# Patent

## Title
Moulded article with improved stress whitening

## Abstract

The present invention relates to a molded article comprising a polypropylene composition, wherein the polypropylene composition comprises comonomer units derived from ethylene in an amount of from 0.5 wt % to 35 wt %, and from at least one C5-12 alpha-olefin in an amount of from 1.0 mol % to 3.0 mol %, wherein the polypropylene composition has an amount of xylene solubles XS of from 20 wt % to 39 wt %, and the xylene solubles have an amount of ethylene-derived comonomer units of from 4.0 wt % to 70 wt %.

## Background
CROSS REFERENCE TO RELATED APPLICATIONS
This application is a National Stage of International Application No. PCT/EP2013/059557, filed May 8, 2013. This application claims priority to European Patent Application No. 12168523.4 filed on May 18, 2012. The disclosure of the above applications are incorporated herein by reference.
The present invention relates to a moulded article with improved stress whitening properties.
Polypropylene is frequently used for preparing moulded articles. However, it still remains a challenge to design moulded articles with reduced haze and increased softness and toughness.
Another problem that may arise with moulded articles is stress whitening. The stress whitening effect occurs under tensile or impact loading and deteriorates the aesthetic qualities of the moulded article.
It is an object of the present invention to provide a moulded article which comprises polypropylene and results in low haze, increased softness and toughness, while suppressing stress whitening as much as possible.
According to a first aspect of the present invention, the object is solved by providing a moulded article comprising a polypropylene composition, wherein said polypropylene composition comprises comonomer units derived from ethylene in an amount of from 0.5 wt % to 35 wt %, and from at least one C5-12 alpha-olefin in an amount of from 1.0 mol % to 3.0 mol %, wherein the polypropylene composition has an amount of xylene solubles XS of from 20 wt % to 39 wt %, and the xylene solubles have an amount of ethylene-derived comonomer units of from 4.0 wt % to 70 wt %.
Preferably, the at least one C5-12 alpha-olefin is selected from 1-hexene, 1-octene, or any mixture thereof.
As indicated above, the polypropylene composition of the moulded article comprises comonomer units derived from ethylene in an amount of from 0.5 wt % to 35 wt %.
In a preferred embodiment, the amount of the comonomer units derived from ethylene in the polypropylene composition is from 0.8 wt % to 25 wt %, more preferably from 1.0 wt % to 15 wt %, even more preferably from 1.0 wt % to 10 wt %, or from 1.0 wt % to 6.0 wt %.
As indicated above, the polypropylene composition of the moulded article comprises comonomer units derived from at least one C5-12 alpha-olefin in an amount of from 1.0 mol % to 3.0 mol %.
In a preferred embodiment, the amount of the comonomer units derived from the at least one C5-12 alpha-olefin, more preferably from 1-hexene or 1-octene, in the polypropylene composition is from 1.0 mol % to 2.5 mol %.
If the C5-12 alpha-olefin is 1-hexene and its amount is indicated in wt %, the amount of 1-hexene-derived comonomer units in the propylene polymer composition is preferably from 2.0 wt % to 6.0 wt %, more preferably from 2.5 wt % to 5.0 wt %.
If the C5-12 alpha-olefin is 1-octene and its amount is indicated in wt %, the amount of 1-octene-derived comonomer units in the propylene polymer composition is preferably from 2.5 wt % to 7.5 wt %, more preferably from 3.0 wt % to 6.5 wt %.
As will be discussed below, the polypropylene composition of the moulded article may optionally contain one or more additives. Preferably, the amounts of comonomer units derived from ethylene and/or at least one C5-12 alpha-olefin in the polypropylene composition are based on the total amount of propylene polymer(s) being present in the composition. As will also be discussed in further detail below, the polypropylene composition may contain just one propylene polymer fraction (i.e. prepared in a single step polymerization process) or may alternatively contain a mixture of two or more (e.g. three) propylene polymer fractions which are preferably prepared in a sequence of at least two (e.g. three) polymerization reactors (i.e. so-called reactor-blending). If there are two or more propylene polymer fractions, it is the total weight of these fractions on which the amounts of comonomer units derived from ethylene and/or at least one C5-12 alpha-olefin in the polypropylene composition are based.
In a preferred embodiment, the polypropylene composition of the moulded article does not contain any butene-derived (such as 1-butene-derived) comonomer units.
In a preferred embodiment, the polypropylene composition of the moulded article is a terpolymer, wherein the C5-12 alpha-olefin is preferably either 1-hexene or 1-octene. Thus, the polypropylene composition is preferably either a terpolymer composition containing ethylene- and 1-hexene-derived comonomer units or alternatively a terpolymer composition containing ethylene- and 1-octene-derived comonomer units.
As indicated above, the polypropylene composition of the moulded article has an amount of xylene solubles XS of from 20 wt % to 39 wt %.
The amount of xylene solubles XS (sometimes also referred to as xylene cold solubles XCS) is a parameter frequently used to determine the amount of those components within a polymer composition which are mainly amorphous and/or elastomeric or of low crystallinity. The measuring method is described in further detail below under the headline “Measuring Methods”. As a first approximation, the amount of the xylene solubles XS corresponds to the amount of rubber and those polymer chains of the matrix with low molecular weight and low stereoregularity.
Preferably, the amount of xylene solubles XS of the polypropylene composition is from 20 wt % to 37 wt %. In a preferred embodiment, the amount of xylene solubles XS of the polypropylene composition can be from 20 wt % to 30 wt %. Alternatively, it can also be preferred that the amount of xylene solubles XS of the polypropylene composition is from 30 wt % to 39 wt %, more preferably 30 wt % to 37 wt %.
Preferably, the amount of xylene solubles of the polypropylene composition is based on the total amount of propylene polymer(s) being present in the composition. The polypropylene composition may contain just one propylene polymer fraction (i.e. prepared in a single step polymerization process) or may alternatively contain a mixture of two or more (e.g. three) propylene polymer fractions which are preferably prepared in a sequence of at least two (e.g. three) polymerization reactors (i.e. so-called reactor-blending). If there are two or more propylene polymer fractions, it is the total weight of these fractions on which the amount of xylene solubles of the polypropylene composition is based.
As indicated above, the xylene solubles of the polypropylene composition of the moulded article have an amount of ethylene-derived comonomer units of from 4.0 wt % to 70 wt %.
In a preferred embodiment, the amount of the ethylene-derived comonomer units in the xylene solubles is from 4.0 wt % to 50 wt %, more preferably from 5.0 wt % to 30 wt %, even more preferably from 6.0 wt % to 20 wt %, or from 6.0 to 15 wt %.
In the present invention, it is preferred that the majority of the ethylene-derived comonomer units of the polypropylene composition are present in the elastomeric parts or domains of the composition.
In a preferred embodiment, the polypropylene composition satisfies the following relation:

[C2(XS)×XS/100]/C2(total)≧0.9

wherein

C2(XS) is the amount in wt % of the ethylene-derived comonomer units in the xylene solubles,

XS is the amount in wt % of xylene solubles of the polypropylene composition,

C2(total) is the amount in wt % of the ethylene-derived comonomer units in the polypropylene composition.

In a preferred embodiment, [C2(XS)×XS/100]/C2(total)≧0.95; even more preferably 1.0≧[C2(XS)×XS/100]/C2(total)≧0.95.
Preferably, the xylene solubles contain an amount of comonomer units which are derived from the least one C5-12 alpha-olefin such as 1-hexene and/or 1-octene of from 0.01 mol % to 2.0 mol %, more preferably from 0.05 mol % to 1.0 mol %.
If the C5-12 alpha-olefin is 1-hexene and its amount is indicated in wt %, the amount of 1-hexene-derived comonomer units in the xylene solubles is preferably from 0.02 wt % to 4.0 wt %, more preferably from 0.1 wt % to 2.0 wt %.
If the C5-12 alpha-olefin is 1-octene and its amount is indicated in wt %, the amount of 1-octene-derived comonomer units in the xylene solubles is preferably from 0.03 wt % to 5.0 wt %, more preferably from 1.3 wt % to 2.5 wt %.
Preferably, the total amount of comonomer units, more preferably of the comonomer units derived from ethylene and at least one C5-12 alpha-olefin, in the polypropylene composition of the moulded article is preferably from 1.7 mol % to 33 mol %, more preferably from 2.5 mol % to 14 mol %, even more preferably from 3.0 mol % to 8.5 mol %.
If the C5-12 alpha-olefin is 1-hexene and its amount is indicated in wt %, the total amount of ethylene- and 1-hexene-derived comonomer units in the polypropylene composition is preferably from 2.5 wt % to 31 wt %, more preferably from 4 wt % to 9 wt %.
If the C5-12 alpha-olefin is 1-octene and its amount is indicated in wt %, the total amount of ethylene- and 1-octene-derived comonomer units in the polypropylene composition is preferably from 3.0 wt % to 30 wt %, more preferably from 5.0 wt % to 11 wt %.
As already indicated above, the amounts of comonomer units derived from ethylene and/or at least one C5-12 alpha-olefin in the polypropylene composition of the moulded article are preferably based on the total amount of propylene polymer(s) being present in the composition. If there are two or more propylene polymer fractions, it is the total weight of these fractions on which the amounts of comonomer units derived from ethylene and/or at least one C5-12 alpha-olefin in the polypropylene composition are based.
Melt flow rate MFR (2.16 kg, 230° C.) of the polypropylene composition of the moulded article can be varied over a broad range. Preferably, the polypropylene composition has a melt flow rate MFR (2.16 kg, 230° C.) of from 2.0 to 100 g/10 min, more preferably 4.0 to 80 g/10 min, even more preferably from 5.0 to 50 g/10 min, or from 5.0 to 30 g/10 min.
The xylene solubles of the polypropylene composition of the moulded article may have an intrinsic viscosity IV of at least 0.7 dl/g, more preferably from 0.7 to 5.0 dl/g, even more preferably from 0.7 to 3.0 dl/g, such as 0.8 to 2.0 dl/g.
The xylene solubles can be completely amorphous or may still have some degree of crystallinity. Preferably the xylene solubles have some crystallinity and the melting enthalpy ΔHm(XS) of the xylene solubles is preferably within the range of from 0.5 to 60 J/g, more preferably from 0.5 to 50 J/g.
In order to provide sufficient softness, it can be preferred that the polypropylene composition of the moulded article has a tensile modulus of less than 700 MPa, more preferably less than 600 MPa, or even less than 500 MPa. As a preferred lower limit for tensile modulus, a value of 100 MPa can be chosen.
As already indicated above, the polypropylene composition of the moulded article may contain just one propylene polymer fraction (i.e. prepared in a single step polymerization process) or may alternatively contain a mixture of two or more (e.g. three) propylene polymer fractions which are preferably prepared in a sequence of at least two (e.g. three) polymerization reactors (i.e. so-called reactor-blending).
In a preferred embodiment, the polypropylene composition is a reactor blend. Preferably, the reactor blend comprises at least two, more preferably at least three different propylene polymer fractions prepared by sequential polymerization in at least three polymerization reactors.
In a preferred embodiment, the polypropylene composition of the moulded article is a blend, preferably a reactor blend, comprising the following propylene polymer fractions P1, P2 and P3:

    
    
        (P1) a propylene homopolymer or a propylene copolymer comprising comonomer units derived from at least one C5-12 alpha-olefin in an amount of less than 1.0 mol %, more preferably of from 0.1 mol % to less than 1.0 mol %,
        (P2) a propylene copolymer comprising comonomer units derived from at least one C5-12 alpha-olefin in an amount of from 2.0 mol % to 7.0 mol %, more preferably of from 2.6 mol % to 5.3 mol %, and
        (P3) a propylene copolymer comprising ethylene-derived comonomer units in an amount of from 4.0 wt % to 70 wt %, more preferably of from 5.0 wt % to 50 wt %, even more preferably from 5.0 wt % to 30 wt %, like from 6.0 wt % to 20 wt %, or from 6.0 to 15 wt %.
    
    


Preferably, each of the propylene polymer fractions P1 and P2 contains less than 1.0 wt % of ethylene-derived comonomer units, more preferably neither P1 nor P2 contains ethylene-derived comonomer units.
If the propylene polymer fraction P1 contains comonomer units derived from at least one C5-12 alpha-olefin such as 1-hexene and/or 1-octene, it is preferably the same C5-12 alpha-olefin as in the propylene polymer fraction P2.
Preferably, the propylene polymer fraction P1 has a melt flow rate MFR (2.16 kg/230° C.) of from 2 to 1000 g/10 min.
Preferably, the propylene polymer fraction P2 has a melt flow rate MFR (2.16 kg/230° C.) of from 2 to 1000 g/10 min.
Optionally, the propylene polymer fraction P3 may additionally contain comonomer units derived from at least one C5-12 alpha-olefin, such as 1-hexene or 1-octene. If present, it is preferably the same C5-12 alpha-olefin as in polymer component P2. In a preferred embodiment, the propylene polymer fraction P3 contains less than 2.0 mol %, more preferably from 0.1 mol % to less than 1.0 mol % of comonomer units derived from at least one C5-12 alpha-olefin.
Preferably, the propylene polymer fraction P1 is present in the polypropylene composition in an amount of from 20 to 45 wt %, more preferably from 25 to 40 wt %, based on the total weight of P1+P2+P3.
Preferably, the propylene polymer fraction P2 is present in the polypropylene composition in an amount of from 20 to 45 wt %, more preferably from 25 to 40 wt %, based on the total weight of P1+P2+P3.
Preferably, the propylene polymer fraction P3 is present in the polypropylene composition in an amount of from 15 to 40 wt %, more preferably from 20 to 40 wt %, based on the total weight of P1+P2+P3.
Preferably, the propylene polymer fraction P3 has an intrinsic viscosity IV of from 0.7 to 5.0 dl/g, more preferably from 0.7 to 3.0 dl/g or from 0.8 to 2.0 dl/g.
In a preferred embodiment, the polypropylene composition of the moulded article is a heterophasic polypropylene composition comprising a polymer matrix and a dispersed polymer phase (i.e. dispersed in said matrix).
Preferably, the dispersed polymer phase comprises the propylene polymer fraction P3 as described above.
The polypropylene composition of the moulded article may contain additives known in the art, like antioxidants, nucleating agents, slip agents and antistatic agents. Typically the composite does not contain more than 7 wt.-%, more preferably not more than 5 wt.-%, or not more than 2.5 wt.-% of additives mentioned herein, based on the total weight of the polypropylene composition.
Preferably, at least 80 wt %, more preferably at least 90 wt % of the moulded article is made of the polypropylene composition described above. However, it is also possible that the moulded article consists of the polypropylene composition.
Preferably, the moulded article is an injection moulded article, an injection blow moulded article, or an injection stretch blow moulded article.
Preferably, the moulded article comprises one or more three-dimensionally curved areas (i.e. is not entirely flat). Furthermore, the moulded article is preferably rigid.
Preferably, the moulded article is not a film (such as a film used for heat-sealed packages).
Preferably, the moulded article has a stress whitening intensity of less than 3.0, more preferably less than 2.5, even more preferably less than 2.0 or even less than 1.5. Stress whitening intensity is determined by the method described in further detail below under the headline “Measuring methods”.
The moulded article of the present invention is useful e.g. for automotive applications, packaging applications (e.g. rigid packaging, transport packaging, etc.), caps and closures (hinge caps), appliances, house ware, or bottles.
The polypropylene composition of the moulded article as described above can be prepared by a process, comprising:

    
    
        (i) preparing as a first propylene polymer fraction a propylene homopolymer or a propylene copolymer comprising comonomer units derived from at least one C5-12 alpha-olefin in a first polymerization reactor PR1,
        (ii) transferring the first propylene polymer fraction obtained in the first polymerization reactor to a second polymerization reactor PR2 and preparing a second propylene polymer fraction by polymerizing propylene and at least one C5-12 alpha-olefin in the presence of the first propylene polymer fraction, thereby obtaining a reactor blend of the first and second propylene polymer fractions,
        (iii) transferring the reactor blend of step (ii) into a third polymerization reactor
    
    


PR3 and preparing a third propylene polymer fraction by polymerizing propylene and ethylene in the presence of the reactor blend of step (ii), thereby obtaining a reactor blend of the first, second and third propylene polymer fractions.
If present in step (i), the at least one C5-12 alpha-olefin is preferably the same as in step (ii).
Preferably, no separate C5-12 alpha-olefin feed is introduced into the third polymerization reactor PR3. However, the third polymerization reactor PR3 may contain unreacted C5-12 alpha-olefin from the second polymerization reactor PR2.
Preferably, the first, second and third propylene polymer fractions prepared in steps (i), (ii) and (iii) correspond to those fractions as already described above, i.e. propylene polymer fractions P1, P2, and P3.
Preferably, the split between the first propylene polymer fraction of PR1 and the second propylene polymer fraction of PR2 is 70/30 to 30/70, more preferably 60/40 to 40/60.
Preferably, the split between the reactor blend of step (ii) (i.e. the fractions of PR1 and PR2) and the third propylene polymer fraction of PR3 is 85/15 to 60/40, more preferably 80/20 to 60/40.
Preferably, the first polymerization reactor PR1 is a slurry reactor, such as a loop reactor.
Appropriate conditions for operating a slurry reactor such as a loop reactor and how to adjust and fine-tune final polymer properties are generally known to the skilled person or can be determined by routine experimentation. Exemplary operation conditions in the slurry reactor may be as follows:

    
    
        temperature within the range of 40° C. to 110° C., more preferably between 60° C. and 100° C.,
        pressure within the range of 20 bar to 80 bar, more preferably between 40 bar to 70 bar,
        hydrogen can be added for controlling the molar mass in a manner known per se.
    
    


Preferably, the second and third polymerization reactors are both a gas phase reactor.
Appropriate conditions for operating a gas phase reactor and how to adjust and fine-tune final polymer properties are generally known to the skilled person or can be determined by routine experimentation. Exemplary operation conditions in the gas phase reactor may be as follows:

    
    
        temperature within the range of 50° C. to 130° C., more preferably between 60° C. and 100° C.,
        pressure within the range of 5 bar to 50 bar, more preferably between 15 bar to 40 bar,
        hydrogen can be added for controlling the molar mass in a manner known per se.
    
    


Optionally, a pre-polymerization reactor is operated up-stream the first polymerization reactor PR1.
Preferably, a catalyst composition comprising a single site catalyst is used in at least one of the polymerization reactors PR1 to PR3. In a preferred embodiment, the same single site catalyst is used in all polymerization reactors PR1 to PR3.
Catalyst compositions based on single site catalysts such as metallocene compounds are generally known to the skilled person.
The catalyst composition can be supported on an external support material or carrier such as an inorganic oxide (e.g. a silica support of sufficiently high pore volume and/or BET surface area).
Alternatively, it can be preferred to use a catalyst composition comprising solid catalyst particles which do not contain any external support material. This type of catalyst composition is described e.g. in WO 03/051934 and can be prepared by an emulsion solidification technology.
In a preferred embodiment, the catalyst composition is a solid catalyst system (SCS) which has a porosity measured according ASTM 4641 of less than 1.40 ml/g and/or a surface area measured according to ASTM D 3663 of lower than 25 m2/g.
Preferably the solid catalyst system (SCS) has a surface area of lower than 15 m2/g, yet still lower than 10 m2/g and most preferred lower than 5 m2/g, which is the lowest measurement limit. The surface area is measured according to ASTM D 3663 (N2).
Alternatively or additionally it is preferred that the solid catalyst system (SCS) has a porosity of less than 1.30 ml/g and more preferably less than 1.00 ml/g. The porosity has been measured according to ASTM 4641 (N2). In another preferred embodiment the porosity is not detectable when determined with the method applied according to ASTM 4641 (N2).
Furthermore the solid catalyst system (SCS) typically has a mean particle size of not more than 500 μm, i.e. preferably in the range of 2 to 500 μm, more preferably 5 to 200 μm. It is in particular preferred that the mean particle size is below 80 μm, still more preferably below 70 μm. A preferred range for the mean particle size is 5 to 70 μm, or even 10 to 60 μm.
As stated above the transition metal (M) is preferably zirconium (Zr) or hafnium (Hf), preferably zirconium (Zr).
The term “σ-ligand” is understood in the whole description in a known manner, i.e. a group bound to the metal via a sigma bond. Thus the anionic ligands “X” can independently be halogen or be selected from the group consisting of R′, OR′, SiR′3, OSiR′3, OSO2CF3, OCOR′, SR′, NR′2 or PR′2 group wherein R′ is independently hydrogen, a linear or branched, cyclic or acyclic, C1 to C20 alkyl, C2 to C20 alkenyl, C2 to C20 alkynyl, C3 to C12 cycloalkyl, C6 to C20 aryl, C7 to C20 arylalkyl, C7 to C20 alkylaryl, C8 to C20 arylalkenyl, in which the R′ group can optionally contain one or more heteroatoms belonging to groups 14 to 16. In a preferred embodiments the anionic ligands “X” are identical and either halogen, like Cl, or methyl or benzyl.
A preferred monovalent anionic ligand is halogen, in particular chlorine (Cl). The substituted cyclopentadienyl-type ligand(s) may have one or more substituent(s) being selected from the group consisting of halogen, hydrocarbyl (e.g. C1 to C20 alkyl, C2 to C20 alkenyl, C2 to C20 alkynyl, C3 to C20 cycloalkyl, like C1 to C20 alkyl substituted C5 to C20 cycloalkyl, C6 to C20 aryl, C5 to C20 cycloalkyl substituted C1 to C20 alkyl wherein the cycloalkyl residue is substituted by C1 to C20 alkyl, C7 to C20 arylalkyl, C3 to C12 cycloalkyl which contains 1, 2, 3 or 4 heteroatom(s) in the ring moiety, C6 to C20-heteroaryl, C1 to C20-haloalkyl, —SiR“3, —SR”, —PR′′2 or —NR′′2, each R′′ is independently a hydrogen or hydrocarbyl (e.g. C1 to C20 alkyl, C1 to C20 alkenyl, C2 to C20 alkynyl, C3 to C12 cycloalkyl, or C6 to C20 aryl) or e.g. in case of —NR′′2, the two substituents R′′ can form a ring, e.g. five- or six-membered ring, together with the nitrogen atom wherein they are attached to.
Further “R” of formula (I) is preferably a bridge of 1 to 4 atoms, such atoms being independently carbon (C), silicon (Si), germanium (Ge) or oxygen (O) atom(s), whereby each of the bridge atoms may bear independently substituents, such as C1 to C20-hydrocarbyl, tri(C1 to C20-alkyl)silyl, tri(C1 to C20-alkyl)siloxy and more preferably “R” is a one atom bridge like e.g. —SIR′′′2-, wherein each R′′′ is independently C1 to C20-alkyl, C2 to C20-alkenyl, C2 to C20-alkynyl, C3 to C12 cycloalkyl, C6 to C20-aryl, alkylaryl or arylalkyl, or tri(C1 to C20 alkyl)silyl-residue, such as trimethylsilyl-, or the two R′′′ can be part of a ring system including the Si bridging atom.
In a preferred embodiment the transition metal compound has the formula (II)




wherein

    M is zirconium (Zr) or hafnium (Hf), preferably zirconium (Zr),
    X are ligands with a σ-bond to the metal “M”, preferably those as defined above for formula (I),
    
        preferably chlorine (Cl) or methyl (CH3), the former especially preferred,
    
    
    R1 are equal to or different from each other, preferably equal to, and are selected from the group consisting of linear saturated C1 to C20 alkyl, linear unsaturated C1 to C20 alkyl, branched saturated C1-C20 alkyl, branched unsaturated C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, C7 to C20 alkylaryl, and C7 to C20 arylalkyl, optionally containing one or more heteroatoms of groups 14 to 16 of the Periodic Table (IUPAC),
    
        preferably are equal to or different from each other, preferably equal to, and are C1 to C10 linear or branched hydrocarbyl, more preferably are equal to or different from each other, preferably equal to, and are C1 to C6 linear or branched alkyl,
    
    
    R2 to R6 are equal to or different from each other and are selected from the group consisting of hydrogen, linear saturated C1-C20 alkyl, linear unsaturated C1-C20 alkyl, branched saturated C1-C20 alkyl, branched unsaturated C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkylaryl, and C7-C20 arylalkyl, optionally containing one or more heteroatoms of groups 14 to 16 of the Periodic Table (IUPAC), preferably are equal to or different from each other and are C1 to C10 linear or branched hydrocarbyl, more preferably are equal to or different from each other and are C1 to C6 linear or branched alkyl,
    R7 and R8 are equal to or different from each other and selected from the group consisting of hydrogen, linear saturated C1 to C20 alkyl, linear unsaturated C1 to C20 alkyl, branched saturated C1 to C20 alkyl, branched unsaturated C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, C7 to C20 alkylaryl, C7 to C20 arylalkyl, optionally containing one or more heteroatoms of groups 14 to 16 of the Periodic Table (IUPAC), SiR103, GeR103, OR10, SR10 and NR102,
    
        wherein
        R10 is selected from the group consisting of linear saturated C1-C20 alkyl, linear unsaturated C1 to C20 alkyl, branched saturated C1 to C20 alkyl, branched unsaturated C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, C7 to C20 alkylaryl, and C7 to C20 arylalkyl, optionally containing one or more heteroatoms of groups 14 to 16 of the Periodic Table (IUPAC),
        and/or
        R7 and R8 being optionally part of a C4 to C20 carbon ring system together with the indenyl carbons to which they are attached, preferably a C5 ring, optionally one carbon atom can be substituted by a nitrogen, sulfur or oxygen atom,
    
    
    R9 are equal to or different from each other and are selected from the group consisting of hydrogen, linear saturated C1 to C20 alkyl, linear unsaturated C1 to C20 alkyl, branched saturated C1 to C20 alkyl, branched unsaturated C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, C7 to C20 alkylaryl, C7 to C20 arylalkyl, OR10, and SR10, preferably R9 are equal to or different from each other and are H or CH3,
    
        wherein
        R10 is defined as before,
    
    
    L is a bivalent group bridging the two indenyl ligands, preferably being a C2R114 unit or a SiR112 or GeR112, wherein,
    
        R11 is selected from the group consisting of H, linear saturated C1 to C20 alkyl, linear unsaturated C1 to C20 alkyl, branched saturated C1 to C20 alkyl, branched unsaturated C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, C7 to C20 alkylaryl or C7 to C20 arylalkyl, optionally containing one or more heteroatoms of groups 14 to 16 of the Periodic Table (IUPAC),
        preferably Si(CH3)2, SiCH3C6H11, or SiPh2,
        wherein C6H11 is cyclohexyl.
    
    


Preferably the transition metal compound of formula (II) is C2-symmetric or pseudo-C2-symmetric. Concerning the definition of symmetry it is referred to Resconi et al. Chemical Reviews, 2000, Vol. 100, No. 4 1263 and references herein cited.
Preferably the residues R1 are equal to or different from each other, more preferably equal, and are selected from the group consisting of linear saturated C1 to C10 alkyl, linear unsaturated C1 to C10 alkyl, branched saturated C1 to C10 alkyl, branched unsaturated C1 to C10 alkyl and C7 to C12 arylalkyl. Even more preferably the residues R1 are equal to or different from each other, more preferably equal, and are selected from the group consisting of linear saturated C1 to C6 alkyl, linear unsaturated C1 to C6 alkyl, branched saturated C1 to C6 alkyl, branched unsaturated C1 to C6 alkyl and C7 to C10 arylalkyl. Yet more preferably the residues R1 are equal to or different from each other, more preferably equal, and are selected from the group consisting of linear or branched C1 to C4 hydrocarbyl, such as for example methyl or ethyl.
Preferably the residues R2 to R6 are equal to or different from each other and linear saturated C1 to C4 alkyl or branched saturated C1 to C4 alkyl. Even more preferably the residues R2 to R6 are equal to or different from each other, more preferably equal, and are selected from the group consisting of methyl, ethyl, iso-propyl and tert-butyl.
Preferably R7 and R8 are equal to or different from each other and are selected from hydrogen and methyl, or they are part of a 5-methylene ring including the two indenyl ring carbons to which they are attached. In another preferred embodiment, R7 is selected from OCH3 and OC2H5, and R8 is tert-butyl.
In a preferred embodiment the transition metal compound is rac-methyl(cyclohexyl)silanediyl bis(2-methyl-4-(4-tert-butylphenyl)indenyl)zirconium dichloride.
In another preferred embodiment, the transition metal compound is rac-dimethylsilanediyl bis(2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl)zirconium dichloride.
In another preferred embodiment, the transition metal compound is rac-dimethylsilanediylbis(2-methyl-4-phenyl-5-methoxy-6-tert-butylindenyl)zirconium dichloride.
Preferably, the solid catalyst system (SCS) comprises a cocatalyst comprising an element of group 13 of the periodic table (IUPAC), for instance the cocatalyst comprises a compound of Al.
Examples of such cocatalyst are organo aluminium compounds, such as aluminoxane compounds.
Particularly preferred cocatalysts are the aluminoxanes, in particular the C1 to C10-alkylaluminoxanes, most particularly methylaluminoxane (MAO).
Preferably, the organo-zirconium compound of formula (I) and the cocatalyst (Co) of the solid catalyst system (SCS) represent at least 70 wt %, more preferably at least 80 wt %, even more preferably at least 90 wt %, even further preferably at least 95 wt % of the solid catalyst system. Thus it is appreciated that the solid catalyst system is featured by the fact that it is self-supported, i.e. it does not comprise any catalytically inert support material, like for instance silica, alumina or MgCl2 or porous polymeric material, which is otherwise commonly used in heterogeneous catalyst systems, i.e. the catalyst is not supported on external support or carrier material. As a consequence of that the solid catalyst system (SCS) is self-supported and it has a rather low surface area.
Appropriate moulding processes for preparing the moulded article of the present invention are commonly known to the skilled person. Preferably, the moulded article is prepared by injection moulding, injection blow moulding, injection stretch blow moulding, thin wall injection moulding, high speed injection moulding, or any combination thereof.
According to a further aspect, the present invention relates to the use of the polypropylene composition described above for improving stress whitening, in particular of a moulded article (e.g. injection moulded article).
The present invention will now be described in further detail by the following Examples.


EXAMPLES
1. Measuring Methods
If not otherwise indicated, the parameters mentioned in the present application are measured by the methods outlined below.
1. Comonomer Content by NMR Spectroscopy
Quantitative nuclear-magnetic resonance (NMR) spectroscopy was used to quantify the tacticity, regio-regularity and comonomer content of the polymers.
Quantitative 13C {1H} NMR spectra recorded in the molten-state using a Bruker Advance III 500 NMR spectrometer operating at 500.13 and 125.76 MHz for 1H and 13C respectively. All spectra were recorded using a 13C optimised 7 mm magic-angle spinning (MAS) probehead at 180° C. using nitrogen gas for all pneumatics. Approximately 200 mg of material was packed into a 7 mm outer diameter zirconia MAS rotor and spun at 4 kHz. This setup was chosen primarily for the high sensitivity needed for rapid identification and accurate quantification. Standard single-pulse excitation was employed utilising the NOE at short recycle delays and the RS-HEPT decoupling scheme. A total of 1024 (1 k) transients were acquired per spectra.
Quantitative 13C {1H} NMR spectra were processed, integrated and relevant quantitative properties determined from the integrals. All chemical shifts are internally referenced to the methyl isotactic pentad (mmmm) at 21.85 ppm. Characteristic signals corresponding to regio defects and comonomer were observed.
The tacticity distribution was quantified through integration of the methyl region between 23.6-19.7 ppm correcting for any sites not related to the stereo sequences of interest.
Specifically the influence of regio defects and comonomer on the quantification of the tacticity distribution was corrected for by subtraction of representative regio defect and comonomer integrals from the specific integral regions of the stereo sequences.
The isotacticity was determined at the triad level and reported as the percentage of isotactic triad (mm) sequences with respect to all triad sequences:

[mm]%=100*(mm/(mm+mr+rr))

where mr represents the sum of the reversible mr and rm triad sequences.

The presence of 2,1 erythro regio defects was indicated by the presence of the two methyl sites at 17.7 and 17.2 ppm and confirmed by other characteristic sites.
Characteristic signals corresponding to other types of regio defects were not observed.
The amount of 2,1 erythro regio defects was quantified using the average integral of the two characteristic methyl sites at 17.7 and 17.2 ppm:

P21e=(Ie6+Ie8)/2

The amount of 1,2 primary inserted propene was quantified based on the methyl region with correction undertaken for sites included in this region not related to primary insertion and for primary insertion sites excluded from this region:

P12=ICH3+P12e 

The total amount of propene was quantified as the sum of primary (1,2) inserted propene and all other present regio defects:

Ptotal=P12+P21e 

The mole percent of 2,1 erythro regio defects was quantified with respect to all propene:

[21e] mol %=100*(P21e/Ptotal)

Characteristic signals corresponding to the incorporation of C5-12 alpha-olefin were observed. The amount isolated C5-12 alpha-olefin incorporated in PPC5-12PP sequences was quantified using the integral of the corresponding sites accounting for the number of reporting sites per comonomer.
The amount isolated 1-hexene incorporated in PPHPP sequences was quantified using the integral of the αB4 sites at 44.1 ppm accounting for the number of reporting sites per comonomer:

H=I[αB4]/2

With sites indicative of consecutive incorporation not observed the total 1-hexene comonomer content was calculated solely on this quantity:

Htotal=H 

The amount isolated 1-octene incorporated in PPOPP sequences was quantified using the integral of the αB6 sites at 44.0 ppm accounting for the number of reporting sites per comonomer:

O=I[αB6]/2

With sites indicative of consecutive incorporation not observed the total 1-octene comonomer content was calculated solely on this quantity:

Ototal=O 

Characteristic signals corresponding to the incorporation of ethylene were observed. The amount isolated ethylene incorporated in PPEPP sequences was quantified using the integral of the Sαγ sites at 37.8 ppm accounting for the number of reporting sites per comonomer:

E=I[Sαγ]/2

The amount consecutively incorporated ethylene in PPEEPP sequences was quantified using the integral of the Sβδ site at 26.9 ppm accounting for the number of reporting sites per comonomer:

EE=ISβ

Sites indicative of further types of ethylene incorporation e.g. PPEPEPP and PPEEEPP were quantified from characteristic signals as EPE and EEE and accounted for in a similar way as PPEEPP sequences. The total ethylene comonomer content was calculated based on the sum of isolated, consecutive and non consecutively incorporated ethylene:

Etotal+E+EE+EPE+EEE 

The total mole fraction of comonomer in the polymer was calculated as:

fE=(Etotal/(Etotal+Ptotal+C5-12;total)

fC5-12=(Etotal/(Etotal+Ptotal+C5-12;total)

The mole percent comonomer incorporation in the polymer was calculated from the mole fraction according to:

[C5-12] mol %=100*fc5-12 

[E] mol %=100*fE 

The weight percent 1-hexene and ethylene incorporation in the polymer was calculated from the mole fraction according to:

[H] wt %=100*(fH*84.16)/((fE*28.05)+(fH*84.16)+((1−(fE+fH))*42.08))

[E] wt %=100*(fE*28.05)/((fE*28.05)+(fH*84.16)+((1−(fE+fH))*42.08))

The weight percent 1-octene and ethylene incorporation in the polymer was calculated from the mole fraction according to:

[O] wt %=100*(fO*112.21)/((fE*28.05)+(fO*112.21)+((1−(fE+fO))*42.08))

[E] wt %=100*(fE*28.05)/((fE*28.05)+(fO*112.21)+((1−(fE+fO))*42.08))

2. Amount of Xylene Solubles (XS, Wt.-%)
The amount of xylene solubles was determined at 25° C. according ISO 16152; first edition; 2005-07-01.
3. MFR (230° C., 2.16 kg)
Melt flow rate MFR (230° C., 2.16 kg) was measured according to ISO 1133 (230° C., 2.16 kg load).
4. Melting Temperature (Tm) and Melting Enthalpy (ΔHm), Crystallization Temperature (Tc) and Crystallization Enthalpy (ΔHc 
Measured with Mettler TA820 differential scanning calorimetry (DSC) on 5 to 10 mg samples. DSC is run according to ISO 11357-3:1999 in a heat/cool/heat cycle with a scan rate of 10° C./min in the temperature range of +23 to +210° C. Crystallization temperature and crystallization enthalpy are determined from the cooling step, while melting temperature and melting enthalpy are determined from the second heating step. Melting and crystallization temperatures were taken as the peaks of endotherms and exotherms.
5. Haze and Clarity
Haze was determined according to ASTM D 1003-00on 60×60×2 mm3 plaques injection moulded in line with EN ISO 1873-2 using a melt temperature of 200° C.
6. Tensile Modulus; Tensile Stress at Break
were measured according to ISO 527-2 (cross head speed=1 mm/min; 23° C.) using injection molded specimens as described in EN ISO 1873-2 (dog bone shape, 4 mm thickness).
7. Charpy Impact Test
The Charpy notched impact strength (Charpy NIS) was measured according to ISO 179 1 eA at 23° C., using injection molded bar test specimens of 80×10×4 mm3 mm3 prepared in accordance with ISO 294-1:1996
8. Intrinsic Viscosity is Measured According to DIN ISO 1628/1, October 1999 (in Decalin at 135° C.)
9. Calculation of Comonomer Content, Xylene Solubles XS and MFR (2.16 kg, 230° C.) of the Individual Propylene Polymer Fractions P2 and P3, Respectively
Calculation of comonomer content of the propylene polymer fraction P2:




  
    
      
        
          
            
              C
              ⁡
              
                (
                
                  
                    P
                    ⁢
                    
                      
                    
                    ⁢
                    1
                  
                  +
                  
                    P
                    ⁢
                    
                      
                    
                    ⁢
                    2
                  
                
                )
              
            
            -
            
              
                w
                ⁡
                
                  (
                  
                    P
                    ⁢
                    
                      
                    
                    ⁢
                    1
                  
                  )
                
              
              ×
              
                C
                ⁡
                
                  (
                  
                    P
                    ⁢
                    
                      
                    
                    ⁢
                    1
                  
                  )
                
              
            
          
          
            w
            ⁡
            
              (
              
                P
                ⁢
                
                  
                
                ⁢
                2
              
              )
            
          
        
        =
        
          C
          ⁡
          
            (
            
              P
              ⁢
              
                
              
              ⁢
              2
            
            )
          
        
      
    
    
      
        (
        I
        )
      
    
  




wherein

    w(P1) is the weight fraction [in wt.-%] of the propylene polymer fraction P1 in the blend of propylene polymer fractions P1 and P2,
    w(P2) is the weight fraction [in wt.-%] of the propylene polymer fraction P2 in the blend of propylene polymer fractions P1 and P2,
    C(P1) is the comonomer content [in wt.-%] of the propylene polymer fraction P1,
    C(P1+P2) is the comonomer content [in wt.-%] of the blend of propylene polymer fractions P1 and P2,
    C(P2) is the calculated comonomer content [in wt.-%] of the propylene polymer fraction P2.

Calculation of the amount of xylene solubles XS of the propylene polymer fraction P2:







  
    
      
        
          
            
              XS
              ⁡
              
                (
                
                  
                    P
                    ⁢
                    
                      
                    
                    ⁢
                    1
                  
                  +
                  
                    P
                    ⁢
                    
                      
                    
                    ⁢
                    2
                  
                
                )
              
            
            -
            
              
                w
                ⁡
                
                  (
                  
                    P
                    ⁢
                    
                      
                    
                    ⁢
                    1
                  
                  )
                
              
              ×
              
                XS
                ⁡
                
                  (
                  
                    P
                    ⁢
                    
                      
                    
                    ⁢
                    1
                  
                  )
                
              
            
          
          
            w
            ⁡
            
              (
              
                P
                ⁢
                
                  
                
                ⁢
                2
              
              )
            
          
        
        =
        
          XS
          ⁡
          
            (
            
              P
              ⁢
              
                
              
              ⁢
              2
            
            )
          
        
      
    
    
      
        (
        II
        )
      
    
  




wherein

    w(P1) is the weight fraction [in wt.-%] of the propylene polymer fraction P1 in the blend of propylene polymer fractions P1 and P2,
    w(P2) is the weight fraction [in wt.-%] of the propylene polymer fraction P2 in the blend of propylene polymer fractions P1 and P2,
    XS(P1) is the amount of xylene solubles XS [in wt.-%] of the propylene polymer fraction P1,
    XS(P1+P2) is the amount of xylene solubles XS [in wt.-%] of the blend of propylene polymer fractions P1 and P2,
    XS(P2) is the calculated amount of xylene solubles XS [in wt.-%] of the propylene polymer fraction P2.

Calculation of melt flow rate MFR2 (230° C.) of the propylene polymer fraction P2:







  
    
      
        
          M
          ⁢
          
            
          
          ⁢
          F
          ⁢
          
            
          
          ⁢
          
            R
            ⁡
            
              (
              
                P
                ⁢
                
                  
                
                ⁢
                2
              
              )
            
          
        
        =
        
          10
          
            [
            
              
                
                  log
                  ⁡
                  
                    (
                    
                      MFR
                      ⁡
                      
                        (
                        
                          
                            P
                            ⁢
                            
                              
                            
                            ⁢
                            1
                          
                          +
                          
                            P
                            ⁢
                            
                              
                            
                            ⁢
                            2
                          
                        
                        )
                      
                    
                    )
                  
                
                -
                
                  
                    w
                    ⁡
                    
                      (
                      
                        P
                        ⁢
                        
                          
                        
                        ⁢
                        1
                      
                      )
                    
                  
                  ×
                  
                    log
                    ⁡
                    
                      (
                      
                        MFR
                        ⁡
                        
                          (
                          
                            P
                            ⁢
                            
                              
                            
                            ⁢
                            1
                          
                          )
                        
                      
                      )
                    
                  
                
              
              
                w
                ⁡
                
                  (
                  
                    P
                    ⁢
                    
                      
                    
                    ⁢
                    2
                  
                  )
                
              
            
            ]
          
        
      
    
    
      
        (
        III
        )
      
    
  




wherein

    w(P1) is the weight fraction [in wt.-%] of the propylene polymer fraction P1 in the blend of propylene polymer fractions P1 and P2,
    w(P2) is the weight fraction [in wt.-%] of the propylene polymer fraction P2 in the blend of propylene polymer fractions P1 and P2,
    MFR (P1) is the melt flow rate MFR2 (230° C.) [in g/10 min] of the propylene polymer fraction P1,
    MFR (P1+P2) is the melt flow rate MFR2 (230° C.) [in g/10 min] of the blend of propylene polymer fractions P1 and P2,
    MFR (P2) is the calculated melt flow rate MFR2 (230° C.) [in g/10 min] of the propylene polymer fraction P2.

Calculation of comonomer content of the propylene polymer fraction P3:







  
    
      
        
          
            
              C
              ⁡
              
                (
                
                  
                    P
                    ⁢
                    
                      
                    
                    ⁢
                    1
                  
                  +
                  
                    P
                    ⁢
                    
                      
                    
                    ⁢
                    2
                  
                  +
                  
                    P
                    ⁢
                    
                      
                    
                    ⁢
                    3
                  
                
                )
              
            
            -
            
              
                w
                ⁡
                
                  (
                  
                    
                      P
                      ⁢
                      
                        
                      
                      ⁢
                      1
                    
                    +
                    
                      P
                      ⁢
                      
                        
                      
                      ⁢
                      2
                    
                  
                  )
                
              
              ×
              
                C
                ⁡
                
                  (
                  
                    
                      P
                      ⁢
                      
                        
                      
                      ⁢
                      1
                    
                    +
                    
                      P
                      ⁢
                      
                        
                      
                      ⁢
                      2
                    
                  
                  )
                
              
            
          
          
            w
            ⁡
            
              (
              
                P
                ⁢
                
                  
                
                ⁢
                3
              
              )
            
          
        
        =
        
          C
          ⁡
          
            (
            
              P
              ⁢
              
                
              
              ⁢
              3
            
            )
          
        
      
    
    
      
        (
        IV
        )
      
    
  




wherein

    w(P1+P2) is the weight fraction [in wt.-%] of the amount of propylene polymer fractions P1 and P2 in the blend of propylene polymer fractions P1, P2 and P3,
    w(P3) is the weight fraction [in wt.-%] of the propylene polymer fraction P3 in the blend of propylene polymer fractions P1, P2 and P3,
    C(P1+P2) is the comonomer content [in wt.-%] of the blend of propylene polymer fractions P1 and P2,
    C(P1+P2+P3) is the comonomer content [in wt.-%] of the blend of propylene polymer fractions P1, P2 and P3,
    C(P3) is the calculated comonomer content [in wt.-%] of the propylene polymer fraction P3.


10. Stress Whitening
The stress-whitening is determined by the method according to Altendorfer and Frank, (Kunststoffe 70 (1980), pages 98-101). In this context, a tensile test was carried out at 23° C. and at a test speed of 5 mm/min with an injection moulded modified F3/4 specimen according to DIN 53455/1981 where the width of the specimen is reduced in the middle with two round edgewise notches from 10 to 8 mm. The clamped length is 110 mm and the measured length is 50 mm. The whitening of the sample is then determined with an optical sensor in the narrowed part of the specimen. From the resulting force and light intensity vs. elongation—diagram the stress whitening intensity can be determined.
II. Preparation of Samples
Polypropylene samples have been prepared. The catalyst used in the polymerization process was a metallocene catalyst as described in example 10 of WO 2010/052263A1.
Reaction conditions are summarized in Table 1:







TABLE 1







Reaction conditions









Example












CE1
CE2
IE1
IE2















Loop
Reactor temperature (° C.)
70
75
70
70



MFR2 (g/10 min)
4.7
4
3.0
4.3



C6 content (wt %)
1.3
0
1.8
1.7



Split loop/(loop + GPR1) %
47
44
45
49



Split with respect to
41
—
30
38



final reactor blend (%)






GPR1
Reactor temperature (° C.)
85
85
85
85



MFR2 (g/10 min)
8.7
7.1
9.9
9.7



C6 content, total (wt %)
4.9
3.4
4.4
4.9



calculated C6 content
8.1
—
6.5
8.0



in GPR fraction, (wt %)







Split GPR1/(loop + GPR1) %
53
56
55
51



Split with respect to
47
—
36
39



final reactor blend (%)






GPR2
Reactor temperature (° C.)
80
80
80
80



C2/C3 ratio feed GPR2 (kg/kg)
0
0
0.3
0.3



Split %
12

34
23









The properties of the prepared polypropylene compositions are summarized in Table 2:







TABLE 2







PP properties









Ex.












CE1
CE2
IE1
IE2














MFR(2.16 kg/230° C.) (g/10 min)
7
8
15
15


C6 (wt % - NMR)
3.5
3.3
3.4
4.2


C2 (wt % - NMR)
0
0
3.3
2.1


C6 (mol % - NMR)
1.9
1.6
1.7
2.2


C2 (mol % - calc.)
0
0
4.9
3.1


Total comonomer (mol %)
1.9
1.6
6.6
5.3


C6 in XS (wt % - NMR)
nm
nm
1.1
1.4


C2 in XS (wt % - NMR)
0
0
9.6
9.1


XS (wt %)
0.97
1.7
34.1
22.9


Tensile modulus (MPa)
1108
950
477
572


Notched impact strength
4.4
nm
80.2
22


(NIS) at 23° C. (KJ/m2)






Haze (%)
80.8
76.5
62.7
71.2


Clarity (%)
90.2
89.1
96
96.9


Tm(° C.)
140
147
135
134









As shown by the data of Table 2, the samples of the present invention have an improved balance of low haze and high softness and toughness/impact strength.
Injection moulded samples of CE1, CE2, IE1 and IE2 were subjected to stress whitening measurements. The results are shown below in Tables 3 to 6.







TABLE 3







Stress whitening (SW) intensity of CE1











Energy
Force
Elongation
Distance
SW


[Nm]
[N]
[%]
[mm]
intensity





1.3840
660.1
4.19
2.79
3.00


1.3127
654.9
4.05
2.70
3.00


1.3376
657.3
4.09
2.73
3.00


1.3270
659.2
4.08
2.72
3.00


1.3610
660.7
4.13
2.77
3.00
















TABLE 4







Stress whitening (SW) intensity of CE2











Energy
Force
Elongation
Distance
SW


[Nm]
[N]
[%]
[mm]
intensity





1.5324
713.2
4.30
2.869
4.00


1.3443
715.5
3.86
2.575
4.00


1.4075
701.2
4.06
2.710
3.00


1.3717
707.3
3.95
2.633
3.00


1.3845
687.5
4.04
2.693
3.00
















TABLE 5







Stress whitening (SW) intensity of IE1











Energy
Force
Elongation
Distance
SW


[Nm]
[N]
[%]
[mm]
intensity














—
—
23.44
15.63
0


—
—
11.23
7.48
0
















TABLE 6







Stress whitening (SW) intensity of IE2











Energy
Force
Elongation
Distance
SW


[Nm]
[N]
[%]
[mm]
intensity





0.0260
123.1
0.59
0.396
0


2.1536
346.5
9.95
6.634
0


—
—
9.16
6.106
0









The data of Tables 5 and 6 clearly demonstrate that stress whitening is more or less completely suppressed in the samples according to the present invention.
FIG. 1 shows a shift of the ductile-brittle transition to lower temperatures in samples IE1 and IE2 (if compared to CE1 and CE2), thereby improving impact properties.
As demonstrated by the data provided above, the samples of the present invention have an improved balance of low haze and high softness and toughness/impact strength (see Table 2), while simultaneously more or less completely suppressing stress whitening (see Tables 5 and 6).

## Claims

1. A moulded article comprising a polypropylene composition, wherein the polypropylene composition comprises comonomer units derived from ethylene in an amount of from 0.5 wt % to 35 wt %, and from at least one C5-12 alpha-olefin in an amount of from 1.0 mol % to 3.0 mol %, wherein the polypropylene composition has an amount of xylene solubles XS of from 20 wt % to 39 wt %, and the xylene solubles have an amount of ethylene-derived comonomer units of from 4.0 wt % to 70 wt %, and the article has a tensile modulus of less than 700 MPa.

2. The moulded article according to claim 1, wherein the at least one C5-12 alpha-olefin is selected from 1-hexene, 1-octene, or any mixture thereof.

3. The moulded article according to claim 1, wherein the following relation is satisfied:


[C2(XS)×XS/100]/C2(total)≧0.9


wherein
C2(XS) is the amount in wt % of the ethylene-derived comonomer units in the xylene solubles,
XS is the amount in wt % of xylene solubles of the polypropylene composition,
C2(total) is the amount in wt % of the ethylene-derived comonomer units in the polypropylene composition.

4. The moulded article according to claim 1, wherein the xylene solubles of the polymer composition contain an amount of comonomer units which are derived from the at least one C5-12 alpha-olefin of from 0.01 mol % to 2.0 mol %.

5. The moulded article according to claim 1, wherein the total amount of comonomer units in the polypropylene composition is from 1.7 mol % to 33 mol %.

6. The moulded article according to claim 1, wherein the polypropylene composition is a blend comprising the following propylene polymer fractions P1, P2 and P3:
(P1) a propylene homopolymer or a propylene copolymer comprising comonomer units derived from at least one C5-12 alpha-olefin in an amount of less than 1.0 mol %,
(P2) a propylene copolymer comprising comonomer units derived from at least one C5-12 alpha-olefin in an amount of from 2.0 mol % to 7.0 mol %, and
(P3) a propylene copolymer comprising ethylene-derived comonomer units in an amount of from 4.0 wt % to 70 wt %.

7. The moulded article according to claim 1, wherein the moulded article is an injection moulded article.

8. The moulded article according to claim 1, having a stress whitening intensity of less than 3.0, wherein the stress whitening is determined utilizing a tensile test carried out at 23° C. and at a test speed of 5 mm/min with an injection moulded modified F3/4 specimen according to DIN 53455/1981 where the width of the specimen is reduced in the middle with two round edgewise notches from 10 to 8 mm, and where the clamped length is 110 mm and the measured length is 50 mm, and wherein the whitening of the sample is then determined with an optical sensor in the narrowed part of the specimen where from the resulting force and light intensity versus elongation the stress whitening intensity is determined.

9. The moulded article according to claim 1, wherein the xylene solubles of the polymer composition contain an amount of comonomer units which are derived from the at least one C5-12 alpha-olefin of from 0.05 mol % to 1.0 mol %.

10. The moulded article according to claim 1, wherein the total amount of comonomer units derived from ethylene and at least one C5-12 alpha-olefin in the polypropylene composition is from 1.7 mol % to 33 mol %.

11. The moulded article according to claim 1, wherein the polypropylene composition is a reactor blend comprising the following propylene polymer fractions P1, P2 and P3:
(P1) a propylene homopolymer or a propylene copolymer comprising comonomer units derived from at least one C5-12 alpha-olefin in an amount of less than 1.0 mol %,
(P2) a propylene copolymer comprising comonomer units derived from at least one C5-12 alpha-olefin in an amount of from 2.0 mol % to 7.0 mol %, and
(P3) a propylene copolymer comprising ethylene-derived comonomer units in an amount of from 4.0 wt % to 70 wt %.