~ - ~ -07 3 A=99=30 

sv1~OCC L%1 Roft9tra 00 

March 23, 1998 

Mr. Bill Neuffer 

Emission Standards Division (MD-13) 

U.S. Environmental Protection Agency 

Office of Air Quality Planning and Standards 

Research Triangle Park, NC 27711 

Dear Mr. Neuffer: 

Enclosed, is Endicott Clay Products Co.'s completed information request for brick and 

structural clay products manufacturing operations. As you can see, we have used 

Enclosure 2 as our preferred form. We have very little actual test data as we have always 

relied on published emission factors when completing the required environmental reports. 

The only stack test data we have is a stack test for hydrogen fluoride done by Barry Ellis 

of Clemson in 1994. The results of this test are included in the enclosed information 

request. If you have any questions about our response, please let me know. 

Sincerely, 

~.L..~Y ~ • 

Paul W. Judd 

V.P., Endicott Clay Products Co. 

Post Office Box 17 • Fairbury, Nebraska 68352 • 402/729/3315 

FAX 402/729-5804 / 
Enclosure ? 

N0T $JBJECT TO i:ic iE1i'RE1lENTS Op ~ S..TION 3577, PAPER'rIJRR TEDUCTIOd ACT, QP 1980. 

~ 

INF'ORMATION REQUEST FOR BRICK AND 

STRUCTUR.4L CLAY PRODUCTS MANUFACTURING OPERATIONS 

I. Instructions 

Please return the completed information request to: 

Bruce C. Jordan, Director 

Attn: Bill Neuffer 

Emission Standards Division (\ ~iD-13) 

U. S. Environmental Protection Agency 

Office of Air Quality Plannina and Standards 

Research Triangle Park, North Carolina 27711 

If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at 

(919) 541-5435. 

This information request should be completed for each facility that manufactures brick and 

structural clay products, including facilities that are not major sources. Information is 

requested for all processes at your plant that emit hazardous air pollutants (HAP's), 

including those processes that are not associated with brick and structural ciay 

products manufacturing. Sections II throuQh VII request information specific to brick 

and structural clay products manufacturing, and Section VIII requests information on 

emissions of HAP's from other processes located at the faciliry. Processes that may emit 

HAP's include those processes that use or handle any materials that contain a HAP 

compound. a11 processes with elevated temperatures, and all other processes in which HAP 

compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is 

included as Attachment 1 to this information request. Attachment 2 provides back?round 

information on the requirements of the Clean Air Act and explains how the information 

requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations 

and acronyms used in this information request. 

Several tables are provided throujhout the information request for your convenience in 

answering the questions. An example response is given (shaded first column or row) in 

each table. If additional space is needed to respond, please make copies of applicable 

pages. If necessary, please make copies of this information request for additional facilities. 

No additional emission testing or monitoring is required to respond to this request. 

U. General Facilitv Information 

A. Name of company Endicott Clay Products Co. 

Name of facility Endicott Clav Products Co. 

Pa~e 1 of 28 

~~ 
Facility address: 

No. and street 57120 707th Rd. 

City Fairbury State NE Zip 68352 

Latitude and longitude coordinates of plant: 040 04 35 / 097 07 35 

Standard Industrial Classification (SIC) Code(s) of brick and structural clay products 

manufacturing operations 3251 & 3253 

Dun and Bradstreet No. 007268535 

Total No. of employees for company 195 for facility 190 

(If facility is a foreign subsidiary or if company has foreign subsidiaries, include 

number of employees not based in the U.S.). 

Please complete the following shift information for the facility: 

Shift No. of employees Hours per shift Days per year 

1 157 9 280 

2 26 9 280 

3 7 9 280 

B. Respondentname Paul W. Judd 

Respondent title yice President 

Respondent address (if different from above) and telephone number: 

No. and street P• o. sox 17 

City Fairbury State NE Zip68352 

Telephone No. (4 729-3315 

Name and telephone number of technical contact person (if different from above) 

Name Same as above. Telephone No. (_) 

M. Information on Operating Permits and Applicable Federal Emission Standards 

A. Please provide copies of relevant parts of all operating permits and permit 

applications for your facility. Relevant parts include the sections that provide 

specific information and data on: processes that emit HAP's; the use of HAPcontaining substances; emission levels for HAP and surrogate pollutants (i.e., VOC 

Page 2 of 28 
for orcanic HAP's and PM for metal and other particulate HAP's); emission control 

device design and operation; monitoring and operation and maintenance (O&M) 

procedures for control devices; and generation and releases of other media such as 

wastewater and solid waste that are associated with the operation of air pollution 

controls for brick and structural clay products manufacturinc ,processes. 

Note : Pertinant pages of Endicott Clay Products Co. Title V Permit Application are include 

If the operating permit or application contains the same information requested 

in any part of this questionnaire, you may respond to the requested information 

by referencing the page or section of the permit/application to avoid 

duplication. If you reference your permit or application, you must supplement your 

response with all of the additional information requested in this questionnaire that is 

not included in the permit or permit application. If you prefer, you may submit the 

requested information from your permit/application on a 3- 1/z inch diskette. 

B. If any source or emission unit at this facility is subject to a New Source Performance 

Standard or other Federal emission standard, please identify the source and 

applicable standard. Examples of applicable NSPS include 40 CFR 60, 

Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing 

Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and 

Dryers in Mineral Industries. 

N/A 

IV. Brick and Structural Clav Products Production and Raw Material Consumption 

Information 

A. Please provide the 1996 production rates and the current production capacity for 

each type of brick and structural clay product manufactured (e.g., structural brick, 

clay sewer pipes, structural clay tile, etc.). Note that production data should be 

provided in units of tons per year (tons/yr). 

Product 1996 production (tons) Production capacity (tons/yr) 

Structural Brick 89,500 200,000 

1/2 " Floor & Wall Tile 10,718 50,000 

Glazed 1/2" Tile 320 13,797 

Page 3 of 28 

~ 
Title V Air Permit Application 

Endicott Clay Products Co. 

Fairbury, Nebraska 

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GEOTECHNlCAL AND GEOENV/RONMENTAL CONSULTANTS 

. . . PR,4CTICAL SOLUTIONS, SUPER/OR SERVICE 

S 

Prepared By: 

Gectechnical Sevi,es, 1nc. 

7050 South 'i 1 Oth Street 

Omaha, Nebraska 68128 

(402) 339-6104 

October 3, 1996 

GSI# 2301395 

Prepared Fer: 

trdicott Clay Products Co. 

P.O. Box 17 

Fairbury, Nebraska 68352 

Geotechnical 

Services Inca 
I A. ... 

I 

~ ST ATE OF NEBRASKA 

DEP ARTINIENT OF SP-1 

~ ENVIRON-INlENTAL QUALITY 

PERMIT APPLICATION 

~ 

Source Name 

City 

For Agency Use Only: 

Permit No. 

~ TO OPERATE AN AIR CONTAMINANT SOURCE 

(SPECIFIC PERMIT) 

~ Sources requirell to obtain a permit under Title 129, Chapter 5, must comP lete and return this 

forin. Applications are incomplete unless all applicable information requested herein is supplied. 

~ Failure to supply any additional information requested by the Department of Environmental 

Quality to enable it to act on the application may result in denial of this application. EncIosed 

forms may be copied as needed. 

~ 

SECTIOr A- GEi`1ERAL APPLICATION Ii`tFOR:vIATIOv 

~ Completion of this section is mandatory for all applicants, althou.zh certain fields may not apply 

to all sources. 

~ Tvpe of permit for tivhich application is being made: (Complete this section last.) 

Initial X Class I- Major Source X 

~ Renewal Class II - Minor Source 

Standard Industrial Classification Codes (SIC) 

List the three Standard Industrial Classification codes (if three apply) that best describe the 

processes or products associated with the source. List the corresponding descriptions. Use the 

S tandard Industrial Classification Manual, 1987, available through National Technical 

Information Service, 5285 Port Royal Road, Sprinofield, Virainia 22161. 

Description 

Primarv SIC 3251 Brick and structural clav tile 

Secondary SIC 3253 Ceramic wall and floor tile 

Tertiary SIC 

**' THIS APPL[C,3TION CANNOT BE USED BY ACID RAIN SOURCES *** 

01- 
Source Name & Location 

Firm Name Endicott Clay Products Co. 

Street Address 57120 707th Rd. 

City Fairbuy 

State Nebraska ZIP 68352 County Jefferson 

Contact: (Last) Judd (First) Paul (~II) W. 

Title: Vice President 

Telephone (402) 729-3315 Ext. Fa.Y (402) 729-5804 

` Plant Owner 

Name Endicott Clav Products Co. 

iVlsil Address P.O. BoY 17 

City Fairbury 

State Nebraska ZIP 68352 Telephone (402) 729 ~315 E:ct. 

Plant Manager (if different from o'wner) 

Name Dean Cemv 

V1ai1 Address P.O. Box 17 

City Fairbury 

State Nebraska ZIP 68352 Telephone (402) 729 -3313 Est. 

Property Owner (if different from plant owner) 

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ZIP Telephone E.ct. 

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For Renewals Only 

Current Operatin ~ Permit Number 

Expiration Date of Cunent Operating Permit 

Responsible Official 

Name (Last) Judd 

Title V ice President 

Address P.O. Box 17 

StateNebraska ZIP68352 

Fax(402)729-5804 

(First) Paul (MI)W. 

City Fairbury 

Telephone (402) 729-; 315 EYt. 

Certification of Truth, Accuracy and Completeness 

iNote: This certitication must be siped by a responsible official (see Title 129, Chapter 1, 

Section 093). 

Applications without a signed certification will be retumed as incomplete. 

I certify under penalty of law that, based on information and belief formed after 

reasonable inquiry, the statements and information contained in this application 

are true, accurate and complete. All production records shall be made available 

to the staff of the Department of Environmental Quality as shall access to any 

facilitv or control device. 

Name (typed) Paul W Judd 

(S iQned) Date: /Q121#/f 4 

Title Vice President 

3 

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~1 

I 

SECTION B- DESCRIPTION OF SOURCE, EQUIPMENT AiND PROCESSES 

~ 

~ A facilitv consists of one or more sets of emission units that have the same type of operation and 

emission controls. A source consists of one or more contiguous or adjacent facilities which are 

owned or operated bv the same entity. Property may be split by rail or by city, county or state 

~ road. Property does not always have to be adjoining to be considered adjacent. The key factor is 

the interdependence betvveen two adjacent facilities. If one facility cannot exist without another, 

~ and tlhev are tocated near each other, they belong to the same source. 

Provide an S 1/2" 1 11" plan (overhead) drawing of the complete source. Label each emission 

~ unit and include a north arrow. Indicate all streets, railroad tracks or other objects of division_ 

Use a red pen ar pencil to designate the source boundary. If there is any question of multiple 

facilities belonainQ to the same source, include a map detailed as described above, shoizzng all 

~ facilities and indicating the names of land ownership or lease. 

~ Complete the enclosed set of forms as they apply to your operation. Supply all information 

requested. Put "NA" where information is requested that is not applicable to your operation. If 

~ the complete form is not applicable, put "NA" at the top of the page. Copy the forms as needed 

or supply your own 8 1/2" Y 11" similarly formatted forms. 

~ List all emission control devices and their efficiencies in the spaces provided. If necessary, use 

additional pages. The following efficiencies for common control devices are recognized bv 

NDEQ. If higher efficiencies are proposed, include acceptable documentation of the eiiciencies 

~ such as stack test results. If a control device is not listed, contact the Air Division of i`iDEQ. If 

these control efficiencies are used as part of a Federally enforceable condition, future verification 

~ i1iav be reRuired. 

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M ; 
No. CONTROL DEVICE 

CONTROL EFFICIENCY % 

TSP/LEAD Pvllo NO, 

001 ' Wet Scrubber - Hi;h Effciency 95 90 93 

*008 Centrif''ugal Collector Medium Efficiency 80 60 -- 

010 Electrostatic Precipitator - High Efficiency 95 93 -- 

016 I Fabric Filter - Hiah Temp 98 95 -- 

*018 I Fabric Filter - Low Temp ' 98 95 -- 

0?5 f Staued Combustion -- 50 

ie056 Enclosed Grindin` and Screenina Areas -- 90 

*061 Dust Suppression by Water Sprays (Stock 

Pile) 

80 80 

*061 Dust Suppression by Water Sprays (Road) 50 50 -- 

L: 062 Dust Suppression by Chemical Stabilizers 

or Wettinv Agents 

50 

7 

-- 

* Applicable Controls 

/~ 
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~ 

In each location where a yearly rate is requested (fuel, process rate, products, etc ... ), enter the 

~ normal rate; then a slash; then the maximum potential yearly rate (i.e. 4000/8000 tons). If the 

hourly rate is given for a process, the maximum yearly rate is 8760 times the hourly rate. 

(Hourly rate implies maximum hourly rate.) If the hourly rate is not available, the maximum 

~ yearly rate is obtained by dividing 8760 by the number of hours in a normal workino year and 

multiplying the quotient times the normal yearly rate. Include a worksheet showing all 

calculations. 

If there is a reason to believe that the maximum yearly rate of a process is less than that obtained 

~ by either of the above methods, fully e:cplain the situation. 

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a Normal Operating Schedule24 / 24Hrs/Day 7/ 7 Days/Week52 / 52Weeks/Year 

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STATE OF NEBRASKA 

DEP.aRTNIENT OF ENVIRONMENTAL QUALITY OPERATING PERMIT APPLICATION 

~ 

FUEL COMBUSTION DATA 

~

FUEL BURNTNG UNIT DATA FUEL DATA 

UNIT CAPACITY TYPE UNIT* TYPE AiNvfOU1VT AMOUNT HRS 

(.D. NO. BTU/HR OR FUEL(S) HOUR** YEAR** USED 

~ HP BURNED YEAR 

42 Fuel Oil 6.3 aal. 625 ! 59,239 gal. 92 / 8760 

24-1 372 hp Reciprocating 

~ 

R2 Fuel Oil 1? szal 0/ 600 gal. 01500 

39-1 68 hp Reciprocatin; 

~ 

Fuel Oii 3? 2al. 0/ 1,691 gal. 01500 

~

#2 

30-1 175 - Reciprocatina, 

~ 

~ *Boiler, Turbine, Reciprocating, Diesel, Large Bore Diesel (Duel Fuel) 

**Indicate Fuel Units 

~ Unit I.D. No. 24-1 29-1 30-1 

lnstallation Date: 1960 1996 1975 

~ IF B I L R BURNS FUEL (~TI , LIST UNIT ;`fUMBERS WHICH ARE: 

HORIZONTALLY FIRED i`lA TANGENTIALLY FIRED 

~ IF COAL IS BURNED, IDENTIFY UNITNUVIBER(S) A2VD TYPE OF FURNACE: NA 

AIR POLLUTION 

STACK DATA CONTROL EOUTPMENT 

,.00ESS HEIGHT TOP INSIDE EXIT VELOCITY EXIT TEMP T`!PE OF EFFIC- DATE 

iNUNIBER DIANIETER OF GAS OF GAS EQUTPMENT rENCY INSTALLED 

24-! 13 ft 0.5 ft 190 ft/sec 840 °F 

29-1 12 ft 0.25 ft. 119 ft/sec 1270 °F 

30-1 7 ft 0.3 -z4 4 ft 621 fUsec 950 °F 

ft ft ft/sec °F 

~ COAL DATA FUEL OIL DATA 

%'°ASH ",S,SULFUR HEAT CONTENT SOURCE GRADE °'°SULFUR HEAT CONTENT SOURCE 

~ 4!2 0.03 

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142,800 BTU/gai Amoco 

9 /z 
E 

~ STATE OF NEBRASKA 

DEPARTiyIENT OF ENVIRONMENTAL QUALITY OPERATING PERMIT APPLICATION 

~ PROCESS INFORMATION 

Briefly describe all processes undertaken at your facility. Include ra%v materials, manufacturing procedures and 

~ finished products. Include complete flow diagams on 8 1/2" x 11" sheets. 

Endicott Clav Products Co. is a manufacturer of brick and clav tile. The material is mined at the site and stored in a 

stora}e oile. The storrage pile is wetted to to control dust. The material is broken up in a, inder, molded and heated 

~ in kilns. The plant has 3 tunnel kilns and 9 periodic kilns. Aalazine line with a kiln will be used on a percenta;e of 

the brick or tile that does not meet Endicott's standards of qualitv. Gro; is nroduct that can not be repaired and is 

around to be reused as raw material. 

~ - 

MATERIAL PROCESSED , FINAL PRODUCT 

PROCESS TYPE OF AMOUNT AMOUNT PRODUCT Aiti10UNT 

NUMBER MATERIAL (LBS/HR) (TON/YEAR) DESCRIPTION (TON/YR) 

~ I - i thru 30-1 Clay 26,173 / 45,662 1 14,636 / 200,000 Brick & Tile 114,636 / 

200,000 

~ 

~ 

~ IN PROCESS FUEL DATA 

PROCESS PROCESS EQUIPIvtENT USED TYPE FUEL AIvIOUNT* AMOUNT* 

N U M B E R BURNED HOUR YEAR 

~ 10- l Plant 2: Kiln 1 Natural gaas 12.5 / 21.95 109,500/192,282 

M cu ft M cu ft 

14.5 / 21.95 127,020/ 192,282 

1 1-1 Plant 2: Kiln 2 Natural -as Mcuft ytcuft 

Natural cyas 12.9/22.3 113,386/217,648 

12-1 Plant 3: Kiln 1 ° Mcuft Mcuft 

0/ 6.25 0/ 54,750 

~ 15-1 Plant l: Kiln I Natural oas = Mcuft N'tcuft 

Enter boiler data on Fuel Combustion Data Sheet *Indicate fuel units 

~ AIR POLLUTION 

STACK DATA rONTROL EOUiPMENT 

HEIGHT TOP INSIDE EXIT VELOCITY EXIT TEivIP TYPE OF EFFIC- DATE 

~

PROCESS 

NUMBER DIAMETER OF GAS OF GAS EQUIPMENT IENCY INSTALLED 

10-1 40 ft 3 ft 50 ft/sec 320 °F NA 

~ 1 1-1 40 ft 3 ft 50 ft/sec 350 °F NA 

12- l 40 ft 3 ft 50 ft/sec 400 °F NA 

~ I5-1 30 ft 2.6 ft Nat. draft ft/sec 400 °F NA 

0 13 
E 

~ STATE OF NEBRASKA 

DEPARTMENT OF ENVIRONMENTAL QUALITY OPERATING PERMIT APPLICATION 

~ PROCESS INFORMATION . 

Brieffly describe all processes undertaken at your facility. Include raw materials, manufacturina procedures and 

finished products. Include complete flow diagrams on 8 1/2" x 11" sheets. 

' ~End' Clav Products Co is a manufacturer of brick and clav tile The material is mined at the site and stored 'n a 

storage pile The storage ~ ile is wetted to to conirol dust The material is broken up in a, inder molded a_nd heated 

~ in kilns The plant has 3 tunnel kilns and 9periodic kilns A;lazinq line wiLh a kiln will be used on apercentaie of 

the brick or tile that does not meet Endicott's standards of qualitv. Gro; is product that can not be repaired and is 

around to be retised as raw material. 

~ 

MATERIAL PROCESSED , FNAL PRODUCT 

PROCESS _ TYPE OF AMOUNT AMOUNT PRODUCT AMOUNT 

NUiv1BER ivIATERIAL (LBS/HR) (TONiYEAR) DESCRIPTION (TON/YR) 

~ I- I tliru 3,0- I Clay 26,173 / 45.622 114,636 / 200,000 Brick & Ti1e 114.636 i 

200,000 

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PROCESS PROCESS EQUIPMENT USED TYPE FL~L 

TN PROCESS FUEL DATA 

AMOUNT* AiviOUNT* 

NUIvI BER BUR~~IED HOUR YEAR 

~ 

0/ 6.25 0/ 54,750 16-1 Plant l: Kiln 2 Natural aas Mcuft Mcuft 

0 / 6.25 0 / 54,750 

17- f Plant 1: Kiln 4 Natural gas M cu ft 'Vf cu ft 

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0/ 12.5 01109,500 

13- 1 i 13-2 Plant 1: Kiln 5& 6 Natural gas Mcuft Mcuft 

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0/ 6.25 19-1 Plant 1: Kiln 7 Naturai gas Mc uft 0![ ~ ft 

Enter boiler data on Fuel Combustion Data Sheet *Indicate fuel units 

~ 

STACK DATA 

AIR POLLUTION 

CONTROL EOUIPMENT 

~ PROCESS HEIGHT TOP INSIDE EXIT VELOCITY EXIT TEMP TYPE OF EFFIC- DATE 

NUIv1BER DIAMETER OF GAS OF GAS EQUIPIvLENT fENCY INSTALLED 

16-1 30 ft 2.6 ft Nat, draft ft/sec 400 °F NA 

~ 17-1 30 ft 2.6 ft Nat. draft ft/sec 400 °F NA 

18-1 / 18-2 30 ft 4 ft Nat. draft fI/sec 400 °F NA 

~ 19-1 30 ft 2.2 ft Nat. draft ft/sec 400 °F NA 

9 

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Elm 

~ STATE OF NEBRASKA 

DEPARTViENT OF ENVIRONMENTAL QUALITY OPERATING PERNIIT APPLICATION 

~ PROCESS INFORMATIOIY 

Briefly describe all processes undertaken at your facility. Include raw materials, manufacturing procedures and 

~ finished products. Include complete flow diagrams on 8 1/2" x 11" sheets. 

Fndicott Clav_ P_roducts Co. is a manu acturer of brick and clav tile. The material is mined at the site and stored in a 

~ 

gora ge oile. The stora;e oile is wetted to to control dust. The 

in kilns. The Rlant has 3 tunnel kilns and 9 periodic kilns. Aag laziny 

material is broken up in agrinder. molded and heated 

line with a kiln will be used on agercentaoe of 

the brick or tile that does not meet Endicott's standards of qualitv. Groa is product that can not be repaired and is 

}round to be reused as raw material. 

~ 7 

~ ' MATERIAL PROCESSED • FNAL PRODUCT 

PROCESS TYPE OF AMOUNT AMOUNT PRODUCT Ai'vfOUNT 

NUIvIBER MATERIAL (LBS/HR) (TON/YEAR) DESCRIPTION (TON/YR) 

~ 1- I thru 30-1 Clay 26,173 / 45,662 114,636 / 200,000 Brick & Tile 114,6361 

200,000 

~ 

~ 

~ IN PROCESS FUEL DATA 

PROCESS PROCESS EQUIPMENT USED TYPE FUEL AMOUNT* AMOUNT* 

N U Ni B ER BURNED HOUR YEAR 

~ 

0/ 6Z5 

20-1 Plant l: Kiln 8 Natural -as Mcuft O M cu ft 

0/ 6.25 0/ 54,750 

21-1 Plant 1: Kiln 9 Natural -as ~ ~ iyI cu ft ~t cu ft 

0/ 6.25 0/ 54,750 

2~ -1 Plant 1: Kiln 10 

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Natural aas Mcuft Mcuft 

~ 27-1 Roller kiln on glaze line Natural gas 0/ 4.59 M cu ft 0/40,103 ivl cu ft 

Enter boiler data on Fuei Combustion Data Sheet *Indicate fuei units 

~ AIR POLLUTION 

STACK DATA CONTROL EOUIPMENT 

~ PROCESS HEIGHT TOP INSIDE EXIT VELOCITY EXIT TEMP TYPE OF EFFIC- DATE 

NUiMBER DIAMETER OF GAS OF GAS EQUIPMENT IENCY INSTALLED 

20-1 30 ft 2.2 ft Nat. draft ft/sec 400 °F NA 

~ 21- l 30 ft 2.6 ft Nat. draft ft/sec 400 °F NA 

22-1 30 ft 3.6 ft Nat. draft ft/sec 400 °F NA 

~ 27-1 35 ft 2.3 ft 94 Wsec 450 °F NA 

10 

~ ~~ 
~ STATE OF NEBRASKA 

DEPARTMENT OF ENVIRONMENTAL QUALITY OPERATING PERMIT APPLICATION 

~ PROCESS INFORtrIATION 

Brietly describe all processes undertaken at your facility. Include raw materials, manufacturing procedures and 

~ finished products. Include complete flow diagrams on 8 1/2" x 11" sheets. 

Fndicott Clav Prodticts Co is a manufacturer of brick and clav tile The material is mined at the site and stored in a 

$ ora t ge oile The stora ~e nile is wetted to to control dust The material is broken up in a Srinder, molded and heated 

~ in kilns. The plant has 3 tunnel kilns and 9 periodic kilns. A glazing line with a kiln wiil be used on aer vi centa.}e of 

the brick or tile that does not meet Endicott's standards of q,ualiry, GrQg is product that can not be reoaired and is 

around to be reused as raw material. 

~ 

~ MATERIAL PROCESSED . FNAL PRODUCT 

PROCESS - TYPE OF AMOUNT Av10UNT PRODUCT AlvIOUNT 

NUiVIBER NIATERIAL (LBS/HR) (TON/YEAR) DESCRIPTION (TON/YR) 

~ l - I thru 30-1 Clay 26,173 / 45,662 114,636 / 200,000 Brick & Tile 1 14,636 / 

200,000 

~ 

~ PROCESS 

NUMBER 

~ 2s-1 

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IN PROCESS FUEL DATA 

PROCESS EQUIPMENT USED TYPE FUEL AMOUNT* AMOUNT* 

BUILNED HOUR YEAR 

Shrink oven Natural -as 90 / 400 cu ft 788 /' '045 

Mcuft 

Enter boiler data on Fuel Combustion Data Sheet *Indicate fuel units 

~ PROCESS 

NUfvtBER 

AIR POLLUTION 

STACK DATA CONTROL EOUiPMENT 

HEIGHT TOP INSIDE EXIT VELOCITY EXIT TEMP TYPE OF EFFIC- DATE 

DIAMETER OF GAS OF GAS EQUIPMELNT IENCY INSTALLED 

20 ft 0.5 ft 18.67 ft/sec 400 °F NA 

ft ft ft/sec °F 

ft ft ftlsec °F 

ft ft ft/sec °F 

11 

/ ~2 
~ 

a 

SECTION C- Eiv1ISSION POINT INFORIYIATION 

~ List each Source Classification Code (SCC) which corresponds to each emission's segment. 

SCC's may be found in AIRS Facility Subsvstem Source Classification Codes and Emission 

~ Factor Listina for Criteria Air Pollutant. 1990, available through National Technical Information 

Service, 5285 Port Royal Road, Springfield, Virginia 22161. 

~ List each emissions point. This refers to a specific piece of equipment or process that emits a 

regulated pollutant. List each emissions segment. This is the description which corresponds to 

the SCC number previously mentioned. 

~ Number each emissions oint, startin P ~ ~ with "1 ". Then, ut a dash and a number corre ondin P sP g 

~ to the emissions segment. , 

Esample: A 50 MiVIBtu/hr steam boiler runs on 9,2 oil or natural gas. The two SCC numbers 

~ are 102) 00501 for "Grades 1 and 2 oil" and 10200602 for "10-100 MMBtu/hr" (under the 

category "Natural Gas"). You can use the descriptions out of the manual or simplify them. The 

Emissions Point/Seament number for the boiler buming oil is 1-1. The number for buming a gas 

~ is 1-2. The neYt emissions point would 'oe 2 and its first segrnent would be 2-1. List all alternate 

operatina sc,--narios. Esample: This might include the use of propane fuel for a boiler that 

normallv burns natural cras. Make sure all emission points are listed, even if the operation is 

~ seldom used. V 

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SECTION D- INL4XIUVIUM POTENTIAL AIR EiYIISSIONS 

~ Using the information regarding maximum process rates in Section B, calculate maxi.mum 

potential yearly emission rates for all emission points listed in Section C. List point/segment 

~ numbers and SCC numbers as in Section C. Enter process rates, in the same manner that "Units" 

are listed in the AIRS manual. 

~ Esample: For 92 oil burning boiler, the process rate in AIRS is in "1000 gallons bu.med." If the 

boiler would bum 70,000 gallons of #2 oil per year at maximum capacity, enter 70 in "Process 

~ Rate." Compute emission rates without the use of control efficiencies, even if controls are used. 

Emission rates are calculated for TSP (PART), PM 10 , SO,,, NOc, VOC, CO, and LEA.D by taking 

the process rate times the "lbs/unit" rate given in the AIRS manual for each pollutant. If the 

~ emission factor in AIRS is denoted by a dash, that means a factor has not been established in this 

system. The factor will have to be determined by other means such as AP42, mass balance, or 

stack test. Note the method of determining the emission factor if other than AIRS. Total each 

~ pollutant for the entire source. Complete the Volatile Organic Compounds sheet and the Air 

Toxics Information sheet based upon maximum process rates. Do not list emissions on the VOC 

~ sheet if they have already been listed on the emission point sheet. 

NOTE: Emissions may be calculated by other methods as noted in Title 129, Chapters 5 and 6. 

~ If other methods are used, include all test data and calculations. 

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STATE OF NEBRASKA 

DEPARTMENT OF ENVIRONMENTAL QUALITY 

OPERATING PERiVIIT APPLICATION 

AIR TOXICS INFOR ~tiIATIOY 

List any chemicals manufactured or used which appear on the enclosed list of 189 air to:cics covered by 

the Clean Air Amendment. 

Air Toxic 

Ch em i ca 1 

Ca,s No. Process 

Description 

Total Used 

(Ibs/Yr) 

Total Emitted 

(lbs/Yr) 

Hydrogen Fluoride 7664393 Plant 1: Kiln 1 NA 1410 

Hydrosen Fluoride 7664393 Plant 1: Kiln 2 NA 1410 

Hydrogen Fiuoride 1 664393 Plant 1: Kiln 4 NA 1410 

Hydrogen Fluoride 7664393 Plant,l: Kiln 5 NA 1410 

Hvdrogen Fluoride - 7664393 Plant I: KiIn 6 NA 1410 

Hydrouen Fluoi- ide 7664393 Plant l: Kiln 7 NA 1410 

Hydrogen Fluoride 7664393 Plant 1: Kiln 8 NA 1410 

Hydrogen Fluoride 7664393 Plant 1: Kiln 9 NA 14I0 

Hydrogen Fluoride I 7664393 Plant 1: Kiln 10 NA 1410 

Hydro ~en Fluoride 7664393 Plant 2: Kiln 1 NA 36,396 

Hvdrogen Fluoride 7664393 Plant 2: Kiln 2 NA . 36,396 

Hvdrosen Fluoride, I 7664393 Plant 3: Kiln 1 NA 37,055 

I 

TOTAL NA 122,537 

CONIN(ENTS: Emission factor from Factor Information Retrevial System 0.47 11b/ton 

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SECTION E- ACTUAL AIR EMISSIONS 

Using the informattion regarding actual process rates in Section B, calculate the actual emissions 

(for a normal operating year). Follow the procedure outlined in Section D; however, this time 

use control efficiencies of actual controls (in proper operating condition). Enter control number 

and etficiency, taken from Section B. If evidence was provided in Section B of a hijher 

efficiency, list that efficiency. Total the yearly emission rates of all regulated pollutants. 

Complete the VOC and Air To:cics sheets making note of any control devices that would liniit 

emissions. Total the VOC's and air to:tics. 

See Note in Section D. 

30 

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STATE OF NEBRASKA 

~ DEPARTMENT OF ENVIRONiVIENTAL QUALITY 

OPERATING PER1vlIT APPLICATION 

AIR TOXICS INFORitiIATION 

~ 

List any chemicals manufactured or used which appear on the enclosed list of 189 air toxics covered by 

~ the Clean Air Anendment. 

Air Toxic 

Chem ical 

( Cas No. Process Total Used Total Emitted 

Description (lbs/Yr) (lbs/Yr) 

~ Hydrogen Fluoride 7664393 Plant 1: Kiln I NA 0.0 

Fiuoride 7664393 Plant l: Kiln 2 NA 0.0 

~

Hydrogen 

~ Hvdrouen Fluoride :664393 Plant 1: Kiln 4 NA I 0.0 

~ 

Hydrosen Fluoride I 7664393 Plant• 1: Kiln 5 NA 0.0 I 

Hydi-o~;en F?uoride ~ 7664393 Plant 1: Kiln 6 NA 0.0 

Hydro.g.en Fluoride 7664393 I Plant l: Kiln 7 I NA 0.0 

i 

Hvdrogen Fluoride 7664393 Plant l: Kiln 8 NA 0.0 I 

Hydrogen Fluoride I 7664393 Plant l: Kiln 9 NA ( 0.0 

~ Hydro ~en Fluoride 7664393 Plant 1: Kiln 10 NA ---T 0.0 

Hydrogen Fluoride 7664393 Plant 2: KiIn i NA 7,517.76 

~ Hydrogen Fiuoride 7664393 Plant 2: KiIn 2 NA 8,541.12 

~ 

Hydrogen Fluoride 

I 

I 

~ 

7664393 Plant 3: Kiln 1 NA 10,872.56 I 

~ , 

~ 

I 

~ TOTAL 26,931.44 

COMMENTS: Emission factor from Stack Testing 0.234931b/ton 

~ 

35 

~ ~O 

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i 
~ 

~ 

APPENDIX 1 - PLAN DRAWING 

~ 

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_ qpPENDIX 2 - FLOW DIAGRAM 

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co 

R (.O Cfl CD CO CO CO CO (O CO CO (D CD LL 

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Endicott Clay Products Co. 

1) PM CALCULATIONS FOR THE GLAZING OPERATION 

b= Total potential tons of brick produced per year 

b - 13797 tons 

Emission factors from the SCC 3-05-020-03 in pounds per ton 

P;V1ef = Emission factor for PM 

6.0 

pePM = The potential to emit PM in pounds per year uncontrolled 

paPiVt .= b•PMef 

pel'k-I = 327S2 Ib/yr 

ptePM = The potential to emit in PM tons per year uncontrolled 

ptcP ~ 1 ., pePM • 

2000 

ptC:'R1 = •t 1.39 tons/yr 

2) CONTROL EQUIPMENT CALCULATiONS 

The exhaust volume of the glazing line deduster will be less than or equal to 4.95 oz/hr 

Exhaust = 4.95 ozJhr (Manufacturers guarantee) 

eye = The maximum potential pounds of panticulate released per year controlled 

~ 4.95 

"` !6 3760 

c%• =371U.125 Iblyr 

ety = The maximum potentiai tons of particulate released per year controlled 

CY 

etv 

ety = 1.36 tons/yr 

The control ef5ciency for the dedusting unit for PM is calculated at 96.7% 

PM = The potential tons to emit utilizing the control equipment 

IUU - (96. 7) 

PI~I = pteP!~t I IUU 

P4t = 1.37 tons/yr (controlled) 

Calculated control efficiency 

cePM = Control efficiency for PM 

cuP:Vt = I lUU - 

` / 

( p~ePM• 10U1 

cel'~t =916.7 % 

ci~~ 
~ -- - 

~ 

j 3) PM10 CALCULATIONS FOR THE GLAZING OPERATION 

b= Total potential tons of brick produced per year 

h - 13797 tons 

i . 

Emission factors from the SCC 3-05-020-03 in pounds per ton 

PM 10ef = Emission factor for PM10 

PVIIUet•:= 3.1 

~. 

~ pePM10 = The potential to emit PM10 in pounds per year uncontrolled 

pePiV110 := b•PM1UeP 

pe PINI l U= 42771 Ib/yr 

ptePM10 = The potential to emit in PM tons per year uncontrolled 

prPM IU 

1U = 2000 

. 

pteP.!',•110 =21.39 tons/yr 

4) CONTc:OL EQUIPN1ENT CALCULATIONS 

The exhaust volume of the glazing line deduster will be less than or equal to 4.95 oz/hr 

Exhaust = 4.95 oz/hr (Manufscturers guarantee) 

ey = The maximum potential pounds of particulate released per year controlled 

4.95 

Cy = 271 U Ib\yr 

ety = The maximum potential tons of particulate released per year controlled 

CY 

1 000 

.~ 

etv = 1.36 tons/yr 

The control efFiciency for the dedusting unit for PM10 is calculated at 93.7% 

~ PM10 = The potential tons to emit utilizing the control equipment 

( 100 - (93.7) 1 

~ 

P~ fIU = ptePMlU•Il lUU 1 

PM 10 = 1.35 tons/yr (controlled) 

~ Calculated control efficiency 

cePM10 = Control efficiency for PM10 

~ cci'M IU = (UU - eCy .I0U1 I [ (ptePM10 J ~ 

~ ccPMIU =93.7 % 

~ 
~ 

~ 

~ 

~ 

i THE EMERGENCY GENERATOR FOR GLAZE LINE 

The emergency generator will have the potential to operate a maximum of 500 hours. That generator 

will be utilized is a 30 KVA generator. The generator required to supply this power will be 68 hp. 

hp=68 

Btuhr = hp2545 

Btu hr-1.731x10E5 

Total Btu = Btu x 500 

Total Btu = 8.655x10E5 

Total fuel = Total Btu / 140000 

Total Fuel = 618 gallons of distillate fuel 
I 

1~ 

!~ 

I THE EMERGENCY GENERATOR FOR PLANT 2 KILNS 

I 

The emergency genes•ator will have the potential to operate a maximum of 500 hours. The generator ti ~ at 

wiit be ut ilized is a 75 KVA generator. The generator required to supply this power will be 175 hp. 

i 

hh 175 

; litultr hp•3545 

~ 

IaL1111 = d- In' Btu/hr 

•I-utullitu = f3Lul,r•500 

Tcitxll3tu =2-237•1U'` Total Btu 

Tcua I f3 tu 

I ~~ talCuel - I ;rlpU(l 

"I'ciiall'ucl = i-5;1 gallons of distillate fuel 

~ 

~ 

A 

~ - 

.. . • .-- . .. • • - ~' : 

- - . - - • - - " ::;;;= - _ - - - 

. .-. . ._ ~'~= : _ . - - _ . .. .. . _- " . 

. . •• -. : - ~-~°.. • • . .. 

.; . 

, 

~ 

_ y5 
THE GENERATOR FOR OPERATING GROG MACHINE 

The emergency generator will have the potential to operate a maximum of 8760 hours. The generator that 

will be utilized is a 75 KVA generator. The generator required to supply this power will be 372 hp. 

hp - :72 

Btuhr = hp•2545 

13tuhr = 9- lU' Btu/hr 

l'otall3tu := 13tuhr•8760 

'rotall3cu =9.293-10 9 Total Btu 

rotalBtu 

r~~ 4,I1tiCt := la0000 

- 

I'utaltuel =59239 gallons of distillate fuel 

~ ~E 
B. Please provide the type and amount of each raw material and body additive used in 

1996 for manufacturing brick and structural clay products at your facility. Examples 

include clays, shale, and any additives that are mixed into the raw material prior to 

forming. Indicate additives by chemical compound, rather than by trade name. If the 

information requested is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than providing the information 

below. 

Raw materiaf/body additive Amount used in 1996 (tons/yr) 

Kaolinite Clay 86,798 

Crushed Brick (Grog) 13,035 

Additive A 700 

Brickox 131 

Barium Carbonate 87 

Chromox 167 

C. If available, please provide a copy of the MSDS's for the raw materials and additives 

listed above. 

MSDS Sheets Included. 

D. If available, please provide chemical analyses, including fluorine, metals, and organic 

conten[, of the raw materials listed above. 

Not Available. 

Page 4 of 28 

q-1 
MATERIAL SAFETY DATA SHEET ADDITIVE A TYPE 1 LICUID• PAGE 1 OF 2 

lYYYYYYY*YYYYYYYYYYYYYYYYYYY1rYYYYY*YYYYY*YYYY*Y*YY*Y'YYY*YYYYYYY ~YY}*YYyYYY*YY* YYYM*Y*YYYYYYYY*!~lYY*Y**}Y* 

,IGNOTECH USA, INC. EMERGENCY PHONE (715)359-6544 MSDS N0. . 301100R 

Research A Development *CHEMTREC PHONE (800)424-9300 ORDER NO. . 

100 Highway 51 South DATE PREPARED: 06-MAY-1994 

Rothschild, 4I 54474-1198 *USE ONLY IN THE EVENT OF CHEMICAL EMERGENCIES REPLACES . ALL Previous 

TEL: (715)359-6544 INVOLVING A SPILL, LEAK, FIRE, EXPOSURE, OR PREPARED BY : G. Rasmussen 

FAX: (715)355-3648 ACCIDENT INVOLVING CHEMICALS. »> NOT OSHA OR NHMIS HAZARDCUS «< 

******************************************* I. PRODUCT IDENTIFICATION 

COMMON•,NAME : Calcium Lignosulfonate CHEMICAL FORMILA Amorpheus Polymer 

SYNONYMS : See Above CHEMICAL FAMILY . Vood Chemicals 

MANUFACTURER . LignoTech USA, Inc. CAS NUNBER(s) . 66071-92-9 

SHIPPING NAME - DOT : Lignin Liquor - Ctass 55. , 

HAZARD CLASS - DOT : Not Restricted UN NUMBER . Excluded 

HAZARD CLASS - IATA : Not Restricted PHYSICAL STATE . Liauid 

HMIS RATING (SCALE 0-4) : HEALTH s 0 FIRE a 0 REACTIVITY s 0 SPECIAL = 

*YYYiFttY YYYYYYYYYYYYYY41MYttY#YYYYY*#11! II. HAZARDOUS IIIGREDIEIITS ******Y*YYf*YYYYYY*YYYYYIIYYltY*#YYY**Y*Y!**YY**#Y*YY*!*#Yy** 

PRINCIPAL HAZJIRDOUS COMPQNENTS PERCENT THRESHOLD LIMIT VALUE'(UNITS) 

Barium 1.24 1.0 (Sara 313 List) 

III. PHYSICAL DATA **Y***************'*****Y**YY****** 

BOILING POINT (C) : 104 C SPECIFIC GRAVITY (25 C) : 1.2590 

FREEZING POINT (C) .-2 C pH (3X Sotn) : 3.0 

VAPOR PRESSURE (mn Hg) : 14.2 a 20 C BULK DENSITY (g/ml) : Not Applicable 

VAPOR DENSITY (Air 9 1) : 1.21 e1 20 C SOLUBILITY IN YATER : 100% SolubLe 

X VOLATILES BY WEIGHT : 50 (water) EVAPORATION RATE : Nonmal 0.4 (water) 

.PPEARANCE AND ODOR . Brawn liouid with slight odor. YATER/OIL DIST.COEFF. . 100% in water 

rYYYYYY'YYYYYY'RYYYYY IV. HEALTH HAZARD DATA  YYYYYYYY+YY7'YYYYYYYYYYYYYYYYYYMY** YYYYYYYYYYYYYYYYYYYY 

THRESHOLD LIMIT VALUES : OSHA PELV = None Established ACGIH TLV = None Established 

CARCINOGEN LISTINGS - NTP / IARC : 

PRIMARY ROUTE(s) OF ENTRY . 

SYMPTCMS OF OVEREXPOSURE 

CONDITIONS AGGRAVATED BY EXPOSURE: 

IRRITANCY OF MATERIAL . 

SENSITIZATION TO MATERIAL . 

TERATOG'cNICITY . 

MUTAGEMICITY . 

REPRODUCTIVE TOXICITY . 

SYNERGISTIC SUBSTANCES . 

Minimize contact with eyes, skin, clothing. Ncn-toxic with an L.D50 = 5 g/kg for rats 

Not a carcinogen 

Skin contact, eye contact 

No effects of overexposure to lignasulfonates are known. 

None known. 

None known. 

None known. 

None known. 

None known. 

None known. 

None known. 

FIRST AID -- EYES : Irrigate with potable water. 

SKIN : Skin should be flushed with clean water. 

INHAL.ATION : Not Applicable - aqueous sotution. 

INGESTION . Give water to dilute and get medical attention. 

NOTES TO PHYSICIAN : Very low toxicity. 

V. FIRE AND EXPLOSION HAZARD OATA ********* ****************** 

FLASH POINT (Method Used) : Not Applicabte AUTO IGNITION TEMP: Mot Appticable 

FLAMMABLE LIMITS IN AIR, X BY VOL. : L04ER: Not Applicable UPPER: Not Applicable 

EXTINGiJiSHING MEDIA : None. 

SPECIAL FIRE FIGHTING PROCEDURES : None. 

UNUSUAL FIRE AND EXPLOSION HAZARDS : None. 

Vill" 
MATERIAL SAFETY DATA SHEET ADDITIVE A TYPE 1 LIGUID PAGE 2 OF 2 

** VI. SPILL OR LEAK PROCEDURES * 

SPILL RESPONSE : Nechanically collect and remove spilled material. Area may be washed with water. 

NEUTRALIZING CHEMICALS : None required. 

WASTE OISPOSAL METHOOS . 

********'*******•*******+************** VII. REACTIVITY DATA *****+*** * 

STABILITY : Stable CONOITIONS TO AVOID: Contact with strong oxidizing agents. 

INCOMtsATIBILITY . MATERIALS TO AVOID : Nane 

HAZARDOUS POLYMERIZATION : YiLI not occur CONDITIONS TO AVOID: Nane 

HAZARDOUS DEC0MPOSITION PROOUCTS : Sulfur dioxide, carbon dioxide, and carbon monoxide. 

VIII. CONTROL NEASURES **+******************** ******* 

VENTILATION RECUIREHENTS : Adequate ventilation for comfort is recoamended. 

RESPIRATORY PROTECTION : Full respiratory protection program reconmended. 

PROTECTIVE GLOVES . GLoves recommended for prolonged exposure. 

EYE PROTECTION : Goggles recartmended for prolonged exposure. 

OTHER PROTECTIVE ECUIPMENT : CLothing which contacts skin should be changed daily. 

*****************r****************** IX. SPECIAL PRECAUTIONS 

REPAIR/MAINTENANCE OF . None required. 

CONTAMINATED EQUIPMENT 

HYGIENE IN HANDLING ANO STORAGE : Personal hygiene is strongly encouraged so alL cLothing items are changed daily. 

OTHER : Normal precautians comman to good manufacturing practice shoutd be followed. 

 ++** *'***** X. ADDITIONAL REGULATORY:CONCERNS ************ 

Lignosulfonates are nonrtoxic & non-irritating. Government regulations for use of lignosutfonates are surtmarized below: 

21 CFR 176.210 - Defoamers 

40 CFR 180.1001 Section (e) - Pesticides for Animals 21 CFR 177.1210 - Gaskets 

21 CFR 176.120; 176.170; 176.180; 178.3120 - Paper 21 CFR 175.105 - Adhesives 

21 CFR 173.310 - Boiler Water 

The information and recortmendations contained herein are offered as a service to our customers but are not intended to 

relieve the user from its responsibility to investigate and understand pertinent sources of information and to cartply with 

alL Laws and procedures applicable to the safe handling and use of these materials. The information and recommendations 

provided herein were believed by LignoTech USA, Inc. to be accurate at the time of preparation ar obtained from sources 

believed to be generally reliable. However, Lignoiech USA, Inc. makes no warranty concerning their accuracy and LignaTech 

USA, Inc. wiLL not be tiabte for ctaims relating to any party's use of or retiance on information or reconmendations contained herein, regardless of whether it is claimed that the information or recommendations are inaccurate, incomplete or 

otherwise misleading. 

«LAST PAGE» 

w 
Material Safety Data Sheet 

Substance Identification 

.dentity: MANGANESE DIOXIDE Cas R: 13 13-13-9 

Trade Names: Brickox, GranuSpeck 

Manufacturer: The Prince Manufacturing Co. Emerger,cy: Chemtrec 

One Prince Plaza 1-800-424-9300 

Quincy, IL 62301 

217-222-8854 

Components and Contaminants 

Chemical Name: CAS n OSHA PEL ACG1H TLV Percen 

Manganese Compound ( as Mn) 7439-96-5 5 mg/m' (C) 5 mg/m' (C) 51-55% Mn 

Iron Oxide 1309-37-1 -- — 1-5°/, Fe ZO, 

Silica, Crystalline Quartz (respirable) 14808-GO-7 0.1 mg/m= 0.1 mg/m' (TWA) 1-5% SiO Z 

Aluminum Oxide (non-fibrous) 

(respirable fraction) 1344-28-1 5 mg/m3 5 mg/m' (TWA) 1-7%Al 203 

Barium Oxide 1304-28-5 -= -- --= 0.2-2% Ba0 

Physical Data 

Boiling Point: NA Specif;c Gravity (H 2O=1): 5.0 

Vapor Pressure (mrnlHg): NA Melting Point: 535° C 

Vapor Density (Air-1): NA Evaporation Rate (Butyl Acetate=l): NA 

Solubility in Water: insoluble 

Appearance and Odor: blackto brownish black, no odor 

Fire and Explosion Hazard Data 

Fiash Point: Notcombustible 

'lammable Limits: LEL NA UEL NA 

Extinguishing Media: Foam, CO2, dry chemicai erwater. 

Special Fire Fighting Procedures: In the event of ire, wear full pro'tective clothing and NIOSi-l-approved 

self-contained breathing apparatus with full face piece operated in the 

pressure dernand cr other positive pressure mode. 

Unusual Fire and expiosion hazards: Not combustible, but substance is a strone oxidizer and its heat of 

~ reaction with reduc:nc agents or combustibles may cause ienition. 

Increases the ftarnmability of any combustible substance. 

Reactivity Data 

Stability: Stable under crdi<<arl ccnditions of use and storage. 

Conditions to avoid: Do not heat cr crr:d in the presence of e2sily oxidizable substances o , 

orgznic 

Incompatibility (materials to avoid): Easily oxidizable subs:arces, sulfur, sulfides, phosphides, 

hydrophcsphid-as, c`,Icrates, peroxides, aluminum powder, rubidium 

acetylide, azide, c;llorine triluor,de. Reactswith 

hydrochleric ac:d to fcrlm corrosive chlorine gas. 

Hazardous Decomposition or Byproducts: Upon heatinc it d=composes to form mancanese sasquioxide and 

oxygen whic^ facilitat=_s c:.mbustion. 

Hazardous Polymerization: Will not occur. 

Health Hazard Data 

Route of Entry: INHALATION: ylay irritate the resciratory tract. May increase the 

incidence cl ucPer r=_spira:cry infections (pneumonia). Prolonged 

exposure to siiica d::st n-ay result in silicosis, a fibrotic lung disease. 

SKIN: May cause ir"i;a:icn. 

INGESTION: N1ay cause abdominal pain and nausea. Manganese 

dioxide dust is cccriy abscrbed throuah the gut. 

?v(anganese Dioxidc, P__: ' 

RevicweC Jaly 1996 Unchangedsinee Jul} N' 

...~h 
Health Hazard Data 

Health Hazards (Acute and Chronic): Chronic exposure and inhalation c; excessive manganese dust may cause 

disorders of the central r,ervous sys:em. 

Carcinogenicity: NTP: No IARC f:;oncgraphs: Yes (Silica) 

Signs and Symptoms of Exposure: Early symptoms of mancanese toxic;',y inc!ude sluggishness, sleepiness, 

and weakness in legs. Symptcms cf silicosis inc!ude impaired pulmonary 

function and wheezing. 

Aggravation of Pre-existing Conditions: Persons with impaired resciratcry runctian may be more susceptible to the 

efflect of this substance. 

Emergency and First Aid Procedures: IF INHALED, remove to fresh air anc seek medical attention for any 

breathing difficulty. 

IN CASE OF SKIN CONTACT, was ~ ~ with soap & water. Seek medical 

attention if red & irritated. 

IN CASE OF EYE CONTACT, ftush eyes immediately with water for at least 

15 minutes. Seek medical attention if irritation persists. 

IF INGESTED, induce vamiting immediately by giving two glasses of water 

and sticking finger down throat. Never give anything by mouth to an 

unconscious person. Call a physician immediately. 

Precautions for Safe Handling and Use 

Material Release or Spil[ Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory 

protection. Recover uncontaminate•: mat—arial for use. Vacuum or sweep 

remaining material, keepina dus: to a minimum. Isolata wet material from 

dry ar,d store away from combustible materials. • 

Waste Disposal Method: Dispose of unreclaimable material in a RCRA-approved waste facility. 

Handling and Storing Precautions: Manganese dioxide is classified as an oxidizer and should be storad in a 

dry place away from cembusitlbes arid sources of high heat. Protect 

ccntainers from damage and keep c:csed when not in use. 

Other Precautions: Observe good personal hygiene. Wa:h after handling. 

Control Measures 

Respiratory Protection: Use NIOSH approved particula;s ras: irator if dust generation occurs or is 

anticipated. OSHA standard 1910.134 or ANSI Z88.2-1980 specifications 

are recommended. 

Ventilation: ' A system of local andlor cenera! ex^aust is recommended to keep 

employee exposures be!ow the Air'_- crne E:xposure Limits. Local exhaust is 

cenerally preferred because it can ccntrol the emissions of the contaminant 

at its source, preventing dispersicn cf it into the general work area. Please 

refer to the ACGIH docur-;ent, "Incus:rial Ventilation, A Manual of 

Recommended Practices", mcst recant eciticn, for details. 

Protective Gioves: Yes 

Eye Protection: Safety goggles are recommended. 

Other Protective Clothing or Equipment: Use other protective equipment whe- necessary in order to avoid 

prolonged exposure to skin. 

'Nork and Hygienic Practices: Observe good personal hyoiene. 'Alash a'er handline. 

SARA Title lll Section 313 Supplier Notifcation 

i nis product contains the fcllowing texic chemicals subject to the reporing requirer-e^ts cf, secticn 313 of the Emergency 

Planning and Community Right-to-Know Act of 1986 and of 40 CFR 37 2.45: 

Comoonent CAS % bv Weiqnt 

:.lancanese Dioxide 1313-13-9 51-55'/o Mn 

:~ arium Oxide 1304-28-5 0.1-1.8% Ba 

This infermation must be included in all MSDS's that are copied and distributed fcr tinis ma.erial. 

>l:uigancsc Dio.idc. P36 Z J ~ 

P.evir.ved luty 1996 Unchanged sinc: Jul} ~ 199

c

6 
Material Safetv Data Sheet 

Substance Identification 

Identiry: IRON CHROMI'I'E CAS L308-38-9 

Trade Names: CHROMOX 

Nfanufacturer: The Prince Manufacturing Company Emergency: Chemtrec 

One Prince Piaz.a 1-800-424-9"-~00 

Quincy, IL 62301 _ 

217-=-8854 

Components and Contaminants 

ChemicaI Name CAS # OSFiA PEL ACGIH TLV Percent 

Chromium Cr' ; 7440-47-3 0.5 mg/m' 0.5 mg/m3(TWA) 30-45% Cr 

Silica, Cryst- 11' e Quartz respirable dust 14808-60-7 0.1 mg/m3 0.1 mg/m' (TWA) 1.2% Si0 2 

Physical Data 

Boiling Point: NA Specific Gravity (H20=1): 4.4 

Vapor Pressure (mm/Hg): NA Melting Point 3350 - 4000° F 

Vapor Deasicy (Air=1): NA Evaporatioa Rate (BuryI Acetate=l): NA 

Solubility in Water. insoluble 

Appearance and Odor. blacic powder, ao odor. 

Fire and Explosion Hazard Data 

Fiash Point: Not combustible 

Flammable Limits: LEL NA L-EL NA 

E.Ytinguishing '-rfedia: Foam, COZ, or dry chemical or water. 

Special Fire Fghting Procedures: In the eveat of Fire, wear full protective clothing and ANZOSH-approved selfcontained breathing apparatus with full face piece operated ia the pressure 

demand or other positive pressure mode. 

Uausual Fire and explos'ioa hazards: Not combusuble. 

Reactivity Data 

Stabiliry: Stable under ordinary conditions of use and storage. 

Condicioas to avoid: None Kaowa 

IncompaCibiliry (materials to avoid): None Kaown. 

Hazardous Decompositioa or Byproducts: None Known. 

Hazardous PoIvmerization: Wi11 aot occur. 

Health Ha.zard Data 

Rouce of Eac;r. 1NI~TION: May cause delayed respiratory disease if dust is inhaled over a 

prolonged period of time. 

SKIN: No. 

INGESTION: Ingestioa of Iron Chromite may cause abdominal pain and 

nausea. 

Iron Chromite, Page 1 

April 1991 
Health Hazard Data (ront.) 

Health Hazards (Acute and Chronic): Respiratory disease may result from prolonged overexposure. Can cause eyc. 

irritation. 

Carcinoge:ucity: NTP: Itio L-kRC Nfonographs: Yes (Silica) 

Signs aad Syr.zptoms of Exposure; Excessive inhalation of dust may result ia shortness of breath and reduced pulmonary function. SyTnotoms of silicosis include impaired. pulmonary function 

and wheezing. 

Aggravation of Pre-eusting Conditions: Persons with impaired respiratory functioa may be more susceptible to the effect of this substance. 

Emergenc,v and First A.id Procedures: IF INHAI.ED, re:nove'to fresh air and seek medical attention for any breathing 

difficultv. 

IN C.ASE OF SKIN CONTACT, wash with soap & water. Seek medicaI attentioa if red & irritated. 

IN Ca.SE OF EYE CONTACT, flush eyes immediately with water for at least 

15 minutes. Seek medical attention if irritation persists. 

IF" INGESTED, induce vomiting immediately by giving two glasses of water 

and sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

Precautions for Safe Handling and Use 

`faterial Reiease or Spill Precautions: Should a spill occur, ventiiate area. Clean-up personnel require respiratory 

protection. Rtcover uncontaminated material for use. Vacuum or sweep 

remaining material, '.<eeping dust to a minimum. 

Waste Disposal yfethod: Dispose of unreclaimable material in a RCRA-approved waste facility. 

Handling and Storing Precautions: Protect containers from damage and keep closed when not in use. 

Other Precautions: Observe Pood personal kygiene. Wash after handling. 

Control iYleasures 

Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or is 

anticipated. OSHA standard 1910.14 or ANSI Z88.2-1980 specifications are 

recommended. 

Ventilation: A svstem of local aad / or aeneral eYhaust is recommended to kesp employee 

_ exposures below the Airborne E:cposure Limits. Local e.Yhaust is generally 

preferred because it can controi the emissions of the contaminant at its source, 

preventing dispersioa of it into the general work area. Please refer to the 

ACGIH document, "Industrial Ventiiation, A Manual of Recommended Practices", most recent edition, for details. 

Protective GIoves: Yes 

Eye Protection: Safety goggles are recommended. 

Other Proteczive Clothing or Equipment: Use other protective equipment whea necessary ia order to avoid prolonged 

exposureto skin. 

Work and Hygienic Practices: Observe good personal hygiene. Wash after handling. 

SARA Title III Section 313 Supplier Notification 

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency 

Planning aad Community Right-to Know Act of 1986 and of 40 CFR 3 7/2.45: 

Comvonent CAS * % bv Weieht 

Iron Chromite 1308-38-9 30 - 35010 Cr 

This information must be included in all t'YISDS's that are copied and distributed for this material. 

Iron Chromite, Page? 

April 1991 

~~ 
CHEMICAL PRODUCTS CORPORATION MSDS No. 44 

Revised Sep. 95 

MATERIAL SAFETY DATA SHEET Page 1 of 7 Pages 

1. PRODUCT IDENTIFIER 

NAiviE: Barium Carbonate - All Grades. Type FF, Type CFF, Type S, 

Type H, Type HA, Aqua Flow®, Micro-Flow®, and Photo Grade. 

SYNONYMS: Carbonic Acid, Barium Salt. 

MrNUFACTURER Chemical Products Corporation (CPC) 

P.O. Box 2470 

102 Old M71 Road, S.E. 

Cartersville, Georstia 30120-1692 

Telephone: Day, 770-382-2144; Night, 770-382-2212 

E1lERGENCY: CHEMTREC - 800-424-9300 

2. INFORMATION ON INGREDIENTS 

COMPONTEN'T CAS # EXPOSURE LIlVIITS % BY WT 

Barium Carbonate 513-77-9 OSHA PEL: 0.5 m.,,~/cu m as Ba ca. 97.0 

- 0.74 mglcu m as This Product 

ACGIH TLV-TWA: Same 

3. A.47.aRDS IDENTIFICATION 

E~'1ERGENCY OVERVIEW: White powder or granules with no odor or very slight 

rotten egg odor. Absorbed from lungs or stomach into blood stream. Causes muscle stimulation 

foliowed by transient paralysis. 

POTENTIAL HBALTH EFFECTS: Stomach pain, vomng, and dianhea. 

Routes of Entrv : Ingestion; possibly inhalation. 

Human Effects: Acute over-exposure wi71 caase severe abdominal pain, violent purging with 

watery and bloody stools, vomiting, muscie twiching, and confusion, followed by transiertt muscle 

paralysis, inciud'mg paralysis of the respiratory muscles, which may be fatal. Barium is eliminated 

from the body over several days. Chronic over-exposure may lead to varying degrees of pazalysis 

of the exaemities. Hypertension may also be present. Symptoms of over-exposure wilI disappear 

with time as the body eliminates barium, primardy in the feces. Hypokalemia is often observed; 

potassium shonld be administered - large doses may be required. 

J~ 
Chemical Products Corporation MSDS No. 44 Page 2 of 7 Pages 

Barium Carbonate, All Grades. 

Acute Inhalation: See Human Effects on Page 1. 

Chronic Inhalation: See Human Effects on Pase 1. 

Acute Sldn Contact: Barium ion is not li'lsely to penetrate intact skin; penetration through cuts 

and bums may produce symptoms of over-exposure. _ 

Chronic Slan Contact: Barium ion is not 1>7cely to penetrate intact skin. A slight irritation of the 

sldn may resuh from the alkaline nature of this product. 

Acute Eve Contact: Particles in the eye will cause pain, tearing,and irritation. 

Chronic Eve Contact: Particles in the eye will cause tearing and irritation. 

Acute InQestion: See Human Effects On Page 1. 

Chronic InQestion: See Human Effects on Page 1. 

CarcinoQenicitv : NTP .......... : 1993 study of barium chloride, a water-soluble barium sait, 

showed no evidence of carcinogenicity. 

IARC ......... : Not listed. 

OSHA. ...... : Not rewlated. 

Medical Conditions AQQravated bv Eanosure : None are losown. 

4. FIRST AID MEASURES 

InQestion:Have victim drink one tablespoon of Epsom Salts (magnesium sulfite) or Glauber's 

Sah (sodium sulfate) dissolved in wazer. If victim is not vomiting, induce vomiting by giving 

Syrnp of Ipecac or by sticking finger down throat. Repeat the entire procedure descnbed above. 

Call for prompt medical attention. Physician should admiaister po tassiu**+ 

Inhalation: Flush mouth and nasal passages with water. Have victim drink one tablespoon of 

Epsom Salts (maeT1Psium sulfate) or Glauber's Salt (sodium sulfate) dissolved in water. Cail for 

prompt medical artention. 

Eve Contact: Flush eyes with large amounu of water untii irritation subsides. Get medical 

attention_ 

Sldn Contact: Wash witli water and use soap if available. Remove severely contaminated 

clothing and wash before reuse. 

/ 

~~ 
Chemical Products Corporation MSDS No. 44 Page 3 of 7 Pages 

Barium Carbonate, All Grades. 

5. FIRE FIGHTING MEASURES 

Flashnoint: Non-Flammable. 

Flammabilitv: Non-Flammable. 

Autoisnition: Non Flammable. 

General Harard: No fire hazard. Will decompose releasing carbon dioxide gas at extremely 

high temperarures. This product is toxic if ingested. 

Fire Fiahtint: Instrnctions: Limit water runoffif it is liIcely to contain suspended barium 

carbonate. Add soluble sulfate such as sodium sulfaxe to the water to make it non-hazardous. 

Fire FL-htins Eauioment: No special equipment is required. Wash away aay barium carbonate 

which may contact the body, clothi.ng, or equipment. 

Hazardous Combustion Products: None. 

6. ACCIDENTAL RELEASE MEASiJRES 

Small Snill: Try to keep mazerial dry. Mix with excess sulfate to ma.ke material non hazardous. 

Lax-a-e SaiIl: Try to keep mazerial dry. Prevent runofffrom ernering storm sewers or ditches 

which lead to nazural waterways. Dispose of spilled mazerial in an appmved bazardous waste 

landfill or mix with excess suIfate to make material non-hazardous. 

7. HANDLING AND STORAGE 

Storaae Temoeratnre: Not critical. 

Storage Pressure: Not criticaL 

GeneraI: This product is not water-soluble, but is soluble in most acids. Keep this material dry. 

Keep containers closed. Emptied containers may presern a toxic hazard; treat or dispose of 

appropriately. 

8. EXPOSURE CONTROLS / PERSONAi, PROTECTION 

Eneineerina Controls: Control airborne concentrazions below the exposure limits. Use only 

with adequate verni3ation. 

J--(o 
Chemical Products Corporation MSDS No. 44 

Barium Carbonate, All Grades. 

Page 4 of 7 Pages 

Resoiratorv Protection: Use a NIOSH-approved dust mask if excessive dust is present. 

Sidn Protection: Cover exposed skin areas and wear general-purpose gloves. 

Eve Protection: Wear safery glasses. Use chemical goggles if excessive dust is present. 

9. PHYSICAL AND CHEMICAL PROPERTIES 

Phvsical State: Solid. 

Vaoor Pressure: Not applicable. 

Suezific Gravitv: 3.1 

Solubilitv in Water. Insoluble. 

vH: 1°'o suspension in water has a pH of 9. 

Boili.ng Point: Decomposes to barium oxide and carbon dioxide at about 1000 Deg. C. 

ylelti.ns Point: About 1000 Deg. C. - Neaz decomposition temperature. 

Vanor Densitv: Not applicable. 

Evanoration Rate: Not applicable. 

Odor. U sually odoriess; possibiy a very slight rotten-egg odor. 

Anoearance: White powder or granules. 

10. STABILITY AND REACTIVITY 

Chemical Stabilitv: Keep away from intense heat which may cause deconiposition. Keep away 

from acids which will cause decomposition. 

Inconioatibilitv: Acids will decompose barium carbonaze with the hberation of carbon dioxide. 

HaTardous Decomoosition Products: Barium carbonate may be decomposed to carbon dioxide 

gas wnich is haznrdous in confined spaces and another barium salt which may be toxic depending 

upon its degree of solubiliry in water or acid. 

Hazardous Polvmerization: Does not occur. 

57 
Chemical Products Corporation MSDS No. 44 Page 5 of 7 Pages 

Barium Carbonate, All Grades. 

11. TOXICOLOGICAL INFORMATION 

Sidn: Contact may be slightly irritating. Barium ion is not eacpected to pass through intact skin. 

Eve: The dust is expected to be slightly to moderately irritaziag. 

Ineestion: Barium carbonate is converted to barium chloride in the stomach. The Oral LD50 for 

rats is about 400 mg/kg of barium chloride. _ A National Toxicology Progrraam study found no 

decrease in two-year survival for rats consuming 110 mg/kg/day of barium chloride for the entire 

two year period. 

Inhalation: No studies. Inhaled dust is expected to exlubit the same systemic toxiciry as 

ingestion because barium carbonate is cleared from the lungs into the bloodstream. 

- Sub-chronic : Raxs and mice exposed to 1,250 ppm of barium chloride dfhydrate in their drinldng 

water continuously for two years showed no adverse effects. 

Chronic/Carcinoeenic : Rats and mice exposed to 2500 ppm of barium chloride dlydrate in 

drinkfng water for two years showed no evidence of carcinogenic response. 

TeratoLwenic : Rats exposed to 2000 ppm of barium chloride dibydraze in their driniting water for 

thirty days exlubited no teratogenic effects, and no fetotoxicity was noted. 

Renroductive: No effects were seen on reproductive indices in a mating trial after male rats 

were exposed to 2000 ppm of barium chloride dihydrate in their drinking wazer for sixty days and 

female rau were exposed to 2000 ppm in their drinking water for thirty days.. 

Mutagenic: Barium chloride dffiydrate was not mutagenic in Salmonella typhimerium strains TA 

100, TA 1535, TA 1537, TA 97, or TA 98, with or without exogenous metabolic activation (S9). 

12. ECOLOGICAL INFORMATION 

TOXICITY: In turbid water at 20 Deg. C, the 96 hour TLM has been reported as 10,000 

mg/1 for Mosquito Fish (Gambusia Affnis). This would have been suspended rather than 

dissolved. 

DISTRIBUTION: Barium carbonate is not water soluble and occurs in nature as the 

mineral witherite. It reacu with sulfa.te ions in the environment to form barium sulfate. No 

appreciable bioconceatrarion is e::pected in the environmern because barium sulfate is nararally 

present in altnost all rocks and soils. 

CHEMICAL FATE: Barium carbonate is expected to react with sulfate in the 

environment to form barium sulfate which is insoluble in both water and acids, and thus is inert 

and non-toxic. ~ ~ 

,~ 
Chemical Products Corporation MSDS No. 44 Page 6 of 7 Pages 

Barium Carbonate, Ali Grades. 

13. `YASTE MANAGEMENT INFORMATION 

Waste conta'ninsmore than 0.2% soluble barium is hazardous under the RCRA criteria.. If 

disposed of in its purchased form, this product would be a hazardous waste based on barium 

solubility in the RCRA TCLP test. Barium compounds can be rendered non-hazardous by 

reaction with escess suIfate to form insoluble barium sulfate. Any disposal practice must be in 

cotnpl'iance with locaL state, and federal laws and regulations. 

14. TRANSPORT INFORMATION 

D.O.T. Shipping Name .................................. : Not Regulated. 

- Technical Shipping Name ............................. : Barium Compound. 

D.O.T. Hazard Class ...................................... : None. 

iT.N.lN. ~ Number ......................................... : None. 

Product R.Q. (lbs) .......................................... : None. 

D.O.T. LabeL ................................................. : None. 

D.O.T. Placard ............................................... : None. 

Freight Class Bulk ......................................... : Inorganic ChemicaL 

Freight Class Package ................................... : Inorganic ChemicaL 

Product LabeL ............................................... : Barium Carbonate, Precipitazed: Type 

FF, Type CFF, Type S, Type HA, 

Type H, Aclua.-Flo®, Micro-Flo®, or 

Photo Grade. 

15. REGULATORY INFORMATION 

OSHA Status......................................................... . This product is hazardous under the 

criteria of the Federal OSHA Hazard Communication Standard, 29 CFR 1910.1200. It is 

classitied as toxic based on the oral rat LD50. 

TSCA Status .......................................................... : Listed on TSCA Invemory 

"Cl 

~ - 
. 1 _ 

Chemical Products Corporation MSDS No. 44 PaQe 7 of 7 Pages 

Barium Carbonate, All Grades. 

CERCLA Reportable Quantitv ............................ : None. 

SARA Titie III: 

Section 302, Extremely Hazardous Substances.... : None. 

Section 311/312, Hazard Categories ................... : Category 1(Acute Hazard). 

Section 313, Toxics Release Inventory ...... :........ : Barium Compounds, Code N040. 

RCRA Status ...............:......................................... : If discarded in its purchased form, 

this product would be a hazardous waste by chara.cteristic. _ Under RCRA, it is the 

responsibility of the product user to determine at the time of disposal, whether a material 

conta'~ the product or derived from the product should be classified as a hazardous 

waste under 40 CFR 261.20-24. 

16. OTHER LNFORMATION . 

N-,-FPA Rating(National Fire Protection Association): 

Health - 2 (Materials which on intense or continued exposure couid cause temporary 

incapacitation or possible residual injury unless prompt medical attention is 

given. 

Fire - 0 (Materiais that are non-Ilammabie). 

Reactivity - 0 (Materials wliich in themselves are normally stable even under fire 

exposure conditions, and which are nor reacdve with water). 

Special - NA 

Reason for Issue ...................... .... ....... : Change in Area Code. 

Preparedby ........................................ : Jerry A. Cook. 

Title .................................................... : Technical Director. 

Approval Date .................................... : September, 1995. 

Supercedes Date ................................ : April, 1995. 

MSDS Number ................................... : 44. 

This information is furnished without warranty, e:cpressed or implied, except that it is 

accurate to the best knowledge of Chemical Products Corporation. The data on this sheet 

relates only to the specific material designated herein. Chemical Products Corpor-ation 

atcumes no legal responsibiliry for use or reliance upon these data. 

iN 
E. Using Table 1, please provide information on the consumption and HAP 

composition of all glazes and colorants that contain HAP's or HAP precursors and 

that your facility applies to brick and structural clay products. Indicate whether the 

coatings are glazes or colorants. Also indicate the ty -pe of product that the coatings 

are applied to and the total weight of coatings used in 1996. If the glazes or 

colorants are formulated at your facility indicate so and provide the production 

capacity. List each ingredient of the glaze or colorant. Beside each ingredient, 

indicate the total amount of the ingredient used in 1996. If the information requested 

in the table is contained in your facility's operating permit or permit application, you 

may reference the applicable sections of the permit (or application) rather than filling 

out the table. 

F. In the space below, please indicate any glazes or colorants used by your facility that 

do not contain HAP's and are substitutes for HAP-containing glazes or colorants 

used by your industry. Indicate which HA.P-containing materials the non-HAP 

glazes or colorants replace. Describe any limitations on the use of those substitute 

glazes or colorants. 

N/A 

G. If your facility colors brick and structural clay products by flashing, please indicate 

the types of substances used to flash the products and the amounts of those 

substances used in 1996. 

Substance Amount used in 1996 Units (specifv) 

Natural Gas We flash by reducing the amount of oxygen in the 

kilns, thereby causing a reduction atmosphere. 

H. If available, please provide a copy of the MSDS's for the glazes and colorants used 

by your facility. If your facility prepares its own glaze, please provide any available 

MSDS's for the glaze ingredients. 

MSDS sheets are included. 

Page 5 of 28 

~~ 
T.4BLE 1. CONSUMPTION AND HAP COMPOSITION OF C'rT A7jZR ANM C'nr nR ANTC 

Type (e.g., Qlaze, colorant) EXAl~LE: 

Glaze - White Kaolin Clay 

Type of product glazed or Structnral tile 

colored Brick 

1996 consumption (tons/yr) . 1,140. 

1.9379 

Produced at facility? (yes/no) pes 

Yes 

Production capacity (tons/yr) 

129 

Total usage (weight) of each Total 1996 

ingledient (that is a HAP, Ingredient usage, tons 

contains a HAP, or is a HAP ~ 

precursor) in 1996 White Kaolin 1.9379 

_• -..,. ;,.,~~ ~ _ ~~: 

~. 

_ ' -d•°~ 

Y ^c 

~ . 

..... ,..~.....:.w... ~_^ -~ . ~ - 

vF~~' _ - • ~ . _ , ~ 

_ _ . .,.. ~. .. ...:,. .._ ~ ... . . ~ ~~

~ •-. . 

•.,. . . ~ ,r....,'.. :... .. ~~ .. ' . .:Yti~ 

If additional space is required, please make copies of this paae. If the information requested in 

the table is contained in your facility's operating permit or permit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

Page 6 of 28 

m 
TABLE I. CONSUMPTION AiND HAP COMPOSITIOV OF C'rT.A7FS ANM C'ni nu eXrrrc 

Type (e.g., glaze, colorant) EXAMPLE: 

GlaZe Target Slip 

Type of product glazed or Structural tile 

colored Brick 

1996 consumption (tons/yr) 

~ 6.8064 

Produced at facility? (yes/no) yes 

Yes 

Production capacity (tons/yr) f,,50~`., 

929 

Total usage (weight) of each ,K .. Total 1996 

ingredient (that is a HAP, 

,.9:_.. ~ •:~ .5...:.n.:4., R,~,~. ~

=; Ingredien~~' 

~ . .. ~ .-.- ~~,,.y, 

_; ulsage, ton~s Ingredient usage, tons 

contains a HAP, or is a HAP 

precursor) in 1996 ~'~ > ~ ~~- _. Blue Kaolin 5.4451 

Albion Kaolin 1.3613 

s .. . 

~. /~~ ~ '.. 

V~VV' - _ 

'-~F`.~— - i'"y(tv.> ~ vG~r •' ~':~~_ _.:.~'3'~yY 

[~-'G,

r•-.. ~ ' . :w~a . ~ ~..-Y 

.. . ~~. .. . .. - . F 

..~ . . . ~ .. ; . . . 

If additional space is required. please make copies of this paQe. If the infotmation requested in 

the table is contained in your facility's operating permit or permit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

Pa~e 6 of 28 

~ 
TABLE 1. CONSUMPTION AND HAP COtiIPOSITION OF GLAZES AND COLORANTS 

Type (e.g., alaze, colorant) EXA~~LE: : 

G1aZe - Grey Engobe 

Type of product glazed or Structural tile 

colored _ Brick 

1996 consumption (tons/yr) 1,140 

.6804 

Produced at facility? (yes/no) ~.~.,. 4`= pei.... 

~ Yes `•w. 4K: ~i~, : a.~ -•.. y,. - Y ~. 

Production capacity (tons/yr) 

..r. .a. ~'°.~st . ~ ~'~

c .•~• -.r•{—•h w. 929 

Total usa;e (weight) of each ,- Total 1996 

ingredient (that is a HAP, Ingredient usage, tons 

contains a HAP, or is a HA.P 7 w - 

precursor) in 1996 ~~ ~` ~ 4- white Kaoli .1335 

Blue Kaolin .5336 

N"11;1, ' Chromor. , .0133 

06 _ 

.~, ~.....: 

— -..__ ~. . . .. - . _ -• _ _ _ •; ...;:..: ~ M ~ . , , ' . :_~ _ _ -: ~

-...-_ ' ~ _ 

'--- , .._ ...- .,... • ....:.x.: ., 

:c~ -.•d, r -.°.,.. 

...., ... l~.. - - ,-i • .v._ ;:_._ 

.. ~~ ..... ~ _ 

. .-. - _. ..,:.=,x!. ~ 

.._ ~ — 

-' 

~1.. { ~. •a~A1. 

+~ r^C'''' •t' ~,~ - 

.:f 

"Ss 

- ..~=Y_» 

If additional space is required. please make copies of this paae. If the infonmation requested in 

the table is contained in your facility 's operatin ~ permit or peit application, you may reference rm 

the applicable sections of the permit (or application) rather than filling out the table. 

Page 6 of 28 

&V 
TABLE l. CONSUMPTTON AiND HAP COMPOSITiO7N OF M A7Pc eNm rrnr nn AXr,-c 

Type (e.g., glaze, colorant) EXAMPLE: 

GlBze Engobe S1-102 

Type of product Qlazed or Structural tile 

colored _ Brick 

1996 consumption (tons/yr) _ 1,140 

6.5555 

Produced at facility? (yes/no) 

Y e s 

Production capacity (tons/yr) , 

~ 

'E-.•"u•~ 929 X r i~ :!i~T't.""

~~ T,°.c.—^.ytS;, r ;~ 

Total usaQe wei ~ ( ~t of each ) ~~ ~~~ 

- 

. ~ot~ ~' Tota11996 

in gr edient that is a HAP, ( Ingredient usage, tons 

contains a HAP, or is a HA.P x 

~~: xaolin 1. 2981 precursor) in 1996 f..-~~ ~~ite 

=•-.-..~x._ . .- ~_. . . 

Blue xaolin 5.1925 

Chromox N- .0649 

~ •.,swrt.-} 4 i ~ _ _ 

,.y..,~ ~. 

a _' ::~~'~•~ ; 

_ •. 

~. 

. . 

_ 

,_ _ ..• .. ~ . . . -. . . .~.:..f-•~~'i~ ` . ... . .- . 

_ .. .. 

.l• ~..~ ~~ i

.iL~u-. .. _ _ - _ - . . 

. _ 

. . .. ....c.. . . _.. .. 

~ 'JA.. ~ - 

... .... . 

If additional space is required, please make copies of this paQe. If the information requested in 

the table is contained in your facility's operating permit or permit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

~ '-- 

Pase 6 of 28 

~/ 
TABLE 1. CONSUMPTION AND HAP COMPOSITIOti OF GL A7FSa ~m cn1 nR ou-rc 

Type (e. g., glaze, colorant) EXAl12PLE: 

Glaze ` Brickox 

Type of product Qlazed or Structural tile 

colored Brick 

1996 consumption (tons/yr) 1,140 .2889 

Produced at facility? (yes/no) ~~ ~ :} yes- 

' No =n3' . _~. 

Production capacity (tons/yr) ~ ~ ~~ {~~ ,;~~ I,SQ~, ~ _ ~ ~ 

~~1=~ 

7 ~} 

. ~ ~a,:s,~..~„'~. 'j, .. . - ' e:•,,, rr _. , 

Total usage (weight) of each Total 1996 

ingedient (that is a HAP, z;Ing~redien~ ; 

c ,~ usage`* ~oas~ Ingredient usage, tons 

contains a HAP, or is a HAP 

precursor) in 1996 ~W 1A _ 

Y~ B._ . 

,.--. 

~-~ 

G — - 

__ Brickox .2889 

,. .._..~ ..~ 

. . ' ".WIJF.;:~-~'~« ~•.....;,~ !/.i~=^ = ~ . , 

.......... • . -. F.o-...... e~t„ ~ .:.. ~ . . _.'.- -.'W 

~

-of

y~~~"m 

.' 

~~•, •: :!. ~~...:.. .. . ~ - ~: . . ^ 4- . . . .,_.-_, ~.. -~ 

~

-'wit A k ~ .. 

*F. •y... 4; _ '-a`i-9 

. 

..y,. . 

. ,. ........ . 

.. ,. . .~ ' 

. . . ~.~ 

~ -- ~ - _ _ •r' ~ 

. ... . . .. 1 

If additional space is required, please make copies of this paQe. If the information requested in 

the table is contained in your facility's operatinQ perrnit or permit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

Page 6 of 28 

iEO 
TABLE 1. CONSUMPTION A1vD HAP COMPOSITION OF GL4ZES AND COLORA~vTS 

Type (e.z., Qlaze, colorant) EXAWLE: 

Glaze White Sand (21) 

Type of product glazed or Structural tile 

colored Brick 

1996 consumption (tons/yr) _ 1,140 15.2848 

Produced at facility? (yes/no) es:~ ~ 

- Y e s 

Production capacity (tons/yr) 

1030 ~d'• . ~LL'. w~~~.a:'Wm.-.~,~:~"e~r7:.... ~}-v:.-. i.aY. >

`~'~•i_), 

Total usaQe (weight) of each . ... .: Total 1996 

. . ingredient (that is a HAP, ~ ...y .. .. ~..~....., . ...~~~ ~ .. . ::;,;Ing~dient, :., 

.=.:. ~ v..~_ :. :.. . : i 

-:us~age~to _ Ingredient usa;e, tons 

contains a HAP, or is a HAP 

precursor) in 1996 ~- ~'~ .~~~ 

Sand 9.6739 

White Kaolin 4.8370 

Superpax .7739 

_ _~~~ ~ ' ~~~~ • 

~s 

—•1~i~_ra~~ 'Y 'r.~zir 

_•~~ 

_ _ — 

If additional space is required, please make copies of this page. lf the information requested in 

the table is contained in your facility's operating permit or permit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

Page 6 of 28 

67 
TABLE 1. CONSUMPTION AND HAP CONiPOsrrrnN, ,OF nq A7FC eNM r'nr nD nxr-rc 

Type (e.Q., glaze, colorant) EXAIMiPLE: 

G1aZe " Black Sand (15) 

Type of product glazed or Structural tile 

colored Brick 

1996 consumption (tons/yr) - .. , .. . • . ~ :. 6.7063 

- -. _ - '.•?. 

Produced at facility? (yes/no) 

-~•:`~'"°;~:i~~ ~ ~ := Yes 

Production capacity (tons/yr) 

: ~ - . ~• z s .:.=M.- - 

TC'''~ 

257 

~

• s ~ - ..r~;•.~~:~-;~ 

Total usage (weight) of each 5,^~"~~.~ Total 1996 

in ~ edient that is a HA.P, ( : ~e~en>~~~- - 

u 

~;>~eY_fo Ingredient usage, tons 

concains a HAP, or is a HAP 

precursor) in 1996 '— ~~~ ' 

. .~ ...- ~, .. 

~ 

~~ ~~ Sand 4.2988 

• :,- ~: ,- ._.~ 

• ~~ 

~ . t-. : ,~-~. , White Kaolin 2.1495 

..,.~.. . 

- 

- 

Brickox .1290 

- .•~ :~~, --t . -- ~ ~,~ ~ 

.Ehromox .1290 

.. S~

".` °°q-•r:_ .y 

..y,, . 

__ °' 

~y+: 

- . . .. ..-. :. ....... - _ 

~ ~

'L; ''i 4 j, M~~:~ `~`~x..~ 

,...- .~K -_ 

-•.npt~r,$~4• _s .:3?' ~~ ~ 

- -•.-. .. •....,;._r 

- - ._~~ 

.~._K'. ~' '+t '• 

• .ak . ..~

"!.'^•.. ~ . - 

•aa.. = fi '~yT.,s~~~ ' ~.. 

;.~ ~ ~ ~ ...3.. .. •. l,_±i .

. -.kC 

~' 1.-,ti' - 

. .-..... . ~ ~ '._F!•~~ _.•. . . .: ~ 

~,. . ~ ....:. .. . ....~~ " 

.. . . ... . ' ~ .. 

... 

. 4 

If additional space is required. please make copies of this page. If the information requested in 

the table is contained in your facility's operating permit or permit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

Page 6 of 28 

~~ 
TABLE 1. CONSUMPTION AiND HAP COIN1POSiTTON OF GT.A7F.c evn rnT no e%- ~-c 

Type (e.g., glaze, colorant) EXAiMPLE: 

GLiyg Red Sand GR,'~I-1 

Type of product glazed or Structural tile 

colored Brick 

1996 consumption (tons/yr) " 1,140 _ - 

12.9956 

Produced at facility? (yes/no) 

Y e s 

Production capacity (tons/yr) 

z.~~- ~ • ~ >> ,. z, , ~ - 

kds 

515 

Total usage (weight) of each r Total y Total 1996 

ingredient (that is a HAP, _:Fngre&en~ ,r. _: asag~ to "__ Ingredient usage, tons 

contains a HAP, or is a HAP 

precursor) in 1996 ~~~~` ~~- ~~~ Sand 8.4939 

.a... 

~ ~~' 

. . Y, 

i - ~.• ~~•~ - White Kaolin 4.2469 

Re d I ron Oxide .2548 

~ • ~ ~. 

-°~~~.`r _- 

~y,n~ ~_ _ : ~ 

~ :

,V•VQ _ ~`e-'-~". 

_ __ _ ~ •rt~_ -_-.~;a'^ . ' - . 

-~-;~~ •. _ _ ~ . _ ~"tCr 

• ~-' 

- .a/ilol~' l.i- ~ - 

. ~ - 4 

.__. •s'~ i 

If additional space is required, please make copies of this paze. If the information requested in 

the table is contained in your facility's operating permit or permit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

Paje 6 of 28 

l0 ~ 
TABLE 1. CONSUMPTION AND HAP COMPOSTTION OF C'7T A7FC A1vi> rnr no e\rrc 

Type (e.g., alaze, colorant) EXA.iWLE: 

GIaZe - Rose Sand GRM-2 

Type of product glazed or Structural tile 

colored Brick 

1996 consumption (tons/yr) 

... 

.. -~ 

. 

.. .. _ . > . . , .... ..: ... .... 

. .,... "„ . 

,. 9.7467 

Produced at facility? (yes/no) pes 

Yes 

Production capacity (tons/yr) 

z,~ F.~~,~r. , ~• ; -~- _- 

~`~ 386 

Total usacre (wei?ht) of each ~~ r~~~ ~~Q~ Total 1996 

ingredient (that is a HAP, 

~. ~b`~'~e' $ 

Frigredient~. . 

-. -1• .- - 3 . ~._K 

nsa~e~ Ingedient usaoe, tons 

contains a HAP, or is a HAP 

precursor) in 1996 "°- ~~~~'~ '=6~ ~_... Sand 6.4548 

~- Z ' White Kaolin 3.2274 

rQA$ ;~ Yellow Iron 

Oxide .0645 

~t -a--✓; ~.~ `= 

,.. .. . .. ta,; -~ ,~:~ ." . 

.iS.3:T 'a'„~a'~sC!. 

..... ..: .A i: 

ro.. . 

. , i ...• . L~ 

.. ~. _.. ~ . " . ~ .. .... . . 

•a:+s.~-....:r?"`-'a-.W.. _ 

. ' 

' : . ~ .%.~f 

-.... . 

. ~.S 

If additional space is required, please make copies of this paQe. If the information requested in 

the table is contained in your facility's operating permit or pe.~nit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

, A•. 

Pase 6 of 28 

7e 
TABLE 1. CONSUMPTION AND HAP COMPOSITIO` OF GLAZES ANr) CnT nR ANTS 

Type (e.g., glaze, colorant) EXAiMIPLE: 

Glaze E01 - White Powder 

Type of product glazed or Structural tile 

colored __ Brick 

1996 consumption (tons/yr) :,_ 1,140 

~. . ... ,. .. . t~ :... 

. . ~ .. _ ....,. 

1.7223 

. .. . . ...~ 

Produced at facility? (yes/no) 

Yes 

Production capacity (tons/yr) 

..,.a: x-~.~~ 

. ; ,~•4 --. 

129 

Total usage (weight) of each Total 1996 

in gr edient (that is a HAP, ~ ~gt~edi ent~ ~~ , ~ _ toi~ In gr edient usa e g , tons 

contains a HAP, or is a HAP ~~~~ ~ J ~~;~ 

precursor) in 1996 Albion Kaolin 1.0334 

ti Blue Kaolin .3445 

Lithospar . 3444 

=4, , w.dt' - - ~<.✓:. 

~~~r :r:° ~..:.3:;~. , __ '_w.~,... r.• _'v?;';~`-~ 

, . ... ..c• 4. 

..-f.; ~.._:.'•.... _ 

_ ~,.... y 

- 

~,.~ •• ~ 

_. . . 

...:•_ 

. , ~:~-.:: ~ ;;. ~•,.. . ,- . ~ ~ •>.. ~~ .~ . _ ~ _ a..;.. 

.- _ 

If additional space is required, please make copies of this paae. If the information requested in 

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PaQe 6 of 28 

Vl 
TABLE 1. CONSUMPTION AND HAP COVIPOSITION OF GLAZES AND (`nr nR aNvrc 

Type (e.g., ?laze, colorant) EXAMPLE: 

Glaze " white SF-48 

Type of product glazed or Structural tile 

colored Brick 

1996 consumption (tons/yr) ` 1,140 _ 

.4187 

Produced at facility? (yes/no) 

Yes 

.~`.~,:.~,_'..... ~.'A.,}'^.'.T.J+ ~......~~... _ ~ .'.. .... .•;'....'. 

Production capacity (tons/yr) ~ G { ,S1I0 = 

.'ri "'n., • 59 

Totai usage (weight) of each 

ingedient (that is a HAP, 

S .at 

•. 

y~~en~ ~ :.usag~ 

 ..~ 5% 

to>~ Ingredient 

Total 1996 

usage, tons 

contains a HAP, or is a HAP .~ : 

~-

~~F 

 .~- -ft,:= ~ 

precursor) in 1996 ~ 6°~~~a~ Silica Flour .2093 

Albion Kaolin .2094 

°OAS"=: ==;~ 

.• ,,:,, _ - /~ ..: • 4 

„'`SSY.~+T~ v ..f::..,.. 

~~~'.-_(J•:~4✓

/+'~t ''~~~.. 

"~- ., .. .•~~• 

`~~ -.• ~~^~J-+1 

w-.l ~'"~~ 

~±' 'M~•~~4 ~_ 

~...r' ' ~5+''

=~~~ ~~• 

-?~ "t1T .A~.~~

°... ~~.w.•v....c' 

_ : 

. . ~ 

!`~w" -~, ~ 

-'. ry~'; ~qL ~~•^ :~Y 

• ~eia _ • • 

' ~'.~ R •y ~xa ' - ~- 'S' . 

. n.•` _ . 

.....__, a`~ 3.^.... s .. " . 

~ .. ..-....... ... . .. 

~ .. ~ .._ ..:._c:..: ~ r;.... .. __ . ...-..... __..._ ~ .. ... . . .. . .... . . ... . ~ ._ 

... . . ... ~ 

... ~ .. ._ ...~ : . ' ' 

.. 

- Y 

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Page 6 of 28 

/4~~ 
Tr1BLE 1. CONSUMPTIOti AND HAP COINIPOSITTON; OF c ~ -TT a7Pc eNrn rnT nD nXrrc 

a...,..~.. . ~ 

Type (e.g., glaze, colorant) EXr1ALPLE: 

G1aZe - Sante Fe Blue 

Type of product glazed or Structural tile 

colored Brick 

1996 consumption (tons/yr) 

.2662 

Produced at facility? (yes/no) 

Yes 

Production capacity (tons/yr) 

118 

Total usage (weight) of each ~ a`~~~~ ~ ~ TQbg' 

~ ~. Total 1996 

ingredient (that is a HAP, ~

L. 

ent ;; aSages to ~ Ingredient usage, tons 

contains a HAP, or is a HAP 

precuTSOr) in 1996 ~~~~`- ~'~~~~ Silica Flour .2605 

- 

Cobalt Oxide .0052 

(ta$ Brickox .0005 

.:_'.t,•..s • .~?.. ~.~ 

~ 4.:^-.Y ;. 

_ 

"~ .E ti L ~ --~=• 

. _ ~. ~ ~ .. . ...,_.. . . .:-r......... -.~-..,. : . w._;~•ty~,a...;~~

ir..:.. , . ..:.. ~ _ c-: .'_. - . . ,_ '. .._- ... ~.`.:. 

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Page 6 of 28 

2_3 
TABLE 1. CONSUMPT10v A~~D HAP COMPOSITIOti OF GLAZES AriD COLOR AVTS 

Type (e.Q., alaze, colorant) EXAMPLE: 

G1aZE Santa Fe Grey 

Type of product glazed or Structural tile 

colored Brick 

1996 consumption (tons/yr) 1,140 ~ 

.3401 

.. - - _ •r - -. ~ 

Produced at facility? (yes/no) 

z Yes 

Production capacity (tons/yr) 

118 

Total usaae (weight) of each ota~ Total 1996 

ingredient (that is a HAP, ~T~ieni~ ',nsagesto " Ingredient usa;e, tons 

contains a HAP, or is a HAP 

precursor) in 1996 M. :~-~ ~~. Silica Flour .3239 

Cobalt Oxide .0032 

Brickox .0130 

l w JT 

. ~•'kW.nLw6:..~Vr'r..1. 3a ~ . - 

-... ._~ _...r . .. 

~ N..." 

:v14,_ 

. 

. . . -.. ..Tl 

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Page 6 of 28 

~~ 
TABLE 1. CONSUMPTTOV AND HAP COMPOSITION OF GL.AZES AND COLORANI'S 

Type (e.g., glaze, colorant) EXAMPLE: 

GlaZe Grey C-123-A 

Type of product glazed or Structural tile 

colored Brick 

1996 consumption (tons/yr) :1,240 

. . ... ..... . . . ... _ .. ~ _.. .... . . .. 

.... ,.. . ... ., -_ .:. - .. _ .. _.:, - _ .2295 .-,---• 

Produced a:v: acility? (yes/no) 

-~ '. .~,~ r r •~: ~, Ye s 

"-_~'.~.~,`~.%~,~~ _ . ,a~'.r i,,•--_. .:'<.' 

Production capacity (tons/yr) 

~ 

.,:. , ~ ~ "°= ~ -'s._ ~.~-..: ;.~.~.-..p..~~`

'

✓

~~'.~ 

~.....;r.`, .~

,~ 

 118 

Total usage (weight) of each ~'~~~'~~ ~ e-$ e TotaC ~-- Total 1996 

in gr edient that is a HAP, ( . - ~ :'€~edien~~'' ;: `_•`'' xosag,erfo `" ~`~ ` Ingredient usage, tons 

contains a HAP, or is a HAP 

Lithos .2186 precursor) in 1996 P ar 

Cobalt Oxide .0022 

~ ` ~~~ ~ ~- /~~ ( ~-- s Brickox .0087 

~~~~,?r Cfy''.

~ ~ F _.V•~- ~cL` 

~ 

-i ~- 

,. 7.: 

n 

~ ~•~W

Y

"...f ' - ~~. w~.P'" a: . 

y~ 

--~-~. 

_ ~ - - 

- ~,• fi ry!_"i _ 

~ '!''S'~.~•~~ 

-•--'-:...:• - 

, 

.. _ _ a`~! v~ Y 

~~~ y~•c. ~e- 

'~ . 

-~:~..,. "'Y~ .a:,,.,; ..,_..._ •zK.. '.. r :. .-i : _ ' ~ -. - ~ _} 

.~ '~'•~' .t.~ • .. , _ 

...:~

.r . . , .. 

e~~ a~~.~4. `:-'• _~ - 

. <, '1M.. ~ ._.W. '~__+~ :• 

. . . '/+. 

, ~ 

..,~ ..~re:..'.-.."-. .. . 

' .....- .•.: . .r.-- ~., _ 

..,. .. . S- _ :~ : 

'. .:. -' .; :...... . .. .. * 

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Page 6 of 28 

2-5 / 
TABLE 1. CONSUMPTION AND HAP CO'i'YIPOSITIOti OF GLAZES AND COLORANTS 

Type (e.g., glaze, colorant) EX,AiMPLE: 

GIaZe Target Slip 

Type of product glazed or Structural tile 

colored _ Tile 

1996 consumption (tons/yr) 1,140.:: ' 

1.1380 

Produced at facility? (yes/no) yes 

~. 

~ ..... ~ - Y e s 

Production capacity (tons/yr) 

v~.'7.~•'.~• - ~ '•• ~ r -75;•~~- "

ZE:r 706 

Total usage (weight) of each 

~yy~~ 

~.-~~,~~~-~~ ..,, T ',. ~-~ ~~~utat~ 

~ w'~~-~ 

k 

y ± 

.~ ; ~ •-- 

Total 1996 

ingredient (that is a HAP, ~)Eiigredien>1: ~.; ; osag_~ fo' :. Ingredient usage, tons 

contains a HAP, or is a HAP •- -m =4,2 

Blue Kaolin .9104 precursor) in 1996 ii0-~~~''~' '' ~+~~4`~~ K_ ~- 

Albion Kaolin .2276 

.. ;,_ : .... ._ 

'- ~~p-•='=x• ~-• 0.~~~- 

-. :. ...:. .. . .. . ... .. .. ..: e:..; _ 

. 

~ .._...... . . - ... _ ... ; 

,.- ~_ :.~.s....':_; :~~~ .' ,;:.•} ,=•a,;;_:;} . . . -" - .—._' 

. .. ~ .:~ ,._.- .~-=-•: 

~.C°'_'S1• : _ .. ._ - _ __ 

.. ~

+1'•+~'- 1} ~~ 

..+~c..:~~ ~ 

-- , :~ 

~~ • 

._. . Sy s a ~ .<. `?'.. . - ..*~s.,._... . -, - -%-•- . 

_" =.~L¢' ;.~` i l T- ~ .f+':. 2 .: •~ Y 

.S

rJi:Y^'' -I^; ~-.A:: ~~~ _ - - •~ - ':'a..s ~

~ •'i~.~.2'..;'Srrilt . ~ .. . . . 

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\ • 

Page 6 of 28 

~I/ 
TA.BLE 1. CONSUMPTION AiND HAP CON1POSiTiON OF C'rT A7-P.c eTVri rnT no e\rrc 

vLVL~fI.I ~ LJ 

Type (e.g., glaze, colorant) EXAMPLE: 

Glaze Brickox 

Type of product glazed or Structural tile 

colored Tile 

1996 consumption (tons/yr) 1,140 = 

-~~ .9315 

Produced at facility? (yes/no) 

~`w,"-° -.-,~~, No 

✓., ~_=° ::.~~.- - - - _ 

... _ ~,~ .. 

Production capacity (tons/yr) 

~ 64 

Total usage (weight) of each '~-•0.'3,3. a~~a~' s' 

r .. . L_:.. ~;~ 

Total 1996 

~ 

.,~~~°~ 

. . '. -~ ingredient (that is a HAP, :}~u~edient ~ n~ to ``_ Ingredient usage, tons 

contains a HAP, or is a HAP :. ~,:: ~~;-., ~ „_~ ~•~~ 

precursor) in 1996 

;~`

~~"~ 

~ Brickox .9315 

:.. -• _ ~ 

.....,.- ~-~_.... , ... 

... . 

~ 

-•• ~ 

:~~~ 

_ -~~ 

•~ ::~ 

b? _~.;Z _ 

^_- 

~~ `S...r a. : .4r. S .: <•. ~ 

~ 

~ '~: ...... .....~ 

: -.~fyf.,i+..s.' . ~ i • -. . ..~ '. 

. ~.~.~c~i ..._. . ... ~ ... ..:~ 

- .... 

. .'.._.y.'.= 'c. V. 

~ . ... .. .~._ . 

• . .. -v 

_.... .. 

. . ~ 

If additional space is required, please make copies of this page. If the information requested in 

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Page 6 of 28 

2;? 
TABLE I. CONSUMPTION Alti'D HAP COMPOSITION OF GLAZES ANn ['Oi.ORaNrrs 

Type (e.g., Qlaze, colorant) EXAMPLE: White Sand (21) = G1aZe 

Type of product glazed or Strnctural tile - Tile colored 

1996 consumption (tons/yr) 

_. 

: •~-. =. : . .. 37.3498 

Produced at facility? (yes/no) Yes 

"W~~ 

Production capacity (tons/yr) ~ 

- 1150 

Total usaee wei ~ ( gh t) of each `-~"~"~~~ ~' ~~., .. ; ,. ~o ~ t~ ~, . r_ -. Total 1996 

ingredient (that is a HAP, Ingredient usage, tons 

contains a HAP, or is a HAP . ~ 

~ 

precursor) in 1996 ~~~~~= W_~~~ ~; Sand 23.6391 

White Kaolin 11.8196 

.=-•~~ - 

,' ~ Su er ax 1.8911 

,R ~ . 

~ ~~~`.~..~-' 

-•` ~c-~;- Of-__ 

~ff 

T~''~~~~~~,~~ .. _a•G ~-~ . 1+1~~ 

. 

}• ~ '~~~a.~. "r .fl

~ ..; .~ 

: =s 

:..r.. _ ~ ... • ---- ,~..,, 

.l ~~~ ' _ - ,~ • - 

j_ -~_~ A'.... ~ _~~~.~

yw.....~•~. - 

^':Sy~}} ~, T'Y"

'4:_ 

i ' - '.~iy0„Y 

=(~',,• •' 

. 

-- 

~~,FS~ ' ~ _!~ ~ _p~' -~ .. -^v+P! ~.. ~Yy~~'~~:•'~~. t 

' - • ~Y _ 

jr.. ~. •~Ia; N..A'w . u 

_ • }. ~.~.— - 

. 

~. ~ - ~ ; ; ~

. 

. - . . . :V 

Y 

If additional space is required, please make copies of this page. If the information requested in 

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Page 6 of 28 

~i 
TABLE 1. CONSUMPTION AND HAP COMPOSiTiON OF C'rT.a7FC errn rOT rnD eNJ-rc 

Type (e. ~ ., ;laze, colorant) EXAMPLE: 

G13Ze Black Sand (15) 

Type of product glazed or Structural tile 

colored Tile 

1996 consumption (tons/yr) 1,140 = 

26.7878 

Produced at facility? (yes/no) 

Yes 

Y'9 

Production ca aci F tons/ ty ( yr) 

.5.~ . . . 

287 

Total usage (weight) of each 

s 

Yn ~ Total 1996 

in ~ edient that is a HAP, ( ~ In~red"en~~ r o5ages ~o _ Ingredient usage, tons 

contains a HAP, or is a HAP 

~--~5~~~ 

~;~, ~.~ .>~- 

precursor) in 1996 ~~ ~ ~ Sand 17.1716 

-• :~ r 

ri~~~.: 

-.~ 

White Kaolin 8.5858 

Chromox .5152 

,=1{Viil~•-~ ~a(1~~ =~ 

,.... Brickox .5152 

.... ...- .~:; =~ . .. ......... ..... . ... .~ 

.~ - .' - 

.. . . ._ . . , 

~ _ ;c ~ . .. ~ ... . _ . 

. . 

. ,... . . . . ... 

._ _ ... ..._.. ~ . .: . • - - ....-.,: . ... . .. . .. 

.k -.~ ' :• 

4(a~y 

j .' " ..'.'3.~

w 

. 

..-_ ~n.... 

.: ~ - .. ._ 

~~lib•4_. ....vAY 

. _. 

. .•..r, r.p"S4a.-- -. , ,. ' . . ' - i 

. . .. _ .. . . ... _ . - 

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Page 6 of 28 

~/ 
TA.BLE l. CONSUMPTION AND HAP C0iMPOSTTION OF G LAZEV, aiNm rnr nR a ~--rc 

Type (e.;., Qlaze, colorant) EXAMPLE: 

Glaze Red Sand GRM-1 

Type of product glazed or Structnral tile 

colored Tile 

1996 consumption (tons/yr) 

~ 33.8214 

Produced at facility? (yes/no) 

Ye s 

Production capacity (tons/yr) x- 

~-~~~ 575 

~,, 

- ~~~ ~.;~ 

Total usaae (weight) of each a t, ~~ Total 1996 

ingredient (that is a HAP, ~ *~-• ~~ , '~en1~L- ~ ;:, ~ ~- 

~osag.~,~o Ingredient usage, tons 

contains a HAP, or is a HAP 

precursor) in 1996 ~~~ ~~ ~~~~~=, Sand 22.1055 

~~ ~~ ' aF.'23` White Kaolin 11.0527 

Red Iron Oxide .6632 

..: . 

' !i• ~L ~. .: .. .'.` i:.«, . •;r.. r ....: y'~'- .' - - ~ ~:...i.. 

... ..., _.. ~ ...r..~~ 

,. 

4

~~ 

~... 

... .. .~ 

:

1:7D 

~f..L:^ 

~ ]!Y 

~t' • _ _ 

:i•w'i 4 .. ' . . 

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Pa ~e 6 of 28 

m 
TABLE l. CONSUMPTION AND HAP COMPOSITiOV OF GLA7F.q avn rnr nu e\.rrc 

Type (e.a., alaze, colorant) EXAMPLE: 

Glaze Rose Sand GRM-2 

Type of product ;lazed or Structural tile 

colored Tile 

1996 consumption (tons/yr) 1,i40, ` 

' - l'~y 25.3660 

Produced at facili ty? (yes/no) 

~ 

°-'° 

Yes 

Production capacity (tons/yr) 

~:- 

. ~ ' :~,~. 

: -•. _ ~. - _ ~ _..N..:...,-_ 431 

Total usage (weight) of each 

b 

~ 

_ 

Total 1996 

in~edient (that is a HAP, •;~. ~ ea~.. 

:,..-:,,y._ 

, n~ge~" tu : _ ~ ~ •:, In ~ edient usa e g , tons 

contains a HAP, or is a HAP 

precursor) in 1996 Sand 16.7987 

~a~.~ ~a23~ J White Kaolin 8.3993 

Yellow Iron 

:

- ~'h Oxide .1680 

- ":a{-..:::K..•'}`." ;_y~:.y~-~ ___ a.-!w 

- - .: ~,.~~

..::.LL~- '

';+r~

"-f.C ~ :: .. ;.5x.~.yd,£,._..,...-:_. ~•. - ' 

~t^•yc 

. ...a:..,. +a,.e . 

a 

. .w. .. ~:-': T•' . .: ~ ' - _ ~ ~ 

k'!r' ' ~~,„-,"h..0 ~'~Y.'.w'_•,`~,+yti..r . ' . .. . . . .. . . -_,y-:y 

- _._..e+'1~

..",•_a"'°... -.-.. . ' '-- _i_ 

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Page 6 of 28 

kl 
T.A.BLE l. CONSUMPTION AND HAP CO-ktPOSrrrn ~ nF r-:r e7~ c erM f-nT nn A,.ITn 

Type (e.g., glaze, colorant) EXANEPLE_- 

GIaZe = Glaze 

Type of product glazed or Structura.i tile - Glazed Tile colored = 

. _ . _.._.. 

--- -- - - 

1996 consumption (tons/yr) 

8.91 

-- - - ~~ , 

Produced at facility? (yes/no) ~~. ~ ~ i.. 

`-, ye~;.=~- 

Yes 

Production capacity (tons/yr) 

267 

Total usage (weight) of each Total 1996 

in ~ 

dient that is a HAP, ( ~ _ _ ~" : `~° ~'~ Ingredient . usage, tons 

: 

_ 

contains a HAP, or is a HAP ~~, ... ,Y ~, 

precursor) in 1996 ~''~"~ 

.: _ _ ... .. 

~ CM-932 1.98 

-.. ~ 

CM-933 2.91 

~~~,,.R. F ~„ . - ~ CM-935 1.03 

~ -:.: - -• ~::.r- - = ~.:~,~ - 

CM-937 1.08 

. .. : sa-..•rqA 

~_ z.Y~- ' Frit 3134-2 0.402 

~ . 

Frit CC261-2 

- 

0.402 

EPK Kaolin 0.153 

.. _._, 

:..~. - -~ 

:..~

. . . 

' :~ Superpax 0.559 

Rutile 0.079 

6y . 

•. . y~,._ . 

~• 

~ycS~c/ Cobalt Oxide 0.022 

71 Chrome Oxide 0.02 

Chear Cogp 75 0.031 

Red Iro ~.,. Oxide 0.031 

,r,= .,,.... - , ~ Continued Next Page 

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Page 6 of 28 

%~j 
Tr1BLE 1. CONSUMP'ITON AI`ID HAP CONIPOSITIO` OF GLAZESANTD C'nr nR e u-rc 

Type (e-g., glaze, colorant) EXAMpI,E: 

GI3Ze - Glaze 

T e of roduct Q aZed or yP F ~ Structural tile - __ -- ~ - ~~r: Continued from previous 

colored page 

~ . .. . . ... • __ ' .-. ' .__ - _ __ ~L~ 

1996 consumpaon (tons/yr) -~ 

~ 

~~.=_'~ 

Produced at facility? (yes/no) ~~..~~ ~ - Z 

Production capacity (tons/yr) 

Total usage (weight) of each 

....r.....: .: . ,...~. 

~~,,~ ` 

-..... 

~a~~ Tota11996 

in~edient (that is a HAP, ~,.~~ e;~ 

-.~:_: 

a~ ~ Ingredient usage, tons 

contains a HAP or s a HA.P i - . 

' 

~~~~~ 

= ~y```~ - Zinc Oxide 0.023 precursor) in 1996 

Brickox 0.073 

~+ Pigment C-292 0.002 

Pigment C-416 0.005 

_ _ Pi ent C-790 0.022 

.. - _ _.. -:.---.•„- _: ~ - :,~:.; ~-~_,= 

Pigment C-892 0.014 .. ...F. :,. - 

Pigment C-1802 0.05 

.. ^•.r -. Pigment F-3794 0.022 

_:~^~."-~

,,._•

;

.'•— , _..r-""- 

~•~::,: ~ -n-,.~.~~,~--~~-.,-_ '~—'' . - n:.~, Y +•.. ~; . _~ ~ ,.. ~ . 

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Page 6 of 28 

~ 

k~ 
Material Safetv Data Sheet 

Substance Identification 

Identity: IRON CHROMITE C.kS 1: 1308-38-9 

Trade Names: CHROMOX 

Manufacturer: The Prince Manufacturing Company Emergenc;r. Chemtrec 

One Prince Plaza 1-800-424-930 0 

Quincy, IL 62301 _ 

217-~?'~ -8854 

Components and Contaminants 

Cheniical Narne CAS # OSHA PEL A.CGIH TLV Pe-rcent 

Chromium Cr' 3 7440-47-3 0.5 mg/m' 0.5 mg/m3(TWA) 30-454'o Cr 

Silica, Crystslline Quartz respirable dust 14808-60-7 0.1 mg/m' 0.1 mg/m' (TWA) 1?Ci'o Si02 

Physical Data 

Boiling Point: NA Specific Graviry (H20=1): 4.4 

Vapor Pressure (mm/Hg): NA Melting Point: 3350 - 4C00° F 

Vapor Deasity (Air=1): NA Evaporation Rate (Butyl Acetate=l): NA 

Solubilitv in 'Water: insoluble 

Appearance and Odor: black powder, no odor. 

Fire and ExpIosion Hazard Data 

Flash Point: Not combustibie 

Flammable Limits: LEL NA L-EL NA 

Extinguishing tifedia: Foam, CO,, or dry chemical or water. 

Specal Fire Fghting Procedures: In the event of fu-e, wear full protec^ve clothing and NIOSH-aoproved se'.fcontained breathing apparatus with fu11 face piece operated in the pressure 

demand or other positive pressure mode. 

Unusual Fire and explosion hazards: Not combustible. 

Reactivity Data 

Stabiiiry: Stable under ordinary conditions of use and storage. 

Conditions to avoid: None Know- a 

Incompatibiliry (mate:ials to avoid): None Kaown. 

Hazardous Decomposirioa or Byproducts: None Known. 

Hazardous Polvmerizarion: Will not occur. 

Health Hazard Data 

Route oE Entrr. INHALATION: Ivfay cause delayed respiratory disease if dust is inhaled over a 

prolonged period of time. 

S FtIN: No. 

INGESTION: Ingestion of Iron Chromite may cause abdominal pain and 

na usea. 

Iron Chromice, Page 1 

April 1991 kv 
Health Hazard Data (<onr.) 

Health Hazards (Acute and Chronic): Respiratory disease mav result from protonged overexposure. Can cause eyc. 

irritation. 

Csrcinoge:.icity: NTP: ho LyRC Monographs: Yes (Silica) 

Sigr:s and S,~r..ptoms of E.~osure: Excessive ir.halacion of dust aav result in shortness of breath and reduced pulmonary function. S,---otoms of silicosis include impaired pulmonary functioa 

and wheezng. 

Aggavation of Pre-e:.sting Conditions: Persons with impair ed respiratory function may be more susceptiole to the effecc of this substance. 

Ezergency and rtrst Aid Procedures: IF INHALED, re^iove to fresh air and seek medical attention for any breathing 

diificultv. 

Iti CASE OF SI:IN CONTACT, wash with soap 8c water. Seek medical attentioa if red 3t irritated. 

IN CASE OF EYE COVTACT, tlush eyes immediately with water for at least 

15 minutes. Seek medical attention if irritatioa persists. 

IF' INGESTED, induce vomiting i-mr-nediately by giving two glasses of water 

and sticking finger do ~arn t;Lroat. Never give anything by mouth to an'unconscious person. CaII a physic:an immediately. 

Precautions for Safe Handling and Use 

'N,faterial Reieas:, or SpiIl Precautions: Should a saill occur, ventiiate area. Clean-up personnel require respiratory 

protection. Recove.-unconta:^inat_d material for use. Vacuum or s•,Weep 

remainin; nlaterial, keeoinz dust to a minimum. 

w'aste Disposai 1 ~ fethod: Dispose of unreciaimabie mate:ial in a RCRA-approved wasce FaciIity. 

I-iandling and Storing Precautions: Protec: containers from da,^age asld'.{eep closed when not in use. 

Other Precautions: Observe aood persor.al hl,•cene. Wash after handlinv. 

Control '.Measures 

Respiratory Protection: Lse NIOSH approved par:ic::iace respirator if dust generation occurs or is 

anticipated. OSi-i.-k standard i910.1.4 or ANSI Z88?-1980 specifications are 

recommended. 

Ventilation: A system of local and / or ?eneral e:.haust is recommended to keep employee 

_ exposures below the ?.irborne Exposure Limits. Local ex:zaust is generallv 

preferred because it c:n control the emissions of the contaminant at its source, 

preventing dispersion of it into the general work area. Please refer to the 

ACGIH document, "I :dustr:al Ventiiation, A Manual of Recommended Practices", most recent edition, for detaiLs. 

Protective Gloves: YeS 

Eye Protection: Safety goggles are recommended. 

Other Protective Clothing or Equipmeat: Use other protective equipment when necessary in order to avoid prolonged 

exposure to skin. 

Work and Hygienic Practices: Observe good personal hygiene. Wash after handling. 

SARA Titie III Section 313 Supplier Notification 

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emerge .c;r 

Planning and Communiry Right-to Know Act of 1986 and of :0 CPR 372.45: 

Comoonent CAS * % bv Weight 

Iron Chromite 1308-38-9 30 - 3517o Cr 

This ir.formation must be inciuded in all ~iSDS's that are copie.~. a:.d distributed for this mate:ial. 

fron ehramite, Page 2 

April 1991 

. ~~/ 
Material Safety Data Sheet 

Substance Identification 

.dentity: MANGANESE DIOXIDE Cas #: 13 13-13-9 

Trade Names: Erickox, GranuSpeck 

Manufacturer: The Prince Manufacturing Co. Emercer.cy: Che:n;trec 

Or,e Prince Plaza 1-ECO-424-9300 

Quincy, IL 62301 

217-222-8854 

Components and Contaminants 

Chemical Name: CAS # OSHA PEL ACGIH TLV P rc n 

h:langanese Compound ( as Mn) 7439-96-5 5 mg/m' (C) 5 ma/m' (C) 51-55% Mn 

Iron Oxide 1309-37-1 -- — 1-5'/o Fe ZO, 

Silica, Crystalline Quartz (res,oirable) 14508-60-7 0.1 mg/m' 0.1 mc/m' (TvV„) 1-5'/o SiO Z 

r.luminum Oxide (non- fibrous) 

(respirable fraction) 1344-28-1 5 mc/m3 5 mg/m3(TVi„) 1-7% Al203 

Barium Oxide 1304-28-5 = ---= 0.2-2% Ba0 

Physical Data 

Boiling Point: NA Specific Gravity (H 2O=1): 5.0 

Vapor Pressure (mmlHg): NA Melting Point: 535 1 0 

Vapor Density (Air=I): NA Evaporation Rate (Butyl Acetate=l): NA 

Solubility in Water: insoluble 

Aopearance and Odor: black to brownish black, no odor 

Fire and Explosion Hazard Data 

r"lash Point: Not combusticle 

'lammabie Limits: LEL NA UEL NA 

Extinguishing Media: Feam, COz , dryche^ic2l crvr2t=r. 

Special Fire Fightinc Proc2dures: In the event of tire, we=_r full rrot-=ctive clotnine and NIOSn-approved 

- seli-contained breat"nir,c azcara:'.:s :'Ji'u1 fL'll face piece operated in the 

pressure derr.and cr ot`!er positive pressure mcde. 

Unusual Fire ar.d explosicn hazards: Ne; ccmbustibie, but substance is a sttor;c _xidiz=r and its heat of 

' reacticn with re.^.l:C;r ~ C a_=enlj Gr C.^.ri iDLSi(CicS rr~ ay CaUse iCniiion. 

lnCreases th e flaRima:.il!CV cf anV C^.rlbUSi:^i? subsiance. 

Reactivity Da+.a 

Stabiiity: Stable undar crcir.a-;i ccndiaens cf use anc storace. 

Conditions to avoid: Dc nct heat cr erirc in t;~ e ?res= :Ce of easiiy oxidizable substances o - 

cry=.nic rnat:sr. 

Incompatibility (materials to avoid): Easily oxidiz='- le s::ttst=::ce.s, sulfur, sulfides, phos:,hides, 

hycrophcsphides, c ~ ,Icra:es, peroxides, al',:rninum powder, rubidium 

acetjIlde, pGtasSil: ~~ azt..=, GIlcrin= triiuC ~, ,4 e. Reacts wltil 

hydrochleric acid tc fcrm ccrrosive chlorine ;as. 

Hazardous Decompesitien or Byproducts: Ucon he.airc it d=c:.mroses to :`crm rnancanese sesquioxide and 

oxyeen whic^ facilita:es ..cr:,usticn. 

Hazardous Polvmerizaticn: WiII not occur. 

Health Hazard Data 

Poute of Entry: INHALATIONL Ma;i irrita.e .',e ras ;:iratcry:ract. k1ay increase the 

ir,cicence cf uc;.er En°ec:ions (pre'.:monia). Prolonged 

exnosure to Siiica c a; --.ay resu`t in siiicosis, a r!brotic lurg dise2se. 

SKIN: May ca.'.:s ~ 

INGESTION: P•,1ay ca°.:s= a'--dornir,al pain and nausea. Manganese 

dioxide dust is pccr;y a'bscrbed thrcuch the gut. 

Manganese Dioxide, 

:clv 1996 Unchanged sir,ce J! I i•- 

~~ 
Health Hazard Data 

Health Hazards (Acute and Chronic): Chronic exposure and inhalat:on cf excessive manganese dust may cause 

cisorders of the central nervous sys:em. 

Carcinogenicity: NTP: No 1,=,RC Moncgraphs: Yes (Silica) 

Signs and Symptoms of Exposure: Early symptoms of manca,nese tox:c:ty irc'.ude sluggishness, sleepiness, 

and weakness in le:s. SympteMs cf siliccsis include impaired pulmonary 

function and wheezinc. 

Aggravation of Pre-existing Conditions: Persens with imp2ire --4respira:crf'ur ~ c:icn may be more susceptible to the 

e~ ~ect of this substance. 

Emergency and First Aid Procedures: IF INHALED, remove to fresh air anc see'.< medical at:ention for any 

breathing dif iculty. 

IN CASE OF SKIN CONTACT, was; ,, with soap & water. Seek medical 

attention if red & irritated. 

IN CASE OF EYE CONTACT, fiush eyes immediately with water for at least 

15 minutes. Seek mecical attention if irritation persists. 

IF INGESTED, induce vcmitina immeciate:y by giving two glasses of water 

and sticking finger dcwn throat. Never give anything by mouth to an 

unconsc;ous person. Call a physician! im,;,ediate!y. 

Precautions for Safe Handling and Use 

Material Release or Spill Precautions: Should a spill occur, ver,tilate area. C(e=_n- :p personne! require respiratory 

protection. Recover uncontamir,ate ~ matEria! for use. Vacuum or sweep 

remaining material, keepina dust to a mini,;,um. Isclate wet material from 

driard store away frcn ccmbustible materials. - Waste Disposal Nlethod: Dispese of unreclaimable material in a RCRA-_pproved waste facility. 

Handling and Storing Precautions: Manganese cioxide is ciassiTled as an oxiciz=-r and should be stored in a 

dry place away from combusit!bes and scurces of hieh heat. Protect 

, contair,ers from dama;e and ke_o cicsed vihen not in use. 

Other Precautions: Observe gocd personai hvcie^e ~':a_h a- er handlinc. 

Control MeasuresRespiratory Protection: Use NIOSi-i approved paric Jla:e rspira;cr i; c at ge^era'tion occurs or is 

anticipated. OSHA star,dard 1910.1'34 er A.NSi Z83.2-1980 specifications 

are recommended. 

Ventilation: - A system of local and/cr cenera! ex ~ a:;st is recommended to keep 

employee exposures be!ow the ExPcsure Limits. Local exhaust is 

cenerally preferred because it can t=e e:-nissions of the contaminant 

at its source, preventing cispersion c' it general work area. Please 

refer to the ACGIH doc::r-;e.^.t, "IncL:s:rial Ventilation, A Manual of 

Recommended Practic:.s", r;rnost recent edit'.en, for details. 

Protective Gloves: Yes 

Eye Protection: Safety goggles are recommende ,-J. 

Other Protective Clothing or Equipment: Use cther protective e;.:ipment •ri; -^,e-, necessar/ in order to avoid 

prcicnged exposure to skin. 

'Nork and Hygienic Practices: Observe good Dersonal hygiene. Wash after handlinc_. 

SAR.A Title III Section 313 Supplier Notifcation 

-nis crecuct c ~ ntair,s the °cilowing t.xic chemlcais sL'biect to the reperir,g re ~ .ir ~ r -^ts c: s_cticn 313 of the EmerSency 

?!annina and Ccrnmunitv Riaht-to-Kr ~ ow Act of 1986 and of 40 CFR 372.45: 

~ omQoner, CAS ;T °/, bv 'Neiaht 

.tancanese Dioxide 1313-13-9 51-55','o Mn 

3arium Oxide 1304-28-5 0.1-1.0°% 6a 

7 nis inrermation must be included in all MSDS's that are copied and cistributec' fcr t`is ma:=rial. 

.`, l:uioancsc Dio.cidc. 2 

Revie••vc: J::iv 1996 l.'nchanged sinc; Julv 1996 ~/~ 
t E r-s c3 T4-- c I-ti r-: i Sa a " ci 4pI 4--- d r o r-r S.i 1 i c ~ 

F' .O. Bo;: 177, Walnut & Jaci:son Streets 

Wedron, Illinois 60557 

Phone 1-E00-47.5-7856 

MF~ TER I AL SAFETY DATA SHEET 

Date; January 25, 1994, Supersedes October 26, 199-= 

_ - F''FiODUGT I DENT I F I GAT I QN 

TRADE NAME AS LAgELLED: Silica or Lak.e Sand. A11 Grades. 

CHEMICAL NAME & FORMULA: Silica, mainly in the form of Quartz. 

Si0^ 

I I _ HAZARDOUS I NGFREI? I EiVTS 

CAS Number Chemical Name Percent AC6IH-TLV OSi-IA-PEL 

14e08-60-7 Quartz ?90 0.1 mg/m3 0.1 mg/m3' 

Remaining composition of material is naturally occuring, nonhaaardous minerals. 

NIOSH recommends a Permissible Exposure Limit (PEL) of 0.05 mg/m.= 

respirable f ree silica. 

, _= 2 ~ F~HYE I GAL ~RGP'ERT I ES 

' Vapor density: Not Applicable Melting Point: 1710 C 

Specific Gravity: 22 .65 Boiling Point: 2230 C Solubility in 

Water: Insoluble Evaporation Rate: None Vapor Pressure: lOmm 

@ 1730 C Appearance and Odor: White to tan sand. 

Odorless. 

_NJ _ F I F2E AND EX PLOS I QRi 

Flash Point: Does not flash. Autoignition Temperature: None. 

Flammable Limits in Air: None. Lower: 

Upper: 

Fire Extinguishing Materials: Non Combustible. May by used to 

e:atinguish fires. Water Spray:_ Carbon Dioxide:_ Foam:_ 

Dry Chemical: Other:_ 

Unusual Fire Fighting Procedures: None. Unusual Fire and 

Explosion Haaards: None. 

V_ HEALTH HA Z AFRD I NFOFRMAT I QN 

Sy®ptoms of Overexposure: 

Inhaled: Shortness of Preath, coughing, reduced pulmonary 

function. 

Page 1 of .= 

Fy~' 
~~ ■ \ ~ \~~ ~ ■\ ■ ~ ~ •- • - _ 

~Y~ ► l 1 ~~Y~ ■ 

Contact Witt-h Eyes or Skin: Eye irritation. 

Swallowed: May cause gastrointestinal discomfort. 

First Aid: (Emergency Procedures). 

Eye Contact: Wash with water for at least fifteen (15) minutes. 

If irritation or redness persists see a physician. 

Skin Contact: Wash with soap and water. If irritation persists 

see a physician. 

Inhaled: Remove to fresh air at once. Apply ar_tificial 

respiration if in breathing difficulties. 

Swallowed: Give one or two glasses of water. If discomfort 

persists see a physician. 

Suspected Cancer Agent? Yes Federal OSHA Ua NTPYes IARC 

Ye= 

NTP: Respirable Crystalline Silica has been listed in the 6th 

Annual Report on Carcinogens. 

IARC: Monographs on the Evaluation of the Carcinogenic Risk of 

Chemicals to Humans (vol. 42, 1997) concludes that there is 

limited evidence for the carcinogenicity of crystalline silica to 

e::perimental animals, and there is limited evidence of 

carcinogenicity of crystalline silica to humans. 

,^ V I _ F2EACT = V I TY DATA 

Stability: Stable Unstable 

Incompatibility (materials to avoid): CIF3, MnF3, OF2 

~ Hazardous Polymerization: May Occur. _X,X_Will Not Occur. 

Hazardous Decomposition Products: None 

LL ? ILEA1< F=kIVI} D I SPQSAL 

P'RQCEDURES 

Spill Response Procedures (includs°_,; employee protection 

measures): Clean up using approved du. ;ess methods (water or 

vacuum) to minimize generation of respira!:rle silica particles. 

Waste Disposal: Dispose of in facility approved for silica. 

SPEC I AL HANDL. I NG 

= NFOF2C'1AT I OhJ 

Ventilation and Engineering Controls: Local mechanical to reduce 

respirable silica to below safe levels. 

Respiratory Protection (type): Use NIOSH approved equipment. 

Positive pressure supplied-air type recommended. 

Eye Protection (type): Safety glasses. Gloves (specify 

material): Not normally required. 

Other Protective Clothing and Equipment: Not normally required. 

Work Practices, Hygienic Practices: Clean up spills promptly. 

Do not engage in activities that will generate respirable silica 

particles. 

Page 2 '>f - 

~ 
Other Handling and Storage Requirements: Avoid generating dust. 

No special storage requirements. Train all e:posed persons in 

all Gections of this M.S.D.S. and the proper handling of silica 

before they worF: with this product. 

See OSHA Hazard Communication Rule CFR 1910.1200 9 1915.99, 

1917.2B. 1928.21, state, local worker, or community "right to 

know" laws and regulations. We recommend that smoking be 

prohibited in all areas where respirators must be used. Warn 

your employees (and you customer users in case of resale) by 

posting and other means of the hazard and OSHA precautions to be 

used. Provide training about the OSHA precautions. 

_ }f _ QTHEF:Z = NFOF2MAT 2 ON 

H.M.I.S. Rating 

Health Hazard Rating 1* 

Flammability Hazard Rating O 

Reactivity Hazard Rating O 

Personal Protective Equipment E** 

*- Chronic exposure to respirable size silica will result in 

silicosis. 

**- Comply with special OSHA respiratory protection if 

sandblasting. 

D.O.T. - Not regulated. 

SARA TITLE III - Not listed. 

Prepared by: Edward Clements 

Page :1 of 3 

.' 

m 
(D5 '20 ,i-C-O j5! 23 TAft CE«r`t'IP:S jllr:, 715 <°S 3gc6 F, G?2 

MATERIAL SAFETY UATA SHEET 

;r+n~ Mfe Tomarou . foley' 

!~ i, Y Y' i+•rif.'i ^ X,u . . ,y..- T' i ~ ~ lO ^{ j.: . ~1 •;] t i 

'

'u. ~~L' N.•. '* ~ ~ _r._.. ~•~

.y tii 

1.tAt1Vr,lCi U`ir1FR "I HA61E 

TAM C E fIAM(CS, iNCUfiPqRAi'ED _ 

~ inctr An0AES5 — ^ CIT'f. ~ IAt`! 

B OX C,B RiDGE S[ATIO N 

—77DuCT ! CCC* 1.0, tttap f H ~ +! 

C:Pr•amic (7paclfier ( . 51ti15 jSuperpax 

vArQ 

5/14/90 

NIAGARA f=ALLS, NY. 14305 

~9:4-0 ~

.~

71812 4 

PERCZrNT OSHA TWA AC(?IH VAPOA pftESS41FtE 

1NaFiEDIENT CAS / sT WElOHT PEL TLV LEL X mmHo4 Qd•F 

2ircotiium Slllcate ~~ 1 a9U0-68-Z 93 5 my /rt, 5 mglm 3 N/Il N%A 

t2espi - able CZuartz 1 fi809-6f?-7 7 N JA N/A 

(1) As messut - ed by NIUSH requimtions vfi 

Crystallm,Sillca - see hand book of 

T QX I C &b;1z;vrdQws_ chami ~;al.s 

Roau4o 

0 ! A 

YaI.ArILE WEtd1AT 8P£CJFfC 

VAPOA ,'JEtJ81TY EVAP4Ftr1TtON nATE _ dY VOLUM£ PER aALLC?H 

N/A 

- GRAYt1Y 

❑ 11EAVtNF~ ALD LIGHIEtl THAN Af ~1 ❑ rA,BTENRlA❑ 8LC}WER THAN ETHER N/A 4. 5 

txor C.tTtcaR'r 

Nnl Re g atstt ul i 

F.xT1Ha1JlaM1H4 Ia601A 

S.~ WATER•F04 4-~ FUAM 

1.29 CA RBON DIOXIDE®_ DRY C 

VtiulRUAI. f1n[ AHp f.YCt.Of1OH ftALAAO! 

Nane 

B•tS), At rIPIE i+0+lsfNa ri3OCHOVnG7 

Nofle 

❑ OtHEIi 

n 

LEI. 

IA 

IjiAJJIIITY 

❑_Utf31A8LE U 8TA6L7s 

ir,rOrwnATAE' ~_iTr 

tiOfle. tuatEs•rAt! 10 xVOfM 

CONObTM7Ft3 TO AvOIp 

Nofle 

r.V.nO'7V5 C`E'-Ou n pSir i pr4 n^qp'JG*S N(Jrlf; ~/ 
.—:•1 r a ~ , •t jrr 

RCUIEn 0 0E!nRr 

Ir ~ CL*st(arT,_ j rTiialatiQri arid cntitact 

rAn rY 

1J1 RC lzas classifiedc~ stallin e Sllfca_es a_prnbahh lY c~rc~~1~e i~c fc~ r hum~ a~ 

^lTF.0 ► 0 ertxras nE ~ _ 

J F~oss~~~~a! ~ ung Yrritatiori from Crystalllnr! 5111ca. Long terTSr expostrre ta crystaltlnb slflca ca 

ctTuse prieumocosiosis. Symptoms Inclucie eoughing, wtTeezfhg, tiyspnea, and IrnpairIl6d 

put ndnary functloris. 

Cht-nr 4c fieaitlt effects: CrystalllnA Sillcs has bpen classified by IARC es a probabiy carc:fimger7 tc for hurnarTs. CrystAlilne Sillca ls "a'Iso a known catrse of Silicosls, a non cencerbus 

lusty disEasP caused by excessive exposure to Cryntallln ~ Si11Ga. 

1uEn0Er,cY A+rp rmsr Arp pna:eouni; 

t>•rs: Noruta+ washing to remova' dust 

s><, ,: Normal wastTing to remove duat 

Ir+r+ALAt , Q++: Remove to trQsll air 

INOE4frorl. Ca1) a physician 

SECTIONY11~ $piL ~ L L AK PF~ OCEDURES 

,. 

{Ttlyd TO t! . TAKEN u+ CA:•,E M t2pIAL la qEllASlD OA BPILLEO ~ 

Normal tirecautiortis for rwisanv;a, duist sirovld be observad. 

Avoid prolonged InITalation of dustr 

wKBtE b18P0PL METH00 

Diepose of (n accordaricp with Local, State artid federai regulatiohs. 

SECTIQN Vtli= spECIAU PaOrEC-rroN IN1rv.RMA-rIQN:+~ 

+ RE3 ~ i4Atprty Pf10tfC1tOH 

Where 7 LV is exceeded, use of mn approved dust respirbtor is recommerided, 

YiHTtIATiOH 

~ Provide as reauired to keep TLV below acceptab{e iimits. 

Pr,oTFC!rYl: rrloY5s None 

Er}rnnrtCilON Normal protection against foreign substances as naec3ed-sarety giasses. 

oTNrar•rorr.cTlo++eov+eveM* None 

 PA ~ CAUT14: ~

: . .,. ~#~. ~`~•~;. . ~ . ,r;y 

_ i 

in6cAU1 i0H8 10 >!d TP Ksrr Ir+ -r1+0ttrrG AHb llioarrro 

orrTTal precautions ror "nulsanca dust" shoufd be provided. 

( 

01)4•n PnacAu , raras 

' DIyCI AIMER OF LIAtiILITY r A A ~ qrRr'+ Cs I^c, ,artnal lnlfcipele 111 o0ntlrtlon! Undar whlCt ~ Ihls Intormetlon and our prtxfunlf, Or trM OrdluCtO 01 o1hOr 

m■ nu{nr.tuMrf In Cnmblra+ on -Ith eW producl , mAy ba uead. w& do nol 039Ume any 1969OnllbllllY ar,d sitprelely tll.teiaim Iny 11 1bllitr tot J,ny vts al U•e 

rn~~~ nal, InlprieA110n ~~~ ~ +^ed h„re ~ n r>t balle.e ~ to bs Irue end eccvrb(a , bUt ati Slat4r* ~ CnIR or ttvqpa; nnnt ar• rnn-14 wllt+out anr werranty, erpreaa o•lmalle , 

--• -- •.. ~ •...d ~ 

nnnnr,elM wllh lhp Ue* oI lrir, n1Itr.r;J11 or Iha rarulls to bo- obtalned t+om tna utt rhefeor. ~~ 
Material Safety Data Sheet 

Substance Identification - 

Identity. SYNTHETIC RED IRON OXIDE CAS #: 1309-37-1 

Trade Names: 

Manufacturer: The Prince Manufacturing Company Emergency: Chemtrec 

One Prince Plaza 1-800-424-9300 

Quinry, IL 62301 

217-222-8854 

Components and Contaminants 

Chemical Name CAS # OSHA PEL ACGIH TLV Percent 

Iron Oxide 1309-37-1 --- --- 80-95% Fe203 

Particles not otherwise Regulated 

Total 15 mg/m3 15 mg/m3(TWA) 

Respirable Fraction 5 mg/m3 5 mg/m3(TWA) 

Physical Data . -. 

Boiling Point: NA Specific Gravity (H20 =1).: 4.8 - 53 

Vapor Pressure (mm/Hg): NA Melting Point:-. > 1700° C 

Vapor Density (Air =1): NA Evaporation Rate (Butyl Acetate =1): NA 

Solubility in Water. . insoluble ~ 

Appearance and Odor. red to reddish-brown powder, no odor. 

Fire and Explosion Hazard Data 

~ Flash Point: Not combustible 

~ Flammable Limits: LEL NA UEL NA 

F_xtinguishing Media: Foam, CO., or dry chemical or water. 

Special F'ire Fighting Procedures: In the event of Pire, wear full protective clothing and MOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure 

demand or other positive pressure mode. 

Unusual Fire and explosion hazards: Not combustible. 

Reactivity Data 

Stability: Stable under ordinary conditions of use and storage. 

Conditions to avoid: None Known 

Incompatibility (materials to avoid): Aluminum, Ethylene Oxide, Hydrazine, Calcium Hypochlorite, Performic 

Acid, Bromine Pentatlouride. 

Hazardous Decomposition or Byproducts: None Known. 

Hazardous Polymerization: Will not occur. __ _ 

Health Hazard Data 

Route of Entry: INHALATION: May cause irritation of mucous membrane if dust is inhaled 

over a prolonged period of time. 

SKIN: No. 

INGESTION: Ingestion of mineral compounds may cause abdominal pain and 

nausea. 

Synthetic Red Iron O)dde, Page 1 

June 1991 

93 
Health Hazard Data (ront.) 

Health Hazards (Acute and Chronic): Can cause eye irritation. Injury to skin may occur by direct mechanical action. 

Carcinogenicity: NTP: No IARC Monographs: No 

Signs and Symptoms of Exposure: Excessive inhalation oF dust may result in shortness of breath and reduced pulmonary function. Iron oxide fume has been linked to siderosis which is considered to be a benign pneumoconiosis that e.rhibits no adverse health effects. To 

the best of our knowledge, this condition has not been observed after 

prolonged exposure. to iron oxide pigments. 

Aggravation of Pre-existing Conditions: None Known. 

Emergency and F'irst Aid Procedures: IF INHALED, remove to fresh air and seek medical attention for any breathing 

difficulty. 

IN CASE OF SKIN CO1V'TACT, wash with soap & water. Seek medical attention if red & irritated. 

IN CASE OF EYE CONTACT, flush eyes immediately with water for at least 

15 minutes. Seek medical attention if irritation persists. 

IF INGESTED, induce vomiting immediately by giving two glasses of water 

and sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

Precautions for Safe Handling and Use 

Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory 

protection. Recover uncontaminated material for use. Vacuum or sweep 

remaining material, keeping dust to a minimum. 

Waste Disposal Method: Dispose of unreclaimable material in a RCRA-approved waste facility. 

Handling and Storing Precautions: Protect containers from damage and keep closed when not in use. 

Other Precautions: Observe good personal hygiene. Wash after handling. 

, Control Measures 

Respiratory Protection: Use IVIOSH approved particulate respirator if dust generation occurs or is 

anticipated. OSHA standard 1910.134 or ANSI Z88.2-1980 specifications are 

recommended. ° 

Ventilation: A system of Iocal and / or general exhaust is recommended to keep employee 

- exposures below the Airborne Exposure Limits. Local exhaust is geaerally 

preferred because it can control the emissions of the contaminant at its source, 

preventing dispersion of it into the general work area. Please refer to the 

ACGIH document, "Industrial Ventilation, A Manual of Recommended PracProtective Gloves: — _ _ Yes 

tices", most recent edition, for details. , .. . ...-- 

Eye Protection: Safety goggles are recommended. 

Other Protective Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonged 

exposure to skin. 

Work and Hygienic Practices: Observe good personal hygiene. Wash after handling. 

SARA Title III Section 313 Supplier Notification 

This product does not contain toxic chemicals subject to the reporting requirements of sectioa 313 of the Emergency Planning and Community Right-to Kaow Act of 1986 and of 40 CFR 372.45. ---- 

This information must be included in all MSDS's that are copied and distn•buted for this material. 

Synthetic Red Iron Oxide, Page 2 

June 1991 ~ ~ 
Material Safety Data Sheet 

Substance Identification 

Identity: SYNTHETIC YELLOW IRON OXIDE CAS #: 51274-00-1 

Trade Names: Hydrated Iron Oxide 

Manufacturer: The Prince Manufacturing Company Emergency: Chemtrec 

One Prince Plaza 1-800-424-9300 

Quincy, II. 62301 

217-222-8854 

Components and Contaminants 

Chemical Name CAS # OSHA PEL ACGIH TLV Perc.ent 

Hydrated Iron Oxide 51274-00-1 --- — 80-95% Fe203 

Particles not otherwise Regulated 

Total 15 mg/m3 15 mg/m3(TWA) 

Respirable Fraction 5 mg/m3 5 mg/m3(TWA) 

Physical Data 

Boiling Point: NA Specif c Gravity (HZO =1): 4.8 - 53 

Vapor Pressure (mm/Hg): NA Melting Point: -_ > 1700° C 

Vapor Density (Air=1): NA ' Evaporation Rate (Butyl Acetate=l): NA 

Solubility in Water. insoluble ; 

Appearance and Odor: yellow powder, no odor. 

Fire and Explosion Hazard Data 

Flash Point: Not combustible 

Flammable Lim-its: LEL NA UEL NA 

Extinguishing Media: Foam, CO2, or dry chemical or water. 

Special Fire Fighting Procedures: In the event of fire, wear full protective clothing and NIOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure 

demand or other positive pressure mode. 

Unusual Fire and explosion hazards: Not combust>,ble. 

Reactivity Data 

Stability: Stable under ordinary conditions of use and storage. 

Conditions to avoid: Temperatures above 300° F can cause this product to become unstable and 

loose its water of hydration, converting it to red iron. 

Incompatibilitty (materials to avoid): Aluminum, Ethylene Oxide, Hydrazine, Calcium Hypochlorite, Performic 

Acid, Bromine Pentaflouride. 

Hazardous Decomposition or Byproducts: None Known. 

Hazardous Polymerization: WiIl not occur. 

Health Hazard Data - - 

Route of Entry: INHALATION: May cause irritation of mucous membrane if dust is inhaled 

over a prolonged period of time. 

S KIN: No. - - 

INGESTION: Ingestion of mineral compounds may cause abdominal pain and 

nausea. 

Synthetic Yellow Iron Oxide, Page 1 

June 1991 

f~ 
Health Hazard Data 

Health Hazards (Acute and Chronic): Can cause eye irritation. Injury to skin may occur by direct mechanical action. 

Carcinogenicity: NTP: No IARC Monographs: No 

Signs and Symptoms of Exposure: Excessive inhalation of dust may result in shortness of breath and reduced puImonary function. Iron oxidefumehas been linked to siderosis which is considered to be a benign pneumoconiosis that exhibits no adverse health effects. To 

the best of our knowledge, this condition has not been observed after 

prolonged exposure to iron oxide pigments. 

Aggravation of Pre-ex;sting Conditions: None Known. 

Emergency and First Aid Procedures: IF INHALED, remove to fresh air and seek medical attention for any breathing 

diff culty. 

IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. 

U- I CASE OF EYE CONTACT, flush eyes immediately with water for at least 

15 minutes. Seek medical attention if irritation persists. 

IF INGESTED, induce vomiting immediately by giving two glasses of water 

and sticking fmger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

Precautions for Safe Handling and Use 

Material Release or SpiIl Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory 

protection. Recover uncontaminated material for use. Vacuum or sweep 

remaining material, keeping dust to a mi*+in+ um. - 

Waste Disposal Method: Dispose of unreclaimable material in a RCRA-approved waste facflity. 

Handli.ng and Storing Precautions: Protect containers from damage and keep closed when not in use. 

Other Precautions: 

A 

Observe good personal hygiene. Wash aher handling. 

Control Measures 

Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or is 

- anticipated. OSHA standard 1910.134 or ANSI Z.88.2-1980 specifications are 

recommended. " 

Ventilation: A system of local and / or general exhaust is recommended to keep employee 

exposures below the Airborne Exposure Limits. Local exhaust is generally 

preferred because it can control the emissions of the contaminant at its source, 

preventing dispersion of it into the general work area. Please refer to the 

- ACGIH document, "Industrial VentiIation, A Manual of Recommended Prac- 

_ __ tices", most recent edition, for detaiLs. 

Protective Gloves: Yes 

Eye Protection: :- Safety goggles are recommended. 

Other Protective Clothi.ng or Equipment: Use other protective equipment when necessary in order to avoid prolonged 

exposure to skin. 

Work and Hygienic Practices: Observe good personal hygiene. Wash after handling. 

SARA Title III Section 313 Supplier Notification 

This product does ,nQt contain toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-to Know Act of 1986 and of 40 CFR 372.45. 

This information must be included in all MSDS's that are copied and distributed for this material. 

Synthetic Yelloav Iron Oxide, Page 2 

June 1991 

q~ 
02/05%98 THU 12: J1 F.3.T SP:1RT,1N MINERAL ~ 002 

Materiaf Safety 

~ Data Sheet 

LITHQSPAe (PULVERIZED) 

(uSq/Canada) 

Effective 04/12/91 

Replaces 09/09/88 

Page 1 of 8 

• :. .• 

I. PRODIN.T IDENrIFICATION 

~n~farf+.~r_ R-r. Corporation, Lithium Division Rern,lar T.le hnn ! 704-868-5300 

P.O. Box 795 

Bessesner City, NC 28016-0795 

UERWWY TEI FPN(~JF (AmamS 

rr.adP Na _: LIIIIOSPAR®, Gulverized Madi a11, ollartl3 303-595-9048 

Svr onu<„s; Mi xture of Potassi un Al urtri nosi 1 i cate and Sodi urn Chernt,rp,r,800-q24-9300 

Aluminosilicate 

(.heffical Formila: KZO.Al 203 .6Si02+ Na20.Ai 203 .6Si02fi Si02 I ifh_ ilrn oivision: 704-629-5361 

Chemi ca 1 Fami 1T S i 1 i cateS 

G.A.S. Nn.: ho applicable infornation available. 

CAnadi en prodW-Tl] No_ : None 1 isted. 

PrnduCt 15P• Industrial P4snufacturing 

II. HAZNtD LABE}_ STA7F7rENT Effective 09/08/88 

Replaces 11/01/85 

HFni7H ya7 RDc: PFC6ABLE CAaCMEN. May cause cancer on continuous exposure. Contains 

Quartz or Crystalline Silica, 

RESPIRATORY IRRI7AN7. Prolonged inhalation of airborne dust can produce scar 

t'.ssue in the lungs. The condition is not reversible. 

None. 

C_PECTAI FIpF F)S'~'TNCLPRXFfYIRF•None. Material is nor-carbustible. 

Ha,41TNC AND srrxzar'F- Oo not breathe dust and avoid getting in eyes. Keea container closeo. _ec 

with adequate ventilation. Drying and/or grindirg rrLy increase dustino 

hazards. Control dust 1evels in the wor4: place. 

✓ ~7 
02/05/98 THL' 12:32 FAX SPr1RTA.v 1[INTRkI. 

LITM05PAlM (PULVERIZID) 

(USA/Canada) 

Effective 04/12/91 

Page 2 of 8 

(a 003 

Exa-u Irmediateiy flush the eyes w9th plenty of water for at least fifteen minut¢s. If 

irritation occurs or persists, obtain medical attention. 

Tnhalation: R,emve to fresh air. If breathing is difficult, give oxygen. If irritation occurs and 

persists, obtain medical attention, 

III. INGREDIENTS 

TNGRFnIENr EXP_OSIRtF L7MfTS 

NatQri ai or 

C=nPn C. A . S . Nn _ W" -2EL- --Mda_ 

TU r)gta 

.STFL. Ca.iLin.Q TE1.H_ 

(OSHA) (AOGIH) (ACGIH) (OSHA) (OSF+A) 

Potassiun None 16 to 22 No Applicable informstion was found. 

Aluninosilicate 

Sodiian 1344-00-9 33 to 39 No Applicable information was found. 

Aluninosilicate 

aart.z 14808-50-7 45 10 rtg/m3~ 0.1 rtg/m3 No applicable 50ug/m3 

% SiO

? 

 +2 (respirable inform3tion 10 hr TWA 

(rssplrable dust) vas found. (respirable 

quartZ) free silica) 

IM«I>:NT_ APLiML TM nATA 

Matarial_ or 

C=nn CAnadian PTN 

Potassiun None listed. 

Al uml nosi 1 i cata 

5odium None listed, 

Aluminosilicate 

Quartz None listed. 

Sna ~ ie and RocrtQ -Spn _i c and Rou ? 

No available information vres found. 

No available inform3tion wis found. 

No available inform3tion ws found. 

q U7 
SPART:>y HI`'ERAL u_tK)SPAM (PULVERIZED) 

0004 ' 

(USA/Canada) 

Effective 04/12/91 

Page 3 of 8 

0 2-` 0 5/ 9 8 THi 12 : 3 2 FAX 

IV. PHYSICJAL b4TA ~ 

PHYST a STATF: Solid, ygpOR DFNSTTY_ Not applicable, 

Ai r = 1 

AePFagat!CF ArfD OQ']R: C>riorl ess, fine sand-1 i ke 

particle5. VAPM_PRFSC 1R ~ Not dppliCBble. 

ffiOR THFnHoi D: Not appl i aabl e. 

PATt TN. Pn NT: 1238 °C (2260 ° F) FREE77rY; PciNTl ~

WLnNG$ZINT@ 1238°C (2260°F) 

DFNSTTY Q- SPECTE 

GRAVITY - 

Ql: 

EVAPOPATTON _I 

~~: ~1 ~ : • 

Approxin ately 3 g/cc 

Not appiicable. 

Not appliceble. 

Not applicable. 

SQtiBILTTY TN WATFRr Insoluble- 

=k by wt. @ 25 °C (77°F) 

PH ( c ic)Sa Not applicable. 

nH (tar S urrv) Cd 25°C. Not applicable. 

V. FIRE. DWLOSION AND REACZZVTTY [34TA 

PHYSTCA1 . A7ARr - Non-canbusti • MZON.aL FTRF 981TF('TTON =F 704 

FLASH M .I _. - Fi re 

(Red) 0 

• uQ . C.. 2r - a: t - 

Healtn Reactivity 

(61ue) 0 (Yellow) 0 

FlA4-11nG1 c' L7MM; 7N TR - Upper: Not applicable. 

L"r: Not appl i cabl e. 

I 
02-05-98 THU 12:32 FAX SPART:LV HINERAL z oo; 

LtTHOSPARa (PULVERIZED) 

(USA/Canada) 

Effective 04/12/91 

Page 4 of 6 

V_ FZ OSION AND RFAfT7vrn ne.TA CONTTNLEn 

ECINGliSHiNC MML Any suitable for fire in surrounding area. 

SPEQT r FIRE FTj'rrt ,_PFIf1CFDUFI_F• Not appl icabl e. 

1 tM 1Sl lAf FI F& Q9P( ClSION HAZARI) S None . 

Nc ~am ic r77y& iSTTQM Pcam x= : , Not appl i cabl e. 

EXEjDSTaN ba,TA: Non-e.,glosive. 

SIIySI-rTymr m rE~TCAi ~nHBaCr s Not appl i cabl e. 

SENc IyI?1' TO C_TaTTC QiSO4ARK;F• Not applicahle. 

4TgPTIi"n': Stable. 

OLNOi3:Ld4S =TRr rTI ti1'~ INS'[ggTi TTY: None. 

INQCWA RTLTTV: None. 

OONOLTMr1S' (1F RFA('TTVTTY: Nane. 

NA7G,RrYi JS QFCCM3QSTTTCN pRC><Y 1Ct'S : Not App 1 i cabl e. 

C(YVOTTTC(VS CY]NTRTRLR'TW1 TD HA7_4Rfn1IS PQ( YMFRT7GTTaN: Does not polyTMri2e. 

VI. PROOIK.`T FIEAI.T}i MAZA32D INFOfS1ATI0N 

PR(1nLw'T HEBLV_F, fl76Rb: PFCBABLE CAARCINCGETI. May cause cancer on continuous exposure. 

RESPIRATORY IRRITANr. Prolonged inhalation of airbome dust can produce scar 

tissue in the lungs. Thls condition is not reversible. 

PftODL.r`T 2JS!2E I TMTTS: No information was found for product. See INGRmIENTS, Section III. 

pRQQW=ANIM HAZeRn TFSr nATA See INGREAIENI'S, Section III. 

Ran-F (S) 0F FXPO91R tiBZABQ PROM K`* Tox nnTA a_nd GFERFNCF 

Fyp nntP= M3y irritate the eyes. No anirral toxicology data 

sw . .0 Respirable particles of quartz 

are hazardous to inhale. 

availabte. 

No anirral LCso  toxi col ogy datl 

available. 

I 
02- 05/9 8 THL' 12 : 32 F:1.T SPART.AIv MIINERaL 

LIT-CSPAFi© (pULVERIZED) 

10006 

(USA/Canada) 

Effective 04/12/91 

Paoe 5 of 6 

: 

Possible irritation to the eyes. 

Respiratory irritant. Chronic lung damage, scar tissue development in lungs can occur if inhaled over 

an extended period of time. Follow TLV e)qosure limits, Section III. 

This preduct -contains >0.1% silica and is therefore classified as a probable carcinogen. The 

International Agency for Research on Cancer (IARC 42., 1997) has concluded that there is sufficient 

evidence for the carcinogenicity of crystaTline silica to experimental animals and limited evidence 

for the carcinogenicity to hunans. Based on this and OSliA requirements, this necessitates the 

classification of the product as a probable carcinogen. 

F~e: IRRediately flush the eyes with plenty of ~,rater for at least fifteen minutes. If 

irritation occurs or persists, obtain medical attention. 

Ichalxrinn: Rertvve to fresh air. If not breathing, give artificial respiration. Zf breathing is 

difficult, give o)Wgen. If irritation occurs and persists, obtain medical attention. 

c'_a rrino_enisitv: Material is a probable carzinogen. 

NTP Annual: Not listed. 

IARC hbnographs Crystalline silica is listed as a 

carcinogen to animals and there is 

limited evidence for the 

carcincgenicity to humans, Group 2A. 

OSHA 29 CFR Part 1910 Subpart Z: Not listed. 

ACGIM (Appendix A): -Not•listed. 

irri an v : Crystalline silica is a respiratory irritant per OSHA, ACGIH and NIOSH 

and Canadian 4hMI5. 

Senei ua ion : No inforttation available. 

Tara.oqPni .i v : No infonnation available. 

Mutaq ni i : No infonmtion available. 

TOXi col oqi rLa71,v, 

Cvnereistir PjMd,~! No information available. 

Cny PediSa1 Conditions ,o _narnllv 

Rernoni7%j ac_ eeing A,gqravated bv Fmosrrw: Prior existing lung or respiratory illness. 

/~ f 
02/05/98 THL 12:3 3 F_~ 

sPART:~v JfI`+'ER.AL 

(~ 007 

LITNMPAA© (PULVERIZEb) 

(USA/Canada) 

Effective 04/12/gl 

Page 6 of 8 

VII. O11iEA GOVERf hENtAi l ISTINGS 

cggg TjT S,i7?M 3137 This product does = contain any toxic chemicals subject to the reporting 

requiranents of Section 313 of Title III of the Superfund Amerxtnents and 

Reauihorization Act of 1986 (SAPA) and 40 CFR Parrt 372. 

jSCA; Listed. 

rFECIA• Not listed. 

gFGTIc"N 302 . Not 1 i sted, 

22&; Not listed. 

('alifornia Fre—floai ;on 6c; Not listed. 

['anarii en Cy}dyTl S ) 

Hm7ari Class D, Division 2, Subdivision A(Carcinoaen and Respirato•y Tract Sensitization) 

Qiec~loeure tiat - Silica is listed (1N). 

VIII. DISPOSALL. SPILi. OR LF.NC PROCEDi1RF5 

2MCPY 1RF Fcx2 RFl Eas' OR :pJI 1: Wet with tAHter to reduce dusting and col iect in a suitable container. 

wnSTE oT_po~p~ N~r~- Oispose of waste according to federal EPA, state and local regulations. 

IX. PER.SOtyAL PRdTEC7I0PJ INFOR4ATION 

VEMILAIIM REOtLiR,EMialLi Provide adequate ventilation to rtt3intain •below exposure lim;ts (Section III) 

for quartz. 

CP _TFI!: ?Ef1SCYdAI-P20=1CH~c7JTRMENT „

Bagniratnnr• Wear a NIOSH/hSHA approved respirator when adequate ventilation is not available. 

Fy2C , Safety glasses or goggles. 

rlo s. None. 

FflotwPar: No special type indicated. 

C1_o hino: No soecial type indicated. 

Qtben - None. 

M 
02- 05: 88 THL' 12: 33 FAX 

SPARTdN MINERkL 

L.IT}iJSPAF.a (PULVERIZEQ) 

ZoOa 

(USA/Canada) 

Effective 04/I2/91 

Page 7 of 9 

I 

X. VANDLING Afb STORAGE 

Do not breathe dust and avoid getting in eyes. 

Keep container closed. 

Use with adequate ventilation, 

Drying and/or grinding ngv lncrease dusting hazards. 

Control dust levels in the work place. 

XI- TR4NSPOR'TATION GATA 

DOT Prvper Shipping Nam: LITHJSPAO 

DOT Classi fi cation: None 

D(7f Label s : None 

COT Marking: LIT}idSPARP PULVEAIZED 

G>aT Pl acarti : Hone 

UN Number: None 

INCO Proper Shipping Narre; LI7HQSPAR® 

I1hCD Hazard C1as3ification: None 

IhKX3 Labels: LITHOSPAA©PULVERIZW 

IhM Marking: None 

7tsf ► Z Z au4- •..c 

Prrorm•u ione tr hr+ Tik¢n yp Transnorrar5nn• No special precautions, 

50 pound three-ply bags 

/0 
SPART:11'r iltINERaL 

C~ oog 

0 2/ 0 5,~ 9 8 'IHL~ 12 : 3 3 FAX • • 

LITF•lOSPAFi9 (PULVERIZED) r 

(U5:4/Canada) 

Effective 04/12/91 

Page a of a 

XII. CONTACT PERSON 

M;nager, Technical Services 

F7-C Corporation, Lithiun Division 

449 Pforth Cox Road 

P.O. 8ox 3925 

Gastonia, North Carolina 28054-0020 

~~ -.: • ~ 

Copyright 1992. R-C Corisoration, Lithiun Division, A11 Rights Reserved. 

LIT110SRAO is a tradwark of FK Carporation, LithiLn Division 
BLACR COBALT 0%IDB April 22, 1996 

CBRAMIC COLOR & CHBMICAL MFG. C0. 

MATBRIAL SAFBTY DATA SHBBT 

HAZARDOIIS IHGRBDIBNTS 

Hazardous Ingredients Calcul4t ~ d Compositi n C.A.S. No. PBL1-mg/ml TLy? m m3 

Oxide 86-93 1308-06-1 0.05 as Co 0.05 as Co 

j Coal

O t~ -Cobaltic 

`qbllfous, pxide, I Co0) 7-13 1307-96-6 0.05 as Cq 0.05 as Cp Nickel Oxide (Ni0) 0.1-1 1312-99-1 1 as Ni 1 as Ni 

PHYSICAL AND CHSMICAL DATA 

Black, odorless powder 98% of which passes through a 350 mesh sieve. 

S pec i fic So . in H20 In4redient Mol. wt. Gtavitv m.o. QC b.p. 1 ml 0 . n.~v. n.av 

Cq6 74.93 

4. 

6.45 1935 n.av. 0 

Ni0 74.71 6.67 1990 n.av. 0 

PHYSICAL HAZARDS 

None 

HBALTH HAZARDS3 Cobalto-Cobaltic Oxide 

LD 50 ORAL RAT > 5000 mq/kg 

Inhalation: Some wprkers en a g ed,lon -ter ~ p in the roduction of cobalt o ~ ides, S howed s Ym toms,of chr nic bronchi is. In ~ aIatipn ~~ pe~ imeDts shppw that cobalto-cobaltic oxide accumUl ~ated in the ~ ymph 

nodes o

j dogs suggesting it is tissue insoluble. 

Bye Contact: Chronic exosur ~ pf animal eyes to dusts of mineral containing both cobalt and arsenic has caused corieal inlury. 

Cobaltous Oxide: 

LD 5 0 oral rat 202 mg/kq 

Inhalation: Bxcessive concentraGions of airborne cobaltous oxide re sulted in,the develqpme4t of emph ema 

and neumoconiosis in hamsters., Some wo;k ~ rs en aggd 1 p nq -term in th rodUc ~ ion of cab~a~t oxid ~ s shpwed sym toms of,ch; Qnic br 4nchi ~ is. T ~ e inhala[io ~ of coba ~t~us oxide has not 

resulted in an in ~ reased incidence of malignant lung tumors in rodents. 

Bye Contact: Chronic exposurg pf animal eyes to dusts of minerals containing both cobalt and arsenic has 

caused corfleal inlury. 

Wounds: Cobaltous oxide has caused tumors at the site of injection in rodents. 

NICZBL 0%IDB 

LD 50 ORAL RAT >5000 mg/kg 

Inhalation: The National Toxicolo Pro ram,has li$t ? d n i ckel,oxide as reasonalb anticipdted to be a 

carcinoqen based on t ~ ro~uction of in ection it ~ tu ~ pors. Howevel, there is reasoq to 

believe that the compouni actu ~ ll teste ~ was a ~ asic nickel caXbonate, The Intern 4 tional 

A enc Y for Researc 4bn C ~ ncer IA~ C1 concluded,ther ~ w s sufficie t evidence that nicke l 

c ~m oUnds are arcino genic to humans. B idemiolo iGa lstud l es o~ w 4 rkers ex osed to nickel 

i

ow~ er and to ~ pst,and fume generated in ~ he, rpdp~ tion of pickel allo s and ~ f stainless 

teel have not indicated the presence of a si ~nificant respiratory can ~ er hazard. 

The inhalatin of nickel oxide has not resulted in an increased incidence of malignant lung 

tumors in ro5ents. 

Inhalation of nickel oxide at concentrations 50 times the PBL, produced pneumoconiosis in 

hamsters. 

Reeated int racheal instillation of nickel oxide produced an increased incidence of malignant 

luig tumors in rats. 

Wounds: Nickel oxide has caused tumors at the site of injection in rodents.s. 

Ingestion: The p.S.,National Institu e for Occu atipnal Safet an¢ Health (NIOSH) concluded that nickel 

an its inorganic compoun~ s are not pCarcinogenic w ~ en ingested. 

/0~ 
PRBCAUTIONS FOR SAF& S?ORAGS, HANDLING AND USB 

Do,not iphale. Ree p container closed wh ~ n not in,use V ntilation is normal jy re guired yh en,hand 1 in or 

using thi roduct to kee p exposure to airbo ~ ne nickel be ~ ow the ex osure limit If ventilation alpn ~ Gannot 

sp cbntro ~ ~ x osure, use NIQSE p rpved re sp irators s ~ l cted accord ~ng to OSHA 29 CFR 1910.134. Maintain the 

airborne conc ~ ntration of nicke ~ ~xide as 1Dw as possib ~ e. 

SPILL, LBA%, AHD DISPOSAL PROCBDIIRS 

Collect s ills b yet wee p in , Q r by,vacuumin with,th ,vacuum xtaust assin t hrough a high efficiency 

particula ~ e arre ~ ting ~ HBPA) ~ liter if the ex ~ aust is ~ ischarge ~ into t ~ e wor~place. 

Wear a p ro riat ~ NjOSH-a pproved ~ es irators if Gollection and d is osal of spills is likely to cause the 

concent ~at ~ on o. airbornp contamina ~ ts to exceed the exposure lim~ ts. 

Cobalt-containinq waste is normally co llected to recover nickel values. Should vaste disposal be deemed necessary follow BPA and local regulations. 

BMBRGBNCY AND FIRST AID PROCBDIIRBS 

Cleanse wounds thoroughly to remove any particles. 

SARA S6CTION 313 SUPPLIBg NOTIFICATION 

This roduct coDtains the followin g chemicalls) sub 1' g ct to th r s orting r quirements of Section 313 of the 

Bmerg ~ ncy Planning and Community Right-to-Rnow Act bf 1986 an~ o~ ~ 0 CFR 37 ~ . 

Cobalto- cobaltic,Oxide Cobaltous Qxide Nickel Oxide 

Refer to the Hazardous Ingredients section of this MSDS for the appropriate CAS numbers and the percent_by 

weight. 

CBRAMIC COLOR & CHBMICAL MFG. C0. 13th StPeet & 11th Avenue New Brighton, PA 15066 

412-846-4000 

Footnotes: 

1.OSHA Permissible SxDosure Limit 

2.Threshold Limit value of the American Conference of Governmental Industrial Hygienists, 

3.Describe ~ ~ossible health hazardS of th ~ ,product ~ u ~ l jed. T f pser ogerationS han e it to otber ~ hemical 

f orms, w e her as end p roducts, interme ietes or u ~ tive emissions, he possib ~ e h~ alth hazards o such 

forms must be determinEd by the user. 

1~ 
MATERIAL SAFETY DATA SHEET 

Issue Date: /1 / 

TO THE PURCHASER: This MSDS contains important environmental, safety 

information for your employees. Federal regulations require that this information 

be made available to them. If you resell this product, a copy of this MSDS should 

be given to the buyer. 

PRODUCT IDENTIFICATION: CM932 

(Corroon Name) Ferro Qlaze CM932 

DESCRIPTION: 

containing FRIT (TSCA Inventory CAS T 65997-18-4*) plus the following typical 

glaze raw materials. 

Silica (CAS 14808-60-7) Feldspar (CAS 68476-25-5) 

Electrolyte Alumina (CAS 1334-28-1) 

Wollastonite (CAS 1344-95-2) C1ay (CAS 1332-58-7) 

SECTION I 

MANUFACTURERS NAME: Ferro Corporation, Frit Division 

MAIL:4150 East 56th. Street HIP: 4150 East 56th. Street 

P.O. Box 6550 Cleveland, Ohio 44105 

Cieveiand, Ohio 44101 

TELEPHONE:Ferro 24 hour Informational number: (216) 641-5324 

Facility Informational number: (216) 641-8580 

SECTION IIa - HAZARDOUS COMPONENTS 

This glazp- mixture contains the following potentially hazardous substances 

referenced by Fed/OSHA in 29 CFR 1910.1200 : 

Exposure Limit (Air), mg/m3 

COMPONENT: CAS No A.CGIH/TLV FED-OSHA/PEL CAL-OSHA/PEL 

Aluminum oxide, as A1 1344-28-1 10. 1035. (r)10. 

Crystalline silica 14808-60-7 0.1 (a) (e) 0.1 (a) 

Zirconium ccmpounds, as Zr (b) 5.0 5.0 5.0 

Particulates not otherwise classified (b) 10/3 (r) 15. 10. 

(Total Dust) 

(b) Present as frit or any of the raw materials listed 

above. 

(e) 10/(2+%respirable quartz) 

(r) Respirable 

(a) Respirable quartz 

/D ~ 
PRODUCT IDENTIFICATION: CM932 

SECTION IIb - "SARA III" DATA 

This product contains the following component(s) that require reporting under Section 

313 of the Emerg;.ncy Planning and Community Right-To-Know Act, also known as Title 

III of the SARA (The Superfund Amendments and Reauthorization Act), and 40 CFR Part 

372: 

COMPONENT: CAS N. PERCENT PRESENT: ( a ) 

Zinc compounds (b) < 1.5°6 as Zn 

(a)The percent reported is based on the theoretical composition of this 

glaze mixture. 

(b) Only present as part of frit CAS # 66997-18-4* 

SECTION III - PHYSICAL DATA 

SPECIFIC GRAVITY (H20 = 1) 1. -.0 MELTING POINT (°F.) > 12 

VAPOR PRESSURE (T.m Hg) NXA BOILING POINT (°F.) NXA 

VAPOR DENSITY (Air = 1) NXA PERCENT VOLATILE NXA 

(by volume) 

SOLUBILITY IN WATER Ne4liqible EVAPORATION RATE NXA 

(butyl acetate = 1) 

APPEARANCE AND ODOR Off-white Qowder / Sliaht earthv odor 

SECTION IV - FIRE & EXPLOSION HAZAP.D DATA 

FLASH POINT: N/A FLAMMABLE LIMITS: N/A 

EXTINGUISHING MEDIA: None 

SPECIAL FIP,E FIGHTING PROCEDURES: None UNUSUAL FIRE & EXPLOSION HAZARDS: None 

SECTION V - REACTIVITY DATA 

STABILITY: StableXUnstableN/A Conditions to avoidN/A 

INCOMPATIBILITY: (Materials to avoid) N/A 

HA.ZARDOUS DECOMPOSITION OR BYPRODUCTS: Avoid fumes from firina 

HAZARDOUS POLYMEF.IZATION: Will not occur X(Conditions to avoid) N/A 

Page 2 of 4 I~1 
PRODUCT IDENTiFIC,~TION: CM932 

SECTION VI - HEALTH HAZARD DATA 

PRINCIPAL RCUTES CF ABSORPTION: Inhalation and Ingestion 

EFFECTS OF OVEREXPOSURE: Excessive ingestion of barium containing frit may cause 

inflammation of the gastrointestinal tract, muscular paralysis, slow pulse rate, 

irregular heart contractions, and low blood potassium .levels. 

Metal fumes from firing may cause lung inflarmation and injury in terms of hours 

with symptems of chest pains, chills, cough, headache, and diarrhea. 

Prolonaed contact with frit dust can be very irritating to the eyes and/or skin. 

High dust levels can be irritating to the respiratory tract. 

Excessive inhalation of crystalline silica containing dusts over many years can 

result in silicosis, a disabling lung disease. 

With adequate ventilation, dust control, and good personal hygiene, symptoms of 

overexposure should not occur. Advise regular medical monitoring of employees by a 

physician ccmpetent in industrial health.- 

CARCINOGENICITY: In IARC Supplement 7, crystalline silica is given a 2A rating which 

indicates "sufficient evidence" for carcinogenicity to animals and "limited evidence" 

for carcinogenicity to humans. 

EMERGENCY AND FIRST AID PROCEDURES: If overexposure is suspected move employee to 

fresh air; if breathing is difficult give oxygen. Call a physician. For dust in 

eyes; flush immediately with clean water and call a physician._ 

SOURCE OF HEALTH HAZARD DATA: This MSDS was developEd from information on the 

constituent substznces of this mixture, not from test daia on the mixture itself. 

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Uncontaminated material 

may be recovered and re-used. If contaminated scoop, vacuum, or wash into a 

receptacle for disposal. 

WASTE DISPOSAL METHOD: Follow Federal or State and Lccal regulations for disposal. 

Barium is lisLed in US-EPA Code of Federal Regulations 40, Part 261.24. Testing of 

the waste may be required to determine status under the hazardous waste re gulations. 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Protect containers against physical 

damage; store in dry area away from feed and food products. 

OTHER PRECAUTIONS: Employees should wash and change into clean clothes before going 

home. 

Page 3 of 4 

/De 
PRODUC T I OE:N T I F I C-LIJ I ON : M 32 

SECTION VIII - CONTROL MEASURES 

RESPIRATOR'r' PROTECTION: (Specify Type) Use a NIOSH approved dust and/or fume 

respirator es necessary. 

VENTILATION: Lccal Exhaust - Recommended for dust control; vent dust to collector. 

PROTECTIVE GLOVES: Use judgment - work gloves recorrmended. 

EYE PROTECTION: Use judgement - safety glasses recommended. 

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Wear appropriate clean, protective clothing 

such as, but not limited to, coveralls, smocks, aprons, gloves, shoes, and hats: 

WORK/HYGIENIC PRACTICES: Food, beverages, and smoking materials should NOT be in the 

work area. Hygiene is very important; employees should wash thoroughly before 

eating, drinking, smoking, or applying cosmetics. 

Judgments as to the suitability of information herein or the purchaser's purposes are 

necessarily the purchaser's responsibility. Reasonable care has been taken in the 

preparation of this information, but FERRO EXTENDS NO WARRANTIES, MAKES NO 

REPRESENIATIONS AiUD ASSUMES NO RESPONSIBILITY AS TO THE ACCURACY OR SUITABILITY OF 

THIS INFORXIATION FOR ANY PURCHASER'S USE OR FOR ANY CONSEQUENCE OF ITS USE. 

Non-Standard Abbreviations Used on Material Safety Data Sheets 

ACGIH - A;;.rican Conference of Governmental Industrial Hygienists 

CAL/OSHA - California Occupational Safety and Health Administration 

CAS #- Chernical Aybstract Service Number 

CFR - Code cf Federal Regulations 

FED/OSHA - Federal Occupational Safety and Health Administration 

IARC - Int?rnational Agency for Research on Cancer 

MSDS - Material Safety Data Sheet 

N/A - Not ~.pp i i cab1 e 

NIOSH - Na --ional Institute for Occupational Safety and Health 

NTP - Naticnai Toxicology Program (Department of Health and Human Services) 

PEL - Permissible Exposure Limit 

TSCA - Tox'c Substances Control Act 

TLV - Tnres,~ old Limit Value (registered terminology of ACGIH) 

TWA - T i me '~;;.i ghted Average 

US EPA - United States Environmental Protection Agency 

Page 4 of 4 

~~~~C 
MATERIAL SAFETY DATA SHEET 

Issue Date: 11 

TO THE PURCHASER: This MSDS contains important environmental, safety 

information for your employees. Federal regulations require that this information 

be made available to them. If you resell this product, a copy of this MSDS should 

be given to the buyer. 

PRODUCT IDENTIFICATION: CM933 

(Common Name) Ferro alaze CM933 

DESCRIPTION: 

containina FRIT (TSCA Inventory CAS # 65997-18-4X) plus the following typical 

glaze raw materials. 

Silica (CAS 14808-60-7) Electrolyte 

Clay (CAS 1332-58-7) 

SECTION I 

MANUFACTURERS NAME: Ferro Corporation, Frit Division 

MAIL:4150 East 56th. Street HI_P: 4150 East 56th. Street 

P.O. Box 6550 Cleveland, Ohio 44105 

Cleveland, Ohio 44101 

TFLEPHONE:Ferro 24 hour Informational number: (216) 641-5324 

Facility Informational number: (216) 641-8580 

SECTION IIa - HAZARDOUS COMPONENTS 

This glaze mixture contains the following potentially haz,:rdous substances 

referenc:ed by Fed/OSHA in 29 CFR 1910.1200 : 

Exposure Limit (Air>, mg/m3 

COMPONENT: CAS No. ACGIH/TLU FED-OSHA/PEL CAL-OSHA/PEI_ 

Crystalline silica 14808-60-7 0.1 (a) (e) 0.1 (a) 

Particulates not otherwise classified (b) 10/ 1, (r) 15. 10. 

(Total Dust) 

(b) Present as frit or any of the raw materials listed 

above. 

(e) 10/(2+'6respirable quartz) 

(r) Respirable 

(a) Respirable quartz 

• ~/b 
PRODUCT IDENTIFICATION: CM933 

SECTION IIb - "SARA III" DATA 

This product contains the following component(s) that require reporting under Section 

313 of the Emeraency Planning and Community Right-To-Know Act, also known as Title 

III of the SARA (The Superfund Amendments and Reauthorization Act), and 40 CFR Part 

372: 

COMPONENT: CAS N . PERCENT PRESENT: ( a ) 

Zinc compounds (b) < 4.5°6 as Zn 

(a)The percent reported is based on the theoretical composition of this 

glaze mixture. 

(b) Only present as part of frit CAS ~ 65997-18-4'`~ 

SECTION III - PHYSICAL DATA 

SPECIFIC GR.AVITY (H 20 = 1) 1.6-3.0 MELTING POINT (°F.) > 12 

VAPOR PRESSURE (rm Hg) N/A BOILING POINT (°F.) N/A 

UAPOR DENSITY (Air = 1) N/A PERCENT VOLATILE N/A 

(by volume) 

SOLUBILITY IN WATER Nealiaible EVAPORATION RATE N/A 

(butyl acetate = 1) 

APPEARANCE AND ODOR Off white oowder / Sliaht earthy odor 

SECTION IV - FIRE & EXPLOSION HAZARD DATA 

FLASH POINT: N/A. FLAMMARLE LIMITS: N/A 

EXTINGUISHING MEDIA: None 

SP ECIAL FIP.E FIGHTING PROCEDURES: None UNUSUAL FIRE & EXPLOSION HAZARDS: None 

SECTION V - REACTIVITY DATA 

STABILITY: StableXUnstableN/A Conditions to avoid N/A 

iNCOMPATIBILITY: (Materials to avoid) N/A 

HAZARDOUS DECOMPOSITION OR BYPRODUCTS:Avoid fumes from firina 

HAZARDOUS POLYMERIZATION: Will not occur X (Conditions to avoid) N/A 

Page 2 of 4 
F'RODUCT IDEVTIFICAT ION: M 

SECTION VI - HEA.LTH HAZARD DATA 

PRINCIPAL ROUTES OF ABSORPTION: Inhalation and Incestion 

EFFECTS OF OVEREXPOSURE: Metal fumes from firing may cause lung inflammation and 

injury in terms of 

hours with sympters of chest pains, chills, cough, headache, and diarrhea. 

Prolenced contact with frit dust can be very irritating to the eyes and/or skin. 

High dust levels can be irritating to the respiratory tract. Excessive inhalation of 

crystalline silica containing dusts over many years can result in silicosis, a 

disabling lung disease. 

With adequate ventilation, dust control, and good personal hygiene, symptoms of 

overexposure should not occur. Advise regular medical monitoring of employees by a 

physician competent in industrial health. 

CARCINOGENICITY: In IARC Supplement 7, c-rystalline silica is given a 2A rating which 

indicates "sufficient evidence" for carcinogenicity to animals and "limited evidence" 

for carcinogenicity to humans. 

EMERGENCY AND FIRST AID PROCEDURES: If overexposure is suspected move employee to 

fresh air; if breathing is difficult give oxygen. Call a physician. . For dust in 

eyes: flush immediately with clean water and call a physician. 

SOURCE OF HEALTH HAZARD DATA: This MSDS was developed frcm information on the 

constituent substances of this mixture, not from test data on the mixture itself. 

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Uncontaminated material 

may be recovered and re-used. If contaminated scoop, vacuum, or wash into a 

receptacle for disposal. 

WASTE DISrCSAL METHOD: Follow Federal or State and Local regulations for disposal. 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Protect containers against physical 

damace: store in dry area away from feed and food products. 

OTHER PRECAUTIONS: Employees should wash and chance into clean clothes before going 

home. 

Page 3 of 4 

112-1 
PRODUCT IDENTIFICATION: CM933 

SECTION VIII - CONTROL MEASURES 

RESPIRATORY PROTECTION: (Specify Type) Use a NIOSH approved dust and/or fume 

respirator as necessary. 

VENTILATION: Local Exhaust - Recommended for dust controi; vent dust to collector. 

PROTECTIVE GLOVES: Use judgment - work gloves recommended. 

EYE PROTECTION: Use judgement - safety glasses recommended. 

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Wear appropriate clean, protective clothing 

such as, but not limited to, coveralls, smocks, aprons, gloves, shoes, and hats. 

WORK/HYGIENIC PRACTICES: Food, beverages, and smoking materials should NOT be in the 

work area. Hygiene is very important; employees should wash thoroughly before 

eating, drinkina, smoking, or applying cosmetics. 

Judgments as to the suitability of information herein or the purchaser's purposes are 

necessarily the purchaser's responsibility. Reasonable care has been taken in the 

preparation of this information, but FERRO EXTENDS NO WARRANTIES, MAKES NO 

REPRESENTATIONS AND ASSUMES NO RESPONSIBILITY AS TO THE ACCURACY OR SUITABILITY OF 

THIS INFORMATION FOR ANY PURCHASER'S USE OR FOR ANY CONSEQUENCE OF ITS USE. 

Non-Standard Abbreviations Used on Material Safety Data Sheets 

ACGIH - American Conference of Governmental Industrial Hygienists 

CAL/OSHA - California Occupational Safety and Health Administration 

CAS #- Chemical Abstract Service Number 

CFR - Code of Federal Regulations 

FED/OSHA - Federal Occupational Safety and Health Administration 

IA.RC - International Agency for Research on Cancer 

MSDS - Material Safety Data Sheet 

N/A - Not Aoolicable 

NIOSH - Nationai Institute for Occupational Safety and Heaith 

NTP - National Toxicology Program (Department of Health and Human Services) 

PEL - Permissible Exposure Limit 

TSCA - Toxic Substances Control Act 

TLV - Threshold Limit Value (registered terminology of ACGiH) 

TWA - Time Weighted A.verage 

US EPA - United States Environmental Protection Agency 

Page 4 of 4 
MATERIAL SAFETY DATA SHEET 

Issue Date: /l. / 

TO THE PURCHASER: This MSDS contains important environmental, safety 

information for your employees. Federal regulations require that this information 

be made available to them. If you resell this product, a copy of this MSDS should 

be given to the buyer. 

PRODUCT IDENTIFT-CATION: CM935 

(Common Name) Ferro alaze CM935 

DESCRIPTION: 

containing FRIT (TSCA Inventory CAS # 65997-18-4X) plus the following typical 

glaze raw materials. 

Silica (CAS 14808-60-7) Electrolyte 

Zinc oxide (CAS 1314-13-2) Fluorspar (CAS# 7789-75-5) 

Bentonite (CAS 1302-78-9) 

SECTION I 

MANUFACTUR.ERS NA^^E: Ferro Corporation, Frit Division 

MAIL:4150 East 56th. Street SHIP:4150 East 56th. Street 

P.O. Box 6550 Cleveland, Ohio 44105 

Cleveland, Ohio 44101 

TELEPHONE:Ferro 24 hour Informational number: (216) 641-5324 

Facility Informational number: (216) 641-8580 

SECTION IIa - HAZARDOUS COMPONENTS 

This glaze mixture contains the following potentially hazardous substances 

referenced by Fed/OSHA in 29 CFR 1910.1200 : 

Exposure Limit (Air), mg/m3 

COMPONENT: CAS N. ACGIH/TLV FED-OSHA/PEL CAL-OSHA/PEL 

Fluorides, as F (b) 2.5 2.5 2.5 

Crystalline silica 14808-60-7 0.1 (a) (e) 0.1 (a) 

Zinc oxide, as Zn 1314-13-2 5.0 5.0 5.0 

Particulates not otherwise classified (b) 10/3 (r) 15. 10. 

(Total Dust) 

(b) Present as frit or any of the raw materials listed 

above. 

(e) 10/(2+%respirable quartz) 

(r) Respirable 

(a) Respirable quartz 

//~ 
PRODUCT IDENTIFICATION: Lf ~~ 

SECTION IIb - "SARA III" DATA 

This product contains the following component(s) that require reporting under Section 

313 of the Emergency Planning and Community Right-To-Know Act, also known as Title 

III of the SARA (The Superfund Amendments and Reauthorization Act), and 40 CFR Part 

372: 

COMPONENT: AS N0. PERCENT PRESENT: ( a ) 

Zinc oxide 1314-13-2 < 9.0% as Zn 

( a ) The percent reported is based on the theoretical composition of this 

glaze mixture. 

SECTION III - PHYSICAL DATA 

SPECIFIC GPAVITY (H 20 = 1) 1.6-3.0 MELTING POINT (°F.) > 12 

VAPOR PRESSURE (T,m Hg) N/A BOILING POINT (°F.) NXA 

VAPOR DENSITY (Air = 1) N/A PERCENT VOLATILE NXA 

(by volume) 

SOLUBILITY IN WATER Nealiaible EVAPORATION RATE NXA 

(butyl acetate = 1) 

APPEARANCE AND ODOR Off white oowder / Odorless 

SECTION IV - FIRE & EXPLOSION HAZARD DATA 

FLASH POINT: N/A FLA~MA,BLE LIMITS: N/A 

EXTINGUISHING MEDIA: None 

SPECIAL FiRE FIGHTING PROCEDURES: None UNUSUAL FIRE & EXPLOSION HAZARDS: None 

SECTION V - REACTIVITY DATA 

STABILITY: StabieXUnstableN/A Conditions to avoid N/A 

INCOMPATIBILITY: (Materials to avoid) N/A 

HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Avoid fumes from firina 

HAZARDOUS POLYMERIZATION: Will not occur X(Conditions to avoid) N/A 

Page 2 of 4 

1I

~ 
PRODUCT IDENTIFICATION: LE23L 

SECTION VI - HEALTH HAZARD DATA 

PRINCIPAL ROUTES OF ABSORPTION: Inhalation and Ingestion 

EFFECTS OF OVEREXPOSURE: Metal fumes and/or fluoride containing vapors from firing 

may cause lung inflammation and injury in terms of hours with symptoms of chest 

pains, chills, cough, headache, and diarrhea. 

Prolonged contact with frit dust can be very irritating to the eyes and/or skin. 

High dust levels can be irritating to the respiratory tract. 

Excessive inhalation of crystalline silica containing dusts over many years can 

result in silicosis, a disabling lung disease. 

With adequate ventilation, dust control, and good personal hygiene, symptoms of 

overexposure should not occur. Advise regular medical monitoring of employees by a 

physician competent in industrial health. 

CARCINOGENICITY: In IARC Supplement 7, c-rystalline silica is given a 2A rating which 

indicates "sufficient evidence" for carcinogenicity to animals and "limited evidence" 

for carcinogenicity to humans. 

EMERGENCY AND FIRST AID PROCEDURES: If overexposure is suspected move employee to 

fresh air: if breathing is difficult give oxygen. Call a physician. .For dust in 

eyes; flush immediately with clean water and call a physician. 

SOURCE OF HEALTH HAZARD DATA: This MSDS was developed fr.ominformation on the 

constituent substances of this mixture, not from test data on the mixture itself. 

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Uncontaminated material 

may be recovered and re-used. If contaminated scoop, vacuum, or wash into a 

receptacie for disposal. 

WASTE DISPCSAL METHOD: Follow Federal or State and Local regulations for disposal. 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Protect containers against physical 

damage; stcre in dry area away from feed and food products. 

OTHER PRECAUTIONS: Employees should wash and change into clean clothes before going 

home. 

Page 3 of 4 

A2 
PRODUCT IDENTIFIC:-`,TION: ~CM 5 

SECTION VIII - CONTROL MEASURES 

RESPIRATORY PROTECTION: (Specify Type) Use a NIOSH approved dust and/or fume 

respirator as necessary. 

VENTILATION: Local Exhaust - Recommended for dust control: vent dust to collector. 

PROTECTIVE GLOVES: Use judgment - work gloves recommended. 

EYE PROTECTION: Use judgement - safety glasses recommended. 

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Wear appropriate clean, protective clothing 

such as, but not limited to, coveralls, smocks, aprons, gloves, shoes, and hats. 

WORK/HYGIENIC PRACTICES: Food, beverages, and smoking materials should NOT be in the 

work area. Hygiene is very important; employees should wash thoroughly before 

eating, drinking, smoking, or applying cosmetics. 

Judgments as to the suitability of information herein or the purchaser's purposes are 

necessarily the purchaser's responsibility. Reasonable care has been taken in the 

preparation of thls information, but FERRO EXTENDS NO WARRANTIES, MAKES NO 

REPRESENTATIONS AND ASSUMES NO RESPONSIBILITY AS TO THE ACCURACY OR SUITABILITY OF 

THIS INFOwMATI0N FOR ANY PURCHASER'S USE OR FOR ANY CONSEQUENCE OF ITS USE. 

Non-Standard Abbreviations Used on Material Safety Data Sheets 

ACGIH - American Conference of Governmental Industrial Hygienists 

CAL/OSHA - California Occupational Safety and Health Administration 

CAS #- Chemical A.bstract Service Number 

CFR - Code of Federal Regulations 

FED/OSHA - Federal Occupational Safety and Health Administration 

IARC - International Agency for Research on Cancer 

MSDS - Material Safety Data Sheet 

N/A - Not Acplic.zble 

NIOSH - National Institute for Occupational Safety and Health 

NTP - National Toxicology Program (Department of Health and Human Services) 

PEL - Permissible Exposure Limit 

TSCA - Toxic Substances Control Act 

TLV - Tnres',old Limit Value (registered terminology of ACGIH) 

TWA - Ti me We i ghted Average 

US EPA - United States Environmental Protection Agency 

Page 4 of 4 

111 
MATERIAL SAFETY DATA SHEET 

Issue Date: 6/1 / 7 

. TO THE PURCHASER: This MSDS contains important environmental, safety 

information for your employees. Federal regulations require that this information 

be made available to them. If you resell this product, a copy of this MSDS should 

be given to the buyer. 

PRODUCT IDENTIFICATION: CM 7 

(Cc4runon Name) Ferro Qlaze CM937 

DESCRIPTION: 

containinc FRIT (TSCA Inventory CAS # 65997-18-4*) plus the following typical 

glaze raw materials. 

Silica (CAS 14808-60-7) Feldspar (CAS 68476-25-5) 

Alumina (CAS 1334-28-1) Zirconium silicate(CAS 14940-68-2) 

Clay (CAS 1332-58-7) 

SECTION I 

MANUFACTURERS NAME: Ferro Corporation, Frit Division 

MAIL: 4150 East 56th. Street HIP• 4150 East 56th. Street 

P.O. Box 6550 Cleveland, Ohio 44105 

Cleveland, Ohio 44101 

TELEPHONE: Ferro 24 hour Informational number: (216) 641-5324 

Facility Informational number: (216) 641-8580 

SECTION.IIa - HAZARDOUS COMPONENTS 

This glaze mixtur2 contains the following potentially hazardous substances 

referenced by Fed/OSHA in 29 CFR 1910.1200 : 

Exposure Limit (Air), mg%m 

COMPONENT: CAS No. ACGIH/TLV FED-OSHA/PEL CAL-OSHA/PEL 

Aluminum oxide, as A1 1344-28-1 10. 1035. (r)10. 

Crystalline silica 14808-60-7 0.1 (a) (e) 0.1 (a) 

Zirconium ccmpounds, as Zr (b) 5.0 5.0 5.0 

Particulates not otherwise classified (b) 10/3 (r) 15. 10. 

(Total Dust) 

(b) Present as frit or any of the raw materials listed 

above. (r) Respirable 

(e) 10/(2+Arespirable quartz) (a) Respirable quartz 

n,,,.. 1 ..f n l`0 
PRODUCT IDENTIFICATION: CM937 

SECTION IIb - "SARA III" DATA 

This product contains the following component(s) that require reporting under Section 

313 of the Emergency Planning and Community Right-To-Know Act, also known as Title 

III of the SARA (The Superfund Amendments and Reauthorization Act), and 40 CFR Part 

372: 

COMPONENT: CAS N0. PERCENT PRESENT: 

None (b) 

The percent reported is based on the theoretical composition of this 

qlaze mixture. 

(b) V Only present as part of frit CAS # 65997-18-4* 

SECTION III - PHYSICAL DATA 

SPECIFIC GRAVITY 1.6-3_.0 MELTING POINT > 1200 

VAPOR PRESSURE (rrm Hg) NXA BOILING POINT NXA 

VAPOR DENSITY (Air = 1) NXA PERCENT VOLATILE N/A 

(by volume) 

SOLUBILITY IN WATER NegliQible EVAPORATION RATE NXA 

(butyl acetate = 1) 

APPEARANCE AND ODOR Off white powder / Slicht earthy odor 

SECTION IV - FIRE & EXPLOSION HAZARD DATA 

FLASH POINT:N/A FLAMMABLE LIMITS:N/A 

EXTINGUISHING MEDIA: None 

SPECIAL FIRE FIGHTING PROCEDURES: NoneUNUSUAL FIRE & EXPLOSION HAZARDS: None 

SECTION V - REACTIVITY DATA 

STABILITY: Stable X Unstable N/A Conditions to avoid N/A 

INCOMPATIBILITY: (Materials to avoid) N/A 

HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Avoid fumes from firina 

HAZARDOUS POLYMERIZATION: Will not occur X(Conditions to avoid) N/A 

Page 2 of 4 
PRODUCT IDENTIFICATION: CM937 

SECTION VI - HEALTH HAZARD DATA 

PRINCIPAL ROUTES OF ABSORPTION: Inhalation and InQestion 

EFFECTS OF OVEREXPOSURE: Metal fumes from firing may cause lung inflammation and 

injury in terms of 

hours with symptc~s of chest pains, chills, cough, headache, and diarrhea. 

Prolonged contact with frit dust can be very irritating to the eyes and/or skin. 

High dust levels can be irritating to the respiratory tract. Excessive inhalation of 

crystalline silica containing dusts over many years can result in silicosis, a 

disabling lung disease. 

With adequate ventilation, dust control, and good personal hygiene, symptoms of 

overexposure should not occur. Advise regular medical monitoring of employees by a 

physician competent in industrial health. 

CARCINOGENICITY: In IARC Supplement 7, crystalline silica is given a 2A rating which 

indicates "sufficient evidence" for carcinogenicity to animals and "limited evidence" 

for carcinogenicity to humans. 

EMERGENCY AND FIRST AID PROCEDURES: If overexposure is suspected move employee to 

fresh air; if breathing is difficult give oxygen. Call a physician. For dust in 

eyes; flush immediately with clean water and call a physician. 

SOURCE OF HEALTH HAZARD DATA: This MSDS was developed from information on the 

constituent substances of this mixture, not from test data on the mixture itself. 

SECTION VII - PRECAUTIONS FOR SAFE HANGLING AND USE 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Uncontaminated material 

may be recovered and re-used. If contaminated scoep, vacuum, or wash into a 

receptacle for disposal. 

WASTE DISPOSAL ME --i­HOD: Follow Federal or State and Lccal regulations for disposal. 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Protect containers against physical 

damage; Stcre in dry area away from feed and food products. 

OTHER PRECAUTIONS: Employees should wash and change into clean clothes before going 

home. 

Page 3 of 4 

/,~ D 
PRODUCT IDENTIFICATION: CM937 

SECTION VIII - CONTROL MEASURES 

RESPIRATORY PROTECTION: (Specify Type) Use a NIOSH approved dust and/or fume 

respirator as necessary. 

VENTILATION: Local Exhaust - Recommended for dust control; vent dust to collector. 

PROTECTIVE GLOVES: Use judgment - work gloves reccmmehded. 

EYE PROTECTION: Use judgement - safety glasses recommended. 

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Wear appropriate clean, protective clothing 

such as, but not limited to, coveralls, smocks, aprons, gloves, shoes, and hats. 

WORK/HYGIENIC PRACTICES: Food, beverages, and smoking materials should NOT be in the 

work area. Hygiene is very important; employees should wash thoroughly before 

eating, drinking, smoking, or applying cosmetics. 

Judgments as to the suitability of information herein or the purchaser's purposes are 

necessarily the purchaser's responsibility. Reasonable care has been taken in the 

preparation of this information, but FERRO EXTENDS NO WARRANTIES, MAKES NO 

REPRESENTATIONS AND ASSUMES NO RESPONSIBILITY AS TO THE ACCURACY OR SUITABILITY OF . 

THIS INFORMATION FOR ANY PURCHASER'S USE OR FOR ANY CONSEQUENCE OF ITS USE. 

Non-Standard Abbreviations Used on Material Safety Data Sheets 

ACGIH - American Conference of Governmental Industrial Hygienists 

CAL/OSHA - California Occupational Safety and Health Administration 

CAS #- Che:aical Abstract Service Number 

CFR - Code of Federal Regulations 

FED/OSHA - Federal Occupational Safety and Health Administration 

IARC - International Agency for Research on Cancer 

MSDS - Material Safety Data Sheet 

N/A - Not APD1- .ble 

NIOSH - National Institute for Occupational Safety and Health 

NTP - National Toxicology Program (Department of Health and Human Services) 

PEL - Permissible Exposure Limit 

TSCA - Toxic Substances Control Act 

TLV - Thres ~~ old Limit Value (registered terminology of ACGIH) 

T,WA - Ti me Wei ghted Average 

US EPA - United States Environmental Protection Agency 

Page 4 of 4 

i~ 
MATERIAL SAFETY DATA SHEET 

Issue Date: 11/27/96 

TO THE PURCHASER: This MSDS contains important environmental, safety and health 

information for your employees. Federal regulations require that this information 

be made available to them. If you resell this product, a copy of this MSDS should 

be given to the buyer. 

_PRODUCT IDENTIFICATION: 3134/3134-2/3134-3 

(Common Name)Ferro frit 3134 

CHEMICAL FAJ1-1ILY: Frits TSCA Inventory CAS # 65997-18-4x 

YN NYM: Chemical substances manufactured in the production of frit. 

(From US-EPA/TSCA description) "Frit is a mixture of inorganic chemical substances 

produced by rapidly quenching a molten, complex combination of materials, confining 

the chemical substances thus manufactured as non migratory components of glassy 

solid flakes or granules. ---" 

SECTION I 

MANUFACTURERS NAME: Ferro Corporation, Frit Division 

MAIL: 4150 East 56th. Street aKL 4150 East 56th. Street 

P.O. Box 6550 Cleveland, Ohio 44105 

Cleveland, Ohio 44101 

TELEPHONE: Ferro 24 hour Informational number: (216) 641-5324 

Faciiity Informational number: (216) 641-8580 

SECTION IIa - HAZARDOUS COMPONENTS 

Frit is a fused silicate glass substance. The components of 

listed belcw are from the inventory of potentially hazardous 

by FED-OSHA in 29 CFR 1910.1200. 

Exposure Limit (Air), mg/m 3 

ACGIH/TLV FED OSHA/PEL CAL OSHA/PFL 

Particulates not otherwise classified 10/3 (r) 15. 10. 

(Total Dust) 

(r) Respirable 

this glass prcduct 

substances referenced 

COMPONENT: 

Page 1 of 4 

/~~ 
PRODUCT IP'c"JTIFICATION: 3134/3134-2/3134-3 

SECTION IIb - °SARA III° DA.Ta 

This product contains the following component(s) t;;,~ t require reporting under Section 

313 of thz Emereency Planning and Community Right-To-Know Act, also known as Title 

III of the SARA. (The Superfund Amendments and Reauthorization Act), and 40 CFR Part 372: 

COMPONENT: (a) 

None 

(a) The percent re - -ted is based on the theoretical composition of this frit. 

While existing in theor the ccmponent(s) mentioned are only present as part of 

FRIT (CAS;,—' 65997-18-4*; . 

SECTION III - PHYSICAL DATA 

SPECIFIC GRr,VITY (H 20 = 1)1.6-3.0 MELTING POINT (°F.)> 1200 

SOLUBILITY IN WATER Neqlioible 

APPEARANCE ;-'.ND ODOR Frit flake or milled class pcwder / Odorless 

Boiling Pcint /Vapor Pressure / Vapor Density Volatiles By Volume / Evaporation 

RateA11 NiA 

SECTION IV - FIRE & EXPLOSION HAZA,P.D DATA 

FLASH POINT:N/A FLAMMABLE LIMITS:N/A 

EXTINGUISHING MEDIA:None UNUSUAL FIRE & EXPLOSION HAZARDS: None 

SECTION V - REACTIVITY DATA 

STABILITY: Stable X Unstable N/A Conditions to avoid N/A 

INCOMPATIBI'ITY: (Materials to avoid) N/A 

HAZARCOUS C= ~ OMFOSITION OR BYPRODUCTS:Avoid fumes from firinQ 

HAZARCOUS Pl'iLYME::?ZATION: Will not occurX (Conditions to avoid) N/A 

Page 2 of 4 
PRODUCT IDENTIFICATION: 3134/3134-2/3134- 

SECTION VIII - CONTROL MEASURES 

RESPIRATORY PROTECTION: (Specify Type) Use a NIOSH approved dust and/or fume 

respirator as necessary. 

VENTILATI0N: Local Exhaust - Recommended for dust control: vent dust to collector. 

PROTECTIVE GLOVES: Use judgment - work gloves reconmended. 

EYE PROTECTION: Use judgement - safety glasses recommended. 

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Wear appropriate clean, protective clothing 

such as, but not limited to, coveralls, smocks, aprons, gloves, shoes, and hats. 

WORK/HYGIENIC PRACTICES: Food, beverages, and smoking materials should NOT be in the 

work area. Hygiene is very important; employees should wash thoroughly before 

eating, drinking, smoking, or applying cosmetics. 

Judgments as to the suitability of information herein or the purchaser's purposes are 

necessarily the purchaser's responsibility. Reasonable care has been taken in the 

preparation of this information, but FERRO EXTENDS NO WARRANTIES, MAKES N0 

REPRESENTATiONS AND ASSUMES NO RESPONSIBILITY AS TO THE ACCURACY OR SUITABILITY OF 

THIS INFORMATION FOR ANY PURCHASER'S USE OR FOR ANY CONSEQUENCE OF ITS USE. 

Non-Standard Abbreviations Used on Material Safety Data Sheets 

ACGIH - American Conference of Governmental Industrial Hygienists 

CAL/OSHA - California Occupational Safety and Health Administration 

CAS #- Chemical Abstract Service Number 

CFR - Code of Federal Regulations 

FED/OSHA - Federal Occupational Safety and Health Administration 

IARC - International Agency for Research on Cancer 

MSDS - Material Safety Data Sheet 

N/A - Not Applicable 

NIOSH - National Institute for Occupational Safety and Health 

NTP - National Toxicology Program (Department of Health and Human Services) 

PEL - Permissible Exposure Limit 

TSCA - Toxic Substances Control Act 

TLV - Threshold Limit Value (registered terminology of ACGIH) 

TWA - Time Weighted Average 

US EPA - United States Environmental Protection Agency 

Page 4 of 4 h 

~ o~1~ 
PRODUCT IDENTIFICATION: 3134/3134-2/3134-3 

SECTION VI - HEALTH HAZARD DATA 

PRINCiPAL ROUTES OF ABSORPTION: Inhalation and Ingestion 

EFFECTS CF OVEREXPOSURE: Prolonged contact with frit dust can be very irritating to 

the eyes and/or srin. High dust levels can be irritatang to the respiratory tract. 

With adecuate ventilation, dust control, and good personal hygiene, symptoms of 

overexposure snould not occur. Advise regular medical monitoring of employees by a 

physician competent in industrial health. 

CARCINOGENICITY: N/A 

EMERGENCY AND FIRST AID PROCEDURES: If overexposure is suspected move employees to 

fresh air: if breathing is difficult give oxygen. Call a physician. For dust in 

eyes; flush immediately with clean water and call a physician. 

SOURCE OF HEALTH HAZARD DATA: This MSDS was developed from information on the 

constituent substances of this frit material, not from test data on the frit itself. 

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE 

STEPS TO BE TA.KEN IN CASE MATERIAL IS RELEASED OR SPILLED: Uncontaminated material 

may be recovered and re-used. If contaminated scoop, vacuum, or wash into a 

receptacle for disposal. 

WASTE DiSPOSAL METHOD: Follow Federal or State and Local regulations for disposal. 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Protect containers against physical 

damage; store in dry area away from feed and food products. 

OTHER PRECAUTIONS: Employees should wash and change into clean clothes before going 

home. 

Page 3 of 4 

i~ 
MATERIAL SAFETY DATA SHEET 

Issue Date: 1/11/9 

TO THE PURCHASER: This MSDS contains important environmental, safety and health 

information for your employees. Federal regulations require that this information 

be made available to them. If you resell this product, a copy of this MSDS should 

be given to the buyer. 

PRODUCT IDENTIFICATION: CC261/CC261-2 

(Corrunon Name) Ferro frit CC261 

CHEMICAL FAMILY: Frits TSCA Inventory CAS # 65997-18-4* 

SYNONYM: Chemical substances manufactored in the production of frit. 

(From US-EPA/TSCA description) "Frit is a mixture of inorganic chemical substances 

produced by rapidly quenching a molten, complex combination of materials, confining 

the chemical substances thus manufactured as non migratory components of glassy 

solid flakes or granules. ---" 

SECTION I 

MANUFACTURERS NAME: Ferro Corporation, Frit Division 

MA : 4150 East 5oth. Street aELL 4150 East 56th. Street 

P.O. Box 6550 Cleveland, Ohio 44105 

Cleveland, Ohio 44101 

TELEPHONE: Ferro 24 hour Informational number: (216) 641-5324 

Facility Informational number: (216) 641-8580 

SECTION IIa - HAZARDOUS COMPONENTS 

Frit is a fused silicate glass substance. The comp , 

listed below are from the inventory of potentially 

by FED-OSHA in 29 CFR 1910.1200. 

Exposure 

COMPONENT: ACGIH/TLV 

Particulates not otherwise classified 10/3 (r) 

(Total Dust) 

Dnents of this glass product 

hazardous substances referenced 

Limit (Air), mg/m3 

FED OSHA/PEL CAL OSHA/PEL 

15. 10. 

(r) Respirable 

Page 1 of 4 

~o~ ~ 
PRODUCT IDENTIFICATION: CC261/CC261-2 

SECTION IIb - "SARA III" DATA 

This product contains the following component(s) that require reporting under Section 

313 of the Emergency Planning and Community Right-To-Know Act, also known as Title 

III of the SARA (The Superfund Amendments and Reauthorization Act), and 40 CFR Part 372: 

COMPONENT: ( a ) 

Zinc compounds < 9.0% as Zn 

( a ) The percent reported is based on the theoretical composition of this frit. 

While existing in theory, the component(s) mentioned are only present as part of 

FRIT (CAS # 65997-18-4*). 

SECTION III - PHYSICAL DATA 

SPECIFIC GRAVITY (H20 = 1) 1.6-3.0 MELTING POINT (°F.) > 1200 

SOLUBILITY IN WATER Negliaible 

APPEARANCE AND ODOR Frit flake or milled class oowder / Odorless 

Boiling Point / Vapor Pressure / Vapor Density /% Volatiles By Volume / Evaporation 

RateA11 N/A 

SECTION IV - FIRE & EXPLOSION HAZARD DATA 

FLASH POINT:N/A FLAMMABLE LIMITS: N/A 

EXTINGUISHING MEDIA: None UNUSUAL FIRE & EXPLOSION HAZARDS: None 

SECTION V - REACTIVITY DATA 

STABILITY: Stable _LUnstableN/AConditions to avoidN/A 

INCOMPATIBiLITY: (Materials to avoid) N/A. 

HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Avoid fumes from firing 

HAZARDOUS POLYME?IZATION: Will not occur X (Conditions to avoid) N/A 

Page 2 of 4 

l 'I ~ 
. PRODUCT IDENTIFICATION: CC261/CC261-2 

SECTION VI - HEALTH HAZARD DATA 

PRINCIPAL ROUTES OF ABSORPTION: Inhalation and Ingestion 

EFFECTS OF OVEREXPOSURE: Metal fumes from firinc may cause lung inflammation and 

injury in terms of hours with symptoms of chest pains, chills, cough, headache, and 

diarrhea. 

Prolonged contact with frit dust can be very irritating to the eyes and/or skin. 

High dust levels can be irritating to the respiratory tract. 

With adequate ventilation, dust control, and good personal hygiene, symptoms of 

overexposure should not occur. Advise regular medical monitoring of employees by a 

physician competent in industrial health. 

CARCINOGENICITY: N/A 

EMERGENCY AND FIRST AID PROCEDURES: If overexposure is suspected move employee to 

fresh air; if breathing is difficult give oxygen. Call a physician. For dust in 

eyes; flush immediately with clean water and call a physician. 

SOURCE OF HEALTH HAZARD DATA: This MSDS was developed from information on the 

constituent substances of this frit material, not from test data on the frit itself. 

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE 

STEPS TO BE TAKE,N IN CASE MATERIAL IS RELEASED OR SPILLED: Uncontaminated material 

may be recovered and re-used. If contaminated scoop, vacuum, or wash into a 

receptacle for disposal. 

WASTE DISPOSAL METHOD: Follow Federal or State and Local regulations for disposal. 

PRECAUTIONS TO BE TAKEN IN . HANDLING AND STORING: Protect containers against physical 

damage; store in dry area away from feed and food products. 

OTHER PRECA.UTIONS: Employees should wash and change into clean clothes before going 

home. 

Page 3 of 4 

16p-f - 
PRODUCT IDENTIFICATION: CC261/CC261-2 

SECTION VIII - CONTROL MEASURES 

RESPIRATORY PROTECTION: (Specify Type) Use a NIOSH approved dust and/or fume 

respirator as necessary. 

VENTILATION: Local Exhaust - Recommended for dust control: vent dust to collector. 

PROTECTIVE GLOVES: Use judgment - work gloves recommended. 

EYE PROTECTION: Use judgement - safety glasses recommended. 

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Wear appropriate clean, protective clothing 

such as, but not limited to, coveralls, smocks, aprons, gloves, shoes, and hats. 

WORK/HYGIENIC PRACTICES: Food, beverages, and smoking materials should NOT be in the 

work area. Hygiene is very important; employees should wash thoroughly before 

eating, drinking, smoking, or applying cosmetics. 

Judgments as to the suitability of information herein or the purchaser's purposes are 

necessarily the purchaser's responsibility. Reasonable care has been taken in the 

preparation of this information, but FERRO EXTENDS NO WARRANTIES, MAKES NO 

REPRESENTATIONS AND ASSUMES NO RESPONSIBILITY AS TO THE ACCURACY OR SUITABILITY OF. 

THIS INFORMATI0N FOR ANY PURCHASER'S USE OR FOR ANY CONSEQUENCE OF ITS USE. 

Non-Standard Abbreviations Used on Material Safety Data Sheets 

ACGIH - American Conference of Governmental Industrial Hygienists 

CAL/OSHA - California Occupational Safety and Health Administration 

CAS #- Chemical Abstract Service Number 

CFR - Code of Federal Regulations 

FED/OSHA - Federal Occupational Safety and Health Administration 

IARC - International Agency for Research on Cancer 

MSDS - Material Safety Data Sheet 

N/A - Not Aaplicable 

NIOSH - National Institute for Occupational Safety and Health 

NTP - National Toxicology Program (Department of Health and Human Services) 

PEL - Permissible Exposure Limit 

TSCA - Toxic Substances Control Act 

TLV - Threshold Limit Value (registered terminology of ACGIH) 

TWA - T ime 'Aei ghted Average 

US EPA - United States Environmental Protection Agency 

Page 4 of 4 
FILE No. 972 03iO3 '98 15:26 ID:CUSTOf1ER SERVICE 216 641 7029 PAGE 2 

03/03/1998 16:19 3388686149 GENE=RAL CO!_OR PAGE 02 

CS)tcno FTs' 

MATERIAL SAFETY DATA SHEET 

1040 Cronn Polntl Pkwy. Sult. 270, Allanta, pA 30338 •(770) 282- 4A0 n Faa (7701791-8870 

SrlC I'luN A. 1 ltUlaUC'1 ANU CUMI ANY 1llEN L'IFICAT101Y `~t~l ~~ 

PRODUCT NAMI';: tPK KiIO,L/N 

CHEMICAL NnML: Kaolinite (CAS No. 1332-58•7) 

PEZOI)UCEIt: 

71te Fcadspar Corporalion 

1040 Crown Pointe 11'arkway. Suite 270 

Atlanta, GA 30338 

MSDS No. 9704 DATB PREPARLD: November 1, 1997 

TELEPHONE NUMI3E12S: 

(Emergency and Informatioti) 

(770) 392-8660 8am - Spm BST M-F 

(770) 392-8670 FAX 

SECTION 11. !•IAZARDOUS IlYGREpI&NTS 

rree Silica (Crystattuia Quartz) Formula: Si02 Typically 0.1-4% CAS No. 14808-60-7 

Kaolin or kaotinite is atisturally occuring hydrous aluminunt silieate niineral. Foniiula: H4AIZSi209; SiO2 

SECPION Ill. 1'I IYSICAL UATA 

BO LING POINT: Not Applicabie YAPQ1t PRLSSURE: Not Applicable SPECIHiC G AV1TY: 2.56 

J~ 1~, 'INGPOtNT: 1740-1785 0C 59LWRILITY IN WATER: Negligible PGRCCr1'j' VOLATILG: Not Applicabie 

QDOR n)VD AI'1'GA1tANCE: Girthy sntell when wel. White to ligltt gray lunip.; buff-colorod powder. 

SECTiON 1V. Flltl: ANU EXPL,OSION UATA: Non-flanimable And non-exploaive. 

SECTION V. 11EAL'1'li IIA'LAltll lhFOHM1ITI.ON 

05HA 1'CL: CItYS'I'ALLINEQUAKI'Z (Respirabla) 0.1 mg/ttt 3 (TWA-'fLV) 

ACGI1i 11V; CKYSTALI,IN1's QllARTZ (Respirable) 0.1 mg/nt 3(TWA-TLV) 

NIOSI ( TW/1: CIiYSTALLINIs Ql1AR17 (Respirabic) 0.05 mg/nt 3 

.._ 

. e . 

jLl1411t.i1TIoN: WAI4N11V(;: 'llicsc products contnin crystallino silicn. Itepcated. prolongcd itthnlation of dust mey 

cause dclnyed fung irtjury witielt may resull in silioosis or pneuinoconiosis. The International Agency Por Iteseareh On 

Cauccr in its publicatiott, "/ARC A•Ianogroplu On Ttie Lvoluariuor UJThr Carci ruKairic Risk Tu Haiiiun,y — Silitu. Sume 

Sllfcarer. Ctxil Dusr uaid Pu%rlranrid Fibrlis" - Voluine 611, 1997, har concluded tltat tltare is suf'Ficient evidenee for the 

carclnoganicity of crystailine silica itt itumans, .nd has, therefore, claasified erystalline siliea in Group 1, carcinogertic to 

Itumans. Tite Nntional Toxicology Progratn's ("NTPht") Sixth Annual lteport on Caroinogena, 1991, liats crystalline 

iilica (reapirabie) as a subatance wl iclt may teasonably be anticipated to be a careinogett. !n humalls, a number of 

studies liave fouttd an associaiion between lung cancar and exposure to dust cantaining respirable erystalllne alllea. In 

ntany of these studics, lhvugit ttot all, lung cancer riska were elevated and couid not be explainad by cvnfounding factors 

such as cigarette stnokittg or amenic or radon itthalation. While the IARC working group concluded tltere was auffieient 

evidenca in humans for the earcinogenicity of inhalal cryatttlline silica in tlro fonn of quartz or erystobalite. it noted that 

earcinogenicity iit humana wae not detected in lt circumstances studied. NOTR: The State of California requires the 

foltowing statement: "Airborne pertic{es of rospirable size of crystalline silica nn: known to ti e State of California to 

eause cancor." 

ING[STjON: Nausea ntay reault Iront aecidantal ingestion. Mny eausa cancer. 

/3c~ 
FILE Nc. 972 03;03 '98 15:26 ID:CUST0MER SERVICE 216 641 7029 PAGE 3 

83/03/1999 16:19 3308086149 GENERAI. C'JLOR PAGE 03 

SECTION V. 11EALT1I T;IAZAIZD INFORIYSATIION (CoatlauaJ) 

EU-: Inflamnlatioa of eye tissuo 1»ay occur from overexposure. 

SK},i;J CONTACT/ADSORPT ON : lnflalnlnation from contact with open cuts may occur. 

5 105 aNa SYMI'TOMS A550C1A190 WITH ExrOSU1tEOVEft TI•tL TLV : 

Short Temt: Si ortness of breath, eougltittg assoeialed witl ► (nl alation of dust. Long Terin: May cause silicosis, n 

c(hronic disease of the lungs tnerked by acute flbrosis; tnay cause cancer. 

EMERGENCY/I'IM A1D AROCED UBL-SI: 

INHALATION: Move to fresl ► air; consult physieian and /or obtaitt competent niedica( assistance as necea9ary. 

INGf'~S'IION: Consult physician and/or obtait ► conipetent rnedical asaistance. 

EYR CONTACT: Fluslt witli water; coasult physician and/or obtain conipeteot medical assistauce as necessary. 

SKIN CONTnCT: Wasl ► Utoroug! ly wili► watar. 

SEC"TION V1. RCACTIVITY AATA 

STA13lL1"TY : Ka1i1it ► is a stablo materin) undcr ord'a ary conditions. 

1N OMI'A'1 1)It_I']'Y : Nunc klwwn. 

H ZAIZUUUS 1'OLYMj?jtIZA'IION: Nut known to occur. 

SECTIOW V11. Sl 1 1LL Oit LF:AK 11 110CEUUJtLS 

5TCi'$_ TO i3G l'AKWJlr MA'1'EB1" SPILLED Olt REL[ASED : 

If uncontltnit+nted, recovcr and reusc. If contarninated, coliect in suitable containers for disposal. Usc appropriatc 

ntetltoc) to avoid crr:tting dust. Avoid bitstliting dust. Wenr a NIOSN/MSHA/OSHA approved respirator. 

WASTL• DISI'OSAL M1's"1'I4OD : May be buried In approved land disposal facility in accordance witlt Federal, 5tate, attd 

local regutations. fcldspar is not a liaxardous waste uqder RCRA (40 CFR Part 261). 

SECT1On v111. CONUCfIONs FOK bAFE USIc; 

VENTIl.AT10N : Local exbaust required for dust ranioval. Refer to OSHA 1910.24, ASTM, and/or ANSI Standards. 

Do not excoed OSHA 1'GL or ACOIH TLV: 

RZ-SrIitATOrtY P1toTLCT10N : Use NIOSH/MSHA/OSHA approved respirator if dust is present. 

>=VE PRQTL"CT10CJ : Oiitional, but recommended. NIOSH recomntetids against wearing contact lenses wllcn svorkillg 

witli cryatalline silica, 

pROTECTiVL• GLOVCS : Optioiial, but recommended. 

SBCTION IX. SI'EC1AL 1'HECAU')('IONiS 

1. Do nut bmatlta dust. 

2. AvofeJ crcaling dust in closcd arcas, 

3. Uso odayuatvvautilation as rccotnrneuded by NJOSH/MSHA/OSHA for crystalline silica, 

SEC'['iON 7C. 5T11E1i ItE1.ATk;ll INFORMATION 

1. NI'CA / C1'MA I(MI5 ltatings: Ilcallh (3) Flatnntability (0) Reactivity (D) Persottal I'rtnectiun (G) 

2. Kaulin is twt ba-rardouz uiuler I)OT ltcguiations. 

). lJUvcrnmcnt rettuinlitltts rt:quire tl nt personnel working witli crystalline silica receive appropriate trnining iti anfc 

..•vek llabitt, rosrirntary Iwolection and Itcalth risks. 

T1y t>0/0 fFm MeM.M b IM eCeulelN, I3u11M -ftny11KhIN W-0%*1 M..d ,CMY rnlh rOIpCC/ rClpwn1A/i1Y IO/ IeFa11C• 

1Awsw. IAw dole -4a1e1 w+ll W qvsoMO/.t nTOle ~nl ao\Cl.lwd II0IM. IMrN 0M11 f4e1 Nkfro IO N1 w Co1MnON0" wWlw ylv OMN' rnallnON or M Olry p•OaeLI 

Ily /eIQqNn 1HffftCl M qw.N er Mw~. eeneC/1W.0 IRN 1"aN01 MO .,{11.(I1NY el 111M11 (D ,Ef-y porIR1110, oylpOw 111~bAM. dH0 we pAumv m0 

qM Vw o1 Mol pqwN.n:l I1./ IrrPM• ~ 11MYM 1~~ y1M11.~ MI'YQ•bIro.•~ A i.rM~.wl. vnt w, ~o~nvinw.s ~ vAh vlrp4ebN nwhn or ~ q w1~tY twn end 

rtOrasro 

131 
Mar-09-98 02:34P SOUTHERN COLOR CO. 770 382 8770 P.02 

MATF.RIA[, SAFE'I'Y DATA SHF.E'T' 

~ 

 Rutile Ore Page 1 of2 

----- -- ------------------ ---- --------------------- -- -------- -------- 

~. 

1. PitflDUCT IDENTIFICA'TION - 

Produot Name ...................................... : Rutile Ore 

CAS Number ................... ................... : 134663-67-7 

Chemical Structure .............................. : TfO, 

Chemical Formula ................................. : Fe,O, +TiO, + SiO, + ZrO, + A1,0, 

Manufacturer's Name/Address: SOUTFERN COLOR COMPANY. rNC 

, P.O. BOX 1507 

CARTERSVTLLE, GA 30120 

Emergescy Telephone No.: 513-771-7190 

— --------- -------- --- ------------------------ — ------------------------------------ — ---- ---- 

2. .PAZARDOUS IlYGREDIENTS - 

CAS N°. 1a PELJPI'LV 

'1G'tts ium Dioxide Ti02 134663-67-7 97.0 Min 10 mglm' 

Fred Sffica (Quartz) Si0 2 1480-60-7 .95 Max 10 mg/m3-(SiO,) 

Ziticonium e ZrOZ 14940-68-2 1.0 Max 5 mg/m' 

Irob 0adde Fe,103 1309-37-1 1.0 Max 5 mg/m3 

Aluminum Oxide Al20, 1344-28-1 .5 Max 10 mg/m-` 

3. PH.YSICAL DATA - 

Appesrartce and Odor .................. Odorless Powder 

Boiling Point ............................... Not Applicable 

Melting Pourt ................... ,.......... 1640°C 

Vapor Pressure (mm Hg)............ Not Applicab(e 

Vapor Density ............................ Will Not Evaporate 

% Volatile .................................. Not Volatile 

Speci6c GravitY (H20 = 1).......... 4.0 - 4.6 

Solubility in Water ...................... Insoluble 

Evaporation Rate ........................ Not Applicable 

4. FIRE AND EXPLOSION DATA - 

Flash Point °F ( ° C) : Not applicable 

Flammable Limits : Lel-Not Applicable 

Uel-Not Applicable 

~ Extinguishing Stedia: Not Flammable 

Special Fire Fighting Procedures/Unusuai Fire or Explosion Hazards: None, use procedures necessary for 

~•: suirouading p+oducts. 

Unusual Fire 8t Explosion Hazards: Does not burrn or explode 

......_._ _ ----------- --------- — ------------------------------------------------------- -- ----- ----- 

5... TH HAZARD DATA - 

~ ute~. of Entry: 

Inhalation: Composite on mucous membranes - nuisance dust 

~ Skia: Solid pardcles will not absorb. 

Eyes: Irritant if particles lodge in eye, physical discomfort only. 

Ingestion: No adverse effects are seen in animals after ingestion. 

Health Hazards (Acute and Chronic): Harmfiil eil'ects itre known to hr cau ~ ed by exposure of Titanium 

~ ;..

.~:. 

130?- 
Mar-09-98 02:34P SOUTHERN COLOR CO. 770 382 8770 P.03 

compounds above the published TLV liniit 

C3nditions which may be aggravated by exposure: None kno«n 

Careinogenity: Part or ingredient listed as a carcinogen by I.qRC. N11":\SHA or AC'GIH 

; SiW and Symptoms of Exposure: None 

~~~~>t~gestcy and First Aad Procedures: 

Eyes: idush with water - consult a phsyician 

Slcin: wash with soap and water for notTnal hygenic eflectiveries; 

Inhalation: Not expected to be a problem 

Ingestion: Not expected to be a problem 

= Sldn Absorption: Not a problem 

6.f-Vioduct

'IVI1Y IDATA - 

 is stable. 

Conditions to Avoid: Use adequate ventilation; comply with OSHA reviilations 

Hazardous Decomposition Products: Will not decompose 

Incompatibilities ... : None known 

Hazardous Polymerization will not occur. 'i= ~= 

~~~_~_~______~_~__-------------------------------------------------______--_--__ 

7. PRECAUTIONS FOR SAFE HANDLIIVG AND USE - 

Steps to be taken in case material is released or spilled: Scoop up by some means and store in a waste 

:,. '•`- ~:ti~c~siner. 

Waste disposal method: Disposal must be made in accordanc:e «•itli Fcclerll, State, and local regulationsPreeautions to take in.handling and storage: LJse adequate ve.ritilation iirid dust collection. Practice good 

housekeeping. Do not permit dust to collect on walls, floors, sills, ledges, and equipment- Wash clean 

and test respirators in accordance with OSHA regulations. Maintain rnd test ventilation and dust 

4,.collection equipment. 

precautions: None 

a. COKMOL MEASIIRES - 

Eye Protectton: Safety glasses to protect from dust partictes. 

S1cia Protection: gloves are optional for personal convenience. 

Respintory Protection: Avoid breathing dust. Exposure limit: OSHA 8-hr. Time Weighted Average 

(TVWA) for airbome Titanium compounds is 10 mg/m3. If exposure limit is exceeded, use OSHA 

premissible respirator. (See NIOSH Publication No. 76-189 available from HHS IVIOSH, 4676 

Co~a Parirway, Cincinaati, Ohio 45226.) 

Ventilation: Adequate to maintain exposure level above OSHA standards Excessive concentrations of 

nuisance dust in the workroom air may seriously reduce visih lity and ciiuse unpleasant deposits in eyes, 

eara, and nasal passages. 

Other Protectfre C7othing or Equipment: Optional 

Worlk/Hygenic Practices: Do not store near food and drink. 

Tttis im%rmation is Rntdshed without warranty, expressed or implied, except that is accurate to the best 

knowledge of SCC. The data on this sheet relates only to the speci('ic material <lesiened herein. SCC asaumes 

no leg,el responsibility for use or reliance upon these data. 

Page 2 o€2 

e Ore 

: 10/30/85 

~ :. 

~ T j '. 

ID, 
Mar-09-98 02:35P SOUTHERN COLOR CO_ 770 382 8770 P.04 

MATERIAL SAFETY DATA SHEET BB2 

Issue Date: 4/29/91 

N 

l. PRODUCT IDENTIFICATION - 

Product Name . 

Product Code . 

Chemical Family : 

Color Indez Name : 

Color Indez Number . 

DCPlA Numbe r : 

Chemical Name . 

Synonyss . 

CAS Number : 

Formula s 

Chrome Oxide Green 

J5351 - 5360 - 5370 - 5371 

5375 - 5376 - 5377 

Chrome (III) Oxide 

Pigment Green 17 

77288 

3-05-3 

Chromium Oxide 

Chromium Green-Black Hematite 

1308-38-9 

Cr203 

Manufacturer's Name/Address: 

Emergency Telephone No.: 

Mineral Pigments Corporation 

7011 Muirkirk Road 

Beltsville, MD 20705 

301-776-2400 

Supplier's Name/Address: Mineral Pigments Corp./Davis Colors 

7011 Muirkirk Road 

Beltsville, MD 20705 

Emergency Telephone No.: 301-776-2400 

2. HAZARDOIIS INGREDIENTS 

CO!lPONENTS: CAS NO. OSHA-PEL ACGIH-TLV g 

Chrome (III: Oxide 1308-38-9 .500 mg/m3 .500 mg/m3 *TWA Approx 

*TWA 100 

*Chrome (III) Compounds (as Cr) 

---------------------------------------------------------- ------------------- 

3. PHYSICAL DATA - 

Appearance s Powder 

Color : Green 

Odor : Odorless 

Melt Point/Freeze Point: Greater than 1832 F(1000 C) 

Boiling Point : Not Applicable 

Vapor Pressure : Not Applicable 

pfl : 5 to 7 at 50 g/1 water at 68 F(20 C); DIN 53200 

Specific Gravity : 5.2 at 68 F(20 C) 

Solubility in water : Insoluble 

a Volatile by Volume : Not Applicable 

Bulk Density : Approx. 800 kg/m3 at 68 F(20 C) 

------------------------------------------------- -- ------------------ -------- 

HAZARDOIIS MATERIALS IDENTIFICATION SYSTEA (HMIS) 

EIEALTE 0 FLAlM1MABILITY 0 REACTIVITY 0 

Page 1 of 5 

/3~ 
Mar-09-98 02:35P SOUTHERN COLOR CO. 770 382 8770 P.05 

BB2 

-------------------------------------------------- --------------------------- 

4. FIRE AND E%P~OSLON DATA - 

Flash Point F( C) : Not Applicable 

Flammable Limits: Lel - Not Applicable 

Uel - Not Applicable 

Extinguishing Kedia: Use,extinguishing agents that are suitable to the 

surrounding fire. 

Special Fire Fighting Procedures/Onusual Fire or Explosion Hazards: 

Fire fighters should be equipped with self-contained breathing apparatu• 

Under fire conditions irritating and/or toxic aerosols or gases may L 

present. 

5.-HUMAN HEALTH DATA - 

Primary Route(s) of Exposure: Eye Contact; Skin Contact; Inhalation 

Human Effects and Symptoms Of Overexposure: 

Acute : On the basis of animal toxicity testing (See Section 11), we 

would expect this product to be non-irritating to the eyes and 

skin and essentially non-toxic by ingestion. 

Mechanical irritation (ie. abrasion) to the eyes may occur due 

to exposure to fines. Eyes may become red and scratchy and may 

tear. As with all dusty materials, inhalation may cause respiratory irritation, sneezing, coughing and runny nose. 

Chronic: Repeated or prolonged inhalation of trivalent chromium compounds may cause chronic respiratory effects. i 

Carcinogenicity: This product is not listed by NT P, IARC or regulated as a 

carcinogen by OSHA. 

Other : NTP, IARC and ACGIH found that "there is sufficient evidence for 

the carcinogenicity o€ Chromium and Certain Chromium Compounds 

both ir humans and experimental animals" . The Chromium Compounds 

that t - considered carcinogenic are hexavalent chromium compound:: This product is a trivalent chromium cornpound. It is 

not s,: :.fically listed as a carcinogen by NTP, IARC or ACGIH. 

This ;: juct contains an average of less than 50 ppm of leachable 

hexav::: -:-nt chromium (0.0050$) . 

Exposure 

Limits : Not established for this product as a whole, refer to Section 2 

for exposure limits of hazardous constituents. 

Medical Conditions Aggravated by Exposure: 

Persons with pre-existing eye conditions or impaired pulmonary 

function may be more susceptible to the effects of this product. 

1 ACGIH "Documentation of the Threshold Limit Values" 

----------------------------------------------------------------------------- 

Page 2 of 5 

11,16 
Mar-09-98 02:36P SOUTHERN COLOR CO. 770 382 8770 P.06 

BB2 Issue Date: 4/29/91 

6. EMERGENCY & FIRST AID PROCEDUP,ES - 

Eye Contact : Flush eyes with plenty of water, lifting lids periodically for 

at least 15 minutes. Consult a physician if irritation 

persists. 

Skin Contact: Wash with soap and water. 

Inhalation : Remove from dusty area to fresh air. If not breathir.g give 

artificial respiration. If breathing is difficult, give oxygen. 

Call a physician. 

Ingestion : Immediately contact a physician. 

----------------------------------------------------------------------------- 

7. EMPLOYEE PROTECTION RECOMMENDATIONS - 

Eye Protection : Safety glasses 

Skin Protection: Rubber, cloth or plastic gloves if appropriate for job 

conditions. 

Respiratory : Work ambient concentrations should be monitored and if 

Protection the recommended exposure ll mit is exceeded, a NICSH/MSHA 

approved dust respirator should be worn. (Do not e°ceed 

use limits of the respirator.) 

Ventilation : Use local ventilaticn to maintain air levels below the 

recommended exposure limit if dusting is a problem. 

Other : Eye wash stations and washing facilities should be available. Employees should wash their hands and face before 

eating, drinking or using tobacco products. 

S. REACTIVITY DATA - 

Stability: Stable 

Polymerization: Will not occur 

Incompatibility (Materials to avoid): None Known 

Hazardous Decomposition Products: None Known 

9. SPILL OR LEA1C PROCEDURES - 

Steps to be taken in case material is released or spilled: Vacuurn or scoop 

material into an appropriately marked container for reclamation or 

disposal. Spill area can be washed with water. Collect wash water for 

approved disposal. Keep from entering water or ground water. Avoid 

excessive generation of dust. If dust is generated, use a p p r o p r i a t e 

respiratory protection. 

CERCLA (SUPERFIII+ID) Reportable Quantity: None 

Waste disposal method: Material which cannot be recycled into your process 

should be landfilled in accordance with federal, state and local environmental control regulations. 

----------------------------------------------- ------------------------------ 

Page 3 of 5 

/36 
Mar-09-98 02:36P SOUTHERN COLOR CO. 770 382 8770 P_O7 

BB2 

10. SPECIAL PRECAOTIONS 6 STORAGE DATA - 

Storage Temperature (Min/Max): Ambient/Ambient 

Average Shelf Life : 12 months in closed container 

Special Sensitivity : None Known 

(Heat;Light;Moisture) : None 

Precautions To Be Taken In 

Handling and Storing : Avcid breathing dust. Avoid getting in 

eyes or on skin. Wash thoroughly after 

handl ing. Store in a dry place away f rom 

excessive heat . Avoid contact with moistLie. 

Reseal containers immediatelirfter use. 

Store away from food and beverages. 

----------------------------------------------------------------------------- 

11. ANIPlAL TO%ICITY DATA - 

ACDTE - Oral, LD50 ............: Greater than 10,000 mg/kg (Rat). 

Dermal LD50 ........... : Data not established for product. 

Inhalation LC50 ....... : Data not established for product. 

Eye Effects ........... : Mechanical irritation only (Rabbit). 

Skin Effects .......... : Non-irritating to rabbit skin (24 hr). 

Sensitization ......... : Data not established for product. 

Subcbronic Toxicity ... : Data not established for product. 

Chronic Toxicity ...... : Data not established for product. 

Other Toxicity Data ... : (Mutagenic, Teratogenic, Reproductive 

Tests): Mutagenic and teratogenic effects 

cited. 

AQUATIC TO%ICITY ...... :Fish LCo a 1000 mg/1 (Golden Orfe - 

Leuciscus Idus) ; No harmful effects on 

Escherichia Coli at 1000 mg/1; No harmful 

effects on Pseudomonas Fluoresceus at 

10,000 mg/1. 

----------------------------------------------------------------------------- 

12. FEDERAL REGOLATORY INFORPlATION - 

OSHA STATOS ................ : This product is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. 

TSCA STATOS ................: On TSCA Inventory 

CERCLA REPORTABLE QOANTITY.: Chromium and Compounds - no RQ has bt 

established for this generic class. 

SARA TITLE III: 

SECTION 302 EXTREMELY 

HAZARDOOS SOBSTANCES..: None 

SECTION 311/312 

BAZARD CATEGORIES ..... i Immediate Health Hazard; Delayed Health 

Hazard. 

Page 4 of 5 

i3~ 
Mar-09-98 02:37P SOUTHERN COLOR CO. 770 382 8770 P.08 

BB2 Issue Date: 4/29/91 

---------------------------- 

12. FEDERAL REGIILATORY INFORMATION - CONT'D. 

SECTION 313 

TOXIC CHEHICAI.S.......: Chromium Compounds, < 70$ (Total Cr). 

RCRA STATUS ................: When discarded in its purchased form, this 

product meets the criteria of EP Toxicity, 

and should be managed as a hazardous waste. 

(40 CFR 261.20-24) - contains an average of 

50 ppm of hexavalent chromium. 

------------------------------------------------------------------------- 

OTHER REGULATORY INFORMATION 

The following chemicals are specifically listed by individual states; other 

product specific health and safety data, in other sections of the MSDS, may 

also be applicable for state requirements. For details on your regulatory 

requirements you should contact the appropriate agency in your state. 

COIKPONENT NAl4E/CAS NUMBER CONCENTRATION STATE CODE 

Chrome (III) Oxide/1308-38-9 Approx. 100$ PA3; MA; NJ4; 

CN1 

Hexavalent Chromium (Cr+6)/ <50 ppm** CA; AlA 

18540-29-9 

Lead/7439-92-1 1 ppm* CA 

Arsenic/7440-38-2 1 ppm* CA; MA 

Cadmium/7440-43-9 1 ppm* CA; MA 

----------------------------------------------------------------------------- 

CA = California Proposition 65 

MA = Flassachusetts Hazardous Substance List 

`7j4 = New Jersey Other - included in 5 predominant ingredients > 1$ 

?A3 = Pennsylvania Non-hazardous present at 3$ or greater. 

C:dl = Canada WHMIS Ingredient Disclosure List over 1$. 

* Please note that these were random sample analyses and content may vary from 

batch to batch. ** Leachable hexavalent chromium. 

----------------------------------------------------------------------------- 

This information is furnished without warranty, expressed or implied, except 

that it is accurate to the best knowledge of MPC Cotporation. The data on this 

sheet relates oniy to the specific materfal designated herein. MPC Corporation 

assumes no legal responsibility for use or reiiance upon these data. 

--------------------------------------------------------------------------- 

MSDS NO.:BB2 MSDS PAGE 5 

APPROVAL DATE:4/29/91 (Last Page) 

GRNBB2.MSD 

/3~ 
03/03/98 13:28 V217 222 8854 PRIVCE Lab Z002/004 

NPCA - 1114QB B;AZARD RATING 

Health 1 

MATERIAL SAFETY DATA SHEET Flemmability o 

Reactiviry o 

CHEM COPP 75 Ma"'n'~ Perwasl Protection E 

SECiION I AMERICAN CHEMET CORPORATION MANUFACTURER P.O. Boz ll60 

East Helena, MT 59635 

EMERGENCY TELEPHONE (406) 227-5302 ATTN: Dan Britnhall 

CHEMICAL NAMB FORMULA 

CUPROUS OXIDE Cu ZO 

CUPRIC OXIDE Cu0 

METALLIC COPPER Cu 

CAS NUMBER APPROX. WT. `ii 

1317-39-1 3 

1317-38-0 91 

7440-50-8 0.5 

TALC 3 Mg 0.4Si 0 2 H10 14807-96-6 5.5 

SECTION II HAZARDOUS INGREDIENTS 

% TLV & PEL . 

COPPER 75 % (Min) 1 mg/m' 

There is no ACGIH TLV or OSHA PEL for .either cuprous oxide or cupric oAde. Exposute is governed by the g hour TWA estabtished for finely divided copper 

in dusts or mists. Cuproua oxide, cupric oxide and copper are not carcinogenic matetials as liated by OSHA (29CFR1910) or ACGIH (Appendix A, Thresliold Linrit 

Values for Chemical Substances 1989-1990). 

SECTION III PHYSICAL DATA 

Boiling Point (f): Speci6c Gravity: Vapor Pressure: Petcent Volatile by volume: (46): 

NA H=0=1 6.0 NA 0% 

Vapor Densiry: Evaporation 

Rate: Solubility in Water: Melting Point: Appearance and Odor: 

NA NA NegHgible Cupric oxide decomposes at 1847°F to eaprous Black 8nely divided powder. 

oxide and oxygen. Cuprous oxide melts at 2255 °F No odor. 

SECTION IV FIRE & EXPWSION HAZARD DATA 

Flash Point Flammable Linnits 

LEL UEL 

NA NA NA 

Eztinguishing Media: Will not bum. 

Speciai Fire Fighting Ptoadttres: None latown. 

Unusual F'ue Fighring Ptocednres: See Section VI. 

SECTION V HEALTH HAZARD DATA 

Threshold Limit Va1ue: See Section II 

Signs, Symptoms. and Effects of Overezposure: Nansea, chills, diarrhea. May caose respiratory itritation; skin irritation (oaide pox); fever, tye iniffition with retbxse. 

pain and conjunctivitis; preeaisting lung diseases may be aggravated by exposure. Could resultin n:spiratory disease if over ezposed on a chronic basis. 

Primary Routes of Entry: Inhalation and/or ingestion. 

Emergency and First Aid Proctdure: Remove to fresh air. Lay patient down. Cover with bianket. If irtitatad, nush eyes and skin with large volumes of Eresh water 

for 15 minutas. Refer to physician. 

SECTION VI REACTIVITY DATA 

Stable X 'Unstable 

Conditions and Materials to Avoid: Cupric oxide may react violently with strong reductants, e.g., organic compounds, such as but not limlted to hydrazine and aarylene carbide compoands, acids, bases, and metals such as but aot limited to Al, Mg, B, K. Nu, Ti, & 71. 

Haxardous Decompoeition Products: Copper fumes will be released if cuproua oxide is heated above its melting point (2255°). 

Hazardous Polvmerizatioa Will not occur. 

SECTION V II SPILL OR LEAR PROCEDURES 

Steps to be taken in case material is released or spilled. Clean up with vaccurtt or conventional tools. Avoid dusting. 

Waste Disposal: Approved land fill if allowed by local, state and federal authori8es. 

SECTION VIII SPECL4L PROTECTION INFORMATION 

Respiratory Proteaion: Camidge type filter or dust mask approved by MSHA or NOISH. Refer to Respiratory Proteotive Devices approved by Bureatt of Mina 

Circular IC 8436, 

Ventitation: To keep below iisted TLV in Section II, use general dilution type ventilation. 

Protative Gloves: Wear if akin conmct is probable and skin is sensitive. 

Eye Protection: Safery glasses or goggles. 

Othrr Protective Equipment: Long sleeve shirts if contact is probable and skin is sensitive. 

SECTION D{ SPECIAL PRECAUITONS 

Precautions to be taken in handling and storing: Keep lids tighdy sealed. Store io cool, dry piace. 

Other Precautions: Do not take internally. Avoid prolonged contact with skia. Wash with soap and water aRer contact. 

SECTION X SARA TPTLE III 

This product contains copper compounds and is sabject to the reporting requirements of Section 313 of Title III of the Superfund Amendtnenta and Reauthorization 

Aa of 1986 and 40 CFR Part 372, 

Date: February 15, 1991 (Rev. S) 042491 

/3~ 
03/03/98 13:29 ^q217 222 8854 PRINCE Lab Z 003/004 

Material Safety Data Sheet 

Substance Identification 

Identity: ZINC OX1DE CAS #: 1314-13-2 

Trade Names: 

Manufacturer: The Prince Manufacturing Co. Emergency: Chemtrec 

One Prince Plaza 1-800-424-9300 

Quincy, IL 62301 

217-222-8854 

Components and Contaminants 

Chemicai Namei CAS # OSHA PEL ACGIH TLV ercen 

Zinc Oxide (respirabie fraction) 1314-13-2 5 mg/m' 5 mglm3 (TWA) 90-93% Zn0 

Calcium Oxide 1305-78-8 5 mg/m' 5 mg/m' (TWA) 6% Ca0 

Silica, Crystalline Quartz (respirabie) 14808-60-7 0.1 mg/m3 0.1 mg/m3 (TWA) 1.5% SiOZ 

Cobalt Oxide 13455-36-2 -- -- 0.2% Co0 

Physical Data 

Boiling Point: NA Specific Gravity (1-120=1): 5.6 

Vapor Pressure (mm/Hg): NA Melting Point: 1975° C 

Vapor Density (Air-1): NA Evaporation Rate (Butyl Acetate=l): NA 

Solubility In Water: insoiuble 

Appearance and Odor: off white to brown, no odor. 

Fire and Explosion Hazard Data 

Flash Point: Not combustible 

Flammable Limits: LEL NA UEL NA 

Extinguishing Media: Foam, COZ , dry chemical or water. 

Special Fire Fighting Procedures: In the event of fire, wear full protective cfothing and NIOSH-approved 

seif-contained breathing apparatus with full face piece operated in the 

pressure demand or other positive pressure mode. 

Unusual Fire and expiosion hazards: Not combustible. 

Reactivi#y Data 

Stability: Stable under ordinary conditions of use and storage. 

Conditions to avoid: NA 

Incompatibility (materials to avoid): Mineral acids, sulfur, chlorinated hydrocarbons, or magnesium (when 

heated). 

Hazardous Decomposition or Byproducts: None. 

Hazardous Polymerization: Wili not occur. 

Health Hazard Data 

Route of Entry: INHALATION: May irritate the respiratory tract. May increase the 

incidence of upper respiratory infections (pneumonia). 

SKIN: May cause in•itation. 

INGESTION: Zinc Oxide is reiatively non-toxic by mouth but may 

cause abdominal pain and nausea. 

Zinc Oxide, Page 1 

Reviewed: July 1998 Unchanged since Aprfl 1991 

f ~o 
03/03/98 13:30 ^G217 222 8854 PRINCE Lab 1a004/004 

Health Hazard Data (cont.) 

Health Hazards (Acute and Chronic): Metal fume fever may result from prolonged overexposure. 

Carcinogenicity: NTP: No IARC Monographs: Yes (Silica) 

Signs and Symptoms of Exposure: Symptoms of inhalation of excessive zinc dust (metal fume fever) are 

tightness of chest, metallic taste, cough, fever, and chills. Symptoms of 

silicosis include impaired pulmonary function and wheezing. 

Aggravation of Pre-existing Conditions: Persons with impaired respiratory function may be more susceptible to the 

effect of this substance. 

Emergency and First Aid Procedures: IF INHALED, remove to fresh air and seek medical attention for any 

breathing difficuity. 

IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical 

attenfion if red & irritated. 

IN CASE OF EYE CONTACT, flush eyes immediately with water for at least 

15 minutes. Seek medical attention if irritation persists. 

IF INGESTED, induce vomiting immediately by giving two glasses of water 

and sticking finger down throat. Never give anything by mouth to an 

unconscious person. Call a physician immediately. 

Precautions for Safe Handling and Use 

Material Release or Spill Precautions: Should a spiil occur, ventilate area. Clean-up personnel require respiratory 

protection. Recover uncontaminated material for use. Vacuum or sweep 

remaining material, keeping dust to a minimum. 

Waste Disposal Method: Dispose of unreclairnable material in a RCRA-approved waste facility. 

Handting and Storing Precautions: Protect containers from damage and keep ciosed when not in use. 

Other Precautions: Observe good personal hygiene. Wash after handling. 

Control Measures 

Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or is 

anticipated. OSHA standard 1910.134 or ANSI Z88.2-1980 specifications 

are recommended. 

Ventilation: A system of local and/or general exhaust is recommended to keep 

employee exposures below the Airtiorne Exposure Limits. Local exhaust is 

generally preferred because it can control the emissions of the contaminant 

at its source, preventing dispersion of it into the general work area. Please 

refer to the ACGIH document, "Industriai Ventilation, A Manual of 

Recommended Practices", most recent edition, for details. 

Protective Gloves: Yes 

Eye Protection: Safety goggles are recommended. 

Other Protective Ciothing or Equipment: Use other protective equipment when necessary in order to avoid 

prolonged exposure to skin. 

Worfc and Hygienic Practices: Observe good personal hygiene. Wash after handling. 

SARA Title Ili Section 313 Supplier Notification 

This product contains the following toxic chemicals subject to the reporbng requirements of section 313 Emergency 

Planning and Community Right-to-Know Act of 1986 and of 40 CFR 372.45: 

ComRZrtt CAS # % by Weight 

Zinc Oxide 1314-13-2 72-75% Zn 

This information must be included In all MSDS's that are copied and distributed for this material. 

Zinc Oxide, Page 2 

Reviewed: July 1996 Unchanged since April 1991 

i~ll 
COOOR DIVISION 

F=RRO CORRORaTION 

F~~~ ® 

4 ~ G 0 -Ea 57 56tn 5'.i"ccT 

.O. BOx 6550 P

Cl=VclANO. ONIO 4:;01 

TELE?HOV: 12161 641.8580 

~

0 TELcX 98•0165 

ce~.o~ ~~T~~4lAL s ~~~~~ ®~ i A sHEET 

SECTION 1 PFiODUCT IDENTIFICATION 

TRADE NAME AND SYNONYb1S C-292 Blue Pigment 

CHE:'111CAL NAME AND SYNONYUIS Zirconium Vanadium Blue Zircon 

C.I. Pigment Blue #71 

CHEMICAL FAMILY Inorganic Plcment TSCA INVENTORY CAS : 68186-95-8^ 

CHEMICAL FORMULA (Zr,V)SiO 4 C.I. #77998 

SECTION 11 H.^,ZARDOUS INGREDfENTS 

P=IVCI=AL F!AZAP.CCUS CC`.1FCNENi(S) I TLV 3 ` I E ~ ~ ~ -.,c' ~ IS ~S~ GS .- 

mg/:1 P=! (Units; 

Zirconium Compound ' 5.0 ( 5.Omg/M3 

~ 10.0 ~ 10.0mg/M3 Silicate 

I I 

Tnis pigment is forWed by high temperatu-_e calcization. Therefore, it dces not 

nec=ssarily ha•re any cf the properties of its component oxides or metals. 

SECTION lil PHYSICAL DATA 

BOILING POINT Not Appiicabte VAPOR PRESSURE Not Applicable 

MELTING POINT Nct Ap;.ticabte VAPOR DENSITY Nct Applicable 

SPEC1FiC GRAVITY (H 2 0=1) 4.5 EVAPORATiON Not Appticabte 

SOLUBILITY IN WATER NegliSibie VOLATIL: Not Appiicable 

APPEARANCE Blue Odorfess Powder AND ODOR 

SECTION IV F1RE AND EXPLOSION HAZARD DATA 

FLAS1-I POINT Nc: 

METHOD USED Apclicatie 

EXTINGUISHING Nct FLAMh1ASLE Nct 

MEDIA F'.ammabie (EXPLOSIVE) L1tvAlTS Applica='e 

BPEC1AL F1RE FIGHTING Ncne'ne:;tireC 

— PROCEDURES 

UNUSiJAL F1RE AND Nane 

EXPLOSION HAZAROS 

#c 9 ' 
Fi=RRO PRODUCT DESIGNATION C-292 Blue Pigtnent 

ScCTION V HEALTH HAZARD DATA a

HEALTH !-IAZARD DATA 

PRINCIPAL ROUTE.S SK1N AND EYE 

OF AESORPTiON Inhalaticn 8 Ingestion As Nuisance Dust IRRITATION 

RELE VANT SYh1PTOfL1S Dus; from produc: may cause irritation o: the respiratcry system, or 

OF EXPOSURE Nausea or metallic taste in the mou:h. 

EFr=ECTS OF Prclonged expcsure bdust may lead to pulmorary problems. CHRONIC EXPOSURE 

EMERGENCY SRin - wash off contamina;icr, with scap and water. 

AN D FI RST AI D Eyes- flush immediateiy wi;:; c!ean water and call ophthalmolcgist. 

PROCEDURES Irgestion-for excessive ingestion drinlc water or milk.Ca11 a pay ici 

SECTION VI REACTiVITY DATA 

CONDITIONS CONTRIBUTING CONDIT)ONS CONTRIBUTING 

TO INSTABILITY Stable J TO HAZARDOUS POLYMERlZATION Will Not Oc=ur 

INCOMPAT)BILITY 

If.'a;=ria!s to Avoid) . one 

HAZARDOUS DECOPIIPOS1TiON 

PRODUCTS None 

SECTION V11 SPILL OR LEAK PROCEDURES 

STEr=S TO BE TAi{EN IN 

C:.SE r.1ATERt ~,L IS Urcor;amir,a;ed nzte^z! -z :e scccced _,, f^r us:. If ,.ontamira;ed, sc ' x p 

R=L=ASED OR SPILLED 

or vac:.ium into a rece_;zc'e !cr dispcsal. ~"~ 

W,"•,ST= DISPOSAL Use as landfill in acc.,,da-_= wi;h tccai state, arC federal regulation. 

fti1ETl!OD 

SECTION VII1 SPECIAL PROTECTION INFORMATION 

VENTILATION PROTECTiVE EQUIPMENT 

-, Suita b le for dusts not more tcxic than lead. F.E..UIREMENTS EYE Frotec: zgainst dust par,ic!es 

MECHANICAL (GENERAL) Vert dust tc coJector. ~ GLOVES Work gloves (cotton) 

SPECIAL N OZe I RESPIRATOR OSi-iA approved for dust. 

OTHER PROTECTiVE Wear appropriate, clean, pro::c:ive c1c:`fny, suc~ as, but not limited to 

EO U I PFJ1 E NT coveralls, smocks, aprons, gloves. s`ces ar.d/or hats. 

SECTION 1X SPECIAL PRECAUTIONS 

PR E C:.UT10 NS TO B E 

TAKcN IN HANDLING 

Pretec: containers agairst ;,;ysica; t ~ amage. Store in dry area away from feed 

and `ccd produc:s. Avoid m.a:<ir.; d_s;. Cc not ir,haie dust. Do not ingest Wash 

AN D STORAGE hands, forearms, face and t•eck tefcre eatir.g, dr!r.kirg, srn ;,king or aoplying cosmetics. 

Carr::,ogenicicy: ` — trTP? N0 IARC Mo:Ograpns? 

YES 

OSriA Regulated? NO 

This pigmen*_ is a crystalline compound (not a mixture) whose basic 

can be expressed as 100% (Zr,V)SiO4- It does not contain material 

chemical formu-Ta 

reportable under 

SAR?. Tit1e III. 

FARC considers silica a susr. ,_—_t carcinogen. 

~ 

i~&4_zz~' November 1988 

Signature Date 

'The intormation herein is given in gcod fa!'n 5ut no warrar.ry, e:press or irnolied. is made." ~ 

I 

1CC__•?:25 
& FERRO 

COLOR OMSION 

FERRO CORPORATION 

4150 EAST 66tn STREET 

F. o. 13ox 6s5o 

CLEVELAND. OHIO 44101 

TELEPHONE (216) 641-8580 

TELEX 98-0165 

COLOR MATERIAL SAFETY DATA SHEET 

SECTION I PRODUCT IDENTiF1CAT10N 

TRADE NAME AND SYNONYMS 

C-416 Yellow Pigment 

CHEMICAL NAME AND SYNONYMS Zirconium Praseodymium Yellow Zircon _ 

C.I. Pigment Yellow #159 

CHEMICAL FAMILY Inorganic Pigment —T—TSCA INVENTORY CAS *68187-15-5* 

CHEMICAL FORMUI.A (Zr,Pr)SiO 4 C.I. #77997 

SECTION 11 HAZARDOUS INGREDtENTS 

PRINCIPAL HAZARDOUS COMPONENT(S) TLV 3 

mg/M 

ESTABLISHED OSHA 

PEL (Units) 

Zirconium Com ound 5.0 5.Omg/M3 

STEL 3 

lO.Omg/M 

This pigment is formed by high temperature calcination. Therefore, it does not 

necessarily have any of the properties of its component,oxides or metals. 

SECTiON III PHYSICAL DATA 

BOILING POINT Not Appticable VAPOR PRESSURE Not Applicable 

MELTING POINT Not Applicable VAPOR DENSITY Not Applicable 

SPEC1FiC GRAVtTY (H2O=1) 4. 3-4. 7 

EVAPORATION Not Applicable 

SOLUBILITY IN WATER Negiigible VOLATiLE Not Appticable 

APPEARANCE Yellow Odoriess Powder AND OOOR 

SECTION IV FiRE AND EXPLOSION HAZARD DATA 

FLASH POINT Not EXTINGUISHING Not I FLAMMABLE Not 

ME:THOD USED Applicabie I MEDIA Flammable I (EXPLOSIVE) LIMITS Applicable 

SPECIAL F1RE FiGHTING None Required 

PROCEDURES 

UNUSUAL F1RE AND None 

EXPLOSION HAZARDS _7==j 

/_, 1 
FERRO PRODUCT DESiGNAT10N C-416 Yellow Pigment 

SECTION V HEALTH HAZARD DATA 

HEALTH HAZARD DATA 

PRINCIPAL ROUTES 

OF ABSORPTION 

SKIN AND EYE Inhalation 8 Ingestion As Nuisance Dust lRRITATION 

RELEVANT SYMPTOMS Dust from product may cause irritation of the respiratory system, or 

OF FXPOSURE Nausea or metallic taste in the mouth. 

EFF:'.'"`TS OF Prolon ed ex osure tDdust ma Id tl 

g p y

eao pumona rY problems. CHRONIC EXPOSURE 

EMERGENCY Skin - wash off contamination with soap and water. 

AND FIRST AID Eyes- flush immediately with clean water and call ophthalmologist. 

PROCEDURES Ingestion-for excessive ingestion drink water or milk.Ca11 a phy 

SECTION VI REACTIVITY DATA 

CONDITIONS CONTRIBUTING CONDITIONS CONTRIBUTING 

TO INSTABILITY Stable 

[ TO HAZARDOUS POLYMERIZATION Will Not Occur 

1NCOMPATIBILITY 

(Materials to Avoid) None 

HAZARDOUS DECOMPOSITION 

PRODUCTS None 

SECTION VII SPILL OR LEAK PROCEDURES 

STEPS TO BE TAKEN IN Uncontaminated material may be scooped up for use. if contaminated, scoop CASE MATERIAL IS or vacuum into a receptacle for disposal. RELEASED OR SPfLLED 

WASTE DISPOSAL Use as landfill in accordance with (ocal state, and federal regulation. 

METHOD 

SECTION VIII SPECIAL PROTECTION 1NFORMATION 

VENTILATION 

REOUIREMENTS Suitable for dusts not more toxic than lead. PROTECTIVE EOUIPMENT 

EYE Protect against dust particles. 

MECHANICAL (GENERAL) Vent dust to collector. GLOVES Work gloves (cotton) 

SPECIAL None RESPIRATOR OSHA approved for dust 

OTHER PROTECTIVE Wear appropriate, clean, protective clothing, such as, but not Iimited to 

EQUIPMENT coveralls, smocks, aprons, gloves, shoes and/or hats 

SECTION IX SPECIAL PRECAUTIONS 

PRECAUTIONS TO BE Protect containers against physical damage. Store in dry area away from feed 

TAKEN IN HANDLlNG and food products. Avoid making dusL Do not inhale dust Do not ingesL Wash 

AND STORAGE hands, forearms, face and neck before eating, drinking, smoking or aoplying cosmetics. 

— --- - --- -- -- --- - - 

Carcino9erucity 

N 

TP7 NO t/1RC Monograptts? NO OSHA Regulated? NO ! 

This pigment is a crystalline compound (not a mixture) whose basic chemical formula can 

be expressed as (ZrPr) SiO 4 . It does not contain material reportable under SARA Title 

III Section 313. 

It may be adjusted with silica which IARC considers a suspect carcinogen. 

OF 

June, 1989 

Sig ature Date 

'The information herein is given in good faith but no warranty, eYpress or implied, is made' 

10052-2/85 

-ESSENTIALLY SIMIUiR' TO FORM OSHA-20 

~ a~ 

ic 
;-790, C-790EZ 

Revision of 

02/06/95 

Page 1 of 4 

Ferro Corporation ??:: Color Division 

P.O.Box 6550 

Cleveland, Ohio 44101 

PH:(216)641-8580 FAX:(216)641•8831 

GRAY 

Emergency Phone : (216)641-5324 

1. Identification of the substance/preparation and the company/undertaking 

2. Composition/information on ingredients 

CAS NUMBER: 68186890* 

CHEMICAL NAME OF THE SUBSTANCE: Black 25 

This pigment may be adjusted using Kaolin (CAS #: 1332-58-7*) 

CHEMICAL FORMULA: (Co.Ni)O:ZrSiO4 

CHEMICAL NAME: Cobalt Nickel Gray Periclase 

CHEMICAL FAMILY: Inorganic Pigment 

C.I. NUMBER: 77332 

3. Hazards identification 

EMERGENCY OVERVIEU: An inorganic powder that poses little or no immediate hazard. 

It will not burn in a fire. 

Repeated or prolonged breathing of any dust may cause lung damage. 

ROUTES OF ENTRY: * Inhalation: 

* Ingestion 

INHALATION: Dust from the product may cause irritation of the respiratory system, 

nausea. or a metallic taste in the mouth. 

ING'cSTION: The product has low solubility in body fluids. Ingesting small amounts is unlikely to 

cause any severe health risks. 

SKIN & EYE CONTACT: May irritate eyes and skin. 

Acts as nuisance dust. 

MEDICAL CONDITIONS: Some inhalation and skin disorders may be aggravated by exposure to this compound. 

CHRONIC EXPOSURE: Prolonged exposure to dust may lead to pulmonary problems. 

HMIS HAZARD CLASS: Health: 1* Fire: 0 Reactivity: 0 

4. First aid measures 

INHALATION: Move to fresh air. 

INGESTION: Far excessive ingestion, drink water or milk. Call a physician. Never give anything by 

mouth to an unconscious person. 

EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. 

SKIN CONTACT: Nash off immediately with saap and plenty of water. 

110 
A

~.y:~~~~ :<:::>?:':::':><::::: ; R evi 'i :;:::~~ ;:.;:.;:.;:.;:.;;:.::.>:.;;: s on of <.;: ;;:.: : : .; «;: : : . :.. :. : . : : . . . . . 

:.>:::>::>::>::::>:;:::>::< ?:>;;::::<;:>:::::::::»:: ......:::...:.: >:=. . ,. . ...... 02 06 95 :::..................,. ... .... .. ..:. ::. .........:.::.:.:::. ........::.:::::::................................::::::::::::::. / / 

. . .. .... . .. ... . . . ... ., . . ., .. . .,, . .,:. ., . .,~: ::,,.,.,,, . . ..: .., ., . .. ...., ..,,,, ., . ..... ...... ... . . . .. . . . .... . .... ........ .......... ...... .. . .. Ferro Corporation ;;;; Color Division 

P'O.Box 6550 

C-790, C-790EZ Page 2 of 4 Cleveland. Ohio 44101 

PH:(216)641-8580 FAX:(216)641-8831 

GRAY 

5. Fire-fighting measures 

EXTINGUISHING MEDIA: * ABC Dry Chemical, or 

* Water 

SPECIAL PRCCEDURES: No special firefighting procedures are required. 

UNUSUAL FIRE HAZARDS No unusual fire or explosion hazards exist. 

NFPA HAZARD CLASS: Health: 1 Fire: 0 Reactivity: 0 

6. Accidental release measures 

Avoid dusting. Uncontaminated material may be scooped up for use. If contaminated. scoop or vacuum into a 

receptacle for disposal. Certain spills may require National Response Center (800-424-8802) notification. 

7. Handling and storage 

" Protect containers against physical damage. 

Store in a dry area away from feed and food products. 

Wash thoroughly after handling. 

8. Exposure controls / personal protection 

EXPOSURE CONTROLS: 

CAS 7'r: 7440-48-4 Cobalt metal, dust, and fume (as Co) 

OSHA PEL: 0.10 mg/m3 

ACGIH TLV: 0.02 mg1m3 

CAS #: 7440•02-0 Nickel, Metal & Insoluble Compounds (as Ni) 

OSHA PEL: 1.0 mg/m3 

ACGIH TLV: 0.05 mg/m3 

CaS 7'r: 7440-07-7 Zirconium Compounds, (as Zr) 

OSHA PEL: 5.0 mg/m3 

ACGIH TLV: 5.0 mg/m3 

ACGIH STEL: 10.0 mg/m3 

CAS #: 1332-58-7 Kaolin 

OSHA PEL: None 

ACGIH TLV: 2 mg/m3 (resp. fraction of dust) 

This pigment is formed by high temperature calcination. Therefore, it does not necessarily have any of the 

properties of its component oxides or metals. 

VENTILATION: Use local exhaust ventilation to keep air contaminants below their PEL's while using this 

product. 

PERSONAL PROTECTION: 

PRoTECTIVE EQUIPMENT xSafety glasses (to protect eyes against dust) 

xCotton work gloves 

=Protective clothing, such as, but not limited to coveralls, smocks, shoes, and/or hats 

RESPIRATORY: Use a NIOSH approved respirator for dust. 

WCRK PRACTICES: Avoid making dust. 

Da not breath or eat dust. 

Use only with adequate ventilation. 

dash thoroughly before eating, drinking, smoking, or applying cosmetics. 

, y ~ 
R e v' is o i n of 

............ .. ..... 

••• ••~~~- 02/06 /9 5 

...............................,.,,..,.....,......,,,..,,,.,,,,.~, 

.... Ferro Corporation •••• .... Color Division 

P.O.Box 6550 

1-790, C-790EZ Page 3 of 4 Cleveland, Ohio 44101 

PH:(216)641-8580 FAX:(216)641-8831 

GRAY 

9. Physical and chemical properties 

Aggregation : Not Applicable Colour : Gray 

Odour : Odorless pH (at conc.) : Not Available 

Boiling Point : Not Applicable Melting Point : Not Available 

Flash Point : Not Applicable Flammability : Does not Burn 

Autoignition : Not Applicable Explosivity : Not Applicable 

Oxydation : Not Applicable Vapour Pressure : Not Applicable 

Density : 5.1-5.3 Solubility (water) : Negligible 

Solubility (others) : Not Available 

Form : Powder. 

10. Stability and reactivity 

STABILITY: Stable at normal conditions. 

POLYMERIZATION: Hazardous polymerization will not occur. 

INCOMPATIBILITY: Nane expected 

BY-PRODUCTS: Ncne expected 

CONDITIONS TO AVOID: Nane 

1. Toxicological information 

CARCINOGENICITY NTP: YES IARC MONOGRAPH: YES OSHA REGULATEJ: NO 

Cobalt and cobalt compounds. as a group, are listed by IARC as possibly carcinogenic to humans (Group 2B). 

However, no data has been found on the cobalt compound in this product to indicate that it is carcinogenic. 

Nickel and nickel compounds are listed by IARC as carcinogens (Group 1). However. IARC states 'this applies to the 

group of chemicals as a whole and not necessarily to all individual chemicals within the group.' No data has been 

found on the nic!cel compound in this product to indicate that it is carcinogenic. 

LD50/oral/rat : N/A 

LD50/derm./rat : N/A 

LC501inh/lh/rat : N/A 

12. Ecological information 

Ecological injuries are not known or expected under normal use. 

13. Disposal considerations 

RCRA INFORMATICN: Tnis material does not meet RCRA's characteristic definition of ignitability, corrosivity, 

cr reactivity. It is not listed in 40 CFR 261.33. Contact the Regulatory Specialist in 

the Color Division R&D Laboratory for any Toxicity Characteristic Leaching Procedure 

(TCLP) data. 

/-` ~ 
- 

>~~~ < ::::: >::>:<`:><::>:«::;::;<:.<::;::;?<: :::i #:.`~~ €:~iw ...:.::..:.................:.,.::.................. Revision of :::<:::::z:i:: ~>_<::i::<~;:::[:<'.:i:<::<:>::>:::: ::'>~ ?::<:'<:::>:s>:::> ~ ::::::~:::>:»::>::> ~:>::>:::<: : :;: < 

........ 

.: 

............ 

::::.:::::::::::::.:..:. .... :, 

»::>:<> :~«:::> ~:«<.:;:::;:<:: »::>::»::;:: 02 6 / 0 95 / ` '"'~ • Ferro Corporation ;;;; Color Division .................:.;::•::;:: 

................. ~::.;;; :•:::•::. . . . ......... ... . ..... 

P.O.Box 6550 

(',-790, C-790EZ Page 4 of 4 Cleveland. Ohio 44101 

PH:(216)641-8580 FAX:(216)641-8831 

GRAY 

14. Transport information - 

DOT: Not regulated. 

IATA: Not regulated. 

CERCLA RQ: None 

15. Regulatory information 

SARA TITLE III: The approximate percent compound and metai reportable under SARA Title III, Section 313 is 

listed below. 

Cobalt Compound X: 80-100 

X Co: 5 

Nickel Compound X: 80-100 

X Ni: 16 

TSCA:. This product and/or its component(s) are listed on the Toxic Substances Control Act (TSCA) 

Chemical Substance Inventory. 

This substance is not subject to Section 12(b) of TSCA (Export Notification). 

16. Other information 

KEY: ACGIH = American Confernece of Governmental Industrial Hygenists 

05hiA = Occupational Safety and Health Administration 

TLV = Threshold Limit Value 

PEL = Permissable Exposure Limit 

(C) = Ceiling 

mppcf = Millions.of particles per cubic foot of air 

STEL = Short-Term Exposure Limit 

N/A = Not Available 

est = estimated 

DISCLAIMER: Judgement as to the suitability of information herein or to the purchaser's purposes are 

the purchaser's responsibility. Reasonable care has been taken in the preparation of this 

information, but FERRO EXTENDS NO WARRANTIES. MAKES NO REPRESENTATIONS AND ASSUMES NO 

RESPONSIBILITY OF THIS INFORMATION FOR ANY PURCHASER'S US"c OR FOR ANY CONSEQUENCES OF ITS 

USE. 
& FERRO 

COLOR DIViSION 

FERRO CO?PpRxTICN 

41fi0 EA$T 56Ih $TR=-;' 

P.O. 90X 655c) 

CLcVELA40, OHlO 4-:C1 

TcLc?HGYE (216) 6 4 1•853C 

T°_L;X 98-0165 

GOLOI:t MAi`ERIAL SAIFETY DATA SHSET 

SECTION I PRODUCT IDENTIFICATION 

TRADE NAME AND SYNONYMS C-892 Peach Pigment 

CHEMICAL NAME AND SYNONYMS Zirconium Iron Pink Zircon 

C.I. Pigment red 232 

CHE?VIICAL FA1/tILY Ir,crca: -;ic F;cmen; I TSCA INVENTORY CAS : 68 4_2- 79- 3* 

CHEMICAL FORMULA (Zrre)SiO 4 C.I. -r77995 

SECTION II HAZARDOUS INGREDiENTS 

FF'i1.NCIFAL I-fr.Z.ZnZCUS COlia:-ONENi(Si T~ 73 

mg/'q 

EJTi,ELISi-iED 05-::- 

PE: (Units) 

Zirconium Silicate as Zr j 5.0 I 5.Oag/m3 

I ~ 

l I 

This pigment is formed by high temperature calcination. 

necessarily have any of the properties of its component 

Therefore, 

oxides or 

it does not 

metals. 

SECTION 1t1 PHYSiCAL DATA 

BOILING POINT Not Applicable VAPOR PAESSURE Not Applicable 

MELTING POINT Not Appticable VAPOR DENSITY Not ApGticable 

SPECIFIC GRAVITY (H2 0=1) 4.5 EVAPORATION Not Aptrlicable 

SOLUBILITY IN WATER NegliSicle I VOLATILE Not Appticable 

APPEARANCE Peach Odorless Powder AND OOOR ~ 

SECTION IV FIRE AND EXPLOSION HAZ,ARD DATA 

FLAS'ri PO(NT Nct EXTiNGU1SHING Not FLAP.1*.iABLE 

METHC)O USED Apclicat!e MEDIA Fiammable (EXPLOSIVE) LIMITS 

JSPECIAL FIRE FIGi=TiNG None Required 

PROC'cDURES 

UNUSL'AL FIFiE AND None 

EXi-L.^.SiCN H"•ZARDS - 

Not 

Applicacle 
FcnRO PRODUCT DESIGNATION C-39' Pa.:ca Pigment 

SECT10N V H_ALTH HAZARD DATA 

HE=,LTi-I HAZARD DATA 

PRINCiPAL ROUTES SiCIN AND EY= 

OF A?SORPTION ln-a ~ ation d fr:es;icn 

IRRITATION %^s Nuisance Dust 

REL=VAVT SY;IAPTOMS Dus; `ron pr cduc. r ay cause irritaticn of the respiratc:; s.:s;ern, or 

OF cXrOSURE Nausea or metailic tas;e in the mouth. 

G F r EC T S O F Prclonged expcsure M dust may fead to pulmcnary ;,r„cie -s. 

CH:;ONIC EXPOSURE 

EMERGENCY Siin - wash off contamir,ation with soap and water. 

AND FiRST AID Eyes-flush innee:ate!v with c!ean water ar.d alI op"`airno!cyist. 

PRCCEDURE S fr_=_sticn ior escess:ve in,est_cn ~ driz: .:ater or nl?k.Ca11 a phv _c:aSECTiON VI REACTIVI T Y DATA 

CONDITIONS CONTctIBUTING CONDITIONS CONTRI=UTING 

TO INSTABILIT'f Sta:le I TO HAZARDOUS POLYME=cIZi,T10N =il Nct Cccur 1 

INCOrAPATI=IL1 i f I 

Avoidl tione ` 

HAZr,RDOUS DECCfL1POSITION 

PF.00UCTS . 

r one 

SEC T tON V11 SP1LL OR LSAK PROCSt7URES 

SECTION V111 Se-EC1AL PROT'eCTiON 1Ne'-ORMA7 iON 

V=NTILATiON I PROTE CTIVE E•.;UIPMENT 

RECUIR=ME?VT5 Sui,atle jor dusts not ,more toxic than lead ='±= Prctec: ac2!rs; cust pai—tiC:es. 

MEC:-;ANICAL (GENERAL) Vent dust ;e collec:or. ~ GLOVES Work gloves (co;:orn) 

SP_CIAL None ~ RESPiRATOR OS1A apprcved `.cr _ust 

OTFi ER PROTECTIVE Wear appropriate, clean, protective clothing, such as, t::: not Iirnited to 

EOUI P":1 ENT coveralls. smocks, apror.s, gloves, shoes and/or thats. 

SECTION (X SPECIAL PRECAU i IONS 

P;=,=CAJTIONS TO BE P-ctec: containers against physical damaSe. Store in c: f area away from feed 

TA'rC='V iN HANDLING and tocd products. Avoid making dust. Cc not ir.hale =_st. Do not ingest. v.'ash 

AND STOFI;,GE hands, forearms. face and neck 5efcre eatiry, drinki _ s-akir.g or applyPnc -csmetics. 

CQr~x^.y °ntc:,y: Nir, ? ~ 0 -- IARC Mcnog2^ns? ;T,s OSiv4 Regutated? \0 

T _.J 

_—is pier.nent is a crystalline compound (not a mitture) whose basic chemical formula 

ca:: 5e e::pr=_ssed as 100". (ZrFe1SiO4. It does not contain ^aterial reportable under 

S.-~_RA Tit1e III. 

LARC considers silica a suspect carcinoge*>.. 

~ November, '1988 

sic-a:::re Cate 

i ne :nicr r.at!o nerein :s .r.er. ,. ; „p `zr,.. Cut :9Q warrz.^•ty. exore-: - , = -_. :s ':1aQe. 

t 

~ 
FILE No. 988 03iO3 '98 16:35 ID:COLOR CUSTOf1ER SERVICE 2166418831 PAGE 5 

C-1802 

MAROON 

Revision of 

02/03/95 Ferro Corporation ;;;; Color Division 

P.O.Box 6550 

Pa g e 1 of 4 Cleveland, ohio 44101 

PH:(216)641-8580 FAX:(216)641•8831 

Emergency Phone : (216)641-5324 

1. Identification of the substance/preparation and the company/undertaking 

2. Composition/information on ingredients 

CAS NUMBER: 68187122* 

CHEMICAL NAME OF THE SUBSTANCE: Red 233 

This pigment may be adjusted using Kaolin (CAS #: 1332•58•7*). 

CHEMICAL FORMULA: Ca0:Sn0:Si02:Cr203 

CHEMICAL NAME: Chrone Tin Pink Sphene 

CHEMICAL FAMILY: Inorganic PIgment 

C.I. NIIMBER: 77301 

3. Hazards identification 

EMERGENCY OVERVIE41: An inorganic powder that poses little or no iiemediate hazard. 

IL will not burn in a fire. 

Repeated ar prolonged breathing of any dust may cause lung daeage. 

ROUTES OF ENTRY; * Inhalation: 

* Ingestion 

INHALATION: Dust from the product may cause irritation of the respiratory system, 

nausea, or a metallic taste in the mouth. 

INGESTION: The product has 1ow solubility in body fluids. Ingesting swall aeounts is unlikely to 

cause any severe health risks. 

SKIN 8 EYE CDNTACT: May irritate eyes and skin. 

Acts as nuisance dust. 

MEDICAL CONDITIONS: Sose inhalation and skin disorders may be aggravated by exposure to this conpound. 

CHRONIC EXP05URE: Prolonged exposure to dust may lead to pulmonary problems. 

HMIS HAZARD CLASS: Health: 1* Fire: 0 Reactivity: 0 

4. First eid measures 

INHALATION: Move to fresh air. 

INGESTION: For excessive ingestion, drink weter or nilk. Call a physician. Never give anything by 

mouth to an unconscious person. 

EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. 

SKIN CONTACT: wash off imnediately with soap and plenty of water. 

~~~ 
FILE No. 988 03iO3 '98 16:35 ID:COLOR CUSTOf1ER SERVICE 2166418831 PAGE 6 

C-1802 

MAROON 

Revision of 

02/03/95 

Page 2 of 4 

Ferro Corporation ;; Color Division 

P.O.Box 6550 

Cleveland, Ohio 44101 

PH:(216)641•8580 FAX:(21E)641-8831 

5. Fire-fighting measures 

EXTINGUISHING MEDIA: * A8C Dry Chemical, ar 

* Water 

SPECIAL PROCEDURES: No special firefighting procedures are required. 

UNUSUAL FIRE HAZARDS No unusual fire or explosion hazards exist. 

NFPA HA7ARD CLASS: Health: 1 Fire: 0 Reactivity: 0 

B. Accidental release measures 

Avoid dusting. Uncontaminated material may be scooped up for use. If conta inated. scoop or vacuum into ii 

receptacle for disposal. Certain spills may require National Response Center (800-424-8802) notification. 

7. Handling and storage 

Protect containers against physical damage. 

Store in a dry area away from feed and food products. 

wash thoroughly after handling. 

8. Exposure controls / personal protection 

EXPOSURE CONTROLS: 

CAS 7440-47-3 Chromium (III) Coapounds (as Cr) 

OSHA PEL: 0.5 mg/0 

ACGIH TLV: 0.5 Ng/m3 

CAS 7440-31-5 Tin, Inorganic Cowpounds, (as Sn) 

OSHA PEL: none (OSHA excludes oxides) 

ACGIH TLV: 2.0 ag/m3 

CAS 1332-58-7 Kaolin 

OSHA PEL: None 

ACGIH TLV: 2 Mg/m3 (resp. frection of dust) 

This pigment is forsed by high temperature calcination. Therefore, it does not necessarily have any of ttie 

properties of its conponent oxides or setals. 

VENTILATION: Use local exhaust ventilation to keep air contaminants below their PEL's while uiing this 

product. 

PERSONAL PROTECTION: 

PROTECTIVE EQUIPNENT *Safety glasses (to protect eyes against dust) 

*Cotton work gloves 

*Protective clothing. such as, but not limited to coveralls, sieocks, shoes, andlor hats 

RESPIRATORY: Use a NIOSH approved respirator for dust, 

WORK PRACTICES: Avoid making dust. 

Do not breath or eat dust. 

Use only with adequate ventilation. 

Wash thoroughly before eating, drinking, smoking, or applying cosmetics. 

I 53 
FILE No. 988 03%03 '98 16:36 ID:COLOR CUSTOf1ER SERVICE 21664188:21 PAGE 7 

Revision of 

02/03/95 

C- 1$02 Page 3 of 4 

MAROON 

9. Physicai and chemical properties 

Ferro Corporation :;;: Color Division 

P.O.BoX 6550 

Cleveland, Ohio 44301 

PH:(216)641-8580 FAX:(216)641-8831 

Aggregation : Not Applicable Colour : Maroon 

Odour : Odorless pH (at conc.) : Not Available 

Boilirng Point : Not Applicalbe Melting Point : Not Availuble 

F1ash Point : Not Applicable Flaeumability : Does not Burn 

Autoignitien : Not Applicable Exptosivity : Not Applieable 

oxydation : Not Applicable Vapour Pressure : Not Applicable 

Density : Not Available Solubility (water) : Negligible 

Solubility (others) : Not Available 

Form : Powder. 

10. Stability and reactivity 

STABiLITY: Stable at normal conditions. 

POLYHERIZATION: Hazardous polymerization uill not occur. 

INCOMPATIBILITY: None expected 

8Y-PRODUCTS: None expected 

CONOITIONS TO AVOID: None 

11. Toxicological information 

CARCINOGENICITY NTP: NO IARC MONOGRIIPH= NO OSHA REGULATED: NO 

LD50/orallrat : N/A 

LD50/derm./rat : N/A 

LC50/inh/lh/rat ; N/A 

12. Ecological information 

Ecological injuries are not known or expected under norAlal use. 

13. Disposai considerations 

RCRA INFORHIITION: This material does not meet RCRA's characteristic definition of ignitability, corrosivity, 

or reactivity. It is not listed in 40 CFR 261.33- Contact the Regulatory Specialist in 

the Color Division R&D Laboratory for any Toxicity Characteristic Leaching Procedure 

(TCLP) data. 

14. Transport information 

DOT: Not regulated. 

IATA: Not regulated. 

CERCLA Rp: None 

/JY 
—

FILE No. 988 03iO3_'98 16:36 ID:COLOR CUSTOf1ER SERVICE 2166418831 PAGE 8 

C-1802 

Revision of 

02/03/95 

Page 4 of 4 

Ferro Corporation ;;6E Color Division 

P.O.Box 6550 

Cleveland, Ohio 44101 

PH:(216)641•8580 FAX:(216)641•8831 

MAROON 

15. Regu{atory information 

SARA TITLE III: The approximate percent compound and metal reportable urlder SARA Title III. Section 313 is 

listed below. 

Chramium Compound X: 80-100 

X Cr: <1 

TSCA; This product and/or its component(s) are listed on the Toxic Substances Control Act (TSCA) 

Chemical Substance Inventory. 

This substance is not subject to Section 12(b) of TSCA (Export Notification). 

16. Other information 

KEY: ACGIH o American Confernece of Governieental Industrial Hygenists 

OSHA - Occupational Safety and Nealth Adsinistration 

TLV = Threshold Limit Value 

PEL = Permissable Exposure Limit 

(C) = Ceiling 

mppcf = Millions of particles per cubic foot of air 

STEL F Short•Term Exposure Limit 

N/A = Not Available 

est a estimated 

DISCLAIMER: Judgement as to the suitability of inforination herein or to the purchaser's purposes are 

the purchaser's responsibility. Reasonable care has been taken in the preparatiori of this 

information, but FERRO ExTENDS NO WARRANTIES. MAKES NO REPRESENTATIONS AND ASSUMES NO 

RESPONSIBILITY OF THIS INFORMATION FOR ANY PURCHASER'S USE OR FOR ANY CONSEOUENCES OF ITS 

USE. 

~5~ 
FILE No. 988 03iO3 '98 16:37 ID:COLOR CUSTOf1ER SERVICE 2166418831 FAGE 9 

F-3794 

BLaCK 

Revision of 

02/06/95 Ferro Corporation ; Color Division 

P.O.Box 6550 

Page 1 of 4 Cleveland. Ohio 44101 

PH:(216)641-8580 FAX:(216)641•8831 

Emergency Phone : (216)641-5324 

1. Identification of the substance/preparation and the company/undertaking 

2. Composition/information on ingredients 

CAS NUMBER: 68186970* 

CHEMICAL NAME OF THE SUBSTANCE: Black Z7 

This pigment may be adjusted using Kaolin (CAS #: 1332-58•7*). 

CHEMICAL FORMULA: (Co.Fe)(Fe.Cr)204:Ni0:Si0Z 

CHEMICAL NAME: Iron Cobalt Chromite Black Spinel 

CHEMICAL FAMILY: Inorganic Pigment 

C,I. NUMBER: 77502 

3. Haiards identification 

EMERGENCY OVERVIEII: An inorganic powder that poses little or no imqediate ha2ard. 

It will not burn in a fire. 

Repeated or prolonged breathing of any dust may cause 1Ung damage. 

ROUTES OF ENTRY: * Inhalation; 

* Ingestion 

INHALATION: Dust from the product may cause irritation of the respiratory systea. 

nausea. Dr a metallic taste in the mouth. 

INGESTION: The product has low solubility in body fluids. Ingesting small amounts is unlikely to 

cause any severe health risks. 

SKIN 3 EYE CONTACT: May irritate eyes and skin. 

Acts as nuisance dust. 

MEDICAL CONDITIONS: Some inhalation and skin disorders may be aggravated by exposure to this coapound. 

C!!RONIC El(POSURE: Prolonged exposure to dust Uay lead to puleonary problems. 

HM1S HAZARD CLASS: Health: 1* Fire: 0 Reactivity: 0 

4. First aid measures 

INHALATION: Move to fresh air. 

INGESTION: For excessive ingestion. drink water or milk. Ca11 a physician. Never give anything by 

mouth to en unconscious person. 

EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a phyaician. 

SKIN CONTACT: Wash off immedlately with soap and plenty of water. 

0 
FILE No. 988 03iO3 'C8 16:37 ID:COLOR CUSTO(1ER SERVICE 2166418831 PAGE 10 

~` Revision of 

MR, :; .. F '~, ^ 02/06/95 

~'~k.. $. ~fi. ... ~;~..+~t~''.~~i'Sa'k ~ .n ;..;~.'r.. ~ .,.. . ~~

F-3794 Page 2 of a 

BLACK 

S. Fire-fighting measures 

EXTINGUISHING MEDIA: * ABC Dry Chemicat, or 

* Water 

SPECIAL PROCEDURES: No special firefighting procedures are required. 

UNUSUAL fIRE HAZARDS No unusual fire or explosion hazards exist. 

NFPA HAZARD CLASS: Health: 1 Fire: 0 Reactivity: 0 

6. Accidental release measures 

Ferro Corporation i::: Color Division 

P.O.Box 6550 

Cleveland. Ohio 44101 

PH:(216)641-8580 FAX:(216)641-8831 

Avoid dusting. Uncontaminated material may be scooped up for use. If contarinated, scoop or vacuum into a 

receptacle for disposal. Certain spills may require National Response Center (800-424•8802) notification. 

7. Handling and storage 

Protect containers against physical damage. 

Store in a dry area away fron feed and food products. 

Wash thoroughly after handling. 

8. Exposure controls / personal protection 

EXPOSURE CONTROLS: 

CAS #: 7440-48-4 Cobalt metal, dust, and fume (as Co) 

OSHA PEL: 0.10 mg/m3 

ACGIH TLV: 0.02 mg1m3 

CAS #: 74d0-47•3 Chromium (II1) Compounds (as Cr) 

OSHA PEL: 0.5 mg/m3 

ACGIH TLV: 0.5 mg/0 

CAS #: 7440-02-0 Nickel, Metal 6 Insoluble Coapounds (as Ni) 

OSHA PEL: 1.0 mg/m3 

ACGIH TLV: 0.05 mg/0 

CAS $: 1332-58-7 Kaolin 

DSHA PEL: None 

ACGIFi TLV: 2 mg/0 (resp. fraction of dust) 

This pigment is forroed by high temperature calcination. Therefore, it does not necessarily have any of the 

properties of its component ozides or metals. 

VENTILATION: Use local exhaust ventilation to keep air contaminants below their PEL's while using this 

product. 

PERSONAL PROTECTION: 

PROTECTIVE EQUIPMEHT *Safety glasses (to protect eyes against dust) 

*Cotton work gloves 

*Protective clothing, such as, but not limited to coveralts. smocks. shoes, and/or hats 

RESPIRATORY: Use a NIOSH approved respirator for dust. 

V10RK PRACTICES: Avoid making dust. 

Do not breath or eat dust. 

Use only with adequate ventilation. 

Wash thoroughly before eating, drinking, seoking, or applying cosmetics. 

h/ 

Iv 
FILE No. 988 03iO3 '98 16:37 ID:COLOR CUSTOf1ER SERVICE 2166418831 PAGE 11 

p ~b: "~~ ~i~a ' ' `~;~ .:Y9.~3.: a• ,i s a3 ^ ~ g,~

'r ° ~ • • 

• i 

F-3794 Page 3 of 4 Cleveland , ohio 44101 

PH:(216)641•8580 FAX:(216)641-8831 

BLACK 

9. Physical and chemical properties 

Aggregation : Not Applicable Colour : Black 

Odour : Odorless pH (at conc.) : Not Available 

Boiling Point : Not Applicable Melting Point : Not Available 

Fiash Point : Not Applicable Flammability : Does not Burn 

Autoignition ; Not Applicab)e Explosivity : Not Applicable 

Oxydation : Not Applicable Vapour Pressure : Not Applicable 

Density : 5.0•5.4 Solubility (water) : Negligible 

Solubility (others) : Not Available 

Form : Powder. 

10. Stability and reactivity 

STABILITY: Stable at normal conditions. 

POLYMERIZATION: Hazardous polyrserization will not occur. 

INCOMPATIBILITY: None expected 

BY-PRODUCTS: None expected 

CONDITIONS TO AVOID: None 

11. Toxicological Information 

CARCINOGENICIT'r NTP: YE5 IARC MONOGRAPH: YES oSHA REGULATED: NO 

Cobalt and cobait compounds, as a group, are listed by IARC as possibly carcinogenic to humans (Group 2B). 

However, no data has been found on the cobalt compound in this product to indicate that it is carcinogenic. 

Nickel and nickel compounds are listed by IARC as carcinogens (Group 1). However. IARC states `this applies to the 

group of chereicals as a whole and not necessarily to all individual chemicals within the group•' No data has been 

found an the nickel conraound in this product to indicate that it is carcinogenic. 

LD50/oralirat : N/A 

LD50/derm./rat : N/A 

LC50/inh/lh/rat : N/A 

12. Ecological information 

Ecological injuries are not known or expected under normal use. 

13. Disposal considerations 

RCRA INFORMATION: This material does not meet RCRA's charecteristic definition of ignitability. corrosivity, 

or reactivity. It is not listed in 40 CFR 261.33. Contact the Regulatory Specialist in 

the Color Division R6D Laboratory for any Toxicity Characteristic Leaching Procedure 

(TCLP) data. 

/54?1~' 
FILE No. 988 03iO3 '98 16:38 ID:COLOR CUST0MER SERVICE 2166418831 PAGE 12 

:•~;~~>~• ~ t ~ ~rs ~ . Revision of 

:~t. s~~ ; r,::;~.° ;~~! . .. ~. .. , ~ . .;.r.~s::~(•;~•h,~~~:>3:;+:.. . ., . ,. ... .:h 02106/95 Ferro Corporation .... Calor 01Wsion 

P.O.Box.6550 

F-3794 Page 4 of 4 Cleveland. Ohia 44101 

PH:(216)641•8580 FAX:(216)641-8831 

BLACK 

14. Transport information 

DOT: Not regulated. 

IATA: Nat regulated, 

CERCLA Rp: None 

15. Regulatory information 

SARA TITLE III: The approximate percent compound and metal reportable under SARA Title fII, Sectien 313 is 

1 i sted bel ovr. 

Cabalt Compound X: 75-100 

X Co: 24 

Chromium CcWound x: 75-100 

X Cr: 17 

Nickel Compound X: 75-100 

X Ni: 14 

TSCA: This product and/or its coeiponent(s) are listed on the Toxic Substances Cantrol Act (TSCA) 

Chemical Substance Inventory. 

This substance is not subject to Section 12(b) of TSCA (Export Notification). 

16. Other information 

KEY: ACGIH American Confernece of Governmental Industrial Hygenists 

OSHA Occupational Safety and Health Administration 

TLV = Threshold Limit Value 

PEL = Permissable Exposure Limit 

(C) = Ceiling 

mppcf o Millions of particles per cubic foot of air 

STEL = Short-Term Exposure Limit 

N/A - Not Available 

est = estimated 

DISCLAIMER: ]udgement as to the suitability of information herein or to the purchaser's purposes are 

the purchaser's responsibility. Reasonable care ha9 been taken in the preparation of this 

information, but FERRO EXTENDS NO IiARRl1NTIES. MAKES NO REPRESENTATIONS AND ASSUMEb NO 

RESPONSIBILITY OF THIS INFORMATION FOR ANY PURCHASER'S USE OR FOR ANY CONSECUENCES OF IT5 

USE, 

ih', 
V. Description of Brick and Structural Clay Product Manufacturina Processes 

A. Please provide a simple process flow diagram for each brick and structural clay 

product manufacturing process line. An example process flow diagram is provided 

in Figure 1. A diagram of the plant layout with all processes and emission points 

clearly labeled is also acceptable. 

Assign a unique identification number (ID No.) for each process that has 

associated emissions (e.g., TK-1 for tunnel kiln no. l) and each emission point. 

Please identify all emission points, including those that do not emit HAP's. For 

emission points that are vented to an air pollution control device (APCD), assign an 

ID No. to the APCD (e.g., BH-1 -for baghouse no. 1). For emission points that are 

uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof 

vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information 

request for any responses that pertain to any process or emission point. 

Page 7 of 28 

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B. Using Tables 2A and 2B, please provide current production rates, production 

capacities, aad related information for each t;rpe of equipment used in brick and 

structural clay product manufacturing. In Table 2A, provide the requested 

information for only those sources that are known or expected to emit HAP's. In 

Table 2B, provide the requested information for all thermal processing, such as 

drying and firing sources. For combustion sources that use different fuels, Table 2B 

should be completed for each type of fuel. For esample, if a kiln typically is fired 

with gas, but periodically is frred with oil, one column in Table 2B should be 

completed for the kiln when fired with gas, and another column should be completed 

for the same kiln when fired with oil. Provide the data in the units listed for each 

row. 

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Page 11 of 28 

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C. Using Table 3, please provide information on procedures used to monitor the 

process operating rate for each of the pieces of equipment and HAP ernission 

sources listed in Tables 2A and 2B. Use the same HAP emission source types and 

equipment ID numbers you listed in Tables 2A to 2B. 

Indicate whether you monitor process rate or not. 

Provide a summary of process rate monitoring procedures that 

describes how process rate is measured for the particular piece of 

equipment. Include where the rate is monitored (i.e., rate of material fed, 

rate of material discharged, or material production rate), the units used to 

measure process rate (e.g, lb/hr or pieces/hr), and how the process data is 

recorded, i.e., manually, automatically (e.g., computer - printout or stored 

to disk, or not at all). If you monitor process rate at both the feed and 

discharge ends of the equipment, indicate so. 

Indicate the type of monitor, equipment, or instrument used to measure 

process operating rate. 

Indicate the monitoring frequency or how often process rate 

measurements are made. 

If instruments are used to measure process throughput, indicate in the 

monitor accuracy column the accuracy of the instrument. The monitor 

accuracy could be listed in terms of a percentage of the throughput 

(± 1 percent), mass per unit time (±2 lb/hr), number of pieces per unit time 

(± 10 pieces/hr), or other appropriate units. 

Indicate the frequency that the monitor is calibrated. 

Provide data in the units listed for each row. 

Page 12 of 28 

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VI. Identification of Brick and Structural Clay Product Manufacturing Emission Points 

A. Use the process flow diagrams developed for your facility and Table 4 to provide 

the following information for each HAP emission source at your facility. 

• Define HAP etnission source type in terms of equipment, such as dryers, kilns, 

etc. As in the process flow diagram, you may group multiple pieces of similar 

equipment. 

• Use the same equipment ID numbers indicated on the process flow 

diagram(s). 

• If the emission source vents inside a building or to outside ambient air without 

first passing through a control device, place a check mark in the uncontrolled 

column. 

• If the emission source vents inside a building or to outside ambient air after 

passing through a fabric filter, dry injection fabric filter, or scrubber, place 

the APCD ID number(s) in the column corresponding to the APCD type. 

• If the emission source vents through a control device type not listed in Table 4, 

indicate the control device type in the other control column and place the 

APCD ID number in the appropriate cell_ 

• In the emission test data column, place a"yes" or "no" in the appropriate cell to 

indicate whether the specific source has been tested for MY pollutants, including 

any HAP's, VOC, PM, or opacity. 

Page 14 of 28 

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B. Using Table 5, please provide information on stack parameters and emission 

estimates for each emission point at your facility that is known or expected to emit 

HAP's. Provide information for all APCD's, including those that exhaust inside the 

buildinQ. Include data for each inlet and outlet, if available, as indicated in the 

table. If you have more than one inlet to an APCD, provide data for each of the 

inlets. Provide data in the units listed for each row. 

Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal 

HAP's or VOC for organic HAP's. Emission estimates may consist of 

measurements reported in emission test reports or may be calculated using mass 

balances, emission factors, engineering ju dgement, or other estimation methods. 

Provide the emission estimates as emission factors in units of lb of pollutant 

emitted per ton of product (Ib/ton). Provide complete copies of any emission test 

reports or other reports that document measurements of emissions. Test 

reports and other emission measurement documents should include the following 

information: process identification; location of sampling point; stack diameter, 

temperature, and flow rate; test method, including analytical procedures; number of 

test runs; emission concentration, emission rate, percent oxygen, and percent 

moisture for each test run; process operating rate; type of APCD; and APCD 

operating parameters. However, test reports with incomplete documentation may 

still be useful and should also be submitted. 

You do not need to flll out Table 5 for emission points that are covered by an 

emission test report that is included in your submittal. If emission test reports are 

not available, provfde calculations that support your emission estimate, 

including the basis for all assumptions in the estimate. Note that emission 

estimates are needed for all HAP's that the facility emits or has the potential to emit. 

(Please refer to the HAP list in Attachment 1.) If the information requested in the 

table is contained in your facility's operating permit, you may reference the 

applicable sections of the permit rather than filling out the table. 

Page 16 of 28 

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C. Using Tables 6A through 61), please provide design and operating data for each 

APCD associated with all dryers, kilns, and any other brick aad structural clay products 

manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of 

APCD's. Use Table 6D for other types of APCD's. When using Table 6D, please 

specify the type of control device and 2 to 4 key design or operating parameters for the 

device. Provide data in the units listed for each row. If the information requested in 

Tables 6A through 6D is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the tables. 

Page 19 of 28 

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~ 

M-O 
D. Usina Table 7, please provide the following information on current monitoring 

procedures for each of the control devices listed in Tables 6A to 6D: parameters 

monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices 

used (e.g., differential pressure transducer, thermocouple), and recordkeeping 

practices (e.g., manually recorded in log book, continuously recorded by electronic data 

acquisition system). Describe briefly other operation and maintenance (O&M) 

procedures for each control device. If the information requested in the table is 

contained in your facility's operating permit, you may reference the applicable sections 

of the permit rather than filling out the table. 

VII. Pollution Prevention Practices for Brick and Structural_Clav Products Manufacturinz 

A. Please describe all pollution prevention practices (i.e., process modifications, such as 

re-use of discarded or rejected materials, or any practice that prevents or reduces the 

amount of air emissions, or the generation and release of solid waste or wastewater 

associated with the operation of air pollution controls). If the information requested 

here is contained in your facility's operating perm.it , you may reference the applicable 

sections of the permit rather than providing the information below. 

Waste brick and tile is crushed and reintroduced into the raw material 

as grog. Waste raw materials such as floor sweepings, waste clay, and 

baghouse fines are reintroduced into the raw material stream. 

Page 24 of 28 

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Page 26 of 28 
VIII. Information on Processes Other Than Brick and Structural Clav Products Manufacturins 

Processes 

A. Using Table 8, please identify all other processes or operations at this facility that are 

not addressed in Items II through VII above and that are potential sources of HAP 

emissions. Estimate total annual emissions of each HAP emitted by these colocated 

processes. If the information requested in the table is contained in your facility's 

operating permit, you may reference the applicable sections of the permit rather than 

filling out the table. 

Page 27 of 28 

C~6 6~ 
TABLE 8. ESTIMATED ANNUAL HAP E~IISSIOVS FRnNt nTUFR.snirRCF.q 

Process/emission source/SIC Code(s) HAP's emitted 

Estimated annual 

emissions, tons 

4 _ i _ .~~~~ . ~ _ ~i~.-.~~.4Y' ~ " `7' '~ ~C 

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SIC 

SIC 

If the information requested in the table is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the table. 

Page 28 of 28 

~~