### 13339 Hagers Ferry Road H untersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 

# Order Summary Report 

# Analytical Laboratory

Order Number: J12070244 Project Name: ALLEN Somerville Waste Water

Lab Contact: Jason C Perkins 

### Date: 8/3/2012 C ustomer Address: 253 Plant Allen Road Customer Name(s): Don Scruggs, Robbin Jolly, Ray Lidke, Bill Kennedy

Belmont, NC 28012

P hone: 980-875-5348 Report Authorized By: (Signature)


### Program Comments: Please contact the Program Manager (Jason C Perkins) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, A nalytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.

## Sample ID's & Descriptions:

Sample ID Plant/Station C ollection Date and Time Collected By Sample Description 2012015396 A LLEN 16-Jul-12 5:40 AM Chris Williams FGD Purge Eff 2012015397 ALLEN 16-Jul-12 5:46 AM Chris Williams EQ Tank Eff 2012015398 ALLEN 16-Jul-12 6:12 AM Chris Williams BioReactor 1 Inf 2012015399 ALLEN 16-Jul-12 6:12 AM Chris Williams BioReactor 1 Inf BLANK 2012015400 ALLEN 16-Jul-12 6:03 AM Chris Williams BioReactor 2 Inf 2012015401 ALLEN 16-Jul-12 6:03 AM Chris Williams BioReactor 2 Inf BLANK 2012015402 ALLEN 16-Jul-12 6:17 AM Chris Williams BioReactor 2 Eff 2012015403 ALLEN 16-Jul-12 6:17 AM Chris Greene BioReactor 2 Eff BLANK 2012015404 ALLEN 16-Jul-12 4:30 AM Chris Williams Filter Blk 2012015405 ALLEN 16-Jul-12 6:17 AM Chris Williams BioReactor 2 Eff BLANK DUP 10 Total Samples

### COC and .pdf report are in agreement with sample totals

a nd analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. The Vendor Laboratories have been qualified by the Analytical Laboratory Yes No



# Technical Validation Review Checklist:

Yes No
Yes No



## Report Sections Included:

Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody

R eviewed By: 

### DataBase Administrator Date: 

### 8/3/2012 Yes

Electronic Data Deliverable (EDD) Sent Separately

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12070244

2012015396 Collection Date: 16-Jul-12 5:40 AM 

### Site: FGD Purge Eff M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F ALKALINITY Vendor Parameter C omplete V_PRISM 1 I NORGANIC IONS BY IC Bromide 17 m g/L EPA 300.0 23-Jul-12 17:51 JAHERMA 5 50 C hloride 2300 mg/L EPA 300.0 23-Jul-12 17:51 JAHERMA 50 500 S ulfate 1400 mg/L EPA 300.0 23-Jul-12 17:51 JAHERMA 50 500 M ERCURY (COLD VAPOR) IN WATER Mercury (Hg) 18. 1 ug/L EPA 245.1 02-Aug-12 12:16 AGIBBS 2 .5 50 TOTAL RECOVERABLE METALS BY ICP Boron (B) 106 m g/L EPA 200.7 20-Jul-12 13:52 DJSULL1 0 .5 10 C alcium (Ca) 2160 mg/L EPA 200.7 20-Jul-12 13:52 DJSULL1 0 .1 10 I ron (Fe) 77.2 mg/L EPA 200.7 20-Jul-12 13:52 DJSULL1 0 .1 10 Li thium (Li) 0.149 mg/L EPA 200.7 20-Jul-12 13:52 DJSULL1 0. 05 10 M agnesium (Mg) 447 mg/L EPA 200.7 20-Jul-12 13:52 DJSULL1 0. 05 10 M anganese (Mn) 2.81 mg/L EPA 200.7 20-Jul-12 13:52 DJSULL1 0. 05 10 P otassium (K) 26.6 mg/L EPA 200.7 20-Jul-12 13:52 DJSULL1 1 10 S odium (Na) 24.5 mg/L EPA 200.7 20-Jul-12 13:52 DJSULL1 0 .5 10 D ISSOLVED METALS BY ICP-MS Manganese (Mn) 161 u g/L EPA 200.8 20-Jul-12 14:00 KRICHAR 10 10 S elenium (Se) 647 ug/L EPA 200.8 20-Jul-12 14:00 KRICHAR 10 10 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 187 u g/L EPA 200.8 19-Jul-12 12:11 KRICHAR 10 10 C admium (Cd) < 10 ug/L EPA 200.8 19-Jul-12 12:11 KRICHAR 10 10 C hromium (Cr) 132 ug/L EPA 200.8 19-Jul-12 12:11 KRICHAR 10 10 C opper (Cu) 130 ug/L EPA 200.8 19-Jul-12 12:11 KRICHAR 10 10 N ickel (Ni) 182 ug/L EPA 200.8 19-Jul-12 12:11 KRICHAR 10 10 S elenium (Se) 923 ug/L EPA 200.8 19-Jul-12 12:11 KRICHAR 10 10 S ilver (Ag) < 10 ug/L EPA 200.8 19-Jul-12 12:11 KRICHAR 10 10 Z inc (Zn) 219 ug/L EPA 200.8 19-Jul-12 12:11 KRICHAR 10 10 S ELENIUM SPECIATION Vendor Parameter C omplete V_AS&C 1 TOTAL DISSOLVED SOLIDS Vendor Parameter co mplete V_PACE 1

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12070244

2012015396 Collection Date: 16-Jul-12 5:40 AM 

### Site: FGD Purge Eff M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F TOTAL SUSPENDED SOLIDS Vendor Parameter C omplete V_PACE 1


### 2012015397 Collection Date: 16-Jul-12 5:46 AM 

### Site: EQ Tank Eff M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 15. 5 ug/L EPA 245.1 02-Aug-12 12:18 AGIBBS 2 .5 50 TOTAL RECOVERABLE METALS BY ICP Boron (B) 113 m g/L EPA 200.7 20-Jul-12 13:56 DJSULL1 0 .5 10 C alcium (Ca) 1790 mg/L EPA 200.7 20-Jul-12 13:56 DJSULL1 0 .1 10 I ron (Fe) 64.0 mg/L EPA 200.7 20-Jul-12 13:56 DJSULL1 0 .1 10 Li thium (Li) 0.141 mg/L EPA 200.7 20-Jul-12 13:56 DJSULL1 0. 05 10 M agnesium (Mg) 463 mg/L EPA 200.7 20-Jul-12 13:56 DJSULL1 0. 05 10 M anganese (Mn) 2.38 mg/L EPA 200.7 20-Jul-12 13:56 DJSULL1 0. 05 10 P otassium (K) 26.0 mg/L EPA 200.7 20-Jul-12 13:56 DJSULL1 1 10 S odium (Na) 25.9 mg/L EPA 200.7 20-Jul-12 13:56 DJSULL1 0 .5 10 D ISSOLVED METALS BY ICP-MS Manganese (Mn) <10 ug/L EPA 200.8 20-Jul-12 14:04 KRICHAR 10 10 S elenium (Se) 626 ug/L EPA 200.8 20-Jul-12 14:04 KRICHAR 10 10 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 140 u g/L EPA 200.8 19-Jul-12 12:14 KRICHAR 10 10 C admium (Cd) < 10 ug/L EPA 200.8 19-Jul-12 12:14 KRICHAR 10 10 C hromium (Cr) 107 ug/L EPA 200.8 19-Jul-12 12:14 KRICHAR 10 10 C opper (Cu) 112 ug/L EPA 200.8 19-Jul-12 12:14 KRICHAR 10 10 N ickel (Ni) 149 ug/L EPA 200.8 19-Jul-12 12:14 KRICHAR 10 10 S elenium (Se) 873 ug/L EPA 200.8 19-Jul-12 12:14 KRICHAR 10 10 S ilver (Ag) < 10 ug/L EPA 200.8 19-Jul-12 12:14 KRICHAR 10 10 Z inc (Zn) 172 ug/L EPA 200.8 19-Jul-12 12:14 KRICHAR 10 10


### 2012015398 Collection Date: 16-Jul-12 6:12 AM 

### Site: BioReactor 1 Inf M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F ALKALINITY Vendor Parameter C omplete V_PRISM 1

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12070244

2012015398 Collection Date: 16-Jul-12 6:12 AM 

### Site: BioReactor 1 Inf M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F MERCURY 1631 Vendor Parameter C omplete V_BRAND 1 M ERCURY 1631 - DISSOLVED Vendor Parameter C omplete V_BRAND 1 TOTAL RECOVERABLE METALS BY ICP Boron (B) 111 m g/L EPA 200.7 20-Jul-12 14:00 DJSULL1 0 .5 10 C alcium (Ca) 1820 mg/L EPA 200.7 20-Jul-12 14:00 DJSULL1 0 .1 10 I ron (Fe) < 0.1 mg/L EPA 200.7 20-Jul-12 14:00 DJSULL1 0 .1 10 Li thium (Li) 0.080 mg/L EPA 200.7 20-Jul-12 14:00 DJSULL1 0. 05 10 M agnesium (Mg) 360 mg/L EPA 200.7 20-Jul-12 14:00 DJSULL1 0. 05 10 M anganese (Mn) < 0.05 mg/L EPA 200.7 20-Jul-12 14:00 DJSULL1 0. 05 10 P otassium (K) 15.8 mg/L EPA 200.7 20-Jul-12 14:00 DJSULL1 1 10 S odium (Na) 25.9 mg/L EPA 200.7 20-Jul-12 14:00 DJSULL1 0 .5 10 D ISSOLVED METALS BY ICP-MS Manganese (Mn) <10 ug/L EPA 200.8 20-Jul-12 14:08 KRICHAR 10 10 S elenium (Se) 498 ug/L EPA 200.8 20-Jul-12 14:08 KRICHAR 10 10 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) <10 ug/L EPA 200.8 19-Jul-12 12:17 KRICHAR 10 10 C admium (Cd) < 10 ug/L EPA 200.8 19-Jul-12 12:17 KRICHAR 10 10 C hromium (Cr) 11.4 ug/L EPA 200.8 19-Jul-12 12:17 KRICHAR 10 10 C opper (Cu) < 10 ug/L EPA 200.8 19-Jul-12 12:17 KRICHAR 10 10 N ickel (Ni) < 10 ug/L EPA 200.8 19-Jul-12 12:17 KRICHAR 10 10 S elenium (Se) 547 ug/L EPA 200.8 19-Jul-12 12:17 KRICHAR 10 10 S ilver (Ag) < 10 ug/L EPA 200.8 19-Jul-12 12:17 KRICHAR 10 10 Z inc (Zn) < 10 ug/L EPA 200.8 19-Jul-12 12:17 KRICHAR 10 10 S ELENIUM SPECIATION Vendor Parameter C omplete V_AS&C 1


### 2012015399 Collection Date: 16-Jul-12 6:12 AM 

### Site: BioReactor 1 Inf BLANK M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F MERCURY 1631 Vendor Parameter C omplete V_BRAND 1 M ERCURY 1631 - DISSOLVED Vendor Parameter C omplete V_BRAND 1

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12070244

2012015400 Collection Date: 16-Jul-12 6:03 AM 

### Site: BioReactor 2 Inf M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F ALKALINITY Vendor Parameter C omplete V_PRISM 1 M ERCURY 1631 Vendor Parameter C omplete V_BRAND 1 M ERCURY 1631 - DISSOLVED Vendor Parameter C omplete V_BRAND 1 TOTAL RECOVERABLE METALS BY ICP Boron (B) 113 m g/L EPA 200.7 20-Jul-12 14:04 DJSULL1 0 .5 10 C alcium (Ca) 1830 mg/L EPA 200.7 20-Jul-12 14:04 DJSULL1 0 .1 10 I ron (Fe) < 0.1 mg/L EPA 200.7 20-Jul-12 14:04 DJSULL1 0 .1 10 Li thium (Li) 0.083 mg/L EPA 200.7 20-Jul-12 14:04 DJSULL1 0. 05 10 M agnesium (Mg) 359 mg/L EPA 200.7 20-Jul-12 14:04 DJSULL1 0. 05 10 M anganese (Mn) 0.062 mg/L EPA 200.7 20-Jul-12 14:04 DJSULL1 0. 05 10 P otassium (K) 18.3 mg/L EPA 200.7 20-Jul-12 14:04 DJSULL1 1 10 S odium (Na) 26.4 mg/L EPA 200.7 20-Jul-12 14:04 DJSULL1 0 .5 10 D ISSOLVED METALS BY ICP-MS Manganese (Mn) 56. 8 ug/L EPA 200.8 20-Jul-12 14:11 KRICHAR 10 10 S elenium (Se) 212 ug/L EPA 200.8 20-Jul-12 14:11 KRICHAR 10 10 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) <10 ug/L EPA 200.8 19-Jul-12 12:21 KRICHAR 10 10 C admium (Cd) < 10 ug/L EPA 200.8 19-Jul-12 12:21 KRICHAR 10 10 C hromium (Cr) < 10 ug/L EPA 200.8 19-Jul-12 12:21 KRICHAR 10 10 C opper (Cu) < 10 ug/L EPA 200.8 19-Jul-12 12:21 KRICHAR 10 10 N ickel (Ni) < 10 ug/L EPA 200.8 19-Jul-12 12:21 KRICHAR 10 10 S elenium (Se) 231 ug/L EPA 200.8 19-Jul-12 12:21 KRICHAR 10 10 S ilver (Ag) < 10 ug/L EPA 200.8 19-Jul-12 12:21 KRICHAR 10 10 Z inc (Zn) < 10 ug/L EPA 200.8 19-Jul-12 12:21 KRICHAR 10 10 S ELENIUM SPECIATION Vendor Parameter C omplete V_AS&C 1


### 2012015401 Collection Date: 16-Jul-12 6:03 AM 

### Site: BioReactor 2 Inf BLANK M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F MERCURY 1631 Vendor Parameter C omplete V_BRAND 1

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12070244

2012015401 Collection Date: 16-Jul-12 6:03 AM 

### Site: BioReactor 2 Inf BLANK M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F MERCURY 1631 - DISSOLVED Vendor Parameter C omplete V_BRAND 1


### 2012015402 Collection Date: 16-Jul-12 6:17 AM 

### Site: BioReactor 2 Eff M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F ALKALINITY Vendor Parameter C omplete V_PRISM 1 I NORGANIC IONS BY IC Bromide 36 m g/L EPA 300.0 23-Jul-12 16:57 JAHERMA 5 50 C hloride 3400 mg/L EPA 300.0 23-Jul-12 16:57 JAHERMA 50 500 S ulfate 1400 mg/L EPA 300.0 23-Jul-12 16:57 JAHERMA 50 500 M ERCURY 1631 Vendor Parameter C omplete V_BRAND 1 M ERCURY 1631 - DISSOLVED Vendor Parameter C omplete V_BRAND 1 TOTAL RECOVERABLE METALS BY ICP Boron (B) 121 m g/L EPA 200.7 20-Jul-12 14:08 DJSULL1 0 .5 10 C alcium (Ca) 2020 mg/L EPA 200.7 20-Jul-12 14:08 DJSULL1 0 .1 10 I ron (Fe) 0.228 mg/L EPA 200.7 20-Jul-12 14:08 DJSULL1 0 .1 10 Li thium (Li) 0.092 mg/L EPA 200.7 20-Jul-12 14:08 DJSULL1 0. 05 10 M agnesium (Mg) 387 mg/L EPA 200.7 20-Jul-12 14:08 DJSULL1 0. 05 10 M anganese (Mn) 0.071 mg/L EPA 200.7 20-Jul-12 14:08 DJSULL1 0. 05 10 P otassium (K) 26.4 mg/L EPA 200.7 20-Jul-12 14:08 DJSULL1 1 10 S odium (Na) 28.9 mg/L EPA 200.7 20-Jul-12 14:08 DJSULL1 0 .5 10 D ISSOLVED METALS BY ICP-MS Manganese (Mn) 64. 0 ug/L EPA 200.8 20-Jul-12 14:15 KRICHAR 5 5 S elenium (Se) 5.10 ug/L EPA 200.8 20-Jul-12 14:15 KRICHAR 5 5

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12070244

2012015402 Collection Date: 16-Jul-12 6:17 AM 

### Site: BioReactor 2 Eff M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) <5 ug/L EPA 200.8 19-Jul-12 12:24 KRICHAR 5 5 C admium (Cd) < 5 ug/L EPA 200.8 19-Jul-12 12:24 KRICHAR 5 5 C hromium (Cr) < 5 ug/L EPA 200.8 19-Jul-12 12:24 KRICHAR 5 5 C opper (Cu) < 5 ug/L EPA 200.8 19-Jul-12 12:24 KRICHAR 5 5 N ickel (Ni) < 5 ug/L EPA 200.8 19-Jul-12 12:24 KRICHAR 5 5 S elenium (Se) 5.50 ug/L EPA 200.8 19-Jul-12 12:24 KRICHAR 5 5 S ilver (Ag) < 5 ug/L EPA 200.8 19-Jul-12 12:24 KRICHAR 5 5 Z inc (Zn) < 5 ug/L EPA 200.8 19-Jul-12 12:24 KRICHAR 5 5 S ELENIUM SPECIATION Vendor Parameter C omplete V_AS&C 1


### 2012015403 Collection Date: 16-Jul-12 6:17 AM 

### Site: BioReactor 2 Eff BLANK M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F MERCURY 1631 Vendor Parameter C omplete V_BRAND 1 M ERCURY 1631 - DISSOLVED Vendor Parameter C omplete V_BRAND 1


### 2012015404 Collection Date: 16-Jul-12 4:30 AM 

### Site: Filter Blk M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F DISSOLVED METALS BY ICP-MS Manganese (Mn) <1 ug/L EPA 200.8 20-Jul-12 12:37 KRICHAR 1 1 S elenium (Se) 2.23 ug/L EPA 200.8 20-Jul-12 12:37 KRICHAR 1 1


### 2012015405 Collection Date: 16-Jul-12 6:17 AM 

### Site: BioReactor 2 Eff BLANK DUP M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F MERCURY 1631 Vendor Parameter C omplete V_BRAND 1

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12070244

2012015405 Collection Date: 16-Jul-12 6:17 AM 

### Site: BioReactor 2 Eff BLANK DUP M atrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst D F MERCURY 1631 - DISSOLVED Vendor Parameter C omplete V_BRAND 1

## July 24, 2012

LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92124528



## 92124528 Project: Pace Project No.: RE: Program Manager Duke Energy

,

J12070244
Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on July 17, 2012. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely,

Kevin Godwin for Kevin Herring kevin.herring@pacelabs.com Project Manager

Enclosures



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 9 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### CERTIFICATIONS

Pace Project No.: Project: 92124528

J12070244

Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia Certification #: 00072 West Virginia Certification #: 356 Virgina/VELAP Certification #: 460147



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 9 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### SAMPLE SUMMARY

Pace Project No.: Project: 92124528

J12070244

Lab ID Sample ID Matrix Date Collected Date Received 92124528001 2012015396 Water 07/16/12 05:40 07/17/12 17:52



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 9 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### SAMPLE ANALYTE COUNT

Pace Project No.: Project: 92124528

J12070244

Lab ID Sample ID Method Analytes Reported Laboratory Analysts 92124528001 2012015396 SM 2540C 1 PASI-A LMD SM 2540D 1 PASI-A LMD



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 9 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### ANALYTICAL RESULTS

Pace Project No.: Project: 92124528

J12070244 Sample: 2012015396 Lab ID: 92124528001 Collected: 07/16/12 05:40 Received: 07/17/12 17:52 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. Qual MDL Limit Report

2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 8180 mg/L 1 07/18/12 22:49 500 500 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 3630 mg/L 1 07/19/12 01:43 250 250



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 07/24/2012 09:25 AM Page 5 of 9 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### QUALITY CONTROL DATA

Pace Project No.: Project: 92124528

J12070244

QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/21674 SM 2540C SM 2540C 2540C Total Dissolved Solids Associated Lab Samples: 92124528001

Parameter Units Blank Result Reporting

Limit Qualifiers METHOD BLANK: 797493 Associated Lab Samples: 92124528001 Matrix: Water

Analyzed Total Dissolved Solids mg/L ND 25.0 07/18/12 22:46

Parameter Units LCS Result % Rec Limits Qualifiers % Rec Conc. 797494 LABORATORY CONTROL SAMPLE: LCS Spike
Total Dissolved Solids mg/L 262 250 105 80-120

Parameter Units Dup Result Max RPD Qualifiers RPD Result 92124722001 797504 SAMPLE DUPLICATE:

Total Dissolved Solids mg/L 17100 1 20 17000



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 07/24/2012 09:25 AM Page 6 of 9 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### QUALITY CONTROL DATA

Pace Project No.: Project: 92124528

J12070244

QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/21677 SM 2540D SM 2540D 2540D Total Suspended Solids Associated Lab Samples: 92124528001

Parameter Units Blank Result Reporting

Limit Qualifiers METHOD BLANK: 797521 Associated Lab Samples: 92124528001 Matrix: Water

Analyzed Total Suspended Solids mg/L ND 2.5 07/19/12 01:38

Parameter Units LCS Result % Rec Limits Qualifiers % Rec Conc. 797522 LABORATORY CONTROL SAMPLE: LCS Spike Total Suspended Solids mg/L 246 250 98 80-120

Parameter Units Dup Result Max RPD Qualifiers RPD Result 92124188002 797523 SAMPLE DUPLICATE:

Total Suspended Solids mg/L 23.0 10 20 25.4

Parameter Units Dup Result Max RPD Qualifiers RPD Result 92124513001 797524 SAMPLE DUPLICATE:

Total Suspended Solids mg/L ND 20 ND



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 07/24/2012 09:25 AM Page 7 of 9 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### QUALIFIERS

Pace Project No.: Project: 92124528

J12070244

DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PRL - Pace Reporting Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - Asheville PASI-A



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 07/24/2012 09:25 AM Page 8 of 9 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### QUALITY CONTROL DATA CROSS REFERENCE TABLE

Pace Project No.: Project: 92124528

J12070244

Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92124528001 WET/21674 2012015396 SM 2540C 92124528001 WET/21677 2012015396 SM 2540D



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 07/24/2012 09:25 AM Page 9 of 9 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 

# Case Narrative 07/24/2012

Duke Energy Corporation (04) Jay Perkins 13339 Hagers Ferry Road Huntersville, NC 28078 Project: Allen Shay/Miller Creek Project No.: J12070244 Lab Submittal Date: 07/17/2012 Prism Work Order: 2070379 VA Certification No. 1287



### Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC.



### VP Laboratory Services Reviewed By

Data Qualifiers Key Reference: 

### HT Sample received and analyzed outside of the hold time.

Method Detection Limit MDL Below Reporting Limit BRL Relative Percent Difference RPD


## * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 1 of 9

# Sample Receipt Summary 07/24/2012 

## Prism Work Order: 2070379 Client Sample ID Matrix Lab Sample ID Date Sampled Date Received 

### 2070379-01 07/16/12 2012015396/FGD Purge Eff 07/17/12 Water 2070379-02 07/16/12 2012015398/BioReactor 1 Inf 07/17/12 Water 2070379-03 07/16/12 2012015400/BioReactor 2 Inf 07/17/12 Water 2070379-04 07/16/12 2012015402/BioReactor 2 Eff 07/17/12 Water Samples received in good condition at 5.6 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 2 of 9

# Laboratory Report 07/24/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen Shay/Miller Creek Duke Energy Corporation (04)
Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2070379-01 Prism Work Order: 2070379 Time Collected: 07/16/12 05:40 Time Submitted: 07/17/12 17:30 2012015396/FGD Purge Eff


### J12070244

General Chemistry Parameters 6.9 *SM4500-H B P2G0342 1 7/18/12 16:00 JAB HT pH Units pH 38 *SM2320 B P2G0343 1 5.0 7/18/12 15:45 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2G0344 1 5.0 7/18/12 15:45 JAB mg/L 0.66 Carbonate Alkalinity 38 *SM2320 B P2G0345 1 5.0 7/18/12 15:45 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 3 of 9

# Laboratory Report 07/24/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen Shay/Miller Creek Duke Energy Corporation (04)
Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2070379-02 Prism Work Order: 2070379 Time Collected: 07/16/12 06:12 Time Submitted: 07/17/12 17:30 2012015398/BioReactor 1 Inf


### J12070244

General Chemistry Parameters 7.2 *SM4500-H B P2G0342 1 7/18/12 16:00 JAB HT pH Units pH 46 *SM2320 B P2G0343 1 5.0 7/18/12 15:45 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2G0344 1 5.0 7/18/12 15:45 JAB mg/L 0.66 Carbonate Alkalinity 46 *SM2320 B P2G0345 1 5.0 7/18/12 15:45 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 4 of 9

# Laboratory Report 07/24/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen Shay/Miller Creek Duke Energy Corporation (04)
Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2070379-03 Prism Work Order: 2070379 Time Collected: 07/16/12 06:03 Time Submitted: 07/17/12 17:30 2012015400/BioReactor 2 Inf


### J12070244

General Chemistry Parameters 7.5 *SM4500-H B P2G0342 1 7/18/12 16:00 JAB HT pH Units pH 160 *SM2320 B P2G0343 1 5.0 7/18/12 15:45 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2G0344 1 5.0 7/18/12 15:45 JAB mg/L 0.66 Carbonate Alkalinity 160 *SM2320 B P2G0345 1 5.0 7/18/12 15:45 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 5 of 9

# Laboratory Report 07/24/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen Shay/Miller Creek Duke Energy Corporation (04)
Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2070379-04 Prism Work Order: 2070379 Time Collected: 07/16/12 06:17 Time Submitted: 07/17/12 17:30 2012015402/BioReactor 2 Eff


### J12070244

General Chemistry Parameters 7.2 *SM4500-H B P2G0342 1 7/18/12 16:00 JAB HT pH Units pH 180 *SM2320 B P2G0343 1 5.0 7/18/12 15:45 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2G0344 1 5.0 7/18/12 15:45 JAB mg/L 0.66 Carbonate Alkalinity 180 *SM2320 B P2G0345 1 5.0 7/18/12 15:45 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 6 of 9

### 7/24/12 

## Level II QC Report

13339 Hagers Ferry Road Project No: J12070244 Project: Allen Shay/Miller Creek Duke Energy Corporation (04)
Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 2070379 Time Submitted: 7/17/2012 5:30:00PM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control



### Batch P2G0342 - NO PREP LCS (P2G0342-BS1) 

### Prepared & Analyzed: 07/18/12 pH pH Units 6.91 6.860 99-101 101 

### Batch P2G0343 - NO PREP Blank (P2G0343-BLK1) 

### Prepared & Analyzed: 07/18/12 Total Alkalinity mg/L BRL 5.0 LCS (P2G0343-BS1) 

### Prepared & Analyzed: 07/18/12 Total Alkalinity mg/L 245 5.0 250.0 90-110 98 LCS Dup (P2G0343-BSD1) 

### Prepared & Analyzed: 07/18/12 Total Alkalinity mg/L 248 5.0 250.0 200 90-110 99 2 

### Batch P2G0344 - NO PREP Blank (P2G0344-BLK1) 

### Prepared & Analyzed: 07/18/12 Carbonate Alkalinity mg/L BRL 5.0 LCS (P2G0344-BS1) 

### Prepared & Analyzed: 07/18/12 Carbonate Alkalinity mg/L 245 5.0 90-110 LCS Dup (P2G0344-BSD1) 

### Prepared & Analyzed: 07/18/12 Carbonate Alkalinity mg/L 248 5.0 200 90-110 2 

### Batch P2G0345 - NO PREP Blank (P2G0345-BLK1) 

### Prepared & Analyzed: 07/18/12 Bicarbonate Alkalinity mg/L BRL 5.0

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 7 of 9

### 7/24/12 

## Level II QC Report

13339 Hagers Ferry Road Project No: J12070244 Project: Allen Shay/Miller Creek Duke Energy Corporation (04)
Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 2070379 Time Submitted: 7/17/2012 5:30:00PM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control



### Batch P2G0345 - NO PREP LCS (P2G0345-BS1) 

### Prepared & Analyzed: 07/18/12 Bicarbonate Alkalinity mg/L 245 5.0 250.0 90-110 98 LCS Dup (P2G0345-BSD1) 

### Prepared & Analyzed: 07/18/12 Bicarbonate Alkalinity mg/L 248 5.0 250.0 200 90-110 99 2

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 8 of 9

### Page 9 of 9

### 3958 6 th

### Ave NW • Seattle, WA 98107 • T: 206-632-6206 • F: 206-632-6017 • www.brooksrand.com • brl@brooksrand.com 

## August 2, 2012 Duke Energy ATTN: Jay Perkins Scientific Support-Laboratory 13339 Hagers Ferry Road Huntersville NC 28078 jcperkins@duke-energy.com labcustomer@duke-energy.com RE: Project DUK-HV1201 Client Project: J12070244 Dear Mr. Perkins, On July 18, 2012, Brooks Rand Labs (BRL) received three (3) wastewater samples and three (3) corresponding field blanks. An aliquot was removed from each sample bottle and filtered into a separate container designed for dissolved mercury (Hg) analysis. The sample volume from the original container was logged-in for total Hg analysis. All samples were received, prepared, analyzed, and stored according to BRL SOPs and EPA methodology. The results were blank-corrected as described in the calculations section of the applicable SOP(s) and may be evaluated using adjusted reporting limits to account for sample aliquot size. Please refer to the Sample Results page for sample-specific detection limits and other details.Data used for regulatory purposes has a 24 hour filtration holding time requirement. Nonregulatory purposed data has a 48 hour filtration holding time. The samples were received within the 48 hour filtration requirement. The total Hg analysis for BioReactor 2 Inf Hg Blk (1229025-07) produced a detectable concentration of 65.5 ng/L. The sample was re-analyzed and confirmed the reported result. While this result was less than the associated field sample, the field sample result (178 ng/L) was within 10x the concentration of the blank and contamination was considered significant. All data was reported without additional qualification, aside from concentration qualifiers, and all associated quality control sample results met the acceptance criteria. BRL, an accredited laboratory, certifies the reported results of all analyses for which BRL is NELAP accredited meet all NELAP requirements. For more details, see the Report Information page of the report. Please feel free to contact me if you have any questions regarding this report. Sincerely,

Tiffany Stilwater Project Manager tiffany@brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



## Definition of Data Qualifiers

(Effective 9/23/09) 

## Laboratory Accreditation BRL is accredited by the National Environmental Laboratory Accreditation Program (NELAP) through the State of Florida Department of Health, Bureau of Laboratories (E87982) and is certified to perform many environmental analyses. BRL is also certified by many other states to perform environmental analyses. For a current list of our accreditations/certifications, please visit our website at <http://www.brooksrand.com/default.asp?contentID=586>. Results reported relate only to the samples listed in the report. 

# Report Information

BLK BRL BS CAL CCV CRM D DUP ICV MSD ND NR PS REC RPD RSD SCV SOP 

### method blank Brooks Rand Labs laboratory fortified blank calibration standard continuing calibration verification certified reference material dissolved fraction duplicate initial calibration verification matrix spike duplicate non-detect non-reportable post preparation spike percent recovery relative percent difference relative standard deviation secondary calibration verification standard operating procedure MDL MRL MS



### method detection limit method reporting limit matrix spike

SRM T COC



### standard reference material total recoverable fraction chain of custody record 

## Common Abbreviations

These qualifiers are based on those previously utilized by Brooks Rand Labs, those found in the EPA SOW ILM03.0, Exhibit B, Section III, pg. B-18, and the USEPA Contract Laboratory Program National Functional Guidelines for Inorganic Superfund Data Review; USEPA; January 2010. These supersede all previous qualifiers ever employed by BRL. Detected by the instrument, the result is > the MDL but ≤the MRL. Result is reported and considered an estimate. B E 

### An estimated value due to the presence of interferences. A full explanation is presented in the narrative. H 

### Holding time and/or preservation requirements not met. Result is estimated. J 

### Estimated value. A full explanation is presented in the narrative. J-M 

### Duplicate precision (RPD) for associated QC sample was not within acceptance criteria. Result is estimated. J-N 

### Spike recovery for associated QC sample was not within acceptance criteria. Result is estimated. M 

### Duplicate precision (RPD) was not within acceptance criteria. Result is estimated. N 

### Spike recovery was not within acceptance criteria. Result is estimated. R 

### Rejected, unusable value. A full explanation is presented in the narrative. U 

### Result is ≤the MDL or client requested reporting limit (CRRL). Result reported as the MDL or CRRL. X 

### Result is not BLK-corrected and is within 10x the absolute value of the highest detectable BLK in the batch. Result is estimated. 

## Field Quality Control Samples Please be notified that certain EPA methods require the collection of field quality control samples of an appropriate type and frequency; failure to do so is considered a deviation from some methods and for compliance purposes should only be done with the approval of regulatory authorities. Please see the specific EPA methods for details regarding required field quality control samples.

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Information

Report Matrix Type Received Sampled Sample Lab ID 

### 1229025-01 BioReactor 1 Inf 07/16/2012 07/18/2012 Sample Influent 1229025-02 BioReactor 1 Inf 07/16/2012 07/18/2012 Sample Influent 1229025-03 BioReactor 1 Inf Hg Blk 07/16/2012 07/18/2012 Field Blank DIW 1229025-04 BioReactor 1 Inf Hg Blk 07/16/2012 07/18/2012 Field Blank DIW 1229025-05 BioReactor 2 Inf 07/16/2012 07/18/2012 Sample Influent 1229025-06 BioReactor 2 Inf 07/16/2012 07/18/2012 Sample Influent 1229025-07 BioReactor 2 Inf Hg Blk 07/16/2012 07/18/2012 Field Blank DIW 1229025-08 BioReactor 2 Inf Hg Blk 07/16/2012 07/18/2012 Field Blank DIW 1229025-09 BioReactor 2 Eff 07/16/2012 07/18/2012 Sample Effluent 1229025-10 BioReactor 2 Eff 07/16/2012 07/18/2012 Sample Effluent 1229025-11 BioReactor 2 Eff Hg Blk 07/16/2012 07/18/2012 Field Blank DIW 1229025-12 BioReactor 2 Eff Hg Blk 07/16/2012 07/18/2012 Field Blank DIW 1229025-13 BioReactor 2 Eff DUP 07/16/2012 07/18/2012 Sample Effluent 1229025-14 BioReactor 2 Eff DUP 07/16/2012 07/18/2012 Sample Effluent 

# Batch Summary

Analyte Prepared Analyzed Sequence Batch Lab Matrix Method 

### B121255 07/20/2012 07/23/2012 1200555 Water EPA 1631 Hg

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Results

Sample Sequence Result MDL MRL Unit Batch

Qualifier Analyte Basis

Report Matrix 

### BioReactor 1 Inf 

### 1720 T 1200555 B121255 Influent 8.42 3.16 1229025-01 Hg ng/L 461 D 1200555 B121255 Influent 8.08 3.03 1229025-02 Hg ng/L
BioReactor 1 Inf Hg Blk 

### 0.15 T U 1200555 B121255 DIW 0.40 0.15 1229025-03 Hg ng/L 0.15 D U 1200555 B121255 DIW 0.41 0.15 1229025-04 Hg ng/L

BioReactor 2 Eff 

### 37.1 T 1200555 B121255 Effluent 1.99 0.74 1229025-09 Hg ng/L 3.17 D 1200555 B121255 Effluent 0.40 0.15 1229025-10 Hg ng/L

BioReactor 2 Eff DUP 

### 40.2 T 1200555 B121255 Effluent 2.09 0.78 1229025-13 Hg ng/L 4.15 D 1200555 B121255 Effluent 0.41 0.15 1229025-14 Hg ng/L
BioReactor 2 Eff Hg Blk 

### 0.15 T U 1200555 B121255 DIW 0.40 0.15 1229025-11 Hg ng/L 0.15 D U 1200555 B121255 DIW 0.40 0.15 1229025-12 Hg ng/L

BioReactor 2 Inf 

### 178 T 1200555 B121255 Influent 2.09 0.79 1229025-05 Hg ng/L 7.24 D 1200555 B121255 Influent 0.40 0.15 1229025-06 Hg ng/L
BioReactor 2 Inf Hg Blk 

### 65.5 T 1200555 B121255 DIW 0.41 0.15 1229025-07 Hg ng/L 0.15 D U 1200555 B121255 DIW 0.40 0.15 1229025-08 Hg ng/L

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Accuracy & Precision Summary

Batch: 

### B121255

Analyte Result Units Native Spike REC & Limits RPD & Limits Method: 

### EPA 1631 Lab Matrix: 

### Water

Sample Certified Reference Material (1229081, NIST 1641d 1000x dilution) B121255-SRM1 

### 15.68 100% ng/L 85-115 Hg 15.66
Matrix Spike (1229033-03) B121255-MS1 

### 96.17 107% ng/L 71-125 Hg 121.9

18.99
Matrix Spike Duplicate (1229033-03) B121255-MSD1 

### 97.88 113% ng/L 71-125 246% Hg 129.7

18.99
Matrix Spike (1229037-01) B121255-MS2 

### 6.538 95% ng/L 71-125 Hg 7.49

1.26
Matrix Spike Duplicate (1229037-01) B121255-MSD2 

### 6.560 109% ng/L 71-125 2411% Hg 8.39

1.26

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Method Blanks & Reporting Limits

Batch: 

### B121255 Method: 

### EPA 1631 Matrix: 

### Water Analyte: 

### Hg Result Units Sample 

### B121255-BLK1 ng/L 0.15 B121255-BLK2 ng/L 0.07 B121255-BLK3 ng/L 0.07 B121255-BLK4 ng/L 0.07 MDL: 

### 0.15 Average: 

### 0.09 Standard Deviation: 

### 0.04 Limit: 

### 0.10 Limit: 

### 0.50 MRL: 

### 0.40

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Instrument Calibration

Sequence: 

### 1200555 Method: 

### EPA 1631 Instrument: 

### HGAAS-2 Date: 

### 07/23/2012 Total Mercury and Mercury Speciation by CVAFS
Analyte: 

### Hg REC & Limits Result True Value Lab ID Units 

### 1200555-IBL1 5.74 pg of Hg 1200555-IBL2 6.69 pg of Hg 1200555-IBL3 8.85 pg of Hg 1200555-IBL4 9.94 pg of Hg 1200555-CAL1 25.00 23.82 pg of Hg 95% 1200555-CAL2 100.0 103.5 pg of Hg 104% 1200555-CAL3 500.0 487.7 pg of Hg 98% 1200555-CAL4 2500 2627 pg of Hg 105% 1200555-CAL5 10000 9926 pg of Hg 99% 1200555-ICV1 1568 1566 pg of Hg 100% 85-115 1200555-CCV1 500.0 505.2 pg of Hg 101% 77-123 1200555-CCB1 10.0 pg of Hg 1200555-CCV2 500.0 536.1 pg of Hg 107% 77-123 1200555-CCV3 500.0 509.0 pg of Hg 102% 77-123 1200555-CCB2 6.77 pg of Hg 1200555-CCV4 500.0 511.2 pg of Hg 102% 77-123

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Containers

Lab ID: 

### 1229025-01 Report Matrix: 

### Influent Sample Type: 

### Sample Received: 

### 07/18/2012 Sample: 

### BioReactor 1 Inf Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71628390 10 Cooler

none n/a 500 mL Bottle FLPE Hg-T

Lab ID: 

### 1229025-02 Report Matrix: 

### Influent Sample Type: 

### Sample Received: 

### 07/18/2012 Sample: 

### BioReactor 1 Inf Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71659890 20 Cooler

none n/a 250 mL Bottle FLPE Hg-T Comments: 

### Split from 500 mL

Lab ID: 

### 1229025-03 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 07/18/2012 Sample: 

### BioReactor 1 Inf Hg Blk Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71628390 10 Cooler

none n/a 500 mL Bottle FLPE Hg-T

Lab ID: 

### 1229025-04 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 07/18/2012 Sample: 

### BioReactor 1 Inf Hg Blk Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71659890 20 Cooler

none n/a 250 mL Bottle FLPE Hg-T Comments: 

### split from 500 mL

Lab ID: 

### 1229025-05 Report Matrix: 

### Influent Sample Type: 

### Sample Received: 

### 07/18/2012 Sample: 

### BioReactor 2 Inf Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71628390 10 Cooler

none n/a 500 mL Bottle FLPE Hg-T

Lab ID: 

### 1229025-06 Report Matrix: 

### Influent Sample Type: 

### Sample Received: 

### 07/18/2012 Sample: 

### BioReactor 2 Inf Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71659890 20 Cooler

none n/a 250 mL Bottle FLPE Hg-T Comments: 

### split from 500mL

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Containers

Lab ID: 

### 1229025-07 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 07/18/2012 Sample: 

### BioReactor 2 Inf Hg Blk Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71353280 10 Cooler

none n/a 500 mL Bottle FLPE Hg-T

Lab ID: 

### 1229025-08 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 07/18/2012 Sample: 

### BioReactor 2 Inf Hg Blk Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71659890 20 Cooler

none n/a 250 mL Bottle FLPE Hg-T Comments: 

### split from 500mL

Lab ID: 

### 1229025-09 Report Matrix: 

### Effluent Sample Type: 

### Sample Received: 

### 07/18/2012 Sample: 

### BioReactor 2 Eff Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71628390 10 Cooler

none n/a 500 mL Bottle FLPE Hg-T

Lab ID: 

### 1229025-10 Report Matrix: 

### Effluent Sample Type: 

### Sample Received: 

### 07/18/2012 Sample: 

### BioReactor 2 Eff Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71659890 20 Cooler

none n/a 250 mL Bottle FLPE Hg-T Comments: 

### split from 500mL

Lab ID: 

### 1229025-11 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 07/18/2012 Sample: 

### BioReactor 2 Eff Hg Blk Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71353280 10 Cooler

none n/a 500 mL Bottle FLPE Hg-T

Lab ID: 

### 1229025-12 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 07/18/2012 Sample: 

### BioReactor 2 Eff Hg Blk Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71659890 20 Cooler

none n/a 250 mL Bottle FLPE Hg-T Comments: 

### split from 500mL

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Containers

Lab ID: 

### 1229025-13 Report Matrix: 

### Effluent Sample Type: 

### Sample Received: 

### 07/18/2012 Sample: 

### BioReactor 2 Eff DUP Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71629390 10 Cooler

none n/a 500 mL Bottle FLPE Hg-T

Lab ID: 

### 1229025-14 Report Matrix: 

### Effluent Sample Type: 

### Sample Received: 

### 07/18/2012 Sample: 

### BioReactor 2 Eff DUP Collected: 

### 07/16/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71659890 20 Cooler

none n/a 500 mL Bottle FLPE Hg-T Comments: 

### split from 500mL



# Shipping Containers

Cooler Tracking No: 

### 535305192208 via FedEx Temperature: 

### 1.4 °C Coolant Type: 

### Ice Description: 

### Cooler Damaged in transit? 

### No Returned to client? 

### No Custody seals present? 

### No Custody seals intact? 

### No COC present? 

### Yes Received: 

### July 18, 2012 8:45

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

## July 25 , 201 2

Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 (704) 875-5245 Project: Allen Shay/MillerCreek (LIMS#J12070244)
Dear Mr. Perkins, Attached is the report associated with four (4) aqueous samples submitted for selenium speciation analysis on July 17, 2012

.The samples were received in a sealed cooler at-0. 5 ° C on July 18, 2012

.Selenium speciation analysis was performed via ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP-CRC-MS). Any issues associated with the analysis are addressed in the following report. If you have any questions, please feel free to contact me at your convenience. Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLC

## Applied Speciation and Consulting, LLC Report prepared for: Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 Project: Allen Shay/MillerCreek (LIMS#J12070244)

July 25 , 2012

1. Sample Reception Four (4) aqueous samples in125mL HDPE bottles (provided by Applied Speciation and Consulting) were submitted for selenium speciation analysi s on July 1 7 , 2012. The samples were received on July 18, 2012 in a sealed container at -0. 5 ° C. The samples were received in a laminar flow clean hood, void of trace metals contamination and ultra-violet radiation, and was designated a discrete sample identifier. An aliquot of each sample was filtered (0.45μm) and each filtrate w asstored in a secure, monitored cryofreezer (maintained at a temperature of -80o

## C) until selenium speciation analysis could be performed via ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP- CRC -MS).

2. Sample Preparation All sample preparation is performed in laminar flow clean hoods known to be free from trace metals contamination. All applied water for dilutions and sample preservatives are monitored for contamination to account for any biases associated with the sample results. Selenium Speciation Analysis by IC-ICP-CRC-MS Prior to analysis, an aliquot of each sample was filtered with a syringe filter (0.45μm) and injected directly into a sealed autosampler vial. No further sample preparation was performed as any chemical alteration of a sample may shift the equilibrium of the system, resulting in changes in speciation ratios. 3. Sample Analysis All sample analysis is preceded by a minimum of a five-point calibration curve spanning the entire concentration range of interest. Calibration curves are performed at the beginning of each analytical day. All calibration curves, associated with each species of interest, are

## standardized by linear regression resulting in a response factor. All sample results are

instrument blank correctedto account for any operational biases associated with the analytical platform. Prior to sample analysis, all calibration curves are verified using second source standards which are identified as initial calibration verification standards (ICV). Ongoing instrument performance is identified by the analysis of continuing calibration verification standards (CCV) and continuing calibration blanks (CCB) at a minimal interval of every ten analytical runs. Selenium Speciation Analysis by IC-ICP-CRC-MS Eachsample for selenium speciation analysis w asanalyzed by ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP- CRC -MS) on July 18, 2012. An aliquot of eachsample is injected onto an anion exchange column and mobilized by a basic (pH > 7) gradient. The eluting selenium species are then introduced into a radio frequency (RF) plasma where energy-transfer processes cause desolvation, atomization, and ionization. The ions are extracted from the plasma through a differentially-pumped vacuum interface and travel through a pressurized chamber (CRC) containing a reaction gas which preferentially reacts with interfering ions of the same target mass to charge ratios (m/z). A solid-state detector detects ions transmitted through the mass analyzer and the resulting current is processed by a data handling system. Retention times for each eluting species are compared to known standards for species identification.

4. Analytical Issues The overall analyses went well and no significant analytical issues were encountered. All quality control parameters associated with the samples were within acceptance limits. The estimated method detection limits (eMDLs) for selenite, selenate, and selenocyanate are generated from replicate analyses of the lowest standard in the calibration curve. Not all selenium species are present in preparation blanks; therefore, eMDL calculations based on preparation blanks are artificially biased low. The eMDL for methylseleninic acid and selenomethionine is calculated from the average eMDL of selenite, selenate, and selenocyanate. The calibration does not contain methylseleninic acid or selenomethionine due to impurities in these standards which would bias the results for other selenium species.

## If you have any questions or concerns regarding this report, please feel free to contact me.

Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLC

### Sample Results

Sample ID Se(IV) Se(VI) SeCN MeSe(IV) SeMe Unknown Se Species (n) FGD Purge Eff ND (<2.2) 723 ND (<1.2) ND (<1.6) ND (<1.6) 0 (0) BioReactor 1 Inf 10.3 487 ND (<0.31) 1.02 ND (<0.40) 0.45 (1) BioReactor 2 Inf 19.6 192 ND (<0.31) 0.75 ND (<0.40) 0 (0) BioReactor 2 Eff ND (<0.56) ND (<0.33) ND (<0.31) ND (<0.40) ND (<0.40) 0 (0) All results reflect the applied dilution and are reported in μg/L ND = Not detected at the applied dilution SeCN = Selenocyanate MeSe(IV) = Methylseleninic acid SeMe = Selenomethionine Unknown Se Species = Total concentration of all unknown Se species observed by IC-ICP-MS n = number of unknown Se species observed Report Generated by: Russell Gerads Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Allen Shay/MillerCreek Contact: Jay Perkins
Date: July 25, 2012 LIMS #J12070244

## Quality Control Summary - Preparation Blank Summary

Analyte (μg/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL* eMDL 250x eMDL 1000x Se(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.0022 0.56 2.2 Se(VI) 0.000 0.000 0.000 0.000 0.000 0.000 0.0013 0.33 1.3 SeCN 0.000 0.000 0.000 0.000 0.000 0.000 0.0012 0.31 1.2 MeSe(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.0016 0.40 1.6 SeMe 0.000 0.000 0.000 0.000 0.000 0.000 0.0016 0.40 1.6 eMDL = Estimated Method Detection Limit *Please see narrative regarding eMDL calculations
Quality Control Summary - Certified Reference Materials Analyte (μg/L) CRM True Value Result Recovery Se(IV) LCS 9.57 9.37 97.9 Se(VI) LCS 9.48 9.09 95.9 SeCN LCS 8.92 8.82 98.9 MeSe(IV) LCS 6.47 6.78 104.7 SeMe LCS 9.32 8.15 87.4 Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Allen Shay/MillerCreek Contact: Jay Perkins LIMS #J12070244 Date: July 25, 2012 Report Generated by: Russell Gerads

## Quality Control Summary - Matrix Duplicates

Analyte (μg/L) Sample ID Rep 1 Rep 2 Mean RPD Se(IV) Batch QC 47.4 48.0 47.7 1.4 Se(VI) Batch QC 22.8 20.7 21.7 9.7 SeCN Batch QC ND (<1.2) ND (<1.2) NC NC MeSe(IV) Batch QC 2.4 2.4 2.4 1.8 SeMe Batch QC ND (<1.6) ND (<1.6) NC NC ND = Not detected at the applied dilution NC = Value was not calculated due to one or more concentrations below the eMDL

Quality Control Summary - Matrix Spike/ Matrix Spike Duplicate Analyte (μg/L) Sample ID Spike Conc MS Result Recovery Spike Conc MSD Result Recovery RPD Se(IV) Batch QC 5560 6427 114.7 5560 6463 115.4 0.6 Se(VI) Batch QC 5045 5465 107.9 5045 5522 109.0 1.0 SeCN Batch QC 4575 4586 100.2 4575 4599 100.5 0.3 Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Allen Shay/MillerCreek Contact: Jay Perkins LIMS #J12070244 Date: July 25, 2012 Report Generated by: Russell Gerads