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® 1341 West Mockingbird Lane • Dallas, Texas 75247 • 972.647.6700 • www.txi.com 

May 29, 1998 

Mr. Bill Neuffer, Minerals and Inorganic Chemicals Group 

Office Of Air Quality Planning And Standards 

U.S.E.P.A. 

Research Triangle Park, NC 27711 

Re: Athens Brick Company 

Information Collection Requests 

Dear Mr. Neuffer: 

TXI on behalf of its subsidiary, Athens Brick Company, submits the enclosed information 

collection requests, (ICR's), for each of its three brick manufacturing operations located in 

Mooringsport, Louisiana; Athens, Texas; and Mineral Wells, Texas. 

Enclosure 2 was completed for each facility. Material Safety Data Sheets are included and 

may be common to each of the three facilities. The stack test data applies only to the specified 

facility. 

Please call me directly at (972)647-3932 if you have any questions concerning the ICR's or 

otherwise. 

S' ely, 

Robert B. Cain 

Senior Environmental Engineer 

9 
Enclosur~ 2 

^~ NOT SUBJeCT Tu i;lc Of I; 

4 SECTION 3507, PAPEdiiORK REDUCTIOrd AC! Of 19d0. II 

i I 

INFORNiATION REQUEST FOR BRICK AND 

STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS 

I. Instructions 

Please return the completed information request to: 

Bruce C. Jordan, Director 

Attn: Bill Neuffer 

Emission Standards Division (MD-13) 

U. S. Environmental Protection Agency 

Office of Air Quality Planning and Standards 

Research Triangle Park, North Carolina 27711 

If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at 

(919) 541=5435. 

This information request should be completed for each facility that manufactures brick and 

structural clay products, including facilities that are not major sources. Information is 

requested for all proces.ses at your plant that emit hazardous air pollutants (HAP's), 

including those processes that are not associated with brick and structural clay 

products manufacturing. Sections II through VII request information specific to brick 

and structural clay products manufacturing, and Section VIII requests information on 

emissions of HAP's from other processes located at the facility. Processes that may emit 

HAP's include those processes that use or handle any materials that contain a HAP 

compound, all processes with elevated temperatures, and all other processes in which HAP 

compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is 

included as Attachment 1 to this information request. Attachment 2 provides background 

information on the requirements of the Clean Air Act and explains how the information 

requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations 

and acronyms used in this information request. 

Several tables are provided throughout the information request for your convenience in 

answering the questions. An example response is given (shaded first column or row) in 

each table. If additional space is needed to respond, please make copies of applicable 

pages. If necessary, please make copies of this information request for additional facilities. 

No additional emission testing or monitoring is required to respond to this request. 

II. General Facilitv Information 

A. Name of company Athens Brick Conipany 

Name of facility Athens Brick - Caddo Plant 

Page 1 of 28 

~ 
Facility address: 

No. and street 8469 Barnette Road 

City 1`boringsport State LA Zip 71060 

Latitude and longitude coordinates of plant: 324000, 935652 

Standard Industrial Classification (SIC) Code(s) of brick and structural clay products 

manufacturing operations 3251 

Dun and Bradstreet No. 041083627 

Total No. of employees for company 2350 for facility 25 

(If facility is a foreign subsidiary or if company has foreign subsidiaries, include 

number of employees not based in the U.S.). 

Please complete the following shift information for the facility: 

Shift No. of employees Hours per shift Days per year 

1 23 8-10 345 

2 1 8 365 

3 1 8 365 

B. Respondent name Rbbert B. Cain 

Respondenttitle Senior Environmental Engineer 

Respondent address (if different from above) and telephone number: 

No. and street 1341 W. Mockingbird Lane 

City Dal-las State TX Zip 75247 

Telephone No. 972/647-3932 

Name and telephone number of technical contact person (if different from above) 

Name Telephone No. (__) 

M. Information on Operatine Permits and Applicable Federal Emission Standards 

A. Please provide copies of relevant parts of all operating permits and permit 

applications for your facility. Relevant parts include the sections that provide 

specific information and data on: processes that emit HAP's; the use of HAPcontaining substances; emission levels for HAP and surrogate pollutants (i.e., VOC 

Page 2 of 28 

j 
for organic HAP's and PM for metal and other particulate HAP's); emission control 

device design and operation; monitoring and operation and maintenance (O&M) 

procedures for control devices; and generation and releases of other media such as 

wastewater and solid waste that are associated with the operation of air pollution 

controls for brick and structural clay products manufacturing processes. 

If the operating pernzit or application contains the same information requested 

in any part of this questionnaire, you may respond to the requested information 

by referencing the page or section of the permit/application to avoid 

duplication. If you reference your permit or application, you must supplement your 

response with all of the additional information requested in this questionnaire that is 

not included in the permit or permit application. If you prefer, you may submit the 

requested information from : ~ Air permit/application on a 3- 1/z inch diskette. 

B. If any source or emission uni: :d this facility is subject to a New Source Performance 

Standard or other Federal emission standard, please identify the source and 

applicable standard. Examples of applicable NSPS include 40 CFR 60, 

Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing 

Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and 

Dryers in Mineral lndustries. 

W. Brick and Structural Clay Products Production and Raw Material Consumption 

Information 

A. Please provide the 1996 production rates and the current production capacity for 

each type of brick and structural clay product manufactured (e.g., structural brick, 

clay sewer pipes, structural clay tile, etc.). Note that production data should be 

provided in units of tons per year (tons/yr). 

Product 1996 production (tons) Production capacity (tons/yr) 

Face brick 30,000 38,000 

Page 3 of 28 

v 
B. Please provide the type and amount of each raw material and body additive used in 

1996 for manufacturing brick and structural clay products at your facility. Examples 

include clays, shale, and any additives that are mixed into the raw material prior to 

forming. Indicate additives by chemical compound, rather than by trade name. If the 

information requested is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than providing the information 

below. 

Raw materiaVbody additive I Amount used in 1996 (tons/yr) 

Clay 30,000 

Vermiculite 1 

Manganese dioxi.de 2 

Pyrotrol, pyrophyllite 0.25 

C. If available, please provide a copy of the MSDS's for the raw materials and additives 

listed above. 

D. If available, please provide chemical analyses, including fluorine, metals, and organic 

content, of the raw materials listed above. 

Page 4 of 28 

5 
E. Using Table 1, please provide information on the consumption and HAP 

composition of all glazes and colorants that contain HAP's or HAP precursors and 

that your facility applies to brick and structural clay products. Indicate whether the 

coatings are glazes or colorants. Also indicate the type of product that the coatings 

are applied to and the total weight of coatings used in 1996. If the glazes or 

colorants are formulated at your facility indicate so and provide the production 

capacity. List each ingredient of the glaze or colorant. Beside each ingredient, 

indicate the total amount of the ingredient used in 1996. If the information requested 

in the table is contained in your facility's operating permit or permit application, you 

may reference the applicable sections of the permit (or application) rather than filling 

out the table. 

F. In the space below, please indicate any glazes or colorants used by your facility that 

do not contain HAP's and are substitutes for HAP-containing glazes or colorants 

used by your industry. Indicate which HAP-containing materials the non-HAP 

glazes or colorants replace. Describe any limitations on the use of those substitute 

glazes or colorants. 

None 

G. If your facility colors brick and structural clay products by flashing, please indicate 

the types of substances used to flash the products and the amounts of those 

substances used in 1996. 

Substance Amount used in 1996 Units (specifv) 

H. If available, please provide a copy of the MSDS's for the glazes and colorants used 

by your facility. If your facility prepares its own glaze, please provide any available 

MSDS's for the glaze ingredients. 

Page 5 of 28 

~ 
TABLE l. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND COLORANTS 

Type (e.g., glaze, colorant) EXAMPLE: 

Gtaze 

Type of product glazed or gtrufpindAbar : 

colored 

1996 consumption (tons/yr) , ~9FI4i~; 

Produced at facility? (yes/no) 

Production capacity (tons/yr) 

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If additional space is required, please make copies of this page. If the information requested in 

the table is contained in your facility's operating permit or permit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

Page 6 of 28 

~ 
V. Description of Brick and Structural Clay Product ManufacturingProcesses 

A. Please provide a simple process flow diagram for each brick and structural clay 

product manufacturing process line. An example process flow diagram is provided 

in Figure 1. A diagram of the plant layout with all processes and emission points 

clearly labeled is also acceptable. 

Assign a unique identification number (ID No.) for each process that has 

associated emissions (e.g., TK-1 for tunnel kiln no. l) and each emission point. 

Please identify all emission points, including those that do not emit HAP's. For 

emission points that are vented to an air pollution control device (APCD), assign an 

ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are 

uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof 

vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information 

request for any responses that pertain to any process or emission point. 

Page 7 of 28 

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B. Using Tables 2A and 2B, please provide current production rates, production 

capacities, and related information for each type of equipment used in brick and 

structural clay product manufacturing. In Table 2A, provide the requested 

information for only those sources that are known or expected to emit HAP's. In 

Table 213, provide the requested information for all thermal processing, such as 

drying and firing sources. For combustion sources that use different fuels, Table 2B 

should be completed for each type of fuel. For example, if a kiln typically is fired 

with gas, but periodically is fired with oil, one column in Table 2B should be 

completed for the kiln when fired with gas, and another column should be completed 

for the same kiln when fired with oil. Provide the data in the units listed for each 

row. 

Page 9 of 28 

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Page 11 of 28 

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C. Using Table 3, please provide information on procedures used to monitor the 

process operating rate for each of the pieces of equipment and HAP emission 

sources listed in Tables 2A and 2B. Use the same HAP emission source types and 

equipment ID numbers you listed in Tables 2A to 2B. 

Indicate whether you monitor process rate or not. 

Provide a summary of process rate monitoring procedures that 

describes how process rate is measured for the particular piece of 

equipment. Include where the rate is monitored (i.e., rate of material fed, 

rate of material discharged, or material production rate), the units used to 

measure process rate (e.g, lb/hr or pieces/hr), and how the process data is 

recorded, i.e., manually, automatically (e.g., computer - printout or stored 

to disk, or not at all). If you monitor process rate at both the feed and 

discharge ends of the equipment, indicate so. 

Indicate the type of monitor, equipment, or instrument used to measure 

process operating rate. 

Indicate the monitoring frequency or how often process rate 

measurements are made. 

If instruments are used to measure process throughput, indicate in the 

monitor accuracy column the accuracy of the instrument. The monitor 

accuracy could be listed in terms of a percentage of the throughput 

(t 1 percent), mass per unit time (t21b/hr), number of pieces per unit time 

(t 10 pieces/hr), or other appropriate units. 

Indicate the frequency that the monitor is calibrated. 

Provide data in the units listed for each row. 

Page 12 of 28 

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VI. Identification of Brick and Structural Clay Product Manufacturing Emission Points 

A. Use the process flow diagrams developed for your facility and Table 4 to provide 

the following information for each HAP emission source at your facility. 

• Define HAP emission source type in terms of equipment, such as dryers, kilns, 

etc. As in the process flow diagram, you may group multiple pieces of similar 

equipment. 

• Use the same equipment ID numbers indicated on the process flow 

diagram(s). 

• If the emission source vents inside a building or to outside ambient air without 

first passing through a control device, place a check mark in the uncontrolled 

column. 

• If the emission source vents inside a building or to outside ambient air after 

passing through a fabric fllter, dry injection fabric filter, or scrubber, place 

the APCD ID number(s) in the column corresponding to the APCD type. 

• If the emission source vents through a control device type not listed in Table 4, 

indicate the control device type in the other control column and place the 

APCD ID number in the appropriate cell. 

• In the emission test data column, place a"yes" or "no" in the appropriate cell to 

indicate whether the specific source has been tested for any pollutants, including 

any HAP's, VOC, PM, or opacity. 

Page 14 of 28 

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Page 15 of 28 

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B. Using Table 5, please provide information on stack parameters and emission 

estimates for each emission point at your facility that is known or expected to emit 

HAP's. Provide information for all APCD's, including those that exhaust inside the 

building. Include data for each inlet and outlet, if available, as indicated in the 

table. If you have more than one inlet to an APCD, provide data for each of the 

inlets. Provide data in the units listed for each row. 

Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal 

HAP's or VOC for organic HAP's. Emission estimates may consist of 

measurements reported in emission test reports or may be calculated using mass 

balances, emission factors, engineering judgement, or other estimation methods. 

Provide the emission estimates as emission factors in units of lb of pollutant 

emitted per ton of product (lb/ton). Provide complete copies of any emission test 

reports or other reports that document measurements of emissions. Test 

reports and other emission measurement documents should include the following 

information: process identification; location of sampling point; stack diameter, 

temperature, and flow rate; test method, including analytical procedures; number of 

test runs; emission concentration, emission rate, percent oxygen, and percent 

moisture for each test run; process operating rate; type of APCD; and APCD 

operating parameters. However, test reports with incomplete documentation may 

still be useful and should also be submitted. 

You do not need to fill out Table 5 for emission points that are covered by an 

emission test report that is included in your submittal. If emission test reports are 

not available, provide calculations that support your emission estimate, 

including the basis for all assumptions in the estimate. Note that emission 

estimates are needed for all HAP's that the facility emits or has the potential to emit. 

(Please refer to the HAP list in Attachment 1.) If the information requested in the 

table is contained in your facility's operating permit, you may reference the 

applicable sections of the permit rather than filling out the table. 

Page 16 of 28 

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C. Using Tables 6A through 6D, please provide design and operating data for each 

APCD associated with all dryers, kilns, and any other brick and structural clay products 

manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of 

APCD's. Use Table 6D for other types of APCD's. When using Table 61), please 

specify the type of control device and 2 to 4 key design or operating parameters for the 

device. Provide data in the units listed for each row. If the information requested in 

Tables 6A through 6D is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the tables. 

Page 19 of 28 

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D. Using Table 7, please provide the following information on current monitoring 

procedures for each of the control devices listed in Tables 6A to 6D: parameters 

monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices 

used (e.g., differential pressure transducer, thermocouple), and recordkeeping 

practices (e.g., manually recorded in log book, continuously recorded by electronic data 

acquisition system). Describe briefly other operation and maintenance (O&M) 

procedures for each control device. If the information requested in the table is 

contained in your facility's operating permit, you may reference the applicable sections 

of the permit rather than filling out the table. 

VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing 

A. Please descritie all pollution prevention practices (i.e., process modifications, such as 

re-use of discarded or rejected materials, or any practice that prevents or reduces the 

amount of air emissions, or the generation and release of solid waste or wastewater 

associated with the operation of air pollution controls). If the information requested 

here is contained in your facility's operating permit, you may reference the applicable 

sections of the permit rather than providing the information below. 

Broken fired ware and unfired reject greenware are added into 

the raw material feed. 

Page 24 of 28 

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VIII. Information on Processes Other Than Brick and Structural Clay Products Manufacturing 

Processes 

A. Using Table 8, please identify all other processes or operations at this facility that are 

not addressed in Items II through VII above and that are potential sources of HAP 

emissions. Estimate total annual emissions of each HAP emitted by these colocated 

processes. If the information requested in the table is contained in your facility's 

operating permit, you may reference the applicable sections of the permit rather than 

filling out the table. 

Page 27 of 28 

aP' 
TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES 

SIC 

SIC 

SIC 

SIC 

If the information requested in the table is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the table. 

Page 28 of 28 

o~- ~ 
Enclosure 2 

NOT SUBJECT TO i;lc RECJ!RE\1ENTS OF 11 

SECTION 3507, PAPERiIORK REDUCTIOri ACT OF 1980. 1' 

INFORMATION REQUEST FOR BRICK AND 

STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS 

I. Instructions 

Please return the completed information request to: 

Bruce C. Jordan, Director 

Attn: .Bill Neuffer 

Emission Standards Division (MD-13) 

U. S. Environmental Protection Agency 

Office of Air Quality Planning and Standards 

Research Triangle Park, North Carolina 27711 

If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at 

(919) 541-5435. 

This information request should be completed for each facility that manufactures brick and 

structural clay products, including facilities that are not major sources. Information is 

requested for all processes at your plant that emit hazardous air pollutants (HAP's), 

including those processes that are not associated with brick and structural clay 

products manufacturing. Sections II through VII request information specific to brick 

and structural clay products manufacturing, and Section VIII requests information on 

emissions of HAP's from other processes located at the facility. Processes that may emit 

HAP's include those processes that use or handle any materials that contain a HAP 

compound, all processes with elevated temperatures, and all other processes in which HAP 

compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is 

included as Attachment 1 to this information request. Attachment 2 provides background 

information on the requirements of the Clean Air Act and explains how the information 

requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations 

and acronyms used in this information request. 

Several tables are provided throughout the information request for your convenience in 

answering the questions. An example response is given (shaded first column or row) in 

each table. If additional space is needed to respond, please make copies of applicable 

pages. If necessary, please make copies of this information request for additional facilities. 

No additional emission testing or monitoring is required to respond to this request. 

U. General Facility Information 

A. Name of company Athens Brick Corpany 

Name of facility At.hens Brick Plant 

Page 1 of 28 

~~ ~ 
Facility address: 

No. and street 200 Athens Brick Road 

City Athens State TX Zip 75751 

Latitude and longitude coordinates of plant: 321215, 954922 

Standard Industrial Classification (SIC) Code(s) of brick and structural clay products 

manufacturing operations 3251 

Dun and Bradstreet No. 041083403 

Total No. of employees for company 2350 for facility 49 

(If facility is a foreign subsidiary or if company has foreign subsidiaries, include 

number of employees not based in the U.S.). 

Please complete the following shift information for the facility: 

Shift No. of employees Hours per shift Days per year 

1 46 8-10 345 

2 2 8 365 

3 1 8 365 

B. Respondent name R°bert B. Cain 

Respondenttitle Senior Environmental Engineer 

Respondent address (if different from above) and telephone number: 

No. and street 1341 W. Nbckingbird Lane 

City Da11as State 'I'X Zip 75247 

Telephone No. (--) 972/647-3932 

Name and telephone number of technical contact person (if different from above) 

Name Telephone No. (__) 

III. Information on Operating Permits and Applicable Federal Emission Standards 

A. Please provide copies of relevant parts of all operating permits and permit 

applications for your facility. Relevant parts include the sections that provide 

specific information and data on: processes that emit HAP's; the use of HAPcontaining substances; emission levels for HAP and surrogate pollutants (i.e., VOC 

Page 2 of 28 

31 
for organic HAP's and PM for metal and other particulate HAP's); emission control 

device design and operation; monitoring and operation and maintenance (O&M) 

procedures for control devices; and generation and releases of other media such as 

wastewater and solid waste that are associated with the operation of air pollution 

controls for brick and structural clay products manufacturing processes. 

If the operating permit or application contains the same information requested 

in any part of this questionnaire, you may respond to the requested information 

by referencing the page or section of the permit/application to avoid 

dupGcation. If you reference your permit or application, you must supplement your 

response with all of the additional information requested in this questionnaire that is 

not included in the permit or permit application. If you prefer, you may submit the 

requested information from your penmit/application on a 3-'/x inch diskette. 

B. If any source or emission unit at this facility is subject to a New Source Performance 

Standard or other Federal emission standard, please identify the source and 

applicable standard. Examples of applicable NSPS include 40 CFR 60, 

Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing 

Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and 

Dryers in Mineral Industries. 

IV. Brick and Structural Clay Products Production and Raw Material Consumption 

Information 

A. Please provide the 1996 production rates and the current production capacity for 

each type of brick and structural clay product manufactured (e.g., structural brick, 

clay sewer pipes, structural clay tile, etc.). Note that production data should be 

provided in units of tons per year (tons/yr). 

Product 1996 production (tons) Production capacity (tons/yr) 

Face brick 57,000 65,000 estimated 

Page 3 of 28 

3z 
B. Please provide the type and amount of each raw material and body additive used in 

1996 for manufacturing brick and structural clay products at your facility. Examples 

include clays, shale, and any additives that are mixed into the raw material prior to 

forming. Indicate additives by chemical compound, rather than by trade name. If the 

information requested is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than providing the information 

below. 

Raw materiaVbody additive Amount used in 1996 (tons/yr) 

Clay 90,000 

Bottom ash 2,150 

BariLUn carbonate 55 

Iron oxide 1 

Sand 30 

P7anganese dioxi.de 1.5 

Grog - broken bric,ks and non-glazed 18,000 

fired clay ceram.ics 

C. If available, please provide a copy of the MSDS's for the raw materials and additives 

listed above. 

D. If available, please provide chemical analyses, including fluorine, metals, and organic 

content, of the raw materials listed above. 

Page 4 of 28 

-~O 
E. Using Table 1, please provide information on the consumption and HAP 

composition of all glazes and colorants that contain HAP's or HAP precursors and 

that your facility applies to brick and structural clay products. Indicate whether the 

coatings are glazes or colorants. Also indicate the type of product that the coatings 

are applied to and the total weight of coatings used in 1996. If the glazes or 

colorants are formulated at your facility indicate so and provide the production 

capacity. List each ingredient of the glaze or colorant. Beside each ingredient, 

indicate the total amount of the ingredient used in 1996. If the information requested 

in the table is contained in your facility's operating permit or permit application, you 

may reference the applicable sections of the permit (or application) rather than filling 

out the table. 

F. In the space below, please indicate any glazes or colorants used by your facility that 

do not contain HAP's and are substitutes for HAP-containing glazes or colorants 

used by your industry. Indicate which HAP-containing materials the non-HAP 

glazes or colorants replace. Describe any limitations on the use of those substitute 

glazes or colorants. 

None 

G. If your facility colors brick and structural clay products by flashing, please indicate 

the types of substances used to flash the products and the amounts of those 

substances used in 1996. 

Substance Amount used in 1996 Units (specify) 

H. If available, please provide a copy of the MSDS's for the glazes and colorants used 

by your facility. If your facility prepares its own glaze, please provide any available 

MSDS's for the glaze ingredients. 

Page 5 of 28 

3V 
TA.BLE 1. CONSUMPTION AND HAP COMPOSTTION OF GLAZES AND COLORANTS 

Type (e.g., glaze, colorant) EXAMpLEt 

Type of product glazed or StrtietnraC tite: >:;'; 

colored 

1996 consumption (tons/yr) 

F 

Produced at facility? (yes/no) ~ 

 .-,.. ~. P. 

.... 

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. 

. .. .. .::. 

Fproduction capacity (tons/yr) 

Total usage (weight) of each 

ingredient (that is a HAP, 

contains a HAP, or is a HAP 

precursor) in 1996 

I Tota11996 

Ingredient usage, tons 

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If additional space is required, please make copies of this page. If the information requested in 

the table is contained in your facility's operating permit or permit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

Page 6 of 28 

~ 
V. Descril2tion of Brick and Structural CIaYProduct Manufacturing Processes 

A. Please provide a simple process flow diagram for each brick and structural clay 

product manufacturing process line. An example process flow diagram is provided 

in Figure 1. A diagram of the plant layout with all processes and emission points 

clearly labeled is also acceptable. 

Assign a unique identification number (ID No.) for each process that has 

associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. 

Please identify all emission points, including those that do not emit HAP's. For 

emission points that are vented to an air pollution control device (APCD), assign an 

ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are 

uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof 

vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information 

request for any responses that pertain to any process or emission point. 

Page 7 of 28 

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Page 8 of 28 

,? ~ 
B. Using Tables 2A and 2B, please provide current production rates, production 

capacities, and related information for each type of equipment used in brick and 

structural clay product manufacturing. In Table 2A, provide the requested 

information for only those sources that are known or expected to emit HAP's. In 

Table 2B, provide the requested information for all thermal processing, such as 

drying and firing sources. For combustion sources that use different fuels, Table 2B 

should be completed for each type of fuel. For example, if a kiln typically is fired 

with gas, but periodically is fired with oil, one column in Table 2B should be 

completed for the kiln when fired with gas, and another column should be completed 

for the same kiln when fired with oil. Provide the data in the units listed for each 

row. 

Page 9 of 28 

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Page 11 of 28 + 

.~lJ 
C. Using Table 3, please provide information on procedures used to monitor the 

process operating rate for each of the pieces of equipment and HAP emission 

sources listed in Tables 2A and 2B. Use the same HAP emission source types and 

equipment ID numbers you listed in Tables 2A to 2B. 

Indicate whether you monitor process rate or not. 

Provide a sununary of process rate monitoring procedures that 

describes how process rate is measured for the particular piece of 

equipment. Include where the rate is monitored (i.e., rate of material fed, 

rate of material discharged, or material production rate), the units used to 

measure process rate (e.g, lb/hr or pieces/hr), and how the process data is 

recorded, i.e., manually, automatically (e.g., computer - printout or stored 

to disk, or not at all). If you monitor process rate at both the feed and 

discharge ends of the equipment, indicate so. 

Indicate the type of monitor, equipment, or instrument used to measure 

process operating rate. 

Indicate the monitoring frequency or how often process rate 

measurements are made. 

If instruments are used to measure process throughput, indicate in the 

monitor accuracy column the accuracy of the instrument. The monitor 

accuracy could be listed in terms of a percentage of the throughput 

(± 1 percent), mass per unit time (t21b/hr), number of pieces per unit time 

(t 10 pieces/hr), or other appropriate units. 

Indicate the frequency that the monitor is calibrated. 

Provide data in the units listed for each row. 

Page 12 of 28 

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Page 13 of 28 

V2- 
VI. Identification of Brick and Structural Clay Product Manufacturing Emission Points 

A. Use the process flow diagrams developed for your facility and Table 4 to provide 

the following information for each HAP emission source at your facility. 

• Define HAP emission source type in terms of equipment, such as dryers, kilns, 

etc. As in the process flow diagram, you may group multiple pieces of similar 

equipment. 

• Use the same equipment ID numbers indicated on the process flow 

diagram(s). 

• If the emission source vents inside a building or to outside ambient air without 

first passing through a control device, place a check mark in the uncontrolled 

column. 

• If the emission source vents inside a building or to outside ambient air after 

passing through a fabric filter, dry injection fabric filter, or scrubber, place 

the APCD ID number(s) in the column corresponding to the APCD type. 

• If the emission source vents through a control device type not listed in Table 4, 

indicate the control device type in the other control column and place the 

APCD ID number in the appropriate cell. 

• In the emission test data column, place a"yes" or "no" in the appropriate cell to 

indicate whether the specific source has been tested for My pollutants, including 

any HAP's, VOC, PM, or opacity. 

Page 14 of 28 

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Page 15 of 28 

4717 
B. Using Table 5, please provide information on stack parameters and emission 

estimates for each emission point at your facility that is known or expected to emit 

HAP's. Provide information for all APCD's, including those that exhaust inside the 

building. Include data for each inlet and outlet, if available, as indicated in the 

table. If you have more than one inlet to an APCD, provide data for each of the 

inlets. Provide data in the units listed for each row. 

Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal 

HAP's or VOC for organic HAP's. Emission estimates may consist of 

measurements reported in emission test reports or may be calculated using mass 

balances, emission factors, engineering judgement, or other estimation methods. 

Provide the emission estimates as emission factors in units of lb of pollutant 

emitted per ton of product (lb/ton). Provide complete copies of any emission test 

reports or other reports that document measurements of emissions. Test 

reports and other emission measurement documents should include the following 

information: process identification; location of sampling point; stack diameter, 

temperature, and flow rate; test method, including analytical procedures; number of 

test runs; emission concentration, emission rate, percent oxygen, and percent 

moisture for each test run; process operating rate; type of APCD; and APCD 

operating parameters. However, test reports with incomplete documentation may 

still be useful and should also be submitted. 

You do not need to fill out Table 5 for emission points that are covered by an 

emission test report that is included in your submittal. If emission test reports are 

not available, provide calculations that support your emission estimate, 

including the basis for all assumptions in the estimate. Note that emission 

estimates are needed for all HAP's that the facility emits or has the potential to emit. 

(Please refer to the HAP list in Attachment 1.) If the information requested in the 

table is contained in your facility's operating permit, you may reference the 

applicable sections of the permit rather than filling out the table. 

Page 16 of 28 

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y7 
C. Using Tables 6A through 6D, please provide design and operating data for each 

APCD associated with all dryers, kilns, and any other brick and structural clay products 

manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of 

APCD's. Use Table 6D for other types of APCD's. When using Table 61), please 

specify the type of control device and 2 to 4 key design or operating parameters for the 

device. Provide data in the units listed for each row. If the information requested in 

Tables 6A through 6D is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the tables. 

Page 19 of 28 

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D. Using Table 7, please provide the following information on current monitoring 

procedures for each of the control devices listed in Tables 6A to 6D: parameters 

monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices 

used (e.g., differential pressure transducer, thermocouple), and recordkeeping 

practices (e.g., manually recorded in log book, continuously recorded by electronic data 

acquisition system). Describe briefly other operation and maintenance (O&M) 

procedures for each control device. If the information requested in the table is 

contained in your facility's operating permit, you may reference the applicable sections 

of the permit rather than filling out the table. 

VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing 

A. Please describe all pollution prevention practices (i.e., process modifications, such as 

re-use of discarded or rejected materials, or any practice that prevents or reduces the 

amount of air emissions, or the generation and release of solid waste or wastewater 

associated with the operation of air pollution controls). If the information requested 

here is contained in your facility's operating permit, you may reference the applicable 

sections of the permit rather than providing the information below. 

Broken fired ware and unfired reject greenware are added into 

the raw material feed. 

Page 24 of 28 

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VIII. Information on Processes Other Than Brick and Structural Clay Products Manufacturing 

Processes 

A. Using Table 8, please identify all other processes or operations at this facility that are 

not addressed in Items II through VII above and that are potential sources of HAP 

emissions. Estimate total annual emissions of each HAP emitted by these colocated 

processes. If the information requested in the table is contained in your facility's 

operating permit, you may reference the applicable sections of the permit rather than 

filling out the table. 

Page 27 of 28 

J-6 
TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES 

SIC 

SIC 

SIC 

SIC 

If the information requested in the table is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the table. 

Page 28 of 28 

57 
Exhaust Emission Sampling 

Athens Brick Company 

Athens, TX 

December 13, 1995 

Armstrong Environmental, Inc. 

Project W-1752-95 

Report Prepared For: 

Mr. Robeit Cain 

Texas Industries, Inc. 

1341 W. Mockingbird Lane 

Dallas, TX 75247-6913 

Report Prepared December 15, 1995 By: 

Armstrong Errvironmental, Inc. 

7715 Sovereign Row 

Dallas, Texas 75247 

(214)631-0021 

,s7Y 
TABLE OF CONTENTS 

Page 

I. Introduction 1 

II. Summary 2 - 4 

III. Procedures 5 - 6 

IV. Appendices 

A. Calculation Summaries 7- 12 

B. Continuous Emission Monitor Record'mgs 13 - 36 

C. Analytical Summaries 37 - 56 

D. Field Data Sheets 57 - 62 

E. Gas Standard Certifications 63 - 71 

F. Equipment Cahbrations 72 - 87 

~~ 
I. INTRODUCTION 

A series oftests were performed on the Kiln exhaust and Dryer exhaust at the Athens 

Brick Company facility in Athens, TX December 13, 1995. 

The purpose of this test series was to determine the exhaust emission rates of particulate, 

carbon monoxide, nitrogen oxides, VOC, sulfur dioxide, hydrogen chloiide and hydrogen 

fluoride in terms of Ibs/hr. 

Testing followed procedures detalled in Title 40: Code of Federal Regulations (40:CFR). 

Sampling was performed by Joe Barrera, Danny Barrera, Cody Jefferson and Tom 

Armstrong of Aimstrong Environmental, Inc. using two Apex Method 5 Sampling Trains, 

a TECO 51 continuous FID analyzer, a TECO Mode110 cont.inuous Nox analyzer, a 

Hon'ba VIA continuous S02 analyzer, and a FUJI NDIR continuous CO analyzer. 

Sampling on the kiln was perfonned 8:28 am to 3:05 pm, with a 3 hour delay between 

Runs 1 and 2 due to a power-outage. Sampling on the dryer was performed 3:40 pm to 

7:14 pm. 

Submitted by: 

Armstrong Environmental, lnc. 

~ 

Tom Armstrong 

President 

.s 
Source/Run # 

Kiln Ezhaust 

1 

~M 

Particulate, lbs/hr 2.629 

I Carbon Monoxide, lbs/hr 3.38 

Nitrogen Oxides, lbs/hr 1.29 

Sulfur Dioxide, Ibs/hr 8.85 

VOC as C3H8, Ibs/hr 0.654 

Hydrogen Chloride, lbs/hr 1.507 

Hydrogen Fluoride, IbsJhr 5.875 

3 AveraQe 

2.027 3.369 2.675 

2.95 3.16 3.16 

1.47 1.26 1.34 

7.61 9.59 8.68 

0.520 0.505 0.560 

1.367 1.809 1.561 

5.019 4.858 5.251 

II. SUMNfARY 

A series of tests were performed on the Ki}n exhaust and Dryer exhaust at the Athens 

Brick Company facility in Athens, TX December 13, 1995. 

Sampling was performed following procedures detai7ed in Title 40: Code of Federal 

Regulations. 

Results of this test series are summarizea .: ~ :'able 1- 2. 

Results indicate the following emission ra: 

Dryer Ezhaust 

Particulate, Ibs/hr 2.514 1.372 1.806 1.897 

Carbon Monoxide, lbslhr 0.395 1.068 0.851 0.771 

Nrtrogen Oxides, Ibs/hr 0.061 0.032 0.248 0.114 

Sulfur Dioxide, lbs/hr 0.377 1.376 1.925 1.226 

VOC as C3H8, lbs/hr 2.016 3.487 2.691 2.731 

Hydrogen Chloride, lbs/hr 0.117 0.138 0.024 0.093 

Hydrogen Fluoride, lbs/hr 1.936 2.094 0.475 1.501 

It should be noted that between Runs #1 and #2 and plant-wide power outage occurred, 

causing the kiln to shut down. Sampling resumed once power was restored and the kiln 

was back up to temperature. 

2 &;,/ 
SUMMARY OF EMISSIONS TEST DATA 

Table : 1 

Plant : Athens Brick Company, Athens, TX 

Location : Kiln Exhaust 

Operator : D. Barrera, J. Barrera, C. Jefferson 

Test Date : 13-Dec-95 

Repetition: 1 

STACK GAS 

Temperature, F 378.6 

Velocity, fps 71.53 

Volume Flow, acfm 20742.9 

scfm 12031.0 

scfh 721859 

Moisture, % 7.10% 

CO2, % 2.50 

02, % 17.50 

SAMPLE 

Start Time, hrs:min 8:26 AM 

Fnish Time, hrs:min 9:30 AM 

Sample Volume, scf 50.476 

Isokinetic Ratio, % 101.1315 

PARTICULATE 

Front Half 

Sample Weight, mg 75.30 

Concentration, gr/scf 0.023019 

Emissions, Ibs/hr 2.374505 

Back Half 

Sample Weight, mg 8.10 

Concentration, gr/scf 0.002476 

Emissions, Ibs/hr 0.255425 

Total Particulate, Ibs/hr 2.62993 

CARBON MONOXIDE 

Concentration, ppm 64.39 

Emissions, Ibs/hr 3.378645 

NITROGEN OXIDE AS NO2 

Concentration, ppm 14.98 

Emissions, Ibs/hr 1'.291326 

VOC AS C31-18 

Concentration, ppm WB 7.37 

Concentration, ppm DB 7.933563 

Emissions, Ibs/hr 0.654165 

SULFUR DIOXIDE 

Concentration, ppm 73.85 

Emissions, Ibs/hr 8.857204 

HYDROGEN FLUORIDES 

Sample Weight, mg 186.32 

Concentration, ppm 156.7622 

Emissions, Ibs/hr 5.875401 

HYDROGEN CHLORIDE 

Sample Weight, mg 47.80 

Concentration, ppm 22.03764 

Emissions, Ibs/hr 1.507385 

2 3 

402.7 

70.69 

20500.0 

11067.0 

664023 

11.03% 

3.00 

16.00 

407.1 

69.30 

20094.2 

11245.9 

674752 

7.28% 

2.50 

17.00 

12:45 PM 

1:50 PM 

47.521 

103.5045 

2:00 PM 

3:05 PM 

46.480 

99.6274 

61.80 

0.020067 

1.904136 

98.50 

0.032699 

3.152987 

4.00 

0.001299 

0.123245 

2.027381 

61.15 

2.951556 

6.75 

0.002241 

0.216068 

3.369055 

64.48 

3.162575 

18.53 

1.469365 

15.69 

1.264266 

6.1 

6.856478 

0.520056 

6.08 

6.557181 

0.505391 

68.94 

7.605851 

85.57 

9.593107 

162.92 

145.5987 

5.019772 

44.37 

21.72749 

1.367096 

3 

151.75 

138.6522 

4.857521 

56.52 

28.29681 

1.809207 

(02, 
2 3 

106.1 105.6 

32.40 33.07 

23329.1 23810.6 

20360.1 20220.4 

1221605 1213224 

5.45 % 8.07% 

0.00 0.00 

21.00 21.00 

4:57 PM 6:11 PM 

6:00 PM 7:14 PM . 

33.485 34.213 

98.43176 101.2682 

13.90 7.80 

0.006405 0.003518 

1.118168 0.60989 

3.15 15.30 

0.001452 0.0069 

0.253398 1.196323 

1.371565 1.806214 

12.03 9.65 

1.068239 0.851021 

0.22 1.71 

0.032094 0.247747 

23.63 17.85 

24.9919 19.41679 

3.487359 2.690822 

6.78 9.55 

1.3761 14 1.925033 

26.04 6.07 

33.02619 7.534615 

2.094754 0.47462 

1.72 0.31 

1.195317 0.211529 

0.138363 0.024317 

4 &3 

SUMMARY OF EMISSIONS TEST DATA 

Table : 2 

Plant : Athens Brick Company, Athens, TX 

Location : Dryer Exhaust 

Operator : D. Barrera, J. Barrera, C. Jefferson 

Test Date : 13-Dec-95 

Repetition : 1 

STACK GAS 

Temperature, F 106.4 

Velocity, fps 33.55 

Volume Flow, acfm 24158.0 

scfm 20655.0 

scfh 1239303 

Moisture, % 7.31 % 

CO2, % 0.00 

02, % 21.00 

SAMPLE 

Start Time, hrs:min 3:40 PM 

Finish Time, hrs:min 4:45 PM 

Sample Volume, scf 33.702 

Isokinetic Ratio, % 97.65585 

PARTICULATE 

Front Half 

Sample Weight, mg 15.70 

Concentration, gr/scf 0.007188 

Emissions, Ibs/hr 1.273007 

Back Half 

Sample Weight, mg 15.30 

Concentration, gr/scf 0.007005 

Emissions, Ibs/hr 1.240573 

Total Particulate, Ibs/hr 2.51358 

CARBON MONOXIDE 

Concentration, ppm 4.39 

Emissions, Ibs/hr 0.39547 

NITROGEN OXIDE AS NO2 

Concentration, ppm 0.41 

Emissions, Ibs/hr 0.060678 

VOC AS C3H8 

Concentration, ppm WB 13.2 

Concentration, ppm 14.24163 

Emissions, Ibs/hr 2.016059 

SULFUR DIOXIDE 

Concentration, ppm 1.83 

Ernissions, Ibs/hr 0.37681 

HYDROGEN FLUORIDE 

Sample Weight, mg 23.87 

Concentration, ppm 30.07893 

Emissions, Ibs/hr 1.935457 

HYDROGEN CHLORIDE 

Sample Weight, mg 1.44 

Concentration, ppm 0.994282 

Ernissions, Ibs/hr 0.11676 
III. PROCEDURES 

The procedure for emissions sampling followed USEPA test methods as detailed in Title 

40: Code of Federal Regulations. The following methods were used: 

Method Title 

1 Sample and Velocity Traverses for Stationary Sources 

2 Determination of Stack Gas Velocity and Vohunetric Flow Rate (Type S 

Pitot Tube) 

3 Gas Analysis for CO2, 02, Excess Air and Dry Molecalar Weight 

4 Determination of Moisture Content in Stack Gases 

5 Determination of Particulate Emissions from Stationary Sources 

6C Determination of Sulfur Dioxide Emissions from Stationary Sources 

(Instrumental Analyzer Procedure) 

7E Determination of Nitrogen Oxides Emissions from Stationary Sources 

(Instramental Analyzer Proceduie) 

10 Determination of Carbon Monoxide Emissions from Stationary Sources 

25A Determination of Total Gaseous Organic Concentration Using a Flame 

Ionization Analyzer 

26A Determination of Halogens and Hydrogen Halides Emissions from 

Stationary Sources 

02 and CO2 were determined using Fyrite Analyzers. 

Sampling was performed on the 25" X 29" kiln exhaust for 2.5 minutes at each of 24 

points, 6 points per 4 traverses, making a total run duration of 60 minutes. Sampling was 

performed on the 36" X 48" dryer exhaust for 2.5 minutes at each of 24 points, 4 points 

per 6 traverses, making a total run duration of 60 minutes. Sampling was performed using 

a teflon lined heated sample probe with H20 in the first and second impingers, 0.1 NaOH 

in the third, the fourth impinger empty and the fifth 200 grms of silica geL Particulate 

sample includes `Tront-half' (probe wash and filter) and "back-half' (impinger solution 

residue). Hcl and HF were analyzed in the $rst and second impinger by IC/HPLC. 

Nox was determined using a ThermoEnvironmental Mode110 continuous Nox analyzer 

cah'brated with 50.8 ppm and 32.2 ppm EPA Protocol NO in N2 standards. 
CO was detennined using a Fuji NDIR continuous CO analyzer cahbrated with 398, 249 

and 95 ppm CO in N2 certified standards. 

VOC was determmed using a TECO Mode151 continuous FID analyzer cahbrated with 

91.6 ppm, 49.3 ppm and 31.1 ppm C3H8 in N2 EPA Protocol l gas standards. 

S02 was detennined using a Honba VIA 10 continuous S02 analyzer cahbrated with 451 

ppm and 225 ppm S02 in N2 gas standards. 

A heated teflon sample line was used xo convey the sample from the stack to the analyzers. 

All analyzers were spanned from the front of the sample line using tedla.r gas bags, and 

zeroed with nitrogen. 

i 

6 ~~ 
APPENDIX A 

& (° 
EMSSION TEST SUIVMRY 

PLANT : Athens Brick Comparry, Athens, TX 

DATE : 13-0ec-95 

PLACE : Dryer Etiaust 

RUN+k : 1 

TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 56.5 

NOmE DIAMETER (INCH.) : 0.2476 PARTICULATE WEIGHT (Frorrt half mp) 15.7 

METER COEFFICIENT (Y) : 0.99183 PARTICULATE WEIGHT (Baok haH mp) 15.3 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (In. H20) : 0.25 

GAS METER VOL(Cu.Ft) : 35.648 PERCENT CO2 0 

BAROMETRIC PRESSURE : 29.59 PERCENT 02 21 

PERCENT CO 0 

FOR CIRCULAR STACK FOR RECTANGULAR STACK 

STACK DIAMETER pneh): 0 STACK LENGTHQnchs) : 48 

STACK AREA (Sq.Ft) : 0 STACKWIDTHQnchs) : 36 

NOZaE AREA (feet): 0.000334 STACK AREA (Sq.Ft) : 12 

ENTER THE STACK AREA SHOWN ABOVE: 12 

FLOWS 

SAMPLED VOLUME (STD. CU .FT.): 33.7019 

VOLUME OF WATER VAPOR (STD. CU .FT.): 2.6595 

FRACTIONAL MOISTURE CONTENT (%): 0.0731 

DRY BASE: 79.0000 

MOLECULAR WT. OF STACK Gy4S (DRY BASE): 28.8400 

MOLECULAR WT. OF STACK GAS (WET BASE): 28.0472 

STACK PRESSURE Qndf Hp): 29.6084 

STACK GAS VELOCITY (1t/sec.): 33.5528 

ACTUAL STACK GAS FLOW RATE (ACFM): 24157.9876 

STANDARD STACK GAS FLOW RATE (SCFH): 12393026 

PARTICULATE 

FRONT HALF 

PARTICULATE CONCENTRATION (GRJSCF): 0.0072 

PARTICULATE CONCENTRATION (LBS/SCF): 1.03E-06 

PARTICULATE EMISSION (LBS(HR): 1.2730 

BACK HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0070 

PARTICULATE CONCENTRATION (LBS/SCF): 1.00E-06 

PARTICULATE EMISSION (LBS/HR): 1.2406 

ISOKINETIC RATIO (%): 97.6558 

POINTS STACK T. DELTA P QUAR D. DELTA H METER T. METER T. 

deg F INLET OUTLFT 

1 106 0.37 0.608276 1.35 84 83 

2 106 0.46 ' 0.678233 1.70 86 83 

3 106 0.57 0.754983 2.10 90 83 

4 106 0.49 0.7 1.80 91 84 

5 106 0.43 0.655744 1.60 93 83 

6 106 0.39 0.6245 1.40 93 63 

7 106 0.42 0.648074 1.50 94 84 

8 106 0.55 0.74162 2.00 95 84 

9 106 0.37 0.608276 1.40 96 85 

10 107 0.30 0.547723 1.10 95 85 

11 107 0.35 0.591608 1.30 95 85 

12 107 0.52 0.72111 1.90 95 86 

13 107 0.45 0.67082 1.70 95 86 

14 107 0.32 0.565685 1.20 95 86 

15 107 0.30 0.547723 1.10 95 86 

16 107 0.40 0.632456 1.50 95 86 

17 107 0.34 0.583095 1.20 95 86 

18 107 0.28 0.52915 1.00 95 87 

19 107 0.11 0.331662 0.40 95 87 

20 107 0.17 0.412311 0.62 93 87 

21 107 0.19 0.43589 0.70 94 87 

22 106 0.09 0.3 0.33 93 87 

23 105 0.07 0.264575 0.33 94 87 METER T. 

24 105 0.18 0.424264 0.66 93 87 AVERAGE 

106.41667 0.5657 1.2454 93.2917 85.2917 89.2917 
EMSSION TEST SUNMARY 

PLANT : Athens &ick Comparry, Athens, TX 

DATE : 13-0eo-95 

PLACE : Dryer E.*aust 

RUNk : 2 

TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 41 

NOmE DIAMETER (INCH.) : 0.2476 PARTICULATE WEIGHT (Frart half mp) 13.9 

METER COEFFICIENT (Y) : 0.99183 PARTICULATE WEIGHT (Back haH mp) 3.15 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE pn H20) : 0.26 

GAS METER VOL(Cu.Ft) : 35.298 PERCENT CO2 0 

BAROMETRIC PRESSURE : 29.59 PERCENT 02 21 

PERCENT CO 0 

FOR CIRCULAR STACK FOR RECTANGULAR STACK 

STACK D64METER pneh): 0 STACK LENGTHpnehes) : 

STACK AREA (Sq.Ft) : 0 STACKWIDTHpnehes) : 

NOZaE AREA (feet): 0.000334 STACK AREA (Sq.Ft) : 0 

ENTER THE STACK AREA SHOWN ABOVE: 12 

FLOWS 

SAMPLED VOLUME (STD. CU .FT.): 33.4848 

VOLUME OF WATER VAPOR (STD. CU.FT.): 1.9299 

FRACTIONAL MOISTURE CONTENT (46): 0.0545 

DRY BASE: 79.0000 

MOLECULAR WT. OF STACK GAS (DRY BASE): 28.8400 

MOLECULAR WT. OF STACK GAS (WET BASE): 28.2493 

STACK PRESSURE Qrieh HO): 29.6091 

STACK GAS VELOCITY (lt/sec.): 324015 

ACTUAL STACK GJ1S FLOW RATE (ACFM): 23329.09 

STANDARD STACK GAS FLOW RATE (SCFH): 1221605.49 

PARTICULATE 

FRONT HALF 

PARTICULATE CONCENTRATION (GRJSCF): 0.0064 

PARTICULATE CONCENTRATION (LBS/SCF): 9.15E-07 

PARTICULATE EMISSION (L8S/HR): 1.1182 

BACK HALF 

PARTICULATE CONCENTRATION (GRJSCF): 0.0015 

PARTICULATE CONCENTRATION (LBS/SCF): 2.07E-07 

PARTICULATE EMISSION (LBS/HR): 0.2534 

ISOKINETIC RATIO (°.6): 98.4318 

POINTS STACK T. DELTA P QUAR D. DELTA H METER T. METER T. 

dep F INLET OUTLET 

1 106 0.32 0.565685 1.20 86 86 

2 106 0.47 0.685565 1.70 85 84 

3 106 0.56 0.748331 2.00 89 83 

4 106 0.49 0.7 1.80 91 83 

5 106 0.41 0.640312 1.50 92 83 

6 106 0.37 0.608276 1.40 92 83 

7 107 0.39 0.6245 1.40 92 82 

8 107 0.54 0.734847 2.00 92 82 

9 106 0.40 0.632456 1.50 92 82 

10 106 0.31 0.556776 1.10 94 82 

11 106 0.33 0.574456 120 94 82 

12 106 0.40 0.632456 1.50 95 83 

13 106 0.37 0.608276 1.40 95 83 

14 106 0.33 0.574456 1.20 94 83 

15 106 0.30 0.547723 1.10 95 83 

16 106 0.38 0.616441 1.40 94 83 

17 106 0.32 0.565685 1.20 94 84 

18 106 0.27 0.519615 1.00 94 83 

19 106 0.11 0.331662 0.40 94 83 

20 106 0.20 0.447214 0.73 92 83 

21 106 0.14 0.374166 0.51 90 83 

22 106 0.12 0.34641 0.44 89 83 

23 106 0.08 0.282843 0.30 88 83 METER T. 

24 106 0.06 0.244949 0.27 87 83 AVERAGE 

106.08333 0.5485 1.1771 91.6667 83.0000 87.3333 

8 ~C~ 
EMSSIOM TEST SUMIMRY 

PLANT : Athem &Ick Comparry, Afhem, TX 

DATE : 13-0ec-95 

PLACE : Dryar Eshsust 

RUN# : 3 

TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 63.8 

NOZbE DU4METER (INCH.) : 0.2476 PARTICULATE WEIGHT (Frorrt hsH mp) 7.8 

METER COEFFICIENT (1r) : 0.99183 PARTICULATE WEIGHT (Back hdf mp) 15.3 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (In. H20) : 0.22 

GAS METER VOL(Cu.Ft) : 35.859 PERCENT CO2 0 

BAROMETRIC PRESSURE : 29.59 PERCENT 02 21 

PERCENT CO 0 

FOR CIRCULAR STACK FOR RECTANGULAR STACK 

STACK D64ME7ER pneh): 0 STACK LENGTHQnchs) : 

STACK AREA (Sq.Ft) : 0 STACKWIDTHQnehs) : 

NOZZLE AREA (feet): 0.000334 STACK AREA (Sq.Ft) : 0 

ENTER THE STACK AREA SHOWN ABOVE: 12 

FLOWS 

SAMPLED VOLUME (STD. CU .FT.): 34.2131 

VOLUME OF WATER VAPOR (STD. CU.FT.): 3.0031 

FRACTIONAL MOISTURE CONTENT (°6): 0.0807 

DRY BASE: 79.0000 

MOLECULAR WT. OF STACK GAS (DRY BASE): 28.8400 

MOLECULAR WT. OF STACK GAS (WET BASE): 27.9653 

STACK PRESSURE (indh Hp): 29.6062 

STACK GAS VELOCITY (1t/see.): 33.0703 

ACTUAL STACK GAS FLOW RATE (ACFM): 23810.6357 

STANDARD STACK GAS FLOW RATE (SCFH): 1213224.29 

PARTICULATE 

FRONT HALF 

PARTICULATE CONCENTRATION (GRJSCF): 0.0035 

PARTICULATE CONCENTRATION (LBS/SCF): 5.03E-07 

PARTICULATE EMISSION (LBS/HR): 0.6099 

BACK HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0069 

PARTICUL4TE CONCENTRATION (LB8/SCF): 9.86E-07 

PARTICULATE EMISSION (LBSIHR): 1.1963 

ISOKINETIC RATIO (%): 101.2682 

POINTS STACK T. DELTA P QUAR D. DELTA H METER T. METER T. 

deq F INLET OUTLET 

1 105 0.31 0.556776 1.13 83 83 

2 106 0.45 0.67082 1.64 84 80 

3 105 0.57 0.754983 2.08 86 80 

4 105 0.47 0.685565 1.71 87 79 

5 105 0.41 0.640312 1.49 89 79 

6 106 0.35 0.591608 1.28 89 79 

7 106 0.39 0.6245 1.42 89 79 

8 105 0.51 0.714143 1.86 90 79 

9 106 0.40 0.632456 1.46 91 79 

10 106 0.31 0.556776 1.13 90 79 

11 106 0.36 0.6 1.31 90 79 

12 106 0.52 0.72111 1.90 90 79 

13 106 0.46 0.678233 1.68 92 79 

14 105 0.28 0.52915 1.02 90 79 

15 106 0.36 0.6 1.31 91 79 

16 106 0.41 0.640312 1.50 91 80 

17 106 0.32 0.565685 1.17 92 79 

18 106 0.19 0.43589 0.69 91 80 

19 106 0.12 0.34641 0.44 90 79 

20 106 028 0.52915 1.02 89 80 

21 105 0.12 0.34641 0.44 89 79 

22 106 0.06 0.244949 0.22 89 79 

23 105 0.08 0.282843 0.29 88 78 METER T. 

24 104 0.18 0.424264 0.66 89 79 AVERAGE 

105.58333 0.5572 1.2021 89.1250 79.3333 84.2292 

9 /p ~ 
EMSSION TEST SUMIMRY 

PLANT : Atheru Brick Company, Atham, TX 

DATE : 13-0ec-95 

PLACE : bin Exhaust 

RUN#: 1 

TEST DURATION (MINUTES) : 60 LIOUID COLLECTED (mis) : 82 

NOm E DIAMETER (INCH.) : 0.2476 PARTICULATE WEIGHT (Front half mp) 75.3 

METER COEFFICIENT (1) : 1.0203 PARTICULATE WEIGHT (Back hal/ mp) 8.1 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in H20) : 0.67 

GAS METER VOL(Cu.Ft) : 50.544 PERCENT CO2 2.5 

BAROMETRIC PRESSURE : 29.62 PERCENT 02 17.5 

PERCENT CO 0 

FOR CIRCULAR STACK FOR RECTANGULAR STACK 

STACK DIAMETER Qnch): 0 STACK LENGTHpndu) : 29 

STACKAREA (Sq.Ft) : 0 STACK WIDTHpnehs) : 24 

NOmE AREA (feet): 0.000334 STACK AREA (S¢Ft) : 4.833333 

ENTER THE STACK AREA SHOWN ABOVE: 4.833 

FLOWS 

SAMPLED VOLUME (S7D. CU.FT.): 

VOLUME OF WATER VAPOR (STD. CU.FT.): 

FRACTIONAL MOISTURE CONTENT (%): 

DRY BASE: 

MOLECULAR WT. OF STACK GAS (DRY BASE): 

MOLECULAR WT. OF STACK GAS (WET BASE): 

STACK PRESSURE pndi Hp): 

STACK GAS VELOCITY (ft/sec.): 

ACTUAL STACK GAS FLOW RATE (ACFM): 

STANDARD STACK GAS FLOW RATE (SCFH): 

PARTICULATE 

FRONT HALF 

PARTICULATE CONCENTRATION (GRJSCF): 

PARTICULATE CONCENTRATION (LBS/SCF): 

PARTICULATE EMISSION (LBS/HR): 

BACK HALF 

PARTICULATE CONCENTRATION (GR./SCF): 

PARTICULATE CONCENTRATION (LBS/SCF): 

PARTICULATE EMISSION (LBS/HR): 

ISOKINETIC RATIO (°.6): 

50.4758 

3.8597 

0.0710 

80.0000 

29.1000 

28.3115 

29.6693 

71.5321 

20742.8818 

721859.105 

0.0230 

3.29E-06 

2.3745 

0.0025 

3.54E-07 

0.2554 

101.1315 

POINTS STACK T. DELTA P OUAR D. DELTA H METER T. METER T. 

dep F INLET OUTLET 

1 382 1.20 1.095445 2.70 71 70 

2 376 1.30 1.140175 3.00 73 71 

3 377 1.30 1.140175 3.00 75 71 

4 374 1.20 1 7 095445 2.70 77 71 

5 374 1.20 1.095445 270 77 71 

6 375 0.77 0.877496 1.80 78 72 

7 380 1.10 1.048809 2.50 79 73 

8 384 1.10 1.048809 2.50 80 73 

9 385 1.20 1.095445 2.70 80 73 

10 384 1.20 1.095445 2.70 80 74 

11 381 1.20 1.095445 2.70 80 74 

12 388 0.90 0.948683 2.00 80 75 

13 383 0.92 0.959166 2.20 79 75 

14 385 0.98 0.989949 2.20 80 75 

15 391 1.00 1 2.20 81 76 

16 396 1.10 1.048809 2.50 81 75 

17 396 1.10 1.048809 2.50 82 76 

18 401 0.84 0.916515 1.60 81 76 

19 397 0.70 0.83666 1.60 81 76 

20 310 0.72 0.848528 1.60 82 76 

21 308 0.95 0.974679 2.20 82 76 

22 388 0.83 0.911043 1.90 83 77 

23 385 0.80 0.894427 1.80 83 77 METER T. 

24 386 0.52 0.72111 1.20 83 77 AVERAGE 

378.58333 0.9969 2.2708 79.5000 74.1667 76.8333 

10 / ~ 
EMSSION TEST SUNMI RY 

PLANT : Atl~ ena Briek Comprrry, Athens, TX 

DATE : 13-Dea-05 

PLACE : YOIn E)(heuat 

RUNik : 2 

TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 125.2 

NOm.E DIAMETER (INCH.) : 0.2476 PARTICULATE WEIGHT (Front helf mq) 61.8 

METER COEFFICIENT (Y) : 1.0203 PARTICULATE WEIGHT (Baek helf mp) 4 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (In. H20) : 0.59 

GAS METER VOL(Cu.Ft) : 48.226 PERCENT CO2 3 

BAROMETRIC PRESSURE : 29.62 PERCENT 02 16 

PERCENT CO 0 

FOR CIRCULAR STACK FOR RECTANGULAR STACK 

STACK DIAMETER Qrxh): 0 STACK LENGTH(inehes) : 

STACKAREA (Sq.Ft) : 0 STACK WIDTHpnehes) : 

NOZaE AREA (feet): 0.000334 STACK AREA (Sq.Ft) : 0 

ENTER THE STACK AREA SHOWN ABOVE: 4.833 

FLOWS 

SAMPLED VOLUME (STD. CU .FT.): 47.5206 

VOLUME OF WATER VAPOR (STD. CU .FT.): 5.8932 

FRACTIONAL MOISTURE CONTENT (%): 0.1103 

DRY BASE: 81.0000 

MOLECULAR WT. OF STACK GAS (DRY BASE): 29.1200 

MOLECULAR WT. OF STACK GAS (WET BASE): 27.8931 

STACK PRESSURE (ndi Hp): 29.6634 

STACK GAS VELOCITY (ft/see.): 70.6944 

ACTUAL STACK GAS FLOW RATE (ACFM): 20499.9526 

STANDARD STACK GAS FLOW RATE (SCFH): 664022.533 

PARTICULATE 

FRONT HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0201 

PARTICULATE CONCENTRATION (L8S/SCF): 2.87E-06 

PARTICULATE EMISSION (LBS/HR): 1.9041 

BACK HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0013 

PARTICULATE CONCENTRATION (LBS/SCF): 1.86E-07 

PARTICULATE EMISSION (LBS/HR): 0.1232 

ISOKINETIC RATIO (°.6): 103.5045 

POINTS STACK T. DELTA P QUAR D. DELTA H METER T. 

dep F INLET 

1 425 0.93 0.964365 2.20 

2 302 1.30 1.140175 3.00 

3 293 120 1.095445 2.60 

4 453 1.00 1 220 

5 402 0.95 0.974679 2.10 

6 401 0.51 0.714143 1.10 

7 400 1.10 1.048809 2.40 

8 402 1.20 1.095445 2.60 

9 401 1.20 1.095445 2.70 

10 403 1.10 1.048809 2.50 

11 404 1.00 1 2.30 

12 404 0.87 0.932738 2.00 

13 395 0.98 0.989949 220 

14 408 1.00 1 2.30 

15 409 1.00 1 2.30 

16 407 0.96 0.979796 2.20 

17 409 0.94 0.969536 2.10 

18 407 0.74 0.860233 1.70 

19 410 0.77 0.877496 1.80 

20 422 0.80 0.894427 1.80 

21 424 0.83 0.911043 1.80 

22 429 0.82 0.905539 1.80 

23 428 0.75 0.866025 1.70 

24 426 0.60 0.774597 1.30 

40266667 0.9641 2.1125 

METER T. 

OUTLET 

78 78 

80 78 

81 78 

82 78 

83 78 

84 79 

84 79 

86 80 

87 80 

88 81 

88 81 

88 82 

84 82 

86 82 

87 83 

88 83 

88 83 

89 83 

90 83 

90 84 

90 84 

90 84 

90 85 METER T. 

91 85 AVERAGE 

86.3333 81.3750 83.8542 

11 ~~ 
EMSSION TEST SUNIW RY 

PLANT : Atheris Brick Company, Athens, TX 

DATE : 13-0ec-95 

PLACE : Klin Exhaust 

RUNi: 3 

TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 77.5 

NOmE DIAME7ER (INCH.) : 0.2476 PARTICULATE WEIGHT (Front half mp) 98.5 

METER COEFFICIENT (1) : 1.0203 PARTICULATE WEIGHT (Back half mp) 6.75 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE Qn. H20) : 0.52 

GAS METER VOL(Cu.Ft) : 47.541 PERCENT CO2 2.5 

BAROMETRIC PRESSURE : 29.62 PERCENT 02 17 

PERCENT CO 0 

FOR CIRCULAR STACK FOR RECTANGULAR STACK 

STACK D64METER pnch): 0 STACK LENGTHpnchs) : 

STACK AREA (Sq.Ft) : 0 STACK WIDTHpnchs) : 

NOZID.E AREA (lbet): 0.000334 STACK AREA (Sq.Ft) : 0 

ENTER THE STACK AREA SHOWN ABOVE: 4.833 

FLOWS 

SJIMPLED VOLUME (STD. CU.FT.): 46.4801 

VOLUME OF WATER VAPOR (STD. CU.FT.): 3.6479 

FRACTIONAL MOISTURE CONTENT (°•6): 0.0728 

DRY BASE: 80.5000 

MOLECULAR WT. OF STACK GAS (DRY BASE): 29.0800 

MOLECULAR WT. OF STACK GAS (WET BASE): 28.2737 

STACK PRESSURE Qnch Hp): 29.6582 

STACK GAS VELOCITY (it/sec.): 69.2951 

ACTUAL STACK GAS FLOW RATE (ACFM): 20094.1877 

STANDARD STACK GAS FLOW RATE (SCFH): 674751.828 

PARTICULATE 

FRONT HALF 

PARTICULATE CONCENTRATION (GRJSCF): 0.0327 

PARTICULATE CONCENTRATION (LBS/SCF): 4.67E-06 

PARTICULATE EMISSION (LBS/HR): 3.1530 

BACK HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0022 

PARTICULATE CONCENTRATION (LBS/SCF): 3.20E-07 

PARTICULATE EMISSION (LBS/HR): 0.2161 

ISOKINETIC RATIO (%): 99.6274 

POINTS STACK T. DELTA P QUAR D. DELTA H METER T. METER T. 

dep F INLET OUTLET 

1 397 0.91 0.953939 2.00 84 84 

2 404 0.96 0.979796 2.10 87 84 

3 403 0.98 0.989949 2.20 88 84 

4 400 1.00 1 2.20 90 84 

5 403 0.89 0.943398 2.00 90 85 

6 402 0.54 0.734847 1.20 90 85 

7 403 1.00 1 2.20 90 86 

8 402 1.10 1.048809 2.40 91 86 

9 403 1.00 1 2.20 91 86 

10 404 1.10 1.048809 2.40 91 86 

11 403 1.10 1.048809 2.40 91 86 

12 406 0.81 0.9 1.80 91 86 

13 409 0.92 0.959166 2.00 87 86 

14 411 0.94 0.969536 2.10 89 85 

15 413 0.98 0.989949 2.20 90 85 

16 412 1.00 1 2.20 91 85 

17 412 0.95 0.974679 2.10 92 66 

18 413 0.76 0.87178 1.70 92 86 

19 410 0.80 0.894427 1.80 92 87 

20 411 0.82 0.905539 1.80 91 87 

21 414 0.85 0.921954 1.90 92 87 

22 410 0.97 0.984886 2.10 92 87 

23 412 0.82 0.905539 1.80 92 87 METER T. 

24 414 0.56 0.748331 1.20 92 87 AVERAGE 

407.125 0.9489 2.0000 90.2500 85.7083 87.9792 

12 ~~ 
APPENDIX B 

-5~3 
1213GL 

FlLE MAAAE: 1213d 

LOGI'~INO SE 1 SiARr LOOl31N13 Q 1/M/// 07:1922: 

Ir3i SAMPLE 0 rY/M1iY 07:50:37: 

ACi1VEC4M 1A 1B 2A 2S 

MODLIE lYP Ydops Vdsgs VdeP VtlsP 

SMPLE RAT 16 aee 16 sso 15 ssc 18 sso 

LNTS: Vds NO; ppm Vds CO. {qn Vds VOC. ppm Vdt SOQ. ppm 

12/1311986 7:1922AM 0.1 0.8 0.0 13.0 0.1 0.9 0.0 21.12 

7:19:37AM 0.1 0.8 0.0 120 0.1 0.9 0.0 24 

7:19:52AM 0.1 0.9 QO 120 0.1 0.9 0.0 2208 

720:07AM 0.1 QB 0.0 120 0.1 0.9 0.0 23.04 

72022AM 0.1 0.8 0.0 i.0 0.1 U.9 0.0 24 

720:37AM 0.1 0.7 a0 SO 0.1 0.9 0.0 0.98 

720:52AM 0.1 0.8 0.0 6.0 0.1 Q9 0.0 3.84 

721:07AM 0.1 0.B 0.0 -4.0 0.1 Q9 0.0 1.92 

72122AM 0.1 0.e 0.0 3.0 0.1 0.9 0.0 0.9e 

721:37 AM 0.1 a8 0.0 3.a 0.0 0.0 0.0 .184 

721:52AM 0.1 0.7 0.0 4.0 0.0 0.0 0.0 d94 

722:07AM 0.1 0.6 0.0 3.0 0.0 0.0 ao 1.92 

72222AM 0.1 0.8 0.0 4.0 0.3 29 0.0 384 

72237AM 0.1 0.9 O.o 10 a3 3.1 0.0 1.92 

72252AM 0.1 aB 0.0 3.0 0.3 3.0 0.0 3.84 

723:07AM 0.1 0.8 0.0 4.0 0.3 3.3 0.0 3.84 

72322AM 0.1 Q7 0.0 3.0 7.6 78.2 0.0 1.92 

723:37 AM 0.1 Q8 0.0 20 7.7 78.5 a0 6.72 

723:52AM _ 0.1 0.7 0.0 QO 9.2 922 0.0 4.8 

724:07AM 0.1 0.7 0.0 1.0 9.2 9z1 0.0 4.8 

72422AM 0.1 0.7 0.0 0.0 Q9 e9.3 a0 .6.72 

724:37AM 0.1 0.8 0.0 3.0 0.4 3.8 0.0 288 

724:52AM 0.1 0.8 0.0 1.0 4.9 48.5 0.0 184 

725:07AM 0.1 0.B 0.0 20 4.9 49.4 0.0 4.8 

72522AM 0.1 0.8 0.0 1.0 4.9 49.4 0.0 194 

725:37AM 0.1 0.7 0.0 1.0 4.9 49.4 Qo S76 

725:52AM 0.1 0.7 0.0 3.0 ze 28.1 0.0 3.84 

728:07AM 0.1 a8 0.0 3.a 0.5 4.5 a0 3.84 

72822AM 0.1 0.8 0.0 4.0 3.1 3Q8 0.0 4.8 

72e:37AM 0.1 0.8 0.0 3.0 3.1 31.0 0.0 2Be 

726:52AA1 0.1 QB 0.0 3.0 3.1 31.0 0.0 4.8 

727:07 AM 0.1 Q8 0.0 4.0 3.1 30.9 0.0 184 

72722-AM a1 ae 0.0 20 28 28.1 a0 1.92 

727:37AM 0.1 0.e 0.0 3.0 0.4 3.7 0.0 S7e 

727:52AM 0.1 0.8 0.0 3.0 0.4 3.e 0.0 3.84 

728:07AM 0.1 0.8 0.0 37.0 a0 0.0 0.0 2ee 

72922AM 0.1 0.5 0.4 386.0 a0 0.0 0.0 3.84 

728:37AM 0.1 0.6 a4 401.0 0.0 a0 0.0 0.96 

728:62AM 0.1 0.6 0.4 4020 0.0 0.0 0.0 3.64 

729:07Ah1 0.1 0.8 0.4 4020 a1 1.1 0.0 2B8 

72922AM 0.1 0.e 0.1 1220 0.3 3.4 0.0 288 

729:37 AM 0.1 0.7 0.0 43.0 0.0 0.0 a0 4.8 

729:52AM 0.1 0.7 0.2 248.0 0.0 0.0 0.0 1.92 

7:30:07AM 0.1 0.7 0.3 254.0 0.0 -0.1 0.0 3.64 

7:3022AM 0.1 0.5 0.3 256.0 0.0 0.0 0.0 3.84 

7:30:37AM 0.1 0.6 0.3 256.0 0.1 0.e 0.0 1.92 

7:30:52AM 0.1 0.7 0.1 93.0 0.3 13 0.0 4.8 

7:31:07 AM 0.1 0.8 0.0 9.0 0.0 0.0 0.0 1.92 

7:3122AM 0.1 0.8 0.1 9a0 0.0 0.0 U.0 2BB 

7:31:37AM 0.1 0.7 0.1 101.0 0.0 0.0 0.0 z88 

7:31:52AM 41 0.7 0.1 1020 0.0 0.0 0.0 1.92 

7:32:07AM 0.1 0.7 0.1 101.0 a0 0.0 ao 3.84 

7:32'22AM a1 Qe 0.1 58.0 0.3 2e 0.0 1.92 

7:3237AM 0.1 0.e 0.0 8.o 0.1 ae 0.0 288 

7:32:62 AM 0.1 0.8 0.0 4.0 0.0 0.0 RO 3.84 

7:33:07 AM 2e 28.4 0.0 e.0 0.0 0.0 0.0 1.92 

7:33:22AM 4.4 43.e 0.0 QO 0.a 0.0 0.0 3.84 

7:33:37AM 4.5 461 0.0 SO 0.0 0.0 0.0 288 

7:33:52 AM 4.6 44.9 0.0 6.0 0.3 25 0.0 2e8 

7:34:07AM 0.2 22 0.0 5.0 0.7 29 0.0 4.8 

7:3422AM 4.4 44.3 0.0 4.0 0.0 a0 QO 1.92 

7:34:37AM 6.0 49.7 0.0 4.0 0.0 0.0 0.0 184 

7:34:52AM Qi $1.3 0.0 3.0 0.0 0.0 a0 288 

7:36:07AM 6.2 51.8 0.0 4.0 0.0 0.0 a0 1.92 

7:3572AAA 5.1 81.1 0.0 4.0 0.0 a0 0.0 6.72 

7:35:37AM 0.3 3.1 0.0 4.0 0.3 11 0.0 4.8 

7:35:52AM 0.3 2e 0.0 6.0 0.3 3.4 0.0 3.84 

7:3e:07AM 1.0 10.3 0.0 5.0 a.0 0.0 0.0 3.84 

7:3e22AM 3.4 33.5 0.0 4.0 0.0 a0 0.0 288 

7:3e:37AM 3.4 33.e 0.0 4.0 0.o 0.0 0.0 4.8 

7:38:52AM 3.4 33.e Qo 4.0 00 -0.1 0.0 1.92 

7:37:07AM 13 33.4 0.0 4.0 0.0 0.0 0.0 3.84 

7:3722AM 2.2 221 0.0 4.0 0.3 3.0 0.0 . 3.84 

7:37:37AM 0.3 3,2 0.0 4.0 O.o 0.0 0.0 4.8 

7:37:52AM 0.5 4.e 0.0 6.0 ao -0.1 0.4 3561e 

7:38:07AM 0.4 3.9 0.a 6.0 0.0 Q1 0.4 423.3e 

7:3872AM 0.3 3.4 0.0 6.0 0.0 -0.1 0.8 446.4 

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7:39:07 AM 0.3 28 0.0 4.0 0.0 0.4 0.5 488.46 

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7:39:37AM 0.3 25 0.0 4.0 0.0 d1 Q8 450 

7:39:62AM 0.3 26 0.0 4.0 0.0 L.1 0.6 460.24 

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7:49:52AM 0.2 1,8 0.0 4.0 0.0 -0.1 OS 218.98 

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8:11:02AM 1.5 14.7 0.1 59.0 0.9 &8 0.1 7290 

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8:18:17AM 1.8 15.6 0.1 59.0 0.5 a3 0.1 8152 

8:18:32AM 1.6 1a0 0.1 59.0 0.e SB 0.1 61.8 

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629:02AM 1.4 14.4 a1 e0.o 0.7 e.9 0.1 70.06 

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15 2 t~~ 
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16 

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8:57'.17AM 1.E iSe 0.1 9&0 Qe 8.4 0.7 76.84 

6:57:32AM 1.e 15.7 0.1 e&0 0.e 5.7 0.7 78.8 

8:57:47 AM 1.8 1&6 0.1 67.0 0.e &8 0.1 74.88 

8:58:02MA 1.9 15.7 a1 6&0 0.5 5.0 0.1 77.76 

8:58:17AM 1.9 1e.0 a1 e&0 0.6 9.2 0.1 73.72 

8:58:32AM 1.5 15.3 0.1 eB.O 0.6 e.4 a1 7584 

8:58:47 AM 1.9 15.9 0.1 89.0 0.6 9.1 at 78.72 

8:59:02AM 1.8 1e.0 0.1 67.0 0.9 9.3 0.1 7684 

8:59:17AM 1.8 19.4 0.1 e&0 0.7 e.8 0.1 Bae4 

8:59:32AM 1.6 16.1 a1 e7.0 1.1 ta8 0.1 79.e8 

8:59:47 AM 1.e 16.1 0.1 67.0 1.1 11.0 0.1 77.76 

9:00:02AM 1.8 16.1 0.1 e7.0 1.0 10.3 0.1 81.6 

9:00:17M1 1.9 18.3 a7 67.0 0.9 &7 0.1 78.72 

9:00:32AM 1.7 18.6 at 67.0 0.8 8.0 0.1 80.e4 

9:00:47AM 1.7 1e.5 0.1 6&0 0.8 &4 0.1 81.9 

9:01:02AM 1.6 18.3 0.1 97.0 0.7 7.1 0.1 77.78 

9:01:17AM 1.7 16.5 0.1 6&0 0.7 7.4 0.1 8266 

9:01:72 AM 1.7 16.6 a 1 67.0 0.7 7.1 0.1 80.64 

9:01:47 AM 1.e 1e.3 0.1 ee.0 0.7 9.5 0.1 8a64 

9:02:02AM 1.7 17.0 0.1 6Q0 aS 5.4 0.1 8352 

9:02:17AN 1.7 16.6 0.1 66.0 0.9 e.1 a1 81.9 

9:02:32M1 1.7 1Q6 0.1 67.0 0.7 e.5 0.1 6352 

9:02:47 AM 1.7 1e.7 0.1 67.0 0.e 6.1 0.1 83.52 

9:03:02 AM 1.7 17.4 0.1 68.0 0.e 6.3 0.1 63.52 

9:03:17 MI 1.7 19.9 0.1 8e.0 0.8 7.8 0.1 84.48 

9:03:32MA 1.7 18.9 0.1 97.0 0.8 &4 0.1 61.0 

9:03:47AM 1.7 16.9 0.1 67.0 0.7 9.8 0.1 81.6 

9:04:02MA 1.8 17.5 0.1 68.0 0.6 6.1 0.1 95.44 

9:04:17AM 1.7 19.8 0.1 e7.0 0.7 9.7 0.1 81.8 

9:04:32AM 1.7 17.0 0.1 6R0 0.7 7.2 a1 84.48 

9:04:47AM 1.7 17.3 0.1 6&0 0.7 7.4 0.1 83.62 

9:06:02AM 1.6 1e.4 0.1 87.0 0.8 7.6 0.1 81.e 

9:05:17NN 1.7 17.4 a1 e9.0 0.7 7.0 0.1 8e.4 

9:05:32AM 1.7 19.8 a1 67.0 0.7 7.2 0.1 8a64 

9:05:47AM 1.7 17.1 0.1 e&0 0.7 7.2 0.1 64.48 

9:08:02AM 1.7 1e.8 0.1 67.0 0.7 7.2 0.1 63.52 

9:0e:17AM 1.7 17.0 a1 67.0 0.5 5.0 0.7 81.e 

9:08:32AM 1.7 1e.8 0.1 9&0 0.5 4.8 0.1 84.48 

9:08:47AM 1.7 17.1 0.1 87.0 ae S8 0.1 8152 

9:07:02AM 1.7 17.1 0.1 67.0 0.8 7.9 0.1 82.58 

9:07:17AM 1.7 16.7 0.1 67.0 0.6 &3 0.1 825e 

9:07:32AM 1.7 1e.9 0.1 88.0 1.1 10.7 0.1 81.6 

9:07:47 AM 1.7 te.9 0.1 9&0 0.9 9.0 0.1 80.84 

9:08:02NN 1.7 18.6 0.1 69.0 0.7 eA 0.1 81.9 

9:08:17AM 1.7 1e.5 0.1 9&0 0.9 e.1 0.1 78.72 

9:08:32AM 1.7 16.e 0.1 e9.0 0.e 0.2 at 83.62 

9:08:47AM 1.6 16.4 at e&0 0.6 5.5 0.7 81.6 

9:09:02AM 1.7 17.0 0.1 69.0 0.6 4.9 0.1 83.52 

9:09:17 AM 1.7 1e.9 0.1 6&0 0.8 7.9 0.1 88.4 

9:09:32AM 1.7 17.0 a1 89.0 1a9 &9 a1 ffi.52 

9:09:47AM 1.7 17.0 a1 69.0 0.9 9.2 a1 8e.4 

9:10:02AM 1.7 1e.9 0.1 e&0 0.9 0.4 a1 84.48 

9:10:17AM 1.7 1e.9 ai 67.0 1.0 9.6 0.1 815e 

9:1a:32AM 1.7 17.1 0.1 e&0 0.8 8.3 0.1 64.48 

9:10:47AM 1.7 16.9 0.1 e7.0 0.8 &0 0.7 e0.84 

911:02AM 1.7 17.1 0.1 e6.0 0.7 7.1 a1 84.48 

9:11:17AM 1.7 1a.9 ai e7.0 ae 8.0 0.1 84.48 

9:11:32AM 1.7 17.0 0.1 67.0 0.9 &7 0.1 63.52 

9:11:47 AM 1.7 17.1 0.1 67.0 0.8 7.7 0.1 85.44 

9:12:02 AM 1.7 1e.7 0.1 9e.0 0.8 7.9 0.1 825a 

9:12:17 AM 1.7 17.2 0.1 67.0 0.6 e.4 0.1 83.52 

9:12:32AM 1.7 17.0 0.1 97.0 Qe 5.7 0.1 95.44 

9:12:47 AM 1.2 11.9 0.1 03.0 a7 6.7 0.1 T7.75 

9:13:02AM 0.7 7.1 0.0 380 0.8 7.6 a0 38.4 

9:13:17M1 0.9 &9 0.1 5a0 0.6 7.7 0.0 38.4 

9:13:32M1 0.9 9.0 0.0 48.0 0.9 8.5 0.0 40.32 

9:13:47 AM 1.0 9.6 0.1 64.0 1.0 10.3 0.1 628 

9:14:02M1 0.9 9.1 0.1 61.0 1.0 9.e 0.1 50.86 

914:17AM 1.0 9.8 0.1 34.0 ae 7.e 0.1 5a76 

9:14:32 AM 1.0 9.6 0.1 53.0 1.0 10.0 0.1 56.e8 

9:14:47AM 0.9 9.2 0.1 520 1.4 13.5 0.1 64.72 

9:16:02 AM 1.0 9.7 0.1 63.0 1.4 14.3 0.1 56.61 

9:15:17AM 0.9 92 0.1 520 G.9 0.4 0.1 50.66 

9:16:32AM 1.0 10.0 0.1 S&0 0.8 7.6 a1 67.e 

9:16:47 AM 10 19.6 0.1 75.0 0.8 7.7 a 7 117.12 

9:19:02AM 1.8 1&0 a1 eao 0.7 e.9 a1 108.46 

9:16:17AM 1.8 17.5 0.1 e0.0 0.7 66 0.1 10168 

9:1e:32AM 1.7 17.4 0.1 e6.0 0.e 6.7 a1 94.08 

9:1e:47AAA 1.6 17.7 0.1 e3.0 0.4 4.4 ai 90.44 

9:17:02AM 1.6 17.6 0.1 eno 0.4 4.2 ai 93.12 

9:17:17AM 1.6 18.0 0.1 6Qo 0.4 4.1 ai 89.28 

9:17:32MA 1.8 1&1 0.1 67.0 0.e S.6 0.1 69.2e 

9:17:47 MI 1.8 179 0.1 67.0 a 7 e.6 0.1 67.3e 

9:18:a2MA 1.6 1&0 a1 67.0 0.7 7.2 0.1 ee.4 

9:18:17 AA1 1.8 17.8 0.1 67.0 0.6 7.7 0.1 87.3e 

9:18:32,MA 1.8 17.9 a1 6&0 0.7 7.1 0.1 664 

9:18:471M7 1.8 17.e a1 67.0 0.7 e.e 0.1 86.4 

17 

'e- 
Stop R7 

1213R1 

9:19:02AM 1.8 17.8 41 8&0 0.7 8.7 0.1 86.1 

9:19:17AM 1.7 n.z 0.1 87.0 0. 7 7.2 0.1 8258 

919:32 AM 1.6 16.4 0.1 68.0 0.8 7.8 0.1 8256 

9:19:47 AM 1.8 16.2 0.1 89.0 0.7 8.5 0.1 80.84 

920:02AM 1.8 15.6 0.1 88.0 0.8 &0 0.1 8464 

920:17AM 1.8 15.8 0.1 89.0 0.7 8.9 0. 1 87.8 

920:32 AM 1.6 15.6 0.1 88.0 0.8 8.1 41 8464 

920:47 MA 1.5 15.2 0.1 70.0 48 &2 0.1 8258 

921:02 AM 1.8 16.1 0.1 89.0 0.9 8.9 0.1 94.48 

921:17 AM 1.7 17.1 0.1 69.0 1.0 10.1 0.1 8928 

921:32 AM 1.7 17.1 0.1 6&0 0.9 9.3 0.1 91.2 

921:47AM 1.7 18.9 0.1 8&0 0.9 Qt 0.1 87.36 

a2202AM 1.7 17.1 0.1 6&0 0.8 &3 41 87.36 

922•17 M1 1.7 17.1 0.1 8&0 0.8 7.5 0.1 85.44 

922:32 AM 1.7 17.4 0.1 6&0 0.6 8.4 0.1 84.48 

922:47 AM 1.8 17.8 0.1 8a.0 0.7 7.2 0.1 8928 

923:02AM 1.8 ~ 17.6 0.1 6&0 0.7 8.6 0.1 86.44 

923:17 AM 1.8 17.8 0.1 68.0 48 5.9 0.1 87.36 

923:32AM 1.8 17.8 0.1 8&0 0.5 4.8 0.1 8&32 

923:47AM 1.8 1&0 0.1 89.0 0.8 5.8 0.1 8&32 

Avsrap 14.98 64.39 7.37 73.85 

924:02 AM 1.8 17.8 0. 1 87.0 0.8 & 1 0. 1 89.28 

924:17AM 1.8 1&1 0.1 69.0 0.8 &4 0.1 89.28 

924:32,4A 0.3 3.2 0.0 440 0.4 4.0 0.1 85.28 

924:47 AM 0.2 1.9 0.0 5.0 0.3 3.2 40 21.12 

925:02AM 0.2 1.B 0. 0 3.0 0.3 3.3 0.0 9.6 

925:17AM 0.2 1.8 0.0 4.0 43 12 0.0 0.64 

925:32 AM 0.2 1.7 0.0 4.0 0.3 3.2 0.0 6.72 

925:47 AM 0.2 1.7 0.0 4.0 0.3 3.2 0. 0 4.8 

926:02AM 0.3 25 0.0 4.0 43 28 0.0 7.68 

928:17AM 0.2 1.9 0.0 3.0 28 27.8 0.0 3.64 

928:32AM 0.2 1.7 0.0 ZO 29 2&9 0.0 5.76 

926:47 AM 0.2 1.8 40 5.0 ' 3.0 29.5 0.0 8.72 

927;02AM 42 1.8 0.0 4.0 7.0 29.7 0.0 3.94 

927:17AM 0.2 1.9 40 4.0 29 29.4 0.0 6.72 

927:32AM 42 1.B 0.0 5.0 0.4 3.8 0.0 5.78 

927:47 AM 0.3 28 0.0 5.0 0.1 0.8 0.0 4.8 

92B:OZAM 3.4 33.7 Q0 5.0 0.1 0.5 0.0 S76 

92B:17AM 3.3 33.1 0.0 4.0 02 1.8 0.0 286 

928:32 AM 3.3 33.4 0. 0 4.0 0.2 1.8 0. 0 6.76 

928:47 AM 3.3 33.4 0.0 4.0 0.2 1.5 0.0 4.8 

929:02AM 0.4 3.8 0.0 4.0 45 4.8 0.0 4.8 

929:17AM 0.2 1.5 0.0 11.0 0.1 1.0 0.0 5.76 

929:32AM 0.2 1.6 41 1040 0.1 0.9 0. 0 286 

929:47 AM 0.2 1.6 0. 1 103.0 41 48 0.0 4.8 

9:30:02AM 02 1.5 0.1 102.0 0.1 0.8 0. 0 4.8 

9:30:17AM 0.2 1.5 0. 1 103.0 0. 1 0. 5 0.0 Z84 

9:30:32 AM 0.2 1.6 0.1 1020 0.1 0.8 0.0 &84 

9:30:47 AM 0.2 1.8 0.0 13.0 0.1 48 0.1 140.16 

9:31:02AM Q2 1.5 0. 0 5.0 0. 1 0. 5 42 213.12 

9:3117 AIN 0.2 1.5 40 4.0 0.0 0.4 0.2 230.4 

9:31:32 AM 0.1 1.4 0.0 4.0 0.0 0.4 0.2 229.41 

9:31:47 AM 0.1 1.4 40 4.0 40 0.3 0.2 236.2 

9:32'02AM 0.2 1.5 0. 0 SO 0.4 3.7 0.2 236.2 

9:3217AM 0. 2 1.5 40 10 0.4 3.8 0.0 4224 l s 

Fqp 4 

~y 
1213CAL2 

FlL.E NAME: 1213nQ 

LOGGIN6 SE 1 START LOGGINf3 ® NIMlNM 11:3231: 

LAST SAMPLE ® NMNYM 11:40:48: 

ACTIVE CJ-M tA 1B 211 2B 

MODU..E Tv vovp votq votaps v~ 

SMPLE RAT 15 sec 15 s•a 16 aec 15 see 

wTS: va[s NOiC {pm vots 00, ppm vds vOC, ppm vots S02, ppm 

12I1311996 11:32:31 AM 0.1 1.4 0.0 ao 0.4 4.2 0.0 0 

11:32'48AM 0.1 1.4 0.0 6.0 0.4 4.3 0.0 1.92 

11:37:01 AM 0.1 1.4 0.0 4.0 0.4 4.2 0.0 0.98 

11:33:18AM 0.2 1.5 0.0 -4.0 14 3.7 0.0 498 

11:33:31 AM 0.1 1.4 0.0 20 0.4 3.8 0.0 3.84 

11:33:48AM 0.1 1.4 0.0 7.0 0.0 0.4 0.0 098 

• 11:34:01 AM 0.1 1.4 0.1 020 0.0 0.4 0.0 -1.92 

11:34:18AM 0.2 1.5 0.1 100.0 0.0 0.4 0.0 3.84 

11:34:71 AM 0.1 1.4 0.1 100.0 0.0 0.0 0.0 -288 

11:34:48AM 0.2 1.6 0.1 97.0 0.0 0.0 0.0 d84 

11:36:01 AM 0.2 1.8 0.1 96.0 0.3 3.3 0.0 268 

11:3518AM 0.2 1.5 0.0 7.0 0.4 16 0.0 -4.8 

11:35:31 AM 0.2 1.5 00 a.0 9.7 98.8 0.0 -0.98 

11:35:48AM 0.2 1.5 0.0 4.0 9.2 921 0.0 2e8 

11:38:01 AM 0.2 1.8 0.0 d0 9.2 923 0.0 0 

11:3e:19 AM 0.2 1.9 0.0 -7.0 9.2 921 0.0 1.92 

11:3e:31 AM 0.2 1.8 0.0 3A 6.9 86.e 00 0.9e 

11:38:48AM 0.2 1.5 0.0 -4.0 0.4 3.9 0.0 -4.8 

11:37:01 AM 0.2 1.5 0.0 -4.0 0.3 3.4 0.0 -4.8 

11:37:18AM 0.2 1.6 0.0 1.0 0.1 0.5 0.0 d78 

11:37:31 AM 3.2 31.8 0.0 -&0 0.0 0.0 0.0 872 

11:37:48 AM 12 ' 322 0.0 -1.0 QO 0.0 0.0 -288 

11:38:01 AM 3.2 322 0.0 30 0.0 0.0 0.0 i.8 

11:38:18 AM 3.2 322 0.0 a.0 0.0 0.0 0.0 472 

11:38:31 AM 3.2 320 0.0 -20 0.3 27 0.0 .1.84 

11:38:46AM 0.2 20 0.0 -1.0 0.0 0.0 0.0 0.98 

11:39:01 AM 0.2 1.8 0.0 -7.0 0.0 0.0 0.2 196.84 

11:39:18AM 0.2 1.8 0.0 -20 0.0 41 0.2 221.78 

11:39:31 AM 0.2 1.8 0.0 45.0 QO L.1 0.2 223.e8 

11:39:4eAM 0.2 1.8 0.0 $0 0.0 -0.1 0.2 223.88 

11:40:01 AM 02 1.8 0.0 3.0 0.0 d.1 0.2 22548 

11:40:1eAM 0.2 1.9 0.0 40 0.0 -m1 02 224.84 

11:40:31 AM 0.2 1.8 0.0 -20 0.4 3.8 0.2 22272 

11:40:4e AM 0.2 1.9 0.0 0.0 0.4 7.7 0.0 17.29 

19 

P.o.1 

Ov 
1213R2A 

PILENAME 121326 

LOCit31Nf3 SE 1 STARf LOOdNG (Q NN/NisM 12:3925: 

LA6T SMRE ® NMIM 13:52:11: 

ACTIVE QHW tA 19 2A 2B 

MODIA.E TYP Vcfap VoNP VofOP Votap 

SAhPLE RAT 16 sse 15 ssa 16 sse 16 sm 

W TS: Vds Nm Fpm Va[s CO, ppn Vais VOC, pan Vats S02, ppm 

12113/1996 123928 PM 0.2 1.9 0.0 .10 02 1.8 QO 484 

12:39:41 PM 02 1.8 0.0 5.0 0.2 1.7 0.0 878 

- 1239:58 PM 0.2 1.8 0.0 6.0 0.3 29 0.0 -14.4 

12:40:11 PM 0.2 1.7 0.0 -4.0 0.5 4.6 0.0 -13.44 

12:4025 PM 1.8 15.8 0.1 58.0 a8 8.0 0.0 44.1e 

1Z:40:41 PM 1.8 16.0 0.1 57.0 0.7 6.8 a1 S28 

12:40:6ePM 1.8 16.2 a1 Sao 0.6 6.0 0.1 54.72 

12•41:11 PM 1.8 18.3 a1 5&0 0.7 8.6 0.1 66.68 

12:4128PM 1.8 1e.4 at 54.0 0.8 7.7 0.1 59.52 

12:41:41 PM 1.8 1e.2 0.1 58.0 0.8 &1 0.1 69.52 

12:41:58 PM 1.7 16.5 0.1 57.0 0.7 7.0 0.1 81.44 

Strt R4 

12:4211 PM 1.7 16.7 0.1 58.0 0.9 8.9 0.1 83.36 

12:4228PM 1.7 1e.5 at Sao 0.9 8.8 a1 6a48 

12:42:41 PM 1.7 16.9 0.1 80.0 0.6 &1 0.1 86.28 

1242:58 PM 1.8 18.2 0.1 53.0 0.7 8.5 0.1 69.62 

12:43:11 PM 1.7 16.6 0.1 56.0 0.7 7.0 0.1 91.44 

12'.4328PM 1.7 19.8 ai 57.0 aa 8.4 0.1 924 

12'43:41 PM 1.7 17.0 0.1 52o 0.e e.4 0.1 81.44 

12:43:59PM 1.7 19.7 0.1 54.0 0.7 6.8 0.1 e24 

12:44:11 PM 1.7 16.7 0.1 57.0 0.7 8.9 0.1 824 

12:4428PM 1.7 1417 0.1 54.0 0.7 &e at 60.48 

12:44:41 PM 1.7 1&5 0.1 57.0 0.8 e.3 0.1 64.32 

12:44:58 PM 1.8 15.5 0.1 57.0 0.9 5.7 0.1 58.58 

12:45:11 PM 0.e 5.9 0.0 320 1.0 10.2 0.0 34.5e 

12'4628PM 0.6 5.4 0.0 36.0 0.8 7.5 0.0 13.44 

12'45:41 PM 0.5 &1 0.0 33.0 1.1 11.0 a0 9.e 

12:45:SBPM 0.8 0.1 0.0 38.0 aa 7.9 0.0 13.44 

12:46:11 PM 0.e 6.4 0.0 40.0 0.9 9.4 0.0 - 16.32 

12:4e2e PM 0.7 7.1 a0 40.0 1.2 124 0.0 21.12 

124e:41 PM 0.8 7.5 QO 40.0 0.9 &8 0.0 25.92 

12:48:56 PM 0.9 9.0 0.0 49.0 0.8 8.4 0.0 33.8 

12'47:11 PM 0.8 8.2 0.0 40.0 0.8 7.5 0.0 34.5e 

12'472ePM 0.9 8.8 0.0 40.0 0.e S6 a0 33.e 

12'47:41 PM 0.9 9.1 0.0 43.0 0.7 6.6 QO 35.52 

12•47:58 PM 0.9 8.7 0.0 38.0 0.9 &a 0.0 38.4 

12•48:11 PM 0.8 8.4 0.0 37.0 0.7 7.0 0.0 30.72 

124828 PM 0.9 9.1 0.0 44.0 0.8 62 0.0 31.88 

12:48:41 PM 0.9 8.7 0.0 40.0 0.7 8.6 0.0 37.44 

12:48:58PM 0.9 &8 0.0 4a0 0.7 9.7 0.0 3264 

1249:11 PM 0.9 8.7 0.0 41.0 0.9 8.7 0.0 34.58 

12:4925PM 0.8 8.4 0.0 39.0 0.7 7.1 0.0 36.52 

12:49:41 PM 0.9 9.0 0.0 41.0 0.9 8.5 QO 3264 

12:49:56PM 0.9 9.4 U.0 43.0 0.8 7.5 0.0 38.4 

12:50:11 PM 20 19.9 0.1 69.0 0.5 52 0.1 74.a6 

12:6028PM zo 19.7 at 57.0 0.5 4.7 0.1 84.08 

12:50:41 PM 1.9 18.7 0.1 69.0 0.6 5.2 0.1 85.44 

12:50:58 PM 1.8 18.4 0.1 53.0 0.7 &8 . 0.1 74.88 

12:51:11 PM 1.9 1&8 0.1 $4.0 0.8 7.5 0.1 73.92 

12•5128PM 1.8 18.2 0.1 5&0 0.7 6.8 0.1 69.12 

12:51:41 PM 1.8 18.1 0.1 51.0 0.7 6.5 a1 85.24 

12:51:58PM 1.8 18.4 0.1 Sa.O Qe 5.e 0.1 a&ta 

12:52:11 PM 1.8 18.4 0.1 53.0 0.5 5.4 0.1 54.32 

125228PM 1.9 18.5 0.1 51.0 0.5 4.0 0.1 88.24 

12:52'41 PM 1.9 18.8 0.1 $4.0 0.5 4.7 0.1 ae.24 

12:52:58PM 1.8 18.1 0.1 S.10 0.7 &7 0.1 84.32 

1253:11 PM 1.9 18.5 0.1 61.0 0.8 &a 0.1 a824 

12:5328 PM 1.9 18.5 at 57.0 0.7 7.2 0.1 93.3e 

1253:41 PM 1.8 182 0.1 szo 0.7 7.2 at 6136 

12:53:56PM 1.9 18.6 0.1 64.0 0.e 0.4 0.1 98.24 

1254:11 PM 1.9 18.9 at 57.0 0.5 5.2 0.1 a3.3e 

125420PM 1.9 1&8 ai 63.0 ae 6.4 Qt 67.2 

12'54:41 PM 1.9 16.5 a1 57.0 0.7 7.1 at 65.28 

12:54:58 PM 1.9 1&9 0.1 5&0 0.7 7.4 0.1 63.38 

1255:11 PM 1.9 19.0 0.1 $4.0 0.7 8.8 0.1 68.24 

12:6625PM 1.9 18.9 0.1 6&0 0.7 e.e 0.1 64.32 

12:55:41 PM 1.9 19.2 0.1 5&0 0.7 6.9 0.1 84.32 

12:55:5ePM 1.9 1&8 at 57.0 0.7 E4 0.1 e72 

12:56:11 PM 1.9 19.o at 60.o 0.e 5.7 0.1 66.28 

125828PM 1.9 19.2 at 57.0 0.e 5.7 0.1 69.12 

12:5e:41 PM 1.9 1&8 0.1 6&0 0.5 3.3 0.1 88.24 

12:56:66PM 1.9 1&7 0.1 67.0 0.e e.0 0.1 98.24 

12:57'.11 PM 1.9 1e.e 0.1 56.0 0.7 6.6 LLt 68.1e 

12:5720 PM 1.9 18.e 0.1 68.0 0.e 6.4 0.1 66.28 

12:57:41 PM 1.9 19.0 0.1 5&0 0.5 5.4 0.1 57.2 

12:57:5ePM 1.9 18.7 at 56.0 0.7 7.2 at eale 

12:58:11 PM 1.9 18.9 0.1 eao 0.7 7.4 0.1 $4.32 

12:5825PM 1.9 1&8 0.1 S&0 0.8 7.8 0.1 99.12 

12:68:41 PM 1.9 19.1 0.1 59.0 Qe 62 a1 68.24 

12:58:56PM 1.9 19.0 0.1 69.0 0.8 5.6 0.1 67.2 

12:59:11 PM 1.9 18.7 0.1 ea0 0.e 6.1 0.1 58.1e 

12:5925PM 1.9 18.7 at at.0 aa 5.7 0.1 6628 - 

12:59:41 PM 1.9 19.0 0.1 59.0 0.6 5.3 0.1 69.12 

12:59:58PM 1.9 18.7 Qt e1t0 0.7 7.1 0.1 57.2 

1:00:11 PM 1.9 1&9 0.1 a3.0 0.9 9.2 0.1 65.26 

 1:0025PM 1.9 16.7 at 60.0 0.8 &0 0.1 09.12 

1:00:41 PM 1.9 18.7 0.1 59.0 0.7 7.3 0.1 64.32 

1:00:5ePM 1.9 1&8 0.1 a2o 0.7 bt 0.1 67.2 

1:01:11 PM 1.9 1&e 0.1 6&0 0.7 8.7 0.1 e7.2 

1:0115PM 1.9 1&a 0.1 66.0 0.e 6.9 at 54.32 

1:01:41 PM 1.9 18.7 0.1 e1.0 0.5 5.2 0.1 e&1e 

1:01:5ePM 1.9 1&e 0.1 5&0 0.7 e.8 a1 05.24 

20 p-~ 
1213faA 

1:02:11 PM 1.9 18.8 a1 e2.0 0.5 41 a1 6428 

1:022ePM 1.9 18.8 at eao 0.5 4.6 0.1 98.16 

1:02:41 PM 1.9 18.6 0.1 59.0 a5 4.8 0.1 6428 

1:02:58PM 1.9 1&8 0.1 64.0 0.9 8.0 0.1 67.2 

1:03:11 PM 1.9 18.7 0.1 a0.0 0.8 7.e 0.1 67.2 

1:0328 PM 1.9 18.8 0.1 59.0 0.8 7.7 0.1 88.24 

1:03:41 PM 1.9 18.6 0.1 e4.0 0.9 9.2 0.1 89.12 

1:03:5ePM 1.9 1&e 0.1 Bz0 0.9 &5 0.1 96Z4 

1:04:11 PM 1.9 1&7 0.1 90.0 a9 8.7 0.1 e7.2 

1:0428PM 1.9 18.7 0.1 e40 0.7 7.1 ai 641e 

1:04:41 PM 1.9 18.9 0.1 ez0 Qe 44 0.1 6e.24 

1:04:56 PM 1.9 19.0 0.1 61.0 0.e 6.9 0.1 e9.12 

1:06:11 PM 1.9 19.2 0.1 ee.0 0.e 4e 0.1 67.2 

1:0625PM 1.9 1&e 0.1 e1.0 0.7 7.0 a1 e7.2 

1:05:41 PM 1.9 1&9 at 66.0 ae 6.2 0.1 641e 

1:06:6ePM 1.9 t9.o ai 91.0 a6 40 0.1 97.2 

1:06:11 PM 1.9 19.4 0.1 5&0 0.6 4.9 a1 70.08 

1:0e26PM 1.9 19.0 0.1 91.0 ae 7.6 0.1 70.08 

1:09:41 PM 1.9 1&9 0.1 59.0 0.7 7.2 0.1 9&16 

1:08:56 PM 1.9 19.4 0.1 91.0 a9 9.1 0.1 71.04 

1:07:11 PM 1.9 19.4 0.1 94.0 0.7 7.1 0.1 68.16 

1:0725PM 1.9 19.0 a1 e1.0 aa &2 ai 69.12 

1:07:41 PM 1.9 19.1 0.1 940 0.6 5.9 a1 70.08 

1:07:5ePM 1.9 19.4 0.1 B5.0 ae 46 0.1 641e 

1:08:11 PM 1.9 19.2 a1 620 0.9 49 0.1 71.04 

1:082e PM 1.9 19.3 0.1 640 0.e 46 0.1 99.12 

1:08:41 PM 1.9 19.3 0.1 e20 0.8 45 0.1 6412 

1:08:56PM 1.9 192 0.1 63.0 0.6 48 at 72 

1:09:11 PM 1.9 1&9 0.1 940 . 0.7 4e 0.1 e&12 

1:0926PM 1.9 19.1 0.1 B3.0 0.5 5.3 0.1 69.12 

1:09:41 PM 1.9 19.0 0.1 ez0 0.6 43 a1 70.08 

1:09:6ePM 1.9 19.3 0.1 640 ae 42 0.1 641e 

1:10:11 PM z0 19.E at 61.0 0.5 4.7 0.1 71.04 

1:102ePM 1.9 19.2 0.1 920 0.6 49 0.1 71.04 

1:10:41 PM 20 19.6 0.1 e2o ae S.e 0.1 e9.12 

1:10:5ePM 20 19.6 0.1 aQo 0.6 41 0.1 72 

1:11:11 PM z0 19.8 0.1 69.0 0.6 48 0.1 6&12 

1:112ePM 20 19.8 0.1 Q40 0.7 48 at 72 

1:11:41 PM 20 20.0 0.1 ez0 0.7 46 - 0.1 71.04 

1:11:5ePM 2o 20L1 0.1 eao 0.6 5.6 0.1 7a0e 

1:12'11 PM 20 20.1 at e&0 Qe 49 0.1 729e 

1:1226PM 20 20.4 0.1 61.0 0.9 42 a1 72 

1:12:41 PM 20 20.0 0.1 84.0 0.7 6.7 a1 73.92 

1:12sePM 20 2a3 at 63.0 0.7 4s ai 72.9e 

1:13:11 PM zt 20.6 0.1 az0 0.6 8.4 0.1 71.04 

1:1328PM 21 20.6 0.1 e40 0.7 7.1 a1 74.a8 

1:13:41 PM 21 20.6 0.1 e3.0 0.6 41 ai 729e 

1:13:SePM z1 20.6 0.1 e20 0.7 &8 a1 729e 

1:14:11 PM 21 2a7 0.1 87.0 a7 7.1 0.1 76.8 

1:1428PM 21 20.6 a1 83.0 0.e 49 0.1 7296 

1:14:41 PM 21 20.8 0.1 63.o QS 43 a1 7484 

1:14:5e PM 21 20.6 0.1 67.0 Qe 6.0 0.1 74.88 

1:15:11 PM z1 20.8 0.1 Bz0 0.9 E.0 0.1 73.92 

1:152ePM z1 20.5 0.1 64.0 a6 40 a1 77.76 

1:15:41 PM 21 20.8 0.1 67.0 0.6 5.5 0.1 74.88 

1:15:56PM z1 20.7 Qt 820 0.5 5.0 0.1 7484 

1:16:11 PM 21 21.3 at e40 0.5 4.a 0.1 74a 

1:1e28PM z1 21.1 0.1 67.0 0.5 40 0.1 7484 

1:19:41 PM 21 21.0 0.1 91.0 Qe Se 0.1 77.76 

1:1e:5ePM zt 21.4 0.1 e40 ae 6.7 at 748 

1:17:11 PM 21 21.0 0.1 e3.0 ab 7e a1 70.8 

1:1728 PM 21 21.1 0.1 e3.0 0.7 48 0.1 76.72 

1:17:41 PM 21 21.3 Qi 67.0 0.6 41 0.1 74&1 

1:17:58PM zt 21.2 at 64.0 0.7 6.e a1 746 

1:ta:11 PM 21 21.1 0.1 94.0 . ae 6.4 a1 78.72 

1:192ePM z1 21.0 0.1 940 0.7 8.7 at 78.8 

1:18:41 PM 21 21.1 0.1 a4o 0.7 4e 0.1 8064 

1:1a:6ePM 21 20.3 0.1 e3.0 0.6 6.4 0.1 77.7e 

1:19:11 PM zt 21.3 41 e&o 0.7 7.0 0.1 7472 

1:192ePAA 21 20.9 at e3.0 0.7 e.8 a1 a1.e 

1:19:41 PM 21 21.2 0.1 67.0 ae 6.2 0.1 77.7e 

1:19:5ePM 21 21.0 0.1 62o . 0.e 5.9 0.1 79.68 

120:11 PM 21 21.0 0.1 a2.0 0.7 7.0 0.1 79.68 

1202ePM 21 21.4 0.1 e&0 0.7 4a ai 77.7e 

120:41 PM z1 20a 0.1 03.0 aa 7.6 0.1 a2se 

120:5ePM 21 21.1 0.1 61.0 0.9 9.0 0.1 78.72 

121:11 PM 21 20.8 0.1 a4o aa 7.7 0.1 80.64 

1212ePM z1 20.e at 6Ro aa 7.7 ai aae4 

121:41 PM z1 218 0.1 e7.0 0.7 7.2 0.1 77.7e 

121:6ePM 21 2ae ai a4o 0.7 6.8 ai 81.e 

1=11 PM 21 2a6 0.1 67.0 0.7 46 a1 78.72 1 1121 ePM 21 20.7 0.1 e&0 0.6 e.3 0.1 7&72 

1:22:41 PM z1 20.6 a1 e40 0.6 42 0.1 80.04 

1325ePM z0 20.3 0.1 e&o 0.0 6.e a1 77.7e 

123:11 PM 21 20.e 0.1 67.0 ae 46 0.1 aae4 

12338PM 21 2aa at a&o a6 41 a1 7472 

123:41PM 20 20.2 0.1 a40 0.6 40 0.1 748 

123:6ePM 20 212 0.1 640 0.5 6.4 0.1 78.72 

1'.24:11 PM 2o 2110 0.1 a40 ae 44 ai 748 

12428PM 20 20.0 0.1 67.0 0.6 5.0 0.1 77.7e 

124:41 PM 2o 19.6 0.1 e40 0.6 4.7 0.1 77.76 

124:5ePM z0 19.9 0.1 eao 0.6 4.6 0.1 76.64 

126:11 PM zo 212 0.1 64.0 0.6 4.e 0.1 7&72 

12695PM 2o 2a0 a1 e&0 0.6 4.7 a1 748 

125:41 PM 1.9 1&3 0.1 ee.o ae 47 0.1 7e.8 

125:5ePM zo 19.6 at 6&0 0.4 4.2 Qi 77.7e 

12e:11 PM zo t&7 0.1 Q&0 0.5 4.9 0.1 74.68 

1282ePM 2o 19.6 0.1 70.0 0.4 4.4 0.1 7e.8 

12e:41 PM 1.9 19.3 a1 6&0 0.6 43 0.1 75.94 

12e:68PM 1.9 114 0.1 720 a6 40 0.1 74.88 

127:11 PM 1.9 149 0.1 64.0 0.4 4.1 a1 77.76 

12726PM 1.9 111 0.1 09.0 0.6 4.7 0.1 73.92 

127:41 PM 1.9 18.9 0.1 70.0 a6 &1 0.1 76.84 

21 

~ 

P~ 2 
1213R2A 

127:58 PM 1.9 19.1 0.1 88.0 0.5 5.0 0.1 75.84 

128:11 PM 1.9 19.2 0.1 71.0 0.5 5.2 0.1 73.92 

12828PM 1.9 19.4 0.1 8&0 0.7 8.5 0.1 78.9 

128:41 PM 1.9 19.1 0.1 84.0 0.8 5.5 0.1 74.88 

128:56PM 1.9 1&6 0.1 87.0 0.6 5.7 0.1 74.88 

129:11 PM 1.9 1&6 0.1 86.0 0.8 5.6 0.1 75.84 

12928 PM 1.9 1&6 0.1 70.0 0.5 4.7 0.1 72 

129:41 PM 1.9 1&9 0.1 B&0 0.4 3.8 0.1 74.88 

129:68 PM 1.9 1&8 0.1 68.0 0.4 4.2 0.1 72.98 

1:30:11 PM 1.9 19.0 0.1 89.0 0.4 4.2 0.1 71.04 

1:3028PM 1.9 18.7 0.1 65.0 0.4 3.9 0.1 74.86 

1:30:41 PM 1.9 19.0 0.1 86.0 0.4 4.3 0.1 72 

1:30:58 PM 1.9 19.2 0.1 71.0 0.6 4.6 0.1 76.94 

1:31:11 PM 1.9 1&7 0.1 6&0 0.5 &0 0.1 76.94 

1:3128 PM 1.9 1&8 0.1 87.0 0.6 4.6 0.1 7298 

1:31:41 PM 1.9 19.1 0.1 72.0 0.4 3.8 G.1 78.a 

1:31:58PM 1.9 1&6 0.1 68.0 0.8 4.8 0.1 74.96 

1:32.•11 PM 1.9 19.0 0.1 70.0 a5 4.8 0.1 7192 

1:3228PM 1.9 1&7 0.1 69.0 a5 5.1 0.1 7Q8 

1:32:41 PM 1.9 19.1 0.1 87.0 0.5 S.1 0.1 72 

1:32'56PM 1.9 1&6 0.1 68.0 0.8 5.9 0.1 74.88 

1:33:11 PM 1.9 1&9 0.1 8&o 0.8 6.2 at 7298 

1:3326PM 1.9 19.0 0.1 88.0 0.4 4.2 0.1 72 

1:33:41 PM 1.9 19.4 0.1 8&0 0.4 3.6 0.1 75.84 

1:33:58PM zo 19.5 0.1 89.0 0.4 4.4 0.1 72 

1:34:11 PM zo 19.8 0.1 64.0 0.6 6.4 0.1 74.88 

1:3428 PM 1.9 19.4 0.1 71.0 a6 S3 0.1 74.88 

1:34:41 PM 20 19.7 0.1 87.0 0.6 5.0 0.1 73.82 

1:34:68PM zo 19.5 0.1 8Qo 0.8 5.7 0.1 7Qa 

1:35:11 PM zo 19.6 a1 69.0 a8 5.8 0.1 74.88 

1:3528 PM zo 19.9 0.1 8&0 0.6 4.6 0.1 74.86 

1:36:41 PM zo 19.9 0.1 86.0 0.8 5.7 0.1 78.9 

1:35:58PM zo 19.9 0.1 70.0 0.8 &8 a1 73.92 

1:38:11 PM zo 20.1 0.1 8&0 a8 5.7 0.1 78.8 

1:3828PM zo 20.1 0.1 71.0 0.8 S8 0.1 75.84 

1:38:41 PM 2.0 2a1 0.1 7z0 0.6 4.5 0.1 74.88 

1:36:58PM zo 20.2 0.1 67.0 0.6 6.7 0.1 77.76 

1:37:11 PM zo 20.4 0.1 71.0 0.6 5.7 0.1 74.88 

1:3728 PM 21 2a8 0.1 70.0 0.8 5.6 0.1 78.8 

1:37:41 PM zt 21.0 0.1 86.0 0.6 5.6 (11 76.6 

1:37:58PM zt 21.2 0.1 88.0 0.8 5.8 at 75.64 

1:38:11 PM z1 21.0 0.1 87.0 0.5 5.1 at 79.66 

1:3826PM 21 21.3 0.1 6&0 0.4 4.2 0.7 75.84 

1:38:41 PM z1 21.1 0.1 BB.o aa 7.8 0.1 7&72 

1:38:58PM zt 21.0 0.1 a8.o a7 7.4 at 78.72 

1:39:11 PM z1 21.2 0.1 6&0 0.6 6.2 0.1 75.94 

1:3928 PM 21 21.1 0.1 70.0 0.7 7.4 a 1 79.86 

1:39:41 PM z1 21.0 0.1 88.o 0.8 &2 0.1 78.8 

1:39:56PM zt 21.2 0.1 7ao 0.8 7.8 0.1 78.9 

1:40:11 PM zt 21.0 0.1 8&o 0.8 ao 0.1 81.6 

1:4028PM zt 21.0 0.1 88.0 as 6.4 0.1 77.78 

1:40:41 PM z1 21.2 0.1 71.0 0.5 4.7 0.1 81.8 

1:40:56 PM 21 20.8 0.1 87.0 0.8 6.6 0.1 8a84 

1:41:11 PM z1 20.3 0.1 67.0 0.5 4.6 0.1 77.78 

1:4128PM z1 21.0 0.1 8&o a6 5.4 at 91184 

1:41V1PM z1 2a7 0.1 86.0 0.6 5.2 at 77.78 

1:41:58PM zo 20.3 at 87.0 0.8 fia ai 7&72 

1:4211 PM z1 20.5 0.1 67.0 0.5 4.8 at 79.68 

1:4228PM zo 20.4 at 88.0 0.0 0.0 0.1 76.a 

1:42:41 PM zo 19.6 0.1 63.o a3 2.9 0.1 7&72 

1:42:58PM zo 20.4 0.1 71.0 0.2 1.8 0.1 77.76 

STap R2 Avwp 1&53 61.16 6.10 6&94 

1:43:11 PM zo 2a4 0.1 64.0 0.3 27 0.1 7&72 

1:4328PM zo 20.3 0.1 88.0 0.4 319 0.1 91.8 

1:43:41 PM z0 20.2 0.1 87.0 0.7 7.0 0.1 79.88 

1:43:58PM zo 2a0 0.1 64.0 0.6 4.9 0.1 at.e 

1:44:11 PM 20 19.9 0.1 6&0 0.6 5.6 0.1 79.6a 

1:4428 PM 1.3 126 0.1 64.0 a6 4.9 0.1 76.6 

1:44:41 PM 0.2 z3 0.0 3&0 0.4 4.2 0.1 a0.64 

1:44:56PM 02 z1 0.0 11.0 0.4 3.8 0.0 z8a 

1:46:11 PM o.2 zt 0.0 &0 0.4 3.9 0.0 3.84 

1:4526 PM 0.2 zo 0.0 14.0 0.4 4.2 0.0 4.6 

1:45:41 PM 0.1 1.3 0.0 10.0 0.4 3.9 0.o zB6 

1:45:58 PM 0.1 1.3 0.0 9.0 0.4 3.a 0.0 3.84 

1:48:11 PM 0.1 1.3 0.0 13.0 a4 A7 0.0 1.92 

1:4626PM 3.7 37.1 0.0 9.0 0.0 0.0 a0 1.92 

1:46:41 PM 3.3 3zs 0.0 .1.o 0.0 0.0 Qo z86 

1:48:56PM 3.2 3z4 0.0 d.0 0.0 0.0 QO 0.98 

1:47:11 PM 3.2 32.3 0.0 -4.0 0.0 a0 0.0 z86 

1:4728 PM 3.2 31.9 0.0 4.o 0.2 1.6 0.0 1.92 

1:47:41 PM 0.1 0.8 0.0 3.0 0.3 3.2 0.0 1.92 

1:47:58PIM 0.1 a6 0.0 3.0 27 27.1 ao 298 

1:48:11 PM 0.1 0.5 a0 8.0 z8 28.4 0.o 0 

1:4926PM 0.1 0.5 QO -10 2.9 28.8 0.0 1.92 

1:48:41 PM 0.0 a4 0.0 1.0 29 2&9 0.0 2.Ba 

1:48:58PM 0.0 0.4 0.0 20 29 `8.7 0.0 0.98 

1:49:11 PM 0.0 0.4 0.0 -1.0 a4 .7 ao 3.64 

1:4928PM ao 0.4 ao &o ao 0.0 0 

1:49:41 PM 0.0 0.3 0.1 89.0 QO o.! ao -1.92 

1:49:56 PM 0.0 0.4 0.1 98.0 0.0 0.:: 0.0 1.92 

1:50:11 PM QO 0.4 0.1 1o1.-^ 0.0 0-0 0.0 1.92 

1:5026PM 0.0 a4 0.1 98.0 ao aG 0.0 4.9 

1:50:41 PM ao 0.3 0.1 97.0 0.0 0.0 0.0 288 

1:50:58PM 0.0 0.4 0.0 14.0 0.0 0.0 0.1 az56 

1:51:11 PM 0.0 0.2 0.0 -20 0.0 0.1 0.2 221.78 

1:5128PM 0.0 0.2 0.0 -zo ao -0.1 0.2 228.56 

1:51:41 PM 0.0 a3 0.0 J.o 0.0 -0.1 0.2 230.4 

1:51:56PM 0.0 0.3 0.0 -zo 0.0 Q7 0.2 230.4 

t:6z'11 PM 0.0 0.3 0.0 5.0 0.0 a1 0.2 231.38 

22 ® 

PUM3 
1213R3 

FILENAME 1213/3 

LOf3GOJO SE 1 START LOG(31N0 ® MNBYN 13:S2:58: 

LAST SAWPLE ® MMA4MMI 16:14:58: 

A011VE CFM 1A 18 ?A 2B 

MODU.E TY Valep Vofap Vdam VdaP 

SAMPLE RAT 16 esc 16 ae 15 no 76 aeo 

WTB: Vds NOY, ppm Vata 00, ppm Ve1s VOC, ppm VWS S02, ppm 

1211311996 1:SZ:66PM 0.0 0.3 ao .l0 0.3 3.1 0.0 3.84 

1:63:13PA1 a3 3.3 0.0 -zo 0.6 6.2 0.0 8.7e 

1:5326PM 1.9 180 0.1 50.0 a7 7.2 0.1 8268 

1:53:43PM 1.9 19.0 0.1 6ao a7 a8 0.1 100.8 

1:53:56PM 1.9 19.1 0.1 66.a ae 8.0 a1 9184 

1:64:13PM 1.9 192 a1 69.0 0.6 6.0 0.7 101.7e 

1:5428PM 1.9 19.0 0.1 57.0 0.0 8.0 at 1aa8 - 

1:54:43PM 1.8 17.8 0.1 59.0 0.7 7.3 0.1 97.92 

1:54:68 PM 1.7 17.1 0.1 81.0 a8 7.8 0.1 97.92 

1:66:13 PM 1.7 17.0 a1 S8.0 0.7 7.0 0.1 97.92 

1:5628 PM 1.7 18.9 at 83.o 0.7 8.7 0.1 9&68 

1:55:43 PM 1.6 182 a1 56A 0.7 7.1 0.1 101.78 

1:55:58PM 1.8 18.9 0.1 Sa0 0.8 0.1 0.1 86.68 

1:58:13PM 1.9 10.1 0.1 fia0 0.5 6.4 0.1 103Ae 

1:5828PM 1.8 15.8 0.1 6flo 0.5 5.4 a1 100.8 

1:58:43PM 1.7 16.8 0.1 5&0 0.4 4.2 ai 10272 

1:56:58PM 1.8 17.7 0.1 61.0 0.4 4.4 at 111.38 

Start R3 

1:57:13PM 1.8 17.7 0.1 58.0 0.8 5.8 a1 109.44 

1:5728PM 1.8 /6.1 0.1 61.0 aG 6.7 0.1 110.4 

1:57:43PM 1.8 18.1 0.1 59.0 0.8 6.6 0.1 108.6E 

1:57:56Ph1 1.8 18.0 0.1 57.0 0.5 Sa 0.1 103.88 

1:56:13PM 1.8 18.1 0.1 59.0 0.5 4.8 0.1 10Q58 

1:58:28 PM 1.8 182 0.1 820 0.8 6.1 0.1 101.75 

1:68:43PM 1.8 182 a1 SAO 0.8 8.4 0.1 103.88 

1:58:66PM 1.8 18.0 0.1 63.0 0.8 6.4 0.1 10272 

1:59:13PM 1.8 18.0 a1 8a0 0.6 6.4 0.1 100.8 

1:5928PM 1.8 16.0 0.1 fiaa 0.8 S8 0.1 10.1.68 

1:59:43PM 1.8 17.5 a1 86.0 0.6 6.0 0.1 100.8 

1:59:68PM 1.8 17.5 0.1 6a0 0.4 4.4 0.1 9d86 

2A0:13PM 1.7 17.4 at 820 0.4 4.2 0.1 100.8 

20028PM 1.7 17.4 0.1 60.0 0.3 3.4 0.1 98.96 

2:00:43PM 1.7 17.2 at 57.0 0.4 3.8 0.1 99.64 

2:00:58PM 1.7 17.4 a1 83.0 0.4 3.7 0.1 9d88 

201:13PM 1.7 17.1 a1 61.0 0.8 S8 a1 96.98 

2•0128PM 1.7 17.2 a1 64.0 0.8 Q2 at 99.64 

2:01:43PM 1.7 iS8 0.1 87.o ae 6.7 0.1 96.04 

2:01:58 PM 1.7 18.7 0.1 81.0 G.5 5.3 0.1 96 

2:02:13 PM 1.7 147 0.1 84.0 0.5 6,4 0.1 96.04 

2:0228 PM 1.7 1Q6 0.1 61.0 . a6 5.8 0.1 94.08 

2'0Z:43 PM 1.6 1E.4 a1 62.0 0.7 6.7 a1 96.04 

2•02:58PM 1.8 18.3 0.1 86.0 0.7 8.8 at 912 

203:13PM 1.6 16.3 a1 83.0 0.7 8.8 U.1 921E 

20326PM 1.8 /8.2 0.1 88.0 0.8 0.1 0.1 91.2 

2'03:43PM 1.8 16o at 830 a8 Q2 0.7 90.24 

2•03:58PM 1.8 18.0 0.1 810 0.8 S9 0.1 93.12 

2:04:13PM 1.8 182 ai 88.0 0.7 6.7 0.1 9a24 

20428PM 1.8 1S9 0.1 82A 0.7 6.7 0.1 80.28 

204:47PM 1.6 15.8 ai 68.0 0.8 7.6 0.1 91.2 

204:58PM 1.6 15.8 a1 64.0 0.7 7.0 0.1 8932 

2'05:13PM 1.5 1S2 0.1 60.0 0.7 7.3 a1 89.28 

20528PM 1.5 1S2 a1 64.0 0.8 61 ai 87.38 

2:06:43PM 1.5 16.4 at 61.0 0.8 5.9 0.1 87.38 

205:58PM 1.5 15.4 0.1 83.0 0.7 8.7 a1 89.28 

2:06:13PM 1.5 15.2 0.1 66.0 0.7 8.7 0.1 86.44 

2•0828PM 1.6 1A2 at aza QO S7 0.1 8532 

2'08:43 PM 1.5 16.1 0.1 67.0 0.6 8.4 0.1 86.44 

2•08:58PM 1.8 16.0 0.1 8a0 0.6 6.8 0.1 85.44 

2•07:13 PM 1.5 16.1 0.1 SS.O 0.8 6.6 0.1 87.36 

2•0728 PM 1.5 1l9 0.1 860 0.Q S9 0.1 81.48 

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FlLE NM1E 1213r4 

LOGGIN6 S 1 S7ART LOOGINO ® NNN//M 15:38:12' 

LAS'T SAWFLE ® RMWMM 16:62:57: 

ACTIVE CtN 1A 1B 2A 2g 

MO011E1V Volps Vatep4 Vatp4 Vo1my4 

SAIaPLE RA 16 sso 16 aee 15 aoe 15 s»e 

INTS: VaU NOn. pppe Vots 00, ppm Vat• VOC, ppn Vata B02, ppm 

17/1311995 3:3e:12PM at 0.9 0.0 e.0 0.7 1S9 a0 -854 

3:3e27PM a1 0.9 0.0 8.0 a7 15.4 0.0 0.9e 

3:3e:42PM ai 1.0 0.0 5.0 0.7 15.0 0.0 472 

3:39:57PM a1 1.0 ao 7.0 0.7 1s.0 ao 184 

Slrt R4 

3:37:12 PM 0.1 1.0 0.0 5.0 0.8 14.5 n0 4.8 

3:3727 PM 0.1 1.1 0.0 8,0 aB 13.8 0.0 288 

3:37:42PM 0.1 1.0 0.0 SO a8 13.8 0.0 5.78 

3:37:57PM 0.1 aB 0.0 5.0 ae 17.4 0.0 2B8 

3:38:12 PM 0.1 0.6 0.0 7.0 a8 13.4 0.0 1.92 

3:3827 PM 0.1 ae 0.0 20 0.8 13.2 0.0 4.9 

3:38:42 PM 0.1 0.8 0.0 9.0 0.8 13.2 0.0 28B 

3:36:57PM 0.1 0.8 0.0 20 ae 13.e 0.0 1.92 

3:39:12PM a1 0.8 0.0 Qo ae 13.8 0.0 4.8 

3:3927PM 0.1 ae ao S.o o.e 14.1 0.0 1.92 

3:39:42PM ai 0.7 0.0 -20 0.8 14.7 0.0 288 

3:39:57 PM 0.1 0.7 0.0 60 0.6 14.5 0.0 184 

3:40:12PM 0.1 0.7 0.0 1.0 0.6 14.5 0.0 1.92 

3:4027 PM 0.1 0.7 0.0 4.0 0.8 14.6 0.0 3.84 

3:40:42 PM 0.1 0.7 0.0 8.0 ne 14.1 0.0 288 

3:40:57 PM 0.1 0.7 0.0 4.0 0.0 14.1 n0 0.98 

3:41:12PM at 0.7 a0 5.0 0.8 13.8 0.0 S84 

3:4127PM a1 0.7 a0 20 0.8 13.e 0.0 1.92 

3:41:42PM at 0.7 0.0 5.0 aB 13.8 0.0 0.9e 

3:41:57 PM 0.1 0.8 0.0 5.0 0.8 13.e 0.0 3.84 

3:42:12PM 0.1 0.8 0.0 4.0 0.8 13.4 0.0 0.98 

3:4227PM 0.1 0.7 0.0 7.0 a8 13.4 0.0 1.92 

3:42•42 PM 0.1 0.7 0.0 -20 0.8 114 0.0 3.84 

3:4257 PM 0.1 0.7 n0 7.0 0.e 13.2 0.0 0.98 

3:43:12PM 0.1 0.7 0.0 e.o U.e 127 a0 1.92 

3:4327PM 0.1 0.8 0.0 3.0 0.6 126 0.0 288 

7:43:42 PM 0.1 0.8 0.0 4.0 ae 125 0.0 0 

3:43:57PM 0.1 0.7 0.0 -20 ne 129 0.0 288 

3:44:12PM at 0.8 0.0 -20 0.8 132 0.0 0.98 

3:4427PM a1 0.8 0.0 4.0 0.e 13.4 0.0 0 

3:44:42PM 0.1 0.7 0.0 a0 0.e 13.2 0.0 288 

3:44:67PM 0.1 0.7 0.0 7.0 0.8 13.4 0.0 0 

3:45:12PM 0.1 0.7 0.0 -1.0 ae 13.4 0.0 0 

3:4527 PM 0.1 a7 0.0 3.0 aB 13.4 0.0 288 

3:46:42 PM 0.1 0.8 a0 8.0 a8 132 0.0 -1.92 

3:45:57 PM 0.1 0.7 0.0 0.0 0.e 13.2 0.0 286 

3:48:12PM 0.1 0.7 0.0 3.0 ae 13.2 0.0 1.92 

3:4627 PM 0.1 0.8 0.0 7.0 ae 13.2 0.0 a9e 

3:48:42 PM 0.1 0.8 0.0 20 0.9 129 0.0 2e8 

3:4e:67PM 0.1 ae a0 5.0 ae 13.4 0.0 0.9e 

3:47:12 PM 0.1 0.7 0.0 3.0 0.e 13.e 0.0 0.98 

3:4727 PM (11 0.7 0.0 -1.0 0.e 13.6 0.0 3.84 

3:47:42PM a1 0.7 0.0 8.0 ae 14.3 0.0 0 

3:47:67PM at 0.7 0.0 0.0 O.e 14.5 0.0 a90 

3:48:12PM 0.1 0.8 QO 20 ne 14.5 U.0 1.92 

3:4827PM 0.1 0.7 0.0 5.0 0.0 14.5 a0 -1.92 

3:48:42 PM 0.1 a7 0.0 -20 O.e 14.3 0.0 1.92 

3:48:57 PM 0.1 0.7 0.0 e.0 0.0 13.8 0.0 d9e 

3:49:12 PM 0.1 0.7 n0 -1.0 O.e 13e 0.0 -1.92 

3:4927PM 0.1 0.8 a0 3.0 ae 13.4 0.0 1.92 

3:49:42PM at 0.7 a0 S.0 0.e 13.e 0.0 288 

3:49:67PM a1 ae 0.0 1.0 aB 13.8 0.0 0 

3:50:12PM 0.1 0.7 n0 e.0 0.8 14.7 a0 0.96 

3:5027PM 0.1 0.8 a0 e.0 aB 14.5 a0 0.9e 

3:50:42PM a1 0.7 0.0 20 0.6 14.5 0.0 2B8 

3:60:57PM 0.1 0.8 0.0 8.0 aB 14.5 0.0 1.92 

3:51:12PM 0.1 0.7 0.0 4.0 ae 14.3 0.0 0.9e 

3:5127PM 0.1 0.7 a0 5.0 ae 14.5 0.0 288 

3:51:42PM 0.1 0.7 a0 0.0 U.e 14.6 0.0 0.98 

3:51:57PM 0.1 ae 0.0 1.0 0.7 14.8 0.0 1.92 

3:52:12PM a1 0.7 0.0 7.0 0.7 16,7 0.0 288 

3:5227 PM 0.1 0.7 0.0 -4.0 0.7 1Q9 0.0 0 

3:5242PM 0.1 0.7 0.0 10 0.7 15.4 a0 1.92 

3:5257 PM 0.1 0.8 0.0 d0 0.7 15.4 0.0 a98 

3:53:12PM 0.1 0.7 0.0 -20 0.7 15.2 a0 0 

3:6327PM 0.1 ae 0.0 -1.0 0.e 14.5 a0 2e8 

3:63:42PM a1 ae 0.0 1.0 0.e 14.6 0.0 0 

3:63:57PM 0.1 0.7 0.0 5.0 0.e 14.5 0.0 1.92 

3:64:12PM at 0.7 a0 -1.0 ae 14.3 0.0 1.92 

3:5427PM at 0.7 0.0 41.0 0.6 14.3 0.0 0 

3:64:42PM 0.1 0.7 0.0 S0 0.e 13.8 0.0 288 

3:54:57PM ai as 0.0 8.0 ae 14.1 0.0 0 

3:55:12PM ai 0.8 0.0 -1.0 ae 14.1 0.0 0 

3:5527PM ai 0.9 0.0 4.0 ae 13.8 0.0 1.92 

3:55:42 PM 0.1 0.8 a0 5.0 ae 13.e 0.0 d.9e 

3:65:67PM .0.1 a9 a0 3.0 ae 11e 0.0 288 

3:58:12PM 0.1 0.9 0.0 1.0 aB 13.8 0.0 1.92 

3:5827PM 0.1 0.9 0.0 7.0 0.7 14.8 a0 0.98 

3:5e:42PM 0.1 0.9 0.0 -20 0.6 14.1 0.0 3.84 

3:56:57PM 0.1 a8 0.0 -20 ne 14.5 0.0 0.98 

3:57:12PM 0.1 0.8 0.0 SO 0.0 14.5 0.0 1.92 

3:5727PM 0.1 0.7 a0 a0 0.7 14.8 0.0 1.92 

3:57:42PM 0.1 0.7 0.0 4.0 0.7 14.8 0.0 -0.9e 

3:57:57PM 0.1 0.6 a0 4.0 0.7 15.0 0.0 288 

3:58:12PM at 0.5 ao 4.0 0.8 14.6 0.0 0.9e 

3:5827PM 0.1 0.5 0.0 7.0 0.e 14.5 0.0 a9e 

3:5e:42PM ai 0.5 a0 1.0 ae 14.1 0.0 288 

2

Pip ~i 1 
1213R4 

3:56:57PM 0.1 0.5 0.0 7.0 0.6 14.3 0.0 Q98 

3:59:12 PM 0.1 0.6 0.0 1.0 0.8 13.9 0.0 1.92 

3:6927PM 0.0 Q4 0.0 4.0 Q8 13.9 QO 0.98 

3:59:42PM 0.1 0.5 0.0 20 0.8 14.1 0.o a9e 

3:59:57PM 0.1 0.5 0.0 3.0 0.6 13.9 QO 3.64 

4:00:12PM 0.0 Q4 0.0 &0 0.8 13.2 0.0 0.96 

4:0027PM QO 0.3 . 0.0 -20 0.8 129 0.0 266 

4:00:42PM QO - 0.3 0.0 &0 0.6 129 0.0 2e6 

4:00:57 PM 0.0 a4 0.0 a.0 0.6 129 0.0 0.96 

4:01:12 PM 0.0 0.7 0.0 -20 0.6 129 0.0 4.8 

4:0127PM 0.1 QS 0.0 6.0 0.8 132 QO 1.92 

4:01:42PM QO Q4 0.0 3.0 Qe 129 (10 266 

4:01:57PM 0.1 QS 0.0 8.0 Q6 127 a0 3.64 

4:02:12PM 0.1 aS 0.0 5.0 0.6 127 0.0 1.92 

4:0227PM 0.1 ae 0.0 1.0 0.6 127 O.o 4.6 

4:02:42PM 0.1 O.e 0.0 &0 0.6 1z9 0.0 1.e2 

4:02:57PM a1 0.5 0.0 4.0 0.6 125 a0 z66 

4:03:12PM 0.1 0.6 0.0 8.0 ae 125 a0 4.6 

4:0327 PM 0.0 a4 0.0 &0 0.e 12s a0 1.92 

4:03:42PM 0.0 0.3 0.0 3.0 0.6 123 0.0 3.64 

4:03:57PM 0.0 0.3 0.0 7.0 0.5 120 0.0 z68 

4:04:12 PM QO -0.1 0.0 0.0 0.6 11.8 0.0 1.92 

4:0427 PM 0.0 0.2 0.0 4.0 0.6 11.8 0.0 164 

4:04:42PM 0.0 dt 0.0 6.0 0.6 11.6 0.0 1.92 

4:04:57PM 0.0 d1 0.0 3.0 0.5 11.8 QO 286 

4:05:12PM QO a0 0.0 5.0 Q6 11.8 QO 266 

4:0527PM 0.0 -0.1 0.0 -20 0.5 11.1 0.0 Q98 

4:06:42 PM 0.0 bt 0.0 7.0 0.5 11.6 QO 3.61 

4:05:57 PM 0.0 d2 0.0 -1.0 0.5 11.4 QO 1.92 

4:08:12PM 0.0 d2 0.0 8.o 0.5 11.4 QO 266 

4:0827 PM 0.0 42 0.0 6.0 0.5 11.4 QO 1.92 

4:08:42PM 0.0 42 Qo 3.0 0.8 11.1 QO 0.98 

4:08:57 PM 0.0 -0.3 0.0 7.0 0.8 11.1 0.0 3.94 

4:07:12PM 0.0 43 0.0 -1.0 Q6 10.9 0.0 0.98 

4:0727 PM 0.0 -02 0.0 -1.0 Q5 10.4 0.0 1.92 

4:07:42 PM 0.0 4).2 QO 9.0 Qs 10.4 0.0 1.92 

4:07:57 PM 0.0 d3 0.0 -20 0.6 11.1 0.0 0.96 

4:09:12 PM 0.0 -0.2 0.0 7.0 a5 11.e 0.0 266 

4:0827 PM 0.0 d3 a0 6.0 0.5 11.1 0.0 0.98 

4:09:42 PM 0.0 44 0.0 -20 0.5 11.4 0.0 1.92 

4:09:57 PM 0.0 -0.3 0.0 7.0 0.5 11.4 QO 1.92 

4:09:12 PM 0.0 d3 0.0 1.0 0.6 10.7 (10 0 

4:0927PM 0.0 43 QO 7.0 a5 10.9 QO 3.64 

4:09:42PM 0.0 44 0.0 -1.0 Q6 10.9 0.0 a96 

4:09:57 PM 0.0 -0.4 0.0 2o a6 10.9 0.0 1.02 

4:10:12PM 0.0 44 0.0 6.0 Q6 11.1 0.0 1.92 

4:1027 PM 0.0 4).3 0.0 -2o QS 11.1 0.0 0 

4:10:42PM 0.0 b4 QO 5.0 0.5 11.1 0.0 266 

4:10:57 PM 0.0 Q1 0.0 4.0 0.5 11.1 0.0 0 

4:11:12 PM QO d4 0.0 &0 QS 11.4 QO 0.96 

4:1127 PM -0.1 -0.5 0.0 -1.0 0.5 11.8 0.0 1.92 

4:11:42 PM 0.0 -0.3 QO 0.0 0.5 11.1 0.0 -0.96 

4:11:57 PM 0.0 -0.4 0.0 &0 0.6 120 0.0 266 

4:12:12 PM 0.0 -0.4 0.0 5.0 0.5 11.6 QO Q96 

4:1227 PM dt -0.5 0.0 4.0 a6 120 QO 0.98 

4:12:42 PM -0.1 -0.5 0.0 7.0 0.5 11.8 0.0 1.92 

4:12'S7 PM dt -0.5 0.0 -4.0 Q6 120 0.0 d96 

4:13:12PM d1 45 a0 &0 0.6 120 QO 286 

4:1327PM dt -0.5 0.0 1.0 0.5 120 0.0 498 

4:13:42PM -0.1 d6 0.0 20 0.3 120 0.0 0.96 

4:13:57 PM -0.1 45 0.0 6.0 0.6 125 0.0 1.92 

4:14:12 PM -0.1 -0.5 0.0 -4.0 0.6 129 0.0 Q98 

4:1427PM -0.1 b5 0.0 -1.0 0.6 129 QO 3.84 

4:14:42 PM -0.1 d5 QO S.0 0.6 112 0.0 0.96 

4:14:57 PM 411 as 0.0 2o 0.9 13.2 0.0 1.9z 

4:15:12 PM -0.1 -0.s 0.0 7.0 ae 13.4 a0 1.92 

4:1527 PM -0.1 45 0.0 a0 ae 13.2 ao 0.96 

4:15:42 PM -0.1 46 0.0 8.0 a6 129 0.0 296 

4:16:57PM Q7 -0.S 0.0 6.0 Q6 129 QO 0.98 

4:16:12 PM -0.1 -0.8 0.0 3.0 O.S . 127 0.0 z86 

4:1627 PM -0.1 -0.6 0.0 10.o a6 1z9 0.0 1.92 

4:19:42PM 0.0 -0.1 0.0 6.0 0.8 112 0.0 0.99 

4:18:67 PM 0.1 0.6 0.0 4.0 0.6 13.2 0.0 3.64 

4:17:12PM 0.1 QS 0.0 3.0 Qe 13.8 QO 0.98 

4:1727PM 0.1 0.6 0.0 &o Q6 14.1 0.0 286 

4:17:42 PM 0.1 0.9 0.0 8.0 0.7 14.8 QO 1.92 

4:17:57 PM 0.1 a6 QO 4.0 0.6 14.6 0.0 1.92 

4:18:12PM 0.1 0.9 0.0 7.0 0.6 14.6 0.0 164 

4:1827 PM 0.1 Q6 0.0 8.0 U.e 14.6 0.0 1.92 

4:18:42PM 0.1 0.6 0.0 3.0 0.8 14.3 0.0 A91 

4:18:57 PM 0.1 QB 0.0 7.0 0.6 14.5 0.0 1.92 

4:19:12PM 0.1 0.6 0.0 4,0 a6 14.1 0.0 1.92 

4:1927PM 0.1 ae 0.0 3.0 O.e 13.e Qo 3.94 

4:19:42PM 0.1 ae 0.0 &0 0.6 13.2 QO 0.96 

4:19:37PM 0.1 0.6 0.0 4.0 ae 129 0.0 164 

420:12PM 0.1 0.7 0.0 7.0 0.6 129 0.0 1.92 

42027 PM 0.1 0.7 0.0 1.0 0.6 129 0.0 1.92 

420:42PM a1 0.7 0.0 6.0 0.8 125 0.0 3.64 

420:57PM 0.1 0.7 0.0 10.0 0.e 12s 0.0 0.9e 

421:12 PM 0.1 a7 0.0 3.0 a6 127 O.o 3.64 

42127 PM 0.1 0.7 0.0 7.0 0.6 1z9 0.0 1.92 

421:42 PM 0.1 0.7 0.0 7.0 0.6 129 Qo 1.92 

421:57 PM 0.1 0.7 0.0 3.0 a3 123 a0 25e 

422:12 PM 0.1 ae 0.0 7.0 0.e 127 0.0 (198 

42227PM 0.1 ae 0.0 3.0 ae 129 0.0 3.64 

422:42PM 0.1 0.7 0.0 6.0 0.e 129 0.0 0.98 

422:57PM 0.1 0.9 0.0 4.0 0.6 13.2 0.0 2e6 

423:12 PM 0.1 Q7 0.0 4.0 0.6 13.2 0.0 1.92 

42327 PM 0.1 O.e 0.0 7.0 0.e 127 0.0 0.96 

423:42PM 0.1 0.6 0.0 7.0 O.e 127 0.0 3.64 

423:57 PM 0.1 0.7 0.0 e.o ae 127 a0 a9e 

424:12 PM 0.1 ae 0.0 9.0 0.e 127 0.0 26e 

42427 PM 0.1 ae 0.0 4.0 0.6 129 0.0 1.92 

28 

a.o. 2 
1213R4 

424:42 PM 0.1 0.6 0.0 11.0 a8 127 0.0 0.98 

424:57 PM 0.1 0.8 U.0 8.0 06 126 0.0 3.84 

425:12 PM 0.1 0.8 0.0 8.0 06 123 0.0 0.96 

42527 PM 0.1 ae 0.0 9.0 0.5 123 0.0 3.84 

425:42PM 0.1 0.6 0.0 4.0 0.6 120 0.0 1.92 

425:57 PM 0.1 0.8 0.0 1.0 0.5 120 0.0 0.98 

428:12PM 0.1 0.6 0.0 9.0 0.6 11.8 0.0 3.84 

42827 PM 0.1 0.6 0.0 6.0 QS 11.8 0.0 268. 

428:42PM 0.1 0.5 0.0 10.0 0.5 11.6 0.0 3.84 

428:57PM 0.1 0.6 0.0 6.0 O6 120 0.0 0.98 

427:12 PM 0.1 05 0.0 4.0 0.8 11.8 0.0 0.98 

42727PM 0.1 08 0.0 7.0 0.5 123 0.0 28B 

427:42PM 0.1 0.6 0.0 20 0.8 128 0.0 098 

427:67 PM 0.1 0.6 0.0 10.0 0.8 126 0.0 3.84 

428:12PM 0.1 0.5 0.0 &0 08 125 0.0 0.88 

44827 PM 0.0 0.4 0.0 8.0 0.8 125 0.0 288 

429:42PM 0.1 0.5 0.0 11.0 0.8 127 0.0 1.92 

428:57 PM 0.1 0.5 0.0 5.0 0.8 13.2 0.0 098 

429:12PM 0.0 0.4 0.0 7.0 0.8 13.4 0.0 184 

42927PM 0.1 0.5 0.0 9.0 0.8 13.2 0.0 0.98 

429:42 PM 0.1 06 0.0 8.0 0.8 13.2 00 288 

429:57PM 0.o 0.4 0.0 10.0 0.8 13.8 Oo 1.82 

4:30:12 PM 0.0 0.4 0.0 5.0 0.8 13A 0.0 0.98 

4:3027PM 0.0 0.4 0.0 8.0 0.8 14.1 0.0 288 

4:30:42 PM 0.1 0.5 0.0 10.0 0.8 14.1 0.0 0 

4:30:67 PM 0.0 0.4 0.0 5.0 0.8 14.1 0.0 286 

4:31:12PM 0.0 0.4 0.0 8.0 0.8 14.3 QO 098 

4:3127PM 0.0 0.4 0.0 &0 0.7 15.0 0.0 0.98 

4:31:42PM 0.0 0.4 0.0 4.0 0.7 16.0 0.0 288 

4:31:57PM 0.0 0.4 0.0 9.0 0.7 15.2 0.0 0.98 

4:32:12PM 0.0 • 03 0.0 4.0 0.7 16.2 0.0 1.92 

4:3227PM 0.0 0.3 0.0 8.0 o.e 14.8 0.0 286 

4:32:42 PM 0.0 0.4 0.0 11.0 0.7 14.8 0.0 0 

4:32:57PM 0.0 0.4 0.0 5.0 0.7 14.8 0.0 1.92 

4:33:12PM U.0 0.3 0.0 10.0 0.8 14.6 0.0 288 

4:3327PM 0.0 0.3 0.0 8.0 0.8 14.1 0.0 -1.92 

4:33:42 PM 0.0 0.4 0.0 8.0 0.8 13.8 0.0 268 

4:33:57PM 0.0 0.4 0.0 120 0.8 14.1 0.0 098 

4:34:12 PM 0.0 0.4 0.0 7.0 0.8 13.6 0.0 0 

4:3427 PM QO 0.4 0.0 6.0 0.8 14.1 (10 288 

4:34:42 PM 0.0 0.3 0.0 10.0 0.8 14.1 0.0 -0.98 

4:34:57PM 0.0 0.4 0.0 8.0 0.8 13.8 0.0 288 

4:36:12PM 0.0 0.3 0.0 9.0 0.8 134 0.0 0.98 

4:3627PM 0.0 0.3 0.0 e.o ae 13.8 Oo 0.98 

4:35:42 PM 00 0.3 0.0 7.0 0.8 13.6 0.0 288 

4:36:57 PM ao 0.3 0.0 &a 0.8 13A 0.0 -1.82 

4:38:12 PM 0.0 0.1 0.0 6.a 0.8 13.2 0.0 1.92 

4:3827PM 0.0 0.2 0.0 10.0 0.8 129 0.0 a98 

4:38:42PM 0.0 0.2 0.0 4.0 0.8 129 QO -1.92 

4:38:57 PM 0.0 0.3 0.0 11.0 0.8 129 0.0 3.64 

4:37:12PM 0.0 0.2 0.0 7.0 0.8 127 0.0 0 

4:3727PM 0.0 0.2 0.0 7.0 0.8 129 0.0 -1.92 

4:37:42 PM 0.0 0.2 0.0 11.0 0.8 129 0.0 286 

4:37:57 PM 0.0 0.1 0.0 8.0 0.8 13.2 0.0 -0.98 

Sap R4 Avays 0.41 4.39 13.20 1.83 

4:38:12 PM O.a 0.0 0.0 11.0 0.6 10.7 QO 0.98 

4:3627PM 0.0 d1 0.0 7.0 0.4 10.0 0.0 3.64 

4:38:42PM 0.0 0.3 0.0 8.0 0.6 10.2 0.0 098 

4:38:57PM 0.0 -0.1 0.0 11.0 0.4 9.6 0.0 4.8 

4:39:12 PM 0.1 0.8 0.0 5.0 0.4 9.1 0.0 48 

4:3927 PM 3.4 34.1 0.0 10.0 0.1 27 0.0 4.8 

4:39:42 PM 3.4 33.5 0.0 Sa 0.1 25 0.0 7.88 

4:39:57 PM 3.4 33.7 0.0 10.0 0.1 23 0.0 4.8 

4:40:12PM 3.4 33.0 0.0 0.0 0.1 1.8 O.o 6.78 

4:4027PM -3.4 33.8 0.0 S.0 0.1 3.2 U.0 9.8 

4:40:42 PM 3.4 33.7 0.0 &0 0.1 23 0.0 672 

4:40:57PM 3.4 33.7 0.0 4.0 0.3 7.0 0.0 &84 

4:41:12 PM 27 27.0 0.0 7.0 0.4 8.2 0.0 11.52 

4:4127 PM 0.0 -0.2 0.0 10.0 0.4 7.9 0.0 &64 

4:41:42 PIN 0.0 4X2 0.0 8.0 0.4 7.9 0.0 9.8 

l:41:57 PM 0.0 -0.2 0.0 10.0 0.3 7.7 0.0 1248 

4:4212 PM 0.0 d3 0.0 7.0 0.4 7.9 0.0 &84 

4:4227 PM 0.0 Q2 0.0 7.0 0.3 7.7 0.0 9.8 

4:42'.42 PM 0.0 43 0.0 10.0 0.3 7.5 0.0 11.52 

4:42:57 PM 0.0 -0.2 0.0 7.0 0.9 19.6 0.0 &84 

4:43:12PM 0.0 -0.2 0.0 7.0 1.3 29.3 0.0 9.8 

4:4337PM 0.0 •0.2 0.0 9.0 1.3 29.7 0.0 10.58 

4:43:42 PM 0.0 -0.3 0.0 5.0 1.3 30.0 0.0 8.84 

4:43:67PM 0.0 -0.3 0.0 10.0 1.3 29.7 0.0 11.52 

4:44:12 P1d 0.0 42 0.0 7.0 1.2 27.9 0.0 Q8 

4:4427PM 0.0 -0.2 0.0 &0 0.7 16.1 0.0 .8.64 

4:44:42PM 0.0 -0.2 0.0 7.0 , 1.2 27.2 0.0 11.52 

4:44:57PM 0.0 d3 0.0 SO 0.4 9.1 QO &84 

4:46:12PM 0.0 -0.3 0.0 11.0 a4 7.9 0.0 9.8 

4:4627 PM 0.0 43 0.0 6.0 0.3 7.3 0.0 13.44 

4:46:42PM 0.0 -0.3 0.0 9.0 0.1 1.8 0.0 10.68 

4:46:67 PM 0.0 -0.4 0.1 61.0 0.1 1.1 0.0 1248 

4:48:12 PM 0.0 d4 0.1 93.0 0.1 1.1 0.0 1246 

4:4827PM o.0 44 0.1 10&0 0.1 1.1 0.0 10.56 

4:48:42PM 0.0 -0.4 0.1 101.0 0.0 0.9 0.0 13.44 

4:46:57 PM 0.0 -0.3 0.1 106.0 0.1 23 0.0 1248 

4:47:12 PM -0.1 -0.6 0.1 63.0 0.1 1.4 0.1 64.32 

4:4727PM 0.0 44 0.0 &0 0.0 0.7 0.2 185.28 

4:47:42PM 0.0 43 0.0 1&0 0.0 -0.2 0.2 193.92 

4:47:57PM 0.0 d4 0.0 8.0 0.0 -0.2 0.2 200.64 

4:46:12 PM -0.1 -0.6 0.0 7.0 0.0 -0.2 0.2 207.38 

4:4827PM -0.1 G6 0.0 120 0.0 0.2 0.2 208.4 

4:46:42PM 0.0 Q4 0.0 &0 00 0.7 0.2 209.26 

4:46:57PM 0.0 4X4 0.0 9.0 0.2 6.0 0.1 78.6 

4:49:12PM 0.0 44 0.0 10.0 0.3 8.1 0.0 30.72 

4:4927PAA -0.1 Q6 0.0 &0 29 88.3 0.0 26.92 

29 ~~ 
121JR4 

4:49:42 PM -0.1 -0.5 0.0 10.0 7.9 98.5 0.0 24.98 

4:49:57PM -0.1 -0.5 0.0 7.0 i9 98.8 0.0 21.12 

4:50:12 PM O.1 45 0.0 7.0 19 99.2 0.0 21.12 

4:5027PM -0.1 -0.5 0.0 15.0 3.9 89.0 0.0 2208 

4:50:42 PM -0.1 46 0.0 . 8.0 4.0 91.0 0.0 18.24 

4:50:57 PM -0.1 A6 0.0 11.0 3.9 BB.B 0.0 20.18 

4:51:12 PM 41 O.8 0.0 9.0 25 55.3 0.0 18.24 

4:5127 PM -0.1 -0.6 0.0 9.0 0.8 127 0.0 15.78 

4:51:42 PM -0.1 d5 &0 13.0 0.4 9.6 0.0 19.2 

4:51:57PM -0.1 -0.5 0.0 9.0 4.0 90.1 QO 1728 

4:52:12PM -0.1 d.6 0.0 8.0 4.0 90.1 QO 17.28 

4:6227PM Q7 45 0.0 13.0 4.0 90.1 0.0 20.18 

4:52:42PM d1 d8 0.0 &0 4.0 90.1 0.0 17.26 

4:5257 PM 41 -0.6 0.0 120 4.0 90.1 0.0 17.26 

30 

PP 4 ~l 
1213R5 

FlLE NIIME: 1213r6 

LOGGIN6 SE 1 SiART LOGGOV6 Q iAMMNYMb 18:53:40: 

LAST SNMPLE 0 A4pqNNS 18:08:10: 

ACi1VEQJA 1A iB 2A 28 

MODILE TY Vavps Vafaps VafeOs Vab¢ 

SM.PLE RA7 15 ssc 16 sse 15 ase 16 am 

WTS: Vots NOiG {pm Vds 00, ppm Vob VOC, ppm Vots S02, ppm 

12/1311995 4:63:40 PM -0.1 a5 0.0 9.0 a8 19.2 0.0 17.28 

4:63:65PM -0.1 a8 a0 8.0 0.5 11.6 0.0 17.28 

4:54:10PM a1 a8 QO 120 0.5 11.9 U.0 14.4 

ShR R5 

4:5425PM at -0.8 0.0 9.0 0.4 9.6 0.0 16.32 

4:54:40PM 0.0 a4 0.0 16.0 0.6 19.2 0.0 14.4 

4:54:55PM 0.0 a2 0.0 11.0 0.9 23.8 0.0 1248 

4:55:10 PM 0.0 a2 0.0 16.0 1.0 24.8 0.0 14.4 

4:6525 PM 0.0 -0.2 0.0 10.0 1.0 25.3 a0 1248 

4:66:40 PM 0.0 -02 0.0 11.0 1.0 25.6 0.0 11.52 

4:55:55 PM 0.0 a2 0.0 17.0 1.0 25.0 0.0 14.4 

4:58:10 PM 0.0 a2 0.0 13.0 1.0 24.8 a0 11.52 

4:5825 PM 0.0 -0.2 0.0 11.0 1.0 24.8 0.0 10.58 

4:58:40PM QO a1 0.0 16.0 1.0 25.0 a0 1248 

4:68:55 PM a0 a2 0.0 120 1.0 25.8 0.0 9.8 

4:57:10 PM 0.0 a2 0.0 13.0 1.0 25.3 QO 9.9 

4:5725 PM 0.0 a3 0.0 11.0 1.0 25.0 0.0 11.52 

4:57:40 PM 0.0 -0.4 0.0 11.0 1.0 24.8 0.0 8.84 

4:57:55PM 0.0 a4 0.0 120 1.0 24.3 0.0 11.62 

4:58:10 PM 0.0 a4 0.0 10.0 0.9 23.5 0.0 9.e 

4:5825PM a.1 -0.s 0.0 14.0 0.9 23.0 0.0 7.68 

4:58:40PM a1 as 0.0 120 0.9 228 a0 10.58 

4:68:66PM -0.1 a6 0.0 15.0 0.9 223 0.0 7.68 

4:59:10PM at a6 0.0 120 a9 21.8 0.o 8.72 

4:5925PM a1 a5 0.0 11.0 ab 21.3 0.0 9.e 

4:69:40PM at a5 0.0 16.0 0.8 202 0.0 8.72 

4:59:65PM a1 as 0.0 12o a6 19.6 0.0 7.68 

5:00:10PM a1 ae 0.0 16.0 a8 19.2 0.0 8.84 

5:0025PM a1 as 0.0 16.0 0.8 19.7 0.0 6.78 

5:00:40PM a1 ae 0.0 11.0 0.8 19.2 0.0 7.68 

5:00:66PM a1 a5 a0 17.0 ab 19.0 0.0 8.54 

5:01:10PM -0.1 ae 0.0 11.0 0.7 18.5 0.0 5.7e 

5:0125PM a1 46 0.0 13.0 0.7 18.2 0.0 7.68 

5:01:40PM -0.1 as 0.0 17.0 0.7 16.2 0.0 768 

5:01:65 PM 0.0 a3 a0 9.0 0.7 182 a0 6.7e 

6:0210 PM 0.0 a3 0.0 14.0 0.7 18.5 0.0 8.04 

5:0225PM 0.0 a3 0.0 10.0 ab 19.2 0.0 6.72 

5:0240 PM 0.0 44 0.0 17.0 0.8 19.5 0.0 5.78 

5:0255PM 0.0 a3 0.0 120 0.8 19.7 0.0 9.8 

5:03:10PM 0.0 a4 0.0 11.0 ab 20.2 a0 e.72 

5:0325PM a1 46 0.0 10.0 as 20.2 0.0 5.70 

5:03:40PM a1 a6 0.0 13.0 0.8 20.2 0.0 8.84 

5:03:55PM -0.1 . as 0.0 tzo 0.8 20.0 0.0 6.7e 

5:04:10PM -0.1 ae 0.0 1a0 0.8 19.0 0.0 7.68 

5:0425PM a1 ae 0.0 13.0 0.7 18.0 0.0 7.68 

5:04:40PM a1 -0.7 a0 17.0 0.7 18.0 0.0 5.7e 

5:04:56PM -0.1 a7 0.0 120 0.7 17.7 0.0 8.84 

5:05:10PM a1 a.i ao 13.0 0.7 18.0 a0 5.7e 

5:0625 PM -0.1 Q7 a0 15.0 0.7 1&0 0.0 7.68 

5:05:40 PM -0.1 as 0.0 15.0 0.8 19.0 0.0 0.72 

5:05:56PM -0.1 ae 0.0 12o 0.8 19.5 0.0 5.78 

5:08:1oPM a.1 47 0.0 14.0 ab 19.2 a0 a84 

5:0825PM at a7 0.0 120 0.8 19.2 0.0 5.7e 

5:0e:40PM - a1 -0.e 0.0 110 0.8 2a0 0.0 7.68 

5:0e:68PM 0.1 0.5 0.0 11.0 0.8 2a5 a0 6.76 

5:07:10PM a1 0.5 0.0 13.0 ab 20.7 0.0 6.7e 

5:0725PM 0.1 0.5 0.0 1e.0 0.8 20.7 0.0 7.e8 

5:07:40 Phl 0.0 0.4 0.0 14.0 48 20.5 0.0 4.8 

5:07:55 PM 0.1 0.5 0.0 17.0 0.8 20.0 0.0 7.88 

5:08:10PM 0.1 0.6 QO 18.0 0.8 20.2 0.0 4.8 

5:0825PM 0.0 a4 0.0 13.0 0.8 20.7 QO 5.70 

5:08:40PM 0.1 0.6 0.0 160 0.9 21.8 0.0 7.68 

5:08:66PM 0.1 0.5 0.0 1e.0 a9 228 U.0 4.6 

5:09:10PM 0.1 0.6 0.0 13.0 1.0 24.0 QO 5.78 

5:0925 PM 0.0 0.4 0.0 18.0 1.0 25.0 0.0 9.72 

5:09:40PM a1 as 0.0 11.0 1.0 25.e O.o 4.8 

5:09:56PM 0.0 0.4 0.0 17.0 1.1 2e.8 0.0 7.68 

5:10:10PM 0.0 0.4 0.0 16.0 1.1 27.3 0.0 4.8 

5:1025PM QO 0.4 0.0 13.0 1.1 27.3 0.0 5.78 

5:10:40PM 0.1 0.5 0.0- 15.0 1.1 27.3 0.0 6.76 

5:10:66PM 0.1 0.5 0.0 12o 1.1 27.1 0.0 4.8 

5:11:10PM 0.1 0.6 0.0 13.0 1.1 2e.e 0.0 672 

5:1125PM a1 0.6 0.0 18.0 1.1 2e.e a0 4.8 

5:11:40 PM 0.1 ae 0.0 120 1.0 25.7 0.0 6.72 

5:11:55PM 0.1 0.5 0.0 19.0 1.0 2e.3 0.0 4.8 

S:12•1oPAA 0.1 a6 0.0 1e.0 1.1 27.3 0.0 5.7e 

5:1225PM 0.1 0.5 0.0 110 1.1 266 0.0 10.58 

5:12'40PM 0.1 a6 0.0 17.0 1.2 29.3 0.0 7.88 

6:1236PM 0.1 0.5 0.0 15.0 12 3a1 40 10.58 

5:13:10PM 0.0 0.4 0.0 18.0 1.2 30.4 QO 7.86 

3:1326 PM 0.0 0.4 0.0 16.0 1.2 29.8 C.0 8.64 

5:13:40PM QO 0.4 0.0 16.0 1.2 29.1 0.0 9.8 

5:13:56PM U.1 0.5 0.0 19.0 1.1 29.8 0.0 6.72 

5:14:10PM 0.0 0.4 0.0 120 1.1 28.8 0.0 7.68 

5:1425PM 0.1 0.8 0.0 16.0 1.2 29.3 0.0 8.64 

5:14:40PM 0.0 0.4 0.0 13.0 1.2 30.4 0.0 5.7e 

5:14:56PM 0.0 0.4 0.0 13.0 1.2 30.9 0.0 7.68 

6:1610PM 0.0 0.4 0.0 18.0 1.2 31.4 0.0 7.88 

5:1526PM 0.0 0.4 0.0 10.0 1.3 321 0.0 e.72 

6:15:40PM 0.0 0.4 0.0 14.0 1.3 320 0.0 8.84 

5:15:55PM 0.0 0.4 0.0 18.0 1.3 33.1 0.0 8.72 

6:18:10PM 0.0 0.4 0.0 13.0 1.3 33.4 0.0 7.68 

31 

Pw•1 9Zi 
1213R5 

5:1825 PM a0 0.4 0.0 20.0 1.3 33.9 0.0 6.72 

5:18:40 PM 0.0 0.3 0.0 18.0 1.3 33.4 0.0 5.78 

5:18:55 PM 0.1 0.5 0.0 14.0 1.4 34.2 0.0 &e4 

5:17:10PM 0.0 0.4 0.0 21.0 1.3 33.9 0.0 5.78 

5:1725PM 0.0 0.4 0.0 14.0 1.3 33.4 0.0 7.68 

5:17:40PM 0.0 0.4 0.0 15.0 1.3 33.1 0.0 7.88 

5:17:56PM 0.0 0.3 0.0 18.0 1.0 25L3 0.0 5.78 

s:1a:1oPM 0.0 0.4 0.0 19.0 1.0 25.3 0.0 8.84 

5:1825 PM 0.0 0.3 ao 10.0 1.0 25.e 0.0 8.72 

5:18:40 PM 0.0 0.4 a0 14.0 1.1 2&a 0.0 6.72 

5:18:55 PM 0.0 0.4 0.0 14.0 1.1 . 27.6 0.0 9.e 

5:19:10 PM 0.0 0.3 0.0 10.0 1.1 27.8 0.0 e.72 

6:1925 PM 0.0 0.4 0.0 14.0 1.1 28.1 0.0 &84 

6:19:40 PM a0 0.4 0.0 &0 1.1 2&3 0.0 6.72 

5:19:66 PM a0 0.4 0.0 9.0 1.1 2&9 0.0 S7e 

520:10 PM QO 0.4 0.0 14.0 1.1 27.8 0.0 8.84 

52025PM 0.0 a4 0.0 11.0 1.1 27.1 QO S76 

520:40PM 0.0 0.4 0.0 14.0 1.0 25.8 0.0 6.78 

520:55PM 0.0 (13 a0 11.0 1.0 25.0 0.0 7.88 

521:1OPM 0.0 a4 0.0 11.0 1.0 25.0 0.0 5.78 

52125 PM 0.0 0.3 0.0 15.0 1.0 24.8 0.0 8.72 

521:40PM 0.0 0.4 0.0 10.0 1.0 25.0 0.0 5.78 

521:56PM a0 0.4 0.0 14.0 1.0 25.0 0.0 578 

52210PM QO 0.4 0.0 13.0 1.0 25.8 0.0 6.72 

52225 PM 0.0 0.3 0.0 11.0 1.0 25.8 0.0 4.8 

522:40PM 0.0 0.3 a0 14.0 1.0 24.8 0.0 7.68 

622:66PM 0.0 0.3 0.0 12.o 1.0 24.3 0.0 &78 

523:10PM 0.0 a4 a0 11.0 0.9 23.5 0.0 S78 

52725PM 0.0 0.4 0.0 15.0 0.9 23.3 0.0 7.e8 

523:40PM 0.0 0.2 0.0 11.0 0.9 23.6 a0 4.8 

523:56PM 0.0 0.3 0.o 9.0 1.0 24.0 0.0 7.68 

524:10PM 0.0 0.3 0.0 14.0 1.0 24.3 0.0 S.78 

524'15PM 0.0 0.3 0.0 11.0 1.0 24.8 0.0 5.78 

524:40PM 0.0 0.3 0.0 14.0 1.0 25.8 0.0 7.88 

524:66PM 0.0 0.4 0.0 17.0 1.0 25.a 0.0 4.8 

5'15:10PM QO 0.3 QO 10.0 1.0 29.1 0.0 &78 

52525PM ao 0.3 0.0 18.o 1.0 21L1 0.0 8.72 

525:40 PM 0.0 0.4 0.0 11.0 1.0 25.8 0.0 4.6 

525:66PM a0 0.3 0.0 14.0 1.0 24.8 0.0 8.72 

528:10PM 0.0 0.3 0.0 17.0 1.0 24.0 0.0 4.6 

52825PM 0.0 0.4 0.0 10.0 0.9 23.5 0.0 5.78 

529:40PM 0.0 0.3 0.0 120 0.9 23.3 0.0 4.8 

528:56PM 0.0 0.3 0.0 15.0 0.9 23.3 a0 3.54 

527:10PM 0.0 0.3 0.0 110 0.9 23.0 0.0 6.72 

52725PM 0.0 0.3 0.0 130 0.9 228 0.0 3.84 

527:40PM (10 0.3 0.0 1&0 0.9 225 0.0 4.6 

527:65PM 0.0 0.4 a0 12.0 0.9 220 0.0 4.8 

528:10 PM 0.0 0.2 0.0 14.0 0.9 22.3 0.0 2.aa 

52825 PM 0.0 0.3 0.0 1Q0 0.9 21.8 0.0 5.78 

528:40 PM 0.0 0.3 0.0 14.0 0.8 20.7 0.0 1.92 

528:65 PM 0.0 0.3 0.0 18.0 0.8 20.6 0.0 3.84 

529:10 PM 0.0 0.3 0.0 11.0 0.8 20.5 0.0 161 

52925 PM 0.0 0.2 a0 16.0 0.8 20.2 0.0 2.88 

529:40PM 0.0 0.4 0.0 13.0 0.8 20.7 0.0 4.8 

529:55 PM 0.0 0.2 a0 13.0 0.8 20.7 0.0 2a8 

6:30:10 PM 0.0 0.3 0.0 17.0 0.8 20.2 0.0 6.7e 

5:3025PM ao 0.2 a0 13.0 aa 20.0 a0 3.84 

5:30:40PM a0 0.3 0.0 18.0 a8 19.s 0.0 3.84 

5:30:65PM 0.0 0.3 0.0 10.0 0.8 19.2 0.0 S78 

5:31:10PM 0.0 0.2 a0 9.0 0.8 19.2 0.0 2ea 

5:3125PM 0.0 0.2 0.0 11.0 a8 19.2 0.0 6.78 

5:01:40 PM 0.0 0.3 0.0 &0 0.7 16.5 0.0 3.84 

5:31:55PM 0.0 0.3 0.0 7.0 0.7 18.6 0.0 Z84 

5:3210 PM 0.0 0.3 0.0 11.0 a8 20.0 QO 5.78 

5:3225 PM 0.0 0.2 0.0 5.0 a8 19.5 0.0 3.84 

5:32'40 PM 0.0 0.2 0.0 5.0 0.8 19.7 0.0 6.72 

5:32:55PM 0.0 0.1 0.0 5.0 0.5 19.2 0.0 3.84 

5:33:10PM 0.0 0.3 0.0 11.0 0.8 19.0 0.0 4.6 

5:3325 PM 0.0 0.1 0.0 &0 0.8 19.0 0.0 4.a 

5:33:40 PM 0.0 0.3 0.0 &0 0.8 19.2 0.0 2.e8 

5:33:66 PM 0.0 0.3 a0 15.0 0.8 19.5 0.0 &72 

5:34:10 PM 0.0 0.4 0.0 &0 0.8 20.2 0.0 184 

5:3445 PM 0.0 0.4 0.0 9.0 . 0.8 21.3 0.0 3.94 

5:34:40PM 0.0 0.4 0.0 15.0 0.9 21.8 0.0 6.72 

5:34:55 PM 0.1 0.5 0.0 &0 0.9 22.0 0.0 4.8 

5:36:10PM 0.1 0.5 0.0 9.0 0.9 22.0 0.0 3.84 

5:3625PM 0.1 a8 0.0 1&0 0.9 22.0 0.0 8.72 

5:36:40 PM 0.1 0.8 0.0 6.0 a9 22.3 0.0 4.8 

5:35:55PM at 0.5 0.0 120 0.9 225 0.0 3.84 

5:39:10 PM 0.1 0.e 0.0 7.0 0.9 225 0.0 7.68 

5:3e25PM a1 a5 0.0 120 0.9 226 0.0 4.8 

5:3e:40 PM O.o 0.4 a0 11.10 0.9 21.3 0.0 S7e 

5:39:55PM a0 0.4 0.0 4.0 0.9 21.3 0.0 0.72 

5:37:10 PM a0 0.4 0.0 13.0 0.9 21.5 0.0 4.8 

5:3725 PM QO 0.4 0.0 &0 0.9 21.5 0.0 6.72 

5:37:40 PM 0.0 0.3 0.0 8.0 0.9 21.6 0.0 5.78 

5:37:55 PM 0.0 0.3 0.0 13.0 0.9 220 a0 5.7e 

5:38:10 PM 0.0 0.3 0.0 7.0 0.9 21.5 0.0 8.72 

5:3825 PM 0.0 0.3 0.0 11.0 a9 2z0 0.0 5.7e 

5:38:40 PM 0.0 0.3 0.0 13.0 0.9 226 a0 6.84 

5:38:56 PM a0 0.3 0.0 10.0 a9 22.8 0.0 S7e 

5:39:10 PM 0.0 0.4 0.0 14.0 0.9 23.3 0.0 872 

5:3923 PM 0.0 0.3 0.0 10.0 0.9 23.0 0.0 7.89 

5:39:40 PM 0.0 0.3 0.0 9.0 0.9 23.3 0.0 6.78 

5:39:66PM 0.0 0.3 0.0 11.0 0.9 22.3 0.0 8.e4 

5:40:10PM 0.0 0.3 0.0 10.0 ae 20.6 0.0 A72 

5:4025 PM 0.0 0.3 0.0 10.0 ae 20.0 0.0 e.72 

5:40:40 PM 0.0 0.2 0.0 10.0 0.8 20.6 0.0 &e4 

6:40:56 PM 0.0 0.3 0.0 7.0 ae 20.2 0.0 &7e 

5:41:10PM 0.0 0.3 0.0 10.0 0.8 20.2 0.0 &64 

6:4125PM 0.0 0.3 0.0 7.0 0.6 20.5 a0 0.72 

5:41:40PM 0.0 0.3 0.0 5.0 0.9 21.0 0.0 8.72 

5:41:66PM 0.0 0.3 0.0 12.0 0.9 21.8 a0 &64 

32 

PoP2 
1213R5 

5:42:10PM 0.0 0.4 0.0 &0 0.9 225 0.0 576 

5:4225 PM 0.0 0.3 0.0 11.0 0.9 23.3 QO 6.64 

5:42:40 PM 0.0 0.3 0.0 &0 0.9 23.3 0.0 6.72 

5:4256PM 0.0 0.3 0.0 9.0 0.9 23.8 0.0 6.7e 

5:43:10PM 0.0 0.4 0.0 13.0 1.0 24.3 0.0 8.84 

5:4325PM 0.0 0.4 0.0 9.0 1.0 24.3 0.0 5.78 

5:43:40 PM 0.0 0.3 0.0 11.0 1.0 24.8 QO 5.72 

5:43:66 PM 0.0 0.4 0.0 11.0 1.0 24.8 0.0 6.78 

5:44:10PM 0.0 0.3 0.0 8.0 1.0 25.8 QO 4.8 

5:44:25 PM 0.0 0.3 0.o 13.0 1.0 25.8 0.0 7.66 

5:44:40 PM 0.0 0.4 0.0 &0 1.0 25.1 0.0 4.8 

5:44:56PM 0.0 0.4 0.0 &0 1.0 215.3 0.0 6.72 

5:46:10PM 0.0 0.4 0.0 10.0 1.0 21L1 0.0 5.78 

5:4625PM 0.0 0.4 0.0 5.0 1.0 28.1 QO 4.8 

5:46:40 PM 0.0 0.4 0.0 11.0 1.0 25.6 0.0 7.68 

5:45:66PM 0.1 0.6 0.0 7.0 1.0 20.1 0.0 &7e 

5:48:10PM 0.1 0.6 0.0 7.0 1.0 20.1 QO 8.72 

5:4e'.26PM 0.0 0.4 0.0 11.0 1.0 25.8 0.0 6.72 

5:48:40 PM 0.0 0.4 0.0 9.0 1.0 25.8 0.0 4.8 

5:4e:66PM 0.0 a4 0.0 10.0 1.0 25.3 0.0 7.68 

5:47:10 PM 0.1 0.6 a0 110 1.0 25.0 0.0 5.76 

5:4725PM at 0.5 0.0 7.0 1.0 24.8 0.0 8.72 

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5:48:10 PM 0.1 a5 0.0 7.0 1.0 24.3 0.0 &64 

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5:49:10PM 0.1 0.5 0.0 9.0 1.0 24.3 0.0 8.72 

5:4926PM 0.0 0.4 0.0 7.0 1.0 24.8 0.0 8.64 

-5:49:40PM ai 0.5 0.0 11.0 1.0 26.0 0.0 7.68 

5:49:66PM 0.1 0.5 0.0 7.0 1.0 25.3 a0 6.72 

5:60:tOPM 0.1 0.8 0.0 &0 1.0 25.6 0.0 9.6 

5:6025PM a1 0.5 0.0 120 1.0 26.8 0.0 8.72 

5:50:40PM 0.1 0.6 0.0 9.0 1.0 25.8 0.0 7.86 

5:50:55PM 0.1 a5 0.0 130 1.0 25.8 0.0 7.88 

5:51:10 PM 0.1 0.5 0.0 9.0 1.0 25.8 0.0 6.76 

5:5126 PM 0.1 0.6 0.0 &0 1.0 2S.8 0.0 &64 

5:51:40 PM a1 0.5 0.0 13.0 1.0 24.6 0.0 5.7e 

5:61:55PM 0.1 a8 0.0 9.0 0.9 23.8 0.0 5.76 

5:5110PM 0.1 0.6 0.0 13.0 0.9 23.0 0.0 7.68 

5:6225PM 0.1 0.5 0.0 9.0 0.9 228 QO 4.8 

5:52:40PM 0.1 0.6 0.0 S.0 0.9 220 0.0 6.72 

5:6256PM 0.1 O.e 0.0 13.0 0.9 225 0.0 5.7e 

5:53:10PM 0.1 0.6 0.0 9.0 0.9 275 0.0 4.8 

6:5326 PM 0.1 0.5 0.0 110 a9 228 0.0 7.68 

5:63:40 PM 0.1 0.9 0.0 11.0 0.9 23.0 0.0 4.8 

5:53:55 PM 0.1 0.5 0.0 a0 0.9 228 0.0 8.72 

5:64:10 PM 0.1 0.6 0.0 120 0.9 23.3 0.0 6.72 

5:6425 PM 0.1 0.9 0.0 &0 0.9 23.6 0.0 4.8 

5:64:40PM 0.1 O.e 0.0 7.0 0.9 23.8 0.0 &84 

5:64:56PM ai 0.9 0.0 11.0 0.9 23.6 0.0 5.7e 

Stop RS Avarys 0.22 1203 23.63 6.78 

5:55:tOPM 0.1 0.5 0.0 &0 0.8 20L0 a0 6.72 

5:5525 PM 0.1 0.6 0.0 18.0 O.e 13.9 0.0 7.68 

5:56:40 PM 0.1 0.6 QO 6.0 1.1 28.3 0.0 7.88 

5:56:55PM 0.1 0.5 0.0 9.0 0.8 19.0 0.0 10.6e 

5:56:10PM 23 225 0.0 13.0 0.4 9.4 0.0 8.64 

5:5626PM 29 29.0 0.0 5.0 0.2 4.0 ao &84 

5:58:40 PM 3.2 324 0.0 10.0 0.2 3.8 0.0 11.52 

5:58:65PM 3.2 32z 0.0 a0 0.1 2e 0.0 9.6 

5:57:10 PM 3.2 323 0.0 ao 0.1 3.0 a0 11.52 

5:5725PM 3.2 323 0.0 11.0 0.1 3.5 0.0 9.e 

5:67:40 PM 0.2 1.6 0.0 ao 0.3 e.3 a0 9.e 

6:57:66PM 0.1 1.1 0.0 35.0 0.3 7.1 0.0 12.48 

5:58:10 PM 0.1 1.1 0.1 101.0 0.1 3.3 0.0 8.64 

5:6925PM 0.1 1.1 0.1 100.0 0.1 28 a0 1a69 

5:66:40 PM 0.1 1.0 0.1 107.0 0.1 28 0.0 10.6e 

5:58:56 PM 0.1 1.0 0.1 101.0 0.1 23 0.0 8.64 

5:59:10 PM 0.1 1.0 0.1 107.0 0.1 20 0.0 11.52 

5:6925PM 0.1 1.1 0.1 103.0 0.1 23 0.0 8.94 

5:59:40PM 0.1 1.1 0.0 320 0.2 at ao &dl 

5:69:66PM 0.1 1.1 0.0 &0 24 81.0 0.0 11.62 

e:00:10 PM 0.1 1.1 0.0 &0 3.9 91.1 0.0 9.9 

9:0025 PM 0.1 1.1 0.0 10.0 3.7 929 0.0 11.52 

9:00:40PM at 1.1 0.0 7.0 3.7 9ze a0 11.62 

8:00:55 PM 0.1 1.0 0.0 4.0 3.7 9ze 0.0 9.6 

e:01:10PM 0.1 1.1 0.0 10.0 3.7 9ze 0.0 1248 

B:o123PM 0.1 1.0 0.0 7.0 27 67.6 0.0 1a58 

6:01:40PM 0.1 1.1 0.0 10.0 1.6 38.6 0.0 11.52 

6:01:66PM 0.1 1.0 0.0 e.0 0.7 17.7 0.0 10.56 

e:02'10PM 0.1 1.1 0.0 a0 0.6 11.8 0.0 8.84 

9:0226 PM 0.1 1.0 0.0 7.0 0.1 3.0 0.0 8.04 

e:02:40PM 0.1 1.1 0.0 4.0 0.0 1.0 0.0 4.6 

e:0266PM 0.1 1.1 0.0 6.0 0.0 1.0 0.0 4.8 

e:03:10 PM 0.1 1.0 0.0 9.0 0.0 1.0 0.0 7.68 

8:0325 PM 0.1 1.0 0.0 ao 0.1 1.3 a0 4.8 

6:03:40 PM 0.1 1.0 0.0 10.0 0.1 1.3 0.0 7.e8 

6:03:56PM 0.1 1.0 0.0 &0 0.1 10 0.0 7.e8 

' e:04:10PIN 0.1 1.1 0.0 &0 0.1 25 0.0 a72 

6:0425PM 0.1 1.1 0.0 12o 0.0 1.0 at 101.7e 

e:04:40PM a1 1.0 0.0 7.0 0.1 1.3 0.2 17a64 

8:04:66PM 0.1 1.1 0.0 &0 0.0 0.8 0.2 189.12 

9:06:10 PM 0.1 1.0 0.0 &0 0.0 0.6 a2 194.88 

8:0525PM 0.1 1.1 0.0 7.0 0.0 0.3 0.2 224.64 

8:05:40PM 0.1 1.1 0.0 &0 0.0 0.6 0.2 22&48 

e:05:56PM 0.1 1.0 0.0 7.0 0.0 0.8 0.2 22a6e 

e:08:10PM 0.1 1.0 0.0 &0 0.0 0.6 0.2 227.52 

33 ~ ~ 
1213R6 

FlLE NAAIE: 1213i8 

LOGGINO S 1 SiARr LOGGING ® NIAIhtAW 18:07:14: 

LAS'T SAMPLE ® MMNpM{ 19:1629: 

ACTIVE CW1 tA 1B 2A 2B 

A1OOl.lE Tr Votaps Vafaps Vo[ps Vataps 

SAAPLE RA 15 ssc 16 sse 15 ssc 15 aeo 

WTS: Vals NOx, ppm Vots CO, ppn Vats VOC, pppn Vals S02, Mn 

12/1311996 8:07:14 PM 0.1 1.1 0.0 &0 0.3 3.0 QO 3&4 

8:0729 PM 0.1 1.1 a0 10.0 0.3 3.0 QO 31.68 

8:07:44 PM 0.1 1.1 0.0 11.0 0.2 21 0.0 288 

6:07:59PM Q7 1.1 0.0 4.0 0.2 22 0.0 464 

Start R8 

8:08:14 PM 0.1 1.3 0.0 120 0.e &4 0.0 11.52 

6:0829 PM 0.1 1.2 0.0 &0 1.0 10.3 0.0 13.41 

8:08:44 PM 0.1 1.2 QO 9.0 1.1 10.9 0.0 1248 

8:08:59PM a1 1.3 0.0 1&0 1.0 9.8 0.0 1Q32 

8:09:14 PM 0.1 12 0.0 10.0 1.2 11.5 0.0 13.44 

8:0929 PM 0.1 1.2 0.0 120 1.2 11.8 QO 15.39 

8:09:44PM 0.1 1.2 0.0 8.0 1.2 124 0.0 1&38 

8:09:59 PM Q7 1.3 0.0 d0 1.3 127 QO 13.44 

8:10:14 PM 0.1 1.3 QO 11.0 1.3 1z8 0.0 17.28 

8:1029 PM 0.1 1.2 0.0 &0 1.3 127 0.0 13.44 

8:10:44PM 0.1 1.2 0.o 8.0 1.3 127 0.0 14.4 

8:10:59PM Q1 1.2 0.0 13.0 1.3 127 QO 14.4 

8:11:14PM Q1 1.2 0.0 8.0 1.3 1z5 0.0 1248 

E:1129PM 0.1 1.2 ao 11.0 1.2 122 0.0 1&36 

6:11:44 PM 0.1 1.2 0.0 7.0 1.2 1z1 0.0 13.d 

6:11:59 PM 0.1 i.2 0.0 &0 1.2 1zo 0.0 1246 

6:12'14PM 0.1 1.2 0.0 120 1.2 1z1 QO 1344 

e:1229 PM 0.1 1.2 0.0 7.0 1.2 123 QO 10.59 

8:1244 PM 0.1 1.2 0.0 120 1.2 124 0.0 13.44 

8:12:59PM 0.1 1.2 0.0 9.0 1.3 127 0.0 10.56 

8:13:14 PM 0.1 1.3 0.0 11.0 1.3 128 0.0 9.e 

6:1329PM Q1 1.4 QO 9.0 1.2 11.9 0.0 1246 

6:13:44 PM 0.2 1.5 0.0 &0 1.3 129 0.0 9.6 

6:13:69PM 0.2 1.5 QO 1z0 1.3 13.0 U.0 10.56 

6:14:14 PM 0.2 1.6 QO &0 1.3 13.0 QO 10.56 

6:1429 PM 0.2 1.5 0.0 7.0 1.3 13.0 QO &64 

6:14:44 PM 01 1.6 0.0 120 1.3 13.0 0.0 11.52 

8:14:69 PM 0.1 1.4 QO &0 1.3 129 0.0 9.6 

8:16:14 PM 0.1 1.4 0.0 9.0 1.3 1z6 0.0 9.8 

6:1629PM Q1 1.3 0.0 4.0 1.3 13.2 0.0 10.58 

6:16:44PM 0.1 1.3 0.0 7.0 1.3 12e 0.0 &e4 

8:15:59 PM 0.1 1.3 0.0 12o 1.7 1ze 0.0 11.52 

6:1e:14PM Qt 1.3 0.0 7.0 1.3 126 0.0 A6 

6:1629 PM 0.1 1.3 0.0 13.0 1.3 128 0.0 10.56 

6:16:44 PM 0.1 1.3 0.0 &0 1.3 1ze 0.0 11.52 

6:1e:59PM Q7 1.3 0.0 9.0 1.3 126 0.0 9.9 

6:17:14 PM 0.1 1.3 0.0 11.0 1.3 128 0.0 11.52 

8:1729 PM 0.1 1.3 0.0 &0 1.3 127 0.0 10.58 

6:17:44 PM 0.1 1.3 0.0 14.0 1.3 127 0.0 9.6 

6:17:59PM 0.1 1.2 0.0 &0 1.3 127 0.0 1248 

8:18:14PM 0.1 1.3 0.0 11.0 1.3 127 ao 9.9 

8:1829PM 0.1 1.2 0.0 7.0 1.3 127 0.0 11.52 

8:18:44 PM 0.1 1.2 QO 7.0 1.2 tz2 0.0 10.59 

8:18:59 PM 0.1 1.2 0.0 10.0 1.8 17.9 0.0 9.6 

6:19:14PM 0.1 1.2 0.0 9.0 1.8 1&1 0.0 11.62. 

6:1929 PM 0.1 1.2 0.0 9.0 1.8 17.8 0.0 &64 

6:19:44PM Q7 1.3 0.0 4.0 1.8 17.9 0.0 10.56 

e:19:69PM 0.1 1.3 0.o e.0 1.a 17.6 0.0 &84 

820:14 PM 0.1 1.3 0.0 10.0 1.8 17.9 0.0 7.68 

82029 PM 0.1 1.2 0.0 &0 1.8 1&3 0.0 10.50 

620:44PM Q7 1.3 0.0 110 1.9 1&6 0.0 fl72 

820:59 PM 0.1 1.3 0.0 10.0 1.4 14.2 0.0 &64 

821:14 PM 0.1 1.3 0.0 8.0 1.3 13.0 0.0 &e4 

82129PM 0.1 13 0.0 120 1.2 123 0.0 &72 

621:44 PM 0.1 1.2 0.0 7.0 1.2 123 0.0 10.58 

821:59 PM 0.1 1.3 0.0 9.0 1.2 122 0.0 7.68 

8:=14PM 0.7 13 0.0 13.0 1.2 121 0.0 &64 

82229PM 0.1 1.3 0.0 7.0 1.2 120 0.0 9.e 

82244 PM 0.1 1.2 0.0 tzo 0.2 1.8 0.0 7.68 

632:59PM 0.1 1.4 0.0 9.0 0.2 1.8 0.0 10.5e 

623:14PM 0.2 1.6 0.0 9.0 0.3 ze a0 &64 

92329PM 0.2 1.e 0.0 14.0 0.3 26 0.0 7.68 

823:44 PM 0.2 1.6 0.0 &0 1.8 1&4 0.0 10.36 

623:69PM 0.2 1.6 0.0 &0 1.9 18.6 0.0 7A8 

924:14PM 0.2 1.6 0.0 13.0 1.9 1&5 0.0 9.e 

82429PM 0.2 1.7 0.0 &0 1.9 1&e 0.0 &81 

674:44 PM 0.2 1.7 0.0 13.0 1.9 1&6 0.0 7.68 

824:59 PM 0.2 1.7 0.0 14.0 1.9 1&8 0.0 1a56 

823:14 PM 0.2 1.6 0.0 11.0 1.9 1&S 0.0 &64 

82629PM 0.2 1.8 0.0 14.0 1.9 1&5 0.0 &64 

e'13:44 PM 0.2 1.6 0.0 11.0 1.9 1&s 0.0 9.e 

626:59 PM 0.2 1.8 0.0 120 1.9 18.6 0.0 7.66 

625:14 PM 0.2 1.9 0.0 15.0 1.9 1&e 0.0 9.e 

62629PM 0.2 1.9 0.0 10.0 1.9 1&7 0.0 &e4 

82E:44PM 0.2 1.8 0.0 9.0 1.9 1&7 0.0 7.6e 

e29:59PM 0.2 1.9 0.0 14.0 1.9 1&7 0.0 1a5e 

827:14 PM 0.2 1.9 Qo 10.0 1.9 18.e 0.0 7.66 

82729PM 0.2 1.9 0.0 120 1.9 1&S 0.0 &64 

827:44PM 0.2 1.9 0.0 120 1.9 1&S QO Q6 

827:59PM 0.2 21 0.0 &0 1.9 1&8 0.0 e.72 - 

828:14 PM 0.2 21 0.0 13.0 1.9 19.0 0.0 9.0 

eZ629 PM 0.2 21 0.0 10.0 1.9 19.1 0.0 7.68 

928:44PM 0.2 21 0.0 10.0 1.9 19.1 0.0 &72 

e28:39PM 0.2 22 0.0 14.0 1.9 19.1 0.0 10.5e 

629:14PM 0.2 zt 0.0 120 1.9 19.2 0.0 &72 

62929 PM 0.2 22 0.0 11.0 1.9 19.2 0.0 7.68 

929:41 PM 0.2 23 0.0 16.0 1.9 19.3 0.0 9.8 

34 

Pe 1 
1213Ra 

629:59 PM 0.2 23 0.0 11.0 1.9 19.3 0.0 8.72 

8:30:14PM 0.2 23 0.0 13.0 1.9 19.4 ao 10.58 

6:3029PM 0.2 23 0.0 10.0 1.9 19.4 0.0 &84 

6:30:44 PM 0.2 2.4 0.0 9.0 20 19.5 0.0 7.65 

6:30:59PM 0.2 23 0.0 11.0 20 19.5 0.0 10.58' 

8:31:14 PM 0.2 24 0.0 7.0 1.9 19.4 0.0 7.86 

6:3129 PM 0.2 24 0.0 &0 1.9 19.4 0.0 &64 

8:31:44PM 0.2 24 0.0 11.0 1.9 19.4 0.0 9.5 

8:31:59 PM 0.2 24 0.0 &0 1.9 19.3 0.0 8.72 

6:32:14 PM 0.2 24 0.0 &0 1.9 19.4 0.0 10.58 

8:3219 PM Q3 25 0.0 120 1.9 19.4 0.0 7.86 

8:32:44 PM 0.3 26 0.0 9.0 20 19.8 0.0 7.66 

6:3259PM 0.3 27 0.0 13.0 2o 19.8 0.0 10.66 

6:33:14PM 0.3 2a 0.0 9.0 20 20.0 0.0 7.68 

6:3329PM 0.3 27 0.0 1zo 2o 20.3 0.0 9.8 

6:33:44 PM 0.3 2S 0.0 9.0 21 20.6 0.0 &64 

8:33:59PM 0.3 2a 0.0 13.0 21 20.7 0.0 8.72 

8:34:14 PM 0.3 29 0.0 10.0 z1 20.6 0.0 9.8 

8:3429PM 0.3 29 0.0 9.0 21 206 0.0 &64 

8:34:44 PM 0.3 29 0.0 10.0 20 20.4 0.0 7.68 

6:34:69PM 0.3 2a 0.0 &0 2o 20.3 0.0 10.5B 

8:35:14 PM 0.3 3.0 0.0 11.0 21 20.5 0.0 &72 

8:3629PM 0.3 3.0 0.0 11.0 21 20.6 0.0 &64 

6:35:44 PM 0.3 3.1 0.0 SO 21 20.6 0.0 &64 

8:35:59PM (13 3.3 0.0 10.0 20 20.4 0.0 0.72 

6:3a:14PM 0.3 10 0.0 &0 20 20.1 0.0 9.6 

8:3829PM 0.3 3.3 QO 7.0 20 19.9 0.0 7.66 

8:38:44PM 0.3 3.7 0.0 11.0 20 148 0.0 7.88 

8:36:59PM 0.3 3.3 0.0 &0 1.9 19.4 0.0 9.8 

8:37:14 PM 0.3 3.3 0.0 9.0 1.9 19.4 QO 6.72 

6:3729PM 0.3 3.2 0.0 120 zo 19.8 a0 9.9 

6:37:44PM 0.3 32 0.0 &0 zo 19.6 0.0 &84 

6:37:59PM 0.3 32 0.0 14.0 20 19.9 0.0 &72 

8:38:14 PM 0.3 12 0.0 10.0 z0 19.9 0.0 1QSa 

8:3829 PM 0.3 32 0.0 8.0 2o 19.8 0.0 7.08 

8:38:44PM 0.3 3.3 0.0 11.0 20 19.a 0.0 &64 

6:38:59PM 0.3 3.2 0.0 11.0 zo 19.9 0.0 9.8 

8:39:14PM 0.3 3.2 O.o &0 2o 19.9 0.0 7.88 

8:3929PM 0.3 3.3 0.0 11.0 2o 1&9 0.0 10.56 

6:39:44PM 0.3 3.2 0.0 4.0 20 19.9 0.0 &BS 

8:39:59 PM 0.3 12 a.0 &0 20 19.8 0.0 7.69 

6:40:14 PM 0.3 3.2 0.0 11.0 zo 19.9 0.0 10.66 

8:4019PM 0.3 3.2 0.0 9.0 20 19.6 QO 7.58 

8:40:44PM 0.3 13 0.0 14.0 20 1&8 0.0 &54 

6:40:59PM 0.3 3.3 0.0 120 20 1B.a 0.0 9.8 

8:41:14 PM 0.3 3.4 0.0 9.0 20 19.6 0.0 7.88 

6:4129PM 0.3 3.4 0.0 130 1.9 19.4 0.0 10.68 

6:41:44PM 0.3 14 0.0 9.0 1.9 19.1 0.0 &84 

6:41:59 PM 0.1 1.4 0.0 7.0 21 20.S 0.0 &64 

6:42•14PM 0.1 1.3 0.0 12o 20 201 0.0 19.2 

8:4229PM 0.1 1.3 0.0 7.0 20 20.7 0.0 10.58 

8:42444 PM 0.1 1.3 0.0 &0 20 203 0.0 11.52 

8:42:59 PM 0.1 1.3 0.0 11.0 z t 20.3 0.0 11.62 

8:43:14PM 0.1 1.2 0.0 7.0 21 20.7 0.0 9.8 

6:4329PM 0.1 1.3 0.0 120 21 21.0 0.0 11.52 

8:43:44 PM 0.1 1.2 0.0 10.0 21 21.3 QO 9.6 

8:43:69 PM 0.1 1.3 0.0 6.0 22 21.6 0.0 9.8 

6:44:14PM Q1 1.3 0.0 11.0 22 224 0.0 11.52 

6:4429PM 0.1 1.2 0.0 9.0 23 2z9 0.0 9.8 

6:44:41 PM 0.1 1.3 0.0 10 23 23.4 00 11.52 

8:44:59 PM 0.1 1.3 &o 13.0 24 23.8 0.0 105a 

a:45:14PM 0.1 12 0.0 &0 24 23.6 0.0 9.8 

6:4529PM 0.1 1.3 0.0 &0 23 23.0 0.0 1248 

8:46:44PM 0.1 1.2 0.0 13.0 21 2Q7 &0 9.8 

8:46:59 PM 0.1 1.3 0.0 9.0 21 20a 0.0 10.66 

8:4a:14PM 0.1 1.3 0.0 &0 20 20.4 0.0 11.52 

6:4629 PM 0.1 1.3 0.0 13.0 20 20.2 0.0 9.8 

6:48:444 PM 0.1 1.3 0.0 &0 20 20.1 0.0 1248 

8:4a:S9PM 0.1 1.3 0.0 10.0 2o 20.1 0.0 10.66 

8:47:14PM 0.1 12 0.0 9.0 20 202 QO 10.66 

8:4729 PM 0.1 1.3 0.0 7.0 20 201 0.0 11.62 

8:47:44PM 0.1 13 0.0 120 20 20.1 QO &84 

8:47:59 PM 0.1 12 0.0 7.0 20 19.9 0.0 11.52 

8:48:14PM 0.1 1.3 0.0 10.0 20 19.9 0.0 9.8 

8:4829 PM 0.1 1.3 &o S.0 20 19.9 0.0 9.8 

6:48:44 PM 0.1 1.2 0.0 120 20 20.1 0.0 10.56 

6:48:59PM a1 1.2 0.0 8.0 2o 20.3 0.0 &64 

8:49:14PM , 0.1 1.2 a0 &0 2o 204 0.0 10.58 

8:4929PM 0.1 1.3 0.0 14.0 z1 20.5 0.0 &84 

8:49:44PM 0.1 1.3 0.0 7.0 21 20.6 0.0 7.88 

6:49:59PM 01 1.3 0.0 14.0 21 20.6 0.0 9.6 

8:50:14 PM 0.1 1.2 0.0 130 20 2a4 0.0 5.72 

6:5029PM a1 1Z 0.0 7.0 20 201 a0 9.6 

8:50:44 PM 41 1.2 0.0 13.0 z0 20.1 0.0 &a4 

8:60:59PM 0.1 1.3 0.0 7.0 2o 20.0 0.0 7.68 

8:51:14 PM 0.1 1.2 0.0 10.0 20 20.2 0.0 10.58 

6:6129 PM 0.1 1.3 0.0 13.0 20 20.3 a0 7.68 

8:51:44 PM 0.1 1.3 0.0 &0 2o 20.3 Oo &64 

6:61:69PM &1 1.3 0.0 120 2o 20.2 &0 9.8 

6:52'14 PM 0.1 1.3 0.0 &0 20 20.2 0.0 7.88 

8:5229PM a1 1.3 0.0 &0 20 2a0 &0 10.58 

6:52:44 PM 0.1 1.2 0.0 11.0 20 20.1 0.0 &64 

8:62:39 PM 0.1 1.3 0.0 7.0 20 20.2 0.0 9.6 

8:53:14 PM 0.1 1.2 0.0 10.0 20 20.3 0.0 10.56 

a:5329PM a1 1.2 0.0 12a 21 20.8 0.0 &64 

8:53:44 PM 0.1 1.3 0.0 &0 21 20.8 a0 10.58 

a:53:59 PM 0.1 1.2 a0 13.0 21 206 0.0 9.6 

6:64:14 PM 0.1 1.2 0.0 &0 21 20.5 0.0 &a4 

0:6429 PM 0.1 1.3 0.0 &0 20 20.4 0.0 11.52 

6:64:44 PAA 0.1 1.2 0.0 13.0 20 20.3 0.0 &54 

8:64:39PM 0.1 1.3 0.0 10.0 20 20.1 0.0 10.6e 

8:66:14 PM 0.1 1.3 0.o 7.0 20 19.9 0.0 9.8 

6:5629PM a1 1.2 0.0 11.0 2o 19.6 0.0 7.08 

35 

P~ 2 9z 
1213R8 

8:55:44 PM a1 1.3 0.0 7.0 z0 19.8 0.0 10.58 

8:55:59 PM 0.1 1.2 0.0 120 2o 19.7 QO 7.68 

8:58:14 PM 0.1 1.2 0.0 &0 z0 19.5 0.0 7.68 

8:5829 PM 0.1 1.3 0.0 &0 z0 19.5 0.0 9.8 

8:58:44 PM 0.1 1.3 0.0 10.0 2o 19.8 0.0 5.78 

8:58:59 PM 0.1 1.2 0.0 3.0 2o 19.8 ao &84 

8:57:14PM 0.1 1.3 0.0 7.0 20 19.8 a0 &72 

8:5729PM 0.1 1.2 0.0 10.0 2o 19.9 a0 a72 

8:57:44PM at 1.2 0.0 &o zo 19.9 a0 &84 

8:57:59PM a1 1.2 0.0 9.0 20 19.9 0.0 R72 

8:58:14PM 0.1 1.2 0.0 13.0 20 19.9 0.0 &84 

8:5829PM a1 1.2 0.0 &o zo 20.0 0.0 7.88 

8:58:44 PM 0.1 1.3 0.0 13.0 zo 20.0 0.0 8.72 

8:58:59PM 0.1 1.4 0.0 14.0 2o 20.0 ao 9.8 

6:69:14 PM 0.2 1.5 0.0 9.0 zo 19.9 a0 &72 

8:5929 PM 0.2 1.5 0.0 14.0 20 19.9 0.0 9.8 

8:59:44PM 0-2 1.8 0.0 &0 2o 2a1 0.0 &84 

8:59:59PM 0.2 1.5 0.0 7.0 20 20.1 QO 6.72 

7:00:14PM 0.2 1.6 0.0 120 20 2a3 0.0 10.58 

7:0029 PM 0.2 1.8 0.0 &0 20 20.3 0.0 7.68 

7:00:44 PM a2 1.8 a0 11.0 z0 2a4 0.0 &84 

7:00:59 PM a2 1.7 0.0 &0 zo 20.3 0.0 9.8 

7:01:14 PM 0.2 1.8 0.0 8.0 20 20.3 0.0 7.88 

7:0129 PM 0.2 1.8 0.0 9.0 zo 20.0 a0 10.58 

7:01:44PM 0.2 1.8 0.0 8.0 zo 20.1 0.0 &64 

7:01:59 PM 0.2 1.5 0.0 7.0 zo 19.9 0.0 9.8 

7:02:14 PM 0.2 1.5 0.0 12o 20 20.0 0.0 1a58 

7:0229PM 0.1 1.4 0.0 &0 20 19.9 0.0 7.88 

7:02:44PM 0.1 1.4 0.0 13.0 z0 19.9 0.0 11.62 

7:02:59PM 0.1 1.4 0.0 120 z0 19.9 0.0 &84 

7:03:14 PM 0.1 1.3 0.0 &0 2o 19.9 0.0 172 

7:0329 PM 0.1 1.3 0.0 13.0 zo 19.9 a0 9.8 

7:03:44 PM 0.1 1.3 0.0 8.0 2o 19.8 a0 &72 

7:03:59 PM 0.1 1.2 0.0 9.0 20 19.7 0.0 &64 

7:04:14PM 0.1 1.2 0.0 13.0 z0 19.8 0.0 7.68 

7:0429PM 0.1 1.3 0.0 -z0 1.9 19.4 0.0 6.78 

7:04:41 PM 0.1 1.3 0.0 &0 1.9 1&9 0.0 9.8 

7:04:59 PM 0.1 1.4 0.0 10.0 1.2 121 0.0 &72 

STop R8 AvwEW 1.71 9.65 17.86 9.56 

7:06:14PM 0.1 1.1 0.0 &0 0.2 1.7 0.0 &84 

7:0529PM ai 1.1 0.0 5.0 a2 1.5 a0 10.58 

7:05:44 PM 0.1 1.1 0.0 11.0 0.1 1.3 0.0 9.8 

7:05:59 PM 0.1 1.1 0.0 8.0 0.1 1.2 0.0 13.44 

7:08:14 PM 0.1 1.1 0.0 11.0 0.2 22 0.0 10.58 

7:0629PM 0.1 1.1 0.0 8.0 0.2 22 0.0 1248 

7:08:41 PM 0.1 1.1 0.0 12o 0.2 21 0.0 14.4 

7:08:59 PM 0.1 1.1 0.0 9.0 0.2 21 0.0 11.52 

7:07:14 PM 9.3 33.1 0.0 6.0 0.o 0.0 0.0 14.4 

7:0729PM 3.3 33.4 0.0 11.0 0.0 0.0 0.0 1248 

7:07:44 PM 3.3 314 0.0 7.0 0.0 0.0 0.0 1248 

7:07:59PM 34 33.5 0.0 &0 0.0 0.0 0.0 1538 

7:08:14 PM 3.3 33.4 0.0 120 0.0 0.0 a0 1248 

7:0829PM 25 2&1 0.0 5.0 QO 0.0 QO 14.4 

7:08:44PM a1 1.3 0.0 10.0 a2 1.8 ao 14.4 

7:08:59PM a1 1.2 ao 11.0 7.2 72.4 ao 15.38 

7:09:14PM Qi 1.2 0.0 8.0 &B 8&1 0.0 19.2 

7:0929PM 0.1 1.2 0.0 7.0 9.0 89.6 0.0 1&38 

7:09:44 PM 0.1 1.1 0.0 11.0 9.0 9a2 0.0 1&32 

7:09:59 PM 0.1 1.2 0.0 5.0 7.4 74.3 a0 1726 

7:10:14 PM 0.1 1.1 0.0 7.0 4.7 47.4 0.0 14.4 

7:10?9PM at 1.2 QO 8.0 0.2 1.8 QO 1&32 

7:10:44 PM 0.1 1.1 0.0 5.0 0.0 0.2 0.0 1248 

7:10:59 PM 0.1 1.1 a0 11.0 0.0 0.0 0.0 1248 

7:11:14 PM 0.1 1.2 0.0 4.0 0.0 0.0 0.0 14.4 

7'.1129 PM 0.2 1.5 a0 10 0.0 ao ao 11.52 

7:11:44PM 0.2 1.6 0.0 10.0 0.0 QO 0.0 14.4 

7:11:59PM 0.2 1.5 0.0 8.0 0.0 0.0 0.0 1248 

7:12'14PM 0.2 1.6 0.0 3.0 0.0 0.o 0.0 11.52 

7:1229 PM 0.1 1.3 0.0 11.0 0.0 0.0 0.0 3.84 

7:12:44PM 0.1 1.3 0.0 8.0 0.0 0.0 0.0 Q96 

7:12:59PM a1 1.2 0.1 57.0 0.0 0.0 QO 1.92 

7:13:14 PM 0.1 1.2 0.1 9&0 0.0 0.0 0.0 1.92 

7:1329PM 0.1 1.2 0.1 97.0 0.0 0.0 - ao -0Ae 

7:13:44 PM a1 1.2 0.1 103.0 0.0 Qo 0.0 4.8 

7:17:59PM a1 1.1 0.1 101.0 0.0 0.0 QO a88 

7:14:14PM 0.1 1.2 at 7&0 QO 0.0 0.0 266 

7:1429PM at 1.3 ao &0 0.0 0.0 0.1 89.12 

7:14:44 PM 0.1 1.2 (XO 0.0 0.0 -0.1 0.2 20926 

7:14:59PM a1 1.1 0.0 7.0 0.0 4).1 0.2 2Z7.62 

7:15:14PM a1 1.2 a0 3.0 0.0 -0.1 0.2 22&8 

7:1529 PM 0.1 1.2 0.0 &0 0.0 Qt 0.2 227.52 

36 

Pup3 l7 
APPENDIX C 

~~r 
PARTICULATE ANALYTICAL DATA FORM 

Company: Athens Bdck 

Date: 12/13/95 

Location: Kiln Ex PW 

Run I Run 2 Run 3 

Density (Pa) .:::..:::::.:.:.d .. 

. . . ....... . . .......... 

0: 1851 ~ Blank Concentrabon (Ca) 1. 05E 6.;i 

Rinse Volume (Vaw) 7- 777:7: :200., :125: 

Residue in Rinse (Wa) = Ca*Vaw*Pa 0.0011 0.0007 0.0010 

Date of Weighing 

Gross Weight 106.147: 7. :::4:06.4984. 

.... ........ 

Date of Weighing 

Gross Weight 10&71.47. ...406.14985s: 

Average Gross Weight 111.2209 106.7147 106.4985 

Less Blank Residue (Wa) 77.7o. 0 000 1 7 

Tare Weight 06.706 2- 

Weight of Particulate in Rinse (grams) 0.0195 0.0078 0.0171 

.. 

Date of Weighing 

........ .. ... . .......... 2j. 1.21 4M: 

Gross Filter Weight OA6W:: -0.4597 

Date of Weighing 1 V, 1 41N.: 12/14195. 

Gross Filter Weight GqQ641 : 0.4599 

Average Gross Weight 0.4667 0.4263 0.4598 

Filter Tare Weight A1.08. 

Weight of Particulate on Filter (grams) 0.0559 0.0162 0.0447 

Total Weight of Parficulate (mg) 75.3 24.0 61.8 

ACETONE BLANK ANALYTICAL DATA FORM 

Blank Volume (Va) 

Date of Weighing 12/15/95: 

Gross Weight -.114.71122. 

Date of Weighing 

. ...... ... 

Gross Weight 1

.

44.711 89:. 

Average Gross Weight :4.71905 

Tare Weight 2 114.7185r: 

Weight of Blank (Ma) 0.00055 

Ca= Ma/(Va*Pa) = mg/g 7.005E-06 

~

Note: In no case should a blank residue greater than 0.01 mg/g or 0.001 % of the blank 

weight be subtracted from the sample weight. 

37 
PARTICULATE ANALYTICAL DATA FORM 

Company: Athens Bdck 

Date: 12/13/95 

Location: Kiln Ex PW 

Run 4 

Density (Pa) .::. :-.. 6 .7 86t.. 

Blank Concentrabon (Ca) 

Rinse Volume (Vaw) j 

75.1 

Residue in Rinse (Wa) = Ca*Vaw*Pa 0.0010 

Date of Weighing 

Gross Weight 

Date of Weighing 

Gross Weight QT0428.1 

Average Gross Weight 107.0429 

Less Blank Residue (Wa) 7. 770-oa.1-0; 

Tare Weight 

Weight of Parficulate in Rinse (grams) 0.0325 

Date of Weighing 

Gross Filter Weight 

Date of Weighing 1211`4196.: 

Gross Filter Weight 0.4787. 

Average Gross Weight 0.4786 

Filter Tare Weight 

Weight of Parficulate on Filter (grams) 0.0661 

Total Weight of Particulate (mg) 98.5 

ACETONE BLANK ANALYTICAL DATA FORM 

Blank Volume (Va) 

... . ...... ::: ...... 40 

Date of Weighing 12115/95. 

Gross Weight 1.14.7192.. 

Date of Weighing 1V1:5/0 

Gross Weight 

Average Gross Weight 114.71905 

Tare Weight 1: 4.71851. 

Weight of Blank (Ma) 0.00055 

Ca= Ma/(Va*Pa) = mg/g 7.005E-06 

Note: In no case should a blank residue greater than 0.01 mg/g or 0.001 % of the blank 

weight be subtracted from the sample weight. 

38 /G/'P 
PARTICULATE ANALYTICAL DATA FORM 

Company: Athens Brick 

Date: 12/13/95 

Location: Klln Ex Imps 1&2 

Run 1 Run 2 Run 3 Run 4 

Total Volume 

Aliquot Volume, mis 100.0000 100.0000 100.0000 100.0000 

Date of Weighing 12l1519~ [2f1.5/95; 12M5195' 12115195 

Gross Weight 'i.03:3232! 106:0655:: "::i 1i;4;51:59; iOgi3257 

Date of Weighing 1~l15L95 t2115195: 1?115195: 12/t5/95 

Gross Weight 103.32361: 1`06.0658.; 11:4.5161 109:3258 

Average Gross Weight 103.3234 106.0657 114.5160 109.3258 

Tare Weight i0.~ .3207 1'Q6.Q636: 'i:1:4.;515t~ t05:3235: 

Weight of Particulate in Rinse, mg 2.7000 2.0500 1.0000 2.2500 

Adjustment for Aliquot=RV/Aliquot 3 3 4 3 

Total Particulate, mg 8.10 6.15 4.00 6.75 

39 lO/ 
100.5219 

: 0:0006: 

1 Q0:51'it~ ; 

; 

........ ': 

72f1. 195. 

0:4194.' 

0.4195 

0 4133 

n nn--.l 

,G 7 

PARTICULATE ANALYTICAL DATA FORM 

Company: Athens Brick 

Date: 12/13/95 

Location: Dryer Ex PW 

Run 1 

Density (Pa) Q;:7851::: 

Blank Concentration (Ca) 7 aU5E::0~ 

Rinse Volume N aw ) [: 00: 

Residue in Rinse (Wa) = Ca*Vaw*Pa 0.0006 

: :12f1:5I95;: 

.......... ... 

9 

100:52~ 9i': 

Date of Weighing 

Gross Weight 

Date of Weighing 

Gross Weight 

Run 2 

6:18M 

;: 7:OQSE-06; 

1`00:: 

0.0006 

' '[=2f15l9S 

101:::98'18:: 

:''..... . 

101 9616': 

Run 3 

Q:78Si'; 

'7:aO5E-06: 

—. :.---- ': s0 

A /1A/1. 

1:2/15/95: 

1:05:12544 ; 

105:1253: 

Average Gross Weight 

Less Blank Residue (V11a) 

Tare Weight 

Weight of Particulate in Rinse (grams) 

Date of Weighing 

Gross Filter Weight 

Date of Weighing 

Gross Filter Weight 

Average Gross Weight 

Filter Tare Weight 

Weight of ParGculate on Filter (grams) 

Total Weight of Particulate (mg) 

101.9817 105.1254 

:.0:0006. O::aOa4; 

: 'C:01:9.7C4 1:05~1 'I'89; 

0.0048 

:;13:4231~ 0:4:1::63? 

. 17J14~g5:; I0't4/9S:: 

0:424 

0.4240 0.4164 

777T4jW 14C: 

0.0091 0.0017 

4 7 n 7 0 

ACETONE BLANK ANALYTICAL DATA FORM 

Blank Volume (Va) 

. .. 

Date of Weighing l?11:5L95`; 

Gross Weight 114:7492 

Date of Weighing 12f1:S{S5: 

Gross Weight 

Average Gross Weight 114.71905 

Tare Weight 11;4:T1':85 

Weight of Blank (Ma) 0.00055 

Ca= Ma/(Va*Pa) = mg/g 7.005E-06 

Note: ln no case should a blank residue greater than 0.01 mg/g or 0.001 % of the blank 

weight be subtracted from the sample weight. 

40 /~ Z 
PARTICULATE ANALYTICAL DATA F®RM 

Company: Athens Brick 

Date: 12/13/95 

Location: Dryer Ex Imps 1&2 

Run 1 

Rinse Volume 

Aliquot Volume, mis 

Date of Weighing 

Gross Weight 

Date of Weighing 

Gross Weight 

Average Gross Weight 

Tare Weight 

Weight of Par6culate in Rinse, mg 

Adjustment for Aliquot=RV/Aliquot 

Total Pardculate, mg 

Run 2 Run 3 

100.0000 

96.a 34a 

12f15~95r: 

96.1334':' 

96.1341 _ . .. .......... 

L A /1f%A 

J 

15.3 

100.0000 

`1711 Sla5 

105:9626 

!?Jibl~ 

1:05.96:1:.3 

105.9620 

105:9609 

1.0500 

3 

3.15 

100.0000 

. 12/'j5195 

1:09.093:: 

1.09.0922:: 

109.0926 

1 Q9':Q&7S: 

G , /1!~ !1 . 

J 

15.3 

41 /02 
Sheetl 

Summary of Fluoride and Chloride Analysis 

Plant: Athens Brick, Athens, TX 

Date: 12/13/95 

Kiln Exhaust 

R# Volume Dilution FI, ug/ml HF, mg CI, ug/ml HCI, mg 

1 300 10 58.98 186.3178 58.94 181.771 

1 300 100 8.15 257.4585 1.55 47.802 

3 400 10 38.68 162.9202 10.79 44.36848 

4 300 10 48.04 151.7584 18.33 56.52972 

Dryer Exhaust 

1 300 1 23.87 7.540533 4.68 1.443312 

2 300 1 26.04 8.226036 5.57 1.717788 

3 3001 1 6.07 1.917513 1.01 0.311484 

42 

Page 1 /a ~~ 
Component Ezternal Units 

(unknown) N/A 

(unknown) N/A 

F- 2.00 ug/,1 

(unknown) N/A 

Cl- 3.00 ug/al 

Br- 1.29 ug/ 

NO3 9.62 ug/al 

(unknown) N/A 

(unknown) N/A 

1 • ~_ 

~— 

2 4' ~ 

3 ~ 

5 

4 

5 ~ . 

6 

1 

8 : 

Description = Channel 1 

Conditions : 2.00 Fluoride std 

: 3.00 Chloride std 

Date : 12/15/1995 

Time = 11=47=58 

—51.200mV 512.00OmV 

0.416 2.150 41.80 

0.125 3.166 45.30 

1.116 39.609 282.61 M 

1.358 1.132 10.16 M 

1.116 49.283 536.05 M 

2.991 5.340 99.59 M 

3.375 35.013 356.60 M 

4.475 0.469 13.35 M 

5.050 2.350 55.34 M 

Rete ntion Height Area 

91-- • 

0 

43 /~~ 
Description : Channel 1 

Conditions = 10.0 Fluoride std 

: 15.0 Chloride std 

Date : 12/15/1995 

Time = 12=01:23 

–51.200mV 512.00OmV 

Component 

(unknown) 

FC1- 

BrNO3 

(unknown) 

(unknown) 

PO4- 

External Units 

N/A 

10.00 ug/al 

15.00 ug/al 

0.26 ug/ 3 4 : 

41.07 ug/o1 ~ 

4 

 i. 

N/A '? 

5 — 

N/A 

0.55 ug/sl 

6 

7— : 

ntion Height Area 

0.533 2.690 83.15 

1.116 132.713 122.75 M 

1.683 146.185 2473.12 M 

3.016 1.530 19.65 M 

3.300 174.343 1898.69 M 

4.175 11.829 471.29 N 

5.316 1.589 17.66 M 

5.691 0.977 11.54 M 

1 

1 != 

44 ~0 ~ 
Description : Channel 1 

Conditions = 20.0 Fluoride std 

: 30.0 Chloride std 

Date : 12/15/1995 

Time : 12:13:38 

–51.200mV 

Component Ezternal Units 

(unknown) N/A 

(unknown) N/A 

F- 20.00 ug/ o1 

C1- 30.00 ug/ A 

512.00OmV 

Retention Height Area 

0.000 48.900 951.05 

0.891 9.366 60.65 

1.141 243.032 1483.06 

1.691 209.159 3458.73 

Br- 2.03 ug/ 

NO3 91.92 ug/ al 

(unknown) N/A 

(unknown ) N/A 

~ ~ 

~ :• 

1 ~ 

~ 

-' 1 

1 — 

-- 

~ 

3 

4 ;i 

5 

I• 

6 ; 

1 

8 

9 

10 

11 

2.841 7366 156.14 

3.383 316.818 4583.23 

4.225 11.329 296.63 

4.650 0.160 45.00 

45 

/~ ~ 
Calibration file = F.CAL 

AMOUNT INJECTED 

AREA 0.000 20.000 

0.000 

1 

-rA 

K 

4 

1483 .060 

Avg slope of curve= 90.78 

Y-axis intercept= 0.00 

Coeff of lin regr = 0.64 

No. Area Amount CF 

0: 0.000 0.000 0.000 

1= 282.610 2.000 141.305 

2= 722.750 10.000 72.275 

3= 1483.060 20.000 74.153 

46 

~~~ 
Calibration file = CL.CAL 

AMOUNT INJECTED 

AREA 0.000 30.000 

0.000 

1 

2 

3 

4 

3458.730 

Avg slope of curve: 135.27 

Y-axis intercept= 0.00 

Coeff of 1 i n regr : 0.76 

No. Area Amount CF 

0: 0.000 0.000 0.000 

1: 536.050 3.000 178.683 

2= 2473.120 15.000 164.875 

3: 3458.730 30.000 115.291 

47 

IG ~ 
Description : Channel 1 

Conditions : Athens Brick 

: 12/13/95 

= Kiln Ex Imps 1&2 

= Run #1 

: 1/10 dilution 300 ml 

Date = 12/15/1995 

Time = 13:56:04 

Coaponent 

(unknown) 

-51.200mV 

External Units 

N/A 

512.00OmV 

Retention Height Area 

316.11 

1 : •ti •''~ 

'~- 

2 = _ 

3 

1 1 ~ 

4 

5 ~ 

6 

1 

8 ~ 

9 

10 

11 

(unknown) N/A 

F- 58.98 ug/a 

C1- 58.94 ug/a 

NO3 2.02 ug/i 

Br- 0.51 ug/® 

0.000 11.900 

0.808 13.082 132.67 

1.183 612.299 4446.88 

1.775 195.145 5360.53 

3.115 5.369 74.99 

3.491 2.637 39.05 

48 • 

// L, 
Description = Channel 1 

Conditions : Athens Brick 

= 12/13/95 

= Kiln Ex Imps 1&2 

= Run #1 

: 1/100 dilution 300 ml 

Date : 12/15/1995 

Time : 14:10:08 

—51.200mV 512.00OmV 

Component Ezternal Units Retention Height Area 

(unknown) N/A 0.666 0.883 100.19 

F- 8.15 ug/sl 

lr; 

1.133 89.284 621.22 M 

C1- 1.55 ug/sl 1.116 30.133 277.81 M 

1 

1 

49 
Description : Channel 1 

Conditions : Athens Brick 

= 12/13/95 

= Kiln Ex Imps 1&2 

= Run #2 

= 1/10 dilution 300 ml 

Date = 12/15/1995 

Time = 14:18=37 

(unknown) N/A 

F- 17.63 ug/ 

C1- 7.45 ug/ 

—51.200mV 

sl 

~ 

®11 ,r-- 

2 

3 (: 

4 

5 

6 

1 

8 ~ 

9 

10 

11 

512.00OmV 

Retention Height 

0.125 0.000 

1.141 201.992 

1.125 51.941 

Area 

42.83 

1302.19 M 

1254.41 M 

Coeponent Ezternal Units 

50 )12-, 
Description : Channel 1 

Conditions = Athens Brick 

: 12/13/95 

: Kiln Ex Imps 1&2 

= Run #3 

: 1/10 dilution 400 ml 

Date : 12/15/1995 

Time = 14:57:17 

—51.200mV 512.00OmV 

CoAponent External Units _ R etention Height Area 

(unknown) N/A 0.758 12.204 156.75 

F- 38.68 ug/al 1.158 462.260 2903.15 M 

C1- 10.79 ug/sl 1.133 101.197 1794.15 M 

1 

51 

11-3 
Description = Channel 1 

Conditions = Athens Brick 

= 12/13/95 

= Kiln Ex Imps 1&2 

= Run #4 

= 1/10 dilution 300 ml 

Date = 12/15/1995 

Time = 15=11=17 

—51.200mV 512.00OmV 

Coaponent EXternal Unit 

(unknown) N/A 

F- 48.04 ug/A 

Cl- 18.33 ug/u 

s M R 

1 1 

2 

3 

4 

6 

1 

8 

9 

10 • 

11 ~ 

etention Height Area 

0.600 0.600 108.32 

1.166 549.983 3614.74 M 

1.133 111.432 2692.00 M 

" 52 

~l Y 
Description : Channel 1 

Conditions : Athens Brick 

= 12/13/95 

: Dryer Ex Imps 1&2 

= Run #1 

= 300 ml 

Date = 12/15/1995 

Time = 15:15:26 

—51.200mV 512.00OmV 

Co®ponent Ezternal Units tention Height Area 

(unknoan) N/A 0.625 13.642 395.81 

F- 23.87 ug/el 1.166 279.910 1177.59 M 

C1- 4.68 ug/a1 1.775 63.210 801.40 M 

9 

10 

11 

53 ~~~ 
Description = Channel 1 

Conditions : Athens Brick 

= 12/13/95 

= Dryer Ex Zmps 1&2 

= Ru n #2 

= 300 ml 

Date = 12/15/1995 

Time = 15:22=41 

–51.200mV 

External Units 

512.00OmV 

Co®ponent 

(unknown) 

FC1- 

N04- 

N/A 

1 – • 

26.04 ug/i1 — 

5.51 ug/ml ~ - = 

2 . ; . 9• 

3 

0.90 ug/ 4 

ention Height Area 

0.175 13.508 157.24 

1.166 313.369 1942.58 M 

1.766 64.308 950.48 M 

3.908 0.045 15.63 M 

1 

8 

9 

10 

11 ~ 

54. 

jI 

 / 
(unknown) N/A 

el 

1 ~ 

~ l 

 •T~'—.. 

2 

3 

4 

5 

6 

1 

8 

9 

10 

11 •— 

(unknown) N/A 

(unknown) 

N/A1 ug/ 

C1- 1.01 ug/ 

0.166 1.610 22.86 

1.133 69.100 506.63 M 

1.483 5.078 108.55 M 

1.100 24.918 181.05 M 

2.825 2.113 58.12 M 

Description = Channel 1 Conditions = Athens Brick 

= 12/13/95 

: Dryer Ex Imps 1&2 

= Run #3 

= 300 ml 

Date = 12/15/1995 

Time : 15:31:11 

–51.200mV 512.00OmV 

Component External Units Retentien Heiaht Area 

55 

117 
Description = Channel 1 

Conditions : Athens Brick 

= 12/13/95 

: H20 blank 

Date : 12/15/1995 

Time = 16=18:30 

Conponent 

~

unknown 

unknown 

unknown ~ 

F - 

ClEzternal Units 

N/A 

N/A 

N/A 

0.98 ug/nl 

0.34 ug/o1 

-51.200mV 

~ 

- ;- 

:i 

512.00OmV 

Retention Height 

0.125 3.365 

0.433 11.416 

0.141 18.965 

1.150 9.560 

1.691 5.100 

Area 

56.48 

285.35 

130.16 

138.30 M 

60.80 M 

(unknown) N/A 2.650 3.926 115.42 M 

(unknown) N/A 6.625 3.516 102.90 M 

1 

56 /l~ 
APPENDIX D 

11,5~ 
PARTiCiJLATE F3ELD DATA 

.-o 

PLANT : IvAcwS og/'JC/C Y 

DATE : 12 43- j S 

REPETITION:t 

LOCATION: 44eiR i/.74 

OPERATOR : aB~gi ~3 

STACIC #:l{Zq eX 

SAMPLE BOX '1r: 

METER BOX #:8 

AMB IENT TEMPERATURE : 70 ° 

BAROMETRI C PRESSIIRE ;;LQ- 6 Z' 

ASSUMED P40ISTQRE: S°(o 

PROBE LENGHTV '4pEX-66 

NOZZLE DIAMETER••2`~ g/• ~ y ~~•z `~~ C• ~~ )~J C , oO~ 33 YSS~ 

STACR D IAI~TER :~. S w X Z 5 L 

METER H 

C FACTOR: ~ y 

METER CO-EFFICIENT :/. 0a63 o 3 

FILTER TARE : I t//d 

PRE-TEST LEAK CHECK 

Meter: Cu. ft.is in. HG 

Pitots: ~ ~,$ in. H20 

_~ • c . 9~ ~ 

TMP TN(rFR R 

Initial Fina1 

1 -S S 

I I ~ 

Lo Z 

O 

ZD1 

COIKMENTS: yZ 

2, $S 17, S%~ 

POST-TEST L'GAK CHECS 

-Meter:0•oa8 Cu. ft. 5 in. HG 

Pitots 

~ 

5.1 in. H20 

 s. y 

i ~ 

I_ I ~ ~ Ai! 

~ ~• 

TS ,f a , a , 

~ I ~ 

Vn ~-TELIAP'

?n ~ZTMa. M VACTJC 

► 

OVEN 

c~~ ~ ~ 1P. 

. ~... 

°" r I r3 INL=`► ~t C C IN P-ic 

KOLL i 13 J~ 2 I / ,A 1 1 13 ,052,1 7 I 70 1 ,;L q 2 i(a 1 3.0 

~ 18 -,zg:jo) •( 3 1 1.3 t 1 3.6 I f 7 1 7/ I;ZS5 ! 4 7 1 3-6 

3 IY: 31 1 13'2 7 I 1.3 I I .a 13S6.7t I 1 -7 1 2S 1(.7 ( 3.6 

y 11:33:301 ( - I 1 { 2,-7 13E3.) I I 1.2 (~ { 6? 1?.d 

5 1g-34 1 I 7. 1 1,7 1 I 13SS.51 i77 1 7/ I-IsS I G I?. 

(3:3170 ( 13 7S i 77 1 f 1,6 13 67 351 7g i 125 1 ~,? 1 3, d 

Q 13 ff0 I 1. ( 1 ! 13 s`r. '? 31 '7 T 1 73 1 ~.S S I 6? f 310 

:Z I:u :301 I i/ I, r 1 1 zS 134,/, 13 I D 1 -) 1aa I/,

? 1 1-6 

3 g;Y 1 1355 I -Z 1- I.7 I GY,f3,3 I o 1 73 I;~-5( I 6 8' 1 3.6 

!;Yqt?o{t 0 1 1 1 I 2. 136 6. 415ZI 60 i? : -~- S 2, i GV I j. a 

S '/sz, i 13 I. I 1 2-7 136$ 77 1 Yo 1*7q 1)5 

t:sY=3bf '.3 -al 1, a 1 1 2- 71 o d.1 fr b I S 125'7 (/. o 

~ t-:s 9 13 ,T3 i 9 ~ 1 I. 2 1373 -o59 i 7 7 1 75 1 ~-sS Y, o 

K:o/:301 1 .3 X5 1 7y f i 2 L I 75.19 I Wo I?S 12513' 1 6 9 1 Y• o 

3 19:a I I Q( 1.0 I 2,2, 13 7 7,-Z991 ft f ? (. I SS I 1 Y. ~ 

Z .YD 1 175 ! 2S 

o I: 13 1 t.l l I 2.5 13Sl142: 1 

':3af I ot I 1 • 13 83,81qL I 

•~ <<S 13 1. 7 1 I l, l38 ~ I I ~ I a SO I G S- ( 2, c) 

1 lq;r7;3a 13 / 1 7 Z 1 I . 1377.33- f 1 7 1253 16 ff 1 2- 

13o IA ~ i 3'2- I 0,s -7 

1365 I I 171,2 y 71 3 1 1 2, s/ 

19: is 1 13 S'S I p i I, 93. /7 93 1 7712-59 Ib I 

is I i I. 139 , e ~ 9 I 3 1 7 I ~ 

i tiy64 
PLANT : ~f`1e~ S ~~~c "4- 

DATE:Z2-1j g S 

REPETITION:3 

LOCATION: A~~eA 51

7Y. 

OPERATOR : D3,.Jl3. CD 

STACK ~ :k~ '& ex 

SAMPLE BOX a: ~ 

METER BOX #: $~ 

AMHIENT TEMPERATIIRE : 7~ 

BAROM'ETRIC PRESSIIRE:al'1.62 

ASSUSED M0I STURE : S% 

PROBE LENGHT:L ~ p~x 4c - 5~•~~ 

NOZZLE DIAMETER :~ 2Y'76) ,, 

STACR DIAIwETER :as W 49 cMETER H : 1, 5333'1y 

C FACTOR:I Yy 

METER CO-EFFICIENT:1 A203a 3 

FILTER TgRE: ~ L11$1 

PRE-TEST LEAFC CHECK 

Mete: : D.o o$ Cu. ft. 15 in. HG 

Pitots• - y/ in. E20 

~ ~!. L • ~ 

o e 

SI i ~ 

~ 

~ 

F'R1J 

2 FI ELD DATA 

~ . 

I?KPINGERS 

~ Initial Final 

.:_.;. ~z : ~ ao•~ ! S > 1~ D 

ZQ6 

~ ✓ a2: ~oorn ~ S • _ 161 

w-S : 1OUI-?l S NAd~ 

aS : }oA_SY', ~ ~. 207. ~ 

~---~_ 

COMMENTS: 

c d Z 'Z 

d ~~~ 1z_l% 

POST-TEST LEgKK C3ECR 

-Meter:O.Do 7cu _ ft.s in. HG 

Pitots I--- in. H20 

PARTI CULATE 

t* 

_ ~ ATI 

~ ~• 

i S fI ! I 

! 

V n ► rn 

t AlL.= ~ ~ZTn 

 i~ 

tM~

r3 

OV~.N 

i c~vtF i' MF. C IN Hc, 

I I ra: y-5 I iZ 5 I 1 1.2- 1 I2 l03 ( I -7 JE 1 i 1 2- 6 

. 13o"z i I I 3.a 19 11.2191 0 i 79 1 z 1 6 ( 3.0 

(a •Sa 1 1,293 l 1.2, ( ( 2•(c ! gi 1 7 I2S"3 I 6 7 I.O 

y I 1 l ( 2 1!9. 3 I I 1)Gv ( 67 ! 3 -0 

s 1/2;ss i 1Ya '2, I 9.5 1 . f 2,1 I z/ a1 3 1 13 I 8 e?~s-y t 47 i 2_ 

I yb l ! 51 I I/i 1 1 23.0 1 '5y I 7 I 2S 1 47 f 2,0 

11166 I, I I 2. I Y:zy, S28 I ( I S 1(' 1 2<0 

2 1; 0.301 I`LV 1 1.2 214 { 9 r. I so ~-5"6 1 4. W' I?- d 

Yo 1 I) 2 1 2.7 I zS. a I 5f 7 1 96 i 2SZ I ~~f 

I o3 I. L I 

{~ i I YD I 1 I I 2• 3 lY33.SZ I ~'8 ! i ~ S i ~ fs I 3• d 

1 2.6 I 35.6 I$ ! 1257 

C! ' I I 1 1 Z I ll I ~ 1 gZ 12s' !G8' i z 

2<< :?o{ 5 I o 1 1 . 1 f.Z.3 I 3!( 8 ( 13 z 1 2 5 7 I6 ( Z- v 

3 t I o 1 1,0 1 2-3 I/,?3 11 87 1!~-3 1 a-5 Z 1 ~ $' I -o 

y r:Zb:N 1Y6'7 1 17t, 1 2,2 , IqV3.01 Sal l 33 ! 255 I 1 Z d 

I Yzi cl I gY i 1 2 ly 6.a2 ! 1 Y3 1 a- ,5- ! G- 1-2 o 

~ 11:31:sd i Y,03 1, 7 I I 1. -2 lqfe,674 I i 1,261 1 6 1 3. a 

I glo 1 77 1 I l. IYYq, 1 20 1 83 1';-S9 I i, $ 1 z_ 

2•1 / 37:.161 1 ~ 2'1- 1,9a I ( l,8 1V51.75s 1910 1 gY I ~iS s~ It. Z - eD 

2!, • uA I 1 c/1 Ll 1 9'4, ( I li8 I y53-(.`181 170 1 8y Il66 i 6 4 IZ.O . ~ I / : 41:m I Y)Lq 1 

5 lr yS I I yl 1 

Ir. ~ 7-3b1 I 

I!: S'o I I I 

i 1 /19 IYS l qo I I;Ls5 I1~ q 1 2.0 

s I 1 0 jqp,yqo t 4 n I A S 1 2S(, IAY • I z- O 

6 1 1/ 3 I'tS9 zyfll 91 (IS S 12,3 ( ( 2' c. 

- ► 1 58 1 y60.3 65 I I 

av 
IMPINGERS 

Initial 

~ l:iaan,JS> ~[/ U 

ltr2: io4)^l S ~ 

#3 : /~v. ~/ S N4 a 1~ 

a4 : ------ 

45: 20Rlf, 

COMHENTS : 

Cd Z 

2, ~ l ~~ 

Fina1 

/ SS+ 

P-r— 

IGZ 

Zo 6 •cS 

------~ 

PARTICULATE FiELD DATA 

rN 

PLANT: t~y~rn 

DATE:/;L -13-95 

REPETITION:y 

LOCATION:/¢1444 s '/"I' 

OPERATOR : '6ai OQ' L~ 

ST11CR -W: Ki iYl G,,fi 

SAMPLE BoX -U : ! / 

METER Box #: g 

AMBIENT TEMPERATIIRE: 

BAROMETRI C PRESSURE :.1.9• 4 ~ 

ASSIIHED M0I STU~£ : S °fj . 

PROBE LENGRT. / p~X-CvG Sfa%nless 

NOZZLE DI AMETEB 

STACK D IAAiETER : A S KI ,X 2g L 

METER H :!. S 33 34 y 

C FACTOR : , V/ 

METER CO-EFFICIENT:/.02e3a3 

FILTER TARE : , q 1 ~-5 

PRE-TEST LEAK CHECR 

Meter: d.aa$ Cu. ft.15 in. HG 

Pitots : ~ y,ti in. E20 

POST-TEST LEAR CHECR 

-Heter: 0,0 p Cu. ft. y in. HG 

Pitots ~ j in. fi20 

A 

~ . 

e 

~ ~ 21. 

is °" f p ~ p 

~ ~ 

 V n ► n l_~Tjrn 

i 

OV~Pt 

~ i ctrtP. P-i~ I 

~kM~-- ~}VL~.~C;: 

- I c~ , r ~ I I r~.~ iNL=~ t i~ T MP lCIN 

(!2;ao 1 I `I I ~ ! f D. 1 1141,1531 ! i Y.L. I( I 2,0 

~ 2;cZ:3ai l a v I ! I 2,1 IY63•7 ! 97 i I2 0 14'? 1.7. 

i 3 ( I 1 ~65/br ! I I ! 1)-52- 1 ! 2,0 

1 f I D I 1,2. 1(a7.I.5 I O I IV 1 -2-51 i 4,16 ! z.G 

I=: 3 I,3 I f D 4116 .'!3{ I S 17. ! Co ~ I Z. 

I7;«=,~ oi I --- I 5._ I 11 i3 I I 95 1 26 Z I Gir 1 2.6 

f o 3 i - I I z. IAI-72. ~y7 I o I 140 ! ~r 11- o 

I o 2 i I I z. q lq7Y,93q I i fr- - 1 Z a 

I Yc 3 1,0 l 1.2 I 77,1z3 I I & i S I(o S I 1- 

i~ ; y:3Dl I V6 ti I 1 1 2 I 7. 2 f 4/ : Zs I G 1 2. o 

lyll.qobl l g I a-.Ss 47 1 

83 -53 

C ! 1z y I7 I q I I o I ~ SS. ~ b ! 7 I ~? I 2<S! l cq I Z. 0 

i I, I i I 87. 1 ?9 f -5 0,52- 1 G Q ! 2. v 

I,L%39 1 I13 1 I 2: 89• y9 I O 1 IS 12-5 I Gc7 1 2. 6 

' y1'yr 1 Iq/'I, f i, a I 2. 1 Y I I 1 85 I 2. o 

(o IZ57 I-rf 1 2_ O 

I3: 44 t3 1,7(o 

1 b I ~ b I D I i ~ .S I So I I ~ ! 2,S 16 I 2.a 

2•I ~ 5z;3 I / l I I. I'~ 95370 ! 

iz;55 1 I r i S I l. 1 S51,z6/ 1 9 ~ i$ I zSS I ~ I z. 

Li I.2 ~ 5:301 11 io I i 1 563 /151 cl 7, 1 I 2Sy I I? 

I', c a I i L I 3, ( I I 5 I cl 2 1 pS7 I 1SZ l 0 I. Z. o 

13;O1%3dl I. 4 l, D, I d7. ( ci2 I 

I Av 

. 

I I I i k 1 i4~ ,Sy► ! I : k ~ 

.L 1.11. 
PARTI ClJ LATE Fi ELD DATA = 

Y•, ~ ~ 

000voa d = /.o ~ Z6'~ 

eCOEF 

PLANT :41Ne_A 9 U e(= ✓~' 3. 2 ~ o 

DATE : t Z-1 3 tq y 

Y8a REPETITION:1 

LOCATION: ~~ ~r _ IlipINGERS 

OP£RATOR:,~ ~ u4~~ Initial Final 

STACK #_

~J Z SAI~LE BO7C # : ~`j /~/~~ ' ~`'rI ;IOD•" 

METER B07C #.'7 U lFA~ F v #2;.%O~L~ 

AMBIENT TEMPERATIIRE:7S \ ' #3 e~~~ y,:~ ./~ :`L ~~"~ 

BAROMETRIC PRESSURE: AS- 4 ~ $4: ~ ~ 

ASSDHED MOISTURE: #5: ZGY,jr 2, 

PROBE LENGHT : (q c 

NOZZLE DIAMETER: •~ Yfr, , Lyt, .ZSrSrC• Zi~7s~A00?~,SS' O S: 

STACIC DIAMETE~$. ~ ~~~Y~w ~ 

METER H / ~ 7 G 

C FACTOR: 

METER Co-EFFICIEN r : , %~ l ~ / Q ~v 7!, 

FILTER TARE : ~ q/23 

PRE-TEST LEAS CHECR POST-TEST LEAR CHECIi 

lrieterwl4 Cu. ft.ly in. HG . -Pieter:.0/9 Cu. ft. in. FiG 

Pitots : / ' I ~,s" _ in H

' 

20 Ptots i V in. H20 

=~ 

~~ 

TI Ts °~ ' ~H Vm 

 r~ 

i n ~TMM 

tNL_'"ii 

OVEl~t tt~1PT,,, 

TC7~SP. T— MP! 

VACut~r 

CINf-i-c,

, 

~ 31, 10 1 I o(a 1 1 -1 , 1 i f7 12Y I s 12,0 

2~ 1 i• I ~ ! I 0,15 I ~ f IZ I ~~ ~' IZ,J 

3; S I ~ o~e E'5. 1f 1-, 12 1 y7 2! 1} 1 3. 12 yo I;- 

! I1,64 1,51 1 Y i i y 1 5/ Ir 126o 1 6-_ 7 I.~ 

c3 : s'0 i Ig/~ I,qu 1, I/, ! W,17q 1 073 I Z J I z sy ! 12 a 

Z 1 1 lc~ 

I.3el, 3 I, ~/ I/1, I-13 i KJ I 2 S'?' 1 

I!~ 1 1! G I, I I, 1 L(9,ye 71 1 c/ I Y 1 1 - 1 6- I.~ , U 

t I I sS' I 0 I r s-I J` I Fq I z r-,11 I I ~? a 

LI : oQ I f: . , v s3. .? I No I f(S` I2 s 1! r! 1 2.4 

Z. f I o i. I,? f i s. ST ~ i s' : 2sv 1 r I ~_ 

4'0sf 1 D ~ I I ,3s i. I ~1'S' I ~ 1~ r l~ 7 1 2.d 

!-161 k.q5 1.571. I' I Sl• 141 9 I r I2_~O 1 7 120 

~ -1 r I r! rt, ZS-3 io 7 ! z0 

7 1.2, D 

f s t S 1 Z-5-1 f 67 I2 ~ a 

I d f r ( l r 3, & V zl q r ( 4 I z sy I eg 7 12,0 

I( , I 95- i I zsr 1 07 I ~ 

I I7 1 + ~ .i Z c I(r, vl I '~ I 8 I zSY 

~F 

4 : 2 

1 

I '/0 7 1+ U. 

1/, 7 1•32- 

I 1 

1 -1 1 

I i o 

( 1 6 

I•& b! 1 .S 1 0.7 I 7S3 

100, 2S0 i 13 f f 7 1 2S/ 1 

q9 I f7 1-Zs) 

Z I 3 I IZS I%:,~ 

1 

I 

~ : I OS'' I j8 I I 3 I2 12 I y I 

I ► 141f 1 4 1.W VMH !K 7 sI I 

t7ly, 211 1 

I_ ~ 

69 

1 av I 1 I1,7-03 

~o 

-4~ -5 r r 
PARTICULATE FIELD DATA 

~ 

PLANT 4 .14~top g 

DATE: 12-t3-4 ~ 

REPETITION:,Q 

LOCATION:O" 4" 

OPERATOR : r} ~~ 

STACK # : 

SAMPLE B07C #:la 

METER BO% #:7 

AMBIENT TEMPERgTIIRE:70 ° 

BAROMETRI C PRESSIIRE : 21. S1 

ASSUMED MOISTIIRE: s°~ 

PROBE LENGHT :6 ' SS ~ G z`t~6 ~ NOZZLE DIAMETEB: . ~~0~ 03 3 Y ~ ~ 

STACIC DIAMETER: ~6,,y1'4!s,"!,b 

METER H : /.R 768GZ 

C FACTOR : . gz{ 

METER CO-EFFICI'..NT: '• 

IMPINGERS 

Initial 

COMMENTS: 

co 

~—. 

Final 

fL9 

/ U ~o 

z~ y 

q/ 

FILTER TARE : 

PRE-TEST LEAK CHECK POST-TEST LEAK CHECK 

Meter:,14r Ca. ft. // in. HG . -Meter: Cu. ft. in. HG 

Pitots: in. E20 Pitots in. H20 

~ — [) 

V 

Z7 

~ ~ F 

~ 

~ 

Q. ` 

a~ 

~ H V m 

r~ 

` ? m ~TM I tNL:'T T 

4V~i~i tMP V~~: 

~ icMP. ~MP. 1 ~ IN F-i~: 

1 Y : " I/ -01 I 1 3 2.. I b L 1 , 0 I G 12SQ I GeK 1 Zo 

z 1 f 2& - I /,~ 1(/"1 1 I, ,9 IrC- I tf 4' 1 1 

S: dL I/4 I, I I. , 0 { 7• 7 7Y !yy { Y,7 1 2 s`' I GV I z, 

I 

~ 

2 

~ d71. 

I 

i i qt 

I 1(26 1 71 

I I ~s 

1 , 

~'~ zl z 

it'`1.779 1 9 I Y3 Ioz5-- 1 1 6,~l' I4a 

3 1,~7 I z. 1 I r 1111 1 1. 1176 ,0101 1Z 1V Z-- 1 2s-Y i Os I.1.0 

1 I 7 I f rq 1 t 14 1 g74rl1rl 1 L ! Z- i zs" 1 12 ~ 

Gi s:17 I 1 /6r0 1qD I 1/ s- 1 tiGss! 9z I CZ I 2rl 1 ~ s I ~ o 

z I I 0~ t 1 I ~. 1 y~ , f i Z:2s6 I C~ f iz.d 

I25-a 

+ 

1 

~( 

S: Z7 1 /al 1 

I ! o/ I 

/09 1 

I G 1,3 f>' 

1 

I 

f,y 

I • Z 

ht 

If s { 3 

I 7~7i2 I Q y I 3 

Lf 1,2sZ I 1r I 8"7 

8 Z I Y f ~ 

2<! 

I 5c 

i 2 

I 2"1- 

i 64 i 7.1 

f G I 

i66 i..IJ 

i l 

E l 

1 

r l 

S~ 7 

s:4t 

I s! u7 

1 = I I.3~ 2 

! I I 

t D& i,/l 

1 

1 

I 

I 

I/~ Z 

c 

I 

( 73 

1 ~ SI 

l 21 ~ 7. ,. I I ~ 

1 31 i E I p 

I 41LAY I I 

!, 7 I`l~ I 3 

1, 37 -710 1 fJ 

t g 

~'/ 

12yf 

I ; 

1 :2 sy 

7 I 

I ~ 1 7 

I Io 7 Iz 

t i l - ' 

1 2 1 2.6 - 

1 

► 

I r', i ~ 2 

I I 

t 

I 

I~ y 

30 

I. xz 

• 76 1 3 I 2Sf 

Iq 3bS i I V5 1 27r 

le, I I -1 f Z 

1 67 1 2. d 

I G 7 1__ 6 

1 b yI ?_. 

I! -71 I I i I 61 I910. 711t 1 I I i 

^ t Ay t 
PARTICIJLATE FIELD DATA 

n 

PLANT : AYX-ex s ~~~ ~ 1~ 

DATE : /Z//;/fs 

REPETITION: :g 

LOCATION : 

OPERATOR: 

STACIC a: tCie ),a c, s~ 

SAMPLE BOX a: 

METER BOX #: 7 

AMBIENT TEPPERATDRE:6~°~ 

BAROiiETRIC PRESS7RE: Zg- ~ 

ASSUMED MOISTORE: S% 

PROBE LENGHT: _ 

NOZZLE DIAMETER:(-2Y76) 

STACQ DIAMETER: 30"L X'f8 w 

MET--R H : /. y7o &6 L 

C FACTOR:-Fy 

• METER CO-EFFICI."NT: 

FILTER TARE: 

PRE-TEST LEAR CHECS 

Meter : .o i e Cu. ft. / 7 in . HG 

Pitots : in. EE20 

I?'~.P INGF.RS 

Initial 

4rI «If //,O 

vJ''2 : 4 • fi~20 

#3 : /go'.a , /N N•t o ~ 

~. a4: 

a!5 : 

COMPlEN'"S: 

POST-TLST LEAK CgECIC 

Meter: G,o /z.Cu. ft. or in. HG 

Pitotsi $.T in. H20 

Final 

~G 

1D%z 

6 34 

~ 2 

I ,A?t 

~ ~ 

i s I ~, c ~ I V n 

r~,~ 

! i rn !,~, Zrn, 

iTlL< •i 

Ov=st IM~--1}vL~.~C: 

C i ~r.. P. Y ~ t~AP. I~ I~~ IN 

! I h~ 

& ..., 

1 16: /! 1 I // S 1. 3/ 1 1. 1 O J I d-> I i v- I 1 c 

! i I/or 1,yS 1 I/4 1gY I ° I 2sZ I 6 7 1 

l6;/6 I I oS 1 .67 1 1 2.08 I/t./ ! e4 1 So l 2S3 IaY I 

Y I I I -W7 {/. -7 f IS? I 79

, 1 77? {Z, 7 1 

U I -1 /-" 91 1 71 1 Z4id! 1 4 8" 1 

1 ~.~► I ky 1?9 i zsi I ak- I 

s Z 2 3 I s~i ' f -7 I ~-? 16/ 7 f I 

i 23. 1 yo 1 29 1 Zr/ I G 7 I/ 

o G f, o I 74 1 zs7 I ~ 7 I l 

I ~ { I 06 117 / I 1/•! I 27.6 I So i 79 

3 16; 37 f I a< I. ~ i I ,3 1 ' 29- / I o I 9 I zsy 1 -1 7 1 i 

I.sz. I I •q I,,3v. ZS3 1 6? I ~ 

I76 I I /-Gt 1Fz7 6. I q I I s3 1 6 8 I I 

.8, i t,o z I 3y v I qo ZSZ I ~ ,k I I 

-7 I Zr3 I 6' ~ I/ 

I/06 I, I . 1 37•Y I / 1 

o~ !, 3 ! ( -~~ 1 39.Z I ~t 2 l 79 

Z I ! I 1,06 I./ I I 1lev•7 1 4~ 1 I I Z~ZI GG l 1 

t&4,6 I, I 2 I I- I y-il I o l 747 1 ZS 1 67 1 ~ 

• 1 I I/oG , ! 28 t I 1 ~r, t fy ( to I 25S 1 6 c I 

~ 1 I ~

:a ~ . oyl 1 o S' I./ Z I • yi/ Ilel ZI ~ I I 2SS' 1 6g- I/ 

sa 1 47 I j 

( ( I I; ,! 1 1.0 W. I I 7g f Z y4-' 1 6 7 1 / 

I?y fy I I I I I 62 1 V7, 4771 

I 1 v I I I i I 1 i?f.SlS'r1► I ` I ' 

i~ ~ 
APPENDIX E 

/Z,~ 
BOC GASES 

SLJL. :7c15e5 

Divi s ion ofi the BOC uroup, Inc. 

1075 Cincla'r, e Dr, ive 

Port Allen, LA 7k.~ 767 

Customer, Order No. : SF725 

Shipper IVo. : 716519 

Test No. . 0895-001 

;NFL`!TICAL RF_-'ORT 

To : iiOC RETialL 

DALLAS, TX 

BOC GASES 

1075 Gnclare Drive 

Port Allen 

Louisiana 70767 

Telephone: 504-3 88-0900 

FAX: 504-388-0959 

Date Repor-ted: 08/01/95 

Material Submitted: CARBON MONOXIDE IN NITROGEN 

Inrormation Requested: CARLON MONOXIDE CONCENTRATION 

r+lethed of i=Hnalysis: NON—DISF'ERSIVE INFRARED 

Result of Investigation: Cy1.No. : CC40334 

Comoonent Specification Concentrat i on 

CARriON MONOXIDE 400 F'F'M 398 PF'M +/— E% 

N I TROGEN BALANCE LiALANCE 

A Division ofThe BOC Group.lnc. 

e 

63 Alithor,ized Signatur•e 

/~ 7 
aa 

06 

J 

tIj -7 

en 

I-L 

n M 

lo 

13 

= — 

,m -l=- -= -o 

I crr eo 

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M cxmw C= 

to 

CD 

em 

ew 

02 

r:r "Z •w 

zic 

co 

64 

C) 

0 

cn 

m 

cn 

co 

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o 1\0 1 

c- t -i 

CA C7 

co 

co 

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eb 10 

Q6 C3• 

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0 

CO 

CO 

-0 

0 

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c 

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(3) 

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93 

73 

C%O 

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6 
.;~.Scott Specialty Gases 

500 WEAVER PARK ROAD. LONGMONT, CO 80501 (303) 4424700. (303) 651-3094 FAX: (303) 772-7673 

CERTiFiCATE OF ANALYSIS: EPA Protocol Gas 

Customer Assay Labontory Pluchase Order 1515 

ARMSTRONG ENVIRONMENTAL Scott speQaltyGases, Inc. Scott Projed x 0820996 

7715 SOVEREIGN ROW 500 Weaver Park Road CGA Fitting 660 

DALLAS TX 75247 Longmont, CO 80501 File Nnmber 20996-03 

ANALYTICAL INFORMATION 

Thls certification was performed according to EPA Traceability Protocol for Assay and Certification of G.tseous Glibration Standards; 

Procedure Gl; September,1993. 

Cylinder Number ALM-053354 Certification Date 08/30/95 Expiration Date 08/30/97 

Cylinder Pressnre 1857 psig Previous Certification Dates None 

ANALYZED CYLINDER 

Components Certified Concentration Analytical Uncertainty' 

(Sulfur Dioxide) 451 ppm t1 % Directly NL4T Traceable 

(Nitrogen) Balance 

•Ana)ytical uncertainty is inciusive of usual known error sources which at least includes pr<avion of the measurement ptocesses 

REFERENCE STANDARD 

Type Expiration Date Cylinder Number Concentration 

NTRM 1661 05/25/96 ALM-040325 468.9 ppm S02 / N2 

INSTRUMENTATION 

Instrnment/Model/Serial li Last Date Calibrated Analytical Principle 

Nicolet FTII2 / 8220 / AAB9400251 08/21/95 Scott Enhanced FTII2 TM 

ANALYZER READINGS (Z=Zero Gas R=Reference Gas T=Test Gas r-Correlation Coefficient) 

Components First Triad Analysis Second Triad ?.nalysis Calibration Cnrve 

(Sulfur Dioxide) Oau 08123195 Response Units: ppm Oato 09r30195 Rasponse Units: ppm Conpntratlon • A+gx+Cx2+Ox3+Ex4 

Zt - 0.204 Rt - 488.900 T1 - 451.236 Z1 - 0.073 Rt • 4e8.900 Tt = 449.923 r- 0.99999 

R2 • 4e9.513 Z2 • 0.3Be T2 = 451109 R2 - 4e8.597 Z2 • 0.302 T2 = 450.171 Constarttx A - 0.07994e3 

Z3 - 0.403 T3 • 451.210 R3 - 4e9.158 Z1 • 0.149 T3 • M9.627 R3 - 468.373 B- 0.9587 C. 0 

Avq. Cono. of Cyl. a 451.35 ppm Avg. Cona of Cyl - 449.91 ppm D• 0 E- 0 

000 

(. -I 

.. - 

Spedal Notes Do not use when rylinder pressure is below 150 psig. 

70 
Scott Specialty Gases 

500 WEAVER PARK ROAD. LONGMONT. CO80501 (303) 442-4700. (303) 651-3094 FAX: (303) 772-7673 

CERTiFiCATE OF ANALYSIS: EPA Protocot Gas 

Customer Assay Laboratory Purchase Ordm 1515 

ARMSTRONG ENVIRONMENTAL Scott Specialty Gases, Inc. Scott Project M 0820996 

7715 SOVEREIGN ROW 500 Weaver Park Road CGA Fitting 660 

DALLAS TX 75247 Longmont, CO 80501 File Namber 20996-04 

ANALYTICAL INFORMATION 

ThCs certification was performed accordinp, to EPA Traceabilitv Protocol for Assav and Certification ot Gaseous C.dibration Standards; 

Proczdure Gl; September,1993. 

Cylinder Number ALb1-053368 Certification Date 08/30/95 Expiration Date 08/30/97 

Cylinder Pressare 1847 psig Previous Certification Dates None 

ANALYZED CYLINDER 

Components Certified Concentration AnalKtical Uncertaintv' 

(Stilfnr Dioxide) 235 ppm tl % Directly NLSI' Traceable 

(Nitrogen) Balance 

•Analvtica) uncertaintv fs 'uxlusive of usual known ertor soun:es which at Icast includes prrciaion of the measurement processes. 

REFERENCE STANDARD 

Type Expiration Date Cylinder Nnmber Concentration 

NTRM 1661 05/25/96 ALM-040325 468.9 ppm S02 / N2 

INSTRiJMENTATIaN 

Instrnment/Model/Seriai M Last Date Calibrated Analytical Principle 

Nicolet FIIR / 8220 / AAB9400251 08/21/95 Scott Enhanced FTII2 TM 

ANALYZER READINGS- (Z=ZeroGas i'.=ReferenceGas T=TestGas r=CorrelationCoeffic:ent) 

Components First Triad Anal sia Second Triad Analysis Calibration Cnrve 

(Sulfur Dioxide) Date 0829195 Rssponse Unns: ppm Data 08130/95 Rssponse Unitr. ppm Concantraoon A*Bx•Cs2+Dx3+Ex4 

Zt • 0.204 R1 • 488.900 T7 - 225.201 Zt = 0.073 R7 - 488.900 T7 = 224.479 r- 0.99999 

R2 - 489.513 Z2 - 0.388 T2 • 225.835 R2 - 488.597 Z2 = 0.302 T2 - 224.104 Constants: A= 0.0799483 

Z3 • 0.409 T3 - 225.095 R3 - 489.158 Z3 - 0.148 T3 • 224.294 R3 = 488.373 8- 0.9597 C. 0 

Avg. Cono. of Cyl m 225.31 ppm Avg. Conc of CyL = _ 224.29 ppm 0= 0 E- 0 

000 

71 

Special Notes Do not use when rylinder pressute is below 150 psig. 

135 
APPENDIX F 

136 
Pre Test Meter Calibration 

Meter Box Number = 8 Average Y Average H 

Calibration Date = 11/10/95 1.020303 1.533344 

Calibrated By »> DB 

Barometric Pressure (Hg) = 29.48 

Point #1 Point #2 Point #3 Point #4 Point #5 Point #6 

Delta H 0.5 1 1.5 2 3 4 

Test Meter Volume 5 5 10 101 11 10 

Meter Box Volume 4.908 4.836 9.597 9.5441 10.361 9.334 

Test Meter Temperature (F) 70.5 71 71.5 72 72.5 73 

Average Meter Box Temp (F) 74.75 76.25 77.75 79.5 80.75 81.75 

Time (minutes) 11.7 8.17 13.75 11.71 10.351 8.14 

Test Meter Y 0.985 0.975 0.97 0.965 0.9571 0.958 

Meter Box Y 1.025627 1.041537 1.050316 1.057276 1.070115 1.078183 

Meter Box Corrected Y 1.010243 1.015498 1.018806 1.020271 1.0241 1.032899 

Meter Box H 1.549364 1.509585 1.601971 1.547061 1.497584 1.494501 

72 /j,7 
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73 

~~~ 
AKMS 1 RONG ENV{ RONMENTa_L +ING. 

URY (GAS METER #: ~ 

DATE: /l-io -95 

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74 
Temperatnre Meter Calbration Form 

Meter 9 ~ 

1 /- 16,- (7s 

Emtecli K 

Themwcouple Checker Probe Stack . Oven Exit Anx 

Point 1 32 F 

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~ D B 

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75 ~~G 
Pre Test Meter Calibration 

Meter Box Number = 81 Average YI Average H 

Calibration Date = 12/14/95 1.03185 1.479067 

Calibrated By »> D.B. 

Barometric Pressure (Hg) = 29.781 

Point #1 Point #2 Point #3 Point #4 Point #.5 Point #6 

Delta H 0.5 1 1.51 2 3 4 

Test Meter Volume 5 5 101 11 10 10 

Meter Box Volume 4.777 4.77 9.5141 10.431 9.406 9.359 

Test Meter Temperature (F) 70 70.5 711 71 71.5 .72 

Average Meter Box Temp (F) 75.75 77.5 78.51 801 801 81.25 

Time (minutes) 11.32 8.02 13.611-12.6" 81 9.471 8.17 

Test Meter Y 01.985 0.975 0.97 0.9651 0.957 0.958 

Meter Box Y 1.056733 1.059434 1.0619951 1.0671531 1.072211 1.076437 

Meter Box Corrected Y 1.040882 1.032948 1.0301351 1.0298031 1.026106 1.031227 

Meter Box H 1.430365 1.4339551 1.5486221 1.477111 1:498196 1.486155 

76 

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Calibrated By »> D.B. 

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Point #1 IPoint#2 Point #3 

Delta H 11 1 1 

Test Meter Volume 101 10 10 

Meter Box Volume 9.775 9.832 9.875 

Test Meter Temperature (F) 69.5 70 70.5 

Average Meter Box Temp (F) 68.75 73.5 76.5 

Time (minutes) 15.97 15.88 15.921 

Test Meter Y 0.975 0.975 0.975 

Meter Box Y 1.019053 1.021282 1.021589 

Meter Box Corrected Y 0.993576 0.99575 0.996049 

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Point #1 Point #2 Point #3 Point #4 Point #5 Point #6 

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Point 1 32 F 

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Poiat 1 

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~~~ 
Enclosu_re 2 

NOT SUBJcCT TC iilE REu ~:!REA'ENTS OF ~ 

SECTION 3507. PAPER;iORK RE7UCTIOt4 ACT OF 1980. I 

INFORMATION REQUEST FOR BRICK AND 

STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS 

I. Instructions 

Please return the completed information request to: 

Bruce C. Jordan, Director 

Attn: Bill Neuffer 

Emission Standards Division (IVID-13) 

U. S. Environmental Protection Agency 

Offce of Air Quality Planning and Standards 

Research Triangle Park, North Carolina 27711 

If you need clarification.of any question or item, please contact Mr. Bill Neuffer of EPA at 

(919) 541-5435. 

This information request should be completed for each facility that manufactures brick and 

structural clay products, including facilities that are not major sources. Information is 

requested for all processes at your plant that emit hazardous air pollutants (HAP's), 

including those processes that are not associated with brick and structural clay 

products manufacturing. Sections II through VII request information specific to brick 

and structural clay products manufacturing, and Section VIII requests information on 

emissions of HAP's from other processes located at the facility. Processes that may emit 

HAP's include those processes that use or handle any materials that contain a HAP 

compound, all processes with elevated temperatures, and all other processes in which HAP 

compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is 

included as Attachment 1 to this information request. Attachment 2 provides background 

information on the requirements of the Clean Air Act and explains how the information 

requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations 

and acronyms used in this information request. 

Several tables are provided throughout the information request for your convenience in 

answering the questions. An example response is given (shaded first column or row) in 

each table. If additional space is needed to respond, please make copies of applicable 

pages. If necessary, please make copies of this information request for additional facilities. 

No additional emission testing or monitoring is required to respond to this request. 

H. General Facility Information 

A. Name of company At-hens Brick CorTpany 

Name of facility Athens Brick - M.i.neral Wells Plant 

Page 1 of 28 

1--0 
Facility address: 

No. and street 7510 Highway 180 East 

City Mineral Wells StateTX Zip 76080 

Latitude and longitude coordinates of plant: 

Standard Industrial Classification (SIC) Code(s) of brick and structural clay products 

manufacturing operations 3251 

Dun and Bradstreet No. 041083403 

Total No. of employees for company 2350 for facility 19 

(If facility is a foreign subsidiary or if company has foreign subsidiaries, include 

number of employees not based in the U.S.). 

Please complete the following shift information for the facility: 

Shift No. of employees Hours per shift Days per year 

1 17 8-10 345 

2 1 / 8 365 

3 1 8 365 

B. Respondent name Robert B. Cai.n 

Respondent title Senior Environme.ntal Engineer 

Respondent address (if different from above) and telephone number: 

No. and street 1341 W. Nbckingbird Lane 

City Dallas StateTXZip 75247 

Telephone No. (_j 972/647-3932 

Name and telephone number of technical contact person (if different from above) 

Name Telephone No. (__) 

III. Information on Ogerating~Permits and Applicable Federal Emission Standards 

A. Please provide copies of relevant parts of all operating permits and permit 

applications for your facility. Relevant parts include the sections that provide 

specific information and data on: processes that emit HAP's; the use of HAPcontaining substances; emission levels for HAP and surrogate pollutants (i.e., VOC 

Page 2 of 28 

/~-V 
for organic HAP's and PM for metal and other particulate HAP's); emission control 

device design and operation; monitoring and operation and maintenance (O&M) 

procedures for control devices; and generation and releases of other media such as 

wastewater and solid waste that are associated with the operation of air pollution 

controls for brick and structural clay products manufacturing processes. 

If the operating permit or application contains the same information requested 

in any part of this questionnaire, you may respond to the requested information 

by referencing the page or section of the permit/application to avoid 

duplication. If you reference your permit or application, you must supplement your 

response with all of the additional information requested in this questionnaire that is 

not included in the permit or permit application. If you prefer, you may submit the 

requested information from your permit/application on a 3-'/i inch diskette. 

B. If any source or emission unit at this facility is subject to a New Source Performance 

Standard or other Federal emission standard, please identify the source and 

applicable standard. Examples of applicable NSPS include 40 CFR 60, 

Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing 

Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and 

Dryers in Mineral Industries. 

/ 

IV. Brick and Structural Clay Products Production and Raw Material Consumption 

Information 

A. Please provide the 1996 production rates and the current production capacity for 

each type of brick and st.ructural clay product manufactured (e.g., structural brick, 

clay sewer pipes, structural clay tile, etc.). Note that production data should be 

provided in units of tons per year (tons/yr). 

Product 1996 production (tons) Production capacity (tons/yr) 

Face brick 45,000 55,000 esttmated 

Page 3 of 28 

Z'~~ 
B. Please provide the type and amount of each raw material and body additive used in 

1996 for manufacturing brick and structural clay products at your facility. Examples 

include clays, shale, and any additives that are mixed into the raw material prior to 

forming. Indicate additives by chemical compound, rather than by trade name. If the 

information requested is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than providing the information 

below. 

Raw materiaVbody additive Amount used in 1996 (tons/yr) 

Clay/shale 45,000 

Iron oxide 14,400 

Manganese d.foxide 1.5 

Epsom salt 0.525 

C. If available, please provide a copy of the MSDS's for the raw materials and additives 

listed above. 

D. If available, please provide chemical analyses, including fluorine, metals, and organic 

content, of the raw materials listed above. 

Page 4 of 28 

/ ~~ 
E. Using Table 1, please provide information on the consumption and HAP 

composition of all glazes and colorants that contain HAP's or HAP precursors and 

that your facility applies to brick and structural clay products. Indicate whether the 

coatings are glazes or colorants. Also indicate the type of product that the coatings 

are applied to and the total weight of coatings used in 1996. If the glazes or 

colorants are formulated at your facility indicate so and provide the production 

capacity. List each ingredient of the glaze or colorant. Beside each ingredient, 

indicate the total amount of the ingredient used in 1996. If the information requested 

in the table is contained in your facility's operating permit or permit application, you 

may reference the applicable sections of the permit (or application) rather than filling 

out the table. 

F. In the space below, please indicate any glazes or colorants used by your facility that 

do not contain HAP's and are substitutes for HAP-containing glazes or colorants 

used by your industry. Indicate which HAP-containing materials the non-HAP 

glazes or colorants replace. Describe any limitations on the use of those substitute 

glazes or colorants. 

None 

G. If your facility colors brick and structural clay products by flashing, please indicate 

the types of substances used to flash the products and the amounts of those 

substances used in 1996. 

Substance Amount used in 1996 Units (specifv) 

H. If availabk, please provide a copy of the MSDS's for the glazes and colorants used 

by your facility. If your facility prepares its own glaze, please provide any available 

MSDS's for the glaze ingredients. 

Page 5 of 28 

/.5 7 
TABLE 1. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND CnT.OR ANr.q 

Type (e.g., glaze, colorant) 

II Type of product glazed or 

colored 

111996 consumption (tons/yr) 

11 Produced at facility? (yes/no) 

I Production capacity (tons/yr) 

. >'.. 

Structurai tile:; 

' ~~'':. ~ .:.' :..' ..: ! ~~ !.: ~ qi.:.•. ~~ r`.i 

:.'• .;C..;..._ ..:."- :: ... .. ~ ,: '... ~~ t --~ 

`~.x:X,:i-:aY.e vr^,~'.. ♦ ..:/.yl: -h'•S ~»if'I:.Zy.-. ~ i:':~;'<f~~: : '

•.r:4 

.~ .. _~xL;a.~:~a>i'c ieriti'd~ii',+~:g>":a~b~_ ~~it3?'-~#~si:•,i~~.t 

Colorant 

Face brick 

1.5 

0 

Total usage (weight) of each 

ingredient (that is a HAP, 

contains a HAP, or is a HAP 

precursor) in 1996 

• 

•• i ~•r~ °°2~ F~+•"'%. ' ~ `~ 7. -af '"~

'7§t ~ _ r+.-.' ' • 

'•"_ #- ~~':~'~"~ !I {j~.; • _ - • - _ • 

c~^y~~ ~;: °~~,. ~~ 

~~_ p; ~'~~~ Y.~, ~1~ ~~' 

o-...2-.,'4 

I 1 • II ce~-..+,t • 

• . .- . _. _. :^FYyr 

!';Y.~r~~,:Ti`.:~t. :L•w~

i";~ ' . . 

- . ,~ :-,~-~aH"^~

C...i::• ... - 

s' 

If additional space is required, please make copies of this page. If the information requested in 

the table is contained in your facility's operating permit or permit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

Page 6 of 28 

~ 

/ •~ 
V. Description of Brick and Structural Clay Product Manufacturing Processes 

A. Please provide a simple process flow diagram for each brick and structural clay 

product manufacturing process line. An example process flow diagram is provided 

in Figure 1. A diagram of the plant layout with all processes and emission points 

clearly labeled is also acceptable. 

Assign a unique identification number (ID No.) for each process that has 

associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. 

Please identify all emission points, including those that do not emit HAP's. For 

emission points that are vented to an air pollution control device (APCD), assign an 

ID No. to.the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are 

uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof 

vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information 

request for any responses that pertain to any process or emission point. 

Page 7 of 28 

/.~~ 
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Page 8 of 28 

/ t-c 
B. Using Tables 2A and 2B, please provide current production rates, production 

capacities, and related information for each type of equipment used in brick and 

structural clay product manufacturing. In Table 2A, provide the requested 

information for only those sources that are known or expected to emit HAP's. In 

Table 2B, provide the requested information for all thermal processing, such as 

drying and firing sources. For combustion sources that use different fuels, Table 2B 

should be completed for each type of fuel. For example, if a kiln typically is fired 

with gas, but periodically is fired with oil, one column in Table 2B should be 

completed for the kiln when fired with gas, and another column should be completed 

for the same kiln when fired with oil. Provide the data in the units listed for each 

row. 

Page 9 of 28 

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Page 11 of 28 

lb-3 
C. Using Table 3, please provide information on procedures used to monitor the 

process operating rate for each of the pieces of equipment and HAP emission 

sources listed in Tables 2A and 2B. Use the same HAP emission source types and 

equipment ID numbers you listed in Tables 2A to 2B. 

Indicate whether you monitor process rate or not. 

Provide a sununary of process rate monitoring procedures that 

describes how process rate is measured for the particular piece of 

equipment. Include where the rate is monitored (i.e., rate of material fed, 

rate of material discharged, or material production rate), the units used to 

measure process rate (e.g, lb/hr or pieces/hr), and how the process data is 

recorded, i.e., manually, automatically (e.g., computer - printout or stored 

to disk, or not at all). If you monitor process rate at both the feed and 

discharge ends of the equipment, indicate so. 

Indicate the type of monitor, equipment, or instrument used to measure 

process operating rate. 

Indicate the monitoring frequency or how often process rate 

measurements are made. 

If instruments are used to measure process throughput, indicate in the 

monitor accuracy column the accuracy of the instrument. The monitor 

accuracy could be listed in terms of a percentage of the throughput 

(t 1 percent), mass per unit time (±21b/hr), number of pieces per unit time 

(t 10 pieces/hr), or other appropriate units. 

Indicate the frequency that the monitor is calibrated. 

Provide data in the units listed for each row. 

Page 12 of 28 

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Page 13 of 28 

/ 6a.~ 
VI. Identification of Brick and Structural Clay Product Manufacturing Emission Points 

A. Use the process flow diagrams developed for your facility and Table 4 to provide 

the following information for each HAP emission source at your facility. 

• Define HAP emission source type in terms of equipment, such as dryers, kilns, 

etc. As in the process flow diagram, you may group multiple pieces of similar 

equipment. 

• Use the same equipment ID numbers indicated on the process flow 

diagram(s). 

• If the 'emission source vents inside a building or to outside ambient air without 

first passing through a control device, place a check mark in the uncontrolled 

column. 

• If the emission source vents inside a building or to outside ambient air after 

passing through a fabric filter, dry injection fabric fillter, or scrubber, place 

the APCD ID number(s) in the column corresponding to the APCD type. 

• If the emission source vents through a control device type not listed in Table 4, 

indicate the control device_ type in the other control column and place the 

APCD ID number in the appropriate cell. 

• In the emission test data column, place a"yes" or "no" in the appropriate cell to 

indicate whether the specific source has been tested for My pollutants, including 

any HAP's, VOC, PM, or opacity. 

Page 14 of 28 

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Page 15 of 28 

167 
B. Using Table 5, please provide information on stack parameters and emission 

estimates for each emission point at your facility that is known or expected to emit 

HAP's. Provide information for all APCD's, including those that exhaust inside the 

building. Include data for each inlet and outlet, if available, as indicated in the 

table. If you have more than one inlet to an APCD, provide data for each of the 

inlets. Provide data in the units listed for each row. 

Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal 

HAP's or VOC for organic HAP's. Emission estimates may consist of 

measurements reported in emission test reports or may be calculated using mass 

balances, emission factors, engineering judgement, or other estimation methods. 

Provide the emission estimates as emission factors in units of lb of pollutant 

emitted per ton of product (lb/ton). Provide complete copies of any emission test 

reports or other reports that document measurements. of emissions. Test 

reports and other emission measurement documents should include the following 

information: process identification; location of sampling point; stack diameter, 

temperature, and flow rate; test method, including analytical procedures; number of 

test runs; emission concentration, emission rate, percent oxygen, and percent 

moisture for each test run; process operating rate; type of APCD; and APCD 

operating parameters. However, test reports with incomplete documentation may 

still be useful and shouid also be submitted. 

You do not need to fill out Table 5 for emission points that are covered by an 

emission test report that is included in your submittal. If emission test reports are 

not available, provide calculations that support your emission estimate, 

including the basis for all assumptions in the estimate. Note that emission 

estimates are needed for all HAP's that the facility emits or has the potential to emit. 

(Please refer to the HAP list in Attachment 1.) If the information requested in the 

table is contained in your facility's operating permit, you may reference the 

applicable sections of the permit rather than filling out the table. 

Page 16 of 28 

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C. Using Tables 6A through 6D, please provide design and operating data for each 

APCD associated with all dryers, kilns, and any other brick and structural clay products 

manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of 

APCD's. Use Table 6D for other types of APCD's. When using Table 61), please 

specify the type of control device and 2 to 4 key design or operating parameters for the 

device. Provide data in the units listed for each row. If the information requested in 

Tables 6A through 6D is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the tables. 

Page 19 of 28 

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D. Using Table 7, please provide the following information on current monitoring 

procedures for each of the control devices listed in Tables 6A to 61): parameters 

monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices 

used (e.g., differential pressure transducer, thermocouple), and recordkeeping 

practices (e.g., manually recorded in log book, continuously recorded by electronic data 

acquisition system). Describe briefly other operation and maintenance (O&M) 

procedures for each control device. If the information requested in the table is 

contained in your facility's operating permit, you may reference the applicable sections 

of the permit rather than filling out the table. 

VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing 

A. Please describe all pollution prevention practices (i.e., process modifications, such as 

re-use of discarded or rejected materials, or any practice that prevents or reduces the 

amount of air emissions, or the generation and release of solid waste or wastewater 

associated with the operation of air pollution controls). If the information requested 

here is contained in your facility's operating perrriit, you may reference the applicable 

sections of the permit rather than providing the information below. 

Broken fired ware and unfired reject greenware are added into 

the raw material feed. 

Page 24 of 28 

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VIII. Information on Processes Other Than Brick and Structural C1av Products Manufacturing 

Processes 

A. Using Table 8, - please identify all other processes or operations at this facility that are 

not addressed in Items II through VII above and that are potential sources of HAP 

emissions. Estimate total annual emissions of each HAP emitted by these colocated 

processes. If the information requested in the table is contained in your facility's 

operating permit, you may reference the applicable sections of the permit rather than 

filling out the table. 

Page 27 of 28 

/ 7 /~ 
TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES 

Process/emission source/SIC Code(s) HAP's emitted 

trace metals; 

com : P~., 

SIC 

SIC 

SIC 

SIC 

If the information requested in the table is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the table. 

Page 28 of 28 

/z 
Material Safety Data Sheet 

Substance Identification 

Identity: MANGAIVESE DIOXIDE CAS #: 1313-13-9 

Trade Names: Brickox, GranuSpeck . .. 

Manufacturer: The Pr3nce Manufacturing Company Emergency: Chemtrec 

One Prince Plaza 1-800-424-9300 

Quincy, II. 62301 

217-222-8854 

Components and Contaminants . 

Chemical Name CAS # OSHA PEL ACGIH TLV Percent 

Manganese Compound (as Mn) 7439-96-5 5 mg/m3(C) 5 mg/m3(C) 51-55% Mu 

Iron Oxide 1309-37-1 --- --- 1-5% FeZO3 Silica, Crystalline Quartz (respirabl.e) 14808-60-7 0.1 mg/m3 0.1 mg/m3(TWA) 1-5% Si0 

Aluminum Oxide (non-fibrous) 

(respirable fraction) 1344-28-1 5 mg/m3 15 mg/m3(TWA) 1-7% Al2

03 

Barium Oxide 1304-28-5 --- --- 0.2-2% Ba0 

Physical Data 

Boiling Point: NA Specific Gravity (H20 =1): 5.0 

Vapor Pressure (mm/Hg): NA Melting Point: (Decomposes) 535°C 

Vapor Density (Air =1): NA Evaporation Rate (Butyl Acetate =1): NA 

Solubility in Water: insoluble 

Appearance and Odor: black to brownish black, no odor 

Fire and Explosion Hazard Data 

Flash Point: Not combustible 

Flammabie Limits: LEL NA UEL NA 

Extinguishing Media: Foam, CO , or dry chemical. 

Special Fire Fighting Procedures: In the event of fire, wear full protective clothing and NIOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure 

demand or other positive pressure mode. 

Unusual Fire and explosion hazards: Not combustible, but substance is a strong oxidizer and its heat of reaction with 

reducing agents or combustibles may cause ignition. Increases the f7ammability of any combustible substance. 

Reactivity Data 

Stability: Stable under ordinary conditions of use and storage. 

Conditions to avoid: Do not heat or grind in the presence of easily oxidizable substances or organic 

matter. 

Incompatibility (materials to avoid): Easily oxidizable substances, sulfur, sulfides, phosphides, hydrophosphides. 

chlorates, peroxides, aluminum powder, rubidium acetylide, potassium azide, 

chlorine tritluoride. Reacts with hydrochloric acid to form corrosive chlorine 

gas. 

Hazardous Decomposition or Byproducts: Upon heating it decomposes to form manganese sesquioxide and oxygen which 

facilitates combustion. 

Hazardous Polymerization: Will not occur. 

Manganese Diozide, Page i 

Reviewed October 1994 Unchanged since July 1991 

1~/ 
Health Hazard Data 

Route of Entry: INHAI.ATION: May irritate the respiratory tract. May inerease the incidencc 

of upper respiratory infections (pneumonia). Prolonged exposure to silica dust 

may result in silicosis, a fibrotic lung disease. 

SKIN: May cause irritation. 

INGESTION: May cause abdominal pain and nausea. Manganese dioxid4 

dust is poorly absorbed through the gut. 

Health Hazards (Acute and Chronic): Chronic exposure and inhalation of excessive manganese dust mav cause disorders of the central nervous system. 

Carcinogenicity: NTP: No IARC Monographs: Yes (Silica) 

Signs and Symptoms of Exposure: Early symptoms of manganese toxicity include sluggishness, sleepiness, an,i 

weakness in legs. Symptoms of silicosis indude impaired pulmonary function 

and wheezing. 

Aggravation of Pre-existing Conditions: Persons with impaired respiratory function may be more susceptible to the effect of this substance. 

Emergency and First Aid Procedures: IF INHAI.ED, remove to fresh air and seek medical attention for anv breathinc! 

difficulty. 

IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. 

IN CASE OF EYE CONTACT, flush eyes immediately with water for at least 

15 minutes. Seek medical attention if irritation persists. 

- IF INGESTED, induce vomiting immediately by giving two glasses of water 

and sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

Precautions for Safe Handling and Use 

Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory 

protection. Recover uncontaminated material for use. Vacuum or sweep 

remaining material, keeping dust to a minimum. Isolate wet material from drv 

and store away from combustible materials. 

Waste Disposal Method: Dispose of unreclaimable material in a RCRA-approved waste facility. 

Handling and Storing Precautions: Manganese dioxide is classiSted as an oxidizer and should be stored in a dri 

place away from combustibles and sources of high heat. Protect containers 

from damage and keep closed when not in use. 

Other Precautions: Observe good personal hygiene. Wash after handling. 

Control Measures 

Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or i< 

anticipated. USBM approved schedule 21B respirator or equal is recor,imended. 

Ventilation: A system of local and / or general exhaust is recommended to keep employc: 

exposures below the Airborne Exposure Limits. Loca1 exhaust is generall% 

preferred because it can control the emissions of the contaminant at its 

source, preventing dispersion of it into the general work area. Please refer to 

the ACGIH document, "Industrial Ventilation, A Manual of Recommended 

Practices", most recent edition, for details. 

Protective Gloves: Yes 

Eye Protection: Safety goggles are recommended. 

Other Protective Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonaci 

exposure to skin. 

Work and Hygienic Practices: Observe good personal hygiene. Wash after handling. 

SARA Title III Section 313 Supplier Notification 

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emercenc ~ 

Planning and Community Right-to KnowAct of 1986 and of 40 CFR 372.45: 

Coml2onent 

Manganese Dioxide 

Barium Oadde 

CAS # bv Weight 

1313-13-9 51- 55% Mn 

1304-28-5 0.1 - 1.8% Ba 

This information must be included in all MSDS's that are copied and distributed for this material. 

Manganese Dioxide. Pa;c _ 

Reviewed October 1994 Unchanged since Jul ~ I ,'-: 

J~y 
CLAY 

MATERIAL SAFETY DATA SHEET 

SECTION 1 -: IDENTI' iY 

Name Address 

TXI OPERATIONS, LP 1341 W. MOCKINGBIRD LANE, DALLAS, TEXAS 75247 

Emergency Telephone Number Person Responsible for Preparation Date 

(972) 647-6700 NANCY GARNETI' SEPTEMBER 1996 

Common Name (used on label) Chemical Family 

CLAY SILICATE 

Chemical Name Fonnula 

DOES NOT APPLY A HETEROGENEOUS BLEND OF SILICA, ALUMINA, FERRIC 

Trade Name & Synonyms OXIDE, CALCIUM OXIDE, MAGNESIUM OXIDE AND WATER. 

NONE 

`SECTION 2: -'HAZARDOUS>!INGREDIENTS:; 

Harardous Componeat CAS # % Typical TLV (Units) PEL (Units) 

CIAY 100 

NUISANCE MINERAL DUST: 

FOR CLAY WITH < 1% QUARTZ - RESPIRABLE 5 mg/m' 

FOR CLAY WITH < 1% QUARTZ - TOTAL DUST 10 mg/m' 15 mg/m' 

OUARTZ CONTAINING DUST: 

FOR CLAY WTTH > i% QUARTZ - RESPIRABLE .1 mg/m' 0.1 mg/m' 

FOR CLAY WTfH > 1% QUARTZ - TOTAL DUST 30 mg/m'/% Si0= +2 

PEL: Permiasibla Expaeure Limit eatablished by the Oeoapational Safety and Hea11h Admiaiatration (OSHA). 

TLV: Threshold Limit Vahre established by the Ameriean Confeteace of Goveromental Industrial Hygienists (ACGIID. 

. : SECTTQN T

. 

 - PHYSICAL 'DATA 

Boiling Pofnt Spxific Gravity (Ht0 = 1) Vapor Pressure (mm = Hg) 

> 3000 deg F 2.5 DOES NOT APPLY 

Percwt Volatile by Volume Vapor Density (Air = 1) Evaporation Rate (n=Butyl Acetate) 

0% DOES NOT APPLY DOES NOT APPLY 

Percent Soluble in Water Reactivity in Water 

INSOLUBLE WII,L NOT EVOLVE FIAMMABLE OR TOXIC GASES 

Appearance and Odor 

EARTHY, FINE GRAIlVED POWDER OR AMORPHOUS SOLID. NO ODOR. 

Huardous Material Information Svstem Identitier (HMIS1 

HEALTH = U FLAMMABII.ffY = 0 REACTIVITY = 0 PERSONAL PROTECTION = X 

_ .:... ,. 

SECT. IQN 4:' -..FLRE AND. EXPLO.SLQN DATA: :;... ..: .. . 

Flash Point 

DOES NOT APPLY 

pgkguWiing Media 

DOES NOT APPLY 

Unusual Fire and Explosion Haurds 

NONE 

Special Fire Fighting Pracedures 

NONE 

TXI031 Temporary 

Flammabk Limits in Air (% by Vohume) 

Lower. DOES NOT APPLY UPper. DOES NOT APPLY 

Auto Ignitioa Tempaature 

DOES NOT APPLY 

1,0 
SECTION 5 -..HEALTH INFORMAT.ION 

Signs and Symptoms of Exposure -(1) Acute Ovcrexposure 

INHALATION: EXPOSURE TO A LARGE CONCENTRATIONOF DUST MAY CAUSE IRRITATION. SKIN: NONE. EYE: PARTICLES IN THE EYE MAY CAUSE 

IRRITATION. INGESTION: IlVTESTINAL OBSTRUCTION. 

Signs and Symptoms of Exposure -(2) Chronic Overexposure 

INHALATION: REPEATED EXPOSURE TO LARGE CONCENTRATIONS OF DUST MAY CAUSE PNEUMOCONIOSIS. SYMPTOMS OF PNEUMOCONIOSIS ARE 

PAIN IN THE CHEST, COUGH, DYSPNEA, REDUCED THORACIC EXCURSION, SOMETIMES CYANOSIS, AND FATIGUE AFTER SLIGHT EXERTION. THE 

PNEUMOCONIOSIS MAY TAKE THE FORM OF SILICOSIS IF A HIGH CONCENTRATION OF FREE SILICA IS CONTAINED IN THE CLAY. SKIN: NONE. 

EYE: NO DATA AVAII,ABLE. 1NGESTION: NO DATA AVAIIABLE. 

Medical Conditions Generally Aggravated by Exposure 

RESPIRATORY DISORDERS OR DISEASES. 

ChenticallComponeat Listed as Carcinogen NTP IARC OSHA 

QUARTZ YES YES NO 

Other Exposure Limits 

QUARTZ: 30 MILLION PARTICLES PER CUBIC FOOT - ACGIH WORKPLACE EXPOSURE. 

Emecgency & First Aide Procedures for Indicated Routes of Entry 

EYE CONTACT: IMMEDIATELY FLUSH EXPOSED AREA WITH WATER OR NORMAL SALINE FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. 

SKIN CONTACT: WASH AREA WPCH WATER. 

INHALATION: REMOVE FROM EXPOSURE. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN AND 

CONSULT A PHYSICIAN IMMEDIATELY. 

INGESTION: TREAT SYMPTOMATICALLY AND SUPPORTNELY. GET MEDICAL ATTENTION. 

SECTION 6 - REACTIVITY DATA 

Stability Conditions to Avoid 

STABLE HANDLING PROCEDURES WHICH MAY GENERATE DUST. 

Incompatibility (Materials to Avoid) 

MOLTEN LITHIUM ATTACKS SQ,ICATES. 

Hazardous Decomposition or Combustion Products 

DOES NOT APPLY 

Hazsrdous Polymerizatioa 

WII.L NOT OCCUR 

SECTION 7= SP.ILIs .:OR LEAK PROCED:LTRES: 

Steps to be Talcen in Case Material is Leaked or Spilled 

WEAR NIOSH/MSHA APPROVED ABt PURD?YING RESPIRATOR W1TH A PARTICULATE FILTER TO PREVENT DUST EXPOSURE. WEAR PROTECPIVE 

GOGGLES TO PROTEGT AGAINST EYE IRRITATION. PICK UP SOLID MATERIAL W1TH A MQQASUM OF DUSTiNG. 

Waste Disposal Method 

GENERALLY NOT RESTRICTED. CONSULT APPROPRIATE FEDERAL, STATE, AND LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL 

PROCEDURES. 

. ::. ; . SECTION 8: PERSONAL PROTECTIQN:TNFORMA ~ION`!; 

Respiratory Protution 

PROVIDE GENERAL VENTII.ATION AND LOCAL EXHAUST. NIOSH APPROVED DUST FILTER RESPIRATOR SHOULD BE USED IN DUSTY CONDII'IONS. 

Ventilation 

SUFFICIIIVT TO MAIIVTAIN AIRBORNE CONCENTRATIONS BELOW THE THRESHOLD LIIu1Tf VALUE (TLV). 

Protective Glovea Eye Protection 

NOT REQUIItED, THOUGH RECOMMENDED FOR LONG TERM EXPOSURE. CLOSE FITTTNG SAFETY GOGGLES 

Other Prafective Cladting or F.quipment 

WEAR PROTECCIVE CLOTHIIVG, SUCH AS LONG SLEEVE SHIRT, LONG PANTS EXTFlVDING OVER THE TOPS OF WORK SHOES, TO PREVENT SKIN 

CONTACT. ANEYEWASH SHOULD BE AVAILABLE NEAR WORK AREA. PERSONAL PROTP.CITVE CLOTHIIVO AND USE OF EQUIPMENT MUST BE IN 

ACCORDANCE WITH 29 CFR 1910.132. 

_. 

` SEC~*ZU~1 `9~ SPECIAL PRECAUTIONS 

Precautioaa to be Talcea in Handling & Storing 

WEAR APPROPRIATE SAFETY EQUIPbffiVT AND CLOTHIIdG TO PREVENT INHALATION, SKIN, AND EYE CONTACT. 

Other Precautioos 

NONE 

TXI031 Temporary 

I~ k 
d 49 

HARCROS 

MATERIAL SAFETY DATA SHEET 

wwwrs 

Harcros PIgments Inc. Producx: SYNTTiETIC / NATURAL 

11 Fxecutive Dr., Suite 1 IRON 03QDE BLENDS 

Fairview Heights, IL 62208 MSDS No. PIGMENT / HPI-024 

Revision: Revision 2 

Date: August 1994 

11.4ZARD MATERL4L IDENTIFICATION SYSTEM ' 

Health Haard 1 - Slight 

Flammability Hazard 0 - Minimal 

Reactivity Harard 0 - Minimal 

Personal Protection E- Glasses, Gloves, Dust Resp 

SECT70N I. MATERfAL IDENT7FICA770N 

'IYade/Material Name: 

Desctigtion • 

Other Designations• 

Chemical Name• 

MANUFACTURER• 

SYNTHETIC / NATURAL IRON OXIDE BLENDS 

Iron Oxide - - - 

NR-4284. NR-4686 

Fe:03 

Harcros Pigments Inc. PHONE: 618-271-4700 

11 Executive Dr., Suite 1 E- St. Louis Plant 

Fairview Heights, IL 62208 

ti, 

.- --~~ 

SECTION II. INGREDIENTS AND- 1YAZARDS 

INGREDIENT NAME: CAS NUMBER: PERCENT EXPOSURE LIMITS 

Nat'I Iron Oxide 1332-37-2 30-50' ACGIH TLV S mg/M3 TWA 

(Iron Oxide Fume as Fe) 

Syn. Iron Oxide 1332-37-2 40-60' OSHA STEL: 10 ppm 

(Iron Oxide Fume as Fe) 

Barium Sulfate 772743-7 5-15' ACGIH TLY 10 mg/M 3 TWA total dust 

OSHA STEL: 10 ppm 

Silica - Quartz 14808-60-7 0.1-1.5' ACGIH TZ.V 0.1 mglM 3TWA Respirable Dust 

OSHA PEL: 10 mg/M 3 TWA Respirable Dust 

"Application Specific -7n 

.r- - 

(Ingredients and Ha7ards continued on next page) 

. ~ .-. -~ ~ E;-•

, 

HPI-024 Page 1 of 4 

~ 
(Ingredients and Hazards continued from previous page) 

SARA TITLE III: Section 313 Supplier Notification 

Ihis product does not contain touc chetnicals subject to the reporting requirements of Section 313 of the 

Emergency Planning and Community Right-'Ib-Know Act of the 1986 and of 40 CFTt 372: 

SECTION Ill. PHYSICAL/CHEMICAL CNARACTERISTICS 

Annearance and Odor-. Reddish Brown Powder, No Odor 

Solubility ir. Water (96): Insoluble 

Speciflc Graviry (H:0=1): - _- --49-5.1 

SECTION IV. FIRE AND EXPLOSION DATA ~ 

F1ash Point (method): Non-tlammable Limits: L.EI.96: N/A UEL96: N/A 

Exting_uishing Media: As appropriate for surrounding combusd'bles. Does not burn or support 

combustion. No fire or ezplosion hazard. 

Unusual Fre or Eaplosion Hazards: None 

Special Frefightinit Praxdures: Frefightets should wear self-contained bteathing apparatus. 

SECTION Y. REACTIVlTY DATA 

MM 

Material is stable - Harardous polvmerization will not occur 

Chemical incompatibilities: None known 

Hazardaus DecomRosition Products: Will not oa.vr 

HPI-024 Page 2 of 4 

ov ! 
SECTION VI. ' HEALTH 11AZ,4RD DATA 

Summary of Health Risks 

and Svmptoms of EaMure: Skin contact may cause mechanical irritation due to the abrasion. Eye 

contact will result in no specific effects other than general particulate 

irritation in the eye. Not absorbed by the body. Excessive exposure abov+e 

the TLY can give mild pulmonary irritation. 

Principal Routes of Entrv: Inhalation, ingestion, sidn and eye eontacL 

Accute Effects: Inhalation of the dust may cause mechanical irriation to the respiratory 

tract. Skf n and eye eontact may cause a mechanicral abrasion irritation. 

Chronic Health Effects(sl: Long term overexposure to silicra causes silicosis, a form of pulmonary 

fibrosis. Continued exposure to silicra can lead to cardiopulmonary 

impairment. 

Emergency and Frst Aid Procedures: 

Eye Contact: Flush thoroughly with plenty of water for at least 15 minutes. Get medical 

help if irritation persists. 

Skin Contact: Wash skin with mild soap and water. 

Inhalation: - - Remove to fresh air. Get medicral help for any breathing difHculty. 

Ingestion: _ If conscious, give large quantities of water to inducx vomiting. Get medical 

attention. ' 

Crystalline silica which may be present in quantities greater than 0.1% has been reviewed by IARG IARC 

found limited evidencx for carcinogenicity of crystalline silica in humans and sufficient evidence in 

experimental animals. 

SECTION VII. . PRECAUTIONS FOR SAFE HANDLING, USE OR DISPOSAL 

Spill / Leak procedures: Those involved in clean-up of spills should use respiratory protection for 

airborne dust. Vacuum or seoop up spilled material for recovery or 

disposal, avoiding dusting conditions and using good venilation. Wetting the 

spill with a water spray may help to keep the airborne dust levels down. 

Waste manatement / disposal: Refer to any local, State or Federal regulations for specific disposal 

information. Pursuant to 40 CF'R part 261 of the Resource Conservation 

& Recovery Act (RCRA) regulations currently in effect, discarded Iron 

Oxide would not be classified as a hazardous waste. 

Precautions to be taken 

in handlin¢ and storin¢: For transportation emergencies, call CHEMTREG 24 hour information 

service, (800) 424-9300. 

HP1-024 Page 3 of 4 / S-'-7 
SEC?70N YIII. SPECIAL PROTEC?'ION INFORMATION : 

Personal protective equipment : 

Goggles: Safety glasses with side shields or dust tight goggles. 

Gloves: L,eather or rubber gloves. 

_ 

Respirator. If exposure limits are exoceded, an appropriate NIOSH approved dust 

respirator should be used. 

Workplace Considerations: 

Ventilation: Provide adequate exhaust ventilation to meet TLV requiremeats in - the 

workplacx. An exhaust filter system may be required to avoid environmental 

' i = contamination. 

Safety Stations: An eye wash station should be available to the area of use. 

Other. Good industrial hygiene practioe requires that employee exposure be 

- -- maintained below the recommended TLV This is preferably achieved through 

, the provision of adequate venu'lation where necessary. Where dust cannot be 

- controlled in this way, personal respiratory protection should be employod. 

SECTION M SPECL4L PRECA UTIONS 

DOT Class• - Not regulated 

Preparedhevised by: R. E. Rader August 1994 

The infamatioa pteseated herein is believed to be aocvcate attd was obtained from sourca bdieved to be tr.liabk. tloweAa. the 

infotwatlon is pravided without atry t'epKSentation or wamnty, acptessed or implle4 with respea to its accvrary or completa>em 1t is tDe 

uaers' trspoosibiRty to detamine the suitabiGty of this pcodua aod the oelkvance o[ this information for their ux Hanros Pigmeats Iaa 

does not as,wme tiabitity tesultiag from the use, handlin=, stoca;e, and dispoaal of this product. 

HPI-024 Page 4 of 4 ~~~ 
Material Safety Data Sheet 

May be used to Compiy with 

OSHA's Hazard Communication Standard. 

29 CFR 1910.1200. Standard must be 

consulted 'or spepfic requirements. 

U.S. Department of Labor 

Occupational Safety and Health Administration 

(Non-Mandatory Form) 

Form Approved 

OMB No. 1218-0072 

/ 

IDENl771f (As Used on Lapel ano tJSt)

t 

Mota: 8lank spacas a ~s nor Dennrtred ll any mam rs not apWrcaGb. or no 

Bottom Ash ir/onmaaan is ava,rabw, rrre space musr oe mar*ad to mmcav mar. 

Section I 

Manutaaurer's En ergency Telephprie Numoer 

214 944-7462 

Addmrea 

..;.... . 

(NumOer. Sbset Ciry. Statb. anO 7JP Code) Telephone NumOer for Informatan 

400 N. Olive Street 214 944-7462 

Date Preparetl 

P.O. Box 81 6/24/88 ^ 

Dallas, Texas 75201 

Section 11 — Harardous Ingredients/[dentity Information ( / v 

Hatardous Components (Specifie Chemical Idenfity, Common Name(s)) OSHA PEL ACGIH TLV 4/0000na» 

Crystalline Silica (Quartz) CAS/114808-60-7: 14 

Respirable Fraction 0.63mQ/m 3 0.1 mg/m3 

Total Dust 1.88mg/m3 - 

Crystalline Silica (Cristobalite) CAS#14464-46-1: 2 

Resyirable Fraction 1.25mg/m3 0.05ma/m3 

Total Dust 3.75mQ/m3 

Aluminum CAS#7429-90-5 - 10.0 mg/m3 <10 

Calcium CAS#1305-78-8 5.0 mg/m3 2.0 mg/m3 (Ca0) <7 

Iron CAS#1309-37-1 10.0 mg/m3 5.0 mg/m3 (Fe0 Fume) . <6 

Magnesium CAS#1309-48-4 15.0 mg/m3 10.0 mg/m3(Mg0 Fume) <2 

Section )It — PhysicaUCttemical Characteristics 

8oding ParK SPeafic GravitY (H20 - 1) 

NA NA 

VaPor Presswe (nun H4) μe" Pant 

NA 

Vapa Osraty (AIR t) Eraporatia+ Raa 

NA I (8utyl Acetate a 1► NA 

Saua* in wao.r 

Insoluble in water. pH 3 5-6 

Appearance and Odar 

Granular. 

Section IV — Fre and Explos ion Hazard Data 

Fiaah Poutt (MethoC Used) I FlarttmabN Ci NA I LEL I UEL 

NA 

Exarxguisrung Meoia 

No special media required. 

Speaa! Firn F,qftng Proceoures 

None. 

Unuaual Fre and Exptos+on Hazards 

None. 

(ReoroCuce Iocalty)* Composition may vary. NA = Not Available;Not Applicable. OSHA 174, ~V~S 
Sectlon V — Reacttvity Data 

staodity UnstabN I CondRfona oo Avoid 

Sw" I X None known. 

Incompatibiuty (Matena/s to Aroid) 

None known. 

Hazardow oeoompoesbon or eyproauct: 

None known. 

Hazaroous 

potyr~lon 

May Occiu CondiOOro to AMoid 

Wil Nd OCCtr 

X None known. 

Section VI — Heafth Hazard Data 

Routs(s) af Erm~r, lr>haterion? Skin? inqesoon ? 

YES YES YES 

Heatth Hax>R78 (AtLO and ClrorrC) 

Acute: Eye, skin, and resDiratorv tract irritation. 

Chronic: Pneumoconiosis. 

CWcZno9W"carO N ~ YE~? pSt~A ReguWted?

NO 

Silica is listed in IARC monographs, volume 42. 

Sigra and Sympom ot EAxxR" 

Skin or eye irritation; respiratory tract irritation. 

Medical Contlitions 

GeneratN AgWavaxed bY Enoo" 

NA 

Em

~

.y and Fr~e Aid ProcearesFor e ~e contact, flu h e yes wit water, see me ica attention. 

or skin contact. wash e fected area. i ~ redness or irritation develovs, seek 

attention. r'or inhaiatlon contact, ex 

Sertlon VII — Precautlom for 3afe HandNng and Use 

Sbps tD 8o Taksn in Case AAasenal Is Releas ~d oa SpiMd 

Fresh bottom ash may be hot. Avoid stepping into areas of fresh bottom ash spillage. 

Handle bottom ash spillage to avoid creating airborne dust. Use wet methods or 

vacuuming to clean up spills. 

Waam oispoQW Mett+od 

No special procedures required. Handle as an inert bulk material. Material may 

be disDosed of in sanitary landfills. 

P+scautions to Ba Takan in Har%lirg and Storv ~g 

_ Fresh bottom ash >nav be hot. Avoid orolontted skin contact. Handle bottom ash to 

avoid creating airborne dust. 

othsr Precauoona 

NA 

Section VIII — Control Meaaurcs 

Resar&ImY P+%x*c= (,Vec+Y TYwl Half-mask or fullface air-purifying respirator equippe wit 

filters approved for protection a ainst pneumoconiosis producing dusts. 

Venniaoon Loai Ext+am o keep dust levels below PEL, gpocw j 

open conveyine s stems. NA 

Mectwtc;W (GaxrhTo keep dust levels belowOa>K 

PEL. Recommended for confined areas. NA 

Pnx°ctiw Gov" E>e Pf~ Safety glasses with side shields, `?one normally required. I Cover ¢oe2les. 

Ottw P+vtsctrvw Clottung or Equuprnant 

Vone normally reauired. 

worwF+ygwuc Fracacaa 

Practice good oersonal hygiene. 

Rs" 2 1 M1_691-329/47773 

) 1 ~ 
IDENT/TV 

BARIUM CARBONATE, PRECIPITATED AND CALCINED (ALL FORMS AND GRADES) 

AQUA-FLO@, MICRO-FLO*, TYPE FF, PHOTO GRADE, TYPE TV, AND TYPE CFF, TYPE S. 

k

: , : ....: r ~ ;, ,;;; ~ 

~ ~ ^ ~ V 

ti . 

a Be 

MATERIAL SAFETY DATA SHEET 

TRADE NAME 

INCLUDES 

1 

MANUFACTURER'S CHEMICAL PRODUCTS CORPORATION NAME 

ADDRESS P.O. BOX 449, CARTERSVILLE, GEORGIA 30120 

PREPARED BY: JERRY A. COOK, TECHNICAL DIRECTOR 

REGULAR TELEPHONE NO. Day 404/382-2144 Night 404/382-2212 

EMERGENCY TELEPHONE NO. CHEMTREC 1-800-424-9300 

11 HAZARDOUS INGREDIENTS 

COMPONENT CAS NO. % HAZARD OSHA 

PEL 

ACGIH 

TLV 

OTHER LIMITS 

RECOMMENDED 

BARIUM CARBONATE 513-77-9 ca 99% TOXIC 0.5 mc~/m~ 

of Bar um 

0.5 m/m~ 

of Bar um NONE 

I11 PHYSICAL DATA 

BOILING POINT, 760 MM HG Not Applicable MELTING POINT- Decomposes to Barium 

Oxide ca 1000° C 

PECIFIC GRAVITY (H~ 0=1) 4.4 VAPOR PRESSURE Not Applicable 

VAPOR DENSITY (AIR=1 ) Not Applicable SOLUBILITY IN WATER

% BY WEIGHT 0.002°k (20°C) 

APPEARANCE AND ODOR White powder or granules. 

Odorless 

EVAPORATION RATE 

(BUTYL ACETATE=1) Not Applicable 

IV FIRE AND EXPLOSION DATA 

FLASH POINT AUTOIGNITION 

(TEST METHOD) NON-FLAMMABLE TEMPERATURE NON-FLAMMABLE 

FLAMMABLE LIMITS IN AIR, % BY VOL. LOWER UPPER 

NONE NONE NONE 

EXTINGUISHING 

MEDIA NO FIRE HAZARD 

SPECIAL FIRE Avoid contact with acid — large quantities of carbon dioxide will be evolved. 

FIGHTING Barium carbonate is toxic if ingested. 

PROCEDURES Avoid inhalation of dust. 

UNUSUAL FIRE 

AND EXPLOSION NONE 

HAZARDS 

While the information and recommendations contained in this publication are believed to be accurate forthis material when 

not in combination with others, Chemical Products Corporation makes no warranty or guarantee as to such information and 

recommendations. Proper use of the information contained herein and of the product are the responsibility of the user. 

Pag.; 1 of 3 Pages

1 

 lA1 
CHEMICAL PRODUCTS CORPORATION BARIUM CARBONATE 

V REACTIVITY DATA 

ZONDITIONS CONTRIBUTING TO INSTABILITY 

Very high temperature (ca 1000° C) causes decomposition to barium oxide and carbon dioxide. 

INCOMPATIBILITY 

Acids will decompose barium carbonate to other barium salts with liberation of carbon dioxide. 

The reaciion may be violenf. 

HAZARDOUS DECOMPOSITION PRODUCTS 

Barium carbonate may be decomposed to form other barium salts. AII water and acid soluble barium salts are toxic. 

CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERZATION 

None 

VI HEALTH HAZARD INFORMATION 

ROUTES OF EXPOSURE HAZARD CLASSIFICATION BASIS FOR CLASSIFICATION i SOURCE ~ 

INHALATION Moderately Toxic Inhalation - Rat NIOSH 

24 Hours Registry of Toxic Effects ~ TCLo-1150 mg/m' of Chemical Substances. 

SKIN CONTACT Believed to be no hazard None None 

SKIN ABSORPTION Believed to be no hazard None None 

EYE CONTACT Believed to be irritant None None 

INGESTION TOXIC Oral - Human NIOSH 

LDLo - 57 mg/kg Registry of Toxic Effects 

Oral - Rat of Chemical Substances 

LDso - 418 mg/kg 

SYMPTOMB EXCESSIVE INGESTION MAY CAUSE EXCESSIVE SALIVATION, VOMITING, 

OF SEVERE ABDOMINAL PAIN, VIOLENT PURGING WITH WATERY AND BLOODY STOOLS, 

OVEREXPOSURE SLOW AND OFTEN IRREGULAR PULSE, MUSCLE TWITCHINGS PROGRESSING TO 

CONVULSIONS AND/OR PARALYSIS, DILATED PUPILS, CONFUSION, POSSIBLY DEATH. 

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: NONE 

CARCINOGENICITY: NTP - NO IARC MONOGRAPHS - NO OSHA REGULATED - NO 

EMERGENCY AND FIRST A/D PROCEDURES 

EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER: 

ALWAYS SEEK MEDICAL ATTENTION. 

SKIN: WASH WITH SOAP AND WATER. 

INHALATION: FLUSH MOUTH AND NASAL PASSAGES WITH WATER AS MUCH AS POSSIBLE. 

INGESTION: ADMINISTER ONE TABLESPOON OF EPSOM SALTS (MAGNESIUM SULFATE) OR 

GLAUBER'S SALT (SODIUM SULFATE) DISSOLVED IN WATER. 

IF VICTIM IS NOT VOMITING, INDUCE VOMITING BY GIVING SYRUP OF IPECAC OR 

BY STICKING FINGER DOWN THROAT. 

NOTES ITYPOKALEMIA IS OFTEN OBSERVED; POTASSIUM SHOULD BE ADMINISTERED — 

TO LARGE DOSES MAY BE REQUIRED. 

PHYSICIAN IN ACUTELY POISONED DOGS, POTASSIUM INFUSIONS CORRECTED ALL OF THE 

CLINICAL SIGNS OF BARIUM POISONING EXCEPT THE HYPERTENSION. 

I 

Page 2 of 3 Pages 

/ ~1i 
CHEMICAL PRODUCTS CORPORATION BAR I U M CAR BONATE 

VII PRECAUTIONS FOR SAFE HANDLING AND USE 

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED 

Try to keep material dry and away from acid. 

Sweep or scoop up spilled material. 

Dispose of in an approved hazardous waste landfill or mix with excess sulfate to make material non-hazardous. 

NEUTRALIZING CHEMICALS 

Can be made non-toxic by forming insoluble barium sulfate. 

React with sulfuric acid (caution - reaction can be vioient). 

WASTE DISPOSAL METHOD 

Waste containing more than 0.2% soluble barium is hazardous. 

Can be rendered non-hazardous by reaction with excess sulfate to form insoluble barium sulfate. 

Observe all federal, state, and local laws. 

PRECAUTIONARY STATEMENTS 

1. Reaction with acid can release large quantities of carbon dioxide which could lead to suffocation in a confined area. 

Use adequate ventilation. 

2. A small amount of toxic hydrogen sulfide gas may be liberated on acidification (as an impurity). 

Use adequate ventilation. 

OTHER HANDLING AND STORAGE REQUIREMENTS 

Store awav from acids. 

VI11 CONTROL MEASURES 

VENTILATION REQUIREMENTS 

Provide sufficient ventilation to remove dust. 

SPECIFIC PERSONAL PROTECTIVE EQUIPMENT 

RESPIRATORY 

Use NIOSH approved dust mask if excessive dust is present. 

EYE 

Safety glasses 

GLOVES 

General purpose 

OTHER CLOTHING AND EOUIPMENT 

Cover exposed skin areas. Provide epsom salts as part of the first aid supplies. 

Page 3 of 3 Pages 

/ 5~ ~ 
~s 

PIEDMONT MINERALS COMPANY, INCORPORATED 

Subsidiary of RESCO Products. Inc. 

P. O. BOX 7247 / GREENSBORO, N. C. 27407-0247 , TELEPHONE 919-292-0949 

November 15, 1985 

TRADE NAME 

Pyrofrac A-320, B-320, C-320 

Pyrofrac A-720 

Pyrofrac A-202 

Pyrophyl A-100, B-100, C-100, D-100 

Pyrophyl A-140, B-140 

Pyroph.yl A-202, B-202 

Pyrotrol W-200 

Pyrotrol W-325 

Pyrotrol R-065 

Pyrotrol R-200 

A1ka trol 213 

Alkatrol 226 

Seriphyl A, B, C, D, G 

FORINULA 

Andal usi te Al203 ' Si 02 

Pyrophyllite Al203 - 4Si02 • H20 

Quartz Si02 

Sericite (K20, Na0) - 3Al203 - 6Si02 - H20 

PYROTROL;ALKATROL; PYROTROL'ALKATROL: PYROTROL, ALKATROLi PYROTROLiALKATROL 
U.S. UtNAFi I MLN I UF- LAt3UFH 

Occupational Safety and Health Administration 

MATERIAL SAFETY DATA SHEET 

rOrm raDPrOveO 

OMB No. 44-R1367 

PY ~- 

I Required under USDL Safety and Health Regulations for Ship Repairing, (11-85) I 

Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) 

SECTION I 

MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. 

Piedmont Minerals Company, Incorporated (919) 292-0949 

ADDRESS (Number, Street, City, Stvte, and ZIPCode) 

3514 West Wendover Avenue Greensboro North Carolina 27407-0247 

CHEMICAL NAME AND SYNONYMS tiSer cl te 

~ silica), 

TRADE NAME AND SYNONYMS 

Andalusite, Pyrophyllite, Quar L z See Attachment 

CHE M ICA ~ FAMILY 

Alumi-num - Silicates 

FORMULA 

See Attachment 

SECTION II HAZARDOUS INGREDIENTS 

PAINTS, PRESERVATIVES, & SOLVENTS % Units ALLOYS AND METALLIC COATINGS % (Un ts) 

PIGMENTS N A BASE METAL N/A 

CATALYST • [(T/A ALLOYS N/A 

VEHICLE N/A METALLIC COATINGS N/A 

S OLVENTS N/A 

FILLER METAL 

PLUS COATING OR CORE FLUX N A 

ADDITIVES N/A OTHERS N/A 

OTHERS N/A 

HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % 

TLV 

(Units) 

SECTION III - PHYSICAL DATA 

BOILING POINT ( ° F.) XIA SPECIFIC GRAVITY (H2O=1) 2,$5 

VAPOR PRESSURE (mm Hg.) N A 

PERCENT, VOLATILE 

BY VOLUME (%) N/ A 

VAPOR DENSITV (AIR=1) N A 

EVAPORATION RATE 

( =1) N/A 

SOLUBILITY IN WATER Insoj ublk 

APPEARANCE AND ODOR White to off-white, granular to powder, no odor 

SECTION IV - FIRE AND EXPLOSION HAZARD DATA 

FLASH POINT (Method used) 

N A 

FLAMMABLE LIMITS 

NIA 

Lel Uel 

EXTINGUISHING MEDIA 

N/A 

SPECIAL FIRE FtGHTING PROCEDURES 

UNUSUAL FIRE AND EXPLOSION HA2ARDS , 

PAGE (1) (Continued on reverse side) Form OSHA-20 

Rw. 41aY 72 

f ~.~ 
I SECTION V- HEALTH HAZARD DATA 

THRESHOLD LIMIT VALUE 

0.53 MG/M 3 

EFFECTS OF OVEREXPOSURE 

Inhalation of dust over a prolonged period of time noy cause 

injury to 1un s. Airborne dust inay be irritating to e es. 

EMERGENCY AND FIRST AID PROCEDURES 

NIA 

SECTION VI - REACTIVITY DATA 

STABILITY UNSTABLE CONDITIONS TO AVOID N/A 

STABLE X 

INCOMPATABILITY (,ilaterials to avoid) . N A 

HAZARDOUS DECOMPOSITION PRODUCTS 

N/A 

HAZARDOUS 

POLYMERIZATION 

MAY OCCUR 

CONOITIONS TO AVOID 

NIIA 

WILL NOT OCCUR X 

SECTION VII - SPILL OR LEAK PROCEDURES 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED 

Clean up bg recommended dustless methods water or vacuum . 

DO NOT EXCEED TLV A.S SHOWN ABOVE. 

WASTE DISPOSAL METHOD 

Disposal sha11 be in accordance with federal, state and 1oca1 

re ulations. 

SECTION VIII - SPECIAL PROTECTION INFORMATION 

RESPIRATORY PROTECTION S 2C7 Y t 2 When TLV is excee ed;A ~IOSH/MSHA approved respirators are required. 

VENTILATION LOCAL EXHAUST 

Sufficient to keep dust below TLV 

SPECIAL 

None 

MECHANICAL (Generclf OTHER 

Bag tqpe dust collector recommended None 

PROTECTIVE GLOVES EYE PROTECTION 

None re uired Recomrrtended 

OTHER PROTECTIVE EQUIPMENT 

None required 

SECTION IX - SPECIAL PRECAUTIONS 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING 

Use dustless s stems for handlin , stora e, and clean up not to exceed TLV 

shown above. 

OTHER PRECAUTIONS 

Practice good housekeeping and utilize ade uate ventilation and dust 

collection equipment. Use respirators when TLV is exceeded. 

GPO 934-110 

PAGE (2) Form OSHA-20 

Rev. May 72 

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