**FORM A -1** 

**COMPA NY INFORMA**  **TION**

**I. Parent Company / Legal Corporate Owner Information**

1. Legal Parent Company / Legal Corporate Name Example Resins 2. Mailing Address 123 Example Resins Rd 3. City Any town 4. State North Carolina 5. Zip Code 28590 6. County Any County

501-750 7. Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned):



### Page 1 of 1 **DRA FT** PVC Section 114 Survey Part 1 06/23/2009**FORM A -2** 

**FA CILITY INFORMA** 

**TION**

**II. Polyvinyl Chloride and Copolymers (PVC) Production Facility Information**

1. Facility

Name Example Resins Sometown Facility Address a. Street 123 Any Road W ay b. City Som etown c. State Louisiana d. Zip Code 70767 e. County Any Parish Facility Coordinates (Decimal Degrees to the 5th decimal place) f. Latitude 35.72154 g. Longitude -79.17732

2. Number of employees attached to the PVC production facility : 175

**III. Technical Contact**

1. Name John Doe 2. Technical Contact Title Environm ental Manager 3. Telephone 1-234-567-8910 4. Facsimile 1-234-567-8910 5. Em ail John.Doe@ExampleResins.com

**IV. Other**

1. Is the facility

a major source of HAP? Yes

2. If No, did the facility

take a limit of its potential HAP em issions to avoid classification as a major source?

3. If the facility

took a limit of its potential HAP

em issions to avoid classification as a major source, provide the date on which the limit was taken (MM/DD/YYYY).

4. Does the facility

manufacture other products in addition to PVC resin? Yes

5. If Yes, list the other products manufactured at the facility

. Ethylene Dichloride, Vinyl Chloride Monom er

6. Are there any

HAP em issions associated with any co-located facilities? Yes



### Page 1 of 1 **DRA FT** PVC Section 114 Survey Part 1 06/23/2009**FORM C ECONOMIC LIFE AND APPLICABLE REGULATIONS FOR PVC PRODUCTION UNIT** 

Year Facility Commenced PVC Production: 1980 years Remaining Economic Life PVC Production Unit: 50 years
**Table 1. Federal, State, and Local Regulations (list, include all regulations that apply to any part of the process unit)**

**Table 2. Federal, State, and Local Permits**

LA01251356 Louisiana Pollutant Discharge Elimination System Permit Wa ter, Treated Process W aste W ater, Treated Sanitary W astewater, Stormwater and Hydrostatic Test W ater LA05541321 Louisiana Pollutant Discharge Elimination System Permit - Statewide General Permit Discharges of Hydrostatic Test and Vessel Testing W astewater **Permit ID Permit Type**  **Regulated Process Equipment/Control Device/Recovery Equipment (list ID provided in Form B)** 5648-V4 Title V/Part 70 Operating Permit Entire PVC Process 40 CFR 82 Refrigerant RE-3 40 CFR 63 NESHAP Subpart Q National Emission Standards For Hazardous Air Pollutants For Industrial Process Cooling Towers U-8

40 CFR 68 Chemical Accident Prevention Provisions Enitre PVC Process 40 CFR 63 NESHAP Subpart B NESHAP for Source Catagories - Requirements for Control Technology Determinations for Major Sources C-2 40 CFR 63 NESHAP Subpart H National Emission Standards for Organic Hazardous Air Pollutants for Equipment Leaks Enitre PVC Process 40 CFR 61 Subpart A National Emission Standards For Hazardous Air Pollutants - General Provisions Enitre PVC Process 40 CFR 61 Subpart F National Emission Standard For Vinyl Chloride Enitre PVC Process 40 CFR 60 NSPS Subpart A Standards of Performance For New Stationary Sources - General Provisions Enitre PVC Process LAC 33:III. Chapter 9 General Regulations on Control of Emissions and Emission Standards C-2 LAC 33:III. Chapter 11 Control of Emissions of Smoke C-2 **Regulation Citation Regulation Title**  **Regulated Process Equipment/Control Device/Recovery Equipment (list ID provided in Form B)** LAC 33:III. Chapter 5 Permit Procedures C-2

LAC 33:III. Chapter 13 Emission Standards for Particulate Matter C-3, C-4

Page 1 of 1 **DRAFT**PVC Section 114 Survey Part 1 06/23/2009**FORM D-2**

**30 DA Y RESIN SA** **MP LING - STRIPPER OUTLET(S)** 

**Instructions**

2. Do not submit partial data for any day : each day

must include (at a minimum) concentration analysis results for all HAP in Table 10 to Subpart HHHHHHH of 40 CFR Part 63. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, daily resin production, number of samples composited, number of resin strippers sampled, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Provide the total daily production from the resin strippers samples for the type of resin. If your final product is sold as a dried resin, report production on a dry basis. If your final product is sold as a wet resin report production on a wet basis. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of 5. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 6. Enter any

notes or additional information relevant to the sampling or analysis. 7. Refer to Attachment B of Enclosure 1 "Summary of Test Procedures, Methods, and Reporting Requirements For Resin and Process W astewater Sampling and Analysis at Poly vinyl Chloride and Copoly me r (PVC) Facilities" for additional instructions and information.

**CA S No.**  **HA P** 

107211 Ethylene glycol 67561 Methanol 75070 Acetaldehyde 50000 Formaldehyde 51285 2,4-dinitrophenol 98862 Acetophenone 117817 Bis(2-ethylhexyl) phthalate (DEHP) 123319 Hydroquinone 108952 Phenol 79345 1,1,2,2-tetrachloroethane 106990 1,3-butadiene 540841 2,2,4-trimethylpentane 71432 Benzene 108907 Chlorobenzene 67663 Chloroform 126998 Chloroprene 98828 Cumene 75003 Ethyl chloride (Chloroethane) 100414 Ethylbenzene 107062 Ethylene dichloride (1,2-Dichloroethane) 75343 Ethylidene dichloride (1,1-Dichloroethane) 74873 Methyl chloride (Chloromethane) 75092 Methylene chloride 110543 n-Hexane 108883 Toluene 71556 Methyl chloroform (1,1,1-Trichloroethane) 79005 1,1,2-Trichloroethane 1. Complete the table below for each resin type produced by the facility

during the 30 days of sampling. If the facility produced more than one resin ty pe during the 30 days, create multiple copies of this worksheet as necessary and complete one worksheet for each resin ty pe. Do not enter data for multiple resin types on a single worksheet.

**Resin Type (suspension, dispersion, bulk, etc.) -->**

**Total Daily Resin Production Rate (lbs of resin per day from sampled resin strippers) Number of Samples Composited for A** **nalysis Number of Resin Strippers Sampled to Obtain Composite**  **If Other, Please Provide a Description of the Resin Type -->**108054 Vinyl acetate 593602 Vinyl bromide 75014 Vinyl chloride 75354 Vinylidene chloride (1,1-Dichloroethylene) 1330207 Xylenes (isomers and mixtures)2. Do not submit partial data for any day : each day

must include (at a minimum) concentration analysis results for all HAP in Table 10 to Subpart HHHHHHH of 40 CFR Part 63. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, daily resin production, number of samples composited, number of resin strippers sampled, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Provide the total daily production from the resin strippers samples for the type of resin. If your final product is sold as a dried resin, report production on a dry basis. If your final product is sold as a wet resin report production on a wet basis. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of 40 CFRPart 63) in the table below. 5. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 6. Enter any

notes or additional information relevant to the sampling or analysis. 7. Refer to Attachment B of Enclosure 1 "Summary of Test Procedures, Methods, and Reporting Requirements For Resin and Process W astewater Sampling and Analysis at Poly vinyl Chloride and Copoly me r (PVC) Facilities" for additional instructions and information.

**An alysis M**  **ethod Concentration**  **(ppmw) Non-Detect?** 

SW -846-8015C 5 SW -846-8015C 10 SW -846-8315A 0.1 SW -846-8315A 0.5 SW -846-8270D 8 SW -846-8270D 1 SW -846-8270D 2 SW -846-8270D 1 SW -846-8270D 1 SW -846-8260B 0.5 SW -846-8260B 0.5 SW -846-8260B 6 SW -846-8260B 8 SW -846-8260B 0.1 SW -846-8260B 0.05 Non-detect SW -846-8260B 0.07 Non-detect SW -846-8260B 1 SW -846-8260B 0.05 Non-detect SW -846-8260B 1 SW -846-8260B 1 SW -846-8260B 1 SW -846-8260B 0.01 Non-detect SW -846-8260B 0.02 Non-detect SW -846-8260B 0.01 Non-detect SW -846-8260B 0.01 Non-detect SW -846-8260B 0.5 SW -846-8260B 0.5 1. Complete the table below for each resin type produced by the facility

during the 30 days of sampling. If the facility produced more than one resin ty pe during the 30 days, create multiple copies of this worksheet as necessary and complete one worksheet for each resin ty pe. Do

**Sample Date -->** 02/15/14 **Resin Type (suspension, dispersion, bulk, etc.) -->** Suspension

**Total Daily Resin Production Rate (lbs of resin per day from sampled resin strippers)** 7000 **Number of Samples Composited for A nalysis**  **Number of Resin Strippers Sampled to Obtain Composite An**  **alysis Date -->** 02/17/14 **Lab Report ID -->** IA-001 **Lab Sample ID -->** IAS-001 **If Other, Please Provide a Description of the Resin Type -->**SW -846-8260B 0.01 Non-detect

SW -846-8260B 0.05 Non-detect EPA Method 107 2 SW -846-8260B 3 SW -846-8260B 12. Do not submit partial data for any day : each day

must include (at a minimum) concentration analysis results for all HAP in Table 10 to Subpart HHHHHHH of 40 CFR Part 63. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, daily resin production, number of samples composited, number of resin strippers sampled, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Provide the total daily production from the resin strippers samples for the type of resin. If your final product is sold as a dried resin, report production on a dry basis. If your final product is sold as a wet resin report production on a wet basis.

5. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

7. Refer to Attachment B of Enclosure 1 "Summary of Test Procedures, Methods, and Reporting Requirements For Resin and Process W astewater Sampling and Analysis at Poly vinyl Chloride and Copoly me r (PVC) Facilities" for additional instructions and information.

**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 10 0.1 0.5 8 1 2 1 1 0.5 0.5 6 8 0.1 0.05 Non-detect 0.07 Non-detect 1 0.05 Non-detect 1 1 1 0.01 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 1. Complete the table below for each resin type produced by the facility

during the 30 days of sampling. If the facility produced more than one resin ty pe during the 30 days, create multiple copies of this worksheet as necessary and complete one worksheet for each resin ty pe. Do

02/15/14 02/16/14 **1 2** 

Suspension Suspension

7000 7000 3 3

02/17/14 02/18/14 IA-001 IA-001 IAS-001 IAS-002 4 40.01 Non-detect 0.05 Non-detect 2 3 17. Refer to Attachment B of Enclosure 1 "Summary of Test Procedures, Methods, and Reporting Requirements For Resin and Process W astewater Sampling and Analysis at Poly vinyl Chloride and Copoly me r (PVC) Facilities" for additional instructions and information.

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect?**

5 5 10 10 0.1 0.1 0.5 0.5 8 8 1 1 2 2 1 1 1 1 0.5 0.5 0.5 0.5 6 6 8 8 0.1 0.1 0.05 Non-detect 0.05 Non-detect 0.07 Non-detect 0.07 Non-detect 1 1 0.05 Non-detect 0.05 Non-detect 1 1 1 1 1 1 0.01 Non-detect 0.01 Non-detect 0.02 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 0.5 0.5 1. Complete the table below for each resin type produced by the facility

during the 30 days of sampling. If the facility produced more than one resin ty pe during the 30 days, create multiple copies of this worksheet as necessary and complete one worksheet for each resin ty pe. Do

02/17/14 02/18/14 **3**

Suspension Suspension

7000 7000 3

02/19/14 02/20/14 IA-001 IA-002 IAS-003 IAS-004 40.01 Non-detect 0.01 Non-detect 0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 10 0.1 0.5 8 1 2 1 1 0.5 0.5 6 8 0.1 0.05 Non-detect 0.07 Non-detect 1 0.05 Non-detect 1 1 1 0.01 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 **4 5**  02/18/14 02/19/14 Suspension Suspension

7000 7000 3 3

02/20/14 02/21/14 IA-002 IA-002 IAS-004 IAS-005 4 40.01 Non-detect 0.05 Non-detect 2 3 1**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 5 10 10 0.1 0.1 0.5 0.5 8 8 1 1 2 2 1 1 1 1 0.5 0.5 0.5 0.5 6 6 8 8 0.1 0.1 0.05 Non-detect 0.05 Non-detect 0.07 Non-detect 0.07 Non-detect 1 1 0.05 Non-detect 0.05 Non-detect 1 1 1 1 1 1 0.01 Non-detect 0.01 Non-detect 0.02 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 0.5 0.5 **6** 02/20/14 02/21/14 Suspension Suspension

7000 7000 3

02/22/14 02/23/14 IA-002 IA-003 IAS-006 IAS-007 40.01 Non-detect 0.01 Non-detect 0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 10 0.1 0.5 8 1 2 1 1 0.5 0.5 6 8 0.1 0.05 Non-detect 0.07 Non-detect 1 0.05 Non-detect 1 1 1 0.01 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 **7 8**  02/21/14 02/22/14 Suspension Suspension

7000 7000 3 3

02/23/14 02/24/14 IA-003 IA-003 IAS-007 IAS-008 4 40.01 Non-detect 0.05 Non-detect 2 3 1**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 5 10 10 0.1 0.1 0.5 0.5 8 8 1 1 2 2 1 1 1 1 0.5 0.5 0.5 0.5 6 6 8 8 0.1 0.1 0.05 Non-detect 0.05 Non-detect 0.07 Non-detect 0.07 Non-detect 1 1 0.05 Non-detect 0.05 Non-detect 1 1 1 1 1 1 0.01 Non-detect 0.01 Non-detect 0.02 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 0.5 0.5 **9** 02/23/14 02/24/14 Suspension Suspension

7000 7000 3

02/25/14 02/26/14 IA-004 IA-003 IAS-009 IAS-010 40.01 Non-detect 0.01 Non-detect 0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 10 0.1 0.5 8 1 2 1 1 0.5 0.5 6 8 0.1 0.05 Non-detect 0.07 Non-detect 1 0.05 Non-detect 1 1 1 0.01 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 **10 11**  02/24/14 02/25/14 Suspension Suspension

7000 7000 3 3

02/27/14 02/26/14 IA-004 IA-004 IAS-011 IAS-010 4 40.01 Non-detect 0.05 Non-detect 2 3 1**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 5 10 10 0.1 0.1 0.5 0.5 8 8 1 1 2 2 1 1 1 1 0.5 0.5 0.5 0.5 6 6 8 8 0.1 0.1 0.05 Non-detect 0.05 Non-detect 0.07 Non-detect 0.07 Non-detect 1 1 0.05 Non-detect 0.05 Non-detect 1 1 1 1 1 1 0.01 Non-detect 0.01 Non-detect 0.02 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 0.5 0.5

**12** 02/26/14 02/27/14 Suspension Suspension

7000 7000 3

02/28/14 03/01/14 IA-004 IA-005 IAS-012 IAS-013 40.01 Non-detect 0.01 Non-detect 0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 10 0.1 0.5 8 1 2 1 1 0.5 0.5 6 8 0.1 0.05 Non-detect 0.07 Non-detect 1 0.05 Non-detect 1 1 1 0.01 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 **13 14**  02/27/14 02/28/14 Suspension Suspension

7000 7000 3 3

03/01/14 03/02/14 IA-005 IA-005 IAS-013 IAS-014 4 40.01 Non-detect 0.05 Non-detect 2 3 1**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 5 10 10 0.1 0.1 0.5 0.5 8 8 1 1 2 2 1 1 1 1 0.5 0.5 0.5 0.5 6 6 8 8 0.1 0.1 0.05 Non-detect 0.05 Non-detect 0.07 Non-detect 0.07 Non-detect 1 1 0.05 Non-detect 0.05 Non-detect 1 1 1 1 1 1 0.01 Non-detect 0.01 Non-detect 0.02 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 0.5 0.5

**15** 03/01/14 03/02/14 Suspension Suspension

7000 7000 3

03/03/14 03/04/14 IA-005 IA-006 IAS-015 IAS-016 40.01 Non-detect 0.01 Non-detect 0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 10 0.1 0.5 8 1 2 1 1 0.5 0.5 6 8 0.1 0.05 Non-detect 0.07 Non-detect 1 0.05 Non-detect 1 1 1 0.01 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 **16 17**  03/02/14 03/03/14 Suspension Suspension

7000 7000 3 3

03/04/14 03/05/14 IA-006 IA-006 IAS-016 IAS-017 4 40.01 Non-detect 0.05 Non-detect 2 3 1**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 5 10 10 0.1 0.1 0.5 0.5 8 8 1 1 2 2 1 1 1 1 0.5 0.5 0.5 0.5 6 6 8 8 0.1 0.1 0.05 Non-detect 0.05 Non-detect 0.07 Non-detect 0.07 Non-detect 1 1 0.05 Non-detect 0.05 Non-detect 1 1 1 1 1 1 0.01 Non-detect 0.01 Non-detect 0.02 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 0.5 0.5

**18** 03/04/14 03/05/14 Suspension Suspension

7000 7000 3

03/06/14 03/07/14 IA-006 IA-007 IAS-018 IAS-019 40.01 Non-detect 0.01 Non-detect 0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 10 0.1 0.5 8 1 2 1 1 0.5 0.5 6 8 0.1 0.05 Non-detect 0.07 Non-detect 1 0.05 Non-detect 1 1 1 0.01 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 **19 20**  03/05/14 03/06/14 Suspension Suspension

7000 7000 3 3

03/07/14 03/08/14 IA-007 IA-007 IAS-019 IAS-020 4 40.01 Non-detect 0.05 Non-detect 2 3 1**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 5 10 10 0.1 0.1 0.5 0.5 8 8 1 1 2 2 1 1 1 1 0.5 0.5 0.5 0.5 6 6 8 8 0.1 0.1 0.05 Non-detect 0.05 Non-detect 0.07 Non-detect 0.07 Non-detect 1 1 0.05 Non-detect 0.05 Non-detect 1 1 1 1 1 1 0.01 Non-detect 0.01 Non-detect 0.02 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 0.5 0.5

**21** 03/08/14 03/07/14 Suspension Suspension

7000 7000 3

03/09/14 03/10/14 IA-007 IA-008 IAS-021 IAS-022 40.01 Non-detect 0.01 Non-detect 0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 10 0.1 0.5 8 1 2 1 1 0.5 0.5 6 8 0.1 0.05 Non-detect 0.07 Non-detect 1 0.05 Non-detect 1 1 1 0.01 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 **22 23**  03/08/14 03/09/14 Suspension Suspension

7000 7000 3 3

03/10/14 03/11/14 IA-008 IA-008 IAS-023 IAS-022 4 40.01 Non-detect 0.05 Non-detect 2 3 1**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 5 10 10 0.1 0.1 0.5 0.5 8 8 1 1 2 2 1 1 1 1 0.5 0.5 0.5 0.5 6 6 8 8 0.1 0.1 0.05 Non-detect 0.05 Non-detect 0.07 Non-detect 0.07 Non-detect 1 1 0.05 Non-detect 0.05 Non-detect 1 1 1 1 1 1 0.01 Non-detect 0.01 Non-detect 0.02 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 0.5 0.5

**24** 03/10/14 03/11/14 Suspension Suspension

7000 7000 3

03/12/14 03/13/14 IA-008 IA-009 IAS-024 IAS-025 40.01 Non-detect 0.01 Non-detect 0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 10 0.1 0.5 8 1 2 1 1 0.5 0.5 6 8 0.1 0.05 Non-detect 0.07 Non-detect 1 0.05 Non-detect 1 1 1 0.01 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 **25 26**  03/11/14 03/12/14 Suspension Suspension

7000 7000 3 3

03/13/14 03/14/14 IA-009 IA-009 IAS-025 IAS-026 4 40.01 Non-detect 0.05 Non-detect 2 3 1**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

5 5 10 10 0.1 0.1 0.5 0.5 8 8 1 1 2 2 1 1 1 1 0.5 0.5 0.5 0.5 6 6 8 8 0.1 0.1 0.05 Non-detect 0.05 Non-detect 0.07 Non-detect 0.07 Non-detect 1 1 0.05 Non-detect 0.05 Non-detect 1 1 1 1 1 1 0.01 Non-detect 0.01 Non-detect 0.02 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 0.5 0.5

**27** 03/13/14 03/14/14 Suspension Suspension

7000 7000 3

03/15/14 03/16/14 IA-009 IA-010 IAS-027 IAS-028 40.01 Non-detect 0.01 Non-detect 0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

5 10 0.1 0.5 8 1 2 1 1 0.5 0.5 6 8 0.1 0.05 Non-detect 0.07 Non-detect 1 0.05 Non-detect 1 1 1 0.01 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 **28 29**  03/14/14 03/15/14 Suspension Suspension

7000 7000 3 3

03/17/14 03/16/14 IA-010 IA-010 IAS-029 IAS-028 4 40.01 Non-detect 0.05 Non-detect 2 3 1**Concentration**

**(ppmw) Non-Detect?**  **Note(s)**

5 10 0.1 0.5 8 1 2 1 1 0.5 0.5 6 8 0.1 0.05 Non-detect 0.07 Non-detect 1 0.05 Non-detect 1 1 1 0.01 Non-detect 0.02 Non-detect 0.01 Non-detect 0.01 Non-detect 0.5 0.5 **30**

03/16/14 Suspension

7000 3

03/18/14 IA-010 IAS-030 40.01 Non-detect 0.05 Non-detect 2 3 1**FORM E-1-a**

**PROCESS WA STEWA**  **TER**

**Instructions**

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC process wastewater treatment system (identified in Form B-3). 3. For each wastewater steam stripper identified in Table 2 of Form B-3, provide the requested information in Table 3 below. 4. In Table 5, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

. 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 2** 

W- 1 W- 2 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a control device, a piece of recovery equipm ent, or process equipment and is not treated to reduce the concentration of vinyl chloride or any other HAP before being discharged from the PVC production facility

.

**Name of PVC Process Wastewater Stream**

Centrifuge Off W ater Condenser Pot Purge **1**

**PVC Process Wastewater Stream ID** 

(W-x...ID should match those provided in the process flow diagram)**Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System 1**  **2 3**  **4 5** 

**Min Ma** **x**

**Table 3. Wastewater Steam Strippers**

**1 2**  **3 4**  **5 6**  **7 8**  **9 10**  **11 12**  **13 14**  **15 16**  **17 18**  **19 20**  **21**

**Table 4. PVC Process Wastewater Destination Codes Table**

Onsite wastewater treatment system with biological treatment process **Destination Description PVC Process**  **Wastewater Treatment**  **System ID PVC Process**  **Wastewater Stream ID** 

(W-x...ID should match those provided in the process flow diagram) **Is this process wastewater**  **treatment system batch or continuous**  **operation? PVC Process Wastewater Stream Flow Rate (gallons**  **per day)**

PVC Process W astewater Treatment Equipment ID:

Wa stewater Maximum Design Feed Rate for Batch Strippers (liters) Wa stewater Maximum Design Feed Rate (liters/hr): Wa stewater Maximum Design Feed Rate (lb/hr):

Steam to Feed Ratio (kg steam/liter of wastewater): Steam Feed Rate (lb/hr): Feed Inlet Pressure (psia): Feed Temperature (°F): Wa stewater Operating Feed Rate for Batch Strippers (liters) Wa stewater Operating Feed Rate (lb/hr):

Operating Temperature (°F): Operating Pressure (psig): Total Number of Stages:

**1** Equipm ent Currently

Regulated Under (cite regulations): Year Equipm ent Installed: Stripping Factor: Overall Calculated Tray Efficiency :

Colum n Height (meters): Number of Actual Trays: Flow configuration (countercurrent, cocurrent): Wa stewater Operating Feed Rate (liters/hr):Onsite wastewater treatment system without biological treatment process

Discharge without treatment by pipeline, sewer, or other conveyance to surface water Discharge to POTW , no treatment Discharge to PrOTW , no treatment Zero discharge or alternative disposal method Recycle to process Other

**Table 5. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 2** 

**Min Process Wastewater Stream Flow Rate (gallons per day)**  **Source of Process Wastewater Stream**

**1**2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC process wastewater treatment system (identified in Form B-3). 3. For each wastewater steam stripper identified in Table 2 of Form B-3, provide the requested information in Table 3 below. 4. In Table 5, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 3**  **4 5**  **6 7** 

**Min Ma** **x Av**  **erage** 100 10000 8000 Estimated 350 10 100 75 Estimated 350 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a control device, a piece of recovery equipm ent, or process equipment and is not treated to reduce the concentration of vinyl chloride or any other HAP before being discharged from

**Operating Days Per Year**  **Flow Rate Determination**  **Me thod**  **PVC Process Wastewater Stream Flow Rate**

**(gallons per day) 6**  **7 8**  **9 10** 

**Av erage** 

**2 Code**  OSW WT -w-Biotrt **PVC Process Wastewater**  **Stream Destination**  **Code**

(Refer to Table 4 below) **PVC Process Wastewater Stream Flow Rate (gallons Flow Rate**  **Determination Me**  **thod As**  **sociated Destination**  **Information**

(Refer to Table 3 below) **Operating Days Per Year** OSW WT -w/o-Biotrt SW POTW RAW PrOTW RAW ZEROALT RECYC OTHER

**Table 5. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 3**  **4 5**  **6 7** 

**Ma x**  **Av erage**  **Flow Rate Determination**  **Me thod**  **PVC Process Wastewater Treatment**  **System ID Operating Days**  **Per Year Process Wastewater Stream Flow Rate (gallons per day)** 4. In Table 5, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**8 9** 

Process Equipment U-5 Recovery

Equipm ent RE-3 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a control device, a piece of recovery equipm ent, or process equipment and is not treated to reduce the concentration of vinyl chloride or any other HAP before being discharged from

**Ty pe of Originating**  **Equipment/Device Originating PVC Equipment/Device**  **ID 11** 

Provide nam e of the wastewater treatment system **Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 Is this PVC process wastewater**  **stream exposed to the atmosphere at any point between the outlet of**  **the PVC process wastewater treatment system and its**  **destination?**

**3**Provide nam e of the wastewater treatment system

Provide nam e of outfall Provide nam e of POTW Provide nam e of PrOTW Describe method Describe where in the process the stream is recycled Describe**10 11** 

OSW WT -w-Biotrt Onsite Shared Bio-Treatment Plant OSW WT -w-Biotrt Onsite Shared Bio-Treatment Plant 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a control device, a piece of recovery equipm ent, or process equipment and is not treated to reduce the concentration of vinyl chloride or any other HAP before being discharged from

**PVC Process Wastewater Stream Destination Code** 

(Refer to Table 4 below) **As sociated Destination Information** **Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**

**3 12** 

Yes Yes **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the originating PVC process equipment**  **and its destination? FORM E-1-b** 

**MA INTENA**  **NCE WA STEWA**  **TER**

Is your facility subject to any Federal, State, local or other requirements to collect, store, treat, or otherwise handle maintenance wastewater? No

If "Yes," please provide the regulation citation or permit requirement as appropriate:

(If you answered "No," please provide responses to the questions below). Provide a detailed description of the activities that create maintenance wastewater.

Procedures followed to collect, handle, manage, and treat maintenance wastewater? Include any further processing steps.

Is the maintenance wastewater exposed to the atmosphere at any point?

Describe procedure for controlling HAP emissions from the maintenance wastewater (if any): Reactor cleanouts and silo washdowns.

All water collected in plant drainage system, sent to onsite bio-treatment system

Yes, at generation and transport to onsite bio-treatment.

Maintenance wastewater is sent to onsite bio-treatment system.

Page 1 of 1 **DRA FT** PVC Section 114 Survey Part 2 06/23/2009**FORM E-2-a**

**30 DA Y PVC PROCESS WA** **STEWA TER SA** **MP LING A** **ND A NA** **LYSIS DA TA** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of Form 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of 40 CFR Part 63) in the table below. 5. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 6. Enter any

notes or additional information relevant to the sampling or analysis. 7. Refer to Attachment B of Enclosure 1 "Summary of Test Procedures, Methods, and Reporting Requirements For Resin and Process W astewater Sampling and Analysis at Poly vinyl Chloride and Copoly me r (PVC) Facilities" for additional instructions and information.

**PVC Process Wastewater Treatment System ID**

**CA S No.**  **HA P** 

107211 Ethylene glycol 67561 Methanol 75070 Acetaldehyde 50000 Formaldehyde 51285 2,4-dinitrophenol 98862 Acetophenone 117817 Bis(2-ethylhexyl) phthalate (DEHP) 123319 Hydroquinone 108952 Phenol 79345 1,1,2,2-tetrachloroethane 106990 1,3-butadiene 540841 2,2,4-trimethylpentane 71432 Benzene 108907 Chlorobenzene 67663 Chloroform 126998 Chloroprene 98828 Cumene 75003 Ethyl chloride (Chloroethane) 100414 Ethylbenzene 107062 Ethylene dichloride (1,2-Dichloroethane) 75343 Ethylidene dichloride (1,1-Dichloroethane) 74873 Methyl chloride (Chloromethane) 75092 Methylene chloride 110543 n-Hexane 108883 Toluene 71556 Methyl chloroform (1,1,1-Trichloroethane) **If Other, Please Provide a Description of the Resin Type --> Stream Flow Rate Exiting the Treatment System (gallons per minute) -->**  **Resin Type (suspension, dispersion, bulk, etc.) -->**79005 1,1,2-Trichloroethane 108054 Vinyl acetate 593602 Vinyl bromide 75014 Vinyl chloride 75354 Vinylidene chloride (1,1-Dichloroethylene) 1330207 Xylenes (isomers and mixtures)**30 DA Y PVC PROCESS WA** **STEWA TER SA** **MP LING A** **ND A NA** **LYSIS DA TA** 

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of Form 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of 40 CFR Part 63) in the table below. 5. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 6. Enter any

notes or additional information relevant to the sampling or analysis. 7. Refer to Attachment B of Enclosure 1 "Summary of Test Procedures, Methods, and Reporting Requirements For Resin and Process W astewater Sampling and Analysis at Poly vinyl Chloride and Copoly me r (PVC) Facilities" for additional instructions and information.

WWT -1

**An alysis M**  **ethod Concentration**  **(ppmw) Non-Detect?** 

SW -846-8015C 500 SW -846-8015C 10000 SW -846-8315A 50 SW -846-8315A 75 SW -846-8270D 10 SW -846-8270D 5 SW -846-8270D 10 SW -846-8270D 15 SW -846-8270D 23 SW -846-8260B 25.1 SW -846-8260B 26.2 SW -846-8260B 15.4 SW -846-8260B 13.4 SW -846-8260B 7.5 SW -846-8260B 7.9 SW -846-8260B 8.5 SW -846-8260B 15.8 SW -846-8260B 5.2 SW -846-8260B 0.01 Non-detect SW -846-8260B 0.01 Non-detect SW -846-8260B 0.01 Non-detect SW -846-8260B 0.02 SW -846-8260B 0.03 SW -846-8260B 10 SW -846-8260B 0.05 SW -846-8260B 15 **If Other, Please Provide a Description of the Resin Type --> Sample Date -->**  Suspension

**Lab Sample ID --> Lab Report ID -->**  **An alysis Date -->**  **Stream Temperature (degrees F) --> Stream Flow Rate Exiting the Treatment System (gallons per minute) -->**  **Resin Type (suspension, dispersion, bulk, etc.) -->**

155 5 02/15/14

IAS-001 IA-001 02/17/14 **Flow Rate Determination Method -->** MeasuredSW -846-8260B 2

SW -846-8260B 5 SW -846-8260B 10 EPA Method 107 2 SW -846-8260B 3 SW -846-8260B 51. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of Form B-3

. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

5. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

7. Refer to Attachment B of Enclosure 1 "Summary of Test Procedures, Methods, and Reporting Requirements For Resin and Process W astewater Sampling and Analysis at Poly vinyl Chloride and Copoly me r (PVC) Facilities" for additional instructions and information.

**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

500 10000 50 75 10 5 10 15 23 25.1 26.2 15.4 13.4 7.5 7.9 8.5 15.8 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.03 10 0.05 15 Suspension Suspension

02/18/14

IAS-002 **1 2** 

155 6.5 02/16/14

IA-001 Measured Measured2 5 10 2 3 57. Refer to Attachment B of Enclosure 1 "Summary of Test Procedures, Methods, and Reporting Requirements For Resin and Process W astewater Sampling and Analysis at Poly vinyl Chloride and Copoly me r (PVC) Facilities" for additional instructions and information.

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect?**

500 500 10000 10000 50 50 75 75 10 10 5 5 10 10 15 15 23 23 25.1 25.1 26.2 26.2 15.4 15.4 13.4 13.4 7.5 7.5 7.9 7.9 8.5 8.5 15.8 15.8 5.2 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.02 0.03 0.03 10 10 0.05 0.05 15 15

Suspension Suspension

02/19/14

IAS-003 IAS-004 **3**

155 155 5 4 02/18/14 02/17/14

02/20/14 IA-001 IA-001 Measured Measured2 2 5 5 10 10 2 2 3 3 5 5**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

500 10000 50 75 10 5 10 15 23 25.1 26.2 15.4 13.4 7.5 7.9 8.5 15.8 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.03 10 0.05 15 Suspension Suspension

IAS-005 **4 5** 

155 5 02/19/14

02/21/14 IA-001 Measured Measured2 5 10 2 3 5**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

500 500 10000 10000 50 50 75 75 10 10 5 5 10 10 15 15 23 23 25.1 25.1 26.2 26.2 15.4 15.4 13.4 13.4 7.5 7.5 7.9 7.9 8.5 8.5 15.8 15.8 5.2 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.02 0.03 0.03 10 10 0.05 0.05 15 15

Suspension Suspension

155 6 5

IAS-006 IAS-007 **6** 02/20/14 02/21/14

155 02/22/14 02/23/14 IA-002 IA-002 Measured Measured2 2 5 5 10 10 2 2 3 3 5 5**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

500 10000 50 75 10 5 10 15 23 25.1 26.2 15.4 13.4 7.5 7.9 8.5 15.8 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.03 10 0.05 15 Suspension Suspension

7 02/22/14 **7 8** 

155 02/24/14 IA-002 IAS-008 Measured Measured2 5 10 2 3 5**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

500 500 10000 10000 50 50 75 75 10 10 5 5 10 10 15 15 23 23 25.1 25.1 26.2 26.2 15.4 15.4 13.4 13.4 7.5 7.5 7.9 7.9 8.5 8.5 15.8 15.8 5.2 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.02 0.03 0.03 10 10 0.05 0.05 15 15

Suspension Suspension

Measured Measured 5 5 02/23/14 02/24/14 **9**

155 155 02/25/14 02/26/14 IA-002 IA-002 IAS-009 IAS-0102 2 5 5 10 10 2 2 3 3 5 5**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

500 10000 50 75 10 5 10 15 23 25.1 26.2 15.4 13.4 7.5 7.9 8.5 15.8 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.03 10 0.05 15 Suspension Suspension

Measured 4 Measured 02/25/14 **10 11** 

155 02/27/14

IAS-011 IA-0032 5 10 2 3 5**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

500 500 10000 10000 50 50 75 75 10 10 5 5 10 10 15 15 23 23 25.1 25.1 26.2 26.2 15.4 15.4 13.4 13.4 7.5 7.5 7.9 7.9 8.5 8.5 15.8 15.8 5.2 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.02 0.03 0.03 10 10 0.05 0.05 15 15

Suspension Suspension

4 5

155 155 Measured Measured 02/26/14 02/27/14 **12**

02/28/14 03/01/14

IAS-012 IAS-013 IA-003 IA-0032 2 5 5 10 10 2 2 3 3 5 5**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

500 10000 50 75 10 5 10 15 23 25.1 26.2 15.4 13.4 7.5 7.9 8.5 15.8 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.03 10 0.05 15 Suspension Suspension

6.5

155 Measured Measured **13 14**  02/28/14

03/02/14

IAS-014 IA-0032 5 10 2 3 5**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

500 500 10000 10000 50 50 75 75 10 10 5 5 10 10 15 15 23 23 25.1 25.1 26.2 26.2 15.4 15.4 13.4 13.4 7.5 7.5 7.9 7.9 8.5 8.5 15.8 15.8 5.2 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.02 0.03 0.03 10 10 0.05 0.05 15 15

Suspension Suspension

6

155 Measured **15** 03/01/14 03/02/14

155 Measured

03/03/14 03/04/14

IAS-015 IA-003 IA-003 IAS-016 72 2 5 5 10 10 2 2 3 3 5 5**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

500 10000 50 75 10 5 10 15 23 25.1 26.2 15.4 13.4 7.5 7.9 8.5 15.8 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.03 10 0.05 15 Suspension Suspension **17 16**  03/03/14

Measured Measured 155

IA-004 IAS-017 03/05/14 82 5 10 2 3 5**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

500 500 10000 10000 50 50 75 75 10 10 5 5 10 10 15 15 23 23 25.1 25.1 26.2 26.2 15.4 15.4 13.4 13.4 7.5 7.5 7.9 7.9 8.5 8.5 15.8 15.8 5.2 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.02 0.03 0.03 10 10 0.05 0.05 15 15

Suspension Suspension **18** 03/05/14 03/04/14

Measured Measured 155 155 03/07/14 IA-004 IA-004 IAS-018 IAS-019 03/06/14 5 42 2 5 5 10 10 2 2 3 3 5 5**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

500 10000 50 75 10 5 10 15 23 25.1 26.2 15.4 13.4 7.5 7.9 8.5 15.8 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.03 10 0.05 15 Suspension Suspension **19 20**  03/06/14

5 Measured Measured 155 03/08/14 IA-004 IAS-0202 5 10 2 3 5**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

500 500 10000 10000 50 50 75 75 10 10 5 5 10 10 15 15 23 23 25.1 25.1 26.2 26.2 15.4 15.4 13.4 13.4 7.5 7.5 7.9 7.9 8.5 8.5 15.8 15.8 5.2 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.02 0.03 0.03 10 10 0.05 0.05 15 15

Suspension Suspension **21** 03/07/14 03/08/14

155 Measured Measured 155

IA-004 03/10/14 03/09/14 5 5

IAS-021 IAS-022 IA-0052 2 5 5 10 10 2 2 3 3 5 5**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

500 10000 50 75 10 5 10 15 23 25.1 26.2 15.4 13.4 7.5 7.9 8.5 15.8 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.03 10 0.05 15 Suspension Suspension

Measured Measured 155 03/11/14 5

IAS-023 IA-004 03/09/14 **22 23** 2 5 10 2 3 5**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

500 500 10000 10000 50 50 75 75 10 10 5 5 10 10 15 15 23 23 25.1 25.1 26.2 26.2 15.4 15.4 13.4 13.4 7.5 7.5 7.9 7.9 8.5 8.5 15.8 15.8 5.2 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.02 0.03 0.03 10 10 0.05 0.05 15 15

Suspension Suspension

155 03/12/14 03/13/14 IA-005 IA-006 IAS-024 IAS-025 5 5 03/10/14 03/11/14 **24**

155 Measured Measured2 2 5 5 10 10 2 2 3 3 5 5**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

500 10000 50 75 10 5 10 15 23 25.1 26.2 15.4 13.4 7.5 7.9 8.5 15.8 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.03 10 0.05 15 Suspension Suspension **26** 03/12/14 **25**

Measured 5

155

IAS-026 03/14/14 IA-005 Measured2 5 10 2 3 5**Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?** 

500 500 10000 10000 50 50 75 75 10 10 5 5 10 10 15 15 23 23 25.1 25.1 26.2 26.2 15.4 15.4 13.4 13.4 7.5 7.5 7.9 7.9 8.5 8.5 15.8 15.8 5.2 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.02 0.03 0.03 10 10 0.05 0.05 15 15

Suspension Suspension **27** 03/13/14 03/14/14

6 8

155 155

IAS-027 IAS-028 03/15/14 03/16/14 IA-006 IA-006 Measured Measured2 2 5 5 10 10 2 2 3 3 5 5**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

500 10000 50 75 10 5 10 15 23 25.1 26.2 15.4 13.4 7.5 7.9 8.5 15.8 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.03 10 0.05 15 Suspension Suspension **28**

IA-006 IAS-029 **29** 03/15/14

7

155 03/17/14 Measured Measured2 5 10 2 3 5**Concentration**

**(ppmw) Non-Detect?**  **Note(s)**

500 10000 50 75 10 5 10 15 23 25.1 26.2 15.4 13.4 7.5 7.9 8.5 15.8 5.2 0.01 Non-detect 0.01 Non-detect 0.01 Non-detect 0.02 0.03 10 0.05 15 Suspension

03/18/14 IA-006 Measured

IAS-030 **30** 03/16/14

5

1552 5 10 2 3 5**FORM E-2-b**

**30 DA Y PVC PRODUCTION PROCESS WA** **STEWA TER SA** **MP LING PRODUCTION DA**  **TA**

**Instructions**

1. Please complete this worksheet for your PVC production facility

. 2. For the complete time period covering your PVC process wastewater treatment system(s) sampling, provide the total resin production from your PVC production facility

.

4. Refer to "Enclosure 1" for additional instructions and details.

1.) Sampling Start Date: 2/15/2014

2.) Sampling End Date: 3/16/2014

3). Total resin production from sampling start date to sampling end dateand the type of resin produced:

3.a.) Total Resin Produced: 210000

3.b.) Resin Type Produced: Suspension

3.c.) If Other, Specify :

4.a.) Total Resin Produced: 7000

4.b.) Days of Production: 1

4.b.) Resin Type Produced: Suspension

4.c.) If Other, Specify :

5.) Total DAILY maximum PVC production capacity : 10000 3. If the process wastewater treatment system(s) is/are treating process wastewater that was generated by the PVC production facility PRIOR to the start of the sampling period, then also include the amount of resin produced during the period prior to the start of sampling and indicate how many days of production that represents.

4.) Total resin produced and number of days of production prior to the start of the sampling period generated by

the process and treated during the sampling period :2. For the complete time period covering your PVC process wastewater treatment system(s) sampling, provide the total resin production from your PVC production facility

.

and the type of resin produced:

pounds

pounds

days

pounds per day

(max) 3. If the process wastewater treatment system(s) is/are treating process wastewater that was generated by the PVC production facility PRIOR to the start of the sampling period, then also include the amount of resin produced during the period prior to the start of sampling and indicate how many days of production that represents.

prior to the start of the sampling period and for which process wastewater was**FORM F-1 CONTROL DEVICES - ABSORBER** 

**Instructions**

1. Complete the form for each absorber used as a control device within the PVC production facility, or for any absorber that emits directly to atmosphere. 2. Refer to "Enclosure 1" for additional instructions and details.

**1** Type of Equipment or Device Control Device **2** Equipment of Device ID C-1 **3 Type of Absorber**  Packed bed **4** If other, provide a description: **5** Gas inlet flow rate (dscfm): 2300 **6** Gas inlet temperature (°F): 170 **7** Pressure drop (in H 2 O): 10 **8** Liquid-to-gas ratio (gal/10 3acfm): 18 **Inlet scrubbing liquor 9**  Liquor used: Water **10** pH: 6.5 **11** Percent solids: 7 **12** Type of alkali added, if any: NaOH **13** Addition rate (lb/gal): 0.01 **14** Wa stewater generation rate (gal/min): 10

**15** Year Equipment Installed: 1985 **16** Equipment Currently Regulated Under (cite regulations): 40 CFR 61 Subpart F

Page 1 of 1 **DRAFT**PVC Section 114 Survey Part 1 06/23/2009**FORM F-2 CONTROL DEVICES - THERMAL OR CATALYTIC OXIDIZER** 

**1** Control Device ID: C-2 **2** Number of operating hours per year (hours/year): 8400 **3** Is this emergency equipment? No **4 Type**  (Thermal Oxidizer or Catalytic Oxidizer) Thermal Oxidizer **5** Oxidizer Inlet Flow Rate (dscfm): 2300 **6** Average percentage of total flow originating from the production facility: 10

**7** Combustion chamber temperature (°F): (please note if temperature

me asurement is not in chamber) 1800

**8** Excess air (%): 25 **9** Nominal residence time (s): 1.5 **Heat recovery 10**  Recuperative, percent heat recovery **11** Regenerative, percent heat recovery **12** Design Capacity (Heat Input) (MMBtu/hr): 5 **13** Fuel Basis for Design Capacity: Fuel Gas **14** Heat Release Rate (Btu/scf): 792 **15** Is the unit subject to NSPS? No **16** If yes, indicate the year: **Start-up Fuel/Material 17**  Start-up fuel: Fuel Gas **18** Number of start-ups per year: 2 **19** Typical length of time for start-up (hours): 16 **20** Higher heating value (HHV): 792 **Fuels/Materials Combusted During Normal Operations (include solid, liquid, and gas waste streams) 21**  Fuel 1: PVC Vent **22** Hours used per year: 8400 **23** Higher heating value (HHV): 421 **24** Fuel 2: EDC/VCM Vent **25** Hours used per year: 8400 **26** Higher heating value (HHV): 1600 **27** Fuel 3: Fuel Gas **28** Hours used per year: 8400 **29** Higher heating value (HHV): 792 **30** Fuel 4: Natural Gas **31** Hours used per year: 10 **32** Higher heating value (HHV): 993 **33** Fuel 5: **34** Hours used per year: **35** Higher heating value (HHV):

**36** Year Equipment Installed: 1985 **37** Equipment Currently Regulated Under (cite regulations): 40 CFR 61 Subpart F

Page 1 of 1 **DRAFT** PVC Section 114 Surv ey Part 1 06/23/2009**FORM F-3 CONTROL DEVICES - CONDENSERS** 

**Instructions**

1. Complete the form for each condenser used as a control device within the PVC production facility, or for any condenser that emits directly to atmosphere. 2. Refer to "Enclosure 1" for additional instructions and details.

**1** Type of Equipment or Device **2** Equipment of Device ID **3 Type of Condenser**  **4** If other, provide a description: **5** Is the condenser refrigerated?

**6** Describe the materials condensed:

**7** Describe the fate of the non-condensed gas stream:

**8** Describe the fate of the condensate outlet stream:

**9** Gas inlet flow rate (dscfm): **10** Gas inlet temperature (° F): **11** Gas outlet temperature (° F): **12** Liquid outlet for rate (gpm):

**15** Year Equipment Installed: **16** Equipment Currently Regulated Under (cite regulations):

Page 1 of 1 **DRAFT**PVC Section 114 Survey Part 1 06/23/2009**FORM G**

**COOLING TOWERS A ND HEA**  **T EXCHA NGE SYSTEMS** 

**Instructions**

3. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.a Cooling Tower Identification** Cooling Tower ID U-8 Total CT Return Flow Rate (gal/min): 20,000 Number of processes served by cooling tower: 7

Number of these from a PVC production process unit: 7 Is the heat exchange system

mo nitored for the presence of one or more HAP or VOC in the cooling water? Yes

**Table 1.b Cooling Tower Emission Reductions** For this cooling tower (if the single combined inlet line is monitored), ORfor each heat exchange system from a PVC process unit (if individual CT return lines are monitored individually ), please provide the following:

(list sequentially

beginning with "H1")

H-1 No 1. Please complete one worksheet for each cooling tower, providing as much of the requested information as possible. Copy and paste additional worksheets for each cooling tower. 2. Using the table beginning on row 23, provide the requested information for the cooling tower. If only the single combined inlet line is monitored, you may delete rows 31 through 36 and enter information for the cooling tower. If cooling tower return lines are monitored individually , please provide information for each process. Identify the PVC process in column A. Copy and paste more rows to the table to add additional processes.

PVC HTEX System No.

Is the heat exchange system currently regulated? If Yes, cite the regulation(s):[ADD MORE ROW S TO THIS TABLE FOR ADDITIONAL HTEX SYSTEMS FOR THIS COOLING TOW ER]**Table 2. Once-through Heat Exchange Systems** No

for each heat exchange system from a PVC process unit (if individual CT return lines are monitored individually ), please provide the following:

**(gal/min)** (list speciation and/or group) (e.g., continuous, daily

,

weekly , monthly , yearly

, other) (e.g., visual

inspection, surrogate

mo nitoring, water sampling, air stripping, other) (e.g., EPA

Method 601, EPA Method 624, Mod El Paso, etc.)

20,000 Vinyl chloride weekly water sampling EPA Method 107 Ethylene dichloride (1,2- Dichloroethane) weekly water sampling EPA Method 8260B (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) 1. Please complete one worksheet for each cooling tower, providing as much of the requested information as possible. Copy and paste additional worksheets for each cooling tower.

Does your PVC production facility use any once-through heat exchange systems? 2. Using the table beginning on row 23, provide the requested information for the cooling tower. If only the single combined inlet line is monitored, you may delete rows 31 through 36 and enter information for the cooling tower. If cooling tower return lines are monitored individually , please provide information for each process. Identify the PVC process in column A. Copy and

CT Return Flow Rate for HTEX System List ALL Compounds Analy zed: Monitoring frequency Type of

mo nitoring Monitoring,

sampling, or air stripping analysis(select HAP) [ADD MORE ROW S TO THIS TABLE FOR ADDITIONAL HTEX SYSTEMS FOR THIS COOLING TOW ER]for each heat exchange system from a PVC process unit (if individual CT return lines are monitored individually ), please provide the following:

Value Unit

(provide the

num eric MDL) (provide the

MDL units) (CT inlet, outlet,

both) **(ppbw) (days)**  **(ppbw) (days)** 

0.01 ppm w CT inlet 500 10 50 20

0.01 ppm w CT inlet 500 10 50 20 Leak Repair Threshold Repair Time for

Normal Leak Events Em ission Reduction Measures

MDL Monitoring

Location Delay of Repair Threshold Repair Time for

Delayed Repairs**(#) (days)** 

2 15 Number of Leaks in 2013 Total

Duration of All Repairs Leaks in 2013**FORM H EQUIPMENT LEAKS** 

**Instructions**

1. Submit a copy of the leak detection and repair procedures for the PVC production facility and provide responses to the questions below. 2. Refer to "Enclosure 1" for additional instructions and details.

**Table 1. LDAR Program**

Yes

Yes No

No

$10,000

**Table 2. Equipment Counts**

**In Source Category**  **Subtotal of Equipment Associated**

**with Closed Vent System(s)** (Subset of count in source category)

50 13 5 0

20 0 4 0

100 25 10 0

1 0 10 0

75 15 5 0 100 10 10 0 10 2 80 21 Is there an equipment leak detection and repair (LDAR) program for all equipment at your facility included in the source category? If "No," how are equipment leaks detected and repaired?

If "Yes," is the equipment subject to the requirements of: 40 CFR Part 63, Subpart UU

Valves

In heavy liquid service

In light liquid service Pumps 40 CFR Part 61, Subpart V Other Federal LDAR Regulation Specify: State LDAR Regulation Specify: Provide the total cost to your facility for conducting the LDAR program at this process unit in 2013:

**Equipment**

In heavy liquid service In gas, vapor, and light liquid service

In liquid service In gas and vapor service Pressure Relief Devices

Open ended valves and lines Sampling connection systems Compressors Instrumentation systems

In heavy liquid service In gas, vapor, and light liquid service Connectors

In heavy liquid service In gas, vapor, and light liquid service Agitators

Page 1 of 1 **DRAFT** PVC Section 114 Survey Part 1 06/23/2009**FORM J**

**OFF-SPECIFICATION RESIN AND MATERIAL REMOVAL FROM EQUIPMENT**

**Instructions** 1. Complete this form for 2013 only.

3. Provide copies of estimation worksheets and any other relevant documentation. 4. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., in-line filters). 5. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**

Source Equipment Type: Process Equipment Source Process Equipment ID (if applicable): U-3 Equipment Description: Total Pounds of Material Removed in 2013 ( do not include the contribution of water or other fluids(s) to remove the material from the equipment) : 200

Describe the procedure for removal of the material from equipment:

Is the material exposed to the atmosphere at any point during or after removal from the equipment?

Describe procedure for controlling HAP emissions from the material during and after removal from the equipment:

Describe the fate/disposition of the material beginning from the time it is removed from the equipment. Include any further processing steps.

**Table 2.**

Minimum Maximum Average

Vinyl chloride 0.01 1 0.05 Acetaldehyde 0.01 5 1 **Notes** Yes 2. This form covers resin that is removed from equipment and is not processed further through the normal processing steps. Examples include, but are not limited to, off-specification resin removed from the polymerization reactor or any other downstream process equipment, resin removed from equipment during maintenance and cleanout operations, etc.

**Concentration in Resin or Resin Slurry Immediately Prior to Removal From Equipment and Before Being Mixed**  **With Other Materials or Fluids (ppmw)** Inside of reactor is hydroblasted. Resin is collected via filters installed on reactor wash-out drain. Resin is allowed to dry and packaged and sold as off-spec material.

Reactor is subject to multiple steam purges and vacuum drawn downs before opening equipment. This results in "stripping" of the resin remaining in the reactor.

Resin is allowed to dry and packaged and sold as off-spec material.

**Individual HAP Present**

Page 1 of 2 **DRAFT**PVC Section 114 Survey Part 2 06/23/2009Chloroform 0.05 5 1 Acetophenone 0.01 2 0.05 (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP)

Page 2 of 2 **DRAFT**PVC Section 114 Survey Part 2 06/23/2009**FORM K-1**

**TA NKS, VESSELS A** **ND PORTA BLE CONTA** **INERS USED FOR FEEDSTOCK STORA GE, PRODUCT STORA** **GE, VENT GA S STORA** **GE, HOLDING, A ND WA**  **STEWA TER** 

**Instructions** 1. Complete this form for 2013 only. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers). 4. Do not include gas holders on this form. Complete Form K-2 for gas holders. 4. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**

VCM Storage Bullets

25 50 65

**Table 2.**

**Vapor Pressure Total Emissions**  (in H2O) Minimum Maximum Average **(pounds)** Vinyl chloride 1391 99 100 99.1 0 (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) Source Equipment Type:

Number of turnovers: Equipment volume (m 3 ):

**Notes** Storage Temperature (°F)

If Yes, How Are The Emissions Controlled? Displaced vapor during filling is routed to VCM recovery system.

**Concentration (ppmvd @ 3% O2)** How is the HAP Concentration Determined? Equipment is VCM storage - all material stored is HAP. Are HAP Emissions Controlled? Ye s

**Individual HA P Present**  VCM Storage Bullet - pressure vessel

Feedstock storage

If Other, please specify, being as descriptive as possible: Source Process Equipment ID (if applicable): Equipment Description: If not provided in the equipment description above, describe the tank, vessel, or container and indicate (if applicable) if the tank is a fixed, floating internal, or floating external roof.

Select the purpose of the equipment:

Page 1 of 1 **DRAFT**PVC Section 114 Survey Part 2 06/23/2009**FORM K-2**

**GA S HOLDERS** 

**Instructions** 1. Complete this form for 2013 only

. 2. Provide copies of estimation worksheets and any other relevant documentation. 3. Refer to "Enclosure 1" for additional instructions and details.

**Table 1.**

Ye s 1 Ye s

**Table 2.**

**Vapor Pressure Total Emissions** 
(in H2O) **(pounds)** Vinyl chloride 1391 5 (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) (select HAP) **Notes**

Emissions based on engineering calculations Does your PVC production facility use gas holders: Indicate the number of gas holders in use at your PVC production facility : Are HAP Emissions Controlled? If Yes, How Are The Emissions Controlled? Seal water is covered with a floating mat that reduces VCM loss.

**Individual HA P Present** 

Page 1 of 1 **DRA FT** PVC Section 114 Survey Part 2 06/23/2009**FORM L STARTUP, SHUTDOWN, AND MALFUNCTION** 

**Instructions**

1. Complete this form for 2013 only. 2. Submit with your response to this survey, copies of all records of emissions during periods of process startup, shutdown, and malfunctions for 2013 only. 3. Refer to "Enclosure 1" for additional instructions and details.

Yes

Startup Shutdown 32 24

For a malfunction:

Yes Yes

No No

40 CFR Part 61 Subpart F 40 CFR Part 61 Subpart F

Control equipment (thermal oxidizer and scrubber) is brought online before startup begins. Control equipment (thermal oxidizer and scrubber) is kept online until plant is completely shutdown.

Vinyl chloride (pounds) 0.02 0.02 Hydrochloric acid (pounds) 0.05 0.05 Methylene chloride (Dichloromethane) (pounds) 0.01 0.01 (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) (select HAP) (pounds) Is there a written startup, shutdown and/or malfunction plan for the process unit?
Provide a description of the systems and equipment in place that function to notify operators that a malfunction **is occurring**

. Pressure monitors on reactors with high, high-high alarms. All PRDs are "backed" by rupture disks - vapor space between is monitored for pressure and alarms when > atmospheric detected. Thermal oxidizer bypass has a flow detector which alarms to operator whenever flow is detected in the bypass.

Applicable standard or regulation:

Describe what actions, if any, were taken to minimize emissions to the atmosphere:

**Total Emissions During Startup, Shutdown, or Malfunction Event**  We re all of the emissions control devices operating for the entire duration of the startup, shutdown, or malfunction event? Startup, Shutdown or Malfunction?

If startup or shutdown, what was the duration (hours):

Provide a short description of the malfunction and the circumstances:

If No, which control devices were not operating (Control Equipment ID), for how long, and why:

We re permitted emissions limits exceeded?

Provide a description of the procedures used to alert the owner/operator that the malfunction occurred. If the malfunction resulted in a release of emissions, describe any indicators used to signal and/or measure the release.

Page 1 of 1 **DRAFT** PVC Section 114 Survey Part 1 06/23/2009**FORM M FACTORS THAT AFFECT HAP/VOC EMISSION REDUCTIONS** 

**Name of Unit Operation Description of process change or**  **other pollution prevention or source**

**reduction measure: Quantify emissions reductions (e.g. tons/year) resulting**  **from the use of pollution or source reduction measures:** VCM Recovery - Gasholder Installed seal water cover. Reduced VCM emissions by 15 pounds per year. For each unit operation for which pollution reduction or source reduction measures have resulted in a decrease in HAP/VOC emissions since 1976, provide the following information.

If recovery or recycling of feedstocks is used, quantify the effect of the program (e.g., estimated annual purchase of feedstock in the absence of recovery/recycling compared to actual annual purchase):

Approximately 40,000 pounds of VCM is recovered/recycled back to process each year.

Are you aware of any alternative processes (e.g., feedstock substitutions or eliminations) or control devices or techniques that could result in fewer impacts between environmental media (water, air, and land) or reduced total release to all environmental media (e.g., reduced wastewater or solid waste)? Discuss whether these processes could be adapted to the polyvinyl chloride and copolymers production source category and any experience you have with them:

No.

Page 1 of 1 **DRAFT**PVC Section 114 Survey Part 1 06/23/2009**FORM N**

**MISCELLA NEOUS** 

If any control or process change described on Form M was instituted as a result of new source review requirements pursuant to 40 CFR 51.160, Subpart I, Review of New Sources and Modifications, provide the date at which the lowest achievable emission rate (LAER) came into effect:

Not Applicable

Describe any

factors not addressed in the questions in this survey that might serve to distinguish your facility from others in this source category for purposes of developing a separate source category or subcategory

and MACT standards:

Our facility

operates under a purchased technology license from the "W e Make All Chemicals" company ; therefore we are very similar to several other PVC Suspension resin producing facilities. W e are unaware of any particular process or factor that would warrent subcategorization.

Page 1 of 1 **DRA FT** PVC Section 114 Survey Part 1 06/23/2009