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# OAR Box 1338 Prepped by Ollie Stewart



## Document

Number: 

# 50 ) F

. R

. Decembe r20 , 198 9
Docket Number: 

# A-89-1 1

Printed 6/17/2008 1:48:07

PM Sheet 50 of 105P. 2

521S 0 Federa l Register/Vol

. 54 , No

. 243 , Wednesday , Decembe r 20 , 1989/Propose dRule s ENVIRONMENTA L PROTECTIO N AGENC Y 4 0 CF R Par t 6 0 Standard s o f Performanc e fo r Ne w Stationar y Sources ; Appendi x A — Additio n o f Method s fo r Measuremen t o f Polychlorinate d Dlbenzo-p-Dloxlns , Polychlorinate d Dibenzofurans , an d Hydroge n Chlorid e Emission s Fro m Stationar y Source s IAD-FRL-3694-2 ] AGENCY : Environmenta l Protectio n Agenc y (EPA)

. ACTION : Propose drul e an dnotic e o f publi c hearing

. SUMMARY : Th e purpos e o f thi s propose d rul e i s t o ad dMetho d23 , "Determinatio n o f Polychlorinate dDibenzo-p-Dioxin s (PCDDs ) an dPolychlorinate d Dibenzofuran s (PCDFs ) fro mStationar y Sources, " an dMetho d26

. "Determinatio n o

f Hydroge n Chlorid e Emission s fromStationar y Sources " t o Appendi x A o

f CF Rpar t 60

. Thes e method s ar e bein g propose dt o determin e complianc e with subpart s C a an dE ao f par t 60

. A publi c hearin g wil l b e held , i f requested , t o provid e intereste dperson s a n opportunit y fo

r ora l presentatio n o

f data , views , o r

argument s concernin g th e propose drule

. DATES : Comments. Comment s mus t b e receive do n o r

before Marc h 5.1990

. Public Hearing. I i anyon e contact s EP A requestin g t o spea k

a t apubli c hearin g b y Januar y 10,1990 , apubli c hearin g wil l b e hel dFebruar y 7,1990 , beginnin g a t

1 0 a.m . Person s intereste d i n attendin g th e hearin g shoul dcal l th e contac t mentione dunde r

ADDRESSE

S t o verif y tha t ahearin g wil l b e held

. Request to Speak at Hearing. Person s wishin g t o presen t

ora l testimon y mus t contac t EP A b y January 10,1990

. ADDRESSES : Comments. Comment s shoul db e submitte d(in duplicat e i f possible ) to : Air

Docke t (LE-131) , Attention : Docke t

Numbe r A-89-11 , U.S

. Environmenta l Protectio n Agency , roo m M-1500,1s t

Floor , Watersid e Mall , 40 1 M Stree t SW. , Washington , D C 20460

. Public Hearing. I

f anyon e contact s EP A requestin g apubli c hearing , i t wil l b e hel da t EPA' s Emissio n Measuremen t Laborator y Building , Researc h Triangl e Park , Nort

h Carolina

. Person s intereste d i n attendin g th e hearin g o r wishin g t o • presen t ora l testimon y shoul dnotif y Gar y McAIister , Emissio n Measuremen t Branc h (MD-19) , Technica l Support Division , U.S

. Environmenta l Protectio n Agency , Researc h Triangl e Park , Nort h Carolin a27711 , telephon e (919 ) 541

- 1062

. Docket. Docke t No

. A-89-11

. containin g material s relevan t to thi s rulemaking , i s availabl e fo r publi c inspectio n an dcopyin g betwee n 8 a.m . an d3:3 0 p.m. , Monday throug h Friday , a t EPA' s Ai r

Docke t roo mM-1500,1s t

. Floor , Watersid e Mall , 401 M Stree t SW. , Washington , DC

. 20460

. A reasonabl e fee may b e charge dfo r copying

. FO RFURTHE RINFORMATIO N CONTACT: . Gar y McAIister

o r Roger Shigehara , Emissio n Measuremen t

Branc h (MD-19) , Technica l Support

Division , U.S

. Environmenta l Protectio n Agency , Researc h Triangl e Park , Nort h Carolin a 27711 , telephon e numbe r

(919) 541-1082

. SUPPLEMENTAR Y INFORMATION : I

. Th e Rulemakin g Unde r subpart s C aan dEa , th e EP A i s proposin g t o regulat e emission s from municipa l wast e combustor s (MWCs ) whic h wil l includ e settin g emission

. . limit s fo r polychlorinate ddibenzo-p

dioxin s (PCDDs , CDDs , o r dioxins] , polychlorinate ddibenz o furan s (PCDFs , CDFs , o r furans) , an dhydrochlori c aci d (HCl)

. Ther e ar e presentl y n o method s publishe di n 40 CF

Rpar t 60 , appendi x A , t o measur e an y o

f thes e pollutants

. Thi s actio n woul dpropos e on e metho dt o measur e th e PCDD s an dPCDF s an d anothe r metho dt o measur e th e HCl

. Summary of.Reference Methods Metho d2 3 i s use dt o measur e th e emissio n o

f PCDD s an dPCDF s from MWCs

. A sampl e i s withdraw n isokineticall y fromth e stac k throug h a probe , afilter , an datra p packe dwit h a soli dadsorben t

Th e PCDD s an dPCDF s ar e collecte di n th e probe , o n th e filter , an do n th e soli dadsorben t Th e PCDD s an dPCDF s ar e extracte dfromth e particulat e matte r

an dth e adsorben t with aho t organi c solvent

. Th e extracte dPCDD s an dPCDF s ar e separate db y capillar y ga s chromatograph y an dthe n eac h isome r i s identifie dan dmeasure dwit h mas s spectrometry (GC/MS)

. Th e tota l PCDD s an dPCDF s ar e th e su mo

f th e individua l isomers

. Toxicit

y factor s ar e no t

use di n th e calculation

. Metho d26 i s use dt o measur e th e emissio n o

f HC l fromMWC3

. A sampl e i s withdraw n a t

aconstan t

rat e fromth e Btac k throug h aprob e an dimpinger s fille dwith adilut e acid

. Th e HC l i s collecte di n th e impinger

solution

. Th e chlorid e io n i s separate db y io n chromatograph y an dmeasure db y a conductivity detector

. Background In 1983 , th e America n Societ y o f Mechanica l Engineer s (ASME ) recognize dtha t

th e testin g fo

r PCDD s an dPCDF s neede dt o b e standardized

.

In Februar y o

f 1984 , th e ASM

E convene d acommitte e o

f governmen t representatives , testin g consultants , equipmen t

manufacturers , an d incinerato r

operator s t o writ e a standar dprocedur e for

PCDD s an d PCDFs

. Thi s eventuall y distribute da s a draf t ASM E protoco l i n Decembe r

of 1984

. Th e procedur e tha t

w e ar e proposin g wa s derive dfromthi s draf t ASME protocol

. W e ar e proposin g significan t change s i n th e quality assuranc e requirement s an dth e solvent s use dto recove r

th e sample

. Becaus e mor e labele dcompound s ar e available , th e propose dmetho dwil l requir e additiona l labele dinterna l standard s an dsurrogat e compound s whic h wil l provid e bette r

representatio n o

f th e entir e rang e o

f PCDD s an dPCDFs

. Unde r th e proposa l th e filter

an dsoli d adsorben t woul db e extracte di n th e laborator y with toluen e t o assur e ahig h PCD D an dPCDF recover y efficiency

. Additionall y th e propose dsampl e recover y solvent s use dfo r rinsin g th e sampl e trai n glasswar e i n th e field woul db e aceton e followe db y . methylen e chlorid e with afinal quality assuranc e rins e usin g toluene

. EP A wil l continu e to revie w th e toluen e fiel d rins e qualit y assuranc e result s an d continu e t o evaluat e th e desirabilit y o f replacin g methylen e chlorid e with toluen e fo r fiel drinsin g sampl e glassware

. II

. Administrativ e Requirements A. Public Hearing A publi c hearin g wil l b e held , i f requested , t o discus s th e propose dtes t method s i n accordanc e wit h sectio n 307(d)(5 ) o

f th e Clean Ai r

Ac t Person s wishin g t o mak e ora l presentation s shoul dcontac t

EP A a t th e addres s give n i n th e ADDRESSE

S sectio n o

f thi s preamble

. Ora l presentation s wil l b e limite dt o 1 5 minute s each

. An y membe r o f th e publi c ma y file awritte n statemen t with EP A before , during , o r withi n 3 0 day s after

th e hearing

. Writte n statement s shoul db e addresse dto th e Ai r Docke t addres s give n i n th e AODRESSE

S sectio n o

f thi s preamble

. A verbati mtranscrip t

o f th e hearin g an dwritte n statement s wil l b e availabl e fo r publi c inspectio n an dcopyin g durin g norma l workin g hour s a t

EPA' s Ai r Docke t i n Washington , D C (se e ADDRESSE S sectio n o

f thi s preamble)

. B. Docket Th e docke t

i s a n orj?".^

v -i d an d complet e file o

f al l th e informatio n submitte dt o o r

otherwis e considere db y EP A i n th e developmen t

o f thi s propose dP. 3

^ < w*affl«^rcwira«^a*ww* , i f



### Fedsra J Reg&ter/Vol

. 54 , No

. 343 , Wednesday , Decembe r 20 , 1989/ProposedRule s 10 1 EasagaaragitaaiiwwwMsaBaM^aaaag&raiEzr^ ^ rniaraulung

. Th e principa l p^irpose s o f th e docke t

are : (1 ) T aallo w intereste d partie s to identif

y an dlocat e document s s o tha t the y ca n effectivel y participat e i n th e rulemakin g proces s an d (2 ) t o serv e a s th e recor di n cas e of judicial , revie w (excep t

fo r interagenc y revie w materials ) [sectio n 307(d](7)(A)]

. • C Office of Management

and Budget Review Executiv e Orde r

1229 1 Review

. Unde r Executiv e Orde r

12291 , EP

A mu3 t judg e whethe r aregulatio n i s "major " and , therefore , subjec t

t o th e rsquiremen t

o f a regulatory impac t

analysis

. Th e proposa l of thes e tes t

method s i s no t

majo r becaus e i t

wii l no t hav e a n annua l effect o n th e economy o

f §100 millio n o r

more : i t wil l no t resul t i n amajo r

increas e i n cost s o r prices ; an dther e wil l b e n o significan t advers e effect s o n competition , employment , investment , productivity , innovation , o r o n th e abilit y o f U.S.-ba3e denterprise s t o compet e with foreign-baae denterprise s i n domesti c o r

export markets

. An y burde n resultin g fro

mth e us e o

f thes e method s i s considere di n th e burde n estimat e for

th e regulatio n requirin g th e us e o f thes e methods

. D. Rei4uiatyrjFkx&iliiy Act Compliar.no Pursuan t to th e provision s o

f 5 U.3.C

. 605(b) , I hereb y certif

y tha t thi s attache d r?ile , i f promulgated , wii l no t

hav e a n economi c impac t

on smal l entitie s becaus e n o additiona l cost s wil l b e incurre dfromthi s action

. Thi s proposa l doe 9 no t

contai n any Informatio n coilsctio n requirement s subjec t t o OM B revie w unde r

th e Paperwork

Reductio n Ac t

o f 1380 , 4- S U.S.C

. 330 1 eises

. Lis t o f Subject s i n 2

0 CF RPar t G O Ai r pollutio n control , Municipa l wast e combustors , MWCs , Polychlorinate d dibenzo-p-dioxins , Polychlorinate d dibenzofurans , Hydroge n chloride , Dstad : Novambs

r 30,1989

. Willia mK

. Reiiiy , Administrator, Th e EP A propose s t o amen dtid e 40 , par t 6 0 o f th e Cod e o

f Federa l Regulation s a s follows : 1

. Th e authorit y citatio n fo r par t 6 0 continue s t

o rea da s follows : Authority : 4

2 U.S.C

. 7401 , 7411

. "414

. 7416 , 7601

. 2

. Append!:' ; A i s tende d b y addin g Method s 2 3 an d2 8 to rea da s fallows : Apjsamib s A—Jlsforenc aMethod s MeSfco d ^-Determinatio n o

f Polychloriauted

. Dibsnzo-p-Olcxin s Polychlorinate d Dibonzcfurons Fro

mStationar

y Source s 3. Applicability and

Principle 1. 1 Applicability

. Thi

ametho d i s applicable t

o the determinatio

n o f polychlorinate

d dibsnzo-p-dioxin s (PCDDs ) andpolychlorinateddibenzofuran s [PODFs J fromstationar

y sources . 1. 2 Principle

. A sampl

e i s withdrawn from th e ga s strea misokinetically

. andcollected i n th e sampl e probe , o n aglas s fiber

filter, an d o n apacke dcolum n o f adsorben t material

. Th e PCDD s an dPCDF s ar e extracte dfro

m tb. s sainpla , separate db

y hig h resolutio n ga s chromatography , an

dmeasure db y hig h resolution mas s spectrometry , Z Apparatus 2. 1 Sampling

. A schematic o f th e samplin g trai n usedi

n thi s metho

di s show n i n Figur e 23-1

. Th atrain i s identica

l t o tha t describe d i n Sectio n 2. 1 o f Metho d5 o f thi s appendi

x wit h the followin

g additions : 2.1. 1 Nozzle

. Th

e nozzl e shall b e mad

e o f nickel , iiicke

l platedstainles s steel , quartz , o r borosilicat e glass

. WWHGcoot

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