SAMPLE SUMMARY 

HOD2704.79 

SAMPLED SAMP 

NO # SAMPLE'" CLIENT SAMPLE ID DATE TIME 

LOKON 001 MOO31 UNIT 2 RUN 1 SET 1 TENAX 04/23/10 

LOKIC 002 MOO3l UNIT 2 RUN 1 SET 1 TEN/CHAR 04/23/10 

LOKID 003 MOO3! UNIT 2 RUN 1 SET 2 TENAX 04/23/10 

LOKIF 00. MOO31 UNIT 2 RUN 1 SET 2 TEN/CHAR 04/23/10 

LOKIJ 005 MOO31 UNIT 2 RUN 1 SET 3 TENAX 04/23/10 

LOKIP 006 MOO3! UNIT 2 RUN 1 SET 3 TEN/CHAR 04/23/10 

LOKIO 009 MOO31 UNIT 2 RUN 1 CONO 04/23/10 

LOKll 010 MOO3! UNIT 2 RUN 2 SET 1 TENAX 04/23/10 

LOK13 011 MOO3! UNIT 2 RUN 2 SET 1 TEN/CHAR 04/23(10 

LOK16 012 MOO31 UNIT 2 RUN 2 SET 2 TENAX 04/23/10 

LOK19 013 MOO31 UNIT 2 RUN 2 SET 2 TEN/CHAR 04/23/10 

LOK2C 014 MOO31 UNIT 2 RUN 2 SET 3 TENAX 04/23/10 

LOK2E 015 MOO3! UNIT 2 RUN 2 SET 3 TEN/CHAR 04/23/10 

LOK2J 018 MOO3! UNIT 2 RUN 2 COND 04/23/10 

LOK2M 019 MOO31 UNIT 2 RUN 3 SET 1 TENAX 04/23/10 

LOK2T 020 MOO31 UNIT 2 RUN 3 SET 1 TEN/CHAR 04/23/10 

LOK2V 021 MOO3! UNIT 2 RUN 3 SET 2 TBNAX 04/23/10 

LOK2W 022 MOO31 UNIT 2 RUN 3 SET 2 TEN/CHAR 04/23/10 

LOK20 023 MOO31 UNIT 2 RUN 3 SET 3 TENAX 04/23/10 

LOK21 024 MOO31 UNIT 2 RUN 3 SET 3 TEN/CHAR 04/23/10 

LOK22 025 MOO31 UNIT 2 RUN 3 SET 4 TENAX 04/23/10 

LOK24 026 M0031 UNIT 2 RUN 3 SET • TEN/CHAR 04/23/10 

LOK25 027 M0031 UNIT 2 RUN 3 COND 04/23/10 

LOK28 028 M0031 UNIT 2 RUN FB TENAX 04/23/10 

LOK29 029 M0031 UNIT 2 RUN FB TEN/CHAR 04/23/10 

LOK3A 030 MOO31 UNIT 2 RUN FB COND 04/23/10 

NOTE (S) : 

- The analytical results of the sample! listed above are presented on the following pages. 

- All calculalions are performed before rounding tD a~oid round·off errors in calculated results. 

• Result!; noted as ·'ND·· were not dQleCled at or above the stated limit. 

· This re~orl must not be reproduced. except in full. without the written approval of the laboratory. 

• R.sults for the follOWing parameters ere never reported on a dry weight basis: color. corrosi~ity. density. fiashpoint. ignilability. layers. odor. 

paint filter test pH. porosity pressure. reaClivity. redox polenlial, specific gravity. spot lesls, solids. solubilily. lemperature. viscosity. and weight. 
AirNova, Inc. 

Client Sample 1D: M0031 UNIT 2 RUN 1 SET 1 TENAX 

Lot-Sample # ... : HOD270479-001 

Date Sampled ... : 04/23(10 

Prep Date ...... : 04(30/10 

Prep Batch # ... : 0119073 

Dilution Factor: 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4-Chlorotoluene 

1,2-Dibromo-3-chloropropane 

1,2-Dibromoethane 

Dibromomethane 

1,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Dichlorodifluoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

cis-l,2-Dichloroethene 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

1,2-Dichloropropane 

1,3-Dichloropropane 

2,2-Dichloropropane 

cis-l,3-Dichloropropene 

trans-l,3-Dichloropropene 

l,l-Dichloropropene 

GC/MS volatiles 

Work Order # ... : LOKONlAA 

Date Received .. : 04/27(10 

Analysis Date .. : 04/30/10 

Method ........• : SW846 VOST 

REPORTING 

RESULT LIMIT 

0.27 B 0.10 

0.044 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.025 

0.0085 J 0.050 

NO 0.10 

NO 0.010 

NO 0.010 

NO 0.010 

0.21 0.010 

0.0019 J 0.010 

NO 0.010 

NO 0.025 

NO 0.050 

NO 0.010 

0.019 J,B 0.050 

NO 0.010 

NO 0.010 

NO 0.050 

NO 0.025 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

(Continued on next page) 

Matrix ......... : AIR 

UNITS MOL 

U9 0.030 

u9 0.0035 

u9 0.0020 

u9 0.0028 

U9 0.0013 

U9 0.010 

U9 0.0059 

u9 0.10 

u9 0.0010 

U9 0.0010 

U9 0.0011 

u9 0.0019 

u9 0.0012 

u9 0.0010 

U9 0.0020 

u9 0.0062 

u9 0.0011 

u9 0.0025 

U9 0.0012 

U9 0.0014 

U9 0.013 

u9 0.0014 

u9 0.0021 

U9 0.0018 

U9 0.0014 

U9 0.0015 

u9 0.0024 

u9 0.0010 

u9 0.0017 

U9 0.0010 

U9 0 .0020 

u9 0 .0015 

u9 0 .0017 

u9 0 .0014 

U9 0.0010 

U9 0.0017 

U9 0.0012 

u9 0.0010 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN I SET I TENAX 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-001 Work Order # ... : LOKONlAA 

REPORTING 

PARAMETER RESULT LIMIT 

Ethylbenzene 0.0010 J 0.010 

Hexachlorobutadiene NO 0.025 

2-Hexanone NO 0.10 

Isopropylbenzene NO 0.010 

p-Isopropyltoluene NO 0.010 

Methylene chloride 0.021 J,B 0.025 

4-Methyl-2-pentanone NO 0.10 

Naphthalene NO 0.025 

n-Propylbenzene NO 0.010 

Styrene NO 0.010 

1,1,1,2-Tetrachloroethane NO 0.010 

1,1,2,2-Tetrachloroethane NO 0.025 

Tetrachloroethene 0.0028 J 0.010 

Toluene 0.0071 J 0.010 

1,2,3-Trichlorobenzene NO 0.025 

1,2,4-Trichloro- NO 0.025 

benzene 

1,1,1-Trichloroethane NO 0.025 

1,1,2-Trichloroethane NO 0.025 

Trichloroethene NO 0.010 

Trichlorofluoromethane 0.026 J 0.050 

1,2,3-Trichloropropane NO 0.025 

1,2,4-Trimethylbenzene NO 0.010 

1,3,5-Trimethylbenzene NO 0.010 

Vinyl chloride NO 0.010 

m-xylene & p-Xylene 0.0028 J 0.020 

a-xylene NO 0.010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 90 (50 123) 

1,2-Dichloroethane-d4 78 (50 128) 

Toluene-d8 91 (50 120) 

Bromofluorobenzene 76 (50 120) 

NOTE(S) : 

B Method blank contamination. The essociated method blank contains the t~rsel en"lyte at a reportable level. 

J EstimalCd relull. Result il leIS than RL. 

Matrix ......... : AIR 

UNITS MOL 

ug 0.0010 

ug 0.0025 

ug 0.0068 

ug 0.0010 

ug 0.0010 

ug 0.0022 

ug 0.10 

ug 0.010 

ug 0.0010 

ug 0.0013 

ug 0.0011 

ug 0.0029 

ug 0.0011 

ug 0.0010 

ug 0.0010 

ug 0.0016 

ug 0.0010 

ug 0.010 

ug 0.0022 

ug 0.0017 

ug 0.025 

ug 0.0015 

ug 0.0018 

ug 0.0021 

ug 0.0020 

ug 0.0010 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 1 SET 1 TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... , HOD270479-002 Work Order # ... , LOK1C1AA Matrix ......... : AIR 

Date Sampled ... : 04/23/10 Date Received .. : 04/27/10 

Prep Date ...... : 04/30/10 Analysis Date .. : 04/30/10 

Prep Batch fL .. : 0119073 

Dilution Factor: 1 Method ......... : SW846 VOST 

REPORTING 

PARAMETER RESULT LIMIT UNITS MDL 

Acetone 0.15 B 0.10 u9 0.030 

Benzene NO 0.010 u9 0.0035 

Bromobenzene NO 0.010 u9 0.0020 

Bromochloromethane NO 0.025 U9 0.0028 

Bromodichloromethane NO 0.010 u9 0.0013 

Bromoform ND 0.025 u9 0.010 

Bromomethane 0.023 J 0.050 u9 0.0059 

2-Butanone ND o. 10 u9 0.10 

n-Butylbenzene ND o. 010 U9 0.0010 

sec-Butylbenzene ND 0 .010 U9 0.0010 

tert-Butylbenzene ND 0 .010 u9 0.0011 

Carbon disulfide ND 0.010 u9 0.0019 

Carbon tetrachloride ND 0.010 u9 0.0012 

Chlorobenzene ND 0.010 U9 0.0010 

Chlorodibromomethane ND 0.025 u9 0.0020 

Chloroethane ND 0.050 u9 0.0062 

Chloroform NO 0.010 u9 0.0011 

Chloromethane 0.054 B 0.050 U9 0.0025 

2-Chlorotoluene NO 0.010 U9 0.0012 

4-Chlorotoluene ND 0 .010 u9 0.0014 

1,2-Dibromo-3-chloro- ND 0.050 u9 0.013 

propane 

1,2-Dibromoethane ND 0.025 u9 0.0014 

Dibromomethane ND 0.025 U9 0.0021 

1,2-Dichlorobenzene ND 0.010 u9 0.0018 

1,3-Dichlorobenzene ND 0.010 u9 0.0014 

1,4-Dichlorobenzene NO 0.010 u9 0.0015 

Dichlorodifluoromethane 0.0056 J 0.025 u9 0.0024 

1,1-Dichloroethane ND 0.010 u9 0.0010 

1,2-Dichloroethane NO 0.010 U9 0.0017 

cis-1,2-Dichloroethene NO 0.010 U9 0.0010 

trans-1,2-Dichloroethene ND 0.010 u9 0.0020 

1,1-Dichloroethene ND 0.010 u9 0.0015 

1,2-Dichloropropane ND 0.010 u9 0.0017 

l,3-Dichloropropane ND 0.010 U9 0.0014 

2,2-Dichloropropane NO 0.010 U9 0.0010 

cis-1,3-Dichloropropene NO 0.010 U9 0.0017 

trans-1,3-Dichloropropene ND 0.010 u9 0.0012 

1,1-Dichloropropene ND 0.010 u9 0.0010 

(Continued on next page) 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 1 SET 1 TEN/CHAR 

GC/MS volatiles 

Lot-Sample # ... : HOD270479-002 Work Order # ... : LOK1C1AA 

REPORTING 

PARAMETER RESULT LIMIT 

Ethylbenzene ND 0.010 

Hexachlorobutadiene ND 0.025 

2-Hexanone ND 0.10 

Isopropylbenzene ND 0.010 

p-Isapropyltoluene ND 0.010 

Methylene chloride 0.041 B 0.025 

4-Methyl-2-pentanone ND 0.10 

Naphthalene ND 0.025 

n-Propylbenzene ND 0.010 

Styrene ND 0.010 

1,1,1,2-Tetrachloroethane ND 0.010 

1,1,2,2-Tetrachloroethane ND 0.025 

Tetrachlaroethene 0.0018 J 0.010 

Toluene 0.0096 J 0.010 

1, 2, 3-Trichlorobenzene ND 0.025 

1,2,4-Trichloro- ND 0.025 

benzene 

l,l,l-Trichloroethane ND 0.025 

1, 1, 2-Trichloroethane ND 0.025 

Trichloroethene ND 0.010 

Trichlorofluoromethane 0.0025 J 0.050 

1,2,3-Trichloropropane ND 0.025 

1, 2, 4-Trimethylbenzene ND 0.010 

1, 3, 5-Trimethylbenzene ND 0.010 

Vinyl chloride ND 0.010 

m-Xylene & p-xylene ND o. 020 

a-Xylene ND 0.010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibramofluoromethane 90 {50 l23} 

1,2-Dichloroethane-d4 7, {50 128} 

Toluene-d8 87 (50 120) 

Bromofluorobenzene 75 (50 120) 

NOTE(S) : 

B Melhoo blank contamination The associated method blank conlain~ the IIIrget analyt. al a reportBble level. 

J ESlimaled resull. Result is le'ls than RL. 

Matrix ..... __ .. : AIR 

tmITS MDL 

ug 0.0010 

ug 0.0025 

ug 0.0068 

ug 0.0010 

ug 0.0010 

ug 0.0022 

ug 0.10 

ug 0.010 

ug 0.0010 

ug 0.0013 

ug 0.0011 

ug 0.0029 

ug 0.0011 

ug 0.0010 

ug 0.0010 

ug 0.0016 

ug 0.0010 

ug 0.010 

ug 0.0022 

ug 0.0017 

ug 0.025 

ug a .0015 

ug 0.0018 

ug 0.0021 

ug 0.0020 

ug 0.0010 
AirNova. Inc. 

Client Sample ID: M003l UNIT 2 RUN 1 SET 2 TENAX 

Lot-Sample # ... : HOD270479-003 

Date Sampled ... : 04/23/10 

Prep Date ...... : 04/30/10 

Prep Batch # ... : 0119073 

Dilution Factor: 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4-Chlorotoluene 

l,2-Dibromo-3-chloropropane 

l,2-Dibromoethane 

Dibromomethane 

l,2-Dichlorobenzene 

l,3-Dichlorobenzene 

l,4-Dichlorobenzene 

Dichlorodifluoromethane 

1,1-Dichloroethane 

l,2-Dichloroethane 

cis-1,2-Dichloroethene 

trans-1,2-Dichloroethene 

l,l-Dichloroethene 

l,2-Dichloropropane 

l,3-Dichloropropane 

2,2-Dichloropropane 

ciS-l,3-Dichloropropene 

trans-l,3-Dichloropropene 

1,1-Dichloropropene 

GC/MS Volatiles 

Work Order # ... : LOK1D1AA 

Date Received .. : 04/27/10 

Analysis Date .. : 04/30/10 

Method ......... : SW846 VOST 

REPORTING 

RESULT LIMIT 

0.69 B 0.10 

0.065 0.010 

ND 0.010 

ND 0.025 

ND 0.010 

ND 0.025 

0.0096 J 0.050 

ND 0.10 

ND 0.010 

ND 0.010 

ND 0.010 

0.19 0.010 

ND 0.010 

ND 0.010 

ND 0.025 

ND 0.050 

ND 0.010 

0.014 J,B 0.050 

ND 0.010 

ND 0.010 

ND 0.050 

ND 0.025 

ND 0.025 

ND 0.010 

ND 0.010 

ND 0.010 

ND 0.025 

ND 0.010 

ND 0.010 

ND 0.010 

ND 0.010 

ND 0.010 

ND O. 010 

ND 0.010 

ND 0.010 

ND 0.010 

ND 0.010 

ND 0.010 

(Continued on next page) 

Matrix ...•..... : AIR 

UNITS MDL 

ug 0.030 

ug 0.0035 

ug 0.0020 

ug 0.0028 

ug 0.0013 

ug 0.010 

ug 0.0059 

ug 0.10 

ug 0.0010 

ug 0.0010 

ug 0.0011 

ug 0.0019 

ug 0.0012 

ug 0.0010 

ug 0.0020 

ug 0.0062 

ug 0.0011 

ug 0.0025 

ug 0.0012 

ug 0.0014 

ug 0.013 

ug 0.00l4 

ug 0.0021 

ug 0.0018 

ug 0.0014 

ug 0.0015 

ug 0.0024 

ug 0.0010 

ug 0.0017 

ug 0.0010 

ug 0.0020 

ug 0.0015 

ug 0.0017 

ug 0.0014 

ug 0.0010 

ug 0.0017 

ug 0.0012 

ug 0.0010 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 1 SET 2 TENAX 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-003 Work Order # ... : LOKlDlAA 

REPORTING 

PARAMETER RESULT LIMIT 

Ethylbenzene ND 0.010 

Hexachlorobutadiene ND 0.025 

2-Hexanone ND 0.10 

Isopropylbenzene ND 0.010 

p-Isopropyltoluene ND 0.010 

Methylene chloride 0.10 B 0.025 

4-Methyl-2-pentanone ND 0.10 

Naphthalene ND 0.025 

n-Propylbenzene ND 0.010 

Styrene ND 0.010 

1,1,1,2-Tetrachloroethane ND 0.010 

1,1,2,2-Tetrachloroethane ND 0.025 

Tetrachloroethene ND 0.010 

Toluene 0.0050 J 0.010 

1,2,3-Trichlorobenzene ND 0.025 

1,2,4-Trichloro- ND 0.025 

benzene 

l,l,l-Trichloroethane ND 0.025 

1,1,2-Trichloroethane ND 0.025 

Trichloroethene ND 0.010 

Trichlorofluoromethane 0.012 J 0.050 

1,2,3-Trichloropropane ND 0.025 

1,2,4-Trimethylbenzene ND 0.010 

1,3,5-Trimethylbenzene ND 0.010 

vinyl chloride ND 0.010 

m-Xylene & p-Xylene ND O. 020 

o-Xylene ND 0.010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 91 (50 123) 

1,2-Dichloroethane-d4 77 (50 l2B) 

Toluene-dB 91 (50 120) 

Bromofluorobenzene 73 (50 120) 

NOTE(S) : 

B Mel~o~ blank contamination. The a,seciated method blank eontaiM the target anBlyt! at a reponabl! level. 

J Estimated result. Result is less than RL. 

Matrix ......... : AIR 

UNITS MDL 

ug 0.0010 

ug 0.0025 

ug 0.0068 

ug 0.0010 

ug 0.0010 

ug 0.0022 

ug 0.10 

ug 0.010 

ug 0.0010 

ug 0.0013 

ug 0.0011 

ug o . 002 9 

ug 0.0011 

ug 0.0010 

ug 0.0010 

ug 0.0016 

ug 0.0010 

ug 0.010 

ug 0.0022 

ug 0.0017 

ug 0.025 

ug 0.0015 

ug 0.0018 

ug 0.0021 

ug 0.0020 

ug 0.0010 
AirNova. Inc. 

Client Sample ID: M0031 UNIT 2 RUN 1 SET 2 TEN/CHAR 

Lot-Sample # ... : HOD270479-004 

Date Sampled ... : 04/23/10 

Prep Date ...... : 04/30/10 

Prep Batch # ... : 0119073 

Dilution Factor: 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromadichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4-Chlorotoluene 

1,2-Dibromo-3-chloropropane 

1,2-Dibromoethane 

Dibromomethane 

1.2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4 -Dichlorobenz.ene 

Dichlorodifluoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

cis-1,2-Dichloroethene 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

l,2-Dichloropropane 

1,3-Dichloropropane 

2,2-Dichloropropane 

cis-1,3-Dichloropropene 

trans-l,3-Dichloropropene 

1,1-Dichloropropene 

GC/MS Volatiles 

Work Order # ... : LOK1F1AA 

Date Received .. : 04/27/10 

Analysis Date .. : 04/30/10 

Method ......... : SW846 vaST 

REPORTING 

RESULT LIMIT 

0.52 B 0.10 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.025 

0.030 J 0.050 

NO 0.10 

NO 0.010 

No 0.010 

NO 0.010 

0.0052 J 0.010 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.050 

NO 0.010 

0.046 J,B 0.050 

NO 0.010 

No 0.010 

NO 0.050 

NO 0.025 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

0.0031 J 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

(Continued on next page) 

Matrix ......... : AIR 

UNITS MDJ~ 

u9 0.030 

U9 0.0035 

U9 0.0020 

U9 0.0028 

u9 0.0013 

u9 0.010 

U9 0.0059 

U9 0.10 

u9 0.0010 

u9 0.0010 

u9 0.0011 

U9 0.0019 

U9 0.0012 

U9 0.0010 

u9 0.0020 

U9 0.0062 

U9 0.0011 

U9 0.0025 

u9 0.0012 

u9 0.0014 

u9 0.013 

U9 0.0014 

U9 0.0021 

u9 0.0018 

u9 0.0014 

u9 0.0015 

U9 0.0024 

U9 0.0010 

u9 0.0017 

u9 0.0010 

u9 0.0020 

U9 0.0015 

U9 0.0017 

U9 0.0014 

u9 0.0010 

u9 0.0017 

u9 0.0012 

u9 0.0010 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 1 SET 2 TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-004 Work Order # ... : LOK1F1AA 

REPORTING 

PARAMETER RESULT LIMIT 

Ethylbenzene NO 0.010 

Hexachlorobutadiene NO 0.025 

2-Hexanone NO 0.10 

Isopropylbenzene NO 0.010 

p-Isopropyltoluene NO 0.010 

Methylene chloride 0.020 J,B 0.025 

4-Methyl-2-pentanone NO 0.10 

Naphthalene NO 0.025 

n-Propylbenzene NO 0.010 

Styrene NO 0.010 

1,1,1,2-Tetrachloroethane ND 0.010 

1,1,2,2-Tetrachloroethane ND 0.025 

Tetrachloroethene NO 0.010 

Toluene 0.0071 J 0.010 

1,2,3-Trichlorobenzene ND 0.025 

1,2,4-Trichloro- ND 0.025 

benzene 

l,l,l-Trichloroethane ND 0.025 

1,1,2-Trichloroethane ND 0.025 

Trichloroethene ND 0.010 

Trichlorofluoromethane ND 0.050 

1,2,3-Trichloropropane ND 0.025 

1,2,4-Trimethylbenzene ND 0.010 

1,3,5-Trimethylbenzene ND 0.010 

Vinyl chloride ND 0.010 

m-Xylene & p-Xylene ND 0.020 

o-Xylene ND 0.010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 97 (50 123) 

1,2-Dichloroethane-d4 81 (50 128) 

Toluene-d8 101 (50 120) 

Bromofluorobenzene 81 (50 120) 

NOTE(Sj: 

B Method blank COIllaminatlon. The asso-cialed ml!lhod blank conlains Ihe largel analyte al a rllporlable level. 

J ESlimaled result. Resuilis less than RL. 

Matrix ........ _: AIR 

UNITS MOL 

U9 0.0010 

u9 0.0025 

u9 0.0068 

u9 0.0010 

U9 0.0010 

U9 0.0022 

U9 0.10 

u9 0.010 

u9 0.0010 

u9 0.0013 

U9 0.0011 

U9 0.0029 

u9 0.0011 

u9 0.0010 

U9 0.0010 

U9 0.0016 

u9 0.0010 

u9 0.010 

U9 0.0022 

U9 0.0017 

u9 0.025 

u9 0.0015 

u9 0.0018 

U9 0.0021 

U9 0.0020 

U9 0.0010 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 1 SET 3 TENAX 

Lot-Sample # ... : HOD270479-005 

Date Sampled ... : 04/23/10 

Prep Date ...... : 04/30/10 

Prep Batch # ... : 0119073 

Dilution Factor: 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4 -Chlorotoluene 

l,2-Dibromo-3-chloropropane 

1,2-Dibromoethane 

Dibromomethane 

l,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Dichlorodifluoromethane 

l,l-Dichloroethane 

1,2-Dichloroethane 

cis-l,2-Dichloroethene 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

1,2-Dichloropropane 

1,3-Dichloropropane 

2,2-Dichloropropane 

ciS-1,3-Dichloropropene 

trans-1,)-Dichloropropene 

l,l-Dichloropropene 

CC/MS Volatiles 

Work Order # ... : LOK1JlAA 

Date Received .. : 04/27/10 

Analysis Date .. : 04/30/10 

Method ......... : SW846 vaST 

REPORTING 

RESULT LIMIT 

0.096 J,B 0.10 

0.052 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.025 

0.0090 J 0.050 

NO 0.10 

NO 0.010 

NO 0.010 

NO 0.010 

0.14 0.010 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.050 

NO 0.010 

0.0098 J,B 0.050 

NO 0.010 

NO 0.010 

NO 0.050 

NO 0.025 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

(Continued on next page) 

Matrix ......... ; AIR 

UNITS MOL 

u9 0.030 

u9 0.0035 

u9 0.0020 

U9 0.0028 

U9 0.0013 

u9 0.010 

u9 0.0059 

u9 0.10 

U9 0.0010 

U9 0.0010 

u9 0.0011 

u9 0.0019 

u9 0.0012 

U9 0.0010 

u9 0.0020 

u9 0.0062 

u9 0.0011 

u9 0.0025 

U9 0.0012 

U9 0.0014 

u9 0.013 

u9 0.0014 

u9 0.0021 

U9 0.0018 

u9 0.0014 

u9 0.0015 

u9 0.0024 

u9 0.0010 

U9 0.0017 

U9 0.0010 

u9 0.0020 

u9 0.0015 

u9 0.0017 

U9 0.0014 

U9 0.0010 

U9 0.0017 

u9 0.0012 

u9 0.0010 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 1 SET 3 TENAX 

GC/MS volatiles 

Lot-Sample # ... : HOD270479-005 Work Order #. __ : LOKIJlAA Mat.rix ......... : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Et.hylbenzene NO 0.010 u9 0.0010 

Hexachlorobut.adiene NO 0.025 u9 0.0025 

2-Hexanone NO 0.10 u9 0.0068 

Isopropylbenzene NO 0.010 U9 0.0010 

p-Isopropyltoluene NO 0.010 U9 0.0010 

Methylene chloride 0.025 B 0.025 u9 0.0022 

4-Methyl-2-pentanone NO 0.10 u9 0.10 

Naphthalene NO 0.025 u9 0.010 

n-Propylbenzene NO 0.010 U9 0.0010 

Styrene NO 0.010 U9 0.0013 

1,1,1,2-Tetrachloroethane NO 0.010 u9 0.0011 

1,1,2,2-Tetrachloroethane NO 0.025 u9 0.0029 

Tetrachloroethene NO 0.010 u9 0.0011 

Toluene 0.027 0.010 U9 0.0010 

l,2,3-Trichlorobenzene NO 0.025 U9 0.0010 

1,2,4-Trichloro- NO 0.025 u9 0.0016 

benzene 

1,1,1-Trichloroethane NO 0.025 u9 0.0010 

1,1,2-Trichloroethane NO 0.025 U9 0.010 

Trichloroethene NO 0.010 u9 0.0022 

Trichlorofluoromethane 0.019 J 0.050 u9 0.0017 

1,2,3-Trichloropropane NO 0.025 u9 0.025 

1,2,4-Trimethylbenzene NO 0.010 u9 0.0015 

l,3,S-Trimethylbenzene NO 0.010 U9 0.0018 

Vinyl chloride NO 0.010 U9 0.0021 

m-Xylene & p-Xylene NO 0.020 u9 0.0020 

a-Xylene NO 0.010 u9 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 98 (50 123) 

l,2-Dichloroethane-d4 92 (50 128) 

Toluene-d8 90 (50 120) 

Bromofluorobenzene 78 (50 120) 

NOTE(S) : , Estimated result. Result is less than RL. 

B Method blank eontaminalion. The associated metl10d blank contains the larget an. lyle at a reportable level. 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 1 SET 3 TEN/CHAR 

Lot-Sample # ... : HOD270479-006 

Date Sampled ... : 04/23/10 

Prep Date ...... ; 04/30/10 

Prep Batch # ... ; 0119073 

Dilution Factor; 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4-Chlorotoluene 

1,2-Dibromo-3-chloropropane 

1,2-Dibromoethane 

Dibromomethane 

1,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Dichlorodifluoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

cis-l,2-Dichloroethene 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

1,2-Dichloropropane 

1,3-Dichloropropane 

2,2-Dichloropropane 

cis-l,3-Dichloropropene 

trans-1,3-Dichloropropene 

1,1-Dichloropropene 

GC/MS Volatiles 

Work Order # ... : LOK1P1AA 

Date Received .. : 04/27/10 

Analysis Date .. ; 04/30/10 

Method ...... _ •. ; SW846 VOST 

REPORTING 

RESULT LIMIT 

0.088 J,B 0.10 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.025 

0.037 J 0.050 

NO 0.10 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.050 

NO 0.010 

0.036 J,B 0.050 

NO 0.010 

NO 0.010 

NO 0.050 

NO 0.025 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

0.0028 J 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

(Continued on next page) 

Matrix ......... ; AIR 

UNITS MOL 

ug 0.030 

ug 0.0035 

ug 0.0020 

ug 0.0028 

ug 0.0013 

ug 0.010 

ug 0.0059 

ug 0.10 

ug 0.0010 

ug 0.0010 

ug O. 0011 

ug 0.0019 

ug 0.0012 

ug 0.0010 

ug 0.0020 

ug 0.0062 

ug 0.0011 

ug 0.0025 

ug 0.0012 

ug O. 0014 

ug O. 013 

ug 0.0014 

ug 0.0021 

ug 0.0018 

ug 0.0014 

ug 0.0015 

ug 0.0024 

ug 0.0010 

ug 0.0017 

ug 0.0010 

ug 0.0020 

ug 0.0015 

ug 0.0017 

ug 0.0014 

ug 0.0010 

ug 0.0017 

ug 0.0012 

ug 0.0010 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 1 SET 3 TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... ; HOD270479-006 Work Order # ... : LOKIPlAA Matrix ......... ; AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Ethylbenzene NO 0.010 ug 0.0010 

Hexachlorobutadiene NO 0.025 ug 0.0025 

2-Hexanone NO 0.10 ug 0.0068 

Isopropylbenzene NO 0.010 ug 0.0010 

p-Isopropyltoluene NO 0.010 ug 0.0010 

Methylene chloride 0.0078 J,B 0.025 ug 0.0022 

4-Methyl-2-pentanone NO 0.10 ug 0.10 

Naphthalene NO 0.025 ug 0.010 

n-Propylbenzene NO 0.010 ug 0.0010 

Styrene NO 0.010 ug 0.0013 

l,l,1,2-Tetrachloroethane NO 0.010 ug 0.0011 

l,l,2,2-Tetrachloroethane ND 0.025 ug 0.0029 

Tetrachloroethene NO 0.010 ug 0.0011 

Toluene 0.0029 J 0.010 ug 0.0010 

1,2,3-Trichlorobenzene NO 0.025 ug 0.0010 

1,2,4-Trichloro- NO 0.025 ug 0.0016 

benzene 

l,l,l-Trichloroethane NO 0.025 ug 0.0010 

1,1,2-Trichloroethane NO 0.025 ug 0.010 

Trichloroethene NO 0.010 ug 0.0022 

Trichlorofluoromethane NO 0.050 ug 0.0017 

1,2,3-Trichloropropane NO 0.025 ug 0.025 

1,2,4-Trimethylbenzene NO 0.010 ug 0.0015 

1,3,5-Trimethylbenzene NO 0.010 ug 0.0018 

vinyl chloride NO 0.010 ug 0.0021 

m-Xylene & p-Xylene NO 0.020 ug 0.0020 

o-Xylene NO 0.010 ug 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 94 (50 123) 

1,2-Dichloroethane-d4 83 (50 128) 

Toluene-d8 99 (50 120) 

Bromofluorobenzene 82 (50 120) 

NOTE(S) ; 

J ESlimaled ,.,ull. Resull i~ 1",1 th.n RL. 

B Melncd blank contamination. Th. ",sociated method bl.nk conLains the tarSjetlnalyte at a '!portable level. 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 1 COND 

Lot-Sample # ... : HOD270479-009 

Date Sampled ... : 04/23/10 

Prep Date ...... : 05/01/10 

Prep Batch # ... : 0119312 

Dilution Factor: 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4-Chlorotoluene 

1,2-Dibromo-3-chloropropane 

1,2-Dibromoethane 

Dibrornomethane 

1,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Dichlorodifluorornethane 

l,l-Dichloroethane 

1,2-Dichloroethane 

cis-l,2-Dichloroethene 

trans-l,2-Dichloroethene 

l,l-Dichloroethene 

1,2-Dichloropropane 

l,3-Dichloropropane 

2,2-Dichloropropane 

cis-l,3-Dichloropropene 

trans-l,3-Dichloropropene 

1,1-Dichloropropene 

GC/MS volatiles 

Work Order # ... : LOKI0lAA 

Date Received .. : 04/27/10 

Analysis Date .. : 05/01/10 

Matrix ......... : WATER 

Method ....... _.: SW846 8260B 

REPORTING 

RESULT LIMIT UNITS MOL 

63. E ,. ug/L 2 .• 

0.088 J 1.. ug/L 0.025 

NO 1.0 ug/L 0.051 

1.7 1.. ug/L 0.097 

NO 1.0 ug/L 0.065 

NO 1.0 ug/L 0.50 

NO 2.0 ug/L 0.14 

13 5.0 ug/L 1.3 

NO 1.0 ug/L 0.038 

NO 1.0 ug/L 0.034 

NO 1.0 ug/L 0.035 

NO 1.0 ug/L 0.039 

NO 1.0 ug/L 0.054 

NO 1.0 ug/L 0.041 

NO 1.0 ug/L 0.11 

NO 2.0 ug/L 0.13 

0.23 J 1.. ug/L 0.036 

0.099 J 2.0 ug/L 0.064 

NO 1.0 ug/L 0.050 

NO 1.0 ug/L 0.050 

NO 2.0 ug/L 0.33 

NO 1.0 ug/L 0.094 

NO 1.0 ug/L 0.097 

NO 1.0 ug/L 0.035 

NO 1.0 ug/L 0.043 

NO 1.0 ug/L 0.049 

NO 2.0 ug/L 0.48 

NO 1.0 ug/L 0.034 

NO 1.0 ug/L 0.046 

NO 1.0 ug/L 0.054 

NO 1.0 ug/L 0.036 

NO 1.0 ug/L 0.066 

NO 1.0 ug/L 0.048 

NO 1.0 ug/L 0.036 

NO 1.0 ug/L 0.053 

NO 1.0 ug/L 0.059 

NO 1.0 ug/L 0.056 

NO 1.0 ug/L 0.042 

(Continued on next page) 
AirNova, Inc. 

Client Sample ID: MOO]1 UNIT 2 RUN 1 COND 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-009 Work Order # ... : LOK101AA Matrix ..•...... : WATER 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Ethylbenzene NO 1.0 ug/L 0.040 

Hexachlorobutadiene NO 2.0 ug/L 0.19 

2-Hexanone 1.8 J 5.0 ug/L 0.25 

Isopropylbenzene NO 1.0 ug/L 0.036 

p-Isopropyltoluene NO 1.0 ug/L 0.034 

Methylene chloride NO 2.0 ug/L 0.070 

4-Methyl-2-pentanone NO 5.0 ug/L 1.3 

Naphthalene NO 1.0 ug/L 0.12 

n-Propylbenzene NO 1.0 ug/L 0.017 

Styrene NO 1.0 ug/L 0.041 

1,1,1,2-Tetrachloroethane NO 1.0 ug/L 0.054 

1,1,2,2-Tetrachloroethane NO 1.0 ug/L 0.082 

Tetrachloroethene NO 1.0 ug/L 0.051 

Toluene 0.57 J 1.0 ug/L 0.04.7 

1,2,3-Trichlorobenzene NO 1.0 ug/L 0.14 

1,2,4-Trichloro- NO 1.0 ug/L 0.10 

benzene 

l,l,l-Trichloroethane NO 1.0 ug/L 0.070 

1,1,2-Trichloroethane NO 1.0 ug/L 0.079 

Trichloroethene NO 1.0 ug/L 0.054 

Trichlorofluoromethane NO 2.0 ug/L 0.038 

1,2,3-Trichloropropane NO 1.0 ug/L 0.18 

1,2,4-Trimethylbenzene NO 1.0 ug/L 0.031 

1,3,S-Trimethylbenzene NO 1.0 ug/L 0.017 

Vinyl chloride NO 2.0 ug/L 0.088 

m-Xylene & p-Xylene NO 2.0 ug/L 0.036 

o-Xylene NO 1.0 ug/L 0.046 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 97 (79 120) 

1,2-Dichloroethane-d4 96 (71 127) 

Toluene-d8 97 (80 120) 

Bromofluorobenzene 94 (69 126) 

NOTE(S) : 

E Estimated re,ult. Result concentration e.cecds the calibration range. 

J Estimated resull. Result is tess than RL. 
AirNova, Inc. 

Client Sample ID; M0031 UNIT 2 RUN 2 SET 1 TENAX 

Lot-Sample # ... ; HOD270479-010 

Date Sampled ... ; 04/23/10 

Prep Date ...... ; 04/30/10 

Prep Batch # ... ; 0119073 

Dilution Factor; 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4-Chlorotoluene 

l,2-Dihromo-3-chloropropane 

l,2-Dibromoethane 

Dibromomethane 

1,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Dichlorodifluoromethane 

l,l-Dichloroethane 

l,2-Dichloroethane 

cis-l,2-Dichloroethene 

trans-l,2-Dichloroethene 

1,1-Dichloroethene 

1,2-Dichloropropane 

1,3-Dichloropropane 

2,2-Dichloropropane 

cis-l,3-Dichloropropene 

tranS-l,3-Dichloropropene 

1,1-Dichloropropene 

GC/MS Volatiles 

work Order # ... ; LOKlllAA 

Date Received •. ; 04/27/10 

Analysis Date •. ; 04/30/10 

Method ......... ; SW846 VOST 

REPORTING 

RESULT LIMIT 

0.095 J,B 0.10 

0.093 0.010 

ND 0.010 

ND 0.025 

ND 0.010 

ND 0.025 

0.015 J 0.050 

ND 0.10 

ND 0.010 

ND 0.010 

ND 0.010 

0.25 0.010 

0.0026 J 0.010 

ND 0.010 

ND 0.025 

ND 0.050 

ND 0.010 

0.029 J,B 0.050 

ND 0.010 

ND 0.010 

ND 0.050 

ND 0.025 

ND 0.025 

ND 0.010 

ND 0.010 

ND 0.010 

ND 0.025 

ND 0.010 

ND 0.010 

ND 0.010 

ND 0.010 

ND 0.010 

ND 0.010 

0.0018 J 0.010 

ND 0.010 

ND 0.010 

ND 0.010 

ND 0.010 

(Continued on next page) 

Matrix .......•. ; AIR 

UNITS MDL 

U9 0.030 

U9 0.0035 

U9 0.0020 

u9 0.0028 

u9 0.0013 

u9 0.010 

U9 0.0059 

U9 0.10 

u9 0.0010 

u9 0.0010 

U9 0.0011 

U9 0.0019 

U9 0.0012 

u9 0.0010 

u9 0.0020 

U9 0.0062 

U9 0.0011 

u9 0.0025 

u9 0.0012 

u9 0.0014 

U9 0.013 

U9 0.0014 

u9 0.0021 

u9 0.0018 

U9 0.0014 

u9 0.0015 

U9 0.0024 

u9 0.0010 

u9 0.0017 

u9 0.0010 

u9 0.0020 

U9 0.0015 

U9 0.0017 

u9 0.0014 

u9 0.0010 

u9 0.0017 

u9 0.0012 

U9 0.0010 
AirNova, Inc. 

client Sample ID: M0031 UNIT 2 RUN 2 SET 1 TENAX 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-010 Work Order # ... : LOKlllAA Matrix .....•... : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Ethylbenzene NO 0.010 u9 0.0010 

Hexachlorobutadiene ND 0.025 u9 0.0025 

2-Hexanone NO 0.10 U9 0.0068 

Isopropylbenzene NO 0.010 U9 0.0010 

p-Isopropyltoluene NO 0.010 u9 0.0010 

Methylene chloride 0.023 J,B 0.025 u9 0.0022 

4-Methyl-2-pentanone NO 0.10 u9 0.10 

Naphthalene NO 0.025 u9 0.010 

n-Propylbenzene NO 0.010 U9 0.0010 

Styrene NO 0.010 U9 0.0013 

1, 1, l,2-Tetrachloroethane NO 0.010 u9 0.0011 

l,l,2,2-Tetrachloroethane NO 0.025 u9 0.0029 

Tetrachloroethene NO 0.010 U9 0.0011 

Toluene 0.018 0.010 U9 0.0010 

1,2,3-Trichlorobenzene NO 0.025 u9 0.0010 

1,2,4-Trichloro- NO 0.025 u9 0.0016 

benzene 

l,l,l-Trichloroethane ND 0.025 u9 0.0010 

l,l,2-Trichloroethane NO 0.025 U9 0.010 

Trichloroethene NO 0.010 u9 0.0022 

Trichlorofluoromethane 0.036 J 0.050 u9 0.0017 

1,2,3-Trichloropropane NO 0.025 u9 0.025 

1,2,4-Trirnethylbenzene NO 0.010 U9 0.0015 

1,3,5-Trirnethylbenzene NO 0.010 U9 0.0018 

Vinyl chloride NO 0.010 U9 0.0021 

m-Xylene & p-Xylene NO 0.020 u9 0.0020 

o-Xylene NO 0.010 u9 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 96 (50 123) 

1,2-Dichloroethane-d4 84 (50 128) 

Toluene-d8 91 (50 120) 

Bromofluorobenzene 78 (50 120) 

NOTE (S) : 

Estimated result. Result is less ltwn RL. 

B Method blank contamination. The associated me1hod blank contains the target analyte at a reportable level. 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 2 SET 1 TEN/CHAR 

Lot-Sample # ... : HOD270479-011 

Date Sampled ... : 04/23/10 

Prep Date ...... : 04/30/10 

Prep Batch # ... : 0119073 

Dilution Factor: 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4-Chlorotoluene 

1,2-Dibromo-3-chloropropane 

1,2-Dibromoethane 

Dibromomethane 

1,2-Dichlorobenzene 

l,3-Dichlorobenzene 

l,4-Dichlorobenzene 

Dichlorodifluoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

cis-1,2-Dichloroethene 

trans-l,2-Dichloroethene 

l,l-Dichloroethene 

l,2-Dichloropropane 

l,3-Dichloropropane 

2,2-Dichloropropane 

ciS-1,3-Dichloropropene 

trans-l,3-Dichloropropene 

1,1-Dichloropropene 

GC/MS Volatiles 

Work Order # ... : LOK131AA 

Date Received .. : 04/27/10 

Analysis Date .. ; 04/30/10 

Method ......... : SW846 VOST 

REPORTING 

RESULT LIMIT 

0.086 J," 0.10 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.025 

0.039 J 0.050 

NO 0.10 

NO 0.010 

NO 0.010 

NO 0.010 

0.011 0.010 

NO 0.010 

NO 0 010 

NO 0.025 

NO 0.050 

NO 0.010 

0.094 " 0.050 

NO 0.010 

NO 0.010 

NO 0.050 

NO 0.025 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

0.011 J 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

(Continued on next page) 

Matrix ......... : AIR 

UNITS MOL 

ug 0.030 

ug 0.0035 

ug 0 .0020 

ug 0.0028 

ug 0.0013 

ug 0.010 

ug 0.0059 

ug 0.10 

ug 0.0010 

ug 0.0010 

ug 0.0011 

ug 0.0019 

ug 0.0012 

ug 0.0010 

ug 0.0020 

ug 0.0062 

ug 0.0011 

ug 0.0025 

ug 0.0012 

ug 0.0014 

ug 0.013 

u9 0.0014 

ug 0.0021 

ug 0.0018 

ug 0.0014 

u9 0.0015 

ug 0.0024 

ug 0.0010 

ug 0.0017 

ug 0.0010 

ug 0.0020 

ug 0.0015 

ug 0 0017 

ug 0.0014 

ug 0.0010 

ug 0.0017 

ug 0.0012 

ug 0.0010 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 2 SET 1 TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-011 Work Order # ... : LOK131AA Matrix ......... : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MDL 

Ethylbenzene ND 0.010 u9 0.0010 

Hexachlorobutadiene ND 0.025 U9 0.0025 

2-Hexanone ND 0.10 U9 0.0068 

Isopropylbenzene ND 0.010 u9 0.0010 

p-Isopropyltoluene ND 0.010 u9 0 0010 

Methylene chloride 0.36 B 0.025 U9 0.0022 

4-Methyl-2-pentanone ND 0.10 U9 0.10 

Naphthalene ND 0.025 U9 0.010 

n-Propylbenzene ND 0.010 u9 0.0010 

Styrene ND 0.010 u9 0.0013 

1,1,1,2-Tetrachloroethane ND 0.010 u9 0.0011 

1,1, 2, 2-Tetrachloroethane ND 0.025 U9 0.0029 

Tetrachloroethene ND 0.010 U9 0.0011 

Toluene 0.0046 J 0.010 u9 0.0010 

1,2,3-Trichlorobenzene ND 0.025 u9 0.0010 

1,2,4-Trichloro- ND 0.025 U9 0.0016 

benzene 

l,I,I-Trichloroethane ND 0.025 U9 0.0010 

1,1,Z-Trichloroethane ND 0.025 u9 0.010 

Trichloroethene ND 0.010 U9 0.0022 

Trichlorofluoromethane 0.0071 J 0.050 u9 0.0017 

l,2,3-Trichloropropane ND 0.025 U9 0.025 

l,2,4-Trimethylbenzene ND 0.010 u9 0.0015 

1,3,5-Trimethylbenzene ND 0.010 u9 0.0018 

vinyl chloride ND 0.010 u9 0.0021 

m-xylene & p-Xylene ND 0.020 U9 0.0020 

o-xylene ND 0.010 U9 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 93 (50 123) 

1,2-Dichloroethane-d4 81 (50 128) 

Toluene-d8 93 (50 120) 

Bromofluorobenzene 82 (50 120) 

NOTE (5) : 

Estilllilted result. Resutt is leS$lhan RL. 

B Methgd blank COlIlamination. TMe associated method blank contains the target anatyle at a repgrtabl. level. 
AirNova. Inc. 

Client Sample ID: M0031 UNIT 2 RUN 2 SET 2 TENAX 

Lot-Sample # ... ; HOD270479-012 

Date Sampled ... ; 04/23(10 

Prep Date ...... : 04(30(10 

Prep Batch # ... : 0119073 

Dilution Factor: 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4-Chlorotoluene 

1,2-Dibromo-3-chloropropane 

1,2-Dibromoethane 

Dibromomethane 

l,2-Dichlorobenzene 

l,3-Dichlorobenzene 

l,4-Dichlorobenzene 

Dichlorodifluoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

cis-1,2-Dichloroethene 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

1,2-Dichloropropane 

1.3-Dichloropropane 

2,2-Dichloropropane 

cis-1,3-Dichloropropene 

trans-1,3-Dichloropropene 

1,1-Dichloropropene 

GC/MS Volatiles 

Work Order #. _.: LOK16lAA 

Date Received .. : 04/27/10 

Analysis Date .. : 04(30(10 

Method ......... : SW846 VOST 

REPORTING 

RESULT LIMIT 

0.086 J,B 0.10 

0.072 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.025 

0.016 J 0.050 

NO 0.10 

NO 0.010 

NO 0.010 

NO 0.010 

0.095 0.010 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.050 

NO 0.010 

0.053 B 0.050 

NO 0.010 

NO 0.010 

NO 0 .050 

NO O. 025 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

0.0016 J 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

(Continued on next page) 

Matrix_ ........ : AIR 

UNITS MDT" 

U9 0.030 

U9 0.0035 

U9 0.0020 

u9 0.0028 

U9 0.0013 

u9 0.010 

U9 0.0059 

u9 0.10 

u9 0.0010 

u9 0.0010 

U9 0.0011 

U9 0.0019 

u9 0.0012 

u9 0.0010 

U9 0.0020 

U9 0.0062 

U9 0.0011 

u9 0.0025 

u9 0.0012 

u9 0.0014 

U9 0.013 

U9 0.0014 

u9 0.0021 

u9 0.0018 

U9 0.0014 

U9 0.0015 

U9 0.0024 

u9 0.0010 

u9 0.0017 

u9 0.0010 

U9 0.0020 

U9 0.0015 

U9 0.0017 

u9 0.0014 

u9 0.0010 

u9 0.0017 

u9 0.0012 

U9 0.0010 
AirNova. Inc. 

Client sample ID: M0031 UNIT 2 RUN 2 SBT 2 TENAX 

GC/MS Volatiles 

Lot~Sample # ... : HOD270479-012 Work Order # ... : LOK161AA Matrix ......•.. : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MDL 

Ethylbenzene ND 0.010 u9 0.0010 

Hexachlorobutadiene ND 0.025 u9 0.0025 

2~Hexanone ND 0.10 U9 0.0068 

Isopropylbenzene ND 0.010 U9 0.0010 

p~Isopropyltoluene ND 0.010 u9 0.0010 

Methylene chloride 0.019 J,B 0.025 u9 0.0022 

4-Methyl-2-pentanone ND 0.10 u9 0.10 

Naphthalene ND 0.025 u9 a .010 

n-Propylbenzene ND 0.010 U9 0.0010 

Styrene ND 0.010 U9 0.0013 

1,1,1,2-Tetrachloroethane ND 0.010 u9 0.0011 

1,1,2,2-Tetrachloroethane ND 0.025 u9 0.0029 

Tetrachloroethene ND 0.010 U9 0.0011 

Toluene 0.0024 J 0.010 U9 0.0010 

1,2,3-Trichlorobenzene ND 0.025 u9 0.0010 

1,2,4-Trichloro- ND 0.025 u9 0.0016 

benzene 

1,1, I-Trichloroethane ND 0.025 U9 0.0010 

1,1,2-Trichloroethane ND 0.025 U9 0.010 

Trichloroethene ND 0.010 u9 0.0022 

Trichlorofluoromethane 0.018 J 0.050 u9 0.0017 

1,2,3-Trichloropropane ND 0.025 u9 0.025 

1,2,4-Trimethylbenzene ND 0.010 U9 0.0015 

1,3,5-Trimethylbenzene ND 0.010 U9 0.0018 

Vinyl chloride ND 0.010 u9 0.0021 

m-xylene & p-Xylene ND 0.020 u9 0.0020 

a-Xylene ND 0.010 u9 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibramofluaromethane 105 {50 123} 

1,2-Dichloroethane-d4 89 (50 128) 

Toluene-d8 99 {50 l20} 

Bromofluorobenzene 83 (50 120) 

NOTE (S) : , ESlimated result. Result is le~ Ihan RL. 

B Melhod blank conlamination. The associated melhod blank conlains the tar"el anD lyle at a reportable level. 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 2 SET 2 TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... , HOD270479-013 Work Order fL .. : LOK191AA Matrix ......... : AIR 

Date Sampled ... : 04/23/10 Date Received .. : 04/27/10 

Prep Date ...... : 04/30/10 Analysis Date .. : 04/30/10 

Prep Batch # ... , 0119073 

Dilution Factor: 1 Method ......... : SW846 VOST 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Acetone 0.099 J,B 0.10 U9 0.030 

Benzene NO 0.010 U9 0.0035 

Bromobenzene NO 0.010 U9 0.0020 

Bromochloromethane NO 0.025 u9 0.0028 

Bromodichloromethane NO 0.010 u9 0.0013 

Bromoform NO 0.025 u9 0.010 

Bromomethane 0.044 J 0.050 U9 0.0059 

2-Butanone NO 0.10 U9 0.10 

n-Butylbenzene NO 0.010 u9 0.0010 

sec-Butylbenzene NO 0.010 u9 0.0010 

tert-Butylbenzene NO 0.010 U9 0.0011 

Carbon disulfide 0.0030 J 0.010 U9 0.0019 

Carbon tetrachloride NO 0.010 u9 0.0012 

Chlorobenzene NO 0.010 u9 0.0010 

Chlorodibromomethane NO 0.025 u9 0.0020 

Chloroethane NO 0.050 U9 0.0062 

Chloroform NO 0.010 U9 0.0011 

Chloromethane 0.38 B 0.050 u9 0.0025 

2-Chlorotoluene NO 0.010 u9 0.0012 

4-Chlorotoluene NO 0.010 u9 0.0014 

1,2-Dibromo-3-chloro- NO 0.050 U9 0.013 

propane 

1,2-Dibromoethane NO 0.025 U9 0.0014 

Dibromomethane NO 0.025 u9 0 0021 

1,2-Dichlorobenzene NO 0.010 u9 0.0018 

1,3-Dichlorobenzene NO 0.010 U9 0.0014 

1,4-Dichlorobenzene NO 0.010 u9 0.0015 

Dichlorodifluoromethane 0.0031 J 0.025 U9 0.0024 

1,1-Dichloroethane NO 0.010 u9 0.0010 

1,2-Dichloroethane NO 0.010 u9 0.0017 

cis-1,2-Dichloroethene NO 0.010 u9 0.0010 

trans-l,2-Dichloroethene NO 0.010 u9 0.0020 

1,1-Dichloroethene NO 0.010 U9 0.0015 

1,2-Dichloropropane NO 0.010 U9 0.0017 

1,3-Dichloropropane NO 0.010 u9 0.0014 

2,2-Dichloropropane NO 0.010 u9 0.0010 

ciS-l,3-Dichloropropene NO 0.010 u9 0.0017 

trans-l,3-Dichloropropene NO 0.010 u9 0.0012 

1,1-Dichloropropene NO 0.010 U9 0.0010 

(Continued on next page) 
AirNova, Inc. 

Client sample ID: MOO]1 UNIT 2 RUN 2 SET 2 TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-013 Work Order # ... : LOK191AA Matrix ......... : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Ethylbenzene NO 0.010 ug 0.0010 

Hexachlorobutadiene NO 0.025 ug 0.0025 

2-Hexanone NO 0.10 ug 0.0068 

!sopropylbenzene NO 0.010 ug 0.0010 

p-Isopropyltoluene NO 0.010 ug 0.0010 

Methylene chloride 0.021 J,B 0.025 ug 0.0022 

4-Methyl-2-pentanone NO 0.10 ug 0.10 

Naphthalene NO 0.025 ug 0.010 

n-Propylbenzene NO 0.010 ug 0.0010 

Styrene NO 0.010 ug 0.0013 

1,1,1,2-Tetrachloroethane NO 0.010 ug 0.0011 

1,1,2,2-Tetrachloroethane NO 0.025 ug 0.0029 

Tetrachloroethene NO 0.010 ug 0.0011 

Toluene 0.011 0.010 ug 0.0010 

1,2,3-Trichlorobenzene NO 0.025 ug 0.0010 

1,2,4-Trichloro- NO 0.025 ug 0.0016 

benzene 

l,l,l-Trichloroethane NO 0.025 ug 0.0010 

1,1,2-Trichloroethane NO 0.025 ug 0.010 

Trichloroethene NO 0.010 ug 0.0022 

Trichlorofluoromethane 0.0042 J 0.050 ug 0.0017 

l,2,3-Trichloropropane No 0.025 ug 0.025 

1,2,4-Trimethylbenzene NO 0.010 ug 0.0015 

1,3,5-Trimethylbenzene NO 0.010 ug 0.0018 

vinyl chloride NO 0.010 ug 0.0021 

m-xylene &. p-Xylene NO 0.020 ug 0.0020 

o-xylene NO 0.010 ug 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 107 (50 123) 

1,2-Dichloroethane-d4 93 (50 l28) 

Toluene-d8 102 (50 120) 

Bromofluorobenzene 88 (50 120) 

NOTE (S) : 

Estimated ,.sult. Resull i. less lhan RL. 

B Method blank cDI1laminnion. The assoclaled melhod blank conlains Ih~ largel analyte at a reportable level. 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 2 SET 3 TENAX 

Lot-Sample # ... : HOD270479-014 

Date Sampled ... : 04/23/10 

Prep Date .. _ ... : 04/30/10 

Prep Batch ~' ... : 0119073 

Dilution Factor: 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4-Chlorotoluene 

1,2-Dibromo-3-chloropropane 

1,2-Dibromoethane 

Dibromomethane 

1,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Dichlorodifluoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

cis-l,2-Dichloroethene 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

1,2-Dichloropropane 

1,3-Dichloropropane 

2,2-Dichloropropane 

ciS-1,3-Dichloropropene 

trans-l,3-Dichloropropene 

1,1-Dichloropropene 

GC/MS Volatiles 

Work Order # __ .; LOK2C1AA 

Date Received .. : 04/27/10 

Analysis Date .. : 04/30/10 

Method ......... : SW846 VOST 

REPORTING 

RESULT LIMIT 

0.070 J,B 0.10 

0.068 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.025 

0.013 J 0.050 

NO 0.10 

NO 0.010 

NO 0.010 

NO 0.010 

0.13 0.010 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.050 

NO 0.010 

0.035 J,B 0.050 

NO 0.010 

NO 0.010 

NO 0.050 

NO 0.025 

ND 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

ND 0.025 

ND 0.010 

ND 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

0.0016 J 0.010 

NO 0.010 

ND 0.010 

ND 0.010 

ND 0.010 

(Continued on next page) 

Matrix ......... ; AIR 

UNITS MOL 

U9 0.030 

u9 0.0035 

u9 0.0020 

u9 0.0028 

U9 0.0013 

U9 0.010 

U9 0.0059 

u9 0.10 

u9 0.0010 

U9 0.0010 

U9 0.0011 

u9 0.0019 

u9 0.0012 

u9 0.0010 

U9 0.0020 

U9 0.0062 

U9 0.0011 

u9 0.0025 

u9 0.0012 

u9 0.0014 

U9 0.013 

u9 0.0014 

u9 0.0021 

U9 O. 0018 

U9 0.0014 

U9 0.0015 

U9 0.0024 

u9 0.0010 

u9 0.0017 

u9 0.0010 

U9 0.0020 

U9 0.0015 

u9 0.0017 

u9 0.0014 

u9 0.0010 

u9 0.0017 

U9 0.0012 

U9 0.0010 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 2 SET 3 THNAX 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-014 Work Order # ... : LOK2C1AA Matrix ......... : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Ethylbenzene NO 0.010 ug 0.0010 

Hexachlorobutadiene NO 0.025 ug 0.0025 

2-Hexanone NO 0.10 ug 0.0068 

Isopropylbenzene NO 0.010 ug 0.0010 

p-Isopropyltoluene NO 0.010 ug 0.0010 

Methylene chloride 0.012 J,B 0.025 ug 0.0022 

4-Methyl-2-pentanone NO 0.10 ug 0.10 

Naphthalene NO 0.025 ug 0.010 

n-propylbenzene NO 0.010 ug 0.0010 

Styrene NO 0.010 ug 0.0013 

1,1,1,2-Tetrachloroethane NO 0.010 ug 0.0011 

1,1, 2, 2-Tetrachloroethane NO 0.025 ug o . 002 9 

Tetrachloroethene NO 0.010 ug 0.0011 

Toluene 0.004.0 J 0.010 ug 0.0010 

1,2,3-Trichlorobenzene NO 0.025 ug 0.0010 

1,2,4-Trichloro- NO 0.025 ug 0.0016 

benzene 

1,1, I-Trichloroethane NO 0.025 ug 0.0010 

1,1,2-Trichloroethane NO 0.025 ug 0.010 

Trichloroethene NO 0.010 ug 0.0022 

Trichlorofluoromethane 0.030 J 0.050 ug 0.0017 

1,2,3-Trichloropropane NO 0.025 ug 0.025 

1,2,4-Trimethylbenzene NO 0.010 ug 0.0015 

1,3,5-Trimethylbenzene NO 0.010 ug 0.0018 

Vinyl chloride NO 0.010 ug 0.0021 

m-xylene & p-Xylene NO 0.020 ug 0.0020 

o-xylene NO 0.010 ug 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

DibromoEluoromethane 105 (50 123) 

1,2-Dichloroethane-d4 91 (50 128) 

Toluene-dB 96 (50 120) 

Bromofluorobenzene 83 (50 120) 

NOTE (S) : 

ESlimaled result. Result i~ leiS than RL 

B Method blank ~Qntamination. The a"oeioted method blank contains the target ~nalyte at a reponable level. 
AirNova. Inc. 

Client sample ID: M0031 UNIT 2 RUN 2 SET 3 TEN/CHAR 

Lot-Sample # ... : HOD270479-015 

Date Sampled ... : 04/23/10 

Prep Date ...... : 04/30/10 

Prep Batch # ... : 0119073 

Dilution Factor: 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromornethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4 -Chlorotoluene 

1,2-Dibromo-3-chloropropane 

1,2-Dibromoethane 

Dibromomethane 

1,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Dichlorodifluoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

cis-l,2-Dichloroethene 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

1,2-Dichloropropane 

1,3-Dichloropropane 

2,2-Dichloropropane 

ciS-1,3-Dichloropropene 

trans-1,3-Dichloropropene 

1,1-Dichloropropene 

GC/MS Volatiles 

Work Order # ... : LOK2ElAA 

Date Received .. : 04/27/10 

Analysis Date .. : 04/30/10 

Method ......... : SW846 VOST 

REPORTING 

RESULT LIMIT 

0.068 J,' 0.10 

0.0043 J 0.010 

NO 0.010 

No 0.025 

NO 0.010 

NO 0.025 

0.065 0.050 

NO 0.10 

NO 0.010 

NO 0.010 

NO 0.010 

0.0064 J 0.010 

NO 0.010 

No 0.010 

NO 0.025 

NO 0.050 

NO 0.010 

0.57 B 0.050 

NO 0.010 

NO 0.010 

NO 0.050 

NO 0.025 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

0.0057 J 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

(Continued on next page) 

Matrix ......... : AIR 

UNITS MOL 

U9 0.030 

U9 0.0035 

U9 0.0020 

u9 0.0028 

u9 0.0013 

u9 0.010 

U9 0.0059 

u9 0.10 

u9 0.0010 

u9 0.0010 

U9 0.0011 

U9 0.0019 

U9 0.0012 

u9 0.0010 

U9 0.0020 

U9 0.0062 

U9 0.0011 

u9 0.0025 

u9 0.0012 

u9 0 .0014 

U9 0.013 

U9 0.0014 

u9 0.0021 

u9 0.0018 

U9 0.0014 

U9 0.0015 

U9 0.0024 

u9 0.0010 

u9 0.0017 

u9 0.0010 

U9 0.0020 

U9 0.0015 

U9 0.0017 

u9 0.0014 

u9 0.0010 

u9 0.0017 

u9 0.0012 

U9 0.0010 
AirNova, Inc. 

Client sample ID: M0031 UNIT 2 RUN 2 SET 3 TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-015 Work Order # ... : LOK2ElAA Matrix ......... : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MDL 

Ethylbenzene ND 0.010 u9 0.0010 

Hexachlorobutadiene ND 0.025 u9 0.0025 

2-Hexanone ND 0.10 u9 0.0068 

Isopropylbenzene ND 0.010 U9 0.0010 

p-Isopropyltoluene ND 0.010 u9 0.0010 

Methylene chloride 0.019 J.B 0.025 u9 0.0022 

4-Methyl-2-pentanone ND 0.10 u9 0.10 

Naphthalene ND 0.025 u9 0.010 

n-Propylbenzene ND 0.010 U9 0.0010 

Styrene ND 0.010 U9 0.0013 

1,1,1,2-Tetrachloroethane ND 0.010 u9 0.0011 

l,l,2,2-Tetrachloroethane ND 0.025 u9 0.0029 

Tetrachloroethene ND 0.010 u9 0.001l 

Toluene 0.0032 J 0.010 U9 0.0010 

1,2,3-Trichlorobenzene ND 0.025 U9 0.0010 

l,2,4-Trichloro- ND 0.025 u9 0.0016 

benzene 

l,l,l-Trichloroethane ND 0.025 u9 0.0010 

1,1,2-Trichloroethane ND 0.025 U9 0.010 

Trichloroethene ND 0.010 u9 0.0022 

Trichlorofluoromethane 0.0075 J 0.050 u9 0.0017 

1,2,3-Trichloropropane ND 0.025 u9 0.025 

1,2,4-Trimethylbenzene ND 0.010 u9 0.0015 

l,3,5-Trimethylbenzene ND 0.010 U9 0.0018 

Vinyl chloride ND 0.010 U9 0.0021 

m-xylene & p-xylene ND 0.020 u9 0.0020 

o-Xylene ND 0.010 u9 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 102 (50 123) 

1,2-Dichloroethane-d4 95 (50 128) 

Toluene-d8 103 (50 120) 

Bromofluorobenzene 93 (50 120) 

NOTE (8) : 

Estimaled result. Result is less Ihan RL. 

B Method blank contamination The associated method blank contains the target !nalyte at a reporuoble I~vel. 
AirNova, Inc. 

Client Sample 10: M003l UNIT 2 RUN 2 COND 

GC/MS Volatiles 

Lot-Sample # ... , HOD270479-0l8 Work Order # ... , LOK2J1AA Matrix ......... : WATER 

Date Sampled ... : 04/23/10 Date Received .. ; 04/27/10 

Prep Date ...... : 05/01/10 Analysis Date .. : 05/01/10 

Prep Batch ft ... : 0119312 

Dilution Factor: 1 Method. ......... : SW846 8260B 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Acetone 710 E 10 ug/L 2.0 

Benzene 0.14 J 1.0 ug/L 0.025 

Bromobenzene NO 1.0 ug/L 0.051 

Bromochloromethane 1.0 1.0 ug/L 0.097 

Bromodichloromethane NO 1.0 ug/L 0.065 

Bromoform ND 1.0 ug/L 0.50 

Bromomethane NO 2.0 ug/L 0.14 

2-Butanone 17 5.0 ug/L 1.3 

n-Butylbenzene ND 1.0 ug/L 0.038 

sec-Butylbenzene ND 1.0 ug/L 0.034 

tert-Butylbenzene ND 1.0 ug/L 0.035 

Carbon disulfide ND 1 a ug/L 0.039 

Carbon tetrachloride ND 1.0 ug/L 0.054 

Chlorobenzene ND 1.0 ug/L 0.041 

Chlorodibromomethane ND 1.0 ug/L 0.11 

Chloroethane NO 2.0 ug/L 0.13 

Chloroform 0.19 J 1.0 ug/L 0.036 

Chloromethane 0.088 J 2 .• ug/L 0.064 

2-Chlorotoluene ND I.. ug/L 0.050 

4-Chlorotoluene ND I .• ug/L 0.050 

l,2-Dibromo-3-chloro- ND 2 .• ug/L 0.33 

propane 

1,2-Dibromoethane ND 1.0 ug/L 0.094 

Dibromomethane ND 1.0 ug/L 0.097 

l,2-Dichlorobenzene NO I.. ug/L 0.035 

l,3-Dichlorobenzene ND I.. ug/L 0.043 

l,4-Dichlorobenzene ND I.. ug/L 0.049 

Dichlorodifluoromethane ND 2 .• ug/L 0.48 

l,l-Dichloroethane ND 1.0 ug/L 0.034 

l,2-Dichloroethane ND 1.0 ug/L 0.046 

cis-l,2-Dichloroethene ND I.. ug/L 0.054 

trans-l,2-Dichloroethene ND 1.0 ug/L 0.036 

l,l-Dichloroethene ND 1.0 ug/L 0.066 

1,2-Dichloropropane ND 1.0 ug/L 0.048 

l,3-Dichloropropane NO 1.0 ugjr, 0.036 

2,2-Dichloropropane ND I.. ugjL 0.053 

CiS-l,3-Dichloropropene ND I.. ugjL 0.059 

trans-l,3-Dichloropropene ND I.. ug/L 0.056 

1,1-Dichloropropene ND I .• ug/L 0.042 

(Continued on next page) 
AirNova, Inc. 

Client Sample ID; M0031 UNIT 2 RUN 2 COND 

GC/MS Volatiles 

Lot-Sample # ... ; HOD270479-018 Work Order # ... ; LOK2JlAA 

REPORTING 

PARAMETER RESULT LIMIT 

Ethylbenzene NO 1.0 

Hexachlorobutadiene NO 2.0 

2-Hexanone 2.3 J 5.0 

Isopropylbenzene NO 1.0 

p-Isopropyltoluene NO 1.0 

Methylene chloride 1100 B,E,S 2.0 

4-Methyl-2-pentanone NO 5.0 

Naphthalene NO 1.0 

n-Propylbenzene NO 1.0 

Styrene NO 1.0 

l,l,1,2-Tetrachloroethane NO 1.0 

1,1,2,2-Tetrachloroethane NO 1.0 

Tetrachloroethene NO 1.0 

Toluene 0.082 J 1.0 

1,2,3-Trichlorobenzene NO 1.0 

1,2,4-Trichloro- NO 1.0 

benzene 

1,1,1-Trichloroethane ND 1.0 

1,1,2-Trichloroethane NO 1.0 

Trichloroethene NO 1.0 

Trichlorofluoromethane NO 2.0 

1,2,3-Trichloropropane NO 1.0 

1,2,4-Trimethylbenzene NO 1.0 

1,3,5-Trimethylbenzene NO 1.0 

vinyl chloride NO 2.0 

m-xylene & p-Xylene NO 2.0 

o-xylene NO 1.0 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 99 (79 120) 

1,2-Dichloroethane-d4 102 (71 127) 

Toluene-dB 9< (80 120) 

Bromofluorobenzene 93 (69 126) 

NOTE (S) ; 

E Estimated result. Result ~onccntnllion exceeds the calibration r~nge. 

J Estimated result. Result is less than RL. 

B Me1hod blank contamination. The associated method blank contains the target analyte at a reportable level. 

S Mass spectrometer 5aruralion. 

Matrix ..... __ ._: WATER 

UNITS MOL 

ug/L 0.040 

ug/L 0.19 

ug/L 0.25 

ug/L 0.036 

ug/L 0.034 

ug/L 0.070 

ug/L 1.3 

ug/L 0.12 

ug/L 0.017 

ug/L 0.04.1 

ug/L 0.054 

ug/L 0.OB2 

ug/L 0.051 

ug/L 0.047 

ug/L 0.14 

ug/L 0.10 

ug/L 0.070 

ug/L 0.079 

ug/L 0.054 

ug/L 0.038 

ug/L 0.18 

ug/L 0.031 

ug/L 0.017 

ug/L 0.08B 

ug/L 0.036 

ug/L 0.046 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 SET 1 TENAX 

Lot-Sample # ... : HOD270479-019 

Date Sampled ... : 04/23/10 

Prep Date ...... : 04/30/10 

Prep Batch # ... : 0119073 

Dilution Factor: 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4-Chlorotoluene 

l,2-Dibromo-3-chloropropane 

l,2-Dibromoethane 

Dibromomethane 

1,2-Dichlorobenzene 

l,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Dichlorodifluoromethane 

l,l-Dichloroethane 

l,2-Dichloroethane 

cis-1,2-Dichloroethene 

trans-1,2-Dichloroethene 

l,l-Dichloroethene 

l,2-Dichloropropane 

l,3-Dichloropropane 

2,2-Dichloropropane 

cis-l,3-Dichloropropene 

trans-1,3-Dichloropropene 

l,l-Dichloropropene 

GC/MS Volatiles 

Work Order # ... : LOK2M1AA 

Date Received .. : 04/27/10 

Analysis Date .. : 04/30/10 

Method ......... : SW846 VaST 

REPORTING 

RESULT LIMIT 

0.073 J,B 0.10 

0.041 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.025 

0.018 J 0.050 

NO 0.10 

NO 0.010 

NO 0.010 

NO 0.010 

0.11 0.010 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.050 

NO 0.010 

0.066 B 0.050 

NO 0.010 

NO 0.010 

NO 0.050 

NO 0.025 

NO 0 025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

(Continued on next page) 

Matrix ......... : AIR 

UNITS MOL 

u9 0.030 

U9 0.0035 

U9 0.0020 

U9 0.0028 

u9 0.0013 

u9 0.010 

u9 0.0059 

U9 0.10 

U9 0.0010 

u9 0.0010 

u9 0.0011 

u9 0.0019 

u9 0.0012 

U9 0.0010 

u9 0.0020 

u9 0.0062 

u9 0.001l 

U9 0.0025 

U9 0.0012 

u9 0.0014 

u9 0.013 

u9 0.0014 

U9 0.0021 

u9 0.0018 

u9 0.0014 

u9 0.0015 

u9 0.0024 

u9 0.0010 

U9 0.0017 

U9 0.0010 

u9 0.0020 

u9 0.0015 

u9 0.0017 

U9 0.0014 

U9 0.0010 

U9 0.0017 

U9 0.0012 

u9 0.0010 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 SET 1 TENAX 

GC/MS volatiles 

Lot-Sample ft •.. : HOD270479-0l9 Work Order # ... : LOK2MlAA Matrix ......... : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MDL 

Ethylbenzene ND 0.010 u9 0.0010 

Hexachlorobutadiene ND 0.025 u9 0.0025 

2-Hexanone ND 0.10 U9 0.0068 

Isopropylbenzene ND 0.010 U9 0.0010 

p-Isopropyltoluene ND 0.010 u9 0.0010 

Methylene chloride 0.012 J,B 0.025 u9 0.0022 

4-Methyl-2-pentanone ND 0.10 u9 0.10 

Naphthalene ND 0.025 u9 0.010 

n-Propylbenzene ND 0.010 U9 0.0010 

Styrene ND 0.010 U9 0.0013 

1,1,1,2-Tetrachloroethane ND 0.010 u9 0.0011 

1,1,2,2-Tetrachloroethane ND 0.025 u9 0.0029 

Tetrachloroethene ND 0.010 U9 0.0011 

Toluene 0.0028 J 0.010 U9 0.0010 

1,2,3-Trichlorobenzene ND 0.025 u9 0.0010 

1,2,4-Trichloro- ND 0.025 u9 0.0016 

benzene 

1,1,1-Trichloroethane ND 0.025 U9 0.0010 

1,1,2-Trichloroethane ND 0.025 U9 0.010 

Trichloroethene ND 0.010 u9 0.0022 

Trichlorofluoromethane 0.054 0.050 u9 0.0017 

1,2,3-Trichloropropane ND 0.025 u9 0.025 

1,2,4-Trimethylbenzene ND 0.010 U9 0.0015 

1,3 , S-Trimethylbenzene ND 0.010 U9 0.0018 

Vinyl chloride ND 0.010 u9 0.0021 

rn-Xylene & p-Xylene ND 0.020 u9 0.0020 

o-Xylene ND 0.010 u9 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 88 (50 123) 

1,2-Dichloroethane-d4 70 (50 128) 

Toluene-d8 96 (50 120) 

Bromofluorobenzene 86 (50 120) 

NOTE(S) : , Estimated result. Result Is less than RL. 

B Method blank contamination. The associated method blank contains the larget analyro ala reportable level. 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 SET 1 TEN/CHAR 

GC/MS volatiles 

Lot-Sample # ... , HOD270479-020 Work Order # ... , LOK2T1AA Matrix ......•.. : AIR 

Date Sampled ... : 04/23/10 Date Received .. : 04/27/10 

Prep Date ...... : 04/30/10 Analysis Date .. : 04/30/10 

Prep Batch # ... : 0119073 

Dilution Factor: 1 Method ......... : SW846 VOST 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Acetone 0.069 J,B 0.10 u9 0.030 

Benzene NO 0.010 ug 0.0035 

Bromobenzene NO 0.010 ug 0.0020 

Bromochloromethane NO 0.025 ug 0.0028 

Bromodichloromethane NO 0.010 ug 0.0013 

Bromoform NO 0.025 ug 0.010 

Bromomethane 0.051 0.050 u9 0.0059 

2-Butanone NO 0.10 ug 0.10 

n-Butylbenzene NO 0.010 ug 0.0010 

sec-Butylbenzene NO 0.010 ug 0.0010 

tert-Butylbenzene NO 0.010 ug 0.0011 

Carbon disulfide NO 0.010 u9 0.0019 

Carbon tetrachloride NO 0.010 u9 0.0012 

Chlorobenzene NO 0.010 u9 0.0010 

Chlorodibromomethane NO 0.025 U9 0.0020 

Chloroethane NO 0.050 u9 0.0062 

Chloroform NO 0.010 u9 0.0011 

Chloromethane 0.36 B 0.050 u9 0.0025 

2 -Chlorotoluene NO 0.010 U9 0.0012 

4 -Chlorotoluene NO 0.010 U9 0.0014 

1,2-Dibromo-3-chloro- NO 0.050 u9 0 .013 

propane 

1,2-Dibromoethane NO 0.025 u9 0 .0014 

Dibromomethane NO 0.025 u9 0.0021 

1,2-Dichlorobenzene NO 0.010 U9 0.0018 

1,3-Dichlorobenzene NO 0.010 u9 0.0014 

1,4-Dichlorobenzene NO 0.010 U9 0.0015 

Dichlorodifluoromethane 0.0041 J 0.025 u9 0.0024 

l,l-Dichloroethane NO 0.010 u9 0.0010 

1,2-Dichloroethane NO 0.010 u9 0.0017 

cis-1,2-Dichloroethene NO 0.010 U9 0.0010 

trans-1,2-Dichloroethene NO 0.010 U9 0.0020 

1,1-Dichloroethene NO 0.010 u9 0.0015 

1,2-Dichloropropane NO 0.010 u9 0.0017 

l,3-Dichloropropane NO 0.010 u9 0.0014 

2,2-Dichloropropane NO 0.010 U9 0.0010 

cis-1,3-Dichloropropene NO 0.010 u9 0.0017 

trans-1,3-Dichloropropene NO 0.010 U9 0.0012 

1,1-Dichloropropene NO 0.010 u9 0.0010 

(Continued on next page) 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 SET 1 TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-020 Work Order # ... : LOK2T1AA Matrix ...••...• : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MDL 

Ethylbenzene ND 0.010 ug 0.0010 

Hexachlorobutadiene ND 0.025 ug 0.0025 

2-Hexanone ND 0.10 ug 0.0068 

Isopropylbenzene ND 0.010 ug 0.0010 

p-Isopropyltoluene ND 0.010 ug 0.0010 

Methylene chloride 0.013 J,B 0.025 ug 0.0022 

4-Methyl-2-pentanone ND 0.10 ug 0.10 

Naphthalene ND 0.025 ug 0.010 

n- Propylbenzene ND 0.010 ug 0.0010 

Styrene ND 0.010 ug 0.0013 

1,1,1,2-Tetrachloroethane ND 0.010 ug 0.0011 

1,1,2,2-Tetrachloroethane NO 0.025 ug 0.0029 

Tetrachloroethene ND 0.010 ug 0.0011 

Toluene 0.0027 J 0.010 ug 0.0010 

1,2,3-Trichlorobenzene ND 0.025 ug 0.0010 

1,2,4-Trichloro- ND 0.025 ug 0.0016 

benzene 

l,l,l-Trichloroethane ND 0.025 ug 0.0010 

1,1,2-Trichloroethane ND 0.025 ug 0.010 

Trichloroethene ND 0.010 ug 0.0022 

Trichlorofluoromethane 0.0062 J 0.050 ug 0.0017 

1,2,3-Trichloropropane ND 0.025 ug 0.025 

1,2,4-Trimethylbenzene ND 0.010 ug 0.0015 

1,3,5-Trimethylbenzene ND 0.010 ug 0.0018 

vinyl chloride ND 0.010 ug 0.0021 

m-Xylene & p-Xylene NO 0.020 ug 0.0020 

o-Xylene NO 0.010 ug 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 101 (50 123) 

1,2-Dichloroethane-d4 87 (50 128) 

Toluene-d8 102 (50 120) 

Bromofluorobenzene 85 (50 120) 

NOTE (8) : 

Estimated resull. Result i~ less 1han RL. 

B Method blank contamination. TMe associated melhod blank conlains the Illrgel ~naly1e al a reportable level. 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 SET 2 TENAX 

Lot-Sample # ... : HOD270479-021 

Date Sampled ... : 04/23/10 

Prep Date ...... ; 04/30/10 

Prep Batch # ... ; 0119073 

Dilution Factor: 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4-chlorotoluene 

1,2-Dihromo-3-chloropropane 

1,2-Dihromoethane 

Dibromomethane 

1,2-Dichlorobenzene 

1,3-Dichlorobenzene 

l,4-Dichlorobenzene 

Dichlorodifluoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

cis-1,2-Dichloroethene 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

1,2-Dichloropropane 

1,3-Dichloropropane 

2,2-Dichloropropane 

cis-1,3-Dichloropropene 

trans-l,3-Dichloropropene 

1,1-Dichloropropene 

GC/MS Volatiles 

Work Order # ... : LOK2V1AA 

Date Received .. : 04/27/10 

Analysis Date .. : 04/30/10 

Method ......... : SW846 VaST 

REPORTING 

RESULT LIMIT 

0.044 J,B 0.10 

0.048 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.025 

0.021 J 0.050 

NO 0.10 

NO 0.010 

NO 0.010 

NO 0.010 

0.11 0.010 

0.0015 J 0.010 

NO 0.010 

NO 0.025 

NO 0.050 

NO 0.010 

0.088 B 0.050 

NO 0.010 

ND 0.010 

NO 0.050 

NO 0.025 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

(Continued on next page) 

Matrix ......•.. ; AIR 

UNITS MOL 

u9 0.030 

u9 0.0035 

ug 0.0020 

ug 0.0028 

U9 0.0013 

U9 0.010 

u9 0.0059 

u9 0.10 

ug 0.0010 

ug 0.0010 

ug 0.0011 

u9 0.0019 

u9 0.0012 

ug 0.0010 

U9 0.0020 

u9 0.0062 

u9 0.0011 

u9 0.0025 

U9 0.0012 

U9 0.0014 

u9 0.013 

u9 0.0014 

ug 0.0021 

ug 0.0018 

ug 0.0014 

U9 0.0015 

u9 0.0024 

u9 0.0010 

u9 0.0017 

U9 0.0010 

U9 0.0020 

u9 0.0015 

ug 0.0017 

ug 0.0014 

ug 0.0010 

ug 0.0017 

U9 0.0012 

u9 0.0010 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 SET 2 TENAX 

OC/MS Volatiles 

Lot-sample # ... : HOD270479-021 Work Order # ... : LOK2V1AA Matrix ......... : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Ethylbenzene NO 0.010 u9 0.0010 

Hexachlorobutadiene NO 0.025 U9 0.0025 

2-Hexanone NO 0.10 U9 0.0068 

Isopropylbenzene NO 0.010 u9 0.0010 

p-Isopropyltoluene NO 0.010 u9 0.0010 

Methylene chloride 0.022 J,B 0.025 U9 0.0022 

4-Methyl-2-pentanone NO 0.10 U9 0.10 

Naphthalene NO 0.025 U9 0.010 

n-Propylbenzene NO 0.010 u9 0.0010 

Styrene NO 0.010 u9 0.0013 

1,1,1,2-Tetrachloroethane NO 0.010 u9 0.0011 

1,1,2,2-Tetrachloroethane NO 0.025 U9 0.0029 

Tetrachloroethene NO 0.010 U9 0.0011 

Toluene 0.018 0.010 u9 0.0010 

1,2,3-Trichlorobenzene NO 0.025 u9 0.0010 

1,2,4-Trichloro- NO 0.025 u9 0.0016 

benzene 

l,l,l-Trichloroethane NO 0.025 U9 0.0010 

1, 1, 2-Trichloroethane NO 0.025 u9 0.010 

Trichloroethene NO 0.010 u9 0.0022 

Trichlorofluoromethane 0.070 0.050 u9 0.0017 

1,2,3-Trichloropropane NO 0.025 U9 0.025 

1,2,4-Trirnethylbenzene NO 0.010 U9 0.0015 

1,3,5-Trirnethylbenzene NO 0.010 u9 0.0018 

Vinyl chloride NO 0.010 u9 0.0021 

rn-Xylene & p-Xylene NO 0.020 u9 0.0020 

o-Xylene NO 0.010 u9 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibrornofluoromethane 104 (50 123) 

1,2-Dichloroethane-d4 93 (50 128) 

Toluene-da 97 (50 120) 

Brornofluorobenzene 01 (50 120) 

NOTE{S): 

Estimated resull. Result is less than RL. 

B Method blank cont~mination. The associated method blank contains \he t.&rget analyte at a reportable level. 
AirNova. Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 SET 2 TEN/CHAR 

Lot-Sample # ... : HOD270479-022 

Date Sampled ... : 04/23/10 

Prep Date ...... : 04/30/10 

Prep Batch ~, ... : 0119073 

Dilution Factor: 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4-Chlorotoluene 

1,2-Dibromo-3-chloropropane 

1,2-Dibromoethane 

Dibromomethane 

l,2-Dichlorobenzene 

l,3-Dichlorobenzene 

l,4-Dichlorobenzene 

Dichlorodifluoromethane 

1,1-Dichloroethane 

1,2-Dichloroethane 

cis-1,2-Dichloroethene 

trans-l,2-Dichloroethene 

l,l-Dichloroethene 

l,2-Dichloropropane 

1,3-Dichloropropane 

2,2-Dichloropropane 

ciS-l,3-Dichloropropene 

trans-1,3-Dichloropropene 

l,l-Dichloropropene 

GC/MS Volatiles 

Work Order # ... : LOK2WlAA 

Date Received .. : 04/27/10 

Analysis Date .. : 04/30/10 

Method ......... : SW846 VaST 

REPORTING 

RESULT LIMIT 

0.11 B 0.10 

NO 0.010 

NO 0.010 

NO o. 025 

NO 0.010 

NO 0.025 

0.054 0.050 

NO 0.10 

NO 0.010 

NO 0.010 

NO 0.010 

0.0024 J 0.010 

NO 0.010 

NO 0.010 

NO 0.025 

NO 0.050 

NO 0.010 

0.49 B 0.050 

NO 0.010 

NO 0.010 

NO 0.050 

NO 0.025 

NO 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

0.0051 J 0.025 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

NO 0.010 

(Continued on next page) 

Matrix ......... : AIR 

UNITS MOL 

u9 0.030 

u9 0.0035 

u9 0.0020 

u9 0.0028 

U9 0.0013 

U9 0.010 

u9 0.0059 

u9 0.10 

U9 0.0010 

U9 0.0010 

U9 0.0011 

u9 0.0019 

u9 0.0012 

u9 0.0010 

U9 0.0020 

u9 0.0062 

u9 0.0011 

u9 0.0025 

U9 0.0012 

U9 0.0014 

U9 0.013 

u9 0.0014 

u9 0.0021 

U9 0.0018 

U9 0.0014 

U9 0.0015 

u9 0.0024 

u9 0.0010 

u9 0.0017 

U9 0.0010 

U9 0.0020 

u9 0.0015 

u9 0.0017 

u9 0.0014 

u9 0.0010 

u9 0.0017 

U9 0.0012 

u9 0.0010 
AirNova, Inc. 

Client Sample ID; M0031 UNIT 2 RUN 3 SET 2 TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... ; HOD270479-022 Work Order # ... ; LOK2WlAA 

REPORTING 

PARAMETER RESULT LIMIT 

Ethylbenzene NO 0.010 

Hexachlorobutadiene NO 0.025 

2-Hexanone NO 0.10 

Isopropylbenzene NO 0.010 

p-Isopropyltoluene NO 0.010 

Methylene chloride 0.77 B 0.025 

4-Methyl-2-pentanone NO 0.10 

Naphthalene NO 0.025 

n-Prapylbenzene NO 0.010 

Styrene NO 0.010 

1,1,1,2-Tetrachlaroethane NO 0.010 

1,1,2,2-Tetrachloroethane NO 0.025 

Tetrachloroethene NO 0.010 

Toluene 0.027 0.010 

1,2,3-Trichlorobenzene NO 0.025 

1,2,4-Trichloro- NO 0.025 

benzene 

l,l,l-Trichloroethane NO 0.025 

1,1,2-Trichloroethane NO 0.025 

Trichloroethene NO 0.010 

Trichlorofluoromethane 0.0084 J 0.050 

1,2,3-Trichloropropane NO 0.025 

1,2,4-Trimethylbenzene NO 0.010 

1,3,5-Trimethylbenzene NO 0.010 

Vinyl chloride NO 0.010 

m-Xylene & p-xylene NO 0.020 

a-Xylene NO 0.010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibramafluaramethane 103 (50 123) 

1,2-Dichloroethane-d4 99 (50 128) 

Toluene-dB 97 (50 120) 

Bromofluorobenzene 88 (50 120) 

NOTE(S) : 

B Method blank conlamination. The associated method blank cOI1!ains the large! analyte at a rcponable level. 

J ESilmaltd result. Result is less than RL. 

Matrix ......... ; AIR 

UNITS MOL 

ug 0.0010 

ug 0.0025 

ug 0.0068 

ug 0.0010 

ug 0.0010 

ug 0.0022 

ug 0.10 

ug 0.010 

ug 0.0010 

ug 0.00l3 

ug O.OOll 

ug 0.0029 

ug O.OOll 

ug 0.0010 

ug 0.0010 

ug 0.0016 

ug 0.0010 

ug 0.010 

ug 0.0022 

ug 0.0017 

ug 0.025 

ug 0.0015 

ug 0.0018 

ug 0.0021 

ug 0.0020 

ug 0.0010 
AirNova, Inc. 

Client sample ID: M003l UNIT 2 RUN 3 SET 3 TENAX 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-023 Work Order # ... , LOK201AA Matrix ......... : AIR 

Date Sampled ... : 04/23/10 Date Received .. : 04/27/10 

Prep Date ...... : 04/30/10 Analysis Date .. : 04/30/10 

Prep Batch # ... , 0119073 

Dilution Factor: 1 Method ......... : SW846 VOST 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Acetone 0.054 J.B 0.10 U9 0.030 

Benzene 0.019 0.010 U9 0.0035 

Bromobenzene NO 0.010 U9 0.0020 

Bromochloromethane NO 0.025 u9 0.0028 

Bromodichloromethane NO 0.010 U9 0.0013 

Bromoform NO 0.025 u9 0.010 

Bromomethane 0.011 J 0.050 U9 0.0059 

2-Butanone NO 0.10 u9 0.10 

n-Butylbenzene NO 0.010 u9 0.0010 

sec-Butylbenzene NO 0.010 u9 0.0010 

tert-Butylbenzene NO 0.010 U9 0.0011 

Carbon disulfide 0.13 0.010 U9 0.0019 

Carbon tetrachloride NO 0.010 U9 0.0012 

Chlorobenzene NO 0.010 u9 0.0010 

Chlorodibromomethane NO 0.025 u9 0.0020 

Chloroethane NO 0.050 U9 0.0062 

Chloroform NO 0.010 U9 0.0011 

Chloromethane 0.074 B 0.050 u9 0.0025 

2-Chlorotoluene NO 0.010 u9 0.0012 

4-Chlorotoluene NO 0.010 u9 0.0014 

l,2-Dibromo-3-chloro- NO 0.050 U9 0.013 

propane 

l,2-Dibromoethane NO 0.025 U9 0.0014 

Dibroroomethane NO 0.025 u9 0.0021 

l,Z-Dichlorobenzene NO 0.010 u9 0.0018 

l,3-Dichlorobenzene NO 0.010 U9 0.0014 

l,4-Dichlorobenzene NO 0.010 u9 0.0015 

Dichlorodifluoromethane NO 0.025 U9 0.0024 

1,1-Dichloroethane NO 0.010 u9 0.0010 

1,2-Dichloroethane NO 0.010 u9 0.0017 

cis-1,Z-Dichloroethene NO 0.010 u9 0.0010 

trans-l,2-Dichloroethene NO 0.010 u9 0.0020 

l,l-Dichloroethene NO 0.010 U9 0.0015 

l,2-Dichloropropane NO 0.010 U9 0.0017 

l,3-Dichloropropane NO 0.010 u9 0.0014 

2,2-Dichloropropane NO 0.010 u9 0.0010 

ciS-1,3-Dichloropropene NO 0.010 u9 0.0017 

trans-l,3-Dichloropropene NO 0.010 u9 0.0012 

l,l-Dichloropropene NO 0.010 U9 0.0010 

(Continued on next page) 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 SET 3 TENAX 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-023 Work Order # ... : LOK201AA Matrix ......... : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MDL 

Ethylbenzene ND 0.010 ug 0.0010 

Hexachlorobutadiene ND 0.025 ug 0.0025 

2-Hexanone ND 0.10 ug 0.0068 

Isopropylbenzene ND 0.010 ug 0.0010 

p-Isopropyltoluene ND 0.010 ug 0.0010 

Methylene chloride 0.0097 J,B 0.025 ug 0.0022 

4-Methyl-2-pentanone ND 0.10 ug 0.10 

Naphthalene ND 0.025 ug 0.010 

n-Propylbenzene ND 0.010 ug 0.0010 

Styrene ND 0.010 ug 0.0013 

l,l,l,2-Tetrachloroethane ND 0.010 ug 0.0011 

l,l,2,2-Tetrachloroethane ND 0.025 ug 0 0029 

Tetrachloroethene ND 0.010 ug 0.0011 

Toluene ND 0.010 ug 0.0010 

1,2,3-Trichlorobenzene ND 0.025 ug 0.0010 

1,2,4-Trichloro- ND 0.025 ug 0 .0016 

benzene 

1,1,1-Trichloroethane ND 0.025 ug 0 .0010 

1,1,2-Trichloroethane ND 0.025 ug 0.010 

Trichloroethene ND 0.010 ug 0.0022 

Trichlorofluoromethane 0.012 J 0.050 ug 0.0017 

1,2,3-Trichloropropane ND 0.025 ug 0.025 

1,2,4-Trimethylbenzene ND 0.010 u9 0.0015 

1,3,5-Trimethylbenzene ND 0.010 ug 0.0018 

Vinyl chloride ND 0.010 ug 0.0021 

m-xylene & p-xylene ND 0.020 ug 0.0020 

o-Xylene ND 0.010 ug 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 63 (50 123) 

1,2-Dichloroethane-d4 44 • (50 128) 

Toluene-d8 86 (50 120) 

Bromofluorobenzene 6' (50 120) 

NDTE(S): 

Surrogate recov~ry is outside ~taled controllimil5. 

E51imaled 'e~ult. Resull is less than RL. 

B Method blank contaminalion. The a~socia1ed method blank conlains the (.rge( .n"lyle.t. reportable level. 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 SET 3 TEN/CHAR 

GC/MS Volatiles 

Lot-Sample :/L •• : HOD270479-024 Work Order # ... , LOK211AA Matrix ......•.. : AIR 

Date Sampled ... : 04/23/10 Date Received .. : 04/27/10 

Prep Date ...... : 04/30/10 Analysis Date •. : 04/30/10 

Prep Batch :JI: ••• : 0119073 

Dilution Factor: 1 Method ......... : SW846 VOST 

REPORTING 

PARAMETER RESULT LIMIT UNITS MDL 

Acetone 0.098 J.B 0.10 U9 0.030 

Benzene ND 0.010 u9 0.0035 

Bromobenzene ND 0.010 u9 0.0020 

Bromochloromethane ND 0.025 u9 0.0028 

Bromodichloromethane ND 0.010 U9 0.0013 

Bromoform ND 0.025 U9 0.010 

Bromomethane 0.034 J 0.050 u9 0.0059 

2-Butanone ND 0.10 u9 0.10 

n-Butylbenzene ND 0.010 u9 0.0010 

sec-Butylbenzene ND 0.010 U9 0.0010 

tert-Butylbenzene ND 0.010 U9 0.0011 

Carbon disulfide ND 0.010 u9 0.00l9 

Carbon tetrachloride ND 0.010 u9 0.0012 

Chlorobenzene ND 0.010 u9 0.0010 

Chlorodibromomethane ND 0.025 U9 0.0020 

Chloroethane ND 0.050 U9 0.0062 

Chloroform ND 0.010 u9 0.0011 

Chloromethane 0.28 B 0.050 u9 0.0025 

2-Chlorotoluene ND 0.010 u9 0.0012 

4-Chlorotoluene ND 0.010 U9 0.0014 

1,2-Dibromo-3-chloro- ND 0.050 U9 0.013 

propane 

1,2-Dibromoethane ND 0.025 u9 0.0014 

Dibromomethane ND 0.025 u9 0.0021 

1 / 2-Dichlorobenzene ND 0.010 U9 0.0018 

1,3-Dichlorobenzene ND 0.010 U9 0.0014 

1,4-Dichlorobenzene ND 0.010 U9 0.0015 

Dichlorodifluoromethane 0.0025 J 0.025 U9 0.0024 

1,1-Dichloroethane ND 0.010 u9 0.0010 

1,2-Dichloroethane ND 0.010 u9 0.0017 

cis-1,2-Dichloroethene ND 0.010 u9 0.0010 

trans-1,2-Dichloroethene ND 0.010 U9 0.0020 

1,1-Dichloroethene ND 0.010 U9 0.0015 

1,2-Dichloropropane ND 0.010 U9 0.0017 

1,3-Dichloropropane ND 0.010 u9 0.0014 

2,2-Dichloropropane ND 0.010 u9 0.0010 

cis-l,3-Dichloropropene ND 0.010 u9 0.0017 

trans-1,3-Dichloropropene ND 0.010 u9 0.0012 

1,1-Dichloropropene ND 0.010 U9 0.0010 

(Continued on next page) 
AirNova, Inc. 

Client Sample ID: M003l UNIT 2 RUN 3 SET 3 TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-024 Work Order # ... : LOK211AA Matrix ......... : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Ethylbenzene NO 0.010 U9 0.0010 

Hexachlorobutadiene NO 0.025 u9 0.0025 

2-Hexanone NO 0.10 u9 0.0068 

Isopropylbenzene NO 0.010 U9 0.0010 

p-Isopropyltoluene NO 0.010 U9 0.0010 

Methylene chloride 0.012 J,B 0.025 u9 0.0022 

4-Methyl-2-pentanone NO 0.10 u9 0.10 

Naphthalene NO 0.025 u9 0.010 

n-Propylbenzene NO 0.010 U9 0.0010 

Styrene NO 0.010 U9 0.0013 

1,1,1,2-Tetrachloroethane NO 0.010 U9 0.0011 

1,1,2,2-Tetrachloroethane NO 0.025 u9 0.0029 

Tetrachloroethene NO 0.010 u9 0.0011 

Toluene 0.0043 J 0.010 u9 0.0010 

1,2,3-Trichlorobenzene NO 0.025 U9 0.0010 

1,2,4-Trichloro- NO 0.025 U9 0.0016 

benzene 

l,l,l-Trichloroethane NO 0.025 u9 0.0010 

1,1,2-Trichloroethane NO 0.025 U9 0.010 

Trichloroethene NO 0.010 U9 0.0022 

Trichlorofluoromethane NO 0.050 U9 0.0017 

1,2,3-Trichloropropane NO 0.025 u9 0.025 

l,2,4-Trimethylbenzene NO 0.010 u9 0.0015 

1,3,5-Trimethylbenzene NO 0.010 u9 0.0018 

Vinyl chloride NO 0.010 U9 0.0021 

m-xylene & p-xylene NO 0.020 U9 0.0020 

o-xylene NO 0.010 U9 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 102 (50 123) 

1,2-Dichloroethane-d4 87 (50 126) 

Toluene-d8 99 (50 120) 

Bromofluorobenzene 86 (50 120) 

NOTE (S) : 

Estimated reJull. Result is teJltha~ RL. 

8 Method blank contamination. The as~ciated method blank ~onlains the target analyte at a reportable lwei. 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 COND 

Lot-Sample # ... : HOD270479-027 

Date Sampled ... : 04/23/10 

Prep Date ...... : 05/01/10 

Prep Batch # ... : 0119312 

Dilution Factor: 1 

PARAMETER 

Acetone 

Benzene 

Bromobenzene 

Bromochloromethane 

Bromodichloromethane 

Bromoform 

Bromomethane 

2-Butanone 

n-Butylbenzene 

sec-Butylbenzene 

tert-Butylbenzene 

Carbon disulfide 

Carbon tetrachloride 

Chlorobenzene 

Chlorodibromomethane 

Chloroethane 

Chloroform 

Chloromethane 

2-Chlorotoluene 

4-Chlorotoluene 

1,2-Dibromo-3-chloropropane 

l,2-Dibromoethane 

Dibromomethane 

l,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

Dichlorodifluoromethane 

1,1-Dichloroethane 

1,2-Dich1oroethane 

cis-l,2-Dichloroethene 

trans-1,2-Dichloroethene 

1,1-Dichloroethene 

1,2-Dichloropropane 

1,3-Dichloropropane 

2,2-Dichloropropane 

cis-l,3-Dichloropropene 

trans-l,3-Dichloropropene 

l,l-Dichloropropene 

GC/MS Volatiles 

Work Order # ... : LOK251AA 

Date Received .. : 04/27/10 

Analysis Date .. : 05/01/10 

Matrix ..... _ ... : WATER 

Method ......... : SW846 82608 

REPORTING 

RESULT LIMIT UNITS MDL 

790 E 10 ug/L 2.0 

0.042 J 1.0 ug/L 0.025 

ND 1.0 ug/L 0.051 

0.72 J 1.0 ug/L 0.097 

ND 1.0 ug/L 0.065 

ND 1.0 ug/L 0.50 

ND 2.0 ug/L 0.14 

19 5.0 ug/L 1.3 

ND 1.0 ug/L 0.038 

ND 1.0 ug/L 0.034 

ND 1.0 ug/L 0.035 

ND 1.0 ug/L 0.039 

ND 1.0 ug/L 0.054 

ND 1.0 ug/L 0.041 

ND 1.0 ug/L 0.11 

ND 2.0 ug/L 0.13 

0.21 J 1.0 ug/L 0.036 

0.088 J 2.0 ug/L 0.064 

ND 1.0 ug/L 0.050 

ND 1.0 ug/L 0.050 

ND 2.0 ug/L 0.33 

ND 1.0 ug/L 0.094 

ND 1.0 ug/L 0.097 

ND 1.0 ug/L 0.035 

ND 1.0 ug/L 0.043 

ND 1.0 ug/L 0.049 

ND 2.0 ug/L 0.48 

ND 1.0 ug/L 0.034 

ND 1.0 ug/L 0.046 

ND 1.0 ug/L 0.054 

ND 1.0 ug/L 0.036 

ND 1.0 ug/L 0.066 

ND 1.0 ug/L 0.048 

ND 1.0 ug/L 0.036 

ND 1.0 ug/L 0.053 

ND 1.0 ug/L 0.059 

ND 1.0 ug/L 0.056 

ND 1.0 ug/L 0.042 

(Continued on next page) 
AirNova, Inc. 

Client Sample ID; M0031 UNIT 2 RUN 3 COND 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-027 Work Order # ... ; LOK251AA 

REPORTING 

PARAMETER RESULT LIMIT 

Ethylbenzene ND 1.0 

Hexachlorobutadiene ND 2.0 

2-Hexanone 2." J 5.0 

Isopropylbenzene ND 1.0 

p-Isopropyltoluene ND 1.0 

Methylene chloride 1000 B,E,S 2." 

4-Methyl-2-pentanone NO 5." 

Naphthalene NO 1.0 

n-Propylbenzene NO 1.0 

Styrene NO 1.0 

l,l,l,2-Tetrachloroethane NO 1.0 

l,l,2,2-Tetrachloroethane NO 1." 

Tetrachloroethene NO 1." 

Toluene 0.14 J 1." 

l,2,3-Trichlorobenzene NO 1.0 

l,2,4-Trichloro- NO 1." 

benzene 

l,l,l-Trichloroethane NO 1.0 

1,I,2-Trichloroethane NO 1.0 

Trichloroethene NO 1.0 

Trichlorofluoromethane NO 2.0 

l,2,3-Trichloropropane NO 1.0 

l,2,4-Trimethylbenzene NO 1.0 

l,3,S-Trimethylbenzene NO i.o 

Vinyl chloride NO 2.0 

m-Xylene & p-Xylene NO 2.0 

o-Xylene NO 1.0 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 100 (79 120) 

l,2-Dichloroethane-d4 96 (71 127) 

Toluene-d8 94 (80 120) 

Bromofluorobenzene 92 (69 126) 

NOTE (5) : , EslirTlllted result Resull concentration exceeds tne ealibratlon range. 

ESlimated re,ult. Result is less th"n RL. 

B Method blank contamination. The associated method blank contains the larget analyte at a reportable level. 

S Mass s~~trometer saturation. 

Matrix ......... ; WATER 

UNITS MDL 

ug/L 0.040 

ug/L 0.19 

ug/L 0.25 

ug/J~ 0.036 

ug/L 0.034 

ug/L 0.070 

ug/L 1.3 

ug/L 0.12 

ug/L 0.017 

ug/L 0.041 

ug/L 0.054 

ug/L " 082 

ug/L 0.051 

ug/L 0.047 

ug/L 0.14 

ug/L 0.10 

ug/L 0.070 

ug/L 0.079 

ug/L 0.054 

ug/L 0.038 

ug/L 0.18 

ug/L 0.031 

ug/L 0.017 

ug/L 0.088 

ug/L 0.036 

ug/L 0.046 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 SET 4 TENAX 

GC/MS volatiles 

Lot-Sample # ... , 1-I0D270479-025 Work Order # ... , LOK221AA Matrix ......... ; AIR 

Date Sampled ... : 04/23/10 Date Received .. : 04/27/10 

Prep Date ...... : 05/03/10 Analysis Date .. : 05/03/10 

Prep Batch # ... : 0119218 

Dilution Factor: 1 Method ......... : SW846 VOST 

REPORTING 

PARAMETER RESULT LIMIT UNITS MDL 

Acetone 0.047 J,B 0.10 u9 0.030 

Benzene 0.031 0.010 U9 0.0035 

Bromobenzene NO 0.010 U9 0.0020 

Bromochloromethane NO 0.025 u9 0.0028 

Bromodichloromethane ND 0.010 u9 0.0013 

Bromoform ND 0.025 u9 0.010 

Bromomethane 0.0093 J 0.050 u9 0.0059 

2-Butanone ND 0.10 U9 0.10 

n-Butylbenzene ND 0.010 u9 0.0010 

sec-Butylbenzene ND 0.010 u9 0.0010 

tert-Butylbenzene ND 0.010 u9 0.0011 

Carbon disulfide 0.74 0.010 U9 0.0019 

Carbon tetrachloride 0.0013 J 0.010 U9 0.0012 

Chlorobenzene ND 0.010 U9 0.0010 

Chlorodibromomethane ND 0.025 u9 0.0020 

Chloroethane ND 0.050 U9 0.0062 

Chloroform ND 0.010 u9 0.0011 

Chloromethane 0.026 J,B 0.050 U9 0.0025 

2-Chlorotoluene ND 0.010 u9 0.0012 

4-Chlorotoluene ND 0.010 u9 0.0014 

1,2-Dibromo-3-chloro- ND O. 050 u9 0.013 

propane 

1,2-Dibromoethane ND 0 .025 u9 0.0014 

Dibromomethane NO 0.025 U9 0.0021 

l,2-Dichlorobenzene ND 0.010 u9 0.0018 

l,3-Dichlorobenzene ND 0.010 u9 0.0014 

l,4-Dichlorobenzene ND 0.010 u9 0.0015 

Dichlorodifluoromethane NO 0.025 u9 0.0024 

l,l-Dichloroethane ND 0.010 U9 0.0010 

l,2-Dichloroethane ND 0.010 U9 0.0017 

cis-1,2-Dichloroethene ND 0.010 U9 0.0010 

trans-l,2-Dichloroethene ND 0.010 u9 0.0020 

l,l-Dichloroethene NO 0.010 u9 0.0015 

l,2-Dichloropropane ND 0.010 u9 0.0017 

1,3-Dichloropropane ND 0.010 U9 0.0014 

2,2-Dichloropropane ND 0.010 U9 0.0010 

cis-1,3-Dichloropropene ND 0.010 U9 0.0017 

trans-l,3-Dichloropropene ND 0.010 u9 0.0012 

l,l-Dichloropropene ND 0.010 u9 0.0010 

(Continued on next page) 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 SET 4 TENAX 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-025 Work Order # ... : LOK221AA Matrix ......... : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MDL 

Ethylbenzene ND 0.010 u9 0.0010 

Hexachlorobutadiene ND 0.025 u9 0.0025 

2-Hexanone ND 0.10 U9 0.0068 

Isopropylbenzene ND 0.010 U9 0.0010 

p-Isapropyltoluene ND 0.010 u9 0.0010 

Methylene Chloride 0.012 J,B 0.025 u9 0.0022 

4-Methyl-2-pentanone ND 0.10 u9 0.10 

Naphthalene ND 0.025 u9 0.010 

n-Propylbenzene ND 0.010 U9 0.0010 

Styrene ND 0.010 U9 0.0013 

1,1,1,2-Tetrachloroethane ND 0.010 u9 0.0011 

l,l,2,2-Tetrachloroethane ND 0.025 u9 0.0029 

Tetrachloroethene ND 0.010 U9 0.0011 

Toluene ND 0.010 U9 0.0010 

l,2,3-Trichlorobenzene ND 0.025 u9 0.0010 

l,2,4-Trichloro- ND 0.025 u9 0.0016 

benzene 

l,l,l-Trichloroethane ND 0.025 u9 0.0010 

l,l,2-Trichloroethane ND 0.025 U9 0.010 

Trichloroethene ND 0.010 u9 0.0022 

Trichlorofluoromethane 0.00a3 J 0.050 u9 0.0017 

1,2,3-Trichloroprapane ND 0.025 u9 0.025 

1,2,4-Trimethylbenzene ND 0.010 U9 0.0015 

1,3,5-Trimethylbenzene ND 0.010 U9 0.0018 

vinyl chloride ND 0.010 u9 0.0021 

m-Xylene & p-Xylene ND 0.020 u9 0.0020 

a-Xylene ND 0.010 u9 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoramethane 63 (50 123) 

1,2-Dichloroethane-d4 50 (50 128) 

Toluene-d8 79 (50 120) 

Bromofluorobenzene 52 (50 120) 

NOTE(S) : 

E~(imated result. Result Is less lh~n RL. 

B Method blank contamlnalion. The associated method blank contain. the largel anD lyle ill. reportable level. 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 SET 4 TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... , HOD270479-026 Work Order # ... , LOK241AA Matrix ......... : AIR 

Date Sampled ... : 04/23/10 Date Received. _: 04/27/10 

Prep Date ...... : 05/03/10 Analysis Date .. : 05/03/10 

Prep Batch :It ••• : 0119218 

Dilution Factor: 1 Method ......... : SW846 vaST 

REPORTING 

PARAMETER RESULT LIMIT UNITS MDL 

Acetone 0.10 B 0.10 u9 0.030 

Benzene ND 0.010 u9 0.0035 

Bromobenzene ND 0.010 u9 0.0020 

Bromochloromethane ND 0.025 U9 0.0028 

Bromodichloromethane ND 0.010 U9 0.0013 

Bromoform ND 0.025 U9 0.010 

Bromomethane 0.0088 J 0.050 u9 0.0059 

2-Butanone ND 0.10 u9 0.10 

n-Butylbenzene ND 0.010 U9 0.0010 

sec-Butylbenzene ND 0.010 U9 0.0010 

tert-Butylbenzene ND 0.010 u9 0.0011 

Carbon disulfide 0.0071 J 0.010 u9 0.0019 

Carbon tetrachloride ND 0.010 u9 0.0012 

Chlorobenzene ND 0.010 U9 0.0010 

Chlorodibromomethane ND 0.025 u9 0.0020 

Chloroethane ND 0.050 u9 0.0062 

Chloroform ND 0.010 u9 0.0011 

Chloromethane 0.029 J,B 0.050 u9 0.0025 

2-Chlorotoluene ND 0.010 U9 0.0012 

4-Chlorotoluene ND 0.010 U9 0.0014 

1,2-Dibromo-3-chloro- ND 0.050 u9 0.013 

propane 

1,2-Dibromoethane ND 0.025 u9 0.0014 

Dibromomethane ND 0.025 u9 0.0021 

1,2-Dichlorobenzene ND 0.010 U9 0.0018 

1,3-Dichlorobenzene ND 0.010 U9 0.0014 

1,4-Dichlorobenzene ND 0.010 U9 0.0015 

Dichlorodifluoromethane ND 0.025 u9 0.0024 

1,1-Dichloroethane ND 0.010 u9 0.0010 

1,2-Dichloroethane ND 0.010 u9 0.0017 

cis-1,2-Dichloroethene ND 0.010 U9 0.0010 

trans-l,2-Dichloroethene ND 0.010 U9 0.0020 

l,l-Dichloroethene ND 0.010 u9 0.0015 

1,2-Dichloropropane ND 0.010 u9 0.0017 

1,3-Dichloropropane ND O. 010 u9 0.0014 

2,2-Dichloropropane ND 0.010 U9 0.0010 

cis-1,3-Dichloropropene ND 0.010 u9 0.0017 

trans-1,3-Dichloropropene ND 0.010 U9 0.0012 

l,l-Dichloropropene ND 0.010 u9 0.0010 

(Continued on next page) 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN 3 SET 4 TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-026 Work Order # ... : LOK241AA 

REPORTING 

PARAMETER RESULT LIMIT 

Ethylbenzene ND 0.010 

Hexachlorobutadiene ND 0.025 

2-Hexanone ND 0.10 

Isopropylbenzene ND 0.010 

p-Isopropyltoluene ND 0.010 

Methylene chloride 0.031 B 0.025 

4-Methyl-2-pentanone ND 0.10 

Naphthalene ND 0.025 

n-Propylbenzene ND 0.010 

Styrene ND 0.010 

1,1,1,2-Tetrachloroethane ND 0.010 

1,1,2,2-Tetrachloroethane ND 0.025 

Tetrachloroethene ND 0.010 

Toluene 0.0073 J 0.010 

1,2,3-Trichlorobenzene ND 0.025 

1,2,4-Trichloro- ND 0.025 

benzene 

1,1,1-Trichloroethane ND 0.025 

1,1,2-Trichloroethane ND 0.025 

Trichloroethene ND 0.010 

Trichlorofluoromethane ND 0.050 

1,2,3-Trichloropropane ND 0.025 

1,2,4-Trimethylbenzene ND 0.010 

1,3,5-Trimethylbenzene ND 0.010 

Vinyl chloride ND 0.010 

m-Xylene & p-Xylene 0.0020 J 0.020 

o-Xylene ND 0.010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 90 (50 123) 

1,2-Dichloroethane-d4 7, (50 128) 

Toluene-dB 96 (50 120) 

BromoEluorobenzene 8, (50 120) 

NOTE (S) : 

B Method blank contamination. The associated method blank contains the target analyte at a reporuble level. 

J E~timaled resull. ReSUlt is less than RL. 

Matrix .•.•....• : AIR 

UNITS MDL 

u9 0.0010 

u9 0.0025 

U9 0.0068 

U9 0.0010 

u9 0.0010 

u9 0.0022 

u9 0.10 

u9 0.010 

U9 0.0010 

U9 0.0013 

u9 0.0011 

u9 0.0029 

U9 0.0011 

U9 0.0010 

u9 0.0010 

u9 0.0016 

u9 0.0010 

U9 0.010 

u9 0.0022 

u9 0.0017 

u9 0.025 

U9 0.0015 

U9 0.0018 

U9 0.0021 

u9 0.0020 

u9 0.0010 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN FB TKNAX 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-028 Work Order # ... , LOK281AA Matrix ......... : AIR 

Date Sampled ... : 04/23/10 Date Received .. : 04/27/10 

Prep Date ...... : 04/30/10 Analysis Date .. : 04/30/10 

Prep Batch It ... : 0119073 

Dilution Factor: 1 Method ......... ; SW846 vaST 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Acetone 0.049 J.B 0.10 ug 0.030 

Benzene NO 0.010 ug 0.0035 

Bromobenzene NO 0.010 ug 0.0020 

Bromochloromethane NO 0.025 ug 0.0028 

Bromodichloromethane NO 0.010 ug 0.0013 

Bromoform NO 0.025 ug 0.010 

Bromomethane NO 0.050 ug 0.0059 

2-Butanone NO 0.10 ug 0.10 

n-Butylbenzene NO 0.010 ug 0.0010 

sec-Butylbenzene NO 0.010 ug 0.0010 

tert-Butylbenzene NO 0.010 ug 0.0011 

Carbon disulfide NO 0.010 ug 0.0019 

Carbon tetrachloride NO 0.010 ug 0.0012 

Chlorobenzene NO 0.010 ug 0.0010 

Chlorodibromomethane NO 0.025 ug 0.0020 

Chloroethane NO 0.050 ug 0.0062 

Chloroform NO 0.010 ug 0.0011 

Chloromethane 0.0030 J.B 0.050 ug 0.0025 

2-Chlorotoluene NO 0.010 ug 0.0012 

4-Chlorotoluene No 0.010 ug 0.0014 

l,2-Dibromo-3-chloro- NO 0.050 ug 0.013 

propane 

1,2-Dibrornoethane NO 0.025 ug 0.0014 

Dibromornethane NO 0.025 ug 0.0021 

l,2-Dichlorobenzene NO 0.010 ug 0.0018 

l,3-Dichlorobenzene NO 0.010 ug 0.0014 

l,4-Dichlorobenzene NO 0.010 ug 0.0015 

Dichlorodifluoromethane 0.0031 J 0.025 ug 0.0024 

l,l-Dichloroethane NO 0.010 ug 0.0010 

1,2-Dichloroethane NO 0.010 ug 0.0017 

cis-1,2-Dichloroethene NO 0.010 ug 0.0010 

trans-l,2-Dichloroethene NO 0.010 ug 0.0020 

l,l-Dichloroethene NO 0.010 ug 0.0015 

l,2-Dichloropropane NO 0.010 ug 0.0017 

l,3-Dichloropropane NO 0.010 ug 0.0014 

2,2-Dichloropropane NO 0.010 ug 0.0010 

cis-1,3-Dichloropropene NO O. 010 ug 0.0017 

tranS-l,3-Dichloropropene NO O. 010 ug 0.0012 

l,l-Dichloropropene NO O. 010 ug 0.0010 

(Continued on next page) 
AirNova, Inc. 

Client Sample ID: M003! UNIT 2 RUN FB TENAX 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-028 Work Order # ... ; LOK281AA Matrix ......... : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Ethylbenzene NO 0.010 ug 0.0010 

Hexachlorobutadiene NO 0.025 ug 0.0025 

2-Hexanone NO 0.10 ug 0.0068 

Isopropylbenzene NO 0.010 ug 0.0010 

p-Isopropyltoluene NO 0.010 ug 0.0010 

Methylene chloride 0.073 B 0.025 ug 0.0022 

4-Methyl-2-pentanone NO 0.10 ug 0.10 

Naphthalene NO 0.025 ug 0.010 

n-propylbenzene NO 0.010 ug 0.0010 

Styrene NO 0.010 ug 0.0013 

1,1,1,2-Tetrachloroethane NO 0.010 ug 0.0011 

1,1, 2, 2-Tetrachloroethane NO 0.025 ug 0.0029 

Tetrachloroethene NO 0.010 ug 0.0011 

Toluene 0.0078 J 0.010 ug 0.0010 

1,2,3-Trichlorobenzene NO 0.025 ug 0.0010 

1,2,4-Trichloro- NO 0.025 ug 0.0016 

benzene 

1, 1, I-Trichloroethane NO 0.025 ug 0.0010 

1,1,2-Trichloroethane NO 0.025 ug 0.010 

Trichloroethene NO 0.010 ug 0.0022 

Trichlorofluoromethane NO 0.050 ug 0.0017 

1,2,3-Trichloropropane NO 0.025 ug 0.025 

1,2,4-Trimethylbenzene NO 0.010 ug 0.0015 

1,3,5-Trimethylbenzene NO 0.010 ug 0.0018 

Vinyl chloride NO 0.010 ug 0.0021 

m-xylene & p-Xylene NO 0.020 ug 0.0020 

o-xylene NO 0.010 ug 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 94 (50 123) 

1,2-Dichloroethane-d4 80 (50 120) 

Toluene-dB 99 (50 120) 

Bromofluorobenzene 81 (50 120) 

NOTE(S): 

Estimated result. Result is less Hliln RL. 

B Method blank contamination The associated method blank contains the target "nslyle at" reponeble level. 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN FB TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... , HOD270479-029 Work Order # ... , LOK291AA Matrix .•....... : AIR 

Date Sampled ... : 04/23/10 Date Received .. : 04/27/10 

Prep Date ...... : 04/30/10 Analysis Date .. : 04/30/10 

Prep Batch # ... : 0119073 

Dilution Factor; 1 Method ......... : SW846 vaST 

REPORTING 

PARAMETER RESULT LIMIT UNITS MDL 

Acetone 0.044 J,. 0.10 u9 0.030 

Benzene ND 0.010 u9 0.0035 

Bromobenzene ND 0.010 u9 0.0020 

Bromochloromethane ND 0.025 u9 0.0028 

Bromodichloromethane ND 0.010 U9 0.0013 

Bromoform ND 0.025 U9 0.010 

Bromomethane ND 0.050 u9 0.0059 

2-Butanone ND 0.10 u9 0.10 

n-Butylbenzene ND 0.010 U9 0.0010 

sec-Butylbenzene ND 0.010 U9 0.0010 

tert-Butylbenzene ND 0.010 U9 0.0011 

Carbon disulfide ND 0.010 u9 0.0019 

Carbon tetrachloride ND 0.010 u9 0.0012 

Chlorobenzene ND 0.010 u9 0.0010 

Chlorodibromomethane ND 0.025 U9 0.0020 

Chloroethane ND 0.050 u9 0.0062 

Chloroform ND 0.010 u9 0.0011 

Chloromethane 0.0065 J,B 0.050 u9 0.0025 

2-Chlorotoluene ND 0.010 U9 0.0012 

4-Chlorotoluene ND 0.010 U9 0.0014 

l,2-Dibromo-3-chloro- ND 0.050 U9 0.013 

propane 

l,2-Dibromoethane ND 0.025 u9 0.0014 

Dibromomethane ND 0.025 u9 0.0021 

l,2-Dichlorobenzene ND 0.010 U9 0.0018 

l,3-Dichlorobenzene ND 0.010 U9 0.0014 

l,4-Dichlorobenzene ND 0.010 U9 0.0015 

Dichlorodifluoromethane ND 0.025 u9 0.0024 

1,1-Dichloroethane ND 0.010 u9 0.0010 

1,2-Dichloroethane ND 0.010 u9 0.0017 

cis-l,2-Dichloroethene ND 0.010 U9 0.0010 

trans-1,2-Dichloroethene ND 0.010 U9 0.0020 

1,1-Dichloroethene ND 0.010 u9 0.0015 

l,2-Dichloropropane ND 0.010 u9 0.0017 

l,3-Dichloropropane ND 0.010 u9 0.0014 

2,2-Dichloropropane ND 0.010 u9 0.0010 

cis-l,3-Dichloropropene ND 0.010 u9 0.0017 

trans-l,3-Dichloropropene ND 0.010 U9 0.0012 

l,l-Dichloropropene ND 0.010 U9 0.0010 

{Continued on next page} 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN FB TEN/CHAR 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-029 Work Order # ... : LOK29lAA Matrix ......... : AIR 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Ethylbenzene NO 0.010 u9 0.0010 

Hexachlorobutadiene NO 0.025 U9 0.0025 

2-Hexanone NO 0.10 U9 0.0068 

Isopropylbenzene NO 0.010 u9 0.0010 

p-Isopropyltoluene NO 0.010 u9 0.0010 

Methylene chloride 0.068 B 0.025 U9 0.0022 

4-Methyl-2-pentanone NO 0.10 U9 0.10 

Naphthalene NO 0.025 U9 0.010 

n-Propylbenzene NO 0.010 u9 0.0010 

Styrene NO 0.010 u9 0.0013 

1,1,1,2-Tetrachloroethane NO 0.010 u9 0.0011 

1,1,2,2-Tetrachloroethane NO 0.025 U9 0.0029 

Tetrachlaraethene NO 0.010 U9 0.0011 

Toluene 0.0025 J 0.010 u9 0.0010 

1,2,3-Trichlorobenzene NO 0.025 u9 0.0010 

1,2,4-Trichloro- NO 0.025 u9 0.0016 

benzene 

1,1, I-Trichloroethane NO 0.025 U9 0.0010 

l,l,2-Trichloroethane NO 0.025 u9 0.010 

Trichloroethene NO 0.010 u9 0.0022 

Trichlorofluoromethane NO 0.050 u9 0.0017 

1,2,3-Trichloroprapane NO 0.025 U9 0.025 

l,2,4-Trimethylbenzene NO 0.010 U9 0.0015 

l,3,S-Trimethylbenzene No 0.010 U9 0.0018 

Vinyl chloride NO 0.010 u9 0.0021 

m-Xylene & p-xylene NO 0.020 u9 0.0020 

a-Xylene NO 0.010 u9 0.0010 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibramafluoromethane 87 150 123) 

1,2-Dichloroethane-d4 72 150 128) 

Toluene-dB 93 150 120) 

Bromofluorobenzene 67 150 120) 

NOTE{S): 

E!limBled result. Result is less Ihan RL. 

B Melhod blank contamination, The associated method blank conlains the target an"lyle at a reponable level. 
METHOD BLANK REPORT 

GC/MS Volatiles 

Client Lot If; ••• ; HOD270479 Work Order # ... , LOPCC1AA Matrix .... ..... ; AIR 

MB Lot-Sample ff; HOD290000-073 

Prep Date ...... ; 04/30/10 

Analysis Date .. ; 04/30/10 Prep Batch # ... ; 0119073 

Dilution Factor; 1 

REPORTING 

PARAMETER RESULT LIMIT UNITS METHOD 

Acetone 0.049 J 0.10 u9 SW846 VOST 

Benzene ND 0.010 U9 SW846 VOST 

Bromobenzene ND 0.010 U9 SW846 VOST 

Bromochloromethane ND 0.025 U9 SW846 VOST 

Bromodichloromethane ND 0.010 u9 SWB46 VaST 

Bromoform ND 0.025 u9 SW846 vaST 

Bromomethane ND 0.050 u9 SW846 VOST 

2-Butanone ND 0.10 U9 SWB46 VOST 

n-Butylbenzene ND 0.010 U9 SW846 VOST 

sec-Butylbenzene ND 0.010 U9 SW846 VOST 

tert-Butylbenzene ND 0.010 u9 SW846 VOST 

Carbon disulfide ND 0.010 u9 SWB46 VOST 

Carbon tetrachloride ND 0.010 u9 SWB46 VOST 

Chlorobenzene ND 0.010 U9 SW846 VOST 

Chlorodibromomethane ND 0.025 u9 SW846 VOST 

Chloroethane ND 0.050 u9 SW846 VOST 

Chloroform ND 0.010 u9 SW846 VOST 

Chloromethane 0.0066 J 0.050 u9 SW846 VOST 

2-Chlorotoluene ND 0.010 U9 SW846 VOST 

4-Chlorotoluene ND 0.010 U9 SW846 VaST 

l,2-Dibromo-3-chloro- ND 0.050 u9 SW846 VaST 

propane 

1,2-Dibromoethane ND 0.025 u9 SW846 VaST 

Dibromomethane ND 0.025 u9 SW846 vaST 

1,2-Dichlorobenzene ND 0.010 U9 SW846 vaST 

l,3-Dichlorobenzene ND 0.010 u9 SW846 vaST 

l,4-Dichlorobenzene ND 0.010 U9 SW846 vaST 

Dichlorodifluoromethane ND 0.025 u9 SW846 VaST 

l,l-Dichloroethane ND 0.010 u9 SW846 vaST 

1,2-Dichloroethane ND 0.010 u9 SW846 vaST 

cis-l,2-Dichloroethene ND 0.010 U9 SW846 VOST 

trans-l,2-Dichloroethene ND 0.010 U9 SWB46 vaST 

1,1-Dichloroethene ND 0.010 u9 SW846 VaST 

1,2-Dichloropropane ND 0.010 u9 SWB46 vaST 

1,3-Dichloropropane ND 0.010 u9 SW846 vaST 

2,2-Dichloropropane ND 0.010 U9 SWB46 VOST 

cis-1,3-Dichloropropene ND 0.010 u9 SWB46 vaST 

trans-l,3-Dichloropropene ND 0.010 U9 SW846 VOST 

1,1-Dichloropropene ND 0.010 u9 SWB46 vaST 

Ethylbenzene ND 0.010 u9 SWB46 VOST 

Hexachlorobutadiene ND 0.025 u9 SW846 VOST 

(Continued on next page) 
METHOD BLANK REPORT 

GC/MS Volatiles 

Client Lot # ... : HOD270479 Work Order ft ..• : LOPCClAA 

PARAMETER 

2-Hexanone 

Isopropylbenzene 

p-Isopropyltoluene 

Methylene chloride 

4-Methyl-2-pentanone 

Naphthalene 

n- propylbenzene 

Styrene 

1,1,1,2-Tetrachloroethane 

1,1,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

1,2,3-Trichlorobenzene 

1,2,4-Trichlorobenzene 

1,1,1-Trichloroethane 

1,1,2-Trichloroethane 

Trichloroethene 

Trichlorofluoromethane 

1,2,3-Trichloropropane 

1,2,4-Trimethylbenzene 

1,3,5-Trimethylbenzene 

vinyl chloride 

m-xylene & p-Xylene 

o-Xylene 

SURROGATE 

Dibromofluoromethane 

1,2-Dichloroethane-d4 

Toluene-d8 

Bromofluorobenzene 

NOTE (8) : 

RESULT 

ND 

ND 

ND 

0.0027 J 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

0.0014 J 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

ND 

PERCENT 

RECOVERY 

93 

79 

92 

77 

Calculations are performed before rounding to avoid round·off errors In calculal~d results. 

J EsHmated result Result is less [han RL. 

REPORTING 

LIMIT UNITS 

0.10 u9 

0.010 U9 

0.010 U9 

0.025 u9 

0.10 u9 

0.025 u9 

0.010 u9 

0.010 U9 

0.010 u9 

0.025 u9 

0.010 u9 

0.010 u9 

0.025 U9 

0.025 U9 

0.025 u9 

0.025 u9 

0.010 U9 

0.050 u9 

0.025 u9 

0.010 u9 

0.010 u9 

0.010 U9 

0.020 U9 

0.010 u9 

RECaVERY 

LIMITS 

(50 123) 

(50 128) 

(50 120) 

(50 120) 

Matrix ..... " .. : AIR 

METHaD 

SW846 VaST 

SW846 VOST 

SW846 vaST 

SW846 vaST 

SW846 vaST 

SW846 VOST 

SW846 vaST 

SW846 VOST 

SW846 vaST 

SW846 vaST 

SW846 vaST 

SW846 vaST 

SW846 VOST 

SW846 vaST 

SW846 vaST 

SW846 vaST 

SW846 VOST 

SW846 vaST 

SW846 vaST 

SW846 vaST 

SW846 vaST 

SW846 VOST 

SW846 vaST 

SW846 vaST 
LABORATORY CONTROL SAMPLE EVALUATION REPORT 

GC/MS volatiles 

Client Lot # ... : HOD270479 

HOD290000-073 

04/30/10 

0119073 

Work Order # ... : LOPCC1AC-LCS 

LOPCC1AD-LCSD 

Analysis Date .. : 04/30/10 

Matrix ......... : AIR 

LCS Lot-sample#; 

Prep Date ...... : 

Prep Batch # ... : 

Dilution Factor: 1 

PERCENT 

PARAMETER RECOVERY 

Benzene 102 

100 

Chlorobenzene " B4 

1,I-Dichloroethene 113 

lOB 

Toluene .3 

B6 

Trichloroethene 115 

112 

SURROGATE 

Dibromofluoromethane 

1,2-Dichloroethane-d4 

Toluene-d8 

Broroofluorobenzene 

NOTE (5) : 

Calculations arc performed before rounding 10 ~void round..,rr errors in calcul8tcd msults. 

Bold print denolei control paramelers 

RECOVERY RPO 

LIMITS RPD LIMITS METHOD 

( 6"7 120) SN846 VOST 

(67 120) 1.. (0-22) SN846 VOST 

(5. 120) SN846 VOST 

(5. 120) 7.7 (0-26) SN846 VOST 

(66 121) SW846 VOST 

(66 121) 5.1 (0-22) SW846 VOST 

(62 120) SN846 VOST 

(62 120) B.1 (0-22) SN846 VOST 

(6B 128) SN846 VOST 

(6B 120) 2.B (0-32) SW846 VOST 

PERCENT RECOVERY 

RECOVERY LIMITS 

102 (50 123) 

•• (50 123) 

8' (50 128) 

85 (50 128) 

100 (50 120) 

94 (50 120) 

B3 (50 120) 

B1 (50 120) 
LABORATORY CONTROL SAMPLE DATA REPORT 

GC/MS volatiles 

Client Lot # ... : HOD270479 Work Order # ... : LOPCCIAC-LCS Matrix ......... : AIR 

LCS Lot-Sample#: HOD290000-073 

Prep Date ...... : 04/30/10 Analysis Date .. : 

LOPCCIAD-LCSD 

04/30/10 

Prep Batch # ... : 0119073 

Dilution Factor: 1 

SPIKE MEASURED 

PARAMETER AMOUNT AMOUNT 

Benzene 0.250 0.255 

0.250 0.250 

Chlorobenzene 0.250 0.227 

0.250 0.211 

1,1-Dichloroethene 0.250 0.284 

0.250 0.269 

Toluene 0.250 0.232 

0.250 0.214 

Trichloroethene 0.250 0.288 

0.250 0.280 

SURROGATE 

Dibromofluoromethane 

1,2-Dichloroethane-d4 

Toluene-dS 

Bromofluorobenzene 

NOTE(S) ; 

Calculation, are perrorrned berore rounding to avoid round·orr errors in calculated results. 

Bold print denotes conlrol par~melers 

PERCENT 

UNITS RECOVERY 

ug 102 

ug 100 

ug 91 

ug 8. 

ug 113 

ug 108 

ug 93 

ug 8. 

ug 115 

ug 112 

PERCENT RECOVERY 

RECOVERY LIMITS 

102 (SO 123) 

99 (SO 123) 

8' (SO US) 

85 (SO 12S) 

100 (SO 120) 

" (SO 120) 

83 (SO 120) 

81 (SO 120) 

RPD METHOD 

SWS46 VOST 

1.9 SWS46 VOST 

SW846 VOST 

1.1 SWS46 VOST 

SW846 VOST 

5.1 SWS46 VOST 

SWS46 VOST 

8.1 SW846 VOST 

SW846 VOST 

2.8 SW846 VOST 
METHOD BLANK REPORT 

GC/MS Volatiles 

Client Lot # ... : HOD270479 Work Order # ... , LOPQRlAA Matrix ......... : AIR 

MB Lot-sample #: HOD290000-2l8 

Prep Date ...... : 05/03/10 

Analysis Date .. : 05/03/10 Prep Batch # ... : 0119218 

Dilution Factor: 1 

REPORTING 

PARAMETER RESULT LIMIT UNITS METHOD 

Acetone 0.039 J 0.10 u9 SWB46 VOST 

Benzene ND 0.010 u9 SW846 VaST 

Bromobenzene ND 0.010 u9 SW846 VaST 

Brornochloromethane ND 0.025 u9 SW846 VaST 

Bromodichloromethane ND 0.010 U9 SW846 VaST 

Bromoform ND 0.025 U9 SW846 VOST 

Bromomethane ND 0.050 u9 SW846 VOST 

2-Butanone ND 0.10 u9 SW846 VOST 

n-Butylbenzene ND 0.010 U9 SW846 VOST 

sec-Butylbenzene ND 0.010 U9 SW846 VOST 

tert-Butylbenzene ND 0.010 u9 SW846 VaST 

Carbon disulfide ND 0.010 u9 SW846 VOST 

Carbon tetrachloride ND 0.010 u9 SW846 VOST 

Chlorobenzene ND 0.010 u9 SW846 VOST 

Chlorodibromomethane ND 0.025 U9 SW846 VOST 

Chloroethane ND 0.050 u9 SW846 VOST 

Chloroform ND 0.010 u9 SW846 VOST 

Chloromethane 0.0097 J 0.050 u9 8W646 VOST 

2-Chlorotoluene ND 0.010 U9 SW846 VaST 

4-Chlorotoluene ND 0.010 U9 SW846 VOST 

l,2-Dibromo-3-chloro- ND 0.050 u9 SW846 VaST 

propane 

1,2-Dibromoethane ND 0.025 u9 SW846 VOST 

Dibromomethane ND 0.025 u9 SW846 VOST 

1,2-Dichlorobenzene ND 0.010 U9 SW846 VaST 

l,3-Dichlorobenzene ND 0.010 U9 SW846 VaST 

1 ,'I-Dichlorobenzene ND 0.010 U9 SW846 VaST 

Dichlorodifluoromethane ND 0.025 U9 SW846 VaST 

l,l-Dichloroethane ND 0.010 u9 SW846 VOST 

l,2-Dichloroethane ND 0.010 u9 SW846 VOST 

cis-l,2-Dichloroethene ND 0.010 u9 SW846 VaST 

trans-l,2-Dichloroethene ND 0.010 U9 8W846 VaST 

l,l-Dichloroethene ND 0.010 u9 SW846 VOST 

l,2-Dichloropropane ND 0.010 u9 SW846 VOST 

l,3-Dichloropropane ND 0.010 u9 SW846 VOST 

2,2-Dichloropropane ND 0.010 u9 SW846 VOST 

cis-l,3-Dichloropropene ND 0.010 u9 SW846 VOST 

tranS-l,3-Dichloropropene ND 0.010 U9 SW846 VOST 

l,l-Dichloropropene ND 0.010 U9 SW846 VOST 

Ethylbenzene ND 0.010 U9 8W846 VOST 

Hexachlorobutadiene ND 0.025 u9 81'1846 VOST 

(Continued on next page) 
METHOD BLANK REPORT 

GC/MS Volatiles 

Client Lot # ... : HOD270479 work Order # ... : LOPQRlAA 

PARAMETER 

2-Hexanone 

Isopropylbenzene 

p-Isopropyltoluene 

Methylene chloride 

4-Methyl-2-pentanone 

Naphthalene 

n-Propylbenzene 

Styrene 

l,l,l,2-Tetrachloroethane 

l,l,2,2-Tetrachloroethane 

Tetrachloroethene 

Toluene 

l,2,3-Trichlorobenzene 

1,2,4 -Trichlorobenzene 

l,l,l-Trichloroethane 

1,1,2-Trichloroethane 

Trichloroethene 

Trichlorofluoromethane 

l,2,3-Trichloropropane 

l,2,4-Trimethylbenzene 

1,3,5-Trimethylbenzene 

vinyl chloride 

m-xylene & p-Xylene 

o-Xylene 

SURROGATE 

Dihromofluoromethane 

l,2-Dichloroethane-d4 

Toluene-d8 

Bromofluorobenzene 

NOTE(S) : 

RESULT 

NO 

NO 

NO 

0.0042 J 

NO 

NO 

NO 

NO 

NO 

NO 

NO 

NO 

0.0012 J 

NO 

NO 

NO 

NO 

NO 

NO 

NO 

NO 

NO 

NO 

NO 

PERCENT 

RECOVERY 

86 

77 

93 

76 

Calculations are performed Derore rounding to avoid round·orr errors in calcuhrted results. 

J Estimaled re'iult. Resuli i, less than RL. 

REPORTING 

LIMIT UNITS 

0.10 U9 

0.010 U9 

0.010 u9 

0.025 u9 

0.10 U9 

0.025 U9 

0.010 U9 

0.010 u9 

0.010 u9 

0.025 u9 

0.010 U9 

0.010 U9 

0.025 u9 

0.025 u9 

0.025 U9 

0.025 U9 

0.010 U9 

0.050 u9 

0.025 U9 

0.010 U9 

0.010 U9 

0.010 u9 

0.020 u9 

0.010 u9 

RECOVERY 

LIMITS 

(50 123) 

(50 128) 

(50 l20) 

(50 l20) 

Matrix ......... : AIR 

METHaD 

SW846 VOST 

SWB46 VaST 

SWB46 vaST 

SWB46 vaST 

SW846 vaST 

SW846 VOST 

SW846 VOST 

SW846 vaST 

SW846 vaST 

SWB46 vaST 

SW846 vaST 

SW846 VOST 

SW846 VOST 

SWB46 vaST 

SW846 VOST 

SW846 VOST 

SWB46 vaST 

SWB46 vaST 

SW846 vaST 

SW846 vaST 

SW846 VaST 

SW846 vaST 

SWB46 vaST 

SWB46 vaST 
LABORATORY CONTROL SAMPLE EVALUATION REPORT 

GC/MS Volatiles 

Client Lot 11:. .. : HOD270479 Work Order # ... : LOPQR1AC-LCS Matrix ......... : AIR 

LC8 Lot-8ample#: HOD290000-218 

Prep Date ...... : 05/03/10 Analysis Date .. : 

LOPQRIAD-LCSD 

05/03/10 

Prep Batch # ... : 0119218 

Dilution Factor; 1 

PERCENT 

PARAMETER RECOVERY 

Benzene 90 

92 

Chlorobenzene 85 

81 

l,l-Dichloroethene 100 

105 

Toluene 88 

87 

Trichloroethene 100 

103 

SURROGATE 

Dibromofluoromethane 

1,2-Dichloroethane-d4 

Toluene-d8 

Bromofluorobenzene 

NOTE(S) : 

Calculaliorn; are perrormed berore rounding \0 avoid round-off errors in ealcul81ed resull'i. 

Bold print denoles conlrol paramelers 

RECOVERY RPD 

LIMITS RPD LIMITS 

(67 120) 

(67 120) 2.3 (0-22) 

(59 120) 

(59 120) 5.3 (0-26) 

(66 121) 

(66 121) 0.7 (0-22) 

(62 120) 

(62 120) 1.7 (0-22) 

(68 128) 

(68 128) 0.70 (0-32) 

PERCENT RECOVERY 

RECOVERY LIMITS 

85 (50 123) 

84 (50 123) 

73 (50 128) 

69 (50 128) 

90 (50 120) 

85 (50 120) 

77 (50 120) 

71 (50 120) 

METHOD 

SW846 VOST 

SW846 VaST 

SW846 VaST 

SW84.6 VaST 

SW846 VaST 

8W846 VOST 

8W846 VeST 

SW846 veST 

SW84.6 VaST 

8W846 VOST 
LABORATORY CONTROL SAMPLE DATA REPORT 

GC/MS volatiles 

Client Lot # ... : HOD270479 Work Order # ... : LOPQRIAC-LCS Matrix ......... : AIR 

LCS Lot-Sample#: HOD290000-218 

Prep Date ...... : 05/03/10 Analysis Date .. : 

LOPQRIAD-LCSD 

05/03/10 

Prep Batch # ... : 0119218 

Dilution Factor: 1 

SPIKE MEASURED 

PARAMETER AMOUNT AMOUNT 

Benzene 0.250 0.225 

0.250 0.230 

Chlorobenzene 0.250 0.213 

0.250 0.202 

1,I-Dichloroethene 0.250 0.251 

0.250 0.263 

Toluene 0.250 0.220 

0.250 0.217 

Trichloroethene 0.250 0.260 

0.250 0.258 

SURROGATE 

Dibromofluoromethane 

1,2-Dichloroethane-d4 

Toluene-d8 

Bromofluorobenzene 

NOTE (S) ; 

Calculation, are performed before rounding to avoid roull!:l·off errors in calculated r •• ults. 

Bold print. denotes control parameters 

PERCENT 

UNITS RECOVERY 

ug 90 

ug 92 

ug 85 

ug 81 

ug 100 

ug 105 

ug 88 

ug 87 

ug 100 

ug 103 

PERCENT RECOVERY 

RECOVERY LIMITS 

85 (50 123) 

8. (50 123) 

73 (50 128) 

69 (50 128) 

90 (50 120) 

85 (SO 120) 

77 (SO 120) 

71 (SO 120) 

RPD METHOD 

SW846 VOST 

2.3 SW846 VOST 

SW846 VOST 

5.3 SW846 VOST 

SW846 VOST 

4.7 SW846 VOST 

SW846 VOST 

1.7 SW846 VOST 

SW846 VOST 

0.70 SW846 VDST 
AirNova, Inc. 

Client Sample ID; M0031 UNIT 2 RUN FB COND 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-030 Work Order # ... , LOK3AlAA Matrix ......... : WATER 

Date Sampled ... : 04/23/10 Date Received .. : 04/27/10 

Prep Date ...... : 05/01/10 Analysis Date .. : 05/01/10 

Prep Batch # ... , 0119312 

Dilution Factor: 1 Method ......... : SW846 8260B 

REPORTING 

PARAMETER RESULT LIMIT UNITS MOL 

Acetone 16 10 ug/L 2.0 

Benzene NO 1.0 ug/L 0.025 

Bromobenzene NO 1.0 ug/L 0.051 

Bromochloromethane NO 1.0 ug/L 0.097 

Bromodichloromethane 0.084 J 1.0 ug/L 0.065 

Bromoform NO 1.0 ug/L 0.50 

Bromomethane NO 2.0 ug/L 0.14 

2-Butanone NO 5.0 ug/L 1.3 

n-Butylbenzene NO 1.0 ug/L 0.038 

sec-Butylbenzene NO 1.0 ug/L 0.034 

tert-Butylbenzene NO 1.0 ug/L 0.035 

Carbon disulfide 0.17 J 1.0 ug/L 0.039 

Carbon tetrachloride NO 1.0 ug/L 0.054 

Chlorobenzene NO 1.0 ug/L 0.041 

Chlorodibromomethane NO 1.0 ug/L 0.11 

Chloroethane NO 2.0 ug/L 0.13 

Chloroform 0.54 J 1.0 ug/L 0.036 

Chloromethane NO 2.0 ug/L 0.064 

2-Chlorotoluene NO 1.0 ug/L 0.050 

4-Chlorotoluene NO 1.0 ug/L 0.050 

l,2-Dibromo-3-chloro- NO 2.0 ug/L 0.33 

propane 

l,2-Dibromoethane NO 1.0 ug/L 0.094 

Dibromomethane NO 1.0 ug/L 0.097 

1,2-Dichlorobenzene NO 1.0 ug/L 0.035 

1/3-Dichlorobenzene NO 1.0 ug/L 0.043 

l,4-Dichlorobenzene NO 1.0 ug/L 0.049 

Dichlorodifluoromethane NO 2.0 ug/L 0.48 

l,l-Dichloroethane NO 1.0 ug/L a 034 

1,2-Dichloroethane NO 1.0 ug/L 0.046 

cis-l,2-Dichloroethene NO 1.0 ug/L 0.054 

trans-l,2-Dichloroethene NO 1.0 ug/L 0.036 

l,l-Dichloroethene NO 1.0 ug/L 0.066 

l,2-Dichloropropane NO 1.0 ug/L 0.048 

l,3-Dichloropropane NO 1.0 ug/L 0.036 

2,2-Dichloropropane NO 1.0 ug/L 0.053 

cis-l,3-Dichloropropene NO 1.0 ug/L 0.059 

trans-l,3-Dichloropropene NO 1.0 ug/L 0.056 

l,l-Dichloropropene NO 1.0 ug/L 0.042 

(Continued on next page) 
AirNova, Inc. 

Client Sample ID: M0031 UNIT 2 RUN FB COND 

GC/MS Volatiles 

Lot-Sample # ... : HOD270479-030 Work Order t~ ... : LOK3A1AA Matrix ......... : WATER 

REPORTING 

PARAMETER RESULT LIMIT UNITS MDL 

Ethylbenzene ND 1.0 ug/L 0.040 

Hexachlo~obutadiene ND 2.0 ug/L 0.19 

2-Hexanone ND 5.0 ug/L 0.25 

Isop~opylbenzene ND 1.0 ug/L 0.036 

p-Isopropyltoluene ND 1.0 ug/L 0.034 

Methylene chloride 4.8 B 2.0 ug/L 0.070 

4-Methyl-2-pentanone ND 5.0 ug/L 1.3 

Naphthalene ND 1.0 ug/L 0.12 

n-Propylbenzene ND 1.0 ug/L 0.017 

Styrene ND 1.0 ug/L 0.041 

l,l,l,2-Tetrachloroethane ND 1.0 ug/J~ 0.054 

1,1,2,2-Tetrachloroethane ND 1.0 ug/L 0.082 

Tetrachloroethene ND 1.0 ug/L 0.051 

Toluene 0.23 J 1.0 ug/L 0.047 

1,2,3-Trichlorobenzene ND 1.0 ug/L 0.14 

1, 2, 4-Trichloro- ND 1.0 ug/L 0.10 

benzene 

1,1,1-Trichloroethane ND 1.0 ug/L 0.070 

l,l,2-Trichloroethane ND 1.0 ug/L 0.079 

Trichloroethene ND 1.0 ug/L 0.054 

Trichlorofluoromethane ND 2.0 ug/L 0.038 

l,2,3-Trichloropropane ND 1.0 ug/L 0.18 

l,2,4-Trimethylbenzene ND 1.0 ug/L 0.031 

l,3,5-Trimethylbenzene ND 1.0 ug/L 0.017 

Vinyl chloride ND 2.0 ug/L 0.088 

m-xylene & p-Xylene ND 2.0 ug/L 0.036 

o-xylene ND 1.0 ug/L 0.046 

PERCENT RECOVERY 

SURROGATE RECOVERY LIMITS 

Dibromofluoromethane 100 (79 120) 

1,2-Dichloroethane-d4 9, (71 127) 

Toluene-d8 9S (80 120) 

Bromofluorobenzene 89 (69 126) 

NOTE (8) : 

Estimated reSIJl1. Result is Ie .. than RL. 

B Method blank contamination. The a",ociatcd methed blank cootains the l~rget ~n&tyte at a reportable level. 
METHOD BLANK REPORT 

GC/MS Volatiles 

Client Lot it ... ! HOD270479 Work Order # ... ! LOQDMlAA Matrix ......... : WATER 

MB Lot-Sample #: HOD290000-312 

Prep Date ...... : 05/01/10 

Analysis Date .. : 05/01/10 Prep Batch # ... : 0119312 

Dilution Factor: 1 

REPORTING 

PARAMETER RESULT LIMIT UNITS METHOD 

Acetone NO 10 ug/L SW846 8260B 

Benzene NO 1.0 ug/L SW846 8260B 

Bromobenzene NO 1.0 ug/L SW846 8260B 

Bromochloromethane NO 1.0 ug/L SW846 8260B 

Bromodichloromethane NO 1.0 ug/L SW846 8260B 

Bromoform NO 1.0 ug/L SW846 8260B 

Bromomethane NO 2.0 ug/L SW846 8260B 

2-Butanone NO 5.0 ug/L SW846 8260B 

n-Butylbenzene NO 1.0 ug/L SW846 8260B 

sec-Butylbenzene NO 1.0 ug/L SW846 8260B 

tert-Butylbenzene NO 1.0 ug/L SW846 8260B 

Carbon disulfide NO 1.0 ug/L SW846 8260B 

Carbon tetrachloride NO 1.0 ug/L SW846 8260B 

Chlorobenzene NO 1.0 ug/L SW846 8260B 

Chlorodibromomethane NO 1.0 ug/L SW646 8260B 

Chloroethane NO 2.0 ug/L SW846 8260B 

Chloroform NO 1.0 ug/L SW846 8260B 

Chloromethane NO 2.0 ug/L SW846 8260B 

2-Chlorotoluene NO 1.0 ug/L SW846 8260B 

4-Chlorotoluene NO 1.0 ug/L SW846 8260B 

l,2-Dibromo-3-chloro- NO 2.0 ug/L SW646 8260B 

propane 

l,2-Dibromoethane NO 1.0 ug/L SW646 8260B 

Dibromomethane NO 1.0 ug/L SW846 8260B 

l,2-Dichlorobenzene NO 1.0 ug/L SW846 8260B 

1,3-Dichlorobenzene NO 1.0 ug/L SW846 6260B 

1,4-Dichlorobenzene NO 1.0 ug/L SW846 6260B 

Dichlorodifluoromethane NO 2.0 ug/L SW646 8260B 

l,l-Dichloroethane NO 1.0 ug/L SW846 8260B 

l,2-Dichloroethane NO 1.0 ug/L SW846 8260B 

cis-l,2-Dichloroethene NO 1.0 ug/L SW846 8260B 

trans-l,2-Dichloroethene NO 1.0 ug/L SW846 8260B 

l,l-Dichloroethene NO 1.0 ug/L SW846 8260B 

l,2-Dichloropropane NO 1.0 ug/L SW846 8260B 

l,3-Dichloropropane NO 1.0 ug/L SW846 8260B 

2,2-Dichloropropane NO 1.0 ug/L SW846 8260B 

cis-l,3-Dichloropropene NO 1.0 ug/L SW846 8260B 

trans-l,3-Dichloropropene NO 1.0 ug/L SW846 8260B 

l,l-Dichloropropene NO 1.0 ug/L SW846 8260B 

Ethylbenzene NO 1.0 ug/L SW846 8260B 

Hexachlorobutadiene NO 2.0 ug/L SW846 8260B 

(Continued on next page) 
METHOD BLANK REPORT 

GC/MS 

Client Lot # ... : HOD270479 Work Order 

PARAMETER RESULT 

2-Hexanone ND 

Isopropylbenzene ND 

p-Isopropyltoluene ND 

Methylene chloride 0.37 J 

4-Methyl-2-pentanone ND 

Naphthalene ND 

n-Propylbenzene ND 

Styrene ND 

1,1,1,2-Tetrachloroethane ND 

1, I, 2, 2-Tetrachloroethane ND 

Tetrachloroethene ND 

Toluene ND 

1,2,3-Trichlorobenzene ND 

1,2,4-Trichloro- ND 

benzene 

l,l,l-Trichloroethane ND 

1,1,2-Trichloroethane ND 

Trichloroethene ND 

Trichlorofluoromethane ND 

1,2,3-Trichloropropane ND 

1,2,4-Trimethylbenzene ND 

1,3,S-Trimethylbenzene ND 

vinyl chloride ND 

m-Xylene & p-Xylene ND 

a-Xylene ND 

PERCENT 

SURROGATE RECOVERY 

Dibromofluoromethane 94 

1,2-Dichloroethane-d4 91 

Toluene-d8 99 

Bromofluorobenzene 93 

NOTE(S) : 

Calculations ~re performed before rounding to avoid round-off errors in calculated results. 

J Estimated re,ult. Re,ult is len lh.n RL. 

Volatiles 

:If- ••• : LOQDM1AA 

REPORTING 

LIMIT UNITS 

5.0 ug/L 

1.0 ug/L 

1.0 ug/L 

2.0 ug/L 

5.0 ug/L 

1.0 ug/L 

1.0 ug/L 

1.0 ug/L 

1.0 ug/L 

1.0 ug/L 

1.0 ug/L 

1.0 ug/L 

1.0 ug/L 

1.0 ug/L 

1.0 ug/L 

1.0 ug/L 

1.0 ug/L 

2.0 ug/L 

1.0 ug/L 

1.0 ug/L 

1.0 ug/L 

2.0 ug/L 

2.0 ug/L 

1.0 ug/L 

RECOVERY 

LIMITS 

(79 120) 

(71 127) 

(80 120) 

(69 126) 

Matrix ......... : WATER 

METHOD 

SW846 82608 

SW846 82608 

SW846 8260B 

SW846 82608 

SW846 82608 

SW846 82608 

SW846 82608 

SW846 8260B 

SW846 82608 

SW846 8260B 

SW846 82608 

SW846 8260B 

SW846 82608 

SW846 8260B 

SW846 8260B 

SW846 82608 

SW846 82608 

SW846 8260B 

SW846 8260B 

SW846 8260B 

SW846 8260B 

SW846 8260B 

SW846 8260B 

SW846 8260B 
LABORATORY CONTROL SAMPLE EVALUATION REPORT 

GC/MS Volatiles 

Client Lot # ... : HOD270479 Work Order # ... : LOQDMIAC-LCS Matrix ......... : WATER 

LCS Lot-Sample#: HOD290000-312 

Prep Date ...... : 05/01/10 Analysis Date .. ; 

LOQDMIAD-LCSD 

05/01/10 

Prep Batch # ... : 0119312 

Dilution Factor: 1 

PERCENT 

PARAMETER RECOVERY 

Benzene 98 

93 

Chlorobenzene 96 

93 

1,1-Dichloroethene 101 

93 

Toluene 9. 

90 

Trichloroethene 97 

91 

SURROGATE 

Dibromofluoromethane 

1,2-Dichloroethane-d4 

Toluene-d8 

Bromofluorobenzene 

NOTE (S) : 

Calculations an! performecl before rounding to avoid round·off errors in calculated results. 

Bold print denotes control parameters 

RECOVERY RPD 

LIMITS RPD LIMITS 

(80 121) 

(80 121) 5.2 (0-20) 

(80 121) 

(80 121) 3.3 (0-20) 

(70 128) 

(70 120) 8.8 (0-26) 

(77 124) 

(77 124) 4.1 (0-20) 

(80 121) 

(88 121) 6.8 (0-20) 

PERCENT RECOVERY 

RECOVERY LIMITS 

102 (79 120) 

100 (79 120) 

97 (71 127) 

92 (71 127) 

95 (80 120) 

97 (80 120) 

93 (69 126) 

9. (69 126) 

METHOD 

SW846 8260B 

SW846 82GOB 

SW846 82GOB 

SW846 8260B 

SW846 8260B 

SW846 8260B 

SW846 8260B 

SW846 8260B 

SW84.6 8260B 

SW846 8260B 
LABORATORY CONTROL SAMPLE DATA REPORT 

GC/MS Volatiles 

Client Lot # ... : HOD270479 

HOD290000-312 

05/01/10 

0119312 

Work Order ft ... : LOQDM1AC-LCS 

LOQDM1AD-LCSD 

Analysis Date .. : 05/01/10 

Matrix ......... : WATER 

LCS Lot-Sample#: 

Prep Date ...... : 

Prep Batch # ... : 

Dilution Factor: 1 

SPIKE MEASURED 

PARAMETER AMOUNT AMOUNT 

Benzene 10.0 9.82 

10.0 9.32 

Chlorobenzene 10.0 9.63 

10.0 9.31 

1,1-Dichloroethene 10.0 10.1 

10.0 9.25 

Toluene 10.0 9.41 

10.0 9.03 

Trichloroethene 10.0 9.69 

10.0 9.05 

SURROGATE 

Dibromofluoromethane 

1,2-Dichloroethane-d4 

Toluene-d8 

Bromofluorobenzene 

NOTE (S) : 

Calculations are performed before rounding to avoid round-orr errorS in calculated result5. 

Bold print denotes conlrOl parameters 

PERCENT 

UNITS RECOVERY RPD METHOD 

ug/L 9B 8W846 8260B 

ug/L 93 5.2 8""846 8260B 

ug/L 96 8""846 8260B 

ug/L 93 3.3 8""846 8260B 

ug/L 101 8""846 8260B 

ug/L 93 B.B 8""846 8260B 

ug/L 9. 8""846 8260B 

ug/L 90 4.1 8W846 8260B 

ug/L 97 8W846 8260B 

ug/L 91 6.B SW846 8260B 

PERCENT RECOVERY 

RECOVERY LIMIT8 

102 (79 120) 

100 (79 120) 

97 (71 127) 

92 (71 127) 

95 (BO 120) 

97 (80 120) 

93 (69 126) 

94 (69 126) 
. . .. ', ' .. ••• _. e •• _ 

., ...... '". -........ '. 

••••••••••• 

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AirNova, Inc. 

5845 Clayton Ava. 

Pennsauken, NJ 081 09 

856486-1500 

Fax: 856-486-9895 

~nm 

- Chain Of Custody Documentation Form 

I ~ ;?3:S3 ~lant: 'E-prvctv..t€ Gr>v,cbKir.A1I-lpud Vft' I sam~le Lobtion: IItv I r '""/wO 

,Date: '1-2-s - -ztiro 

,Date: '</-? s - "20/0 

d by: kiJ. 

Report Results To: It IT-PO lilt 

T .. t 

Sot 

i ~ T'L __ L"n Type Legend Contamer Type Legl 

F = fronl S IF' P = polybort!e (HOPE) tV 

Collection IAnalysis 

Method 

(include additional 

requirements) 

C =catch B = back amp e ractions G= glass wftluoroJid '" PreservlltiOIl 

Run Q = qlla!1z T = fluoropolymer (indicate # of each & Container Type) T=trap. ':' =vial..... \.. __ 

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.. --f(Jan. 2010) f I 
Iii II ~NALYTICAL PERSPECTIVES 

28 May 2010 

Joe Jackson 

AIRNOVA, Inc. 

5845 Clayton Avenue 

Pennsauken, NJ 08109 

Ph,; 856-486-1500 

FaK: 856-486-9896 

E-mail: iackson@aimoj!!!-.~cQm 

Subject Certificate of Results 

Dear Joe; 

Attached to this narrative are the analytical results you requested on the samples 

submitted for the detennination of polychlorinated dibenzo-p-dioxins and dibenzofurans 

and polychlorinated bIphenyl congeners. The insert below summanzes the relevant 

infonnation pertaining to your project In particular, the QC annotations bring to yOUT 

attention specific analytical observations and assessments made during the sample 

handling and data interpretation phases. A brief description of the report's components is 

provided on the next page. Results reported relate only to the items tested. 

Project Information SUmmary When applicable, see QC Annotations for details 

Client Project No. 

AP Project No. 

Analytical Protocol 

No. Samples Submitted 

No. Samples Analyzed 

No. Laboratory Method Blanks 

No. OPRs I Batch CS3 

No. Outstanding Samples 

Date Received 

Condition Received 

Temperature upon Receipt (e) 

Extraction within Holding Time 

Analysis within Holding Tlma 

Data meet QAlQC Requirements 

Exceptions 

Analytical Difficulties 

3333 Unit4 

P2196 

Methods 23 & 1668 

4 

4 

1 

o 

29·Apr-2010 

go"" 

·9 (Traps & Filten;). -2 (Solvents) 

y~ 

2714 ExCHANGE DRIVE 

WILMINGTON, NC 28405 

PH.: 91 0-794·1613 

112 

y~ 

see noles below 

see notes below 

see noles below 
PERSPECTIVES 

QC Annotations: 

I. Please see the attached appendices for a list of data qualifiers and lab identifiers 

that may be contained in the report. 

Analytical Perspeclives remains committed to serving you in the most effective manner. 

Should you have any questions or need additional information and technical support, 

please, do not hesitate to contact us. Thank you for choosing Analytical Perspectives as 

part of your analytical support team. 

Sincerely, 

r)../i Q ~~'«..:.<'::':"il..2...~ /. ',.--1-./ 

Heather Steele, Ph.D. 

Project Manager 

2714 EXCHANGE DRIVE 

WILMINGTON, NC 28405 

PH." 91Q·794·1613 

212 
APPENDIX A: DATA QUALIFIERS / DATA ATTRIBUTES 

• The reported concentration exceeds the calibration range (upper point of the calibration 

cllrve)~l 

> Indicates high recoveries. Shown with the numeric value at the top of the range. 

B The analyte is found in the method blank, at a level that is <-lOx the sample 

concentration. 

Two or more congeners co-elute. In EDDs C denotes the lowest IUPAC congener in a 

C co-elution group and additional co-eluters for the group are shown with the number of the 

lowest IUPAC co-eluter. 

E The reported concentration exceeds the calibration range (upper point of the calibration 

curve)~ 

Represents an Estimated Maximum PossIble Concentration. EMPC's al1se III cases where 

EMPC the signal/noise ratio is not sufficient for peak identification (the detelTI1ined IOnabundance ratio is outside the allowed theoretical range), or where there is a co-elutIng 

interference. 

ETH Indicates the presence of a diphenyl ether that appears to interfere with the quantitation of 

a furan. The reported concentration is the maximum. 

H/h If the standard recovery is below the method or SOP specified value "H" is assigned. If 

the obtained value is less than half the soecified value "h" is assigned. J 

J Indicates that an analyte has a concentration below the reporting limit (lowest point of the 

calibration curve). 

ND Indicates a non-detect. 

NR Indicates a value that is not reportable. 

PR Due to Interference, the associated congener is poorly resolved, 

QI Indicates the presence of a Quantitative interference. 

Ra The new ratio - [Ra] -- for 2,3,7,8-TCDD following the J/C14-2,3,7,8-TCDD correction is 

shown between squared brackets in the DL column. J 

Denotes "Single Ion Mode" and is utilized for PCBs where the secondary ion trace has a 

SI significantly elevated noise level due to background PFK. Responses for such peaks are 

calculated using an EMPC approach based solely on the pnmalY IOn area(s) and may be 

considered estimates. J 

U The analyte was not detected. The estImated detection limit (EDL) may be reported for 

this analyte. 

V The labeled standard recovery was found to be outside of the method control limits. 

X Indicates results reported from rein'ection, refractionahon, or repeat analyses. 

APPENDIX B: LAB ID IDENTIFIERS 

AR Indicates use of the archived portion of the sample extract. 

CU Indicates a sample that required additional clean-up prior to MS in'ection/processmg, 

D Indicates a dilution of the sample extract. The number that follows the "D" Indicates the 

dilution factor, 

DE Indicates a dilution perfolTI1ed with the addition of ES (extractIon standard) solution. 

DUP Designation for a duplicate sample. 

MS Designation for a matrix spike, 

MSD Designation for a matrix spike duplicate, 

RJ Indicates a reinjection of the sample extract. 

S Indicates a sample spliL. The number that follows the "S" indicates the split factor. 

Denotes data quaiIfiers/attnbutes whose use wJiI be phased out over tune 
Sample Summary 

Part 1 

Analyte 

2,3,7,8·TCDD 

1,2,3,7,8-PeCDD 

1,2,3,4,7,8-HxCDD 

1,2,3,6,7,8-HxCDD 

1,2.3,7,8,9-Hx.CDD 

1,2,3,4,6,7,8-HpCDD 

oeDO 

2,3,7,S-TCDF 

1,2,3,7,8-PeCDF 

2,3.4.7.8-PeCOF 

1,2,3,4,7,8-HxCDF 

1,2,3,6,7,6-HxCDF 

2,3,4,6,7,8-HxCDF 

1,2.3,7,6,9-HxCOF 

1,2,3,4,6,7,8-HpCDF 

1,2,3,4,7,8,9-HpCDF 

oeDF 

ITEF TEQ (ND=-O; EMPC"'O) 

ITEF TEQ (ND=O; EMPC=EMPC) 

ITEF TEQ (ND=DU2; EMPC=O) 

ITEF TEQ (NO=DU2; EMPC:EMPC) 

ITEF TEQ (ND=DL; EMPC;EMPC) 

Checkcode 

LablD 

() = DL 

[] = EMPC 

P2196 - TEQ 

Project ID: 3333 Unit 4 

.11 ANALYTICAL PERSPECTIVES 

O_7753_MBOO1 Blank Run One 

P9 P9 09 

(4.18) (3.46) (3.47) 

(4.25) (3.31) (3.41) 

(3.77) (3.32) (3.53) 

(4.15) (3.59) (3.84) 

(4.29) (3.86) (4.1) 

(5.01) (4.47) (4.38) 

(10.7) (9.2) (7.77) 

(2.72) (1.97) (2.47) 

(2.51) (2.24) (2.4) 

(2.51) (2.14) (2.17) 

(2.31) (1.98) (2.19) 

(2.29) (1.8) (2.3) 

(2.27) (2.01) (2.5) 

(3.04) (2.53) (3.2) 

(2.84) (1.82) 4.32 

(3.89) (3 14) (3.72) 

(8.83) (8.16) (7.48i 

0.00 0.00 0.0432 

0.00 0.00 0.0432 

5.15 4.26 4.49 

5.15 4.26 4.49 

10.3 8.51 8.93 

899-148 179-419 153-946 

MB1_7753 OF SDSRJ P2196 7753 001RJ P2196 7753 002RJ 

Method 23 

Run Two Run Three 

po P9 

(3.41) (2.03) 

(4.47) (1.72) 

(4 17) (1.79) 

(446) (1.86) 

(4.82) (2.04) 

(3.94) (2.03) 

42.3 16.7 

(2.61) (1.23) 

(2.44) (1.07) 

(2.49) (1.05) 

[3.39] (1.03) 

[2.95] (0.931) 

[3.72] (1.11) 

(3.62) (1.25) 

79.9 8.19 

(387) (1.64) 

74.3 [13.2] 

0.916 0.0986 

1.92 0.112 

5.87 2.41 

6.45 2.43 

11.0 4.74 

928·313 829·859 

P2196_7753_003RJ P2196_7753_004RJ 
Sample Summary 

Part 1 

Analyte 

2.3,7,S-ICOO 

1,2,3,7,8-PeCDD 

1,2,3.4.7,8-HxCDD 

1,2,3,6,7,8-HxCDD 

1,2,3,7,8,9-HxCDD 

1,2,3,4,6,7,8-HpCDD 

oeoo 

2,3,7,8·TCDF 

1,2,3,7,S·PeCDF 

2,3,4,7.8-PeCDF 

1,2,3,4,7,8-HxCDF 

1,2,3,6,7,8-HxCDF 

2,3,4,6,7.8-HxCDF 

1,2,3,7,8,9-HxCDF 

1,2,3,4,6,7,8-HpCDF 

1,2,3,4,7,6,9-HpCDF 

OCDF 

WHO·200S TEQ (ND=O; EMPC-=O) 

WHO·200S TEQ (ND:::O; EMPC=EMPC) 

WHO-200S TEQ (ND=DU2; EMPC=O) 

WHO-200S TEQ (ND:DU2; EMPC=EMPC) 

WHO-200S TEQ (ND:DL; EMPC=EMPC) 

Checkcode 

Lab 10 

() = DL 

[J = EMPC 

P2196 - WHO-200S-TEQ 

Project 10: 3333 Unit 4 

.11 ANALYTICAL PERSPECTIVES 

OJ7S3_MBOO1 Blank Run One 

P9 PO P9 

(4.18) (3.46) (3.47) 

(4.25) (3.31) (3.41 ) 

(3.77) (332) (3.53) 

(4.15) (359) (3.84) 

(4.29) (3.86) (4.1) 

(5.01) (4.47) (4.38) 

(10.7) (9 2) (7.77) 

(2.72) (1.97) (2.47) 

(2.51) (2.24) (2.4) 

(2.51) (2.14) (2.17) 

(2.31) (1.98) (2.19) 

(2.29) (1.8) (2.3) 

(2.27) (2.01) (2.5) 

(3.04) (2.53) (3.2) 

(2.84) (1.82) 4.32 

(3.89) (3.14) (3.72) 

(8.83) (8.16) (7.48) 

0.00 0.00 0.0432 

0.00 0.00 0.0432 

5.93 4.84 5.09 

5.93 4.84 5.09 

11.9 9.69 10.1 

899·148 179-419 153·946 

MB1_7753_0F _SOSRJ P2196_7753_001 RJ P2196_7753_002RJ 

Method 23 

Run Two Run Three 

P9 P9 

(3.41 ) (2.03) 

(4.47) (1.72) 

(4.17) (1.79) 

(4.46) (1.86) 

(4.82) (2.04) 

(3.94) (2.03) 

42.3 16.7 

(2.61) (1.23) 

(2.44) (1.07) 

(2.49) (1.05) 

[3.39J (1.03) 

[2.95J (0.931) 

[3.72J (1.11) 

(3.62) (1 25) 

79.9 8.19 

(3.87) (1.64) 

74.3 [13.2J 

0.834 0.0869 

1.84 0.0909 

6.63 2.71 

7.21 2.72 

12.6 5.34 

928·313 829-859 

P2196_7753_003RJ P2196_7753_004RJ 
P2196 - Totals 

Project 10: 3333 Unit 4 

Sample Summary II ANALYTICAL PERSPECTIVES Method 23 Part 2 .IJ-~~~~ 

Analyte O_7753_MB001 Blank Run One Run Two Run Three 

~ ~ ~ ~ ~ 

Totals 

TCOOs 0 0 0 0 0 

PeCDDs 0 0 0 0 0 

HxCDDs 0 0 0 0 0 

HpCDDs 0 0 0 0 0 

OCOO 0 0 0 42.3 16.7 

TCOFs 0 0 12.4 3.08 10.1 

PeCDFs 0 a 0 0 0 

HxCDFs 0 0 0 12 0 

HpCDFs 0 0 4.32 79.9 8.19 

OCDF 0 0 0 74.3 13.2 

Total PCDD/Fs(NO-=O; EMPC-=O) 0.00 0.00 16.7 212 35.0 

Tolal PCDD/Fs (NO-=O; EMPC-=EMPC) 0.00 0.00 32.1 257 67.0 

Tolal PCDDIFs (2378·X ND:DL; EMPC=EMPC) 69.5 59.0 91.0 298 87.8 

total,,2378s (NO=O;.EMPC=O)" '0.00 _ O~OO --' 4.32. ',~~;_ 0, .24,9 

T~_I'~318~' (~D~9,5; .I;Nn',C~O)· 34.80 -:" 29;50 ~3.~8.1 ' _._.-- -',2:2-1-,-: r _. 37.3' TotaJt3:78fj;,~D"'1; E.MPC=1)}-. 69.5' 59.0 . ,- 63.2' '-~45" 49.6. 

Total 2378s (NO:O; EMPC";'1'1 '0.00 0.00 8.65: . '403 -63:0 

TotaI2378sJNO=O.5;EMPC,=1) 34.8 -29.5- 33.8 227-- 48.5 

TOlal2378s(ND=1;EMPC=1) 69.5 59.0: 63:2'. - __ 247 -58;8 

Checkcode 899-148 179-419 153·946 928-313 829-859 

LablD M61_7753_DF_SDSRJ P2196_7753_001RJ P2196_7753_002RJ P2196_7753_003RJ P2196_7753_004RJ 

() = DL 

[] = EMPC 
Sample Summary 

Part 3 

Analyte 

Other PCDDIFs (ND:O, EMPC 0) 

Other TCDD 

Other PeCDD 

Other HxCDD 

Other HpCDD 

Other TCDF 

Other PeCDF 

Other HxCDF 

Other HpCOF 

Other PCDDIFs (ND=O, EMPC_EMPC) 

OlherTCDD 

Other PeCDD 

Other HxCDD 

Other HpCDD 

OlherTCDF 

Other PeCDF 

Other HxCDF 

Other HpCDF 

Checkcode 

Lab ID 

() = DL 

I] = EMPC 

P2196 - Others 

Project 10: 3333 Unit 4 

.11 ANALYTICAL PERSPECTIVES 

O_7753_MBOO1 Blank Run One 

PO pg pg 

0 0 0 

0 0 0 

0 0 0 

0 0 0 

0 0 12.4 

0 0 0 

0 0 0 

0 0 0 

0 0 0 

0 0 0 

0 0 0 

0 0 0 

0 0 27.8 

0 0 0 

0 0 0 

0 0 0 

899-148 179-419 153-946 

MB1_7753 OF _SDSRJ P2196_7753_001 RJ P2196_7753 002RJ 

Method 23 

Run Two Run Three 

pg pg 

0 0 

0 0 

0 0 

0 0 

3.08 10.1 

0 0 

12 0 

0 0 

6.97 0 

0 0 

0 0 

0 0 

24.1 25.7 

0 0 

197 0 

0 3.24 

928-313 829-859 

P2196_7753_003RJ P2196_7753_004RJ 
Sample Summary 

Part 5 

Analyte 

2,3,7,8-TCDD 

1.2,3,7.6-PeCDD 

1,2,3,4,7,8-HxCDD 

1,2,3,6,7,6-HxCDD 

1,2,3,7,B,e-HxCOD 

1,2,3.4.6,7,8-HpCDD 

ocoo 

2,3,7,8-TCDF 

1,2,3,7,8-PeCDF 

2,3,4,7,8-PeCDF 

1,2,3.4.7,8-HxCDF 

1,2,3,6,7,6-HxCDF 

2,3,4,6,7,8-HxCDF 

1,2,3,7,6,9·HxCDF 

1,2,3,4,6,7.8-HpCDF 

1,2,3,4,7,8,9-HpCDF 

OCDF 

TolalTCDD 

Total PeCDD 

Total HxCDD 

Total HpCDD 

Total TCOF 

Total PeCOF 

Total HxCOF 

Total HpCOF 

Checkcode 

Lab 10 

P2196 - DLs 

Proiect 10: 3333 Unit 4 

.11 ANALYTICAL PERSPECTIVES 

03753_MBOO1 Blank Run One 

P9 P9 P9 

4.18 3.46 3.47 

4.25 3.31 3.41 

3.77 3.32 353 

4.15 3.59 384 

429 3.86 4.1 

5.01 4.47 4.38 

10.7 9.2 7.77 

2.72 1.97 2.47 

2.51 2.24 2.4 

2.51 2.14 2.17 

2.31 1.98 2.19 

2.29 1.8 2.3 

2.27 2.01 2.5 

3.04 2.53 3.2 

2.84 1.82 233 

389 3.14 3.72 

8.83 8.16 7.48 

4.18 3.46 3.47 

4.25 3.31 3.41 

4.06 358 3.81 

5.01 4.47 4.38 

2.72 1.97 2.47 

2.51 2.19 2.28 

2.45 2.05 2.5 

3.3 2.35 2.92 

899-148 179-419 153-946 

MB1 7753 OF SDSRJ P2196 7753~OO1RJ P2196 7753~OO2RJ 

Method 23 

Run Two Run Three 

P9 P9 

3.41 2.03 

4.47 1.72 

4.17 1.79 

4.46 186 

4.82 2.04 

3.94 2.03 

10.2 4.47 

2.61 1.23 

2.44 1.07 

2.49 1.05 

2.95 1.03 

2.71 0.931 

2.96 1.11 

3.62 1.25 

2.71 1.1 

3.87 1.64 

8.28 3.98 

3.41 2.03 

4.47 1.72 

4.47 1.89 

3.94 2.03 

261 123 

2.46 1.06 

3.03 1.07 

3.2 1.33 

928-313 829-859 

P2196 7753~OO3RJ P2196~7753~004RJ 
pg 

4-' 

0' " 

0' 

~~" ,>" 

~'" '" 

ITEF-TEQ 

ProjecllD: 3333 Unil4 

P2196 

oc· 

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Q ND=O- EMPC-O -

~ ND=O; EMPC=EMPC I 

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Project 10: 3333 Unit 4 

P2196 

o~· 

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EJND=O; EMPC=O 

~ ND=O; EMPC=EMPC 

o ND=DU2; EMPC=O 

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rn ND=DL; EMPC=EMPC -~--.,-. 

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pg 

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Totals 

Project 10: 3333 Unit 4 

P2196 

o· o 

,<-",0 

0Total PCDD/Fs (ND=O; EMPC=O) 

DTotal PCDD/Fs (ND=O; EMPC=EMPC) 

~Total PCDO/Fs (2378-X ND=DL; EMPC=EMPC) 

~o ~ .,,0 •• <f 

,<-",0 
% Rec. 

Mean Recoveries of Extraction Standards (N=5) 

Project 10: 3333 Unit 4 

P2196 L:Mean o SId. Dev. 

, iC--,gr , '" .~ ..$!J~ .' , Of' ," ,1" <{Yo., 90 ," ," ," <i:P 

, 

80 ; 

70 

60 

50 , 

, 

40 

30 

20·· 

10 

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,,"j .;:s '" , 

1/" cl 

" 

Method Specification Limits: Tetra-Hexa ES: 40-130%, Hepta-Octa ES: 25-130% (F = fail) 

" 

~, 

,- .~ 

,,' .0 cl 

-('--

/. 

/. 

,,' 0° CJ " 
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Mean Recoveries of Sampling Standards (N=5) 

Project 10: 3333 Unit 4 

" 

0S' (?0 

P2196 

" 

<§ 

.0 

c;< 

" 

<§ p 

c;'" 

Method Specification Limits: Tetra-Octa SS: 70-130% (F = fail) 

121 Mean 

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Sample 10: 0 7753 MBOO1 Method 23 

Client Data Sample Data Laboratory Data 

Name- AirNova, Inc. Matnx: Air Lab Project 10; P2196 Date Received: o/a 

Project ID: 3333 Unit 4 WeighWolume: 1 Lab Sample 10 MB1J753_DF _SDSRJ Date Extracted: 06 May 2010 

Date Collected- o/a OC Batch No: 7753 Date Analyzed: 22 May 2010 

Split 2 Dilulion- - Time Analyzed: 00:46:17 

Analyte Cone. (pg) Dl (pg) EMPC (pg) Qualifiers Standard ES Recoveries Qualifiers 

2378-TCDD NO 4.18 ES237lHCDD 89-1 

12376-PeCOD NO 4.25 ES 12378·PecOD 858 

123478-HxCDD NO 3.77 ES 123478-HxCDD 87.9 

123676-HxCDD NO 415 ES 123678-HxCDO 87 

1237B9-HxCDD NO 4.29 ES 123789-HxCDD 86.9 

1234678-HpCOD NO 5.01 ES 1234678-HpCOO 88 

OCOD NO 10] ESOCDD 81.7 

237S-TeOF NO 2.72 ES 237!3-TCDF 87.2 

12378-PeCDF NO 2.51 ES 12378-PeCOF 84.1 

23478-PeCDF NO 2.51 ES 23476-PeCDF 83 

123476-HxCDF NO 2_31 ES 123478-HxCDF 87.2 

123676-HxCDF NO 2.29 ES 123678-HxCDF 859 

234678-HxCDF NO 2.27 ES 234678-HxCDF 87.6 

123769-HxCDF NO 3.04 ES 123789-HxCDF 88 

1234678-HpCDF NO 2.84 ES 1234678-HpCDF 87.9 

1234789-HpCDF NO 3.89 ES 1234789-HpCOF 88.6 

OCDF NO 8.83 ESOCDF 82.2 

Totals Standard SS/AS Recoveries 

ss 37CI-2376-TCOO 95.5 

Total TCDD NO 4.18 NO SS 12347-PeCDD 95A 

Total PeCDD NO 425 NO SS 12346-PeCDF 94.8 

Total HxCOO NO 4.06 NO SS 123469-HxCOF 101 

Total HpCOO NO 5.01 NO SS 1234689-HpCOF 95.2 

AS 1386-TCOO 88.9 

Total TCDF NO 2.72 NO AS 1368-TCDF 835 

Total PeCDF NO 251 NO 

Total HxCOF NO 245 NO 

Total HpCDF NO 3.3 NO 

Total PCDD/Fs NO NO 

ITEF TEQs 

TEO: ND=O 0 0 .11 ANALYTICAL PERSPECTIVES 

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Checkcode: 699-146 AP OIF 2010 Rev. L Report Created: 22-May-2010 11:09 Analyst: MC 
Sample 10: Blank Method 23 

Client Data Sam~le Data LabolCltory Data 

Name: AirNova, Inc Matrix: Air lab Project 10: P2196 Date Received: 29 Apr 2010 

Project 10 3333 Unit 4 WeighWolume: 1 Lab Sample 10 P2196_7753_001RJ Date Extracted: 06 May 2010 

Date Collected: 22 Apr 2010 QC Batch No: 7753 Date Analyzed: 22 May 2010 

Split: 2 Dilution: - Time Analyzed: 01 :36:51 

Analyte Cone. (pg) DL (pg) EMPC (P9) Qualifiers Standard ES Recoveries Qualifiers 

2378-TCDD NO 3.46 ES 2378-TCDD 84.3 

12378-PeCDD NO 3.31 ES 12378-PeCDD 86.1 

123478-HxCDD NO 3.32 ES 123478-HxCDD 85.2 

123678-HxCDD NO 3.59 ES 123678-HxCOD 81.3 

123789-HxCDD NO 3.86 ES 123789-HxCDD 80.8 

1234678-HpCDD NO 4.47 ES 1234678-HpCOO 83.3 

OCOD NO 92 ESOCDO 75.3 

2378-TCDF NO 1.97 ES 2378-TCDF 86.2 

12378-PeCDF NO 2.24 ES 12378-PeCOF 83.2 

23478-PeCDF NO 2.14 E523478·PeCDF 85.8 

123478·HxCDF NO 1.98 E5 123478-HxCDF 82.6 

123678·HxCDF NO 1.8 E5 123678-HxCDF 84.6 

234678·HxCDF NO 2.01 E5234678-HxCDF 78.5 

123789·H:w::CDF NO 2.53 E5 1237S9-H:w::CDF 80.3 

1234678·HpCDF NO 1.82 E51234678-HpCDF 87.1 

1234789·HpCDF NO 3.14 E51234789-HpCDF 75 

OCDF NO 8.16 E50CDF 72.1 

Totals Standard SSIAS Recoveries , 

5537CI-2378·TCDD 99.' l 

Total TCDD NO 3.46 NO 5512347-PeCDD 96.3 

Tolal PeCDD NO 3.31 NO 55 12346·PeCDF 101 

Tolal HxCDD NO 3.58 NO 55 123469-H)(CDF 95.2 

Tolal HpCDD NO 4.47 NO 55 1234589-HpCDF 89.4 

AS 1368-TCDD 89.3 

Total TCDF NO 1.97 NO AS 1368-TCDF 86.6 

Tolal PeCDF NO 2.19 NO 

Total HxCDF NO 2.05 NO 

Total HpCDF NO 2.35 NO 

Total PCDD/Fs NO NO 

ITEF TEQs 

TEQ: ND=O 0 0 II ANALYTICAL PERSPECTIVES 

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Tel: +1 910794-1613 (Fa:w::: ·3919); ToIl·Free 866 846·8290 www.ultratrace.oom 

Checkcode: 179419 AP DfF 2010 Rev. L Report Created: 22-May-2010 11:10 Analyst: MC 
Sample 10: Run One Method 23 

Client Data SamP'le Data Laborato!)f Data 

Name: AirNova, Inc. Matrix: Air Lab Project ID: P2196 Date Received: 29 Apr 2010 

Project 10: 3333 Unit 4 WeighWolume. 1 Lab Sample 10 P2196_7753_002RJ Date Extracted: 06 May 2010 

Date Collected" 20 Apr 2010 QC Batch No: 7753 Date Analyzed. 22 May 2010 

Split: 2 Dilution: - Time Analyzed: 02:27:24 

Analyte Cone. (pg) OLlpg) EMPe Ipg) Qualifiers standard ES Recoveries Qualifiers 

2378-TCOD NO 3.47 ES 2378-TeDD 84.9 

12378-PeCDD NO 341 ES 12378-PeCDD 87.9 

123478-HxCDD NO 3.53 ES 12347S-HxCDD 90.3 

123678-HxCDD NO 3.84 ES 123678-HxCDD 88.1 

123789--HxCDD NO 4.1 ES 123789-HxCDD 85.3 

1234678-HpCOD NO 4.38 ES 1234678-HpCOD 85.9 

Deco NO 7,77 ESOCDD 75.3 

2378-TCDF NO 2.47 ES 2378-TCDF 82.8 

12378-PeCDF NO 2. ES 12378-PeCDF 82.9 

23478-PeCDF NO 2.17 ES 23478·PeCDF 83.2 

123478'HxCDF NO 2 19 ES 123478-HxCDF 908 

123678·HxCDF NO 2.3 ES 123678-HxCDF 89.3 

234678·HxCDF NO 2.5 ES 234678-HxCDF 87.9 

123789·HxCDF NO 3.2 ES 123789-HxCDF 82 

1234678·HpCDF 4.32 J ES 1234678-HpCDF 87 

1234789·HpCDF NO 3.72 E51234789·HpCDF 83.8 

OCDF NO 7.48 ESOCDF 77.9 

Totals Standard SS/AS Recoveries 

SS 37CI·2378~TCDD 97 

Total TCDD NO 3.47 NO SS 12347·PeCDD 98.8 

Tolal PeCDD NO 341 NO 5512346·PeCDF 101 

Tolal HxCDD NO 381 NO 55 123469-HxCDF 101 

Tolal HpCDD NO 4.38 NO 551234689-HpCDF 98.5 

AS 1368·TCDD 94.2 

Total TCDF 12.4 27.8 AS 1368-TCDF 89 

Total PeCDF NO 2.28 NO 

Total HxCDF NO 2.5 NO 

Tolal HpCDF 4.32 4.32 

Total PCDD/Fs 16.7 32.1 

ITEF TEQs 

TEO ND=O 0.0432 0.0432 .11 ANALYTICAL PERSPECTIVES 

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Chec::J(code: 153--945 AP DfF 2010 Rev. l Report Crealed: 22-May·2010 11.10 Analyst: MC 
Sample 10: Run Two Method 23 

Client Data Sam~le Data Laboratory Data 

Name: AirNova, Inc Matrix: Air Lab Project 10: P2196 Date Received: 29 Apr 2010 

Project 10: 3333 Unit 4 WeightIVolume. 1 lab Sample ID P2196_77S3_003RJ Date Extracted: 06 May 2010 

Date Collected: 21 Apr 2010 QC Batch No: 7753 Date Analyzed: 22 May 2010 

Split: 2 Dilution: - Time Analyzed: 03:17:59 

Analyte Cone. (pg) DL (pg) EMPC Cpg) Qualifiers Standard ES Recoveries Qualifiers 

2378-TCDD NO 3.41 ES 2378-TCDD 80.7 

12378-PeCDD NO 4.47 ES 12378-PeCDD 82.2 

123478-H)CCDD NO 4.17 ES 123478-HxCOD 83 

123678-HxCDD NO 4.46 ES 123678-HxCDD 79.8 

123789-HxCDD 

, NO 4.82 ES 123789·H)(CDO 79.5 

'1234678-HpCDD NO 3.94 ES 1234678-HpCDD 7B.S 

oeoc 42.3 J ESOCDD 72.9 

237S-leOF NO 2.61 ES 2378-TeDF 81.8 

12378-PeCDF NO 2.44 ES 12378-PeCDF 82 1 

23478-PeCDF NO 2.49 ES 23476-PeCDF 79.2 

123478-HxCOF EMPC 3_39 J ES 123476-HxCOF 80.2 

123678-HxCDF EMPC 2.95 J ES 123678-HxCDF 81.2 

234678-HxCDF EMPC 3.72 J ES 234678-HxCDF 79.9 

123789-HxCDF NO 3.62 ES 123789-HxCDF 79.5 

1234678-HpCDF 79_9 ES 1234678-HpCOF 825 

12347B9-HpCDF NO 3.87 ES 1234789-HpCDF 79 

oeDF 74.3 J ESOCDF 75.6 

Totals Standard SS/AS Recoveries 

55 37CI-2378-TCDD 94.5 

Total TeDD NO 697 5512347-PeCDD 90.5 

Total PeCOD NO 4.47 NO 55 12346-PeCDF 94.6 

Total HxCDD NO 4.47 NO 58 123469-HxCDF 90.9 

Total HpCDD NO 3.94 NO 55 1234689-HpCOF 90.5 

AS 1368-TCOD 85.5 

Total leDF 3.08 24.1 AS 1368-TCDF 80.5 

Total PeCDF NO 2.46 NO 

Total HxCDF 12 29.7 

Total HpCDF 79.9 79.9 

Total PCDD/Fs 212 257 

ITEFTEQs 

TEO: ND=O 0.916 1.92 .11 ANALYTICAL PERSPECTIVES 

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Checkcode: 928-313 AP DIF 2010 Rev. L Report Created: 22-May-2010 11:10 Analyst MC 
Sample 10: Run Three Method 23 

Client Data Sample Data Laboratory Data 

Name_ AirNova, Inc. Matrix: A" Lab Project ID: P2196 Date Received: 29 Apr 2010 

Project ID: 3333 Unit 4 WeighWolume: 1 Lab Sample ID P2196_77S3_004RJ Date Extracted: 06 May 2010 

Date Collected: 22 Apr 2010 QC Batch No: 7753 Date Analyzed: 22 May 2010 

Split 2 Dilution: - Time Analyzed: 04:08:33 

Analyte Conc. (pg) DL (pg) EMPe (pg) Qualifiers Standard ES Recoveries Qualifiers 

2378-TCDD NO 203 ES 2378-TCDD 91.4 

12376-PeCDD NO 1.72 ES 12378-PeCDD 975 

12347B-HxCDO NO 1.79 ES 12347S-HxCDD 92.2 

123678-HxCDD NO 1.86 ES 123678-HxCDO 90.7 

123789-HxCDD NO 2.04 ES 123789-HxCDD 89.8 

1234678-HpCDD NO 2.03 ES 1234678·HpCDD 88.6 

aeoc 16.7 J ESOCDD 76.7 

2378-TCDF NO 1.23 ES 2378-TCDF 91.5 

12378-PeCDF NO 1.07 ES 12378-PeCDF 89.9 

23478-PeCDF NO 1.05 E523478-PeCDF 90.3 

123478-HxCDF NO 1.03 E5 12'1478-HxCDF 92.2 

123678-HxCDF NO 0.931 ES 123678-HxCDF 93 

234678-HxCDF NO 1.11 E5234678-HxCDF 86.9 

123789-HxCDF NO 1.25 E5123789-HxCDF 88.7 

1234678-HpCDF 8.19 J E5 1234678-HpCDF 89.2 

1234789-HpCDF NO 1.64 E5 1234789-HpCDF 85.9 

oeD' EMPC 13.2 J E50CDF 79.1 

Totals Standard SS/AS Recoveries 

5537CI-2378-TCDD 94 

Tolal TCDO NO 2.03 NO 5512347-PeCDD 94.5 

Total PeCOD NO 1.72 NO S512346-PeCDF 95.6 

Total HxCDD NO 1.89 NO S5123469-HxCDF 94.7 

Total HpCDD NO 2.03 NO 55 1234689-HpCDF 95.4 

AS 1368-TCDD 97_3 

Total TCDF 10.1 25.7 AS 1368..-TCDF 941 

Tolal PeCDF NO 1_06 NO 

Total HxCDF NO 1.07 NO 

Total HpCDF 8.19 11.4 

Total PCDD/Fs 3. 67 

ITEF TEQs 

TEO: ND=O 0.0986 0.112 .11 ANALYTICAL PERSPECTIVES 

2714 Exchange Drive 

TEa· ND=DU2 2.41 2.43 Wilminglon, NC 28405, USA 

TEO NO=DL 4.73 4.74 info@ullralrace.com 

Tel: +1 910794-1613 (Fax: -3919); Toll-Free 866 846-8290 www.ultratrace.com 

Checkcode: 829--859 AP DIF 2010 Rev. L Report Created: 22-May-2010 11:10 Analyst Me 
Sample Summary 

Analyte 

PCB-77 

PCB-81 

PCB-i0S 

PCB-114 

PCB-118 

PCB-123 

PCB-126 

PCB-156/157 

PCB-167 

PCB-169 

PCB-189 

TEQs (WHO 2005 M/H) 

NO=O;EMPC=O 

NO = 0; EMPC = EMPC 

NO = OU2; EMPC = 0 

NO = OLl2; EMPC = EMPC 

NO=OL;EMPC=O 

NO = OL; EMPC = EMPC 

Checkoode 

() = DL 

0= EMPC 

Method Blank 

O_7753_MBOO1 

Conc. P9 

(6.4B) 

(6.7B) 

(5.25) 

(5.21) 

23.3 

(5.39) 

(7.95) 

(11.3) 

(B.65) 

(10.B) 

(11.6) 

0.000699 

0000699 

0.562 

0.562 

1.12 

1.12 

PW 

P2196 

Project ID: 3333 Unit 4 

.11 ANALYTICAL PE):l:SPEC'l"VES 

Blank Run One 

Conc. pg Conc. P9 

(10.9) 16.2 

(10.7) (14.9) 

[14.7] 64.9 

(B.50) (9.55) 

36.2 173 

(B.30) (9.07) 

(B.64) (11.7) 

(14.6) (20.2) 

(10.9) (15.2) 

(14.9) (21.1) 

(13.1) (17.B) 

0.00109 0.00876 

0.00153 0.00876 

0.659 0.913 

0.659 0.913 

1.32 1 B2 

1.32 1 B2 

,8 " 

HR-PCB 

Run Two Run Three 

Conc. P9 Conc. pg 

12.8 18.2 

(4.64) (7.67) 

6B.B 94.0 

(4.5) (5.01) 

177 242 

(4.34) (4 7B) 

(6 15) (6.29) 

22.9 32.5 

(7.54) (7.4B) 

(9.93) (10.7) 

(B.21) (B.47) 

0.00933 0.0129 

0.00933 0.Q129 

0.467 0.489 

0.467 0.489 

0.925 0.965 

0.925 0.965 

" u~ 
PCB Recoveries 

Standard 

ES PCB-1 

ES PCB-3 

ES PCB-4 

ES PCB-15 

ES PCB-19 

ES PCB-37 

ES PCB-54 

ES PCB-77 

ES PCB-81 

ES PCB-104 

ES PCB-tOS 

ES PCB-114 

ES PCB·118 

ES PCB-123 

ES PCB-126 

ES PCB-1S3 

ES PCB-1SS 

ES PCB-1S6/1S7 

ES PCB-167 

ES PCB-169 

ES PCB-170 

ES PCB-180 

ES PCB-188 

ES PCB-169 

ES PCB-202 

ES PCB-20S 

ES PCB-206 

ES PCB-20B 

ES PCB-209 

Che<:kcode 

0= DL 

0= EMPC 

P2196 

Project 10: 3333 Unit 4 

.11 ANA.LYTICA.L PERSPECTIVES 

Method Blank Blank O_7753_MBOO1 

78.5 734 

87.3 80.3 

879 80.3 

105 90.0 

94.6 82.0 

109 90.9 

105 87.2 

105 869 

108 88.5 

107 89.0 

107 91.0 

104 87.6 

105 67.1 

107 92.3 

103 88.0 

107 88.5 

110 93.5 

104 89.9 

105 93.3 

100 88.4 

116 100 

115 980 

105 89.8 

113 97.4 

105 90.0 

110 97.2 

108 93.4 

115 96.9 

105 905 

,"' " 

HR-PCB 

Run One Run Two Run Three 

73.3 65.9 67.8 

79.3 79.7 80.6 

80.6 80.8 82.2 

91.0 90.8 97.1 

83.1 82.0 85.7 

92.4 91.9 94.0 

89.7 84.4 81.8 

8a.2 86.6 88.3 

88.3 87.3 90.4 

96.5 95.0 99.0 

90.4 86.9 91 1 

88.4 87.9 88.8 

90.3 89.7 90.6 

92.6 91.8 92.7 

67.2 85.0 65.0 

92.3 91.8 96.4 

97.3 97.4 102 

90.6 67.5 90.4 

93.0 89.4 93.6 

64.8 85.9 84.1 

102 102 107 

103 103 104 

92.6 90.3 942 

100 101 101 

91.2 89.2 94.6 

98.0 98.1 98.1 

98.3 98.7 97.7 

101 101 102 

95.7 93.5 94.0 

~11 " u; 
,."' " ,.< J>~ 

+-'" 

"" 

+~" "' 

PCBTEQ 

Project 10: 3333 Unit 4 

P2196 

,. 

<i;'b'<::' o<f 

",< 

~o ~ .-,,0 

,§> 

,,, 

.-,,< 

ND = 0, EM PC = 0 .NO = 0; EMPC = EMPC DND = DU2; EMPC = 0 

o NO = DU2; EMPC = EMPC • NO = DL; EMPC = 0 iii NO = DL; EM PC = EMPC -------- - ------~-.--------------.. 
250 

200 / 

150 

pg 

100-

50 

o , 

,p"? 

0' 

~"," 

-0{Jv 

*"' ,." .'" ~# 

PCB WHO 

Project 10: 3333 Unit 4 

P2196 

¥~- ... 

<:iJ-'?><::' * 

, ,-

o "0 

<>co" 

" , 

~p 

<>co" 

'" 

~o!' 

<>co" 

II!IPCB-77 .PCB-8!E~CB-105 DPCB-114 .PCB-118 ~PCB-123 .PCB-126 DPC~_:~56/157 .PCB~167 .PCB-169 DPCB-1@ 
in 

z " -

S~~-66 

aO~-E6 

OLL-L6 

88-08 

Le-6.!. 
Sample 10: Blank 

Client Data Sample Data 

Name: AirNova,lnc_ Matrix: 

Project 10: 3333 Unit4 WeighWolume: 

Dale Collected: 22-Apr-l0 

Analyle Cone. 

pg 

PCB-7733'44"-TeCB NO 

PCB-81344'5-TeCB NO 

PCB-10S 233'44"-PeCB EMPC 

PCB-1142344'S-PeCS NO 

PCB-lIB 23'44'5-PeCB 36.2 

PCB-12323'44'5'-PeCB NO 

peB-12633'44'S-PeCB NO 

PCB-156/IS7233'44'S/233'44'S'-HxCB NO 

PCB-16723'44'55'-H)(CB NO 

PCB-16933'44'5s'-HxCB NO 

PCB-189233'44'55'-HpCB NO 

TEQs (WHO MlH) 

ND"'O 0.00109 

ND=O.sxDL 0.659 

" .11 ANALYTICAL PERSPECTIVES 

Laboratory Data 

Air Project No.: 

1 Sample 10. 

ac Balch No.: 

DL EMPC 

pg pg 

10.9 

10.7 

14.7 

8.5 

8.3 

8.64 

14.6 

10.9 

14.9 

13.1 

0.00153 

0.659 

2714 Exchange Drive T: 910 794-1613 

Wilmington F: 910 794-3919 

North Carolina 2840S Info@ultratrace.com 

USA www.ultratrace.com 

Method HR-PCB 

P2196 Date Received- 29-Apr-l0 

P2196_7753_PCB_OOI Date Extracted: 6-May-l0 

7753 Date Analyzed: 20-May-l0 

Qualifier Standard Recovery 

% 

ES PCB-' 73.4 

ES PCB-3 80.3 

J ES PCB-4 80.3 

ES PCB-1S 90 

B ES PCB-19 82 

ES PCB-37 90.9 

ES PCB~54 87.2 

C ES PCB-77 86.9 

ES PCB-81 88.5 

ES PCB-104 89 

ES PCB-105 91 

ES PCB-114 67.6 

ES PCB-118 87.1 

ES PCB-123 92.3 

ES PCB-126 88 

ES PCB-153 88.5 

ES PCB-155 93.5 

ES PCB-I56/IS7 89.9 

ES PCB-167 93.3 

ES PCB-169 88.4 

ES PCB-HO 100 

ES PCB-180 98 

ES PCB-188 89.8 

ES PCB-1a9 97.4 

ES PCB-202 90 

ES PCB-20s 97.2 

ES PCB-2OO 93.4 

ES PCB-208 98.9 

ES PCB-209 90.5 

SfSS PCB-28 92.6 

SfSS PCB-11t 93.4 

CS/SS PCB-H8 94.7 

AP PCB 2010 Rev. A 
Sample 10: Run One 

Client Data Sample Data 

Name: AirNova, Inc. Matrix: 

Project 10. 3333 Unil4 WeighWolume: 

Dale Collected: 20-Apr-10 

Analyte Cone. 

pg 

PCB-77 33'44'-TeCB 162 

PCB-81344'5-TeCB NO 

PCB-IDs 233"44'·PeCB 64.' 

PCB-114 2344'5~PeCB NO 

PCB-lIB 23'44'5-PeCB 173 

PCB-12323'44'5'-PeCB NO 

PCB-12633'44'5-PeCS NO 

PCB-156/1S7 233'44'5/233'44 'S'-HxCB NO 

PCB-16723'44'5S"-HxCB NO 

PCB·16933'44'55'-HxCB NO 

PCB-189233'44'5S'-HpC8 NO 

TEQs (WHO MfH) 

NO = 0 0.00876 

ND=0.5xDL 0.913 

" .11 ANALYTICAL. PERSPECTIVES 

Laboratory Oata 

Air Project No_: 

1 Sample 10: 

QC Balch No.: 

0' EMPC 

PO pg 

14.9 

9_55 

9.07 

11.7 

20.2 

15.2 

21-1 

17.6 

0.00676 

0.913 

2714 Exchange Drive T: 910 794-1613 

Wilmington F: 910 794-3919 

North Carolina 28405 info@ultratrace.com 

USA www.ultrntrace.com 

Method HR-PCB 

P2196 Date Received: 29-Apr-l0 

P2196_7753_PCB_002 Dale Exlrac:ed: 6_May_10 

7753 Date Analyzed: 20-May-10 

Qualifier Standard Recovery 

% 

J ES PCB-1 73.3 

ESPCB-3 79.3 

ES PCB-4 80.6 

ES PCB-IS 91 

• ES PCB-19 83.1 

ES PCB-37 92.4 

ES PCB-54 89.7 

C ES PCB-77 88.2 

ES PCB-81 88.3 

ES PCB-l04 96.5 

ES PCB-10S 90.' 

ES PC6-114 66.4 

ES PCB-116 90.3 

ES PCB-123 92.6 

ES PCB-126 87.2 

ES PCB-153 92.3 

ES PCB-155 97.3 

ES PCB-156/157 90.8 

ES PCB-167 93 

ES PCB-169 84.8 

ES PCB-170 102 

ES PCB-180 103 

ES PCB-1BB 92.6 

ES PCB-1a9 100 

ES PCB-202 91.2 

ES PCB-20S ,. 

ES PCB-206 98.3 

ES PCB-208 101 

ES PCB-209 95.7 

SISS PCB-28 97.7 

CS/SS PCB-111 97.5 

SISS PCB-178 95.4 

AP PCB 2010 Rev. A 
Sample 10: Run Two 

Client Data Sample Data 

Name: AirNova, Inc. Matrix: 

Project 10: 3333 Unit4 WeighWolume: 

Date Collected: 21-Apr-l0 

Analyte Conc. 

pg 

PCB-77 33'44'-TeCB 12.8 

PCB-81344'S-TeCB NO 

PCB-IDS 233'44'-PeCB 68.6 

PCB-1142344'S-PeCS NO 

PCB-lIB 23'44'5-PeCB 177 

PCB-12323'44'5'-PeCB NO 

PCB-12633'44'5-PeCB NO 

PCB-15611S7233'44'51233"44'5'-HxCB 22.9 

PCB-t6723'44'55'-HxCB NO 

PCB-t6933'44'S5'-HxCB NO 

PCB-189233'44'S5'-HpCB NO 

TEQs (WHO MIH) 

NO = 0 0.00933 

ND=O.5xDL 0.467 

pp 

.11 ANALYTICAL PERSPECTIVES 

Laboratory Data 

Air Project No.: 

1 Sample 10: 

QC Batch No.: 

DL EMPC 

PO pg 

4.64 

4.5 

4.34 

6.15 

7.54 

9.93 

8.21 

0.00933 

0.467 

2714 Exchange Drive T: 910 794-1613 

Wilmington F: 910 794-3919 

North Carolina 28405 info@ultratrace.com 

USA www.ullratrace.com 

Method HR-PCB 

P2196 Date Received: 29-Apr-l0 

P21963753_PCB_003 Date Extracted: 6-May-tO 

7753 Dale Analyzed: 20-May-l0 

Qualifier Standard Recovery 

% 

J ES PCB-l 65.9 

ESPCB-3 79.7 

ES PCB-4 808 

ES PCB-IS 90.8 

B ES PCB-19 82 

ES peS-37 91.9 

ES PCB-54 84.4 

JC ES PCB-77 86.6 

ES PCB-81 87.3 

ES PCB-1M 95 

ES PCB-lOS 88.9 

ES PCB-114 87.9 

ES PCB-118 89.7 

ES PCB-123 91.8 

ES PCB-126 85 

ES PCB-153 91.8 

ES PCB-155 97.4 

ES PCB-156/157 87.5 

ES PCB-16l 89.4 

ES PCB-169 85.9 

ES PCB-170 102 

ES PCB-laO 103 

ES PCB-18S 90.3 

ES PCB-1a9 101 

ES PCB-202 89.2 

ES PCB-20S 98.1 

ES PCB-20e 98.7 

ES PCB-20B 101 

ES PCB-20e 93.5 

SfSS PCB-28 96.3 

CS/SS PCB-111 95.2 

CS/SS PCB-178 96.2 

AP PCB 2010 Rev. A 
Sample 10: Run Three 

Client Data Sample Data 

Name: AirNova, Inc_ Matrix: 

Project 10: 3333 Unit4 WeighWolume: 

Dale Collected: 22-Apr-l0 

Analyte Conc. 

PCB-77 33'44'-TeCB 18.2 

PCB-al 344'5-TeCB NO 

PCB-IDS 233'44'-PeCB 94 

PCB-1142344'S-PeCS NO 

PCB-1t B 23"44'5-PeCB 242 

PCB-12323"44'S'-PeCB NO 

peB-12633'44'S-PeCB NO 

PCB-156/1S7233'44'S/233'44'5'-HxCB 32_5 

PCB-16l23'44'55'-HxCB NO 

PCB-16933'44'55'-HxCB NO 

PCB~189 233'44'55'-HpCB NO 

TEQs (WHO M/H) 

NO = 0 0.0129 

NO=O.5xOL 0.489 

us 

.11 ANALYTICAL PERSPECTIVES 

Laboratory Data 

Air Project No_: 

1 Sample 10_ 

QC Balch No.: 

OL EMPC 

pg pg 

7.67 

5.01 

4.78 

6.29 

7.48 

10.7 

8.47 

0.0129 

0.489 

2714 Exchange Drive T: 910 794-1613 

Wilmington F: 910 794-3919 

North Carouna 28405 info@ultratrace.com 

USA www.ultratrace.com 

Method HR-PCB 

P2196 Date Received. 29-Apr-l0 

P2196J7S3_PCB_004 Date Extracted: 6-May-l0 

7753 Date Analyzed: 20-MaHO 

Qualifier Standard Recovery 

% 

J ES PCB-1 67.8 

ES peS-3 80_6 

ES PCB-4 82.2 

ES PCB-IS 97_1 

ES PCB-19 85.7 

ES PCB-37 94 

ES PCB-54 81.8 

JC ES PCB-77 88_3 

ES PCB-Sl 90.4 

ES PCB-104 99 

ES PCB-105 91.1 

ES PCB-114 88.8 

ES PCB-118 90.6 

ES PCB-123 92.7 

ES PCB-126 B5 

ES PCB-153 96.4 

ES PCB-155 102 

ES PCB-156/157 90.4 

ES PCB-167 93.6 

ES PCB-169 84.1 

ES PCB-170 107 

ES PCB-180 104 

ES PCB-188 94.2 

ES PCB-189 101 

ES PCB-202 94.6 

ES PCB-205 98.1 

ES PCB-206 97.7 

ES PCB-208 102 

ES PCB-209 94 

CS/SS PCB-28 93.7 

CSISS PCB-111 93.6 

CS/SS PCB-17S 92.3 

AP PCB 2010 Rev. A 
Appendix C 

Emission Calculations 
Unit NO.1 
Spruance Genco, LLC 

Richmond, Virginia 

Project No. 3333 

April 16, 2010 

Unit No.1 

Run No.1 

Coal Analysis for F Factor Calculation 

F FACTOR CALCULATION 

INPUT % H= 4.82 Hydrogen Content (%) 

INPUT %c= 76.49 Carbon Content (%) 

INPUT %N= 1.4 Nitrogen Content (%) 

INPUT %0= 4.54 Oxygen Content (%) 

INPUT %s= 0.69 Sulfur Content (%) 

INPUT GCV= 13494 Gross Calorific Value (Btu/lb) 

Fd = 10'6' [(3.64'%H) + (1.53'%C) + (0.57'%S) + (0.14'%N) - (0.46'%02))1 GCV 

Fd = 9862 scf/MMBtu 
Spruance Genco, LLC 

Richmond, Virginia 

Project No. 3333 

April 19, 2010 

Unit No.3 

Run No.2 

Coal Analysis for F Factor Calculation 

F FACTOR CALCULATION 

INPUT %H= 5.04 Hydrogen Content (%) 

INPUT %c= 76.71 Carbon Content (%) 

INPUT %N= 1.56 Nitrogen Content (%) 

INPUT %0= 6.35 Oxygen Content (%) 

INPUT %8= 1.05 Sulfur Content (%) 

INPUT GCV= 13696 Gross Calorific Value (Btu/lb) 

Fd = 10"6'" [(3_64"%H) + (1.53*%C) + (0,57"'%S) + (O.14*%N) - (0.46"%02)] /GCV 

Fd = 9755 scf/MMBtu 
Spruance Genco, LLC 

Richmond, Virginia 

Project No, 3333 

April 19, 2010 

Unit No.3 

Run No.3 

Coal Analysis for F Factor Calculation 

F FACTOR CALCULATION 

INPUT % H = 5.12 Hydrogen Content (%) 

INPUT %c= 78.65 Carbon Content (%) 

INPUT %N= 1.67 Nitrogen Content (%) 

INPUT %0= 5.68 Oxygen Content (%) 

INPUT %s= 1 04 Sulfur Content (%) 

INPUT GCV= 13902 Gross Calorific Value (Btu/lb) 

Fd = 10116'" ((3 64~O/oH) + (1.S3*%C) + (O.57*%S) + (O.14*%N) - (0-46·%02)]1 GCV 

Fd = 9868 scf/MMBtu 
Client 

Project No. 

Test Location 

Test Date 

Spruance Genco. LLC 

3333 

Unit #1 

04/12110 

Parameter: Oxygen 

Instrument Soan f% 02)' 22.03 

Actual Calibration Gas Value (% 02): 

Anal\:::zer Calibration ResQ.onse (% 021: 

Analvzer Calibration Error 1% Span): 

Zero Sy:stem Calibration Gas 

A{2Q.arent Init. S:iS. Init. Sk:s. Final S\:::s. Final S:k:s. 

~ Calib Cal. Bigs. Calib. Cal. Bigs. 

Run Cone, ResDons.e (% span) ResQ.Onse f% s{2an) 

1 4.80 0.13 0.01 0.04 0.23 

2 4.96 0.04 0.23 0.06 0.32 

3 4.27 0.06 0.32 0.10 0.50 

4 0.00 0.10 0.50 0.00 0.05 

5 0.00 0.00 0.05 0.00 0.05 

6 0.00 0,00 0.05 0.00 0.05 

7 0.00 0.00 0.05 0.00 0.05 

8 0.00 0.00 0.05 0.00 0.05 

9 0.00 0.00 0.05 0.00 0.05 

10 0.00 0.00 0.05 0,00 0.05 

11 0.00 000 0.05 0.00 0.05 

12 0.00 0.00 0.05 0.00 0.05 

AirNova, Inc. Page 1 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Ang/wr Calib. Gases. UQ.scale 

zero low mid high S\:::s. Cal. Gas 

0.00 NIA 11.90 22.03 11.90 

-0.01 NIA 11.70 21.79 11.70 

-0.05 0.00 -0,91 -1.11 

Ugscale Sy:stem Calibration Gas 

Ca/ib. Init. S:I:§. Init S\:::s. Final S:iS. Final S!!s. Calib. 

Drift Calib. Cal. Bias Calib. Cal. Bias Drift """"'" ~ 

(% span) ReSQ.onse f% span! Response f% sQ.anJ (% span) Cone. 

-0.41 11.80 0.45 11.70 0.00 -0.45 4.81 

0.09 11.70 0.00 11.70 0.00 0.00 5.02 

0.18 11.70 0.00 11.93 1.04 1.04 4.25 

-0.45 11.93 1.04 0.00 -53,11 -54.15 ·0.10 

0.00 0.00 -53.11 0.00 -53.11 0.00 ERR 

0.00 0,00 -53.11 0.00 -53.11 0.00 ERR 

0.00 0.00 -53.11 0.00 -53.11 0.00 ERR 

0.00 0.00 -53.11 0.00 -53.11 0.00 ERR 

0.00 0.00 -53,11 0.00 -53.11 0.00 ERR 

0.00 0.00 -53.11 0.00 -53,11 0.00 ERR 

0.00 0.00 -53.11 0.00 -53.11 0.00 ERR 

0.00 0.00 -53.11 0.00 -53.11 0.00 ERR 
o 

Client 

Project No. 

Test Location 

Test Date 

Spl1Jance Genco, LLC 

3333 

Unit #1 

04112110 

Parameter: Carbon Dioxide 

Instrument Span f% C02): 22.28 

Actual Calibration Gas Value f% C021: 

Analvzer Calibration Response f% C02): 

Analyzer Calibration Error f% Span): 

Zero Sy:§tem Calibration Gas 

AQQarent Init, Sys Init. Sys. Final Sys. Final $\,,8. 

Stack Calib. Cat Bias Calib. Cal. Bias 

Run Cone. Response t% span) Response t% soan) 

1 15.00 0.00 0.10 -0.12 -0.49 

2 14.55 -0.12 -0.49 0.00 0.04 

3 14.70 0.00 0.04 -0.12 -0.49 

4 0.00 -0.12 -0.49 0.00 0.04 

5 0.00 0.00 004 0.00 0.04 

6 0.00 0.00 0.04 0.00 0.04 

7 0.00 0.00 004 0.00 0.04 

8 0.00 0.00 0.04 0.00 0.04 

g 0.00 0.00 0.04 0.00 0.04 

10 0.00 0.00 0.04 0.00 0.04 

11 0.00 0.00 0.04 0.00 0.04 

12 0.00 0.00 0.04 0.00 0.04 

AirNova, Inc. Page 2 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

An~l~zer Calib. Gases Uuscale 

zero low mid high SI:§:. Qal. Gas 

0.00 N/A 12.39 22.28 12.39 

-0.01 N/A 12.46 21.98 12.46 

-0.04 0.00 0,31 -1.35 

U[!scale Sy:stem Calibration Gas 

GaliP. Init. Sys. fnit Sys Final SjI's. Final Sys, Galib. Actua/ 

Drift Calib. Cal. Bias Calib. Cal, Bias Drift Stack 

t% span) Response t% span) Response t% span) t% span) Cone. 

-0.54 12.35 -0.49 12.33 -0.58 -0.09 15.05 

0.54 12.33 -0.58 12.33 -0.58 0.00 14.61 

-0.54 12.33 -0.58 12.45 -0.04 0.54 14.69 

0.54 12.45 -0.04 0.00 -55.92 -55.88 0.12 

0.00 0.00 -55.92 0.00 -55.92 0.00 ERR 

0.00 0.00 -55.92 0.00 -55.92 0.00 ERR 

0.00 0.00 -55.92 0.00 -55.92 0.00 ERR 

0.00 0.00 -55.92 0.00 -55.92 0.00 ERR 

0.00 0.00 -55.92 0.00 -55.92 0.00 ERR 

0.00 0.00 -55.92 0.00 -55.92 0.00 ERR 

0.00 0.00 -55.92 0.00 -55.92 0.00 ERR 

0.00 0.00 -55.92 0.00 -55.92 0.00 ERR 
o 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit #1 

04/12/10 

Parameter: Sulfur Dioxide 

Instrument Span (ppmV 8021: 443 

Actual Calibration Gas Value (Ppm V S021: 

Analyzer Calibration Response (ppm V S02): 

Analyzer Calibration Error (% Soan): 

Zero S~stem Calibration Gas 

A(lQarent Init. S"-S. Init. S!!:S:. Final S'iS Final S\:,:s. 

Stack Calib. Cal. Bias Calib Cal. Bias 

Run Conc. Response (% span) Response (% span) 

1 32.2 -0.2 0.00 2.4 0.60 

2 21.0 2.A 0.60 -2.4 -0.50 

3 19.6 -2.4 -0.50 -2.4 -050 

4 0.0 -2.4 -0.50 0.0 0.05 

5 0.0 0.0 0.05 0.0 0.05 

6 0.0 0.0 0.05 0.0 0.05 

7 0.0 0.0 0.05 0.0 0.05 

8 0.0 0.0 0.05 0.0 0.05 

9 0.0 0.0 0.05 0.0 0.05 

10 0.0 0.0 0.05 0.0 0.05 

11 0.0 0.0 0.05 0.0 0.05 

12 0.0 0.0 0.05 00 0.05 

AirNova, Inc. Page 3 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal'izer Calib. Gasf:S: UQ.sca/e 

zero low mid high S!:::,:s. e.g/. Gas 

0.0 0.0 222.0 443.0 222.0 

-0.2 0.0 224.6 441,0 224.6 

-0,05 0.00 0.59 -0.46 

URscale Sllstem Calibration Gas 

Calib. Init. ~vs. IniI. S,,-s. Final S,,-s. FinaIS~. Cafib, Actual 

Drift Calib. Cal- Bias Calib. Cal. Bias Drift Stack 

(% span) Response (% span) Response (% span! (% span) Conc. 

0.60 224.6 0.00 222.2 -0.55 -0.55 31.1 

-1.10 222.2 -0.55 222.2 -0.55 0.00 21.0 

0.00 222.2 -0.55 224.6 0.00 0.55 21.6 

0.55 224.6 0.00 0.0 -50.70 -50.70 2.' 

0.00 0.0 -50.70 0.0 -50.70 0.00 ERR 

0.00 0.0 -50.70 0.0 -50.70 0.00 ERR 

000 0.0 -50.70 0.0 -50.70 0.00 ERR 

0.00 0.0 -50.70 0.0 -50.70 0.00 ERR 

0.00 0.0 -50.70 00 -50.70 0.00 ERR 

0.00 0.0 -50.70 0.0 -50.70 0.00 ERR 

0.00 0.0 -50.70 0.0 -50.70 0.00 ERR 

0.00 0.0 -50.70 0.0 -50.70 0.00 ERR 
o 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit #1 

04/12/10 

Parameter: Nitrogen Oxides (as N02) 

Run 

1 

2 

3 

4 

5 

6 

7 

a 

g 

10 

11 

12 

Instrument Span (ppmV NOxJ: 502.9 

Actual Calibration Gas Value (opmV NOx)'-

Analvzer Calibration Response (ppm V NOx): 

Analvzer Calibration Error (% Span): 

Zero Sllstem Calibration Gas 

AgQarent !nit S'iS. Inif. S!!s. Final :S:l!s. Final S'lS, 

Stack Galib. Cal. Bias Galib. Cal. Bias 

Cone. Response (% span) Response t% span) 

211.0 0.3 0.00 0.3 0.00 

210.5 0.3 0_00 -0.3 -0.11 

218.8 -0.3 -0.11 1.2 0.19 

0.0 1.2 0.19 0.0 -0.05 

00 0.0 -0,05 0.0 -0.05 

0.0 00 -0.05 0.0 -0.05 

0.0 0.0 -0.05 0.0 -0,05 

0.0 0.0 -0.05 0.0 -0.05 

0.0 0.0 -005 0.0 -0.05 

00 0.0 -0.05 00 -0.05 

0.0 0.0 -0.05 0.0 -0.05 

0.0 00 -0.05 0.0 -0.05 

AirNova, Inc. Page 4 

EPA Method Be Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal'izer Calib. Gg§es UgS!;.g/e 

zero low mid high ,s'is. Cal. Gas 

0.0 0.0 246.8 502.9 246.8 

0.3 0.0 245.5 501.7 245.5 

0.05 0.00 -0.27 -0.25 

U(;!scale Sllstem Calibration Gas 

CatiP. Init· S'i5. !nit S'ls. Final S'i,'l. Final S'iS. Galib. ~ 

Drift Galib. Cal. Bias Galib. Cal. Bias Drifl Stack 

(% span) Response (% span) Response (% span) (% span) Cone. 

0_00 245.7 0.05 246.5 0.21 0.16 211.5 

-0.11 246.5 0.21 246.5 0.21 0.00 210.7 

0,30 246.5 0.21 249.0 0.69 0.48 217.9 

-0.24 249.0 0_69 0.0 -48.81 -49.50 -1.2 

0.00 0.0 -48.81 0.0 -48.81 0.00 ERR 

0.00 0.0 -48.81 0.0 -48.81 0.00 ERR 

0.00 0.0 -48_81 0.0 -48.81 0.00 ERR 

0_00 0.0 -48.81 0.0 -48.81 0_00 ERR 

0_00 0.0 -48.81 00 -48_81 0.00 ERR 

0.00 00 -48.81 0.0 -48.B1 0.00 ERR 

0.00 0.0 -48.81 0.0 -48.81 0.00 ERR 

0.00 0.0 -48.81 0.0 -48.81 0.00 ERR 
3333-HCI-HF-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

t= 

Os = 

As= 

Cp = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

CF = 

CF = 

102] 

IC02] 

IN2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and 26A 

(Flows, 02/C02, H20,and HCI/HF) 

Spruance Genco, LLC 

3333 

Unit No.1 

One 

04/12/10 

0840-1149 

334.2 cc 

Emission Data 

120.514 dcf 

-050 in. H20 

30.32 in. Hg 

30.28 in. Hg 

29.92 In Hg 

o 7014 in H20 1\ 5 

1.243 in. H20 

538.2 R 

659.0 R 

527.7 R 

0.248 in. 

0.000335 sq. ft. 

0.97 

180 min. 

10.300 ft 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sElmpling time 

Diameter of stack 

83,323 sq. ft, Cross sectional area of stack 

0,84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)"'(inHg)]".S}/[s"'R"inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.fUml 

0.0026688 in.Hg-cf/ml-R 

9862 scf/MMBtu 

9.461 E-08 Ib/dscf I ppmVd 

5.192E-08 Ib/dscf I ppmVd 

Instrumental Data 

4,81 %-dry 

15,05 %-dry 

80.14 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCI 

Conversion Factor for HF 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, llC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y 'Vm ' (Pb + dH/13.6) ITm 

Vmstd = 116.500 dsc! 

330 dscm 

Unit No.1 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw( std) = K2 " Vic 

Vw(std) = 15.731 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 0.119 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32"%02) + (2S"%N2))' (1-Bws) I + (1S'Bws) 

Ms = 29.10 Ib/lbmoJe 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP) " (Ts/Ps"Ms)A5 

Vs = 43.55 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs ., As 

Qa = 217732.6 efm 

6166.2 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa" (TstdlTs)" (Ps/Pstd)' (1-Bws) 

Qstd = 155486.4 dscfm 

4403.4 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test location 

Test Run 

Calculations (cont.) 

8) Hydrogen Chloride Concentration and Emissions 

Unit No.1 

One 

M[HCI[ = M[CI-[(mg) • MW[HCI[(mg/mmol) 1 MW[CI-](mg/mmol) 

Page 3 

C[HCI] = (M[HCI](mg) " 2.20SE-06(lb/mg) • 21.8S(scf"inHgllbmol·R) • K1 • 10'6) 1 (MW[HCI](Ib/lbmol) • Vmstd(d 

C[HCI](@corr. 02) = C[HCI](ppmV)" [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HCI] = M[HCI](m9)' Qstd(dscfm)' (2.20SE-06)(lb/mg)· 60(min/hr) 1 Vmstd(dscD 

E[HCI] = C[HCI](ppmV)' Fd" CF(HCI)' (20.9/(20.9-%02)) 

M[HCI] = 

C[HCI] = 

C[HCI] = 

E[HCI] = 

E[HCI] = 

S.99 mg 

1.199 ppmV 

1.03S ppmV 

1.0S8 Ib/hr 

1.4SE-03 Ib/MMBtu 

9) Hydrogen Fluoride Concentration and Emissions 

C[HF] = M[HF](mg) 1 Vmstd(dscm) 

(@ 7.0 % 02) 

C[HF] = (M[HF](mg)' 2.20SE-06(lb/mg)· 21.8S(scf"inHg/lbmol·R)· K1 "10'6) 1 (MW[HF](lb/lbmol)' Vmstd(dsc 

C[HF](@corr. 02) = C[HF](mg/dscm)' [(20.9-corrected 02) 1 (20 9-actual %02)] 

E[HF] = C[HF](mg/dscm) " Qstd(dscmm) " (2.20SE-06)(lb/mg) • 60(min/hr) 

E[HF] = C[HF](ppmV)' Fd" CF(HF)' (20.9/(20.9-%02)) 

M[HF] = 

C[HF] = 

C[HF] = 

C[HF] = 

E[HF] = 

E[HF] = 

10) Isokinecity, I. 

O.soo mg 

0.152 mg/dscm 

0.182 ppmV 

0.1S7 ppmV (@ 

0.088 Ib/hr 

1.21 E-04 Ib/MMBtu 

7.0 

% 1 = (100·Ts·(K3·Vlc+(Vm·YlTm)(Pb+dH/13.6)))/(60·t·Ps-Vs·An) 

% I = 103.4 

% 02) 
3333-HCI-HF-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

t = 

Ds = 

As= 

Cp= 

Kp= 

K1 = 

K2= 

K3= 

Fd = 

CF = 

CF = 

[02J 

[C02J 

[N2J 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and 26A 

(Ftows, 021C02, H20,and HCIIHF) 

Spruance Genco, LLC 

3333 

Unit No.1 

Two 

04112110 

1215-1524 

354.1 cc 

122.346 dcf 

Emission Data 

~O.50 in. H20 

30.35 in. Hg 

30,31 in. Hg 

2992 in. Hg 

06887 in. H20 ",5 

1.253 in. H20 

561.5 R 

657.8 R 

527.7 R 

0.248 in. 

0.000335 sq. ft. 

0.97 

180 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometnc pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge readmg 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]1\.5}/[s*R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.ftlml 

00026688 in.Hg-cf/ml-R 

9755 scf/MMBtu 

9.461 E-08 Ib/dscf I ppmVd 

5.192E-08 Ibldscf I ppmVd 

Instrumental Data 

5.02 %-dry 

14.61 %-dry 

80.37 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCI 

Conversion Factor for HF 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm * (Pb + dH/13.6) 'Tm 

Vmstd = 113.488 dscf 

3.21 dscm 

Unit NO.1 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 'Vie 

Vw(std) = 16667 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.128 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (1-Bws) ) + (18'Bws) 

Ms= 28.93 Ibllbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP) , (TsIPs'Msj'.5 

Vs = 42.83 fps 

6) Average actual stack gas volumetric flowrate, Oa. 

Qa = 60 sec/min * Vs * As 

Qa = 214130.8 cfm 

6064.2 cmm 

7) Average stack gas dry volumetric flowrate, Ostd. 

Qstd = Qa' (Tstd/Ts)' (PsIPstd)' (1-Bws) 

Qstd = 151754.6 dscfm 

4297.7 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Hydrogen Chloride Concentration and Emissions 

Unit No.1 

Two 

M[HCI] = M[CI-](mg) • MW[HCI](mg/mmol) 1 MW[CI-](mg/mmol) 

Page 3 

C[HCI] = (M[HCI](mg) • 2.205E-06(lb/mg) • 21.85(scf·inHgllbmol·R) • K1 • 10'6) 1 (MW[HCI](Ib/lbmol) • Vmstd(d 

C[HCI](@corr 02) = C[HCI](ppmV)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HCI] = M[HCI](mg) • Ostd(dscfm) • (2.205E-06)(lb/mg) • 60(min/hr) 1 Vmstd(dscD 

E[HCI] = C[HCI](ppmV)' Fd' CF(HCI)' (20.9/(20.9-%02)) 

M[HCI] = 5.98 mg 

C[HCI] = 1.228 ppmV 

C[HCI] = 1.075 ppmV (@ 7.0 % 02) 

E[HCI] = 1.058 Ib/hr 

E[HCI] = 1.49E-03 Ib/MMBtu 

9) Hydrogen Fluoride Concentration and Emissions 

C[HF] = M[HF](mg) 1 Vmstd(dscm) 

C[HF] = (M[HF](mg) • 2.205E-06(lb/mg) • 21.85(scf'inHg/lbmol·R) 'K1 • 10'6) 1 (MW[HF](lb/lbmol) • Vmstd(dsc 

C[HF](@corr. 02) = C[HF](mg/dscm)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HF] = C[HF](mg/dscm)' Qstd(dscmm)' (2.205E-06)(lb/mg)' 60(min/hr) 

E[HF] = C[HF](ppmV)' Fd' CF(HF)' (20 9/(20.9-%02)) 

< M[HF] = 

< C[HF] = 

< C[HF] = 

< C[HF] = 

< E[HF] = 

< E[HF] = 

10) Isokinecity, I. 

0.040 mg 

o 012 mg/dscm 

0015 ppmV 

0.013 ppmV (@ 

0.007 Ib/hr 

9.98E-06 Ib/MMBtu 

7.0 

% 1 = (100·Ts·(K3'Vlc+(Vm'Y/Tm)(Pb+dH/13.6)))/(60't'Ps'Vs·An) 

% I = 103.2 

% 02) 
3333-HCI-HF-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

T5 = 

Tstd= 

Dn = 

An = 

y= 

t= 

Ds= 

As= 

Cp= 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

CF= 

CF= 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and 26A 

(Flows, 02/C02, H20,and HCI/HF) 

Spruance Genco, LLC 

3333 

Unit No.1 

Three 

04/12/10 

1555-1904 

368.9 cc 

123.001 dcf 

Emission Data 

~O.50 in. H20 

30.28 in. Hg 

30.24 in. Hg 

29.92 in. Hg 

0.6670 In. H20 11.5 

1.176 in. H20 

563.8 R 

6570 R 

527.7 R 

0.248 in. 

0.000335 sq. ft. 

0.97 

180 min. 

10.300 ft. 

83.323 sq. ft. 

084 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

Cross sectional area of stack 

Pltot tube coefficient 

85.49 ft[(lb/lbmol)'(inHg)]'.5)/[s'R'inH20] P,tot tube constant 

17.637 Rlin.Hg 

0047070 cU.fUml 

0.0026688 in.Hg-cf/ml-R 

9868 scf/MMBtu 

9.461 E-08 Ib/dscf I ppmVd 

5.192E-08 Ib/dscf! ppmVd 

Instrumental Data 

425 %-dry 

14.69 %-dry 

81.06 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for Hel 

Conversion Factor for HF 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1"" Y ~ Vm * (Pb + dH/13.6) / Tm 

Vmstd = 113.341 dscf 

3.21 dscm 

Unit No.1 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 'Vie 

Vw(std) = 17.364 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

8ws = 0.133 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (1-Bws) I + (18'Bws) 

Ms= 28.86 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp , Cp , (dP) , (Ts/Ps'Ms)'.5 

Vs = 41.56 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min"" Vs '" As 

Oa = 207786.9 cfm 

5884.5 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa' (Tstdrrs)' (Ps/Pstd)' (1-Bws) 

Ostd = 146278.1 dscfm 

4142.6 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Hydrogen Chloride Concentration and Emissions 

Unit No.1 

Three 

M[HCI] = M[CI-](mg) , MW[HCI](mg/mmol) 1 MW[CI-](mg/mmol) 

Page 3 

C[HCI] = (M[HCI](mg)' 2.205E-06(lb/mg)' 21.85(scf'inHg/lbmol'R)' K1 '10'6) 1 (MW[HCI](lbllbmol)' Vmstd(d 

C[HCI](@corr. 02) = C[HCI](ppmV)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HCI] = M[HCI](mg)' Qstd(dscfm)' (2.205E-06)(lb/mg)" 60(min/hr) 1 Vmstd(dscf) 

E[HCI] = C[HCI](ppmV) , Fd ' CF(HCI) • (20.9/(20.9-%02)) 

M[HCI]= 10.00 mg 

C[HCI] = 2.057 ppmV 

C[HCI] = 1.717 ppmV (@ 7.0 % 02) 

E[HCI] = 1.7071b/hr 

E[HCI]= 2.41E-03Ib/MMBtu 

9) Hydrogen Fluoride Concentration and Emissions 

C[HF] = M[HF](mg) 1 Vmstd(dscm) 

C[HF] = (M[HF](mg) '2.205E-06(lb/mg) • 21.85(scf·inHg/lbmol·R) • K1 • 10'6) 1 (MW[HF](lb/lbmol) • Vmstd(dsc 

C[HF](@corr. 02) = C[HF](mg/dscm)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HF] = C[HF](mg/dscm)' Qstd(dscmm)' (2.205E-06)(lb/mg)' 60(min/hr) 

E[HF] = C[HF](ppmV)' Fd' CF(HF)' (20.9/(20.9-%02)) 

< M[HF] = 

< C[HF] = 

< C[HF] = 

< C[HF] = 

< E[HF] = 

< E[HF] = 

10) Isokinecity, I. 

0.040 mg 

0.012 mg/dscm 

0015 ppmV 

0.013 ppmV ( @ 

0007 Ib/hr 

9.B4E-OB Ib/MMBtu 

7.0 

% I = (100'Ts'(K3'Vlc+(Vm'YlTm)(Pb+dH/13.6)))/(60't"Ps'Vs·An) 

%1= 106.9 

% 02) 
Client 

Project No. 

Test Location 

Fuel Type 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

INPUT Tstd= 

INPUT Y = 

INPUT t = 

INPUT Dn = 

An = 

INPUT Ds = 

As = 

INPUT 

INPUT 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

INPUT [02] 

INPUT [C02] 

[N2] 

INPUT [NOx] 

INPUT [S02] 

AirNova, Inc. Page 1 of3 

EPA Methods 1, 2, 3A, 4, 6 and 7E 

(Flows, 02/C02, H20, S02 and NOx) 

Spruance Genco, LLC 

3333 

Unit No. 

Coal 

One 

04/12110 

0840-1149 

Emission Data 

334.2 cc 

120.514 dcf 

-0.50 in. H2O 

30.32 in. Hg 

30.28 tn. Hg 

2992 in. Hg 

0.7014 in. H20" 5 

1.24 in. H2O 

538.2 R 

659.0 R 

527.7 R 

097 

180 min. 

0.248 in. 

0.000335 sq. ft. 

10.300 ft. 

83323 sq ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coeffir.ient 

85.49 ft[(lb/lbmolt(inHg)]".5}f[s*R'"inH20] 

17637 Rfin.Hg constant 

0.047070 cu.ftlml 

0.0026688 in.Hg-cf/ml-R 

9862 scf/MMBtu 

Instrumental Data 

4.81 %-dry 

1505 %-dry 

80.14 %-dry 

211.5 ppmV-dry 

31.1 ppmV-dry 

constant Pitot tube constant 

constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Nitrogen Oxides concentration 

Sulfur Dioxide concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1" Y "Vm ;0 (Pb + dH/13.6) / Tm 

Vmstd = 116.500 dscf 

3.299 dscm 

Unit No.1 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw{std) = 15.731 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 0.1190 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [{(44"%C02) + (32"%02) + (28;O%N2))'" (1-Bws) 1 + (18;OBws) 

Ms = 29101 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp" Cp " (dP) " (Ts/Ps*Ms)".5 

Vs = 43.552 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min ;0 Vs .., As 

Qa = 217732.6 cfm 

6166.2 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa ~ (Tstd/Ts) * (Ps/Pstd) * (1-Bws) 

Qstd = 155486.4 dscfm 

4403.4 dscmm 

Page 2 of 3 
Client 

Project No. 

8pruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No. 

One 

Page 3 of3 

9) Nitrogen Oxides concentrations and emissions 

Carr. C[NOx] = ((20.9-02% corr. value)/(20.9-actual avg. 02% value))*Avg. raw NOx value 

E[NOx] = (C[NOxl~Mol Wt[NOx]*60(min/hr)*Qstd(dscfm»/(Molar Vol. alr*10"6) 

E[NOx Ib/MMBtu] = Cd;O Fd * (20.9/(20.9-actual 02%)) 

C[NOx] = 211 5 ppmVd 

C[NOx] = 182.7 ppmVd corrected to 7 % 02 

Mol. Wt. [NOx]= 46.01 Ib/lb-mole 

Molar vol air= 

E[NOx[ = 

Cony Factor. 

E[NOx[ = 

385 scmb-mole @ 

235.80 Ib/hr 

68 

1.194E-07 convert ppmV to Jb/scf NOx 

0.323 Jb/MMBtu 

10) Sulfur Dioxide concentrations and emissions 

def F 

Carr. C[S02] = ((20.9-02% corr. value)/(20.9-actual avg. 02% value))*Avg. raw 802 value 

E(lb/MMBtu) = Cd(lb/scf) ... Fd(scf/MMBtu) * [20.9 I (20.9-% 02)] 

E[S02 Ib/hr] = (C[S02]*Mol Wt[S02]*60(mm/hr)*Qstd(dscfm»/(Molar Vol. air*10"6) 

C[S02] = 31.1 ppmV (dry) Actual Conc. 

C[S02] = 26.9 ppmVd corrected to 7 % 02 

Mol. Wt. [802]= 64.06 Ib/lb-mole 

Molar vol air= 

Cony Factor. 

E[S02[ = 

E[S02[ = 

385 scfllb-mole @ 68 

1 66E-07 convert ppmV to Ib/scf 802 

0.066 JbfMMBtu 

48.28 fb/hr 

def F 
Client 

Project No. 

Test Location 

Fuel Type 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

y= 

t= 

Dn = 

An = 

Ds = 

As= 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[02[ 

[C02J 

[N2J 

[NOxJ 

[S02J 

AirNova, Inc. 

EPA Methods 1, 2, 3A, 4, 6 and 7E 

(Flows, 02/C02, H20, S02 and NOx) 

Spruance Genco, LLC 

3333 

Unit No. 

Coal 

Two 

04/12/10 

1215-1524 

Emission Data 

354.1 cc 

122.346 dcf 

-0.50 in. H20 

30.35 In. Hg 

30.31 in. Hg 

29.92 in. Hg 

0.6887 in. H20 '\5 

1 25 in. H20 

561.5 R 

657.8 R 

527.7 R 

0.97 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

180 min. Duration of sampling time 

0.248 in. Nozzle diameter 

0.000335 sq. ft. Nozzle area 

10.300 ft. Diameter of stack 

83.323 sq. ft Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbflbmol)*(inHg)]".5}/[s·WinH20] 

17.637 Rlin.Hg constant 

Page 1 of 3 

0.047070 cu.fUml constant Pitot tube constant 

0.0026688 in.Hg-cf/ml-R constant 

9755 scf/MMBtu From EPA Reference Method 19 

Instrumental Data 

5.02 %-dry Oxygen concentration 

14.61 %-dry Carbon Dioxide concentration 

80.37 %-dry Nitrogen concentration 

210.7 ppmV-dry Nitrogen Oxides concentration 

21.0 ppmV-dry Sulfur Dioxide concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm * (Pb + dH/13.6) I Tm 

Vmstd = 113.488 dscf 

3.214 dscm 

Unit No. 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 16.667 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd J (Vmstd+Vwstd) 

Bws= 0.1281 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32*%02) + (28*%N2)) * (1-Bws) 1 + (18*Bws) 

Ms = 28.933 Ibf Ibmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp * (dP) • (Ts/Ps*Ms)" 5 

Vs = 42.831 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min· Vs • As 

Qa= 214130.8cfm 

6064.2 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa * (TstdlTs) * (Ps/Pstd);O (1-Bws) 

Qstd = 151754.6 dsefm 

4297.7 dscmm 

Page 2 of 3 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No. 

Two 

Page 3 of 3 

9) Nitrogen Oxides concentrations and emissions 

Corr. C[NOx] = (20.9-02% corr. value)/(20.9-actual avg. 02% value))"Avg. raw NOx value 

EINOx] = (C[NOx]*Mol Wt[NOx]*60(min/hr)*Qstd(dscfm»/(Molar Vol. air*10"6) 

E[NOx Ib/MMBtu] = Cd * Fd * (20 9/(20.9-actual 02%)) 

C[NOx] = 210.7 ppmVd 

C[NOx] = 184.4 ppmVd corrected to 7 % 02 

Mol. Wt. [NOx]= 46.01 Ibllb-mole 

Molar vol air= 

E[NOx] = 

Conv Factor. 

EINOx] = 

385 scfllb-mole @ 

229.27 Ib/hr 

68 

1.194E-07 convert ppmV to Ib/scf NOx 

0.323 Ib/MMBtu 

10) Sulfur Dioxide concentrations and emissions 

def F 

Corr. C[S02] = «20.9-02% corr. value)/(20.9-actual avg. 02% valueWAvg. raw 802 value 

E(lb/MMBtu) = Cd(lb/scf) * Fd(scf/MMBtu) * [20.9 I (20 9-% 02)] 

E[802 Ib/hr] = (C[802rMol Wt[802]*60(min/hr)*Qstd(dscfm))/(Molar Vol. air*10"6) 

C[802] = 21.0 ppmV (dry) Actual Conc. 

C[S02] = 18.4 ppmVd corrected to 7 % 02 

Mol. Wt. [802]= 64.06 Ibllb-mole 

Molar vol air= 

Conv Factor. 

EIS02] = 

EIS02] = 

385 scf/lb-mole @ 68 

1.66E·07 convert ppmV to Ib/scf 802 

0.045 Ib/MMB1u 

31.82 Ib/hr 

def F 
Client 

Project No. 

Test Location 

Fuel Type 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

y= 

j= 

On = 

An = 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

INPUT [02] 

INPUT [C02] 

[N2] 

INPUT [NOx] 

INPUT [802] 

AirNova, Inc. 

EPA Methods 1, 2, 3A, 4, 6 and 7E 

(Flows, 021C02, H20, 802 and NOx) 

Spruance Genco, LLC 

3333 

Unit No. 

Coal 

Three 

04112/10 

1555·1904 

Emission Data 

368.9 cc 

123.001 dcf 

-0.50 in. H20 

30.28 m. Hg 

30.24 in. Hg 

29.92 in. Hg 

0.6670 in. H20 A.5 

1.18 in. H20 

563.8 R 

657.0 R 

527.7 R 

0.97 

180 min. 

0.248 in. 

0.000335 sq. ft. 

10.300 ft. 

83.323 sq. ft. 

Vol. of H20 colle:cted 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft. gauge readmg 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling tIme 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitotlube coefficient 

85.49 ft[(lb/lbmol)'(inHg)]'5}/[s'R'inH20] 

Page 1 of 3 

17.637 R/in.Hg 

0.047070 cu ftlml 

00026688 in.Hg·cf/ml-R 

9868 scf/MMBtu 

constant 

constant Pitot tube constant 

constant 

From EPA Reference Method 19 

Instrumental Data 

425 %-dry Oxygen concentration 

14.69 %-dry Carbon Dioxide concentration 

81.06 %·dry Nitrogen concentration 

217.9 ppmV-dry Nitrogen Oxides concentration 

21.6 ppmV-dry Sulfur DioxJde concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y· Vm * (Pb + dH/13 6) / Tm 

Vmstd = 113.341 dscf 

3.210 dscm 

Unit No, 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 • Vic 

Vw(sld) = 17.364 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 01328 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44*%C02) + (32*%02) + (2B*%N2» ~ (1-Sws) 1 + (18~Bws) 

Ms= 28.857 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp * (dP) * (Ts/Ps~Ms)J\.5 

Vs= 41.562 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min ;0 Vs ., As 

Qa = 207786.9 cfm 

5884.5 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa· (Tsld/Ts) ~ (Ps/Psld) ~ (1-Bws) 

Qstd = 146278,1 dscfm 

4142.6 dscmm 

Page 2 of 3 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cant.) 

Unit No.1 

Three 

Page 3 of 3 

9) Nitrogen Oxides concentrations and emissions 

Carr C[NOx] = «20.9-02% carr. value)/(20.9·actual avg. 02% value))*Avg. raw NOx value 

E[NOx] = (C[NOx]*Mol Wt[NOx]*60(min/hr)*Qstd(dscfm»/(Molar Vol. air"10Jl6) 

E[NOx Ib/MMBtu] = Cd .. Fd .. (20 9/(20.9-actual 02%)) 

C[NOx] = 217.9 ppmVd 

C[NOx] = 181.9 ppmVd corrected to 7 % 02 

Mol. WI. [NOxj= 46.01 Ibllb-mole 

Molar vol air= 385 scf/lb-mole @ 68 def F 

E[NOx] = 228.55 Ib/hr 

Conv Factor. 

E[NOx] = 

1.194E-07 convert ppmV to Ib/scf NOx 

0.322 Ib/MMBtu 

10) Sulfur Dioxide concentrations and emissions 

Carr. C[S02] = «20.9-021;'/0 corf. value)/(20.9-actual avg. 02% value»*Avg. raw S02 value 

E(lb/MMBtu) = Cd(lb/set)· Fd(scf/MMBtu)' [20.9/ (20.9-% 02)] 

E[S02Ib/hr] = (C[S02]·Mol Wt(S02]"60(min/hr)"Qstd(dscfm»/(Molar Vol. air"10116) 

C(S02] = 21.6 ppmV (dry) Actual Conc. 

C(S02] = 18.0 ppmVd corrected to 7 % 02 

Mol. WI. [S02]= 6406 Ib/lb-mole 

Molar vol air= 

Conv Factor. 

E[S02) = 

E[S02] = 

385 scf/lb-mole @ 68 

1.66E-07 convert ppmV to Ib/scf S02 

0044 Ib/MMBtu 

31.54 Ib/hr 

def F 
3333-HCN-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

t = 

Os = 

As= 

Cp= 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

CF= 

[02[ 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and Modified 26 

(Ftows, 02/C02, H20,and HCN) 

Spruance Genco, LLC 

3333 

Unit No.1 

One 

04/12/10 

0840-0940 

152 cc 

42.521 del 

Emission Data 

-050 in. H20 

30.32 in. Hg 

30.28 m. Hg 

29.92 in Hg 

0.7021 in. H20 ".5 

1.660 in. H20 

532.1 R 

654.4 R 

527.7 R 

0.244 in. 

0.000325 sq. ft. 

1.00 

60 min. 

10.300 It. 

83.323 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft{(lb/lbmol)*(inHg)1".5}/[s*R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.ft!ml 

0.0026688 m.Hg-cf/ml-R 

9862 scf/MMBtu 

7.014E-08 Ib/dsefl ppmVd 

Instrumental Data 

4.81 %-dry 

15.05 %-dry 

80.14 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCN 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y 'Vm ' (Pb + dH/13.6) I Tm 

Vmstd = 42.904 dscf 

1.22 dscm 

Unit No.1 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 'Vic 

Vw(std) = 7.155 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws = 0,143 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (1-Bws) I + (18'Bws) 

Ms = 28,80 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP) , (Ts/Ps'Ms)'.5 

Vs= 43.68 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs ,. As 

Qa = 218349.3 cfm 

6183.7 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

Qstd = 152748.6 dscfm 

4325,8 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

8) Hydrogen Cyanide Concentration and Emissions 

Unit No.1 

One 

M[HCN[ = M[CN-](mg) , MW[HCN](mg/mmol) 1 MW[CN-](mg/mmol) 

Page 3 

C[HCN] = (M[HCN](mg) , 2.205E-06(lb/mg) , 21.85(scf'inHg/lbmol'R) , K1 • 10'6) 1 (MW[HCN](lb/lbmol) 'Vms' 

C[HCN](@corr 02) = C[HCN](ppmV)' [(20.9-correcled 02) 1 (20.9-aclual %02)] 

E[HCN] = M[HCN](mg)' Qsld(dscfm)' (2.205E-06)(lb/mg)' 60(min/hr) 1 Vmstd(dscf) 

E[HCN] = C[HCN](ppmV)' Fd' CF(HCN)' (20.9/(20.9-%02)) 

< M[HCN]= 

< C[HCN] = 

< C[HCN] = 

< E[HCN] = 

< E[HCN] = 

0.004 mg 

0.003 ppmV 

0.003 ppmV 

0.002 Ib/hr 

263E-06 Ib/MMBtu 

(@ 7.0 %02) 
3333-HCN-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

t = 

Ds = 

As= 

Cpo 

Kp= 

K1 = 

K2= 

K3 = 

Fd = 

CF = 

[02[ 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and Modified 26 

(Flows, 02/C02, H20,and HeN) 

Spruanee Genco, LLC 

3333 

Unit No.1 

Two 

04/12/10 

1215-1315 

Emission Data 

148.4 cc 

43.863 def 

-0.50 in. H2O 

30.35 m. Hg 

30.31 in Hg 

29,92 in, Hg 

0.6899 in, H20 ".5 

1.660 in. H2O 

550.3 R 

6579 R 

527.7 R 

0.244 in 

0.000325 sq. ft 

1.00 

60 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calJbration factor 

Duration of sampling time 

Diameter of stack 

83,323 sq. ft, Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)"(inHg)]".5}/[s'*R*inH20] Pitot tube constant 

17.637 R/in.Hg constant 

0.047070 cU.fUml 

0.0026688 in.Hg-ef/ml-R 

9755 scf/MMBtu 

7.014E-08 Ib/dsef I ppmVd 

Instrumental Data 

5,02 %-dry 

14.61 %-dry 

80.37 %-dry 

constant 

constant 

Fuel Factor 

Conversion Factor for HCN 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1~' Y .., Vm " (Pb + dH/13.6) I Tm 

Vmstd = 42.839 dsef 

1.21 dscm 

Unit No, 1 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 'Vic 

Vw(std) = 6.985 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.140 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (1-Bws) I + (18'Bw;) 

Ms= 28.78 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP)' (Ts/Ps'Ms)'.5 

Vs= 43_02 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 see/mrn * Vs * As 

Qa = 215088.8 efm 

6091.3 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Oa' (TstdlTs)' (Ps/Pstd)' (1-Bws) 

Qstd = 150292.4 dscfm 

4256.3 dsemm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

8) Hydrogen Cyanide Concentration and Emissions 

Unit No.1 

Two 

M[HCN[ = M[CN-[(mg) , MW[HCN[(mg/mmol) 1 MW[CN-[(mg/mmol) 

Page 3 

C[HCN[ = (M[HCN[(mg) , 2.205E-06(lb/mg) , 21.85(scf'inHg/lbmol'R) , K1 ' 10'6) 1 (MW[HCN[(lb/lbmol) • Vmsl 

C[HCN[(@corr 02) = C[HCN[(ppmV)' [(20.9-corrected 02) 1 (20.9-actual %02) [ 

E[HCN[ = M[HCN[(mg) , Qstd(dscfm) , (2.205E-06)(lb/mg) '60(min/hr) 1 Vmstd(dscf) 

E[HCN[ = C[HCN[(ppmV)' Fd' CF(HCN)' (20.9/(20.9-%02)) 

< M[HCN] = 0.004 mg 

< C[HCN] = 0.003 ppmV 

< C[HCN] = 0.003 ppmV (@ 7.0 % 02) 

< E[HCN] = 0.002 Ib/hr 

< E[HCN] = 2.64E-06 Ib/MMBtu 
3333-HCN-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

Dn = 

An = 

y= 

t = 

Ds= 

As= 

Cp= 

Kp = 

K1 = 

K2= 

K3= 

Fd = 

CF = 

[02J 

[C02J 

[N2J 

Ai,Nova, Inc. 

EPA Methods 1,2,3A,4,and Modified 26 

(Flows, 021C02, H20,and HeN) 

Spruance Genco, LLC 

3333 

Unit No.1 

Three 

04/12/10 

1555-1655 

147,7 cc 

44.933 dcf 

Emission Data 

-0.50 in. H20 

30.28 in Hg 

30.24 in. Hg 

29,92 in. Hg 

0,6678 in. H20 ".5 

1.660 in. H20 

563.1 R 

656.2 R 

527.7 R 

0.244 in, 

0.000325 sq. ft 

1.00 

60 min 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)"'(inHg)]".5}/[s*R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.fUml 

0.0026688 in.Hg-cf/ml-R 

9868 scf/MMBtu 

7.014E-08 Ib/dscf I ppmVd 

Instrumental Data 

4.25 %-dry 

14.69 %-dry 

81.06 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCN 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1} Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y 'Vm ' (Pb + dH/13.6) I Tm 

Vmstd = 42.785 dscf 

1.21 dscm 

Unit NO.1 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 'Vic 

Vw(std) = 6.952 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.140 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) I + (1S'Bws) 

Ms= 28.77 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP)' (Ts/Ps'Ms)A5 

Vs= 41.65 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min'" Vs * As 

Qa = 208214.1 cfm 

5896.6 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

Qstd = 145592.3 dscfm 

4123.2 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

8) Hydrogen Cyanide Concentration and Emissions 

Unit No.1 

Three 

M[HCN[ = M[CN-[(mg) , MW[HCN](mg/mmol) 1 MW[CN-](mg/mmol) 

Page 3 

C[HCN] = (M[HCN](mg) • 2.20SE-06(lb/mg) '21.8S(scf"inHg/lbmol'R) , K1 • 10'6) 1 (MW[HCN](Ib/lbmol) 'Vmsl 

C[HCN](@corr. 02) = C[HCN](ppmV)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HCN] = M[HCN](mg)' Qstd(dscfm)' (2.20SE-06)(lb/mg)· 60(min/hr) 1 Vmstd(dscf) 

E[HCN] = C[HCN](ppmV)' Fd' CF(HCN)' (20 9/(20.9-%02)) 

M[HCN] = 0.136 mg 

C[HCN] = 0.100 ppmV 

C[HCN] = 0.083 ppmV (@ 7.0 % 02) 

E[HCN] = 0.061 Ib/hr 

E[HCN] = 8.68E-OS Ib/MMBtu 
Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit #1 

04113110 

Parameter: 

Instrument Span (% 02): 

Oxygen 

22.03 

Actual Calibration Gas Value t% 02): 

Analyzer Calibration Response t% 02): 

Analyzer Calibration Error t% Span): 

Zero S~stem Calibration Gas 

Apparent Init. S\,:s Init. Sk':s. Final S!'§. FinaJ S\,:s. 

Stack Ga/ib. Gal. Bias Ca/ib. Cal. Bias 

Run Gonc. Response (% span) Response t% span) 

1 4.24 0.04 0.01 0.01 ·0.14 

0 0.00 0.01 -0.14 0.00 -0.18 

0 0.00 0.00 -0.18 0.00 -0.18 

0 0.00 0.00 -0.18 0.00 -0.18 

0 0.00 0.00 -0.18 0.00 -0.18 

0 0.00 0.00 -0.18 0.00 -0.18 

0 0.00 0.00 -0.18 0.00 -0.18 

0 0.00 0.00 -0.18 0.00 -0.18 

0 0.00 0.00 -0.18 0.00 -0.18 

0 0.00 0.00 -0.18 0.00 -0.18 

0 0.00 0.00 -0.18 0.00 -0.18 

0 0.00 0.00 -0.18 0.00 -0.18 

AirNova, Inc. Page 1 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal"t.zer Calib. Gases !lQ§'Qa/~ 

zero low mid high Sk':s. Cal. Gas 

0.00 NIA 11.90 22.03 11.90 

0.04 NIA 11.87 21.79 11.87 

o 18 0.00 -0 14 -1.11 

Uj;!scale Sy:stem Calibration Gas 

Calib. Init. S\,:s. Init. S\,:s. Final Sk':s. Final S\':S Calib. ~ 

Drift Calib. Cal. Bias Galib. Cal. Bias Drift Stack 

t% span) Response t% span) Response t% soan) (% span) Conc. 

·0.14 11.93 0.27 11.94 0.32 0.05 4.21 

-0.05 11.94 0.32 0.00 -53.88 -54.20 ·0.01 

0.00 0.00 -53.88 0.00 -53.88 0.00 ERR 

0.00 000 -53.88 0.00 -53.88 0.00 ERR 

0.00 0.00 -53.88 0.00 -53.88 0.00 ERR 

0.00 0.00 -53.88 0.00 -53.88 0.00 ERR 

0.00 0.00 -53.88 0.00 -53.88 0.00 ERR 

0.00 0.00 -53.88 0.00 -53.88 0.00 ERR 

0.00 0.00 -53.88 0.00 -53.88 0.00 ERR 

0.00 0.00 -53.88 0.00 -53.88 0.00 ERR 

0.00 0.00 -53.88 0.00 -53.88 0.00 ERR 

0.00 000 -53.88 0.00 -53.88 0.00 ERR 
Client 

Project No. 

Test Location 

Test Date 

Parameter: 

Spruance Genco, LLC 

3333 

Unit #1 

04/14/10 

Instrument Span (% 02)' 

Oxygen 

22.03 

Actual Calibration Gas Value (% 02L 

Analyzer Calibration Response (% 02): 

Analyzer Calibration Error (% Soanl: 

Zero S~stem Calibration Gas 

AQparent Init. S'!.s Init. S\:::s. Final S'!.s. Fingl S\:::s. 

Stack Calib Gal. Bias c..ali.!L Cal. Bias 

Run Gone. ReSQon§.e (% span) Response (% span) 

2 4.34 0.10 0.01 0.10 0.50 

3 4.37 0.10 0.50 0.10 0.50 

0 0.00 0.10 0.50 0.00 0.05 

0 0.00 0.00 0.05 0.00 0.05 

0 0.00 0.00 0.05 000 0.05 

0 0.00 0.00 0.05 0.00 0.05 

0 0.00 0.00 0.05 0.00 0.05 

0 0.00 0.00 0.05 0.00 0.05 

0 0.00 0.00 0.05 0.00 0.05 

0 0.00 0.00 0.05 0.00 0.05 

0 0.00 0.00 0.05 0.00 005 

0 0.00 0.00 0.05 0.00 0.05 

AirNova, Inc. Page 1 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Ana/'!.zer Galib. Gases Upscale 

= low mid high Svs. Gal. Gas 

0.00 N/A 11.90 22.03 11.90 

-0.01 N/A 11.93 21.96 11.93 

-0.05 0.00 0.14 -034 

Ugscale S~stem Calibration Gas 

Calib. Init. S'!.s. Init. S'!.s. Final S'i..S: Final S'!.s. Calib. Actual 

Drift Galib. e.g/. Bias Calib. Cal. Big§. Drift 'ilidi 

(% span) Response (% span) Response (% span) (% span) Cone. 

0.00 11.90 -0.14 11.90 -0.14 0.00 4.28 

0.00 11.90 -0.14 11.90 -0.14 0.00 4.31 

-0.45 11.90 -0.14 0.00 -54.15 -54.02 -0.10 

0.00 0.00 -54.15 0.00 -54.15 0.00 ERR 

0.00 0.00 -54.15 0.00 -54.15 0.00 ERR 

0.00 0.00 -54.15 0.00 -54.15 0.00 ERR 

0.00 0.00 -54.15 0.00 -54.15 0.00 ERR 

0.00 0.00 -54 15 0.00 -54.15 0.00 ERR 

0.00 000 -54.15 0.00 -54.15 0.00 ERR 

0.00 0.00 -54.15 0.00 -54.15 0.00 ERR 

0.00 0.00 -54.15 0.00 -54.15 0.00 ERR 

0.00 0.00 -54.15 0.00 -54.15 0.00 ERR 
o 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLG 

3333 

Unit #1 

04113110 

Parameter: Carbon Dioxide 

Instrument Span f% C02): 22.28 

Actual Calibration Gas Value r% C021-' 

AnalYZer Calibration Response f% C02): 

Analvzer Calibration Error r% Span): 

Zero Sy:stem Calibration Gas 

AQJ1arent {nit. SKS. Init. Si::s. Final Sk's. Final Sk's. 

Stack Calib. Cal. Bias Calib. Cal. Bias 

Run Cone. Response f% span) Response f% span) 

1 16.21 0.12 0.10 0.00 0.04 

0 0.00 0.00 0.04 0.00 0.04 

0 0.00 0.00 0.04 0.00 0.04 

0 0.00 0.00 0.04 000 0.04 

0 0.00 0.00 0.04 0.00 004 

0 0.00 0.00 0.04 0.00 0.04 

0 0.00 0.00 0.04 0.00 0.04 

0 0.00 0.00 0.04 0.00 0.04 

0 0.00 0.00 0.04 0.00 0.04 

0 0.00 0.00 0.04 0.00 0.04 

0 0.00 0.00 0.04 0.00 0.04 

0 0.00 0.00 0.04 0.00 0.04 

AirNova, Inc. Page 2 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal't.zer Calib. Gase~ IJJ2~Qfi.I~ 

'"'" """ mid high SKS. Cal. Gas 

0,00 NfA 12.39 2228 12.39 

-0.01 NfA 12.33 22.34 12.33 

-0.04 0.00 -0.27 0.27 

Urui;cale Sy:stem Calibration Gas 

Calib. Init. Sk's. Init. Sk'S, Final Sk'S Final Sk's. Calib. Actual 

Drift Calib. Cal. Bias Cafib. C!3.f. Bifi.~ Drift Stack 

f% span) Response (% span) Response (% span) r% span) = 

-0.54 12.33 0.00 12.31 -0.09 -0.09 16.32 

0.00 12.31 -0.09 0.00 -55.34 -55.25 0.00 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -5534 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 
o 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit #1 

04114110 

Parameter: Carbon Dioxide 

Instrument Span f% C02): 22.28 

Actual Calibration Gas Value (% C02): 

Analyzer Calibration Response (% C021: 

Analvzer Calibration Error t% Span).-

Zero System Calibration Gas 

Armarent Init. SjI'S. Init. SJ,':S. Fina! SjI's. Final S,,-s. 

Stack Calib. Cal. Bias Calib. Cal. Bias 

Run ~ Response (% span) Response (% span) 

2 14.77 -0.12 0.10 -0.12 0.00 

3 14.75 -0.12 0.00 -0.12 0.00 

0 0.00 -0.12 0,00 0.00 0.54 

0 0.00 0.00 0.54 0.00 0.54 

0 0.00 0.00 0.54 0.00 0.54 

0 0.00 0.00 0.54 0.00 0.54 

0 0.00 0.00 0.54 0.00 0.54 

0 0.00 0.00 0.54 0.00 0.54 

0 0.00 0.00 0.54 0.00 0.54 

0 0.00 0.00 0.54 0.00 0.54 

0 0.00 0.00 0.54 0.00 0.54 

0 0.00 0.00 0.54 0.00 0.54 

AirNova, Inc. Page 2 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal'izer Galib. Gases UQ~Qg/e 

zero iflliL mid high S,,-s. Cal. Gas 

0.00 NfA 12.39 22.28 12.39 

~O.12 NfA 12.33 22.34 12.33 

-0.54 0.00 -0.27 0.27 

Ugscale Sllstem Calibration Gas 

Galib. Init S"-S. Init. 81:::5. Final SI:§. FinaIS~. !&1iJL Actual 

Drift Gal/b. GgL Bi;;Js Calib, Caf. Bias Drift Slack 

(% span) Response (% span) Response (% span) (% span) QQaQ. 

0.00 12.33 0.00 12.33 0.00 0.00 14.82 

0.00 12.33 0.00 12.33 0.00 0.00 14.80 

0.54 12.33 000 0.00 -55.34 -55.34 0.12 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 

0.00 0.00 -55.34 0.00 -55.34 0.00 ERR 
3333-PM2.5-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

Dn = 

An= 

y= 

tr = 

Os = 

As = 

Cp= 

Kp = 

K1 = 

K2= 

K3= 

C1= 

C2= 

C3= 

C4= 

C5= 

C6 = 

B1 = 

Fd = 

[02[ 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Methods 1,2,3,4, OTM 27 and 202 

(Flows, 021C02, H20, PM2.S and CPM) 

Spruance Genco, LLC 

3333 

Unit NO.1 

One 

04113110 

1601-2211 

Emission Data 

379.7 cc VoL of H20 collected 

113.235 dcf Dry gas meter reading 

-0.50 in. H20 Static pressure 

30.38 In, Hg Barometric pressure 

30.34 in. Hg Stack pressure 

29.92 in Hg EPA Standard pressure 

0.6871 in. H20 ".5 Average sq.rt delta P 

0.310 in H20 Average draft gauge reading 

528.7 R Average meter temperature 

654.3 R Average stack temperature 

527.7 R Standard temperature 

a 189 in. Nozzle diameter 

0.000195 sq. ft Area of nozzle orifice 

1.00 Meter calibration factor, gamma 

357.22 min Duration of sampling time 

10,300 ft. Diameter of stack 

83,32 sq, ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

8549 ft[(lbllbmol)'{inHg)]'.5}/[s·R"inH20] Pito1 tube constant 

17.637 Rfin.Hg constant 

0.047070 cu.fUml constant 

0.0026688 in.Hg-cf/ml-R 

-150.3162 upoise 

13.4622 upolse/R"0.5 

3861530 upoisefR"2 

0.591123 upolse 

91,9723 upoise 

1.51761 E-05 upoiseJR"2 

0.15625 

9862 dscf/MMBtu 

Instrumental Data 

4.21 %-dry 

16,32 %-dry 

79.47 %-dry 

constant 

Viscosity constant 

Viscosity constant 

Viscosity constant 

Viscosity constant 

Viscosity constant 

Viscosity constant 

Constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

NItrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

Unit No.1 

One 

1) Dry Gas Volume at standard conditions, Vms (EPA OTM 27 Equation 27). 

Vms =K1* Y .. Vm * (Pb + dH/13.6) I Tm 

Vms = 114.635 dscf 

3.252 dsem 

2) Dry gas sampling rate at standard conditions, QsST (EPA OTM 27 Equation 28) 

QsST = Vms I tr 

asST= 0.321 dscfm 

0.009 dsem I min. 

3) Volume of water vapor condensed at standard conditions, Vws (EPA OTM 27 Equation 29). 

Vws = K2 "Vic 

Vws= 17.872 scf 

4) Decimal fraction of moisture by volume in stack gas, Bws (EPA aTM 27 Equation 30). 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.135 

5) Molecular weight of the stack gas on a wet basis, Mw (EPA OTM 27 Equations 1 &2). 

Mw = [((44'%C02) + (32"%02) + (28"%N2))' (1-Bws) I + (18"Bws) 

Mw = 29 06 Ib/lbmole 

6) Gas sampling rate at actual Cyclone conditions, Os (EPA OTM 27 Equation 31). 

as = (Pstd/Tstdl'asST' (1/(1-Bws))'(Ts/Ps) 

Os = 0.454 aefm 

7) Average stack gas velocity, Vs (EPA OTM 27 Equation 11). 

Vs = Kp' Cp" (ave of (dP)'O.5)· (Ts/Ps"Mw)'O.5 

Vs = 4251 fps 

8) Average actual stack gas volumetric f/owrate, Oa. 

Oa = 60 sec/min" Vs .. As 

Oa = 212499.8 efm 

6016.0 cmm 

9) Average stack gas dry standard volumetric f/owrate, Ostd 

astd = aa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

Ostd = 150404.0 dsefm 

4259.4 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.1 

One 

Page 3 

10) Analytical data 

Cvclone and Filter Fractions (EPA Method aTM 27): 

Ml) Instack quartz microfibre filter, <2 Sum 

0.0054 9 PM <2.S filter netwt 

M2-4) Cyclone acetone washes 

0.0000 9 actual mass of >2.S, Containers 2&3 

0.0026 9 actual mass of </=2.5um, Container 4 

0.0000 9 acetone blank net wt 

o mL volume 

150 mL volume 

150 mL volume 

o 0000 9 blank corrected mass of >2.5um, Containers 2&3 = M2&M3 

00026 9 blank corrected mass of </=2.Sum, Container 4 = M4 

Condensible Parliculate Matter (CPMJ Fractions (EPA Method 202): 

M5) Back Half Aqueous Wash 

0.0107 9 actual sample mass 

0.0003 9 aqueous blank mass 

300 ml blank vol. 

300 ml Sample volume 

0.0104 9 condensIble aqueous PM 

M6) Back Half MeCI2 Extraction Portion 

0.0000 9 extraction net wt 

0.0000 g MeCI2 blank net wt 

300 ml blank vol. 

300 ml MeCI2 extraction volume 

o 0000 9 condensible organic PM 

M[CPM] = blank corrected mass of Total CPM, M5 & M6 (in grams) 

M[CPM] = 0.0104 9 CPM 

11) Parliculate Concentrations, C (EPA OTM27 and EPA 202). 

Equation 43 

Equation 45 

EPA 202 

C[totalsus] = M 1 (g)+M2(g)+M3(g)+M4(g)'15.43(grains/g)Nmstd(dscf)= 

C[PM2.5sus] = M1 (g) + M4(g) " 15.43(grains/g) 1 Vmstd(dscf) = 

C[CPM] = M[CPM](g) "15 43(gralns/g) 1 Vmstd(dscf) 

where 15.43 = 7000/453592*1000 

C[PMtotal] = C[PMtotalsus] + C[CPM] 

C[PM2.5total] = C[PM2.5sus] + C[CPM] 

0.0011 gr/dscf PMsus 

0.0011 gr/dscf PM2 5sus 

0.0014 gr/dscfCPM 

0.0025 gr/dscfTo1al PM 

0.0025 gr/dscf Total PM2.5 
Client Spruance Genco, LLC 

Project No. 3333 

12) Particulate Emission Rates, E. 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.1 

One 

E[lblhr] = C[](grldscD • (1 Ibl7000 gr) • Qstd(dscfm) • 60(minlhr) 

E[lbIMMBtu] = C[](grldscD • (1 Ibl7000 gr) • Fd(dscfIMMBtu) • (20.9120 9-%02) 

E[totalsusJ = 1.39 Ib/hr total sus PM 

E[totalsus] = 0.0019 Ib/MMBtu total sus PM 

E[PM2.5sus] = 1.39 Ib/hr PM2.5sus = 43.5 % of Total PM2.5 

E[PM2.5sus] = 0.0019 Ib/MMBtu PM2.5sus = 

E[CPM]= 1.80 Ibfhr CPM 56.5 % of Total PM2.5 

E[CPM] = 00025 IblMMBtu CPM 

E[PMtotal] = 319 Ibfhr total PM 

E[PMtotal] = 0.0044 Ib/MMBtu total PM 

E[PM2 5total] = 3.19 Iblhr total PM2.5 

E[PM2.5total] = 0.0044 IblMMBtu total PM2 5 

13) Percent fsokinectic Sampling, %1 (EPA OTM 27 Equation 40). 

% I = [100"Ts*Vms*Pstd) I (60*Vs*tr*An*Ps*(1-Bws)*Tstd) 

%1= 9141 

14) Stack Gas Viscosity, u (EPA OTM 27 Equation 3). 

u = C1 + C2"'(TsIIO.5) + C3*(Tsll-2) + C4*(%02) - (C5*Bws) + C6*Bws*(TsIl2) 

u = 194.0 micropoise 

Page 4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

15) Test Condition Reynolds number, Nre (EPA OTM 27 Equation 8). 

Nre = 8.64"10'5"(Ps"MwiTs),(Oslu) 

Nre = 2726 

Unit No.1 

One 

16) Actual Particle Cut ~iameter for Cyclone I, 050 (EPA OTM 27 Equation 32). 

050 = 81 " ( [ Ts 1 ( Mw" Ps))'.2091) " ( (u lOs)'. 7091) 

050 = 10.77 um 

17) Actual Cunningham Correction Factor based on Op = 2.5um, C (EPA OTM 27 Equation 4). 

C = 1+ 0.0057193" (ul(Ps"Op))" (TsIMw)'O.5 

C = 1.0694 

18) Initial D50 for Cyclone IV based on test condition Reynolds number from OTM 27 Equation 8. 

If Nre < 3162, use Equation 33 which results in 050 for IV = 

If Nre >= 3162, use Equation 34 which results in 050 for iV = 

Initial 050 

243 

2.29 

Equation 33 

Equation 34 

Equation 35 

050 = 0.0024302"(uIOs),1.1791"(1IC)'OS(Tsl(Ps"Mw)),0.6790 

050 = 0 019723"(uIOs)'O.8058"(1IC)'0.5·(Tsl(Ps"Mw)),0.3058 

Cr = 1 + 0.0057193"(ul(Ps"050)),(TslMw),0.5 

19) Re·established D50 for Cyclone IV, 050-1. 

Page 5 

Re·established 

Cunningham, Cr 

1.0715 

1.0757 

If Nre < 3162, use Equation 36 which results in 050 for IV = 

If Nre >= 3162, use Equation 37 which results in 050 for iV = 

Recalculated Cut Oiam, 050-1 

2.42 

2.29 

Equation 36 

Equation 37 

050-1 = 0.0024302·(uIOs),1.1791"(1ICr)'O 5"(Tsl(Ps"Mw))'0.6790 

050-1 = O. 019723"(uIOs)'O. 8058"( 1ICr)'0.5"(TsI(Ps"Mw))'0. 3058 

19) Establishing "Z" value, Z. 

If Equation 36 was used, then 

If Equation 37 was used, then 

Z=050-11050= 

Z = 050-1 1050 = 

If 0.99 < Z < 1.01, then 050-1 is best cut diameter estimate. 

If 0.99 > Z > 1.01, then repeat calcs for Cr using 050-1 

1.00 

1.00 
3333-PM2.5-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

T5 = 

Tstd= 

Dn = 

An= 

y= 

tr = 

Ds= 

As= 

Cp= 

Kp= 

K1 = 

K2= 

K3 = 

C1= 

C2 = 

C3= 

C4= 

C5= 

C6= 

81 = 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3,4, aTM 27 and 202 

(Flows, 02/C02, H20, PM2.5 and CPM) 

Spruance Genco, LLC 

3333 

Unit No.1 

Two 

04114110 

0739-1408 

Emission Data 

390 cc Vol. of H20 collected 

121.466 def Dry gas meter reading 

-0.50 in. H20 Static pressure 

30.57 in. Hg Barometric pressure 

30.53 In. Hg Stack pressure 

29.92 in. Hg EPA Standard pressure 

0.7113 In, H20 fI 5 Average sq.rt delta P 

0.310 in. H20 Average draft gauge reading 

5249 R Average meter temperature 

656.7 R Average stack temperature 

527,7 R Standard temperature 

0.189 in. Nozzle diameter 

0000195 sq. ft. Area of nozzle orifice 

1.00 Meter calibration factor, gamma 

36566 min. Duration of sampling time 

10.300 ft. Diameter of stack 

83.32 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)'(inHg)]A.5)/[s'WinH20] P,tot tube constant 

17.637 R/in Hg constant 

0.047070 cu.ftlml constant 

0.0026688 in.Hg-cf/ml-R constant 

-150.3162 upoise Viscosity constant 

13.4622 upoise/R"0.5 Viscosity constant 

3861530 upoise/R"2 Viscosity constant 

0.591123 upoise Viscosity constant 

91.9723 upoise Viscosity constant 

1.51761 E-05 upoise/R"2 Viscosity constant 

0.15625 Constant 

9755 dscf/MMBtu Fuel Factor 

Instrumental Data 

428 %-dry 

14.82 %-dry 

80.90 %-dry 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

Unit No.1 

Two 

1) Dry Gas Volume at standard conditions, Vms (EPA OTM 27 Equation 27JVms =K1' Y' Vm ' (Pb + dH/13.6) ITm 

Vms = 124.870 dscf 

3536 dscm 

2) Dry gas sampling rate at standard conditions, QsST (EPA OTM 27 Equation 28). 

QsST = Vms I tr 

QsST= 0.341 dscfm 

0.010 dscm I min. 

3) Volume of water vapor condensed at standard conditions, Vws (EPA OTM 27 Equation 29). 

Vws = K2 "Vic 

Vws= 18357 scf 

4) Decimal fracllon of mOIsture by volume in stack gas, Bws (EPA OTM 27 Equation 30). 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.128 

5) Molecular weight of the stack gas on a wet basIs, Mw (EPA OTM 27 Equations 1 &2). 

Mw = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) I + (1S'Bws) 

Mw = 28.93 Ib/lbmole 

6) Gas samplmg rate at actual Cyclone conditions, Os (EPA OTM 27 Equation 31). 

Qs = (PstdlTstd),QsST ' (1/(1-Bws))'(Ts/Ps) 

as = 0.478 acfm 

7) Average stack gas velocIty, Vs (EPA OTM 27 Equation 11). 

Vs = Kp , Cp • (ave of (dP)'O.5) , (Ts/Ps'Mw)'O 5 

Vs = 4404 fps 

8) Average actual stack gas volumetric fJowrate, Qa. 

Qa = 60 sec/min" Vs " As 

Qa = 220170.7 cfm 

6235.2 cmm 

9) Average stack gas dry standard volumetric flowrate, Qstd. 

Qstd = Qa ' (TstdlTs) , (Ps/Pstd) , (1-Bws) 

Qstd = 157406.7 dscfm 

4457.8 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.1 

Two 

Page 3 

10) Analytical data 

Cyclone and Filter Fractions (EPA Method aTM 27): 

M1) Instack quartz microfibre filter, <2 Sum 

0.0083 9 PM <2.5 filter net wt 

M2-4) Cyclone acetone washes 

0.0000 9 actual mass of >2.S, Containers 2&3 

o 0022 9 actual mass of <1=2.5um, Container 4 

0_0000 g acetone blank net wt 

a mL volume 

100 mL volume 

150 mLvolume 

0.0000 g blank corrected mass of >2.5um, Containers 2&3 = M2&M3 

0.0022 9 blank corrected mass of <I=2.5um, Container 4 = M4 

Condensible Parliculate Matter (CPM) Fractions (EPA Method 202): 

M5) Back Half Aqueous Wash 

0.0102 9 actual sample mass 

00003 9 aqueous blank mass 

300 ml blank vol. 

300 ml Sample volume 

0.0099 9 condensible aqueous PM 

M6) Back Half MeCI2 ExtractIon Portion 

0.0000 9 extraction net wt 

0.0000 9 MeCI2 blank net wt 

300 ml blank vol. 

300 ml MeCI2 extraction volume 

0.0000 9 condensible organic PM 

M[CPM] = blank corrected mass of Total CPM, M5 & M6 (in grams) 

M[CPM] = 0.0099 9 CPM 

11) Particulate Concentrations, C (EPA OTM27 and EPA 202). 

Equation 43 

Equation 45 

EPA 202 

C[totalsus] = M1 (g)+M2(g)+M3(g)+M4(g)'15.43(grains/g)Nmstd(dscf)= 

C[PM2.5sus] = M1(g) + M4(g) '15 43(grains/g) 1 Vmstd(dscf) = 

C[CPM] = M[CPM](g) , 15.43(grains/g) 1 Vmstd(dscf) 

where 15.43 = 7000/453592'1000 

C[PMtotal] = C[PMtotalsus] + C[CPM] 

C[PM2.5total] = C[PM2.5sus] + C[CPM] 

0.0013 gr/dscf PMsus 

0.0013 gr/dscf PM2.5sus 

0.0012 gr/dscfCPM 

0.0025 gr/dscf Total PM 

0.0025 gr/dscf Tolal PM2.5 
Client 

Project No. 

Spruance Genco, LLC 

3333 

12) Particulate Emission Rates, E. 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.1 

Two 

E[lb/hr] = C[](gr/dscn • (1 Ib/7000 gr) • Qsld(dscfm) • 60(min/hr) 

E[lb/MMBlu] = C[](gr/dsc0' (1 Ib/7000 gr)' Fd(dscf/MMBlu)' (20.9/20.9-%02) 

E[lotalsus] = 1.75 Ib/hr total sus PM 

E[totalsusJ = 0.0023 Ib/MMBtu total sus PM 

E[PM2.5sus] = 1 75 Iblhr PM2.5sus = 51.5 % of Total PM2.5 

E[PM2.5sus] = 0.0023 Ib/MMBtu PM2 5sus = 

E[CPM] = 1 65 Ib/hr CPM 48.5 % of Total PM2.5 

E[CPM] = 0.0021 Ib/MMBlu CPM 

E[PMlolal] = 3.40 Ib/hr total PM 

E[PMlolal] = 0.0044 Ib/MMBtu total PM 

E[PM2.5Iolal] = 3.40 Ib/hr total PM2.5 

E[PM2.5Iolal] = 0.0044 Ib/MMBlu lola I PM2.5 

13) Percent fsokinectic Sampling, %f (EPA OTM 27 Equation 40). 

% I = [1 OO"'Ts"'Vms*Pstd) I (6D*Vs*tr*An*Ps*(1-Bws)*Tstd) 

% I = 92.78 

14) Stack Gas Viscosity, u (EPA OTM 27 Equation 3). 

u = C1 + C2*(Ts"O.5) + C3*(Ts"-2) + C4*(%02) - (C5*Bws) + CS*Bws*(Ts"2) 

u = 195.2 micropoise 

Page 4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

15) Test Condition Reynolds number, Nre (EPA OTM 27 Equation B). 

Nre = 8.64*10"S*(Ps""MwlTs)*(Qs/u) 

Nre = 2844 

Unit No 1 

Two 

16) Actual Particle Cut Diameter for Cyclone I, 050 (EPA OTM 27 Equation 32). 

DSO = 81 • ([ Ts I (Mw' Ps))'.2091)· ((u I Qs)'.7091) 

D50 = 10.44 um 

17) Actual Cunningham Correction Factor based on Dp = 2 5um, C (EPA OTM 27 Equation 4). 

C = 1+ 0 00S7193' (u/(Ps'Dp))' (Ts/Mw)'O.S 

C= 1.0697 

18) Initial 050 for Cyclone IV based on test condition Reynolds number from orM 27 Equation 8. 

If Nre < 3162, use Equation 33 which results in DSO for IV = 

If Nre >= 3162, use Equation 34 which results in DSO for iV = 

Initial D50 

2.30 

2.21 

Equation 33 

Equation 34 

Equation 35 

DSO = 0.0024302·(u/Qs)'1.1791·(1/C),0.S"(Ts/(Ps"Mw)),0 6790 

DSO = 0.019723·(u/Qs)'0.8058·(1/C)'0.S·(Ts/(Ps·Mw)),0.30S8 

Cr = 1 + 0.00S7193·(u/(Ps·DSO))·(Ts/Mw)'0.S 

19) Re·established 050 for Cyclone IV, 050-1. 

Page 5 

Re-establlshed 

Cunningham, Cr 

1.07S6 

1.0787 

If Nre < 3162, use Equation 36 which results in DSO for IV = 

If Nre >= 3162, use Equation 37 which results in DSO for iV = 

Recalculated Cut Diam, DSO-1 

230 

2.20 

Equation 36 

Equation 37 

DSO-1 = 0 0024302·(u/Qs)'11791·(1/Cr)'0.S·(TsI(Ps·Mw)),0.6790 

DSO-1 = 0.019723·(u/Qs),0.80SS·(lICr),0.S·(Ts/(Ps·Mw))'0.30S8 

19) Establishing "Z" value, Z. 

If Equation 36 was used, then 

If Equation 37 was used, then 

Z= DSO-1/DSO= 

Z = DSO-1/DSO = 

If 0.99 < Z < 1.01, then DSO-1 is best cut diameter estimate. 

If 0.99 > Z > 1.01, then repeat cales for Cr using DSO-1 

1.00 

1.00 
3333-PM2.5-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

Dn = 

An = 

y= 

tr = 

Os = 

As= 

Cp= 

Kp= 

K1 = 

K2= 

K3 = 

C1 = 

C2 = 

C3= 

C4= 

C5= 

C6 = 

B1 = 

Fd = 

[02[ 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3,4, OTM 27 and 202 

(Flows, 02/C02, H20, PM2.5 and CPM) 

Spruance Genco, LLC 

3333 

Unit No 1 

Three 

04/14/10 

1451-2120 

Emission Data 

431 cc Vol. of H20 collected 

139.204 dcf Dry gas meter reading 

-0.50 in H20 Static pressure 

30.51 in_ Hg Barometric pressure 

30.47 in. Hg Stack pressure 

29.92 in. Hg EPA Standard pressure 

0.6667 in. H20 ".5 Average sq,rt delta P 

0.340 in. H20 Average draft gauge reading 

538.7 R Average meter temperature 

656.1 R Average stack temperature 

527.7 R Standard temperature 

0.180 in, Nozzle diameter 

0.000177 sq. ft. Area of nozzle orifice 

0.97 Meter calibration factor, gamma 

388.84 min. DUration of sampling time 

10.300 ft. Diameter of stack 

83.32 sq. ft. Cross sectional area of stack 

o 84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R*jnH20] Pltot tube constant 

17 637 R/in.Hg constant 

0.047070 cu.ftlml constant 

0.0026688 in.Hg-cf/ml-R constant 

-150.3162 upoise Viscosity constant 

134622 upoise/R"0.5 Viscosity constant 

3861530 upoise/R"2 Viscosity constant 

0.591123 upoise Viscosity constant 

91.9723 upoise Viscosity constant 

1.51761 E-05 upoise/R"2 Viscosity constant 

0.15625 Constant 

9868 dscf/MMBtu 

Instrumental Data 

4.31 %-dry 

14.80 %-dry 

8089 %-dry 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

Unit No.1 

Three 

1) Dry Gas Volume at standard conditions, Vms (EPA OTM 27 Equation 27). 

Vms =K1" Y" Vm " (Pb + dH/13.6) ITm 

Vms = 134.989 dscf 

3.823 dsem 

2) Dry gas sampling rate at standard conditions, QsST (EPA OTM 27 Equation 28). 

QsST = Vms I tr 

asST= 0.347 dscfm 

0.010 dscm I min. 

3) Volume of water vapor condensed at standard conditions, Vws (EPA OTM 27 Equation 29). 

Vws = K2 ·Vlc 

Vws = 20.287 sef 

4) Decimal fraction of moisture by volume in stack gas, Bws (EPA OrM 27 Equation 30). 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.131 

5) Molecular weight of the stack gas on a wet basis, Mw (EPA OTM 27 Equations 1 &2). 

Mw = [((44"%C02) + (32"%02) + (2S"%N2))" (1-Bws) I + (1S'Bws) 

Mw = 28,90 Ib/lbmole 

6) Gas sampling rate at actual Cyclone conditions, Os (EPA aTM 27 Equation 31) 

as = (Pstd/Tstd)"asST' (11(1-Bws))'(Ts/Ps) 

Qs = 0.487 aefm 

7) Average stack gas velocity, Vs (EPA arM 27 Equation 11). 

Vs = Kp • Cp " (ave of (dP)'O.5) • (Ts/Ps"Mw)'O.5 

Vs = 41.33 Ips 

8) Average actual stack gas volumetric f/owrate, Qa. 

Qa = 60 sec/min * Vs • As 

Qa = 206595.8 efm 

5850.8 cmm 

9) Average stack gas dry standard volumetric f/owrate, Qstd. 

astd = aa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

Qstd = 147122.3 dsefm 

4166,5 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.1 

Three 

Page 3 

10) Analytical data 

Cyclone and Fifter Fractions (EPA Method OTM 27J: 

M1) Instack quartz microfibre filter, <2.5um 

0.0085 9 PM <2.5 filter net wt 

M2-4) Cyclone acetone washes 

0.0000 9 actual mass of >2.5, Containers 2&3 

0.0014 9 actual mass of <1=2.5um, Container 4 

0.0000 9 acetone blank net wt 

a mL volume 

100 mL volume 

150 mL volume 

0.0000 9 blank corrected mass of >2.5um, Containers 2&3 = M2&M3 

0.0014 9 blank corrected mass of <1=2.Sum, Container 4 = M4 

Condensible Particulate Matter (CPMJ Fractions (EPA Method 202): 

MS) Back Half Aqueous Wash 

0.0105 9 actual sample mass 

0.0003 9 aqueous blank mass 

300 ml blank vol. 

300 ml Sample volume 

0.0102 9 condensible aqueous PM 

M6) Back Half MeCI2 Extraction Portion 

0.0000 9 extraction net wt 

0.0000 9 MeCI2 blank net wt 

300 ml blank vol. 

300 ml MeCI2 extraction volume 

0.0000 9 condensible organic PM 

M[CPM] = blank corrected mass of Total CPM, MS & M6 (in grams) 

M[CPM[ = 0.0102 9 CPM 

11) Particulate Concentrations, C (EPA OTM27 and EPA 202). 

Equation 43 

Equation 45 

EPA 202 

C[totalsus[ = M 1 (g)+M2(g)+M3(g)+M4(g)'15.43(grains/g)Nmstd(dsc0= 

C[PM2 5sus] = M1 (g) + M4(g) " 15.43(grains/g) 1 Vmstd(dscf) = 

C[CPM] = M[CPM](g)" 15.43(groins/g) 1 Vmstd(dsc0 

where 15.43 = 7000/453592"1000 

C[PMtotal] = C[PMtotalsus] + C[CPM] 

C[PM2.5total] = C[PM2.5sus] + C[CPM] 

0.0011 grJdscf PMsus 

0.0011 gr/dscf PM2.5sus 

0.0012 grJdscf CPM 

0.0023 grJdscf Total PM 

0.0023 gr/dscfTotal PM2.5 
Client 

Project No. 

Spruance Genco, LLC 

3333 

12) Parliculate Emission Rates, E 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.1 

Three 

E[lblhr] = C[](grldscD' (1 Ibl7000 gr)' Qstd(dscfm)' 60(minlhr) 

E[lbIMMBtu] = C[](grldscD' (1 Ibl7000 gr)' Fd(dscfIMMBtu)' (20.9120.9-%02) 

E[totalsusJ = 1.43 Ibfhr total SllS PM 

E[totalsus] = 0.0020 Ib/MMBtu total sus PM 

E[PM2.5sus] = 1.43 Ib/hr PM2.Ssus = 493 % of Total PM2.S 

E[PM2.5sus] = 0.0020 Ib/MMBtu PM2.Ssus = 

E[CPM] = 1.47 Iblhr CPM SO 7 % of Total PM2 S 

E[CPM] = 0.0021 IblMMBtu CPM 

E[PMtotal] = 2.90 Ib/hr total PM 

E[PMtotal] = 0.0041 Ib/MMBtu total PM 

E[PM2.5total] = 2.90 Ib/hr total PM2.S 

E[PM2.5total] = 0.0041 Ib/MMBtu total PM2.S 

13) Percent Isokinectic Sampling, %1 (EPA OTM 27 Equation 40). 

% I = [100*Ts*Vms·Pstd) I (60*Vs*tr*An*Ps*(1-Bws)*Tstd) 

%1= 111.26 

14) Stack Gas Viscosity, u (EPA OTM 27 Equation 3). 

u = C1 + C2"(Ts"0.S) + C3*(Ts"-2) + C4*(%02) - (CS"Bws) + C6"Bws"(TsA2) 

u = 194.9 mlcropoise 

Page 4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

15) Test Condition Reynolds number. Nre (EPA orM 27 Equation 8). 

Nre = B.64""10/1-5'''(Ps·MwlTs)*(QsJu) 

Nre = 2901 

Unit No.1 

Three 

16) Actual Particle Cut Diameter for Cyclone I. 050 (EPA OrM 27 Equation 32). 

050 = 81 '( [Ts 1 (Mw' Ps)['.2091)' ((u 1 Os)' 7091) 

050 = 10.28 um 

17) Actual Cunningham Correction Factor based on Dp = 2.Sum, C (EPA OrM 27 Equation 4). 

C = 1+ 0 0057193' (u/(Ps'Op))' (Ts/Mw)'O 5 

C= 1.0697 

18) Initial 050 for Cyclone IV based on test condition Reynolds number from OrM 27 Equation 8. 

If Nre < 3162, use Equation 33 which results in 050 for IV = 

If Nre >= 3162, use Equation 34 which results in 050 for iV = 

Initial 050 

2.25 

2.18 

Equation 33 

Equation 34 

Equation 35 

050 = 00024302'(u/Os),1 1791'(1/C)'0.5'(Ts/(Ps'Mw))'0.6790 

050 = 0.019723'(u/Os)'0.8058'( l/C)'0.5'(Ts/(Ps'Mw)),0.3058 

Cr = 1 + 0.0057193'(u/(Ps'050))'(Ts/Mw)'0 5 

19) Re-establlshed 050 for Cyclone IV, D50-1. 

Page 5 

Re-established 

Cunningham. Cr 

1.0775 

1.0801 

If Nre < 3162, use Equation 36 which results in 050 for IV = 

If Nre >= 3162, use Equation 37 which results in 050 for IV = 

Recalculated Cut Olam, 050-1 

2.24 

2.17 

Equation 36 

Equation 37 

050-1 = 0.0024302'(u/Os)'1 1791'(1/Cr)'0.5'(Ts/(Ps'Mw))'0.6790 

050-1 = 0.019723'(u/Os)'0.8058'( l/Cr)'0.5'(Ts/(Ps'Mw))'0. 3058 

19) Establishing "z" value, Z. 

If Equation 36 was used, then Z = 050-1 f 050 = 

If Equation 37 was used, then Z = 050-11 050 = 

If 0.99 < Z < 1.01, then 050-1 is best cut diameter estimate 

If 0.99 > Z > 1.01, then repeat calcs for Cr using 050-1 

1.00 

1.00 
3333-TSP·Metals-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps= 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

Dn = 

An = 

y= 

t= 

Ds= 

As= 

Cp= 

Kp = 

K1 = 

K2 = 

K3= 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,5 and 29 

(Flows, 02/C02, H20, TSP and Metals) 

Spruance Genco. LLC 

3333 

Unit No.1 

One 

04/13/10 

1601-2216 

Emission Data 

630.3 cc 

208.204 dcf 

-0.50 in, H20 

30.38 in, Hg 

30,34 in. Hg 

29.92 in. Hg 

0.6873 in. H20 11,5 

0,883 in. H20 

532.5 R 

655,5 R 

527,7 R 

0,230 in. 

0.000289 sq. ft. 

0.97 

360 min. 

10.30 ft. 

VoL of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq, rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmolt{inHg)JII.5}/[s·R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cU.Wml 

0.0026688 in.Hg-cf/ml-R 

9862 scf/MMBtu 

Instrumental Data 

4.21 %-dry 

16.32 %-dry 

79.47 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm * (Pb + dH/13.6) / Tm 

Vmstd = 203.668 dscf 

5.768 dscm 

Unit No.1 

Ooe 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

VW(Sld) = 29.668 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1271 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms= 29.155 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp * (dP) • (TslPs*Ms)".5 

Vs = 42.481 fps 

6) Average actual stack gas volumetric flowrate, aa. 

Qa = 60 sec/min * Vs * As 

Qa = 212372.54 cfm 

6014.39 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa * (TstdfTs)· (ps/Pstd) * (1-Bws) 

Qstd = 151351.62 dscfm 

4286.28 dscmm 

Page2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Unit No.1 

One 

Calculations (cont.) 

8) Particulate Matter Analytical Data 

INPUT A 0.0290 9 

INPUT B 100 ml 

INPUT C 0.0512 9 

INPUT D 100 ml 

INPUT E 0.0000 9 

9) Particulate sample mass calculations 

H 

I 

J 

Front Half: 

Acetone blank adj. residue v 

Adj. Acetone wash partwt. 

Front half sample wt. 

10) Front Half Particulate Matter Emission Data 

Filter sample net wt 

Front acetone wash vol. 

Front acetone residue wt. 

Acetone blank vol. 

Acetone blank residue wt. 

0.0000 g 

0.OS12 9 

0.0802 9 

E"(B/D) 

C-H 

A>I 

C[PMJ = (Front HalfWt){g) * (1Nmstd) * 15.43(grainsfg) 

E[PMJ = C[PMJ * Vdscfm * A * (60 minfhr);O (1 Ib f 7000 grains) 

Page 3 

E[PMJ IbfMMBtu = E[PMJ Ibfhr*{Fuel HV) scffBtu*{fuel use) 1 hourfkscf*kscff1000scf'"10"6BtufMMBtu 

C[PMJ = 6.08E-03 grainsfdscf 

C[PM] = 8.68E-07 Ibfdscf 

E[PM] = 7.882 Ibfhr 

E[PM] = 1_07E-02IbfMMBtu 

11)Trace metal concentrations and emission rates 

Element 

Antimony 

Arsenic 

Beryllium 

Cadmium 

Chromium 

Cobalt 

Lead 

Manganese 

Nickel 

Selenium 

C[MJ = M[M] tug) f Vmstd (dscm) 

C[MJ(lb/dscf) = C[MJ{ug/dscm) * 1e-06g/ug;O 2.205e-03Ib/g;O 0.02832 dscm/dscf 

E[MJ(lb/hr) = C[MJ (ug/dscm) * (2.205E-09) (Ib/ug) * Qstd (dscmm) * 60 (minfhr) 

E[MJ{lb/MMBtu) = C[M]{lbfdscf);O Fd ;0 (20.9/20.9-%02) 

C[M]{@ corr. 02) = C[MJ (ug/dscm) * ( (20.9-corrected %02) I (20.9-actual %02) ] 

Corrected 02 percentage is: 70 % 

Sample Conc. Conc.@corr. 02 Conc. Emission Rate 

Mass tug) (ugfdscm) (ugfdscmj {Ib/dscf} {lbfhr} 

2.771 4.80E-01 4.00E-01 3.00E-11 2.72E-04 

1.802 3.12E-01 2.60E-01 1.95E-11 1.77E-04 

0.777 1.35E-01 1.12E-01 8.41E-12 7.64E-05 

0.308 5.34E-02 4_45E-02 3.33E-12 3.03E-05 

6.56 1.14E+OO 9.47E-01 7.10E-11 6.45E-04 

2.64 4.5SE-01 3.81E-01 2.86E-11 2.60E-04 

5.434 9.42E-01 7.S5E-01 5.88E-11 S.34E-04 

5.364 9.30E-01 7.75E-01 5.S1E-11 5.27E-04 

5.762 9.99E-01 8.32E-01 6.24E-11 5.66E-04 

0.915 1.59E-01 1.32E-01 9.91E-12 9.00E-05 

12) Isoklneclty, I. 

% I = [100*Ts*(K3~Vlc+«(Vm~Y)fTm)*(Pb+(dH/13 6»)))J I (60*t*Ps*Vs*An) 

% I = 107.95 

" < " symbol indicates values given are the quantitative detection limit. 

Emission Rate 

(lbfMMBtu) 

3_70SE-07 

2.409E-07 

1.039E-07 

4.11SE-OS 

S.771E-07 

3.S30E-07 

7.265E-07 

7.172E-07 

7.704E-07 

1.223E-07 
3333-TSP-Metals-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

dP= 

dH = 

Tm= 

Ts = 

Tstd= 

Dn = 

An= 

y= 

1= 

Ds = 

As = 

Cp = 

Kp= 

K1 = 

K2= 

K3 = 

Fd = 

[02) 

[C02) 

[N2) 

AirNova, Inc. 

EPA Methods 1,2,3A,4,5 and 29 

(Flows, 02lC02, H20, TSP and Metals) 

Spruance Genco, LLC 

3333 

Unit No.1 

Two 

04/14/10 

0739-1354 

Emission Data 

627.4 cc 

188.668 dcf 

-0.50 in. H20 

30.57 in. 

30.53 in. 

29.92 in. 

0.6820 in. 

0.880 in. 

527.7 R 

658.2 R 

527.7 R 

0.230 in. 

H9 

H9 

H9 

H20 ".5 

H2O 

0.000289 sq. ft. 

1.00 

360 min, 

10.30 ft, 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.3204 sq, ft, Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbllbmol)·(inHg)1",5}/[s~R·inH201 Pitot tube constant 

17.637 Riin,Hg 

0.047070 cu.fUml 

0.0026688 in.Hg·cf/ml·R 

9755 scf/MMBtu 

Instrumental Data 

4.28 %-dry 

14,82 %-dry 

80,90 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y' Vm * (Pb + dH/13.6) I Tm 

Vmstd = 193.175 dscf 

5.471 dscm 

Unit No. 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 • Vic 

Vw(std) = 29.532 scf 

3) Decimal fraction of moisture by volume In stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.1326 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32*%02) + (28*%N2» * (1-Bws) J + (18*Bws) 

Ms= 28.879 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp' (dP) * (Ts/Ps*Ms)".5 

Vs= 42.312 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min * Vs ;0 As 

Qa= 211525.76cfm 

5990.41 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Oa * (TstdfTs);O (PsiPstd) • (1-Bws) 

Qstd = 150114.11 dscfm 

4251.23 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Unit No. 

Two 

Calculations (cont.) 

8) Particulate Matter Analytical Data 

INPUT A 0.0494 9 

INPUT 8 100 ml 

INPUT C 0.0203 9 

INPUT 0 100 ml 

INPUT E 0.0000 g 

9) Particulate sample mass calculations 

H 

J 

Fron! Half: 

Acetone blank adj. residue v 

Adj. Acetone wash part.wt. 

Front half sample wt. 

10) Front Half Particulate Matter Emission Data 

Filter sample net wt 

Front acetone wash vol. 

Front acetone residue wt. 

Acetone blank vol. 

Acetone blank residue wt. 

0.0000 9 

0.0203 9 

0.0697 9 

E'(8ID) 

C-H 

A+ I 

C[PM] = (Front Half Wt)(g)'" (1Nmstd) w 15.43(grainslg) 

E[PM];:: C[PM] *Vdscfm'" A ~ (60 min/hr) ~ (11b 17000 grains) 

Page 3 

E[PM]lb/MMBtu = E[PMllbfhr~(Fuel HV} scf/Btu"(fuel use) 1 hourlKscf""kscf/1000scf*10"6Btu/MMBlu 

C[PM] = 5.57E-03 grains/dscf 

C[PMJ = 7.95E-07 Ib/dscf 

E[PM] = 7.1631b/hr 

E{PM] = 9.76E-03Ib/MMBtu 

11 )Trace metal concentrations and emission rates 

Element 

Antimony 

Arsenic 

Beryllium 

Cadmium 

Chromium 

Cobalt 

Lead 

Manganese 

Nickel 

Selenium 

C[M] = M[M] (ug) I Vmstd (dscm) 

C[M](lb/dscf) = C[M](ug/dscm) ~ 1e-06gfug ~ 2.205e-03Ib/g ~ 0.02832 dscmfdscf 

E[M](lb/hr) = C[M] (ug/dscm) ~ (2.205E-09) (Ibfug) ~ Qstd (dscmm) '" 60 (min/hr) 

E(M](lb/MMBtu) = C[M](lbfdscf) • Fd ~ (20.9/20.9-%02) 

C[M](@ carr. 02) = C[M] (ug/dscm) ~ [(20.9-corrected %02) I (20.9-actual %02) 1 

Corrected 02 percentage is: 7.0 % 

Sample Conc. Qonc.@cQII QZ Conc. Emission Rate 

Mass (ugj {ugfdscmj {ugfdscmj {Ib/dscf} {lb/hrj 

6.521 1.19E+00 9.97E·01 7.44E-11 6.70E-04 

2.406 4.40E-01 3.68E·01 2.75E-11 2.47E-04 

1.22 2.23E·01 1.87E-01 139E-11 1 25E-04 

0.366 6.69E-02 5.60E-02 4.1BE-12 3.76E-OS 

7.034 1.29E+00 1.08E+00 B.03E·11 7.23E-04 

3.31 6.0SE-01 5.06E-01 3.78E-11 3.40E-04 

S.549 1.01E+00 B.48E-01 6.33E-11 5.70E-04 

5.23 956E·01 8.00E·01 5.97E·11 5. 38E-04 

6.685 1.22E+00 1.02E+OO 7.63E-11 6.B7E-04 

2.37 4.33E-01 3.62E-01 2.71E·11 2.44E-04 

12) Isokinecity, I. 

% I = [100~Ts*(K3~Vlc+«(Vm·Y)fTm"(Pb+(dH/13.6»»]1 (60*t·Ps·Vs*An) 

%1= 103.23 

" <" symbol indicates values given are the quantitative detection limit. 

Emission Rate 

(lb/MMBtuj 

9.131E-07 

3.369E-07 

1.706E-07 

S.12SE-OB 

9.849E-07 

4.635E-07 

7.770E-07 

7.323E-07 

9.361 E-07 

3.319E-07 
3333-TSP-Metals-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps= 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

Dn = 

An = 

y= 

t= 

Ds = 

As= 

Cp = 

Kp= 

K1 = 

K2 = 

K3 = 

Fd = 

[02[ 

[C02) 

[N2) 

AirNova, Inc. 

EPA Methods 1,2,3A,4,5 and 29 

(Flows, 02/C02, H20, TSP and Metals) 

Spruance Genco, LLC 

3333 

Unit No.1 

Three 

04/14/10 

1451·2056 

633.9 cc 

190.479 dcf 

Emission Data 

-0.50 in. H20 

30.51 in. Hg 

30.47 in. Hg 

29.92 in. Hg 

0.6775 in. H20 ".5 

0.882 in. H20 

538.7 R 

655.4 R 

527.7 R 

0.230 in. 

0.000289 sq. fl. 

1.00 

360 min. 

10.30 fl. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.3204 sq. fl. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 f1[(lb/lbmolt(inHg»)".5}/[s·R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.ftIml 

0.0026688 in.Hg-cf/ml-R 

9868 scf/MMBtu 

Instrumental Data 

4.31 %-dry 

14.80 %-dry 

80.89 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1~ Y * Vm * (Pb + dH/13.6) I Tm 

Vmstd = 190.688 dscf 

5.400 dscm 

Unit No. 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std), 

Vw(std) = K2 * Vic 

Vw(std) = 29.838 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwsld I (Vmsld+Vwsld) 

Bws= 0.1353 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = I «44*%C02) + (32*%02) + (28*%N2» * (1-Bws) 1 + (18*Bws) 

Ms= 28.844 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)".5 

Vs = 42.012 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

aa = 60 sec/min * Vs * As 

Oa = 210029.36 cfm 

5948.03 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Oa * (TstdlTs) * (Ps/Pstd) * (1-Bws) 

Qsld= 148937.55 dscfm 

4217.91 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Unit No.1 

Three 

Calculations (cont.) 

8) Particulate Matter Analytical Data 

INPUT A 0.0526 9 

INPUT B 100 ml 

INPUT C 0.0326 9 

INPUT D 100 ml 

INPUT E 0.0000 9 

9) Particulate sample mass calculations 

H 

J 

Front Half: 

Acetone blank adj. residue v 

Adj. Acetone wash part.wt. 

Front half sample wt. 

10) Front Hair Particulate Matter Emission Data 

Filter sample net wt 

Front acetone wash vol. 

Front acetone residue wt. 

Acetone blank vol. 

Acetone blank residue wt. 

0.0000 9 

0.0326 9 

0.0852 9 

E'(BID) 

C-H 

A+ I 

C{PM] = (Front HalfWt)(g) ~ (1Nmstd)" 15.43(grains/g) 

E[PM] = C{PMj" Vdscfm" A ~ (60 min/hr) "(1 Ib 17000 grains) 

Page 3 

E[PM]lb/MMBtu = E[PM]lb/hr*(Fuel HV) set/Btu"(fuel use) 1 hour/kscf*kscf/1000scr10"6Btu/MMBtu 

C{PM] = 6.89E-03 grainsldscf 

C{PM] = 9.85E-07 Ib/dscf 

E[PM] = 8.801 Ib/hr 

E[PM] = 1.22E-02Ib/MMBtu 

11 )Trace metal concentrations and emission rates 

Element 

Antimony 

Arsenic 

Beryllium 

Cadmium 

Chromium 

Cobalt 

Lead 

Manganese 

Nickel 

Selenium 

C[M] = M[M] (ug) I Vmstd (dscm) 

C[M](Jb/dscf) = C[M](ug/dscm) " 1e-06g/ug" 2.205e-03Ib/g;O 0.02832 dscm/dscf 

E[M](lb/hr) = C[M] (ug/dscm) • (2.205E-09) (Ib/ug)" Qstd (dscmm) "60 (min/hr) 

E[M](lb/MMBtu) = C{M](lb/dscf) " Fd * (20.9120.9-%02) 

C[M](@corr. 02) = C{M] (ug/dscm)'" [(20.9-corrected %02) I (20.9-actual %02) ] 

Corrected 02 percentage is: 7.0 % 

Sample Conc. Conc.@corr. 02 Conc. Emission Rate 

Mass (ug) (ug/dscm) (ug/dscm) (Ib/dscfl (lb/hr) 

4.235 7.84E-01 6.57E-01 4_90E-11 4.38E-04 

2.96 5.48E-01 4.59E-01 3.42E-11 306E-04 

1.34 2.48E-01 2.08E-01 1.55E-11 138E-04 

0.739 1.37E-01 1.15E-01 8.55E-12 7.64E-05 

8.522 1.58E+OO 1.32E+00 9.85E-11 8.81E-04 

3.59 6.65E-01 5.57E-01 4.15E-11 3.71E-04 

6.088 1.13E+00 9.45E-01 7.04E-11 6.29E-04 

6.503 1.20E+OO 1.01E+00 7.52E-11 6.72E-04 

8.001 1.48E+00 1.24E+00 9.25E-11 8.27E-04 

3.07 5.68E-01 4.76E-01 3.55E-11 3.17E-04 

12) Isoklneclty, I. 

% 1 = [100*Ts"(K3"Vlc+«{Vm"Y)fTm)"(Pb+(dH/13.6))))] I (60*t*Ps"Vs*An) 

%1= 102.71 

" <" symbol indicates values given are the quantitative detection limit. 

Emission Rate 

(lb/MMBtuj 

6.088E-07 

4.255E-07 

1.926E-07 

1.062E-07 

1.225E-06 

5.161E-07 

B.752E-07 

9.348E-07 

1.150E-06 

4.413E-07 
3333-Hg-unspiked-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

Tm= 

INPUT Ts = 

INPUT Tstd= 

INPUT y= 

INPUT t = 

INPUT Ds= 

INPUT 

INPUT 

INPUT 

As= 

Kp = 

K1 = 

K2= 

K3= 

Fd· 

[02[ 

[C02[ 

[N2] 

AirNova, Inc. 

EPA Method 1, 2, 3A, and 308 - Unspiked Tube 

(Flows, 021C02, and Mercury) 

Spruance Genco, LLC 

3333 

Unit No.1 

One 

04/13/10 

1601-2216 

Emission Data 

8.879 dcf 

-0.50 in. H2O 

30.38 in. Hg 

30.34 in. Hg 

29.92 in Hg 

524.5 R 

655.5 R 

527.7 R 

1.000 

360 min 

10.30 ft. 

Dry gas meter reading 

Static presSure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration faclor 

Duration of sampling time 

Diameter of Stack 

83.32043375 sq. ft. Cross sectional area of stack 

85.49 ft[(lb/lbmol)*(inHg)l". 5}/1 s*R*1 n H20] 

17.637 R/in.Hg 

0.047070 cU.fVml 

0.0026688 in.Hg·cf/ml·R 

9862 scf/MMBtu 

Instrumental Data 

4.21 %-dry 

1632 %-dry 

79.47 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions. Vmstd. 

Vmstd =K1~ Y * Vm " Pbl Tm 

Vmstd = 9.071 dscf 

0.2569 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws = 

Bws = 

Based on the M29 sampling train 

0.1271 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No.1 

One 

Ms = [«44"%C02) + (32*%02) + (28*%N2)) " (1-Bws) ] + (18*Bws) 

Ms= 29.155 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs= 

Vs = 

Based on the M29 sampling train 

42647 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 secJmin " Vs * As 

Oa = 213201.99 cfm 

6037.88 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Ostd = Qa * (TstdlTs) ~ (Ps/Pstd) * (1·Bws) 

Qstd = 151939.41 dscfm 

4302.92 dscmm 

8) Mercury concentrations and emission rates 

C[M] = M[M] (ug) 1 Vmstd (dscm) 

C[M](Ib/dscf) = C[M](ug/dscm) • 1 e-06g/ug· 2.205e-03Ib/g • 0 02832 dscm/dscf 

E[M](lb/hr) = C[MJ (ug/dscm) " (2 205E·09) (Ib/ug) "Qstd (dscmm) ~ 60 (min/hr) 

E[M](Ib/MMBtu) = C[MJ(lb/dscf) • Fd " (20.9/20.9-%02) 

Element 

Mercury 

C[M](@ corr. 02) = C[M] (ug/dscm) " ( (20.9-corrected %02) 1 (20.9-actual %02) ] 

Corrected 02 percentage is' 7 % 

Sample 

Mass (ug) 

0.0011 

Conc. 

(ug/dscm) 

0.004 

Conc.@corr. 02 

(ug/dscm) 

0.004 

Conc. 

(lb/dscfl 

2.67E-13 

Emission Rate 

(Ib/hr) 

2,44E-06 

Page 2 

Emission Rate 

(lb/MMBtu) 

3.30E-09 
3333-Hg-unspiked-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

Tm = 

INPUT Ts = 

INPUT Tstd= 

INPUT Y = 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

t= 

Ds= 

As = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

[02[ 

[C02] 

[N2] 

AirNova, Inc. 

EPA Method 1, 2, 3A, and 30B - Unspiked Tube 

(Flows, 02/C02, and Mercury) 

Spruance Genco, LLC 

3333 

Unil No.1 

Two 

04/14/10 

0739-1354 

Emission Data 

7.791 dcf 

-0.50 in. H2O 

3057 In. Hg 

30.53 in. Hg 

29.92 in. Hg 

520.5 R 

658.2 R 

527.7 R 

1.000 

360 min. 

10.30 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83.32043375 sq. ft. Cross sectional area of stack 

85.49 ft[(lbllbmol)·(inHg)]".5}I[s·R·inH20] 

17.637 R/in.Hg 

0.047070 cu.ftlml 

0.0026688 in.Hg-cf/ml-R 

9755 scf/MMBtu 

Instrumental Data 

4.28 %·dry 

14.82 %-dry 

80.90 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client Spruance Genco, LLC Test Location 

Project No. 3333 Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmsld =K1· Y· Vm· Pb/ Tm 

Vmsld = 8.070 dscf 

0.2286 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws = 

Bws = 

Based on the M29 sampling tram 

0.1326 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No. 

Two 

Ms = I «44~%C02) + (32~%02) + (28~%N2»· (1-Bws)] + (18*Bws) 

Ms= 28.879 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs = 

Vs = 

Based on the M29 sampling tram 

42.326 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min" Vs " As 

Qa= 211597.24cfm 

5992.43 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Oa • (TstdfTs) " (Ps/Pstd) * (1-Bws) 

Ostd = 150165.40 dscfm 

4252.68 dscmm 

8) Mercury concentrations and emission rates 

C[MI • MIMI (ug) I Vmstd (dscm) 

C[M]{Ib/dscf) = C[M]{ug/dscm) 0; 1e-06g/ug" 2.205e-03Ib/g" 0 02832 dscm/dscf 

E[M](lb/hr) = C[M] (ug/dscm) " (2.205E-09) (Ib/ug) " Qstd (dscmm) "60 (min/hr) 

E[M](lb/MMBtu) = C[M](Ib/dscf) " Fd • (20.9/20.9-%02) 

Element 

Mercury 

C[M](@ carr. 02) = C[M] (ug/dscm) " [ (20.9-corrected %02) / (20 9-actual %02) 1 

Corrected 02 percentage is: 7 % 

Sample 

Mass (ug) 

0.0039 

Conc 

(ug/dscm) 

0.017 

Cone@eorr. 02 

(ug/dscm) 

0.014 

Conc. 

(lb/dscO 

1.07E-12 

Emission Rate 

Clb/hr) 

9.BOE-OB 

Page 2 

Emission Rate 

(lb/MMBtu) 

1.31 E-08 
3333-Hg-unspiked-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

Tm = 

Ts= 

Tsld= 

y= 

t= 

Ds = 

As = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Method 1, 2, 3A, and 30B· Unspiked Tube 

(Flows, 02/C02, and Mercury) 

Spruance Genco, LLC 

3333 

Unit No.1 

Three 

04114110 

1451-2056 

Emission Data 

6.924 dcf 

-0.50 in H20 

30.51 in. Hg 

30.47 in. Hg 

29.92 In. Hg 

537.1 R 

655.4 R 

527.7 R 

1.000 

360 min. 

10.30 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83.32043375 sq. ft. Cross sectional area of stack 

85.49 fi[ (Ib/lbmol)* (inHg)]" . 5}1[ s ·R"*in H20] 

17.637 R/in.Hg 

0.047070 cu.fUml 

0.0026688 in.Hg-cf/ml-R 

9868 scf/MMBtu 

Instrumental Data 

4.31 %-dry 

14.80 %-dry 

80.89 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client Spruance Genco, LLC Test Location 

Project No. 3333 Test Run 

Calculations 

1) Volume of gas sampled at standard conditions. Vmstd. 

Vmstd =K1~ Y ~ Vm ~ Pb/ Tm 

Vmstd = 8.941 dscf 

0.2532 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws= 

Bws= 

Based on the M29 sampling Irain 

0.1353 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No.1 

Three 

Ms = [«44~%C02) + (32·%02) + (28~%N2))" (1·Bws)] + (18"Bws) 

Ms= 28.844 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs = 

Vs = 

Based on the M29 sampling train 

42.025 fps 

6) Average actual stack gas volumetric f1owrate, Qa. 

Oa = 60 sec/min" Vs .. As 

Oa = 210092.47 cfm 

5949.82 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Ostd = Oa" (TstdfTs)" (PslPstd)· (1·Bws) 

Ostd = 148975.07 dscfm 

4218.97 dscmm 

8) Mercury concentrations and emission rates 

C[M] = M[M] (ug) / Vmstd (dsem) 

C[M]{lb/dscf) = C[M](ug/dscm)" 1e·06g/ug" 2.205e-03Ib/g" 0.02832 dscm/dscf 

E(M](lb/hr) = C[M} (ug/dscm) .. (2.20SE-09) (Ib/ug) .. Ostd (dscmm) .. 60 (min/hr) 

E[MJllbIMMBtu) = C[M](lbldsc0 • Fd • (20.9120 9-%02) 

C[M](@corr. 02) = C[M] (ug/dscm) "[ (20.9·corrected %02) / (20.9·actual %02)] 

Corrected 02 percentage is: 7 % 

Page 2 

Sample 

Mass (ug) 

0.0012 

Cone. 

(ug/dscm) 

0.005 

Conc.@corr. 02 

(ug/dscm) 

0.004 

Cone. 

(Ib/dsef) 

2.96E-13 

Emission Rate Emission Rate 

Element 

Mercury 

(Ib/hrl (lb/MMBlu) 

2.65E-06 3.68E·09 
M7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco,LLC 

3333 

Unit No.1 

04115110 

Parameter: Oxygen 

Instrument SQ.an f% 021: 22.03 

Actual CalibratiQn Gas Value (% 021: 

Ang/\::zer Calibration Rfj.sQ.onse ('M! 021. 

Analvzer Calibration ErroL(% Span): 

Zero S~stem Calibration Gas 

At2Qarent Init. SI§. fnit $):,5. Final $1:::8. Final SI@. 

Slack ~ Cal. Bias Calib. Cal. Bias 

Run Cone. Response (% span) Response (% span) 

1 9.33 0.12 0.45 0.06 0.18 

2 13.30 0.06 0.18 0.00 -0.09 

3 12,91 0.00 -0.09 0.07 0.23 

4 0.00 007 0.23 0.00 -0.09 

5 0,00 0.00 -0.09 0.00 -0.09 

6 0.00 0.00 -0.09 0.00 -0.09 

7 0.00 0.00 -0.09 0.00 -0.09 

8 0.00 0.00 -0.09 0.00 -0.09 

g 0.00 0.00 -0.09 0.00 -0.09 

10 0.00 0.00 -0.09 0.00 -0.09 

11 0.00 0.00 -0.09 0.00 -0.09 

12 0.00 0.00 -0.09 0.00 -0.09 

AirNova, Inc. Page 1 

EPA Method 6e Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Ana/\::zfj:f Calib, Gases Uascafe 

zero low mid high $\,:5. Qa!. Gas 

0.00 NIA 11.90 22.03 11,90 

0.02 NIA 12.02 21.97 11.90 

0.09 0.00 0.54 -027 

U[!scale Sy:stem Ci!;libration Gas 

Calib. lait. $1::5. Init. S\,:s. Final S!!s. Fingl $\,:s. Ca/ib. Actual 

Drift Calib. Cal. Bias Calib. (2el. Bias Drift Stack 

(% span) Response (% soan) Response (% span) (% span) Cone. 

-0.27 11.91 0.05 11.96 0.27 0.23 9.28 

-0.27 11.96 0.27 12.00 0.45 0.18 13.21 

0.32 12.00 0.45 12.00 0.45 0.00 12.81 

-0.32 12.00 0.45 0.00 -54.02 -54.47 -0.07 

0.00 0.00 -54.02 0.00 -54.02 0.00 ERR 

0.00 0.00 -54.02 0.00 -54.02 0.00 ERR 

0.00 0.00 -54.02 0.00 -54.02 0,00 ERR 

0.00 0.00 -54.02 0.00 -54 02 0.00 ERR 

0.00 000 -54.02 0.00 -54.02 000 ERR 

0.00 0.00 -54.02 0.00 -54.02 0.00 ERR 

0.00 0.00 -54.02 0.00 -54.02 0.00 ERR 

0.00 0.00 -54.02 0.00 -54.02 0.00 ERR 
M7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco,LLC 

3333 

Unit No.1 

04/15110 

Parameter: 

Instrument Span (% C02!: 

Carbon Dioxide 

22.28 

Actual Calibration Gas Value (% C02)" 

Analyzer Calibration Response (% C021: 

Analyzer Calibration EfTor t% Span): 

Zero Sy:stem Calibration Gas 

Am.!8[f!nt lnit. Sys. Init. $)!S_ Final S):::s. FinfJ.1 S\"s. 

Stack Galib. Cal. Biail Galib. Cal. Bia~ 

Run Conc. Response (% span) Response (% span) 

9.96 -0.12 -0.54 0.00 0.00 

2 6.37 0.00 0.00 -0_12 -0.54 

3 6.85 -0.12 -0.54 -0.12 -0.54 

4 0.00 -0.12 -0.54 0_00 0.00 

5 000 0.00 0.00 0.00 0.00 

6 0_00 0_00 0.00 0.00 0.00 

7 0.00 0_00 0.00 0.00 0.00 

8 0.00 0.00 0.00 0.00 0.00 

9 0.00 0.00 0.00 0.00 0_00 

10 0.00 0.00 0.00 0.00 0.00 

11 0.00 0.00 0.00 0.00 0.00 

12 0.00 0.00 0_00 0.00 0.00 

AirNova, Inc. Page 2 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Analyzer Galib. Gases Upscale 

"'-0 low mid high Sys. Cal. Ga~ 

0.00 N/A 12.38 22.28 12.38 

0.00 N/A 12.21 22.34 12.38 

0.00 0.00 -0]6 0.27 

URscale Sy:stem Calibration Gas 

Ga/ib. Init Sys. Init. S!!s. Final Sys. Final Sys Galib. Actual 

Drift Galib. Cal. Bias Gal/b_ CaL Bias On'lt Stack 

(% span) Response (% span) Response (% span) (% span) Conc_ 

0.54 12_33 -0.22 12.33 -022 0.00 10.01 

-0.54 12.33 -0.22 12.45 0.31 0.54 6.39 

0.00 12.45 0.31 12.45 0.31 0.00 6.86 

0.54 12.45 0.31 0.00 -55.57 -55.88 0.12 

0.00 0_00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55_57 0.00 -55.57 0.00 ERR 

0_00 0.00 -55_57 0.00 -55.57 0_00 ERR 

0_00 0.00 -55.57 0.00 -55.57 0_00 ERR 

0_00 0.00 -55.57 0.00 -5557 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0_00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 
M7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco,LLC 

3333 

Unit No.1 

04/15/10 

Parameter: Carbon Monoxide 

Instrument Span (pDmV CO): 935.7 

Actua! Calibration Gas Value (ppmV CO): 

Analyzer Calibration Response topmV CO): 

Analyzer Calibration Error (% Spanl: 

Zero Sy:stem Calibration Gas 

AQQarent Init. S!!s. Init. Sys. Final SI:§:. Final Sys 

Stack CaNb. Cal. Bla~ Cafib. Cal. Bias 

Run = Response (% span) Response (% span) 

1 1362.3 -4.9 0.00 -4.9 0.00 

2 583.5 -4.9 0.00 -4.9 0.00 

3 390.6 -4.9 0.00 -4.9 0.00 

4 0.0 -4.9 0.00 0.0 0.52 

5 0.0 0.0 0.52 0.0 0.52 

6 0.0 0.0 0.52 0.0 0.52 

7 0.0 0.0 0.52 00 0.52 

8 00 0.0 0.52 0.0 0.52 

9 0.0 0.0 0.52 0.0 0.52 

10 0.0 0.0 0.52 0.0 0.52 

11 0.0 0.0 0.52 0.0 052 

12 0.0 0.0 0.52 0.0 052 

AirNova, Inc. Page 3 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Analyzer CalilJ.. Gases U{2scale 

zero low mid high Sk':S. Cal. Gas 

0.0 0.0 486.0 935.7 486.0 

-4.9 0.0 488.0 933.0 486.0 

-0.52 0.00 0.21 -029 

URscale Sy:stem Calibration Gas 

CaNb. Ini!. S'i.s. Init. Sys. Fingl Sys, Final Sys. Calib. Actual 

On' Calib. Cal. Bi!3.§ Calib_ Cal. Bias Drift Stack 

(% span) Response (% span) Response (% span! (% span) Cone. 

0.00 479.0 -0.75 479.0 -0.75 000 1373.1 

0.00 479.0 -0.75 493.0 0.75 1.50 582.5 

0.00 493.0 0.75 474.0 -1.28 -2.03 393.6 

0.52 474.0 -1.28 0.0 -51.94 -50.66 5 .• 

0.00 00 -51.94 00 -51.94 0.00 ERR 

0.00 0.0 -51.94 00 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 000 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 00 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 
M7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance GenCO,LLC 

3333 

Unit No.1 

04/15110 

Parameter: Total Hydrocarbons (as 

Instroment Span (ppm V THCJ: 20 

Actual Calibration Gas Value (ppmV THCJ: 

Analyzer Calibration Response fppmV THC!: 

AnalyzerCa1ibrafion Error (% Cal. Gas Value): 

Zero S~stem Calibralion Gas 

AQQarent Init. S)(S. mit. S:I:§. Final Sys. Fma/.5:\"s. 

Stack Calib. CaL. Bias Calib. Cal. Bias 

Run ~ Response (% span) Response (% span) 

1 6.9 -0.1 0.00 0.3 2.00 

2 5.0 0.3 2.00 0.0 0.50 

3 3.5 0.0 0.50 0.2 1.50 

4 0.0 0.2 1.50 0.0 0.50 

5 0.0 0.0 0.50 0.0 0.50 

6 0.0 0.0 0.50 0.0 0.50 

7 0.0 0.0 0.50 0.0 0.50 

8 0.0 0.0 0.50 0.0 0.50 

9 0.0 00 0.50 00 0.50 

10 0.0 0.0 0.50 0.0 0.50 

11 0.0 0.0 0.50 0.0 0.50 

12 0.0 0.0 0.50 0.0 0.50 

AirNova, Inc. Page 4 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

CH4 ) 

Anal\"zer Callb. Ga~es UQ.scale 

zero !illx mid high SlI:s. Ca'- Gas 

0.0 4.9 9.1 17.4 9.1 

-0.1 4.9 9.1 17.3 9.1 

0.41 0.11 -0.57 

Ugscale Sl/stem Calibration Gas 

Gallb. Init· S):':S. Init. Sl!s. Final S!:,:s. Final S)@. Calib. Actual 

Drift Galib, Cal. BIB§. Callb. Cal. Bias Drift Stack 

(% span) Response (% span) Response (% span) (% span) Cone. 

2.00 4.9 -20.95 4.9 -20.95 0.00 12.9 

-1.50 4.9 -20.95 5.0 -20.45 0.50 9.2 

1.00 5.0 -20.45 4.9 -20.95 -0.50 6.4 

-1.00 4.9 -20.95 00 -45.45 -24.50 ·0.4 

0.00 0.0 -45.45 0.0 -45.45 0.00 ERR 

0.00 0.0 -45.45 0.0 -45.45 0.00 ERR 

0.00 0.0 -45.45 0.0 -45.45 0.00 ERR 

0.00 0.0 -45.45 0.0 -45.45 0.00 ERR 

0.00 0.0 -45.45 0.0 -45.45 0.00 ERR 

0.00 0.0 -45.45 0.0 -45.45 0.00 ERR 

0.00 00 -45.45 0.0 -45.45 0.00 ERR 

0.00 00 -45.45 00 -45.45 0.00 ERR 
3333-Formaldehyde-R 1 

Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

Vlc= 

Vm= 

Pstatic = 

Pb= 

Ps= 

Pstd = 

dP = 

dH = 

Tm· 

Ts = 

Tstd= 

y= 

t= 

Dn = 

An = 

Ds = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

CF = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2.3A,4,and RCRA Method 0011 

(Flows, 02/C02, H20, and Formaldehyde) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit No.1 

04/15/10 

One 

1130-1336 

Emission Data 

317.2 cc 

89.740 dcf 

-0.50 in. H20 

30.39 in. Hg 

30.35 in. Hg 

29.92 in. Hg 

0.639 in. H20 ".5 

1.81 in. H20 

538.8 R 

674.4 R 

527.7 R 

1.00 

120 min. 

0.296 in. 

0.000478 sq. ft. 

10.30 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meier temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 Pilot tube coefficient 

85.49 ft[(lb/lbmol)*(mHg)]".5}/[s"R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.fVml 

0.0026688 in.Hg-cf/ml-R 

9862 scf/MMBtu 

7.793E-08 Ib/dscf 1 ppmVd 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for CH20 

EPA Method 3A Instrumental Data 

9.28 %-dry 

10.01 %-dry 

80.71 %-dry 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Data from' 

EPA4 

EPA4 

EPA 2 

EPA 2 

EPA2 

EPA4 

EPA4 

EPA2 

EPA2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmsld =K1* Y * Vm '" (Pb + dH/13_6) I Tm 

Vmsld = 89,666 dscf 

2.539 dscm 

Richmond, Virginia 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2" Vic 

Vw(std) = 14.931 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws = 0.1427 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44*%C02) + (32*%02) + (2S*%N2)) * (1-Bws) I + (1S*Bws) 

Ms = 28.264 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp" Cp,o (dP) " (Ts/Ps*Ms)".5 

Vs = 40.670 fps 

6) Average actual stack gas volumetric f1owrate, Oa. 

Oa = 60 sec/min· Vs " As 

Oa= 20331981 cfm 

5758,02 cmm 

7) Average stack gas dry volumetric flowrate, Qsld. 

Qstd = Oa" (TstdfTs)" (Ps/Pstd)" (1-Bws) 

Qsld = 138364.38 dscfm 

Qstd = 3918.48 dscmm 

Page 2 
Client Spruance Genco, llC 

Project No. 3333 

Test location 

Test Run 

Calculations (cont.) 

8) Formaldehyde - Concentrations and EmissIon Rates 

M[CH20] = sample mass (mg) 

Richmond, Virginia 

One 

C[CH20] = M[CH20] (mg) / sample volume (dscm) 

C[CH20 @ corr. %021 = C[CH20] (ppmV) * (20 9-Corr. %02)/(20.9-Actual %02) 

Corrected 02 Percentage = 7 % 

Page 3 

E[CH20] = C[CH20] (mg/dscm) * 60 (minlhr) * Qstd {dscmm);O; (1 Ib 14.536 e+05 mg) 

E[CH20](lb/MMBtu) = C[CH20]{ppmV) CF * Fd * (20.9/20.9-%02) 

Compound Sample Mass Concentration Concentration Concentration Mass Emission 

ll:!:!9l (mg/dscm) !mmJlil pmV@Corr.%O (Ib/hr) 

Formaldehyde 0.20600 0.081 0065 0078 0.042 

9) Isokinecity, I. % 1= [100,oTs*(K3*Vlc+«{Vm*Y)fTm)*(Pb+(dH/13.6))))] I (60*t*Ps·Vs*An) 

%1= 94.16 

Mass Emission 

(lb/MMBtu) 

8.98E-OS 
3333-Formaldehyde-R2 

Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

Vlc= 

Vm= 

Psratic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm'" 

Ts= 

Tstd= 

y= 

t= 

On = 

An = 

Os = 

As = 

Cp = 

Kp '" 

K1 = 

K2 '" 

K3 '" 

Fd '" 

CF '" 

[02[ 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and ReRA Method 0011 

(Flows, 02/C02, H20, and Formaldehyde) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit No 1 

04/15/10 

Two 

1440-1653 

Emission Data 

271.6 cc 

82.242 def 

-0,50 in. H2O 

30.32 In, Hg 

30.28 in Hg 

29,92 in Hg 

0.706 in H20 ".5 

1.37 in H2O 

555.2 R 

638.5 R 

527,7 R 

1,00 

120 min. 

0.250 in. 

o 000341 sq. ft. 

1030 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]".5}/[s~R"lnH201 Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu,fUml 

0.0026688 in.Hg-cf/ml-R 

9755 scf/MMBtu 

7.793E-08 Ib/dscf I ppmVd 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for CH20 

EPA Method 3A Instrumental Data 

13.21 %-dry 

6.39 %-dry 

80.40 %-dry 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Data from: 

EPA4 

EPA4 

EPA 2 

EPA2 

EPA2 

EPA4 

EPA4 

EPA2 

EPA2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y· Vm * (Pb + dH/13.6) I Trn 

Vmstd = 79.482 dscf 

2.251 dscm 

Richmond. Virginia 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 12.784 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1386 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32*%02) + (28*%N2»;O (1-Bws)] + (18*Bws) 

Ms= 27.9501b/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp· Cp * (dP) * (Ts/Ps*Ms)" 5 

Vs = 44.015 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min· Vs • As 

Qa = 220041 58 cfm 

6231 58 cmm 

7) Average stack gas dry volumetric f1owrate, Qstd. 

Qstd = Qa • (TstdfTs) • (Ps/Pstd) • (1-Bws) 

Qstd = 158573.91 dscfm 

Qstd = 4490.81 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Richmond, Virginia 

Two 

8) Formaldehyde· Concentrations and Emission Rates 

M[CH20] = sample mass (mg) 

C[CH20] = M[CH20] (mg) 1 sample volume (dscm) 

C[CH20 @ corr. %02] = C[CH20] (ppmV) ~ (20_9-Corr. %02)/(20 9-Aclual %02) 

Corrected 02 Percentage = 7 % 

E[CH20] = C[CH20] (mg/dscm)" 60 (min/hr) "Qstd (dscmm)" (1 Ib /4.536 e+05 mg) 

E[CH20]{lb/MMBtu) = C[CH201{ppmV) CF" Fd ~ (20.9/20.9-%02) 

Page 3 

Compound Sample Mass Concentration Concentration Concentration Mass Emission Mass Emissjon 

{!!llll (mq/dscm) {QruJ:)Yl 'pmV@Corr.%O (Ib/hr) (lb/MMBlu) 

Formaldehyde 0.05600 0.025 0.020 0_036 0.015 4 12E-05 

9) Isokineclty, I % I = [100*Ts*{K3*Vlc+«(Vm*Y)fTm)*(Pb+(dH/13.6))))] 1 (60''l*Ps·Vs*An) 

% I = 102.10 
3333-Formaldehyde-R3 

Client 

Project No. 

Test location 

Emission Source 

Test Date 

Test Run 

Time Period 

Vlc= 

Vm= 

Pstatic = 

Pb= 

Ps= 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

y= 

t= 

Dn = 

An = 

Ds = 

As = 

Cpo 

Kp= 

K1 = 

K2 = 

K3 = 

Fd = 

CF = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and RCRA Method 0011 

(Flows, 02/C02, H20, and Formaldehyde) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit No.1 

04/15/10 

Three 

1812-2022 

Emission Data 

278.2 cc 

82.782 dcf 

-0.50 in. H20 

30.24 in. 

30.20 in. 

29.92 in. 

0.706 in. 

1.41 in. 

548.4 R 

641.5 R 

527.7 R 

1.00 

H9 

H9 

H9 

H20h.5 

H2O 

120 min. 

0.250 in. 

0.000341 sq. ft. 

10.30 ft 

Vol of H20 collected 

Dry gas meter reading 

Slatic pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

DIameter of stack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*{inHg)jh.5}/[s*R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.Wml 

0.0026688 in.Hg-cf/ml-R 

9868 scf/MMBtu 

7.793E-OB Ib/dscf I ppmVd 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for CH20 

EPA Method 3A Instrumental Data 

12.B1 %-dry Oxygen concentration 

6.86 %-dry Carbon Dioxide concentration 

80.33 %-dry Nitrogen concentration 

Data from: 

EPA4 

EPA4 

EPA 2 

EPA 2 

EPA2 

EPA4 

EPA4 

EPA2 

EPA2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard condillons, Vmstd. 

Vmstd =K1" Y " Vm .. (Pb + dH/13.6) / Tm 

Vmstd = 80.791 dscf 

2.288 dscm 

2) Volume of water vapor collected at standard conditions, Vw(std) 

Vw(Sld) = K2 .. Vic 

Vw(std) = 13.095scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1395 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Richmond. Virginia 

Three 

Ms = [«44*%C02) + (32·%02) + (28*%N2»" (1-Bws) 1 + (1S*Bws) 

Ms= 27.991 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp .. Cp" (dP) " (Ts/Ps·Ms)".5 

Vs = 44170 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min" Vs .. As 

Oa = 220815.76 cfm 

6253.50 cmm 

7) Average stack gas dry volumetric fJowrate, Qstd. 

Qstd = Oa" (TstdfTs)" (Ps/Pstd)" (1-Bws) 

Qstd = 157800.68 dscfm 

Qstd = 4468.92 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Formaldehyde - Concentrations and Emission Rates 

M[CH20] = sample mass (mg) 

Richmond. Virginia 

Three 

C[CH20] = M[CH20] (mg) 1 sample volume (dscm) 

C[CH20 @corr. %02] = qCH20] (ppmV) • (20.9-Corr. %02)1(20.9-ActuaJ %02) 

Corrected 02 Percentage = 7 % 

E[CH20] '" C[CH20] (mg/dscm) .. 60 (min/hr) * Qstd (dscmm) * (1 Ib 14.536 e+05 mg) 

E[CH20](lb/MMBtu) = C[CH20](ppmV) CF ~ Fd .. (20.9/20.9-%02) 

Page 3 

Compound Sample Mass Concentration Concentration Concentration Mass Emission Mass Emission 

irr!.9l (mq/dscm) (QQrffiQ. 'pmV@Corr.%O (Ib/hr) (lb/MMBtu) 

Formaldehyde 0.02870 0.013 0.010 0.017 0.007 2.00E-05 

9) Isokinecity, I. % I = [100~Ts*(K3·Vlc+«(Vm·Y)fTm)"(Pb+(dH/13.6))))]1 (60*t*Ps·Vs*An) 

%1= 104.29 
Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatlc = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

y= 

t= 

On = 

An = 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[02[ 

[C02[ 

[N2] 

{COl 

{THC[ 

[CH4[ 

AirNova, Inc. Page 1 of 3 

EPA Methods 1, 2, 3A, 4,10,18 and 25A 

(Flows, 02/C02, H20, CO and NMHC) 

Spruance Genco, LLC 

3333 

Richmond, VIrginia 

Unit No.1 

04/15/10 

00. 

1130-1336 

Emission Data 

317_2 cc 

89.740 dcf 

-0.50 in. H20 

30.39 in, Hg 

3035 in. Hg 

29.92 in, Hg 

0.6388 in. H20 A 5 

1 81 in, H2O 

538.8 R 

674.4 R 

527.7 R 

1,00 

120 min. 

0.296 in. 

0.000478 sq, ft 

10.300 ft. 

Vol of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

83.3204 sq_ ft Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft.[(1bjlbmol)·(inHgW.5}/[s~R·inH201 

17.637 R/in.Hg constant 

0047070 cU.ftlml 

0.0026688 in.Hg-cf/ml-R 

9862 scf/MMBtu 

Instrumental Data 

9,28 %-dry 

10.01 %-dry 

80.71 %-dry 

1373.1 ppmV-dry 

12 9 ppmV-wet 

28.9 ppmV-dry 

constant Pitot tube constant 

constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentratlon 

Nitrogen concentration 

Carbon Monoxide concentration 

Total Hydrocarbon concentration 

Methane Concentration by GC-FID 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Emission Source Unit No.1 

Test Run One 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1" Y" Vm,o (Pb + dH/13.6) / Tm 

Vmstd = 89.666 dscf 

2.539 dscm 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2" Vic 

Vw{std) = 14.931 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1427 

4) Molecular weight of the stack gas on a wet basis. Ms. 

Ms = [«44"%C02) + (32*%02) + (28*%N2» * (1-Bws) 1 + (18*Bws) 

Ms = 28.264 Ib/lbmole 

5) Average stack gas velocity. Vs. 

Vs = Kp " Cp " (dP) * (Ts/Ps*Ms)" 5 

Vs = 40.670 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/mm " Vs • As 

Qa = 203319.8 cfm 

5758.0 cmm 

7) Average stack gas dry vOlumetric flowrate, Qstd. 

Qstd = Qa" (TstdlTs),o (Ps/Pstd)" (1-Bws) 

Qstd = 138364.4 dscfm 

3918.5 dscmm 

Page 2 of 3 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.1 

One 

Page 3 of3 

8) Total Hydrocarbon concentrations and emissions 

INPUT 

C[THC] dry basIs = C[THC] wet/(1-Bws) 

C[VOC] dry basis = C[THC] - C[CH4] 

Corr. crCH4] = ({20.9-02% corr. value)/(20.9-actual avg. 02% value»"VOC value 

E[VOC] = (C[VOC]*Mol Wt[VOC equivalent]*60(min/hr)*Qstd(dscfm))/(Molar Vol. air*10"6) 

E[VOC Ib/MMBtu] = Cd;O Fd" (20.9/(20.9-actual 02%)) 

C[THC] = 12.9 ppmVw 

C[THC] = 15.0 ppmVd 

C[CH4] = 28.9 ppmVd 

C[VOC] = -13.9 ppmVd 

C[VOC] = -16.6 ppmVd corrected 10 7 % 02 

Mol. WI. [THCJ= 44.096 Ib/lb-mole 

Molar vol air= 385 scf/lb·mole @ 

Propane 

68 def F 

E[VOC] = -13.17 Ib/hr 

Conv Factor. 

E]VOC] = 

4.134E·oa convert ppmV to Ib/scf THC as CH4 

-1.02E·02 Ib/MMBtu 

9) Carbon Monoxide concentrations and emissions 

Corr. C[CO] = «20.9·02% corr. value)/(20.9·actual avg. 02% value»·Avg. raw CO value 

E[CO Ib/hr] = (C[CO]*Mol Wt[CO]*60(min/hr)*Qstd(dscfm»/(Molar Vol. air*10"6) 

E[CO Ib/MMBtu] = Cd" Fd ~ (20.9/(20.9-aclual 02%» 

C[CO] = 1373.1 ppmVd 

qCO] = 1642.5 ppmVd corrected to 7 % 02 

Mol. Wt. [CO]= 28.01 Ib/lb-mole 

Molar vol airE]CO] = 

Conv Factor. 

E[CO] = 

385 scf/lb-mole @ 

829.34 Ib/hr 

7.235E-08 convert ppmV to Ib/scf CO 

1.762 Ib/MMBtu 

68 def F 
Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

INPUT Tstd= 

INPUT y = 

INPUT t = 

INPUT On = 

An = 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[O2[ 

[C02[ 

[N2] 

[COr 

[THC[ 

[CH4] 

AirNova, Inc. 

EPA Methods 1, 2, 3A,4, 10, 18 and 25A 

(Flows, 02/C02, H20, CO and NMHC) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit No.1 

04/15/10 

Two 

1440-1653 

Emission Data 

271.6 cc 

82.242 dcf 

-0.50 in. H2O 

30.32 in. Hg 

30.28 in. Hg 

29.92 in. Hg 

0.7057 in. H20 ".5 

1.37 in. H2O 

555.2 R 

638.5 R 

527.7 R 

1.00 

120 min. 

0.250 in. 

0.000341 sq. ft.. 

10300 ft 

83.3204 sq. ft.. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Slack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft. gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)}".5}/[s*R*inH20] 

17.637 R/in Hg constant 

Page 1 of 3 

0.047070 cu.ft/ml constant Pitot tube constant 

0.0026688 in Hg-cf/ml-R 

9755 scf/MMBtu 

Instrumental Data 

13.21 %-dry 

6.39 %-dry 

80.40 %-dry 

582.5 ppmV-dry 

9.2 ppmV-wet 

13.6 ppmV-dry 

constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentratLon 

Nitrogen concentration 

Carbon Monoxide concentration 

Total Hydrocarbon concentration 

Methane Concentration by GC-FID 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Emission Source Unit No. 1 

Test Run Two 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1*Y"Vm * (Pb + dH/13.6) ITm 

Vmstd = 79.482 dscf 

2.251 dscm 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw{sld) = K2 ,. Vic 

Vw{std) = 12.784 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 01386 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [({44*%C02) + (32*%02) + (28*%N2)) * (1-Bws) 1 + (18*Bws) 

Ms = 27.950 Ib/lbmole 

S) Average stack gas velocity, Vs. 

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)".5 

Vs = 44.015 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min * Vs ,. As 

Qa = 220041.6 cfm 

6231.6 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa * (TstdlTs) * (Ps/Pstd) * (1-Bws) 

Qsld = 158573.9 dscfm 

4490.8 dscmm 

Page 2 of 3 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.1 

Two 

Page 3 of 3 

8) Total Hydrocarbon concentrations and emissions 

INPUT 

C[THC] dry basis = C[THC] wet/(1-Bws) 

C[VOCJ dry basis = C[THC] - C[CH4] 

Carr. C[CH4] = «20.9-02% carr. value)/(20.9-actual avg. 02% value))*VOC value 

E[VOC] = (C[VOC]*Mol Wt[VOC equivalent]*60(mm/hr)*Qstd(dscfm»/{Molar Vol. air*10A6) 

E[VOC Ib/MMBtu] = Cd * Fd * (20.9/(20.9-actual 02%» 

C[THC] = 9.2 ppmVw 

C[THC] = 10.7 ppmVd 

C[CH4) = 13.6 ppmVd 

C[VOC) = -2.9 ppmVd 

C[VOC] = -5.3 ppmVd corrected to 

Mol. Wt. [THC]= 44.096 lb/lb-mole 

Molar vol air= 385 scf/lb-mole @ 

E[VOG) = -3.18Iblhr 

7 

Propane 

68 

Conv Factor. 

E[VOG) = 

4.134E-08 convert ppmV to Ib/scf THC as CH4 

-3.20E-03 Ib/MMBtu 

%02 

def F 

9) Carbon Monoxide concentrations and emissions 

Carr. C[CO] = «20.9-02% carr. value)/(20.9-actual avg. 02% value))*Avg. raw CO value 

E[CO Ib/hr] = (C[COl"Mol Wt[CO]*60(min/hr)'"Qstd(dscfm))/(Molar Vol. ai~101\6) 

E[CO Ib/MMBtu] = Cd * Fd * (20.9/(20.9-actual 02%)) 

C[CO) = 582.5 ppmVd 

C[CO] = 1052.9 ppmVd corrected to 7 % 02 

Mol. Wt [CO]= 2801 Ib/lb-mole 

Molar vol air= 

E[CO) = 

Conv Factor. 

E[CO) = 

385 scf/lb-mole @ 

403.21 Ib/hr 

7.235E-08 convert ppmV to Ib/scf CO 

1.117 Ib/MMBtu 

68 def F 
Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

INPUT Tstd= 

INPUT y = 

INPUT t = 

INPUT On = 

An = 

INPUT Os = 

As = 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[O2[ 

[CO2] 

[N2] 

[CO] 

[THC] 

[CH4] 

AirNova, Inc. 

EPA Methods 1, 2, 3A, 4, 10, 18 and 25A 

(Flows, 02/C02, H20, CO and NMHC) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit No, 1 

04/15/10 

Three 

1812-2022 

Emission Data 

278.2 cc 

82.782 dcf 

-0.50 in. H2O 

30.24 in. Hg 

30.20 in. Hg 

29.92 in. Hg 

0.7061 in. H20 11.5 

1.41 in. H2O 

548.4 R 

641.5 R 

527.7 R 

1.00 

120 min. 

0.250 in. 

0.000341 sq. ft.. 

10.300 ft. 

83,3204 sq. ft.. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft. gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft.[(lb/lbmol)*(inHgW.5}/[s*R*inH201 

17.637 R/in.Hg constant 

Page 1 of 3 

0,047070 cu.ft!ml 

00026688 in.Hg-cf/ml-R 

9868 scf/MMBtu 

constant Pitot tube constant 

Instrumental Data 

12.81 %-dry 

6.86 %-dry 

80.33 %-dry 

3936 ppmV-dry 

6.4 ppmV-wet 

7.6 ppmV-dry 

constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Carbon Monoxide concentration 

Total Hydrocarbon concentration 

Methane Concentration by GC-FID 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Emission Source Unit No.1 

Test Run Three 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1· Y· Vm • (Pb + dH/13.6) I Tm 

Vmstd = eo 791 dscf 

2.288 dscm 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 ~ Vie 

Vw(std) = 13095 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.1395 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32*%02) + (28*%N2)" (1-Bws) 1 + (1e~Bws) 

Ms = 27.991 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp;O Cp" (dP);O (Ts/Ps~Ms)".5 

Vs = 44.170 fps 

6) Average actual stack gas volumetric f1owrate, Qa. 

Qa = 60 sec/min" Vs .. As 

Qa = 220815.8 efm 

6253.5 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa" (Tstd/Ts)" (Ps/Pstd)'" (1-Bws) 

Qstd = 157800.7 dscfm 

4468.9 dscmm 

Page 2 of 3 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cant.) 

Umt No.1 

Three 

Page 3 of 3 

8) Total Hydrocarbon concentrations and emissions 

INPUT 

C[THC] dry basts = C[THC] wetl(1-Bws) 

C[VOC] dry basis = C[THC]- C[CH4] 

Corr. C[CH4] = «20.9-02% carr. value)/(20.9-actual avg. 02% value))*VOC value 

E[VOC] = (C(VOC]*Mol Wt[VOC equivalent]*60(min/hr)*Qstd(dscfm»/(Molar Vol. air*1 0"6) 

E[VOC Ib/MMBtu] = Cd * Fd * (20.9/(20.9-actual 02%» 

C[THC] = 6.4 ppmVW 

C]THC] = 7.4 ppmVd 

C[CH4] = 7.6 ppmVd 

C(VOC] = -0.2 ppmVd 

C[VOC} = -0.3 ppmVd corrected to 7 %02 

Mol. WI. [THC]= 44.096 Ib/lb-mole 

Molar vol air= 

E]VOC] = 

Conv Factor. 

E]VOC] = 

385 scf/lb-mole @ 

-0.18 Ib/hr 

Propane 

68 def F 

4.134E·08 convert ppmV to Ib/scf THC as CH4 

-1.71E-04Ib/MMBtu 

9) Carbon Monoxide concentrations and emissions 

Corr. qCO] = «20.9-02% corr. value)/(20.9-actual avg. 02% valueWAvg. raw CO value 

E[CO Ib/hr] = (C[CO]*Mol Wt[CO]*60(min/hr)*Qsld(dscfm»/(Molar Vol. air*10"6) 

E[CO Ib/MMBtu] = Cd * Fd * (20.9/(20.9-actual 02%» 

C[CO] = 393.6 ppmVd 

C[CO] = 676.3 ppmVd corrected to 7 % 02 

Mol. Wt. [CO]= 28.01 Ib/lb·mole 

Molar vol air= 

E]CO] = 

Conv Faclor. 

E[CO] = 

385 scf/lb-mole @ 

271.12 Ib/hr 

7.235E-08 convert ppmV to Ib/scf CO 

0.726 Ib/MMBtu 

68 def F 
3333-SSVOH-R1 AirNova, Inc. 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

EPA Methods 1,2,3A,4 and 0010 with SW-846 Method 82700 

(Flows, 02fC02, H20. Speclated Semivolatile Organic HAPs and PAHs) 

Vlc= 

Vm" 

Pstatic = 

Pb= 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts= 

Tstd= 

On = 

An = 

y= 

t = 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd" 

[02] 

[C02] 

[N2] 

Spruance Genco, LLC 

3333 

Unit No_ 1 

One 

04/15/10 

1130-1342 

Emission Data 

296,6 cc 

85.997 dcf 

-0.50 in, H20 

30,39 in. Hg 

30.35 in. Hg 

29.92 in. Hg 

0.5922 in H20 ",5 

1.529 in, H20 

538.1 R 

668.4 R 

527.7 R 

0.3 in. 

0000491 sq, ft. 

0.97 

120 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[{lb/lbmol)*{inHg)]",5}/[s·R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.ftfml 

00026688 m.Hg-cf/ml-R 

9862 scf/MMBtu 

Instrumental Data 

9.28 %-dry 

10.01 %-dry 

80.71 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1'" Y '" Vm '" (Pb + dH!13.6) / Tm 

Vmsld = 83.395 dscf 

2.36 dscm 

Unit No.1 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) '" K2 .. Vic 

Vw(std) '" 13.961 scf 

3) Decimal fraction of moisture by volume in stack gas, 8ws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws'" 0.143 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms'" [«44*%C02) + (32*%02) + (28"%N2»" (1-Bws) 1 + (18"'Bws) 

Ms = 28.26 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp '" Cp • (dP) .. (Ts/Ps"Ms)".5 

Vs '" 37.54 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min" Vs * As 

Qa = 187672.7 cfm 

5314.9 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Oa * (TstdfTs).o (Ps/Pstd)" (1-Bws) 

Qstd = 128764.0 dscfm 

3646.6 dscmm 

Page 2 
Client Spruance Genco, LLC Test Location Unit No. Page 3 

Project No. 3333 Test Run One 

Calculations (cont.) 

8) Speciated Semivolatile Organic HAPs - Concentrations and Emissions 

qSSVOH] '" M[SSVOH](ug) I Vmstd(dscm) 

qSSVOH](Ib/dscf) '" qSSVOH](ug/dscm) * 1e-06g/ug * 2.205e-03Ib/g;O 0.02832 dscm/dscf 

E[SSVOH](lb/hr) = qSSVOH](ug/dscm) * Qstd(dscmm) * (2.205E-09)(lb/ug) ·60(min/hr) 

E[SSVOH](lb/MMBtu) = qS8VOH](lb/dscf) • Fd * (20.9/20.9-%02) 

qSSVOH](@ carr. 02) = qSSVOH] (ug/dscm) * [ (20.9-corrected %02) 1 (20.9-actual %02) ] 

Corrected 02 percentage is: 7.0 % 

SSVOH SamJ;!le Conc. QQn!;;.@ggrr. 02 Conc. Emission Rate Emission Rate 

Analyte Mass (uql (uq/dscm) (ug/dscm) (lb/dscO (Ib/hr) (lb/MMBtu) 

Acenaphthene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Acenaphthylene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO o OOE+OO 

Acetophenone 0.00 0.00 0.000 O.OOE+OO O.OOE+OO o OOE+OO 

Aniline 0.00 0.000 0.000 O.OOE+OO O.OOE+OO o OOE+OO 

Anthracene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO o OOE+OO 

Benzidine 000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(a)anthracene 000 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(b )fluoranthene 0.00 0.000 0000 O.OOE+OO O.OOE+OO o OOE+OO 

Benzo(k)f1uoranthene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzoic Acid 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(g,h,i)perylene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO o OOE+OO 

Benzo(a)pyrene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzyl Alcohol 11000 46.58 55.715 2.91 E-09 2.25E-02 5.16E-05 

bis (2-ChloroethyJ) ether 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

bis (2-Ethylhexyl) phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Bromophenyl phenyl ether 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Butyl benzyl phthalate 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Carbazole 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Chloroaniline 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Chloro-3-methylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Chloronaphthalene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Chlorophenol 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Chlorophenyl phenyl ether 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Chrysene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Dibenzo(a,h)anthracene 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 

Dibenzofuran 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 

Di-n-butyl phthalate 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 

1,2-Dichlorobenzene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,3-Dichlorobenzene 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 

1,4-Dichlorobenzene 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 

3,3-Dichlorobenzidine 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 

2,4-Dichlorophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Diethyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,4-Dimethylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Dimethyl phthalate 4.30 1.B2 2.178 1.14E-10 B.78E-04 2.02E-06 

4,6-Dinitro-2-methylphenol 0.00 000 0.000 O.OOE+OO O.OOE+OD O.OOE+OO 
Client 

Project No. 

Spruance Genco, LLC 

3333 

SSVOH Sample 

Analyte Mass (ug) 

2.4-Dinitrophenol 0.00 

2,4-Dimtrotoluene 0.00 

2,6-Dimtrotoluene 0.00 

Di-n-octyl phthalate 0 00 

1.2-Diphenylhydrazine 0.00 

Fluoranthene 0.00 

Fluorene 0 00 

Hexachlorobenzene 0.00 

Hexachlorobutadiene 0.00 

Hexachlorocyclopentadiene 0.00 

Hexachloroethane 0.00 

Indeno(1.2,3-c,d)pyrene 0.00 

Isophorone 0.00 

2-Methylnaphthalene 0.00 

2-Methylphenol 0.00 

3 & 4-Methylphenol 0.00 

Naphthalene 0.00 

2-Nitroaniline 0.00 

3-Nilroaniline 000 

4-Nilroaniline 0.00 

Nitrobenzene 0.00 

2-Nitrophenol 0.00 

4-Nltrophenol 0.00 

N-Nitrosodimethylamine 0 00 

N-Nitrosodiphenylamine 0.00 

N-Nitrosodi-n-propylamine 0.00 

Pentachlorobenzene 0.00 

Pentachloronitrobenzene 0.00 

Pentachlorophenol 0.00 

Phenanthrene 0.00 

Phenol 0.00 

2.2'-oxybis (1-Chloropropane) 0.00 

pyrene 0.00 

Pyridine 0.00 

1,2,4-Triehlorobenzene 0.00 

2,4,5-Tnehlorophenol 0.00 

2,4,6-Trichlorophenol 000 

Total SSVOHs 114.300 

Test Location 

Test Run 

Calculations (cont.) 

Cone. 

(ug/dscm) 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.620 

Unit NO.1 

Ooe 

Conc.@corr. 02 Cone. 

(ug/dscm) (Ib/dscf) 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.752 4.03E-11 

Page4 

Emission Rate Emission Rate 

(Ib/hr) (lb/MMBlu) 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO OOOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO OOOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO OOOE+OO 

O.OOE+OO OOOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

2.33E-02 5.36E-05 
Client Spruance Genco, LLC Test Location Unit No. Page 5 

Project No. 3333 Test Run 00. 

Calculations (cont.) 

9) PAH Concentrations and Emissions 

C[PAH] = M[PAH](ug) 1 Vmstd(dscm) 

C[PAH](lb/dscf) = C[PAH](ug/dscm) '* 1e-06g/ug" 2.20Se-03Ib/g" 0.02832 dscm/dscf 

E[PAH](lb/hr) = C[PAH](ug/dscm) '* QSld(dscmm) ,. (2.20SE-09)(lb/ug) ., 60(min/hr) 

E[PAH](lb/MMB1u) = C[PAH](lb/dsc~ ,. Fd ~ (20.9/20.9-%02) 

C[PAH](@ corr. 02) = C[PAH] (ug/dscm) '* [(20.9-correcled %02) I (20.9-actual %02)] 

Corrected 02 percentage IS: 7.0 % 

PAH Sample Cone. Conc.@o;;Qrr. Q2 Conc. Emission R~Ie: Emission Rate 

Analvte Mass (ug) (ug/dscm) (ug/dsem) (Ib/dscf) (lb/hr) (lb/MMBtu) 

Acenaph1hene 0.00180 0.00 0001 4.76E-14 3.68E-07 8.44E-10 

Acenapl11hylene 0.07300 0.03 0037 1.93E-12 1.49E-05 3.42E-08 

Anthracene 0.00210 0.00 0001 5.5SE-14 4.29E-07 9.85E-l0 

Benzo{a)an1hraeene 000280 0.001 0001 7.40E-14 5.72E-07 1.31 E-09 

Benzo{b)fluoranlhene 0.00540 0.002 0003 1.43E-13 1.10E-06 2.53E-09 

Benzo{k)fluoranthene 0.00270 0.001 0.001 714E-14 5.52E-07 1.27E-09 

Benzo(g, h, i)perylene 0.01490 0.006 o OOB 3.94E-13 3.04E-06 6.99E-09 

Benzo(a)pyrene 0.00510 0.002 0003 135E-13 1.04E-06 2.39E-09 

Benzo(e)pyrene 0.00510 0.002 0.003 135E-13 1.04E-06 2.39E-09 

Chrysene O.OOSBO 0.002 0.003 1.53E-13 1.1BE-06 2.72E-09 

Dibenzo(a,h)an1hracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Fluoranthene 0.05100 0.02 0.026 135E-12 1.04E-OS 2.39E-OB 

Fluorene 0.00800 0.00 0.004 212E-13 1.63E-06 3.7SE-09 

Indeno(1,2,3-c,d)pyrene 0.00340 0.001 0.002 8.99E-14 6.9SE-07 1 59E-09 

2-Me1hylnaphlhalene 0.10300 0.04 0052 272E·12 2 10E-05 4.B3E-08 

Naphthalene 1.24000 0.53 0.62B 3.28E-11 2 S3E-04 5.B2E-07 

Perylene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Phenanthrene 0.11700 0.05 0.059 309E·12 239E-05 5.49E-OB 

Pyrene 001100 0.00 0.006 291E-13 225E-06 5.16E-09 

Total PAHs 1.6521 0.037 0.044 2.30E·12 3.37E-04 7.75E-07 

10) Isokinecity, I. 

% I = [100*Ts*(K3*Vlc+{«Vm"Y)fTm)*(Pb+(dH/13.6»)))] 1 (60*t~Ps*Vs*An) 

% I = 91.61 
3333-SSVOH-R2 AirNova, Inc. 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

EPA Methods 1,2,3A,4 and 0010 with SW-84S Method 82700 

(Flows, 02/C02, H20, Speciated Semivolatile Organic HAPs and PAHs) 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

On = 

An = 

y= 

t= 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[02] 

[C02] 

[N2] 

Spruance Genco, LLC 

3333 

Unit No.1 

Two 

04/15/10 

1440-1653 

Emission Data 

289.3 cc 

80.586 dcf 

-0.50 in. H20 

30.32 m. Hg 

30.28 in. Hg 

29.92 in. Hg 

0.6960 in. H20 ".5 

1.182 in H20 

553.5 R 

640.5 R 

527.7 R 

0.246 in 

0.000330 sq. ft. 

0.97 

120 min. 

10300 ft. 

83.3204 sq. ft. 

0.84 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge readmg 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling lime 

Diameter of stack 

Cross sectional area of stack 

Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R*inH20] Pitot tube constant 

17.637 R/in Hg constant 

0.047070 cu fIIml constant 

0.0026688 in.Hg-cf/ml-R 

9755 scf/MMBtu 

Instrumental Data 

13.21 %·dry 

6.39 %-dry 

80.40 %-dry 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmsld =K1· Y· Vm • (Pb + dH/13.6) / Tm 

Vmstd = 75.744 dscf 

2.15 dscm 

Unit No. 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 .. Vic 

Vw(std) = 13.617 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 0.152 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32*%02) + (28*%N2»· (1-Bws) 1 + (18*Bws) 

Ms = 27.79 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp" Cp" (dP) .. (Ts/Ps*Ms)".5 

Vs= 43.60 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min" Vs .. As 

Oa = 217980.8 cfm 

6173.2 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Ostd = Oa" (TstdfTs)· (Ps/Pstd)" (1-Bws) 

Ostd = 154064.8 dscfm 

4363.1 dsemm 

Page 2 
Client Spruance Genco, LlC Test location Unit No.1 Page 3 

Project No. 3333 Test Run Two 

Calculations (cont.) 

8) Speciated Semivolatile Organic HAPs - Concentrations and Emissions 

qSSVOH] = M[SSVOH](ug) I Vmstd(dscm) 

qSSVOH)(lb/dscf) = qSSVOH)(ug/dscm);O 1e-06gfug· 2.205e-03Ibfg;O 0.02832 dscmfdscf 

E[SSVOH](lb/hr) = qSSVOH)(ugfdscm) ~ Qstd(dscmm) * (2.205E-09)(lbfug) ·60(min/hr) 

E[SSVOH](lb/MMBtu) '" crSSVOH](lb/dscf) • Fd * (20 9/20.9-%02) 

crSSVOH)(@ corr. 02) = crSSVOH) (ug/dscm) * [(20.9-corrected %02) I (20.9-actual %02) I 

Corrected 02 percentage is: 7.0 % 

SSVOH Samgle Conc. Ggn!;; @!;&!rr. Q2 Conc. Emission Rate Emission Rate 

Analyte Mass (ug) (ug/dscm) (ug/dscm) (lb/dscf) (lb/hr) (lb/MMBtu) 

Acenaphthene 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Acenaphthylene 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Acetophenone 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Aniline 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Anthracene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzidine 0.00 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(a)anthracene 0.00 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(b)f1uoranthene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(k)f1uoranthene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzoic Acid 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(g, h, i)perylene 0.00 0000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(a)pyrene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzyl Alcohol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

bls (2-Chloroelhyl) ether 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

bis (2-Ethylhexyl) phthalate 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Bromophenyl phenyl ether 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Butyl benzyl phthalate 0.00 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Carbazole 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Chloroaniline 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Chloro-3-melhylphenol 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Chloronaphthalene 000 0.00 0.000 O.OOE~OO O.OOE+OO o OOE+OO 

2-Chlorophenol 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Chlorophenyl phenyl ether 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Chrysene 0.00 0.00 0.000 O.OOE+OO o OOE ... OO o OOE+OO 

Dibenzo(a,h)anthracene 0.00 0.00 0.000 O.OOE+OO o OOE+OO O.OOE+OO 

Dibenzofuran 0.00 0.00 0.000 O.OOE+OO o OOE+OO O.OOE+OO 

Di-n·butyl phthalate 0.00 0.00 0.000 O.OOE+OO o OOE+OO O.OOE+OO 

1,2-Dichlorobenzene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,3-Dichlorobenzene 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,4-Dichlorobenzene 000 0.00 0.000 O.OOE+OO o OOE+OO O.OOE+OO 

3,3-Dichlorobenzidine 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,4-Dichlorophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Dielhyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO o OOE+OO 

2,4-Dimethylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO o OOE+OO 

Dimethyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4,6-Dinitro-2-methylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 
Client 

Project No. 

Spruance Genco, LLC 

3333 

SSVOH 

Analyte 

2,4~Dmltrophenol 

2,4~Dinitrotoluene 

2,6~Dinitrotoluene 

Di~n~oclyl phthalate 

1 ,2~Diphenylhydrazine 

Fluoranthene 

Fluorene 

Hexaehlorobenzene 

Hexaehlorobutadiene 

Hexaehlorocyclopentadiene 

Hexachloroethane 

Indeno(1 ,2,3~c,d)pyrene 

Isophorone 

2~Methylnaphthalene 

2~Methylphenol 

3 & 4~MethylphenoJ 

Naphthalene 

2~Nitroaniline 

3~Nitroaniline 

4~Nltroaniline 

Nitrobenzene 

2~NitrophenoJ 

4~Nitrophenol 

N~Nitrosodimethylamine 

N~Nit(Qsodiphenylamine 

N~Nitrosodl·n~propylamine 

Pentachlorobenzene 

Pentaehloronitrobenzene 

Pentachlorophenol 

Phenanthrene 

Phenol 

2,2'~oxybis (1~Chloropropane) 

Pyrene 

Pyridine 

1,2,4· Trichlorobenzene 

2,4,5· Triehlorophenol 

2,4,6~Triehlorophenol 

Total SSVOHs 

Sample 

Mass (ug) 

0.00 

000 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

000 

0.00 

0.00 

0.00 

0.00 

6.50 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

000 

000 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

000 

6.500 

Test Location 

Test Run 

Calculations (cont.) 

Cone. 

(ug/dscm) 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

3.03 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

000 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.039 

Unit No.1 

Two 

CQnc.@corr. 02 Conc. 

(ug/dsem) (Ib/dscf) 

0.000 OOOE+OO 

0.000 OOOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

5.477 1.89E·10 

0.000 O.OOE+OO 

0000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0000 O.OOE+OO 

0000 O.OOE+OO 

0000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.071 2.52E-12 

Emission Rate 

{Ib/hrl 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

1.75E-03 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

1.75E-03 

Page 4 

Emission Rate 

(lb/MMBtu) 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOHOO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

5.02E-06 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

5.02E-06 
Client 

Project No. 

Spruance Genco, LLC 

3333 

9) PAH Concentrations and Emissions 

Test Location 

Test Run 

Calculations (cont.) 

C[PAH] = M[PAH](ug) I Vmstd{dscm) 

Unit No.1 

Two 

C[PAH](lb/dscf) = C[PAH](ug/dscm)" 1e-06g/ug" 2.20Se-03Ib/g ~ 0.02832 dscm/dscf 

E[PAH](Ib/hr) = C[PAH]{ug/dscm) .. Qstd(dscmm) .. (2.20SE-09){lb/ug)" 60(min/hr) 

E[PAH](Ib/MMBtu) = C[PAH](Ib/dscf)' Fd • (20.9120.9-%02) 

C[PAH](@ corr. 02) = C[PAH] (ug/dscm) * [(20.9-corrected %02) I (20.9-actual %02)] 

Corrected 02 percentage IS: 7.0 % 

PAH Sample Conc. QQnc.@oorr. 02 Conc. Emission Rate 

Analyte Mass (ug) (ug/dscm) (ug/dscml (Ib/dscf) (Ib/hr) 

Acenaphthene 0.02700 0.01 0.023 7.86E-13 727E·06 

Acenaphthylene 0.03884 0.02 0.033 113E-12 1 OSE-OS 

Anthracene 0.00000 0.00 0000 O.OOE+OO O.OOE+OO 

Benzo(a)anthracene 0.00000 0.000 0000 O.OOE+OO O.OOE+OO 

Benzo(b)f1uoranthene 0.00330 0.002 0.003 9.61E-14 8 S8E-07 

Benzo(k)f1uoranthene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Benzo{g,h.i)perylene 0.00900 0.004 0.008 2.62E-13 2.42E-06 

Benzo{a)pyrene 000230 0.001 0.002 6.70E-14 6.19E-07 

Benzo(e)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Chrysene 0.00091 0.000 0.001 2.65E-14 2.45E-07 

Dibenzo(a,h)anthracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Fluoranthene 0.02500 0.01 0.021 7.28E-13 6.73E-06 

Fluorene 0.01030 0.00 0.009 3.00E-13 2.77E-06 

Indeno{1,2,3-c,d)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

2-Methylnaphthalene 0.97900 0.46 0.825 2.85E-11 263E-04 

Naphthalene 10.17000 4.74 8.570 2.96E-10 2.74E-03 

Perylene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Phenanthrene 003400 0.02 0.029 9.90E-13 9.15E-06 

Pyrene 0.00000 0.00 0.000 O.OOE+OO O.OOE+OO 

Total PAHs 11.2997 0.277 0.501 1.73E-11 3.04E-03 

10) Isokinecity, I. 

%1= 103.43 

Page 5 

Emission Rate 

(lb/MMBtul 

2.08E-08 

3.00E-08 

O.OOE+OO 

o OOE+OO 

2.55E-09 

O.OOE+OO 

6.95E-09 

1.78E-09 

o OOE+OO 

7.02E-10 

O.OOE+OO 

1.93E-08 

7.9SE-09 

o OOE+OO 

7.56E-07 

7.85E-06 

O.OOE+OO 

2.62E-08 

O.OOE+OO 

8.72E-06 
3333-SSVOH-R3 AirNova, Inc. 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

EPA Methods 1,2,3A,4 and 0010 with SW-B46 Method 82700 

(Flows, 021C02, H20, Speciated Semivolatile Organic HAPs and PAHs) 

Vlc= 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

On = 

An = 

y= 

t= 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

1021 

IC021 

IN21 

Spruance Genco, LLC 

3333 

Unit No.1 

Three 

04/15110 

1812-2022 

Emission Data 

293.5 cc 

84.794 dcf 

-0.50 in. H20 

30.24 in. H9 

30.20 in. H9 

29.92 in. H9 

07058 in. H20 ".5 

1.263 in. H2O 

547.7 R 

6425 R 

527.7 R 

0.246 in. 

0.000330 sq. ft. 

0.97 

120 min. 

10.300 ft. 

83.3204 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle onfice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmolt(inHg)]".5}/[s~R~InH201 Pitot tube constant 

17.637 R/in.Hg constant 

0.047070 cu.ftlml constant 

0.0026688 in.Hg-c1lml-R 

9868 sc1/MMBtu 

Instrumental Data 

12.81 %-dry 

6.86 %-dry 

80.33 %-dry 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y'" Vm " (Pb + dH/13.6) J Tm 

Vmstd = 80.340 dscf 

2.28 dscm 

Unit No. 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std), 

VW{Sld) = K2" Vic 

Vw{std) = 13.815 set 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.147 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44"%C02) + (32*%02) + (28*%N2»" (1-Bws)] + (18*8ws) 

Ms= 27.91 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp ." Cp'" (dP)'" (Ts/Ps*Ms)" 5 

Vs = 44.25 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs .. As 

Qa = 221218.1 cfm 

6264.9 cmm 

7) Average stack gas dry volumetric flowrate, Ostd. 

Qstd '" Qa'" (TstdfTs)· (PsJPstd)" (1-Bws) 

Qstd = 156492.1 dscfm 

4431.9 dscmm 

Page 2 
Client 

Project No. 

Spruanee Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.1 

Three 

8) Speciated Semivolatile Organic HAPs - Concentrations and Emissions 

qSSVOH] = M[SSVOH](ug) / Vmstd{dscm) 

qSSVOH]{lb/dscf) = qSSVOH](ug/dscm) • 1e-06g/ug ~ 2.205e-03Ib/g ·0.02832 dsem/dscf 

E[SSVOH]{lbfhr) '" C[SSVOH]{ug/dscm) ;0 Qstd{dscmm);O (2.205E-09)(lb/ug) * 60{min/hr) 

E[SSVOH](lb/MMBtu) = qSSVOH](lb/dscf)· Fd * (20.9120 9-%02) 

qSSVOH](@ corr. 02) = qSSVOH] (ug/dsem) * [ (20 9-correcled %02) / (20.9-actual %02)] 

Corrected 02 percentage is 7.0 % 

SSVOH 

AnaMe 

Acenaphthene 

Aeenaphthylene 

Acetophenone 

Anrline 

Anthracene 

Benzidine 

Benzo(a)anthracene 

Benzo(b )f1uoranthene 

Benzo(k)fluoranthene 

BenzOIc ACid 

Benzo{g, h, i) perylene 

Benzo(a)pyrene 

Benzyl Alcohol 

bis (2-Chloroelhyl) ether 

bis (2-Ethylhexyl) phthalate 

4-Bromophenyl phenyl ether 

Butyl benzyl phthalate 

Carbazole 

4-Chloroaniline 

4-Chloro-3-methylphenol 

2-Chloronaphthalene 

2-Chlorophenol 

4-Chlorophenyl phenyl ether 

Chrysene 

Dibenzo(a,h)anthraeene 

Dibenzofuran 

Di-n-butyl phthalate 

1,2-Dichlorobenzene 

1,3-Dichlorobenzene 

1 A-Dichlorobenzene 

3,3-Dichlorobenzidine 

2,4-Dichlorophenol 

Diethyl phthalate 

2.4-Dimethylphenol 

Dimethyl phthalate 

4,6-Dinitro-2-methylphenol 

Sample 

Mass (ug) 

000 

0.00 

000 

000 

000 

0.00 

0.00 

0.00 

0.00 

3800 

0.00 

0.00 

0.00 

0,00 

0.00 

0.00 

0.00 

0.00 

0,00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0,00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

Cone, 

(ug/dsem) 

0.00 

0.00 

0.00 

0.000 

0.000 

0000 

0000 

0000 

0000 

16.702 

0000 

0.00 

0.00 

0.000 

0.00 

0.00 

0000 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

Conc.@corr. 02 Cone. 

(ug/dsem) (lb/dscf) 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O,OOE+OO 

28.696 1.04E-09 

0.000 O,OOE+OO 

0.000 O,OOE+OO 

0.000 OOOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 OOOE+OO 

0.000 O.OOE+OO 

0.000 O,OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0,000 O.OOE+OO 

0.000 O,OOE+OO 

0.000 O,OOE+OO 

0.000 O.OOE+OO 

0,000 O.OOE+OO 

0.000 OOOE+OO 

0.000 OOOHOO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

Emission Rate 

(Iblhr) 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.ODE+OO 

O.ODE+OO 

979E-D3 

O.ODE+OO 

O.OOE+OO 

O.OOE+OO 

o OOE+OO 

o ODE+DO 

O.OOE+OO 

O.OOE+OD 

O.OOE+OD 

D.DOE+OO 

D.OOE+OO 

O.ODE+OO 

O,OOE+OO 

O,OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OD 

o OOE+OD 

O.OOE+OD 

O.OOE+OO 

D.DOE+OO 

D.OOE+OO 

O.OOE+OO 

O.ODE+OO 

O.ODE+OO 

O.ODE~·OO 

Page 3 

Emission Rate 

Clb/MMBtu) 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

2.66E-05 

O.OOE+OO 

O,OOE+OO 

O,OOE+OO 

O.OOHOO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O,OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

o OOE+OO 

o OOE+OO 

O.OOE+OO 

O.OOE+OO 

O,OOE+OO 

O,OOE+OO 

O.OOE+OO 

O.OOE+OO 
Client Spruance Genco, LLC Test Location Unil No. Page 4 

Project No. 3333 Test Run Three 

Calculations (cont.) 

SSVOH Sample Conc. Canc.@corr. 02 Conc. Emission Rate: Emission Rate 

Analyte Mass (ug) (uq/dscm) (uq/dscm) ([b/dscO (lb/hr) (lb/MMBlu) 

2,4-0Inilrophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,4-0InitroloJuene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,6-0initrotoluene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Oi-n-octyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,2-Diphenylhydrazine 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Fluoranthene 000 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Fluorene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Hexachlorobenzene 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Hexachlorobutadiene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Hexachlorocyclopentadiene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO o OOE+OO 

Hexachloroethane 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Indeno(1,2,3-c,d)pyrene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Jsophorone 0.00 0.00 0000 O.OOE+OO o OOE+OO O.OOE+OO 

2-Methylnaphthalene 0.00 0.00 0000 O.OOE+OO o OOE+OO O.OOE+OO 

2-Methylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

3 & 4-Methylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Naphthalene 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Nitroaniline 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

3-Nitroaniline 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Nitroaniline 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Nitrobenzene 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Nitrophenol 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Nitrophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

N-Nitrosodimethylamine 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

N-Nitrosodiphenylamine 0.00 000 0.000 O.OOE+OO o OOE+OO O.OOE+OO 

N-Nitrosodi-n-propylamine 0.00 0.00 0.000 O.OOE+OO o OOE+OO O.OOE+OO 

Pentachlorobenzene 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 

Pentachloronilrobenzene 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 

Pentachlorophenol 0.00 0.00 0000 O.OOE+OO O.OOE+OO o OOE+OO 

Phenanthrene 0.00 0.00 0000 O.OOE+OO O.OOE+OO o OOE+OO 

Phenol 0.00 000 0.000 O.OOE+OO O.OOE+OO o OOE+OO 

2,2'-oxybIS (1-Chloropropane) 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Pyrene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Pyridine 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,2,4-Trichlorobenzene 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,4,5-Trichlorophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO o OOE+OO 

2,4,6-TrichlorophenoJ 0.00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 

Total SSVOHs 38.000 0.214 0.373 1.39E-11 9.79E-03 2.66E-05 
Client 

Project No. 

Spruanee Genco, LLC 

3333 

9) PAH Concentrations and Emissions 

Test Location 

Test Run 

Calculations (cont.) 

C[PAH] = M[PAH](ug) I Vmstd(dscm) 

Unit No. 

Three 

C[PAH](lb/dsef) = C[PAH](ug/dscm)· 1e-06g/ug '* 2.205e-03Ib/g ~ 0.02832 dscm/dsef 

E[PAH](Ib/hr) = C[PAH](ug/dscm) .. Qstd(dscmm) " (2.205E-09)(lb/ug) * 60(min/hr) 

E[PAH](Ib/MMBtu) = C[PAH](lb/dscf) * Fd * (20.9/20_9-%02) 

C[PAH](@corr. 02) = C[PAH] (ug/dscm) * [(20.9-eorreeted %02) f (20.9-actual %02) 1 

Corrected 02 percentage IS: 7.0 % 

PAH Sample Cone. Conc.@corr Q2 Conc. Emission Rat!i! 

AnaMe Mass (ug) (uq/dscm) (ug/dscm) (lb/dscf) (Ib/hr) 

Acenaphthene 0.00170 0.00 0.001 4.67E-14 43SE-07 

Acenaphthylene 0.03548 0.02 0_027 9.74E-13 9 14E-06 

Anthracene 000000 0.00 0.000 O.OOE+OO O.OOE+OO 

Benzo(a)anthracene 000000 0.000 0.000 O.OOE+OO O.OOE+OO 

Benzo(b)f1uoranthene 0.00000 0.000 0.000 O.OOHOO O.OOE+OO 

Benzo{k)f1uoranthene 0.00000 0_000 0.000 O.OOE+OO O.OOE+OO 

Benzo(g,h,i)perylene 0.00000 0000 0.000 O.OOE+OO O.OOE+OO 

8enzo{a)pyrene 0.00660 0003 0.005 181E-13 1 70E-06 

8enzo(e)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Chrysene 0.00297 0.001 0.002 8.15E-14 7.65E-07 

Dibenzo(a,h)anthracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Fluoranthene 0_01BOO 0.Q1 0.014 494E-13 4.64E-OS 

Fluorene 000800 0.00 0.006 2.20E-13 2.0BE-OS 

Indeno(1,2,3-c,d)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

2-Methylnaphthalene 0.07300 0.03 0.055 2.00E-12 1.B8E-05 

Naphthalene 0.27400 0.12 0.207 7.52E·12 706E-05 

Perylene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Phenanthrene 0.02400 0.01 0.Q18 6.59E-13 6.18E-06 

Pyrene 0.00000 0.00 0.000 o OOE+OO O.OOE+OO 

Total PAHs 0,4438 0.010 0018 6,41E-13 1.14E-04 

10) Isokineclty, L 

% J = [100*Ts"(K3*Vlc+({(Vm"Y)fTm)*(Pb+(dH/13_S»)))] I (60*t*Ps'*Vs*An) 

%1= 10800 

Page 5 

Emission Rate 

(lb/MMBtu) 

1.19E-09 

2,4SE-08 

O_OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

4.62E-09 

O.OOE+OO 

2.0BE-09 

O.OOE+OO 

1.26E-OB 

5.S0E-09 

O.OOE+OO 

5.11E-08 

1.92E-07 

O.OOE+OO 

1.68E-08 

O.OOE+OO 

3.10E-07 
3333-VQST-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb = 

Ps= 

Pstd = 

Tm= 

INPUT Ts = 

INPUT Tstd= 

INPUT Y = 

INPUT t = 

INPUT Ds = 

As = 

Kp = 

K1 = 

K2 = 

K3= 

INPUT Fd = 

INPUT [02[ 

INPUT [C02[ 

[N2[ 

AirNova, Inc. 

EPA Method 1, 2, 3A and 0031JSW-846 Method 82608 

(Flows, 021C02, and Speciated Volatile Organic HAPs) 

Spruance Genco, LLC 

3333 

Unit No.1 

Ooe 

04/15/10 

1130-1330 

Emission Data 

1.016 dct 

-0.50 in. H2O 

30.39 in. H9 

30.35 in. H9 

29.92 in. H9 

544.6 R 

668.4 R 

527.7 R 

1,000 

90 min. 

10,300 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83.3204 sq. ft. Cross sectional area of slack 

85.49 ft[(lb/lbmoIY"(inHg)]".5}/[s*R*inH20] 

17.637 R/in.Hg constant 

0.047070 CU.ft/ml constant 

0.0026688 in.Hg-cf/ml-R constant 

9862 scf/MMBtu Fuel Factor 

Instrumental Data 

9.28 %-dry Oxygen concentration 

10.01 %-dry Carbon Dioxide concentration 

80.71 %-dry Nitrogen concentration 
Client 

Project No. 

Spruance Genco, llC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1'* Y '* Vm - Pbf Tm 

Vmstd = 1.000 dsef 

0.0283 dsem 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws = 

Bws = 

Based on the SSVOH sampling train 

0.1430 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No. 

One 

Ms = [«44*%C02) + (32*%02) + (28*%N2))" (1-Bws) I + (18*Bws) 

Ms= 28.261 Ibf Ibmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs = 

Vs = 

Based on the SSVOH sampling train 

37.230 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min * Vs ., As 

Qa = 186121.18 cfm 

5270.95 cmm 

7) Average stack gas dry volumetric f1owrate, Qstd. 

Qstd = Qa ., (TstdfTs) * (PsfPstd) • (1-Bws) 

Qstd = 127752.88 dscfm 

3617.96 dscmm 

Page 2 
Client Spruance Genco, LLC Test Location Unit No.1 Page 3 

Project No. 3333 Test Run Ooe 

Calculations (cant.) 

8) Speciated Volatile Organic HAPs - Concentrations and Emission Rates 

C[SVOH] = M(SVOH] lug) I Vmstd (dscm) 

C[SVOH]{lb/dscf) = C(SVOH]{ug/dscm) * 1e-06g/ug" 2,205e-03Ib/g • 0.02832 dscm/dscf 

E(SVOH](lb/hr) = C(SVOH] (ug/dscm) • (2.20SE-09) (Ib/ug) * Qstd (dscmm) * 60 (min/hr) 

E[SVOH](lb/MMBtu) = C(SVOH](Ib/dscf) • Fd * (20.9/20.9-%02) 

CjSVOH](@carr. 02) = C[SVOH[ (ug/dscm) * [ (20.9-corrected %02) I (20,S-actual %02)] 

Corrected 02 percentage is: 7.0 % 

Cone. Conc.@corr. 02 Cone. Emission Rate Emission Rate 

Compound {ug/dseml (ug/dsem) (lb/dscfl (lb/hrl (lb/MMBtu) 

Acetone 1177,924 1409.048 7.36E-08 5,64E-01 1.30SE-03 

Benzene 1.377 1,647 B.60E-11 6,S9E-04 1.S2SE-06 

Bromobenzene 0.177 0.211 1.10E-11 B,4SE-OS 1.956E-07 

Bromochloromethane 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Bromodichloromethane 0.000 0.000 O.OOE+OO O.OQE+OO O,OOOE+OO 

Bromoform 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Bromomethane 3.083 3.688 1.93E-10 1,48E-03 3,415E-06 

2-Butanone 3.767 4.506 2.3SE-10 i.80E-03 4,172E-06 

n-Butylbenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

sec-Butylbenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

tert-Butylbenzene 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Carbon Disulfide 0.1S2 0.182 9,48E-12 7.27E-05 1.682E-07 

Carbon Tetrachloride 0.530 0.634 3.31 E-11 2.54E-04 S.867E-07 

Chlorobenzene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Chlorodibromomethane 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Chloroethane 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Chloroform 0,473 0.566 2.95E-11 2,26E-04 5.241 E-07 

Chloromethane 9,768 11.684 6.10E-10 4.68E-03 1.082E-05 

2-Chlorotoluene 0.000 0000 O.OOE+OO O,OOE+OO O.OOOE+OO 

4-Chlorotoluene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

1 ,2-Dibromo-3-chloropropane 0000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dibromoethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Dibromomethane 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

i,3-Dichlorobenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

1 A·Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Dichlorodifluoromethane 4.121 4.930 2.57E-10 1.97E-03 4.565E-06 

1,1-Dichloroethane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichloroethane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

cis-1,2-Dichloroethene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

trans-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1-Dichloroethene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,3-Dichloropropane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

2,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

cis-i,3-Dichloropropene 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

trans-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 
Client Spruance Genco, LLC Test Location Unit No. Page 4 

Project No. 3333 Test Run Doe 

Calculations (cont.) 

Conc. Qonc.@oorr. 02 Conc. Emission Rate Emission Rate 

Compound (uq/dscm) (uq/dscm) (lb/dscO (lb/hr) (lb/MMBtu) 

1,1-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Ethylbenzene 0.042 0.051 2.65E-12 2.03E-05 4.694E-OB 

Hexachlorobutadiene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

2-Hexanone 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Isopropyl benzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

p-Isopropyltoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Methylene Chloride 122.560 146.607 7.65E-09 5.B7E-02 1.358E-04 

4-Methyl-2-Pentanone 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Naphthalene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

n-Propylbenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Styrene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

1,1,1,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

1,1,2,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Tetrachloroethene 0.258 0.308 1.61E-11 1.23E-04 2.855E-07 

Toluene 19.240 23.015 1.20E-09 9.21E-03 2.131E-05 

1,2,3-Trichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2,4-Trichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1,1-Trichloroethane 0.049 0,059 3.09E-12 2.37E-OS 5,476E-08 

1,1,2-Trichloroethane 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Trichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Trichlorofluoromethane 85.874 102,724 5.36E-09 4.11E-02 9.512E-05 

1,2,3-Trichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2,4-Trimethylbenzene 0.120 0.144 7.50E-12 5.75E-05 1.330E-07 

1,3,5-Trimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Vinyl Chloride 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

m-Xylene & p-Xylene 0.088 0.106 5.51E-12 4.23E-05 9.779E-OB 

o-Xylene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Total 21.661 24.784 1.31E-09 6.B4E-01 1.5B4E-03 
3333~VOST-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb= 

Ps= 

Pstd = 

Tm= 

Ts= 

Tstd= 

y= 

t= 

Ds= 

As= 

Kp = 

K1 = 

K2= 

K3= 

Fd = 

[021 

[C021 

[N21 

AirNova, Inc. 

EPA Method 1, 2, 3A and 00311SW·846 Method 82608 

(Flows, 02fC02, and Speclated Volatile Organic HAPs) 

Spruance Genco, LLG 

3333 

Unit NO.1 

Two 

04/15f10 

1450-1650 

Emission Data 

1.337 dcf 

-0.50 in, H20 

30.31 in. Hg 

30.27 in. Hg 

29.92 in. Hg 

553.9 R 

640.5 R 

527.7 R 

1.000 

90 min. 

10.300 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83.3204 sq. ft. Cross sectional area of stack 

85.49 ft[(lbllbmol)"(inHg)1".5}/[s~R*inH201 

17.637 Rlin.Hg constant 

0.047070 cu.ftlml constant 

0.0026688 in.Hg-cffml-R 

9755 scffMMBtu 

Instrumental Data 

13.21 %-dry 

6.39 %-dry 

80AO %-dry 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd t::K1~ Y" Vm * Pbl Tm 

Vmstd = 1,290 dscf 

0.0365 dscm 

3) Decimal fraction of moisture by volume In stack gas, Bws. 

INPUT 

Bws= 

Bws= 

Based on the SSVOH sampling train 

0,1520 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No. 

Two 

Ms = [«44~%C02) + (32~%02) + (28~OloN2)) * (1-Bws) 1 + (18*8ws) 

Ms= 27.795 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs = 

Vs= 

Based on the SSVOH sampling train 

42.970 fps 

G) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min * Vs * As 

Oa = 214816.74 cfm 

6083.61 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Oa * (TstdfTs) * (Ps/Pstd)" (1-Bws) 

Qstd = 151855.03 dscfm 

4300.63 dscmm 

Page 2 
Client Spruance Genco, LLC Test Location Unit No.1 Page 3 

Project No. 3333 Test Run Two 

Calculations (cont.) 

8) Specialed Volatile Organic HAPs - Concentrations and Emission Rates 

C[SVOH] = M[SVOH] (ug) I Vmstd (dscm) 

C[SVOH](lb/dscf) = C[SVOH](ugfdscm) ~ 1e-06g/ug· 2.205e-03Ibfg * 0.02832 dscm/dscf 

E[SVOH](lblhr) = C[SVOH] (ugfdscm) ~ (2,205E-09) (Ib/ug) * Qstd (dscmm)· 60 (min/hr) 

E[SVOHj(lb/MMBtu) = C[SVOHj(lb/dscf) * Fd '" (20.9/20.9-%02) 

C[SVOH](@ cerro 02) = C[SVOH] (ugfdscm) * [(20.9-corrected %02) f (20.9-actual %02)] 

Corrected 02 percentage is: 7.0 % 

Conc. Conc.@corr. 02 Cone. Emission Rate Emission Rate 

Compound (ug/dscm) (ug/dscm) (lb/dscO (lb/hr) (lb/MMBtu) 

Acetone 501.965 907.323 3.13E-08 2.86E-01 8.310E-04 

Benzene 3.557 6.430 2.22E-10 2.02E-03 5.890E-06 

Bromobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Bromochloromethane 0.255 0.462 1.59E-11 1.45E-04 4.228E-07 

Bromodichloromethane 0.000 0.000 O.OOE+OO O,OOE~'OO O.OOOE+OO 

Bromoform 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Bromomethane 1.792 3.240 1.12E-10 1.02E-03 2_967E-06 

2-Butanone 4.652 8.409 2.90E-10 2.65E-03 7.702E-06 

n-Butylbenzene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

sec-Butyl benzene 0,000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

tert-Butylbenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Carbon Disulfide 2.619 4.734 1.64E-10 1.49E-03 4.336E-06 

Carbon Tetrachloride 0.520 0.940 3.25E-11 2.96E-04 8,BOBE-07 

Chlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Chlorodibromomethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Chloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Chloroform 0.354 0.640 2,21E-11 2.01E-04 5.S59E-07 

Chloromethane 9.293 16.798 5.80E-10 5.29E-03 1.539E-05 

2-Chlorotoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

4-Chlorotoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1 ,2-Dibromo-3-chloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OO 

1,2-Dibromoethane 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Dibromomethane 0.000 0,000 O_OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichlorobenzene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,3-Dichlorobenzene 0,000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

1.4-Dichlorobenzene 0,000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Dichlorodifluoromethane 3.295 5,955 2.06E-10 1.87E-03 5.455E-06 

1,1-Dichloroethane 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichloroethane 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

cis-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

trans-1 ,2-Dichloroethene 0.000 0_000 O.OOE+OO O,OOE+OO O.OOOE+OO 

1,1-Dichloroethene 0.000 0.000 O.OOE+OO O,OOE+OO O_OOOE+OO 

1,2-Dichloropropane 0.000 0,000 O.OOE+OO O.OOE+OO O_OOOE+OO 

1,3-Dichloropropane 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

2,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

cis-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

trans-1 ,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OO 
Client Spruance Genco, LLC Test Location Unit No.1 Page 4 

Project No. 3333 Test Run Two 

calculations (cont.) 

Conc. QonQ.@!<QIT Q2 Conc. Emission Bate Emission Rate: 

Compound (ugfdscml (ug/dscm) (lb/dscO (lb/hr) (lb/MMBtu) 

1,1-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Ethylbenzene 0.077 0.138 4.78E·12 4.36E-05 1.269E-07 

Hexachlorobutadiene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

2-Hexanone 0.602 1.088 3.76E-11 3.43E-04 9.967E-07 

Isopropylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

p-Isopropyltoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Methylene Chloride 118.518 214.226 7.40E-oe 6.74E-02 1.962E-04 

4-Methyl-2-Pentanone 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Naphthalene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

n-Propylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Styrene 0.038 0.069 2.39E-12 2.i8E-05 6.343E-08 

1,1,1,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1,2,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Tetrachloroethene 0.115 0208 7.18E-12 6.54E-05 1.e03E-07 

Toluene 2.268 4.099 1.42E-10 1. 29E-03 3.754E-06 

1,2,3-Trichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2,4-Trichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1 ,1 ,i-Trichloroethane 0.030 0.054 1.88E-12 1.7iE-05 4.984E-08 

1,1,2-Trichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Trichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

T richlorofluoromethane 6.825 12.336 4.26E-10 3.88E-03 1.130E-05 

1,2,3-Trichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2,4-Trimethylbenzene 0.109 0.198 6.84E-12 6.23E-05 1.8i2E-07 

1,3,5-Trimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO o OOOE+OO 

Vinyl Chloride 0.000 0000 O.OOE+OO O.OOE+OO O.OOOE+OO 

m-Xylene & p-Xylene 0.167 0.302 1.04E-11 9.50E-05 2.764E-07 

o-Xylene 0.036 0.064 2.22E-12 2.02E-05 5.890E-08 

Total 9.956 17.213 B.03E-10 374E-01 i.088E-03 
3333-VOST-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

Tm= 

INPUT Ts = 

INPUT Tstd= 

INPUT Y = 

INPUT t= 

INPUT 

INPUT 

INPUT 

INPUT 

Ds = 

As = 

Kp = 

K1 = 

K2= 

K3= 

Fd = 

[02[ 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Method 1, 2, 3A and 0031/SW-846 Method 8260B 

(Flows, 02fC02, and Speciated Volatile Organic HAPs) 

Spruance Genco, LLC 

3333 

Unit No.1 

Three 

04/15/10 

1812-2012 

Emission Data 

0.922 def 

-0.50 in. H2O 

30.24 in. Hg 

30.20 in. Hg 

29.92 in. Hg 

543.0 R 

642.5 R 

527.7 R 

1.000 

90 min. 

10.300 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83.3204 sq. ft. Cross sectional area of stack 

85.49 ft[(lbflbmolt(inHg»)1I.5}/[s*WinH20] 

17.637 Rfin.Hg constant 

0.047070 cu fUml constant 

0.0026688 in.Hg·cffml-R 

9868 scf/MMBtu 

Instrumental Data 

12.81 %-dry 

6.86 %·dry 

80.33 %-dry 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmsld =K1* Y * Vm * Pbf Tm 

Vmstd = 0.906 dscf 

0.0256 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws = 

Bws = 

Based on the SSVOH sampling train 

0.1470 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No.1 

Three 

Ms = [«44*%C02) + (32*%02) + (28*%N2»· (1-Bws) 1 + (18*Bws) 

Ms = 27,903 Ib! Ibmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs= 

Vs= 

Based on the SSVOH sampling train 

43.650 fps 

6) Average actual stack gas volumetric flowrate, Ca. 

Qa = 60 sec/min" Vs * As 

Qa = 218216.22 cfm 

6179,88 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa" (TstdfTs)" (Ps!Pstd) " (1-Bws) 

Qstd = 154326.99 dscfm 

4370.54 dscmm 

Page 2 
Client Spruance Genco, LLC Test Location Unit NO.1 Page 3 

Project No. 3333 Test Run Three 

Calculations (cont.) 

8) Speciated Volatile Organic HAPs - Concentrations and Emission Rates 

C[SVOHj = M!SVOH] (ug) IVmstd (dscm) 

C[SVOH](lb/dscf) = C[SVOH](ug/dscm) * 1e-06g/ug· 2.20Se-03Ib/g * 0,02832 dscm/dscf 

E[SVOH)(lb/hr) = C[SVOH] (ug/dscm) * (2.20SE-09) (lb/ug) ~ Qstd (dscmm) * 60 (min/hr) 

E[SVOH)(lb/MMBtu) = C[SVOH](lb/dscf} * Fd ~ (20.9/20.9-%02) 

C[SVOH](@ corr. 02) = C[SVOH] (ug/dscm) * [(20.9-corrected %02) I (20.9-actual %02)] 

Corrected 02 percentage is: 7.0 % 

Conc. Conc.@corr. 02 Conc. Emission Rate Emission Rate 

Compound (ug/dscm) (ug/dscm) (lb/dscO (lb/hr) (lb/MMBtu) 

Acetone 540.160 928,088 3_37E-08 3.12E-01 8,599E-04 

Benzene 78.577 135.008 4_91 E-09 4.S4E-02 1.2S1E-04 

Bromobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Bromochloromethane 0.247 0.424 1,S4E-11 1.43E-04 3.931E-07 

Bromodichloromethane 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Bromoform 0,000 0.000 O_OOE+OO O.OOE+OO O.OOOE+OO 

Bromomethane 11.736 20.16S 7.33E-i0 6.79E-03 i.868E-OS 

2-Butanone 9.748 16.748 6.09E-10 S,64E-03 1.SS2E-OS 

n-Butylbenzene 0.000 0,000 O,OOE+OO O.OOE+OO O.OOOE+OO 

sec-Bulylbenzene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

tert-Bulylbenzene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Carbon Disulfide 153.638 263.976 9.S9E-09 8.88E-02 2.446E-04 

Carbon Tetrachloride 00409 0_703 2.S6E-11 2,37E-04 6.518E-07 

Chlorobenzene 0,000 0_000 O.OOE+OO O,OOE+OO O,OOOE+OO 

Chlorodibromomethane 0,000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Chloroethane 0,000 0,000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Chloroform 0_675 1.159 4_21E-11 3.90E-04 1.074E-06 

Chloromethane 39.264 67.463 24SE-09 2.27E-02 6.251 E-05 

2-Chlorotoluene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

4-Chlorotoluene 0.000 0.000 O.OOE+OO O_OOE+OO O.OOOE+OO 

1 ,2-Dibromo-3-ch loropropane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dibromoethane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

Dibromomethane 0.000 0.000 o OOE+OO O_OOE+OO O.OOOE+OO 

1,2-Dichlorobenzene 0.000 0.000 o OOE+OO O.OOE+OO O.OOOE+OO 

1,3-Dichlorobenzene 0,000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,4-Dichlorobenzene 0,000 0,000 O,OOE+OO O.OOE+OO O.OOOE+OO 

Dichlorodifluoromethane 4.429 7,610 2.77E-10 2.S6E-03 7.051 E-06 

1,1-Dichloroethane 0.000 0_000 O,OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

cis-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

trans-1,2-Dichloroethene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

1,1-Dichloroethene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichloropropane 0.000 0.000 O,OOE+OO O.OOE+OO O,OOOE"'OO 

1 ,3·Dichloropropane 0,000 0,000 O.OOE+OO O.OOE+OO O.OOOE"'OO 

2,2-Dichloropropane 0,000 0,000 O.OOE+OO O,OOE+OO O.OOOE"'OO 

cis-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

trans-1 ,3-Dichloropropene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 
Client Spruance Genco, LLC Test Location Unit No.1 Page 4 

Project No. 3333 Test Run Three 

Calculations (cant.) 

Conc. Conc.@corr. og Cone. Emission Rate Emission Rate: 

Compound (ug/dseml (ug/dscml (lb/dscO (Ib/hr) (lbfMMBtu) 

1,1-Dichloropropene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Ethylbenzene 0.113 0.194 7.06E-12 6.54E-05 1.BOOE-07 

Hexaehlorobutadiene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

2-Hexanone 1.131 1.943 7_06E-11 6.54E-04 1.BOOE-06 

Isopropylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

p-Isopropyltoluene 0.000 0.000 O.OOE+OO O,OOE+OO O,OOOE+OO 

Methylene Chloride 147.647 2S3,683 9.22E-09 8.S4E-02 2.3S0E-04 

4-Methyl-2-Pentanone 0.000 0,000 O.OOE+OO O,OOE+OO O,OOOE+OO 

Naphthalene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

n-Propyibenzene 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Styrene 0.152 0.261 9.S0E-12 8,79E-OS 2.421E-07 

1,1,1,2-Tetrachloroethane 0.000 0.000 o OOE+OO O.OOE+OO O.OOOE+OO 

1,1,2,2-Tetraehloroethane 0.000 0.000 O_OOE+OO O.OOE+OO O.OOOE+OO 

Tetraehloroethene 0.160 0.275 9.98E-12 9.24E-OS 2.S45E-07 

Toluene 4.358 7.488 2.72E-10 2,52E-03 6.938E-06 

1,2,3-Trichlorobenzene 0.000 0,000 O.OOE+OO O,OOE+OO O.OOOE+OO 

1,2,4-Trichlorobenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

1,1,1-Trichloroethane 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1,2-Trichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Trichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Trichlorofluoromethane 3.611 6.204 225E-10 2.09E-03 5.748E-06 

1 ,2,3-T riehloropropane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

1,2,4-Trimethylbenzene 0.000 0_000 O.OOE·OO O.OOE·OO O.OOOE+OO 

1,3,5-Trimethylbenzene 0.000 0_000 O.OOE+OO O.OOE·OO O.OOOE·OO 

Vinyl Chloride 0_000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

m-Xylene & p-Xylene 0.285 0.489 1.78E-11 1.65E-04 4.S31E-07 

a-Xylene 0.078 0.134 4,87E-12 4.S1E-OS 1.241E-07 

Total 15.097 24.812 9,15E-10 5.76E-01 1.586E-03 
Unit No 2 
Spruance Genco, LLC 

Richmond, Virginia 

Project No, 3333 

April 22, 2010 

Unit No.2 

Run No.1 

Coal Analysis for F Factor Calculation 

F FACTOR CALCULATION 

INPUT % H= 4.67 Hydrogen Content (%) 

INPUT %c= 70.81 Carbon Content (%) 

INPUT % N= 1.39 Nitrogen Content (%) 

INPUT %0= 551 Oxygen Content (%) 

INPUT %8= 0.83 Sulfur Content (%) 

INPUT GCV= 12563 Gross Calorific Value (Btu/lb) 

Fd = 10"6 * [(3.64*%H) + (1.53*%C) + (0.57*%8) + (O.14*%N) - (0.46·%02)] / GCV 

Fd = 9828 scf/MMBtu 
Spruance Genco, LLC 

Richmond, Virginia 

Project No. 3333 

April 22, 2010 

Unit No.2 

Run No.2 

Coal Analysis for F Factor Calculation 

F FACTOR CALCULATION 

INPUT %H= 4.99 Hydrogen Content (%) 

INPUT %c= 76.57 Carbon Content (%) 

INPUT % N= 1.54 Nitrogen Content (%) 

INPUT %0= 6.47 Oxygen Content (%) 

INPUT %s= 0.88 Sulfur Content (%) 

INPUT GCV= 13751 Gross Calorific Value (Btu/lb) 

Fd = 10'6 ' [(3.64'%H) + (1.53'%C) + (0.57'%8) + (0.14'%N) - (0.46'%02)11 GCV 

Fd = 9676 scflMMBtu 
Spruance Genco, LLC 

Richmond, Virginia 

Project No. 3333 

April 23, 2010 

Unit No.2 

Run No.3 

Coal Analysis for F Factor Calculation 

F FACTOR CALCULATION 

INPUT %H= 4.95 Hydrogen Content (%) 

INPUT %C= 74.35 Carbon Content (%) 

INPUT % N= 1.48 Nitrogen Content (%) 

INPUT %0= 5.61 Oxygen Content (%) 

INPUT %5= 0.89 Sulfur Content (%) 

INPUT GCV= 13221 Gross Calorific Value (Btu/lb) 

Fd = 10A6 > [(3.64>%H) + (1.S3>%C) + (o.sr%S) + (0.14>%N) - (0.46>%02)11 GCV 

Fd = 9826 scf/MMBtu 
3333·7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit No.2· Acid Gases 

04/20/10 

Parameter: Oxygen 

Instrument Span (% 02): 21.96 

Actual Calibration Gas Value (% 02): 

Analvzer Calibration Response (% 02): 

Ana/'i.zer Calibration Error (% Span): 

Zero S~stem Calibration Gas 

Apparent Init. S'i.s. Init. SI@. Final S)@. Fina/,s)@. 

Stack QgJjQ, Cal. Bias Calib. Cal. Bias 

Run Conc. Response (% span) Response (% span) 

4.06 0.02 0.00 0.00 -0.09 

2 4.30 0.00 -0.09 001 -005 

0 0.00 0.01 -0.05 0.00 -0.09 

0 0.00 0.00 -0.09 0.00 -0.09 

0 0.00 0.00 -0.09 0.00 -0.09 

0 0.00 0.00 -0.09 0.00 -0.09 

0 0.00 0.00 -0.09 0.00 -0.09 

0 0.00 0.00 -0.09 0.00 -0.09 

0 0.00 0.00 -009 0.00 -0.09 

0 0.00 0.00 -0.09 0.00 -0.09 

0 0.00 0.00 -0.09 0.00 -0.09 

0 0.00 0.00 -0.09 000 -0.09 

AirNova, Inc. 

EPA Method 7E Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal'i.zer Cali!J.. Gases UQ.scale 

zero low mid high ,s'i.~. Cal. Gas 

0.00 NIA 12.46 21.96 12.46 

0.02 NIA 12.46 21.92 12.46 

0.09 0.00 0.00 ·0.18 

URscale S~stem Calibration Gas 

~ Init. SJ,':s, Init. S'i.s. Final S'i.s. Final SJ,':s. Calib. Actual 

Drift Galib. Cal. Bias Calib. Cal. Bias. Drift Stack 

(% span) Response (% span) Response (% span) (% span) Cone. 

-0.09 12.38 -0.36 12.37 -0.41 -0.05 4.08 

005 12.37 -0.41 12.33 -0.59 -0.18 4.34 

-0.05 12.33 -0.59 0.00 -5674 -56 15 -0.01 

0.00 0.00 -56.74 0.00 -56.74 0.00 ERR 

0.00 0.00 -56.74 0.00 -56.74 0.00 ERR 

0.00 0.00 -56.74 0.00 -56.74 0.00 ERR 

0.00 0.00 -56.74 0.00 -56.74 0.00 ERR 

0.00 0.00 -56.74 0.00 -56.74 0.00 ERR 

0.00 0.00 -56.74 0.00 -56.74 0.00 ERR 

0.00 0.00 -56.74 0.00 -56.74 0.00 ERR 

0.00 0.00 -56.74 0.00 -56.74 0.00 ERR 

0.00 0.00 -56.74 0.00 -56.74 0.00 ERR 
3333-7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, llC 

3333 

Unit No.2 - Acid Gases 

04/20/10 

Parameter: Carbon Dioxide 

Instrumenf Span (% C02): 17.83 

Actual Cali!J.ration GaS Value (% C02)' 

Analyzer Calibration Response (% C02): 

Analyzer Calibration Error (% SQan): 

Zero S~stem Calibr§jtion Gas 

Ag,Qarent Init. S"t.s. Init. S"t.,s:. Final S"t.s. Final S"t,s. 

Stack Ga/ib. Cal Bias Gafib. Cal. Bias 

Run Cone. Resgonse (% s,Qan) Res,Qonse (% sPBn) 

1 14.49 0.11 1.01 0.23 1.68 

2 14.11 0.23 1.68 0.21 157 

0 0.00 0.21 1.57 0.00 0.39 

0 0.00 0.00 0.39 0.00 0.39 

0 0.00 0.00 0.39 0.00 0.39 

0 0.00 0.00 0.39 0.00 0.39 

0 0.00 0.00 0.39 0.00 0.39 

0 0.00 0.00 0.39 0.00 0.39 

0 0.00 0.00 0.39 0.00 0.39 

0 0.00 0.00 0.39 0.00 0.39 

0 0.00 0.00 0.39 0.00 0.39 

0 0.00 000 0.39 0.00 039 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal"t,zer Cali!J.. Gases UQscale 

,ero low mid high S"t.s. Cal. Gas 

0.00 N/A 12.39 17.83 12.39 

-0.07 N/A 12.41 17.89 12.41 

-0.39 0.00 0.11 0.34 

U(:!scale S~stem Qalibration Gas 

~ Init. S!!s. Init. S"t.s. Final S):::s. Final S!!S Galib. Actual 

Drift Calib. Cal. Bias Cali!J.. Cal. Bias Drift Stack 

f% s,QanJ Res,Qonse (% wan) Resgonse (% sgan) (% s,Qan) Cone. 

0.67 12.38 -0.17 12.31 -0.56 -0.39 14.57 

-0.11 12.31 -0.56 12.32 -0.50 0.06 14.23 

-1.18 12.32 -0.50 0.00 -69.60 -69.10 -0.21 

0.00 0.00 -69.60 0.00 -69.60 0.00 ERR 

0.00 0.00 -6960 0.00 -69.60 0.00 ERR 

0.00 0.00 -69.60 0.00 -69.60 0.00 ERR 

0.00 0.00 -69.60 000 -69.60 0.00 ERR 

0.00 0.00 -69.60 0.00 -69.60 0.00 ERR 

0.00 0.00 -69.60 0.00 -69.60 0.00 ERR 

0.00 0.00 -69.60 0.00 -69.60 0.00 ERR 

0.00 0.00 -69.60 0.00 -69.60 0.00 ERR 

000 0.00 -69.60 0.00 -6960 0.00 ERR 
3333·7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit No.2· Acid Gases 

04/20110 

Parameter: Nitrogen Oxides (as N02) 

Instrument Span (ppmV NOx): 232.6 

Actual Calibration Gas Value (ppmV NOx): 

Analvzer Calibration Response (ppmV NOx): 

AnalYZer Calibration Error (% Span); 

Zero S~stem Calibr!ltion Gas 

APl2amnt Init. 5\::s. Init. S~s. Final S\::s. Final S~s. 

Stack Calib Cal. Bias Ca/ib. Cal. Bias 

Run Conc. Response (% span) Response f% span) 

198.7 0.0 -0.52 00 -0.52 

2 198.0 0.0 -0.52 0.0 -0.52 

0 0.0 0.0 -0.52 0.0 -0.52 

0 0.0 0.0 -0.52 0.0 -0.52 

0 00 0.0 -0.52 0.0 -0.52 

0 0.0 0.0 -0.52 0.0 -0.52 

0 0.0 00 -0.52 0.0 -0.52 

0 0.0 0.0 -0.52 0.0 -0.52 

0 0.0 0.0 -0.52 0.0 -0.52 

0 0.0 0.0 -0.52 0.0 -0.52 

0 00 0.0 -0.52 00 -0.52 

0 0.0 00 -0.52 0.0 -0.52 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal-aer Calib. Gases Upscale 

..", low mid high S\::s. Cal. Gas 

0.0 0.0 122.1 232.6 122.1 

1.2 0.0 120.9 233.9 120.9 

0.52 0.00 -0.54 0.54 

Uj2scale S~stem ~alibration Gas 

1!..a1Lt.L Init. S\::s. Init. S\:::s. Final S\:::s. Final S\::s. Calib. Actual 

Drift Calib. Cal. Bias Calib. Qal. Bias Drift Stack 

f% span) Response f% span) Response (% span) (% span) Conc. 

0.00 120.9 -0.02 122.1 0.52 0.54 199.7 

0.00 122.1 0.52 120.9 0.00 -0.52 199.0 

0.00 120.9 0.00 0.0 -51.98 -51.98 0.0 

0.00 00 -51.98 0.0 -51.98 0.00 ERR 

0.00 00 -51.98 0.0 -51.98 0.00 ERR 

0.00 0.0 -51.98 0.0 -51.98 0.00 ERR 

0.00 0.0 -51.98 0.0 -51.98 0.00 ERR 

000 0.0 -51.98 0.0 -51.98 0.00 ERR 

0.00 0.0 -51.98 0.0 -51.98 0.00 ERR 

0.00 0.0 -51.98 00 -51.98 0.00 ERR 

0.00 0.0 -51.98 0.0 -51.98 0.00 ERR 

0.00 00 -51.98 0.0 -51.98 0.00 ERR 
3333·7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit No.2 - Acid Gases 

04/20/10 

Parameter: Sulfur Dioxide 

Instrument Span (ppmV S02): 89.9 

Actual Calibration Gas Value (oomV S02).-

Analyzer Calibration Response (ppmV son 

Analyzer Calibration Error (% Span): 

Zero Sy:stem Calibmtion Gas 

Apparent Init. Sys. Init. Sys. Final Sys. Final Sy:s. 

S!fg;f<, Calib. Cal. Bias Calib. k§.l. Bias 

Run Conc. Respont!e (% span) Response (% span) 

30,9 0.3 0.00 -0.8 -1 30 

2 33.3 -0.8 -1.30 1.8 1.64 

0 0.0 18 1.64 0.0 -0.38 

0 0.0 0.0 -0.38 0.0 -0.38 

0 0.0 0.0 -0.38 0.0 -038 

0 0.0 0.0 -0.38 0.0 -0.38 

0 0.0 0.0 -0.38 0.0 -0.38 

0 0.0 0.0 -0,38 0.0 -0.38 

0 00 0.0 -0.38 0.0 -0.38 

0 00 0.0 -0.38 00 -0.38 

0 0.0 0.0 -0.38 00 -0.38 

0 0.0 0.0 -0.38 0.0 -0.38 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Analyzer Calib. Gases Upscale 

""'" low mid high Sys. Cal. Gas 

00 0.0 50.7 899 50.7 

0.3 0.0 510 89.0 51.0 

0.15 0.00 0.15 -0.38 

Up'seale Sy:stem Calibration Gas 

Calib. Inil. Sy:s. Init. Sys. Final Sys. Final Sys. Calib. ~ 

Drift Calib. Cal. Biat! Calib. Cal. Bias Drift Stack 

(% span) Response (% span) Response f% span} r% span) Cone. 

-1.30 51,0 0.00 51.0 0.00 0.00 30.8 

2.94 51.0 0.00 50.6 -0.44 -0.44 33.1 

-2.01 50.6 -0.44 0.0 -56.73 -56.28 ·1.9 

0,00 0.0 -56.73 0.0 -56.73 0.00 ERR 

0.00 00 -56.73 0.0 -56.73 0.00 ERR 

000 0.0 -5673 0.0 -56.73 0.00 ERR 

0.00 0.0 -56.73 00 -56.73 0.00 ERR 

0,00 0.0 -56.73 0.0 -56.73 0.00 ERR 

0.00 0.0 -56.73 00 -5673 0.00 ERR 

0.00 0.0 -56.73 0.0 -56.73 0.00 ERR 

0.00 0.0 -56.73 0.0 -56.73 0.00 ERR 

0.00 0.0 -56.73 0.0 -56.73 000 ERR 
3333-7E-R3 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit No.2 - Acid Gases 

04/21/10 

Parameter: Oxygen 

Instrument Span (% 02): 21.96 

Actual Calibration Gas Value (% 02): 

AnalYZer Calibration Response (% 02!: 

Analvzer Calibration Error (% Span!: 

Zero S),stem Calibration Gas 

AQ[2arent Init. Svs. Init. S\,:s. Final S~s. Final S~s. 

Stack Cafib. Cal. Bias Calib. Cal. Bias 

Run Conc. Response (% soan! Response (% s[2an! 

3 4.92 0.02 0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 000 -0.05 0.00 -0.05 

0 0.00 000 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -005 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

a 0.00 0.00 -0.05 0.00 -0.05 

AirNova, Inc. 

EPA Method 7E Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal~zer Calib. Gases U[2scg/€!. 

""" low mid high S\,:s. Cal. Gas 

0.00 NIA 12.46 21.96 12.46 

0.01 NIA 12.39 21.74 12.39 

0.05 0.00 -0.32 -1.00 

Ul2scale Sllstem Calibration Gas 

~ Init. S)!s. Init. S)!~. Final S)!:s. Final S~s. Calib. Actual 

Drift Calib. e.g/. Bias Calib. Cal. Bia~ Drift Slack 

(% span) Response (% span! Response (% spgn! (% span) Cone. 

-0.09 12.35 -0.18 12.37 -0.09 0.09 4.95 

0.00 12.37 -009 0.00 -56.42 -56.33 0.00 

0.00 0.00 -56.42 0.00 -56.42 0.00 ERR 

0.00 0.00 -56.42 0.00 -56.42 0.00 ERR 

0.00 000 -56.42 0.00 -56.42 0.00 ERR 

0.00 0.00 -56.42 0.00 -56.42 0.00 ERR 

0.00 0.00 -56.42 0.00 -56.42 000 ERR 

0.00 0.00 -56.42 0.00 -56.42 0.00 ERR 

0.00 0.00 -56.42 0.00 -56.42 0.00 ERR 

0.00 0.00 -56.42 0.00 -56.42 0.00 ERR 

0.00 0.00 -56.42 0.00 -56.42 0.00 ERR 

0.00 0.00 -56.42 0.00 -56.42 0.00 ERR 
3333-7E-R3 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit No.2 - Acid Gases 

04121/10 

Parameter: Carbon Dioxide 

Instrument Span f% C02): 17,83 

Actual Calibration Gas Value (% C02): 

Analy.zer Calibration Rewonse f% C02): 

Analvzer Calibration Error (% Span): 

Zero Sy:stem Calibration Gas 

At2Qarent Init. Sy's. Init. Sy's. Final Sy.s. Final S\::s. 

Stack Calib. Clil. Bias Calib. Cal. Bias 

Run Cone. Res{2onse f% soan) Res{2onse (% span) 

3 13.76 0.22 0.50 0.16 0.17 

0 0.00 0.16 0.17 0.00 -0.73 

0 0.00 0.00 -0.73 0.00 -0,73 

0 0.00 0.00 -0.73 0.00 -0.73 

0 0.00 0.00 -0.73 0.00 -0.73 

0 0.00 0.00 -0.73 0.00 -0.73 

0 0.00 0.00 -0.73 0.00 -0.73 

0 0,00 0.00 -0.73 0.00 -0.73 

0 0.00 0.00 -0.73 0.00 -0.73 

0 0.00 000 -0.73 0.00 -073 

0 0.00 0.00 -0.73 0.00 -0.73 

0 0.00 0.00 -0.73 0.00 -0.73 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Analy.zer Calib. Gases U{2scale 

zero low mid hioh $)i's. Cal. Gas 

0.00 NIA 12.39 17,83 12.39 

0.13 NIA 12.38 17.75 12.38 

0.73 0.00 -0.06 -0.45 

Uescale Sy:stem Calibration Gas 

Calib. lnit. Sy's. Init. S\::s Final $\:::s. Finlil S\::s. Calib. Actual 

Drift Calib. Cal. Bias Calib. Cal. Bias Drift Stack 

(% span) Response (% span) Response (% s{2an) (% span) Cone. 

-0.34 12.32 -0.34 12.32 -0.34 0.00 13.86 

-0,90 12.32 -0.34 0.00 -69.43 -69.10 -0.16 

0.00 0.00 -69.43 0.00 -69.43 0.00 ERR 

0.00 0,00 -69.43 0.00 -69.43 0.00 ERR 

0.00 0.00 -69.43 0.00 -69.43 0.00 ERR 

0.00 0.00 -69.43 0.00 -69.43 0.00 ERR 

0.00 0.00 -69.43 0.00 -69.43 0.00 ERR 

0.00 0.00 -69.43 0.00 -69.43 0.00 ERR 

0.00 0.00 -69.43 0.00 -69.43 0.00 ERR 

0.00 0.00 -69.43 0.00 -69.43 0.00 ERR 

0.00 0.00 -69.43 0.00 -69.43 0.00 ERR 

000 0.00 -69.43 0.00 -69.43 0.00 ERR 
3333-7E-R3 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit No.2 - Acid Gases 

04121/10 

Parameter: Nitrogen Oxides (as N02) 

Instrument Span (ppmV NOx): 232.6 

Actual Calibration Gas Valu!1. fppmV NOx): 

AnalvzerCalibration R!1.SDOnSe (opmV NOx): 

Analyzer Calibration Error(% Spgn): 

Zero S~stem Calibration Gas 

AE2J2arent Init. Sys. Init. S't.s. Final Sys. Final S:'t.s. 

Stack Galib. Cal. Bias Ga/ib. Ca'- Bias 

Run Cone. Response (% span) Re§.Qonse (% span) 

3 189.9 0.0 0.00 0.0 0.00 

0 0.0 0.0 0.00 00 0.00 

0 00 0.0 000 00 0.00 

0 0.0 0.0 0.00 0.0 0.00 

0 0.0 0.0 0.00 0.0 0.00 

0 0.0 0.0 0.00 0.0 0.00 

0 0.0 00 0.00 0.0 0.00 

0 0.0 0.0 0.00 0.0 0.00 

0 0.0 0.0 0.00 0.0 0.00 

0 0.0 0.0 0.00 0.0 0.00 

0 0.0 0.0 0.00 0.0 0.00 

0 00 0.0 0.00 00 0.00 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal't.zer Calib. Gase§. UpSCal!1. 

zero low mid high S't.s. Cal. Gas 

0.0 00 122.1 232.6 122.1 

0.0 0.0 120.9 232.7 120.9 

000 0.00 -0.52 0.04 

Uj;lscale System Calibration Gas 

Calib. lnit S~· Init. S\:::s. Final S:'t.s. Final Sys. Ga/ib. Actual 

Drift ka.!i!L Cal. Bias Calib. Gal. Bias Dnft Stack 

(% span) Response (% span) R!1.sponSe (% span) (% §.ognJ Conc. 

0.00 120.9 0.00 119.6 -0.56 -0.56 192.9 

0.00 119.6 -0.56 0.0 -51.98 -51.42 0 .• 

0.00 0.0 -51.98 0.0 -51.98 0.00 ERR 

0.00 0.0 -51.98 0.0 -51,98 0.00 ERR 

0.00 0.0 -51.98 0.0 -51.98 0.00 ERR 

0.00 0.0 -51.98 0.0 -51.98 0.00 ERR 

0,00 0.0 -51.98 0.0 -51.98 0.00 ERR 

0.00 00 -51.98 0.0 -51.98 0.00 ERR 

000 0.0 -51.98 0.0 -51.98 0.00 ERR 

0.00 0.0 -51,98 0.0 -51.98 0,00 ERR 

0.00 0.0 -51.98 0.0 -51.98 000 ERR 

0.00 0.0 -51.98 00 -51,98 0.00 ERR 
3333-7E·R3 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit No_ 2 - Acid Gases 

04/21/10 

Parameter: Sulfur Dioxide 

Instrument Span (ppm V S02): 89.9 

Actual Calibration Gas Value (ppmV S021. 

Analvzer Calibration Response (ppmV S02): 

AnaNzer Calibration Error(% Span): 

Zero S~tem Calibration Gas 

ApQar~nt Init. S)!s. Init. S,,-s. Final S,,-s. Final S,,-s. 

Stack Ca/ib. Cal. Bias Calib. Cal. Bias 

Run Conc_ Respon,s:§: (% span) Response (% sPf1.n) 

3 31.6 0.4 0.00 1.0 0,60 

0 0.0 1.0 0.60 0.0 -0.49 

0 0.0 0.0 -0,49 0.0 -0.49 

0 0.0 0.0 -0.49 0.0 -0.49 

0 0.0 0.0 -0.49 0.0 -0.49 

0 0.0 0.0 -0,49 0.0 -0.49 

0 0.0 00 -0,49 0.0 -0.49 

0 00 0.0 -0,49 00 -0.49 

0 0.0 0.0 -0.49 00 -0,49 

0 0.0 0.0 -0.49 0.0 -0.49 

0 0.0 0.0 -0.49 0.0 -0.49 

0 0.0 0.0 -0.49 0.0 -0.49 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Ana/,,-zer Calib. Ga,s:§:s UQ.,s:QB.le 

zero low mid high S,,-s. Cal. Gas 

0.0 0.0 50.7 89.9 50.7 

0.4 0.0 50.8 89.0 50.8 

0.19 0.00 0.04 -0.39 

Ur;lscale Sy:stem Calibration Gas 

Calib. lnit. S,,-s. Init. S,,-s. Final S~. Final S)!s. Calib. Actual 

Drift Calib. Cal. Bias Calib_ Cal. Bias Drift Stack 

(% span) Response (% span) Response (% span) (% sQanJ Conc. 

0.60 50.8 0.00 49.7 -1.22 -122 31.6 

-1.09 49.7 -1.22 0.0 -56.51 -55.28 -1.0 

0.00 0.0 -5651 0.0 -56.51 0.00 ERR 

0.00 00 -56_51 0.0 -56.51 0,00 ERR 

0.00 00 -56.51 0.0 -56.51 0.00 ERR 

0.00 00 -56.51 0.0 -56.51 0.00 ERR 

000 0.0 -56.51 0.0 -56.51 0.00 ERR 

0.00 0.0 -56.51 0.0 -56.51 0.00 ERR 

0.00 0.0 -56.51 0.0 -56_51 0.00 ERR 

0.00 0.0 -56.51 0.0 -56_51 0_00 ERR 

0.00 0.0 -56.51 0.0 -56.51 0_00 ERR 

0.00 0.0 -5651 0.0 -56.51 0.00 ERR 
3333-HCI-HF-R1 

Client 

Project No. 

Test location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP= 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

t = 

Os = 

As = 

Cp= 

Kp= 

K1 = 

K2= 

K3 = 

Fd = 

CF= 

CF = 

[02[ 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and 26A 

(Flows, 02/C02, H20,and HCI/HF] 

Spruance Genco, LLC 

3333 

Unit No.2 

One 

04/20/10 

1107-1414 

373.9 cc 

Emission Data 

117.848 dcf 

-0.47 in. H20 

30.04 in. Hg 

30.01 In. Hg 

29.92 in. Hg 

o 7286 in. H20 '\5 

1.468 in. H20 

538.4 R 

649.2 R 

527.7 R 

0.248 in 

0.000335 sq. ft. 

1.01 

180 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq, ft, Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)'(inHg)]'.5}/[s·R·onH20] Pilot lube constant 

17.637 R/in.Hg 

0.047070 cu.ftlml 

0.0026688 in.Hg-ef/ml-R 

9828 sef/MMBtu 

9.461 E-OB Ib/dscf I ppmVd 

5.192E-08 Ib/dseff ppmVd 

Instrumental Data 

4.0B %-dry 

14.57 %-dry 

81.35 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCI 

Conversion Factor for HF 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y 'Vm ' (Pb + dH/13.6) I Tm 

Vmstd = 117.557 dscf 

3,33 dscm 

Unit No.2 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 • Vie 

Vw(std) = 17.599 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws = 0.130 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [ ((44'%C02) + (32'%02) + (28'%N2)) • (1-Bws) J + (18'Bws) 

Ms= 28,87 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP)' (Ts/Ps'Ms)A5 

Vs = 4529 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min * Vs ., As 

Qa = 226446.6 efm 

6413,0 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa' (TstdlTs)' (Ps/Pstd)' (1-Bws) 

Qstd = 160555.3 dscfm 

4546.9 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Hydrogen Chloride Concentration and Emissions 

Unit No.2 

One 

M[HCI[ = M[CI-lImg)' MW[HCI](mg/mmol) 1 MW[CI-](mg/mmol) 

Page 3 

C[HCI] = (M[HCI](mg) • 2.205E-06(lb/mg) • 21.85(scf·inHg/lbmol·R) • K1 • 10'6) 1 (MW[HCI](lb/lbmol) • Vmstd(d 

C[HCI](@corr 02) = C[HClllppmV)' [(20.9-corrected 02) 1 (20 9-actual %02)] 

E[HCI] = M[HClllmg) • Qstd(dscfm) • (2.205E-06)(lb/mg) • 60(min/hr) 1 Vmstd(dscD 

E[HCI] = C[HCI](ppmV)' Fd' CF(HCI)' (20.9/(20.9-%02)] 

< M[HCI] = 

< C[HCI] = 

< C[HCI] = 

< E[HCI] = 

< E[HCI] = 

0.07 mg 

0.014 ppmV 

0.011 ppmV 

0.013 Ib/hr 

1 60E-05 Ib/MMBtu 

9) Hydrogen Fluoride Concentration and Emissions 

C[HF] = M[HF](mg) 1 Vmstd(dscm) 

(@ 7.0 % 02) 

C[HF] = (M[HF](mg) • 2.205E-06(lb/mg) '21.85(scr'InHgllbmol'R) , K1 ' 10'6) 1 (MW[HF](Ibllbmol) 'Vmstd(dsc 

C[HF](@corr. 02) = C[HF](mg/dscm)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HF] = C[HF](mg/dscm)' Qstd(dscmm)' (2.205E-06)(lb/mg)' 60(min/hr) 

E[HF] = C[HFllppmV)' Fd' CF(HF)' (20.9/(20.9-%02)) 

M[HF] = 

C[HF] = 

C[HF] = 

C[HF] = 

E[HF] = 

E[HF] = 

10) Isokinecity, I. 

0.670 mg 

0.201 mg/dscm 

0.242 ppmV 

0.200 ppmV ( @ 

0.121 Ib/hr 

1.53E-04 Ib/MMBtu 

7.0 

% I = (100'Ts'(K3OVlc+(Vm·YlTm)(Pb+dH/13.6)))/(60't·Ps'Vs'An) 

%1= 101.0 

% 02) 
3333-HCI-HF-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

lest Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts= 

Tstd= 

Dn = 

An= 

y= 

t= 

Ds = 

As= 

Cp = 

Kp= 

K1 = 

K2= 

K3= 

Fd = 

CF = 

CF = 

[02] 

]C02] 

]N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and 26A 

(Flows, 021C02, H20,and HCIIHF) 

Spruance Genco, LLC 

3333 

Unit No.2 

Two 

04/20/10 

1430-1738 

376.3 cc 

120.241 del 

Emission Data 

,·0.45 in. H20 

29.99 in, Hg 

29.96 in. Hg 

29,92 in. Hg 

0.7343 in. H20 '\5 

1 533 in. H20 

5410 R 

6500 R 

527.7 R 

0.248 in. 

0.000335 sq. ft. 

1.01 

180 min. 

10.300 ft 

83.323 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle onfice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R"mH20] Pitot tube constant 

17.637 Rlin Hg 

0047070 cu.ftlml 

0.0026688 in.Hg-ellml-R 

9676 scf/MMBtu 

9.461 E-08 Ibldsell ppmVd 

5.192E-08 Ibldsell ppmVd 

Instrumental Data 

4.34 %-dry 

1423 %-dry 

81.43 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for Hel 

Conversion Factor for HF 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y' Vm' (Pb + dH/13.6) /Tm 

Vmstd = 119.174 dscf 

3.38 dscm 

Unit NO.2 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 'Vic 

Vw(std) = 17712 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.129 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (1-Bws) I + (18'Bws) 

Ms = 28.84 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp , Cp , (dP) , (Ts/Ps'Msj'.5 

Vs = 45.73 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min * Vs * As 

Qa = 228644 8 cfm 

64752 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

Qstd = 161817.4 dscfm 

4582.7 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Hydrogen Chloride Concentration and Emissions 

Unit No.2 

Two 

M[HCI] = M[CI-lImg) , MW[HCllImglmmol) 1 MW[CI-](mglmmol) 

Page 3 

C[HCI] = (M[HCI](mg) , 2 205E-06(lblmg) , 21.85(scf·'nHgllbmol'R) , K1 ' 10'6) 1 (MW[HCI)(Ibllbmol) 'Vmstd(d 

C[HCIII@corr. 02) = C[HCI](ppmV)' [(20.9-corrected 02) 1 (20 9-actual %02)] 

E[HCI] = M[HCI](mg)' Qstd(dscfm)' (2.205E-06)(lblmg)' 60(minlhr) 1 Vmstd(dscn 

E[HCI] = C[HCllIppmV)' Fd' CF(HCI)' (20.91(20.9-%02)) 

< M[HCI] = 0.08 mg 

< C[HCI] = 0.016 ppmV 

< C[HCI] = 0.013 ppmV (@ 7.0 %02) 

< E[HCI] = 0.014 Iblhr 

< E[HCI] = 1.81E-05IbIMMBtli 

9) Hydrogen Fluoride Concentration and Emissions 

C[HF] = M[HF](mg) 1 Vmstd(dscm) 

C[HF] = (M[HF](mg) , 2 205E-06(lblmg) , 21.85(scf'inHgllbmol'R) , K1 ' 10'6) 1 (MW[HFlIlbllbmol) • Vmstd(dsc 

C[HF](@corr. 02) = C[HF](mgldscm)' [(20.9-corrected 02) 1 (20.9-octual %02)] 

E[HF] = C[HF](mgldscm)' Qstd(dscmm)' (2.205E-06)(lblmg)· 60(minlhr) 

E[HF] = C[HF](ppmV)' Fd' CF(HF)' (20.91(20.9-%02)) 

M[HF] = 

C[HF] = 

C[HF] = 

C[HF] = 

E[HF] = 

E[HF] = 

10) Isokinecity, I. 

0.700 mg 

0.207 mg/dscm 

0.249 ppmV 

0.209 ppmV (@ 

0.126 Iblhr 

1.58E-04 IblMMBtu 

7.0 

% I = (1 00'Ts'(K3'Vlc+(Vm·YlTm)(Pb+dHI13.6)))1(60't'Ps'Vs·An) 

%1= 101.6 

%02) 
3333-HCI-HF-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm = 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dp = 

dH = 

Tm= 

Ts= 

Tstd= 

Dn = 

An = 

y= 

t = 

Ds = 

As = 

Cp = 

Kp= 

K1 = 

K2= 

K3= 

Fd = 

CF= 

CF= 

[02[ 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and 26A 

(Flows, 021C02, H20,and HCtIHF) 

Spruance Genco, LLC 

3333 

Unit No.2 

Three 

04121110 

0655-1000 

381.8 cc 

114.872 del 

Emission Data 

-045 in, H20 

29_87 in. Hg 

29.84 in. Hg 

29.92 in, Hg 

07263 in. H20 ".5 

1.443 in. H20 

514.2 R 

647.6 R 

527.7 R 

0,248 in. 

0.000335 sq. ft. 

1.01 

180 min, 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter readfng 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbllbmol),(inHg)]'.5)/[s'R'inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.ftlml 

0.0026688 in.Hg-cf/ml-R 

9826 scf/MMBtu 

9.461 E-08 Ibldscf I ppmVd 

5.192E-08 Ibldscff ppmVd 

Instrumental Data 

4.95 %-dry 

13.86 %-dry 

81.19 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCI 

Conversion Factor for HF 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y' Vm' (Pb + dH/13.6) I Tm 

Vmstd = 119.290 dscf 

338 dscm 

Unit No 2 

Three 

2) Volume of water vapor collected at standard conditions, Vw{std). 

Vw(std) = K2 • Vic 

Vw(std) = 17.971 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0131 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) [+ (1S'Bws) 

Ms= 28.79 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP)' (Ts/Ps·Ms)'.5 

Vs = 45.29 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min '* Vs '* As 

Qa = 226405.0 cfm 

6411.8 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

Qstd = 159883.5 dscfm 

4527.9 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Hydrogen Chloride Concentration and Emissions 

Unit No 2 

Three 

M[HCI] = M[CI-](mg) , MW[HCI](mglmmol) 1 MW[CI-](mglmmol) 

Page 3 

C[HCI] = (M[HCI](mg) , 2 205E-06(lblmg) , 21.85(scf'lnHgllbmol'R) , K1 ' 10'6) 1 (MW[HCI](Ibllbmol) 'Vmstd(d 

C[HCI](@corr. 02) = C[HCI](ppmV)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HCI] = M[HCI](mg) , Qstd(dscfm) , (2.205E-06)(lblm9) '60(minlhr) 1 Vmstd(dscf) 

E[HCI] = C[HCI](ppmV)' Fd' CF(HCI)' (20.91(20.9-%02)] 

< M[HCI]= 0.07 mg 

< C[HCI] = 0.014 ppmV 

< C[HCI] = 0.012 ppmV (@ 7.0 % 02) 

< E[HCI]= 0.012 Ibfhr 

< E[HCI] = 1.67E-05 IblMMBtu 

9) Hydrogen Fluoride Concentration and Emissions 

C[HF] = M[HF](mg) IVmstd(dscm) 

C[HF] = (M[HF](mg) '2.205E-06(lblm9) , 21.85(scf'lnHgllbmol'R) , K1 ' 10'6) 1 (MW[HF](Ibllbmol) , Vmstd(dsc 

C[HF](@corr. 02) = C[HF](mgldscm)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HF] = C[HF](mgldscm)' Qstd(dscmm)' (2.205E-06)(lblmg)' 60(minlhr) 

E[HF] = C[HF](ppmV) , Fd ' CF(HF) , (20.91(20 9-%02)] 

M[HF] = 

C[HF] = 

C[HF] = 

C[HF] = 

E[HF] = 

E[HF] = 

10) Isokinecity,l. 

0.620 m9 

0,184 mgfdscm 

0.221 ppmV 

0.192 ppmV (@ 

0.1101bfhr 

1 48E-04 IblMMBtu 

7.0 

% 1 = (100'Ts'(K3'Vlc+(Vm"YlTm)(Pb+dHI13.6)))1(60't'Ps'Vs'An) 

% I = 103.0 

% 02) 
Client 

Project No. 

Test Location 

Fuel Type 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts= 

Tstd= 

y= 

t= 

On = 

An = 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[02J 

[C02J 

[N2J 

[NOxJ 

[802J 

AirNova, Inc. 

EPA Methods 1, 2, 3A, 4, 6 and 7E 

(Flows, 02/C02, H20, 802 and NOx) 

Spruance Genco, LLC 

3333 

Unit No, 2 

Coal 

One 

04/20/10 

1107-1414 

Emission Data 

373.9 cc 

117,848 dcf 

-0.47 in. H20 

30,04 in. Hg 

30.01 in. Hg 

2992 in. Hg 

0.7286 in. H20 ".5 

1.47 in. H2O 

538.4 R 

649.2 R 

5277 R 

1.01 

180 min. 

0.248 in, 

0.000335 sq. ft. 

10.300 ft, 

83,323 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

o 84 Pitot tube coefficient 

85.49 ft.[ (lb/lbmolt(1 n Hg) J". 5}/[ s*R*i n H20] 

17.637 R/in. Hg constant 

Page 1 of 3 

0.047070 cu.fVml constant Pitot tube constant 

0.0026688 in.Hg-cf/ml-R 

9828 scf/MMBtu 

Instrumental Data 

4.08 %-dry 

14.57 %-dry 

81.35 %-dry 

199.7 ppmV-dry 

30.8 ppmV-dry 

constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Nitrogen Oxides concentration 

Sulfur Dioxide concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y" Vm" (Pb + dH/13 6) I Tm 

Vmstd = 117.557 dscf 

3.329 dscm 

Unit No.2 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 ~ Vic 

Vw(std) = 17.599 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws'" 0.1302 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44"%C02) + (32"%02) + (2S*%N2»" (1-Bws) 1 + (1S*Bws) 

Ms= 28.867 tbl tbmote 

5) Average stack gas velocity, Vs. 

Vs = Kp" Cp" (dP) " (TslPs*Ms)ll.5 

Vs = 45.295 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min" Vs " As 

Oa = 226446.6 cfm 

6413.0 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Ostd = Oa" (TstdfTs)"" (Ps/Pstd)" (1-Bws) 

Qstd = 160555.3 dscfm 

4546.9 dscmm 

Page 2 of 3 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cant.) 

Umt No, 2 

One 

Page 3 of3 

9) Nitrogen Oxides concentrations and emissions 

Carr. C[NOx] = «20.9-02% carr. value)/(20.9-actual avg 02% value))"Avg. raw NOx value 

E[NOx] = (C[NOx]"Mol Wt[NOx]*60(min/hr)*Qstd(dscfm))/(Molar Vol. air"10"6) 

E[NOx Ib/MMBtu] = Cd * Fd • (20.9/(20.9-actual 02%)) 

C[NOx] = 199.7 ppmVd 

C[NOx] = 165.0 ppmVd corrected to 7 % 02 

Mol. Wt. [NOx]= 46,01 Ib/lb-mole 

Molar vol air= 

E[NOx[ = 

Cony Factor, 

E[NOx[ = 

385 scf/lb-mole @ 

229.90 Ib/hr 

68 

1.194E-07 convert ppmV to Ib/scf NOx 

0,291 lb/MMBtu 

10) Sulfur Dioxide concentrations and emissions 

def F 

Corr. C[S02] = ({20.9-02% carr. value)/(20.9-actual avg. 02% vaJue))·Avg. raw 502 value 

E(lb/MMBtu) = Cd(lb/scf) ~ Fd(scf/MMBtu) " [20.9 I (20.9-% 02)] 

E[S02 Ib/hr] = (C[S02]*Mol Wt[S02]*60(min/hr)*Qstd(dscfm))/(Molar Vol. alr"10"6) 

C[S02] = 30.8 ppmV (dry) Actual Conc. 

C[S02] = 25.5 ppmVd corrected to 7 % 02 

Mol. WI. [S02]= 64.06 Ib/lb-mole 

Molar vol air= 

Conv Factor, 

E[S02[ = 

E[S02[ = 

385 scf/lb-mole @ 68 

1.66E-07 convert ppmV to Ib/scf S02 

0.062 Ib/MMBtu 

49.37 Ib/hr 

def F 
Client 

Project No. 

Test Location 

Fuel Type 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

y= 

t= 

On = 

An = 

Ds= 

As= 

Cp= 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

INPUT [02] 

INPUT [C02] 

[N2] 

INPUT [NOx] 

INPUT [S02] 

AirNova, Inc. 

EPA Methods 1, 2, 3A, 4, 6 and 7E 

(Flows, 02/C02, H20, 502 and NOx) 

Spruance Genco, LLC 

3333 

Unit No.2 

Coal 

Two 

04/20/10 

1430-1738 

376.3 cc 

Emission Data 

120.241 dcf 

-0.45 in. H20 

29.99 in. Hg 

29.96 in. Hg 

29.92 in. Hg 

0.7343 In. H20 ".5 

1.53 in. H20 

541.0 R 

650.0 R 

527.7 R 

1.01 

180 min. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

0.248 in Nozzle diameter 

0.000335 sq. ft. Nozzle area 

10.300 ft. Diameter of stack 

83 323 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[ (Ib/lbmol)*(in Hg)J". 5}/[ s~R*inH201 

17.637 R/in.Hg constant 

0.047070 cu.ftlml 

00026688 in.Hg-cf/ml-R 

9676 scf/MMBtu 

Instrumental Data 

4.34 %-dry 

14.23 %-dry 

81.43 %-dry 

1990 ppmV-dry 

33.1 ppmV-dry 

constant Pitot tube constant 

constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Nitrogen Oxides concentration 

Sulfur Dioxide concentration 

Page 1 of 3 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm * (Pb + dH/13 6) ITm 

Vmstd= 119.174 dscf 

3.375 dscm 

Unit No.2 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 17.712 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.1294 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32*%02) + (28*%N2»· (1-Bws) 1 + (18*Bws) 

Ms = 28.839 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp * (dP) " (TsJPs*Ms)".5 

Vs = 45735 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min * Vs • As 

Oa = 228644.8 cfm 

6475.2 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Ostd = Oa • (Tstd/Ts) • (Ps/Pstd) * (1-Bws) 

Ostd = 161817.4 dscfm 

4582.7 dscmm 

Page 2 of 3 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test location 

Test Run 

Calculations (cont.) 

Unit No 2 

Two 

Page 3 ot3 

9) Nitrogen Oxides concentrations and emissions 

Corr. C[NOx] = «20.9-02% corr value)/{20.9-actual avg 02% value»"Avg. raw NOx value 

E[NOxJ = (C[NOxtMol WI[NOxl~60{min/hrtQstd(d$cfm))/(Molar Vol air*10116) 

E[NOx Ib/MMBtu] = Cd ., Fd ,. (20.9/(20.9-actual 02%» 

C[NOx] = 199.0 ppmVd 

C[NOx] = 1670 ppmVd corrected to 7 % 02 

Mol. WI. [NOx]= 46.01 Ib/lb·mole 

385 scf/lb-mole @ 

230.90 Ib/hr 

Molar vol air- 68 

E[NOx[ = 

Conv Factor. 

E[NOx] = 

1 .194E-07 convert ppmV to Ib/scf NOx 

0290 Ib/MMBtu 

10) Sulfur Dioxide concentrations and emissions 

defF 

Corr. C[802] = ({20.9-02% corr. value)/(20.9-actual avg. 02% value»*Avg. raw 802 value 

E{lb/MMBtu) = Cd(lb/scf) * Fd(scf/MMBtu) * [20.91 (20.9-% 02)J 

E[802Ib/hr] = (C[S02]"Mol Wt[802]*60(min/hr)*Qstd(dscfm»/{Molar Vol. air"10116) 

C[802] = 33.1 ppmV (dry) Actual Cone. 

C[S02] = 27.8 ppmVd corrected to 7 % 02 

Mol. WI. [802]= 64.06 Ib/lb-mole 

Molar vol air= 

Conv Factor. 

E[S02] = 

E[S02] = 

385 scf/lb-mole @ 68 

1.66E-07 convert ppmV to Ib/scf 802 

0.067 Ib/MMBtu 

5347 Ib/hr 

def F 
Client 

Project No. 

Test Location 

Fuel Type 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

y= 

t= 

Dn = 

An = 

Ds = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[02[ 

[C02[ 

[N2] 

[NOx] 

[S02] 

AirNova, Inc. 

EPA Methods 1, 2. 3A. 4. 6 and 7E 

(Flows, 02/C02. H20, 802 and NOx) 

Spruance Genco, LLC 

3333 

Unit No.2 

Coal 

Three 

04/21/10 

0655-1000 

381.8 cc 

Emission Data 

114.872 dcf 

-0.45 in. H20 

29.87 in. Hg 

29.84 in. Hg 

29.92 in Hg 

0.7263 in. H20 '\5 

1.44 in H20 

514.2 R 

647.6 R 

527.7 R 

1.01 

180 min. 

0.248 in. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

0.000335 sq ft. Nozzle area 

10.300 ft. Diameter of stack 

83.323 sq. ft. Cross sectional area of stack 

o 84 Pitot tube coefficient 

85.49 ft[ (lb/lbmol)*(inHg)]". 5}/( s *R*inH20] 

17.637 R/in.Hg constant 

0047070 CU.fl/ml 

0.0026688 in.Hg-cf/ml-R 

9826 scf/MMBtu 

Instrumental Data 

4.95 %-dry 

13.86 %-dry 

81.19 %-dry 

192.9 ppmV-dry 

31.6 ppmV-dry 

constant Pitot tube constant 

constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Nitrogen Oxides concentration 

Sulfur Dioxide concentration 

Page 1 of 3 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1~ Y * Vm * (Pb + dH/13.6) I Tm 

Vmstd = 119.290 dscf 

3.378 dscm 

Unit No.2 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 17.971 scf 

3) Oecimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.1309 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32"%02) + (28*%N2))" (1-Bws) 1 + (18*Bws) 

Ms = 28790 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp'" Cp * (dP)" (Ts/Ps~Ms)".5 

Vs = 45 287 fps 

6) Average actual stack gas volumetric flowrate. Qa. 

Qa = 60 sec/min ~ Vs ~ As 

Qa = 226405.0 cfm 

6411.8 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa ~ (Tstd/Ts)" (Ps/Pstd);O; (1-Bws) 

Qstd = 159883.5 dscfm 

4527.9 dscmm 

Page 2 of 3 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.2 

Three 

Page 3 of3 

9) Nitrogen Oxides concentrations and emissions 

Corr. C[NOx] = {(20.9-02% carr. value)/{20.9-actual avg. 02% value»"Avg. raw NOx value 

E[NOx] = (C[NOx]*Mol Wt[NOx]*60{min/hr)*Qstd{dscfm))/{Molar Vol. air*1 0"6) 

E[NOx Ib/MMBtu] = Cd· Fd· (20.9/{20.9-actual 02%)) 

C[NOx] = 192.9 ppmVd 

C[NOx] = 168.1 ppmVd corrected to 7 % 02 

Mol. wt. [NOx]= 46.01 Ib/lb-mole 

Molar vol air= 385 scf/lb-mole @ 68 def F 

E[NOx] = 221.15 Ib/hr 

Conv Factor. 

E[NOx] = 

1.194E-07 convert ppmV to Ib/scf NOx 

0297 Ib/MMBtu 

10) Sulfur Dioxide concentrations and emissions 

Carr. C[S02] = ({20.9-02% carr. value)/{20.9-actual avg. 02% value»*Avg. raw S02 value 

E{lb/MMBtu) = Cd{lb/scf) " Fd{scf/MMBtu) • [20.9 I (20.9-% 02)] 

E[S02 Ib/hr] = (C[S02]*Mol Wt[S02t60(min/hrtQstd(dscfm»/{Molar Vol. air"10"6) 

C[S02] = 31.6 ppmV (dry) Actual Conc 

C[S02] = 27.5 ppmVd corrected to 7 % 02 

Mol. wt. [S02]= 

Molar vol air= 

Conv Factor. 

E[S02] = 

E[S02] = 

64.06 Ibllb-mole 

385 scf/lb-mole @ 68 

1 66E-07 convert ppmV to Ib/scf S02 

0.068 Ib/MMBtu 

50.44 Ib/hr 

defF 
3333-HCN-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP= 

dH = 

Tm= 

Ts= 

Tstd= 

On = 

An = 

y=. 

t= 

Ds = 

As= 

Cp= 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

CF= 

[02] 

[C02] 

]N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and Modified 26 

(Flows, 02/C02, H20,and HCN) 

Spruance Genco, LLC 

3333 

Unit No.2 

One 

04/20/10 

1107-1207 

142 cc 

44.207 dcl 

Emission Data 

~O.50 in, H20 

30.04 in, Hg 

30.00 in. Hg 

29.92 in. Hg 

0.7294 in, H20 11,5 

1.820 in. H20 

537.2 R 

647.5 R 

527.7 R 

Din. 

0.000000 sq. ft. 

0.99 

60 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83,323 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbllbmol)'(inHg)]'.5)/]s·WinH20] Pitot tube constant 

17.637 R/in.Hg 

0047070 cU.ft/ml 

0.0026688 in.Hg-cflml-R 

9828 scf/MMBtu 

7.014E-08 Ib/dscfl ppmVd 

Instrumental Data 

4.08 %-dry 

14.57 %-dry 

81.35 %-dry 

constant 

constant 

constant 

Fuel Fador 

Conversion Factor for HCN 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1 * Y * Vm * (Pb + dH/13.6) I Tm 

Vmstd = 43.356 dsef 

1.23 dsem 

Unit No.2 

One 

2} Volume of water vapor collected at standard conditions, Vw(std). 

Vw(sld) = K2 'Vic 

Vw(sld) = 6.684 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.134 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) [+ (1S'Bws) 

Ms= 28.83 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP) , (Ts/Ps'Ms)'.5 

Vs = 45.32 Ips 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min ~ Vs * As 

Qa = 226582.1 efm 

6416.8 emm 

7) Average stack gas dry volumetric fJowrate, Qstd. 

Qsld = Qa' (TsldfTs)' (Ps/Psld)' (1-Bws) 

Qstd = 160431.4 dscfm 

4543.4 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

8) Hydrogen Cyanide Concentration and Emissions 

Unit No.2 

One 

M[HCN[ = M[CN-[(mg) , MW[HCN](mglmmol) 1 MW[CN-](mglmmol) 

Page 3 

C[HCN] = (M[HCN](mg) , 2.205E-06(1blmg) • 21.85(scf'inHgllbmol'R) , K1 ' 10'6) 1 (MW[HCN](lbllbmol) 'Vmsl 

C[HCN](@corr. 02) = C[HCN](ppmV)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HCN] = M[HCN](mg)' Qstd(dscfm)' (2.205E-06)(lblmg)' 60(minlhr) 1 Vmstd(dscf) 

E[HCN] = C[HCN[(ppmV)' Fd' CF(HCN)' (20.91(20.9-%02)) 

< M[HCN] = 0.004 mg 

< C[HCN] = 0003 ppmV 

< C[HCN] = 0.002 ppmV (@ 7.0 % 02) 

< E[HCN] = o 002 Iblhr 

< E[HCN] = 2.48E-06 IblMMBtu 
3333-HCN-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

Dn = 

An = 

y= 

t= 

Ds = 

As= 

Cp= 

Kp= 

K1 = 

K2= 

K3 = 

Fd = 

CF = 

[02] 

[C02] 

]N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and Modified 26 

(Flows, 02/C02, H20,and HCN) 

Spruance Genco, LLC 

3333 

Unit No.2 

Two 

04/20/10 

1430-1530 

143.3 cc 

44.725 def 

Emission Data 

-OA5 in. H20 

29.99 in. Hg 

29.96 in. Hg 

29.92 in. Hg 

07348 in. H20 11.5 

1.820 in. H20 

5399 R 

6495 R 

527.7 R 

Din. 

0.000000 sq. ft. 

0.99 

60 min, 

10.300 ft 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle onfice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq. ft. Cross sectional area of stack 

0.84 Pltot tube coeffiCient 

85.49 ft[(lb/lbmol)*(inHg)]A.5}/[s*R*inH20] Pitot tube constant 

17.637 R/in.Hg constant 

0.047070 cu.ftlml constant 

0.0026688 in.Hg-cf/ml-R 

9676 scf/MMBtu 

7.014E-08 Ib/dsef 1 ppmVd 

Instrumental Data 

4.34 %-dry 

14.23 %-dry 

81 43 %-dry 

constant 

Fuel Factor 

Conversion Factor for HeN 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm ., (Pb + dH/13.6) I Tm 

Vmstd = 43.575 dscf 

1.23 dscm 

Unit No.2 

Two 

2) Volume of water vapor collected at standard conditions, Vw{std). 

Vw(std) = K2 'Vie 

Vw(std) = 6.745 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 0.134 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (1-Bws)] + (18'Bws) 

Ms= 28.78 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP) , (TsIPs'Ms)'.5 

Vs = 45.80 Ips 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs * As 

Qa = 228983.2 elm 

6484.8 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qsld = Qa' (TsldITs], (PsIPstd)' (1-Bws) 

Qstd = 161294.8 dscfm 

4567.9 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

8) Hydrogen Cyanide Concentration and Emissions 

Unit No, 2 

Two 

M[HCN[ = M[CN-](mg) , MW[HCN](mg/mmol) 1 MW[CN-](mg/mmol) 

Page 3 

C[HCN] = (M[HCN](mg)' 2.20SE-06(lb/mg)' 21.8S(scf'inHg/lbmol'R)' K1 '10"6) 1 (MW[HCN](lb/lbmol)' Vmsl 

C[HCN](@corr. 02) = C[HCN](ppmV)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HCN] = M[HCN](mg) , Qstd(dscfm) • (2.20SE-06)(lb/mg) • 60(min/hr) 1 Vmstd(dscf) 

E[HCN] = C[HCN](ppmV)' Fd' CF(HCN)' (20.9/(20.9-%02)) 

< M[HCN] = 0.005 mg 

< C[HCN] = 0.004 ppmV 

< C[HCN] = 0.003 ppmV (@ 70 %02) 

< E[HCN] = 0.002 Ib/hr 

< E[HCN] = 309E-06 Ib/MMBtu 
3333-HCN-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

T5 = 

Tstd= 

On = 

An = 

y= 

t = 

Os= 

As= 

Cp = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

CF= 

[02[ 

[C02[ 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and Modified 26 

(Flows, 02/C02, H20,and HCN) 

Spruance Genco, LLC 

3333 

Unit No.2 

Three 

04/21/10 

0655-1000 

Emission Data 

159,2 cc 

47.973 def 

-0,45 in. H20 

29.87 in. Hg 

29.84 in Hg 

29.92 in Hg 

0.7266 in. H20 A.S 

1.820 in. H20 

515.9 R 

647.2 R 

527.7 R 

Din. 

0.000000 sq. ft. 

0.99 

60 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)"(inHg)]".5}/[s*R"inH20] Pltot tube constant 

17.637 R/in.Hg 

0.047070 cu.fUml 

0.0026688 In.Hg-cf/ml-R 

9826 sef/MMBtu 

7.014E-08 Ib/dscf I ppmVd 

Instrumental Data 

4.95 %-dry 

13.86 %-dry 

81.19 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HeN 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1" Y .. Vm .. (Pb + dH/13.6) I Tm 

Vmstd = 48.719 dscf 

1.38 dscm 

Unit NO.2 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 'Vic 

Vw(std) = 7494 sct 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.133 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (l-Bws) I + (18'Bws) 

Ms = 28.76 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP) , (Ts/Ps'Msl' 5 

Vs = 45.32 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs * As 

Qa = 226554.2 efm 

6416.0 emm 

7) Average stack gas dry volumetric flowrate, Ostd. 

Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (l-Bws) 

Qstd = 159653.4 dscfm 

4521.4 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

8) Hydrogen Cyanide Concentration and Emissions 

Umt No.2 

Three 

M[HCN[ = M[CN-[(mg) " MW[HCN](mg/mmol) 1 MW[CN-](mg/mmol) 

Page 3 

C[HCN] = (M[HCN](mg) " 2 205E-06(lb/mg) " 21.85(scf"inHg/lbmol"R) " K1 " 10'6) 1 (MW[HCN](lb/lbmol) "Vmsl 

C[HCN](@corr 02) = C[HCN](ppmV)" [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HCN] = M[HCN](mg) " Qstd(dscfm) " (2.205E-06)(lb/mg) "60(min/hr) 1 Vmstd(dsc0 

E[HCN] = C[HCN](ppmV)" Fd" CF(HCN)' (20.9/(20.9-%02)) 

< M[HCN] = 

< C[HCN] = 

< C[HCN] = 

< E[HCN] = 

< E[HCN] = 

0.005 mg 

0.003 ppmV 

0.003 ppmV 

0.002 Ib/hr 

2 91 E-06 Ib/MMBtu 

(@ 7.0 % 02) 
3333-7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, llC 

3333 

Unit No.2 - Metallic HAPs 

04/22/10 

Parameter: 

Instrument Span f% 02): 

Oxygen 

21,96 

Actual Calibralion Gas Value f% 02t 

Analyzer Calibration Response (% 02): 

Analvzer Calibration Error(% Span): 

Zero S~tem Calibration Gas 

Apparent Init. Sys. Init. Sys. Final S\,:§. Final Sys. 

Stack Calib. C{Ji. Bias Calib. Cal. Bias 

Run Conc. Response f% span) Response (% span) 

1 4.86 0.02 0.09 0.01 0.05 

2 4.43 0.01 0.05 0.03 0.14 

0 0.00 0.03 0.14 0.00 0.00 

0 0.00 0.00 0.00 0.00 0.00 

0 0.00 0.00 0.00 0.00 0.00 

0 0,00 0.00 0.00 0.00 0.00 

0 0.00 0.00 0.00 0.00 0.00 

0 0.00 0.00 0.00 0.00 0.00 

0 0.00 0.00 0.00 0.00 0.00 

0 0.00 0.00 0.00 0.00 0.00 

0 0.00 0.00 0.00 0.00 0.00 

0 0.00 0.00 000 000 0.00 

AirNova, Inc. 

EPA Method 7E Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

zero 

0.00 

0.00 

0.00 

AnalYZer Calib. Gases 

~ mid 

N/A 12.46 

N/A 12.33 

0.00 -0.59 

high 

21.96 

21.74 

-1,00 

Ugscale S~stem Calibration Gas 

Calib. Init. Sys. Init. Sys. Final Sys. Final Sys. 

Drift Calib. Cal. Bias Calib. Cal. Big§. 

(% span) Response (% spanl Response (% span) 

-D.05 12.34 0.05 12.37 0.18 

0.09 12.37 0.18 12.34 0.05 

-0.14 12.34 0.05 0.00 -56.15 

0.00 0.00 -56.15 0.00 -56.15 

0.00 0.00 -56.15 0.00 -56.15 

0.00 0.00 -56.15 0.00 -56.15 

000 0.00 -56.15 0.00 -56.15 

0.00 0.00 -56.15 0.00 -56.15 

0.00 0.00 -56.15 0.00 -56.15 

0.00 0.00 -56.15 0.00 -56.15 

0.00 0.00 -56.15 0,00 -56.15 

0.00 0.00 -56.15 0.00 -56.15 

Upscale 

Svs. Cal. Gas 

1246 

12.33 

Calib. 

DnJt 

f% span) 

0.14 

-0.14 

-56.19 

0.00 

000 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

Page 1 

Actual 

Steck 

Conc. 

4.89 

4.45 

-0.03 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 
3333-7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit No_ 2 - Metallic HAPs 

04/22110 

Parameter: Carbon Dioxide 

Instrument Span (% G02!: 17.83 

Actual Calibration Gas Value (% C02L 

Analvzer Calibration Response (% G02): 

Analyzer Calibration Error(% Span!: 

Zero Sllstem Calibration Gas 

Apr1.arent Init. S\"s_ Init. S\"S. Fingl S!!s. Final S\::s_ 

Stack Galib. Cgf. BigS Calib. Cal. Bias 

Run Gonc. Response (% span) Response (% span) 

1 13.92 0.06 0.84 0.21 1.68 

2 14.19 0.21 1.68 -0.01 0.45 

0 0.00 -0.01 0.45 0.00 0.50 

0 0.00 0.00 0.50 0.00 0_50 

0 0.00 000 0.50 0.00 050 

0 0.00 0.00 0.50 0.00 050 

0 0.00 0.00 0.50 0.00 0.50 

0 0.00 0.00 0.50 0.00 0.50 

0 0.00 0.00 0.50 0_00 0.50 

0 0.00 0.00 0,50 0_00 0.50 

0 0.00 0.00 0.50 0.00 0.50 

0 0.00 0.00 0.50 0.00 0.50 

AirNova, Inc. Page 2 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal\::zer Calib. G§:ses W2~cale 

zero !ill!i mid high S\::s. Cal. Gg~ 

0.00 NfA 12.39 17.83 12.39 

-009 NfA 12.26 17.74 12.26 

-0.50 0.00 -0.73 -0 50 

U~scale Sy:stem Calibration Gas 

Calib. fnit S\::s. Init. Svs. Final Sys. Final S\::s. Cafib. Actual 

Drift Galib. Cal. Bias Calib. Gg/. Bias Drift !ltil2; 

(% span! Response (% span) Response (% span) (% span) Conc_ 

0.84 12.29 0.17 12.32 0_34 0.17 14.03 

-1.23 12.32 0.34 12,32 0.34 0.00 14.29 

0.06 12.32 0.34 0.00 -68.76 -69.10 0.01 

000 0.00 --68,76 0.00 -68.76 0.00 ERR 

0_00 0.00 -68.76 0.00 -68.76 0_00 ERR 

0_00 0.00 -68.76 0.00 -68,76 0_00 ERR 

0.00 0.00 -68.76 0.00 -6876 0.00 ERR 

0.00 0.00 -68.76 0.00 -68_76 0.00 ERR 

0.00 0.00 -68.76 000 -68.76 0.00 ERR 

0.00 0_00 -68.76 0.00 -68.76 0.00 ERR 

0.00 0_00 -68.76 0.00 -68.76 0.00 ERR 

0.00 0.00 -68,76 0.00 -68.76 0.00 ERR 
3333-7E-R3 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit No.2 - Metallic HAPs 

04/23/10 

Parameter: Oxygen 

Instrument Soan (% 02): 21.96 

Actugl Calibration Gas Value (% 02): 

Analyzer Calibration Resflonse (% 02): 

Analyzer CalibratIon Error (% Span): 

Zero S~stem Calibration Gas 

Aflgarent Init. Sys. Init. Sys. Final S~s. Final Sys. 

stack Ca/lb. Qa/. Bias Galib. Cal. Bias 

Run Cone. Response r% sgan) Resflonse t% sflan) 

3 4.95 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0,00 0.00 -0.05 000 -0.05 

0 0.00 0,00 -0.05 0.00 -0.05 

0 0.00 0.00 -0,05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -005 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0,00 0.00 -0.05 0.00 -0,05 

0 0,00 0.00 -0.05 0.00 -0.05 

AirNova, Inc. Page 1 

EPA Method 7E Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal~zer Calib. Ga~§:s Ufl~~g/e 

zero low mid high ,svs. Cal. Gas 

0.00 NfA 12.46 21,96 12.46 

0.01 NfA 12.38 21.62 12.38 

0.05 0.00 -0.36 -1.55 

Ugscale Sllstem Calibration Gas 

Cg/ib. Init. Sys. Init. Sys. Final Sys. FinaIS~. Calib. Actual 

Drift Galib. Cal. Bif!.S Galib. Gal. Bia~ Drift Stack 

t% S!)gn) Resflonse f% sQf!.n) Resgonse (% span) r% span) Gonc. 

000 12.38 0.00 12.45 0.32 032 4.97 

000 12.45 0.32 0.00 -56.38 -56.69 0.00 

0.00 0.00 -56.38 0.00 -5638 0.00 ERR 

0.00 0.00 -56.38 0.00 -56.38 0.00 ERR 

0.00 0.00 -56.38 0.00 -56,38 0.00 ERR 

0.00 0.00 -56.38 000 -56.38 0.00 ERR 

0.00 000 -56.38 0.00 -56.38 0.00 ERR 

000 0.00 -56.38 0.00 -56.38 0.00 ERR 

0.00 0.00 -56.38 0.00 -56.38 0.00 ERR 

0.00 0.00 -56.38 0.00 -56.38 0.00 ERR 

0.00 0.00 -56.38 0.00 -56.38 000 ERR 

0.00 0.00 -56.38 0.00 -56.38 0.00 ERR 
3333-7E-R3 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit No.2 - Metallic HAPs 

04/23/10 

Parameter: 

Instrument Soan (% C02): 

Carbon Dioxide 

17.83 

Actual Calibration Gas Value (% C02): 

Ana/,,-zer Calibration Responsft. t% C02): 

AnafyzerCaJibration Error (% Span): 

ZerQ S~tem Calibration Gas 

AQQarent Init. S~. Init. Sys. Final S):::s. FinaIS~. 

Stack ~ Gal. Bias Gallb. Gal Bias 

Run Cone. ResQonse (% span) ResQonse (% span) 

3 13.78 0.03 -006 0.10 0.34 

0 0.00 0.10 0.34 0.00 -0.22 

0 0.00 0.00 -022 0.00 -0.22 

0 0.00 0.00 -0.22 0.00 -0.22 

0 0.00 0.00 -0.22 0.00 -0.22 

0 0.00 0.00 -0.22 0.00 -0.22 

0 0.00 0.00 -0.22 0.00 -0.22 

0 0.00 0.00 -0.22 0.00 -0.22 

0 0.00 0.00 -0.22 0.00 -0.22 

0 0.00 0.00 -0.22 0.00 -0.22 

0 0.00 0.00 -022 0.00 -0.22 

0 0.00 0.00 -0.22 0.00 -0.22 

AirNova, Inc. Page 2 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal,,-zer CaNb. Gases Uusealft. 

zero low mid high S,,-s. Cal. Gas 

0.00 N/A 7.49 1783 7.49 

0.04 N/A 7.52 17.83 7.52 

0.22 0.00 0.17 0.00 

!.!gscale Sxstem Calibration Gas 

CaNb. lnit ~):::s. Init. S):::s. Final S):::s. Final S):::s. Calib. Actual 

Drift Calib. Gal. Bias ~ Cal. Bias Drift Slack 

(% span) ResQonse (% spgn) Response f% span) (% soan) Cone. 

0.39 7.52 0.00 7.61 050 0.50 13.70 

-0.56 7.61 0.50 0.00 -42.18 -42.68 -0.10 

0.00 0.00 -4218 0.00 -42.18 000 ERR 

0.00 0.00 -42.18 000 -42.18 0.00 ERR 

0.00 0.00 -42.18 0.00 -42.18 0.00 ERR 

0.00 0.00 -42.18 0.00 -42.18 0.00 ERR 

0.00 0.00 -42.18 0.00 -42.18 0.00 ERR 

0.00 0.00 -42.18 0.00 -42.18 0.00 ERR 

0.00 0.00 -42.18 0.00 -42.18 0.00 ERR 

0.00 0.00 -42.18 0.00 -4218 0.00 ERR 

0.00 0.00 -42.18 0.00 -42.18 000 ERR 

0.00 0.00 -42.18 0.00 -42.18 0.00 ERR 
3333-PM2.5-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb ~ 

Ps = 

Pstd = 

dP ~ 

dH ~ 

Tm= 

Ts = 

Tstd= 

Dn = 

An = 

y~ 

tr = 

Os= 

As= 

Cp~ 

Kp ~ 

K1 ~ 

K2~ 

K3= 

C1 = 

C2 = 

C3 ~ 

C4= 

C5= 

C6= 

81 = 

Fd = 

[02J 

[C02J 

[N2J 

AirNova, Inc. 

EPA Methods 1,2,3,4, OTM 27 and 202 

(Flows, 02/C02, H20, PM2.S and CPM) 

Spruance Genco, LLC 

3333 

Unit No.2 

One 

04122110 

0647·1318 

Emission Data 

406.3 cc Vol. of H20 collected 

134.716 dcf Dry gas meter reading 

-0.45 in. H20 Static pressure 

29 81 in Hg Barometric pressure 

2978 in. Hg Stack pressure 

29.92 in. Hg EPA Standard pressure 

0.7715 in. H20 ".5 Average sq.rt delta P 

0.390 in. H20 Average draft gauge reading 

523.9 R Average meter temperature 

6492 R Average stack temperature 

5277 R Standard temperature 

0.180 in. Nozzle diameter 

0000177 sq. ft. Area of nozzle orifice 

0.99 Meter calibration factor, gamma 

382 min. Duration of sampling time 

10.300 ft. Diameter of stack 

83.32 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmolninHg)J'.5)/[s'R'inH20J Pilot tube constant 

17.637 R/in.Hg constant 

0.047070 cu.ftlml constant 

0.0026688 in.Hg·cf/ml·R constant 

-150.3162 upoise Viscosity constant 

13.4622 upoise/R"0.5 Viscosity constant 

3861530 upoise/R"2 Viscosity constant 

0.591123 upoise Viscosity constant 

91.9723 upoise Viscosity constant 

1.51761 E-05 upoise/R"2 Viscosity constant 

0.15625 Constant 

9828 dscflMMBtu Fuel Factor 

Instrumental Data 

4.89 %-dry 

14.03 %·dry 

81.08 %-dry 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

Unit No.2 

One 

1) Dry Gas Volume at standard conditions, Vms (EPA aTM 27 Equation 27). 

Vms =K1' Y' Vm' (Pb + dHI13.6) I Tm 

Vms = 133.980 dscf 

3.794 dscm 

2) Dry gas sampling rate at standard conditions, OsST (EPA aTM 27 Equation 28). 

OsST = Vms I tr 

QsST= 0.351 dscfm 

0.010 dsem I min. 

3) Volume of water vapor condensed at standard conditions, Vws (EPA aTM 27 Equation 29). 

Vws = K2 *Vle 

Vws= 19124 sef 

4) Decimal fraction of moisture by volume in stack gas, Bws (EPA aTM 27 Equation 30). 

Bws = Vwstd I (Vmstd+Vwstd) 

BW5 = 0.125 

5) Mo/ecular weight of the stack gas on a wet basis, Mw (EPA aTM 27 Equations 1 &2). 

Mw = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) I + (1S'Bws) 

Mw = 28.89 Ib/lbmole 

6) Gas sampling rate at actual Cyclone conditions, Os (EPA aTM 27 Equation 31). 

Qs = (PsldlTsldrQsST' (1/(1-Bws))'(Ts/Ps) 

Os = 0 495 8efm 

7) Average stack gas velocity, Vs (EPA aTM 27 Equation 11). 

Vs = Kp' Cp' (ave of (dPyO.5)' (Ts/Ps'Mw)'O.5 

Vs = 48.13 fps 

8) Average actual stack gas volumetnc f/owrate, Oa. 

Oa = 60 sec/min" Vs * As 

Oa = 240633.6 efm 

6814.7 cmm 

9) Average stack gas dry standard volumetric f/owrate, Qstd 

Qsld = Qa' (TsldlTs)' (Ps/Psld)' (1-Bws) 

Ostd = 170347.2 dscfm 

48242 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No 2 

One 

Page 3 

10) Analytical data 

Cvclone and Filter Fractions (EPA Method orM 27); 

M1) Instack quartz microfibre filter, <2.5um 

0.0054 9 PM <2.5 filter net wt 

M2-4) Cyclone acetone washes 

o 0000 9 actual mass of >2.5, Containers 2&3 

0.0006 9 actual mass of <1=2.5um, Container 4 

0.0000 9 acetone blan k net wt 

o mL volume 

100 mL volume 

100 mL volume 

0.0000 9 blank corrected mass of >2.5um, Containers 2&3 = M2&M3 

0.0006 9 blank corrected mass of </=2.5um, Contamer 4 = M4 

Condensible Particulate Matter (CPM) Fractions (EPA Method 202): 

M5) Back Half Aqueous Wash 

0.0076 9 actual sample mass 

0.0003 9 aqueous blank mass 

300 ml blank vol. 

300 ml Sample volume 

0.0073 9 condensible aqueous PM 

M6) Back Half MeCI2 Extraction Portion 

0.0014 9 extraction netwt 

0.0000 9 MeCI2 blank net wt 

300 ml blank vol. 

300 ml MeCI2 extraction volume 

00014 9 condensible organic PM 

M[CPM] = blank corrected mass of Total CPM, M5 & M6 (in grams) 

M[CPM] = 0.0087 9 CPM 

11) Particulate Concentrations, C (EPA OTM27 and EPA 202). 

Equation 43 

Equation 45 

EPA 202 

C[totalsus] = M 1 (g)+M2(g)+M3(g)+M4(g)·15.43(grainslg)Nmstd(dscn= 

C[PM2.5sus] = M1 (g) + M4(g) • 15.43(grainslg) 1 Vmstd(dscn = 

C[CPM] = M[CPM](g) • 15.43(grainslg) 1 Vmstd(dscf) 

where 15.43 = 7000/453592'1000 

C[PMtotal] = C[PMtotalsus] + C[CPM] 

C[PM2.5total] = C[PM2.5sus] + C[CPM] 

0.0007 gr/dscf PMsus 

0.0007 gr/dscf PM2.5sus 

0.0010 gr/dscf CPM 

0.0017 gr/dscf Total PM 

0.0017 gr/dscfTotal PM2.5 
Client 

Project No. 

Spruance Genco, LLC 

3333 

12) Particulate Emission Rates, E. 

Test Location 

Test Run 

Calculations (cont,) 

Unit No.2 

One 

E[lb/hr[ = C[](gr/dscf) • (1 Ib/7000 gr) • Qstd(dscfm) • 60(min/hr) 

E[lb/MMBtu] = C[](gr/dsc0 • (1.lb/7000 gr) • Fd(dscf/MMBtu) • (20.9/20.9-%02) 

E[totalsus] = 1.01 Ib/hr total sus PM 

E[totalsus] = 0.0013 IbJMMBtu total sus PM 

E[PM2.5sus] = 1.01 Ib/hr PM2.5sus = 40.8 % of Total PM2.5 

E[PM2.5sus] = 0.0013 IbJMMBtu PM2.5sus = 

E[CPM] = 1.46 Ib/hr CPM 59.2 % of Total PM2.5 

E[CPM] = 0.0018 Ib/MMBtu CPM 

E[PMtotal] = 2.47 Ib/hr total PM 

E[PMtotal[ = 0.0031 Ib/MMBtu total PM 

E[PM2.5total] = 2.47 Ib/hr total PM2.5 

E[PM2 5total] = 0.0031 Ib/MMBtu total PM2.5 

13) Percent Isokinectic Sampling, %1 (EPA OTM 27 Equation 40). 

% I = [100*Ts*Vms*Pstd) I (60*Vs*tr*An*Ps"(1-Bws)*Tstd) 

% I = 97.08 

14) Stack Gas Viscosity, u (EPA OTM 27 Equation 3). 

u = C1 + C2*(TsI\0.5) + C3*(Ts"-2) + C4*(%02) - (C5*Bws) + C6*Bws*(TsIl2) 

u = 194.1 micropoise 

Page 4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

1S) Test Condition Reynolds number, Nre (EPA OTM 27 Equation 8). 

Nre = 8.64"10A S"(Ps"Mwrrs)"'(Qs/u) 

Nre = 2923 

Unit No, 2 

One 

16) Actual Particle Cut ~iameter for Cyclone 1.050 (EPA OTM 27 Equation 32). 

OSO = 81 • ([ Ts 1 (Mw" Ps)['2091)" ((u 1 05)'.7091) 

050 = 10.16 um 

17) Actual Cunningham Correction Factor based on Op = 2.5um. C (EPA OTM 27 Equation 4), 

C = 1+ 0.00S7193" (u/(Ps"Op))" (Ts/Mw)·O.S 

C = 1.0707 

18) Initial OSO for Cyclone IV based on test condition Reynolds number from OTM 27 Equation 8. 

If Nre < 3162, use Equation 33 which results in 050 for IV = 

If Nre >= 3162, use Equation 34 which results in D50 for IV = 

Initial D50 

2.21 

2.1S 

Equation 33 

Equation 34 

Equation 35 

OSO = 0.0024302"(u/Os)Al.1791"(1/C)AO.5"(Ts/(PS"Mw))AO.6790 

OSO = 0 019723"(u/0s)"0.80S8·(1/C)·0.5"(Ts/(Ps·Mw)),0.30S8 

Cr = 1 + 0.0057193"(u/(Ps"050))"(Ts/Mw)AO.S 

19) Re-estab/ished OSO forCyc/one IV, 050-1. 

Page 5 

Re-established 

Cunningham, Cr 

1.0798 

1.0822 

If Nre < 3162, use Equation 36 which results In 050 for IV = 

If Nre >= 3162, use Equation 37 which results in D50 for IV = 

Recalculated Cut Diam. 050-1 

2.20 

2.14 

Equation 36 

Equation 37 

OSO-1 = 0.0024302"(u/Os),1.1791"(lICr),0.S"(Ts/(Ps·Mw)),0.6790 

OSO-1 = 0.019723"(u/Os)·0.8058"(lICr)·0.S"(Ts/(Ps"Mw))AO.30S8 

19) Establishmg "Z" value, Z. 

If Equation 36 was used, then 

If Equation 37 was used, then 

Z= OSO-11 OSO= 

Z = OSO-1 1 OSO = 

If 0.99 < Z < 1.01, then 050-1 is best cut diameter estimate, 

If 0.99 > Z > 1.01, then repeat calcs for Cr using 050-1 

1.00 

0.99 
3333-PM2 5-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

tr = 

Ds= 

As= 

Cp = 

Kp= 

K1 = 

K2= 

K3= 

C1= 

C2 = 

C3= 

C4= 

C5= 

C6 = 

81 = 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3,4, OTM 27 and 202 

[Flows, 021C02, H20, PM2.S and CPM) 

Spruance Genco, LLC 

3333 

Unit No_ 2 

Two 

04122110 

1335-1943 

Emission Data 

387.9 cc Vol. of H20 collected 

129,724 dcf Dry gas meter reading 

-0.45 in. H20 Static pressure 

29,81 in. Hg Barometric pressure 

29,78 in. Hg Stack pressure 

29.92 m. Hg EPA Standard pressure 

0,7130 m. H20"5 Averagesq.rtdelta P 

0.390 In. H20 Average draft gauge reading 

537.7 R Average meter temperature 

650.5 R Average stack temperature 

527.7 R Standard temperature 

0.180 in. Nozzle diameter 

0,000177 sq, ft Area of nozzle onfice 

0.99 Meter calibration factor, gamma 

359.2 min. Duration of sampling time 

10.300 ft. Diameter of stack 

83.32 sq ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbllbmol)"(inHg)j'.5)I[s·R·inH20] Pitot tube constant 

17.637 R/in.Hg constant 

0.047070 cu.ftlml constant 

0.0026688 in.Hg-cf/ml-R 

-150.3162 upoise 

13.4622 upoise/RflO.5 

3861530 upoise/Rfl2 

0.591123 upoise 

91.9723 upoise 

1.51761 E-05 upoise/Rfl2 

0.15625 

9676 dscf/MMBtu 

Instrumental Data 

4.45 %-dry 

14.29 %-dry 

81.26 %-dry 

constant 

Viscosity constant 

Viscosity constant 

Viscosity constant 

Viscosity constant 

Viscosity constant 

Viscosity constant 

Constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

Unit No.2 

Two 

1) Dry Gas Volume at standard conditions, Vms (EPA aTM 27 Equation 27). 

Vms =K1' Y' Vm ' (Pb + dH/13.6) I Tm 

Vms = 125.696 dscf 

3.560 dscm 

2) Dry gas sampling rate at standard conditions, OsST (EPA aTM 27 Equation 28). 

QsST = Vms I tr 

QsST= 0.350 dsefm 

0.010 dsem I min. 

3) Volume of water vapor condensed at standard conditions, Vws (EPA OTM 27 Equation 29). 

Vws = K2 *Vle 

Vws= 18.258 sef 

4) Decimal fraction of moisture by volume in stack gas, Bws (EPA aTM 27 Equation 30). 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.127 

5) Molecular weight of the stack gas on a wet basis, Mw (EPA OTM 27 Equations 1 &2). 

Mw = [ ((44'%C02) + (32'%02) + (28'%N2)) , (1-Bws) I + (18'Bws) 

Mw = 28.88 Ib/lbmole 

6) Gas sampling rate at actual Cyclone conditions, Os (EPA OTM 27 Equation 31). 

Qs = (PstdlTstd),QsST' (1/(1-Bws))'(Ts/Ps) 

as = 0.496 acfm 

7) Average stack gas velocity, Vs (EPA OTM 27 Equation 11). 

Vs = Kp' Cp' (ave 01 (dP)'0.5)' (Ts/Ps'Mw)'0.5 

Vs = 44.53 fps 

8) Average actual stack gas vo/umetflc f/owrate, Qa 

·Qa = 60 sec/min * Vs * As 

Qa = 222605 9 elm 

6304.2 cmm 

9) Average stack gas dry standard volumetric f/owrate, Qstd. 

Qstd = Qa • (TstdlTs) , (Ps/Pstd) , (1-Bws) 

Qstd = 156916.5 dscfm 

4443.9 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.2 

Two 

Page 3 

10) Analytical data 

Cvclone and Filter Fractions (EPA Method OTM 27). 

M1) Instack quartz microfibre filter, <2.Sum 

0.0213 9 PM <2,S filter net wi 

M2-4) Cyclone acetone washes 

0_0000 9 actual mass of >2 5, Containers 2&3 

0.0014 9 actual mass of <1=2.5um, Container 4 

0.0000 9 acetone blank net wt 

o mL volume 

100 mL volume 

100 mL volume 

0.0000 9 blank corrected mass of >2 5um, Containers 2&3 = M2&M3 

0.0014 9 blank corrected mass of <1=2.Sum, Con tamer 4 = M4 

Condensible Particulate Matter (CPMJ Fractions (EPA Method 202): 

MS) Back Half Aqueous Wash 

0.0136 9 actual sample mass 

0.0003 9 aqueous blank mass 

300 ml blank vol. 

300 ml Sample volume 

0,0133 g condensible aqueous PM 

M6) Back Half MeCI2 Extraction Portion 

0.0015 9 extraction netwt 

0.0000 g MeCI2 blank net wt 

300 ml blank vol 

300 ml MeCI2 extraction volume 

0.0015 9 condensible organic PM 

M[CPMJ = blank corrected mass of Total CPM, M5 & M6 (in grams) 

M[CPM[ = 0.0148 9 CPM 

11) Parilculate Concentrations, C (EPA OTM27 and EPA 202). 

Equation 43 

Equation 45 

EPA 202 

C[totalsus] = M1 (g)+M2(g)+M3(g)+M4(g)'1543(grainslg)Nmstd(dscD= 

C[PM2.5sus] = M1(g) + M4(g) • 1543(grainslg) I Vmstd(dscD = 

C[CPM] = M[CPM](g) • 1543(grainslg) I Vmstd(dscf) 

where 15.43 = 70001453592*1000 

C[PMtotal] = C[PMtotalsus] + C[CPM] 

C[PM2.5total] = C[PM2.5sus] + C[CPM] 

0.0028 gr/dscf PMsus 

0,0028 gr/dscf PM2,5sus 

0.0018 gr/dscfCPM 

0,0046 gr/dscfTotal PM 

0.0046 grJdscfTotal PM2.5 
Client 

Project No. 

Spruance Genco, LLC 

3333 

12) Particulate Emission Rates, E. 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.2 

Two 

E[lblhr[ = C[[(grldscD' (11b17000 gr)' Qstd(dscfm)' 60(minlhr) 

E[lbIMMBtu] = C[](grldscD • (1 Ibl7000 gr) • Fd(dscfIMMBtu) • (20.9120.9-%02) 

E[totalsus1 = 3.7S Ib/hr total sus PM 

E[totalsusj = 0.0049 IbfMMBtu total sus PM 

E[PM2.Ssus1 = 3.7S Ib/hr PM2.Ssus = 60.S % of Total PM2 S 

E[PM2.Ssus] = 0.0049 Ib/MMBtu PM2.Ssus = 

E[CPM] = 2.44 Iblhr CPM 39.S % of Total PM2 S 

E[CPM] = 0.0032 Ib/MMBtu CPM 

E[PMtotal] = 6.19 Ib/hr total PM 

E[PMtotal] = 0.0081 IbfMMBtu total PM 

E[PM2 Stotal[ = 6.19 Ib/hr total PM2.S 

E[PM2.Stotal] = 0.0081 IblMMBtu total PM2.S 

13) Percent Isokinectic Sampling, %1 (EPA OTM 27 Equation 40). 

% I = [100"'Ts*Vms"'Pstd) f (60"'Vs*tr*An*Ps~(1-Bws)*Tstd) 

%1= 10S.15 

14) Stack Gas Viscosity, u (EPA OTM 27 Equation 3). 

u = C1 + C2*(TsII.0.S) + C3*(TslI.-2) + C4"(%02) - (CS*Bws) + CS"Bws*{TsIl2) 

u = 193.9 micropoise 

Page 4 
Client 

Project No. 

Spruance Genco. LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

15) Test Condition Reynolds number, Nre (EPA OTM 27 Equation 8). 

Nre = 8.64*101\5*(Ps*Mw/Ts)*(Qs/u) 

Nre = 2924 

Unit NO.2 

Two 

16) Actual Particle Cut Diameter for Cyclone I, 050 (EPA OTM 27 Equation 32). 

050 = 61 ' ( [ Ts 1 ( Mw' Ps)['.2091) • ( (u 1 OsY.7091) 

050 = 10.15 um 

17) Actual Cunningham Correction Factor based on Dp = 2.5um, C (EPA OTM 27 Equation 4) 

C = 1+ 0.0057193' (u/(Ps'Op))' (Ts/Mw)'O 5 

C = 1.0707 

18) Initial 050 for Cyclone IV based on test condition Reynolds number from OTM 27 Equation 8. 

If Nre < 3162. use Equation 33 Which results in 050 for IV = 

If Nre >= 3162, use Equation 34 which results in 050 for IV = 

Initial 050 

2.21 

215 

Equation 33 

Equation 34 

Equation 35 

050 = 0.0024302'(u/OsY1.1791·(1IC)'OS(Ts/(Ps'Mw)),0.6790 

050 = O. 019723'(u/Os)'0.8058'( lIC)'OS(Ts/(Ps'Mw)),0.3058 

Cr = 1 + 00057193'(u/(Ps'050)),(Ts/MwYO.5 

19) Re-established 050 for Cyclone IV, 050-1. 

Page 5 

Re-established 

Cunningham. Cr 

1.0800 

1.0824 

If Nre < 3162, use Equation 36 which results in 050 for IV = 

If Nre >= 3162, use Equation 37 which results in 050 for iV = 

Recalculated Cut Oiam, 050-1 

2.20 

2.13 

Equation 36 

Equation 37 

050-1 = 0.0024302'(u/Os)'1.1791'(lICr)'OS(Ts/(Ps·Mw))'0.6790 

050-1 = 0.019723·(u/OsYO.8058'(1/Cr)'0.5'(Ts/(Ps'Mw)),0 3058 

19) Establishing "Z" value, Z. 

If Equation 36 was used, then Z = 050-11 OSO = 

If Equation 37 was used, then Z = 050-11 OSO = 

If 0.99 < Z < 1.01. then 050-1 is best cut diameter estimate. 

If 0,99 > Z > 1.01, then repeat cales for Cr using 050-1 

1.00 

0.99 
3333-PM2.5-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

Dn= 

An = 

y= 

tr = 

Os = 

As= 

Cp= 

Kp= 

K1 = 

K2= 

K3= 

C1= 

C2 = 

C3 = 

C4= 

C5 = 

C6 = 

81 = 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3,4, OTM 27 and 202 

(Flows, 02/C02, H20, PM2.5 and CPM) 

Spruance Genco, LLC 

3333 

Unit No.2 

Three 

04/23/10 

0600-1210 

377.7 cc 

Emission Data 

131.008 def 

~O.45 in. H20 

29.90 in. Hg 

29.87 in. Hg 

29.92 In. Hg 

0.7352 in. H20 '\5 

0.390 in. H20 

528.1 R 

650.8 R 

5277 R 

0.180 in. 

0.000177 sq ft. 

0.99 

370.7 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor, gamma 

Duration of sampling time 

Diameter of stack 

83.32 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmolr(inHg)]'.5}/[s·WinH20] Pitot tube constant 

17.637 R/in.Hg constant 

0.047070 cU.fVml constant 

0.0026688 in.Hg-cf/ml-R constant 

-150.3162 upoise Viscosity constant 

13.4622 upoise/R"0.5 Viscosity constant 

3861530 upoise/R"2 Viscosity constant 

0.591123 upoise Viscosity constant 

91.9723 upoise Viscosity constant 

1.51761E-05 upoise/R"2 Viscosity constant 

0.15625 Constant 

9826 dscf/MMBtu Fuel Factor 

Instrumental Data 

4.97 %-dry 

1370 %-dry 

81.33 %-dry 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

Unit No.2 

Three 

1) Dry Gas Volume at standard conditions, Vms (EPA orM 27 Equation 27). 

Vms =K1* Y * Vm * (Pb + dH/13.6) I Tm 

Vms = 129.633 dscf 

3,671 dscm 

2) Dry gas sampling rate at standard conditions, QsST (EPA OTM 27 Equation 28). 

OsST = Vms I tr 

QsST= 0.350 dscfm 

0.010 dscm I min. 

3) Volume of water vapor condensed at standard conditions. Vws (EPA OTM 27 Equation 29). 

Vws = K2 * Vic 

Vws= 17.778 scf 

4) Decimal fraction of moisture by volume in stack gas, Bws (EPA OrM 27 Equation 30). 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.121 

5) Molecular weight of the stack gas on a wet basis, Mw (EPA OTM 27 Equations 1 &2). 

Mw = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) [+ (1S'Bws) 

Mw = 28.90 Ib/lbmole 

6) Gas sampling rate at actual Cycfone conditions, Os (EPA OTM 27 Equation 31). 

Qs = (PstdlTstd),QsST ' (1/(1-Bws))'(TsJPs) 

Os = 0.491 acfm 

7) Average stack gas velocity, Vs (EPA OrM 27 Equation 11). 

Vs = Kp' Cp' (ave of (dPI'O.5)' (Ts/Ps'Mw)AO.5 

Vs = 45,85 fps 

8) Average actual stack gas volumetnc f/owrate, Oa. 

Oa = 60 sec/min * Vs * As 

Oa = 229194.6 cfm 

6490.8 cmm 

9) Average stack gas dry standard volumetric f/owrate, Qstd. 

Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

Ostd = 163143,1 dscfm 

4620.2 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.2 

Three 

Page 3 

10) Analytical data 

evclone and Filter Fractions (EPA Method OTM 27): 

M1) Instack quartz microfibre filter, <2.5um 

0.0172 9 PM <25filternetwt 

M2-4) Cyclone acetone washes 

0.0000 9 actual mass of >2.5, Containers 2&3 

0.0003 9 actual mass of <1=2.5um, Container 4 

0.0000 9 acetone blank net wt 

o mL volume 

100 mL volume 

100 mL volume 

0.0000 9 blank corrected mass of >2.5um, Containers 2&3 = M2&M3 

0.0003 9 blank corrected mass of <1=2.5um, Container 4 = M4 

Condensible Pariiculate Matter (CPMJ Fractions (EPA Method 202): 

M5) Back Half Aqueous Wash 

0.0047 9 actual sample mass 

0.0003 9 aqueous blank mass 

300 ml blank vol. 

300 ml Sample volume 

0.0044 9 condensible aqueous PM 

M6) Back Half MeCI2 Extraction Portion 

0.0009 g extraction net wt 

0.0000 9 MeCI2 blank net wt 

300 ml blank vol. 

300 ml MeCI2 extraction volume 

0.0009 9 condensible organic PM 

M[CPMl = blank corrected mass of Total CPM, M5 & M6 (10 grams) 

M[CPM] = 0.0053 9 CPM 

11) Pariiculate Concentrations, C (EPA OTM27 and EPA 202). 

Equation 43 

Equation 45 

EPA 202 

C[totalsus] = M 1 (g)+M2(g)+M3(g)+M4(g),15.43(grains/g)Nmstd(dsc0= 

C[PM2.5sus] = M1(g) + M4(g) '15 43(grains/g) 1 Vmstd(dsc0 = 

C[CPM] = M[CPM](g)' 15.43(grains/g) 1 Vmstd(dsc0 

where 15.43 = 7000/453592"'1000 

C[PMtotal] = C[PMtotalsus] + C[CPM] 

C[PM2.5total] = C[PM2.5sus] + C[CPM] 

00021 gr/dscf PMsus 

00021 gr/dscf PM2.5sus 

0.0006 gr/dscf CPM 

0.0027 gr/dscfTotal PM 

0.0027 gr/dscfTotal PM2.5 
Client 

Project No. 

Spruance Genco, LLC 

3333 

12) Particulate Emission Rates, E. 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.2 

Three 

E[lb/hr] = C[](gr/dscf)' (1 Ib/7000 gr)' Qstd(dscfm)' 60(min/hr) 

E[lb/MMBtu] = C[](gr/dscD • (1 Ib/7000 gr) • Fd(dscf/MMBtu) • (20.9120.9-%02) 

E[totalsus] = 2.91 Ib/hr total sus PM 

E[totalsus] = 0.0038 Ib/MMBtu total sus PM 

E[PM2.5sus] = 2.91 Ib/hr PM2.5sus = 76.8 % of Total PM2.5 

E[PM2 5sus] = 0.0038 Ib/MMBtu PM2.5sus = 

E[CPM] = 0.88 Ib/hr CPM 23.2 % of Total PM2.5 

E[CPM] = 0.0012 Ib/MMBtu CPM 

E[PMtotal] = 3.79 Ib/hr total PM 

E[PMtotal] = 0.0050 Ib/MMBtu total PM 

E[PM25total] = 3.79 Ib/hr total PM2.5 

E[PM2 5total] = 0.0050 Ib/MMBtu total PM2.5 

13) Percent Isokinectic Samplmg, %1 (EPA OTM 27 Equation 40). 

% I = [100*Ts*Vms*Pstd) / (60"'Vs*tr*An"Ps*(1~Bws)*Tstd) 

%1= 101.07 

14) Stack Gas ViscoSity, u (EPA OTM 27 Equation 3). 

u = C1 + C2*(Ts"0.5) + C3"(TslI~2) + C4*(%02) ~ (C5*8ws) + C6*Bws*(TsIl2) 

u = 194 8 micropoise 

Page 4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

15) Test Condition Reynolds number, Nre (EPA OTM 27 Equation 8). 

Nre = 8.64'10'S'(Ps'MwlTs),(Qslu) 

Nre = 2889 

Unit NO.2 

Three 

16) Actual Particle Cut Diameter for Cyclone I, 050 (EPA OTM 27 Equation 32). 

DSO = 81' ([ Tsl (Mw' Ps)]'.2091)' ((u I QsY.7091) 

DSO = 10.2S urn 

17) Actual Cunningham Correction Factor based on Dp = 2.5um, C (EPA OTM 27 Equation 4). 

C = 1+ 0.00S7193' (u/(Ps'Dp))' (Ts/MwYO.S 

C= 1.0708 

18) Initial D50 for Cyclone IV based on test condition Reynolds number from OTM 27 Equation 8. 

If Nre < 3162, use Equation 33 which results in 050 for IV = 

If Nre >= 3162, use Equation 34 which results in 050 for iV = 

Initial 050 

2.2S 

2.17 

Equation 33 

Equation 34 

Equation 35 

DSO = 0.0024302'(u/Qs)'1.1791'(lICYO.S'(Ts/(Ps'Mw))'0.6790 

DSO = 0.019723'( u/QsYO.80S8'(lIC)'05'(Ts/(Ps'Mw))'0.30S8 

Cr = 1 + 0.00S7193'(u/(Ps'DSO)),(Ts/Mw)'0.S 

19) Re-established 050 (or Cyclone IV, 050-1, 

Page 5 

Re-established 

Cunningham, Cr 

1.0789 

1.0816 

If Nre < 3162, use Equation 36 which results in 050 for IV = 

If Nre >= 3162, use Equation 37 which results In 050 for iV = 

Recalculated Cut Oiam, 050-1 

2.24 

2.16 

Equation 36 

Equation 37 

DSO-1 = 0.0024302'(u/Qs)'1.1791'( 1/Cr)'05'(Ts/(Ps'Mw)),06790 

DSO-1 = 0.019723'(u/Qs)'0. 80S8'(1ICr)'0.S'(Ts/(Ps'Mw))'0.30S8 

19) Establis/ling "Z" value, Z. 

If Equation 36 was used, then Z = 050-1/ 050 = 

If Equation 37 was used, then Z = 050-11 050 = 

If 0.99 < Z < 1,01, then 050-1 is best cut diameter estrmate, 

If 0.99 > Z > 1.01, then repeat cales for Cr using 050-1 

1.00 

1.00 
3333-TSP-Metals-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tsld= 

On = 

An = 

y= 

t= 

Ds= 

As= 

Cp= 

Kp= 

K1 = 

K2= 

K3= 

Fd = 

(02( 

(C02( 

(N2( 

AirNova, Inc. 

EPA Methods 1,2,3A,4,5 and 29 

(Flows, 02/C02, H20, TSP and Metals) 

Spruance Genco, LLC 

3333 

Unit No.2 

One 

04/22110 

0647-1318 

Emission Data 

724.3 cc 

233.649 dcf 

-0.45 in. H20 

29.81 in. Hg 

29.78 in. Hg 

29.92 in. Hg 

0.7235 in. H20 ".5 

1.446 in. H20 

523.5 R 

650.5 R 

527.7 R 

0.248 in. 

0.000335 sq. ft. 

1.01 

360 min. 

10.30 ft. 

83.3204 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq. rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]".5}/[s·R·inH20) Pitot tube constant 

17.637 Rlin.Hg 

0.047070 cu.fVml 

0.0026688 in.Hg-cf/ml-R 

9828 scf/MMBtu 

Instrumental Data 

4.89 %-dry 

14.03 %-dry 

81.08 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y" Vm ~ (Pb + dH/13.6) I Tm 

Vmstd = 237.872 dscf 

6.737 dscm 

Unit No.2 

Ooe 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 .. Vic 

Vw(std) = 34.093 set 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.1254 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44~%C02) + (32*%02) + (28*%N2))· (1-Bws) 1 + (18"Bws) 

Ms= 28.881 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp" Cp" (dP) .. (Ts/Ps*Ms)~.5 

Vs= 45.187 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min * Vs .. As 

Qa = 225901.83 cfm 

6397.54 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa .. (TstdfTs) .. (Ps/Pstd) .. (1-Bws) 

Qstd = 159529.83 dscfm 

4517.88 dscmm 

Page 2 
Client Spruanee Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Unit No, 2 

One 

Calculations (cont.) 

8) Particulate Matter Analytical Data 

INPUT A 0.0510 9 

INPUT B 100 ml 

INPUT C 0.0189 9 

INPUT D 100 ml 

INPUT E 0.0000 9 

9) Particulate sample mass calculations 

H 

J 

Front Half: 

Acetone blank adj. residue v 

Adj. Acetone wash part.wt. 

Front half sample wt, 

10) Front Half Particulate Matter Emission Data 

Filler sample net wt 

Front acetone wash vol. 

Front acetone residue wt. 

Acetone blank vol, 

Acetone blank residue wt. 

0.0000 9 

0.0189 9 

0.0699 9 

E·(B/D) 

C-H 

A+ I 

C[PM) = (Front HalfWt)(g)" (1Nmstd) "15.43(grainslg) 

E[PM) = C[PM] .. Vdscfm .. A .. (60 min/hr) .. (1 Ib 17000 grains) 

Page 3 

E[PM] Ib/MMBtu = E[PM] Ib/hr*(Fuel HV) scf/Btu .. (tuel use) 1 hour/kscrkscf/1000scf10116Btu/MMBtu 

C[PM] = 4,53E-03 grains/dscf 

C[PM] = 6.48E-07 Ib/dscf 

E[PM] = 6.200 Ibfhr 

E[PM] = 8.31E-03IbfMMBtu 

11)Traee metal concentrations and emission rates 

Element 

Antimony 

Arsenic 

Beryllium 

Cadmium 

Chromium 

Cobalt 

Lead 

Manganese 

Nickel 

Selenium 

C[M) = M[M) (ug) fVmstd (dsem) 

C[M)(lb/dscf) = C[M](ugfdscm) ~ 1e-06g/ug" 2.205e-03Ibfg" 0.02832 dscmfdscf 

E[M)(lb/hr) = C[M] (ugfdscm)" (2.20SE-09) (Ib/ug)" Qstd (dsemm)" 60 (minfhr) 

E[M)(lb/MMBtu) = C[M](Ibldscf) ~ Fd • (20.9/20.9-%02) 

C[M](@corr. 02) = C[M] (ug/dscm) ~ [(20.9-corrected %02) / (20.9-aetual %02) 1 

Corrected 02 percentage is: 7.0 % 

Sample Cone. Conc.@92rr. Q2 Conc. Emission Rate 

Mass tug) (ug/dscm) (ug/dsem) {lb/dseD (lb/hrl 

0.556 8.25E-02 7.17E·02 5.15E-i2 4.93E-05 

3.293 4,89E-01 4.24E-01 3.05E-11 2,92E-04 

0.704 1.05E-01 9.07E-02 6.53E-12 6.25E-05 

0.697 i.03E-01 8.9BE-02 6.46E-12 6.18E-OS 

9.668 1.44E+00 1.25E+00 B.96E-11 8.58E-04 

2.23 3.31E-01 2.87E·01 2.07E-11 1.98E-04 

4,569 6.7BE-01 5.B9E·01 4.24E-11 4.05E-04 

6.66 9.89E-01 B.5BE-01 6.17E-11 5,9iE-04 

'14.09 2.09E·~00 1.82E+00 1.31E-10 1.25E-03 

1.37 2.03E-01 1.77E-01 1.27E-11 1.22E-04 

12) Isokinecity, I. 

% I = [100*Ts~(K3*Vlc+«(Vm·Y)lTm)*(Pb+(dH/13.6»»11 (BO't*Ps·Vs*An) 

%1= 102.88 

" < " symbol indicates values given are the quantitative detection limit. 

Emission Rate 

(lb/MMBtu) 

6.6i2E-08 

3.916E-07 

8.373E-OB 

B.289E-OB 

1.150E-06 

2.652E-07 

5.434E-07 

7.921 E-07 

1.B76E-06 

1.629E-07 
3333-TSP-Metals-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

Dn = 

An = 

y= 

t = 

Ds= 

As= 

Cp = 

Kp= 

K1 = 

K2 = 

K3= 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,5 and 29 

(Flows, 02lC02, H20, TSP and Metals) 

Spruance Genco, LLC 

3333 

Unit No.2 

Two 

04/22/10 

1335-1943 

Emission Data 

698.3 cc 

229.530 dcf 

-0.45 in. H20 

29.81 in. Hg 

29.78 in. Hg 

29.92 in. Hg 

0.7114 in. H20 ".5 

1.423 in. H20 

533.0 R 

652.3 R 

527.7 R 

0.248 in. 

0.000335 sq. ft. 

1.01 

360 min. 

10.30 ft. 

83.3204 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 fl[(lbllbmoIY"(inHg)]".5}/[s*R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.ftfml 

0.0026688 in.Hg-cf/ml-R 

9676 scf/MMBtu 

Instrumental Data 

4.45 %-dry 

14.29 %-dry 

81.26 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y;O Vm ~ (Pb .~ dH/13.6) I Tm 

Vmstd = 229.500 dscf 

6.499 dscm 

Unit No.2 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

VW(std) = 32.869 scf 

3) Decimal fraction of moisture by volume In stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1253 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32*%02) + (28*O/ON2» * (1-Bws) I" (18*Bws) 

Ms = 28.903 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp * (dP) ~ (Ts/Ps*Ms)".5 

Vs = 44.476 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min'" Vs * As 

Qa = 222346.97 cfm 

6296.87 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa * (Tstd/Ts);O (Ps/Pstd) ;0 (1-Bws) 

Qstd = 156592.36 dscfm 

4434.70 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cant.) 

Unit No.2 

Two 

8) Particulate Matter Analytical Data 

INPUT A 0.0337 9 

INPUT B 100 ml 

INPUT C 0.0240 9 

INPUT D 100 ml 

INPUT E 0.0000 9 

9) Particulate sample mass calculations 

H 

I 

J 

Front Half: 

Acetone blank adj. residue v 

Adj. Acetone wash part.wt. 

Front half sample wt. 

10) Front Half Particulate Matter Emission Data 

Filter sample net wt 

Front acetone wash vol. 

Front acetone residue wt. 

Acetone blank vol. 

Acetone blank residue wt. 

0.0000 9 

0.0240 9 

0.0577 9 

E'(BID) 

C-H 

A+ I 

C[PM] = (Front Half Wt)(g) * (1Nmstd) * 1S.43(grains/g) 

E[PMJ = C[PMJ ~ Vdscfm * A * (60 min/hr) .. (1 Ib 17000 grains) 

Page 3 

E[PM)lb/MMBtu = E[PM)lb/hr"(Fuel HV) scf/Btu*(fuel use) 1 hour/kscf*kscf/1000scf*10"6BtuIMMBtu 

C[PM) = 3.8BE-03 grains/dscf 

C[PM) = 5.S4E-07 Ib/dscf 

E[PM) = 5.207 Ib/hr 

E[PM) = 6.81E·03Ib/MMBtu 

11)Trace metal concentrations and emission rates 

Element 

Antimony 

Arsenic 

Beryllium 

Cadmium 

Chromium 

Cobalt 

Lead 

Manganese 

Nickel 

Selenium 

C[M) = M[MI (ug) I Vmstd (dscm) 

C[M)(lb/dscf) = C[M](ug/dscm) ~ 1e-06g/ug" 2.205e-03Ib/g" 0.02832 dscm/dscf 

E[M)(lb/hr) = C[M] (ug/dscm) .. (2.20SE-09) (Ib/ug)" Qstd (dscmm) * 60 (min/hr) 

E[M)(lb/MMBtu) = C[M)(lb/dscf) * Fd" (20.9f20.9-%02) 

C[M)(@corr. 02) = C[M] (ug/dscm) ,. [ (20.9-corrected %02) I (20.9-actual %02) I 

Corrected 02 percentage is: 7.0 % 

Sample Conc. Conc.@corr. 02 Cone. Emission Rate 

Mass tug) (ug/dscm) (ugldscm) {Ib/dscf} (lb/hrl 

1.122 1.73E-01 1.46E-01 1.0BE-11 1.01 E-04 

2.51 3.B6E-01 3.26E-01 2.41E-11 2.27E-04 

0.607 9.34E-02 7.B9E-02 S.B3E-12 S.4BE-05 

0.413 6.35E-02 5.37E-02 3.97E-12 373E-05 

6.127 9.43E-01 7.97E-01 5.89E-11 553E-04 

2.25 3.46E-01 2.93E-01 2.16E-11 203E-04 

4.20B 6.47E-01 5.47E-01 4.04E-11 3.80E-04 

6.34 9.7SE-01 8.24E-01 6.09E-11 5.72E-04 

29.964 4.61E+00 3.90E+OO 2.BBE-10 2.70E-03 

1.11 1.71 E-01 1.44E-01 1.07E-11 1.00E-04 

12) Isokinecity, I. 

% I = [100'TS*(K3*Vlc+«(Vm*Y)fTm)*(Pb+(dH/13.6))))] I (60*t*Ps*Vs*An) 

%1= 101.12 

" < " symbol indicates values given are the quantitative detection limit. 

Emission Rate 

(lb/MMBtu) 

1.325E-07 

2.965E-07 

7.170E-OB 

4.B7BE-OB 

7.237E-07 

2.658E-07 

4.970E-07 

7.48BE-07 

3.539E-06 

1.311E-07 
3333-TSP-Metals-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps= 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An= 

y= 

t= 

Os= 

As= 

Cp = 

Kp = 

K1 = 

K2 = 

K3= 

Fd= 

[02[ 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Methods 1,2,3A,4,5 and 29 

(Flows, 02/C02, H20, TSP and Metals) 

Spruance Genco, LLC 

3333 

Unit No.2 

Three 

04/23/10 

0600-1210 

Emission Data 

724.3 cc 

231.745 dcf 

-0.45 in H20 

29.90 in. Hg 

29.87 in. Hg 

29.92 in. Hg 

0.7254 in. H20 A.5 

1.424 in. H20 

525.0 R 

654_8 R 

527.7 R 

0.248 in. 

0.000335 sq. ft. 

1.01 

360 min. 

10.30 ft. 

83.3204 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbrnol)*(inHg)]".S}/(s*R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.ftlml 

0.0026688 in.Hg-cf/ml-R 

9826 scf/MMBtu 

Instrumental Data 

4.97 %-dry 

13.70 %-dry 

81.33 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1~ Y ~ Vm· (Pb + dH/13.6) I Tm 

Vmstd = 235.917 dscf 

6.681 dscm 

Unit No.2 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 34.093 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws, 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1263 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44~%C02) + (32*%02) + (28*%N2» * (1-Bws) 1 + (18*Bws) 

Ms = 28.826 Ib/lbmole 

5) Average stack gas velocity, Vs, 

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)"_5 

Vs = 45.426 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs ~ As 

Qa = 227093.70 cfm 

6431.29 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa * (TstdfTs) * (Ps/Pstd) * (1-Bws) 

Qstd = 15962589 dscfm 

4520.61 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Unit No.2 

Three 

Calculations (cont.) 

8) Particulate Matter Analytical Data 

INPUT A 0.0635 9 

INPUT 8 100 ml 

INPUT C 0.0213 9 

INPUT 0 100 ml 

INPUT E 0.0000 9 

9) Particulate sample mass calculations 

H 

I 

J 

Front Half: 

Acetone blank adj. residue 'I 

Adj. Acetone wash part.wt. 

Front half sample wI. 

10) Front Half Particulate Matter Emission Data 

Filter sample net wt 

Front acetone wash vol. 

Front acetone residue wt. 

Acetone blank vol. 

Acetone blank residue wt. 

0.0000 9 

0.0213 9 

0.0848 9 

E'(8/D) 

C-H 

A+ I 

C[PM] = (Front Half Wt)(g) ~ (1Nmstd) • 1S.43(grainsfg) 

E[PM] = C[PM] • Vdscfm • A * (60 minlhr) * (1 Ib 17000 grains) 

Page 3 

E[PM] Ib/MMBtu = E[PM] Ib/hr-(Fuel HV) scfIBtu*(fuel use) 1 hour/kscf*kscf/1000scf*10"6Btu/MMBtu 

C[PM] = 5.55E-03 grainsJdscf 

C[PM] = 7,92E-07Ib/dscf 

E[PM] = 7.589 Iblhr 

E[PMJ = 1.02E-02 Ib/MMBtu 

11)Trace metal concentrations and emission rates 

Element 

Antimony 

Arsenic 

Beryllium 

Cadmium 

Chromium 

Cobalt 

Lead 

Manganese 

Nickel 

Selenium 

C[M] = M[M] (ug) I Vmstd (dscm) 

C[M](Jb/dscf) '" C[M](ug/dscm) * 1e-06gfug '* 2,205e-03Ibfg '* 0.02832 dscmfdscf 

E[MJ(lbfhr) = C[M] (ug/dscm) * (2.205E-09) (Ibfug)· Qstd (dscmm) '. 60 (min/hr) 

E[M](lbfMMBtu) = C[M](lb/dscf) * Fd * (20.9120.9-%02) 

C[M](@ corr. 02) = C[M] (ug/dscm)" [(20_9-corrected %02) I (20.9-actual %02)] 

Corrected 02 percentage is: 7.0 % 

Sample Conc. Conc.@corr, 02 Conc. Emission Rate 

Mass (ug} (ug/dscm) (ug/dscm) (lb/dscQ (lb/hr) 

0.68 1.02E-01 8.88E-02 6.36E-12 6.09E-OS 

2.801 4.19E-01 3.66E-01 2.62E-11 2.51E-04 

0,944 1.41E-01 1.23E-01 8,82E-12 B.45E-05 

0.406 6.0BE-02 5.30E-02 3.79E-12 3.63E-05 

9.3'19 1.39E+00 1.22E+00 B.71E-11 8.34E-04 

3.08 4.61E-01 4.02E-01 2,88E-11 2.76E-04 

4.77 7.14E-01 6.23E-01 4.46E-11 4.27E-04 

7.121 1.07E+OO 9,30E-01 6.66E-11 6.37E-04 

34.765 5.20E+00 4.54E+OO 3.25E-10 3.11E-03 

3.4 S.09E-01 4.44E-01 3.18E-11 3.04E-04 

12) Isoklnecity. I. 

% I = [100*Ts*(K3~Vlc+«(Vm*Y)lTmr(Pb+(dHf13.6))))J 1 (60'*t'*Ps·Vs*An) 

%1= 101,97 

" <" symbol indicates values given are the quantitative detection limit. 

Emission Rate 

(lb/MMBtuj 

8,193E-08 

3.375E-07 

1.137E-07 

4.892E-08 

1.123E-06 

3.711E-07 

5.747E-07 

8.580E-07 

4.189E-06 

4.097E-07 
3333-Hg-unspiked-R 1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

Tm= 

Ts = 

Tstd= 

y= 

t= 

Ds= 

As = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Method 1, 2, 3A, and 30B - Unspiked Tube 

(Flows, 02/C02, and Mercury) 

Spruance Genco, LLC 

3333 

Unit No.2 

One 

04/22/10 

0647-1247 

Emission Data 

11.729 dcf 

-0.45 in H20 

29.81 in. Hg 

29.78 in. Hg 

29.92 in. Hg 

528.2 R 

650.5 R 

527.7 R 

1.000 

360 min. 

10.30 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83.32043375 sq. ft. Cross sectional area of stack 

85.49 ft[(lb/lbmolt(inHg)]".5}/[s*R*inH20] 

17.637 R/in.Hg constant 

0.047070 cU.ft!ml 

0.0026688 in.Hg-cf/ml-R 

9828 scf/MMBtu 

Instrumental Data 

4.89 %-dry 

14.03 %-dry 

81.08 %-dry 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client Spruance Genco, LLC Test Location 

Project No. 3333 Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =Kl" Y * Vm .. Pbl Tm 

Vmstd = 11,675 dscf 

0.3306 dsem 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws= 

Bws= 

Based on the M29 sampling train 

0.1254 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Umt No.2 

One 

Ms = [ «44*%C02) + (32*%02) + (28"%N2» .. (1-Bws) 1 + (18*Bws) 

Ms = 28.880 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs = 

Vs = 

Based on the M29 sampling train 

45_187 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min" Vs " As 

Qa = 225900.03 cfm 

6397.49 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa" (TstdlTs)" (Ps/Pstd)" (1-Bws) 

Qstd = 159508.42 dscfm 

4517.28 dscmm 

8) Mercury concentrations and emission rates 

Element 

Mercury 

C[M] = M[M] (ug) I Vmstd (dscm) 

C[M](Ib/dscf) = C[M](ug/dscm) *1e-06g/ug" 2.205e-03Ib/g" 0,02832 dscm/dscf 

E[M](lb/hr) = C[M] (ug/dscm) .. (2.205E-09) (Ib/ug) .. Qstd (dscmm) .. 60 (minlhr) 

E[M](Ib/MMBtu) = C[M](lb/dscf) .. Fd .. (20.9120.9-%02) 

C[M](@carr. 02) = C[M] (ug/dscm) * [(20.9-corrected %02) 1 (20.9-actual %02)] 

Corrected 02 percentage is: 7 % 

Sample 

Mass (ug) 

0.0006 

Conc. 

(ug/dscm) 

0.002 

Canc.@corr. 02 

(ug/dsem) 

0.002 

Conc. 

(Ib/dscf) 

1.13E-13 

Emission Rate 

(Ib/hr) 

1.0BE-06 

Page 2 

Emission Rate 

(lb/MMBtu) 

1.45E-09 
3333-Hg-unspiked-R2 , 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

Tm= 

Ts = 

Tstd= 

y= 

t= 

Ds= 

As = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

1021 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Method 1, 2, 3A, and 308 - Unspiked Tube 

(Flows, 02/C02, and Mercury) 

Spruance Genco, LLC 

3333 

Unit NO.2 

Two 

04/22/10 

1336-1936 

Emission Data 

10.286 dcf 

-0.45 in. H20 

29.81 in. Hg 

29.78 in. Hg 

29.92 in. Hg 

545.1 R 

652.3 R 

527.7 R 

1.000 

360 min. 

10.30 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83,32043375 sq. ft. Cross sectional area of stack 

85.49 ft[(1 b/lbmol)*(i nHg)]1I .5}/[ s*R*inH20] 

17.637 R/in.Hg 

0.047070 cu.ftIml 

0.0026688 in,Hg-cf/ml-R 

9676 scf/MMBtu 

Instrumental Data 

4.45 %-dry 

14.29 %-dry 

81,26 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1'" Y" Vm '" Pb/ Tm 

Vmstd = 9.921 dscf 

0.2810 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws = 

Bws = 

Based on the M29 sampling train 

0,1253 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No.2 

Two 

Ms = [((44"'%C02) + (32*%02) + (28~%N2» '" (1-Bws)] + (18*Bws) 

Ms= 28,903 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs = 

Vs = 

Based on the M29 sampling train 

44A76 fps 

6) Average actual stack gas volumetric fJowrate, Qa. 

Qa = 60 sec/min'" Vs '" As 

Qa = 222345,58 cfm 

6296.83 cmm 

7) Average stack gas dry VOlumetric f1owrate, Qstd. 

Qstd = Qa * (Tstdffs)'" (Ps/Pstd) '" (1-Bws) 

Qstd = 156583.29 dscfm 

4434.44 dscmm 

8) Mercury concentrations and emission rates 

C[Mj = M[M] (ug) 1 Vmstd (dscm) 

C[M](lb/dscf) = C[M](ug/dscm) '" 1 e-06g/ug" 2.205e-03Ib/g ... 0.02832 dscm/dscf 

E[M](lb/hr) = C[M] (ug/dscm) * (2.205E-09) (Ib/ug) * Qstd (dscmm) * 60 (rnin/hr) 

E[M](lb/MMBtu) = C[M](Ib/dscf) * Fd ;0 (20.9/20.9-%02) 

C[M](@ carr. 02) = C[MJ (ug/dscm) ... [ (20.9-corrected %02) 1 (20 9-actual %02)] 

Corrected 02 percentage is: 7 % 

Sample Cone QQnc.@corr. 02 Conc_ Emissioo Bat§! 

Element Mass (ug) (lIg/dscml (ug/dscm) (Ib/dscfl (lb/hr) 

Mercury 0.0009 0003 0.003 2.00E-13 1.88E-06 

Page 2 

Emission Bate! 

(lb/MMBtu) 

2.46E-09 
3333-Hg-unspiked-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

Tm= 

Ts = 

Tstd= 

y, 

!, 

Ds= 

As = 

Kp' 

K1 = 

K2' 

K3 ' 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc_ 

EPA Method 1, 2, 3A, and 30B - Unspiked Tube 

(Flows, 02JC02, and Mercury) 

Spruance Genco, LLC 

3333 

Unit NO.2 

Three 

04/23/10 

0600-1200 

Emission Data 

6,540 dcf 

-OA5 in H20 

29.90 in. Hg 

29.87 in. Hg 

29.92 tn. Hg 

536.5 R 

654.8 R 

527.7 R 

1.000 

360 min. 

10.30 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83,32043375 sq. ft Cross sectional area of stack 

85A9 ft[(lb/lbmolninHgW.5}J[s*R~inH20J 

17.637 R/in.Hg 

0.047070 cu:ftlml 

0.0026688 m.Hg-cf/ml-R 

9826 scf/MMBtu 

Instrumental Data 

4,97 %-dry 

13.70 %-dry 

81.33 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1~ Y,o Vm,o Pbl Tm 

Vmstd = 6.428 dscf 

0.1821 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws = 

Bws = 

Based on the M29 sampling train 

0.1263 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No 2 

Three 

Ms = [«44*%C02) + (32*%02) + (2B*%N2»· (1-Bws)] + (1B,oBws) 

Ms = 28.826 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs= 

Vs = 

Based on the M29 sampling train 

45.426 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min ;0; Vs * As 

Oa = 227094.84 cfm 

6431.33 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd '" Qa,o (TstdlTs)· (Ps/Pstd) * (1-Bws) 

Qstd = 159616.12 dscfm 

4520.33 dscmm 

8) Mercury concentrations and emission rates 

Element 

Mercury 

C[M] = M[M] (ug) I Vmstd (dscm) 

C[M](lb/dscf) = C[M](ug/dscm) ,o1e-06g/ug,o 2.205e-03Ib/g * 0.02832 dscm/dscf 

E[M](lb/hr) = C[M] (ug/dscm) * (2.20SE-09) (Ib/ug)· Qstd (dscmm) * 60 (mm/hr) 

E[M](lb/MMBtu) = C[M](lb/dscf) • Fd .. (20.9120.9-%02) 

C[M]{@ corr. 02) = C[M] (ug/dscm) • [(20.9-corrected %02) / (20 9-actual %02) 1 

Corrected 02 percentage is: 7 % 

Sample 

Mass (ug) 

0.0009 

Conc. 

(ug/dscm) 

0.005 

Cgnc.@corr. 02 

(ug/dscm) 

0.004 

Conc 

(Ib/dscfl 

3.09E-13 

Emission Rate 

(Ib/hr) 

2.96E-06 

Page 2 

Emission Rate 

(lb/MMBtu) 

3.98E-09 
M7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco,LLC 

3333 

Unit No.2 

04123110 

Parameter: 

Instrument Span f% 02): 

Oxygen 

21.96 

Actual Calibration Gas Value f% 02): 

Analyzer Calibrafion Response (% 02): 

Analvzer Calibration Error f% Span): 

Zero S~stem Calibration Gas 

A(2Qarent Init. Sl::::s. Inil. Sl::::s. Final S)!s. Final S:t::s. 

Stack Calib. Cal. Bias Calib. Cal. Bias 

Run Cone. Response (% soan) Response (% span) 

1 4.59 -0.01 -0.09 0.02 0.05 

2 4.17 0.02 0.05 0.02 0.05 

3 4.04 0.02 0.05 0.02 0.05 

4 0.00 0.02 0.05 0.00 -0.05 

5 0.00 0.00 -0.05 0.00 -0.05 

6 0.00 0.00 -0.05 0.00 -0.05 

7 0.00 000 -0.05 0.00 -005 

8 0.00 0.00 -0.05 0.00 -0.05 

9 0.00 0.00 -0.05 0.00 -0.05 

10 0.00 0.00 -0.05 0.00 -0.05 

11 0.00 0.00 -0.05 0.00 -0.05 

12 0.00 0.00 -0.05 0.00 -0.05 

AirNova, Inc. Page 1 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

An§!/~z!,'!:r Galib. Gases UQscalft. 

zero low mid high SI:§:. c.al. Gas 

0.00 NIA 12.46 21.96 12-46 

0.01 NIA 12.38 21.62 12.38 

0.05 000 -0.36 -1.55 

URscale Sllstem Calibration Gas 

Calib. {nit- Sl:::":s. Ini!. S!!,s. Final Sl::::s. Final Sl!s. Gatib. Actual 

Drift Galib. Cal. Bias Calib. Cal. Bjg~ !lli!l Stack 

(% span) Response (% soan) Response r% span) r% span) Cone. 

0.14 12.39 0.05 12.44 0.27 0.23 4.60 

0.00 12.44 0.27 12.45 0.32 0.05 4.16 

0.00 12.45 0.32 12.43 0.23 -0.09 4.03 

-0.09 12.43 0.23 0.00 -56.38 -56.60 -0.02 

0.00 0.00 -56.38 0.00 -56.38 0.00 ERR 

0.00 0.00 -56.38 0.00 -56.38 0.00 ERR 

0.00 0.00 -56.38 0.00 -56.38 0.00 ERR 

0.00 0.00 -56.38 0.00 -56.38 0.00 ERR 

0.00 0.00 -56.38 0.00 -56.38 0.00 ERR 

0.00 000 -5638 0.00 -56.38 0.00 ERR 

0.00 0.00 -56.38 0.00 -5638 0.00 ERR 

0.00 0.00 -56.38 0.00 -56.38 0.00 ERR 
M7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance GenCO,LLC 

3333 

UnirNa.2 

04123110 

Parameter 

Instrument Span f% C02): 

Carbon Dioxide 

17.83 

Actual Calibration Gas Value t% C02): 

Analyzer Calibration Response f% C02): 

Analvzer Calibration EfTOr (% Span'.' 

Zero SYStem Calibration Gas 

Apparent Init. S\:::s. Init. S:ys. Final Sys. Final S\:,:s. 

Stack c..a.ti!2. Cal. Bias Calib. Ca'- Bias 

Run Cone. Response (% span) Response (% span) 

1 13.95 0.04 0.00 0.00 -0.22 

2 14.65 0.00 -0.22 0.04 0.00 

3 14.74 0.04 0.00 004 0.00 

4 0.00 0.04 0.00 0.00 -0.22 

5 0.00 0.00 -0.22 0.00 -0.22 

6 0.00 000 -0.22 0.00 -022 

7 0.00 0.00 -0.22 0.00 -0.22 

8 0.00 0.00 -0.22 0.00 -0.22 

9 0.00 0.00 -0.22 0.00 -0.22 

10 0.00 0.00 -0.22 000 -0.22 

11 0.00 0.00 -0.22 0.00 -0.22 

12 0.00 0.00 -0.22 0.00 -0.22 

AirNova, Inc. Page 2 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

AnalYZer Galib. Gases Upscale 

zero low mid high $\:,:8. Cal. Gas 

0.00 NIA 7.49 17.83 7.49 

0.04 NIA 7.52 17.83 7.52 

0.22 0.00 0.17 0.00 

Upscale System Calibration Gas 

Ga/ib. Init. S!:::,:s. Init. S:~. Final S)t:s. Final Sys. Cafib. ~ 

Drift Calib. Cflf. Bias Ca/ib. Cal. Bias Dnlt Stack 

(% span) Response (% soan) Response (% span) (% span) Cone. 

-0.22 7.53 006 7.46 -0.34 -0.39 13.96 

0.22 746 -0.34 7.63 0.62 0.95 14.56 

0.00 7.63 0.62 7.62 0.56 -0.06 14.52 

-0.22 7.62 0.56 0.00 -42.18 -42.74 -0.04 

0.00 0.00 -42 18 0.00 -42.18 0.00 ERR 

000 0.00 -42.18 0.00 -42.18 0.00 ERR 

0.00 000 -42.18 0.00 -42.18 0.00 ERR 

0.00 0.00 -42.18 0.00 -42.18 000 ERR 

0.00 0.00 -42.18 0.00 -42.18 0.00 ERR 

0.00 0.00 -42.18 0.00 -42.18 0.00 ERR 

0.00 0.00 -42.18 0.00 -42.18 0.00 ERR 

0.00 0.00 -42.18 0.00 -42 18 0.00 ERR 
M7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco,LLC 

3333 

Unit No.2 

04/23/10 

Parameter. Carbon Monoxide 

Instrument Span (ppmV CO): 2246 

Actual Calibration Gas Value (ppmV CO): 

Analyzer Calibration Response (ppmV COl: 

Analvzer Calibration Error (% Spant 

Zero Sllstem Calibration Gas 

AQQarent fnit. $\:,s. Init. S)!s. Final Sl!s. Final Sk§. 

Stack Ca/ib. Cal. Bias Calib. Cal. Bias 

Run Cone. Response (% span) Response (% span) 

1 529.2 2.4 0.11 -1.2 -0.05 

2 268.3 -1.2 -0.05 -24 -0.11 

3 478.3 -2.4 -0.11 -1.2 -0.05 

4 00 -1.2 -0.05 0.0 0.00 

5 0.0 0.0 0.00 00 0.00 

6 0.0 00 0.00 0.0 0.00 

7 0.0 0.0 0.00 0.0 000 

a 0.0 0.0 0.00 0.0 0.00 

g 00 0.0 0.00 0.0 0.00 

10 0.0 0.0 0.00 00 0.00 

11 0.0 00 0.00 0.0 0.00 

12 0.0 0.0 0.00 0.0 000 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drjft and Bias Adjustment) 

zero 

0.0 

0.0 

0.00 

Analyzer CaNb. Gases 

/QJI< mid 

0.0 1204.0 

0.0 1209.7 

0.00 025 

high 

2246.0 

2254.6 

0.38 

Ugscale S~stem Calibration Gas 

~ Inil. Sl!s. Inft. $1::s. Final SI§. Finf1! S)!s. 

Drift Calib. Cal. Bias Galib. Cal. Bias 

(% span) Response (% span) Response (% span) 

-0.16 1207.5 -0.10 1209.7 0.00 

-0.05 1209.7 0.00 1202,4 -0.33 

0.05 1202.4 -0.33 1201.5 -0.37 

0.05 1201.5 -0.37 00 -53.86 

0.00 0.0 -53.86 0.0 -53.86 

0.00 00 -53.86 0.0 -53.86 

000 00 -53.86 0.0 -53.86 

0.00 0.0 -53.86 0.0 -53.86 

0.00 0.0 -53.86 00 -53.86 

0.00 0.0 -53.86 0.0 -53.86 

0.00 0.0 -53.86 0.0 -53.86 

000 00 -53.86 0.0 -53.86 

Page 3 

UQscale 

S!!s. Qal. Gas 

1204.0 

1209.7 

Cafib. Actual 

Drift Stack 

(% span) Cone, 

0.10 526.8 

-0.33 269.3 

-0.04 480.2 

-53.49 1.2 

0.00 ERR 

0.00 ERR 

0.00 ERR 

0.00 ERR 

0.00 ERR 

0.00 ERR 

0.00 ERR 

0.00 ERR 
M7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco,LLC 

3333 

Unit No.2 

04/23/10 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Parameter: Total Hydrocarbons (as CH4 

Run 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

Instrument Span (ppm V THe): 20 

Actual Calibration Gas Value (ppmV THe): 

Analvzer Calibration Response (PpmV THe/. 

Analvzer Calibration Error (% Cal Gas Value).-

Zero S~stem Calibration Gas 

AQQsrent Init S~,:;;. Init· S)§. Final S\"s. Final S\"s. 

Stack Calib, Cal. Bias CaNb. Cal. Bias 

Cone. Response (% soan) Response f% span) 

1.7 -0.0 0.00 0.0 0.40 

1.0 0.0 0.40 0.1 0.70 

1.2 0.1 0.70 -0.0 0.15 

0.0 -0.0 0.15 0.0 020 

0.0 0.0 020 0.0 020 

0.0 0.0 0.20 0.0 0.20 

00 0.0 0.20 0.0 0.20 

00 0.0 0.20 00 0.20 

0.0 0.0 0.20 0.0 0.20 

0.0 00 020 0.0 0_20 

0.0 0.0 0.20 0.0 0.20 

0.0 0.0 0.20 0.0 0.20 

Analmr Calib. Gases 

'"'" low mid high 

0.0 4.9 9.1 17.4 

-0.0 4.8 9.2 17.5 

-1.84 0.99 0.75 

Uescale Sy:stem Calibration Gas 

Galib. Init. S)!s. Init. S~. Final S)!S, Final S)!s. 

Drift Calib. Cal. Bias Calib. Cal. Bias 

(% span) Response (% span) Response t% span) 

0.40 9.2 0.00 9.0 -0.75 

0.30 9.0 -0.75 9.0 -1.00 

-0.55 9.0 -1.00 9.0 -1.00 

0.05 9.0 -1.00 0.0 -45_90 

0.00 0.0 -45_90 0.0 -45.90 

0.00 0.0 -45_90 0.0 -45.90 

000 00 -45.90 0.0 -45.90 

0.00 0.0 -45.90 0.0 -45.90 

0.00 0.0 -45.90 0.0 -45.90 

0.00 0.0 -45.90 0.0 -45.90 

0.00 0.0 -45.90 0.0 -45.90 

0_00 00 -45.90 0.0 -45.90 

Page 4 

UQscaJe 

S)§. Qat Gas 

9.1 

9.2 

Calib. Actual 

Drift Stack 

(% span) Cone. 

-0.75 1.7 

-0.25 0." 

0.00 1.2 

-44.90 0.0 

0_00 ERR 

0.00 ERR 

0.00 ERR 

0.00 ERR 

0.00 ERR 

0.00 ERR 

0.00 ERR 

0.00 ERR 
3333-Formaldehyde-R1 

Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

Vlc= 

Vm= 

Pstatic = 

Pb =-

Ps= 

Pstd = 

dP" 

dH = 

Tm= 

Ts = 

Tstd= 

y= 

t= 

On = 

An = 

Os = 

As= 

Cpo 

Kp= 

K1 = 

K2 = 

K3 = 

Fd = 

CF = 

[02[ 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and RCRA Method 0011 

(Flows, 02/C02, H20, and Formaldehyde) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit No.2 

04/23/10 

One 

1245-1450 

Emission Data 

252.2 cc 

80.739 dcf 

-0.45 in. H20 

29.93 in. Hg 

29.90 In. Hg 

29.92 in. Hg 

0.714 In. H20 A.S 

1.50 in. H20 

542.3 R 

649.7 R 

527. 7 R 

0.99 

120 min, 

0.253 in. 

0.000349 sq. ft. 

10.30 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]'"" 5}/[s*R*lnH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.ft!ml 

0.0026688 in.Hg-cf/ml-R 

9828 scf/MMBtu 

7.793E-08 Ib/dscf I ppmVd 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for CH20 

EPA Method 3A Instrumental Data 

4.60 %-dry 

13.96 %-dry 

81.44 %-dry 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Data from: 

EPA4 

EPA4 

EPA 2 

EPA 2 

EPA 2 

EPA4 

EPA4 

EPA 2 

EPA2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd, 

Vmstd =K1* Y· Vm • (Pb + dH/13,6) I Tm 

Vmsld = 78 095 dscf 

2212 dscm 

Richmond, Virginia 

One 

2) Volume of water vapor collected al standard conditions, Vw(Sld). 

Vw(std) = K2 * Vic 

Vw(sld) = 11.871 scf 

3) DecImal fraction of moisture by volume In stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.1319 

4) Molecular weight of the stack gas on a wet basis, Ms, 

Ms = [«44·%C02) + (32"'%02) + (2S·%N2))· (1-Bws) 1 + (18*8ws) 

Ms= 28.779 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp'" Cp" (dP) .. (Ts/Ps·Ms)".5 

Vs = 44.576 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min· Vs .. As 

Qa = 222845.42 cfm 

6310.98 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa" (TsldlTs)" (Ps/Pstd)" (1-Bws) 

Qstd = 156995.68 dscfm 

Qsld = 4446.12 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cant.) 

8) Formaldehyde - Concentrations and Emission Rates 

M[CH20] = sample mass (mg) 

RIchmond, Virginia 

One 

qCH20] = M[CH20] (mg) J sample volume (dscm) 

qCH20@ corr. %02] ., qCH20] (ppmV) ~ (20.9-Corr. %02)/(20.9-Actual %02) 

Corrected 02 Percentage" 7 % 

E[CH20] = C[CH20] (mg/dscm) • 60 (min/hr) * Qstd (dscmm) * (1 Ib 14.536 e+05 mg) 

E[CH20](lb/MMBtu) = C[CH20](ppmV) CF * Fd * (20.9120.9-%02) 

Page 3 

Coml2ound Sample Mass Concentration Concentration Concentration Mass Emission Mass Emi::isiQO 

!mg) (mg/dscm) !QQmYl pmV@Corr.%O (lb/hr) (lb/MMBtu) 

Formaldehyde 0.00452 2.04E-03 1.64E-03 1.40E-03 1.20E·03 1.61E·06 

NO NO NO NO NO NO 

9) Isokinecity, I. % I = [100*Ts*(K3"Vlc+«(Vm*Y)/Tm)*(Pb+(dH/13 6»)))]1 (60*t*Ps*Vs*An) 

% I = 98.94 
3333-FormaJdehyde-R2 

Client 

Project No. 

Test location 

Emission Source 

Test Date 

Test Run 

Time Period 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

y= 

1= 

On = 

An = 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

CF = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and RCRA Method 0011 

(Flows, 02/C02, H20, and Formaldehyde) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit No.2 

04/23/10 

Two 

1520-1725 

Emission Data 

252.8 cc 

82.077 dcf 

-045 in. H20 

29.90 in. Hg 

2987 In. Hg 

29.92 in. Hg 

0.706 in. H20 ".5 

1.48 in. H20 

542.3 R 

650.9 R 

527.7 R 

0.99 

120 min. 

0.253 in. 

0.000349 sq. ft. 

10.30 ft 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R'inH20J Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.fVml 

0.0026688 in.Hg-cf/ml-R 

9676 scf/MMBtu 

7.793E-08 Ib/dscf I ppmVd 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for CH20 

EPA Method 3A Instrumental Data 

4.16 %-dry 

14.56 %-dry 

81.28 %-dry 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Data from: 

EPA4 

EPA 4 

EPA 2 

EPA 2 

EPA 2 

EPA 4 

EPA4 

EPA 2 

EPA2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1~ Y ~ Vm ;0 (Pb + dH/13.6) / Tm 

Vmstd = 79.305 dscf 

2.246 dscm 

Richmond, VIrginia 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 ~ Vic 

Vw(std) = 11.899 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.1305 

4) Molecular weight of the stack gas on a wet basis, Ms 

Ms = [((44*%C02) + (32*%02) + (28*%N2»· (1-Bws) 1 + (18*Bws) 

Ms = 28866 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp;O Cp • (dP) • (Ts/Ps~Ms)".5 

Vs = 44048 fps 

6) Average actual slack gas volumetric flowrale, Qa. 

Qa = 60 sec/min· Vs " As 

Qa = 220205.96 cfm 

6236.23 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa· (TstdfTs)· (Ps/Pstd) * (1-Bws) 

Qstd = 

Qstd = 

154966.74 dscfm 

4388.66 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Formaldehyde - Concentrations and Emission Rates 

M[CH20] = sample mass (mg) 

Richmond, Virginia 

Two 

C[CH20] = M[CH20] (mg) 1 sample volume (dscm) 

C[CH20 @ corr, %02] = C[CH20] (ppmV) ~ (20.9-Corr. %02)/(20.9-Aclual %02) 

Corrected 02 Percentage = 7 % 

E[CH20] = C[CH20] (mg/dscm) "60 (mln/hr)· Qsld (dscmm) • (1 Ib 14.536 e+05 mg) 

E[CH20](lb/MMBlu) = C[CH20](ppmV) CF " Fd .. (20.9/20,9-%02) 

Page 3 

Com~ound Sam~le Mass Concentration Concentration ConcentratloD Mass Emission Mass Emis,siQD 

ill19l (mg/dscm) !Jlimllil 'pmV@Corr.%O (lb/hr) Clb/MMBlu) 

Formaldehyde 0.00476 2.12E-03 1.70E-03 1,41E-03 1.23E-03 1.60E-06 

NO NO NO NO NO NO 

9) Isokineclty, I. % I = [100*Ts*(K3"Vlc+((Vm*Y}fTm)*(Pb+(dH/13.6))))] I (60"t*Ps*Vs*An) 

% I = 101.78 
3333-F ormaldehyde-R3 

Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

Vlc= 

Vm= 

Pstatic = 

Pb= 

Ps= 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

y= 

t= 

On = 

An = 

Ds= 

As= 

Cp= 

Kp= 

K1 = 

K2 = 

K3 = 

Fd = 

CF = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and RCRA Method 0011 

(Flows, 02/C02, H20, and Formaldehyde) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit No.2 

04/23/10 

Three 

1803-2003 

Emission Data 

253.0 IX 

83.136 dcf 

-0.45 in. H2O 

29.90 in. Hg 

29.87 in. Hg 

29.92 in. Hg 

0718 in. H20 '\5 

1.53 in. H20 

540.0 R 

651.4 R 

527.7 R 

0.99 

120 min. 

0.253 in. 

0.000349 sq. ft 

10.30 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometnc pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration facior 

Durairon of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of slack 

83.3204 sq. ft Cross sectional area of stack 

0.84 Pilot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R"inH20] PltOt tube constant 

17.637 R/in.Hg 

0047070 cu.ftlml 

0.0026688 in.Hg·cf/ml-R 

9826 scf/MMBtu 

7.793E-08 Ib/dscf I ppmVd 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for CH20 

EPA Method 3A Instrumental Data 

4.03 %·dry 

14.52 %-dry 

81.45 %-dry 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Data from: 

EPA4 

EPA4 

EPA2 

EPA 2 

EPA2 

EPA4 

EPA4 

EPA2 

EPA2 
Client 

Project No. 

Spruance Genco. llC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmsld =K1 ~ Y ., Vm ,. (Pb + dH/13.6) / Tm 

Vmstd = 80.685 dscf 

2.285 dscm 

Richmond, Virginia 

Three 

2) Volume of water vapor collected al standard conditions, Vw(std). 

Vw(sld) = K2 ,. Vic 

Vw(std) = 11.909 scf 

3) Decimal fraction of moisture by volume in stack gas, 8ws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws =- 0.1286 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44'%C02) + (32·%02) + (2S·%N2»" (1-Bws) 1 + (18'*Bws) 

Ms= 28.879 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp .. (dP) '* (Ts/Ps*Ms)".5 

Vs = 44.829 fps 

6) Average actual stack gas volumetric flowrate, Oa. 

Qa = 60 sec/min '* Vs • As 

Qa = 224108.79 cfm 

6346.76 cmm 

7) Average stack gas dry volumetnc flowrate, Qstd. 

Qstd = Qa '* (TstdlTs) '* (Ps/Pstd) * (1-Bws) 

Ostd = 

Ostd = 

157928.65 dscfm 

4472.54 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

B) Formaldehyde - Concentrations and Emission Rates 

M[CH20] = sample mass (mg) 

Richmond, Virginia 

Three 

QCH20] = M[CH20] (mg) I sample volume (dscm) 

QCH20 @ corr. %02) = QCH20] (ppmV) ~ (20.9-Corr. %02)/(20.9-Actual %02) 

Corrected 02 Percentage = 7 % 

E[CH20] = C[CH20] (mg/dscm) .. 60 (min/hr) "Qstd (dscmm) • (1 Ib 14 536 e+05 mg) 

E[CH20](lb/MMBtu) = C[CH20](ppmV) CF .. Fd" (20.9/20.9-%02) 

Page 3 

Comgound Samgle Mass Concentration Concentration Concentration Mass Emission Mass EmiSsiQo 

!mg) (mg/dscm) iQQ!lllll 'pmV@Corr.%o Ob/hr) (lb/MMBtu) 

Formaldehyde 0.00530 2.32E·03 1.86E-03 1 53E-03 1.37E-03 1.76E-06 

NO NO NO NO NO NO 

9) Isokinecity, I. % I = [100*Ts*(K3*Vlc+«(Vm*Y)/Tm)*(Pb+(dH/13.6))))] I (60*t"Ps"Vs*An) 

% I = 101.61 
Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

y= 

t= 

Dn = 

An = 

Ds = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[O2[ 

[C02[ 

[N2] 

[CO] 

[THC] 

[CH4] 

AirNova, Inc. Page 1 of 3 

EPA Methods 1, 2, 3A, 4, 10, 18 and 25A 

(Flows, 02/C02, H20, CO and NMHC) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unil No.2 

04/23/10 

One 

1245-1450 

Emission Data 

252.2 cc 

80.739 dcf 

-0.45 in. H20 

29.93 in. Hg 

29.90 in. Hg 

29.92 in. Hg 

07143 in, H20 1\..5 

1.50 in. H2O 

542.3 R 

649.7 R 

527.7 R 

0.99 

120 min. 

0.253 in, 

0,000349 sq. ft. 

10.300 ft. 

83.3204 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pilot tube coefficient 

85.49 ft[(lb/lbmol)'{lnHgW.5j/[s·R·lnH201 

17.637 R/in.Hg constant 

0.047070 cu,fUml 

0.0026688 in.Hg-cf/ml-R 

9828 scf/MMBtu 

Instrumental Data 

460 %-dry 

1396 %-dry 

81.44 %-dry 

526.8 ppmV-dry 

1.7 ppmV-wet 

0.0 ppmV-dry 

constant Pilot tube constant 

constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Carbon Monoxide concentration 

Total Hydrocarbon concentration 

Methane Concentration by GC-FID 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Emission Source Unit No.2 

Test Run One 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1· Y * Vm * (Pb + dH/13 6) I Tm 

Vmstd = 78.095 dscf 

2.212 dscm 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 11.871 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1319 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44*%C02) + (32*%02) + (2B*%N2)) * (1·Bws) 1 + (18*Bws) 

Ms = 28 779 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp • (dP) • (Ts/Ps~Ms)".5 

Vs = 44.576 fps 

6) Average actual stack gas volumetric ftowrate, Qa. 

Qa = 60 sec/min * Vs • As 

Qa = 222845.4 cfm 

6311.0 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa .. (TstdlTs) .. (Ps/Pstd) .. (1-Bws) 

Qstd = 156995.7 dscfm 

4446.1 dscmm 

Page 2 of3 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cant.) 

Unit No.2 

One 

Page 3 of 3 

8) Total Hydrocarbon concentrations and emissions 

INPUT 

C[THC] dry basis = C[THC] wet/(1-Bws) 

C[VOC] dry bas;s = C[THC] - C[CH4] 

Corr. C[CH41 = «20.9-02% corf. value)/(20 9-actual avg. 02% value))"VOC value 

E[VOC] = (C(VOq"Mol W1[VOC eqUlvalent]"60(min/hr)*Qstd(dscfm»)I(Molar Vol. air*10"6) 

E[VOC Ib/MMBtu] = Cd * Fd * (20.9/(20.9-actual 02%)) 

C(THC] = 1.7 ppmVw 

C[THC[ = 2.0 ppmVd 

qCH4] = 0.0 ppmVd 

qvOC] = 2.0 ppmVd 

C(VOC] = 1.7 ppmVd corrected to 7 % 02 

Mol. Wt. [THC]= 44.096 Ib/lb-mole 

Molar vol air= 385 scf/lb-mole @ 

Propane 

68 def F 

E[VOC] = 2.11 Ib/hr 

Conv Factor. 

E[VOC] = 

4134E-08 convert ppmVto Ib/scfTHC as CH4 

1.02E-03 Ib/MMBtu 

9) Carbon Monoxide concentrations and emissions 

Corr. C(CO] = «20.9-02% corr. value)/(20.9-actual avg. 02% value»*Avg. raw CO value 

E[CO Ib/hr] = (C[CO]*Mol Wt[CO]*60{min/hr)*Qstd{dscfm))/(Molar Vol. air*10"6) 

E[CO Ib/MMBtu] = Cd" Fd * (20.9/(20.9-actual 02%)) 

qCO] = 526.8 ppmVd 

C[CO] = 449.2 ppmVd corrected to 7 % 02 

Mol. WI. [CO]= 28.01 Ib/lb-mole 

Molar vol air- 385 scf/lb-mole @ 68 def F 

E[CO] = 361.02 Ib/hr 

Conv Factor. 

E[CO] = 

7.235E-08 convert ppmV to Ib/scf CO 

0.480 Ib/MMBtu 
Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

y= 

t= 

On = 

An = 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[02] 

[CO2] 

[N2] 

[CO] 

[THC] 

[CH4] 

AirNova, Inc. Page 1 of3 

EPA Methods 1, 2, 3A, 4, 10, 18 and 25A 

(Flows, 02/C02, H20, CO and NMHC) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit NO.2 

04/23/10 

Two 

1520-1725 

Emission Data 

252.8 cc 

82.077 dcf 

-0.45 in. H20 

29.90 in. Hg 

29.87 m. Hg 

29.92 in. Hg 

0.7059 in. H20 ".5 

1.48 in. H20 

542.3 R 

650.9 R 

527.7 R 

0.99 

120 min. 

0.253 in. 

0.000349 sq ft 

10.300 ft. 

83 3204 sq. ft 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter cahbration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbllbmol)'(in Hg)]'. 5}1[ s'WinH20] 

17.637 R/in.Hg 

0.047070 cU.ft!ml 

0.0026688 in.Hg-cf/ml-R 

9676 scf/MMBtu 

Instrumental Data 

4.16 %-dry 

14.56 %-dry 

81 28 %-dry 

269.3 ppmV-dry 

0.9 ppmV-wet 

0.0 ppmV-dry 

constant 

constant 

constant 

Pitot tube constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Carbon Monoxide concentration 

Total Hydrocarbon concentration 

Methane Concentration by GC-FID 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Emission Source Unit No.2 

Test Run Two 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1" Y" Vm" (Pb + dH/13.6) I Tm 

Vmstd = 79.305 dscf 

2.246 dscm 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 ., Vic 

Vw(std) = 11.899 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.1305 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32*%02) + (28"%N2»" (1-Bws)] + (1S*Bws) 

Ms= 28 866 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp· (dP) • (TS/Ps*Ms)".5 

Vs = 44.048 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs * As 

Qa = 220206.0 cfm 

6236.2 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa· (Tstd/Ts)· (Ps/Pstd) * (1-Bws) 

Qstd = 154966.7 dscfm 

4388.7 dscmm 

Page 2 of 3 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.2 

Two 

Page 3 of 3 

8) Total Hydrocarbon concentrations and emissions 

INPUT 

CjTHC] dry basis = C[THC] wet/(1-Bws) 

CjVOC] dry basis = C{THC]- C{CH4] 

Corr. CjCH4] = «20.9-02% corr. value)f(20.9-actual avg. 02% value))"'VOC value 

E[VOC] = (CjVOC]*Mol Wt[VOC equivalenW60(min/hr)*Qstd(dscfm»f(Molar Vol. air*10116) 

E[VOC Ib/MMBtu] = Cd ... Fd ~ (20.9/(20.9-actual 02%)) 

CjTHC] = 0.9 ppmVw 

C[THC] = 1.0 ppmVd 

C[CH4] = 0.0 ppmVd 

C[VOC[ = 1.0 ppmVd 

C[VOC] = 0.9 ppmVd corrected to 

Mol. Wt. [THC]= 44.096 Ib/lb-mole 

Molar vol alr= 385 scf/lb-mole @ 

E[VOC] = 1.10 Ib/hr 

7 

Propane 

68 

Cony Factor. 

E]VOC] = 

4.134E-08 convert ppmV to Ib/scf THC as CH4 

5.17E-04Ib/MMBtu 

% 02 

def F 

9) Carbon Monoxide concentrations and emissions 

Corr. C[CO] = «20 9-02% corr. value)/(20.9-actual avg. 02% value))*Avg. raw CO value 

E[CO Ib/hr] = (C[CO]*Mol Wt[CO]*60(min/hr)*Qstd(dscfm))/(Molar Vol. air*10"6) 

E[CO Ib/MMBtu] = Cd" Fd" (20.9/(20.9-actual 02%» 

C[CO] = 269.3 ppmVd 

CjCO] = 223.6 ppmVd corrected to 7 % 02 

Mol. Wt. [CO]= 28.01 Ib/lb-mole 

Molar vol air= 

E]CO] = 

Cony Factor. 

E]CO] = 

385 scf/lb-mole @ 

182.17 Ib/hr 

7.235E-08 convert ppmV to Ib/scf CO 

0.235 Ib/MMBtu 

68 def F 
Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

y= 

t= 

Dn = 

An = 

Ds = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[O2[ 

[C02[ 

[N2[ 

[COl 

[THC[ 

[CH4[ 

AirNova, Inc_ 

EPA Methods 1, 2, 3A, 4, 10, 18 and 25A 

(Flows, 021CQ2, H20, CO and NMHC) 

Spruance Genco, LLC 

3333 

RIchmond, Virginia 

Unit No.2 

04123/10 

Three 

1803-2003 

Emission Data 

253,0 cc 

83.136 dcf 

-0.45 in, H20 

29.90 in. Hg 

29.87 in. Hg 

29.92 in Hg 

0.7183 in, H20 ".5 

1 53 in, H20 

540.0 R 

651.4 R 

527.7 R 

099 

120 min, 

0.253 in 

0,000349 sq. ft. 

10.300 ft. 

83.3204 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0,84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)' (i n Hg)[, . 5}/[ s 'R'In H20) 

17,637 R/in.Hg constant 

Page 1 of 3 

0.047070 cu.ftlml 

0,0026688 in.Hg-cf/ml-R 

9826 scf/MMBtu 

constant Pitot tube constant 

Instrumental Data 

4,03 %-dry 

14.52 %-dry 

81.45 %-dry 

480.2 ppmV-dry 

1.2 ppmV-wet 

0.0 ppmV-dry 

constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Carbon Monoxide concentration 

Total Hydrocarbon concentration 

Methane Concentration by GC-FID 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Emission Source Unit No.2 

Test Run Three 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm" (Pb + dH/13.6) I Tm 

Vmstd = 80.685 dsef 

2.285 dsem 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 ;0 Vic 

Vw(std) = 11.909 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1286 

4) Molecular weight ofthe stack gas on a wet basis, Ms. 

Ms = [((44*%C02) + (32*%02) + (28~%N2» * (1-Bws) 1 + (1S*Bws) 

Ms = 2S.879 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)".5 

Vs = 44.829 fps 

6) Average actual stack gas volumetric f1owrate, Qa. 

Oa = 60 sec/min ;0 Vs • As 

Oa = 22410S.8 efm 

6346.S cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Ostd = Oa" (TstdlTs) * (Ps/Pstd) * (1-Bws) 

Qstd = 15792S.6 dscfm 

4472.5 dscmm 

Page 2 of 3 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit NO.2 

Three 

Page 3 of 3 

8) Total Hydrocarbon concentrations and emissions 

INPUT 

C[THCJ dry basis = C[THCJ wet/(1-Bws) 

C[VOG] dry basis = C[THG] - CiCH4] 

Corr. C[CH4] = ((20.9-02% carr. value)/(20.9-actual avg. 02% value))*VOC value 

E[VOCJ = (C[VOC]*Mol Wt[VOC equivalent]*60(min/hr)*Qstd(dscfm»/(Molar Vol. air~10A6) 

E[VOC Ib/MMBtu] = Cd * Fd .. (20.9/(20.9-actual 02%» 

G]THC] = 1.2 ppmVw 

C[THCJ = 1.4 ppmVd 

CiCH4] = 0.0 ppmVd 

C[VOC] = 1.4 ppmVd 

C[VOC] = 1.1 ppmVd corrected to 7 % 02 

Mol. Wt. [THCJ= 44.096 Ib/lb-mole 

Molar vol air= 

E[VOG] = 

Conv Factor. 

E[VOG] = 

385 scf/lb-mole @ 

1,49 Ib/hr 

Propane 

68 def F 

4.134E-08 convert ppmV to Ib/scf THC as CH4 

6.93E-04 Ib/MMBtu 

9) Carbon Monoxide concentrations and emissions 

Corr. C[CO] = ((20.9-02% corr. value)/(20.9-actual avg. 02% value»*Avg. raw CO value 

E[CO Ib/hr] = (C[CO]*Mol Wt[CO]*60(min/hr)*Qstd(dscfm»/(Molar Vol. air"10"6) 

E[CO Ib/MMBtu] = Cd" Fd" (20.9/(20.9-actual 02%» 

qCO] = 4802 ppmVd 

C[CO] = 395.7 ppmVd corrected to 7 % 02 

Mol. Wt. [CO]= 28.01 Ib/lb-mole 

Molar vol air= 

E[CO] = 

Conv Factor. 

E[CO] = 

385 scf/lb-mole @ 

331.04 Ib/hr 

7.23SE-08 convert ppmV to Ib/scf CO 

0.423 Ib/MMBtu 

68 def F 
3333-SSVOH-R1 AirNova, Inc. 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

EPA Methods 1 ,2,3A,4 and 0010 with SW-846 Method 82700 

(Flows, 02/C02, H20, Speciated Semivolatile Organic HAPs and PAHs) 

Vlc= 

Vm= 

Pstatlc '" 

Pb· 

Ps = 

Pstd = 

dP = 

dH· 

Tm= 

Ts= 

Tstd= 

Dn = 

An = 

y. 

, . 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

1021 

IC021 

IN21 

Spruance Genco, LLC 

3333 

Unit No.2 

Doe 

04123/10 

1245-1450 

Emission Data 

2367 cc 

78.05 dcf 

-0.45 in. H20 

29.93 in. Hg 

29.90 in. Hg 

29.92 in. Hg 

0.7133 in. H20 ".5 

1.389 111. H20 

534.2 R 

652.3 R 

527.7 R 

0.248 in. 

0.000335 sq. ft. 

1.01 

120 min. 

10.300 ft. 

83.3204 sq. ft 

0.84 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter cailbration factor 

Duration of sampling time 

Diameter of stack 

Cross sectional area of stack 

Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]" .5}/[s*R*inH20] Pltot tube constant 

17.637 R/in.Hg constant 

0.047070 cu.ftlml constant 

0.0026688 in.Hg-cf/ml-R 

9828 scf/MMBtu 

Instrumental Data 

4.60 %-dry 

13.96 %-dry 

81.44 %-dry 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruanee Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1 ~ Y * Vm * (Pb + dH/13.6) / Tm 

Vmstd = 78.157 dscf 

2.21 dscm 

Unit No.2 

Doe 

2) Volume of water vapor collected at standard conditIons, Vw(stcl). 

Vw(std) = K2 ., Vic 

Vw(std)= 11.141 sef 

3) Decimal fraction of moisture by volume in stack gas, 8ws. 

8ws = Vwstd / (Vmstd+Vwstd) 

8ws = 0.125 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32*%02) + (28*%N2» * (1-Bws) 1 + (18*Bws) 

Ms= 28.87 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp • (dP) * (Ts/Ps*Ms)".5 

Vs = 44.53 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min" Vs ., As 

Oa = 222605.6 cfm 

6304.2 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa * (Tstdrrs) * (Ps/Pstd) * (1-Bws) 

Qstd = 157498.3 dscfm 

4460.4 dscmm 

Page 2 
Client Spruance Genco, llC Test Location Unit No, 2 Page 3 

Project No. 3333 Test Run One 

Calculations (cont.) 

8) Speciated Semivolatile Organic HAPs - Concentrations and Emissions 

qSSVOH] = M[SSVOH](ug) I Vmstd(dscm) 

C[SSVOH](lb/dscf):: C[SSVOH](ug/dscm)· 1e-06g/ug" 2,20Se-03Ib/g" 0.02832 dscm/dscf 

E[SSVOH](lb/hr) = C[SSVOH](ug/dscm) * Qstd(dscmm) • (2.20SE-09)(lb/ug)" 60(min/hr) 

E[SSVOH](lb/MMBtu) = C[SSVOH](lb/dscf) • Fd .. (20.9/20.9-%02) 

C[SSVOH](@ corr. 02) = C[SSVOH] (ug/dscm);O; {(20.9-corrected %02) 1 (20.9-actual %02)] 

Corrected 02 percentage is: 70 % 

SSVOH Sam(;lle Conc. Conc.@ooIT Q2 Conc. Emission Rate Emission Rate 

Analvte Mass (ug) (ug/dscm) (ug/dscm) (Ib/dscfl Clb/hr) (lb/MMBtu) 

Acenaphthene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Acenaphthylene 0.00 0.00 0.000 O.OOE+OO O,OOE+OO O.OOE+OO 

Acetophenone 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Aniline 000 0.000 0.000 O.OOE+OO O,OOE+OO O.OOE+OO 

Anthracene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzidine 0.00 0,000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(a)anthracene 0.00 0.000 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(b)fluoranthene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(k)fluoranthene 0.00 0.000 0.000 O.OOE+OO O,OOE+OO O.OOE+OO 

Benzoic Acid 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(g, h, i)peryJene 0.00 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(a)pyrene 0.00 0.00 0.000 O.OOE+OO O,OOE+OO O.OOE+OO 

Benzyl Alcohol 0.00 0.00 0.000 O,OOE+OO O,OOE+OO O.OOE+OO 

bis (2-Chloroethyl) ether 000 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

bis (2-Ethylhexyl) phthalate 0.00 0.00 0_000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Bromophenyl phenyl ether 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Butyl benzyl phthalate 0.00 0,000 0.000 O,OOE+OO O.OOE+OO O.OOE+OO 

Carbazole 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Chloroaniline 0.00 0.00 0000 O.OOE+OO O.OOE+OO O,OOE+OO 

4-Chloro-3-methylphenol 0.00 0.00 0.000 O,OOE+OO O.OOE+OO O.OOE+OO 

2-Chloronaphthalene 0.00 0.00 0.000 O,OOE+OO O.OOE+OO O.OOE+OO 

2-Chlorophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Chlorophenyl phenyl ether 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 

Chrysene 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 

Dibenzo(a,h)anthracene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Dibenzofuran 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Di-n-butyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,2-Dichlorobenzene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,3-Dichlorobenzene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,4-Dichlorobenzene 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

3,3-Dichlorobenzidine 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,4-Dichlorophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Diethyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,4-Dimethylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Dimethyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4,6-Dinitro-2-methylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 
Client Spruance Genco, LLC Test Location Unit No.2 Page 4 

Project No. 3333 Test Run Ooe 

Calculations (cont.) 

SSVOH Saml2le Conc. Conc.@!;;Qrr. Q2 Conc. Emission Rate Emission Rate 

Analyte Mass (ug) (ug/dscm) (ug/dscm) (Ib/dscf) (lbfhr) (lb/MMBtu) 

2,4-Dinitrophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,4-Dinitrotoluene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,6-Dinitrotoluene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Di-n-octyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,2-Diphenylhydrazine 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Fluoranthene 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Fluorene 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Hexachlorobenzene 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Hexachlorobutadiene 000 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Hexachlorocyclopentadiene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Hexachloroethane 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Indeno(1,2,3-c,d)pyrene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Isophorone 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Methylnaphthalene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Methylphenol 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

3 & 4-Methylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Naphthalene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Nitroaniline 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

3-Nitroaniline 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Nitroamline 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Nitrobenzene 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Nitrophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Nitrophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

N-NitfOsodimethylamlne 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

N-NitfOsodlphenylamine 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

N-Nitrosodi-n-propylamine 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Pentachlorobenzene 0.00 0.00 0.000 O.OOE+OO o OOE+OO O.OOE+OO 

Pentachloronitrobenzene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Pentachlorophenol 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Phenanthrene 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Phenol 0.00 000 0.000 O.OOE+OO o OOE+OO O.OOE+OO 

2,2'-oxybis (1-Chloropropane) 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Pyrene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Pyridine 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,2,4-Trichlorobenzene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,4,5-Trichlorophenol 0.00 0.00 0.000 O.OOE+OO o OOE+OO O.OOE+OO 

2,4,6-Trichlorophenol 0.00 0.00 0.000 O.OOE+OO o OOE+OO O.OOE+OO 

Total SSVOHs 0.000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 
Client 

Project No. 

Spruance Genco, LLC 

3333 

9) PAH Concentrations and Emissions 

Test Location 

Test Run 

Calculations (cant.) 

C[PAH] = M[PAH]{ug) I Vmstd(dscm) 

Unit No.2 

One 

C[PAH](lb/dscf) = C[PAH]{ug/dscm) ·1e-06g/ug· 2.205e-03Ib/g· 0.02832 dscm/dscf 

E[PAH](lb/hr) = C[PAH]{ug/dscm) • Qstd(dscmm) .,. (2.205E-09)(lb/ug) * 60(min/hr) 

E[PAH](lb/MMBtu) = C[PAH](lb/dscf) * Fd * (20.9/20.9-%02) 

C[PAH](@ corr. 02) '" C[PAH] (ug/dscm) * [ (20.9-corrected %02) 1 (20.9-aclual %02) ] 

Corrected 02 percentage is: 7.0 % 

PAH Sample Cone. Conc.@corr. 02 Conc. Emission Ral.fl: 

Analyte Mass (ug) (ug/dscm) (ug/dscm) (Ib/dscfl (Iblhrl 

Acenaphthene 0.00860 0.00 0.003 2.43E-13 229E-06 

Acenaphthylene 000730 0.00 0.003 2.06E-13 1.9SE-06 

Anthracene 0.00000 0.00 0.000 O.OOE+OO O.OOE+OO 

8enzo(a)anthracene 0.00200 0001 0.001 564E-14 5.33E-07 

Benzo(b)fluoranlhene 0.00500 0002 0.002 1.41E-13 1.33E-06 

Benzo(k)fluoranthene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Benzo(g,h,i)perylene 0.00110 0.000 0.000 3.10E-14 2.93E-07 

Benzo(a)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Benzo(e)pyrene 0.00590 0.003 0.002 166E-13 1.57E-06 

Chrysene 0.00780 0.004 0.003 2.20E-13 2.08E-06 

Dibenzo(a,h)anlhracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Fluoranthene 0.01100 0.00 0.004 3.10E-13 2.93E-06 

Fluorene 0.01400 001 0.005 3.95E-13 3.73E-06 

Indeno(1,2,3-c,d)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

2-Melhylnaphthalene 0.24100 0.11 0.093 6.80E-12 6.43E-05 

Naphthalene 0.56000 0.25 0.216 1 58E-11 1 49E-04 

Perylene 000000 0.000 0.000 O.OOE+OO O.OOE+OO 

Phenanthrene 000000 0.00 0.000 O.OOE+OO O.OOE+OO 

Pyrene 0.00000 0.00 0.000 O.OOE+OO O.OOE+OO 

Total PAHs 0.8637 0.021 0.018 128E-12 2.30E-04 

10) Isokinecity, I. 

% I '" [100*Ts*(K3*Vlc+«(Vm*Y)fTm)*(Pb+(dH/13.6))))] I (60*t·Ps*Vs*An) 

% I = 102.72 

Page 5 

Emission Rate 

Clb/MMBtu) 

3.06E-09 

260E-09 

O.OOE·~OO 

7.11E-10 

1.78E-09 

O.OOE+OO 

391E-10 

O.OOE+OO 

2 10E-09 

2.77E-09 

O.OOE+OO 

391 E-09 

498E-09 

O.OOE+OO 

8.S7E-08 

1.99E-07 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

3.07E-07 
3333-SSVOH-R2 AirNova, Inc. 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

EPA Methods 1,2,3A,4 and 0010 with SW-846 Method 82700 

(Flows, 02/C02, H20, Speciated Semivolatile Organic HAPs and PAHs) 

Vic = 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts= 

Tsld= 

On = 

An = 

y= 

t= 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

1021 

IC02] 

IN2] 

Spruance Genco, LLC 

3333 

Unit No.2 

Two 

04/23/10 

1525-1730 

Emission Data 

238.1 cc 

77.03 dcf 

-OA5 in. H20 

29.9 In. Hg 

29.87 in. Hg 

29.92 in. Hg 

06968 in. H20 ".5 

1.325 In. H20 

536.0 R 

651.5 R 

527.7 R 

0.248 in. 

0.000335 sq. ft. 

1.01 

120 min. 

10.300 ft. 

83.3204 sq_ ft 

0.84 

Vol. of H20 collected 

Dry gas meier reading 

Static pressure 

Barometnc pressure 

Stack pressure 

EPA Standard pressure 

Average sq_rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

Cross sectional area of stack 

Pilot tube coefficient 

85A9 ft[(lb/lbmol)*{inHg)]".5}/[s"R*inH20] Pitot tube constant 

17_637 R/in.Hg constant 

0.047070 cu.ft!ml constant 

0.0026688 in.Hg-cf/ml-R 

9676 scf/MMBlu 

Instrumental Data 

4.16 %-dry 

14.56 %-dry 

81.28 %-dry 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =Kl* Y * Vm * (Pb + dH/13.6) I Tm 

Vmstd = 76.801 dscf 

2.18 dscm 

Unit No.2 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 '" Vic 

Vw(std) = 11.207 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.127 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = ((44*%C02) + (32"%02) + (28~%N2» '" (1.Bws) 1 + (18*Bws) 

Ms= 28.90 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp '" Cp '" (dP) * (Ts/Ps*Ms)".5 

Vs= 43.47 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min'" Vs '" As 

Qa = 217302.3 cfm 

6154.0 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa '" (TSldfTs) * (Ps/Pstd) * (l-Bws) 

Qstd = 153335.3 dscfm 

4342.5 dscmm 

Page 2 
Client Spruance Genco, LLC Test Location Unit No, 2 Page 3 

Project No. 3333 Test Run Two 

Calculations (cont.) 

8) Speciated Semivolatile Organic HAPs - Concentrations and Emissions 

qSSVOH] = M[SSVOH](ug) I Vmstd(dscm) 

qS8VDH](lb/dscf) = qSSVOH](ug/dscm) ~ 1e-06g/ug'" 2.205e-03Ib/g '" 0,02832 dscm/dscf 

E[SSVOH](lb/hr) = qSSVOH](ug/dscm) * Qstd(dscmm) * (2.205E-09)(lb/ug) ·60(min/hr) 

E[SSVDH](lb/MMBtu) = qSSVOH](lb/dscf) * Fd ~ (20.9/20.9-%02) 

qSSVOH](@corr. 02) = qSSVOH] (ug/dscm) • [(20.9-corrected %02) I (20 9-actual %02) ] 

Corrected 02 percentage is: 7.0 % 

SSVOH Sam!;!le Conc. Canc.@corr. 02 Conc. Emission Rate Emission Rate 

Analyte Mass Cug) (ug/dscm) (uqtdscm) (Ib/dscf) (lb/hr) Clb/MMBtu) 

Acenaphthene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Acenaphthylene 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Acetophenone 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Aniline 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Anthracene 0,00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzidine 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(a)anthracene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(b)f1uoranthene 0.00 0000 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(k)f1uoranthene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzoic Acid 0,00 0.000 0.000 O,OOE+OO O.OOE+OO O.OOE+OO 

Benzo(g, h, i)perylene 0.00 0,000 0000 O.OOE+OO O,OOE+OO O.OOE+OO 

Benzo(a)pyrene 0.00 0.00 0,000 O,OOE+OO O.OOE+OO O.OOE+OO 

Benzyl Alcohol 0,00 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 

bis (2-Chloroethyl) ether 000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

bis (2-Ethylhexyl) phthalate 0.00 0.00 0,000 o OOE+OO O.OOE+OO O.OOE+OO 

4-Bromophenyl phenyl ether 000 0.00 0.000 o OOE+OO O.OOE+OO O.OOE+OO 

Butyl benzyl phthalate 000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Carbazole 0.00 0.00 0.000 O,OOE+OO O.OOHOO O.OOE+OO 

4-Chloroanilme 000 0.00 0.000 O,OOE+OO O.OOE+OO O.OOE+OO 

4-Chloro-3-methylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Chloronaphthalene 000 0.00 0.000 O,OOE+OO O.OOE+OO O.OOE+OO 

2-Chlorophenol 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Chlorophenyl phenyl ether 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Chrysene 0.00 0,00 0.000 O.OOE+OO O,OOE+OO O.OOE+OO 

Dibenzo(a.h)anthracene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Dibenzofuran 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O,OOE+OO 

Di-n-butyl phthalate 000 0.00 0.000 O.OOE+OO O.OOE+OO O,OOE+OO 

1,2-Dichlorobenzene 000 0,00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,3-Dichlorobenzene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,4-Dichlorobenzene 000 0.00 0.000 O,OOE+OO O.OOE+OO O.OOE+OO 

3,3-Dichlorobenzidine 000 0.00 0.000 O.OOE+OO O.OOE+OO O,OOE+OO 

2,4-Dichlorophenol 0.00 000 0.000 O.OOE+OO O,OOE+OO O.OOE+OO 

Diethyl phthalate 0.00 000 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,4-Dimethylphenol 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Dimethyl phthalate 0.00 000 0.000 O,OOE+OO O.OOE+OO o OOE+OO 

4.6-Dinitro-2-methylphenol 000 0.00 0.000 Q,OOE+OO O.OOE+OO o OOE+OO 
Client Spruance Genco, LLC Test Location Unit No, 2 Page 4 

Project No, 3333 Test Run Two 

Calculations (cont.) 

SSVOH Sample Cone, Qonc,@corr, 02 Cone. Emission Rate Emission Rate 

Analyte Mass (ug) (ug/dscm) (ug/dscm) (lb/dscO (Ib/hrl (lb/MMBtu) 

2,4-0initrophenol 0.00 0,00 0.000 O.OOE+OO O.OOE+OO O,OOE+OO 

2,4-0initrotoluene 000 0,00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 

2,6-0Imtrotoluene 0.00 0.00 0.000 O,OOE+OO O,OOE+OO O.OOE+OO 

Di-n-octyl phthalate 0.00 0,00 0,000 O.OOE+OO O.OOE+OO O,OOE+OO 

1,2"Diphenylhydrazine 0,00 0.00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 

Fluoranthene 0.00 0.00 0.000 O,OOE+OO O,OOE+OO O.OOE+OO 

Fluorene 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 

Hexachlorobenzene 0.00 0.00 0.000 o OOE+OO O,OOE+OO O,OOE+OO 

Hexachlorobuladiene 0,00 0.00 0.000 o OOE+OO O,OOE+OO O,OOE+OO 

Hexachlorocyclopentadiene 0,00 0.00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 

Hexachloroethane 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Indeno{1,2,3-c,d)pyrene 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Isophorone 0.00 0,00 0.000 O.OOE+OO O.OOE+OO O,OOE+OO 

2-Melhylnaphthalene 0,00 0.00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 

2-Methylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

3 & 4-Methylphenol 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 

Naphthalene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Nitroaniline 0,00 0,00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 

3-Nitroaniline 0.00 0.00 0.000 O,OOE+OO O,OOE+OO O.OOE+OO 

4-Nitroaniline 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 

Nitrobenzene 000 0,00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 

2-Nitrophenol 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Nitrophenol 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 

N-Nitrosodimethylamine 0.00 0,00 0.000 O.OOE+OO O.OOE+OO O,OOE+OO 

N-Nilrosodiphenylamine 0,00 0,00 0.000 O.OOE+OO O,OOE+OO O,OOE+OO 

N-Nltrosodi-n-propylamine 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O,OOE+OO 

Pentachlorobenzene 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Pentachloronitrobenzene 0.00 0,00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Pentachlorophenol 0,00 000 0.000 O.OOE+OO O,OOE+OO O,OOE+OO 

Phenanthrene 0.00 000 0.000 O.OOE+OO O,OOE+OO O,OOE+OO 

Phenol 0.00 000 0.000 O.OOE+OO O,OOE+OO O,OOE+OO 

2,2'-oxybis (1-Chroropropane) 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 

pyrene 0.00 0,00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Pyridine 000 0.00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 

1,2,4-Trichlorobenzene 0.00 0.00 0.000 O,OOE+OO O,OOE+OO O,OOE+OO 

2,4,5-Trichlorophenol 0.00 0.00 0,000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,4,6-Tnchloropbenol 0,00 0,00 0.000 O.OOE+OO O,OOE+OO O,OOE+OO 

Total SSVOHs 0000 0.000 0.000 O,OOE+OO O,OOE+OO O.OOE+OO 
Client 

Project No. 

Spruance Genco. llC 

3333 

9) PAH Concentrations and Emissions 

Test Location 

Test Run 

Calculations (cant.) 

C[PAH] = M[PAH](ug) I Vmstd(dscm) 

Unit No 2 

Two 

C[PAH](Ib/dscf) = C[PAH](ug/dscm) '* 1e-06g/ug '* 2.205e-03Ib/g * 0.02832 dscm/dscf 

E[PAH](Ib/hr) = C[PAH](ug/dscm) '* Qstd(dscmm) .. (2.20SE-09)(lb/ug) .. 60{min/hr) 

E[PAH]{Ib/MMBtu) = C[PAH](lb/dscf) '* Fd ,. (20.9/20 9-%02) 

C[PAH]{@corr. 02) = C[PAH] (ug/dscm) ,. [ (20.9-corrected %02) I (20.9-actual %02) ] 

Corrected 02 percentage is: 7.0 % 

PAH Sample Conc. COrlQ_@QQrr. Q2 Conc. Emission Rate 

Analyte Mass (ugl (ug/dscm) (ug/dscml Clb/dscO (Ib/hr) 

Acenaphthene 0.00700 0.00 0.003 2.01E-13 1.8SE-06 

Acenaphthylene 0.00180 0.00 0.001 S.17E-14 4.7SE-07 

Anthracene 0.00000 0.00 0.000 O.OOE+OO O.OOE+OO 

Benzo(a)anthracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Benzo{b)fluoranthene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Benzo(k)fluoranthene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Benzo(g.h.i)perylene 000000 0.000 0.000 O.OOE+OO O.OOE+OO 

Benzo{a)pyrene 000000 0.000 0.000 O.OOE+OO O.OOE+OO 

Benzo(e)pyrene 000000 0.000 0.000 O.OOE+OO O.OOE+OO 

Chrysene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Dibenzo(a,h)anthracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO 

Fluoranthene 0.00650 0.00 0.002 1 87E-13 1.72E-06 

Fluorene 0.01000 0.00 0.004 2.B7E-13 2.64E-06 

Indeno(1,2,3-c,d)pyrene 0.00000 0.000 0000 O.OOE+OO O.OOE+OO 

2-Methylnaphthalene 0.11000 0.05 0.042 3.16E-12 2.91E-OS 

Naphthalene 0.35500 0.16 0.136 1 02E-11 9.38E-05 

Perylene 0.00000 0.000 0000 O.OOE+OO O.OOE+OO 

Phenanthrene 0.03300 0.02 0013 9.47E-13 8.72E-06 

Pyrene 000000 0.00 0.000 O.OOE+OO O.OOE+OO 

Total PAHs 0.5233 0.013 0.011 7.91E-13 1.38E-04 

10) leokinecity, I. 

% I = [100"Ts*(K3'·Vlc+{{(Vm*y)fTmt(Pb+{dH/13.6»)))] I (60*I*Ps"Vs"An) 

% I = 103.68 

Page 5 

Emission Rate 

(lb/MMBtu) 

2.43E-09 

6.24E-10 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

O.OOE+OO 

2.2SE-09 

3A7E-09 

O.OOE+OO 

3.B2E-08 

1.23E-07 

O.OOE+OO 

1.14E-08 

O.OOE+OO 

1.82E-07 
3333-SSVOH-R3 AirNoV8, Inc. 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

EPA Methods 1,2,3A,4 and 0010 with SW-84S Method 82700 

(Flows, 02fC02, H20, Speciated SemivolatJIe Organic HAPs and PAHs) 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

Dn = 

An = 

y= 

t = 

Ds = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[02] 

[C02] 

[N2] 

Spruance Genco. LLC 

3333 

Unit No.2 

Three 

04123f10 

1808-2018 

Emission Data 

245,9 cc 

77.869 def 

-0.45 in, H20 

299 in. Hg 

29.87 in. Hg 

29.92 il1. Hg 

0.7192 in. H20 ".5 

1,410 in. H20 

536.8 R 

652.3 R 

527.7 R 

0.248 in. 

0.000335 sq, ft, 

1.01 

120 min. 

10,300 ft 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meier calibration factor 

Duralion of sampling time 

Diameter of stack 

833204 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]" .5}f[s*R*inH20] Pltot tube constant 

17,637 R/in,Hg constant 

0.047070 cu.ftlml 

0_0026688 in.Hg-cf/ml-R 

9826 scf/MMBtu 

Instrumental Data 

4.03 %-dry 

14.52 %-dry 

81.45 %-dry 

constant 

conslant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentralion 

Nilrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm * (Pb + dH/13.6) I Tm 

Vmstd = 77.533 dsef 

2.20 dsem 

Unit No.2 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 • Vic 

Vw{std) = 11.574 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.130 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44*%C02) + (32*%02) + (28*~/oN2» * (1-Bws)] + (18*Bws) 

Ms= 28.86 rb/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp • Cp· (dP) • (Ts/Ps·Ms)".5 

Vs = 44.92 fps 

6) Average actual stack gas volumetric flowrate, 03, 

Oa = 60 sec/mm ,. Vs * As 

Qa = 224585.8 cfm 

63603 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Oa * (TstdfTs)· (Ps/Pstd)· (1-Bws) 

Qstd = 157809.9 dscfm 

4469.2 dscmm 

Page 2 
Client Spruance Genco, LLC Test Location Unit No.2 Page 3 

Project No. 3333 Test Run Three 

Calculations (cont.) 

8) Speciated Semivolatile Organic HAPs - Concentrations and Emissions 

C[SSVOH] = M[SSVOH](ug) I Vmstd{dscm) 

C[SSVOH]{lb/dscf) = C[SSVOH](ug/dscm) ~ 1e-06g/ug * 2.205e-03Ib/g * 0.02832 dscm/dscf 

E[SSVOHJ(lb/hr) = C[SSVOH](ug/dscm) • Qstd(dscmm) • (2.20SE-09)(lb/ug) ·60(minlhr) 

E[SSVOH](Ib/MMBtu) = C[SSVOH](lb/dscf) ;0 Fd "(209/20.9-%02) 

C[SSVOH](@ corr. 02) = C[SSVOH] (ug/dscm) • [ (20.9-corrected %02) 1 (20.9-actual %02) ] 

Corrected 02 percentage is: 7.0 % 

SSVOH Sam(;lle Conc. Conc.@corr. 02 Conc. Emission Rate Emission Rate 

Analyte Mass (ug) (uq/dscm) (ug/dscm) Clb/dscf) (Ib/hr) (lb/MMBtu) 

Acenaphthene 0.00 0.00 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Acenaphthylene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO o OOE+OO 

Acetophenone 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Amline 0.00 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Anthracene 0.00 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzidine 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(a)anthracene 0.00 0.000 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(b)f1uoranthene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(k)f1uoranthene 0.00 0.000 0000 O.OOE+OO o OOE+OO O.OOE+OO 

Benzoic Acid 000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo{g,h,i)perylene 0.00 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo(a)pyrene 0.00 0.00 0000 O.OOE+OO o OOE+OO O.OOE+OO 

Benzyl Alcohol 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

bis (2-Chloroethyl) ether 000 0.000 0.000 O.OOE+OO O.OOE+OO o OOE+OO 

bis (2-Ethylhexyl) phthalate 6.S0 296 2439 1.85E-10 1.75E-03 2.2SE-06 

4-Bromophenyl phenyl ether 0.00 000 0000 O.OOE+OO O.OOE+OO O.OOE+OO 

Butyl benzyl phthalate 000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Carbazole 000 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Chloroanitine 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Chloro-3-methylphenol 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Chloronaphlhalene 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Chlorophenol 000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4-Chlorophenyl phenyl ether 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Chrysene 0.00 000 0.000 O.OOE+OO o OOE+OO O.OOE+OO 

Dlbenzo(a,h)anthracene 0.00 000 0.000 O.OOE+OO o OOE+OO O.OOE+OO 

Dibenzofuran 0.00 000 0000 O.OOE+OO o OOE+OO O.OOE+OO 

Di-n-butyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,2-Dichlorobenzene 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,3-Dichlorobenzene 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

1,4-Dichlorobenzene 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

3,3-Dichlorobenzidine 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,4-Dichlorophenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Diethyl phthalate 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2,4-Dimethylphenol 0.00 000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Dimethyl phthalate 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

4,6-Dinitro-2-methylphenol 0.00 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 
Client 

Project No. 

Spruance Genco. LLC 

3333 

SSVOH Sample 

Analyte Mass lug) 

2,4-Dinitrophenol 000 

2,4-Dinitrotoluene 000 

2,6-Dinilrololuene 0.00 

Di-n-oclyl phthalate 0.00 

1,2-Diphenylhydrazine 0.00 

FILIoranlhene 0.00 

Fluorene 0.00 

Hexachlorobenzene 0.00 

Hexachlorobuladiene 0.00 

Hexachlorocyclopentadiene 0.00 

Hexachloroethane 0.00 

Indeno{1.2.3-c,d)pyrene 0.00 

Isophorone 0.00 

2-Methylnaphthalene 0.00 

2-Melhylphenol 0_00 

3 & 4-Methylphenol 0.00 

Naphthalene 0 00 

2-Nitroamline 0 00 

3-Nilroaniline 0.00 

4-Nftroamline 000 

Nitrobenzene 000 

2-Nitrophenol 0.00 

4-Nitrophenol 000 

N-Nitrosodimelhylamine 000 

N-Nitrosodiphenylamine 0.00 

N-Nitrosodi-n-propylamlne 0.00 

Pentachlorobenzene 000 

Pentachloronitrobenzene 0.00 

Pentachlorophenol 0.00 

Phenanthrene 0.00 

Phenol 0.00 

2.2'-oxybis (1-Chloropropane) 0.00 

Pyrene 0.00 

Pyridine 0.00 

1,2,4-Trichlorobenzene 0.00 

2,4,S-Trichlorophenol 0.00 

2.4.6-Tflchlorophenol 000 

Total SSVOHs 6.S00 

Test Location 

Test Run 

Calculations (cont.) 

Conc. 

(uq/dscm) 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.038 

Unit No.2 

Three 

CQnc.@corr. 02 Cone. 

(ug/dscm) (Ib/dscf) 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOHOO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0000 O.OOE+OO 

0000 O.OOE+OO 

0.000 O.OOE+OO 

0000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOHOO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.000 O.OOE+OO 

0.032 2.46E·12 

Page 4 

Emission Rate Emission Rate 

(Ib/hr) (lb/MMBlu) 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO OOOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO OOOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

O.OOE+OO O.OOE+OO 

o OOE+OO O.OOE+OO 

1.7SE-03 2.2SE-06 
Client Spruance Genco, LLC Test Location Unit No.2 PageS 

Project No. 3333 Test Run Three 

Calculations (cont.) 

9) PAH Concentrations and Emissions 

C[PAH] = M[PAH](ug) I Vmstd{dscm) 

C[PAH]{lb/dscf) = C[PAH]{ug/dscm);O 1e-OBg/ug" 2.205e-03Ib/g" 0.02832 dscm/dscf 

E[PAH]{lblhr) = C[PAH]{ug/dscm) .. Qstd{dscmm) • (2.205E-09){lb/ug) .. 60{mm/hr) 

E[PAH]{lb/MMBtu) = C[PAH]{lb/dscf) .. Fd • (20.9120.9-%02) 

C[PAH]{@ corr. 02) = C[PAH1 (ug/dscm) .. [ (20.9-corrected %02) I (20.9-actual %02)] 

Corrected 02 percentage is: 70 % 

PAH Sample Cone. Conc.@gQrr. 02 Cone. Emission Rate EmissIon Bat!';!: 

Analyte Mass (U9) (ug/dscm) (ug/dscm) (lb/dscf) (Ib/hr) (lb/MMBlu) 

Acenaphthene 0.00530 0.00 0002 1.S1E-13 1.43E-06 1.83E-09 

Acenaphthylene 0.00200 0.00 0001 S.69E-14 5.39E-07 6.92E-10 

Anthracene 0.00000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo{a)anthracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo{b)fluoranthene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo{k)f1uoranthene 000000 0.000 0000 O.OOE+OO O.OOE+OO o OOE+OO 

Benzo{g, h, i) perylene 000000 0.000 0.000 O.OOE+OO O.OOE+OO o OOE+OO 

Benzo{a)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Benzo{e)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Chrysene o 00S82 0.003 0.002 1.66E-13 1.57E-06 2.01 E-09 

Dibenzo{a,h)anthracene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Fluoranthene 0.01090 0.00 0.004 3.10E-13 294E-06 3.77E-09 

Fluorene 0.00750 0.00 0.003 2.13E-13 2.02E-06 2.60E-09 

Indeno{1,2,3-c,d)pyrene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

2-Methylnaphthalene 010100 O.OS 0.038 2.B7E-12 2.72E-OS 3.50E-OB 

Naphthalene 0.24000 0.11 0.090 6.B3E-12 6A6E-OS B.31E-OS 

Perylene 0.00000 0.000 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Phenanthrene 0.02700 0.01 0.010 768E-13 7.27E-06 9.3SE-09 

pyrene 0.00000 0.00 0.000 O.OOE+OO O.OOE+OO O.OOE+OO 

Total PAHs 0.3995 0.010 O.OOB 5.9BE-13 1.08E-04 1.3BE-07 

10) Isokinecity, I. 

% I = [100*Ts*{K3*Vlc+({(Vm"Y)fTm)*{Pb+{dH/13 6»)))]1 (60*t·Ps*Vs·An) 

%1= 10170 
3333-VOST-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vm= 

Pslatic = 

Pb= 

Ps = 

Pstd = 

Tm = 

Ts = 

Tstd= 

y= 

t= 

Ds= 

As= 

Kp= 

K1 = 

K2 :: 

K3 = 

Fd = 

[02[ 

[C02[ 

[N2] 

AirNova, Inc. 

EPA Method 1, 2, 3A and 0031JSW-848 Method 82808 

(Flows, 02/C02, and Speciated Volatile Organic HAPs) 

Spruance Genco, LLC 

3333 

Unit No.2 

One 

04/23/10 

1245-1445 

1.125 

-0.45 

29.93 

29.90 

Emission Data 

dcf 

in. H2O 

in. H9 

in. H9 

29.92 in. H9 

551.5 R 

652.3 R 

527.7 R 

1.000 

90 min. 

10.300 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83.3204 sq. ft. Cross sectional area of stack 

85.49 ft[(lb/lbmolt(InHg)]".5}/{s*R*inI-l20] 

17.637 Rfin.Hg 

0.047070 cu.ft/ml 

0.0026688 in.Hg-cf/ml-R 

9828 scf/MMBtu 

tnstrumental Data 

4.60 %-dry 

13.96 %-dry 

81.44 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm * Pbl Tm 

Vmstd = 1.077 dscf 

0.0305 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws = 

Bws = 

Based on the SSVOH sampling train 

0.1250 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No.2 

One 

Ms = ( «44*%C02) + (32"%02) + (2B*%N2» * (1-Bws) I + (1B*Bws) 

Ms = 28-865 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs = 

Vs = 

Based on the SSVOH sampling train 

44.460 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min ~ Vs" As 

Oa = 222265.59 cfm 

6294.56 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa .. (TstdlTs)" (Ps/Pstd) .. (1-Bws) 

Qstd = 157211.66 dscfm 

4452.23 dscmm 

Page 2 
Client Spruance Genco, LLC Test Location Unit No.2 Page 3 

Project No. 3333 Test Run O,e 

Calculations (cont.) 

8) Speciated Volatile Organic HAPs - Concentrations and Emission Rates 

C[SVOH] = M[SVOH] (ug) J Vmstd (dscm) 

C[SVOH](lbJdscf) = C[SVOH](ugldscm) ""1e-06gJug * 2.205e-03Ib/g· 0.02832 dscm/dscf 

E[SVOH](lb/hr) = C[SVOH] (ug/dscm) ~ (2.205E-09) (Ib/ug) • Qstd (dscmm) ·60 (min/hr) 

E[SVOH](lb/MMBtu) = C[SVOH](lbJdscf)· Fd * (20.9/20.9-%02) 

C[SVOH](@corr. 02) = C[SVOHj (ugJdscm) * [(20 9-corrected %02) I (20.9-actual %02) ] 

Corrected 02 percentage is: 70 % 

Conc. Conc_@>;:Qrr. 02 Conc. Emission Rats/: Emission Rate 

Compound (ug/dscm) (ug/dscm) (Ibfdscf) (lbfhrl (lb/MMBtu) 

Acetone 748.116 637.964 4.67E-08 4.41E-Oi 5.887E-04 

Benzene 5.376 4.584 3.36E-10 3.17E-03 4.230E-OB 

Bromobenzene 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Bromochloromethane 1.858 1.585 UBE-i0 1,09E-03 1.4B2E-OB 

Bromodichloromethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Bromoform 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Bromomethane 3.840 3.275 2.40E-i0 2.2BE-03 3.022E-OB 

2-Butanone 14.210 12,118 8.87E-10 8.37E-03 1.118E-05 

n-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

sec-Butyl benzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

tert-Butylbenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Carbon Disulfide 17.878 15.248 1. 12E-09 1,05E-02 1.407E-05 

Carbon Tetrachloride 0.062 0.053 3.89E-12 3.67E-05 4,903E-08 

Chlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Chlorodibromomethane 0000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Chloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Chloroform 0.251 0.214 1.57E-11 1.48E-04 1.978E-07 

Chloromethane 5,971 5.092 3.73E-10 3.52E-03 4.699E-06 

2-Chlorotoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

4-Chlorotoluene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dibromo-3-chloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dibromoethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Dibromomethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichlorobenzene 0.000 0,000 O.OOE+OO O.OOE+OO O,OOOE+OO 

1,3-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1 A-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Dichlorodifluoromethane 0.377 0.322 2.35E-11 2.22E-04 2.968E-07 

1,1-DichIOl"oethane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichloroethane 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

cis-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

trans-1,2-Dichloroethene 0.000 0.000 o.OOE+OO O.OOE+OO O.OOOE+OO 

1,1-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OO 

1,2-Dichloropropane 0.000 0.000 O,OOE+OO O.OOE+OO O,OOOE+OO 

1,3-Dichloropropane 0.000 0,000 O,OOE+OO O.OOE+OO o OOOE+OO 

2,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO o OOOE+OO 

cis-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

trans-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 
Client Spruance Genco, LLC Test Location Unit No.2 Page 4 

Project No. 3333 Test Run 00. 

Calculations (cont.) 

Conc. Conc.@corr. o:?; Conc. Emission Rate Emission Rate 

Compound (uq/dscml (uq/dscm) (lb/dscO (lb/hrl (lb/MMBtu) 

1,1-Dichloropropene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

Ethylbenzene 0.033 0.028 2,05E-12 1.93E-05 2.580E-08 

Hexachlorobutadiene 0,000 0,000 O.OOE+OO o OOE+OO O.OOOE+OO 

2-Hexanone 1.968 1,678 1.23E-10 1,16E-03 1.54BE-06 

Isopropylbenzene 0,000 0,000 O.OOE+OO o OOE+OO O.OOOE+OO 

p-Isopropyltoluene 0.000 0,000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Methylene Chloride 7.044 6.007 4.40E-10 4.15E-03 5.543E-06 

4-Methyl-2-Pentanone 0.000 0.000 O.OOE+OO O,OOE+OO O,OOOE+OO 

Naphthalene 0.000 0,000 O.OOE+OO O,OOE+OO O,OOOE+OO 

n-Propylbenzene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Styrene 0,000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

1,1,1,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OO 

1,1,2,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Tetrachloroethene 0,151 0.129 9.42E-12 8.89E-OS 1.187E-07 

Toluene 2.548 2,173 1.59E-10 1,50E-Q3 2.005E-06 

1,2,3-Trichlorobenzene 0.000 0,000 O.OOE+OO O.OOE+OO O,OOOE+OO 

1,2,4-Trichlorobenzene 0.000 0.000 O.OOE+OO O,OOE+OO O,OOOE+OO 

1,1,1-Trichloroethane 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1,2-Trichloroethane 0.000 0,000 O.OOE+OO O,OOE+OO O,OOOE+OO 

Trichloroethene 0,000 0,000 O.OOE+OO O,OOE+OO O,OOOE+OO 

Trichlorofluorometl1ane 1,951 1.664 1.22E-10 1.15E-03 1,S35E-06 

1,2,3-Trichloropropane 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1 ,2,4-T rimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,3,S-Trimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Vinyl Chloride 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

m-Xylene & p-Xylene 0,092 0.078 5.73E-12 S.41E-05 7.225E-08 

o-Xylene 0.000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Total 12.299 10.032 7.45E-10 4.78E-01 6.388E-04 
3333-VOST-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb= 

Ps= 

Pstd = 

Tm= 

INPUT Ts = 

INPUT Tstd= 

INPUT y = 

INPUT t = 

INPUT Ds = 

As = 

Kp = 

K1 = 

K2 = 

K3 = 

INPUT Fd = 

INPUT [02[ 

INPUT [C02[ 

[N2[ 

AirNova, Inc. 

EPA Method 1, 2, 3A and 0031/SW-846 Method 82608 

(Flows, 02/C02, and Speciated Volatile Organic HAPs) 

Spruance Genco, LLC 

3333 

Unit No.2 

Two 

04123f10 

1525-1730 

1.107 

-0.45 

29.90 

29.87 

Emission Data 

dcf 

in. H2O 

in. H9 

in. H9 

29.92 in. H9 

549.7 R 

651.5 R 

527.7 R 

1.000 

90 min. 

10.300 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83.3204 sq. ft. Cross sectional area of stack 

85.49 ft[(lb/lbmol)*(inHgl]" 5}/[s*R*inH20] 

17.637 Rfin.Hg 

0.047070 cu.ftlml 

0.0026688 in.Hg-cffml-R 

9676 scf/MMBtu 

Instrumental Data 

4.16 %-dry 

14.56 %-dry 

81.28 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm ~ Pbl Tm 

Vmstd = 1.062 dsd 

0.0301 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws= 

Bws= 

Based on the SSVOH sampling train 

0,1270 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unil No, 2 

Two 

Ms = [((44*%C02) + (32*%02) + (2S*%N2» '* (1-Bws) 1 + (1S*Bws) 

Ms = 28.909 Ibf Ibmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs= 

Vs= 

Based on the SSVOH sampling train 

43.450 fps 

6) Average actuat stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min ~ Vs * As 

Qa = 217216.37 cfm 

6151.57 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa * (TstdfTs) * (Ps/Psld) * (1-Bws) 

Qstd = 153323.32 dscfm 

4342.12 dscmm 

Page 2 
Client Spruance Genco, LLC Test Location Unit No.2 Page 3 

Project No. 3333 Test Run Two 

Calculations (cont.) 

8) Speciated Volatile Organic HAPs - Concentrations and Emission Rates 

qSVOH] '" M[SVOH] (ug) / Vmstd (dscm) 

qSVOH](lb/dscf) = qSVOH](ug/dscm)" 1e-06g/ug ~ 2.20Se-03Ib/g ~ 0.02832 dscm/dscf 

E[SVOH](lb/hr) = qSVOH] (ug/dscm)" (2.20SE-09) (Ib/ug) * Qstd (dscmm) ·60 (min/hr) 

E[SVOH](lb/MMBtu) = qSVOH](Ib/dscf) ~ Fd * (20.9/20.9-%02) 

qSVOH](@corr. 02) = qSVOH] (ug/dsem) * [(20.9-corrected %02) I (20.9-actual %02) I 

Corrected 02 percentage is: 7.0 % 

Conc. Conc.@ggrr Q2 Conc. Emission Rate Emission Rate: 

Compound (ug/dscm) (ug/dscm) (lb/dscO (lblhr) (lb/MMBtu) 

Acetone 803.668 667.323 S.02E-08 4.62E-01 6.063E-04 

Benzene 8.045 6.680 S.02E-10 4.62E-03 6.069E-06 

Bromobenzene 0.000 0.000 O.OOE+OO o OOE+OO O.OOOE+OO 

Bromochloromethane 1.108 0.920 6.92E-11 6.37E-04 8.361 E-07 

Bromodichloromethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Bromoform 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Bromomethane 6.384 5.301 3.99E-10 3.67E-03 4.816E-06 

2-Butanone 18.842 15.645 i.18E-09 1.08E-02 1.421 E-05 

n-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

sec-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

tert-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Carbon Disulfide 16.472 13.677 i.03E-09 9.46E-03 1.243E-05 

Carbon Tetrachloride 0.086 0.072 S.40E-12 4.97E-OS 6.S22E-08 

Chlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Chlorodibromomethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Chloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Chloroform 0.211 0.175 1.31E-11 1.21E-04 1.S89E-07 

Chloromethane 38.700 32.13S 2.42E-09 2.22E-02 2.919E-OS 

2-Chlorotoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

4-Chlorotoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1 ,2-Dibromo-3-ch loropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dibromoethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Dibromomethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichiorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,3-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,4-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Dichlorodifluoromethane 0.6S8 0.547 4.11E-11 3.78E-04 4.966E-07 

1,1-Dichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

cis-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

trans-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,3-Dichloropropane 0.166 0.138 1.04E-11 9.SSE-OS 1.2S4E-07 

2,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

cis-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

trans-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 
Client Spruance Genco, LLC Test Location Unit No.2 Page4 

Project No. 3333 Test Run Two 

Calculations (cont.) 

Conc. Conc.@oorr. 02 Conc. Emission Rate Emission Rate 

Compound (ug/dscm) (ug/dscm) (lb/dscO (lbfhr) (lbfMMBtu) 

1,1-Dlchloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Ethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Hexachlorobutadiene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

2-Hexanone 2.549 2.117 1.59E-10 1.46E-03 1.923E-06 

Isopropylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

p-Isopropyltoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Methylene Chloride 1234.252 1024.857 7.71E-08 7.09E-01 9.311E-04 

4-Methyl-2-Pentanone 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Naphthalene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

n-Propylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Styrene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1,1,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1,2,2·Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Tetrachloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Toluene 1.527 1.268 9.54E-11 8.77E-04 1.152E-06 

1,2,3-Trichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2,4-Trichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1,1-Trichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1,2-Trichloroethane 0000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Trichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Trichlorofluoromethane 3.418 2.838 2.13E·10 1.96E-03 2.579E-06 

1 ,2,3-Trichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2,4-Trimethylbenzene 0.000 0.000 o OOE+OO O.OOE+OO O.OOOE+OO 

1,3,5· Trimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Vinyl Chloride 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

m·Xylene & p-Xylene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

a-Xylene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Total 32.365 25.706 1.96E-09 1.23E+00 1.611E-03 
3333-VOST-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb = 

Ps= 

Pstd= 

Tm = 

INPUT Ts = 

INPUT Tstd= 

INPUT Y = 

INPUT t., 

INPUT Ds '" 

As ., 

Kp= 

K1 = 

K2 = 

K3 = 

INPUT Fd = 

INPUT 1021 

INPUT IC021 

IN21 

AirNova, Inc. 

EPA Method 1, 2, 3A and 0031/SW·846 Method 8260B 

(Flows, 02/C02, and Speciated Volatile Organic HAPs) 

SprLlance Genco, LLC 

3333 

Unit No.2 

Three 

04/23f10 

1808-2018 

1.092 

-0.45 

29.90 

29.87 

Emission Data 

dof 

in. H2O 

in. Hg 

in. Hg 

29.92 in. Hg 

548.4 R 

652.3 R 

527.7 R 

1.000 

90 min. 

10.300 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83.3204 sq. ft. Cross sectional area of stack 

85.49 fI[(lb/lbmol)*(in Hg)l". 5}/[s*R*inH20] 

17.637 R/in.Hg 

0.047070 cu.fllml 

0.0026688 in.Hg-cffml-R 

9826 scf/MMBtu 

Instrumental Data 

4.03 %-dry 

14.52 %-dry 

81.45 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

8pruance Genco. LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1" Y * Vm * Pbl Tm 

Vmstd = 1.050 dscf 

0.0297 dscm 

3) Decimal fraction of moisture by volume In stack gas, Bws. 

INPUT 

Bws= 

Bws= 

Based on the SSVOH sampling train 

0.1300 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No.2 

Three 

Ms = [((44*%C02) + (32*%02) + (28*%N2» * (1-Bws) J + (18*Bws) 

Ms= 28,861 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs = 

Vs= 

Based on the SSVOH sampling train 

44.900 fps 

6) Average actual stack gas volumetric flowrate, Oa. 

Oa = 60 secJmin • Vs • As 

Oa = 224465.25 cfm 

6356.86 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Ostd = Oa" (TstdfTs) * (PslPstd) * (1-Bws) 

Qstd = 157701.86 dscfm 

4466.12 dscmm 

Page 2 
CHent Spruance Genco, LLC Test Location Unit No, 2 Page 3 

Project No. 3333 Test Run Three 

Calculations (cont.) 

8) Speciated Volatile Organic HAPs· Concentrations and Emission Rates 

C[SVOHj = M[SVOHj tug) 1 Vmstd (dscm) 

C[SVOH](lb/dscf) = C[SVOH](ug/dscm) * 1e-06g/ug ~ 2-205e-03Ib/g ~ 0.02B32 dscm/dscf 

E[SVOH](lb/hr) = C[SVOH] (ug/dscm) * (2.205E-09) (Ib/ug) * Qstd (dscmm) * 60 (min/hr) 

E[SVOH](lb/MMBtu) = C[SVOH]{lb/dscf) * Fd * (20,9/20.9-%02) 

C[SVOH](@ corr. 02) = C[SVOH] (ug/dscm) • [ (20,9-corrected %02) I (20.9-actual %02) ) 

Corrected 02 percentage is: 7.0 % 

Cone. Conc.@corr.02 Conc. Emission Rate Emission Rate 

Compound (uq/dscm) (ugfdscm) Ob/dscfl (lb/hr) (lb/MMBtu) 

Acetone 900.569 742.022 S.62E-08 5,32E-01 6.B46E-04 

Benzene 3.679 3.031 2.30E-10 2.17E-03 2,796E-06 

Bromobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OO 

Bromochloromethane 0.807 0.665 5.04E-11 4.77E-04 6,135E-07 

Bromodichloromethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Bromoform 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Bromomethane 6.355 5.237 3.97E-10 3.76E-03 4.831E-06 

2-Butanone 21.297 17.548 1.33E-09 1.26E-02 1.619E-05 

n-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

sec-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OO 

tert-Butylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Carbon Disulfide 11.850 9.764 7AOE-10 7.00E-03 9.00BE-06 

Carbon Tetrachloride 0.050 0.042 3.15E-12 2.9BE-05 3.834E-OB 

Chlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Chlorodibromomethane 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

Chloroethane 0.000 0.000 O.OOE+OO O.OOE+OO o OOOE+OO 

Chloroform 0.235 0.194 1A7E-11 1.39E-04 1,789E-07 

Chloromethane 45.764 37.707 2.86E-09 2.70E-D2 3,479E-05 

2-Chlorotoluene 0,000 0.000 O.OOE+OO O.OOE+OO O,OOOE+OO 

4-Chlorotoluene 0.000 0.000 O,OOE+OO O.OOE+OO O.OOOE+OO 

1 ,2-Dibromo-3-chloropropane 0.000 0.000 O.OOE+OO o OOE+OO O.OOOE+OO 

1,2-Dibromoethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Dibromomethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,3-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1 A-Dichlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Dichlorodifluoromethane 0.393 0.324 2.46E-11 2.32E·04 2.991E-07 

1,1-Dichloroethane 0,000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

cis-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

trans-1,2-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1-Dichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,3-Dichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

2,2-Dichloropropane 0000 0,000 O.OOE+OO O.OOE+OO O.OOOE+OO 

cis-1,3-Dichloropropene 0.000 0.000 O.OOE+OO O,OOE+OO O.OOOE+OO 

trans-1 ,3-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 
Client Spruance Genco, LLC Test Location Unit No.2 Page 4 

Project No. 3333 Test Run Three 

Calculations (cant.) 

Conc. Conc.@corr.Q;:: Conc. Emission Rate Emission Rat!:: 

Compound (ug/dscml (ug/dscm) (lb/dscO (Ib/hr) (lb/MMBtu) 

1,1-Dichloropropene 0.000 0.000 O.OOE+OO O.OOE+OO o OOOE+OO 

Ethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO o OOOE+OO 

Hexachlorobutadiene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

2-Hexanone 2.914 2.401 1.82E-10 1.72E·03 2.215E-06 

Isopropylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

p-Isopropyltoluene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Methylene Chloride 1149.094 946.794 7.1SE-OS 6.79E-01 S.735E·04 

4-MethYI-2-Pentanone 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Naphthalene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

n-Propylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Styrene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1,1,2-Tetrachloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1,2,2-Tetrachloroethane 0.000 0.000 O.OOE+OO o OOE+OO O.OOOE+OO 

Tetrachloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Toluene 2.000 1.64S 1.25E-10 1.1SE-03 1 520E-06 

1,2,3-Trlchlorobenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2,4-Trlchlorobenzene 0.000 0.000 O.OOHOO O.OOE+OO O.OOOE+OO 

1,1,1-Trichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,1,2-Trichloroethane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Trichloroethene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Trichlorofluoromethane 5.064 4.173 3.16E-10 2.99E-03 3.S50E-06 

1,2,3-Trichloropropane 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,2,4-Trimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

1,3,5-Trimethylbenzene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Vinyl Chloride 0.000 0000 O.OOE+OO O.OOE+OO O.OOOE+OO 

m-Xylene & p-Xylene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

o-Xylene 0.000 0.000 O.OOE+OO O.OOE+OO O.OOOE+OO 

Total 32.577 25.675 1.97E-09 1.27E+00 1.634E·03 
Unit No.3 
Spruance Genco, LLC 

Richmond, Virginia 

Project No. 3333 

April 16, 2010 

Unit No.3 

Run No.1 

Coal Analysis for F Factor Calculation 

F FACTOR CALCULATION 

INPUT %H= 4.82 Hydrogen Content (%) 

INPUT %c= 76.49 Carbon Content (%) 

INPUT % N= 1.4 Nitrogen Content (%) 

INPUT %0= 4.54 Oxygen Content (%) 

INPUT %8= 0.69 Sulfur Content (%) 

INPUT GCV= 13494 Gross Calorific Value (Btu/lb) 

Fd = 1011.6" [(3.64*%H) + (1,53*%C) + (0.57"%8) + (O.14*%N) - (O.46*%02)]/GCV 

Fd = 9862 scf/MMBtu 
Spruance Genco, LLC 

Richmond, Virginia 

Project No. 3333 

April 19, 2010 

Unit No.1 

Run No.2 

Coal Analysis for F Factor Calculation 

F FACTOR CALCULATION 

INPUT %H= 5.04 Hydrogen Content (%) 

INPUT %c= 76.71 Carbon Content (%) 

INPUT %N= 1.56 Nitrogen Content (%) 

INPUT %0= 6.35 Oxygen Content (%) 

INPUT %s= 1.05 Sulfur Content (%) 

INPUT GCV= 13696 Gross Calorific Value (Btu/lb) 

Fd = 10116'" [(3.64"%H) + (1.53*%C) + (0.57·%S) + (0 14"'%N) - (0.46*%02)]1 GCV 

Fd = 9755 scf/MMBtu 
Spruance Genco, LLC 

Richmond, Virginia 

Project No. 3333 

April 19, 2010 

Unit No.1 

Run NO.3 

Coal Analysis for F Factor Calculation 

F FACTOR CALCULATION 

INPUT % H= 5.12 Hydrogen Content (%) 

INPUT %c= 78.65 Carbon Content (%) 

INPUT %N= 1.67 Nitrogen Content (%) 

INPUT %0= 5.68 Oxygen Content (%) 

INPUT %s= 1.04 Sulfur Content (%) 

INPUT GGV= 13902 Gross Calorific Value (Btu/lb) 

Fd = 10"6" [(3.64"%H) + (1.53*%C) + (0.57*%5) + (O.14*%N) - (0.46*%02)1 / GCV 

Fd = 9868 scf/MMBtu 
3333-7E 

Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Date 

Unit No.3 - Acid Gases & Non OF HAPs 

04/15/10 

Parameter: Oxygen 

Instrument S[2an (% 021: 21.96 

Actual Gafibration Gas Value (% 021: 

Analy'zer calibration Res[2onse f% 021: 

Analvzer Calibration Error (% SoanJ: 

Zero Sy:stem Calibration Gas 

A[212arent Init Sy.s. Init. Sy.s. Final Sl:::s. Final Sl:::s. 

Stack Carib. Gal. Bias Cafib. Cal. Bias 

Run Cone. Response (% s[2anl Response f% span) 

4.29 0.15 0.64 0.09 0.36 

2 4.11 0.09 0.36 0.06 0.23 

3 3.99 0,06 0.23 0.05 0.18 

4 0,00 0.05 0.18 0.00 -0.05 

5 0.00 0.00 -0.05 0.00 -0,05 

6 0.00 0.00 -0.05 0.00 -005 

7 0.00 0.00 -0.05 0.00 -0.05 

a 0.00 0.00 -0.05 0.00 -0.05 

9 0.00 0.00 -0.05 0.00 -0.05 

10 0.00 000 -0,05 0.00 -0.05 

11 0.00 000 -0.05 0.00 -0.05 

12 0.00 0.00 -0.05 0.00 -0.05 

AirNova, Inc. Page 1 

EPA Method 7E Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Analy.zer Cafib. Gases U[2scalf!. 

,ero low mid high Sy's. Cal. Gas 

0.00 N/A 12.46 21.96 12.46 

0.01 N/A 12.33 21.95 12.33 

0.05 0.00 -0.59 -0.05 

U~scale Sy:stem Calibration Gas 

Cal/b. Init. Sl:::s. !nit. Sl:::s. Final S:y's. Fina! Sl:::s. Cafib. ~ 

Drift Calib. Cal. Bias Calib. Cal. Bias Dnff Stack 

(% spanJ Response (% span) Rf!.sponse (% span) (% soanl ~ 

-0.27 12.37 0.18 12.39 0.27 0.09 4.24 

-0.14 12.39 0.27 12.38 0.23 -005 4.08 

-0.05 12,38 0.23 12.38 0.23 0.00 3.98 

-0.23 12.38 0.23 0.00 -56.15 -56.38 -0.05 

0.00 0.00 -56.15 0.00 -56.15 0.00 ERR 

000 0.00 -56.15 0.00 -56.15 0.00 ERR 

0.00 000 -56 15 0.00 -56.15 0.00 ERR 

0.00 0,00 -56.15 0.00 -56.15 0.00 ERR 

0.00 0.00 -56.15 0.00 -56.15 0.00 ERR 

0.00 0.00 -56.15 0.00 -56.15 0.00 ERR 

0.00 0.00 -56.15 0.00 -56.15 0.00 ERR 

000 0.00 -56,15 0.00 -56.15 0.00 ERR 
3333-7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit No.3 - Acid Gases & Non DF HAPs 

04/15/10 

Run 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

Parameter: 

Instrument Soan (% C02): 

Carbon Dioxide 

17.83 

Actual Calibration Gas Value (% C02): 

Anal'i.Zer Calibration Response (% C02).-

AnalYZer CalibratIOn Error (% Span): 

Zero System Calibration Gas 

Agparent Init. S:ls. Init. S:ls. Final S:ls. Fingl S'i.s. 

Stack Galib_ CfJ.'- Bias Ca/ib. Gal. Bias 

Gone. Response (% span) Response (% span) 

14.17 0.06 0.45 0.02 0.22 

14.23 0.02 0.22 0.13 0.84 

14.22 0.13 0.84 0.13 0.84 

0.00 0.13 0_84 0_00 0.11 

0_00 000 0.11 0_00 0.11 

0_00 000 0.11 0.00 0.11 

0.00 0.00 0.11 0.00 0.11 

0,00 0.00 0.11 0.00 0.11 

0.00 0.00 0.11 0.00 0.11 

0.00 0.00 0_11 0_00 0.11 

0.00 000 0.11 0.00 0.11 

000 000 0.11 0.00 0.11 

AirNova, Inc. Page 2 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal'i.zer Qa/ib. Gases UQscale 

zero low mid high S:ls. Cal. Gas 

0.00 NfA 12.39 17.83 12.39 

-0.02 NfA 12.36 17.76 12.36 

-0.11 0.00 -0.17 -0.39 

UQscale Sy:stem C~libration Gas 

Calib_ {nit. S:ls. Init. S:ls. Final S:ls. Fina{ S:ls. Gallb. Actual 

Drift Calib. Cal. Bias Galib. Gal. Bias Drift Stack 

(% span) Response (% span) Resoonse (% span) (% span) ~ 

-0.22 12.32 -0.22 12_32 -0.22 0.00 14.26 

0.62 12.32 -0.22 12.31 -0.28 -0.06 14.33 

0.00 12.31 -0.28 12.31 -0.28 0.00 14.33 

-0.73 12.31 -0.28 0.00 -69.32 -69.04 -0.13 

0_00 0.00 -69.32 0.00 -69.32 0.00 ERR 

0.00 0.00 -6932 0.00 -69.32 0.00 ERR 

0.00 0_00 -69.32 0.00 -69.32 0.00 ERR 

0.00 000 -69.32 0.00 -69.32 0.00 ERR 

0.00 0.00 -69.32 0.00 -69.32 0.00 ERR 

0.00 0.00 -69,32 0_00 -69.32 0_00 ERR 

0_00 0,00 -69.32 0.00 -69.32 0_00 ERR 

0_00 0.00 -69_32 0.00 -69.32 0.00 ERR 
3333·7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit No.3 - Acid Gases & Non OF HAPs 

04115110 

Parameter: Carbon Monoxide 

Instn;ment Span (ppmV CO): 2246 

Actual Calibration Gas Value (pomV CO): 

Anal'Ger Calibration Response (ppmV CO): 

AnalYZer Calibration Error (% Span). 

Zero Sy:stem Calibration Gas 

AQparent Init. S~s. Init. S)!s. Fmal S)!s. Final S)!s. 

stack Calib. Cal. Bia!j Calib. Cal. Bias 

Run Conc. ResQonse (% sQanl ResQonse (% span) 

747.1 -1.2 0.00 2.4 0.16 

2 327.2 2.4 0.16 2.4 0.16 

3 467.5 24 0.16 2.4 0.16 

4 0.0 2.4 0.16 0.0 0.05 

5 0.0 0.0 0.05 0.0 0.05 

6 0.0 0.0 0.05 0.0 005 

7 0.0 0.0 0.05 0.0 0.05 

B 0.0 0.0 0.05 0.0 0.05 

9 0.0 0.0 0.05 0.0 0.05 

10 0.0 0.0 0.05 0.0 0.05 

11 0.0 0.0 0.05 0.0 005 

12 0.0 0.0 0.05 0.0 005 

AirNova, Inc. Page 3 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal'Ger Calib. Gases UQscale 

zero low mid high S~s. Cal. Gas 

0.0 0.0 1204.0 2246.0 1204.0 

-1.2 0.0 1202.4 22A6.9 1202.4 

-0.05 0.00 -0.07 0.04 

Ul2scale Sy:§tem Calibration Gas 

Calib. {nit. S)!s. Init. S)!s. Final S~s. Final S)!s. Calib. !'&!ml 

Drift Calib. Cal. Bia~ Cafib. Cal. Bias Drift SW£ 

(% span) Response f% Man) Response (% span) (% sQanl Conc. 

0.16 1217.0 0.65 12012 -0.05 -0.70 743.7 

0.00 1201.2 -0.05 12109 0.38 0.43 324.9 

0.00 1210.9 038 1212.2 0.44 0.06 463.1 

-0.11 1212.2 0.44 0.0 -53.54 -53.97 -2.4 

0.00 00 -53.54 0.0 -53.54 0.00 ERR 

0,00 00 -53.54 0.0 -53.54 0.00 ERR 

0.00 0.0 -53.54 00 -53.54 0,00 ERR 

0.00 0.0 -53.54 00 -5354 0.00 ERR 

0.00 0.0 -53.54 0.0 -53.54 0.00 ERR 

0.00 0.0 -53.54 0.0 -53.54 000 ERR 

0.00 00 -53.54 0.0 -53.54 0.00 ERR 

0,00 00 -5354 0.0 -5354 0,00 ERR 
3333-7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit No.3 - Acid Gases & Non DF HAPs 

04/15/10 

Parameter.· Nitrogen Oxides (as N02) 

Instrument Span (ppmV NOxJ: 232.6 

AQtual Calibration Gas Value (ppmV NOxJ: 

Analyzer Calibration Response (pomV NOx): 

Anal)lZer Calibration Error (% Span): 

ZerQ S~stem Calibration Gas 

Appa@.nt Init. SJ:::s. Init S)'.s. Final S)'.s. Final S)'.:S:. 

Stack Calib. Cal. Bias Calib. Cal. Bias 

Run Conc. Re,s:ponse (% span) Response (% span) 

203.8 0.0 0.00 2.4 1.03 

2 196.1 2.4 1.03 0.0 0.00 

3 197.S 0.0 0.00 0.0 0.00 

4 0.0 0.0 000 00 0.00 

5 0.0 0.0 0.00 0.0 0.00 

6 0.0 00 0.00 0.0 0.00 

7 0.0 0.0 0.00 0.0 0.00 

a 0.0 00 0.00 0.0 0.00 

g 0.0 0.0 0.00 0.0 0.00 

10 0.0 0.0 0.00 0.0 0.00 

11 0.0 0.0 0.00 0.0 0.00 

12 0.0 0.0 0.00 0.0 0.00 

AirNova, Inc. Page 4 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal)'.zer CaliP. Gas:es U{2§'Qale 

zero """ mid high S)'.s. Cal. Gas: 

0.0 00 122.1 232.6 122.1 

0.0 0.0 120.9 230.3 120.9 

0.00 0.00 -0.54 -0.99 

Ugscale Sy:stem Calibration Gas 

Calib. In;t. S)'.:S:. Init. SJ:::s. Final,$:)'.s. Final SJ:::s. Calib. Actual 

Drift ~ Cal. Bias Calib. Cal. Bias Drift Slack 

(% span! Response (% span) Resoonse (% span} (% soan! Conc. 

1.03 120.6 -0.12 120.9 -0.02 0.09 206.9 

-1.03 120.9 -0.02 122.1 052 0.54 197.9 

0.00 122.1 0.52 122.1 0.52 0.00 197.8 

0.00 122.1 0.52 0.0 -51.98 -52.49 0.0 

0.00 00 -51.9S 0.0 -51.98 0.00 ERR 

0.00 00 -51.98 0.0 -51.98 0.00 ERR 

0.00 00 -51.98 0.0 -51.98 0.00 ERR 

0.00 0.0 -51.9a 0.0 -51.98 0.00 ERR 

0.00 0.0 -51.9a 0.0 -51.9a 0.00 ERR 

0.00 0.0 -51.9a 0.0 -51.9a 0.00 ERR 

0.00 0.0 -51.9a 0.0 -51.9a 0.00 ERR 

0.00 0.0 -51.9a 0.0 -51.9a 0.00 ERR 
3333-7E 

Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Date 

Unit No.3- ACId Gases & Non OF HAPs 

04115/10 

Run 

1 

2 

3 

4 

5 

6 

7 

B 

9 

10 

11 

12 

Parameter; Sulfur Dioxide 

Instrument Span (ppmV S02): 443 

Actual Calibration Gas Value (ppmV S02): 

AnalYZer Calibration Response (ppmV S02): 

Anal¥Z.er Calibration Error (% Span): 

Zero Sy:stem Calibration Gas 

Ap/2~Ustnt Inll S!!s. Init. S\':S. Final S\,:s. Final S\':S 

Stack Calib. Cal. Bias Callb_ ~gl. Bias 

~ Response (% span) Response (% span) 

37_0 5.1 OA6 5A 0.51 

38.1 5A 0_51 4.6 0.35 

34.7 4.6 0.35 3.2 0.02 

0.0 3.2 0.02 0.0 -0_70 

0.0 0.0 -0.70 0.0 -0.70 

00 0.0 -0_70 0.0 -0.70 

0.0 0.0 -070 0.0 -0.70 

0.0 0.0 -0.70 0.0 -0_70 

0.0 0.0 -0.70 0.0 -0.70 

0.0 0.0 -0.70 0.0 -0.70 

0.0 00 -0.70 0.0 -0_70 

0.0 0.0 -0.70 0.0 -0.70 

AirNova, Inc. Page 5 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal¥Z.er Calib. Gases Upscale 

zero low mid high S\,:s. Cal. Gas 

0.0 0.0 222_0 443_0 222.0 

3.1 0.0 225.8 446.8 225.8 

1.33 0.00 1.62 1.63 

Ul2scale Sy:stem Calibration Gas 

Calib. Init. ~vs. Init. ~~. Fina.l S~. Final S!!s. Ca/ib. Actual 

Drift Ga/ib. Gal. Bias Galib_ Cal_ Bias Drift Stack 

(% span) Response (% span) Response (% span) f% span) Gonc. 

0.05 225.8 0.00 225.8 0.01 0.01 32.0 

-0.16 225_8 0.Q1 222.2 -0.80 -0.81 33.5 

-0.33 222.2 -0.80 222.5 -0.74 0.07 31.3 

-0.72 222.5 -0.74 0.0 -50.96 -50.23 -3.2 

000 0.0 -50.96 0.0 -5096 0.00 ERR 

0.00 0.0 -50.96 0.0 -50.96 0.00 ERR 

0.00 0.0 -50.96 0.0 -50.96 000 ERR 

0.00 00 -5096 0.0 -50.96 0.00 ERR 

0_00 0.0 -50.96 0.0 -50_96 0.00 ERR 

0.00 0.0 -50.96 0.0 -50.96 0.00 ERR 

0.00 0.0 -50.96 0.0 -50.96 0.00 ERR 

000 0.0 -50.96 0.0 -50.96 0.00 ERR 
3333-7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit NO.3 - Non Dioxm/Furan HAPs 

04/15110 

Parameter. Total Hydrocarbons (as 

Instrument Span (ppmV THC): 20 

Actual Calibration Gas Value (ppm V THC): 

Analyzer Calibra/ion Response (ppm V THC!: 

Analyzer Calibration Error (% Cal. Gas Value): 

Zero S~stem Calibration Gas 

AQQarent Init. Svs. InIt. S:vs. Final S,,-s. Final S,,-s. 

Stack Calib. Cal. Bias Calib. Cal. Bias 

Run Cone. Response (% span) ReSPonse (% span) 

1 0.9 -0.0 000 0.1 0.75 

2 0.3 o 1 0.75 -0.1 -0.20 

3 0.3 -0.1 -0.20 -0.1 -0.65 

4 0.0 -0.1 -0.65 0.0 0.05 

5 0.0 0.0 0.05 0.0 0.05 

6 0.0 0.0 0.05 0.0 0.05 

7 0.0 0.0 0.05 0.0 0.05 

B 0.0 00 0.05 00 0.05 

9 0.0 0.0 0.05 00 0.05 

10 0.0 00 0.05 0.0 0.05 

11 0.0 0.0 0.05 0.0 005 

12 0.0 0.0 0.05 0.0 0.05 

AirNova, Inc. PageS 

EPA Method SC Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

C3H8 ) 

Ana/,,-zer Calib. Gases Upscale 

zero low mid high S"-s. Cal. Gas 

0.0 4.9 9.1 17.0 9.1 

-0.0 4.9 9.1 17A 9.1 

-0.10 -0.20 1.65 

U~scale S~stem Calibration Gas 

Calib. Init. Sl!s. Init. S,,-s. Final S~. Final S"-S Calib. Actual 

Drift ~ Cal. Bias Calib. Qal. Bias Drift Stack 

(% span! Response (% span) Response (% span) (% span) Cone. 

0.75 9.1 0.00 9.0 -0.30 -0.30 0." 

-0.95 9.0 -0.30 9.1 0.05 0.35 0.2 

-0.45 9.1 0.05 9.0 -0.35 -OAO 0.3 

0.70 9.0 -0.35 0.0 -45.25 -44.90 0.1 

0.00 00 -45.25 0.0 -45.25 0.00 ERR 

0.00 0.0 -45.25 00 -45.25 0.00 ERR 

0.00 0.0 -45.25 0.0 -45.25 000 ERR 

0.00 0.0 -45.25 0.0 -45.25 0.00 ERR 

000 0.0 -45.25 0.0 -45.25 0.00 ERR 

0.00 00 -45.25 0.0 -45.25 0.00 ERR 

0.00 0.0 -45.25 0.0 -45.25 0.00 ERR 

0.00 0.0 -45.25 0.0 -45.25 0.00 ERR 
3333-HCI-HF-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

1= 

Os = 

As= 

Cp= 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

CF = 

CF = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and 26A 

(Flows, 02/C02, H20,and HCI/HF) 

Spruance Genco, LLC 

3333 

Unit No.3 

One 

04/15/10 

0900-1211 

343 cc 

113.979 dcf 

Emission Data 

-0.50 in H20 

30.44 in. Hg 

30.40 in. Hg 

29.92 in H9 

0.7037 in H20 ".5 

1.414 in. H20 

527.1 R 

654.4 R 

527.7 R 

0.25 in. 

0.000341 sq. ft. 

1.01 

180 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83 323 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)"(inHg)]".5}/[s"R"rnH20] Pitot tube constant 

17.637 R/in.Hg 

0047070 cu.ftlml 

0.0026688 in.Hg-cf/ml-R 

9862 scf/MMBtu 

9.461E-OB Ib/dscf I ppmVd 

5.192E-OB Ib/dscf I ppmVd 

Instrumental Data 

4.24 %-dry 

14.26 %-dry 

81.50 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCI 

Conversion Factor for HF 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y' Vm ' (Pb + dHI13.6) I Tm 

Vmstd = 117.650 dscf 

3.33 dscm 

Unit NO.3 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 'Vic 

Vw(std) = 16.145scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 0.121 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) I + (1S-Bws) 

Ms = 28.95 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp - (dP) , (TsIPs'Ms)'.5 

Vs= 43.57 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs ,. As 

Qa = 217831.4 cfm 

6169.0 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa - (Tstd/Ts)' (PsIPstd)' (1-Bws) 

Qstd = 156962.8 dscfm 

4445.2 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Hydrogen Chloride Concentration and Emissions 

Unit NO.3 

One 

M[HCI) = M[CI-)(mg) ° MW[HCI)(mglmmol) 1 MW[CI-)(mglmmol) 

Page 3 

C[HCI) = (M[HCI)(mg) ° 2.205E-06(lblmg) ° 21.85(scf"inHgllbmoIOR) ° K1 '10A6) 1 (MW[HCI](Ibllbmol)' Vmstd(d 

C[HCI)(@corr. 02) = C[HCI)(ppmV)' [(20.9-corrected 02) 1 (20.9-8ctU81 %02)) 

E[HCI) = M[HCI)(mg) ° Qstd(dscfm) • (2.20SE-06)(lblmg) ° 60(minlhr) 1 Vmstd(dscf) 

E[HCI) = C[HCI)(ppmV) ° Fd ° CF(HCI) ° (20.91(20.9-%02)) 

M[HCI) = 0.13 mg 

C[HCI) = 0026 ppmV 

C[HCI) = 0.021 ppmV (@ 7.0 %02) 

E[HCI) = 0.023 Iblhr 

E[HCI) = 3.02E-OS IblMMBtu 

9) Hydrogen Fluoride Concentration and Emissions 

C[HF) = M[HF)(mg) 1 Vmstd(dscm) 

C[HF) = (M[HF)(mg) ° 220SE-06(1blmg) ° 21 8S(scf"inHgllbmoIOR) ° K1 ° 1 OA6) 1 (MW[HF)(lbllbmol) ° Vmstd(dsc 

C[HF)(@corr. 02) = C[HF)(mgldscm) ° [(20.9-corrected 02) 1 (20.9-8ctu81 %02)) 

E[HF) = C[HF)(mgldscm) ° Qstd(dscmm) ° (2.20SE-06)(lblmg)· 60(minlhr) 

E[HF) = C[HF)(ppmV)' Fd' CF(HF)' (20.91(20.9-%02)) 

< M[HF) = 

< C[HF) = 

< C[HF) = 

< C[HF) = 

< E[HF) = 

< E[HF) = 

10) Isokinecity, I. 

0.030 mg 

0.009 mg/dscm 

0.011 ppmV 

0.009 ppmV (@ 

O.OOS Iblhr 

6.96E-06 IblMMBtu 

70 

% 1 = (1 00"Ts·(K3°Vlc+(VmoYlTm)(Pb+dHI13.6)))1(600tOPs'VsoAn) 

%1= 101.8 

% 02) 
3333-HCI-HF-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

t= 

Ds = 

As= 

Cp= 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

CF = 

CF= 

[02[ 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and 26A 

(Flows, 021C02, H20,and HCIIHF) 

Spruance Genco, LLC 

3333 

Unit No.3 

Two 

04/15/10 

1308-1615 

340.4 cc 

114.615 def 

Emission Data 

-0,50 in, H20 

30.37 in. Hg 

30.33 in. Hg 

29.92 in. Hg 

0.6879 in. H20 '\5 

1.394 In, H20 

545.0 R 

656.5 R 

527.7 R 

0.25 in. 

0.000341 sq. ft. 

1.01 

180 min, 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbllbmolr(inHg)j'.5}/[s·R·inH20] PltOt tube constant 

17.637 R/in Hg 

0.047070 cu ftlml 

0.0026688 in.Hg-ef/ml-R 

9755 scf/MMBtu 

9.461 E-08 Ibldsef I ppmVd 

5.192E-08 Ibldsell ppmVd 

Instrumental Data 

4.08 %-dry 

14.33 %-dry 

81.59 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HC] 

Conversion Factor for HF 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

SprLlance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y' Vm' (Pb + dH/13.6) I Tm 

Vmstd = 114.167 dscf 

3.23 dscm 

Unit No.3 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 • Vic 

Vw(std) = 16.023 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.123 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) I + (18'Bws) 

Ms= 28.92 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP)' (Ts/Ps'Ms)".5 

Vs= 42.73 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min· Vs * As 

Qa = 213644.4 cfm 

6050.4 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

Qstd = 152666.3 dscfm 

4323.5 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Hydrogen Chloride Concentration and Emissions 

Unit No.3 

Two 

M[HCI[ = M[CI-[(mg) , MW[HCI](mglmmol) 1 MW]CI-[(mglmmol) 

Page 3 

C[HCI] = (M]HCI](mg) , 2.205E-06(lblmg) • 21.85(scf"inHgllbmol'R) • K1 ' 10A6) 1 (MW[HCI](lbllbmol) 'Vmstd(d 

C[HCI](@corr. 02) = C[HCI](ppmV)' [(20 9-corrected 02) 1 (20.9-actual %02)] 

E[HCI] = M[HCI](mg) , Qstd(dscfm) , (2.205E-06)(lblmg) '60(minlhr) 1 Vmstd(dscD 

E[HCI] = C[HCI](ppmV)' Fd' CF(HCI)' (20.91(20.9-%02)) 

M[HCI] = 0.09 mg 

C[HCI] = 0.018 ppmV 

C[HCI] = 0.015 ppmV (@ 7.0 %02) 

E[HCI] = 0.016 Iblhr 

E[HCI] = 2 11 E-OS IblMMBtu 

9) Hydrogen Fluoride Concentration and Emissions 

C[HF] = M[HF](mg) 1 Vmstd(dscm) 

C[HF] = (M[HF](mg)' 2.205E-06(1blmg)' 21.85(scf"inHgllbmol·R)· K1 '10A6) 1 (MW[HF](Ibllbmol)' Vmstd(dsc 

C[HF](@corr. 02) = C[HF](mgldscm)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HF] = C[HF](mgldscm)' Qstd(dscmm)' (2.20SE-06)(lblmg)' 60(minlhr) 

E[HF] = C[HF](ppmV)' Fd' CF(HF)' (20.91(20.9-%02)) 

< M[HF] = 

< C[HF] = 

< C[HF] = 

< C[HF] = 

< E[HF] = 

< E[HF] = 

10) Isokinecity, I. 

0040 mg 

0.012 mgfdscm 

0.015 ppmV 

0.012 ppmV (@ 

0.007 Ibfhr 

9.36E-06 IblMMBtu 

7.0 

% 1 = (100·Ts'(K3-Vlc+(Vm'YlTm)(Pb+dHI13.6)))1(60·t'Ps·Vs'An) 

%1= 101.6 

%02) 
3333-HCI-HF-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts= 

Tstd= 

On = 

An = 

y= 

t = 

Ds= 

As = 

Cp= 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

CF = 

CF= 

[02] 

]C02] 

]N2] 

AirNova, Inc, 

EPA Methods 1,2,3A,4,and 26A 

(Flows, 02/C02, H20,and HCI/HF) 

Spruance Genco, LLC 

3333 

Unit No.3 

Three 

04/15/10 

1724-2033 

341.9 cc 

118.979 dcf 

Emission Data 

~O.50 in H20 

30.25 in. Hg 

30.21 in. Hg 

29.92 in. Hg 

0.7029 in. H20 ",5 

1.479 in H20 

548.3 R 

6424 R 

527.7 R 

0.25 in. 

0.000341 sq ft. 

1.01 

180 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbllbmol)"(inHg)]A.S}/[s·WinH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.ftlml 

0.0026688 In.Hg-cf/ml-R 

9868 scf/MMBtu 

9.461 E-08 Ib/dscf I ppmVd 

5.192E-08 Ib/dscf I ppmVd 

Instrumental Oata 

3.98 %-dry 

14.33 %-dry 

81.69 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCI 

Conversion Factor for HF 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1" Y"" Vm" (Pb + dH/13.6) I Tm 

Vmstd = 117.354 dsef 

3.32 dsem 

Unit No.3 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 ' Vic 

Vw(std) = 16.093 scI 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.121 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [ ((44'%C02) + (32'%02) + (28'%N2)) , (1-Bws) ) + (18'Bws) 

Ms= 28.95 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP) , (TsfPs'Ms)'.5 

Vs = 43.26 Ips 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs " As 

Qa = 216265.1 elm 

6124.6 emm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa' (TstdfTs)' (PsfPstd)' (l-Bws) 

Qstd = 157766.4 dscfm 

4467.9 dsemm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Hydrogen Chloride Concentration and Emissions 

Unit No.3 

Three 

M[HCI] = M[CI-](mg) • MW[HCI](mg/mmol) 1 MW[CI-](mg/mmol) 

Page 3 

C[HCI] = (M[HCI](mg) • 2.205E-06(lb/mg) • 21 85(scf"inHg/lbmol'R) • K1 • 10'6) 1 (MW[HCI](Ibllbmol) • Vmstd(d 

C[HCI](@corr. 02) = C[HCI](ppmV)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HCI] = M[HCI](mg)' Qstd(dscfm)' (2.205E-06)(lb/mg)· 60(min/hr) 1 Vmstd(dscf) 

E[HCI] = C[HCI](ppmV)' Fd' CF(HCI)' (20.9/(20.9-%02)) 

M[HCI] = 0.11 mg 

C[HCI] = 0.022 ppmV 

C[HCI] = 0.018 ppmV (@ 7.0 % 02) 

E[HCI] = 0.020 Ib/hr 

E[HCI] = 2 52E-05 Ib/MMBtu 

9) Hydrogen Fluoride Concentration and Emissions 

C[HF] = M[HF](mg) 1 Vmstd(dscm) 

C[HF] = (M[HF](mg) • 2205E-06(lb/mg) • 21.85(scf"inHg/lbmol·R) • K1 • 10'6) 1 (MW[HF](Ib/lbmol) • Vmstd(dsc 

C[HF](@corr. 02) = C[HF](mg/dscm)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HF] = C[HF](mg/dscm) • Qstd(dscmm) • (2205E-06)(lb/mg) • 60(m.n/hr) 

E[HF] = C[HF](ppmV)' Fd' CF(HF)' (20.9/(20.9-%02)) 

< M[HF] = 

< C[HF] = 

< C[HF] = 

< C[HF] = 

< E[HF] = 

< E[HF] = 

10) Isokinecity,l. 

0.040 mg 

0.012 mg/dscm 

0.014 ppmV 

0.012 ppmV (@ 

0.007 Ib/hr 

9.16E-06Ib/MMBtu 

7.0 

% 1 = (1 00·Ts·(K3·Vlc+(Vm·YlTm)(Pb+dH/13.6)))/(60·t·Ps-Vs·An) 

%1= 101.0 

% 02) 
Client 

Project No. 

Test Location 

Fuel Type 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

y= 

t= 

On = 

An = 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

[02[ 

[CO2] 

[N2] 

[CO] 

[THC] 

[CH4] 

[NOx] 

[S02] 

AirNova, Inc. Page 1 of 4 

EPA Methods 1, 2, 3A, 4, 6, 7E, 10, 18 and 2SA 

(Flows, 02/C02, H20, 502, NOx, CO and NMHC) 

Spruance Genco, LLC 

3333 

Unit NO.3 

Coal 

One 

04/15/10 

0900-1211 

343 cc 

Emission Data 

113.979 dcf 

-0.50 in. H20 

30.44 in. Hg 

30.40 in Hg 

29.92 in. Hg 

0.7037 in H20 ".5 

1.41 in. H20 

527.1 R 

654.4 R 

527.7 R 

1.01 

180 min. 

0.250 in 

0.000341 sq. ft. 

10.300 ft. 

83.3231 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)"'(inHg)]" 5}/[s"*R*inH20] 

17.637 R/in.Hg constant 

0.047070 cu.ftIml constant Pitot tube constant 

0.0026688 in.Hg-cf/ml-R constant 

9862 scf/MMBtu From EPA Reference Method 19 

Instrumental Data 

4.24 %-dry Oxygen concentration 

14.26 %-dry Carbon Dioxide concentration 

81.50 %-dry Nitrogen concentration 

743.7 ppmV-dry Carbon Monoxide concentration 

0.8 ppmV-wet Total Hydrocarbon concentration 

0.0 ppmV-dry Methane Concentration by GC-FID 

206.9 ppmV-dry Nitrogen Oxides concentration 

32.0 ppmV-dry Sulfur Dioxide concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y" Vm " (Pb + dH/13.6) I Tm 

Vmstd = 117.650 dscf 

3.332 dscm 

Unit NO.3 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw{std) = K2 * Vic 

Vw{std) = 16.145 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1207 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44*%C02) + (32"%02) + (28"%N2))" (1-Bws) 1 + (18"Bws) 

Ms= 28.949 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp" (dP) • (Ts/Ps"Ms)".5 

Vs = 43.572 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min "Vs ., As 

Qa = 217831.4 cfm 

6169.0 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa" (Tstd/Ts)" (Ps/Pstd)" (1-Bws) 

Qstd = 156962.8 dscfm 

4445.2 dscmm 

Page 2 of4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cant.) 

Unit No.3 

One 

Page 3 of4 

8) Total Hydrocarbon concentrations and emissions 

INPUT 

CfTHC] dry basis = C[THC] wetl(1-Bws) 

C[VOC] dry bas", = C[THC]- C[CH4] 

Carr. C[CH4] = «20.9-02% carr. value)/(20.9-actual avg. 02% value))*VOC value 

E[VOC] = (C[VOC]*Mol Wt[VOC equivalent]*60(min/hr)*Qstd(dscfm»/{Molar Vol. air*10"6) 

E[VOC Ib/MMBtu] = Cd" Fd" (20.9/(20.9·actual 02%» 

C[THC] = 0 8 ppmVw 

C[THC] = 0 9 ppmVd 

C[CH4] = 0.0 ppmVd 

C[VOC] = 0.9 ppmVd 

C[VOC] = 0.8 ppmVd corrected to 7 % 02 

Mol. wt. [THC]= 44096 Ib/lb-mole Propane 

Molar vol air= 385 scf/lb-mole @ 68 def F 

E[VOC] = 0.98 Ib/hr 

Conv Factor. 

E]VOC] = 

4.134E-08 convert ppmV to Ib/scf THC as CH4 

4.65E-04 Ib/MMBtu 

9) Nitrogen Oxides concentrations and emissions 

Carr. C[NOx] = «20.9-02% carr. value)/{20.9-actual avg. 02% value))*Avg. raw NOx value 

E[NOx] = (C{NOx]*Mol Wt[NOx]*60{min/hrtQstd(dscfm))/(Molar Vol. air"'10"6) 

E[NOx Ib/MMBtu] = Cd ... Fd ... (20.9/(20.9-actual 02%)) 

C[NOx] = 206.9 ppmVd 

C[NOx] = 172.6 ppmVd corrected to 7 % 02 

Mol. Wt. [NOxl= 46.01 Ib/lb-mole 

Molar vol alr= 

E]NOx] = 

Conv Factor. 

E]NOx] = 

385 scf/lb-mole @ 

232.86 Ib/hr 

68 

1.194E-07 convert ppmV to Ibfscf NOx 

0.306 Ib/MMBtu 

defF 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Unit No, 3 

One 

Page4of4 

10) Carbon Monoxide concentrations and emissions 

Corr. C[CO] = «20.9-02% corr, value)/(20.9-actual avg. 02% value»*Avg. raw CO value 

E[CO Ib/hr] = (C[CO]*Mol Wt[CO]*60(minfhr)*Qstd(dscfm»/{Molar Vol. air'*10"6) 

E[CO Ib/MMBtu] = Cd '* Fd * (20.9/{20.9-actual 02%» 

qCO] = 743.7 ppmVd 

C[CO] = 620.5 ppmVd corrected to 7 % 02 

Mol. WI. [CO]= 28.01 Ib/lb-mole 

Molar vol air= 

EICO] = 

Conv Factor. 

EICO] = 

385 scf/lb-mole@ 

509.56 Ib/hr 

7235E-08 convert ppmV to Ib/scf CO 

0.666 Ib/MMBtu 

11) Sulfur Dioxide concentrations and emissions 

68 def F 

Corr, C[S02] = {(20.9-02% corr. value)J{20,9-actuaJ avg. 02% value»*Avg. raw S02 value 

E(lb/MMBtu) = Cd(lb/scf) * Fd{scf/MMBtu) * [20.91 (20,9-% 02)] 

E[S02Ib/hr] = (C[S02l"'Mol Wt[S02]*60(min/hr)*Qstd(dscfm»/{Molar Vol air*10"6) 

C[S02] = 32.0 ppmV (dry) Actual Conc. 

C[S02] = 26,7 ppmVd corrected to 7 % 02 

Mol. Wt. [S02]= 64.06Ib/lb-mole 

Molar vol air= 

Conv Factor. 

EIS02] = 

EIS02] = 

385 scf/lb-mole @ 68 

1.66E-07 convert ppmV to Ib/scf S02 

0066 Ib/MMBtu 

50,14 Ib/hr 

defF 
Client 

Project No. 

Test Location 

Fuel Type 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

y= 

t = 

On = 

An = 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[02[ 

[C02[ 

[N2] 

[CO] 

[THC] 

[CH4] 

[NOx] 

[S02] 

AirNova, Inc. Page 1 of 4 

EPA Methods 1, 2. 3A, 4, 6, 7E, 10, 18 and 25A 

(Flows, 02/C02, H20, 802. NOx, CO and NMHC) 

Spruance Genco, LLC 

3333 

Unit NO.3 

Coal 

Two 

04/15/10 

1308-1615 

340.4 cc 

Emission Data 

114.615 dcf 

-0.50 in. H20 

30.37 in. Hg 

30.33 in. Hg 

29.92 in. Hg 

0.6879 in. H20 ".5 

1.39 in. H2O 

545.0 R 

656.5 R 

527.7 R 

1.01 

180 min. 

0.250 in. 

0.000341 sq. ft. 

10.300 ft. 

83.3231 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge readmg 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbllbmol)*{inHg)]". 5}/[ s*R"1 n H20] 

17.637 R/in.Hg constant 

0.047070 cu fUml 

0.0026688 in.Hg-cf/ml-R 

9755 scf/MMBtu 

Instrumental Data 

4.08 %-dry 

14.33 %-dry 

81.59 %-dry 

3249 ppmV-dry 

0.2 ppmV-wet 

0.0 ppmV-dry 

197.9 ppmV-dry 

33.5 ppmV-dry 

constant Pitot tube constant 

constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Carbon Monoxide concentration 

Total Hydrocarbon concentration 

Methane Concentration by GC-FID 

Nitrogen Oxides concentration 

Sulfur Dioxide concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y" Vm " (Pb + dH/13.6) I Tm 

Vmstd= 114.167 dscf 

3.233 dscm 

Unit No.3 

Two 

2) Volume otwater vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 .. VIc 

Vw(std) = 16.023 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.1231 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32*%02) + (28*%N2»" (1-Bws) 1 + (18*Bws) 

Ms= 28.923 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp .. Cp " (dP) .. (Ts/Ps"Ms)".5 

Vs = 42.734 fps 

6) Average actual stack gas volumetric f1owrate, Qa. 

Qa = 60 sec/min" Vs .. As 

Qa = 213644.4 cfm 

6050.4 emm 

7) Average stack gas dry volumetric f1owrate, Qstd. 

Qstd = Qa .. (Tsld/Ts) .. (Ps/Pstd) .. (1-Bws) 

Qstd = 152666.3 dscfm 

4323.5 dscmm 

Page 20f4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit NO.3 

Two 

Page 3 of4 

8) Total Hydrocarbon concentrations and emissions 

INPUT 

C[THC] dry basis = C[THC] wet/(1-Bws) 

C[VOC] d<y basis = C[THC[ - C[CH4] 

Corr. C[CH4] = ({20.9-02% corr. value)/(20.9-actual avg. 02% value))*VOC value 

E[VOC] = (C[VOC]*Mol Wt[VOC equivalent]*60(min/hr)*Qstd(dscfm»)/(Molar Vol air*10"6) 

E[VOC Ib/MMBtu] = Cd .. Fd * (20.9/(20.9-actual 02%)) 

C[THC] = 0.2 ppmVw 

C[THC] = 0.2 ppmVd 

C]CH4] = 0.0 ppmVd 

C]VOC] = 0.2 ppmVd 

qVOC] = 0.2 ppmVd corrected to 7 % 02 

Mol. Wt. [THC]= 44.096 Ib/lb-mole Propane 

Molar vol air= 385 scf/lb-mole @ 68 def F 

E[VOC] = 0 24 Ib/hr 

Conv Factor. 

E[VOC] = 

4.134E·08 convert ppmV to Ib/scf THC as CH4 

1.14E-04Ib/MMBtu 

9) Nitrogen Oxides concentrations and emissions 

Carr. C[NOx] = «20.9-02% carr. value)/(20.9-actual avg. 02% value))*Avg. raw NOx value 

E[NOx] = (C[NOxl"Mol Wt[NOx]*60(min/hr)*Qstd{dscfm))/{Molar Vol. air*10"6) 

E[NOx Ib/MMBtu] = Cd * Fd .. (20.9f(20.9-actual 02%» 

C[NOx] = 197.9 ppmVd 

C[NOx] = 163.5 ppmVd corrected to 7 % 02 

Mol. Wt. [NOx]= 4601 Ib/lb-mole 

Molar vol air= 

E[NOx] = 

Conv Factor. 

E[NOx] = 

385 scf/lb-mole @ 68 

216.64 Ib/hr 

1.194E-07 convert ppmV to Ib/scf NOx 

0.286 Ib/MMBtu 

defF 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Unit NO.3 

Two 

Page 4 of 4 

10) Carbon Monoxide concentrations and emissions 

Corr. C[CO] = «20.9-02% carr. value)/(20.9-actual avg. 02% value»*Avg. raw CO value 

E[CO Ib/hr) = (C[CO]*Mol Wt[CO]*60(min/hrYOstd(dscfm»/(Molar Vol. air'10"6) 

E[CO Ib/MMBtu] = Cd ., Fd * (20.9/(20.9-actual 02%)) 

C[CO] = 324.9 ppmVd 

C[CO] = 268.5 ppmVd corrected to 7 % 02 

Mol. Wt. [CO]= 28.01 Ibflb-mole 

Molar vol air= 

E]CO] = 

Conv Factor. 

E]CO]~ 

385 scf/lb-mole @ 

216.52 Ib/hr 

7.235E-08 convert ppmV to Ib/scf CO 

0.285 Ib/MMBtu 

11) Sulfur Dioxide concentrations and emissions 

68 def F 

Corr. C[S02] = «20.9-02% corr. value)/(20.9-actuaJ avg. 02% value))*Avg. raw S02 value 

E(lb/MMBtu) = Cd(lb/sc~' Fd(scflMMBtu) ']20.91 (20.9-% 02)] 

E[S02 Ib/hr] = (C[S02]*Mol Wt[S02]*60(min/hr)*Qstd(dscfm))/(Molar Vol. air*10"6) 

C[S02] = 33.5 ppmV (dry) Actual Conc. 

C[S02] = 27.7 ppmVd corrected to 7 % 02 

Mol. Wt. [S02]= 64.06 Ib/lb-mole 

Molar vol air= 

Cony Factor 

E[S02] = 

E[S02] = 

385 scf/lb-mole @ 68 

1.66E-07 convert ppmV to Ib/scf S02 

0.067 Ib/MMBtu 

51 06 Ib/hr 

defF 
Client 

Project No. 

Test Location 

Fuel Type 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Ps1alic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

y= 

t = 

Dn = 

An = 

Ds = 

As = 

Cp= 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

[02[ 

[C02[ 

[N2[ 

[COl 

[THC) 

[CH4J 

[NOxJ 

[S02J 

AirNova, Inc. Page 1 of4 

EPA Methods 1, 2, 3A, 4, 6, 7E, 10, 18 and 2SA 

(Flows, 02/C02, H20, 802, NOx, CO and NMHC) 

Spruance Genco, LLC 

3333 

Unit NO.3 

Coal 

Three 

04/15/10 

1724-2033 

341,9 cc 

Emission Data 

118,979 dcf 

-0.50 in. H20 

30.25 in. Hg 

30.21 in. Hg 

29.92 in. Hg 

07029 in. H20 ".5 

1.48 in. H20 

5483 R 

642_4 R 

5277 R 

1.01 

180 min. 

0.250 m. 

0.000341 sq. ft. 

10.300 ft. 

83.3231 sq. ft. 

Vol. of H20 collected 

Dry gas meier reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling lime 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitol tube coefficient 

85.49 ft[(lbllbmol)"(inHgJr.5JI[s·R"inH20J 

17.637 R/m.Hg 

0.047070 CU.ft!ml 

0.0026688 in.Hg-cf/ml-R 

9868 scf/MMBtu 

Instrumental Data 

3.98 %-dry 

14.33 %-dry 

81,69 %-dry 

463.1 ppmV-dry 

0,3 ppmV-wet 

0.0 ppmV-dry 

197.8 ppmV-dry 

31.3 ppmV-dry 

constant 

constant 

constant 

Pitot tube constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Carbon Monoxide concentration 

Total Hydrocarbon concentration 

Methane Concentration by GC-FID 

Nitrogen Oxides concentration 

Sulfur Dioxide concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1~ y'" Vm .. (Pb + dH/13.6) I Tm 

Vmstd = 117.354 dscf 

3.323 dscm 

Umt NO.3 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 .. Vic 

Vw(std) = 16.093 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1206 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32"%02) + (28*%N2))" (1-Bws) 1 + (18"Bws) 

Ms= 28 950 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp .. Cp " (dP) .., (Ts/Ps*Ms)i'.5 

Vs = 43.258 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs .., As 

Qa = 216265.1 cfm 

6124.6 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa'" (TstdfTs)" (Ps/Psld)'" (1-Bws) 

Qstd = 157766.4 dscfm 

4467.9 dscmm 

Page 2 of 4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No 3 

Three 

Page 3 of 4 

8) Total Hydrocarbon concentrations and emissions 

INPUT 

C[THCJ dry basis = C[THC] weV{1-Bws) 

C[VOC[ dry basis = C[THC] - C]CH4] 

Corr. C[CH4] = (20.9-02% carr. value)/(20.9·actual avg. 02% value»*VOC value 

E[VOCJ = (C[VOCJ*Mol WtlVOC equivalent]*60(mm/hr)~Qstd(dscfm»/(Molar Vol. air*1 0"6) 

E[VOC Ib/MMBlu] = Cd ,. Fd * (20.9/(20.9-actual 02%)) 

C[THC] = 0.3 ppmVw 

C[THC] = 0.3 ppmVd 

C[CH4] = 0.0 ppmVd 

C[VOC[ = 0.3 ppmVd 

qVOCj = 0.3 ppmVd corrected to 7 % 02 

Mol. Wt. [THC}= 44.096 Ibllb-mole Propane 

Molar vol air= 385 scf/lb-mole @ 68 def F 

E[VOC] = 0.37 lb/hr 

Conv Factor. 

E[VOC] = 

4.134E-08 convert ppmV to Ib/scf THC as CH4 

1.72E-04 tb/MMBtu 

9) Nitrogen Oxides concentrations and emissions 

Carr. C[NOx] = ((20.9-02% carr. value)/(20.9-actual avg. 02% value»*Avg. raw NOx value 

E[NOx] = (C[NOxj*Mol Wt[NOxl~60{min/hr)*Qstd(dscfm))/(Molar Vol. alr*10"6) 

E[NOx lb/MMBtu] = Cd * Fd ., (20.9/(20.9-actual 02%» 

C[NOx] = 197.8 ppmVd 

C[NOx] = 162.5 ppmVd corrected to 7 % 02 

Mol. Wt. [NOx)= 46.01 Ib/lb-mole 

Molar vol air= 385 scfllb-mole @ 68 def F 

E[NOx] = 223.76 Ib/hr 

Conv Factor. 

E[NOx] = 

1.194E-07 convert ppmV 10 Ib/scf NOx 

0288 Ib/MMBtu 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Unit No.3 

Three 

Page 4 of 4 

10) Carbon Monoxide concentrations and emissions 

Carr. ClCO] = «20.9-02% carr. value)/(20.9-actual avg. 02% value»"Avg. raw CO value 

E[CO Ib/hr] = (ClC01~Mol Wt[CO]"60(min/hr)"Qstd(dscfm»/(Molar Vol. air"10"6) 

E[CO Ib/MMBtu] = Cd" Fd" (20 9/(20.9-actual 02%» 

qCO] = 463 1 ppmVd 

ClCO] = 3804 ppmVd corrected to 7 % 02 

Mol. WI. [CO]= 28.01 Ib/lb-mole 

Molar vol aif= 

E[CO] = 

Conv Factor. 

E[CO] = 

385 scf/lb-mole @ 

318.93 Ib/hr 

7.235E-08 convert ppmV to Ib/scf CO 

0.408 Ib/MMBtu 

11) Sulfur Dioxide concentrations and emissions 

68 defF 

Carr. C[S02] = «20.9-02% carr. value)/(20.9-actual avg. 02% value»"Avg. raw S02 value 

E(lb/MMBtu) = Cd(lb/scf)" Fd(scf/MMBtu)" {20.91 (20.9-% 02)] 

E[S021b/hrJ = (ClS02]~Mol Wt[S02]*60(min/hr)*Qstd(dscfm»/(Molar Vol. air*10"6) 

C[S02] = 31.3 ppmV (dry) Actual Conc. 

ClS02] = 25.7 ppmVd corrected to 7 % 02 

Mol. WI. [S02]= 64.06Ib/lb-mole 

Molar vol air= 

Conv Factor. 

E[S02] = 

E[S02] = 

385 scf/lb-mole @ 68 

1.66E-07 convert ppmV to Ib/sct S02 

0.063 Ib/MMBtu 

49.30 Ib/hr 

def F 
3333-HCN-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

VIc = 

Vm= 

Pstatie = 

Pb = 

Ps = 

Pstd = 

dP= 

dH = 

Tm= 

Ts= 

Tstd= 

On = 

An = 

y= 

t = 

Ds= 

As= 

Cpo 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

CF= 

[02[ 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and Modified 26 

(Flows, 02/C02, H20,and HeN) 

Spruance Genco, LLC 

3333 

Unit NO.3 

One 

04/15/10 

0901-1001 

129.3 cc 

41.156 def 

Emission Data 

-0.50 in. H20 

30.44 in. Hg 

30.40 in, Hg 

29,92 in. Hg 

0.7043 in. H20 ",5 

1.700 in. H20 

522.7 R 

652.7 R 

527.7 R 

Din. 

0.000000 sq ft. 

1.02 

60 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[{lbJlbmol) .... (inHg)]".5}J[s .. R"inH20] Pitot tube constant 

17.637 R/in Hg 

0.047070 cu.ftlml 

0.0026688 in.Hg-ef/ml-R 

9862 scfJMMBtu 

7.014E-08 Ib/dsef I ppmVd 

Instrumental Data 

4.24 %-dry 

14.26 %-dry 

81.50 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCN 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y 'Vm ' (Pb + dH/13 6) /Tm 

Vmstd = 43.294 dscf 

1.23 dscm 

Unit No.3 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 ." Vic 

Vw(std) = 6.086 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

BwS = Vwstd I (Vmstd+Vwstd) 

Bws= 0123 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (1-Bws) I + (18'Bws) 

Ms= 28.92 Ib/lbmole 

5} Average stack gas velocity, Vs. 

Vs = Kp , Cp , (dP) , (Ts/Ps'Ms)'.5 

Vs = 43.58 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min * Vs ." As 

Qa = 217858.9 cfm 

6169.8 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa' (TstdlTs)' (Ps/Pstd)' (1-Bws) 

Qstd = 156921.7 dscfm 

4444.0 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

8) Hydrogen Cyanide Concentration and Emissions 

Unit No.3 

One 

M[HCN] = M[CN-](mg) , MW[HCN](mg/mmol) 1 MW[CN-](mg/mmol) 

Page 3 

C[HCN] = (M[HCN](mg) , 2.20SE-06(lb/mg) • 21.8S(scf'onHg/lbmol'R) • K1 • 10A6) 1 (MW[HCN](lbllbmol) 'Vmsl 

C[HCN](@corr 02) = C[HCN](ppmV)' [(20.9-corrected 02) 1 (20.9-octuol %02)] 

E[HCN] = M[HCN](mg)' Ostd(dscfm)' (2.20SE-06)(lb/mg)· 60(min/hr) 1 Vmstd(dscfj 

E[HCN] = C[HCN](ppmV)' Fd' CF(HCN)' (20.9/(20.9-%02)) 

< M[HCN] = 0.004 mg 

< C[HCN] = 0.003 ppmV 

< C[HCN] = 0.002 ppmV (@ 7.0 %02) 

< E[HCN] = 0.002 Ib/hr 

< E[HCN] = 2.S2E-06 Ib/MMBtu 
3333-HCN-R2 

Client 

Project No. 

Test Location 

Test RUn 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

t= 

Os = 

As= 

Cp= 

Kp = 

K1 = 

K2= 

K3= 

Fd = 

CF = 

[02J 

[C02J 

[N2J 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and Modified 26 

(Flows, 02/C02, H20,and HCN) 

Spruance Genco, LLC 

3333 

Unit NO.3 

Two 

04/15/10 

1308-1408 

141.2 cc 

42.811 def 

Emission Data 

-0.50 in. H20 

30.37 in. Hg 

30.33 in. Hg 

29.92 in. Hg 

0.6892 in. H20 ".5 

1.700 in. H20 

546.7 R 

655.4 R 

527.7 R 

o in. 

0.000000 sq ft. 

1.02 

60 min. 

10.300 ft 

Vol. of H20 collected 

Dry gas meter readrng 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge readrng 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbJlbmol)*(inHg)]".5}/[s*R"inH20] Pitot tube constant 

17.637 R/in Hg 

0.047070 cu.ftlml 

0.0026688 in.Hg-cf/ml-R 

9755 scf/MMBtu 

7.014E-08 Ib/dsefl ppmVd 

Instrumental Data 

4.08 %-dry 

14.33 %-dry 

81.59 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCN 

Oxygen concentratIon 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y 'Vm • (Pb + dH/13.6) I Tm 

Vmstd = 42.960 dscf 

1,22 dscm 

Unit No, 3 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 'Vic 

Vw(std) = 6.646 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.134 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (1-Bws) I + (18'Bws) 

Ms= 28,79 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp , Cp • (dP) , (Ts/Ps'Ms)'5 

Vs = 42.88 fps 

6) Average actual stack gas volumetric flowrate, aa. 

Oa = 60 sec/min * Vs * As 

Oa = 214358,9 cfm 

6070.6 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

Qstd = 151540.6 dscfm 

4291.6 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

8) Hydrogen Cyanide Concentration and Emissions 

Unit No.3 

Two 

M[HCN[ = M[CN-](mg) , MW[HCN](mg/mmol) 1 MW[CN-](mg/mmol) 

Page 3 

C[HCN] = (M[HCN](mg) , 2.205E-06(lb/mg) , 21.B5(scf'inHg/lbmol'R) , K1 ' 10'6) 1 (MW[HCN](Ib/lbmol) • Vmsl 

C[HCN](@corr. 02) = C[HCN](ppmV)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HCN] = M[HCN](mg)' Qstd(dscfm)' (2.205E-06)(lb/mg)' 60(min/hr) 1 Vmstd(dscD 

E[HCN] = C[HCN](ppmV)' Fd' CF(HCN)' (20.9/(20.9-%02)) 

< M[HCN] = 0.003 mg 

< C[HCN] = 0.002 ppmV 

< C[HCN] = 0002 ppmV (@ 7.0 % 02) 

< E[HCN] = 0.001 Ib/hr 

< E[HCN] = 1.B7E-06 Ib/MMBtu 
3333-HCN-R3 

Client 

Project No. 

Test Location 

Test RUn 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

t= 

Ds = 

As= 

Cp= 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

CF = 

[02[ 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and Modified 26 

(Flows, 021C02, H20,and HCN) 

Spruance Genco, LLC 

3333 

Unit NO.3 

Three 

04/15/10 

1724-1824 

139,5 cc 

Emission Data 

42.625 def 

-0.50 in. H20 

30.25 in. Hg 

30.21 in. Hg 

29.92 in. Hg 

o 7043 in. H20 ".5 

1.700 in. H20 

544.4 R 

655.9 R 

527.7 R 

o in. 

0.000000 sq. ft. 

1.02 

60 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq. ft Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)1".5}/[s*R*inH20] Pltot tube constant 

17.637 Rlin.Hg 

0047070 cu.ftlml 

0.0026688 in.Hg-cf/ml-R 

9868 scflMMBtu 

7.014E-08 Ibldsef I ppmVd 

Instrumental Data 

3.98 %-dry 

14.33 %-dry 

81.69 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCN 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y 'Vm ' (Pb + dH/13.6) I Tm 

Vmstd = 42.787 dsef 

1.21 dsem 

Unit NO.3 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 'Vic 

Vw(std) = 6.566 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws = 0.133 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (1-Bws) I + (18'Bws) 

MS= 28.80 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP) , (Ts/Ps'Ms)A.5 

Vs = 43.91 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs * As 

Qa = 219533.2 efm 

6217.2 emm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

Qstd = 154633.6 dscfm 

4379.2 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

8) Hydrogen Cyanide Concentration and Emissions 

Unit No, 3 

Three 

M[HCN[ = M[CN-[(mg)' MW[HCN](mg/mmol) 1 MW[CN-](mg/mmol) 

Page 3 

C[HCN[ = (M[HCN](mg) • 2.20SE-06(lb/mg) • 21.8S(scf"inHg/lbmol·R) • K1 • 10'6) 1 (MW[HCN[(lb/lbmol) • Vmsl 

C[HCN[(@corr. 02) = C[HCN[(ppmV)' [(20.g-corrected 02) 1 (20.9-actual %02) [ 

E[HCN[ = M[HCN](mg)' Qstd(dscfm)' (2.20SE-06)(1b/mg)· 60(min/hr) 1 Vmstd(dscD 

E[HCN[ = C[HCN[(ppmV)' Fd' CF(HCN)' (20.9/(20.9-%02)) 

M[HCN] = 0.071 mg 

C[HCN[ = 0.OS2 ppmV 

C[HCN[ = 0.043 ppmV (@ 7.0 % 02) 

E[HCN[ = 0034 Ib/hr 

E[HCN[ = 4.46E-OS Ib/MMBtu 
3333-Forma!dehyde-R1 

Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

Vlc= 

Vm= 

Pstatic = 

Pb= 

Ps= 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

y= 

t= 

On = 

An = 

Ds= 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

CF = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and RCRA Method 0011 

(Flows, 02/C02, H20. and Fonnaldehyde) 

Spruance Genco. LLC 

3333 

Richmond, Virginia 

Unit NO.3 

04/15/10 

00. 

0900-1110 

Emission Data 

256.1 cc 

79.545 dcf 

-0.50 in. H20 

30.44 in. Hg 

30.40 in. Hg 

2992 in. Hg 

0.723 in. H20" 5 

1.53 in. H20 

522.0 R 

654.7 R 

527.7 R 

0.99 

120 min. 

0.251 in. 

0.000344 sq. ft. 

10.30 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)"(inHg)] ..... 5}/[s·R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.flIml 

0.0026688 in.Hg-cf/ml-R 

9862 scf/MMBtu 

7.793E-08 Ib/dscf I ppmVd 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for CH20 

EPA Method 3A Instrumental Data 

4.24 %-dry 

14.26 %-dry 

81.50 %-dry 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Data from: 

EPA 4 

EPA 4 

EPA 2 

EPA 2 

EPA2 

EPA 4 

EPA 4 

EPA 2 

EPA2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y" Vm ~ (Pb + dH/13 6) ITm 

Vmstd = 81.301 dscf 

2.302 dscm 

Richmond, Virginia 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 12055 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 0.1291 

4) Molecular weight of Ihe stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32"'%02) + (28*%N2» r (1·Bws) 1 + (18*Bws) 

Ms= 28.843 Ib/lbmole 

5) Average stack gas velocity, Vs 

Vs = Kp * Cp'" (dP) * (Ts/Ps*Ms)".5 

Vs = 44.877 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min * Vs * As 

Qa = 224352.16 cfm 

6353.65 cmm 

7) Average stack gas dry volumetriC fJowrate, Qstd. 

Qstd = Qa * (TstdlTs) * (Ps/Pstd) ~ (1-Bws) 

Qstd = 

Qstd = 

160025.33 dscfm 

4531.92 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Richmond, Virginia 

One 

8) Formaldehyde - Concentrations and Emission Rates 

M[CH20] = sample mass (mg) 

QCH201 = M[CH20] (mg) 1 sample volume (dscm) 

QCH20 @ corr. %02] = qCH20] (ppmV) .. (20.9-Corr. %02)/{20.9-Actual %02) 

Corrected 02 Percentage = 7 % 

E[CH20] = qCH20] (mg/dscm) ~ 60 (min/hr) .. Qsld (dscmm) • (1 Ib 14 536 e+05 mg) 

E[CH20]{lb/MMBlu) = QCH20]{ppmV) CF· Fd * (20 9/20.9-%02) 

Page 3 

ComQound Sample Mass Concentration Concentration Concentration Mass Emission Mass EmissiQn 

1m9l (mq/dscm) !Immlil 'PmV@Corr.%O (lb/hr) (lb/MMBtu) 

Formaldehyde 0.00610 2.65E-03 2.12E-03 1.77E-03 1.59E-03 2.05E-OB 

NO NO NO NO NO NO 

9) Isokinecity, I. % I = [100*Ts*{K3*Vlc+({{Vm·Y)fTm)*{Pb+{dH/13.6))))] 1 (60"I*Ps·Vs·An) 

% I = 102.66 
3333-Formaldehyde-R2 

Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

y= 

t= 

On = 

An = 

Ds= 

As = 

Cp = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

CF = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A.4.and RCRA Method 0011 

(Flows, 021C02, H20, and Formaldehyde) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit No.3 

04/15/10 

Two 

1308-1518 

Emission Data 

250.5 cc 

79.504 dcf 

-0.50 in. H20 

30.37 in. Hg 

3033 in. Hg 

2992 in. Hg 

0.701 in. H20 ".5 

143 in. H20 

539.5 R 

656.7 R 

527.7 R 

0.99 

120 min_ 

0.251 in 

0.000344 sq. ft. 

10.30 ft. 

Vol. of H20 collected 

Dry gas meter reading 

StatIc pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R*mH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.fUml 

00026686 in.Hg-cf/ml-R 

9755 scf/MMBtu 

7.793E-08 Ib/dscf j ppmVd 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for CH20 

EPA Method 3A Instrumental Data 

4.08 %-dry 

14.33 %-dry 

81.59 %-dry 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Data from: 

EPA4 

EPA4 

EPA 2 

EPA2 

EPA2 

EPA4 

EPA4 

EPA2 

EPA2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm • (Pb + dH/13.6) I Tm 

Vmstd = 78.423 dsd 

2.221 dscm 

2) Volume of water vapor collected at standard conditions, Vw(std) 

Vw(std) = K2 • Vic 

Vw(std) = 11.791 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1307 

4) Molecular weight of the stack gas on a wet basIs, Ms. 

Richmond, Virginia 

Two 

Ms = [{(44*%C02) + (32*%02) + (28*%N2»;O (1-Bws) 1 + (18*Bws) 

Ms = 28.828 Ib/lbmole 

5) Average slack gas velocity, Vs. 

Vs = Kp • Cp * (dP) • (Ts/Ps;OMs)".5 

Vs = 43.650 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min· Vs • As 

Qa = 218213.76 cfm 

6179.81 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qsld = Qa" (TstdfTs) * (Ps/Pstd)" (1-Bws) 

Qstd = 154535.87 dscfm 

Qstd '" 4376.46 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Richmond, Virginia 

Two 

8) Formaldehyde - Concentrations and Emission Rates 

M[CH20] = sample mass (mg) 

C[CH20] = M[CH20] (mg) I sample volume (dscm) 

C[CH20 @ corr %02] = C[CH20] (ppmV) * (20,9-Corr. %02)/(20.9-Actual %02) 

Corrected 02 Percentage = 7 % 

E[CH20] = C[CH20] (mg/dscm)· 60 (min/hr) .. Qstd (dscmm) * (1 Ib 14.536 e+05 mg) 

E[CH20](lb/MMBtu) = C[CH20](ppmV) CF· Fd .. (20.9/20.9-%02) 

Page 3 

ComQo!.!DQ SamQle Mass Concentration Concentration Concentration Mass Emission Mass Emil:!12ion 

i!lliil (mg/dscm) (QQ!!JlQ 'pmV@Corr.%O (Iblhr) (lb/MMBtu) 

Formaldehyde 0.00472 2.13E-03 1,70E·03 141E-03 1 23E-03 1.61 E-06 

NO NO NO NO NO NO 

9) Isokinecity, I. % I = [100*Ts·(K3*Vlc+«(Vm*Y)lTm)*(Pb+(dH/13.6»))] J (60·t*Ps·Vs*An) 

%1= 10255 
3333-Formaldehyde-R3 

Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

Vlc= 

Vm= 

Pstatlc = 

Pb = 

Ps = 

Pstd '" 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

y= 

t= 

On = 

An = 

Os = 

As = 

Cp = 

Kp ::: 

K1 ::: 

K2 ::: 

K3 = 

Fd = 

CF = 

[02[ 

[C02) 

[N2) 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and RCRA Method 0011 

(Flows, 02/C02, H20, and Formaldehyde) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit NO.3 

04/15/10 

Three 

1724-1933 

Emission Data 

244-3 cc 

80.591 def 

-0.50 in. H20 

30.25 in. Hg 

30.21 in. Hg 

29.92 m. Hg 

0.710 in. H20" 5 

1.51 in. H20 

547.5 R 

660.0 R 

5277 R 

0.99 

120 min. 

0.251 in. 

o 000344 sq. ft. 

10.30 ft. 

83,3204 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft{(lb/lbmol)*(mHg)]".5}/[s*R*inH20] Pitot tube constanl 

17.637 R/in.Hg 

0.047070 cu fUml 

0.0026688 in,Hg-cf/ml-R 

9868 scf/MMBtu 

7,793E-08 Ib/dscf I ppmVd 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for CH20 

EPA Method 3A Instrumental Data 

3.98 %-dry Oxygen concentration 

14.33 %-dry Carbon Dioxide concentration 

81.69 %-dry Nitrogen concentration 

Data from: 

EPA4 

EPA4 

EPA 2 

EPA2 

EPA2 

EPA4 

EPA4 

EPA 2 

EPA2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1,o Y,o Vm "(Pb + dH/13.6) I Tm 

Vmstd = 78.028 dscf 

2.210 dscm 

Richmond, Virginia 

Three 

2) Volume of water vapor collected at standard conditions, Vw{std). 

Vw(std) = K2 ,. Vic 

Vw(std) = 11.499 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 01284 

4) Molecular weight of the slack gas on a wei baSis, Ms. 

Ms = [«44*%C02) + (32*%02) + (28"%N2»· (1-Bws) 1 + (18*Bws) 

Ms= 28.853 Ib/lbmole 

5) Average stack gas velocity, Vs 

Vs = Kp'" Cp· (dP)· (Ts/Ps·Ms)".5 

Vs = 44.344 fps 

6) Average actual stack gas volumetric flowrale, Oa. 

Oa = 60 sec/mm ,. Vs • As 

Oa = 221684.42 cfm 

6278.10 cmm 

7) Average stack gas dry volumetric flowrale, Qstd. 

Qstd = Oa;i; (TstdfTs) * (Ps/Pstd)" (1-Bws) 

Qstd = 

Qstd = 

156006.47 dscfm 

4418.10 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Formaldehyde - Concentrations and Emission Rates 

M[CH20] = sample mass (mg) 

Richmond. Virgmia 

Three 

qCH20] = M[CH20] (mg) / sample volume (dscm) 

qCH20@ corr. %021 = qCH20] (ppmV) " (20.9-Corr. %02)/(20.9-Actual %02) 

Corrected 02 Percentage = 7 % 

E[CH20] = C[CH201 (mg/dscm) * 60 (min/hr) * Qstd (dscmm) • (1 Ib /4.536 e+05 mg) 

E[CH20]ClbIMMBlu) = CiCH20](ppmV) CF' Fd' (20.9120.9-%02) 

Page 3 

Coml2oun!::l Saml2le Mass Concentration Concentration Concentration Mass Emission Mass Emi~iJi!iQD 

!mill (mg/dscm) ioo!TIlil 'I2mV@Corr.%O (Ib/hr) (lb/MMBtu) 

Formaldehyde 0.00540 2.44E-03 1.96E-03 161E-03 1.43E-03 1.86E-06 

NO NO NO NO NO NO 

9) Isokinecily, I. % I = [100*Ts*(K3·Vlc+{«Vm"Y)fTm)*{Pb+(dH/13 6»»]1 (60*I*Ps*Vs*An) 

%1= 101.07 
3333-7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit NO.3 - Metallic HAPs 

04116/10 

Parameter: 

Instrument Span (% 02l-' 

Oxygen 

21.96 

Actual Calibration Gas: Vall1ft (% 02): 

Analyzer Calibration Response (% 02).-

Analyzer Calibration Error (% Soan). 

Zero Sllstem Caligratjllo Gas 

Armarent Init Sys. Init. S!!s. Final S!!s. EiQal Sys:. 

Stack Calib. Cal Bia§. Calib. Cal. Bias 

Run Conc. Resoonse f% span) Response (% span) 

1 4,07 0.04 0.14 0.05 0.18 

0 0.00 0.05 o 18 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0,05 

0 0.00 0.00 -005 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0.05 

0 0.00 0.00 -0.05 0.00 -0 05 

0 0.00 0.00 -0,05 0.00 -0,05 

0 0.00 0.00 -0.05 0.00 -0.05 

AirNova, Inc. Page 1 

EPA Method 7E Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal't.zer Calib. Gases: !lJ2scgJ€i. 

zero IQy; !I11Sl high S't.s. Cal. Gas 

0.00 NfA 12.46 21.96 12.46 

0.01 NfA 12.44 21.81 12.44 

0.05 0.00 -0.09 -0.68 

Uruica1e Sllstem Calibmti!:![l Gas 

Ca/ib. Init. Sys. Init. :S:vs:. Final S'i.,S: Final S!!s. Ca/ib. Actual 

Drift Calib. Cal. Bias Calib. (;.13.1. Bias Drift Stack 

f% span) Respon§.e (% span) Response (% span) (% span) Conc. 

0.05 12.43 -0.05 12.33 -0,50 -0.46 4.07 

-0.23 12.33 -0,50 0.00 -56.65 -56.15 -0.05 

0.00 0.00 -56.65 0.00 -56.65 0.00 ERR 

0.00 000 -56.65 0.00 -56.65 0.00 ERR 

0.00 0.00 -56.65 0.00 -56.65 0.00 ERR 

0.00 0.00 -56.65 0.00 -56.65 0.00 ERR 

0.00 0.00 -56.65 0.00 -5665 0.00 ERR 

0.00 0.00 -56.65 0.00 -56.65 0.00 ERR 

0.00 0.00 -56.65 0.00 -56.65 0.00 ERR 

0.00 0.00 -56.65 0.00 -56.65 0.00 ERR 

0.00 0.00 -56.65 0.00 -56.65 0.00 ERR 

0.00 0.00 -56.65 0.00 -56.65 0.00 ERR 
3333-7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, llC 

3333 

Unit No_ 3 - Metallic HAPs 

04/16/10 

Parameter' 

Instrument Span (% C02): 

Carbon Dioxide 

17.83 

Actual Calibration Gas Value (% C02): 

AnaNzer Calibration Response (% C02): 

AnaNzer Calibration Error (% Soan): 

Zero S),stem Caligratillo Gall 

AIJQarent Init. S\::':S. Init. S\::':S. Final S\:::s_ Final S\::':S 

Stack Calib. Cal. Bias Calib. Cal. Bias 

Run Conc_ Response (% sQan) Response (% span! 

14.62 0.05 0.28 0.02 0,11 

0 0.00 0.02 0_11 0.00 0.00 

0 0.00 0.00 0.00 0.00 0.00 

0 000 0.00 0.00 000 0_00 

0 0,00 0.00 0.00 0.00 0.00 

0 0.00 0.00 0.00 0.00 0.00 

0 0.00 000 0.00 0.00 0.00 

0 0.00 0.00 0.00 0.00 0_00 

0 0.00 0.00 000 0.00 0.00 

0 0.00 0_00 0.00 0.00 0.00 

0 0.00 000 0.00 0.00 0.00 

0 0.00 0.00 0.00 0.00 0.00 

AirNova, Inc. Page 2 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal't.zer Cf!/ib. Gg,s:§:~ UQscale 

zero fow mid high S't.s, Cal. Gas 

0.00 NfA 12.39 17.83 12_39 

0.00 NfA 12.40 17.91 12.40 

0.00 0.00 0.06 0.45 

Up'scal§: S),stem Calib[aiillo Gas 

Calib. Init. S\::':S. Init. S):::s. Final S\::':S_ Final S\::':S. f!..alLtL Actual 

Drift Calib, Cal_ BiiJ.~ Calib. Cal. Bias Drift Stack 

(% span) Re,s:ponse (% span! Response (% span! (% sQan) Conc. 

-0.17 12.32 -0.45 12.23 -0_95 -0.50 14.76 

-0.11 12.23 -0.95 0.00 -69.55 -68.59 -0.02 

0.00 0.00 -69.55 0.00 -69.55 0.00 ERR 

0_00 000 -69.55 0.00 -69.55 0.00 ERR 

0.00 0,00 -69.55 0.00 -69.55 000 ERR 

0.00 0.00 -69.55 0.00 -69.55 0_00 ERR 

0.00 0_00 -69.55 0.00 -69.55 0.00 ERR 

0.00 0.00 -69.55 0.00 -69_55 0,00 ERR 

0.00 0.00 -69.55 0.00 -69.55 0.00 ERR 

0.00 0.00 -69.55 0.00 -69.55 0.00 ERR 

0.00 0_00 -69.55 0,00 -69.55 0.00 ERR 

0.00 0.00 -69.55 0.00 -6955 0_00 ERR 
3333-7E 

Client 

Project No. 

Test Location 

Test Date 

Spl1.Jance Genco, LLC 

3333 

Unit No.3 - Metallic HAPs 

04/19/10 

Parameter: 

Instrument Span f% 02): 

Oxygen 

21.96 

Actual Calibration Gas Value f% 02).-

Analyzer Calibration Response (% 02): 

Analyzer Calibration Error f% Span): 

Zero S~stem CalibratjO!l Gas 

AQJl.arent Init. S!!,s. Init. S!!,s. Final S!!,s. Fmal SI::§. 

Stack Calib. Cal. BlfI.§. Calib. Cal. Bias 

Run Cone. Response f% span) Response (% span) 

2 3.87 0.06 0.18 0.05 0.14 

3 5_01 0,05 0.14 0.05 0.14 

0 0.00 0.05 0,14 0_00 -0_09 

0 0.00 0_00 -0.09 0.00 -0.09 

0 0.00 0.00 -0.09 0.00 -0.09 

0 0.00 0.00 -0.09 0.00 -0.09 

0 0.00 0.00 -009 0.00 -0.09 

0 0.00 0.00 -0_09 0.00 -0.09 

0 0.00 0,00 -0.09 0.00 -0.09 

0 000 0.00 -0.09 000 -0.09 

0 0.00 0.00 -0.09 0.00 -0.09 

0 0.00 0.00 -0.09 0.00 -0.09 

AirNova, Inc. Page 1 

EPA Method 7E Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Analvzer Calib. Gases upscale 

zero low mid high S!!,s. Cal. Gas 

0.00 N/A 12.46 21.96 12.46 

0.02 N/A 12.45 21.89 12.45 

0.09 0.00 -0.05 -0_32 

Uj;!scale S~stem Calib[atioD Gas 

Calib. Init. S)!s. Init. S)!s. Final SI",S: Final S)!s. Calib. Actual 

Drift Calib. Cal. Bias Calib Cal. Big:! Drift Stack 

f% §.Df!.n! Response (% span) Response (% span) (% span) Cone. 

-005 12.48 0_14 12.44 -0.05 -0.18 3.83 

0.00 12.44 -0.05 12.40 -0.23 -0.18 5.00 

-0.23 12.40 -0.23 0.00 -56_69 -56.47 -0.05 

0.00 0.00 -56,69 0.00 -56.69 0.00 ERR 

0.00 0.00 -56.69 0,00 -56.69 0.00 ERR 

0.00 0.00 -56.69 0_00 -56.69 0.00 ERR 

0.00 0.00 -56_69 0.00 -56.69 0.00 ERR 

0.00 0.00 -56.69 0.00 -56.69 0.00 ERR 

0.00 0.00 -56.69 0.00 -56.69 0.00 ERR 

0.00 0.00 -56.69 0.00 -5669 0.00 ERR 

0.00 0.00 -5669 0.00 -56.69 000 ERR 

000 0.00 -56.69 0.00 -56.69 0.00 ERR 
3333-7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco. LLC 

3333 

Umt No 3 - Metallic HAPs 

04f19/10 

Parameter: 

Instrument Span (% C02): 

Carbon Dioxide 

1783 

Actual Calibration Gas Value t% C02): 

AnalYZer Calibration Response f% C02): 

Analyzer Calibration Error f% Span): 

Zero Sy:stem Calibration Gas 

AQparent Ini!. Sk:s. Init. Sk:s. Final Svs. Final Sys. 

Stack Calib. Cal. Bias Calib. Cal. Bias 

Run Cone. Response (% span) Response t% span) 

2 15.00 0.00 -0.06 0.05 0.22 

3 1393 0.05 0.22 0.00 -0,06 

0 0.00 0.00 -0.06 0,00 -0.06 

0 0.00 0.00 -0.06 0.00 -0.06 

0 0.00 0.00 -0.06 0.00 -0.06 

0 0.00 0.00 -0.06 0.00 -0.06 

0 0.00 000 -006 000 -0.06 

0 0.00 0.00 -0.06 0.00 -0.06 

0 0.00 0.00 -0.06 0.00 -0.06 

0 0.00 0.00 -0.06 0.00 -0.06 

0 0.00 000 -0.06 0,00 -0.06 

0 0.00 0.00 -0.06 0.00 -0.06 

AirNova, Inc. Page 2 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Ana/k:zfl:r Qalib. Gases Upscale 

zero fow mid high Sk:s. Cal. Gas 

0,00 NfA 12.39 17.83 12.39 

0.01 NfA 12.38 17.83 12.38 

0.06 0.00 -0.06 0.00 

Ugscale Sy:stem Calibration Gas 

Ca/ib. Inil. Svs. Init. SJ@. Final Sk:s. Final Sys. Calib. Actual 

Drift Calib. Cal. Bias Calib. Cal. Bia§. Drift Stack 

f% .soan) Response f% span) Response r% span) (% span) Cone. 

0.28 12.37 -0.06 12,32 -0.34 -0.28 15.06 

-0.28 12.32 -0.34 12,44 0.34 0.67 13.94 

0.00 12.44 0.34 0.00 -69,43 -69.77 0.00 

0.00 0.00 -69.43 0.00 -69,43 0.00 ERR 

0.00 0.00 -69,43 0.00 -69.43 000 ERR 

0.00 0.00 -69.43 0.00 -69.43 0.00 ERR 

0.00 0.00 -69,43 0.00 -69,43 0.00 ERR 

0.00 0,00 -69,43 0.00 -69,43 0.00 ERR 

0.00 0.00 -69.43 0.00 -6943 0.00 ERR 

0.00 0.00 -69.43 0.00 -69.43 0.00 ERR 

0.00 0.00 -69.43 0.00 -69.43 0.00 ERR 

0.00 0.00 -69.43 0.00 -69.43 0.00 ERR 
3333-PM2.5-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

PstatlC = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

Dn = 

An= 

y= 

tr = 

Ds= 

As= 

Cp = 

Kp = 

K1 = 

K2= 

K3 = 

C1= 

C2 = 

C3 = 

C4= 

C5= 

C6= 

61 = 

Fd = 

[02[ 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Methods 1,2,3,4, OTM 27 and 202 

(Flows, 02/C02, H20, PM2.S and CPM) 

Spruance Genco, LLC 

3333 

Unit NO.3 

One 

04116110 

0840-1448 

Emission Data 

374 cc Vol. of H20 collected 

127745 dcf Dry gas meter reading 

-0.50 in H20 Static pressure 

30.07 in. Hg Barometric pressure 

30.03 in Hg Stack pressure 

29 92 in. Hg EPA Standard pressure 

0.7005 in. H20 11.5 Average sq rt delta P 

0.390 in. H20 Average draft. gauge reading 

542.5 R Average meter temperature 

650,6 R Average stack temperature 

527.7 R Standard temperature 

0.180 in. Nozzle diameter 

0.000177 sq. ft Area of nozzle orifice 

0.99 Meter calibration factor, gamma 

357.2 min. Duration of sampling time 

10.300 ft. Diameter of stack 

83.32 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbllbmolt(inHg)]'.5)/[s·R'inH20] Pilot tube constant 

17637 Rlin.Hg constant 

0.047070 cu ftlml constant 

0.0026688 in.Hg-cf/ml-R constant 

-150.3162 upoise Viscosity constant 

13.4622 upoise/R"0.5 Viscosity constant 

3861530 upoise/R"2 Viscosity constant 

0.591123 upoise Viscosity constant 

91.9723 upoise Viscosity constant 

1.51761 E-05 upoise/R"2 Viscosity constant 

0.15625 Constant 

9862 dscf/MMBtu 

Instrumental Data 

4.07 %-dry 

14.76 %-dry 

81.17 %-dry 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

Unit No 3 

One 

1) Dry Gas Volume at standard conditions, Vms (EPA OTM 27 Equation 27) 

Vms =K1' Y • Vm ' (Pb + dH/13.6) I Tm 

Vms= 123.744 dscf 

3.504 dscm 

2) Dry gas sampling rate at standard conditions, QsST (EPA OTM 27 Equation 28). 

OsST = Vms I tr 

OsST= 0346 dscfm 

0.010 dscm I min. 

3) Volume of water vapor condensed at standard conditions, Vws (EPA aTM 27 Equation 29). 

Vws = K2 "Vlc 

Vws= 17.604 scf 

4) Decimal fraction of moisture by volume in stack gas, Bws (EPA aTM 27 Equation 30). 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.125 

5) Mo/ecu/arweight of the stacl, gas on a wet basis, Mw (EPA aTM 27 Equations 1 &2). 

Mw = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) I + (1S'Bws) 

Mw = 28.96 Ib/lbmole 

6) Gas sampling rate at actual Cyclone conditions, Os (EPA aTM 27 Equation 31). 

Os = (Pstd/Tstd),OsST' (1/(1-Bws))'(Ts/Ps) 

Os = 0.486 acfm 

7) Average stacl{ gas velocity, Vs (EPA aTM 27 Equation 11) 

Vs = Kp' Cp' (ave 01 (dPyO.5)' (Ts/Ps·MwYO.5 

Vs = 43.51 Ips 

8) Average actual stack gas volumetric f/owrate, Oa. 

Oa = 60 sec/min'" Vs .., As 

Oa = 217499.9 cfm 

6159.6 cmm 

9) Average stack gas dry standard volumetnc f/owrate, Ostd. 

Ostd = Oa • (Tstd/Ts) , (Ps/Pstd) , (1-Bws) 

Ostd = 155022.9 dscfm 

4390.2 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cant.) 

Unit No.3 

One 

Page 3 

10) Analytical data 

Cvclone aod Filter Fractions (EPA Method OTM 27); 

M1) Instack quartz microfibre filter, <2.Sum 

0.0163 9 PM <2.5 filter net wt 

M2-4) Cyclone acetone washes 

0.0000 9 actual mass of >2.5, Containers 2&3 

0.0029 9 actual mass of <1=2.5um, Container 4 

0.0000 9 acetone blank net wt 

o mL volume 

100 mL volume 

100 mL volume 

0.0000 9 blank corrected mass of >2.Sum, Containers 2&3 = M2&M3 

0.0029 9 blank corrected mass of </=2.5um, Container 4 = M4 

Condensible Particulate Matter (CPM) Fractions (EPA Method 202); 

MS) Back Half Aqueous Wash 

0.0087 9 actual sample mass 

0.0003 9 aqueous blank mass 

300 ml blank vol. 

300 ml Sample volume 

0.0064 9 condensible aqueous PM 

M6) Back Half MeCI2 Extraction Portion 

0.0015 g extraction net wt 

0.0000 g MeCI2 blank net wt 

300 ml blank vol 

300 ml MeCI2 extraction volume 

00015 9 condensible organic PM 

M[CPMl = blank corrected mass of Tolal CPM, M5 & M6 (in grams) 

M[CPM[ = 0.0099 9 CPM 

11) Particulate Concentrattons, C (EPA OTM27 and EPA 202). 

Equation 43 

Equation 45 

EPA 202 

C[totalsus[ = M1 (g)+M2(g)+M3(g)+M4(g)'15.43(grainslg)Nmstd(dscf)= 

C[PM2.5sus] = M1 (g) + M4(g) '1543(grainslg) I Vmstd(dscD = 

C[CPM] = M[CPM](g) , 1543(grainslg) I Vmstd(dscf) 

where 15.43 = 7000/453592·1000 

C[PMtotal] = C[PMtotalsus] + C[CPM] 

C[PM2.5total] = C[PM2.5sus] + CiCPM] 

0.0024 gr/dscf PMsus 

0.0024 gr/dscf PM2. 5sus 

0.0012 gr/dscfCPM 

0.0036 gr/dscfTolal PM 

0.0036 gr/dscf Total PM2.5 
Client 

Project No. 

Spruance Genco, LLC 

3333 

12) Particulate Emission Rates, E. 

Test Location 

Test Run 

Calculations (cant.) 

Unit No.3 

One 

E[lb/hr] = C[](gr/dscf) • (1 Ib/7000 gr) • Ostd(dscfm) • 60(min/hr) 

E[lb/MMBtu] = C[](gr/dscf)' (1 Ib/7000 gr)' Fd(dscf/MMBtu)' (20.9/20.9·%02) 

E[totalsus] = 3.18 Ib/hr total sus PM 

E[totalsus] = 0.0042 Ib/MMBtu total sus PM 

E[PM2.5sus] = 3.18 Ib/hr PM2.5sus = 66.0 % of Total PM2 5 

E[PM2.5sus] = 00042 Ib/MMBtu PM2.5sus = 

E[CPM] = 1.64 Ib/hr CPM 34.0 % of Total PM2.S 

E[CPM] = 0.0022 Ib/MMBtu CPM 

E[PMtotal] = 4.82 Ib/hr total PM 

E[PMtotal] = 0.0063 Ib/MMBtu total PM 

E[PM2.5total] = 4.82 Ib/hr total PM2.S 

E[PM2.5total] = 0.0063 Ib/MMBtu total PM2.5 

13) Percent Isokinectic Sampling, %1 (EPA OTM 27 Equation 40). 

% I = [100*Ts~ms"Pstd) I (60"Vs*tr*An*Ps*(1-Bws)*Tstd) 

% I = 10S.37 

14) Stack Gas Viscosity, u (EPA OTM 27 Equation 3). 

u = C1 + C2"'(Ts"0.5) + C3*(Ts"-2) + C4·(%02) - (C5*Bws) + C6·Bws*(TsIl2) 

u = 193.9 micropoise 

Page4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test location 

Test Run 

Calculations (cont.) 

15) Test Condition Reynolds number, Nre (EPA OTM 27 Equation 8). 

Nre = 8.64'10'5'(Ps'MwlTs)·(Qslu) 

Nre = 2895 

Unit No.3 

One 

16) Actual Particle Cut Diameter for Cyclone I, D50 (EPA OTM 27 Equation 32). 

050 = B1 • ([ Ts 1 (Mw' Ps)]A2091)' ((u 1 Qs)' 7091) 

050 = 10.28 um 

17) Actual Cunningham Correction Factor based on Dp = 25um, C (EPA OTM 27 Equation 4). 

C = 1+ 0 0057193' (ul(Ps'Op))' (TsIMw),0.5 

C = 1.0700 

18) Initial 050 for Cyclone IV based on test condition Reynolds number from OTM 27 Equation 8. 

If Nre < 3162, use Equation 33 which results in 050 for IV = 

If Nre >= 3162, use Equation 34 which results In 050 for iV = 

Initial 050 

2.25 

2.18 

Equation 33 

Equation 34 

Equation 35 

050 = 0.0024302'(uIQs),1.1791'( 1IC)'0.5·(Tsl(Ps·Mw))'0.6790 

050 = 0.019723·(uIQs)'0.S05S'(1IC),OS(T sl(Ps·Mw))'0.305S 

Cr = 1 + 0.0057193·(ul(Ps'050)),(TsIMw)'0.5 

19) Re-established 050 for Cyclone IV, 050-1. 

Page 5 

Re-established 

Cunningham, Cr 

1.0778 

1.0805 

If Nre < 3162, use Equation 36 which results in 050 for IV = 

If Nre >= 3162, use Equation 37 which results in 050 for iV = 

Recalculated Cut oiam, 050-1 

2.24 

2.17 

Equation 36 

Equation 37 

050-1 = 0.0024302·(uIQs),1.1791·(1ICryO.5'(Tsl(Ps·Mw))'0.6790 

050-1 = 0.019723'(uIQs)'O S05S'(1ICr)'OS(Tsl(Ps'Mw))'O.305S 

19) Establishing "Z" value, Z. 

If Equation 36 was used, then 

If Equation 37 was used, then 

Z = 050-1 1 050 = 

Z=D50-11050= 

If 0.99 < Z < 1.01, then D50-1 is best cut diameter estimate. 

If 0.99 > Z > 1 01, then repeat calcs for Cr using 050-1 

1.00 

1 00 
3333-PM2.5-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

Dn = 

An = 

y= 

tr = 

Os = 

As= 

Cp = 

Kp= 

K1 = 

K2= 

K3= 

C1 = 

C2= 

C3= 

C4= 

C5= 

C6= 

81 = 

Fd = 

[02[ 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Methods 1,2,3,4, OlM 27 and 202 

(Flows, 02/C02, H20, PM2.5 and CPM) 

Spruance Genco, LLC 

3333 

Unit NO.3 

Two 

04119110 

0730-1349 

Emission Data 

376.8 cc Vol. of H20 collected 

125.617 dcf Dry gas meter reading 

-0.50 in. H20 Static pressure 

30.10 in. Hg Barometric pressure 

30.06 in. Hg Stack pressure 

29.92 in. Hg EPA Standard pressure 

0.7218 in. H20 ".5 Average sq.rt delta P 

0.390 in. H20 Average draft gauge reading 

525,1 R Average meter temperature 

647.4 R Average stack temperature 

527.7 R Standard temperature 

0.180 in. Nozzle diameter 

0.000177 sq. ft. Area of nozzle orifice 

0.99 Meter calibration factor, gamma 

366.55 min. Duration of sampling time 

10.300 ft, Diameter of stack 

83.32 sq. ft. Cross sectional area of stack 

0,84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)l".5}/[s*R*inH20] Pitot tube constant 

17.637 R/in.Hg constant 

0.047070 cu.ftlml constant 

0.0026688 in.Hg-cffml-R constant 

-150.3162 upolse Viscosity constant 

13.4622 upoisefR"0.5 Viscosity constant 

3861530 upOlse/R"2 Viscosity constant 

0,591123 upoise Viscosity constant 

91.9723 upolse Viscosity constant 

1.51761 E-05 upoise/R"2 Viscosity constant 

0.15625 Constant 

9755 dscf/MMBtu Fuel Factor 

Instrumental Data 

3.83 %-dry 

15.06 %-dry 

81.11 %-dry 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruanee Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

Unit No.3 

Two 

1) Dry Gas Volume at standard conditions, Vms (EPA OTM 27 Equation 27). 

Vms =K1* Y * Vm * (Pb + dH/13.6) I Tm 

Vms = 125.844 dsef 

3.564 dscm 

2) Dry gas sampling rate at standard conditions, QsST (EPA OTM 27 Equation 28). 

QsST = Vms / tr 

asST= 0.343 dscfm 

0.010 dscm / min. 

3) Volume of water vapor condensed at standard conditions, Vws (EPA OTM 27 Equation 29). 

Vws = K2 * Vic 

Vws= 17.736 sef 

4) Decimal fraction of moisture by volume In stack gas, Bws (EPA OTM 27 Equation 30). 

Bws = Vwstd , (Vmstd+Vwstd) 

Bws = 0.124 

5) Molecular weight of the stack gas on a wet basis, Mw (EPA OTM 27 Equations 1 &2). 

Mw = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) [+ (1S'Bws) 

Mw = 2901 Ib/lbmole 

6) Gas sampling rate at actual Cyclone conditions, Os (EPA OTM 27 Equation 31). 

as = (Pstd/Tstd),asST' (1/(1-Bws))'(Ts/Ps) 

Qs = 0.478 aefm 

7) Average stack gas velocity, Vs (EPA OTM 27 Equation 11) 

Vs = Kp , Cp , (ave of (dP)'O.5) , (Ts/Ps'Mw),O.5 

Vs = 44.65 fps 

8) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min * Vs ,. As 

Qa = 223236.5 cfm 

6322.1 cmm 

9) Average stack gas dry standard volumetric f/owrate, Qstd. 

astd = aa' (Tstd/Ts)' (Ps/Pstd)' (1-Bws) 

Qstd = 160256.3 dscfm 

4538.5 dsemm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.3 

Two 

Page 3 

10) Analytical data 

Cvclone and Filter Fractions (EPA Method OrM 27). 

M1) Instack quartz mlcrofibre filter, <2.5um 

0.0057 9 PM <2.5 filter net wt 

M2-4) Cyclone acetone washes 

0.0000 9 actual mass of >2.5, Containers 2&3 

0.0030 9 actual mass of </=2.5um, Container 4 

0.0000 9 acetone blank net wt 

o mL volume 

100 mL volume 

100 mL volume 

0.0000 g blank corrected mass of >2.5um, Containers 2&3 = M2&M3 

0.0030 9 blank corrected mass of </=2.5um, Container 4 = M4 

Condensible Particulate Matter (CPM) Fractions (EPA Method 202). 

M5) Back Half Aqueous Wash 

0.0064 9 actual sample mass 

0.0003 9 aqueous blank mass 

300 ml blank vol. 

300 ml Sample volume 

0.0061 9 condensible aqueous PM 

M6) Back Half MeCI2 Extraction Portion 

0.0019 9 extraction net wt 

0.0000 9 MeCI2 blank net wt 

300 ml blank vol. 

300 ml MeCI2 extraction volume 

0.0019 9 condensible organic PM 

M[CPM] = blank corrected mass of Total CPM, M5 & M6 (in grams) 

MICPM] = 0.0080 9 CPM 

11) Particulate Concentrations, C (EPA OTM27 and EPA 202). 

Equation 43 

Equation 45 

EPA 202 

Cltotalsus] = M 1 (g)+M2(g)+M3(g)+M4(g)'1543(grains/g)Nmstd( dscf)= 

C[PM2 5sus] = M1 (g) + M4(g) , 15.43(grains/g) 1 Vmstd(dscD = 

C[CPM] = MICPM](g) , 15.43(gralns/g) 1 Vmstd(dscD 

where 15.43 = 7000/453592*1000 

C[PMtotal] = C[PMtotalsus] + C[CPM] 

C[PM2.5total] = C[PM2.5sus] + C[CPM] 

0.0011 gr/dscf PMsus 

0.0011 gr/dscf PM2.5sus 

0.0010 gr/dscf CPM 

0.0020 gr/dscf Total PM 

0.0020 gr/dscf Total PM2.5 
Client 

Project No. 

Spruance Genco, LLC 

3333 

12) Particulate Emission Rates, E. 

Test Location 

Test Run 

Calculations (cont.) 

Unit No, 3 

Two 

E[lb/hr[ = C[[(gr/dscD • (1 Ib/7000 gr) • Qstd(dscfm) • 60(min/hr) 

E[lb/MMBtu] = C[](gr/dscD' (1 Ib/7000 gr)' Fd(dscf/MMBtu)' (20.9/20.9-%02) 

E[totalsusj = 1.47 Ib/hr total sus PM 

E[totalsus] = 0.0018 Ib/MMBtu total sus PM 

E[PM2.5sus] = 1.47 Ib/hr PM2.5sus = 52,1 %ofTotalPM2.5 

E[PM2.5sus] = 0.0018 Ib/MMBtu PM2.Ssus = 

E[CPM] = 1.35 Ib/hr CPM 479 % of Total PM2.5 

E[CPM] = 0.0017 Ib/MMBtu CPM 

E[PMtotal] = 2.81 Ib/hr total PM 

E[PMtotal] = 0.0035 Ib/MMBtu total PM 

E[PM2.5total] = 2.81 Ib/hr total PM2.5 

E[PM2.5total] = 0.0035 Ib/MMBtu total PM2.S 

13) Percent Isokinectic Sampling, %1 (EPA OTM 27 Equation 40). 

% I = [100'Ts'Vms'Pstd) 1 (60·Vs·tr·An·Ps·(1-Bws)'Tstd) 

% I = 101.01 

14) Stack Gas Viscosity, U (EPA OTM 27 Equation 3). 

u = C1 + C2*(TsI\0.5) + C3 .... (TsA-2) + C4*(%02) - (CS*Bws) + C6*Bws .... (TsA2) 

u = 193,1 micropoise 

Page 4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

15) Test Condition Reynolds number, Nre (EPA OTM 27 Equation 8). 

Nre = S.64*10115*(Ps*MwlTs)*(Qs/u) 

Nre = 2883 

Unit NO.3 

Two 

16) Actual Particle Cut Diameter for Cyclone /, 050 (EPA OTM 27 Equation 32) 

050 = 81 • ([ Ts 1 (Mw' Ps)!' 2091)' ((u 1 Os)'.7091) 

050 = 10.35 um 

17) Actual Cunningham Correction Factor based on Op = 2.5um, C (EPA OTM 27 Equation 4). 

C = 1+ 0 0057193' (ul(Ps'Op))' (TsIMwyO.5 

C = 10694 

18) Initial 050 for Cyclone IV based on test condition Reynolds number from OTM 27 Equation 8 

If Nre < 3162. use Equation 33 which results in 050 for IV = 

If Nre >= 3162, use Equation 34 which results in 050 for iV = 

Initial 050 

2.27 

2.19 

Equation 33 

Equation 34 

Equation 35 

050 = 0.0024302'(uIOs)'1.1791'(11C)'0.5'(Tsl(Ps'Mw)),0.6790 

050 = 0.019723'(uIOs)'0.8058'(1ICYO 5'(Tsl(Ps'Mw))'0.3058 

Cr = 1 + 0.0057193'(ul(Ps'050)),(TsIMwYO.5 

19) Re-establlshed 050 for Cyclone IV, 050-1. 

Page 5 

Re-established 

Cunningham. Cr 

1.0764 

1.0792 

If Nre < 3162, use Equation 36 which results in 050 for IV = 

If Nre >= 3162, use Equation 37 which results in 050 for iV = 

Recalculated Cut Oiam. 050-1 

2.26 

218 

Equation 36 

EquatIOn 37 

050-1 = 0.0024302'(uIOsY1.1791'(1ICr)'0.5'(Tsl(Ps·Mw)),0.6790 

050-1 = 0.019723'(uIOs)'0. 805S'(1ICrYO.5'(Tsl(Ps'Mw))'0 3058 

19) Establishing "Z" value, Z. 

If Equation 36 was used, then 

If Equation 37 was used, then 

Z = 050-1 1 050 = 

Z=050-11050= 

If 0.99 < Z < 1.01, then 050-1 is best cut diameter estimate. 

If 0.99 > Z > 1.01, then repeat cales for Cr using D50-1 

1.00 

1 00 
3333-PM2.5-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

Dn = 

An = 

y= 

tr = 

Ds = 

As = 

Cp= 

Kp = 

K1 = 

K2 = 

K3 = 

C1= 

C2 = 

C3 = 

C4= 

C5= 

C6= 

61 = 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3,4, OTM 27 and 202 

(Flows, 021C02, H20, PM2.5 and CPM) 

Spruance Genco, LLC 

3333 

Unit NO.3 

Three 

04/19/10 

1448-2103 

Emission Data 

355.8 cc Vol. of H20 collected 

123,826 dcf Dry gas meter reading 

-0.50 in. H20 Static pressure 

30,03 in Hg Barometric pressure 

29.99 in. Hg Stack pressure 

2992 in Hg EPA Standard pressure 

0.6956 in, H20 ".5 Average sq.rt delta P 

0.390 in. H20 Average draft gauge reading 

538.5 R Average meter temperature 

646.2 R Average stack temperature 

527.7 R Standard temperature 

0.180 in. Nozzle diameter 

0.000177 sq. ft. Area of nozzle orifice 

o 99 Meter calibration factor, gamma 

353.29 min Duration of sampling time 

10.300 ft. Diameter of stack 

83.32 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbllbmolt(inHg)]'.5)I[s·R·inH20] Pito11ube constan1 

17,637 R/in.Hg constant 

0,047070 cU.fUml constant 

0.0026688 in,Hg-cf/ml-R constant 

-150.3162 upolse Viscosity constant 

13.4622 upoise/RAO.5 Viscosity constant 

3861530 upoise/RA2 Viscosity constant 

0.591123 upoise Viscosity constant 

91.9723 upoise Viscosity constant 

1.51761 E-05 upoise/RA2 Viscosity constant 

0,15625 Constant 

9868 dscf/MMBtu 

Instrumental Data 

5.00 %-dry 

13.94 %-dry 

81.06 %-dry 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruanee Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

Unit No 3 

Three 

1) Dry Gas Volume at standard conditions, Vms (EPA OTM 27 Equation 27), 

Vms =K1* Y ." Vm ." (Pb + dH/13.6) I Tm 

Vms = 120.678 dscf 

3.418 dscm 

2) Dry gas sampling rate at standard conditions, QsST (EPA OTM 27 Equation 28). 

QsST = Vms / tr 

QsST = 0.342 dscfm 

0.010 dscm J min, 

3) Volume of water vapor condensed at standard conditions, Vws (EPA OTM 27 Equation 29). 

Vws = K2 "'Vlc 

Vws= 16.747 sef 

4) Decimal fraction of moisture by volume in stack gas, Bws (EPA OTM 27 Equation 30). 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 0.122 

5) Molecular weight of the stack gas on a wet basis, Mw (EPA OTM 27 Equations 1 &2). 

Mw = [ ((44'%C02) + (32'%02) + (2S'%N2)) , (1-Bws) I + (1S'Bws) 

Mw = 28.92 Ib/lbmole 

6) Gas sampling rate at actual Cyclone conditions, OS (EPA OTM 27 Equation 31). 

Qs = (PstdlTstd)'QsST' (1/(1-Bws))'(Ts/Ps) 

Qs = 0.475 acfm 

7) Average stack gas velocity, Vs (EPA OTM 27 Equation 11). 

Vs = Kp' Cp' (ave 01 (dPyO.5)' (Ts/Ps'MwyO.5 

Vs = 43.12 Ips 

8) Average actual stack gas volumetric fJowrate, Oa. 

Oa = 60 sec/min" Vs .. As 

Oa = 215568,9 cfm 

6104.9 cmm 

9) Average stack gas dry standard volumetric fJowrate, Ostd. 

Qstd = Qa' (TstdlTs)' (Ps/Pstd)' (1-Bws) 

Qstd = 154963.4 dscfm 

4388,6 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit NO.3 

Three 

Page 3 

10) Analytical data 

Cvclone and FOter Fractions (EPA Method OTM 27): 

M1) Instack quartz microfibre filter, <2.5um 

0.0045 9 PM <2.5 filter net wt 

M2-4) Cyclone acetone washes 

0.0000 9 actual mass of >2.5, Containers 2&3 

0.0024 9 actual mass of <1=2.5um, Container 4 

0.0000 9 acetone blank net wt 

o mL volume 

100 mL volume 

100 mL volume 

0.0000 9 blank corrected mass of >2.5um, Containers 2&3 = M2&M3 

0.0024 9 blank corrected mass of <1=2.5um, Container 4 = M4 

Condensible Particulate Matter (CPM) Fractions (EPA Method 202): 

M5) Back Half Aqueous Wash 

0.0107 9 actual sample mass 

0.0003 9 aqueous blank mass 

300 ml blank vol. 

300 ml Sample volume 

0.0104 9 condensible aqueous PM 

M6) Back Half MeCI2 Extraction Portion 

0_0012 g extraction net wt 

0_0000 9 MeCI2 blank net wt 

300 ml blank vol. 

300 ml MeCI2 extraction volume 

0.0012 9 condensible organic PM 

M[CPM] = blank corrected mass of Total CPM, M5 & M6 (in grams) 

M[CPM] = 0.0116 9 CPM 

11) Pariiculate Concentrations, C (EPA OTM27 and EPA 202). 

Equation 43 

Equation 45 

EPA 202 

C[totalsus] = M1 (g)+M2(g)+M3(g)+M4(gt15.43(grains/g)Nmstd(dscf)= 

C[PM2.5sus] = Ml(g) + M4(g) '15.43(gralns/g) IVmstd(dscD = 

C[CPM] = M[CPM](g) '15 43(grains/g) 1 Vmstd(dscD 

where 15.43 = 7000/453592"'1000 

C[PMtotal] = C[PMtotalsus] + C[CPM] 

C[PM2.5total] = C[PM2.5sus] + C[CPM] 

0.0009 gr/dscf PMsus 

0.0009 gr/dscf PM2.Ssus 

0.0015 gr/dscfCPM 

0.0024 gr/dscfTotal PM 

0,0024 gr/dscfTotal PM2,S 
Client 

Project No. 

Spruance Genco, LLC 

3333 

12) Particulate Emission Rates, E. 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.3 

Three 

E[lb/hr[ = C[[(gr/dscf)' (1 Ib/7000 gr)' Qstd(dscfm)' 60(min/hr) 

E[lb/MMBtu] = C[](gr/dscf)' (1 Ib/7000 gr)' Fd(dscf/MMBtu)' (20.9120.9-%02) 

E[totalsusJ = 1.17 Ib/hr total sus PM 

E[totalsus] = 0.0016 Ib/MMBtu total sus PM 

E[PM2.5slls] = 1.17 Ib/hr PM2 5sus = 37.3 % of Total PM2.5 

E[PM2.5sus] = 0.0016 Ib/MMBtu PM2.5sus = 

E[CPM] = 1.97 Ib/hr CPM 62.7 % of Total PM2 5 

E[CPM] = 0.0027 Ib/MMBtu CPM 

E[PMtotal] = 314 Ib/hr total PM 

E[PMtotal] = 0.0044 IblMMBtu total PM 

E[PM2.5total] = 3.14 Ib/hr total PM2.5 

E[PM2.5total] = 00044 Ib/MMBtu total PM2 5 

13) Percent fsokinectic Sampling, %1 (EPA OTM 27 Equation 40). 

% I = [100*Ts*Vms*Pstd) I (60~Vs~tr*An*Ps*(1-Bws)*Tstd) 

% [= 103.93 

14) Stack Gas Viscosity, u (EPA OTM 27 Equation 3). 

u = C1 + C2*(Ts"0.5) + C3*(Tsl\-2) + C4*(%02) - (C5*Bws) + C6*Bws*(TsI\2) 

u = 193.7 micropoise 

Page 4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

15) Test Condition Reynolds number, Nre (EPA aTM 27 Equation B). 

Nre = 8.64'1 0'5'(Ps'MwlTs),(Os/u) 

Nre = 2845 

Unit NO.3 

Three 

16) Actual Particle Cut Diameter for Cyclone I, 050 (EPA OTM 27 Equation 32). 

D50 = B1'( ITs/( Mw' Ps)]'.2091), ((u/Os)'.7091) 

050 = 1 0.42 urn 

17) Actual Cunningham Correction Factor based on Op = 2.5um, C (EPA OTM 27 Equation 4). 

C = 1+ 0.0057193' (u/(Ps'Dp))' (Ts/Mw)'0.5 

C = 1.0698 

18) Initial 050 for Cyclone IV based on test condition Reynolds number from OTM 27 Equation B. 

If Nre < 3162, use Equation 33 which results in 050 for IV = 

If Nre >= 3162, use Equation 34 which results in 050 for iV = 

Initial 050 

230 

2.21 

Equation 33 

Equation 34 

Equation 35 

D50 = 0.0024302'(u/Os),1.1791'(1/C)'0.5'(Ts/(Ps'Mw)),0.6790 

D50 = 0.019723'(u/Os)'0.8058'(1/C),0.5'(Ts/(Ps'Mw))'0.3058 

Cr = 1 + 0.0057193'(u/(Ps'D50)),(Ts/Mw)'0.5 

19) Re-established 050 for Cyclone IV, 050-1. 

Page 5 

Re-establlshed 

Cunningham, Cr 

1.0759 

1.0790 

If Nre < 3162, use Equation 36 which results in 050 for IV = 

If Nre >= 3162, use Equation 37 which results in 050 for iV = 

Recalculated Cut Oiam 050-1 

2.29 

2.20 

Equation 36 

Equation 37 

D50-1 = 0 0024302'(u/Os)'1.1791'(lICr)'0.5'(Ts/(Ps'Mw))'0.6790 

D50-1 = O. 019723'(u/Os),0. 8058'( lICr)'O. 5'(Ts/(Ps'Mw)),0. 3058 

19) EstablishIng "Z" value, Z. 

If Equation 36 was used, then 

If Equation 37 was used, then 

Z= D50-1/D50 = 

Z=D50-1/D50= 

If 0,99 < Z < 1.01, then 050-1 IS best eut diameter estimate. 

If 0.99 > Z > 1.01, then repeat cales for Cr using 050-1 

1.00 

1.00 
3333-TSP-Me\als-R 1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb= 

Ps= 

Pstd = 

dP= 

dH = 

Tm= 

Ts= 

Tstd= 

On = 

An = 

y= 

t= 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc, 

EPA Methods 1,2,3A,4,5 and 29 

(Flows, 02/C02, H20, TSP and Metals) 

Spruance Genco, LLC 

3333 

Unit NO.3 

One 

04/16/10 

0840-1446 

696.7 cc 

Emission Data 

230.214 dcf 

-0.50 in. H20 

30.07 in. Hg 

30.03 in. Hg 

29.92 in. Hg 

0.6865 in. H20 ".5 

1,398 in. H20 

543.5 R 

652.8 R 

527.7 R 

0.250 in. 

0.000341 sq. ft. 

1.01 

360 min. 

10.30 ft. 

83.3204 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]".S}/{s*R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.ftlml 

0.0026688 in.Hg-Cf/ml-R 

9862 scf/MMBtu 

Instrumental Data 

4.07 %-dry 

14.76 %-dry 

81.17 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruanee Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1~ Y * Vm • (Pb + dH/13.6) I Tm 

Vmstd = 227.685 dsef 

6.448 dsem 

Unit NO.3 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2· Vic 

Vw(std) = 32.794 sef 

3) Decimal fraction of moisture by volume In stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1259 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [({44~%C02) + (32'"%02) + (28*%N2)) * (1-Bws) 1 + (18*Bws) 

Ms= 28.948 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp· (dP);; (TsJPs*Ms)",5 

Vs = 42.718 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min * Vs * As 

Oa = 213555.99 efm 

6047.91 emm 

7) Average stack gas dry volumetric f1owrate, Qstd. 

Ostd = Oa;; (TstdfTs) * (Ps/Pstd) • (1-Bws) 

Ostd = 151472.15 dscfm 

4289.69 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Unit No, 3 

One 

Calculations (cont.) 

8) Particulate Matter Analytical Data 

INPUT A 0.2207 9 

INPUT B 100 ml 

INPUT C 0,1692 9 

INPUT 0 100 ml 

INPUT E 0.0000 9 

9) Particulate sample mass calculations 

H 

J 

Front Half: 

Acetone blank adj. residue v 

Adj. Acetone wash part.wt. 

Front half sample wt. 

10) Front Half Particulate Matter Emission Data 

Filter sample net wt 

Front acetone wash vol 

Front acetone residue wt, 

Acetone blank vol. 

Acetone blank residue wt. 

0.0000 9 

0.1692 9 

0.3899 9 

E·(BID) 

C-H 

A+ I 

C[PM] = (Front Half Wt){g) "(1Nmstd) " 15.43(grains/g) 

E[PM] = C[PM] " Vdscfm " A • (60 min/hr)· (1 Ib 17000 grains) 

Page 3 

E[PM]lb/MMBtu = E[PM]lb/hr*{Fuel HV) scf/Btu"(fuel use) 1 hour/kscfkscfl1000scf10"6Btu/MMBtu 

C[PM] = 2.S4E-02 grains/dscf 

C[PM] = 3.77E-06 Ib/dscf 

E(PM] = 34,306 Ib/hr 

E[PMJ = 4,S2E-02 Ib/MMBtu 

11)Trace metal concentrations and emission rates 

Element 

Antimony 

Arsenic 

Beryllium 

Cadmium 

Chromium 

Cobalt 

Lead 

Manganese 

Nickel 

Selenium 

C[M] = M[M] tug) I Vmstd (dscm) 

C[M]{lb/dscf) = C[M]{ug/dscm) " 1e-OSg/ug" 2.20Se-03Ib/g • 0.02832 dscmldscf 

E[M]{Ibfhr) = C[M] (ug/dscm) .. (2.20SE-09) (Ibfug)"* Qstd (dscmm) "60 (min/hr) 

E[M]{Ib/MMBtu) = C[M)(lbfdscf) .. Fd "(20.9f20.9-%02) 

C[M](@eorr. 02) = C[M] (ugfdscm) • [(20.9-corrected %02) I (20,9-actual %02») 

Corrected 02 percentage is: 7.0 % 

Sample Conc. Conc.@!;;Q[r.Q2 Cone. Emission Rate 

Mass tug} (ugfdscml (ug/dscm) (Ibfdscf} (lbfhr) 

3.496 S.42E-01 4.48E-01 3.39E-11 3.0BE-04 

8.996 1.40E+OO 1.1SE+00 B.71E-11 7,92E-04 

5.16 B.00E-01 S.SIE-01 S.00E-11 4,S4E-04 

0.903 1.40E-01 1.1SE-Ol B.75E-12 7.9SE-OS 

15.363 2.38E+00 1_97E+OO 1.49E-l0 1.35E-03 

16.09 2.50E+00 2.0SE+OO 1.56E-l0 1.42E-03 

17.814 2.76E+OO 2.2BE+OO 1.73E-l0 1.S7E-03 

12.871 2,OOE+00 1.SSE+OO 1.2SE-10 1.13E-03 

23.27 3,61 E+OO 2.98E+OO 2,25E-10 2.05E-03 

9 1.40E+OO 1.1SE+OO B,72E-11 7.92E-04 

12) Isokinecity, I. 

% I = [100·Ts·(K3"*Vlc+«{Vm"Y)fTm)"(Pb+(dHf13.6))))] I (60*t·Ps"Vs*An) 

%1= 102.06 

.. < .. symbol indicates values given are the quantitative detection limit. 

Emission Rate 

(lb/MMBtu) 

4.146E-07 

1.0S7E-OS 

6.120E-07 

1.071E-07 

1.822E-OS 

1.90BE-OS 

2.113E-OS 

1.S27E-06 

2.760E-06 

1.0B7E-06 
3333-TSP-Metals-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

t= 

Os = 

As ::; 

Cp = 

Kp ::; 

K1 = 

K2 = 

K3 = 

Fd = 

[02] 

[C02[ 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,5 and 29 

(Flows, 02/C02, H20, TSP and Metals) 

Spruance Genco, LLC 

3333 

Unit No.3 

Two 

04119/10 

0730-1435 

Emission Data 

669.9 cc 

226,121 dcf 

-0.50 in. H20 

30.10 in. Hg 

30.06 in. Hg 

29.92 in. Hg 

0.6931 in. H20 ".5 

1.375 in. H20 

521.5 R 

651.0 R 

527.7 R 

0.250 in. 

0.000341 sq. ft. 

1.01 

360 min. 

10.30 ft. 

83.3204 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stacK temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampllng time 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol}"(inHg)1".5}/[s~R*inH201 Pitot tube constant 

17.637 R/in.Hg constant 

0.047070 cu.ftlml constant 

0.0026688 in.Hg-cf/ml-R 

9755 scf/MMBlu 

Instrumental Data 

3.83 %-dry 

15.06 %-dry 

81.11 %-dry 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1"* Y" Vm "* (pb + dHf13.6) I Tm 

Vmstd = 233.254 dscf 

6.606 dscm 

Unit No.3 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 31.532 set 

3) Decimal fraction of moisture by volume In stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.1191 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32*%02) + (28*%N2)) "* (1-Bws) 1 + (18*Bws) 

Ms = 29.067 Ibf lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp * (dP)"* (TsfPs~Ms)/I..5 

Vs = 42.958 fps 

6) Average actual stack gas volumetric flowrate, Oa. 

Qa = 60 sec/min * Vs * As 

Qa = 214758.86 cfm 

6081.97 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa"* (TstdfTs) * (Ps/Pstd) * (1-Bws) 

Qstd = 154098.57 dscfm 

4364.07 dscmm 

Page2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Unit NO.3 

Two 

Calculations (cont.) 

8) Particulate Matter Analytical Data 

INPUT A 0.2045 9 

INPUT B 100 ml 

INPUT C 0.1071 9 

INPUT D 100 ml 

INPUT E 0.0000 9 

9) Particulate sample mass calculations 

H 

J 

Front Half: 

Acetone blank adj. residue v 

Adj. Acetone wash part.wI. 

Front half sample wt. 

10) Front Half Particulate Matter Emission Data 

Filter sample net wt 

Front acetone wash vol. 

Front acetone residue wi, 

Acetone blank vol. 

Acetone blank residue wi. 

0.0000 9 

0.1071 9 

0,3116 9 

E'(B/D) 

C-H 

A+ I 

C[PMJ = (Front Half Wt)(g) * (1Nmstd) * 15.43{grains/g) 

E[PM] = C[PM] ~ Vdscfm * A - (60 minfhr) * (1 Ib 17000 grains) 

Page 3 

E[PM]lbfMMBtu = E[PM]lbfhr-(Fuel HV) scf/Btu*(fuel use) 1 hourfkscf*kscff1000scf"10"6BtuIMMBtu 

C[PM] = 2.05E-02 grainsldscf 

C[PM] = 2.94E-06 Ibfdscf 

E[PM) = 27.226 Ibfhr 

E[PM) = 3.S2E-02 IbfMMBtu 

11 )Trace metal concentrations and emission rates 

Element 

Antimony 

Arsenic 

Beryllium 

Cadmium 

Chromium 

Cobalt 

Lead 

Manganese 

Nickel 

Selenium 

C[M] = M[MJ (ug) I Vmstd (dscm) 

C[M](lbfdscf) = C[M){ugldscm) *1e-06glug * 2.205e-03Ib/g * 0.02832 dscm/dscf 

E[MlOb/hr) = C[M] (ugldscm) * (2.20SE-09) (Ibfug) * Qstd (dscmm) * 50 (min/hr) 

E[M](IbfMMBtu) '" C[M){lbfdscf) * Fd * (20.9f20.9-%02) 

C[M](@corr. 02) = C[M) (ug/dscm) * [(20.9-corrected %02) I (20.9-actual %02)] 

Corrected 02 percentage is: 7.0 % 

Sample Conc. Conc.@corr. 02 Cone. Emission Rate 

Mass tug} (ug/dscm) (ug/dscm) {Ibfdscf} (lbfhrl 

2,417 3.66E-01 2.98E-01 2,28E-11 2.11 E-04 

14.358 2.17E+OO 1.77E+OO 1,36E-10 1.2SE-03 

3,12 472E-01 3.8SE-01 2.9SE-11 2.73E-04 

1.01 1.S3E-01 1.2SE-01 9.5SE-12 B.S3E-OS 

17.94 2.72E+00 2.21E+OO 1.70E-10 1.57E-03 

9.63 1.46E+OO 1.19E"'OO 9. 1 OE-11 S.42E-04 

17.958 2.72E+OO 2.21E"'OO 1.70E-10 t57E-03 

13.782 2.09E+OO 1.70E+OO 1.30E-10 1.20E-03 

21.58 3.27E+OO 2.66E+OO 2.04E-10 t89E-03 

7.95 1.20E+OO 9,80E-01 7.S2E-11 6.95E-04 

12) Isokinecity, I. 

% I = [100*TS*(K3"Vlc+«{Vm-Y)fTm)*(Pb+(dHf13.6))))) I (60*t*Ps*VS"An) 

% I = 102,77 

"<" symbol indicates values given are the quantitative detection limit. 

Emission Rate 

(lb/MMBtu) 

2.729E-07 

1.521E-06 

3.S23E-07 

1.140E-07 

2.026E-06 

1.0B7E-06 

2.028E-06 

1.SS6E-06 

2,437E-06 

8976E-07 
3333-TSP-Metals-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts= 

Tstd= 

On = 

An = 

y= 

1= 

Os = 

As= 

Cp= 

Kp= 

K1 = 

K2= 

K3= 

Fd = 

[02[ 

[C02[ 

[N21 

AirNova, Inc. 

EPA Methods 1 ,2,3A,4,5 and 29 

(Flows, 02/C02, H20, TSP and Metals) 

Spruance Genco, LLC 

3333 

Unit No.3 

Three 

04/1911 0 

1448-2103 

626.1 cc 

214.412 dcf 

Emission Data 

-0.50 in. H20 

30.03 in. Hg 

29.99 in. Hg 

29.92 in. Hg 

0.6420 in. H20 ''.5 

1.186 in. H20 

531.4 R 

648.0 R 

527.7 R 

0.250 in. 

0.000341 sq. ft. 

1.01 

360 min. 

10.30 ft. 

83.3204 sq. ft. 

0.84 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

Cross sectional area of stack 

Pitot tube coefficient 

85.49 ft[(lb/lbmol)"(inHg)I".5}f[s"R·inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.ftfml 

0.0026688 in.Hg-cf/ml-R 

9868 scf/MMBtu 

Instrumental Data 

5.00 %-dry 

13.94 %-dry 

81.06 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1 ~ Y * Vm • (Pb + dHf13.6) I Tm 

Vmstd = 216.479 dscf 

6.131 dscm 

Unit No.3 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 29.470 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd f (Vmstd+Vwstd) 

Bws= 0.1198 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44·%C02) + (32*%02) + (2S*%N2)) ~ (1-Bws) 1 + (18~Bws) 

Ms= 28.941 Ibf Ibmole 

5) Average stack gas velocity, Vs. 

Vs = Kp" Cp ~ (dP) * (Ts/Ps~MsY'.5 

Vs = 39.835 fps 

6) Average actual stack gas volumetric flowrate, Ca. 

Qa = 60 sec/min ~ Vs " As 

Qa = 199144.23 cfm 

5639.76 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa;O (TstdlTs)" (Ps/Pstd) * (1-Bws) 

Qstd = 143083.41 dscfm 

4052.12 dscmm 

Page 2 
Client Spruance Genco, llC 

Project No. 3333 

Test Location 

Test Run 

Unit No.3 

Three 

Calculations (cont.) 

8) Particulate Malter Analytical Data 

INPUT A 0.1218 g 

INPUT B 100 ml 

INPUT C 0.0758 9 

INPUT 0 100 ml 

INPUT E 0.0000 9 

9) Particulate sample mass calculations 

H 

J 

Front Half: 

Acetone blank adj. residue v 

Adj, Acetone wash part.wt. 

Front half sample wt. 

10) Front Half Particulate Matter Emission Data 

Filter sample net wt 

Front acetone wash vol, 

Front acetone residue wt. 

Acetone blank vol. 

Acetone blank residue wt. 

0.0000 9 

0.0758 9 

0.1976 9 

E"(B/O) 

C-H 

A+ I 

C[PM] = (Front Half Wt)(g) ~ (1Nmstd) " 15.43(9rains/g) 

E[PM] = C[PM] • Vdscfm ~ A .. (60 min/hr)" (1 Ib 17000 grains) 

Page 3 

E[PM]lb/MMBtu = E[PM]lbfhr~(Fuel HV) scf/Btu"(fuel use) 1 hourfkscf"kscf/1000scr10~6Btu/MMBtu 

C[PM] = 1.41E-02 grains/dsd 

C[PM] = 2.01E-06Ib/dscf 

E[PM] = 17.2731bfhr 

E[PM] = 2.61 E-02 IbfMMBtu 

11)Trace metal concentrations and emission rates 

Element 

Antimony 

Arsenic 

Beryllium 

Cadmium 

Chromium 

Cobalt 

lead 

Manganese 

Nickel 

Selenium 

C[M] = M[M] (ug) f Vmstd (dscm) 

C[M](lb/dscf) = C[M](ug/dscm) "1e-06g/ug" 2.205e-03Ib/g" 0.02832 dscmfdscf 

E[M](Ib/hr) = C[MJ (ug/dscm)" (2.20SE-09) (Ib/ug)" Qstd (dscmm)" 60 (min/hr) 

E[M](Ib/MMBtu) = C[M](Ib/dscf)" Fd • (20.9/20.9-%02) 

C[M](@corr.02)=C[M](ug/dscm)·[(20.9-corrected%02) I (20.9-actual %02)] 

Corrected 02 percentage is: 7.0 % 

Sample Cone. Conc.@corr_ Q2 Conc_ Emission Rate 

Mass (ug) {ugfdscm} {ug/dscm} (lb/dscf) (lb/hr) 

2.109 3.44E-01 3.01E-01 2.1SE-11 1.B4E-04 

11.424 1.86E+OO 1.63E+00 1.18E-10 9.99E-04 

1.72 2.81E-01 2.4SE-01 1.75E-11 1,50E-04 

0.959 1.SBE-01 1.37E-01 9.77E-12 8.39E-05 

13.36 2.18E+OO 1_91E+OO 1.3BE-10 1,17E-03 

5,84 9.53E-01 8.33E-01 5,95E-11 S.11E-04 

14.122 2,30E+QO 2_01E+OO 1.44E-10 1.23E-03 

9.802 1,SOE+QO 1.40E+00 9.98E-11 8.S7E-04 

17.88 2,92E+OO 2.S5E+00 1.82E-10 i.5SE-03 

5.51 8.99E-01 7.86E-01 5_S1E-11 4.82E-04 

12) Isokinecity, I. 

% I = [100·Ts·(K3"Vlc+«(Vm"Y)/Tm)*(Pb+(dHf13 6»)))]1 (60*t*Ps"Vs"An) 

%1= 102.73 

" < " symbol indicates values given are the quantitative detection limit. 

Emission Rate 

{lb/MMBtu} 

2.786E-07 

1.509E-OB 

2.272E-07 

1.267E-07 

1.76SE-OB 

7.71BE-07 

1,8BBE-OB 

1.295E-OB 

2362E-OB 

7.280E-07 
3333-Hg-unspiked-R 1 

Client 

Project No. 

Test location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatlc = 

Pb = 

Ps = 

Pstd = 

Tm· 

Ts = 

Tstd= 

y= 

,= 

Os = 

As = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

[02[ 

[C02) 

[N2) 

AirNova, Inc. 

EPA Method 1, 2, 3A, and 30B - Unspiked Tube 

(Flows, 02/C02, and Mercury) 

Spruance Genco, LLC 

3333 

Unit No.3 

One 

04/16/10 

0840-1440 

Emission Data 

8.002 dcf 

-0.50 in. H20 

30.07 in. Hg 

30.03 in. Hg 

29.92 in. Hg 

562.8 R 

652.8 R 

527.7 R 

1.000 

360 min. 

10.30 ft 

Dry gas meter readmg 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83.32043375 sq. ft Cross sectional area of stack 

85.49 ft[(lb/lbmol)*(inHg)]".5}/[s"R"mH20] 

17637 R/in.Hg 

0.047070 cu.ftlml 

0.0026688 in.Hg-cf/ml-R 

9862 scf/MMBtu 

Instrumental Data 

4.07 %-dry 

14.76 %-dry 

81.17 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm * Pbl Tm 

Vmstd = 7.541 dscf 

0.2135 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Based on the M29 sampling train 

INPUT Bws = 0.1259 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No.3 

One 

Ms = [«44*%C02) + (32*%02) + (28*%N2» * (1~Bws)] + (18*Bws) 

Ms= 28.948 Ibllbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs= 

Vs = 

Based on the M29 sampling train 

42.718 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 seclmin * Vs ., As 

Qa = 213556.94 cfm 

6047.93 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa * (TstdfTsj * (PsIPstd) * (1-Bws) 

Qstd = 151468.49 dscfm 

4289.59 dscmm 

8) Mercury concentrations and emission rates 

C[M] = M[M] (ug) I Vmstd (dscm) 

C[M](Ib/dscf) = C[M](ug/dscm) ·1e-06g/ug'" 2.205e-03Ib/g'" 0.02832 dscm/dscf 

E[MJ(lb/hr) = C[M] (ug/dscm) ... (2.20SE-09) (Ib/ug) "Qstd (dscmm) ;0; 60 (minlhr) 

E[M](Ib/MMBtu) = C[M](lbldscf) • Fd ... (20.9/20.9-%02) 

Element 

Mercury 

C[MJ(@ carr. 02) = C[M] (ug/dscm) ;0; [(20.9-corrected %02) I (20 9-actual %02) I 

Corrected 02 percentage is 7 % 

Sample 

Mass (ug) 

0.0012 

Conc. 

(ug/dscml 

0.006 

Conc.@COrr. 02 

(ug/dscm) 

0.005 

Cone. 

(lb/dscf) 

3.S1E-13 

Emission Rate 

(Ib/hr) 

3 19E-06 

Page 2 

Emission Rate 

(lb/MMBtu) 

4.30E-09 
3333-Hg-unspiked-R2 

Client 

Project No. 

Test location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

Tm = 

Ts = 

Tstd= 

y= 

t= 

Os = 

As = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Method 1, 2, 3A, and 30B - Unspiked Tube 

(Flows, 02fC02, and Mercury) 

Spruance Genco, LLC 

3333 

Unit NO.3 

Two 

04/19/10 

0730-1330 

Emission Data 

5,340 dcf 

-0,50 in. H20 

30.10 in, Hg 

30.06 in. Hg 

29.92 in. Hg 

532.3 R 

651.0 R 

527.7 R 

1,000 

360 mm. 

10.30 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83.32043375 sq. ft. Cross sectional area of stack 

85.49 ft[(lbflbmol)*{inHg)J",5}/[s·R*inH20] 

17.637 Rlin.Hg 

0.047070 cu.ftlml 

0,0026688 in.Hg-cf/ml-R 

9755 scf/MMBtu 

Instrumental Data 

3.83 %-dry 

15.06 %-dry 

81,11 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client Spruance Genco, LLC Test location 

Project No. 3333 Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1'* Y,o Vm * Pbl Tm 

Vmstd = 5,326 dscf 

0_1508 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws= 

Bws= 

Based on the M29 sampling train 

0.1191 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No_ 3 

Two 

Ms = [«44"%C02) + (32"'%02) + (28,o%N2» * (1-Bws) 1 + (18'*Bws) 

Ms = 29.067 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs = 

Vs = 

Based on the M29 sampling train 

42958 fps 

6) Average actual stack gas volumetric nowrate, Qa. 

Oa = 60 sec/mm '* Vs • As 

Oa = 214756.75 cfm 

6081.91 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa * (TstdfTs) * (Ps/Pstd) * (1-Bws) 

Qstd = 154082.62 dscfm 

4363.62 dscmm 

8) Mercury concentrations and emission rates 

Element 

Mercury 

C[M] = M[M] (ug) I Vmstd (dscm) 

C[MJ(lb/dscf) = C[M](ug/dscm) * 1e-06g/ug * 2205e-031b/g" 0.02832 dscm/dscf 

EIM](lb/hr) = C[M] (ug/dscm) '* (2.205E-09) (Ib/ug) * Qstd (dscmm) * 60 (min/hr) 

E[M]{lb/MMBtu) = C[M](lb/dscf) * Fd • (20.9/20.9-%02) 

C[M](@ corr. 02) = C[M] (ug/dscm) • [(20.9-corrected %02) I (20.9-actual %02) 1 

Corrected 02 percentage is: 7 % 

Sample 

Mass (ug) 

0.0012 

Conc 

(ug/dscm) 

0008 

Conc.@oorr. 02 

(ug/dscm) 

0.006 

Conc. 

(lb/dscQ 

4.97E-13 

Emission Rate 

(lb/hr) 

4.59E-06 

Page 2 

Emission Rate 

(lb/MMBtu) 

5,93E-09 
3333-Hg·unspiked-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb= 

Ps = 

Psld = 

Tm= 

Ts = 

Tstd= 

y= 

t= 

Os = 

As = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

[02[ 

[C02[ 

[N2] 

AirNova, Inc. 

EPA Method 1, 2, 3A, and 30B - Unspiked Tube 

(Flows, 02fC02, and Mercury) 

Spruance Genco, LLC 

3333 

Unit NO.3 

Three 

04/19/10 

1449-2049 

Emission Data 

9.596 dd 

-0.50 in. H20 

30.03 in Hg 

29.99 in. Hg 

29.92 in. Hg 

5330 R 

648.0 R 

527.7 R 

1.000 

360 min. 

10.30 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83.32043375 sq. ft. Cross sectional area of stack 

85.49 ft[(lb/lbmol)*(inHg)]".5}1[s*R*lnH20] 

17.637 Rfin.Hg 

0.047070 cu.ftlml 

0.0026688 in.Hg-d/ml-R 

9868 sdfMMBtu 

Instrumental Data 

5.00 %-dry 

13.94 %-dry 

81.06 %·dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmsld =K1* Y"'Vm" Pb/Tm 

Vmstd = 9.536 dscf 

0.2700 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws = 

Bws= 

Based on the M29 sampling train 

0.1198 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No 3 

Three 

Ms = [«44"%C02) + (32*%02) + (28*%N2» ., (1-Bws) J + (18~Bws) 

Ms = 28941 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs = 

Vs = 

Based on the M29 sampling train 

39.835 fps 

6) Average actual stack gas volumetric f1owrate, Qa. 

Oa = 60 sec/min * Vs .. As 

Oa = 199144.17 cfm 

5639.76 cmm 

7) Average stack gas dry volumetric f1owrate, Qstd. 

Qstd =- Oa" (TstdlTs)" (Ps/Pstd)" (1-Bws) 

Ostd =- 14309444 dscfm 

4052.43 dscmm 

8) Mercury concentrations and emission rates 

Element 

Mercury 

C[M] = M[M] (ug) I Vmstd (dscm) 

C[M](Ib/dscf) = C[MJ(ug/dscm) " 1 e-06g/ug'" 2.205e-03Ib/g" 0.02832 dscm/dscf 

E[M](lb/hr) = C[M] (ug/dscm) * (2.205E-09) (Ib/ug) "Qstd (dscmm)" 60 (min/hr) 

E[M](lb/MMBtu) = C[M](Ib/dscf) ... Fd '" (20.9/20.9-%02) 

C[M](@ carr. 02) = C[M] (ug/dscm) ... [(20.9-corrected %02) 1 (20.9-actual %02) 1 

Corrected 02 percentage is: 7 % 

Sample 

Mass (ug) 

0.0013 

Conc. 

(ug/dscm) 

0.005 

Conc.@corr. 02 

(ug/dscm) 

0.004 

Conc. 

Clb/dscO 

301 E-13 

Emission Rate 

(Ib/hr) 

2.58E-06 

Page 2 

Emission Rate 

(lb/MMBtu) 

3.90E-09 
Unit No.4 
Spruance Genco, LLC 

Richmond, Virginia 

Project No, 3333 

April 20, 2010 

Unit No.4 

Run No.1 

Coal Analysis for F Factor Calculation 

F FACTOR CALCULATION 

INPUT %H = 5.00 Hydrogen Content (%) 

INPUT %c= 74.72 Carbon Content (%) 

INPUT %N = 1.58 Nitrogen Content (%) 

INPUT %0= 6.29 Oxygen Content (%) 

INPUT % s= 0.92 Sulfur Content (%) 

INPUT GCV= 13335 Gross Calorific Value (Btu/lb) 

Fd = 10"6'" [(3.64*%H) + (1.53"'%C) + (0.57*%5) + (O.14*%N) - (0.46"%02)]1 GCV 

Fd = 9777 scfJMMBtu 
Spruance Genco, LLC 

Richmond, Virginia 

Project No. 3333 

April 20, 2010 

Unit No.4 

Run No.2 

Coal Analysis for F Factor Calculation 

F FACTOR CALCULATION 

INPUT %H= 4.89 Hydrogen Content (%) 

INPUT %c= 73.94 Carbon Content (%) 

INPUT %N= 1.55 Nitrogen Content (%) 

INPUT %0= 5.38 Oxygen Content (%) 

INPUT %s= 0.93 Sulfur Content (%) 

INPUT GCV= 13024 Gross Calorific Value (Btu/rb) 

Fd = 10'6' [(3.64·%H) + (1.53'%C) + (0.57'%S) + (0.14'%N) - (0.46'%02)]1 GCV 

Fd = 9920 scf/MMBtu 
Spruance Genco, LLC 

Richmond, Virginia 

Project No. 3333 

April 21, 2010 

Unit No.4 

Run No.3 

Coal Analysis for F Factor Calculation 

F FACTOR CALCULATION 

INPUT % H= 4.90 Hydrogen Content (%) 

INPUT %C= 73.91 Carbon Content (%) 

INPUT % N= 1.51 Nitrogen Content (%) 

INPUT %0= 6.71 Oxygen Content (%) 

INPUT %8= 0.85 Sulfur Content (%) 

INPUT GCV= 13243 Gross Calorific Value (Btu/lb) 

Fd = 10'6 ' [(364'%H) + (1.53'%C) + (0.57'%S) + (0 14'%N) - (0.46"%02)) I GCV 

Fd = 9705 scf/MMBtu 
M7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, lLC 

3333 

Unit 4 Acid Gases 

04/19/10 

Parameter: Oxygen 

Instrument Span f% 02t 22,08 

Actual Calibration Gas Value f% 021: 

Analvzer Calibration Response r% 02J: 

Analyzer Calibration Error f% Span). 

Zero System Calibration Gas 

AQ(2srent Init. Sys. Init· Svs. Final,s\::::S:. Final $\:::5. 

Stack ~ Cal, Bias Calib, Cal. Bias 

Run Cone. Response (% soan) Response (% span) 

1 4.56 0.09 0.18 0.04 -0.05 

2 4.01 0.04 -0_05 0.10 0.23 

3 6-43 0.10 0.23 0.06 0_05 

4 0.00 0.06 0.05 0.00 -0_23 

5 0.00 0.00 -0.23 0.00 -0.23 

6 0.00 0.00 -0.23 0.00 -0.23 

7 0.00 0.00 -0.23 0,00 -0.23 

B 0.00 0.00 -0.23 0.00 -0.23 

9 000 0_00 -0.23 0.00 -0_23 

10 0.00 0.00 -0.23 0.00 -0.23 

11 0.00 0.00 -0,23 0.00 -0.23 

12 0.00 0.00 -0.23 0,00 -0.23 

AirNova, Inc. 

EPA Method 7E Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anaf~er Calib. Gases U{}.sca/f!. 

zero low mid high S~s. Cal. Gas 

0,00 N/A 11.90 22.08 11.90 

0.05 N/A 11.89 22.07 11.90 

0.23 0.00 -0.05 -0,05 

Ugscale System Calibration Gas 

r&.!i.!L Init S)t::S. Init. Sys. Final Sys. Final S):::s. Galib. !l!;JJm1 

Drift Calib. Cal. Bias CaNb. Cal. Bias Drift Stack 

(% span) Response (% span) Response (% span) (% span) Cone. 

-0.23 11.90 0.00 11.99 0-41 0-41 4.50 

0.27 11 99 0.41 11.95 0_23 -0.18 3.94 

-0.18 11_95 0.23 12.00 0.45 0.23 6.35 

-0.27 12.00 0-45 0,00 -53,89 -54 35 -0.06 

0.00 0.00 -53.89 0.00 -53.89 0_00 ERR 

0.00 0.00 -53.89 0_00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53_89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53_89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 
M7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Uni14 

04/19/10 

Parameter: Carbon Dioxide 

Instrument Span (% C02L' 22.28 

Actual Calibration Gas Value (% e021.-

Analvzer Calibration Response t% C02/: 

Analvzer Calibration Error (% Spant 

Zero Sy:stem Calibration Gas 

A(,2Qarent Inil. SJ,:'s. Init. S:vs. Final S:':::5. Final Sj!s. 

Stack Galib. Cal. Bias. Ca/ib. Cal. Bias 

Run Cone. Response (% soan) Response (% span) 

1 15.21 0.00 0.00 0.00 0.00 

2 15.19 0.00 0.00 0.00 0.00 

3 1281 0.00 0.00 -0.12 -0.54 

4 0.00 -0 12 -0.54 0.00 0.00 

5 0.00 0.00 0.00 0.00 0.00 

6 0.00 0.00 0.00 0.00 0.00 

7 0.00 0.00 0.00 0.00 0.00 

8 0.00 0.00 0.00 0.00 000 

9 0.00 0.00 0.00 0.00 0.00 

10 0.00 0.00 0.00 0.00 0.00 

11 0.00 0.00 000 0.00 0.00 

12 0.00 0.00 0.00 0.00 0.00 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Analyzer Cafib. Gases Upscale 

zero low mid high S\:::s. Cal. Gas 

0.00 N/A 12.38 22.38 12.38 

0.00 N/A 12.45 22.34 12.38 

0.00 0.00 0.31 -0.18 

Urui;cale Sy:stem CalUuation Gas 

Cafib. !nit. S\:::s. Init. Sl!s. Final S~ Final SKS. Galib. Actual 

Drift s&li1L Gat Bias Calib Cal. Bias Drift Stack 

(% span) Response (% span) Resoonse t% span) t% span) Cone. 

000 12.45 0.31 12.45 0.31 0.00 15.12 

0.00 12.45 0.31 12.45 0.31 0.00 15.10 

-0.54 12.45 0.31 12.33 -0.22 -0.54 12.80 

054 12.33 -0.22 0.00 -55.57 -55.34 0.12 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 000 -55.57 0.00 -5557 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 000 ERR 

0.00 0.00 -5557 0.00 -55.57 0.00 ERR 

000 0.00 -55.57 0.00 -55.57 0.00 ERR 
M7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unrt 4 

04/19/10 

Parameter: Carbon Monoxide 

Instrument Span (PPmV CO): 935.7 

Actual Calibration Gas Value (pomV CO): 

Analvzer Calibration Response (pomV GOL 

Analvzer Calibration Error r% Span).-

Zero System Calibration Gas 

AQQarent Inil. St:::s. Inil. Svs. Final $):::8. Final $:':::5. 

fiIg<i< Calib. Cat. Bias Calib. Cal. Bias 

Run Cone. Response (% span) Response (% span) 

1 202.0 00 0.00 -4.9 -0.52 

2 376.0 -4.9 -0.52 0.0 0.00 

3 156.0 0.0 0.00 -4.9 -0.52 

4 0.0 4.9 -0.52 0.0 0.00 

5 00 00 0.00 0.0 0.00 

6 0.0 0.0 0.00 00 0.00 

7 0.0 0.0 0.00 0.0 0.00 

8 0.0 0.0 0.00 0.0 0.00 

9 0.0 0.0 0.00 0.0 0.00 

10 0.0 0.0 0.00 0.0 0.00 

11 0.0 0.0 0.00 00 0.00 

12 0.0 0.0 0.00 0.0 0.00 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Ana1jtZer Calib. Gases UQscale 

lliQ low mid high St:::s. Cal. Gas 

0.0 0.0 486.0 935.7 486.0 

00 0.0 474.0 938.0 486.0 

0.00 0.00 -1.28 0.25 

UJ;!scale System Calibration Gas 

Calib. Init SI:::,s:. Inii- $1:::8. Fmal S\,,8. Final Sk's. Ca/ib. Actual 

Drift Calib. Cal. Bias Galib. caf. Bia~ Drift fiIg<i< 

(% span! Response (% span) Response (% span) f% span) Cone. 

-0.52 488.0 0.21 469.0 -1.82 -2.03 206.6 

0.52 469.0 -1.82 474.0 -1.28 0.53 388.1 

-0.52 474.0 -1.28 474.0 -1.28 0.00 161.6 

0.52 474.0 -1.28 00 -51.94 -50.66 5.0 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

000 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 00 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 
M7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit 4 

04/19/10 

Parameter: Nitrogen Oxides (as N02) 

Run 

2 

3 

4 

5 

6 

7 

B 

9 

10 

11 

12 

Instrument Span (pomV NOxJ: 450.9 

Actual Calibration Gas Value (ppmV NOxJ: 

Analyzer Calibration Response (ppmV NOxt 

Analyzer Calibra/ion Error (% Span): 

Zero System Calibration Gas 

Ar;marent Init. S:vs. Init Sys. Final Sys. Final Sys. 

~ Calib. Cal. Bia§. ~ Cal Bias 

Conc_ Response f% span) Response f% span) 

202.0 -1.0 -0.13 -1.0 -0.13 

211.0 -1.0 -0.13 -0.2 0.04 

175.0 -0.2 0.04 -1.0 -0.13 

0.0 -1.0 -0.13 0.0 0.09 

0.0 0.0 0.09 0.0 0.09 

0.0 0.0 0.09 0.0 009 

0.0 0.0 0.09 0.0 0.09 

0.0 00 009 00 0.09 

0.0 0.0 0.09 00 0.09 

0.0 0.0 0.09 0.0 0.09 

0.0 0.0 0.09 0.0 0.09 

0.0 0.0 0.09 0.0 0.09 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anai'Ger QaIiQ_ Gases !.lQscale 

zero low mid high S~s. Cal. Gas 

0.0 00 246.8 450,9 246.8 

-0.4 0.0 251.0 456.0 246.8 

-0.09 0.00 0.93 1.13 

Up:scale System Calibration Gas 

Calib_ Init. Sl!:s. Init. S):::s. Fingl Sys. Fina! Sys. Ga/ib. Actual 

Drift Calib. Cal, Bias Galib. Cal. Big~ Drift Stack 

f% span) Response f% span) Response f% span) f% span) Cone. 

0.00 246.0 -0.18 251.0 0.93 1 11 200.8 

0.18 251.0 0.93 242.0 -1.06 -2.00 211.3 

-0.18 242.0 -1.06 244.0 -062 0.44 177.9 

0.22 244.0 -0.62 0.0 -54.73 -54.11 1 .• 

0.00 0.0 -54.73 0.0 -54.73 0.00 ERR 

0.00 0.0 -54.73 00 -54.73 0.00 ERR 

0.00 0.0 -54.73 0.0 -54.73 0.00 ERR 

0.00 0.0 -54.73 0.0 -5473 0.00 ERR 

0.00 0.0 -54.73 0.0 -54.73 0.00 ERR 

0.00 0.0 -54.73 0.0 -54.73 0.00 ERR 

0.00 00 -54 73 0.0 -54.73 0.00 ERR 

0.00 0.0 -54.73 0.0 -54.73 0.00 ERR 
M7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit4 

04/19/10 

Parameter: Sulfur Dioxide 

Instrument Span (ppmV S02): 8R9 

Actual Calibration Gas Value fopmV S02): 

Analvzer Calibration Response (ppmV S02/: 

Analvzer Calibration Error (% Span): 

Zero Sy:stem Calibration Gas 

Ar,marent Init. SJ,:'s. Init. S\l:5. Final SJ,:'s. Final SJ,:'s. 

Stack Calib. Cal. Bias Calib. Cal. Bias 

Run Conc. Response (% spanl Response (% span) 

1 50.6 -05 -056 -1.0 -1 11 

2 48.9 -1.0 -1.11 0.0 0.00 

3 36.0 0.0 0.00 0.0 0.00 

4 0.0 0.0 0.00 0.0 0.00 

5 00 0.0 0.00 0.0 0.00 

6 0.0 00 000 0.0 0.00 

7 0.0 0.0 0.00 0.0 0.00 

5 0.0 0.0 0.00 0.0 0.00 

9 0.0 0.0 0.00 0.0 0.00 

10 0.0 0.0 0.00 0.0 000 

11 0.0 0.0 0.00 0.0 000 

12 0.0 0.0 0.00 0.0 0.00 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjusbnent) 

Ana1mr GalilJ.. Gases UQscale 

zero low mid high S)!s. Cal. Gas 

0.0 0.0 507 89.9 50.7 

0.0 0.0 49.8 89.8 50.7 

0.00 0.00 -0.20 -0.02 

URscale System Calibration Gas 

Ca/ib. Init. SJ,:'s. Init. S):,:s. Final S\:,s. Final S)t::s. Galib. Actual 

Drift Calib. Cal. Bias Galib. Cal. Bias Drift Slack 

(% span) Response (% span) Response (% span) (% span) Cone. 

-0.56 50.3 45.00 51.8 1.22 1.67 50.3 

1.11 51.8 1.22 52.7 2.22 1.00 47.5 

0.00 52.7 2.22 49.3 -1.56 -3.78 35.8 

0.00 49.3 -1.56 0.0 -56.40 -54.84 0.0 

0.00 0.0 -56.40 0.0 -56.40 0.00 ERR 

0.00 0.0 -56.40 0.0 -56.40 0.00 ERR 

0.00 0.0 -56.40 0.0 -56.40 0.00 ERR 

0.00 0.0 -56.40 0.0 -56.40 0.00 ERR 

0.00 0.0 -56.40 0.0 -56.40 0.00 ERR 

0.00 0.0 -56.40 0.0 -56.40 0.00 ERR 

0.00 0.0 -56.40 00 -56.40 0.00 ERR 

0.00 0.0 -56.40 0.0 -56.40 0.00 ERR 
3333-7E 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, lLC 

3333 

Unit NO.4 - Non Dioxin/Furan HAPs 

04/19110 

Parameter: Total Hydrocarbons (as 

Instrument Span (pomV THCI: 20 

Actual Calibration Gas Value (ppm V THC): 

Analvzer Calibration Response topmV THC!: 

Analvzer Calibration Error (% Cal. Gas Value): 

Zero Sy:stem Calibration Gas 

Al2l2arent Init. Sl::s. Init. Sl::s. Final Sl::s. Final Sl::s. 

Stack Calib. Cal. Bias Calib. Cal. Bias 

Run = Response (% span) Response (% span) 

1 0.3 00 000 -0.5 -2.50 

2 0.2 -0.5 -2.50 0.1 050 

3 0.3 0.1 0.50 0.0 0.00 

4 00 0.0 0.00 0.0 0.00 

5 0.0 0.0 0.00 0.0 0.00 

6 0.0 0.0 0.00 00 0.00 

7 0.0 00 000 0.0 0.00 

8 0.0 0.0 0.00 0.0 0.00 

9 0.0 0.0 0.00 0.0 0.00 

10 0.0 00 0.00 0.0 0.00 

11 0.0 0.0 0.00 0.0 0.00 

12 00 0.0 0.00 0.0 0.00 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjusbnent) 

C3HS 

Ana/'Ger Calib. Ga,s:es Upscale 

zero low mid high Sl::s. Cal. Gas 

0.0 4.9 9.1 17A 4.9 

0.0 4.8 8.9 17.2 4.8 

-DAD -0.95 -1.00 

Ug§cale Sy:stem Calibration Gas 

Calib Init Sl::S Init Sl::S Final Sl::s. Final Sl::S Calib. Actual 

Drift Gal/b. Gal. Bias Galib. Ga/. Bias Drift Stack 

(% span) Response (% span) Response (% span) (% span) Conc. 

-2.50 4.8 0.00 4.9 0.50 0.50 0.5 

3.00 4.9 0.50 4.B 0.00 -0.50 OA 

-0.50 4B 0.00 4.6 -1.00 -1.00 0.3 

0.00 4.6 -1.00 0.0 -24.00 -23.00 0.0 

0.00 0.0 -24.00 0.0 -24.00 0.00 ERR 

0.00 0.0 -2400 0.0 -24.00 0.00 ERR 

0.00 00 -24.00 0.0 -24.00 0.00 ERR 

0.00 0.0 -24.00 0.0 -24.00 0.00 ERR 

0.00 0.0 -24.00 0.0 -24.00 0.00 ERR 

0.00 0.0 -24.00 0.0 -24.00 0.00 ERR 

0.00 0.0 -24.00 0.0 -24.00 0.00 ERR 

0.00 0.0 -24.00 0.0 -24.00 0.00 ERR 
3333-HCI-HF-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts= 

Tstd= 

On = 

An = 

y= 

1= 

Os= 

As= 

Cp= 

Kp= 

K1 = 

K2= 

K3 = 

Fd = 

CF= 

CF= 

[02] 

[C02] 

[N2[ 

AirNovs, Inc. 

EPA Methods 1,2,3A,4,and 26A 

(Flows, 02/C02, H20,and HCI/HF) 

Spruance Genco, LLC 

3333 

Unit No.4 

One 

04/19/10 

0923-1235 

Emission Data 

316,6 cc 

116.777 dcl 

-0.50 in. H2O 

30.10 m. Hg 

30.06 rn, Hg 

29.92 in, Hg 

07441 in H20 A.5 

1.361 in. H20 

522.5 R 

652.3 R 

527.7 R 

0.245 in. 

0.000327 sq. ft. 

1.02 

180 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq. ft.. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbllbmol)'(inHg)]'.S}/[s·R"inH20] Pilol tube conslant 

17.637 Rhn.Hg 

0047070 cu.ftlml 

0.0026688 in.Hg-cf/ml-R 

9777 scf/MMBtu 

9.461 E-08 Ibldscf! ppmVd 

S.192E-08 Ibldscf! ppmVd 

Instrumental Data 

4.5 %-dry 

15.12 %-dry 

80.38 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCI 

Conversion Factor for HF 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =Kl' Y' Vm ' (Pb + dH/13.6) ITm 

Vmstd = 121.416 dscf 

3.44 dscm 

Unit No.4 

One 

2) Volume of water vapor collected at standard conditions, Vw{std). 

Vw(std) = K2 'Vic 

Vw(std) = 14.902 scf 

3) Decimal fraction of moisture by volume In stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 0.109 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (I-Bws) I + (18'Bws) 

Ms= 29.22 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP)' (Ts/Ps·Ms)'.5 

Vs = 46.05 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min"" Vs • As 

Qa = 230203.0 cfm 

6519.3 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Ostd = 0.' (TstdfTs)' (Ps/Pstd)' (I-Bws) 

Qstd = 166670.1 dscfm 

4720.1 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Hydrogen Chloride Concentration and Emissions 

Unit NO.4 

One 

M[HCI] = M[CI-](mg) • MW[HCI](mg/mmol) 1 MW[CI-](mg/mmol) 

Page 3 

C[HCI] = (M[HCI](mg) • 2205E-06(lb/mg) • 21 85(scf'inHgllbmol'R) • K1 • 10'6) 1 (MW[HCIJ(lbllbmol) • Vmstd(d 

C[HCI](@corr. 02) = C[HCI](ppmV)' [(20 9-corrected 02) 1 (20.9-octuol %02)] 

E[HCI] = M[HCI](mg)' Qstd(dscfm)' (2.205E-06)(lb/mg)· 60(min/hr) 1 Vmstd(dscf) 

E[HCI] = C[HCI](ppmV)' Fd' CF(HCI)' (20.9/(20.9-%02)) 

< M[HCI] = 0.06 mg 

< C[HCI] = 0012 ppmV 

< C[HCI] = 0.010 ppmV (@ 7.0 % 02) 

< E[HCI] = 0.0111b/hr 

< E[HCI] = 1.36E-05 Ib/MMBtu 

9) Hydrogen Fluoride Concentration and Emissions 

C[HF] = M[HF](mg) 1 Vmstd(dscm) 

C[HF] = (M[HF](mg) • 2.205E-06(lb/mg) • 21.85(scf·lnHgllbmol·R) • K1 • 10'6) 1 (MW[HF](lb/lbmol) • Vmstd(dsc 

C[HF](@corr 02) = C[HF](mg/dscm)' [(20.9-corrected 02) 1 (20.9-octuol %02)] 

E[HF] = C[HF](mg/dscm) • Qstd(dscmm) • (2.205E-06)(lb/mg) • 60(min/hr) 

E[HF] = C[HF](ppmV)' Fd' CF(HF)' (20 9/(20 9-%02)) 

M[HF] = 

C[HF] = 

C[HF] = 

C[HF] = 

E[HF] = 

E[HF] = 

10) Isokinecity, I. 

0.600 mg 

0.174 mg/dscm 

0.210 ppmV 

0.178 ppmV (@ 

0.109 Ib/hr 

1.36E-04Ib/MMBtu 

7.0 

% 1 = (100·Ts·(K3·Vlc+(Vm·YlTm)(Pb+dH/13.6)))/(60·t·Ps'Vs·An) 

% I = 103.0 

% 02) 
3333-HCI-HF-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

t= 

Ds = 

As= 

Cp= 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

CF = 

CF = 

[02[ 

[C02[ 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and 26A 

(Flows, 02/C02, H20,and HCIIHF) 

Spruance Genco, LLC 

3333 

Unit No.4 

Two 

04/19/10 

1310-1622 

Emission Data 

361 cc 

117.695 dcf 

-0.50 in. H20 

30.04 in. Hg 

30.00 in. Hg 

29.92 in. Hg 

0.7418 in. H20 11,5 

1.402 in. H20 

537.2 R 

650.5 R 

527.7 R 

0245 in. 

0.000327 sq. ft. 

1.02 

180 min. 

10300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq. ft Cross sectional area of stack 

0,84 Pitot tube coefficient 

85.49 ft[(lbllbmol)'(inHg)]A.5]/[s·R'inH20] Pitot tube constant 

17.637 Rlin.Hg 

0.047070 cu,ft/ml 

0.0026688 in Hg-cflml-R 

9920 scf/MMBtu 

9.461E-08 Ib/dscf I ppmVd 

5.192E-08 Ib/dscf I ppmVd 

Instrumental Data 

3.94 %-dry 

15.1 %-dry 

80.96 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCI 

Conversion Factor for HF 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1"" Y .. Vm '" (Pb + dH/13.6) I Tm 

Vmstd = 118.814 dscf 

3.36 dscm 

Unit No.4 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 • Vie 

Vw(std) = 16.992 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.125 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) I + (1S'Bws) 

Ms= 2900 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP)' (Ts/Ps'Msl' 5 

Vs = 46.06 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min"" Vs ., As 

Qa = 230260 5 efm 

6521.0 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa • (TstdlTs) • (Ps/Pstd) , (1-Bws) 

Qstd = 163888.1 dscfm 

4641.3 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Hydrogen Chloride Concentration and Emissions 

Umt No, 4 

Two 

M[HCI[ = M[CI-[(mg) , MW[HCI](mglmmol) 1 MW[CI-](mglmmol) 

Page 3 

C[HCI] = (M[HCI](mg) , 2.205E-06(lblmg) , 21.85(scf"inHgllbmol'R) , K1 • 10'6) 1 (MW[HCI](lbllbmol) 'Vmstd(d 

C[HCI](@corr 02) = C[HCI](ppmV)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HCI] = M[HCI](mg)' Qstd(dscfm)' (2 205E-06)(lblmg)' 60(mlnlhr) 1 Vmstd(dscf) 

E[HCI] = C[HCI](ppmV)' Fd' CF(HCI)' (20.91(20.9-%02)) 

<: M[HCI] = 0.06 mg 

< C[HCI] = 0.012 ppmV 

< C[HCI] = 0.010 ppmV (@ 7.0 %02) 

< E[HCI] = 0.011 Ib/hr 

< E[HCI] = 1.36E-05 IblMMBtu 

9) Hydrogen Fluoride Concentration and Emissions 

C[HF] = M[HF](mg) IVmstd(dscm) 

C[HF] = (M[HF](mg)' 2.205E-06(lblmg)' 21 85(scf"inHgllbmol'R)' K1 • 10'6) 1 (MW[HF](Ibllbmol)' Vmstd(dsc 

C[HF](@corr. 02) = C[HF](mgldscm)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HF] = C[HF](mgldscm) • Qstd(dscmm) • (2.205E-06)(lblmg) , 60(minlhr) 

E[HF] = C[HF](ppmV)' Fd' CF(HF)' (20.91(20.9-%02)) 

M[HF] = 

C[HF] = 

C[HF] = 

C[HF] = 

E[HF] = 

E[HF] = 

10) Isokinecity, I. 

0.630 mg 

0.1 B7 mg/dscm 

0.225 ppmV 

0.185 ppmV (@ 

0.1151b/hr 

1.43E-04 IblMMBtu 

7.0 

% I = (100'Ts·(K3·Vlc+(Vm·YlTm)(Pb+dHI13.6)))1(60·t·Ps·Vs·An) 

% I = 102.5 

%02) 
3333-HCI-HF-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

PStatlC = 

Pb = 

Ps = 

Pstd = 

dP= 

dH = 

Tm= 

Ts= 

Tstd= 

Dn = 

An = 

y= 

t = 

Ds= 

As= 

Cp = 

Kp= 

K1 = 

K2= 

K3= 

Fd = 

CF = 

CF = 

[02[ 

[C02[ 

[N2) 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and 26A 

[Flows, 02/C02, H20,and HCIIHF) 

Spruance Genco, LLC 

3333 

Unit No.4 

Three 

04/19/10 

1658-2017 

Emission Data 

307.7 cc 

104.628 del 

-0.50 in. H2O 

29.98 in. Hg 

29.94 in. Hg 

29.92 in. Hg 

0.6835 in. H20 1\ 5 

1 146 in. H20 

537.6 R 

649.4 R 

527.7 R 

0.245 in. 

0.000327 sq. ft. 

1.02 

180 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq. ft Cross sectional area of stack 

0.84 Pltot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]1I.5}/[s*R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 eu.ftlml 

0.0026688 in.Hg-el/ml-R 

9705 scf/MMBtu 

9461 E-08 Ib/dsel I ppmVd 

5.192E-08 Ib/dscf I ppmVd 

Instrumental Data 

6.35 %-dry 

12.8 %-dry 

80.85 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCI 

Conversion Factor for HF 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentratIon 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y' Vm' (Pb + dH/13.6) I Tm 

Vmstd = 105.265 dscf 

2.98 dscm 

Unit No 4 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 'Vic 

Vw(std) = 14.483 scI 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 0121 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (1-Bws) I + (18'Bws) 

Ms = 28.81 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp , Cp , (dP) , (Ts/Ps'Ms)A5 

Vs = 42.58 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs .. As 

Qa = 212888.5 cfm 

6029.0 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa ' (TstdlTs) , (Ps/Pstd) , (1-Bws) 

Qstd = 152195.2 dscfm 

4310.2 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test location 

Test Run 

Calculations (cont.) 

8) Hydrogen Chloride Concentration and Emissions 

Unit No.4 

Three 

M[HCI] = M[CI-](mg) • MW[HCI](mg/mmol) 1 MW[CI-](mg/mmol) 

Page 3 

C[HCI] = (M[HCI](mg) • 2 205E-06(lb/mg) • 21.85(scf'lnHg/lbmol'R) • K1 • 10'6) 1 (MW[HCI](lbllbmol) • Vmstd(d 

C[HCI](@corr 02) = C[HCI](ppmV)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HCI] = M[HCI](mg) • Qstd(dscfm) • (2.205E-06)(lb/mg) • 60(min/hr) 1 Vmstd(dscD 

E[HCI] = C[HCI](ppmV)' Fd' CF(HCI)' (20.9/(20.9-%02)) 

M[HCI]= 0.30 mg 

C[HCI] = 0.066 ppmV 

C[HCI] = 0.063 ppmV (@ 7.0 % 02) 

E[HCI] = 0.057 Ib/hr 

E[HCI] = 8.76E-05 Ib/MMBtu 

9) Hydrogen Fluoride Concentration and Emissions 

C[HF] = M[HF](mg) IVmstd(dscm) 

C[HF] = (M[HF](mg) , 2.205E-06(lb/mg) • 21.85(scf'inHgllbmol·R) • K1 • 10'6) 1 (MW[HF](lbllbmol) • Vmstd(dsc 

C[HF](@corr. 02) = C[HF](mg/dscm)' [(209-corrected 02) 1 (20.9-actual %02)] 

E[HF] = C[HF](mg/dscm)' Qstd(dscmm)' (2.205E-06)(lb/mg)· 60(min/hr) 

E[HF] = C[HF](ppmV)' Fd' CF(HF)' (20.9/(20 9-%02)) 

M[HF] = 

C[HF] = 

C[HF] = 

C[HF] = 

E[HF] = 

E[HF] = 

10) Isokinecity, I. 

0.590 mg 

0.198 mgJdscm 

0.238 ppmV 

0.227 ppmV ( @ 

0.1131bJhr 

1.72E-04Ib/MMBtu 

7.0 

% 1 = (100"Ts·(K3'Vlc+(Vm'YlTm)(Pb+dH/13.6»)/(60't'Ps'Vs·An) 

% I = 978 

% 02) 
Client 

Project No. 

Test Location 

Fuel Type 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

PstatlC = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts= 

Tstd= 

y= 

1= 

Dn = 

An = 

Ds = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[O2[ 

[C02[ 

[N2] 

[CO[ 

[THC[ 

[CH4[ 

[NOx[ 

[S02[ 

AirNova, Inc. Page 1 of4 

EPA Methods 1, 2, 3A, 4, 6, 7E, 10, 18 and 25A 

(Flows. 021C02, H20, 502, NOx, CO and NMHC) 

Spruance Genco. LLC 

3333 

Unit No, 4 

Coal 

One 

04/19/10 

0923-1235 

316.6 cc 

Emission Data 

116.777 dcf 

-0.50 in. H20 

30.10 m. Hg 

30.06 in. Hg 

29.92 in. Hg 

0.7441 in, H20 ".5 

1.36 in. H20 

522.5 R 

652.3 R 

527.7 R 

1.02 

180 min. 

0.245 m. 

0,000327 sq. ft. 

10.300 ft, 

83.3231 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbllbmol)*(inHg)]1I.5}/[s·R·inH20] 

17.637 R/m.Hg constant 

0,047070 cu.ftlml constant Pitot tube constant 

0.0026688 in.Hg-cf/ml-R constant 

9777 scf/MMBtu From EPA Reference Method 19 

Instrumental Data 

4.50 %-dry 

15,12 %-dry 

80.38 %-dry 

206.6 ppmV·dry 

0.5 ppmV-wet 

0.0 ppmV-dry 

200.8 ppmV-dry 

50.3 ppmV-dry 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Carbon Monoxide concentration 

Total Hydrocarbon concentration 

Methane Concentration by GC-FID 

Nitrogen Oxides concentration 

Sulfur Dioxide concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y '* Vm * (Pb + dH/13 6) / Tm 

Vmstd = 121.416 dscf 

3.439 dscm 

Unit No, 4 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 • Vic 

Vw(std) = 14,902 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 0,1093 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = ( ({44*%C02) + (32*%02) + (28*%N2)) * (1-Bws) I + (18*Bws) 

Ms = 29.222 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs c Kp· Cp * (dP) * (Ts/Ps*Ms)".5 

Vs = 46,046 fps 

6) Average actual stack gas volumetric f1owrate, Qa. 

Oa = 60 sec/min· Vs • As 

Qa = 230203.0 cfm 

6519.3 cmm 

7) Average stack gas dry volumetric f1owrate, Qstd. 

Qstd =: Qa <; (TstdfTs) '* (PslPstd) '* (1-Bws) 

Qstd = 166670.1 dscfm 

47201 dscmm 

Page 2 of 4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No 4 

One 

Page 3 of4 

8) Total Hydrocarbon concentrations and emissions 

INPUT 

C[THC] dry basis = CITHC] weU{1-Bws) 

C[VOC] dry basis = C[THC] - C[CH4] 

Corr_ C[CH4] = {{20.9-02% corr. value)/(20.9-actuaJ avg. 02% value))*VOC value 

E[VOC] = (C[VOC]*Mol Wt[VOC equivalenW60(min/hr)"*Qstd{dscfm))/{Molar Vol. air*10"S) 

E[VOC Jb/MMBtu] = Cd .. Fd ~ (20.9/{20.9-actual 02%)) 

C[THC] = 0.5 ppmVw 

C[THC] = 0.6 ppmVd 

C[CH4] = 0.0 ppmVd 

C[VOC] = 0.6 ppmVd 

C[VOC] = 0.5 ppmVd corrected to 7 % 02 

Mol. WI. [THC]= 44.096 Ib/lb-mole Propane 

Molar vol air= 385 scf/lb-mole @ 68 def F 

E]VOC[ = 0 64 Iblh, 

Conv Factor. 

E[VOC] = 

4.134E-08 convert ppmV to Ib/scf THC as CH4 

2.89E-04 Ib/MMBtu 

9) Nitrogen Oxides concentrations and emissions 

Corr. C[NOx] = «20.9-02% carr value)/{20.9-actual avg. 02% value))*Avg. raw NOx value 

E[NOx] = (C[NOxl~Mol Wt[NOx]*SO{min/hr)*Qstd(dscfm))/(Molar Vol. air*10"6) 

E{NOx Ib/MMBtu] = Cd" Fd * (20.9/(20.9-actual 02%)) 

C[NOx] = 200.8 ppmVd 

C[NOx] = 170.2 ppmVd corrected to 7 % 02 

Mol. Wt. [NOx]= 46.01 Ib/lb-mole 

Molar vol air= 

E[NOx] = 

Conv Factor. 

E[NOx] = 

385 scf/lb-mole @ 

239.97 Ib/hr 

68 

1.194E-07 convert ppmV to Ib/scf NOx 

0.299 Ib/MMBtu 

def F 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Unit No.4 

One 

Page 4 of 4 

10) Carbon Monoxide concentrations and emissions 

Carr. qCO] = «20.9-02% carr. value)/(20.9-actual avg. 02% value))*Avg. raw CO value 

E[CO Ib/hr] = (qCO]*Mol Wt[CO]*60(min/hrrQstd(dscfm))/(Molar Vol. alr*10"6) 

E[CO Ib/MMBtu] = Cd ,. Fd ~ (20.9/(20.9·actual 02%» 

qCO] = 206.6 ppmVd 

qCO] = 175,1 ppmVd corrected to 7 % 02 

Mol Wt. [CO]= 28.01 Ib/lb-mole 

Molar vol air= 385 scf/lb-mole @ 68 def F 

E[CO] = 150.31 Ib/hr 

Conv Factor. 7.235E-08 convert ppmV to Ib/scf CO 

E[CO] = 0.186 Ib/MMBtu 

11) Sulfur Dioxide concentrations and emissions 

Carr C[S02] = «20.9-02% carr. value)/(20 9-actual avg. 02% value))*Avg. raw S02 value 

E(lb/MMBtu) = Cd(lb/scf) ~ Fd(scf/MMBtu) * [20.91 (20.9-% 02)] 

E[S02 Ib/hr] = (C[S02l*Mol Wt[S02]*60(min/hrtQstd(dscfm))/(Molar Vol air*10"6) 

qS02] = 50.3 ppmV (dry) Actual Conc. 

C[S02] = 42,6 ppmVd corrected to 7 % 02 

Mol Wt. [S02]= 64.06 Ib/lb-mole 

Molar vol air= 

Conv Factor. 

E[S02] = 

E[S02] = 

385 scf/lb-mole @ 68 

1.66E-07 convert ppmV to Ib/scf 502 

0.104 Ib/MMBtu 

83,70 Ib/hr 

defF 
Client 

Project No. 

Test Location 

Fuel Type 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

INPUT Tstd= 

INPUT y= 

INPUT t = 

INPUT Dn = 

An = 

INPUT Ds = 

As = 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[02J 

[CO2] 

[N2J 

[COJ 

[THC] 

[CH4] 

[NOxJ 

[S02] 

AirNova, Jnc. 

EPA Methods 1, 2, 3A, 4, 6, 7E, 10, 18 and 25A 

(Flows, 02/C02, H20, S02, NOx, CO and NMHC) 

Spruance Genco, LLC 

3333 

Unit No.4 

Coal 

Two 

04/19/10 

1310-1622 

Emission Data 

361 cc 

117.695 dcf 

-0.50 in. H2O 

30.04 in. Hg 

30.00 in. Hg 

29.92 in. Hg 

0.7418 m. H20 A.5 

1.40 in. H2O 

537.2 R 

650.5 R 

527.7 R 

102 

180 min. 

0.245 in. 

0.000327 sq ft 

10.300 ft. 

833231 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]A 5}/[s~R*inH201 

17.637 R/in.Hg constant 

0.047070 cU.ft!ml 

0.0026688 in.Hg-cf/ml-R 

9920 scf/MMBtu 

Instrumental Data 

3.94 %-dry 

15.10 %-dry 

80.96 %-dry 

388.1 ppmV-dry 

0.4 ppmV-wet 

constant Pltot tube constant 

constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Carbon Monoxide concentration 

Total Hydrocarbon concentration 

Page 1 of4 

0.0 ppmV-dry Methane Concentration by GC-FID 

211.3 ppmV-dry Nitrogen Oxides concentration 

47.5 ppmV-dry Sulfur DiOXide concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1· Y· Vm· (Pb + dH/13.6) / Tm 

Vmstd= 118.814 dscf 

3.365 dscm 

Unit No, 4 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw{std) = K2 '" Vic 

Vw(std) = 16.992 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.1251 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = r ((44*%C02) + (32*%02) + (28*%N2»'" (1-Bws) J + (18*Bws) 

Ms= 29.000 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp '* Cp * (dP);O (Ts/Ps"'Ms)".5 

Vs = 46,058 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min '* Vs ... As 

Oa = 230260.5 cfm 

65210 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Oa· (TstdfTs)· (Ps/Pstd)'" (1-Bws) 

Ostd = 163888.1 dscfm 

4641.3 dscmm 

Page 2 of4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test location 

Test Run 

Calculations (cont.) 

Unit No.4 

Two 

Page 3 of4 

8) Total Hydrocarbon concentrations and emissions 

INPUT 

C[THCJ dry basis = C[THCJ weU(1-Bws) 

C[VOC] dey basis = C[THC]- C[CH4] 

Carr C[CH4] = «20.9-02% carr. varue)/(20 9-actual avg. 02% value))*VOC value 

E[VOCJ = (C[VOCl"Mol Wt[VOC equivalent]*60(min/hr)*Qstd(dscfm))/(Morar Vol. air*10"6) 

E[VOC Ib/MMBtu] = Cd" Fd * (20 9/(20.9-aclual 02%)) 

C]THC] = 0.4 ppmVw 

C[THC] = 0.5 ppmVd 

C]CH4] = 0.0 ppmVd 

C]VOC] = 0.5 ppmVd 

C[VOC] = 0.4 ppmVd corrected to 

Mol. Wt. [THC]= 44.096 Ib/lb-mole 

385 scf/lb-mole @ 

0.51 Ib/hr 

7 

Propane 

Molar vol air= 68 

E]VOG] = 

Conv Factor 

E[VOG] = 

4.134E-08 convert ppmV to lb/scf THC as CH4 

2.31 E-04 Ib/MMBtu 

%02 

def F 

9) Nitrogen Oxides concentrations and emissions 

Carr. C[NOx] = «20.9-02% carr. value)/(20.9-actual avg. 02% value)}"Avg. raw NOx value 

E[NOx] = (C[NOxl"Mol Wt[NOx]~60(min/hr)*Qstd(dscfm))/(Molar Vol air*10"6) 

E[NOx Ib/MMBtu] = Cd" Fd" (20.9/(20.9-actual 02%)) 

C[NOx] = 211.3 ppmVd 

C[NOx] = 173.2 ppmVd corrected to 7 % 02 

Mol. WI. [NOx]= 46.01 Ib/lb-mole 

Molar vol air= 385 scfllb-mole @ 68 def F 

E[NOx] = 248.31 Ib/hr 

Conv Factor. 

E[NOx] = 

1.194E-07 convert ppmV to Ib/sct NOx 

0.308 Ib/MMBtu 
Client 

Project No. 

8pruance Genco, LLC 

3333 

Test Location 

Test Run 

Unit No.4 

Two 

Page 4 of4 

10) Carbon Monoxide concentrations and emissions 

Carr. qCO] = «20.9-02% corr. value)/(20.9-actual avg. 02% value))*Avg. raw CO value 

E[CO Ib/hr] = (C[COl"Mol Wt[CO]*60(min/hr)"Qstd(dscfm»)/(Molar Vol. alr"10116) 

E[CO Ib/MMBtu] = Cd· Fd· (20.9/(20.9-actual 02%» 

CleO] = 388.1 ppmVd 

C[CO] = 318.1 ppmVd corrected to 7 % 02 

Mol. WI. [CO]= 28.01 Ib/lb-mole 

Molar vol air= 385 scf/lb-mole @ 68 def F 

ErCO] = 277.65 Ib/hr 

Conv Factor. 7.235E-08 convert ppmV to Ib/scf CO 

E[CO] = 0.343 Ib/MMBtu 

11) Sulfur Dioxide concentrations and emissions 

Carr. C[802] = «20.9-02% corr. value)/(20 9-actual avg. 02% value»*Avg. raw 802 value 

E(lb/MMBtu) = Cd(lb/scf) • Fd(scf/MMBtu) * [20.91 (20.9-% 02)] 

E[S02 Ib/hr] = (C[802]*Mol Wt[S02]~60(min/hr)·Qstd(dscfm))/(Molar Vol. air*10116) 

C[S02] = 47.5 ppmV (dry) Actual Conc. 

C[S02] = 38.9 ppmVd corrected to 7 % 02 

Mol. Wt. [802]= 64.06 Ib/lb-mole 

Molar vol air= 

Conv Factor. 

E[802] = 

E[802] = 

385 scfllb-mole @ 68 

1.66E-07 convert ppmV to Ib/scf S02 

0.096 Ib/MMBtu 

77.72 Ib/hr 

def F 
Client 

Project No. 

Test Location 

Fuel Type 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

y= 

t = 

Dn = 

An = 

Ds = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

[02[ 

[C02[ 

[N2[ 

[COl 

[THC[ 

[CH4[ 

[NOx[ 

[802] 

AirNova, Inc. Page 1 of4 

EPA Methods 1, 2, 3A,4, 6, 7E, 10, 18 and 25A 

(Flows, 02/C02, H20, S02, NOx, CO and NMHC) 

Spruance Genco, LLC 

3333 

Unit No_ 4 

Coal 

Three 

04/19/10 

1658-2017 

Emission Data 

307.7 cc 

104.628 dcf 

-0.50 in. H20 

29.98 rn. Hg 

29.94 in. Hg 

29.92 in. Hg 

0.6835 in. H20 ".5 

1.15 in. H2O 

5376 R 

649.4 R 

527.7 R 

1.02 

180 min. 

0.245 in. 

0.000327 sq. ft 

10.300 ft. 

83.3231 sq. ft 

Vol of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitottube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]II.5}/[s*R*inH20] 

17.637 R/in.Hg constant 

0.047070 cu.ftlml constant Pitot tube constant 

0.0026688 in Hg-cf/ml-R constant 

9705 scf/MMBtu From EPA Reference Method 19 

Instrumental Data 

6.35 %-dry Oxygen concentration 

1280 %-dry Carbon Dioxide concentration 

80.85 %-dry Nitrogen concentration 

161.6 ppmV-dry Carbon Monoxide concentratIon 

0.3 ppmV-wet Total Hydrocarbon concentration 

0.0 ppmV-dry Methane Concentration by GC-FID 

177.9 ppmV-dry Nitrogen Oxides concentration 

35.8 ppmV·dry Sulfur Dioxide concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm * (Pb + dH/13.6) I Tm 

Vmstd = 105.265 dscf 

2.981 dsem 

Unit No.4 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 .. Vic 

Vw(std) = 14.483 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1209 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44*%C02) + (32"%02) + (28*%N2» ~ (1·Bws) 1 + (18*Bws) 

Ms= 28.814 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp" (dP) ~ (Ts/Ps*Ms)".5 

Vs = 42.583 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min" Vs * As 

Oa = 212888.5 cfm 

6029.0 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa * (TstdlTs) .. (Ps/Pstd) .. (1-Bws) 

Qstd = 152195 2 dscfm 

43102 dscmm 

Page 2 of 4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.4 

Three 

Page 3 of 4 

8) Total Hydrocarbon concentrations and emissions 

INPUT 

C[THC] dry basis = C[THC] weU(1-Bws) 

C[VOC] dry basis = C{THC] - C[CH4] 

Corr. C[CH4] = «20.9-02% corr. value)/(20 9-actual avg. 02% value))*VOC value 

E[VOC] = (C[VOC]*Mol Wt[VOC equivalenW60(min/hr)*Qstd(dscfm))/(Molar Vol. air*10"6) 

E[VOC Ib/MMBtu] = Cd'" Fd'" (20.9/(20.9-actual 02%)) 

C{THC] = 0.3 ppmVw 

C[THC] = 0.3 ppmVd 

C[CH4] = 0.0 ppmVd 

C[VOC] = 0.3 ppmVd 

C[VOC] = 0.3 ppmVd corrected to 7 % 02 

Mol. Wt. [THC]= 44.096 Ib/lb-mole Propane 

Molar vol air= 385 scf/lb-mole @ 68 def F 

E[VOC] = 0.36 Ib/hr 

Conv Factor 

E[VOC] = 

4.134E-08 convert ppmV to Ib/scf THC as CH4 

1.97E-04 Ib/MMBtu 

9) Nitrogen Oxides concentrations and emissions 

Corr. C[NOx] = «20 9-02% corr. value)/(20.9-actual avg. 02% value))*Avg. raw NOx value 

E[NOx] = (C[NOxl~Mol Wt[NOx]*60(min/hr)"Qstd(dscfm))/(Molar Vol. air"10"6) 

E[NOx Ib/MMBtu] = Cd " Fd " (20.9/(20.9-actual 02%)) 

C{NOx] = 177.9 ppmVd 

C{NOx] = 170.0 ppmVd corrected to 7 % 02 

Mol Wt. [NOx]= 46.01 Ib/lb-moJe 

Molar vol air= 385 scf/lb-mole @ 68 def F 

E[NOx] = 194.14 Ib/hr 

Conv Factor 1.194E-07 convert ppmV to Ib/scf NOx 

E[NOx] = 0.296 Ib/MMBtu 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test location 

Test Run 

Umt No, 4 

Three 

Page 4 of4 

10) Carbon Monoxide concentrations and emissions 

Corr. C[CO] = «20.9-02% corr. value)/(20 9-actual avg. 02% value))"'Avg. raw CO value 

E[CO Ib/hr] = (C[CO]*Mol WI[CO]*60(min/hr)*Qstd(dscfm))/(Molar Vol. alr*10"6) 

E[CO Ib/MMBlu] = Cd ~ Fd ~ (20.9/(20.9-actual 02%» 

qCO] = 161.6 ppmVd 

C[eO] = 154.4 ppmVd corrected to 7 % 02 

Mol. WI. (CO]= 2801 Ibllb-mole 

Molar vol air= 

E[CO[ = 

Conv Factor. 

E[CO[ = 

385 scfllb-mole @ 

107.36 Ib/hr 

7.235E-08 convert ppmV to Ib/scf CO 

0.163 Ib/MMBtu 

11) Sulfur Dioxide concentrations and emissions 

68 def F 

Corr. C[S02] = «20.9-02% corr. value)/(20.9-aclual avg. 02% value»*Avg. raw S02 value 

E(lb/MMBlu) = Cd(lb/scf) * Fd(scf/MMBtu) ~ [20.91 (20_9-% 02)] 

E[S02 Ib/hr] = (C[S02]*Mol Wt[S02]*60(min/hr)*Qsld(dscfm))/(Molar Vol. air~1 0"6) 

qS02] = 35.8 ppmV (dry) Actual Conc. 

C[S021 = 34.2 ppmVd corrected 10 7 % 02 

Mol. WI. [502]= 64.06 Ib/lb-mole 

Molar vol alr= 

Conv Factor. 

E[S02[ = 

E[S02] = 

385 scf/lb-mole@ 68 

1.66E-07 convert ppmV 10 Jb/scf 502 

0.083 Ib/MMBtu 

54.40 Ib/hr 

def F 
3333-HCN-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

VIc = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

t = 

Ds= 

As= 

Cp = 

Kp = 

K1 = 

K2= 

K3= 

Fd = 

CF= 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and Modified 26 

(Flows, 021C02, H20,and HCN) 

Spruance Genco, LLC 

3333 

Unit No.4 

One 

04/19/10 

0923-1023 

134.2 cc 

42.168 def 

Emission Data 

-050 in. H20 

30.10 in. Hg 

30.06 in. Hg 

29.92 in. Hg 

0.7443 in. H20 11.5 

1.600 in. H20 

5248 R 

6532 R 

527.7 R 

o in. 

0.000000 sq. ft. 

1.00 

60 mm. 

10.300 ft. 

Vol of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq. ft. Cross sectional area of stack 

0,84 Pitot tube coefficient 

85.49 ft[(lbllbmol),(inHg)]'.5}/[s·R·inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.ft!ml 

0.0026688 in.Hg-eflml-R 

9777 scf/MMBtu 

7.014E-08 Ibldsef I ppmVd 

Instrumental Data 

4.5 %-dry 

15.12 %-dry 

80.38 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCN 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1" Y "Vm " (Pb + dH/13.6) I Tm 

Vmstd = 42.824 dscf 

1.21 dscm 

Unit NO.4 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 "Vic 

Vw(std) = 6.317 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.129 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44"%C02) + (32"%02) + (28"%N2))" (1-Bws) 1 + (18"Bws) 

Ms = 28.98 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp" Cp" (dP) " (Ts/Ps"Ms)'.5 

Vs = 46.28 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min'" Vs ... As 

Qa= 2313794 cfm 

6552.7 cmm 

7) Average stack gas dry volumetric flowrate, Ostd. 

Qstd = Qa " (TstdlTs) " (Ps/Pstd) " (1-Bws) 

Qstd = 1636761 dscfm 

46353 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

8) Hydrogen Cyanide Concentration and Emissions 

Unit No.4 

One 

M[HCN] = M[CN-](mg) , MW[HCN](mg/mmol) 1 MW[CN-](mg/mmol) 

Page 3 

C[HCN] = (M[HCN](mg) '2.205E-06(lb/mg) , 21.85(scf'inHg/lbmol'R) • K1 ' 10'6) 1 (MW[HCN](lb/lbmol) 'Vmsl 

C[HCN](@corr. 02) = C[HCN](ppmV)' [(20.9-corrected 02) 1 (20.9-octuol %02)] 

E[HCN] = M[HCN](mg) , Ostd(dscfm) • (2.205E-06)(lb/mg) • 60(min/hr) 1 Vmstd(dscf) 

E[HCN] = C[HCN](ppmV) • Fd • CF(HCN) • (20.9/(20.9-%02)) 

< M[HCN] = 

< C[HCN] = 

< C[HCN] = 

< E[HCN] = 

< E[HCN]= 

0.004 mg 

0.003 ppmV 

0.002 ppmV 

0.002 Ib/hr 

2.57E-06 Ib/MMBtu 

(@ 70 %02) 
3333-HCN-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts= 

Tstd= 

On = 

An = 

y= 

t = 

Ds= 

As= 

Cp= 

Kp= 

K1 = 

K2= 

K3 = 

Fd = 

CF = 

[02[ 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and Modified 26 

(Flows, 021C02, H20,and HCN) 

Spruance Genco, LLC 

3333 

Unit NO.4 

Two 

04/19/10 

1310-1410 

140.9 cc 

42.104 del 

Emission Data 

-0.50 in, H20 

30.04 in. Hg 

30.00 in. Hg 

29.92 in. H9 

0.7423 in. H20 A.5 

1.600 in H20 

5315 R 

652.4 R 

527.7 R 

o in. 

0.000000 sq. ft. 

1.00 

60 min, 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.323 sq. ft. Cross sectional area of stack 

0,84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)""(inHg)]",5}/[s"R"[nH20] P[tot tube constant 

17.637 R/in Hg 

0.047070 cu fUml 

0.0026688 in.Hg-cflml-R 

9920 scf/MMBtu 

7.014E-08 Ibldsell ppmVd 

Instrumental Data 

394 %-dry 

15.1 %-dry 

80.96 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCN 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y 'Vm ' (Pb + dHI13.6) I Tm 

Vmstd = 42.132 dscf 

1.19dscm 

Unit NO.4 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 'Vie 

Vw(std) = 6.632 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 0.136 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (1-Bws) I + (18'Bws) 

Ms= 28.86 Ibllbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP) , (TsIPs'Ms)'.5 

Vs= 4627 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min * Vs * As 

Qa = 231299.1 efm 

6550.4 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa' (TstdlTs)' (PsIPstd)' (1-Bws) 

Qstd = 162101.8 dscfm 

4590.7 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

8) Hydrogen Cyanide Concentration and Emissions 

Unit No.4 

Two 

M[HCN] = M[CN-](mg)' MW[HCN](mg/mmol) 1 MW[CN-](mg/mmol) 

Page 3 

C[HCN] = (M[HCN](mg) • 2.205E-06(lb/mg) • 21.85(scf"inHg/lbmol·R) • K1 • 10'6) 1 (MW[HCN](Ib/lbmol) • Vmsl 

C[HCN](@corr. 02) = C[HCN](ppmV)' [(20.9-corrected 02) 1 (20.9-actual %02)] 

E[HCN] = M[HCN](mg) • Qstd(dscfm) • (2.205E-06)(lb/mg) • 60(min/hr) 1 Vmstd(dscf) 

E[HCN] = C[HCN](ppmV) • Fd • CF(HCN) • (20.9/(20.9-%02)) 

< M[HCN] = 0.005 mg 

< C[HCN] = 0.004 ppmV 

< C[HCN] = 0.003 ppmV (@ 7.0 % 02) 

< E[HCN] = 0.003 Ib/hr 

< E[HCN] = 3.20E-06 Ib/MMBtu 
3333-HCN-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

t = 

Ds = 

As = 

Cp= 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

CF= 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and Modified 26 

(Flows, 02fC02, H20,and HCN) 

Spruance Genco, LLC 

3333 

Unit No.4 

Three 

04/19/10 

1658-1758 

120,8 cc 

42.395 del 

Emission Data 

-0.50 in. H20 

29,98 in. Hg 

29.94 in. Hg 

29.92 in. Hg 

0.6856 in. H20 11,5 

1.600 in. H20 

530.0 R 

652.9 R 

527.7 R 

o in. 

0.000000 sq. ft. 

1.00 

60 mm. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of samphng time 

Diameter of stack 

83_323 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft.[(lb/lbmol)"(inHg)]".5}/[s*R*inH20] Pltot tube constant 

17.637 R/in.Hg 

0.047070 cu.fUml 

0.0026688 in.Hg-cf/ml-R 

9705 scf/MMBtu 

7.014E-08 Ibfdscff ppmVd 

Instrumental Data 

6.35 %-dry 

12.8 %-dry 

80.85 %-dry 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for HCN 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1'" Y· Vm '" (Pb + dH/13.6) I Tm 

Vmstd = 42.466 dscf 

1.20 dsem 

Unit No.4 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 ' Vic 

Vw(std) = 5.686 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd , (Vmstd+Vwstd) 

Bws= 0.118 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44'%C02) + (32'%02) + (28'%N2))' (1-Bws) I + (18'Bws) 

Ms= 28.85 fbi Ibmole 

5) Average stack gas velocity, Vs. 

Vs = Kp' Cp' (dP) , (TsIPs'Ms)'.5 

Vs = 42.80 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 see/min '" Vs '" As 

Qa = 213971.2 cfm 

6059.7 emm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa' (Tstd/Ts)' (PsIPstd)' (1-Bws) 

Qstd = 152644.6 dsefm 

4322.9 dsemm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

8) Hydrogen Cyanide Concentration and Emissions 

Unit No.4 

Three 

M(HCN] = M(CN-lImg) , MW(HCN](mg/mmol) 1 MW(CN-](mg/mmol) 

Page 3 

C(HCN] = (M(HCN](mg) , 2.205E-06(1b/mg) , 21.85(scf"inHg/lbmol'R) , K1 • 10'6) 1 (MW(HCN](lb/lbmol) 'Vmsl 

C(HCNII@corr. 02) = C(HCNlIppmV) , ( (20.9-corrected 02) 1 (20.9-actual %02) ] 

E(HCN] = M(HCN](mg) , Qstd(dscfm) , (2.205E-06)(lb/mg) '60(min/hr) 1 Vmstd(dscD 

E(HCN] = C(HCN](ppmV) , Fd ' CF(HCN) • (20.9/(20 9-%02)) 

M(HCN] = 0.096 mg 

C(HCN] = 0.071 ppmV 

C(HCN] = 0.068 ppmV (@ 7.0 %02) 

E(HCN] = 0.046 Ib/hr 

E(HCN]= 6.95E-05 Ib/MMBtu 
3333-Formaldehyde-R 1 

Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

Vic = 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

y= 

t= 

On = 

An = 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

CF = 

[02J 

[C02J 

[N2J 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and RCRA Method 0011 

(Flows, 02/C02, H20, and Formaldehyde) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit No.4 

04/19/10 

Ooe 

0924-1133 

Emission Data 

239.8 cc 

83.469 dcf 

-0.50 in. H20 

30.10 in. Hg 

30.06 in. Hg 

29.92 in. Hg 

0.731 in. H20 ".5 

1.26 in. H20 

523.6 R 

655.0 R 

527.7 R 

0.97 

120 min. 

0.248 in. 

0.000335 sq. ft. 

10.30 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibratIon factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[{lb/lbmol)*{inHg)]".S}/[s*WinH20] Pitot tube constant 

17.637 R/in Hg constant 

0.047070 cu.ftlml 

o 0026688 in.Hg-cf/ml-R 

9777 scf/MMBtu 

7793E·08 Ib/dscf I ppmVd 

constant 

constant 

Fuel Factor 

Conversion Factor for CH20 

EPA Method 3A Instrumental Data 

4.50 %·dry 

15.12 %-dry 

80.38 %-dry 

Oxygen concentration 

Carbon DioxIde concentration 

Nitrogen concentration 

Data from: 

EPA4 

EPA4 

EPA2 

EPA2 

EPA2 

EPA4 

EPA4 

EPA2 

EPA2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm * (Pb + dH/13.6) / Tm 

Vmstd = 82.339 dscf 

2.332 dscm 

Richmond, Virginia 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

\Iw(std) = K2 • Vb 

Vw(std) = 11.287 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 0.1206 

4) Molecular weight of the stack gas on a wet basIs, Ms. 

Ms = [«44*%C02) + (32·%02) + (28*%N2»;O (1-Bws) 1 + (18*Bws) 

Ms= 29.080 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp;O Cp .. (dP) .. (Ts/Ps"Ms)".5 

Vs = 45.416 fps 

6) Average actual stack gas volumetric flowrate, Oa. 

Oa = 60 sec/min" Vs * As 

Oa = 227043.31 cfm 

6429.87 cmm 

7) Average stack gas dry volumetric flowrate, Ostd 

Qstd = Oa'" (TstdlTs)" (Ps/Pstd)" (1-Bws) 

Qstd = 

Qstd = 

161627.12 dscfm 

4577.28 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cont.) 

8) Formaldehyde· Concentrations and Emission Rates 

M[CH20] = sample mass (mg) 

Richmono, Virginia 

One 

C[CH20] = M[CH20] (mg) 1 sample volume (dscm) 

C[CH20 @ corr %02] = C[CH20] (ppmV) * (20.9-Corr. %02)f(20.9-Actual %02) 

Corrected 02 Percentage = 7 % 

E[CH20] = C[CH20] (mg/dscm) * 60 (min/hr) * Qstd (dscmm) * (1 Ib /4.536 e+05 mg) 

E[CH20](lb/MMBtu) = C[CH20](ppmV) CF;O Fd ... (20.9/20.9·%02) 

Page 3 

Comgound Samgle Mass Concentration Concentration Concentration Mass Emission Mass Emili,§ion 

!ml!l (mg/dscm) !JlQmlQ 'gmV@Corr.%O (lblhrl (lb/MMBtu) 

Formaldehyde 0.00720 3.09E-03 2.47E-03 2.10E-03 1.B7E-03 2.40E-06 

NO NO NO NO NO NO 

9) Isokinecity, I. % I = [100*Ts*.(K3*Vlc+«{Vm*y)fTmt(Pb+(dH/13.6»)))] 1 (60*t*Ps·Vs*An) 

% I = 105.45 
3333-Formaldehyde-R2 

Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd ;; 

dP = 

dH = 

Till = 

Ts = 

Tstd= 

y= 

t= 

On ;; 

An ;; 

Os = 

As = 

Cp= 

Kp = 

K1 = 

K2 = 

K3 ;; 

Fd = 

CF = 

[021 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and RCRA Method 0011 

(Flows, 02/C02, H20, and Formaldehyde) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit No.4 

04f19f10 

Two 

1310-1520 

Emission Data 

256.5 cc 

84.875 dcf 

-0.50 in H20 

30.04 in Hg 

30.00 in Hg 

29.92 in Hg 

0.738 in H20 ",5 

1.33 in H20 

542.6 R 

654.4 R 

527. 7 R 

0.97 

120 min. 

0.248 in 

0.000335 sq, ft. 

10.30 ft 

Vol of H20 collected 

Dry gas meter reading 

StatIc pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

83.3204 sq. ft. Cross sectIonal area of stack 

0.B4 Pitot tube coefficient 

85.49 ft[{lbflbmol)~(inHg)11\.5}f[s*R*inH20] Pitot tube constant 

17.637 Rlin.Hg 

0.047070 cU.ft!ml 

0.0026688In,Hg·cf/ml-R 

9920 scf/MMBtu 

7.793E-OB [bfdscf I ppmVd 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for CH20 

EPA Method 3A Instrumental Data 

3.94 %-dry 

15.10 %-dry 

80.96 %-dry 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Data from: 

EPA4 

EPA4 

EPA2 

EPA 2 

EPA 2 

EPA 4 

EPA4 

EPA2 

EPA2 
Client Spruance Genco, llC 

Project No. 3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1 * Y· Vm * (Pb + dH/13.6) I Tm 

Vmstd = 80.648 dscf 

2.284 dscm 

Richmond, Virginia 

Two 

2) Volume of waler vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 12.073 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1302 

4) Molecular weight of the stack gas on a wet basis. Ms. 

Ms = [«44*%C02) + (32*%02) + (2B*%N2»" (1-Bws) 1 + (1a*Bws) 

Ms= 28.936 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp" Cp" (dP) * (Ts/Ps*Ms)".5 

Vs = 46.029 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min * Vs .. As 

Qa = 230110.29 cfm 

6516.72 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa" (TstdfTs) * (Ps/Pstd) * (1-Bws) 

Qstd = 161853.63 dscfm 

Osld = 4583.69 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Richmond, Virgmia 

Two 

8) Formaldehyde - Concentrations and Emission Rates 

M[CH20] = sample mass (mg) 

C[CH20] = M[CH20] (mg) I sample volume (dscm) 

C[CH20 @corr. %02] = C[CH20] (ppmV) * (20.9-Corr. %02)1(20.9-Actual %02) 

Corrected 02 Percentage = 7 % 

E[CH20] = C[CH20] (mg/dscm) * 60 (min/hr) * Qstd (dscmm) * (1 Ib 14.536 e+05 mg) 

E[CH20](lb/MMBtu) = C[CH20](ppmV) CF • Fd * (20.9/20.9-%02) 

Page 3 

Com(;!ound Sam(;!le Mass Concentration Concentration ConcentratioD Mass Emission Mass EmissiQo 

!mgl (mg/dscm) (QQrr!lil 'pmV@Corr.%O (Ib/hr) (lb/MMBtu) 

Formaldehyde 0.00484 2.12E-03 1 70E-03 1.39E-03 1.2BE-03 1.62E-06 

NO NO NO NO NO NO 

9) Isokinecity, I. % I = [100*Ts*(K3*Vlc+{«Vm*Y)fTmt(Pb+(dH/13.6»»]1 (60*t*Ps*Vs*An) 

%1= 10314 
3333-Formaldehyde-R3 

Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

Vic = 

Vm = 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

y= 

t= 

On = 

An = 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2 = 

K3 = 

Fd = 

CF = 

[02J 

[C02J 

[N2J 

AirNova, Inc. 

EPA Methods 1,2,3A,4,and RCRA Method 0011 

(Flows, 021C02, H20, and Formaldehyde) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit No.4 

04/19110 

Three 

1658-1911 

Emission Data 

215.6 cc 

76.544 dcf 

-0.50 in. H20 

29.98 in. Hg 

29.94 in. Hg 

29.92 in. Hg 

0.644 in. H20 ".5 

1.02 in. H20 

542.2 R 

650.3 R 

527.7 R 

0.97 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

BarometfJc pressure 

Stack pressure 

EPA Standard pressure 

Average sq.r1 delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

120 min. Duration of sampling time 

0.248 in. Nozzle diameter 

0.000335 sq. ft. Nozzle area 

10.30 ft. Diameter of stack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 PltOt tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]" 5)/[s*R*inH20] Pitot tube constant 

17637 R/in.Hg 

0.047070 cu.ftlml 

0.0026688 in.Hg-cf/ml-R 

9705 scf/MMBtu 

7.793E-08 Ib/dscf I ppmVd 

constant 

constant 

constant 

Fuel Factor 

Conversion Factor for CH20 

EPA Method 3A Instrumental Data 

6.35 %-dry 

12.80 %-dry 

80.85 %-dry 

Oxygen concentration 

Carbon DioxIde concentratIon 

Nitrogen concentration 

Data from: 

EPA4 

EPA4 

EPA2 

EPA2 

EPA 2 

EPA4 

EPA4 

EPA2 

EPA2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1~ Y" Vm" (Pb + dH/13.6) I Tm 

Vmstd = 72.588 dscf 

2.056 dscm 

Richmond, Virginia 

Three 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 10.148 scf 

3) Dec;:imal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1227 

4) Molecular weight of the stack gas on a wet basis. Ms. 

Ms = [«44*%C02) + (32*%02) + (28~%N2» * (l-Bws) 1 + (18*Bws) 

Ms= 28.7931b/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp * (dP) * (Ts/Ps,oMs)".5 

Vs = 40.193 fps 

6) Average actual stack gas volumetric flowrate, Oa. 

Oa = 60 sec/min * Vs ,. As 

Oa = 200933.84 cfm 

5690.45 cmm 

7) Average stack gas dry volumetric f1owrate, Ostd. 

Ostd = Oa * (TstdfTs)· (PsIPstd)" (1-Bws) 

Qstd = 

Qstd = 

143167.33 dscfm 

4054.50 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Calculations (cant.) 

8) Formaldehyde - Concentrations and Emission Rates 

M[CH20] = sample mass (mg) 

Richmond, Virginia 

Three 

qCH20] = M[CH20] (mg) 1 sample volume (dscm) 

qCH20 @ corr, %02] = qCH20] (ppmV) • (20.9-Corr. %02)/(20.9-Actual %02) 

Corrected 02 Percentage = 7 % 

E[CI-I20] = qCH20] (mg/dscm) * 60 (min/hr) * Qstd (dscmm) • (1 Ib 14.536 e+05 mg) 

E[CH20](lbfMMBtu) = qCH20](ppmV) CF • Fd • (20.9/20.9-%02) 

Page 3 

ComQ:OUOQ Sample Mass Concentration Concentration Concentration Mass Emission Mass EmilSSiQ[! 

lm9l (mq/dscm) ilm!n'Ll 'PmV@Corr.%O (Ib/hr) (lb/MMBIU) 

Formaldehyde 0.00614 2.99E-03 2.39E-03 2.29E-03 1.60E-03 2.60E-06 

NO NO NO NO NO NO 

9) Isokinecity, I. % I = [100~Ts·(K3·Vlc+(((Vm*Y)fTmt(Pb+(dH/13.6))))]1 (60~t·Ps*Vs*An) 

% I = 104.95 
M7EMTL 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit 4 Metals 

04/20/10 

Parameter: Oxygen 

Instrument Span (% 02): 22.08 

Actual Calibration Gas Value (% 02): 

Analyzer Calibration Response (% 02L 

Analyzer Calibration Error (% Span): 

Runs 1 

Zero S~tem Calibration Gas 

AOQarent Init. SJ:::s. Init. Sys. Final Sj!,s:. FinfJ.1 Sys. 

Stack Calib. Cal. Bias Cafib. Cal. Bias 

Run Conc. Response (% sQan) Response (% span) 

1 4.22 0.10 0.36 0.09 0.32 

2 0.00 0.09 0.32 0.00 -0.09 

3 0.00 0.00 -0.09 0.00 -0.09 

4 0.00 0.00 -0.09 0.00 -0.09 

5 0.00 0.00 -0.09 0.00 -0.09 

6 0.00 0.00 -009 0.00 -0.09 

7 0.00 0.00 -0.09 0.00 -0.09 

8 0.00 0.00 -0.09 0.00 -0.09 

9 0.00 0.00 -0.09 0.00 -0.09 

10 0.00 0.00 -0.09 0.00 -0.09 

11 0.00 0.00 -0.09 0.00 -0.09 

12 0.00 0.00 -0.09 0.00 -0.09 

AirNova, Inc. Page 1 

EPA Method 7E Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Analyzer Calib. Gases Upscale 

= low mid high Sy,s:. Gal. Ga~ 

0.00 N/A 11.90 22.08 11.90 

0.02 N/A 11.90 11 98 11.90 

0.09 0.00 0.00 -45.74 

U[!scalg S~stem Calibration Gas 

Calib. Init. Sys. Init. SJ:::s. Final Sys. Final SJ:::s. Calib. ~ 

Drift ~ Cal. Bias Calib. Cal. Bias Drift Stack 

(% span) ResQonse (% span) Response t% span) (% span) Conc. 

-005 11.90 0.00 11.98 0.36 0.36 4.14 

-0.41 11.98 0.36 0.00 -53.89 -54.26 -0.09 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 
M7EMTL 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit4 

04/20/10 

Parameter: 

Instrument Span (% C02): 

Carbon Dioxide 

2228 

Actual Calibration Gas Value (% C02): 

Analyzer Calibration Response (% C02): 

Analvzer Calibration Error (% Span): 

Zero SXstem Calibration Gas 

Apparent Init. S):::s. Init. Svs. Final S)!:s. Final S\:,s. 

Stack Galib. Gal. Bias Galib. Cal. Bias 

Run Conc. Response (% span) Response (% span) 

15.49 0.00 0.00 0.00 0.00 

2 0.00 0.00 0.00 0.00 0.00 

3 0.00 0.00 0.00 0.00 0.00 

4 0.00 0.00 0.00 0.00 0.00 

5 0.00 0.00 0.00 0.00 0.00 

6 0.00 0.00 0.00 0.00 0.00 

7 0.00 0.00 0.00 0.00 0.00 

8 0.00 0.00 0.00 0.00 0.00 

9 0.00 0.00 0.00 0.00 0.00 

10 0,00 000 0.00 0.00 000 

11 0.00 0.00 0.00 0.00 0.00 

12 0.00 0.00 0.00 0.00 0.00 

AirNova, Inc. Page 2 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Analyzer Galib. Gases Upscale 

,ero low mid high S):::s. Cal. Gas 

0.00 N/A 12.38 22.38 12.38 

000 N/A 12.33 2222 12.38 

0.00 0.00 -0.22 -0.72 

Ugscale Sxstem Calibration Gas 

Galib Init. S):::s. Init. S\:,s. Final S!!,s. Final S!!,s. Calib. Actual 

Drift Galib. Cal. Bias Calib. Gal. Bias Drift Stack 

(% span) Response (% span) Response t% span) (% span) Conc. 

0.00 12.45 0.31 12.45 0.31 0.00 15.40 

0.00 12.45 0.31 0.00 -55.57 -55.88 0.00 

0.00 0.00 -5557 0.00 -55.57 0.00 ERR 

0.00 000 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 000 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 
M7EMTL2 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit 4 Metals 

04/21/10 

Parameter: Oxygen 

Instrument Span (% 02): 22.08 

Actual Calibration Gas Value (% 02): 

Analyzer Calibration Response (% 02): 

Analyzer Calibration Error(% Span): 

Metals Run 2 

Metals Run 3 

Zero S~tem Calibration Gas 

Apparent Init· ,s)!,S. Init. Sys, Final S\,:s. Final S\,:s. 

IlIiID< Calib. Cal. Bias Calib. Cal. Bias 

Run Conc. Response (% span) Response (% span) 

1 3.91 0.10 0.45 0.00 0.00 

2 3.83 0.00 0.00 0.00 0.00 

3 0.00 0.00 0.00 0.00 0.00 

4 0,00 0.00 0.00 0.00 0.00 

5 0.00 0.00 0.00 0.00 0.00 

6 000 0.00 0.00 0.00 0.00 

7 0.00 0.00 0.00 0.00 0.00 

8 0.00 0.00 0.00 0.00 0.00 

9 0.00 0.00 0.00 0.00 0.00 

10 0.00 000 0,00 0.00 0.00 

11 000 000 0.00 0.00 000 

12 0.00 0.00 0.00 0.00 0.00 

AirNova, Inc. Page 1 

EPA Method 7E Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

AnalYZer Calib. Gases Upscale 

zero """ mid high S\,:s. ~g/. Gas 

0.00 N/A 11 90 22.08 11.90 

0.00 NfA 11.99 21.92 11.90 

0.00 000 0.41 -0.72 

U[!s!;;S!le S~tem Calibration Gas 

Ca/ib. Init. S\,:s. Init. S\,:s. Final S\,:s. Final S\,:s. Calib. M!Jl.a!. 

Drift Calib. Cal. Bias Cafib. Cal. Bias Dnft Stack 

(% span) Response (% span) Response (% span) (% span) Cone. 

-0.45 11.95 0.23 11,98 0.36 0.14 3.86 

0.00 11.98 036 11.87 -0.14 -0.50 3.82 

0.00 11.87 -0.14 0.00 -53.89 -53.76 0.00 

0.00 0.00 -53.89 000 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -5389 000 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 000 -53.89 0.00 ERR 

0.00 0.00 -5389 0.00 -53,89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 
M7EMTL2 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit 4 

04121/10 

Parameter: 

Instrument Span (% C02): 

Carbon Dioxide 

22-28 

Actual Calib@tion Gas Value (% C02): 

Anal\lZer Calibration Response f% C02): 

Analvzer Calibration Error (% Span)' 

Zero Sy:stem Calibration GilS 

A(2parent Imt. S'is. Init ,s\@:. Final S)!s. Final S,,-s. 

StaQk Calib. Cal. Bias Calib. Cal. Bias 

Run Cone. Res(2onse (% span) Res(2onse (% soan) 

15.18 -0.12 -0.54 0.12 0.54 

2 15.12 0.12 0.54 0.00 0.00 

3 0.00 0.00 0.00 0.00 0.00 

4 0.00 0.00 0.00 0.00 0.00 

5 0.00 0.00 0.00 0.00 0.00 

6 0.00 0.00 0.00 0.00 0.00 

7 0.00 0.00 0.00 0.00 0.00 

8 0.00 0.00 0.00 0.00 0.00 

9 0.00 0.00 0.00 0.00 0.00 

10 0.00 0.00 0.00 0.00 0.00 

11 0.00 0.00 0.00 0.00 0.00 

12 0.00 0.00 0.00 0.00 0.00 

AirNova, Inc. Page 2 

EPA Method G.C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal'izer Calib. Gases UQ.§'Qg/@ 

zero Jow mid high S,,-s. Cal. Gas 

0.00 NJA 12.38 22.38 12.38 

0.00 NJA 12.45 22.34 12.38 

0.00 0.00 0.31 -0.18 

Uescale Sllstem Calibration Gas 

Calib. {nit S)!s. Init. S"-S. FmaJ S:vs. FinaJ S,,-s. Calib. Actual 

Drift Calib. Cal. Bias Calib. Cal. Bias Drift Stack 

(%@an ) R@sponse (% span) Response (% span) (% span) Cone. 

1.08 12.57 0.85 12.57 085 0.00 14.95 

-0.54 12.57 0.85 12.57 0.85 0.00 14.90 

0.00 12.57 0.85 0.00 -55.57 -56.42 0.00 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 000 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 
3333-PM2 .5-R 1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

Dn = 

An = 

y= 

tf = 

Os = 

As= 

Cp= 

Kp= 

K1 = 

K2= 

K3= 

C1= 

C2 = 

C3= 

C4= 

C5 = 

C6 = 

81 = 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3,4, aTM 27 and 202 

(Flows, 02/C02, H20, PM2.S and CPM) 

Spruance Genco, LLC 

3333 

Unit No.4 

One 

04120110 

0925-1558 

394.1 cc 

Emission Data 

123.924 dcf 

-0.50 in, H20 

30.04 in. Hg 

30.00 in. Hg 

29.92 in. Hg 

a 7704 in, H20 ".5 

0.340 in. H20 

537.1 R 

650.0 R 

527.7 R 

0,180 in. 

0.000177 sq. ft 

1.02 

373 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor, gamma 

Duration of sampling time 

Diameter of stack 

83.32 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)·(inHg)]'.5]/[s·R'inH20] Pitol tube constant 

17.637 R/in.Hg constant 

0.047070 cU.fUml constant 

0.0026688 in.Hg-cf/ml-R constant 

-150.3162 upoise Viscosity constant 

13.4622 upolse/RAO.5 Viscosity constant 

3861530 upoise/RA 2 Viscosity constant 

0.591123 upOise Viscosity constant 

91.9723 upolse Viscosity constant 

1.51761 E-05 upoise/RA2 Viscosity constant 

0.15625 Constant 

9777 dscf/MMBtu 

Instrumental Data 

4.14 %-dry 

15.40 %-dry 

8046 %-dry 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

Unit No.4 

One 

1) Dry Gas Volume at standard conditions, Vms (EPA aTM 27 Equation 27). 

Vms =K1' Y' Vm 0 (Pb + dH/13.6) I Tm 

Vms = 124.798 dscf 

3.534 dscm 

2) Dry gas sampling rate at standard conditions, QsST (EPA OTM 27 Equation 28). 

QsST = Vms / tr 

asST = 0.335 dscfm 

0.009 dscm I min. 

3) Volume of water vapor condensed at standard conditions, Vws (EPA OTM 27 Equation 29). 

Vws = K2 ""Vic 

Vws= 18.550 sct 

4) Decimal fraction of moisture by volume in stack gas, Bws (EPA OTM 27 Equation 30). 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.129 

5) Molecular weight of the stack gas on a wet basis, Mw (EPA OTM 27 Equations 1 &2). 

Mw = [ ((44'%C02) + (320%02) + (2S0%N2)) , (1-Bws) [ + (1S0Bws) 

Mw = 29.00 Ib/lbmole 

6) Gas sampling rate at actual Cyclone conditions, Os (EPA OTM 27 Equation 31). 

as = (Pstd/Tstd),asST' (1/(1-BwsJr(Ts/Ps) 

as = 0.472 ae1m 

7) Average stack gas velocity, Vs (EPA OTM 27 Equation 11). 

Vs = Kp' Cp 0 (ave of (dP)'O.5)' (Ts/Ps OMw)·0.5 

Vs = 47.82 fps 

8) Average actual stack gas volumetric flowrate, Oa. 

Oa = 60 seclmin "" Vs "" As 

aa = 239069 9 cfm 

67705 cmm 

9) Average stack gas dry standard volumetric flowrate, Ostd. 

astd = aa 0 (Tstd/Ts) 0 (Ps/Pstd) 0 (1-Bws) 

Qstd = 169433.1 dscfm 

4798.3 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit NO.4 

One 

Page 3 

10) Analytical data 

Cvclone and Filter Fractions (EPA Method OTM 27): 

M1) Instack quartz mtcrofibre filter, <2.5um 

0.0215 9 PM <2.5 filter net wt 

M2·4) Cyclone acetone washes 

0.0000 9 actual mass of >2.5, Containers 2&3 

0.0019 9 actual mass of <1=2.5um, Container 4 

0.0000 9 acetone blank net wt 

o mL volume 

100 mL volume 

100 mL volume 

0.0000 9 blank corrected mass of >2_5um, Containers 2&3 = M2&M3 

0.0019 9 blank corrected mass of </=2.5um, Container 4 = M4 

Condensible Particulate Matter (CPM) Fractions (EPA Method 202): 

M5) Back Half Aqueous Wash 

0.0106 9 actual sample mass 

0.0001 9 aqueous blank mass 

300 ml blank vol. 

300 ml Sample volume 

0.0105 9 condensible aqueous PM 

M6) Back Half MeCI2 Extraction Portion 

0.0019 9 extraction net wt 

0.0000 9 MeCI2 blank net wt 

300 ml blank vol. 

300 ml MeCI2 extraction volume 

0.0019 9 condensible organic PM 

M[CPM] = blank corrected mass of Total CPM, M5 & M6 (in grams) 

M[CPM] = 0.0124 9 CPM 

11) Particulate Concentrations, C (EPA OTM27 and EPA 202). 

Equation 43 

Equation 45 

EPA 202 

C[totalsus] = M1 [g)+M2(g)+M3(g)+M4(g),15.43(grainslg)Nmstd(dscD= 

C[PM2.5sus] = M1 (g) + M4(g) , 15.43(grainslg) 1 Vmstd(dscf) = 

C[CPM] = M[CPM](g) '15 43(grainslg) IVmstd(dscD 

where 15.43 = 7000/453592*1000 

C[PMtotal] = C[PMtotalsus] + C[CPM] 

C[PM2.5total] = C[PM2.5sus] + C[CPM] 

0.0029 gr/dscf PMsus 

0.0029 gr/dscf PM2.5sus 

0.0015 grJdscfCPM 

00044 gr/dscfTotal PM 

0.0044 gr/dscf Total PM2.5 
Client 

Project No. 

Spruance Genco, LLC 

3333 

12) Particulate Emission Rates, E 

Test Location 

Test Run 

Calculations (cont.) 

Unit NO.4 

One 

E[lb/hr[ = C[[(gr/dscf) • (1 IbI7000 gr) • Qstd(dscfm) • 60(min/hr) 

E[lb/MMBtu] = C[](gr/dscf)' (1 Ib/7000 gr)' Fd(dscf/MMBtu)' (20.9/20.9-%02) 

E[totalsusj = 4.20 Ib/hr total sus PM 

E[totalsusj = 0.0050 Ib/MM.Btu total sus PM 

E[PM2.5sus] = 4.20 Ib/hr PM2.5sus = 65.4 % of Total PM2,5 

E[PM2.5sus] = 0.0050 Ib/MMBtu PM2 5sus = 

E[CPM] = 2.23 Ib/hr CPM 34.6 % of Tota! PM2.5 

E[CPM] = 0.0027 Ib/MMBtu CPM 

E[PMtotal] = 6.43 Ib/hr total PM 

E[PMtotal] = 0.0077 Ib/MMBtu total PM 

E[PM2.5total] = 6.43 Ib/hr total PM2 5 

E[PM2 5total] = 0.0077 Ib/MMBtu total PM2.5 

13) Percent Isokinectic Sampling, %1 (EPA aTM 27 Equation 40). 

% I = [100*Ts*Vms·Pstd) I (60*Vs*tr*An*Ps*(1-Bws)"Tstd) 

%1= 93.11 

14) Stack Gas ViscOSIty, u (EPA aTM 27 Equation 3). 

u = C1 + C2*(Ts"O.5) + C3*(Ts"-2) + C4*(%02) - (C5"'Bws) + C6*Bws*(TsII.2) 

u = 193.4 micropoise 

Page 4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

15) Test Condition Reynolds number, Nre (EPA OTM 27 Equation 8). 

Nre = 8.64*10115*(Ps*MwlTs)*(Qs/u) 

Nre = 2822 

Unit No, 4 

One 

16) Actual Particle Cut Diameter for Cyclone I, D50 (EPA OTM 27 Equation 32). 

D50 = 81 • ( [Ts 1 ( Mw' Ps)]A.2091) • ( (u lOs)'. 7091) 

050= 10.47 um 

17) Actual Cunningham Correction Factor based on Op = 2.5um, C (EPA OTM 27 Equation 4) 

C = 1+ 0.0057193' (u/(Ps'Dp))' (Ts/Mw)'0.5 

C= 1.0698 

18) Initial 050 for Cyclone IV based on test condition Reynolds number from OTM 27 Equation 8. 

If Nre < 3162, use Equation 33 which results in 050 for IV = 

If Nre >= 3162, use Equation 34 which results in 050 for iV = 

Initial 050 

2.32 

222 

Equation 33 

Equation 34 

Equation 35 

D50 = 0.0024302'(u/Os)'1.1791·(1/C),O.5'(Ts/(Ps'Mw)),0.6790 

D50 = 0.019723'(u/Os),O.8058'(1/C)'0 5'(Ts/(Ps'Mw))'0 3058 

Cr = 1 + 0.0057193'(u/(Ps'D50)),(Ts/Mw),O.5 

19) Re-establlshed 050 for Cyclone IV, 050-1 

Page 5 

Re-established 

Cunningham, Cr 

1.0753 

1.0786 

If Nre < 3162, use Equation 36 which results in 050 for IV = 

If Nre >= 3162, use Equation 37 which results in 050 for iV = 

Recalculated Cut Oiam, 050-1 

231 

2.21 

Equation 36 

Equation 37 

D50-1 = 0.0024302·(u/Os)'1.1791'(1/Cr)'0.5'(Ts/(Ps·Mw)),0.6790 

D50-1 = O. 019723'(u/Os),0. 805S·(1/Cr)'05'(Ts/(Ps'Mw))'0. 3058 

19) Establishing "Z" value, Z. 

If Equation 36 was used, then Z = 050-1 '050 = 

If Equation 37 was used, then Z = 050-11 050 = 

If 0.99 < Z < 1.01, then 050-1 is best cut diameter estimate, 

If 0.99 > Z > 1.01, then repeat cales for Cr using 050-1 

1 00 

1.00 
3333-PM2.5-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb ~ 

Ps = 

Pstd = 

dP ~ 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

tr = 

Os= 

As = 

Cp= 

Kp= 

K1 = 

K2= 

K3= 

C1= 

C2 = 

C3 = 

C4 = 

C5 = 

C6 = 

81 = 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3,4, OTM 27 and 202 

(Flows, 02/C02, H20, PM2.S and CPM) 

Spruance Genco, LLC 

3333 

Unit NO.4 

Two 

04121110 

0711-1317 

398 cc 

Emission Data 

118.523 dcf 

-0.50 in H20 

29.96 in. Hg 

29,92 In. Hg 

29.92 in. Hg 

0.7661 in. H20 ".5 

0340 in. H20 

518.3 R 

647.7 R 

5277 R 

0.180 in 

0.000177 sq. ft. 

1.02 

371.1 min. 

10.300 II. 

Vol of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor, gamma 

Duration of sampling time 

Diameter of stack 

83.32 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coeffic1ent 

85.49 ft[(lb/lbmol)'(inHg)]'.S}/[s·WinH20] Pilot tube conslant 

17.637 R/in.Hg constant 

0.047070 cu,ftlml constant 

o 0026688 in Hg-cffml-R constant 

-150.3162 upoise Viscosity constant 

13.4622 upoisefR"O 5 Viscosity constant 

3861530 upoise/R"2 Viscosity constant 

0.591123 upoise Viscosity constant 

91.9723 upoise Viscosity constant 

1.51761 E-05 upolse/R"2 Viscosity constant 

0.15625 Constant 

9920 dscf/MMBtu 

Instrumental Data 

3.86 %-dry 

1495 %-dry 

81.19 %-dry 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

Unit No.4 

Two 

1) Ory Gas Volume at standard conditions, Vms (EPA OTM 27 Equation 27). 

Vms =K1' Y' Vm' (Pb + dH/13.6) I Tm 

Vms = 123.357 dscf 

3.493 dscm 

2) Dry gas sampling rate at standard conditions, QsST (EPA OTM 27 Equation 28). 

OsST = Vms / tr 

asST= 0.332 dscfm 

0.009 dscm I min. 

3) Volume of water vapor condensed at standard conditions, Vws (EPA OTM 27 Equation 29). 

Vws = K2 *Vle 

Vws= 18.734 scf 

4) Decimal fraction of moisture by volume in stack gas, Bws (EPA OTM 27 Equation 30). 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws= 0.132 

5) Molecular weight of the stack gas on a wet basis. Mw (EPA OTM 27 Equations 1 &2) 

Mw = [((44'%C02) + (32'%02) + (28'%N2)), (1-Bws) I + (18'Bws) 

Mw = 28.89 Ib/lbmole 

6) Gas sampling rate at actual Cyclone conditions, Os (EPA OTM 27 Equation 31). 

as = (Psld/TsldtasST' (1/(1-Bws))'(Ts/Ps) 

as = 0.470 aefm 

7) Average stack gas velocity, Vs (EPA OTM 27 Equation 11). 

Vs = Kp' Cp' (ave of (dPI'O.5)' (Ts/Ps'MwI'O.5 

Vs = 47.62 fps 

8) Average actual stack gas volumetric ffowrate, Qa. 

Oa = 60 sec/min * Vs * As 

Oa = 238054.1 efm 

6741.7 cmm 

9) Average stack gas dry standard volumetric flowrate, Qstd 

asld = aa' (TsldlTs)' (Ps/Pstd)' (1-Bws) 

astd = 168396.8 dscfm 

4769.0 dsemm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

Unit No.4 

Two 

Page 3 

10) Analytical data 

Cvclone and Filter Fractions (EPA Method OTM 27): 

M1) Instack quartz microfibre filter, <2.Sum 

0.0143 9 PM <2.S filter net \lilt 

M2-4) Cyclone acetone washes 

0.0000 9 actual mass of >2.5, Containers 2&3 

0.0035 9 actual mass of </=2.5um, Container 4 

0.0000 9 acetone blank net wt 

a mL volume 

100 mL volume 

100 mL volume 

0.0000 g blank corrected mass of >2.5um, Containers 2&3 = M2&M3 

0.0035 9 blank corrected mass of </=2.Sum, Container 4 = M4 

Condensible Particulate Matter (CPMJ Fractions (EPA Method 202): 

M5) Back Half Aqueous Wash 

0.0090 9 actual sample mass 

0.0001 9 aqueous blank mass 

300 ml blank vol. 

300 ml Sample volume 

0.0089 9 condensible aqueous PM 

M6) Back Half MeCI2 Extraction Portion 

0.0009 9 extraction net wt 

0.0000 g MeCI2 blank net wt 

300 ml blank vol. 

300 ml MeCI2 extraction volume 

o 0009 9 condensible organic PM 

M[CPM] = blank corrected mass of Total CPM, MS & M6 (in grams) 

MICPM] = 0.0098 9 CPM 

11) Particulate Concentrations, C (EPA OTM27 and EPA 202). 

Equation 43 

Equation 45 

EPA 202 

Cltotalsus] = M 1 (g)+M2(g)+M3(g)+M4(g)"5.43(gralns/g)Nmstd(dscD= 

C[PM2.5sus] = M1(g) + M4(g) , 15.43(gralns/g) 1 Vmstd(dscD = 

C[CPM] = MICPM](g)' 15.43(gralns/g) IVmstd(dscf) 

where 15.43 = 7000/453592'1000 

C[PMtotal] = C[PMtotalsus] + C[CPM] 

C[PM2.5total] = C[PM2.5sus] + C[CPM] 

0.0022 gr/dscf PMsus 

0.0022 gr/dscf PM2.5sus 

0.0012 gr/dscf CPM 

0.0035 gr/dscf Total PM 

o 0035 gr/dscfTotal PM2 5 
Client 

Project No. 

Spruance Genco, LLC 

3333 

12) Particulate Emission Rates, E. 

Test Location 

Test Run 

Calculations (cont.) 

Unit No 4 

Two 

E[lblhr] = C[](grldscD' (1 Ibl7000 gr)' Qstd(dscfm)' 60(minlhr) 

E[lbIMMBtu] = C[](grldscD' (1 Ibl7000 gr)' Fd(dscfIMMBtu)' (20.9120.9-%02) 

E[totalsus] = 3.21 Ib/hr total sus PM 

E[totalsus] = 0.0039 Ib/MMBtu total sus PM 

E[PM2 5sus) = 3.21 Ib/hr PM2.5sus = 64.5 % of Total PM2.5 

E[PM2.5sus] = 0.0039 Ib/MMBtu PM2.5sus = 

E[CPM] = 1.77 Iblhr CPM 35.5 % of Total PM2.5 

E[CPM] = 0.0021 IblMMBtu CPM 

E[PMtotal] = 4.98 Ib/hr total PM 

E[PMtotal] = 0.0060 Ib/MMBtu total PM 

E[PM2.5total] = 4.98 Ib/hr total PM2.5 

E[PM2.5total] = 0.0060 IblMMBtu total PM2.5 

13) Percent Isokinectic Sampling, %1 (EPA OTM 27 Equation 40). 

% I = [100*Ts·Vms*Pstd) I (60*Vs*tr*An~Ps*(1 -Bws)*Tstd) 

% I = 93.07 

14) Stack Gas Viscosity, u (EPA OTM 27 Equation 3). 

u = C1 + C2*(Ts"O.5) + C3"'(Ts"-2) + C4*(%02) - (C5*Bws) + C6*Bws*(Ts"2) 

u = 1925 mlcropoise 

Page 4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cont.) 

15) Test Condition Reynolds number, Nre (EPA OTM 27 Equation 8). 

Nre = B.64*10I\S*(Ps*MwlTs)*(Qs/u) 

Nre = 2815 

Unit No 4 

Two 

16) Actual Particle Cut Diameter for Cyclone I, D50 (EPA OTM 27 Equation 32). 

D50 = 81 • ( [ Ts I ( Mw' Ps)[A2091) • ( (u lOs)'. 7091) 

050 = 10.47 um 

17) Actual Cunningham Correction Factor based on Dp = 2.5um, C (EPA OTM 27 Equation 4). 

C = 1+ 0.0057193' (u/(Ps'Dp))' (Ts/MwyO.5 

C= 1.0697 

18) Initial D50 for Cyclone IV based on test condition Reynolds number from OTM 27 Equation 8. 

If Nre < 3162, use Equation 33 which results in 050 for IV = 

If Nre >= 3162, use Equation 34 which results in 050 for iV = 

Initial 050 

232 

2.22 

Equation 33 

Equation 34 

Equation 35 

D50 = 0.0024302·(u/Os)A1.1791·(1/C)AO 5·(Ts/(Ps·Mw)),0.6790 

D50 = 0 019723·(u/Os)AO.8058·(1/CYO.5·(Ts/(Ps·Mw))AO.3058 

Cr = 1 + 0.0057193·(u/(Ps·D50))"(Ts/MwYO.5 

19) Re-established D50 for Cyclone IV, D50-1. 

Page 5 

Re-established 

Cunningham, Cr 

1.0750 

10783 

If Nre < 3162, use Equation 36 which results in 050 for IV = 

If Nre >= 3162, use Equation 37 whLch results In 050 for iV = 

Recalculated Cut Oiam, 050-1 

2.32 

221 

Equation 36 

Equation 37 

D50-1 = 0.0024302·(u/Os)A11791·(1/Cr)AO 5'(Ts/(Ps'Mw)yO 6790 

D50-1 = 0 019723·(u/OsYO.8058·(1/CryO.5·(Ts/(Ps·Mw)),0.3058 

19) Establishing "Z" value, Z. 

If Equation 36 was used, then 

If Equation 37 was used, then 

Z= D50-1/D50= 

Z = D50-1/D50= 

If 0.99 < Z < 1.01, then 050-1 is best cut diameter estimate. 

If 0.99 > Z > 1.01, then repeat cales for Cr using OSO-1 

1.00 

1.00 
3333-PM2.5-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

On = 

An = 

y= 

tr = 

Ds= 

As= 

Cp= 

Kp = 

K1 = 

K2= 

K3 = 

C1 = 

C2 = 

C3 = 

C4= 

C5= 

C6 = 

B1 = 

Fd = 

[02[ 

[C02[ 

[N2] 

AirNova, Inc. 

EPA Methods 1,2,3,4, OTM 27 and 202 

(Flows, 02/C02, H20, PM2.5 and CPM) 

Spruance Genco, LLC 

3333 

Unit No, 4 

Three 

04/21/10 

1412-2037 

396 cc 

Emission Data 

118.058 dcf 

-0.50 in. H20 

2996 In Hg 

29.92 in. Hg 

29.92 in. Hg 

0.7667 in. H20 ".5 

0340 in. H20 

521.7 R 

648.0 R 

5277 R 

0.180 m. 

0.000177 sq. ft. 

1.02 

371.6 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor, gamma 

Duration of sampling time 

Diameter of stack 

83.32 sq, ft Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)'(inHg)]'.5}/[s·R'inH20] Pitot tube constant 

17.637 R/in.Hg constant 

0.047070 cu.ftlml constant 

0.0026688 in.Hg-cf/ml-R 

-150,3162 upoise 

13.4622 upoise/R"0.5 

3861530 upoise/R"2 

0.591123 upoise 

91.9723 upoise 

1.51761E-05 upoise/R"2 

0.15625 

9705 dscf/MMBtu 

Instrumental Data 

3.82 %-dry 

14.90 %-dry 

81.28 %-dry 

constant 

Viscosity constant 

Viscosity constant 

Viscosity constant 

Viscosity constant 

Viscosity constant 

Viscosity constant 

Constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

Unit No.4 

Three 

1) Dry Gas Volume at standard conditions, Vms (EPA OTM 27 Equation 27). 

Vms =K1' Y' Vm' (Pb + dH1136) / Tm 

Vms = 122.078 dsef 

3457 dscm 

2) Dry gas sampling rate at standard conditions, QsST (EPA OTM 27 Equation 28). 

QsST = Vms I tr 

QsST= 0.329 dscfm 

0.009 dsem I min. 

3) Volume of water vapor condensed at standard conditions, Vws (EPA OTM 27 Equation 29). 

Vws = K2'" Vic 

Vws= 18.640 sef 

4) Decimal fraction of moisture by volume in stac/( gas, Bws (EPA OTM 27 Equation 30). 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.132 

5) Molecular weight of the stack gas on a wet basis, Mw (EPA OTM 27 Equations 1 &2). 

Mw = [((44'%C02) + (32'%02) + (2S'%N2))' (1-Bws) I + (1S'Bws) 

Mw = 28.88 Ib/lbmole 

6) Gas sampling rate at actual Cyclone conditions, Os (EPA OTM 27 Equation 31). 

Qs = (PstdlTstd)'QsST' (1/(1-Bws)t(Ts/Ps) 

Os = 0.465 aefm 

7) Average stack gas velocity, Vs (EPA OTM 27 Equation 11). 

Vs = Kp' Cp' (ave of (dP)AO.5)· (Ts/Ps'Mw)AO.5 

Vs = 47.67 fps 

8) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs " As 

Qa = 238337.8 cfm 

6749.7 cmm 

9) Average stack gas dry standard volumetric f/owrate, Qstd. 

Qstd = Qa' (TstdlTs)' (Ps/Pstd)' (1-Bws) 

Qstd = 168412.6 dscfm 

4769.4 dsemm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cant.) 

Unit No, 4 

Three 

Page 3 

10) Analytical data 

Cyclone and Filter Fractions (EPA Method OTM 27>: 

M1) Instack quartz microfibre filter, <2.5um 

0.0187 9 PM <2.5 filter net wt 

M2-4) Cyclone acetone washes 

0.0000 9 actual mass of >2.5, Containers 2&3 

0.0026 9 actual mass of <1=2.5um, Container 4 

0.0000 9 acetone blank net wt 

a mL volume 

100 mL volume 

100 mL volume 

0,0000 9 blank corrected mass of >2.5um, Containers 2&3 = M2&M3 

0.0026 9 blank corrected mass of <1=2.5um, Container 4 = M4 

Condensible Particulate Matter (CPM) Fractions (EPA Method 202): 

M5) Back Half Aqueous Wash 

0.0058 9 actual sample mass 

0.0001 g aqueous blank mass 

300 ml blank vol. 

300 ml Sample volume 

0,0057 9 condensible aqueous PM 

M6) Back Half MeCI2 Extraction Portion 

0.0003 9 extraction net wt 

0.0000 9 MeCI2 blank net wt 

300 ml blank vol. 

300 ml MeCI2 extraction volume 

0.0003 9 condensible organic PM 

M[CPM] = blank corrected mass of Total CPM, M5 & M6 (in grams) 

M[CPM] = 0.0060 9 CPM 

11) Particulate Concentrations, C (EPA OTM27 and EPA 202). 

Equation 43 

Equation 45 

EPA 202 

C[totalsus] = M 1 (g)+M2(g)+M3(g)+M4(g)'15A3(grains/g)Nmstd(dscf)= 

C[PM2.5sus] = M1 (g) + M4(g) • 15.43(grains/g) 1 Vmstd(dscf) = 

C[CPM] = M[CPM](g)' 15.43(grains/g) 1 Vmstd(dscn 

where 15.43 = 7000/453592'*1000 

C[PMtotal] = C[PMtotalsus] + C[CPM] 

C[PM2.5total] = C[PM2.5sus] + C[CPM] 

0.0027 gr/dscf PMsus 

0.0027 gr/dscf PM2.5sus 

0.0008 gr/dscf CPM 

0.0035 gr/dscfTolal PM 

0.0035 gr/dscfTotal PM2.5 
Client 

Project No. 

Spruance Genco, LLC 

3333 

12) Particulate Emission Rates, E. 

Test Location 

Test Run 

Calculations (cont.) 

Unit NO.4 

Three 

E[lb/hr[ = c[lIgr/dscf) • (1 Ib/7000 gr) • Qstd(dscfm) • 60(min/hr) 

E[lb/MMBtu] = C[](gr/dscD' (1 Ib/7000 gr)' Fd(dscf/MMBtu)' (20.9/20.9-%02) 

E[totalsus] = 3.89 Ib/hr total sus PM 

E[totalsus] = 0.0046 Ib/MMBtu total sus PM 

E[PM2.5sus] = 3.89 Ib/hr PM2.5sus = 78 0 % of Total PM2.5 

E[PM2.5sus] = 0.0046 Ib/MMBtu PM2.5sus = 

E[CPM] = 1.09 Ib/hr CPM 22 0 % of Total PM2.5 

E[CPM] = 0.0013 Ib/MMBtu CPM 

E[PMtotal] = 4.98 Ib/hr total PM 

E[PMtotal] = 0.0059 Ib/MMBtu total PM 

E[PM2.5total] = 4.98 Ib/hr total PM2.5 

E[PM2.5total] = 0.0059 Ib/MMBtu total PM2.5 

13) Percent Isokinectlc Sampling, %1 (EPA OTM 27 Equation 40). 

% 1.= [1 OO*Ts~Vms*Pstd) I (60"'Vs"tr"An"'Ps"{1-Bws)*Tstd) 

% I = 91.98 

14) Stack Gas Viscosity, U (EPA OTM 27 Equation 3). 

II = C1 + C2"(Ts"O.5) + C3*(Ts"-2) + C4*(%02) - (C5"'Bws) + C6*Bws*(Ts"2) 

u = 192.5 micropoise 

Page4 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations (cant.) 

15) Test Condition Reynolds number, Nre (EPA OTM 27 Equation 8). 

Nre = 8.64*1 01\5*(Ps*MwlTs)*(Qs/u) 

Nre = 2783 

Unit No.4 

Three 

16) Actual Particle Cut Diameter for Cyclone /, D50 (EPA OTM 27 Equation 32). 

050 = B1 '( [Ts I (Mw' Ps)['.2091)' ((u I Qs)'.7091) 

050 = 10.55 um 

17) Actual Cunningham Correction Factor based on Dp = 2.5um, C (EPA OTM 27 Equation 4). 

C = 1+ 0 0057193' (ul(Ps'Op))' (TsIMw)'0.5 

C = 10697 

1B) Initial 050 for Cyclone IV based on test condition Reynolds number from OTM 27 Equation B. 

If Nre < 3162, use Equation 33 which results in 050 for IV = 

If Nre >= 3162, use Equation 34 which results in 050 for iV = 

Initial 050 

2.35 

2.24 

Equation 33 

Equation 34 

Equation 35 

050 = 0.0024302'(uIQs)'1.1791'(1IC)'0.5'(TsI(Ps'Mw)),0.6790 

050 = 0.019723'(uIOs),0.8058'( 11C)'0.5'(TsI(Ps'Mw)),0.3058 

Cr = 1 + 0.0057193'(ul(Ps'050)nTsIMw),0.5 

19) Re-established 050 for Cyclone IV, 050-1 

Page 5 

Re-established 

Cunningham, Cr 

1.0740 

10777 

If Nre < 3162, use Equation 36 which results in 050 for IV = 

If Nre >= 3162, use Equation 37 which results in 050 for iV = 

Recalculated Cut Oiam, 050-1 

2.35 

2.24 

Equation 36 

Equation 37 

050-1 = 0.0024302'(uIQs)'1.1791'(1/Cr)'0 5'(TsI(Ps'Mw)),0.6790 

050-1 = 0.019723'(uIQs),0.8058'( 1ICr)'0.5'(TsI(Ps'Mw)),0.3058 

19) Establishing liZ" value, Z. 

If Equation 36 was used, then Z = 050-11 050 = 

If Equation 37 was used, then Z = 050-1 I 050 = 

If 0.99 < Z < 1.01, then 050-1 is best cut diameter estimate 

If 0.99> Z > 1.01, then repeat calcs for Cr using 050-1 

1.00 

1.00 
3333-TSP-Metals-R 1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd ::: 

dP = 

dH = 

Tm = 

Ts = 

Tsld= 

Dn = 

An = 

y= 

t= 

Ds = 

As = 

Cp = 

Kp= 

K1 = 

K2 = 

K3 = 

Fd = 

[02) 

[C02) 

[N2) 

AirNova, Inc. 

EPA Methods 1,2,3A,4,5 and 29 

(Flows, 02/C02, H20, TSP and Metals) 

Spruance Genco, LLC 

3333 

Unit No.4 

One 

04/20/10 

0925-1545 

760.0 cc 

252.753 dcf 

Emission Data 

-0.50 in, H20 

30.04 in. Hg 

30.00 in. Hg 

29.92 in. Hg 

0,7539 in. H20 A.5 

1.322 in. H20 

544,7 R 

651.2 R 

527.7 R 

0.240 in. 

0.000314 sq, ft, 

0.97 

360 min. 

10.30 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq,rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbJlbmolt(inHg)1~.5}J[s·R*inH201 Pitot tube constant 

17.637 RJin.Hg 

0.047070 cU.ftlml 

0.0026688 in.Hg-cfJml-R 

9777 scf/MMBtu 

Instrumental Data 

4.14 %-dry 

15.40 %-dry 

80.46 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1~ y. Vm ~ (Pb + dH/13.6) I Tm 

Vmstd = 239.243 dscf 

6.775 dsem 

Unit No, 4 

One 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 35.773 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.1301 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44~%C02) + (32*%02) + (2S*%N2» * (1-Bws) 1 + (18*Bws) 

Ms= 28.987 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp· (dP) * (TslPs~Ms)",5 

Vs= 46,850 fps 

G) Average actual stack gas volumetric flowrate, Oa. 

Qa = 60 sec/min· Vs * As 

Qa = 234213.54 cfm 

6632.93 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa ~ (TstdlTs) * (Ps/Pstd) * (1-Bws) 

Qstd = 165566,46 dscfm 

4688,84 dsemm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Unit No.4 

One 

Calculations (cont.) 

8) Particulate MaHer Analytical Data 

INPUT A 0.1666 9 

INPUT B 100 ml 

INPUT C 0.0830 9 

INPUT 0 100 ml 

INPUT E 0.0000 g 

9) Particulate sample mass calculations 

H 

J 

Front Half: 

Acetone blank adj. residue v 

Adj. Acetone wash part,wt. 

Front half sample wt. 

10) Front Half Particulate Matter Emission Data 

Filter sample net wt 

Front acetone wash vol. 

Front acetone residue wt. 

Acetone blank vol. 

Acetone blank residue wt. 

0.0000 9 

0.0830 9 

0.2496 9 

E"(BIO) 

C-H 

A+' 

C[PM] = (Front Half Wt)(g)" (1Nmstd) ,. 1S.43(grainsfg) 

E[PM] = C[PM] * Vdscfm" A ., (60 min/hr)" (1 Ib f 7000 grains) 

Page 3 

E[PM]lbfMMBtu = E[PM]lbfhr*(Fuel HV) scffBtu*(fuel use) 1 hour/kscf*kscff1000scf"10"6Btu/MMBtu 

C[PM] = 1.61E-02 grainS/dscf 

C[PM] = 2.30E-06 Ibfdsef 

E[PM] = 22.84S Ibfhr 

E[PM] = 2.80E-02 IbfMMBtu 

11 )Trace metal concentrations and emission rates 

Element 

Antimony 

Arsenic 

Beryllium 

Cadmium 

Chromium 

Cobalt 

Lead 

Manganese 

Nickel 

Selenium 

C[M] = M[M] (ug) / Vmstd (dsem) 

C[M](lb/dsef) = C[M](ug/dsem) • 1e-06g/ug * 2.205e-03Ib/g" 0,02832 dsem/dsef 

E[M](lb/hr) = C[M] (ug/dsem) * (2.20SE-09) (Ib/ug) * Qstd (dsemm) * 60 (min/hr) 

E[M](lb/MMBtu) = C[M](lb/dsef) • Fd * (20.9120.9-%02) 

C[M](@ corr. 02) = C[MJ (ug/dscm) * [ (20.9-corrected %02) / (20.9-actual %02) 1 

Corrected 02 percentage is: 7.0 % 

Sample Cone. QQn!;;.@!<QIT. 02 Cone. Emission Rate 

Mass (ug) (ug/dscm) (ug/dsem) (lb/dscQ Ob/hr) 

1.422 2.10E-01 1.74E-01 1.31E-11 1,30E-04 

9.253 1.37E+OO 1.13E+OO 8.S3E-11 R47E-04 

1.64 2.42E-01 2.01E·01 1.S1E-11 1.S0E-04 

0.705 1.04E·01 8,63E·Q2 6.S0E-12 6.4SE-05 

11.265 1,66E+OO 1,38E+OO 1.04E-10 1.03E-03 

5,67 8.37E-01 6.94E·01 5.23E-11 5.19E-04 

10.951 1.62E+00 1.34E+00 t01E-10 1.00E-03 

10,555 1.S6E+00 1.29E+00 9,73E·11 9.66E-04 

16.134 2.38E+OO 1.97E+OO 1,49E-10 1.48E-03 

3.99 S.89E-01 4.88E-01 3,68E-11 3.65E-04 

12) Isokinecity, I. 

% I = [100~Ts*(K3*Vlc+«(Vm"Y)fTm)*(Pb+(dH/13.6»»11 (60*t*Ps*Vs*An) 

%1= 106,46 

" < " symbol indicates values given are the quantitative detection limit. 

Emission Rate 

(lbfMMBtu) 

1.S9SE-07 

1.040E-06 

1.843E-07 

7.922E-08 

1.266E-06 

6.371E-07 

1.231E-06 

1,186E-06 

1.813E-06 

4.484E-07 
3333-TSP-Metats-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic '" 

Pb = 

Ps = 

Pstd '" 

dP= 

dH = 

Tm= 

Ts = 

Tsld= 

On = 

An = 

y= 

t= 

Os = 

As = 

Cp = 

Kp = 

K1 = 

K2= 

K3= 

Fd = 

[02[ 

[C02[ 

[N21 

AirNova, Inc. 

EPA Methods 1,2,3A,4,5 and 29 

(Flows. 02lC02, H20. TSP and Metals) 

Spruance Genco, LLC 

3333 

Unit No, 4 

Two 

04/21/10 

0711-1317 

Emission Data 

769,2 cc 

241.455 dcf 

-0.50 in, H20 

29.96 in. Hg 

29,92 in, Hg 

29.92 in, Hg 

0_7634 in. H20 A,S 

1.239 in. H20 

524.2 R 

647.4 R 

527.7 R 

0.240 in. 

0.000314 sq, ft, 

0.97 

360 min, 

10.30 ft. 

83.3204 sq. ft. 

0.84 

Vol, of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

Cross sectional area of stack 

Pitot lube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]A.5}1[s*R*inH20] Pitot tube constant 

17.637 R/in.Hg 

0.047070 cU.fVml 

0,0026688 in,Hg·cf/ml-R 

9920 scf/MMBtu 

instrumental Data 

3.86 %-dry 

14.95 %-dry 

81.19 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nlirogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y" Vm * (Pb + dH/13.6) I Tm 

Vmstd = 236.808 dscf 

6.706 dscm 

Unit No.4 

Two 

2) Volume of water vapor collected at standard conditions, Vw(std). 

VW(std) = K2 "Vic 

Vw(std) = 36.206 sd 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws= 0.1326 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32*%02) + (28·%N2»· (1-Bws) 1 + (18*Bws) 

Ms= 28.883 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp· Cp" (dP) • (Ts/Ps*Ms)".5 

Vs = 47.449 fps 

6) Average actual stack gas volumetric flow rate, Qa. 

Qa = 60 sec/min" Vs ;0 As 

Qa = 237207.79 cfm 

6717.72 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa" (TstdlTs) ., (PslPstd)" (1-Bws) 

Qstd = 167735.15 dscfm 

4750.26 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Unit No.4 

Two 

Calculations (cont.) 

8) Particulate Matter Analytical Data 

INPUT A 0.1208 9 

INPUT 8 100 ml 

INPUT C 0.0776 9 

INPUT D 100 ml 

INPUT E 0.0000 9 

9) Particulate sample mass calculations 

H 

J 

Front Half: 

.Acetone blank adj. residue v 

Adj. Acetone wash partwt. 

FrOnt half sample wt. 

10) Front Half Particulate Matter Emission Data 

Filter sample net wt 

Front acetone wash vol. 

Front acetone residue wt. 

Acetone blank vol. 

Acetone blank residue wt. 

0.0000 9 

0.0776 9 

0.1984 9 

E"(8/D) 

C-H 

A+ I 

C[PM] = (Front HalfWt){g)" (1Nmstd) " 15.43(grains/g) 

E[PM}:o C[PM]· Vdscfm • A "(SO minlhr) ~ (1 Ib /7000 grains) 

Page 3 

E[PM} Ib/MMBtu = E[PM)lb/hr*(Fuel HV) scflBtu"*(fuel use) 1 hour/kscrkscf/1000scf"10"6Btu/MMBtu 

C[PM] = 1.29E-02 grains/dscf 

C[PM] = 1.85E-06 Ib/dscf 

E[PM] = 18.586 Ib/hr 

E(PM] = 2.25E-02 Ib/MMBtu 

11)Trace metal concentrations and emission rates 

Element 

Antimony 

Arsenic 

Beryllium 

Cadmium 

Chromium 

Cobalt 

Lead 

Manganese 

Nickel 

Selenium 

C[M) = M[M) (ug) I Vmstd (dscm) 

C[M](lb/dscf) = C[M)(ug/dscm)" 1e·OSg/ug· 2.205e-03Ib/g" 0.02832 dscm/dscf 

E[M](Ib/hr) = C[M) (ug/dscm) .. (2.205E-09) (Ib/ug) • Qstd (dscmm)· 60 (min/hr) 

E[M](lb/MMBtu) c: C[M)(lb/dscf)" Fd .. (20.9/20.9-%02) 

C[M](@ carr. 02) = C[M] (ug/dscm) "[ (20.9-corrected %02) I (20.9-actual %02) I 

Corrected 02 percentage is: 7.0 % 

Sample Cone. Conc.@corr. Q2 Cone. Emission Rate 

Mass (ug) (ug/dscm) (ug/dscm) (lb/dscQ (Ib/hr) 

1.593 2.38E-01 1.94E-01 1.48E-11 1.49E-04 

7.809 i.16E+OO 9.50E-01 7.27E-11 7.32E-04 

1.29 1.92E-01 1.57E-01 1.20E-11 1.21E-04 

0.51S 7.69E-02 6.28E-02 4.80E-12 4.84E-05 

10.731 1.S0E+OO 1.31E+00 9.99E-11 1.01E-03 

5.1 7.60E-01 6.20E-01 4.75E-11 4.78E-04 

9.763 1.46E+OO 1.19E+00 9.09E-11 9.15E·04 

9.787 1.46E+OO 1.19E+00 9.11E-11 9. 17E-04 

12.847 1 92E+OO 1.56E+00 1.20E-10 1.20E-03 

3.1 4.62E-01 3.77E-01 2.89E-11 2.91E-04 

12) Isokinecity, I. 

% I = [100*TS*(K3"*Vlc+«(Vm·Y)!Tm)*(Pb+(dH/13.S»)))] I (60·t*Ps*Vs"An) 

%1= 104.01 

n < n symbol indicates values given are the quantitative detection limit. 

Emission Rate 

(lb/MMBtu) 

i.805E-07 

8.847E-07 

1.461E-07 

5.846E-08 

1.2i6E-OS 

5.778E-07 

1. 1 OSE-OS 

1.109E-06 

1.455E-06 

3.512E-07 
3333-TSP-Metals-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

Dn = 

An = 

y= 

t= 

Ds= 

As= 

Cp = 

Kp = 

K1 = 

K2 = 

K3= 

Fd = 

[02[ 

[C02[ 

[N2[ 

AirNova, Inc. 

EPA Methods 1,2,3A,4,5 and 29 

(Flows, 02lC02, H20, TSP and Metals) 

Spruance Genco, LLC 

3333 

Unit No.4 

Three 

04/21/10 

1412-2037 

Emission Data 

751.2 cc 

235.369 dcf 

-0.50 in. H20 

29.96 in. Hg 

29.92 in. Hg 

29.92 in. Hg 

0.7635 in. H20 ".5 

1.213 in. H20 

523.5 R 

648.7 R 

527.7 R 

0.240 in. 

0.000314 sq. ft. 

0.97 

360 min. 

10.30 ft. 

83.3204 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lbJlbmol)~{inHg)]".5}J[s·R·inH201 Pitot tube constant 

17.637 R/in.Hg 

0.047070 cu.fUml 

0.0026688 in.Hg-cf/ml-R 

9705 scf/MMBtu 

Instrumental Data 

3.82 %-dry 

14.90 %-dry 

81.28 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* y;o Vm· (Pb + dH/13,6) I Tm 

Vmstd = 231,156 dscf 

6,546 dsem 

Unit No.4 

Three 

2) Volume of water vapor collected at standard conditions, Vw(atd). 

Vw{std) = K2 ;0 Vic 

Vw(std) = 35.359 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd f (Vmsld+Vwstd) 

Bws= 0.1327 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms '" [«44~%C02) + (32*%02) + (28*%N2)) * (1-Bws) 1 + (18"'Bws) 

Ms= 28.874 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp ~ Cp" (dP) ~ (Ts/Ps*Ms)".5 

Vs= 47.510 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min· Vs ~ As 

Qa = 237511,54 cfm 

6726.33 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa * (TstdlTs)· (PslPstd) ;0 (1-Bws) 

Qstd = 167594.05 dscfm 

4746.26 dscmm 

Page 2 
Client Spruance Genco, LLC 

Project No. 3333 

Test Location 

Test Run 

Unit No.4 

Three 

Calculations (cont.) 

8) Particulate Matter Analytical Data 

INPUT A 0.1824 9 

INPUT B 100 ml 

INPUT C 0,0909 9 

INPUT D 100 ml 

INPUT E 0.0000 9 

9) Particulate sample mass calculations 

H 

J 

Front Half: 

Acetone blank adj. residue v 

Adj_ Acetone wash part.wt, 

Front half sample wt. 

10) Front Half Particulate Matter Emission Data 

Filter sample net wt 

Front acetone wash vol. 

Front acetone residue wt. 

Acetone blank vol. 

Acetone blank residue wt. 

0,0000 9 

0,0909 9 

0.2733 9 

E"( BID) 

C-H 

A+ I 

C[PM] = (Front Half Wt)(g) • (1Nmstd)" 15.43(grains/g) 

E[PM] = C[PM] " Vdscfm .. A .. (60 min/hr) "(1 Ib 17000 grains) 

Page 3 

E[PM) Ib/MMBtu = E[PM] Ib/hr·(Fuel HV) scf/Btu~(fuel use) 1 hour/kscrkscf/1000scr10"6Btu/MMBtu 

C[PM] = 1.82E-02 grains/dscf 

C[PM] = 2.61E-06Ibfdscf 

E[PM] = 26.207 Ib/hr 

E[PM] = 3.09E-02 Ib/MMBtu 

11)Trace metal concentrations and emission rates 

Element 

Antimony 

Arsenic 

Beryllium 

Cadmium 

Chromium 

Cobalt 

leaa 

Manganese 

Nickel 

Selenium 

C[M] = M[M] (ug) 1 Vmstd (dscm) 

C[M](lb/dscf) = C[M](ug/dscm) w 1e-06g/ug" 2.205e-03Ib/g· 0.02832 dscm/dscf 

E[MJ(lb/hr) ., C[MJ (ug/dscm) .. (2.20SE-09) (Ib/ug) .. Qstd (dscmm) "60 (minfhr) 

E[M)(lb/MMBtu) " C[M](lb/dscf) W Fd W (20.9120.9-%02) 

C[M)(@ corr. 02) = C[M] (ug/dscm)" [ (20.9-corrected %02) I (20.9-actual %02)] 

Corrected 02 percentage is: 7.0 % 

Sample Conc. QQn~@Qilrr_ Q2 Conc. Emission Rate 

Mass lug) (ug/dscm) (ug/dscm) (Ib/dscf) (lb/hrl 

4.1 6.26E·01 S 10E·01 3.91E-11 3.93E-04 

8.949 1,37E+00 1.11E+00 8 S4E·11 8.S8E-04 

1.801 2_7SE-01 2.24E-01 1.72E·11 1.73E-04 

0.688 1,OSE-01 8,S5E-02 6,S6E-12 6.6DE-OS 

10.563 1,61 E+OO 1.31E+OO 1,01E-10 1.01E-03 

6.24 9.S3E-01 7.76E-01 5.9SE·11 S.99E-04 

11.S3 1.76E+00 1.43E+00 1.10E-10 1.11E-03 

11.25 1.72E+OO 1.40E+OO 1.07E-10 i.0BE-03 

16.22 2.48E+OO 2.02E+OO 1,SSE-10 i.S6E-03 

4.29 6,SSE-01 5,33E-01 4,09E-11 4.12E-04 

12) Isokinecity, I. 

% I = [100*TS*(K3'Vlc+«(Vm"Y)fTm)*(Pb+(dH/13,6»)))] I (60*t*Ps"VsWAn) 

%1= 101.61 

" <" symbol indicates values given are the quantitative detection limit. 

Emission Rate 

{lb/MMBtu) 

4,64SE-07 

1,014E-06 

2,040E-07 

7794E-08 

1.197E-06 

7.069E-07 

1.306E-06 

1.274E-06 

1.837E-06 

4.860E-07 
3333-Hg-unspiked-R 1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

Tm= 

INPUT Ts = 

INPUT Tstd= 

INPUT y= 

INPUT t = 

INPUT Os = 

AirNova, Inc. 

EPA Method 1, 2, 3A, and 30B - Unspiked Tube 

(Flows, 02/C02, and Mercury) 

Spruance Genco, LLC 

3333 

Umt No.4 

One 

04/20/10 

0925-1525 

Emission Data 

5.490 dcf 

-0.50 in. H2O 

30.04 in. H9 

30.00 m. H9 

29.92 m. H9 

541.3 R 

651.2 R 

527.7 R 

1.000 

360 min. 

10.30 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

DuratIon of sampling time 

Diameter of Stack 

As = 8332043375 sq. ft. Cross sectional area of stack 

INPUT 

INPUT 

INPUT 

Kp = 85.49 ft[(lb/lbmol)~(inHg)1".5}1[s*R*lnH201 

K1 = 

K2 = 

K3 = 

Fd = 

[02[ 

[C02[ 

[N2[ 

17.637 R/in.Hg 

0.047070 cU.fUml 

0.0026688 In.Hg-cf/ml-R 

9777 scf/MMBtu 

Instrumental Data 

4.14 %-dry 

15.40 %-dry 

80.46 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client Spruance Genco, LLC Test Location 

Project No. 3333 Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1~ Y·Vm * Pb/Tm 

Vmstd = 5.374 dscf 

0.1522 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws '" 

Bws = 

Based on the M29 sampling train 

0.1301 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No.4 

One 

Ms = [«44*%C02) + (32*%02) + (28*%N2» * (1-Bws)] + (18*Bws) 

Ms = 28.986 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs = 

Vs = 

Based on the M29 sampling train 

46.850 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min ;0 Vs * As 

Oa = 234213.74 cfm 

6632.93 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Ostd = Oa ;0 (TstdlTs) • (Ps/Pstd) * (1-Bws) 

Ostd = 165562.09 dscfm 

4688.72 dscmm 

8) Mercury concentrations and emission rates 

Element 

Mercury 

C[M] = M[M] (ug) I Vmstd (dscm) 

C[M](Jb/dscf) '" C[M](ug/dscm) *1e-06g/ug· 2.20Se-03Ib/g· 0.02832 dscm/dscf 

E[M](Ib/hr) = C[M] (ug/dscm) • (2.20SE-09) (Ib/ug) * Ostd (dscmm) .. 60 (min/hr) 

E[M](Ib/MMBtu) = C[M](lb/dscf) * Fd • (20.9/20.9-%02) 

C[M](@ corr. 02) = C[M] (ug/dscm) .. [(20.9-corrected %02) I (20.9-actual %02)] 

Corrected 02 percentage is: 7 % 

Sample 

Mass lug) 

0.0018 

Conc. 

(ug/dscm) 

0.012 

Conc.@COIT. 02 

(ug/dscm) 

0.010 

Conc. 

(lb/dscO 

7.39E-13 

EmissIon Rate 

(Ib/hr) 

7.34E-06 

Page 2 

Emission Rate 

(lb/MMBtu) 

9.01E-09 
3333-Hg-unspiked-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

Tm= 

INPUT Ts = 

INPUT Tstd= 

INPUT Y = 

INPUT t = 

INPUT Ds= 

INPUT 

INPUT 

INPUT 

As = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Method 1, 2, 3A, and 30B - Unspiked Tube 

(Flows, 021C02, and Mercury) 

Spruance Genco, LLC 

3333 

Unit No.4 

Two 

04/21/10 

0711-1311 

Emission Data 

8.462 dcf 

-0.50 in. H2O 

29.96 in Hg 

29.92 in. Hg 

29.92 in Hg 

527.1 R 

647-4 R 

527.7 R 

1.000 

360 min 

10.30 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Diameter of Stack 

83.32043375 sq. ft. Cross sectional area of stack 

8549 ft[(lb/lbmolt(inHg)]".5}/[s*R*inH20] 

17637 R/in.Hg 

0.047070 cu.ftlml 

0.0026688 in.Hg-cf/ml-R 

9920 scf/MMBtu 

Instrumental Data 

3.86 %-dry 

14.95 %-dry 

81.19 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Location 

Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y" Vm .. Pbl Tm 

Vmstd = 8.483 dscf 

0.2402 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws= 

Bws= 

Based on the M29 sampling train 

0.1326 

4) Molecular weight ofthe stack gas on a wet basis, Ms. 

Unit No.4 

Two 

Ms = [((44*%C02) + (32*%02) + (28"*%N2» * (1-Bws)] + (18*Bws) 

Ms = 28883 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs = 

Vs = 

Based on the M29 sampling train 

47.449 fps 

6) Average actual stack gas volumetric flowrate, Oa. 

Oa = 60 sec/min "* Vs ... As 

Qa = 237208.28 cfm 

6717.74 cmm 

7) Average stack gas dry volumetric flowrats, Qstd. 

Ostd = Qa'" (TstdfTs)" (Ps/Pstd)" (1-Bws) 

Qstd = 167729.95 dsefm 

4750.11 dsemm 

8) Mercury concentrations and emission rates 

C[M] = M[M] (ug) / Vmstd (dsem) 

C[M](Ib/dscf) = C[M](ug/dscm) .. 1 e-06g/ug ... 2.205e-03Ib/g ... 0.02832 dsem/dscf 

E[M](lb/hr) = C[M] (ug/dscm) .. (2.205E-09) (Ib/ug) .. Ostd (dscmm) ... 60 (min/hr) 

E[M](tb/MMBtu) = C[M](lb/dscf) ... Fd ... (20.9120.9-%02) 

C[M](@ corr. 02) = C[M] (ug/dsem) ... [ (20 9-corrected %02) I (20.9-actual %02)] 

Corrected 02 percentage is. 7 % 

Sam!;!le Cone Conc.@corr. 02 Cone. Emission Rate 

Element Mass (ug} (ug/dscm} (ug/dsem) (Ib/dscf) (Ib/hr) 

Mercury 0.0033 0.014 0.011 8.58E-13 863E-06 

Page 2 

Emission Rate 

(lb/MMBtu) 

1.04E-08 
3333-Hg-unspiked-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vm= 

Pstatic = 

Pb = 

Ps = 

Pstd = 

Tm= 

Ts = 

Tstd= 

y= 

t= 

Os = 

As = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

[02] 

[C02] 

[N2] 

AirNova, Inc. 

EPA Method 1, 2, 3A, and 30B· Unspiked Tube 

(Flows, 02fC02, and Me,rcury) 

Spruance Genco, LLC 

3333 

Unit No.4 

Three 

04/21/10 

1412-2012 

Emission Data 

7.962 dcf 

-0.50 in, H20 

29.96 in. Hg 

29.92 in. Hg 

29.92 m. Hg 

531.8 R 

648.7 R 

527.7 R 

1.000 

360 min. 

10.30 ft. 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling lime 

Diameter of Stack 

83.32043375 sq. ft Cross sectional area of stack 

85.49 ft[(lb/lbmolt(lnHg)]A.5}/[s*R*inH20] 

17.637 R/in.Hg 

0.047070 cu.fVml 

00026688 in.Hg-cf/ml-R 

9705 scf/MMBtu 

Instrumental Data 

3.82 %-dry 

14.90 %-dry 

81 28 %-dry 

constant 

constant 

constant 

Fuel Factor 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 
Client Spruance Genco, LLC Test Location 

Project No. 3333 Test Run 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm * Pb/ Tm 

Vmstd = 7.911 dscf 

0.2240 dscm 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

INPUT 

Bws = 

Bws = 

Based on the M29 sampling tram 

0.1327 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Unit No.4 

Three 

Ms = [«44*%C02) + (32*%02) + (28*%N2» * (1-Bws)] + (1B*Bws) 

Ms= 28.873 Ib/lbmole 

5) Average stack gas velocity, Vs. 

INPUT 

Vs= 

Vs '" 

Based on the M29 sampling train 

47.510 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Oa = 60 sec/min" Vs .. As 

Oa = 237513.23 cfm 

6726.37 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Ostd = Oa· (TstdfTs)· (PsiPstd)· (1-Bws) 

Ostd = 167589.69 dscfm 

4746.14 dscmm 

8) Mercury concentrations and emission rates 

Element 

Mercury 

C[MI = MIMI (U9) I Vmstd (dscm) 

C[M](Ib/dscf) = C[MJ(ug/dscm) * 1e-06g/ug * 2.205e-03Ib/g * 0.02832 dscm/dscf 

E[M](Ib/hr) '" C[M] (ug/dscm) • (2.20SE-09) (Ib/ug) .. Qstd (dscmm) .. 60 (min/hr) 

E[M](lb/MMBtu) = C[M](lb/dscf) * Fd " (20.9120.9-%02) 

C[M](@ corr. 02) = C[M] (ug/dscm) • [(20.9-corrected %02) 1 (20.9-actual %02) ] 

Corrected 02 percentage is. 7 % 

Sample 

Mass (ug) 

0.0048 

Conc. 

(ug/dscm) 

0.021 

Conc.@corr. 02 

(ug/dscm) 

0.017 

Conc. 

(lb/dscf) 

1.34E-12 

Emission Rate 

(Ib/hr) 

1.35E-05 

Page 2 

Emission Rate 

(Jb/MMBtu) 

1.59E-08 
M7ED/F 

Client 

Project No. 

Test location 

Test Date 

Spruance Genco, LlG 

3333 

Unit 4 DfF 

04/20110 

Parameter: 

Instrument Span (% 02/: 

Oxygen 

22.08 

Actual Calibration Gas Value (% 021: 

AnalYZer Gallbration Response (% 02/.-

AnalvzerCalibration Error(% Span): 

Run 1 

ZerQ System Calibration Gas 

AQQarent Init. Sys. Init. Sys. Final S~. Final SysStack Galib_ Cal. Bias Galib. Qa/. Bias 

Run Conc. Response (% sQan) ResQonse (% span/ 

1 4.21 0.10 0.36 0.09 0.32 

2 0.00 0.09 0.32 0_00 -0.09 

3 0.00 000 -0.09 0_00 -0.09 

4 0.00 0.00 -009 0.00 -0.09 

5 0.00 0_00 -0.09 000 -0.09 

6 0.00 0.00 -0.09 0.00 -0.09 

7 0.00 0.00 -009 0.00 -0.09 

B 0.00 0.00 -0.09 0.00 -0.09 

9 0.00 0.00 -009 0.00 -0.09 

10 0.00 0.00 -0.09 000 -0.09 

11 0.00 0.00 -0.09 000 -0.09 

12 0.00 0.00 -0.09 0_00 -0.09 

AirNova. Inc. 

EPA Method 7E Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

zero 

0.00 

0_02 

0.09 

Analvzer Ca/ib. Gases 

low !11iJ1. 

N/A 11.90 

N/A 

0.00 

11_89 

-005 

high 

22.08 

21.89 

-0.86 

Uescale System Calibration Gas 

~ Init. S:ys Init. Sys. Final Sys. Final S\"s. 

Qaff; Galib. Cal. Bias !&Ji!L Cal. Bia~ 

(% span) Response (% span) Response (% sQanl 

-0,05 11_90 0.00 11.98 0_36 

-041 11 98 0.36 0.00 -53.89 

0.00 0.00 -53_89 0.00 -53.89 

0.00 0.00 -53_89 0.00 -53.89 

000 0.00 -53.89 0.00 -53.89 

0_00 0.00 -53_89 0.00 -53.89 

0.00 0.00 -53.89 0.00 -53.89 

000 0.00 -53_89 0.00 -53.89 

0_00 0.00 -53.89 0.00 -53.89 

0.00 0.00 -53_89 0.00 -5389 

0_00 0.00 -5389 0.00 -53_89 

000 0.00 -53.89 0.00 -53_89 

Upscale 

Sys. Gal. Gas 

11 90 

11.90 

Galib. 

Drift 

f% span) 

0.36 

-54.26 

0_00 

000 

0.00 

000 

0.00 

0_00 

0.00 

0.00 

0.00 

0.00 

Page 1 

Actual 

Stack 

Conc. 

4.13 

-0.09 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 
M7EDfF 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, lLC 

3333 

Unit4 

04120/10 

Parameter: 

Instrument Span (% C02): 

Carbon Dioxide 

22.28 

Actual Calibration Gas Value (% C02). 

AnalvzerCa/ibration Response (% C02): 

Ana/k:zer Calibration Error f% Span): 

Zgro System Calibration Gas 

Al2l2a@nt Init. Sk:s. lo/t. Sk:s. Final Svs. Final Sk's. 

Stack Cafib. Qa/. Bias Calib. Cal. Bias 

Run ~ Response (% spanl Re:iQonse (% span) 

15.48 000 0.00 0.00 0.00 

2 0.00 0.00 0.00 0.00 0.00 

3 0.00 0.00 0.00 0.00 0.00 

4 0.00 0.00 0.00 0.00 0.00 

5 0.00 0.00 0.00 0.00 0.00 

6 0.00 0.00 0.00 0.00 0.00 

7 0.00 0.00 0.00 0.00 0.00 

8 0.00 0.00 0.00 0.00 0.00 

9 0.00 0.00 0.00 0.00 0.00 

10 0.00 0.00 0.00 0.00 000 

11 0.00 000 0.00 000 0.00 

12 0.00 0.00 0.00 0.00 0.00 

AirNova, Inc. Page 2 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Ang/'aer Ca/ib. Ga:ies /JQscale 

""" low mid high Sk:s. Cal. Ga:i 

0.00 N/A 12.38 22.38 12.38 

0.00 N/A 12.33 22.22 12.38 

0.00 0.00 ·0.22 -0.72 

U\2sci!le System Calibration Gas 

Cal/b. Init. Sk's. Init. Sk:s. Final S\:1i. Final Sk:s. Ca/ib. Actual 

Dn"ft Calib. ~a/. Bias Calib. Cal. Bias Drift Slack 

(% span) Response (% span) Re@onse (% span! (% span) Conc. 

0.00 12.45 0.31 12.45 0.31 0.00 15.39 

0.00 12.45 0.31 0.00 -5557 ·55.88 0.00 

0.00 0.00 -5557 0.00 -5557 0.00 ERR 

0.00 0.00 -55.57 0.00 ·55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

000 0.00 -55.57 0.00 -55.57 0.00 ERR 

000 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

000 0.00 -55.57 0.00 -55.57 0.00 ERR 
M7EDfF 

Client 

Project No. 

Test Location 

Test Date 

SpnJance Genco, LLC 

3333 

Unit4 

04120/10 

Parameter: Carbon Monoxide 

Instrument Span (ppm V COt 935.7 

Actual Calibration Gas Value (PQmV CO): 

AnalvzerCalibration Response (ppmV CO): 

Analyzer Calibration Error (% Span): 

Zero S~tem Caligration Gas 

Appaal:nt Init. Sl!~. !nit SI!s. FinfiJ S):,:s Final S):::s. 

Stack Gal/b_ Cal. Bias Galib. Gal. Bias 

Run Conc. Response (% span) Response l% span) 

279.0 0.0 0.52 0.0 0.52 

2 00 00 0.52 0.0 0.52 

3 0.0 0.0 0.52 0.0 0.52 

4 00 00 0.52 0.0 0.52 

5 00 00 0.52 0.0 0.52 

6 0.0 0.0 0.52 0.0 0.52 

7 00 0.0 0.52 0.0 0.52 

8 0.0 0.0 0.52 0.0 0.52 

9 0.0 00 0.52 0.0 0.52 

10 0.0 0.0 0.52 0.0 0.52 

11 0.0 00 0.52 0.0 0.52 

12 00 0.0 0.52 0.0 0.52 

AirNova, Inc. Page 3 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Ana/l!zer Qf!.I/b. Gases Urw;.f!.le 

zero low !11iJJ. high SI!s. Cal. Gas 

0.0 00 486.0 935.7 486.0 

-4.9 00 488.0 942.0 486.0 

-0.52 0.00 0.21 0.67 

Uj2scale Sy:stgm Calibration Gas 

Galib. Init Sl!s. Init. Sl§. Final S):::s. Final SI!s. Galib. Actual 

Drift Calib_ Gal. Bia~ Calib. Cal. Bias Drift Stack 

(% span) Response (% span) Response (% span) (% soan) Conc. 

0.00 483.0 -0.32 479.0 -0.75 -0.43 281.9 

0.00 479.0 -0.75 0.0 -51.94 -51.19 0.0 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 
M7ED/F2 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLG 

3333 

Unit4 OIF 

04/21/10 

Parameter Oxygen 

Instrument Span t% 02): 22.08 

Actual Calibration Gas Value (% 02): 

Anal~er Calibration Response t% 021-

AnalyzerCalibration Error(% Span): 

Run 2 

Zero §y:stem Calibration Gas 

Appa~nt Init. S~. !nit. 8):::5. Final S):::s. Fm§.1 Sj!'s. 

Sreck (;.a/ib. Cal. Bias Calib. Cal. Bias 

Run Conc. Response (% span! Response t% span) 

3.89 0.10 0.36 0.00 -0.09 

2 0.00 0.00 -0.09 0.00 -0.09 

3 0.00 0.00 -0.09 0.00 -0.09 

4 0.00 0.00 -0.09 0.00 -0.09 

5 0.00 0.00 -0.09 0.00 -0.09 

6 0.00 0.00 -0.09 0.00 -0.09 

7 0.00 0.00 -0.09 0.00 -0.09 

8 000 0.00 -0.09 0.00 -0.09 

9 0.00 0.00 -0.09 0.00 -0.09 

10 000 000 -0.09 0.00 -0.09 

11 0.00 0.00 -0.09 0.00 -0.09 

12 0.00 0.00 -009 0.00 -0.09 

AirNova, Inc. Page 1 

EPA Method 7E Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal~er (;.a.fib Gases !.lJJ.scale 

zero lOY!< mid high S!::§:. Cal. Gas 

0.00 NfA 11.90 22.08 11.90 

0.02 NfA 11.99 21.92 11.90 

0.09 0.00 0.41 -0.72 

UR§cale Sy:stem Calibration Gas 

Cafib. Init. S):::s. iait Svs. Final S~. Final S):::s. Galib. Actual 

Drift Calib. Ca.i Bias Cal/b. Cal. Bias Drift Stack 

(% span! Response (% span) Response t% span) (% sp§'n) Conc. 

-0.45 11.95 0.23 11.98 0.36 0.14 3.84 

0.00 11.98 0.36 0.00 -53.89 -54.26 0.00 

0.00 0.00 -53.89 0.00 -5389 0.00 ERR 

000 0.00 -53.89 0.00 -5389 0.00 ERR 

0.00 0.00 -53.89 0.00 -fi3.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.B9 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.B9 0.00 ERR 

000 000 -53.89 0.00 -5389 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.B9 0.00 ERR 

000 0.00 -53.B9 0.00 -53.B9 0.00 ERR 

000 0.00 -53.89 0.00 -53.89 0.00 ERR 
M7ED/F2 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Umt4 

04121/10 

Parameter: Carbon Dioxide 

Instrument Span f% C02): 22 28 

Actual Calibration Gas Value f% C02t 

AnalYZer Calibration Response (% C02): 

Analyzer Calibration Error (% Span): 

Zero S~tem Calibration Gas 

Aggarent Init. ,'iys. fait. Sys. FinfJ/ Sys. Final Sys. 

Stack ~ Cal. Bia§. Calib. Cal. Bias 

Run Cone. Response f% §.Mn) Response f% §.@nJ 

15.22 ·0.12 -0.54 0.12 0.54 

2 0.00 0.12 054 0.00 0.00 

3 0.00 0.00 0.00 0.00 0.00 

4 0.00 0.00 0.00 0.00 0.00 

5 0.00 0.00 0.00 0.00 0.00 

6 0.00 0.00 0.00 0.00 0.00 

7 0.00 0.00 000 0.00 0.00 

a 0.00 0.00 0.00 0.00 0.00 

g 000 0.00 0.00 0.00 0.00 

10 0.00 0.00 0.00 0.00 0.00 

11 0.00 0.00 0.00 0.00 0.00 

12 0.00 0.00 0.00 0.00 0.00 

AirNova, Inc. 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

zero 

0.00 

0.00 

0.00 

Analyzer Calib. Gases 

low !l1iQ 

N/A 12.38 

N/A 12.45 

0.00 031 

high 

22.38 

22.34 

-0.18 

Ugscale Slfstem Calibration Gas 

Ca/ib. Init. Sys. Init. Sys. Final Sys. Final Sys. 

Drift Calib. Cal. Bia§. Calib. Cal. Big§. 

(% span) Resgonse f% span) Response f% §.Qan) 

1.08 12.57 0.85 12.57 0.85 

·0.54 12.57 0.85 0.00 ·55.57 

0.00 0.00 ·55.57 0.00 ·55.57 

0.00 0.00 ·5557 0.00 ·55.57 

0.00 0.00 ·55.57 0.00 ·55.57 

0.00 0.00 ·55.57 0.00 ·55.57 

0.00 0.00 -55.57 0.00 ·55.57 

0.00 000 ·55.57 0.00 ·55.57 

0.00 000 -55.57 0.00 ·55.57 

0.00 0.00 -55.57 0.00 ·55.57 

0.00 0.00 -55.57 0.00 -55.57 

0.00 0.00 -55.57 0.00 -55.57 

Upscale 

Sys. Cal. Gas 

12.38 

12.38 

Ca/ib. 

Drift 

(% span) 

0.00 

-56.42 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

Page 2 

Actual 

Stack 

Cone. 

14.99 

·0.12 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 

ERR 
M7ED/F2 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit4 

04/21/10 

parameter: Carbon Monoxide 

Instrument Span (PpmV COl: 935.7 

Actual Calib@tion Gas VSllue (vpmV CO): 

Analyzer Calibration Response WpmV COt 

Analyzer Calib@tion Error (% Span): 

Zero System CilIlibration GillS 

~rma~nt Init. Sys. Init· Sys. Final Sys. Finfj.1 Sys. 

Stack r:&IJ.!L Cal. Bias ~ Cal. Bias 

Run Conc. Response (% span) Response (% span! 

269.0 -4.9 -0.52 0.0 0.00 

2 0.0 0.0 0.00 00 0.00 

3 0.0 0.0 0.00 00 0.00 

4 00 0.0 0.00 0.0 0.00 

5 0.0 0.0 0.00 0.0 0.00 

6 0.0 0.0 0.00 0.0 0.00 

7 0.0 0.0 0.00 0.0 0.00 

8 0.0 0.0 0.00 0.0 0.00 

9 0.0 0.0 0.00 0.0 0.00 

10 0.0 00 0.00 0.0 0.00 

11 00 0.0 0.00 0.0 0.00 

12 00 0.0 0.00 00 0.00 

AirNova, Inc. Page 3 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Ana/l.a~rCalib. GSises Uf}.scale 

zero low mid high S~. Cal. Gas 

0.0 0.0 486.0 935.7 486.0 

0.0 0.0 488.0 938.0 4860 

0.00 0.00 0.21 0.25 

Ugscale System CalibratiQn ~as 

Cafib. Init. Sys. Init. Sys. Final Sys. Final Sys. Calib. Actual 

Drift Calib. Cal. Bias Ca/ib. Cal. Bias Drift Stack 

(% span) Response (% span) Response (% span) (% span! Cone. 

0.52 479.0 -0.75 479.0 -0.75 0.00 274.0 

0.00 4790 -0.75 0.0 -51.94 -51.19 O.D 

0.00 0.0 -51.94 00 -51.94 0.00 ERR 

0.00 0.0 -51.94 00 -51 94 0.00 ERR 

000 0.0 -51.94 0.0 -51.94 000 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 000 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 00 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 
M7ED/F3 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit 4 OfF 

04/22/10 

Parameter: 

Instrumenf Span (% 02): 

Oxygen 

22.08 

Actual Calibration Gas Value t% 02!: 

Analyzer Calibration Response t% 02): 

Analyzer Calibration Error (% Span); 

Run 3 

Zero SY1!tem Calibration Gas 

Apparent Init. ,£ys. Init. S~. FinaIS!::§. Final SJ:::s. 

Stack Calib. Cal. Bias Calib. Cal. Bias 

Run Conc. Response (% soanl Response (% span! 

406 0.12 0.45 0.10 0.36 

2 0.00 0.10 0.36 0.00 -0,09 

3 0.00 0.00 -0.09 0.00 -0.09 

4 0.00 0.00 -0.09 0.00 -0.09 

5 0.00 0.00 -0.09 0.00 -009 

6 0.00 000 -0.09 0.00 -0.09 

7 0.00 0.00 -0.09 0.00 -0.09 

8 0.00 0.00 -0.09 0.00 -0.09 

9 0.00 0.00 -009 0.00 -0.09 

10 0.00 0.00 -0.09 0.00 -0.09 

11 0.00 0.00 -0.09 0.00 -0.09 

12 0.00 0.00 -0.09 0.00 -0.09 

AirNova, Inc. Page 1 

EPA Method 7E Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Analvzer Calib. Gases Upscale 

zero low mid high S!:,:s. Cal. Gas 

000 NfA 11.90 22.08 11.90 

0.02 NfA 11.89 21.91 11 90 

0.09 0.00 -0.05 -0.77 

UR§,cale Sllstgm CalibratiQn Gas 

Calib. Init. SJ:::s. lait SJ:::s. Final SJ:::s. Final S\:':S. Galib. Actual 

Drift Calib. Cal. Bias Galib. Cal. Bias Drift Stack 

(% span) Response (% spanl Response (% span! (% soan! Conc. 

-0.09 11.96 0.27 11.96 0.27 0.00 3.97 

-0.45 11 96 0.27 0.00 -53.89 -54.17 -0.10 

0.00 0.00 -53.89 000 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

000 0.00 -53.89 000 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -5389 0.00 ERR 

000 0.00 -53.89 0.00 -53.89 0.00 ERR 

000 0.00 -53.89 0.00 -53.89 0.00 ERR 

000 0,00 -53.89 0.00 -53.89 0.00 ERR 

0.00 0.00 -53.89 0.00 -53.89 0.00 ERR 
M7EDJF3 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit4 

04/22/10 

Parameter: Carbon Dioxide 

Instrument Span (% C02!: 22.28 

Actual Calibration Gas Value (% C02): 

Analvzer Calibration Response (% C02): 

Analyzer Calibration Error (% Span): 

Zero Sy:stem Calibration Gas 

{jQJ1.f!.fent !nit. SJl:s. Init. SJl:s ... Final SJl:s. Final SJl:s. 

SIiill< Ca/ib. Cal. Bias Calib. Qal Bias 

Run Conc. Response (% soan) Response (% span) 

1 15.52 0.00 0.00 0.00 0.00 

2 0.00 0.00 0.00 0.00 0.00 

3 0.00 0.00 0.00 0.00 0.00 

4 000 0.00 0.00 0.00 0.00 

5 0.00 0.00 0.00 0.00 0.00 

6 0.00 0.00 0.00 0.00 0.00 

7 0.00 0.00 000 0.00 0.00 

8 0,00 0.00 000 0,00 0.00 

9 0.00 0.00 0.00 0.00 0.00 

10 0,00 0.00 000 0.00 0.00 

11 0.00 0.00 0.00 0.00 0.00 

12 0.00 0.00 0.00 0.00 0.00 

AirNova,lnc. Page 2 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal'Lzer Cafib. Gases Upscale 

zero low mid high SJl:s. Cal. Gas 

0.00 N/A 12.38 22.38 12.38 

0.00 N/A 12.45 22.46 12.38 

0.00 0.00 0.31 0.36 

U~scale Sy:§:tem galil;2ration Gas 

Calib. Init. SJl:s. Init. SJl:s. Final SJl:s. Final S~. Calib. ~ 

Drift Cafib. Cal. Bia;s. CaJib. Cal. Bia;s. Drift Stack 

(% span) Response (% span) Response (% span) (% span) Conc. 

0.00 12,57 085 12.45 0.31 -054 15.36 

000 12.45 0.31 0.00 -55.57 -55.88 0.00 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0,00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0,00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

000 000 -55.57 0.00 -55.57 0.00 ERR 
M7ED/F3 

Client 

Project No. 

Test Location 

Test Date 

Spruance Genco, LLC 

3333 

Unit4 

04/22110 

Parameter: Carbon Monoxide 

Instrument Span (ppmV GO): 935.7 

Actual Calibration Gas Value (ppmV CO): 

AnalvzerCalibratlOn Response (oemV CO), 

Anafy2er Calibration Error £% Span): 

Zero S~tem Calibration Gas 

A/J.earent Init. SJ:::s. Init· Sit's. Final SJ:::s. Final SJ:::s. 

Stack Galib. Cal. Bias Calib. Gal. Bias 

Run Cone. Response (% span) Response (% span) 

1 332.0 0.0 0.00 -4.9 -0.52 

2 0.0 -4.9 -0.52 0.0 0.00 

3 0.0 0.0 0.00 00 0.00 

4 0.0 0.0 0.00 00 0.00 

5 0.0 0.0 0.00 00 0.00 

6 0.0 0.0 0.00 0.0 0.00 

7 0.0 0.0 0.00 00 0.00 

8 0.0 0.0 0.00 00 0.00 

9 0.0 0.0 0.00 0.0 0.00 

10 0.0 0.0 0.00 00 0.00 

11 0.0 0.0 0.00 0.0 0.00 

12 0.0 0.0 0.00 0.0 0.00 

AirNova, Inc. Page 3 

EPA Method 6C Calculations 

(Cal. Error, Bias Drift and Bias Adjustment) 

Anal'a,er Galib. Gases UpSCa/f/. 

Zf/.ro low mid high SJ:::s. Gal. Gas 

0.0 0.0 486.0 935.7 486.0 

0.0 0.0 488.0 938.0 4860 

0.00 0.00 0.21 0.25 

Uru!c~Je System Calibration Gas 

Galib. Init. SJ:::s. Init. Sit's. Final,slt's. Final SJ:::s. Cafib. &JJJ.m 

Drift Ca/ib. Gal. Bias Cafib. Gal. Bia§. Drift Stack 

f% sean) Response (% span) Reseonse (% span) (% span) Cone. 

-0.52 474.0 -1.28 479.0 -0.75 0.53 339.4 

0.52 479.0 -0.75 0.0 -51.94 -51.19 4.' 

0.00 0.0 -51.94 0.0 -51.94 0.00 ERR 

000 0.0 -51.94 0.0 -51.94 000 ERR 

000 00 -51.94 0.0 -51.94 0.00 ERR 

0.00 00 -51.94 0.0 -51.94 0.00 ERR 

0.00 00 -51.94 0.0 -5194 0.00 ERR 

0.00 0.0 -51.94 0.0 -5194 0.00 ERR 

0.00 00 -51.94 0.0 -51.94 0.00 ERR 

000 0.0 -51.94 0.0 -51 94 0.00 ERR 

0.00 00 -51.94 0.0 -51.94 0.00 ERR 

0.00 00 -51.94 0.0 -51.94 0.00 ERR 
3333-M23-R1 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd= 

dP= 

dH= 

Tm= 

Ts= 

Tstd= 

On = 

An = 

y= 

,= 

Os = 

As= 

Cp= 

Kp= 

K1 = 

K2= 

K3= 

Fd = 

[021 

[C021 

[N2) 

AirNova, Inc. 

EPA Methods 1,2,3A,4, and 23 

(Flows, 021C02, H20, and PCDDIPCDF) 

Spruance Genco, LLC 

3333 

Unit No.4 

0" 

04/20/10 

0925-1736 

Emission Data 

811.4 cc 

272.217 dcf 

-0.50 in. H20 

30.04 in. Hg 

30.00 in. Hg 

29.92 in. Hg 

0.7452 in. H20 ".5 

0.959 in. H20 

550.5 R 

652_5 R 

527.7 R 

0.225 in. 

0.000276 sq. ft. 

'1.02 

480 min. 

10.300 ft. 

Vol. of H20 collected 

Dry 9as meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 fl[(lb/lbmol)*(inHgW.5}l[s~R*inH2( Pitot tube constant 

17.637 Rlin.Hg 

0.047070 cU.fUml 

0.0026688 in.Hg-cflml-R 

9777 scf/MMBtu 

constant 

constant 

constant 

Fuel Factor 

Instrumental Data 

4.13 %-dry Oxygen concentration 

15.39 %-dry Carbon Dioxide concentration 

80.48 %-dry Nitrogen concentration 
Client 

Project No. 

Spruance Genco, llC 

3333 

Test Locatiot Unit No.4 

Test RUn One 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd :K1* Y ~ Vm ~ (Pb + dH/13.6) ITm 

Vmstd: 267.860 dscf 

7.59 dscm 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) : K2 * Vic 

Vw(std) = 38.192 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws : Vwstd I (Vmstd+Vwstd) 

Bws: 0.125 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms: ((44*%C02) + (32-%02) + (28*%N2» * (1-Bws) J + (18*Bws) 

Ms '" 29.05 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs : Kp * Cp * (dP) * (TsJPs*Ms)".5 

Vs: 46.30 fps 

6) Average actual stack gas volumetric flowrate, Qa, 

Qa = 60 sec/min * Vs * As 

Qa: 231466.3 cfm 

6555.1 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd: Qa - (TstdfTs) * (Ps/PSld) * (1-Bws) 

Qsld = 164282.3 dscfm 

4652.5 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Locatior Unit No.4 

Test Run One 

Calculations (cont.) 

08a) Chlorinated Oibenzodioxins (COD) Concentrations and Emission Rates 

Cone. [CDD]:: Mass [CCD](ng) IVmstd(dscm) 

C[CDD](@corr. 02) = qCDD] (ng/dscm) ~ [(20.9-corrected %02) I (20.9-actual %02) I 

C[CDD](lb/dscf):: C[CDD](ng/dscm) * 1e-09g/ng * 2.20Se-03Ib/g * 0.02832 dscm/dscf 

E[CDD](lbIMMBtu) = C[CDD](lb/dscf) * Fd * (20.9/20.9-%02) 

Corrected 02 percentage is: 7.0 % 

Sample Conc_ Conc, Conc. Emission Rate 

Compound Mass (ng) (ng/dscm) (ng/dscm (lb/dscO (lb/MMBtu) 

@7%02) 

2.3.7,8-TCDD 0.00347 4.S7E-04 3.79E-04 2.86E-17 3A8E-13 

other TCDD 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

2,3,7,8-PeCDD 0.00341 4.S0E-04 3.73E-04 2.B1E-17 3.42E-13 

other PeCDD 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

2,3,7,B-HxCDD 0.01147 1.S1E-03 1.2SE-03 9.44E-17 1.1SE-12 

other HxCDD 0,00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

2,3,7,B-HpCDD 0.00438 S.77E-04 4.79E-04 3,61E-17 4.39E-13 

other HpCDD 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O_OOE+OO 

OCDD 0.00777 1.02E-03 B.49E-04 6.40E-17 7.79E-13 

COD Avg Cone. 3.70E-04 Avg Ib/MMBtu 3.40E-13 

Page 3 

< 

< 

< 

< 

< 

< 

< 

< 

< 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Locatior Unit No.4 

Test Run One 

Calculations (cont.) 

08b) Chlorinated Oibenzofurans (COF) Concentrations and Emission Rates 

Conc. [CDF] = Mass [CDF](ng) /Vmstd(dscm) 

C[CDF](@carr. 02) = C[CDF] (ng/dscm)· [(20.9-corrected %02) I (20.9-actual %02) 1 

C[CDF](lb/dscf) = C[CDF](ng/dscm) * 1e-09g/ng * 2.205e-03Ib/g ~ 0.02832 dscmldscf 

E[CDF](lb/MMBtu) = C[CDF](lb/dscf)· Fd • (20.9/20.9-%02) 

Corrected 02 percentage is: 7.0 % 

Samole Conc. Conc. Conc. Emission Rate 

Compound Mass {ng} {ng/dscm} (ng/dscm (Ib/dscf) {lb/MMBtu} 

@7%02) 

2,3,7,S-TCDF 0.00247 3.26E-04 2.70E-04 2.03E-17 2.48E-13 

other TCDF 0.01240 1.63E-03 1.3SE-03 1.02E-16 1.24E-12 

1,2,3,7,8-PeCDF 0.00240 3.16E-04 2.62E-04 1.9BE-17 2.41E-13 

2,3,4,7,B-PeCOf 0.00217 2.S6E-04 2.37E-04 1.79E-17 2.18E-13 

other PeCDF 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

2,3,7,8-HxCDF 0.01019 1.34E-03 1.11E-03 B.39E-17 1.02E-12 

other HxCDF 000000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

2,3,7,B-HpCDF 0.00432 S.69E-04 4.72E-04 3.S6E-17 4.33E-13 

other HpCDF 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

OCDF 0.00748 9.B6E-04 B.17E-04 6.16E-17 7.S0E-13 

COF Avg Cone. 4.S3E·04 Avg IblMMBtu 4.16E·13 

Total Dioxin Avg Cone. 4.11 E·04 Avg Ib/MMBtu 3.78E·13 

Page 4 

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Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Locatior Unit No.4 

Test Run One 

08c)Non-ortho and Mono·ortho Substituted PCBs Concentrations and Emission Rates 

Conc. [PCB] = Mass [PCB](ng) I Vmstd(dscm) 

qCDF](@corr. 02) = C[CDF] (ng/dscm) * [(20.9-corrected %02) I (20.9-actual %02) I 

qCDF](lb/dscf) = C[CDF](ng/dscm) * 1e-099/n9 * 2.20Se-03Ib/g ~ 0.02832 dscm/dscf 

E[CDF](lb/MMBtu) = C[CDF](lbfdscf) * Fd * (20.9(20.9-%02) 

Corrected 02 percentage is: 7.0 % 

Non-ortho Substituted PCBs 

Samole Cone. Conc. Conc. Emission Rate 

Coml2ound Mass {ng} {ng/dscm} (ng/dscm (lb/dscO {lb/MMBtu} 

@7%02l 

PCB 77 0.01620 2.14E-03 1.77E-03 1.33E-16 1.62E-12 

PCB 81 0.01490 1.96E-03 1.63E-03 1.23E-16 1.49E-12 

PCB 126 0.01170 1.54E-03 1.28E-03 9.63E-17 1.17E-12 

PCB 169 0.02110 2.78E-03 2.31 E·03 1.74E-16 2.12E-12 

Mono-ortho Substituted PCBs 

PCB 105 0.06490 8.S6E-03 7.09E-03 5.34E-16 6.51E-12 

PCB 114 0.00955 1.26E-03 1.04E-03 7.86E-17 9,58E-13 

PCB118 0.17300 2.28E-02 1.89E-02 1,42E-15 i.74E-11 

PCB 123 0.00907 i.20E-03 9,91 E-04 7.47E-17 9.10E-13 

PCB 156 0.01010 i.33E-03 i.i0E-03 8.31E-17 1.01E-12 

PCB 157 0.01010 1.33E-03 1.10E-03 8.31E-17 1,01E-12 

PCB 167 0.01520 2.00E-03 1.66E-03 1.25E-16 1.52E·12 

PCB 189 0.01780 2.35E-03 1 94E-03 1,47E-16 1.79E-12 

Total PCBs Avg Conc. 3.4E·03 Avg Ib/MMBtu 8.9E-13 

Total Dioxin & PCBs Avg Conc. 1.91E·03 Avg Ib/MMBtu 6.35E-13 

9) Isokinecity, I. 

% I = [100*Ts"(K3*Vlc+(((Vm*Y)fTmt(Pb+(dH/13.6))))] I (60*t"Ps"Vs*An) 

%1= 102,51 

" < " symbol indicates values given are the quantitative detection limit. 

Page 5 

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3333-M23-R2 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm = 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP= 

dH ::: 

Tm= 

Ts= 

Tstd= 

Dn = 

An = 

y= 

1= 

Os = 

As = 

Cp = 

Kp= 

K1 = 

K2= 

K3= 

Fd = 

1021 

[C02] 

IN21 

AirNova, Inc. 

EPA Methods 1,2,3A,4, and 23 

(Flows, 02fC02, H20, and PCDDIPCDF) 

Spruance Genco, LLC 

3333 

Unit No.4 

Two 

04f21f10 

0711-2037 

Emission Data 

873.1 cc 

265.307 dcf 

-0.50 in. H2O 

29.96 in. H9 

29.92 in. H9 

29-92 in. H9 

0.7634 in. H20 h.5 

0.984 in. H2O 

526.0 R 

649.0 R 

527.7 R 

0.225 in. 

0.000276 sq. ". 

1.02 

480 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rtdelta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of stack 

83.3204 sq ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmol)*(inHg)]A.5}/[s*R*inH2i Pitot tube constant 

17.637 Rlin.Hg 

0.047070 cu.ftlml 

constant 

constant 

0.0026688 in.Hg-cf/ml-R constant 

9920 scf/MMBtu Fuel Factor 

Instrumental Data 

3.84 %-dry Oxygen concentration 

14.99 %-dry Carbon Dioxide concentration 

81.17 %-dry Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Locatior Unit No.4 

Test Run Two 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1" Y ~ Vm " (Pb + dH/13.6) I Tm 

Vmstd = 272.512 dscf 

7.72 dscm 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 41.097 sef 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws '" Vwstd I (Vmstd+Vwstd) 

Bws = 0.131 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [((44~%C02) + (32*%02) + (28*%N2)) * (1-Bws) 1 + (18"Bws) 

Ms = 28.91 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)h.5 

Vs = 47.49 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min * Vs * As 

Oa = 237412.8 efm 

6723.5 emm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa· (TstdfTs)· (Ps/Pstd)· (1-Bws) 

Qstd = 167752.4 dscfm 

4750,7 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Locatior Unit No.4 

Test Run Two 

Calculations (cont.) 

08a) Chlorinated Oibenzodioxins (COD) Concentrations and Emission Rates 

Conc. [CDD] = Mass [CCD](ng) 1 Vmstd(dscm) 

C[CDD](@corr, 02) = C[CDD] (ng/dscm) ~ [(20.9-corrected %02) 1 (20.9-actual %02)] 

C[CDD](lb/dscfj = C[CDD](ng/dscm) ·1e-09g/ng * 2.205e-03Ib/g * 0.02832 dscm/dscf 

E[CDD](lbIMMBtu) = C[CDD](lb/dscfj ~ Fd * (20.9/20.9-%02) 

Corrected 02 percentage is: 7.0 % 

Sample Conc. Conc. Conc. Emission Rate 

Compound Mass (ng) (ng/dscml (ng/dscm Ob/dscfl (lblMMBtu) 

@7%02) 

2,3,7,8-TCDD 0,00341 4.42E·04 3.60E-04 2.76E·i7 3.35E-i3 

other TCDD 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

2,3,7,8-PeCDD 0.00447 5.79E-04 4.72E-04 3.62E-17 4.40E-13 

other PeCDD 0.00000 O.OOE+OO O,OOE+OO O.OOE+OO O.OOE+OO 

2,3,7,8-HxCDD 0.01345 1.74E-03 1.42E-03 i.09E-16 1.32E-12 

other HxCDD 0.00000 O,OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

2,3,7,8-HpCDD 0.00394 5.11E-04 4.16E-04 3.i9E-i7 3.87E-i3 

other HpCDD 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

OCDD 0.04230 S.48E-03 4.47E-03 3.42E-16 4.16E-12 

COD Avg Conc. 7.93E·04 Avg IbfMMBtu 7.38E-13 

Page 3 

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Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Locatior Unit No.4 

Test Run Two 

Calculations (cont) 

OSb) Chlorinated Dibenzofurans (CDF) Concentrations and Emission Rates 

Conc. [CDF] = Mass [CDF](ng) I Vmstd(dscm) 

C[CDF](@corr. 02) = C[CDF] (ngJdscm) r [(20.9-corrected %02) J (20.9-actual %02)] 

C[CDF](lbJdscf) = C[CDF](ng/dscm) * le-09g/ng * 2.205e-03Ib/g ~ 0.02832 dscm/dscf 

E[CDF](lb/MMBtu) = C[CDF](lb/dscf) ~ Fd * (20.9/20.9-%02) 

Corrected 02 percentage is: 7.0 % 

Sample Conc. Conc. Conc. Emission Rate 

Compound Mass (ng) (ng/dscm) (ng/dscm Ob/dscfl (lb/MMBtu) 

@7%02) 

2,3,7,8-TCDF 0.00261 3.3SE-04 2.76E-04 2.11E-17 2.57E-13 

other TCDF 0.00308 3.99E-04 3.25E-04 2.49E-17 303E-13 

1,2,3,7,8-PeCDF 0.00244 3.16E-04 2.58E-04 1.97E-17 2.40E-13 

2,3,4,7,S-PeCDF 0.00249 3.23E-04 2.63E-04 2.01E-17 2.45E-13 

other PeCDF 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

2,3,7,8-HxCDF 0.01006 1.30E-03 1.06E-OS 8.14E-17 9.89E-13 

other HxCDF 001200 1.55E-03 1.27E-03 9.71E-17 1.18E-12 

2,3,7,8-HpCDF 0.07990 1.04E-02 8.44E-03 6.47E-16 7.86E-12 

other HpCDF 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

OCDF 0.07430 9.63E-03 7.84E-03 6.01E-16 7.31E-12 

COF Avg Cone. 1.97E-03 Avg Ib/MMBtu 1.S4E-12 

Total Dioxin Avg Cone. 1.3SE-03 Avg IblMMBtu 1.29E-12 

Page 4 

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Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Locatior Unit No.4 

Test Run Two 

OBc)Non-ortho and Mono·ortho Substituted PCBs Concentrations and Emission Rates 

Conc. [PCB) = Mass [PCB)(ng) I Vmstd(dscm) 

C[CDF](@carr. 02) = C[CDF) (ng/dscm)" [(20.9·corrected %02) 1 (20.9-actual %02)] 

C[CDF](Ib/dscf) = C[CDF](ng/dscm} * 1e-09g/ng" 2.205e-03Ib/g ~ 0.02832 dscm/dscf 

E[CDF)(lbIMMBtu) = C[CDF](lb/dscf) "Fd * (20,9/20.9-%02) 

Corrected D2 percentage is: 7.0 % 

Non-ortho Substituted PCBs 

Sample Conc. Conc. Conc. Emission Rate 

Compound Mass tng} (ng/dscm) (ng/dscm (lb/dscO {lb/MMBtu} 

@7%02) 

PCB 77 0.01280 1.66E-03 1.35E-03 1.04E-16 1.26E-12 

PCB 81 0,00464 6.01 E-04 4.90E-04 3.75E-17 4.56E·13 

PCB 126 0.00615 7,97E-04 6.49E-04 4,98E·17 6.05E-13 

PCB 169 0.00993 1.29E-03 1.05E-03 8.03E-17 9.76E-13 

Mono-ortho Substituted PCBs 

PCB 105 0.06880 8.91 E-03 726E-03 5.57E-16 6.77E-12 

PCB114 0,00450 5.83E-04 4,75E-04 3.64E-17 4.43E-13 

PCB118 0.17700 2.29E-02 1.87E-02 1.43E-15 1.74E-11 

PCB 123 0.00434 5.62E-04 4.58E-04 3.51E-17 4,27E-13 

PCB 156 0.01145 1.48E-03 1.21E-03 9.26E·i7 1.13E-12 

PCB 157 0.01145 1.48E·03 i.21E-03 9.26E·17 1.13E-12 

PCB 167 0.00754 9.77E-04 7.96E-04 6.10E-17 7.41E-13 

PCB 189 0.00821 1.06E-03 8.67E-04 6.64E-17 a,07E-13 

Total PCBs Avg Conc. 2.9E·03 Avg IblMMBtu 4.0E-13 

Total Dioxin & PCBs Avg Cone. 2.13E-03 Avg IblMMBtu 8,46E·13 

9) Isokinecity, I. 

% I = [100"Ts*(K3·Vlc+«(Vm~Y)fTmr(Pb+(dH/13.6))))J I (60*t"Ps*\ls"An) 

%1= 102.13 

"<" symbol indicates values given are the quantitative detection limit. 

Page 5 

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3333-M23-R3 

Client 

Project No. 

Test Location 

Test Run 

Test Date 

Test Time 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

dP= 

dH= 

Tm= 

Ts= 

Tstd= 

Dn = 

An = 

y= 

t= 

Ds = 

As= 

Cp= 

Kp = 

K1 = 

K2= 

K3= 

Fd= 

(02( 

[C02] 

(N2) 

AirNova, Inc. 

EPA Methods 1,2,3A,4, and 23 

(Flows, 021C02, H20, and PCDDIPCDF) 

Spruance Genco, LLC 

3333 

Unit No.4 

Three 

04/22/10 

0700-1509 

Emission Data 

797.4 cc 

271.163 dcl 

-0.50 in. H20 

29.96 in. Hg 

29.92 In. Hg 

29.92 in. Hg 

0.7449 in. H20 ''.5 

0.965 in. H20 

546.2 R 

653.5 R 

527.7 R 

0.225 in. 

0.000276 sq. ft. 

1.00 

480 min. 

10.300 ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Nozzle diameter 

Area of nozzle orifice 

Meter calibration factor 

Duration of sampling time 

Diameter of slack 

83.3204 sq. ft. Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ft[(lb/lbmolt(inHg)]~ .5)/[s*R*inH2! Pitot tube constant 

17.637 Rlin.Hg constant 

0.047070 cu.ft/ml constant 

0.0026688 in.Hg-cf/ml-R constant 

9705 scf/MMBtu Fuel Factor 

Instrumental Data 

3.97 %-dry Oxygen concentration 

15.36 %-dry Carbon Dioxide concentration 

80.67 %-dry Nitrogen concentration 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Locatior Unit No.4 

Test Run Three 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1' Y * Vm "(Pb + dHf13,6) f Tm 

Vmstd = 262_930 dscf 

7.45 dscm 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2" Vic 

Vw(std) = 37.533 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws '" Vwstd I (Vmstd+Vwstd) 

Bws= 0.125 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44"%C02) + (32*%02) + (28*%N2»" (1-Bws) J + (18*Bws) 

Ms= 29.04 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp" Cp" (dP) " (TsJPs*Ms)h.S 

Vs = 46.39 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs " As 

Qa = 231914,2 cfm 

6567.8 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa" (TstdfTs)" (Ps/Pstd)" (1-Bws) 

Qstd = 163886:1 dscfm 

4641.3 dscmm 

Page 2 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Locatior Unit No, 4 

Test Run Three 

Calculations (cont.) 

08a) Chlorinated Dibenzodioxins (CDD) Concentrations and Emission Rates 

Conc. [CDDI = Mass [CCD](ng) fVmstd(dscm) 

C[CDD](@ carr. 02) = C[CDDI (ngfdscm) * [(20.9-corrected %02) f (20.9-actual %02)] 

C[CDD](lbfdscf) = C[CDD](ng/dscm) *1e-09gfng * 2.205e-03Ib/g· a 02832 dscmfdscf 

E[CDD](lbfMMBtu) = C[CDD](lb/dscf);t Fd;t (20.9f20.9-%02) 

Corrected 02 percentage IS: 7.0 % 

Sample Conc. Conc. Conc. Emission Rate 

Compound Mass (ng) (ngfdscm) (ngfdscm (Ibfdscf) (lbfMMBtu) 

@7%02) 

2,3,7,8-TCDD 0.00203 2,73E-04 2.24E-04 1.70E-17 2,04E-13 

ather TCDD 0.00000 O.OOE+OO O,OOE+OO O,OOE+OO O.OOE+OO 

2,3,7,8-PeCDD 0,00172 2.31E-04 1.90E-04 1.44E-17 1.73E-13 

ather PeCDD 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

2,3,7,8-HxCDD 0.00569 7,64E-04 6.27E-04 4.77E-17 5.72E-13 

ather HxCDD 0,00000 O.OOE+OO O,OOE+OO O.OOE+OO O.OOE+OO 

2,3,7,S.HpCDD 0.00203 2.73E-04 2.24E-04 1.70E-17 2.04E-13 

other HpCDD 0.00000 O,OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

OCDD 0,01670 2.24E-03 1.S4E-03 1.40E-16 1.6SE-12 

COD Avg Cone, 3.45E-04 Avg IblMMBtu 3.14E-13 

Page 3 

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Project No. 

Spruance Genco, LLC 

3333 

Test Locatior Unit No.4 

Test RUn Three 

Calculations (cont.) 

OBb) Chlorinated Dibenzofurans (CDF) Concentrations and Emission Rates 

Conc. [CDF] = Mass [CDF](ng) I Vmstd(dscm) 

ClCDF](@corr. 02) := C[CDF] (ng/dscm) * [(20.9-corrected %02) I (20.9-actual %02)] 

ClCDF](lb/dscf) = C[CDF](ng/dscm) -le-09g/ng - 2.20Se-03Ib/g - 0.02832 dscmldscf 

E[CDF](lbIMMBtu) = ClCDF](lb/dscf)· Fd· (20,9/20,9-%02) 

Corrected 02 percentage is: 7.0 % 

Sample Conc. Conc Conc. Emission Rate 

Compound Mass (ng) (ng/dscm) (ng/ds!<m ~ (lb/MMBtu) 

@7%02) 

2,3,7,8-TCDF 0.00123 1.6SE-04 1.36E-04 1.03E-17 1.24E-13 

other TCDF 0.01010 1.36E-03 1.11E-03 8,47E-17 1.01E-12 

1,2,3,7,8-PeCDF 0.00107 1,44E-04 1,18E-04 8,97E-18 1.08E-13 

2,3,4,7,8-PeCDF 0.00106 1,41E-04 1,16E-04 8.81E-18 1.0SE-13 

otherPeCDF 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

2,3,7,8-HxCDF 0.00432 S,80E-04 4.76E-04 3.62E-17 4.34E-13 

other HxCDF 0.00000 O.OOE+OO O,OOE+OO O,OOE+OO O.OOE+OO 

2,3,7,8-HpCDF 0.00819 1.10E-03 9.03E-04 6.87E-17 8.23E-13 

other HpCDF 0.00000 O.OOE+OO O.OOE+OO O.OOE+OO O.OOE+OO 

OCDF 0.01320 1.77E-03 1,46E-03 1.11E-16 1.33E-12 

COF Avg Conc. 4.32E-04 Avg Ib/MMBtu 3.93E-13 

Total Dioxin Avg Conc. 3.88E-04 Avg Ib/MMBtu 3.54E·13 

Page 4 

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, 

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, 

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Client 

Project No. 

Spruance Genco, LLC 

3333 

Test Locatior Unit No.4 

Test Run Three 

08c)Non-ortho and Mono-ortho Substituted PCBs Concentrations and Emission Rates 

Conc. [PCB] = Mass [PCB](ng) IVmstd(dscm) 

qCDF]{@corr. 02) = qCDF] (ngldscm) * [(20.9-corrected %02) I (20.9-actual %02)] 

qCDF](lb/dscf) = qCDF](ng/dscm) *1e-09glng * 2.20Se-031b1g" 0.02832 dscm/dscf 

E[CDF)(lbIMMBtu) = qCDF](lb/dscf)· Fd" (20.9/20.9-%02) 

Corrected 02 percentage is: 7.0 % 

Non-ortho Substituted PCBs 

Sample Conc. Conc. Conc. Emission Rate 

Compound Mass (ng) (ngldscm) {ng/dscm {lb/dscO (lb/MMBtu) 

@7%02} 

PCB 77 0.01820 2.44E-03 2.01E-03 1.S3E-i6 1.83E-12 

PCB 81 0.00767 1.03E-03 8.46E-04 6.43E-17 7.71E-13 

PCB 126 0.00629 8.45E-04 6.94E-04 5.27E-17 6_32E-13 

PCB 169 0.01070 1.44E-03 1.18E-03 8.97E-17 1_08E-12 

Mono-ortho Substituted PCBs 

PCB 105 0.09400 1.26E-02 1.04E-02 7.S8E-16 9.44E-12 

PCB 114 0,00501 6,73E-04 5,5ZE-04 4.Z0E-17 5.03E-13 

PCB118 0.24Z00 3.Z5E-OZ 2.67E-02 2.03E-15 2.43E-i1 

PCB 123 0.00478 6.42E-04 5.27E-04 4.01E-17 4.80E·13 

PCB 156 0.01625 2.1SE-03 1.79E-03 i.36E-16 1.63E-·12 

PCB 157 0.01625 2_18E-03 1.79E-03 i.36E-16 1.63E-12 

PCB 167 0.00748 1.00E-03 8.25E-04 6.27E-17 7.52E-13 

PCB 189 0.00847 1.14E-03 9.34E-04 7.10E-17 8.51E-13 

Total PCBs Avg Cone. 4.0E-03 Avg IblMMBtu 4.3E-13 

Total Dioxin & PCBs Avg Conc. 2.20E-03 Avg IblMMBtu 3.90E·i3 

9) Isokinecity, I. 

% I = [100*Ts*(K3*Vlc+«(Vm*Y)fTm)*(Pb+(dH/13.6))))) I (60*t"Ps"Vs*An) 

% I :: 100.86 

.. <; .. symbol indicates values given are the quantitative detection limit. 

PageS 

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Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm= 

Pstatic = 

Pb= 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

y= 

1= 

Dn = 

An = 

Ds = 

As = 

Cp = 

Kp = 

K1 = 

K2= 

K3 = 

Fd = 

[02[ 

[C02] 

[N2] 

[COr 

AirNova, Inc. 

EPA Methods 1, 2, 3A, 4,10,18 and 25A 

(Flows, 02/C02, H20, CO and NMHC) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit NO.4 

04/20f10 

One 

0925-1736 

Emission Data 

811.4 cc 

272.217 dcf 

-0.50 in. H20 

30.04 in. Hg 

30.00 in Hg 

29.92 in. Hg 

0.7452 In. H20 '\5 

0.96 in. H2O 

550.5 R 

652.5 R 

527.7 R 

1.02 

480 min. 

0.225 in. 

0.000276 sq. ft. 

10.300 ft. 

83.3204 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of slack 

0.84 Pitot lube coefficient 

85.49 ft[ (lb/lbmol)~{inHg)]" .5}/[ s*R*inH20] 

17.637 Rfin.Hg constant 

0.047070 cU.Wml 

00026688 in.Hg-cf/ml-R 

9777 scf/MMBtu 

Instrumental Data 

4.13 %-dry 

15.39 %-dry 

80.48 %-dry 

281.9 ppmV-dry 

constant Pitot tube constant 

constant 

From EPA Reference Method 19 

Oxygen concentratIOn 

Carbon Dioxide concentration 

Nitrogen concentration 

Carbon Monoxide concentration 

Page 1 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Emission Source Unit No.4 

Test Run One 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm • (Pb + dH/13.6) I Tm 

Vmstd = 267.860 dscf 

7.586 dscm 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 38.192 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwsld I (Vmstd+Vwsld) 

Bws = 0.1248 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«(44~%C02) + (32*%02) + (28*%N2»· (1-Bws)] + (18~Bws) 

Ms= 29.052 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp * (dP) • (Ts/Ps*Ms)".5 

Vs = 46.300 fps 

6) Average actual stack gas volumetric flowrate, Ca. 

Oa '" 60 sec1min * Vs * As 

Oa = 231466.3 cfm 

6555.1 cmm 

7) Average stack gas dry volumetric flowrate. Qstd. 

Qstd = Qa * (TstdlTs) * (Ps/Pstd) • (1-Bws) 

Qstd = 164282.3 dscfm 

4652.5 dscmm 

8) Carbon Monoxide concentrations and emissions 

Corr. C[CO] = «20.9-02% corr. value)/(20.9·actual avg. 02% value»""Avg, raw CO value 

E[CO Ib/hrj = (C[CO]*Mol WI[CO]*60(min/hr)*Qstd(dscfm))/(Molar Vol. air*10"6) 

E[CO Ib/MMBluj = Cd .. Fd .. (20 9/(20.9-actual 02%» 

C[CO] = 281 9 ppmVd 

qCO] = 233.7 ppmVd corrected to 7 % 02 

Mol. Wt. [CO}= 28.01 Ib/lb-mole 

Molar vol air= 

E[CO) = 

Conv Factor. 

E[CO) = 

385 scf/lb·mole @ 68 

202.16 Ib/hr 

7.235E-08 convert ppmV 10 lb/scf CO 

0,249 Ib/MMBtu 

def F 

Page 2 
Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vic = 

Vm = 

Pstatic = 

Pb = 

Ps= 

Psld = 

dP = 

dH = 

Tm = 

Ts = 

Tstd= 

y= 

t= 

On = 

An" 

Ds= 

As = 

Cp = 

Kp = 

K1 = 

K2= 

K3= 

Fd = 

(02( 

(C021 

(N21 

(COj 

AirNova, Inc. 

EPA Methods 1, 2, 3A, 4, 10, 18 and 25A 

(Flows, 021C02, H20, CO and NMHC) 

Spruance Genco, LLC 

3333 

Richmond, Virginia 

Unit No.4 

04/21/10 

Two 

0711-2037 

Emission Data 

873.1 cc 

265.307 dcf 

-0.50 in. H20 

29.96 In. Hg 

29.92 in. Hg 

29.92 in. Hg 

0.7634 in. H20 ".5 

0.98 in. H2O 

526.0 R 

649.0 R 

527.7 R 

1.02 

480 min. 

0.225 in. 

0.000276 sq ft. 

10.300 ft 

83.3204 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling time 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 fI[ (lbllbmol)*(inHg))". 5}/[ s*R*inH20j 

17.637 Rfin.Hg constant 

0_047070 cu.Wml 

0.0026688 in.Hg-cffml-R 

9920 scf/MMBtu 

Instrumental Data 

3.84 %-dry 

14.99 %-dry 

81.17 %-dry 

274.0 ppmV-dry 

constant Pilot tube constant 

constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Carbon Monoxide concentration 

Page 1 
Client 

Project No. 

Spruance Genco, LLC 

3333 

Emission Source Unit No 4 

Test Run Two 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1~ Y * Vm" (Pb + dH/13.6) / Tm 

Vmstd = 272.512 dsc1 

7.718 dscm 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 41.097 scf 

3) Decimal fraction of moisture by volume in stack gas, Bws. 

Bws = Vwstd / (Vmstd+Vwstd) 

Bws = 0.1310 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = [«44*%C02) + (32*%02) + (2S*%N2» * (l-Bws)] + (lS*Bws) 

Ms= 28.907 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp * Cp ;0 (dP) .. (Ts/Ps*Ms)".5 

Vs = 47490 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min" Vs * As 

Qa = 237412.8 cfm 

6723.5 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd = Qa * (Tstd/Ts)· (Ps/Pstd)" (1-Bws) 

Qstd = 167752.4 dscfm 

4750.7 dscmm 

8) Carbon Monoxide concentrations and emissions 

Carr. qCO] = «20.9-02% carr. value)l(20.9-actual avg. 02% valueWAvg. raw CO value 

E[CO Ib/hr] = (qCO]*Mol Wt[COj*60(min/hr)*Qstd(dscfm»/(Molar Vol. air~10"6) 

E[CO Ib/MMBtu] = Cd • Fd .. (20.9/(20.9-actual 02%» 

qCO] = 2740 ppmVd 

qCO] = 223 2 ppmVd corrected to 7 % 02 

Mol. WI. [CO]= 28.01 Ib/lb-mole 

Molar vol air= 

E[CO]-

Conv Factor. 

E[CO]-

385 scf/lb-mole @ 

200.64 lb/hr 

7.235E-08 convert ppmV to Ib/scf CO 

0.241 Ib/MMBtu 

68 def F 

Page 2 
Client 

Project No. 

Test Location 

Emission Source 

Test Date 

Test Run 

Time Period 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

Vlc= 

Vm = 

Pstatic = 

Pb = 

Ps = 

Pstd = 

dP = 

dH = 

Tm= 

Ts = 

Tstd= 

y= 

1= 

Do· 

An = 

Os = 

As = 

Cp = 

Kp = 

Kl = 

K2= 

K3 = 

Fd = 

[02[ 

[C02[ 

[N2[ 

[COr 

AirNova, Inc. 

EPA Methods 1, 2, 3A, 4, 10, 18 and 25A 

(Flows, 02/C02, H20, CO and NMHC) 

Spruance Genco, LLC 

3333 

Richmond, Virgima 

Unit No, 4 

04/22/10 

Three 

0700-1509 

Emission Data 

797.4 cc 

271 163 dc1 

-050 in, H20 

29.96 in. Hg 

29,92 in, Hg 

29.92 in. Hg 

0.7449 in. H20 ".5 

0.97 in. H2O 

5462 R 

653.5 R 

527.7 R 

1.00 

480 min, 

0.225 in. 

0.000276 sq. ft. 

10300 ft. 

83.3204 sq. ft. 

Vol. of H20 collected 

Dry gas meter reading 

Static pressure 

Barometric pressure 

Stack pressure 

EPA Standard pressure 

Average sq.rt delta P 

Average draft gauge reading 

Average meter temperature 

Average stack temperature 

Standard temperature 

Meter calibration factor 

Duration of sampling tIme 

Nozzle diameter 

Nozzle area 

Diameter of stack 

Cross sectional area of stack 

0.84 Pitot tube coefficient 

85.49 ftl (Ib/lbmol)·(in Hg) 1".S}/[ s*R~in H20] 

17637 Rlin.Hg constant 

0.047070 cu,ft/ml 

0,0026688 in.Hg-cf/ml-R 

9705 scf/MMBtu 

Instrumental Data 

3.97 %-dry 

15.36 %-dry 

80,67 %-dry 

339.4 ppmV-dry 

constant Pitot tube constant 

constant 

From EPA Reference Method 19 

Oxygen concentration 

Carbon Dioxide concentration 

Nitrogen concentration 

Carbon Monoxide concentration 

Page 1 
Client 

Project No. 

Spruance Genco. LLC 

3333 

Emission Source Unit No_ 4 

Test Run Three 

Calculations 

1) Volume of gas sampled at standard conditions, Vmstd. 

Vmstd =K1* Y * Vm * (Pb + dH/13.6) I Tm 

Vmstd = 262.930 dsef 

7.446 dsem 

2) Volume of water vapor collected at standard conditions, Vw(std). 

Vw(std) = K2 * Vic 

Vw(std) = 37.533 sef 

3) Decimal fraction of moisture by volume In stack gas, Bws. 

Bws = Vwstd I (Vmstd+Vwstd) 

Bws = 0.1249 

4) Molecular weight of the stack gas on a wet basis, Ms. 

Ms = I ((44*%C02) + (32~%02) + (28*%N2» * (1-Bws)] + (18*8ws) 

Ms= 29.040 Ib/lbmole 

5) Average stack gas velocity, Vs. 

Vs = Kp • Cp • (dP) • (Ts/Ps*Ms)".5 

Vs = 46390 fps 

6) Average actual stack gas volumetric flowrate, Qa. 

Qa = 60 sec/min * Vs * As 

Qa = 231914.2 cfm 

6567.8 cmm 

7) Average stack gas dry volumetric flowrate, Qstd. 

Qstd'" Qa ~ (TstdfTs) * (Ps/Pstd) * (1-Bws) 

Qsld = 163886,1 dscfm 

4641.3 dscmm 

8) Carbon Monoxide concentrations and emissions 

Carr. C[CO] = {(20.9-02% carr. value)/{20.9-actual avg. 02% value»*Avg, raw CO value 

E[CO Ib/hr] = (C[CO)*Mol Wt[CO]*60(minfhr)*Qstd(dscfm))/(Molar Vol. air*10"6) 

E[CO Ib/MMBtul = Cd * Fd * (20.9/(20.9-actual 02%» 

C[CO] = 339.4 ppmVd 

qCO] = 278.7 ppmVd corrected to 7 % 02 

Mol. WI. [CO]= 28 01 Ib/lb-mo[e 

Molar vol air= 

E[COJ = 

Cony Factor. 

E[COJ = 

385 scf/lb-mole @ 68 

242.81 Ib/hr 

7.235E-08 convert ppmV to Ibfscf CO 

0.294 Ib/MMBtu 

def F 

Page 2 
Appendix 0 

Calibration Data 
Airgas. CERTIFICATE OF ANALYSIS 

Grade of Product: EPA Protocol 

Alrgas Specialty GaS9S 

600 Union LandlnQ Road 

Riverton. NJ 08077 

(856) 829-7878 

Part Number: E03NI80E15A 1087 Reference Number: 82-124198678-1 

fax (856) 829-0571 

WWW.a;rgas.com 

Cylinder Number: CC10892 Cylinder Volume: 150 Cu.Ft. 

Laboratory: ASG· Riverton - NJ Cylinder Pressure: 2015 PSIG 

Analysis Date: Nov 18, 2009 Valve Outlet: 590 

Expiration Date: Nov 18,2012 

Cerlificalion performed in accordance with "EPA Traceability Protocol (Sept. 1997)" using the assay procedures lisled. Analytical Methodology does not require correction for 

analytical interferences This cylinder has a lolal analyllcal uncertainty as slaled below with a ronrrdence level of 95%. There are no significant impurities which affect the use 

of this calibration mixture. All concentrations are on a volume/volume basis unless otherwise noted. 

Do Not Use This Cylinder below 150 psig.i.e. 1 Mega Pascal 

ANALYTICAL RESULTS 

Component Requested Actual Protocol Total Relative 

Concentration Concentration Method Uncertainty 

CARBON DIOXIDE 7.500 % 7.485 % G1 +/·1% NISTTraceable 

OXYGEN 12.50 % 12.46 % G1 +/~ 1% NIST Traceable 

NITROGEN Balance 

CALIBRATION STANDARDS 

Type LotiO Cylinder No Concentration Expiration Date 

NTf~Mplus 06120412 CC184945 19.66% CARBON DIOXIDE/NITROGEN May01,2010 

NTRM 03060218 XC024401 B 22.60% OXYGENfNlTROGEN Ju101,2011 

ANALYTICAL EQUIPMENT 

InstrumenUMakelModel Analytical PrinCiple Last Multipoint Calibration 

Siemens UJtramat 6E N1·NO·0820 NDIR Oct26,2009 

Siemens 5E SN805 Paramagnetic Oct 30, 2009 

Page 1 of 82·12419a678~1 

15000 
Airgas .. 

CERTIFICATE OF ANALYSIS 

Grade of Product: EPA Protocol 

Airgas Specially Gases 

600 Union LaMing Road 

Rivp,rton, MI 00077 

(B56) 829·7878 

fa, (055) S~9-057j 

Part Number: E03N!65E15A 1094 Reference Number: 82-124165926-1 

Cylinder Number" CC7900S Cylinder Volume: 154 Cu.Ft. 

Laboratory; ASG - Riverton - NJ Cylinder Pressure: 2015 PSIG 

AnalYSIS Date: Feb 02, 2009 Valve Outlet 590 

Expiration Date: Feb 02, 2012 

Certmoatlon performed In aooordance wllh "EPA Traceability Protocol (Sapl 1997)" using Ihe assay procedures lisled. Analytical Methodology dOes not require correction for 

analytical inlerferences_ This cylinder has a 10lal analytical uncertainly as slaled below with a conndence level of95%. There are no significanlimpurilies which affect Ihe use 

of Ihls calibration mixture. All concentrations sre on a volume/volume basis unless otherwise noled. 

Do Not Use This Cylinder below 150 pslg.I.e. 1 Mega Pascal 

-, ANALYTICAL.RlJSULTS . 

Component Requested Act~c'll Protocol Total Relative 

...... ' ..... .' .'. 

C~ncetitratloi1 , ,'" ~ "-

Ccincentratlo!1 lI!Iethofi Uncertainty 

"CI:\RB~N bidxIDE":" '1;2'!Sq "io."; --':,,' 1·2,.'39:·';(~ . 

:q'!, - t-I_' 1% NIsT Traceable 

'OXYGEN 22.00 ~.1, 21.96 % G1 +1·1 % NIST Traceable . NITRO~EN . . -Bal,a'nee, 

'. '.' 

CALIBRATION STANDARDS 

Type Lot 10 Cylinder No Concentration Expiration Date 

NTRM 08061313 CC254791 20.09% CAR80~1 DIOXIDEINITROGEN Jul 15, 2012 

NTRM 03060212 XC0243978 22.60% OXYGENINITROGEN Ju101,2011 

ANALYTICAL EQUIPMENT 

Instrument/Make/Model Analytical Principle Last Multipoint Calibration 

Siemens Ultramat 6E N1-NO-OB20 NDIR Jan 19, 2009 

Siemens SE BN805 Paramagnetic Jan 02, 2009 

Triad,pata Available Upon Request 

No~:_i ~-" 

(:::=~=;)l( al AN!/L,-~l Cr;[!l!2tc 

QA Approval 

Page 1 of 82-124165926_1 

15000 
lUqutb ijtccbitoIogp Qi:orporation 

Industry Leader in Specialty Gases, Equipment and Service 

Customer 

Date 

Delivery Receipt 

Gas Standard 

Final Analysis Date 

Expiration Date 

Cylinder Data 

Cylinder Serial Number: 

Cylinder Volume: 

Expiration Date: 

Analytical Data 

Certificate of Analysis 

- EPA PROTOCOL GAS -

Air Nova (Pennsauken, N J) 

February 23, 2010 

DR-27602 

7.00% C02, 12.0% OxygeniNitrogen - EPA PROTOCOL 

February 23, 2010 

February 23, 2013 

CC-233 16-1 

140 Cubic Feet 

February 23, 2013 

DO NOT USE BELOW 150 psig 

Cylinder Outlet: 

Cylinder Pressure: 

CGA 590 

20QQJ:>sig, 70°F 

EPA Protocol,. Section No. 2.2, Procedure G·I 

Reference StandardCs): 

GMISISRM: 

Cylinder Number: 

Concentration: 

Expiration Date: 

Replicate Concentrations 

Carbon Dioxide: 7,08% +/- 0,07% 

Oxygen: 11,9% +/- 0,11 % 

Nitrogen: Balance 

GMIS/GMIS 

CC-159026/CC-165377 

5.14% C02110.05% C02 

03/3 J /l ! - 04/06/11 

GMIS/GMIS 

CC-231332/CC-85458 

10.10% OxygenI20.97% 02INitrogen 

03/04111 - 04115111 

Certification Instrumentation 

Component: 

Make/Model: 

Serial Nllmpcr: 

Principal of Measurement: 

Last Calibration: 

Carbon Dioxide 

Agilenl7890A 

. CNI0736166 

TCD 

February 09, 2010 

Oxygen 

Servomex 244a 

1847 

Paramagnetic 

February 15,2010 

Analytical uncertainly and NIST Traceability are in compliance with EPA-600/R-971121. 

Certified by: 

Mike Duncan 

Unmatched Excellence 

2564 Pemberton Drive - Apopka, Florida 32703 - Phone (407)-292-:2990 - Fax (407)-29:2-3313 

- www.liquidtechcorp.com -
, 

\ 

Airgas. 

CERTIFICATE OF ANALYSIS 

Grade of Product: EPA Protocol 

Alrgas Specialty Gases 

600 Union Lindlng Road 

RiVlrton,l!IJ 08017 

(856) 829-7878 

Fax (8S6) 829-0571 

www.alrgis.com 

Part Number. E03NI65E15A1094 Reference Number: 82-124142222-1 

Cylinder Number: CC5693 Cylinder Volume" 154 CU.Ft. 

Laboratory: ASG - Riverton - NJ Cylinder Pressure" 2015 PSrG 

Analysis Date: Jun 23,2008 Valve Outlet: 590 

Expiration Date: Jun 23, 2011 

Certification performed in accordance wjlh "EPA Traceability Protocol (Sept. 1997)" using Ihe assay procedures lis led. Analylical Methodology does nol require correction for 

analytical Interferences. This cylinder hilS a lolal anaiylical uncertainty as slated below with a confidence level of 95%. There are no significant impurilies which allecl th<l use 

oflhis callbraUan mixture. All concenlrations are on a voJumal'lOlume basis unless olherwise noled. 

Do Not Use This Cylinder beloW 150 psig,l.e. 1 Mega Pasoal 

ANA: RESULTS 

Component Requested A,,, ~I Protocol 

Concentration Method 

CARBON DIOXIDE 12.50 % 12.38 % G1 

OXYGEN 22.00 % 22.03 % G1 . 

CALIBRATION STANDARDS 

I Type LotiO Cylinder No Concentration 

NTRM 03060212 XC024397B 22.60% OXYGEN/NITROGEN 

NTRM 04060437 XC0343168 19.84% CARBON DIOXIDE/NITROGEN 

ANALYTICAL EQUIPMENT 

I I I 

Siemens I NDIR 

;5~ I, 

Triad Data Available Upon Request 

Notes:02 CONCENTRATION CORRECTED FOR C02 

INTERFERENCE. 

C . Clvx:! ~'" oOe--

QA Approval 

Tot.11 Relative 

-!-/- 1 % NIST Traceable 

"'/-1% N[STTraceable 

Expiration Dale 

Ju101.2011 

May 15, 2012 

Last I Calibration 

J": ::. :::: Jun • 

'Page 1 of82-124142222-1 

15000 
Airgas .. 

00 

CERTIFICATE OF ANALYSIS 

Airgas Speclallv Gases 

500 Union l.ndlnu Rg.d 

Aiverton. NJ oaon 

Grade of Product: EPA Protocor::':.:::", 

www.airg.!s.eom 

Part Number: E02NI78E15A0346 Reference Number; 82-124093653-1 

Cylinder Number; XC0186948 

Laboratory: 

Analysis Date. 

ASG - Riverton - NJ 

Apr23,2007 

Expiration Date: Apr 23,2010 

Cylinder Volume: 

Cylinder Pressure; 

Valve Outret 

158 Cu.Ft. 

2015 PSJG 

580 

CertIfication performed In accordance witI'! "EPA Traceability Protocol (Sap!' 1997)" using the asuy procedures lisled. Analytical Methodology does not require correction for 

analytical interferences, This cylinder has a total analytical uncertainlY as slated below wfth a confidence revel of95%. There are no signfflcant impurities whioh affectlh. .. use 

oflhis calibraUon mixlura. All concentrations are on a volume/volume basis unless olherwl!e noled. 

Do Nol Use Tills Cyjlnder below 150 pslg.l.e. 1 Mega Pasoal 

. ANAU"flCAI. RESULTS 

Componant R'equesled 'Actual Protocol Total Relative 

Concentration Concentration Method Uncerialiiity. 

CARBON DIOXIDE 22.00 % 22.26'% G1 +/-1% NISTTraceable 

NITROGEN Balance 

CALIBRATION STANDARDS 

Type LotiO Cylinder No Concentration Expiration Date 

, NTRM 00060309 XC034300B 19.64%CARBON DIOXIDE/NITROGEN May 15, 2008 

ANALYTICAL EQUIPMENT 

Instrument/Make/Model Analytical Principle Last Multipoint Calibration 

I Nicolet 560 AOU9800406 CO/CO2 FTIR Apr 12, 2007 

Triad Data Available Upon Request 

Notes: ~ c-

:hCfu. ..-llet4.."-

QAApprovai 

Page 1 of 82-124093653-1 
Customer 

Date 

Delivery Receipt 

Gas Standard 

Final Analysis Date 

Expiration Date 

Component 

Balance Gas 

Analytical Data: 

LIQUID TECHNOLOGY CORPORATION 

"INDUSTRY LEADER IN SPECIALTY GASES" 

Certificate of Analysis 

- EPA PROTOCOL GAS -

** Recertification ** 

Air Nova (Pennsauken, NJ) 

June 03, 2010 

DR-2962I 

22.28% Carbon DioxidelNitrogen-EPA PROTOCOL 

May 28, 20lO 

May28,20l3 

Carbon Dioxide 

Nitrogen 

DO NOT USE BELOW 150 psig 

EPA Protocol, Section No. 2.2~~_~ 

/ . ~ ., 

Reported ConcentratIOns .. 

Carbon Dioxide: 21.7% +1- 0.21 % 

Reference Standards: 

SRM/GMIS, 

Cylinder Number: 

Concentration: 

Expiratil?n Date: 

Certification Instrumentation 

Component: 

Make/Model: 

Serial Number: 

Principal of Measurement: 

Last Calibration: 

Cylinder Data 

Cylinder Serial Number: 

Nitrogen: Balance 

OGMMr;IS'--------·--·--· . 

CC-115915 

19.44% C02/Nitrogen 

December 31, 20 [ 1 

Carbon Dioxide 

Agilent 7890A 

CNI0736166 

GC-TCD 

May21,2010 

Cylinder Outlet: 

Cylinder Volume: 136 Cubic Feet Cylinder Pre~sure: 

Expiration Date: June 03, 2013 

eGA 580 

1950 psig, 70°F 

Analytical Uncertainty and NIST Traceability are in compliance with EPA-600/R-97112L 

Certified by: 

Mike Duncan 

Original Data: 22.28% C02INitrogen (April 23, 2007) • Airgas: Riverton, NJ 08077 

"UNMATCHED EXCELLENCE" 

2564 PEMBERTON DRIVE ApOPKA, FLoRIDA 32703 - PHONE (407)·292·2990 FAX (407)-292·3313 

www liQUIDTECI-ICORP.COM 
I / 

t}J!l!f1lPRAXAIR Praxair Distribution Mid-Atlantic lLC 

145 Sillmersville Rood· Bethlehem, PA 18015 • Phone: 610.317.1608 • Fax: 610.758.8384 

"'!flOwer & Order 111/0rllloII0i/: 

POI WHSE SANFORD NC STORE 

1510 HAWKINS AVE 

SANFORD NC 27330 

Expiration Date: 

Cylinder Number: 

17.83 

21.36 

% 

% 

/),~No~"':<r: OOOOOOOTg~O 

o,,,,-~ N"",h.,,, 172937600 

(","","" I~ (j ~'''I"lJrr: 9557~5Nll 

}'pI/v",,·, 

• 4 1',,,,MmWc" 

/"";<1',,/><,; 

Ci'''I'ioJr So<' '" O",kl: 

fjl".I" p",~,,,,,, '" v.,/"''''', 

Cerflj1ed COlI:':'C":I'CU:I:'O::::":' _______ <>_>_"_"_"_>k_>_~_'_"_",,/w'O 

6130/2012 

CC116648 

CARBON DIOXIDE 

OXYGEN 

Analytical Uncertainly: 

± 1 % 

± 1 % 

Balance NITROGEN 

NO. "PO, • (NO); V.'ua. lor ftef ... e""" Only) 

CerrijicnfiollllljilflJrllffUII: Cerlifi'':iJlion Dale: 613012009 Term: 31;1 Mon.ths Expiralion Dale: 6/30;2012 

" Thl£ cyiH1dQ' wa, .. wried 3CCOlding to lh. 1991 ePA Tr.oo"U,l,ly Prol,.,.,i. <Iocumool ~ErA.sooJR-g11121. using proO<XlLO"e G1 

2 00 1)0\ ~.o l~i. ,landard ,t pr., .. ,[9 IS '0" lhan 150 rS1G 

,.j.lmlyfil:,d J)<lI"~ (R=R8ferellco Standard, Z=Zero Gas, C=G8S Candidllle) 

, ,Componenl' CARBON DIOXIDe 

ReqllOolOd Conca,,~.loon' 18 '4 

CoM,.d Co,""onl.ol"", 11-<>3 'l> 

In'l""llaN I.HA6' 

Malyl",_1 Mel'",d 

la .. Mu,I,,,,,:nl Cal,"'''''on: 

Fl'st A"oly.l. DolO: 

,. , R, 181 

Z: 0 

UOM: % 

R, 187 

Z: 0 

C. 11.04 

2 Compon"n" OXYGEN 

R.qu~'lO!<l e""",,"".ll"'" 

C.<1fliQ~ e,.,eenl,ol,"" 

In.l,umen! U •• d: 

Analylical Molhod. 

l""l Multiprnnl Colib!allOn' 

First Analysl. Oat.: 

, , " ~ .. " "00 " 0 

" 0 " 21 2~ 

SI':M~~'5 UL TP.AMlT SE stl: D2·~11 

NON·~I$prRSlV~ ,,,J'A~~EO 

6/1m2009 

Oal.: 

" 1784 Cane: 

" \1.84 Cone: 

" 13.r CO".: 

Mo.n Tesl Ass.y, 

10.~% 

21.;m% 

_W". 

" .. 17.83 

17,£!3 

1163% 

SIEMENS QXy,,v,T 5E SiN FI·ll, 

PNWAAGNETIC 

61312009 

Dolo: ~'24rI()Q9 

" 21.28 Cone: 21.38 

" ~1.3 Cone: 21-4 

" nU6 Conc' ZI J8 

Reterence Slandard TyJ'<i 

Ret Sld.CYilnclor,4 

Ref Sid. Cone .. 

~" CCIJ921~ 

flef. $ld. T"'ce.ble loSRM #: 

13,69% 

274~ 

Second Analyols Oala: 

" 0 " 0 

" 0 " 0 

" 0 " 0 

UOM.- "' 

Rer.,o""" Slandard Type. 

Rel Sid. Cyl,nde' ~ . 

Ref. Sid. CMC. 

"et Sid Traceablo'a SRM ~, 

. Second An.ly.roO.1o: 

" 0 " 0 

" 0 " 0 

" 0 0 0 

O.w 

" 0 Cone' 

" 0 Cone: 

" 0 Cone: 

Me.n Tul Assay: 

" " " 

GIlliS 

CC1(l.1il6 

nS7% 

,.., 

0<01.: 

0 Cone: 

0 Cone: 

0 Cone, 

612512000 

NI COla05E·AS 

AS "' 590 

2ooo""i 

"" 

o 

o 

o 

", 

o 

o 

o 

UOI,I' • Mo.nT .. 1A.··Y, 21 J8'~ UOM: % Mo.n Tost A.,oy' 0 % 

Analyzed by: Robin Morgan Certified by. rfK 1, /·01 

J 

IIIO,,,,,,I;ofl ""'M'''''~ horoin ha, b~n p,epared al \'<l'" ,oquesl by qu.li~ .. d """"". with;, GTS·W<llo:o I!tc. 'M>~" 'NO bo"""" iMIlllhe Informa'iOn I. aCCLO".la wilhln lho l,m;l. "Ilho analyi,",,1 

'''elhods employod a"d i, complolo 10 11'0 ""IMI of Ine .p~i~c analys •• pedo,",ed. WO mak" no WOJl1ml/ or :Of"".or>talion o.r<> lho .u'l.bll"~ ollho uS<) 01 lho ,nfotmQriCln lor alYj' purpose. The 

'olo<malo"" IS 011.,,,,, w~h (I .. ,,,,U."'Md"'9 IMal any uss or Ihe ",Ie,malio" is 81 ~,e sole di,,,,eUon a·,ei ,isk ollno u,er. In no evenl shalll~. I",bllily .1 GTS-Welco. Inc., .,,'''''' oul ~11M usa of lh. 

'''I",maloo'' con "'.,,'" M'eon ~xce.a In" 100 oslat.r .. ".~ fOf providing .uch ,nfO/mallCn. 
lLiquib \!Ccrbnologp <!Corporation 

Industry Leader in SpecIalty Gases, Equipment and SerVIce 

Certificate of Analysis 

Customer 

Date 

Delivery Receipt 

Gas Standard 

Final Analysis Date 

Expiration Date 

Component 

Balance Gas 

Analytical Data: 

- EPA PROTOCOL GAS -

Air Nova (Pennsauken, NJ) 

January 26, 2010 

DR-27309, 

4S0 - SOO ppm Carbon MonoxidelNitrogen - EPA PROTOCOL 

January 2S, 2010 

January 2S, 2013 

Carbon Monoxide 

Nitrogen 

DO NOT USE BELOW 150 p,ig 

EPA Protocol, Section No. 2.2, Procedure G-1 

Replicate Concentrations 

Carbon Monoxide: 486 ppm +1- 4,8 ppm 

Nitrogen: Balance 

Reference Standards: 

SRM/GMIS: 

Cylinder Number: 

Concentration: 

Expiration Date 

Certification Instrumentation 

Component: 

MakelM octel: 

Serial Number: 

Principal of Measurement: 

Last Calibration: 

Cylinder Data 

Cylinder Serial Number: 

Cylinder Volume: 

GMIS 

CC-2S IS49 

GMIS 

CC-2S0292 

267.38 ppm COlNitrogen 

November 01, 201 1 

S 1 I.S ppm COlNitrogen 

January OS, 2012 

Carbon Monoxide 

Nicolet - NEXUS 470 

AEP99000lS4 

FTIR 

January 11,2010 

CC-2S1891 

140 Cubic Feet 

Cylinder Outlet: eGA 3 SO 

Cylinder Pressure: 2000 psig, 70°F 

Analytical Uncertainty and NIST Traceab,ility are in compliance with EPA-6.00/R-971l21. 

Certified by: 

M;ke Duncan 

Unmatched Excellence 

2564 Pemberton Drive - Apopka, Florida 32703 - Phone (407)-292-2990 - Fax (407)-292-3313 

- www.liquidtechcorp.com-
Airgas .. 

CERTIFICATE OF ANALYSIS 

Grade of Product: EPA Protocol 

Airgas Specialty Gases 

BOO Union Landing Road 

Riverton, NJ 08071 

(856) 829-7878 

Fa~ (B56) 829-0571 

WWI'/,airgas.wm 

Part Number. E02NI99E15A0305 Reference Number: 82-124159539-1 

Cylinder Number: 8G9147178 Cylinder Volume: 144 Cu.Ft. 

Laboratory: ASG - Riverton - NJ Cylinder Pressure: 2015 PSIG 

Analysis Date: Dec 04, 2008 Valve Outlet: 350 

Expiration Date: Dec 04, 2011 

Certification parlormed in acoordancB with "cPA TracBabillty Proioool (Sept. 1997)" using the essay procedures lis led. Analyllcal Methodology does noi require correction lor 

analytical interferences. This cylinder has II (alai analytical uncertainly as stated b~lowwilh II confidence level 01 95%. There are no significant impurities which affeeltha use 

of lhis calibralion mi~lure. All concenlralions are on a volumelvoluma basis unless olherwise noled. 

Do Nol Use This Cylinder belOW 150 psig.l.e. 1 Mega Pascal 

ANAL,\ ''-'M RESULTS 

Componenl ~~tual , 

I 

CARBON MONOXIDE 950.0 PPM 935.7 PPM G1 

I I 

CALIBRATION STANDARDS 

Type lotiO II No Concentration 

NTRMplus 08060404 CC255339 1002 4PPM CARBON MONOXIDE/NITROGEN 

I I 

, Ullmm,'"':'>191 

Triad Dala Available Upon Request 

Notes: 

C . CV'j 1'0\ Q1z",CVQA Approval 

ANALYTICAL EQUIPMENT 

I I 

NDIR 

To", I 

I 

+/-1o/~ NIST Traceable 

I ;; Date 

Apr 15, 2012 

~,tI I 

Deo 03. 2006 

Page 1 of82-124159539-1 

#5000 
JUquO.l m:erbno{ogp QCorporation 

Customer 

Date 

Delivery Receipt 

Gas Standard 

Final Analysis Date 

Expiration Date 

Component 

Balance Gas 

Analytical Data: 

Industry Leader in Specialty Gases, Equipment and Servtce 

Certificate of Analysis 

- EPA PROTOCOL GAS -

Air Nova (Pennsauken, NJ) 

January 26, 2010 

DR-27309 

1200 ppm Carbon MonoxidelNitrogen - EPA PROTOCOL 

January 26, 2010 

January 26, 2013 

Carbon Monoxide 

Nitrogen 

DO NOT USE BELOW 150 psig 

EPA Protoco1, Section No. 2.2, Procedure G~l 

Replicate Concentrations 

Carbon Monoxide: 1204 ppm +/- 12 ppm 

Nitrogen: Balance 

Reference Standards: 

SRM/GMIS: 

Cylinder Number: 

Concentration: 

Expiration Date 

Certification Instrumentation 

GMIS 

CC-251970. 

1003.2 ppm COlNitrogen 

November 12, 2010 

Component: Carbon Monoxide 

Make/Model: Nicolet - NEXUS 470 

Serial Number: AEP99000i54 

Principal of Measurement FTIR 

Last Calibration: January 11, 2010 

Cylinder Data 

GMIS 

CC-166608 

1539.7 ppm COlNitrogen 

January 12,2012 

Cylinder Serial Number: CC-117928 

140 Cubic Feet 

Cylinder Outlet: CGA 350 

Cylinder Volume: Cylinder Pressure: 2000 psig, 70°F 

Analytical Uncertainty and NIST Traceability are in compliance with EPA-iiOOIR-971121. 

Certified by: 

. Mike Duncan 

Unmatched Excellence 

25f'4 Pemberton Drive .... Apopka, F(orlda 327(}3 - Phone (4Q7J·Z82-2990 - Fax (407)-292-3313 

.... www.llquidtechcorp.com-
Airgas, 

CERTIFICATE OF ANALYSIS 

Grade of Product: EPA Protocol 

Air!l3S Specially Gases 

600 Union landin~ Roa~ 

Riverton. NJ 08071 

(B56) 829-7378 

fa> (856) 829·D571 

WWW,alruas_com 

Part Number: E02NI99E15AOO63 Reference Number: 82-124186914-1 

Cylinder Number: CC45673 Cylinder Volume: 144 Cu_Ft. 

Laboratory: ASG - Riverton - NJ Cylinder Pressure: 2015 PSIG 

Analysis Date: Aug 12, 2009 Valve Outlet 350 

Expiration Date: Aug 12, 2012 

Certification performed j~ ~ccordance with "EPA Traceability Protocol (Sept 1997)" using the assay procedures listed Analytical Methodology does not require correction for 

analytical interferences. This cylinder has a lolal analytical uncertainty as slated below with a confidence level or 95%. There are no signi[lcant jmpurilie~ which allect the use 

01 this c~libralion mi~lure. All concenlr6lions ale on a volumaNolumo basis unless otherwise noted. 

00 Not Use This Cylinder below 150 pSlg.i.e. 1 Mega Pascal 

ANALYTICAL RESULTS 

Component Requested Actual Protocol 

Concentration Concentration Method 

CARBON MONOXIDE 2250 PPM 2246 PPM G1 

NITROGEN Balance 

CALIBRATION STANDARDS 

Type LotiO Cylinder No Concentration 

NTRMpru$ 08060404 CC255339 

InstrumentlMake/Model 

Siemens 6E U~ramat L9 0191 

Triad Data Available Upon Request 

Notes: 

C "!2-.-v~4? , QA Approval 

Page 1 of 82-124166914_1 

15000 

1002.4PPM CARBON MONOXIDE/NITROGEi~ 

ANALYTICAL EQUIPMENT 

Analytical Principle 

NDIR 

\) . 

Total Relative 

Uncertainty ~( +1-1 % NIST Traceable , .' . i. ~ 

, , 

Expiration Date 

Apr 15, 2012 

Last Multipoint Calibration 

Aug 08, 2009 

" 
Airgas. 

CERT,IFICATE OF ANALYSIS 

Grade of Product: EPA Protocol 

Airllas Specialty Gases 

600 U"io" Landing Road 

Riverton. NJ 00077 

(856) 829-7878 

Part Number: E02NI99E15A3865 Reference Number: 82-124195280-1 Fax (1].56) 829-0571 

Cylinder Number: GG87198 Cylinder Volume: 144 GU,Ft. www.airlja.com 

Laboratory: ASG - Riverton - NJ Cylinder Pressure: 2015 PSIG 

Analysis Date: Oct 27,2009 Valve Outlel: 660 

Expiration Date: Oc127,2011 

Certification performed in accordance with "EPA Traceability Protocol (Sept. 1997)" using the assay procedures listed. Analytical Methodology does nol require correction ror 

analytical interferences. This cylinder has a tolal analytical uncertainly as slated below with a confidence level of 95%. There are no signiflcanllmpurities which affecllhe use 

of this calibration mixture. All concentrations era on e volume/volume basis unless othelWlse notad, 

Component 

NITRIC OXIDE 

NITROGEN 

Total oxides of nitrogen 

Type Lot 10 Cylinder No 

NTRM 09060330 CC286961 

, 

Do Not Usa Tilis Cylinder below 150 psig.i.e. 1 Mega Pascal 

ANALYTICAL RESULTS 

Requested 

Concentration 

125.0 PPM 

Balance 

Actual 

Concentration 

122,1 PPM 

122.5 PPM 

Protocol 

Method 

G1 

CALIBRATION STANDARDS 

Concentration 

250.6PPM NITRIC OXIDE/NITROGEN 

ANALYTICAL EQUIPMENT 

Total Relative 

Uncertainty 

+1-1% NIST Traceable 

For Reference Only 

Expiration Date 

Feb 01, 2011 

Instrument/Make/Model Analytical Principle Last Multipoint Calibration 

Nicolel6700 AHR0801933 NO/NOx rTlR Oct 26 2009 I 

~----------------------------------------------------------------------------'-------------------- ~ Availabl. Upon Requ.st~ , 

C I.e,! I r .c!'''-:'\.~ (].t:e~ QAl\p oval 

Page 1 Qf82-124195280-1 
Airgas. "; 

<~"" /,,~.~, 

Part Number. 

CERTIFICATE OF ANALYSIS 

Grad~,;9f Product: ~PA Protocol -.-+ 

E02NI99E15A0237 Reference Number. 82-124135439-1 

Cylinder Number: CC91627 Cylinder Volume: 144 Cu.Ft 

Laboratory: ASG - Riverton - NJ Cylinder Pressure; 2015 PSIG 

Analysis Date: May 07, 2008 Valve Outlet: 660 

AI1'{I8S SpecIalty Gases 

600 Union landing Road 

Ai •• rlDn, NJ 00077 

(856) 629-7678 

Fa~ (856) 829·0571 

www.ail1JiI..l.com 

Expiration Date: May 07, 2010 ~-f' 

==========~~~~==========~, Ce,(mcalion performed in accoroance with "EPA Traceability Protocol (Sept. 1997)" using the assay procedures listed, Analytical MethodO,'09y ~oes not requ,'h' ~,rreClhion for 4.::.i: . analylicallnlerferences. ThiS cylinder has a loial analytical uncertainty as slaled below with a conndence leVf.l1 of95%. There are no slgni Icanllmpurilles wh c a ectt e use """ >,~ 

oJ this calibration mixture. All concentralions are on a volume/volume basis unless otherwise noled, 

00 NOI Use This Cylinder below 150 pSig.l.e. 1 Mega Pascal 

Component 

NITRIC OXIDE 

NITROGEN 

Total oxides of mtrogen 

Type LotiO 

NTRM 06060234 

Instrument/Make/Model 

Nicolel470AEP0000416 NO 

Cylinder No 

CC207442 

Triad Data Available Upon Request 

Notes' 

(f"L..::; "3iF;: 

QA Approval 

ANALYTICAL RESULTS 

Requested 

Concentration 

2300 PPM 

Balance 

Actual 

Concentration 

232.6 PPM 

2333 PPM 

Protocol 

Method 

G1 

CALIBRATION STANDARDS 

Concentration 

2S7.0PPM NITRIC OXIDE/NITROGEN 

ANALYTICAL EQUIPMENT 

Analytical Principle 

FTIR 

Total Relative 

Uncertainity 

+/-1% NJSTTraceabie 

For Reference Only 

Expiration Date 

Jan 01, 2010 

Last Multipoint Calibration 

May OS, 2008 

, 

Page 1 of82-124136439-1 

15000 
lUquil:J m:crbnologp <!Corporation 

Industry Leader In Specialty Gases, Equipment and Service 

Customer 

Date 

Delivery Receipt 

Gas Standard 

Final Analysis Date 

Expiration DaL 

Analytical Data 

Certificate of Analysis 

- EPA PROTOCOL GAS -

Air Nova (Pennsauken, NJ) 

March 25, 2010 

DR-27903 

50.0 ppm Sulfur DioxidelNitrogen - EPA PROTOCOL 

March 25, 2010 

March 25, 2012 

DO NOT USE BELOW 150 psig 

EPA Protocol, Section No. 2.2, Procedure G~ 1 

Reference Standard0t 

SRM/GMIS, 

Cylinder Number: 

Concenlration: . 

Expiration Date: 

Replicate Concentrations 

Sulfur Dioxide: 50.6 ppm +/- 0.50 ppm 

Nitrogen: Balance 

GMIS 

CC-231494 

50.87 ppm S02INitrogen 

January 28,2011 

Certification I.pstrumentation 

Component: 

Make/Model: 

Serial Number: 

Principal of M';:<i nrement: 

Last Calibration 

Cylinder Data 

Cylinder Number: 

Cylinder Outlet: 

Expiration Date: 

Sulfur Dioxide 

Nicolet - NEXUS 470 

AEP9900015'l. 

FTIR 

March 10,2010 

EB-0023444 

CGA 660 

Match 25,2012 

Cylinder Volume: 

Cylinder Pressure: 

140 Cubic Feet 

2000 psig, 70°F 

Analytical uncertainty and NIST Traceability are in compliance with EPA-600/R-971l21. 

Certified by: 

Mike Duncan 

Unmatched Excellence 

2564 Pemberton Drive - Apopka, Florida 32703 - Phone {407}-292-2990 _ Fax {407}-292-3313 

- WWW.liquidtl3chcorp.com-
liraas. 

CERTIFICATE OF ANALYSIS 

Grade of Product: EPA Protocol 

Alrgas Spe£ially Gases 

600 Union landing Road 

Riverton. NJ 06077 

(856)829·1a78 

fa>: (855) 829-0571 

lY\V\v .• iraas.com 

Part Number: E02NI99E15A0239 Reference Number: 82-124189610-1 

Cylinder Number: CC281332 Cylinder Volume: 144 CU.Ft. 

Laboratory: ASG - Riverton - NJ Cylinder Pressure: 2015 PSIG 

Analysis Date: Sep 03, 2009 Valve Outlet: 660 

Expiration Date: Sep 03, 2011 

Certification performed in accordance with "EPA Traceability Protocol (Sept. 1997)" using the IIssay procedures listed. Analytical Methodology does not require correction for 

analytical interferences. T~is cylinder has a tOlal analytical uncertainty as ~Ialed belC)Wwllh a conndence level of95%. There are 00 significant impurities which aflecttha use 

of this calibration mixture. All concentrallons are on a volume/volUme basis unless otheJWise noted. 

ComponE!nt 

SULFUR DIOXIDE 

NITROGEN 

Type Lot 10 Cylinder No 

NTRM 08061502 CC254449 

InstrumenVMake/Model 

Nicolet 6700 AHR0801933 S02 

Triad Data Available Upon Request 

Notes: 

C~~~(~- QA Approval 

00 Not Use This Cylinder below 150 psig.i.e. 1 Mega Pascal 

ANALYTICAL RESULTS 

Requested Actual Protocol Total Relative 

Concentration Concentration Method Uncertainty 

90.00 PPM (19.90 PPM Gj +/-1% N1STTraceabie 

Balance 

CALIBRATION STANDARDS 

Concentration ExpiratIOn Date 

94.67PPM SULFUR DIOXIDE/NITROGEN Oct 15, 2012 

ANALYTICAL EQUIPMENT 

Analytical Principle Last Multipoint Calibration 

FTIR AU9 19, 2009 

Page 1 Of 82-124189610_1 

#5000 
1Liquib \!recbnologp ({orporation 

Industry Leader in Specialty Gases, Equipment and Service 

Customer 

Date 

Delivery Re'£_:.mn 

Gas Standard 

Final Analysis Date 

Expiration Date 

Analytical Data 

Certificate of Analysis 

- EPA PROTOCOL GAS -

Air Nova (Pennsauken, NJ) 

March 25, 20 I 0 

DR-27903 

225 ppm Sulfur DioxidelNitrogen - EPA PROTOCOL 

March 24, 2010 

March 24, 2012 

DO NOT USE BELOW 150 psig 

EPA Protocol, Section No. 2.2. Procedure G-I 

Reference StaIldardCs); 

SRMiGMIS: 

Cylinder Numb~r: 

Concentration: 

Expiration Date. 

Certification Instrumentation 

Component: 

Make/Model: 

Serial Number: 

Principal of Measurement: 

Last Calibration: 

Cylinder Data 

Cylinder Number: 

Cylinder Outlet: 

Expiration Date: 

Replicate Concentrations 

Sulfur Dioxide: 222 ppm +/~ 2.2 ppm 

Nitrogen: Balance 

GMIS 

CC-233823 

GMIS 

CC-lS4202 

98.02 ppm S02INitrogen 

January 24, 2012 

409.1 ppm S02INitrogen 

March 15,2012 

Sulfur Dioxide 

Nicolet - NEXUS 470 

AEP99000154 

FTIR 

March 10,2010 

EB-OOI5920 

CGA660 

March 24, 2012 

Cylinder Volume: 

Cylinder Pressure: 

140 Cubic Feet 

2000 psig, 70'F 

Analytical uncortainty and NIST Traceability are in compliance with EPA-600/R-971121, 

Certified by: 

Mike Duncan 

Unmatched Excellence 

2564 Pemberton Drive - Apopka, Florida 32703 - Phone (407)-292-2990 - Fax (407)-292-3313 

- www.liquldtechcorp.com-
1Liquib 'Qrecbnolo~p ([orporation 

Industry Leader in Specialty Gases, Equipment and Service 

Customer 

Date 

Delivery Receipt 

Gas Standard 

Final Analysis Date 

Expiration Date 

Analytical Dat~ 

Certificate of Analysis 

- EPA PROTOCOL GAS -

Air Nova (Pennsauken, NJ) 

March 25, 20 I 0 

DR-27903 

450 ppm Sulfur DioxidelNitrogen - EPA PROTOCOL 

March 24, 2010 

March 24, 2012 

DO NOT USE BELOW 150 psig 

EPA Protocol, Section No. 2.2, Procedure o·} 

Reference StandardCs): 

SRMiOMIS: 

Cylinder Number: 

Concentration: 

Expiration Date: 

Certification Instrumentation 

Component: 

Make/Model; 

Serial Number: 

Principal of Measurement: 

Last Calibration: 

Cylinder Data 

Cylinder Ntonber: 

Cylinder Outlet: 

Expiration Date: 

Replicate Concentrations 

Sulfur Dioxide: 443 ppm +1- 4.4 ppm 

Nitrogen: Balance 

OMIS 

CC-184202 

GMIS 

CC-115955 

409.1 ppm S02INitrogen 

March 15,2012 

758.3 ppm S02INitrogen 

May 05, 201 J 

Sulfur Dioxide 

Nicolet· NEXUS 470 

AEP99000154 

FTIR 

March 10,2010 

CC-23 1248 

CGA 660 

March 24, 2012 

Cylinder Volume: 

Cylinder Pressure: 

140 Cubic Feet 

2000 psig, 70°F 

Analytical uncertainty and NIST Traceability are in compliance with EPA-600/R-971I21. 

Certified by: 

Mike Duncan 

Unmatched Excellence 

2564 Pemberton Drive - APOPka, Florida 32703 - Phone (407)-292-2990 _ Fax (407)-292-3313 

. - www.flquidtechcorp.com _ 
lUquib \!rccbnologp QCorporation 

Industry Leader in Specialty Gases, EqUipment and Service 

Customer 

Date 

Delivery Recelvt 

Gas Standard 

Final Analysis Date 

Expiration Date 

Component 

Balance Gas 

Certificate of Analysis 

- EPA PROTOCOL GAS -

Air Nova (Penhsauken, NJ) 

January 18,2010 

DR-27270 

5.00 ppm Propane/Air - EPA PROTOCOL 

January 18,2010 

January 18,2013 

Propane 

Air 

Analytical Data: . DO NOT USE BELOW 150 psig 

EPA Protocol, Section No. 2.2, Procedure 0-1 

Reference Standards: 

SRM/GMIS: 

Cylinder Number: 

Reported Concentrations 

Propane: 4.88 ppm +/- 0.04 ppm 

Air: Balance 

GMIS 

CC-166066 

GMIS 

CC-165367 

Concentration: 

Expiration Date: 

3.05 ppm PropanelNitrogen 

October 02, 2010 

19.92 ppm Propane/Nitrogen 

October 02, 2010 

Certification Instrumentation 

Component Propane 

Malee/Model: Agilent 7890A 

Serial Number: CNI0736166 

Principal of Measurement: GC-FID 

Last Calibration: January 11, 20 I 0 

Cylinder Data 

Cylinder Serial Number: 

Cylinder Volume: 

EB-0019898 

140 Cubic Feet 

Cylinder Outlet 

Cylinder Pressure: 

CGA 590 

2000 psig, 70°F 

Analytical Uncertainty and NIST Traceability are in compliance with EPA-600/R-97/121. 

Certified by: 

Mike Duncan 

Unmatched Excellence 

2564 Pemberton Drive - Apopka, Florida 32703 - Phone (407)-292_2990 - Fax (407)-292-3313 

- www.liquldtechcorp.com-
( 

Airgas. 

CERTIFICATE OF ANALYSIS 

Grade of Product: EPA Protocol 

Airgas SpetiaJly Gases 

600 Union Landing RD.d 

Riv,rton, J>lJ 08077 

(856)829-7878 

F;)~ (856) 829-0571 

www ... gas.com 

Part Number: E02AI99E15A 1486 Reference Number: 82-124188616·1 

Cylinder Number: XCOO23688 Cylinder Volume: 146 CLI.Ft. 

Laboratory: ASG - Riverton - NJ Cylinder Pressure: 2015 PS1G 

Analysis Date: Aug 25, 2009 Valve Outlet: 590 

Expiration Date: Aug 25, 2012 

Certificalion per/ormed in acoord~nce with "EPA Troceabillly Protocol (Sept. 1997)"1.I5In9 the assay procedures listed, Analytical Methodology does nol require correction for 

analytical int9rfere~ces_ This cylinder has a lotal analytical uncertainly as slated below wilh a conndsnce level or 95%. Ther", ~re no signirlcant impurities which affect Ihe use 

or this calibration mixlure. All concentralions are on a volume/volume besis unless olherwi!EI noled. 

Do Nol Use This Cylinder below 150 psig.l.e. 1 Mega Pascal 

ANALYTICAL RESULTS 

Component Requested Actual Protocol Total Relative 

Concentration Concentration Method Uncertainty 

PROPANE 9.000 PPM 9.099 PPM G1 +/-1% NIST Traceable 

Air Balance 

CALIBRATION STANDARDS 

Type LotlD Cylinder No Concentration Expiration Date 

NTRM 06061410 CC20S963 9.49PPM PROPANE/AIR Oct 02, 2010 

ANALYTICAL EQUIPMENT 

InstrumentiMakefModel Analytical Principle Last Multipoint Calibration 

Nicole1470 AEP0000416 C3H8 FTIR Aug 20, 2009 

Triad ta Available Upon Request 

Not s: 

-QA-Appfoval 

Pilge 1 of82·1241811616·1 

15000 
J'Liquib m:ccbnologp QCorporation 

Industry Leader in Specialty Gases, Equipment and Service 

Customer 

Date 

Delivery Receipt 

Gas Standard 

Final Analysis Datf: 

Expiration Date 

Component 

Balance Gas 

Analytical Data: 

Ce11ificate of Analysis 

- EPA PROTOCOL GAS -

Air Nova (PelUlSClUken, NJ) 

January 18, 2010 

DR-27270 

18.0 ppm Propane/Air - EPA PROTOCOL 

January 18,2010 

January 18,2013 

Propane 

Air 

DO NOT USE BELOW 150 psig 

EPA Protocol, Section No. 2.2, Procedure G·l 

Reference Standards: 

SRM/GMIS: 

Cylinder Number: 

Concentration: 

Expiration Date: 

Certification Instrumentation 

Reported Concentrations 

Propane: 17,4 ppm +/- 0,17 ppm 

Air: Balance 

GMIS 

CC-166066 

3.05 ppm PropanelNitrogen 

October 02, 2010 

GMIS 

CC-165367 

19.92 ppm Propaneli."Jitrogen 

October 02, 2010 

Component: Propane 

Make/Model: Agilent 7890A 

Serial Number: CN10736166 

Principal of Measurement: GC-FID 

Last Calibration: January 11, 20ID 

Cylinder Data 

Cylinder Serial Number: 

Cylinder Volume: 

EB-0019899 

140 Cubic Feet 

Cylinder Outlet: CGA 590 

Cylinder Pressure: 2000 psig, 70°F 

Analytical Uncertainty and NIST Traceability are in compliance with EPA-600/R-971121. 

Certified by: 

Mike Duncan 

Unmatched Excellence 

2564 Pemberton Drive - Apopka, Florida 32703 - Phone (407)-292-2990 - Fax (407)-292-3313 

- www.flqu/dtechcorp.com -
PrOJ 3333 

NOx Converter Test 

Outlet NOx Trailer - 2 

Step 1. 

Step 2. 

Step 3. 

Step 4. 

Step 5. 

Step 6. 

Step 7. 

AirNova, Inc. 

NOx Converter Effeciency Test 

Date 

Analyzer ID 

Analyst 

Range 

Cal. Standard 

April 12, 2010 

TECO Model 10 

Chemilumlnescent 

KZ 

502.9 

502.9 

Verify that all tubing is properly connected and securely fastened 

ppmV Nitric Oxide 

Adjust the NOx analyzer to the correct span gas concentration and 

record the response. 

Turn on oxygen (zero air) flow and adjust to blend the NO span gas 

and oxygen to dilute the span concentration by 10% of the span gas 

value. (example = 90.0 ppmV NO reduced by 10% is 81.0 ppmV NO,) 

Record the response. 

Turn on the TEeO 100B NOx Ozonator voltage, and increase the voltage 

until the analyzers NO response is 20% of the span gas value. (example20% of 90.0 ppmV NO is 18.0 ppmV NO), Record the response. 

Turn the NOx analyzer from the NO mode to NOx mode, Allow for a 

stable response by the NOx analyzer. and record the concentration_ 

Turn off the TECO 1008 NOx Ozonator voltage. and allow for a stable 

response by the NOx analyzer. Record the concentration. 

Calculate the NOx converter effeciency by the following equation: 

STEP 5 - STEP 4 X 100% = % Converter Effeciency 

STEP 6 - STEP 4 

OK 

502.9 

450,2 

99.3 

444.5 

449.6 

98.5 

NOx Converter Effeciency must be > 90 % (SOURCE: 40CFR. Part 60, Appendix A, Method 20, Sec. 3.1) 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

% Effeciency 
Proj 3333 

NOx Converter Test 

Rosemont NOx Trailer - 1 

Step 1. 

Step 2. 

Step 3. 

Slep4. 

Step 5. 

Step 6. 

Step 7 

AirNova, Inc. 

NOx Converter Effeciency Test 

Date 

Analyzer ID 

Analyst 

Range 

Cal. Standard 

April 20, 2010 

Rosemont NOx 

Chemiluminescent 

LDK 

232.6 

232.6 

Verify that all tubing is properly connected and securely fastened 

ppmV Nitric Oxide 

Adjust the NOx analyzer to the correct span gas concentration and 

record the response. 

Turn on oxygen (zero air) flow and adjust to blend the NO span gas 

and oxygen 10 dilute the span concentration by 10% of the span gas 

value. (example = 90.0 ppmV NO reduced by 10% is 81.0 ppmV NO.) 

Record the response. 

Turn on the TEeO 1008 NOx Ozonator voltage, and increase the voltage 

until the analyzers NO response is 20% of the span gas value. (example20% of90.0 ppmV NO is 18.0 ppmV NO). Record Ihe response. 

Turn the NOx analyzer from the NO mode to NOx mode. Allow for a 

stable response by the NOx analyzer, and record the concentration. 

Turn off the TEeO 100B NOx Ozonator voltage, and allow for a stable 

response by the NOx analyzer. Record the concentration 

Calculate the NOx converter effeciency by the following equation: 

STEP 5 - STEP 4 X 100% = % Converter Effeciency 

STEP 6 - STEP 4 

OK 

232.6 

207.8 

45_7 

2042 

207.7 

97.8 

NOx Converter Effeciency must be > 90 % (SOURCE: 40CFR, Part 60, Appendix A, Method 20, Sec. 3_1) 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

% Effeciency 
Proj 3333 

NOx Converter Test 

Rosemont NOx Trailer - 1 

Step 1. 

Step 2. 

Step 3. 

Step 4. 

Step 5. 

Step 6. 

Step 7 

AirNova, Inc. 

NOx Converter Effeciency Test 

Date 

Analyzer 10 

Analyst 

Range 

Cal. Standard 

April 15, 2010 

Rosemont NOx 

Chemiluillinescent 

LDK 

232.6 

232.6 

Verify that all tubing is properly connected and securely fastened 

PPIllV Nitric Oxide 

Adjust the NOx analyzer to the correct span gas concentration and 

record the response. 

Turn on oxygen (zero air) flow and adjust to blend the NO span gas 

and oxygen to dilute the span concentration by 10% of the span gas 

value. (example = 90.0 ppmV NO reduced by 10% is 81.0 PPIllV NO.) 

Record the response. 

Turn on the TECO 100B NOx Ozonator voltage, and increase the voltage 

until the analyzers NO response is 20% of the span gas value. (example20% of 90.0 ppmV NO is 18.0 ppmV NO). Record the response. 

Turn the NOx analyzer from the NO mode to NOx mode. Allow for a 

stable response by the NOx analyzer, and record the concentratIon. 

Turn off the TECO 100B NOx Ozonator voltage, and allow for a stable 

response by the NOx analyzer. Record the concentration. 

Calculate the NOx converter effeciency by the following equation: 

STEP 5 - STEP 4 X 100% = % Converter Effeciency 

STEP 6 - STEP 4 

OK 

232.6 

208.4 

46.7 

205.9 

208.7 

98.3 

NOx Converter Effeciency must be ;> 90 % (SOURCE: 40CFR, Part 60, Appendix A, Method 20, Sec. 3.1) 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

% Effeciency 
Proj 3333 

NOx Converter Test 

Outlet NOx Trailer - 2 

Step 1 

Step 2 

Step 3. 

Step 4 

Step 5 

Step 6. 

Step 7. 

AirNova, Inc. 

NOx Converter Effeciency Test 

Date 

Analyzer 10 

Analyst 

Range 

Cal. Standard 

April 19, 2010 

TEeo Model 10 

Chemiluminescent 

MDD 

450.9 

450.9 

Verify that all tubing is properly connected and securely fastened 

ppmV Nitric Oxide 

Adjust the NOx analyzer to the correct span gas concentration and 

record the response. 

Turn on oxygen (zero air) flow and adjust to blend the NO span gas 

and oxygen to dilute the span concentration by 10% of the span gas 

value. (example = 90.0 ppmV NO reduced by 10% IS 81.0 ppmV NO.) 

Record the response. 

Turn on the TEeO 1008 NOx Ozonator voltage, and increase the voltage 

until the analyzers NO response is 20% of the span gas value. (example20% of 90.0 ppmV NO is 18.0 ppmV NO). Record the response. 

Turn the NOx analyzer from the NO mode to NOx mode. Allow for a 

stable response by the NOx analyzer, and record the concentration. 

Turn off the TEeO 1008 NOx Ozonator voltage, and allow for a stable 

response by the NOx analyzer. Record the concentration. 

Calculate the NOx converter effeciency by the following equation: 

STEP 5 - STEP 4 X 100% = % Converter Effeciency 

STEP 6 - STEP 4 

OK 

450.9 

403.8 

89.3 

399.1 

402.9 

98.8 

NOx Converter Effeciency must be > 90 % (SOURCE: 40CFR, Part 60, Appendix A, Method 20, Sec. 3.1) 

INPUT 

INPUT 

INPUT 

INPUT 

INPUT 

% Effeciency 
Reference 

Point 

1 

2 

3 

4 

Source 

Ice Water 

BoiJing Water 

Very Hot Oil Bath 

Ambient Temp. 

AirNova, Inc. 

Pitot Thermocouple 

Calibration data 

Date. 

Thermocouple 1.0. : 

Probe Length: 

Calibrator 

Ambient Temp,(F): 

Barometric Pressure (" Hg): 

Reference Thermometer: 

Ref. Thermometer 

Temp,(F) 

37 

207 

358 

62 

Average Temp. Change: 

Thermocouple 

Temp,(F) 

35 

209 

360 

61 

Temperature Difference must be < 1.5 % 

Signature: , 

/(~J.C{UL 

'11/17/09 

AN-U5A 

5 Foot 

KA 

62 

30.10 

ASTM-2F 

Temperature 

Diff, (%) 

0.4% 

0.3% 

0.2% 

0.2% 

0.3% 
. : ~ ; ~ " . . . . . . . . . . . ' ....... ' . 

........ • 0. A.- rNova. I . ...•••••... _ n c . 

••• • • • • • • •• '" ....... ' 

......... , ~ . . . " . Type 5 Pitot Tube 

Dimensional Specification Verification Form 

Pitot No. 

Calibrator 

Date II /0 / rr'I' . , 

Verify the following criteria and check all that apply 

1) Face opening plane perpendicular to the transverse axis? ,~ 

'.--------- 2) Face-opening plane parallel to the logitudinal axis? __ ~ 

.:--. 

3) Are Legs A & B of equal length and are centerlines coincident? __ _ 

If all the above criteria are met, a pitot coeffecient of 0.84 may be assigned to 

the respective pitot tube. If one of the following criteria above is not met, the 

pitottube must be calibrated in a wind tunnel. 

Recommended Dimensions 

4) Diameter of pitot tubing? (Dt) = ,375' in. (0.1875 < Dt < 0.375) 

5) Dimensions of Pa = ·5t)(;> In. PaiDt = i. 3 ) (1.05 < Dt < 1.50) 

6) Dimensions of Pb = ,5" 0 in. Pb/Dt = /,3 7 (1.05 < Dt < 1.50) 

rRUS'\lE~$( I' ,. 

Tun Al($ .lB2j_. 

t--o::;[~Q-f . nA"($ . 

W' 

............. 

.... O~._ -E' ,~! ±-;;:-$~·=F'·.I ::: ...... ....... d ~ _ I, ••••• . .. _. _ . 

........... 

" 

-E-. ,'" Er-' 
Reference 

Point 

1 

2 

3 

4 

Source 

Ice Water 

BOiling Water 

Very Hot Oil Bath 

Ambient Temp. 

AirNova, Inc. 

Pitot Thermocouple 

Calibration data 

Date: 

Thermocouple 1.0. : 

Probe Length: 

Calibrator 

Ambient Temp,(F): 

Barometric Pressure (" Hg): 

Reference Thermometer: 

Ref. Thermometer 

Temp,(F) 

34 

210 

358 

62 

Average Temp. Change: 

Thermocouple 

Temp,(F) 

35 

210 

360 

61 

Temperature Difference must be <: 1.5 % 

Signature: /t' ~ {, atL-

'11117109 

AN-U5E 

5 Foot 

KA 

62 

30,10 

ASTM-2F 

Temperature 

Dill, (%) 

0.2% 

0.0% 

0.2% 

0.2% 

0.1% 

Date: J( I, 7/0<:'; 
· . . . . . . · ..... . ~ ....... ~. 

;'::;;:::::~ Ai rNova, Inc . • • • • • • • • • •• . . . . . . . . .. ' 

....... .' . · '. . . . : Type S Pitot Tube 

Dimensional Specification Verification Form 

Pitot No. 

Catibrator 

Date JI/17/0 f , 

Verify the following criteria and check all that appty 

1) Face opening plane perpendicular to the transverse axis? _---- __ 

2) Face-opening plane parallel to the logitudinal axis? __ .------- _ 

3) Are Legs A & B of equal length and are centerlines coincident? 

If all the above criteria are met, a pitot coeffecient of 0.84 may be assigned to 

the respective pitot tube. If one of the following criteria above is not met, the 

pitot tube must be calibrated in a wind tunnel. 

Recommended Dimensions 

4) Diameter of pitot tubing? (Dt) = • 3?s in. 

5) Dimensions of Pa = . 712- in. PaiDt = 1.37 (1.05 < Dt < 1.50) 

6) DimensionsofPb= (51.). in. Pb/Dt = /' J"7 (1.05 < Dt < 1.50) 

ra~~!iVE~SE [' i 

rUle ~~lS • 

.... " ....... r ~ .... "'~ . 

lE923-· ~Q::;I~Q-l . I'l~KES • 

" 

... ....... , 

.-&==.-.,.-, E---y-' 
Reference 

Point 

1 

2 

3 

4 

Source 

Ice Water 

Boiling Water 

Very Hot Oil Bath 

Ambient Temp. 

AirN ova, Inc. 

Pitot Thermocouple 

Calibration data 

Date: 

Thermocouple J.D. : 

Probe Length: 

Calibrator 

Ambient Temp.(F): 

Barometric Pressure (It Hg): 

Reference Thermometer: 

Ref. Thermometer 

Temp,(F) 

34 

208 

351 

62 

Average Temp. Change: 

Thermocouple 

Temp.(F) 

32 

209 

352 

62 

Temperature Difference must be < 1.5 % 

'11/17/09 

AN-50 

5 Foot 

KA 

62 

30.10 

ASTM-2F 

Temperature 

Dill. (%) 

0.4% 

0.1% 

0.1% 

0.0% 

0.2% 

Date: 
- .- ' . , -, - - ...... , - ........ --

~-;;:;:::::~ AirNova, Inc. -, ........ - - -....... --

- ...... ' - - , , - Type S Pitot Tube - . . . - Dimensional Specification Verification Form 

Pitot No. 

Calibrator 

Date Ii ((lltrr 

Verify the following criteria and check all that apply 

1) Face opening plane perpendicular to the transverse axis? __ -_-

2) Face-opening plane parallel to the logiludinal axis? _...:-----::.. 

3) Are Legs A & B of equallen'gth and are centerlines coincident? ~. 

If all the above criteria are met, a pitot coeflecient of 0.84 may be assigned to 

the respective pitot tube. If one of the following criteria above is not met, the 

pitot tube must be calibrated in a wind tunnel. 

Recommended Dimensions 

4) Diameter of pitot tubing? (Dt) = • J 75in. (0.1875 < Dt < 0.375) 

5) Dimensions of Pa = ·:fI /) in. PalOt = /-3(" (1.05 < Dt < 1.50) 

6) Dimensions of Pb = ..-5'/1> in. PblDt = / • ..Jt. (1.05 < Dt < 1 50) 

Tft~UVERH I' I lUI! 1.~4S .lE921-· t--0::;r~Q-I _ PlAII($ . 

w' 

All ....... ' 

",,".~.--tf~~ ~~ .. ~~ ~~".I ;:':<"'"' "U,"-,G ~ _', ••••• 

_. - .--

..... ""'" .. 

. -\C. - .• ",(-?---
Reference 

Point 

1 

2 

3 

4 

Source 

Ice Water 

Boiling Water 

Very Hot Oil Bath 

Ambient Temp. 

AirNova, Inc. 

Pitot Thermocouple 

Calibl'ation data 

Date' 

Thermocouple LD. 

Probe Length: 

Calibrator 

Ambient Temp.(F): 

Barometric Pressure (" Hg): 

Reference Thermometer: 

Ref. Thermometer 

Temp,(F) 

33 

211 

342 

62 

Average Temp. Change: 

Thermocouple 

Temp,(F) 

34 

212 

342 

62 

Temperature Difference must be < 1.5 % 

'11/17/09 

AN-5H 

5 Foot 

KA 

62 

30.10 

ASTM-2F 

Temperature 

Dill, (%) 

0.2% 

0.1% 

0.0% 

0.0% 

0.1% 

Date: tL (, 7/0 ~ 
. . . . . . . . . . . . . . . . ' ...... '. 

;':;:;;:;:: ~_-,-A,-,~i~r~N~~o~~v~a~,,-~I-,-n~~c~.,-_______________ _ " ....... " ......... " 

......... Type S Pitot Tube . ~ . . . " . 

Dimensional Specification Verification Form 

Pitot No. 

Calibrator 

Date 

AI" -5 H 

11(17/0 1 

Verify the following criteria and check all that apply 

(...---'-

1) Face opening plane perpendicular to the transverse axis? __ _ 

2) Face-opening plane parallel to the logiludinal axis? ",~ 

3) Are Legs A & B of equal len'gth and are centerlines coincident? __ -_ -

If all the above criteria are met, a pitot coeffecient of 0.84 may be assigned to 

the respective pitot tube. If one of the following criteria above is not met, the 

pitot tube must be calibrated in a wind tunnel. 

Recommended Dimensions 

4) Diameter of pilot tubing? (01) = ,3 7£in. (0.1875 < Dt < 0.375) 

5) Dimensions of Pa = ·Iio/} in. 

6) Dimensions of Pb = ,5 tJ P in. 

PaiDt = i, J} (1.05 < Dt < 1.50) 

PbfOl = /.1J (1.05 < 01 < 1.50) 

TftA~SVUISt I' I' lUll "'_IS .lE92j-· ~O::;I~G-I . ....AKU . 

" 

A .......... ' 

·~~] .. I :;':.", .. P, ..... .. _ .. - . 

............ , ., 

.-tr==.-.,.-. E-r-' 
Reference 

Point 

1 

2 

3 

4 

Source 

Ice Water 

Boiling Water 

Very Hot Oil Bath 

Ambient Temp. 

AirNova, Inc. 

Pitot Thermocouple 

Calibration data 

Date: 

Thermocouple 1.0. 

Probe Length: 

Calibrator 

Ambient Temp,(F): 

Barometric Pressure (" Hg): 

Reference Thermometer: 

Ref. Thermometer 

Temp.(F) 

34 

211 

353 

62 

Average Temp. Change: 

Thermocouple 

Temp.(F) 

33 

212 

351 

63 

Temperature Difference must be < 1.5 % 

Signature ;( o'A~u:u1 (; t:lt1--

• 

'11/17/09 

ANT5A 

5 Foot 

KA 

62 

30.10 

ASTM-2F 

Temperature 

Ditt. (%) 

0.2% 

0.1% 

0.2% 

0.2% 

0.2% 

Date: 
. ; . . . .• . ......... 

. . ' ....... . ~;:;::::::: AirNova, Inc .. ••• • • • • • • •• •• • • • • • • ••• . . . . . . . . . Type S Pitot Tube . ~ . . . : . Dimensional Specification Verification Form 

Pitot No. 

Calibrator 

Date 

Verify the following criteria and check all that apply 

1) Face opening plane perpendicular to the transverse axis? 

~~ 

2) Face-opening plane parallel to the logitudinal axis? __ _ 

----- 3) Are Legs A & B of equal length and are centerlines coincident? __ 

If all the above criteria are met, a pitot coeffecient of 0.84 may be assigned to 

the respective pitot tube. If one of the following criteria above is not met, the 

pitot tube must be calibrated in a wind tunnel. 

Recommended Dimensions 

4) Diameter of pitot tubing? (01) = .] 7~ in. (0.1875 < Dt < 0.375) 

5) Dimensions of Pa = .;i/O In. PaiDt = /,3C- (1.05 < Dt < 1.50) 

6) Dimensions of Pb = ·5(6 in. Pb/Dt = //3(. (1.05 < 01 < 1.50) 

'A"~;VE~$E I' " rUle "XIS lESEj_. 

t-o;t;,~~-1 "-""EI . ,,' 

, ... ·:IT.'·-'-f,±i ::±;'-:=;::$"':'=F,".' ::::<"'"' ,." ... d ~ ." ••••• 

. . - - .. - . 

........... , 

" 

'-S=.-" .-E-3--. 
AirNova, Inc. 

Dry gas meter & orifice 

Calibration data and calculations 

Meter Box #: 4 

Checked with Pump #: 4 

'2/2/10 

KA 

delta H = 

Pb = 

Time = 

0.5 in. H20 

30.05 in. Hg 

19.0 min. 

Std Test Meter Data 

IVw= 

FVw= 

TVw= 

tw= 

delta H = 

Pb = 

Time = 

174.977 

182.851 

7.874 

62 

1.0 In. H20 

30.05 in. Hg 

14.0 min. 

Std Test Meter Data 

IVw= 

FVw= 

TVw= 

tw = 

delta H = 

Pb = 

Time = 

166.969 

174.977 

8.008 

62 

1.5 in. H20 

30.05 in. Hg 

11.0 min. 

Std Test Meter Data 

IVw= 

FVw= 

TVw= 

tw= 

159.362 

166.969 

7.607 

62 

Date: 

Calibrator: 

Dry Test Meter Data 

IVd = 185.789 

FVd= 193.678 

TVd 7.889 

ltd = 58 

Ftd= 55 

Avg. td = 56.5 

Dry Test Meter Data 

IVd= 177.777 

FVd = 185.789 

TVd 8.012 

ltd = 68 

Ftd= 63 

Avg. td = 655 

Dry Test Meter Data 

IVd = 

FVd = 

TVd 

ltd = 

Ftd= 

Avg. td = 

170.171 

177.777 

7.606 

68 

62 

65 

"Yi 

1.620 0.986 

"H@i "Yi 

1.672 1.004 

'H@i "Yi 

1.717 1.002 

Pg. 1 of 2 
Date: '2/2/10 

delta H = 

Pb = 

Time = 

20 in H20 

30.05 in. Hg 

10 min. 

Std Test Meter Data 

IVw= 

FVw= 

TVw= 

tw = 

delta H = 

Pb = 

TIme = 

151.200 

159.362 

8.162 

61 

3.0 in. H20 

30.05 in. Hg 

8.0 min. 

Std Test Meter Data 

IVw= 

FVw= 

TVw= 

tw = 

delta H = 

Pb = 

Time = 

142.993 

150.950 

7.957 

60 

4.0 in. H20 

30.05 in. Hg 

7 min. 

Std Test Meter Data 

rvw= 

FVw= 

TVw= 

tw= 

134.970 

142.993 

8.023 

60 

AirNova, Inc, 

Calibration Data 

Dry Test Meter Data 

IVd= 162.038 

FVd = 170.171 

TVd 8.133 

ltd = 67 

Ftd= 61 

Avg. td = 64 

Dry Test Meter Data 

IVd= 153.940 

FVd = 161.789 

TVd 7.849 

ltd = 65 

Ftd= 59 

Avg. td = 62 

Dry Test Meter Data 

IVd = 

FVd = 

TVd 

ltd = 

Ftd= 

Avg. td = 

146.047 

153.940 

7.893 

63 

58 

60,5 

Avg,AH@= 

Signature: , L<J;;! L d~ 

1,66 

MB#: 4 

"Yi 

1.641 1.004 

"H@i "Yi 

1.657 1.010 

"Yi 

1.669 1.008 

Avg, Y = 1,00 

Date: ?/?-./;u 

Pg.2of2 
AirNoV8, Inc. 

Calibration data and calculations 

Meter Box Temperature Sensors 

Meier Box #: 

Date: 

Calibrator: 

Ambient Temp. (F): 

Barometric Pressure ("Hg): 

Reference Thermometer: 

Dry Gas Meter Thermocouple· INLET 

Reference POlDt Ref. Thermometer 

Temp. (F) 

Ambient Temp. 55 

Hot Water (104-122F) 110 

Dry Gas Meter Thermocouple - OUTLET 

Reference Point Ref. ThermQmfltflr 

Temp. CF) 

Ambient Temp. 55 

Hot Water (104-122F) 113 

note: tolerance for inlet and outlet = +/- 5.4 F 

Thermocouple connector/lED readout: 

Ref. Thermometer 

Temp. (F) 

1 Stack 55 

2 Probe 55 

3 Filter 55 

4 Dryer 55 

5Aux 55 

note: tolerance = +/- 2 F 

4 

'2/2/10 

KA 

55 

30.20 

ASTM-2F 

Thermocouple 

Temo. (F) 

54 

112 

Thermocouple 

Temp. (F) 

54 

110 

ThermocouQle 

Temp. (F) 

54 

55 

55 

55 

55 

Diff. 

1 

2 

Diff. 

1 

3 

Diff. 

1 

0 

0 

0 

0 

Signature: ,L/t~c t2?L.- Date: ;>-/"-//0 
AirNova, Inc. 

Dry gas meter & orifice 

Calibration data and calculations 

Meter Box #. 

Checked with Pump #: 

Date: 

Calibrator: 

5 

5 

'2/9/10 

KA 

delta H = 0.5 in H2O 

Pb = 29.97 in. Hg 

Time = 19.0 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 487.046 IVd = 623.455 

FVw= 494.825 FVd = 631.166 

TVw= 7.779 TVd 7.711 

tw= 58 ltd = 63 

Ftd= 60 

Avg. td = 615 

---------------------

delta H = 1.0 in. H2O 

Pb = 2997 in. Hg 

Time = 23.0 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 473.964 IVd= 610.560 

FVw= 487.046 FVd = 623.455 

TVw= 13.082 TVd 12.895 

tw = 57 ltd = 62 

Ftd= 59 

Avg. td = 60.5 

---------------------

delta H = 1.5 in. H2O 

Pb= 29.97 in. Hg 

Time = 15.0 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 463.755 IVd= 600.565 

FVw= 473.964 FVd = 610.564 

TVw= 10.209 TVd 9.999 

tw = 55 ltd = 60 

Ftd= 56 

Avg. td = 58 

"H@i "Vi 

1.623 1.014 

"H@i "Yi 

1.679 1.019 

"H@i "Yi 

1.754 1.023 

Pg.1 of2 
AirNova, Inc. 

Date: '2/9/10 Calibration Data MB#: 5 

---------------------

delta H = 2.0 in. H2O 

Pb = 29.97 in. Hg 

Time = 13.0 min 

Std Test Meter Data Dry Test Meter Data 'H@i "Yi 

IVw= 453.446 IVd = 590.535 1.726 1.025 

FVw= 463.755 FVd = 600,565 

TVw= 10.309 TVd 10.030 

tw= 54 ltd = 57 

Ftd= 53 

Avg. td = 55 

---------------------

delta H = 3.0 in. H2O 

Pb = 29.97 in. Hg 

Time = 12.0 min. 

Std Test Meter Data Dry Test Meter Data "H@i "Yi 

IVw= 441.774 IVd= 579.275 1.724 1.027 

FVw= 453.446 FVd = 590.535 

TVw= 11.672 TVd 11 260 

tw = 53 ltd = 54 

Ftd= 50 

Avg. td = 52 

---------------------

delta H = 4.0 in. H2O 

Pb = 29.97 in. Hg 

Time = 6.0 min. 

Std Test Meter Data Dry Test Meter Data IIH@i "Vi 

IVw= 432.756 IVd = 570.645 1.707 1.032 

FVw= 441.774 FVd = 579.275 

TVw= 9.016 TVd 6.630 

tw = 51 ltd = 50 

Ftd= 49 

Avg td = 49.5 

---------------------

Avg,AH@= 1.70 Avg. y= 1.02 

Signature: / ( -'_Z' ~c' ()jL Date: 2/'l ~J P9· 2of2 
AlrNova, Inc. 

Calibration data and calculations 

Meter Box Temperature Sensors 

Meter Box#: 

Date' 

Calibrator: 

Ambient Temp. (F): 

Barometric Pressure ("Hg): 

Reference Thermometer: 

Dry Gas Meter Thermocouple • INLET 

Reference Point Ref, Thermometer 

Temp (F) 

Ambient Temp. 48 

Hot Water (104-122F) N/A 

Dry Gas Meter Thermocouple - OUTLET 

Reference Point Ref. Thermometer 

Temp. (Fl 

Ambient Temp. 48 

Hot Water (104-122F) N/A 

note: tolerance for inlet and Qutlet = +/- 5.4 F 

Thermocouple connector/LED readout: 

Ref, Thermometer 

Temp (F) 

1 Stack 48 

2 Probe 48 

3 Filter 48 

4 Dryer 48 

5Aux 48 

note: tolerance = +/- 2 F 

Signature: 

5 

'01/05/09 

KA 

48 

30.00 

ASTM-2F 

The[mQ!:;Q!.H2Ie 

Temp. (Fl 

48 

N/A 

ThermocQuglf! 

Temp. (Fl 

48 

N/A 

Ib§:rmQQQUQle 

Temp, (Fl 

48 

48 

48 

48 

48 

Diff. 

0 

0 

Diff. 

0 

0 

om, 

0 

0 

0 

0 

0 
AirNova, Inc. 

Dry gas meter & orifice 

Calibration data and calculations 

Meter Box #: 6 

Checked with Pump #: 6 

'212110 

KA 

Date: 

Calibrator: 

delta H = 0.5 in. H2O 

Pb = 30.10 in. Hg 

Time = 18 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 76.589 IVd = 170.545 

FVw= 83920 FVd = 178.235 

TVw= 7.331 TVd 7.690 

tw= 60 ltd = 60 

Ftd= 80 

Avg. td = 70 

._--""-"-"-""-""-""-" 

delta H = 1.0 in. H2O 

Pb = 30.10 in. Hg 

Time = 13 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 83.920 IVd= 178.235 

FVw= 91.321 FVd = 186.140 

TVw= 7.401 TVd 7.905 

tw = 61 ltd = 80 

Ftd= 88 

Avg. td = 84 

""-""-"-"""-""--"---" 

delta H = 1.5 in. H2O 

Pb = 30.10 in. Hg 

Time = 11 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 91.321 IVd = 186.140 

FVw= 98.819 FVd = 194.214 

TVw= 7.498 TVd 8.074 

tw = 59 ltd = 90 

Ftd= 90 

Avg. td = 90 

AH@i AYi 

1.620 0.970 

AH@i AYi 

1.621 0.975 

AH@i flYi 

1.665 0981 

Pg. 1 0[2 
AirNova, Inc. 

Date: '2/2/10 Calibration Data MB#. 6 

---------------------

delta H = 20 in H2O 

Pb = 30.10 in. Hg 

Time = 10 min. 

Std Test Meter Data Dry Test Meter Data "'H@i "'Vi 

IVw= 99.819 IVd = 194.214 1.734 0.980 

FVw= 107.497 FVd = 202.540 

TVw= 7.678 TVd 8.326 

tw = 58 ltd = 93 

Ftd= 93 

Avg. td = 93 

---------------------

delta H = 3.0 in H2O 

Pb = 30.10 in. Hg 

Time = 8 min. 

Std Test Meter Data Dry Test Meter Data AH@i "Yi 

IVw= 107.497 IVd= 202.540 1.762 0.983 

FVw= 114.939 FVd = 210.605 

TVw= 7.442 TVd 8.065 

tw = 58 ltd = 96 

Ftd= 96 

Avg td = 96 -------_.------------

delta H = 4.0 in. H2O 

Pb = 30.10 in. Hg 

Time = 7 min. 

Std Test Meter Data Dry Test Meter Data AH@i "Yi 

IVw= 113.939 IVd = 210.605 1.772 0.981 

FVw= 121 423 FVd = 218.744 

TVw= 7.484 TVd 8.139 

tw = 58 ltd = 98 

Ftd= 98 

Avg. td = 98 

-------_.------------

Avg.AH@= 1.70 Avg. Y = 0.98 

Signature: /t:~f, t2..c-L Date: ;;2-/(,"-' 

Pg.2or2 
AirNova, Inc. 

Calibration data and calculations 

Meter Box Temperature Sensors 

Meter Box #: 

Date: 

Calibrator: 

Ambient Temp. (F): 

Barometric Pressure ("Hg): 

Reference Thermometer: 

Dry Gas Meter Thermocouple 

Reference Point Ref. Thermometer 

Temp (F) 

Ambient Temp. 57 

Hot Water (104-122F) N/A 

note: tolerance for inlet and outlet = +/- 5.4 F 

Thermocouple connector/LEO readout: 

Ref. Thermometer 

Temp. (F) 

1 Stack 57 

2 Probe 57 

3 Filter 57 

4 Dryer 57 

SAux 57 

6Aux 57 

note: tolerance = +/- 2 F 

6 

'2/2/10 

KA 

57 

29.93 

ASTM-2F 

Thermocouple 

Temp, (F) 

57 

N/A 

ThermocouQle 

Temp. IF) 

58 

56 

56 

58 

58 

58 

Diff. 

0 

0 

Diff, 

1 

1 

1 

1 

1 

1 

Signature: I~;t(c dd Date: z6;(<> 
AirNova, Inc. 

Dry gas meter & orifice 

Calibration data and calculations 

Meter Box #: 7 

Checked with Pump #: 7 

"213110 

KA 

Date: 

Calibrator: 

delta H = 0.5 in. H2O 

Pb = 30.00 in. Hg 

Time = 20.0 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 296.863 IVd = 701.463 

FVw= 304.737 FVd = 709.271 

TVw= 7.874 TVd 7.808 

tw = 54 ltd = 55 

Ftd= 57 

Avg. td = 56 

---------------.-----

delta H = 1.0 in. H2O 

Pb = 30.00 in. Hg 

Time = 16.0 mIn. 

Std Test Meter Data Dry Test Meter Data 

IVw= 288.065 IVd = 692.766 

FVw= 296.863 FVd = 701.463 

TVw= 8.798 TVd 8.697 

tw= 54 ltd = 53 

Ftd= 57 

Avg. td = 55 

---------------------

delta H = 1.5 In. H2O 

Pb = 30.00 in. Hg 

Time = 13.0 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 279.360 IVd = 684.221 

FVw= 288.065 FVd = 692.766 

TVw= 8.705 TVd 8.545 

tw = 54 ltd = 51 

Ftd= 57 

Avg. td = 54 

"H@j "Yi 

1.745 1.011 

I\H@i "Yi 

1.793 1.011 

"H@j "Vi 

1.817 1.015 

P9· 1or2 
Date: '2/3110 

delta H = 

Pb = 

Time = 

2.0 in. H20 

3000 In. Hg 

100 min. 

Std Test Meter Data 

IVw= 

FVw= 

TVw= 

tw= 

delta H = 

Pb = 

Time = 

271.591 

279.360 

7.769 

53 

3.0 in. H20 

30.00 in. Hg 

9.0 min. 

Std Test Meter Data 

IVw= 

FVw= 

TVw= 

tw= 

delta H = 

Pb = 

Time = 

263058 

271.591 

8.533 

52 

4.0 in. H20 

30.00 in. Hg 

10.0 min. 

Std Test Meter Data 

IVw= 

FVw= 

TVw= 

tw = 

252.163 

263.058 

10.895 

52 

AirNova, Inc. 

Calibration Data 

Dry Test Meter Data 

IVd = 

FVd= 

TVd 

ltd = 

Ftd= 

Avg. td = 

676.579 

684.221 

7.642 

48 

57 

52.5 

Dry Test Meter Data 

IVd= 668186 

FVd = 676.579 

TVd 8.393 

ltd = 46 

Ftd= 55 

Avg. td = 50.5 

Dry Test Meter Data 

IVd = 

FVd = 

TVd 

ltd = 

Ftd= 

Avg. td = 

657.532 

668.168 

10.636 

45 

52 

48.5 

1.80 

MB#: 7 

AH@i 

1.798 1.011 

"H@i 

1.811 1.006 

"H@i 

1.836 1.007 

Avg. y= 1.01 

Pg.2of2 
AirNova. Inc. 

Calibration data and calculations 

Meter Box Temperature Sensors 

Meter Box #. 

Date: 

Calibrator: 

Ambient Temp. (F): 

Barometnc Pressure ("Hg), 

Reference Thermometer: 

Dry Gas Meter Thermocouple -INLET 

Reference Pomt Ref Thermometer 

Temo. (El 

Ambient Temp. 50 

Hot Water (104-122F) 110 

Dry Gas Meter Thermocouple· OUTLET 

Reference Point R!;l:f. Ihermometer 

Temp. (F) 

Ambient Temp. 50 

Hot Water (104-122F) 112 

note: tolerance for inlet and outlet = +/- 5.4 F 

Thermocouple connector/LED readout: 

Ref. Thermometer 

Temp. (F) 

1 Stack 50 

2 Probe 50 

3 Filter 50 

4 Dryer 50 

5Aux 50 

note: tolerance = +/- 2 F 

7 

'2/3/10 

KA 

50 

30.00 

ASTM·2F 

Thermocougle 

Temp, (F) 

48 

112 

Thermocouple 

Temp. (F) 

47 

111 

ThermoQQugle 

Temp, (F) 

50 

50 

50 

50 

50 

Diff. 

2 

2 

Diff. 

3 

1 

Diff. 

a 

a 

a 

a 

a 

Signature: /L....d t, c:2...LL.. Date: 2/3!/U 
AirNova, Inc. 

Dry gas meter & orifice 

Calibration data and calculations 

Meter Box #: 8 

Checked with Pump #: 8 

'213110 

KA 

Date: 

Calibrator: 

delta H = 0.5 in. H2O 

Pb = 30.00 in. Hg 

Time = 18.0 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 418.178 IVd = 348.247 

FVw= 425.584 FVd = 356.016 

TVw= 7.406 TVd 7.769 

tw= 61 ltd = 77 

Ftd= 63 

Avg. td = 70 

---------------------

delta H = 10 in. H2O 

Pb = 30.00 in Hg 

Time = 13.0 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 410.371 IVd = 340.124 

FVw= 418.178 FVd = 348.247 

TVw= 7.807 TVd 8.123 

tw = 60 ltd = 69 

Ftd= 61 

Avg. td = 65 

---------------------

delta H = 1.5 in. H2O 

Pb = 30.00 in. Hg 

TIme = 11.0 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 402.330 IVd = 331 784 

FVw= 410.371 FVd = 340.124 

TVw= 8.041 TVd 8.340 

tw= 59 ltd = 66 

Ftd= 60 

Avg. td = 63 

flH@i "Yi 

1598 0.969 

"H@i flYi 

1509 0968 

IIH@i "Yi 

1.528 0.968 

Pg.1 of2 
Date: '2/3/10 

delta H = 

Pb = 

Time = 

2.0 in. H20 

30.00 in. Hg 

10 min. 

Std Test Meter Data 

IVw= 

FVw= 

TVw= 

tw= 

delta H = 

Pb = 

Time = 

394.085 

402.330 

8.245 

59 

30 in H20 

30.00 in. Hg 

15.0 min. 

Std Test Meter Data 

IVw= 378.935 

FVw= 394.085 

TVw= 15.150 

tw = 58 

---------------------

delta H = 4.0 in. H2O 

Pb = 30.00 in. Hg 

Time = 7.0 min. 

Std Test Meter Data 

IVw= 

FVw= 

TVw= 

tw= 

Signature: 

370.716 

378.935 

8.219 

58 

Avg.AH@= 

AirNova, Inc, 

Calibration Data 

Dry Test Meter Data 

IVd = 323.289 

FVd = 331.784 

TVd 8.495 

ltd = 67 

Ftd= 60 

Avg. td = 63.5 

Dry Test Meter Data 

IVd= 307.779 

FVd = 323.289 

TVd 15.510 

ltd = 61 

Ftd= 53 

Avg. td = 57 

Dry Test Meter Data 

IVd = 

FVd = 

TVd 

ltd = 

Ftd= 

Avg. td = 

299.449 

307.799 

8.350 

55 

50 

52.5 

1.58 

MB#: 8 

AH@i IIYi 

1.600 0.974 

"H@i "Yi 

1.613 0968 

"H@i "Yi 

1.605 0.964 

Avg. y= 0.97 

Pg.2of2 
AlrNova, Inc. 

Calibration data and calculations 

Meter Box Temperature Sensors 

Meter Box #: 

Date: 

Calibrator: 

Ambient Temp. (F): 

Barometric Pressure ("Hg): 

Reference Thermometer: 

Dry Gas Meter Thermocouple -INLET 

Reference Point Ref. Thermometer 

Temp. (F) 

Ambient Temp. 52 

Hoi Water (104-122F) 110 

Dry Gas Meter Thermocouple ~ OUTLET 

Reference Point Ref. Thermometer 

Temp. (F) 

Ambient Temp. 52 

Hot Water (104-122F) 107 

note: tolerance for inlet and outret = +/- 5.4 F 

Thermocouple connector/LED readout: 

Ref. Thermometer 

Temp, (F) 

1 Stack 52 

2 Probe 52 

3 Filter 52 

4 Dryer 52 

5Aux 52 

note: tolerance = +/- 2 F 

8 

'2/3/10 

KA 

52 

30.00 

ASTM-2F 

Thermocougle 

Temp. (F) 

49 

112 

ThermOcou(;!l§ 

Temp. (F) 

50 

108 

Thfl;rmOCQu!;!;le 

Temlhill 

52 

52 

53 

52 

52 

Diff. 

3 

2 

Diff. 

2 

1 

Diff, 

0 

0 

1 

0 

0 

Signature:._,If.~----"~"""'~~t.:~.t:2U---~~,,----_ Date: 2/-:5/0 
AirNova, Inc. 

Dry gas meter & orifice 

Calibration data and calculations 

Meter Box #: 9 

Checked with Pump #: 9 

'2/3/10 

KA 

Date: 

Calibrator: 

delta H = 0.5 in. H2O 

Pb = 30.00 in. Hg 

Time = 21.0 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 360.452 IVd = 547.683 

FVw= 369.081 FVd = 556.280 

TVw= 8.629 TVd 8.597 

two 61 ltd = 70 

Ftd= 70 

Avg. td = 70 

---------------------

delta H = 1.0 in. H2O 

Pb = 30.00 in. Hg 

Time = 18.0 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 349.756 IVd = 537.096 

FVw= 360.452 FVd = 547.638 

TVw= 10.696 TVd 10.542 

two 59 ltd = 70 

Ftd= 70 

Avg. td = 70 

---------------------

delta H = 1.5 in. H2O 

Pb = 30.00 in. Hg 

Time = 13.0 min. 

Std Test Meter Data Dry Test Meter Data 

lVw= 340.360 IVd= 527.820 

FVw= 349.756 FVd = 537.096 

TVw= 9.396 TVd 9.276 

tw = 57 ltd = 68 

Ftd= 68 

Avg. td = 68 

AH@i "Yi 

1.603 1.020 

"H@i AYi 

1.521 1.034 

"H@i "Yi 

1.536 1.031 

Pg. 1 of 2 
Date: '2/3/10 

delta H = 

Pb = 

Time = 

2.0 in, H20 

30.00 in. Hg 

100 min 

Std Test Meter Data 

IVw= 

FVw= 

TVw= 

two 

delta H = 

Pb = 

Time = 

332.219 

340,360 

8.141 

56 

3.0 in. H20 

30.00 in, Hg 

90 min 

Std Test Meter Data 

IVw= 

FVw= 

TVw= 

tw = 

delta H = 

Pb = 

Time = 

323,371 

332,219 

8,848 

54 

4,0 in. H20 

30,00 in, Hg 

9.0 min 

Std Test Meter Data 

IVw= 312.833 

FVw= 323,371 

TVw= 10.538 

tw = 53 

---------------------

Avg.AH@= 

AirNova, Inc, 

Calibration Data 

Dry Test Meter Data 

IVd= 519.800 

FVd= 527.820 

TVd 8,020 

ltd = 67 

Ftd= 67 

Avg, td = 67 

Dry Test Meter Data 

IVd = 511.176 

FVd = 519.800 

TVd 8,624 

ltd = 64 

Ftd= 64 

Avg, td = 64 

Dry Test Meter Data 

IVd = 500.912 

FVd = 511.176 

TVd 10.264 

ltd = 58 

Ftd= 58 

Avg, td = 58 

1.58 

Signature: , 

£~[';aJ.L 

MB#' 9 

"H@i IIYi 

1.611 1.032 

"H@j "Yi 

1.654 1.038 

"H@i "'Yi 

1 ,566 1,027 

Avg. Y = 1.03 

Date: *!/d 

Pg.2of2 
AirNova, Inc. 

Calibration data and calculations 

Meter Box Temperature Sensors 

Meter Box#: 

Date: 

Calibrator: 

Ambient Temp. (F): 

Barometric Pressure ("Hg): 

Reference Thermometer 

Dry Gas Meter Thermocouple -INLET 

Reference Point R!l!f. Thermometer 

Temp. (F) 

Ambient Temp. 52 

Hot Water (104-122F) 110 

Dry Gas Meter Thermocouple - OUTLET 

Reference Point 

Ambient Temp, 

Hot Water (104-122F) 

Ref. Thermome!~r 

Temp_ (F) 

N/A 

N/A 

note: tolerance for inlet and outlet = +/- 5 4 F 

Thermocouple connector/LED readout: 

Ref, Thermometer 

Temp. (Fl 

1 Stack 52 

2 Probe 52 

3 Filter 52 

4 Dryer 52 

5 Aux 52 

note: tolerance = +/- 2 F 

9 

'2/3/10 

KA 

52 

3000 

ASTM-2F 

Thermocougle 

Temp. (Fl 

54 

109 

ThflrmQ!;;Q!.!!lI!l! 

Temp (Fl 

N/A 

N/A 

Thermocougle 

Temp. (F) 

52 

52 

52 

52 

52 

Diff. 

2 

1 

Diff. 

0 

0 

Diff 

0 

0 

0 

0 

0 
AirNova, Inc. 

Dry gas meter & orifice 

Calibration data and calculations 

Meter Box #: 

Checked with Pump #. 

Date: 

Calibrator: 

10 

10 

'2/2/10 

KA 

delta H = 0.5 in. H2O 

Pb= 30.05 in. Hg 

Time = 19.0 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 228.386 IVd = 582.395 

FVw= 235.845 FVd = 589.975 

TVw= 7.459 TVd 7.580 

tw = 61 ltd = 66 

Ftd= 66 

Avg. td = 66 

---------------------

delta H = 1.0 in. H2O 

Pb = 3005 in. Hg 

Time = 14.0 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 220.786 IVd = 574.700 

FVw= 228.386 FVd = 582.395 

TVw= 7.600 TVd 7695 

two 61 ltd = 66 

Ftd= 66 

Avg. td = 66 

---------------------

delta H = 1.5 in. H2O 

Pb = 30.05 in. Hg 

Time = 11.0 min. 

Std Test Meter Data Dry Test Meter Data 

IVw= 213.258 IVd = 567.100 

FVw= 220.786 FVd = 574.700 

TVw= 7.528 TVd 7.600 

tw = 61 ltd = 66 

Ftd= 66 

Avg. td = 66 

"H@i "Yi 

1.766 0.992 

"H@i "Yi 

1.847 0.995 

AH@i "Yi 

1.743 0.996 

P9.1 of2 
Date: '2/2/10 

delta H = 

Pb = 

Time = 

2,0 in, H20 

30,05 in. Hg 

11.0 min, 

Std Test Meter Data 

IVw= 

FVw= 

TVw= 

tw= 

delta H = 

Pb = 

Time= 

204.824 

213.258 

8434 

61 

3.0 In. H20 

30,05 in, Hg 

10.0 min. 

Std Test Meter Data 

IVw= 

FVw= 

Ww= 

tw= 

delta H = 

Pb = 

Time = 

195,491 

204.824 

9.333 

61 

4,0 in. H20 

30.05 in. Hg 

10.0 min. 

Std Test Meter Data 

IVw= 184,630 

FVw= 195,491 

TVw= 10.861 

tw= 61 

Signature: 

AirNova, Inc. 

Calibration Data 

Dry Test Meter Data 

IVd = 558,576 

FVd = 567,100 

TVd 8.524 

ltd = 66 

Ftd= 66 

Avg. td = 66 

Dry Test Meter Data 

IVd= 549.210 

FVd = 558,576 

TVd 9,366 

ltd = 65 

Ftd= 65 

Avg, td = 65 

Dry Test Meter Data 

IVd = 538.324 

FVd = 549.210 

TVd 10,886 

ltd = 63 

Ftd= 63 

Avg. td = 63 

1.82 

MB#: 10 

"H@i 

1.852 0.994 

"H@i 

1,878 0.997 

AH@i 

1,857 0,992 

Avg. Y = 0.99 

Date: .1. 4/; <J 

Pg.2of2 
AirNova, Inc. 

Calibration data and calculations 

Meter Box Temperature Sensors 

Meter Box#, 

Date: 

Calibrator: 

Ambient Temp. (E): 

Barometric Pressure (nHg): 

Reference Thermometer: 

Dry Gas Meter Thermocouple - INLET 

Reference Point Be! Thermometer 

Temp. (F) 

AmbIent Temp. 73 

Hot Water (104-122F) 101 

Dry Gas Meter Thermocouple· OUTLET 

Beference Point B!iil Thermometer 

Temp. (Fl 

Ambient Temp N/A 

Hoi Water (104-122F) N/A 

note: tolerance for Inlet and outlet = +/- 5.4 F 

Thermocouple connector/LED readout: 

Ber Thermometer 

Temo. (Fl 

1 Stack 73 

2 Probe 73 

3 Filter 73 

4 Dryer 73 

5 Aux 73 

note: tolerance = +1- 2 F 

Signature: /~ C. {lLt10 

'2/2/10 

KA 

73 

30.05 

ASTM-2F 

TberrnocouQle 

Temp. (Fl 

72 

101 

Ibe[mo!;;Q!.!QJe 

Temp. (E) 

N/A 

N/A 

IberQlocQupJe 

Temp. (F) 

74 

73 

73 

73 

73 

Dltt. 

1 

0 

Qifl 

0 

0 

Diff. 

1 

0 

0 

0 

0