FORM A-1

COMPANY INFORMATION

I. Parent Company / Legal Corporate Owner Information

1. Legal Parent Company / Legal Corporate Name Example Resins

2. Mailing Address 123 Example Resins Rd

3. City Anytown

4. State North Carolina 

5. Zip Code 28590

6. County Any County

501-750

7. Size of Company (approximate number of employees 

including all subsidiaries, branches, and related 

establishments owned):

Page 1 of 1

DRAFT PVC Section 114 Survey Part 1

06/23/2009
FORM A-2

FACILITY INFORMATION

II. Polyvinyl Chloride and Copolymers (PVC) Production Facility Information

1. Facility Name Example Resins Sometown

Facility Address

a. Street 123 Any Road Way

b. City Sometown

c. State Louisiana 

d. Zip Code 70767

e. County Any Parish

Facility Coordinates (Decimal Degrees to the 5th decimal place)

f. Latitude 35.72154

g. Longitude -79.17732

2. Number of employees attached to the PVC 

production facility:

175

III. Technical Contact

1. Name John Doe

2. Technical Contact Title Environmental Manager

3. Telephone 1-234-567-8910

4. Facsimile 1-234-567-8910

5. Email John.Doe@ExampleResins.com

IV. Other

1. Is the facility a major source of HAP? Yes

2. If No, did the facility take a limit of its 

potential HAP emissions to avoid classification 

as a major source?

3. If the facility took a limit of its potential HAP 

emissions to avoid classification as a major 

source, provide the date on which the limit was 

taken (MM/DD/YYYY).

4. Does the facility manufacture other products 

in addition to PVC resin?

Yes

5. If Yes, list the other products manufactured 

at the facility.

Ethylene Dichloride, Vinyl Chloride Monomer

6. Are there any HAP emissions associated 

with any co-located facilities?

Yes

Page 1 of 1

DRAFT PVC Section 114 Survey Part 1

06/23/2009
FORM C

ECONOMIC LIFE AND APPLICABLE REGULATIONS FOR PVC PRODUCTION UNIT

Year Facility Commenced PVC Production: 1980 years

Remaining Economic Life PVC Production Unit: 50 years

Table 1. Federal, State, and Local Regulations (list, include all regulations that apply to any part of the process unit)

Table 2. Federal, State, and Local Permits

LA01251356 Louisiana Pollutant Discharge Elimination System Permit Water, Treated Process Waste Water, Treated Sanitary Wastewater, Stormwater and Hydrostatic Test Water 

LA05541321 Louisiana Pollutant Discharge Elimination System Permit - Statewide General Permit Discharges of Hydrostatic Test and Vessel Testing Wastewater

Permit ID Permit Type Regulated Process Equipment/Control Device/Recovery Equipment (list ID provided in Form B)

5648-V4 Title V/Part 70 Operating Permit Entire PVC Process

40 CFR 82 Refrigerant RE-3

40 CFR 63 NESHAP Subpart Q National Emission Standards For Hazardous Air Pollutants For Industrial Process Cooling Towers U-8

40 CFR 68 Chemical Accident Prevention Provisions Enitre PVC Process

40 CFR 63 NESHAP Subpart B NESHAP for Source Catagories - Requirements for Control Technology Determinations for Major Sources C-2

40 CFR 63 NESHAP Subpart H National Emission Standards for Organic Hazardous Air Pollutants for Equipment Leaks Enitre PVC Process

40 CFR 61 Subpart A National Emission Standards For Hazardous Air Pollutants - General Provisions Enitre PVC Process

40 CFR 61 Subpart F National Emission Standard For Vinyl Chloride Enitre PVC Process

40 CFR 60 NSPS Subpart A Standards of Performance For New Stationary Sources - General Provisions Enitre PVC Process

LAC 33:III. Chapter 9 General Regulations on Control of Emissions and Emission Standards C-2

LAC 33:III. Chapter 11 Control of Emissions of Smoke C-2

Regulation Citation Regulation Title Regulated Process Equipment/Control Device/Recovery Equipment (list ID provided in Form B)

LAC 33:III. Chapter 5 Permit Procedures C-2

LAC 33:III. Chapter 13 Emission Standards for Particulate Matter C-3, C-4

Page 1 of 1

DRAFT PVC Section 114 Survey Part 1

06/23/2009
FORM D-2

30 DAY RESIN SAMPLING - STRIPPER OUTLET(S)

Instructions

2. Do not submit partial data for any day: each day must include (at a minimum) concentration analysis results for all HA

3. Complete columns 1 through 30. Enter the sample date, resin type, daily resin production, number of samples compo

4. Provide the total daily production from the resin strippers samples for the type of resin. If your final product is sold as a 

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of 

5. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detecti

6. Enter any notes or additional information relevant to the sampling or analysis.

7. Refer to Attachment B of Enclosure 1 "Summary of Test Procedures, Methods, and Reporting Requirements For Res

CAS No. HAP

107211 Ethylene glycol

67561 Methanol

75070 Acetaldehyde

50000 Formaldehyde

51285 2,4-dinitrophenol

98862 Acetophenone

117817 Bis(2-ethylhexyl) phthalate (DEHP)

123319 Hydroquinone

108952 Phenol

79345 1,1,2,2-tetrachloroethane

106990 1,3-butadiene

540841 2,2,4-trimethylpentane

71432 Benzene

108907 Chlorobenzene

67663 Chloroform

126998 Chloroprene

98828 Cumene

75003 Ethyl chloride (Chloroethane)

100414 Ethylbenzene

107062 Ethylene dichloride (1,2-Dichloroethane)

75343 Ethylidene dichloride (1,1-Dichloroethane)

74873 Methyl chloride (Chloromethane)

75092 Methylene chloride

110543 n-Hexane

108883 Toluene

71556 Methyl chloroform (1,1,1-Trichloroethane)

79005 1,1,2-Trichloroethane

1. Complete the table below for each resin type produced by the facility during the 30 days of sampling. If the facility prod

not enter data for multiple resin types on a single worksheet.

Resin Type (suspension, dispersion, bulk, etc.) -->

Total Daily Resin Production Rate (lbs of resin per day from sampled resin strippers)

Number of Samples Composited for Analysis

Number of Resin Strippers Sampled to Obtain Composite

If Other, Please Provide a Description of the Resin Type -->
108054 Vinyl acetate

593602 Vinyl bromide

75014 Vinyl chloride

75354 Vinylidene chloride (1,1-Dichloroethylene)

1330207 Xylenes (isomers and mixtures)
st include (at a minimum) concentration analysis results for all HAP in Table 10 to Subpart HHHHHHH of 40 CFR Part 63.

date, resin type, daily resin production, number of samples composited, number of resin strippers sampled, analysis date, lab report ID, and 

pers samples for the type of resin. If your final product is sold as a dried resin, report production on a dry basis. If your final product is sold as 

re not listed in Table 10 to Subpart HHHHHHH of 40 CFR Part 63) in the table below.

such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

 the sampling or analysis.

Test Procedures, Methods, and Reporting Requirements For Resin and Process Wastewater Sampling and Analysis at Polyvinyl Chloride a

Analysis Method Concentration 

(ppmw) Non-Detect?

SW-846-8015C 5

SW-846-8015C 10

SW-846-8315A 0.1

SW-846-8315A 0.5

SW-846-8270D 8

SW-846-8270D 1

SW-846-8270D 2

SW-846-8270D 1

SW-846-8270D 1

SW-846-8260B 0.5

SW-846-8260B 0.5

SW-846-8260B 6

SW-846-8260B 8

SW-846-8260B 0.1

SW-846-8260B 0.05 Non-detect

SW-846-8260B 0.07 Non-detect

SW-846-8260B 1

SW-846-8260B 0.05 Non-detect

SW-846-8260B 1

SW-846-8260B 1

SW-846-8260B 1

SW-846-8260B 0.01 Non-detect

SW-846-8260B 0.02 Non-detect

SW-846-8260B 0.01 Non-detect

SW-846-8260B 0.01 Non-detect

SW-846-8260B 0.5

SW-846-8260B 0.5

ced by the facility during the 30 days of sampling. If the facility produced more than one resin type during the 30 days, create multiple copies 

Sample Date --> 02/15/14

Resin Type (suspension, dispersion, bulk, etc.) --> Suspension

ate (lbs of resin per day from sampled resin strippers) 7000

Number of Samples Composited for Analysis

mber of Resin Strippers Sampled to Obtain Composite

Analysis Date --> 02/17/14

Lab Report ID --> IA-001

Lab Sample ID --> IAS-001

her, Please Provide a Description of the Resin Type -->
SW-846-8260B 0.01 Non-detect

SW-846-8260B 0.05 Non-detect

EPA Method 1072

SW-846-8260B3

SW-846-8260B1
Subpart HHHHHHH of 40 CFR Part 63.

 resin strippers sampled, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

ort production on a dry basis. If your final product is sold as a wet resin report production on a wet basis.

, in the "Concentration (ppmw)" column.

Wastewater Sampling and Analysis at Polyvinyl Chloride and Copolymer (PVC) Facilities" for additional instructions and information.

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5

10

0.1

0.5

8

1

2

1

1

0.5

0.5

6

8

0.1

0.05 Non-detect

0.07 Non-detect

1

0.05 Non-detect

1

1

1

0.01 Non-detect

0.02 Non-detect

0.01 Non-detect

0.01 Non-detect

0.5

0.5

 one resin type during the 30 days, create multiple copies of this worksheet as necessary and complete one worksheet for each resin type. D

02/15/14 02/16/14

1 2

Suspension Suspension

7000 7000

3 3

02/17/14 02/18/14

IA-001 IA-001

IAS-001 IAS-002

4 4
0.01 Non-detect

0.05 Non-detect

2

3

1
 and information.

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 5

10 10

0.1 0.1

0.5 0.5

8 8

1 1

2 2

1 1

1 1

0.5 0.5

0.5 0.5

6 6

8 8

0.1 0.1

0.05 Non-detect 0.05 Non-detect

0.07 Non-detect 0.07 Non-detect

1 1

0.05 Non-detect 0.05 Non-detect

1 1

1 1

1 1

0.01 Non-detect 0.01 Non-detect

0.02 Non-detect 0.02 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.5 0.5

0.5 0.5

heet for each resin type. Do 

02/17/14 02/18/14

3

Suspension Suspension

7000 7000

3

02/19/14 02/20/14

IA-001 IA-002

IAS-003 IAS-004

4
0.01 Non-detect 0.01 Non-detect

0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5

10

0.1

0.5

8

1

2

1

1

0.5

0.5

6

8

0.1

0.05 Non-detect

0.07 Non-detect

1

0.05 Non-detect

1

1

1

0.01 Non-detect

0.02 Non-detect

0.01 Non-detect

0.01 Non-detect

0.5

0.5

4 5

02/18/14 02/19/14

Suspension Suspension

7000 7000

3 3

02/20/14 02/21/14

IA-002 IA-002

IAS-004 IAS-005

4 4
0.01 Non-detect

0.05 Non-detect

2

3

1
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 5

10 10

0.1 0.1

0.5 0.5

8 8

1 1

2 2

1 1

1 1

0.5 0.5

0.5 0.5

6 6

8 8

0.1 0.1

0.05 Non-detect 0.05 Non-detect

0.07 Non-detect 0.07 Non-detect

1 1

0.05 Non-detect 0.05 Non-detect

1 1

1 1

1 1

0.01 Non-detect 0.01 Non-detect

0.02 Non-detect 0.02 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.5 0.5

0.5 0.5

6

02/20/14 02/21/14

Suspension Suspension

7000 7000

3

02/22/14 02/23/14

IA-002 IA-003

IAS-006 IAS-007

4
0.01 Non-detect 0.01 Non-detect

0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5

10

0.1

0.5

8

1

2

1

1

0.5

0.5

6

8

0.1

0.05 Non-detect

0.07 Non-detect

1

0.05 Non-detect

1

1

1

0.01 Non-detect

0.02 Non-detect

0.01 Non-detect

0.01 Non-detect

0.5

0.5

7 8

02/21/14 02/22/14

Suspension Suspension

7000 7000

3 3

02/23/14 02/24/14

IA-003 IA-003

IAS-007 IAS-008

4 4
0.01 Non-detect

0.05 Non-detect

2

3

1
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 5

10 10

0.1 0.1

0.5 0.5

8 8

1 1

2 2

1 1

1 1

0.5 0.5

0.5 0.5

6 6

8 8

0.1 0.1

0.05 Non-detect 0.05 Non-detect

0.07 Non-detect 0.07 Non-detect

1 1

0.05 Non-detect 0.05 Non-detect

1 1

1 1

1 1

0.01 Non-detect 0.01 Non-detect

0.02 Non-detect 0.02 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.5 0.5

0.5 0.5

9

02/23/14 02/24/14

Suspension Suspension

7000 7000

3

02/25/14 02/26/14

IA-003 IA-004

IAS-009 IAS-010

4
0.01 Non-detect 0.01 Non-detect

0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5

10

0.1

0.5

8

1

2

1

1

0.5

0.5

6

8

0.1

0.05 Non-detect

0.07 Non-detect

1

0.05 Non-detect

1

1

1

0.01 Non-detect

0.02 Non-detect

0.01 Non-detect

0.01 Non-detect

0.5

0.5

10 11

02/24/14 02/25/14

Suspension Suspension

7000 7000

3 3

02/26/14 02/27/14

IA-004 IA-004

IAS-010 IAS-011

4 4
0.01 Non-detect

0.05 Non-detect

2

3

1
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 5

10 10

0.1 0.1

0.5 0.5

8 8

1 1

2 2

1 1

1 1

0.5 0.5

0.5 0.5

6 6

8 8

0.1 0.1

0.05 Non-detect 0.05 Non-detect

0.07 Non-detect 0.07 Non-detect

1 1

0.05 Non-detect 0.05 Non-detect

1 1

1 1

1 1

0.01 Non-detect 0.01 Non-detect

0.02 Non-detect 0.02 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.5 0.5

0.5 0.5

12

02/26/14 02/27/14

Suspension Suspension

7000 7000

3

02/28/14 03/01/14

IA-004 IA-005

IAS-012 IAS-013

4
0.01 Non-detect 0.01 Non-detect

0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5

10

0.1

0.5

8

1

2

1

1

0.5

0.5

6

8

0.1

0.05 Non-detect

0.07 Non-detect

1

0.05 Non-detect

1

1

1

0.01 Non-detect

0.02 Non-detect

0.01 Non-detect

0.01 Non-detect

0.5

0.5

13 14

02/27/14 02/28/14

Suspension Suspension

7000 7000

3 3

03/01/14 03/02/14

IA-005 IA-005

IAS-013 IAS-014

4 4
0.01 Non-detect

0.05 Non-detect

2

3

1
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 5

10 10

0.1 0.1

0.5 0.5

8 8

1 1

2 2

1 1

1 1

0.5 0.5

0.5 0.5

6 6

8 8

0.1 0.1

0.05 Non-detect 0.05 Non-detect

0.07 Non-detect 0.07 Non-detect

1 1

0.05 Non-detect 0.05 Non-detect

1 1

1 1

1 1

0.01 Non-detect 0.01 Non-detect

0.02 Non-detect 0.02 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.5 0.5

0.5 0.5

15

03/01/14 03/02/14

Suspension Suspension

7000 7000

3

03/03/14 03/04/14

IA-005 IA-006

IAS-015 IAS-016

4
0.01 Non-detect 0.01 Non-detect

0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5

10

0.1

0.5

8

1

2

1

1

0.5

0.5

6

8

0.1

0.05 Non-detect

0.07 Non-detect

1

0.05 Non-detect

1

1

1

0.01 Non-detect

0.02 Non-detect

0.01 Non-detect

0.01 Non-detect

0.5

0.5

16 17

03/02/14 03/03/14

Suspension Suspension

7000 7000

3 3

03/04/14 03/05/14

IA-006 IA-006

IAS-016 IAS-017

4 4
0.01 Non-detect

0.05 Non-detect

2

3

1
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 5

10 10

0.1 0.1

0.5 0.5

8 8

1 1

2 2

1 1

1 1

0.5 0.5

0.5 0.5

6 6

8 8

0.1 0.1

0.05 Non-detect 0.05 Non-detect

0.07 Non-detect 0.07 Non-detect

1 1

0.05 Non-detect 0.05 Non-detect

1 1

1 1

1 1

0.01 Non-detect 0.01 Non-detect

0.02 Non-detect 0.02 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.5 0.5

0.5 0.5

18

03/04/14 03/05/14

Suspension Suspension

7000 7000

3

03/06/14 03/07/14

IA-006 IA-007

IAS-018 IAS-019

4
0.01 Non-detect 0.01 Non-detect

0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5

10

0.1

0.5

8

1

2

1

1

0.5

0.5

6

8

0.1

0.05 Non-detect

0.07 Non-detect

1

0.05 Non-detect

1

1

1

0.01 Non-detect

0.02 Non-detect

0.01 Non-detect

0.01 Non-detect

0.5

0.5

19 20

03/05/14 03/06/14

Suspension Suspension

7000 7000

3 3

03/07/14 03/08/14

IA-007 IA-007

IAS-019 IAS-020

4 4
0.01 Non-detect

0.05 Non-detect

2

3

1
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 5

10 10

0.1 0.1

0.5 0.5

8 8

1 1

2 2

1 1

1 1

0.5 0.5

0.5 0.5

6 6

8 8

0.1 0.1

0.05 Non-detect 0.05 Non-detect

0.07 Non-detect 0.07 Non-detect

1 1

0.05 Non-detect 0.05 Non-detect

1 1

1 1

1 1

0.01 Non-detect 0.01 Non-detect

0.02 Non-detect 0.02 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.5 0.5

0.5 0.5

21

03/07/14 03/08/14

Suspension Suspension

7000 7000

3

03/09/14 03/10/14

IA-007 IA-008

IAS-021 IAS-022

4
0.01 Non-detect 0.01 Non-detect

0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5

10

0.1

0.5

8

1

2

1

1

0.5

0.5

6

8

0.1

0.05 Non-detect

0.07 Non-detect

1

0.05 Non-detect

1

1

1

0.01 Non-detect

0.02 Non-detect

0.01 Non-detect

0.01 Non-detect

0.5

0.5

22 23

03/08/14 03/09/14

Suspension Suspension

7000 7000

3 3

03/10/14 03/11/14

IA-008 IA-008

IAS-022 IAS-023

4 4
0.01 Non-detect

0.05 Non-detect

2

3

1
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 5

10 10

0.1 0.1

0.5 0.5

8 8

1 1

2 2

1 1

1 1

0.5 0.5

0.5 0.5

6 6

8 8

0.1 0.1

0.05 Non-detect 0.05 Non-detect

0.07 Non-detect 0.07 Non-detect

1 1

0.05 Non-detect 0.05 Non-detect

1 1

1 1

1 1

0.01 Non-detect 0.01 Non-detect

0.02 Non-detect 0.02 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.5 0.5

0.5 0.5

24

03/10/14 03/11/14

Suspension Suspension

7000 7000

3

03/12/14 03/13/14

IA-008 IA-009

IAS-024 IAS-025

4
0.01 Non-detect 0.01 Non-detect

0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5

10

0.1

0.5

8

1

2

1

1

0.5

0.5

6

8

0.1

0.05 Non-detect

0.07 Non-detect

1

0.05 Non-detect

1

1

1

0.01 Non-detect

0.02 Non-detect

0.01 Non-detect

0.01 Non-detect

0.5

0.5

25 26

03/11/14 03/12/14

Suspension Suspension

7000 7000

3 3

03/13/14 03/14/14

IA-009 IA-009

IAS-025 IAS-026

4 4
0.01 Non-detect

0.05 Non-detect

2

3

1
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

5 5

10 10

0.1 0.1

0.5 0.5

8 8

1 1

2 2

1 1

1 1

0.5 0.5

0.5 0.5

6 6

8 8

0.1 0.1

0.05 Non-detect 0.05 Non-detect

0.07 Non-detect 0.07 Non-detect

1 1

0.05 Non-detect 0.05 Non-detect

1 1

1 1

1 1

0.01 Non-detect 0.01 Non-detect

0.02 Non-detect 0.02 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.5 0.5

0.5 0.5

27

03/13/14 03/14/14

Suspension Suspension

7000 7000

3

03/15/14 03/16/14

IA-009 IA-010

IAS-027 IAS-028

4
0.01 Non-detect 0.01 Non-detect

0.05 Non-detect 0.05 Non-detect 2 2 3 3 1 1
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

5

10

0.1

0.5

8

1

2

1

1

0.5

0.5

6

8

0.1

0.05 Non-detect

0.07 Non-detect

1

0.05 Non-detect

1

1

1

0.01 Non-detect

0.02 Non-detect

0.01 Non-detect

0.01 Non-detect

0.5

0.5

28 29

03/14/14 03/15/14

Suspension Suspension

7000 7000

3 3

03/16/14 03/17/14

IA-010 IA-010

IAS-028 IAS-029

4 4
0.01 Non-detect

0.05 Non-detect

2

3

1
Concentration 

(ppmw) Non-Detect? Note(s)

5

10

0.1

0.5

8

1

2

1

1

0.5

0.5

6

8

0.1

0.05 Non-detect

0.07 Non-detect

1

0.05 Non-detect

1

1

1

0.01 Non-detect

0.02 Non-detect

0.01 Non-detect

0.01 Non-detect

0.5

0.5

30

03/16/14

Suspension

7000

3

03/18/14

IA-010

IAS-030

4
0.01 Non-detect

0.05 Non-detect

2

3

1
FORM E-1-a

PROCESS WASTEWATER

Instructions

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC process wastewater trea

3. For each wastewater steam stripper identified in Table 2 of Form B-3, provide the requested information in Table 3 be

4. In Table 5, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for ea

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System

2

W-1

W-2

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production faci

the PVC production facility.

Name of PVC Process Wastewater Stream

Centrifuge Off Water

Condenser Pot Purge

1

PVC Process 

Wastewater Stream ID

(W-x...ID should match 

those provided in the 

process flow diagram)
Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System

1 2 3 4 5

Min Max

Table 3. Wastewater Steam Strippers

1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

Table 4. PVC Process Wastewater Destination Codes Table

Onsite wastewater treatment system with biological treatment process

Destination Description

PVC Process 

Wastewater 

Treatment 

System ID

PVC Process 

Wastewater 

Stream ID

(W-x...ID should 

match those 

provided in the 

process flow 

diagram)

Is this process 

wastewater 

treatment system 

batch or continuous 

operation?

PVC Process Wastewater Stream Flow Rate (gallons 

per day)

PVC Process Wastewater Treatment Equipment ID:

Wastewater Maximum Design Feed Rate for Batch Strippers (liters)

Wastewater Maximum Design Feed Rate (liters/hr):

Wastewater Maximum Design Feed Rate (lb/hr):

Steam to Feed Ratio (kg steam/liter of wastewater):

Steam Feed Rate (lb/hr):

Feed Inlet Pressure (psia):

Feed Temperature (°F):

Wastewater Operating Feed Rate for Batch Strippers (liters)

Wastewater Operating Feed Rate (lb/hr):

Operating Temperature (°F):

Operating Pressure (psig):

Total Number of Stages:

1

Equipment Currently Regulated Under (cite regulations):

Year Equipment Installed:

Stripping Factor:

Overall Calculated Tray Efficiency:

Column Height (meters):

Number of Actual Trays:

Flow configuration (countercurrent, cocurrent):

Wastewater Operating Feed Rate (liters/hr):
Onsite wastewater treatment system without biological treatment process

Discharge without treatment by pipeline, sewer, or other conveyance to surface water

Discharge to POTW, no treatment

Discharge to PrOTW, no treatment

Zero discharge or alternative disposal method

Recycle to process

Other

Table 5. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System

2

Min

Process Wastewater Stream Flow Rate (g

Source of Process Wastewater Stream

1
a PVC process wastewater treatment system (identified in Form B-3).

ested information in Table 3 below.

ewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC 

atment System

3 4 5 6 7

Min Max Average

100 10000 8000 Estimated 350

10 100 75 Estimated 350

 within the PVC production facility that exits a control device, a piece of recovery equipment, or process equipment and is not treated to redu

Operating Days Per 

Year

Flow Rate 

Determination 

Method

PVC Process Wastewater Stream Flow Rate 

(gallons per day)
6 7 8 9 10

Average

2

Code

OSWWT-w-Biotrt

PVC Process 

Wastewater 

Stream 

Destination 

Code

(Refer to Table 4 

below)

Stream Flow Rate (gallons 

Flow Rate 

Determination 

Method

Associated 

Destination 

Information

(Refer to Table 3 below)

Operating Days 

Per Year
OSWWT-w/o-Biotrt

SW

POTWRAW

PrOTWRAW

ZEROALT

RECYC

OTHER

Wastewater Treatment System

3 4 5 6 7

Max Average

Flow Rate 

Determination 

Method

PVC Process 

Wastewater Treatment 

System ID

Operating Days 

Per Year

stewater Stream Flow Rate (gallons per day)
but that does not originate from the PVC production facility.

8 9

Process Equipment U-5

Recovery Equipment RE-3

cess equipment and is not treated to reduce the concentration of vinyl chloride or any other HAP before being discharged from 

Type of Originating 

Equipment/Device

Originating PVC Equipment/Device 

ID
11

Provide name of the wastewater treatment system

Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Ta

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the outlet of 

the PVC process wastewater 

treatment system and its 

destination?

3
Provide name of the wastewater treatment system

Provide name of outfall

Provide name of POTW

Provide name of PrOTW

Describe method

Describe where in the process the stream is recycled

Describe
10 11

OSWWT-w-Biotrt Onsite Shared Bio-Treatment Plant

OSWWT-w-Biotrt Onsite Shared Bio-Treatment Plant

 or any other HAP before being discharged from 

PVC Process Wastewater Stream 

Destination Code

(Refer to Table 4 below)

Associated Destination Information
s to Provide in Column 12 of Table 1 and Column 11 of Table 2

3

12

Yes

Yes

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the 

originating PVC process equipment 

and its destination?

FORM E-1-b

MAINTENANCE WASTEWATER

Is your facility subject to any Federal, State, local or 

other requirements to collect, store, treat, or otherwise 

handle maintenance wastewater?

No

If "Yes," please provide the regulation citation or permit 

requirement as appropriate:

(If you answered "No," please provide responses to the 

questions below).

Provide a detailed description of the activities that create 

maintenance wastewater.

Procedures followed to collect, handle, manage, and 

treat maintenance wastewater? Include any further 

processing steps.

Is the maintenance wastewater exposed to the 

atmosphere at any point?

Describe procedure for controlling HAP emissions from 

the maintenance wastewater (if any):

Reactor cleanouts and silo washdowns. 

All water collected in plant drainage system, sent to onsite bio-treatment system

Yes, at generation and transport to onsite bio-treatment.

Maintenance wastewater is sent to onsite bio-treatment system.

Page 1 of 1

DRAFT PVC Section 114 Survey Part 2

06/23/2009
FORM E-2-a

30 DAY PVC PROCESS WASTEWATER SAMPLING AND ANALYSIS DATA

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system 

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID mu

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determinat

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of 40 CFR Part 6

5. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method dete

6. Enter any notes or additional information relevant to the sampling or analysis.

7. Refer to Attachment B of Enclosure 1 "Summary of Test Procedures, Methods, and Reporting Requirements For R

PVC Process Wastewater Treatment System ID

CAS No. HAP

107211 Ethylene glycol

67561 Methanol

75070 Acetaldehyde

50000 Formaldehyde

51285 2,4-dinitrophenol

98862 Acetophenone

117817 Bis(2-ethylhexyl) phthalate (DEHP)

123319 Hydroquinone

108952 Phenol

79345 1,1,2,2-tetrachloroethane

106990 1,3-butadiene

540841 2,2,4-trimethylpentane

71432 Benzene

108907 Chlorobenzene

67663 Chloroform

126998 Chloroprene

98828 Cumene

75003 Ethyl chloride (Chloroethane)

100414 Ethylbenzene

107062 Ethylene dichloride (1,2-Dichloroethane)

75343 Ethylidene dichloride (1,1-Dichloroethane)

74873 Methyl chloride (Chloromethane)

75092 Methylene chloride

110543 n-Hexane

108883 Toluene

71556 Methyl chloroform (1,1,1-Trichloroethane)

If Other, Please Provide a Description of the Resin Type -->

Stream Flow Rate Exiting the Treatment System (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->
79005 1,1,2-Trichloroethane

108054 Vinyl acetate

593602 Vinyl bromide

75014 Vinyl chloride

75354 Vinylidene chloride (1,1-Dichloroethylene)

1330207 Xylenes (isomers and mixtures)
 ANALYSIS DATA

stewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single st

m ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of Form 

date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sa

re not listed in Table 10 to Subpart HHHHHHH of 40 CFR Part 63) in the table below.

such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

 the sampling or analysis.

Test Procedures, Methods, and Reporting Requirements For Resin and Process Wastewater Sampling and Analysis at Polyvinyl Chloride a

WWT-1

Analysis Method Concentration 

(ppmw) Non-Detect?

SW-846-8015C 500

SW-846-8015C 10000

SW-846-8315A 50

SW-846-8315A 75

SW-846-8270D 10

SW-846-8270D 5

SW-846-8270D 10

SW-846-8270D 15

SW-846-8270D 23

SW-846-8260B 25.1

SW-846-8260B 26.2

SW-846-8260B 15.4

SW-846-8260B 13.4

SW-846-8260B 7.5

SW-846-8260B 7.9

SW-846-8260B 8.5

SW-846-8260B 15.8

SW-846-8260B 5.2

SW-846-8260B 0.01 Non-detect

SW-846-8260B 0.01 Non-detect

SW-846-8260B 0.01 Non-detect

SW-846-8260B 0.02

SW-846-8260B 0.03

SW-846-8260B 10

SW-846-8260B 0.05

SW-846-8260B 15

her, Please Provide a Description of the Resin Type -->

Sample Date -->

Suspension

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

 Exiting the Treatment System (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->

155

5

02/15/14

IAS-001

IA-001

02/17/14

Flow Rate Determination Method --> Measured
SW-846-8260B

2

SW-846-8260B5

SW-846-8260B 10

EPA Method 1072

SW-846-8260B3

SW-846-8260B5
and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

sted in Table 2 of Form B-3.

ature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

, in the "Concentration (ppmw)" column.

Wastewater Sampling and Analysis at Polyvinyl Chloride and Copolymer (PVC) Facilities" for additional instructions and information.

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

500

10000

50

75

10

5

10

15

23

25.1

26.2

15.4

13.4

7.5

7.9

8.5

15.8

5.2

0.01 Non-detect

0.01 Non-detect

0.01 Non-detect

0.02

0.03

10

0.05

15

Suspension Suspension

02/18/14

IAS-002

1 2

155

6.5

02/16/14

IA-001

Measured Measured
25

10235
 and information.

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

500 500

10000 10000

50 50

75 75

10 10

5 5

10 10

15 15

23 23

25.1 25.1

26.2 26.2

15.4 15.4

13.4 13.4

7.5 7.5

7.9 7.9

8.5 8.5

15.8 15.8

5.2 5.2

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.02 0.02

0.03 0.03

10 10

0.05 0.05

15 15

Suspension Suspension

02/19/14

IAS-003 IAS-004

3

155 155

5 4

02/17/14 02/18/14

02/20/14

IA-001 IA-001

Measured Measured
2

2

55

10 10 2 2 3 3 5 5
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

500

10000

50

75

10

5

10

15

23

25.1

26.2

15.4

13.4

7.5

7.9

8.5

15.8

5.2

0.01 Non-detect

0.01 Non-detect

0.01 Non-detect

0.02

0.03

10

0.05

15

Suspension Suspension

IAS-005

4 5

155

5

02/19/14

02/21/14

IA-001

Measured Measured
25

10235
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

500 500

10000 10000

50 50

75 75

10 10

5 5

10 10

15 15

23 23

25.1 25.1

26.2 26.2

15.4 15.4

13.4 13.4

7.5 7.5

7.9 7.9

8.5 8.5

15.8 15.8

5.2 5.2

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.02 0.02

0.03 0.03

10 10

0.05 0.05

15 15

Suspension Suspension

155

6 5

IAS-006 IAS-007

6

02/20/14 02/21/14

155

02/22/14 02/23/14

IA-002 IA-002

Measured Measured
2

2

55

10 10 2 2 3 3 5 5
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

500

10000

50

75

10

5

10

15

23

25.1

26.2

15.4

13.4

7.5

7.9

8.5

15.8

5.2

0.01 Non-detect

0.01 Non-detect

0.01 Non-detect

0.02

0.03

10

0.05

15

Suspension Suspension

7

02/22/14

7 8

155

02/24/14

IA-002

IAS-008

Measured Measured
25

10235
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

500 500

10000 10000

50 50

75 75

10 10

5 5

10 10

15 15

23 23

25.1 25.1

26.2 26.2

15.4 15.4

13.4 13.4

7.5 7.5

7.9 7.9

8.5 8.5

15.8 15.8

5.2 5.2

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.02 0.02

0.03 0.03

10 10

0.05 0.05

15 15

Suspension Suspension

Measured Measured

5 5

02/23/14 02/24/14

9

155 155

02/25/14 02/26/14

IA-002 IA-002

IAS-009 IAS-010
2

2

55

10 10 2 2 3 3 5 5
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

500

10000

50

75

10

5

10

15

23

25.1

26.2

15.4

13.4

7.5

7.9

8.5

15.8

5.2

0.01 Non-detect

0.01 Non-detect

0.01 Non-detect

0.02

0.03

10

0.05

15

Suspension Suspension

Measured

4

Measured

02/25/14

10 11

155

02/27/14

IAS-011

IA-003
25

10235
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

500 500

10000 10000

50 50

75 75

10 10

5 5

10 10

15 15

23 23

25.1 25.1

26.2 26.2

15.4 15.4

13.4 13.4

7.5 7.5

7.9 7.9

8.5 8.5

15.8 15.8

5.2 5.2

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.02 0.02

0.03 0.03

10 10

0.05 0.05

15 15

Suspension Suspension

4 5

155 155

Measured Measured

02/26/14 02/27/14

12

02/28/14 03/01/14

IAS-012 IAS-013

IA-003 IA-003
2

2

55

10 10 2 2 3 3 5 5
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

500

10000

50

75

10

5

10

15

23

25.1

26.2

15.4

13.4

7.5

7.9

8.5

15.8

5.2

0.01 Non-detect

0.01 Non-detect

0.01 Non-detect

0.02

0.03

10

0.05

15

Suspension Suspension

6.5

155

Measured Measured

13 14

02/28/14

03/02/14

IAS-014

IA-003
25

10235
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

500 500

10000 10000

50 50

75 75

10 10

5 5

10 10

15 15

23 23

25.1 25.1

26.2 26.2

15.4 15.4

13.4 13.4

7.5 7.5

7.9 7.9

8.5 8.5

15.8 15.8

5.2 5.2

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.02 0.02

0.03 0.03

10 10

0.05 0.05

15 15

Suspension Suspension

6

155

Measured

15

03/01/14 03/02/14

155

Measured

03/03/14 03/04/14

IAS-015

IA-003 IA-003

IAS-016

7
2

2

55

10 10 2 2 3 3 5 5
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

500

10000

50

75

10

5

10

15

23

25.1

26.2

15.4

13.4

7.5

7.9

8.5

15.8

5.2

0.01 Non-detect

0.01 Non-detect

0.01 Non-detect

0.02

0.03

10

0.05

15

Suspension Suspension

16 17

03/03/14

Measured Measured

155

IA-004

IAS-017

03/05/14

8
25

10235
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

500 500

10000 10000

50 50

75 75

10 10

5 5

10 10

15 15

23 23

25.1 25.1

26.2 26.2

15.4 15.4

13.4 13.4

7.5 7.5

7.9 7.9

8.5 8.5

15.8 15.8

5.2 5.2

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.02 0.02

0.03 0.03

10 10

0.05 0.05

15 15

Suspension Suspension

18

03/04/14 03/05/14

Measured Measured

155 155

03/07/14

IA-004 IA-004

IAS-018 IAS-019

03/06/14

5 4
2

2

55

10 10 2 2 3 3 5 5
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

500

10000

50

75

10

5

10

15

23

25.1

26.2

15.4

13.4

7.5

7.9

8.5

15.8

5.2

0.01 Non-detect

0.01 Non-detect

0.01 Non-detect

0.02

0.03

10

0.05

15

Suspension Suspension

19 20

03/06/14

5

Measured Measured

155

03/08/14

IA-004

IAS-020
25

10235
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

500 500

10000 10000

50 50

75 75

10 10

5 5

10 10

15 15

23 23

25.1 25.1

26.2 26.2

15.4 15.4

13.4 13.4

7.5 7.5

7.9 7.9

8.5 8.5

15.8 15.8

5.2 5.2

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.02 0.02

0.03 0.03

10 10

0.05 0.05

15 15

Suspension Suspension

21

03/07/14 03/08/14

155

Measured Measured

155

IA-004

03/09/14 03/10/14

5 5

IAS-021 IAS-022

IA-005
2

2

55

10 10 2 2 3 3 5 5
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

500

10000

50

75

10

5

10

15

23

25.1

26.2

15.4

13.4

7.5

7.9

8.5

15.8

5.2

0.01 Non-detect

0.01 Non-detect

0.01 Non-detect

0.02

0.03

10

0.05

15

Suspension Suspension

Measured Measured

155

03/11/14

5

IAS-023

IA-004

03/09/14

22 23
25

10235
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

500 500

10000 10000

50 50

75 75

10 10

5 5

10 10

15 15

23 23

25.1 25.1

26.2 26.2

15.4 15.4

13.4 13.4

7.5 7.5

7.9 7.9

8.5 8.5

15.8 15.8

5.2 5.2

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.02 0.02

0.03 0.03

10 10

0.05 0.05

15 15

Suspension Suspension

155

03/12/14 03/13/14

IA-005 IA-006

IAS-024 IAS-025

5 5

03/10/14 03/11/14

24

155

Measured Measured
2

2

55

10 10 2 2 3 3 5 5
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

500

10000

50

75

10

5

10

15

23

25.1

26.2

15.4

13.4

7.5

7.9

8.5

15.8

5.2

0.01 Non-detect

0.01 Non-detect

0.01 Non-detect

0.02

0.03

10

0.05

15

Suspension Suspension

26

03/12/14

25

Measured

5

155

IAS-026

03/14/14

IA-005

Measured
25

10235
Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

500 500

10000 10000

50 50

75 75

10 10

5 5

10 10

15 15

23 23

25.1 25.1

26.2 26.2

15.4 15.4

13.4 13.4

7.5 7.5

7.9 7.9

8.5 8.5

15.8 15.8

5.2 5.2

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.01 Non-detect 0.01 Non-detect

0.02 0.02

0.03 0.03

10 10

0.05 0.05

15 15

Suspension Suspension

27

03/13/14 03/14/14

6 8

155 155

IAS-027 IAS-028

03/15/14 03/16/14

IA-006 IA-006

Measured Measured
2

2

55

10 10 2 2 3 3 5 5
Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

500

10000

50

75

10

5

10

15

23

25.1

26.2

15.4

13.4

7.5

7.9

8.5

15.8

5.2

0.01 Non-detect

0.01 Non-detect

0.01 Non-detect

0.02

0.03

10

0.05

15

Suspension Suspension

28

IA-006

IAS-029

29

03/15/14

7

155

03/17/14

Measured Measured
25

10235
Concentration 

(ppmw) Non-Detect? Note(s)

500

10000

50

75

10

5

10

15

23

25.1

26.2

15.4

13.4

7.5

7.9

8.5

15.8

5.2

0.01 Non-detect

0.01 Non-detect

0.01 Non-detect

0.02

0.03

10

0.05

15

Suspension

03/18/14

IA-006

Measured

IAS-030

30

03/16/14

5

155
25

10235
FORM E-2-b

30 DAY PVC PRODUCTION PROCESS WASTEWATER SAMPLING PRODUCTION DATA

Instructions

1. Please complete this worksheet for your PVC production facility. 

2. For the complete time period covering your PVC process wastewater treatment system(s) sampling, provide the total 

4. Refer to "Enclosure 1" for additional instructions and details.

1.) Sampling Start Date: 2/15/2014

2.) Sampling End Date: 3/16/2014

3). Total resin production from sampling start date to sampling end date and the type of resin produced:

3.a.) Total Resin Produced: 210000

3.b.) Resin Type Produced: Suspension

3.c.) If Other, Specify:

4.a.) Total Resin Produced: 7000

4.b.) Days of Production: 1

4.b.) Resin Type Produced: Suspension

4.c.) If Other, Specify:

5.) Total DAILY maximum PVC production capacity: 10000

3. If the process wastewater treatment system(s) is/are treating process wastewater that was generated by the PVC prod

the amount of resin produced during the period prior to the start of sampling and indicate how many days of production th

4.) Total resin produced and number of days of production prior to the start of the sampling period

generated by the process and treated during the sampling period:
stem(s) sampling, provide the total resin production from your PVC production facility.

 of resin produced:

 pounds

 pounds

 days

 pounds per day (max)

hat was generated by the PVC production facility PRIOR to the start of the sampling period, then also include 

ate how many days of production that represents.

mpling period and for which process wastewater was 
FORM F-1

CONTROL DEVICES - ABSORBER

Instructions

1. Complete the form for each absorber used as a control device within the PVC production facility, or for any absorber that emits directly to atmosphere.

2. Refer to "Enclosure 1" for additional instructions and details.

1 Type of Equipment or Device Control Device

2 Equipment of Device ID C-1

3 Type of Absorber Packed bed

4 If other, provide a description:

5 Gas inlet flow rate (dscfm): 2300

6 Gas inlet temperature (°F): 170

7 Pressure drop (in H2O): 10

8 Liquid-to-gas ratio (gal/103

 acfm): 18

Inlet scrubbing liquor

9 Liquor used: Water

10 pH: 6.5

11 Percent solids: 7

12 Type of alkali added, if any: NaOH

13 Addition rate (lb/gal): 0.01

14 Wastewater generation rate (gal/min): 10

15 Year Equipment Installed: 1985

16 Equipment Currently Regulated Under (cite regulations): 40 CFR 61 Subpart F

Page 1 of 1

DRAFT PVC Section 114 Survey Part 1

06/23/2009
FORM F-2

CONTROL DEVICES - THERMAL OR CATALYTIC OXIDIZER

1 Control Device ID: C-2

2 Number of operating hours per year (hours/year): 8400

3 Is this emergency equipment? No

4 Type (Thermal Oxidizer or Catalytic Oxidizer) Thermal Oxidizer

5 Oxidizer Inlet Flow Rate (dscfm): 2300

6 Average percentage of total flow originating from the production facility: 10

7

Combustion chamber temperature (°F): (please note if temperature 

measurement is not in chamber) 1800

8 Excess air (%): 25

9 Nominal residence time (s): 1.5

Heat recovery

10 Recuperative, percent heat recovery

11 Regenerative, percent heat recovery

12 Design Capacity (Heat Input) (MMBtu/hr): 5

13 Fuel Basis for Design Capacity: Fuel Gas

14 Heat Release Rate (Btu/scf): 792

15 Is the unit subject to NSPS? No

16 If yes, indicate the year:

Start-up Fuel/Material

17 Start-up fuel: Fuel Gas

18 Number of start-ups per year: 2

19 Typical length of time for start-up (hours): 16

20 Higher heating value (HHV): 792

Fuels/Materials Combusted During Normal Operations (include solid, liquid, and gas waste streams)

21 Fuel 1: PVC Vent

22 Hours used per year: 8400

23 Higher heating value (HHV): 421

24 Fuel 2: EDC/VCM Vent

25 Hours used per year: 8400

26 Higher heating value (HHV): 1600

27 Fuel 3: Fuel Gas

28 Hours used per year: 8400

29 Higher heating value (HHV): 792

30 Fuel 4: Natural Gas

31 Hours used per year: 10

32 Higher heating value (HHV): 993

33 Fuel 5:

34 Hours used per year:

35 Higher heating value (HHV):

36 Year Equipment Installed: 1985

37 Equipment Currently Regulated Under (cite regulations): 40 CFR 61 Subpart F

Page 1 of 1

DRAFT PVC Section 114 Survey Part 1

06/23/2009
FORM F-3

CONTROL DEVICES - CONDENSERS

Instructions

1. Complete the form for each condenser used as a control device within the PVC production facility, or for any condenser that emits directly to atmosphere.

2. Refer to "Enclosure 1" for additional instructions and details.

1 Type of Equipment or Device

2 Equipment of Device ID

3 Type of Condenser

4 If other, provide a description:

5 Is the condenser refrigerated?

6 Describe the materials condensed:

7 Describe the fate of the non-condensed gas stream:

8 Describe the fate of the condensate outlet stream:

9 Gas inlet flow rate (dscfm):

10 Gas inlet temperature (°F):

11 Gas outlet temperature (°F):

12 Liquid outlet for rate (gpm):

15 Year Equipment Installed:

16 Equipment Currently Regulated Under (cite regulations):

Page 1 of 1

DRAFT PVC Section 114 Survey Part 1

06/23/2009
FORM G

COOLING TOWERS AND HEAT EXCHANGE SYSTEMS

Instructions

3. Refer to "Enclosure 1" for additional instructions and details.

Table 1.a Cooling Tower Identification

Cooling Tower ID U-8

Total CT Return Flow Rate 

(gal/min): 20,000

Number of processes served by

cooling tower: 7

Number of these from a PVC 

production process unit: 7

Is the heat exchange system 

monitored for the presence of one 

or more HAP or VOC in the cooling 

water?

Yes

Table 1.b Cooling Tower Emission Reductions

For this cooling tower (if the single combined inlet line is monitored), OR for each heat exchange system from a PVC proces

(list sequentially beginning with "H1")

H-1 No

1. Please complete one worksheet for each cooling tower, providing as much of the requested information as possible. C

2. Using the table beginning on row 23, provide the requested information for the cooling tower. If only the single combin

enter information for the cooling tower. If cooling tower return lines are monitored individually, please provide informatio

paste more rows to the table to add additional processes. 

PVC HTEX System No.

Is the heat exchange 

system currently

regulated?

If Yes, cite the 

regulation(s):
[ADD MORE ROWS TO THIS TABLE FOR ADDITIONAL HTEX SYSTEMS FOR THIS COOLING TOWER]
Table 2. Once-through Heat Exchange Systems

No

r each heat exchange system from a PVC process unit (if individual CT return lines are monitored individually), please provide the following:

(gal/min) (list speciation and/or 

group)

(e.g., continuous, daily, 

weekly, monthly, yearly, 

other)

(e.g., visual 

inspection, 

surrogate 

monitoring, 

water 

sampling, air 

stripping, 

other)

(e.g., EPA 

Method 601, 

EPA 

Method 624, 

Mod El 

Paso, etc.)

20,000 Vinyl chloride weekly water samplingEPA Method 107

Ethylene dichloride (1,2-

Dichloroethane) weekly water samplingEPA Method 8260B

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

 much of the requested information as possible. Copy and paste additional worksheets for each cooling tower. 

Does your PVC production facility use any once-through heat exchange systems?

on for the cooling tower. If only the single combined inlet line is monitored, you may delete rows 31 through 36 and 

 monitored individually, please provide information for each process. Identify the PVC process in column A. Copy and 

CT Return Flow Rate for 

HTEX System List ALL Compounds 

Analyzed: Monitoring frequency Type of monitoring

Monitoring, 

sampling, or 

air stripping 

analysis 
(select HAP)

S FOR THIS COOLING TOWER]
ally), please provide the following:

Value Unit

(provide the 

numeric 

MDL)

(provide the 

MDL units)

(CT inlet, outlet, 

both) (ppbw) (days) (ppbw) (days)

0.01 ppmw CT inlet 500 10 50 20

0.01 ppmw CT inlet 500 10 50 20

Leak 

Repair 

Threshold

Repair Time for 

Normal Leak 

Events

Emission Reduction Measures

MDL Monitoring 

Location

Delay of Repair 

Threshold

Repair Time for 

Delayed Repairs

(#) (days)

2 15

Number of 

Leaks in 

2013

Total 

Duration 

of All 

Repairs

Leaks in 2013

FORM H

EQUIPMENT LEAKS

Instructions

1. Submit a copy of the leak detection and repair procedures for the PVC production facility and provide responses to the questions below.

2. Refer to "Enclosure 1" for additional instructions and details.

Table 1. LDAR Program

Yes

Yes

No

No

$10,000

Table 2. Equipment Counts

In Source 

Category

Subtotal of Equipment Associated 

with Closed Vent System(s)

(Subset of count in source category)

50 13

5 0

20 0

4 0

100 25

10 0

1 0

10 0

75 15

5 0

100 10

10 0

10 2

80 21

Is there an equipment leak detection and repair (LDAR) 

program for all equipment at your facility included in the 

source category?

If "No," how are equipment leaks detected and repaired?

If "Yes," is the equipment subject to the requirements of:

40 CFR Part 63, Subpart UU

Valves

In heavy liquid service

In light liquid service

Pumps

40 CFR Part 61, Subpart V

Other Federal LDAR Regulation

Specify: 

State LDAR Regulation

Specify:

Provide the total cost to your facility for conducting the LDAR 

program at this process unit in 2013:

Equipment

In heavy liquid service

In gas, vapor, and light liquid service

In liquid service

In gas and vapor service

Pressure Relief Devices

Open ended valves and lines

Sampling connection systems

Compressors

Instrumentation systems

In heavy liquid service

In gas, vapor, and light liquid service

Connectors

In heavy liquid service

In gas, vapor, and light liquid service

Agitators

Page 1 of 1

DRAFT PVC Section 114 Survey Part 1

06/23/2009
FORM J

OFF-SPECIFICATION RESIN AND MATERIAL REMOVAL FROM EQUIPMENT

Instructions

1. Complete this form for 2013 only.

3. Provide copies of estimation worksheets and any other relevant documentation.

4. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., in-line filters).

5. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Source Equipment Type: Process Equipment

Source Process Equipment ID (if applicable): U-3

Equipment Description:

Total Pounds of Material Removed in 2013 (do not 

include the contribution of water or other fluids(s) to 

remove the material from the equipment) :

200

Describe the procedure for removal of the material 

from equipment:

Is the material exposed to the atmosphere at any 

point during or after removal from the equipment?

Describe procedure for controlling HAP emissions 

from the material during and after removal from the 

equipment:

Describe the fate/disposition of the material 

beginning from the time it is removed from the 

equipment. Include any further processing steps.

Table 2.

Minimum Maximum Average

Vinyl chloride 0.01 1 0.05

Acetaldehyde 0.01 5 1

Notes

Yes

2. This form covers resin that is removed from equipment and is not processed further through the normal processing steps. Examples include, but are 

not limited to, off-specification resin removed from the polymerization reactor or any other downstream process equipment, resin removed from 

equipment during maintenance and cleanout operations, etc.

Concentration in Resin or Resin Slurry Immediately Prior 

to Removal From Equipment and Before Being Mixed 

With Other Materials or Fluids (ppmw)

Inside of reactor is hydroblasted. Resin is collected via filters installed on reactor wash-out drain. Resin is allowed to dry and packaged and 

sold as off-spec material.

Reactor is subject to multiple steam purges and vacuum drawn downs before opening equipment. This results in "stripping" of the resin 

remaining in the reactor.

Resin is allowed to dry and packaged and sold as off-spec material.

Individual HAP Present

Page 1 of 2

DRAFT PVC Section 114 Survey Part 2

06/23/2009
Chloroform 0.05 5 1

Acetophenone 0.01 2 0.05

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Page 2 of 2

DRAFT PVC Section 114 Survey Part 2

06/23/2009
FORM K-1

TANKS, VESSELS AND PORTABLE CONTAINERS USED FOR FEEDSTOCK STORAGE, PRODUCT STORAGE, VENT GAS STORAGE, HOLDING, AND WASTEWATER

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Complete this form for individual equipment, including equipment that is not assigned an equipment ID (e.g., portable containers).

4. Do not include gas holders on this form. Complete Form K-2 for gas holders.

4. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

VCM Storage Bullets

25

50

65

Table 2.

Vapor Pressure Total Emissions

(in H2O) Minimum Maximum Average (pounds)

Vinyl chloride 1391 99 100 99.1 0

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Source Equipment Type:

Number of turnovers:

Equipment volume (m3):

Notes

Storage Temperature (°F)

If Yes, How Are The Emissions Controlled? Displaced vapor during filling is routed to VCM recovery system.

Concentration (ppmvd @ 3% O2)

How is the HAP Concentration Determined? Equipment is VCM storage - all material stored is HAP.

Are HAP Emissions Controlled? Yes

Individual HAP Present

VCM Storage Bullet - pressure vessel

Feedstock storage

If Other, please specify, being as descriptive as possible:

Source Process Equipment ID (if applicable):

Equipment Description:

If not provided in the equipment description above, 

describe the tank, vessel, or container and indicate (if 

applicable) if the tank is a fixed, floating internal, or floating 

external roof. 

Select the purpose of the equipment:

Page 1 of 1

DRAFT PVC Section 114 Survey Part 2

06/23/2009
FORM K-2

GAS HOLDERS

Instructions

1. Complete this form for 2013 only.

2. Provide copies of estimation worksheets and any other relevant documentation.

3. Refer to "Enclosure 1" for additional instructions and details.

Table 1.

Yes

1

Yes

Table 2.

Vapor Pressure Total Emissions

(in H2O) (pounds)

Vinyl chloride 1391 5

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

(select HAP)

Notes

Emissions based on engineering calculations

Does your PVC production facility use gas holders:

Indicate the number of gas holders in use at your PVC production facility:

Are HAP Emissions Controlled?

If Yes, How Are The Emissions Controlled? Seal water is covered with a floating mat that reduces VCM loss.

Individual HAP Present

Page 1 of 1

DRAFT PVC Section 114 Survey Part 2

06/23/2009
FORM L

STARTUP, SHUTDOWN, AND MALFUNCTION

Instructions

1. Complete this form for 2013 only.

2. Submit with your response to this survey, copies of all records of emissions during periods of process startup, shutdown, and malfunctions for 2013 only.

3. Refer to "Enclosure 1" for additional instructions and details.

Yes

Startup Shutdown

32 24

For a malfunction:

Yes Yes

No No

40 CFR Part 61 Subpart F 40 CFR Part 61 Subpart F

Control equipment (thermal oxidizer and scrubber) 

is brought online before startup begins.

Control equipment (thermal oxidizer and scrubber) 

is kept online until plant is completely shutdown.

Vinyl chloride (pounds) 0.02 0.02

Hydrochloric acid (pounds) 0.05 0.05

Methylene chloride 

(Dichloromethane) (pounds) 0.01 0.01

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

(select HAP) (pounds)

Is there a written startup, shutdown and/or 

malfunction plan for the process unit?

Provide a description of the systems and 

equipment in place that function to notify 

operators that a malfunction is occurring .

Pressure monitors on reactors with high, high-high alarms. All PRDs are "backed" by rupture disks - vapor space between is monitored for pressure and 

alarms when > atmospheric detected. Thermal oxidizer bypass has a flow detector which alarms to operator whenever flow is detected in the bypass. 

Applicable standard or regulation:

Describe what actions, if any, were taken to 

minimize emissions to the atmosphere:

Total Emissions During Startup, Shutdown, 

or Malfunction Event

Were all of the emissions control devices 

operating for the entire duration of the startup, 

shutdown, or malfunction event?

Startup, Shutdown or Malfunction?

If startup or shutdown, what was the 

duration (hours):

Provide a short description of 

the malfunction and the 

circumstances:

If No, which control devices were not operating 

(Control Equipment ID), for how long, and why:

Were permitted emissions limits exceeded?

Provide a description of the 

procedures used to alert the 

owner/operator that the 

malfunction occurred. If the malfunction resulted in 

a release of emissions, 

describe any indicators used 

to signal and/or measure the 

release.

Page 1 of 1

DRAFT PVC Section 114 Survey Part 1

06/23/2009
FORM M

FACTORS THAT AFFECT HAP/VOC EMISSION REDUCTIONS

Name of Unit Operation

Description of process change or 

other pollution prevention or source 

reduction measure:

Quantify emissions reductions (e.g. tons/year) resulting 

from the use of pollution or source reduction measures:

VCM Recovery - GasholderInstalled seal water cover. Reduced VCM emissions by 15 pounds per year.

For each unit operation for which pollution reduction or source reduction measures have resulted in a decrease in HAP/VOC emissions since 1976, provide the following information.

If recovery or recycling of feedstocks is used, quantify the effect of the program (e.g., estimated annual purchase of feedstock in the absence of recovery/recycling compared to actual annual 

purchase):

Approximately 40,000 pounds of VCM is recovered/recycled back to process each year.

Are you aware of any alternative processes (e.g., feedstock substitutions or eliminations) or control devices or techniques that could result in fewer impacts between environmental media (water, air, 

and land) or reduced total release to all environmental media (e.g., reduced wastewater or solid waste)? Discuss whether these processes could be adapted to the polyvinyl chloride and 

copolymers production source category and any experience you have with them:

No.

Page 1 of 1

DRAFT PVC Section 114 Survey Part 1

06/23/2009
FORM N

MISCELLANEOUS

If any control or process change described on Form M was instituted as a result of new source review requirements pursuant to 40 CFR 

51.160, Subpart I, Review of New Sources and Modifications, provide the date at which the lowest achievable emission rate (LAER) came 

into effect:

Not Applicable

Describe any factors not addressed in the questions in this survey that might serve to distinguish your facility from others in this source 

category for purposes of developing a separate source category or subcategory and MACT standards:

Our facility operates under a purchased technology license from the "We Make All Chemicals" company; therefore 

we are very similar to several other PVC Suspension resin producing facilities. We are unaware of any particular 

process or factor that would warrent subcategorization. 

Page 1 of 1

DRAFT PVC Section 114 Survey Part 1

06/23/2009