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# ~ ® 1341 West Mockingbird Lane • Dallas, Texas 75247 • 972.647.6700 • www.txi.com



# May 29, 1998 Mr. Bill Neuffer, Minerals and Inorganic Chemicals Group Office Of Air Quality Planning And Standards 

# U.S.E.P.A. Research Triangle Park, NC 27711 Re: Athens Brick Company Information Collection Requests Dear Mr. Neuffer: TXI on behalf of its subsidiary, Athens Brick Company, submits the enclosed information collection requests, (ICR's), for each of its three brick manufacturing operations located in Mooringsport, Louisiana; Athens, Texas; and Mineral Wells, Texas. Enclosure 2 was completed for each facility. Material Safety Data Sheets are included and may be common to each of the three facilities. The stack test data applies only to the specified facility. Please call me directly at (972)647-3932 if you have any questions concerning the ICR's or otherwise. 

# S' ely,

Robert B. Cain Senior Environmental Engineer



# 9

# Enclosur ~ 

# 2
^~ 

### NOT SUBJeCT Tu i;lc Of I; 4 

### SECTION 3507, PAPEdiiORK REDUCTIOrd AC! Of 19d0. II i I 

# INFORNiATION REQUEST FOR BRICK AND STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS I. Instructions Please return the completed information request to: Bruce C. Jordan, Director Attn: Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at (919) 541=5435. 

# This information request should be completed for each facility that manufactures brick and structural clay products, including facilities that are not major sources. Information is requested for all proces.ses at your plant that emit hazardous air pollutants (HAP's), including those processes that are not associated with brick and structural clay products manufacturing. Sections II through VII request information specific to brick and structural clay products manufacturing, and Section VIII requests information on emissions of HAP's from other processes located at the facility. Processes that may emit HAP's include those processes that use or handle any materials that contain a HAP compound, all processes with elevated temperatures, and all other processes in which HAP compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this information request. Attachment 2 provides background information on the requirements of the Clean Air Act and explains how the information requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations and acronyms used in this information request. Several tables are provided throughout the information request for your convenience in answering the questions. An example response is given (shaded first column or row) in each table. If additional space is needed to respond, please make copies of applicable pages. If necessary, please make copies of this information request for additional facilities. No additional emission testing or monitoring is required to respond to this request. II. General Facilitv Information A. Name of company Athens Brick Conipany Name of facility Athens Brick - Caddo Plant

Page 1 of 28



# ~

# Facility address: No. and street 8469 Barnette Road
City 1`boringsport State LA Zip 71060 Latitude and longitude coordinates of plant: 324000, 935652 Standard Industrial Classification (SIC) Code(s) of brick and structural clay products manufacturing operations 3251 Dun and Bradstreet No. 041083627 Total No. of employees for company 2350 for facility 25 (If facility is a foreign subsidiary or if company has foreign subsidiaries, include number of employees not based in the U.S.). Please complete the following shift information for the facility: Shift No. of employees Hours per shift Days per year 1 23 8-10 345 2 1 8 365 3 1 8 365 B. Respondent name Rbbert B. Cain Respondenttitle Senior Environmental Engineer Respondent address (if different from above) and telephone number: No. and street 1341 W. Mockingbird Lane
City Dal-las State TX Zip 75247 Telephone No. 972/647-3932 Name and telephone number of technical contact person (if different from above) Name Telephone No. (__) M. Information on Operatine Permits and Applicable Federal Emission Standards A. Please provide copies of relevant parts of all operating permits and permit applications for your facility. Relevant parts include the sections that providespecific information and data on: processes that emit HAP's; the use of HAPcontaining substances; emission levels for HAP and surrogate pollutants (i.e., VOC Page 2 of 28 j

# for organic HAP's and PM for metal and other particulate HAP's); emission control device design and operation; monitoring and operation and maintenance (O&M) procedures for control devices; and generation and releases of other media such as wastewater and solid waste that are associated with the operation of air pollution controls for brick and structural clay products manufacturing processes. If the operating pernzit or application contains the same information requested in any part of this questionnaire, you may respond to the requested information by referencing the page or section of the permit/application to avoid duplication. If you reference your permit or application, you must supplement your response with all of the additional information requested in this questionnaire that is not included in the permit or permit application. If you prefer, you may submit the requested information from :

~ 

# Air permit/application on a 3- 1 /z inch diskette. B. If any source or emission uni: :d this facility is subject to a New Source Performance Standard or other Federal emission standard, please identify the source and applicable standard. Examples of applicable NSPS include 40 CFR 60, Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in Mineral lndustries.

W. Brick and Structural Clay Products Production and Raw Material Consumption Information A. Please provide the 1996 production rates and the current production capacity for each type of brick and structural clay product manufactured (e.g., structural brick, clay sewer pipes, structural clay tile, etc.). Note that production data should be provided in units of tons per year (tons/yr).
Product 1996 production (tons) Production capacity (tons/yr) Face brick 30,000 38,000

Page 3 of 28 

# v

# B. Please provide the type and amount of each raw material and body additive used in 1996 for manufacturing brick and structural clay products at your facility. Examples include clays, shale, and any additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade name. If the information requested is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. Raw materiaVbody additive 

# I Amount used in 1996 (tons/yr) Clay 30,000 

# Vermiculite 1 Manganese dioxi.de 2 Pyrotrol, pyrophyllite 0.25

C. If available, please provide a copy of the MSDS's for the raw materials and additives listed above. D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above.

Page 4 of 28 

# 5

# E. Using Table 1, please provide information on the consumption and HAP composition of all glazes and colorants that contain HAP's or HAP precursors and that your facility applies to brick and structural clay products. Indicate whether the coatings are glazes or colorants. Also indicate the type of product that the coatings are applied to and the total weight of coatings used in 1996. If the glazes or colorants are formulated at your facility indicate so and provide the production capacity. List each ingredient of the glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient used in 1996. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. F. In the space below, please indicate any glazes or colorants used by your facility that do not contain HAP's and are substitutes for HAP-containing glazes or colorants used by your industry. Indicate which HAP-containing materials the non-HAP glazes or colorants replace. Describe any limitations on the use of those substitute glazes or colorants. 

# None

G. If your facility colors brick and structural clay products by flashing, please indicate the types of substances used to flash the products and the amounts of those substances used in 1996. Substance Amount used in 1996 Units (specifv)

H. If available, please provide a copy of the MSDS's for the glazes and colorants used by your facility. If your facility prepares its own glaze, please provide any available MSDS's for the glaze ingredients.

Page 5 of 28



# ~

# TABLE l. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND COLORANTS

Type (e.g., glaze, colorant) EXAMPLE: 

# Gtaze Type of product glazed or gtrufpindAbar : colored 

# 1996 consumption (tons/yr) , ~ 9 

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# If additional space is required, please make copies of this page. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. Page 6 of 28

~

# V. Description of Brick and Structural Clay Product ManufacturingProcesses A. Please provide a simple process flow diagram for each brick and structural clay product manufacturing process line. An example process flow diagram is provided in Figure 1. A diagram of the plant layout with all processes and emission points clearly labeled is also acceptable. 

# Assign a unique identification number (ID No.) for each process that has associated emissions (e.g., TK-1 for tunnel kiln no. l) and each emission point. Please identify all emission points, including those that do not emit HAP's. For emission points that are vented to an air pollution control device (APCD), assign an ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof vent (e.g., RV-1). 

# Use these same ID Nos. throughout the rest of the information request for any responses that pertain to any process or emission point.

Page 7 of 28 

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# B. Using Tables 2A and 2B, please provide current production rates, production capacities, and related information for each type of equipment used in brick and structural clay product manufacturing. In Table 2A, provide the requested information for only those sources that are known or expected to emit HAP's. In Table 213, provide the requested information for all thermal processing, such as drying and firing sources. For combustion sources that use different fuels, Table 2B should be completed for each type of fuel. For example, if a kiln typically is fired with gas, but periodically is fired with oil, one column in Table 2B should be completed for the kiln when fired with gas, and another column should be completed for the same kiln when fired with oil. Provide the data in the units listed for each row.

Page 9 of 28 

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# C. 

# Using Table 3, please provide information on procedures used to monitor the process operating rate for each of the pieces of equipment and HAP emission sources listed in Tables 2A and 2B. Use the same HAP emission source types and equipment ID numbers you listed in Tables 2A to 2B. Indicate whether you 

# monitor process rate or not. Provide a 

# summary of process rate monitoring procedures that describes how process rate is measured for the particular piece of equipment. Include 

# where the rate is monitored (i.e., rate of material fed, rate of material discharged, or material production rate), the units used to measure process rate (e.g, lb/hr or pieces/hr), and how the process data is 

# recorded, i.e., manually, automatically (e.g., computer - printout or stored to disk, or not at all). If you monitor process rate at both the feed and discharge ends of the equipment, indicate so. Indicate the 

# type of monitor, equipment, or instrument used to measure process operating rate. Indicate the 

# monitoring frequency or how often process rate measurements are made. If instruments are used to measure process throughput, indicate in the 

# monitor accuracy column the accuracy of the instrument. The monitor accuracy could be listed in terms of a percentage of the throughput (t 

# 1 percent), mass per unit time (t21b/hr), number of pieces per unit time (t 10 pieces/hr), or other appropriate units. Indicate the 

# frequency that the monitor is calibrated. Provide data in the units listed for each row.

Page 12 of 28 / ✓ ?"~.
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# /Y

# VI. Identification of Brick and Structural Clay Product Manufacturing Emission Points A. Use the process flow diagrams developed for your facility and Table 4 to provide the following information for each HAP emission source at your facility. • Define HAP emission source type in terms of equipment, such as dryers, kilns, etc. As in the process flow diagram, you may group multiple pieces of similar equipment. • Use the same equipment ID numbers indicated on the process flow diagram(s). • If the emission source vents inside a building or to outside ambient air without first passing through a control device, place a check mark in the uncontrolled column. • If the emission source vents inside a building or to outside ambient air after passing through a fabric fllter, dry injection fabric filter, or scrubber, place the APCD ID number(s) in the column corresponding to the APCD type. • If the emission source vents through a control device type not listed in Table 4, indicate the control device type in the other control column and place the APCD ID number in the appropriate cell. • In the emission test data column, place a"yes" or "no" in the appropriate cell to indicate whether the specific source has been tested for any pollutants, including any HAP's, VOC, PM, or opacity.

Page 14 of 28

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# Page 15 of 28

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# B. Using Table 5, please provide information on stack parameters and emission estimates for each emission point at your facility that is known or expected to emit HAP's. Provide information for all APCD's, including those that exhaust inside the building. Include data for each inlet and outlet, if available, as indicated in the table. If you have more than one inlet to an APCD, provide data for each of the inlets. Provide data in the units listed for each row. Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal HAP's or VOC for organic HAP's. Emission estimates may consist of measurements reported in emission test reports or may be calculated using mass balances, emission factors, engineering judgement, or other estimation methods. Provide the emission estimates as emission factors in units of lb of pollutant emitted per ton of product (lb/ton). 

# Provide complete copies of any emission test reports or other reports that document measurements of emissions. Test reports and other emission measurement documents should include the following information: process identification; location of sampling point; stack diameter, temperature, and flow rate; test method, including analytical procedures; number of test runs; emission concentration, emission rate, percent oxygen, and percent moisture for each test run; process operating rate; type of APCD; and APCD operating parameters. However, test reports with incomplete documentation may still be useful and should also be submitted. You do not need to fill out Table 5 for emission points that are covered by an emission test report that is included in your submittal. 

# If emission test reports are not available, provide calculations that support your emission estimate, including the basis for all assumptions in the estimate. Note that emission estimates are needed for all HAP's that the facility emits or has the potential to emit. (Please refer to the HAP list in Attachment 1.) If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 16 of 28 

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# C. Using Tables 6A through 6D, please provide design and operating data for each APCD associated with all dryers, kilns, and any other brick and structural clay products manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of APCD's. Use Table 6D for other types of APCD's. When using Table 61), please specify the type of control device and 2 to 4 key design or operating parameters for the device. Provide data in the units listed for each row. If the information requested in Tables 6A through 6D is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the tables.

Page 19 of 28 

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# D. Using Table 7, please provide the following information on current monitoring procedures for each of the control devices listed in Tables 6A to 6D: parameters monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices used (e.g., differential pressure transducer, thermocouple), and recordkeeping practices (e.g., manually recorded in log book, continuously recorded by electronic data acquisition system). Describe briefly other operation and maintenance (O&M) procedures for each control device. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table. VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing A. Please descritie all pollution prevention practices (i.e., process modifications, such as re-use of discarded or rejected materials, or any practice that prevents or reduces the amount of air emissions, or the generation and release of solid waste or wastewater associated with the operation of air pollution controls). If the information requested here is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. 

# Broken fired ware and unfired reject greenware are added into the raw material feed.

Page 24 of 28

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Page 25 of 28

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# VIII. Information on Processes Other Than Brick and Structural Clay Products Manufacturing

Processes 

# A. Using Table 8, please identify all other processes or operations at this facility that are not addressed in Items 

# II through VII above and that are potential sources of HAP emissions. Estimate total annual emissions of each HAP emitted by these colocated processes. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 27 of 28 

# aP'

# TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES



# SIC

SIC

SIC

SIC If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.
Page 28 of 28

o~ - ~

# Enclosure 2 NOT SUBJECT TO i;lc RECJ!RE\1ENTS OF 11 SECTION 3507, PAPERiIORK REDUCTIOri ACT OF 1980. 1' 

# INFORMATION REQUEST FOR BRICK AND STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS I. Instructions Please return the completed information request to: Bruce C. Jordan, Director Attn: .Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at (919) 541-5435. 

# This information request should be completed for each facility that manufactures brick and structural clay products, including facilities that are not major sources. Information is requested for all processes at your plant that emit hazardous air pollutants (HAP's), including those processes that are not associated with brick and structural clay products manufacturing. Sections II through VII request information specific to brick and structural clay products manufacturing, and Section VIII requests information on emissions of HAP's from other processes located at the facility. Processes that may emit HAP's include those processes that use or handle any materials that contain a HAP compound, all processes with elevated temperatures, and all other processes in which HAP compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this information request. Attachment 2 provides background information on the requirements of the Clean Air Act and explains how the information requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations and acronyms used in this information request. Several tables are provided throughout the information request for your convenience in answering the questions. An example response is given (shaded first column or row) in each table. If additional space is needed to respond, please make copies of applicable pages. If necessary, please make copies of this information request for additional facilities. No additional emission testing or monitoring is required to respond to this request. U. General Facility Information A. Name of company Athens Brick Corpany Name of facility At.hens Brick Plant

Page 1 of 28



# ~~ ~

# Facility address: No. and street 200 Athens Brick Road
City Athens State TX Zip 75751 Latitude and longitude coordinates of plant: 321215, 954922 Standard Industrial Classification (SIC) Code(s) of brick and structural clay products manufacturing operations 3251 Dun and Bradstreet No. 041083403 Total No. of employees for company 2350 for facility 49 (If facility is a foreign subsidiary or if company has foreign subsidiaries, include number of employees not based in the U.S.). Please complete the following shift information for the facility: Shift No. of employees Hours per shift Days per year 1 46 8-10 345 2 2 8 365 3 1 8 365 B. Respondent name R°bert B. Cain Respondenttitle Senior Environmental Engineer Respondent address (if different from above) and telephone number: No. and street 1341 W. Nbckingbird Lane
City Da11as State 'I'X Zip 75247 Telephone No. (--) 

# 972/647-3932 Name and telephone number of technical contact person (if different from above) Name Telephone No. (__) III. Information on Operating Permits and Applicable Federal Emission Standards A. Please provide copies of relevant parts of all operating permits and permit applications for your facility. Relevant parts include the sections that providespecific information and data on: processes that emit HAP's; the use of HAPcontaining substances; emission levels for HAP and surrogate pollutants (i.e., VOC Page 2 of 28 

# 31

# for organic HAP's and PM for metal and other particulate HAP's); emission control device design and operation; monitoring and operation and maintenance (O&M) procedures for control devices; and generation and releases of other media such as wastewater and solid waste that are associated with the operation of air pollution controls for brick and structural clay products manufacturing processes. 

# If the operating permit or application contains the same information requested in any part of this questionnaire, you may respond to the requested information by referencing the page or section of the permit/application to avoid dupGcation. If you reference your permit or application, you must supplement your response with all of the additional information requested in this questionnaire that is not included in the permit or permit application. If you prefer, you may submit the requested information from your penmit/application on a 3-'/x inch diskette. B. If any source or emission unit at this facility is subject to a New Source Performance Standard or other Federal emission standard, please identify the source and applicable standard. Examples of applicable NSPS include 40 CFR 60, Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in Mineral Industries.

IV. Brick and Structural Clay Products Production and Raw Material Consumption Information A. Please provide the 1996 production rates and the current production capacity for each type of brick and structural clay product manufactured (e.g., structural brick, clay sewer pipes, structural clay tile, etc.). Note that production data should be provided in units of tons per year (tons/yr).
Product 

# 1996 production (tons) Production capacity (tons/yr) Face brick 57,000 65,000 

# estimated

Page 3 of 28 

# 3z

# B. Please provide the type and amount of each raw material and body additive used in 1996 for manufacturing brick and structural clay products at your facility. Examples include clays, shale, and any additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade name. If the information requested is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. Raw materiaVbody additive Amount used in 1996 (tons/yr) Clay 90,000 Bottom ash 2,150 BariLUn carbonate 55 

# Iron oxide 1 Sand 30 P7anganese dioxi.de 1.5 

# Grog - broken bric,ks and non-glazed 18,000 fired clay ceram.ics



# C. If available, please provide a copy of the MSDS's for the raw materials and additives listed above. D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above.

Page 4 of 28

-~ 

# O

# E. Using Table 1, please provide information on the consumption and HAP composition of all glazes and colorants that contain HAP's or HAP precursors and that your facility applies to brick and structural clay products. Indicate whether the coatings are glazes or colorants. Also indicate the type of product that the coatings are applied to and the total weight of coatings used in 1996. If the glazes or colorants are formulated at your facility indicate so and provide the production capacity. List each ingredient of the glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient used in 1996. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. F. In the space below, please indicate any glazes or colorants used by your facility that do not contain HAP's and are substitutes for HAP-containing glazes or colorants used by your industry. Indicate which HAP-containing materials the non-HAP glazes or colorants replace. Describe any limitations on the use of those substitute glazes or colorants. None

G. If your facility colors brick and structural clay products by flashing, please indicate the types of substances used to flash the products and the amounts of those substances used in 1996. Substance Amount used in 1996 Units (specify)

H. If available, please provide a copy of the MSDS's for the glazes and colorants used by your facility. If your facility prepares its own glaze, please provide any available MSDS's for the glaze ingredients.

Page 5 of 28 

# 3V

# TA.BLE 1. CONSUMPTION AND HAP COMPOSTTION OF GLAZES AND COLORANTS

Type (e.g., glaze, colorant) EXAMpLEt Type of product glazed or StrtietnraC tite: >:;'; colored 1996 consumption (tons/yr)
F 

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# Ingredient usage, tons

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# If additional space is required, please make copies of this page. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. Page 6 of 28

~

# V. Descril2tion of Brick and Structural CIaYProduct Manufacturing Processes A. Please provide a simple process flow diagram for each brick and structural clay product manufacturing process line. An example process flow diagram is provided in Figure 1. A diagram of the plant layout with all processes and emission points clearly labeled is also acceptable. 

# Assign a unique identification number (ID No.) for each process that has associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. Please identify all emission points, including those that do not emit HAP's. For emission points that are vented to an air pollution control device (APCD), assign an ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof vent (e.g., 

# RV-1). Use these same ID Nos. throughout the rest of the information request for any responses that pertain to any process or emission point.

Page 7 of 28 

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# B. Using Tables 2A 

# and 2B, please provide current production rates, production capacities, and related information for each type of equipment used in brick and structural clay product manufacturing. In Table 2A, provide the requested information for only those sources that are known or expected to emit HAP's. In Table 2B, provide the requested information for all thermal processing, such as drying and firing sources. For combustion sources that use different fuels, Table 2B should be completed for each type of fuel. For example, if a kiln typically is fired with gas, but periodically is fired with oil, one column in Table 2B should be completed for the kiln when fired with gas, and another column should be completed for the same kiln when fired with oil. Provide the data in the units listed for each row.

Page 9 of 28 

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# C. Using Table 3, please provide information on procedures used to monitor the process operating rate for each of the pieces of equipment and HAP emission sources listed in Tables 2A and 2B. Use the same HAP emission source types and equipment ID numbers you listed in Tables 2A to 2B. Indicate whether you monitor process rate or not. Provide a sununary of process rate monitoring procedures that describes how process rate is measured for the particular piece of equipment. Include where the rate is monitored (i.e., rate of material fed, rate of material discharged, or material production rate), the units used to measure process rate (e.g, lb/hr or pieces/hr), and how the process data is recorded, i.e., manually, automatically (e.g., computer - printout or stored to disk, or not at all). If you monitor process rate at both the feed and discharge ends of the equipment, indicate so. Indicate the type of monitor, equipment, or instrument used to measure process operating rate. Indicate the monitoring frequency or how often process rate measurements are made. If instruments are used to measure process throughput, indicate in the monitor accuracy column the accuracy of the instrument. The monitor accuracy could be listed in terms of a percentage of the throughput (± 1 percent), mass per unit time (t21b/hr), number of pieces per unit time (t 10 pieces/hr), or other appropriate units. Indicate the frequency that the monitor is calibrated. Provide data in the units listed for each row.

Page 12 of 28



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# V2-

# VI. Identification of Brick and Structural Clay Product Manufacturing Emission Points A. Use the process flow diagrams developed for your facility and Table 4 to provide the following information for each HAP emission source at your facility. • Define 

# HAP emission source type in terms of equipment, such as dryers, kilns, etc. As in the process flow diagram, you may group multiple pieces of similar equipment. • Use the same 

# equipment ID numbers indicated on the process flow diagram(s). • If the emission source vents inside a building or to outside ambient air without first passing through a control device, place a check mark in the 

# uncontrolled column. • If the emission source vents inside a building or to outside ambient air after passing through a 

# fabric filter, dry injection fabric filter, or scrubber, place the APCD 

# ID number(s) in the column corresponding to the APCD type. • If the emission source vents through a control device type not listed in Table 4, indicate the control device type in the 

# other control column and place the APCD 

# ID number in the appropriate cell. • In the 

# emission test data column, place a"yes" or "no" in the appropriate cell to indicate whether the specific source has been tested for My pollutants, including any HAP's, VOC, PM, or opacity.

Page 14 of 28 

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# Page 15 of 28

4717

# B. Using Table 5, please provide information on stack parameters and emission estimates for each emission point at your facility that is known or expected to emit HAP's. Provide information for all APCD's, including those that exhaust inside the building. Include data for each inlet and outlet, if available, as indicated in the table. If you have more than one inlet to an APCD, provide data for each of the inlets. Provide data in the units listed for each row. Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal HAP's or VOC for organic HAP's. Emission estimates may consist of measurements reported in emission test reports or may be calculated using mass balances, emission factors, engineering judgement, or other estimation methods. Provide the emission estimates as emission factors in units of lb of pollutant emitted per ton of product (lb/ton). Provide complete copies of any emission test reports or other reports that document measurements of emissions. Test reports and other emission measurement documents should include the following information: process identification; location of sampling point; stack diameter, temperature, and flow rate; test method, including analytical procedures; number of test runs; emission concentration, emission rate, percent oxygen, and percent moisture for each test run; process operating rate; type of APCD; and APCD operating parameters. However, test reports with incomplete documentation may still be useful and should also be submitted. You do not need to fill out Table 5 for emission points that are covered by an emission test report that is included in your submittal. If emission test reports are not available, provide calculations that support your emission estimate, including the basis for all assumptions in the estimate. Note that emission estimates are needed for all HAP's that the facility emits or has the potential to emit. (Please refer to the HAP list in Attachment 1.) If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 16 of 28
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# Page 18 of 28 

# y7

# C. Using Tables 6A through 6D, please provide design and operating data for each APCD associated with all dryers, kilns, and any other brick and structural clay products manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of APCD's. Use Table 6D for other types of APCD's. When using Table 61), please specify the type of control device and 2 to 4 key design or operating parameters for the device. Provide data in the units listed for each row. If the information requested in Tables 6A through 6D is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the tables.

Page 19 of 28
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# D. Using Table 7, please provide the following information on current monitoring procedures for each of the control devices listed in Tables 6A to 6D: parameters monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices used (e.g., differential pressure transducer, thermocouple), and recordkeeping practices (e.g., manually recorded in log book, continuously recorded by electronic data acquisition system). Describe briefly other operation and maintenance (O&M) procedures for each control device. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table. VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing A. Please describe all pollution prevention practices (i.e., process modifications, such as re-use of discarded or rejected materials, or any practice that prevents or reduces the amount of air emissions, or the generation and release of solid waste or wastewater associated with the operation of air pollution controls). If the information requested here is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. 

# Broken fired ware and unfired reject greenware are added into the raw material feed.

Page 24 of 28 

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# VIII. Information on Processes Other Than Brick and Structural Clay Products Manufacturing

Processes 

# A. Using Table 8, please identify all other processes or operations at this facility that are not addressed in Items II through VII above and that are potential sources of HAP emissions. Estimate total annual emissions of each HAP emitted by these colocated processes. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 27 of 28 

# J-6

# TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES

SIC

SIC

SIC

SIC If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.
Page 28 of 28

5 

# 7

# Exhaust Emission Sampling Athens Brick Company Athens, TX December 13, 1995 

# Armstrong Environmental, Inc. Project W-1752-95

Report Prepared For: Mr. Robeit Cain Texas Industries, Inc. 1341 W. Mockingbird Lane Dallas, TX 75247-6913

Report Prepared December 15, 1995 By: Armstrong Errvironmental, Inc. 7715 Sovereign Row Dallas, Texas 75247 (214)631-0021

,s7Y

# TABLE OF CONTENTS Page

I. Introduction 1 II. Summary 2 - 4 III. Procedures 5 - 6 IV. Appendices A. Calculation Summaries 7- 12 B. Continuous Emission Monitor Record'mgs 13 - 36 C. Analytical Summaries 37 - 56 D. Field Data Sheets 57 - 62 E. Gas Standard Certifications 63 - 71 F. Equipment Cahbrations 72 - 87



# ~~

# I. INTRODUCTION

A series oftests were performed on the Kiln exhaust and Dryer exhaust at the Athens Brick Company facility in Athens, TX December 13, 1995. The purpose of this test series was to determine the exhaust emission rates of particulate, carbon monoxide, nitrogen oxides, VOC, sulfur dioxide, hydrogen chloiide and hydrogen fluoride in terms of Ibs/hr. Testing followed procedures detalled in Title 40: Code of Federal Regulations (40:CFR). Sampling was performed by Joe Barrera, Danny Barrera, Cody Jefferson and Tom Armstrong of Aimstrong Environmental, Inc. using two Apex Method 5 Sampling Trains, a TECO 51 continuous FID analyzer, a TECO Mode110 cont.inuous Nox analyzer, a Hon'ba VIA continuous S02 analyzer, and a FUJI NDIR continuous CO analyzer. Sampling on the kiln was perfonned 8:28 am to 3:05 pm, with a 3 hour delay between Runs 1 and 2 due to a power-outage. Sampling on the dryer was performed 3:40 pm to 7:14 pm. Submitted by: 

# Armstrong Environmental, lnc.



# ~ Tom Armstrong 

# President



# .s

# Source/Run #



# Kiln Ezhaust 1

~ M 

# Particulate, lbs/hr 2.629 I Carbon Monoxide, lbs/hr 3.38 Nitrogen Oxides, lbs/hr 1.29 Sulfur Dioxide, Ibs/hr 8.85 VOC as C3H8, Ibs/hr 0.654 Hydrogen Chloride, lbs/hr 1.507 Hydrogen Fluoride, IbsJhr 5.875 3 AveraQe 2.027 3.369 2.675 2.95 3.16 3.16 1.47 1.26 1.34 7.61 9.59 8.68 0.520 0.505 0.560 1.367 1.809 1.561 5.019 4.858 5.251 

# II. SUMNfARY A series of tests were performed on the Ki}n exhaust and Dryer exhaust at the Athens Brick Company facility in Athens, TX December 13, 1995. Sampling was performed following procedures detai7ed in Title 40: Code of Federal Regulations. Results of this test series are summariz 

# ea .:

~ 

# :'able 1- 2. Results indicate the following emission ra:

Dryer Ezhaust Particulate, Ibs/hr 2.514 1.372 1.806 1.897 Carbon Monoxide, lbslhr 0.395 1.068 0.851 0.771 Nrtrogen Oxides, Ibs/hr 0.061 0.032 0.248 0.114 Sulfur Dioxide, lbs/hr 0.377 1.376 1.925 1.226 VOC as C3H8, lbs/hr 2.016 3.487 2.691 2.731 Hydrogen Chloride, lbs/hr 0.117 0.138 0.024 0.093 Hydrogen Fluoride, lbs/hr 1.936 2.094 0.475 1.501
It should be noted that between Runs #1 and #2 and plant-wide power outage occurred, causing the kiln to shut down. Sampling resumed once power was restored and the kiln was back up to temperature.

2 &;,/

### SUMMARY OF EMISSIONS TEST DATA Table 

## : 1 Plant 

## : Athens Brick Company, Athens, TX Location 

## : Kiln Exhaust Operator 

## : D. Barrera, J. Barrera, C. Jefferson Test Date 

## : 13-Dec-95 Repetition: 1 STACK GAS Temperature, F 378.6 Velocity, fps 71.53 Volume Flow, acfm 20742.9

scfm 12031.0 scfh 721859 Moisture, 

## % 7.10% CO2, 

## % 2.50 02, 

## % 17.50 SAMPLE Start Time, hrs:min 8:26 AM Fnish Time, hrs:min 9:30 AM Sample Volume, scf 50.476 Isokinetic Ratio, 

## % 101.1315 PARTICULATE Front Half Sample Weight, mg 75.30 Concentration, gr/scf 0.023019 Emissions, Ibs/hr 2.374505 Back Half Sample Weight, mg 8.10 Concentration, gr/scf 0.002476 Emissions, Ibs/hr 0.255425 Total Particulate, Ibs/hr 2.62993 CARBON MONOXIDE Concentration, ppm 64.39 Emissions, Ibs/hr 3.378645 NITROGEN OXIDE AS NO2 Concentration, ppm 14.98 Emissions, Ibs/hr 1'.291326 VOC AS C31-18 Concentration, ppm WB 7.37 Concentration, ppm DB 7.933563 Emissions, Ibs/hr 0.654165 SULFUR DIOXIDE Concentration, ppm 73.85 Emissions, Ibs/hr 8.857204 HYDROGEN FLUORIDES Sample Weight, mg 186.32 Concentration, ppm 156.7622 Emissions, Ibs/hr 5.875401 HYDROGEN CHLORIDE Sample Weight, mg 47.80 Concentration, ppm 22.03764 Emissions, Ibs/hr 1.507385 2 3

402.7 70.69 20500.0 11067.0 664023 11.03% 3.00 16.00 407.1 69.30 20094.2 11245.9 674752 7.28% 2.50 17.00

12:45 PM 1:50 PM 47.521 103.5045 2:00 PM 3:05 PM 46.480 99.6274

61.80 0.020067 1.904136 98.50 0.032699 3.152987

4.00 0.001299 0.123245 2.027381

61.15 2.951556 6.75 0.002241 0.216068 3.369055

64.48 3.162575

18.53 1.469365 15.69 1.264266

6.1 6.856478 0.520056 6.08 6.557181 0.505391

68.94 7.605851 85.57 9.593107

162.92 145.5987 5.019772

44.37 21.72749 1.367096 

# 3 151.75 138.6522 4.857521

56.52 28.29681 1.809207 

# (02,

### 2 3

106.1 105.6 32.40 33.07 23329.1 23810.6 20360.1 20220.4 1221605 1213224 5.45 

## % 8.07% 0.00 0.00 21.00 21.00

4:57 PM 6:11 PM 6:00 PM 7:14 PM



## . 33.485 34.213 98.43176 101.2682

13.90 7.80 0.006405 0.003518 1.118168 0.60989

3.15 15.30 0.001452 0.0069 0.253398 1.196323 1.371565 1.806214

12.03 9.65 1.068239 0.851021

0.22 1.71 0.032094 0.247747

23.63 17.85 24.9919 19.41679 3.487359 2.690822

6.78 9.55 1.3761 14 1.925033

26.04 6.07 33.02619 7.534615 2.094754 0.47462

1.72 0.31 1.195317 0.211529 0.138363 0.024317 

# 4 

# &3 SUMMARY OF EMISSIONS TEST DATA Table 

## : 2 Plant 

## : Athens Brick Company, Athens, TX Location 

## : Dryer Exhaust Operator 

## : D. Barrera, J. Barrera, C. Jefferson Test Date 

## : 13-Dec-95 Repetition 

## : 1 STACK GAS Temperature, F 106.4 Velocity, fps 33.55 Volume Flow, acfm 24158.0

scfm 20655.0 scfh 1239303 Moisture, 

## % 7.31 

## % CO2, 

## % 0.00 02, 

## % 21.00 SAMPLE Start Time, hrs:min 3:40 PM Finish Time, hrs:min 4:45 PM Sample Volume, scf 33.702 Isokinetic Ratio, 

## % 97.65585 PARTICULATE Front Half Sample Weight, mg 15.70 Concentration, gr/scf 0.007188 Emissions, Ibs/hr 1.273007 Back Half Sample Weight, mg 15.30 Concentration, gr/scf 0.007005 Emissions, Ibs/hr 1.240573 Total Particulate, Ibs/hr 2.51358 CARBON MONOXIDE Concentration, ppm 4.39 Emissions, Ibs/hr 0.39547 NITROGEN OXIDE AS NO2 Concentration, ppm 0.41 Emissions, Ibs/hr 0.060678 VOC AS C3H8 Concentration, ppm WB 13.2 Concentration, ppm 14.24163 Emissions, Ibs/hr 2.016059 SULFUR DIOXIDE Concentration, ppm 1.83 Ernissions, Ibs/hr 0.37681 HYDROGEN FLUORIDE Sample Weight, mg 23.87 Concentration, ppm 30.07893 Emissions, Ibs/hr 1.935457 HYDROGEN CHLORIDE Sample Weight, mg 1.44 Concentration, ppm 0.994282 Ernissions, Ibs/hr 0.11676

# III. PROCEDURES

The procedure for emissions sampling followed USEPA test methods as detailed in Title 40: Code of Federal Regulations. The following methods were used: Method Title 1 Sample and Velocity Traverses for Stationary Sources 2 Determination of Stack Gas Velocity and Vohunetric Flow Rate (Type S

Pitot Tube) 3 Gas Analysis for CO2, 02, Excess Air and Dry Molecalar Weight 4 Determination of Moisture Content in Stack Gases 5 Determination of Particulate Emissions from Stationary Sources 6C Determination of Sulfur Dioxide Emissions from Stationary Sources

(Instrumental Analyzer Procedure) 7E Determination of Nitrogen Oxides Emissions from Stationary Sources

(Instramental Analyzer Proceduie) 10 Determination of Carbon Monoxide Emissions from Stationary Sources 25A Determination of Total Gaseous Organic Concentration Using a Flame

Ionization Analyzer 26A Determination of Halogens and Hydrogen Halides Emissions from

Stationary Sources 02 and CO2 were determined using Fyrite Analyzers. Sampling was performed on the 25" X 29" kiln exhaust for 2.5 minutes at each of 24 points, 6 points per 4 traverses, making a total run duration of 60 minutes. Sampling was performed on the 36" X 48" dryer exhaust for 2.5 minutes at each of 24 points, 4 points per 6 traverses, making a total run duration of 60 minutes. Sampling was performed using a teflon lined heated sample probe with H20 in the first and second impingers, 0.1 NaOH in the third, the fourth impinger empty and the fifth 200 grms of silica geL Particulate sample includes `Tront-half' (probe wash and filter) and "back-half' (impinger solution residue). Hcl and HF were analyzed in the $rst and second impinger by IC/HPLC. Nox was determined using a ThermoEnvironmental Mode110 continuous Nox analyzer cah'brated with 50.8 ppm and 32.2 ppm EPA Protocol NO in N2 standards.

# CO was detennined using a Fuji NDIR continuous CO analyzer cahbrated with 398, 249

and 95 ppm CO in N2 certified standards. VOC was determmed using a TECO Mode151 continuous FID analyzer cahbrated with 91.6 ppm, 49.3 ppm and 31.1 ppm C3H8 in N2 EPA Protocol l gas standards. S02 was detennined using a Honba VIA 10 continuous S02 analyzer cahbrated with 451 ppm and 225 ppm S02 in N2 gas standards. A heated teflon sample line was used xo convey the sample from the stack to the analyzers. All analyzers were spanned from the front of the sample line using tedla.r gas bags, and zeroed with nitrogen.

i 

# 6 ~~

# APPENDIX A



# & (°

## EMSSION TEST SUIVMRY

PLANT : 

### Athens Brick Comparry, Athens, TX DATE : 

### 13-0ec-95 PLACE : 

### Dryer Etiaust RUN+k : 

### 1 TEST DURATION (MINUTES) : 

### 60 LIQUID COLLECTED (mis) : 

### 56.5 NOmE DIAMETER (INCH.) : 

### 0.2476 PARTICULATE WEIGHT (Frorrt half mp) 15.7 METER COEFFICIENT (Y) : 

### 0.99183 PARTICULATE WEIGHT (Baok haH mp) 15.3 PITOT COEFFICIENT (Cp) : 

### 0.84 STATIC PRESSURE (In. H20) : 

### 0.25 GAS METER VOL(Cu.Ft) : 

### 35.648 PERCENT CO2 0 BAROMETRIC PRESSURE : 

### 29.59 PERCENT 02 21 PERCENT CO 0 FOR CIRCULAR STACK FOR RECTANGULAR STACK STACK DIAMETER pneh): 0 STACK LENGTHQnchs) : 

### 48 STACK AREA (Sq.Ft) : 

### 0 STACKWIDTHQnchs) : 

### 36 NOZaE AREA (feet): 0.000334 STACK AREA (Sq.Ft) : 

### 12 ENTER THE STACK AREA SHOWN ABOVE: 12 FLOWS SAMPLED VOLUME (STD. CU .FT.): 33.7019 VOLUME OF WATER VAPOR (STD. CU .FT.): 2.6595 FRACTIONAL MOISTURE CONTENT (%): 0.0731

DRY BASE: 79.0000 MOLECULAR WT. OF STACK Gy4S (DRY BASE): 28.8400 MOLECULAR WT. OF STACK GAS (WET BASE): 28.0472 STACK PRESSURE Qndf Hp): 29.6084 STACK GAS VELOCITY (1t/sec.): 33.5528 ACTUAL STACK GAS FLOW RATE (ACFM): 24157.9876 STANDARD STACK GAS FLOW RATE (SCFH): 12393026 PARTICULATE FRONT HALF PARTICULATE CONCENTRATION (GRJSCF): 0.0072 PARTICULATE CONCENTRATION (LBS/SCF): 1.03E-06 PARTICULATE EMISSION (LBS(HR): 1.2730 BACK HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0070 PARTICULATE CONCENTRATION (LBS/SCF): 1.00E-06 PARTICULATE EMISSION (LBS/HR): 1.2406 ISOKINETIC RATIO (%): 97.6558

POINTS STACK T. DELTA P QUAR D. DELTA H METER T. METER T.

deg F INLET OUTLFT 1 106 0.37 0.608276 1.35 84 83 2 106 0.46 ' 

### 0.678233 1.70 86 83 3 106 0.57 0.754983 2.10 90 83 4 106 0.49 0.7 1.80 91 84 5 106 0.43 0.655744 1.60 93 83 6 106 0.39 0.6245 1.40 93 63 7 106 0.42 0.648074 1.50 94 84 8 106 0.55 0.74162 2.00 95 84 9 106 0.37 0.608276 1.40 96 85 10 107 0.30 0.547723 1.10 95 85 11 107 0.35 0.591608 1.30 95 85 12 107 0.52 0.72111 1.90 95 86 13 107 0.45 0.67082 1.70 95 86 14 107 0.32 0.565685 1.20 95 86 15 107 0.30 0.547723 1.10 95 86 16 107 0.40 0.632456 1.50 95 86 17 107 0.34 0.583095 1.20 95 86 18 107 0.28 0.52915 1.00 95 87 19 107 0.11 0.331662 0.40 95 87 20 107 0.17 0.412311 0.62 93 87 21 107 0.19 0.43589 0.70 94 87 22 106 0.09 0.3 0.33 93 87 23 105 0.07 0.264575 0.33 94 87 METER T. 24 105 0.18 0.424264 0.66 93 87 AVERAGE 106.41667 0.5657 1.2454 93.2917 85.2917 89.2917

### EMSSION TEST SUNMARY

PLANT : Athens &ick Comparry, Athens, TX DATE : 13-0eo-95 PLACE : Dryer E.*aust 

### RUNk : 2 TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 41 NOmE DIAMETER (INCH.) : 0.2476 PARTICULATE WEIGHT (Frart half mp) 13.9 METER COEFFICIENT (Y) : 0.99183 PARTICULATE WEIGHT (Back haH mp) 3.15 PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE pn H20) : 0.26 GAS METER VOL(Cu.Ft) : 35.298 PERCENT CO2 0 BAROMETRIC PRESSURE : 29.59 PERCENT 02 21 PERCENT CO 0 FOR CIRCULAR STACK FOR RECTANGULAR STACK STACK D64METER pneh): 0 STACK LENGTHpnehes) : STACK AREA (Sq.Ft) : 0 STACKWIDTHpnehes) : NOZaE AREA (feet): 0.000334 STACK AREA (Sq.Ft) : 0 ENTER THE STACK AREA SHOWN ABOVE: 12 

### FLOWS SAMPLED VOLUME (STD. CU .FT.): 33.4848 VOLUME OF WATER VAPOR (STD. CU .FT.): 1.9299 FRACTIONAL MOISTURE CONTENT (46): 0.0545

DRY BASE: 79.0000 MOLECULAR WT. OF STACK GAS (DRY BASE): 28.8400 MOLECULAR WT. OF STACK GAS (WET BASE): 28.2493 STACK PRESSURE Qrieh HO): 29.6091 STACK GAS VELOCITY (lt/sec.): 324015 ACTUAL STACK GJ1S FLOW RATE (ACFM): 23329.09 STANDARD STACK GAS FLOW RATE (SCFH): 1221605.49 PARTICULATE FRONT HALF PARTICULATE CONCENTRATION (GRJSCF): 0.0064 PARTICULATE CONCENTRATION (LBS/SCF): 9.15E-07 PARTICULATE EMISSION (L8S/HR): 1.1182 BACK HALF PARTICULATE CONCENTRATION (GRJSCF): 0.0015 PARTICULATE CONCENTRATION (LBS/SCF): 2.07E-07 PARTICULATE EMISSION (LBS/HR): 0.2534 ISOKINETIC RATIO (°.6): 98.4318

POINTS STACK T. DELTA P QUAR D. DELTA H METER T. METER T.

dep F INLET OUTLET 1 106 0.32 0.565685 1.20 86 86 2 106 0.47 0.685565 1.70 85 84 3 106 0.56 0.748331 2.00 89 83 4 106 0.49 0.7 1.80 91 83 5 106 0.41 0.640312 1.50 92 83 6 106 0.37 0.608276 1.40 92 83 7 107 0.39 0.6245 1.40 92 82 8 107 0.54 0.734847 2.00 92 82 9 106 0.40 0.632456 1.50 92 82 10 106 0.31 0.556776 1.10 94 82 11 106 0.33 0.574456 120 94 82 12 106 0.40 0.632456 1.50 95 83 13 106 0.37 0.608276 1.40 95 83 14 106 0.33 0.574456 1.20 94 83 15 106 0.30 0.547723 1.10 95 83 16 106 0.38 0.616441 1.40 94 83 17 106 0.32 0.565685 1.20 94 84 18 106 0.27 0.519615 1.00 94 83 19 106 0.11 0.331662 0.40 94 83 20 106 0.20 0.447214 0.73 92 83 21 106 0.14 0.374166 0.51 90 83 

### 22 106 0.12 0.34641 0.44 89 83 23 106 0.08 0.282843 0.30 88 83 METER T. 24 106 0.06 0.244949 0.27 87 83 AVERAGE 106.08333 0.5485 1.1771 91.6667 83.0000 87.3333



# 8 ~C~

### EMSSIOM TEST SUMIMRY

PLANT : Athem &Ick Comparry, Afhem, TX DATE : 13-0ec-95 PLACE : Dryar Eshsust RUN# : 3 TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 63.8 NOZbE DU4METER (INCH.) : 0.2476 PARTICULATE WEIGHT (Frorrt hsH mp) 7.8 METER COEFFICIENT (1r) : 0.99183 PARTICULATE WEIGHT (Back hdf mp) 15.3 PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (In. H20) : 0.22 GAS METER VOL(Cu.Ft) : 35.859 PERCENT CO2 0 BAROMETRIC PRESSURE : 29.59 PERCENT 02 21 PERCENT CO 0 FOR CIRCULAR STACK FOR RECTANGULAR STACK STACK D64ME7ER pneh): 0 STACK LENGTHQnchs) : STACK AREA (Sq.Ft) : 0 STACKWIDTHQnehs) : NOZZLE AREA (feet): 0.000334 STACK AREA (Sq.Ft) : 0 ENTER THE STACK AREA SHOWN ABOVE: 12 

### FLOWS SAMPLED VOLUME (STD. CU .FT.): 34.2131 VOLUME OF WATER VAPOR (STD. CU .FT.): 3.0031 FRACTIONAL MOISTURE CONTENT (°6): 0.0807

DRY BASE: 79.0000 MOLECULAR WT. OF STACK GAS (DRY BASE): 28.8400 MOLECULAR WT. OF STACK GAS (WET BASE): 27.9653 STACK PRESSURE (indh Hp): 29.6062 STACK GAS VELOCITY (1t/see.): 33.0703 ACTUAL STACK GAS FLOW RATE (ACFM): 23810.6357 STANDARD STACK GAS FLOW RATE (SCFH): 1213224.29 PARTICULATE FRONT HALF PARTICULATE CONCENTRATION (GRJSCF): 0.0035 PARTICULATE CONCENTRATION (LBS/SCF): 5.03E-07 PARTICULATE EMISSION (LBS/HR): 0.6099 BACK HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0069 PARTICUL4TE CONCENTRATION (LB8/SCF): 9.86E-07 PARTICULATE EMISSION (LBSIHR): 1.1963 ISOKINETIC RATIO (%): 101.2682

POINTS STACK T. DELTA P QUAR D. DELTA H METER T. METER T.

deq F INLET OUTLET 1 105 0.31 0.556776 1.13 83 83 2 106 0.45 0.67082 1.64 84 80 3 105 0.57 0.754983 2.08 86 80 4 105 0.47 0.685565 1.71 87 79 5 105 0.41 0.640312 1.49 89 79 6 106 0.35 0.591608 1.28 89 79 7 106 0.39 0.6245 1.42 89 79 8 105 0.51 0.714143 1.86 90 79 9 106 0.40 0.632456 1.46 91 79 10 106 0.31 0.556776 1.13 90 79 11 106 0.36 0.6 1.31 90 79 12 106 0.52 0.72111 1.90 90 79 13 106 0.46 0.678233 1.68 92 79 14 105 0.28 0.52915 1.02 90 79 15 106 0.36 0.6 1.31 91 79 16 106 0.41 0.640312 1.50 91 80 17 106 0.32 0.565685 1.17 92 79 18 106 0.19 0.43589 0.69 91 80 19 106 0.12 0.34641 0.44 90 79 20 106 028 0.52915 1.02 89 80 21 105 0.12 0.34641 0.44 89 79 22 106 0.06 0.244949 0.22 89 79 23 105 0.08 0.282843 0.29 88 78 METER T. 24 104 0.18 0.424264 0.66 89 79 AVERAGE 105.58333 0.5572 1.2021 89.1250 79.3333 84.2292



# 9 /p 

# ~

### EMSSION TEST SUMIMRY

PLANT : Atheru Brick Company, Atham, TX DATE : 13-0ec-95 PLACE : bin Exhaust 

## RUN#: 1 TEST DURATION (MINUTES) : 60 LIOUID COLLECTED (mis) : 82 NOm E DIAMETER (INCH.) : 0.2476 PARTICULATE WEIGHT (Front half mp) 75.3 METER COEFFICIENT (1) : 1.0203 PARTICULATE WEIGHT (Back hal/ mp) 8.1 PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in H20) : 0.67 GAS METER VOL(Cu.Ft) : 50.544 PERCENT CO2 2.5 BAROMETRIC PRESSURE : 29.62 PERCENT 02 17.5 PERCENT CO 0 FOR CIRCULAR STACK FOR RECTANGULAR STACK STACK DIAMETER Qnch): 0 STACK LENGTHpndu) : 29 STACKAREA (Sq.Ft) : 0 STACK WIDTHpnehs) : 24 NOmE AREA (feet): 0.000334 STACK AREA (S¢Ft) : 4.833333 ENTER THE STACK AREA SHOWN ABOVE: 4.833 

### FLOWS SAMPLED VOLUME (S7D. CU.FT.): VOLUME OF WATER VAPOR (STD. CU .FT.): FRACTIONAL MOISTURE CONTENT (%):

DRY BASE: MOLECULAR WT. OF STACK GAS (DRY BASE): MOLECULAR WT. OF STACK GAS (WET BASE): STACK PRESSURE pndi Hp): STACK GAS VELOCITY (ft/sec.): ACTUAL STACK GAS FLOW RATE (ACFM): STANDARD STACK GAS FLOW RATE (SCFH): PARTICULATE FRONT HALF PARTICULATE CONCENTRATION (GRJSCF): PARTICULATE CONCENTRATION (LBS/SCF): PARTICULATE EMISSION (LBS/HR): BACK HALF PARTICULATE CONCENTRATION (GR./SCF): PARTICULATE CONCENTRATION (LBS/SCF): PARTICULATE EMISSION (LBS/HR): ISOKINETIC RATIO (°.6): 50.4758 3.8597 0.0710 80.0000 29.1000 28.3115 29.6693 71.5321 

## 20742.8818 721859.105

0.0230 3.29E-06 

## 2.3745
0.0025 3.54E-07 0.2554 101.1315

POINTS STACK T. DELTA P OUAR D. DELTA H METER T. METER T.

dep F INLET OUTLET 1 382 1.20 1.095445 2.70 71 70 2 376 1.30 1.140175 3.00 73 71 3 377 1.30 1.140175 3.00 75 71 4 374 1.20 1 7 095445 2.70 77 71 5 374 1.20 1.095445 270 77 71 6 375 0.77 0.877496 1.80 78 72 

## 7 380 1.10 1.048809 2.50 79 73 8 384 1.10 1.048809 2.50 80 73 9 385 1.20 1.095445 2.70 80 73 

## 10 384 1.20 1.095445 2.70 80 74 11 381 1.20 1.095445 2.70 80 74 

## 12 388 0.90 0.948683 2.00 80 75 13 383 0.92 0.959166 2.20 79 75 14 385 0.98 0.989949 2.20 80 75 15 391 1.00 1 2.20 81 76 16 396 1.10 1.048809 2.50 81 75 17 396 1.10 1.048809 2.50 82 76 18 401 0.84 0.916515 1.60 81 76 19 397 0.70 0.83666 1.60 81 76 20 310 0.72 0.848528 1.60 82 76 21 308 0.95 0.974679 2.20 82 76 22 388 0.83 0.911043 1.90 83 77 23 385 0.80 0.894427 1.80 83 77 METER T. 24 386 0.52 0.72111 1.20 83 77 AVERAGE 

## 378.58333 0.9969 2.2708 79.5000 74.1667 76.8333



# 10 / 

# ~

### EMSSION TEST SUNMI RY

PLANT : Atl

~ 

### ena Briek Comprrry, Athens, TX DATE : 13-Dea-05 PLACE : YOIn E)(heuat RUNik : 2 TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 125.2 NOm.E DIAMETER (INCH.) : 0.2476 PARTICULATE WEIGHT (Front helf mq) 61.8 METER COEFFICIENT (Y) : 1.0203 PARTICULATE WEIGHT (Baek helf mp) 4 PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (In. H20) : 0.59 GAS METER VOL(Cu.Ft) : 48.226 PERCENT CO2 3 BAROMETRIC PRESSURE : 29.62 PERCENT 02 16 PERCENT CO 0 FOR CIRCULAR STACK FOR RECTANGULAR STACK STACK DIAMETER Qrxh): 0 STACK LENGTH(inehes) : STACKAREA (Sq.Ft) : 0 STACK WIDTHpnehes) : NOZaE AREA (feet): 0.000334 STACK AREA (Sq.Ft) : 0 ENTER THE STACK AREA SHOWN ABOVE: 4.833 

### FLOWS SAMPLED VOLUME (STD. CU .FT.): 47.5206 VOLUME OF WATER VAPOR (STD. CU .FT.): 5.8932 FRACTIONAL MOISTURE CONTENT (%): 0.1103

DRY BASE: 81.0000 MOLECULAR WT. OF STACK GAS (DRY BASE): 29.1200 MOLECULAR WT. OF STACK GAS (WET BASE): 27.8931 STACK PRESSURE (ndi Hp): 29.6634 STACK GAS VELOCITY (ft/see.): 70.6944 ACTUAL STACK GAS FLOW RATE (ACFM): 20499.9526 STANDARD STACK GAS FLOW RATE (SCFH): 664022.533 PARTICULATE FRONT HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0201 PARTICULATE CONCENTRATION (L8S/SCF): 2.87E-06 PARTICULATE EMISSION (LBS/HR): 1.9041 

### BACK HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0013 PARTICULATE CONCENTRATION (LBS/SCF): 1.86E-07 PARTICULATE EMISSION (LBS/HR): 0.1232 ISOKINETIC RATIO (°.6): 103.5045

POINTS STACK T. DELTA P QUAR D. DELTA H METER T.

dep F INLET 1 425 0.93 0.964365 2.20 2 302 1.30 1.140175 3.00 3 293 120 1.095445 2.60 4 453 1.00 1 220 5 402 0.95 0.974679 2.10 6 401 0.51 0.714143 1.10 7 400 1.10 1.048809 2.40 8 402 1.20 1.095445 2.60 9 401 1.20 1.095445 2.70 10 403 1.10 1.048809 2.50 11 404 1.00 1 2.30 12 404 0.87 0.932738 2.00 13 395 0.98 0.989949 220 14 408 1.00 1 2.30 15 409 1.00 1 2.30 16 407 0.96 0.979796 2.20 17 409 0.94 0.969536 2.10 18 407 0.74 0.860233 1.70 19 410 0.77 0.877496 1.80 20 422 0.80 0.894427 1.80 21 424 0.83 0.911043 1.80 22 429 0.82 0.905539 1.80 23 428 0.75 0.866025 1.70 24 426 0.60 0.774597 1.30 40266667 0.9641 2.1125 METER T. OUTLET 78 78 80 78 81 78 82 78 83 78 84 79 84 79 86 80 87 80 88 81 88 81 88 82 84 82 86 82 87 83 88 83 88 83 89 83 90 83 90 84 90 84 90 84 90 85 METER T. 91 85 AVERAGE 86.3333 81.3750 83.8542



# 11 ~~

### EMSSION TEST SUNIW RY

PLANT : Atheris Brick Company, Athens, TX DATE : 13-0ec-95 PLACE : Klin Exhaust 

## RUNi: 3 TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 77.5 NOmE DIAME7ER (INCH.) : 0.2476 PARTICULATE WEIGHT (Front half mp) 98.5 METER COEFFICIENT (1) : 1.0203 PARTICULATE WEIGHT (Back half mp) 6.75 PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE Qn. H20) : 0.52 GAS METER VOL(Cu.Ft) : 47.541 PERCENT CO2 2.5 BAROMETRIC PRESSURE : 29.62 PERCENT 02 17 PERCENT CO 0 FOR CIRCULAR STACK FOR RECTANGULAR STACK STACK D64METER pnch): 0 STACK LENGTHpnchs) : STACK AREA (Sq.Ft) : 0 STACK WIDTHpnchs) : NOZID.E AREA (lbet): 0.000334 STACK AREA (Sq.Ft) : 0 ENTER THE STACK AREA SHOWN ABOVE: 4.833 

### FLOWS SJIMPLED VOLUME (STD. CU .FT.): 46.4801 VOLUME OF WATER VAPOR (STD. CU .FT.): 3.6479 FRACTIONAL MOISTURE CONTENT (°•6): 0.0728

DRY BASE: 80.5000 MOLECULAR WT. OF STACK GAS (DRY BASE): 29.0800 MOLECULAR WT. OF STACK GAS (WET BASE): 28.2737 STACK PRESSURE Qnch Hp): 29.6582 STACK GAS VELOCITY (it/sec.): 69.2951 ACTUAL STACK GAS FLOW RATE (ACFM): 20094.1877 STANDARD STACK GAS FLOW RATE (SCFH): 674751.828 PARTICULATE FRONT HALF PARTICULATE CONCENTRATION (GRJSCF): 0.0327 PARTICULATE CONCENTRATION (LBS/SCF): 4.67E-06 PARTICULATE EMISSION (LBS/HR): 3.1530 BACK HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0022 PARTICULATE CONCENTRATION (LBS/SCF): 3.20E-07 PARTICULATE EMISSION (LBS/HR): 0.2161 ISOKINETIC RATIO (%): 99.6274

POINTS STACK T. DELTA P QUAR D. DELTA H METER T. METER T.

dep F INLET OUTLET 1 397 0.91 0.953939 2.00 84 84 2 404 0.96 0.979796 2.10 87 84 3 403 0.98 0.989949 2.20 88 84 4 400 1.00 1 2.20 90 84 5 403 0.89 0.943398 2.00 90 85 6 402 0.54 0.734847 1.20 90 85 7 403 1.00 1 2.20 90 86 8 402 1.10 1.048809 2.40 91 86 9 403 1.00 1 2.20 91 86 10 404 1.10 1.048809 2.40 91 86 11 403 1.10 1.048809 2.40 91 86 12 406 0.81 0.9 1.80 91 86 13 409 0.92 0.959166 2.00 87 86 14 411 0.94 0.969536 2.10 89 85 15 413 0.98 0.989949 2.20 90 85 16 412 1.00 1 2.20 91 85 17 412 0.95 0.974679 2.10 92 66 18 413 0.76 0.87178 1.70 92 86 19 410 0.80 0.894427 1.80 92 87 20 411 0.82 0.905539 1.80 91 87 21 414 0.85 0.921954 1.90 92 87 22 410 0.97 0.984886 2.10 92 87 23 412 0.82 0.905539 1.80 92 87 METER T. 24 414 0.56 0.748331 1.20 92 87 AVERAGE 407.125 0.9489 2.0000 90.2500 85.7083 87.9792



# 12 ~~

# APPENDIX B



# -5
~ 

# 31213GL

FlLE MAAAE: 1213d LOGI'

~ INO SE 1 SiARr LOOl31N13 Q 1/M/// 07:1922: Ir3i SAMPLE 0 rY/M1iY 07:50:37: ACi1VEC4M 1A 1B 2A 2S MODLIE lYP Ydops Vdsgs VdeP VtlsP SMPLE RAT 16 aee 16 sso 15 ssc 18 sso LNTS: Vds NO; ppm Vds CO. {qn Vds VOC. ppm Vdt SOQ. ppm 12/1311986 7:1922AM 0.1 0.8 0.0 13.0 0.1 0.9 0.0 21.12

7:19:37AM 0.1 0.8 0.0 120 0.1 0.9 0.0 24 7:19:52AM 0.1 0.9 QO 120 0.1 0.9 0.0 2208 720:07AM 0.1 QB 0.0 120 0.1 0.9 0.0 23.04 72022AM 0.1 0.8 0.0 i.0 0.1 U.9 0.0 24 720:37AM 0.1 0.7 a0 SO 0.1 0.9 0.0 0.98 720:52AM 0.1 0.8 0.0 6.0 0.1 Q9 0.0 3.84 721:07AM 0.1 0.B 0.0 -4.0 0.1 Q9 0.0 1.92 72122AM 0.1 0.e 0.0 3.0 0.1 0.9 0.0 0.9e 721:37 AM 0.1 a8 0.0 3.a 0.0 0.0 0.0 .184 721:52AM 0.1 0.7 0.0 4.0 0.0 0.0 0.0 d94 722:07AM 0.1 0.6 0.0 3.0 0.0 0.0 ao 1.92 72222AM 0.1 0.8 0.0 4.0 0.3 29 0.0 384 72237AM 0.1 0.9 O.o 10 a3 3.1 0.0 1.92 72252AM 0.1 aB 0.0 3.0 0.3 3.0 0.0 3.84 723:07AM 0.1 0.8 0.0 4.0 0.3 3.3 0.0 3.84 72322AM 0.1 Q7 0.0 3.0 7.6 78.2 0.0 1.92 723:37 AM 0.1 Q8 0.0 20 7.7 78.5 a0 6.72 723:52AM _ 0.1 0.7 0.0 QO 9.2 922 0.0 4.8 724:07AM 0.1 0.7 0.0 1.0 9.2 9z1 0.0 4.8 72422AM 0.1 0.7 0.0 0.0 Q9 e9.3 a0 .6.72 724:37AM 0.1 0.8 0.0 3.0 0.4 3.8 0.0 288 724:52AM 0.1 0.8 0.0 1.0 4.9 48.5 0.0 184 725:07AM 0.1 0.B 0.0 20 4.9 49.4 0.0 4.8 72522AM 0.1 0.8 0.0 1.0 4.9 49.4 0.0 194 725:37AM 0.1 0.7 0.0 1.0 4.9 49.4 Qo S76 725:52AM 0.1 0.7 0.0 3.0 ze 28.1 0.0 3.84 728:07AM 0.1 a8 0.0 3.a 0.5 4.5 a0 3.84 72822AM 0.1 0.8 0.0 4.0 3.1 3Q8 0.0 4.8 72e:37AM 0.1 0.8 0.0 3.0 3.1 31.0 0.0 2Be 726:52AA1 0.1 QB 0.0 3.0 3.1 31.0 0.0 4.8 727:07 AM 0.1 Q8 0.0 4.0 3.1 30.9 0.0 184 72722
- AM a1 ae 0.0 20 28 28.1 a0 1.92 727:37AM 0.1 0.e 0.0 3.0 0.4 3.7 0.0 S7e 727:52AM 0.1 0.8 0.0 3.0 0.4 3.e 0.0 3.84 728:07AM 0.1 0.8 0.0 37.0 a0 0.0 0.0 2ee 72922AM 0.1 0.5 0.4 386.0 a0 0.0 0.0 3.84 728:37AM 0.1 0.6 a4 401.0 0.0 a0 0.0 0.96 728:62AM 0.1 0.6 0.4 4020 0.0 0.0 0.0 3.64 729:07Ah1 0.1 0.8 0.4 4020 a1 1.1 0.0 2B8 72922AM 0.1 0.e 0.1 1220 0.3 3.4 0.0 288 729:37 AM 0.1 0.7 0.0 43.0 0.0 0.0 a0 4.8 729:52AM 0.1 0.7 0.2 248.0 0.0 0.0 0.0 1.92 7:30:07AM 0.1 0.7 0.3 254.0 0.0 -0.1 0.0 3.64 7:3022AM 0.1 0.5 0.3 256.0 0.0 0.0 0.0 3.84 7:30:37AM 0.1 0.6 0.3 256.0 0.1 0.e 0.0 1.92 7:30:52AM 0.1 0.7 0.1 93.0 0.3 13 0.0 4.8 7:31:07 AM 0.1 0.8 0.0 9.0 0.0 0.0 0.0 1.92 7:3122AM 0.1 0.8 0.1 9a0 0.0 0.0 U.0 2BB 7:31:37AM 0.1 0.7 0.1 101.0 0.0 0.0 0.0 z88 7:31:52AM 41 0.7 0.1 1020 0.0 0.0 0.0 1.92 7:32:07AM 0.1 0.7 0.1 101.0 a0 0.0 ao 3.84 7:32'22AM a1 Qe 0.1 58.0 0.3 2e 0.0 1.92 7:3237AM 0.1 0.e 0.0 8.o 0.1 ae 0.0 288 7:32:62 AM 0.1 0.8 0.0 4.0 0.0 0.0 RO 3.84 7:33:07 AM 2e 28.4 0.0 e.0 0.0 0.0 0.0 1.92 7:33:22AM 4.4 43.e 0.0 QO 0.a 0.0 0.0 3.84 7:33:37AM 4.5 461 0.0 SO 0.0 0.0 0.0 288 7:33:52 AM 4.6 44.9 0.0 6.0 0.3 25 0.0 2e8 7:34:07AM 0.2 22 0.0 5.0 0.7 29 0.0 4.8 7:3422AM 4.4 44.3 0.0 4.0 0.0 a0 QO 1.92 7:34:37AM 6.0 49.7 0.0 4.0 0.0 0.0 0.0 184 7:34:52AM Qi $1.3 0.0 3.0 0.0 0.0 a0 288 7:36:07AM 6.2 51.8 0.0 4.0 0.0 0.0 a0 1.92 7:3572AAA 5.1 81.1 0.0 4.0 0.0 a0 0.0 6.72 7:35:37AM 0.3 3.1 0.0 4.0 0.3 11 0.0 4.8 7:35:52AM 0.3 2e 0.0 6.0 0.3 3.4 0.0 3.84 7:3e:07AM 1.0 10.3 0.0 5.0 a.0 0.0 0.0 3.84 7:3e22AM 3.4 33.5 0.0 4.0 0.0 a0 0.0 288 7:3e:37AM 3.4 33.e 0.0 4.0 0.o 0.0 0.0 4.8 7:38:52AM 3.4 33.e Qo 4.0 00 -0.1 0.0 1.92 7:37:07AM 13 33.4 0.0 4.0 0.0 0.0 0.0 3.84 7:3722AM 2.2 221 0.0 4.0 0.3 3.0 0.0

. 3.84 7:37:37AM 0.3 3,2 0.0 4.0 O.o 0.0 0.0 4.8 7:37:52AM 0.5 4.e 0.0 6.0 ao -0.1 0.4 3561e 7:38:07AM 0.4 3.9 0.a 6.0 0.0 Q1 0.4 423.3e 7:3872AM 0.3 3.4 0.0 6.0 0.0 -0.1 0.8 446.4 7:38:37AM 0.3 3.2 0.0 4.0 a0 a1 0.5 456.04 7:39:52AM 0.3 3.1 0.0 3.0 0.0 d.1 0.5 4e1.7e 7:39:07 AM 0.3 28 0.0 4.0 0.0 0.4 0.5 488.46 7:39Z2 AM 0.3 28 0.0 6.0 0.0 d.1 Q6 4613 7:39:37AM 0.3 25 0.0 4.0 0.0 d1 Q8 450 7:39:62AM 0.3 26 0.0 4.0 0.0 L.1 0.6 460.24 7:40:07AM 0.3 25 0.0 6.0 0.0 d1 0.6 461.2 7:4022 AM 0.2 23 0.0 Sa 0.0 -0.1 0.5 484.08 7:40:37AM 0.2 24 0.0 0.0 0.0 -0.1 0.6 46218 7:40:52AM 0.2 22 0.0 SO 0.3 12 0.4 407.04 7:41:07AM 0.2 Z2 0.0 4.0 0.3 l3 Q1 68.68 7:4122AAA 0.2 20 a0 6.0 0.3 12 0.o 28.8 7:41:37AM 0.2 22 0.0 6.0 0.3 3.0 QO 2208 7:41:52AM 0.2 23 0.0 5.0 0.2 24 0.0 1636 7:42:07AM (12 22 0.0 0.0 0.0 0.0 0.0 19.2 7:4222AM 0.3 2e 0.0 6.0 a0 a.1 02 191.04


## 13 o.... ,1213GL

7:42:37 AAA 0.2 z 1 0.0 5.0 0.0 -0.1 0.2 211.2 7:42:52AM 0.2 z1 0.0 4.0 0.0 -0.1 0.2 21&88 7:43:07 AM 0.2 z0 0.0 4.0 0.0 -0.1 0.2 217.92 7:4322AM 0.2 zt 0.0 4.0 0.0 0.0 0.2 221.78 7:43:37AM 0.2 zt 0.0 4.0 0.0 at 0.2 221.78 7:43:52 IA1 0.2 zo 0.0 4.0 0.0 at 0.2 221.78 7:44:07AM 0.2 zo 0.0 4.0 0.0 at 0.2 224.84 7:4422AM 0.2 1.9 0.0 4.0 0.3 z9 0.2 213.12 7:44:37AM 0.2 1.9 0.0 4.0 0.3 3.3 0.o 43.2 7:44:52AM 0.2 1.8 0.0 4.0 0.1 0.6 0.0 2z08 7:45:07AM 3.5 34.5 0.0 4.0 0.0 0.0 0.0 1&38 7:4572AM 3.4 33.5 0.0 3.0 0.0 0.0 0.0 1248 7:45:37 AM 3.4 33.8 0.0 4.0 0.0 0.0 0.0 9.8 7:46:52MA 3.3 33.3 0.0 5.0 0.0 0.0 0.0 9.8 7:48:07 AM 3.3 33.1 0.0 4.0 0.2 1.5 0.0 7.68 7:4822AM 0.2 z0 0.0 SO 0.3 29 0.0 7.88 7:48:37AM 0.2 1.9 0.0 &0 0.0 0.0 O.o 9.e 7:48:52/Md 0.2 1.7 Qo 5.0 0.0 0.0 0.0 7.68 7:47:07AM 0.2 1.7 0.0 4.0 0.0 0.0 0.0 &64 7:4732AM 0.2 1.8 0.0 4.0 0.0 0.0 0.0 5.78 7:47:37AM 0.2 1.5 0.0 4.0 0.0 0.0 0.0 0 7:47:52AM 0.2 1.7 0.0 4.0 0.3 25 0.0 z58 7:48:07 AM 0.2 1.7 0.0 4.0 0.0 0.0 0.0 5.78 7:4822 AM 0.2 1.8 0.0 8.0 0.0 0.0 02 182.4 7:48:37 AA1 0.2 1.8 0.0 5.0 0.0 a 1 0.2 20258 7:48:52AM 0.2 1.8 0.0 5.0 0.0 a1 0.2 210.24 7:49:07 AM 0.2 1.8 0.0 5.0 0.0 -0.1 0.2 214.08 7:4922AM 0.2 1.7 0.0 5.0 0.0 a1 0.2 214.08 7:49:37AM 0.2 1.5 0.0 5.0 0.0 (10 0.2 217.92 7:49:52AM 0.2 1,8 0.0 4.0 0.0 -0.1 OS 218.98 7:50:07AM 0.2 1.6 0.0 5.0 0.0 a1 0.2 21&88 7:5022IA1 0.2 1.7 0.0 5.0 0.0 at 0.2 21&88 7:50:37AM (12 1.5 0.0 4.0 0.0 -0.1 0.2 217.92



# 14 ~ 

# ' ~~1213R1

FlLENAME 1213r1 LO(iGINO S 1 STARi LOGGINO ® sONWO 08:04:47: LA87 3AWI.E ® NMYMN# 09:3217: ACTIVECFN 1A 1B 2A 2B MOOI.Ie Tv Vouw vos.p vohp. vae.0. SAFPLE RA 15 asc 15 ese 16 sae 16 sse LtJTS: Vats NOx, pppn Vats CO, ppm Vots VOC, ppn Vols S02, ppm 1211311996 8:04:47AM 0.1 1.3 0.0 5.0 0.3 3.0 0.0 472

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# 15 2 t ~~1213R1

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16

PoP 2 '211213R1

8:53:17MI 1.5 16.1 0.1 67.0 0.7 7.0 0.1 72 8:53:32AM 1.5 14.8 0.1 67.0 0.8 7.8 0.1 73.92 8:53:47AM 1.5 14.9 a1 89.0 0.7 7.4 0.1 72 8:54:02 AA1 1.6 14.9 0.1 88.0 0.7 6.8 0.1 73.92 8:54:17AM 1.5 1&0 at 6&0 0.9 9.0 0.1 74.88 8:64:32 AM 1.5 14.7 0.1 6&0 0.6 e.4 0.1 7299 8:54:47AM 1.5 1S3 0.1 6&0 0.9 8.4 0.1 7E.8 8:55:02 AM 1.5 15.3 0.1 98.0 0.7 8.7 0.1 74.88 8:55:17 AM 1.5 15.0 0.1 e80 ae 6.3 0.1 73.92 8:66:32AM 1.5 15.2 0.1 89.0 0.7 7.0 0.1 75.84 8:55:47IAA 1.5 15.3 0.1 e&0 0.8 7.6 0.1 729e 8:58:02AM 1.5 14.9 0.1 6&0 0.7 0.7 G.1 74.88 8:6e:17AM 1.5 1&0 0.1 98.0 0.9 6.3 0.1 73.92 8:5e:32AM 1.5 15.0 ai 9&0 0.6 5.2 0.1 72.9e 8:59:47AM 1.9 15.6 0.1 e&0 0.6 So 0.1 7e.e 8:57:02AM 1.5 1S4 0.1 97.0 0.7 6.7 0.1 74.88 8:57'.17AM 1.E iSe 0.1 9&0 Qe 8.4 0.7 76.84 6:57:32AM 1.e 15.7 0.1 e&0 0.e 5.7 0.7 78.8 8:57:47 AM 1.8 1&6 0.1 67.0 0.e &8 0.1 74.88 8:58:02MA 1.9 15.7 a1 6&0 0.5 5.0 0.1 77.76 8:58:17AM 1.9 1e.0 a1 e&0 0.6 9.2 0.1 73.72 8:58:32AM 1.5 15.3 0.1 eB.O 0.6 e.4 a1 7584 8:58:47 AM 1.9 15.9 0.1 89.0 0.6 9.1 at 78.72 8:59:02AM 1.8 1e.0 0.1 67.0 0.9 9.3 0.1 7684 8:59:17AM 1.8 19.4 0.1 e&0 0.7 e.8 0.1 Bae4 8:59:32AM 1.6 16.1 a1 e7.0 1.1 ta8 0.1 79.e8 8:59:47 AM 1.e 16.1 0.1 67.0 1.1 11.0 0.1 77.76 9:00:02AM 1.8 16.1 0.1 e7.0 1.0 10.3 0.1 81.6 9:00:17M1 1.9 18.3 a7 67.0 0.9 &7 0.1 78.72 9:00:32AM 1.7 18.6 at 67.0 0.8 8.0 0.1 80.e4 9:00:47AM 1.7 1e.5 0.1 6&0 0.8 &4 0.1 81.9 9:01:02AM 1.6 18.3 0.1 97.0 0.7 7.1 0.1 77.78 9:01:17AM 1.7 16.5 0.1 6&0 0.7 7.4 0.1 8266 9:01:72 AM 1.7 16.6 a 1 67.0 0.7 7.1 0.1 80.64 9:01:47 AM 1.e 1e.3 0.1 ee.0 0.7 9.5 0.1 8a64 9:02:02AM 1.7 17.0 0.1 6Q0 aS 5.4 0.1 8352 9:02:17AN 1.7 16.6 0.1 66.0 0.9 e.1 a1 81.9 9:02:32M1 1.7 1Q6 0.1 67.0 0.7 e.5 0.1 6352 9:02:47 AM 1.7 1e.7 0.1 67.0 0.e 6.1 0.1 83.52 9:03:02 AM 1.7 17.4 0.1 68.0 0.e 6.3 0.1 63.52 9:03:17 MI 1.7 19.9 0.1 8e.0 0.8 7.8 0.1 84.48 9:03:32MA 1.7 18.9 0.1 97.0 0.8 &4 0.1 61.0 9:03:47AM 1.7 16.9 0.1 67.0 0.7 9.8 0.1 81.6 9:04:02MA 1.8 17.5 0.1 68.0 0.6 6.1 0.1 95.44 9:04:17AM 1.7 19.8 0.1 e7.0 0.7 9.7 0.1 81.8 9:04:32AM 1.7 17.0 0.1 6R0 0.7 7.2 a1 84.48 9:04:47AM 1.7 17.3 0.1 6&0 0.7 7.4 0.1 83.62 9:06:02AM 1.6 1e.4 0.1 87.0 0.8 7.6 0.1 81.e 9:05:17NN 1.7 17.4 a1 e9.0 0.7 7.0 0.1 8e.4 9:05:32AM 1.7 19.8 a1 67.0 0.7 7.2 0.1 8a64 9:05:47AM 1.7 17.1 0.1 e&0 0.7 7.2 0.1 64.48 9:08:02AM 1.7 1e.8 0.1 67.0 0.7 7.2 0.1 63.52 9:0e:17AM 1.7 17.0 a1 67.0 0.5 5.0 0.7 81.e 9:08:32AM 1.7 1e.8 0.1 9&0 0.5 4.8 0.1 84.48 9:08:47AM 1.7 17.1 0.1 87.0 ae S8 0.1 8152 9:07:02AM 1.7 17.1 0.1 67.0 0.8 7.9 0.1 82.58 9:07:17AM 1.7 16.7 0.1 67.0 0.6 &3 0.1 825e 9:07:32AM 1.7 1e.9 0.1 88.0 1.1 10.7 0.1 81.6 9:07:47 AM 1.7 te.9 0.1 9&0 0.9 9.0 0.1 80.84 9:08:02NN 1.7 18.6 0.1 69.0 0.7 eA 0.1 81.9 9:08:17AM 1.7 1e.5 0.1 9&0 0.9 e.1 0.1 78.72 9:08:32AM 1.7 16.e 0.1 e9.0 0.e 0.2 at 83.62 9:08:47AM 1.6 16.4 at e&0 0.6 5.5 0.7 81.6 9:09:02AM 1.7 17.0 0.1 69.0 0.6 4.9 0.1 83.52 9:09:17 AM 1.7 1e.9 0.1 6&0 0.8 7.9 0.1 88.4 9:09:32AM 1.7 17.0 a1 89.0 1a9 &9 a1 ffi.52 9:09:47AM 1.7 17.0 a1 69.0 0.9 9.2 a1 8e.4 9:10:02AM 1.7 1e.9 0.1 e&0 0.9 0.4 a1 84.48 9:10:17AM 1.7 1e.9 ai 67.0 1.0 9.6 0.1 815e 9:1a:32AM 1.7 17.1 0.1 e&0 0.8 8.3 0.1 64.48 9:10:47AM 1.7 16.9 0.1 e7.0 0.8 &0 0.7 e0.84 911:02AM 1.7 17.1 0.1 e6.0 0.7 7.1 a1 84.48 9:11:17AM 1.7 1a.9 ai e7.0 ae 8.0 0.1 84.48 9:11:32AM 1.7 17.0 0.1 67.0 0.9 &7 0.1 63.52 9:11:47 AM 1.7 17.1 0.1 67.0 0.8 7.7 0.1 85.44 9:12:02 AM 1.7 1e.7 0.1 9e.0 0.8 7.9 0.1 825a 9:12:17 AM 1.7 17.2 0.1 67.0 0.6 e.4 0.1 83.52 9:12:32AM 1.7 17.0 0.1 97.0 Qe 5.7 0.1 95.44 9:12:47 AM 1.2 11.9 0.1 03.0 a7 6.7 0.1 T7.75 9:13:02AM 0.7 7.1 0.0 380 0.8 7.6 a0 38.4 9:13:17M1 0.9 &9 0.1 5a0 0.6 7.7 0.0 38.4 9:13:32M1 0.9 9.0 0.0 48.0 0.9 8.5 0.0 40.32 9:13:47 AM 1.0 9.6 0.1 64.0 1.0 10.3 0.1 628 9:14:02M1 0.9 9.1 0.1 61.0 1.0 9.e 0.1 50.86 914:17AM 1.0 9.8 0.1 34.0 ae 7.e 0.1 5a76 9:14:32 AM 1.0 9.6 0.1 53.0 1.0 10.0 0.1 56.e8 9:14:47AM 0.9 9.2 0.1 520 1.4 13.5 0.1 64.72 9:16:02 AM 1.0 9.7 0.1 63.0 1.4 14.3 0.1 56.61 9:15:17AM 0.9 92 0.1 520 G.9 0.4 0.1 50.66 9:16:32AM 1.0 10.0 0.1 S&0 0.8 7.6 a1 67.e 9:16:47 AM 10 19.6 0.1 75.0 0.8 7.7 a 7 117.12 9:19:02AM 1.8 1&0 a1 eao 0.7 e.9 a1 108.46 9:16:17AM 1.8 17.5 0.1 e0.0 0.7 66 0.1 10168 9:1e:32AM 1.7 17.4 0.1 e6.0 0.e 6.7 a1 94.08 9:1e:47AAA 1.6 17.7 0.1 e3.0 0.4 4.4 ai 90.44 9:17:02AM 1.6 17.6 0.1 eno 0.4 4.2 ai 93.12 9:17:17AM 1.6 18.0 0.1 6Qo 0.4 4.1 ai 89.28 9:17:32MA 1.8 1&1 0.1 67.0 0.e S.6 0.1 69.2e 9:17:47 MI 1.8 179 0.1 67.0 a 7 e.6 0.1 67.3e 9:18:a2MA 1.6 1&0 a1 67.0 0.7 7.2 0.1 ee.4 9:18:17 AA1 1.8 17.8 0.1 67.0 0.6 7.7 0.1 87.3e 9:18:32,MA 1.8 17.9 a1 6&0 0.7 7.1 0.1 664 9:18:471M7 1.8 17.e a1 67.0 0.7 e.e 0.1 86.4 

# 17 'e-Stop R7 

## 1213R1

9:19:02AM 1.8 17.8 41 8&0 0.7 8.7 0.1 86.1 9:19:17AM 1.7 n.z 0.1 87.0 0. 7 7.2 0.1 8258 919:32 AM 1.6 16.4 0.1 68.0 0.8 7.8 0.1 8256 9:19:47 AM 1.8 16.2 0.1 89.0 0.7 8.5 0.1 80.84 920:02AM 1.8 15.6 0.1 88.0 0.8 &0 0.1 8464 920:17AM 1.8 15.8 0.1 89.0 0.7 8.9 0. 1 87.8 920:32 AM 1.6 15.6 0.1 88.0 0.8 8.1 41 8464 920:47 MA 1.5 15.2 0.1 70.0 48 &2 0.1 8258 921:02 AM 1.8 16.1 0.1 89.0 0.9 8.9 0.1 94.48 921:17 AM 1.7 17.1 0.1 69.0 1.0 10.1 0.1 8928 921:32 AM 1.7 17.1 0.1 6&0 0.9 9.3 0.1 91.2 921:47AM 1.7 18.9 0.1 8&0 0.9 Qt 0.1 87.36 a2202AM 1.7 17.1 0.1 6&0 0.8 &3 41 87.36 922•17 M1 1.7 17.1 0.1 8&0 0.8 7.5 0.1 85.44 922:32 AM 1.7 17.4 0.1 6&0 0.6 8.4 0.1 84.48 922:47 AM 1.8 17.8 0.1 8a.0 0.7 7.2 0.1 8928 923:02AM 1.8 ~ 17.6 0.1 6&0 0.7 8.6 0.1 86.44 923:17 AM 1.8 17.8 0.1 68.0 48 5.9 0.1 87.36 923:32AM 1.8 17.8 0.1 8&0 0.5 4.8 0.1 8&32 923:47AM 1.8 1&0 0.1 89.0 0.8 5.8 0.1 8&32

Avsrap 14.98 64.39 7.37 73.85 924:02 AM 1.8 17.8 0. 1 87.0 0.8 & 1 0. 1 89.28 924:17AM 1.8 1&1 0.1 69.0 0.8 &4 0.1 89.28 924:32,4A 0.3 3.2 0.0 440 0.4 4.0 0.1 85.28 924:47 AM 0.2 1.9 0.0 5.0 0.3 3.2 40 21.12 925:02AM 0.2 1.B 0. 0 3.0 0.3 3.3 0.0 9.6 925:17AM 0.2 1.8 0.0 4.0 43 12 0.0 0.64 925:32 AM 0.2 1.7 0.0 4.0 0.3 3.2 0.0 6.72 925:47 AM 0.2 1.7 0.0 4.0 0.3 3.2 0. 0 4.8 926:02AM 0.3 25 0.0 4.0 43 28 0.0 7.68 928:17AM 0.2 1.9 0.0 3.0 28 27.8 0.0 3.64 928:32AM 0.2 1.7 0.0 ZO 29 2&9 0.0 5.76 926:47 AM 0.2 1.8 40 5.0 ' 3.0 29.5 0.0 8.72 927;02AM 42 1.8 0.0 4.0 7.0 29.7 0.0 3.94 927:17AM 0.2 1.9 40 4.0 29 29.4 0.0 6.72 927:32AM 42 1.B 0.0 5.0 0.4 3.8 0.0 5.78 927:47 AM 0.3 28 0.0 5.0 0.1 0.8 0.0 4.8 92B:OZAM 3.4 33.7 Q0 5.0 0.1 0.5 0.0 S76 92B:17AM 3.3 33.1 0.0 4.0 02 1.8 0.0 286 928:32 AM 3.3 33.4 0. 0 4.0 0. 2 1.8 0. 0 6.76 928:47 AM 3.3 33.4 0.0 4.0 0.2 1.5 0.0 4.8 929:02AM 0.4 3.8 0.0 4.0 45 4.8 0.0 4.8 929:17AM 0.2 1.5 0.0 11.0 0.1 1.0 0.0 5.76 929:32AM 0.2 1.6 41 1040 0.1 0.9 0. 0 286 929:47 AM 0.2 1.6 0. 1 103.0 41 48 0.0 4.8 9:30:02AM 02 1.5 0.1 102.0 0.1 0.8 0. 0 4.8 9:30:17AM 0. 2 1.5 0. 1 103.0 0. 1 0. 5 0.0 Z84 9:30:32 AM 0.2 1.6 0.1 1020 0.1 0.8 0.0 &84 9:30:47 AM 0.2 1.8 0.0 13.0 0.1 48 0.1 140.16 9:31:02AM Q2 1.5 0. 0 5.0 0. 1 0. 5 42 213.12 9:3117 AIN 0.2 1.5 40 4.0 0.0 0.4 0.2 230.4 9:31:32 AM 0.1 1.4 0.0 4.0 0.0 0.4 0. 2 229.41 9:31:47 AM 0.1 1.4 40 4.0 40 0.3 0.2 236.2 9:32'02AM 0.2 1.5 0. 0 SO 0.4 3.7 0.2 236.2 9:3217AM 0. 2 1.5 40 10 0.4 3.8 0.0 4224



# l 

# s Fqp 4 

# ~ y1213CAL2

FlL.E NAME: 1213nQ LOGGIN6 SE 1 START LOGGINf3 ® NIMlNM 11:3231: LAST SAMPLE ® NMNYM 11:40:48: ACTIVE CJ-M tA 1B 211 2B MODU..E Tv 

## vovp votq votaps 

## v~ SMPLE RAT 15 sec 15 s•a 16 aec 15 see wTS: va[s NOiC {pm vots 00, ppm vds vOC, ppm vots S02, ppm 12I1311996 11:32:31 AM 0.1 1.4 0.0 

## ao 0.4 4.2 0.0 0

11:32'48AM 0.1 1.4 0.0 6.0 0.4 4.3 0.0 1.92 11:37:01 AM 0.1 1.4 0.0 4.0 0.4 4.2 0.0 0.98 11:33:18AM 0.2 1.5 0.0 -4.0 14 3.7 0.0 498 11:33:31 AM 0.1 1.4 0.0 20 0.4 3.8 0.0 3.84 11:33:48AM 0.1 1.4 0.0 7.0 0.0 0.4 0.0 098 • 11:34:01 AM 0.1 1.4 0.1 020 0.0 0.4 0.0 -1.92

11:34:18AM 0.2 1.5 0.1 100.0 0.0 0.4 0.0 3.84 11:34:71 AM 0.1 1.4 0.1 100.0 0.0 0.0 0.0 -288 11:34:48AM 0.2 1.6 0.1 97.0 0.0 0.0 0.0 d84 11:36:01 AM 0.2 1.8 0.1 96.0 0.3 3.3 0.0 268 11:3518AM 0.2 1.5 0.0 7.0 0.4 16 0.0 -4.8 11:35:31 AM 0.2 1.5 00 a.0 9.7 98.8 0.0 -0.98 11:35:48AM 0.2 1.5 0.0 4.0 9.2 921 0.0 2e8 11:38:01 AM 0.2 1.8 0.0 d0 9.2 923 0.0 0 11:3e:19 AM 0.2 1.9 0.0 -7.0 9.2 921 0.0 1.92 11:3e:31 AM 0.2 1.8 0.0 3A 6.9 86.e 00 0.9e 11:38:48AM 0.2 1.5 0.0 -4.0 0.4 3.9 0.0 -4.8 11:37:01 AM 0.2 1.5 0.0 -4.0 0.3 3.4 0.0 -4.8 11:37:18AM 0.2 1.6 0.0 1.0 0.1 0.5 0.0 d78 11:37:31 AM 3.2 31.8 0.0 -&0 0.0 0.0 0.0 872 11:37:48 AM 12 ' 322 0.0 -1.0 QO 0.0 0.0 -288 11:38:01 AM 3.2 322 0.0 30 0.0 0.0 0.0 i.8 11:38:18 AM 3.2 322 0.0 a.0 0.0 0.0 0.0 472 11:38:31 AM 3.2 320 0.0 -20 0.3 27 0.0 .1.84 11:38:46AM 0.2 20 0.0 -1.0 0.0 0.0 0.0 0.98 11:39:01 AM 0.2 1.8 0.0 -7.0 0.0 0.0 0.2 196.84 11:39:18AM 0.2 1.8 0.0 -20 0.0 41 0.2 221.78 11:39:31 AM 0.2 1.8 0.0 45.0 QO L.1 0.2 223.e8 11:39:4eAM 0.2 1.8 0.0 $0 0.0 -0.1 0.2 223.88 11:40:01 AM 02 1.8 0.0 3.0 0.0 d.1 0.2 22548 11:40:1eAM 0.2 1.9 0.0 40 0.0 -m1 02 224.84 11:40:31 AM 0.2 1.8 0.0 -20 0.4 3.8 0.2 22272 11:40:4e AM 0.2 1.9 0.0 0.0 0.4 7.7 0.0 17.29



# 19
P.o.1 

# Ov1213R2A

PILENAME 121326 LOCit31Nf3 SE 1 STARf LOOdNG (Q NN/NisM 12:3925: LA6T SMRE ® NMIM 13:52:11: ACTIVE QHW tA 19 2A 2B MODIA.E TYP Vcfap VoNP VofOP Votap SAhPLE RAT 16 sse 15 ssa 16 sse 16 sm W TS: Vds Nm Fpm Va[s CO, ppn Vais VOC, pan Vats S02, ppm 12113/1996 123928 PM 0.2 1.9 0.0 .10 02 1.8 QO 484

12:39:41 PM 02 1.8 0.0 5.0 0.2 1.7 0.0 878

- 1239:58 PM 0.2 1.8 0.0 6.0 0.3 29 0.0 -14.4

12:40:11 PM 0.2 1.7 0.0 -4.0 0.5 4.6 0.0 -13.44 12:4025 PM 1.8 15.8 0.1 58.0 a8 8.0 0.0 44.1e 1Z:40:41 PM 1.8 16.0 0.1 57.0 0.7 6.8 a1 S28 12:40:6ePM 1.8 16.2 a1 Sao 0.6 6.0 0.1 54.72 12•41:11 PM 1.8 18.3 a1 5&0 0.7 8.6 0.1 66.68 12:4128PM 1.8 1e.4 at 54.0 0.8 7.7 0.1 59.52 12:41:41 PM 1.8 1e.2 0.1 58.0 0.8 &1 0.1 69.52 12:41:58 PM 1.7 16.5 0.1 57.0 0.7 7.0 0.1 81.44 Strt R4 12:4211 PM 1.7 16.7 0.1 58.0 0.9 8.9 0.1 83.36

12:4228PM 1.7 1e.5 at Sao 0.9 8.8 a1 6a48 12:42:41 PM 1.7 16.9 0.1 80.0 0.6 &1 0.1 86.28 1242:58 PM 1.8 18.2 0.1 53.0 0.7 8.5 0.1 69.62 12:43:11 PM 1.7 16.6 0.1 56.0 0.7 7.0 0.1 91.44 12' .4328PM 1.7 19.8 ai 57.0 aa 8.4 0.1 924 12'43:41 PM 1.7 17.0 0.1 52o 0.e e.4 0.1 81.44 12:43:59PM 1.7 19.7 0.1 54.0 0.7 6.8 0.1 e24 12:44:11 PM 1.7 16.7 0.1 57.0 0.7 8.9 0.1 824 12:4428PM 1.7 1417 0.1 54.0 0.7 &e at 60.48 12:44:41 PM 1.7 1&5 0.1 57.0 0.8 e.3 0.1 64.32 12:44:58 PM 1.8 15.5 0.1 57.0 0.9 5.7 0.1 58.58 12:45:11 PM 0.e 5.9 0.0 320 1.0 10.2 0.0 34.5e 12'4628PM 0.6 5.4 0.0 36.0 0.8 7.5 0.0 13.44 12'45:41 PM 0.5 &1 0.0 33.0 1.1 11.0 a0 9.e 12:45:SBPM 0.8 0.1 0.0 38.0 aa 7.9 0.0 13.44 12:46:11 PM 0.e 6.4 0.0 40.0 0.9 9.4 0.0 - 16.32 12:4e2e PM 0.7 7.1 a0 40.0 1.2 124 0.0 21.12 124e:41 PM 0.8 7.5 QO 40.0 0.9 &8 0.0 25.92 12:48:56 PM 0.9 9.0 0.0 49.0 0.8 8.4 0.0 33.8 12'47:11 PM 0.8 8.2 0.0 40.0 0.8 7.5 0.0 34.5e 12'472ePM 0.9 8.8 0.0 40.0 0.e S6 a0 33.e 12'47:41 PM 0.9 9.1 0.0 43.0 0.7 6.6 QO 35.52 12•47:58 PM 0.9 8.7 0.0 38.0 0.9 &a 0.0 38.4 12•48:11 PM 0.8 8.4 0.0 37.0 0.7 7.0 0.0 30.72 124828 PM 0.9 9.1 0.0 44.0 0.8 62 0.0 31.88 12:48:41 PM 0.9 8.7 0.0 40.0 0.7 8.6 0.0 37.44 12:48:58PM 0.9 &8 0.0 4a0 0.7 9.7 0.0 3264 1249:11 PM 0.9 8.7 0.0 41.0 0.9 8.7 0.0 34.58 12:4925PM 0.8 8.4 0.0 39.0 0.7 7.1 0.0 36.52 12:49:41 PM 0.9 9.0 0.0 41.0 0.9 8.5 QO 3264 12:49:56PM 0.9 9.4 U.0 43.0 0.8 7.5 0.0 38.4 12:50:11 PM 20 19.9 0.1 69.0 0.5 52 0.1 74.a6 12:6028PM zo 19.7 at 57.0 0.5 4.7 0.1 84.08 12:50:41 PM 1.9 18.7 0.1 69.0 0.6 5.2 0.1 85.44 12:50:58 PM 1.8 18.4 0.1 53.0 0.7 &8

. 0.1 74.88 12:51:11 PM 1.9 1&8 0.1 $4.0 0.8 7.5 0.1 73.92 12•5128PM 1.8 18.2 0.1 5&0 0.7 6.8 0.1 69.12 12:51:41 PM 1.8 18.1 0.1 51.0 0.7 6.5 a1 85.24 12:51:58PM 1.8 18.4 0.1 Sa.O Qe 5.e 0.1 a&ta 12:52:11 PM 1.8 18.4 0.1 53.0 0.5 5.4 0.1 54.32 125228PM 1.9 18.5 0.1 51.0 0.5 4.0 0.1 88.24 12:52'41 PM 1.9 18.8 0.1 $4.0 0.5 4.7 0.1 ae.24 12:52:58PM 1.8 18.1 0.1 S.10 0.7 &7 0.1 84.32 1253:11 PM 1.9 18.5 0.1 61.0 0.8 &a 0.1 a824 12:5328 PM 1.9 18.5 at 57.0 0.7 7.2 0.1 93.3e 1253:41 PM 1.8 182 0.1 szo 0.7 7.2 at 6136 12:53:56PM 1.9 18.6 0.1 64.0 0.e 0.4 0.1 98.24 1254:11 PM 1.9 18.9 at 57.0 0.5 5.2 0.1 a3.3e 125420PM 1.9 1&8 ai 63.0 ae 6.4 Qt 67.2 12'54:41 PM 1.9 16.5 a1 57.0 0.7 7.1 at 65.28 12:54:58 PM 1.9 1&9 0.1 5&0 0.7 7.4 0.1 63.38 1255:11 PM 1.9 19.0 0.1 $4.0 0.7 8.8 0.1 68.24 12:6625PM 1.9 18.9 0.1 6&0 0.7 e.e 0.1 64.32 12:55:41 PM 1.9 19.2 0.1 5&0 0.7 6.9 0.1 84.32 12:55:5ePM 1.9 1&8 at 57.0 0.7 E4 0.1 e72 12:56:11 PM 1.9 19.o at 60.o 0.e 5.7 0.1 66.28 125828PM 1.9 19.2 at 57.0 0.e 5.7 0.1 69.12 12:5e:41 PM 1.9 1&8 0.1 6&0 0.5 3.3 0.1 88.24 12:56:66PM 1.9 1&7 0.1 67.0 0.e e.0 0.1 98.24 12:57'.11 PM 1.9 1e.e 0.1 56.0 0.7 6.6 LLt 68.1e 12:5720 PM 1.9 18.e 0.1 68.0 0.e 6.4 0.1 66.28 12:57:41 PM 1.9 19.0 0.1 5&0 0.5 5.4 0.1 57.2 12:57:5ePM 1.9 18.7 at 56.0 0.7 7.2 at eale 12:58:11 PM 1.9 18.9 0.1 eao 0.7 7.4 0.1 $4.32 12:5825PM 1.9 1&8 0.1 S&0 0.8 7.8 0.1 99.12 12:68:41 PM 1.9 19.1 0.1 59.0 Qe 62 a1 68.24 12:58:56PM 1.9 19.0 0.1 69.0 0.8 5.6 0.1 67.2 12:59:11 PM 1.9 18.7 0.1 ea0 0.e 6.1 0.1 58.1e 12:5925PM 1.9 18.7 at at.0 aa 5.7 0.1 6628 - 12:59:41 PM 1.9 19.0 0.1 59.0 0.6 5.3 0.1 69.12 12:59:58PM 1.9 18.7 Qt e1t0 0.7 7.1 0.1 57.2 1:00:11 PM 1.9 1&9 0.1 a3.0 0.9 9.2 0.1 65.26 1:0025PM 1.9 16.7 at 60.0 0.8 &0 0.1 09.12 1:00:41 PM 1.9 18.7 0.1 59.0 0.7 7.3 0.1 64.32 1:00:5ePM 1.9 1&8 0.1 a2o 0.7 bt 0.1 67.2 1:01:11 PM 1.9 1&e 0.1 6&0 0.7 8.7 0.1 e7.2 1:0115PM 1.9 1&a 0.1 66.0 0.e 6.9 at 54.32 1:01:41 PM 1.9 18.7 0.1 e1.0 0.5 5.2 0.1 e&1e 1:01:5ePM 1.9 1&e 0.1 5&0 0.7 e.8 a1 05.24 

# 20 p- 

# ~1213faA

1:02:11 PM 1.9 18.8 a1 e2.0 0.5 41 a1 6428 1:022ePM 1.9 18.8 at eao 0.5 4.6 0.1 98.16 1:02:41 PM 1.9 18.6 0.1 59.0 a5 4.8 0.1 6428 1:02:58PM 1.9 1&8 0.1 64.0 0.9 8.0 0.1 67.2 1:03:11 PM 1.9 18.7 0.1 a0.0 0.8 7.e 0.1 67.2 1:0328 PM 1.9 18.8 0.1 59.0 0.8 7.7 0.1 88.24 1:03:41 PM 1.9 18.6 0.1 e4.0 0.9 9.2 0.1 89.12 1:03:5ePM 1.9 1&e 0.1 Bz0 0.9 &5 0.1 96Z4 1:04:11 PM 1.9 1&7 0.1 90.0 a9 8.7 0.1 e7.2 1:0428PM 1.9 18.7 0.1 e40 0.7 7.1 ai 641e 1:04:41 PM 1.9 18.9 0.1 ez0 Qe 44 0.1 6e.24 1:04:56 PM 1.9 19.0 0.1 61.0 0.e 6.9 0.1 e9.12 1:06:11 PM 1.9 19.2 0.1 ee.0 0.e 4e 0.1 67.2 1:0625PM 1.9 1&e 0.1 e1.0 0.7 7.0 a1 e7.2 1:05:41 PM 1.9 1&9 at 66.0 ae 6.2 0.1 641e 1:06:6ePM 1.9 t9.o ai 91.0 a6 40 0.1 97.2 1:06:11 PM 1.9 19.4 0.1 5&0 0.6 4.9 a1 70.08 1:0e26PM 1.9 19.0 0.1 91.0 ae 7.6 0.1 70.08 1:09:41 PM 1.9 1&9 0.1 59.0 0.7 7.2 0.1 9&16 1:08:56 PM 1.9 19.4 0.1 91.0 a9 9.1 0.1 71.04 1:07:11 PM 1.9 19.4 0.1 94.0 0.7 7.1 0.1 68.16 1:0725PM 1.9 19.0 a1 e1.0 aa &2 ai 69.12 1:07:41 PM 1.9 19.1 0.1 940 0.6 5.9 a1 70.08 1:07:5ePM 1.9 19.4 0.1 B5.0 ae 46 0.1 641e 1:08:11 PM 1.9 19.2 a1 620 0.9 49 0.1 71.04 1:082e PM 1.9 19.3 0.1 640 0.e 46 0.1 99.12 1:08:41 PM 1.9 19.3 0.1 e20 0.8 45 0.1 6412 1:08:56PM 1.9 192 0.1 63.0 0.6 48 at 72 1:09:11 PM 1.9 1&9 0.1 940

. 0.7 4e 0.1 e&12 1:0926PM 1.9 19.1 0.1 B3.0 0.5 5.3 0.1 69.12 1:09:41 PM 1.9 19.0 0.1 ez0 0.6 43 a1 70.08 1:09:6ePM 1.9 19.3 0.1 640 ae 42 0.1 641e 1:10:11 PM z0 19.E at 61.0 0.5 4.7 0.1 71.04 1:102ePM 1.9 19.2 0.1 920 0.6 49 0.1 71.04 1:10:41 PM 20 19.6 0.1 e2o ae S.e 0.1 e9.12 1:10:5ePM 20 19.6 0.1 aQo 0.6 41 0.1 72 1:11:11 PM z0 19.8 0.1 69.0 0.6 48 0.1 6&12 1:112ePM 20 19.8 0.1 Q40 0.7 48 at 72 1:11:41 PM 20 20.0 0.1 ez0 0.7 46 - 0.1 71.04 1:11:5ePM 2o 20L1 0.1 eao 0.6 5.6 0.1 7a0e 1:12'11 PM 20 20.1 at e&0 Qe 49 0.1 729e 1:1226PM 20 20.4 0.1 61.0 0.9 42 a1 72 1:12:41 PM 20 20.0 0.1 84.0 0.7 6.7 a1 73.92 1:12sePM 20 2a3 at 63.0 0.7 4s ai 72.9e 1:13:11 PM zt 20.6 0.1 az0 0.6 8.4 0.1 71.04 1:1328PM 21 20.6 0.1 e40 0.7 7.1 a1 74.a8 1:13:41 PM 21 20.6 0.1 e3.0 0.6 41 ai 729e 1:13:SePM z1 20.6 0.1 e20 0.7 &8 a1 729e 1:14:11 PM 21 2a7 0.1 87.0 a7 7.1 0.1 76.8 1:1428PM 21 20.6 a1 83.0 0.e 49 0.1 7296 1:14:41 PM 21 20.8 0.1 63.o QS 43 a1 7484 1:14:5e PM 21 20.6 0.1 67.0 Qe 6.0 0.1 74.88 1:15:11 PM z1 20.8 0.1 Bz0 0.9 E.0 0.1 73.92 1:152ePM z1 20.5 0.1 64.0 a6 40 a1 77.76 1:15:41 PM 21 20.8 0.1 67.0 0.6 5.5 0.1 74.88 1:15:56PM z1 20.7 Qt 820 0.5 5.0 0.1 7484 1:16:11 PM 21 21.3 at e40 0.5 4.a 0.1 74a 1:1e28PM z1 21.1 0.1 67.0 0.5 40 0.1 7484 1:19:41 PM 21 21.0 0.1 91.0 Qe Se 0.1 77.76 1:1e:5ePM zt 21.4 0.1 e40 ae 6.7 at 748 1:17:11 PM 21 21.0 0.1 e3.0 ab 7e a1 70.8 1:1728 PM 21 21.1 0.1 e3.0 0.7 48 0.1 76.72 1:17:41 PM 21 21.3 Qi 67.0 0.6 41 0.1 74&1 1:17:58PM zt 21.2 at 64.0 0.7 6.e a1 746 1:ta:11 PM 21 21.1 0.1 94.0

. ae 6.4 a1 78.72 1:192ePM z1 21.0 0.1 940 0.7 8.7 at 78.8 1:18:41 PM 21 21.1 0.1 a4o 0.7 4e 0.1 8064 1:1a:6ePM 21 20.3 0.1 e3.0 0.6 6.4 0.1 77.7e 1:19:11 PM zt 21.3 41 e&o 0.7 7.0 0.1 7472 1:192ePAA 21 20.9 at e3.0 0.7 e.8 a1 a1.e 1:19:41 PM 21 21.2 0.1 67.0 ae 6.2 0.1 77.7e 1:19:5ePM 21 21.0 0.1 62o

. 0.e 5.9 0.1 79.68 120:11 PM 21 21.0 0.1 a2.0 0.7 7.0 0.1 79.68 1202ePM 21 21.4 0.1 e&0 0.7 4a ai 77.7e 120:41 PM z1 20a 0.1 03.0 aa 7.6 0.1 a2se 120:5ePM 21 21.1 0.1 61.0 0.9 9.0 0.1 78.72 121:11 PM 21 20.8 0.1 a4o aa 7.7 0.1 80.64 

### 1212ePM z1 20.e at 6Ro aa 7.7 ai aae4 121:41 PM z1 218 0.1 e7.0 0.7 7.2 0.1 77.7e 121:6ePM 21 2ae ai a4o 0.7 6.8 ai 81.e 1=11 PM 21 2a6 0.1 67.0 0.7 46 a1 78.72 1 11 2 1 ePM 21 20.7 0.1 e&0 0.6 e.3 0.1 7&72 1:22:41 PM z1 20.6 a1 e40 0.6 42 0.1 80.04 1325ePM z0 20.3 0.1 e&o 0.0 6.e a1 77.7e 123:11 PM 21 20.e 0.1 67.0 ae 46 0.1 aae4 12338PM 21 2aa at a&o a6 41 a1 7472 123:41PM 20 20.2 0.1 a40 0.6 40 0.1 748 123:6ePM 20 212 0.1 640 0.5 6.4 0.1 78.72 1' .24:11 PM 2o 2110 0.1 a40 ae 44 ai 748 12428PM 20 20.0 0.1 67.0 0.6 5.0 0.1 77.7e 124:41 PM 2o 19.6 0.1 e40 0.6 4.7 0.1 77.76 124:5ePM z0 19.9 0.1 eao 0.6 4.6 0.1 76.64 126:11 PM zo 212 0.1 64.0 0.6 4.e 0.1 7&72 12695PM 2o 2a0 a1 e&0 0.6 4.7 a1 748 125:41 PM 1.9 1&3 0.1 ee.o ae 47 0.1 7e.8 125:5ePM zo 19.6 at 6&0 0.4 4.2 Qi 77.7e 12e:11 PM zo t&7 0.1 Q&0 0.5 4.9 0.1 74.68 1282ePM 2o 19.6 0.1 70.0 0.4 4.4 0.1 7e.8 12e:41 PM 1.9 19.3 a1 6&0 0.6 43 0.1 75.94 12e:68PM 1.9 114 0.1 720 a6 40 0.1 74.88 127:11 PM 1.9 149 0.1 64.0 0.4 4.1 a1 77.76 12726PM 1.9 111 0.1 09.0 0.6 4.7 0.1 73.92 127:41 PM 1.9 18.9 0.1 70.0 a6 &1 0.1 76.84 

# 21

~ P~ 21213R2A

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1:43:11 PM zo 2a4 0.1 64.0 0.3 27 0.1 7&72 1:4328PM zo 20.3 0.1 88.0 0.4 319 0.1 91.8 1:43:41 PM z0 20.2 0.1 87.0 0.7 7.0 0.1 79.88 1:43:58PM zo 2a0 0.1 64.0 0.6 4.9 0.1 at.e 1:44:11 PM 20 19.9 0.1 6&0 0.6 5.6 0.1 79.6a 1:4428 PM 1.3 126 0.1 64.0 a6 4.9 0.1 76.6 1:44:41 PM 0.2 z3 0.0 3&0 0.4 4.2 0.1 a0.64 1:44:56PM 02 z1 0.0 11.0 0.4 3.8 0.0 z8a 1:46:11 PM o.2 zt 0.0 &0 0.4 3.9 0.0 3.84 1:4526 PM 0.2 zo 0.0 14.0 0.4 4.2 0.0 4.6 1:45:41 PM 0.1 1.3 0.0 10.0 0.4 3.9 0.o zB6 1:45:58 PM 0.1 1.3 0.0 9.0 0.4 3.a 0.0 3.84 1:48:11 PM 0.1 1.3 0.0 13.0 a4 A7 0.0 1.92 1:4626PM 3.7 37.1 0.0 9.0 0.0 0.0 a0 1.92 1:46:41 PM 3.3 3zs 0.0 .1.o 0.0 0.0 Qo z86 1:48:56PM 3.2 3z4 0.0 d.0 0.0 0.0 QO 0.98 1:47:11 PM 3.2 32.3 0.0 -4.0 0.0 a0 0.0 z86 1:4728 PM 3.2 31.9 0.0 4.o 0.2 1.6 0.0 1.92 1:47:41 PM 0.1 0.8 0.0 3.0 0.3 3.2 0.0 1.92 1:47:58PIM 0.1 a6 0.0 3.0 27 27.1 ao 298 1:48:11 PM 0.1 0.5 a0 8.0 z8 28.4 0.o 0 1:4926PM 0.1 0.5 QO -10 2.9 28.8 0.0 1.92 1:48:41 PM 0.0 a4 0.0 1.0 29 2&9 0.0 2.Ba 1:48:58PM 0.0 0.4 0.0 20 29 `8.7 0.0 0.98 1:49:11 PM 0.0 0.4 0.0 -1.0 a4 .7 ao 3.64 1:4928PM ao 0.4 ao &o ao 0.0 0 1:49:41 PM 0.0 0.3 0.1 89.0 QO o.! ao -1.92 1:49:56 PM 0.0 0.4 0.1 98.0 0.0 0.:: 0.0 1.92 1:50:11 PM QO 0.4 0.1 1o1.-^ 0.0 0-0 0.0 1.92 1:5026PM 0.0 a4 0.1 98.0 ao aG 0.0 4.9 1:50:41 PM ao 0.3 0.1 97.0 0.0 0.0 0.0 288 1:50:58PM 0.0 0.4 0.0 14.0 0.0 0.0 0.1 az56 1:51:11 PM 0.0 0.2 0.0 -20 0.0 0.1 0.2 221.78 1:5128PM 0.0 0.2 0.0 -zo ao -0.1 0.2 228.56 1:51:41 PM 0.0 a3 0.0 J.o 0.0 -0.1 0.2 230.4 1:51:56PM 0.0 0.3 0.0 -zo 0.0 Q7 0.2 230.4 t:6z'11 PM 0.0 0.3 0.0 5.0 0.0 a1 0.2 231.38

22 

# ®

PUM31213R3

FILENAME 1213/3 LOf3GOJO SE 1 START LOG(31N0 ® MNBYN 13:S2:58: LAST SAWPLE ® MMA4MMI 16:14:58: A011VE CFM 1A 18 ?A 2B MODU.E TY Valep Vofap Vdam VdaP SAMPLE RAT 16 esc 16 ae 15 no 76 aeo WTB: Vds NOY, ppm Vata 00, ppm Ve1s VOC, ppm VWS S02, ppm 1211311996 1:SZ:66PM 0.0 0.3 ao .l0 0.3 3.1 0.0 3.84

1:63:13PA1 a3 3.3 0.0 -zo 0.6 6.2 0.0 8.7e 1:5326PM 1.9 180 0.1 50.0 a7 7.2 0.1 8268 1:53:43PM 1.9 19.0 0.1 6ao a7 a8 0.1 100.8 1:53:56PM 1.9 19.1 0.1 66.a ae 8.0 a1 9184 1:64:13PM 1.9 192 a1 69.0 0.6 6.0 0.7 101.7e 1:5428PM 1.9 19.0 0.1 57.0 0.0 8.0 at 1aa8 - 1:54:43PM 1.8 17.8 0.1 59.0 0.7 7.3 0.1 97.92 1:54:68 PM 1.7 17.1 0.1 81.0 a8 7.8 0.1 97.92 1:66:13 PM 1.7 17.0 a1 S8.0 0.7 7.0 0.1 97.92 1:5628 PM 1.7 18.9 at 83.o 0.7 8.7 0.1 9&68 1:55:43 PM 1.6 182 a1 56A 0.7 7.1 0.1 101.78 1:55:58PM 1.8 18.9 0.1 Sa0 0.8 0.1 0.1 86.68 1:58:13PM 1.9 10.1 0.1 fia0 0.5 6.4 0.1 103Ae 1:5828PM 1.8 15.8 0.1 6flo 0.5 5.4 a1 100.8 1:58:43PM 1.7 16.8 0.1 5&0 0.4 4.2 ai 10272 1:56:58PM 1.8 17.7 0.1 61.0 0.4 4.4 at 111.38 Start R3 1:57:13PM 1.8 17.7 0.1 58.0 0.8 5.8 a1 109.44

1:5728PM 1.8 /6.1 0.1 61.0 aG 6.7 0.1 110.4 1:57:43PM 1.8 18.1 0.1 59.0 0.8 6.6 0.1 108.6E 1:57:56Ph1 1.8 18.0 0.1 57.0 0.5 Sa 0.1 103.88 1:56:13PM 1.8 18.1 0.1 59.0 0.5 4.8 0.1 10Q58 1:58:28 PM 1.8 182 0.1 820 0.8 6.1 0.1 101.75 1:68:43PM 1.8 182 a1 SAO 0.8 8.4 0.1 103.88 1:58:66PM 1.8 18.0 0.1 63.0 0.8 6.4 0.1 10272 1:59:13PM 1.8 18.0 a1 8a0 0.6 6.4 0.1 100.8 1:5928PM 1.8 16.0 0.1 fiaa 0.8 S8 0.1 10.1.68 1:59:43PM 1.8 17.5 a1 86.0 0.6 6.0 0.1 100.8 1:59:68PM 1.8 17.5 0.1 6a0 0.4 4.4 0.1 9d86 2A0:13PM 1.7 17.4 at 820 0.4 4.2 0.1 100.8 20028PM 1.7 17.4 0.1 60.0 0.3 3.4 0.1 98.96 2:00:43PM 1.7 17.2 at 57.0 0.4 3.8 0.1 99.64 2:00:58PM 1.7 17.4 a1 83.0 0.4 3.7 0.1 9d88 201:13PM 1.7 17.1 a1 61.0 0.8 S8 a1 96.98 2•0128PM 1.7 17.2 a1 64.0 0.8 Q2 at 99.64 2:01:43PM 1.7 iS8 0.1 87.o ae 6.7 0.1 96.04 2:01:58 PM 1.7 18.7 0.1 81.0 G.5 5.3 0.1 96 2:02:13 PM 1.7 147 0.1 84.0 0.5 6,4 0.1 96.04 2:0228 PM 1.7 1Q6 0.1 61.0

. a6 5.8 0.1 94.08 2'0Z:43 PM 1.6 1E.4 a1 62.0 0.7 6.7 a1 96.04 2•02:58PM 1.8 18.3 0.1 86.0 0.7 8.8 at 912 203:13PM 1.6 16.3 a1 83.0 0.7 8.8 U.1 921E 20326PM 1.8 /8.2 0.1 88.0 0.8 0.1 0.1 91.2 2'03:43PM 1.8 16o at 830 a8 Q2 0.7 90.24 2•03:58PM 1.8 18.0 0.1 810 0.8 S9 0.1 93.12 2:04:13PM 1.8 182 ai 88.0 0.7 6.7 0.1 9a24 20428PM 1.8 1S9 0.1 82A 0.7 6.7 0.1 80.28 204:47PM 1.6 15.8 ai 68.0 0.8 7.6 0.1 91.2 204:58PM 1.6 15.8 a1 64.0 0.7 7.0 0.1 8932 2'05:13PM 1.5 1S2 0.1 60.0 0.7 7.3 a1 89.28 20528PM 1.5 1S2 a1 64.0 0.8 61 ai 87.38 2:06:43PM 1.5 16.4 at 61.0 0.8 5.9 0.1 87.38 205:58PM 1.5 15.4 0.1 83.0 0.7 8.7 a1 89.28 2:06:13PM 1.5 15.2 0.1 66.0 0.7 8.7 0.1 86.44 2•0828PM 1.6 1A2 at aza QO S7 0.1 8532 2'08:43 PM 1.5 16.1 0.1 67.0 0.6 8.4 0.1 86.44 2•08:58PM 1.8 16.0 0.1 8a0 0.6 6.8 0.1 85.44 2•07:13 PM 1.5 16.1 0.1 SS.O 0.8 6.6 0.1 87.36 2•0728 PM 1.5 1l9 0.1 860 0.Q S9 0.1 81.48 2:07:43 PM 1.6 14.9 0.1 64.0 o.e 63 0.1 6{.48 2•07:58PM 1.5 16.4 0.1 69.o 0.e A9 a1 88.4 2'08:13 PM 1.5 16.0 0.1 610 0.6 8.3 0.1 84.48 2:0828PM 1.5 14.8 0.1 630 0.8 7.8 a1 87.3E 208:43 PM 1.6 14.7 0.1 880 0.8 7.8 0.1 64.46 2'oe:58PM 1.5 14.8 0.1 661.0 0.7 7.1 a1 84.48 2:09:13PM 1.6 16.0 0.1 64.0 0.6 8.2 0.1 86.44 2:0928PM 1.6 14.9 a1 86.0 0.8 8.4 a1 82.58 2:09:43 PM 1.6 16.0 0.1 62.0 0.8 8.1 0.1 84.48 - 2:09:58PM 1.6 14.6 0.1 86.0 0.7 8.6 a1 83.52 2.•10:13PM 1.6 14.8 0.1 610 a0 8.1 0.1 8268 2•1028 PM 1.6 14A 0.1 84.0 0.8 6.9 0.1 84.48 210:43 PM 1.6 15.0 0.1 88.0 0.8 6.8 0.1 8258 - 2:10:58 PM 1.5 16.0 0.1 820 0.6 6.7 0.1 64.48 2:11:13PM 1.3 16.0 0.1 87.0 0.7 0.7 0.1 83.52 2:1128PM 1.6 16.0 0.1 80.0 0.7 8.6 0.1 81.6 2:11:43PM 1.6 14.7 ai 86.0 a6 7.6 0.1 66.44 211:68PM 1.5 1S0 0.1 69.0 0.7 6.8 0.1 81.6 212:13PM 1.5 14.8 0.1 8S0 0.7 6.5 a1 8258 21228PM 1.5 14.8 0.1 69.0 0.8 8.o a1 8258 2:12:43PM 1.6 14.9 at 69.0 0.8 8.4 a1 81.8 212:58 PM 1.6 14.8 0.1 810 0.8 7.7 a 1 84.48 2:13:13PM 1.6 14.9 0.1 70.0 0.8 7.7 ai 8258 2:1328PM 1.6 76.2 0.1 64.0 0.7 7.2 0.1 6258 2:13:43 PIN 1.5 16.0 0.1 66.0 0.7 Q6 0.1 64.46 213:Sfi PM 1.6 14.9 0.1 67.0 0.7 8.7 0.1 61.6 2•14:13 PM 1.5 14.6 0.1 84.0 0.7 6.8 0.1 83.52 2:1428 PM 1.5 14.8 0.1 86.0 0.7 8.8 0.1 81.8 2:14:43PM 1.5 14.6 0.1 8S0 a6 8.1 0.1 80.84 2:14:58PM 1.5 14.8 a1 86.0 0.8 8.0 0.1 64.48 215;13PM 1.5 14.9 0.1 89.0 aC 6.7 0.1 81.8 21628 PM 1.6 14.9 0.1 86.o 0.7 66 at 8152

23 e -//-1213R3

215:43PM 1.5 14.9 0.1 7Q0 0.8 7.9 0.1 83.62 2'15:58 PM 1.5 14.7 0.1 70.0 0.8 A3 0.1 81.6 2:16:13 PM 1.5 14.8 0.1 84.0 0.8 7.9 0.1 83.52 2•1828 PM 1.5 14.8 0.1 70.0 0.6 5.8 0.1 81.0 218:43 PM 1.6 16.0 0.1 64.0 0.6 5.5 0.1 81.8 218:58PM 1.5 14.7 at 8A0 0.9 8.4 at 83.52 2'17:13PM 1.5 14.8 ai 70.0 ae 7.7 a1 8ae4 2'1728 PM 1.6 15.0 0.1 87.0 a8 A4 0.1 64.48 2'17:43 PM 1.5 14.8 0.1 67.0 0.7 8.5 0.1 83.52 217:68PM 1.5 15.0 a1 71.0 0.8 8.3 0.1 8258 2•18:13 PM 1.5 16.1 0.1 aAo 0.6 5.7 0.1 8A44 21828PM 1.5 tAt at 88A 0.6 AO a1 825e 2:18:43PM 1.6 1A0 0.1 86.0 0.6 A2 0.1 83.52 2•18:58PM 1.5 14.6 0.1 64.0 0.8 8.4 at 83.62 119:13PM 1.5 14.8 0.1 68.0 0.8 5.9 0.1 Ba84 21928PM 1.6 1A0 0.1 84.0 0.8 8.4 0.1 83.62 2:19:43PM 1.5 110 0.1 64.0 0.7 6.5 a1 81.e 219:68 PM 1.5 16.2 0.1 BAO 0.7 9.7 0.1 6258 220:17 PM 1.6 14.8 0.1 86.0 0.8 7.5 0.1 83.52 22028PM 1.5 14.8 0.1 89.0 0.8 7.6 a1 8a64 220:43PM 1.5 1so 0.1 87.0 0.7 7.0 0.1 83.6z 220:68PM 1.5 1So 0.1 BAO a7 A8 0.1 81.6 221:13PM 1.5 1A0 0.1 68.o a7 7.0 0.1 Bae4 22128PM 1.4 14.0 0.1 67.0 0.7 e.e a1 825e 221:43PM 1.3 13.4 0.1 86.0 0.8 8.4 0.7 75.84 221:68 PM 1.3 13.4 0.1 720 0.7 8.9 0.1 77.76 22213PM 1.4 13.3 0.1 8e.0 0.8 7.7 0.1 77.7a 22228 PM 1.4 13.8 0.1 71.0 0.8 8.2 0.1 77.76 222:43 PM 1.3 13.4 0.1 69.0 a7 7.2 0.1 81.8 222:58PM 1.4 13.8 0.1 6A0 0.8 5.8 0.1 7A72 223:13PM 1.4 1a7 0.1 6A0 0.7 7.0 0.1 80.84 22328PM 1.5 14.6 0.1 84.0 0.7 9.e 0.1 81.e 223:43PM 1.5 14.9 0.1 87.0 ae A2 0.1 81.6 223:58PM 1.5 1S3 0.1 e4.0 O.a 5.9 ai Be.4 224:13 PM 1.6 14.9 0.1 9A0 0.7 8.9 0.1 8A44 22428 PM 1.6 14.9 0.1 8A0 a8 8.0 0.1 64.48 224:43 PM 1.6 15.1 0.1 97.0 0.0 S.e 0.1 84.48 224:68PM 1.5 1A0 a1 BAO 0.8 6.1 a1 8258 226:13PM 1.5 14.8 0.1 7a0 0.e 6.a a1 84.48 22528PM 1.6 1A1 0.1 B6.0 a5 4.7 0.1 62.Sa 225:43PM 1.5 1A0 0.1 e9.0 0.6 4.8 0.1 81.e 226:58PM 1.5 1A1 0.1 87.0 a6 4.6 0.1 83.52 228:13PM 1.6 1S1 0.1 69.0 0.4 3.9 0.1 81.8 22828 PM 1.5 16.2 0.1 89.0 0.4 4.1 a1 83.52 228:43PM 1.6 15.1 0.1 Ba.o 0.8 AO 0.1 8259 228:68PM 1.5 14.9 a1 69.0 0.7 6.7 0.1 8a84 227:13PM 1.5 14.9 0.1 84.0 0.6 5.7 Qi 8258 22728 PM 1.5 14.9 0.1 88.0 0.e S7 0.1 80.64 227:43PM 1.5 1s0 0.1 8A0 0.7 7.0 0.1 81.6 227:58PM 1.5 tAt 0.1 64.0 0.7 Aa 0.1 8268 226:13PM 1.5 16.0 0.1 8A0 a7 7.0 0.1 Ba64 22828PM 1.5 1A3 0.1 BAo 0.8 AO 0.1 8162 22B:43PM 1.5 16.2 0.1 8a0 a7 7,4 0.1 826a 226:58PM 1.5 16.1 0.1 89.0 0.e 6.4 a1 62.55 229:13PM 1.5 15.3 0.1 67.0 a7 8.7 0.1 8A62 22026PM 1.3 1S3 0.1 Ba.O 0.8 5.9 0.1 81.8 229:43PM 1.5 15.2 0.1 69.0 0.e 5.5 0.1 83.62 229:56PM 1.5 15.4 at 87.0 0.6 4.8 0.1 83.62 230:13PM 1.9 1S6 0.1 8A0 0.8 6.0 0.1 61.8 2:3028 PM 1.6 15.3 0.1 71.0 a6 5.2 0.1 ' 8A4 2'30:43PM 1.8 15.7 0.1 87.0 0.5 5.0 0.1 83.62 230:58PM 1.6 1A0 0.1 89.0 0.8 5.2 0.1 83.52 231:13PM 1.6 1Ci7 0.1 67.0 0.6 5.0 0.1 84.48 2'3128 PM 1.8 18.0 0.1 87.0 O.a 5.5 0.1 825a 271:43 PM 1.8 16.0 0.1 8A0 0.e 6.3 0.1 814 231:58PM 1.6 16.4 0.1 67.0 0.7 6.6 0.1 84.48 232'13PM 1.8 15.7 0.1 83.0 a7 7.2 0.1 83.52 2:3228PM 1.5 1A4 0.1 87.0 0.9 A5 0.1 8A44 232:43PM 1.3 16.2 0.1 84.0 U.8 A4 0.1 83.62" 23258PM 1.e 1A6 0.1 BAo 0.8 7.7 a1 85.44 233:13PM 1.9 1A7 0.1 97.0 0.6 6.1 0.1 l25e 23328PM 1.6 1A8 0.1 BAO 0.7 8.8 0.1 83.62 233:43PM 1.6 1A7 0.1 8Ao ae 9.0 a1 Ba4 2:33:66PM 1.8 tAt 0.1 87.0 0.8 AS 0.1 84.48 234:13PM 1.6 15.e 0.1 610 0.8 A1 0.1 68.4 23428PM 1.e 18.0 0.1 69.0 0.7 7.1 0.1 87.3e 2:34:43PM 1.e 1S9 0.1 8a.0 0.8 A1 0.1 8A4 234:58 PM 1.6 18.1 0.1 67.0 0.7 7.2 0.1 90.24 236:13PM 1.8 149 a1 6A0 0.7 7.3 0.1 8A32 2:3628 PM 1.e 16.0 a1 aRo 0.6 8.3 0.1 8A32 2'35:43 PM 1.8 1A0 0.1 86.0 0.8 6.0 0.1 69.28 2:36:68PM 1.7 18.5 0.1 89:0 0.7 8.e a1 87.35 23e:13PM 1.8 18.1 0.1 aQo 0.e 9.0 0.1 9a24 23e28PM 1.8 1A4 0.1 0A0 0.0 A2 a1 8A28 238:43PM 1.9 18.3 0.1 66.0 0.e Aa 0.1 8928 23e:58PM 1.9 1A3 0.1 87.0 0.e A7 0.1 93.12 2:37:13PM 1.7 18.e 0.1 8Ao 0.e S5 0.1 89.28 2:3728 PM 1.8 1e.3 0.1 63.0 0.7 6.8 0.1 91.2 2:37:43 PM 1.9 1113 0.1 69.0 0.8 8.4 0.1 92.18 2:37:68 PM 1.7 1A6 a1 84.0 0.5 s.s 0.1 9a24 238:13 PM 1.7 1A8 G.1 ae.o 0.5 4.9 0.1 94.06 23828PM 1.7 17.1 a1 71.0 0.e 6.3 0.1 90.44 2'38:43 PM 1.7 16.6 0.1 64.0 ae A4 0.1 91.2 238:58PM 1.7 16.6 0.1 ed0 0.8 6.8 0.1 94.08 239:13 PM 1.9 1A4 0.1 59.0 0.5 A2 a1 91.2 2:3920 PM 1.7 1e.7 a1 67.0 0.6 6.1 0.1 93.12 239:43PM 1.7 16.9 0.1 70.0 U.7 8.6 0.1 91.2 239:58 PM 1.7 16.8 0.1 67.0 0.7 6.8 0.1 91.2 240:13PM 1.7 18.6 0.1 66.0 0.7 A6 G.1 94.08 24026PW 1.7 17.2 0.1 7Q0 0.8 0.2 at 9218 240:43PM 1.7 16.9 0.1 a3.0 0.6 6.4 0.1 93.12 2:40:58PM 1.7 18.7 at 71.0 ae A4 0.1 93.12 241:13PM 1.7 17.1 0.1 e3.0 0.6 A4 0.1 91.2 

# 24 ~5~1213R3

24128PM 1.7 17.0 0.1 e3.o a8 5.9 a1

. 94.08 2:41:43 PM 1.7 17.0 0.1 8&o ao 8.2 0.1 921E 2:41:58PM 1.7 17.1 0.1 65.0 as 5.0 0.1 91.2 2:4213PM 1.7 17.3 0.1 8&0 0.6 5.1 a1 91.2 2•4228PM 1.7 18.8 0.1 a3.0 a5 S.0 0.1 9024 242:43 PM 1.7 18.8 0.1 8&0 0.5 4.8 0.1 91.2 2:42:58 PM 1.7 168 0.1 8&0 0.5 4.8 0.1 89.28 2:43:13 PM 1.8 18.2 0.1 81.0 0.8 &1 0.1 89.28 2:4328 PM 1.7 18.8 0.1 8&0 0.7 7.2 0.1 90.24 243:43 PM 1.7 18.8 0.1 93.0 0.7 6.6 0.1 88.32 243:68 PM 1.7 18.7 0.1 64.0 0.5 6.3 0.1 91.2 2'44:13 PM 1.7 18.8 0.1 89.0 a8 8.3 0.1 9&32 24428PM 1.7 18.5 0.1 8Q0 0.7 e.s 0.1 80.4 2:44:43PM 1.7 18.6 0.1 68.0 0.8 5.9 0.1 89.28 244:58 PM 1.6 18.1 0.1 64.0 0.8 8.2 0.1 86.44 2:46:13PM 1.8 16.1 0.1 820 0.8 6.8 0.1 87.35 24628 PM 1.7 1Q8 a1 aRo 0.6 - 6.1 0.1 88.4 245:43 PM 1.8 18.3 0.1 63.0 0.8 flo at 83.62 2:48:58 PM 1.7 1&9 0.1 a8.o 0.8 6.8 a1 88.4 2:48:13PM 1.7 169 0.1 a20 0.7 6.8 0.1 8258 2•4828 PM 1.7 17.0 0.1 83.0 0.8 5.2 0.1 83.52 2'48:43 PM 1.7 17.0 0.1 88.0 0.7 8.8 0.1 84.48 2:48:58 PM 1.7 17.2 0.1 84.0 0.7 B.8 0.1 8258 247:13 PM 1.7 17.3 0.1 BQO 0.7 8.8 0.1 85.44 24728 PM 1.7 17.2 0.1 85.0 0.8 5.9 0.1 8&44 247:43 PM 1.7 17.2 0.1 67.0 0.0 5.6 0.1 64.48 247:58 PM 1.7 17.1 0.1 85.0 0.7 8.8 0.1 89.28 2'48:13 PM 1.7 17.3 0.1 8&0 0.7 7.2 0.1 85.44 24828 PM 1.7 17.4 0.1 - B&0 0.7 8.9 0.1 88.32 2:48:43 PM 1.7 17.3 0.1 87.0 0.8 7.9 0.1 88.32 2:48:58PM 1.7 17.3 0.1 83.0 0.8 &0 a1 88.4 249:13 PM 1.8 17.5 0.1 70.0 0.7 6.9 0.1 90.24 2:4928 PM 1.8 17.5 0.1 88.0 0.7 6.7 0.1 87.38 2:49:43PM 1.8 17.7 0.1 a9.0 0.8 &1 0.1 8&32 2'49:58PM 1.0 9.8 0.1 83.0 0.9 &8 0.1 , 8a24 2•50:13PM 0.8 &4 0.0 41.0 0.7 8.8 0.1 87.38 25028PM 0.7 8.5 0.0 47.0 0.5 5.4 ai 90.24 260:47RM 0.8 7.8 0.0 48.0 0.4 4.4 a1 6928 2:60:58PM 0.9 &7 0.1 51.0 0.5 4.8 0.1 8&32 251:13PM 0.9 3.6 0.1 S&0 0.5 &0 0.1 91.2 2'6128 PM 0.9 9.2 0.1 61.0 0.5 5.1 0./ 88.32 2'51:43PM 0.9 92 0.1 Sa0 0.5 &3 0.1 9a24 2:51:58PM a9 8.7 0.1 51.0 0.6 &4 a1 88.32 2:52•13 PM 0.8 &3 0.0 48.0 0.8 &8 0.1 86.44 25228 PM 0.9 8.9 0.1 520 0.6 5.2 0.1 85.4 252:43 PM 0.8 8.1 0.0 47.0 0.8 8.3 0.1 81.8 152:58 PM 0.9 8.8 0.1 50.0 0.8 5.9 0.1 78.72 263:13 PM 21 20.8 0.1 75.0 0.4 4.3 0.1 78.8 25338 PM 20 19.5 0.1 820 0.4 3.8 0.1 7298 253:43 PM 1.9 18.7 0.1 81.0 0.4 3.7 0.1 73.92 2•53:58 PM 1.8 18.2 0.1 82o 0.4 3.8 0.1 70.08 154:13 PM 1.8 1&1 0.1 58.0 a4 4.0 0.1 88.18 2:5428PM 1.9 1&8 0.1 820 a4 3.8 0.1 71.04 264:43 PM 1.9 1&8 0.1 a0.0 0.5 4.8 0.1 68.24 254:58 PM 1.9 19.0 0.1 69.0 0.4 4.0 0.1 87.2 2:55:13 PM 1.9 19.1 0.1 Bz.O 0.4 3.6 0.1 85.24 2:5528 PM 1.9 192 0.1 59.0 0.4 3.7 0.1 a3.38 2'55:43PM 1.9 19.4 0.1 a20 a4 4.4 0.1 88.24 2•55:58PM 1.9 19.3 0.1 54.0 0.6 4.6 0.1 824 258:13 PM 1.9 19.3 0.1 81.0 0.5 4.9 0.1 8138 2:5828 PM 1.9 113 0.1 86.0 0.5 5.0 0.1 54.32 2•58:43 PM 1.9 19.4 0.1 620 0.8 8.1 0.1 81.44 2•58:68PM 1.9 19.3 0.1 a0.o 0.8 8.2 0.1 86.28 767:13 PM 1.9 19.1 0.1 8&0 0.6 & 1 0.1 83.38 2:5728 PM 1.9 19.3 0.1 a20 0.8 6.7 0.1 8138 2:57:43PM 1.9 19.4 0.1 87.0 0.5 4.8 0.1 67.2 2•57:58PM 1.9 19.2 0.1 8&0 0.6 6.9 0.1 8524 STop R3 AvMq 15.89 84.48 8.08 85.67

2:58:13PM 20 19.7 0.1 67.0 ab 7.8 0.1 8&18 25828 PM 1.9 19.4 0.1 88.0 afi 8.0 0.1 87.2 2:59:43PM 1.9 19.3 0.1 54.0 0.7 da a1 8&18 258:58PM 0.1 1.3 0.0 18.0 0.4 3.8 a1 7298 259:13 PM 0.1 1.1 0.0 8.0 0.3 29 0.0 18.24 2:5928PM 0.1 1.0 0.0 -1.0 0.3 26 0.0 14.4 2:59:43PM 0.1 0.9 0.0 8.0 0.3 28 0.0 1144 2:69:58PM 0.1 1.0 0.0 -20 0.3 28 0.0 1248 3:00:13PM 0.1 0.9 0.0 &0 0.3 28 0.0 14.4 3:0038PM 0.1 0.9 0.0 4.0 0.2 20 0.0 11.52 3:00:43PM 3.3 33.2 0.0 7.0 QO 0.0 0.0 1a58 3:00:58 PM 3.4 3la 0.0 7.0 a0 0.0 0.0 1248 3:01:13 PM 3.4 33.8 0.0 20 0.0 0.0 0.0 9.8 3:0128 PM 3.4 33.8 0.0 60 0.0 0.0 0.0 1248 3:01:43PM. 28 27.8 0.0 5.0 0.2 1.8 0.0 1248 3:01:58PM a1 1.0 0.0 10.0 0.3 27 0.0 11.52 3:02:13 PM 0.1 a9 0.0 11.0 8.4 83.8 0.0 1248 3:0238PM 0.1 0.8 0.0 5.0 &5 aS1 0.0 10.56 3:02:43PM a1 0.8 0.0 7.0 8.7 87.2 ao 1248 3:0258 PM 0.1 0.9 0.0 3.0 9.2 920 0.0 11.52 3:03:13 PM 0.1 0.6 0.0 4.0 9.2 92.1 0.0 1a68 3:0328 PM 0.1 0.8 0.0 7.0 21 21.1 0.0 1144 3:03:43 PM 0.1 0.7 0.0 5.0 0.4 19 0.0 9.8 3:03:58 PM 0.1 0.7 0.1 S&0 0.0 0.0 0.0 S78 3:04:13 PM 0.1 0.8 0.1 9S0 0.0 0.0 0.0 5.78 3:0428PM 0.1 0.8 0.1 96.0 0.0 0.0 a0 1.92 3:04:43PM 0.1 0.7 0.0 21.0 0.3 3.0 0.0 4.6 3:04:58 PM 0.1 0.8 0.0 8.o 0.4 19 0.0 184 3:05:13PM 0.1 0.7 0.0 11.0 0.5 4.7 0.0 1.92 3:0628 PM 0.1 0.7 0.0 7.0 0.5 4.8 0.0 4.3 3:05:43 PM 0.1 0.8 0.0 &0 0.6 4.5 0.0 288 3:05:68PM a1 0.9 a0 11.0 0.1 1.1 a0 4.8 3:06:13 PM a 1 1.0 0.0 9.0 0.1 1.4 0.0 3.84 

# 25 0 ~1213R3

3:0828 PM 0.1 1.1 QO 11.0 0.1 0.7 0.0 286 3:08:43PM Q1 0.6 QO 7.0 0.3 27 0.0 9.8 3:08:58 PM 0.1 as 0.0 7.0 Q3 3.4 0.0 8.72 3:07:13PM 0.1 Q6 0.0 10.0 0.4 4.3 0.0 5.78 3:0728PM 0.1 0.5 0.0 1.0 0.5 4.6 0.0 7.88 3:07:43 PM 0.1 Q6 0.0 7.0 Q6 4.6 0.0 4.8 3:07:68 PM 0.1 0.5 0.1 83.0 0.0 0.1 0.0 8.72 3:08:17 PM 0.1 0.6 0.1 83.0 QO 0.0 0.0 7.88 3:0828PM 0.1 0.8 Q7 96.0 0.0 0.0 0.0 6.78 3:08:43 PM 0.1 QS 0.1 98.0 0.0 0.0 0.0 8.84 3:08:58PM 0.1 Q5 0.1 86.0 QO 0.0 0.0 Q72 3:09:13PM 0.1 0.6 0.1 SQO 0.4 3.6 0.0 11.52 3:0928PM 0.1 Qs 0.0 QO 0.0 0.0 Q1 68.66 3:09:43 PM 0.1 0.6 0.0 8.0 0.0 QO 0.2 167.44 3:09:58PM Qt 0.6 0.0 -1.0 0.0 0.0 0.2 16d9E 3:10:13PM 0.1 QS 0.0 -20 QO -0.1 03 165.12 3:1028PM 0.1 0.7 0.0 8.0 0.0 0.2 0.2 10224 3:10:43PM Qt 0.8 0.0 10 0.2 22 0.2 149.78 3:10:68 PM 0.1 Q8 0.0 5.0 0.3 3.3 0.1 118.1E 3:11:13 PM 0.1 0.8 0.0 7.0 0.2 1.9 0.1 84.48 3:1128PM 0.1 1.0 0.0 4.0 0.2 23 0.1 67.8 3:11:43 PM 0.1 1.0 0.0 6.0 0.2 24 0.0 38.36 3:11:68 PM 0.1 1.0 0.0 -1.0 0.3 28 0.0 34.5E 3:12:13PM 0.1 1.0 0.0 4.0 48 7.5 0.0 2Q88 3:1228 PM 0.0 0.4 0.0 -20 0.2 1.8 0.0 48.08 3:12'43PM 0.1 Q6 0.0 -1.0 0.1 0.7 0.2 216.86 3:12:58PM 0.1 0.5 0.0 -20 0.0 0.4 0.2 218.88 3:13:13 PM 0.1 0.6 0.0 -20 0.0 0.2 0.2 220.8 3:1328 PM 0.1 0.5 0.0 4.0 0.0 0.2 0.2 223.68 3:13:43 PM 0.1 0.5 0.0 -1.0 0.0 02 0.2 221.75 3:13:58 PM 0.1 0.8 0.0 0.0 0.0 0.2 0.2 1824 3:14:13 PM 0.1 QS 0.1 104.0 0.0 Q2 0.0 27.84 3:1428 PM 0.1 0.5 0.1 100.0 0.0 0.2 0.0 21.12 3:14:43 PM 0.1 0.6 0.1 103.0 U.0 Q2 0.0 2208 3:14:58 PM 0.1 Q8 0.1 100.0 0.0 0.1 QO 10.2



# 26 & 

# ~ ~71213R4

FlLE NM1E 1213r4 LOGGIN6 S 1 S7ART LOOGINO ® NNN//M 15:38:12' LAS'T SAWFLE ® RMWMM 16:62:57: ACTIVE CtN 1A 1B 2A 2g MO011E1V Volps Vatep4 Vatp4 Vo1my4 SAIaPLE RA 16 sso 16 aee 15 aoe 15 s»e INTS: VaU NOn. pppe Vots 00, ppm Vat• VOC, ppn Vata B02, ppm 17/1311995 3:3e:12PM at 0.9 0.0 e.0 0.7 1S9 a0 -854

3:3e27PM a1 0.9 0.0 8.0 a7 15.4 0.0 0.9e 3:3e:42PM ai 1.0 0.0 5.0 0.7 15.0 0.0 472 3:39:57PM a1 1.0 ao 7.0 0.7 1s.0 ao 184 Slrt R4 3:37:12 PM 0.1 1.0 0.0 5.0 0.8 14.5 n0 4.8

3:3727 PM 0.1 1.1 0.0 8,0 aB 13.8 0.0 288 3:37:42PM 0.1 1.0 0.0 SO a8 13.8 0.0 5.78 3:37:57PM 0.1 aB 0.0 5.0 ae 17.4 0.0 2B8 3:38:12 PM 0.1 0.6 0.0 7.0 a8 13.4 0.0 1.92 3:3827 PM 0.1 ae 0.0 20 0.8 13.2 0.0 4.9 3:38:42 PM 0.1 0.8 0.0 9.0 0.8 13.2 0.0 28B 3:36:57PM 0.1 0.8 0.0 20 ae 13.e 0.0 1.92 3:39:12PM a1 0.8 0.0 Qo ae 13.8 0.0 4.8 3:3927PM 0.1 ae ao S.o o.e 14.1 0.0 1.92 3:39:42PM ai 0.7 0.0 -20 0.8 14.7 0.0 288 3:39:57 PM 0.1 0.7 0.0 60 0.6 14.5 0.0 184 3:40:12PM 0.1 0.7 0.0 1.0 0.6 14.5 0.0 1.92 3:4027 PM 0.1 0.7 0.0 4.0 0.8 14.6 0.0 3.84 3:40:42 PM 0.1 0.7 0.0 8.0 ne 14.1 0.0 288 3:40:57 PM 0.1 0.7 0.0 4.0 0.0 14.1 n0 0.98 3:41:12PM at 0.7 a0 5.0 0.8 13.8 0.0 S84 3:4127PM a1 0.7 a0 20 0.8 13.e 0.0 1.92 3:41:42PM at 0.7 0.0 5.0 aB 13.8 0.0 0.9e 3:41:57 PM 0.1 0.8 0.0 5.0 0.8 13.e 0.0 3.84 3:42:12PM 0.1 0.8 0.0 4.0 0.8 13.4 0.0 0.98 3:4227PM 0.1 0.7 0.0 7.0 a8 13.4 0.0 1.92 3:42•42 PM 0.1 0.7 0.0 -20 0.8 114 0.0 3.84 3:4257 PM 0.1 0.7 n0 7.0 0.e 13.2 0.0 0.98 3:43:12PM 0.1 0.7 0.0 e.o U.e 127 a0 1.92 3:4327PM 0.1 0.8 0.0 3.0 0.6 126 0.0 288 7:43:42 PM 0.1 0.8 0.0 4.0 ae 125 0.0 0 3:43:57PM 0.1 0.7 0.0 -20 ne 129 0.0 288 3:44:12PM at 0.8 0.0 -20 0.8 132 0.0 0.98 3:4427PM a1 0.8 0.0 4.0 0.e 13.4 0.0 0 3:44:42PM 0.1 0.7 0.0 a0 0.e 13.2 0.0 288 3:44:67PM 0.1 0.7 0.0 7.0 0.8 13.4 0.0 0 3:45:12PM 0.1 0.7 0.0 -1.0 ae 13.4 0.0 0 3:4527 PM 0.1 a7 0.0 3.0 aB 13.4 0.0 288 3:46:42 PM 0.1 0.8 a0 8.0 a8 132 0.0 -1.92 3:45:57 PM 0.1 0.7 0.0 0.0 0.e 13.2 0.0 286 3:48:12PM 0.1 0.7 0.0 3.0 ae 13.2 0.0 1.92 3:4627 PM 0.1 0.8 0.0 7.0 ae 13.2 0.0 a9e 3:48:42 PM 0.1 0.8 0.0 20 0.9 129 0.0 2e8 3:4e:67PM 0.1 ae a0 5.0 ae 13.4 0.0 0.9e 3:47:12 PM 0.1 0.7 0.0 3.0 0.e 13.e 0.0 0.98 3:4727 PM (11 0.7 0.0 -1.0 0.e 13.6 0.0 3.84 3:47:42PM a1 0.7 0.0 8.0 ae 14.3 0.0 0 3:47:67PM at 0.7 0.0 0.0 O.e 14.5 0.0 a90 3:48:12PM 0.1 0.8 QO 20 ne 14.5 U.0 1.92 3:4827PM 0.1 0.7 0.0 5.0 0.0 14.5 a0 -1.92 3:48:42 PM 0.1 a7 0.0 -20 O.e 14.3 0.0 1.92 3:48:57 PM 0.1 0.7 0.0 e.0 0.0 13.8 0.0 d9e 3:49:12 PM 0.1 0.7 n0 -1.0 O.e 13e 0.0 -1.92 3:4927PM 0.1 0.8 a0 3.0 ae 13.4 0.0 1.92 3:49:42PM at 0.7 a0 S.0 0.e 13.e 0.0 288 3:49:67PM a1 ae 0.0 1.0 aB 13.8 0.0 0 3:50:12PM 0.1 0.7 n0 e.0 0.8 14.7 a0 0.96 3:5027PM 0.1 0.8 a0 e.0 aB 14.5 a0 0.9e 3:50:42PM a1 0.7 0.0 20 0.6 14.5 0.0 2B8 3:60:57PM 0.1 0.8 0.0 8.0 aB 14.5 0.0 1.92 3:51:12PM 0.1 0.7 0.0 4.0 ae 14.3 0.0 0.9e 3:5127PM 0.1 0.7 a0 5.0 ae 14.5 0.0 288 3:51:42PM 0.1 0.7 a0 0.0 U.e 14.6 0.0 0.98 3:51:57PM 0.1 ae 0.0 1.0 0.7 14.8 0.0 1.92 3:52:12PM a1 0.7 0.0 7.0 0.7 16,7 0.0 288 3:5227 PM 0.1 0.7 0.0 -4.0 0.7 1Q9 0.0 0 3:5242PM 0.1 0.7 0.0 10 0.7 15.4 a0 1.92 3:5257 PM 0.1 0.8 0.0 d0 0.7 15.4 0.0 a98 3:53:12PM 0.1 0.7 0.0 -20 0.7 15.2 a0 0 3:6327PM 0.1 ae 0.0 -1.0 0.e 14.5 a0 2e8 3:63:42PM a1 ae 0.0 1.0 0.e 14.6 0.0 0 3:63:57PM 0.1 0.7 0.0 5.0 0.e 14.5 0.0 1.92 3:64:12PM at 0.7 a0 -1.0 ae 14.3 0.0 1.92 3:5427PM at 0.7 0.0 41.0 0.6 14.3 0.0 0 3:64:42PM 0.1 0.7 0.0 S0 0.e 13.8 0.0 288 3:54:57PM ai as 0.0 8.0 ae 14.1 0.0 0 3:55:12PM ai 0.8 0.0 -1.0 ae 14.1 0.0 0 3:5527PM ai 0.9 0.0 4.0 ae 13.8 0.0 1.92 3:55:42 PM 0.1 0.8 a0 5.0 ae 13.e 0.0 d.9e 3:65:67PM .0.1 a9 a0 3.0 ae 11e 0.0 288 3:58:12PM 0.1 0.9 0.0 1.0 aB 13.8 0.0 1.92 3:5827PM 0.1 0.9 0.0 7.0 0.7 14.8 a0 0.98 3:5e:42PM 0.1 0.9 0.0 -20 0.6 14.1 0.0 3.84 3:56:57PM 0.1 a8 0.0 -20 ne 14.5 0.0 0.98 3:57:12PM 0.1 0.8 0.0 SO 0.0 14.5 0.0 1.92 3:5727PM 0.1 0.7 a0 a0 0.7 14.8 0.0 1.92 3:57:42PM 0.1 0.7 0.0 4.0 0.7 14.8 0.0 -0.9e 3:57:57PM 0.1 0.6 a0 4.0 0.7 15.0 0.0 288 3:58:12PM at 0.5 ao 4.0 0.8 14.6 0.0 0.9e 3:5827PM 0.1 0.5 0.0 7.0 0.e 14.5 0.0 a9e 3:5e:42PM ai 0.5 a0 1.0 ae 14.1 0.0 288


# 2 ip P 

### ~ i 11213R4

3:56:57PM 0.1 0.5 0.0 7.0 0.6 14.3 0.0 Q98 3:59:12 PM 0.1 0.6 0.0 1.0 0.8 13.9 0.0 1.92 3:6927PM 0.0 Q4 0.0 4.0 Q8 13.9 QO 0.98 3:59:42PM 0.1 0.5 0.0 20 0.8 14.1 0.o a9e 3:59:57PM 0.1 0.5 0.0 3.0 0.6 13.9 QO 3.64 4:00:12PM 0.0 Q4 0.0 &0 0.8 13.2 0.0 0.96 4:0027PM QO 0.3

. 0.0 -20 0.8 129 0.0 266 4:00:42PM QO

- 0.3 0.0 &0 0.6 129 0.0 2e6 4:00:57 PM 0.0 a4 0.0 a.0 0.6 129 0.0 0.96 4:01:12 PM 0.0 0.7 0.0 -20 0.6 129 0.0 4.8 4:0127PM 0.1 QS 0.0 6.0 0.8 132 QO 1.92 4:01:42PM QO Q4 0.0 3.0 Qe 129 (10 266 4:01:57PM 0.1 QS 0.0 8.0 Q6 127 a0 3.64 4:02:12PM 0.1 aS 0.0 5.0 0.6 127 0.0 1.92 4:0227PM 0.1 ae 0.0 1.0 0.6 127 O.o 4.6 4:02:42PM 0.1 O.e 0.0 &0 0.6 1z9 0.0 1.e2 4:02:57PM a1 0.5 0.0 4.0 0.6 125 a0 z66 4:03:12PM 0.1 0.6 0.0 8.0 ae 125 a0 4.6 4:0327 PM 0.0 a4 0.0 &0 0.e 12s a0 1.92 4:03:42PM 0.0 0.3 0.0 3.0 0.6 123 0.0 3.64 4:03:57PM 0.0 0.3 0.0 7.0 0.5 120 0.0 z68 4:04:12 PM QO -0.1 0.0 0.0 0.6 11.8 0.0 1.92 4:0427 PM 0.0 0.2 0.0 4.0 0.6 11.8 0.0 164 4:04:42PM 0.0 dt 0.0 6.0 0.6 11.6 0.0 1.92 4:04:57PM 0.0 d1 0.0 3.0 0.5 11.8 QO 286 4:05:12PM QO a0 0.0 5.0 Q6 11.8 QO 266 4:0527PM 0.0 -0.1 0.0 -20 0.5 11.1 0.0 Q98 4:06:42 PM 0.0 bt 0.0 7.0 0.5 11.6 QO 3.61 4:05:57 PM 0.0 d2 0.0 -1.0 0.5 11.4 QO 1.92 4:08:12PM 0.0 d2 0.0 8.o 0.5 11.4 QO 266 4:0827 PM 0.0 42 0.0 6.0 0.5 11.4 QO 1.92 4:08:42PM 0.0 42 Qo 3.0 0.8 11.1 QO 0.98 4:08:57 PM 0.0 -0.3 0.0 7.0 0.8 11.1 0.0 3.94 4:07:12PM 0.0 43 0.0 -1.0 Q6 10.9 0.0 0.98 4:0727 PM 0.0 -02 0.0 -1.0 Q5 10.4 0.0 1.92 4:07:42 PM 0.0 4).2 QO 9.0 Qs 10.4 0.0 1.92 4:07:57 PM 0.0 d3 0.0 -20 0.6 11.1 0.0 0.96 4:09:12 PM 0.0 -0.2 0.0 7.0 a5 11.e 0.0 266 4:0827 PM 0.0 d3 a0 6.0 0.5 11.1 0.0 0.98 4:09:42 PM 0.0 44 0.0 -20 0.5 11.4 0.0 1.92 4:09:57 PM 0.0 -0.3 0.0 7.0 0.5 11.4 QO 1.92 4:09:12 PM 0.0 d3 0.0 1.0 0.6 10.7 (10 0 4:0927PM 0.0 43 QO 7.0 a5 10.9 QO 3.64 4:09:42PM 0.0 44 0.0 -1.0 Q6 10.9 0.0 a96 4:09:57 PM 0.0 -0.4 0.0 2o a6 10.9 0.0 1.02 4:10:12PM 0.0 44 0.0 6.0 Q6 11.1 0.0 1.92 4:1027 PM 0.0 4).3 0.0 -2o QS 11.1 0.0 0 4:10:42PM 0.0 b4 QO 5.0 0.5 11.1 0.0 266 4:10:57 PM 0.0 Q1 0.0 4.0 0.5 11.1 0.0 0 4:11:12 PM QO d4 0.0 &0 QS 11.4 QO 0.96 4:1127 PM -0.1 -0.5 0.0 -1.0 0.5 11.8 0.0 1.92 4:11:42 PM 0.0 -0.3 QO 0.0 0.5 11.1 0.0 -0.96 4:11:57 PM 0.0 -0.4 0.0 &0 0.6 120 0.0 266 4:12:12 PM 0.0 -0.4 0.0 5.0 0.5 11.6 QO Q96 4:1227 PM dt -0.5 0.0 4.0 a6 120 QO 0.98 4:12:42 PM -0.1 -0.5 0.0 7.0 0.5 11.8 0.0 1.92 4:12'S7 PM dt -0.5 0.0 -4.0 Q6 120 0.0 d96 4:13:12PM d1 45 a0 &0 0.6 120 QO 286 4:1327PM dt -0.5 0.0 1.0 0.5 120 0.0 498 4:13:42PM -0.1 d6 0.0 20 0.3 120 0.0 0.96 4:13:57 PM -0.1 45 0.0 6.0 0.6 125 0.0 1.92 4:14:12 PM -0.1 -0.5 0.0 -4.0 0.6 129 0.0 Q98 4:1427PM -0.1 b5 0.0 -1.0 0.6 129 QO 3.84 4:14:42 PM -0.1 d5 QO S.0 0.6 112 0.0 0.96 4:14:57 PM 411 as 0.0 2o 0.9 13.2 0.0 1.9z 4:15:12 PM -0.1 -0.s 0.0 7.0 ae 13.4 a0 1.92 4:1527 PM -0.1 45 0.0 a0 ae 13.2 ao 0.96 4:15:42 PM -0.1 46 0.0 8.0 a6 129 0.0 296 4:16:57PM Q7 -0.S 0.0 6.0 Q6 129 QO 0.98 4:16:12 PM -0.1 -0.8 0.0 3.0 O.S

. 127 0.0 z86 4:1627 PM -0.1 -0.6 0.0 10.o a6 1z9 0.0 1.92 4:19:42PM 0.0 -0.1 0.0 6.0 0.8 112 0.0 0.99 4:18:67 PM 0.1 0.6 0.0 4.0 0.6 13.2 0.0 3.64 4:17:12PM 0.1 QS 0.0 3.0 Qe 13.8 QO 0.98 4:1727PM 0.1 0.6 0.0 &o Q6 14.1 0.0 286 4:17:42 PM 0.1 0.9 0.0 8.0 0.7 14.8 QO 1.92 4:17:57 PM 0.1 a6 QO 4.0 0.6 14.6 0.0 1.92 4:18:12PM 0.1 0.9 0.0 7.0 0.6 14.6 0.0 164 4:1827 PM 0.1 Q6 0.0 8.0 U.e 14.6 0.0 1.92 4:18:42PM 0.1 0.6 0.0 3.0 0.8 14.3 0.0 A91 4:18:57 PM 0.1 QB 0.0 7.0 0.6 14.5 0.0 1.92 4:19:12PM 0.1 0.6 0.0 4,0 a6 14.1 0.0 1.92 4:1927PM 0.1 ae 0.0 3.0 O.e 13.e Qo 3.94 4:19:42PM 0.1 ae 0.0 &0 0.6 13.2 QO 0.96 4:19:37PM 0.1 0.6 0.0 4.0 ae 129 0.0 164 420:12PM 0.1 0.7 0.0 7.0 0.6 129 0.0 1.92 42027 PM 0.1 0.7 0.0 1.0 0.6 129 0.0 1.92 420:42PM a1 0.7 0.0 6.0 0.8 125 0.0 3.64 420:57PM 0.1 0.7 0.0 10.0 0.e 12s 0.0 0.9e 421:12 PM 0.1 a7 0.0 3.0 a6 127 O.o 3.64 42127 PM 0.1 0.7 0.0 7.0 0.6 1z9 0.0 1.92 421:42 PM 0.1 0.7 0.0 7.0 0.6 129 Qo 1.92 421:57 PM 0.1 0.7 0.0 3.0 a3 123 a0 25e 422:12 PM 0.1 ae 0.0 7.0 0.e 127 0.0 (198 42227PM 0.1 ae 0.0 3.0 ae 129 0.0 3.64 422:42PM 0.1 0.7 0.0 6.0 0.e 129 0.0 0.98 422:57PM 0.1 0.9 0.0 4.0 0.6 13.2 0.0 2e6 423:12 PM 0.1 Q7 0.0 4.0 0.6 13.2 0.0 1.92 42327 PM 0.1 O.e 0.0 7.0 0.e 127 0.0 0.96 423:42PM 0.1 0.6 0.0 7.0 O.e 127 0.0 3.64 423:57 PM 0.1 0.7 0.0 e.o ae 127 a0 a9e 424:12 PM 0.1 ae 0.0 9.0 0.e 127 0.0 26e 42427 PM 0.1 ae 0.0 4.0 0.6 129 0.0 1.92

28 a.o. 21213R4

424:42 PM 0.1 0.6 0.0 11.0 a8 127 0.0 0.98 424:57 PM 0.1 0.8 U.0 8.0 06 126 0.0 3.84 425:12 PM 0.1 0.8 0.0 8.0 06 123 0.0 0.96 42527 PM 0.1 

### ae 0.0 9.0 0.5 123 0.0 3.84 425:42PM 0.1 0.6 0.0 4.0 0.6 120 0.0 1.92 425:57 PM 0.1 0.8 0.0 1.0 0.5 120 0.0 0.98 428:12PM 0.1 0.6 0.0 9.0 0.6 11.8 0.0 3.84 42827 PM 0.1 0.6 0.0 6.0 QS 11.8 0.0 268. 428:42PM 0.1 0.5 0.0 10.0 0.5 11.6 0.0 3.84 428:57PM 0.1 0.6 0.0 6.0 O6 120 0.0 0.98 427:12 PM 0.1 05 0.0 4.0 0.8 11.8 0.0 0.98 42727PM 0.1 08 0.0 7.0 0.5 123 0.0 28B 427:42PM 0.1 0.6 0.0 20 0.8 128 0.0 098 427:67 PM 0.1 0.6 0.0 10.0 0.8 126 0.0 3.84 428:12PM 0.1 0.5 0.0 &0 08 125 0.0 0.88 44827 PM 0.0 0.4 0.0 8.0 0.8 125 0.0 288 429:42PM 0.1 0.5 0.0 11.0 0.8 127 0.0 1.92 428:57 PM 0.1 0.5 0.0 5.0 0.8 13.2 0.0 098 429:12PM 0.0 0.4 0.0 7.0 0.8 13.4 0.0 184 42927PM 0.1 0.5 0.0 9.0 0.8 13.2 0.0 0.98 429:42 PM 0.1 06 0.0 8.0 0.8 13.2 00 288 429:57PM 0.o 0.4 0.0 10.0 0.8 13.8 Oo 1.82 4:30:12 PM 0.0 0.4 0.0 5.0 0.8 13A 0.0 0.98 4:3027PM 0.0 0.4 0.0 8.0 0.8 14.1 0.0 288 4:30:42 PM 0.1 0.5 0.0 10.0 0.8 14.1 0.0 0 4:30:67 PM 0.0 0.4 0.0 5.0 0.8 14.1 0.0 286 4:31:12PM 0.0 0.4 0.0 8.0 0.8 14.3 QO 098 4:3127PM 0.0 0.4 0.0 &0 0.7 15.0 0.0 0.98 4:31:42PM 0.0 0.4 0.0 4.0 0.7 16.0 0.0 288 4:31:57PM 0.0 0.4 0.0 9.0 0.7 15.2 0.0 0.98 4:32:12PM 0.0 • 03 0.0 4.0 0.7 16.2 0.0 1.92 4:3227PM 0.0 0.3 0.0 8.0 

### o.e 14.8 0.0 286 4:32:42 PM 0.0 0.4 0.0 11.0 0.7 14.8 0.0 0 4:32:57PM 0.0 0.4 0.0 5.0 0.7 14.8 0.0 1.92 4:33:12PM U.0 0.3 0.0 10.0 0.8 14.6 0.0 288 4:3327PM 0.0 0.3 0.0 8.0 0.8 14.1 0.0 -1.92 4:33:42 PM 0.0 0.4 0.0 8.0 0.8 13.8 0.0 268 4:33:57PM 0.0 0.4 0.0 120 0.8 14.1 0.0 098 4:34:12 PM 0.0 0.4 0.0 7.0 0.8 13.6 0.0 0 4:3427 PM QO 0.4 0.0 6.0 0.8 14.1 (10 288 4:34:42 PM 0.0 0.3 0.0 10.0 0.8 14.1 0.0 -0.98 4:34:57PM 0.0 0.4 0.0 8.0 0.8 13.8 0.0 288 4:36:12PM 0.0 0.3 0.0 9.0 0.8 134 0.0 0.98 4:3627PM 0.0 0.3 0.0 e.o ae 13.8 Oo 0.98 4:35:42 PM 00 0.3 0.0 7.0 0.8 13.6 0.0 288 4:36:57 PM ao 0.3 0.0 &a 0.8 13A 0.0 -1.82 4:38:12 PM 0.0 0.1 0.0 6.a 0.8 13.2 0.0 1.92 4:3827PM 0.0 0.2 0.0 10.0 0.8 129 0.0 a98 4:38:42PM 0.0 0.2 0.0 4.0 0.8 129 QO -1.92 4:38:57 PM 0.0 0.3 0.0 11.0 0.8 129 0.0 3.64 4:37:12PM 0.0 0.2 0.0 7.0 0.8 127 0.0 0 4:3727PM 0.0 0.2 0.0 7.0 0.8 129 0.0 -1.92 4:37:42 PM 0.0 0.2 0.0 11.0 0.8 129 0.0 286 4:37:57 PM 0.0 0.1 0.0 8.0 0.8 13.2 0.0 -0.98 Sap R4 Avays 0.41 4.39 13.20 1.83

4:38:12 PM O.a 0.0 0.0 11.0 0.6 10.7 QO 0.98 4:3627PM 0.0 d1 0.0 7.0 0.4 10.0 0.0 3.64 4:38:42PM 0.0 0.3 0.0 8.0 0.6 10.2 0.0 098 4:38:57PM 0.0 -0.1 0.0 11.0 0.4 9.6 0.0 4.8 4:39:12 PM 0.1 0.8 0.0 5.0 0.4 9.1 0.0 48 4:3927 PM 3.4 34.1 0.0 10.0 0.1 27 0.0 4.8 4:39:42 PM 3.4 33.5 0.0 Sa 0.1 25 0.0 7.88 4:39:57 PM 3.4 33.7 0.0 10.0 0.1 23 0.0 4.8 4:40:12PM 3.4 33.0 0.0 0.0 0.1 1.8 O.o 6.78 4:4027PM

- 3.4 33.8 0.0 S.0 0.1 3.2 U.0 9.8 4:40:42 PM 3.4 33.7 0.0 &0 0.1 23 0.0 672 4:40:57PM 3.4 33.7 0.0 4.0 0.3 7.0 0.0 &84 4:41:12 PM 27 27.0 0.0 7.0 0.4 8.2 0.0 11.52 4:4127 PM 0.0 -0.2 0.0 10.0 0.4 7.9 0.0 &64 4:41:42 PIN 0.0 4X2 0.0 8.0 0.4 7.9 0.0 9.8 l:41:57 PM 0.0 -0.2 0.0 10.0 0.3 7.7 0.0 1248 4:4212 PM 0.0 d3 0.0 7.0 0.4 7.9 0.0 &84 4:4227 PM 0.0 Q2 0.0 7.0 0.3 7.7 0.0 9.8 4:42'.42 PM 0.0 43 0.0 10.0 0.3 7.5 0.0 11.52 4:42:57 PM 0.0 -0.2 0.0 7.0 0.9 19.6 0.0 &84 4:43:12PM 0.0 -0.2 0.0 7.0 1.3 29.3 0.0 9.8 4:4337PM 0.0 •0.2 0.0 9.0 1.3 29.7 0.0 10.58 4:43:42 PM 0.0 -0.3 0.0 5.0 1.3 30.0 0.0 8.84 4:43:67PM 0.0 -0.3 0.0 10.0 1.3 29.7 0.0 11.52 4:44:12 P1d 0.0 42 0.0 7.0 1.2 27.9 0.0 Q8 4:4427PM 0.0 -0.2 0.0 &0 0.7 16.1 0.0 .8.64 4:44:42PM 0.0 -0.2 0.0 7.0 , 1.2 27.2 0.0 11.52 4:44:57PM 0.0 d3 0.0 SO 0.4 9.1 QO &84 4:46:12PM 0.0 -0.3 0.0 11.0 a4 7.9 0.0 9.8 4:4627 PM 0.0 43 0.0 6.0 0.3 7.3 0.0 13.44 4:46:42PM 0.0 -0.3 0.0 9.0 0.1 1.8 0.0 10.68 4:46:67 PM 0.0 -0.4 0.1 61.0 0.1 1.1 0.0 1248 4:48:12 PM 0.0 d4 0.1 93.0 0.1 1.1 0.0 1246 4:4827PM o.0 44 0.1 10&0 0.1 1.1 0.0 10.56 4:48:42PM 0.0 -0.4 0.1 101.0 0.0 0.9 0.0 13.44 4:46:57 PM 0.0 -0.3 0.1 106.0 0.1 23 0.0 1248 4:47:12 PM -0.1 -0.6 0.1 63.0 0.1 1.4 0.1 64.32 4:4727PM 0.0 44 0.0 &0 0.0 0.7 0.2 185.28 4:47:42PM 0.0 43 0.0 1&0 0.0 -0.2 0.2 193.92 4:47:57PM 0.0 d4 0.0 8.0 0.0 -0.2 0.2 200.64 4:46:12 PM -0.1 -0.6 0.0 7.0 0.0 -0.2 0.2 207.38 4:4827PM -0.1 G6 0.0 120 0.0 0.2 0.2 208.4 4:46:42PM 0.0 Q4 0.0 &0 00 0.7 0.2 209.26 4:46:57PM 0.0 4X4 0.0 9.0 0.2 6.0 0.1 78.6 4:49:12PM 0.0 44 0.0 10.0 0.3 8.1 0.0 30.72 4:4927PAA -0.1 Q6 0.0 &0 29 88.3 0.0 26.92 

# 29 ~~

### 121JR4

4:49:42 PM -0.1 -0.5 0.0 10.0 7.9 98.5 0.0 24.98 4:49:57PM -0.1 -0.5 0.0 7.0 i9 98.8 0.0 21.12 4:50:12 PM O.1 45 0.0 7.0 19 99.2 0.0 21.12 4:5027PM -0.1 -0.5 0.0 15.0 3.9 89.0 0.0 2208 4:50:42 PM -0.1 46 0.0

. 8.0 4.0 91.0 0.0 18.24 4:50:57 PM -0.1 A6 0.0 11.0 3.9 BB.B 0.0 20.18 4:51:12 PM 41 O.8 0.0 9.0 25 55.3 0.0 18.24 4:5127 PM -0.1 -0.6 0.0 9.0 0.8 127 0.0 15.78 4:51:42 PM -0.1 d5 &0 13.0 0.4 9.6 0.0 19.2 4:51:57PM -0.1 -0.5 0.0 9.0 4.0 90.1 QO 1728 4:52:12PM -0.1 d.6 0.0 8.0 4.0 90.1 QO 17.28 4:6227PM Q7 45 0.0 13.0 4.0 90.1 0.0 20.18 4:52:42PM d1 d8 0.0 &0 4.0 90.1 0.0 17.26 4:5257 PM 41 -0.6 0.0 120 4.0 90.1 0.0 17.26



# 30

PP 4 

# ~ 

# l1213R5

FlLE NIIME: 1213r6 LOGGIN6 SE 1 SiART LOGGOV6 Q iAMMNYMb 18:53:40: LAST SNMPLE 

### 0 A4pqNNS 18:08:10: ACi1VEQJA 1A iB 2A 28 MODILE TY Vavps Vafaps VafeOs Vab¢ SM.PLE RA7 15 ssc 16 sse 15 ase 16 am WTS: Vots NOiG {pm Vds 00, ppm Vob VOC, ppm Vots S02, ppm 12/1311995 4:63:40 PM -0.1 a5 0.0 9.0 a8 19.2 0.0 17.28

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5:42:10PM 0.0 0.4 0.0 &0 0.9 225 0.0 576 5:4225 PM 0.0 0.3 0.0 11.0 0.9 23.3 QO 6.64 5:42:40 PM 0.0 0.3 0.0 &0 0.9 23.3 0.0 6.72 5:4256PM 0.0 0.3 0.0 9.0 0.9 23.8 0.0 6.7e 5:43:10PM 0.0 0.4 0.0 13.0 1.0 24.3 0.0 8.84 5:4325PM 0.0 0.4 0.0 9.0 1.0 24.3 0.0 5.78 5:43:40 PM 0.0 0.3 0.0 11.0 1.0 24.8 QO 5.72 5:43:66 PM 0.0 0.4 0.0 11.0 1.0 24.8 0.0 6.78 5:44:10PM 0.0 0.3 0.0 8.0 1.0 25.8 QO 4.8 5:44:25 PM 0.0 0.3 0.o 13.0 1.0 25.8 0.0 7.66 5:44:40 PM 0.0 0.4 0.0 &0 1.0 25.1 0.0 4.8 5:44:56PM 0.0 0.4 0.0 &0 1.0 215.3 0.0 6.72 5:46:10PM 0.0 0.4 0.0 10.0 1.0 21L1 0.0 5.78 5:4625PM 0.0 0.4 0.0 5.0 1.0 28.1 QO 4.8 5:46:40 PM 0.0 0.4 0.0 11.0 1.0 25.6 0.0 7.68 5:45:66PM 0.1 0.6 0.0 7.0 1.0 20.1 0.0 &7e 5:48:10PM 0.1 0.6 0.0 7.0 1.0 20.1 QO 8.72 5:4e' .26PM 0.0 0.4 0.0 11.0 1.0 25.8 0.0 6.72 5:48:40 PM 0.0 0.4 0.0 9.0 1.0 25.8 0.0 4.8 5:4e:66PM 0.0 a4 0.0 10.0 1.0 25.3 0.0 7.68 5:47:10 PM 0.1 0.6 a0 110 1.0 25.0 0.0 5.76 5:4725PM at 0.5 0.0 7.0 1.0 24.8 0.0 8.72 5:47:40PM 0.o 0.4 0.0 15.0 1.0 24.6 0.0 7.88 5:47:58 PM a0 0.4 0.0 &0 1.0 24.3 0.0 5.7e 5:48:10 PM 0.1 a5 0.0 7.0 1.0 24.3 0.0 &64 5:4825 PM 0.1 0.5 0.0 11.0 1.0 24.3 0.0 672 5:48:40 PM 0.0 0.4 0.0 &0 1.0 24.5 0.0 5.78 5:48:65 PM U.1 0.5 0.0 120 1.0 24.3 0.0 &51 5:49:10PM 0.1 0.5 0.0 9.0 1.0 24.3 0.0 8.72 5:4926PM 0.0 0.4 0.0 7.0 1.0 24.8 0.0 8.64 -5:49:40PM ai 0.5 0.0 11.0 1.0 26.0 0.0 7.68 5:49:66PM 0.1 0.5 0.0 7.0 1.0 25.3 a0 6.72 5:60:tOPM 0.1 0.8 0.0 &0 1.0 25.6 0.0 9.6 5:6025PM a1 0.5 0.0 120 1.0 26.8 0.0 8.72 5:50:40PM 0.1 0.6 0.0 9.0 1.0 25.8 0.0 7.86 5:50:55PM 0.1 a5 0.0 130 1.0 25.8 0.0 7.88 5:51:10 PM 0.1 0.5 0.0 9.0 1.0 25.8 0.0 6.76 5:5126 PM 0.1 0.6 0.0 &0 1.0 2S.8 0.0 &64 5:51:40 PM a1 0.5 0.0 13.0 1.0 24.6 0.0 5.7e 5:61:55PM 0.1 a8 0.0 9.0 0.9 23.8 0.0 5.76 5:5110PM 0.1 0.6 0.0 13.0 0.9 23.0 0.0 7.68 5:6225PM 0.1 0.5 0.0 9.0 0.9 228 QO 4.8 5:52:40PM 0.1 0.6 0.0 S.0 0.9 220 0.0 6.72 5:6256PM 0.1 O.e 0.0 13.0 0.9 225 0.0 5.7e 5:53:10PM 0.1 0.6 0.0 9.0 0.9 275 0.0 4.8 6:5326 PM 0.1 0.5 0.0 110 a9 228 0.0 7.68 5:63:40 PM 0.1 0.9 0.0 11.0 0.9 23.0 0.0 4.8 5:53:55 PM 0.1 0.5 0.0 a0 0.9 228 0.0 8.72 5:64:10 PM 0.1 0.6 0.0 120 0.9 23.3 0.0 6.72 5:6425 PM 0.1 0.9 0.0 &0 0.9 23.6 0.0 4.8 5:64:40PM 0.1 O.e 0.0 7.0 0.9 23.8 0.0 &84 5:64:56PM ai 0.9 0.0 11.0 0.9 23.6 0.0 5.7e Stop RS Avarys 0.22 1203 23.63 6.78

5:55:tOPM 0.1 0.5 0.0 &0 0.8 20L0 a0 6.72 5:5525 PM 0.1 0.6 0.0 18.0 O.e 13.9 0.0 7.68 5:56:40 PM 0.1 0.6 QO 6.0 1.1 28.3 0.0 7.88 5:56:55PM 0.1 0.5 0.0 9.0 0.8 19.0 0.0 10.6e 5:56:10PM 23 225 0.0 13.0 0.4 9.4 0.0 8.64 5:5626PM 29 29.0 0.0 5.0 0.2 4.0 ao &84 5:58:40 PM 3.2 324 0.0 10.0 0.2 3.8 0.0 11.52 5:58:65PM 3.2 32z 0.0 a0 0.1 2e 0.0 9.6 5:57:10 PM 3.2 323 0.0 ao 0.1 3.0 a0 11.52 5:5725PM 3.2 323 0.0 11.0 0.1 3.5 0.0 9.e 5:67:40 PM 0.2 1.6 0.0 ao 0.3 e.3 a0 9.e 6:57:66PM 0.1 1.1 0.0 35.0 0.3 7.1 0.0 12.48 5:58:10 PM 0.1 1.1 0.1 101.0 0.1 3.3 0.0 8.64 5:6925PM 0.1 1.1 0.1 100.0 0.1 28 a0 1a69 5:66:40 PM 0.1 1.0 0.1 107.0 0.1 28 0.0 10.6e 5:58:56 PM 0.1 1.0 0.1 101.0 0.1 23 0.0 8.64 5:59:10 PM 0.1 1.0 0.1 107.0 0.1 20 0.0 11.52 5:6925PM 0.1 1.1 0.1 103.0 0.1 23 0.0 8.94 5:59:40PM 0.1 1.1 0.0 320 0.2 at ao &dl 5:69:66PM 0.1 1.1 0.0 &0 24 81.0 0.0 11.62 e:00:10 PM 0.1 1.1 0.0 &0 3.9 91.1 0.0 9.9 9:0025 PM 0.1 1.1 0.0 10.0 3.7 929 0.0 11.52 9:00:40PM at 1.1 0.0 7.0 3.7 9ze a0 11.62 8:00:55 PM 0.1 1.0 0.0 4.0 3.7 9ze 0.0 9.6 e:01:10PM 0.1 1.1 0.0 10.0 3.7 9ze 0.0 1248 B:o123PM 0.1 1.0 0.0 7.0 27 67.6 0.0 1a58 6:01:40PM 0.1 1.1 0.0 10.0 1.6 38.6 0.0 11.52 6:01:66PM 0.1 1.0 0.0 e.0 0.7 17.7 0.0 10.56 e:02'10PM 0.1 1.1 0.0 a0 0.6 11.8 0.0 8.84 9:0226 PM 0.1 1.0 0.0 7.0 0.1 3.0 0.0 8.04 e:02:40PM 0.1 1.1 0.0 4.0 0.0 1.0 0.0 4.6 e:0266PM 0.1 1.1 0.0 6.0 0.0 1.0 0.0 4.8 e:03:10 PM 0.1 1.0 0.0 9.0 0.0 1.0 0.0 7.68 8:0325 PM 0.1 1.0 0.0 ao 0.1 1.3 a0 4.8 6:03:40 PM 0.1 1.0 0.0 10.0 0.1 1.3 0.0 7.e8 6:03:56PM 0.1 1.0 0.0 &0 0.1 10 0.0 7.e8 ' e:04:10PIN 0.1 1.1 0.0 &0 0.1 25 0.0 a72

6:0425PM 0.1 1.1 0.0 12o 0.0 1.0 at 101.7e e:04:40PM a1 1.0 0.0 7.0 0.1 1.3 0.2 17a64 8:04:66PM 0.1 1.1 0.0 &0 0.0 0.8 0.2 189.12 9:06:10 PM 0.1 1.0 0.0 &0 0.0 0.6 a2 194.88 8:0525PM 0.1 1.1 0.0 7.0 0.0 0.3 0.2 224.64 8:05:40PM 0.1 1.1 0.0 &0 0.0 0.6 0.2 22&48 e:05:56PM 0.1 1.0 0.0 7.0 0.0 0.8 0.2 22a6e e:08:10PM 0.1 1.0 0.0 &0 0.0 0.6 0.2 227.52


# 33 ~ ~1213R6

FlLE NAAIE: 1213i8 LOGGINO S 1 SiARr LOGGING ® NIAIhtAW 18:07:14: LAS'T SAMPLE ® MMNpM{ 19:1629: ACTIVE CW1 tA 1B 2A 2B A1OOl.lE Tr Votaps Vafaps Vo[ps Vataps SAAPLE RA 15 ssc 16 sse 15 ssc 15 aeo WTS: Vals NOx, ppm Vots CO, ppn Vats VOC, pppn Vals S02, Mn 12/1311996 8:07:14 PM 0.1 1.1 0.0 &0 0.3 3.0 QO 3&4

8:0729 PM 0.1 1.1 

### a0 10.0 0.3 3.0 QO 31.68 8:07:44 PM 0.1 1.1 0.0 11.0 0.2 21 0.0 288 6:07:59PM Q7 1.1 0.0 4.0 0.2 22 0.0 464 Start R8 8:08:14 PM 0.1 1.3 0.0 120 0.e &4 0.0 11.52

6:0829 PM 0.1 1.2 0.0 &0 1.0 10.3 0.0 13.41 8:08:44 PM 0.1 1.2 QO 9.0 1.1 10.9 0.0 1248 8:08:59PM a1 1.3 0.0 1&0 1.0 9.8 0.0 1Q32 8:09:14 PM 0.1 12 0.0 10.0 1.2 11.5 0.0 13.44 8:0929 PM 0.1 1.2 0.0 120 1.2 11.8 QO 15.39 8:09:44PM 0.1 1.2 0.0 8.0 1.2 124 0.0 1&38 8:09:59 PM Q7 1.3 0.0 d0 1.3 127 QO 13.44 8:10:14 PM 0.1 1.3 QO 11.0 1.3 1z8 0.0 17.28 8:1029 PM 0.1 1.2 0.0 &0 1.3 127 0.0 13.44 8:10:44PM 0.1 1.2 0.o 8.0 1.3 127 0.0 14.4 8:10:59PM Q1 1.2 0.0 13.0 1.3 127 QO 14.4 8:11:14PM Q1 1.2 0.0 8.0 1.3 1z5 0.0 1248 E:1129PM 0.1 1.2 

### ao 11.0 1.2 122 0.0 1&36 6:11:44 PM 0.1 1.2 0.0 7.0 1.2 1z1 0.0 13.d 6:11:59 PM 0.1 i.2 0.0 &0 1.2 1zo 0.0 1246 6:12'14PM 0.1 1.2 0.0 120 1.2 1z1 QO 1344 e:1229 PM 0.1 1.2 0.0 7.0 1.2 123 QO 10.59 8:1244 PM 0.1 1.2 0.0 120 1.2 124 0.0 13.44 8:12:59PM 0.1 1.2 0.0 9.0 1.3 127 0.0 10.56 8:13:14 PM 0.1 1.3 0.0 11.0 1.3 128 0.0 9.e 6:1329PM Q1 1.4 QO 9.0 1.2 11.9 0.0 1246 6:13:44 PM 0.2 1.5 0.0 &0 1.3 129 0.0 9.6 6:13:69PM 0.2 1.5 QO 1z0 1.3 13.0 U.0 10.56 6:14:14 PM 0.2 1.6 QO &0 1.3 13.0 QO 10.56 6:1429 PM 0.2 1.5 0.0 7.0 1.3 13.0 QO &64 6:14:44 PM 01 1.6 0.0 120 1.3 13.0 0.0 11.52 8:14:69 PM 0.1 1.4 QO &0 1.3 129 0.0 9.6 8:16:14 PM 0.1 1.4 0.0 9.0 1.3 1z6 0.0 9.8 6:1629PM Q1 1.3 0.0 4.0 1.3 13.2 0.0 10.58 6:16:44PM 0.1 1.3 0.0 7.0 1.3 12e 0.0 &e4 8:15:59 PM 0.1 1.3 0.0 12o 1.7 1ze 0.0 11.52 6:1e:14PM Qt 1.3 0.0 7.0 1.3 126 0.0 A6 6:1629 PM 0.1 1.3 0.0 13.0 1.3 128 0.0 10.56 6:16:44 PM 0.1 1.3 0.0 &0 1.3 1ze 0.0 11.52 6:1e:59PM Q7 1.3 0.0 9.0 1.3 126 0.0 9.9 6:17:14 PM 0.1 1.3 0.0 11.0 1.3 128 0.0 11.52 8:1729 PM 0.1 1.3 0.0 &0 1.3 127 0.0 10.58 6:17:44 PM 0.1 1.3 0.0 14.0 1.3 127 0.0 9.6 6:17:59PM 0.1 1.2 0.0 &0 1.3 127 0.0 1248 8:18:14PM 0.1 1.3 0.0 11.0 1.3 127 ao 9.9 8:1829PM 0.1 1.2 0.0 7.0 1.3 127 0.0 11.52 8:18:44 PM 0.1 1.2 QO 7.0 1.2 tz2 0.0 10.59 8:18:59 PM 0.1 1.2 0.0 10.0 1.8 17.9 0.0 9.6 6:19:14PM 0.1 1.2 0.0 9.0 1.8 1&1 0.0 11.62. 6:1929 PM 0.1 1.2 0.0 9.0 1.8 17.8 0.0 &64 6:19:44PM Q7 1.3 0.0 4.0 1.8 17.9 0.0 10.56 e:19:69PM 0.1 1.3 0.o e.0 1.a 17.6 0.0 &84 820:14 PM 0.1 1.3 0.0 10.0 1.8 17.9 0.0 7.68 82029 PM 0.1 1.2 0.0 &0 1.8 1&3 0.0 10.50 620:44PM Q7 1.3 0.0 110 1.9 1&6 0.0 fl72 820:59 PM 0.1 1.3 0.0 10.0 1.4 14.2 0.0 &64 821:14 PM 0.1 1.3 0.0 8.0 1.3 13.0 0.0 &e4 82129PM 0.1 13 0.0 120 1.2 123 0.0 &72 621:44 PM 0.1 1.2 0.0 7.0 1.2 123 0.0 10.58 821:59 PM 0.1 1.3 0.0 9.0 1.2 122 0.0 7.68 8:=14PM 0.7 13 0.0 13.0 1.2 121 0.0 &64 82229PM 0.1 1.3 0.0 7.0 1.2 120 0.0 9.e 82244 PM 0.1 1.2 0.0 tzo 0.2 1.8 0.0 7.68 632:59PM 0.1 1.4 0.0 9.0 0.2 1.8 0.0 10.5e 623:14PM 0.2 1.6 0.0 9.0 0.3 ze a0 &64 92329PM 0.2 1.e 0.0 14.0 0.3 26 0.0 7.68 823:44 PM 0.2 1.6 0.0 &0 1.8 1&4 0.0 10.36 623:69PM 0.2 1.6 0.0 &0 1.9 18.6 0.0 7A8 924:14PM 0.2 1.6 0.0 13.0 1.9 1&5 0.0 9.e 82429PM 0.2 1.7 0.0 &0 1.9 1&e 0.0 &81 674:44 PM 0.2 1.7 0.0 13.0 1.9 1&6 0.0 7.68 824:59 PM 0.2 1.7 0.0 14.0 1.9 1&8 0.0 1a56 823:14 PM 0.2 1.6 0.0 11.0 1.9 1&S 0.0 &64 82629PM 0.2 1.8 0.0 14.0 1.9 1&5 0.0 &64 e'13:44 PM 0.2 1.6 0.0 11.0 1.9 1&s 0.0 9.e 626:59 PM 0.2 1.8 0.0 120 1.9 18.6 0.0 7.66 625:14 PM 0.2 1.9 0.0 15.0 1.9 1&e 0.0 9.e 62629PM 0.2 1.9 0.0 10.0 1.9 1&7 0.0 &e4 82E:44PM 0.2 1.8 0.0 9.0 1.9 1&7 0.0 7.6e e29:59PM 0.2 1.9 0.0 14.0 1.9 1&7 0.0 1a5e 827:14 PM 0.2 1.9 Qo 10.0 1.9 18.e 0.0 7.66 82729PM 0.2 1.9 0.0 120 1.9 1&S 0.0 &64 827:44PM 0.2 1.9 0.0 120 1.9 1&S QO Q6 827:59PM 0.2 21 0.0 &0 1.9 1&8 0.0 e.72 - 828:14 PM 0.2 21 0.0 13.0 1.9 19.0 0.0 9.0 eZ629 PM 0.2 21 0.0 10.0 1.9 19.1 0.0 7.68 928:44PM 0.2 21 0.0 10.0 1.9 19.1 0.0 &72 e28:39PM 0.2 22 0.0 14.0 1.9 19.1 0.0 10.5e 629:14PM 0.2 zt 0.0 120 1.9 19.2 0.0 &72 62929 PM 0.2 22 0.0 11.0 1.9 19.2 0.0 7.68 929:41 PM 0.2 23 0.0 16.0 1.9 19.3 0.0 9.8 

# 34
Pe 1

### 1213Ra

629:59 PM 0.2 23 0.0 11.0 1.9 19.3 0.0 8.72 8:30:14PM 0.2 23 0.0 13.0 1.9 19.4 ao 10.58 6:3029PM 0.2 23 0.0 10.0 1.9 19.4 0.0 &84 6:30:44 PM 0.2 2.4 0.0 9.0 20 19.5 0.0 7.65 6:30:59PM 0.2 23 0.0 11.0 20 19.5 0.0 10.58' 8:31:14 PM 0.2 24 0.0 7.0 1.9 19.4 0.0 7.86 6:3129 PM 0.2 24 0.0 &0 1.9 19.4 0.0 &64 8:31:44PM 0.2 24 0.0 11.0 1.9 19.4 0.0 9.5 8:31:59 PM 0.2 24 0.0 &0 1.9 19.3 0.0 8.72 6:32:14 PM 0.2 24 0.0 &0 1.9 19.4 0.0 10.58 8:3219 PM Q3 25 0.0 120 1.9 19.4 0.0 7.86 8:32:44 PM 0.3 26 0.0 9.0 20 19.8 0.0 7.66 6:3259PM 0.3 27 0.0 13.0 2o 19.8 0.0 10.66 6:33:14PM 0.3 2a 0.0 9.0 20 20.0 0.0 7.68 6:3329PM 0.3 27 0.0 1zo 2o 20.3 0.0 9.8 6:33:44 PM 0.3 2S 0.0 9.0 21 20.6 0.0 &64 8:33:59PM 0.3 2a 0.0 13.0 21 20.7 0.0 8.72 8:34:14 PM 0.3 29 0.0 10.0 z1 20.6 0.0 9.8 8:3429PM 0.3 29 0.0 9.0 21 206 0.0 &64 8:34:44 PM 0.3 29 0.0 10.0 20 20.4 0.0 7.68 6:34:69PM 0.3 2a 0.0 &0 2o 20.3 0.0 10.5B 8:35:14 PM 0.3 3.0 0.0 11.0 21 20.5 0.0 &72 8:3629PM 0.3 3.0 0.0 11.0 21 20.6 0.0 &64 6:35:44 PM 0.3 3.1 0.0 SO 21 20.6 0.0 &64 8:35:59PM (13 3.3 0.0 10.0 20 20.4 0.0 0.72 6:3a:14PM 0.3 10 0.0 &0 20 20.1 0.0 9.6 8:3829PM 0.3 3.3 QO 7.0 20 19.9 0.0 7.66 8:38:44PM 0.3 3.7 0.0 11.0 20 148 0.0 7.88 8:36:59PM 0.3 3.3 0.0 &0 1.9 19.4 0.0 9.8 8:37:14 PM 0.3 3.3 0.0 9.0 1.9 19.4 QO 6.72 6:3729PM 0.3 3.2 0.0 120 zo 19.8 a0 9.9 6:37:44PM 0.3 32 0.0 &0 zo 19.6 0.0 &84 6:37:59PM 0.3 32 0.0 14.0 20 19.9 0.0 &72 8:38:14 PM 0.3 12 0.0 10.0 z0 19.9 0.0 1QSa 8:3829 PM 0.3 32 0.0 8.0 2o 19.8 0.0 7.08 8:38:44PM 0.3 3.3 0.0 11.0 20 19.a 0.0 &64 6:38:59PM 0.3 3.2 0.0 11.0 zo 19.9 0.0 9.8 8:39:14PM 0.3 3.2 O.o &0 2o 19.9 0.0 7.88 8:3929PM 0.3 3.3 0.0 11.0 2o 1&9 0.0 10.56 6:39:44PM 0.3 3.2 0.0 4.0 20 19.9 0.0 &BS 8:39:59 PM 0.3 12 a.0 &0 20 19.8 0.0 7.69 6:40:14 PM 0.3 3.2 0.0 11.0 zo 19.9 0.0 10.66 8:4019PM 0.3 3.2 0.0 9.0 20 19.6 QO 7.58 8:40:44PM 0.3 13 0.0 14.0 20 1&8 0.0 &54 6:40:59PM 0.3 3.3 0.0 120 20 1B.a 0.0 9.8 8:41:14 PM 0.3 3.4 0.0 9.0 20 19.6 0.0 7.88 6:4129PM 0.3 3.4 0.0 130 1.9 19.4 0.0 10.68 6:41:44PM 0.3 14 0.0 9.0 1.9 19.1 0.0 &84 6:41:59 PM 0.1 1.4 0.0 7.0 21 20.S 0.0 &64 6:42•14PM 0.1 1.3 0.0 12o 20 201 0.0 19.2 8:4229PM 0.1 1.3 0.0 7.0 20 20.7 0.0 10.58 8:42444 PM 0.1 1.3 0.0 &0 20 203 0.0 11.52 8:42:59 PM 0.1 1.3 0.0 11.0 z t 20.3 0.0 11.62 8:43:14PM 0.1 1.2 0.0 7.0 21 20.7 0.0 9.8 6:4329PM 0.1 1.3 0.0 120 21 21.0 0.0 11.52 8:43:44 PM 0.1 1.2 0.0 10.0 21 21.3 QO 9.6 8:43:69 PM 0.1 1.3 0.0 6.0 22 21.6 0.0 9.8 6:44:14PM Q1 1.3 0.0 11.0 22 224 0.0 11.52 6:4429PM 0.1 1.2 0.0 9.0 23 2z9 0.0 9.8 6:44:41 PM 0.1 1.3 0.0 10 23 23.4 00 11.52 8:44:59 PM 0.1 1.3 &o 13.0 24 23.8 0.0 105a a:45:14PM 0.1 12 0.0 &0 24 23.6 0.0 9.8 6:4529PM 0.1 1.3 0.0 &0 23 23.0 0.0 1248 8:46:44PM 0.1 1.2 0.0 13.0 21 2Q7 &0 9.8 8:46:59 PM 0.1 1.3 0.0 9.0 21 20a 0.0 10.66 8:4a:14PM 0.1 1.3 0.0 &0 20 20.4 0.0 11.52 6:4629 PM 0.1 1.3 0.0 13.0 20 20.2 0.0 9.8 6:48:444 PM 0.1 1.3 0.0 &0 20 20.1 0.0 1248 8:4a:S9PM 0.1 1.3 0.0 10.0 2o 20.1 0.0 10.66 8:47:14PM 0.1 12 0.0 9.0 20 202 QO 10.66 8:4729 PM 0.1 1.3 0.0 7.0 20 201 0.0 11.62 8:47:44PM 0.1 13 0.0 120 20 20.1 QO &84 8:47:59 PM 0.1 12 0.0 7.0 20 19.9 0.0 11.52 8:48:14PM 0.1 1.3 0.0 10.0 20 19.9 0.0 9.8 8:4829 PM 0.1 1.3 &o S.0 20 19.9 0.0 9.8 6:48:44 PM 0.1 1.2 0.0 120 20 20.1 0.0 10.56 6:48:59PM a1 1.2 0.0 8.0 2o 20.3 0.0 &64 8:49:14PM , 0.1 1.2 a0 &0 2o 204 0.0 10.58 8:4929PM 0.1 1.3 0.0 14.0 z1 20.5 0.0 &84 8:49:44PM 0.1 1.3 0.0 7.0 21 20.6 0.0 7.88 6:49:59PM 01 1.3 0.0 14.0 21 20.6 0.0 9.6 8:50:14 PM 0.1 1.2 0.0 130 20 2a4 0.0 5.72 6:5029PM a1 1Z 0.0 7.0 20 201 a0 9.6 8:50:44 PM 41 1.2 0.0 13.0 z0 20.1 0.0 &a4 8:60:59PM 0.1 1.3 0.0 7.0 2o 20.0 0.0 7.68 8:51:14 PM 0.1 1.2 0.0 10.0 20 20.2 0.0 10.58 6:6129 PM 0.1 1.3 0.0 13.0 20 20.3 a0 7.68 8:51:44 PM 0.1 1.3 0.0 &0 2o 20.3 Oo &64 6:61:69PM &1 1.3 0.0 120 2o 20.2 &0 9.8 6:52'14 PM 0.1 1.3 0.0 &0 20 20.2 0.0 7.88 8:5229PM a1 1.3 0.0 &0 20 2a0 &0 10.58 6:52:44 PM 0.1 1.2 0.0 11.0 20 20.1 0.0 &64 8:62:39 PM 0.1 1.3 0.0 7.0 20 20.2 0.0 9.6 8:53:14 PM 0.1 1.2 0.0 10.0 20 20.3 0.0 10.56 a:5329PM a1 1.2 0.0 12a 21 20.8 0.0 &64 8:53:44 PM 0.1 1.3 0.0 &0 21 20.8 a0 10.58 a:53:59 PM 0.1 1.2 a0 13.0 21 206 0.0 9.6 6:64:14 PM 0.1 1.2 0.0 &0 21 20.5 0.0 &a4 0:6429 PM 0.1 1.3 0.0 &0 20 20.4 0.0 11.52 6:64:44 PAA 0.1 1.2 0.0 13.0 20 20.3 0.0 &54 8:64:39PM 0.1 1.3 0.0 10.0 20 20.1 0.0 10.6e 8:66:14 PM 0.1 1.3 0.o 7.0 20 19.9 0.0 9.8 6:5629PM a1 1.2 0.0 11.0 2o 19.6 0.0 7.08 

# 35

P~ 2 

# 9z1213R8

8:55:44 PM a1 1.3 0.0 7.0 z0 19.8 0.0 10.58 8:55:59 PM 0.1 1.2 0.0 120 2o 19.7 QO 7.68 8:58:14 PM 0.1 1.2 0.0 &0 z0 19.5 0.0 7.68 8:5829 PM 0.1 1.3 0.0 &0 z0 19.5 0.0 9.8 8:58:44 PM 0.1 1.3 0.0 10.0 2o 19.8 0.0 5.78 8:58:59 PM 0.1 1.2 0.0 3.0 2o 19.8 ao &84 8:57:14PM 0.1 1.3 0.0 7.0 20 19.8 a0 &72 8:5729PM 0.1 1.2 0.0 10.0 2o 19.9 a0 a72 8:57:44PM at 1.2 0.0 &o zo 19.9 a0 &84 8:57:59PM a1 1.2 0.0 9.0 20 19.9 0.0 R72 8:58:14PM 0.1 1.2 0.0 13.0 20 19.9 0.0 &84 8:5829PM a1 1.2 0.0 &o zo 20.0 0.0 7.88 8:58:44 PM 0.1 1.3 0.0 13.0 zo 20.0 0.0 8.72 8:58:59PM 0.1 1.4 0.0 14.0 2o 20.0 ao 9.8 6:69:14 PM 0.2 1.5 0.0 9.0 zo 19.9 a0 &72 8:5929 PM 0.2 1.5 0.0 14.0 20 19.9 0.0 9.8 8:59:44PM 0-2 1.8 0.0 &0 2o 2a1 0.0 &84 8:59:59PM 0.2 1.5 0.0 7.0 20 20.1 QO 6.72 7:00:14PM 0.2 1.6 0.0 120 20 2a3 0.0 10.58 7:0029 PM 0.2 1.8 0.0 &0 20 20.3 0.0 7.68 7:00:44 PM a2 1.8 a0 11.0 z0 2a4 0.0 &84 7:00:59 PM a2 1.7 0.0 &0 zo 20.3 0.0 9.8 7:01:14 PM 0.2 1.8 0.0 8.0 20 20.3 0.0 7.88 7:0129 PM 0.2 1.8 0.0 9.0 zo 20.0 a0 10.58 7:01:44PM 0.2 1.8 0.0 8.0 zo 20.1 0.0 &64 7:01:59 PM 0.2 1.5 0.0 7.0 zo 19.9 0.0 9.8 7:02:14 PM 0.2 1.5 0.0 12o 20 20.0 0.0 1a58 7:0229PM 0.1 1.4 0.0 &0 20 19.9 0.0 7.88 7:02:44PM 0.1 1.4 0.0 13.0 z0 19.9 0.0 11.62 7:02:59PM 0.1 1.4 0.0 120 z0 19.9 0.0 &84 7:03:14 PM 0.1 1.3 0.0 &0 2o 19.9 0.0 172 7:0329 PM 0.1 1.3 0.0 13.0 zo 19.9 a0 9.8 7:03:44 PM 0.1 1.3 0.0 8.0 2o 19.8 a0 &72 7:03:59 PM 0.1 1.2 0.0 9.0 20 19.7 0.0 &64 7:04:14PM 0.1 1.2 0.0 13.0 z0 19.8 0.0 7.68 7:0429PM 0.1 1.3 0.0 -z0 1.9 19.4 0.0 6.78 7:04:41 PM 0.1 1.3 0.0 &0 1.9 1&9 0.0 9.8 7:04:59 PM 0.1 1.4 0.0 10.0 1.2 121 0.0 &72 STop R8 AvwEW 1.71 9.65 17.86 9.56

7:06:14PM 0.1 1.1 0.0 &0 0.2 1.7 0.0 &84 7:0529PM ai 1.1 0.0 5.0 a2 1.5 a0 10.58 7:05:44 PM 0.1 1.1 0.0 11.0 0.1 1.3 0.0 9.8 7:05:59 PM 0.1 1.1 0.0 8.0 0.1 1.2 0.0 13.44 7:08:14 PM 0.1 1.1 0.0 11.0 0.2 22 0.0 10.58 7:0629PM 0.1 1.1 0.0 8.0 0.2 22 0.0 1248 7:08:41 PM 0.1 1.1 0.0 12o 0.2 21 0.0 14.4 7:08:59 PM 0.1 1.1 0.0 9.0 0.2 21 0.0 11.52 7:07:14 PM 9.3 33.1 0.0 6.0 0.o 0.0 0.0 14.4 7:0729PM 3.3 33.4 0.0 11.0 0.0 0.0 0.0 1248 7:07:44 PM 3.3 314 0.0 7.0 0.0 0.0 0.0 1248 7:07:59PM 34 33.5 0.0 &0 0.0 0.0 0.0 1538 7:08:14 PM 3.3 33.4 0.0 120 0.0 0.0 a0 1248 7:0829PM 25 2&1 0.0 5.0 QO 0.0 QO 14.4 7:08:44PM a1 1.3 0.0 10.0 a2 1.8 ao 14.4 7:08:59PM a1 1.2 ao 11.0 7.2 72.4 ao 15.38 7:09:14PM Qi 1.2 0.0 8.0 &B 8&1 0.0 19.2 7:0929PM 0.1 1.2 0.0 7.0 9.0 89.6 0.0 1&38 7:09:44 PM 0.1 1.1 0.0 11.0 9.0 9a2 0.0 1&32 7:09:59 PM 0.1 1.2 0.0 5.0 7.4 74.3 a0 1726 7:10:14 PM 0.1 1.1 0.0 7.0 4.7 47.4 0.0 14.4 7:10?9PM at 1.2 QO 8.0 0.2 1.8 QO 1&32 7:10:44 PM 0.1 1.1 0.0 5.0 0.0 0.2 0.0 1248 7:10:59 PM 0.1 1.1 a0 11.0 0.0 0.0 0.0 1248 7:11:14 PM 0.1 1.2 0.0 4.0 0.0 0.0 0.0 14.4 7'.1129 PM 0.2 1.5 a0 10 0.0 ao ao 11.52 7:11:44PM 0.2 1.6 0.0 10.0 0.0 QO 0.0 14.4 7:11:59PM 0.2 1.5 0.0 8.0 0.0 0.0 0.0 1248 7:12'14PM 0.2 1.6 0.0 3.0 0.0 0.o 0.0 11.52 7:1229 PM 0.1 1.3 0.0 11.0 0.0 0.0 0.0 3.84 7:12:44PM 0.1 1.3 0.0 8.0 0.0 0.0 0.0 Q96 7:12:59PM a1 1.2 0.1 57.0 0.0 0.0 QO 1.92 7:13:14 PM 0.1 1.2 0.1 9&0 0.0 0.0 0.0 1.92 7:1329PM 0.1 1.2 0.1 97.0 0.0 0.0 - ao -0Ae 7:13:44 PM a1 1.2 0.1 103.0 0.0 Qo 0.0 4.8 7:17:59PM a1 1.1 0.1 101.0 0.0 0.0 QO a88 7:14:14PM 0.1 1.2 at 7&0 QO 0.0 0.0 266 7:1429PM at 1.3 ao &0 0.0 0.0 0.1 89.12 7:14:44 PM 0.1 1.2 (XO 0.0 0.0 -0.1 0.2 20926 7:14:59PM a1 1.1 0.0 7.0 0.0 4).1 0.2 2Z7.62 7:15:14PM a1 1.2 a0 3.0 0.0 -0.1 0.2 22&8 7:1529 PM 0.1 1.2 0.0 &0 0.0 Qt 0.2 227.52

36
Pup3 

# l7

# APPENDIX C



# ~~ 

# r

# PARTICULATE ANALYTICAL DATA FORM Company: Athens Bdck Date: 

# 12/13/95 Location: Kiln Ex PW Run 

# I Run 2 Run 

# 3 Density (Pa) 

# .:::..:::::.:.:.d

.. . . . ....... . . .......... 

# 0 : 1851 ~ 

# Blank Concentrabon (Ca) 1. 

# 05E 6.;i Rinse Volume (Vaw) 7 - 

# 777:7: :200., :125: Residue in Rinse (Wa) = Ca*Vaw*Pa 

# 0.0011 0.0007 0.0010

Date of Weighing Gross Weight 106.14 7: 7. :::4:06.4984.

.... ........ 

# Date of Weighing Gross Weight 

# 10&71.47. ...406. 1 4985s: Average Gross Weight 

# 111.2209 106.7147 106.4985 Less Blank Residue (Wa) 77.7o. 0 000 1 

# 7 Tare Weight 

# 06.706 2 - Weight of Particulate in Rinse (grams) 

# 0.0195 0.0078 0.0171

.. 

# Date of Weighing ........ .. ... . .......... 

# 2j. 1.21 4M: Gross Filter Weight OA6W:: -0.4597 Date of Weighing 

# 1 V, 1 41N.: 12/14195. Gross Filter Weight GqQ64 1 : 0.4599 Average Gross Weight 

# 0.4667 0.4263 

# 0.4598 Filter Tare Weight 

# A1.08. Weight of Particulate on Filter (grams) 

# 0.0559 0.0162 0.0447 Total Weight of Parficulate (mg) 

# 75.3 24.0 

# 61.8



# ACETONE BLANK ANALYTICAL DATA FORM Blank Volume (Va) Date of Weighing 

# 12/15/95: Gross Weight -.114.71122. Date of Weighing . ...... ... 

# Gross Weight 1 . 44.71 1 89:. Average Gross Weight 

# :4.71905

Tare Weight 2 114.7185r: Weight of Blank (Ma) 

# 0.00055 Ca= Ma/(Va*Pa) 

# = mg/g 

# 7.005E-06



# ~ Note: In no case should a blank residue greater than 

# 0.01 mg/g or 

# 0.001 % of the blank weight be subtracted from the sample weight.



# 37

# PARTICULATE ANALYTICAL DATA FORM Company: Athens Bdck Date: 12/13/95 Location: Kiln Ex PW Run 4 Density (Pa) .::. 

# :-.. 6 .7 

# 86t.. Blank Concentrabon (Ca) Rinse Volume (Vaw) 

# j 75.1 

# Residue in Rinse (Wa) = Ca*Vaw*Pa 0.0010

Date of Weighing Gross Weight Date of Weighing Gross Weight 

# QT0428.1 Average Gross Weight 

# 107.0429 Less Blank Residue (Wa) 

# 7. 770-oa.1-0;

Tare Weight Weight of Parficulate in Rinse (grams) 0.0325

Date of Weighing Gross Filter Weight Date of Weighing 

# 121 

# 1 

# `4196.: Gross Filter Weight 

# 0.4787. Average Gross Weight 

# 0.4786 Filter Tare Weight Weight of Parficulate on Filter (grams) 

# 0.0661 Total Weight of Particulate (mg) 

# 98.5



# ACETONE BLANK ANALYTICAL DATA FORM Blank Volume (Va) ... . 

# ...... 

# :::



# ...... 

# 40 Date of Weighing 

# 12115/95. Gross Weight 

# 1.14.7192.. Date of Weighing 

# 1V1:5/0 Gross Weight Average Gross Weight 

# 114.71905

Tare Weight 

# 1: 4.71851. Weight of Blank (Ma) 

# 0.00055 Ca= Ma/(Va*Pa) = mg/g 7.005E-06 Note: In no case should a blank residue greater than 0.01 mg/g or 0.001 % of the blank 

# weight be subtracted from the sample weight.

38 

# /G/'P

# PARTICULATE ANALYTICAL DATA FORM Company: Athens Brick Date: 12/13/95 Location: Klln Ex Imps 1&2 Run 1 Run 2 Run 3 Run 4
Total Volume Aliquot Volume, mis 100.0000 100.0000 100.0000 100.0000 Date of Weighing 12l1519 ~ 

## [2f1.5/95; 12M5195' 12115195 Gross Weight 'i.03:3232! 106:0655:: "::i 1i;4;51:59; iOgi3257 Date of Weighing 1~ 

## l15L95 t2115195: 1?115195: 12/t5/95 Gross Weight 103.32361: 1`06.0658.; 11:4.5161 109:3258 Average Gross Weight 103.3234 106.0657 114.5160 109.3258

Tare Weight i0.
~ 

## .3207 1'Q6.Q636: 'i:1:4.;515t ~ 

## t05:3235: Weight of Particulate in Rinse, mg 2.7000 2.0500 1.0000 2.2500 Adjustment for Aliquot=RV/Aliquot 3 3 4 3

Total Particulate, mg 8.10 6.15 4.00 6.75



# 39 

# lO/

# 100.5219 : 0:0006: 1 Q0:51'it
~ 

# ;

; ........ ': 

# 72f1. 195.

0:4194.' 0.4195 0 4133 n nn--.l

,G 7 

# PARTICULATE ANALYTICAL DATA FORM Company: Athens Brick Date: 12/13/95 Location: Dryer Ex PW Run 1 Density (Pa) 

# Q;:7851::: Blank Concentration (Ca) 

# 7 aU5E::0 ~ 

# Rinse Volume 

# N aw 

# [:



# ) 00: Residue in Rinse (Wa) = Ca*Vaw*Pa 

# 0.0006 : :12f1:5I95;:

.......... ... 

# 9 100:52
~ 

# 9i': Date of Weighing Gross Weight Date of Weighing Gross Weight Run 2 6:18M 

# ;: 7:OQSE-06; 1`00:: 0.0006 ' '[=2f15l9S 101:::98'18:: :''.....

. 

# 101 9616': Run 3 

# Q:78Si'; '7:aO5E-06: —. :. ---- 

# ': s0 A /1A/1. 

# 1:2/15/95: 1:05:1254 4 ;


# 105:1253: Average Gross Weight Less Blank Residue (V11a)

Tare Weight Weight of Particulate in Rinse (grams)

Date of Weighing Gross Filter Weight Date of Weighing Gross Filter Weight Average Gross Weight Filter Tare Weight Weight of ParGculate on Filter (grams) Total Weight of Particulate (mg) 101.9817 

# 105.1254 :.0:0006. 

# O::aOa4; : 'C:01:9.7C4 

# 1:05

~ 

# 1 'I'89; 0.0048
:;13:4231 ~ 

# 0:4:1::63? . 17J14

~ 

# g5:; 

# I0't4/9S:: 0:424 0.4240 0.4164 

# 777 T4jW 14C: 

# 0.0091 0.0017

4 7 n 7 0 

# ACETONE BLANK ANALYTICAL DATA FORM Blank Volume (Va) 

# . .. Date of Weighing 

# l?11:5L95`; Gross Weight 

# 114:7492 Date of Weighing 

# 12f1:S{S5: Gross Weight Average Gross Weight 

# 114.71905

Tare Weight 

# 11;4:T1':85 Weight of Blank (Ma) 

# 0.00055 Ca= Ma/(Va*Pa) = mg/g 

# 7.005E-06 Note: ln no case should a blank residue greater than 0.01 mg/g or 0.001 % of the blank 

# weight be subtracted from the sample weight. 

# 40 / ~ 

# Z

# PARTICULATE ANALYTICAL DATA F®RM Company: Athens Brick Date: 12/13/95 Location: Dryer Ex Imps 1&2 Run 1

Rinse Volume Aliquot Volume, mis Date of Weighing Gross Weight Date of Weighing Gross Weight Average Gross Weight

Tare Weight Weight of Par6culate in Rinse, mg Adjustment for Aliquot=RV/Aliquot

Total Pardculate, mg Run 2 Run 3



# 100.0000


# 96.a 34a 12f15
~ 

# 95r: 96.1334':' 96.1341 _ . .. ..........

L A /1f%A

J 

# 15.3 

# 100.0000



# `1711 

# Sla5 105:9626 

# !?Jibl ~ 

# 1:05.96:1:.3 

# 105.9620 105:9609 1.0500 3 3.15 

# 100.0000

. 12/'j5195 1:09.093::
1.09.0922:: 109.0926 1 Q9':Q&7S: G , /1! 

### ~ !1 .

J 

# 15.3



# 41 /02

# Sheetl

Summary of Fluoride and Chloride Analysis Plant: Athens Brick, Athens, TX 

# Date: 12/13/95 Kiln Exhaust R# Volume Dilution FI, ug/ml HF, mg CI, ug/ml HCI, mg 

# 1 300 10 58.98 186.3178 58.94 181.771 1 300 100 8.15 257.4585 1.55 47.802 3 400 10 38.68 162.9202 10.79 44.36848 4 300 10 48.04 151.7584 18.33 56.52972 Dryer Exhaust 1 300 1 23.87 7.540533 4.68 1.443312 2 300 1 26.04 8.226036 5.57 1.717788 3 3001 1 6.07 1.917513 1.01 0.311484



# 42 Page 1 

# /a ~~

# Component Ezternal Units

(unknown) N/A (unknown) N/A F- 2.00 ug/,1 (unknown) N/A 

# Cl- 3.00 ug/al

Br- 1.29 ug/ 

# NO3 9.62 ug/al
(unknown) N/A (unknown) N/A 1 • 

# ~ _ 

# ~—
2 4 ' ~ 

# 3 ~

5 

# 4

5
~ 

# . 

# 6

1 8 : 

# Description = Channel 1 Conditions : 2.00 Fluoride std



# : 3.00 Chloride std Date : 12/15/1995 Time = 11=47=58

—51.200mV 512.00OmV


# 0.416 2.150 41.80 0.125 3.166 45.30 1.116 39.609 282.61 M 1.358 1.132 10.16 M 1.116 49.283 536.05 M

2.991 5.340 99.59 M 3.375 35.013 356.60 M

4.475 0.469 13.35 M 5.050 2.350 55.34 M Rete 

# ntion Height Area

91-- •



# 0

43 / 

# ~~

# Description : Channel 1

Conditions = 10.0 Fluoride std

: 15.0 Chloride std Date : 12/15/1995 Time = 12=01:23

–51.200mV 512.00OmV Component 

# (unknown) F



# C1-
BrNO3


# (unknown) (unknown) PO4- 

# External Units

N/A 10.00 ug/al 15.00 ug/al
0.26 ug/ 3 4 : 41.07 ug/o1 ~ 

# 4 i. 

# N/A '? 

# 5 — N/A 0.55 ug/sl 6
7— : 

# ntion Height Area 0.533 2.690 83.15 1.116 132.713 122.75 M 1.683 146.185 2473.12 M

3.016 1.530 19.65 M 3.300 174.343 1898.69 M

4.175 11.829 471.29 N 5.316 1.589 17.66 M 5.691 0.977 11.54 M

1 1 !=

44 ~0 ~

# Description : Channel 1

Conditions = 20.0 Fluoride std

: 30.0 Chloride std Date : 12/15/1995 

# Time : 12:13:38

–51.200mV 

# Component Ezternal Units (unknown) N/A (unknown) N/A F- 20.00 ug/ 

# o1 C1- 30.00 ug/ A 512.00OmV 

# Retention Height Area 0.000 48.900 951.05
0.891 9.366 60.65 1.141 243.032 1483.06 1.691 209.159 3458.73



# Br- 2.03 ug/ NO3 91.92 ug/ 

# al (unknown) N/A (unknown ) 

# N/A ~ ~

~ :• 

## 1 ~ 

# ~ -' 1 

# 1 — --

~ 

# 3

4 ;i



# 5 I• 6 ;

1
8

9

10
11 

# 2.841 7366 156.14 3.383 316.818 4583.23
4.225 11.329 296.63 4.650 0.160 45.00



# 45 /~ ~

# Calibration file = F.CAL

AMOUNT INJECTED AREA 0.000 20.000 

# 0.000 1

- 

# rA

K

4 1483 .060 

# Avg slope of curve= 90.78 Y-axis intercept= 0.00 Coeff of lin regr = 0.64 

# No. Area Amount CF 0: 0.000 0.000 0.000 1= 282.610 2.000 141.305 2= 722.750 10.000 72.275 3= 1483.060 20.000 74.153

46


# ~~~

# Calibration file = CL.CAL

AMOUNT INJECTED AREA 0.000 30.000 0.000 1
2

3

4 3458.730 

# Avg slope of curve: 135.27 Y-axis intercept= 0.00 Coeff of 1 i n regr : 0.76 

# No. Area Amount CF 0: 0.000 0.000 0.000 

# 1: 536.050 3.000 178.683 2= 2473.120 15.000 164.875 3: 3458.730 30.000 115.291

47 

# IG 

# ~

# Description : Channel 1

Conditions : Athens Brick

: 12/13/95 

# = Kiln Ex Imps 1&2 = Run #1 : 1/10 dilution 300 ml Date = 12/15/1995 Time = 13:56:04
Coaponent (unknown) -51.200mV



# External Units N/A 512.00OmV 

# Retention Height Area



# 316.11 1 : •ti •''
~ 

### '~-


# 2 = _

3 

## 1 

# 1 ~ 4

5 ~
6

1
8 ~

9

10
11 

# (unknown) N/A F- 58.98 ug/a C1- 58.94 ug/a

NO3 2.02 ug/i Br- 0.51 ug/® 

# 0.000 11.900 0.808 13.082 132.67 1.183 612.299 4446.88 1.775 195.145 5360.53

3.115 5.369 74.99 3.491 2.637 39.05

48 • 

# // L,

# Description = Channel 1

Conditions : Athens Brick

= 12/13/95 = Kiln Ex Imps 1&2 = Run #1 : 1/100 dilution 300 ml Date : 12/15/1995 Time : 14:10:08

—51.200mV 512.00OmV Component Ezternal Units 

# R etention Height Area (unknown) N/A 0.666 0.883 100.19 F- 8.15 ug/sl 

# lr; 1.133 89.284 621.22 M C1- 1.55 ug/sl 1.116 30.133 277.81 M

1
1



# 49

# Description : Channel 1



# Conditions : Athens Brick

= 12/13/95 

# = Kiln Ex Imps 1&2 = Run #2 

# = 1/10 dilution 300 ml Date = 12/15/1995 Time = 14:18=37

(unknown) N/A F- 17.63 ug/ C1- 7.45 ug/ —51.200mV



# sl 

# ~ ®11 ,r-- 2


# 3 (:

4

5 6

1 8 ~


# 9

10
11 512.00OmV 

# Retention Height
0.125 0.000 1.141 201.992 1.125 51.941 Area

42.83 1302.19 M 1254.41 M 

# Coeponent Ezternal Units

50 )12-,

# Description 

# : Channel 1

Conditions 

# = Athens Brick



# : 12/13/95 

# : Kiln Ex Imps 1&2 

# = Run #3 

# : 1/10 dilution 400 ml Date 

# : 12/15/1995 Time 

# = 14:57:17

—51.200mV 512.00OmV CoAponent External Units

_ 

# R etention Height Area (unknown) N/A 0.758 12.204 156.75 F- 38.68 ug/al 1.158 462.260 2903.15 M C1- 10.79 ug/sl 1.133 101.197 1794.15 M

1

51 

# 11-3

# Description = Channel 1

Conditions = Athens Brick

= 12/13/95 

# = Kiln Ex Imps 1&2 = Run #4 = 1/10 dilution 300 ml Date = 12/15/1995 Time = 15=11=17

—51.200mV 512.00OmV 

# Coaponent EXternal Unit (unknown) N/A F- 48.04 ug/A Cl- 18.33 ug/u 

# s M R

1 1 2
3

4

6

1
8

9

10 • 11 ~ 

# etention Height Area
0.600 0.600 108.32 1.166 549.983 3614.74 M 1.133 111.432 2692.00 M

" 52



# ~ 

# l Y

# Description : Channel 1



# Conditions : Athens Brick

= 12/13/95 

# : Dryer Ex Imps 1&2 = Run #1 

# = 300 ml Date = 12/15/1995 Time = 15:15:26

—51.200mV 512.00OmV 

# Co®ponent Ezternal Units tention Height Area (unknoan) N/A 0.625 13.642 395.81 F

- 

# 23.87 ug/el 1.166 279.910 1177.59 M 

# C1- 4.68 ug/a1 1.775 63.210 801.40 M

9

10
11

53 ~~~

# Description = Channel 1

Conditions : Athens Brick

= 12/13/95 

# = Dryer Ex Zmps 1&2 = Ru n #2 

# = 300 ml Date = 12/15/1995 Time = 15:22=41

–51.200mV 

# External Units 512.00OmV 

# Co®ponent (unknown) 

# F



# C1-

N04- N/A 1 – •



# 26.04 ug/i1 — 

# 5.51 ug/ml ~ 

# - =

2

. ; . 9• 3
0.90 ug/ 4 

# ention Height Area
0.175 13.508 157.24 1.166 313.369 1942.58 M 1.766 64.308 950.48 M

3.908 0.045 15.63 M

1
8

9

10
11 ~



# 54. jI /

# (unknown) N/A el 1

~

~ 

# l 

# •T ~'—.. 2
3

4

5
6


# 1
8

9

10 

# 11 •— (unknown) N/A (unknown) N/A1 ug/ C1- 1.01 ug/ 0.166 1.610 22.86 1.133 69.100 506.63 M 1.483 5.078 108.55 M 1.100 24.918 181.05 M

2.825 2.113 58.12 M 

# Description = Channel 1 Conditions = Athens Brick

= 12/13/95 

# : Dryer Ex Imps 1&2 = Run #3 = 300 ml Date = 12/15/1995 Time : 15:31:11

–51.200mV 512.00OmV 

# Component External Units Retentien Heiaht 

# Area

55 117

# Description = Channel 1

Conditions : Athens Brick



# = 12/13/95 : H20 blank Date : 12/15/1995 Time = 16=18:30


# Conponent



# ~ unknown unknown 

# unknown 

# ~ F

-

# Cl

# Ezternal Units

N/A 

# N/A N/A 0.98 ug/nl 0.34 ug/o1 -51.200mV

~ 

# - ;- 

# :i 512.00OmV 

# Retention Height 0.125 3.365 0.433 11.416 0.141 18.965 1.150 9.560 1.691 5.100 

# Area

56.48 285.35 130.16 138.30 M 60.80 M (unknown) 

# N/A 2.650 3.926 115.42 M

(unknown) 

# N/A 6.625 3.516 102.90 M

1

56 /l 

# ~

# APPENDIX D



# 11,5 ~

# PARTiCiJLATE F3ELD DATA .-o

PLANT : IvAcwS og/'JC/C Y 

# DATE : 12 43- j S 

# REPETITION:t
LOCATION: 4 4e iR i / .74 

# OPERATOR : aB

~ 

# gi

~ 3 

# STACIC #:l{Zq eX 

# SAMPLE BOX '

1r: METER BOX #:8 AMB IENT TEMPERATURE : 70 ° BAROMETRI C PRESSIIRE 

# ;;LQ- 6 Z' ASSUMED P40ISTQRE: S°(o PROBE LENGHTV ' 4pEX-66 

# NOZZLE DIAMETER••2`

~ 

# g/•

~ y ~~ •z `~~ C• ~~ ) ~ J 

# C , 

# oO 

# ~ 33 YSS 

# ~ STACR D IAI

~ 

# TER :

~ 

# . S w X Z 5 L 

# METER H 

# C FACTOR: ~ 

# y METER CO-EFFICIENT 

# :/. 0a63 o 3 FILTER TARE : I t//d 

# PRE-TEST LEAK CHECK Meter: Cu. ft.is 

# in. HG Pitots: ~ ~ 

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# el ZI ~ 

# I I 2SS' 1 6g- I/ sa 1 47 I j ( ( I I; ,! 1 1.0 W. I I 7g f Z y4-' 1 6 7 1 / 

# I?y fy I I I I I 62 1 

# V 

# 7 , 4771 I 1 v I I I i I 1 i?f.SlS' r 1► 

# I ` I ' i~ ~

# APPENDIX E



# /Z, ~

# BOC GASES

SLJL. :7c15e5 

# Divi s ion ofi the BOC uroup, Inc. 1075 Cincla'r , e Dr , ive Port Allen, LA 7k.

~ 

# 767 Customer , Order No. : SF725 Shipper IVo. : 716519 Test No. . 0895-001 

# ;NFL`!TICAL RF_-'ORT 

# To : iiOC RETialL 

# DALLAS, TX BOC GASES 1075 Gnclare Drive Port Allen 

## Louisiana 70767 Telephone: 504-3 88-0900 

## FAX: 504-388-0959 Date Repor-ted: 08/01/95



# Material Submitted: CARBON MONOXIDE IN NITROGEN Inrormation Requested: CARLON MONOXIDE CONCENTRATION r+lethed of i=Hnalysis: NON—DISF'ERSIVE INFRARED Result of Investigation: Cy1.No. : CC40334 

# Comoonent Specification Concentrat i on CARriON MONOXIDE 400 F'F'M 398 PF'M +/— E% 

# N I TROGEN BALANCE 

# LiALANCE

A Division ofThe BOC Group.lnc. e 

# 63 Alithor , ized Signatur•e /~ 7

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. 

# Scott Specialty Gases

500 WEAVER PARK ROAD. LONGMONT, CO 80501 (303) 4424700. (303) 651-3094 FAX: (303) 772-7673



# CERTiFiCATE OF ANALYSIS: EPA Protocol Gas

Customer Assay Labontory Pluchase Order 1515 

# ARMSTRONG ENVIRONMENTAL Scott speQalt y Gases, Inc. Scott Projed x 0820996 7715 SOVEREIGN ROW 500 Weaver Park Road CGA Fittin g 660 DALLAS TX 75247 Lon g mont, CO 80501 File Nnmber 20996-03



# ANALYTICAL INFORMATION Thls certification was performed according to EPA Traceability Protocol for Assay and Certification of G.tseous Glibration Standards; Procedure Gl; September,1993. 

## Cylinder Number ALM-053354 Certification Date 08/30/95 Expiration Date 08/30/97 Cylinder Pressnre 1857 psig Previous Certification Dates 

## None ANALYZED CYLINDER Components Certified Concentration Analytical Uncertainty' (Sulfur Dioxide) 451 ppm t1 % Directly NL4T Traceable

(Nitrogen) Balance •Ana)ytical uncertainty is inciusive of usual known error sources which at least includes pr<avion of the measurement ptocesses 

## REFERENCE STANDARD Type Expiration Date Cylinder Number Concentration NTRM 1661 05/25/96 ALM-040325 468.9 ppm S02 / N2



## INSTRUMENTATION Instrnment/Model/Serial li Last Date Calibrated Analytical Principle Nicolet FTII2 / 8220 / AAB9400251 08/21/95 Scott Enhanced FTII2 TM



# ANALYZER READINGS (Z=Zero Gas R=Reference Gas T=Test Gas r-Correlation Coefficient) Components First Triad Analysis Second Triad ?.nalysis Calibration Cnrve (Sulfur Dioxide) Oau 08123195 Response Units: ppm Oato 09r30195 Rasponse Units: ppm Conpntratlon • A+gx+Cx2+Ox3+Ex4 Zt - 0.204 Rt - 488.900 T1 - 451.236 Z1 - 0.073 Rt • 4e8.900 Tt = 449.923 r- 0.99999 R2 • 4e9.513 Z2 • 0.3Be T2 = 451109 R2 - 4e8.597 Z2 • 0.302 T2 = 450.171 Constarttx A - 0.07994e3 Z3 - 0.403 T3 • 451.210 R3 - 4e9.158 Z1 • 0.149 T3 • M9.627 R3 - 468.373 B- 0.9587 C. 0 Avq. Cono. of Cyl. a 451.35 ppm Avg. Cona of Cyl - 449.91 ppm D• 0 E- 0 

# 000

(. - I

.. - 

## Spedal Notes Do not use when rylinder pressure is below 150 psig. 

# 70

# Scott Specialty Gases

500 WEAVER PARK ROAD. LONGMONT. CO 80501 (303) 442-4700. (303) 651-3094 FAX: (303) 772-7673



# CERTiFiCATE OF ANALYSIS: EPA Protocot Gas

Customer Assay Laboratory Purchase Ordm 1515 

# ARMSTRONG ENVIRONMENTAL Scott Specialty Gases, Inc. Scott Project M 0820996 

# 7715 SOVEREIGN ROW 500 Weaver Park Road CGA Fitting 660 

# DALLAS TX 75247 Longmont, 

## CO 80501 File Namber 20996-04



# ANALYTICAL INFORMATION ThCs certification was performed accordinp, to EPA Traceabilitv Protocol for Assav and Certification ot Gaseous C.dibration Standards; Proczdure Gl; September,1993. Cylinder Number ALb1-053368 Certification Date 08/30/95 Expiration Date 08/30/97 Cylinder Pressare 1847 psig Previous Certification Dates None 

## ANALYZED CYLINDER Components Certified Concentration AnalKtical Uncertaintv' (Stilfnr Dioxide) 235 ppm tl % Directly NLSI' Traceable

(Nitrogen) Balance •Analvtica) uncertaintv fs 'uxlusive of usual known ertor soun:es which at Icast includes prrciaion of 

### the measurement processes. 

## REFERENCE STANDARD Type Expiration Date Cylinder Nnmber Concentration 

## NTRM 1661 05/25/96 ALM-040325 468.9 ppm S02 / N2



## INSTRiJMENTATIaN Instrnment/Model/Seriai 

## M Last Date Calibrated Analytical Principle Nicolet 

## FIIR / 8220 / AAB9400251 08/21/95 Scott Enhanced 

## FTII2 TM



# ANALYZER READINGS- (Z=ZeroGas i'.=ReferenceGas T=TestGas r=CorrelationCoeffic:ent) Components First Triad Anal 

### sia Second Triad Analysis Calibration 

### Cnrve (Sulfur Dioxide) Date 0829195 Rssponse Unns: ppm Data 08130/95 Rssponse Unitr. ppm Concantraoon A*Bx•Cs2+Dx3+Ex4

Zt 

### • 0.204 R1 

### • 488.900 T7 

### - 225.201 Zt 

### = 0.073 R7 

### - 488.900 T7 

### = 224.479 r- 0.99999 R2 

### - 489.513 Z2 

### - 0.388 T2 

### • 225.835 R2 

### - 488.597 Z2 

### = 0.302 T2 

### - 224.104 Constants: A= 

### 0.0799483 Z3 

### • 0.409 T3 

### - 225.095 R3 

### - 489.158 Z3 

### - 0.148 T3 

### • 224.294 R3 

### = 488.373 8- 0.9597 C. 0 Avg. 

### Cono. of Cyl m 

### 225.31 ppm Avg. Conc of CyL 

### = _ 224.29 ppm 0= 0 E- 0 

# 000

71 Special Notes 

## Do not use when rylinder pressute is below 150 psig. 

# 135

# APPENDIX F



# 136

# Pre Test Meter Calibration

Meter Box Number 

# = 8 Average Y Average H Calibration Date 

# = 11/10/95 1.020303 1.533344 Calibrated By »> DB Barometric Pressure (Hg) 

# = 29.48 Point #1 Point #2 Point #3 Point #4 Point #5 Point #6 Delta H 0.5 1 1.5 2 3 4 Test Meter Volume 5 5 10 101 11 10 Meter Box Volume 4.908 4.836 9.597 9.5441 10.361 9.334 Test Meter Temperature (F) 70.5 71 71.5 72 72.5 73 Average Meter Box Temp (F) 74.75 76.25 77.75 79.5 80.75 81.75

Time (minutes) 11.7 8.17 13.75 11.71 10.351 8.14 Test Meter Y 0.985 0.975 0.97 0.965 0.9571 0.958 Meter Box Y 1.025627 1.041537 1.050316 1.057276 1.070115 1.078183 Meter Box Corrected Y 1.010243 1.015498 1.018806 1.020271 1.0241 1.032899 Meter Box H 1.549364 1.509585 1.601971 1.547061 1.497584 1.494501

72 

# /j,7

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# Enclosu_re 2 NOT SUBJcCT TC iilE REu

~ 

### :!REA'ENTS OF ~ 

### SECTION 3507. PAPER;iORK RE7UCTIOt4 ACT OF 1980. I 

# INFORMATION REQUEST FOR BRICK AND STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS I. Instructions Please return the completed information request to: Bruce C. Jordan, Director Attn: Bill Neuffer Emission Standards Division (IVID-13) U. S. Environmental Protection Agency Offce of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 If you need clarification.of any question or item, please contact Mr. Bill Neuffer of EPA at (919) 541-5435. 

# This information request should be completed for each facility that manufactures brick and structural clay products, including facilities that are not major sources. Information is requested for all processes at your plant that emit hazardous air pollutants (HAP's), including those processes that are not associated with brick and structural clay products manufacturing. Sections II through VII request information specific to brick and structural clay products manufacturing, and Section VIII requests information on emissions of HAP's from other processes located at the facility. Processes that may emit HAP's include those processes that use or handle any materials that contain a HAP compound, all processes with elevated temperatures, and all other processes in which HAP compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this information request. Attachment 2 provides background information on the requirements of the Clean Air Act and explains how the information requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations and acronyms used in this information request. Several tables are provided throughout the information request for your convenience in answering the questions. An example response is given (shaded first column or row) in each table. If additional space is needed to respond, please make copies of applicable pages. If necessary, please make copies of this information request for additional facilities. No additional emission testing or monitoring is required to respond to this request. H. General Facility Information A. Name of company At-hens Brick CorTpany Name of facility Athens Brick - M.i.neral Wells Plant



# Page 1 of 28 

# 1--0

# Facility address: No. and street 7510 Highway 180 East


# City Mineral Wells State TX 

# Zip 76080 

# Latitude and longitude coordinates of plant: Standard Industrial Classification (SIC) Code(s) of brick and structural clay products manufacturing operations 3251 

# Dun and Bradstreet No. 041083403 

# Total No. of employees for company 2350 for facility 19 

# (If facility is a foreign subsidiary or if company has foreign subsidiaries, include number of employees not based in the U.S.). Please complete the following shift information for the facility: Shift No. of employees Hours per shift Days per year 1 17 8-10 345 2 1 / 8 365 

# 3 1 8 365 

# B. Respondent name Robert B. Cai.n 

# Respondent title Senior Environme.ntal Engineer 

# Respondent address (if different from above) and telephone number: No. and street 1341 W. Nbckingbird Lane
City 

# Dallas State TX 

# Zip 75247 

# Telephone No. (_j 972/647-3932 

# Name and telephone number of technical contact person (if different from above) Name Telephone No. (__) III. Information on Ogerating

~ 

# Permits and Applicable Federal Emission Standards 

# A. Please provide copies of relevant parts of all operating permits and permit applications for your facility. Relevant parts include the sections that providespecific information and data on: processes that emit HAP's; the use of HAPcontaining substances; emission levels for HAP and surrogate pollutants (i.e., VOC Page 2 of 28 

# /~ 

# -V

# for organic HAP's and PM for metal and other particulate HAP's); emission control device design and operation; monitoring and operation and maintenance (O&M) procedures for control devices; and generation and releases of other media such as wastewater and solid waste that are associated with the operation of air pollution controls for brick and structural clay products manufacturing processes. If the operating permit or application contains the same information requested in any part of this questionnaire, you may respond to the requested information by referencing the page or section of the permit/application to avoid duplication. If you reference your permit or application, you must supplement your response with all of the additional information requested in this questionnaire that is not included in the permit or permit application. If you prefer, you may submit the requested information from your permit/application on a 3-'/i inch diskette. B. If any source or emission unit at this facility is subject to a New Source Performance Standard or other Federal emission standard, please identify the source and applicable standard. Examples of applicable NSPS include 

# 40 CFR 60, Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing Plants, and 

# 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in Mineral Industries.

/



# IV. Brick and Structural Clay Products Production and Raw Material Consumption Information A. Please provide the 1996 production rates and the current production capacity for each type of brick and st.ructural clay product manufactured (e.g., structural brick, clay sewer pipes, structural clay tile, etc.). Note that production data should be provided in units of tons per year (tons/yr).
Product 1996 production (tons) Production capacity (tons/yr) Face brick 45,000 55,000 esttmated

Page 3 of 28 

# Z'~~

# B. Please provide the type and amount of each raw material and body additive used in 1996 for manufacturing brick and structural clay products at your facility. Examples include clays, shale, and any additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade name. If the information requested is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. Raw materiaVbody additive Amount used in 1996 (tons/yr) Clay/shale 45,000 Iron oxide 14,400 Manganese d.foxide 1.5 

# Epsom salt 0.525

C. If available, please provide a copy of the MSDS's for the raw materials and additives listed above. D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above.

Page 4 of 28

/ ~~

# E. Using Table 1, please provide information on the consumption and HAP composition of all glazes and colorants that contain HAP's or HAP precursors and that your facility applies to brick and structural clay products. Indicate whether the coatings are glazes or colorants. Also indicate the type of product that the coatings are applied to and the total weight of coatings used in 1996. If the glazes or colorants are formulated at your facility indicate so and provide the production capacity. List each ingredient of the glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient used in 1996. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. F. In the space below, please indicate any glazes or colorants used by your facility that do not contain HAP's and are substitutes for HAP-containing glazes or colorants used by your industry. Indicate which HAP-containing materials the non-HAP glazes or colorants replace. Describe any limitations on the use of those substitute glazes or colorants. None

G. If your facility colors brick and structural clay products by flashing, please indicate the types of substances used to flash the products and the amounts of those substances used in 1996. Substance Amount used in 1996 Units (specifv)

H. If availabk, please provide a copy of the MSDS's for the glazes and colorants used by your facility. If your facility prepares its own glaze, please provide any available MSDS's for the glaze ingredients.

Page 5 of 28 

# /.5 7

# TABLE 1. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND CnT.OR ANr.q

Type (e.g., glaze, colorant) 

# II Type of product glazed or colored 111996 consumption (tons/yr) 11 Produced at facility? (yes/no) I Production capacity (tons/yr) . >'.. 

# Structurai tile:;
' ~~ '':. ~ .:.' :..' ..: !

~~ ! .: ~ qi.:.•.

~~ r`.i

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- h'•S

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# Colorant

Face brick

1.5

0



# Total usage (weight) of each ingredient (that is a HAP, contains a HAP, or is a HAP precursor) in 1996 • •• i

~ •r ~ 

## °°2 ~

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## 7. -af '"

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# If additional space is required, please make copies of this page. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. Page 6 of 28

~ 

### / • 

## ~

# V. Description of Brick and Structural Clay Product Manufacturing Processes A. Please provide a simple process flow diagram for each brick and structural clay product manufacturing process line. An example process flow diagram is provided in Figure 1. A diagram of the plant layout with all processes and emission points clearly labeled is also acceptable. Assign a unique identification number (ID No.) for each process that has associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. Please identify all emission points, including those that do not emit HAP's. For emission points that are vented to an air pollution control device (APCD), assign an ID No. to.the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information request for any responses that pertain to any process or emission point.

Page 7 of 28
/.~~

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# Page 8 of 28 

# / t-c

# B. Using Tables 2A and 2B, please provide current production rates, production capacities, and related information for each type of equipment used in brick and structural clay product manufacturing. In Table 2A, provide the requested information for only those sources that are known or expected to emit HAP's. In Table 2B, provide the requested information for all thermal processing, such as drying and firing sources. For combustion sources that use different fuels, Table 2B should be completed for each type of fuel. For example, if a kiln typically is fired with gas, but periodically is fired with oil, one column in Table 2B should be completed for the kiln when fired with gas, and another column should be completed for the same kiln when fired with oil. Provide the data in the units listed for each row.

Page 9 of 28



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# lb-3

# C. Using Table 3, please provide information on procedures used to monitor the process operating rate for each of the pieces of equipment and HAP emission sources listed in Tables 2A and 2B. Use the same HAP emission source types and equipment ID numbers you listed in Tables 2A to 2B. Indicate whether you 

# monitor process rate or not. Provide a 

# sununary of process rate monitoring procedures that describes how process rate is measured for the particular piece of equipment. Include where the rate is monitored (i.e., rate of material fed, rate of material discharged, or material production rate), the units used to measure process rate (e.g, lb/hr or pieces/hr), and how the process data is 

# recorded, i.e., manually, automatically (e.g., computer - printout or stored to disk, or not at all). If you monitor process rate at both the feed and discharge ends of the equipment, indicate so. Indicate the 

# type of monitor, equipment, or instrument used to measure process operating rate. Indicate the 

# monitoring frequency or how often process rate measurements are made. If instruments are used to measure process throughput, indicate in the 

# monitor accuracy column the accuracy of the instrument. The monitor accuracy could be listed in terms of a percentage of the throughput (t 

# 1 percent), mass per unit time (±21b/hr), number of pieces per unit time (t 10 pieces/hr), or other appropriate units. Indicate the 

# frequency that the monitor is calibrated. Provide data in the units listed for each row.

Page 12 of 28 

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# / 6a. 

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# VI. Identification of Brick and Structural Clay Product Manufacturing Emission Points A. Use the process flow diagrams developed for your facility and Table 4 to provide the following information for each HAP emission source at your facility. • Define HAP emission source type in terms of equipment, such as dryers, kilns, etc. As in the process flow diagram, you may group multiple pieces of similar equipment. • Use the same equipment ID numbers indicated on the process flow diagram(s). • If the 'emission source vents inside a building or to outside ambient air without first passing through a control device, place a check mark in the uncontrolled column. • If the emission source vents inside a building or to outside ambient air after passing through a fabric filter, dry injection fabric fillter, or scrubber, place the APCD ID number(s) in the column corresponding to the APCD type. • If the emission source vents through a control device type not listed in Table 4, indicate the control device_ type in the other control column and place the APCD ID number in the appropriate cell. • In the emission test data column, place a"yes" or "no" in the appropriate cell to indicate whether the specific source has been tested for My pollutants, including any HAP's, VOC, PM, or opacity.

Page 14 of 28 

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# 167

# B. Using Table 5, please provide information on stack parameters and emission estimates for each emission point at your facility that is known or expected to emit HAP's. Provide information for all APCD's, including those that exhaust inside the building. Include data for each inlet and outlet, if available, as indicated in the table. If you have more than one inlet to an APCD, provide data for each of the inlets. Provide data in the units listed for each row. Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal HAP's or VOC for organic HAP's. Emission estimates may consist of measurements reported in emission test reports or may be calculated using mass balances, emission factors, engineering judgement, or other estimation methods. Provide the emission estimates as emission factors in units of lb of pollutant emitted per ton of product (lb/ton). 

# Provide complete copies of any emission test reports or other reports that document measurements

.of emissions. Test reports and other emission measurement documents should include the following information: process identification; location of sampling point; stack diameter, temperature, and flow rate; test method, including analytical procedures; number of test runs; emission concentration, emission rate, percent oxygen, and percent moisture for each test run; process operating rate; type of APCD; and APCD operating parameters. However, test reports with incomplete documentation may still be useful and shouid also be submitted. You do not need to fill out Table 5 for emission points that are covered by an emission test report that is included in your submittal. 

# If emission test reports are not available, provide calculations that support your emission estimate, including the basis for all assumptions in the estimate. Note that emission estimates are needed for all HAP's that the facility emits or has the potential to emit. (Please refer to the HAP list in Attachment 1.) If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 16 of 28 

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# C. Using Tables 6A through 6D, please provide design and operating data for each APCD associated with all dryers, kilns, and any other brick and structural clay products manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of APCD's. Use Table 6D for other types of APCD's. When using Table 61), please specify the type of control device and 2 to 4 key design or operating parameters for the device. Provide data in the units listed for each row. If the information requested in Tables 6A through 6D is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the tables.

Page 19 of 28 

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# D. Using Table 7, please provide the following information on current monitoring procedures for each of the control devices listed in Tables 6A to 61): parameters monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices used (e.g., differential pressure transducer, thermocouple), and recordkeeping practices (e.g., manually recorded in log book, continuously recorded by electronic data acquisition system). Describe briefly other operation and maintenance (O&M) procedures for each control device. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table. VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing A. Please describe all pollution prevention practices (i.e., process modifications, such as re-use of discarded or rejected materials, or any practice that prevents or reduces the amount of air emissions, or the generation and release of solid waste or wastewater associated with the operation of air pollution controls). If the information requested here is contained in your facility's operating perrriit, you may reference the applicable sections of the permit rather than providing the information below. 

# Broken fired ware and unfired reject greenware are added into the raw material feed.

Page 24 of 28 

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# VIII. Information on Processes Other Than Brick and Structural C1av Products Manufacturing



# Processes A. Using Table 8,

- please identify all other processes or operations at this facility that are not addressed in Items II through VII above and that are potential sources of HAP emissions. Estimate total annual emissions of each HAP emitted by these colocated processes. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 27 of 28 

# / 7 /
~

# TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES

Process/emission source/SIC Code(s) HAP's emitted trace metals;
com 

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SIC If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.
Page 28 of 28 

# /z

# Material Safety Data Sheet
Substance Identification Identity: MANGAIVESE DIOXIDE CAS #: 1313-13-9 Trade Names: Brickox, GranuSpeck . .. Manufacturer: The Pr3nce Manufacturing Company Emergency: Chemtrec One Prince Plaza 1-800-424-9300 Quincy, II. 62301 

# 217-222-8854 

# Components and Contaminants

. Chemical Name CAS # OSHA PEL ACGIH TLV Percent 

# Manganese Compound (as Mn) 7439-96-5 5 mg/m 3 (C) 5 mg/m 3 (C) 51-55% Mu Iron Oxide 1309-37-1 --- --- 1-5% Fe Z O 3 Silica, Crystalline Quartz (respirabl.e) 14808-60-7 0.1 mg/m 3 0.1 mg/m 3 (TWA) 1-5% Si0 Aluminum Oxide (non-fibrous) (respirable fraction) 1344-28-1 5 mg/m 3 15 mg/m 3 (TWA) 1-7% Al 2 0 3 Barium Oxide 1304-28-5 --- --- 0.2-2% Ba0 

# Physical Data Boiling Point: NA Specific Gravity (H 2 0 =1): 5.0 Vapor Pressure (mm/Hg): NA Melting Point: (Decomposes) 535 ° C Vapor Density (Air =1): NA Evaporation Rate (Butyl Acetate =1): NA Solubility in Water: insoluble 

# Appearance and Odor: black to brownish black, no odor 

# Fire and Explosion Hazard Data Flash Point: Not combustible Flammabie Limits: LEL NA UEL NA Extinguishing Media: Foam, CO , or dry chemical. Special Fire Fighting Procedures: In the event of fire, wear full protective clothing and NIOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Unusual Fire and explosion hazards: Not combustible, but substance is a strong oxidizer and its heat of reaction withreducing agents or combustibles may cause ignition. Increases the f7ammability of any combustible substance. 

# Reactivity Data Stability: Stable under ordinary conditions of use and storage. Conditions to avoid: Do not heat or grind in the presence of easily oxidizable substances or organic 

# matter. Incompatibility (materials to avoid): Easily oxidizable substances, sulfur, sulfides, phosphides, hydrophosphides. chlorates, peroxides, aluminum powder, rubidium acetylide, potassium azide, chlorine tritluoride. Reacts with hydrochloric acid to form corrosive chlorine 

# gas. Hazardous Decomposition or Byproducts: Upon heating it decomposes to form manganese sesquioxide and oxygen which facilitates combustion. Hazardous Polymerization: Will not occur.

Manganese Diozide, Page i Reviewed October 1994 Unchanged since July 1991



# 1~ 

# /

# Health Hazard Data

Route of Entry: INHAI.ATION: May irritate the respiratory tract. May inerease the incidencc of upper respiratory infections (pneumonia). Prolonged exposure to silica dust may result in silicosis, a fibrotic lung disease. SKIN: May cause irritation. INGESTION: May cause abdominal pain and nausea. Manganese dioxid4 dust is poorly absorbed through the gut. Health Hazards (Acute and Chronic): Chronic exposure and inhalation of excessive manganese dust mav cause disorders of the central nervous system. Carcinogenicity: NTP: No IARC Monographs: Yes (Silica) Signs and Symptoms of Exposure: Early symptoms of manganese toxicity include sluggishness, sleepiness, an,i weakness in legs. Symptoms of silicosis indude impaired pulmonary function and wheezing. Aggravation of Pre-existing Conditions: Persons with impaired respiratory function may be more susceptible to the effect of this substance. Emergency and First Aid Procedures: IF INHAI.ED, remove to fresh air and seek medical attention for anv breathinc! difficulty.IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. IN CASE OF EYE CONTACT, flush eyes immediately with water for at least 15 minutes. Seek medical attention if irritation persists.

- IF INGESTED, induce vomiting immediately by giving two glasses of waterand sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

# Precautions for Safe Handling and Use Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory protection. Recover uncontaminated material for use. Vacuum or sweep remaining material, keeping dust to a minimum. Isolate wet material from drv and store away from combustible materials. Waste Disposal Method: Dispose of unreclaimable material in a RCRA-approved waste facility. Handling and Storing Precautions: Manganese dioxide is classiSted as an oxidizer and should be stored in a dri place away from combustibles and sources of high heat. Protect containers from damage and keep closed when not in use. Other Precautions: Observe good personal hygiene. Wash after handling. 

# Control Measures Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or i<anticipated. USBM approved schedule 21B respirator or equal is recor,imended. Ventilation: A system of local and / or general exhaust is recommended to keep employc: exposures below the Airborne Exposure Limits. Loca1 exhaust is generall% preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details. Protective Gloves: Yes Eye Protection: Safety goggles are recommended. Other Protective Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonaci 

# exposure to skin. Work and Hygienic Practices: Observe good personal hygiene. Wash after handling.



# SARA Title III Section 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emercenc ~ 

# Planning and Community Right-to KnowAct of 1986 and of 40 CFR 372.45: Coml2onent 

# Manganese Dioxide Barium Oadde 

# C AS # bv Weight 1313-13-9 51- 55% Mn 

# 1304-28-5 0.1 - 1.8% Ba This information must be included in all MSDS's that are copied and distributed for this material. Manganese Dioxide. Pa;c _ Reviewed October 1994 Unchanged since Jul ~ 

### I ,'-:



# J~ 

# y

# CLAY

MATERIAL SAFETY DATA SHEET

SECTION 

# 1 -: IDENTI' i Y
Name Address TXI OPERATIONS, LP 1341 W. MOCKINGBIRD LANE, DALLAS, TEXAS 75247 Emergency Telephone Number Person Responsible for Preparation Date (972) 647-6700 NANCY GARNETI' SEPTEMBER 1996 Common Name (used on label) Chemical Family CLAY SILICATE Chemical Name Fonnula DOES NOT APPLY A HETEROGENEOUS BLEND OF SILICA, ALUMINA, FERRIC Trade Name & 

### Synonyms OXIDE, CALCIUM OXIDE, MAGNESIUM OXIDE AND WATER. NONE 

# `SECTION 2: -'HAZARDOUS>!INGREDIENTS:; Harardous Componeat CAS # % Typical TLV (Units) PEL (Units) CIAY 100 NUISANCE MINERAL DUST: FOR CLAY WITH < 1% QUARTZ - RESPIRABLE 5 mg/m' FOR CLAY WITH < 1% QUARTZ - TOTAL DUST 10 mg/m' 15 mg/m' OUARTZ CONTAINING DUST: FOR CLAY WTTH > i% QUARTZ - RESPIRABLE .1 mg/m' 0.1 mg/m' FOR CLAY WTfH > 1% QUARTZ - TOTAL DUST 30 mg/m'/% Si0 = +2
PEL: Permiasibla Expaeure Limit eatablished by the Oeoapational Safety and Hea11h Admiaiatration (OSHA). TLV: Threshold Limit Vahre established by the Ameriean Confeteace of Goveromental Industrial Hygienists (ACGIID.

. 

# : SECTTQN T . - PHYSICAL 'DATA Boiling Pofnt Spxific Gravity (H t 0 = 1) Vapor Pressure (mm = Hg) > 3000 deg F 2.5 DOES NOT APPLY Percwt Volatile by Volume Vapor Density (Air = 1) Evaporation Rate (n=Butyl Acetate) 0% DOES NOT APPLY DOES NOT APPLY Percent Soluble in Water Reactivity in Water INSOLUBLE WII,L NOT EVOLVE FIAMMABLE OR TOXIC GASES Appearance and Odor EARTHY, FINE GRAIlVED POWDER OR AMORPHOUS SOLID. NO ODOR. Huardous Material Information Svstem Identitier (HMIS1 HEALTH = U FLAMMABII.ffY = 0 REACTIVITY = 0 PERSONAL PROTECTION = X

_ .:... ,. 

# SECT. IQN 4:' -..FLRE AND. EXPLO.SLQN DATA : : ; ... ..: .. .
Flash Point DOES NOT APPLY pgkguWiing Media DOES NOT APPLY Unusual Fire and Explosion Haurds NONE Special Fire Fighting Pracedures NONE TXI031 Temporary Flammabk Limits in Air (% by Vohume) Lower. DOES NOT APPLY UPper. DOES NOT APPLY Auto Ignitioa Tempaature DOES NOT APPLY



# 1,0

# SECTION 5 -..HEALTH INFORMAT.ION

Signs and Symptoms of Exposure -(1) Acute Ovcrexposure INHALATION: EXPOSURE TO A LARGE CONCENTRATIONOF DUST MAY CAUSE IRRITATION. SKIN: NONE. EYE: PARTICLES IN THE EYE MAY CAUSE IRRITATION. INGESTION: IlVTESTINAL OBSTRUCTION. Signs and Symptoms of Exposure -(2) Chronic Overexposure INHALATION: REPEATED EXPOSURE TO LARGE CONCENTRATIONS OF DUST MAY CAUSE PNEUMOCONIOSIS. SYMPTOMS OF PNEUMOCONIOSIS ARE PAIN IN THE CHEST, COUGH, DYSPNEA, REDUCED THORACIC EXCURSION, SOMETIMES CYANOSIS, AND FATIGUE AFTER SLIGHT EXERTION. THE PNEUMOCONIOSIS MAY TAKE THE FORM OF SILICOSIS IF A HIGH CONCENTRATION OF FREE SILICA IS CONTAINED IN THE CLAY. SKIN: NONE. EYE: NO DATA AVAII,ABLE. 1NGESTION: NO DATA AVAIIABLE. Medical Conditions Generally Aggravated by Exposure RESPIRATORY DISORDERS OR DISEASES. ChenticallComponeat Listed as Carcinogen NTP IARC OSHA QUARTZ YES YES NO Other Exposure Limits QUARTZ: 30 MILLION PARTICLES PER CUBIC FOOT - ACGIH WORKPLACE EXPOSURE. Emecgency & First Aide Procedures for Indicated Routes of Entry EYE CONTACT: IMMEDIATELY FLUSH EXPOSED AREA WITH WATER OR NORMAL SALINE FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN CONTACT: WASH AREA WPCH WATER. INHALATION: REMOVE FROM EXPOSURE. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN AND CONSULT A PHYSICIAN IMMEDIATELY. INGESTION: TREAT SYMPTOMATICALLY AND SUPPORTNELY. GET MEDICAL ATTENTION. 

# SECTION 6 - REACTIVITY DATA Stability Conditions to Avoid 

### STABLE HANDLING PROCEDURES WHICH MAY GENERATE DUST. Incompatibility (Materials to Avoid) MOLTEN LITHIUM ATTACKS SQ,ICATES. Hazardous Decomposition or Combustion Products DOES NOT APPLY Hazsrdous Polymerizatioa WII.L NOT OCCUR 

# SECTION 7= SP.ILIs .:OR LEAK PROCED:LTRES: Steps to be Talcen in Case Material is Leaked or Spilled WEAR NIOSH/MSHA APPROVED ABt PURD?YING RESPIRATOR W1TH A PARTICULATE FILTER TO PREVENT DUST EXPOSURE. WEAR PROTECPIVE GOGGLES TO PROTEGT AGAINST EYE IRRITATION. PICK UP SOLID MATERIAL W1TH A MQQASUM OF DUSTiNG. Waste Disposal Method GENERALLY NOT RESTRICTED. CONSULT APPROPRIATE FEDERAL, STATE, AND LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES.

. ::. ; .



# SECTION 8: PERSONAL PROTECTIQN:TNFORMA

~ 

# ION`!; Respiratory Protution PROVIDE GENERAL VENTII.ATION AND LOCAL EXHAUST. NIOSH APPROVED DUST FILTER RESPIRATOR SHOULD BE USED IN DUSTY CONDII'IONS. Ventilation SUFFICIIIVT TO MAIIVTAIN AIRBORNE CONCENTRATIONS BELOW THE THRESHOLD LIIu1Tf VALUE (TLV). Protective Glovea Eye Protection 

### NOT REQUIItED, THOUGH RECOMMENDED FOR LONG TERM EXPOSURE. CLOSE FITTTNG SAFETY GOGGLES Other Prafective Cladting or F.quipment WEAR PROTECCIVE CLOTHIIVG, SUCH AS LONG SLEEVE SHIRT, LONG PANTS EXTFlVDING OVER THE TOPS OF WORK SHOES, TO PREVENT SKIN CONTACT. AN EYEWASH SHOULD BE AVAILABLE NEAR WORK AREA. PERSONAL PROTP.CITVE CLOTHIIVO AND USE OF EQUIPMENT MUST BE IN ACCORDANCE WITH 29 CFR 1910.132.

_.



# ` SEC

~ 

# *ZU

~ 

# 1 `9 ~ 

# SPECIAL PRECAUTIONS Precautioaa to be Talcea in Handling & Storing WEAR APPROPRIATE SAFETY EQUIPbffiVT AND CLOTHIIdG TO PREVENT INHALATION, SKIN, AND EYE CONTACT. Other Precautioos 

## NONE
TXI031 Temporary



# I~ 

# k

### d 

# 49 HARCROS 

# MATERIAL SAFETY DATA SHEET wwwrs


# Harcros PIgments Inc. Producx: SYNTTiETIC / NATURAL 11 Fxecutive Dr., Suite 1 IRON 03QDE BLENDS Fairview Heights, IL 62208 MSDS No. PIGMENT / HPI-024 Revision: Revision 2 Date: August 1994


# 11.4ZARD MATERL4L IDENTIFICATION SYSTEM ' Health Haard 1 - Slight Flammability Hazard 0 - Minimal Reactivity Harard 0 - Minimal Personal Protection E- Glasses, Gloves, Dust Resp 

# SECT70N I. MATERfAL IDENT7FICA770N 'IYade/Material Name : 

# Desctigtion • 

# Other Designations

• 

# Chemical Name • 

# MANUFACTURER • SYNTHETIC / NATURAL IRON OXIDE BLENDS Iron Oxide - - - NR-4284. NR-4686 

# Fe : 0 3 Harcros Pigments Inc. PHONE: 618-271-4700 11 Executive Dr., Suite 1 E- St. Louis Plant Fairview Heights, IL 62208 ti,



## .- -- ~~



# SECTION II. INGREDIENTS AND- 1YAZARDS
INGREDIENT NAME : 

# CAS NUMBER : 

# PERCENT EXPOSURE LIMITS Nat'I Iron Oxide 1332-37-2 30-50' ACGIH TLV S mg/M 3 TWA (Iron Oxide Fume as Fe) Syn. Iron Oxide 1332-37-2 40-60' OSHA STEL: 10 ppm 

# (Iron Oxide Fume as Fe) Barium Sulfate 772743-7 5-15' ACGIH TLY 10 mg/M 3 TWA total dust 

# OSHA STEL: 10 ppm Silica - Quartz 14808-60-7 0.1-1.5' ACGIH TZ.V 0.1 mglM 3 TWA Respirable Dust OSHA PEL: 10 mg/M 3 TWA Respirable Dust "Application Specific -7n .r- - 

# (Ingredients and Ha7ards continued on next page)

. ~ .-. - 

# ~ ~ E; - • , 

# HPI-024 Page 1 of 4
~

# (Ingredients and Hazards continued from previous page)

SARA TITLE III: Section 313 Supplier Notification Ihis product does not contain touc chetnicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-'Ib-Know Act of the 1986 and of 40 CFTt 372:

SECTION Ill. PHYSICAL/CHEMICAL CNARACTERISTICS

Annearance and Odor-. Reddish Brown Powder, No Odor Solubility ir. Water (96): Insoluble Speciflc Graviry (H:0=1): - _- --49-5.1



# SECTION IV. FIRE AND EXPLOSION DATA

~ 

# F1ash Point (method): Non-tlammable Limits: L.EI.96: N/A UEL96: N/A Exting_uishing Media: As appropriate for surrounding combusd'bles. Does not burn or support combustion. No fire or ezplosion hazard. Unusual Fre or Eaplosion Hazards: None Special Frefightinit Praxdures: Frefightets should wear self-contained bteathing apparatus.



# SECTION Y. REACTIVlTY DATA
MM



# Material is stable - Harardous polvmerization will not occur Chemical incompatibilities: None known
Hazardaus DecomRosition Products: Will not oa.vr

HPI-024 Page 2 of 4 ov !

# SECTION VI. ' HEALTH 11AZ,4RD DATA

Summary of Health Risks and Svmptoms of EaMure: Skin contact may cause mechanical irritation due to the abrasion. Eye contact will result in no specific effects other than general particulate irritation in the eye. Not absorbed by the body. Excessive exposure abov+e the TLY can give mild pulmonary irritation. Principal Routes of Entrv: Inhalation, ingestion, sidn and eye eontacL Accute Effects: Inhalation of the dust may cause mechanical irriation to the respiratory tract. Skf n and eye eontact may cause a mechanicral abrasion irritation. Chronic Health Effects(sl: Long term overexposure to silicra causes silicosis, a form of pulmonary fibrosis. Continued exposure to silicra can lead to cardiopulmonary impairment. Emergency and Frst Aid Procedures: Eye Contact: Flush thoroughly with plenty of water for at least 15 minutes. Get medical help if irritation persists. Skin Contact: Wash skin with mild soap and water. Inhalation: - - Remove to fresh air. Get medicral help for any breathing difHculty. Ingestion:

_ If conscious, give large quantities of water to inducx vomiting. Get medical attention. ' Crystalline silica which may be present 

# in quantities greater than 0.1% has been reviewed by IARG IARC found limited evidencx for carcinogenicity of crystalline silica in humans and sufficient evidence in experimental animals.



# SECTION VII. . PRECAUTIONS FOR SAFE HANDLING, USE OR DISPOSAL Spill / Leak procedures: Those involved in clean-up of spills should use respiratory protection for airborne dust. Vacuum or seoop up spilled material for recovery or disposal, avoiding dusting conditions and using good venilation. Wetting the spill with a water spray may help to keep the airborne dust levels down. Waste manatement / disposal: Refer to any local, State or Federal regulations for specific disposal information. Pursuant to 40 CF'R part 261 of the Resource Conservation & Recovery Act (RCRA) regulations currently in effect, discarded Iron Oxide would not be classified as a hazardous waste. Precautions to be taken in handlin¢ and storin¢: For transportation emergencies, call CHEMTREG 24 hour information service, (800) 424-9300.

HP1-024 

# Page 3 of 4 

# / S-'-7

# SEC?70N YIII. SPECIAL PROTEC?'ION INFORMATION :

Personal protective equipment 

# : Goggles: Safety glasses with side shields or dust tight goggles. Gloves: L,eather or rubber gloves. _ Respirator. If exposure limits are exoceded, an appropriate NIOSH approved dust respirator should be used.
Workplace Considerations 

# : Ventilation: Provide adequate exhaust ventilation to meet TLV requiremeats in - the workplacx. An exhaust filter system may be required to avoid environmental ' i = contamination. Safety Stations: An eye wash station should be available to the area of use. Other. Good industrial hygiene practioe requires that employee exposure be

- -- maintained below the recommended TLV This is preferably achieved through , the provision of adequate venu'lation where necessary. Where dust cannot be

- 

# c ontrolled in this way, personal respiratory protection should be employod.



# SECTION M SPECL4L PRECA UTIONS

DOT Class 

# • - Not regulated

Preparedhevised by: R. E. Rader August 1994

The infamatioa pteseated herein is believed to be aocvcate attd was obtained from sourca bdieved to be tr.liabk. tloweAa. the infotwatlon is pravided without atry t'epKSentation or wamnty, acptessed or implle4 with respea to its accvrary or completa>em 1t is tDe uaers' trspoosibiRty to detamine the suitabiGty of this pcodua aod the oelkvance o[ this information for their ux Hanros Pigmeats Iaa does not as,wme tiabitity tesultiag from the use, handlin=, stoca;e, and dispoaal of this product. 

# HPI-024 Page 4 of 4 

# ~~~

# Material Safety Data Sheet

May be used to Compiy with 

# OSHA's Hazard Communication Standard. 29 CFR 1910.1200. Standard must be consulted 'or spepfic requirements. 

# U.S. Department of Labor Occupational Safety and Health Administration (Non-Mandatory Form) 

# Form Approved OMB No. 1218

- 

# 0072 

# /

IDENl771f (As Used 

# on Lapel ano tJSt) 

# t Mota: 8lank 

# spacas a

~ 

# s nor Dennrtred ll any mam rs 

# not apWrcaGb. 

# or no 

# Bottom Ash ir / 

### onmaaan is ava,rabw, rrre 

# space musr oe mar*ad to 

# mmcav mar. Section I Manutaaurer's En ergency Telephprie Numoer 

# 214 944-7462 Addm r 

# ea ..;.... . (NumOer. Sbset Ciry. Statb. anO 7JP Code) Telephone NumOer for Informatan 

# 400 N. Olive Street 214 944-7462 Date Preparetl 

# P.O. Box 81 6/24/88 ^ Dallas, Texas 75201 Section 11 — Harardous Ingredients/[dentity Information ( / v Hatardous Components (Specifie Chemical Idenfity, Common Name(s)) OSHA PEL ACGIH TLV 4/0000na» 

# Crystalline Silica (Quartz) CAS/114808-60-7: 14 Respirable Fraction 0.63mQ/m 3 0.1 mg/m 3 Total Dust 1.88mg/m 3 - Crystalline Silica (Cristobalite) CAS#14464-46-1: 2 Resyirable Fraction 1.25mg/m 3 0.05ma/m 3 Total Dust 3.75mQ/m 3 Aluminum CAS#7429-90-5 - 10.0 mg/m 3 <10 Calcium CAS#1305-78-8 5.0 mg/m 3 2.0 mg/m 3 (Ca0) <7 Iron CAS#1309-37-1 10.0 mg/m 3 5.0 mg/m 3 (Fe0 Fume) . <6 Magnesium CAS#1309-48-4 15.0 mg/m 3 10.0 mg/m 3 (Mg0 Fume) <2

Section )It — PhysicaUCttemical Characteristics 8oding ParK SPeafic GravitY (H20 - 1) 

# NA NA VaPor Presswe (nun H4) μe" Pant 

# NA Vapa Osraty (AIR t) Eraporatia+ Raa 

# NA I (8utyl Acetate a 1► NA Saua* in wao.r 

# Insoluble in water. pH 3 5-6 Appearance and Odar 

# Granular. Section IV — Fre and Explos i 

# o n Hazard Data Fiaah Poutt (MethoC Used) I FlarttmabN Ci N A I LEL I UEL 

# NA Exarxguisrung Meoia 

# No special media required. Speaa! Firn F,qftng Proceoures 

# None.
Unuaual Fre and Exptos+on Hazards 

# None.
(ReoroCuce Iocalty)* 

# Composition may vary. NA = Not Available;Not Applicable. OSHA 174, 

# ~V~S

## Sectlon V — Reacttvity Data staodity UnstabN 

# I CondRfona oo Avoid



# Sw 

# " 

# I X None known. Incompatibiuty (Matena/s to Aroid) 

# None known. Hazardow oeoompoesbon or eyproauct: 

# None known. Hazaroous potyr

~ 

### lon 

## May Occiu CondiOOro to AMoid

Wil Nd OCCtr 

# X None known. Section VI — Heafth Hazard Data Routs(s) af 

# Erm

~ 

# r, lr>haterion? Skin? 

## inqesoon ? 

# YES YES YES Heatth Hax>R78 (AtLO and ClrorrC) 

# Acute: Eye, skin, and resDiratorv tract irritation. Chronic: Pneumoconiosis.CWcZno9W"carN 

# O ~ YE~? pSt

~ 

### A ReguWted? NO 

# Silica is listed in IARC monographs, volume 42. Sigra and Sympom ot EAxxR" 

# Skin or eye irritation; respiratory tract irritation. Medical Contlitions GeneratN AgWavaxed bY Enoo" 

# NA 

# Em

~ .y and Fr ~ 

# e Aid ProcearesFor e
~ 

# e contact, flu h e y 

# es wit water, see me ica attention. 

# or skin contact. wash e fected area. i 

# ~ redness or irritation develovs, seek attention. r'or inhaiatlon contact, ex Sertlon VII — Precautlom for 3afe HandNng and Use Sbps tD 8o Taksn in Case AAasenal Is Releas

~ 

## d oa SpiMd 

# Fresh bottom ash may be hot. Avoid stepping into areas of fresh bottom ash spillage. Handle bottom ash spillage to avoid creating airborne dust. Use wet methods or vacuuming to clean up spills. Waam oispoQW Mett+od 

# No special procedures required. Handle as an inert bulk material. Material may be disDosed of in sanitary landfills. P+scautions to Ba Takan in Har%lirg and Storv

~ 

## g 

# _ Fresh bottom ash >nav be hot. Avoid orolontted skin contact. Handle bottom ash to avoid creating airborne dust. othsr Precauoona 

# NA
Section VIII — Control Meaaurcs Resar&ImY P+%x*c= ( ,

Vec+Y TYwl 

# Half-mask or fullface air-purifying respirator equippe wit 

# filters approved for protection a ainst pneumoconiosis producing dusts. Venniaoon Loai Ext+am o keep dust levels below PEL, 

# j gpocw 

# open conveyine s stems. NA Mectwtc;W (GaxrhTo keep dust levels belowOa>K P 

# EL. Recommended for confined areas. NA Pnx°ctiw Gov" E>e Pf ~ Safety glasses with side shields, 

# `?one normally required. 

# I Cover ¢oe2les. Ottw P+vtsctrvw Clottung or Equuprnant 

# Vone normally reauired. worwF+ygwuc Fracacaa 

# Practice good oersonal hygiene.
Rs" 2 1 M1_691-329/47773 ) 

# 1 ~

### IDENT/TV 

# BARIUM CARBONATE, PRECIPITATED AND CALCINED (ALL FORMS AND GRADES) AQUA-FLO@, MICRO-FLO*, TYPE FF, PHOTO GRADE, TYPE TV, AND TYPE CFF, TYPE S.



# k : , : ....: r ~ 

# ;, ,;;; ~ ~ ~ ^ ~ V ti 

# . a 

# Be 

# MATERIAL SAFETY DATA SHEET

TRADE NAME INCLUDES 

# 1 MANUFACTURER'S CHEMICAL PRODUCTS CORPORATION 

# NAME ADDRESS P.O. BOX 449, CARTERSVILLE, GEORGIA 30120 PREPARED BY: JERRY A. COOK, TECHNICAL DIRECTOR REGULAR TELEPHONE NO. Day 404/382-2144 Night 404/382-2212 EMERGENCY TELEPHONE NO. CHEMTREC 1-800-424-9300 

# 11 HAZARDOUS INGREDIENTS COMPONENT CAS NO. % HAZARD OSHA PEL ACGIH

TLV OTHER LIMITS

RECOMMENDED BARIUM CARBONATE 513-77-9 ca 99% TOXIC 0.5 mc ~/m~ 

# of Bar um 0.5 m/m ~



# of Bar um NONE 

# I11 PHYSICAL DATA BOILING POINT, 760 MM HG Not Applicable MELTING POINT- Decomposes to Barium Oxide ca 1000° C 

# PECIFIC GRAVITY (H

~ 

# 0=1) 4.4 VAPOR PRESSURE Not Applicable VAPOR DENSITY (AIR=1 ) Not Applicable SOLUBILITY IN WATER % BY WEIGHT 0.002°k (20°C) APPEARANCE AND ODOR White powder or granules. Odorless EVAPORATION RATE (BUTYL ACETATE=1) Not Applicable 

# IV FIRE AND EXPLOSION DATA FLASH POINT AUTOIGNITION (TEST METHOD) NON-FLAMMABLE TEMPERATURE NON-FLAMMABLE FLAMMABLE LIMITS IN AIR, % BY VOL. LOWER UPPER 

# NONE NONE NONE EXTINGUISHING MEDIA NO FIRE HAZARD SPECIAL FIRE Avoid contact with acid — large quantities of carbon dioxide will be evolved. FIGHTING Barium carbonate is toxic if ingested. PROCEDURES Avoid inhalation of dust.
UNUSUAL FIRE AND EXPLOSION NONE 

# HAZARDS While the information and recommendations contained in this publication are believed to be accurate forthis material when not in combination with others, Chemical Products Corporation makes no warranty or guarantee as to such information and recommendations. Proper use of the information contained herein and of the product are the responsibility of the user.


# Pag.; 1 of 3 Pages 1 

# lA1

# CHEMICAL PRODUCTS CORPORATION 

# BARIUM CARBONATE V REACTIVITY DATA ZONDITIONS CONTRIBUTING TO INSTABILITY 

# Very high temperature (ca 1000° C) causes decomposition to barium oxide and carbon dioxide. INCOMPATIBILITY 

# Acids will decompose barium carbonate to other barium salts with liberation of carbon dioxide. The reaciion 

# may be violenf. 

# HAZARDOUS DECOMPOSITION PRODUCTS 

# Barium carbonate may be decomposed to form other barium salts. AII water and acid soluble barium salts are toxic. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERZATION 

# None 

# VI HEALTH HAZARD INFORMATION ROUTES OF EXPOSURE HAZARD CLASSIFICATION BASIS FOR CLASSIFICATION i 

# SOURCE 

# ~ INHALATION Moderately Toxic Inhalation - Rat NIOSH 24 Hours Registry of Toxic Effects 

# ~ TCLo-1150 mg/m' of Chemical Substances. SKIN CONTACT Believed to be no hazard None None SKIN ABSORPTION Believed to be no hazard None None EYE CONTACT Believed to be irritant None None INGESTION TOXIC Oral - Human NIOSH LDLo - 57 mg/kg Registry of Toxic Effects Oral - Rat of Chemical Substances LDso - 418 mg/kg SYMPTOMB EXCESSIVE INGESTION MAY CAUSE EXCESSIVE SALIVATION, VOMITING, OF SEVERE ABDOMINAL PAIN, VIOLENT PURGING WITH WATERY AND BLOODY STOOLS, OVEREXPOSURE SLOW AND OFTEN IRREGULAR PULSE, MUSCLE TWITCHINGS PROGRESSING TO CONVULSIONS AND/OR PARALYSIS, DILATED PUPILS, CONFUSION, POSSIBLY DEATH. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: NONE CARCINOGENICITY: 

# NTP - NO 

# IARC MONOGRAPHS - NO OSHA 

# REGULATED - NO


# EMERGENCY AND FIRST A/D PROCEDURES EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER: ALWAYS SEEK MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. INHALATION: FLUSH MOUTH AND NASAL PASSAGES WITH WATER AS MUCH AS POSSIBLE. INGESTION: ADMINISTER ONE TABLESPOON OF EPSOM SALTS (MAGNESIUM SULFATE) OR GLAUBER'S SALT (SODIUM SULFATE) DISSOLVED IN WATER. IF VICTIM IS NOT VOMITING, INDUCE VOMITING BY GIVING SYRUP OF IPECAC OR BY STICKING FINGER DOWN THROAT. NOTES ITYPOKALEMIA IS OFTEN OBSERVED; POTASSIUM SHOULD BE ADMINISTERED — TO LARGE DOSES MAY BE REQUIRED. PHYSICIAN IN ACUTELY POISONED DOGS, POTASSIUM INFUSIONS CORRECTED ALL OF THE 

# CLINICAL SIGNS OF BARIUM POISONING EXCEPT THE HYPERTENSION. I



# Page 2 of 3 Pages 

# / 

# ~ 1i

# CHEMICAL PRODUCTS CORPORATION 

# BAR I U M CAR BONATE VII PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Try to keep material dry and away from acid. Sweep or scoop up spilled material. 

# Dispose of in an approved hazardous waste landfill or mix with excess sulfate to make material non-hazardous. NEUTRALIZING CHEMICALS 

# Can be made non-toxic by forming insoluble barium sulfate. React with sulfuric acid (caution - 

# reaction can be vioient). WASTE DISPOSAL METHOD Waste containing more than 0.2% soluble barium is hazardous. 

# Can be rendered non-hazardous by reaction with excess sulfate to form insoluble barium sulfate. Observe all federal, state, and local laws. PRECAUTIONARY STATEMENTS 

# 1. Reaction with acid can release large quantities of carbon dioxide which could lead to suffocation in a confined area. Use adequate ventilation. 2. A small amount of toxic hydrogen sulfide gas may be liberated on acidification (as an impurity). Use adequate ventilation. OTHER HANDLING AND STORAGE REQUIREMENTS Store awav from acids. 

# VI11 CONTROL MEASURES VENTILATION REQUIREMENTS Provide sufficient ventilation to remove dust. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY Use NIOSH approved dust mask if excessive dust is present. 

# EYE Safety glasses GLOVES General purpose OTHER CLOTHING AND EOUIPMENT 

# Cover exposed skin areas. Provide epsom salts as part of the first aid supplies.

Page 3 of 3 Pages 

# / 5~ ~

# ~ 

# s

PIEDMONT MINERALS COMPANY, INCORPORATED Subsidiary of RESCO Products. Inc. 

### P. O. BOX 7247 / GREENSBORO, N. C. 27407-0247 , TELEPHONE 919-292-0949



# November 15, 1985

TRADE NAME 

# Pyrofrac A-320, B-320, C-320 Pyrofrac A-720 Pyrofrac A-202 Pyrophyl A-100, B-100, C-100, D-100 Pyrophyl A-140, B-140 Pyroph.yl A-202, B-202 Pyrotrol W-200 Pyrotrol W-325 Pyrotrol R-065 Pyrotrol R-200 A1ka trol 213 

# Alkatrol 226 Seriphyl A, 

# B, C, D, G

FORINULA Andal usi te Al203 ' Si 02 

# Pyrophyllite Al203 - 4Si02 • H 2 0 Quartz Si02 Sericite (K20, Na0) - 3Al203 - 6Si02 - H20

PYROTROL;ALKATROL; PYROTROL'ALKATROL: PYROTROL, ALKATROLi PYROTROLiALKATROL

## U.S. UtNAFi I MLN I UF - LAt3UFH 

## Occupational Safety and Health Administration 

# MATERIAL SAFETY DATA SHEET rOrm raDPrOveO OMB No. 44-R1367 

# PY

~ 

# -

I Required under USDL Safety and Health Regulations for Ship Repairing, 

## (11-85) I Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917)



# SECTION I MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. 

# Piedmont Minerals Company, Incorporated (919) 292-0949 ADDRESS 

## (Number, Street, City, Stvte, and ZIPCode) 

# 3514 West Wendover Avenue Greensboro North Carolina 27407-0247 CHEMICAL NAME AND SYNONYMS ti Ser cl 

## t e 

# ~ silica), TRADE NAME AND SYNONYMS 

# Andalusite, 

# Pyr ophyllite, Quar L 

# z See Attachment CHE 

### M ICA ~ FAMILY 

# Alumi-num - Silicates FORMULA 

# See Attachment 

# SECTION II HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES, & SOLVENTS % Units ALLOYS AND METALLIC COATINGS % (Un ts) PIGMENTS 

## N A BASE METAL 

## N/A
CATALYST • [(T/A ALLOYS 

## N/A
VEHICLE 

## N/A METALLIC COATINGS 

# N/A
S OLVENTS 

## N/A FILLER METAL 

### PLUS COATING OR CORE FLUX 

## N A ADDITIVES 

## N/A OTHERS 

## N/A
OTHERS 

# N/A HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % 

## TLV (Units)



# SECTION III - PHYSICAL DATA BOILING POINT ( ° F.) 

# XIA SPECIFIC GRAVITY (H2O=1) 2,$5 VAPOR PRESSURE (mm Hg.) 

# N A PERCENT, VOLATILE 

### BY VOLUME (%) 

## N / 

## A VAPOR DENSITV (AIR=1) 

## N A EVAPORATION RATE ( =1) 

## N/A
SOLUBILITY IN WATER 

# I nsoj 

# ublk APPEARANCE AND ODOR 

## White 

# to off-white, granular 

# to powder, no 

# odor SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) 

# N A FLAMMABLE LIMITS 

# NIA Lel Uel
EXTINGUISHING MEDIA 

# N/A SPECIAL FIRE FtGHTING PROCEDURES

UNUSUAL FIRE AND EXPLOSION HA2ARDS ,


## PAGE (1) (Continued on reverse side) Form OSHA-20 Rw. 41aY 72 

# f ~.~

# I SECTION V- HEALTH HAZARD DATA THRESHOLD LIMIT VALUE 

## 0.53 MG/M 3 EFFECTS OF OVEREXPOSURE 

# Inhalation of dust over a prolonged period of time noy cause injury to 1un s. Airborne dust inay be irritating to e es. EMERGENCY AND FIRST AID PROCEDURES 

# NIA



# SECTION VI - REACTIVITY DATA
STABILITY UNSTABLE CONDITIONS TO AVOID 

## N/A STABLE X INCOMPATABILITY ( 

## ,ilaterials to avoid)

. 

# N A HAZARDOUS DECOMPOSITION PRODUCTS 

# N/A
HAZARDOUS POLYMERIZATION MAY OCCUR CONOITIONS TO AVOID 

## NIIA WILL NOT OCCUR X



# SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED 

# Clean up bg recommended dustless methods water or vacuum .

DO NOT EXCEED TLV A.S SHOWN ABOVE.

WASTE DISPOSAL METHOD 

# Disposal sha11 be in accordance with federal, state and 1oca1 re ulations.

SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION S 2C7 Y t 2


# ~ IOSH/MSHA When TLV is excee ed; A approved respirators are required. VENTILATION LOCAL EXHAUST



# Sufficient to keep dust below TLV SPECIAL 

# None MECHANICAL 

### (Generclf OTHER 

# Bag tqpe dust collector recommended None PROTECTIVE GLOVES EYE PROTECTION 

# None re uired Recomrrtended OTHER PROTECTIVE EQUIPMENT 

# None required SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING 

# Use dustless s 

# stems for handlin 

# , stora e, and clean up 

# not to exceed TLV shown above. OTHER PRECAUTIONS 

# Practice good housekeeping and utilize ade uate ventilation and dust collection equipment. Use respirators when TLV is exceeded.
GPO 934-110 

## PAGE (2) Form OSHA-20 Rev. May 72 

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