# FINAL REPORT

MODELING SUPPORT

FOR EXPOSURE ASSESSMENT OF ACETONITRILE

EPA Contract No

. 68-W7-0030 Work Assignment No

. II-1

Submitted to: U .S

. ENVIRONMENTAL PROTECTION AGENCY Office of Pollution Prevention and Toxins

401 M Street, S .W

. Washington, D

.C

. 20460 Project Officer: Catherine Turner Work Assignment Manager : Lynn Delpire Exposure Assessor: Annett Nold

Submitted by : GENERAL SCIENCES CORPORATION

a subsidiary of SAIC 6100 Chevy Chase Drive, Suite 200 Laurel, Maryland 20707

July 10, 1998

# TABLE OF CONTENTS

1

. INTRODUCTION

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 II

. CHEMICAL INFORMATION

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2 III .MODELING RESULTS

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 1

. Air Modeling

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 2

. Water Modeling

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 APPENDIX A - Acetonitrile Air Dischargers, Sorted by Release Quantity

. . . . . . . . . . . . . . . . . . . . . . . . . A-1 APPENDIX B - 1995 Acetonitrile Water Dischargers, Sorted by Release Quantity

. . . . . . . . . . B-1 APPENDIX C - ISCLT3 Modeling Results of Top 1995 Acetonitrile Dischargers

. . . . . . . . . . . . . C-1 APPENDIX D - ISCLT3 Modeling Results of Top 1996 Acetonitrile Dischargers

. . . . . . . . . . . . . D-1 APPENDIX E - SCREEN3 Modeling Results of Top 1995 Acetonitrile Dischargers

. . . . . . . . . E-1 APPENDIX F - ISCST3 Modeling Results of Top 1995 Acetonitrile Dischargers

. . . . . . . . . . . . . . .F-1 APPENDIX G - ISCST3 Modeling Results of Top 1996 Acetonitrile Dischargers

. . . . . . . . . . . .G-1 APPENDIX H - Acute and Chronic Acetonitrile Concentrations at Utility Intakes

. . . . . . . . . . H-1

# I

. INTRODUCTION

This is a modeling support report for the exposure assessment of acetonitrile (CAS No: 75-05-8)

. Nationwide releases to air and surface water bodies reported for acetonitrile for 1995 were retrieved fromthe Toxic Release Inventory System(TRIS) database

. The information was retrieved from EPA CD-ROM 749-C-97003, titled "1987-1995 Toxics Release Inventory" (released in August, 1997)

. Selective 1996 TRIS air release data was also retrieved

. Appendix A summarizes the air release information of all facilities that reported release of acetonitrile in 1995

. For the top 1995 air release facilities, their 1996 air release data is also listed

. Appendix B details 1995 water release information of all facilities that release acetonitrile

. 

# The 1995 data is incorporated with the ISCLT3, SCREEN3, ISCST3, and ReachScan models to estimate acetonitrile's chronic and acute concentrations resulting fromthe reported releases

. For comparison purpose, the 1996 air release data is applied to ISCLT3 and ISCST3 only to estimate the chemical's chronic and acute air concentrations

.

# II

. CHEMICAL INFORMATION

To facilitate the modeling, the fate of acetonitrile in the environment was reviewed

. Chemical properties were presented in ICBt

. Estimated half-lives for acetonitrile in the air and surface waters were selected after review of Howard et

. al.Z,

. The results of the study and certain parameters required by the above models are presented in the following: Molecular Weight (g/mol) : 41 .05 Water Solubility at 20 °C : 1,000g/1 Vapor Pressure at 20 °C: 72.8 torr (Mellan 1977) Half-Life in Surface Water : - 1 week Half-Life in Air: > 54 days

1 Industrial Chemistry Branch (ICB, J

. Tou), 1998

. Acetonitrile Chemistry Report, Exposure evaluation Division, Office of Pollution Prevention and Toxics, USEPA, Feb

. 10, 1998

. Z Howard, P

.H., R .S

. Boethling, W

.F

. Jarvis, W

.M

. Meylan, E.M

. Michalenko, 1991

. Handbook of environmental Degradation Rates

. Lewis Publishers, Chelsea, Michigan

.

# III

. MODELING RESULTS

1

. Air Modeling 1995 and 1996 TRI data of 10 facilities that have 1995 air fugitive release of over 20,000 pounds is used with the following input parameters for air modeling (all parameters are applicable to both stack and fugitive releases unless otherwise indicated) : Duration of Releases: Release Height : Exiting Gas Temperature : Area Source Size: 

# Stack Exit Gas Velocity: Stack Inner Diameter : First Receptor Distance: Site Layout : Other Modeling Options: constant over 365 days per year 10 meters for stack release and 3 meters for fugitive release 293 ° K lOm by lOm(for fugitive release only) 0.01 meter/sec 0.1 meter 100meters flat, rural regulatory default The environmental concentrations were modeled using polar grids at the distances of 100m, 200m, 300m, 400m, 500m, 600m, 700m, and 800mfromeach facility release center

. While ISCST3 (for modeling of 1995 and 1996 data) and SCREEN3 (for modeling of 1995 only) were used for acute concentration calculation, ISCLT3 (for modeling of 1995 and 1996 data) was used for calculating chronic concentration

. The air modeling results are presented in Appendix C through Appendix Gwhere: Appendix C presents the ISCLT3 modeling results for 1995

. Appendix Dpresents the ISCLT3 modeling results for 1996

. Appendix E outlines the SCREEN3 modeling results for 1995

. Appendix F displays the ISCST3 modeling results for 1995

. Appendix Gdisplays the ISCST3 modeling results for 1995

.
2

. Water Modeling The water concentration modeling of the 10 sites that released acetonitrile to receiving water bodies in 1995 was performed using ReachScan with the following input parameters : Duration of Releases : constant over 365 days per year Distance of Search: 100 Km Direction of Search: downstream Type of Search : Flow Type : search for utilities

harmonic mean flow

for chronic and low

flow(7Q10) for acute Appendix Hlists 1995 chronic and acute concentrations in water that occur within 100 km downstreamof each modeled facility

. Note that MLDrepresents the notation for million liters

# per day

. The Hit Codes indicate if the intake is actually on the REACH(Y-yes), on a tributary of

a REACH (N-no), or unknown (?)

. The intake is not in a direct downstreampath if hit code is unspecified

. The estimates listed in the appendix should be seen as rough estimates of high-end contributions due to the following reasons: i

. All release quantities were assumed to occur continuously and at a constant rate during a 365day year since the number of release days were not included fromreports to the TRIS database

. Releases that occurred over shorter periods would result in higher concentrations

. ii

. Complete mixing over the width and depth of streamis assumed

.

# APPENDIX A Acetonitrile Air Dischargers, Sorted by Release Quantity

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# APPENDIX B

1995 Acetonitrile Water Dischargers, Sorted by Release Quantity

# p. 15

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# APPENDIX C

ISCLT3 Modeling Results of Top 1995 Acetonitrile Dischargers

# p. 18

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# ~ ~ a

# APPENDIX D

ISCLT3 Modeling Results of Top 1996 Acetonitrile Dischargers

# p. 23

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n~a`

# APPENDIX E

SCREEN3 Modeling Results of Top 1995 Acetonitrile Dischargers

# p. 28



# SCREEN3 Air Modeling Results of Top 1995 Acetonitrile Dischargers Site: DU PONT MEMPHIS PLANT, MEMPHIS, TN 381 Concentration of Acetonitrile due to point release DistaConcentration (uglm^3) U10M USTK MIX HT (M) 1-Hour 24-Hour Stability (M /S) (M/S) (M) 100 8 .76 3.50 3 1 1 320 200 7 .66 3.06 5 1 1 10000 300 7 .03 2.81 5 1 1 10000 400 7 .10 2 .84 6 1 1 10000 500 6 .53 2 .61 6 1 1 10000 600 5.10 2 .28 6 1 1 10000 700 4.92 1 .97 6 1 1 10000 800 4.26 1 .70 6 1 1 10000 

# Plume Sigma Sigma HT (M) Y (M) Z (M) 9.97 12.46 7 .44 9.97 11 .63 6 .24 9.97 16.89 8 .70 9,97 14.64 7.05 9.97 17 .97 8.40 9.97 21 .24 9.69 9.97 24 .46 10.93 9.97 27.63 11 .98 

# Site: CLINTON LABORATORIES, CLINTON, IN 47842 Concentration of Acetonitrile due to point release DistaConcentration (uglm^3) UtOM USTK (M) 1-Hour 24-Hour Stability (M/S) (M /S) 100 ##### 403.60 3 1 1 200 882.30 352.92 5 1 1 300 809.60 323.84 5 1 1 400 817.90 327.16 6 1 1 500 751 .70 300.68 6 1 1 600 656.90 262.76 6 1 1 700 566.30 226.52 6 1 1 800 490.40 196.16 6 1 1 

# MIX HT Plume Sigma Sigma (M) HT (M) Y (M) Z (M) 320 9 .97 12.46 7.44 10000 9.97 11 .63 6 .24 10000 9.97 16.89 8 .70 10000 9.97 14.64 7 .05 10000 9.97 17 .97 8.40 10000 9.97 21 .24 9.69 10000 9.97 24.46 10.93 10000 9.97 27 .63 11 .98 

# Site: HOECHST CELANESE, NARROWS, VA 241241000 Concentration of Acetonitrile due to point release DistaConcentration (uglm^3) U10M USTK (M) 1-Hour 24-Hour Stability (M /S) (M/S) 100 76.66 30.66 3 1 1 200 67 .06 26.82 5 1 1 300 61 .54 24.62 5 1 1 400 62.11 24.87 6 1 1 500 57 .13 22.85 6 1 1 600 49 .93 19.97 6 1 1 700 43 .04 17 .22 6 1 1 800 37 .27 14 .91 6 1 1 

# MIX HT Plume Sigma Sigma (M) HT (M) Y (M) Z (M) 320 9 .97 12.46 7.44 10000 9 .97 11 .63 6 .24 10000 9.97 16.89 8 .70 10000 9.97 14.64 7.05 10000 9.97 17 .97 8.40 10000 9.97 21 .24 9.69 10000 9.97 24 .46 10.93 10000 9.97 27 .63 11 .98 

# Site: AMOCO CHEMICAL C0

. CHOCOLATE BAYOU PLANT, ALVIN, TX 715111488 Concentration of Acetonitrile due to point release DistaConcentration (uglm^3) U10M USTK (M) 1-Hour 24-Hour Stability (M/S) (M /S) 100 16.09 6.44 3 1 1 200 14 .07 5.63 5 1 1 300 12 .91 5.16 5 1 1 400 13 .05 5 .22 6 1 1 500 11 .99 4 .80 6 1 1 600 10.48 4 .19 6 1 1 700 9.03 3.61 6 1 1 800 7.82 3.13 6 1 1 

# MIX HT Plume Sigma Sigma (M) HT (M) Y (M) Z (M) 320 9.97 12.46 1 .44 10000 9.97 11 .63 6.24 10000 9.97 16.89 8.70 10000 9.97 14 .64 7.05 10000 9.97 17 .97 8.40 10000 9.97 21 .24 9.69 10000 9.97 24.46 10.93 10000 9 .97 27 .63 11 .98 

# Site : LILLY TECH

. CENTER, INDIANAPOLIS, IN 46221 Concentration of Acetonitrile due to point release DistaConcentration (uglm^3) U10M USTK (M) 1-Hour 24-Hour Stability (M /S) (M/S) 100 174.90 69.96 3 1 1 200 153.00 61 .20 5 1 1 300 140.40 56.16 5 1 1 400 141 .80 56.72 6 1 1 500 130.30 52.12 6 1 1 600 113 .90 45 .56 6 1 1 700 98.19 39 .28 6 1 1 800 85.01 34 .00 6 1 1 

# MIX HT Plume Sigma Sigma (M) HT (M) Y (M) Z (M) 320 9.97 12.46 7.44 10000 9 .97 11 .63 6.24 10000 9 .97 16.89 8.70 10000 9.97 14.64 7.05 10000 9.97 17.97 8 .40 10000 9.97 21 .24 9.69 10000 9.97 24 .46 10.93 10000 9.97 27.63 11 .98 Site: DU PONT MEMPHIS PI-ANT, MEMPHIS, TN 3812~ Concentration of Acetonitrile cue to area release DistaConcentration (ug'm^3) U10M USTK (M) 1-Hour 24-Hour Stability (M/S) (M/S) 100 25,030.00 10,012.00 6 1 1 200 15,260.00 6,104.00 6 1 1 300 8,966.00 3,586.40 6 1 1 400 5,859.00 2,343.60 6 1 1 500 4,141 .00 1,656.40 6 1 1 600 3,097.00 1,238.80 6 1 1 700 2,413 .00 965.20 6 1 1 800 1,964 .00 785 .60 6 1 1 

# Site: CLINTON LABORATORIES, CLINTON, IN 47842 Concentration of Acetonitrile cue to area release DistaConcentration (ug'm^3) U10M USTK (M) 1-Hour 24-Hour Stability (M/S) (M/S) 100 11,400.00 4,560.00 6 1 1 200 6,952.00 2,780.80 6 1 1 300 4,086.00 1,634.40 6 1 1 400 2,670.00 1,068.00 6 1 1 500 1,887.00 754.80 6 1 1 600 1,411 .00 564.40 6 1 1 700 1,100.00 440.00 6 1 1 800 894.90 357.96 6 1 1 MIX HT Plume (M) HT (M) 10000 3 10000 3 10000 3 10000 3 10000 3 10000 3 10000 3 10000 3

MIX HT Plume (M) HT (M) 10000 3 10000 3 10000 3 10000 3 10000 3 10000 3 10000 3 10000 3 

# Site: HOECHST CELANESE, NARROWS, VA 241241000 Concentration of Acetonitrile cue to area release DistaConcentration (ug'm^3) (M) 1-Hour 24-Hour Stability 100 9,185.00 3,674.00 6 200 5,599.00 2,239.60 6 300 3,290.00 1,316.00 6 400 2,150.00 860.00 6 500 1,520.00 608.00 6 600 1,136.00 454.40 6 700 885.50 354.20 6 800 720.70 288.28 6 

# U10M USTK MIX HT Plume (M /S) (M/S) (M) HT (M) 1 1 10000 3 1 1 10000 3 1 1 10000 3 1 1 10000 3 1 1 10000 3 1 1 10000 3 1 1 10000 3 1 1 10000 3 

# Site: AMOCO CHEMICAL CC)

. CHOCOLATE BAYOU PLANT, ALVIN, TX 775111488 Concentration of Acetonitrile cue to area release DistaConcentration (ug'mA3) U10M USTK MIX HT Plume (M) 1-Hour 100 9,067.00 200 5,527.00 24-Hour Stability (M/S) (M/S) (M) HT (M)

3,626.80 6 1 1 10000 3 2,210.80 6 1 1 10000 3 300 3,248.00 1,299.20 400 2,122.00 848.80 500 1,500 .00 600.00 600 1,122 .00 448.80 700 874.20 349.68 800 711 .40 284 .56 1 1 1 1 1 1 1 10000 1 10000 1 10000 1 10000 1 10000 1 10000 3

3 3 3 3 3 6 6 6 6 6 6 

# Site : LILLY TECH

. CENTER, INDIANAPOLIS, IN 46221 Concentration of Acetonitrile cue to area release DistaConcentration (ug'm^3) (M) 1-Hour 24-Hour Stability 100 7,143.00 2,857.20 6 200 4,354.00 1,741 .60 6 300 2,559.00 1,023 .60 6 400 1,672.00 668.80 6 500 1,182.00 472.80 6 600 883 .70 353.48 6 700 688 .60 275.44 6 800 560.40 224.16 6 

# U10M USTK MIX HT Plume (M/S) (M/S) (M) HT (M) 1 1 10000 3 1 1 10000 3 1 1 10000 3 1 1 10000 3 1 1 10000 3 1 1 10000 3 1 1 10000 3 1 1 10000 3 

# E-

# p. 29



# SCREEN3 Air Modeling Results of Top 1995 Acetonitrile Dischargers Site: LYONDELL PETROCHEMICAL C0

. CHANNELVIEWCOMPLEX, TX 77530 Concentration of Acetonitrile due to point release Site: LYONDELL PETROCHEMICAL C0

. CHANNELVIEWCOMPLEX, TX 17530 Concentration of Acetonitrile cue to area release DistaConcentration (uglmA3) UtOM USTK MIX HT Plume Sigma Sigma (M) 1-Hour 24-Hour Stability (M IS) (MIS) (M) HT (M) Y (M) Z (M) 100 179 .10 71 .64 3 1 1 320 9.97 12 .46 7.44 200 156 .60 62 .64 5 1 1 10000 9.97 11 .63 6.24 300 143 .70 57 .48 5 1 1 10000 9.97 16 .89 8,70 400 145 .20 58 .08 6 1 1 10000 9.97 14 .64 7,05 500 133 .40 53 .36 6 1 1 10000 9.97 17 .97 8.40 600 116 .60 46 .64 6 1 1 10000 9.97 21 .24 9.69 700 100.50 40 .20 6 1 1 10000 9.97 24 .46 10.93 800 87 .05 34 .82 6 1 1 10000 9.97 27 .63 11 .98 

# Site: HOECHST CELANESE CORP

. CELRIVER PLANT, ROCK HILL, SC 29730 Concentration of Acetonitrile due to point release DistaConcentration (uglm^3) U10M USTK MIX HT Plume Sigma Sigma (M) 1-Hour 24-Hour Stability (MIS) (M IS) (M) HT (M) Y (M) Z (M) 100 498.00 199 .20 3 1 1 320 9.97 12 .46 7.44 200 435.70 174 .28 5 1 1 10000 9.97 11 .63 6.24 300 399.80 159.92 5 1 1 10000 9.97 16 .89 8.70 400 403.90 161 .56 6 1 1 10000 9.97 14.64 7.05 500 371 .10 148.44 6 1 1 10000 9.97 17 .97 8.40 600 324.30 129.72 6 1 1 10000 9.97 21 .24 9.69 700 279.60 111 .84 6 1 1 10000 9.97 24.46 10.93 800 242.10 96.84 6 1 1 10000 9.97 27 .63 11 .98 

# Site : DIXIE CHEMICAL C0

. INC ., PASADENA , TX 77507 Concentration of Acetonitrile due to point release DistaConcentration (uglm^3) U10M USTK MIX HT Plume Sigma Sigma (M) 1-Hour 24-Hour Stability (MIS) (M IS) (M) HT (M) Y (M) Z (M) 100 33.01 13.20 3 1 1 320 9.97 12.46 7 .44 200 28.88 11 .55 5 1 1 10000 9.97 11 .63 6 .24 300 26.50 10.60 5 1 1 10000 9.97 16.89 8 .70 400 26 .77 10.71 6 1 1 10000 9.97 14.64 7.05 500 24 .60 9.84 6 1 1 10000 9.97 17 .97 8.40 600 21 .50 8 .60 6 1 1 10000 9.97 21 .24 9.69 700 18 .54 7.42 6 1 1 10000 9.97 24.46 10.93 800 16 .05 6 .42 6 1 1 10000 9.97 27 .63 11 .98 

# Site: GOODYEAR TIRE & RUBBER CO ., CHEEK, TX 77705 Concentration of Acetonitrile due to point release DistaConcentration (uglm^3) U10M USTK MIX HT Plume Sigma Sigma (M) 1-Hour 24-Hour Stability (MIS) (M IS) (M) HT (M) Y (M) Z (M) 100 7.12 2.85 3 1 1 320 9.97 12.46 7.44 200 6.23 2.49 5 1 1 10000 9 .97 11 .63 6.24 300 5.72 2.29 5 1 1 10000 9 .97 16.89 8.70 400 5.77 2.31 6 1 1 10000 9 .97 14.64 7.05 500 5.31 2.12 6 1 1 10000 9 .97 17 .97 8.40 600 4 .64 1 .85 6 1 1 10000 9 .97 21 .24 9.69 700 4 .00 1 .60 6 1 1 10000 9.97 24.46 10.93 800 3 .46 1 .38 6 1 1 10000 9.97 27 .63 11 .98 

# Site: TIPPECANOE LABS., SHADELAND, IN 47905 Concentration of Acetonitrile due to point release DistaConcentration (uglm^3) U10M USTK MIX HT Plume Sigma Sigma (M) 1-Hour 24-Hour Stability (M IS) (MIS) (M) HT (M) Y (M) Z (M) 100 84.63 33.85 3 1 1 320 9 .97 12.46 7.44 200 74.04 29.62 5 1 1 10000 9 .97 11 .63 6.24 300 67 .94 27 .18 5 1 1 10000 9.97 16.89 8 .70 400 68 .63 27 .45 6 1 1 10000 9.97 14.64 7.05 500 63 .07 25.23 6 1 1 10000 9.97 17 .97 8 .40 600 55 .12 22.05 6 1 1 10000 9.97 21 .24 9 .69 700 47 .52 19 .01 6 1 1 10000 9.97 24 .46 10.93 800 41 .15 16 .46 6 1 1 10000 9.97 27 .63 11 .98 

# E-2 DistaConcentration (ug'm^3) U10M USTK MIX HT Plume (M) 1-Hour 24-Hour Stability (M IS) (M IS) (M) HT (M) 100 6,635.00 2,654.00 6 1 1 10000 3 200 4,045.00 1,618.00 6 1 1 10000 3 300 2,377.00 950.80 6 1 1 10000 3 400 1,553.00 621 .20 6 1 1 10000 3 500 1,098 .00 439.20 6 1 1 10000 3 600 820.90 328.36 6 1 1 10000 3 700 639 .70 255.88 6 1 1 10000 3 800 520.60 208.24 6 1 1 10000 3 

# Site: HOECHST CELANESE CORP

. CELRIVER PLANT, ROCK HILL, SC 29730 Concentration of Acetonitrile cue to area release DistaConcentration (ugmA3) U10M USTK MIX HT Plume (M) 1-Hour 24-Hour Stability (MIS) (MIS) (M) HT (M) 100 6,434 .00 2,573.60 6 1 1 10000 3 200 3,922 .00 1,568.80 6 1 1 10000 3 300 2,305 .00 922.00 6 1 1 10000 3 400 1,506 .00 602.40 6 1 1 10000 3 500 1,065 .00 426 .00 6 1 1 10000 3 600 796.10 318 .44 6 1 1 10000 3 700 620.30 248.12 6 1 1 10000 3 800 504.90 201 .96 6 1 1 10000 3 

# Site: DIXIE CHEMICAL C0

. IdC ., PASADENA , TX 77507 Concentration of Acetonitrile cue to area release DistaConcentration (ug m^3) U10M USTK MIX HT Plume (M) 1-Hour 24-Hour Stability (MIS) (MIS) (M) HT (M) 100 6,328.00 2,531 .20 6 1 1 10000 3 200 3,857.00 1,542 .80 6 1 1 10000 3 300 2,267.00 906.80 6 1 1 10000 3 400 1,481 .00 592.40 6 1 1 10000 3 500 1,047.00 418.80 6 1 1 10000 3 600 783.00 313.20 6 1 1 10000 3 700 610.10 244.04 6 1 1 10000 3 800 496 .50 198.60 6 1 1 10000 3 

# Site: GOODYEAR TIRE 8 ROBBER CO., CHEEK, TX 77705 Concentration of Acetonitrile cue to area release DistaConcentration (ug'm^3) U10M USTK MIX HT Plume (M) 1-Hour 24-Hour Stability (M IS) (M IS) (M) HT (M) 100 3,861 .00 1,544 .40 6 1 1 10000 3 200 2,353.00 941 .20 6 1 1 10000 3 300 1,383,00 553 .20 6 1 1 10000 3 400 903.70 361 .48 6 1 1 10000 3 500 638.80 255 .52 6 1 1 10000 3 600 477.70 191 .08 6 1 1 10000 3 700 372.20 148.88 6 1 1 10000 3 800 302.90 121 .16 6 1 1 10000 3 

# Site: TIPPECANOE LABS., SHADELAND, IN 47905 Concentration of Acetonitrile cue to area release DistaConcentration (ug'm^3) U10M USTK MIX HT Plume (M) 1-Hour 24-Hour Stability (MlS) (M IS) (M) HT (M) 100 3,400.00 1,360 .00 6 1 1 10000 3 200 2,073.00 829 .20 6 1 1 10000 3 300 1,218.00 487.20 6 1 1 10000 3 400 795.90 318.36 6 1 1 10000 3 500 562.60 225.04 6 1 1 10000 3 600 420.70 168.28 6 1 1 10000 3 700 327.80 131 .12 6 1 1 10000 3 800 266 .80 106.12 6 1 1 10000 3 

# 29

# APPENDIX F

ISCST3 Modeling Results of Top 1995 Acetonitriile Dischargers

# p. 31

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# p. 41



# ISCST3 Air Modeling Results of Top 1995 Acetonitrile Dischargers The Maximum

501-Hour and 24-Hour Acetonitrile Concentrations

Site: DU PONT MEMPHIS PLANT The maximum 50 1-hour average acetonitrile Concentration values in uglmA3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 15,934 .10 88062021 0.00 100 .00 26 12,266 .90 38092622 -92.39 38.27 2 15,732 .44 88081821 -38.27 92.39 27 12,156 .32 38080922 -70.71 70.71 3 15,456 .89 88012420 0.00 -100.00 28 12,023 .37 38081422 -38.27 92.39 4 15,387 .57 88092019 38.27 -92.39 29 12,023 .37 38082522 -38 .27 92 .39 5 15,387 .57 88100204 38.27 -92.39 30 12,023 .37 38091401 -38 .27 92 .39 6 15,387 .53 88100124 -92.39 38.27 31 12,017 .74 38030103 -92 .39 38.27 7 15,367 .56 88112403 -70.71 70.71 32 11,999 .01 88090520 -38 .27 -92.39 8 15,285 .60 88110107 70.71 70.71 33 11,997 .05 38082723 70 .71 70.71 9 15,198 .51 88081405 -70.71 70.71 34 11,987 .98 38120518 38 .27 92 .39 10 15,115.22 88081322 0 .00 100

.00 35 11,987 .96 88121719 92 .39 38.27 11 15,100 .14 88092523 -70.71 -70.71 36 11,950 .57 38061522 0.00 100 .00 12 14,604.83 88091320 92 .39 -38.27 37 11,950.57 38091304 0.00 100 .00 13 14,505.07 88080624 -100.00 0 .00 38 11,899.34 38081624 -100 .00 0.00 14 13,802.20 88022823 -38 .27 92 .39 39 11,899.34 88051904 -100 .00 0.00 15 13,802.20 88072901 -38 .27 92 .39 40 11,867 .60 38080301 -38 .27 92 .39 16 13,408.26 88090122 -100 .00 0 .00 41 11,799.34 88112319 92 .39 -38 .27 17 13,408.26 88112305 0.00 -100.00 42 11,799.33 38071102 -38 .27 92 .39 18 13,143.76 88043023 -92 .39 38 .27 43 11,774.10 38080321 -100 .00 0.00 19 12,951 .25 88072805 70 .71 70.71 44 11,658.72 38121017 92 .39 38 .27 20 12,951 .25 88042823 70 .71 70.71 45 11,592.67 38061002 0.00 -100.00 21 12,708.08 88092602 -38 .27 -92 .39 46 11,592.67 38101202 0.00 -100 .00 22 12,708.08 88010820 -38 .27 -92 .39 47 11,592.66 38063004 -100 .00 0.00 23 12,708.04 88050120 -92 .39 -38 .27 48 11,592.66 88030707 -100 .00 0.00 24 12,708.03 88111402 -92 .39 -38 .27 49 11,578.67 38082003 38 .27 92 .39 25 12,280.34 88080406 -38 .27 92 .39 50 11,578.67 38090503 92 .39 38 .27 

# The maximum 50 24-hour average acetonitrile Concentration values in ug/mA3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 2,337 .94 88032224 0.00 100 .00 26 1,443 .70 38041224 0.00 -100.00 2 2,178 .88 88120624 38.27 92.39 27 1,435 .79 38032024 70.71 70.71 3 2,030.57 88110124 70.71 70.71 28 1,410.01 88101924 -100.00 0.00 4 2,017 .33 88080524 0.00 100 .00 29 1,403 .77 88120424 -38.27 -92.39 5 1,925 .95 88100524 -38.27 -92.39 30 1,402 .74 38103024 -38.27 -92.39 6 1,852 .13 88090124 -100.00 0.00 31 1,390.04 38040824 -38.27 -92.39 7 1,849.88 88090924 -100.00 0.00 32 1,385.80 38073024 70.71 70 .71 8 1,814.93 88101524 0.00 100 .00 33 1,384.60 88062024 0 .00 100.00 9 1,696.58 88092224 0.00 100 .00 34 1,381 .51 88122924 -100.00 0.00 10 1,666.70 88020124 0.00 100.00 35 1,365.59 38021624 0 .00 100.00 11 1,654.33 88060624 -100 .00 0.00 36 1,349.37 38083124 -92 .39 -38 .27 12 1,624.46 88111324 0.00 100.00 37 1,336.95 88090624 -38 .27 -92 .39 13 1,593.52 88070124 -100 .00 0.00 38 1,333.39 ,38012724 0.00 100.00 14 1,581 .74 88121024 92 .39 38 .27 39 1,330.30 .38112324 0.00 -100 .00 15 1,565 .54 88090224 -70.71 70 .71 40 1,325.40 88062424 70.71 70 .71 16 1,561 .34 88110224 0.00 100.00 41 1,324.32 88070524 0.00 100.00 17 1,551 .16 88083024 -70.71 -70.71 42 1,321 .15 38100724 -38.27 -92 .39 18 1,531 .20 88112124 -38.27 -92 .39 43 1,317 .17 ~38052624 -70.71 -70.71 19 1,528 .88 88101024 70.71 70.71 44 1,306 .00 ,38100424 -38.27 -92.39 20 1,517 .81 88013124 0 .00 100

.00 45 1,304.91 d8092524 -38.27 -92.39 21 1,512.26 88091824 -38.27 92 .39 46 1,304.15 ,38012624 70.71 -70.71 22 1,501 .42 88090524 -38.27 -92 .39 47 1,300.04 38110824 -100.00 0.00 23 1,477.25 88080624 -100.00 0.00 48 1,299.02 88103024 -70.71 -70.71 24 1,473.26 88031724 -100.00 0.00 49 1,261 .02 38091324 0.00 100.00 25 1,445.02 88073124 38 .27 92 .39 50 1,247.23 38100924 -38 .27 92 .39



# -------------------------------------------------------------------------------------------- F-11 

# 41

# p. 42



# ISCST3 Air Modeling Results of Top 1995 Acetonitrile Dischargers The Maximum

501-Hour and 24-Hour Acetonitrile Concentrations

Site: CLINTON LABORATORIES The maximum 50 1-hour average acetonitrile Concentration values in ug/mA3 Rank Concentration yymmddhh X y Rank Concentration yymmddhh X Y 1 10,332 .54 90081103 100 .00 0

.00 26 6,790.91 90073003 92 .39 38.27 2 7,385 .81 90042306 -70.71 70.71 27 6,789 .65 30062502 92 .39 38.27 3 7,324 .33 90080205 -70.71 -70.71 28 6,656 .28 90071902 92 .39 -38.27 4 7,301 .78 90061103 38.27 -92.39 29 6,655 .65 90062604 92 .39 -38.27 5 7,301 .68 90032021 38.27 -92.39 30 6,289 .27 10082921 92 .39 -38.27 6 7,301 .66 90111304 38.27 -92.39 31 6,121 .85 90062707 92 .39 38.27 7 7,284 .43 90072403 92 .39 38.27 32 6,121 .14 90030919 70.71 70.71 8 7,261 .65 90082524 100 .00 0

.00 33 6,098 .70 90102406 92 .39 38.27 9 7,261 .32 90081124 100 .00 0

.00 34 5,999 .48 90092719 -38.27 92 .39 10 7,229 .87 90111721 0 .00 -100.00 35 5,946 .14 90090120 100.00 0.00 11 7,168.83 90102320 92 .39 -38.27 36 5,882 .09 '10061705 0.00 100 .00 12 7,044.87 90091205 -100.00 0 .00 37 5,769 .39 ')0060704 -70.71 70.71 13 7,035.16 90012303 38 .27 92 .39 38 5,684.85 '10010519 92 .39 38 .27 14 7,011 .87 90091020 -92 .39 38.27 39 5,651 .87 '30072306 70 .71 -70.71 15 7,011 .78 90082605 -92 .39 38 .27 40 5,646.56 90101204 -38 .27 -92 .39 16 7,011 .74 90082505 -92 .39 38 .27 41 5,596.32 90030120 38 .27 92 .39 17 7,007.24 90081103 200.00 0 .00 42 5,539.58 90082104 -70.71 70 .71 18 7,002.51 90042305 -70.71 70.71 43 5,539.33 90041304 -70.71 70 .71 19 6,907.85 90081324 -38 .27 -92 .39 44 5,521 .13 90062804 70 .71 70 .71 20 6,889.20 90082822 100.00 0.00 45 5,519.98 90010804 70 .71 70 .71 21 6,889.19 90081122 0.00 100.00 46 5,493.02 90110622 -70.71 -70.71 22 6,881 .65 90052404 -70.71 -70 .71 47 5,478.89 90081403 92 .39 -38 .27 23 6,819.91 90072505 -38 .27 -92 .39 48 5,478.87 ')0111501 -38 .27 92 .39 24 6,790.91 90071803 38 .27 92 .39 49 5,468.48 '10083103 -38 .27 -92 .39 25 6,790.91 90062806 92 .39 38 .27 50 5,468 .25 '30102219 -38 .27 -92 .39 The maximum 50 24-hour average acetonitrile Concentration values in ug/m^3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 1,101 .46 90103124 70.71 70.71 26 676.98 90062724 70.71 70.71 2 1,054 .35 90081124 100 .00 0.00 27 672 .70 ')0080224 -70.71 -70.71 3 1,015 .52 90072124 70.71 70.71 28 665.85 '10123124 100 .00 0.00 4 1,002 .14 90010624 92 .39 38.27 29 647.62 90061024 38.27 -92.39 5 966

.19 90081824 70.71 70.71 30 644.29 90112024 -70.71 70.71 6 956

.60 90040524 92 .39 38.27 31 638.44 '10031124 70.71 70 .71 7 845.55 90082724 70 .71 70.71 32 634.88 '10101224 -38.27 -92 .39 8 835.29 90010724 70 .71 70 .71 33 624.75 '30073024 92 .39 38 .27 9 821 .63 90032024 38 .27 -92 .39 34 621 .42 90111724 70 .71 -70.71 10 820

.79 90062524 92 .39 38 .27 35 618.08 90111924 -70 .71 70 .71 11 815 .35 90041524 92 .39 38 .27 36 616 .86 '10041124 70 .71 -70.71 12 790.96 90090624 70 .71 70 .71 37 612.20 90102224 -38 .27 -92 .39 13 747 .01 90020824 -38 .27 92 .39 38 598.47 90082424 -92 .39 38 .27 14 744.02 90042324 -70.71 70 .71 39 592 .37 ')0081624 0.00 100.00 15 738.79 90062124 92.39 38 .27 40 591 .83 90022024 -38.27 -92 .39 16 737 .94 90040824 70.71 70.71 41 589.90 90010824 38.27 92.39 17 736

.56 90070424 70.71 70.71 42 585 .70 '10111824 -92.39 38.27 18 723.56 90010824 70.71 70.71 43 580 .32 90081124 200 .00 0.00 19 722.79 90091724 -38.27 -92.39 44 575.72 30083124 -70 .71 70.71 20 719.20 90062724 92 .39 38 .27 45 575.34 '10071724 70.71 70 .71 21 715.22 90082824 70.71 70 .71 46 573.52 30060724 -70 .71 70 .71 22 700

.47 90021224 0.00 100.00 47 570 .01 90072324 70 .71 -70.71 23 698.66 90033024 -38 .27 92 .39 48 567.43 ')0102524 38 .27 -92 .39 24 686

.58 90120924 70 .71 70 .71 49 566 .95 '30021124 70 .71 -70.71 25 677.72 90062824 70 .71 70 .71 50 566 .38 90102424 92 .39 38 .27



# -------------------------------------------------------------------------------------------- F-12

# p. 43



# ISCST3 Air Modeling Results of Top 1995 Acetonitrile Dischargers The Maximum501-Hour and 24-Hour Acetonitrile Concentrations
Site: HOECHST CELANESE The maximum 50 1-hour average acetonitrile Concentration values in uglm^3 Rank Concentration yymmddhh X y Rank Concentration yymmddhh X Y 1 5,948 .20 90022821 70.71 -70.71 26 5,547 .05 ')0021223 0 .00 100

.00 2 5,926 .85 90091001 70.71 70.71 27 5,547 .05 't0010701 0 .00 100

.00 3 5,926 .81 90102905 70.71 70.71 28 5,467 .36 't0072004 38 .27 92.39 4 5,897 .84 90071902 -70.71 -70.71 29 5,467 .32 90053102 38 .27 92 .39 5 5,897 .80 90112019 -70.71 -70 .71 30 5,467 .30 90120823 92 .39 38.27 6 5,865 .97 90082723 38.27 92.39 31 5,456 .61 '30110320 -92 .39 38 .27 7 5,865.92 90072001 38 .27 92.39 32 5,456.60 '10042305 -92 .39 38 .27 8 5,865.87 90012706 38 .27 92 .39 33 5,065.15 '10062601 -38 .27 92 .39 9 5,665.58 90120703 38 .27 92 .39 34 5,065.15 90070224 -38 .27 92 .39 10 5,665.58 90111405 38 .27 92 .39 35 4,958.09 90111418 38 .27 92 .39 11 5,646.96 90082522 -92 .39 38 .27 36 4,918.92 90020521 38 .27 92 .39 12 5,639.62 90080324 -70.71 70 .71 37 4,851 .24 90082819 70 .71 70 .71 13 5,639.61 90121922 -70.71 70 .71 38 4,847.66 '10100119 70 .71 70 .71 14 5,609.70 90090220 70 .71 70 .71 39 4,823.56 '10011019 38 .27 -92 .39 15 5,609.61 90051403 70 .71 70 .71 40 4,823.56 30022002 38 .27 -92 .39 16 5,609 .59 90010902 70 .71 70 .71 41 4,823 .52 90080801 -92 .39 38 .27 17 5,577 .60 90062002 -70.71 70 .71 42 4,752 .93 90053123 70.71 70 .71 18 5,577 .60 90092702 -70.71 70 .71 43 4,752 .91 90013106 70.71 70 .71 19 5,577 .59 90121108 -70.71 70 .71 44 4,752 .91 '30102904 70.71 70.71 20 5,562 .43 90071906 -38 .27 -92 .39 45 4,749 .84 ')0062623 -70.71 70.71 21 5,560.10 90090124 0.00 100.00 46 4,749 .84 '10081602 -70.71 70.71 22 5,560.09 90071524 0.00 100 .00 47 4,749 .84 90010906 -70.71 70.71 23 5,560.09 90100703 0.00 100 .00 48 4,657 .71 '30081121 -70.71 70.71 24 5,560.09 90010624 0.00 100 .00 49 4,577 .88 30090520 92 .39 38.27 25 5,547 .06 90092421 0.00 100 .00 50 4,501 .80 90062204 -92 .39 38.27 

# The maximum 50 24-hour average acetonitrile Concentration values in uglm^3 Rank Concentration yymmddhh X y Rank Concentration yymmddhh X Y 1 782 .16 90111424 38 .27 92 .39 26 520 .69 90092524 38 .27 92 .39 2 677 .04 90012824 70 .71 70 .71 27 516.59 '10120724 0.00 100.00 3 662 .79 90030224 70 .71 70 .71 28 516.39 90032624 92 .39 38 .27 4 654.46 90030824 -70.71 70 .71 29 514 .95 ',30040124 100 .00 0.00 5 642.61 90091324 0.00 100.00 30 509.21 ')0021424 70.71 70.71 6 623 .60 90100224 70.71 70.71 31 502 .27 10092124 -38.27 92.39 7 613 .66 90120924 92.39 38.27 32 497 .68 ')0022824 38.27 -92.39 8 610

.32 90071124 70.71 70.71 33 485.92 ')0122824 -70.71 70.71 9 583.14 90061624 -70.71 70.71 34 484.81 90090124 -38.27 92 .39 10 570

.83 90082824 70.71 70.71 35 479.43 90092924 -38.27 92 .39 11 567.28 90111224 92 .39 -38.27 36 479.00 ')0010124 92.39 -38.27 12 567.09 90083124 -70 .71 70.71 37 478.47 't0102424 0 .00 -100 .00 13 566

.98 90080924 -70.71 70 .71 38 477.88 ',30022824 70 .71 -70.71 14 566.59 90091124 -70.71 70 .71 39 476 .51 '10022024 38 .27 -92 .39 15 563 .21 90072024 38 .27 92 .39 40 466.14 't0112724 -38 .27 92 .39 16 559.05 90021224 0.00 100.00 41 464 .93 90012624 92.39 -38 .27 17 556.17 90031124 70.71 70.71 42 463.91 ')0013124 70.71 70.71 18 537 .36 90012224 100 .00 0.00 43 461 .85 't0011524 70.71 70.71 19 536

.43 90120624 70.71 70.71 44 460 .30 90070424 70.71 70.71 20 533.99 90102924 70.71 70.71 45 458.90 '10101624 -38.27 92 .39 21 529.24 90092024 0 .00 -100.00 46 456 .91 90070924 70.71 70 .71 22 525.29 90072024 70.71 70 .71 47 455.09 90070524 92 .39 38 .27 23 522.75 90031024 92 .39 38 .27 48 449 .72 't0032824 -70.71 70 .71 24 521 .56 90020824 0.00 100.00 49 449 .42 '30020324 -38 .27 92 .39 25 521 .28 90031824 92 .39 -38 .27 50 447.93 90091324 70 .71 70 .71



# -------------------------------------------------------------------------------------------- F-13
41

# p. 44



# ISCST3 Air Modeling Results of Top 1995 Acetonitrile Dischargers The Maximum

501-Hour and 24-Hour Acetonitrile Concentrations

Site : AMOCO CHEMICAL C0

. CHOCOLATE BAYOU PLANT The maximum 50 1-hour average acetonitrile Concentration values in ug/mA3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 5,871 .74 88072121 70 .71 -70.71 26 5,290.81 38041305 92 .39 -38 .27 2 5,871 .73 88051805 70 .71 -70.71 27 5,254.70 38091401 0.00 -100 .00 3 5,807.51 88051503 92 .39 -38 .27 28 5,254.69 38030420 0.00 -100 .00 4 5,747.62 88102604 -100 .00 0.00 29 5,254 .69 38120507 0.00 -100 .00 5 5,699.30 88050503 92 .39 -38 .27 30 5,000.05 38042623 92 .39 -38 .27 6 5,699 .30 88041304 92 .39 -38 .27 31 5,000.04 38020622 -38 .27 92 .39 7 5,699 .30 88121704 92 .39 -38 .27 32 4,857 .37 38061906 0.00 -100 .00 8 5,599 .50 88060104 0.00 -100 .00 33 4,857 .36 88061705 0.00 -100 .00 9 5,592 .73 88082523 92.39 38 .27 34 4,857 .35 88100502 0.00 -100 .00 10 5,574 .37 88121223 38.27 -92 .39 35 4,761 .56 38082801 38.27 -92 .39 11 5,567 .12 88040201 70.71 -70.71 36 4,761 .56 38022006 38.27 -92 .39 12 5,567 .12 88121405 70.71 -70.71 37 4,696 .00 38090906 100 .00 0.00 13 5,537 .45 88051423 70.71 70.71 38 4,691 .80 38092003 70.71 70.71 14 5,505 .89 88040906 70.71 -70.71 39 4,691 .79 38081224 70.71 70.71 15 5,490.86 88062305 -38.27 -92 .39 40 4,691 .79 ~38102024 70.71 70.71 16 5,490.84 88122102 -38.27 -92 .39 41 4,603 .70 d8082921 -92.39 -38.27 17 5,490.83 88111624 -38.27 -92 .39 42 4,585 .96 88022724 70.71 -70.71 18 5,470.26 88011904 -70.71 -70.71 43 4,535 .90 ~38081624 -70.71 -70.71 19 5,470.25 88101304 -70.71 -70.71 44 4,535 .89 38060604 -70.71 -70.71 20 5,421 .34 88070522 -92.39 -38.27 45 4,535 .89 38082723 -70.71 -70.71 21 5,421 .34 88100922 -92.39 -38.27 46 4,518 .89 38082706 92 .39 38.27 22 5,421 .33 88101524 -92.39 -38.27 47 4,488 .92 38100424 -92 .39 -38.27 23 5,421 .33 88112619 -92.39 -38.27 48 4,488 .91 38121407 -38.27 -92.39 24 5,421 .33 88011505 -92 .39 -38.27 49 4,463 .42 ,38120518 38 .27 -92.39 25 5,386 .44 88091422 38 .27 -92.39 50 4,403 .80 ;38112821 -70.71 70.71 

# The maximum 50 24-hour average acetonitrile Concentration values in ug/m^3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 841 .36 88113024 0.00 -100.00 26 459.27 38071724 38 .27 92 .39 2 738.42 88121224 38 .27 -92 .39 27 455 .60 38051424 70 .71 70 .71 3 667 .06 88112124 0.00 -100 .00 28 453 .66 38020824 -100 .00 0.00 4 606.33 88090424 0.00 -100 .00 29 450.13 88100624 -92 .39 -38 .27 5 603 .78 88092524 0.00 -100 .00 30 443 .35 88040924 70.71 -70.71 6 585.82 88012124 92.39 -38 .27 31 439.80 38020324 0.00 -100 .00 7 552 .15 88032024 38.27 92.39 32 438.31 88022024 92.39 -38.27 8 545.00 88092624 -38.27 -92 .39 33 426.60 88073024 -92.39 -38.27 9 540.63 88041324 92.39 -38 .27 34 420.93 38110324 -38.27 92.39 10 534.69 88093024 0.00 -100.00 35 419.32 88010224 -38.27 -92.39 11 529.00 88090524 0.00 -100.00 36 414.29 88010524 -70.71 -70.71 12 522.89 88060424 0 .00 -100.00 37 411 .90 38051824 70.71 -70.71 13 514.96 88060624 -70 .71 -70.71 38 411 .78 38112224 -38.27 -92 .39 14 503.08 88071324 0.00 100.00 39 410 .77 ;38012324 38 .27 92 .39 15 499

.80 88032524 70 .71 70 .71 40 405.79 88092324 0.00 100.00 16 499.35 88100324 0.00 -100 .00 41 403.19 38040424 -92 .39 38 .27 17 491 .95 88100224 38.27 -92 .39 42 401 .64 ;38050424 38.27 -92 .39 18 487 .14 88070124 0.00 100.00 43 400.10 88072224 38.27 -92 .39 19 485.27 88071624 0.00 100.00 44 399.48 38070224 38.27 92.39 20 485.07 88072724 70.71 70.71 45 397 .01 38122024 -38.27 92.39 21 482 .19 88050924 0.00 100 .00 46 394 .23 88103024 -70.71 -70.71 22 478.98 88101724 0.00 100 .00 47 392 .76 38030524 38.27 92.39 23 474.61 88050824 0 .00 100

.00 48 392.18 38030324 38.27 -92.39 24 472.12 88092224 0 .00 100

.00 49 391 .50 88121724 70.71 -70.71 25 464.27 88032324 -70 .71 70.71 50 391 .01 38110824 0 .00 100.00



# -------------------------------------------------------------------------------------------- F-14 

# 43

# p. 45



# ISCST3 Air Modeling Results of Top 1995 Acetonitrile Dischargers The Maximum

501-Hour and 24-Hour Acetonitrile Concentrations

Site : LILLY TECH

. CENTER The maximum 50 1-hour average acetonitrile Concentration values in ug/m^3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 6,470.56 90081103 100 .00 0

.00 26 4,251 .95 90073003 92 .39 38.27 2 4,625 .56 90042306 -70.71 70.71 27 4,251 .73 '30062502 92 .39 38.27 3 4,586 .52 90080205 -70.71 -70.71 28 4,168 .13 '30071902 92 .39 -38.27 4 4,572 .86 90061103 38.27 -92.39 29 4,168 .02 ')0062604 92 .39 -38.27 5 4,572 .85 90032021 38.27 -92.39 30 3,938 .87 '10082921 92 .39 -38.27 6 4,572 .84 90111304 38.27 -92.39 31 3,788 .02 ')0062707 92.39 38.27 7 4,561 .66 90072403 92.39 38.27 32 3,784 .00 '10102406 92 .39 38.27 8 4,547 .42 90082524 100 .00 0

.00 33 3,782 .92 '10030919 70.71 70.71 9 4,547 .36 90081124 100 .00 0

.00 34 3,714 .19 't0092719 -38.27 92.39 10 4,527 .81 90111721 0.00 -100.00 35 3,687 .02 '10090120 100 .00 0

.00 11 4,489 .71 90102320 92.39 -38.27 36 3,682 .84 ')0061705 0.00 100 .00 12 4,411 .35 90091205 -100.00 0.00 37 3,612 .82 '10060704 -70.71 70.71 13 4,405 .82 90012303 38.27 92.39 38 3,559 .94 '10010519 92 .39 38.27 14 4,391 .32 90091020 -92.39 38.27 39 3,536 .25 ')0101204 -38.27 -92.39 15 4,391 .30 90082605 -92.39 38.27 40 3,504 .21 ')0072306 70.71 -70.71 16 4,391 .30 90082505 -92.39 38.27 41 3,478 .12 ')0030120 38.27 92.39 17 4,385 .57 90042305 -70.71 70.71 42 3,469 .21 ')0082104 -70.71 70.71 18 4,325 .70 90081324 -38.27 -92.39 43 3,469 .17 ')0041304 -70.71 70.71 19 4,313 .85 90082822 100 .00 0.00 44 3,456 .96 ')0062804 70.71 70.71 20 4,313 .85 90081122 0.00 100 .00 45 3,456 .76 ')0010804 70.71 70.71 21 4,309 .43 90052404 -70.71 -70.71 46 3,439 .85 '10110622 -70.71 -70.71 22 4,284 .94 90081103 200 .00 0.00 47 3,431 .25 't0081403 92.39 -38.27 23 4,270.85 90072505 -38.27 -92.39 48 3,431 .25 '10111501 -38.27 92.39 24 4,251 .95 90071803 38.27 92.39 49 3,424 .42 ')0083103 -38.27 -92.39 25 4,251 .95 90062806 92.39 38.27 50 3,424 .38 ')0102219 -38.27 -92.39 

# The maximum 50 24-hour average acetonitrile Concentration values in ug/m^3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 667.30 90103124 70.71 70.71 26 402 .53 '30033024 -38.27 92 .39 2 647.05 90081124 100 .00 0

.00 27 397.70 90061024 38 .27 -92.39 3 606

.26 90010624 92 .39 38.27 28 394.79 '30062824 70 .71 70.71 4 600

.57 90072124 70.71 70.71 29 390 .71 '10101224 -38 .27 -92 .39 5 593.27 90040524 92 .39 38 .27 30 385.04 90062724 70 .71 70 .71 6 581 .73 90081824 70 .71 70.71 31 384.05 30112024 -70.71 70 .71 7 517.65 90010724 70 .71 70.71 32 379.96 10073024 92 .39 38 .27 8 505.21 90032024 38 .27 -92 .39 33 376 .76 30031124 70 .71 70 .71 9 498.47 90082724 70 .71 70 .71 34 374.41 90111724 70 .71 -70.71 10 497 .38 90062524 92 .39 38 .27 35 373.81 ')0041124 70 .71 -70.71 11 492 .71 90041524 92 .39 38 .27 36 371 .96 '10111924 -70.71 70 .71 12 467 .97 90090624 70 .71 70 .71 37 370.57 '10022024 -38 .27 -92 .39 13 464.31 90020824 -38 .27 92 .39 38 367 .67 90102224 -38 .27 -92 .39 14 463 .60 90042324 -70.71 70 .71 39 363 .95 90082424 -92 .39 38 .27 15 446.73 90091724 -38 .27 -92 .39 40 361 .54 ')0010824 38.27 92.39 16 444.94 90040824 70.71 70 .71 41 351 .67 '10111824 -92.39 38.27 17 442 .53 90010824 70.71 70.71 42 350.55 90081124 200 .00 0.00 18 441 .97 90062724 92.39 38.27 43 349.48 '30072324 70.71 -70.71 19 434.53 90070424 70.71 70.71 44 348.69 't0102524 38.27 -92.39 20 434.16 90062124 92.39 38.27 45 347 .32 't0102424 92 .39 38.27 21 429.95 90082824 70.71 70.71 46 345.00 '10060724 -70.71 70.71 22 412.50 90021224 0.00 100 .00 47 337 .82 't0083124 -70.71 70.71 23 411 .38 90120924 70.71 70.71 48 336.93 10082524 -92 .39 38.27 24 407.44 90123124 100.00 0 .00 49 335.99 90120824 92 .39 38 .27 25 403.92 90080224 -70.71 -70.71 50 334.58 ')0093024 70 .71 -70.71

-------------------------------------------------------------------------------------------- F-15 

# yu

# p. 46



# ISCST3 Air Modeling Results of Top 1995 Acetonitrile Dischargers The Maximum

501-Hour and 24-Hour Acetonitrile Concentrations

Site: LYONDELL PETROCHEMICAL C0

. CHANNELVIEW COMP The maximum 50 1-hour average acetonitrile Concentration values in ug/m^3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 4,296 .86 88072121 70 .71 -70.71 26 3,871 .77 38041305 92.39 -38 .27 2 4,296 .81 88051805 70 .71 -70.71 27 3,845 .33 88091401 0.00 -100 .00 3 4,249 .85 88051503 92 .39 -38 .27 28 3,845 .28 88030420 0.00 -100 .00 4 4,206 .13 88102604 -100 .00 0.00 29 3,845 .27 38120507 0.00 -100 .00 5 4,170.62 88050503 92 .39 -38 .27 30 3,658 .92 88042623 92.39 -38 .27 6 4,170.61 88041304 92 .39 -38 .27 31 3,658 .90 ;38020622 -38 .27 92.39 7 4,170.61 88121704 92 .39 -38 .27 32 3,554 .87 38061906 0.00 -100 .00 8 4,097 .78 88060104 0.00 -100 .00 33 3,554 .77 88061705 0.00 -100 .00 9 4,092 .84 88082523 92 .39 38 .27 34 3,554 .67 ,38100502 0.00 -100 .00 10 4,079 .19 88121223 38 .27 -92 .39 35 3,484 .39 ,38082801 38.27 -92 .39 11 4,073 .88 88040201 70 .71 -70.71 36 3,484 .38 38022006 38.27 -92 .39 12 4,073 .87 88121405 70 .71 -70.71 37 3,436 .42 ,38090906 100 .00 0.00 13 4,052 .45 88051423 70 .71 70 .71 38 3,433 .62 38092003 70.71 70 .71 14 4,029 .14 88040906 70 .71 -70.71 39 3,433 .62 38081224 70.71 70 .71 15 4,018 .47 88062305 -38 .27 -92 .39 40 3,433 .62 88102024 70.71 70 .71 16 4,018 .29 88122102 -38 .27 -92 .39 41 3,369 .28 88082921 -92 .39 -38 .27 17 4,018 .22 88111624 -38 .27 -92 .39 42 3,356 .05 38022724 70.71 -70.71 18 4,003 .24 88011904 -70.71 -70.71 43 3,319 .54 38081624 -70.71 -70.71 19 4,003 .16 88101304 -70.71 -70.71 44 3,319 .53 38060604 -70.71 -70.71 20 3,967 .42 88070522 -92 .39 -38 .27 45 3,319 .53 38082723 -70.71 -70.71 21 3,967 .42 88100922 -92 .39 -38 .27 46 3,307 .21 38082706 92.39 38 .27 22 3,967 .34 88101524 -92 .39 -38 .27 47 3,284 .94 38100424 -92 .39 -38 .27 23 3,967 .33 88112619 -92 .39 -38 .27 48 3,284 .91 ;38121407 -38 .27 -92 .39 24 3,967 .26 88011505 -92 .39 -38 .27 49 3,277 .57 ~38120518 38.27 -92 .39 25 3,941 .88 88091422 38 .27 -92 .39 50 3,232 .46 38021309 38.27 92.39 The maximum 50 24-hour average acetonitrile Concentration values in uglm^3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 619.00 88113024 0.00 -100 .00 26 342 .15 38020824 -100.00 0.00 2 552 .29 88121224 38.27 -92 .39 27 339.98 d8071724 38.27 92.39 3 496.18 88112124 0.00 -100.00 28 333 .42 38051424 70.71 70.71 4 449.24 88090424 0.00 -100.00 29 333 .36 ,38100624 -92.39 -38.27 5 447.39 88092524 0.00 -100.00 30 331 .85 38020324 0 .00 -100.00 6 430

.03 88012124 92 .39 -38.27 31 328.84 ,38040924 70 .71 -70.71 7 406

.80 88032024 38 .27 92.39 32 322.99 ,38022024 92 .39 -38.27 8 400

.70 88092624 -38.27 -92.39 33 317.50 38073024 -92 .39 -38.27 9 400

.51 88093024 0 .00 -100.00 34 316 .71 ,38010224 -38 .27 -92.39 10 396

.08 88041324 92 .39 -38.27 35 310 .41 38112224 -38 .27 -92.39 11 395.41 88060424 0.00 -100.00 36 308.57 88110324 -38 .27 92 .39 12 393.23 88090524 0.00 -100.00 37 307.04 88010524 -70.71 -70.71 13 380

.69 88060624 -70.71 -70.71 38 306 .34 38012324 38 .27 92 .39 14 376.19 88032524 70 .71 70 .71 39 304.64 38040424 -92 .39 38 .27 15 374 .91 88071324 0.00 100.00 40 303 .40 38051824 70 .71 -70.71 16 372 .13 88100324 0.00 -100 .00 41 302 .60 ,38050424 38 .27 -92 .39 17 365.50 88100224 38 .27 -92 .39 42 302 .01 38092324 0.00 100.00 18 362 .34 88050924 0.00 100.00 43 300.21 88072224 38.27 -92 .39 19 361 .52 88071624 0.00 100.00 44 297 .95 38103024 -70.71 -70.71 20 358.97 88070124 0.00 100.00 45 297 .91 ,38122024 -38.27 92.39 21 358.51 88072724 70.71 70.71 46 297 .58 38030324 38.27 -92.39 22 356.89 88101724 0.00 100 .00 47 297 .46 88070224 38.27 92.39 23 355.08 88050824 0.00 100 .00 48 292 .86 88110824 0 .00 100

.00 24 353.33 88092224 0.00 100 .00 49 291 .26 ,38021524 38.27 -92.39 25 349

.11 88032324 -70.71 70.71 50 290 .71 38121724 70.71 -70.71

-------------------------------------------------------------------------------------------- 

# F-16
45

# p. 47



# ISCST3 Air Modeling Results of Top 1995 Acetonitrile Dischargers The Maximum

501-Hour and 24-Hour Acetonitrile Concentrations

Site: HOECHST CELANESE CORP

. CELRIVER PLANT The maximum 50 1-hour average acetonitrile Concentration values in ug/mA3
Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X y 1 4,167 .07 90062004 -70.71 70 .71 26 3,895 .08 '10051121 0.00 100 .00 2 4,167 .07 90092821 -70.71 70 .71 27 3,882 .51 '10040201 -70.71 -70.71 3 4,167 .07 90072321 70 .71 -70.71 28 3,882 .48 90013119 -70.71 -70.71 4 4,167 .07 90082001 70 .71 -70.71 29 3,847.56 90101624 -92 .39 -38 .27 5 4,166.94 90110321 -70.71 70 .71 30 3,823.11 90072924 38 .27 -92 .39 6 4,166.93 90121402 70 .71 -70 .71 31 3,822.74 ')0032721 -92 .39 38 .27 7 4,166.89 90012706 -70.71 70 .71 32 3,754.87 90032202 -38 .27 92 .39 8 4,132.01 90030324 -70 .71 -70

.71 33 3,729.05 90101704 -100 .00 0.00 9 4,113.90 90082424 -92.39 -38.27 34 3,729.03 '10011621 -100 .00 0.00 10 4,113 .29 90011320 -92.39 -38.27 35 3,548 .29 ')0071903 92 .39 -38.27 11 4,096.81 90082123 0 .00 100

.00 36 3,548 .24 '30021306 -38.27 92 .39 12 4,096 .50 90011706 0.00 100 .00 37 3,465 .39 90060806 70.71 70.71 13 4,096 .49 90121004 0.00 100 .00 38 3,447 .57 '30101701 -100.00 0 .00 14 4,078 .95 90020103 -100.00 0 .00 39 3,447 .57 ')0101702 -100.00 0 .00 15 4,044 .62 90082404 92.39 -38.27 40 3,447 .46 90110623 0.00 -100.00 16 4,044 .62 90080224 -38.27 92.39 41 3,447 .44 90041903 -100.00 0 .00 17 3,955 .84 90111421 -92 .39 38.27 42 3,447 .44 90110706 0.00 -100 .00 18 3,955 .84 90122606 38.27 -92.39 43 3,445 .93 '30121306 38.27 92.39 19 3,950.67 90011501 -70.71 70.71 44 3,445 .91 ')0113007 92.39 38 .27 20 3,950.67 90011323 -70.71 70.71 45 3,379.00 90030403 38.27 -92 .39 21 3,930.72 90082824 70 .71 70 .71 46 3,378.99 90053124 -92 .39 38 .27 22 3,930.45 90101421 70 .71 70 .71 47 3,378.97 '10012806 -92 .39 38 .27 23 3,930.09 90032306 70 .71 70 .71 48 3,378.07 '30031519 -38 .27 92 .39 24 3,930.07 90111204 70 .71 70 .71 49 3,332.55 90082022 0.00 100.00 25 3,907.43 90032122 -70 .71 70 .71 50 3,332.51 90102302 0.00 100.00 The maximum50 24-hour average acetonitrile Concentration values in ug/m^3 Rank Concentration yymmddhh X y Rank Concentration yymmddhh X Y 1 1,001 .12 90122524 38 .27 -92.39 26 420 .70 '10080824 -92 .39 -38.27 2 729.76 90082024 70 .71 -70 .71 27 417.32 '10102724 0.00 100.00 3 629

.71 90041424 -38.27 92 .39 28 411 .58 ')0100324 70 .71 -70 .71 4 607.57 90122524 76 .54 -184.78 29 410 .79 30082424 -92 .39 -38.27 5 600

.76 90071924 92 .39 -38.27 30 405.27 90061324 0.00 100 .00 6 581 .52 90011724 0 .00 100

.00 31 399 .61 90120224 -100.00 0 .00 7 559.53 90110724 0 .00 -100.00 32 399.08 90012724 -70.71 70.71 8 550

.39 90101724 -100.00 0 .00 33 397 .63 90070524 70.71 70.71 9 537.90 90102424 0 .00 -100.00 34 394.86 '10101424 70.71 70.71 10 516.84 90092424 38.27 -92.39 35 392 .16 ')0071424 -38.27 92.39 11 510

.35 90072924 38.27 -92.39 36 391 .28 '10110724 0.00 -200.00 12 509.61 90021324 -38.27 92.39 37 390.29 ')0112624 -38.27 92.39 13 488.19 90112724 -38.27 92.39 38 388.78 ')0120724 -38.27 -92.39 14 486

.06 90100524 38.27 -92.39 39 387 .54 ')0052724 70.71 70.71 15 481 .78 90101624 -92.39 -38.27 40 380.37 '10101524 0.00 -100.00 16 472 .57 90091624 70.71 -70.71 41 379.05 '10090224 38.27 -92.39 17 471 .91 90082724 38.27 -92.39 42 377 .78 '10082024 0.00 100 .00 18 465.26 90083024 70.71 -70.71 43 374.84 '10031524 -38.27 92.39 19 453 .33 90110124 38.27 -92.39 44 373 .36 '10101324 0.00 -100.00 20 450.61 90032224 -38.27 92.39 45 366.63 '10102724 0.00 -100.00 21 445.02 90101924 0 .00 -100.00 46 363 .75 ')0122524 114.81 -277 .16 22 434.74 90072524 0 .00 -100.00 47 357 .32 '10062824 38.27 92.39 23 428.60 90122624 38.27 -92.39 48 351 .17 ')0112624 0.00 100 .00 24 422 .40 90010724 -92.39 -38.27 49 350.22 ')0122724 -70.71 -70.71 25 420.93 90082824 70.71 -70.71 50 347 .93 '10111424 -92.39 38.27



# F-17

# p. 48



# ISCST3 Air Modeling Results of Top 1995 Acetonitrile Dischargers The Maximum501-Hour and 24-Hour Acetonitrile Concentrations
Site: DIXIE CHEMICAL C0

. INC The maximum 50 1-hour average acetonitrile Concentration values in ug/m^3 Rank Concentration yymmddhh X y Rank Concentration yymmddhh X Y 1 4,098 .00 88072121 70.71 -70 .71 26 3,692.56 88041305 92 .39 -38 .27 2 4,097.99 88051805 70 .71 -70 .71 27 3,667.35 ,38091401 0.00 -100 .00 3 4,053.17 88051503 92 .39 -38.27 28 3,667.34 ,38030420 0.00 -100 .00 4 4,011 .39 88102604 -100 .00 0.00 29 3,667.34 88120507 0.00 -100 .00 5 3,977.64 88050503 92 .39 -38 .27 30 3,489 .62 38042623 92.39 -38 .27 6 3,977.64 88041304 92 .39 -38 .27 31 3,489 .62 38020622 -38.27 92.39 7 3,977.64 88121704 92 .39 -38 .27 32 3,390.09 88061906 0.00 -100 .00 8 3,908.01 88060104 0.00 -100 .00 33 3,390.07 38061705 0.00 -100 .00 9 3,903.29 88082523 92 .39 38.27 34 3,390.05 38100502 0.00 -100.00 10 3,890.45 88121223 38 .27 -92 .39 35 3,323 .17 ;38082801 38.27 -92.39 11 3,885 .39 88040201 70.71 -70.71 36 3,323 .17 ~38022006 38.27 -92.39 12 3,885 .39 88121405 70.71 -70.71 37 3,277 .42 38090906 100 .00 0

.00 13 3,864 .72 88051423 70.71 70.71 38 3,274 .52 38092003 70.71 70.71 14 3,842 .66 88040906 70.71 -70.71 39 3,274 .52 38081224 70 .71 70 .71 15 3,832 .22 88062305 -38.27 -92.39 40 3,274.52 ,38102024 70 .71 70 .71 16 3,832 .18 88122102 -38.27 -92.39 41 3,213.06 ;38082921 -92 .39 -38 .27 17 3,832 .17 88111624 -38.27 -92.39 42 3,200.64 38022724 70 .71 -70.71 18 3,817 .82 88011904 -70.71 -70 .71 43 3,165.72 i38081624 -70.71 -70.71 19 3,817.80 88101304 -70.71 -70 .71 44 3,165.71 88060604 -70.71 -70.71 20 3,783.67 88070522 -92 .39 -38.27 45 3,165 .71 38082723 -70.71 -70.71 21 3,783.67 88100922 -92 .39 -38 .27 46 3,153 .86 38082706 92.39 38 .27 22 3,783.66 88101524 -92 .39 -38 .27 47 3,132 .91 ;38100424 -92 .39 -38 .27 23 3,783.66 88112619 -92 .39 -38 .27 48 3,132 .89 38121407 -38.27 -92 .39 24 3,783.65 88011505 -92 .39 -38 .27 49 3,116 .58 ,38120518 38.27 -92.39 25 3,759.32 88091422 38 .27 -92 .39 50 3,074 .39 ~38021309 38.27 92.39 

# The maximum 50 24-hour average acetonitrile Concentration values in ug/m^3 Rank Concentration yymmddhh X y Rank Concentration yymmddhh X y 1 587 .63 88113024 0.00 -100.00 26 321 .04 88071724 38 .27 92 .39 2 516.91 88121224 38 .27 -92.39 27 317.98 38051424 70 .71 70 .71 3 466.60 88112124 0 .00 -100.00 28 317.94 38020824 -100 .00 0 .00 4 423.89 88090424 0 .00 -100.00 29 314 .67 38100624 -92 .39 -38 .27 5 422 .11 88092524 0 .00 -100.00 30 310 .00 88040924 70 .71 -70 .71 6 409.03 88012124 92 .39 -38 .27 31 308 .25 .38020324 0.00 -100 .00 7 385 .71 88032024 38 .27 92 .39 32 306 .20 ,38022024 92.39 -38 .27 8 380 .61 88092624 -38 .27 -92 .39 33 298 .42 38073024 -92.39 -38.27 9 377 .37 88041324 92.39 -38 .27 34 293 .94 88010224 -38.27 -92.39 10 374.37 88093024 0.00 -100 .00 35 293.84 38110324 -38.27 92 .39 11 370.00 88090524 0.00 -100.00 36 289.64 38010524 -70 .71 -70.71 12 366

.59 88060424 0.00 -100.00 37 288.57 :38112224 -38.27 -92 .39 13 359.90 88060624 -70 .71 -70.71 38 287.73 .38051824 70 .71 -70.71 14 351 .99 88071324 0.00 100.00 39 287.43 +38012324 38 .27 92 .39 15 350.18 88032524 70 .71 70 .71 40 283 .87 ~38092324 0.00 100.00 16 349.38 88100324 0.00 -100 .00 41 282 .64 38040424 -92.39 38.27 17 344.05 88100224 38.27 -92 .39 42 281 .44 ~38050424 38.27 -92.39 18 340.31 88070124 0.00 100 .00 43 280 .20 ,38072224 38.27 -92.39 19 339

.51 88071624 0 .00 100

.00 44 279.47 ,38070224 38.27 92 .39 20 339.00 88072724 70.71 70.71 45 278.04 ,38122024 -38.27 92 .39 21 337.76 88050924 0.00 100.00 46 276 .37 38103024 -70 .71 -70.71 22 335.12 88101724 0.00 100.00 47 275.09 38030324 38 .27 -92 .39 23 332 .25 88050824 0.00 100.00 48 274.11 38030524 38 .27 92 .39 24 330.52 88092224 0.00 100.00 49 273 .78 ;38121724 70 .71 -70.71 25 325.24 88032324 -70.71 70.71 50 273 .77 38110824 0.00 100 .00

# p. 49



# ISCST3 Air Modeling Results of Top 1995 Acetonitrile Dischargers The Maximum501-Hour and 24-Hour Acetonitrile Concentrations
Site: GOODYEAR TIRE b RUBBER CO The maximum 50 1-hour average acetonitrile Concentration values in uglm^3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 2,500.08 90100602 -70.71 70.71 26 2,331 .46 90083105 0.00 100 .00 2 2,491 .07 90061505 70.71 70.71 27 2,331 .46 ')0031824 0.00 100.00 3 2,491 .07 90070323 70.71 70.71 28 2,297.94 '10081722 38 .27 92 .39 4 2,491 .07 90082022 70.71 70.71 29 2,297.93 '30102820 92 .39 38 .27 5 2,478 .88 90062804 -70.71 -70.71 30 2,297.93 '30031805 92 .39 38 .27 6 2,478.88 90081504 -70.71 -70 .71 31 2,293.44 '10121902 38 .27 -92 .39 7 2,467.72 90120523 -92 .39 -38.27 32 2,252.73 90061804 92 .39 -38 .27 8 2,465.47 90080223 38 .27 92 .39 33 2,237.35 90121823 0.00 -100 .00 9 2,465.47 90081401 38 .27 92 .39 34 2,128 .93 ')0111223 92.39 -38 .27 10 2,465.47 90091506 38 .27 92 .39 35 2,128 .93 ')0111224 92.39 -38 .27 11 2,465.46 90013022 38 .27 92 .39 36 2,067 .46 ')0062004 92.39 38.27 12 2,457.76 90042304 0.00 100 .00 37 2,067 .46 90081023 92.39 38.27 13 2,426 .66 90091805 92 .39 -38 .27 38 2,067 .45 90021119 92.39 38.27 14 2,384 .16 90111424 -100 .00 0.00 39 1,999 .46 ')0081302 0.00 100 .00 15 2,373 .46 90040402 38.27 -92.39 40 1,997 .68 '10082901 70.71 70.71 16 2,373 .46 90110601 38.27 -92.39 41 1,996 .39 '30061805 70.71 -70.71 17 2,370.38 90072922 70.71 -70.71 42 1,990.35 ')0031804 100 .00 0

.00 18 2,370.37 90102724 70.71 -70.71 43 1,960.18 '30091901 -38 .27 -92 .39 19 2,357 .75 90091507 70.71 70.71 44 1,956.23 '10072920 70 .71 -70.71 20 2,357 .74 90021122 70.71 70.71 45 1,931 .29 ')0111404 -70.71 -70.71 21 2,344 .31 90071903 70.71 -70 .71 46 1,924.06 90070123 38 .27 92 .39 22 2,337 .91 90081706 -92.39 -38.27 47 1,924.06 '10082123 92 .39 38 .27 23 2,337.90 90121004 -92 .39 -38.27 48 1,911 .30 '10111501 -92 .39 -38 .27 24 2,336.96 90040201 100.00 0.00 49 1,911 .30 '30120503 -92 .39 -38 .27 25 2,331 .47 90061802 100.00 0.00 50 1,892 .12 90062504 38.27 -92 .39 

# The maximum 50 24-hour average acetonitrile Concentration values in ug/m^3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 359 .62 90121224 0.00 100.00 26 231 .70 90091524 70 .71 70.71 2 345 .39 90042224 0.00 100.00 27 227.43 ')0082024 70 .71 70.71 3 344.30 90102424 38.27 -92.39 28 226.75 '10012624 38 .27 92 .39 4 341 .52 90031824 0.00 100.00 29 224.62 90121124 -70 .71 70 .71 5 312.89 90061424 0 .00 100.00 30 222 .12 '10042324 0 .00 100 .00 6 297.12 90100724 -38 .27 92 .39 31 221 .61 '30091524 38 .27 92 .39 7 293.72 90072324 38 .27 92 .39 32 218 .96 '10101524 -70 .71 70 .71 8 279 .02 90012224 0 .00 100 .00 33 218 .24 't0102824 0.00 -100 .00 9 271 .46 90120824 38 .27 -92 .39 34 215 .51 90080724 -38.27 -92 .39 10 269.54 90060524 0.00 100.00 35 215.03 30061324 0.00 100 .00 11 269.05 90072924 70.71 -70.71 36 213 .45 '10122524 -92.39 -38.27 12 262 .90 90072724 70.71 -70.71 37 208.63 30102024 -92.39 38 .27 13 260

.44 90080224 38.27 92.39 38 208.10 ')0081324 0 .00 100.00 14 256

.12 90120524 -92 .39 -38.27 39 207.91 90121324 0 .00 100.00 15 254.88 90070724 0.00 100.00 40 204.74 '30060324 0.00 100.00 16 251 .29 90012024 0.00 -100 .00 41 204.49 30012124 0.00 -100 .00 17 249.02 90100624 -70.71 70 .71 42 203 .83 '30081524 38.27 92.39 18 246.41 90072524 0.00 100.00 43 201 .65 90060624 0.00 100 .00 19 244.52 90072424 0.00 100 .00 44 200.71 90071024 -38.27 92.39 20 238.50 90121124 -92.39 38.27 45 197.81 90081024 92.39 38.27 21 238.25 90072124 0 .00 100

.00 46 197.36 ')0041724 0 .00 100

.00 22 237.58 90092124 38.27 92 .39 47 197.35 90031824 0 .00 200.00 23 237.12 90111224 92 .39 -38 .27 48 196.11 90122224 38 .27 -92 .39 24 236

.00 90081824 0.00 100.00 49 192.53 '10081924 38 .27 92 .39 25 235.26 90120724 70 .71 -70.71 50 191 .78 90112524 -38 .27 92 .39

# p. 50



# ISCST3 Air Modeling Results of Top 1995 Acetonitrile Dischargers The Maximum501-Hour and 24-Hour Acetonitrile Concentrations
Site : TIPPECANOE LABS The maximum 50 1-hour average acetonitrile Concentration values in uglmA3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 3,080.20 90081103 100.00 0.00 26 2,024.07 90073003 92 .39 38.27 2 2,201 .92 90042306 -70.71 70 .71 27 2,023 .97 ')0062502 92.39 38.27 3 2,183.34 90080205 -70.71 -70.71 28 1,984 .17 '10071902 92.39 -38.27 4 2,176.83 90061103 38 .27 -92 .39 29 1,984 .12 90062604 92.39 -38.27 5 2,176 .83 90032021 38 .27 -92.39 30 1,875 .03 90082921 92.39 -38.27 6 2,176 .82 90111304 38 .27 -92.39 31 1,803 .36 ')0062707 92.39 38.27 7 2,171 .50 90072403 92.39 38.27 32 1,801 .42 ')0102406 92 .39 38.27 8 2,164 .72 90082524 100 .00 0.00 33 1,800.95 90030919 70 .71 70.71 9 2,164 .70 90081124 100 .00 0

.00 34 1,768.21 ')0092719 -38 .27 92 .39 

# 10 2,155 .39 90111721 0.00 -100.00 35 1,755.26 '10090120 100 .00 0 .00 11 2,137 .25 90102320 92 .39 -38.27 36 1,753.16 90061705 0 .00 100 .00 12 2,099.95 90091205 -100.00 0.00 37 1,719.82 90060704 -70 .71 70 .71 13 2,097.32 90012303 38 .27 92 .39 38 1,694.65 '10010519 92 .39 38 .27 14 2,090.41 90091020 -92 .39 38 .27 39 1,683.37 ')0101204 -38 .27 -92 .39 15 2,090.41 90082605 -92 .39 38 .27 40 1,668 .23 '10072306 70.71 -70 .71 16 2,090.40 90082505 -92 .39 38 .27 41 1,655 .78 '10030120 38.27 92.39 17 2,087.68 90042305 -70 .71 70.71 42 1,651 .46 '30082104 -70.71 70.71 18 2,059.18 90081324 -38 .27 -92 .39 43 1,651 .44 90041304 -70.71 70.71 19 2,053 .54 90082822 100.00 0.00 44 1,645 .63 90062804 70.71 70.71 20 2,053 .54 90081122 0.00 100.00 45 1,645 .54 ')0010804 70.71 70.71 21 2,051 .43 90052404 -70.71 -70.71 46 1,637 .48 '10110622 -70.71 -70.71 22 2,040 .09 90081103 200.00 0.00 47 1,633 .39 ')0081403 92 .39 -38.27 23 2,033 .07 90072505 -38.27 -92.39 48 1,633 .39 ')0111501 -38.27 92 .39 24 2,024 .07 90071803 38.27 92.39 49 1,630.14 90083103 -38 .27 -92 .39 25 2,024 .07 90062806 92 .39 38.27 50 1,630.12 90102219 -38 .27 -92 .39 The maximum 50 24-hour average acetonitrile Concentration values in uglmA3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 317 .72 90103124 70 .71 70 .71 26 191 .72 '10033024 -38.27 92.39 2 308.06 90081124 100.00 0.00 27 189.34 ')0061024 38.27 -92.39 3 288.67 90010624 92.39 38.27 28 188.02 !30062824 70.71 70.71 4 286.00 90072124 70.71 70.71 29 186.01 90101224 -38 .27 -92.39 5 282 .44 90040524 92.39 38.27 30 183.41 '10062724 70 .71 70.71 6 276

.99 90081824 70.71 70.71 31 182.88 '30112024 -70.71 70 .71 7 246

.44 90010724 70 .71 70.71 32 180 .91 90073024 92 .39 38 .27 8 240

.53 90032024 38 .27 -92.39 33 179 .42 '10031124 70 .71 70 .71 9 237.38 90082724 70 .71 70 .71 34 178.28 '30111724 70.71 -70.71 10 236.82 90062524 92 .39 38 .27 35 177 .99 '10041124 70.71 -70.71 11 234.60 90041524 92 .39 38 .27 36 177 .11 ')0111924 -70.71 70.71 12 222 .85 90090624 70.71 70 .71 37 176.40 '10022024 -38.27 -92.39 13 221 .04 90020824 -38.27 92.39 38 175.07 90102224 -38.27 -92.39 14 220

.70 90042324 -70.71 70.71 39 173.29 ')0082424 -92.39 38 .27 15 212.68 90091724 -38 .27 -92 .39 40 172.13 90010824 38 .27 92 .39 16 211 .86 90040824 70 .71 70 .71 41 167.45 '10111824 -92 .39 38 .27 17 210.69 90010824 70 .71 70 .71 42 166 .91 90081124 200 .00 0.00 18 210.42 90062724 92 .39 38 .27 43 166.39 ')0072324 70.71 -70.71 19 206.93 90070424 70.71 70 .71 44 166.01 90102524 38.27 -92 .39 20 206.76 90062124 92.39 38.27 45 165 .36 90102424 92.39 38.27 21 204.72 90082824 70.71 70.71 46 164 .27 '10060724 -70.71 70.71 22 196

.44 90021224 0 .00 100

.00 47 160 .88 90083124 -70.71 70.71 23 195.89 90120924 70.71 70.71 48 160 .39 '10082524 -92.39 38 .27 24 193.99 90123124 100 .00 0.00 49 159.98 90120824 92 .39 38 .27 25 192.33 90080224 -70 .71 -70.71 50 159.30 '10093024 70 .71 -70.71

# APPENDIX G

ISCST3 Modeling Results of Top 1996 Acetonitrl'ile Dischargers

# p. 52

N .- A N O No ~- OJ M NM

O N NN ~- L QQ Q QQ

Q Q Q Q Q Q QQ

Q Q Q L_ W

O O ~ N N ~ o o N ~ ^ N N o N N NN N N N N NN n - M m W M W 4~ m N NN N N N Q M L W Y~ ~ r ~ Y~ p> O M ~A O m W M W ~ N

O O

O O ~_ O N N

N O O N_ .- O "O ~- O O ~ M

O O ~ N

O M O ON ~ ~ A m W m ~ N ~ Of OJ Y~ m Nm "O N N '- N O

at~ N

Y7 ~- O

W Y> W

Oa N ~ E O

- - O

Om - O

O - O

O O O O ~- O O ~ r- rO O O 

# m W W m m W m m W ao m ao m

- W om m

- e°o E omo W

m m W m m m amo m m omo m

m m ao E ao T m W m W m W m m W m T oc0 W

M W YJ CM N

o N- n r ~- W t0 W o M W r Q

o r M

OJ '- Ir Q p~ N NN n O cG ~ W

O) ~ cG ~(7 n o M In Ir ~- r n ON O O ~ n N Q QJ Q

~ NW

W m V u~ o N N N Y7 A

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O m O ~ M ~ Y~ ~ p> O M M M m M m m Q 47 of0 0- oW - - - - N Q <G

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Q Q W m Q Q CM mC'J CM n A t0 A r ~C7 W W ~ ~ ~ N ~
- - - - - - - - - - - - - - -- N ~ n N O N r m o N M

O N N N ~ Q Q Q Q Q QQ

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O O O ~ O N

----------

o o ~ O ~ ~- O O ~ M

O O ~ N O M O O N ~ r W

~ u~ W

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O Y7 N~l7 ~ O m W m m N ~ 

## E o o ~ o o ~ o o ~ o 0 0 0 o r o E o ,- ~ .- ~ o 0 0 ~ ~ o 0 0 0 0 0 Wm mW

m WmW

0 W

m m m m m m mW mW

mW m W

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# p. 62



# ISCST3 Air Modeling Results of Top 1996 Acetonitrile Dischargers The Maximum

501-Hour and 24-Hour Acetonitrile Concentrations
Site : DU PONT MEMPHIS PLANT The maximum 50 1-hour average acetonitrile concentration values in uglmA3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 22,623 .63 88062021 0.00 100 .00 26 17,417 .10 88092622 -92 .39 38.27 2 22,337 .18 88081821 -38 .27 92.39 27 17,259.76 88080922 -70 .71 70.71 3 21,946 .02 88012420 0.00 -100.00 28 17,071 .04 88081422 -38 .27 92 .39 4 21,847 .53 88092019 38 .27 -92.39 29 17,071 .04 88082522 -38 .27 92 .39 5 21,847 .50 88100204 38 .27 -92.39 30 17,071 .04 88091401 -38 .27 92 .39 6 21,847 .44 88100124 -92 .39 38 .27 31 17,062 .98 88030103 -92 .39 38 .27 7 21,819.06 88112403 -70.71 70.71 32 17,060 .22 88082723 70 .71 70 .71 8 21,702.87 88110107 70 .71 70 .71 33 17,036 .64 88090520 -38 .27 -92 .39 9 21,579.24 88081405 -70.71 70 .71 34 17,020 .81 88120518 38 .27 92 .39 10 21,461 .12 88081322 0.00 100 .00 35 17,020 .78 88121719 92 .39 38 .27 1 1 21,439.66 88092523 -70.71 -70 .71 36

_ 16,967 .72 88061522 0.00 100.00 12 20,736.39 88091320 92 .39 -38.27 37 16,967 .72 88091304 0.00 100.00 13 20,594.58 88080624 -100 .00 0.00 38 16,894 .99 88081624 -100 .00 0.00 14 19,596.55 88072901 -38 .27 92 .39 39 16,894 .93 88051904 -100 .00 0.00 15 19,596.54 88022823 -38 .27 92 .39 40 16,850 .17 88080301 -38 .27 92 .39 16 19,037 .67 88090122 -100 .00 0.00 41 16,752 .88 88071102 -38 .27 92 .39 17 19,037 .38 88112305 0.00 -100.00 42 16,752 .86 88112319 92 .39 -38 .27 18 18,661 .67 88043023 -92 .39 38 .27 43 16,717 .05 88080321 -100 .00 0.00 19 18,388.69 88072805 70 .71 70 .71 44 16,572 .94 88121017 92.39 38 .27 20 18,388.52 88042823 70 .71 70 .71 45 16,459 .66 88063004 -100 .00 0.00 21 18,043.53 88050120 -92 .39 -38 .27 46 16,459 .56 88061002 0.00 -100 .00 22 18,043.36 88092602 -38 .27 -92 .39 47 16,459 .54 88101202 0.00 -100 .00 23 18,043.25 88010820 -38 .27 -92 .39 48 16,459 .50 88030707 -100 .00 0.00 24 18,043.23 88111402 -92 .39 -38 .27 49 16,439 .74 88082003 38.27 92 .39 25 17,460.07 88080406 -38 .27 92 .39 50 16,439 .67 88090503 92.39 38 .27 The maximum 50 24-hour average acetonitrile concentration values in ug/mA3 

# Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 3,321 .64 88032224 0.00 100 .00 26 2,058.48 88073124 38.27 92.39 2 3,105 .50 88120624 38.27 92.39 27 2,042.25 88032024 70.71 70.71 3 2,883 .38 88110124 70.71 70.71 28 2,003.30 88103024 -38.27 -92.39 4 2,875 .51 88080524 0 .00 100

.00 29 2,002.87 88101924 -100.00 0.00 5 2,742 .43 88100524 -38.27 -92.39 30 1,997.01 88120424 -38.27 -92.39 6 2,633 .91 88090124 -100.00 0.00 31 1,984.49 88040824 -38.27 -92.39 7 2,627 .27 88090924 -100.00 0.00 32 1,973.99 88073024 70 .71 70.71 8 2,581 .26 88101524 0 .00 100

.00 33 1,973.01 88122924 -100.00 0 .00 9 2,409 .28 -88092224 0 .00 100

.00 34 1,970.36 88062024 0.00 100 .00 10 2,380.28 88020124 0 .00 100

.00 35 1,945.67 88021624 0.00 100 .00 11 2,356 .94 88060624 -100.00 0.00 36 1,927.72 88083124 -92 .39 -38.27 12 2,307 .08 88111324 0.00 100 .00 37 1,907.97 88090624 -38 .27 -92 .39 13 2,275 .10 88070124 i ; 00 .00 0 .00 38 1,895.57 88012724 0.00 100.00 14 2,253 .33 88121024 92 .39 38.27 39 1,893 .30 88112324 0.00 -100 .00 15 2,232 .82 88090224 -70.71 70.71 40 1,887 .18 88100724 -38 .27 -92 .39 16 2,224 .78 88110224 0.00 100.00 41 1,886.41 88070524 0.00 100.00 17 2,214.95 88083024 -70.71 -70 .71 42 1,886 .20 88062424 70.71 70 .71 18 2,180.84 88112124 -38 .27 -92 .39 43 1,874 .84 88052624 -70.71 -70.71 19 2,177.00 88101024 70 .71 70 .71 44 1,862 .98 88092524 -38.27 -92 .39 20 2,165.30 88013124 0.00 100.00 45 1,860.17 88100424 -38.27 -92 .39 21 2,155.43 88091824 -38 .27 92 .39 46 1,857 .69 88012624 70.71 -70.71 22 2,144.41 88090524 -38 .27 -92 .39 47 1,852 .05 88103024 -70.71 -70.71 23 2,099 .91 88031724 -100.00 0.00 48 1,845.84 88110824 -100.00 0.00 24 2,097 .44 88080624 -100.00 0.00 49 1,790.45 88091324 0 .00 100

.00 25 2,060.98 88041224 0.00 -100 .00 50 1,779.55 88093024 -70 .71 70.71

# p. 63



# ISCST3 Air Modeling Results of Top 1996 Acetonitrile Dischargers The Maximum

501-Hour and 24-Hour Acetonitrile Concentrations
Site : CLINTON LABORATORIES The maximum 50 1-hour average acetonitrile concentration values in ug/mA3 

# Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X y 1 3,551 .59 90081103 100 .00 0.00 26 2,334 .74 90073003 92.39 38.27 2 2,538 .48 90042306 -70.71 70 .71 27 2,333 .91 90062502 92 .39 38 .27 3 2,517 .73 90080205 -70.71 -70.71 28 2,288 .13 90071902 92 .39 -38.27 4 2,509 .65 90061103 38.27 -92 .39 29 2,287 .71 90062604 92 .39 -38.27 5 2,509 .59 90032021 38.27 -92 .39 30 2,161 .58 90082921 92 .39 -38.27 6 2,509 .57 90111304 38.27 -92 .39 31 2,139 .19 90030919 70.71 70 .71 7 2,503 .93 90072403 92 .39 38 .27 32 2,136 .18 90062707 92 .39 38 .27 8 2,496 .07 90082524 100 .00 0.00 33 2,120.89 90102406 92 .39 38 .27 9 2,495 .86 90081124 100 .00 0.00 34 2,092 .15 90092719 -38.27 92 .39 10 2,484 .95 90111721 0 .00 -100 .00 35 2,069.46 90090120 100 .00 0.00 11 2,480.72 90081103 200 .00 0.00 36 2,022 .34 90061705 0 .00 100.00 12 2,463 .88 90102320 92 .39 -38 .27 37 1,983 .22 90060704 -70.71 70 .71 13 2,421 .78 90091205 -100.00 0.00 38 1,967.29 90072306 70 .71 -70.71 14 2,418 .06 90012303 38.27 92.39 39 1,954.11 90010519 92 .39 38 .27 15 2,410.00 90091020 -92.39 38.27 40 1,942.11 90030120 38 .27 92 .39 16 2,409 .94 90082605 -92.39 38.27 41 1,940.75 90101204 -38 .27 -92 .39 17 2,409 .91 90082505 -92.39 38.27 42 1,904.01 90082104 -70.71 70 .71 18 2,406 .70 90042305 -70 .71 70.71 43 1,903.85 90041304 -70.71 70 .71 19 2,374 .58 90081324 -38.27 -92 .39 44 1,898.15 90062804 70 .71 70 .71 20 2,368 .28 90082822 100 .00 0.00 45 1,897.39 90010804 70 .71 70 .71 21 2,368 .28 90081122 0 .00 100

.00 46 1,888.14 90110622 -70.71 -70.71 22 2,365 .47 90052404 -70 .71 -70.71 47 1,883.12 90081403 92 .39 -38 .27 23 2,344 .19 90072505 -38.27 -92 .39 48 1,883.10 90111501 -38 .27 92 .39 24 2,334 .74 90071803 38 .27 92.39 49 1,880.10 90030108 -38 .27 92 .39 25 2,334 .74 90062806 92 .39 38.27 50 1,879.76 90083103 -38 .27 -92 .39 The maximum 50 24-hour average acetonitrile concentration values in ug/m^3 

# Rank Concentration yymmddhh X y Rank Concentration yymmddhh X Y 1 394.31 90103124 70 .71 70.71 26 248 .98 90120924 70 .71 70 .71 2 373.79 90072124 70 .71 70.71 27 243.35 90080224 -70.71 -70.71 3 371 .64 90081124 100.00 0.00 28 235 .56 90031124 70 .71 70.71 4 359.36 90010624 92 .39 38.27 29 235 .53 90123124 100 .00 0.00 5 348

.41 90081824 70 .71 70.71 30 235 .03 90112024 -70.71 70.71 6 332.85 90040524 92 .39 38.27 31 233 .27 90081624 0.00 100 .00 7 312.34 90082724 70 .71 70.71 32 228.10 90061024 38.27 -92.39 8 293.75 90062524 92 .39 38.27 33 225 .88 90071724 70.71 70.71 9 292.76 90041524 92 .39 38.27 34 223 .90 90111724 70.71 -70.71 10 290

.99 90090624 70 .71 70.71 35 223 .02 90101224 -38.27 -92.39 11 290

.91 90010724 70 .71 70.71 36 223 .01 90111924 -70.71 70.71 12 288.93 90032024 38 .27 -92.39 37 222 .63 90073024 92.39 38 .27 i~ 273.86 90062124 92 .39 38.27 38 221 .41 90102224 -38.27 -92 .39 14 271 .85 90070424 70 .71 70.71 39 220.76 90041124 70.71 -70 .71 15 265 .65 90040824 70 .71 70.71 40 213 .77 90083124 -70.71 70 .71 16 264.61 90033024 -38 .27 92 .39 41 213 .28 90082424 -92 .39 38 .27 17 259.89 90062724 70 .71 70.71 42 211 .89 90111824 -92.39 38 .27 18 259.21 90020824 -38 .27 92 .39 43 210 .50 90072424 70 .71 -70.71 19 259.05 90021224 0.00 100.00 44 209.50 90021124 70 .71 -70.71 20 258.38 90082824 70.71 70 .71 45 208.46 90081124 200.00 0.00 21 257 .37 90042324 -70.71 70 .71 46 208.27 90010824 38 .27 92 .39 22 256.10 90010824 70 .71 70 .71 47 207.64 90021524 -38 .27 -92 .39 23 253 .65 90062824 70.71 70.71 48 207.04 90022824 -38 .27 -92 .39 24 253 .09 90062724 92 .39 38.27 49 207.03 90060724 -70.71 70.71 25 252 .57 90091724 -38.27 -92 .39 50 205.86 90010624 184 .78 76.54

# p. 64



# ISCST3 Air Modeling Results of Top 1996 Acetonitrile Dischargers The Maximum501-Hour and 24-Hour Acetonitrile Concentrations
Site : HOECHST CELANESE The maximum 50 1-hour average acetonitrile concentration values in ug/mA3 

# Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X y 1 6,942 .11 90022821 70.71 -70.71 26 6,473 .93 90021223 0.00 100 .00 2 6,917.19 90091001 70.71 70.71 27 6,473 .93 90010701 0.00 100 .00 3 6,917.14 90102905 70.71 70.71 28 6,380.91 90072004 38.27 92.39 4 6,883.33 90071902 -70.71 -70.71 29 6,380.88 90053102 38.27 92.39 5 6,883.28 90112019 -70.71 -70.71 30 6,380.86 90120823 92.39 38.27 6 6,846.13 90082723 38.27 92.39 31 6,368 .37 90110320 -92 .39 38.27 7 6,846.08 90072001 38.27 92.39 32 6,368 .37 90042305 -92 .39 38.27 8 6,846.02 90012706 38.27 92.39 33 5,911 .52 90070224 -38 .27 92.39 9 6,612.26 90120703 38.27 92.39 34 5,911 .52 90062601 -38 .27 92.39 10 6,612.26 90111405 38.27 92.39 35 5,785 .72 90111418 38.27 92.39 11 6,590.54 90082522 -92 .39 38.27 36 5,740.84 90020521 38.27 92.39 12 6,581 .97 90080324 -70.71 70.71 37 5,660.54 90082819 70.71 70.71 13 6,581 .96 90121922 -70.71 70.71 38 5,656 .77 90100119 70.71 70.71 14 6,547.04 90090220 70.71 70.71 39 5,629 .55 90011019 38.27 -92.39 15 6,546.94 90051403 70.71 70.71 40 5,629 .55 90022002 38.27 -92.39 16 6,546.92 90010902 70.71 70.71 41 5,629 .50 90080801 -92 .39 38.27 17 6,509.59 90062002 -70.71 70 .71 42 5,547 .11 90053123 70.71 70.71 18 6,509.59 90092702 -70.71 70 .71 43 5,547 .09 90013106 70.71 70.71 19 6,509.58 90121108 -70.71 70 .71 44 5,547 .09 90102904 70.71 70.71 20 6,491 .87 90071906 -38 .27 -92 .39 45 5,543 .51 90062623 -70.71 70.71 21 6,489 .16 90090124 0.00 100.00 46 5,543 .51 90081602 -70.71 70.71 22 6,489 .16 90071524 0.00 100.00 47 5,543 .51 90010906 -70.71 70.71 23 6,489 .15 90100703 0.00 100.00 48 5,435 .45 90081121 -70.71 70.71 24 6,489.15 90010624 0.00 100.00 49 5,342 .80 90090520 92.39 38.27 25 6,473.93 90092421 0.00 100.00 50 5,254 .02 90062204 -92 .39 38.27 The maximum50 24-hour average acetonitrile concentration values in uglmA3 

# Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 912.79 90111424 38 .27 92 .39 26 607.53 90092524 38.27 92 .39 2 789.38 90012824 70 .71 70 .71 27 602 .85 90120724 0.00 100 .00 3 772.86 90030224 70 .71 70 .71 28 602.57 90032624 92.39 38 .27 4 762.99 90030824 -70.71 70.71 29 600 .59 90040124 100 .00 0

.00 5 749.62 90091324 0.00 100.00 30 593.85 90021424 70.71 70 .71 6 727.75 90100224 70 .71 70 .71 31 585.71 90092124 -38-.27 92 .39 7 715.86 90120924 92 .39 38 .27 32 580 .21 90022824 38.27 -92.39 8 711 .70 90071124 70 .71 70 .71 33 566 .57 90122824 -70.71 70 .71 9 680

.15 90061624 -70.71 70 .71 34 565.68 90090124 -38.27 92 .39 10 665.64 90082824 70 .71 70.71 35 559.25 90092924 -38.27 92 .39 11 661 .84 90111224 92 .39 -38 .27 36 558 .72 90010124 92 .39 -38 .27 12 661 .54 90080924 -70.71 70 .71 37 558.19 90102424 0 .00 -100 .00 13 661 .49 90083124 -70.71 70.71 38 557.68 90022824 70 .71 -70.71 14 661 .07 90091124 -70.71 70.71 39 555.91 90022024 38 .27 -92 .39 15 657 .30 90072024 38.27 92.39 40 543.92 90112724 -38 .27 92 .39 16 652 .46 90021224 0 .00 100

.00 41 542 .02 90012624 92 .39 -38 .27 17 648.53 90031124 70.71 70.71 42 541 .43 90013124 70 .71 70 .71 18 626.94 90012224 100 .00 0.00 43 538.79 90011524 70 .71 70 .71 19 626.00 90120624 70.71 70.71 44 537 .16 90070424 70 .71 70 .71 20 623.21 90102924 70.71 70.71 45 535 .48 90101624 -38 .27 92.39 21 616.80 90092024 0 .00 -100.00 46 533 .05 90070924 70 .71 70.71 22 612 .60 90072024 70.71 70.71 47 530.91 90070524 92 .39 38.27 23 608.83 90031024 92 .39 38.27 48 524 .33 90032824 -70.71 70.71 24 608.63 90020824 0 .00 100

.00 49 524 .29 90020324 -38 .27 92.39 25 608.08 90031824 92 .39 -38.27 50 522 .40 90091324 70.71 70.71

# p. 65



# ISCST3 Air Modeling Results of Top 1996 Acetonitrile Dischargers The Maximum

501-Hour and 24-Hour Acetonitrile Concentrations
Site : AMOCO CHEMICAL C0

. CHOCOLATE BAYOU PLANT The maximum 50 1-hour average acetonitrile concentration values in uglmA3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 1,926.67 88072121 70.71 -70.71 26 1,736.05 88041305 92.39 -38 .27 2 1,926.67 88051805 70.71 -70.71 27 1,724.20 88091401 0.00 -100 .00 3 1,905 .60 88051503 92 .39 -38.27 28 1,724 .20 88030420 0.00 -100 .00 4 1,885.95 88102604 -100.00 0.00 29 1,724.20 88120507 0.00 -100 .00 5 1,870.09 88050503 92 .39 -38.27 30 1,640.64 88042623 92 .39 -38 .27 6 1,870.09 88041304 92 .39 -38.27 31 1,640.64 88020622 -38 .27 92 .39 7 1,870.09 88121704 92 .39 -38.27 32 1,593.85 88061906 0.00 -100 .00 8 1,837 .35 88060104 0.00 -100.00 33 1,593.84 88061705 0.00 -100 .00 9 1,835 .13 88082523 92 .39 38.27 34 1,593.83 88100502 0.00 -100 .00 10 1,829 .09 88121223 38 .27 -92.39 35 1,562.39 88082801 38.27 -92.39 11 1,826 .71 88040201 70 .71 -70.71 36 1,562.39 88022006 38.27 -92.39 12 1,826 .71 88121405 70 .71 -70.71 37 1,540.88 88090906 100 .00 0

.00 13 1,817 .00 88051423 70 .71 70.71 38 1,539.52 88092003 70.71 70.71 14 1,806 .63 88040906 70 .71 -70.71 39 1,539.51 88081224 70.71 70.71 15 1,801 .71 88062305 -38 .27 -92.39 40 1,539.51 88102024 70.71 70.71 16 1,801 .70 88122102 -38 .27 -92.39 41 1,510.62 88082921 -92.39 -38.27 17 1,801 .69 88111624 -38 .27 -92.39 42 1,504.78 88022724 70.71 -70.71 18 1,794 .95 88011904 -70.71 -70.71 43 1,488.36 88081624 -70.71 -70.71 19 1,794 .94 88101304 -70.71 -70.71 44 1,488.36 88060604 -70.71 -70.71 20 1,778 .89 88070522 -92 .39 -38.27 45 1,488.36 88082723 -70.71 -70.71 21 1,778 .89 88100922 -92 .39 -38.27 46 1,482.79 88082706 92 .39 38.27 22 1,778 .89 88101524 -92 .39 -38.27 47 1,472 .93 88100424 -92.39 -38.27 23 1,778 .88 88112619 -92 .39 -38.27 48 1,472 .93 88121407 -38.27 -92 .39 24 1,778 .88 88011505 -92 .39 -38.27 49 1,465.29 88120518 38 .27 -92 .39 25 1,767 .44 88091422 38 .27 -92.39 50 1,445.46 88021309 38 .27 92 .39 

# The maximum 50 24-hour average acetonitrile concentration values in ug/mA3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 276.29 88113024 0 .00 -100.00 26 150 .95 88071724 38 .27 92 .39 2 243.07 88121224 38 .27 -92.39 27 149 .51 88020824 -100 .00 0 .00 3 219.40 88112124 0 .00 -100.00 28 149 .50 88051424 70 .71 70 .71 4 199.31 88090424 0 .00 -100.00 29 147 .96 88100624 -92 .39 -38 .27 5 198.47 88092524 0.00 -100.00 30 145.76 88040924 70.71 -70 .71 6 192.31 88012124 92.39 -38.27 31 144.96 88020324 0.00 -100 .00 7 181 .35 88032024 38.27 92.39 32 143.97 88022024 92.39 -38 .27 8 178.95 88092624 -38 .27 -92 .39 33 140.32 88073024 -92.39 -38.27 9 177.42 88041324 92.39 -38 .27 34 138.23 88010224 -38.27 -92.39 10 176

.04 88093024 0.00 -100.00 35 138.15 88110324 -38.27 92.39 11 173.97 88090524 0.00 -100 .00 36 136.19 88010524 -70.71 -70.71 12 172 .40 88060424 0.00 -100.00 37 135.70 88112224 -38.27 -92.39 13 169.22 88060624 -70.71 -70.71 38 135.28 88051824 70.71 -70.71 14 165 .51 88071324 0.00 100 .00 39 135.15 88012324 38 .27 92 .39 15 164 .67 88032524 70 .71 70.71 40 133 .48 88092324 0.00 100.00 16 164 .28 88100324 0.00 -100.00 41 132 .92 88040424 -92 .39 38 .27 17 161 .78 88100224 38 .27 -92.39 42 132 .35 88050424 38 .27 -92 .39 18 160.01 88070124 0.00 100 .00 43 131 .76 88072224 38 .27 -92 .39 19 159.64 88071624 0.00 100 .00 44 131 .41 88070224 38 .27 92 .39 20 159.39 88072724 70 .71 70.71 45 130.75 88122024 -38 .27 92.39 21 158.83 88050924 0.00 100 .00 46 129.97 88103024 -70.71 -70.71 22 157.58 88101724 0.00 100.00 47 129.37 88030324 38.27 -92 .39 23 156

.23 88050824 0.00 100.00 48 128.88 88030524 38.27 92.39 24 155.42 88092224 0.00 100.00 49 128.74 88110824 0.00 100 .00 25 152 .94 88032324 -70.71 70 .71 50 128.73 88121724 70.71 -70.71

# p. 66



# ISCST3 Air Modeling Results of Top 1996 Acetonitrile Dischargers
The Maximum

501-Hour and 24-Hour Acetonitrile Concentrations
Site : LILLY TECH

. CENTER The maximum 50 1-hour average acetonitrile concentration values in uglm^3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 4,470.63 90081103 100.00 0.00 26 2,937 .81 90073003 92 .39 38 .27 2 3,195.85 90042306 -70.71 70 .71 27 2,937 .61 90062502 92 .39 38 .27 3 3,168.93 90080205 -70.71 -70.71 28 2,879 .86 90071902 92 .39 -38 .27 4 3,159.45 90061103 38 .27 -92 .39 29 2,879 .76 90062604 92 .39 -38 .27 5 3,159.43 90032021 38 .27 -92 .39 30 2,721 .40 90082921 92 .39 -38 .27 6 3,159.43 90111304 38 .27 -92 .39 31 2,621 .21 90062707 92 .39 38 .27 7 3,151 .74 90072403 92 .39 38 .27 32 2,618 .10 90030919 70 .71 70 .71 8 3,141 .90 90082524 100.00 0.00 33 2,617 .52 90102406 92.39 38 .27 9 3,141 .84 90081124 100.00 0.00 34 2,569 .96 90092719 -38 .27 92 .39 10 3,128.32 90111721 0.00 -100 .00 35 2,550.64 90090120 100 .00 0.00 11 3,101 .99 90102320 92 .39 -38 .27 36 2,544 .60 90061705 0.00 100.00 12 3,047.91 90091205 -100 .00 0.00 37 2,496 .18 90060704 -70.71 70.71 13 3,044.04 90012303 38 .27 92 .39 38 2,459 .63 90010519 92.39 38 .27 14 3,034.02 90091020 -92 .39 38 .27 39 2,443 .24 90101204 -38.27 -92 .39 15 3,034.00 90082605 -92 .39 38 .27 40 2,424 .21 90072306 70.71 -70.71 16 3,034.00 90082505 -92 .39 38 .27 41 2,405 .42 90030120 38.27 92.39 17 3,030.04 90042305 -70.71 70 .71 42 2,396 .93 90082104 -70.71 70.71 18 2,988 .72 90081324 -38 .27 -92 .39 43 2,396 .89 90041304 -70.71 70.71 19 2,980.55 90082822 100 .00 0.00 44 2,388 .53 90062804 70.71 70.71 20 2,980.55 90081122 0 .00 100.00 45 2,388.34 90010804 70 .71 70.71 21 2,977 .47 90052404 -70.71 -70.71 46 2,376.66 90110622 -70.71 -70.71 22 2,969 .59 90081103 200 .00 0.00 47 2,370.69 90081403 92 .39 -38.27 23 2,950.81 90072505 -38.27 -92 .39 48 2,370.69 90111501 -38 .27 92 .39 24 2,937 .81 90071803 38.27 92.39 49 2,366.00 90083103 -38 .27 -92 .39 25 2,937 .81 90062806 92.39 38.27 50 2,365.96 90102219 -38 .27 -92 .39 

# The maximum 50 24-hour average acetonitrile concentration values in uglm^3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 463 .02 90103124 70.71 70.71 26 280 .60 90080224 -70.71 -70.71 2 448.22 90081124 100 .00 0.00 - 27 275 .47 90061024 38 .27 -92 .39 3 420.75 90010624 92 .39 38.27 28 275.36 90062824 70.71 70 .71 4 418.05 90072124 70 .71 70.71 29 270.55 90101224 -38 .27 -92 .39 5 410

.41 90040524 92 .39 38.27 30 269.44 90062724 70.71 70.71 6 403.97 90081824 70 .71 70.71 31 267 .05 90112024 -70.71 70.71 7 358.13 90010724 70 .71 70.71 32 263.51 90073024 92.39 38.27 8 349.88 90032024 38 .27 -92.39 33 262.33 90031124 70.71 70.71 9 347.12 90082724 70 .71 70.71 34 259.98 90111724 70.71 -70.71 10 345.11 90062524 92 .39 38.27 35 259.37 90041124 70.71 -70.71 11 341 .99 90041524 92 .39 38 .27 36 258 .32 90111924 -70.71 70.71 12 325.73 90090624 70 .71 70 .71 37 256 .04 90022024 -38 .27 -92.39 13 321 .11 90020824 -38 .27 92 .39 38 255.41 90102224 -38 .27 -92 .39 14 320.51 90042324 -70.71 70 .71 39 252.41 90082424 -92 .39 38 .27 15 309.17 90091724 -38 .27 -92 .39 40 250 .49 90010824 38 .27 92 .39 16 308.93 90040824 70.71 70.71 41 244 .30 90111824 -92 .39 38 .27 17 306.68 90010824 70.71 70.71 42 243 .33 90081124 200.00 0.00 18 306.10 90062724 92.39 38.27 43 242 .12 90072324 70 .71 -70.71 19 302 .57 90070424 70.71 70.71 44 241 .50 90102524 38.27 -92 .39 20 302 .47 90062124 92 .39 38.27 45, 240.62 90102424 92.39 38.27 21 298.63 90082824 70 .71 70.71 46 239.61 90060724 -70.71 70.71 22 287.30 90021224 0.00 100 .00 47 235.40 90083124 -70.71 70.71 23 285.86 90120924 70 .71 70.71 48 233.28 90120824 92.39 38.27 24 282.35 90123124 100.00 0 .00 49 232.90 90082524 -92.39 38.27 25 281 .18 90033024 -38 .27 92 .39 50 232.68 90021124 70.71 -70.71

# p. 67



# ISCST3 Air Modeling Results of Top 1996 Acetonitrile Dischargers The Maximum

501-Hour and 24-Hour Acetonitrile Concentrations
Site: LYONDELL PETROCHEMICAL C0

. CHANNELVIEW COMP The maximum 50 1-hour average acetonitrile concentration values in uglmA3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 4,296.81 88072121 70 .71 -70 .71 26 3,871 .72 88041305 92 .39 -38 .27 2 4,296.79 88051805 70 .71 -70 .71 27 3,845 .29 88091401 0.00 -100 .00 3 4,249.81 88051503 92 .39 -38.27 28 3,845 .26 88030420 0.00 -100 .00 4 4,206.04 88102604 -100 .00 0 .00 29 3,845 .25 88120507 0.00 -100 .00 5 4,170.60 88050503 92 .39 -38.27 30 3,658 .90 88042623 92 .39 -38 .27 6 4,170.60 88041304 92 .39 -38.27 31 3,658 .89 88020622 -38 .27 92 .39 7 4,170.60 88121704 92 .39 -38.27 32 3,554 .68 88061906 0.00 -100 .00 8 4,097.67 88060104 0.00 -100.00 33 3,554 .63 88061705 0.00 -100 .00 9 4,092.73 88082523 92 .39 38 .27 34 3,554 .57 88100502 0.00 -100 .00 10 4,079.17 88121223 38 .27 -92 .39 35 3,484 .38 88082801 38 .27 -92 .39 11 4,073.87 88040201 70 .71 -70 .71 36 3,484 .37 88022006 38 .27 -92 .39 12 4,073.86 88121405 70 .71 -70 .71 37 3,436 .41 88090906 100 .00 0.00 13 4,052.30 88051423 70 .71 70 .71 38 3,433 .48 88092003 70.71 70.71 14 4,029.10 88040906 70 .71 -70 .71 39 3,433 .47 88081224 70 .71 70.71 15 4,018.27 88062305 -38 .27 -92 .39 40 3,433 .47 88102024 70.71 70.71 16 4,018.17 88122102 -38 .27 -92 .39 41 3,369 .07 88082921 -92 .39 -38 .27 17 4,018.13 88111624 -38 .27 -92 .39 42 3,355 .97 88022724 70.71 -70.71 18 4,003.11 88011904 -70.71 -70 .71 43 3,319 .39 88081624 -70.71 -70.71 19 4,003.07 88101304 -70.71 -70 .71 44 3,319 .38 88060604 -70.71 -70.71 20 3,967.30 88070522 -92 .39 -38 .27 45 3,319 .38 88082723 -70.71 -70.71 21 3,967.30 88100922 -92 .39 -38 .27 46 3,307 .01 88082706 92.39 38.27 22 3,967.26 88101524 -92 .39 -38 .27 47 3,284 .90 88100424 -92.39 -38.27 23 3,967 .26 88112619 -92.39 -38 .27 48 3,284 .89 88121407 -38.27 -92.39 24 3,967 .22 88011505 -92.39 -38 .27 49 3,272 .11 88120518 38.27 -92.39 25 3,941 .77 88091422 38.27 -92 .39 50 3,227 .49 88021309 38.27 92 .39 The maximum 50 24-hour average acetonitrile concentration values in uglmA3 

# Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 617 .41 88113024 0.00 -100 .00 26 338 .11 88071724 38 .27 92 .39 2 546.56 88121224 38.27 -92 .39 27 337.26 88020824 -100.00 0.00 3 492 .32 88112124 0 .00 -100 .00 28 333 .41 88051424 70.71 70 .71 4 446.58 88090424 0 .00 -100 .00 29 331 .46 88100624 -92 .39 -38 .27 5 444.72 88092524 0 .00 -100 .00 30 327 .04 88020324 0.00 -100 .00 6 429.38 88012124 92 .39 -38 .27 31 326.73 88040924 70 .71 -70.71 7 405.48 88032024 38 .27 92.39 32 321 .91 88022024 92 .39 -38 .27 8 399.80 88092624 -38.27 -92 .39 33 314 .94 88073024 -92 .39 -38 .27 9 396.07 88093024 0.00 -100.00 34 311 .98 88010224 -38 .27 -92 .39 10 395.86 88041324 92 .39 -38.27 35 308.31 88110324 -38 .27 92.39 11 390

.29 88090524 0.00 -100.00 36 306.05 88112224 -38.27 -92.39 12 389.28 88060424 0.00 -100.00 37 305 .18 88010524 -70.71 -70.71 13 378.84 88060624 -70.71 -70.71 38 303 .58 88012324 38.27 92 .39 14 371 .66 88071324 0.00 100 .00 39 302 .45 88051824 70.71 -70.71 15 371 .17 88032524 70 .71 70.71 40 300.03 88040424 -92.39 38 .27 16 368.90 88100324 0.00 -100.00 41 299.58 88092324 0 .00 100.00 17 362 .86 88100224 38.27 -92 .39 42 298.43 88050424 38.27 -92 .39 18 358 .44 88071624 0.00 100.00 43 296 .64 88072224 38.27 -92 .39 19 357 .79 88050924 0.00 100.00 44 295.00 88070224 38 .27 92 .39 20 357 .78 88070124 0.00 100.00 45 294.36 88122024 -38.27 92 .39 21 356.81 88072724 70.71 70 .71 46 293.41 88103024 -70 .71 -70.71 22 353 .83 88101724 0 .00 100.00 47 292.49 88030324 38 .27 -92 .39 23 351 .35 88050824 0.00 100 .00 48 289 .63 88110824 0.00 100 .00 24 349.56 88092224 0.00 100 .00 49 288 .68 88121724 70 .71 -70.71 25 344.61 88032324 -70 .71 70.71 50 287.57 88021524 38 .27 -92 .39

# p. 68



# ISCST3 Air Modeling Results of Top 1996 Acetonitrile Dischargers The Maximum

501-Hour and 24-Hour Acetonitrile Concentrations
Site : HOECHST CELANESE CORP

. CELRIVER PLANT The maximum 50 1-hour average acetonitrile concentration values in uglmA3 

# Rank Concentration yymmddhh X Y 1 574.82 2 572 .20 3 567 .09 4 563 .42 5 561 .94 6 555.38 7 555.37 8 549.28 9 540.54 10 540.08 11 514.88 12 513 .70 13 504.43 14 501 .02 15 488.46 16 488.46 17 488.30 18 485.27 19 485.07 20 483 .60 21 483 .02 22 482 .17 23 477 .03 24 476.24 25 474.96 90020517 90062208 90092718 90072518 90022618 90082317 90010610 90022616 90052708 90122515 90052418 90092809 90080618 90060806 90042216 90060517 90082324 90012501 90041523 38 .27 92.39

70 .71 70.71 0.00 100

.00 0.00 -100.00 92 .39 -38.27 0.00 100

.00 0.00 100

.00 0.00 100

.00 92 .39 38.27 38 .27 -92.39 38 .27 92 .39 92 .39 -38.27 -92 .39 -38.27 141 .42 141 .42 -70.71 -70

.71 -70.71 -70

.71 141 .42 141 .42 0.00 -200.00 -141 .42 141 .42 90121724 -76 .54 90082407 -184 .78 90091308 70 .71 90100418 92 .39 90081508 0.00 90101119 -141 .42 184 .78 -76.54 -70 .71 38 .27 200.00 141 .42 

# Rank Concentration yymmddhh X Y 26 474.45 90082614 38.27 -92.39 27 473.84 90010708 -141 .42 -141 .42 28 473.82 90122823 -141 .42 -141 .42 29 471 .39 90091310 141 .42 -141 .42 30 471 .39 90092019 141 .42 -141 .42 31 467.73 90082101 -282.84 282.84 32 467.73 90100619 -282.84 282.84 33 465.27 90010618 -141 .42 -141 .42 34 463.16 90012211 92 .39 -38.27 35 460

.89 90010707 76 .54 -184.78 36 460

.70 90110607 76 .54 -184.78 37 459

.94 90010908 76 .54 184.78 38 458

.07 90122906 -76.54 -184.78 39 457.21 90100519 153 .07 -369.55 40 456.81 90050108 184 .78 -76.54 41 456.44 90082903 153 .07 369 .55 42 456.21 90101318 76 .54 -184.78 43 455 .70 90082101 -212 .13 212 .13 44 455 .70 90100619 -212 .13 212 .13 45 455 .32 90091322 -369.55 -153.07 46 452 .68 90061007 70 .71 70.71 47 448.40 90100519 114 .81 -277 .16 48 448.12 90082903 114 .81 277 .16 49 446.06 90091322 -277 .16 -114 .81 50 444 .26 90081619 100.00 0.00 The maximum 50 24-hour average acetonitrile concentration values in uglmA3 Rank1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Concentration yymmddhh

96.19 90092024 94.21 90122524 88.52 90090224 88.17 90090224 85.92 90122524 85.91 90122524 84.54 90102424 81 .91 90101324 80.06 90091324 78 .92 90072524 78 .69 90082724 78 .40 90110724 77 .28 90110724 77 .10 90090624 76 .90 90120724 76 .62 90102424 75 .62 90110124 75 .40 90010724 75 .28 90073024 74 .36 90072524 74 .18 90090224 73 .26 90122524 71 .49 90101324 71 .43 90091324 71 .16 90080824 X Y 70 .71 -70.71 114.81 -277 .16 38.27 -92 .39 76.54 -184 .78 76.54 -184 .78 153.07 -369 .55 0.00 -200 .00 0.00 -200 .00 70.71 -70.71 

# 0.00 -200 .00 38.27 -92 .39 0.00 -300 .00 0.00 -400 .00 70.71 -70 .71 -76.54 -184 .78 0.00 -100 .00 38 .27 -92.39 -184 .78 -76.54 92 .39 -38.27 0.00 -100.00 114 .81 -277 .16 191 .34 -461 .94 0.00 -100.00 141 .42 -141 .42 -184 .78 -76 .54 

# Rank Concentration yymmddhh X Y 26 69 .37 90072024 184 .78 -76 .54 27 68 .94 90041424 -76 .54 184 .78 28 68 .43 90110724 0.00 -500 .00 29 67 .88 90071424 -76 .54 184.78 30 67 .75 90090124 0.00 -100.00 31 67 .25 90101324 76.54 -184.78 32 65.86 90052724 70.71 70.71 33 65.70 90122524 38.27 -92.39 34 64.89 90101524 38.27 =92.39 35 64.14 90010724 -92.39 -38.27 36 63.82 90021524 0 .00 200

.00 37 63.74 90092024 141 .42 -141 .42 38 62.40 90120924 38.27 -92.39 39 62.01 90102124 0 .00 -200.00 40 61 .60 90072524 0 .00 -300.00 41 61 .52 90052724 141 .42 141 .42 42 61 .39 90122524 229 .61 -554 .33 43 61 .34 90120724 -38.27 -92 .39 44 61 .31 90102424 0.00 -300 .00 45 61 .04 90071624 -92 .39 38 .27 46 60 .38 90122724 -141 .42 -141 .42 47 60 .30 90041424 -38 .27 92 .39 48 59 .64 90111324 38.27 -92 .39 49 59 .28 90110724 0.00 -200 .00 50 59 .04 90021824 -76 .54 -184 .78

# p. 69



# ISCST3 Air Modeling Results of Top 1996 Acetonitrile Dischargers The Maximum501-Hour and 24-Hour Acetonitrile Concentrations
Site : DIXIE CHEMICAL C0

. INC The maximum 50 1-hour average acetonitrile concentration values in uglmA3 

# Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 582 .24 88051610 0.00 100 .00 26 517 .27 88040906 70.71 -70.71 2 565.81 88101609 -70.71 70.71 27 517 .11 88062305 -38.27 -92.39 3 562 .63 88040916 38 .27 -92 .39 28 516.44 88122102 -38.27 -92.39 4 561 .85 88082307 70 .71 70.71 29 516.21 88111624 -38.27 -92.39 5 551 .61 88072121 70 .71 -70 .71 30 515 .23 88100124 114 .81 -277 .16 6 551 .44 88051805 70 .71 -70 .71 31 514 .55 88011904 -70.71 -70.71 7 547 .66 88120216 -70.71 70 .71 32 514 .27 88101304 -70.71 -70.71 8 545.51 88051503 92 .39 -38 .27 33 513 .83 88082706 277 .16 114.81 9 545.40 88120316 -70.71 -70 .71 34 509.88 88070522 -92 .39 -38.27 10 540.30 88102604 -100 .00 0.00 35 509.88 88100922 -92 .39 -38.27 11 539.91 88102618 -141 .42 141 .42 36 509.61 88101524 -92 .39 -38.27 12 535.18 88050503 92 .39 -38 .27 37 509.57 88112619 -92 .39 -38.27 13 535.16 88041304 92 .39 -38 .27 38 509.32 88011505 -92 .39 -38 .27 14 535.15 88121704 92 .39 -38 .27 39 508.76 88062107 -70.71 -70.71 15 526.56 88060104 0.00 -100 .00 40 507 .88 88092208 0.00 100.00 16 525.97 88082523 92 .39 38 .27 41 506 .60 88091422 38 .27 -92 .39 17 523 .42 88121223 38 .27 -92 .39 42 503.92 88061422 -212 .13 212 .13 18 522 .73 88040201 70 .71 -70.71 43 503.43 88082921 -277 .16 -114 .81 19 522.71 88121405 70 .71 -70.71 44 500 .59 88061103 114 .81 -277 .16 20 522 .67 88121006 0.00 -100 .00 45 499.90 88092206 212.13 -212 .13 21 522 .29 88062305 -114 .81 -277 .16 46 499.77 88050305 184.78 -76 .54 22 521 .20 88022905 -38 .27 92 .39 47 497.91 88062305 -76 .54 -184 .78 23 521 .20 88122006 -38 .27 92 .39 48 497.68 88061906 0.00 -300 .00 24 521 .16 88123102 -70.71 70 .71 49 497.12 88041305 92.39 -38 .27 25 521 .02 88051423 70.71 70 .71 50 494.06 88102605 141 .42 -141 .42 The maximum 50 24-hour average acetonitrile concentration values in ug/mA3 

# Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 115.22 88121224 38.27 -92 .39 26 72 .70 88100324 0.00 -100.00 2 98 .23 88060424 0.00 -100 .00 27 72 .03 88050624 -70.71 70.71 3 93 .56 88112124 0.00 -100 .00 28 71 .95 88022824 92.39 38.27 4 91 .73 88113024 0 .00 -100 .00 29 71 .55 88120624 -92.39 38.27 5 87 .12 88032524 70.71 70.71 30 71 .13 88050424 38.27 -92.39 6 86 .88 88121224 76.54 -184.78 31 70 .97 88061024 -70 .71 -70

.71 7 85 .77 88060424 0 .00 -200.00 32 70 .58 88021024 -100.00 0.00 8 85 .74 88093024 0 .00 -100.00 33 70 .55 88080124 -70 .71 70 .71 9 81 .78 88050924 0.00 100 .00 34 70 .22 88071624 0.00 100.00 10 81 .73 88020824 -100.00 0 .00 35 70 .19 88121024 0.00 -100 .00 11 81 .26 88123124 38 .27 -92.39 36 69 .65 88112124 0.00 -200 .00 12 79 .81 88020324 0.00 -100.00 37 69 .61 88113024 0.00 -200 .00 13 79 .61 88032324 -70.71 70.71 38 69.55 88 .~01724 0.00 100.00 14 78 .34 88071124 0.00 100.00 39 69.43 88060924 38.27 92 .39 15 78 .26 88090424 0.00 -100 .00 40 68.69 88091624 -92.39 -38 .27 16 78.07 88092524 0.00 -100 .00 41 68.51 88060524 -38.27 -92.39 17 77 .53 88030324 38.27 -92 .39 42 68.50 88020724 -100.00 0.00 18 77 .30 88010224 -38 .27 -92 .39 43 68.04 88062624 -38.27 92 .39 19 74.79 88040424 -92.39 38 .27 44 67 .39 88100224 38.27 -92 .39 20 74.48 88092224 0.00 100 .00 45 66.90 88071324 0 .00 200.00 21 74 .46 88050824 0.00 100 .00 ' 46 66.38 88030324 76.54 -184.78 22 73 .56 88112224 -38.27 -92.39 47 66.30 88111524 0 .00 100.00 23 73 .42 88103024 -70.71 -70.71 48 66.14 88072224 38 .27 -92 .39 24 73 .29 88071324 0 .00 100

.00 49 65.93 88021524 38 .27 -92 .39 25 73 .19 88090524 0 .00 -100.00 50 65 .69 88122024 -38 .27 92 .39

# p. 70



# ISCST3 Air Modeling Results of Top 1996 Acetonitrile Dischargers The Maximum501-Hour and 24-Hour Acetonitrile Concentrations
Site : GOODYEAR TIRE 8 RUBBER CO The maximum 50 1-hour average acetonitrile concentration values in ug/mA3 

# Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 2,500.08 90100602 -70.71 70 .71 26 2,331 .46 90083105 0.00 100 .00 2 2,491 .07 90061505 70.71 70 .71 27 2,331 .46 90031824 0.00 100 .00 3 2,491 .07 90070323 70 .71 70 .71 28 2,297 .94 90081722 38 .27 92 .39 4 2,491 .07 90082022 70.71 70 .71 29 2,297 .93 90102820 92 .39 38 .27 5 2,478.88 90062804 -70.71 -70.71 30 2,297 .93 90031805 92 .39 38 .27 6 2,478.88 90081504 -70.71 -70.71 31 2,293 .44 90121902 38 .27 -92 .39 7 2,467.72 90120523 -92 .39 -38 .27 32 2,252 .73 90061804 92 .39 -38 .27 8 2,465.47 90080223 38.27 92 .39 33 2,237 .35 90121823 0.00 -100.00 9 2,465.47 90081401 38.27 92 .39 34 2,128 .93 90111223 92.39 -38 .27 10 2,465 .47 90091506 38.27 92 .39 35 2,128.93 90111224 92.39 -38 .27 11 2,465 .46 90013022 38.27 92 .39 36 2,067.46 90062004 92.39 38 .27 12 2,457 .76 90042304 0.00 100.00 37 2,067 .46 90081023 92.39 38 .27 13 2,426 .66 90091805 92.39 -38 .27 38 2,067.45 90021119 92.39 38 .27 14 2,384 .16 90111424 -100.00 0.00 39 1,999.46 90081302 0.00 100.00 15 2,373 .46 90040402 38.27 -92 .39 40 1,997.68 90082901 70.71 70 .71 16 2,373 .46 90110601 38.27 -92 .39 41 1,996.39 90061805 70.71 -70.71 17 2,370.38 90072922 70.71 -70.71 42 1,990.35 90031804 100 .00 0.00 18 2,370.37 90102724 70.71 -70.71 43 1,960.18 90091901 -38.27 -92 .39 19 2,357 .75 90091507 70.71 70 .71 44 1,956.23 90072920 70.71 -70.71 20 2,357 .74 90021122 70.71 70.71 45 1,931 .29 90111404 -70.71 -70.71 21 2,344 .31 90071903 70.71 -70.71 46 1,924.06 90070123 38.27 92 .39 22 2,337 .91 90081706 -92.39 -38 .27 47 1,924.06 90082123 92.39 38 .27 23 2,337 .90 90121004 -92.39 -38.27 48 1,911 .30 90111501 -92.39 -38 .27 24 2,336 .96 90040201 100 .00 0

.00 49 1,911 .30 90120503 -92.39 -38 .27 25 2,331 .47 90061802 100.00 0 .00 50 1,892 .12 90062504 38.27 -92 .39 The maximum 50 24-hour average acetonitrile concentration values in ug/mA3 

# Rank Concentration yymmddhh X Y 1 359.62 90121224 0.00 100 .00 2 345.39 90042224 0.00 100 .00 3 344.30 90102424 38 .27 -92 .39 4 341 .52 90031824 0.00 100.00 5 312.89 90061424 0.00 100.00~ 6 297.12 90100724 -38 .27 92 .39 7 293.72 90072324 38 .27 92 .39 8 279.02 90012224 0.00 100.00 9 271 .46 90120824 38 .27 -92 .39 10 269.54 90060524 0.00 100.00 11 269.05 90072924 70.71 -70.71 12 262 .90 90072724 70.71 -70.71 13 260.44 90080224 38.27 92.39 14 256.12 90120524 -92.39 -38 .27 15 254.88 90070724 0.00 100 .00 16 251 .29 90012024 0.00 -100.00 17 249.02 90100624 -70 .71 70.71 18 246.41 90072524 0.00 100 .00 19 244.52 90072424 0.00 100 .00 20 238.50 90121124 -92 .39 38.27 21 238.25 90072124 0.00 100 .00 22 237.58 90092124 38 .27 92 .39 23 237.12 90111224 92 .39 -38.27 24 236

.00 90081824 0.00 100.00 25 235.26 90120724 70 .71 -70 .71 

# Rank Concentration yymmddhh X Y

26 231 .70 90091524 70 .71 70.71 27 227 .43 90082024 70 .71 70.71 28 226.75 90012624 38 .27 92 .39 29 224.62 90121124 -70.71 70 .71 30 222.12 90042324 0.00 100.00 31 221 .61 90091524 38.27 92 .39 32 218.96 90101524 -70.71 70 .71 33 218.24 90102824 0.00 -100 .00 34 215.51 90080724 -38 .27 -92 .39 35 215.03 90061324 0.00 100.00 36 213.45 90122524 -92.39 -38 .27 37 208.63 90102024 -92.39 38 .27 38 208.10 90081324 0.00 100.00 39 207.91 90121324 0 .00 100

.00 40 204.74 90060324 0 .00 100

.00 41 204.49 90012124 0 .00 -100.00 42 203.83 90081524 38 .27 92 .39 43 201 .65 90060624 0.00 100.00 44 200.71 90071024 -38 .27 92 .39 45 197 .81 90081024 92 .39 38 .27 46 197.36 90041724 0.00 100.00 47 197.35 90031824 0.00 200.00 48 196.11 90122224 38 .27 -92 .39 49 192.53 90081924 38 .27 92 .39 50 191 .78 90112524 -38 .27 92 .39 

# i

# p. 71



# ISCST3 Air Modeling Results of Top 1996 Acetonitrile Dischargers The Maximum501-Hour and 24-Hour Acetonitrile Concentrations
Site : TIPPECANOE LABS The maximum 50 1-hour average acetonitrile concentration values in uglm^3 Rank Concentration yymmddhh X Y Rank Concentration yymmddhh X Y 1 5,090.96 90081103 100.00 0.00 26 3,345 .46 90073003 92.39 38 .27 2 3,639.30 90042306 -70.71 70 .71 27 3,345 .23 90062502 92.39 38 .27 3 3,608.64 90080205 -70.71 -70.71 28 3,279 .46 90071902 92.39 -38 .27 4 3,597.84 90061103 38 .27 -92 .39 29 3,279 .34 90062604 92.39 -38 .27 5 3,597.82 90032021 38 .27 -92 .39 30 3,099 .02 90082921 92.39 -38 .27 6 3,597.82 90111304 38 .27 -92 .39 31 2,985 .21 90062707 92.39 38.27 7 3,589.06 90072403 92.39 38 .27 32 2,981 .69 90030919 70.71 70.71 8 3,577.86 90082524 100 .00 0.00 33 2,980.94 90102406 92.39 38.27 9 3,577.80 90081124 100 .00 0.00 34 2,926 .83 90092719 -38.27 92.39 10 3,562 .40 90111721 0 .00 -100 .00 35 2,904 .79 90090120 100 .00 0

.00 11 3,532 .41 90102320 92.39 -38 .27 36 2,897 .69 90061705 0.00 100 .00 12 3,470.83 90091205 -100 .00 0.00 37 2,842 .54 90060704 -70.71 70.71 13 3,466.42 90012303 38.27 92 .39 38 2,800.93 90010519 92 .39 38.27 14 3,455 .01 90091020 -92 .39 38 .27 39 2,782 .25 90101204 -38.27 -92.39 15 3,454 .99 90082605 -92 .39 38 .27 40 2,760.80 90072306 70.71 -70.71 16 3,454 .98 90082505 -92 .39 38 .27 41 2,739 .35 90030120 38.27 92 .39 17 3,450.47 90042305 -70.71 70 .71 42 2,729 .52 90082104 -70.71 70.71 18 3,403 .43 90081324 -38 .27 -92 .39 43 2,729 .47 90041304 -70.71 70.71 19 3,394 .13 90082822 100 .00 0.00 44 2,719 .95 90062804 70 .71 70.71 20 3,394 .12 90081122 0 .00 100

.00 45 2,719 .74 90010804 70 .71 70 .71 21 3,390.61 90052404 -70.71 -70.71 46 2,706 .44 90110622 -70.71 -70.71 22 3,382 .29 90081103 200 .00 0.00 47 2,699 .64 90081403 92 .39 -38 .27 23 3,360.25 90072505 -38.27 -92 .39 48 2,699 .64 90111501 -38 .27 92 .39 24 3,345 .46 90071803 38.27 92.39 49 2,694.30 90083103 -38 .27 -92 .39 25 3,345 .46 90062806 92.39 38.27 50 2,694.26 90102219 -38 .27 -92 .39 The maximum 50 24-hour average acetonitrile concentration values in uglm^3 

# Rank Concentration yymmddhh X y Rank Concentration yymmddhh X y 1 527 .40 90103124 70.71 70.71 26 319 .64 90080224 -70.71 -70.71 2 510.50 90081124 100 .00 0.00 27 313 .76 90062824 70.71 70 .71 3 479.26 90010624 92 .39 38.27 28 313 .74 90061024 38.27 -92 .39 4 476.28 90072124 70 .71 70.71 29 308.14 90101224 -38.27 -92 .39 5 467.39 90040524 92 .39 38.27 30 307 .08 90062724 70.71 70.71 6 460

.17 90081824 70 .71 70.71 31 304 .23 90112024 -70.71 70.71 7 407.86 90010724 70 .71 70.71 32 300.14 90073024 92.39 38.27 8 398.48 90032024 38 .27 -92.39 33 298.88 90031124 70.71 70.71 9 395.48 90082724 70 .71 70.71 34 296.15 90111724 70.71 -70.71 10 393.10 90062524 92 .39 38.27 35 295 .44 90041124 70.71 -70.71 11 389.56 90041524 92 .39 38.27 36 294 .25 90111924 -70.71 70.71 12 371 .09 90090624 70 .71 70.71 37 291 .56 90022024 -38.27 -92.39 13 365.69 900,20824 -38 .27 92 .39 38 290 .94 90102224 -38.27 -92.39 14 365 .00 90042324 -70.71 70 .71 39 287.50 90082424 -92 .39 38 .27 15 352.11 90091724 -38 .27 -92 .39 40 285.29 90010824 38 .27 92 .39 16 351 .90 90040824 70.71 70 .71 41 278.29 90111824 -92 .39 38 .27 17 349.30 90010824 70.71 70.71 42 277.18 90081124 200.00 0.00 18 348.63 90062724 92.39 38.27 43 275.76 90072324 70 .71 -70.71 19 344.72 90070424 70.71 70.71 44 275.05 90102524 38 .27 -92 .39 20 344.61 90062124 92.39 38.27 45 274.05 90102424 92 .39 38 .27 21 340.18 90082824 70.71 70.71 46 272 .94 90060724 -70.71 70 .71 22 327 .33 90021224 0 .00 100

.00 47 268.20 90083124 -70.71 70.71 23 325.64 90120924 70 .71 70.71 48 265 .73 90120824 92.39 38.27 24 321 .58 90123124 100.00 0 .00 49 265 .22 90082524 -92.39 38.27 25 320

.42 90033024 -38 .27 92.39 50 265 .10 90021124 70.71 -70.71

# APPENDIX H

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