 9 condensible aqueous PM M6) Back Half MeCI2 Extraction Portion
0.0014 9 extraction netwt 0.0000 9 MeCI2 blank net wt 300 ml blank vol. 300 ml MeCI2 extraction volume
00014 9 condensible organic PM M[CPM] = blank corrected mass of Total CPM, M5 

### & M6 (in grams) M[CPM] = 0.0087 9 CPM 11) Particulate Concentrations, 

### C (EPA OTM27and EPA 202).

Equation 43 Equation 45

EPA 202 

### C[totalsus] = M 1(g)+M2(g)+M3(g)+M4(g)·15.43(grainslg)Nmstd(dscn= C[PM2.5sus] = M1 (g) + M4(g) • 15.43(grainslg) 1Vmstd(dscn = C[CPM] = M[CPM](g) • 15.43(grainslg) 1Vmstd(dscf) where 15.43 = 7000/453592'1000 C[PMtotal] = C[PMtotalsus] + C[CPM] C[PM2.5total] = C[PM2.5sus] + C[CPM] 0.0007 gr/dscf PMsus 0.0007 gr/dscf PM2.5sus 0.0010 gr/dscf CPM
0.0017 gr/dscfTotal PM 0.0017 gr/dscfTotal PM2.5

### Client Project No. 

### Spruance Genco, LLC 3333



### 12) Particulate Emission Rates, 

### E. Test Location Test Run

Calculations (cont,) Unit No.2 One

E[lb/hr[ = 

### C[](gr/dscf) • (1 Ib/7000 gr) • Qstd(dscfm) • 60(min/hr) E[lb/MMBtu] 

### = C[](gr/dsc0 • (1.lb/7000 gr) • Fd(dscf/MMBtu) • (20.9/20.9-%02) 

### E[totalsus] = 1.01 

### Ib/hrtotal sus PM E[totalsus] = 

### 0.0013 

### IbJMMBtu total sus PM E[PM2.5sus]

# = 1.01 

### Ib/hr PM2.5sus = 

### 40.8 %ofTotal 

### PM2.5 E[PM2.5sus]

# = 0.0013 

### IbJMMBtu PM2.5sus = 

### E[CPM]

# = 1.46 Ib/hr CPM 

### 59.2 %ofTotal PM2.5 E[CPM]

# = 0.0018 Ib/MMBtu CPM E[PMtotal]

# = 2.47 

### Ib/hrtotal PM E[PMtotal[

# = 0.0031 

### Ib/MMBtu total PM E[PM2.5total]

# = 2.47 

### Ib/hrtotal PM2.5 E[PM2 5total]

# = 0.0031 

### Ib/MMBtu total PM2.5 

### 13) PercentIsokinectic Sampling, %1 (EPA OTM

### 27Equation 40).
% I = 

### [100*Ts*Vms*Pstd) I 

### (60*Vs*tr*An*Ps"(1-Bws)*Tstd) % I = 

### 97.08 

### 14) Stack Gas Viscosity, u(EPA OTM

### 27Equation 3).

u = 

### C1 + 

### C2*(TsI\0.5) + 

### C3*(Ts"-2) + 

### C4*(%02) - (C5*Bws) + 

### C6*Bws*(TsIl2) u = 

### 194.1 micropoise Page4

### Client Project No. Spruance Genco, LLC 3333 

### Test Location Test Run

Calculations (cont.) 1S) 

### Test Condition Reynolds number, Nre (EPA OTM27 

### Equation 8).
Nre

# = 8.64"10A

### S"(Ps"Mwrrs)"'(Qs/u) 

### Nre

# = 2923 Unit No, 

### 2 One



### 16) ActualParticle Cut**~iameter** 

### for Cyclone 1.050 (EPA OTM27 

### Equation 32).
OSO = 81 • ([Ts 

### 1(Mw" Ps)['2091)" ((u 

### 105)'.7091) 050 = 

### 10.16 um 

### 17) Actual Cunningham Correction Factorbasedon 

### Op = 

### 2.5um. C 

### (EPA OTM27 

### Equation 4),
C = 1+ 0.00S7193" (u/(Ps"Op))" (Ts/Mw)·O.S C = 1.0707 

### 18) InitialOSO 

### for Cyclone IVbasedon testcondition Reynolds numberfrom OTM27 

### Equation 8.
If Nre 

### < 3162, use Equation 33 which results in 050 for IV

### = If Nre 

### >= 3162, use Equation 34 which results in D50 for IV = 

### Initial D50 2.21 2.1S 

### Equation 33 Equation 34 Equation 35 OSO = 0.0024302"(u/Os)Al.1791"(1/C)AO.5"(Ts/(PS"Mw))AO.6790 OSO = 0 019723"(u/0s)"0.80S8·(1/C)·0.5"(Ts/(Ps·Mw)),0.30S8 Cr= 1 + 0.0057193"(u/(Ps"050))"(Ts/Mw)AO.S 

### 19) Re-estab/ishedOSO 

### forCyc/one IV, 050-1. Page 5

Re-established Cunningham, Cr 1.0798 1.0822

IfNre 

### < 3162, use Equation 36 which results In 050 for IV

# = IfNre 

### >= 3162, use Equation 37 which results in D50 for IV

# = Recalculated Cut Diam. 050-1 2.20 2.14 

### Equation 36 Equation 37 OSO-1 = 0.0024302"(u/Os),1.1791"(lICr),0.S"(Ts/(Ps·Mw)),0.6790 OSO-1 = 0.019723"(u/Os)·0.8058"(lICr)·0.S"(Ts/(Ps"Mw))AO.30S8 

### 19) Establishmg "Z" value, 

### Z.
If Equation 36 was used, then If Equation 37 was used, then Z= OSO-11 OSO= Z = OSO-1 

### 1OSO =
If 0.99 < 

### Z < 

### 1.01, then 050-1 is best cutdiameterestimate, If0.99 > 

### Z > 

### 1.01, then repeat calcs for Cr using 050-1 1.00 0.99

### 3333-PM2 

### 5-R2

Client Project No. 

### Test Location Test Run Test Date 

### TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT
INPUT INPUT INPUT
INPUT

INPUT INPUT Vic

# = Vm= Pstatic 

### = Pb

# = Ps

# = Pstd

# = dP

# = dH

# = Tm= Ts

# = Tstd= On 

### = An

# = y= 

### tr

# = Ds= As= Cp

# = Kp= K1 

# = K2= K3= 

### C1= 

### C2 = 

### C3= C4= C5= 

### C6 = 

### 81 

# = Fd 

### =

[02] [C02] [N2] AirNova, Inc. EPA Methods 1,2,3,4, OTM 27 and 202 

### [Flows, 021C02, H20, PM2.S and CPM) Spruance Genco, LLC 

### 3333 UnitNo_ 2 Two 

### 04122110 

### 1335-1943
Emission Data
387.9 

## cc Vol. of H20 collected 129,724 dcf 

### Dry gas meter reading -0.45 in. 

### H20 Static pressure 

### 29,81 

### in. Hg Barometric pressure 29,78 

### in. Hg Stack pressure 

### 29.92 

### m. Hg EPA Standard pressure 0,7130 

## m. H20"5 Averagesq.rtdelta P

0.390 In. 

### H20 Average draft gauge reading 

### 537.7 R Average meter temperature 650.5 R Average stack temperature 527.7 R Standard temperature 0.180 in. Nozzle diameter 0,000177 

### sq, 

### ft Area of nozzle onfice 

### 0.99 Metercalibration factor, gamma 359.2 min. Duration ofsampling time 10.300 ft. 

### Diameterof stack

83.32 sq ft. 

### Cross sectional area ofstack

0.84 Pitottube coefficient 

### 85.49 ft[(lbllbmol)"(inHg)j'.5)I[s·R·inH20] Pitottube constant 17.637 R/in.Hg constant 0.047070 cu.ftlml constant 0.0026688 in.Hg-cf/ml-R

-150.3162 upoise

13.4622 upoise/RflO.5 3861530 upoise/Rfl2 0.591123 upoise

91.9723 upoise 1.51761E-05 upoise/Rfl2 

### 0.15625 9676 dscf/MMBtu
Instrumental Data
4.45 %-dry 14.29 %-dry 81.26 %-dry constant Viscosity constant Viscosity constant Viscosity constant Viscosity constant Viscosity constant Viscosity constant Constant Fuel Factor

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations Unit No.2 

### Two

1) Dry

### Gas Volume atstandardconditions, Vms (EPA aTM

### 27 Equation 27).


### Vms =K1'Y'Vm ' (Pb 

### + dH/13.6) ITm Vms = 125.696 dscf 3.560 dscm 

### 2) Drygas 

### sampling rate atstandardconditions, OsST 

### (EPA aTM

### 27 Equation 28).
QsST

# = Vms 

### Itr 

### QsST= 0.350 dsefm 

### 0.010 dsem 

### I min. 

### 3) Volume ofwater vaporcondensedatstandardconditions, Vws (EPA OTM

### 27 Equation 29).


### Vws

# =K2 *Vle Vws= 18.258 sef 4) Decimalfraction ofmoisture byvolume in stackgas, Bws (EPA aTM

### 27 Equation 30).


### Bws

# = Vwstd 

### I (Vmstd+Vwstd) Bws

# = 0.127 5) Molecular weight

### ofthe stackgas on 

### a wet

### basis, Mw (EPA OTM

### 27 Equations 

### 1&2).
Mw = [ ((44'%C02) 

### + (32'%02) 

### + (28'%N2)) , (1-Bws) 

## I+ (18'Bws) Mw

# = 28.88 Ib/lbmole 6) Gas sampling rate atactualCyclone conditions, Os 

### (EPA OTM

### 27 Equation 31). 

### Qs = (PstdlTstd),QsST' (1/(1-Bws))'(Ts/Ps) 

# as = 0.496 acfm 7) Average stackgas 

### velocity, Vs 

### (EPA OTM

### 27Equation 11).


### Vs = Kp' Cp' (ave 01 

### (dP)'0.5)' (Ts/Ps'Mw)'0.5 Vs

# = 44.53 fps 

### 8) Average actualstackgas vo/umetflc f/owrate, 

### Qa
·Qa

# = 60 sec/min * 

### Vs *

### As Qa = 222605 9 elm 6304.2 cmm 9) Average stackgas drystandard volumetric f/owrate, Qstd. 

### Qstd = Qa • (TstdlTs) , (Ps/Pstd) , (1-Bws) Qstd

# = 156916.5 dscfm 4443.9 dscmm 

### Page 2

### Client Project No. Spruance Genco, LLC 3333 Test Location Test Run



### Calculations (cont.) Unit No.2 

### Two Page 3

10) Analyticaldata
Cvclone andFilterFractions (EPA Method OTM27). 

### M1) Instack quartz microfibre filter, <2.Sum
0.0213 9 PM <2,S filter net wi M2-4) Cyclone acetone washes
0_0000 9 actual mass of>2 5, Containers 2&3 0.0014 9 actual mass of <1=2.5um, 

### Container 4 0.0000 9 acetone blank netwt 

# omL volume 100 mL volume 100 mLvolume
0.0000 9 blank corrected mass of >2 5um, Containers 2&3

# =M2&M3 0.0014 9 blank corrected mass of <1=2.Sum, 

### Contamer 4 = 

### M4
Condensible Particulate Matter(CPMJ Fractions (EPA Method202): 

### MS) Back HalfAqueousWash
0.0136 9 actual sample mass 0.0003 9 aqueous blank mass 300 ml blankvol. 300 ml Sample volume 0,0133 g condensible aqueous PM M6) Back Half MeCI2 Extraction Portion
0.0015 9 extraction netwt 0.0000 g MeCI2 blank net

### wt 300 ml blank vol 300 ml MeCI2 extraction volume
0.0015 9 condensible organic PM M[CPMJ = 

### blank corrected mass of Total CPM, M5 

### & M6 (in grams) M[CPM[ = 0.0148 9 CPM 11) Parilculate Concentrations, 

### C (EPA OTM27andEPA 202).

Equation 43 Equation 45

EPA 202 

### C[totalsus] = M1(g)+M2(g)+M3(g)+M4(g)'1543(grainslg)Nmstd(dscD= C[PM2.5sus] = M1(g) + M4(g) • 1543(grainslg) I Vmstd(dscD = C[CPM] = M[CPM](g) • 1543(grainslg) I Vmstd(dscf) where 15.43

### = 70001453592*1000 

### C[PMtotal] = C[PMtotalsus] + C[CPM] C[PM2.5total] = C[PM2.5sus] + C[CPM] 0.0028 gr/dscf PMsus 0,0028 gr/dscf PM2,5sus 0.0018 gr/dscfCPM 0,0046 gr/dscfTotal PM 0.0046 grJdscfTotal PM2.5

### Client Project No. 

### Spruance Genco, LLC 3333



### 12) Particulate Emission Rates, E. Test Location Test Run

Calculations (cont.) 

### Unit No.2 

## Two

E[lblhr[

# = C[[(grldscD' (11b17000 gr)' Qstd(dscfm)'60(minlhr) E[lbIMMBtu]

# = C[](grldscD • (1 Ibl7000 gr) • Fd(dscfIMMBtu) • (20.9120.9-%02) 

### E[totalsus1 = 

### 3.7S 

### Ib/hr total sus PM E[totalsusj 

# = 0.0049 

### IbfMMBtu total sus PM E[PM2.Ssus1

# = 3.7S 

### Ib/hr PM2.Ssus = 

### 60.S % 

### ofTotal PM2 S E[PM2.Ssus]

# = 0.0049 

### Ib/MMBtu PM2.Ssus = 

### E[CPM]

# = 2.44 Iblhr CPM 

### 39.S % 

### ofTotal PM2 S E[CPM]

# = 0.0032 

### Ib/MMBtu CPM E[PMtotal]

# = 6.19 

### Ib/hrtotal PM E[PMtotal]

# = 0.0081 

### IbfMMBtu total PM E[PM2 Stotal[

# = 6.19 

### Ib/hrtotal PM2.S E[PM2.Stotal]

# = 0.0081 IblMMBtu total PM2.S 

### 13) Percent Isokinectic Sampling, %1 (EPA OTM

### 27Equation 40).


### % I = 

### [100"'Ts*Vms"'Pstd) f**(60"'Vs*tr*An*Ps~(1-Bws)*Tstd)** 

### %1= 10S.15 

### 14) Stack Gas Viscosity, u(EPA OTM

### 27Equation 3).

u = 

### C1 + 

### C2*(TsII.0.S) + 

### C3*(TslI.-2) + 

### C4"(%02) - (CS*Bws) + 

### CS"Bws*{TsIl2) 

### u = 

### 193.9 micropoise Page 4

### Client Project No. Spruance Genco. LLC 

### 3333 Test Location Test Run

Calculations (cont.) 15) Test Condition Reynolds number, Nre (EPA OTM

### 27 Equation 8).


### Nre

# = 8.64*101\5*(Ps*Mw/Ts)*(Qs/u) Nre

# = 2924 Unit NO.2 

### Two

16) ActualParticle CutDiameterfor Cyclone I, 050 (EPA OTM

### 27Equation 32).


### 050

# =61 ' ( [Ts 1( 

### Mw' Ps)['.2091) • ( (u 1

### OsY.7091) 050

# = 10.15 um 17) Actual Cunningham Correction Factorbasedon Dp = 

### 2.5um, 

### C (EPA OTM

### 27 Equation 4)


### C 

### = 1+ 0.0057193' (u/(Ps'Op))' (Ts/Mw)'O 5 C 

### = 1.0707 18) Initial 050 for Cyclone IVbasedon testcondition Reynolds numberfrom OTM

### 27Equation 8.


### IfNre < 

### 3162. use Equation 33 Which results in 050 for IV

# = If Nre >= 

### 3162, use Equation 34 which results in 050 for IV = 

### Initial 050 

### 2.21 215 Equation 33 Equation 34 Equation 35 

### 050

# = 0.0024302'(u/OsY1.1791·(1IC)'OS(Ts/(Ps'Mw)),0.6790 050

# = O.019723'(u/Os)'0.8058'(lIC)'OS(Ts/(Ps'Mw)),0.3058 Cr

# =1 + 00057193'(u/(Ps'050)),(Ts/MwYO.5 19) Re-established050 for Cyclone IV, 050-1. 

### Page 5

Re-established Cunningham. Cr 

### 1.0800 1.0824

IfNre < 

### 3162, use Equation 36 which results in 050 for IV

# = If Nre >= 

### 3162, use Equation 37 which results in 050 for iV

# = Recalculated Cut Oiam, 050-1 

### 2.20 2.13 Equation 36 Equation 37 

### 050-1 = 

### 0.0024302'(u/Os)'1.1791'(lICr)'OS(Ts/(Ps·Mw))'0.6790 050-1 

# = 0.019723·(u/OsYO.8058'(1/Cr)'0.5'(Ts/(Ps'Mw)),0 3058 19) Establishing "Z" value, 

### Z.
If Equation 36 was used, then Z

# =050-11 OSO 

### = If Equation 37 was used, then Z

# =050-11 OSO 

### =
If 0.99 < 

### Z < 

### 1.01. then 050-1 is best cut diameterestimate. If0,99 > 

### Z > 

### 1.01, then repeat cales for Cr using 050-1 

### 1.00 0.99

### 3333-PM2.5-R3



### Client Project No. 

### Test Location 

### Test Run Test Date 

### Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT
INPUT INPUT INPUT
INPUT

INPUT INPUT Vic

# = Vm= Pstatic

### = Pb = 

### Ps

# = Pstd

# = dP

# = dH

# = Tm= Ts

# = Tstd= 

### Dn= An

# = y= tr= Os

# = As= Cp= Kp= K1 

# = K2= 

### K3= C1= 

### C2 = 

### C3

# = C4= 

### C5 = 

### C6

# = 81 

### = Fd

# =

[02] [C02] [N2] 

### AirNova, Inc. EPA Methods 1,2,3,4, OTM 27 and 202 

### (Flows, 02/C02, 

### H20, PM2.5 and CPM) Spruance Genco, LLC 3333 

### UnitNo.2 

### Three 04/23/10 0600-1210



### 377.7 

## cc Emission Data

131.008 

### def**~O.45** in. 

### H20

29.90 

### in. Hg 29.87 in. Hg 

### 29.92 

## In. Hg 0.7352 in. 

### H20 

### '\5

0.390 

### in. H20 528.1 R 650.8 R 5277 R 

### 0.180 in. 0.000177 sq ft. 0.99 

### 370.7 min. 10.300 ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area ofnozzle orifice Metercalibration factor, gamma 

### Duration ofsampling time Diameter ofstack 83.32 sq. 

### ft. Cross sectional area of stack

0.84 Pitot tube coefficient 85.49 

### ft[(lb/lbmolr(inHg)]'.5}/[s·WinH20] Pitot tube constant 17.637 R/in.Hg constant 0.047070 cU.fVml constant 0.0026688 in.Hg-cf/ml-R constant

-150.3162 upoise Viscosity constant

13.4622 upoise/R"0.5 Viscosity constant 3861530 upoise/R"2 Viscosity constant 0.591123 upoise Viscosity constant

91.9723 upoise Viscosity constant 1.51761E-05 upoise/R"2 Viscosity constant 0.15625 Constant 9826 dscf/MMBtu Fuel Factor
Instrumental Data


### 4.97 %-dry 1370 %-dry 

### 81.33 %-dry 

### Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations 

### Unit No.2 Three



### 1) Dry

### Gas Volume atstandardconditions, Vms (EPA orM

### 27 Equation 27).


### Vms =K1*

### Y*Vm * 

### (Pb + dH/13.6) I

### Tm Vms 

### = 129.633 dscf 3,671 dscm 2) Dry

### gas sampling rate atstandardconditions, QsST(EPA OTM

### 27 Equation 28).


### OsST

### =Vms I

### tr QsST= 0.350 dscfm 0.010 dscm I 

### min. 3) Volume 

### ofwater vaporcondensedatstandardconditions. Vws (EPA OTM

### 27 Equation 29).


### Vws = 

### K2 *Vic Vws= 

### 17.778 scf 

### 4) Decimalfraction ofmoisture byvolume in stackgas, Bws (EPA OrM

### 27 Equation 30).


### Bws 

### =Vwstd I 

### (Vmstd+Vwstd) Bws= 0.121 5) Molecular weightofthe stackgas on 

### a wetbasis, Mw (EPA OTM

### 27 Equations 

### 1 &2).
Mw = [((44'%C02) + 

### (32'%02) + 

### (2S'%N2))' (1-Bws) [+ 

### (1S'Bws) Mw = 28.90 Ib/lbmole 6) Gas sampling rate atactual Cycfone conditions, 

### Os (EPA OTM

### 27 Equation 31).


### Qs = (PstdlTstd),QsST ' (1/(1-Bws))'(TsJPs) Os = 0.491 acfm 7) Average stackgas velocity, Vs (EPA OrM

### 27 Equation 11).


### Vs = Kp' Cp' (ave of (dPI'O.5)' (Ts/Ps'Mw)AO.5 Vs = 45,85 fps 8) Average actualstackgas volumetnc f/owrate, 

### Oa.
Oa =60 sec/min * 

### Vs *

### As Oa

# = 229194.6 cfm 6490.8 cmm 9) Average stackgas drystandard volumetric f/owrate, Qstd.


### Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) Ostd = 

### 163143,1 dscfm 4620.2 dscmm Page 2

### Client Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations (cont.) Unit No.2 Three Page 3

10) Analyticaldata
evclone andFilterFractions (EPA Method OTM27): 

### M1) Instack quartz microfibrefilter, <2.5um
0.0172 9 PM <25filternetwt M2-4) Cyclone acetone washes
0.0000 9 actual mass of >2.5, Containers 2&3 0.0003 9 actual massof <1=2.5um, 

### Container 4 0.0000 9 acetone blank netwt 

# omLvolume 100 mL volume 100 mLvolume
0.0000 9 blank corrected mass of >2.5um, Containers 2&3

# =M2&M3 0.0003 9 blank corrected mass of <1=2.5um, Container 4 = M4
Condensible Pariiculate Matter(CPMJ Fractions (EPA Method202): 

### M5) Back HalfAqueous Wash
0.0047 9 actual sample mass 0.0003 9 aqueous blank mass 300 ml blank vol. 300 ml Sample volume
0.0044 9 condensible aqueous PM M6) Back Half MeCI2 Extraction Portion
0.0009 g extraction net

## wt 0.0000 9 MeCI2 blank netwt 300 ml blank vol. 300 ml MeCI2 extraction volume
0.0009 9 condensible organic PM M[CPMl = blank corrected mass of Total CPM, M5 & 

### M6 (10 grams) M[CPM] = 0.0053 9 CPM 11) Pariiculate Concentrations, 

### C (EPA OTM27andEPA 202).

Equation 43 Equation 45

EPA 202 

### C[totalsus] = M 1(g)+M2(g)+M3(g)+M4(g),15.43(grains/g)Nmstd(dsc0= C[PM2.5sus] = M1(g) + M4(g) '1543(grains/g) 

### 1Vmstd(dsc0 = C[CPM] = M[CPM](g)' 15.43(grains/g) 

### 1Vmstd(dsc0 where 15.43 = 7000/453592"'1000 

### C[PMtotal] = C[PMtotalsus] + C[CPM] C[PM2.5total] = C[PM2.5sus] + C[CPM] 00021 gr/dscf PMsus 00021 gr/dscf PM2.5sus 0.0006 gr/dscfCPM
0.0027 gr/dscfTotal PM 0.0027 gr/dscfTotal PM2.5

### Client Project No. Spruance Genco, LLC 

### 3333



### 12) Particulate Emission Rates, 

### E. Test Location Test Run

Calculations (cont.) Unit No.2 Three



### E[lb/hr]

# = C[](gr/dscf)' (1 Ib/7000 gr)' Qstd(dscfm)' 60(min/hr) E[lb/MMBtu]

# = C[](gr/dscD • (1 Ib/7000 gr) • Fd(dscf/MMBtu) • (20.9120.9-%02) E[totalsus] = 

### 2.91 Ib/hr total sus PM E[totalsus] = 

### 0.0038 Ib/MMBtu total sus PM 

### E[PM2.5sus] 

### = 2.91 Ib/hr PM2.5sus = 

### 76.8 % of Total PM2.5 

### E[PM2 5sus] 

### = 0.0038 Ib/MMBtu PM2.5sus = 

### E[CPM] 

### = 0.88 Ib/hr CPM 23.2 % of Total PM2.5 

### E[CPM] 

### = 0.0012 Ib/MMBtu CPM E[PMtotal] 

### = 3.79 Ib/hr total PM 

### E[PMtotal] 

### = 0.0050 Ib/MMBtu total PM E[PM25total] 

### = 3.79 Ib/hr total PM2.5 

### E[PM2 5total] 

### = 0.0050 Ib/MMBtu total PM2.5 

### 13) Percent Isokinectic Samplmg, %1 (EPA OTM

### 27Equation 40).

% I = [100*Ts*Vms*Pstd) /**(60"'Vs*tr*An"Ps*(1~Bws)*Tstd)** 

### %1= 101.07 

### 14) Stack Gas ViscoSity, u(EPA OTM

### 27 Equation 3).

u = C1 + 

### C2*(Ts"0.5) 

### +**C3"(TslI~2)** + 

### C4*(%02)**~** 

### (C5*8ws) + 

### C6*Bws*(TsIl2) 

### u = 194 8 micropoise Page 4

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations (cont.) 15) Test Condition Reynolds number, Nre (EPA OTM

### 27Equation 8).


### Nre = 8.64'10'S'(Ps'MwlTs),(Qslu) Nre 

### = 2889 Unit NO.2 Three

16) ActualParticle CutDiameterfor Cyclone I, 050 (EPA OTM

### 27 Equation 32).


### DSO = 81' ([ 

### Tsl (Mw' Ps)]'.2091)' ((u 

### I QsY.7091) DSO

# = 10.2S urn 17) Actual Cunningham Correction Factorbasedon Dp

# = 2.5um, 

### C (EPA OTM

### 27 Equation 4).


### C = 1+ 0.00S7193' (u/(Ps'Dp))' (Ts/MwYO.S C= 1.0708 18) Initial D50 for Cyclone IVbasedon testcondition Reynolds numberfrom OTM

### 27 Equation 8.


### If Nre < 

### 3162, use Equation 33 which results in 050 for IV = 

### If Nre 

### >= 3162, use Equation 34 which results in 050 for iV 

### = Initial 050 

### 2.2S 2.17 Equation 33 Equation 34 Equation 35 

### DSO = 0.0024302'(u/Qs)'1.1791'(lICYO.S'(Ts/(Ps'Mw))'0.6790 DSO = 0.019723'(u/QsYO.80S8'(lIC)'05'(Ts/(Ps'Mw))'0.30S8 Cr = 1 + 0.00S7193'(u/(Ps'DSO)),(Ts/Mw)'0.S 19) Re-established050 (orCyclone IV, 050-1, 

### Page 5

Re-established Cunningham, Cr 

### 1.0789 1.0816

If Nre < 

### 3162, use Equation 36 which results in 050 for IV

# = If Nre 

### >= 3162, use Equation 37 which results In 

### 050 for iV

### = Recalculated Cut Oiam, 050-1 

### 2.24 2.16 Equation 36 Equation 37 

### DSO-1 = 0.0024302'(u/Qs)'1.1791'(1/Cr)'05'(Ts/(Ps'Mw)),06790 DSO-1 = 0.019723'(u/Qs)'0.80S8'(1ICr)'0.S'(Ts/(Ps'Mw))'0.30S8 19) Establis/ling "Z" value, 

### Z.
IfEquation 36 was used, then Z 

### = 050-1/ 050

### = If Equation 37 was used, then Z

# =050-11 050

# =
If 0.99 < 

### Z < 

### 1,01, then 050-1 is best cut diameterestrmate, If0.99 > 

### Z > 

### 1.01, then repeat cales for Cr using 050-1 

### 1.00 1.00

### 3333-TSP-Metals-R1

Client Project No. Test Location Test Run Test

### Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vic = Vm= Pstatic = Pb= Ps 

### = Pstd = dP = dH 

### = Tm= Ts = Tsld= On 

### = An = y= t= Ds= As= Cp= Kp= K1 = K2= K3= Fd =

(02(
(C02( (N2( 

### AirNova, Inc. EPA Methods 1,2,3A,4,5and 29 (Flows, 02/C02, H20,TSP and Metals) 

### Spruance Genco, LLC 

### 3333 Unit No.2 One 

### 04/22110 

### 0647-1318

Emission Data



### 724.3 

### cc 233.649 dcf -0.45 in. H20 

### 29.81 in. Hg 

### 29.78 in. Hg 

### 29.92 in. Hg 0.7235 in. H20 ".5



### 1.446 in. H20 

### 523.5 R 650.5 R 

### 527.7 R 

### 0.248 in. 

### 0.000335 sq. ft. 1.01 

### 360 min. 10.30 ft. 83.3204 sq. ft. Vol. of H20 collected Dry gas meter reading Staticpressure Barometric pressure Stack pressure EPA Standard pressure Average sq. rt delta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area ofnozzle orifice Meter calibration factor Duration ofsampling time Diameterofstack Cross sectional area of stack 0.84 Pitot tube coefficient 85.49 ft[(lb/lbmol)*(inHg)]".5}/[s·R·inH20) Pitottube constant 17.637 Rlin.Hg 0.047070 cu.fVml 0.0026688 in.Hg-cf/ml-R 9828 scf/MMBtu

Instrumental Data



### 4.89 

### %-dry

14.03 

### %-dry

81.08 

### %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1*

### Y"Vm**~** (Pb + dH/13.6) I Tm Vmstd = 237.872 dscf 6.737 dscm 

### Unit No.2 Ooe

2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2

.. Vic Vw(std) = 34.093 set
3) Decimal fraction ofmoisture byvolume in stack gas, Bws.

Bws =Vwstd I (Vmstd+Vwstd) Bws= 0.1254
4) Molecularweightofthe stack gas on awet basis, Ms.

Ms =**[«44~%C02)** + (32*%02) + (28*%N2))· (1-Bws) 

## 1 + (18"Bws) Ms= 28.881 Ib/lbmole
5)Average stack gasvelocity, Vs.

Vs = Kp" Cp" (dP)

..**(Ts/Ps*Ms)~.5** Vs= 45.187 fps
6)Average actual stack gasvolumetric flowrate, Qa.
Qa =60 sec/min * Vs

.. As Qa

# = 225901.83 cfm 6397.54 cmm 7)Average stack gasdryvolumetric flowrate, Qstd.
Qstd = Qa

.. (TstdfTs)

.. (Ps/Pstd)

.. (1-Bws) Qstd = 159529.83 dscfm 4517.88 dscmm Page 2Client Spruanee Genco, LLC Project No. 3333 Test Location Test Run Unit No, 2 One
Calculations (cont.) 8) Particulate MatterAnalytical Data INPUT 

### A 0.0510 9 INPUT B 100 ml INPUT 

### C 0.0189 9 INPUT D 100 ml INPUT E 0.0000 9 9) Particulate sample mass calculations

H



### J Front Half: Acetone blank adj. residuev Adj. Acetone wash part.wt. Front half sample wt, 10) Front Half Particulate Matter Emission Data Filler sample netwt Front acetone wash vol. Front acetone residuewt. Acetone blank vol, Acetone blank residue wt.

0.0000 9 0.0189 9 0.0699 9 E·(B/D) 

### C-H A+ I

C[PM) = (Front HalfWt)(g)" (1Nmstd) "15.43(grainslg) E[PM) = C[PM]

.. Vdscfm

.. A

.. (60 min/hr)

.. (1 Ib 17000grains) Page 3

E[PM] Ib/MMBtu = E[PM] Ib/hr*(Fuel HV) scf/Btu

..(tuel use) 1 hour/kscrkscf/1000scf10116Btu/MMBtu C[PM] = 4,53E-03 grains/dscf C[PM] = 6.48E-07 Ib/dscf E[PM] = 6.200 Ibfhr E[PM] = 8.31E-03IbfMMBtu 11)Traee metal concentrations and emission rates

Element Antimony Arsenic Beryllium Cadmium Chromium

Cobalt Lead Manganese Nickel Selenium C[M) = M[M) (ug) fVmstd (dsem) C[M)(lb/dscf) = C[M](ugfdscm)**~** 1e-06g/ug"2.205e-03Ibfg" 0.02832 dscmfdscf E[M)(lb/hr) = C[M] (ugfdscm)" (2.20SE-09) (Ib/ug)" Qstd (dsemm)" 60 (minfhr) E[M)(lb/MMBtu) = C[M](Ibldscf)**~** Fd • (20.9/20.9-%02) C[M](@corr. 02) = C[M] (ug/dscm)**~** [(20.9-corrected %02) / (20.9-aetual %02)

## 1 Corrected 02 percentage is: 7.0 % Sample Cone. Conc.@92rr. Q2 Conc. Emission Rate Mass tug) (ug/dscm) (ug/dsem) {lb/dseD (lb/hrl

0.556 8.25E-02 7.17E·02 5.15E-i2 4.93E-05 3.293 4,89E-01 4.24E-01 3.05E-11 2,92E-04 0.704 1.05E-01 9.07E-02 6.53E-12 6.25E-05 0.697 i.03E-01 8.9BE-02 6.46E-12 6.18E-OS 9.668 1.44E+00 1.25E+00 B.96E-11 8.58E-04 2.23 3.31E-01 2.87E·01 2.07E-11 1.98E-04 4,569 6.7BE-01 5.B9E·01 4.24E-11 4.05E-04 6.66 9.89E-01 B.5BE-01 6.17E-11 5,9iE-04 '14.09**2.09E·~00** 1.82E+00 1.31E-10 1.25E-03 1.37 2.03E-01 1.77E-01 1.27E-11 1.22E-04 12) Isokinecity, I.
% I =**[100*Ts~(K3*Vlc+«(Vm·Y)lTm)*(Pb+(dH/13.6»»11** (BO't*Ps·Vs*An) %1= 102.88
" < " symbol indicates values given arethe quantitative detection limit. Emission Rate (lb/MMBtu) 6.6i2E-08 3.916E-07 8.373E-OB B.289E-OB 1.150E-06 2.652E-07 5.434E-07 7.921 E-07 1.B76E-06 1.629E-073333-TSP-Metals-R2

Client Project No. Test Location Test Run Test Date Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vic = Vm= Pstatic = Pb 

### = Ps 

### = Pstd = dP = dH = Tm= Ts = Tstd= Dn = An = y= t = Ds= As= Cp = Kp= K1 = K2 = K3= Fd =

[02] [C02]
[N2] 

### AirNova, Inc. EPA Methods 1,2,3A,4,5 and 29 (Flows, 02lC02, H20,TSP and Metals) 

### Spruance Genco, LLC 

### 3333 Unit No.2 

## Two 04/22/10 

### 1335-1943

Emission Data

698.3 cc 229.530 dcf -0.45 in. H20 29.81 in. Hg 29.78 in. Hg 29.92 in. Hg 0.7114 in. H20 ".5

1.423 in. H20 533.0 R 652.3 R 527.7 R 0.248 in. 0.000335 sq. ft. 1.01 360 min. 10.30 ft. 83.3204 sq. ft. Vol. of H20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rtdelta P Average draftgauge reading Average metertemperature Average stack temperature Standardtemperature Nozzle diameter Area of nozzle orifice Metercalibration factor Duration ofsampling time Diameter ofstack Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 fl[(lbllbmoIY"(inHg)]".5}/[s*R*inH20] Pitottube constant 17.637 R/in.Hg 0.047070 cu.ftfml 0.0026688 in.Hg-cf/ml-R 9676 scf/MMBtu

Instrumental Data

4.45 %-dry

14.29 %-dry

81.26 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 Test Location Test Run
Calculations 1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1* Y;O Vm**~** (Pb**.~** dH/13.6) ITm Vmstd = 229.500 dscf 6.499 dscm Unit No.2 

### Two

2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2 * Vic VW(std) = 32.869 scf 3) Decimal fraction ofmoisture byvolume In stack gas, Bws.

Bws =Vwstd I (Vmstd+Vwstd) Bws = 0.1253 4) Molecularweight ofthe stack gas on awet basis, Ms.
Ms = [«44*%C02) + (32*%02) + (28*O/ON2» * (1-Bws) I" (18*Bws) Ms = 28.903 Ib/lbmole 5) Average stack gas velocity, Vs.
Vs = Kp * Cp * (dP)**~** (Ts/Ps*Ms)".5 Vs = 44.476 fps 6) Average actual stack gasvolumetric flowrate, Qa.
Qa =60 sec/min'"Vs *As Qa = 222346.97 cfm 6296.87 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa * (Tstd/Ts);O (Ps/Pstd) ;0 (1-Bws) Qstd = 156592.36 dscfm 4434.70 dscmm Page 2Client Project No. Spruance Genco, LLC 3333 Test Location Test Run
Calculations (cant.) Unit No.2 

### Two

8) Particulate MatterAnalytical Data
INPUT 

### A 0.0337 9 INPUT B 100 ml INPUT 

### C 0.0240 9 INPUT D 100 ml INPUT E 0.0000 9 9) Particulate sample mass calculations

H I 

### J Front Half: Acetone blank adj. residue v Adj. Acetone wash part.wt. Front halfsamplewt. 10) Front Half Particulate MatterEmission Data Filter sample netwt Frontacetone wash vol. Frontacetone residue

### wt. Acetone blank vol. Acetone blank residue wt.

0.0000 9 0.0240 9 0.0577 9 

### E'(BID) C-H A+ I

C[PM] = (Front HalfWt)(g) * (1Nmstd) * 1S.43(grains/g) E[PMJ = C[PMJ**~** Vdscfm * A * (60 min/hr)

.. (1 Ib 17000 grains) Page 3

E[PM)lb/MMBtu = E[PM)lb/hr"(Fuel HV) scf/Btu*(fuel use) 1 hour/kscf*kscf/1000scf*10"6BtuIMMBtu C[PM) = 3.8BE-03 grains/dscf C[PM) = 5.S4E-07 Ib/dscf E[PM) = 5.207 Ib/hr E[PM) = 6.81E·03Ib/MMBtu 11)Trace metal concentrations and emission rates

Element Antimony Arsenic Beryllium Cadmium Chromium

Cobalt Lead Manganese Nickel Selenium C[M) = M[MI (ug) IVmstd (dscm) C[M)(lb/dscf) = C[M](ug/dscm)**~** 1e-06g/ug"2.205e-03Ib/g" 0.02832 dscm/dscf E[M)(lb/hr) = C[M] (ug/dscm)

.. (2.20SE-09) (Ib/ug)" Qstd (dscmm) * 60 (min/hr) E[M)(lb/MMBtu) = C[M)(lb/dscf) * Fd" (20.9f20.9-%02) C[M)(@corr. 02) = C[M] (ug/dscm) ,. [ (20.9-corrected %02) I (20.9-actual %02) 

## I Corrected 02 percentage is: 7.0 

### % Sample Conc. Conc.@corr. 02 Cone. Emission Rate Mass tug) (ug/dscm) (ugldscm) {Ib/dscf} (lb/hrl

1.122 1.73E-01 1.46E-01 1.0BE-11 1.01 E-04 2.51 3.B6E-01 3.26E-01 2.41E-11 2.27E-04 0.607 9.34E-02 7.B9E-02 S.B3E-12 S.4BE-05 0.413 6.35E-02 5.37E-02 3.97E-12 373E-05 6.127 9.43E-01 7.97E-01 5.89E-11 553E-04 2.25 3.46E-01 2.93E-01 2.16E-11 203E-04 4.20B 6.47E-01 5.47E-01 4.04E-11 3.80E-04 6.34 9.7SE-01 8.24E-01 6.09E-11 5.72E-04 29.964 4.61E+00 3.90E+OO 2.BBE-10 2.70E-03

1.11 1.71 E-01 1.44E-01 1.07E-11 1.00E-04 12) Isokinecity, I.
% I = [100'TS*(K3*Vlc+«(Vm*Y)fTm)*(Pb+(dH/13.6))))] I (60*t*Ps*Vs*An) %1= 101.12
" < " symbol indicates values given are the quantitative detection limit. Emission Rate (lb/MMBtu) 1.325E-07 2.965E-07 7.170E-OB 4.B7BE-OB 7.237E-07 2.658E-07 4.970E-07 7.48BE-07 3.539E-06 1.311E-073333-TSP-Metals-R3

Client Project No. Test Location TestRun Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vic = Vm= Pstatic= Pb = Ps= Pstd = dP = dH = Tm= Ts = Tstd= On = An= y= t= Os= As= Cp = Kp = K1 = K2 = K3= Fd=

[02[ [C02[
[N2[ 

### AirNova, Inc. EPA Methods 1,2,3A,4,5 and 29 (Flows, 02/C02, H20,TSP and Metals) 

### Spruance Genco, LLC 

### 3333 Unit No.2 Three 

### 04/23/10 

### 0600-1210

Emission Data

724.3 cc 231.745 dcf -0.45 in H20 29.90 in. Hg 29.87 in. Hg 29.92 in. Hg 0.7254 in. H20A.5

1.424 in. H20 525.0 R 654_8 R 527.7 R 0.248 in. 0.000335 sq. ft. 1.01 360 min. 10.30 ft. 83.3204 sq. ft. Vol. ofH20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rtdelta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area of nozzle orifice Meter calibration factor Duration of sampling time Diameterofstack Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbrnol)*(inHg)]".S}/(s*R*inH20] Pitottube constant 17.637 R/in.Hg 0.047070 cu.ftlml 0.0026688 in.Hg-cf/ml-R 9826 scf/MMBtu

Instrumental Data

4.97 %-dry

13.70 %-dry

81.33 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. 

### Spruance Genco, LLC 3333 Test Location Test Run

Calculations
1)Volume of gas sampled atstandard conditions, Vmstd.

Vmstd**=K1~** Y**~** Vm· (Pb + dH/13.6) ITm Vmstd = 235.917 dscf 6.681 dscm Unit No.2 

### Three

2) Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std) = K2 * Vic Vw(std) = 34.093 scf
3) Decimal fraction of moisture byvolume in stack gas, Bws,

Bws = Vwstd I (Vmstd+Vwstd) Bws = 0.1263
4) Molecularweightofthe stack gas on a wet basis, Ms.

Ms=**[«44~%C02)** + (32*%02) + (28*%N2» * (1-Bws) 

### 1 + (18*Bws) Ms = 28.826 Ib/lbmole
5) Average stack gas velocity, Vs,

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)"_5 Vs = 45.426 fps
6) Average actual stack gasvolumetric flowrate, Qa.
Qa = 60 sec/min"Vs**~** As Qa = 227093.70 cfm 6431.29 cmm 7)Average stack gas dry volumetric flowrate, Qstd.
Qstd = Qa * (TstdfTs) * (Ps/Pstd) * (1-Bws) Qstd = 15962589 dscfm 4520.61 dscmm Page 2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run Unit No.2 Three
Calculations (cont.) 8) Particulate MatterAnalytical Data
INPUT 

### A 0.0635 9 INPUT 

### 8 100 ml INPUT C 0.0213 9 INPUT 

### 0 100 ml INPUT E 0.0000 9 9) Particulate sample mass calculations

H I 

### J Front Half: Acetone blank adj. residue 'I Adj. Acetone wash part.wt. Front halfsamplewI. 10) Front Half Particulate Matter Emission Data Filter sample netwt Front acetone wash vol. Front acetone residue wt. Acetone blankvol. Acetone blank residue wt.

0.0000 9 0.0213 9 0.0848 9 E'(8/D) C-H A+ I

C[PM] = (Front HalfWt)(g)**~** (1Nmstd) • 1S.43(grainsfg) E[PM] = C[PM] • Vdscfm • A * (60 minlhr) * (1 Ib 17000 grains) Page 3

E[PM] Ib/MMBtu = E[PM] Ib/hr-(Fuel HV) scfIBtu*(fuel use) 1 hour/kscf*kscf/1000scf*10"6Btu/MMBtu C[PM] = 5.55E-03 grainsJdscf C[PM] = 7,92E-07Ib/dscf E[PM] = 7.589 Iblhr E[PMJ = 1.02E-02 Ib/MMBtu 11)Trace metal concentrations and emission rates

Element Antimony Arsenic Beryllium Cadmium Chromium

Cobalt Lead Manganese Nickel Selenium C[M] = M[M] (ug) IVmstd (dscm) C[M](Jb/dscf) '" C[M](ug/dscm) * 1e-06gfug '* 2,205e-03Ibfg '* 0.02832 dscmfdscf E[MJ(lbfhr) 

### =C[M] (ug/dscm) * (2.205E-09) (Ibfug)· Qstd (dscmm) '. 60 (min/hr) E[M](lbfMMBtu) = C[M](lb/dscf) * Fd * (20.9120.9-%02) C[M](@ corr. 02) = C[M] (ug/dscm)" [(20_9-corrected %02)I (20.9-actual %02)] Corrected 02 percentage is: 7.0 

### % Sample Conc. Conc.@corr, 02 Conc. Emission Rate Mass (ug} (ug/dscm) (ug/dscm) (lb/dscQ (lb/hr) 0.68 1.02E-01 8.88E-02 6.36E-12 6.09E-OS 2.801 4.19E-01 3.66E-01 2.62E-11 2.51E-04 0,944 1.41E-01 1.23E-01 8,82E-12 B.45E-05 0.406 6.0BE-02 5.30E-02 3.79E-12 3.63E-05 9.3'19 1.39E+00 1.22E+00 B.71E-11 8.34E-04 3.08 4.61E-01 4.02E-01 2,88E-11 2.76E-04 4.77 7.14E-01 6.23E-01 4.46E-11 4.27E-04 7.121 1.07E+OO 9,30E-01 6.66E-11 6.37E-04 34.765 5.20E+00 4.54E+OO 3.25E-10 3.11E-03

3.4 S.09E-01 4.44E-01 3.18E-11 3.04E-04 12) Isoklnecity. I.
% I =**[100*Ts*(K3~Vlc+«(Vm*Y)lTmr(Pb+(dHf13.6))))J** 1(60'*t'*Ps·Vs*An) %1= 101,97
" <"symbol indicates values given are the quantitative detection limit. Emission Rate (lb/MMBtuj 8,193E-08 3.375E-07 1.137E-07 4.892E-08 1.123E-06 3.711E-07 5.747E-07 8.580E-07 4.189E-06 4.097E-073333-Hg-unspiked-R1

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT INPUT

INPUT INPUT INPUT INPUT INPUT



### INPUT

INPUT

INPUT Vm= Pstatic = Pb= Ps 

### = Pstd = Tm= Ts = Tstd= 

### y= t= Ds= As = Kp = K1 = K2= K3 = Fd =

[02]
[C02]
[N2] 

### AirNova, Inc. EPA Method 1, 2, 3A, and 30B

- Unspiked Tube (Flows, 02/C02, and Mercury) 

### Spruance Genco, LLC 

### 3333 Unit No.2 One 04/22/10 

### 0647-1247

Emission Data

11.729 

### dcf

-0.45 in H20 29.81 in. Hg 29.78 in. Hg 29.92 in. Hg 

### 528.2 R 650.5 R 527.7 R 1.000

360 min. 10.30 ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average meter temperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time DiameterofStack 83.32043375 sq. ft. Cross sectional area ofstack 85.49 ft[(lb/lbmolt(inHg)]".5}/[s*R*inH20] 17.637 R/in.Hg constant 0.047070 cU.ft!ml 0.0026688 in.Hg-cf/ml-R 9828 scf/MMBtu

Instrumental Data

4.89 %-dry

14.03 %-dry

81.08 %-dry constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Spruance Genco, LLC Test Location Test Run Project No. 3333

Calculations
1)Volume ofgas sampled atstandard conditions,Vmstd.

Vmstd 

### =Kl" Y* Vm

.. PblTm Vmstd 

### = 11,675 dscf 0.3306 dsem
3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

INPUT Bws= Bws= Based on the M29 sampling train 0.1254
4) Molecularweightofthestackgas on a wet basis, Ms. Umt No.2 One

Ms 

### = [ «44*%C02)

### + (32*%02) 

### +(28"%N2»

.. (1-Bws) 

## 1 + (18*Bws) Ms = 28.880 Ib/lbmole
5) Average stackgas velocity, Vs.

INPUT Vs 

### = Vs = Based on the M29 sampling train 45_187 fps
6) Average actual stackgasvolumetric flowrate, Qa.

Oa = 60 sec/min"Vs " As Qa = 225900.03 cfm 6397.49 cmm 7) Average stackgasdryvolumetricflowrate, Qstd.
Qstd = Qa" (TstdlTs)" (Ps/Pstd)" (1-Bws) Qstd = 159508.42 dscfm 4517.28 dscmm
8) Mercuryconcentrations andemission rates

Element Mercury C[M] 

### =M[M] (ug) 

### IVmstd (dscm) C[M](Ib/dscf) = C[M](ug/dscm) *1e-06g/ug"2.205e-03Ib/g" 0,02832 dscm/dscf E[M](lb/hr) = C[M] (ug/dscm)

.. (2.205E-09) (Ib/ug)

.. Qstd (dscmm)

.. 60 (minlhr) E[M](Ib/MMBtu) = C[M](lb/dscf)

.. Fd

.. (20.9120.9-%02) C[M](@carr. 02) = C[M] (ug/dscm) * [(20.9-corrected %02) 1(20.9-actual %02)] Corrected 02 percentage is: 7 % Sample Mass (ug)

0.0006 Conc. (ug/dscm)

0.002 Canc.@corr. 02 (ug/dsem)

0.002 Conc. (Ib/dscf) 1.13E-13 Emission Rate (Ib/hr) 1.0BE-06 Page 2

Emission Rate

(lb/MMBtu)

1.45E-093333-Hg-unspiked-R2 ,

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT INPUT

INPUT INPUT INPUT INPUT INPUT



### INPUT

INPUT

INPUT Vm= Pstatic = Pb 

### = Ps = Pstd = Tm= Ts 

### = Tstd= y= t= Ds= As 

### = Kp = K1 = 

### K2= K3 = Fd 

### =

1 021 [C02[
[N2[ 

### AirNova, Inc. EPA Method 1, 2, 3A, and 308

- Unspiked Tube (Flows, 

### 02/C02, and Mercury) 

### Spruance Genco, LLC 

### 3333 Unit NO.2 

### Two 04/22/10 

### 1336-1936

Emission Data

10.286 dcf

-0.45 in. H20 29.81 in. Hg 29.78 in. Hg 29.92 in. Hg 545.1 R 652.3 R 527.7 R 

### 1.000

360 min. 10.30 ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time Diameterof Stack 83,32043375 sq. ft. Cross sectional area ofstack 85.49 

### ft[(1b/lbmol)*(inHg)]1I.5}/[ s*R*inH20] 17.637 R/in.Hg 0.047070 cu.ftIml 0.0026688 in,Hg-cf/ml-R 9676 scf/MMBtu

Instrumental Data

4.45 %-dry

14.29 %-dry
81,26 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled at standard conditions, Vmstd.

Vmstd =K1'" 

### Y"Vm '" Pb/ Tm Vmstd 

### = 9.921 dscf 0.2810 dscm 3) Decimalfraction ofmoisture by volume instackgas, Bws.

INPUT Bws = Bws = Based on the M29 sampling train 0,1253
4) Molecularweightofthe stack gas on a wet basis, Ms. Unit No.2 

### Two

Ms = [((44"'%C02) 

### + (32*%02) 

### +**(28~%N2»** '" (1-Bws)] 

### + (18*Bws) Ms= 28,903 Ib/lbmole
5) Average stackgas velocity, Vs.

INPUT Vs 

### = Vs = Based on the M29 sampling train 

### 44A76 fps 6) Average actualstack gasvolumetric fJowrate, Qa.
Qa = 60 sec/min'" Vs '" As Qa 

### = 222345,58 cfm 6296.83 cmm 7) Average stackgas dryVOlumetric f1owrate, Qstd.
Qstd = Qa * (Tstdffs)'" (Ps/Pstd) '" (1-Bws) Qstd = 156583.29 dscfm 4434.44 dscmm
8) Mercuryconcentrations and emission rates C[Mj = M[M] (ug) 1Vmstd (dscm) C[M](lb/dscf) 

### =C[M](ug/dscm) '" 1e-06g/ug"2.205e-03Ib/g

... 0.02832 dscm/dscf E[M](lb/hr) = C[M] (ug/dscm) * (2.205E-09) (Ib/ug) * Qstd (dscmm) * 60 (rnin/hr) E[M](lb/MMBtu) = C[M](Ib/dscf) * Fd ;0 

### (20.9/20.9-%02) C[M](@ carr. 02) = C[MJ (ug/dscm)

... [ (20.9-corrected %02) 1(20 9-actual %02)] Corrected 02percentage is: 

### 7 

### % Sample Cone QQnc.@corr. 02 Conc_ Emissioo Bat§! Element Mass (ug) (lIg/dscml (ug/dscm) (Ib/dscfl (lb/hr) Mercury 0.0009 

### 0003 0.003 2.00E-13 1.88E-06 Page 2

Emission Bate!

(lb/MMBtu) 2.46E-093333-Hg-unspiked-R3

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT INPUT

INPUT INPUT INPUT INPUT INPUT



### INPUT

INPUT

INPUT Vm= Pstatic

### = Pb= Ps = Pstd = Tm= Ts = Tstd= 

### y, !, Ds= As 

### = Kp' K1 = 

### K2' K3 ' Fd =

[02]
[C02]
[N2] 

### AirNova, Inc_ EPA Method 1, 2, 

### 3A, and 30B

- Unspiked Tube (Flows, 

### 02JC02, and Mercury) 

### Spruance Genco, LLC 

### 3333 Unit NO.2 Three 04/23/10 

### 0600-1200

Emission Data
6,540 dcf 

### -OA5 in H20 29.90 in. Hg 29.87 in. Hg 29.92 tn. Hg 536.5 R 654.8 R 527.7 R 1.000

360 min. 10.30 ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stack temperature Standard temperature Metercalibration factor Duration ofsampling time Diameter of Stack 83,32043375 sq. ft Cross sectional area ofstack 

### 85A9**ft[(lb/lbmolninHgW.5}J[s*R~inH20J** 17.637 R/in.Hg 0.047070 cu:ftlml 0.0026688 m.Hg-cf/ml-R 9826 scf/MMBtu

Instrumental Data
4,97 %-dry

13.70 %-dry

81.33 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations
1) Volume ofgassampledatstandard conditions, Vmstd.

Vmstd**=K1~** Y,o Vm,o PblTm Vmstd = 6.428 dscf 0.1821 dscm
3) Decimalfraction ofmoisture byvolume instackgas, Bws.

INPUT Bws = Bws = Based on the M29 sampling train 0.1263
4) Molecularweightofthe stackgas on a wet basis, Ms. Unit No 2 Three

Ms = [«44*%C02)

### + (32*%02) 

### + (2B*%N2»· (1-Bws)] 

### + (1B,oBws) Ms = 28.826 Ib/lbmole
5) Average stack gas velocity, Vs.

INPUT Vs= Vs 

### = Based on the M29 sampling train 45.426 fps
6)Average actualstackgasvolumetricflowrate, Qa.

Oa = 60 sec/min ;0; Vs * As Oa = 227094.84 cfm 6431.33 cmm 7) Average stack gas dryvolumetricflowrate, Qstd.
Qstd '" Qa,o (TstdlTs)· (Ps/Pstd) * (1-Bws) Qstd 

### = 159616.12 dscfm 4520.33 dscmm
8) Mercury concentrationsand emission rates

Element Mercury C[M] = M[M] (ug) IVmstd (dscm) C[M](lb/dscf) = C[M](ug/dscm) ,o1e-06g/ug,o 2.205e-03Ib/g * 0.02832 dscm/dscf E[M](lb/hr) = C[M] (ug/dscm) * (2.20SE-09) (Ib/ug)· Qstd (dscmm) * 60 (mm/hr) E[M](lb/MMBtu) 

### =C[M](lb/dscf) • Fd

.. (20.9120.9-%02) C[M]{@ corr. 02) = C[M] (ug/dscm) • [(20.9-corrected %02)/ (20 9-actual %02)

## 1 Corrected 02 percentage is: 

### 7 % Sample Mass (ug)

0.0009 Conc. (ug/dscm)

0.005 Cgnc.@corr. 02 (ug/dscm)

0.004 Conc (Ib/dscfl 3.09E-13 Emission Rate (Ib/hr) 2.96E-06 Page 2

Emission Rate

(lb/MMBtu) 3.98E-09M7E

Client Project No. Test Location Test Date 

### Spruance Genco,LLC 

### 3333 UnitNo.2 

### 04123110



### Parameter: InstrumentSpan f% 02): 

### Oxygen 21.96

Actual Calibration Gas Value f% 02): AnalyzerCalibrafion Response (% 02): AnalvzerCalibration Errorf% Span):

Zero**S~stem** Calibration Gas A(2Qarent Init. Sl::::s. Inil. Sl::::s. Final S)!s. FinalS:t::s.

Stack Calib. 

### Cal. Bias Calib. Cal. Bias 

### Run Cone. 

### Response (% 

### soan) Response (% 

### span)

1 4.59 -0.01 -0.09 0.02 0.05 2 4.17 0.02 0.05 0.02 0.05 3 4.04 

### 0.02 0.05 0.02 0.05 4 

### 0.00 0.02 0.05 0.00 -0.05 5 0.00 0.00 -0.05 0.00 -0.05 6 0.00 0.00 -0.05 0.00 -0.05 7 

### 0.00 000 -0.05 0.00 -005 8 0.00 0.00 -0.05 0.00 -0.05 

### 9 0.00 0.00 -0.05 0.00 -0.05 10 0.00 0.00 -0.05 0.00 -0.05 11 0.00 0.00 -0.05 0.00 -0.05 12 0.00 0.00 -0.05 0.00 -0.05 

### AirNova, Inc. Page 1 EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)**An§!/~z!,'!:r** Galib. Gases UQscalft. zero low mid high 

### SI:§:. 

### c.al. Gas 0.00 

### NIA 12.46 21.96 12-46 0.01 

### NIA 12.38 21.62 12.38 0.05 

### 000 -0.36 

### -1.55

URscale Sllstem Calibration Gas Calib. {nit- 

### Sl:::":s. Ini!. 

### S!!,s. FinalSl::::s. Final Sl!s. Gatib. Actual Drift Galib. Cal. Bias Calib. Cal.**Bjg~** 

### !lli!l Stack (%

### span) Response (% soan) 

### Response r% span) 

### r% span) 

### Cone.

0.14 12.39 0.05 12.44 0.27 0.23 4.60 0.00 12.44 0.27 12.45 0.32 0.05 4.16 0.00 12.45 0.32 12.43 0.23 -0.09 4.03 -0.09 12.43 0.23 0.00 -56.38 -56.60 -0.02 0.00 0.00 -56.38 0.00 -56.38 0.00 

### ERR 0.00 0.00 -56.38 0.00 -56.38 0.00 

### ERR 0.00 0.00 -56.38 0.00 -56.38 0.00 

### ERR 0.00 0.00 -56.38 0.00 -56.38 0.00 

### ERR 0.00 0.00 -56.38 0.00 -56.38 0.00 

### ERR 0.00 000 -5638 0.00 -56.38 0.00 

### ERR 0.00 0.00 -56.38 0.00 -5638 0.00 

### ERR 0.00 0.00 -56.38 0.00 -56.38 0.00 

### ERRM7E

Client Project No. Test Location Test Date Spruance GenCO,LLC 

### 3333 UnirNa.2 

### 04123110



### Parameter InstrumentSpan f% C02): 

### Carbon Dioxide 17.83

Actual Calibration Gas Value t% C02): AnalyzerCalibration Response f% C02): AnalvzerCalibration EfTOr(% Span'.'

Zero SYStem Calibration Gas Apparent Init. S\:::s. Init. 

### S:ys. Final Sys. FinalS\:,:s.

Stack 

### c..a.ti!2. Cal. Bias Calib. 

### Ca'- Bias 

### Run Cone. Response (% span) Response (% span)



### 1 13.95 0.04 0.00 0.00 -0.22 2 14.65 0.00 -0.22 0.04 0.00 3 

### 14.74 0.04 0.00 004 0.00 4 0.00 0.04 0.00 0.00 -0.22 

### 5 0.00 0.00 -0.22 0.00 -0.22 6 0.00 000 -0.22 0.00 -022 7 0.00 0.00 -0.22 0.00 -0.22 8 

### 0.00 0.00 -0.22 0.00 -0.22 9 

### 0.00 0.00 -0.22 0.00 -0.22 10 0.00 0.00 -0.22 000 -0.22 11 

### 0.00 0.00 -0.22 0.00 -0.22 12 0.00 0.00 -0.22 0.00 -0.22 

### AirNova, Inc. Page2 EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)

AnalYZerGalib. Gases Upscale zero low mid high $\:,:8. Cal. 

### Gas 0.00 

### NIA 7.49 

### 17.83 7.49 0.04 

### NIA 7.52 17.83 7.52 

### 0.22 0.00 

### 0.17 0.00

Upscale System Calibration Gas Ga/ib. Init. S!:::,:s. Init.**S:~.** Final S)t:s. Final Sys. Cafib.**~** Drift Calib. Cflf. Bias Ca/ib. Cal. Bias Dnlt Stack (% span) Response (% soan) Response (% span) (% span) Cone.



### -0.22 7.53 006 7.46 -0.34 -0.39 13.96 

### 0.22 746 -0.34 7.63 0.62 0.95 14.56 

### 0.00 7.63 0.62 7.62 0.56 -0.06 14.52 

### -0.22 7.62 0.56 0.00 -42.18 -42.74 -0.04 

### 0.00 0.00 -42 18 0.00 -42.18 0.00 

### ERR 000 0.00 -42.18 0.00 -42.18 0.00 

### ERR 0.00 000 -42.18 0.00 -42.18 0.00 

### ERR 0.00 0.00 -42.18 0.00 -42.18 000 

### ERR 0.00 0.00 -42.18 0.00 -42.18 0.00 

### ERR 0.00 0.00 -42.18 0.00 -42.18 0.00 

### ERR 0.00 0.00 -42.18 0.00 -42.18 0.00 

### ERR 0.00 0.00 -42.18 0.00 -42 18 0.00 

### ERRM7E

Client Project No. Test Location Test Date Spruance Genco,LLC 

### 3333 Unit No.2 04/23/10



### Parameter. Carbon Monoxide Instrument Span (ppmV

### CO): 2246

Actual Calibration Gas Value (ppmVCO): AnalyzerCalibration Response (ppmV

### COl: AnalvzerCalibration Error

### (% Spant

Zero Sllstem Calibration Gas AQQarent fnit. $\:,s. Init. S)!s. Final Sl!s. Final

### Sk§.

Stack Ca/ib. Cal. Bias Calib. 

### Cal. Bias Run Cone. Response (% span) Response (% span)



### 1 529.2 

### 2.4 0.11 -1.2 -0.05 

### 2 268.3 -1.2 -0.05 

### -24 -0.11 

### 3 478.3 -2.4 -0.11 -1.2 -0.05 

### 4 00 -1.2 -0.05 

### 0.0 0.00 

### 5 0.0 0.0 0.00 

### 00 0.00 6 

### 0.0 00 0.00 

### 0.0 0.00 7 

### 0.0 0.0 0.00 

### 0.0 000 

## a 0.0 0.0 0.00 

### 0.0 0.00 g 

### 00 0.0 0.00 

### 0.0 0.00 

### 10 0.0 0.0 0.00 

### 00 0.00 11 

### 0.0 00 0.00 

### 0.0 0.00 

### 12 0.0 0.0 0.00 

### 0.0 000 

### AirNova, Inc. EPA Method 6C Calculations (Cal. Error, Bias Drjftand Bias Adjustment)

zero 

### 0.0 0.0 0.00 AnalyzerCaNb. Gases /QJI< mid 

### 0.0 1204.0 

### 0.0 1209.7 0.00 

### 025 high 2246.0 

### 2254.6

0.38

Ugscale**S~stem** Calibration Gas**~** Inil. Sl!s. Inft. $1::s. Final SI§. Finf1! 

### S)!s. Drift Calib. Cal. Bias Galib. Cal. Bias (% span) Response (% span) Response (% span)



### -0.16 1207.5 -0.10 1209.7 0.00 -0.05 1209.7 0.00 1202,4 -0.33 0.05 1202.4 -0.33 1201.5 -0.37 0.05 1201.5 -0.37 

### 00 -53.86 0.00 

### 0.0 -53.86 

### 0.0 -53.86 0.00 

### 00 -53.86 

### 0.0 -53.86 

### 000 00 -53.86 

### 0.0 -53.86 0.00 

### 0.0 -53.86 

### 0.0 -53.86 0.00 

### 0.0 -53.86 

### 00 -53.86 0.00 

### 0.0 -53.86 

### 0.0 -53.86 0.00 

### 0.0 -53.86 

### 0.0 -53.86 

### 000 00 -53.86 

### 0.0 -53.86 

### Page 3

UQscale S!!s. 

### Qal. Gas 1204.0 1209.7

Cafib. Actual Drift Stack (% span) Cone,



### 0.10 

### 526.8 -0.33 

### 269.3 -0.04 480.2 -53.49 

### 1.2

0.00 

### ERR 0.00 

### ERR 0.00 

### ERR 0.00 

### ERR 0.00 

### ERR 0.00 

### ERR 0.00 

### ERR 0.00 

### ERRM7E

Client Project No. Test Location Test Date Spruance Genco,LLC 

### 3333 Unit No.2 

### 04/23/10 

### AirNova, Inc. EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)



### Parameter: 

### Total Hydrocarbons (as CH4

Run

1 2 

### 3 4 5 6 7 8 9 10 11 12 Instrument Span (ppm VTHe): 20

Actual Calibration Gas Value (ppmV THe): AnalvzerCalibration Response (PpmV THe/. AnalvzerCalibration Error(% Cal Gas Value).-

Zero**S~stem** Calibration Gas AQQsrent Init**S~,:;;.** Init· 

### S)§. Final

### S\"s. Final S\"s.

Stack Calib, Cal. 

### Bias CaNb. Cal. 

### Bias Cone. Response (% soan) Response f% span)



### 1.7 -0.0 0.00 0.0 0.40 1.0 0.0 0.40 0.1 0.70 1.2 0.1 0.70 -0.0 0.15 0.0 -0.0 0.15 0.0 020 0.0 0.0 020 0.0 020 0.0 0.0 0.20 0.0 0.20 00 0.0 0.20 0.0 0.20 00 0.0 0.20 00 0.20 0.0 0.0 0.20 0.0 0.20 0.0 00 020 0.0 0_20 0.0 0.0 0.20 0.0 0.20 0.0 0.0 0.20 0.0 0.20 AnalmrCalib. 

### Gases 

# '"'" low mid high 

### 0.0 4.9 9.1 17.4 -0.0 

### 4.8 9.2 17.5 -1.84 0.99 0.75

Uescale Sy:stem Calibration Gas Galib. Init. S)!s. Init.**S~.** Final S)!S, Final S)!s. Drift Calib. 

### Cal. Bias Calib. 

### Cal. Bias (% span) Response (% span) Response t% span)



### 0.40 9.2 0.00 9.0 -0.75 0.30 9.0 -0.75 9.0 -1.00 -0.55 9.0 -1.00 9.0 -1.00 0.05 9.0 -1.00 0.0 

### -45_90 0.00 0.0 -45_90 0.0 -45.90 0.00 0.0 -45_90 0.0 -45.90 000 00 -45.90 0.0 -45.90 0.00 0.0 -45.90 0.0 -45.90 0.00 0.0 -45.90 0.0 -45.90 0.00 0.0 -45.90 0.0 -45.90 0.00 0.0 -45.90 0.0 -45.90 0_00 00 -45.90 0.0 -45.90 Page 4

UQscaJe S)§. 

### Qat Gas 

### 9.1 9.2

Calib. 

### Actual Drift Stack (% span) Cone.



### -0.75 1.7 -0.25 0." 0.00 1.2 -44.90 0.0

0_00 

### ERR 0.00 

### ERR 0.00 

### ERR 0.00 

### ERR 0.00 

### ERR 0.00 

### ERR 0.00 

### ERR 0.00 

### ERR3333-Formaldehyde-R1

Client Project No. Test Location Emission Source Test Date Test Run Time Period

Vlc= Vm= Pstatic = Pb 

### =- Ps= Pstd 

### = dP" dH 

### = Tm= Ts = Tstd= y= t= On 

### = An 

### = Os = As= 

### Cpo Kp= K1 = K2 = K3 

### = Fd 

### = CF 

### =

[02[ [C02[
[N2[ 

### AirNova, Inc. EPA Methods 1,2,3A,4,and RCRA Method 0011

(Flows, 

### 02/C02, H20, and Formaldehyde)
Spruance Genco, LLC 3333 Richmond, Virginia Unit No.2 04/23/10 One 1245-1450

Emission Data

252.2 cc 80.739 dcf

-0.45 in. H20 29.93 in. Hg 29.90 In. Hg 29.92 in. Hg 0.714 In. H20 A.S

1.50 in. H20 542.3 R 649.7 

### R 527.7 R

0.99 120 min, 0.253 in. 0.000349 sq. ft. 10.30 ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration of sampling time Nozzle diameter Nozzle area Diameter ofstack 83.3204 sq. ft. Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lb/lbmol)*(inHg)]'"" 5}/[s*R*lnH20] Pitot tube constant 17.637 R/in.Hg 0.047070 cu.ft!ml 0.0026688 in.Hg-cf/ml-R 9828 scf/MMBtu 7.793E-08 Ib/dscf I ppmVd constant constant constant Fuel Factor Conversion Factor for CH20

EPA Method 3A Instrumental Data 4.60 %-dry 13.96 %-dry

81.44 %-dry Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration Data from:

EPA4 EPA4 EPA 2

EPA 2

EPA 2 EPA4 EPA4 EPA 2

EPA2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

Calculations

1) Volume ofgas sampled at standard conditions, Vmstd, Vmstd =K1* Y·Vm • (Pb + dH/13,6) 

### ITm Vmsld = 78 095 dscf 2212 dscm Richmond, Virginia One

2) Volume ofwatervaporcollected alstandard conditions, Vw(Sld). Vw(std) = K2 * Vic Vw(sld) = 11.871 scf

3) DecImal fraction of moisture by volume In stack gas, Bws. Bws = Vwstd 

### I (Vmstd+Vwstd) Bws= 0.1319

4) Molecularweight ofthe stack gas on awet basis, Ms, Ms 

### =[«44·%C02) + (32"'%02) + (2S·%N2))· (1-Bws) 1 + (18*8ws) Ms= 28.779 Ib/lbmole

5) Average stack gas velocity, Vs. Vs = Kp'" Cp" (dP)

.. (Ts/Ps·Ms)".5 Vs 

### = 44.576 fps

6) Average actual stack gas volumetricflowrate, Qa. Qa = 60 sec/min·Vs

.. As Qa = 222845.42 cfm 6310.98 cmm

7) Average stack gas dry volumetric flowrate, Qstd. Qstd = Qa" (TsldlTs)" (Ps/Pstd)" (1-Bws) Qstd = 156995.68 dscfm Qsld = 4446.12 dscmm Page 

### 2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

Calculations (cant.)
8) Formaldehyde

- Concentrations and Emission Rates M[CH20]

### =sample mass (mg) RIchmond, Virginia One

qCH20]

### = M[CH20] (mg) Jsample volume (dscm) qCH20@ corr. %02] ., qCH20] (ppmV)**~** (20.9-Corr. %02)/(20.9-Actual %02) Corrected 02 Percentage" 

### 7 

### % E[CH20] 

### =C[CH20] (mg/dscm) • 60 (min/hr) * Qstd (dscmm) 

### * (1 Ib 

### 14.536 e+05 mg) E[CH20](lb/MMBtu) 

### =C[CH20](ppmV) CF * Fd * (20.9120.9-%02) Page 3

Coml2ound Sample Mass Concentration Concentration Concentration Mass Emission Mass Emi::isiQO !mg) (mg/dscm) 

### !QQmYl pmV@Corr.%O (lb/hr) (lb/MMBtu)
Formaldehyde 0.00452 2.04E-03 1.64E-03 1.40E-03 

### 1.20E·03 1.61E·06 

### NO NO NO NO NO NO
9) Isokinecity, 

### I. % I = [100*Ts*(K3"Vlc+«(Vm*Y)/Tm)*(Pb+(dH/13

### 6»)))]1 (60*t*Ps*Vs*An) 

### % I= 98.943333-FormaJdehyde-R2

Client Project No. Test location Emission Source Test Date Test Run Time Period

Vlc= Vm= Pstatic= Pb = Ps = Pstd = dP = dH = Tm = Ts = Tstd= y= 1= On 

### = An 

### = Os = As 

### = Cp 

### = Kp 

### = K1 

# = K2 = K3 = Fd = CF =

[02] [C02]
[N2] 

### AirNova, Inc. EPA Methods 1,2,3A,4,and RCRA Method 0011

(Flows, 02/C02, H20, and Formaldehyde)
Spruance Genco, LLC 3333 Richmond, Virginia Unit No.2 04/23/10 Two 1520-1725

Emission Data

252.8 cc 82.077 dcf

-045 in. H20 29.90 in. Hg 2987 In. Hg 29.92 in. Hg 0.706 in. H20 ".5

1.48 in. H20 542.3 R 650.9 R 527.7 R

0.99 120 min. 0.253 in. 0.000349 sq. ft. 10.30 ft Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta 

### P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration of sampling time Nozzle diameter Nozzle area Diameter of stack 83.3204 sq. ft. Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R'inH20J Pitot tube constant 17.637 R/in.Hg 0.047070 cu.fVml 0.0026688 in.Hg-cf/ml-R 9676 scf/MMBtu 7.793E-08 Ib/dscf

### I ppmVd constant constant constant Fuel Factor Conversion Factorfor CH20

EPA Method 3A Instrumental Data 4.16 %-dry 14.56 %-dry

81.28 %-dry Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration Data from:

EPA4 EPA4 EPA

### 2

EPA

### 2

EPA2 EPA

### 4 EPA4 EPA2

EPA2

### Client Project No. Spruance Genco, LLC 3333 

### Test Location Test Run


### Calculations

1) Volume ofgas sampled at standard conditions, Vmstd. Vmstd**=K1~** Y**~** Vm ;0 (Pb + dH/13.6)/ Tm Vmstd = 79.305 dscf 2.246 dscm Richmond, VIrginia 

### Two

2) Volume ofwatervapor collected at standard conditions, Vw(std). Vw(std) = K2**~** Vic Vw(std) = 11.899 scf

3) Decimal fraction of moisture by volume in stack gas, Bws. Bws =Vwstd I (Vmstd+Vwstd) Bws= 0.1305

4) Molecularweight ofthe stack gas on a wet basis, Ms Ms = [((44*%C02) 

### + (32*%02) + (28*%N2»· (1-Bws) 

## 1 + (18*Bws) Ms = 28866 Ib/lbmole

5) Average stack gasvelocity, Vs. Vs 

### =Kp;O Cp • (dP) •**(Ts/Ps~Ms)".5** Vs = 44048 fps

6) Average actual slack gas volumetric flowrale, 

### Qa. Qa 

### =60 sec/min·Vs " As Qa 

### = 220205.96 cfm 6236.23 cmm

7) Average stack gas dryvolumetricflowrate, Qstd. Qstd = Qa· (TstdfTs)· (Ps/Pstd) * (1-Bws) Qstd = Qstd = 154966.74 dscfm 4388.66 dscmm 

### Page 2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

Calculations (cont.)
8) Formaldehyde

- Concentrations and Emission Rates M[CH20] = sample mass (mg) Richmond, Virginia Two

C[CH20] = M[CH20] (mg) 1sample volume (dscm) C[CH20 @ corr, %02] 

### =C[CH20] (ppmV)**~** (20.9-Corr. %02)/(20.9-Aclual %02) Corrected 02 Percentage 

### = 7 % E[CH20]

### =C[CH20] (mg/dscm) "60 (mln/hr)· Qsld (dscmm) • (1 Ib

### 14.536 e+05 mg) E[CH20](lb/MMBlu) = C[CH20](ppmV) CF " Fd

.. (20.9/20,9-%02) Page 3**Com~ound Sam~le**  Mass Concentration Concentration ConcentratloD Mass Emission Mass Emis,siQD 

## ill19l (mg/dscm) 

## !Jlimllil 'pmV@Corr.%O (lb/hr) Clb/MMBlu)
Formaldehyde 0.00476 2.12E-03 1.70E-03 1,41E-03 1.23E-03 1.60E-06 

### NO NO NO NO NO NO
9) Isokineclty, I. % I

# = [100*Ts*(K3"Vlc+((Vm*Y}fTm)*(Pb+(dH/13.6))))] 

### I (60"t*Ps*Vs*An) % I = 101.783333-Formaldehyde-R3

Client Project No. Test Location Emission Source Test Date Test Run Time Period

Vlc= Vm= Pstatic = Pb= Ps= Pstd = dP = dH = Tm 

### = Ts 

### = Tstd= y= t= On = An = Ds= As= Cp= Kp= K1 = K2 = K3 = Fd = CF =

[02] [C02]
[N2] 

### AirNova, Inc. EPA Methods 1,2,3A,4,and RCRA Method 0011

(Flows, 

### 02/C02, H20, and Formaldehyde)
Spruance Genco, LLC 3333 Richmond, Virginia Unit No.2 

### 04/23/10 Three 1803-2003

Emission Data

253.0 IX 83.136 dcf

-0.45 in. H2O 29.90 in. Hg 29.87 in. Hg 29.92 in. Hg 0718 in. H20 '\5

1.53 in. H20 540.0 R 651.4 R 527.7 R

0.99 120 min. 0.253 in. 0.000349 sq. ft 10.30 ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometnc pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Metercalibration facior Durairon ofsampling time Nozzle diameter Nozzle area Diameter ofslack 83.3204 sq. ft Cross sectional area of stack 0.84 Pilot tube coefficient 85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R"inH20] PltOt tube constant 17.637 R/in.Hg 0047070 cu.ftlml 0.0026688 in.Hg·cf/ml-R 9826 scf/MMBtu 7.793E-08 Ib/dscfI ppmVd constant constant constant Fuel Factor Conversion Factorfor CH20

EPA Method 3A Instrumental Data 4.03 %·dry 14.52 %-dry

81.45 %-dry Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration Data from:

EPA4 EPA4 EPA2

EPA 

### 2

EPA2 EPA4 EPA4 EPA2

EPA2Client Project No. Spruance Genco. llC 

### 3333 Test Location Test Run

Calculations

1) Volume ofgas sampled at standard conditions, Vmstd. Vmsld =K1**~**

### Y ., Vm ,. (Pb + dH/13.6)/ Tm Vmstd = 80.685 dscf 2.285 dscm Richmond, Virginia Three

2) Volume ofwater vapor collected al standard conditions, Vw(std). Vw(sld) = K2 ,. Vic Vw(std) = 11.909 scf

3) Decimal fraction ofmoisture by volume in stack gas, 8ws. Bws = Vwstd / (Vmstd+Vwstd) Bws 

### =- 0.1286

4) Molecularweight ofthe stack gas on awet basis, Ms. Ms 

### =[«44'%C02) + (32·%02) + (2S·%N2»" (1-Bws) 

## 1 + (18'*Bws) Ms= 28.879 Ib/lbmole

5) Average stack gasvelocity, Vs. Vs 

### =Kp * Cp

.. (dP) '* (Ts/Ps*Ms)".5 Vs = 44.829 fps

6) Average actual stack gasvolumetricflowrate, Oa. Qa = 60sec/min '* Vs • As Qa 

### = 224108.79 cfm 6346.76 cmm

7) Average stack gas dry volumetncflowrate, Qstd. Qstd 

### =Qa '* (TstdlTs) '* (Ps/Pstd) * (1-Bws) Ostd = Ostd = 157928.65 dscfm 4472.54 dscmm Page 2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

Calculations (cont.)
B) Formaldehyde

- Concentrations and Emission Rates M[CH20] = sample mass (mg) Richmond, Virginia Three

QCH20] = M[CH20] (mg) 

### I sample volume (dscm) QCH20 

### @ corr. %02) = QCH20] (ppmV)**~** (20.9-Corr. %02)/(20.9-Actual %02) Corrected 02 Percentage = 7 % E[CH20] = C[CH20] (mg/dscm)

.. 60 (min/hr) "Qstd (dscmm) • (1 Ib 14 536 e+05 mg) E[CH20](lb/MMBtu) = C[CH20](ppmV) CF

.. Fd" (20.9/20.9-%02) Page 3

Comgound Samgle Mass Concentration Concentration Concentration Mass Emission Mass EmiSsiQo 

### !mg) (mg/dscm) 

### iQQ!lllll 'pmV@Corr.%o Ob/hr) (lb/MMBtu)
Formaldehyde 0.00530 

### 2.32E·03 1.86E-03 1 53E-03 1.37E-03 1.76E-06 

### NO NO NO NO NO NO
9) Isokinecity, I. % I

### =[100*Ts*(K3*Vlc+«(Vm*Y)/Tm)*(Pb+(dH/13.6))))] I (60*t"Ps"Vs*An) % I

### = 101.61Client Project No. Test Location Emission Source Test Date Test Run Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT INPUT

INPUT INPUT INPUT Vic 

### = Vm= Pstatic 

### = Pb = Ps

# = Pstd = dP = dH

# = Tm= Ts

# = Tstd= 

### y= t= Dn = An 

### = Ds = As 

### = Cp 

### = Kp = K1 

# = K2 = K3

# = Fd =

[O2[ [C02[ [N2] [CO] [THC] [CH4] 

### AirNova, Inc. Page 1 of3 EPA Methods 

### 1, 2, 3A, 

### 4, 10, 18 and 25A (Flows, 

### 02/C02, H20, CO and NMHC)
Spruance Genco, LLC 3333 Richmond, Virginia Unil No.2 

### 04/23/10 One 1245-1450 Emission Data

252.2 cc 80.739 dcf

-0.45 in. H20 29.93 in. Hg 29.90 in. Hg 29.92 in. Hg 07143 in, H20 1\..5 1.50 in. H2O 542.3 R 649.7 R 527.7 R

0.99

120 min. 0.253 in, 0,000349 sq. ft. 10.300 ft. 83.3204 sq. ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta 

### P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameter of stack Cross sectional area ofstack 0.84 Pilottube coefficient 85.49 ft[(lb/lbmol)'{lnHgW.5j/[s·R·lnH201 17.637 R/in.Hg constant 0.047070 cu,fUml 0.0026688 in.Hg-cf/ml-R 9828 scf/MMBtu

Instrumental Data 460 %-dry 1396 %-dry 81.44 %-dry 526.8 ppmV-dry

1.7 ppmV-wet 0.0 ppmV-dry constant Pilottube constant constant From EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Carbon Monoxide concentration Total Hydrocarbon concentration Methane Concentration by GC-FIDClient Project No. Spruance Genco, LLC 3333 Emission Source Unit No.2 Test Run One

Calculations
1)Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1· 

### Y* Vm * (Pb + 

### dH/13 6) 

### I Tm Vmstd = 78.095 dscf 2.212 dscm
2) Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std) = K2 * Vic Vw(std) = 11.871 scf 3) Decimal fraction ofmoisture byvolume in stack gas, Bws.

Bws =Vwstd I (Vmstd+Vwstd) Bws = 0.1319 4) Molecularweightofthe stackgas on a wet basis, Ms.

Ms = [((44*%C02) + (32*%02) + (2B*%N2)) * (1·Bws) 

## 1 + (18*Bws) Ms = 28 779 Ib/lbmole 5) Average stack gasvelocity, Vs.

Vs = Kp * Cp • (dP) •**(Ts/Ps~Ms)".5** Vs = 44.576 fps
6) Average actual stackgas volumetric ftowrate, Qa.
Qa = 60 sec/min * Vs • As Qa = 222845.4 cfm 6311.0 cmm 7) Average stackgas dry volumetricflowrate, Qstd.
Qstd = Qa

.. (TstdlTs)

.. (Ps/Pstd)

.. (1-Bws) Qstd = 156995.7 dscfm 4446.1 dscmm Page 2 of3Client Project No. Spruance Genco, LLC 3333 Test Location Test Run
Calculations (cant.)Unit No.2 One Page 3 of3

8) Total Hydrocarbon concentrations and emissions

INPUT C[THC] dry basis

# = C[THC] wet/(1-Bws) 

### C[VOC] dry bas;s = 

### C[THC]

- C[CH4] Corr. C[CH41 = «20.9-02%corf. value)/(20 9-actual avg. 02% value))"VOC value E[VOC] = (C(VOq"Mol W1[VOC eqUlvalent]"60(min/hr)*Qstd(dscfm»)I(MolarVol. air*10"6) E[VOC Ib/MMBtu] = Cd * Fd * (20.9/(20.9-actual 02%)) C(THC] = 1.7 ppmVw 

### C[THC[ 

# = 2.0 ppmVd 

### qCH4] 

# = 0.0 ppmVd 

### qvOC]

# = 2.0 ppmVd C(VOC] 

### = 1.7 ppmVd corrected to 

### 7 

### % 02 Mol. Wt. [THC]= 44.096 Ib/lb-mole Molarvol air= 385 scf/lb-mole @ Propane 68 def F E[VOC] = 2.11 Ib/hr Conv Factor. 

### E[VOC]

# = 4134E-08 convert ppmVto Ib/scfTHC as CH4 1.02E-03 Ib/MMBtu 9) Carbon Monoxideconcentrations and emissions

Corr. C(CO] = «20.9-02%corr. value)/(20.9-actual avg. 02% value»*Avg. raw CO value E[CO Ib/hr] = (C[CO]*Mol Wt[CO]*60{min/hr)*Qstd{dscfm))/(Molar Vol. air*10"6) E[CO Ib/MMBtu] = Cd" Fd * (20.9/(20.9-actual 02%)) 

### qCO] 

### = 526.8 ppmVd C[CO] = 449.2 ppmVd corrected to 7 

### % 02 Mol. WI. [CO]= 28.01 Ib/lb-mole Molarvol air- 385 scf/lb-mole 

### @ 68 def F E[CO] 

### = 361.02 Ib/hr Conv Factor. 

### E[CO]

# = 7.235E-08 convert ppmV to Ib/scf CO 0.480 Ib/MMBtuClient Project No. Test Location Emission Source Test Date Test Run Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT INPUT

INPUT INPUT INPUT Vic 

### = Vm= Pstatic

# = Pb = Ps

# = Pstd = 

### dP 

### = dH = Tm 

### = Ts = Tstd= y= t= On

# = An = Os

# = As = Cp

# = Kp

# = K1 

# = K2 

### = K3 = Fd

# =

[02] [CO2] [N2] [CO] [THC] [CH4] 

### AirNova, Inc. Page 1 of3 EPA Methods 

### 1, 2, 3A, 

### 4, 10, 18 and 25A

(Flows, 

### 02/C02, H20, CO and NMHC)
Spruance Genco, LLC 3333 Richmond, Virginia Unit NO.2 

### 04/23/10 Two 1520-1725 Emission Data

252.8 cc 82.077 dcf

-0.45 in. H20 29.90 in. Hg 29.87 m. Hg 29.92 in. Hg 0.7059 in. H20 ".5 H20 1.48 in. 542.3 

### R 650.9 

### R 527.7 

### R

0.99

120 min. 0.253 in. 0.000349 sq ft 10.300 ft. 83 3204 sq. ft Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter cahbration factor Duration ofsampling time Nozzle diameter Nozzle area Diameter of stack Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lbllbmol)'(inHg)]'.5}1[s'WinH20] 17.637 R/in.Hg 0.047070 cU.ft!ml 0.0026688 in.Hg-cf/ml-R 9676 scf/MMBtu

Instrumental Data 4.16 %-dry 14.56 %-dry 81 28 %-dry 269.3 ppmV-dry

0.9 ppmV-wet 0.0 ppmV-dry constant constant constant Pitot tube constant

From EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Carbon Monoxide concentration Total Hydrocarbon concentration Methane Concentration by GC-FID

### Client Project No. Spruance Genco, LLC 

### 3333 Emission Source Unit No.2 Test Run Two

Calculations
1) 

### Volume ofgassampled atstandard conditions, Vmstd.

Vmstd =K1"

### Y"Vm" (Pb + dH/13.6) I 

### Tm Vmstd

# = 79.305 dscf 2.246 dscm
2) 

### Volume ofwatervapor collected atstandard conditions, Vw(std). Vw(std) = K2 ., Vic Vw(std) = 11.899 sef
3) 

### Decimal fraction ofmoisture byvolume in stack gas, Bws.

Bws = Vwstd I 

### (Vmstd+Vwstd) Bws= 0.1305 4) Molecularweightofthe stack gas on a wet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28"%N2»" (1-Bws)] + (1S*Bws) Ms= 28 866 Ib/lbmole 5) Average stack gasvelocity, Vs.

Vs = Kp * Cp· (dP) • (TS/Ps*Ms)".5 Vs = 

### 44.048 fps 6) Average actual stack gas volumetric flowrate, 

### Qa.
Qa = 60 sec/min"Vs *

### As Qa = 220206.0 cfm 6236.2 cmm 7) Average stackgas dry volumetric flowrate, Qstd.
Qstd

# = Qa· (Tstd/Ts)· (Ps/Pstd) 

### * (1-Bws) Qstd

# = 154966.7 dscfm 4388.7 dscmm Page 2 of3Client Project No. Spruance Genco, LLC 3333 Test Location Test Run
Calculations (cont.)Unit No.2 

### Two Page 3 of3

8) Total Hydrocarbon concentrations and emissions

INPUT CjTHC] dry basis = C[THC] wet/(1-Bws) CjVOC] dry basis

# = C{THC]- C{CH4] Corr. CjCH4] 

### = «20.9-02%corr. value)f(20.9-actual avg. 02%value))"'VOC value E[VOC] = (CjVOC]*Mol Wt[VOC equivalenW60(min/hr)*Qstd(dscfm»f(MolarVol. air*10116) E[VOC Ib/MMBtu] = Cd

... Fd**~** (20.9/(20.9-actual 02%)) CjTHC] = 0.9 ppmVw C[THC] 

# = 1.0 ppmVd C[CH4] 

# = 0.0 ppmVd C[VOC[

# = 1.0 ppmVd C[VOC] = 0.9 ppmVd corrected to Mol. Wt. [THC]= 44.096 Ib/lb-mole Molarvol alr= 385 scf/lb-mole 

### @ E[VOC] = 1.10 Ib/hr 

### 7 Propane 

### 68 Cony Factor. E]VOC]

# = 4.134E-08 convert ppmVto Ib/scfTHC as CH4 5.17E-04Ib/MMBtu 

### % 02
def F

9) Carbon Monoxide concentrations and emissions

Corr. C[CO]

# =«209-02% corr. value)/(20.9-actual avg. 02% value))*Avg. raw CO value E[CO Ib/hr] = (C[CO]*Mol Wt[CO]*60(min/hr)*Qstd(dscfm))/(Molar Vol. air*10"6) E[CO Ib/MMBtu] = Cd" Fd" (20.9/(20.9-actual 02%» C[CO]

# = 269.3 ppmVd CjCO] = 223.6 ppmVd corrected to 7 % 02 Mol. Wt. [CO]= 28.01 Ib/lb-mole Molarvol air= E]CO]

# = Cony Factor. E]CO] 

### = 385 scf/lb-mole 

### @ 182.17 Ib/hr 7.235E-08 convert ppmV to Ib/scf CO 0.235 Ib/MMBtu 

### 68 def FClient Project No. Test Location Emission Source Test Date Test Run Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT INPUT

INPUT INPUT INPUT Vic = Vm= Pstatic = Pb = Ps

# = Pstd = 

### dP

# = dH = Tm 

### = Ts = Tstd= 

### y= 

### t= Dn

# = An

# = Ds 

### = As

# = Cp = Kp 

### = K1 = 

### K2 

### = K3 

### = Fd 

### =

[O2[ [C02[ [N2[ [COl [THC[ [CH4[ 

## AirNova, Inc_ EPA Methods 

### 1, 2, 3A, 

### 4, 10, 18 and 25A

(Flows, 021CQ2, H20, CO and NMHC)
Spruance Genco, LLC 3333 RIchmond, Virginia Unit No.2 

### 04123/10 Three 1803-2003 Emission Data
253,0 cc 83.136 dcf

-0.45 in, H20 29.90 in. Hg 29.87 in. Hg 29.92 in Hg 0.7183 in, H20 

### ".5 H20 1 53 in, 540.0 R 651.4 R 527.7 R

099

120 min, 0.253 in 0,000349 sq. 

### ft. 10.300 ft. 83.3204 sq. ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameter ofstack Cross sectional area ofstack 0,84 Pitot tube coefficient 85.49 ft[(lb/lbmol)'(inHg)[,

.

### 5}/[ s'R'InH20) 17,637 R/in.Hg constant Page 1 of3

0.047070 cu.ftlml 0,0026688 in.Hg-cf/ml-R 9826 scf/MMBtu constant Pitot tube constant

Instrumental Data 4,03 %-dry 14.52 %-dry 81.45 %-dry 480.2 ppmV-dry

1.2 ppmV-wet 0.0 ppmV-dry constant From EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Carbon Monoxide concentration Total Hydrocarbon concentration Methane Concentration by GC-FIDClient Project No. Spruance Genco, 

### LLC 

### 3333 Emission Source Unit No.2 Test Run Three

Calculations
1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1* Y * Vm" (Pb + dH/13.6) 

### ITm Vmstd = 80.685 dsef 2.285 dsem


### 2) Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std) = K2 ;0 Vic Vw(std) = 11.909 sef 

### 3) Decimal fraction ofmoisture by volume in stack gas, Bws.

Bws = Vwstd 

### I (Vmstd+Vwstd) Bws = 0.1286
4) Molecularweightofthestack gas on a wet basis, Ms.

Ms = [((44*%C02) 

### + (32*%02) 

### +**(28~%N2»** * (1-Bws) 

## 1+ (1S*Bws) Ms = 2S.879 Ib/lbmole
5) Average stackgas velocity, Vs.

Vs = Kp * Cp 

### * (dP) 

### * (Ts/Ps*Ms)".5 Vs

# = 44.829 fps
6) Average actual stack gas volumetric f1owrate, Qa.

Oa 

### =60 sec/min ;0 Vs • As Oa = 22410S.8 efm 6346.S cmm


### 7) Average stack gas dryvolumetric flowrate, Qstd.

Ostd = Oa" (TstdlTs) * (Ps/Pstd) 

### * (1-Bws) Qstd = 15792S.6 dscfm 4472.5 dscmm Page 2of3Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations (cont.)Unit NO.2 Three Page 3 

### of3

8) Total Hydrocarbon concentrations and emissions

INPUT C[THCJ dry basis 

### =C[THCJ wet/(1-Bws) C[VOG] dry basis = C[THG]

- CiCH4] Corr. C[CH4] = ((20.9-02% carr. value)/(20.9-actual avg. 02% value))*VOC value E[VOCJ = (C[VOC]*Mol Wt[VOC equivalent]*60(min/hr)*Qstd(dscfm»/(MolarVol.**air~10A6)** E[VOC Ib/MMBtu] = Cd * Fd

.. (20.9/(20.9-actual 02%» G]THC] 

# = 1.2 ppmVw C[THCJ = 1.4 ppmVd CiCH4] 

# = 0.0 ppmVd C[VOC]

# = 1.4 ppmVd C[VOC]

# = 1.1 ppmVd corrected 

### to 7 

### % 02 Mol. Wt. [THCJ= 44.096 Ib/lb-mole Molarvol air= E[VOG] 

### = Conv Factor. E[VOG] 

### = 385 scf/lb-mole 

### @ 1,49 Ib/hr Propane 

### 68 def F
4.134E-08 convert ppmV to Ib/scf THC as CH4

6.93E-04 Ib/MMBtu 9) Carbon Monoxide concentrations and emissions

Corr. C[CO] = ((20.9-02% corr. value)/(20.9-actual avg. 02%value»*Avg. raw CO value E[CO Ib/hr] = (C[CO]*Mol Wt[CO]*60(min/hr)*Qstd(dscfm»/(MolarVol. air"10"6) E[CO Ib/MMBtu] 

### =Cd" Fd" (20.9/(20.9-actual 02%» qCO] = 4802 ppmVd C[CO]

# = 395.7 ppmVd corrected to 7 % 02 Mol. Wt. [CO]= 28.01 Ib/lb-mole Molarvol air= E[CO] = Conv Factor. E[CO] = 385 scf/lb-mole 

### @ 331.04 Ib/hr 7.23SE-08 convert ppmV to Ib/scfCO 0.423 Ib/MMBtu 

### 68 def F3333-SSVOH-R1 

### AirNova, Inc.

Client Project No. Test Location Test Run Test Date TestTime

INPUT EPA Methods 1,2,3A,4 and 0010 with SW-846 Method 82700 (Flows, 02/C02, H20, Speciated Semivolatile Organic HAPs and PAHs)

Vlc= Vm= Pstatlc '" 

### Pb· Ps 

### = Pstd = dP = 

### dH· Tm= Ts= Tstd= Dn = An = 

### y. 

# ,

# . Os 

### = As = Cp = Kp = K1 = K2 

### = K3 = Fd =



## 1021
IC021
IN21 Spruance Genco, LLC 3333 Unit No.2 

### Doe 04123/10 1245-1450

Emission Data

2367 cc 78.05 dcf -0.45 in. H20 29.93 in. Hg 29.90 in. Hg 29.92 in. Hg 0.7133 in. H20 ".5

1.389 111. H20 534.2 R 652.3 R 527.7 R 0.248 in. 0.000335 sq. ft. 1.01

120 min. 10.300 ft. 83.3204 sq. ft 0.84 Vol. ofH20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq rt delta P Average draft gauge reading Average meter temperature Average stack temperature Standard temperature Nozzle diameter Area of nozzle orifice Metercailbration factor Duration ofsampling time Diameter ofstack Cross sectional area of stack Pitot tube coefficient 85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R*inH20] Pltottube constant 17.637 R/in.Hg constant 0.047070 cu.ftlml constant 0.0026688 in.Hg-cf/ml-R 9828 scf/MMBtu Instrumental Data

4.60 %-dry

13.96 %-dry

81.44 %-dry constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruanee Genco, LLC 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1**~** Y 

### *Vm * (Pb +dH/13.6)/ Tm Vmstd = 78.157 dscf 2.21 dscm Unit No.2 

### Doe

2) Volume ofwatervapor collected atstandard conditIons, Vw(stcl).
Vw(std) = K2 ., Vic Vw(std)= 11.141 sef
3) Decimalfraction of moisture byvolume in stack gas, 8ws.

8ws = Vwstd / (Vmstd+Vwstd) 8ws = 0.125
4) Molecularweight ofthe stack gas on 

### a wet 

### basis, Ms.

Ms = [«44*%C02)+ (32*%02) + (28*%N2» * (1-Bws) 

## 1 + (18*Bws) Ms= 28.87 Ib/lbmole
5) Average stack gas velocity, Vs.

Vs 

### = Kp * Cp • (dP) * (Ts/Ps*Ms)".5 Vs = 44.53 fps
6) Average actual stack gas volumetricflowrate, Qa.

Oa = 60 sec/min"Vs ., As Oa = 222605.6 cfm 6304.2 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa 

### * (Tstdrrs) 

### * (Ps/Pstd) * (1-Bws) Qstd 

### = 157498.3 dscfm 4460.4 dscmm Page 2Client Spruance Genco, 

### llC Test Location Unit No, 2 Page 3 Project No. 3333 Test Run One

Calculations (cont.)
8) Speciated Semivolatile Organic HAPs

- Concentrations and Emissions
qSSVOH]

# = M[SSVOH](ug) 

### IVmstd(dscm) C[SSVOH](lb/dscf):: C[SSVOH](ug/dscm)· 1e-06g/ug"2,20Se-03Ib/g" 0.02832 dscm/dscf E[SSVOH](lb/hr)

# = C[SSVOH](ug/dscm) * Qstd(dscmm) • (2.20SE-09)(lb/ug)" 60(min/hr) E[SSVOH](lb/MMBtu)

# = C[SSVOH](lb/dscf) • Fd

.. (20.9/20.9-%02) C[SSVOH](@ corr. 02)

# = C[SSVOH] (ug/dscm);O; {(20.9-corrected %02) 1(20.9-actual %02)] Corrected 02 percentage is: 

### 70 %

SSVOH Sam(;lle Conc. Conc.@ooIT Q2 Conc. Emission Rate Emission Rate Analvte Mass (ug) (ug/dscm) (ug/dscm) (Ib/dscfl Clb/hr) (lb/MMBtu)
Acenaphthene 

### 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Acenaphthylene 0.00 0.00 0.000 O.OOE+OO O,OOE+OO O.OOE+OO Acetophenone 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Aniline 

### 000 0.000 0.000 O.OOE+OO O,OOE+OO O.OOE+OO Anthracene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzidine 0.00 0,000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(a)anthracene 

### 0.00 0.000 0,000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(b)fluoranthene 

### 0.00 0.000 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(k)fluoranthene 

### 0.00 0.000 

### 0.000 O.OOE+OO O,OOE+OO O.OOE+OO BenzoicAcid 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(g,h,i)peryJene 

### 0.00 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(a)pyrene 0.00 0.00 

### 0.000 O.OOE+OO O,OOE+OO O.OOE+OO Benzyl Alcohol 0.00 0.00 0.000 O,OOE+OO O,OOE+OO O.OOE+OO bis (2-Chloroethyl) ether 

### 000 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO bis (2-Ethylhexyl) phthalate 0.00 0.00 0_000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Bromophenyl phenyl ether 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Butyl benzyl phthalate 0.00 0,000 0.000 O,OOE+OO O.OOE+OO O.OOE+OO Carbazole 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Chloroaniline 

### 0.00 0.00 0000 O.OOE+OO O.OOE+OO O,OOE+OO 4-Chloro-3-methylphenol 0.00 0.00 

### 0.000 O,OOE+OO O.OOE+OO O.OOE+OO 2-Chloronaphthalene 0.00 0.00 0.000 O,OOE+OO O.OOE+OO O.OOE+OO 2-Chlorophenol 0.00 

### 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Chlorophenyl phenyl ether 

### 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO Chrysene 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO Dibenzo(a,h)anthracene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Dibenzofuran 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Di-n-butyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,2-Dichlorobenzene 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,3-Dichlorobenzene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,4-Dichlorobenzene 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 3,3-Dichlorobenzidine 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2,4-Dichlorophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Diethyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2,4-Dimethylphenol 

### 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Dimethyl phthalate 

### 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4,6-Dinitro-2-methylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OOClient Spruance Genco, LLC Test Location Unit No.2 Page 4 Project No. 3333 Test Run Ooe

Calculations (cont.)
SSVOH Saml2le Conc. Conc.@!;;Qrr. Q2 Conc. Emission Rate Emission Rate Analyte Mass (ug) (ug/dscm) (ug/dscm) (Ib/dscf) (lbfhr) (lb/MMBtu)
2,4-Dinitrophenol 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2,4-Dinitrotoluene 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2,6-Dinitrotoluene 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Di-n-octyl phthalate 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,2-Diphenylhydrazine 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Fluoranthene 

### 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO Fluorene 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Hexachlorobenzene 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Hexachlorobutadiene 

### 000 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO Hexachlorocyclopentadiene 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Hexachloroethane 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Indeno(1,2,3-c,d)pyrene 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Isophorone 

### 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Methylnaphthalene 

### 0.00 

### 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Methylphenol 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 3 & 4-Methylphenol 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Naphthalene 

### 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Nitroaniline 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 3-Nitroaniline 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Nitroamline 

### 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO Nitrobenzene 

### 0.00 0.00 

### 0000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Nitrophenol 

### 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Nitrophenol 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO N-NitfOsodimethylamlne 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO N-NitfOsodlphenylamine 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO N-Nitrosodi-n-propylamine 

### 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Pentachlorobenzene 

### 0.00 

### 0.00 0.000 O.OOE+OO o OOE+OO O.OOE+OO Pentachloronitrobenzene 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Pentachlorophenol 

### 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Phenanthrene 

### 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Phenol 

### 0.00 000 0.000 O.OOE+OO o OOE+OO O.OOE+OO 2,2'-oxybis (1-Chloropropane) 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Pyrene 

### 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Pyridine 

### 0.00 0.00 

### 0000 O.OOE+OO O.OOE+OO O.OOE+OO 1,2,4-Trichlorobenzene 

### 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2,4,5-Trichlorophenol 

### 0.00 0.00 0.000 O.OOE+OO o OOE+OO O.OOE+OO 2,4,6-Trichlorophenol 

### 0.00 0.00 0.000 O.OOE+OO o OOE+OO O.OOE+OO

Total SSVOHs 

### 0.000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OOClient Project No. Spruance Genco, LLC 3333

9) PAH Concentrations and Emissions Test Location Test Run

Calculations (cant.)

C[PAH] = M[PAH]{ug) IVmstd(dscm) Unit No.2 One

C[PAH](lb/dscf)

# = C[PAH]{ug/dscm) 

### ·1e-06g/ug·2.205e-03Ib/g· 0.02832 dscm/dscf E[PAH](lb/hr)

# = C[PAH]{ug/dscm) • Qstd(dscmm) .,. (2.205E-09)(lb/ug) * 60(min/hr) E[PAH](lb/MMBtu)

# = C[PAH](lb/dscf) * Fd 

### *(20.9/20.9-%02) C[PAH](@ corr. 02) '" C[PAH] (ug/dscm) * [ (20.9-corrected %02) 1(20.9-aclual %02) ] Corrected 02 percentage is: 

### 7.0 %


### PAH Sample Cone. Conc.@corr. 02 Conc. Emission Ral.fl: Analyte Mass (ug) (ug/dscm) (ug/dscm) (Ib/dscfl (Iblhrl
Acenaphthene 0.00860 0.00 0.003 2.43E-13 229E-06 Acenaphthylene 000730 0.00 0.003 2.06E-13 1.9SE-06 Anthracene 0.00000 0.00 0.000 O.OOE+OO O.OOE+OO 8enzo(a)anthracene 0.00200 0001 0.001 564E-14 5.33E-07 Benzo(b)fluoranlhene 0.00500 0002 0.002 1.41E-13 1.33E-06 Benzo(k)fluoranthene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO Benzo(g,h,i)perylene 0.00110 0.000 0.000 3.10E-14 2.93E-07 Benzo(a)pyrene 

### 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO Benzo(e)pyrene 0.00590 0.003 0.002 166E-13 1.57E-06 Chrysene 0.00780 0.004 0.003 2.20E-13 2.08E-06 Dibenzo(a,h)anlhracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO Fluoranthene 

### 0.01100 0.00 0.004 3.10E-13 2.93E-06 Fluorene 0.01400 

### 001 0.005 3.95E-13 3.73E-06 Indeno(1,2,3-c,d)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 2-Melhylnaphthalene 0.24100 0.11 0.093 6.80E-12 6.43E-05 Naphthalene 0.56000 0.25 0.216 1 58E-11 1 49E-04 Perylene 000000 

### 0.000 0.000 O.OOE+OO O.OOE+OO Phenanthrene 000000 0.00 0.000 O.OOE+OO O.OOE+OO Pyrene 0.00000 0.00 0.000 O.OOE+OO O.OOE+OO

Total PAHs 0.8637 

### 0.021 0.018 128E-12 2.30E-04

10) Isokinecity, I.



### % I '" [100*Ts*(K3*Vlc+«(Vm*Y)fTm)*(Pb+(dH/13.6))))] 

### I (60*t·Ps*Vs*An) % I = 102.72 Page 5

Emission Rate

Clb/MMBtu)

3.06E-09 260E-09**O.OOE·~OO** 7.11E-10 1.78E-09 O.OOE+OO 391E-10 O.OOE+OO 2 10E-09 2.77E-09 O.OOE+OO 391E-09 498E-09 O.OOE+OO 8.S7E-08 1.99E-07 O.OOE+OO O.OOE+OO O.OOE+OO

3.07E-073333-SSVOH-R2 

### AirNova, Inc.

Client Project No. Test Location Test Run Test Date TestTime

INPUT EPA Methods 1,2,3A,4and 0010 with SW-846 Method 82700 (Flows, 02/C02, H20, Speciated Semivolatile Organic HAPs and PAHs)

Vic 

### = Vm= Pstatic = Pb= Ps = Pstd = dP = dH

# = Tm= Ts= Tsld= On = An = y= t= Os = As 

### = Cp = Kp = K1 = 

### K2 

### = K3 

### = Fd =

1021 IC02]
IN2] Spruance Genco, LLC 3333 Unit No.2 

### Two 04/23/10 1525-1730

Emission Data

238.1 cc 77.03 dcf 

### -OA5 in. H20

29.9 In. Hg 29.87 in. Hg 29.92 in. Hg 06968 in. H20 ".5

1.325 In. H20 536.0 R 651.5 R 527.7 

### R 0.248 in. 0.000335 sq. ft. 1.01

120 min. 10.300 ft. 83.3204 sq_ ft 

### 0.84 Vol. of H20 collected Dry gas meier reading Static pressure Barometnc pressure Stack pressure EPA Standard pressure Average sq_rt delta P Average draft gauge reading Average meter temperature Average stack temperature Standard temperature Nozzle diameter Area of nozzle orifice Metercalibration factor Duration ofsampling time Diameter ofstack Cross sectional area ofstack Pilottube coefficient 

### 85A9 ft[(lb/lbmol)*{inHg)]".5}/[s"R*inH20] Pitot tube constant 17_637 R/in.Hg constant 0.047070 cu.ft!ml constant 0.0026688 in.Hg-cf/ml-R 9676 scf/MMBlu Instrumental Data

4.16 %-dry

14.56 %-dry

81.28 %-dry constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations
1)Volume ofgas sampled atstandard conditions,Vmstd.

Vmstd =Kl*Y * Vm * (Pb + dH/13.6) ITm Vmstd 

### = 76.801 dscf 2.18 dscm Unit No.2 Two

2) Volume ofwatervapor collected atstandard conditions, Vw(std).
Vw(std) 

### =K2 '" Vic Vw(std) = 11.207 scf
3) Decimal fraction of moisture by volume in stack gas, Bws.

Bws = Vwstd I (Vmstd+Vwstd) Bws = 0.127
4) Molecularweightofthe stack gas on a wet basis, Ms.

Ms 

### =((44*%C02) + (32"%02) +**(28~%N2»** '" (1.Bws) 

## 1+ (18*Bws) Ms= 28.90 Ib/lbmole
5) Average stack gasvelocity, Vs.

Vs = Kp '" Cp '" (dP) * (Ts/Ps*Ms)".5 Vs= 43.47 fps
6) Average actual stack gas volumetricflowrate, Qa.
Qa 

### =60 sec/min'" Vs '" As Qa = 217302.3 cfm 6154.0 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa '" (TSldfTs) * (Ps/Pstd) * (l-Bws) Qstd = 153335.3 dscfm 4342.5 dscmm Page 2Client Spruance Genco, LLC Test Location Unit No, 2 Page 3 Project No. 3333 Test Run 

### Two

Calculations (cont.)
8) Speciated Semivolatile Organic HAPs

- Concentrations and Emissions qSSVOH]

## =M[SSVOH](ug) IVmstd(dscm) qS8VDH](lb/dscf)

## =qSSVOH](ug/dscm)**~** 1e-06g/ug'"2.205e-03Ib/g '" 0,02832 dscm/dscf E[SSVOH](lb/hr)

## =qSSVOH](ug/dscm) * Qstd(dscmm) 

### * (2.205E-09)(lb/ug) ·60(min/hr) E[SSVDH](lb/MMBtu) 

## =qSSVOH](lb/dscf) * Fd**~** (20.9/20.9-%02) qSSVOH](@corr. 02)

## =qSSVOH] (ug/dscm) • [(20.9-corrected %02) I (20 9-actual %02) ] Corrected 02 percentage is: 

### 7.0 %

SSVOH Sam!;!le Conc. Canc.@corr. 02 Conc. Emission Rate Emission Rate Analyte Mass Cug) (ug/dscm) (uqtdscm) (Ib/dscf) (lb/hr) Clb/MMBtu)
Acenaphthene 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Acenaphthylene 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO Acetophenone 0.00 

### 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO Aniline 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Anthracene 0,00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzidine 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(a)anthracene 

### 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(b)f1uoranthene 

### 0.00 0000 0000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(k)f1uoranthene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzoic Acid 0,00 0.000 0.000 O,OOE+OO O.OOE+OO O.OOE+OO Benzo(g,h,i)perylene 0.00 0,000 0000 O.OOE+OO O,OOE+OO O.OOE+OO Benzo(a)pyrene 0.00 

### 0.00 0,000 O,OOE+OO O.OOE+OO O.OOE+OO Benzyl Alcohol 0,00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO bis (2-Chloroethyl) ether 

### 000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO bis (2-Ethylhexyl) phthalate 0.00 0.00 0,000 o OOE+OO O.OOE+OO O.OOE+OO 4-Bromophenyl phenyl ether 

### 000 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO Butyl benzyl phthalate 

### 000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Carbazole 0.00 0.00 0.000 O,OOE+OO O.OOHOO O.OOE+OO 4-Chloroanilme 

### 000 0.00 0.000 O,OOE+OO O.OOE+OO O.OOE+OO 4-Chloro-3-methylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Chloronaphthalene 

### 000 0.00 0.000 O,OOE+OO O.OOE+OO O.OOE+OO 2-Chlorophenol 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Chlorophenyl phenyl ether 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Chrysene 0.00 0,00 0.000 O.OOE+OO O,OOE+OO O.OOE+OO Dibenzo(a.h)anthracene 0.00 

### 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Dibenzofuran 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O,OOE+OO Di-n-butyl phthalate 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O,OOE+OO 1,2-Dichlorobenzene 

### 000 0,00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,3-Dichlorobenzene 0.00 

### 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,4-Dichlorobenzene 

### 000 0.00 0.000 O,OOE+OO O.OOE+OO O.OOE+OO 3,3-Dichlorobenzidine 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O,OOE+OO 2,4-Dichlorophenol 0.00 

### 000 0.000 O.OOE+OO O,OOE+OO O.OOE+OO Diethyl phthalate 0.00 

### 000 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 2,4-Dimethylphenol 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Dimethyl phthalate 0.00 

### 000 0.000 O,OOE+OO O.OOE+OO o OOE+OO 4.6-Dinitro-2-methylphenol 

### 000 0.00 0.000 Q,OOE+OO O.OOE+OO o OOE+OOClient Spruance Genco, LLC Test Location Unit No, 2 Page 4 Project No, 3333 Test Run Two

Calculations (cont.)
SSVOH Sample Cone, Qonc,@corr, 02 Cone. Emission Rate Emission Rate Analyte Mass (ug) (ug/dscm) (ug/dscm) (lb/dscO (Ib/hrl (lb/MMBtu)
2,4-0initrophenol 

### 0.00 0,00 

### 0.000 O.OOE+OO O.OOE+OO O,OOE+OO 2,4-0initrotoluene 

### 000 0,00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 2,6-0Imtrotoluene 

### 0.00 0.00 0.000 O,OOE+OO O,OOE+OO O.OOE+OO Di-n-octyl phthalate 

### 0.00 0,00 0,000 O.OOE+OO O.OOE+OO O,OOE+OO 1,2"Diphenylhydrazine 

### 0,00 0.00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO Fluoranthene 

### 0.00 0.00 0.000 O,OOE+OO O,OOE+OO O.OOE+OO Fluorene 

### 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO Hexachlorobenzene 

### 0.00 0.00 0.000 o OOE+OO O,OOE+OO O,OOE+OO Hexachlorobuladiene 

### 0,00 0.00 0.000 o OOE+OO O,OOE+OO O,OOE+OO Hexachlorocyclopentadiene 

### 0,00 

### 0.00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO Hexachloroethane 

### 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO Indeno{1,2,3-c,d)pyrene 

### 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO Isophorone 

### 0.00 0,00 0.000 O.OOE+OO O.OOE+OO O,OOE+OO 2-Melhylnaphthalene 

### 0,00 

### 0.00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 2-Methylphenol 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 3 & 4-Methylphenol 

### 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO Naphthalene 

### 0.00 0.00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Nitroaniline 

### 0,00 0,00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 3-Nitroaniline 

### 0.00 0.00 0.000 O,OOE+OO O,OOE+OO O.OOE+OO 4-Nitroaniline 

### 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO Nitrobenzene 

### 000 0,00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 2-Nitrophenol 

### 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Nitrophenol 

### 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO N-Nitrosodimethylamine 

### 0.00 0,00 0.000 O.OOE+OO O.OOE+OO O,OOE+OO N-Nilrosodiphenylamine 

### 0,00 0,00 0.000 O.OOE+OO O,OOE+OO O,OOE+OO N-Nltrosodi-n-propylamine 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O,OOE+OO Pentachlorobenzene 

### 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO Pentachloronitrobenzene 

### 0.00 0,00 

### 0000 O.OOE+OO O.OOE+OO O.OOE+OO Pentachlorophenol 

### 0,00 

### 000 0.000 O.OOE+OO O,OOE+OO O,OOE+OO Phenanthrene 

### 0.00 000 0.000 O.OOE+OO O,OOE+OO O,OOE+OO Phenol 

### 0.00 000 0.000 O.OOE+OO O,OOE+OO O,OOE+OO 2,2'-oxybis (1-Chroropropane) 

### 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO pyrene 

### 0.00 0,00 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Pyridine 

### 000 0.00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 1,2,4-Trichlorobenzene 

### 0.00 0.00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 2,4,5-Trichlorophenol 

### 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 2,4,6-Tnchloropbenol 

### 0,00 0,00 

### 0.000 O.OOE+OO O,OOE+OO O,OOE+OO

Total SSVOHs 

### 0000 0.000 0.000 O,OOE+OO O,OOE+OO O.OOE+OOClient Project No. Spruance Genco. llC 3333

9) PAH Concentrations and Emissions Test Location Test Run

Calculations (cant.)

C[PAH] = M[PAH](ug) I Vmstd(dscm) Unit No 2 Two

C[PAH](Ib/dscf) 

### =C[PAH](ug/dscm) 

### '* 1e-06g/ug'* 2.205e-03Ib/g * 0.02832 dscm/dscf E[PAH](Ib/hr) 

### =C[PAH](ug/dscm) '* Qstd(dscmm)

.. (2.20SE-09)(lb/ug)

.. 60{min/hr) E[PAH]{Ib/MMBtu) = C[PAH](lb/dscf) '* Fd ,. (20.9/20 9-%02) C[PAH]{@corr. 02) = C[PAH] (ug/dscm) ,. [ (20.9-corrected %02) I (20.9-actual %02) ] Corrected 02 percentage is: 

### 7.0 %

PAH Sample Conc. COrlQ_@QQrr. Q2 Conc. Emission Rate Analyte Mass (ugl (ug/dscm) (ug/dscml Clb/dscO (Ib/hr)
Acenaphthene 0.00700 0.00 0.003 2.01E-13 1.8SE-06 Acenaphthylene 0.00180 0.00 0.001 S.17E-14 4.7SE-07 Anthracene 0.00000 

### 0.00 0.000 O.OOE+OO O.OOE+OO Benzo(a)anthracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO Benzo{b)fluoranthene 0.00000 0.000 

### 0.000 O.OOE+OO O.OOE+OO Benzo(k)fluoranthene 0.00000 0.000 

### 0.000 O.OOE+OO O.OOE+OO Benzo(g.h.i)perylene 000000 0.000 0.000 O.OOE+OO O.OOE+OO Benzo{a)pyrene 

### 000000 0.000 0.000 O.OOE+OO O.OOE+OO Benzo(e)pyrene 

### 000000 0.000 0.000 O.OOE+OO O.OOE+OO Chrysene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO Dibenzo(a,h)anthracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO Fluoranthene 0.00650 

### 0.00 0.002 1 87E-13 1.72E-06 Fluorene 0.01000 0.00 0.004 2.B7E-13 2.64E-06 Indeno(1,2,3-c,d)pyrene 0.00000 0.000 0000 O.OOE+OO O.OOE+OO 2-Methylnaphthalene 0.11000 0.05 0.042 3.16E-12 2.91E-OS Naphthalene 0.35500 

### 0.16 0.136 1 02E-11 9.38E-05 Perylene 

### 0.00000 0.000 0000 O.OOE+OO O.OOE+OO Phenanthrene 0.03300 0.02 

### 0013 9.47E-13 8.72E-06 Pyrene 000000 0.00 0.000 O.OOE+OO O.OOE+OO

Total PAHs 0.5233 0.013 0.011 7.91E-13 1.38E-04

10) leokinecity, I.

% I 

### =[100"Ts*(K3'·Vlc+{{(Vm*y)fTmt(Pb+{dH/13.6»)))] I (60*I*Ps"Vs"An) 

### % I 

### = 103.68 Page 5

Emission Rate

(lb/MMBtu)

2.43E-09 6.24E-10 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 2.2SE-09 3A7E-09 O.OOE+OO 3.B2E-08 1.23E-07 O.OOE+OO 1.14E-08 O.OOE+OO

1.82E-073333-SSVOH-R3 

### AirNoV8, Inc.

Client Project No. Test Location Test Run Test Date TestTime

INPUT EPA Methods 1,2,3A,4and 0010 with SW-84S Method 82700 (Flows, 02fC02, H20, Speciated SemivolatJIe Organic HAPs and PAHs)

Vic = Vm= Pstatic

## = Pb

## = Ps

## = Pstd 

### = dP 

### = dH = Tm = Ts = Tstd= Dn 

### = An = y= t 

### = Ds = As = Cp = Kp = K1 = K2 = K3 = Fd 

## =

[02] [C02]
[N2] Spruance Genco. LLC 3333 Unit No.2 Three 04123f10 1808-2018

Emission Data
245,9 cc 77.869 def -0.45 in, H20

299 in. Hg 29.87 in. Hg 29.92 il1. Hg 0.7192 in. H20 ".5

1,410 in. H20 536.8 R 652.3 R 527.7 R 0.248 in. 0.000335 sq, 

### ft, 1.01

120 min. 10,300 ft Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq rt delta P Average draft gauge reading Average meter temperature Average stacktemperature Standard temperature Nozzle diameter Area ofnozzle orifice Meier calibration factor Duralion of sampling time Diameter ofstack 833204 sq. ft. Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lb/lbmol)*(inHg)]".5}f[s*R*inH20] Pltottube constant 17,637 R/in,Hg constant 0.047070 cu.ftlml 0_0026688 in.Hg-cf/ml-R 9826 scf/MMBtu 

### Instrumental Data

4.03 %-dry

14.52 %-dry

81.45 %-dry constant conslant Fuel Factor

Oxygen concentration

Carbon Dioxide concentralion
Nilrogen concentrationClient Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations 1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1* Y * Vm * (Pb

### + dH/13.6) ITm Vmstd = 77.533 dsef 2.20 dsem Unit No.2 Three

2)Volume ofwatervapor collected atstandard conditions, Vw(std). Vw(std) = K2 • Vic Vw{std) = 11.574 scf
3) Decimal fraction of moisture by volume instackgas, Bws.

Bws = Vwstd I (Vmstd+Vwstd) Bws= 0.130
4) Molecularweight ofthe stack gason 

### a wet basis, Ms.

Ms = [((44*%C02) 

### + (32*%02) 

### +**(28*~/oN2»** 

### * (1-Bws)] 

### +(18*Bws) Ms= 28.86 rb/lbmole
5) Average stackgas velocity, Vs.

Vs = Kp • Cp· (dP) • (Ts/Ps·Ms)".5 Vs = 44.92 fps
6) Average actual stackgasvolumetricflowrate, 03,
Oa = 60 sec/mm ,. Vs *As Qa = 224585.8 cfm 63603 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Oa * (TstdfTs)· (Ps/Pstd)· (1-Bws) Qstd = 157809.9 dscfm 4469.2 dscmm Page 2Client Spruance Genco, LLC Test Location Unit No.2 Page 3 Project No. 3333 Test Run Three

Calculations (cont.)
8) Speciated SemivolatileOrganic HAPs

- Concentrations and Emissions
C[SSVOH]

# = M[SSVOH](ug) IVmstd{dscm) C[SSVOH]{lb/dscf)

# = C[SSVOH](ug/dscm)**~** 1e-06g/ug * 2.205e-03Ib/g * 0.02832 dscm/dscf E[SSVOHJ(lb/hr) = C[SSVOH](ug/dscm) • Qstd(dscmm) • (2.20SE-09)(lb/ug) ·60(minlhr) E[SSVOH](Ib/MMBtu) 

### =C[SSVOH](lb/dscf) ;0 Fd "(209/20.9-%02) C[SSVOH](@ corr. 02)

# = C[SSVOH] (ug/dscm) • [ (20.9-corrected %02) 1(20.9-actual %02) ] Corrected 02 percentage is: 

### 7.0 %

SSVOH Sam(;lle Conc. Conc.@corr. 02 Conc. Emission Rate Emission Rate Analyte Mass (ug) (uq/dscm) (ug/dscm) Clb/dscf) (Ib/hr) (lb/MMBtu)
Acenaphthene 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO Acenaphthylene 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO o OOE+OO Acetophenone 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Amline 0.00 

### 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO Anthracene 0.00 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO Benzidine 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(a)anthracene 0.00 

### 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(b)f1uoranthene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(k)f1uoranthene 0.00 

### 0.000 0000 O.OOE+OO o OOE+OO O.OOE+OO BenzoicAcid 

### 000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo{g,h,i)perylene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo(a)pyrene 0.00 0.00 0000 O.OOE+OO o OOE+OO O.OOE+OO Benzyl Alcohol 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO bis (2-Chloroethyl) ether 

### 000 0.000 0.000 O.OOE+OO O.OOE+OO o OOE+OO bis (2-Ethylhexyl) phthalate 6.S0 

### 296 2439 1.85E-10 1.75E-03 2.2SE-06 4-Bromophenyl phenyl ether 0.00 

### 000 0000 O.OOE+OO O.OOE+OO O.OOE+OO Butyl benzyl phthalate 

### 000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Carbazole 

### 000 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Chloroanitine 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Chloro-3-methylphenol 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Chloronaphlhalene 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Chlorophenol 

### 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4-Chlorophenyl phenyl ether 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Chrysene 0.00 

### 000 0.000 O.OOE+OO o OOE+OO O.OOE+OO Dlbenzo(a,h)anthracene 0.00 

### 000 0.000 O.OOE+OO 

# oOOE+OO O.OOE+OO Dibenzofuran 0.00 

### 000 0000 O.OOE+OO 

# oOOE+OO O.OOE+OO Di-n-butyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,2-Dichlorobenzene 

### 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,3-Dichlorobenzene 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 1,4-Dichlorobenzene 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 3,3-Dichlorobenzidine 0.00 

### 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2,4-Dichlorophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Diethyl phthalate 

### 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2,4-Dimethylphenol 

### 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Dimethyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 4,6-Dinitro-2-methylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OOClient Project No. Spruance Genco. LLC 3333

SSVOH Sample Analyte Mass lug)
2,4-Dinitrophenol 000 2,4-Dinitrotoluene 000 2,6-Dinilrololuene 0.00 Di-n-oclyl phthalate 0.00 1,2-Diphenylhydrazine 0.00 FILIoranlhene 0.00 Fluorene 0.00 Hexachlorobenzene 0.00 Hexachlorobuladiene 0.00 Hexachlorocyclopentadiene 0.00 Hexachloroethane 0.00 Indeno{1.2.3-c,d)pyrene 0.00 Isophorone 0.00 2-Methylnaphthalene 0.00 2-Melhylphenol 0_00 3 & 4-Methylphenol 0.00 Naphthalene 0 00 2-Nitroamline 0 00 3-Nilroaniline 0.00 4-Nftroamline 000 Nitrobenzene 000 2-Nitrophenol 0.00 4-Nitrophenol 000 N-Nitrosodimelhylamine 000 N-Nitrosodiphenylamine 0.00 N-Nitrosodi-n-propylamlne 0.00 Pentachlorobenzene 000 Pentachloronitrobenzene 0.00 Pentachlorophenol 0.00 Phenanthrene 0.00 Phenol 0.00 2.2'-oxybis (1-Chloropropane) 0.00 Pyrene 0.00 Pyridine 0.00 1,2,4-Trichlorobenzene 0.00 2,4,S-Trichlorophenol 0.00 2.4.6-Tflchlorophenol 000

Total SSVOHs 6.S00 Test Location Test Run

Calculations (cont.)

Conc. (uq/dscm)

0.00 0.00 0.00 

### 0.00 0.00 0.00 0.00 0.00 0.00 

### 0.00 0.00 

### 0.00 0.00 0.00 0.00 

### 0.00 0.00 0.00 

### 0.00 0.00 0.00 0.00 0.00 0.00 0.00 

### 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 

### 0.00 0.00 0.00 0.00

0.038 Unit No.2 Three

CQnc.@corr. 02 Cone.

(ug/dscm) (Ib/dscf)

0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOHOO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0000 O.OOE+OO 0000 O.OOE+OO 0.000 O.OOE+OO 0000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOHOO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO 0.000 O.OOE+OO

0.032 2.46E·12 Page 4

Emission Rate Emission Rate (Ib/hr) (lb/MMBlu)

O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO OOOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO OOOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO o OOE+OO O.OOE+OO

1.7SE-03 2.2SE-06Client Spruance Genco, LLC Test Location Unit No.2 PageS Project No. 3333 Test Run Three

Calculations (cont.)
9) PAH Concentrations and Emissions
C[PAH] = M[PAH](ug) I Vmstd{dscm) C[PAH]{lb/dscf) = C[PAH]{ug/dscm);O 1e-OBg/ug"2.205e-03Ib/g" 0.02832 dscm/dscf E[PAH]{lblhr) = C[PAH]{ug/dscm)

.. Qstd{dscmm) • (2.205E-09){lb/ug)

.. 60{mm/hr) E[PAH]{lb/MMBtu) = C[PAH]{lb/dscf)

.. Fd • (20.9120.9-%02) C[PAH]{@ corr. 02) = C[PAH1 (ug/dscm)

.. [ (20.9-corrected %02) I (20.9-actual %02)] Corrected 02 percentage is: 

### 70 %


### PAH Sample Cone. Conc.@gQrr. 02 Cone. Emission Rate EmissIon Bat!';!: Analyte Mass (U9) (ug/dscm) (ug/dscm) (lb/dscf) (Ib/hr) (lb/MMBlu)
Acenaphthene 0.00530 

### 0.00 0002 1.S1E-13 1.43E-06 1.83E-09 Acenaphthylene 0.00200 

### 0.00 0001 S.69E-14 5.39E-07 6.92E-10 Anthracene 0.00000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo{a)anthracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo{b)fluoranthene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo{k)f1uoranthene 000000 0.000 

### 0000 O.OOE+OO O.OOE+OO o OOE+OO Benzo{g,h,i)perylene 000000 0.000 0.000 O.OOE+OO O.OOE+OO o OOE+OO Benzo{a)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Benzo{e)pyrene 0.00000 0.000 

### 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Chrysene o 00S82 0.003 0.002 1.66E-13 1.57E-06 2.01 E-09 Dibenzo{a,h)anthracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Fluoranthene 0.01090 

### 0.00 0.004 3.10E-13 294E-06 3.77E-09 Fluorene 0.00750 0.00 0.003 2.13E-13 2.02E-06 2.60E-09 Indeno{1,2,3-c,d)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 2-Methylnaphthalene 

### 010100 O.OS 0.038 2.B7E-12 2.72E-OS 3.50E-OB Naphthalene 0.24000 0.11 0.090 6.B3E-12 6A6E-OS B.31E-OS Perylene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO Phenanthrene 0.02700 0.01 0.010 768E-13 7.27E-06 9.3SE-09 pyrene 0.00000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO

Total PAHs 0.3995 0.010 O.OOB 5.9BE-13 1.08E-04 1.3BE-07

10) Isokinecity, I.

% I = [100*Ts*{K3*Vlc+({(Vm"Y)fTm)*{Pb+{dH/13 6»)))]1 (60*t·Ps*Vs·An) %1= 101703333-VOST-R1

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT INPUT

INPUT INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT Vm= Pslatic = Pb= Ps = Pstd = Tm = Ts = Tstd= y= t= Ds= As= Kp= K1 = K2 :: K3 = Fd 

### =

[02[ [C02[
[N2] 

### AirNova, Inc. EPA Method 1, 2, 3Aand 0031JSW-848 Method 82808 (Flows, 02/C02, and Speciated Volatile Organic HAPs)
Spruance Genco, LLC 3333 Unit No.2 One 04/23/10 1245-1445

1.125 -0.45 29.93 29.90 Emission Data

dcf in. H2O in. H9 in. H9 29.92 in. H9 551.5 

### R 652.3 

### R 527.7 

### R 1.000 90 min. 10.300 ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average meter temperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time DiameterofStack 83.3204 sq. ft. Cross sectional area ofstack 85.49 ft[(lb/lbmolt(InHg)]".5}/{s*R*inI-l20] 17.637 Rfin.Hg 0.047070 cu.ft/ml 0.0026688 in.Hg-cf/ml-R 9828 scf/MMBtu

tnstrumental Data

4.60 %-dry

13.96 %-dry

81.44 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations
1)Volume ofgassampled 

### atstandard conditions, Vmstd.

Vmstd =K1*Y *Vm * PblTm Vmstd = 1.077 dscf 0.0305 dscm
3) Decimal fraction ofmoisture by volume in stack gas, Bws.

INPUT Bws = Bws = Based on the SSVOH sampling train 0.1250 4) Molecularweightofthe stack gas on awet basis, Ms. Unit No.2 One

Ms = ( «44*%C02) + (32"%02) + (2B*%N2» * (1-Bws) 

### I+ (1B*Bws) Ms = 28-865 Ib/lbmole
5) Average stackgasvelocity, Vs.

INPUT Vs = Vs = Based on the SSVOH sampling train 44.460 fps
6) Average actualstack gasvolumetricflowrate, Qa.

Oa =60 sec/min**~** Vs"As Oa = 222265.59 cfm 6294.56 cmm 7)Average stack gasdryvolumetricflowrate, Qstd.
Qstd = Qa

.. (TstdlTs)" (Ps/Pstd)

.. (1-Bws) Qstd = 157211.66 dscfm 4452.23 dscmm Page 2Client Spruance Genco, LLC Test Location Unit No.2 Page 3 Project No. 3333 Test Run 

### O,e

Calculations (cont.) 8) Speciated Volatile Organic HAPs

- Concentrations and Emission Rates C[SVOH] = M[SVOH] (ug) JVmstd (dscm) C[SVOH](lbJdscf) =C[SVOH](ugldscm) ""1e-06gJug *2.205e-03Ib/g· 0.02832 dscm/dscf E[SVOH](lb/hr) = C[SVOH] (ug/dscm)**~** (2.205E-09) (Ib/ug) • Qstd (dscmm) ·60 (min/hr) E[SVOH](lb/MMBtu) = C[SVOH](lbJdscf)· Fd * (20.9/20.9-%02) C[SVOH](@corr. 02) = C[SVOHj (ugJdscm) * [(20 9-corrected %02) I (20.9-actual %02) ] Corrected 02 percentage is: 

### 70 %

Conc. Conc_@>;:Qrr. 02 Conc. Emission Rats/: Emission Rate Compound (ug/dscm) (ug/dscm) (Ibfdscf) (lbfhrl (lb/MMBtu)

Acetone 748.116 637.964 4.67E-08 4.41E-Oi 5.887E-04 Benzene 5.376 4.584 3.36E-10 3.17E-03 4.230E-OB Bromobenzene 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Bromochloromethane 1.858 1.585 UBE-i0 1,09E-03 1.4B2E-OB Bromodichloromethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Bromoform 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Bromomethane 3.840 3.275 2.40E-i0 2.2BE-03 3.022E-OB 2-Butanone 14.210 12,118 8.87E-10 8.37E-03 1.118E-05 n-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO sec-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO tert-Butylbenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO Carbon Disulfide 17.878 15.248 

### 1. 12E-09 1,05E-02 1.407E-05 Carbon Tetrachloride 0.062 0.053 3.89E-12 3.67E-05 4,903E-08 Chlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Chlorodibromomethane 0000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Chloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Chloroform 0.251 0.214 1.57E-11 1.48E-04 1.978E-07 Chloromethane 5,971 5.092 3.73E-10 3.52E-03 4.699E-06 2-Chlorotoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 4-Chlorotoluene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dibromo-3-chloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dibromoethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Dibromomethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichlorobenzene 0.000 0,000 O.OOE+OO O.OOE+OO O,OOOE+OO 1,3-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1A-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Dichlorodifluoromethane 0.377 0.322 2.35E-11 2.22E-04 2.968E-07 1,1-DichIOl"oethane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichloroethane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO cis-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO trans-1,2-Dichloroethene 0.000 0.000 o.OOE+OO O.OOE+OO O.OOOE+OO 1,1-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OO 1,2-Dichloropropane 0.000 0.000 O,OOE+OO O.OOE+OO O,OOOE+OO 1,3-Dichloropropane 0.000 0,000 O,OOE+OO O.OOE+OO o OOOE+OO 2,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO o OOOE+OO cis-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO trans-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OOClient Spruance Genco, LLC Test Location Unit No.2 Page 4 Project No. 3333 Test Run 

### 00.

Calculations (cont.)

Conc. Conc.@corr. o:?; Conc. Emission Rate Emission Rate Compound (uq/dscml (uq/dscm) (lb/dscO (lb/hrl (lb/MMBtu)
1,1-Dichloropropene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO Ethylbenzene 0.033 0.028 2,05E-12 1.93E-05 2.580E-08 Hexachlorobutadiene 0,000 0,000 O.OOE+OO o OOE+OO O.OOOE+OO 2-Hexanone 1.968 1,678 1.23E-10 1,16E-03 1.54BE-06 Isopropylbenzene 0,000 0,000 O.OOE+OO o OOE+OO O.OOOE+OO p-Isopropyltoluene 0.000 0,000 O.OOE+OO O,OOE+OO O.OOOE+OO Methylene Chloride 7.044 6.007 4.40E-10 4.15E-03 5.543E-06 4-Methyl-2-Pentanone 0.000 0.000 O.OOE+OO O,OOE+OO O,OOOE+OO Naphthalene 0.000 0,000 O.OOE+OO O,OOE+OO O,OOOE+OO n-Propylbenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO Styrene 0,000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 1,1,1,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OO 1,1,2,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Tetrachloroethene 0,151 0.129 9.42E-12 8.89E-OS 1.187E-07 Toluene 2.548 2,173 1.59E-10 1,50E-Q3 2.005E-06 1,2,3-Trichlorobenzene 0.000 0,000 O.OOE+OO O.OOE+OO O,OOOE+OO 1,2,4-Trichlorobenzene 0.000 0.000 O.OOE+OO O,OOE+OO O,OOOE+OO 1,1,1-Trichloroethane 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1,2-Trichloroethane 0.000 0,000 O.OOE+OO O,OOE+OO O,OOOE+OO Trichloroethene 0,000 0,000 O.OOE+OO O,OOE+OO O,OOOE+OO Trichlorofluorometl1ane 1,951 1.664 1.22E-10 1.15E-03 1,S35E-06 1,2,3-Trichloropropane 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2,4-Trimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,3,S-Trimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Vinyl Chloride 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO m-Xylene & p-Xylene 0,092 0.078 5.73E-12 S.41E-05 7.225E-08 o-Xylene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO

Total 12.299 10.032 7.45E-10 4.78E-01 6.388E-04

### 3333-VOST-R2

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT INPUT Vm= Pstatic = Pb= Ps= Pstd = Tm= INPUT Ts = INPUT Tstd= INPUT y = INPUT t = INPUT Ds = As = Kp = K1 = K2 = K3 = INPUT Fd =

INPUT [02[

INPUT [C02[
[N2[ 

### AirNova, Inc. EPA Method 1, 2, 3A and 0031/SW-846 Method 82608 (Flows, 02/C02, and Speciated Volatile Organic HAPs)
Spruance Genco, LLC 

### 3333 Unit No.2 

### Two 04123f10 1525-1730

1.107 -0.45 29.90 29.87 Emission Data

dcf in. H2O in. H9 in. H9 29.92 in. H9 549.7 R 651.5 R 527.7 R 1.000 90 min. 10.300 ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration of sampling time Diameterof Stack 83.3204 sq. ft. Cross sectional area ofstack 85.49 ft[(lb/lbmol)*(inHgl]" 5}/[s*R*inH20] 17.637 Rfin.Hg 0.047070 cu.ftlml 0.0026688 in.Hg-cffml-R 9676 scf/MMBtu

Instrumental Data

4.16 %-dry

14.56 %-dry

81.28 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 Test Location Test Run
Calculations
1)Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1* Y*Vm**~** PblTm Vmstd = 1.062 dsd 0.0301 dscm
3) Decimal fraction of moisture byvolume instack gas, Bws.

INPUT Bws= Bws= Based on the SSVOH sampling train 0,1270
4) Molecularweight ofthe stack gason 

### a wet basis, Ms. Unil No, 2 

### Two

Ms = [((44*%C02) 

### + (32*%02) + (2S*%N2» '* (1-Bws) 1

### + (1S*Bws) Ms = 28.909 Ibf Ibmole
5) Average stack gasvelocity, Vs.

INPUT Vs= Vs= Based on the SSVOH sampling train 43.450 fps 6) Average actuat stack gas volumetric flowrate, Qa.
Qa = 60 sec/min**~** Vs * As Qa = 217216.37 cfm 6151.57 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa * (TstdfTs) * (Ps/Psld) * (1-Bws) Qstd = 153323.32 dscfm 4342.12 dscmm Page 2Client Spruance Genco, LLC Test Location Unit No.2 Page 3 Project No. 3333 Test Run 

### Two
Calculations (cont.) 8) Speciated Volatile Organic HAPs

- Concentrations and Emission Rates qSVOH] '" M[SVOH] (ug) /Vmstd (dscm) qSVOH](lb/dscf) =qSVOH](ug/dscm)" 1e-06g/ug**~** 2.20Se-03Ib/g**~** 0.02832 dscm/dscf E[SVOH](lb/hr) = qSVOH] (ug/dscm)" (2.20SE-09) (Ib/ug) * Qstd (dscmm) ·60 (min/hr) E[SVOH](lb/MMBtu) = qSVOH](Ib/dscf)**~** Fd * (20.9/20.9-%02) qSVOH](@corr. 02) = qSVOH] (ug/dsem) * [(20.9-corrected %02) I (20.9-actual %02) 

## I Corrected 02 percentage is: 

### 7.0 %
Conc. Conc.@ggrr Q2 Conc. Emission Rate Emission Rate: Compound (ug/dscm) (ug/dscm) (lb/dscO (lblhr) (lb/MMBtu)

Acetone 803.668 667.323 S.02E-08 4.62E-01 6.063E-04 Benzene 8.045 6.680 S.02E-10 4.62E-03 6.069E-06 Bromobenzene 0.000 0.000 O.OOE+OO oOOE+OO O.OOOE+OO Bromochloromethane 1.108 0.920 6.92E-11 6.37E-04 8.361 E-07 Bromodichloromethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Bromoform 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Bromomethane 6.384 5.301 3.99E-10 3.67E-03 4.816E-06 2-Butanone 18.842 15.645 i.18E-09 1.08E-02 1.421 E-05 n-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO sec-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO tert-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Carbon Disulfide 16.472 13.677 i.03E-09 9.46E-03 1.243E-05 Carbon Tetrachloride 0.086 0.072 S.40E-12 4.97E-OS 6.S22E-08 Chlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Chlorodibromomethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Chloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Chloroform 0.211 0.175 1.31E-11 1.21E-04 1.S89E-07 Chloromethane 38.700 32.13S 2.42E-09 2.22E-02 2.919E-OS 2-Chlorotoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 4-Chlorotoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dibromo-3-chloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dibromoethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Dibromomethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichiorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,3-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,4-Dichlorobenzene 

### 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Dichlorodifluoromethane 0.6S8 0.547 4.11E-11 3.78E-04 4.966E-07 1,1-Dichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO cis-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO trans-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,3-Dichloropropane 0.166 0.138 1.04E-11 9.SSE-OS 1.2S4E-07 2,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO cis-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO trans-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OOClient Spruance Genco, LLC Test Location Unit No.2 Page4 Project No. 3333 Test Run Two

Calculations (cont.)

Conc. Conc.@oorr. 02 Conc. Emission Rate Emission Rate Compound (ug/dscm) (ug/dscm) (lb/dscO (lbfhr) (lbfMMBtu)
1,1-Dlchloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Ethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Hexachlorobutadiene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 2-Hexanone 2.549 2.117 1.59E-10 1.46E-03 1.923E-06 Isopropylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO p-Isopropyltoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Methylene Chloride 1234.252 1024.857 7.71E-08 7.09E-01 9.311E-04 4-Methyl-2-Pentanone 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Naphthalene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO n-Propylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Styrene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1,1,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1,2,2·Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Tetrachloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Toluene 1.527 1.268 9.54E-11 8.77E-04 1.152E-06 1,2,3-Trichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2,4-Trichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1,1-Trichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1,2-Trichloroethane 0000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Trichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Trichlorofluoromethane 3.418 2.838 2.13E·10 1.96E-03 2.579E-06 1,2,3-Trichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2,4-Trimethylbenzene 0.000 0.000 oOOE+OO O.OOE+OO O.OOOE+OO 1,3,5·Trimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Vinyl Chloride 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO m·Xylene 

### & p-Xylene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO a-Xylene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO

Total 32.365 

### 25.706 1.96E-09 1.23E+00 1.611E-033333-VOST-R3

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT INPUT Vm= Pstatic= Pb = Ps= Pstd= Tm = INPUT Ts = INPUT Tstd= INPUT Y = INPUT t., INPUT Ds '" As ., Kp= K1 = K2 = K3 = INPUT Fd =

INPUT 

### 1021

INPUT 

### IC021
IN21 AirNova, Inc. EPA Method 1, 2, 3A and 

### 0031/SW·846 Method 8260B (Flows, 02/C02, and Speciated Volatile Organic HAPs)
SprLlance Genco, LLC 3333 Unit No.2 Three 04/23f10 1808-2018

1.092 -0.45 29.90 29.87 Emission Data

dof in. H2O in. Hg in. Hg 29.92 in. Hg 548.4 

### R 652.3 

### R 527.7 

### R 1.000 90 min. 10.300 ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stacktemperature Standard temperature Meter calibration factor Duration of sampling time Diameter ofStack 83.3204 sq. ft. Cross sectional area ofstack 85.49 fI[(lb/lbmol)*(inHg)l".5}/[s*R*inH20] 17.637 R/in.Hg 0.047070 cu.fllml 0.0026688 in.Hg-cffml-R 9826 scf/MMBtu

Instrumental Data

4.03 %-dry

14.52 %-dry

81.45 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. 8pruance Genco. LLC 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1" Y* Vm * PblTm Vmstd = 1.050 dscf 0.0297 dscm
3) Decimal fraction ofmoisture byvolume Instack gas, Bws.

INPUT Bws= Bws= Based on the SSVOH sampling train 0.1300
4) Molecularweightofthe stack gas on a wet basis, Ms. Unit No.2 Three

Ms = [((44*%C02) + (32*%02) + (28*%N2» * (1-Bws) 

### J+ (18*Bws) Ms= 28,861 Ib/lbmole
5) Average stack gasvelocity, Vs.

INPUT Vs = Vs= Based on the SSVOH sampling train 44.900 fps
6) Average actual stack gasvolumetricflowrate, Oa.

Oa = 60 secJmin • Vs •As Oa = 224465.25 cfm 6356.86 cmm 7) Average stack gas dryvolumetricflowrate, Qstd.

Ostd = Oa" (TstdfTs) * (PslPstd) * (1-Bws) Qstd = 157701.86 dscfm 4466.12 dscmm Page 2CHent Spruance Genco, LLC Test Location Unit No, 2 Page 3 Project No. 3333 Test Run Three

Calculations (cont.) 8) Speciated Volatile Organic HAPs·Concentrations and Emission Rates C[SVOHj = M[SVOHj tug) 1Vmstd (dscm) C[SVOH](lb/dscf) = C[SVOH](ug/dscm) * 1e-06g/ug**~** 2-205e-03Ib/g**~** 0.02B32 dscm/dscf E[SVOH](lb/hr) = C[SVOH] (ug/dscm) * (2.205E-09) (Ib/ug) * Qstd (dscmm) *60 (min/hr) E[SVOH](lb/MMBtu) = C[SVOH]{lb/dscf) * Fd * (20,9/20.9-%02) C[SVOH](@ corr. 02)= C[SVOH] (ug/dscm) • [ (20,9-corrected %02)I (20.9-actual %02) ) Corrected 02 percentage is: 

### 7.0 %
Cone. Conc.@corr.02 Conc. Emission Rate Emission Rate Compound (uq/dscm) (ugfdscm) Ob/dscfl (lb/hr) (lb/MMBtu)

Acetone 900.569 742.022 S.62E-08 5,32E-01 6.B46E-04 Benzene 3.679 3.031 2.30E-10 2.17E-03 2,796E-06 Bromobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OO Bromochloromethane 0.807 0.665 5.04E-11 4.77E-04 6,135E-07 Bromodichloromethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Bromoform 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO Bromomethane 6.355 5.237 3.97E-10 3.76E-03 4.831E-06 2-Butanone 21.297 17.548 1.33E-09 1.26E-02 1.619E-05 n-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO sec-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OO tert-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Carbon Disulfide 11.850 9.764 7AOE-10 7.00E-03 9.00BE-06 Carbon Tetrachloride 0.050 0.042 3.15E-12 2.9BE-05 3.834E-OB Chlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Chlorodibromomethane 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO Chloroethane 0.000 0.000 O.OOE+OO O.OOE+OO o OOOE+OO Chloroform 0.235 0.194 1A7E-11 1.39E-04 1,789E-07 Chloromethane 45.764 37.707 2.86E-09 2.70E-D2 3,479E-05 2-Chlorotoluene 0,000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OO 4-Chlorotoluene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dibromo-3-chloropropane 0.000 0.000 O.OOE+OO 

# oOOE+OO O.OOOE+OO 1,2-Dibromoethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Dibromomethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,3-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1A-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Dichlorodifluoromethane 0.393 0.324 2.46E-11 2.32E·04 2.991E-07 1,1-Dichloroethane 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO cis-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO trans-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,3-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 2,2-Dichloropropane 0000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO cis-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO trans-1 ,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OOClient Spruance Genco, LLC TestLocation Unit No.2 Page 4 Project No. 3333 TestRun Three
Calculations (cant.)

Conc. Conc.@corr.Q;:: Conc. Emission Rate Emission Rat!:: Compound (ug/dscml (ug/dscm) (lb/dscO (Ib/hr) (lb/MMBtu)
1,1-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO oOOOE+OO Ethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO oOOOE+OO Hexachlorobutadiene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 2-Hexanone 2.914 2.401 1.82E-10 1.72E·03 2.215E-06 Isopropylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO p-Isopropyltoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Methylene Chloride 1149.094 946.794 7.1SE-OS 6.79E-01 S.735E·04 4-MethYI-2-Pentanone 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Naphthalene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO n-Propylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Styrene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1,1,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1,2,2-Tetrachloroethane 0.000 0.000 O.OOE+OO oOOE+OO O.OOOE+OO Tetrachloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Toluene 2.000 1.64S 1.25E-10 1.1SE-03 1520E-06 1,2,3-Trlchlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2,4-Trlchlorobenzene 0.000 

### 0.000 O.OOHOO O.OOE+OO O.OOOE+OO 1,1,1-Trichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,1,2-Trichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Trichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Trichlorofluoromethane 5.064 4.173 3.16E-10 2.99E-03 3.S50E-06 1,2,3-Trichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,2,4-Trimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 1,3,5-Trimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO Vinyl Chloride 0.000 0000 O.OOE+OO O.OOE+OO O.OOOE+OO m-Xylene & p-Xylene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO o-Xylene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO

Total 32.577 25.675 1.97E-09 1.27E+00 1.634E·03

### UnitNo.3

## Spruance Genco, LLC Richmond,Virginia Project No. 3333 April 16, 2010 Unit No.3 Run No.1 Coal Analysis for F Factor Calculation

F FACTOR CALCULATION

INPUT 

### %H= 

## 4.82 Hydrogen Content 

### (%) INPUT 

### %c= 

## 76.49 Carbon Content 

### (%) INPUT 

### % N= 

## 1.4 Nitrogen Content (%) INPUT 

### %0= 

## 4.54 Oxygen Content 

### (%) INPUT 

### %8= 

## 0.69 Sulfur Content 

### (%) INPUT 

### GCV= 

## 13494 Gross Calorific Value (Btu/lb)

Fd

# =1011.6" [(3.64*%H) 

### + (1,53*%C) 

### + (0.57"%8) + 

### (O.14*%N)

- 

### (O.46*%02)]/GCV 

### Fd

# = 9862 scf/MMBtu

## Spruance Genco, LLC Richmond, Virginia 

## Project No. 3333 April 19, 2010 Unit No.1 Run No.2 Coal Analysis for F FactorCalculation

F FACTOR CALCULATION

INPUT 

### %H= 

## 5.04 Hydrogen Content (%) INPUT 

### %c= 

## 76.71 Carbon Content (%) INPUT 

### %N= 

## 1.56 Nitrogen Content (%) INPUT 

### %0= 

## 6.35 Oxygen Content (%) INPUT 

### %s= 

## 1.05 Sulfur Content (%) INPUT GCV= 

## 13696 Gross CalorificValue (Btu/lb)

Fd 

### = 10116'" [(3.64"%H) 

### + (1.53*%C) + (0.57·%S) 

### + (0 14"'%N)

- 

### (0.46*%02)]1 GCV 

### Fd = 

### 9755 scf/MMBtu

## Spruance Genco, LLC Richmond, Virginia 

## Project No. 3333 April 19, 2010 Unit No.1 Run NO.3 Coal Analysisfor F FactorCalculation

F FACTOR CALCULATION

INPUT % 

### H= 

## 5.12 Hydrogen Content (%) 

### INPUT 

### %c= 

## 78.65 Carbon Content (%) 

### INPUT 

### %N= 

## 1.67 Nitrogen Content (%) 

### INPUT 

### %0= 

## 5.68 Oxygen Content (%) INPUT 

### %s= 

## 1.04 SulfurContent (%) 

### INPUT 

### GGV= 

## 13902 Gross Calorific Value (Btu/lb)

Fd = 

### 10"6"[(3.64"%H) 

### + (1.53*%C) 

### + (0.57*%5) 

### + (O.14*%N)

- 

### (0.46*%02)1 / GCV 

### Fd

# = 9868 scf/MMBtu3333-7E

Client Spruance Genco, LLC 

### 3333 Project No. Test Location Test Date 

### Unit No.3

- Acid Gases 

### &

### Non OF 

### HAPs 04/15/10

Parameter: 

### Oxygen Instrument S[2an (% 

### 021: 21.96

Actual Gafibration Gas Value (% 

### 021: Analy'zercalibration Res[2onse f% 021: AnalvzerCalibration Error(% SoanJ:

Zero Sy:stem Calibration Gas A[212arent Init Sy.s. Init. Sy.s. FinalSl:::s. FinalSl:::s.

Stack Carib. Gal. Bias Cafib. Cal. Bias Run Cone. Response (%s[2anl Response f% span)



### 4.29 0.15 0.64 0.09 0.36 2 4.11 0.09 0.36 0.06 0.23 3 

### 3.99 0,06 0.23 0.05 0.18 4 

### 0,00 0.05 0.18 0.00 -0.05 5 0.00 0.00 -0.05 0.00 -0,05 6 0.00 0.00 -0.05 0.00 -005 7 0.00 0.00 -0.05 0.00 -0.05 

## a 0.00 0.00 -0.05 0.00 -0.05 9 

### 0.00 0.00 -0.05 0.00 -0.05 10 0.00 000 -0,05 0.00 -0.05 11 0.00 000 -0.05 0.00 -0.05 12 0.00 0.00 -0.05 0.00 -0.05 

### AirNova, Inc. Page 1 EPA Method 7E Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Analy.zerCafib. Gases U[2scalf!. 

### ,ero low mid high Sy's. Cal. Gas 

### 0.00 N/A 

### 12.46 21.96 12.46 0.01 N/A 

### 12.33 21.95 12.33 0.05 0.00 -0.59 -0.05**U~scale** Sy:stem Calibration Gas Cal/b. Init. Sl:::s. !nit. Sl:::s. FinalS:y's. Fina!Sl:::s. Cafib.**~** Drift Calib. Cal. Bias Calib. Cal. Bias Dnff Stack (% spanJ Response (% span) Rf!.sponse (% span) (%soanl**~**



### -0.27 12.37 0.18 12.39 0.27 0.09 4.24 -0.14 12.39 0.27 12.38 0.23 -005 4.08 -0.05 12,38 0.23 12.38 0.23 0.00 3.98 -0.23 12.38 0.23 0.00 -56.15 -56.38 -0.05 0.00 0.00 -56.15 0.00 -56.15 0.00 

### ERR 000 0.00 -56.15 0.00 -56.15 0.00 

### ERR 0.00 000 -56 15 0.00 -56.15 0.00 

### ERR 0.00 0,00 -56.15 0.00 -56.15 0.00 

### ERR 0.00 0.00 -56.15 0.00 -56.15 0.00 

### ERR 0.00 0.00 -56.15 0.00 -56.15 0.00 

### ERR 0.00 0.00 -56.15 0.00 -56.15 0.00 

### ERR 000 0.00 -56,15 0.00 -56.15 0.00 

### ERR3333-7E

Client Project No. Test Location Test Date Spruance Genco, LLC 3333 Unit No.3

- Acid Gases & Non DF HAPs 04/15/10



### Run

2 3 4 5 

### 6 7 

### 8 9 10 11 12 Parameter: InstrumentSoan (% C02): 

### Carbon Dioxide 17.83

ActualCalibration Gas Value (% C02): Anal'i.ZerCalibration Response (% C02).- AnalYZerCalibratIOn Error(% Span):

Zero System Calibration Gas Agparent Init. S:ls. Init. S:ls. Final S:ls. Fingl S'i.s.

Stack Galib_ CfJ.'- Bias Ca/ib. Gal. Bias Gone. Response (% span) Response (% span)

14.17 0.06 0.45 0.02 0.22 14.23 0.02 0.22 0.13 0.84 14.22 0.13 0.84 0.13 0.84 0.00 0.13 0_84 0_00 0.11 0_00 

### 000 0.11 0_00 0.11 0_00 

### 000 0.11 0.00 0.11 0.00 0.00 0.11 0.00 0.11 0,00 0.00 0.11 0.00 0.11 

### 0.00 0.00 0.11 0.00 0.11 0.00 0.00 0_11 0_00 0.11 0.00 

### 000 0.11 0.00 0.11 

### 000 000 0.11 0.00 0.11 

### AirNova, Inc. Page 2 EPA Method 6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

Anal'i.zerQa/ib. Gases UQscale 

### zero low mid high S:ls. Cal. Gas 0.00 NfA 12.39 17.83 12.39 -0.02 NfA 12.36 17.76 12.36 -0.11 0.00 -0.17 

### -0.39

UQscale Sy:stem**C~libration** Gas Calib_ {nit. S:ls. Init. S:ls. FinalS:ls. Fina{S:ls. Gallb. Actual Drift Calib. Cal. Bias Galib. Gal. Bias Drift Stack (% span) Response (% span) Resoonse (% span) (% span)**~**

-0.22 12.32 -0.22 12_32 -0.22 0.00 14.26 0.62 12.32 -0.22 12.31 -0.28 -0.06 14.33 0.00 12.31 -0.28 12.31 -0.28 0.00 14.33 -0.73 12.31 -0.28 0.00 -69.32 -69.04 -0.13 0_00 0.00 -69.32 0.00 -69.32 0.00 

### ERR 0.00 0.00 -6932 0.00 -69.32 0.00 

### ERR 0.00 0_00 -69.32 0.00 -69.32 0.00 

### ERR 0.00 

### 000 -69.32 0.00 -69.32 0.00 

### ERR 0.00 0.00 -69.32 0.00 -69.32 0.00 

### ERR 0.00 0.00 -69,32 0_00 -69.32 0_00 

### ERR 0_00 0,00 -69.32 0.00 -69.32 0_00 

### ERR 0_00 0.00 -69_32 0.00 -69.32 0.00 

### ERR

### 3333·7E

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit No.3

- Acid Gases & Non OF HAPs 

### 04115110

Parameter: 

### Carbon Monoxide Instn;mentSpan (ppmV

### CO): 2246

ActualCalibration Gas Value (pomV

### CO): Anal'GerCalibration Response (ppmV

### CO): AnalYZerCalibration Error(% Span).

Zero Sy:stem Calibration Gas AQparent Init.**S~s.** Init. S)!s. Fmal S)!s. Final S)!s.

stack Calib. Cal. Bia!j Calib. Cal. Bias 

### Run Conc. ResQonse (% sQanl ResQonse (% span)



### 747.1 -1.2 0.00 2.4 0.16 2 327.2 2.4 0.16 2.4 0.16 3 467.5 24 0.16 2.4 0.16 

### 4 0.0 2.4 0.16 0.0 0.05 5 0.0 0.0 0.05 0.0 0.05 6 0.0 0.0 0.05 0.0 005 7 

### 0.0 0.0 0.05 0.0 0.05 B 

### 0.0 0.0 0.05 0.0 0.05 9 

### 0.0 0.0 0.05 0.0 0.05 10 0.0 0.0 0.05 0.0 0.05 11 0.0 0.0 0.05 0.0 005 12 0.0 0.0 0.05 0.0 005 

### AirNova, Inc. Page 3 EPA Method6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

Anal'GerCalib. Gases UQscale zero low mid high**S~s.** Cal. Gas 

### 0.0 0.0 1204.0 2246.0 1204.0 -1.2 0.0 1202.4 22A6.9 

### 1202.4 -0.05 0.00 -0.07 0.04

Ul2scale Sy:§tem Calibration Gas Calib. {nit. S)!s. Init. S)!s. Final**S~s.** FinalS)!s. Calib. 

### !'&!ml Drift Calib. Cal.**Bia~** Cafib. Cal. Bias Drift 

### SW£ (% span) Response f% Man) Response (% span) (% sQanl Conc.



### 0.16 1217.0 0.65 12012 -0.05 -0.70 743.7 0.00 1201.2 -0.05 12109 0.38 0.43 324.9 0.00 1210.9 038 1212.2 0.44 0.06 463.1 -0.11 1212.2 0.44 0.0 -53.54 -53.97 -2.4 0.00 00 -53.54 0.0 -53.54 0.00 

### ERR 0,00 00 -53.54 0.0 -53.54 0.00 

### ERR 0.00 0.0 -53.54 00 -53.54 0,00 

### ERR 0.00 0.0 -53.54 00 -5354 0.00 

### ERR 0.00 0.0 -53.54 0.0 -53.54 0.00 

### ERR 0.00 0.0 -53.54 0.0 -53.54 000 

### ERR 0.00 00 -53.54 0.0 -53.54 0.00 

### ERR 0,00 00 -5354 0.0 -5354 0,00 

### ERR3333-7E

Client Project No. Test Location Test Date Spruance Genco, LLC 3333 Unit No.3

- Acid Gases & Non DF HAPs 04/15/10

Parameter.· 

### Nitrogen Oxides (as N02) InstrumentSpan (ppmVNOxJ: 232.6

AQtual Calibration Gas Value (ppmVNOxJ: AnalyzerCalibration Response (pomVNOx): Anal)lZerCalibration Error(% Span):

ZerQ**S~stem** Calibration Gas Appa@.nt Init. SJ:::s. Init S)'.s. Final S)'.s. FinalS)'.:S:.

Stack Calib. Cal. Bias Calib. Cal. Bias 

### Run Conc. Re,s:ponse (% span) Response (% span)

203.8 

### 0.0 0.00 

### 2.4 1.03 

### 2 196.1 

### 2.4 1.03 

### 0.0 0.00 

### 3 197.S 

### 0.0 0.00 

### 0.0 0.00 

### 4 0.0 0.0 000 00 0.00 

### 5 0.0 0.0 0.00 

### 0.0 0.00 

### 6 0.0 00 0.00 

### 0.0 0.00 

### 7 0.0 0.0 0.00 

### 0.0 0.00 

## a 0.0 00 0.00 

### 0.0 0.00 g 

### 0.0 0.0 0.00 

### 0.0 0.00 

### 10 0.0 0.0 0.00 

### 0.0 0.00 

### 11 0.0 0.0 0.00 

### 0.0 0.00 

### 12 0.0 0.0 0.00 

### 0.0 0.00 

### AirNova, Inc. Page 4 EPA Method 6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

Anal)'.zerCaliP. Gas:es U{2§'Qale zero 

# """ mid high S)'.s. Cal. Gas: 

### 0.0 00 122.1 232.6 122.1 

### 0.0 0.0 120.9 230.3 120.9 0.00 0.00 -0.54 -0.99

Ugscale Sy:stem Calibration Gas Calib. In;t. S)'.:S:. Init. SJ:::s. Final,$:)'.s. FinalSJ:::s. Calib. Actual Drift**~** Cal. Bias Calib. Cal. Bias Drift Slack (% span! Response (% span) Resoonse (% span} (%soan! Conc.

1.03 120.6 -0.12 120.9 -0.02 0.09 206.9 -1.03 120.9 -0.02 122.1 

### 052 0.54 197.9 0.00 122.1 0.52 122.1 0.52 0.00 197.8 0.00 122.1 0.52 

### 0.0 -51.98 -52.49 0.0 0.00 

### 00 -51.9S 

### 0.0 -51.98 0.00 

### ERR 0.00 

### 00 -51.98 

### 0.0 -51.98 0.00 

### ERR 0.00 

### 00 -51.98 

### 0.0 -51.98 0.00 

### ERR 0.00 

### 0.0 -51.9a 

### 0.0 -51.98 0.00 

### ERR 0.00 

### 0.0 -51.9a 

### 0.0 -51.9a 0.00 

### ERR 0.00 

### 0.0 -51.9a 

### 0.0 -51.9a 0.00 

### ERR 0.00 

### 0.0 -51.9a 

### 0.0 -51.9a 0.00 

### ERR 0.00 

### 0.0 -51.9a 

### 0.0 -51.9a 0.00 

### ERR

### 3333-7E

Client Spruance Genco, LLC 3333 Project No. Test Location Test Date Unit No.3- ACId Gases 

### & Non OF HAPs 04115/10

Run



### 1 2 3 4 

### 5 6 7 B 9 

### 10 11 12 Parameter; 

### Sulfur Dioxide Instrument Span (ppmV S02): 443

Actual Calibration Gas Value (ppmVS02): AnalYZerCalibration Response (ppmV

### S02): Anal¥Z.erCalibration Error(% Span):

Zero Sy:stem Calibration Gas**Ap/2~Ustnt** Inll S!!s. Init. S\':S. Final S\,:s. FinalS\':S Stack Calib. Cal. Bias Callb_**~gl.** Bias**~** Response (% span) Response (% span)


### 37_0 5.1 

### OA6 5A 0.51 38.1 

### 5A 0_51 4.6 

### 0.35 34.7 4.6 

### 0.35 3.2 0.02 0.0 3.2 0.02 0.0 -0_70 0.0 0.0 -0.70 0.0 -0.70 00 0.0 -0_70 0.0 -0.70 0.0 0.0 -070 0.0 -0.70 0.0 0.0 -0.70 0.0 -0_70 0.0 0.0 -0.70 0.0 -0.70 0.0 0.0 -0.70 0.0 -0.70 0.0 00 -0.70 0.0 -0_70 0.0 0.0 -0.70 0.0 -0.70 

### AirNova, Inc. Page 5 EPA Method 6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

Anal¥Z.erCalib. Gases Upscale
zero low mid high S\,:s. Cal. Gas 

### 0.0 0.0 222_0 443_0 222.0 3.1 0.0 225.8 446.8 225.8 1.33 0.00 1.62 1.63

Ul2scale Sy:stem Calibration Gas Calib. Init.**~vs.** Init.**~~.** Fina.l**S~.** Final S!!s. Ca/ib. Actual Drift Ga/ib. Gal. Bias Galib_ Cal_ Bias Drift Stack (% span) Response (% span) Response (% span) f% span) Gonc.



### 0.05 225.8 0.00 225.8 0.01 0.01 32.0 -0.16 225_8 0.Q1 222.2 -0.80 -0.81 33.5 -0.33 222.2 -0.80 222.5 -0.74 0.07 31.3 -0.72 222.5 -0.74 0.0 -50.96 -50.23 -3.2 000 0.0 -50.96 0.0 -5096 0.00 

### ERR 0.00 0.0 -50.96 0.0 -50.96 0.00 

### ERR 0.00 0.0 -50.96 0.0 -50.96 000 

### ERR 0.00 00 -5096 0.0 -50.96 0.00 

### ERR 0_00 0.0 -50.96 0.0 -50_96 0.00 

### ERR 0.00 0.0 -50.96 0.0 -50.96 0.00 

### ERR 0.00 0.0 -50.96 0.0 -50.96 0.00 

### ERR 000 0.0 -50.96 0.0 -50.96 0.00 

### ERR3333-7E

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit NO.3

- Non Dioxm/Furan HAPs 04/15110

Parameter. 

### Total Hydrocarbons (as InstrumentSpan (ppmV THC): 20

Actual Calibration 

### Gas Value (ppm V THC): AnalyzerCalibra/ion Response (ppm V THC!: AnalyzerCalibration Error(% Cal. Gas Value):

Zero**S~stem** Calibration Gas AQQarent Init. Svs. InIt. S:vs. FinalS,,-s. Final S,,-s.

Stack Calib. Cal. Bias Calib. Cal. Bias Run Cone. Response (% span) ReSPonse (% span)



### 1 0.9 -0.0 000 0.1 0.75 2 0.3 

## o1 0.75 -0.1 -0.20 3 0.3 -0.1 -0.20 -0.1 -0.65 4 0.0 -0.1 -0.65 0.0 0.05 5 0.0 0.0 

### 0.05 0.0 0.05 6 0.0 0.0 0.05 0.0 0.05 7 

### 0.0 0.0 0.05 0.0 0.05 B 

### 0.0 00 0.05 00 0.05 9 0.0 0.0 0.05 00 0.05 10 0.0 00 0.05 0.0 0.05 11 0.0 0.0 0.05 0.0 005 12 0.0 0.0 0.05 0.0 0.05 

### AirNova, Inc. PageS EPA Method SC Calculations (Cal. Error, Bias Driftand Bias Adjustment)



### C3H8 ) Ana/,,-zerCalib. Gases Upscale zero low mid high 

### S"-s. Cal. 

### Gas 

### 0.0 4.9 9.1 17.0 9.1 -0.0 4.9 9.1 

### 17A 9.1 -0.10 -0.20 1.65**U~scale S~stem**  Calibration Gas Calib. Init. Sl!s. Init. S,,-s. Final**S~.** Final

### S"-S Calib. Actual Drift**~** Cal. Bias Calib. Qal. Bias Drift Stack (% span! Response (% span) Response (% span) (% span) Cone.



### 0.75 9.1 0.00 9.0 -0.30 -0.30 0." -0.95 9.0 -0.30 9.1 0.05 0.35 0.2 -0.45 9.1 0.05 9.0 -0.35 -OAO 

### 0.3 0.70 9.0 -0.35 0.0 -45.25 -44.90 0.1 0.00 00 -45.25 0.0 -45.25 0.00 

### ERR 0.00 0.0 -45.25 00 -45.25 0.00 

### ERR 0.00 0.0 -45.25 0.0 -45.25 000 

### ERR 0.00 0.0 -45.25 0.0 -45.25 0.00 

### ERR 000 0.0 -45.25 0.0 -45.25 0.00 

### ERR 0.00 00 -45.25 0.0 -45.25 0.00 

### ERR 0.00 0.0 -45.25 0.0 -45.25 0.00 

### ERR 0.00 0.0 -45.25 0.0 -45.25 0.00 

### ERR

### 3333-HCI-HF-R1



### Client Project No. Test Location Test Run 

### Test Date 

### Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vic

# = Vm= Pstatic = 

### Pb

# = Ps

# = Pstd

# = dP = 

### dH

# = Tm= Ts

# = Tstd= On = 

### An

# = y= 1= 

### Os

# = As= Cp= 

### Kp = 

### K1 

# = K2= 

### K3

# = Fd

# = CF = 

### CF

# =

[02] [C02]


### [N2] 

## AirNova, Inc. EPA Methods 1,2,3A,4,and 26A (Flows, 

### 02/C02, H20,and HCI/HF) 

## Spruance Genco, LLC 

## 3333 Unit No.3 One 04/15/10 

## 0900-1211

343 

## cc 113.979 dcfEmission Data

-0.50 

### in H20 30.44 

### in. Hg 

### 30.40 

### in. Hg 29.92 

### in H9 

### 0.7037 in 

### H20 

### ".5

1.414 in. H20 527.1 

### R 654.4 

### R 527.7 

### R



### 0.25 in. 0.000341 sq. 

### ft. 1.01 

### 180 

### min. 10.300 

### ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure 

### Stack pressure EPA Standard pressure Average sq 

### rt delta P Average draft gauge reading Average metertemperature Average stacktemperature Standard temperature Nozzle diameter Area ofnozzle orifice Metercalibration factor Duration ofsampling time Diameterofstack 83 323 sq. ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)"(inHg)]".5}/[s"R"rnH20] Pitot tube constant 17.637 R/in.Hg 0047070 cu.ftlml 0.0026688 in.Hg-cf/ml-R 9862 scf/MMBtu 9.461E-OB Ib/dscf

### I ppmVd 5.192E-OB Ib/dscf

### I ppmVd



### Instrumental Data

4.24 %-dry 14.26 %-dry

81.50 %-dry constant constant constant Fuel Factor Conversion Factorfor HCI Conversion Factorfor HF

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions,Vmstd.



### Vmstd =K1'Y'Vm ' (Pb + 

### dHI13.6) I Tm Vmstd

# = 117.650 dscf 3.33 dscm Unit NO.3 One

2) Volume ofwatervaporcollected atstandard conditions, Vw(std).


### Vw(std) = K2 'Vic Vw(std) = 16.145scf
3) Decimal fraction ofmoisture by volume in stack gas, Bws.



### Bws

# = Vwstd / (Vmstd+Vwstd) Bws= 0.121
4) Molecularweight ofthe stackgas on awet basis, Ms.



### Ms = [((44'%C02) + 

### (32'%02) + 

### (2S'%N2))' (1-Bws) 

## I + 

### (1S-Bws) Ms = 

### 28.95 Ib/lbmole
5) Average stack gas velocity, Vs.



### Vs = Kp' Cp

- (dP) , (TsIPs'Ms)'.5 Vs= 43.57 fps
6) Average actual stack gas volumetric flowrate, Qa.
Qa

# = 60 sec/min"Vs ,. As Qa

# = 217831.4 cfm 

### 6169.0 cmm
7) Average stack gas dry volumetric flowrate, Qstd.


### Qstd = Qa

- (Tstd/Ts)' (PsIPstd)' (1-Bws) Qstd

# = 156962.8 dscfm 4445.2 dscmm Page 2

### Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

Calculations (cont.)
8) Hydrogen Chloride Concentration and Emissions Unit NO.3 One

M[HCI) 

### = M[CI-)(mg) ° MW[HCI)(mglmmol) 1MW[CI-)(mglmmol) 

### Page 3

C[HCI) = (M[HCI)(mg) ° 2.205E-06(lblmg) ° 21.85(scf"inHgllbmoIOR) ° K1 '10A 6) 1(MW[HCI](Ibllbmol)'Vmstd(d C[HCI)(@corr. 02)

# = C[HCI)(ppmV)' [(20.9-corrected 02) 1(20.9-8ctU81 %02)) E[HCI)

# =M[HCI)(mg) ° Qstd(dscfm) • (2.20SE-06)(lblmg) ° 60(minlhr) 1Vmstd(dscf) E[HCI)

# = C[HCI)(ppmV) ° Fd ° CF(HCI) ° (20.91(20.9-%02))
M[HCI)

# = 0.13 mg C[HCI)

# = 0026 ppmV C[HCI)

# = 0.021 ppmV (@ 7.0 

### %02) E[HCI)

# = 0.023 Iblhr E[HCI)

# = 3.02E-OS IblMMBtu


### 9) Hydrogen Fluoride Concentration and Emissions
C[HF)

# =M[HF)(mg) 1Vmstd(dscm) C[HF)

# =(M[HF)(mg) ° 220SE-06(1blmg) ° 21 8S(scf"inHgllbmoIOR) ° K1 ° 1OA6) 1(MW[HF)(lbllbmol) ° Vmstd(dsc C[HF)(@corr. 02)

# = C[HF)(mgldscm) ° [(20.9-corrected 02) 1(20.9-8ctu81 %02)) E[HF)

# = C[HF)(mgldscm) ° Qstd(dscmm) ° (2.20SE-06)(lblmg)·60(minlhr) E[HF)

# = C[HF)(ppmV)' Fd' CF(HF)' (20.91(20.9-%02))



### < M[HF) 

### = < C[HF) = 

### < C[HF) 

### =
< C[HF)

# = < E[HF)

# = < E[HF)

# = 10) Isokinecity, I. 0.030 mg 

### 0.009 mg/dscm 0.011 ppmV 0.009 ppmV (@ O.OOS Iblhr 6.96E-06 IblMMBtu 70

% 1

# =(1 00"Ts·(K3°Vlc+(VmoYlTm)(Pb+dHI13.6)))1(600tOPs'VsoAn) 

### %1= 101.8 % 

### 02)

### 3333-HCI-HF-R2



### Client Project No. Test Location Test Run Test Date 

### TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vlc= Vm= 

### Pstatic

# = Pb

# = Ps = 

### Pstd

# = dP

# = dH

# = Tm= Ts

# = Tstd= 

### On

# = An

# = y= t= Ds

# = As= Cp= 

### Kp

# = K1 

# = K2= 

### K3

# = Fd

# = CF 

### = CF=

[02[ [C02[
[N2[ 

## AirNova, Inc. EPA Methods 1,2,3A,4,and26A (Flows, 021C02, H20,and HCIIHF) 

### Spruance Genco, LLC 

## 3333 Unit No.3 Two 

## 04/15/10 1308-1615

340.4 

## cc 114.615 def

### Emission Data

-0,50 

### in, 

### H20 30.37 in. Hg 30.33 in. Hg 29.92 in. Hg 

### 0.6879 in. 

### H20 

### '\5

1.394 In, 

### H20 545.0 R 656.5 R 527.7 

### R



### 0.25 in. 0.000341 sq. ft. 1.01 

### 180 min, 10.300 ft. 

### Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area ofnozzle orifice Meter calibration factor Duration ofsampling time Diameter ofstack 83.323 sq. 

### ft. Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lbllbmolr(inHg)j'.5}/[s·R·inH20] PltOt tube constant 

### 17.637 R/in Hg 0.047070 cu ftlml 0.0026688 in.Hg-ef/ml-R 

### 9755 scf/MMBtu 9.461 E-08 Ibldsef

### I ppmVd 5.192E-08 Ibldsell ppmVd



### Instrumental Data



### 4.08 %-dry 

### 14.33 %-dry

81.59 %-dry constant constant constant Fuel Factor Conversion Factor for HC] Conversion Factorfor HF

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. 

### SprLlance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1)

### Volume ofgas sampled atstandard conditions, Vmstd.



### Vmstd =K1'Y'Vm' (Pb + 

### dH/13.6) I

### Tm Vmstd = 

### 114.167 dscf 

### 3.23 dscm Unit No.3 

### Two

2) 

### Volume ofwatervapor collected atstandard conditions, Vw(std). 

### Vw(std) = K2 • Vic Vw(std) = 16.023 sef
3) 

### Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws =Vwstd I (Vmstd+Vwstd) Bws= 

### 0.123
4) Molecularweight ofthe stack gas on awet basis, Ms.



### Ms = [((44'%C02) 

### + (32'%02)

### + (2S'%N2))' (1-Bws) 

## I+ (18'Bws) Ms= 

### 28.92 Ib/lbmole
5) 

### Average stack gasvelocity, Vs.



### Vs = Kp' Cp' (dP)' (Ts/Ps'Ms)".5 Vs= 

### 42.73 fps
6) 

### Average actual stackgasvolumetric flowrate, Qa.

Qa 

### = 

### 60 sec/min·Vs * 

### As Qa

# = 213644.4 cfm 

### 6050.4 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.


### Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) Qstd

# = 152666.3 dscfm 4323.5 dscmm Page 2

### Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

Calculations (cont.)


### 8) Hydrogen Chloride Concentration and Emissions Unit No.3 

### Two

M[HCI[ 

### = M[CI-[(mg) , MW[HCI](mglmmol) 1MW]CI-[(mglmmol) Page 3



### C[HCI]

# =(M]HCI](mg) , 2.205E-06(lblmg) • 21.85(scf"inHgllbmol'R) • K1 ' 10A6) 1(MW[HCI](lbllbmol) 'Vmstd(d C[HCI](@corr. 02)

### = C[HCI](ppmV)' [(20 9-corrected 02) 1(20.9-actual %02)] E[HCI] 

### = M[HCI](mg) , Qstd(dscfm) , (2.205E-06)(lblmg) '60(minlhr) 1Vmstd(dscD E[HCI] = 

### C[HCI](ppmV)' Fd' CF(HCI)' (20.91(20.9-%02))
M[HCI] = 

### 0.09 mg C[HCI] = 

### 0.018 ppmV C[HCI]

# = 0.015 ppmV (@ 7.0 

### %02) E[HCI] = 

### 0.016 Iblhr E[HCI] = 

### 2 11E-OS IblMMBtu


### 9) Hydrogen Fluoride Concentration and Emissions


### C[HF]

# =M[HF](mg) 1Vmstd(dscm) C[HF]

# =(M[HF](mg)' 2.205E-06(1blmg)' 21.85(scf"inHgllbmol·R)· K1 '10A6) 1(MW[HF](Ibllbmol)'Vmstd(dsc C[HF](@corr. 02)

# = C[HF](mgldscm)' [(20.9-corrected 02) 1(20.9-actual %02)] E[HF] = 

### C[HF](mgldscm)' Qstd(dscmm)' (2.20SE-06)(lblmg)'60(minlhr) E[HF] 

### = C[HF](ppmV)' Fd' CF(HF)' (20.91(20.9-%02))

< 

### M[HF]

# = < C[HF]

# =
< 

### C[HF]

# =
< 

### C[HF] 

### = < 

### E[HF] = 

### < E[HF]

# = 10) Isokinecity, I. 

### 0040 mg 0.012 

### mgfdscm 

### 0.015 ppmV 0.012 ppmV (@ 0.007 

### Ibfhr 

### 9.36E-06 IblMMBtu 7.0

% 1

# =(100·Ts'(K3-Vlc+(Vm'YlTm)(Pb+dHI13.6)))1(60·t'Ps·Vs'An) %1= 101.6 

### %02)

### 3333-HCI-HF-R3



### Client 

### Project No. Test Location Test Run Test Date 

### Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vic

# = Vm= Pstatic

# = Pb 

### = Ps 

### = Pstd = 

### dP

# = dH 

### = Tm= 

### Ts= Tstd= 

### On

# = An

# = y= t = 

### Ds= As

# = Cp= 

### Kp 

### = K1 

### = K2= K3

# = Fd

# = CF

# = CF=

[02] ]C02]
]N2] 

## AirNova, Inc, EPA Methods 1,2,3A,4,and 26A (Flows, 

### 02/C02, H20,and HCI/HF) 

## Spruance Genco, 

## LLC 

## 3333 Unit No.3 Three 04/15/10 

## 1724-2033

341.9 

## cc 118.979 dcfEmission Data**~O.50** 

### in 

### H20 30.25 in. Hg 30.21 in. 

### Hg 29.92 in. Hg 

### 0.7029 in. 

### H20 

### ",5

1.479 

### in H20 548.3 R 6424 R 527.7 R



### 0.25 

### in. 0.000341 sq ft. 1.01 

### 180 min. 10.300 ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature 

### Nozzle diameter Area ofnozzle orifice Metercalibration factor Duration ofsampling time Diameterofstack 83.323 sq. ft. Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lbllbmol)"(inHg)]A.S}/[s·WinH20] Pitottube constant 17.637 R/in.Hg 0.047070 cu.ftlml 0.0026688 In.Hg-cf/ml-R 9868 scf/MMBtu 9.461 E-08 Ib/dscf

### I ppmVd 5.192E-08 Ib/dscf

### I ppmVd

Instrumental Oata

3.98 %-dry 14.33 %-dry

81.69 %-dry constant constant constant Fuel Factor Conversion Factorfor HCI Conversion Factorfor HF

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. 

### Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled at standard conditions,Vmstd.



### Vmstd =K1"Y"" Vm" (Pb 

### + dH/13.6) I 

### Tm Vmstd

# = 117.354 dsef 

### 3.32 dsem 

### Unit No.3 Three

2) Volume ofwatervaporcollected atstandard conditions,Vw(std).


### Vw(std)

# =K2 ' Vic Vw(std) = 

### 16.093 scI
3) Decimal fraction ofmoisture by volume in stack gas, Bws.



### Bws

# = Vwstd 

### I (Vmstd+Vwstd) Bws= 0.121
4) Molecularweight ofthestackgas on awet basis, Ms.



### Ms 

### = [ ((44'%C02) + 

### (32'%02) + 

### (28'%N2)) , (1-Bws) ) + 

### (18'Bws) 

### Ms= 28.95 Ib/lbmole
5) Average stack gas velocity, Vs.



### Vs

# =Kp' Cp' (dP) , (TsfPs'Ms)'.5 Vs

# = 43.26 Ips
6) Average actual stack gas volumetric flowrate, Qa.



### Qa 

### =60 sec/min"Vs " As 

### Qa

# = 216265.1 elm 6124.6 emm
7) Average stack gas dry volumetric flowrate, Qstd.


### Qstd 

### =Qa' (TstdfTs)' (PsfPstd)' (l-Bws) Qstd 

### = 157766.4 dscfm 4467.9 dsemm Page 2

### Client Spruance Genco, LLC Project No. 

### 3333 Test Location Test Run

Calculations (cont.)


### 8) Hydrogen Chloride Concentration and Emissions Unit 

### No.3 Three

M[HCI]

# =M[CI-](mg) • MW[HCI](mg/mmol) 

### 1MW[CI-](mg/mmol) 

### Page 3

C[HCI]

# =(M[HCI](mg) • 2.205E-06(lb/mg) • 21 85(scf"inHg/lbmol'R) • K1 • 10'6) 

### 1(MW[HCI](Ibllbmol) • Vmstd(d C[HCI](@corr. 02)

# = C[HCI](ppmV)' [(20.9-corrected 02) 

### 1(20.9-actual %02)] E[HCI]

# =M[HCI](mg)' Qstd(dscfm)' (2.205E-06)(lb/mg)· 60(min/hr) 

### 1Vmstd(dscf) E[HCI] = 

### C[HCI](ppmV)' Fd' CF(HCI)' 

### (20.9/(20.9-%02))
M[HCI] 

### = 0.11 mg C[HCI] 

### = 0.022 ppmV C[HCI] 

### = 0.018 ppmV (@ 7.0 

### %02) E[HCI] 

### = 0.020 Ib/hr E[HCI] 

### = 2 52E-05 Ib/MMBtu
9) Hydrogen Fluoride Concentration and Emissions
C[HF]

# =M[HF](mg) 

### 1Vmstd(dscm) C[HF]

# =(M[HF](mg) • 2205E-06(lb/mg) • 21.85(scf"inHg/lbmol·R) • K1 • 10'6) 

### 1(MW[HF](Ib/lbmol) • Vmstd(dsc C[HF](@corr. 02)

# = C[HF](mg/dscm)' [(20.9-corrected 02) 

### 1(20.9-actual %02)] E[HF]

# = C[HF](mg/dscm) • Qstd(dscmm) • (2205E-06)(lb/mg) • 60(m.n/hr) E[HF]

# = C[HF](ppmV)' Fd' CF(HF)' 

### (20.9/(20.9-%02))



### < M[HF] 

### = < C[HF]

# = < C[HF]

# =
< C[HF]

# = < E[HF] 

### = < E[HF] 

### = 

### 10) Isokinecity,l. 0.040 mg 

### 0.012 

### mg/dscm 0.014 ppmV 0.012 ppmV (@ 0.007 Ib/hr 9.16E-06Ib/MMBtu 7.0

% 1

### = (1 00·Ts·(K3·Vlc+(Vm·YlTm)(Pb+dH/13.6)))/(60·t·Ps-Vs·An) 

### %1= 

### 101.0 % 

### 02)Client Project No. Test Location Fuel Type Test Run Test Date Time Period



### INPUT INPUT INPUT INPUT

INPUT 

### INPUT INPUT 

### INPUT

INPUT

INPUT

INPUT

INPUT INPUT



### INPUT INPUT INPUT INPUT INPUT Vic 

### = Vm= Pstatic 

### = Pb

# = Ps = Pstd = dP

# = dH = Tm 

### = Ts = Tstd= y= t= On = An

# = Os = As 

### = Cp = Kp 

### = K1 = 

### K2= K3 = Fd

# =

[02[ [CO2] [N2] [CO] [THC] [CH4] [NOx] [S02] 

### AirNova, Inc. Page 1

### of4 EPA Methods 

### 1, 2, 3A, 

### 4, 6, 7E, 

### 10, 18 and 2SA (Flows, 

### 02/C02, H20, 502, NOx, CO and NMHC)
Spruance Genco, LLC 

### 3333 Unit NO.3 Coal One 

### 04/15/10 0900-1211

343 ccEmission Data

113.979 dcf -0.50 in. H20 30.44 in. Hg 30.40 in Hg 29.92 in. Hg 0.7037 in H20 ".5 1.41 in. H20 527.1 R 

### 654.4 R 527.7 R



### 1.01

180 min. 0.250 in 0.000341 sq. ft. 10.300 

### ft. 83.3231 sq. ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameterofstack Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)"'(inHg)]" 5}/[s"*R*inH20] 17.637 R/in.Hg constant 0.047070 cu.ftIml constant Pitot tube constant 0.0026688 in.Hg-cf/ml-R constant 9862 scf/MMBtu From EPA Reference Method 19

Instrumental Data 4.24 %-dry Oxygen concentration 

### 14.26 %-dry Carbon Dioxide concentration 81.50 %-dry Nitrogen concentration 743.7 ppmV-dry Carbon Monoxide concentration

0.8 ppmV-wet Total Hydrocarbon concentration 

### 0.0 ppmV-dry Methane Concentration by GC-FID 206.9 ppmV-dry Nitrogen Oxides concentration

32.0 ppmV-dry Sulfur Dioxide concentrationClient Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled at standard conditions, Vmstd.

Vmstd =K1* 

### Y" Vm " (Pb 

### + dH/13.6) 

### ITm Vmstd 

### = 117.650 dscf 3.332 dscm Unit NO.3 One

2) Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw{std) = K2 *Vic Vw{std) 

### = 16.145 scf
3) Decimal fraction of moisture byvolume in stack gas, Bws.

Bws = Vwstd 

### I (Vmstd+Vwstd) Bws = 0.1207 4) Molecularweightofthestack gas ona wet basis, Ms.

Ms

# = [((44*%C02) 

### + (32"%02) + (28"%N2))" (1-Bws) 

## 1 + (18"Bws) Ms= 28.949 Ib/lbmole
5) Average stackgas velocity, Vs.

Vs = Kp * Cp" (dP) • (Ts/Ps"Ms)".5 Vs 

### = 43.572 fps
6) Average actual stackgas volumetricflowrate, Qa.
Qa

# = 60 sec/min "Vs., As Qa = 217831.4 cfm 6169.0 cmm 7) Average stack gas dryvolumetricflowrate, Qstd.
Qstd

# = Qa" (Tstd/Ts)" (Ps/Pstd)" (1-Bws) Qstd = 156962.8 dscfm 4445.2 dscmm Page 2 of4Client Project No. 

### Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations (cant.)

### Unit No.3 One Page 3 of4

8) Total Hydrocarbon concentrations and emissions



### INPUT CfTHC] dry basis

# = C[THC] wetl(1-Bws) C[VOC] dry bas", 

### =C[THC]- C[CH4] Carr. C[CH4] = 

### «20.9-02%carr. value)/(20.9-actual avg. 02% value))*VOC value E[VOC]

# = (C[VOC]*Mol Wt[VOC equivalent]*60(min/hr)*Qstd(dscfm»/{MolarVol. air*10"6) E[VOC Ib/MMBtu]

# = Cd" Fd" (20.9/(20.9·actual 02%» C[THC] = 0 8 ppmVw C[THC] = 

### 0 9 ppmVd C[CH4] 

### = 0.0 ppmVd C[VOC] 

### = 0.9 ppmVd C[VOC] = 0.8 ppmVd corrected to 7 % 02 Mol. 

### wt. [THC]= 44096 Ib/lb-mole Propane Molarvol air= 385 scf/lb-mole 

### @ 68 def F E[VOC] = 0.98 Ib/hr Conv Factor. E]VOC] = 

### 4.134E-08 convert ppmV to Ib/scf THC as CH4 4.65E-04 Ib/MMBtu 9) Nitrogen Oxides concentrations and emissions


### Carr. C[NOx] = 

### «20.9-02%carr. value)/{20.9-actual avg. 02% value))*Avg. raw NOx value E[NOx] = (C{NOx]*Mol Wt[NOx]*60{min/hrtQstd(dscfm))/(Molar Vol. air"'10"6) E[NOx Ib/MMBtu] = Cd

... Fd

... (20.9/(20.9-actual 02%)) C[NOx] = 

### 206.9 ppmVd C[NOx]

# = 172.6 ppmVd corrected to 7 % 02 Mol. Wt. [NOxl= 46.01 Ib/lb-mole Molarvol alr= E]NOx] = 

### Conv Factor. E]NOx] 

### = 385 scf/lb-mole @ 

### 232.86 Ib/hr 

### 68
1.194E-07 convert ppmVto Ibfscf NOx 0.306 Ib/MMBtu defFClient Project No. 

### Spruance Genco, LLC 

### 3333 Test Location Test Run 

### Unit No, 3 One Page4of4

10) Carbon Monoxide concentrations and emissions


### Corr. C[CO] = «20.9-02% corr, value)/(20.9-actual avg. 02% value»*Avg. raw CO value E[CO Ib/hr] = (C[CO]*Mol Wt[CO]*60(minfhr)*Qstd(dscfm»/{MolarVol. air'*10"6) E[CO Ib/MMBtu] = Cd '* Fd * (20.9/{20.9-actual 02%» 

### qCO] = 

### 743.7 ppmVd C[CO] = 620.5 ppmVd corrected to 7 % 02 Mol. WI. [CO]= 28.01 Ib/lb-mole Molarvol air= 

### EICO] 

### = Conv Factor. 

### EICO] 

### = 385 scf/lb-mole@ 509.56 Ib/hr 7235E-08 convert ppmV to Ib/scfCO 0.666 Ib/MMBtu
11) Sulfur Dioxide concentrations and emissions 

### 68 def F

Corr, C[S02] = {(20.9-02% corr. value)J{20,9-actuaJ avg. 02% value»*Avg. raw S02value E(lb/MMBtu) = Cd(lb/scf) * Fd{scf/MMBtu) * 

### [20.91 (20,9-% 02)] E[S02Ib/hr] = (C[S02l"'Mol Wt[S02]*60(min/hr)*Qstd(dscfm»/{MolarVol air*10"6) C[S02] = 32.0 ppmV (dry) Actual Conc. C[S02] = 26,7 ppmVd corrected to 7 % 02 Mol. Wt. [S02]= 64.06Ib/lb-mole Molarvol air= Conv Factor. 

### EIS02] = 

### EIS02]

# = 385 scf/lb-mole @ 68 1.66E-07 convert ppmV to Ib/scf S02 0066 Ib/MMBtu 50,14 Ib/hr defFClient Project No. Test Location Fuel Type Test Run Test Date Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT INPUT

INPUT INPUT INPUT INPUT INPUT Vic = Vm= Pstatic = Pb 

### = Ps

# = Pstd = 

### dP

# = dH = Tm 

### = Ts

# = Tstd= 

### y= t = On

# = An = Os

# = As

# = Cp = Kp 

### = K1 = K2

# = K3 = Fd

# =

[02[ [C02[ [N2] [CO] [THC] [CH4] [NOx] [S02] 

### AirNova, Inc. Page 1 of4 EPA Methods 

### 1, 2. 3A, 

### 4, 6, 7E, 

### 10, 18 and 25A (Flows, 02/C02, H20, 802. NOx, CO and NMHC)
Spruance Genco, LLC 3333 Unit NO.3 Coal 

### Two 04/15/10 1308-1615

340.4 ccEmission Data

114.615 dcf -0.50 in. H20 30.37 in. Hg 30.33 in. Hg 29.92 in. Hg 0.6879 in. H20 ".5 1.39 in. H2O 

### 545.0 R 656.5 

### R 527.7 

### R

1.01

180 min. 0.250 in. 0.000341 sq. ft. 10.300 ft. 83.3231 sq. ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge readmg Average metertemperature Average stacktemperature Standardtemperature Meter calibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameter ofstack Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lbllbmol)*{inHg)]".

### 5}/[ s*R"1nH20] 17.637 R/in.Hg constant 0.047070 cu fUml 0.0026688 in.Hg-cf/ml-R 9755 scf/MMBtu

Instrumental Data 4.08 %-dry 14.33 %-dry 81.59 %-dry 3249 ppmV-dry

0.2 ppmV-wet 0.0 ppmV-dry 197.9 ppmV-dry

33.5 ppmV-dry constant Pitot tube constant constant From EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Carbon Monoxide concentration Total Hydrocarbon concentration Methane Concentration by GC-FID Nitrogen Oxides concentration Sulfur Dioxide concentration

### Client Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations 1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1* Y"Vm " (Pb + dH/13.6) 

### ITm Vmstd= 114.167 dscf 3.233 dscm Unit No.3 

### Two

2) Volume otwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2

.. VIc Vw(std)

# = 16.023 sef 3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws = Vwstd I 

### (Vmstd+Vwstd) Bws= 0.1231 4) Molecularweightofthe stack gas on awet basis, Ms.

Ms 

### =[«44*%C02)+ (32*%02) 

### + (28*%N2»" (1-Bws) 

## 1 +(18*Bws) Ms= 28.923 Ib/lbmole
5) Average stackgas velocity, Vs.

Vs = Kp

.. Cp " (dP)

.. (Ts/Ps"Ms)".5 Vs

# = 42.734 fps 6) Average actual stack gas volumetric f1owrate, Qa.
Qa = 60 sec/min" Vs

.. As Qa = 213644.4 cfm 6050.4 emm 7) Average stack gas dryvolumetric f1owrate, Qstd.
Qstd 

### =Qa

.. (Tsld/Ts)

.. (Ps/Pstd)

.. (1-Bws) Qstd = 

### 152666.3 dscfm 4323.5 dscmm Page 20f4Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations (cont.)Unit NO.3 

### Two Page 3 of4

8) Total Hydrocarbon concentrations and emissions

INPUT C[THC] dry basis = C[THC] wet/(1-Bws) C[VOC] d<y basis

# = C[THC[

- C[CH4] Corr. C[CH4] = ({20.9-02% corr. value)/(20.9-actual avg. 02% value))*VOC value E[VOC] = (C[VOC]*Mol Wt[VOC equivalent]*60(min/hr)*Qstd(dscfm»)/(MolarVol air*10"6) E[VOC Ib/MMBtu] = Cd

.. Fd * (20.9/(20.9-actual 02%)) C[THC] = 0.2 ppmVw C[THC] 

# = 0.2 ppmVd C]CH4] 

# = 0.0 ppmVd C]VOC]

# = 0.2 ppmVd qVOC] = 0.2 ppmVd corrected to 7 

### % 02 Mol. Wt. [THC]= 44.096 Ib/lb-mole Propane Molarvol air= 385 scf/lb-mole 

### @ 68 def F E[VOC] = 0 24 Ib/hr Conv Factor. E[VOC] = 4.134E·08 convert ppmV to Ib/scfTHC as CH4 1.14E-04Ib/MMBtu 9) Nitrogen Oxides concentrations and emissions
Carr. C[NOx] = «20.9-02%carr. value)/(20.9-actual avg. 02% value))*Avg. raw NOxvalue E[NOx] = (C[NOxl"Mol Wt[NOx]*60(min/hr)*Qstd{dscfm))/{Molar Vol. air*10"6) E[NOx Ib/MMBtu] = Cd * Fd

.. (20.9f(20.9-actual 02%» C[NOx] = 197.9 ppmVd C[NOx] = 163.5 ppmVd corrected to 7 % 02 Mol. Wt. [NOx]= 4601 Ib/lb-mole Molarvol air= E[NOx]

# = Conv Factor. E[NOx] = 385 scf/lb-mole 

### @ 68 216.64 Ib/hr 1.194E-07 convert ppmV to Ib/scf NOx 0.286 Ib/MMBtu defFClient Project No. Spruance Genco, LLC 3333 Test Location Test Run Unit NO.3 

### Two Page 4 of4

10) Carbon Monoxide concentrations and emissions
Corr. C[CO] = «20.9-02%carr. value)/(20.9-actual avg. 02%value»*Avg. raw CO value E[CO Ib/hr) = (C[CO]*Mol Wt[CO]*60(min/hrYOstd(dscfm»/(MolarVol. air'10"6) E[CO Ib/MMBtu] = Cd ., Fd * (20.9/(20.9-actual 02%)) C[CO] 

### = 324.9 ppmVd C[CO] = 268.5 ppmVd corrected to 7 % 02 Mol. Wt. [CO]= 28.01 Ibflb-mole Molarvol air= E]CO]

# = Conv Factor.**E]CO]~** 385 scf/lb-mole 

### @ 216.52 Ib/hr 7.235E-08 convert ppmVto Ib/scf CO 0.285 Ib/MMBtu
11) Sulfur Dioxide concentrations and emissions 

### 68 def F

Corr. C[S02] = «20.9-02% corr. value)/(20.9-actuaJ avg. 02% value))*Avg. raw S02 value E(lb/MMBtu)

# =**Cd(lb/sc~'** Fd(scflMMBtu) 

### ']20.91 (20.9-% 02)] E[S02 Ib/hr] = (C[S02]*Mol Wt[S02]*60(min/hr)*Qstd(dscfm))/(MolarVol. air*10"6) C[S02]

# = 33.5 ppmV (dry) Actual Conc. C[S02]

# = 27.7 ppmVd corrected to 7 % 02 Mol. Wt. [S02]= 64.06 Ib/lb-mole Molarvol air= Cony Factor E[S02] = E[S02]

# = 385 scf/lb-mole 

### @ 68 1.66E-07 convert ppmV to Ib/scfS02 0.067 Ib/MMBtu 51 06 Ib/hr defF

### Client Project No. Test Location Fuel Type Test Run Test Date Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT INPUT

INPUT INPUT INPUT INPUT INPUT Vic = Vm= Ps1alic = Pb 

### = Ps 

### = Pstd 

### = dP 

### = dH = 

### Tm 

### = Ts

# = Tstd= y= t 

### = Dn 

### = An 

### = Ds = As 

### = Cp= Kp 

### = K1 = 

### K2= K3 

### = Fd 

### =

[02[ [C02[ [N2[ [COl [THC) [CH4J [NOxJ [S02J 

### AirNova, Inc. Page 1 of4 EPA Methods 

### 1, 2, 3A, 4, 6, 7E, 

### 10, 18 and 

### 2SA (Flows, 02/C02, 

### H20, 802, NOx, CO and NMHC)

Spruance Genco, LLC 3333 Unit NO.3 Coal Three 

### 04/15/10 1724-2033

341,9 cc

### Emission Data

118,979 dcf -0.50 in. H20 30.25 in. Hg 30.21 in. Hg 29.92 in. Hg 07029 in. H20 ".5 1.48 in. H20 5483 R 642_4 R 5277 R

1.01

180 min. 0.250 m. 0.000341 sq. 

### ft. 10.300 

### ft. 83.3231 sq. 

### ft. Vol. of H20 collected Dry gas meier reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration of sampling lime Nozzle diameter Nozzle area Diameter ofstack Cross sectional area ofstack 0.84 Pitoltube coefficient 85.49 ft[(lbllbmol)"(inHgJr.5JI[s·R"inH20J 17.637 R/m.Hg 0.047070 CU.ft!ml 0.0026688 in.Hg-cf/ml-R 9868 scf/MMBtu

Instrumental 

### Data 3.98 %-dry 14.33 %-dry 81,69 %-dry 463.1 ppmV-dry

0,3 ppmV-wet 0.0 ppmV-dry 197.8 ppmV-dry 31.3 ppmV-dry constant constant constant Pitot tube constant

From 

### EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Carbon Monoxide concentration Total Hydrocarbon concentration Methane Concentration by GC-FID Nitrogen Oxides concentration Sulfur Dioxide concentration

### Client Project 

### No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1)

### Volume ofgas sampled at standard conditions, Vmstd.

Vmstd**=K1~** 

### y'" Vm

.. (Pb + dH/13.6) ITm Vmstd = 117.354 dscf 3.323 dscm Umt NO.3 Three

2) 

### Volume ofwatervapor collected atstandard conditions, Vw(std). Vw(std) = K2

.. Vic Vw(std) = 16.093 scf
3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws =Vwstd I 

### (Vmstd+Vwstd) Bws = 0.1206
4) 

### Molecularweightofthe stack gas on awet basis, Ms.

Ms 

### =[«44*%C02) 

### + (32"%02) 

### + (28*%N2))" (1-Bws) 

## 1 + (18"Bws) Ms= 28 950 Ib/lbmole
5) 

### Average stackgas velocity, Vs.

Vs = Kp

.. Cp " (dP) .., (Ts/Ps*Ms)i'.5 Vs 

### = 43.258 fps
6) 

### Average actual stackgas volumetric flowrate, Qa.
Qa = 

### 60 sec/min"Vs .., As Qa = 216265.1 cfm 6124.6 cmm 7) Average stackgas dry volumetric flowrate, Qstd.
Qstd = Qa'" (TstdfTs)" (Ps/Psld)'" (1-Bws) Qstd 

### = 157766.4 dscfm 4467.9 dscmm Page 2 of4Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations (cont.)Unit No 3 Three Page 3 of4

8) Total Hydrocarbon concentrations and emissions

INPUT C[THCJ dry basis = C[THC] weV{1-Bws) C[VOC[ dry basis 

### =C[THC]

- C]CH4] Corr. C[CH4] = (20.9-02% carr. value)/(20.9·actual avg. 02% value»*VOC value E[VOCJ = (C[VOCJ*Mol WtlVOC**equivalent]*60(mm/hr)~Qstd(dscfm»/(Molar** Vol. air*1 0"6) E[VOC Ib/MMBlu] = Cd ,. Fd 

### * (20.9/(20.9-actual 02%)) C[THC] 

# = 0.3 ppmVw C[THC] = 0.3 ppmVd C[CH4] 

# = 0.0 ppmVd C[VOC[

# = 0.3 ppmVd qVOCj = 0.3 ppmVd corrected to 7 % 02 Mol. Wt. [THC}= 44.096 Ibllb-mole Propane Molarvol air= 385 scf/lb-mole 

### @ 68 def F E[VOC] = 0.37 lb/hr Conv Factor. E[VOC] = 4.134E-08 convert ppmV to Ib/scfTHC as CH4 1.72E-04 tb/MMBtu 9) Nitrogen Oxides concentrations and emissions
Carr. C[NOx] = ((20.9-02% carr. value)/(20.9-actual avg. 02% value»*Avg. raw NOx value E[NOx] = (C[NOxj*Mol**Wt[NOxl~60{min/hr)*Qstd(dscfm))/(Molar** Vol. alr*10"6) E[NOx lb/MMBtu] = Cd * Fd ., (20.9/(20.9-actual 02%» C[NOx] = 197.8 ppmVd C[NOx] = 162.5 ppmVd corrected to 7 % 02 Mol. Wt. [NOx)= 46.01 Ib/lb-mole Molarvol air= 385 scfllb-mole 

### @ 68 def F E[NOx] = 223.76 Ib/hr Conv Factor. E[NOx] = 1.194E-07 convert ppmV 10 Ib/scf NOx 0288 Ib/MMBtuClient Project No. Spruance Genco, LLC 3333 Test Location Test Run Unit No.3 Three Page 4 of4

10) Carbon Monoxide concentrations and emissions

Carr. ClCO] 

### = «20.9-02% carr. value)/(20.9-actual avg. 02% value»"Avg. raw CO value E[CO Ib/hr]

# =**(ClC01~Mol** Wt[CO]"60(min/hr)"Qstd(dscfm»/(MolarVol. air"10"6) E[CO Ib/MMBtu] = Cd" Fd" (20 9/(20.9-actual 02%» 

### qCO] = 463 1 ppmVd ClCO] = 3804 ppmVd corrected to 7 % 02 Mol. WI. [CO]= 28.01 Ib/lb-mole Molarvol aif= 

### E[CO] = Conv Factor. 

### E[CO] = 385 scf/lb-mole @ 318.93 Ib/hr 7.235E-08 convert ppmV to Ib/scf CO 0.408 Ib/MMBtu
11) Sulfur Dioxide concentrations and emissions 

### 68 defF

Carr. C[S02] = «20.9-02%carr. value)/(20.9-actual avg. 02% value»"Avg. raw S02value E(lb/MMBtu) = Cd(lb/scf)" Fd(scf/MMBtu)" {20.91 (20.9-% 02)] E[S021b/hrJ =**(ClS02]~Mol** Wt[S02]*60(min/hr)*Qstd(dscfm»/(MolarVol. air*10"6) C[S02] = 31.3 ppmV (dry) Actual Conc. ClS02] = 25.7 ppmVd corrected to 7 % 02 Mol. WI. [S02]= 64.06Ib/lb-mole Molarvol air= Conv Factor. E[S02] = E[S02] = 385 scf/lb-mole 

### @ 68 1.66E-07 convert ppmVto Ib/sct S02 0.063 Ib/MMBtu 49.30 Ib/hr def F

### 3333-HCN-R1



### Client Project No. Test Location Test Run 

### Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### VIc

# = Vm= Pstatie

# = Pb 

### = Ps 

### = Pstd

# = dP= dH 

### = Tm= 

### Ts= Tstd= On 

### = An

# = y= t

# = Ds= As= 

### Cpo Kp

# = K1 

# = K2= 

### K3

# = Fd

# = CF=

[02[ [C02]
[N2] 

## AirNova, Inc. EPA Methods 1,2,3A,4,and Modified 26 (Flows, 

### 02/C02, H20,and HeN) 

### Spruance Genco, LLC 3333 Unit NO.3 

### One 

## 04/15/10 

## 0901-1001

129.3 

### cc 41.156 defEmission Data



### -0.50 in. 

### H20 30.44 

### in. Hg 

### 30.40 

### in, Hg 29,92 in. 

### Hg 

### 0.7043 in. H20 

### ",5

1.700 

### in. H20 522.7 R 652.7 R 527.7 R Din. 0.000000 sq 

### ft. 1.02



### 60 min. 10.300 

### ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure 

### EPA Standard pressure Average sq.rt delta P Average draftgauge reading Average metertemperature Average stack temperature 

### Standard temperature Nozzle diameter Area of nozzle orifice Metercalibration factor Duration of sampling time Diameter ofstack 83.323 sq ft. Cross sectional area ofstack 

### 0.84 Pitot tube coefficient 85.49 ft[{lbJlbmol)

....(inHg)]".5}J[s

..R"inH20] Pitot tube constant 

### 17.637 R/in Hg 0.047070 cu.ftlml 

### 0.0026688 in.Hg-ef/ml-R 9862 scfJMMBtu 

### 7.014E-08 Ib/dsef I 

### ppmVd

Instrumental Data

4.24 %-dry 14.26 

### %-dry

81.50 %-dry constant constant constant Fuel Factor Conversion Factorfor HCN

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) 

### Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1'Y 'Vm ' (Pb 

### +dH/13 6) /Tm Vmstd = 

### 43.294 dscf 1.23 dscm Unit No.3 

### One

2) 

### Volume ofwatervapor collected atstandard conditions, Vw(std).
Vw(std)

# =K2 ." Vic 

### Vw(std) = 6.086 scf
3) 

### Decimal fraction of moisture byvolume in stack gas, Bws.


### BwS

# = Vwstd 

### I (Vmstd+Vwstd) Bws= 0123


### 4) Molecularweightofthe stack gas on a wet basis, Ms.

Ms = [((44'%C02) + 

### (32'%02) + 

### (28'%N2))' (1-Bws) 

## I+ 

### (18'Bws) Ms= 28.92 Ib/lbmole
5} 

### Average stack gasvelocity, Vs.

Vs = Kp , Cp , (dP) , (Ts/Ps'Ms)'.5 Vs

### = 43.58 fps
6) 

### Average actual stack gasvolumetric flowrate, Qa.


### Qa

# = 60 sec/min *

### Vs ." As 

### Qa

# = 217858.9 cfm 6169.8 cmm
7) 

### Average stack gas dryvolumetric flowrate, Qstd.

Qstd = Qa' (TstdlTs)' (Ps/Pstd)' (1-Bws) Qstd

# = 156921.7 dscfm 4444.0 dscmm Page 2

### Client 

### Spruance Genco, LLC Project No. 

### 3333 Test Location Test Run

8) Hydrogen Cyanide Concentration and Emissions Unit No.3 

### One

M[HCN]

# =M[CN-](mg) , MW[HCN](mg/mmol) 

### 1MW[CN-](mg/mmol) Page 3



### C[HCN]

# =(M[HCN](mg) , 2.20SE-06(lb/mg) • 21.8S(scf'onHg/lbmol'R) • K1 • 10A6) 

### 1(MW[HCN](lbllbmol) 'Vmsl C[HCN](@corr 02)

### =C[HCN](ppmV)' [(20.9-corrected 02) 1

### (20.9-octuol %02)] E[HCN] 

### = M[HCN](mg)' Ostd(dscfm)' (2.20SE-06)(lb/mg)·60(min/hr) 

### 1Vmstd(dscfj E[HCN] 

### =C[HCN](ppmV)' Fd'CF(HCN)' (20.9/(20.9-%02))



## < M[HCN] 

### = 0.004 mg 

## < C[HCN] 

### = 0.003 ppmV 

## < C[HCN] 

### = 0.002 ppmV (@ 7.0 

### %02) 

## < E[HCN] 

### = 0.002 Ib/hr 

## < E[HCN] 

### = 2.S2E-06 Ib/MMBtu

### 3333-HCN-R2



### Client Project No. Test Location Test RUn Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vic = 

### Vm= Pstatic

# = Pb = 

### Ps = 

### Pstd

# = dP

### = dH 

# = Tm= Ts 

### = Tstd= On 

### = An

# = y= t= Os 

### = As= Cp= 

### Kp 

### = K1 

### = K2= 

### K3= Fd 

### = CF

# =

[02J [C02J
[N2J 

## AirNova, Inc. EPA Methods 1,2,3A,4,and Modified 26 (Flows, 

### 02/C02, H20,and HCN) 

### Spruance Genco, LLC 

## 3333 Unit NO.3 

# Two 04/15/10 

## 1308-1408

141.2 

### cc 42.811 defEmission Data



### -0.50 in. 

### H20 30.37 

### in. Hg 

### 30.33 in. Hg 

### 29.92 in. Hg 

### 0.6892 in. 

### H20 

### ".5

1.700 in. 

### H20 546.7 R 655.4 R 527.7 R 

# oin. 

### 0.000000 sq 

### ft. 1.02



### 60 min. 

### 10.300 

### ft Vol. of H20 collected 

### Dry gas meter readrng Static pressure Barometric pressure Stack pressure EPA Standard pressure 

### Average sq.rt delta P Average draftgauge readrng Average metertemperature Average stacktemperature Standard temperature 

### Nozzle diameter Area of nozzle orifice Metercalibration factor Duration ofsampling time Diameterofstack 

### 83.323 sq. ft. Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lbJlbmol)*(inHg)]".5}/[s*R"inH20] Pitottube constant 17.637 R/in Hg 0.047070 cu.ftlml 0.0026688 in.Hg-cf/ml-R 9755 scf/MMBtu 7.014E-08 Ib/dsefl ppmVd

Instrumental Data

4.08 %-dry 14.33 %-dry

81.59 %-dry constant constant constant Fuel Factor Conversion Factorfor HCN

Oxygen concentratIon Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 

### Test Location Test Run
Calculations
1)

### Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1'Y 'Vm • (Pb 

### + dH/13.6) ITm 

### Vmstd

# = 42.960 dscf 1,22 dscm Unit No, 3 

### Two

2) 

### Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std) = K2 'Vic Vw(std) = 

### 6.646 scf
3) 

### Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws

# = Vwstd 

### I (Vmstd+Vwstd) Bws= 0.134
4) Molecularweight ofthestack gas on a

### wet basis, Ms.

Ms = [((44'%C02) + 

### (32'%02) + 

### (28'%N2))' (1-Bws) 

## I+ 

### (18'Bws) 

### Ms= 28,79 Ib/lbmole 5) Average stack gasvelocity, Vs.

Vs = Kp , Cp • (dP) , (Ts/Ps'Ms)'5 Vs = 42.88 fps 

### 6) Average actual stackgasvolumetric flowrate, aa.
Oa

# = 60 sec/min * Vs *As Oa

# = 214358,9 cfm 6070.6 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

### Qstd 

### = 151540.6 dscfm 4291.6 dscmm Page 2

### Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

8) Hydrogen Cyanide Concentration and Emissions Unit No.3 

## Two

M[HCN[

# =M[CN-](mg) , MW[HCN](mg/mmol) 

### 1MW[CN-](mg/mmol) Page 3

C[HCN] = 

### (M[HCN](mg) , 2.205E-06(lb/mg) , 21.B5(scf'inHg/lbmol'R) , K1 ' 10'6) 1

### (MW[HCN](Ib/lbmol) • Vmsl C[HCN](@corr. 02)

# = C[HCN](ppmV)' [(20.9-corrected 02) 1

### (20.9-actual %02)] E[HCN]

# =M[HCN](mg)' Qstd(dscfm)' (2.205E-06)(lb/mg)' 60(min/hr) 1

### Vmstd(dscD E[HCN]

# = C[HCN](ppmV)' Fd'CF(HCN)' (20.9/(20.9-%02))



## < M[HCN]

# = 0.003 

### mg 

## < C[HCN]

# = 0.002 ppmV 

## < C[HCN]

# = 0002 ppmV (@ 7.0 

### %02) 

## < E[HCN]

# = 0.001 Ib/hr 

## < E[HCN]

# = 1.B7E-06 Ib/MMBtu

### 3333-HCN-R3



### Client 

### Project No. Test Location Test RUn Test Date Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT 

### Vlc= Vm= 

### Pstatic

# = Pb

# = Ps

# = Pstd

# = dP

# = dH

# = Tm= 

### Ts

# = Tstd= On

# = An 

### = y= t= Ds 

### = As= Cp= Kp

# = K1 

# = K2= 

### K3

# = Fd = 

### CF

# =

[02[ [C02[
[N2[ 

## AirNova, Inc. EPA Methods 1,2,3A,4,and Modified 26 (Flows, 021C02, H20,and HCN) 

### Spruance Genco, LLC 

## 3333 Unit NO.3 Three 04/15/10 

## 1724-1824

139,5 

### cc Emission Data

42.625 def

-0.50 

### in. H20 30.25 in. 

### Hg 30.21 in. 

### Hg 

### 29.92 

### in. Hg 

# o7043 in. H20 

### ".5

1.700 in. 

### H20 544.4 R 655.9 

### R 527.7 

### R 

# o in. 

### 0.000000 

### sq. 

### ft. 1.02



### 60 min. 10.300 

### ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draftgauge reading Average metertemperature Average stacktemperature Standard temperature Nozzle diameter Area ofnozzle orifice Meter calibration factor Duration ofsampling time Diameterofstack 83.323 sq. ft Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)*(inHg)1".5}/[s*R*inH20] Pltottube constant 17.637 Rlin.Hg 0047070 cu.ftlml 0.0026688 in.Hg-cf/ml-R 9868 scflMMBtu 7.014E-08 IbldsefI ppmVd

Instrumental 

### Data

3.98 

### %-dry 14.33 

### %-dry

81.69 

### %-dry constant constant constant Fuel Factor Conversion Factor for HCN

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions,Vmstd.

Vmstd =K1'Y 'Vm ' (Pb 

### +dH/13.6) ITm Vmstd

# = 42.787 dsef 1.21 dsem Unit 

### NO.3 

### Three

2)

### Volume ofwater vaporcollected atstandard conditions,Vw(std).
Vw(std) = K2 'Vic Vw(std) = 

### 6.566 sef
3) 

### Decimal fraction of moisture by volume in stack gas, Bws.

Bws

# = Vwstd / (Vmstd+Vwstd) Bws

# = 0.133


### 4) Molecularweightofthestack gas on 

## awet basis, Ms.

Ms = [((44'%C02) 

### +(32'%02) + 

### (28'%N2))' (1-Bws) I + 

### (18'Bws) 

## MS= 28.80 Ib/lbmole 

### 5) Average stack gasvelocity, Vs.

Vs = Kp' Cp' (dP) , (Ts/Ps'Ms)A.5 Vs 

### = 43.91 fps
6) Average actual stack gasvolumetric flowrate, Qa.

Qa

# = 60 sec/min" 

### Vs * As 

### Qa = 219533.2 efm 6217.2 emm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) Qstd 

### = 154633.6 dscfm 4379.2 dscmm Page 2

### Client 

### Spruance Genco, LLC Project No. 

### 3333 Test Location Test Run

8) Hydrogen Cyanide Concentration and Emissions 

### Unit No, 3 Three



### M[HCN[

# =M[CN-[(mg)' MW[HCN](mg/mmol) 1

### MW[CN-](mg/mmol) Page 3



### C[HCN[

# =(M[HCN](mg) • 2.20SE-06(lb/mg) • 21.8S(scf"inHg/lbmol·R) • K1 • 10'6) 

### 1(MW[HCN[(lb/lbmol) •Vmsl C[HCN[(@corr. 02)

### =C[HCN[(ppmV)' [(20.g-corrected 02) 

### 1(20.9-actual %02) [ E[HCN[

# =M[HCN](mg)' Qstd(dscfm)' (2.20SE-06)(1b/mg)· 60(min/hr) 

### 1Vmstd(dscD E[HCN[ 

### =C[HCN[(ppmV)' Fd' CF(HCN)' 

### (20.9/(20.9-%02))
M[HCN]

# = 0.071 mg C[HCN[

# = 0.OS2 ppmV C[HCN[

# = 0.043 ppmV (@ 7.0 % 

### 02) E[HCN[

# = 0034 Ib/hr E[HCN[

# = 4.46E-OS Ib/MMBtu3333-Forma!dehyde-R1

Client Project No. Test Location Emission Source Test Date Test Run Time Period

Vlc= Vm= Pstatic = Pb= Ps= Pstd = dP = dH = Tm= Ts = Tstd= y= t= On = An 

### = Ds= 

### As 

### = Cp 

### = Kp 

### = K1 

### = K2 

### = K3 

### = Fd = CF =

[02] [C02]
[N2] 

### AirNova, Inc. EPA Methods 1,2,3A,4,and RCRA Method 0011

(Flows, 02/C02, H20.and Fonnaldehyde) Spruance Genco. LLC 3333 Richmond, Virginia Unit NO.3 04/15/10 

### 00. 0900-1110

Emission Data

256.1 cc 79.545 dcf

-0.50 in. H20 30.44 in. Hg 30.40 in. Hg 2992 in. Hg 0.723 in. H20" 5

1.53 in. H20 522.0 R 654.7 R 527.7 R

0.99 120 min. 0.251 in. 0.000344 sq. ft. 10.30 ft. Vol. of H20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration of sampling time Nozzle diameter Nozzle area Diameter of stack 83.3204 sq. ft. Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lb/lbmol)"(inHg)]

.....5}/[s·R*inH20] Pitot tube constant 17.637 R/in.Hg 0.047070 cu.flIml 0.0026688 in.Hg-cf/ml-R 9862 scf/MMBtu 7.793E-08 Ib/dscf

### I ppmVd constant constant constant Fuel Factor Conversion Factorfor CH20

EPA Method 3A Instrumental Data 4.24 %-dry 14.26 %-dry

81.50 %-dry Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration Data from:

EPA 4 EPA 4 EPA 2

EPA 2

EPA2 EPA4 EPA4 EPA 2

EPA2Client 

### Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations

1) Volume ofgas sampled at standard conditions, Vmstd. Vmstd =K1*

### Y"Vm**~** (Pb + 

### dH/13 

### 6) ITm Vmstd = 81.301 dscf 2.302 dscm Richmond, Virginia One

2) Volume ofwater vapor collected at standard conditions, Vw(std). Vw(std)

# =K2 * Vic Vw(std) = 12055 scf

3) Decimal fraction ofmoisture by volume in stack gas, Bws. Bws = Vwstd / (Vmstd+Vwstd) Bws= 0.1291

4) MolecularweightofIhe stack gas on 

### a wet basis, Ms. Ms = [«44*%C02)+ (32"'%02) + (28*%N2» r (1·Bws) 

## 1 + (18*Bws) Ms= 28.843 Ib/lbmole

5) Average stack gas velocity, Vs Vs = Kp * Cp'" (dP) * (Ts/Ps*Ms)".5 Vs = 44.877 fps

6) Average actual stack gasvolumetricflowrate, Qa. Qa = 60 sec/min 

### *Vs 

### *As Qa = 224352.16 cfm 6353.65 cmm

7) Average stack gas dry volumetriC fJowrate, Qstd. Qstd = Qa * (TstdlTs) * (Ps/Pstd)**~** (1-Bws) Qstd = Qstd = 160025.33 dscfm 4531.92 dscmm 

### Page 2Client Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations (cont.) Richmond, Virginia One

8) Formaldehyde

- Concentrations and Emission Rates M[CH20] = sample mass (mg) QCH201 = M[CH20] (mg) 1sample volume (dscm) QCH20 

### @ corr. %02]

### =qCH20] (ppmV)

.. (20.9-Corr. %02)/{20.9-Actual %02) Corrected 02 Percentage = 7 

### % E[CH20] 

### =qCH20] (mg/dscm)**~** 60 (min/hr)

.. Qsld (dscmm) • (1 Ib 14 536 e+05 mg) E[CH20]{lb/MMBlu) = QCH20]{ppmV) CF· Fd * (20 9/20.9-%02) Page 3

ComQound Sample Mass Concentration Concentration Concentration Mass Emission Mass EmissiQn 

## 1m9l (mq/dscm) 

## !Immlil 'PmV@Corr.%O (lb/hr) (lb/MMBtu)
Formaldehyde 0.00610 2.65E-03 2.12E-03 1.77E-03 1.59E-03 2.05E-OB 

### NO NO NO NO NO NO
9) Isokinecity, I. % I = [100*Ts*{K3*Vlc+({{Vm·Y)fTm)*{Pb+{dH/13.6))))] 1(60"I*Ps·Vs·An) % I = 102.663333-Formaldehyde-R2

Client Project No. Test Location Emission Source Test Date Test Run Time Period

Vlc= Vm= Pstatic 

### = Pb 

### = Ps 

### = Pstd 

### = dP 

### = dH 

### = Tm= Ts 

### = Tstd= 

### y= t= On 

### = An = Ds= As = Cp = Kp = K1 = 

### K2= K3 

### = Fd 

### = CF 

### =

[02] [C02]
[N2] 

### AirNova, Inc. EPA Methods 1,2,3A.4.and RCRA Method 0011

(Flows, 

### 021C02, H20, and Formaldehyde)
Spruance Genco, LLC 3333 Richmond, Virginia Unit No.3 04/15/10 

### Two 1308-1518

Emission Data

250.5 cc 79.504 dcf

-0.50 in. H20 30.37 in. Hg 3033 in. Hg 2992 in. Hg 0.701 in. H20 

### ".5

143 in. H20 539.5 

### R 656.7 

### R 527.7 

### R

0.99 120 min_ 0.251 in 0.000344 sq. 

### ft. 10.30 

### ft. Vol. of H20 collected 

### Dry gas meter reading StatIc pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stacktemperature Standard temperature Meter calibration factor Duration of sampling time Nozzle diameter Nozzle area Diameter ofstack 83.3204 sq. ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R*mH20] Pitot tube constant 17.637 R/in.Hg 0.047070 cu.fUml 00026686 in.Hg-cf/ml-R 9755 scf/MMBtu 7.793E-08 Ib/dscfj ppmVd constant constant constant Fuel Factor Conversion Factor for CH20

EPA Method 3A Instrumental Data 4.08 %-dry 14.33 %-dry

81.59 %-dry Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration Data from:

EPA4 EPA4 EPA 

### 2

EPA2

EPA2 EPA4 EPA4 EPA2



## EPA2Client Spruance Genco, LLC Project No. 

### 3333 Test Location Test Run

Calculations

1) Volume ofgas sampled at standard conditions, Vmstd. Vmstd =K1*Y *Vm • (Pb + dH/13.6) I Tm Vmstd = 78.423 dsd 2.221 dscm

2) Volume ofwatervaporcollected at standard conditions, Vw(std) Vw(std) = K2 • Vic Vw(std) = 11.791 scf

3) Decimal fraction ofmoisture by volume in stack gas, Bws. Bws = Vwstd I (Vmstd+Vwstd) Bws = 0.1307

4) Molecularweightofthe stack gas on a wet basIs, Ms. Richmond, Virginia 

### Two

Ms = [{(44*%C02) + (32*%02) + (28*%N2»;O (1-Bws) 

## 1 + (18*Bws) Ms = 28.828 Ib/lbmole

5) Average slack gas velocity, Vs. Vs = Kp • Cp * (dP) • (Ts/Ps;OMs)".5 Vs = 43.650 fps

6) Average actual stack gas volumetric flowrate, Qa. Qa = 60 sec/min·Vs • As Qa = 218213.76 cfm 6179.81 cmm

7) Average stack gas dry volumetric flowrate, Qstd. Qsld = Qa" (TstdfTs) * (Ps/Pstd)" (1-Bws) Qstd = 154535.87 dscfm Qstd '" 4376.46 dscmm Page 2Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations (cont.) Richmond, Virginia Two

8) Formaldehyde

- Concentrations and Emission Rates M[CH20]

### =sample mass (mg) C[CH20] = M[CH20] (mg) I sample volume (dscm) C[CH20 @ corr %02] = C[CH20] (ppmV) * (20,9-Corr. %02)/(20.9-Actual %02) Corrected 02 Percentage = 7 

### % E[CH20] = C[CH20] (mg/dscm)· 60 (min/hr)

.. Qstd (dscmm) * (1 

### Ib 14.536 e+05 mg) E[CH20](lb/MMBtu) = C[CH20](ppmV) CF· Fd

.. (20.9/20.9-%02) Page 3

ComQo!.!DQ SamQle Mass Concentration Concentration Concentration Mass Emission Mass Emil:!12ion 

## i!lliil (mg/dscm) (QQ!!JlQ 'pmV@Corr.%O (Iblhr) (lb/MMBtu)
Formaldehyde 0.00472 2.13E-03 1,70E·03 141E-03 1 23E-03 1.61 E-06 

### NO NO NO NO NO NO
9) Isokinecity, I. 

### % I = [100*Ts·(K3*Vlc+«(Vm*Y)lTm)*(Pb+(dH/13.6»))]

### J(60·t*Ps·Vs*An) %1= 102553333-Formaldehyde-R3

Client Project No. Test Location Emission Source Test Date Test Run Time Period

Vlc= Vm= Pstatlc = Pb = Ps = Pstd '" dP = dH = Tm= Ts = Tstd= y= t= On = An = Os = As 

### = Cp 

### = Kp ::: K1 ::: K2 ::: K3 = Fd = CF =



### [02[ [C02)
[N2) 

### AirNova, Inc. EPA Methods 1,2,3A,4,and RCRA Method 0011

(Flows, 02/C02, H20, and Formaldehyde)
Spruance Genco, LLC 3333 Richmond, Virginia Unit NO.3 04/15/10 Three 1724-1933

Emission Data

244-3 cc 80.591 def

-0.50 in. H20 30.25 in. Hg 30.21 in. Hg 29.92 m. Hg 0.710 in. H20" 5

1.51 in. H20 547.5 R 660.0 R 5277 R

0.99 120 min. 0.251 in. 

# o000344 sq. ft. 10.30 ft. 83,3204 sq. ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Metercalibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameter ofstack Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft{(lb/lbmol)*(mHg)]".5}/[s*R*inH20] Pitot tube constanl 17.637 R/in.Hg 0.047070 cu fUml 0.0026688 in,Hg-cf/ml-R 9868 scf/MMBtu 7,793E-08 Ib/dscf

### I ppmVd constant constant constant Fuel Factor Conversion Factorfor CH20

EPA Method 3A Instrumental Data 3.98 %-dry Oxygen concentration 14.33 %-dry Carbon Dioxide concentration

81.69 %-dry Nitrogen concentration Data from:

EPA4 EPA4 EPA 2

EPA2

EPA2 EPA4 EPA4 EPA 2

EPA2Client Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations

1) Volume ofgas sampled at standard conditions, Vmstd. Vmstd =K1,o Y,o Vm "(Pb + dH/13.6) 

### ITm Vmstd = 78.028 dscf 2.210 dscm Richmond, Virginia Three

2) Volume ofwatervaporcollected at standard conditions, Vw{std). Vw(std) = K2 ,. Vic Vw(std) = 11.499 scf

3) Decimal fraction of moisture by volume in stack gas, Bws. Bws = Vwstd 

### I (Vmstd+Vwstd) Bws= 01284

4) Molecularweight ofthe slackgason awei baSis, Ms. Ms = [«44*%C02)+ (32*%02) + (28"%N2»·(1-Bws) 

## 1+ (18*Bws) Ms= 28.853 Ib/lbmole



### 5) Average stack gas velocity, Vs Vs = Kp'" Cp· (dP)· (Ts/Ps·Ms)".5 Vs = 44.344 fps

6) Average actual stack gas volumetric flowrale, Oa. Oa =60sec/mm ,. Vs • As Oa = 221684.42 cfm 6278.10 cmm

7) Average stack gas dry volumetricflowrale, Qstd. Qstd = Oa;i; (TstdfTs) * (Ps/Pstd)" (1-Bws) Qstd = Qstd = 156006.47 dscfm 4418.10 dscmm 

### Page2Client Spruance Genco, LLC Project No. 3333 Test Location Test 

### Run

Calculations (cont.)
8) Formaldehyde

- Concentrations and Emission Rates M[CH20] = sample mass (mg) Richmond. Virgmia Three

qCH20] = M[CH20] (mg) / sample volume (dscm) qCH20@ corr. %021 = qCH20] (ppmV) " (20.9-Corr. %02)/(20.9-Actual %02) Corrected 02 Percentage = 

### 7 % E[CH20]

### =C[CH201 (mg/dscm) * 60 (min/hr) 

### * Qstd (dscmm) • (1 Ib /4.536 e+05 mg) E[CH20]ClbIMMBlu) = CiCH20](ppmV) CF' Fd' (20.9120.9-%02) Page 3

Coml2oun!::l Saml2le Mass Concentration Concentration Concentration Mass Emission Mass**Emi~iJi!iQD** 

### !mill (mg/dscm) 

## ioo!TIlil 'I2mV@Corr.%O (Ib/hr) (lb/MMBtu)
Formaldehyde 0.00540 2.44E-03 1.96E-03 161E-03 1.43E-03 1.86E-06 

### NO NO NO NO NO NO
9) Isokinecily, 

### I. % I = [100*Ts*(K3·Vlc+{«Vm"Y)fTm)*{Pb+(dH/13

### 6»»]1 (60*I*Ps*Vs*An) %1= 101.073333-7E

Client Project No. Test Location Test Date 

### Spruance Genco, LLC 

### 3333 Unit NO.3

- Metallic HAPs 04116/10

Parameter: Instrument Span (% 02l-' 

### Oxygen 21.96

Actual Calibration Gas: Vall1ft (% 02): AnalyzerCalibration Response (% 02).- AnalyzerCalibration Error(% Soan).

Zero Sllstem Caligratjllo Gas Armarent Init Sys. Init. S!!s. FinalS!!s. EiQal Sys:.

Stack Calib. Cal Bia§. Calib. Cal. Bias 

### Run Conc. Resoonse f% span) Response (% span)



### 1 4,07 0.04 0.14 0.05 0.18 0 0.00 0.05 

## o18 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0,05 0 0.00 0.00 -005 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0.05 0 0.00 0.00 -0.05 0.00 -0 05 0 0.00 0.00 -0,05 0.00 -0,05 0 

### 0.00 0.00 -0.05 0.00 -0.05 

### AirNova, Inc. Page 1 EPA Method 7E Calculations (Cal. Error, Bias Driftand BiasAdjustment)

Anal't.zerCalib. Gases: !lJ2sc g

J€i. 

### zero IQy; 

### !I11Sl high S't.s. Cal. Gas 

### 0.00 NfA 

### 12.46 21.96 12.46 0.01 NfA 

### 12.44 21.81 12.44 0.05 0.00 -0.09 -0.68

Uruica1e Sllstem Calibmti!:![l Gas Ca/ib. Init. Sys. Init. 

### :S:vs:. FinalS'i.,S: Final S!!s. Ca/ib. Actual Drift Calib. Cal. Bias Calib. (;.13.1. Bias Drift Stack f% span) Respon§.e (% span) Response (% span) (% span) Conc.



### 0.05 12.43 -0.05 12.33 -0,50 -0.46 4.07 

### -0.23 12.33 -0,50 0.00 -56.65 -56.15 -0.05 

### 0.00 0.00 -56.65 0.00 -56.65 0.00 

### ERR 0.00 000 -56.65 0.00 -56.65 0.00 

### ERR 0.00 0.00 -56.65 0.00 -56.65 0.00 

### ERR 0.00 0.00 -56.65 0.00 -56.65 0.00 

### ERR 0.00 0.00 -56.65 0.00 -5665 0.00 

### ERR 0.00 0.00 -56.65 0.00 -56.65 0.00 

### ERR 0.00 0.00 -56.65 0.00 -56.65 0.00 

### ERR 0.00 0.00 -56.65 0.00 -56.65 0.00 

### ERR 0.00 0.00 -56.65 0.00 -56.65 0.00 

### ERR 0.00 0.00 -56.65 0.00 -56.65 0.00 

### ERR

### 3333-7E

Client Project No. Test Location Test Date Spruance Genco, 

### llC 

### 3333 Unit No_ 3 - Metallic HAPs 

### 04/16/10

Parameter' InstrumentSpan (% C02): 

### Carbon Dioxide 17.83

Actual Calibration Gas Value (% C02): AnaNzerCalibration Response (% C02): AnaNzerCalibration Error(% Soan):



### Zero S),stem Caligratillo Gall AIJQarent Init. S\::':S. Init. S\::':S. FinalS\:::s_ FinalS\::':S

Stack Calib. Cal. Bias Calib. Cal. Bias 

### Run Conc_ Response (% sQan) Response (% span!



### 14.62 0.05 0.28 0.02 0,11 0 0.00 0.02 0_11 0.00 0.00 0 0.00 0.00 0.00 0.00 0.00 0 000 0.00 0.00 000 0_00 0 0,00 0.00 0.00 0.00 0.00 0 0.00 0.00 0.00 0.00 0.00 0 0.00 000 0.00 0.00 0.00 0 0.00 0.00 0.00 0.00 0_00 0 0.00 0.00 000 0.00 0.00 0 0.00 0_00 0.00 0.00 0.00 0 0.00 000 0.00 0.00 0.00 0 0.00 0.00 0.00 0.00 0.00 

### AirNova, Inc. Page 2 EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Anal't.zerCf!/ib.**Gg,s:§:~** UQscale
zero fow mid high S't.s, Cal. Gas 

### 0.00 NfA 

### 12.39 17.83 12_39 0.00 NfA 

### 12.40 17.91 12.40 0.00 0.00 0.06 0.45

Up'scal§: S),stem Calib[aiillo Gas Calib. Init. S\::':S. Init. S):::s. FinalS\::':S_ FinalS\::':S. f!..alLtL Actual Drift Calib, Cal_**BiiJ.~** Calib. Cal. Bias Drift Stack (% span) Re,s:ponse (% span! Response (% span! (% sQan) Conc.



### -0.17 12.32 -0.45 12.23 -0_95 -0.50 14.76 

### -0.11 12.23 -0.95 0.00 -69.55 -68.59 -0.02 

### 0.00 0.00 -69.55 0.00 -69.55 0.00 

### ERR 0_00 000 -69.55 0.00 -69.55 0.00 

### ERR 0.00 0,00 -69.55 0.00 -69.55 000 

### ERR 0.00 0.00 -69.55 0.00 -69.55 0_00 

### ERR 0.00 0_00 -69.55 0.00 -69.55 0.00 

### ERR 0.00 0.00 -69.55 0.00 -69_55 0,00 

### ERR 0.00 0.00 -69.55 0.00 -69.55 0.00 

### ERR 0.00 0.00 -69.55 0.00 -69.55 0.00 

### ERR 0.00 0_00 -69.55 0,00 -69.55 0.00 

### ERR 0.00 0.00 -69.55 0.00 -6955 0_00 

### ERR3333-7E

Client Project No. Test Location Test Date 

### Spl1.Jance Genco, LLC 

### 3333 Unit No.3

- Metallic HAPs 04/19/10

Parameter: Instrument Span f% 02): 

### Oxygen 21.96

Actual Calibration Gas Value f% 02).- AnalyzerCalibration Response (% 02): AnalyzerCalibration Errorf% Span):

Zero**S~stem** CalibratjO!l Gas AQJl.arent Init. S!!,s. Init. S!!,s. Final S!!,s. Fmal SI::§.

Stack Calib. Cal. BlfI.§. Calib. Cal. Bias 

### Run Cone. Response f% span) Response (% span)



### 2 3.87 0.06 0.18 0.05 0.14 3 5_01 0,05 0.14 0.05 0.14 0 0.00 0.05 0,14 0_00 -0_09 0 0.00 0_00 -0.09 0.00 -0.09 0 0.00 0.00 -0.09 0.00 -0.09 0 0.00 0.00 -0.09 0.00 -0.09 0 0.00 0.00 -009 0.00 -0.09 0 0.00 0.00 -0_09 0.00 -0.09 0 0.00 0,00 -0.09 0.00 -0.09 0 000 0.00 -0.09 000 -0.09 0 0.00 0.00 -0.09 0.00 -0.09 0 0.00 0.00 -0.09 0.00 -0.09 AirNova, Inc. Page 1 EPA Method 7E Calculations (Cal. Error, Bias Driftand Bias Adjustment)

AnalvzerCalib. Gases upscale zero low mid high S!!,s. Cal. Gas 

### 0.00 N/A 

### 12.46 21.96 12.46 0.02 N/A 

### 12.45 21.89 12.45 0.09 0.00 -0.05 -0_32

Uj;!scale**S~stem** Calib[atioD Gas Calib. Init. S)!s. Init. S)!s. FinalSI",S: Final S)!s. Calib. Actual Drift Calib. Cal. Bias Calib Cal. Big:! Drift Stack f% §.Df!.n! Response (% span) Response (% span) (% span) Cone.



### -005 12.48 0_14 12.44 -0.05 -0.18 3.83 0.00 12.44 

### -0.05 12.40 -0.23 -0.18 5.00 -0.23 12.40 -0.23 0.00 -56_69 -56.47 -0.05 0.00 0.00 -56,69 0.00 -56.69 0.00 

### ERR 0.00 0.00 -56.69 0,00 -56.69 0.00 

### ERR 0.00 0.00 -56.69 0_00 -56.69 0.00 

### ERR 0.00 0.00 -56_69 0.00 -56.69 0.00 

### ERR 0.00 0.00 -56.69 0.00 -56.69 0.00 

### ERR 0.00 0.00 -56.69 0.00 -56.69 0.00 

### ERR 0.00 0.00 -56.69 0.00 -5669 0.00 

### ERR 0.00 0.00 -5669 0.00 -56.69 000 

### ERR 000 0.00 -56.69 0.00 -56.69 0.00 

### ERR

### 3333-7E

Client Project No. Test Location Test Date Spruance Genco. LLC 

### 3333 Umt No 3 - Metallic HAPs 04f19/10

Parameter: InstrumentSpan (% C02): 

### Carbon Dioxide 1783

Actual Calibration Gas Value t% C02): AnalYZerCalibration Response f% C02): AnalyzerCalibration Errorf% Span):

Zero Sy:stem Calibration Gas AQparent Ini!. Sk:s. Init. Sk:s. Final Svs. Final Sys.

Stack Calib. Cal. Bias Calib. Cal. Bias Run Cone. Response (% span) Response t% span)

2 

### 15.00 0.00 -0.06 0.05 0.22 3 

### 1393 0.05 0.22 0.00 -0,06 0 0.00 0.00 -0.06 0,00 -0.06 

### 0 0.00 0.00 -0.06 0.00 -0.06 

### 0 0.00 0.00 -0.06 0.00 -0.06 

### 0 0.00 0.00 -0.06 0.00 -0.06 

### 0 0.00 

### 000 -006 000 -0.06 

### 0 0.00 0.00 -0.06 

### 0.00 -0.06 

### 0 0.00 0.00 -0.06 0.00 -0.06 

### 0 0.00 0.00 -0.06 0.00 -0.06 

### 0 0.00 

### 000 -0.06 0,00 -0.06 

### 0 0.00 0.00 -0.06 0.00 -0.06 

### AirNova, Inc. Page 2 EPA Method6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Ana/k:zfl:rQalib. Gases Upscale zero fow mid high Sk:s. Cal. Gas 

### 0,00 NfA 

### 12.39 17.83 12.39 0.01 NfA 

### 12.38 17.83 12.38 0.06 0.00 -0.06 0.00

Ugscale Sy:stem Calibration Gas Ca/ib. Inil. Svs. Init. 

### SJ@. Final Sk:s. Final Sys. Calib. Actual Drift Calib. Cal. Bias Calib. Cal. Bia§. Drift Stack f% .soan) Response f% span) Response r% span) (% span) Cone.



### 0.28 12.37 -0.06 12,32 -0.34 -0.28 15.06 

### -0.28 12.32 -0.34 12,44 

### 0.34 0.67 13.94 

### 0.00 12.44 0.34 0.00 -69,43 -69.77 0.00 

### 0.00 0.00 -69.43 0.00 -69,43 0.00 

### ERR 0.00 0.00 -69,43 0.00 -69.43 

### 000 

### ERR 0.00 0.00 -69.43 0.00 -69.43 0.00 

### ERR 0.00 0.00 -69,43 

### 0.00 -69,43 0.00 

### ERR 0.00 0,00 -69,43 0.00 -69,43 0.00 

### ERR 0.00 0.00 -69.43 

### 0.00 -6943 0.00 

### ERR 0.00 0.00 -69.43 0.00 -69.43 0.00 

### ERR 0.00 0.00 -69.43 0.00 -69.43 0.00 

### ERR 0.00 0.00 -69.43 0.00 -69.43 0.00 

### ERR

### 3333-PM2.5-R1

Client Project No. Test Location 

### Test Run Test Date Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT
INPUT INPUT INPUT
INPUT

INPUT INPUT 

### Vic

# = Vm= PstatlC

# = Pb 

### = Ps 

### = Pstd

# = dP

### = dH 

# = Tm= Ts

# = Tstd= Dn

# = An= 

### y= 

### tr

# = Ds= As= Cp

# = Kp 

### = K1 

# = K2= K3 = 

### C1= C2

# = C3

# = C4= C5= C6= 

### 61 

# = Fd

# =

[02[ [C02[ [N2[ 

### AirNova, Inc. EPA Methods 

### 1,2,3,4, OTM 27 and 202 

### (Flows, 

### 02/C02, H20, PM2.S and CPM) Spruance Genco, LLC 

### 3333 Unit NO.3 One 

### 04116110 0840-1448


### Emission Data
374 

### cc Vol. of H20 collected 127745 dcf 

### Dry gas meter reading -0.50 

### in H20 Static pressure 

### 30.07 in. 

### Hg Barometric pressure 30.03 

### in Hg Stack pressure 29 92 in. 

### Hg EPA Standard pressure 0.7005 in. 

### H20 11.5 Average sq 

### rt delta P

0.390 in. 

### H20 Average draft. gauge reading 

### 542.5 R Average metertemperature 650,6 R Average stack temperature 527.7 R Standard temperature 0.180 

### in. Nozzle diameter 

### 0.000177 sq. ft 

### Area ofnozzle orifice 

### 0.99 Meter calibration factor, gamma 357.2 min. Duration of sampling time 10.300 

### ft. Diameter ofstack

83.32 sq. 

### ft. Cross sectional area of stack

0.84 Pitot tube coefficient 85.49 ft[(lbllbmolt(inHg)]'.5)/[s·R'inH20] Pilottube constant 17637 Rlin.Hg constant 0.047070 cu ftlml constant 0.0026688 in.Hg-cf/ml-R constant

-150.3162 upoise Viscosity constant

13.4622 upoise/R"0.5 Viscosity constant 3861530 upoise/R"2 Viscosity constant 0.591123 upoise Viscosity constant

91.9723 upoise Viscosity constant 1.51761E-05 upoise/R"2 Viscosity constant 0.15625 Constant 9862 dscf/MMBtu


### Instrumental Data
4.07 %-dry 

### 14.76 %-dry 

### 81.17 %-dry 

### Fuel Factor

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project No. 

### Spruance Genco, LLC 3333 Test Location Test Run
Calculations 

### Unit No 3 One

1) Dry Gas Volume

### atstandardconditions, Vms (EPA OTM

### 27 Equation 27)


### Vms =K1'

### Y• Vm ' (Pb 

### + dH/13.6) ITm Vms= 123.744 dscf 3.504 dscm 2) Drygas sampling rate atstandardconditions, QsST(EPA OTM

### 27 Equation 28).


### OsST

# = Vms 

### I tr 

### OsST= 0346 dscfm 0.010 dscm 

### I min. 3) Volume ofwatervaporcondensed

### atstandardconditions, 

### Vws (EPA aTM

### 27 Equation 29).


### Vws = K2 

### "Vlc Vws= 17.604 scf 4) Decimal fraction ofmoisture byvolume in stackgas, 

### Bws (EPA aTM

### 27Equation 30).


### Bws =Vwstd 

### I (Vmstd+Vwstd) Bws= 0.125 5) Mo/ecu/arweight ofthe stacl,

### gas on 

### a wetbasis, Mw (EPA aTM

### 27 Equations 

### 1 &2).
Mw= [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) 

## I+ (1S'Bws) Mw

### = 28.96 Ib/lbmole 6) Gas sampling rate atactual Cyclone conditions, 

### Os (EPA aTM

### 27 Equation 31).


### Os = (Pstd/Tstd),OsST' (1/(1-Bws))'(Ts/Ps) Os

# = 0.486 acfm 7) Average stacl{gas velocity, Vs (EPA aTM

### 27 Equation 11)


### Vs = Kp' Cp' (ave 

### 01 (dPyO.5)' (Ts/Ps·MwYO.5 Vs= 43.51 Ips 8) Average actualstackgas volumetric f/owrate, 

## Oa.
Oa 

### =60 sec/min'"Vs .., As Oa = 

### 217499.9 cfm 6159.6 cmm 9) Average stack

### gas drystandard volumetnc f/owrate, Ostd.


### Ostd = Oa • (Tstd/Ts) , (Ps/Pstd) , (1-Bws) Ostd = 155022.9 dscfm 4390.2 dscmm Page 2

### Client Project No. Spruance Genco, LLC 3333 

### Test Location Test Run

Calculations (cant.) Unit No.3 One Page 3



### 10) Analyticaldata
Cvclone aodFilterFractions (EPA Method OTM27); M1) Instackquartz microfibre filter, <2.Sum

0.0163 9 PM <2.5 filter netwt M2-4) Cyclone acetone washes
0.0000 9 actual mass of >2.5, Containers 2&3 0.0029 9 actual mass of

### <1=2.5um, Container4 0.0000 9 acetone blank netwt o mL volume 100 mL volume 100 mLvolume
0.0000 9 blank corrected mass of>2.Sum, Containers 2&3 = M2&M3 0.0029 9 blank corrected mass of</=2.5um, Container4 = M4


### Condensible Particulate Matter(CPM) Fractions (EPA Method202); MS) Back HalfAqueousWash

0.0087 9 actual sample mass 0.0003 9 aqueous blank mass 300 ml blank vol. 300 ml Sample volume
0.0064 9 condensible aqueous PM M6) Back Half MeCI2 Extraction Portion

0.0015 g extraction net

## wt 0.0000 g MeCI2 blank netwt 300 ml blank vol 300 ml MeCI2 extraction volume

00015 9 condensible organic PM M[CPMl

# =blank corrected mass of Tolal CPM, M5 & M6 (in grams) M[CPM[ = 0.0099 9 CPM 

### 11) Particulate Concentrattons, 

### C (EPA OTM27andEPA 202).

Equation 43 Equation 45

EPA 202 C[totalsus[ = M1 (g)+M2(g)+M3(g)+M4(g)'15.43(grainslg)Nmstd(dscf)= C[PM2.5sus] = M1 (g) + M4(g) '1543(grainslg) I Vmstd(dscD = C[CPM] = M[CPM](g) , 1543(grainslg) I Vmstd(dscf) where 15.43= 

### 7000/453592·1000 C[PMtotal] = C[PMtotalsus] + C[CPM] C[PM2.5total] = C[PM2.5sus] + CiCPM] 0.0024 gr/dscf PMsus 0.0024 gr/dscf PM2.5sus 0.0012 gr/dscfCPM

0.0036 gr/dscfTolal PM 0.0036 gr/dscfTotal PM2.5

### Client Project No. 

### Spruance Genco, LLC 3333



### 12) Particulate Emission Rates, E. Test Location Test Run

Calculations (cant.) 

### Unit No.3 One

E[lb/hr] = 

### C[](gr/dscf) • (1 Ib/7000 gr) • Ostd(dscfm) • 60(min/hr) E[lb/MMBtu]

# = C[](gr/dscf)' (1 

### Ib/7000 gr)' Fd(dscf/MMBtu)' 

### (20.9/20.9·%02) 

### E[totalsus] 

# = 3.18 

### Ib/hrtotal sus PM E[totalsus] 

# = 0.0042 

### Ib/MMBtu total sus PM E[PM2.5sus]

# = 3.18 

### Ib/hr PM2.5sus

# = 66.0 %ofTotal PM2 5 E[PM2.5sus]

# = 00042 

### Ib/MMBtu PM2.5sus

# = E[CPM]

# = 1.64 Ib/hrCPM 

### 34.0 %of Total PM2.S E[CPM]

# = 0.0022 Ib/MMBtu CPM E[PMtotal]

# = 4.82 

### Ib/hrtotal PM E[PMtotal]

# = 0.0063 

### Ib/MMBtu total PM E[PM2.5total]

# = 4.82 

### Ib/hrtotal PM2.S E[PM2.5total]

# = 0.0063 

### Ib/MMBtu total PM2.5 

### 13) Percent Isokinectic Sampling, %1 (EPA OTM27 

### Equation 40).

% 

### I

# =**[100*Ts~ms"Pstd)** I 

### (60"Vs*tr*An*Ps*(1-Bws)*Tstd) 

### % I = 

### 10S.37 

### 14) StackGas 

### Viscosity, u(EPA OTM27

### Equation 3).

u = 

### C1 + 

### C2"'(Ts"0.5) + 

### C3*(Ts"-2) + 

### C4·(%02)- (C5*Bws) + 

### C6·Bws*(TsIl2) 

### u = 

### 193.9 micropoise 

### Page4

### Client Project No. 

### Spruance Genco, LLC 

### 3333 Test location Test Run

Calculations (cont.) 

### 15) Test Condition Reynolds number, Nre (EPA OTM27 

### Equation 8).


### Nre

# =8.64'10'5'(Ps'MwlTs)·(Qslu) Nre = 

### 2895 

### Unit No.3 

### One

16) Actual Particle CutDiameterfor Cyclone I, D50 (EPA OTM27 

### Equation 32).


### 050= B1 • ([Ts 1(Mw'Ps)]A2091)' ((u1Qs)' 7091) 050

# = 10.28 um 17) Actual Cunningham Correction Factorbasedon Dp 

### =25um, C 

### (EPA OTM27 

### Equation 4).


### C = 1+ 0 0057193'(ul(Ps'Op))' (TsIMw),0.5 C = 1.0700 18) Initial 050 for Cyclone IVbased on testcondition Reynolds numberfrom OTM27 

### Equation 8.
If 

### Nre 

### < 3162, use Equation 33 which results in 050 for IV

# = If 

### Nre 

### >= 3162, use Equation 34which results In 

### 050 for iV

### = Initial 050 

### 2.25 2.18 Equation 33 Equation 34 Equation 35 

### 050 =0.0024302'(uIQs),1.1791'(1IC)'0.5·(Tsl(Ps·Mw))'0.6790 050 =0.019723·(uIQs)'0.S05S'(1IC),OS(Tsl(Ps·Mw))'0.305S Cr = 1 +0.0057193·(ul(Ps'050)),(TsIMw)'0.5 19) Re-established050 for Cyclone IV, 050-1. Page 5



### Re-established Cunningham, Cr 1.0778 

### 1.0805

If 

### Nre < 

### 3162, use Equation 36 which results in 050 for IV

# = If 

### Nre 

### >= 3162, use Equation 37 which results in 050 for iV

### = Recalculated Cut oiam, 050-1 

### 2.24 2.17 Equation 36 Equation 37 

### 050-1 =0.0024302·(uIQs),1.1791·(1ICryO.5'(Tsl(Ps·Mw))'0.6790 050-1 =0.019723'(uIQs)'O S05S'(1ICr)'OS(Tsl(Ps'Mw))'O.305S 19) Establishing "Z" value, 

### Z.
IfEquation 36 was used, then IfEquation 37 was used, then 

### Z= 050-1 1050= Z=D50-11050=
If 0.99 < 

### Z < 

### 1.01, then D50-1 is bestcut diameter estimate. If0.99 

### > Z 

### > 1 01, then repeat calcsfor Cr using 050-1 

### 1.00 100

### 3333-PM2.5-R2

Client 

### Project No. 

### Test Location Test Run Test Date Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT
INPUT INPUT INPUT
INPUT

INPUT INPUT 

### Vic = 

### Vm= Pstatic

# = Pb 

### = Ps

# = Pstd

# = dP

# = dH 

### = Tm= 

### Ts

# = Tstd= 

### Dn

# = An

# = y= tr

# = Os

# = As= Cp = 

### Kp= K1 

### = 

## K2= K3= 

### C1 

# = C2= C3= C4= C5= C6= 81 

### = Fd

# =

[02[ 

### [C02[ [N2[ AirNova, Inc. 

### EPA Methods 1,2,3,4, OlM 27 and 202 (Flows, 

### 02/C02, H20, PM2.5 and CPM) 

### Spruance Genco, LLC 

### 3333 UnitNO.3 

### Two 04119110 0730-1349
Emission Data
376.8 

### cc Vol. of H20 collected 125.617 dcf Dry

### gas meter reading 

### -0.50 

### in. H20 Static pressure 30.10 in. 

### Hg Barometric pressure 

### 30.06 

### in. Hg Stack pressure 29.92 

### in. Hg EPA Standard pressure 

### 0.7218 

### in. H20 ".5 Average sq.rt delta P

0.390 in. 

### H20 

### Average draft gauge reading 

### 525,1 R Average metertemperature 647.4 R Average stack temperature 527.7 R Standard temperature 0.180 in. 

### Nozzle diameter 0.000177 sq. ft. Area ofnozzle orifice 

### 0.99 Meter calibration factor, gamma 366.55 min. Duration of sampling time 10.300 ft, 

### Diameter ofstack 83.32 sq. ft. Cross sectional area ofstack

0,84 Pitot tube coefficient 85.49 ft[(lb/lbmol)*(inHg)l".5}/[s*R*inH20] Pitot tube constant 17.637 R/in.Hg constant 0.047070 cu.ftlml constant 0.0026688 in.Hg-cffml-R constant

-150.3162 upolse Viscosity constant

13.4622 upoisefR"0.5 Viscosity constant 3861530 upOlse/R"2 Viscosity constant 0,591123 upoise Viscosity constant

91.9723 upolse Viscosity constant 1.51761E-05 upoise/R"2 Viscosity constant 0.15625 Constant 9755 dscf/MMBtu Fuel Factor
Instrumental Data


### 3.83 %-dry 15.06 %-dry 81.11 %-dry Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project No. Spruanee Genco, LLC 

### 3333 Test Location Test Run
Calculations 

### Unit No.3 Two

1) DryGas Volume atstandardconditions, 

### Vms (EPA OTM

### 27 Equation 27).


### Vms =K1* 

### Y*Vm * (Pb +dH/13.6) 

### ITm 

### Vms

# = 125.844 dsef 3.564 dscm 2) Drygas 

### sampling rate atstandardconditions, QsST(EPA OTM

### 27 Equation 28). 

### QsST = 

### Vms/tr asST= 

### 0.343 dscfm 0.010 dscm / min. 3) Volume 

### ofwater vaporcondensedatstandardconditions, Vws (EPA OTM

### 27 Equation 29).


### Vws = 

### K2 * Vic Vws= 17.736 sef 4) Decimal fraction 

### ofmoisture by volume In 

### stackgas, Bws (EPA OTM

### 27 Equation 30).


### Bws

# = Vwstd , (Vmstd+Vwstd) Bws

# = 0.124 5) Molecularweight

### ofthe stackgas on 

### a wetbasis, Mw (EPA OTM

### 27 Equations 

### 1&2).
Mw = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) [+ (1S'Bws) 

### Mw

# = 2901 Ib/lbmole 6) Gas sampling rate atactual Cyclone conditions, 

### Os (EPA OTM

### 27 Equation 31).



### as = (Pstd/Tstd),asST' (1/(1-Bws))'(Ts/Ps) 

### Qs

# = 0.478 aefm 7) Average stackgas velocity, Vs (EPA OTM

### 27 Equation 11)


### Vs = Kp , Cp , (ave of (dP)'O.5) , (Ts/Ps'Mw),O.5 

### Vs 

### = 44.65 fps 8) Average actualstack

### gas volumetric flowrate, 

### Qa. Qa = 

### 60 sec/min * 

### Vs ,. As Qa

# = 223236.5 cfm 6322.1 cmm 9) Average stack

### gas drystandard volumetric 

### f/owrate, Qstd.


### astd = aa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

### Qstd = 160256.3 dscfm 4538.5 dsemm Page 2

### Client 

### Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations (cont.) Unit No.3 

## Two Page 3

10) Analyticaldata
Cvclone andFilterFractions (EPA Method OrM27). M1) Instack quartz mlcrofibrefilter, <2.5um

0.0057 9 PM <2.5 filter netwt M2-4) Cyclone acetone washes

0.0000 9 actual mass of >2.5, Containers 2&3 0.0030 9 actual mass of </=2.5um, Container4 0.0000 9 acetone blank netwt 

# omL volume 100 mL volume 100 mL volume

0.0000 g blank corrected mass of>2.5um, Containers 2&3 = M2&M3 0.0030 9 blank corrected mass of</=2.5um, Container4 = M4


### Condensible Particulate Matter(CPM) Fractions (EPA Method202). M5) Back HalfAqueous Wash

0.0064 9 actual sample mass 0.0003 9 aqueous blank mass 300 ml blank vol. 300 ml Sample volume

0.0061 9 condensible aqueous PM M6) Back HalfMeCI2 Extraction Portion
0.0019 9 extraction netwt 

### 0.0000 9 MeCI2 blank netwt 300 ml blank vol. 300 ml MeCI2 extraction volume
0.0019 9 condensible organic PM M[CPM]

### = blank corrected massof Total CPM, M5 

### & M6 (in grams) MICPM] = 0.0080 9 CPM 

### 11) Particulate Concentrations, C 

### (EPA OTM27andEPA 202).

Equation 43 Equation 45

EPA 202 Cltotalsus] = M 1(g)+M2(g)+M3(g)+M4(g)'1543(grains/g)Nmstd(dscf)= C[PM2 5sus] = M1(g) + M4(g) , 15.43(grains/g) 

### 1Vmstd(dscD = C[CPM] = MICPM](g) , 15.43(gralns/g) 

### 1Vmstd(dscD where 15.43

# =7000/453592*1000 C[PMtotal] = C[PMtotalsus] + C[CPM] C[PM2.5total] = C[PM2.5sus] + C[CPM] 0.0011 gr/dscf PMsus 0.0011 gr/dscf PM2.5sus 0.0010 gr/dscfCPM
0.0020 gr/dscfTotal PM 0.0020 gr/dscfTotal PM2.5

### Client Project No. 

### Spruance Genco, LLC 3333



### 12) Particulate Emission Rates, 

### E. Test Location Test Run

Calculations (cont.) Unit No, 3 

### Two

E[lb/hr[

# = C[[(gr/dscD • (1 Ib/7000 gr) • Qstd(dscfm) • 60(min/hr) E[lb/MMBtu]

# = C[](gr/dscD' (1 Ib/7000 gr)' Fd(dscf/MMBtu)' 

### (20.9/20.9-%02) 

### E[totalsusj = 

### 1.47 

### Ib/hrtotal sus PM E[totalsus] = 

### 0.0018 

### Ib/MMBtu total sus PM E[PM2.5sus]

# = 1.47 

### Ib/hr PM2.5sus = 

### 52,1 %ofTotalPM2.5 E[PM2.5sus]

# = 0.0018 

### Ib/MMBtu PM2.Ssus = 

### E[CPM]

# = 1.35 Ib/hr CPM 

### 479 

### %of Total PM2.5 E[CPM]

# = 0.0017 Ib/MMBtu CPM E[PMtotal]

# = 2.81 

### Ib/hrtotal PM E[PMtotal]

# = 0.0035 

### Ib/MMBtu total PM E[PM2.5total]

# = 2.81 

### Ib/hrtotal PM2.5 E[PM2.5total]

# = 0.0035 

### Ib/MMBtu total PM2.S 

### 13) PercentIsokinectic Sampling, %1 (EPA OTM27

### Equation 40).
% I

### = [100'Ts'Vms'Pstd) 1

### (60·Vs·tr·An·Ps·(1-Bws)'Tstd) 

### % I = 

### 101.01 

### 14) StackGas 

### Viscosity, U(EPA OTM27

### Equation 3).

u = 

### C1 + 

### C2*(TsI\0.5) + 

### C3

....(TsA-2) + 

### C4*(%02) - (CS*Bws) + 

### C6*Bws

....(TsA2) u = 

### 193,1 micropoise Page 4

### Client Project No. 

### Spruance Genco, 

### LLC 

### 3333 Test Location Test Run

Calculations (cont.) 15) Test Condition Reynolds number, Nre (EPA OTM

### 27 Equation 8).


### Nre

# =S.64*10115*(Ps*MwlTs)*(Qs/u) Nre

# = 2883 

### Unit NO.3 

### Two

16) Actual Particle CutDiameterfor Cyclone /, 050 (EPA OTM

### 27 Equation 32)


### 050= 81 • ([Ts 1(Mw' Ps)!'2091)'((u 1Os)'.7091) 050

# = 10.35 um 17) Actual Cunningham Correction Factorbasedon Op = 

### 2.5um, 

### C (EPA OTM

### 27 Equation 4).


### C = 1+ 0 0057193'(ul(Ps'Op))' (TsIMwyO.5 C

# = 10694 18) Initial 050 for Cyclone IVbasedon testcondition Reynolds numberfrom OTM

### 27 Equation 8


### IfNre < 

### 3162. use Equation 33 which results in 050 for IV

# = IfNre 

### >= 3162, use Equation 34 which results in 050 for iV 

### = Initial 050 

### 2.27 2.19 Equation 33 Equation 34 Equation 35 

### 050 =0.0024302'(uIOs)'1.1791'(11C)'0.5'(Tsl(Ps'Mw)),0.6790 050 =0.019723'(uIOs)'0.8058'(1ICYO 5'(Tsl(Ps'Mw))'0.3058 Cr= 1 +0.0057193'(ul(Ps'050)),(TsIMwYO.5 19) Re-establlshed050 for Cyclone IV, 050-1. Page 5



### Re-established Cunningham. Cr 

### 1.0764 1.0792

IfNre < 

### 3162, use Equation 36 which results in 050 for IV

# = If Nre 

### >= 3162, use Equation 37 which results in 050 for iV = 

### Recalculated Cut Oiam. 050-1 

### 2.26 218 Equation 36 EquatIOn 37 

### 050-1 =0.0024302'(uIOsY1.1791'(1ICr)'0.5'(Tsl(Ps·Mw)),0.6790 050-1 = 0.019723'(uIOs)'0.805S'(1ICrYO.5'(Tsl(Ps'Mw))'0 3058 19) Establishing "Z" value, 

### Z.
If 

### Equation 36 was used, then 

### If Equation 37 was used, then 

### Z=050-1 1050 = Z=050-11050=
If 0.99 < 

### Z < 

### 1.01, then 050-1 is best cut diameter estimate. If0.99 > 

### Z > 

### 1.01, then repeat cales for Cr using D50-1 

### 1.00 100

### 3333-PM2.5-R3

Client 

### Project No. Test Location Test Run Test Date 

### TestTime



### INPUT INPUT INPUT INPUT

INPUT INPUT
INPUT INPUT INPUT
INPUT

INPUT INPUT Vlc= Vm= Pstatic

### = Pb

# = Ps

# = Pstd = 

### dP

# = dH = 

### Tm= Ts = 

### Tstd= Dn = 

### An

# = y= tr

# = Ds

# = As

# = Cp= Kp

# = K1 

# = K2

# = K3

# = C1= 

### C2 = 

### C3 

### = C4= 

### C5= C6= 61 

# = Fd

# =

[02] [C02] [N2] AirNova, Inc. EPA Methods 1,2,3,4, OTM 27 and 202 

### (Flows, 021C02, H20, PM2.5 and CPM) Spruance Genco, LLC 

### 3333 UnitNO.3 

### Three 04/19/10 1448-2103
Emission Data
355.8 

### cc Vol. of H20 collected 

### 123,826 dcf 

### Dry gas meter reading -0.50 in. 

### H20 Static pressure 

### 30,03 in 

### Hg Barometric pressure 29.99 in. 

### Hg Stack pressure 

### 2992 in 

### Hg EPA Standard pressure 0.6956 

### in, H20 ".5 Average sq.rt delta P

0.390 in. 

### H20 Average draftgauge reading 

### 538.5 R Average metertemperature 646.2 R Average stacktemperature 527.7 R Standard temperature 

### 0.180 in. 

### Nozzle diameter 0.000177 

### sq. ft. Area ofnozzle orifice 

### o 

### 99 Metercalibration factor, gamma 353.29 min Duration ofsampling time 10.300 

### ft. Diameter ofstack

83.32 sq. ft. 

### Cross sectional area ofstack

0.84 Pitottube coefficient 

### 85.49 ft[(lbllbmolt(inHg)]'.5)I[s·R·inH20] Pito11ube constan1 17,637 R/in.Hg constant 0,047070 cU.fUml constant 0.0026688 in,Hg-cf/ml-R constant

-150.3162 upolse Viscosity constant

13.4622 upoise/RA O.5 Viscosity constant 3861530 upoise/RA2 Viscosity constant 0.591123 upoise Viscosity constant

91.9723 upoise Viscosity constant 1.51761E-05 upoise/RA2 Viscosity constant 0,15625 Constant 9868 dscf/MMBtu
Instrumental Data
5.00 %-dry 13.94 %-dry 81.06 %-dry Fuel Factor

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project No. 

### Spruanee Genco, LLC 

### 3333 Test Location Test Run
Calculations 

### Unit No 3 Three



### 1) DryGas 

### Volume atstandardconditions, Vms (EPA OTM27 

### Equation 27),
Vms =K1* Y ." Vm ." (Pb + dH/13.6) 

### ITm Vms = 120.678 dscf 3.418 dscm 

### 2) Drygas sampling rate atstandardconditions, QsST(EPA OTM27 

### Equation 28).
QsST = Vms /tr QsST 

### = 0.342 dscfm 0.010 dscm J

### min, 

### 3) Volume ofwatervaporcondensedatstandardconditions, Vws (EPA OTM27 

### Equation 29).
Vws = K2 "'Vlc Vws= 16.747 sef 

### 4) Decimalfraction ofmoisture by volume in stackgas, Bws 

### (EPA OTM27 

### Equation 30).
Bws =Vwstd / (Vmstd+Vwstd) Bws= 0.122 

### 5) Molecularweightofthe stackgas on 

### a wetbasis, Mw (EPA OTM

### 27 Equations 

### 1 &2).
Mw

### = [ ((44'%C02) + (32'%02) 

### + (2S'%N2)) , (1-Bws) 

## I+ (1S'Bws) Mw = 28.92 Ib/lbmole 

### 6) Gas sampling rate atactual Cyclone conditions, 

### OS (EPA OTM27 

### Equation 31).
Qs

# =(PstdlTstd)'QsST' (1/(1-Bws))'(Ts/Ps) Qs = 0.475 acfm 

### 7) Average stackgas velocity, 

### Vs (EPA OTM

### 27 Equation 11).
Vs

# =Kp' Cp' (ave 

### 01 (dPyO.5)' (Ts/Ps'MwyO.5 Vs = 

### 43.12 Ips 

### 8) Average actualstackgas volumetric fJowrate, 

### Oa.
Oa =60 sec/min"Vs

.. As Oa = 215568,9 cfm 6104.9 cmm 

### 9) Average stackgas drystandard volumetric fJowrate, Ostd.
Qstd 

### =Qa' (TstdlTs)' (Ps/Pstd)' (1-Bws) Qstd = 154963.4 dscfm 4388,6 dscmm Page 2

### Client 

### Project No. Spruance Genco, LLC 3333 

### Test Location Test Run

Calculations (cont.) Unit NO.3 Three Page 3

10) Analyticaldata
Cvclone andFOterFractions (EPA Method OTM27): 

### M1) Instackquartz microfibrefilter, <2.5um
0.0045 9 PM <2.5 filter net

## wt M2-4) Cyclone acetonewashes
0.0000 9 actual mass of>2.5, Containers 2&3 0.0024 9 actual mass of <1=2.5um, 

### Container 4 0.0000 9 acetone blank net

## wt 

# o mL volume 100 mL volume 100 mL volume
0.0000 9 blank corrected mass of >2.5um, Containers 2&3 

### = M2&M3 0.0024 9 blank corrected mass of <1=2.5um, 

### Container 4

# =M4
Condensible Particulate Matter(CPM) Fractions (EPA Method202): 

### M5) Back HalfAqueous Wash
0.0107 9 actual sample mass 0.0003 9 aqueous blank mass 300 ml blank vol. 300 ml Sample volume
0.0104 9 condensible aqueous PM M6) Back Half MeCI2 Extraction Portion
0_0012 g extraction net

## wt 0_0000 9 MeCI2 blank net

## wt 300 ml blank vol. 300 ml MeCI2 extraction volume
0.0012 9 condensible organic PM M[CPM]

# =blank corrected mass of Total CPM, M5 

### & M6 (in grams) M[CPM] = 0.0116 9 CPM 11) Pariiculate Concentrations, 

### C (EPA OTM27andEPA 202).

Equation 43 Equation 45



### EPA 202 

### C[totalsus] = M1 (g)+M2(g)+M3(g)+M4(gt15.43(grains/g)Nmstd(dscf)= C[PM2.5sus] = Ml(g) + 

### M4(g) '15.43(gralns/g) IVmstd(dscD = C[CPM] = M[CPM](g) '1543(grains/g) 1

### Vmstd(dscD where 15.43 = 

### 7000/453592"'1000 

### C[PMtotal] = C[PMtotalsus] + C[CPM] C[PM2.5total] = C[PM2.5sus] + C[CPM] 0.0009 gr/dscf PMsus 0.0009 gr/dscf PM2.Ssus 0.0015 gr/dscfCPM
0.0024 gr/dscfTotal PM 0,0024 gr/dscfTotal PM2,S

### Client Project No. 

### Spruance Genco, LLC 3333



### 12) Particulate Emission Rates, 

### E. Test Location Test Run

Calculations (cont.) 

### Unit No.3 Three

E[lb/hr[

# = C[[(gr/dscf)' (1 Ib/7000 

### gr)'Qstd(dscfm)'60(min/hr) E[lb/MMBtu] 

### = C[](gr/dscf)' (1 Ib/7000 

### gr)' Fd(dscf/MMBtu)' (20.9120.9-%02) 

### E[totalsusJ = 

### 1.17 

### Ib/hrtotal sus PM E[totalsus] = 

### 0.0016 

### Ib/MMBtu total sus PM E[PM2.5slls]

# = 1.17 

### Ib/hr PM2 5sus = 

### 37.3 

### %of Total PM2.5 E[PM2.5sus]

# = 0.0016 

### Ib/MMBtu PM2.5sus = 

### E[CPM]

# = 1.97 Ib/hr CPM 

### 62.7 

### %of Total PM2 5 E[CPM]

# = 0.0027 Ib/MMBtu CPM E[PMtotal]

# = 314 

### Ib/hrtotal PM E[PMtotal]

# = 0.0044 

### IblMMBtu total PM E[PM2.5total]

# = 3.14 Ib/hrtotal PM2.5 E[PM2.5total]

# = 00044 

### Ib/MMBtu total PM2 5 

### 13) Percentfsokinectic Sampling, %1 (EPA OTM27

### Equation 40).
% 

### I = 

### [100*Ts*Vms*Pstd) 

### I**(60~Vs~tr*An*Ps*(1-Bws)*Tstd)** 

### % [= 

### 103.93 

### 14) StackGas 

### Viscosity, u(EPA OTM27 

### Equation 3).



### u = 

### C1 + 

### C2*(Ts"0.5) + 

### C3*(Tsl\-2) + 

### C4*(%02) - (C5*Bws) + 

### C6*Bws*(TsI\2) u = 

### 193.7 micropoise Page4

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations (cont.) 15) Test Condition Reynolds number, Nre (EPA aTM

### 27 Equation B).


### Nre = 8.64'10'5'(Ps'MwlTs),(Os/u) Nre = 

### 2845 Unit NO.3 Three

16) Actual Particle CutDiameterfor Cyclone I, 050 (EPA OTM

### 27 Equation 32).


### D50 = B1'( ITs/( Mw' Ps)]'.2091), ((u/Os)'.7091) 050

# = 1 0.42 

### urn 17) Actual Cunningham Correction Factorbasedon Op

# = 2.5um, 

### C (EPA OTM

### 27 Equation 4).


### C = 1+ 0.0057193' (u/(Ps'Dp))' (Ts/Mw)'0.5 C = 1.0698 18) Initial 050 for Cyclone IVbasedon testcondition Reynolds numberfrom OTM

### 27 Equation B.
IfNre < 

### 3162, use Equation 33 which results in 050 for IV

### = IfNre >= 

### 3162, use Equation 34 which results in 050 for iV = 

### Initial 050 

### 230 2.21 Equation 33 Equation 34 Equation 35 

### D50 = 0.0024302'(u/Os),1.1791'(1/C)'0.5'(Ts/(Ps'Mw)),0.6790 D50 = 0.019723'(u/Os)'0.8058'(1/C),0.5'(Ts/(Ps'Mw))'0.3058 Cr = 1 + 0.0057193'(u/(Ps'D50)),(Ts/Mw)'0.5 19) Re-established050 for Cyclone IV, 050-1. 

### Page 5

Re-establlshed Cunningham, Cr 

### 1.0759 1.0790

If Nre < 

### 3162, use Equation 36 which results in 050 for IV

# = If Nre >= 

### 3162, use Equation 37 which results in 050 for iV = 

### Recalculated Cut Oiam 050-1 

### 2.29 2.20 Equation 36 Equation 37 

### D50-1 = 00024302'(u/Os)'1.1791'(lICr)'0.5'(Ts/(Ps'Mw))'0.6790 D50-1 

# =O.019723'(u/Os),0.

### 8058'(lICr)'O.5'(Ts/(Ps'Mw)),0.3058 19) EstablishIng "Z" value, Z.


### If Equation 36 was used, then If Equation 37 was used, then 

### Z= D50-1/D50 = Z=D50-1/D50=
If 0,99 < 

### Z < 

### 1.01, then 050-1 IS 

### best eut diameter estimate. If 0.99 > 

### Z > 

### 1.01, then repeat cales for Cr using 050-1 

### 1.00 1.003333-TSP-Me\als-R1

Client Project No. Test Location Test Run Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vlc= Vm= Pstatic = Pb= Ps= Pstd = dP= dH

# = Tm= Ts= Tstd= On = An = y= t= Os 

### = As 

### = Cp 

### = Kp = K1 = K2 = K3 

### = Fd 

### =

[02] [C02]
[N2] 

### AirNova, Inc, EPA Methods 1,2,3A,4,5 and 29 (Flows, 02/C02, H20, TSP and Metals) 

### Spruance Genco, LLC 

### 3333 Unit NO.3 One 

### 04/16/10 

### 0840-1446

696.7 cc Emission Data

230.214 dcf -0.50 in. H20 30.07 in. Hg 30.03 in. Hg 29.92 in. Hg 0.6865 in. H20 ".5

1,398 in. H20 543.5 R 652.8 R 527.7 R 0.250 in. 0.000341 sq. 

### ft. 1.01 360 min. 10.30 

### ft. 83.3204 sq. 

### ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area ofnozzle orifice Meter calibration factor Duration ofsampling time Diameterofstack Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lb/lbmol)*(inHg)]".S}/{s*R*inH20] Pitottube constant 17.637 R/in.Hg 0.047070 cu.ftlml 0.0026688 in.Hg-Cf/ml-R 9862 scf/MMBtu

Instrumental Data

4.07 %-dry

14.76 %-dry

81.17 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruanee Genco, LLC 3333 Test Location Test Run

Calculations 1)Volume ofgassampled atstandard conditions, Vmstd.

Vmstd**=K1~** Y*Vm • (Pb +dH/13.6) ITm Vmstd 

### = 227.685 dsef 6.448 dsem Unit NO.3 

### One

2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2·Vic Vw(std) = 32.794 sef 3) Decimal fraction of moisture byvolume In stack gas, Bws.

Bws =Vwstd I (Vmstd+Vwstd) Bws = 0.1259 4) Molecularweightofthe stack gason awet basis, Ms.

Ms =**[({44~%C02)** + (32'"%02) + (28*%N2)) * (1-Bws) 

### 1 + (18*Bws) Ms= 28.948 Ib/lbmole 5) Average stack gas velocity, Vs.

Vs = Kp * Cp· (dP);; (TsJPs*Ms)",5 Vs = 42.718 fps 6) Average actual stack gas volumetric flowrate, Qa.

Oa =60 sec/min * Vs *As Oa = 213555.99 efm 6047.91 emm 7) Average stack gas dryvolumetric f1owrate, Qstd.

Ostd = Oa;; (TstdfTs) * (Ps/Pstd) • (1-Bws) Ostd = 151472.15 dscfm 4289.69 dscmm Page 2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run Unit No, 3 

### One
Calculations (cont.) 8) Particulate MatterAnalytical Data
INPUT 

### A 0.2207 9 INPUT B 100 ml INPUT C 0,1692 9 INPUT 

### 0 100 ml INPUT E 0.0000 9 9) Particulate sample mass calculations

H



### J Front Half: Acetone blank adj. residue v Adj. Acetone wash part.wt. Front halfsamplewt. 10) Front Half Particulate Matter Emission Data Filter sample netwt Front acetone wash vol Front acetone residue wt, Acetone blankvol. Acetone blank residuewt.

0.0000 9 0.1692 9 0.3899 9 

### E·(BID) C-H A+ I

C[PM]

# = (Front HalfWt){g) "(1Nmstd) " 15.43(grains/g) E[PM] = C[PM] " Vdscfm " A • (60 min/hr)· (1 Ib 17000 grains) Page 3

E[PM]lb/MMBtu 

### =E[PM]lb/hr*{Fuel HV) scf/Btu"(fuel use) 1 hour/kscfkscfl1000scf10"6Btu/MMBtu C[PM] = 2.S4E-02 grains/dscf C[PM] = 3.77E-06 Ib/dscf E(PM] = 34,306 Ib/hr E[PMJ = 4,S2E-02 Ib/MMBtu 11)Trace metal concentrations and emission rates

Element Antimony Arsenic Beryllium Cadmium Chromium

Cobalt Lead Manganese Nickel Selenium C[M] 

### =M[M] tug) I Vmstd (dscm) C[M]{lb/dscf) = C[M]{ug/dscm) " 1e-OSg/ug"2.20Se-03Ib/g • 0.02832 dscmldscf E[M]{Ibfhr) = C[M] (ug/dscm)

.. (2.20SE-09) (Ibfug)"* Qstd (dscmm) "60 (min/hr) E[M]{Ib/MMBtu) = C[M)(lbfdscf)

.. Fd "(20.9f20.9-%02) C[M](@eorr. 02) = C[M] (ugfdscm) • [(20.9-corrected %02) I (20,9-actual %02») Corrected 02 percentage is: 7.0 % Sample Conc. Conc.@!;;Q[r.Q2 Cone. Emission Rate Mass tug} (ugfdscml (ug/dscm) (Ibfdscf} (lbfhr)

3.496 S.42E-01 4.48E-01 3.39E-11 3.0BE-04 8.996 1.40E+OO 1.1SE+00 B.71E-11 7,92E-04 5.16 B.00E-01 S.SIE-01 S.00E-11 4,S4E-04 0.903 1.40E-01 1.1SE-Ol B.75E-12 7.9SE-OS 15.363 2.38E+00 1_97E+OO 1.49E-l0 1.35E-03 16.09 2.50E+00 2.0SE+OO 1.56E-l0 1.42E-03 17.814 2.76E+OO 2.2BE+OO 1.73E-l0 1.S7E-03 12.871 2,OOE+00 1.SSE+OO 1.2SE-10 1.13E-03 23.27 3,61 E+OO 2.98E+OO 2,25E-10 2.05E-03

9 1.40E+OO 1.1SE+OO B,72E-11 7.92E-04 12) Isokinecity, I.
% I= [100·Ts·(K3"*Vlc+«{Vm"Y)fTm)"(Pb+(dHf13.6))))] I (60*t·Ps"Vs*An) %1= 102.06

.. <
.. symbol indicates values given arethe quantitative detection limit. Emission Rate (lb/MMBtu) 4.146E-07 1.0S7E-OS 6.120E-07 1.071E-07 1.822E-OS 1.90BE-OS 2.113E-OS 1.S27E-06 2.760E-06 1.0B7E-06

### 3333-TSP-Metals-R2

Client Project No. Test Location Test Run Test Date Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vlc= Vm= Pstatic= Pb = Ps = Pstd = dP = dH = Tm= Ts = Tstd= On = An = y= t= Os = As ::; Cp = Kp ::; K1 

### = K2 = K3 = Fd =

[02] [C02[
[N2] 

### AirNova, Inc. EPA Methods 1,2,3A,4,5and 29 (Flows, 02/C02, H20, TSP and Metals) 

### Spruance Genco, LLC 

### 3333 Unit No.3 Two 04119/10 

### 0730-1435

Emission Data



### 669.9 cc 

### 226,121 dcf -0.50 in. H20 

### 30.10 in. Hg 

### 30.06 in. Hg 

### 29.92 in. Hg 0.6931 in. H20 ".5



### 1.375 in. 

### H20 521.5 R 

### 651.0 R 

### 527.7 R 

### 0.250 in. 

### 0.000341 sq. ft. 

### 1.01 360 min. 

### 10.30 ft. 83.3204 sq. ft. Vol. ofH20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stacK temperature Standard temperature Nozzle diameter Area ofnozzle orifice Meter calibration factor Duration ofsampllng time Diameter ofstack Cross sectional area ofstack 

### 0.84 Pitot tube coefficient 

### 85.49**ft[(lb/lbmol}"(inHg)1".5}/[s~R*inH201** Pitottube constant 17.637 R/in.Hg constant 

### 0.047070 cu.ftlml constant 

### 0.0026688 in.Hg-cf/ml-R 

### 9755 scf/MMBlu

Instrumental Data



### 3.83 %-dry



### 15.06 %-dry



### 81.11 %-dry constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 Test Location Test Run
Calculations 1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1"* 

### Y" Vm "* (pb + dHf13.6) ITm Vmstd = 233.254 dscf 

### 6.606 dscm Unit No.3 Two

2)Volume ofwatervapor collected at standard conditions, Vw(std).
Vw(std) = K2 * Vic Vw(std) = 31.532 set 3) Decimal fraction ofmoisture byvolume In stack gas, Bws.

Bws = Vwstd I (Vmstd+Vwstd) Bws= 

### 0.1191
4) Molecularweight ofthe stack gas on 

### awet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28*%N2)) "* (1-Bws) 

## 1 + (18*Bws) Ms = 29.067 Ibf lbmole 5) Average stack gasvelocity, Vs.

Vs = Kp * Cp * (dP)"***(TsfPs~Ms)/I..5** Vs = 42.958 fps 6) Average actual stack gas volumetric flowrate, Oa.

Qa = 60 sec/min *Vs *As Qa 

### = 214758.86 cfm 

### 6081.97 cmm 7) Average stack gas dryvolumetricflowrate, Qstd.

Qstd = Qa"* (TstdfTs) * (Ps/Pstd) * (1-Bws) Qstd = 

### 154098.57 dscfm 4364.07 dscmm Page2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run Unit NO.3 Two
Calculations (cont.) 8) Particulate MatterAnalytical Data
INPUT A 0.2045 9 INPUT B 100 ml INPUT C 0.1071 9 INPUT D 100 ml INPUT E 0.0000 9 9) Particulate sample mass calculations

H

J Front Half: Acetone blank adj. residue v Adj. Acetone wash part.wI. Front half sample wt. 10) Front HalfParticulate Matter Emission Data Filtersample netwt Frontacetonewash vol. Frontacetone residue wi, Acetone blank vol. Acetone blank residuewi.

0.0000 9 0.1071 9 0,3116 9 E'(B/D) C-H A+ I

C[PMJ = (Front HalfWt)(g) * (1Nmstd) * 15.43{grains/g) E[PM] = C[PM]**~** Vdscfm * A

- (60 minfhr) * (1 Ib

### 17000 grains) Page 3

E[PM]lbfMMBtu = E[PM]lbfhr-(Fuel HV) scf/Btu*(fuel use) 1 hourfkscf*kscff1000scf"10"6BtuIMMBtu C[PM] = 2.05E-02 grainsldscf C[PM] = 2.94E-06 Ibfdscf E[PM) = 27.226 Ibfhr E[PM) = 3.S2E-02 IbfMMBtu
11)Trace metal concentrations and emission rates

Element Antimony Arsenic Beryllium Cadmium Chromium

Cobalt Lead Manganese Nickel Selenium C[M] 

### = M[MJ (ug) IVmstd (dscm) C[M](lbfdscf) = C[M){ugldscm) *1e-06glug * 2.205e-03Ib/g * 0.02832 dscm/dscf E[MlOb/hr) 

### =C[M] (ugldscm) * (2.20SE-09) (Ibfug) * Qstd (dscmm) * 50 (min/hr) E[M](IbfMMBtu) '" C[M){lbfdscf) * Fd * (20.9f20.9-%02) C[M](@corr. 02) = C[M) (ug/dscm) * [(20.9-corrected %02)I (20.9-actual %02)] Corrected 02 percentage is: 7.0 % Sample Conc. Conc.@corr. 02 Cone. Emission Rate Mass tug} (ug/dscm) (ug/dscm) {Ibfdscf} (lbfhrl

2,417 3.66E-01 2.98E-01 2,28E-11 2.11 E-04 14.358 2.17E+OO 1.77E+OO 1,36E-10 1.2SE-03

3,12 472E-01 3.8SE-01 2.9SE-11 2.73E-04 1.01 1.S3E-01 1.2SE-01 9.5SE-12 B.S3E-OS 17.94 2.72E+00 2.21E+OO 1.70E-10 1.57E-03 9.63 1.46E+OO 1.19E"'OO 9. 1OE-11 S.42E-04 17.958 2.72E+OO 2.21E"'OO 1.70E-10 t57E-03 13.782 2.09E+OO 1.70E+OO 1.30E-10 1.20E-03 21.58 3.27E+OO 2.66E+OO 2.04E-10 t89E-03 7.95 1.20E+OO 9,80E-01 7.S2E-11 6.95E-04 12) Isokinecity, I.
% I = [100*TS*(K3"Vlc+«{Vm-Y)fTm)*(Pb+(dHf13.6))))) I (60*t*Ps*VS"An) % I = 102,77
"<"symbol indicates values given arethe quantitative detection limit. Emission Rate (lb/MMBtu) 2.729E-07 1.521E-06 3.S23E-07 1.140E-07 2.026E-06 1.0B7E-06 2.028E-06 1.SS6E-06 2,437E-06 8976E-073333-TSP-Metals-R3

Client Project No. Test Location Test Run Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vlc= Vm= Pstatic = Pb= Ps = Pstd = dP = dH = Tm = Ts= Tstd= On 

### = An 

### = y= 1= Os = As= Cp= Kp= K1 = K2= K3= Fd =

[02[
[C02[
[N21 AirNova, Inc. EPA Methods 

### 1,2,3A,4,5 and 29 (Flows, 02/C02, H20,TSP and Metals) 

### Spruance Genco, LLC 

### 3333 Unit No.3 Three 04/1911

### 0 

### 1448-2103

626.1 cc 214.412 dcfEmission Data

-0.50 in. H20 30.03 in. Hg 29.99 in. Hg 29.92 in. Hg 0.6420 in. H20 ''.5

1.186 in. H20 531.4 R 648.0 R 527.7 R 0.250 in. 0.000341 sq. ft. 1.01 360 min. 10.30 ft. 83.3204 sq. ft. 0.84 Vol. ofH20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rtdelta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area of nozzle orifice Metercalibration factor Duration of sampling time Diameterofstack Cross sectional area ofstack Pitot tube coefficient 85.49 ft[(lb/lbmol)"(inHg)I".5}f[s"R·inH20] Pitot tube constant 17.637 R/in.Hg 0.047070 cu.ftfml 0.0026688 in.Hg-cf/ml-R 9868 scf/MMBtu

Instrumental Data

5.00 %-dry

13.94 %-dry

81.06 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 Test Location Test Run
Calculations
1)Volume ofgas sampled at standard conditions, Vmstd.

Vmstd =K1**~** Y* Vm • (Pb +dHf13.6) I Tm Vmstd = 216.479 dscf 6.131 dscm Unit No.3 Three

2) Volume ofwater vapor collected atstandard conditions, Vw(std). Vw(std) = K2 *Vic Vw(std) = 29.470 scf 3) Decimal fraction ofmoisture by volume in stack gas, Bws.

Bws =Vwstd f(Vmstd+Vwstd) Bws= 0.1198 4) Molecularweight ofthe stack gas on awet basis, Ms.
Ms = [«44·%C02)+ (32*%02) + (2S*%N2))**~** (1-Bws) 

## 1 +**(18~Bws)** Ms= 28.941 Ibf Ibmole 5) Average stack gasvelocity, Vs.

Vs = Kp" Cp**~** (dP) ***(Ts/Ps~MsY'.5** Vs = 39.835 fps 6) Average actual stack gas volumetric flowrate, Ca.
Qa = 60 sec/min**~**Vs " As Qa 

### = 199144.23 cfm 5639.76 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa;O (TstdlTs)" (Ps/Pstd) * (1-Bws) Qstd = 143083.41 dscfm 4052.12 dscmm Page 2Client Spruance Genco, llC Project No. 3333 Test Location Test Run Unit No.3 Three Calculations (cont.) 8) Particulate MalterAnalytical Data INPUT 

### A 0.1218 g INPUT B 100 ml INPUT 

### C 0.0758 9 INPUT 

### 0 100 ml INPUT E 0.0000 9 9) Particulate sample mass calculations

H



### J Front Half: Acetone blank adj. residue v Adj, Acetone wash part.wt. Front half sample wt. 10) Front HalfParticulate Matter Emission Data Filter sample netwt Frontacetone wash vol, Frontacetone residue wt. Acetone blank vol. Acetone blank residue wt.

0.0000 

### 9 0.0758 

### 9 0.1976 

### 9 E"(B/O) C-H A+ I

C[PM] = (Front HalfWt)(g)**~** (1Nmstd) " 15.43(9rains/g) E[PM] 

### =C[PM] •Vdscfm**~** 

### A

.. (60 min/hr)" (1 Ib 17000grains) Page 3

E[PM]lb/MMBtu =**E[PM]lbfhr~(Fuel** HV) scf/Btu"(fuel use) 1**hourfkscf"kscf/1000scr10~6Btu/MMBtu** C[PM] = 1.41E-02 grains/dsd C[PM] 

### = 2.01E-06Ib/dscf E[PM] = 17.2731bfhr E[PM] = 2.61 E-02 IbfMMBtu 11)Trace metal concentrations and emission rates

Element Antimony Arsenic Beryllium Cadmium Chromium

Cobalt lead Manganese Nickel Selenium C[M] = M[M] (ug) fVmstd (dscm) C[M](lb/dscf) = C[M](ug/dscm) "1e-06g/ug" 2.205e-03Ib/g" 0.02832 dscmfdscf E[M](Ib/hr) = C[MJ (ug/dscm)" (2.20SE-09) (Ib/ug)" Qstd (dscmm)"60 (min/hr) E[M](Ib/MMBtu) = C[M](Ib/dscf)" Fd • (20.9/20.9-%02) C[M](@corr.02)=C[M](ug/dscm)·[(20.9-corrected%02) I (20.9-actual %02)] Corrected 02 percentage is: 7.0 % Sample Cone. Conc.@corr_ Q2 Conc_ Emission Rate Mass (ug) {ugfdscm} {ug/dscm} (lb/dscf) (lb/hr)

2.109 3.44E-01 3.01E-01 2.1SE-11 1.B4E-04 11.424 1.86E+OO 1.63E+00 1.18E-10 9.99E-04

1.72 2.81E-01 2.4SE-01 1.75E-11 1,50E-04 0.959 1.SBE-01 1.37E-01 9.77E-12 8.39E-05 13.36 2.18E+OO 1_91E+OO 1.3BE-10 1,17E-03 5,84 9.53E-01 8.33E-01 5,95E-11 S.11E-04 14.122 2,30E+QO 2_01E+OO 1.44E-10 1.23E-03 9.802 1,SOE+QO 1.40E+00 9.98E-11 8.S7E-04 17.88 2,92E+OO 2.S5E+00 1.82E-10 i.5SE-03 5.51 8.99E-01 7.86E-01 5_S1E-11 4.82E-04 12) Isokinecity, I.
% I

### =[100·Ts·(K3"Vlc+«(Vm"Y)/Tm)*(Pb+(dHf136»)))]1 (60*t*Ps"Vs"An) %1= 102.73
" < " symbol indicates values given are the quantitative detection limit. Emission Rate {lb/MMBtu} 2.786E-07 1.509E-OB 2.272E-07 1.267E-07 1.76SE-OB 7.71BE-07 1,8BBE-OB 1.295E-OB 2362E-OB 7.280E-073333-Hg-unspiked-R1

Client Project No. Test location Test Run Test Date Time Period

INPUT INPUT INPUT

INPUT INPUT INPUT INPUT INPUT



### INPUT

INPUT

INPUT Vm= Pstatlc = Pb = Ps = Pstd = 

### Tm· Ts = Tstd= y= 

# ,= Os 

### = As 

### = Kp = K1 = K2= K3 

### = Fd

# =

[02[
[C02) 

### [N2) 

### AirNova, Inc. EPA Method 1, 2, 3A, and 30B

- Unspiked Tube (Flows, 02/C02, and Mercury) 

### Spruance Genco, LLC 3333 Unit No.3 One 04/16/10 

### 0840-1440

Emission Data

8.002 dcf -0.50 in. H20 30.07 in. Hg 30.03 in. Hg 29.92 in. Hg 562.8 R 652.8 R 527.7 

### R 1.000

360 min. 10.30 ft Dry gas meter readmg Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stacktemperature Standard temperature Meter calibration factor Duration ofsampling time Diameter of Stack 83.32043375 sq. ft Cross sectional area of stack 85.49 ft[(lb/lbmol)*(inHg)]".5}/[s"R"mH20] 17637 R/in.Hg 0.047070 cu.ftlml 0.0026688 in.Hg-cf/ml-R 9862 scf/MMBtu

Instrumental Data

4.07 %-dry

14.76 %-dry

81.17 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1)Volume ofgassampled atstandard conditions, Vmstd.

Vmstd =K1* Y * Vm * PblTm Vmstd = 7.541 dscf 0.2135 dscm
3) Decimalfraction ofmoisture byvolume instack gas, Bws.

Bws = Based on the M29 sampling train INPUT Bws = 0.1259
4) Molecularweightofthestackgas on a wet basis, Ms. Unit No.3 One

Ms = [«44*%C02)+ (32*%02) 

### +(28*%N2»***(1~Bws)]** 

### + (18*Bws) Ms= 28.948 Ibllbmole 5) Average stack gas velocity, Vs.

INPUT Vs= Vs = Based on the M29 sampling train 42.718 fps 6) Average actualstack gas volumetricflowrate, Qa.
Qa = 60 seclmin *Vs ., As Qa = 213556.94 cfm 6047.93 cmm 7) Average stack gas dryvolumetricflowrate, Qstd.
Qstd = Qa * (TstdfTsj 

### * (PsIPstd) * (1-Bws) Qstd = 151468.49 dscfm 4289.59 dscmm 8) Mercuryconcentrationsandemission rates
C[M] = M[M] (ug) IVmstd (dscm) C[M](Ib/dscf) 

### =C[M](ug/dscm) ·1e-06g/ug'"2.205e-03Ib/g'" 0.02832 dscm/dscf E[MJ(lb/hr) = C[M] 

### (ug/dscm)

... (2.20SE-09) (Ib/ug) "Qstd (dscmm) ;0; 60 (minlhr) E[M](Ib/MMBtu) = C[M](lbldscf) • Fd

... (20.9/20.9-%02)

Element Mercury C[MJ(@ carr. 02)

# = C[M] (ug/dscm) ;0; [(20.9-corrected %02) I (20 9-actual %02)

## I Corrected 02 percentage is 7 %
Sample Mass (ug)

0.0012 Conc. (ug/dscml



### 0.006 Conc.@COrr. 02 (ug/dscm)

0.005 Cone. (lb/dscf) 3.S1E-13 Emission Rate (Ib/hr) 3 19E-06 Page 2

Emission Rate

(lb/MMBtu) 4.30E-093333-Hg-unspiked-R2

Client Project No. Test location Test Run Test Date Time Period

INPUT INPUT INPUT

INPUT INPUT INPUT INPUT INPUT



### INPUT

INPUT

INPUT Vm= Pstatic = Pb= Ps 

### = Pstd = Tm = Ts = Tstd= y= t= Os 

### = As = Kp = K1 

# = K2= K3 = Fd =



### [02] [C02]
[N2] 

### AirNova, Inc. EPA Method 1, 2, 3A, and 30B

- Unspiked Tube (Flows, 02fC02, and Mercury) 

### Spruance Genco, LLC 

### 3333 Unit NO.3 Two 

### 04/19/10 

### 0730-1330

Emission Data
5,340 dcf -0,50 in. H20 30.10 in, Hg 30.06 in. Hg 29.92 in. Hg 532.3 R 651.0 R 527.7 R 1,000



### 360 mm. 10.30 

### ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stack temperature Standard temperature Metercalibration factor Duration of sampling time DiameterofStack 83.32043375 sq. ft. Cross sectional area ofstack 85.49 ft[(lbflbmol)*{inHg)J",5}/[s·R*inH20] 17.637 Rlin.Hg 0.047070 cu.ftlml 0,0026688 in.Hg-cf/ml-R 9755 scf/MMBtu

Instrumental Data

3.83 %-dry

15.06 %-dry
81,11 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Spruance Genco, LLC Test location Test Run Project No. 3333

Calculations
1)Volume ofgas sampled at standard conditions, Vmstd.

Vmstd =K1'* 

### Y,o Vm * PblTm Vmstd = 5,326 dscf 0_1508 dscm
3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

INPUT Bws= Bws= Based on the M29 sampling train 

### 0.1191 4) Molecularweightofthestack gas on awet basis, Ms. Unit No_ 

### 3 

### Two

Ms = [«44"%C02)

### + (32"'%02) 

### + (28,o%N2» * (1-Bws) 

## 1 + (18'*Bws) Ms 

### = 29.067 Ib/lbmole
5) Average stackgasvelocity,Vs.

INPUT Vs 

### = Vs = Based on the M29 sampling train 42958 fps
6) Average actual stackgasvolumetric nowrate, Qa.

Oa 

### =60 sec/mm '* Vs • As Oa = 214756.75 cfm 6081.91 cmm 7) Average stackgas dry volumetricflowrate, Qstd.
Qstd = Qa * (TstdfTs) * (Ps/Pstd) * (1-Bws) Qstd 

### = 154082.62 dscfm 4363.62 dscmm
8) Mercury concentrations and emission rates

Element Mercury C[M] = M[M] (ug) 

### IVmstd (dscm) C[MJ(lb/dscf) = C[M](ug/dscm) 

### * 1e-06g/ug * 2205e-031b/g" 0.02832 dscm/dscf EIM](lb/hr)

# = C[M] (ug/dscm) '* (2.205E-09) (Ib/ug) 

### * Qstd (dscmm) * 60 (min/hr) E[M]{lb/MMBtu) 

### =C[M](lb/dscf) * Fd • (20.9/20.9-%02) C[M](@ corr. 02) = C[M] (ug/dscm) • [(20.9-corrected %02) 

### I (20.9-actual %02)

## 1 Corrected 02 percentage is: 

### 7 % Sample Mass (ug)

0.0012 Conc (ug/dscm)



### 0008 Conc.@oorr. 02 (ug/dscm)

0.006 Conc. (lb/dscQ 

### 4.97E-13 Emission Rate (lb/hr) 4.59E-06 Page 2

Emission Rate

(lb/MMBtu) 5,93E-093333-Hg·unspiked-R3

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT 

### INPUT

INPUT INPUT INPUT INPUT 

### INPUT



### INPUT

INPUT

INPUT Vm= Pstatic = Pb= Ps 

### = Psld = Tm= Ts = Tstd= y= t= Os = As 

### = Kp 

### = K1 = K2= 

### K3 

### = Fd =

[02[
[C02[
[N2] 

### AirNova, Inc. EPA Method 1, 2, 3A, and 30B

- Unspiked Tube (Flows, 02fC02,and Mercury)
Spruance Genco, LLC 

### 3333 Unit NO.3 

### Three 04/19/10 

### 1449-2049

Emission Data



### 9.596 dd 

### -0.50 in. H20 30.03 in Hg 29.99 in. Hg 29.92 in. Hg 

### 5330 

### R 648.0 

### R 527.7 R 1.000

360 min. 

### 10.30 

### ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stacktemperature Standard temperature Meter calibration factor Duration ofsampling time Diameter of Stack 

### 83.32043375 sq. 

### ft. Cross sectional area ofstack 85.49 ft[(lb/lbmol)*(inHg)]".5}1[s*R*lnH20] 

### 17.637 Rfin.Hg 

### 0.047070 cu.ftlml 

### 0.0026688 in.Hg-d/ml-R 9868 sdfMMBtu

Instrumental Data



### 5.00 %-dry

13.94 %-dry



### 81.06 %·dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations
1) 

### Volume ofgas sampled atstandardconditions, Vmstd.

Vmsld =K1* 

### Y"'Vm" Pb/Tm Vmstd = 9.536 dscf 0.2700 dscm 3) Decimal fraction ofmoisture by

### volume instackgas, Bws.

INPUT Bws = Bws= Based on the M29 sampling train 0.1198
4) 

### Molecularweightofthe stack gason awet basis, Ms. Unit No 

### 3 Three

Ms = [«44"%C02)+ 

### (32*%02) + 

### (28*%N2» ., (1-Bws)

## J+**(18~Bws)** 

### Ms = 28941 Ib/lbmole
5) 

### Average stackgas velocity, Vs.

INPUT Vs 

### = Vs = 

### Based on the M29 sampling train 39.835 fps 6) Average actual stackgasvolumetricf1owrate, Qa.
Oa = 

### 60 sec/min * 

### Vs

..As Oa = 

### 199144.17 cfm 5639.76 cmm 7) Average stackgasdryvolumetricf1owrate, Qstd.
Qstd 

### =- Oa" (TstdlTs)" (Ps/Pstd)" (1-Bws) Ostd 

### =- 14309444 dscfm 4052.43 dscmm 8) Mercury concentrations andemission rates

Element Mercury C[M] = M[M] (ug) I

### Vmstd (dscm) C[M](Ib/dscf) 

### =C[MJ(ug/dscm) " 1e-06g/ug'" 2.205e-03Ib/g" 0.02832 dscm/dscf E[M](lb/hr) = C[M] (ug/dscm) * (2.205E-09) (Ib/ug) "Qstd (dscmm)" 60 (min/hr) E[M](lb/MMBtu) = C[M](Ib/dscf)

... Fd '" (20.9/20.9-%02) 

### C[M](@ carr. 02) 

### =C[M] (ug/dscm)

... [(20.9-corrected %02) 

### 1(20.9-actual %02) 1 Corrected 02 percentage is: 7 

### % Sample Mass (ug)

0.0013 Conc. (ug/dscm)

0.005 Conc.@corr. 02 

### (ug/dscm)

0.004 Conc. Clb/dscO 

### 301E-13 Emission Rate (Ib/hr) 2.58E-06 Page 2

Emission Rate

(lb/MMBtu) 3.90E-09

### Unit No.4

## Spruance Genco, LLC Richmond, Virginia Project No, 3333 April 20, 2010 Unit No.4 Run No.1 Coal Analysisfor F Factor Calculation

F FACTOR CALCULATION

INPUT 

### %H

# = 5.00 Hydrogen Content 

### (%) INPUT 

### %c= 

## 74.72 Carbon Content 

### (%) INPUT 

### %N

# = 1.58 Nitrogen Content 

### (%) INPUT 

### %0= 

## 6.29 Oxygen Content 

### (%) INPUT % 

## s= 0.92 SulfurContent 

### (%) INPUT GCV= 

## 13335 Gross CalorificValue (Btu/lb)

Fd 

### = 10"6'"[(3.64*%H) 

### + (1.53"'%C) 

### + (0.57*%5) 

### + (O.14*%N)

- 

### (0.46"%02)]1 GCV 

### Fd

# = 9777 scfJMMBtu

## Spruance Genco, LLC Richmond, Virginia Project No. 3333 April 20, 2010 Unit No.4 Run No.2 Coal Analysisfor F Factor Calculation

F FACTOR CALCULATION

INPUT 

### %H= 

## 4.89 Hydrogen Content 

### (%) INPUT 

### %c= 

## 73.94 Carbon Content (%) INPUT 

### %N= 

## 1.55 Nitrogen Content 

### (%) INPUT 

### %0= 

## 5.38 Oxygen Content (%) INPUT 

### %s= 

## 0.93 Sulfur Content 

### (%) INPUT GCV= 

## 13024 Gross CalorificValue (Btu/rb)



### Fd = 10'6' [(3.64·%H) 

### + (1.53'%C) 

### + (0.57'%S) 

### + (0.14'%N)

- 

### (0.46'%02)]1 GCV 

### Fd

# = 9920 scf/MMBtu

## Spruance Genco, LLC Richmond, Virginia Project No. 3333 April 21, 2010 Unit No.4 Run No.3 Coal Analysisfor F Factor Calculation

F FACTOR CALCULATION

INPUT % 

### H= 

## 4.90 Hydrogen Content (%) INPUT 

### %C= 

## 73.91 Carbon Content (%) INPUT % 

### N= 

## 1.51 Nitrogen Content (%) INPUT 

### %0= 

## 6.71 Oxygen Content (%) INPUT 

### %8= 

## 0.85 Sulfur Content (%) INPUT GCV= 

## 13243 Gross CalorificValue (Btu/lb)

Fd = 10'6 ' [(364'%H) + (1.53'%C) + (0.57'%S) + (0 14'%N)

- (0.46"%02)) 

### I GCV 

### Fd = 

### 9705 scf/MMBtuM7E

Client 

### ProjectNo. TestLocation TestDate 

### Spruance Genco, lLC 3333 Unit 4 Acid Gases 04/19/10



### Parameter: Oxygen Instrument Span f% 

### 02t 22,08

Actual Calibration 

### Gas Value f% 021: AnalvzerCalibration Response r% 

### 02J: AnalyzerCalibration Errorf% 

### Span).

Zero System Calibration Gas AQ(2srent Init. Sys. Init· 

### Svs. Final,s\::::S:. Final $\:::5.

Stack**~** 

### Cal, Bias Calib, Cal. Bias 

### Run Cone. Response (% soan) Response (% span)



### 1 

### 4.56 0.09 0.18 0.04 

### -0.05 2 

### 4.01 0.04 

### -0_05 0.10 0.23 3 6-43 0.10 0.23 0.06 0_05 4 

### 0.00 0.06 0.05 0.00 -0_23 

### 5 0.00 0.00 -0.23 0.00 -0.23 6 0.00 0.00 -0.23 0.00 -0.23 7 

### 0.00 0.00 -0.23 0,00 -0.23 B 

### 0.00 0.00 -0.23 0.00 -0.23 9 

### 000 

### 0_00 -0.23 0.00 -0_23 10 

### 0.00 0.00 -0.23 0.00 -0.23 11 

### 0.00 0.00 -0,23 0.00 -0.23 12 

### 0.00 0.00 -0.23 0,00 -0.23 

### AirNova, Inc. EPA Method 7E Calculations (Cal. Error, Bias Driftand Bias Adjustment)**Anaf~er** Calib. 

### Gases U{}.sca/f!. 

### zero low 

### mid high**S~s.** Cal. Gas 0,00 N/A 

### 11.90 22.08 

### 11.90 0.05 N/A 

### 11.89 22.07 11.90 0.23 0.00 -0.05 -0,05

Ugscale System Calibration Gas 

### r&.!i.!L Init S)t::S. Init. Sys. Final Sys. Final S):::s. Galib. !l!;JJm1 Drift Calib. Cal. Bias CaNb. Cal. 

### Bias Drift 

### Stack (% span) Response (% span) Response (% span) (% span) Cone.



### -0.23 11.90 0.00 11.99 0-41 0-41 4.50 

### 0.27 11 99 0.41 11.95 0_23 -0.18 3.94 

### -0.18 11_95 0.23 12.00 0.45 0.23 6.35 

### -0.27 12.00 0-45 0,00 -53,89 -54 35 -0.06 

### 0.00 0.00 -53.89 0.00 -53.89 0_00 

### ERR 0.00 0.00 -53.89 0_00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53_89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53_89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERRM7E

Client 

### Project No. 

### TestLocation Test Date Spruance Genco, LLC 

### 3333 Uni14 04/19/10



### Parameter: 

### Carbon Dioxide InstrumentSpan (% C02L' 22.28

Actual Calibration Gas Value (% e021.- AnalvzerCalibration Response t% C02/: AnalvzerCalibration Error(% Spant

Zero Sy:stem Calibration Gas A(,2Qarent Inil. SJ,:'s. Init. 

### S:vs. Final S:':::5. Final Sj!s.

Stack Galib. 

### Cal. Bias. Ca/ib. Cal. 

### Bias Run Cone. Response (% soan) Response (% span)



### 1 15.21 0.00 0.00 0.00 0.00 2 15.19 0.00 0.00 0.00 0.00 

### 3 1281 0.00 0.00 -0.12 -0.54 4 

### 0.00 -0 12 -0.54 0.00 0.00 5 0.00 0.00 0.00 0.00 0.00 6 0.00 0.00 0.00 0.00 0.00 7 0.00 0.00 0.00 0.00 0.00 8 0.00 0.00 0.00 0.00 000 9 

### 0.00 0.00 0.00 0.00 0.00 10 0.00 0.00 0.00 0.00 0.00 11 0.00 0.00 000 0.00 0.00 12 0.00 0.00 0.00 0.00 0.00 

### AirNova, Inc. EPA Method6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

AnalyzerCafib. Gases Upscale 

### zero low mid high S\:::s. Cal. Gas 

### 0.00 N/A 

### 12.38 22.38 12.38 0.00 N/A 12.45 

### 22.34 12.38 0.00 

### 0.00 0.31 -0.18

Urui;cale Sy:stem CalUuation Gas Cafib. !nit. S\:::s. Init. Sl!s. Final**S~** Final SKS. Galib. Actual Drift 

### s&li1L 

### Gat Bias Calib Cal. Bias Drift Stack (% span) Response (% span) Resoonse t% span) t% span) Cone.



### 000 12.45 0.31 12.45 0.31 0.00 15.12 0.00 12.45 0.31 12.45 0.31 0.00 15.10 -0.54 12.45 0.31 12.33 -0.22 -0.54 12.80 054 12.33 -0.22 0.00 -55.57 -55.34 0.12 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 000 -55.57 0.00 -5557 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 000 

### ERR 0.00 0.00 -5557 0.00 -55.57 0.00 

### ERR 000 0.00 -55.57 0.00 -55.57 0.00 

### ERRM7E

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unrt4 04/19/10

Parameter: 

### Carbon Monoxide InstrumentSpan (PPmV

### CO): 935.7

Actual Calibration Gas Value (pomVCO): AnalvzerCalibration Response (pomV

### GOL AnalvzerCalibration Errorr% Span).-

Zero System Calibration Gas AQQarent Inil. St:::s. Inil. Svs. Final $):::8. Final $:':::5.

fiIg<i< Calib. 

### Cat. Bias Calib. 

### Cal. Bias Run 

### Cone. 

### Response (% span) Response (% span)



### 1 202.0 00 0.00 -4.9 -0.52 2 376.0 -4.9 -0.52 0.0 0.00 3 156.0 0.0 0.00 -4.9 -0.52 4 

### 0.0 4.9 

### -0.52 0.0 0.00 

### 5 00 00 0.00 0.0 0.00 6 0.0 0.0 0.00 00 0.00 7 0.0 0.0 0.00 0.0 0.00 8 0.0 0.0 0.00 0.0 0.00 9 

### 0.0 0.0 0.00 0.0 0.00 10 0.0 0.0 0.00 0.0 0.00 11 0.0 0.0 0.00 00 0.00 12 0.0 0.0 0.00 0.0 0.00 

### AirNova, Inc. EPA Method 6C Calculations (Cal. Error, Bias Drift and BiasAdjustment)

Ana1jtZerCalib. Gases UQscale lliQ low mid high St:::s. Cal. Gas 

### 0.0 0.0 486.0 935.7 486.0 

### 00 0.0 474.0 

### 938.0 486.0 0.00 0.00 -1.28 

### 0.25

UJ;!scale System Calibration Gas Calib. Init SI:::,s:. Inii- $1:::8. Fmal S\,,8. Final

### Sk's. Ca/ib. Actual Drift Calib. Cal. Bias Galib. caf.**Bia~** Drift fiIg<i< (% span! Response (% span) Response (% span) f% span) Cone.



### -0.52 488.0 0.21 469.0 -1.82 -2.03 206.6 

### 0.52 469.0 -1.82 474.0 -1.28 0.53 388.1 

### -0.52 474.0 -1.28 474.0 -1.28 0.00 161.6 

### 0.52 474.0 -1.28 00 -51.94 -50.66 5.0 

### 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 000 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 00 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR

### M7E

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit 4 04/19/10

Parameter: 

### Nitrogen Oxides (as N02)

Run



### 2 3 4 

### 5 6 

### 7 B 

### 9 10 11 12 InstrumentSpan (pomV NOxJ: 450.9

Actual Calibration Gas Value (ppmVNOxJ: AnalyzerCalibration Response (ppmVNOxt AnalyzerCalibra/ion Error(% Span):

Zero System Calibration Gas 

### Ar;marent Init. 

### S:vs. Init Sys. Final Sys. Final Sys.**~** Calib. Cal. Bia§.**~** 

### Cal Bias

Conc_ Response f% span) Response f% span)



### 202.0 -1.0 -0.13 -1.0 -0.13 211.0 -1.0 -0.13 -0.2 0.04 175.0 -0.2 0.04 -1.0 -0.13 0.0 -1.0 -0.13 0.0 0.09 0.0 0.0 0.09 0.0 0.09 0.0 0.0 0.09 0.0 009 0.0 0.0 0.09 0.0 0.09 0.0 00 009 00 0.09 0.0 0.0 0.09 00 0.09 0.0 0.0 0.09 0.0 0.09 0.0 0.0 0.09 0.0 0.09 0.0 0.0 0.09 0.0 0.09 

### AirNova, Inc. EPA Method6C Calculations (Cal. Error, Bias Drift and Bias Adjustment)

Anai'Ger

### QaIiQ_ Gases !.lQscale
zero low mid high**S~s.** Cal. 

### Gas 0.0 00 246.8 450,9 

### 246.8 -0.4 

### 0.0 251.0 

### 456.0 246.8 -0.09 

### 0.00 0.93 1.13

Up:scale System Calibration Gas 

### Calib_ Init. Sl!:s. Init. S):::s. Fingl Sys. Fina! Sys. Ga/ib. Actual Drift Calib. Cal, 

### Bias Galib. Cal.**Big~** Drift Stack f% span) Response f% span) Response f% span) f% span) Cone.



### 0.00 246.0 -0.18 251.0 0.93 1 11 200.8 

### 0.18 251.0 0.93 242.0 -1.06 -2.00 211.3 

### -0.18 242.0 -1.06 244.0 -062 0.44 177.9 

### 0.22 244.0 -0.62 0.0 -54.73 -54.11 1.• 0.00 0.0 -54.73 0.0 -54.73 0.00 

### ERR 0.00 0.0 -54.73 00 -54.73 0.00 

### ERR 0.00 0.0 -54.73 0.0 -54.73 0.00 

### ERR 0.00 0.0 -54.73 0.0 -5473 0.00 

### ERR 0.00 0.0 -54.73 0.0 -54.73 0.00 

### ERR 0.00 0.0 -54.73 0.0 -54.73 0.00 

### ERR 0.00 00 -54 73 0.0 -54.73 0.00 

### ERR 0.00 0.0 -54.73 0.0 -54.73 0.00 

### ERR

### M7E

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit4 04/19/10



### Parameter: 

### Sulfur Dioxide Instrument Span (ppmV S02): 8R9

ActualCalibration Gas Value fopmV

### S02): AnalvzerCalibration Response (ppmVS02/: AnalvzerCalibration Error(% Span):

Zero Sy:stem Calibration Gas Ar,marent Init. SJ,:'s. Init. S\l:5. Final SJ,:'s. Final SJ,:'s.

Stack Calib. Cal. Bias Calib. Cal. Bias 

### Run Conc. 

### Response (% spanl Response (% span)



### 1 50.6 -05 -056 -1.0 -1 11 2 48.9 -1.0 -1.11 0.0 0.00 

### 3 36.0 0.0 0.00 0.0 0.00 4 0.0 0.0 0.00 0.0 0.00 5 00 0.0 0.00 0.0 0.00 6 0.0 00 000 0.0 0.00 7 

### 0.0 0.0 0.00 0.0 0.00 5 0.0 0.0 0.00 0.0 0.00 9 

### 0.0 0.0 0.00 0.0 0.00 10 0.0 0.0 0.00 0.0 000 11 0.0 0.0 0.00 0.0 000 12 0.0 0.0 0.00 0.0 0.00 

### AirNova, Inc. EPA Method6C Calculations (Cal. Error, Bias Driftand BiasAdjusbnent)



### Ana1mrGalilJ.. Gases 

### UQscale zero low mid high S)!s. Cal. Gas 

### 0.0 0.0 507 89.9 50.7 

### 0.0 0.0 

### 49.8 89.8 50.7 

### 0.00 0.00 -0.20 -0.02

URscale System Calibration Gas Ca/ib. Init. SJ,:'s. Init. S):,:s. Final S\:,s. FinalS)t::s. Galib. Actual Drift Calib. 

### Cal. Bias Galib. 

### Cal. Bias Drift 

### Slack (% span) Response (% span) Response (% span) (% span) Cone.



### -0.56 50.3 45.00 51.8 1.22 1.67 50.3 1.11 51.8 1.22 52.7 2.22 1.00 47.5 0.00 52.7 2.22 49.3 -1.56 -3.78 35.8 0.00 49.3 -1.56 0.0 -56.40 -54.84 0.0 0.00 0.0 -56.40 0.0 -56.40 0.00 

### ERR 0.00 0.0 -56.40 0.0 -56.40 0.00 

### ERR 0.00 0.0 -56.40 0.0 -56.40 0.00 

### ERR 0.00 0.0 -56.40 0.0 -56.40 0.00 

### ERR 0.00 0.0 -56.40 0.0 -56.40 0.00 

### ERR 0.00 0.0 -56.40 0.0 -56.40 0.00 

### ERR 0.00 0.0 -56.40 00 -56.40 0.00 

### ERR 0.00 0.0 -56.40 0.0 -56.40 0.00 

### ERR3333-7E

Client Project No. Test Location Test Date Spruance Genco, 

### lLC 3333 Unit NO.4

- Non Dioxin/Furan HAPs 04/19110

Parameter: 

### Total Hydrocarbons (as Instrument Span (pomV THCI: 20

Actual Calibration Gas Value (ppm V THC): AnalvzerCalibration Response topmV THC!: AnalvzerCalibration Error(% Cal. Gas Value):

Zero Sy:stem Calibration Gas Al2l2arent Init. Sl::s. Init. Sl::s. Final Sl::s. Final Sl::s.

Stack Calib. Cal. Bias Calib. Cal. Bias 

### Run 

# = Response (% span) Response (% span)



### 1 0.3 00 000 -0.5 -2.50 

### 2 0.2 -0.5 -2.50 

### 0.1 050 3 0.3 0.1 0.50 

### 0.0 0.00 

### 4 

### 00 0.0 0.00 

### 0.0 0.00 

### 5 0.0 0.0 0.00 

### 0.0 0.00 

### 6 0.0 0.0 0.00 

### 00 0.00 7 

### 0.0 00 000 0.0 0.00 

### 8 0.0 0.0 0.00 

### 0.0 0.00 

### 9 0.0 0.0 0.00 

### 0.0 0.00 

### 10 0.0 00 0.00 

### 0.0 0.00 

### 11 0.0 0.0 0.00 

### 0.0 0.00 

### 12 00 0.0 0.00 

### 0.0 0.00 

### AirNova, Inc. EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjusbnent)



### C3HS Ana/'GerCalib. Ga,s:es Upscale zero low mid high Sl::s. Cal. Gas 

### 0.0 4.9 9.1 17A 

### 4.9 0.0 4.8 8.9 17.2 

### 4.8 -DAD -0.95 -1.00

Ug§cale Sy:stem Calibration Gas Calib Init Sl::S Init Sl::S FinalSl::s. FinalSl::S Calib. Actual Drift Gal/b. Gal. Bias Galib. Ga/. Bias Drift Stack (% span) Response (% span) Response (% span) (% span) Conc.

-2.50 

### 4.8 0.00 

### 4.9 0.50 0.50 

### 0.5 3.00 

### 4.9 0.50 

### 4.B 0.00 -0.50 

### OA -0.50 

### 4B 0.00 

### 4.6 -1.00 -1.00 

### 0.3 0.00 

### 4.6 -1.00 

### 0.0 -24.00 -23.00 

### 0.0 0.00 

### 0.0 -24.00 

### 0.0 -24.00 0.00 

### ERR 0.00 

### 0.0 -2400 

### 0.0 -24.00 0.00 

### ERR 0.00 

### 00 -24.00 

### 0.0 -24.00 0.00 

### ERR 0.00 

### 0.0 -24.00 

### 0.0 -24.00 0.00 

### ERR 0.00 

### 0.0 -24.00 

### 0.0 -24.00 0.00 

### ERR 0.00 

### 0.0 -24.00 

### 0.0 -24.00 0.00 

### ERR 0.00 

### 0.0 -24.00 

### 0.0 -24.00 0.00 

### ERR 0.00 

### 0.0 -24.00 

### 0.0 -24.00 0.00 

### ERR

### 3333-HCI-HF-R1



### Client Project No. Test Location Test Run Test Date 

### TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT Vic

# = Vm= Pstatic = 

### Pb

# = Ps

# = Pstd

# = dP

### = dH = 

### Tm= Ts= 

### Tstd= On

# = An = 

### y= 1= 

### Os= As= Cp= Kp= K1 

# = K2= K3

# = Fd

# = CF= CF=

[02] [C02]
[N2[ 

## AirNovs, Inc. EPA Methods 1,2,3A,4,and 26A (Flows, 

### 02/C02, H20,and HCI/HF) 

## Spruance Genco, LLC 

## 3333 Unit No.4 

## One 

## 04/19/10 0923-1235

Emission Data


### 316,6 

### cc 116.777 dcl -0.50 in. H2O 

### 30.10 

### m. Hg 

### 30.06 rn, Hg 

### 29.92 in, Hg 

### 07441 in 

### H20

### A.5

1.361 in. H20 522.5 R 652.3 

### R 527.7 R 

### 0.245 in. 0.000327 sq. ft. 1.02 

### 180 

### min. 10.300 ft. 

### Vol. of H20 collected Dry

### gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area of nozzle orifice Meter calibration factor Duration ofsampling time Diameter of stack 83.323 sq. ft.. Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lbllbmol)'(inHg)]'.S}/[s·R"inH20] Piloltube conslant 

### 17.637 Rhn.Hg 0047070 cu.ftlml 0.0026688 in.Hg-cf/ml-R 

### 9777 scf/MMBtu 9.461 E-08 Ibldscf! ppmVd S.192E-08 Ibldscf! ppmVd



### Instrumental Data

4.5 %-dry 15.12 %-dry

80.38 %-dry constant constant constant Fuel Factor Conversion Factor for HCI Conversion Factor for HF

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions, Vmstd.



### Vmstd =Kl'Y'Vm ' (Pb 

### +dH/13.6) ITm Vmstd

# = 121.416 dscf 

### 3.44 dscm Unit No.4 One



### 2) Volume ofwatervaporcollected at standard conditions, Vw{std). 

### Vw(std) = K2 'Vic Vw(std) = 14.902 scf
3) Decimal fraction of moisture by volume In stack gas, Bws.



### Bws 

### =Vwstd / (Vmstd+Vwstd) Bws= 

### 0.109
4) Molecularweightofthe stack gas on a wet basis, Ms.



### Ms = [((44'%C02) 

### + (32'%02) 

### + (28'%N2))' (I-Bws) I 

### + (18'Bws) Ms= 29.22 Ib/lbmole
5) Average stack gas velocity, Vs.



### Vs = Kp' Cp' (dP)' (Ts/Ps·Ms)'.5 Vs

# = 46.05 fps
6) Average actual stack gas volumetric flowrate, Qa.


### Qa = 

### 60 sec/min""Vs • As Qa

# = 230203.0 cfm 

### 6519.3 cmm 7) Average stack gas dry volumetricflowrate, Qstd.



### Ostd = 

### 0.'(TstdfTs)' (Ps/Pstd)' (I-Bws) Qstd 

### = 166670.1 dscfm 4720.1 dscmm Page 2

### Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

Calculations (cont.)
8) Hydrogen Chloride Concentration and Emissions Unit NO.4 

### One

M[HCI] = 

### M[CI-](mg) • MW[HCI](mg/mmol) 

### 1MW[CI-](mg/mmol) Page 3

C[HCI] 

### = (M[HCI](mg) • 2205E-06(lb/mg) • 21 85(scf'inHgllbmol'R) • K1 • 10'6) 1

### (MW[HCIJ(lbllbmol) • Vmstd(d C[HCI](@corr. 02)

# = C[HCI](ppmV)' [(20 9-corrected 02) 

### 1(20.9-octuol %02)] E[HCI]

# =M[HCI](mg)' Qstd(dscfm)' (2.205E-06)(lb/mg)·60(min/hr) 

### 1Vmstd(dscf) E[HCI] 

### = C[HCI](ppmV)' Fd' CF(HCI)' 

### (20.9/(20.9-%02))



## < M[HCI] 

### = 0.06 

### mg 

## < C[HCI] 

### = 0012 ppmV 

## < C[HCI] 

### = 0.010 ppmV (@ 7.0 % 

### 02) 

## < E[HCI] 

### = 0.0111b/hr 

## < E[HCI] 

### = 1.36E-05 Ib/MMBtu
9) Hydrogen Fluoride Concentration and Emissions
C[HF]

# =M[HF](mg) 

### 1Vmstd(dscm) C[HF]

# =(M[HF](mg) • 2.205E-06(lb/mg) • 21.85(scf·lnHgllbmol·R) • K1 • 10'6) 

### 1(MW[HF](lb/lbmol) • Vmstd(dsc C[HF](@corr 02)

# = C[HF](mg/dscm)' [(20.9-corrected 02) 

### 1(20.9-octuol %02)] E[HF]

# = C[HF](mg/dscm) • Qstd(dscmm) • (2.205E-06)(lb/mg) • 60(min/hr) E[HF]

# = C[HF](ppmV)' Fd' CF(HF)' (20 

### 9/(20 9-%02))
M[HF]

# = C[HF]

# = C[HF]

# = C[HF] 

### = E[HF] = 

### E[HF]

# = 10) Isokinecity, I. 0.600 mg 0.174 mg/dscm 

### 0.210 ppmV 0.178 ppmV (@ 0.109 Ib/hr 

### 1.36E-04Ib/MMBtu 7.0

% 1

# =(100·Ts·(K3·Vlc+(Vm·YlTm)(Pb+dH/13.6)))/(60·t·Ps'Vs·An) 

### % I= 

### 103.0 % 

### 02)

### 3333-HCI-HF-R2



### Client Project No. Test Location 

### Test Run 

### TestDate TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT Vic

# = Vm= Pstatic

# = Pb = 

### Ps

# = Pstd 

### = dP

# = dH

# = Tm= Ts = 

### Tstd= On 

### = An

# = y= t= 

### Ds = 

### As= Cp= 

### Kp

# = K1 

# = K2= 

### K3

# = Fd = 

### CF

# = CF

# =

[02[ [C02[
[N2] 

## AirNova, Inc. EPA Methods 1,2,3A,4,and 26A (Flows, 

### 02/C02, H20,and HCIIHF) 

## Spruance Genco, LLC 

## 3333 Unit No.4 

## Two 04/19/10 

## 1310-1622

Emission Data



### 361 

### cc 117.695 dcf -0.50 in. H20 

### 30.04 in. 

### Hg 

### 30.00 

### in. Hg 

### 29.92 

### in. Hg 

### 0.7418 

### in. H20 11,5

1.402 

### in. H20 537.2 R 650.5 R 527.7 R 

### 0245 in. 0.000327 sq. ft. 1.02 

### 180 min. 10300 ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area ofnozzle orifice Meter calibration factor Duration ofsampling time Diameter ofstack 83.323 sq. 

### ft Cross sectional area ofstack 0,84 Pitot tube coefficient 85.49 ft[(lbllbmol)'(inHg)]A.5]/[s·R'inH20] Pitottube constant 17.637 Rlin.Hg 

### 0.047070 cu,ft/ml 0.0026688 in Hg-cflml-R 

### 9920 scf/MMBtu 9.461E-08 Ib/dscf 

### I ppmVd 5.192E-08 Ib/dscf 

### I ppmVd



### Instrumental Data

3.94 %-dry 15.1 %-dry



### 80.96 %-dry 

### constant constant constant Fuel Factor Conversion Factorfor HCI Conversion Factorfor HF

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations 1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1"" Y

.. Vm '" (Pb + 

### dH/13.6) 

### ITm Vmstd

# = 118.814 dscf 3.36 dscm 

### Unit No.4 Two

2) Volume ofwatervaporcollected atstandard conditions,Vw(std). Vw(std)

# =K2 • Vie Vw(std) = 

### 16.992 scf 

### 3) Decimal fraction of moisture byvolume in stack gas, Bws.

Bws = 

### Vwstd 

### I (Vmstd+Vwstd) Bws = 

### 0.125 

### 4) Molecularweight ofthe stack gas on awet basis, Ms.

Ms = 

### [((44'%C02) + 

### (32'%02) + 

### (2S'%N2))' (1-Bws) 

## I+ 

### (1S'Bws) 

### Ms= 2900 Ib/lbmole 

### 5) Averagestack gasvelocity, Vs.

Vs 

### = Kp' Cp' (dP)' (Ts/Ps'Msl' 5 Vs 

### = 46.06 fps 6) Average actual stack gasvolumetric flowrate, Qa.

Qa 

### = 60 sec/min"" Vs ., As 

### Qa 

### = 230260 5 efm 6521.0 cmm 

### 7) Average stackgas dryvolumetricflowrate, Qstd.
Qstd 

### =Qa • (TstdlTs) • (Ps/Pstd) , (1-Bws) Qstd 

### = 163888.1 dscfm 4641.3 dscmm 

### Page 2

### Client Spruance Genco, 

### LLC Project No. 

### 3333 Test Location Test Run

Calculations (cont.)


### 8) Hydrogen Chloride Concentration and Emissions 

### Umt No, 

### 4 Two



### M[HCI[

# =M[CI-[(mg) , MW[HCI](mglmmol) 1MW[CI-](mglmmol) Page 3



### C[HCI]

# =(M[HCI](mg) , 2.205E-06(lblmg) , 21.85(scf"inHgllbmol'R) , K1 • 10'6) 1(MW[HCI](lbllbmol) 'Vmstd(d C[HCI](@corr 02)

# = C[HCI](ppmV)' [(20.9-corrected 02) 1(20.9-actual %02)] E[HCI] 

### = M[HCI](mg)' Qstd(dscfm)' (2 205E-06)(lblmg)'60(mlnlhr) 1Vmstd(dscf) E[HCI]

# = C[HCI](ppmV)' Fd'CF(HCI)' (20.91(20.9-%02))

<: 

### M[HCI] 

### = 0.06 mg 

## < C[HCI] 

### = 0.012 ppmV 

## < C[HCI] 

### = 0.010 ppmV (@ 7.0 %02) 

## < E[HCI] 

### = 0.011 Ib/hr 

## < E[HCI] 

### = 1.36E-05 IblMMBtu


### 9) Hydrogen Fluoride Concentration and Emissions


### C[HF] 

### = M[HF](mg) IVmstd(dscm) C[HF]

# =(M[HF](mg)'2.205E-06(lblmg)'21 85(scf"inHgllbmol'R)' K1 • 10'6) 1(MW[HF](Ibllbmol)'Vmstd(dsc C[HF](@corr. 02)

# = C[HF](mgldscm)' [(20.9-corrected 02) 1(20.9-actual %02)] E[HF] = 

### C[HF](mgldscm) • Qstd(dscmm) • (2.205E-06)(lblmg) , 60(minlhr) E[HF] 

### = C[HF](ppmV)' Fd' CF(HF)' (20.91(20.9-%02))
M[HF] = 

### C[HF]

# = C[HF]

# = C[HF] 

### = E[HF] = 

### E[HF]

# =
10) Isokinecity, I. 

### 0.630 mg 0.1 B7 

### mg/dscm 

### 0.225 ppmV 0.185 ppmV (@ 0.1151b/hr 

### 1.43E-04 IblMMBtu 7.0

% I = 

### (100'Ts·(K3·Vlc+(Vm·YlTm)(Pb+dHI13.6)))1(60·t·Ps·Vs·An) 

### % I = 102.5 

### %02)

### 3333-HCI-HF-R3



### Client Project No. Test Location Test Run Test Date Test Time



### INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT Vlc= 

### Vm= PStatlC

# = Pb = Ps 

### = Pstd

# = dP= dH 

### = Tm= Ts= Tstd= Dn

# = An

# = y= 

### t

# = Ds= As= Cp 

# = Kp= K1 

### = K2= K3= Fd = 

### CF

# = CF

# =

[02[ [C02[
[N2) 

## AirNova, Inc. EPA Methods 1,2,3A,4,and 26A [Flows, 

### 02/C02, H20,and HCIIHF) 

### Spruance Genco, LLC 

## 3333 Unit No.4 Three 

## 04/19/10 1658-2017

Emission Data



### 307.7 

### cc 104.628 del 

### -0.50 in. 

### H2O 

### 29.98 in. 

### Hg 

### 29.94 in. Hg 

### 29.92 

### in. Hg 

### 0.6835 in. H20 1\ 

### 5

1 146 in. H20 537.6 R 649.4 R 527.7 R 

### 0.245 in. 0.000327 sq. ft. 1.02 

### 180 min. 

### 10.300 ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rtdelta P Average draftgauge reading Average metertemperature Average stacktemperature Standard temperature Nozzle diameter Area of nozzle orifice 

### Metercalibration factor Duration ofsampling time Diameterofstack 

### 83.323 sq. ft 

### Cross sectional area ofstack 

### 0.84 Pltottube coefficient 

### 85.49 ft[(lb/lbmol)*(inHg)]1I.5}/[s*R*inH20] Pitot tube constant 17.637 R/in.Hg 0.047070 eu.ftlml 0.0026688 in.Hg-el/ml-R 9705 scf/MMBtu 9461E-08 Ib/dsel

### I ppmVd 5.192E-08 Ib/dscf

### I ppmVd

Instrumental Data

6.35 %-dry 12.8 %-dry

80.85 %-dry constant constant constant Fuel Factor Conversion Factorfor HCI Conversion Factorfor HF

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentratIon

### Client Project No. 

### Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) Volume ofgas sampled atstandard conditions, Vmstd.



### Vmstd =K1'Y'Vm' (Pb + 

### dH/13.6) ITm Vmstd

# = 105.265 dscf 2.98 dscm Unit No 4 Three

2) Volume ofwater vaporcollected at standard conditions, Vw(std).


### Vw(std) = K2 'Vic Vw(std) = 14.483 scI
3) Decimal fraction of moisture

### by volume in stack gas, Bws.



### Bws 

### =Vwstd / (Vmstd+Vwstd) Bws= 0121
4) Molecularweightofthe stack gas on a wet basis, Ms.



### Ms = [((44'%C02) + (32'%02) + (28'%N2))' (1-Bws) 

## I+ (18'Bws) Ms

# = 28.81 Ib/lbmole
5)Average stackgas velocity, Vs.



### Vs = Kp , Cp , (dP) , (Ts/Ps'Ms)A5 Vs = 

### 42.58 fps
6) Average actual stackgas volumetricflowrate, Qa.



### Qa

# = 60 sec/min"Vs

.. As Qa

# = 212888.5 cfm 6029.0 cmm 7) Average stack gas dry volumetricflowrate, Qstd.


### Qstd = Qa ' (TstdlTs) , (Ps/Pstd) , (1-Bws) Qstd

# = 152195.2 dscfm 4310.2 dscmm Page 2

### Client Spruance Genco, LLC 

### Project No. 3333 Test location Test Run

Calculations (cont.)
8) Hydrogen Chloride Concentration and Emissions Unit No.4 Three

M[HCI] = M[CI-](mg) • MW[HCI](mg/mmol) 

### 1MW[CI-](mg/mmol) 

### Page 3

C[HCI] = (M[HCI](mg) • 2 205E-06(lb/mg) • 21.85(scf'lnHg/lbmol'R) • K1 • 10'6) 1(MW[HCI](lbllbmol) • Vmstd(d C[HCI](@corr 02) = C[HCI](ppmV)' [(20.9-corrected 02) 1(20.9-actual %02)] E[HCI] = M[HCI](mg) • Qstd(dscfm) • (2.205E-06)(lb/mg) • 60(min/hr) 1Vmstd(dscD E[HCI] = C[HCI](ppmV)' Fd' CF(HCI)' 

### (20.9/(20.9-%02))
M[HCI]= 0.30 mg C[HCI] = 0.066 ppmV C[HCI]

# = 0.063 ppmV (@ 

### 7.0 

### %02) E[HCI] = 0.057 Ib/hr E[HCI] = 8.76E-05 Ib/MMBtu


### 9) Hydrogen Fluoride Concentration and Emissions
C[HF] = M[HF](mg) IVmstd(dscm) C[HF] = (M[HF](mg) , 2.205E-06(lb/mg) • 21.85(scf'inHgllbmol·R) • K1 • 10'6) 1(MW[HF](lbllbmol) • Vmstd(dsc C[HF](@corr. 02) = C[HF](mg/dscm)' [(209-corrected 02) 

### 1(20.9-actual %02)] E[HF] = C[HF](mg/dscm)'Qstd(dscmm)' (2.205E-06)(lb/mg)·60(min/hr) E[HF] = C[HF](ppmV)' Fd' CF(HF)' 

### (20.9/(20 9-%02))
M[HF] = C[HF] = C[HF] = C[HF] = E[HF] = E[HF] = 

### 10) Isokinecity, I. 0.590 mg 

### 0.198 mgJdscm 0.238 ppmV 0.227 ppmV ( @ 

### 0.1131bJhr 1.72E-04Ib/MMBtu 7.0

% 1= (100"Ts·(K3'Vlc+(Vm'YlTm)(Pb+dH/13.6»)/(60't'Ps'Vs·An) 

### % I = 

### 978 

### %02)Client Project No. Test Location Fuel Type Test Run Test Date Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT INPUT

INPUT INPUT INPUT INPUT INPUT Vlc= Vm= PstatlC = Pb 

### = Ps 

### = Pstd = 

### dP 

### = dH = Tm= Ts= Tstd= y= 

### 1= Dn

# = An = Ds 

### = As = Cp 

### = Kp

# = K1 = K2

# = K3 = Fd 

### =

[O2[ [C02[ [N2] [CO[ [THC[ [CH4[ [NOx[ [S02[ 

### AirNova, Inc. Page 1 of4 EPA Methods 

### 1, 2, 3A, 4, 6, 7E, 

### 10, 18and 25A (Flows. 

### 021C02, 

### H20, 502, NOx, CO and NMHC)

Spruance Genco. LLC 

### 3333 Unit No, 4 Coal One 

### 04/19/10 

### 0923-1235

316.6 ccEmission Data

116.777 dcf 

### -0.50 in. H20 

### 30.10 

### m. Hg 

### 30.06 in. Hg 29.92 in. Hg 

### 0.7441 in, H20 

### ".5 1.36 in. H20 522.5 

### R 652.3 R 527.7 

### R

1.02

180 min. 

### 0.245 m. 

### 0,000327 sq. 

### ft. 

### 10.300 ft, 

### 83.3231 sq. 

### ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Metercalibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameter ofstack Cross sectional area ofstack 

### 0.84 Pitot tube coefficient 85.49 ft[(lbllbmol)*(inHg)]1I.5}/[s·R·inH20] 

### 17.637 R/m.Hg constant 

### 0,047070 cu.ftlml constant Pitottube constant 

### 0.0026688 in.Hg-cf/ml-R constant 

### 9777 scf/MMBtu From EPA Reference Method 

### 19

Instrumental Data 

### 4.50 %-dry 15,12 %-dry 

### 80.38 %-dry 

### 206.6 ppmV·dry



### 0.5 ppmV-wet 

### 0.0 ppmV-dry 

### 200.8 ppmV-dry



### 50.3 ppmV-dry Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Carbon Monoxide concentration Total Hydrocarbon concentration Methane Concentration by GC-FID Nitrogen Oxides concentration Sulfur Dioxide concentrationClient Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations 1)Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1*

### Y'* Vm * (Pb + 

### dH/13 6) / Tm Vmstd 

### = 121.416 dscf 3.439 dscm Unit No, 4 One

2) Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std) = K2 • Vic Vw(std) 

### = 14,902 scf
3) Decimal fraction ofmoisture by volume in stackgas, Bws.

Bws

# = Vwstd/ (Vmstd+Vwstd) Bws= 0,1093 4) Molecularweightofthestack gas on a wet basis, Ms.

Ms = ( ({44*%C02) + (32*%02) + (28*%N2)) * (1-Bws) I + (18*Bws) Ms

# = 29.222 Ib/lbmole 5) Average stackgas velocity, Vs.

Vs c Kp· Cp 

### * (dP) 

### * (Ts/Ps*Ms)".5 Vs 

### = 46,046 fps
6) Average actual stack gas volumetric f1owrate, Qa.

Oa

# = 60 sec/min·Vs • As Qa = 230203.0 cfm 6519.3 cmm 7) Average stack gas dryvolumetric f1owrate, Qstd.
Qstd =: Qa <; (TstdfTs) '* (PslPstd) '* (1-Bws) Qstd

# = 166670.1 dscfm 47201 dscmm Page 2 of4Client Project No. 

### Spruance Genco, LLC 3333 Test Location Test Run
Calculations (cont.)

### Unit No 4 One Page 3 of4

8) Total Hydrocarbon concentrations and emissions

INPUT 

### C[THC] dry basis

# = CITHC] weU{1-Bws) C[VOC] dry basis = C[THC]

- C[CH4] 

### Corr_ C[CH4] = {{20.9-02% corr. value)/(20.9-actuaJ avg. 02% value))*VOC value E[VOC] = (C[VOC]*Mol Wt[VOC equivalenW60(min/hr)"*Qstd{dscfm))/{Molar Vol. air*10"S) E[VOC Jb/MMBtu] 

### =Cd

.. Fd**~** 

### (20.9/{20.9-actual 02%)) C[THC] 

# = 0.5 ppmVw C[THC] = 0.6 ppmVd C[CH4] = 0.0 ppmVd C[VOC] 

### = 0.6 ppmVd 

### C[VOC] 

### = 0.5 ppmVd corrected to 7 

### % 02 Mol. WI. [THC]= 44.096 Ib/lb-mole Propane Molarvol air= 385 scf/lb-mole 

### @ 68 def F E]VOC[ 

### = 0 64 Iblh, 

### Conv Factor. E[VOC] = 

### 4.134E-08 convert ppmV to Ib/scfTHC as CH4 2.89E-04 Ib/MMBtu 9) Nitrogen Oxides concentrations and emissions


### Corr. C[NOx] = «20.9-02%carr value)/{20.9-actual avg. 02% value))*Avg. raw NOx value E[NOx] =**(C[NOxl~Mol** 

### Wt[NOx]*SO{min/hr)*Qstd(dscfm))/(Molar Vol. air*10"6) E{NOx Ib/MMBtu]

# = Cd" Fd 

### * (20.9/(20.9-actual 02%)) C[NOx] = 200.8 ppmVd C[NOx] = 170.2 ppmVd corrected to 7 % 02 Mol. Wt. [NOx]= 46.01 Ib/lb-mole Molarvol air= E[NOx] = 

### Conv Factor. E[NOx]

# = 385 scf/lb-mole 

### @ 239.97 Ib/hr 

### 68
1.194E-07 convert ppmV to Ib/scf NOx 0.299 Ib/MMBtu def FClient Project No. Spruance Genco, LLC 3333 Test Location Test Run Unit No.4 One Page 4 of4

10) Carbon Monoxide concentrations and emissions

Carr. qCO] = «20.9-02% carr. value)/(20.9-actual avg. 02% value))*Avg. raw CO value E[CO Ib/hr] = (qCO]*Mol Wt[CO]*60(min/hrrQstd(dscfm))/(Molar Vol. alr*10"6) E[CO Ib/MMBtu] = Cd ,. Fd**~** (20.9/(20.9·actual 02%» 

### qCO]

# = 206.6 ppmVd qCO] = 175,1 ppmVd corrected to 7 

### %02 Mol Wt. [CO]= 28.01 Ib/lb-mole Molar vol air= 385 scf/lb-mole 

### @ 68 def F E[CO] = 150.31 Ib/hr Conv Factor. 7.235E-08 convert ppmV to Ib/scf CO E[CO] = 0.186 Ib/MMBtu
11) Sulfur Dioxide concentrations and emissions

Carr C[S02] = «20.9-02%carr. value)/(20 9-actual avg. 02% value))*Avg. raw S02 value E(lb/MMBtu) = Cd(lb/scf)**~** Fd(scf/MMBtu) * [20.91 (20.9-% 02)] E[S02 Ib/hr] = (C[S02l*Mol Wt[S02]*60(min/hrtQstd(dscfm))/(MolarVol air*10"6) qS02] = 50.3 ppmV (dry) Actual Conc. C[S02] = 42,6 ppmVd corrected to 7 % 02 Mol Wt. [S02]= 64.06 Ib/lb-mole Molar vol air= Conv Factor. 

### E[S02] 

### = E[S02] 

### = 385 scf/lb-mole 

### @ 68 1.66E-07 convert ppmV to Ib/scf 502 0.104 Ib/MMBtu 83,70 Ib/hr defFClient Project No. Test Location Fuel Type Test Run Test Date Time Period

INPUT INPUT INPUT INPUT Vic = Vm= Pstatic = Pb 

### = Ps

# = Pstd = dP 

### = dH = Tm= Ts = INPUT Tstd= INPUT y= INPUT t = INPUT Dn = An = INPUT Ds 

### = As

# = INPUT

INPUT

INPUT INPUT

INPUT INPUT INPUT INPUT INPUT Cp

# = Kp = K1 

# = K2 

### = K3 = Fd

# =

[02J [CO2] [N2J [COJ [THC] [CH4] [NOxJ [S02] 

### AirNova, Jnc. EPA Methods 

### 1, 2, 3A, 4, 6, 7E, 10, 18 and 

### 25A (Flows, 

### 02/C02, H20, S02, NOx, CO and NMHC)

Spruance Genco, LLC 3333 Unit No.4 Coal 

## Two 04/19/10 1310-1622 Emission Data

361 cc 117.695 dcf 

### -0.50 in. H2O 

### 30.04 in. Hg 30.00 in. Hg 29.92 in. Hg 0.7418 

### m. H20 A.5 1.40 in. H2O 537.2 

### R 650.5 

### R 527.7 

### R

102

180 min. 0.245 in. 0.000327 sq ft 10.300 ft. 833231 sq. ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stacktemperature Standard temperature Meter calibration factor Duration of sampling time Nozzle diameter Nozzle area Diameter of stack Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[(lb/lbmol)*(inHg)]A**5}/[s~R*inH201** 17.637 R/in.Hg constant 0.047070 cU.ft!ml 0.0026688 in.Hg-cf/ml-R 9920 scf/MMBtu

Instrumental Data 3.94 %-dry 15.10 %-dry 80.96 %-dry 388.1 ppmV-dry

0.4 ppmV-wet constant Pltot tube constant constant From EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Carbon Monoxide concentration Total Hydrocarbon concentration Page 1 of4

0.0 ppmV-dry Methane Concentration by GC-FID 211.3 ppmV-dry Nitrogen Oxides concentration

47.5 ppmV-dry Sulfur DiOXide concentrationClient Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations 1) Volume ofgassampled atstandard conditions, Vmstd.

Vmstd =K1· Y· Vm· (Pb + dH/13.6) / Tm Vmstd= 118.814 dscf 3.365 dscm Unit No, 4 Two

2) Volumeofwatervaporcollected atstandard conditions, Vw(std).
Vw{std) = K2 '" Vic Vw(std) = 16.992 scf
3) Decimal fraction of moisture byvolume in stackgas, Bws.

Bws = Vwstd I (Vmstd+Vwstd) Bws= 0.1251
4) Molecularweightofthestack gas on a wet basis, Ms.

Ms =

# r((44*%C02) + (32*%02) + (28*%N2»'" (1-Bws)

## J+ (18*Bws) Ms= 29.000 Ib/lbmole
5) Average stack gas velocity, Vs.

Vs = Kp '* Cp * (dP);O (Ts/Ps"'Ms)".5 Vs = 46,058 fps
6) Average actual stack gas volumetric flowrate, Qa.

Oa = 60 sec/min '* Vs

... As Oa = 230260.5 cfm 65210 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Oa· (TstdfTs)· (Ps/Pstd)'" (1-Bws) Ostd = 163888.1 dscfm 4641.3 dscmm Page 2 of4Client Project No. Spruance Genco, LLC 3333 Test location Test Run
Calculations (cont.)Unit No.4 

### Two Page 3 of4

8) Total Hydrocarbon concentrations and emissions

INPUT C[THCJ 

### dry basis = C[THCJ weU(1-Bws) C[VOC] dey basis

# = C[THC]- C[CH4] Carr C[CH4]

# =«20.9-02% carr. varue)/(20 9-actual avg. 02% value))*VOC value E[VOCJ = (C[VOCl"Mol Wt[VOC equivalent]*60(min/hr)*Qstd(dscfm))/(Morar Vol. air*10"6) E[VOC Ib/MMBtu] = Cd" Fd * (20 9/(20.9-aclual 02%)) C]THC] 

# = 0.4 ppmVw C[THC] = 0.5 ppmVd C]CH4] 

# = 0.0 ppmVd C]VOC]

# = 0.5 ppmVd C[VOC] 

### = 0.4 ppmVd corrected to Mol. Wt. [THC]= 44.096 Ib/lb-mole 385 scf/lb-mole 

### @ 0.51 Ib/hr 

### 7 Propane 

### 68 Molar vol air= E]VOG] = Conv Factor E[VOG] 

### = 4.134E-08 convert ppmVto lb/scfTHC as CH4 2.31 E-04 Ib/MMBtu %02
def F

9) Nitrogen Oxides concentrations and emissions
Carr. C[NOx]

# =«20.9-02%carr. value)/(20.9-actual avg. 02% value)}"Avg. raw NOx value E[NOx] = (C[NOxl"Mol**Wt[NOx]~60(min/hr)*Qstd(dscfm))/(Molar**Vol air*10"6) E[NOx Ib/MMBtu] = Cd" Fd" (20.9/(20.9-actual 02%)) C[NOx] 

### = 211.3 ppmVd C[NOx] = 173.2 ppmVd corrected to 7 % 02 Mol. WI. [NOx]= 46.01 Ib/lb-mole Molarvol air= 385 scfllb-mole 

### @ 68 def F E[NOx]

# = 248.31 Ib/hr Conv Factor. E[NOx] = 1.194E-07 convert ppmV to Ib/sctNOx 

### 0.308 Ib/MMBtuClient Project No. 8pruance Genco, LLC 3333 Test Location Test Run Unit No.4 

### Two Page 4 of4

10) Carbon Monoxideconcentrationsand emissions
Carr. qCO] 

### = «20.9-02%corr. value)/(20.9-actual avg. 02% value))*Avg. 

### raw CO value E[CO Ib/hr] = (C[COl"Mol Wt[CO]*60(min/hr)"Qstd(dscfm»)/(MolarVol. alr"10116) E[CO Ib/MMBtu] = Cd· Fd· (20.9/(20.9-actual 02%» CleO] = 388.1 ppmVd C[CO] = 318.1 ppmVd corrected to 7 % 02 Mol. WI. [CO]= 28.01 Ib/lb-mole Molarvol air= 385 scf/lb-mole 

### @ 68 def F ErCO] = 277.65 Ib/hr Conv Factor. 7.235E-08 convert ppmV to Ib/scf CO E[CO] = 0.343 Ib/MMBtu
11) Sulfur Dioxide concentrations and emissions

Carr. C[802]

# =«20.9-02%corr. value)/(20 9-actual avg. 02% value»*Avg. raw 802value E(lb/MMBtu) = Cd(lb/scf) • Fd(scf/MMBtu) * [20.91 (20.9-% 02)] E[S02 Ib/hr] = (C[802]*Mol**Wt[S02]~60(min/hr)·Qstd(dscfm))/(Molar**Vol. air*10116) C[S02]

### = 47.5 ppmV (dry) Actual Conc. C[S02] = 38.9 ppmVd corrected to 7 % 02 Mol. Wt. [802]= 64.06 Ib/lb-mole Molarvol air= Conv Factor. 

### E[802]

# = E[802] = 385 scfllb-mole 

### @ 68 1.66E-07 convert ppmV to Ib/scf S02 0.096 Ib/MMBtu 77.72 Ib/hr def FClient Project No. Test Location Fuel Type Test Run Test Date Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT INPUT

INPUT INPUT INPUT INPUT INPUT Vic = Vm= Pstatic

# = Pb = Ps = Pstd = dP = dH 

### = Tm = Ts

# = Tstd= 

### y= t

# = Dn 

### = An = Ds

# = As = Cp = Kp

# = K1 = K2

# = K3 = Fd 

### =

[02[ [C02[ [N2[ [COl [THC[ [CH4[ [NOx[ [802] 

### AirNova, Inc. Page 1 of4 EPA Methods 

### 1, 2, 

### 3A,4, 6, 7E, 

### 10, 18 and 25A (Flows, 

### 02/C02, H20, S02, NOx, CO and NMHC)

Spruance Genco, LLC 3333 Unit No_ 4 Coal Three 04/19/10 1658-2017 Emission Data

307.7 cc 104.628 dcf -0.50 in. H20 29.98 

### rn. Hg 29.94 in. Hg 29.92 in. Hg 0.6835 in. H20 ".5 1.15 in. H2O 5376 

### R 649.4 

### R 527.7 

### R

1.02

180 min. 0.245 in. 0.000327 sq. ft 10.300 ft. 83.3231 sq. ft Vol of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta 

### P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameter of stack Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)*(inHg)]II.5}/[s*R*inH20] 17.637 R/in.Hg constant 0.047070 cu.ftlml constant Pitot tube constant 0.0026688 in Hg-cf/ml-R constant 9705 scf/MMBtu From EPA Reference Method 19

Instrumental Data 6.35 %-dry Oxygen concentration 1280 %-dry Carbon Dioxide concentration 80.85 %-dry Nitrogen concentration

161.6 ppmV-dry Carbon Monoxide concentratIon

0.3 ppmV-wet Total Hydrocarbon concentration 0.0 ppmV-dry Methane Concentration by GC-FID 177.9 ppmV-dry Nitrogen Oxides concentration

35.8 ppmV·dry Sulfur Dioxide concentrationClient Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1)Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1* Y * Vm * (Pb + dH/13.6) ITm Vmstd = 105.265 dscf 2.981 dsem Unit No.4 Three

2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2

.. Vic Vw(std) = 14.483 sef
3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws

# = Vwstd I (Vmstd+Vwstd) Bws

# = 0.1209
4) Molecularweightofthestack gas on a wet basis, Ms.

Ms = [((44*%C02) 

### + (32"%02) 

### + (28*%N2»**~** (1·Bws) 

## 1 + (18*Bws) Ms= 28.814 Ib/lbmole
5) Average stack gasvelocity, Vs.

Vs

# =Kp * Cp" (dP)**~** (Ts/Ps*Ms)".5 Vs = 42.583 fps
6) Average actual stackgas volumetric flowrate, Qa.

Oa = 60 sec/min"Vs *As Oa = 212888.5 cfm 6029.0 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa * (TstdlTs)

.. (Ps/Pstd)

.. (1-Bws) Qstd = 152195 2 dscfm 43102 dscmm Page 2 of4Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations (cont.)Unit No.4 Three Page 3 of4

8) Total Hydrocarbon concentrations and emissions

INPUT C[THC] dry basis = C[THC] weU(1-Bws) C[VOC] dry basis = C{THC]

- C[CH4] Corr. C[CH4] = «20.9-02% corr. value)/(20 9-actual avg. 02%value))*VOC value E[VOC] = (C[VOC]*Mol Wt[VOC equivalenW60(min/hr)*Qstd(dscfm))/(Molar Vol. air*10"6) E[VOC Ib/MMBtu] = Cd'" Fd'" (20.9/(20.9-actual 02%)) C{THC] = 0.3 ppmVw 

### C[THC] 

# = 0.3 ppmVd C[CH4] 

# = 0.0 ppmVd C[VOC] = 

### 0.3 ppmVd C[VOC] = 0.3 ppmVd corrected to 7 

### % 02 Mol. Wt. [THC]= 44.096 Ib/lb-mole Propane Molarvol air= 385 scf/lb-mole 

### @ 68 def F E[VOC] = 0.36 Ib/hr Conv Factor 

### E[VOC]

# = 4.134E-08 convert ppmVto Ib/scfTHC as CH4 1.97E-04 Ib/MMBtu 9) Nitrogen Oxides concentrations and emissions
Corr. C[NOx] = «209-02% corr. value)/(20.9-actual avg. 02% value))*Avg. raw NOxvalue E[NOx] =**(C[NOxl~Mol** Wt[NOx]*60(min/hr)"Qstd(dscfm))/(Molar Vol. air"10"6) E[NOx Ib/MMBtu] = Cd " Fd " (20.9/(20.9-actual 02%)) C{NOx] = 177.9 ppmVd C{NOx] = 170.0 ppmVd corrected to 7 % 02 Mol Wt. [NOx]= 46.01 Ib/lb-moJe Molarvol air= 385 scf/lb-mole 

### @ 68 def F E[NOx] = 194.14 Ib/hr Conv Factor 1.194E-07 convert ppmV to Ib/scf NOx E[NOx] = 0.296 Ib/MMBtuClient Project No. 

### Spruance Genco, LLC 3333 Test location Test Run 

### Umt No, 4 Three Page 4 of4

10) Carbon Monoxide concentrations and emissions


### Corr. C[CO] = «20.9-02%corr. value)/(20 9-actual avg. 02% value))"'Avg. raw CO value E[CO Ib/hr] = (C[CO]*Mol WI[CO]*60(min/hr)*Qstd(dscfm))/(Molar Vol. alr*10"6) E[CO Ib/MMBlu] = Cd**~** 

### Fd**~** 

### (20.9/(20.9-actual 02%» 

### qCO] = 

### 161.6 ppmVd 

### C[eO] = 154.4 ppmVd corrected to 7 % 02 Mol. WI. (CO]= 2801 Ibllb-mole Molarvol air= 

### E[CO[ 

### = Conv Factor. 

### E[CO[

# = 385 scfllb-mole @ 107.36 Ib/hr 7.235E-08 convert ppmVto Ib/scf CO 0.163 Ib/MMBtu
11) Sulfur Dioxide concentrations and emissions 

### 68 def F

Corr. C[S02] = «20.9-02%corr. value)/(20.9-aclual avg. 02% value»*Avg. raw S02 value E(lb/MMBlu) = Cd(lb/scf) * Fd(scf/MMBtu)**~** 

### [20.91 (20_9-% 02)] E[S02 Ib/hr]

# = (C[S02]*Mol Wt[S02]*60(min/hr)*Qsld(dscfm))/(Molar Vol.**air~1**

### 0"6) qS02] = 35.8 ppmV (dry) Actual Conc. C[S021 = 34.2 ppmVd corrected 10 7 % 02 Mol. WI. [502]= 64.06 Ib/lb-mole Molarvol alr= Conv Factor. E[S02[

# = E[S02] = 

### 385 scf/lb-mole@ 68 1.66E-07 convert ppmV 10 Jb/scf502 0.083 Ib/MMBtu 54.40 Ib/hr def F

### 3333-HCN-R1

Client Project 

### No. Test Location Test Run Test Date TestTime



### INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT VIc

# = Vm= Pstatic

# = Pb

# = Ps

# = Pstd

# = dP 

### = dH 

# = Tm= Ts

# = Tstd= 

### On = An

# = y= t

# = Ds= As= Cp = 

### Kp

# = K1 

# = K2= 

### K3= Fd

# = CF=

[02] [C02]
[N2] 

### AirNova, Inc. EPA Methods 

### 1,2,3A,4,and Modified 26 

### (Flows, 021C02, H20,and HCN) 

## Spruance Genco, LLC 

## 3333 Unit No.4 One 04/19/10 

## 0923-1023

134.2 

## cc 42.168 def

### Emission Data

-050 in. H20 30.10 

### in. Hg 30.06 

### in. Hg 

### 29.92 in. Hg 0.7443 in. 

### H20 11.5



### 1.600 in. H20 5248 R 6532 R 527.7 R 

### o in. 0.000000 sq. ft. 1.00



### 60 

## mm. 10.300 ft. Vol of H20 collected Dry 

### gas meter reading Static pressure Barometric pressure Stack pressure EPAStandard pressure Average sq.rtdelta P Average draftgauge reading 

### Average metertemperature Average stacktemperature Standard temperature Nozzle diameter 

### Area ofnozzle orifice Metercalibration factor Duration of sampling time Diameterofstack 

### 83.323 sq. ft. 

### Cross sectional area ofstack 0,84 Pitot tube coefficient 

### 85.49 ft[(lbllbmol),(inHg)]'.5}/[s·R·inH20] Pitot tube constant 17.637 R/in.Hg 0.047070 cu.ft!ml 

### 0.0026688 in.Hg-eflml-R 

### 9777 scf/MMBtu 

### 7.014E-08 IbldsefI ppmVd



### Instrumental Data

4.5 %-dry 

### 15.12 %-dry



### 80.38 %-dry 

### constant constant constant Fuel Factor Conversion Factorfor HCN

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations
1) Volume of gas sampled at standard conditions, Vmstd.



### Vmstd =K1" Y "Vm " (Pb + 

### dH/13.6) ITm Vmstd 

### = 42.824 dscf 

### 1.21 dscm Unit NO.4 One



### 2)Volume ofwatervaporcollected at standard conditions, Vw(std).


### Vw(std) = K2 

### "Vic Vw(std) = 6.317 scf


### 3) Decimal fraction ofmoisture by volume in stack gas, Bws.

Bws 

### =Vwstd 

### I (Vmstd+Vwstd) Bws= 

### 0.129
4) Molecularweight ofthe stack gas on a wet basis, Ms.



### Ms = [((44"%C02) 

### + (32"%02) 

### + (28"%N2))" (1-Bws) 

## 1 + (18"Bws) Ms

# = 28.98 Ib/lbmole


### 5) Average stack gas velocity, Vs.



### Vs = Kp" Cp" (dP) " (Ts/Ps"Ms)'.5 Vs

# = 46.28 fps
6) Average actual stackgas volumetric flowrate, Qa.

Qa

# = 60 sec/min'"Vs

... As 

### Qa= 2313794 cfm 6552.7 cmm 

### 7) Average stack gas dry volumetric flowrate, Ostd.


### Qstd 

### =Qa " (TstdlTs) " (Ps/Pstd) " (1-Bws) Qstd

# = 1636761 dscfm 46353 dscmm Page 2

### Client 

### Spruance Genco, LLC Project No. 

### 3333 Test Location Test Run

8) Hydrogen Cyanide Concentration and Emissions Unit No.4 

### One

M[HCN] = M[CN-](mg) , MW[HCN](mg/mmol) 1

### MW[CN-](mg/mmol) Page 3



### C[HCN] = (M[HCN](mg) '2.205E-06(lb/mg) , 21.85(scf'inHg/lbmol'R) • K1 ' 10'6) 

### 1(MW[HCN](lb/lbmol) 'Vmsl C[HCN](@corr. 02) = C[HCN](ppmV)' [(20.9-corrected 02) 

### 1(20.9-octuol %02)] E[HCN] = M[HCN](mg) , Ostd(dscfm) • (2.205E-06)(lb/mg) • 60(min/hr) 

### 1Vmstd(dscf) E[HCN] = C[HCN](ppmV) • Fd • CF(HCN) • 

### (20.9/(20.9-%02))



## < M[HCN] = 

## < C[HCN] = 

### < C[HCN] = 

## < E[HCN] = 

## < E[HCN]= 0.004 mg 0.003 ppmV 0.002 ppmV 0.002 Ib/hr 2.57E-06 Ib/MMBtu 

### (@ 70 

### %02)

### 3333-HCN-R2



### Client 

### Project No. Test Location Test Run Test Date Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT Vic

# = Vm= 

### Pstatic

# = Pb

# = Ps

# = Pstd

# = dP

# = dH

# = Tm= Ts= Tstd= 

### On 

### = An

# = y= t

# = Ds= 

### As= Cp= Kp= K1 = 

### K2= K3

# = Fd

# = CF

# =

[02[ [C02[
[N2[ 

## AirNova, Inc. EPA Methods 1,2,3A,4,and Modified 26 (Flows, 021C02, H20,and HCN) 

## Spruance Genco, LLC 

## 3333 Unit NO.4 

## Two 04/19/10 

## 1310-1410

140.9 

### cc 42.104 delEmission Data



### -0.50 

### in, 

### H20 30.04 

### in. Hg 30.00 in. Hg 

### 29.92 in. 

### H9 

### 0.7423 in. H20A.5

1.600 in H20 5315 R 652.4 R 527.7 R 

# o in. 

### 0.000000 sq. 

### ft. 1.00



### 60 min, 10.300 

### ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature 

### Standard temperature Nozzle diameter Area ofnozzle orifice Meter calibration factor Duration ofsampling time Diameter ofstack 83.323 

### sq. ft. Cross sectional area ofstack 0,84 Pitottube coefficient 85.49 ft[(lb/lbmol)""(inHg)]",5}/[s"R"[nH20] P[tot tube constant 17.637 R/in Hg 0.047070 cu fUml 0.0026688 in.Hg-cflml-R 9920 scf/MMBtu 7.014E-08 Ibldsell ppmVd

Instrumental Data

394 

### %-dry 15.1 

### %-dry

80.96 

### %-dry constant constant constant Fuel Factor Conversion Factorfor HCN

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations 1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1'Y 'Vm ' (Pb + 

### dHI13.6) I Tm Vmstd

# = 42.132 

### dscf 1.19dscm Unit NO.4 

### Two

2) Volume ofwatervaporcollected at standard conditions, Vw(std). Vw(std) = K2 'Vie Vw(std) = 6.632 scf 

### 3) Decimal fraction ofmoisture by volume in stack gas, Bws.

Bws 

### =Vwstd / (Vmstd+Vwstd) Bws= 0.136 

### 4) Molecularweightofthe stackgason awet basis, Ms.

Ms = [((44'%C02) + 

### (32'%02) + 

### (28'%N2))' (1-Bws) 

## I+ 

### (18'Bws) Ms= 

### 28.86 Ibllbmole 5) Average stack gas velocity, Vs.

Vs = Kp' Cp' (dP) , (TsIPs'Ms)'.5 Vs= 4627 fps 6) Average actual stackgasvolumetric flowrate, Qa.

Qa = 

### 60 sec/min 

### * Vs 

### *As 

### Qa = 231299.1 efm 6550.4 cmm 

### 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa' (TstdlTs)' (PsIPstd)' (1-Bws) Qstd

# = 162101.8 dscfm 4590.7 dscmm 

### Page 2

### Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

8) Hydrogen Cyanide Concentration and Emissions Unit No.4 

## Two

M[HCN]

# =M[CN-](mg)' MW[HCN](mg/mmol) 

### 1MW[CN-](mg/mmol) Page 3



### C[HCN] = 

### (M[HCN](mg) • 2.205E-06(lb/mg) • 21.85(scf"inHg/lbmol·R) • K1 • 10'6) 

### 1(MW[HCN](Ib/lbmol) • Vmsl C[HCN](@corr. 02)

### = C[HCN](ppmV)' [(20.9-corrected 02) 

### 1(20.9-actual %02)] E[HCN] 

### = M[HCN](mg) • Qstd(dscfm) • (2.205E-06)(lb/mg) • 60(min/hr) 

### 1Vmstd(dscf) E[HCN]

# = C[HCN](ppmV) • Fd • CF(HCN) • 

### (20.9/(20.9-%02))



## < M[HCN] 

### = 0.005 

### mg 

## < C[HCN] 

### = 0.004 ppmV 

## < C[HCN] 

### = 0.003 ppmV (@ 7.0 % 

### 02) 

## < E[HCN] 

### = 0.003 Ib/hr 

## < E[HCN] 

### = 3.20E-06 Ib/MMBtu

### 3333-HCN-R3

Client Project No. Test Location Test Run Test Date 

### TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT INPUT Vic

# = Vm= 

### Pstatic

### = Pb 

### = Ps

# = Pstd

# = dP

# = dH 

### = Tm= Ts

# = Tstd= On

# = An

# = y= t

# = Ds

# = As

# = Cp= 

### Kp = 

### K1 

# = K2

# = K3

# = Fd

# = CF=



### [02] [C02]
[N2] 

## AirNova, Inc. EPA Methods 1,2,3A,4,and Modified 26 (Flows, 

### 02fC02, H20,and HCN) 

## Spruance Genco, LLC 

## 3333 Unit No.4 Three 04/19/10 

## 1658-1758

120,8 

### cc 42.395 delEmission Data



### -0.50 in. 

### H20 29,98 

### in. Hg 29.94 

### in. Hg 

### 29.92 in. 

### Hg 0.6856 

### in. 

### H20 11,5



### 1.600 in. 

### H20 530.0 R 652.9 R 527.7 R 

# oin. 

### 0.000000 sq. 

### ft. 

### 1.00

60 

## mm. 10.300 ft. Vol. of H20 collected 

### Dry gas meter reading Static pressure Barometric pressure 

### Stack pressure EPAStandard pressure Average sq.rtdelta P Average draftgauge reading Average metertemperature Average stacktemperature Standard temperature Nozzle diameter Area of nozzle orifice Metercalibration factor Duration of samphng time Diameter ofstack 

### 83_323 

### sq. ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft.[(lb/lbmol)"(inHg)]".5}/[s*R*inH20] Pltottube constant 17.637 R/in.Hg 0.047070 cu.fUml 0.0026688 in.Hg-cf/ml-R 9705 scf/MMBtu 

### 7.014E-08 Ibfdscff ppmVd

Instrumental Data

6.35 %-dry 

### 12.8 %-dry



### 80.85 %-dry constant constant constant Fuel Factor Conversion Factorfor HCN

Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, 

### LLC 3333 Test Location Test Run

Calculations
1) 

### Volume ofgassampled atstandard conditions, Vmstd.

Vmstd =K1'" Y·Vm '" (Pb 

### + dH/13.6) I

### Tm Vmstd

# = 42.466 dscf 1.20 dsem Unit 

### No.4 Three



### 2)Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std)

# =K2 ' Vic Vw(std) = 

### 5.686 sef 

### 3) Decimal fraction of moisture byvolume instackgas, Bws.

Bws

# = Vwstd , (Vmstd+Vwstd) Bws= 0.118
4) 

### Molecularweight ofthestack gas on awet basis, Ms.

Ms

# =[((44'%C02) + 

### (32'%02) + 

### (28'%N2))' (1-Bws) 

## I + 

### (18'Bws) Ms= 28.85 fbi 

### Ibmole
5)

### Average stack gas velocity, Vs.

Vs 

### = Kp' Cp' (dP) , (TsIPs'Ms)'.5 Vs

# = 42.80 fps
6) 

### Average actual stack gas volumetric flowrate, Qa.

Qa 

### =60 see/min '" 

### Vs '" As 

### Qa = 213971.2 cfm 6059.7 emm 7) Averagestack gas dryvolumetric flowrate, Qstd.
Qstd

# =Qa' (Tstd/Ts)' (PsIPstd)' (1-Bws) Qstd

# = 152644.6 dsefm 4322.9 dsemm Page 2

### Client 

### Spruance Genco, LLC Project No. 

### 3333 Test Location Test 

### Run

8) Hydrogen Cyanide Concentration and Emissions Unit No.4 Three



### M(HCN] = M(CN-lImg) , MW(HCN](mg/mmol) 

### 1MW(CN-](mg/mmol) Page 3



### C(HCN] = (M(HCN](mg) , 2.205E-06(1b/mg) , 21.85(scf"inHg/lbmol'R) , K1 • 10'6) 

### 1(MW(HCN](lb/lbmol) 'Vmsl C(HCNII@corr. 02) = C(HCNlIppmV) , ((20.9-corrected 02) 1(20.9-actual %02) ] E(HCN] = M(HCN](mg) , Qstd(dscfm) , (2.205E-06)(lb/mg) '60(min/hr) 

### 1Vmstd(dscD E(HCN] = C(HCN](ppmV) , Fd ' CF(HCN) • 

### (20.9/(20 9-%02))
M(HCN] = 0.096 

### mg C(HCN] = 0.071 ppmV C(HCN] = 0.068 ppmV (@ 7.0 

### %02) E(HCN] = 0.046 Ib/hr E(HCN]= 6.95E-05 Ib/MMBtu3333-Formaldehyde-R1

Client Project No. Test Location Emission Source Test Date Test Run Time Period

Vic = Vm= Pstatic 

### = Pb

# = Ps 

### = Pstd 

### = dP 

### = dH = Tm= Ts 

### = Tstd= y= t= On

# = An 

### = Os 

### = As 

### = Cp 

### = Kp 

### = K1 = K2 = 

### K3 = Fd = 

### CF =



### [02J [C02J
[N2J 

### AirNova, Inc. EPA Methods 1,2,3A,4,and RCRA Method 0011

(Flows, 02/C02, H20, and Formaldehyde)
Spruance Genco, LLC 3333 Richmond, Virginia Unit No.4 04/19/10 Ooe 0924-1133

Emission Data

239.8 

### cc 83.469 dcf

-0.50 in. H20 30.10 in. Hg 30.06 in. Hg 29.92 in. Hg 0.731 in. H20

### ".5

1.26 in. H20 523.6 R 655.0 R 527.7 R

0.97 120 min. 0.248 in. 0.000335 sq. ft. 10.30 ft. Vol. of H20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average meter temperature Average stack temperature Standard temperature Meter calibratIon factor Duration ofsampling time Nozzle diameter Nozzle area Diameterofstack 83.3204 sq. 

### ft. Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 ft[{lb/lbmol)*{inHg)]".S}/[s*WinH20] Pitot tube constant 17.637 R/in Hg constant 0.047070 cu.ftlml 

# o0026688 in.Hg-cf/ml-R 9777 scf/MMBtu 7793E·08 Ib/dscf

### I ppmVd constant constant Fuel Factor Conversion Factorfor CH20

EPA Method 3A Instrumental Data 4.50 %·dry 15.12 %-dry

80.38 %-dry Oxygen concentration Carbon DioxIde concentration
Nitrogen concentration Data from:

EPA4 EPA4 EPA2

EPA2

EPA2 EPA4 EPA4 

### EPA2

EPA2Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations

1) Volume ofgas sampled at standard conditions, Vmstd. Vmstd =K1* Y * Vm * (Pb 

### +dH/13.6)/ Tm Vmstd = 82.339 dscf 2.332 dscm Richmond, Virginia One

2) Volume ofwater vaporcollected at standard conditions, Vw(std). \Iw(std) = K2 • Vb Vw(std) = 11.287 scf

3) Decimal fraction of moisture by volume in stack gas, Bws. Bws = Vwstd / (Vmstd+Vwstd) Bws= 0.1206

4) Molecularweight ofthe stack gas on awet basIs, Ms. Ms = [«44*%C02)+ (32·%02) 

### + (28*%N2»;O (1-Bws) 

## 1 + (18*Bws) Ms= 29.080 Ib/lbmole

5) Average stack gasvelocity, Vs. Vs = Kp;O 

### Cp

.. (dP)

.. (Ts/Ps"Ms)".5 Vs = 45.416 fps

6) Average actual stack gas volumetric flowrate, Oa. Oa = 60 sec/min"Vs * As Oa = 227043.31 cfm 6429.87 cmm

7) Average stack gas dry volumetricflowrate, Ostd Qstd = Oa'" (TstdlTs)" (Ps/Pstd)" (1-Bws) Qstd = Qstd = 161627.12 dscfm 4577.28 dscmm Page 2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

Calculations (cont.)
8) Formaldehyde· Concentrations and Emission Rates M[CH20] = sample mass (mg) Richmono, Virginia One

C[CH20] = M[CH20] (mg) 

### 1sample volume (dscm) C[CH20 

### @ corr %02] = C[CH20] (ppmV) * (20.9-Corr. %02)f(20.9-Actual %02) Corrected 02 Percentage 

### = 7 % E[CH20] = C[CH20] (mg/dscm) * 60 (min/hr) * Qstd (dscmm) * (1 Ib /4.536 e+05 mg) E[CH20](lb/MMBtu) 

### =C[CH20](ppmV) CF;O Fd

... 

### (20.9/20.9·%02) Page 3

Comgound Samgle Mass Concentration Concentration Concentration Mass Emission Mass Emili,§ion 

## !ml!l (mg/dscm) 

### !JlQmlQ 'gmV@Corr.%O (lblhrl (lb/MMBtu)
Formaldehyde 0.00720 3.09E-03 2.47E-03 2.10E-03 1.B7E-03 2.40E-06 

### NO NO NO NO NO NO
9) Isokinecity, 

### I. 

### % I = [100*Ts*.(K3*Vlc+«{Vm*y)fTmt(Pb+(dH/13.6»)))] 

### 1(60*t*Ps·Vs*An) 

### % I

### = 105.453333-Formaldehyde-R2

Client Project No. Test Location EmissionSource Test Date Test Run Time Period

Vlc= Vm= Pstatic = Pb 

### = Ps 

### = Pstd ;; dP

### = dH 

### = Till 

### = Ts 

### = Tstd= y= t= On ;; An ;; Os 

### = As 

### = Cp= Kp = K1 = 

### K2 = K3 ;; Fd 

### = CF =

[021 [C02]
[N2] 

### AirNova, Inc. EPA Methods 1,2,3A,4,and RCRA Method0011

(Flows, 02/C02, H20,and Formaldehyde)
Spruance Genco, LLC 3333 Richmond, Virginia Unit No.4 04f19f10 

### Two 1310-1520

Emission Data

256.5 cc 84.875 dcf

-0.50 in H20 30.04 in Hg 30.00 in Hg 29.92 in Hg 0.738 in H20 ",5

1.33 in H20 542.6 R 654.4 

### R 527.7 R

0.97 120 min. 0.248 in 0.000335 sq, 

### ft. 10.30 ft Vol of H20 collected Dry gas meter reading StatIc pressure Barometric pressure Stack pressure EPA Standard pressure Average sq rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameterofstack 83.3204 sq. 

### ft. Cross sectIonal area ofstack 0.B4 Pitot tube coefficient 85.49**ft[{lbflbmol)~(inHg)11\.5}f[s*R*inH20]** Pitot tube constant 17.637 Rlin.Hg 0.047070 cU.ft!ml 0.0026688In,Hg·cf/ml-R 9920 scf/MMBtu 7.793E-OB [bfdscf 

### I ppmVd constant constant constant Fuel Factor Conversion FactorforCH20

EPA Method 3A Instrumental Data 3.94 %-dry 15.10 %-dry

80.96 %-dry Oxygen concentration Carbon Dioxide concentration
Nitrogen concentration Data from:

EPA4 EPA4 EPA2

EPA 2

EPA 2 EPA 4 EPA4 EPA2

EPA2Client Spruance Genco, llC Project No. 3333 Test Location Test Run

Calculations

1) Volume ofgas sampled at standard conditions, Vmstd. Vmstd =K1 *

### Y·Vm * (Pb + dH/13.6) ITm Vmstd 

### = 80.648 dscf 2.284 dscm Richmond, Virginia Two

2) Volume ofwalervapor collected atstandard conditions, Vw(std). Vw(std) = K2 * Vic Vw(std) = 12.073 scf

3) Decimal fraction ofmoisture byvolume in stack gas, Bws. Bws = Vwstd I (Vmstd+Vwstd) Bws = 0.1302

4) Molecularweight ofthe stack gas on a wet basis. Ms. Ms = [«44*%C02)+ (32*%02) + (2B*%N2»" (1-Bws) 

## 1 + (1a*Bws) Ms= 28.936 Ib/lbmole

5) Average stack gasvelocity, Vs. Vs = Kp" Cp" (dP) * (Ts/Ps*Ms)".5 Vs 

### = 46.029 fps

6) Average actual stack gasvolumetricflowrate, Qa. Oa = 60 sec/min * Vs

.. As Qa = 230110.29 cfm 6516.72 cmm

7) Average stack gasdryvolumetricflowrate, Qstd. Qstd 

### =Qa" (TstdfTs) * (Ps/Pstd) * (1-Bws) Qstd = 161853.63 dscfm Osld = 4583.69 dscmm Page 2Client Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations (cont.)Richmond, Virgmia Two

8) Formaldehyde

- Concentrations and Emission Rates M[CH20] = sample mass (mg) C[CH20] = M[CH20] (mg) I sample volume (dscm) C[CH20 @corr. %02]

### =C[CH20] (ppmV) * (20.9-Corr. %02)1(20.9-Actual %02) Corrected 02 Percentage 

### = 7 % E[CH20] = C[CH20] (mg/dscm) * 60 (min/hr) * Qstd (dscmm) * (1 

### Ib 

### 14.536 e+05 mg) E[CH20](lb/MMBtu) = C[CH20](ppmV) CF • Fd * (20.9/20.9-%02) Page 3

Com(;!ound Sam(;!le Mass Concentration Concentration ConcentratioD Mass Emission Mass EmissiQo !mgl (mg/dscm) (QQrr!lil 'pmV@Corr.%O (Ib/hr) (lb/MMBtu)
Formaldehyde 0.00484 

### 2.12E-03 1 70E-03 1.39E-03 1.2BE-03 1.62E-06 

### NO NO NO NO NO NO
9) Isokinecity, I. 

### % I

### =[100*Ts*(K3*Vlc+{«Vm*Y)fTmt(Pb+(dH/13.6»»] 1(60*t*Ps*Vs*An) %1= 103143333-Formaldehyde-R3

Client Project No. Test Location Emission Source Test Date Test Run Time Period

Vic 

### = Vm 

### = Pstatic = 

### Pb = Ps = Pstd 

### = dP

# = dH = Tm 

### = Ts = Tstd= 

### y= t= On 

### = An = Os 

### = As = Cp = Kp = K1 = 

### K2 = K3 

### = Fd = 

### CF =

[02J [C02J
[N2J 

### AirNova, Inc. EPA Methods 1,2,3A,4,and RCRA Method 0011

(Flows, 021C02, H20, and Formaldehyde)
Spruance Genco, LLC 3333 Richmond, Virginia Unit No.4 04/19110 Three 1658-1911

Emission Data

215.6 cc 76.544 dcf

-0.50 in. H20 29.98 in. Hg 29.94 in. Hg 29.92 in. Hg 0.644 in. H20 

### ".5

1.02 in. H20 542.2 R 650.3 R 527.7 R

0.97 Vol. ofH20 collected Dry gas meter reading Static pressure BarometfJc pressure Stack pressure EPA Standard pressure Average sq.r1 delta P Average draftgauge reading Average meter temperature Average stack temperature Standard temperature Meter calibration factor 120 min. Duration ofsampling time 0.248 in. Nozzle diameter 0.000335 sq. ft. Nozzle area 10.30 ft. Diameter ofstack 83.3204 sq. ft. Cross sectional area ofstack 0.84 PltOt tube coefficient 85.49 ft[(lb/lbmol)*(inHg)]" 5)/[s*R*inH20] Pitottube constant 17637 R/in.Hg 0.047070 cu.ftlml 0.0026688 in.Hg-cf/ml-R 9705 scf/MMBtu 7.793E-08 Ib/dscfI ppmVd constant constant constant Fuel Factor Conversion Factorfor CH20

EPA Method 3A Instrumental Data 6.35 %-dry 12.80 %-dry

80.85 %-dry Oxygen concentration Carbon DioxIde concentratIon
Nitrogen concentration Data from:

EPA4 EPA4 EPA2

EPA2

EPA 2 EPA4 EPA4 EPA2

EPA2Client Project No. Spruance Genco, LLC 3333 Test Location Test Run
Calculations

1) Volume ofgas sampled at standard conditions, Vmstd. Vmstd**=K1~** 

### Y"Vm" (Pb + dH/13.6) 

### ITm Vmstd = 72.588 dscf 2.056 dscm Richmond, Virginia Three

2) Volume ofwatervapor collected at standard conditions, Vw(std). Vw(std) = K2 *Vic Vw(std) 

### = 10.148 scf

3) Dec;:imal fraction ofmoisture by volume in stack gas, Bws. Bws = Vwstd I (Vmstd+Vwstd) Bws = 0.1227

4) Molecularweight ofthe stack gas on awet basis. Ms. Ms 

### =[«44*%C02)+ (32*%02) +**(28~%N2»** * (l-Bws) 

## 1 + (18*Bws) Ms= 28.7931b/lbmole

5) Average stack gas velocity, Vs. Vs = Kp * Cp * (dP) * (Ts/Ps,oMs)".5 Vs 

### = 40.193 fps

6) Average actual stack gasvolumetricflowrate, Oa. Oa = 60 sec/min * Vs ,. As Oa = 200933.84 cfm 5690.45 cmm

7) Average stack gas dry volumetricf1owrate, Ostd. Ostd 

### =Oa * (TstdfTs)· (PsIPstd)" (1-Bws) Qstd = Qstd = 143167.33 dscfm 4054.50 dscmm Page 2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run

Calculations (cant.)
8) Formaldehyde

- Concentrations and Emission Rates M[CH20] = sample mass (mg) Richmond, Virginia Three

qCH20] = M[CH20] (mg) 1sample volume (dscm) qCH20 

### @ corr, %02]

# = qCH20] (ppmV) • (20.9-Corr. %02)/(20.9-Actual %02) Corrected 02 Percentage

# = 7 

### % E[CI-I20] = qCH20] (mg/dscm) * 60 (min/hr) * Qstd (dscmm) • (1 Ib 14.536 e+05 mg) E[CH20](lbfMMBtu) 

### =qCH20](ppmV) CF • Fd • (20.9/20.9-%02) 

### Page 3

ComQ:OUOQ Sample Mass Concentration Concentration Concentration Mass Emission Mass EmilSSiQ[! 

## lm9l (mq/dscm) 

## ilm!n'Ll 'PmV@Corr.%O (Ib/hr) (lb/MMBIU)
Formaldehyde 0.00614 

### 2.99E-03 2.39E-03 2.29E-03 1.60E-03 2.60E-06 

### NO NO NO NO NO NO
9) Isokinecity, I. % I =**[100~Ts·(K3·Vlc+(((Vm*Y)fTmt(Pb+(dH/13.6))))]1****(60~t·Ps*Vs*An)** % I

### = 104.95M7EMTL

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit 4 Metals 

### 04/20/10

Parameter: 

### Oxygen Instrument Span (% 

### 02): 22.08

Actual Calibration Gas Value (% 

### 02): AnalyzerCalibration Response (% 

### 02L AnalyzerCalibration Error

### (% Span): Runs 1

Zero**S~tem** Calibration Gas AOQarent Init. SJ:::s. Init. Sys. Final Sj!,s:. FinfJ.1 Sys.

Stack Calib. Cal. Bias Cafib. Cal. Bias 

### Run Conc. Response (% sQan) Response (% span)



### 1 4.22 0.10 0.36 0.09 0.32 

### 2 0.00 0.09 0.32 0.00 -0.09 3 0.00 0.00 -0.09 0.00 -0.09 4 0.00 0.00 -0.09 0.00 -0.09 5 0.00 0.00 -0.09 0.00 -0.09 6 0.00 0.00 

### -009 0.00 -0.09 7 

### 0.00 0.00 -0.09 0.00 -0.09 8 0.00 0.00 -0.09 0.00 -0.09 

### 9 0.00 0.00 -0.09 0.00 

### -0.09 

### 10 0.00 0.00 -0.09 0.00 -0.09 

### 11 0.00 0.00 -0.09 0.00 -0.09 

### 12 0.00 0.00 -0.09 0.00 -0.09 

### AirNova, Inc. Page 1 EPA Method 7E Calculations (Cal. Error, Bias Driftand BiasAdjustment)

AnalyzerCalib. Gases Upscale 

# = low mid high Sy,s:. Gal.**Ga~** 

### 0.00 N/A 

### 11.90 22.08 11.90 0.02 N/A 

### 11.90 11 98 11.90 0.09 0.00 0.00 -45.74

U[!scalg**S~stem** Calibration Gas Calib. Init. Sys. Init. SJ:::s. Final Sys. FinalSJ:::s. Calib.**~** Drift**~** Cal. Bias Calib. Cal. Bias Drift Stack (% span) ResQonse (% span) Response 

### t% span) (% span) Conc.



### -005 11.90 0.00 11.98 

### 0.36 0.36 4.14 -0.41 11.98 0.36 0.00 -53.89 -54.26 -0.09 

### 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 

### 0.00 -53.89 0.00 -53.89 0.00 

### ERRM7EMTL

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit4 04/20/10

Parameter: Instrument Span (% C02): 

### Carbon Dioxide 2228

Actual Calibration Gas Value (% C02): AnalyzerCalibration Response (% C02): AnalvzerCalibration Error(% Span):

Zero SXstem Calibration Gas Apparent Init. S):::s. Init. Svs. Final S)!:s. Final S\:,s.

Stack Galib. Gal. Bias Galib. Cal. Bias Run Conc. Response (% span) Response (% span)



### 15.49 0.00 0.00 0.00 0.00 2 0.00 0.00 0.00 0.00 0.00 3 0.00 0.00 0.00 0.00 0.00 4 0.00 0.00 0.00 0.00 0.00 5 0.00 0.00 0.00 0.00 0.00 6 0.00 0.00 0.00 0.00 0.00 7 0.00 0.00 0.00 0.00 0.00 8 0.00 0.00 0.00 0.00 0.00 9 

### 0.00 0.00 0.00 0.00 0.00 10 0,00 000 0.00 0.00 000 11 0.00 0.00 0.00 0.00 0.00 12 0.00 0.00 0.00 0.00 0.00 

### AirNova, Inc. Page 2 EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)

AnalyzerGalib. Gases Upscale 

### ,ero low mid high S):::s. Cal. Gas 

### 0.00 N/A 

### 12.38 22.38 12.38 000 N/A 

### 12.33 2222 12.38 0.00 0.00 -0.22 -0.72

Ugscale Sxstem Calibration Gas Galib Init. S):::s. Init. S\:,s. Final S!!,s. Final S!!,s. Calib. Actual Drift Galib. Cal. Bias Calib. Gal. Bias Drift Stack (% span) Response (% span) Response t% span) (% span) Conc.



### 0.00 12.45 0.31 12.45 0.31 0.00 15.40 0.00 12.45 0.31 0.00 -55.57 -55.88 0.00 0.00 0.00 -5557 0.00 -55.57 0.00 

### ERR 0.00 000 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 000 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERRM7EMTL2

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit 4 Metals 04/21/10

Parameter: 

### Oxygen InstrumentSpan (% 

### 02): 22.08

Actual Calibration Gas Value (% 

### 02): AnalyzerCalibration Response (% 

### 02): AnalyzerCalibration Error(% Span): Metals Run 2 Metals Run 3

Zero**S~tem** Calibration Gas Apparent Init· 

### ,s)!,S. Init. Sys, FinalS\,:s. Final S\,:s.



### IlIiID< Calib. Cal. Bias Calib. Cal. Bias Run Conc. Response (% span) Response (% span)



### 1 3.91 0.10 0.45 0.00 0.00 2 3.83 0.00 0.00 0.00 0.00 3 0.00 0.00 0.00 0.00 0.00 4 

### 0,00 0.00 0.00 0.00 0.00 5 0.00 0.00 0.00 0.00 0.00 6 000 0.00 0.00 0.00 0.00 

### 7 0.00 0.00 0.00 0.00 0.00 8 0.00 0.00 0.00 0.00 0.00 

### 9 

### 0.00 0.00 0.00 0.00 0.00 10 0.00 000 0,00 0.00 0.00 11 000 000 0.00 0.00 000 12 0.00 0.00 0.00 0.00 0.00 

### AirNova, Inc. Page 1 EPA Method 7E Calculations (Cal. Error, Bias Driftand Bias Adjustment)

AnalYZerCalib. Gases Upscale
zero 

# """ mid high S\,:s.**~g/.** Gas 

### 0.00 N/A 

### 11 90 22.08 11.90 0.00 NfA 

### 11.99 21.92 11.90 0.00 000 0.41 -0.72

U[!s!;;S!le**S~tem** Calibration Gas Ca/ib. Init. S\,:s. Init. S\,:s. Final S\,:s. Final S\,:s. Calib. 

### M!Jl.a!. Drift Calib. Cal. Bias Cafib. Cal. Bias Dnft Stack (% span) Response (% span) Response (% span) (% span) Cone.



### -0.45 11.95 0.23 11,98 0.36 0.14 3.86 0.00 11.98 036 11.87 -0.14 -0.50 3.82 

### 0.00 11.87 -0.14 0.00 -53.89 -53.76 0.00 0.00 0.00 -53.89 000 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -5389 000 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 

### -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 000 -53.89 0.00 

### ERR 0.00 0.00 -5389 0.00 -53,89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERRM7EMTL2

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit 4 04121/10

Parameter: InstrumentSpan (% C02): 

### Carbon Dioxide 22-28

Actual Calib@tion Gas Value (% C02): Anal\lZerCalibration Response f% C02): AnalvzerCalibration Error(% Span)'

Zero Sy:stem Calibration GilS A(2parent Imt. S'is. Init 

### ,s\@:. Final S)!s. Final S,,-s.

StaQk Calib. Cal. Bias Calib. Cal. Bias Run Cone. Res(2onse (% span) Res(2onse (% soan)



### 15.18 -0.12 -0.54 0.12 0.54 2 

### 15.12 0.12 0.54 

### 0.00 0.00 3 

### 0.00 0.00 0.00 0.00 0.00 4 

### 0.00 0.00 0.00 0.00 0.00 5 

### 0.00 0.00 0.00 0.00 0.00 6 

### 0.00 0.00 0.00 0.00 0.00 7 

### 0.00 0.00 0.00 0.00 0.00 8 

### 0.00 0.00 0.00 0.00 0.00 9 

### 0.00 0.00 0.00 0.00 0.00 10 

### 0.00 0.00 0.00 0.00 0.00 11 0.00 0.00 0.00 

### 0.00 0.00 12 

### 0.00 0.00 0.00 0.00 0.00 

### AirNova, Inc. Page 2 EPA Method G.C Calculations (Cal. Error, Bias Driftand Bias Adjustment)

Anal'izerCalib. Gases UQ.§'Qg/@ 

### zero Jow mid high S,,-s. Cal. Gas 

### 0.00 

### NJA 12.38 22.38 12.38 0.00 

### NJA 12.45 22.34 12.38 0.00 0.00 0.31 -0.18

Uescale Sllstem Calibration Gas Calib. {nit S)!s. Init. S"-S. FmaJS:vs. FinaJS,,-s. Calib. Actual Drift Calib. Cal. Bias Calib. Cal. Bias Drift Stack (%@an) R@sponse (% span) Response (% span) (% span) Cone.



### 1.08 12.57 0.85 12.57 085 

### 0.00 14.95 

### -0.54 12.57 0.85 12.57 0.85 0.00 14.90 

### 0.00 12.57 0.85 0.00 -55.57 -56.42 0.00 

### 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 000 

### -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR

### 3333-PM2.5-R1



### Client Project No. Test Location Test Run Test Date Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT
INPUT INPUT INPUT
INPUT

INPUT INPUT 

### Vlc= Vm= Pstatic 

### = Pb 

### = Ps 

### = Pstd

# = dP

# = dH = 

### Tm= 

### Ts

# = Tstd= 

### Dn

# = An

# = y= tf

# = Os = 

### As= Cp= Kp= K1 

# = K2= 

### K3= C1= C2 = 

### C3= C4= 

### C5

# = C6

# = 81 

# = Fd 

# =

[02] [C02] [N2] 

### AirNova, Inc. EPA Methods 1,2,3,4,

### aTM 27 and 202 (Flows, 

### 02/C02, H20, PM2.S and CPM) Spruance Genco, LLC 

### 3333 UnitNo.4 One 

### 04120110 

### 0925-1558

394.1 

## cc Emission Data

123.924 dcf -0.50 

### in, 

### H20 30.04 in. Hg 

### 30.00 in. Hg 29.92 in. 

### Hg 

# a7704 in, H20 

### ".5

0.340 in. 

### H20 537.1 R 

### 650.0 R 527.7 R 0,180 in. 

### 0.000177 

### sq. ft 

### 1.02



### 373 min. 10.300 ft. Vol. of H20 collected 

### Dry gas 

### meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure 

### Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature 

### Nozzle diameter Area of nozzle orifice Meter calibration factor, gamma Duration ofsampling time Diameter ofstack 

### 83.32 sq. ft. Cross sectional area ofstack



### 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)·(inHg)]'.5]/[s·R'inH20] Pitoltube constant 

### 17.637 R/in.Hg constant 

### 0.047070 cU.fUml constant 

### 0.0026688 in.Hg-cf/ml-R constant



### -150.3162 upoise Viscosity constant



### 13.4622 upolse/RA

### O.5 Viscosity constant 

### 3861530 upoise/RA

### 2 Viscosity constant 

### 0.591123 upOise Viscosity constant



### 91.9723 upolse Viscosity constant 

### 1.51761E-05 upoise/RA

### 2 Viscosity constant 

### 0.15625 Constant 

### 9777 dscf/MMBtu
Instrumental Data


### 4.14 %-dry 

### 15.40 %-dry 

### 8046 %-dry Fuel Factor

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project 

### No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations 

### Unit No.4 One

1) Dry

### Gas Volume atstandardconditions, Vms (EPA aTM

### 27 Equation 27).


### Vms =K1'Y'Vm 0 

### (Pb + 

### dH/13.6) I

### Tm Vms

# = 124.798 dscf 3.534 dscm 2) Drygas sampling rate atstandardconditions, QsST(EPA OTM

### 27 Equation 28).
QsST

# = Vms / tr 

### asST = 0.335 dscfm 0.009 dscm 

### I min. 3) Volume ofwater vaporcondensed

### atstandardconditions, 

### Vws (EPA OTM

### 27 Equation 29).


### Vws 

### = K2 

### ""Vic Vws= 18.550 sct 4) Decimalfraction ofmoisture by volume in stackgas, Bws (EPA OTM

### 27 Equation 30).


### Bws = 

### Vwstd 

### I (Vmstd+Vwstd) Bws= 0.129 5) Molecular weight ofthe stackgas on 

### a wetbasis, Mw (EPA OTM

### 27 Equations 

### 1&2).
Mw = [ ((44'%C02) + 

### (32 0

### %02) + 

### (2S 0

### %N2)) , (1-Bws) [ + 

### (1S0 

### Bws) Mw

# = 29.00 Ib/lbmole 

### 6) Gas sampling rate atactual Cyclone conditions, Os (EPA OTM

### 27 Equation 31).



### as = (Pstd/Tstd),asST' (1/(1-BwsJr(Ts/Ps) 

# as = 0.472 ae1m 7) Average stackgas velocity, Vs (EPA OTM

### 27 Equation 11).


### Vs = Kp' Cp 0 

### (ave of(dP)'O.5)' (Ts/PsO

### Mw)·0.5 Vs 

### = 47.82 fps 8) Average actualstackgas volumetric flowrate, 

## Oa.
Oa

# = 60 seclmin "" Vs "" As aa = 239069 9 cfm 

### 67705 cmm 9) Average stack

### gas drystandard volumetric flowrate, Ostd.


### astd = aa 0 

### (Tstd/Ts) 0 

### (Ps/Pstd) 0 

### (1-Bws) Qstd 

### = 169433.1 dscfm 4798.3 dscmm Page 2

### Client Project No. Spruance Genco, LLC 3333 

### Test Location Test Run

Calculations (cont.) Unit NO.4 

### One 

### Page 3

10) 

### Analyticaldata
Cvclone andFilterFractions (EPA Method OTM27): M1) Instackquartz mtcrofibre filter, <2.5um
0.0215 9 PM <2.5 filter netwt M2·4) Cyclone acetonewashes
0.0000 9 actual mass of>2.5, Containers2&3 0.0019 9 actual mass of <1=2.5um, Container4 0.0000 9 acetone blank netwt o mL volume 100 mL volume 100 mL volume

0.0000 9 blank corrected mass of>2_5um, Containers 2&3

# =M2&M3 0.0019 9 blank corrected mass of</=2.5um, Container4 

### = M4


### Condensible Particulate Matter(CPM) Fractions (EPA Method202): M5) Back HalfAqueous Wash
0.0106 9 actual sample mass 0.0001 9 aqueous blank mass 300 ml blank vol. 300 ml Sample volume
0.0105 9 condensible aqueous PM M6) Back Half MeCI2 Extraction Portion
0.0019 9 extraction netwt 0.0000 9 MeCI2 blank netwt 300 ml blank vol. 300 ml MeCI2 extraction volume
0.0019 9 condensible organic PM M[CPM]

# =blank corrected mass of Total CPM, M5 & M6 (in grams) M[CPM] = 0.0124 9 CPM 

### 11) 

### Particulate Concentrations, C 

### (EPA OTM27andEPA 202).



### Equation 43 Equation 45

EPA 202 C[totalsus] = M1 [g)+M2(g)+M3(g)+M4(g),15.43(grainslg)Nmstd(dscD= C[PM2.5sus] = M1 (g) + M4(g) , 15.43(grainslg) 1Vmstd(dscf) = C[CPM] = M[CPM](g) '15 43(grainslg) IVmstd(dscD where 15.43

### =7000/453592*1000 C[PMtotal] = C[PMtotalsus] + C[CPM] C[PM2.5total] = C[PM2.5sus] + C[CPM] 0.0029 gr/dscf PMsus 0.0029 gr/dscf PM2.5sus 0.0015 grJdscfCPM
00044 gr/dscfTotal PM 0.0044 gr/dscfTotal PM2.5

### Client Project No. Spruance Genco, LLC 3333



### 12) Particulate Emission Rates, 

### E Test Location Test Run

Calculations (cont.) Unit NO.4 One

E[lb/hr[

# = C[[(gr/dscf) • (1 IbI7000 gr) • Qstd(dscfm) • 60(min/hr) E[lb/MMBtu]

# = C[](gr/dscf)' (1 Ib/7000 gr)' Fd(dscf/MMBtu)'

### (20.9/20.9-%02) E[totalsusj = 4.20 

### Ib/hrtotal sus PM E[totalsusj = 0.0050 

### Ib/MM.Btu total sus PM E[PM2.5sus] 

### = 4.20 

### Ib/hr PM2.5sus = 

### 65.4 

### %ofTotal 

### PM2,5 E[PM2.5sus] 

### = 0.0050 

### Ib/MMBtu PM2 5sus = E[CPM] 

### = 2.23 Ib/hr CPM 

### 34.6 

### %ofTota! 

### PM2.5 E[CPM] 

### = 0.0027 Ib/MMBtu CPM E[PMtotal] 

### = 6.43 

### Ib/hrtotal PM E[PMtotal] 

### = 0.0077 Ib/MMBtu total PM E[PM2.5total] 

### = 6.43 

### Ib/hrtotal PM2 5 E[PM2 5total] 

### = 0.0077 

### Ib/MMBtu total PM2.5 

### 13) PercentIsokinectic Sampling, %1 

### (EPA 

### aTM27 

### Equation 40).
% I = 

### [100*Ts*Vms·Pstd) I 

### (60*Vs*tr*An*Ps*(1-Bws)"Tstd) %1= 93.11 

### 14) Stack Gas ViscOSIty, 

## u(EPA 

### aTM27

### Equation 3).

u = 

### C1 + C2*(Ts"O.5) + C3*(Ts"-2) + C4*(%02) - (C5"'Bws) + C6*Bws*(TsII.2) u = 

### 193.4 micropoise Page 4

### Client Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations (cont.) 15) Test Condition Reynolds number, Nre (EPA OTM

### 27 Equation 8).


### Nre

# = 8.64*10115*(Ps*MwlTs)*(Qs/u) Nre

## = 2822 Unit No, 

### 4 One

16) ActualParticle CutDiameterfor Cyclone I, D50 (EPA OTM

### 27 Equation 32).


### D50 = 81 • ( [Ts

### 1( Mw' Ps)]A.2091) • ( (u 

### lOs)'.7091) 050= 10.47 um 17) Actual Cunningham Correction Factorbasedon Op

# = 2.5um, 

### C (EPA OTM

### 27 Equation 4)


### C = 1+ 0.0057193' (u/(Ps'Dp))' (Ts/Mw)'0.5 C= 1.0698 18) Initial

### 050 for Cyclone IVbasedon testcondition Reynolds numberfrom OTM

### 27 Equation 8.


### IfNre < 

### 3162, use Equation 33 which results in 050 for IV = If Nre >= 3162, use Equation 34 which results in 050 for iV = Initial 050 2.32 222 Equation 33 Equation 34 Equation 35 

### D50 = 0.0024302'(u/Os)'1.1791·(1/C),O.5'(Ts/(Ps'Mw)),0.6790 D50 = 

### 0.019723'(u/Os),O.8058'(1/C)'0 5'(Ts/(Ps'Mw))'0 3058 Cr = 1 + 0.0057193'(u/(Ps'D50)),(Ts/Mw),O.5 19) Re-establlshed

### 050 for Cyclone IV, 

### 050-1 Page 5

Re-established Cunningham, Cr 1.0753 1.0786

IfNre < 

### 3162, use Equation 36 which results in 050for IV = If Nre >= 3162, use Equation 37 which results in 050 for iV = Recalculated Cut Oiam, 050-1 231 2.21 Equation 36 Equation 37 

### D50-1 = 0.0024302·(u/Os)'1.1791'(1/Cr)'0.5'(Ts/(Ps·Mw)),0.6790 D50-1 = O.

### 019723'(u/Os),0.805S·(1/Cr)'05'(Ts/(Ps'Mw))'0.3058 19) Establishing "Z" value, 

### Z.
If Equation 36 was used, then Z = 050-1 '050 = If Equation 37 was used, then Z = 050-11 050 = If 0.99 < 

### Z < 

### 1.01, then 050-1 is best cut diameterestimate, If0.99 > 

### Z > 

### 1.01, then repeat cales for Cr using 050-1 

### 1 00 1.00

### 3333-PM2.5-R2



### Client Project No. 

### Test Location Test Run Test Date 

### TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT
INPUT INPUT INPUT
INPUT

INPUT INPUT 

### Vic = 

### Vm= Pstatic

# = Pb**~** 

### Ps

# = Pstd

# = dP**~** 

### dH 

### = Tm= Ts

# = Tstd= 

### On

# = An

# = y= tr

# = Os= As

# = Cp= Kp= K1 

### = K2= K3= C1= C2 = 

### C3

# = C4

# = C5

# = C6

# = 81 

# = Fd

# =

[02] [C02] [N2] 

### AirNova, Inc. EPA Methods 1,2,3,4, OTM 27 and 202 

### (Flows, 02/C02, 

### H20, PM2.S and CPM) Spruance Genco, LLC 

### 3333 UnitNO.4 

## Two 04121110 0711-1317

398 

## cc Emission Data

118.523 dcf 

### -0.50 

### in H20 29.96 in. 

### Hg 29,92 

### In. Hg 

### 29.92 in. 

### Hg 0.7661 in. 

### H20 

### ".5

0340 

### in. H20 518.3 R 

### 647.7 R 5277 R 

### 0.180 in 0.000177 

### sq. 

### ft. 1.02 

### 371.1 min. 

### 10.300 

### II. Vol ofH20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area ofnozzle orifice Metercalibration factor, gamma 

### Duration of sampling time Diameter ofstack 83.32 sq. ft. 

### Cross sectional area ofstack

0.84 Pitot tube coeffic1ent 85.49 

### ft[(lb/lbmol)'(inHg)]'.S}/[s·WinH20] Pilottube conslant 17.637 R/in.Hg constant 0.047070 cu,ftlml constant 

# o0026688 in Hg-cffml-R constant

-150.3162 upoise Viscosity constant

13.4622 upoisefR"O 

### 5 Viscosity constant 3861530 upoise/R"2 Viscosity constant 0.591123 upoise Viscosity constant

91.9723 upoise Viscosity constant 1.51761E-05 upolse/R"2 Viscosity constant 0.15625 Constant 9920 dscf/MMBtu
Instrumental Data


### 3.86 %-dry 

### 1495 %-dry 

### 81.19 %-dry Fuel Factor

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run
Calculations Unit No.4 

### Two

1) Ory Gas 

### Volume atstandardconditions, Vms 

### (EPA OTM27 

### Equation 27).


### Vms =K1'Y'Vm' (Pb +

### dH/13.6) 

### ITm 

### Vms

# = 123.357 dscf 

### 3.493 dscm 

### 2) Drygas sampling rate atstandardconditions, QsST(EPA OTM27 

### Equation 28).
OsST = Vms/ tr 

### asST= 

### 0.332 dscfm 0.009 dscm 

### I min. 

### 3) Volume ofwater vaporcondensedatstandardconditions, Vws (EPA OTM27 

### Equation 29).


### Vws = 

### K2 *Vle Vws= 18.734 scf 

### 4) Decimalfraction ofmoisture byvolume in stackgas, 

### Bws (EPA OTM

### 27 Equation 30).

Bws

# = Vwstd / (Vmstd+Vwstd) Bws= 

### 0.132 5) Molecularweight ofthe stackgas on 

## a wetbasis. Mw (EPA OTM27

### Equations 1 &2)


### Mw = [((44'%C02) + 

### (32'%02) + 

### (28'%N2)),(1-Bws) 

## I+ 

### (18'Bws) 

### Mw

# = 28.89 Ib/lbmole 6) Gas 

### sampling rate atactual Cyclone conditions, Os 

### (EPA OTM 27 

### Equation 31).



### as = (Psld/TsldtasST' (1/(1-Bws))'(Ts/Ps) 

# as = 0.470 aefm 7) Average stackgas 

### velocity, Vs (EPA OTM27 

### Equation 11).


### Vs = Kp' Cp' (ave of(dPI'O.5)' (Ts/Ps'MwI'O.5 

### Vs = 

### 47.62 fps 8) Average actualstackgas 

### volumetric ffowrate, Qa.
Oa

# = 60 sec/min * Vs * As 

### Oa

# = 238054.1 efm 6741.7 cmm 9) Average stackgas 

### drystandard volumetric flowrate, Qstd


### asld = aa' (TsldlTs)' (Ps/Pstd)' (1-Bws) astd = 168396.8 dscfm 

### 4769.0 dsemm 

### Page 2Client Project 

### No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations (cont.) Unit No.4 Two Page 3



### 10) Analyticaldata
Cvclone andFilterFractions (EPA Method OTM27): M1) Instack quartz microfibre filter, <2.Sum

0.0143 

### 9 PM <2.S filter net

### \lilt M2-4) Cyclone acetonewashes
0.0000 

### 9 actual mass of>2.5, Containers 2&3 0.0035 

### 9 actual mass of</=2.5um, Container

### 4 0.0000 

### 9 acetone blank netwt 

# a mL volume 100 mL volume 100 mL volume
0.0000 g blank corrected mass of>2.5um, Containers2&3

### = M2&M3 0.0035 

### 9 blank corrected mass of </=2.Sum, Container4 = M4


### Condensible Particulate Matter(CPMJ Fractions (EPA Method202): M5) Back HalfAqueous Wash

0.0090 

### 9 actual sample mass 0.0001 

### 9 aqueous blank mass 300 ml blank vol. 300 ml Sample volume

0.0089 

### 9 condensible aqueous PM M6) Back Half MeCI2 Extraction Portion
0.0009 

### 9 extraction netwt 0.0000 g MeCI2 blank netwt 300 ml blank vol. 300 ml MeCI2 extraction volume


# o0009 

### 9 condensible organic PM M[CPM] = blank corrected mass of Total CPM, MS & M6 (in grams) MICPM] = 0.0098 9 CPM 

### 11) Particulate Concentrations, 

### C (EPA OTM27andEPA 202).

Equation 43 Equation 45



### EPA 202 Cltotalsus] = M 1(g)+M2(g)+M3(g)+M4(g)"5.43(gralns/g)Nmstd(dscD= C[PM2.5sus] = M1(g) + M4(g) , 15.43(gralns/g) 

### 1Vmstd(dscD = C[CPM] = MICPM](g)' 15.43(gralns/g) IVmstd(dscf) where 15.43= 

### 7000/453592'1000 C[PMtotal] = C[PMtotalsus] + C[CPM] C[PM2.5total] = C[PM2.5sus] + C[CPM] 0.0022 gr/dscfPMsus 0.0022 gr/dscfPM2.5sus 0.0012 gr/dscfCPM
0.0035 gr/dscfTotal PM 

# o0035 gr/dscfTotal PM2 5

### Client Project No. Spruance Genco, LLC 3333

12) Particulate Emission Rates, 

### E. Test Location Test Run
Calculations (cont.) Unit No 4 

## Two

E[lblhr] = 

### C[](grldscD' (1 Ibl7000 gr)'Qstd(dscfm)' 60(minlhr) E[lbIMMBtu]

# = C[](grldscD' (1 Ibl7000 gr)' Fd(dscfIMMBtu)' (20.9120.9-%02) E[totalsus]

# = 3.21 Ib/hr total sus PM E[totalsus] 

### = 0.0039 Ib/MMBtu total sus PM E[PM2 5sus)

# = 3.21 Ib/hr PM2.5sus 

### = 64.5 % ofTotal PM2.5 E[PM2.5sus] 

### = 0.0039 Ib/MMBtu PM2.5sus 

### = E[CPM]

# = 1.77 Iblhr CPM 35.5 % ofTotal PM2.5 E[CPM]

# = 0.0021 IblMMBtu CPM E[PMtotal]

# = 4.98 Ib/hr total PM E[PMtotal]

# = 0.0060 Ib/MMBtu total PM E[PM2.5total]

# = 4.98 Ib/hrtotal PM2.5 E[PM2.5total]

# = 0.0060 IblMMBtu total PM2.5 13) Percent Isokinectic Sampling, %1 (EPA OTM

### 27 Equation 40).
% I

### = [100*Ts·Vms*Pstd) 

### I**(60*Vs*tr*An~Ps*(1**

### -Bws)*Tstd) % I 

### = 93.07 14) StackGas Viscosity, u (EPA OTM27 Equation 3).

u

# = C1 + C2*(Ts"O.5) + C3"'(Ts"-2) + C4*(%02)

- (C5*Bws) + C6*Bws*(Ts"2) u

# = 1925 mlcropoise 

### Page 4

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations (cont.) 15) Test Condition Reynolds number, Nre (EPA OTM

### 27 Equation 8).
Nre = 

### B.64*10I\S*(Ps*MwlTs)*(Qs/u) 

### Nre = 

### 2815 Unit No 4 

### Two

16) ActualParticle CutDiameterfor Cyclone I, D50 (EPA OTM

### 27 Equation 32).


### D50 = 81 • ( [Ts I ( 

### Mw' Ps)[A2091) • ( (u lOs)'.

### 7091) 

### 050

# = 10.47 um 17) Actual Cunningham Correction Factorbasedon Dp 

### =2.5um, 

### C (EPA OTM

### 27 Equation 4).


### C = 1+ 0.0057193' (u/(Ps'Dp))' (Ts/MwyO.5 

### C= 1.0697 18) Initial D50 for Cyclone IVbasedon testcondition Reynolds numberfrom OTM

### 27 Equation 8.
IfNre < 3162, use Equation 

### 33 which results in 

### 050 for IV = 

### If Nre 

### >= 3162, use Equation 

### 34 which results in 

### 050 for iV

### = Initial 

### 050 232 2.22 Equation 33 Equation 34 Equation 35 

### D50 = 

### 0.0024302·(u/Os)A1.1791·(1/C)AO 5·(Ts/(Ps·Mw)),0.6790 D50 = 0 019723·(u/Os)AO.8058·(1/CYO.5·(Ts/(Ps·Mw))AO.3058 Cr = 1 + 

### 0.0057193·(u/(Ps·D50))"(Ts/MwYO.5 19) Re-establishedD50 for Cyclone IV, D50-1. 

### Page 5

Re-established Cunningham, Cr 

### 1.0750 10783

If Nre < 

### 3162, use Equation 

### 36 which results in 

### 050 for IV

# = If Nre 

### >= 3162, use Equation 

### 37whLch results In 

### 050 for iV 

### = Recalculated Cut Oiam, 

### 050-1 2.32 221 Equation 36 Equation 37 

### D50-1 = 0.0024302·(u/Os)A11791·(1/Cr)AO 5'(Ts/(Ps'Mw)yO 6790 D50-1 = 0 019723·(u/OsYO.8058·(1/CryO.5·(Ts/(Ps·Mw)),0.3058 19) Establishing "Z" value, Z.


### If Equation 36 was used, then 

### IfEquation 

### 37 was used, then 

### Z= D50-1/D50= Z = D50-1/D50=
If 

### 0.99 < Z < 

### 1.01, then 

### 050-1 is best cutdiameterestimate. If

### 0.99 > 

### Z > 

### 1.01, then repeat cales for Cr using OSO-1 

### 1.00 1.00

### 3333-PM2.5-R3

Client 

### Project No. Test Location Test Run 

### Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT
INPUT INPUT INPUT
INPUT

INPUT INPUT Vic

# = Vm= 

### Pstatic

# = Pb= 

### Ps

# = Pstd

# = dP 

### = dH = 

### Tm= Ts

# = Tstd= 

### On

# = An

# = y= tr

# = Ds= As= Cp= Kp

# = K1 

# = K2= 

### K3 

### = C1 

### = C2 

### = C3

# = C4= C5= C6

# = B1 

# = Fd 

### =

[02[ [C02[ [N2] 

### AirNova, Inc. EPA Methods 1,2,3,4, OTM 27 and 202 

### (Flows, 

### 02/C02, H20, PM2.5 and CPM) Spruance Genco, LLC 

### 3333 UnitNo, 4 Three 

### 04/21/10 1412-2037

396 

### cc Emission Data



### 118.058 dcf 

### -0.50 in. 

### H20 

### 2996 In 

### Hg 29.92 in. Hg 

### 29.92 in. Hg 

### 0.7667 in. 

### H20 

### ".5

0340 

### in. H20 521.7 R 648.0 R 

### 5277 

### R 0.180 

### m. 0.000177 

### sq. ft. 1.02 

### 371.6 min. 

### 10.300 ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area of nozzle orifice Metercalibration factor, gamma Duration ofsampling time Diameterofstack 83.32 sq, 

### ft Cross sectional area ofstack

0.84 Pitottube coefficient 

### 85.49 ft[(lb/lbmol)'(inHg)]'.5}/[s·R'inH20] Pitot tube constant 17.637 R/in.Hg constant 0.047070 cu.ftlml constant 0.0026688 in.Hg-cf/ml-R

-150,3162 upoise

13.4622 upoise/R"0.5 3861530 upoise/R"2 0.591123 upoise

91.9723 upoise 1.51761E-05 upoise/R"2 0.15625 9705 dscf/MMBtu
Instrumental Data
3.82 %-dry 14.90 %-dry 81.28 %-dry constant Viscosity constant Viscosity constant Viscosity constant Viscosity constant Viscosity constant Viscosity constant Constant Fuel Factor

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project No. 

### Spruance Genco, LLC 3333 Test Location Test Run
Calculations 

### Unit No.4 

### Three

1) Dry Gas Volume atstandardconditions, Vms (EPA OTM

### 27 Equation 27).


### Vms =K1'Y'Vm' (Pb + 

### dH1136) / Tm Vms

### = 122.078 dsef 

### 3457 dscm 2) Drygas sampling rate atstandardconditions, QsST(EPA OTM

### 27Equation 28).


### QsST 

### =Vms I

### tr QsST= 0.329 dscfm 0.009 dsem I 

### min. 3) Volume 

### ofwatervaporcondensedatstandardconditions, Vws (EPA OTM

### 27Equation 29).


### Vws

# =K2'" Vic Vws= 18.640 sef 4) Decimalfraction 

### ofmoisture by volume in stac/(

### gas, Bws (EPA OTM

### 27Equation 30).
Bws

# = Vwstd I 

### (Vmstd+Vwstd) Bws

# = 0.132 5) Molecular weight

### ofthe stackgas on 

### a wet

### basis, Mw (EPA OTM

### 27 Equations 

### 1 &2).
Mw = [((44'%C02) + 

### (32'%02) + 

### (2S'%N2))' (1-Bws) 

## I+ 

### (1S'Bws) Mw

# = 28.88 Ib/lbmole 6) Gas sampling rate 

### at actual Cyclone conditions, Os (EPA OTM

### 27 Equation 31).


### Qs = (PstdlTstd)'QsST' (1/(1-Bws)t(Ts/Ps) Os

# = 0.465 aefm 7) Average stack

### gas velocity, 

### Vs (EPA OTM

### 27Equation 11).


### Vs = Kp' Cp' (ave of(dP)AO.5)· (Ts/Ps'Mw)AO.5 Vs = 47.67 fps 8) Average actualstackgas volumetric flowrate, Qa.
Qa

# = 60 sec/min"Vs " As 

### Qa 

### = 238337.8 cfm 6749.7 cmm 9) Average stackgas drystandard volumetric f/owrate, Qstd.


### Qstd = Qa' (TstdlTs)' (Ps/Pstd)' (1-Bws) Qstd 

### = 168412.6 dscfm 4769.4 dsemm Page 2

### Client Project No. Spruance Genco, LLC 3333 

### Test Location Test Run

Calculations (cant.) Unit No, 4 Three 

### Page 3

10) Analyticaldata Cyclone andFilterFractions (EPA Method OTM27>: M1) Instackquartz microfibre filter, <2.5um
0.0187 9 PM <2.5filter net

### wt M2-4) Cyclone acetonewashes
0.0000 9 actual mass of >2.5, Containers 2&3 0.0026 9 actual mass of <1=2.5um, 

### Container 4 0.0000 9 acetone blank netwt a mL volume 100 mL volume 100 mLvolume
0,0000 9 blank corrected mass of>2.5um, Containers 2&3

# =M2&M3 0.0026 9 blank corrected mass of <1=2.5um, 

### Container 4

# =M4


### Condensible Particulate Matter(CPM) Fractions (EPA Method202): M5) Back HalfAqueous Wash
0.0058 9 actual sample mass 0.0001 g aqueous blank mass 300 ml blank vol. 300 ml Samplevolume
0,0057 9 condensible aqueous PM M6) Back Half MeCI2 Extraction Portion
0.0003 9 extraction netwt 0.0000 9 MeCI2 blank netwt 300 ml blankvol. 300 ml MeCI2 extraction volume
0.0003 9 condensible organic PM M[CPM]

### = blank corrected mass of Total CPM, M5 & M6 (in grams) M[CPM] = 0.0060 9 CPM 

### 11) Particulate Concentrations, C 

### (EPA OTM27andEPA 202).

Equation 43 Equation 45

EPA 202 C[totalsus] = M 1(g)+M2(g)+M3(g)+M4(g)'15A3(grains/g)Nmstd(dscf)= C[PM2.5sus] = M1 (g) + M4(g) • 15.43(grains/g) 

### 1Vmstd(dscf) = C[CPM] = M[CPM](g)' 15.43(grains/g) 

### 1Vmstd(dscn where 15.43

# =7000/453592'*1000 

### C[PMtotal] = C[PMtotalsus] + C[CPM] C[PM2.5total] = C[PM2.5sus] 

### + C[CPM] 0.0027 gr/dscf PMsus 0.0027 gr/dscf PM2.5sus 0.0008 gr/dscfCPM
0.0035 gr/dscfTolal PM 0.0035 gr/dscfTotal PM2.5

### Client Project No. Spruance Genco, LLC 3333



### 12) Particulate Emission Rates, 

### E. Test Location Test Run

Calculations (cont.) Unit NO.4 Three

E[lb/hr[

# = c[lIgr/dscf) • (1 

### Ib/7000 gr) • Qstd(dscfm) • 60(min/hr) E[lb/MMBtu] = C[](gr/dscD' (1 

### Ib/7000 gr)' Fd(dscf/MMBtu)' 

### (20.9/20.9-%02) E[totalsus]

# = 3.89 Ib/hrtotal sus PM E[totalsus]

# = 0.0046 Ib/MMBtu total sus PM E[PM2.5sus]

# = 3.89 Ib/hr PM2.5sus

# = 78 0 

### % ofTotal PM2.5 E[PM2.5sus]

# = 0.0046 Ib/MMBtu PM2.5sus

# = E[CPM]

# = 1.09 Ib/hrCPM 22 0 % ofTotal PM2.5 E[CPM]

# = 0.0013 Ib/MMBtu CPM E[PMtotal]

# = 4.98 Ib/hrtotal PM E[PMtotal]

# = 0.0059 Ib/MMBtu total PM E[PM2.5total]

# = 4.98 Ib/hrtotal PM2.5 E[PM2.5total]

# = 0.0059 Ib/MMBtu total PM2.5 

### 13) Percent Isokinectlc Sampling, %1 

### (EPA OTM27 

### Equation 40).

% 1.= [1**OO*Ts~Vms*Pstd)** 

### I (60"'Vs"tr"An"'Ps"{1-Bws)*Tstd) % 

### I 

### = 91.98 

### 14) Stack Gas Viscosity, U 

### (EPA OTM27 

### Equation 3).

II

# = C1 

### + C2"(Ts"O.5) 

### + C3*(Ts"-2) 

### + C4*(%02)

- (C5"'Bws) 

### + C6*Bws*(Ts"2) u

# = 192.5 micropoise 

### Page4

### Client Project No. Spruance Genco, LLC 

### 3333 Test Location Test Run

Calculations (cant.) 15) Test Condition Reynolds number, Nre (EPA OTM

### 27 Equation 8).


### Nre

# = 8.64*101\5*(Ps*MwlTs)*(Qs/u) Nre

## = 2783 Unit No.4 Three

16) ActualParticle CutDiameterfor Cyclone /, D50 (EPA OTM

### 27 Equation 32).


### 050= B1 '( [TsI(Mw' Ps)['.2091)'((uIQs)'.7091) 050

### = 10.55 um 17) Actual Cunningham Correction Factorbasedon Dp

# = 2.5um, 

### C (EPA OTM

### 27 Equation 4).


### C

# =1+ 00057193'(ul(Ps'Op))' (TsIMw)'0.5 C

# = 10697 1B) Initial 050 for Cyclone IVbasedon testcondition Reynolds numberfrom OTM

### 27Equation B.


### If Nre < 

### 3162, use Equation 33 which results in 050 for 

### IV = IfNre >= 3162, use Equation 34 which results in 050for iV

# = Initial 050 

### 2.35 2.24 Equation 33 Equation 34 Equation 35 

### 050=0.0024302'(uIQs)'1.1791'(1IC)'0.5'(TsI(Ps'Mw)),0.6790 050=0.019723'(uIOs),0.8058'(11C)'0.5'(TsI(Ps'Mw)),0.3058 Cr

# =1 +0.0057193'(ul(Ps'050)nTsIMw),0.5 19) Re-established050 for Cyclone IV, 050-1 

### Page 5

Re-established Cunningham, Cr 

### 1.0740 10777

IfNre < 

### 3162, use Equation 36 which results in 050 for IV = If Nre >= 3162, use Equation 37 which results in 050 for iV

# = Recalculated Cut Oiam, 050-1 

### 2.35 2.24 Equation 36 Equation 37 

### 050-1 

# = 0.0024302'(uIQs)'1.1791'(1/Cr)'0 5'(TsI(Ps'Mw)),0.6790 050-1 = 0.019723'(uIQs),0.8058'(1ICr)'0.5'(TsI(Ps'Mw)),0.3058 19) Establishing 

### liZ" value, Z.


### If Equation 36 was used, then Z = 050-11 050 = If Equation 37 was used, then Z = 050-1 

### I 050 = If 0.99 <

### Z < 

### 1.01, then 050-1 is best cut diameter estimate If0.99> Z > 1.01, then repeat calcs for Cr using 050-1 

### 1.00 1.003333-TSP-Metals-R1

Client Project No. Test Location Test Run Test Date Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vlc= Vm= Pstatic = Pb= Ps = Pstd ::: dP = dH = Tm = Ts = Tsld= Dn = An = y= t= Ds 

### = As = Cp = Kp= K1 = K2 = K3 = Fd =

[02) [C02) [N2) 

### AirNova, Inc. EPA Methods 1,2,3A,4,5 and 29 (Flows, 02/C02, H20, TSP and Metals) 

### Spruance Genco, LLC 

### 3333 Unit No.4 One 

### 04/20/10 

### 0925-1545

760.0 cc 252.753 dcfEmission Data

-0.50 in, H20 30.04 in. Hg 30.00 in. Hg 29.92 in. Hg 0,7539 in. H20A.5

1.322 in. H20 544,7 R 651.2 R 527.7 R 0.240 in. 0.000314 sq, ft, 0.97 360 min. 10.30 ft. Vol. ofH20 collected 

### Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq,rt delta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area ofnozzle orifice Meter calibration factor Duration ofsampling time Diameterof stack 83.3204 sq. ft. Cross sectional area of stack 0.84 Pitottube coefficient 85.49**ft[(lbJlbmolt(inHg)1~.5}J[s·R*inH201** Pitottube constant 17.637 RJin.Hg 0.047070 cU.ftlml 0.0026688 in.Hg-cfJml-R 9777 scf/MMBtu

Instrumental Data

4.14 %-dry

15.40 %-dry

80.46 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 Test location Test Run

Calculations 1) Volume of gas sampled atstandard conditions,Vmstd.

Vmstd**=K1~**y.Vm**~** (Pb + dH/13.6) ITm Vmstd = 239.243 dscf 6.775 dsem Unit No, 4 One

2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2 *Vic Vw(std) = 35.773 sef 3) Decimal fraction of moisture byvolume instack gas, Bws.

Bws =Vwstd I (Vmstd+Vwstd) Bws= 0.1301
4) Molecularweight ofthe stack gason awet basis, Ms.

Ms =**[«44~%C02)** + (32*%02) + (2S*%N2» * (1-Bws) 

## 1 + (18*Bws) Ms= 28.987 Ib/lbmole 5) Average stack gas velocity, Vs.

Vs = Kp * Cp· (dP) ***(TslPs~Ms)",5** Vs= 46,850 fps G) Average actual stack gas volumetricflowrate, Oa.
Qa =60 sec/min·Vs *As Qa = 234213.54 cfm 6632.93 cmm 7) Average stack gasdryvolumetric flowrate, Qstd.
Qstd = Qa**~** (TstdlTs) * (Ps/Pstd) * (1-Bws) Qstd = 165566,46 dscfm 4688,84 dsemm Page 2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run Unit No.4 

### One
Calculations (cont.) 8) Particulate MaHerAnalytical Data
INPUT 

### A 0.1666 9 INPUT B 100 ml INPUT 

### C 0.0830 9 INPUT 

### 0 100 ml INPUT E 0.0000 g 9) Particulate sample mass calculations

H



### J Front Half: Acetone blank adj. residuev Adj. Acetone wash part,wt. Front half sample

### wt. 10) Front Half Particulate Matter Emission Data Filter sample netwt Front acetone wash vol. Front acetone residuewt. Acetone blank vol. Acetone blank residuewt.

0.0000 9 0.0830 9 0.2496 9 E"(BIO) 

### C-H A+'

C[PM] = (Front HalfWt)(g)" (1Nmstd) ,. 1S.43(grainsfg) E[PM] = C[PM] * Vdscfm"A ., (60 min/hr)" (1 Ib f7000 grains) Page 3

E[PM]lbfMMBtu = E[PM]lbfhr*(Fuel HV) scffBtu*(fuel use) 1 hour/kscf*kscff1000scf"10"6Btu/MMBtu C[PM] = 1.61E-02 grainS/dscf C[PM] = 2.30E-06 Ibfdsef E[PM] = 22.84S Ibfhr E[PM] = 2.80E-02 IbfMMBtu
11)Trace metal concentrations and emission rates

Element Antimony Arsenic Beryllium Cadmium Chromium

Cobalt Lead Manganese Nickel Selenium C[M] = M[M] (ug) / Vmstd (dsem) C[M](lb/dsef) 

### =C[M](ug/dsem) • 1e-06g/ug * 2.205e-03Ib/g"0,02832 dsem/dsef E[M](lb/hr) 

### =C[M] (ug/dsem) * (2.20SE-09) (Ib/ug) * Qstd (dsemm) * 60 (min/hr) E[M](lb/MMBtu) = C[M](lb/dsef) • Fd * (20.9120.9-%02) C[M](@ corr. 02) = C[MJ (ug/dscm) * [ (20.9-corrected %02)/ (20.9-actual %02) 1 Corrected 02 percentage is: 7.0 % Sample Cone. QQn!;;.@!<QIT. 02 Cone. Emission Rate Mass (ug) (ug/dscm) (ug/dsem) (lb/dscQ Ob/hr)

1.422 2.10E-01 1.74E-01 1.31E-11 1,30E-04 9.253 1.37E+OO 1.13E+OO 8.S3E-11 R47E-04 1.64 2.42E-01 2.01E·01 1.S1E-11 1.S0E-04 0.705 1.04E·01 8,63E·Q2 6.S0E-12 6.4SE-05 11.265 1,66E+OO 1,38E+OO 1.04E-10 1.03E-03 5,67 8.37E-01 6.94E·01 5.23E-11 5.19E-04 10.951 1.62E+00 1.34E+00 t01E-10 1.00E-03 10,555 1.S6E+00 1.29E+00 9,73E·11 9.66E-04 16.134 2.38E+OO 1.97E+OO 1,49E-10 1.48E-03 3.99 S.89E-01 4.88E-01 3,68E-11 3.65E-04 12) Isokinecity, I. 

### % I=**[100~Ts*(K3*Vlc+«(Vm"Y)fTm)*(Pb+(dH/13.6»»11** (60*t*Ps*Vs*An) %1= 106,46
" < " symbol indicates values given are the quantitative detection limit. Emission Rate (lbfMMBtu) 1.S9SE-07 1.040E-06 1.843E-07 7.922E-08 1.266E-06 6.371E-07 1.231E-06 1,186E-06 1.813E-06 4.484E-073333-TSP-Metats-R2

Client Project No. Test Location Test Run Test Date Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vlc= Vm= Pstatic '" Pb = Ps = Pstd '" dP= dH = Tm= Ts = Tsld= On = An 

### = y= t= Os = As = Cp = Kp = K1 = K2= K3= Fd 

### =

[02[
[C02[
[N21 

### AirNova, Inc. EPA Methods 1,2,3A,4,5 and 29 (Flows. 02lC02, H20.TSP and Metals) 

### Spruance Genco, LLC 

### 3333 Unit No, 4 Two 

### 04/21/10 0711-1317

Emission Data
769,2 cc 241.455 dcf -0.50 in, H20 29.96 in. Hg 29,92 in, Hg 29.92 in, Hg 0_7634 in. H20 A,S

1.239 in. H20 524.2 R 647.4 R 527.7 R 0.240 in. 0.000314 sq, 

### ft, 0.97 360 min, 10.30 ft. 83.3204 sq. ft. 0.84 Vol, of H20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rtdelta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area of nozzle orifice Metercalibration factor Duration ofsampling time Diameterof stack Cross sectional area ofstack Pitot lube coefficient 85.49 ft[(lb/lbmol)*(inHg)]A.5}1[s*R*inH20] Pitot tube constant 17.637 R/in.Hg 0.047070 cU.fVml 0,0026688 in,Hg·cf/ml-R 9920 scf/MMBtu

instrumental Data

3.86 %-dry

14.95 %-dry

81.19 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nlirogen concentrationClient Project No. Spruance Genco, LLC 3333 Test Location Test Run

Calculations
1) Volume ofgassampled atstandard conditions, Vmstd.

Vmstd =K1* Y"Vm * (Pb + dH/13.6) I Tm Vmstd = 236.808 dscf 6.706 dscm Unit No.4 

### Two

2) Volume ofwatervaporcollected atstandard conditions, Vw(std). VW(std) = K2 "Vic Vw(std) = 36.206 sd
3) Decimal fraction ofmoisture byvolume in stack gas, Bws.

Bws =Vwstd I (Vmstd+Vwstd) Bws= 0.1326
4) Molecularweight ofthe stack gason a wet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28·%N2»·(1-Bws) 

## 1 + (18*Bws) Ms= 28.883 Ib/lbmole
5) Average stack gasvelocity, Vs.

Vs = Kp· Cp" (dP) • (Ts/Ps*Ms)".5 Vs = 47.449 fps
6) Average actual stack gasvolumetric flowrate, Qa.
Qa = 60 sec/min"Vs ;0As Qa = 237207.79 cfm 6717.72 cmm 7) Average stack gas dryvolumetricflowrate, Qstd.
Qstd = Qa" (TstdlTs) ., (PslPstd)" (1-Bws) Qstd = 167735.15 dscfm 4750.26 dscmm Page 2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run Unit No.4 

### Two
Calculations (cont.) 8) Particulate MatterAnalytical Data INPUT A 0.1208 9 INPUT 

### 8 100 ml INPUT 

### C 0.0776 9 INPUT D 100 ml INPUT E 0.0000 9 9) Particulate sample mass calculations

H

J Front Half: .Acetone blank adj. residuev Adj. Acetone wash partwt. FrOnt halfsample wt. 10) Front HalfParticulate Matter Emission Data Filter sample netwt Front acetone wash vol. Front acetone residue wt. Acetone blankvol. Acetone blank residue wt.

0.0000 9 0.0776 9 0.1984 9 E"(8/D) C-H A+ I

C[PM] 

### =(Front HalfWt){g)" (1Nmstd) " 15.43(grains/g) E[PM}:o C[PM]·Vdscfm • A "(SO minlhr)**~** (1 Ib/7000 grains) Page 3

E[PM} Ib/MMBtu = E[PM)lb/hr*(Fuel HV) scflBtu"*(fuel use) 1 hour/kscrkscf/1000scf"10"6Btu/MMBtu C[PM] = 1.29E-02 grains/dscf C[PM] = 1.85E-06 Ib/dscf E[PM] = 18.586 Ib/hr E(PM] = 2.25E-02 Ib/MMBtu 11)Trace metal concentrations and emission rates

Element Antimony Arsenic Beryllium Cadmium Chromium

Cobalt Lead Manganese Nickel Selenium C[M) = M[M) (ug) IVmstd (dscm) C[M](lb/dscf) = C[M)(ug/dscm)" 1e·OSg/ug·2.205e-03Ib/g" 0.02832 dscm/dscf E[M](Ib/hr) = C[M) (ug/dscm)

.. (2.205E-09) (Ib/ug) • Qstd (dscmm)·60 (min/hr) E[M](lb/MMBtu) c: C[M)(lb/dscf)" Fd

.. (20.9/20.9-%02) C[M](@ carr. 02) = C[M] (ug/dscm) "[ (20.9-corrected %02) I (20.9-actual %02) I Corrected 02 percentage is: 7.0 % Sample Cone. Conc.@corr. Q2 Cone. Emission Rate Mass (ug) (ug/dscm) (ug/dscm) (lb/dscQ (Ib/hr)

1.593 2.38E-01 1.94E-01 1.48E-11 1.49E-04 7.809 i.16E+OO 9.50E-01 7.27E-11 7.32E-04 1.29 1.92E-01 1.57E-01 1.20E-11 1.21E-04 0.51S 7.69E-02 6.28E-02 4.80E-12 4.84E-05 10.731 1.S0E+OO 1.31E+00 9.99E-11 1.01E-03

5.1 7.60E-01 6.20E-01 4.75E-11 4.78E-04 9.763 1.46E+OO 1.19E+00 9.09E-11 9.15E·04 9.787 1.46E+OO 1.19E+00 9.11E-11 9. 17E-04 12.847 192E+OO 1.56E+00 1.20E-10 1.20E-03

3.1 4.62E-01 3.77E-01 2.89E-11 2.91E-04 12) Isokinecity, I.
% I= [100*TS*(K3"*Vlc+«(Vm·Y)!Tm)*(Pb+(dH/13.S»)))] I (60·t*Ps*Vs"An) %1= 104.01

n < n symbol indicates values given are the quantitative detection limit. Emission Rate (lb/MMBtu) i.805E-07 8.847E-07 1.461E-07 5.846E-08 1.2i6E-OS 5.778E-07 1.1 OSE-OS 1.109E-06 1.455E-06 3.512E-073333-TSP-Metals-R3

Client Project No. Test Location Test Run Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vlc= Vm= Pstatic = Pb = Ps = Pstd = dP = dH = Tm= Ts 

### = Tstd= Dn = An = y= t= Ds= As= Cp = Kp = K1 = K2 = K3= Fd =

[02[ [C02[
[N2[ 

### AirNova, Inc. EPA Methods 1,2,3A,4,5and 29 (Flows, 02lC02, H20, TSP and Metals) 

### Spruance Genco, LLC 

### 3333 Unit No.4 Three 04/21/10 

### 1412-2037

Emission Data

751.2 cc 235.369 dcf -0.50 in. H20 29.96 in. Hg 29.92 in. Hg 29.92 in. Hg 0.7635 in. H20 ".5

1.213 in. H20 523.5 R 648.7 R 527.7 R 0.240 in. 0.000314 sq. ft. 0.97 360 min. 10.30 

### ft. 83.3204 sq. 

### ft. Vol. of H20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average meter temperature Average stacktemperature Standard temperature Nozzle diameter Area of nozzle orifice Metercalibration factor Duration of sampling time Diameter ofstack Cross sectional area ofstack 0.84 Pitottube coefficient 85.49**ft[(lbJlbmol)~{inHg)]".5}J[s·R·inH201** Pitot tube constant 17.637 R/in.Hg 0.047070 cu.fUml 0.0026688 in.Hg-cf/ml-R 9705 scf/MMBtu

Instrumental Data

3.82 %-dry

14.90 %-dry

81.28 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 TestLocation Test Run

Calculations
1)Volume ofgas sampled at standard conditions, Vmstd.

Vmstd =K1*

### y;o Vm· (Pb + dH/13,6) ITm Vmstd = 231,156 dscf 6,546 dsem Unit No.4 Three

2) Volume ofwatervaporcollected atstandard conditions, Vw(atd).
Vw{std) = K2 ;0 Vic Vw(std) = 35.359 scf
3) Decimalfraction ofmoisture byvolume instack gas, Bws.

Bws = Vwstd f (Vmsld+Vwstd) Bws= 0.1327
4) Molecularweightofthe stack gas on a wet basis, Ms.

Ms '"**[«44~%C02)** + (32*%02) + (28*%N2)) * (1-Bws) 

### 1 + (18"'Bws) Ms= 28.874 Ib/lbmole
5) Average stack gasvelocity, Vs.

Vs = Kp**~** Cp" (dP)**~** (Ts/Ps*Ms)".5 Vs= 47.510 fps
6) Average actual stack gasvolumetric flowrate, Qa.
Qa = 60 sec/min·Vs**~** As Qa = 237511,54 cfm 6726.33 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa * (TstdlTs)· (PslPstd) ;0 (1-Bws) Qstd = 167594.05 dscfm 4746.26 dscmm Page 2Client Spruance Genco, LLC Project No. 3333 Test Location Test Run Unit No.4 Three Calculations (cont.) 8) Particulate MatterAnalytical Data
INPUT A 0.1824 9 INPUT B 100 ml INPUT 

### C 0,0909 9 INPUT D 100 ml INPUT E 0.0000 9 9) Particulate sample mass calculations

H



### J Front Half: Acetone blank adj. residue v Adj_ Acetone wash part.wt, Front halfsample wt. 10) Front Half Particulate Matter Emission Data Filter sample netwt Front acetone wash vol. Front acetone residue wt. Acetone blank vol. Acetone blank residuewt.

0,0000 9 0,0909 9 0.2733 9 E"( BID) C-H A+ I

C[PM] = (Front HalfWt)(g) • (1Nmstd)" 15.43(grains/g) E[PM] = C[PM] " Vdscfm

.. A

.. (60 min/hr) "(1 Ib 17000 grains) Page 3

E[PM) Ib/MMBtu = E[PM] Ib/hr·(Fuel HV)**scf/Btu~(fuel** use) 1 hour/kscrkscf/1000scr10"6Btu/MMBtu C[PM] = 1.82E-02 grains/dscf C[PM] = 2.61E-06Ibfdscf E[PM] = 26.207 Ib/hr E[PM] = 3.09E-02 Ib/MMBtu 11)Trace metal concentrations and emission rates

Element Antimony Arsenic Beryllium Cadmium Chromium

Cobalt leaa Manganese Nickel Selenium C[M] = M[M] (ug) 1Vmstd (dscm) C[M](lb/dscf) 

### =C[M](ug/dscm) w 1e-06g/ug"2.205e-03Ib/g·0.02832 dscm/dscf E[MJ(lb/hr) ., C[MJ (ug/dscm)

.. (2.20SE-09) (Ib/ug)

.. Qstd (dscmm) "60 (minfhr) E[M)(lb/MMBtu) " C[M](lb/dscf) W Fd W (20.9120.9-%02) C[M)(@ corr. 02)

### =C[M] (ug/dscm)" [ (20.9-corrected %02) I (20.9-actual %02)] Corrected 02 percentage is: 7.0 

### % Sample Conc.**QQn~@Qilrr_** Q2 Conc. Emission Rate Mass lug) (ug/dscm) (ug/dscm) (Ib/dscf) (lb/hrl 4.1 6.26E·01 S 10E·01 3.91E-11 3.93E-04 8.949 1,37E+00 1.11E+00 8 S4E·11 8.S8E-04 1.801 2_7SE-01 2.24E-01 1.72E·11 1.73E-04 0.688 1,OSE-01 8,S5E-02 6,S6E-12 6.6DE-OS 10.563 1,61 E+OO 1.31E+OO 1,01E-10 1.01E-03 6.24 9.S3E-01 7.76E-01 5.9SE·11 S.99E-04 11.S3 1.76E+00 1.43E+00 1.10E-10 1.11E-03 11.25 1.72E+OO 1.40E+OO 1.07E-10 i.0BE-03 16.22 2.48E+OO 2.02E+OO 1,SSE-10 i.S6E-03 4.29 6,SSE-01 5,33E-01 4,09E-11 4.12E-04 12) Isokinecity, I.
% I= [100*TS*(K3'Vlc+«(Vm"Y)fTm)*(Pb+(dH/13,6»)))] I (60*t*Ps"VsWAn) %1= 101.61
" <"symbol indicates values given are the quantitative detection limit. Emission Rate {lb/MMBtu) 4,64SE-07 1,014E-06 2,040E-07 7794E-08 1.197E-06 7.069E-07 1.306E-06 1.274E-06 1.837E-06 4.860E-07

### 3333-Hg-unspiked-R1

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT INPUT Vm= Pstatic

# = Pb = 

### Ps = 

### Pstd = 

### Tm= INPUT Ts = INPUT Tstd= INPUT y= INPUT t = INPUT Os = 

### AirNova, Inc. EPA Method 

### 1, 2, 3A, and 

### 30B

- Unspiked Tube (Flows, 

### 02/C02, and Mercury) 

### Spruance Genco, LLC 

### 3333 Umt No.4 One 04/20/10 

### 0925-1525

Emission Data

5.490 dcf -0.50 in. H2O 30.04 in. H9 

### 30.00 

### m. H9 

### 29.92 

### m. H9 

### 541.3 

### R 651.2 R 

### 527.7 R 1.000

360 min. 10.30 

### ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stack temperature Standard temperature Meter calibration factor DuratIon ofsampling time Diameter of Stack As = 8332043375 sq. 

### ft. Cross sectional area ofstack



### INPUT

INPUT

INPUT Kp = 85.49**ft[(lb/lbmol)~(inHg)1".5}1[s*R*lnH201** 

### K1 = 

### K2 = 

### K3 

### = Fd 

### =

[02[
[C02[
[N2[ 

### 17.637 R/in.Hg 0.047070 cU.fUml 0.0026688 In.Hg-cf/ml-R 9777 scf/MMBtu

Instrumental Data

4.14 %-dry

15.40 %-dry

80.46 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration Nitrogen concentrationClient Spruance Genco, LLC Test Location Test Run Project No. 3333

Calculations
1)Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd**=K1~** Y·Vm * Pb/Tm Vmstd = 5.374 dscf 0.1522 dscm
3) Decimal fraction of moisture byvolume in stackgas, Bws.

INPUT Bws '" Bws = Based on the M29 sampling train 0.1301 4) Molecularweightofthestackgas on a wet basis, Ms. Unit No.4 One

Ms = [«44*%C02) 

### + (32*%02) 

### + (28*%N2» * (1-Bws)] 

### + (18*Bws) Ms = 28.986 Ib/lbmole
5) Average stackgas velocity, Vs.

INPUT Vs 

### = Vs = Based on the M29 sampling train 46.850 fps
6) Average actual stackgas volumetricflowrate, Qa.

Oa =60 sec/min ;0 Vs * As Oa 

### = 234213.74 cfm 6632.93 cmm 7) Average stackgas dryvolumetricflowrate, Qstd.

Ostd =Oa ;0 (TstdlTs) • (Ps/Pstd) * (1-Bws) Ostd = 165562.09 dscfm 4688.72 dscmm
8) Mercury concentrationsand emission rates

Element Mercury C[M]

# = M[M] (ug) 

### IVmstd (dscm) C[M](Jb/dscf) '" C[M](ug/dscm) *1e-06g/ug· 2.20Se-03Ib/g· 0.02832 dscm/dscf E[M](Ib/hr) = C[M] (ug/dscm) • (2.20SE-09) (Ib/ug) 

### *Ostd (dscmm)

.. 60 (min/hr) E[M](Ib/MMBtu) = C[M](lb/dscf) * Fd • (20.9/20.9-%02) C[M](@ corr. 02) = C[M] (ug/dscm)

.. [(20.9-corrected %02) 

### I (20.9-actual %02)] Corrected 02 percentage is: 7 %
Sample Mass lug)

0.0018 Conc. (ug/dscm)

0.012 Conc.@COIT. 02 (ug/dscm)



### 0.010 Conc. (lb/dscO 7.39E-13 EmissIon Rate (Ib/hr) 7.34E-06 Page 2

Emission Rate

(lb/MMBtu) 9.01E-093333-Hg-unspiked-R2

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT INPUT Vm= Pstatic = Pb = Ps = Pstd = Tm= INPUT Ts = INPUT Tstd= INPUT Y = INPUT t = INPUT Ds=



### INPUT

INPUT

INPUT As 

### = Kp 

### = K1 

# = K2= K3 

### = Fd =

[02]
[C02]
[N2] 

### AirNova, Inc. EPA Method 1, 2, 3A, and 30B

- Unspiked Tube (Flows, 021C02, and Mercury) 

### Spruance Genco, LLC 

### 3333 Unit No.4 

## Two 04/21/10 

### 0711-1311

Emission Data

8.462 dcf -0.50 in. H2O 29.96 in Hg 29.92 in. Hg 29.92 in Hg 527.1 

### R 647-4 R 527.7 R 1.000

360 min 10.30 ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stacktemperature Standard temperature Meter calibration factor Duration ofsampling time Diameter of Stack 83.32043375 sq. ft. Cross sectional area ofstack 8549 ft[(lb/lbmolt(inHg)]".5}/[s*R*inH20] 17637 R/in.Hg 0.047070 cu.ftlml 0.0026688 in.Hg-cf/ml-R 9920 scf/MMBtu

Instrumental Data

3.86 %-dry
14.95 %-dry

81.19 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentration

### Client Project No. Spruance Genco, LLC 3333 Test Location Test Run
Calculations
1)

### Volume ofgas sampled at standard conditions, Vmstd.

Vmstd =K1* 

### Y"Vm

.. Pbl Tm Vmstd = 8.483 dscf 0.2402 dscm
3) 

### Decimal fraction ofmoisture byvolume in stackgas, Bws.

INPUT Bws= Bws= Based on the M29 sampling train 0.1326
4) 

### Molecularweightofthestackgas on awet basis, Ms. 

### Unit No.4 

### Two

Ms = [((44*%C02) + (32*%02) + (28"*%N2» * (1-Bws)] + (18*Bws) Ms = 28883 Ib/lbmole
5) 

### Average stack gasvelocity, Vs.

INPUT Vs 

### = Vs = 

### Based on the M29 sampling train 47.449 fps 6) Average actual stack gasvolumetric flowrate, Oa.
Oa =60 sec/min "* Vs

... As Qa = 

### 237208.28 cfm 6717.74 cmm 7) Average stack gas dryvolumetricflowrats, Qstd.
Ostd = Qa'" (TstdfTs)" (Ps/Pstd)" (1-Bws) Qstd = 167729.95 dsefm 4750.11 dsemm 8) Mercury concentrations and emission rates C[M] = M[M] (ug) /Vmstd (dsem) C[M](Ib/dscf) = C[M](ug/dscm)

.. 1e-06g/ug

... 2.205e-03Ib/g

... 0.02832 dsem/dscf E[M](lb/hr) =C[M] (ug/dscm)

.. (2.205E-09) (Ib/ug)

.. Ostd (dscmm)

... 60 (min/hr) E[M](tb/MMBtu) = C[M](lb/dscf)

... Fd

... (20.9120.9-%02) 

### C[M](@ corr. 02) =C[M] (ug/dsem)

... [ (20 9-corrected %02) I (20.9-actual %02)] Corrected 02 percentage is. 

### 7 

### %
Sam!;!le Cone Conc.@corr. 02 

### Cone. Emission Rate Element Mass (ug} (ug/dscm} (ug/dsem) (Ib/dscf) (Ib/hr) Mercury 0.0033 0.014 0.011 8.58E-13 

### 863E-06 Page 2

Emission Rate

(lb/MMBtu)

1.04E-083333-Hg-unspiked-R3

Client Project No. Test Location Test Run Test Date Time Period

INPUT INPUT 

### INPUT

INPUT 

### INPUT INPUT INPUT INPUT



### INPUT

INPUT

INPUT Vm= Pstatic

### = Pb 

### = Ps = Pstd = Tm= Ts = Tstd= y= t= Os = As 

### = Kp 

### = K1 = K2= K3 

### = Fd 

### =

[02] [C02]
[N2] 

### AirNova, Inc. EPA Method 1, 2, 3A, and 30B· Unspiked Tube (Flows, 

### 02fC02, and Me,rcury) 

### Spruance Genco, LLC 

### 3333 Unit No.4 Three 

### 04/21/10 

## 1412-2012

Emission Data

7.962 dcf -0.50 in, H20 29.96 in. Hg 29.92 in. Hg 29.92 

### m. Hg 531.8 R 648.7 

### R 527.7 R 1.000

360 min. 10.30 

### ft. Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling lime Diameterof Stack 83.32043375 sq. ft Cross sectional area ofstack 85.49 ft[(lb/lbmolt(lnHg)]A.5}/[s*R*inH20] 17.637 R/in.Hg 0.047070 cu.fVml 00026688 in.Hg-cf/ml-R 9705 scf/MMBtu

Instrumental Data

3.82 %-dry

14.90 %-dry



### 81 28 %-dry constant constant constant Fuel Factor

Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Spruance Genco, LLC Test Location Test Run Project No. 3333

Calculations
1)Volume ofgassampled atstandardconditions,Vmstd.

Vmstd =K1* Y * Vm * Pb/Tm Vmstd = 7.911 dscf 0.2240 dscm
3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

INPUT Bws 

### = Bws 

### = Based on the M29 sampling tram 0.1327
4) Molecularweight ofthe stackgas on a wet basis, Ms. Unit No.4 Three

Ms = [«44*%C02)

### + (32*%02) 

### + (28*%N2» * (1-Bws)] 

### +(1B*Bws) Ms= 28.873 Ib/lbmole
5) Average stack gasvelocity, Vs.

INPUT Vs= Vs '" Based on the M29 sampling train 47.510 fps
6) Average actual stack gas volumetricflowrate, Qa.

Oa = 60 sec/min"Vs

.. As Oa = 237513.23 cfm 6726.37 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.

Ostd = Oa· (TstdfTs)· (PsiPstd)· (1-Bws) Ostd = 167589.69 dscfm 4746.14 dscmm
8) Mercuryconcentrations andemission rates

Element Mercury C[MI 

### =MIMI (U9) I Vmstd (dscm) C[M](Ib/dscf) = C[MJ(ug/dscm) * 1e-06g/ug * 2.205e-03Ib/g * 0.02832 dscm/dscf E[M](Ib/hr) '" C[M] (ug/dscm) • (2.20SE-09) (Ib/ug)

.. Qstd (dscmm)

.. 60 (min/hr) E[M](lb/MMBtu) = C[M](lb/dscf) * Fd " (20.9120.9-%02) C[M](@ corr. 02) = C[M] (ug/dscm) • [(20.9-corrected %02) 1(20.9-actual %02) ] Corrected 02 percentage is. 7 %
Sample Mass (ug)

0.0048 Conc. (ug/dscm)

0.021 Conc.@corr. 02 (ug/dscm)

0.017 Conc. (lb/dscf) 1.34E-12 Emission Rate (Ib/hr) 1.35E-05 Page 2

Emission Rate

(Jb/MMBtu)



### 1.59E-08M7ED/F

Client Project No. Test location Test Date Spruance Genco, LlG 

### 3333 Unit 4 DfF 04/20110

Parameter: InstrumentSpan (% 

### 02/: 

### Oxygen 22.08

Actual Calibration Gas Value (% 

### 021: AnalYZerGallbration Response (% 

### 02/.- AnalvzerCalibration Error(% Span): Run 1

ZerQ System Calibration Gas AQQarent Init. Sys. 

### Init. Sys. Final**S~.** Final SysStack Galib_ Cal. Bias Galib. Qa/. Bias 

### Run Conc. Response (% sQan) ResQonse (% span/



### 1 4.21 0.10 0.36 0.09 0.32 2 

### 0.00 0.09 0.32 0_00 -0.09 

### 3 0.00 

### 000 -0.09 0_00 -0.09 4 

### 0.00 0.00 -009 0.00 -0.09 

### 5 0.00 0_00 -0.09 

### 000 -0.09 

### 6 0.00 0.00 -0.09 0.00 -0.09 

### 7 0.00 0.00 -009 0.00 -0.09 B 

### 0.00 

### 0.00 -0.09 0.00 -0.09 

### 9 0.00 0.00 -009 0.00 

### -0.09 10 0.00 0.00 -0.09 

### 000 -0.09 

### 11 0.00 0.00 -0.09 

### 000 -0.09 

### 12 0.00 0.00 -0.09 0_00 -0.09 

### AirNova. Inc. EPA Method7E Calculations (Cal. Error, Bias Driftand BiasAdjustment)

zero 

### 0.00 0_02 0.09 AnalvzerCa/ib. Gases low 

### !11iJ1. N/A 11.90 N/A 

### 0.00 11_89 -005 high 

### 22.08 21.89 -0.86

Uescale System Calibration Gas**~** Init. 

### S:ys Init. Sys. Final Sys. Final S\"s. Qaff; Galib. Cal. Bias 

### !&Ji!L Cal.**Bia~** (% span) Response (% span) Response (% sQanl



### -0,05 11_90 

### 0.00 11.98 0_36 -041 11 

### 98 0.36 0.00 -53.89 0.00 0.00 -53_89 0.00 -53.89 0.00 0.00 -53_89 0.00 -53.89 

### 000 0.00 -53.89 0.00 -53.89 0_00 0.00 -53_89 0.00 -53.89 0.00 0.00 -53.89 0.00 -53.89 

### 000 0.00 -53_89 0.00 -53.89 0_00 0.00 -53.89 0.00 -53.89 0.00 0.00 -53_89 0.00 -5389 0_00 0.00 -5389 0.00 -53_89 

### 000 0.00 -53.89 0.00 -53_89 Upscale Sys. Gal. Gas 

### 11 90 11.90

Galib. Drift f% span)



### 0.36 -54.26

0_00 

### 000 0.00 

### 000 0.00 0_00 0.00 0.00 0.00 0.00 Page 1

Actual Stack Conc.



### 4.13 -0.09 

### ERR ERR ERR ERR ERR ERR ERR ERR ERR ERRM7EDfF

Client Project No. Test Location Test Date Spruance Genco, lLC 

### 3333 Unit4 04120/10

Parameter: Instrument Span (% C02): 

### Carbon Dioxide 22.28

Actual Calibration Gas Value (% C02). AnalvzerCa/ibration Response (% C02): Ana/k:zerCalibration Errorf% Span):

Zgro System Calibration Gas Al2l2a@nt Init. Sk:s. lo/t. Sk:s. Final Svs. Final Sk's.

Stack Cafib. Qa/. Bias Calib. Cal. Bias 

### Run**~** Response (% spanl Re:iQonse (% span)



### 15.48 000 0.00 0.00 0.00 2 0.00 0.00 0.00 0.00 0.00 3 0.00 0.00 0.00 0.00 0.00 4 

### 0.00 0.00 0.00 0.00 0.00 5 0.00 0.00 0.00 0.00 0.00 6 0.00 0.00 0.00 0.00 0.00 7 

### 0.00 0.00 0.00 0.00 0.00 8 0.00 0.00 0.00 0.00 0.00 9 

### 0.00 0.00 0.00 0.00 0.00 10 0.00 0.00 0.00 0.00 000 11 

### 0.00 000 0.00 000 0.00 12 0.00 0.00 0.00 0.00 0.00 

### AirNova, Inc. Page 2 EPA Method 6C Calculations (Cal. Error, Bias Drift and Bias Adjustment)

Ang/'aerCa/ib. Ga:ies /JQscale 

# """ low mid high Sk:s. Cal. Ga:i 

### 0.00 N/A 

### 12.38 22.38 12.38 0.00 N/A 

### 12.33 22.22 12.38 0.00 0.00 ·0.22 -0.72

U\2sci!le System Calibration Gas Cal/b. Init. Sk's. Init. Sk:s. Final S\:1i. Final Sk:s. Ca/ib. Actual Dn"ft Calib.**~a/.** Bias Calib. Cal. Bias Drift Slack (% span) Response (% span) Re@onse (% span! (% span) Conc.



### 0.00 12.45 0.31 12.45 0.31 0.00 15.39 

### 0.00 12.45 0.31 0.00 -5557 ·55.88 0.00 

### 0.00 0.00 -5557 0.00 -5557 0.00 

### ERR 0.00 0.00 -55.57 0.00 ·55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 000 0.00 -55.57 0.00 -55.57 0.00 

### ERR 000 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 000 0.00 -55.57 0.00 -55.57 0.00 

### ERRM7EDfF

Client Project No. Test Location Test Date 

### SpnJance Genco, LLC 

### 3333 Unit4 04120/10

Parameter: 

### Carbon Monoxide Instrument Span (ppm V

### COt 935.7

Actual Calibration Gas Value (PQmVCO): AnalvzerCalibration Response (ppmVCO): AnalyzerCalibration Error(% Span):

Zero**S~tem** Caligration Gas Appaal:nt Init.**Sl!~.** !nit SI!s. FinfiJS):,:s Final S):::s.

Stack Gal/b_ Cal. Bias Galib. 

### Gal. Bias 

### Run Conc. Response (% span) Response l% span)



### 279.0 0.0 0.52 0.0 0.52 2 00 00 0.52 0.0 0.52 

### 3 0.0 0.0 0.52 0.0 0.52 4 00 00 0.52 0.0 0.52 

### 5 00 00 0.52 0.0 0.52 6 0.0 0.0 0.52 0.0 0.52 7 

### 00 0.0 0.52 0.0 0.52 8 0.0 0.0 0.52 0.0 0.52 

### 9 0.0 00 0.52 0.0 0.52 10 0.0 0.0 0.52 0.0 0.52 11 0.0 00 0.52 0.0 0.52 12 00 0.0 0.52 0.0 0.52 

### AirNova, Inc. Page 3 EPA Method 6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

Ana/l!zerQf!.I/b. Gases Urw;.f!.le zero low 

### !11iJJ. high SI!s. Cal. Gas 

### 0.0 00 486.0 935.7 486.0 -4.9 

### 00 488.0 942.0 486.0 -0.52 0.00 0.21 0.67

Uj2scale Sy:stgm Calibration Gas Galib. Init Sl!s. Init. Sl§. Final S):::s. Final SI!s. Galib. Actual Drift Calib_ Gal.**Bia~** Calib. Cal. Bias Drift Stack (% span) Response 

### (% span) Response 

### (% span) (% soan) Conc.



### 0.00 483.0 -0.32 479.0 -0.75 -0.43 281.9 0.00 479.0 -0.75 0.0 -51.94 -51.19 0.0 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERR 0.00 0.0 -51.94 0.0 -51.94 0.00 

### ERRM7ED/F2

Client Project No. Test Location Test Date Spruance Genco, LLG 

### 3333 Unit4 OIF 04/21/10

Parameter 

### Oxygen InstrumentSpan t% 

### 02): 22.08

Actual Calibration Gas Value (% 

### 02):**Anal~er** Calibration Response t% 021- AnalyzerCalibrationError(% Span): Run 2

Zero §y:stem Calibration Gas**Appa~nt** Init.**S~.** !nit. 8):::5. Final S):::s. Fm§.1 Sj!'s. Sreck (;.a/ib. Cal. Bias Calib. Cal. Bias 

### Run Conc. Response (% span! Response t% span)



### 3.89 0.10 0.36 0.00 -0.09 2 

### 0.00 0.00 -0.09 0.00 -0.09 3 0.00 0.00 -0.09 0.00 -0.09 4 0.00 0.00 -0.09 0.00 -0.09 

### 5 0.00 0.00 -0.09 0.00 -0.09 6 

### 0.00 0.00 -0.09 0.00 -0.09 7 0.00 0.00 -0.09 0.00 -0.09 8 000 

### 0.00 -0.09 0.00 -0.09 9 

### 0.00 0.00 -0.09 0.00 -0.09 10 000 000 

### -0.09 0.00 -0.09 

### 11 0.00 0.00 -0.09 0.00 -0.09 

### 12 0.00 0.00 -009 0.00 

### -0.09 

### AirNova, Inc. Page 1 EPA Method7E Calculations (Cal. Error, Bias Driftand BiasAdjustment)**Anal~er** (;.a.fib Gases !.lJJ.scale zero 

### lOY!< mid high S!::§:. Cal. Gas 

### 0.00 NfA 

### 11.90 22.08 11.90 0.02 NfA 

### 11.99 21.92 11.90 0.09 0.00 0.41 -0.72

UR§cale Sy:stem Calibration Gas Cafib. Init. S):::s. iait Svs. Final**S~.** Final S):::s. Galib. Actual Drift Calib. Ca.i Bias Cal/b. Cal. Bias Drift Stack (% span! Response (% span) Response t% span) (% sp§'n) Conc.



### -0.45 11.95 0.23 11.98 0.36 0.14 3.84 0.00 11.98 0.36 0.00 -53.89 -54.26 0.00 0.00 0.00 -53.89 0.00 -5389 0.00 

### ERR 000 

### 0.00 -53.89 0.00 -5389 0.00 

### ERR 0.00 0.00 -53.89 0.00 -fi3.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.B9 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.B9 0.00 

### ERR 000 000 

### -53.89 0.00 -5389 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.B9 0.00 

### ERR 000 

### 0.00 -53.B9 0.00 -53.B9 0.00 

### ERR 000 

### 0.00 -53.89 0.00 -53.89 0.00 

### ERRM7ED/F2

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Umt4 04121/10

Parameter: 

### Carbon Dioxide Instrument

### Span f% C02): 

### 22 28

Actual Calibration Gas Value 

### f% C02t AnalYZerCalibration Response (% C02): AnalyzerCalibration Error(% Span):

Zero**S~tem** Calibration Gas Aggarent Init. ,'iys. fait. Sys. FinfJ/Sys. FinalSys.

Stack**~** Cal. 

### Bia§. Calib. Cal. Bias 

### Run Cone. Response 

### f% §.Mn) Response f% 

### §.@nJ

15.22 ·0.12 -0.54 0.12 0.54 2 

### 0.00 0.12 054 

### 0.00 0.00 3 0.00 0.00 0.00 0.00 0.00 4 0.00 0.00 0.00 0.00 0.00 

### 5 0.00 0.00 0.00 0.00 0.00 6 0.00 0.00 

### 0.00 0.00 

### 0.00 7 0.00 0.00 000 

### 0.00 0.00 

# a 0.00 0.00 

### 0.00 0.00 

### 0.00 g 000 

### 0.00 0.00 0.00 0.00 10 

### 0.00 0.00 0.00 0.00 0.00 11 

### 0.00 0.00 0.00 0.00 0.00 12 

### 0.00 0.00 0.00 0.00 0.00 

### AirNova, Inc. EPA Method 6C Calculations (Cal. 

### Error, Bias Driftand Bias Adjustment)

zero 

### 0.00 0.00 0.00 AnalyzerCalib. Gases low !l1iQ 

### N/A 12.38 N/A 12.45 

### 0.00 031 high 

### 22.38 22.34 -0.18

Ugscale Slfstem Calibration Gas Ca/ib. Init. Sys. Init. Sys. Final Sys. Final Sys. Drift Calib. Cal. Bia§. Calib. Cal. 

### Big§. (% span) Resgonse f% span) Response f% §.Qan)



### 1.08 12.57 0.85 12.57 0.85 ·0.54 12.57 0.85 0.00 ·55.57 0.00 0.00 ·55.57 0.00 ·55.57 0.00 0.00 ·5557 0.00 ·55.57 0.00 0.00 ·55.57 0.00 ·55.57 0.00 0.00 ·55.57 0.00 ·55.57 0.00 0.00 -55.57 0.00 ·55.57 0.00 000 

### ·55.57 0.00 ·55.57 0.00 000 

### -55.57 0.00 ·55.57 0.00 

### 0.00 -55.57 0.00 ·55.57 0.00 0.00 -55.57 0.00 -55.57 0.00 0.00 -55.57 0.00 -55.57 Upscale Sys. Cal. Gas 

### 12.38 12.38

Ca/ib. Drift (% span)



### 0.00 -56.42

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Page 2

Actual Stack Cone.



### 14.99 ·0.12 

### ERR ERR ERR ERR ERR ERR ERR ERR ERR ERRM7ED/F2

Client Project No. Test Location Test Date 

### Spruance Genco, LLC 

### 3333 Unit4 04/21/10

parameter: 

### Carbon Monoxide Instrument Span (PpmV

### COl: 935.7

Actual Calib@tion Gas VSllue (vpmV

### CO): AnalyzerCalibration Response WpmV

### COt AnalyzerCalib@tion Error(% Span):

Zero System CilIlibration GillS**~rma~nt** Init. Sys. Init· Sys. Final Sys. Finfj.1 Sys. Stack 

### r:&IJ.!L Cal. Bias**~** Cal. Bias Run Conc. Response (% span) Response (% span!



### 269.0 -4.9 -0.52 

### 0.0 0.00 

### 2 0.0 0.0 0.00 

### 00 0.00 

### 3 0.0 0.0 0.00 

### 00 0.00 4 

### 00 0.0 0.00 0.0 0.00 

### 5 0.0 0.0 0.00 

### 0.0 0.00 

### 6 0.0 0.0 0.00 

### 0.0 0.00 7 

### 0.0 0.0 0.00 

### 0.0 0.00 

### 8 0.0 0.0 0.00 

### 0.0 0.00 9 

### 0.0 0.0 0.00 

### 0.0 0.00 

### 10 0.0 00 0.00 

### 0.0 0.00 

### 11 00 0.0 0.00 

### 0.0 0.00 

### 12 00 0.0 0.00 

### 00 0.00 

### AirNova, Inc. Page 3 EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment)**Ana/l.a~rCalib.** GSises Uf}.scale zero low mid high**S~.** Cal. Gas 

### 0.0 0.0 486.0 935.7 486.0 

### 0.0 0.0 488.0 938.0 4860 0.00 0.00 0.21 0.25

Ugscale System CalibratiQn**~as** Cafib. Init. Sys. Init. Sys. Final Sys. Final Sys. Calib. Actual Drift Calib. Cal. Bias Ca/ib. Cal. Bias Drift Stack (% span) Response (% span) Response (% span) (% span! Cone.



### 0.52 479.0 -0.75 479.0 -0.75 0.00 274.0 0.00 4790 -0.75 

### 0.0 -51.94 -51.19 

### O.D 0.00 

### 0.0 -51.94 

### 00 -51.94 0.00 

### ERR 0.00 

### 0.0 -51.94 

### 00 -51 94 0.00 

### ERR 000 0.0 -51.94 

### 0.0 -51.94 

### 000 

### ERR 0.00 

### 0.0 -51.94 

### 0.0 -51.94 0.00 

### ERR 0.00 

### 0.0 -51.94 

### 0.0 -51.94 

### 000 

### ERR 0.00 

### 0.0 -51.94 

### 0.0 -51.94 0.00 

### ERR 0.00 

### 0.0 -51.94 

### 0.0 -51.94 0.00 

### ERR 0.00 

### 00 -51.94 

### 0.0 -51.94 0.00 

### ERR 0.00 

### 0.0 -51.94 

### 0.0 -51.94 0.00 

### ERR 0.00 

### 0.0 -51.94 

### 0.0 -51.94 0.00 

### ERRM7ED/F3

Client Project No. Test Location Test Date Spruance 

### Genco, LLC 

### 3333 Unit 4 OfF 

### 04/22/10

Parameter: InstrumenfSpan (% 02): 

### Oxygen 22.08

Actual Calibration Gas Value t% 02!: AnalyzerCalibration Response t% 02): AnalyzerCalibration Error(% Span); Run 

### 3

Zero SY1!tem Calibration Gas Apparent Init. ,£ys. Init.**S~.** FinaIS!::§. FinalSJ:::s.

Stack Calib. Cal. Bias Calib. Cal. Bias 

### Run Conc. Response (% soanl Response (% span!



### 406 0.12 0.45 0.10 0.36 2 0.00 0.10 0.36 0.00 -0,09 

### 3 0.00 0.00 -0.09 0.00 -0.09 4 

### 0.00 0.00 -0.09 0.00 -0.09 5 0.00 0.00 -0.09 0.00 -009 6 0.00 000 -0.09 0.00 -0.09 7 

### 0.00 0.00 -0.09 0.00 -0.09 8 0.00 0.00 -0.09 0.00 -0.09 9 0.00 0.00 -009 0.00 -0.09 10 0.00 0.00 -0.09 0.00 -0.09 11 0.00 0.00 -0.09 0.00 -0.09 12 0.00 0.00 -0.09 0.00 -0.09 

### AirNova, Inc. Page 1 EPA Method 7E Calculations (Cal. Error, Bias Driftand BiasAdjustment)

AnalvzerCalib. Gases Upscale zero low mid high S!:,:s. Cal. Gas 

### 000 NfA 

### 11.90 22.08 11.90 0.02 NfA 

### 11.89 21.91 11 90 0.09 0.00 -0.05 -0.77

UR§,cale Sllstgm CalibratiQn Gas Calib. Init. SJ:::s. lait SJ:::s. FinalSJ:::s. FinalS\:':S. Galib. Actual Drift Calib. Cal. Bias Galib. Cal. Bias Drift Stack (% span) Response (% spanl Response (% span! (% soan! Conc.



### -0.09 11.96 0.27 11.96 0.27 0.00 3.97 

### -0.45 11 96 0.27 0.00 -53.89 -54.17 -0.10 0.00 0.00 -53.89 000 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 000 0.00 -53.89 000 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -5389 0.00 

### ERR 000 0.00 -53.89 0.00 -53.89 0.00 

### ERR 000 0.00 -53.89 0.00 -53.89 0.00 

### ERR 000 0,00 -53.89 0.00 -53.89 0.00 

### ERR 0.00 0.00 -53.89 0.00 -53.89 0.00 

### ERRM7EDJF3

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit4 04/22/10

Parameter: 

### Carbon Dioxide InstrumentSpan (% 

### C02!: 22.28

ActualCalibration Gas Value (% 

### C02): AnalvzerCalibration Response (% 

### C02): AnalyzerCalibration Error(% Span):

Zero Sy:stem Calibration Gas {jQJ1.f!.fent !nit. SJl:s. Init. SJl:s

... FinalSJl:s. FinalSJl:s. 

### SIiill< Ca/ib. Cal. Bias Calib. Qal Bias 

### Run Conc. Response (% soan) Response (% span)

1 

### 15.52 0.00 0.00 0.00 0.00 2 

### 0.00 0.00 0.00 

### 0.00 0.00 3 

### 0.00 0.00 0.00 0.00 0.00 4 000 

### 0.00 0.00 0.00 0.00 5 

### 0.00 0.00 0.00 0.00 0.00 6 

### 0.00 0.00 0.00 0.00 0.00 7 

### 0.00 0.00 000 

### 0.00 0.00 8 

### 0,00 0.00 000 

### 0,00 0.00 9 

### 0.00 0.00 0.00 0.00 0.00 10 

### 0,00 0.00 000 

### 0.00 0.00 11 

### 0.00 0.00 0.00 0.00 0.00 12 

### 0.00 0.00 0.00 0.00 0.00 

### AirNova,lnc. Page 2 EPA Method 6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

Anal'LzerCafib. Gases Upscale
zero low mid high SJl:s. Cal. Gas 

### 0.00 N/A 

### 12.38 22.38 12.38 0.00 N/A 

### 12.45 22.46 12.38 0.00 0.00 0.31 0.36**U~scale** Sy:§:tem galil;2ration Gas Calib. Init. SJl:s. Init. SJl:s. Final SJl:s. Final**S~.** Calib.**~** Drift Cafib. Cal. Bia;s. CaJib. Cal. Bia;s. Drift Stack (% span) Response (% span) Response (% span) (% span) Conc.



### 0.00 12,57 085 

### 12.45 0.31 -054 15.36 000 

### 12.45 0.31 0.00 -55.57 -55.88 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0,00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0,00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 0.00 0.00 -55.57 0.00 -55.57 0.00 

### ERR 000 000 

### -55.57 0.00 -55.57 0.00 

### ERRM7ED/F3

Client Project No. Test Location Test Date Spruance Genco, LLC 

### 3333 Unit4 04/22110

Parameter: 

### Carbon Monoxide InstrumentSpan (ppmVGO): 

### 935.7

Actual Calibration Gas Value (ppmVCO): AnalvzerCalibratlOn Response (oemVCO), Anafy2erCalibration Error

### £% Span):

Zero**S~tem** Calibration Gas A/J.earent Init. SJ:::s. 

### Init· Sit's. Final SJ:::s. FinalSJ:::s.

Stack Galib. Cal. Bias Calib. Gal. Bias 

### Run Cone. Response (% span) Response (% span)



### 1 332.0 

### 0.0 0.00 -4.9 -0.52 

### 2 0.0 -4.9 -0.52 

### 0.0 0.00 

### 3 0.0 0.0 0.00 

### 00 0.00 4 

### 0.0 0.0 0.00 00 0.00 

### 5 0.0 0.0 0.00 

### 00 0.00 6 

### 0.0 0.0 0.00 0.0 0.00 7 

### 0.0 0.0 0.00 

### 00 0.00 

### 8 0.0 0.0 0.00 

### 00 0.00 9 

### 0.0 0.0 0.00 

### 0.0 0.00 

### 10 0.0 0.0 0.00 

### 00 0.00 11 

### 0.0 0.0 0.00 

### 0.0 0.00 

### 12 0.0 0.0 0.00 0.0 0.00 

### AirNova, Inc. Page 3 EPAMethod6C Calculations (Cal. Error, Bias Driftand BiasAdjustment)

Anal'a,erGalib. Gases UpSCa/f/. Zf/.ro low mid high SJ:::s. Gal. Gas 

### 0.0 0.0 486.0 935.7 486.0 

### 0.0 0.0 488.0 938.0 4860 0.00 0.00 0.21 0.25**Uru!c~Je** System Calibration Gas Galib. Init. SJ:::s. Init. Sit's. Final,slt's. FinalSJ:::s. Cafib. 

### &JJJ.m Drift Ca/ib. Gal. Bias Cafib. Gal. Bia§. Drift Stack f% sean) Response (% span) Reseonse (% span) (% span) Cone.



### -0.52 474.0 -1.28 479.0 -0.75 0.53 339.4 0.52 479.0 -0.75 

### 0.0 -51.94 -51.19 4.' 

### 0.00 

### 0.0 -51.94 

### 0.0 -51.94 0.00 

### ERR 000 0.0 -51.94 

### 0.0 -51.94 

### 000 

### ERR 000 00 -51.94 

### 0.0 -51.94 0.00 

### ERR 0.00 

### 00 -51.94 

### 0.0 -51.94 0.00 

### ERR 0.00 

### 00 -51.94 

### 0.0 -5194 0.00 

### ERR 0.00 

### 0.0 -51.94 

### 0.0 -5194 0.00 

### ERR 0.00 

### 00 -51.94 

### 0.0 -51.94 

### 0.00 

### ERR 000 0.0 -51.94 

### 0.0 -51 94 0.00 

### ERR 0.00 

### 00 -51.94 

### 0.0 -51.94 0.00 

### ERR 0.00 

### 00 -51.94 

### 0.0 -51.94 0.00 

### ERR3333-M23-R1

Client Project No. Test Location Test Run Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vlc= Vm= Pstatic= Pb= Ps = Pstd= dP= dH= Tm= Ts= Tstd= On = An = y= 

# ,= Os = As= Cp= Kp= K1 = K2= K3= Fd =

[021 [C021
[N2) 

### AirNova, Inc. EPA Methods 1,2,3A,4, and 23 (Flows, 021C02, H20, and PCDDIPCDF)
Spruance Genco, LLC 3333 Unit No.4 

### 0" 04/20/10 0925-1736

Emission Data

811.4 cc 272.217 dcf -0.50 in. H20 30.04 in. Hg 30.00 in. Hg 29.92 in. Hg 0.7452 in. H20 ".5

0.959 in. H20 550.5 R 652_5 R 527.7 R 0.225 in. 0.000276 sq. ft. '1.02 480 min. 10.300 ft. Vol. of H20 collected Dry 9as meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rtdelta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature Nozzle diameter Area of nozzle orifice Metercalibration factor Duration ofsampling time Diameterofstack 83.3204 sq. ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49**fl[(lb/lbmol)*(inHgW.5}l[s~R*inH2(** Pitottube constant 17.637 Rlin.Hg 0.047070 cU.fUml 0.0026688 in.Hg-cflml-R 9777 scf/MMBtu constant constant constant Fuel Factor

Instrumental Data

4.13 %-dry Oxygen concentration

15.39 %-dry Carbon Dioxide concentration

80.48 %-dry Nitrogen concentrationClient Project No. Spruance Genco, llC 3333 TestLocatiot Unit No.4 Test RUn One

Calculations
1)Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd :K1* Y**~** Vm**~** (Pb + dH/13.6)ITm Vmstd: 267.860 dscf 7.59 dscm
2) Volume ofwatervapor collected atstandard conditions, Vw(std). Vw(std) : K2 *Vic Vw(std) = 38.192 scf
3) Decimal fraction ofmoisture byvolume in stack gas, Bws.

Bws : Vwstd I (Vmstd+Vwstd) Bws: 0.125
4) Molecularweightofthe stack gas on awet basis, Ms.

Ms: ((44*%C02) + (32-%02) + (28*%N2»* (1-Bws)

### J+ (18*Bws) Ms '" 29.05 Ib/lbmole
5)Average stack gasvelocity,Vs.

Vs : Kp * Cp * (dP) * (TsJPs*Ms)".5 Vs: 46.30 fps
6)Average actual stack gasvolumetric flowrate, Qa,
Qa =60 sec/min *Vs *As Qa: 231466.3 cfm 6555.1 cmm 7) Average stack gas dryvolumetricflowrate, Qstd.
Qstd: Qa

- (TstdfTs) * (Ps/PSld) * (1-Bws) Qsld = 164282.3 dscfm 4652.5 dscmm Page 2Client Project No. Spruance Genco, LLC 3333 Test Locatior Unit No.4 Test Run One

Calculations (cont.)
08a) Chlorinated Oibenzodioxins (COD) Concentrations and Emission Rates

Cone. [CDD]:: Mass [CCD](ng) IVmstd(dscm) C[CDD](@corr. 02) =qCDD] (ng/dscm)**~** [(20.9-corrected %02) I (20.9-actual %02) I C[CDD](lb/dscf):: C[CDD](ng/dscm) * 1e-09g/ng*2.20Se-03Ib/g * 0.02832 dscm/dscf E[CDD](lbIMMBtu) = C[CDD](lb/dscf) * Fd * (20.9/20.9-%02) Corrected 02 percentage is: 7.0 %
Sample Conc_ Conc, Conc. Emission Rate Compound Mass (ng) (ng/dscm) (ng/dscm (lb/dscO (lb/MMBtu) @7%02) 2.3.7,8-TCDD 0.00347 4.S7E-04 3.79E-04 2.86E-17 3A8E-13 otherTCDD 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO
2,3,7,8-PeCDD 0.00341 4.S0E-04 3.73E-04 2.B1E-17 3.42E-13 other PeCDD 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO
2,3,7,B-HxCDD 0.01147 1.S1E-03 1.2SE-03 9.44E-17 1.1SE-12 other HxCDD 0,00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO
2,3,7,B-HpCDD 0.00438 S.77E-04 4.79E-04 3,61E-17 4.39E-13

other HpCDD 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O_OOE+OO

OCDD 0.00777 1.02E-03 B.49E-04 6.40E-17 7.79E-13


### COD Avg Cone. 3.70E-04 Avg Ib/MMBtu 3.40E-13 Page3



### < <

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### <

< <

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### <Client Project No. Spruance Genco, LLC 3333 Test Locatior Unit No.4 Test Run One

Calculations (cont.)
08b) Chlorinated Oibenzofurans (COF) Concentrations and Emission Rates

Conc. [CDF] = Mass [CDF](ng) /Vmstd(dscm) C[CDF](@carr. 02)= C[CDF] (ng/dscm)· [(20.9-corrected %02) I (20.9-actual %02) 1 C[CDF](lb/dscf) = C[CDF](ng/dscm) * 1e-09g/ng* 2.205e-03Ib/g**~** 0.02832 dscmldscf E[CDF](lb/MMBtu) = C[CDF](lb/dscf)· Fd • (20.9/20.9-%02) Corrected 02 percentage is: 7.0 %

Samole Conc. Conc. Conc. Emission Rate Compound Mass {ng} {ng/dscm} (ng/dscm (Ib/dscf) {lb/MMBtu} @7%02) 2,3,7,S-TCDF 0.00247 3.26E-04 2.70E-04 2.03E-17 2.48E-13 other TCDF 0.01240 1.63E-03 1.3SE-03 1.02E-16 1.24E-12
1,2,3,7,8-PeCDF 0.00240 3.16E-04 2.62E-04 1.9BE-17 2.41E-13 2,3,4,7,B-PeCOf 0.00217 2.S6E-04 2.37E-04 1.79E-17 2.18E-13

other PeCDF 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO
2,3,7,8-HxCDF 0.01019 1.34E-03 1.11E-03 B.39E-17 1.02E-12 other HxCDF 000000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO
2,3,7,B-HpCDF 0.00432 S.69E-04 4.72E-04 3.S6E-17 4.33E-13 other HpCDF 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO

OCDF 0.00748 9.B6E-04 B.17E-04 6.16E-17 7.S0E-13

COF Avg Cone. 4.S3E·04 Avg IblMMBtu 4.16E·13

Total Dioxin Avg Cone. 4.11E·04 Avg Ib/MMBtu 3.78E·13 Page4



# ,

< < <

< <

<

<Client Project No. Spruance Genco, LLC 3333 Test Locatior Unit No.4 Test Run One

08c)Non-ortho and Mono·ortho Substituted PCBs Concentrations and Emission Rates

Conc. [PCB] = Mass [PCB](ng) IVmstd(dscm) qCDF](@corr. 02) =C[CDF] (ng/dscm) * [(20.9-corrected %02) I (20.9-actual %02)

### I qCDF](lb/dscf) =C[CDF](ng/dscm) * 1e-099/n9 * 2.20Se-03Ib/g**~** 0.02832 dscm/dscf E[CDF](lb/MMBtu) = C[CDF](lbfdscf) * Fd * (20.9(20.9-%02) Corrected 02 percentage is: 7.0 %

Non-ortho Substituted PCBs

Samole Cone. Conc. Conc. Emission Rate Coml2ound Mass {ng} {ng/dscm} (ng/dscm (lb/dscO {lb/MMBtu} @7%02l PCB 77 0.01620 2.14E-03 1.77E-03 1.33E-16 1.62E-12 PCB 81 0.01490 1.96E-03 1.63E-03 1.23E-16 1.49E-12 PCB 126 0.01170 1.54E-03 1.28E-03 9.63E-17 1.17E-12 PCB 169 0.02110 2.78E-03 2.31 E·03 1.74E-16 2.12E-12

Mono-ortho Substituted PCBs

PCB 105 0.06490 8.S6E-03 7.09E-03 5.34E-16 6.51E-12 PCB 114 0.00955 1.26E-03 1.04E-03 7.86E-17 9,58E-13 PCB118 0.17300 2.28E-02 1.89E-02 1,42E-15 i.74E-11 PCB 123 0.00907 i.20E-03 9,91 E-04 7.47E-17 9.10E-13 PCB 156 0.01010 i.33E-03 i.i0E-03 8.31E-17 1.01E-12 PCB 157 0.01010 1.33E-03 1.10E-03 8.31E-17 1,01E-12 PCB 167 0.01520 2.00E-03 1.66E-03 1.25E-16 1.52E·12 PCB 189 0.01780 2.35E-03 1 94E-03 1,47E-16 1.79E-12

Total PCBs Avg Conc. 3.4E·03 Avg Ib/MMBtu 8.9E-13 Total Dioxin & PCBs Avg Conc. 1.91E·03 Avg Ib/MMBtu 6.35E-13
9) Isokinecity, I.

% I= [100*Ts"(K3*Vlc+(((Vm*Y)fTmt(Pb+(dH/13.6))))] I (60*t"Ps"Vs*An) %1= 102,51

" < " symbol indicates values given arethequantitative detection limit. Page 5



### < < <

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### <3333-M23-R2

Client ProjectNo. TestLocation Test Run Test Date Test Time

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vlc= Vm = Pstatic = Pb = Ps = Pstd = dP= dH ::: Tm= Ts= Tstd= Dn = An = y= 1= Os = As = Cp = Kp= K1 = K2= K3= Fd =



### 1021
[C02] 

### IN21 AirNova, Inc. EPA Methods 1,2,3A,4, and 23 (Flows, 02fC02, H20, and PCDDIPCDF) Spruance Genco, LLC 3333 Unit No.4 

### Two 04f21f10 0711-2037

Emission Data

873.1 cc 265.307 dcf -0.50 in. H2O 29.96 in. H9 29.92 in. H9 29-92 in. H9 0.7634 in. H20h.5

0.984 in. H2O 526.0 R 649.0 R 527.7 R 0.225 in. 0.000276 sq.

# ". 1.02 480 min. 10.300 ft. Vol. of H20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rtdelta P Average draftgauge reading Average metertemperature Average stack temperature Standard temperature Nozzlediameter Area ofnozzle orifice Meter calibration factor Duration ofsampling time Diameter ofstack 83.3204 sq ft. Cross sectional area of stack 0.84 Pitot tube coefficient 85.49 ft[(lb/lbmol)*(inHg)]A.5}/[s*R*inH2i Pitottube constant 17.637 Rlin.Hg 0.047070 cu.ftlml constant constant 0.0026688 in.Hg-cf/ml-R constant 9920 scf/MMBtu Fuel Factor

Instrumental Data

3.84 %-dry Oxygen concentration

14.99 %-dry Carbon Dioxide concentration

81.17 %-dry Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 TestLocatior Unit No.4 Test Run Two

Calculations
1)Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1" Y**~** Vm " (Pb +dH/13.6) ITm Vmstd = 272.512 dscf 7.72 dscm 2) Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std) = K2 *Vic Vw(std) = 41.097 sef
3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws '" Vwstd I (Vmstd+Vwstd) Bws = 0.131
4) Molecularweightofthestackgas on awet basis, Ms.

Ms =**[((44~%C02)** + (32*%02) + (28*%N2)) * (1-Bws) 

### 1 + (18"Bws) Ms = 28.91 Ib/lbmole
5)Average stack gas velocity, Vs.

Vs =Kp * Cp * (dP) * (Ts/Ps*Ms)h.5 Vs = 47.49 fps
6) Average actual stack gas volumetric flowrate, Qa.

Qa = 60 sec/min *Vs *As Oa = 237412.8 efm 6723.5 emm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa· (TstdfTs)·(Ps/Pstd)· (1-Bws) Qstd = 167752.4 dscfm 4750,7 dscmm Page 2Client Project No. Spruance Genco, LLC 3333 Test Locatior Unit No.4 Test Run Two

Calculations (cont.)
08a) Chlorinated Oibenzodioxins (COD) Concentrations and Emission Rates

Conc. [CDD]

## =Mass [CCD](ng) 1Vmstd(dscm) C[CDD](@corr, 02)

## = C[CDD] (ng/dscm)**~** [(20.9-corrected %02) 1(20.9-actual %02)] C[CDD](lb/dscfj

## = C[CDD](ng/dscm) ·1e-09g/ng * 2.205e-03Ib/g * 0.02832 dscm/dscf E[CDD](lbIMMBtu)

## = C[CDD](lb/dscfj**~** Fd * (20.9/20.9-%02) Corrected 02 percentage is: 7.0 %
Sample Conc. Conc. Conc. Emission Rate Compound Mass (ng) (ng/dscml (ng/dscm Ob/dscfl (lblMMBtu) @7%02) 2,3,7,8-TCDD 0,00341 4.42E·04 3.60E-04 2.76E·i7 3.35E-i3 otherTCDD 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO
2,3,7,8-PeCDD 0.00447 5.79E-04 4.72E-04 3.62E-17 4.40E-13 other PeCDD 0.00000 O.OOE+OO O,OOE+OO O.OOE+OO O.OOE+OO
2,3,7,8-HxCDD 0.01345 1.74E-03 1.42E-03 i.09E-16 1.32E-12 other HxCDD 0.00000 O,OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO
2,3,7,8-HpCDD 0.00394 5.11E-04 4.16E-04 3.i9E-i7 3.87E-i3 other HpCDD 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO

OCDD 0.04230 S.48E-03 4.47E-03 3.42E-16 4.16E-12


### COD Avg Conc. 7.93E·04 Avg IbfMMBtu 7.38E-13 Page 3



### < <

< <

< <

< <Client Project No. Spruance Genco, LLC 3333 Test Locatior Unit No.4 Test Run Two

Calculations (cont) OSb) Chlorinated Dibenzofurans (CDF) Concentrations and Emission Rates

Conc. [CDF] = Mass [CDF](ng) I Vmstd(dscm) C[CDF](@corr. 02) = C[CDF] (ngJdscm) r [(20.9-corrected %02)J(20.9-actual %02)] C[CDF](lbJdscf) = C[CDF](ng/dscm) * le-09g/ng *2.205e-03Ib/g**~** 0.02832 dscm/dscf E[CDF](lb/MMBtu) = C[CDF](lb/dscf)**~** Fd * (20.9/20.9-%02) Corrected 02 percentage is: 7.0 %
Sample Conc. Conc. Conc. Emission Rate Compound Mass (ng) (ng/dscm) (ng/dscm Ob/dscfl (lb/MMBtu) @7%02) 2,3,7,8-TCDF 0.00261 3.3SE-04 2.76E-04 2.11E-17 2.57E-13 otherTCDF 0.00308 3.99E-04 3.25E-04 2.49E-17 303E-13
1,2,3,7,8-PeCDF 0.00244 3.16E-04 2.58E-04 1.97E-17 2.40E-13 2,3,4,7,S-PeCDF 0.00249 3.23E-04 2.63E-04 2.01E-17 2.45E-13

other PeCDF 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO
2,3,7,8-HxCDF 0.01006 1.30E-03 1.06E-OS 8.14E-17 9.89E-13 other HxCDF 001200 1.55E-03 1.27E-03 9.71E-17 1.18E-12
2,3,7,8-HpCDF 0.07990 1.04E-02 8.44E-03 6.47E-16 7.86E-12 other HpCDF 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO

OCDF 0.07430 9.63E-03 7.84E-03 6.01E-16 7.31E-12

COF Avg Cone. 1.97E-03 Avg Ib/MMBtu 1.S4E-12

Total Dioxin Avg Cone. 1.3SE-03 Avg IblMMBtu 1.29E-12 Page4

<



### < < <

<Client Project No. Spruance Genco, LLC 3333 Test LocatiorUnit No.4 Test Run Two

OBc)Non-ortho and Mono·ortho Substituted PCBs Concentrations and Emission Rates

Conc. [PCB)

## = Mass [PCB)(ng) IVmstd(dscm) C[CDF](@carr. 02)

## = C[CDF) (ng/dscm)" [(20.9·corrected %02) 1(20.9-actual %02)] C[CDF](Ib/dscf)

## = C[CDF](ng/dscm} * 1e-09g/ng"2.205e-03Ib/g**~** 0.02832 dscm/dscf E[CDF)(lbIMMBtu)

## = C[CDF](lb/dscf) "Fd * (20,9/20.9-%02) Corrected D2 percentage is: 7.0 %

Non-ortho Substituted PCBs
Sample Conc. Conc. Conc. Emission Rate Compound Mass tng} (ng/dscm) (ng/dscm (lb/dscO {lb/MMBtu} @7%02) PCB 77 0.01280 1.66E-03 1.35E-03 1.04E-16 1.26E-12 PCB 81 0,00464 6.01 E-04 4.90E-04 3.75E-17 4.56E·13 PCB 126 0.00615 7,97E-04 6.49E-04 4,98E·17 6.05E-13 PCB 169 0.00993 1.29E-03 1.05E-03 8.03E-17 9.76E-13

Mono-ortho Substituted PCBs

PCB 105 0.06880 8.91 E-03 726E-03 5.57E-16 6.77E-12 PCB114 0,00450 5.83E-04 4,75E-04 3.64E-17 4.43E-13 PCB118 0.17700 2.29E-02 1.87E-02 1.43E-15 1.74E-11 PCB 123 0.00434 5.62E-04 4.58E-04 3.51E-17 4,27E-13 PCB 156 0.01145 1.48E-03 1.21E-03 9.26E·i7 1.13E-12 PCB 157 0.01145 1.48E·03 i.21E-03 9.26E·17 1.13E-12 PCB 167 0.00754 9.77E-04 7.96E-04 6.10E-17 7.41E-13 PCB 189 0.00821 1.06E-03 8.67E-04 6.64E-17 a,07E-13

Total PCBs Avg Conc. 2.9E·03 Avg IblMMBtu 4.0E-13 Total Dioxin & PCBs Avg Cone. 2.13E-03 Avg IblMMBtu 8,46E·13
9) Isokinecity, I.

% I

## =**[100"Ts*(K3·Vlc+«(Vm~Y)fTmr(Pb+(dH/13.6))))J** I (60*t"Ps*\ls"An) %1= 102.13

"<"symbol indicates values given are the quantitative detection limit. Page 5

< 

### < <

<



### <

< 

### <3333-M23-R3

Client Project No. Test Location Test Run Test Date TestTime

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT Vic = Vm= Pstatic = Pb= Ps = Pstd = dP= dH= Tm= Ts= Tstd= Dn = An = y= t= Ds = As= Cp= Kp = K1 = K2= K3= Fd=

(02(
[C02]
(N2) 

### AirNova, Inc. EPA Methods 1,2,3A,4, and 23 (Flows, 021C02, H20, and PCDDIPCDF)
Spruance Genco, LLC 3333 Unit No.4 Three 04/22/10 0700-1509

Emission Data

797.4 

### cc 271.163 dcl -0.50 in. H20 29.96 in. Hg 29.92 In. Hg 29.92 in. Hg 0.7449 in. H20 ''.5

0.965 in. H20 546.2 R 653.5 R 527.7 R 0.225 in. 0.000276 sq. ft. 1.00 480 min. 10.300 ft. Vol. of H20collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draftgauge reading Average metertemperature Average stacktemperature Standard temperature Nozzle diameter Area ofnozzle orifice Meter calibration factor Duration of sampling time Diameter of slack 83.3204 sq. ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49**ft[(lb/lbmolt(inHg)]~**.5)/[s*R*inH2! Pitottube constant 17.637 Rlin.Hg constant 0.047070 cu.ft/ml constant 0.0026688 in.Hg-cf/ml-R constant 9705 scf/MMBtu Fuel Factor

Instrumental Data

3.97 %-dry Oxygen concentration

15.36 %-dry Carbon Dioxide concentration

80.67 %-dry Nitrogen concentrationClient Project No. Spruance Genco, LLC 3333 Test Locatior Unit No.4 Test Run Three

Calculations 1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1' Y* Vm "(Pb +dHf13,6) fTm Vmstd = 262_930 dscf 7.45 dscm
2) Volume ofwatervaporcollected atstandard conditions, Vw(std).
Vw(std) = K2"Vic Vw(std) = 37.533 scf
3) Decimal fraction ofmoisture byvolume in stack gas, Bws.

Bws '" Vwstd I (Vmstd+Vwstd) Bws= 0.125
4) Molecularweightofthestackgas on awetbasis, Ms.

Ms = [«44"%C02)+ (32*%02) + (28*%N2»"(1-Bws) J+ (18*Bws) Ms= 29.04 Ib/lbmole
5) Averagestack gas velocity, Vs.

Vs = Kp"Cp" (dP) " (TsJPs*Ms)h.S Vs = 46.39 fps 6) Average actual stack gas volumetric flowrate, Qa.
Qa = 60 sec/min"Vs " As Qa = 231914,2 cfm 6567.8 cmm 7) Average stackgas dryvolumetric flowrate, Qstd.
Qstd = Qa" (TstdfTs)" (Ps/Pstd)" (1-Bws) Qstd = 163886:1 dscfm 4641.3 dscmm Page 2Client Project No. Spruance Genco, LLC 3333 Test Locatior Unit No, 4 Test Run Three

Calculations (cont.)
08a) Chlorinated Dibenzodioxins (CDD) Concentrations and Emission Rates

Conc. [CDDI = Mass [CCD](ng) fVmstd(dscm) C[CDD](@ carr. 02)=C[CDDI (ngfdscm) * [(20.9-corrected %02) f(20.9-actual %02)] C[CDD](lbfdscf) = C[CDD](ng/dscm) *1e-09gfng * 2.205e-03Ib/g·

## a02832dscmfdscf E[CDD](lbfMMBtu) = C[CDD](lb/dscf);t Fd;t (20.9f20.9-%02) Corrected 02 percentage IS: 7.0 %
Sample Conc. Conc. Conc. Emission Rate Compound Mass (ng) (ngfdscm) (ngfdscm (Ibfdscf) (lbfMMBtu) @7%02) 2,3,7,8-TCDD 0.00203 2,73E-04 2.24E-04 1.70E-17 2,04E-13 atherTCDD 0.00000 O.OOE+OO O,OOE+OO O,OOE+OO O.OOE+OO
2,3,7,8-PeCDD 0,00172 2.31E-04 1.90E-04 1.44E-17 1.73E-13 ather PeCDD 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO
2,3,7,8-HxCDD 0.00569 7,64E-04 6.27E-04 4.77E-17 5.72E-13 ather HxCDD 0,00000 O.OOE+OO O,OOE+OO O.OOE+OO O.OOE+OO
2,3,7,S.HpCDD 0.00203 2.73E-04 2.24E-04 1.70E-17 2.04E-13 other HpCDD 0.00000 O,OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO

OCDD 0,01670 2.24E-03 1.S4E-03 1.40E-16 1.6SE-12


### COD Avg Cone, 3.45E-04 Avg IblMMBtu 3.14E-13 Page 3



### < <

< <

< <

< <Client Project No. Spruance Genco, LLC 3333 Test LocatiorUnit No.4 Test RUn Three

Calculations (cont.)
OBb) Chlorinated Dibenzofurans (CDF) Concentrations and Emission Rates

Conc. [CDF] = Mass [CDF](ng) IVmstd(dscm) ClCDF](@corr. 02) := C[CDF] (ng/dscm) * [(20.9-corrected %02) I (20.9-actual %02)] ClCDF](lb/dscf) =C[CDF](ng/dscm) -le-09g/ng

- 2.20Se-03Ib/g

- 0.02832 dscmldscf E[CDF](lbIMMBtu) =ClCDF](lb/dscf)· Fd· (20,9/20,9-%02) Corrected 02 percentage is: 7.0 %
Sample Conc. Conc Conc. Emission Rate Compound Mass (ng) (ng/dscm) (ng/ds!<m**~** (lb/MMBtu) @7%02) 2,3,7,8-TCDF 0.00123 1.6SE-04 1.36E-04 1.03E-17 1.24E-13 otherTCDF 0.01010 1.36E-03 1.11E-03 8,47E-17 1.01E-12
1,2,3,7,8-PeCDF 0.00107 1,44E-04 1,18E-04 8,97E-18 1.08E-13 2,3,4,7,8-PeCDF 0.00106 1,41E-04 1,16E-04 8.81E-18 1.0SE-13

otherPeCDF 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO
2,3,7,8-HxCDF 0.00432 S,80E-04 4.76E-04 3.62E-17 4.34E-13 other HxCDF 0.00000 O.OOE+OO O,OOE+OO O,OOE+OO O.OOE+OO
2,3,7,8-HpCDF 0.00819 1.10E-03 9.03E-04 6.87E-17 8.23E-13 other HpCDF 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO

OCDF 0.01320 1.77E-03 1,46E-03 1.11E-16 1.33E-12


### COF Avg Conc. 4.32E-04 Avg Ib/MMBtu 3.93E-13

Total Dioxin Avg Conc. 3.88E-04 Avg Ib/MMBtu 3.54E·13 Page4



# ,

,
,


# ,

, 

# ,

,Client Project No. Spruance Genco, LLC 3333 Test LocatiorUnit No.4 Test Run Three

08c)Non-ortho and Mono-ortho Substituted PCBs Concentrations and Emission Rates

Conc. [PCB] = Mass [PCB](ng) IVmstd(dscm) qCDF]{@corr. 02)= qCDF] (ngldscm) * [(20.9-corrected %02) I (20.9-actual %02)] qCDF](lb/dscf)= qCDF](ng/dscm) *1e-09glng * 2.20Se-031b1g" 0.02832 dscm/dscf E[CDF)(lbIMMBtu) =qCDF](lb/dscf)· Fd" (20.9/20.9-%02) Corrected 02 percentage is: 7.0 %

Non-ortho Substituted PCBs
Sample Conc. Conc. Conc. Emission Rate Compound Mass (ng) (ngldscm) {ng/dscm {lb/dscO (lb/MMBtu) @7%02} PCB 77 0.01820 2.44E-03 2.01E-03 1.S3E-i6 1.83E-12 PCB 81 0.00767 1.03E-03 8.46E-04 6.43E-17 7.71E-13 PCB 126 0.00629 8.45E-04 6.94E-04 5.27E-17 6_32E-13 PCB 169 0.01070 1.44E-03 1.18E-03 8.97E-17 1_08E-12

Mono-ortho Substituted PCBs

PCB 105 0.09400 1.26E-02 1.04E-02 7.S8E-16 9.44E-12 PCB 114 0,00501 6,73E-04 5,5ZE-04 4.Z0E-17 5.03E-13 PCB118 0.24Z00 3.Z5E-OZ 2.67E-02 2.03E-15 2.43E-i1 PCB 123 0.00478 6.42E-04 5.27E-04 4.01E-17 4.80E·13 PCB 156 0.01625 2.1SE-03 1.79E-03 i.36E-16 1.63E-·12 PCB 157 0.01625 2_18E-03 1.79E-03 i.36E-16 1.63E-12 PCB 167 0.00748 1.00E-03 8.25E-04 6.27E-17 7.52E-13 PCB 189 0.00847 1.14E-03 9.34E-04 7.10E-17 8.51E-13

Total PCBs Avg Cone. 4.0E-03 Avg IblMMBtu 4.3E-13 Total Dioxin & PCBs Avg Conc. 2.20E-03 Avg IblMMBtu 3.90E·i3
9) Isokinecity, I.

% I= [100*Ts*(K3*Vlc+«(Vm*Y)fTm)*(Pb+(dH/13.6))))) I (60*t"Ps"Vs*An) % I :: 100.86

.. <;

.. symbol indicates values given are the quantitative detection limit. PageS



### < < <

<

<

< <Client Project No. Test Location Emission Source Test Date Test Run Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT INPUT

INPUT Vic = Vm= Pstatic = Pb= Ps = Pstd = dP = dH = Tm= Ts = Tstd= y= 1= Dn = An = Ds = As = Cp = Kp 

### = K1 = K2= K3 = Fd =

[02[ [C02] [N2] 

### [COr 

### AirNova, Inc. EPA Methods 1, 2, 3A, 4,10,18and 25A

(Flows, 02/C02, H20, CO and NMHC)
Spruance Genco, LLC 3333 Richmond, Virginia Unit NO.4 04/20f10 One 0925-1736 Emission Data

811.4 cc 272.217 dcf -0.50 in. H20 30.04 in. Hg 30.00 in Hg 

### 29.92 in. Hg 0.7452 In. H20 '\5



### 0.96 in. H2O 550.5 R 652.5 R 527.7 R

1.02

480 min. 0.225 in. 0.000276 sq. ft. 10.300 ft. 83.3204 sq. ft. Vol. ofH20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Metercalibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameterofstack Cross sectional area of slack 

### 0.84 Pitot lube coefficient 85.49 ft[**(lb/lbmol)~{inHg)]"**.5}/[ s*R*inH20] 17.637 Rfin.Hg constant 0.047070 cU.Wml 00026688 in.Hg-cf/ml-R 9777 scf/MMBtu

Instrumental Data 4.13 %-dry 15.39 %-dry 80.48 %-dry 281.9 ppmV-dry constant Pitottube constant constant From EPA Reference Method 19

Oxygen concentratIOn Carbon Dioxide concentration Nitrogen concentration Carbon Monoxide concentration Page 1Client Project No. Spruance Genco, LLC 3333 Emission Source Unit No.4 Test Run One

Calculations
1) Volume ofgas sampled at standard conditions, Vmstd.

Vmstd =K1* Y *Vm • (Pb 

### +dH/13.6) ITm Vmstd = 267.860 dscf 7.586 dscm
2) Volume ofwatervapor collected at standard conditions, Vw(std). Vw(std) = K2 * Vic Vw(std) = 38.192 scf
3) Decimal fraction of moisture byvolume in stack gas, Bws.

Bws =Vwsld I (Vmstd+Vwsld) Bws = 0.1248 4) Molecularweight ofthe stack gas on a wet basis, Ms.
Ms =**[«(44~%C02)** + (32*%02) + (28*%N2»· (1-Bws)] 

### +**(18~Bws)** Ms= 29.052 Ib/lbmole
5) Average stackgasvelocity, Vs.

Vs = Kp * Cp * (dP) • (Ts/Ps*Ms)".5 Vs 

### = 46.300 fps


### 6) Average actual stack gas volumetric flowrate, 

### Ca.

Oa '" 60 sec1min * Vs 

### *As Oa = 231466.3 cfm 6555.1 cmm 7) Average stackgas dryvolumetric flowrate. Qstd.
Qstd = Qa * (TstdlTs) * (Ps/Pstd) • (1-Bws) Qstd = 164282.3 dscfm 4652.5 dscmm
8) Carbon Monoxide concentrations and emissions
Corr. C[CO] = «20.9-02%corr. value)/(20.9·actual avg. 02% value»""Avg, raw CO value E[CO Ib/hrj = (C[CO]*Mol WI[CO]*60(min/hr)*Qstd(dscfm))/(Molar Vol. air*10"6) E[CO Ib/MMBluj 

### =Cd

.. Fd

.. (20 9/(20.9-actual 02%» C[CO] = 281 9 ppmVd qCO] = 233.7 ppmVd corrected to 7 % 02 Mol. Wt. [CO}= 28.01 Ib/lb-mole Molar vol air= 

### E[CO) = Conv Factor. 

### E[CO) = 385 scf/lb·mole 

### @ 68 202.16 Ib/hr 7.235E-08 convert ppmV 10 lb/scfCO 0,249 Ib/MMBtu def F Page 2Client Project No. Test Location Emission Source Test Date Test Run Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT INPUT

INPUT Vic = Vm = Pstatic = Pb = Ps= Psld = dP = dH = Tm = Ts = Tstd= y= t= On = An" Ds= As = Cp = Kp = K1 = K2= K3= Fd =

(02( (C021 (N21 (COj 

### AirNova, Inc. EPA Methods 

### 1, 2, 

### 3A, 4, 10, 18 and 25A

(Flows, 021C02, H20, CO and NMHC)
Spruance Genco, LLC 3333 Richmond, Virginia Unit No.4 04/21/10 

### Two 0711-2037 Emission Data

873.1 cc 265.307 dcf -0.50 in. H20 29.96 In. Hg 29.92 in. Hg 29.92 in. Hg 0.7634 in. H20 

### ".5 0.98 in. H2O 526.0 

### R 649.0 

### R 527.7 

### R

1.02

480 min. 0.225 in. 0.000276 sq ft. 10.300 ft 83.3204 sq. ft. Vol. of H20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rt delta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling time Nozzle diameter Nozzle area Diameter ofstack Cross sectional area ofstack 0.84 Pitot tube coefficient 85.49 fI[(lbllbmol)*(inHg))".5}/[ s*R*inH20j 17.637 Rfin.Hg constant 0_047070 cu.Wml 0.0026688 in.Hg-cffml-R 9920 scf/MMBtu

Instrumental Data 3.84 %-dry 14.99 %-dry 81.17 %-dry 274.0 ppmV-dry constant Pilot tube constant constant From EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Carbon Monoxide concentration Page 1Client Project No. Spruance Genco, LLC 3333 Emission Source Unit No 4 Test Run Two

Calculations
1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd**=K1~** Y *Vm" (Pb +dH/13.6) / Tm Vmstd = 272.512 dsc1 7.718 dscm
2) Volume ofwatervapor collected atstandard conditions, Vw(std). Vw(std) = K2 *Vic Vw(std) = 41.097 scf
3) Decimal fraction of moisture by volume in stack gas, Bws.

Bws =Vwstd / (Vmstd+Vwstd) Bws = 0.1310
4) Molecularweight ofthe stackgas on awet basis, Ms.

Ms = [«44*%C02)+ (32*%02) + (2S*%N2» * (l-Bws)] + (lS*Bws) Ms= 28.907 Ib/lbmole
5) Average stack gas velocity, Vs.

Vs = Kp * Cp ;0 (dP)

.. (Ts/Ps*Ms)".5 Vs = 47490 fps
6) Average actual stack gas volumetric flowrate, Qa.
Qa =60 sec/min"Vs * As Qa = 237412.8 cfm 6723.5 cmm 7) Average stack gas dryvolumetric flowrate, Qstd.
Qstd = Qa * (Tstd/Ts)· (Ps/Pstd)" (1-Bws) Qstd = 167752.4 dscfm 4750.7 dscmm
8) Carbon Monoxide concentrations and emissions
Carr. qCO] = «20.9-02%carr. value)l(20.9-actual avg. 02% valueWAvg. raw CO value E[CO Ib/hr] = (qCO]*MolWt[COj*60(min/hr)*Qstd(dscfm»/(MolarVol.**air~10"6)** E[CO Ib/MMBtu] = Cd • Fd

.. (20.9/(20.9-actual 02%» qCO] = 2740 ppmVd qCO] = 223 2 ppmVd corrected 

### to 7 % 02 Mol. WI. [CO]= 28.01 Ib/lb-mole Molar vol air= E[CO]- Conv Factor. E[CO]- 385 scf/lb-mole @ 200.64 lb/hr 7.235E-08 convert ppmV to Ib/scfCO 0.241 Ib/MMBtu 

### 68 def F Page 2Client Project No. Test Location Emission Source Test Date Test Run Time Period

INPUT INPUT INPUT INPUT

INPUT INPUT INPUT INPUT

INPUT

INPUT

INPUT

INPUT INPUT

INPUT Vlc= Vm = Pstatic = Pb = Ps = Pstd 

### = dP = dH = Tm= Ts 

### = Tstd= y= 1= 

### Do· An = Os = As = Cp 

### = Kp = Kl = K2= K3 = Fd =

[02[ [C02[ [N2[ 

### [COr 

### AirNova, Inc. EPA Methods 1, 2, 3A, 4, 10, 18and 25A

(Flows, 02/C02, H20, CO and NMHC)
Spruance Genco, LLC 3333 Richmond, Virgima Unit No, 4 

### 04/22/10 Three 0700-1509 Emission Data

797.4 cc 271 163 dc1 -050 in, H20 29.96 in. Hg 29,92 in, Hg 29.92 in. Hg 0.7449 in. H20 ".5 0.97 in. H2O 5462 R 653.5 R 527.7 R

1.00 480 min, 

### 0.225 in. 0.000276 sq. ft. 10300 ft. 83.3204 sq. 

### ft. Vol. ofH20 collected Dry gas meter reading Static pressure Barometric pressure Stack pressure EPA Standard pressure Average sq.rtdelta P Average draft gauge reading Average metertemperature Average stack temperature Standard temperature Meter calibration factor Duration ofsampling tIme Nozzle diameter Nozzle area Diameterofstack Cross sectional area of stack 0.84 Pitot tube coefficient 85.49 ftl(Ib/lbmol)·(inHg)1".S}/[**s*R~in**H20] 17637 Rlin.Hg constant 

### 0.047070 cu,ft/ml 0,0026688 in.Hg-cf/ml-R 9705 scf/MMBtu

Instrumental Data 3.97 %-dry 15.36 %-dry 80,67 %-dry 339.4 ppmV-dry constant Pitot tube constant constant From EPA Reference Method 19

Oxygen concentration Carbon Dioxide concentration Nitrogen concentration Carbon Monoxide concentration Page 1Client Project No. Spruance Genco. LLC 3333 Emission Source Unit No_ 4 Test Run Three
Calculations 1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1* Y*Vm * (Pb + dH/13.6) ITm Vmstd = 262.930 dsef 7.446 dsem
2) Volume ofwatervapor collected at standard conditions, Vw(std). Vw(std) = K2 * Vic Vw(std) = 37.533 sef 3) Decimal fraction of moisture by volume In stack gas, Bws.

Bws =Vwstd I (Vmstd+Vwstd) Bws = 0.1249 4) Molecularweight ofthe stack gas on 

### awet basis, Ms.

Ms =

## I ((44*%C02) +**(32~%02)** + (28*%N2» * (1-Bws)] + (18*8ws) Ms= 29.040 Ib/lbmole
5) Average stackgasvelocity, Vs.
Vs = Kp • Cp • (dP) • (Ts/Ps*Ms)".5 Vs 

### = 46390 fps
6) Average actual stack gas volumetric flowrate, Qa.
Qa 

### =60 sec/min *Vs * As Qa = 231914.2 cfm 6567.8 cmm 7) Average stackgas dryvolumetric flowrate, Qstd.
Qstd'" Qa**~** (TstdfTs) * (Ps/Pstd) * (1-Bws) Qsld = 163886,1 dscfm 4641.3 dscmm
8) Carbon Monoxide concentrations and emissions
Carr. C[CO] = {(20.9-02% carr. value)/{20.9-actual avg. 02%value»*Avg, raw CO value E[CO Ib/hr] = (C[CO)*Mol Wt[CO]*60(minfhr)*Qstd(dscfm))/(MolarVol. air*10"6) E[CO Ib/MMBtul = Cd * Fd * (20.9/(20.9-actual 02%» C[CO] = 339.4 ppmVd qCO] 

### = 278.7 ppmVd corrected to 7 % 02 Mol. WI. [CO]= 28 01 Ib/lb-mo[e Molar vol air= 

### E[COJ 

### = Cony Factor. 

### E[COJ = 385 scf/lb-mole @ 68 242.81 Ib/hr 7.235E-08 convert ppmVto IbfscfCO 0.294 Ib/MMBtu defF Page 2

### Appendix 0 

### Calibration Data

# Airgas. CERTIFICATEOFANALYSIS 

# GradeofProduct:EPAProtocol AlrgasSpecialty GaS9S 600 Union LandlnQ Road Riverton. NJ08077 (856) 829-7878 Part Number: E03NI80E15A1087 

### Reference Number: 82-124198678-1 fax (856)829-0571 WWW.a;rgas.com Cylinder Number: CC10892 CylinderVolume: 150 Cu.Ft. Laboratory: ASG· Riverton

- NJ 

### Cylinder Pressure: 2015 PSIG 

### Analysis Date: Nov 18, 2009 Valve Outlet: 590 

### Expiration Date: Nov 18,2012

Cerlificalion performed in accordance with "EPA Traceability Protocol (Sept. 1997)" using the assay procedures lisled. Analytical Methodology does not require correction for analytical interferences This cylinder has a lolal analyllcal uncertainty as slaled belowwith a ronrrdence level of95%. There are no significant impurities which affect the use ofthis calibration mixture. All concentrations are on a volume/volume basis unlessotherwise noted. Do Not Use This Cylinderbelow 150 psig.i.e. 1 Mega Pascal 

## ANALYTICALRESULTS Component Requested Actual Protocol Total Relative Concentration Concentration Method Uncertainty
CARBON DIOXIDE 7.500 % 7.485 % G1 +/·1% NISTTraceable OXYGEN 12.50 % 12.46 % G1**+/~** 1% NISTTraceable NITROGEN Balance 

## CALIBRATIONSTANDARDS Type LotiO Cylinder No Concentration Expiration Date**NTf~Mplus** 06120412 CC184945 19.66% CARBON DIOXIDE/NITROGEN May01,2010 NTRM 03060218 XC024401 B 22.60% OXYGENfNlTROGEN Ju101,2011 

## ANALYTICALEQUIPMENT InstrumenUMakelModel Analytical PrinCiple Last Multipoint Calibration Siemens UJtramat 6E N1·NO·0820 NDIR Oct26,2009 Siemens 5E SN805 Paramagnetic Oct 30, 2009

Page 1of**82·12419a678~1**

15000

# Airgas

.. CERTIFICATEOFANALYSIS 

# Grade ofProduct:EPAProtocol Airgas SpeciallyGases 600Union LaMing Road Rivp,rton, MI 00077 (B56) 829·7878 fa, (055)**S~9-057j** Part Number: E03N!65E15A1094 Reference Number: 

### 82-124165926-1 Cylinder Number" 

### CC7900S Cylinder Volume: 154 Cu.Ft. Laboratory; ASG

- Riverton

- NJ Cylinder Pressure: 2015 PSIG AnalYSIS Date: Feb 02, 2009 Valve Outlet 

### 590 Expiration Date: 

### Feb 02, 2012

Certmoatlon performed In aooordance wllh "EPATraceability Protocol (Sapl 1997)"using Ihe assay procedures lisled.Analytical MethodologydOes not require correction for analytical inlerferences_ This cylinder has a 10lal analytical uncertainlyas slaled below with a conndence level of95%. There are nosignificanlimpurilieswhich affect Ihe use of Ihls calibration mixture.All concentrations sre on avolume/volume basis unless otherwise noled. Do Not UseThis Cylinder below 150 pslg.I.e. 1Mega Pascal 

# -, ANALYTICAL.RlJSULTS

. Component Requested**Act~c'll** Protocol Total Relative



# ...... ' ..... .' .'.

### C~ncetitratloi1

,

## ,'"**~** "- Ccincentratlo!1 lI!Iethofi Uncertainty**"CI:\RB~N** bidxIDE":" 

### '1;2'!Sq "io."; --':,,'**1·2,.'39:·';(~** 

## .:q'!,

-t-I_' 1%

## NIsTTraceable 'OXYGEN 22.00**~.1,** 21.96 % G1 +1·1 %NISTTraceable



## .**NITRO~EN** .

# . -Bal,a'nee, 

### '. '.'



### CALIBRATIONSTANDARDS Type Lot 10 Cylinder No Concentration Expiration Date
NTRM 08061313 CC254791 20.09%**CAR80~1** DIOXIDEINITROGEN Jul 15, 2012 NTRM 03060212 XC0243978 22.60% OXYGENINITROGEN Ju101,2011 

### ANALYTICALEQUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration Siemens Ultramat 6E N1-NO-OB20 NDIR Jan 19, 2009 Siemens SE BN805 Paramagnetic Jan 02, 2009
Triad,pata Available Upon Request

## No~:_i**~-"**

# (:::=~=;)l(

# al**AN!/L,-~l** 

# Cr;[!l!2tc QA Approval

Page 1 of82-124165926_1

15000

# lUqutb ijtccbitoIogp Qi:orporation IndustryLeaderin Specialty

### Gases, Equipmentand Service



### Customer 

### Date Delivery

## Receipt Gas Standard 

### FinalAnalysis Date ExpirationDate 

### CylinderData Cylinder Serial Number: CylinderVolume: ExpirationDate: 

### AnalyticalData CertificateofAnalysis



# - EPAPROTOCOLGAS

-
AirNova (Pennsauken,N

### J) February23, 2010 DR-27602 

### 7.00% C02, 12.0%OxygeniNitrogen

- EPA PROTOCOL February23, 2010 February23, 

### 2013

CC-23316-1 140Cubic Feet February23, 

### 2013 

## DONOTUSE BELOW 150 psig Cylinder Outlet: CylinderPressure: CGA

### 590 20QQJ:>sig, 70°F

EPA Protocol,.SectionNo. 2.2, Procedure G·I

Reference StandardCs): GMISISRM: CylinderNumber: Concentration: Expiration Date: 

## ReplicateConcentrations CarbonDioxide: 7,08% +/- 0,07% Oxygen: 11,9% +/- 

## 0,11% 

## Nitrogen: Balance

GMIS/GMIS 

### CC-159026/CC-165377 5.14% C02110.05%C02 03/3J /l !

- 

### 04/06/11 GMIS/GMIS CC-231332/CC-85458 

### 10.10%OxygenI20.97% 02INitrogen 03/04111

- 

### 04115111


### CertificationInstrumentation Component: Make/Model: 

### SerialNllmpcr: Principal ofMeasurement: LastCalibration: 

### Carbon Dioxide Agilenl7890A

.CNI0736166 TCD February

### 09, 2010 Oxygen Servomex 244a 1847 

### Paramagnetic February 15,2010 Analytical uncertainlyandNISTTraceabilityarein compliancewith

### EPA-600/R-971121.

Certified by: 

### Mike Duncan



## UnmatchedExcellence

2564Pemberton Drive

- Apopka, Florida 32703

- Phone (407)-292-:2990

- Fax (407)-29:2-3313

- www.liquidtechcorp.com

-

# , 

# \ Airgas.
CERTIFICATEOFANALYSIS 

# GradeofProduct:EPAProtocol Alrgas SpecialtyGases 600 Union Lindlng Road RiVlrton,l!IJ08017 (856) 829-7878 Fax (8S6)829-0571 www.alrgis.com Part Number. E03NI65E15A1094 Reference Number: 82-124142222-1 Cylinder Number: 

### CC5693 CylinderVolume" 154 CU.Ft. 

### Laboratory: ASG

- Riverton

- NJ Cylinder Pressure" 2015 PSrG Analysis Date: 

### Jun 

### 23,2008 Valve Outlet: 

### 590 Expiration Date: Jun 

### 23, 2011

Certification performed in accordance wjlh "EPATraceability Protocol (Sept. 1997)"using Iheassay procedures lisled. Analylical Methodologydoes nol require correction for analytical Interferences. This cylinderhilS a lolal anaiylical uncertainty asslated belowwith a confidence level of95%. There are nosignificant impurilieswhich alleclth<l use oflhis callbraUan mixture. All concenlrations are ona voJumal'lOlume basis unless olherwise noled. Do Not Use This CylinderbeloW 150psig,l.e. 1 Mega Pasoal
ANA: 

### RESULTS Component Requested 

# A,,,**~I** Protocol Concentration Method CARBON DIOXIDE 12.50 % 12.38 % G1 OXYGEN 22.00 % 22.03 % G1

. 

### CALIBRATIONSTANDARDS I Type LotiO Cylinder No Concentration

NTRM 03060212 XC024397B 22.60% OXYGEN/NITROGEN NTRM 04060437 XC0343168 19.84%CARBON DIOXIDE/NITROGEN 

### ANALYTICALEQUIPMENT I I I Siemens I NDIR**;5~** I,
Triad Data Available Upon Request Notes:02 CONCENTRATION CORRECTED FOR C02 INTERFERENCE.



# C

.

# Clvx:!**~'"**

# oOe-- QA Approval Tot.11 Relative

-!-/- 1 % NISTTraceable "'/-1% N[STTraceable

Expiration Dale Ju101.2011 May 15,2012

Last I Calibration 

# J":::.:::: Jun •

'Page 1 of82-124142222-1

15000

# Airgas

..

00 

# CERTIFICATEOFANALYSIS Airgas SpeclallvGases 500Unionl.ndlnuRg.d Aiverton.NJ

### oaon 

# GradeofProduct:EPAProtocor::':.:::", www.airg.!s.eom Part Number: E02NI78E15A0346 Reference Number; 82-124093653-1 Cylinder Number; XC0186948 Laboratory: Analysis Date. ASG

- Riverton

- NJ 

### Apr23,2007 Expiration Date: Apr23,2010 CylinderVolume: Cylinder Pressure; Valve Outret 158 Cu.Ft. 

### 2015 PSJG 

### 580

CertIfication performed In accordancewitI'! "EPATraceability Protocol (Sap!' 1997)"using theasuy procedures lisled. Analytical Methodologydoes not require correction for analytical interferences, This cylinderhas a total analytical uncertainlY as slated below wfth a confidence revel of95%. There are no signfflcant impuritieswhioh affectlh.

.. use oflhiscalibraUon mixlura. All concentrations are on avolume/volume basis unless olherwl!e noled. Do Nol UseTillsCyjlnder below 150 pslg.l.e. 1 Mega Pasoal

. 

## ANAU"flCAI.RESULTS Componant R'equesled 'Actual Protocol Total Relative Concentration Concentration Method Uncerialiiity. CARBON DIOXIDE 22.00 % 22.26'% 

### G1 +/-1% NISTTraceable NITROGEN Balance 

### CALIBRATIONSTANDARDS Type 

### LotiO Cylinder No Concentration Expiration Date

, NTRM 00060309 XC034300B 19.64%CARBON DIOXIDE/NITROGEN May 15, 2008 

### ANALYTICALEQUIPMENT Instrument/Make/Model Analytical Principle Last Multipoint Calibration 

## I Nicolet 560AOU9800406 CO/CO2 FTIR Apr 12,2007

Triad Data Available Upon Request 

### Notes:

## ~ c- 

# :hCfu. ..-llet4.."-

QAApprovai

Page 1of82-124093653-1

### Customer Date DeliveryReceipt Gas Standard Final AnalysisDate ExpirationDate Component BalanceGas Analytical Data: 

# LIQUIDTECHNOLOGY CORPORATION "INDUSTRY LEADER IN SPECIALTY GASES"



### Certificate ofAnalysis



# - EPAPROTOCOLGAS

- ** Recertification

# **

AirNova(Pennsauken,NJ) June 

### 03, 2010 DR-2962I 22.28% CarbonDioxidelNitrogen-EPAPROTOCOL May 28,20lO May28,20l3
CarbonDioxide Nitrogen
DO NOTUSEBELOW 150psig EPA Protocol, SectionNo.**2.2~~_~** 

# /

.**~** 

# ., Reported ConcentratIOns

.. 

## CarbonDioxide: 21.7%

# +1- 0.21%

Reference Standards: SRM/GMIS, CylinderNumber: 

### Concentration: 

### Expiratil?n Date:


### CertificationInstrumentation Component: Make/Model: Serial

### Number: 

### Principal ofMeasurement: LastCalibration: 

### CylinderData Cylinder SerialNumber: 

## Nitrogen: Balance

OGMMr;IS'--------·--·--·

. 

### CC-115915 19.44%C02/Nitrogen 

### December 31, 20 [ 1



### Carbon Dioxide Agilent7890A CNI0736166 

### GC-TCD May21,2010

CylinderOutlet: Cylinder Volume: 136 Cubic Feet Cylinder**Pre~sure:** 

### Expiration Date: June 03, 2013 eGA580 1950 psig, 70°F 

### Analytical UncertaintyandNISTTraceabilityare incompliancewith

### EPA-600/R-97112L

Certifiedby: 

### Mike Duncan Original Data: 22.28% C02INitrogen (April 23, 2007) •Airgas: Riverton, NJ 08077

"UNMATCHED EXCELLENCE"
2564 PEMBERTON DRIVE ApOPKA, FLoRIDA 32703

- PHONE (407)·292·2990 FAX (407)-292·3313 

### www liQUIDTECI-ICORP.COMI / 

# t}J!l!f1lPRAXAIR Praxair Distribution Mid-Atlantic lLC 145 Sillmersville 

### Rood· Bethlehem, PA 18015 • 

### Phone: 610.317.1608 • Fax: 610.758.8384

"'!flOwer& Order111/0rllloII0i/: POI WHSE SANFORD NC STORE 1510 HAWKINS AVE SANFORD NC 27330

Expiration Date: Cylinder Number: 17.83 21.36 % %**/),~No~"':<r: OOOOOOOTg~O** **o,,,,-~**N"",h.,,, 172937600 (","",""**I~** (j**~'''I"lJrr: 9557~5Nll**  }'pI/v",,·,

• 4 1',,,,MmWc" /"";<1',,/><,; Ci'''I'ioJrSo<''" O",kl: fjl".I"**p",~,,,,,,** '" v.,/"''''', Cerflj1edCOlI:':'C":I'CU:I:'O::::":'

_______**<>_>_"_"_"_>k_>_~_'_"_",,/w'O** 6130/2012 CC116648
CARBON DIOXIDE 

### OXYGEN Analytical Uncertainly:

± 1 %
± 1% Balance NITROGEN

NO. "PO, • (NO);V.'ua.lorftef

... e"""Only) CerrijicnfiollllljilflJrllffUII: Cerlifi'':iJlion Dale: 613012009 Term: 31;1 Mon.ths Expiralion Dale: 6/30;2012 " Thl£ cyiH1dQ' wa,
.. wried 3CCOlding to lh. 1991 ePATr.oo"U,l,ly Prol,.,.,i. <Iocumool**~ErA.sooJR-g11121.** using proO<XlLO"e G1 2 00 1)0\**~.o l~i.**  ,landard,tpr.,
..,[9IS '0"lhan 150rS1G ,.j.lmlyfil:,d**J)<lI"~** (R=R8ferellco Standard, Z=Zero Gas, C=G8S Candidllle)

, ,Componenl' CARBON DIOXIDe ReqllOolOd**Conca,,~.loon'** 18 '4 CoM,.dCo,""onl.ol"", 11-<>3'l> In'l""llaN I.HA6' Malyl",_1 Mel'",d la

.. Mu,I,,,,,:nl Cal,"'''''on: Fl'stA"oly.l. DolO: 

# ,. 

# , R, 181 Z: 0 UOM: % R, 187 Z: 0 C. 11.04

2 Compon"n" OXYGEN**R.qu~'lO!<l** e""",,"".ll"'"**C.<1fliQ~** e,.,eenl,ol,"" In.l,umen! U••d: Analylical Molhod. l""l Multiprnnl Colib!allOn'
FirstAnalysl. Oat.: 

# , , "**~**

# .. " "00 

# " 0 

# " 0 

# " 21**2~ SI':M~~'5**  ULTP.AMlTSEstl:**D2·~11 NON·~I$prRSlV~** **,,,J'A~~EO** 6/1m2009
Oal.: 

# " 1784 Cane: 

# " \1.84 Cone: 

# " 13.r CO".: Mo.n TeslAss.y,**10.~%**

21.;m% _W". 

# "

# .. 17.83 17,£!3 1163%

SIEMENSQXy,,v,T5ESiNFI·ll, PNWAAGNETIC 61312009
Dolo:**~'24rI()Q9** 

# " 21.28 Cone: 21.38 

# "**~1.3** Cone: 21-4 

# " nU6 Conc' ZI J8 Reterence SlandardTyJ'<i Ret Sld.CYilnclor,4 Ref Sid.Cone

..**~" CCIJ921~**  flef. $ld.T"'ce.bleloSRM#: 13,69%**274~**

Second Analyols Oala: 

# " 0 

# " 0 

# " 0 

# " 0 

# " 0 

# " 0 UOM.- 

# "'

Rer.,o""" SlandardType. Rel Sid. Cyl,nde'**~** . Ref. Sid.CMC. "et Sid Traceablo'aSRM**~,**

. SecondAn.ly.roO.1o:



# " 0 

# " 0 

# " 0 

# " 0 

# " 0 0 0 O.w 

# " 0 Cone' 

# " 0 Cone: 

# " 0 Cone: Me.n TulAssay:



# " 

# " " GIlliS CC1(l.1il6 nS7% 

# ,..,

0<01.: 0 Cone: 0 Cone: 0 Cone, 612512000 NI COla05E·AS 

# "' AS 590 2ooo""i 

# ""

o 

### o o 

# ",

o o o UOI,I' 

# • Mo.nT

..1A.··Y, 21**J8'~** UOM: % Mo.n Tost A.,oy' 0 % Analyzed by: Robin Morgan Certified by. 

## rfK 1,/·01 

# J

IIIO,,,,,,I;ofl**""'M'''''~** horoin ha,**b~n** p,epared al\'<l'" ,oqueslby**qu.li~**..d """"".with;, GTS·W<llo:o I!tc.**'M>~"** 'NO bo"""" iMIlllhe Informa'iOn I. aCCLO".la wilhln lho l,m;l. "Ilhoanalyi,",,1 '''elhodsemployod a"d i,complolo 10 11'0 ""IMIofIne**.p~i~c** analys••pedo,",ed.WO mak" noWOJl1ml/or:Of"".or>talion o.r<> lho**.u'l.bll"~**ollhouS<) 01lho ,nfotmQriCln loralYj' purpose. The 'olo<malo"" IS 011.,,,,,**w~h** (I

..,,,,U."'Md"'9 IMal any uss or Ihe ",Ie,malio" is 81**~,e** soledi,,,,eUon a·,ei ,iskollnou,er. In no evenl**shalll~.** I",bllily .1 GTS-Welco. Inc., .,,''''''oul**~11M** usaoflh. '''I",maloo'' con "'.,,'"M'eon**~xce.a** In" 100 oslat.r

..**".~** fOf providing .uch ,nfO/mallCn.

# lLiquib 

# \!Ccrbnologp <!Corporation IndustryLeaderin SpecIaltyGases, EquipmentandSerVIce 

### Certificate ofAnalysis



### Customer Date DeliveryReceipt Gas Standard Final Analysis Date ExpirationDate Component Balance Gas Analytical Data: 

# - EPAPROTOCOLGAS

-
AirNova(Pennsauken,NJ) January 26, 2010 DR-27309, 

## 4S0

- SOO ppm CarbonMonoxidelNitrogen

- EPA PROTOCOL January

## 2S, 2010 January

## 2S, 2013
CarbonMonoxide Nitrogen
DO NOT USE BELOW 150

## p,ig EPA Protocol,Section No. 2.2, ProcedureG-1 ReplicateConcentrations 

## Carbon Monoxide: 486 ppm 

# +1- 4,8 ppm Nitrogen:Balance

ReferenceStandards: 

## SRM/GMIS: CylinderNumber: Concentration: Expiration Date
CertificationInstrumentation Component: MakelMoctel: Serial Number: Principal ofMeasurement: LastCalibration: 

### CylinderData CylinderSerialNumber: 

### Cylinder Volume: GMIS 

## CC-2SIS49 GMIS 

## CC-2S0292 267.38ppm COlNitrogen November01, 201 1 S

### 1I.S 

### ppm COlNitrogen January 

## OS, 2012

CarbonMonoxide Nicolet

- NEXUS 470 AEP99000lS4 FTIR January 11,2010

CC-2S1891 140Cubic Feet CylinderOutlet: eGA 3SO 

## CylinderPressure: 2000psig, 70°F Analytical Uncertainty and NISTTraceab,ility are in compliance with EPA-6.00/R-971l21.



### Certified by: 

## M;ke Duncan



## UnmatchedExcellence

2564 Pemberton Drive

- Apopka, Florida 32703

- Phone (407)-292-2990

- Fax (407)-292-3313

- www.liquidtechcorp.com-

# Airgas

.. CERTIFICATE OF ANALYSIS 

# Grade of Product: EPA Protocol Airgas SpecialtyGases BOO Union Landing Road Riverton,NJ 08071 (856) 829-7878**Fa~** (B56)829-0571 WWI'/,airgas.wm Part Number. E02NI99E15A0305 Reference Number: 

### 82-124159539-1 Cylinder Number: 8G9147178 Cylinder Volume: 144 Cu.Ft. Laboratory: ASG

- Riverton

- NJ Cylinder Pressure: 2015 PSIG Analysis Date: Dec 04, 2008 Valve Outlet: 

### 350 Expiration Date: 

### Dec04, 2011

Certification parlormed in acoordancB with "cPATracBabillty Proioool (Sept. 1997)" using the essay procedures lisled. Analyllcal Methodologydoes noi require correction lor analytical interferences. This cylinder has II (alai analytical uncertainly as stated**b~lowwilh** II confidence level01 95%. There are no significant impurities which affeeltha use oflhis calibralion**mi~lure.** All concenlralions areon avolumelvoluma basis unless olherwise noled. Do Nol Use This Cylinder belOW 150 psig.l.e. 1 Mega Pascal 

### ANAL,\ 

### ''-'M RESULTS Componenl**~~tual** 

# , I CARBON MONOXIDE 950.0 PPM 935.7 PPM G1

I I 

### CALIBRATION STANDARDS Type lotiO II No Concentration NTRMplus 08060404 CC255339 10024PPM CARBON MONOXIDE/NITROGEN

I I



### ,Ullmm,'"':'>191
Triad Dala Available Upon Request Notes: 

# C

.CV'j 1'0\

# Q1z",CVQAApproval 

### ANALYTICAL EQUIPMENT I I NDIR To", I I**+/-1o/~** NIST Traceable

I 

### ;; Date Apr 15, 2012**~,tI** I Deo 03. 2006

Page 1of82-124159539-1

#5000

# JUquO.l 

# m:erbno{ogp QCorporation

Customer 

## Date DeliveryReceipt Gas Standard FinalAnalysisDate ExpirationDate 

## Component BalanceGas Analytical Data: IndustryLeaderin Specialty

### Gases, Equipmentand

## Servtce 

## Certificate ofAnalysis



# - EPAPROTOCOLGAS

- AirNova(Pennsauken,NJ) January26, 2010 DR-27309 1200ppmCarbonMonoxidelNitrogen

- EPAPROTOCOL January26, 2010 January26,2013 

## CarbonMonoxide Nitrogen
DONOT USEBELOW 150psig EPA

## Protoco1, SectionNo. 2.2, Procedure**G~l** 

### ReplicateConcentrations 

# CarbonMonoxide: 1204 ppm 

# +/- 12 ppm 

# Nitrogen: Balance

Reference Standards: SRM/GMIS: CylinderNumber: Concentration: Expiration Date
CertificationInstrumentation GMIS CC-251970. 1003.2ppm COlNitrogen November 12, 2010



## Component: CarbonMonoxide Make/Model: Nicolet

- NEXUS 470 Serial Number: AEP99000i54 

## Principal ofMeasurement FTIR LastCalibration: January 11, 2010 CylinderData GMIS CC-166608 1539.7ppm COlNitrogen January 12,2012

CylinderSerialNumber: CC-117928 140CubicFeet CylinderOutlet: CGA 350 Cylinder Volume: CylinderPressure: 2000psig, 70°F Analytical UncertaintyandNISTTraceabilityareincompliancewithEPA-iiOOIR-971121.

Certified by:



## . Mike Duncan



## UnmatchedExcellence

25f'4 Pemberton Drive

....Apopka, F(orlda 327(}3

- Phone (4Q7J·Z82-2990

- Fax (407)-292-3313

.... www.llquidtechcorp.com-

# Airgas,
CERTIFICATEOFANALYSIS 

# GradeofProduct: EPA

# Protocol Air!l3S SpeciallyGases 600Union**landin~ Roa~**  Riverton. NJ08071 (B56)829-7378 fa> (856) 829·D571 WWW,alruas_com Part Number: E02NI99E15AOO63 Reference Number: 

### 82-124186914-1 Cylinder Number: 

### CC45673 CylinderVolume: 

### 144 Cu_Ft. Laboratory: ASG

- Riverton

- NJ Cylinder Pressure: 2015 PSIG Analysis Date: Aug 12, 2009 Valve Outlet 

### 350 Expiration Date: Aug 12, 

### 2012

Certification performed**j~ ~ccordance**  with "EPA Traceability Protocol (Sept 1997)" using the assay procedures listed Analytical Methodologydoes not require correction for analytical interferences. This cylinder has a lolal analytical uncertainty as slated below with a confidence level

### or 95%. There are no signi[lcant**jmpurilie~** which allect the use 01 this**c~libralion mi~lure.**  All concenlr6lions ale on avolumaNolumo basis unless otherwise noted. 00 Not Use This Cylinder below 150 pSlg.i.e. 1 Mega Pascal 

### ANALYTICALRESULTS Component Requested Actual Protocol Concentration Concentration Method
CARBON MONOXIDE 2250 PPM 2246 PPM G1 NITROGEN Balance 

### CALIBRATIONSTANDARDS Type LotiO Cylinder No Concentration NTRMpru$ 08060404 CC255339

InstrumentlMake/Model
Siemens 6E**U~ramat** L9 0191

Triad Data Available Upon Request Notes: 

## C

# "!2-.-v~4?

# , QA Approval

Page 1 of82-124166914_1

15000 1002.4PPM CARBON**MONOXIDE/NITROGEi~** 

### ANALYTICALEQUIPMENT Analytical Principle
NDIR 

### \)

. Total Relative

# ~( Uncertainty
+1-1 % NIST Traceable 

### , .'

.i.**~**

, 

# ,

Expiration Date Apr 15, 2012

Last MultipointCalibration Aug 08, 2009

"

# Airgas. CERT,IFICATEOFANALYSIS 

# GradeofProduct: EPAProtocol Airllas Specialty Gases 600U"io" Landing Road Riverton. NJ 00077 (856)829-7878 

### Part Number: E02NI99E15A3865 Reference Number: 82-124195280-1 Fax(1].56) 829-0571 

### Cylinder Number: GG87198 CylinderVolume: 144 GU,Ft. www.airlja.com 

### Laboratory: ASG

- Riverton

- NJ Cylinder Pressure: 2015 PSIG Analysis Date: Oct 27,2009 

### Valve Outlel: 660 

### Expiration Date: Oc127,2011

Certification performed in accordance with "EPATraceability Protocol (Sept. 1997)" using the assay procedures listed. Analytical Methodology does nol require correction ror analytical interferences. This cylinder has a tolal analytical uncertainly as slated belowwith a confidence level of95%. There are no signiflcanllmpurities which affecllhe use ofthis calibration mixture. All concentrations era on e volume/volume basis unlessothelWlse notad,

Component

NITRIC OXIDE NITROGEN
Total oxides of nitrogen

Type Lot 

### 10 Cylinder No NTRM 09060330 CC286961



# , Do Not Usa Tilis Cylinder below 150 psig.i.e. 1 Mega Pascal 

## ANALYTICALRESULTS Requested Concentration
125.0 PPM Balance Actual Concentration 122,1 PPM

122.5 PPM Protocol Method
G1



## CALIBRATIONSTANDARDS Concentration 250.6PPM NITRIC OXIDE/NITROGEN 

## ANALYTICALEQUIPMENT Total Relative Uncertainty
+1-1% NISTTraceable

For Reference Only

Expiration Date Feb 01, 2011

Instrument/Make/Model Analytical Principle Last MultipointCalibration Nicolel6700AHR0801933 NO/NOx rTlR Oct 26 2009 

# I

# ~----------------------------------------------------------------------------'--------------------**~**Availabl. Upon

### Requ.st~ , 

# C I.e,! I 

### r

# .c!'''-:'\.~**(].t:e~** QAl\p oval

Page 1 Qf82-124195280-1

# Airgas. ";**<~"" /,,~.~,** 

Part Number. 

# CERTIFICATEOFANALYSIS**Grad~,;9f**

# Product:**~PA**

# Protocol

-.-+ E02NI99E15A0237 Reference Number. 82-124135439-1 Cylinder Number: 

### CC91627 Cylinder Volume: 144 Cu.Ft 

### Laboratory: ASG

- Riverton

- NJ Cylinder Pressure; 2015 PSIG Analysis Date: May 07, 2008 Valve Outlet: 

### 660 AI1'{I8SSpecIaltyGases 600 Unionlanding Road Ai••rlDn, NJ00077 (856) 629-7678**Fa~** (856) 829·0571
www.ail1JiI..l.com**~-f'** 

### Expiration Date: 

### May 07, 2010

# ==========~~~~==========~, Ce,(mcalion performed in accoroance with "EPA Traceability Protocol (Sept. 1997)"using the assay procedures listed, AnalyticalMethodO,'09y

## ~oes notrequ,'h'

## ~,rreClhion for 4.::.i:

. analylicallnlerferences. ThiS cylinder has a loial analytical uncertaintyas slaled belowwith a conndence leVf.l1 of95%. Thereareno slgni Icanllmpurilles whc a ectt e use """**>,~** oJ this calibration mixture.All concentralionsare on a volume/volume basis unless otherwise noled, 00 NOI Use This Cylinder below 150 pSig.l.e. 1 Mega Pascal

Component

NITRIC OXIDE NITROGEN Total oxides ofmtrogen

Type LotiO NTRM 06060234

Instrument/Make/Model Nicolel470AEP0000416 NO Cylinder No CC207442

Triad Data Available Upon Request 

### Notes' 

### (f"L..::; 

### "3iF;: QA Approval 

### ANALYTICALRESULTS Requested Concentration 2300 PPM Balance Actual Concentration 232.6 PPM

2333 PPM Protocol Method 

### G1



### CALIBRATIONSTANDARDS Concentration 2S7.0PPM NITRIC OXIDE/NITROGEN 

### ANALYTICALEQUIPMENT

Analytical Principle FTIR Total Relative Uncertainity +/-1% NJSTTraceabie

For Reference Only

Expiration Date Jan 01, 2010

Last Multipoint Calibration May OS, 2008 

### ,

Page 1of82-124136439-1

15000

# lUquil:J 

# m:crbnologp <!Corporation IndustryLeaderIn 

### Specialty

### Gases, EquipmentandService



### Customer Date DeliveryReceipt Gas Standard Final Analysis Date 

## ExpirationDaL Analytical Data CertificateofAnalysis



# - EPAPROTOCOLGAS

-
AirNova(Pennsauken, NJ) March25, 2010 DR-27903 50.0ppm SulfurDioxidelNitrogen

- EPAPROTOCOL March25, 2010 March 25, 2012 

## DO NOTUSEBELOW 150psig

EPAProtocol, SectionNo. 2.2, Procedure**G~** 

### 1



## Reference Standard0t SRM/GMIS, 

### CylinderNumber: Concenlration:

. Expiration Date: 

## ReplicateConcentrations SulfurDioxide: 50.6 ppm

## +/- 0.50 ppm Nitrogen: Balance

GMIS 

### CC-231494 50.87 ppm S02INitrogen January

### 28,2011


### Certification I.pstrumentation Component: Make/Model: Serial Number: 

### Principal ofM';:<i

### nrement: Last Calibration 

### Cylinder Data CylinderNumber: CylinderOutlet: Expiration Date: SulfurDioxide Nicolet

- NEXUS470 

### AEP9900015'l. FTIR March 10,2010



### EB-0023444 CGA 660 Match25,2012 CylinderVolume: CylinderPressure: 140 CubicFeet 2000psig, 70°F

Analytical uncertaintyandNISTTraceabilityare in compliancewith EPA-600/R-971l21.



### Certified by: 

## Mike Duncan

UnmatchedExcellence

2564 Pemberton Drive

- Apopka, Florida 32703

- Phone {407}-292-2990

_ Fax {407}-292-3313

- WWW.liquidtl3chcorp.com-

# liraas.

CERTIFICATEOFANALYSIS 

# GradeofProduct:EPAProtocol Alrgas Spe£iallyGases 600 Union landing Road Riverton. NJ 06077 (856)829·1a78 fa>: (855)829-0571 lY\V\v.•iraas.com Part Number: E02NI99E15A0239 Reference Number: 

### 82-124189610-1 Cylinder Number: 

### CC281332 Cylinder Volume: 144 CU.Ft. Laboratory: ASG

- Riverton

- NJ Cylinder Pressure: 2015 PSIG Analysis Date: Sep 03, 2009 

### Valve Outlet: 660 

### Expiration Date: Sep 03, 2011

Certification performed in accordance with "EPA Traceability Protocol (Sept. 1997)" using the IIssay procedures listed. Analytical Methodologydoes not require correction for analytical interferences.**T~is** cylinder has a tOlal analytical uncertainty as**~Ialed** belC)Wwllh a conndence level of95%. Thereare 00 significant impurities which aflecttha use ofthis calibration mixture. All concentrallons are on a volume/volUme basis unless otheJWise noted.

ComponE!nt

SULFUR DIOXIDE NITROGEN

Type Lot 10 Cylinder No NTRM 08061502 CC254449

InstrumenVMake/Model Nicolet 6700 AHR0801933 S02

Triad Data Available Upon Request Notes:

# C~~~(~- QA Approval 00 Not Use This Cylinder below 150psig.i.e. 1 Mega Pascal 

### ANALYTICALRESULTS Requested Actual Protocol Total Relative Concentration Concentration Method Uncertainty

90.00 PPM (19.90 PPM Gj +/-1% N1STTraceabie Balance 

### CALIBRATIONSTANDARDS Concentration ExpiratIOn Date 94.67PPM SULFUR DIOXIDE/NITROGEN Oct 15, 2012 

### ANALYTICALEQUIPMENT

Analytical Principle Last Multipoint Calibration
FTIR AU9 19, 2009

Page 1 Of82-124189610_1

#5000

# 1Liquib 

# \!recbnologp ({orporation IndustryLeaderin SpecialtyGases, 

### EquipmentandService



### Customer Date 

## DeliveryRe'£_:.mn Gas Standard FinalAnalysis Date ExpirationDate Analytical Data CertificateofAnalysis



# - EPAPROTOCOLGAS

-
AirNova(Pennsauken,NJ) March25, 20I0 DR-27903 225 ppm SulfurDioxidelNitrogen

- EPAPROTOCOL March 24,2010 March24, 2012 

# DONOTUSE BELOW 150 psig

EPA Protocol, SectionNo. 

## 2.2. Procedure G-I

Reference StaIldardCs); SRMiGMIS: 

### Cylinder**Numb~r:** 

### Concentration: Expiration Date.


### Certification Instrumentation Component: Make/Model: 

### Serial Number: Principal 

### ofMeasurement: LastCalibration: 

### CylinderData CylinderNumber: CylinderOutlet: ExpirationDate: 

# ReplicateConcentrations SulfurDioxide: 222 ppm**+/~** 

## 2.2 ppm 

## Nitrogen: Balance

GMIS CC-233823 GMIS 

### CC-lS4202 98.02 

### ppm S02INitrogen 

### January 24, 2012 409.1 ppm S02INitrogen 

### March 15,2012

Sulfur Dioxide Nicolet

- NEXUS470 AEP99000154 

### FTIR March 10,2010



### EB-OOI5920 CGA660 March24, 2012 CylinderVolume: CylinderPressure: 140 Cubic Feet 2000psig, 70'F

Analytical uncortainty andNISTTraceabilityare in compliance withEPA-600/R-971121,

Certified by: 

## Mike Duncan

UnmatchedExcellence

2564 Pemberton Drive

- Apopka, Florida 32703

- Phone (407)-292-2990

- Fax (407)-292-3313

- www.liquldtechcorp.com-

# 1Liquib**'Qrecbnolo~p** 

# ([orporation IndustryLeaderin SpecialtyGases, EquipmentandService



### Customer Date DeliveryReceipt Gas Standard Final AnalysisDate ExpirationDate 

## Analytical**Dat~** 

### CertificateofAnalysis



# - EPAPROTOCOLGAS

-
AirNova(Pennsauken, NJ) March25, 20I0 DR-27903 450 ppm 

### SulfurDioxidelNitrogen

- EPAPROTOCOL March24, 2010 March24, 2012 

# DO NOTUSEBELOW 150 psig

EPAProtocol, SectionNo. 2.2, Procedure

## o·}

Reference StandardCs): SRMiOMIS: CylinderNumber: 

### Concentration: Expiration Date:


### CertificationInstrumentation Component: 

### Make/Model; Serial Number: Principal ofMeasurement: Last Calibration: 

### CylinderData CylinderNtonber: CylinderOutlet: ExpirationDate: 

## ReplicateConcentrations SulfurDioxide: 443 ppm 

## +1- 4.4 ppm Nitrogen: Balance

OMIS 

### CC-184202 GMIS CC-115955 409.1 ppm S02INitrogen March 15,2012 758.3 ppm 

### S02INitrogen May05, 201 J



### SulfurDioxide 

### Nicolet· NEXUS 470 AEP99000154 FTIR 

### March 10,2010



### CC-231248 CGA 660 March24, 2012 CylinderVolume: CylinderPressure: 140 CubicFeet 2000psig, 70°F

AnalyticaluncertaintyandNISTTraceabilityare in compliancewith EPA-600/R-971I21.



### Certified by: 

## Mike Duncan

UnmatchedExcellence

2564 Pemberton Drive

- APOPka, Florida 32703

- Phone (407)-292-2990

_ Fax (407)-292-3313

. - www.flquidtechcorp.com

_

# lUquib 

# \!rccbnologp QCorporation IndustryLeaderin SpecialtyGases, EqUipmentand Service



### Customer 

## Date DeliveryRecelvt Gas Standard FinalAnalysis Date ExpirationDate Component Balance Gas Certificate ofAnalysis



# - EPA PROTOCOLGAS

-
Air Nova 

### (Penhsauken, NJ) 

## January 18,2010 DR-27270 5.00ppm Propane/Air

- EPA PROTOCOL January 18,2010 January 18,2013 Propane Air Analytical Data:

. 

## DO NOTUSE BELOW 150 psig EPA Protocol, SectionNo. 2.2, Procedure 0-1

Reference Standards: 

## SRM/GMIS: CylinderNumber: Reported Concentrations 

## Propane: 4.88 ppm +/- 

## 0.04 ppm Air: Balance

GMIS CC-166066 GMIS CC-165367 Concentration: ExpirationDate: 3.05 ppm 

### PropanelNitrogen 

## October02, 2010 19.92 ppm Propane/Nitrogen October02, 2010
CertificationInstrumentation 

## Component Propane Malee/Model: Agilent 

## 7890A SerialNumber: CNI0736166 

## Principal ofMeasurement: GC-FID Last Calibration: January 11, 20I0 CylinderData Cylinder SerialNumber: CylinderVolume: 

## EB-0019898 140 Cubic Feet CylinderOutlet CylinderPressure: 

## CGA590 2000 psig, 70°F Analytical Uncertainty andNISTTraceabilityare in compliancewith

## EPA-600/R-97/121.

Certified by: Mike Duncan



## UnmatchedExcellence

2564 Pemberton Drive

- Apopka, Florida 32703

- Phone (407)-292_2990

- Fax(407)-292-3313

- www.liquldtechcorp.com-

### ( 

# Airgas.
CERTIFICATEOFANALYSIS 

# GradeofProduct: EPAProtocol Airgas SpetiaJlyGases 600 Union Landing RD.d Riv,rton, J>lJ 08077 (856)829-7878**F;)~** (856) 829-0571
www

...gas.com Part Number: E02AI99E15A1486 Reference Number: 

### 82-124188616·1 Cylinder Number: 

### XCOO23688 Cylinder Volume: 146 CLI.Ft. Laboratory: ASG

- Riverton

- NJ Cylinder Pressure: 2015 PS1G Analysis Date: Aug 25, 2009 Valve Outlet: 

### 590 Expiration Date: Aug 25, 2012

Certificalion per/ormed in**acoord~nce** with "EPATroceabillly Protocol (Sept. 1997)"1.I5In9 the assay procedures listed, Analytical Methodologydoes nol require correction for analytical**int9rfere~ces_** This cylinder has a lotal analytical uncertainly as slated belowwilh a conndsnce levelor95%. Ther",**~re** nosignirlcant impurities which affect Ihe use or this calibration mixlure. All concentralions are on a volume/volume besis unlessolherwi!EI noled. Do Nol Use This Cylinder below 150 psig.l.e. 1 Mega Pascal 

### ANALYTICALRESULTS Component Requested Actual Protocol Total Relative Concentration Concentration Method Uncertainty PROPANE 9.000 PPM 9.099 PPM G1 +/-1% NISTTraceable Air Balance 

### CALIBRATIONSTANDARDS Type LotlD Cylinder No Concentration Expiration Date NTRM 06061410 CC20S963 9.49PPM PROPANE/AIR Oct 02, 2010 

### ANALYTICALEQUIPMENT InstrumentiMakefModel Analytical Principle Last MultipointCalibration Nicole1470 AEP0000416 C3H8 FTIR Aug 20, 2009

Triad ta Available Upon Request 

### Not s: -QA-Appfoval

Pilge 1 of82·1241811616·1

15000

# J'Liquib 

# m:ccbnologp QCorporation IndustryLeaderin SpecialtyGases, Equipmentand Service



### Customer Date Delivery Receipt Gas Standard Final Analysis Datf: ExpirationDate Component BalanceGas Analytical Data: 

## Ce11ificate ofAnalysis



# - EPAPROTOCOLGAS

- AirNova (PelUlSClUken, NJ) January 18, 2010 DR-27270 18.0 ppmPropane/Air

- EPAPROTOCOL January 18,2010 January 18,2013 Propane 

## Air
DONOT USE BELOW 150psig EPA Protocol, SectionNo. 2.2, ProcedureG·l

Reference Standards: SRM/GMIS: CylinderNumber: Concentration: Expiration Date:
Certification Instrumentation Reported Concentrations 

## Propane: 17,4 ppm +/- 

## 0,17 ppm Air: Balance

GMIS CC-166066 3.05 ppm 

### PropanelNitrogen October02, 2010 GMIS CC-165367 19.92

### ppm Propaneli."Jitrogen 

### October 02, 2010


## Component: Propane Make/Model: Agilent7890A SerialNumber: CN10736166 

## Principal ofMeasurement: GC-FID LastCalibration: January 11, 20ID 

### CylinderData Cylinder Serial Number: Cylinder Volume: EB-0019899 140 CubicFeet Cylinder Outlet: CGA 590 CylinderPressure: 2000psig, 70°F Analytical UncertaintyandNISTTraceabilityare in compliancewith EPA-600/R-971121.

Certified by: 

## Mike Duncan

UnmatchedExcellence

2564 Pemberton Drive

- Apopka, Florida 32703

- Phone (407)-292-2990

- Fax (407)-292-3313

- www.flqu/dtechcorp.com

-PrOJ 3333 NOx ConverterTest Outlet NOx Trailer

- 2

Step 1.
Step 2.

Step 3.

Step 4.

Step 5.

Step 6.

Step 7. AirNova, Inc. NOx Converter EffeciencyTest

Date
Analyzer ID

Analyst Range Cal. Standard April 12, 2010

TECO Model 10 Chemilumlnescent

KZ 502.9 502.9

Verify that all tubing is properly connected and securely fastened ppmV Nitric Oxide

Adjust the NOx analyzer to the correct span gas concentration and record the response.

Turn on oxygen (zero air) flow and adjust to blend the NO span gas and oxygen to dilute the span concentration by 10% ofthe span gas value. (example = 90.0 ppmV NO reduced by 10% is 81.0 ppmV NO,) Record the response.

Turn on the TEeO 100B NOx Ozonatorvoltage, and increase the voltage until the analyzers NO response is 20% ofthe span gas value. (example20% of90.0 ppmV NO is 18.0 ppmV NO), Record the response.

Turn the NOx analyzerfrom the NO mode to NOx mode, Allowfor a stable response by the NOx analyzer. and record the concentration_

Turn offthe TECO 1008 NOx Ozonator voltage. and allow for a stable response by the NOx analyzer. Record the concentration.

Calculate the NOx converter effeciency by the following equation:

STEP 5

- STEP 4 X 100% = % Converter Effeciency STEP 6

- STEP 4 OK

502.9

450,2

99.3

444.5

449.6



### 98.5

NOx Converter Effeciency must be > 90 % (SOURCE: 40CFR. Part 60, Appendix A, Method 20, Sec. 3.1) INPUT

INPUT

INPUT

INPUT

INPUT

% EffeciencyProj 3333 NOx ConverterTest Rosemont NOx Trailer - 1

Step 1.
Step 2.

Step 3.

Slep4.

Step 5.

Step 6.

Step 7 AirNova, Inc. NOx Converter EffeciencyTest

Date
Analyzer ID

Analyst Range Cal. Standard April 20, 2010

Rosemont NOx Chemiluminescent

LDK 232.6 232.6

Verify that all tubing is properly connected and securely fastened ppmV Nitric Oxide

Adjust the NOx analyzerto the correct span gas concentration and record the response.

Turn on oxygen (zero air) flow and adjust to blend the NO span gas and oxygen 10 dilute the span concentration by 10% ofthe span gas value. (example = 90.0 ppmV NO reduced by 10% is 81.0 ppmV NO.) Record the response.

Turn on the TEeO 1008 NOx Ozonatorvoltage, and increase the voltage until the analyzers NO response is 20% ofthe span gasvalue. (example20% of90.0 ppmV NO is 18.0 ppmV NO). Record Ihe response.

Turn the NOx analyzer from the NO mode to NOx mode. Allowfor a stable response by the NOx analyzer, and record the concentration.

Turn offthe TEeO 100B NOx Ozonator voltage, and allow for a stable response by the NOx analyzer. Record the concentration

Calculate the NOx convertereffeciency by the following equation:

STEP 5 - STEP 4 X 100% 

### = % Converter Effeciency STEP 6 - STEP 4 

## OK

232.6

207.8

45_7

2042

207.7

97.8

NOx Converter Effeciency must be > 90 % (SOURCE: 40CFR, Part 60, AppendixA, Method 20, Sec. 3_1) INPUT

INPUT

INPUT

INPUT

INPUT



### % EffeciencyProj 3333 NOx ConverterTest Rosemont NOxTrailer - 1

Step 1.
Step 2.

Step 3.

Step 4.

Step 5.

Step 6.

Step 7 AirNova, Inc. NOx Converter EffeciencyTest

Date
Analyzer 10

Analyst Range Cal. Standard April 15, 2010

Rosemont NOx Chemiluillinescent

LDK 232.6 232.6

Verify that all tubing is properly connected and securelyfastened PPIllV Nitric Oxide

Adjust the NOx analyzer to the correct span gas concentration and record the response.

Turn on oxygen (zero air) flow and adjust to blend the NO span gas and oxygen to dilute the span concentration by 10% ofthe span gas value. (example 

### =90.0 ppmV NO reduced by 10% is 81.0 PPIllV NO.) Record the response.

Turn on the TECO 100B NOx Ozonatorvoltage, and increase the voltage until the analyzers NO response is 20% ofthe span gas value. (example20% of 90.0 ppmV NO is 18.0 ppmV NO). Record the response.

Turn the NOx analyzerfrom the NO mode to NOx mode. Allowfor a stable response by the NOx analyzer, and record the concentratIon.

Turn offthe TECO 100B NOx Ozonator voltage, and allow for a stable response bythe NOx analyzer. Record the concentration.

Calculate the NOx converter effeciency by the following equation:

STEP 5 - STEP 4 X 100% = % Converter Effeciency STEP 6 - STEP 4 

### OK

232.6

208.4

46.7

205.9

208.7



### 98.3

NOx Converter Effeciency must be ;> 90 

### % (SOURCE: 40CFR, Part 60, Appendix A, Method 20, Sec. 3.1) INPUT

INPUT

INPUT

INPUT

INPUT



### % EffeciencyProj 3333 NOx ConverterTest Outlet NOxTrailer- 2

Step 1 Step 2

Step 3.

Step 4

Step 5

Step 6.

Step 7. AirNova, Inc. NOx Converter EffeciencyTest

Date
Analyzer 10

Analyst Range Cal. Standard April 19, 2010

TEeo Model 10 Chemiluminescent


### MDD 450.9 450.9

Verifythat all tubing is properly connected and securely fastened ppmV Nitric Oxide

Adjust the NOx analyzer to the correct span gas concentration and record the response.
Turn on oxygen (zero air) flow and adjustto blend the NO span gas and oxygen to dilute the span concentration by 10% ofthe span gas value. (example = 90.0 ppmV NO reduced by 10% IS 81.0 ppmV NO.) Record the response.
Turn on the TEeO 1008 NOx Ozonatorvoltage, and increase the voltage until the analyzers NO response is 20% ofthe span gas value. (example20% of90.0 ppmV NO is 18.0 ppmV NO). Record the response.
Turn the NOx analyzerfrom the NO mode to NOx mode. Allowfor a stable response by the NOx analyzer, and record the concentration.

Turn offthe TEeO 1008 NOx Ozonatorvoltage, and allow for a stable response by the NOx analyzer. Record the concentration.

Calculate the NOx convertereffeciency by the following equation:

STEP 5 - STEP 4 X 100% = % Converter Effeciency STEP 6 - STEP 4 OK

450.9

403.8

89.3

399.1

402.9



### 98.8

NOx Converter Effeciency must be > 90 % (SOURCE: 40CFR, Part 60, AppendixA, Method 20, Sec. 3.1) INPUT

INPUT

INPUT

INPUT

INPUT

% Effeciency

### Reference Point

1



## 2

3



## 4 Source



### Ice Water


### BoiJing Water

Very Hot Oil Bath

Ambient Temp. 

# AirNova,Inc. Pitot Thermocouple Calibration data

Date. Thermocouple 1.0. :
Probe Length:
Calibrator
Ambient Temp,(F):
Barometric Pressure (" Hg):
Reference Thermometer:



### Ref. Thermometer Temp,(F)

37

207

358

62



### Average Temp. Change: Thermocouple Temp,(F)

35

209

360

61

Temperature Difference mustbe < 

### 1.5 

### %



### Signature:

# /(~J.C{UL , '11/17/09
AN-U5A

5 Foot


## KA
62
30.10
ASTM-2F

Temperature 

### Diff, (%)



### 0.4%

0.3%

0.2%



### 0.2%

0.3%

## . :**~** 

### ;**~** " 

### .

.

# .

# .

# . . ....

.'

# ....... ' .

........ • 0. 

# A.- 

# rNova. I

. ...•••••...

_ n c . ••• 

# •

# •

# •• • • •• '" 

# ....... '



# .........

,**~**

# . .. " 

### . 

### Type 5 PitotTube Dimensional Specification Verification Form
Pitot No. Calibrator Date II

# /0/rr'I'


# . , 

### Verify the following criteria and checkall that apply

1) 

### Face opening plane perpendicularto the transverse axis?**,~** 

# '.--------- 2) Face-opening plane parallel to the logitudinal axis?

__**~** .:--. 

### 3) Are LegsA 

## & B ofequal length and are centerlines coincident?

__ _

Ifall the above criteria are met, a pitot coeffecient of

## 0.84 may 

## be assigned to the respective pitottube. Ifone ofthe following criteria above is not met, the pitottube must be calibrated in a wind tunnel.

Recommended Dimensions


## 4) Diameter of pitottubing? (Dt) 

## = 

## ,375' in. 

## (0.1875 < 

### Dt < 

## 0.375) 5) Dimensions of Pa = ·5t)(;> In. 

### PaiDt 

## = 

# i. 3) 

## (1.05 < 

### Dt < 

## 1.50) 6) Dimensions of Pb = 

### ,5"0 

### in. 

### Pb/Dt

## = /,3 7 (1.05 < 

### Dt < 

## 1.50)**rRUS'\lE~$(** I' ,. Tun Al($ 

# .lB2j_.**t--o::;[~Q-f**

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# .............



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# :::

......

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. .. _. 

# _ .


# ...........



# " 

# -E-. ,'" Er-'

### Reference 

### Point



## 1

2



### 3

4 

### Source

Ice Water

BOiling Water

Very Hot Oil Bath

Ambient Temp. 

# AirNova, Inc. PitotThermocouple Calibrationdata

Date: Thermocouple 1.0. :
Probe Length:
Calibrator
Ambient Temp,(F):
Barometric Pressure (" Hg):
Reference Thermometer:



### Ref. Thermometer Temp,(F)

34

210

358

62



### AverageTemp. Change: 

### Thermocouple Temp,(F)

35

210

360

61

Temperature Difference mustbe <: 

### 1.5 

### %



### Signature: 

# /t'**~** 

# {, atL- '11117109
AN-U5E


### 5 Foot


## KA

62
30,10
ASTM-2F



### Temperature 

### Dill, (%)



### 0.2%

0.0%



### 0.2%

0.2%



### 0.1%

Date: J(

# I, 7/0<:';· 

# . .

# . .. . 

# ·

# ......**~**

# .......**~.**

# ;'::;;:::::~ 

# AirNova, Inc.

•

### •

## • •

# •

# ••• • ••



## . .

# .

# .

# ... ... '



# ....... .'

.

· '. 

# . . . : Type S PitotTube Dimensional Specification Verification Form
Pitot No. Catibrator Date JI/17/0 

# f
, Verifythe following criteria and check all that appty
1) Face opening plane perpendicularto the transverse axis? _---- __ 

# .------- 2) Face-opening plane parallel to the logitudinal axis?

__ _ 3) Are Legs A & 

## Bofequal length and are centerlines coincident?

Ifall the above criteria are met, a pitot coeffecient of 0.84 may be assigned to the respective pitot tube. Ifone ofthe following criteria above is not met, the pitottube must be calibrated in a wind tunnel.

Recommended Dimensions

4) Diameter of pitottubing? (Dt) 

## = •

## 3?s in. 5) Dimensions of Pa = .712- in. PaiDt= 

## 1.37 (1.05 < 

## Dt < 

## 1.50) 6) DimensionsofPb= (51.). 

## in. Pb/Dt= /'

## J"7 (1.05 < 

## Dt < 

## 1.50)**ra~~!iVE~SE** [' 

# i rUle**~~lS** •



# ...."

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### Reference Point



### 1

2



### 3

4 Source

Ice Water

Boiling Water

Very Hot Oil Bath

AmbientTemp. 

# AirNova, Inc. Pitot Thermocouple Calibration data

Date: 

### Thermocouple J.D. :
Probe Length:
Calibrator
Ambient Temp.(F):
Barometric Pressure 

### (It Hg):
Reference Thermometer:

Ref. Thermometer Temp,(F)

34

208

351

62

Average Temp. Change: 

### Thermocouple Temp.(F)

32

209

352

62

Temperature Difference mustbe < 

### 1.5 % 

### '11/17/09
AN-50


### 5 Foot
KA
62
30.10
ASTM-2F

Temperature 

### Dill. (%)

0.4%



### 0.1%

0.1%



### 0.0%

0.2%



### Date:

### - 

### .- ' 

# . , -, -

-

# ...... , 

### - 

# ........--

# ~-;;:;:::::~ 

# AirNova, Inc.

-,

# ........ -

-

### -

# ....... --



### -

# ...... ' 

### - 

## Type S PitotTube

- 

### , , -



### -

# . . .- 

### Dimensional Specification Verification Form


## Pitot No. Calibrator Date Ii 

# ((lltrr

Verify the following criteria and check all that apply

1) 

## Face opening plane perpendicular to the transverse axis?

__ -_- 2) 

## Face-opening plane parallel to the logiludinal axis? _...:-----::.. 3) 

## Are Legs A & 

### B 

## ofequallen'gth and are centerlines coincident?**~.**



## If all the above criteria are met, a pitot coeflecient of 0.84 may be assigned to the respective pitottube. Ifone ofthe following criteria above is not met, the pitottube must be calibrated in a wind tunnel.

Recommended Dimensions



## 4) Diameterofpitot tubing? (Dt) = • 

## J 75in. (0.1875 

## < Dt 

## <0.375) 

## 5) Dimensions of Pa 

## = 

# ·:fI/) in. PalOt

## = 

## /-3(" (1.05 < 

## Dt < 

## 1.50) 6) Dimensions of Pb = 

### ..-5'/1> in. 

## PblDt 

## = / • 

# ..Jt. (1.05 < 

## Dt < 

## 150)**Tft~UVERH** I' 

# I
lUI!**1.~4S** 

# .lE921-·**t--0::;r~Q-I**

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# ~~**~~".I** ;:':<"'"'
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### Reference Point



## 1

2

3



### 4 Source

Ice Water

Boiling Water

Very Hot Oil Bath



### Ambient Temp. 

# AirNova, Inc. Pitot Thermocouple Calibl'ation data

Date' 

### Thermocouple LD.

Probe Length:


### Calibrator
Ambient Temp.(F):
Barometric Pressure (" Hg):


### Reference Thermometer:

Ref. Thermometer Temp,(F)

33

211

342

62



### Average Temp. Change: Thermocouple Temp,(F)

34

212

342

62

Temperature Difference mustbe < 

### 1.5 

### % '11/17/09


### AN-5H

5 Foot


## KA
62
30.10
ASTM-2F

Temperature 

### Dill, (%)



### 0.2%

0.1%

0.0%



### 0.0%

0.1%

Date: 

## tL(, 7/0

# ~

## . .

. 

# . . .

.

# .

# .

# . . ....

.'

# ...... '. 

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# _______________ _ "

# ....... " 

# ......... "



# ......... Type S PitotTube



## .**~** 

# . .. " . 

### Dimensional Specification Verification Form
Pitot No. Calibrator Date 

# AI"-5

# H 11(17/0 

## 1

Verifythe following criteria and check all that apply

(...---'- 

### 1) Face opening plane perpendicularto thetransverse axis?

__ _ 

### 2) Face-opening plane parallel tothe logiludinal axis?

## ",~ 3) Are Legs A 

### & B ofequal len'gth and are centerlines coincident?

__ -_ -

Ifall the above criteria are met, a pitot coeffecient of0.84 may be assigned to the respective pitottube. Ifone ofthe following criteria above is not met, the pitottube must be calibrated in a wind tunnel.



### Recommended Dimensions

4) Diameterof pilottubing? (01) 

## = ,37£in. (0.1875 

### < Dt 

### < 0.375) 5) Dimensions of Pa 

## = 

## ·Iio/} in. 6) Dimensions of Pb 

## = 

# ,5tJ P in. PaiDt

## = i, J} 

### (1.05 

### < Dt 

### < 1.50)
PbfOl

## = 

# /.1J (1.05 < 

### 01 < 

### 1.50)

## TftA~SVUISt I' I' lUll "'_IS 

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### Reference Point



## 1

2

3

4 Source

Ice Water



### Boiling Water

Very Hot Oil Bath



### Ambient Temp. 

# AirNova, Inc. PitotThermocouple Calibration data

Date: Thermocouple 1.0.
Probe Length:


### Calibrator
Ambient Temp,(F):


### Barometric Pressure (" Hg):
Reference Thermometer:

Ref. Thermometer 

### Temp.(F)

34

211

353

62

Average Temp. Change: Thermocouple 

### Temp.(F)

33

212

351

63

Temperature Difference mustbe < 1.5%



### Signature ;(

# o'A~u:u1 

# (; 

# t:lt1-- • '11/17/09


### ANT5A

5 Foot
KA


### 62
30.10
ASTM-2F

Temperature 

### Ditt. (%)

0.2%

0.1%



### 0.2%

0.2%

0.2%



### Date:. ; 

# .

# .. .•

. 

# .........

. .'

# ........**~;:;:::::::** 

# AirNova, Inc.. ••• 

# •

# •

# •• • • •• •• 

### • 

# •

# • • • • •••

.

# .

# .

# .. ... . 

### Type S PitotTube

.**~**

# . . .:


## . Dimensional Specification Verification Form
Pitot No. Calibrator Date

Verifythe following criteria and check all that apply



### 1) Face opening plane perpendicularto the transverse axis?**~~** 

## 2) Face-opening plane parallel tothe logitudinal axis?

__ _



# ----- 3) Are LegsA & B ofequal length and are centerlines coincident?

__

Ifall the above criteria are met, a pitot coeffecient of

## 0.84 may be assigned to the respective pitottube. Ifone ofthe following criteria above is not met, the pitottube must be calibrated in awind tunnel.



### Recommended Dimensions

4) Diameter ofpitottubing? (01) 

## = .]**7~**in. (0.1875 

### < Dt 

### < 0.375) 

### 5) Dimensions of Pa

# = .;i/O In. 

### PaiDt 

## = 

## /,3C- (1.05 

### < Dt 

### < 1.50) 6) Dimensions of Pb = 

### ·5(6 in. Pb/Dt 

## = //3(. (1.05 < 

### 01 < 

### 1.50)

## 'A"~;VE~$E I' " rUle "XIS 

# lESEj_.**t-o;t;,~~-1** "-""EI

.



# ,,'



# , ...·:IT.'·-'-f,±i

# ::±;'-:=;::$"':'=F,".'

# ::::<"'"'

,."
...d**~** ." •••••

. .- - .. - .


# ..........., 

# " 

# '-S=.-"

. -E-3--.

## AirNova, Inc. 

## Dry gas meter & orifice Calibration data and calculations
Meter Box #: 

### 4 Checked with Pump #: 

### 4 

### '2/2/10

KA



### delta H 

### = 

### Pb

# = Time = 

### 0.5 in. H20 

### 30.05 in. Hg

19.0 

### min.
Std Test Meter Data
IVw= FVw= 

### TVw= tw=

delta H = 

### Pb

## = Time 

## = 174.977 182.851 7.874 62



### 1.0 In. H20 

### 30.05 in. Hg

14.0 

### min.
Std Test Meter Data
IVw= FVw= TVw= 

## tw =



### delta H = 

### Pb = 

### Time = 

### 166.969 174.977 8.008 62

1.5 in. H20 

### 30.05 in. Hg

11.0 

### min.
Std Test Meter Data
IVw= FVw= TVw= 

### tw= 

### 159.362 166.969 

### 7.607 62 Date: 

### Calibrator:



### Dry Test Meter Data
IVd = 

### 185.789 FVd= 

### 193.678 TVd 

### 7.889 ltd = 

### 58 Ftd= 

### 55 Avg. 

### td = 

### 56.5



## Dry Test Meter Data
IVd= 

### 177.777 FVd = 

### 185.789 TVd 

### 8.012 ltd = 

### 68 Ftd= 

### 63 Avg. 

### td = 

### 655

Dry Test Meter Data
IVd = FVd = 

### TVd ltd = Ftd= Avg. 

### td 

## = 170.171 177.777 

### 7.606 68 62 65 "Yi


### 1.620 0.986

"H@i 

### "Yi


### 1.672 1.004

'H@i 

### "Yi


### 1.717 

### 1.002

Pg. 1 of 2

### Date: '2/2/10



### delta H = Pb = Time = 20 in H20 30.05 in. Hg 10 

### min. 

### Std Test Meter Data
IVw= FVw= TVw= 

## tw =



### delta H 

### = Pb = 

### TIme = 151.200 159.362 8.162 61

3.0 in. H20 30.05 in. Hg 8.0 

### min.
Std Test Meter Data
IVw= 

### FVw= TVw= 

## tw =



### delta H 

### = Pb = Time 

### = 142.993 150.950 7.957 60

4.0 in. H20 30.05 in. Hg 

### 7 min.
Std Test Meter Data


# rvw= FVw= TVw= 

## tw= 134.970 142.993 8.023 60 

## AirNova, Inc, Calibration Data

Dry Test Meter Data


### IVd= 162.038 

### FVd = 170.171 

### TVd 8.133 

### ltd = 67 

### Ftd= 61 Avg. 

### td = 64

Dry Test Meter Data


### IVd= 153.940 

### FVd = 161.789 

### TVd 7.849 

### ltd = 65 

### Ftd= 59 Avg. 

### td = 62



### Dry Test Meter Data
IVd = FVd = TVd ltd = Ftd= Avg. 

### td = 146.047 153.940 7.893 63 58 60,5 

## Avg,AH@=

Signature: 

# L<J;;!L

# d~ , 1,66 MB#: 4



## "Yi
1.641 1.004

"H@i 

## "Yi
1.657 1.010

"Yi


### 1.669 1.008



## Avg, Y = 1,00

Date: 

# ?/?-./;u Pg.2of2

## AirNoV8, Inc. 

## Calibration data and calculations Meter BoxTemperature Sensors

Meier Box#: Date: Calibrator: Ambient Temp. (F): Barometric Pressure ("Hg):

Reference Thermometer:



### Dry Gas MeterThermocouple· INLET

Reference POlDt Ref. Thermometer Temp. (F)

Ambient Temp. 

### 55 Hot Water (104-122F) 

### 110 

### Dry Gas MeterThermocouple - OUTLET

Reference Point Ref. ThermQmfltflr Temp. CF)

Ambient Temp. 

## 55 Hot Water (104-122F) 

### 113
note: tolerance for inlet and outlet = +/- 5.4 F 

### Thermocouple connector/lED readout:

Ref. Thermometer Temp. (F)


### 1 Stack 

## 55 2 Probe 

## 55 3 Filter 

## 55 4 Dryer 

## 55 5Aux 55

note: tolerance = +/- 2 F 

### 4 '2/2/10 

### KA 

## 55 30.20 ASTM-2F

Thermocouple

Temo. (F) 

## 54 112

Thermocouple

Temp. (F)


### 54 110

ThermocouQle

Temp. (F) 

## 54 55 55 55 55 Diff.


### 1 

### 2

Diff.



### 1 3

Diff.



### 1 0 0 0 0



## Signature:

# ,L/t~c 

# t2?L.- Date: 

# ;>-/"-//0

## AirNova, Inc. 

## Dry gas meter & orifice Calibration data and calculations
Meter Box #. 

### Checked with Pump #: 

### Date: Calibrator: 

### 5 5 '2/9/10



### KA



### delta H = 0.5 in H2O Pb = 29.97 

### in. 

### Hg Time = 19.0 

### min.


### Std Test Meter Data 

### Dry Test Meter Data


### IVw= 487.046 IVd = 623.455 FVw= 494.825 FVd = 631.166 TVw= 7.779 TVd 7.711 tw= 58 ltd = 63 Ftd= 60 Avg. td = 615



## ------------------

## --- delta H = 1.0 in. H2O Pb = 2997 in. Hg Time 

### = 23.0 

### min.
Std Test Meter Data Dry Test Meter Data


### IVw= 473.964 IVd= 610.560 FVw= 487.046 FVd = 623.455 TVw= 13.082 TVd 12.895 

## tw

# = 57 ltd = 62 Ftd= 59 Avg. td = 60.5



## --------------------- delta H = 1.5 in. H2O Pb= 29.97 

### in. Hg Time

# = 15.0 

### min.
Std Test Meter Data 

### Dry Test Meter Data
IVw= 463.755 IVd= 600.565 FVw= 473.964 FVd = 610.564 TVw= 10.209 TVd 9.999 

## tw = 

### 55 ltd = 60 Ftd= 56 Avg. td = 58 

### "H@i 

### "Vi
1.623 1.014



### "H@i 

### "Yi
1.679 1.019

"H@i 

### "Yi
1.754 1.023

Pg.1 of2

## AirNova, Inc. Date: '2/9/10 

## Calibration Data MB#: 5



## ---------------------
delta H 

### = 2.0 in. H2O Pb = 29.97 in. Hg Time 

### = 13.0 

### min
Std Test Meter Data Dry Test Meter Data 'H@i 

## "Yi
IVw= 453.446 IVd = 590.535 1.726 1.025 FVw= 463.755 FVd = 600,565 TVw= 10.309 TVd 10.030 

## tw= 54 ltd = 57 Ftd= 53 Avg. td = 55

--------------------- 

### delta H = 3.0 in. H2O 

### Pb = 29.97 in. 

### Hg Time = 12.0 min.
Std Test Meter Data 

### Dry Test Meter Data "H@i 

### "Yi
IVw= 441.774 IVd= 579.275 1.724 1.027 FVw= 453.446 FVd = 590.535 TVw= 11.672 TVd 11 260 

## tw = 

### 53 ltd = 54 Ftd= 50 Avg. td = 52

--------------------- 

### delta H = 4.0 in. H2O Pb = 29.97 

### in. Hg Time 

### = 6.0 

### min.
Std Test Meter Data 

### DryTest Meter Data IIH@i 

### "Vi
IVw= 432.756 IVd = 570.645 1.707 1.032 FVw= 441.774 FVd = 579.275 TVw= 9.016 TVd 6.630 

## tw = 

### 51 ltd = 50 Ftd= 49 Avg td = 49.5

--------------------- 

## Avg,AH@= 1.70 Avg. y= 1.02

Signature: 

# (

# ~c' / -'_Z' 

# ()jL Date:

# 2/'l**~J** P9· 2of2

## AlrNova, Inc. Calibration data and calculations Meter Box Temperature Sensors

Meter Box#: Date' 

### Calibrator: AmbientTemp. (F): Barometric Pressure ("Hg):



### Reference Thermometer:



### Dry Gas MeterThermocouple • INLET

Reference Point Ref, Thermometer Temp (F)

AmbientTemp. 

## 48 Hot Water (104-122F) 

### N/A 

### Dry Gas MeterThermocouple - OUTLET

Reference Point Ref. Thermometer 

### Temp. (Fl

Ambient Temp. 

## 48 Hot Water (104-122F) 

### N/A


### note: tolerance for inlet and Qutlet 

## =+/- 

### 5.4 F Thermocouple connector/LED readout:
Ref, Thermometer Temp (F)


### 1 Stack 

## 48 2 Probe 

## 48 3 Filter 

## 48 4 Dryer 

## 48 5Aux 

## 48

note: tolerance 

## =+/- 

### 2 F



## Signature: 5 '01/05/09 

## KA 48 30.00 ASTM-2F

The[mQ!:;Q!.H2Ie



### Temp. (Fl 

## 48 N/A

ThermocQuglf!

Temp. (Fl 

## 48 N/A

Ib§:rmQQQUQle

Temp, (Fl 

## 48 48 48 48 48 Diff.


### 0 0

Diff.


### 0 0



# om,
0 0 0 0 0

## AirNova, Inc. 

## Dry gas meter & 

## orifice Calibration data and calculations

Meter Box 

### #: 

### 6 Checked with Pump 

### #: 

### 6 '212110



### KA Date: Calibrator:



### delta H = 0.5 in. H2O Pb = 30.10 in. Hg Time

# = 18 

### min.
Std Test Meter Data Dry Test Meter Data


### IVw= 76.589 IVd = 170.545 FVw= 

### 83920 FVd = 178.235 TVw= 7.331 TVd 7.690 tw= 60 ltd = 60 Ftd= 80 Avg. td = 70
._--""-"-"-""-""-""-" 

### delta H = 1.0 in. H2O Pb = 30.10 

### in. Hg Time

# = 13 

### min.
Std Test Meter Data Dry Test Meter Data


### IVw= 83.920 IVd= 178.235 FVw= 91.321 FVd = 186.140 TVw= 

### 7.401 TVd 7.905 tw = 

### 61 ltd = 80 Ftd= 88 Avg. td = 84

""-""-"-"""-""--"---" 

### delta H = 1.5 in. H2O Pb = 30.10 

### in. Hg Time

# = 11 

### min.
Std Test Meter Data Dry Test Meter Data
IVw= 

### 91.321 IVd = 186.140 FVw= 

### 98.819 FVd = 194.214 TVw= 7.498 TVd 8.074 tw = 

### 59 ltd = 90 Ftd= 90 Avg. td = 90 

### AH@i AYi
1.620 0.970



### AH@i AYi
1.621 0.975



### AH@i flYi
1.665 0981

Pg. 1 0[2

## AirNova, Inc. Date: 

### '2/2/10 

## Calibration Data MB#. 

### 6



## ---------------------
delta H = 

### 20 in H2O Pb = 

### 30.10 in. Hg 

### Time = 

### 10 min.
Std Test Meter Data Dry Test Meter Data "'H@i 

### "'Vi
IVw= 

### 99.819 IVd = 

### 194.214 1.734 0.980 FVw= 

### 107.497 FVd = 

### 202.540 TVw= 

### 7.678 TVd 

### 8.326 

## tw = 

### 58 ltd = 

### 93 Ftd= 

### 93 Avg. td = 

### 93



## --------------------- delta H = 

### 3.0 in H2O 

### Pb = 

### 30.10 in. Hg Time

# = 8 min.


### Std Test Meter Data Dry Test Meter Data 

### AH@i 

## "Yi
IVw= 

### 107.497 IVd= 

### 202.540 1.762 0.983 FVw= 

### 114.939 FVd = 

### 210.605 TVw= 

### 7.442 TVd 

### 8.065 

## tw = 

### 58 ltd = 

### 96 Ftd= 

### 96 Avg td = 

### 96

-------_.------------ 

### delta H = 

### 4.0 in. H2O 

### Pb = 

### 30.10 in. Hg 

### Time = 

### 7 min.
Std Test Meter Data 

### Dry Test Meter Data 

### AH@i "Yi
IVw= 

### 113.939 IVd = 

### 210.605 1.772 0.981 FVw= 

### 121 423 FVd = 

### 218.744 TVw= 

### 7.484 TVd 

### 8.139 tw

# = 58 ltd = 

### 98 Ftd= 

### 98 Avg. td = 

### 98 

## -------_.------------ Avg.AH@= 

## 1.70 Avg. Y = 

## 0.98

Signature:

# /t:~f, t2..c-L Date: 

# ;;2-/(,"-'
Pg.2or2

## AirNova, Inc. Calibration data and calculations Meter BoxTemperature Sensors

Meter Box

### #: Date: Calibrator: Ambient Temp. (F): Barometric Pressure ("Hg):

Reference Thermometer:


### Dry Gas Meter Thermocouple

Reference Point Ref. Thermometer 

### Temp (F)
AmbientTemp. 

## 57 Hot Water (104-122F) 

### N/A

note: tolerance for inlet and outlet 

### = +/- 

### 5.4 F 

### Thermocouple connector/LEO readout:

Ref. Thermometer Temp. (F)


### 1 Stack 

## 57 2 Probe 

## 57 3 Filter 

## 57 4 Dryer 

## 57 SAux 

## 57 6Aux 

## 57

note: tolerance 

### = +/- 

### 2 F 

### 6 '2/2/10



### KA 

## 57 29.93 ASTM-2F

Thermocouple

Temp, (F) 

## 57 N/A

ThermocouQle



### Temp. IF) 

## 58 56 56 58 58 58 Diff.


### 0 0

Diff,



### 1 1 1 1 1 1



## Signature:

# I~;t(c dd Date: 

# z6;(<>

## AirNova, Inc. 

## Dry gas meter & 

## orifice Calibration data and calculations
Meter Box#: 

### 7 Checked with Pump 

### #: 7 "213110



## KA Date: 

### Calibrator:

delta H = 

### 0.5 

### in. H2O 

### Pb = 30.00 

### in. Hg 

### Time = 20.0 

### min.
Std Test Meter Data 

### Dry Test Meter Data


### IVw= 296.863 IVd = 701.463 FVw= 304.737 FVd = 709.271 TVw= 7.874 TVd 7.808 

### tw

# = 54 ltd = 55 Ftd= 57 Avg. td = 56


## ---------------.----- delta H = 1.0 

### in. H2O 

### Pb = 30.00 

### in. Hg Time = 16.0 

### mIn. Std Test Meter Data Dry Test Meter Data
IVw= 288.065 IVd = 692.766 FVw= 296.863 FVd = 701.463 TVw= 8.798 TVd 8.697 

### tw= 54 ltd = 53 Ftd= 57 Avg. td = 55



## --------------------- delta H = 1.5 

### In. H2O 

### Pb = 30.00 

### in. Hg Time = 13.0 

### min.
Std Test Meter Data 

### Dry Test Meter Data


### IVw= 279.360 IVd = 684.221 FVw= 288.065 FVd = 692.766 TVw= 8.705 TVd 8.545 

## tw = 

### 54 ltd = 51 Ftd= 57 Avg. td = 54 "H@j 

## "Yi
1.745 1.011

I\H@i "Yi


### 1.793 1.011

"H@j 

### "Vi
1.817 1.015

P9· 1or2

### Date: '2/3110



### delta H = Pb

# = Time 

### = 

### 2.0 in. 

### H20 3000 In. 

### Hg

100 min.
Std Test Meter Data
IVw= FVw= TVw= tw=

delta H = 

### Pb 

## = Time 

## = 271.591 279.360 7.769 53

3.0 in. 

### H20 30.00 in. 

### Hg 9.0 

### min.
Std Test Meter Data


### IVw= FVw= TVw= tw=

delta H 

### = Pb 

### = Time

# = 263058 271.591 8.533 52

4.0 in. 

### H20 30.00 in. 

### Hg

10.0 

### min.
Std Test Meter Data


### IVw= FVw= TVw= 

## tw

# = 252.163 263.058

10.895 52 

## AirNova, Inc. 

## Calibration Data

Dry Test Meter Data
IVd = FVd= TVd ltd = Ftd= Avg. 

### td = 

### 676.579 684.221 7.642 48 57 52.5

Dry Test Meter Data


### IVd= 

### 668186 FVd = 

### 676.579 TVd 

### 8.393 ltd = 

### 46 Ftd= 

### 55 Avg. 

### td = 

### 50.5

Dry Test Meter Data


### IVd 

## = FVd = TVd ltd = Ftd= Avg. 

### td = 

### 657.532 668.168

10.636 45 52 48.5


## 1.80 MB#: 

### 7

AH@i


### 1.798 1.011

"H@i


### 1.811 1.006

"H@i


### 1.836 1.007



## Avg. 

## y= 1.01

Pg.2of2

## AirNova. Inc. Calibration data and calculations Meter BoxTemperature Sensors

Meter Box#. Date: Calibrator: AmbientTemp. (F): Barometnc Pressure ("Hg),

Reference Thermometer:



### Dry Gas Meter Thermocouple 

### -INLET

Reference Pomt Ref Thermometer 

### Temo. (El

Ambient Temp. 

### 50 Hot Water (104-122F) 

### 110 

### Dry Gas 

### MeterThermocouple· OUTLET

Reference Point R!;l:f. Ihermometer Temp. (F)

Ambient Temp. 

### 50 HotWater (104-122F) 

### 112

note: tolerance for inlet and outlet 

### = +/- 5.4 F 

### Thermocouple connector/LED readout:

Ref. Thermometer Temp. (F)


### 1 Stack 50 2 Probe 50 3 Filter 50 4 Dryer 

### 50 

### 5Aux 50
note: tolerance = +/- 

### 2 F 

## 7 '2/3/10 KA 

### 50 30.00 ASTM·2F

Thermocougle

Temp, (F)


### 48 112

Thermocouple

Temp. (F)


### 47 111

ThermoQQugle

Temp, (F)


### 50 50 50 50 50 Diff.


### 2 2

Diff.


### 3 1

Diff.


# a a a a a

Signature: 

# /L....d t, 

# c:2...LL.. Date: 

# 2/3!/U

## AirNova, Inc. 

## Dry gas meter & 

## orifice Calibration data and calculations
Meter Box #: 

### 8 Checked with Pump #: 

### 8 '213110 

### KA Date: Calibrator:

delta H = 0.5 in. H2O Pb = 30.00 in. Hg 

### Time = 18.0 min.
Std Test Meter Data 

### Dry Test Meter Data
IVw= 418.178 IVd = 348.247 FVw= 425.584 FVd = 356.016 TVw= 7.406 TVd 7.769 

### tw= 61 ltd = 77 Ftd= 63 Avg. td = 70

--------------------- 

### delta H = 10 in. H2O Pb = 30.00 in Hg 

### Time = 13.0 

### min.
Std Test Meter Data Dry Test Meter Data


### IVw= 410.371 IVd = 340.124 FVw= 418.178 FVd = 348.247 TVw= 7.807 TVd 8.123 

## tw = 

### 60 ltd = 69 Ftd= 61 Avg. td = 65



## --------------------- delta H = 1.5 in. H2O Pb = 30.00 

### in. Hg 

### TIme = 11.0 min.
Std Test Meter Data 

### Dry Test Meter Data


### IVw= 402.330 IVd = 331 784 FVw= 410.371 FVd = 340.124 TVw= 

### 8.041 TVd 8.340 

### tw= 59 ltd = 66 Ftd= 60 Avg. td = 63 

### flH@i "Yi
1598 0.969

"H@i 

### flYi
1509 0968

IIH@i 

### "Yi
1.528 0.968

Pg.1 of2

### Date: 

### '2/3/10

delta H = Pb = Time 

### = 

### 2.0 in. H20 30.00 in. Hg 10 

### min.
Std Test Meter Data
IVw= 

### FVw= TVw= tw=

delta 

### H = Pb = Time 

### = 

### 394.085 402.330 8.245 59

30 in H20 30.00 in. Hg

15.0 

### min.
Std Test Meter Data


### IVw= 

### 378.935 FVw= 394.085 

### TVw= 

### 15.150 

## tw = 

### 58

--------------------- 

### delta 

### H= 

### 4.0 in. H2O 

### Pb = 

### 30.00 in. Hg Time 

### = 

### 7.0 min.
Std Test Meter Data
IVw= FVw= TVw= tw=

Signature: 

### 370.716 378.935 8.219 58



## Avg.AH@= AirNova, Inc, Calibration Data

Dry Test Meter Data
IVd = 

### 323.289 FVd = 

### 331.784 TVd 

### 8.495 ltd = 

### 67 Ftd= 

### 60 Avg. td = 

### 63.5

Dry Test Meter Data
IVd= 

### 307.779 FVd = 

### 323.289 TVd 

### 15.510 ltd = 

### 61 Ftd= 

### 53 Avg. td = 

### 57

Dry Test Meter Data


### IVd = FVd

# = TVd ltd = Ftd= 

### Avg. td = 

### 299.449 307.799 8.350 55 50 52.5 

## 1.58 MB#: 

### 8

AH@i 

### IIYi


### 1.600 0.974

"H@i "Yi


### 1.613 0968

"H@i "Yi


### 1.605 0.964



## Avg. y= 0.97

Pg.2of2

## AlrNova, Inc. Calibration data and calculations Meter BoxTemperature Sensors

Meter Box #: Date: Calibrator: 

### AmbientTemp. (F): Barometric Pressure ("Hg):

Reference Thermometer:



### Dry Gas MeterThermocouple 

## -INLET

Reference Point Ref. Thermometer Temp. (F)

AmbientTemp. 

### 52 Hoi Water (104-122F) 

### 110 Dry Gas MeterThermocouple**~** 

### OUTLET

Reference Point 

### Ref. Thermometer Temp. (F)

Ambient Temp. 

### 52 Hot Water (104-122F) 

### 107
note: tolerance for inlet and outret = +/- 

### 5.4 F Thermocouple connector/LED readout:

Ref. Thermometer Temp, (F)


### 1 Stack 52 2 Probe 52 3 Filter 52 4 Dryer 52 

### 5Aux 52
note: tolerance

# = +/- 

### 2 F 

### 8 '2/3/10 

### KA 52 30.00 ASTM-2F

Thermocougle



### Temp. (F)


### 49 112

ThermOcou(;!l§

Temp. (F)


### 50 108

Thfl;rmOCQu!;!;le



### Temlhill
52 52 53 52 52 Diff.


### 3 2

Diff.


### 2 1

Diff,


### 0 0 1 0 0

# Signature:._,If.~----"~"""'~~t.:~.t:2U---~~,,----_ Date: 

# 2/-:5/0

## AirNova, Inc. 

## Dry gas meter& orifice Calibration data and calculations
Meter Box #: 

### 9 Checked with Pump #: 9 '2/3/10



### KA Date: 

### Calibrator:

delta H = 0.5 in. H2O Pb = 30.00 

### in. Hg 

### Time = 21.0 

### min.
Std Test Meter Data 

### Dry Test Meter Data
IVw= 360.452 IVd = 547.683 FVw= 369.081 FVd = 556.280 

### TVw= 8.629 TVd 8.597 

### two 61 ltd = 70 Ftd= 70 Avg. td = 70



## --------------------- delta H = 

### 1.0 in. H2O Pb = 30.00 in. Hg Time = 18.0 

### min.
Std Test Meter Data Dry Test Meter Data


### IVw= 349.756 IVd = 537.096 FVw= 360.452 FVd = 547.638 

### TVw= 10.696 TVd 10.542 

### two 59 ltd = 70 Ftd= 70 Avg. td = 70



## --------------------- delta H = 1.5 in. H2O Pb = 30.00 

### in. Hg 

### Time = 13.0 

### min.


### Std Test Meter Data 

### Dry Test Meter Data
lVw= 340.360 IVd= 527.820 FVw= 349.756 FVd = 537.096 TVw= 9.396 TVd 9.276 

### tw

# = 57 ltd = 68 Ftd= 68 Avg. td = 68 

### AH@i 

### "Yi
1.603 1.020



### "H@i AYi

1.521 1.034



### "H@i 

### "Yi
1.536 1.031

Pg. 1 of2

### Date: 

### '2/3/10

delta H = Pb = 

### Time 

## = 2.0 in, H20 30.00 in. Hg



### 100 

### min
Std Test Meter Data
IVw= 

### FVw= TVw= 

## two

delta H = 

### Pb 

## = Time = 332.219 340,360 8.141 56

3.0 

### in. H20 30.00 in, Hg 

### 90 min
Std Test Meter Data


### IVw= FVw= TVw= 

## tw =



### delta H = Pb 

## = Time = 323,371 332,219 8,848 54

4,0 in. H20 30,00 in, Hg 9.0 

### min
Std Test Meter Data


### IVw= 312.833 FVw= 

### 323,371 TVw= 10.538 

## tw = 

### 53

--------------------- 

## Avg.AH@= AirNova, 

## Inc, Calibration Data

Dry Test Meter Data
IVd= 519.800 FVd= 527.820 TVd 8,020 ltd = 67 Ftd= 67 Avg, td = 67



### Dry Test Meter Data
IVd = 511.176 FVd = 519.800 TVd 8,624 ltd = 64 Ftd= 64 Avg, td = 64



### Dry Test Meter Data
IVd = 500.912 FVd = 511.176 TVd 10.264 ltd = 58 Ftd= 58 Avg, td = 58 

## 1.58

Signature:

# £~[';aJ.L , 

### MB#' 

### 9

"H@i 

### IIYi
1.611 1.032

"H@j 

### "Yi
1.654 1.038

"H@i 

### "'Yi
1,566 1,027



## Avg. Y = 1.03

Date: 

# *!/d Pg.2of2

## AirNova, Inc. Calibration data and calculations Meter Box Temperature Sensors

Meter Box#: 

### Date: Calibrator: Ambient Temp. (F): Barometric Pressure ("Hg):

Reference Thermometer



### Dry Gas Meter Thermocouple -INLET

Reference Point R!l!f. Thermometer Temp. (F)

Ambient Temp. 

## 52 Hot Water (104-122F) 

### 110 

### Dry Gas Meter Thermocouple - 

### OUTLET

Reference Point

Ambient Temp, Hot Water (104-122F) Ref.**Thermome!~r** Temp_ (F) 

### N/A N/A

note: tolerance for inlet and outlet 

### = +/- 5 4 F 

### Thermocouple connector/LED readout:
Ref, Thermometer Temp. (Fl


### 1Stack 

## 52 2 Probe 

## 52 3 Filter 

## 52 4 Dryer 52 5 Aux 52

note: tolerance 

### = +/- 

### 2 F 

### 9 '2/3/10 

### KA 

## 52 3000 ASTM-2F

Thermocougle



### Temp. (Fl 

## 54 109

ThflrmQ!;;Q!.!!lI!l!

Temp (Fl 

### N/A N/A

Thermocougle

Temp. (F) 

## 52 52 52 52 52 Diff. 

## 2 1

Diff.


### 0 0

Diff


### 0 0 0 0 0

## AirNova, Inc. 

## Dry gas meter 

## &orifice Calibration data and calculations
Meter Box#: Checked with Pump #. 

### Date: Calibrator: 

### 10 10 '2/2/10



### KA

delta H = 0.5 in. H2O Pb= 30.05 

### in. Hg 

### Time = 19.0 

### min.
Std Test Meter Data 

### Dry Test Meter Data
IVw= 

### 228.386 IVd = 582.395 FVw= 235.845 FVd = 589.975 TVw= 7.459 TVd 7.580 

### tw = 61 ltd = 66 Ftd= 66 Avg. td = 66

--------------------- 

### delta H = 1.0 in. H2O Pb = 3005 in. Hg 

### Time 

## = 14.0 

### min.
Std Test Meter Data 

### Dry Test Meter Data
IVw= 220.786 IVd = 574.700 FVw= 228.386 FVd = 582.395 TVw= 7.600 TVd 7695 

### two 61 ltd = 66 Ftd= 66 Avg. td = 66



## --------------------- delta H = 1.5 in. H2O Pb = 30.05 

### in. Hg Time

# = 11.0 

### min.
Std Test Meter Data 

### Dry Test Meter Data
IVw= 

### 213.258 IVd = 567.100 FVw= 220.786 FVd = 574.700 TVw= 

### 7.528 TVd 7.600 

## tw = 

### 61 ltd = 66 Ftd= 66 Avg. td = 66 "H@i 

### "Yi
1.766 0.992

"H@i 

### "Yi
1.847 0.995

AH@i 

### "Yi
1.743 0.996

P9.1 of2

### Date: 

### '2/2/10

delta H 

### = Pb 

## = Time 

### = 2,0 in, H20 30,05 in. Hg



### 11.0 min,
Std Test Meter Data


### IVw= FVw= TVw= tw=

delta H = 

### Pb = Time= 

### 204.824 213.258 8434 61

3.0 In. 

### H20 30,05 in, Hg

10.0 min.
Std Test Meter Data


### IVw= FVw= Ww= 

## tw=

delta H 

### = Pb = Time 

### = 195,491 204.824 9.333 61

4,0 in. H20 30.05 in. Hg

10.0 

### min.
Std Test Meter Data


### IVw= 

### 184,630 FVw= 195,491 TVw= 10.861 tw= 61

Signature: 

## AirNova, Inc. Calibration Data

Dry Test Meter Data


### IVd = 558,576 FVd = 567,100 TVd 8.524 ltd = 66 Ftd= 66 Avg. td = 66



### Dry Test Meter Data
IVd= 549.210 FVd = 558,576 TVd 9,366 ltd = 65 Ftd= 65 Avg, td = 65



### Dry Test Meter Data
IVd = 538.324 FVd = 549.210 TVd 10,886 ltd = 63 Ftd= 63 Avg. td = 63 

## 1.82 MB#: 

### 10

"H@i


### 1.852 0.994

"H@i 

### 1,878 0.997



### AH@i 1,857 0,992



## Avg. Y

# = 0.99

Date: 

### .1.

# 4/; <J Pg.2of2

## AirNova, Inc. Calibration data and calculations Meter BoxTemperature Sensors

Meter Box#, Date: Calibrator: AmbientTemp. (E): Barometric Pressure (nHg):



### Reference Thermometer:



### Dry Gas MeterThermocouple

- INLET

Reference Point Be! Thermometer Temp. (F)


### AmbIent Temp. 

## 73 Hot Water (104-122F) 

### 101 Dry 

### Gas MeterThermocouple· OUTLET
Beference Point B!iil Thermometer 

### Temp. (Fl

AmbientTemp 

### N/A HoiWater (104-122F) 

### N/A

note: tolerance for Inlet and outlet 

### = +/- 5.4 F 

### Thermocouple connector/LED readout:
Ber Thermometer 

### Temo. (Fl


### 1 Stack 

## 73 2 Probe 

## 73 3 Filter 

## 73 4 Dryer 73 5 Aux 

## 73

note: tolerance 

### = 

### +1- 2 F



## Signature:

# /~C. 

# {lLt10 

### '2/2/10 

## KA 

## 73 30.05 ASTM-2F

TberrnocouQle

Temp. (Fl


### 72 101

Ibe[mo!;;Q!.!QJe

Temp. (E)


### N/A N/A

IberQlocQupJe

Temp. (F) 

## 74 73 73 73 73 Dltt.


### 1 0

Qifl



### 0 0

Diff.



### 1 0 0 0 0